diff --git a/layer2/PGEE/code/step4.1_enhanced_classified_questions.json b/layer2/PGEE/code/step4.1_enhanced_classified_questions.json new file mode 100644 index 0000000..85a9121 --- /dev/null +++ b/layer2/PGEE/code/step4.1_enhanced_classified_questions.json @@ -0,0 +1,54974 @@ +[ + { + "idx": 1, + "question": "What are the parameters used to quantitatively describe crystal structures?", + "answer": "Unit cell parameters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述晶体结构的定量描述参数，答案\"Unit cell parameters\"是一个简短的文字回答，符合简答题的特征 | 知识层次: 题目考查对晶体结构定量描述参数的基本概念记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答晶体结构定量描述的基本参数（晶胞参数），属于最基础的定义性知识。不需要解释或描述概念，更不需要阐述复杂体系，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于直接回忆型问题，对知识掌握深度和解题步骤的要求都是最低的。" + }, + { + "idx": 2, + "question": "What are the parameters used to qualitatively describe crystal structures?", + "answer": "Symmetry axes, symmetry center, crystal system, lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答，答案是一系列描述晶体结构的参数，而不是选择、判断或计算。 | 知识层次: 题目考查晶体结构定性描述的基本参数，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求列举定性描述晶体结构的参数，这些参数（对称轴、对称中心、晶系、晶格）都是晶体学中最基础的概念，属于记忆性知识范畴。回答时只需直接罗列术语，无需深入解释或建立概念间的逻辑关系，符合等级1对知识点掌握深度和解题步骤简单的要求。" + }, + { + "idx": 3, + "question": "According to the nature of bonding forces, what are the types of bonding interactions in crystals?", + "answer": "The bonding interactions in crystals can be classified into ionic bonds, covalent bonds, metallic bonds, van der Waals bonds, and hydrogen bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据键合力的性质分类晶体中的键合相互作用，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体中键合相互作用的基本分类，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举晶体中的键合类型，不需要进行概念解释或复杂体系阐述，属于最基础的概念记忆性知识。" + }, + { + "idx": 4, + "question": "The intercepts of a crystal plane on the x, y, and z axes are a/3, b/2, and c, respectively. Determine the Miller indices of this crystal plane.", + "answer": "h:k:l=3:2:1, the Miller indices of this crystal plane are (321).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定晶面的Miller指数，需要应用晶体学中的相关公式和步骤进行计算，最终得出数值结果(321)。 | 知识层次: 题目考查晶体学中Miller指数的基本计算方法，需要应用倒数的概念进行简单计算，属于直接套用公式的范畴，不需要多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目只需要根据给定的截距直接套用Miller指数的计算公式，即取截距的倒数并化为最简整数比，无需额外的步骤或复杂的计算过程。因此，在该题型内属于最简单的难度等级。" + }, + { + "idx": 5, + "question": "What are the two types of voids in the closest packing of equal spheres?", + "answer": "The closest packing of equal spheres includes hexagonal close packing and face-centered cubic close packing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释两种最密堆积中的空隙类型，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对最密堆积中空隙类型的基础概念记忆，仅需回忆和陈述两种基本类型，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答最密堆积中两种空隙类型的名称，属于最基本的概念记忆性知识，不需要额外的解释或论述步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 6, + "question": "A crystal plane has intercepts of 2a, 3b, and 6c on the X, y, and z axes respectively. Find the Miller indices of this crystal plane.", + "answer": "h:k:1=2:3:6=3:2:1, the Miller indices of this crystal plane are (321).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算晶体平面在X、Y、Z轴上的截距来确定其Miller指数，需要应用特定的公式和步骤进行计算，最终得出数值结果(321)。 | 知识层次: 题目考查的是Miller指数的基本计算，需要应用基本公式进行简单计算，属于直接套用公式的应用层次。虽然需要理解截距与Miller指数的关系，但整体思维过程较为直接，不涉及多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要根据给定的截距直接套用Miller指数的计算公式（取倒数并化为最小整数比），无需额外的公式组合或复杂计算步骤。解题过程仅涉及基本数学运算和简单公式应用，符合等级1的标准。" + }, + { + "idx": 7, + "question": "What are the characteristics of covalent bonds?", + "answer": "The characteristics of covalent bonds are directionality and saturation, and the bonding force is also very strong.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释共价键的特性，答案以文字论述形式给出，符合简答题的特征 | 知识层次: 题目考查共价键的基本特性，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述共价键的特性，涉及概念解释和描述，但不需要复杂的体系阐述。属于基础概念记忆层次中的中等难度，需要理解并表述共价键的方向性、饱和性和强键力等基本特征。" + }, + { + "idx": 8, + "question": "What are the characteristics of metallic bonds?", + "answer": "Metallic bonds are non-directional and non-saturated covalent bonds, where the binding force is the electrostatic Coulomb force between ions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属键的特性，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查金属键的基本特征和定义，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目要求解释金属键的特征，涉及非方向性和非饱和性等基本概念，并需要简要说明结合力的本质。这属于概念解释和描述的层次，比单纯的定义简答（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 9, + "question": "Calculate the number of atoms in a face-centered cubic unit cell", + "answer": "Number of atoms 4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算面心立方晶胞中的原子数），答案是一个具体的数值（4），解答过程需要应用晶体学中的原子位置和晶胞结构知识进行计算。 | 知识层次: 题目要求计算面心立方晶胞中的原子数，这需要应用基本的晶体结构知识，但计算过程相对简单直接，仅需套用已知的原子位置和贡献比例公式即可得出结果。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算面心立方晶胞中的原子数，这是一个基本的晶体学问题，只需要直接应用面心立方晶胞的原子数公式（每个角原子贡献1/8，每个面心原子贡献1/2，总计4个原子）即可得出答案。无需多个公式组合或复杂计算步骤，属于该题型中最基础的难度等级。" + }, + { + "idx": 10, + "question": "What are the characteristics of hydrogen bonds?", + "answer": "A hydrogen bond is a bond formed between two atoms with relatively high electronegativity, and it possesses saturation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释氢键的特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查氢键的基本定义和特性，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答氢键的基本特征，属于基础定义简答。题目仅涉及氢键的定义和简单特性（如饱和性），不需要深入解释或复杂概念体系的阐述。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 11, + "question": "What are the characteristics of van der Waals bonds?", + "answer": "Van der Waals bonds are formed through molecular forces, and the molecular forces are very weak.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释van der Waals bonds的特性，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对范德华键基本特性的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目仅要求回答范德华键的基本特征，属于基础定义简答。题目不需要复杂的解释或概念体系阐述，仅需记忆和复述基本定义即可完成回答。因此在该题型和知识层次下属于最低难度等级。" + }, + { + "idx": 12, + "question": "How many tetrahedral voids and octahedral voids are there around a sphere?", + "answer": "There are 8 tetrahedral voids and 6 octahedral voids around a sphere.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述四面体空隙和八面体空隙的数量，答案以文字形式给出，不需要计算或选择选项 | 知识层次: 题目考查对晶体结构中四面体空隙和八面体空隙数量的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并复述关于四面体空隙和八面体空隙数量的基本概念，无需解释或推导过程，属于最基础的知识点考查。" + }, + { + "idx": 13, + "question": "When n equal-sized spheres are closely packed, how many tetrahedral voids and octahedral voids can be formed?", + "answer": "When n equal-sized spheres are closely packed, 2n tetrahedral voids and n octahedral voids can be formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释紧密堆积中四面体空隙和八面体空隙的数量关系，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对紧密堆积中四面体空隙和八面体空隙数量的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答紧密堆积球体中四面体空隙和八面体空隙的数量，这需要对相关概念有一定的理解和记忆，但不需要复杂的推导或深入的分析。虽然涉及两个概念（四面体空隙和八面体空隙），但答案直接给出数量关系，属于中等难度的概念解释题。" + }, + { + "idx": 14, + "question": "What are the characteristics of ionic bonds?", + "answer": "The characteristics of ionic bonds are the absence of directionality and saturation, with very strong bonding forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释离子键的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查离子键的基本特征，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释离子键的特性，涉及概念描述和基本原理的记忆，但不需要复杂的体系阐述或深入分析。属于中等难度，需要学生对离子键的基本特性有清晰的理解和表述能力。" + }, + { + "idx": 15, + "question": "Calculate the coordination number in a face-centered cubic unit cell", + "answer": "Coordination number 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算面心立方晶胞中的配位数，需要应用晶体结构知识进行数值计算，最终给出具体数值结果(Coordination number 6) | 知识层次: 题目要求计算面心立方晶胞的配位数，这需要应用基本的晶体结构知识，但计算过程相对简单直接，属于基本公式应用和简单计算的范畴。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目仅需直接套用面心立方晶胞的配位数公式（固定值为12），属于单一公式直接计算的等级1难度。题目不涉及任何公式组合或推导步骤，完全符合该难度等级\"直接套用基本公式\"的特征。" + }, + { + "idx": 16, + "question": "How are unequal-sized spheres packed?", + "answer": "In the close packing of unequal-sized spheres, it can be considered that the larger spheres are first closely packed as equal-sized spheres, and then the smaller spheres are filled into the gaps according to their sizes. Slightly larger small spheres fill the octahedral voids, while slightly smaller small spheres fill the tetrahedral voids, forming the close packing of unequal-sized spheres.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对不等径球体的紧密堆积方式进行文字解释和论述，答案提供了详细的描述和说明，符合简答题的特征。 | 知识层次: 题目考查对不等径球体密堆积方式的基本概念记忆和理解，属于材料科学中晶体结构的基础知识范畴，不需要复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释不等径球体的密堆积方式，涉及基本概念的记忆和简单应用，但不需要复杂的体系阐述或多步骤推理。学生只需理解并描述大球体和小球体在密堆积中的排列方式即可，属于中等偏下的难度水平。" + }, + { + "idx": 17, + "question": "Write the coordinates of all nodes on the unit parallelepiped of the face-centered cubic lattice.", + "answer": "All nodes on the unit parallelepiped of the face-centered cubic lattice are: (000), (001), (100), (101), (110), (010), (011), (111), (1/2 0 1/2), (0 1/2 1/2), (1/2 1/2 0), (1 1/2 1/2), (1/2 1 1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出面心立方晶格单位平行六面体上所有节点的坐标，答案以列举形式给出，属于需要具体描述和列举的简答题类型。 | 知识层次: 题目考查对face-centered cubic lattice节点坐标的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求写出面心立方晶格单位平行六面体上所有节点的坐标，但只需要记忆和列举这些坐标，不需要进行复杂的推导或解释。相较于等级1的基本定义简答，该题目需要记忆更多的具体坐标点，但相较于等级3的复杂概念体系阐述，该题目不需要深入的解释或论证。因此，该题目在简答题题型内属于等级2的难度。" + }, + { + "idx": 18, + "question": "Calculate the packing coefficient in a face-centered cubic unit cell", + "answer": "Atomic packing coefficient APC=(4×(4/3)πr^3)/(2√2r)^3=74.05%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及使用几何公式计算原子堆积系数，最终给出具体的百分比结果 | 知识层次: 题目要求计算面心立方晶胞的堆积系数，涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，虽然需要理解面心立方晶胞的结构特征和原子堆积系数的概念，但解题过程仅需套用单一几何公式（球体积和立方体体积公式）并进行简单代数运算，无需多步骤推导或复杂公式组合。" + }, + { + "idx": 19, + "question": "Calculate the number of atoms in a hexagonal close-packed unit cell", + "answer": "Number of atoms 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算六方密堆积晶胞中的原子数），答案是一个具体的数值结果（6），这符合计算题的特征 | 知识层次: 题目要求计算六方密堆积晶胞中的原子数，这需要应用基本的晶体结构知识和简单的数学计算。虽然需要理解六方密堆积的结构特点，但计算过程相对直接，属于基本公式应用和简单计算的范畴。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目仅需直接套用单一公式（六方密堆积晶胞原子数计算公式）进行计算，无需组合多个公式或进行复杂推导，属于最基础的难度等级。解题步骤仅涉及简单数值代入和基本算术运算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 20, + "question": "Calculate the packing coefficient in a hexagonal close-packed unit cell", + "answer": "Atomic packing coefficient APC=(6×(4/3)πa^3)/((3√3a^2/2)√8)=74.05%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算六方密堆积晶胞的堆积系数），答案是通过公式应用和数值计算得出的具体百分比结果（74.05%），符合计算题的特征。 | 知识层次: 题目需要应用几何公式和原子堆积原理进行多步计算，涉及对六方密堆积结构的理解和综合分析能力，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解六方密堆积结构的基本概念，应用几何公式进行多步计算，包括球体积、晶胞体积和高度等参数的推导，最终综合得出原子堆积系数。虽然计算过程涉及多个步骤，但各步骤之间的逻辑关系清晰，属于该题型内中等偏上的难度。" + }, + { + "idx": 21, + "question": "Calculate the coordination number in a hexagonal close-packed unit cell", + "answer": "Coordination number 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方密堆积晶胞中的配位数，需要应用相关晶体学知识进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目要求计算六方密堆积晶胞的配位数，属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算六方密堆积晶胞的配位数，这是一个基本且直接的概念应用，无需多个公式组合或复杂计算步骤。学生只需记住并应用配位数的定义即可得出答案，因此在该题型内属于最简单的难度等级。" + }, + { + "idx": 22, + "question": "According to the radius ratio relationship, what is the coordination number when Si4+ coordinates with O2-? Given rO2-=0.132nm, rSi4+=0.039nm.", + "answer": "For Si4+, r+/r-=0.039/0.132=0.295; based on the relationship between cation coordination number and cation-anion radius ratio, the coordination number is 4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的离子半径计算半径比，并基于半径比关系确定配位数。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目涉及基本的半径比计算和协调数的直接应用，属于基本公式应用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需单一公式（半径比关系）直接计算，解题步骤简单，直接套用已知数值即可得出结果，无需复杂推理或多步骤计算。" + }, + { + "idx": 23, + "question": "Based on the radius ratio relationship, determine the coordination number of K+ when coordinated with O2-. Given rO2-=0.132nm and rK+=0.131nm.", + "answer": "For K+, r+/r-=0.131/0.132=0.99; according to the relationship between cation coordination number and the radius ratio of positive to negative ions, the coordination number is 8.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的离子半径数据进行计算，应用半径比关系公式来确定配位数。解答过程涉及数值计算和公式应用，最终得出具体的配位数结果。 | 知识层次: 题目涉及基本的半径比计算和直接套用半径比与配位数关系的表格，属于基本公式应用和简单计算范畴，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用半径比公式进行计算，并直接根据给定的半径比值确定配位数，无需额外的步骤或复杂的公式组合。" + }, + { + "idx": 24, + "question": "The metal magnesium atoms form a hexagonal close packing, and its density is measured to be $1.74\\\\mathrm{g/cm}^{3}$. Find the volume of its unit cell.", + "answer": "Let the volume of the unit cell be V, and the relative atomic mass be M. Then the unit cell volume $$V={\\\\frac{n M}{M_{0}\\\\rho}}={\\\\frac{6\\\\times24}{6.023\\\\times10^{23}\\\\times1.74}}=1.37\\\\times10^{-22}\\\\quad\\\\mathrm{\\\\quad\\\\quad}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案展示了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将密度、相对原子质量和单位晶胞体积的关系直接套用公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算单位晶胞体积，直接套用密度公式即可完成计算，无需多个公式组合或复杂推导。虽然涉及单位换算和科学计数法运算，但整体解题步骤清晰明确，属于该题型框架内的基础难度级别。" + }, + { + "idx": 25, + "question": "In CaO, the unit cell parameter a=0.480 nm, and the anions and cations are in contact with each other. Find the radius of O2-. The radius of Ca2+ is known to be 0.107 nm.", + "answer": "In CaO, a=0.480 nm, and the anions and cations are in contact with each other. a=2(r+ + r-), therefore rO2-=(0.480 nm / 2) - 0.107 nm = 0.097 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解O2-的半径，解答过程涉及单位转换和简单的代数运算，最终给出具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过已知的晶胞参数和离子半径关系进行计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目直接给出了单位晶胞参数和阳离子半径，只需要应用简单的公式a=2(r+ + r-)进行一步计算即可得出结果，无需多个公式组合或复杂推导。" + }, + { + "idx": 26, + "question": "According to the closest packing principle, the higher the space utilization, the more stable the structure. The space utilization of the diamond structure is very low (only 34.01%), why is it also very stable?", + "answer": "The closest packing principle is based on the spherical symmetry and non-directionality of the electron cloud distribution of particles, so it only applies to typical ionic crystals and metallic crystals, and cannot be used to measure the stability of atomic crystals. In addition, the number of single bonds in diamond is 4, meaning each atom is surrounded by 4 single bonds (or atoms), forming a three-dimensional structure through covalent bonding of tetrahedra sharing vertices. Therefore, although the space utilization of the diamond structure is very low (only 34.01%), it is still very stable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么金刚石结构在空间利用率低的情况下仍然非常稳定，答案提供了详细的文字解释和论述，涉及电子云分布、晶体类型和共价键结构等概念，符合简答题的特征。 | 知识层次: 题目不仅需要理解最密堆积原理的基本概念，还需要分析其适用范围和局限性，并进一步解释金刚石结构的稳定性机制。这涉及到对晶体结构、化学键类型（共价键）以及空间利用率和稳定性之间关系的综合分析，需要较高的推理分析和机理解释能力。 | 难度: 在简答题的复杂分析层次中，该题目要求综合运用晶体结构原理、化学键理论以及空间利用率概念，进行多维度推理分析。需要突破最密堆积原理的常规认知，解释原子晶体的特殊稳定性机制，涉及电子云分布对称性、共价键方向性等深层次机理。同时需要构建三维结构认知，论证配位数与稳定性的关系，属于该题型内对知识整合和逻辑推导要求极高的复杂现象全面分析题目。" + }, + { + "idx": 27, + "question": "According to the radius ratio rule, what is the coordination number when Mg2+ coordinates with O2-? Given rO2-=0.132nm, rMg2+=0.078nm.", + "answer": "For Mg2+, r+/r-=0.078/0.132=0.59; based on the relationship between cation coordination number and cation-anion radius ratio, the coordination number is 6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的离子半径计算半径比，并应用半径比规则确定配位数。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用半径比规则进行简单的数值计算，并直接套用已知的半径比与配位数的关系得出结果。虽然涉及基本概念，但主要考察的是基本公式的应用和简单计算能力。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目仅需要应用半径比规则，通过简单的除法计算半径比，然后直接查表或根据已知关系确定配位数。解题步骤简单，无需多个公式组合或复杂计算，符合等级1的标准。" + }, + { + "idx": 28, + "question": "In MgS, the unit cell parameter a=0.5201 nm, and the anions are in contact with each other. Calculate the radius of S2-.", + "answer": "In MgS, a=0.5201 nm, and the anions are in contact with each other, a=2√2 r-, thus rS2-=0.5201 nm / (2√2) = 0.177 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解S2-的半径，答案也展示了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过给定的晶胞参数和几何关系计算离子半径，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用一个简单的几何关系公式（a=2√2 r-）即可直接计算出S2-的半径，无需额外的公式组合或复杂的解题步骤。" + }, + { + "idx": 29, + "question": "Calculate whether the valence of I- in CdI2 crystal is saturated?", + "answer": "In CdI2 crystal, the coordination number (CN) of Cd2+ is 6. I is connected to three Cd2+ on the same side, and the coordination number (CN) of I is 3. Therefore, CN ∑i(z+/CN)=1=1z−1, meaning the valence of I− is saturated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来判断I-在CdI2晶体中的价态是否饱和，答案提供了详细的解释和逻辑推理，而非简单的计算或选择。 | 知识层次: 题目需要理解配位数和价态饱和的概念，并进行多步计算和综合分析，涉及概念关联和简单推理，但不需要复杂的机理分析或创新应用。 | 难度: 在简答题中属于较高难度，需要综合运用晶体结构、配位数、价态饱和等多方面知识进行多步计算和概念关联分析，并给出完整的文字解释和论述。" + }, + { + "idx": 30, + "question": "Why is the transformation temperature between different series of quartz variants much higher than that between variants of the same series?", + "answer": "The transformation within the same series of quartz is a displacive transformation, which does not involve the breaking and rebuilding of bonds in the crystal structure, but only the adjustment of bond lengths and angles, requiring lower energy and being rapidly reversible. In contrast, transformations between different series are reconstructive, involving the breaking of old bonds and the formation of new ones, thus requiring higher energy and proceeding at a slower rate. Therefore, the transformation temperature between different series of quartz is much higher than that between variants of the same series.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释石英变体之间转化温度的差异，答案提供了详细的文字解释和论述，涉及晶体结构变化的机制和能量需求，符合简答题的特征。 | 知识层次: 题目要求解释石英变体间相变温度的差异，涉及位移型相变和重建型相变的机理分析，需要综合运用晶体结构、相变动力学等知识进行推理和解释，思维过程较为深入。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解石英变体之间的转变类型（位移型与重建型），还需要深入解释这两种转变在能量需求和速率上的差异，以及这些差异如何导致转变温度的不同。这需要考生具备扎实的晶体学基础，能够综合运用相关知识进行推理分析，并清晰地阐述其中的机理。虽然题目没有要求全面分析复杂现象（如多种因素的综合影响），但对机理的解释深度要求较高，因此属于等级4。" + }, + { + "idx": 31, + "question": "In CaS, the unit cell parameter a=0.567 nm, and the anions and cations are in contact with each other. Calculate the radius of Ca2+. The radius of S2- is known to be 0.177 nm.", + "answer": "In CaS, a=0.567 nm, and the anions and cations are in contact with each other, a=2(r+ + r-), therefore rCa2+=(0.567 nm / 2) - 0.177 nm = 0.107 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Ca2+的半径），并应用了特定的公式（a=2(r+ + r-)），答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，即通过已知的晶胞参数和离子半径直接套用公式求解未知离子半径。不需要多步计算或综合分析，属于简单应用层次。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用简单的离子半径计算公式a=2(r+ + r-)并进行一步减法运算，无需多步骤推导或复杂公式组合。" + }, + { + "idx": 32, + "question": "Compare the unit cell parameter values obtained from density calculations with those calculated from ionic radii.", + "answer": "Calculated from ionic radii: a=2(r₊+r₋)=0.414 nm ∴ a₀ < a", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目涉及通过密度计算和离子半径计算晶胞参数值，需要数值计算和公式应用。答案展示了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算（密度计算和离子半径计算），并比较两种不同方法得到的结果，涉及概念关联和综合分析。虽然计算本身不复杂，但需要理解离子半径和晶格参数之间的关系，并进行比较分析。 | 难度: 在计算题中属于综合性计算问题，需要结合密度计算和离子半径计算两种方法，并进行比较分析。虽然计算步骤不算特别复杂，但涉及多概念关联和综合分析，属于中等偏上的难度。" + }, + { + "idx": 33, + "question": "In MgO, the unit cell parameter a=0.420 nm, and the anions and cations are in contact with each other. Calculate the radius of Mg2+. The radius of O2- is known to be 0.097 nm.", + "answer": "In MgO, a=0.420 nm, and the anions and cations are in contact with each other. a=2(r+ + r-), therefore rMg2+=(0.420 nm / 2) - 0.097 nm = 0.113 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的单位晶胞参数和离子半径数据进行数值计算，应用晶体几何关系公式（a=2(r+ + r-)）来求解Mg2+的半径，答案呈现为具体的计算结果（0.113 nm），符合计算题的特征。 | 知识层次: 题目涉及基本的晶体结构参数计算，仅需应用简单的公式（a=2(r+ + r-)）进行一步计算即可得到结果，属于直接套用基本公式的简单应用层次。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（a=2(r+ + r-)）并进行简单减法运算即可得出答案，无需多步骤推导或复杂计算。" + }, + { + "idx": 34, + "question": "According to the rules of ionic compound formation, when all octahedral interstitial sites are filled, what valence cations should be inserted in the interstitial sites? Please provide examples.", + "answer": "The ratio of cation to anion valences should be 1:1, such as NaCl.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释离子化合物形成规则，并提供具体例子，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求根据离子化合物形成规则（基础概念）推导间隙位填充时的阳离子价态比（概念关联），并通过举例（NaCl）进行验证，需要理解间隙位填充规则与离子价态的关系，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解离子化合物形成的规则，并能够结合八面体间隙填充的具体情况进行分析。题目要求解释填充间隙的阳离子价态，并举例说明，涉及多步概念关联和综合分析，但不需要过于深入的多角度或深度关联性分析。" + }, + { + "idx": 35, + "question": "Lithium fluoride (LiF) has a NaCl-type structure, and its measured density is 2.6 g/cm³. Based on this data, calculate the unit cell parameter.", + "answer": "Assuming the volume of the unit cell is V and the relative atomic mass is M, for the NaCl-type structure, n=4. Then the unit cell volume V = (n M)/(N0ρ) = (4×26)/(6.023×10²³×2.6) = 6.64×10⁻²³ cm³. Therefore, the unit cell parameter: a₀ = ³√V = 0.405 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的密度数据计算晶胞参数，解答过程涉及数值计算和公式应用，最终得出具体的数值结果。 | 知识层次: 题目需要应用密度计算公式和晶体结构知识进行多步计算，涉及单位换算和立方根运算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶体结构、密度计算、单位晶胞参数等多步计算和概念关联。虽然计算步骤明确，但涉及多个物理量的综合运用和单位转换，对学生的综合分析能力有一定要求。" + }, + { + "idx": 36, + "question": "Calculate the ratio of octahedral void number to O2- number", + "answer": "The ratio of octahedral void number to O2- number is 1:1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算八面体空隙数与O2-离子数的比例），答案给出了具体的数值比例结果（1:1），这符合计算题的特征。 | 知识层次: 题目仅涉及基本公式应用和简单计算，直接套用晶体结构中八面体空隙与阴离子数量的比例关系即可得出答案，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（八面体空隙数与阴离子数之比为1:1）进行计算，无需任何推导或组合公式步骤。" + }, + { + "idx": 37, + "question": "Calculate the ratio of the number of tetrahedral voids to the number of O2- ions", + "answer": "The ratio of the number of tetrahedral voids to the number of O2- ions is 2:1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算四面体空隙与O2-离子的数量比），答案给出了具体的数值比例（2:1），这符合计算题的特征 | 知识层次: 题目涉及基本的晶体结构计算，需要应用已知的晶体学知识（如四面体空隙与离子数量的比例关系）进行简单计算，属于直接套用基本公式的范畴，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用晶体结构中四面体空隙与离子数量的基本比例关系（2:1），无需复杂推导或多步骤计算，属于最基础的公式套用类型。" + }, + { + "idx": 38, + "question": "MgO and CaO both belong to the NaCl-type structure, but when they react with water, CaO is more reactive than MgO. Please explain.", + "answer": "Because ${r_{i\\\\parallel_{g}}}^{2+}$ and ${r_{C a}}^{21}$ are different, $r_{\\\\tt C a2+}>r_{\\\\tt B_{\\\\tt B}2+}$, making the structure of CaO looser than that of $\\\\mathrm{Mg0}$, allowing $\\\\mathrm{H}_{2}\\\\mathrm{0}$ to enter more easily, hence more reactive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释MgO和CaO反应活性的差异，答案通过文字论述和比较离子半径来解释现象，符合简答题的特征。 | 知识层次: 题目要求解释MgO和CaO在反应活性上的差异，涉及离子半径对晶体结构的影响以及与水反应的机理分析。需要综合运用晶体结构知识、离子半径效应和化学反应活性的理解，进行推理和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对离子半径差异导致的晶体结构变化进行机理层面的解释，并推导出反应活性的差异。虽然不需要多因素综合分析（等级5），但需要深入理解晶体结构原理和化学反应性的关系，属于机理深度解释的典型题目。" + }, + { + "idx": 39, + "question": "Calculate whether the valence of O2- in CaTiO3 crystal is saturated?", + "answer": "In CaTiO3 crystal, the coordination number of Ca2+ CN=12, the coordination number of Ti4+ CN=6, and the coordination number of O2- CN=6, so CN ∑i(z+/CN)=2=|z−|, that is, the valence of O2- is saturated.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来判断O2-的价态是否饱和，解答过程中涉及到了配位数和价态的计算，需要应用相关公式和数值计算。 | 知识层次: 题目需要进行多步计算（包括配位数计算和电价平衡计算），并需要理解晶体结构中离子价态的饱和条件，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构中配位数的概念，并进行多步计算来验证氧离子的价态是否饱和。题目涉及多个离子的配位数计算和价态平衡的综合分析，但不需要处理复杂多变量情况。" + }, + { + "idx": 40, + "question": "According to the rules of ionic valence, when all tetrahedral interstitial sites are filled, what valence cations should be filled in the interstitial sites, and provide an example.", + "answer": "The ratio of cation to anion valences should be 1:2, such as CaF2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释离子价规则并举例说明，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解离子价规则并应用到具体的晶体结构中，涉及多步概念关联和综合分析，如确定填隙位点的离子价态比例并举例说明。 | 难度: 在简答题中属于中等难度，需要理解离子价态规则并能够进行综合分析和说明。题目要求解释当所有四面体间隙位被填满时，应填入何种价态的阳离子，并给出实例。这需要掌握离子价态的基本规则，并能将其应用到具体材料中（如CaF2）。虽然涉及多步概念关联，但不需要过于复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 41, + "question": "According to the电价规则, when half of the tetrahedral interstitial sites are filled, what valency cations should be inserted into the interstitial sites, and provide an example to illustrate.", + "answer": "The ratio of cation to anion valency should be 1:1, such as ZnS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释电价规则并举例说明，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解电价规则并应用到具体情境中，涉及多步概念关联和综合分析，如计算离子价态比例并举例说明。 | 难度: 在简答题中属于较高难度，需要综合运用电价规则、晶体结构知识以及化学计量比概念进行多角度分析。题目要求不仅解释理论依据（1:1价态比），还需举例说明（ZnS），涉及概念关联和实例验证两个层面的论述。" + }, + { + "idx": 42, + "question": "According to the电价规则, when half of the octahedral interstitial sites are filled, what valence cations should be inserted into the interstices, and provide examples to illustrate.", + "answer": "The valence ratio of anions to cations should be 1:2, such as TiO2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释电价规则并举例说明，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求应用电价规则进行具体分析，涉及多步推理和概念关联（如离子价态与间隙填充的关系），并需要举例说明，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用电价规则、晶体结构知识，并进行多步计算和概念关联。题目要求不仅解释填充规则，还需举例说明，涉及综合分析能力。" + }, + { + "idx": 43, + "question": "According to the radius ratio relationship, what is the coordination number when Al3+ coordinates with O2-? Given rO2-=0.132nm, rAl3+=0.057nm.", + "answer": "For Al3+, r+/r-=0.057/0.132=0.43; based on the relationship between cation coordination number and the radius ratio of positive to negative ions, the coordination number is 6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的离子半径计算半径比，并应用半径比与配位数的关系来确定配位数。解答过程涉及数值计算和公式应用，属于典型的计算题。 | 知识层次: 题目涉及基本的半径比计算和配位数的确定，属于直接套用已知公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，只需要应用半径比公式进行简单计算即可得出结果，无需多个公式组合或复杂步骤。" + }, + { + "idx": 44, + "question": "Barium titanate is an important ferroelectric ceramic, and its crystal type is perovskite structure. What lattice does it belong to?", + "answer": "It belongs to the cubic crystal system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述Barium titanate的晶体结构类型，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对Barium titanate晶体结构类型的基本概念记忆，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答基本的晶体结构分类，属于最基础的定义简答。不需要进行概念解释或复杂体系阐述，仅需记忆性知识即可作答。在同题型内属于最低难度等级。" + }, + { + "idx": 45, + "question": "Barium titanate is an important ferroelectric ceramic with a perovskite crystal structure. What are the coordination numbers of the ions in this structure?", + "answer": "The coordination numbers of Ba²⁺, Ti⁴⁺, and O²⁻ are 12, 6, and 6, respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述离子在钙钛矿结构中的配位数，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对钙钛矿晶体结构中离子配位数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要记忆Ba²⁺、Ti⁴⁺和O²⁻的配位数，但不需要复杂的推理或阐述。题目考查的是对钙钛矿晶体结构中离子配位数的基本理解，属于中等难度的记忆性知识。" + }, + { + "idx": 46, + "question": "What is the basis for the classification of silicate crystals?", + "answer": "Silicate crystals are mainly classified based on the arrangement and bonding manner of [Si04] in the structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对硅酸盐晶体的分类基础进行解释，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对硅酸盐晶体分类基础概念的记忆和理解，主要涉及[Si04]排列和键合方式的基本原理，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释硅酸盐晶体分类的基础，涉及对[Si04]排列和键合方式的理解和描述，但不需要深入阐述复杂的分类体系或进行多层次的比较分析。这比单纯的定义简答（等级1）要求更高，但比需要系统阐述复杂概念（等级3）的要求低。" + }, + { + "idx": 47, + "question": "Into which categories can silicate crystals be classified?", + "answer": "Silicate crystals can be specifically classified into five categories: island, group, chain, layer, and framework.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对硅酸盐晶体进行分类，并列举具体的类别，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对硅酸盐晶体分类的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对硅酸盐晶体进行分类并列举具体类别，属于概念解释和描述的难度级别。虽然需要记忆五种分类，但不需要深入阐述各类别的形成机制或结构特点，解题步骤相对简单，属于该题型中的中等难度。" + }, + { + "idx": 48, + "question": "What are the structural characteristics of island silicates?", + "answer": "The structural characteristics of island silicates: [Si04] shares 0 O2-, the shape is tetrahedral, the complex anion group is [Si04], and the Si:O ratio is 1:4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释岛状硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对岛状硅酸盐结构特征的基本概念记忆，包括硅氧四面体的形状、共享氧离子数量、复杂阴离子团和硅氧比等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释岛状硅酸盐的结构特征，涉及对[Si04]四面体结构、氧共享情况、复杂阴离子团和Si:O比例的描述。虽然需要记忆多个具体特征，但仍属于基础概念的解释和描述范畴，未达到复杂概念体系阐述的深度。相较于仅回答基本定义的等级1题目，该题需要更系统的知识组织，但解题步骤仍较为直接。" + }, + { + "idx": 49, + "question": "MnS has three polycrystalline forms, two with the NaCl-type structure and one with the cubic ZnS-type structure. When transforming from the cubic ZnS-type structure to the NaCl-type structure, what is the percentage change in volume? Given that for CN=6, ${r_{\\\\mathrm{{Mn}}}}^{2+}=0.08\\\\mathrm{{nm}}$, $\\\\ensuremath{r_{\\\\mathrm{s}}}^{2-}=0.184\\\\mathrm{nm}$; and for CN=4, ${r_{\\\\mathrm{Mn}}}^{2+}\\\\mathrm{=}0.073\\\\mathrm{nm}$, ${r_{\\\\mathrm{S}}}^{2-}{=}0.167\\\\mathrm{nm}$.", + "answer": "For the cubic ZnS-type structure: $a1={\\\\frac{4}{\\\\sqrt{2}}}r_{S}^{2-}={\\\\frac{4}{\\\\sqrt{2}}}\\\\times0.167=0.472\\\\mathrm{nm}$. For the NaCl-type structure: $a_{2}=2(r_{\\\\mathrm{Mn}}^{2+}+r_{\\\\mathrm{S}}^{2-})=2(0.08+0.184)=0.384\\\\mathrm{nm}$. Thus, the volume change is: $V={\\\\frac{a1^{3}-a2^{3}}{a1^{3}}}={\\\\frac{0.472^{3}-0.384^{3}}{0.472^{3}}}=46.15\\\\%$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解体积变化的百分比，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目需要进行多步计算，包括晶体结构参数的计算和体积变化的百分比计算，涉及不同配位数下的离子半径应用，需要综合分析不同晶体结构之间的关系。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要理解晶体结构的概念，正确应用配位数对应的离子半径，进行多步计算（包括晶格常数计算和体积变化百分比计算），并综合分析不同结构类型对计算结果的影响。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有引入复杂变量或高级数学工具，因此在同类计算题中属于中等偏上难度（等级3）。" + }, + { + "idx": 50, + "question": "Barium titanate is an important ferroelectric ceramic with a perovskite crystal structure. Does this structure obey Pauling's rules? Please discuss in detail.", + "answer": "This structure obeys Pauling's rules. Pauling's first rule—the coordination polyhedron rule: rO²⁻=0.132nm, rTi⁴⁺=0.064nm, rBa²⁺=0.143nm. For TiO₆, rTi⁴⁺/rO²⁻=0.064/0.132=0.485, coordination number is 6. For BaO₁₂, rBa²⁺/rO²⁻=0.143/0.132=1.083, coordination number is 12. This complies with Pauling's first rule. Pauling's second rule—the electrostatic valence rule: the anion charge Z=∑(zi⁺/CNi), thus the O²⁻ ion charge=(2/12)×4+(4/6)×2=2, which equals the O²⁻ ion charge, so it complies with Pauling's second rule. Furthermore, according to the perovskite-type structure, its coordination polyhedra do not share edges or faces, and the structural situation also complies with Pauling's fourth rule—the rule of different polyhedron connections and Pauling's fifth rule—the parsimony rule. Therefore, the perovskite structure obeys Pauling's rules.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细讨论钛酸钡的钙钛矿晶体结构是否遵循鲍林规则，答案提供了详细的文字解释和论述，包括对鲍林规则的逐条分析，符合简答题的特征。 | 知识层次: 题目要求详细讨论钛酸钡的钙钛矿结构是否遵循鲍林规则，需要综合运用离子半径比计算、配位数分析、静电价规则验证等多方面知识，并进行机理层面的解释和推理分析。这涉及对晶体结构原理的深入理解和多规则的综合应用，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用Pauling规则对钙钛矿晶体结构进行多维度验证，涉及离子半径比计算、配位数推导、静电价规则验证以及多面体连接规则等复杂分析步骤。需要考生同时掌握晶体化学原理和钙钛矿结构特征，并能进行严密的逻辑推理和定量计算，属于该题型下最高难度的全面综合分析类题目。" + }, + { + "idx": 51, + "question": "The chemical handbook lists the density of NH4Cl as 1.5 g/cm3. X-ray data indicate that NH4Cl has two crystal structures: one is the NaCl-type structure with a=0.726 nm, and the other is the CsCl structure with a=0.387 nm. To which crystal type does the above density value belong? (The NH4+ ion occupies the crystal lattice as a single unit).", + "answer": "Solution: If NH4Cl has the NaCl structure, the density can be calculated using the formula: rho = n / (N_A * V) * M. Thus, the calculation yields: rho = 4 / (6.02 * 10^23) * 52.5 / (0.726 * 10^-7)^3 = 0.912 g/cm3. If NH4Cl has the CsCl structure, the density can be calculated using the formula: rho = n / (N_A * V) * M. Thus, the calculation yields: rho = 1 / (6.02 * 10^23) * 52.5 / (0.387 * 10^-7)^3 = 1.505 g/cm3. The calculation shows that the density of the NaCl-type NH4Cl is close to the value given in the chemical handbook, so the density corresponds to the NaCl crystal type.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定密度对应的晶体类型，解答过程中使用了密度计算公式，并进行了具体的数值运算。 | 知识层次: 题目需要进行多步计算，涉及晶体结构的密度公式应用，并且需要比较计算结果与给定数据以确定晶体类型。虽然计算本身不复杂，但需要理解晶体结构的基本概念和密度计算公式的应用，属于中等应用层次。 | 难度: 在计算题-需要数值计算和公式应用题型中，该题目属于综合性计算问题。题目要求考生进行多步计算（包括两种晶体结构的密度计算），并需要理解晶体结构类型与密度之间的关系。虽然计算过程相对直接，但需要正确应用公式和单位转换，同时进行综合分析判断，因此属于该题型中的中等难度（等级3）。" + }, + { + "idx": 52, + "question": "What are the structural characteristics of chain silicates?", + "answer": "The structural characteristics of chain silicates: [Si04] shares 2 or 3 O2-, shapes include single chains and double chains, the complex anion groups are [Si206]4 and [Si40], with Si:O ratios of 1:3 and 4:11 respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释链状硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查链状硅酸盐的结构特征，属于对基本概念的记忆和理解，包括硅氧四面体的共享氧原子数量、单链和双链的形状、复杂阴离子团的组成以及硅氧比等基础知识点。 | 难度: 在简答题题型中，该题目要求解释链状硅酸盐的结构特征，包括[Si04]的共享氧原子数量、单链和双链的形状、复杂阴离子团的化学式以及Si:O的比例。这需要学生对链状硅酸盐的基本结构有一定的理解和记忆，但不需要进行复杂的体系阐述或深入的分析。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 54, + "question": "What are the structural characteristics of layered silicates?", + "answer": "The structural characteristics of layered silicates: [Si04] shares 3 O2-, the shape is a planar layer, the complex anion group is [Si4010], and the Si:O ratio is 4:10.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释层状硅酸盐的结构特征，答案以文字形式详细描述了其结构特点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对层状硅酸盐结构特征的基本概念记忆和理解，包括硅氧四面体的共享氧、平面层形状、复杂阴离子团和硅氧比等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释层状硅酸盐的结构特征，涉及对[Si04]结构单元、氧共享方式、平面层形状、复杂阴离子团[Si4010]以及Si:O比例的描述。这属于概念解释和描述的范畴，需要学生记忆并理解相关基础概念，但不需要进行复杂的概念体系阐述或深入分析。因此，在简答题的基础概念记忆层次中属于中等难度（等级2）。" + }, + { + "idx": 55, + "question": "What are the structural characteristics of framework silicates?", + "answer": "The structural characteristics of framework silicates: [SiO4] shares 4 O2-, forming a skeleton [(AlxSi4)O], with the complex anion group being [SiO4]4, and the Si:O ratio is 1:4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释框架硅酸盐的结构特征，答案提供了详细的文字描述和结构特点，符合简答题的特征。 | 知识层次: 题目考查对框架硅酸盐结构特征的基本概念记忆和理解，涉及[SiO4]四面体的共享氧原子和骨架形成等基础知识点，属于定义和基本原理的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释框架硅酸盐的结构特征，包括[SiO4]的共享氧原子、骨架形成、复杂阴离子团和Si:O比例等概念。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 56, + "question": "What are the characteristics of silicate crystal structures? How are their chemical formulas characterized?", + "answer": "Silicate crystal structures are very complex, but different structures share the following common characteristics: (1) The $\\\\mathrm{Si}^{4+}$ ions in the structure are located at the center of tetrahedra formed by $\\\\mathrm{O}^{2-}$ ions, constituting the basic structural unit of silicate crystals, the $[\\\\mathrm{SiO}_{4}]$ tetrahedron. The Si-O-Si bond forms a bent line with varying angles, generally around $145^{\\\\circ}$. (2) Each vertex of the $[\\\\mathrm{SiO}_{4}]$ tetrahedron, i.e., the $\\\\mathrm{O}^{2-}$ ion, can be shared by at most two $[\\\\mathrm{SiO}_{4}]$ tetrahedra. (3) Two adjacent $[\\\\mathrm{SiO}_{4}]$ tetrahedra can only share vertices and cannot share edges or faces. (4) The $\\\\mathrm{Si}^{4+}$ ion at the center of the $[\\\\mathrm{SiO}_{4}]$ tetrahedron can be partially replaced by $\\\\mathrm{Al}^{3+}$ ions. This substitution, known as isomorphous replacement, does not significantly alter the structure itself but greatly changes the properties of the crystal, offering possibilities for material modification. The chemical formulas of silicates are primarily characterized by the following two methods: (1) Oxide representation method All oxides constituting the silicate crystal are written out in a certain proportion and order, starting with monovalent alkali metal oxides, followed by divalent and trivalent metal oxides, and finally $\\\\mathrm{SiO}_{2}$. (2) Inorganic complex salt representation method All ions constituting the silicate crystal are written out in a certain proportion and order, with the relevant complex anions enclosed in brackets. The order starts with monovalent and divalent metal ions, followed by $\\\\mathrm{Al}^{3+}$ ions and $\\\\mathrm{Si}^{4+}$ ions, and finally $\\\\mathrm{O}^{2-}$ ions and $\\\\mathrm{OH}^{-}$ ions. The advantage of the oxide representation method is that it clearly reflects the chemical composition of the crystal, allowing for laboratory synthesis based on this formulation. The inorganic complex salt method, on the other hand, provides a more intuitive reflection of the structural type of the crystal, enabling predictions about its structure and properties. The two representation methods can be converted into each other.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释硅酸盐晶体结构的特征及其化学式的表征方法，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目不仅要求记忆和理解硅酸盐晶体结构的基本特征（如[SiO4]四面体的构成和Si-O-Si键的角度），还需要理解并应用这些特征来解释硅酸盐的化学式表征方法（氧化物表示法和无机络盐表示法）。此外，题目还涉及到了同晶取代的概念及其对晶体性质的影响，这需要一定的概念关联和综合分析能力。虽然题目没有涉及复杂的计算或深度推理，但需要将多个概念联系起来进行解释，因此属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析和多角度论述。题目要求详细描述硅酸盐晶体结构的特征及其化学式的表征方法，涉及多个知识点的关联和综合分析。具体来说，需要理解硅酸盐晶体的基本结构单元、键角、共享顶点规则、同晶置换等概念，并能用两种不同的方法（氧化物表示法和无机络盐表示法）来表征化学式，同时比较它们的优缺点。这些要求超出了简单的概念复述，需要进行多步的逻辑推理和综合论述。" + }, + { + "idx": 57, + "question": "What type of silicate structure does Mg2[SiO4] belong to?", + "answer": "Island", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别硅酸盐结构类型，需要文字解释和论述，答案形式为简短的专业术语而非计算或选择 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答硅酸盐结构的基本分类（岛状结构），属于最基础的定义性知识。不需要进行概念解释或复杂体系阐述，仅需记忆性回答即可，符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单的直接回忆型问题。" + }, + { + "idx": 58, + "question": "What type of silicate structure does K[AlSi3O8] belong to?", + "answer": "Framework", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求识别并描述硅酸盐结构类型，需要文字解释和论述，而不是从选项中选择或简单判断对错 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求识别特定的硅酸盐结构类型（框架结构），但不需要复杂的推导或体系阐述，只需基于对硅酸盐结构分类的基本记忆和理解即可作答。相比等级1的基本定义简答，此题需要学生对硅酸盐结构分类有一定认知，但不需要深入分析或综合多个概念，因此属于中等难度。" + }, + { + "idx": 59, + "question": "What type of silicate structure does CaMg[Si2O6] belong to?", + "answer": "Single chain", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释CaMg[Si2O6]属于哪种硅酸盐结构，答案需要文字描述（Single chain），而不是从选项中选择或判断对错，也不需要计算。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，只需识别CaMg[Si2O6]属于单链结构这一知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆层次，仅需回答硅酸盐结构类型（单链结构），无需额外解释或复杂论述。题目直接考察对矿物化学式的结构分类记忆，属于该题型内最基础的难度等级。" + }, + { + "idx": 60, + "question": "What type of silicate structure does Mg3[Si4O10](OH)2 belong to?", + "answer": "Layered (double-chain)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释特定硅酸盐结构的类型，需要文字说明而非选择或判断，答案形式为简短的文字描述而非计算过程 | 知识层次: 题目考查对硅酸盐结构类型的基本分类记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目要求考生不仅记忆硅酸盐结构的基本分类，还需要理解并描述特定化学式对应的结构类型（层状双链结构）。这超出了单纯的定义记忆（等级1），但尚未达到需要阐述复杂概念体系（等级3）的程度，属于概念解释和描述的中间难度。" + }, + { + "idx": 61, + "question": "What type of silicate structure does Ca2Al[AlSiO7] belong to?", + "answer": "Group (double tetrahedron)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Ca2Al[AlSiO7]属于哪种硅酸盐结构，需要文字描述和论述，而不是从选项中选择或简单判断对错。答案\"Group (double tetrahedron)\"是一个简短的文字描述，符合简答题的特点。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，只需识别Ca2Al[AlSiO7]属于双四面体结构类型，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要识别特定的硅酸盐结构类型（双四面体），但不需要复杂的体系阐述或深入分析。主要考察对硅酸盐结构分类的基本记忆和理解，属于中等偏下的难度水平。" + }, + { + "idx": 62, + "question": "Based on the projection diagram of Mg2[SiO4] on the (100) plane, answer: Is the valence of O2- saturated?", + "answer": "O2- is bonded to 3 [Mg] and 1 [SiO], N∑i(z+/CN)=2=1z-1, so O2- is saturated", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于投影图分析O2-的价态是否饱和，需要通过文字解释和论述来回答，而不是简单的选择、判断或计算。答案中包含了化学键合分析和理论解释，符合简答题的特征。 | 知识层次: 题目需要理解投影图并应用化学键合理论进行计算和判断，涉及多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目需要多角度分析论述。首先需要理解Mg2[SiO4]的投影图，然后分析O2-的配位环境，最后通过计算N∑i(z+/CN)=2=1z-1来验证O2-的价态是否饱和。这涉及到晶体结构、配位化学和价态计算等多个概念的综合运用，解题步骤较为复杂，属于该题型内较高难度的题目。" + }, + { + "idx": 63, + "question": "Based on the projection of Mg2[SiO4] on the (100) plane, answer: what is the number of molecules in the unit cell?", + "answer": "z=4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于特定投影分析并回答晶胞中的分子数量，需要一定的解释和论述过程，答案虽然简短但需要理解晶体结构知识。 | 知识层次: 题目要求基于Mg2[SiO4]在(100)面的投影来确定晶胞中的分子数，这需要理解晶体结构投影的概念，并能将二维投影信息与三维晶胞结构关联起来进行计算。虽然不涉及复杂的机理分析，但需要多步思考和综合分析能力，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解晶体投影的概念，并能将二维投影信息与三维晶胞结构关联起来。虽然解题步骤相对明确（分析投影、推导晶胞分子数），但需要综合运用空间想象能力和晶体学知识，属于典型的多步计算和概念关联类题目。" + }, + { + "idx": 64, + "question": "Graphite, talc, and kaolinite have layered structures. Explain the differences in the structure of graphite and the resulting differences in properties.", + "answer": "Compared to talc and kaolinite, in graphite, the carbon atoms in the same layer undergo SP2 hybridization, forming large π bonds, and each layer has a hexagonal network structure. Due to the large interlayer gaps, electrons can move within the same layer, enabling electrical conductivity. The layers are held together by intermolecular forces, making graphite relatively soft.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释石墨的结构差异及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释石墨的结构差异及其对性能的影响，涉及SP2杂化、π键形成、导电性机理等复杂概念的综合分析和关联，需要深入理解材料结构-性能关系并进行推理分析。 | 难度: 在简答题中属于机理深度解释难度，需要考生理解石墨的SP2杂化、大π键形成、层间电子传导机制等复杂概念，并能对比其他层状材料的结构差异。虽然不涉及多因素交互作用（等级5特征），但要求对材料微观结构与宏观性能的关联性进行较深入的机理解释。" + }, + { + "idx": 65, + "question": "Based on the projection diagram of Mg2[SiO4] on the (100) plane, answer: What fraction of the tetrahedral and octahedral voids are occupied by Si4+ and Mg2+?", + "answer": "Si4+ occupies tetrahedral voids = 1/8, Mg2+ occupies octahedral voids = 1/2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于投影图分析并回答特定问题，需要解释和论述Si4+和Mg2+占据四面体和八面体空隙的比例，答案形式为文字描述而非计算或选择。 | 知识层次: 题目需要理解晶体结构投影图，分析四面体和八面体空隙的占据情况，涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要基于投影图进行多步分析和计算，涉及晶体结构中四面体和八面体空隙的占据情况，需要综合运用晶体学知识和空间想象能力，并进行详细论述。" + }, + { + "idx": 66, + "question": "Describe the basic types of dislocations and their characteristics.", + "answer": "There are two main types of dislocations: edge dislocation and screw dislocation. Characteristics of edge dislocation: the slip direction is perpendicular to the dislocation line, denoted by the symbol ⊥, with an extra half-plane of atoms. Characteristics of screw dislocation: the slip direction is parallel to the dislocation line, the plane perpendicular to the dislocation line is not flat, presenting a spiral shape, hence called screw dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述位错的基本类型及其特征，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对位错基本类型（刃位错和螺位错）及其特征的记忆和理解，属于材料科学中最基础的概念性知识，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求描述两种基本位错类型及其特征，需要学生对边缘位错和螺型位错的定义和特点有清晰的理解和记忆，并进行简要的文字描述。虽然涉及两个概念，但不需要复杂的分析或比较，属于该题型中的中等难度。" + }, + { + "idx": 68, + "question": "In silicate crystals, why can Al3+ partially replace Si4+ in the silicon-oxygen framework?", + "answer": "Al3+ can form [AlO4]5- with O2-. Al3+ and Si4+ are in the second period and have similar properties, making it easy for Al3+ to enter the silicate crystal structure and undergo isomorphous substitution with Si4+. Due to compliance with Pauling's rules, only partial substitution is possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al3+可以部分替代Si4+的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释Al3+部分取代Si4+的原因，涉及硅酸盐晶体结构、离子性质比较、类质同象替代以及Pauling规则的应用。这需要综合运用多个知识点，进行推理分析和机理解释，思维过程较深。 | 难度: 在简答题-复杂分析题型中，该题目要求对硅酸盐晶体中Al3+替代Si4+的机理进行深度解释，涉及[AlO4]5-的形成、元素周期律的应用以及Pauling规则的遵守等多重知识点。虽然不需要全面分析复杂现象，但需要综合运用晶体化学和配位化学原理进行推理分析，属于机理深度解释的难度等级。" + }, + { + "idx": 69, + "question": "What is the effect of Al3+ replacing Si4+ on the composition of silicates?", + "answer": "The replacement of Si4+ by Al3+ is a partial substitution. When Al3+ replaces Si4+, the structural units [AlSiO4][AlSiO5] lose electrical neutrality, resulting in excess negative charge. To maintain electrical neutrality, some larger cations with lower charges such as K+, Ca2+, and Ba2+ will enter the structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al3+替换Si4+对硅酸盐组成的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及硅酸盐中Al3+取代Si4+的效应，需要理解离子取代对结构电中性的影响以及如何通过引入其他离子来维持电中性。这需要将多个概念（离子取代、电中性、结构单元）关联起来进行分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解Al3+替换Si4+的基本概念，还需要分析这种替换对硅酸盐结构电中性的影响，并进一步说明如何通过引入其他阳离子来维持电中性。这涉及到多步的逻辑推理和综合分析，属于多角度分析论述的难度等级。虽然不需要进行深度关联性分析（如涉及更复杂的结构或更广泛的应用场景），但已经超出了简单的概念解释或单一步骤的推理。" + }, + { + "idx": 70, + "question": "Asbestos minerals such as tremolite $\\mathrm{Ca_{2}M g_{5}[S i_{4}O_{11}]}$ (OH)2 exhibit a fibrous crystal habit, while talc Mgs[Si4Oo](OH)2 displays a platy crystal habit. Please explain this phenomenon.", + "answer": "Tremolite has a double-chain structure, where the Si-O bonds within the chains are much stronger than the Ca-O and Mg-O bonds between the chains. Therefore, it easily cleaves along the weaker interchain bonding sites, resulting in a fibrous habit. Talc has a layered structure composed of two [SiO4] layers with a brucite-like layer in between. The layers are held together by weak van der Waals forces, and due to the weak intermolecular forces, talc readily cleaves along these weak bonding planes to form platy crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种矿物晶体习性的现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释矿物晶体习性的差异，需要分析晶体结构（双链结构和层状结构）与化学键强度的关系，并推导出不同解理方式导致的晶体形态差异。这涉及对晶体化学键类型、结构特征和力学性能之间关系的深入理解和综合分析，属于机理层面的解释。 | 难度: 在简答题题型中，该题目要求对两种矿物的晶体结构进行深入分析，并解释其不同晶体习性的机理。需要综合运用晶体化学、键合理论和矿物学知识，进行复杂的推理和解释。题目不仅要求识别结构差异，还要将结构与宏观性质（纤维状与片状习性）联系起来，属于该题型内对综合分析和机理解释要求最高的难度等级。" + }, + { + "idx": 71, + "question": "What are the characteristics of non-stoichiometric compounds?", + "answer": "Characteristics of non-stoichiometric compounds: The formation and defect concentration of non-stoichiometric compounds are related to the nature and pressure of the atmosphere; they can be regarded as solid solutions of higher-valent and lower-valent compounds; the defect concentration is related to temperature, which can be seen from the equilibrium constant; non-stoichiometric compounds are all semiconductors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释非化学计量化合物的特性，涉及多个相关概念（如缺陷浓度、温度影响、半导体性质等）的综合分析，需要理解并关联这些概念，但不需要深入推理或创新应用。 | 难度: 在简答题题型中，该题目要求对非化学计量化合物的特性进行多角度分析论述。需要理解并关联多个概念，如缺陷浓度与温度、气氛的关系，以及半导体性质等。虽然不需要进行深度关联性分析（如等级5所要求的），但已超出简单的综合说明（等级3），属于需要较全面论述的中高难度题目。" + }, + { + "idx": 72, + "question": "Using the电价规则, explain that when Al3+ replaces Si4+ in the framework, it usually does not exceed half, otherwise the structure will become unstable.", + "answer": "Assuming Al3+ replaces half of the Si4+, then O2- is connected to one Si4+ and one Al3+. The electrostatic bond strength of the cation = 3/4×1 + 4/4×1 = 7/4. The charge number of O2- is -2, and the difference between the two is 1/4. If the replacement exceeds half, the difference will inevitably be >1/4, causing structural instability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用电价规则解释Al3+替换Si4+时的结构稳定性问题，答案通过文字解释和论述来说明原因，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求学生运用电价规则解释Al3+替代Si4+的结构稳定性问题，涉及静电键强度的计算和结构稳定性的推理分析，需要综合运用多个概念并进行机理层面的解释。 | 难度: 在简答题-复杂分析题型中，该题目要求深入解释电价规则在晶体结构稳定性中的应用，涉及静电键强度的计算和结构不稳定性的推理分析。虽然不需要全面分析复杂现象，但需要机理深度解释，属于该题型中的较高难度等级。" + }, + { + "idx": 73, + "question": "Why are non-stoichiometric compounds all n-type or p-type semiconductor materials?", + "answer": "Due to anion vacancies and interstitial cations leading to an excess of metal ions, metal-excess (n-type) semiconductors are formed; cation vacancies and interstitial anions leading to an excess of anions form anion-excess (p-type) semiconductors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物为何都是n型或p型半导体材料，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非化学计量化合物为何都是n型或p型半导体材料，涉及对半导体类型形成机理的深入理解和分析，需要综合运用材料科学中的缺陷化学和半导体物理知识，属于复杂分析层次。 | 难度: 在简答题的复杂分析层次中，该题目要求全面解释非化学计量化合物为何呈现n型或p型半导体特性的复杂现象。需要综合运用晶体缺陷理论、半导体类型形成机理等知识，进行多步骤推理和深度机理分析，涉及阴离子空位、间隙阳离子等微观结构对宏观性能的影响机制，属于该题型内最高难度的全面分析类题目。" + }, + { + "idx": 74, + "question": "Explain the meaning of the symbol V_{Na}", + "answer": "Sodium atom vacancy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号V_{Na}的含义，需要文字解释和论述，答案形式为简短的文字说明 | 知识层次: 题目考查对材料科学中缺陷符号的基本概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（钠原子空位），属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中这是最简单的类型，只需直接回忆符号对应的专业术语即可。" + }, + { + "idx": 75, + "question": "What is the effect on crystal stability after forming a solid solution?", + "answer": "Stabilizes the crystal lattice and prevents certain polymorphic transitions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固体溶液对晶体稳定性的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解固溶体形成对晶体稳定性的影响，涉及晶体结构和相变的概念关联，并需要综合分析固溶体对晶格稳定性的作用机制。虽然不涉及复杂计算，但需要将多个概念联系起来进行解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释固体溶液对晶体稳定性的影响，但主要涉及晶体稳定性和多晶型转变的基本概念关联，不需要多角度或深度关联性分析。解题步骤相对直接，只需综合说明稳定晶格和防止多晶型转变的效应即可。" + }, + { + "idx": 76, + "question": "What is the effect on lattice activation after forming a solid solution?", + "answer": "Activating the lattice, after forming a solid solution, the lattice structure undergoes certain distortion and is in a high-energy activated state, which is conducive to chemical reactions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固溶体形成后对晶格活化的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及固溶体形成后晶格激活效应的解释，需要理解晶格畸变与高能态之间的关系，并分析其对化学反应的影响。这属于概念关联和综合分析层次，超出了单纯记忆基础概念的范畴，但尚未达到需要复杂推理或创新应用的深度。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释和论述固体溶液形成后对晶格活化的影响，但主要涉及单一概念（晶格活化）的分析和说明，不需要多角度或深度关联性分析。解题步骤相对直接，只需理解晶格畸变和高能态的概念即可回答。" + }, + { + "idx": 77, + "question": "What are the factors affecting the formation of substitutional solid solutions?", + "answer": "Factors influencing the formation of substitutional solid solutions include: (1) Ionic size: The 15% rule - 1. If (R1-R2)/R1 > 15%, discontinuous. 2. If ≤15%, continuous. 3. If >40%, solid solution cannot form. (2) Ionic valence: Same valence leads to continuous solid solution formation. (3) Crystal structure factors: Same structure of matrix and impurity results in continuous solid solution. (4) Field strength factor. (5) Electronegativity: Small difference favors solid solution formation, while large difference leads to compound formation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响置换固溶体形成的因素，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释影响置换固溶体形成的因素，涉及多个概念（离子尺寸、离子价态、晶体结构等）的关联和综合分析，需要理解并应用这些概念来解释现象，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要从多个角度（离子尺寸、离子价态、晶体结构、场强因子、电负性）综合分析置换固溶体形成的影响因素，并解释各因素的具体影响机制和相互关系。题目要求考生不仅掌握基本概念，还要能够将这些概念关联起来进行系统论述，体现了多角度分析论述的要求。" + }, + { + "idx": 78, + "question": "Based on the projection diagram of Mg2[SiO4] on the (100) plane, answer: How many types of coordination polyhedra are there in the structure, and what are the connection modes between the various coordination polyhedra?", + "answer": "There are two types of coordination polyhedra, [SiO4] and [MgO6]. [MgO6] octahedra in the same layer share edges, such as 59[MgO] and 49[MgO6] sharing edges 7502- and 2702-. [MgO6] octahedra in different layers share vertices, such as 1[MgO] and 51[MgO6] sharing vertex 2202-. [MgO] and [SiO4] in the same layer share vertices, such as T[MgO] and 7[SiO4] sharing vertex 2202-. [MgO6] and [SiO4] in different layers share edges, such as T[MgO] and 43[SiO4] sharing 2802- and 2802-.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答关于Mg2[SiO4]结构中配位多面体类型及其连接方式的问题，答案提供了详细的描述而非简单的选择或判断。 | 知识层次: 题目要求分析晶体结构中配位多面体的类型及其连接方式，这需要综合运用晶体学知识、空间想象能力和结构分析能力。不仅需要识别不同类型的配位多面体，还需要理解它们在三维空间中的连接方式（如共享边或顶点），这属于对晶体结构的深入分析和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对晶体结构中的配位多面体类型及其连接方式进行全面分析。需要综合运用晶体化学知识、空间想象能力和结构解析技巧，涉及多个配位多面体的共享方式（边共享和顶点共享）以及不同层间的相互作用。这种深度机理解释和复杂现象分析的要求，在同题型中属于最高难度等级。" + }, + { + "idx": 79, + "question": "What is the effect of forming a solid solution on the mechanical properties of materials?", + "answer": "Solid solution strengthening; the dissolution of solute atoms increases the strength and hardness of the solid solution. The strength and hardness of the solid solution are often higher than those of the constituent elements, while the plasticity is lower.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释固溶体对材料机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查固溶体对材料力学性能影响的基本概念和原理，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释固溶体对材料力学性能的影响，涉及固溶强化的基本原理和性能变化趋势的描述。虽然需要理解并表述多个相关概念（强度、硬度、塑性变化），但不需要构建复杂的理论体系或进行深入分析，属于中等难度的概念解释题。" + }, + { + "idx": 80, + "question": "What is the effect on the physical properties of materials after forming a solid solution?", + "answer": "The electrical, thermal, magnetic, and other physical properties of solid solutions also change continuously with composition, but generally not in a linear relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固体溶液对材料物理性质的影响，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求解释固溶体形成后对材料物理性质的影响，涉及多个物理性质（电、热、磁等）的变化及其与成分的非线性关系，需要综合理解和分析不同性质之间的关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求对固溶体形成后物理性质的变化进行综合分析和说明，涉及多个物理性质（电、热、磁等）的变化趋势，并指出这些变化与成分的非线性关系。虽然需要关联多个概念，但不需要进行多角度或深度关联性分析，解题步骤相对直接，符合等级3的综合分析和说明要求。" + }, + { + "idx": 81, + "question": "Explain the meaning of the symbol V_{Cl}^*", + "answer": "Chlorine ion vacancy, with a single positive charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对材料科学中缺陷符号的基本概念的记忆和理解，涉及简单的定义和符号解释，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求解释符号V_{Cl}^*的含义，即氯离子空位带一个正电荷。这属于基础概念记忆的范畴，只需直接回忆和复述定义即可，无需进行概念解释或复杂体系阐述。因此，在同题型内属于最基本的难度等级。" + }, + { + "idx": 82, + "question": "Explain the meaning of the symbol (V_{Na}'V_{Cl}^*)", + "answer": "An associated center formed by the nearest Na vacancy and Cl vacancy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释符号的含义，需要用文字进行解释和论述，答案也是以文字形式给出的解释说明，符合简答题的特征。 | 知识层次: 题目考查对缺陷化学符号的基本概念记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目要求解释一个特定的符号含义，涉及对缺陷化学中基本概念的理解和描述。虽然需要记忆和解释符号的定义，但并不需要复杂的推导或体系阐述，属于概念解释和描述的难度级别。" + }, + { + "idx": 83, + "question": "Explain the meaning of the symbol Ca_{i}^{* *}", + "answer": "Ca2+ is located at the interstitial site of the lattice", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释符号的含义，答案是通过文字解释和论述来完成的，没有涉及选择、判断或计算 | 知识层次: 题目考查对缺陷化学符号Ca_{i}^{* *}的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释符号Ca_{i}^{* *}的含义，需要理解并描述Ca2+位于晶格间隙位置这一概念。虽然涉及基础概念记忆，但需要一定的解释和描述能力，比单纯的定义简答（等级1）稍复杂，但不需要复杂的体系阐述（等级3）。" + }, + { + "idx": 84, + "question": "Explain the meaning of the symbol Ca_{K}^*", + "answer": "Ca2+ occupies the K site, with a unit positive charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目考查对材料科学中符号表示的基本概念的记忆和理解，即Ca_{K}^*的含义是Ca2+占据K位点并带有一个单位正电荷。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释一个特定的符号含义，涉及基础概念的记忆和简单描述。虽然需要理解Ca2+占据K位点并带有单位正电荷的概念，但不需要复杂的体系阐述或多步骤推理，属于概念解释和描述的难度等级。" + }, + { + "idx": 85, + "question": "Explain the meaning of the symbol Ca_{Ca}", + "answer": "Ca atom located at the Ca atom site", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，答案也是以文字形式给出，没有选项或计算要求。 | 知识层次: 题目考查基本概念的记忆和理解，即对材料科学中缺陷化学符号表示法的基本概念的记忆和简单解释。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求解释一个简单的晶体学符号（Ca_{Ca}），答案只需说明这是指位于钙原子位点上的钙原子。这属于最基础的概念记忆性知识，不需要任何扩展解释或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 86, + "question": "Explain the meaning of the symbol V_{Na}'", + "answer": "Sodium ion vacancy, with a single negative charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，答案形式为简短的文字描述而非选择、判断或计算。 | 知识层次: 题目考查对材料科学中缺陷符号的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对符号V_{Na}'进行基本定义解释，属于最基础的概念记忆性知识。题目不涉及复杂概念体系或需要多步骤推理，仅需直接回忆并表述钠离子空位的定义及其电荷状态，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 87, + "question": "Write the defect reaction equation for NaCl dissolving into CaCl2 to form a vacancy-type solid solution", + "answer": "NaCl > Naca + Cla + Va* NaC", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求写出缺陷反应方程，需要理解固溶体形成的基本原理和缺陷化学的表示方法，涉及多个概念的关联和综合分析。虽然不涉及复杂的计算，但需要将溶解过程和缺陷类型结合起来进行正确的方程表达，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求写出缺陷反应方程，这需要对固体溶液和缺陷化学有深入的理解。其次，题目涉及NaCl溶解到CaCl2中形成空位型固体溶液，这需要综合运用多个概念，包括离子置换、电荷平衡和缺陷类型等。此外，解题过程中需要考虑到离子半径、电荷补偿等复杂因素，并进行多步推导和综合分析。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 88, + "question": "Write the defect reaction equation for the formation of Schottky defects in NaCl", + "answer": "$Rsh$ $+V_{cl}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，答案形式为化学方程式而非数值计算或选择判断 | 知识层次: 题目考查Schottky缺陷的基本概念和反应方程式的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需写出肖特基缺陷的形成反应方程式，不涉及复杂概念解释或体系阐述，属于最基础的概念记忆性知识。" + }, + { + "idx": 89, + "question": "Write the defect reaction equation for the formation of a vacancy-type solid solution when CaCl2 dissolves in NaCl", + "answer": "CaCl2 > CaNa' + 2Clci + Va'", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求写出缺陷反应方程，需要理解固溶体的形成机制和缺陷化学的基本原理，并能够将这些概念关联起来进行综合分析。虽然不涉及复杂的计算或深度推理，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解缺陷反应的基本概念，掌握Kröger-Vink符号表示法，并能正确写出溶解过程中的缺陷反应方程。虽然涉及多步分析和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 90, + "question": "What are the factors affecting the formation of interstitial solid solutions?", + "answer": "Factors influencing the formation of interstitial solid solutions include: (1) Size of impurity particles: The smaller the added atoms, the easier it is to form a solid solution, and vice versa. (2) Crystal (matrix) structure: The size of ions is closely related to the crystal structure, and to a certain extent, the size of the interstitial sites plays a decisive role. Generally, the larger the voids in the crystal, the looser the structure, and the easier it is to form a solid solution. (3) Valence factor: When foreign impurity atoms enter the interstitial sites, they inevitably cause an imbalance in the valence of the crystal structure. This can be compensated by generating vacancies, partial substitution, or changes in the valence state of ions to maintain valence balance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响间隙固溶体形成的因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响间隙固溶体形成的因素，涉及多个概念（如原子尺寸、晶体结构、价态因素）的关联和综合分析，需要理解这些因素如何相互作用并影响固溶体的形成，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对影响间隙固溶体形成的因素进行多角度分析论述。需要考生不仅理解各个因素（如杂质粒子大小、晶体结构、价态因素）的具体影响，还要能够综合这些因素进行关联性分析。题目涉及的知识点较为深入，且需要考生具备将理论知识与实际材料行为相结合的能力，属于中等应用层次中较高难度的题目。" + }, + { + "idx": 91, + "question": "Write the defect reaction equation for the formation of Frenkel defects (Ag entering interstitial sites) in AgI", + "answer": "AgAg $V_{Ag}$ $+Ag_{i}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字描述和化学符号表达，属于简答题类型 | 知识层次: 题目考查缺陷反应方程的基本概念记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题中属于中等难度，需要理解Frenkel缺陷的概念并正确写出缺陷反应方程，但不需要复杂的解释或阐述多个概念体系。" + }, + { + "idx": 92, + "question": "If the partial pressure of surrounding oxygen is increased, how will the density of the non-stoichiometric compound Fe1-xO change? Increase or decrease? Why?", + "answer": "202(g) 0o+Vre’ +2h* k=[O][Vr’’][h']/PO21/2=4[00][Vr’′]3/PO1/2 [Vre′′]PO²1/6, PO[Vr]↓", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物Fe1-xO的密度如何随氧分压变化，并说明原因。答案涉及化学反应平衡和缺陷浓度的理论解释，需要文字论述而非简单选择或计算。 | 知识层次: 题目需要综合运用非化学计量化合物缺陷化学的知识，分析氧分压变化对Fe1-xO中缺陷浓度的影响，并推导密度变化趋势。涉及缺陷反应平衡、质量作用定律的应用以及缺陷浓度与密度的关联，需要较深的推理分析和机理解释能力。 | 难度: 在简答题题型中，该题目属于复杂分析层次，需要综合运用非化学计量比化合物、缺陷化学、质量作用定律等多个高阶概念。解题过程涉及建立缺陷平衡方程、推导浓度关系、分析氧分压对缺陷浓度的影响机制等复杂推理步骤。题目不仅要求掌握基础概念，还需要进行多步骤的数学推导和机理解释，属于该题型框架内对综合能力要求最高的复杂现象全面分析级别。" + }, + { + "idx": 93, + "question": "Both MgO (NaCl-type structure) and Li2O (anti-fluorite-type structure) are based on the cubic close packing of oxygen, and the cations are in the gaps of this arrangement. Why are Frenkel-type point defects the main defects in Li2O?", + "answer": "Li occupies octahedral voids. The octahedral voids are larger, making it easier for Li ions to move from their normal lattice sites to interstitial positions, forming Frenkel defects (simultaneous presence of cation vacancies and interstitial cations).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Li2O中Frenkel型点缺陷是主要缺陷，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释Frenkel型点缺陷在Li2O中为主要缺陷的原因，涉及晶体结构、间隙位置、离子迁移等概念的关联和综合分析，需要深入理解晶体缺陷形成的机理并进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目属于机理深度解释难度。题目要求考生不仅要理解MgO和Li2O的晶体结构差异，还需要从离子尺寸和间隙位置的角度分析Frenkel缺陷的形成机制。这需要综合运用晶体结构知识、缺陷化学原理和空间位阻分析能力，解题过程涉及多个推理步骤和机理解释，但尚未达到需要全面分析复杂现象的最高难度等级。" + }, + { + "idx": 94, + "question": "The density of MgO is $3.58\\\\mathrm{g/cm^{3}}$, and its lattice parameter is $0.42\\\\mathrm{nm}$. Calculate the number of Schottky defects per unit cell of MgO.", + "answer": "Let the number of molecules per unit cell of defective $\\\\mathrm{MgO}$ be ${\\\\bf X}$, the unit cell volume $\\\\mathrm{V}{=}$ (4.20)°, $\\\\scriptstyle{\\\\mathbf{x}}={\\\\mathbf{p}}$ VNO/M=3.96. The number of Schottky defects per unit cell $:=4-\\\\tt X=0.04$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解MgO中每个晶胞的肖特基缺陷数量，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括密度、晶格参数和肖特基缺陷的计算，涉及综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要掌握密度、晶格参数和Schottky缺陷的概念，并进行多步计算和综合分析。虽然计算步骤相对明确，但需要将多个概念关联起来，并正确应用公式，因此在该题型内属于中等偏上难度。" + }, + { + "idx": 95, + "question": "The Schottky defect formation energy of Mg0 crystal is 84 kJ/mol. Calculate the defect concentration of this crystal at 1000K and 1500K.", + "answer": "$\\\\mathrm{n}/\\\\mathrm{N}{=}\\\\mathrm{exp}$ (-E/2RT), $\\\\mathrm{R}{=}8.314$, $\\\\mathrm{T}{=}1000\\\\mathrm{k}$ :n/N=6. $4\\\\times{10}^{-3}$ $\\\\mathrm{T}=1500\\\\mathrm{k}$ $\\\\mathrm{n}/\\\\mathrm{N}{=}3.5\\\\times{10}^{-2}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及Schottky缺陷浓度的计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用Schottky缺陷浓度公式进行数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需套用给定的Schottky缺陷浓度公式进行简单数值计算，无需组合多个公式或进行复杂推导。" + }, + { + "idx": 96, + "question": "In the non-stoichiometric compound Fe_xO, Fe^{3+}/Fe^{2+}=0.1. Find the vacancy concentration in Fe_xO.", + "answer": "Fe2O3 →2FeFe +3O0+V_Fe. Let y be the concentration of Fe^{3+}, then 2y =0.1→2y=0.1-0.3y→y=0.1/2.3=0.0435. The vacancy concentration [V_Fe''] = y = 0.0435.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非化学计量化合物Fe_xO中的空位浓度，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及非化学计量化合物Fe_xO中Fe^{3+}/Fe^{2+}比值的计算，需要理解缺陷化学的基本原理，并应用缺陷反应方程进行多步计算。虽然不涉及复杂的机理分析或创新设计，但需要综合分析缺陷浓度与离子价态之间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解非化学计量化合物的概念，应用电荷平衡原理，并进行多步计算。虽然涉及多个步骤和概念关联，但整体计算过程相对直接，没有引入复杂多变量或高级数学工具。" + }, + { + "idx": 97, + "question": "In the non-stoichiometric compound Fe_xO, Fe^{3+}/Fe^{2+}=0.1, find the value of x in Fe_xO.", + "answer": "Let y be the concentration of Fe^{3+}, y=0.0435. x=1-y=1-0.0435=0.9565, thus the chemical formula is Fe_0.9565O.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解非化学计量化合物Fe_xO中的x值，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要进行多步计算，涉及非化学计量化合物的概念和离子价态比例的转换，需要综合分析Fe^{3+}和Fe^{2+}的比例关系，并通过计算得出x的值。这超出了简单应用的范围，但尚未达到需要复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要理解非化学计量化合物的概念，进行多步计算和电荷平衡分析，涉及Fe^{3+}和Fe^{2+}的比例关系，并最终推导出x的值。虽然计算步骤明确，但需要综合应用多个化学概念和数学技巧。" + }, + { + "idx": 98, + "question": "For edge dislocations, what are the characteristics of the dislocation line direction, Burgers vector, and dislocation motion direction?", + "answer": "Edge dislocation: the dislocation line is perpendicular to the Burgers vector, and the dislocation line is perpendicular to the direction of dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释刃位错的特征，包括位错线方向、伯格斯矢量和位错运动方向之间的关系，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对刃位错基本特征（位错线方向、伯氏矢量、运动方向）的记忆和理解，属于基础概念层面的知识。 | 难度: 在简答题中属于概念解释和描述难度，需要理解并描述边缘位错的位错线方向、伯氏矢量及位错运动方向之间的关系，但不需要进行复杂的概念体系阐述或深入分析。" + }, + { + "idx": 99, + "question": "When two edge dislocations with the same sign meet on the same slip plane, will they repel or attract each other?", + "answer": "Repel, tensile stress overlaps, compressive stress overlaps.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两个同号刃位错在同一滑移面上相遇时的相互作用机制，答案需要文字论述其排斥原因（拉伸应力重叠和压缩应力重叠），而不是简单的选择或判断。 | 知识层次: 题目考查对位错相互作用的理解和应用，需要分析两个同号刃位错在同一滑移面上相遇时的应力场叠加效应，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解位错相互作用的基本原理，并能解释应力场的重叠效应。虽然涉及多步概念关联，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 100, + "question": "For screw dislocations, what are the characteristics of the dislocation line direction, Burgers vector, and dislocation motion direction?", + "answer": "Screw dislocation: the dislocation line is parallel to the Burgers vector, and the dislocation line is parallel to the direction of dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和描述螺位错的特征，包括位错线方向、Burgers矢量和位错运动方向之间的关系。答案提供了详细的文字解释，符合简答题的特点。 | 知识层次: 题目考查对螺型位错基本特征（位错线方向、伯氏矢量、运动方向）的记忆和理解，属于基础概念记忆范畴 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答螺型位错的基本特征，包括位错线方向、柏氏矢量和位错运动方向之间的关系。这些内容属于基础概念记忆层次，只需直接回忆和复述定义即可，不需要进行概念解释或复杂体系阐述。在同类简答题中属于最基础的难度级别。" + }, + { + "idx": 101, + "question": "Both MgO (NaCl-type structure) and Li2O (anti-fluorite-type structure) are based on the cubic close packing of oxygen, and the cations are located in the interstitial sites of this arrangement. Why are Schottky defects the predominant point defects in MgO?", + "answer": "Mg occupies the tetrahedral sites. The tetrahedral sites are relatively small, making it difficult for Mg ions to migrate within the lattice to form Frenkel defects. Therefore, they are more inclined to form Schottky defects (paired cation and anion vacancies).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么MgO中Schottky缺陷是主要的点缺陷，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要综合运用晶体结构、缺陷类型和离子迁移等知识，进行推理分析以解释Schottky缺陷在MgO中占主导的原因。这涉及到对晶体结构中位点大小、离子迁移难度以及缺陷形成倾向的深入理解，属于较高层次的认知能力要求。 | 难度: 在简答题的复杂分析题型中，该题目要求对MgO和Li2O的晶体结构有深入理解，并能解释为什么在MgO中Schottky缺陷是主要的点缺陷。这需要综合运用晶体结构知识、缺陷形成机理以及离子迁移的难易程度等多方面因素进行推理分析。虽然题目提供了部分背景信息，但解答需要机理深度解释，属于该题型中较高难度的题目。" + }, + { + "idx": 102, + "question": "If the partial pressure of surrounding oxygen is increased, how will the density of the non-stoichiometric compound Zn1+xO change? Increase or decrease? Why?", + "answer": "Zn (g) →Zni· +e Zn (g) +1/2O2=ZnO Zn:+e’+1/2O→ZnO [ZnO]=[e'] PO2↑,[Zni]↓", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物Zn1+xO的密度如何随氧分压变化，并说明原因。答案提供了化学反应方程式和文字解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要综合运用非化学计量比化合物的知识，理解氧分压变化对缺陷浓度的影响机制，并分析缺陷反应平衡的移动方向。涉及缺陷化学、质量作用定律等概念的关联应用，需要推理分析和机理解释能力。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用非化学计量化合物、缺陷化学、质量作用定律等多个高阶概念，并建立氧分压与缺陷浓度之间的定量关系。解题需要完整推导缺陷反应方程式、分析电子浓度变化对整体密度的影响机制，属于该题型内对机理深度和综合分析能力要求最高的复杂现象全面分析层级。" + }, + { + "idx": 103, + "question": "What effect will grain boundaries have on the movement of dislocations? Can it be predicted?", + "answer": "Grain boundaries hinder the movement of dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶界对位错运动的影响，并讨论是否可以预测这种影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目不仅需要理解晶界对位错运动的基本影响（基础概念），还需要能够预测这种影响，涉及概念关联和综合分析。虽然不涉及复杂计算，但需要对材料科学中的位错理论和晶界特性有一定的理解和应用能力。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释和论述，但主要考察的是对单一概念（晶界对位错运动的影响）的理解和应用，不需要进行多角度或深度关联性分析。解题步骤相对直接，只需明确阐述晶界对位错的阻碍作用即可，不需要复杂的综合分析或多步推理。" + }, + { + "idx": 104, + "question": "Grain boundaries can be divided into small-angle grain boundaries and large-angle grain boundaries. Can large-angle grain boundaries be described by arrays of dislocations?", + "answer": "No, in large-angle grain boundaries, the atomic arrangement is close to a disordered state, and the distance between dislocations may only be 1 or 2 atoms in size, which is not applicable to large-angle grain boundaries.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（\"Can large-angle grain boundaries be described by arrays of dislocations?\"），并且答案明确给出了\"否\"的判断和解释。这符合判断题的特征。 | 知识层次: 题目考查对晶界分类和位错描述的基本概念的理解，属于基础概念记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解晶界分类的基本概念，并能区分小角度晶界和大角度晶界的特征差异。虽然题目涉及的是基础概念记忆，但需要考生对两种晶界的原子排列状态和位错描述适用性有较深入的理解，而非简单的定义正误判断。" + }, + { + "idx": 105, + "question": "Taking the dissolution of solute A0 in solvent B2O3 as an example, compare the chemical compositions of solid solutions, compounds, and mechanical mixtures.", + "answer": "
Comparison itemSolid solutionCompoundMechanical mixture
Chemical compositionB2xAxO X （x=0~2）AB2O4AO+B2O3
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较固体溶液、化合物和机械混合物的化学成分，答案以表格形式呈现了详细的比较内容，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较固溶体、化合物和机械混合物的化学组成，这需要理解这些概念的定义和特点，并能够进行综合分析。虽然涉及基础概念，但需要将这些概念关联起来进行比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对固体溶液、化合物和机械混合物的化学组成进行多角度比较分析，需要综合运用多个概念并进行详细论述。虽然不涉及深度关联性分析，但解题步骤较为复杂，要求考生具备较强的综合分析能力，因此属于该题型内的较高难度等级。" + }, + { + "idx": 106, + "question": "From the perspective of chemical composition and phase composition, compare the differences between solid solutions and mechanical mixtures.", + "answer": "
Solid solutionMechanical mixture
Formation reasonFormed by atomic-scale 'dissolution'Powder mixing
Number of phasesUniform single phaseMultiphase
Chemical compositionUncertainAs many chemical compositions as there are mixtures
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从化学组成和相组成的角度比较固溶体和机械混合物的差异，需要文字解释和论述。答案以表格形式呈现了两种材料的对比特征，属于简答题的解答方式。 | 知识层次: 题目要求从化学成分和相组成的角度比较固溶体和机械混合物的差异，涉及多个概念的关联和综合分析，需要理解并应用相关原理进行对比，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求从化学组成和相组成两个角度对固溶体和机械混合物进行比较分析。这需要学生不仅掌握两者的基本概念，还需要理解它们在微观结构和宏观性质上的差异，并能进行多角度的论述。虽然不涉及复杂的计算，但需要综合运用材料科学的知识进行清晰的对比和解释，属于中等应用层次中较为复杂的题目。" + }, + { + "idx": 107, + "question": "Explain the similarities between solid solutions, lattice defects, and non-stoichiometric compounds", + "answer": "Solid solutions, lattice defects, and non-stoichiometric compounds are all point defects, which are crystal structure defects, and they are single-phase homogeneous solids with structures identical to the host crystal phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的相似性，需要文字解释和论述，属于简答题类型。 | 知识层次: 题目主要考查对固体溶液、晶格缺陷和非化学计量化合物这些基本概念的理解和记忆，需要解释它们之间的相似性，属于基础概念的记忆和简单关联，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释和描述三个相关概念（固溶体、晶格缺陷和非化学计量化合物）的相似性，属于概念解释和描述的难度等级。虽然需要理解多个概念，但不需要进行复杂的体系阐述或深入分析，因此属于中等难度。" + }, + { + "idx": 108, + "question": "Explain the differences between solid solutions, lattice defects, and non-stoichiometric compounds", + "answer": "Thermal defects - intrinsic defects; solid solutions - extrinsic defects; non-stoichiometric compounds - caused by changes in environmental atmosphere properties and pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的区别，需要文字解释和论述，而不是选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的区别，这需要理解并关联多个概念，进行综合分析。虽然不涉及复杂计算，但需要对材料科学中的缺陷类型及其形成原因有较深入的理解，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对固体溶液、晶格缺陷和非化学计量化合物这三个相关但不同的概念进行区分和解释。需要考生不仅理解每个概念的定义，还要能够分析它们之间的相互关系以及形成原因。这涉及到多角度的分析论述，包括内在缺陷、外在缺陷以及环境因素的影响。虽然不需要进行深度关联性分析（如等级5所要求的），但已经超出了简单的概念解释（等级3），因此属于等级4难度。" + }, + { + "idx": 109, + "question": "Al2O3 forms a limited solid solution in MgO, with approximately 18wt% Al2O3 dissolved in MgO at the eutectic temperature of 1995℃, assuming the unit cell size change of MgO is negligible. Estimate the density change when Al3+ acts as a substitutional ion.", + "answer": "The defect reaction is: Al2O3→MgO 2Al•Mg + 3O×o + V''Mg. Taking 100g of sample as the basis: mAl2O3 = 18/102 = 0.176 mol, mMgO = 82/40.3 = 2.035 mol. The molecular formula after solid solution is Mg2.035Al0.352O2.563. The density change is ρ/ρMgO = (0.176×102 + 2.035×40.3)/(2.563×40.3) = 0.968. The density after solid solution is less than that before solid solution.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及固溶体密度变化的估算，解答过程中使用了摩尔计算和密度公式，属于典型的计算题类型。 | 知识层次: 题目涉及多步计算和概念关联，需要理解缺陷反应、摩尔计算和密度变化的关系，并进行综合分析。虽然不涉及复杂的机理解释或创新应用，但需要一定的思维深度和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解缺陷反应、摩尔计算、分子式推导和密度计算等多个步骤，并进行综合分析。虽然计算过程较为复杂，但题目提供了明确的假设条件和基础数据，降低了部分难度。" + }, + { + "idx": 110, + "question": "In MgO-Al2O3 and PbTiO3-PbZrO3, which pair forms a limited solid solution, and why?", + "answer": "MgO-Al2O3 forms a limited solid solution because the ionic radii of Mg2+ and Al3+ differ significantly, and the crystal structure types of MgO (NaCl-type structure) and Al2O3 (corundum-type structure) are quite different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么某一对材料形成有限固溶体，需要文字解释和论述，而不是从选项中选择或判断对错。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析两种材料体系中哪种形成有限固溶体，并解释原因。这需要理解离子半径差异和晶体结构类型对固溶体形成的影响，涉及多个概念的关联和综合分析，属于复杂分析层次。 | 难度: 在简答题中属于机理深度解释难度等级。该题目要求考生不仅掌握MgO-Al2O3和PbTiO3-PbZrO3两种体系的特性，还需要分析离子半径差异和晶体结构类型对固溶体形成的影响。解题过程需要综合运用材料科学知识进行推理分析，解释为什么其中一对形成有限固溶体。虽然不涉及多体系比较或复杂计算，但对机理的解释深度要求较高，属于简答题中较难的题目。" + }, + { + "idx": 111, + "question": "For MgO, Al2O3, and Cr2O3, the cation-anion radius ratios are 0.47, 0.36, and 0.40 respectively. Is the solid solubility in the MgO-Cr2O3 system expected to be limited or unlimited? Why?", + "answer": "The solid solubility between MgO and Cr2O3 is limited. Reason: different structure types, MgO has a NaCl-type structure while Cr2O3 has a corundum structure. Although (0.47-0.40)/0.47=14.89%<15%, continuous solid solution still cannot be formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么MgO-Cr2O3系统的固溶度是有限的，需要文字论述和解释，而不是简单的选择、判断或计算。答案提供了详细的解释和结构差异的分析，符合简答题的特征。 | 知识层次: 题目需要理解并应用离子半径比与晶体结构类型的关系，进行综合分析判断固溶体的溶解度限制。虽然涉及基础概念，但需要将多个知识点（离子半径比、晶体结构类型、固溶体形成条件）关联起来进行推理分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用多个知识点（包括晶体结构类型、半径比计算、固溶体形成条件等）进行分析和论述。题目不仅要求计算半径比差异（14.89%），还需要结合晶体结构差异（NaCl型 vs 刚玉型）进行综合判断，并解释为何即使半径比差异小于15%仍不能形成连续固溶体。这种多角度分析论述的要求在简答题中属于较复杂的题型。" + }, + { + "idx": 113, + "question": "A certain NiO is non-stoichiometric. If the ratio of $\\\\mathrm{Ni^{3+}/Ni^{2+}}$ in NiO is $10^{-4}$, how many charge carriers are there per $\\\\mathrm{m}^{3}$?", + "answer": "Let the non-stoichiometric compound be $\\\\mathrm{Ni_{1}O}$. The reaction is: $Ni_{2}O_{3}\\\\xrightarrow{2\\\\sqrt{6}O}2^{1\\\\sqrt{1}i_{2}}Ni_{3}O_{0}+\\\\mathrm{V_{Ni}^{''}}$. The ratio $\\\\mathrm{Ni^{3+}/Ni^{2+}}=2y/(1-3y)=10^{-4}$. Solving gives $y=5\\\\times10^{-5}$, $x=1-y=0.99995$, leading to Ni$_{0.99995}$O. The number of charge carriers per $\\\\mathrm{m}^{3}$ is equal to the vacancy concentration: $[\\\\mathrm{V_{Ni}^{''}}]=y/\\\\Omega(1+x)=2.5\\\\times10^{-5}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程中涉及化学反应平衡、比例计算和浓度推导，最终得出具体的数值结果。 | 知识层次: 题目涉及非化学计量比化合物的计算，需要理解缺陷反应方程、电荷平衡关系，并进行多步计算和综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解非化学计量比的概念，建立正确的反应方程式，进行多步数学推导和计算，并最终将结果转化为实际物理量（电荷载流子浓度）。虽然计算过程不涉及复杂变量，但需要较强的概念关联和综合分析能力。" + }, + { + "idx": 114, + "question": "Explain why only substitutional solid solutions can achieve complete mutual solubility between the two components, while interstitial solid solutions cannot.", + "answer": "(1) The interstitial sites in a crystal are limited, with an impurity accommodation capacity of $\\zeta10\\%$; (2) The formation of interstitial solid solutions generally increases the lattice constant, and when this increase reaches a certain extent, the lattice becomes unstable and dissociates; substitutional solid solutions are formed by the exchange of positions between ions of the same type, which does not affect the bonding, thus allowing the formation of continuous solid solutions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么只有置换型固溶体可以实现两种组分的完全互溶，而间隙型固溶体不能。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释置换型固溶体和间隙型固溶体在完全互溶方面的差异，涉及晶体结构、固溶体形成机制、晶格稳定性等多个知识点的综合运用和深入分析。需要理解两种固溶体的本质区别，并能从晶体结构和热力学角度进行推理和解释，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对两种固溶体（置换式和间隙式）的溶解度差异进行机理深度解释。需要综合运用晶体结构、固溶体形成条件、晶格稳定性等多方面知识，并推理分析不同固溶机制对溶解度的影响。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述层面，属于需要深入理解材料科学原理的机理解释题。" + }, + { + "idx": 115, + "question": "For MgO, Al2O3, and Cr2O3, the radius ratios of cations to anions are 0.47, 0.36, and 0.40, respectively. Is it possible for Al2O3 and Cr2O3 to form continuous solid solutions? Why?", + "answer": "Al2O3 and Cr2O3 can form continuous solid solutions, because: 1) They have the same crystal structure type, both belonging to the corundum structure. 2) (0.40-0.36)/0.40=10%<15%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al2O3和Cr2O3是否能形成连续固溶体，并给出原因。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解固溶体形成的条件（晶体结构相同和半径比差异），并进行简单的计算（半径比差异百分比），属于多步计算和概念关联的综合应用。 | 难度: 在简答题题型中，该题目属于较高难度，要求考生不仅掌握晶体结构类型和半径比的概念，还需要进行多步计算（半径比差异百分比计算）和综合分析（判断固溶体形成的条件）。此外，题目还要求考生能够将理论知识与具体材料案例（Al2O3和Cr2O3）相结合，进行多角度的分析论述。这些要求使得该题目在简答题题型中处于较高难度水平。" + }, + { + "idx": 116, + "question": "List a concise table comparing solid solutions, lattice defects, and non-stoichiometric compounds", + "answer": "
ClassificationFormation reasonFormation conditionDefect reactionChemical formulaSolubility, defect concentration
Thermal defectSchottky FrenkelThermal fluctuationT>OkVM M+Vx 0MX MXOnly controlled by temperature
M>M+V
Solid solutionInfinite, finite, substitution, interstitialImpurity dissolutionSize, electronegativity, valence, structureNone: controlled by temperature With: impurity amount < solubility limit controlled by temperature impurity amount > solubility limit controlled by solubility limit
Non-stoichiometric compoundCation vacancy anion interstitial cation interstitial anion vacancyChanges in environmental atmosphere nature and pressureFe1x0 UO2x Zn1x0 TiO2-x[h'] pl16 8 20 [Zni]oPo P-1/6
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列出并比较固体溶液、晶格缺陷和非化学计量化合物的表格，需要文字解释和论述，答案以表格形式呈现，属于简答题类型。 | 知识层次: 题目要求对固体溶液、晶格缺陷和非化学计量化合物进行比较，需要综合多个概念并进行分类和关联分析。虽然涉及基础概念的记忆，但更强调对不同类型缺陷和化合物的理解和比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对固体溶液、晶格缺陷和非化学计量化合物进行多角度比较分析，涉及多个概念的综合运用和详细解释。需要考生不仅理解各个概念的定义和形成原因，还需要掌握它们之间的关联性和区别，并能用表格形式清晰呈现。此外，题目还要求考生能够解释缺陷反应和化学公式，以及溶解度或缺陷浓度的控制因素，这增加了题目的复杂性和深度。因此，在简答题题型中，该题目属于较高难度等级，需要考生具备较强的综合分析能力和知识应用能力。" + }, + { + "idx": 118, + "question": "Chemical analysis of pyrite yields two possible compositions based on the Fe/S ratio from the analytical data: Fe1-xS and FeS1-x. The former implies a defect structure with Fe vacancies, while the latter indicates Fe substitution. How can experimental methods determine whether the mineral belongs to Fe1-xS (Fe vacancy defect structure)?", + "answer": "Fe1-xS contains Fe vacancies and is a non-stoichiometric compound, exhibiting h'P-type semiconductor properties. By measuring its semiconductor characteristics, if the results show h'P-type semiconductor behavior, it can be confirmed that the mineral composition is Fe1-xS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过实验方法确定矿物属于Fe1-xS（Fe空位缺陷结构），并需要解释如何通过测量半导体特性来确认。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求通过实验方法确定矿物属于Fe1-xS（Fe空位缺陷结构），需要综合运用半导体特性测量和缺陷结构分析的知识，涉及多步骤的推理和综合分析，以及对非化学计量化合物和半导体行为的深入理解。 | 难度: 在简答题-复杂分析题型中，该题目要求对非化学计量化合物的缺陷结构进行机理深度解释，并需要通过半导体特性测试来验证特定缺陷类型。这需要综合运用材料表征方法和半导体物理知识，涉及多个知识点的深度整合和推理分析，符合等级4\"机理深度解释\"的标准。虽然题目提供了明确的判断依据（h'P型半导体特性），但完整解答需要展示对缺陷结构与性能关系的深刻理解，难度高于基础分析题但尚未达到需要多维度全面分析的等级5水平。" + }, + { + "idx": 119, + "question": "In MgO-Al2O3 and PbTiO3-PbZrO3, which pair forms an infinite solid solution, and why?", + "answer": "PbTiO3-PbZrO3 forms an infinite solid solution. Although the ionic radii of Ti4+ and Zr4+ differ significantly (approximately 15.28%), they both possess the ABO3 perovskite-type structure, and both Ti4+ and Zr4+ occupy the octahedral voids. These voids are relatively large, allowing the radii of the inserted cations to vary within a certain range without causing structural changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么某一对材料形成无限固溶体，需要文字解释和论述，而不是从选项中选择或简单判断对错。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析两种材料体系中哪种能形成无限固溶体，并解释原因。这需要理解固溶体的形成条件、离子半径差异的影响、晶体结构类型以及阳离子在晶格中的占位情况。涉及多个概念的关联和综合分析，以及对结构-性能关系的深入理解，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求不仅识别出形成无限固溶体的物质对，还需要深入解释其背后的结构机理和容忍因素（如八面体空隙的尺寸适应性）。这需要综合运用晶体结构知识、离子半径比较以及固溶体形成条件的理解，属于该题型内对知识整合和机理解释要求最高的类型。" + }, + { + "idx": 121, + "question": "Use experimental methods to identify SiO2 glass", + "answer": "Use X-ray detection. SiO2 glass - isotropic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过实验方法识别SiO2玻璃，答案给出了具体的实验方法(X-ray detection)和判断依据(isotropic)，属于需要文字解释和论述的简答题形式。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别SiO2玻璃，并解释其各向同性特性。这涉及基本的实验技术应用和简单概念解释，不需要复杂的分析或综合推理。 | 难度: 在简答题中属于简单应用过程描述，只需要直接套用X射线检测方法并说明SiO2玻璃的各向同性特征，无需深入解释或详细步骤分析。" + }, + { + "idx": 122, + "question": "Use experimental methods to identify crystalline SiO2", + "answer": "Use X-ray detection. Crystalline SiO2—particles are arranged regularly in three-dimensional space, exhibiting anisotropy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求使用实验方法识别晶体SiO2，答案给出了具体的实验方法（X-ray detection）和解释（晶体SiO2的三维规则排列和各向异性），这属于需要文字解释和论述的简答题形式。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别晶体SiO2，并解释其晶体结构特征。这涉及基本的实验方法应用和晶体学基本概念的直接应用，不需要复杂的分析或多步骤推理。 | 难度: 在简答题题型中，该题目属于应用方法说明的难度等级。题目要求使用实验方法识别晶体SiO2，并给出了X射线检测的答案。虽然需要解释晶体SiO2的特性（如三维空间中的规则排列和各向异性），但整体上属于直接应用实验方法的范畴，没有涉及复杂的推导或深入的分析。因此，在简答题题型中属于中等难度。" + }, + { + "idx": 123, + "question": "What are the characteristics of the polymer structure of silicate melts?", + "answer": "The characteristics of the polymer structure of silicate melts include: being composed of silicon-oxygen tetrahedra as the basic units forming polymers of varying sizes; undergoing three stages during formation: differentiation, polycondensation, and equilibrium; accompanying deformation during polycondensation, where chain polymers undergo rotation and bending, layered polymers experience wrinkling and warping, and framework polymers exhibit increased thermal defects with changes in the Si-O-Si bond angle; ultimately reaching an equilibrium state of polymerization and depolymerization under the influence of time and temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述硅酸盐熔体聚合物结构的特征，答案提供了详细的文字描述和解释，符合简答题的特点。 | 知识层次: 题目要求解释硅酸盐熔体聚合物结构的特点，涉及多个阶段的形成过程、变形机制以及平衡状态的描述，需要综合运用知识进行推理分析和机理解释，思维过程深度要求较高。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析硅酸盐熔体聚合物结构的多个特征，包括基本组成单元、形成过程的三个阶段、聚合过程中的变形机制以及最终平衡状态。这需要综合运用材料科学、化学和热力学知识，进行深入的推理和机理解释，属于该题型下的最高难度等级。" + }, + { + "idx": 124, + "question": "Use experimental methods to identify SiO2 melt", + "answer": "Use X-ray detection. SiO2 melt—internal structure is framework-like, short-range ordered, long-range disordered.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求使用实验方法识别SiO2熔体，并给出了具体的实验方法和解释，这需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别SiO2熔体的结构特征，涉及实验技术的选择和结构特征的描述。这需要将实验方法与材料结构特性关联起来，属于多步骤的综合分析，但不需要复杂的推理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解SiO2熔体的结构特征，并选择合适的实验方法进行验证。题目要求考生综合运用X射线检测的知识，分析熔体的短程有序和长程无序结构，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 125, + "question": "Use experimental methods to identify silica gel", + "answer": "Use X-ray detection. Silica gel—loose and porous.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用实验方法识别硅胶，答案提供了具体的实验方法（X射线检测）和硅胶的特性描述（松散多孔），属于需要文字解释和论述的简答题形式。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别硅胶，这属于基本实验技术的直接应用，不需要复杂的分析或多步骤推理。答案中提到的硅胶特性（松散和多孔）也是基础知识的简单应用。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求使用实验方法识别硅胶，答案直接给出了X射线检测的方法，并简单描述了硅胶的特性（松散多孔）。解题步骤简单，只需直接套用基本实验方法，无需深入解释或详细论述。因此，在该题型内属于较低难度等级。" + }, + { + "idx": 126, + "question": "Describe the structural and property characteristics of quartz melt", + "answer": "
StructureFramework structure, long-range disorder
PropertiesHigh viscosity, large surface tension
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述石英熔体的结构和性质特征，答案以表格形式提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对石英熔体结构和性质的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求描述石英熔体的结构和性能特征，属于概念解释和描述的难度等级。虽然需要记忆和解释多个特征（如框架结构、长程无序、高粘度、大表面张力等），但不需要进行复杂的体系阐述或深入分析，因此属于等级2。" + }, + { + "idx": 127, + "question": "What are the factors affecting the viscosity of the melt?", + "answer": "The main factors affecting the viscosity of the melt: temperature and the composition of the melt. The increase in the content of alkaline oxides drastically reduces the viscosity. As the temperature decreases, the viscosity of the melt increases exponentially.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响熔体粘度的因素，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对熔体粘度影响因素的基础概念记忆和理解，主要涉及温度和成分对粘度的影响，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答影响熔体粘度的主要因素，并简要解释温度和熔体成分对粘度的影响。虽然需要记忆和解释两个主要因素及其影响方式，但不需要深入分析或阐述复杂的相互作用机制，因此属于中等难度。" + }, + { + "idx": 128, + "question": "What is the process of polymer structure formation in silicate melts?", + "answer": "The formation of polymers is based on the silicon-oxygen tetrahedron as the fundamental unit, forming aggregates of varying sizes. It can be divided into three stages: Initial stage: The breakdown of quartz, where the framework [Si0_{4}] fractures, forming polymers of varying degrees of polymerization in the melt. Middle stage: Polycondensation accompanied by deformation—linear polymers tend to rotate around the Si-O axis while bending, layered polymers cause the layers themselves to wrinkle and warp, framework polymers exhibit increased thermal defects, and the Si-O-Si bond angles change. [Si0_{4}]Na_{4} + [Si_{2}0_{7}]Na_{6} → [Si_{3}0_{10}]Na_{8} + Na_{2}O (short bond) 3[Si_{3}0_{10}]Na_{8} → [Si_{6}0_{18}]Na_{12} + 2Na_{2}O (six-membered ring). Final stage: Within a certain time and temperature range, polymerization and depolymerization reach equilibrium. The Na_{2}O released by polycondensation can further erode the quartz framework, breaking it down into oligomers, and this cycle continues until the system reaches a breakdown-polycondensation equilibrium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物在硅酸盐熔体中的结构形成过程，答案提供了详细的文字描述和分阶段的论述，符合简答题的特征。 | 知识层次: 题目涉及聚合物结构形成的详细过程，包括多个阶段的化学反应和平衡状态，需要综合运用材料科学和化学知识进行推理分析，解释机理。这超出了简单记忆或基础应用的范畴，属于对复杂过程的深入理解和分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对聚合物结构形成的全过程进行详细解释，涉及多个阶段的化学反应和平衡状态。需要综合运用硅酸盐化学、聚合机理和热力学平衡等知识，进行深入的推理分析和机理解释。题目不仅要求描述现象，还需解释背后的化学原理和动态平衡过程，属于该题型内最高难度的复杂现象全面分析。" + }, + { + "idx": 129, + "question": "Analyze the reason why monovalent alkali metal oxides reduce the viscosity of silicate melts.", + "answer": "Generally, alkali metal oxides (Li2O, Na2O, K2O, Rb2O, Cs2O) can reduce melt viscosity. These cations, due to their small charge, large radius, and weak interaction with O2-, provide 'free oxygen' in the system, increasing the O/Si ratio. This causes the original silicon-oxygen anion groups to depolymerize into simpler structural units, thereby reducing the activation energy and decreasing viscosity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析碱金属氧化物降低硅酸盐熔体粘度的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析单价碱金属氧化物降低硅酸盐熔体粘度的原因，涉及对离子特性（电荷、半径）、与氧离子的相互作用、硅氧阴离子团的解聚以及活化能变化等多方面因素的综合理解和机理分析。这需要较高的认知能力层次，包括应用、分析和综合，以及对材料科学中熔体结构和性质之间关系的深入理解。 | 难度: 在简答题-复杂分析题型中，该题目要求对碱金属氧化物降低硅酸盐熔体粘度的机理进行深度解释。需要综合运用化学键理论、熔体结构知识和动力学原理，分析阳离子特性如何影响硅氧网络结构，并推导出粘度变化的机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但需要建立完整的因果链条和结构-性能关系解释，符合等级4的机理深度解释要求。" + }, + { + "idx": 130, + "question": "Describe the structural and property characteristics of quartz crystals", + "answer": "
StructureRegular ordered arrangement, long-range order
Properties
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述石英晶体的结构和性质特征，需要文字解释和论述，答案以表格形式呈现了结构和性质的特点，符合简答题的特征。 | 知识层次: 题目要求描述石英晶体的结构和性质特征，这属于对基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求对石英晶体的结构和性质特征进行描述，属于概念解释和描述的难度等级。虽然需要记忆基本的结构特征（如规则有序排列、长程有序）和性质特征，但不需要进行复杂的体系阐述或多概念综合分析，因此属于中等难度。" + }, + { + "idx": 131, + "question": "The above data were obtained under constant pressure. If obtained under constant volume, do you think the activation energy would change? Why?", + "answer": "If obtained under constant volume, the activation energy would not change. Because activation energy is the energy required for liquid particles to undergo linear motion. It is related to the melt composition and the degree of [Si04] polymerization in the melt.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么在恒容条件下活化能不会改变，需要文字解释和论述，而不是简单的选择或判断。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目需要理解活化能的概念，并将其与实验条件（恒压与恒容）联系起来进行分析。虽然不涉及复杂的计算或多步骤推理，但需要对活化能的本质及其影响因素有一定的理解，并能够解释为什么实验条件的变化不会影响活化能。这属于中等应用层次，涉及概念关联和一定的综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及激活能的概念，但只需要进行单一维度的分析（恒压与恒容条件下的比较），不需要多角度或深度关联性分析。解题步骤相对直接，主要考察对激活能本质的理解和简单应用能力，符合等级3\"综合分析和说明\"的标准。" + }, + { + "idx": 132, + "question": "What are the structural differences between crystalline SiO2, SiO2 glass, silica gel, and SiO2 melt?", + "answer": "Crystalline SiO2—particles are arranged regularly in three-dimensional space, exhibiting anisotropy; SiO2 glass—isotropic; silica gel—loose and porous; SiO2 melt—internal structure is framework-like, with short-range order and long-range disorder.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同形态SiO2的结构差异，答案以文字描述为主，没有选项、计算或判断对错的要求。 | 知识层次: 题目要求对不同形态的SiO2结构进行比较和分析，涉及多个概念的理解和关联，需要综合运用材料科学中的结构知识，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对四种不同形态的SiO2进行多角度分析论述，包括晶体结构、各向异性/各向同性、孔隙率以及短程/长程有序性等关键特征。需要综合运用材料科学中的晶体学、非晶态结构和相变等知识进行关联性说明，解题步骤涉及多个概念的对比和解释，属于该题型内较高难度的综合分析题。" + }, + { + "idx": 133, + "question": "Describe the structural and property characteristics of Na2O·2SiO2 melt", + "answer": "
StructureSix-membered or eight-membered rings, long-range disorder
PropertiesHigh electrical conductivity, high surface tension
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述Na2O·2SiO2熔体的结构和性质特征，答案以表格形式提供了结构和性质的详细说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对Na2O·2SiO2熔体结构和性质特征的基础概念记忆，如六元环或八元环结构、长程无序等结构特征，以及高电导率、高表面张力等性质特征。这些都属于基本原理和分类的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求描述Na2O·2SiO2熔体的结构和性质特征，属于概念解释和描述的难度等级。虽然需要记忆和理解一些基本概念（如六元环或八元环结构、长程无序等），但并不需要复杂的体系阐述或多层次的分析。题目主要考察对特定材料结构和性质的基本记忆和简单解释能力，符合等级2的要求。" + }, + { + "idx": 134, + "question": "Can glass be formed by rapid quenching at 1050°C?", + "answer": "At this temperature, rapid quenching can form glass.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断在1050°C快速淬火是否能形成玻璃，答案直接给出了明确的判断结果（能形成玻璃），符合判断题的特征。 | 知识层次: 题目考查玻璃形成的基本原理和温度条件的记忆，属于基础概念的记忆和理解范畴。 | 难度: 在判断题的基础概念记忆层次中，此题仅需判断\"玻璃是否能在1050°C通过快速淬火形成\"这一基本定义的正确性，不涉及概念理解或复杂陈述的判断，属于最简单的正误判断类型。" + }, + { + "idx": 135, + "question": "CeO2 has a fluorite structure. When 15 mol% CaO is added to form a solid solution, the measured density of the solid solution is d = 7.01 g/cm³, and the unit cell parameter is a = 0.5417 nm. Determine through calculation which type of solid solution is formed. The atomic weights are Ce 140.12, Ca 40.08, O 16.00.", + "answer": "For the CaO-CeO2 solid solution, from the perspective of maintaining electrical neutrality, it can form either an oxygen vacancy solid solution or a solid solution with Ca²⁺ embedded in the anion interstitial sites. The solid solution equations are as follows: For substitutional solid solution, x = 0.15, 1 - x = 0.85, 2 - x = 1.85, so the chemical formula of the substitutional solid solution is Ca0.15Ce0.85O1.85. Since CeO2 has a fluorite structure, the number of unit cell molecules Z = 4, and the unit cell contains three types of ions: Ca²⁺, Ce⁴⁺, and O²⁻. The mass of the unit cell is: W = ΣWi = [4 × (0.15/1) × MCa²⁺ + 4 × (0.85/1) × MCe⁴⁺ + 8 × (1.85/2) × MO²⁻] / 6.022 × 10²² = 102.766 × 10⁻²² g. The calculated density dR = W/V = 0.6465 g/cm³. For interstitial solid solution, the chemical formula is Ca2Ce1-yO2. Compared with the given composition Ca0.15Ce0.85O1.85, the O²⁻ content differs: Ca0.15Ce0.85O1.85 → Ca0.15×2/1.85Ce0.85×2/1.85O2. y = 0.15 × 2 / 1.85, 1 - y = 0.85 × 2 / 1.85 ⇒ y = 0.15 / 1.85. The chemical formula of the interstitial solid solution is Ca0.15×2/1.85Ce1.7/1.85O2. Similarly, the calculated density dg = W/V = 7.033 g/cm³. The measured density is d = 7.01 g/cm³, which is close to d2. Therefore, an interstitial solid solution is formed, with interstitial Ca²⁺ ions present.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算确定形成的固溶体类型，涉及数值计算和公式应用，如密度计算、化学式推导等。答案中详细展示了计算过程和结果比较，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和综合分析，包括化学式的推导、密度的计算以及不同类型固溶体的比较。虽然涉及基础概念如固溶体类型和密度计算，但需要将这些概念关联起来进行综合判断，思维过程较为复杂。 | 难度: 在计算题题型中，该题目属于复杂多变量计算难度等级。题目不仅要求掌握固溶体的基本概念和形成机制，还需要进行多步计算，包括化学式的推导、单位晶胞质量的计算、密度的计算与比较等。此外，题目还涉及电中性原则的应用和两种可能的固溶体类型的分析，要求综合运用多个知识点进行判断。计算过程中需要处理多个变量和参数，如原子量、晶胞参数、密度等，且计算步骤较为复杂，容易出错。因此，在同题型内属于较高难度等级。" + }, + { + "idx": 136, + "question": "The viscosity of SiO2 melt is 10^14 Pa·s at 1000°C and 10^7 Pa·s at 1400°C. What is the activation energy for viscous flow of SiO2 glass?", + "answer": "According to the formula: η=η0exp(ΔE/RT)\\nAt 1000°C, η=10^14 Pa·s, T=1000+273=1273 K\\nAt 1400°C, η=10^7 Pa·s, T=1400+273=1673 K\\nSolving the two equations simultaneously yields: η0=5.27×10^-16 Pa·s\\nΔE=713.5 kJ/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解SiO2玻璃的粘流活化能，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要应用Arrhenius公式进行多步计算，涉及温度转换和联立方程求解，需要一定的综合分析能力，但不需要复杂的推理或创新思维。 | 难度: 在计算题中属于中等偏上难度，需要应用阿伦尼乌斯公式进行多步计算，同时需要理解温度单位转换和活化能的概念。虽然计算步骤较多，但公式应用和解题思路相对明确，属于综合性计算问题。" + }, + { + "idx": 137, + "question": "The melt viscosity is 10^7 Pa·s at 727°C and 10^3 Pa·s at 1156°C. At what temperature will it be 10^6 Pa·s?", + "answer": "According to logη=A+B/T, at 727°C, η=10^7 Pa·s, the equation gives: log10^7=A+B/(727+273) (1). At 1156°C, η=10^3 Pa·s, the equation gives: log10^3=A+B/(1156+273) (2). Solving equations (1) and (2) simultaneously yields A=-6.32 and B=13324. When η=10^6 Pa·s, log10^6=-6.32+13324/(t+273), solving gives t=808.5°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定温度下的熔体粘度，解答过程中涉及对数运算和联立方程的求解，属于典型的计算题。 | 知识层次: 题目需要应用粘度与温度关系的公式，并通过联立方程求解未知数，涉及多步计算和概念关联，但不需要复杂的推理或深度分析。 | 难度: 在计算题中属于综合性计算问题，需要应用对数公式进行多步计算，同时涉及温度单位的转换和联立方程的求解。虽然计算过程较为复杂，但步骤明确且不涉及多变量交互作用，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 138, + "question": "A melt has a viscosity of 310Pa·s at 1300℃ and 10^7Pa·s at 800℃. What is its viscosity at 1050℃?", + "answer": "According to logη=A+B/(T+273), at 1300℃, η=310Pa·s, the formula gives: log310=A+B/(1300+273)①; at 800℃, η=10^7Pa·s, the formula gives: log10^7=A+B/(800+273)②. Solving equations ① and ② simultaneously yields A=−7.2, B=15219.6. When t=1050℃, logη=−7.2+15219.6/(1050+273), solving gives η=20130.5Pa·s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的粘度数据和公式进行数值计算，最终得出特定温度下的粘度值。解答过程涉及公式应用和联立方程求解，属于典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括建立方程、联立求解、代入计算等步骤，涉及对粘度-温度关系的理解和应用，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用对数粘度公式并进行多步计算。题目要求解两个方程以确定常数A和B，然后代入第三个温度值计算粘度。虽然涉及多个步骤，但计算过程相对直接，没有引入额外复杂变量或高级数学技巧，因此在同类题型中属于中等难度。" + }, + { + "idx": 139, + "question": "The viscosity of Pyrex glass is 10^9 Pa·s at 1400°C and 10^13 Pa·s at 840°C. To facilitate forming, approximately what temperature is required for the glass to reach a viscosity of 10^5 Pa·s?", + "answer": "According to the formula: η = η0 exp(ΔE / (R T)). Given η0 = 11.22 Pa·s and ΔE = 254.62 kJ/mol. When η = 10^5 Pa·s, 10^5 = 11.22 exp(254.62 × 1000 / ((273 + t) × 8.314)). Solving gives t = 3094.2°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，以求得特定粘度下的温度值。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用粘度公式进行多步计算，涉及对数运算和温度转换，需要理解公式中各参数的含义并进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用粘度公式进行多步计算，涉及对数运算和温度转换，但未达到复杂多变量计算的程度。" + }, + { + "idx": 140, + "question": "The viscosity of Pyrex glass is 10^9 Pa·s at 1400℃ and 10^13 Pa·s at 840℃. What is the activation energy for viscous flow?", + "answer": "According to the formula: η = η0 exp(ΔE / (R T)). At 1400℃, η = 10^9 Pa·s, T = 1400 + 273 = 1673 K, 10^9 = η0 exp(ΔE / (1673 × 8.314)). At 840℃, η = 10^13 Pa·s, T = 840 + 273 = 1113 K, 10^13 = η0 exp(ΔE / (1113 × 8.314)). Solving the two equations simultaneously yields: η0 = 11.22 Pa·s, ΔE = 254.62 kJ/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解粘性流动的活化能，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换和联立方程求解，属于中等应用层次。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，同时涉及温度单位转换和对数运算。虽然计算过程明确，但需要同时处理两个方程并解出两个未知数（η0和ΔE），对学生的公式应用和代数运算能力有一定要求。相比简单的单步计算题（等级2）更为复杂，但尚未达到需要处理多变量或非线性关系的等级4难度。" + }, + { + "idx": 141, + "question": "From the following two glaze formulas, determine the difference in their melting temperatures? Explain the reason. Glaze formula 1: 0.2K2O 0.2Na2O 0.4CaO 0.2PbO 0.3Al2O3 2.1SiO2; Glaze formula 2: 0.2K2O 0.2MgO 0.6CaO 1.1Al2O3 10.0SiO2", + "answer": "(2) The melting temperature of glaze formula 1 > the melting temperature of glaze formula 2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种釉料配方的熔融温度差异的原因，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种釉料配方的熔化温度差异并解释原因，这涉及到对釉料组成与性能关系的理解，需要分析不同氧化物对熔化温度的影响，属于中等应用层次。虽然不涉及复杂的计算，但需要对多个因素进行综合分析，并运用相关知识进行解释。 | 难度: 在简答题题型中，该题目属于较高难度。需要考生进行多步计算（如计算各氧化物的助熔效果和网络形成能力），同时需要综合分析不同氧化物（如PbO、MgO、CaO等）对釉料熔融温度的影响机制。此外，还需关联理解Al2O3和SiO2在不同配方中的比例变化对熔融特性的影响，并进行对比论述。这超出了简单概念复述或单一步骤计算的要求，属于需要多角度分析论述的题目。" + }, + { + "idx": 142, + "question": "A borosilicate glass used for sealing lamps has an annealing point of 544°C and a softening point of 780°C. Calculate the activation energy for viscous flow of this glass.", + "answer": "According to the formula: η=η0exp(ΔE/RT). At the annealing point of 544°C, η=1.0×10^12 Pa·s, T=544+273=817K; at the softening point of 780°C, η=4.5×10^6 Pa·s, T=780+273=1053K. Solving the simultaneous equations gives: η0=1.39×10^-12 Pa·s, ΔE=373.13 kJ/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解玻璃的粘性流动活化能，答案给出了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算（温度转换、粘度公式应用、联立方程求解），并需要理解粘度与温度的关系（阿伦尼乌斯方程），涉及概念关联和综合分析。虽然计算过程明确，但需要一定的思维深度和步骤整合。 | 难度: 在计算题中属于综合性计算问题。题目需要应用粘性流动的活化能公式，进行多步计算（包括温度单位转换、对数运算和联立方程求解），同时需要理解玻璃的退火点和软化点对应的粘度值概念。虽然计算过程较为复杂，但所有必要参数都已给出，不需要额外推导或假设，因此属于该题型内的中等偏上难度。" + }, + { + "idx": 143, + "question": "From the following two glaze formulas, determine the difference in surface tension between them? Explain the reason. Glaze formula 1: 0.2K2O 0.2Na2O 0.4CaO 0.2PbO 0.3Al2O3 2.1SiO2; Glaze formula 2: 0.2K2O 0.2MgO 0.6CaO 1.1Al2O3 10.0SiO2", + "answer": "(3) Difference in surface tension: The surface tension of glaze formula 1 < the surface tension of glaze formula 2, because the O/Si ratio of glaze formula 1 is less than that of glaze formula 2, and glaze formula 1 contains PbO and B2O3, which can reduce surface tension.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种釉料配方的表面张力差异，并说明原因。答案提供了详细的文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求分析两种釉料配方的表面张力差异，并解释原因。这需要综合运用材料科学中的表面张力理论、氧化物对表面张力的影响、以及O/Si比的计算等知识。此外，还需要理解PbO和B2O3对表面张力的特殊影响，并进行推理分析。整个过程涉及多个知识点的关联和综合分析，思维深度较高。 | 难度: 在简答题题型中，该题目要求综合运用材料科学知识，分析两种釉料配方的表面张力差异，并解释原因。需要深入理解O/Si比、PbO和B2O3对表面张力的影响机理，属于机理深度解释的难度等级。虽然不涉及最复杂的多因素交互分析，但需要较强的推理能力和专业知识支撑。" + }, + { + "idx": 144, + "question": "A borosilicate glass used for sealing lighting lamps has an annealing point of 544°C, a softening point of 780°C, and a viscous flow activation energy of 373.13 kJ/mol. Determine its working range.", + "answer": "The working temperature range viscosity is generally 10^3~10^7 Pa·s. According to the formula T=ΔE/(R·ln(η/η0)): when η=10^3 Pa·s, T=1033.6K=760.6°C; when η=10^7 Pa·s, T=1038.9°C. Therefore, the working temperature range is 760.6°C~1038.9°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定玻璃的工作温度范围，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用公式进行多步计算，涉及粘度和温度的转换，并需要理解工作温度范围的概念。虽然计算过程较为直接，但需要将多个概念关联起来进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用公式进行多步计算，并理解工作温度范围与粘度之间的关系。虽然计算步骤较多，但公式应用和概念关联较为直接，没有涉及复杂多变量的情况。" + }, + { + "idx": 145, + "question": "The working range of a certain type of glass is from $870^{\\\\circ}\\\\mathrm{C}$ ($\\\\eta=10^{6}\\\\mathrm{{Pa}\\\\cdot{}}$) to $1300^{\\\\circ}\\\\mathrm{C}$ ($\\\\eta=10^{2.5}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$). Estimate its annealing point ($\\\\eta=10^{12}\\\\mathrm{{Pa}\\\\cdot\\\\Delta s}$)?", + "answer": "According to the formula: $\\\\mathfrak{H}=\\\\mathfrak{N}_{0}\\\\exp(\\\\frac{\\\\Delta\\\\mathcal{E}}{R T})$ \\n\\nAt $870^{\\\\circ}\\\\mathrm{C}$, $\\\\eta=10^{6}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$, T=870+273=1143K, $10^{6}=1.57\\\\times10^{-7}\\\\exp[\\\\frac{280.16\\\\times1000}{1143\\\\times8.314}]$ (1) \\nAt $1300^{\\\\circ}\\\\mathrm{C}$, $\\\\eta=10^{2.5}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$ (2) \\nBy solving equations (1) and (2) simultaneously, we get: $\\\\mathfrak{V}_{0}=1.57\\\\times\\\\ensuremath{10^{-7}}\\\\mathrm{Pa}\\\\cdot\\\\mathrm{s}$, $\\\\Delta E=280.16\\\\mathrm{kJ/mol}$ \\nWhen $\\\\eta=10^{12}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$, $10^{12}=1.57\\\\times10^{-7}\\\\exp[\\\\frac{280.16\\\\times1000}{(273+t)\\\\times8.314}]$ \\nSolving gives $t=505.15^{\\\\circ}\\\\mathrm{C}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，涉及多个步骤的数学运算和方程求解，最终得出具体数值结果。 | 知识层次: 题目需要应用粘度-温度关系的公式进行多步计算，涉及对数运算和方程求解，同时需要理解粘度与温度之间的关联性，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用公式并进行多步计算，同时涉及温度转换和方程求解，但未达到复杂多变量计算的程度。" + }, + { + "idx": 146, + "question": "What are the kinetic factors affecting the glass formation process?", + "answer": "The key factor affecting glass formation is the cooling rate of the melt. Whether the melt crystallizes or forms glass is related to the degree of supercooling, viscosity, nucleation rate, and crystal growth rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响玻璃形成过程的动力学因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响玻璃形成过程的动力学因素，涉及多个相关概念（冷却速率、过冷度、粘度、成核速率和晶体生长速率）的综合分析，需要理解这些因素之间的相互作用及其对玻璃形成的影响，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并综合说明多个关键因素（冷却速率、过冷度、粘度、成核速率和晶体生长速率）对玻璃形成过程的影响。虽然涉及多个概念，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 147, + "question": "What are the crystallochemical factors affecting the glass formation process?", + "answer": "The crystallochemical factors affecting glass formation include: the size and arrangement of complex anion groups, bond strength, and bond type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述影响玻璃形成的结晶化学因素，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释影响玻璃形成的结晶化学因素，涉及多个概念的关联和综合分析，如复杂阴离子基团的尺寸和排列、键强度和键类型等，需要一定的理解和应用能力，但不需要复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目要求对玻璃形成过程中的结晶化学因素进行多角度分析论述。需要考生理解并关联多个概念（如复杂阴离子基团的尺寸和排列、键强度和键类型），并能够综合这些因素进行解释。虽然不涉及深度关联性分析（等级5），但已超出简单的概念说明（等级3），属于需要多角度分析论述的中高难度题目。" + }, + { + "idx": 148, + "question": "From the following two glaze formulas, determine the difference in viscosity between the two? Explain the reason. Glaze formula 1: 0.2K2O 0.2Na2O 0.4CaO 0.2PbO 0.3Al2O3 2.1SiO2; Glaze formula 2: 0.2K2O 0.2MgO 0.6CaO 1.1Al2O3 10.0SiO2", + "answer": "(1) Difference in viscosity\\nFor glaze formula 1:\\n∵(K2O+Na2O+CaO+PbO)/Al2O3=(0.2+0.2+0.4+0.2)/0.3=3.33>1, Al3+ acts as a network-forming ion,\\nR1=(0.2+0.2+0.4+0.2+0.3×3+2.1×2+0.5×3)/(0.3×2+2.1+0.5×2)=2.05\\nX1=2×2.05-4=0.1\\nY1=4-0.1=3.9\\nFor glaze formula 2:\\n∴(K2O+MgO+CaO)/Al2O3=(0.2+0.2+0.6)/1.1=0.910<1, Al3+ is considered a network-modifying ion\\nR2=(0.2+0.2+0.6+1.1×3+10×2)/10.0=2.43\\nX2=2×2.43-4=0.86\\nY2=4-0.86=3.14\\nThat is: Y of glaze formula 1 > Y of glaze formula 2, so at high temperatures, the viscosity of glaze formula 1 > the viscosity of glaze formula 2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算两种釉料配方的粘度差异，并解释原因。答案中包含了详细的数值计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括氧化物比例的计算、R值的计算、X和Y值的计算，并且需要理解Al3+在不同条件下的作用（网络形成离子或网络修饰离子）。此外，还需要综合分析计算结果来比较两种釉料的粘度差异。这涉及到多个概念的关联和综合应用，超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要理解多个概念（如网络形成离子和网络修饰离子的作用）、进行多步计算（包括比例计算、R值计算、X和Y值计算），并进行综合分析比较。虽然计算步骤较多，但每个步骤相对明确，没有涉及过于复杂的变量或非常规计算方法。" + }, + { + "idx": 150, + "question": "Compare which of the two types of glass has higher viscosity at high temperature?", + "answer": "V1>V2, Glass No.1 has higher viscosity at high temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种玻璃在高温下的粘度高低，并给出具体结论，需要文字解释和论述，而不是简单的选择或判断。答案也以陈述句形式给出，符合简答题的特征。 | 知识层次: 题目要求比较两种玻璃在高温下的粘度，这需要理解粘度的概念以及不同类型玻璃的组成和性质对粘度的影响。虽然不涉及复杂的计算，但需要对材料性质有一定的综合分析能力，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解玻璃粘度的概念，并能综合分析两种玻璃在高温下的粘度差异。题目要求进行比较和说明，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 151, + "question": "Calculate the structural parameters of Glass No. 2, with the composition of Na2O 10 mol%, CaO 0 mol%, Al2O3 20 mol%, SiO2 60 mol%, B2O3 10 mol%", + "answer": "No. 2: Z=4, (Na2O+CaO)/Al2O3=(10+0)/20=0.5<1, Al3+ is considered as a network modifier ion. R1=(10+60+120+30)/(60+20)=2.75. X2=2R-Z=1.5. Y2=4-1.5=2.5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定玻璃的结构参数，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（Z值计算、离子角色判断、R1值计算、X2和Y2值计算），涉及多个结构参数的关联分析，需要理解网络形成体和网络修饰体的概念及其在玻璃结构中的作用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解网络形成体和网络修饰体的概念，进行多步计算（包括摩尔比例计算、结构参数推导等），并综合分析Al3+的离子角色。虽然涉及多个变量，但计算步骤相对清晰，属于中等应用层次中的典型题目。" + }, + { + "idx": 152, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass $\\mathrm{_{6}(1)N a_{2}O\\bullet S i0_{2}}$", + "answer": "Z=4, R=3/1=3, X=2R-Z=6-4=2, Y=8-2R=8-6=2. Non-bridging oxygen %=2/(1+2)=66.7%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中给出了具体的计算步骤和结果，包括结构参数和非桥氧分数的计算过程。 | 知识层次: 题目涉及多步计算（Z、R、X、Y的计算）和概念关联（结构参数与非桥氧分数的关系），需要综合分析玻璃组成与结构参数之间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握结构参数和非桥氧分数的计算方法，涉及多步计算和概念关联，但未达到复杂多变量计算的难度。" + }, + { + "idx": 153, + "question": "Which substances can form non-crystalline solids (NCS)?", + "answer": "Melts and glassy solids can form non-crystalline solids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪些物质可以形成非晶态固体，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对非晶态固体形成物质的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答哪些物质可以形成非晶态固体，属于基本定义简答。题目涉及的知识点较为基础，只需记忆熔体和玻璃态固体可以形成非晶态固体，不需要深入的解释或复杂的论述。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 154, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass $\\mathrm{(3)Na_{2}0\\bullet_{}1/3A l_{2}O_{3}\\bullet S i O_{2}}$", + "answer": "Al2O3>1, Al3+ is considered as a network-forming ion. Z=4, R=(1+1+2)/(2*(2/3)+1)=2.4, X=2R-Z=4.8-4=0.8, Y=4-0.8=3.2. Non-bridging oxygen %=0.8/(1.6+0.8)=33.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及结构参数和非桥氧分数的计算，答案以数值结果呈现。 | 知识层次: 题目需要进行多步计算，包括结构参数和非桥氧分数的计算，涉及网络形成离子的概念和公式应用，需要综合分析玻璃组成和结构之间的关系。虽然不涉及复杂的推理分析或创新应用，但需要一定的概念关联和计算步骤。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要掌握网络形成离子概念、结构参数计算公式（Z、R、X、Y）以及非桥氧百分比计算等多个步骤。虽然计算过程明确，但涉及多个概念的综合应用和公式推导，属于该题型内中等偏上的难度水平。" + }, + { + "idx": 156, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass with the composition $\\mathrm{(4)18Na_{2}0\\cdot10C a0\\cdot72S i0_{2}}$ (wt%)", + "answer": "Na2O: 18%, 0.290 mol, 17.4 mol%; CaO: 10%, 0.179 mol, 10.7 mol%; SiO2: 72%, 1.200 mol, 71.9 mol%. Z=4, R=(17.4+10.7+71.9*2)/71.9=2.39, X=2R-Z=0.78, Y=4-0.78=3.22. Non-bridging oxygen %=0.78/(1.61+0.78)=32.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，如摩尔百分比、结构参数Z、R、X、Y的计算以及非桥氧百分比的推导，这些都是典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括摩尔分数转换、结构参数计算（Z、R、X、Y）以及非桥氧分数的推导。虽然涉及多个公式的应用，但整体思路较为明确，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要掌握多个概念（如摩尔分数、结构参数Z、R、X、Y的计算）并进行多步计算。虽然涉及多个变量和公式，但计算过程相对直接，没有过于复杂的推导或迭代计算，因此属于等级3的综合性计算问题。" + }, + { + "idx": 157, + "question": "For glass No. 1 with the composition of Na2O 8 wt%, Al2O3 12 wt%, and SiO2 80 wt%, use the glass structural parameters to explain the magnitude of its viscosity at high temperatures?", + "answer": "For No. 1: Z=4 Na2O/Al2O3=8.16/7.47>1 Al2O3 is considered as a network-forming ion R=(8.16+7.47×3+84.37×2)/(7.47×2+84.37)=2.007 X1=2R−Z=0.014 Y1=4−X=3.986 Y1=3.986, therefore, the viscosity of No. 1 at high temperatures is high.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用玻璃结构参数来解释高温下粘度的变化，答案提供了详细的参数计算和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求使用玻璃结构参数来解释高温粘度的变化，涉及多个步骤的计算（如Z、R、X1、Y1的计算）和概念关联（网络形成离子、结构参数与粘度的关系），需要综合运用知识进行推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用玻璃结构参数（Z、R、X1、Y1等）进行网络结构分析，并推导高温粘度的机理解释。虽然计算步骤明确，但需要深入理解玻璃网络形成与改性原理，并能将结构参数与宏观性能（粘度）建立关联，属于机理深度解释级别。相比等级5的全面分析题，该题未涉及多因素交互或动态过程分析，因此属于复杂分析题型中的次高难度。" + }, + { + "idx": 158, + "question": "A glass composition (wt%) is Na2O 14%, CaO 13%, SiO2 73%, with a density of 2.5 g/cm3. If soda ash, limestone, and quartz sand are used as raw materials to melt this glass with 1000 kg of quartz sand, how much of the other two raw materials are needed?", + "answer": "With 1000 kg of quartz sand, the required soda ash (Na2CO3) is: (14/73)×1000×(106/62)=327.88 kg. The required limestone (CaCO3) is: (13/73)×1000×(100/56)=318.00 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定所需的原材料数量。答案也展示了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括质量百分比的转换、分子量的计算以及原料用量的确定，涉及多个概念的关联和综合分析。虽然不涉及复杂的机理或创新设计，但需要一定的理解和应用能力来完成计算。 | 难度: 在计算题中属于综合性计算问题，需要理解玻璃成分的百分比计算、原料的化学计量转换以及多步骤的数值计算。虽然不涉及复杂多变量，但需要综合应用多个概念和公式进行推导和计算。" + }, + { + "idx": 160, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass (2) Na2O•CaO•Al2O3•SiO2", + "answer": "Na2O+CaO/(2*Al2O3)=2>1, Al is considered as a network-forming ion. Z=4, R=(1+1+3+2)/(2+1)=2.33, X=2R-Z=4.66-4=0.66, Y=4-0.66=3.34. Non-bridging oxygen %=0.66/(1.67+0.66)=28.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，如结构参数和非桥氧分数的计算过程。 | 知识层次: 题目涉及多步计算和概念关联，需要理解网络形成离子、结构参数计算和非桥氧分数的综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解网络形成体和网络修饰体的概念，进行多步计算（包括结构参数Z、R、X、Y的计算），并最终推导非桥氧百分比。虽然计算步骤较多，但各步骤之间有明确的逻辑关系，属于典型的中等应用层次计算题。" + }, + { + "idx": 161, + "question": "Does this composition have a tendency to form glass? Why?", + "answer": "This composition has a tendency to form glass because the structure maintains a three-dimensional framework at this point, and the viscosity of the glass is still relatively high, making it easy to form glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么该成分有形成玻璃的倾向，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释玻璃形成倾向的原因，涉及对材料结构和性能（如粘度）的综合分析，属于中等应用层次的知识点。需要理解玻璃形成的条件，并能将结构与性能关联起来进行解释。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释和论述，但主要涉及单一概念（玻璃形成倾向）的说明，并基于给定的结构特征和粘度特性进行综合分析。不需要多角度或深度关联性分析，解题步骤相对直接，符合等级3的综合分析和说明要求。" + }, + { + "idx": 162, + "question": "Among the following three substances, which one is the least likely to form glass, and why? (1) Na2O·2SiO2; (2) Na2O·SiO2; (3) NaCl", + "answer": "(3) NaCl is the least likely to form glass. NaCl lacks a network structure and is a typical ionic crystal, making it difficult to form glass.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从三个选项中选择最不可能形成玻璃的物质，并解释原因。虽然需要解释，但核心是选择正确答案，符合选择题的特征。 | 知识层次: 题目要求考生理解玻璃形成的基本原理（网络结构），并能够分析不同物质的化学键类型和结构特征，从而判断其形成玻璃的能力。这需要将多个概念（玻璃形成条件、离子键与共价键特性、网络结构等）进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解玻璃形成的基本条件（如网络结构、键合类型等），并能对不同物质的化学组成和结构特性进行比较分析。虽然题目涉及多个概念的综合运用，但解题步骤相对直接，主要考察对玻璃形成原理的理解和应用能力。" + }, + { + "idx": 163, + "question": "Among the following three substances, which one is most likely to form glass, and why? (1) Na2O·2SiO2; (2) Na2O·SiO2; (3) NaCl", + "answer": "(1) Na2O·2SiO2 is most likely to form glass. Calculations show that R1=2.5, Y1=3. At high temperatures, (1) has high viscosity and is prone to form glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么某个物质最可能形成玻璃，需要文字解释和论述，而不是简单的选择或判断。答案也提供了详细的解释和计算依据。 | 知识层次: 题目要求考生不仅需要知道玻璃形成的基本原理（如硅氧比R和网络形成能力Y的概念），还需要进行计算（R1=2.5, Y1=3）和综合分析（比较不同物质的玻璃形成倾向），这涉及到多步计算和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解玻璃形成的基本原理，进行简单的计算（R1和Y1），并综合分析不同物质的玻璃形成倾向。虽然涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 164, + "question": "Briefly describe the differences in structure and properties between tempered glass and annealed glass.", + "answer": "Glass that eliminates and balances internal stresses caused by temperature gradients is called annealed glass, which is less prone to breakage and easier to cut. Tempering involves heating the product to near its softening temperature to fully anneal the glass, followed by rapid cooling (quenching). This creates uniform internal stresses, resulting in pre-compressive stresses on the glass surface, thereby increasing resistance to bending, impact, and torsional deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述两种玻璃在结构和性能上的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对退火玻璃和钢化玻璃的基本定义、结构差异和性能特点的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述钢化玻璃和退火玻璃在结构和性能上的差异，涉及两种玻璃的基本定义和加工工艺的对比，但不需要深入分析复杂概念体系或进行多层次的论述。回答需要记忆和解释相关概念，但不需要进行复杂的推理或综合应用。" + }, + { + "idx": 165, + "question": "What are the methods for forming non-crystalline solids (NCS)?", + "answer": "Non-crystalline solids can be obtained by supercooling melts and glasses.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释非晶态固体的形成方法，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查非晶态固体形成方法的基本概念记忆和理解，属于基础知识的直接问答，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答非晶态固体的形成方法，需要学生理解并描述\"熔体超冷\"和\"玻璃化\"这两个关键概念，但不需要深入阐述复杂机理或进行多步骤论证。相比等级1的纯定义复述题(如\"什么是非晶态固体\")更具解释性，但比等级3要求系统阐述非晶态形成理论体系(如比较各种制备方法的动力学原理)更为基础。" + }, + { + "idx": 166, + "question": "A glass composition (wt%) is Na2O 14%, CaO 13%, SiO2 73%, with a density of 2.5 g/cm3. Calculate the atomic packing factor (AFP) and structural parameter values of this glass?", + "answer": "The average molecular weight of the glass GW=0.14×62+0.13×56+0.73×60.02=59.77. The number of atoms in 1Å3 is n=2.5×10-24×6.02×1023/59.77=0.252 atoms/Å3. The volume occupied by atoms in 1Å3 V=0.0252×4/3π[0.14×2×0.983+0.13×1.063+0.73×0.393+(0.14+0.13+0.73+0.13+0.13)]×1.323=0.4685. AFP=0.46. Structural parameters: Na2O wt% 14, CaO wt% 13, SiO2 wt% 73; mol Na2O 0.23, CaO 0.23, SiO2 1.22; mol% Na2O 13.7, CaO 13.7, SiO2 72.6. R=(13.7+13.7+72.6×2)/72.6=2.38. Z=4. X=2R-Z=2.38×2-4=0.76. Y=Z-X=4-0.76=3.24.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算原子堆积因子（AFP）和结构参数值。答案中展示了详细的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括平均分子量的计算、原子数的计算、原子占据体积的计算以及原子堆积因子的计算。此外，还需要计算结构参数如R、Z、X和Y，涉及多个概念的综合应用和关联分析。虽然不涉及复杂的推理或创新设计，但需要较高的计算能力和对多个知识点的综合理解。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算原子堆积因子（AFP）和结构参数值，涉及分子量计算、原子数密度、原子体积计算以及结构参数推导等多个步骤。虽然计算过程较为复杂，但题目提供了明确的成分和密度数据，且计算步骤相对固定，因此属于中等难度。" + }, + { + "idx": 167, + "question": "How much CaO needs to be added to 100g of SiO2 to achieve an O:Si ratio of 2.5?", + "answer": "46.67", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算CaO的添加量），涉及化学计量比和公式应用，答案是一个具体的数值结果(46.67)。 | 知识层次: 题目需要进行多步计算，包括理解O:Si比例的含义、计算SiO2中的氧原子数量、确定需要添加的CaO量以达到目标比例，并应用化学计量关系进行综合计算。这超出了简单公式应用的范畴，需要概念关联和综合分析能力。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要理解O:Si比值的概念，掌握CaO和SiO2的化学反应关系，并进行多步计算（包括摩尔质量转换、化学计量比应用等）。虽然不涉及复杂变量，但需要将多个化学概念与计算步骤有机结合，属于该题型内中等偏上的难度水平。" + }, + { + "idx": 168, + "question": "By adding $20\\%\\\\mathrm{B}_{2}0_{3}$ to $\\\\mathrm{Si0_{2}}$, calculate the $0:\\\\mathrm{Si}$ ratio of the melt.", + "answer": "S $\\\\frac{{\\\\cal O}}{\\\\bar{\\\\cal S}\\\\bar{\\\\imath}}=\\\\frac{1\\\\times2+0.2\\\\times3}{1+0.2\\\\times2}=1.86$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解$0:\\\\mathrm{Si}$的比例，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的应用和简单计算，需要理解氧化物摩尔比的计算方法，但不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用基本化学计量比公式，并进行简单的数值计算。虽然涉及两种化合物的比例计算，但步骤直接且无需复杂推导。" + }, + { + "idx": 169, + "question": "If 50 mol% Na2O is added to SiO2, what is the O:Si ratio?", + "answer": "O/Si = (0.5 + 1 × 2)/1 = 2.5", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，答案是通过计算得出的具体数值（O/Si = 2.5），符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，只需理解Na2O和SiO2的化学组成并进行简单的摩尔比例计算即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接应用单一公式（O/Si比例计算）并进行简单数值代入即可得出结果，无需任何复杂步骤或多公式组合。" + }, + { + "idx": 170, + "question": "If 10mol% Na2O is added to SiO2, what is the calculated O:Si ratio?", + "answer": "O:Si = (0.1 + 1 × 2)/1 = 2.1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过计算得出的具体数值结果。 | 知识层次: 题目涉及基本的化学计量计算，只需要应用简单的公式和基本的化学计量知识即可解决，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的化学计量比公式，将给定的摩尔百分比转换为O:Si的比例，计算过程简单直接，无需多个公式组合或复杂的推导步骤。" + }, + { + "idx": 171, + "question": "When Na2O is added to SiO2, making O/Si=2.5, is the crystallization ability enhanced or weakened?", + "answer": "Because O/Si increases, the viscosity decreases, and the crystallization ability is enhanced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Na2O添加到SiO2中导致O/Si=2.5时结晶能力的变化，答案提供了文字解释和论述，说明粘度降低和结晶能力增强的原因，符合简答题的特征。 | 知识层次: 题目需要理解Na2O和SiO2的相互作用对O/Si比的影响，并关联到粘度和结晶能力的变化。这涉及多个概念的关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于中等难度，需要理解O/Si比例变化对材料性能的影响，并进行综合分析和说明。题目涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 172, + "question": "Adding 50mol% Na2O to SiO2, can this ratio form a glass? Why?", + "answer": "Yes, it can form a glass. When 50mol% Na2O is added, although the continuous SiO network skeleton becomes relaxed, it still maintains a three-dimensional network structure, allowing the formation of a glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释为什么50mol% Na2O添加到SiO2中可以形成玻璃，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解Na2O和SiO2在玻璃形成中的作用，分析50mol% Na2O添加对SiO2网络结构的影响，并解释为什么这种比例仍能形成玻璃。这涉及多个概念的关联和综合分析，超出了基础概念记忆和简单应用的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及玻璃形成的基本原理和网络结构的概念，但解答过程主要围绕单一知识点（Na2O-SiO2系统的玻璃形成能力）展开，不需要多角度或深度关联性分析。解题步骤相对直接，只需解释为什么50mol% Na2O仍能形成玻璃，并说明网络结构的变化。因此，在简答题题型内属于等级3的综合分析和说明难度。" + }, + { + "idx": 173, + "question": "How much Na2O should be added to SiO2 to make the O/Si ratio of the glass equal to 2.5? Assume the amount of SiO2 is ymol.", + "answer": "Let xmol of Na2O be added, then O/Si=(x+2y)/y=2.5. Solving gives x=y/2, meaning when the molar ratio of the two is 1:2, O/Si=2.5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过设定变量和建立方程来求解所需的Na2O量。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及基本的化学计量计算和公式应用，只需要简单的代数运算和基本概念理解即可解决，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用O/Si比值的公式，并进行简单的代数运算求解。虽然涉及到了变量的设定和方程求解，但整个过程较为直接，没有复杂的多步骤计算或公式组合。因此，在同题型内属于等级2难度。" + }, + { + "idx": 174, + "question": "What is surface tension?", + "answer": "Surface tension: the surface constriction force acting perpendicularly on a unit length line segment or the work required to increase an object's surface area by one unit; σ= force/total length (N/m)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"surface tension\"进行定义和解释，答案提供了详细的文字描述和公式说明，符合简答题的特征 | 知识层次: 题目考查表面张力的基本定义和单位，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求回答表面张力的基本定义，属于最基础的概念记忆性知识。题目不需要额外的解释或描述，也不涉及复杂的概念体系阐述，因此在该题型内属于最低难度等级。" + }, + { + "idx": 175, + "question": "What is surface energy?", + "answer": "Surface energy: Under constant temperature, pressure, and composition, the non-volume work required to reversibly increase the surface area of a substance is called surface energy; J/m2=N/m", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"surface energy\"进行定义和解释，答案提供了详细的文字描述和单位说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查表面能的基本定义和单位，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目仅要求对表面能的基本定义进行简答，属于最基础的概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接复述定义和单位，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 176, + "question": "What is the difference between surface tension and surface energy in the liquid state?", + "answer": "Liquid: cannot withstand shear stress, the work done by external forces manifests as an expansion of surface area, because surface tension and surface energy are numerically the same", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释表面张力和表面能之间的区别，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查表面张力和表面能这两个基本概念的定义和区别，属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释液体状态下表面张力和表面能的区别，需要考生理解并描述这两个概念的基本原理及其在液体状态下的特殊关系（数值相同）。虽然涉及两个相关概念的比较，但不需要构建复杂的理论体系或进行深入推导，主要考察对基础概念的理解和表述能力。" + }, + { + "idx": 177, + "question": "Explain based on the structure why the mixture of alkali and wollastonite with 0/Si=3 crystallizes instead of forming glass?", + "answer": "When 0/Si=3, Y=2. For silicate glasses, a three-dimensional network cannot be formed when Y=2 because the number of bridging oxygens shared between tetrahedra is less than 2, and the structure mostly consists of tetrahedral chains of varying lengths. Therefore, the mixture of alkali and wollastonite with 0/Si=3 crystallizes instead of forming glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于结构解释混合物结晶而非形成玻璃的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于结构解释混合物结晶而非形成玻璃的原因，涉及硅酸盐玻璃网络形成条件的理解、Y值的计算及其对结构的影响，需要综合分析结构化学和材料科学的知识点，并进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求基于结构解释特定配比下混合物结晶而非形成玻璃的原因。需要深入理解硅酸盐网络结构形成条件（Y值概念）、桥氧与非桥氧比例对玻璃形成能力的影响等机理层面的知识，并能将这些概念整合运用到具体材料体系中。虽然不需要涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述层面，属于需要机理深度解释的难度等级。" + }, + { + "idx": 178, + "question": "Based on the structure, explain why a mixture of alkali and silica with 2<0/Si<2.5 can form glass?", + "answer": "When 2<0/Si<2.5, 390^{\\\\circ},B T\\\\cup\\\\gamma_{\\\\mathrm{SRE}}\\\\times1875^{\\\\circ}$$ So it cannot wet.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的表面张力和界面张力数据，应用公式计算接触角，并判断润湿性。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目主要考查杨氏方程的直接应用和简单计算，涉及表面张力和接触角的基本关系，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用表面张力和接触角的基本公式进行计算，但仅涉及单一公式的直接套用和简单数值计算，无需多个公式组合或复杂推导。" + }, + { + "idx": 198, + "question": "From an atomic scale perspective, explain the differences in the bonding effects of welding", + "answer": "Welding: A process where two or more materials (of the same or different types) are permanently joined by heating, applying pressure, or both, to achieve atomic bonding. The conditions during welding include: base material type, plate thickness, groove shape, joint form, restraint state, ambient temperature and humidity, cleanliness, as well as the type and diameter of the welding wire (or electrode), welding current, voltage, welding speed, welding sequence, deposition method, and gun (or electrode) manipulation method determined based on the above factors. If the weld groove or surface has impurities such as oil (paint), water, or rust, they can cause defects like pores, inclusions, slag, or cracks in the weld, posing hazards and potential risks to the welded joint.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释焊接的键合效应差异，需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求从原子尺度解释焊接的键合效应差异，需要综合运用材料科学中的原子键合理论、焊接工艺参数的影响以及缺陷形成机理等多方面知识进行深入分析和解释。这涉及到对多个概念的综合理解和关联，以及推理分析能力，属于复杂分析层次。 | 难度: 在简答题的复杂分析层次中，该题目要求从原子尺度解释焊接的键合效应差异，涉及多种焊接条件、材料特性和潜在缺陷的综合分析。需要考生具备深厚的材料科学基础、原子键合理论的理解能力，并能将多因素相互作用整合成系统性解释。这种对复杂现象的全面分析和对机理的深度解释要求，符合该题型下的最高难度等级标准。" + }, + { + "idx": 199, + "question": "Heat treat Si3N4 at the eutectic temperature and measure its thermal etching groove angle as 60°, calculate the grain boundary energy of Si3N4.", + "answer": "γss=2γsvcos(ψ/2)=2×900cos30°=1558.8mN/m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式计算Si3N4的晶界能，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的公式和数值进行计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需套用给定的公式γss=2γsvcos(ψ/2)，并代入已知数值进行计算，无需额外的公式组合或复杂推导。解题步骤简单直接，属于该题型中最基础的计算类型。" + }, + { + "idx": 200, + "question": "The eutectic of the MgO-Al2O3-SiO2 system is placed on a Si3N4 ceramic plate. At the eutectic temperature, the surface tension of the liquid phase is 900 mN/m, the interfacial energy between the liquid and solid is 600 mN/m, and the measured contact angle is 70.52°. Find the surface tension of Si3N4.", + "answer": "Yv = Ycosθ + Y = 900cos70.52° + 600 = 900 mN/m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解表面张力，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用表面张力和接触角的公式进行计算，并理解各参数之间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用表面张力公式并进行多步计算（包括三角函数运算和代数运算），同时需要理解界面能、接触角等概念的关联性。虽然计算过程明确，但涉及多个物理量的综合运用，属于中等偏上的复杂度。" + }, + { + "idx": 201, + "question": "From an atomic scale perspective, explain the differences in the bonding effects of sintering", + "answer": "Sintering: It is a high-temperature treatment process that imparts material properties. The diffusion of atoms to contact points causes bonding between particles, and further diffusion ultimately fills the remaining pores and increases the density of the material. It involves heating powder or powder compacts to a temperature below the melting point of their basic components, followed by cooling to room temperature using specific methods and rates. The result of sintering is the bonding between powder particles, increasing the strength of the sintered body, transforming the aggregate of powder particles into a coalescence of grains, thereby obtaining products or materials with desired physical and mechanical properties. Low-temperature pre-sintering stage: During this stage, metal recovery, volatilization of adsorbed gases and moisture, decomposition, and removal of forming agents in the compact mainly occur. Medium-temperature sintering stage: In this stage, recrystallization begins to appear. Within the particles, deformed grains are restored and reorganized into new grains, while surface oxides are reduced, and sintering necks form at particle interfaces. High-temperature sintering completion stage: In this stage, diffusion and flow proceed sufficiently and near completion, forming a large number of closed pores that continue to shrink, reducing pore size and total porosity, significantly increasing the density of the sintered body.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释烧结过程中的键合效应差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从原子尺度解释烧结过程中的键合效应，涉及多个阶段的详细机理分析，包括原子扩散、烧结颈形成、孔隙变化等复杂过程。这需要综合运用材料科学中的扩散理论、热力学和动力学知识，进行深入的推理和解释，属于复杂分析层次。 | 难度: 在简答题的复杂分析层次中，该题目要求对烧结过程的原子尺度机理进行全面解释，涉及低温、中温和高温三个阶段的详细变化，以及扩散、孔隙闭合等复杂现象的深入分析。需要综合运用材料科学知识，进行多步骤推理和机理解释，属于该题型内的最高难度等级。" + }, + { + "idx": 202, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the trend in potential changes of clay after adsorbing the following different cations (use arrows to show: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附后黏土电位变化的趋势，属于需要文字解释和论述的简答题 | 知识层次: 题目要求对不同阳离子在黏土中吸附后的电位变化趋势进行排序，这需要理解阳离子电荷、离子半径等基本概念，并能够综合分析这些因素对黏土电位的影响。虽然不涉及复杂的计算或机理解释，但需要对多个因素进行关联分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解不同阳离子对粘土电位的影响趋势，并进行综合分析和排序。虽然涉及多个离子的比较，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 203, + "question": "Silver plating is required on alumina ceramic parts. It is known that at 1000°C, γ_{Al2O3(s)} = 1.00 mN/m, γ_{Ag(L)} = 0.92 mN/m, and γ_{Ag(L)-Al2O3(s)} = 1.77 mN/m. Can liquid silver wet the surface of alumina ceramic parts? What methods can be used to improve the wettability between them?", + "answer": "cosθ = (γ_{sv} - γ_{sl}) / γ_{lv} = -0.837, θ = 146.8° > 90°, cannot wet. To silver plate ceramic components, the surface of the ceramic must first be ground and polished to improve the wettability between the ceramic and the silver layer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释液态银是否能润湿氧化铝陶瓷表面，并提出改善润湿性的方法。答案包含计算过程和文字解释，需要论述和说明，符合简答题的特征。 | 知识层次: 题目需要应用表面张力的基本公式计算接触角，并根据计算结果判断润湿性。此外，还需要提出改善润湿性的方法，涉及多步计算和综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于中等难度，需要理解表面张力的概念，运用杨氏方程进行计算，并结合计算结果进行解释和论述。虽然涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 204, + "question": "Analyze the scope of action of firmly bound water and loosely bound water in micelles", + "answer": "Firmly bound water surrounds the clay particles, forming an integral whole with them and moving together in the medium, with a thickness of approximately 3 to 10 water molecules. Loosely bound water is located on the periphery of firmly bound water, with poorer orientation. As they are farther from the clay particle surface, the binding force between them is smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求分析胶束中紧密结合水和松散结合水的作用范围，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目考查对胶束中紧密结合水和松散结合水作用范围的基本概念的理解和记忆，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求分析胶束中紧密结合水和松散结合水的作用范围，需要解释两者的定义、位置关系以及特性差异。虽然涉及两个相关概念，但不需要构建复杂的理论体系或进行深入分析，主要考察对基础概念的记忆和理解。相比等级1的基本定义简答，该题需要更多的描述性内容；但相比等级3的复杂概念体系阐述，其知识深度和解题复杂度都较为基础。" + }, + { + "idx": 205, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the ion exchange capacity of clay after adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "Li+ < Na+ < K+ < NH4+ < Mg2+ < Ca2+ < Sr2+ < Ba2+ < Al3+ < H+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用箭头表示离子交换容量的变化模式，需要根据材料科学知识对离子排序，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对黏土离子交换容量变化规律的基础概念记忆，仅需根据已知的离子交换能力顺序进行排列，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，需要理解并记忆不同阳离子在黏土中的离子交换能力顺序，并能够正确排列。虽然不需要复杂的解释或论述，但需要对基础概念有一定的掌握和记忆能力。" + }, + { + "idx": 206, + "question": "Explain the differences between structural water, bound water (tightly bound water, loosely bound water), and free water in clay.", + "answer": "Structural water in clay refers to the water within the clay structure. Since clay particles are generally negatively charged and water is a polar molecule, when clay particles are dispersed in water, under the influence of the negative electric field on the clay surface, water molecules align in a specific orientation around the clay particles, forming hydrogen bonds with the oxygen and hydroxyl groups on the surface, with their negative ends facing outward. A negatively charged surface forms around the first layer of water molecules, attracting a second layer of water molecules. The attractive force of the negative electric field on water molecules weakens with increasing distance from the clay surface, causing the arrangement of water molecules to transition gradually from ordered to disordered. The inner layer of water molecules arranged in an ordered manner is called tightly bound water, which surrounds the clay particles and moves together with them as a whole in the medium, with a thickness of approximately 3 to 10 water molecules. The outer layer of water molecules, which is less ordered, is called loosely bound water. Due to their greater distance from the clay particle surface, the binding force between them is weaker. The water beyond the loosely bound water is called free water.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释不同类型的水在粘土中的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对粘土中不同类型水的定义和分类的记忆和理解，属于基础概念的记忆性知识。虽然答案中涉及了一些关于水分子排列和结合力的描述，但整体上仍属于对基本概念的解释和论述，没有涉及复杂的应用或分析。 | 难度: 在简答题中属于复杂概念体系阐述的难度等级。题目要求解释结构水、结合水（强结合水、弱结合水）和自由水在黏土中的区别，不仅需要准确记忆这些概念的定义，还需要理解它们之间的层次关系和相互作用机制。解答需要系统性地描述水分子在黏土颗粒周围的排列方式、结合力的变化以及不同水层的特性，涉及多个相关概念的串联和对比，属于该题型内较高难度的题目。" + }, + { + "idx": 207, + "question": "Analyze the influence of firmly bound water and loosely bound water on process performance", + "answer": "The density of bound water is high, the heat capacity is small, the dielectric constant is small, and the freezing point is low, which makes it different from free water in physical properties. The amount of clay-water combination can be judged by measuring the heat of wetting. The state and quantity of clay combined with these three types of water will affect the process performance of the clay-water system. When the water content of the clay is constant, if the bound water decreases, the free water increases, resulting in a reduced volume of clay particles that are easier to move, thus lowering the slurry viscosity and improving fluidity. When the amount of bound water is high, the water film is thick, facilitating the sliding between clay particles, which enhances plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析结合水对工艺性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析紧密结合水和松散结合水对工艺性能的影响，涉及多种物理性质的比较和解释，需要综合运用材料科学知识进行推理分析，理解不同状态水对粘土系统性能的影响机制，属于复杂分析层次。 | 难度: 在简答题的复杂分析题型中，该题目要求对紧密结合水和松散结合水对工艺性能的影响进行机理深度解释。需要综合运用材料科学、物理化学等多学科知识，分析不同状态水的物理性质差异及其对粘土-水系统工艺性能的具体影响机制。虽然不涉及多变量交互作用等最复杂层面的分析，但已超出基础概念描述层面，属于需要深入理解并解释因果关系的难度等级。" + }, + { + "idx": 208, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of combined water content in clay after adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附后黏土中结合水含量的变化规律，答案以排序形式给出，需要理解和解释不同阳离子对黏土结合水含量的影响，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求理解不同阳离子对黏土结合水含量的影响，并能够根据离子特性（如电荷、半径等）进行排序。这需要将基础概念（离子吸附与结合水的关系）与具体应用（不同离子的比较）相结合，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解粘土吸附不同阳离子后结合水含量的变化规律，并进行综合分析和排序。虽然不需要多角度或深度关联性分析，但仍需掌握相关概念并进行逻辑推理。" + }, + { + "idx": 209, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation trend in slurry stability when clay adsorbs the following different cations (use arrows to show: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求用箭头表示黏土吸附不同阳离子时浆体稳定性的变化趋势，需要根据材料科学知识进行排序和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土浆体稳定性的影响，并能够根据阳离子的性质（如电荷、离子半径等）进行排序。这需要考生掌握粘土吸附阳离子的基本原理，并能够将这些原理应用到具体情境中，进行多因素的综合分析。虽然不涉及复杂的计算或推理，但需要对多个概念进行关联和比较，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解粘土吸附不同阳离子对浆体稳定性的影响趋势，并能够正确排列这些阳离子的顺序。虽然题目涉及多个阳离子的比较，但主要考察的是对离子特性和吸附效应的基本理解，不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 210, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of slurry fluidity for clay adsorbed with the following different cations (use arrows to denote: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附下粘土浆体流动性的变化规律，属于需要文字解释和论述的简答题类型。答案形式为排列顺序，而非选择或计算。 | 知识层次: 题目要求考生理解不同阳离子对粘土浆体流动性的影响，并能够根据离子特性（如电荷、半径等）进行排序。这需要考生不仅记住阳离子的基本性质，还要能够应用这些知识来分析其对粘土性能的影响，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解粘土吸附不同阳离子对浆体流动性的影响，并按照特定顺序排列。虽然不需要复杂的计算，但需要对离子特性和粘土性质有较好的理解，并能综合分析不同离子对流动性的影响。" + }, + { + "idx": 211, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation trend of the thixotropy of clay slurry when adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Li+ < Na+ < K+ < NH4+ < Mg2+ < Ca2+ < Sr2+ < Ba2+ < Al3+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子对粘土浆触变性的影响趋势，需要文字解释和论述，而不是简单的选择或判断。答案的形式是排列顺序，属于简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土触变性的影响趋势，并能够根据离子性质（如电荷、离子半径等）进行综合分析，排列出正确的顺序。这需要考生不仅记忆阳离子的基本性质，还需要理解这些性质如何影响粘土的行为，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度，需要学生掌握粘土吸附阳离子的规律，并能综合分析不同阳离子对粘土触变性的影响趋势。题目要求用箭头表示从小到大的变化趋势，涉及多种阳离子的比较和排序，需要学生理解离子价态、离子半径等因素对粘土性质的影响，并进行多步分析和综合判断。这超出了简单记忆的范畴，属于中等应用层次中较复杂的综合分析题。" + }, + { + "idx": 212, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of plasticity in clay lumps after adsorbing the following different cations (use arrows to denote: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "Li+ < Na+ < K+ < NH4+ < Mg2+ < Ca2+ < Sr2+ < Ba2+ < Al3+ < H+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附后粘土可塑性的变化规律，需要按照特定顺序排列离子并解释其变化模式，属于需要特定形式回答的简答题类型。 | 知识层次: 题目要求考生理解并应用粘土吸附不同阳离子后塑性变化的规律，需要将离子特性（如电荷、半径等）与粘土塑性关联起来进行分析和排序。这涉及到多个概念的综合应用和一定的推理过程，但不需要复杂的机理解释或创新设计。 | 难度: 在简答题题型中，该题目要求对多种吸附阳离子对粘土可塑性的影响进行排序，并解释其变化规律。这需要学生掌握粘土吸附阳离子的基本原理，理解阳离子价态、半径等因素对可塑性的影响，并能综合分析不同阳离子的特性进行排序。题目涉及多个概念的综合应用和比较分析，属于多角度分析论述的难度等级。" + }, + { + "idx": 213, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the filtrate loss of clay slurry adsorbed with the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子对粘土浆滤失量的影响趋势，需要根据知识进行排序和解释，属于需要文字或符号表述的简答题类型。 | 知识层次: 题目要求根据不同类型吸附阳离子的特性，分析其对粘土浆料滤失量的影响，并排列出变化规律。这需要理解阳离子与粘土相互作用的原理，并能够综合比较不同阳离子的影响，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析不同阳离子对粘土浆料滤失量的影响，并按照特定顺序排列。题目要求掌握阳离子吸附对粘土性质的影响机制，并能将多个阳离子的效应进行比较和排序。这涉及多步概念关联和综合分析，超出了基础记忆或简单应用的范畴。" + }, + { + "idx": 214, + "question": "According to Figure 5-13 and Table 5-2, the atomic densities on different crystallographic planes (110), (100), and (111) of a face-centered cubic lattice are different. Please answer, on which plane will the solid-gas surface energy be the lowest? Why?", + "answer": "According to the formula for surface energy $\\\\frac{\\\\underline{{L}}^{s}\\\\mathcal{E}_{\\\\underline{{\\\\bar{L}}}}}{N_{0}}[1-\\\\frac{n_{i}^{s}}{n_{i}^{\\\\delta}}]=(\\\\Delta\\\\zeta7)_{s,v}\\\\bullet\\\\underline{{\\\\zeta}}^{s}=\\\\gamma_{s o}^{0}$, where $\\\\gamma_{50}^{0}$ is the solid surface energy, $E_{L}$ is the lattice energy, $N_{0}$ is Avogadro's number, and $Z$ is the number of atoms per 1m² surface. $n_{i}^{\\\\delta}$ and $n_{i}^{s}$ represent the number of nearest neighbor atoms for the i-th atom in the bulk and on the surface, respectively. In a face-centered cubic crystal, $n_{i}^{\\\\delta}=12$; $n_{i}^{s}$ is 6 on the (111) plane, 4 on the (100) plane, and 2 on the (110) plane. Substituting these values into the formula gives $\\\\gamma_{s o(110)}^{0}=0.550\\\\frac{E_{z}}{N_{0}}(1-\\\\frac{2}{12})=0.46\\\\frac{E_{z}}{N_{0}}$,\\n$\\\\gamma_{s o(100)}^{0}=0.785\\\\frac{E_{L}}{N_{0}}(1-\\\\frac{4}{12})=0.53\\\\frac{E_{L}}{N_{0}}$,\\n$\\\\gamma_{s o(111)}^{0}=0.907\\\\frac{E_{z}}{N_{0}}(1-\\\\frac{6}{12})=0.45\\\\frac{E_{z}}{N_{0}}$.\\nThus: $\\\\gamma_{_{50(100)}}^{0}>\\\\gamma_{_{50(110)}}^{0}>\\\\gamma_{_{50(111)}}^{0}$.\\n\\nTherefore, the (111) close-packed plane has the lowest surface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪个晶面的固气表面能最低，并给出原因。答案通过公式推导和文字解释详细论述了不同晶面的表面能计算过程，最终得出结论。这符合简答题的特征，即需要文字解释和论述。 | 知识层次: 题目需要综合运用晶体结构、表面能公式和原子密度等知识，进行多步计算和推理分析，解释不同晶面表面能差异的原因，涉及较深的思维过程和综合分析能力。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 215, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the casting time of clay slurry when adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附时粘土浆料浇注时间的变化模式，答案给出了具体的顺序排列，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土浆料浇铸时间的影响，并能够根据阳离子的性质（如电荷、离子半径等）进行排序。这需要考生掌握粘土吸附阳离子的基本原理，并能将这些原理应用到具体情境中，属于中等应用层次。虽然不涉及复杂的计算或深度推理，但需要对多个概念进行关联和综合分析。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求考生理解粘土吸附不同阳离子对浇注时间的影响，这需要掌握粘土表面化学和离子交换的基本原理。其次，题目要求考生将多种阳离子按照特定规律排序，这需要综合分析离子半径、电荷数、水化能等多个因素对粘土-水系统流变性能的影响。最后，题目还要求用箭头符号准确表达变化趋势，这需要考生对概念有清晰的理解并能进行系统化的表达。这些要求使得该题目在简答题中属于多角度分析论述的难度等级。" + }, + { + "idx": 216, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the green body formation rate when the clay adsorbs the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附时坯体形成速率的变化规律，需要文字解释和论述，而不是简单的选择或判断。答案形式为排列顺序，属于简答题类型。 | 知识层次: 题目要求根据不同类型吸附阳离子的特性，分析其对粘土成型速率的影响，并排列顺序。这需要理解阳离子电荷、半径等性质与粘土性能的关系，属于多概念关联和综合分析的应用层次。 | 难度: 在简答题题型中，该题目要求对粘土吸附不同阳离子时生坯形成速率的变化模式进行多角度分析论述。需要综合考虑离子半径、电荷数、水化能力等多个因素对粘土颗粒间作用力的影响，并建立这些因素与生坯形成速率之间的关联。虽然不需要进行复杂的计算，但需要对多个概念进行综合分析，并能够清晰地表述其变化规律。这超出了简单概念复述或单一因素分析的难度（等级3），但尚未达到需要深度关联性分析（等级5）的程度。" + }, + { + "idx": 217, + "question": "What measures can be taken in production to increase or decrease the plasticity of clay to meet the needs of forming processes?", + "answer": "In production, the specific surface area of mineral components can be increased to enhance the capillary force, thereby increasing plasticity; the valence of adsorbed cations can also be increased or decreased to alter the plasticity of clay; or the particle size of minerals can be reduced to increase contact points, thereby enhancing the plasticity of clay;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释生产中可以采取哪些措施来增加或减少粘土的塑性以满足成型工艺的需求，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求考生理解并应用材料科学中关于粘土塑性的知识，涉及多个因素（如矿物组分的比表面积、吸附阳离子的价态、矿物颗粒大小）的综合分析，以调整塑性满足成形工艺需求。这需要考生不仅记住相关概念，还能将这些概念关联起来进行多步分析和应用。 | 难度: 在简答题中属于较高难度，需要从多个角度（如矿物成分比表面积、吸附阳离子价态、矿物颗粒尺寸等）分析并论述如何调控黏土可塑性，涉及多步概念关联和综合分析能力要求。" + }, + { + "idx": 218, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite mineral), compare the differences in the casting rate of the two slurries when the same amount of electrolyte is added.", + "answer": "The addition of Na2CO3 basically has no effect on the casting rate of the clay, while the addition of Na2SiO3 increases the casting rate of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆料浇注速率的影响，并给出解释性的答案，需要文字论述而非选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对粘土浆料浇注速率的影响，需要理解电解质与粘土颗粒间的相互作用机制，并综合分析不同电解质（Na2CO3和Na2SiO3）对浆料流变性能的影响差异。这涉及多步概念关联和综合分析，但不需要深入机理解释或创新设计。 | 难度: 在简答题中属于中等难度，需要理解电解质对粘土浆料的影响，并进行比较分析。题目要求比较两种电解质（Na2CO3和Na2SiO3）对同类型粘土浆料浇注速率的影响，并解释其差异。这涉及到对电解质作用机理的理解和实际应用效果的分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 219, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite mineral), compare the differences in thixotropy of the two slurries when the same amount of electrolyte is added.", + "answer": "Adding Na2CO3 basically has no effect on the thixotropy of the clay, while adding Na2SiO3 reduces the thixotropy of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆体触变性的影响，并给出解释。答案需要文字论述两种电解质的不同效果，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对粘土浆体触变性的影响，涉及对电解质作用机理的理解和不同电解质效果的对比分析。虽然不需要复杂的计算，但需要对材料科学中的胶体化学和表面化学知识有一定的理解和应用能力，属于中等难度的应用分析。 | 难度: 在简答题题型中，该题目要求对两种电解质（Na2CO3和Na2SiO3）对粘土浆体触变性的影响进行比较分析。这需要考生不仅理解触变性的基本概念，还需要掌握电解质与粘土矿物之间的相互作用机制。题目涉及多步分析和概念关联，要求考生能够综合运用所学知识进行论述，属于中等应用层次中的较高难度。因此，在同题型内属于等级4的多角度分析论述难度。" + }, + { + "idx": 220, + "question": "What are the factors affecting the plasticity of clay?", + "answer": "The influencing factors include: 1. Mineral composition, different mineral compositions result in varying interparticle forces. 2. Types of adsorbed cations, higher valence cations improve plasticity. 3. Particle size and shape, finer particles with larger specific surface area and more contact points between particles increase plasticity. 4. Water content, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响粘土塑性的因素，答案以文字论述的形式列出多个影响因素，符合简答题的特征。 | 知识层次: 题目要求解释影响粘土塑性的多个因素，涉及矿物组成、吸附阳离子类型、颗粒大小和形状以及水分含量等概念的综合分析。虽然不需要复杂的计算或深度推理，但需要对不同因素之间的关联和影响进行理解和应用，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要从多个角度（矿物组成、吸附阳离子类型、颗粒尺寸和形状、含水量等）进行分析论述，并解释各因素之间的相互作用和影响机制。这不仅要求对基础概念的掌握，还需要进行综合分析和关联性思考。" + }, + { + "idx": 221, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite minerals), compare the differences in the body density of the two slurries when the same amount of electrolyte is added.", + "answer": "Adding Na2CO3 basically has no effect on the body density of the clay, while adding Na2SiO3 increases the body density of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆体密度的影响，并给出解释，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对黏土浆体密度的影响，需要理解电解质与黏土颗粒的相互作用机制，并分析不同电解质（Na2CO3和Na2SiO3）在相同条件下的效果差异。这涉及多步概念关联和综合分析，但不需要深入机理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解电解质对粘土浆体密度的影响机制，并进行比较分析。题目要求比较两种电解质（Na2CO3和Na2SiO3）对相同粘土浆体密度的影响，涉及对电解质作用原理的理解和应用。虽然需要一定的综合分析能力，但不需要多角度或深度关联性分析，因此属于等级3。" + }, + { + "idx": 222, + "question": "What is the practical significance of Gibbs phase rule?", + "answer": "Applying the phase rule can conveniently determine the degrees of freedom of an equilibrium system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Gibbs相律的实际意义，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对Gibbs相律基本概念的理解和记忆，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目要求对Gibbs相律的实际意义进行解释和描述，属于概念解释和描述的难度等级。虽然需要理解相律的基本原理，但并不需要复杂的体系阐述或多步骤推理，因此属于中等难度。" + }, + { + "idx": 223, + "question": "In the phase diagram of the SiO2 system, find two examples of reversible polymorphic transformations", + "answer": "Reversible polymorphic transformations: β-quartz ↔ α-quartz, α-quartz ↔ tridymite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举可逆多晶型转变的例子，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对SiO2系统相图中可逆多晶转变的基本概念记忆，仅需列举两种转变类型，无需深入分析或综合应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆（SiO2系统的相图和多晶型转变），但需要学生准确回忆并列举两个具体的可逆多晶型转变例子（β-石英 ↔ α-石英，α-石英 ↔ 鳞石英）。这比单纯的定义简答（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 224, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay (mainly composed of kaolinite mineral) slurry, respectively, compare the differences in fluidity of the two slurries when the same amount of electrolyte is added.", + "answer": "Adding Na2CO3 basically has no effect on the fluidity of the clay, while adding Na2SiO3 increases the fluidity of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对黏土浆流动性的影响，并解释差异。答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对黏土浆料流动性的影响，涉及对电解质作用机理的理解和应用。虽然不需要复杂的计算，但需要对Na2CO3和Na2SiO3在黏土浆料中的不同作用进行分析和比较，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解电解质对粘土浆料流动性的影响，并进行比较分析。题目要求比较两种电解质（Na2CO3和Na2SiO3）对同一类型粘土浆料流动性的影响，涉及对粘土矿物（高岭石）和电解质作用机制的基本理解。虽然需要综合分析，但不需要深入探讨作用机理或多角度论述，因此属于等级3。" + }, + { + "idx": 225, + "question": "What is Gibbs phase rule?", + "answer": "The phase rule is a fundamental law of phase equilibrium derived by Gibbs based on thermodynamic principles, also known as Gibbs phase rule, used to describe the relationship between the number of degrees of freedom, the number of components, and the number of phases in a system at phase equilibrium. The general mathematical expression is F=C-P+2, where F is the number of degrees of freedom, C is the number of components, P is the number of phases, and 2 represents the two variables of temperature and pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Gibbs phase rule进行解释和论述，答案提供了详细的文字描述和公式说明，符合简答题的特征。 | 知识层次: 题目考查Gibbs相律的基本定义和数学表达式，属于基础概念的记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要准确表述Gibbs相律的定义和数学表达式，但不需要进行复杂的推导或深入分析多个概念间的关系。主要考察对基础概念的记忆和简单解释能力，符合等级2\"概念解释和描述\"的要求。相比等级1的基本定义简答，该题需要更完整的表述；但相比等级3的复杂概念体系阐述，其知识深度和解题复杂度都较为基础。" + }, + { + "idx": 226, + "question": "In the SiO2 phase diagram, identify two examples of irreversible polymorphic transformations", + "answer": "Irreversible polymorphic transformations: β-cristobalite←→β-quartz, V-tridymite←→β-quartz", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求识别并列举SiO2相图中的不可逆多晶转变例子，答案需要文字解释和具体例子，而不是选择、判断或计算。 | 知识层次: 题目考查对SiO2相图中不可逆多晶转变的具体实例的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求考生不仅记忆SiO2相图中的不可逆多晶型转变实例，还需要准确识别和列举具体转变对。这超出了单纯的定义复述（等级1），但尚未达到需要系统阐述复杂概念体系的等级3要求。题目考查的是对相图特定知识点的掌握和简单应用，属于概念解释和描述的中等难度范畴。" + }, + { + "idx": 227, + "question": "In the Al2O3-SiO2 system, the liquidus line of SiO is very steep, so why is it necessary to strictly prevent the mixing of Al2O3 in silica bricks, otherwise the refractoriness of silica bricks will be greatly reduced?", + "answer": "Al2O3 in the SiO2 system can significantly increase the amount of liquid phase, leading to a substantial decrease in the eutectic point temperature, thereby greatly reducing the refractoriness of silica bricks. Therefore, it is essential to strictly prevent the mixing of Al2O3.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在SiO2系统中混入Al2O3会显著降低硅砖的耐火度，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要解释Al2O3在SiO2系统中如何显著增加液相量，并导致共晶点温度大幅下降，从而降低硅砖的耐火度。这涉及对相图的理解、液相形成的机理分析以及材料性能变化的综合推理，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对Al2O3-SiO2系统的相图特性进行机理深度解释，需要理解陡峭液相线对耐火性能的影响机制，并能准确说明Al2O3混入导致共晶点温度显著降低的因果关系。虽然不涉及多因素交互作用的全面分析，但需要深入的材料热力学知识和对相变行为的准确描述，符合等级4的机理深度解释要求。" + }, + { + "idx": 228, + "question": "At this temperature, after prolonged holding to reach equilibrium, what is the phase composition of the system?", + "answer": "After prolonged holding at 1595°C, the system consists of liquid phase and A3S2, with L% = 21.8%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述系统在特定条件下的相组成，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目需要理解相平衡的概念，并能根据给定的温度条件分析系统的相组成，涉及多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解相平衡概念并应用相图知识进行综合分析。题目要求确定特定温度下的相组成，涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 229, + "question": "In the CaO-SiO2 system, the liquidus line of SiO2 is very steep. Why can a small amount of CaO be added as a mineralizer in the production of silica bricks without reducing their refractoriness?", + "answer": "When a small amount of CaO is added to SiO2, at the eutectic point of 1436°C, the liquid phase content is 2/37=5.4%. The increase in liquid phase content is not significant and does not reduce the refractoriness of silica bricks, so a small amount of CaO can be added as a mineralizer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在硅砖生产中少量添加CaO不会降低其耐火性，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要综合运用相图知识（CaO-SiO2系统相图）和矿物学原理（矿化剂作用机理），通过分析共晶点液相含量变化来解释矿化剂添加对耐火度的影响，涉及多概念关联和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求考生深入理解CaO-SiO2系统的相图特征，并能结合具体生产工艺条件（如矿物添加量对液相线的影响）进行机理层面的解释。需要综合运用相平衡知识、计算能力（如液相含量百分比）和实际应用推理能力，属于需要机理深度解释的等级4难度题目。" + }, + { + "idx": 230, + "question": "When the clay mineral kaolinite (Al2O3•2SiO2•2H2O) is heated to 600°C, it decomposes into water vapor and Al2O3•2SiO2. What happens when it is further heated to 1595°C?", + "answer": "When heated to 1595°C, A3S2 is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释当高岭石加热到1595°C时会发生什么变化，答案需要文字描述反应产物，属于简答题类型。 | 知识层次: 题目需要理解高岭石在不同温度下的分解过程，并关联到具体的化学反应和产物形成。虽然涉及记忆性知识，但需要将多个知识点（分解温度、产物变化）进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解粘土矿物高岭石的热分解过程，并能够关联不同温度下的反应产物。题目要求考生掌握高岭石的热分解反应，并能正确识别在1595°C时形成的产物A3S2。虽然涉及多步反应，但不需要复杂的计算或深度关联性分析，主要考察对反应过程的理解和记忆。" + }, + { + "idx": 231, + "question": "At what temperature does the clay completely melt?", + "answer": "Complete melting means the solid phase completely disappears, which should be at the temperature where the 33% line intersects with the liquidus line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么温度下黏土完全熔化，答案需要文字解释和论述，说明完全熔化的条件，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解相图的基本概念（如liquidus线），并能够通过相图分析确定特定成分（33%）的完全熔化温度，涉及多步分析和概念关联。 | 难度: 在简答题中属于中等难度，需要理解相图的基本概念（如液相线和固相线），并能通过图表分析确定完全熔化的温度点。虽然涉及多步分析和概念关联，但不需要进行复杂的多角度论述或深度关联性分析。" + }, + { + "idx": 232, + "question": "When the system generates 40% liquid phase, what temperature should be reached?", + "answer": "The temperature at which 40% liquid phase is generated needs to be determined by referring to the phase diagram, and the specific temperature is not provided in the answer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定温度，需要参考相图进行分析，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求根据相图确定特定液相比例对应的温度，需要理解相图的基本原理并能够进行多步分析和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求综合分析相图来确定温度，但解题步骤相对明确，主要是通过相图分析来确定特定液相比例对应的温度。这需要学生理解相图的基本概念和液相比例的计算方法，但不需要进行多角度或深度关联性分析。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 233, + "question": "Compare the characteristics of the eutectic point in ternary invariant points and write its equilibrium relationship", + "answer": "The eutectic point is a type of invariant point where several crystalline phases simultaneously precipitate from the melt upon cooling or melt together upon heating. The phase equilibrium relationship is L(E)⇄A+B+C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中共晶点的特性并写出其平衡关系，需要文字解释和论述，答案也以文字形式给出 | 知识层次: 题目要求比较三元不变点中共晶点的特性并写出其平衡关系，涉及多个概念的关联和综合分析，需要理解共晶点的定义、相平衡关系以及在不同体系中的应用，属于中等应用层次。 | 难度: 在简答题中属于较高难度，题目要求比较三元不变点中共晶点的特性并写出其平衡关系。这需要学生不仅理解共晶点的基本概念，还需要掌握三元相图中不变点的特性，并能准确表达相平衡关系。解题步骤涉及概念关联和综合分析，属于多角度分析论述的层次。" + }, + { + "idx": 234, + "question": "Cool a melt containing MgO and $\\\\mathrm{{Al}_{2}\\\\mathrm{{O}_{3}}}$ to a certain temperature, then filter out the precipitated crystals and analyze the remaining liquid phase. It is found that the liquid phase contains 65% MgO, and the amount of liquid phase is 70% of the total system. Determine the composition of the original melt.", + "answer": "$\\\\mathrm{MgO\\\\ 45.5\\\\%}$; $\\\\mathrm{Al_{2}O_{3}\\\\ 54.5\\\\%}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定原始熔体的组成，答案给出了具体的百分比数值，表明需要进行计算才能得出结果。 | 知识层次: 题目需要进行多步计算和概念关联，包括相平衡和成分分析的综合应用，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及相平衡和物质守恒原理的应用，要求分析液体和固体的组成变化，并进行逆向推导。虽然计算步骤较多，但变量关系明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 235, + "question": "Compare the characteristics of the singular peritectic point in ternary invariant points, and write its equilibrium relationship", + "answer": "If the invariant point is at the intersection position, it is a singular eutectic point; if it is at the conjugate position, it is a double peritectic point. The phase transformation relationship is L_{(g)}+A⇌D+C, L_{(g)}+A+B⇌S", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中单一包晶点的特性并写出其平衡关系，需要文字解释和论述，答案也以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求比较三元不变点中的单一包晶点特性并写出其平衡关系，涉及多个概念的关联和综合分析，需要理解相图的基本原理并能够应用这些原理来解释特定现象。虽然不涉及复杂的计算或深度推理，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于较高难度，需要理解并分析三元不变点中的单转熔点特性，同时写出其平衡关系。题目要求综合多个概念（如单转熔点、双转熔点）并进行多步分析，还需要准确表述相变关系（L_{(g)}+A⇌D+C, L_{(g)}+A+B⇌S）。这需要较深的概念关联和综合分析能力，符合等级4的多角度分析论述要求。" + }, + { + "idx": 236, + "question": "Compare the characteristics of transition points in ternary invariant points and write their equilibrium relationships", + "answer": "The transition point is where the properties change from peritectic to eutectic, with no corresponding triangle, and the compositions of the three crystalline phases in equilibrium lie on a straight line", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中的过渡点特性并写出它们的平衡关系，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较三元不变点中过渡点的特性并写出其平衡关系，这需要综合运用相图知识、理解相变机制，并进行推理分析。涉及多个概念的关联和深层次理解，超出了简单记忆或应用的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求对三元不变点中的过渡点特性进行比较，并写出其平衡关系。这需要综合运用相图知识、理解相变机理，并能分析复杂现象。题目不仅要求识别过渡点的特征（如性质从包晶变为共晶、无对应三角形、三相组成共线），还需要解释其平衡关系，这属于该题型下最高难度的全面分析要求。" + }, + { + "idx": 237, + "question": "Compare the characteristics of the double transition point in the ternary invariant point and write its equilibrium relationship", + "answer": "If the invariant point is at the intersection position, it is a single eutectic point; if it is at the conjugate position, it is a double transition point. The phase transformation relationship is L_{(g)}+A⇌D+C, L_{(g)}+A+B⇌S", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中双转变点的特性并写出其平衡关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较三元不变点中双转点的特征并写出其平衡关系，涉及多个概念的关联和综合分析，需要理解相变关系并进行适当的推理分析，但不需要创新或深度设计。 | 难度: 在简答题中属于较高难度，需要综合理解三元不变点的双转点特性，并准确写出其平衡关系式。题目要求不仅识别单共晶点和双转点的位置差异，还需表述相变关系，涉及多步概念关联和综合分析。" + }, + { + "idx": 238, + "question": "From an atomic scale perspective, explain the differences in the bonding mechanism of glass-to-metal sealing.", + "answer": "The sealing of glass and metal is governed by many factors. The most important factors affecting the seal are the following four aspects: (1) Oxidation of the metal: Before the hermetic sealing of glass and metal, the metal is usually moderately oxidized, placing the metal oxide between the glass and the metal. This step is essential for sealing and is also a microscopic control method for glass sealing. The oxidation treatment of the metal is the most critical factor affecting the sealing of glass and metal, and the oxidation mechanism is a key issue in sealing technology. (2) Thermal expansion coefficients of glass and metal: The consistency of the thermal expansion coefficients of glass and metal is a macroscopic control method for achieving good sealing. When the glass melt is sealed with the metal, the glass at high temperature has sufficient viscous fluidity. It deforms while simultaneously contracting along the thermal contraction curve of the metal. However, as the temperature decreases, the glass gradually loses its fluidity, causing it to separate from the metal's thermal contraction curve. This change is continuous and depends on the cooling rate, making it impossible to determine a specific temperature at which the glass separates from the metal's contraction curve. For convenience, a specific temperature TM is often used to represent the state when the glass is fixed to the metal. This means that when T > Tμ, the glass has complete fluidity and does not generate stress. When T < Ti1, the sealing glass contracts along its inherent thermal contraction curve. This specific temperature TM is called the solidification temperature, which is very close to the strain temperature of the glass. At any temperature T, a contraction difference ∠d is generated between the glass and metal, producing stress proportional to △d in the seal. When the stress exceeds the strength limit of the glass, the glass is damaged, affecting the hermeticity of the seal. Below the solidification temperature Ty, the relative relationship of the thermal contraction curves essentially reflects the matching degree of the expansion coefficients, i.e., the contraction difference between the glass and metal starting from Ty should be: △d = (ag - am)(T - T) (Equation 1-1). In Equation 1-1, ag and am represent the expansion coefficients of the glass and metal, respectively, from TM to the matching temperature T. To eliminate permanent stress in the glass, the seal must be annealed. Proper annealing is crucial for sealing quality. After annealing, the seal should not be cooled rapidly because the metal has better thermal conductivity than the glass, causing the metal to cool faster. When the expansion coefficients of the metal and glass are the same, this difference in cooling rates causes the metal to contract more than the glass. Once the glass loses fluidity, the metal must cool within a narrow range, and the length changes affect the adhesion between the glass and metal. If the rapid cooling starts at a temperature above the lower limit of the glass's annealing temperature, the glass will be in a stretched state. To prevent this tensile stress and to ensure the glass is slightly pressurized, the metal part is often heated separately with a gas flame after sealing. (3) Strength of the glass and interfacial diffusion: On the basis of matching the thermal expansion coefficients of the glass and metal, improving the mechanical strength of the glass, especially its tensile strength, is beneficial when the seal is subjected to thermal shock, thermal stress due to temperature gradients, or external forces during use. Generally, the compressive strength of glass can be very high, reaching 600~1500 MPa, while the tensile strength is extremely low, only about 10% of the compressive strength. In practice, only tensile strength poses problems. If possible, using crystallized glass for sealing is an effective way to improve the tensile strength of the glass, typically achieving 3~5 times or even more than 5 times the original tensile strength. It must be noted that the presence of a large number of bubbles (especially clustered bubbles) at the sealing interface is highly detrimental, as it can reduce mechanical strength and cause chronic leaks. Gas dissolved in the metal being released during sealing heating is one cause of bubbles, which is rare in metals like tungsten, molybdenum, and platinum but more common in nickel, iron, and their alloys. To eliminate this factor, metals produced by vacuum smelting are preferred, or the metal can be pre-degassed by heating in a vacuum or hydrogen atmosphere. Another cause of bubbles is carbon, especially in the surface layer of the metal, which oxidizes into carbon dioxide gas during sealing, forming bubbles. This is more severe in nickel, iron, and their alloys than in other metals. The solution is to anneal the metal in wet hydrogen or a vacuum to remove gas and carbon, thereby preventing bubble formation. The annealing temperature is generally 900~1100°C, and the duration depends on the thickness of the metal. Near the sealing interface, there are two scenarios: one involves direct mutual diffusion at the interface between two different materials, such as in glass-to-glass optical grinding seals or metal-to-metal welding. The other involves placing a different material at the interface to facilitate sealing, such as in glass-to-metal or ceramic-to-metal seals where direct mutual diffusion is difficult. In this case, melting diffusion occurs. However, whether mutual diffusion or melting diffusion occurs, the composition and properties near the interface differ from those in the bulk material, and this variation significantly affects the stability of the seal. (4) Shape, size, and surface roughness of the seal: The magnitude and distribution of stress within the seal are influenced by its shape and size. When the stress exceeds the strength limit of the sealing material, the seal is inevitably damaged. Generally, after sealing, if the seal is only a component of an electron tube or vacuum device and requires further processing or sealing with another similar device, it must undergo additional heat treatment or mechanical force. The temporary stress caused by external forces will combine with the thermal contraction stress between the materials. The combined effect of the permanent stress from thermal contraction differences and temporary stress from various causes is considerable. If the influence of shape and size on stress is overlooked, the stability of the seal may be compromised. For example, in production, the plasticity of thin metal edges can be utilized to reduce stress, or even the elasticity of the metal can be used for sealing. Additionally, adhesion tests have shown that if the substrate has uniform凹凸 (凹凸 refers to surface roughness or unevenness), the adhesion is good, which positively affects the sealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释玻璃与金属密封的键合机制差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求从原子尺度解释玻璃-金属封接的键合机制差异，涉及多个复杂因素的综合分析，包括金属氧化、热膨胀系数匹配、玻璃强度和界面扩散等。需要深入理解材料科学原理，并进行多方面的推理和解释，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 239, + "question": "Concentration gradient causes diffusion, does diffusion always proceed from high concentration to low concentration? Why?", + "answer": "Diffusion is caused by gradient differences, and concentration gradient is only one type of gradient difference. When another gradient difference, such as stress gradient, has a greater influence than the concentration gradient, diffusion can proceed from low concentration to high concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对扩散现象进行解释和论述，答案提供了详细的文字说明，涉及梯度差异的概念和不同类型梯度的影响，符合简答题的特征。 | 知识层次: 题目不仅考查扩散的基本概念（浓度梯度），还要求学生理解扩散可以受多种梯度影响（如应力梯度），并分析在不同条件下扩散方向可能逆转的原因。这需要综合运用多个概念，进行推理分析，解释机理，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目不仅要求解释扩散的基本概念（浓度梯度驱动），还需要考生综合运用其他梯度差异（如应力梯度）的知识，分析在特定条件下扩散方向可能逆转的复杂现象。这需要考生具备跨概念的综合分析能力和机理推理能力，符合等级5对复杂现象全面分析的要求。" + }, + { + "idx": 240, + "question": "A petrographic analysis of a certain Portland cement revealed that the flux mineral CA precipitated as a crystalline phase before CAF. Is this formulation a high-alumina formulation (P>1.38) or a high-iron formulation (P<1.38)?", + "answer": "It is a high-alumina formulation (P>1.38).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两个明确的选项（高铝配方或高铁配方）中选择正确答案，答案也是直接给出了其中一个选项作为正确答案。 | 知识层次: 题目需要理解波特兰水泥的矿物组成及其相变行为，并应用P值（铝铁比）的概念来判断水泥配方的类型。这涉及到多步分析和概念关联，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于较高难度，需要理解水泥矿物相变顺序与铝率(P值)的关系，进行多步逻辑推理和综合分析。题目要求考生将相变顺序(CA先于CAF析出)与铝率计算公式关联，并判断P值范围，涉及多个专业概念的整合应用。" + }, + { + "idx": 241, + "question": "Compare the characteristics of polymorphic transition points in ternary invariant points and write their equilibrium relationships", + "answer": "Polymorphic transition points are the temperature points at which two or three crystal forms undergo crystal transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中的多晶型转变点特征并写出它们的平衡关系，这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了概念性的解释而非具体数值或选项。 | 知识层次: 题目要求比较三元不变点中多晶转变点的特性并写出平衡关系，涉及多个概念的关联和综合分析，需要理解多晶转变点的定义并能够将其应用于三元系统的平衡关系分析中。 | 难度: 在简答题题型中，该题目要求对多晶型转变点在三元不变点中的特性进行比较，并写出它们的平衡关系。这需要考生不仅理解多晶型转变的基本概念，还需要能够综合分析不同晶体形式之间的转变关系，并在三元系统中进行多角度分析。题目涉及的知识点较为深入，解题步骤包括概念理解、特性比较和平衡关系的推导，属于多角度分析论述的难度等级。" + }, + { + "idx": 242, + "question": "How should the cooling rate in the clinkering zone be controlled for high-alumina formulations (P>1.38)?", + "answer": "For formulations with an alumina modulus P>1.38, when the melt cools past the KT2 boundary, the liquid phase will reabsorb C3S and precipitate C2S and CsA. Therefore, if the clinker is cooled slowly in the clinkering zone, bringing the cooling process close to equilibrium, some C3S will be reabsorbed, which is detrimental to cement quality. Hence, for formulations with P>1.38, rapid cooling should be employed during the cooling process in the clinkering zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对高铝配方的冷却速率控制进行解释和论述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释高铝配方（P>1.38）在熟料带冷却速率的控制原理，涉及相变过程（KT2边界）、液相重新吸收C3S和析出C2S和CsA的机理分析，以及冷却速率对水泥质量的影响。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求考生不仅要理解高铝配方（P>1.38）在冷却过程中的相变机理，还需要综合运用相关知识，分析冷却速率对水泥质量的影响，并给出合理的控制措施。解题过程涉及多个步骤的推理和解释，要求考生具备较高的综合分析能力和机理理解深度。因此，在同题型内属于最高难度等级。" + }, + { + "idx": 243, + "question": "The batching of high-alumina cement is usually selected within the range of the CA phase region, and it is often produced by firing to melting and then cooling. The main mineral of high-alumina cement is CA, and C2AS has no hydraulic properties, so it is desirable that the cement does not contain C2AS. Therefore, what range of batching should be chosen within the CA phase region, and why (note that complete equilibrium cannot be achieved during production, and independent crystallization processes may occur)?", + "answer": "High-alumina cement has the characteristic of rapid hardening and is widely used in the defense industry. The batching range is Al2O3 35%~55%, CaO 35%~45%, SiO2 5%~10%, Fe2O3 0~15%. This can prevent the formation of C2AS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么选择特定的配料范围，并需要论述防止C2AS形成的原理。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高铝水泥配料范围的选择，并解释为什么选择这个范围以防止C2AS的形成。这需要综合运用材料科学中的相图知识、矿物学特性以及生产工艺的限制条件。此外，题目还提到了生产过程中无法达到完全平衡和可能发生的独立结晶过程，这增加了分析的复杂性，需要对材料科学中的相变和结晶过程有深入的理解和推理能力。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用材料科学知识进行推理分析，并解释机理。具体体现在：" + }, + { + "idx": 244, + "question": "How should the cooling rate of high iron composition (P<1.38) in the burning zone be controlled?", + "answer": "For compositions with an alumina modulus P<1.38, the melt cooling and crystallization process passes through the WT2 boundary, where the liquid phase absorbs C2S back and precipitates CsS and C4AF. Therefore, the slower the clinker cooling rate, the closer it approaches equilibrium, and the more fully C2S is absorbed back. The content of CS in the clinker will increase, which is beneficial for cement quality. Thus, for clinker with P<1.38, the cooling rate in the burning zone should be appropriately slowed down.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何控制高铁成分的冷却速率，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及对高铁成分在燃烧区冷却速率的控制机制的理解，需要分析熔体冷却和结晶过程中的相变行为，以及不同冷却速率对水泥熟料矿物组成和性能的影响。这要求综合运用材料科学和热力学知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题-复杂分析题型中，该题目要求对高铁成分熟料在烧成区的冷却速率控制进行全面的机理分析和综合推理。需要深入理解相平衡边界(WT2边界)的物理化学过程，解释液相吸收C2S并析出CsS和C4AF的复杂相变机制，同时需要将冷却速率与水泥质量的关系进行系统论证。这种需要综合多因素、解释复杂相变机理并推导工艺控制方案的题目，在该题型内属于最高难度等级。" + }, + { + "idx": 245, + "question": "The diffusion coefficient values of CaO at 1145°C and 1650°C", + "answer": "As shown in the figure, the diffusion coefficient values of CaO at 1145°C and 1650°C are D1 and D2, respectively (specific values need to be read from the figure).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表中的数据（扩散系数值）进行描述和解释，答案需要文字说明具体数值的来源和含义，而不是进行计算或选择选项。 | 知识层次: 题目要求根据图表读取扩散系数值，属于基本公式应用和简单计算范畴，不需要多步计算或综合分析。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求根据图示读取扩散系数值并简单说明，无需深入分析或复杂计算。解题步骤直接，仅需基本的数据读取和简单描述，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 246, + "question": "The diffusion coefficient values of Al2O3 at 1393°C and 1716°C", + "answer": "As shown in the figure, the diffusion coefficient values of Al2O3 at 1393°C and 1716°C are D3 and D4, respectively (specific values need to be read from the figure).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表中的数据（扩散系数值）进行描述和解释，答案需要文字说明和具体数值的读取，属于简答题类型。 | 知识层次: 题目要求根据图表读取扩散系数的具体数值，属于基本数据的直接应用，不需要复杂的计算或分析过程。 | 难度: 在简答题中属于简单应用过程描述。题目要求根据图表读取扩散系数值并对应温度，属于直接套用已知信息的过程，无需复杂计算或深入解释。解题步骤简单，仅需识别图表中的数值并正确对应温度，符合等级2对基本公式应用和简单计算的要求。" + }, + { + "idx": 247, + "question": "Provide a full explanation of the various property value estimates you made in the calculation. The Schottky defect formation energy of CaO is known to be 6eV.", + "answer": "The property values used in the calculation include: Schottky defect formation energy ΔHf = 6 eV, converted to joules as 6 × 1.6 × 10^-19 J; Avogadro's constant NA = 6.23 × 10^23 mol^-1; gas constant R = 8.314 J/(mol·K); melting point temperature T = 2600℃ = 2873 K. These values are used to calculate the Schottky defect concentration [V′′Ca] = exp(-ΔHf / 2RT).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提供详细的解释和论述，说明在计算中使用的各种属性值估计，答案也以文字解释的形式呈现，没有涉及具体计算步骤或公式应用，更侧重于对概念和参数的理解和描述。 | 知识层次: 题目涉及多步计算和概念关联，需要将Schottky缺陷形成能量转换为其他单位，并结合Avogadro常数、气体常数和熔点温度进行综合分析，以计算缺陷浓度。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在简答题中属于中等难度，需要综合运用多个概念（如缺陷形成能、单位转换、常数应用）并进行多步计算。虽然涉及公式推导和单位转换，但整体思路清晰，属于典型的应用型题目，未达到需要多角度或深度关联性分析的程度。" + }, + { + "idx": 248, + "question": "Given the diffusion data of hydrogen in face-centered cubic iron as D_Ni = 0.0063 exp(-10300 × 4.18 / RT) cm²/s, calculate the diffusion coefficient at 1000°C.", + "answer": "Substituting T=1000°C into the equation yields D_H=3.6×10^-5 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散方程和温度值进行数值计算，最终得出扩散系数的具体数值。答案是一个具体的计算结果（3.6×10^-5 cm²/s），这符合计算题的特征。 | 知识层次: 题目要求直接套用给定的扩散系数公式进行数值计算，仅需简单的代数运算和单位转换，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，只需要直接套用给定的扩散系数公式，并进行简单的数值计算。不需要额外的公式组合或复杂的解题步骤，属于单一公式直接计算的范畴。" + }, + { + "idx": 249, + "question": "What concentration of trivalent ions is required to ensure that the diffusion of Ca2+ in CaO remains non-intrinsic up to the melting point of CaO (2600°C)? The Schottky defect formation energy of CaO is known to be 6eV.", + "answer": "The defect reaction for doping M3+ is as follows: M2O3 → 2M′′Ca + V′′Ca + 3OO. When CaO is at its melting point, the concentration of Schottky defects is: [V′′Ca] = exp(-ΔHf / 2RT) = exp(-6 × 1.6 × 10^-19 × 6.23 × 10^23 / (2 × 8.314 × 2873)) = 3.6 × 10^-6. Therefore, to ensure that the diffusion of Ca2+ in CaO remains non-intrinsic up to the melting point of CaO (2600°C), the concentration of M3+ must be [M3+] = [M′′Ca] = 2[V′′Ca] > [V′′Ca], i.e., [M3+] > 2 × 3.6 × 10^-6 = 7.2 × 10^-6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定所需的浓度，解答过程中涉及到了Schottky缺陷形成能的计算和浓度关系的推导，这些都是典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括应用Schottky缺陷形成能公式计算缺陷浓度，并理解非本征扩散的条件。虽然涉及一定的综合分析，但整体上仍属于中等应用层次，因为主要依赖于已有公式和概念的直接应用，而不需要深入的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解Schottky缺陷的形成能概念，应用Arrhenius方程计算缺陷浓度，并通过化学计量关系推导掺杂离子浓度。虽然涉及多步骤计算和概念关联，但计算过程相对直接，没有引入复杂变量或高级数学工具。" + }, + { + "idx": 250, + "question": "Calculate the diffusion activation energy Q and D0 value of Ca2+ in CaO", + "answer": "According to D=D0exp(-Q/RT), the ratio of diffusion coefficients of CaO at 1145°C and 1650°C can be used to calculate Q and D0. The specific calculation process is: D1/D2 = exp[-Q/R(1/T1 - 1/T2)], where T1=1418K(1145°C), T2=1923K(1650°C). Solving this equation yields the Q value, and substituting the diffusion coefficient at either temperature gives D0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散激活能Q和D0值，解答过程涉及具体的温度转换、公式代入和数值求解步骤，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解扩散激活能的概念，并运用阿伦尼乌斯方程进行推导和计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散公式进行多步计算，涉及温度转换、对数运算和代数求解。虽然计算过程明确，但需要学生理解扩散系数的温度依赖性并正确关联实验数据，属于中等应用层次的计算题。" + }, + { + "idx": 251, + "question": "Given the diffusion data of nickel in face-centered cubic iron as D_Ni = 4.1 exp(-64000 × 4.18 / RT) cm²/s, calculate the diffusion coefficient at 1000°C.", + "answer": "Substituting T=1000°C into the equation yields D_Ni=4.35×10^-11 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散方程和温度条件进行数值计算，最终得出扩散系数的具体数值。答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目要求直接套用给定的扩散系数公式进行数值计算，属于基本的公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，只需要直接套用给定的扩散系数公式，进行简单的数值代入和计算即可得到结果。不需要额外的公式组合或复杂的推导过程。" + }, + { + "idx": 252, + "question": "Calculate the diffusion activation energy Q and D0 value of Al3+ in Al2O3", + "answer": "According to D=D0exp(-Q/RT), the ratio of diffusion coefficients of Al2O3 at 1393℃ and 1716℃ can be used to calculate Q and D0. The specific calculation process is: D3/D4 = exp[-Q/R(1/T3 - 1/T4)], where T3=1666K(1393℃), T4=1989K(1716℃). Solving this equation yields the Q value, and substituting it into the diffusion coefficient at any temperature gives D0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散激活能Q和D0值，解答过程涉及具体的数学运算和公式推导。 | 知识层次: 题目要求计算扩散激活能Q和D0值，涉及多步计算和公式应用，需要理解扩散系数的温度依赖性并运用阿伦尼乌斯方程进行推导。虽然不涉及复杂的机理分析或创新设计，但需要综合运用相关概念和数学计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散激活能的概念，掌握阿伦尼乌斯方程的应用，并进行多步计算和温度转换。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有涉及复杂多变量或高级数学工具，因此在计算题中属于中等难度。" + }, + { + "idx": 253, + "question": "Explain the difference in diffusion coefficients between hydrogen and nickel in face-centered cubic iron.", + "answer": "Compared to nickel atoms, hydrogen atoms are much smaller and can diffuse more easily through the gaps in face-centered cubic iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释氢和镍在面心立方铁中扩散系数的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释不同元素在面心立方铁中的扩散系数差异，需要理解扩散机制、原子尺寸效应以及晶体结构的影响，属于多概念关联和综合分析。虽然不涉及复杂计算，但需要对材料科学中的扩散现象有较深入的理解和应用能力。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求解释氢和镍在面心立方铁中的扩散系数差异，但答案主要基于原子尺寸差异这一单一因素进行说明，没有涉及更复杂的多步计算或深度关联性分析。解题步骤相对直接，只需理解原子尺寸对扩散的影响这一核心概念即可完成回答，符合\"综合分析和说明\"的等级特征。" + }, + { + "idx": 254, + "question": "When Zn2+ diffuses in ZnS, the diffusion coefficient at 563°C is 3×10−4cm2/s, and at 450°C it is 1.0×10−4cm2/s. Calculate the activation energy for diffusion and D0.", + "answer": "Referring to 7-4, Q=48856J/mol, D0=3×10−15cm2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散的激活能和D0值，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及温度与扩散系数的关系，以及激活能和D0的求解，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、对数运算和方程求解，同时需要理解扩散系数与温度的关系。虽然计算步骤明确，但需要综合运用多个概念和数学技能，属于中等偏上的难度。" + }, + { + "idx": 255, + "question": "Given that the activation energy Q for Zn2+ diffusion in ZnS is 48856 J/mol, and D0=3×10−15 cm2/s, calculate the diffusion coefficient at 750°C.", + "answer": "Substituting T=1023K into D=D0exp(−Q/RT) yields D1023=9.6×10−4 cm2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值。答案是一个计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目要求直接套用扩散系数的计算公式，进行简单的数值计算，不需要多步推理或综合分析，属于基本公式的直接应用。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要将给定的数值代入扩散系数公式D=D0exp(−Q/RT)中进行简单计算，不需要额外的公式组合或复杂的解题步骤。" + }, + { + "idx": 256, + "question": "The diffusion coefficients of carbon in titanium measured at different temperatures are 2×10−9cm2/s (736℃), 5×10−9cm2/s (782℃), and 1.3×10−8cm2/s (838℃). Please calculate the activation energy for diffusion.", + "answer": "From the previous step, it is known that Q=2342787J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用公式计算扩散的活化能，答案是一个具体的数值计算结果。 | 知识层次: 题目需要应用阿伦尼乌斯方程进行多步计算，涉及对数运算和线性回归分析，属于中等应用层次。虽然不涉及复杂的机理分析或创新设计，但需要将多个概念（扩散系数、温度、活化能）关联起来进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和线性回归分析，但变量和计算步骤相对明确，属于中等应用层次。" + }, + { + "idx": 257, + "question": "The diffusion coefficients of carbon in titanium at different temperatures were experimentally measured as 2×10−9cm2/s (736℃), 5×10−9cm2/s (782℃), and 1.3×10−8cm2/s (838℃). Given the activation energy for diffusion Q=2342787J/mol, determine the diffusion coefficient of carbon at 500℃.", + "answer": "Substituting T=773K into D=D0exp(−Q/RT), with Q=2342787J/mol known, D0 is derived from D̅1=2×10−9cm2/s and T1=1009K as D0=2×10−9exp(2342787/(8.31×1009)). The calculated D500℃=1.87×10−10cm2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和激活能，应用阿伦尼乌斯公式进行数值计算，最终得出特定温度下的扩散系数。答案涉及具体的数值计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，包括从已知数据推导前置指数因子D0，再计算新温度下的扩散系数。这涉及对公式的理解和转换，以及数值计算能力，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握扩散系数的计算公式，理解激活能的概念，并能正确进行多步计算。题目要求从已知数据推导出D0，再应用到新的温度条件下，涉及多个计算步骤和概念的综合运用，但未达到复杂多变量计算的级别。" + }, + { + "idx": 258, + "question": "The diffusion coefficients of carbon in titanium were experimentally measured at different temperatures as 2×10−9cm2/s (736℃), 5×10−9cm2/s (782℃), and 1.3×10−8cm2/s (838℃). Please determine whether the experimental results conform to D̅=D̅0exp(−ΔG/RT).", + "answer": "Substituting D̅1=2×10−9cm2/s, D̅2=5×10−9cm2/s, D̅3=1.3×10−8cm2/s, T1=1009K, T2=1055K, T3=1111K into D=D0exp(−ΔG/RT) and following the method used in 7-4 yields Q1=2342787J/mol. Similarly, substituting D̅2, D̅3, T2, T3 gives Q2=2342132J/mol. It can be concluded that the experiment conforms to D=D0exp(−ΔG/RT).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过代入实验数据和公式进行计算，验证扩散系数与温度的关系是否符合给定的方程。解答过程涉及数值计算和公式应用，最终得出定量结论。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及不同温度下的数据代入和比较，需要一定的综合分析能力，但不需要复杂的推理或创新设计。 | 难度: 在计算题-需要数值计算和公式应用题型中，该题目属于综合性计算问题。题目要求将实验数据代入扩散系数公式并进行多步计算，同时需要理解扩散系数与温度的关系（D=D0exp(−ΔG/RT)）。虽然计算过程较为直接，但涉及多个数据点的处理和比较，需要一定的综合分析能力。相比更简单的单步计算问题（等级2），该题目复杂度更高，但尚未达到需要处理复杂多变量或非常规计算方法的等级4难度。" + }, + { + "idx": 259, + "question": "Calculate the diffusion coefficient of carbon in α-Fe (body-centered cubic), given the diffusion coefficient formula as D=0.0079exp[-83600/RT] cm²/s, temperature T=800°C (1073K), and gas constant R=8.314 J/(mol·K).", + "answer": "Substitute T=1073K into the formula D=0.0079exp[-83600/(8.314×1073)] cm²/s, and calculate to obtain D_α=6.7×10^-7 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值。解答过程涉及公式代入和数学运算，符合计算题的特征。 | 知识层次: 题目要求直接套用给定的扩散系数公式进行数值计算，属于基本的公式应用和简单计算，不需要多步推导或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需将给定数值代入公式并进行简单计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 260, + "question": "In a certain material, the grain boundary diffusion coefficient and volume diffusion coefficient of a certain particle are $\\mathrm{D}_{\\mathrm{sb}}{=}2.00\\times{10}^{-10}\\mathrm{exp(-}$ 19100/RT) $\\mathrm{cm}^{2}/\\mathrm{s}$ and $\\mathrm{D}_{\\mathrm{v}}{=}1.00\\times\\mathrm{10}^{-4}\\mathrm{exp}$ (－38200/RT) cm²/s, respectively. Determine the temperature ranges in which the grain boundary diffusion coefficient and volume diffusion coefficient dominate.", + "answer": "When the grain boundary diffusion coefficient dominates, $\\mathrm{D}_{\\mathrm{gb}}>\\mathrm{D}_{\\mathrm{v}}$, i.e., $2.00\\times10^{-10}\\exp(-\\frac{19100}{R T})$ $1.00\\times10^{-4}\\exp(-\\frac{38200}{R T})$. Thus, T<1455.6K; when T>1455.6K, the volume diffusion coefficient dominates.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定温度范围，解答过程中涉及到了指数函数的比较和温度的计算，属于典型的计算题。 | 知识层次: 题目需要应用扩散系数的公式，进行多步计算和综合分析，以确定温度范围。涉及对公式的理解和数值计算，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散系数的概念，掌握指数函数的性质，并进行多步计算和不等式求解。虽然涉及多个步骤，但计算过程相对直接，没有引入复杂变量或需要高级数学技巧。" + }, + { + "idx": 261, + "question": "In the fabrication of silicon semiconductor devices, boron is often diffused into silicon single crystals. If at a temperature of 1600K, the boron concentration on the surface of the silicon single crystal is kept constant (constant source semi-infinite diffusion), and the boron concentration at a depth of $10^{-3}\\\\mathrm{cm}$ from the surface is required to be half of the surface concentration (erfc =0.5 $\\\\frac{x}{2\\\\sqrt{D t}}$ 0.5), how long is needed (given $\\\\boldsymbol{D_{1600^{*}C}}=8\\\\times10^{-12}\\\\mathrm{{cm}^{2}/{s}}$ when 2√Dt, 2√D# )?", + "answer": "This model can be regarded as a one-dimensional diffusion problem of a semi-infinite rod, which can be solved using the Gaussian error function. $\\\\frac{C_{0}-C}{C_{0}-C_{1}}=\\\\mathrm{erf}(\\\\frac{x}{2\\\\sqrt{D t}})$ where $\\\\mathcal{C}_{1\\\\mathrm{~=~}0}$, $C=0.5C_{0}$, so there is $\\\\cot(\\\\frac{x}{2\\\\sqrt{D t}})$, 2=0.5. Substituting $x=10^{-3}\\\\mathrm{cm}$ and $D=8\\\\times10^{-12}\\\\mathrm{{cm}^{2}/\\\\mathrm{{s}}}$ yields $t=1.25\\\\times10^{5}\\\\mathrm{~s~}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和误差函数的计算，最终需要求出时间t的具体数值。答案也给出了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解扩散方程的应用，并正确代入数值进行计算。虽然公式直接给出，但需要正确理解边界条件和误差函数的应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散模型并应用高斯误差函数进行多步计算。题目涉及多个概念（如半无限扩散、恒定表面浓度）和公式转换，同时需要正确代入数值并求解时间参数。虽然计算步骤明确，但需要较强的综合分析能力和对扩散理论的掌握，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 262, + "question": "Explain the difference in diffusion coefficients of carbon in α-Fe and γ-Fe.", + "answer": "The structure of the diffusion medium has a significant impact on diffusion. α-Fe has a body-centered cubic structure, while γ-Fe has a face-centered cubic structure. The body-centered cubic structure is more open than the face-centered cubic structure. A more open structure results in lower diffusion resistance and a higher diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释碳在α-Fe和γ-Fe中扩散系数的差异，答案通过文字论述了两种晶体结构的区别及其对扩散系数的影响，符合简答题的特征。 | 知识层次: 题目要求解释碳在α-Fe和γ-Fe中扩散系数的差异，需要理解晶体结构（体心立方和面心立方）对扩散的影响，并进行机理上的分析和比较。这涉及到对晶体结构、扩散机制和材料性能之间关系的深入理解，属于综合运用和推理分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对α-Fe和γ-Fe的晶体结构差异及其对扩散系数的影响进行机理层面的解释。需要综合运用晶体结构知识和扩散理论，分析不同晶体结构的空间特性如何影响扩散阻力。虽然不涉及多因素交互作用的全面分析（等级5特征），但已经达到机理深度解释的要求（等级4特征），属于该题型中较高难度的题目。" + }, + { + "idx": 263, + "question": "Calculate the diffusion coefficient of carbon in γ-Fe (face-centered cubic), given the diffusion coefficient formula as D=0.21exp[-141284/RT] cm²/s, temperature T=800°C (1073K), and gas constant R=8.314 J/(mol·K).", + "answer": "Substitute T=1073K into the formula D=0.21exp[-141284/(8.314×1073)] cm²/s, and calculate to obtain D_γ=2.1×10^-8 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，只需将给定的数值代入公式并进行计算即可得到结果，无需多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，只需要直接套用给定的单一公式进行数值计算，无需多个公式组合或复杂推导。解题步骤仅涉及简单的温度单位转换和指数运算，属于基本公式应用范畴。" + }, + { + "idx": 264, + "question": "The diffusion activation energies of carbon, nitrogen, and hydrogen in body-centered cubic iron are 84 kJ/mol, 75 kJ/mol, and 13 kJ/mol, respectively. Analyze and explain this difference.", + "answer": "The atomic radii of carbon, nitrogen, and hydrogen decrease sequentially. The smaller the atomic radius, the easier it is for the atom to diffuse through the gaps in body-centered cubic iron, and the lower the corresponding diffusion activation energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析并解释碳、氮、氢在体心立方铁中扩散激活能的差异，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求分析不同元素在体心立方铁中的扩散激活能差异，需要综合运用原子半径、晶体结构间隙和扩散机制等知识进行推理分析，涉及多个概念的关联和机理解释。 | 难度: 在简答题中属于机理深度解释难度，需要理解原子半径与扩散激活能的关系，并能解释不同元素在体心立方铁中的扩散行为差异。虽然涉及多个知识点，但不需要进行复杂的现象全面分析或跨领域综合推理。" + }, + { + "idx": 265, + "question": "Analyze the reasons why the diffusion coefficient of anions is generally smaller than that of cations in ionic crystals.", + "answer": "In ionic crystals, anions generally form close packing, while cations fill the tetrahedral or octahedral voids. Therefore, cations diffuse more easily. If anions diffuse, the crystal packing arrangement must be altered, disrupting the structural framework of the ionic crystal, which results in greater resistance. Hence, in ionic crystals, the diffusion coefficient of anions is generally smaller than that of cations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析离子晶体中阴离子扩散系数通常小于阳离子的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析离子晶体中阴离子扩散系数小于阳离子的原因，涉及晶体结构、扩散机制和能量障碍的综合理解。需要运用晶体学知识解释阴离子和阳离子的位置差异，并分析扩散过程中结构变化带来的能量障碍，属于机理层面的解释和推理分析。 | 难度: 在简答题的复杂分析题型中，该题目要求对离子晶体中阴离子和阳离子扩散系数的差异进行机理深度解释。需要综合运用晶体结构、扩散机制等知识，分析阴离子扩散受阻的结构性原因，并解释其对扩散系数的影响。虽然不涉及多因素交互作用的全面分析，但对单一现象的机理解释要求较高，属于该题型中的较难题目。" + }, + { + "idx": 266, + "question": "What are the advantages, disadvantages, and applicable conditions of the Jander equation?", + "answer": "The Jander equation has good adaptability in the initial stage of the reaction, but the Jander model assumes that the cross-section of spherical particles remains unchanged. Therefore, it is only applicable to cases with low conversion rates in the initial stage of the reaction. Both equations are only applicable to stable diffusion conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Jander方程的优缺点和适用条件，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求分析Jander方程的优缺点和适用条件，需要理解该方程的基本原理并能够进行综合分析，涉及多步概念关联和条件判断，但不需要进行复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对Jander方程进行多角度分析，包括其优点、缺点和适用条件。需要综合运用材料科学中的扩散理论和反应动力学知识，进行概念关联和综合分析。虽然不涉及复杂的数学推导，但需要对理论模型有深入理解，并能准确描述其适用范围和局限性，这在该题型内属于较高难度的要求。" + }, + { + "idx": 267, + "question": "What are the advantages, disadvantages, and applicable conditions of the Ginstling equation?", + "answer": "The Ginstling equation takes into account the fact that the reaction cross-sectional area changes during the reaction process, thus the Ginstling equation has a wider range of application and can be suitable for the initial and middle stages of the reaction. Both equations are only applicable to steady-state diffusion conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Ginstling方程的优缺点和适用条件，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求分析Ginstling方程的优缺点和适用条件，涉及对特定方程的理解和应用，需要将多个概念（如反应截面变化、稳态扩散条件等）进行关联和综合分析。虽然不涉及复杂计算或深度推理，但需要一定程度的理解和应用能力，超出了简单记忆或直接套用的层次。 | 难度: 在简答题题型中，该题目要求对Ginstling方程的优缺点及适用条件进行多角度分析论述。需要考生不仅理解方程的基本原理，还要能够从多个方面（如适用范围、反应阶段等）进行综合分析，并与其他相关概念（如稳态扩散条件）进行关联。这种要求超出了简单的概念解释或单一分析，属于该题型中较高难度的题目。" + }, + { + "idx": 268, + "question": "Explain from the perspectives of structure and energy why $\\mathrm{D}_{\\rightleftarrows\\mathrm{m}}>\\mathrm{D}_{\\rightleftarrows\\mathrm{m}}>\\mathrm{D}$ within the crystal.", + "answer": "Under the influence of surface forces, the particles on the solid surface undergo polarization, deformation, rearrangement, and cause lattice distortion, making the surface structure different from the interior and placing the surface in a higher energy state. The internal particles of the crystal are arranged periodically, with each particle's force field being symmetrical. The activation energy required for particle migration on the surface is smaller than that within the crystal, resulting in a larger diffusion coefficient. Similarly, the arrangement of particles at grain boundaries differs from the interior, being disordered and containing defects such as vacancies and dislocations, placing them in a state of stress distortion with higher energy. The activation energy required for particle migration at grain boundaries is smaller than that within the crystal, leading to a larger diffusion coefficient. However, compared to the interior of the crystal, particles at grain boundaries are influenced by two grains to reach an equilibrium state, adopting a transitional arrangement with lower energy than surface particles. Thus, the resistance to particle migration is greater, resulting in $\\mathrm{D}_{\\mathrm{~\\rightmoon~}}\\mathrm{\\approx}{}$ the surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从结构和能量的角度解释晶体中扩散系数的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从结构和能量的角度解释晶体中不同区域的扩散系数差异，涉及表面力、极化、晶格畸变、晶界缺陷等多个复杂概念的综合运用和机理解释，需要深入分析和推理不同区域的能量状态和粒子迁移的激活能差异，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体结构、表面能、扩散机理等多方面知识进行深度解释和全面分析。需要理解并阐述表面和晶界处的粒子排列差异、能量状态变化、扩散系数差异的物理机制，并能比较不同区域的扩散能力差异。这种需要多维度知识整合和机理推导的题目，在同类题型中属于最高难度级别。" + }, + { + "idx": 269, + "question": "For spherical Al2O3 particles with a diameter of 1μm surrounded by excess MgO particles, the formation of spinel is observed. At a constant temperature, 20% of the Al2O3 reacts in the first hour. Calculate the time required for complete reaction using the Jander equation.", + "answer": "Calculation using the Jander equation: [1-(1-G)^(1/3)]^2 = kt ⇒ k = [1-(1-G)^(1/3)]^2 / t Substituting the reaction time of 1h and reaction progress of 20% given in the problem, we obtain k = [1-(1-0.2)^(1/3)]^2 / 1 = 5.138×10^-3 h^-1 Therefore, the time required for complete reaction (G=1) is t = 1/k = 1/(5.138×10^-3) = 194.62 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用Jander方程进行数值计算，以确定完全反应所需的时间。答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用Jander方程进行多步计算，包括根据已知条件计算反应速率常数k，再推导完全反应所需时间。虽然计算过程相对直接，但涉及公式的变形和数值代入，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用Jander方程进行多步计算，包括反应速率常数的推导和最终反应时间的求解。虽然计算步骤明确，但需要对反应动力学和数学变换有较好的理解，属于中等偏上的难度。" + }, + { + "idx": 270, + "question": "When measuring the decomposition rate of alumina monohydrate, it was found that during the isothermal reaction, the mass loss increased linearly with time up to about 50%, and the rate of mass loss was less than the linear law when exceeding 50%. The rate increases exponentially with temperature. Is this a diffusion-controlled reaction or an interface first-order reaction-controlled reaction?", + "answer": "According to the analysis of the kinetic equations for some important solid-phase reactions in Table 8-2 and the G-t/t0.5 curves for various types of reactions in Figure 8-22, it is known from the problem statement that when G ≤ 50%, G-t shows a linear relationship, and when G > 50%, G-t is less than the linear law. This is a diffusion-controlled reaction, and G² = kt.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来判断反应类型，答案提供了详细的分析过程和结论，符合简答题的特征。 | 知识层次: 题目要求分析氧化铝单水合物分解反应的动力学控制机制，需要综合运用动力学方程和反应类型曲线（G-t/t0.5）进行推理判断。涉及多步骤分析（线性阶段与非线性阶段的对比）、温度对反应速率的影响机制解释，以及扩散控制与界面反应控制的特征区分，属于典型的机理分析与综合推理层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生综合运用动力学方程和反应类型曲线（表8-2和图8-22）进行分析，并解释质量损失与时间的关系变化（线性到非线性转变）。需要理解扩散控制反应的特征（G²=kt关系），并能将实验现象与理论模型准确对应。虽然不涉及多变量交互作用的全面分析（等级5特征），但对反应机理的推导和解释深度已达到等级4要求。" + }, + { + "idx": 271, + "question": "When the temperature increases from 451°C to 493°C, the rate increases by a factor of 10. Calculate the activation energy of this process. (Analyze using Table 8-2 and Figure 8-22)", + "answer": "k=c exp(-Q/RT), and since G²=kt, substituting T₁=451°C=724K, T₂=493°C=766K, G₁=G, G₂=10G, we get k₂/k₁=G₂²/G₁²=exp(-Q/RT₂)/exp(-Q/RT₁)=100. Solving for Q gives Q=RT₁T₂ln(k₂/k₁)/(T₂-T₁)=8.314×724×766×ln(100)/(766-724)=505.561×10³ J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解激活能，答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解阿伦尼乌斯方程并正确代入温度转换后的数值进行计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度单位转换、对数运算和代数求解。虽然计算步骤较多，但每一步都有明确的数学和物理基础，属于中等应用层次的计算题。" + }, + { + "idx": 272, + "question": "What is phase transition?", + "answer": "Phase transition is the mutual transformation between different phases of a material system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"phase transition\"进行文字解释和论述，答案提供了概念的定义和描述，符合简答题的特征 | 知识层次: 题目考查相变这一基本概念的定义，属于基础概念的记忆和理解范畴，不涉及应用或分析等更高层次的认知能力。 | 难度: 在简答题题型中，该题目仅要求回答相变的基本定义，属于最基础的概念记忆性知识。不需要额外的解释、描述或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 273, + "question": "The formation reaction of mullite from Al2O3 and SiO powders is diffusion-controlled and conforms to the Jander equation. What effective measures should be taken to accelerate the formation of mullite?", + "answer": "All factors favorable for diffusion can be employed to accelerate the formation of mullite: reducing particle size, using reactive reactants (such as Al2O3·3H2O), applying appropriate pressure, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出有效措施来加速莫来石的形成，答案提供了文字解释和论述，列举了多种可行的方法，符合简答题的特征。 | 知识层次: 题目要求考生理解扩散控制反应的基本原理（Jander方程），并能够综合分析多种促进扩散的措施（如减小颗粒尺寸、使用活性反应物、施加适当压力等）。这需要将多个概念关联起来，并进行一定程度的综合分析，但不需要进行复杂的机理推理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解扩散控制反应的基本原理，并能够列举出促进扩散的具体措施。虽然涉及多个概念（如Jander方程、扩散控制反应、粒子尺寸效应等），但不需要进行复杂的计算或深度关联性分析。主要考察学生对基础知识的掌握和应用能力。" + }, + { + "idx": 274, + "question": "Spherical Al2O3 particles with a diameter of 1μm are surrounded by excess MgO particles, and the formation of spinel is observed. At a constant temperature, 20% of the Al2O3 reacts in the first hour. Use the Ginstling equation to calculate the time required for complete reaction.", + "answer": "Calculation using the Ginstling equation:\\n\\n1-(2/3)G-(1-G)^(2/3) = kt ⇒ k = [1-(2/3)G-(1-G)^(2/3)] / t\\n\\nSimilarly, substituting the reaction time of 1h and reaction progress of 20% from the problem, we get\\n\\nk = [1-(2/3)×0.2-(1-0.2)^(2/3)] / 1 = 4.893×10^-3 h^-1\\n\\nTherefore, for complete reaction (G=1),\\n\\n1-(2/3)G-(1-G)^2 = kt ⇒ kt = 1/3\\n\\nThus, the time required for complete reaction is t = 1/(3k) = 1/(3×4.893×10^-3) = 68.12 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用Ginstling方程进行数值计算，以确定完全反应所需的时间。答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用Ginstling方程进行多步计算，涉及反应进度与时间的关系推导，并需要将给定的反应进度和时间代入方程求解速率常数，最后计算完全反应所需时间。这要求对动力学方程的理解和综合应用能力，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用Ginstling方程进行多步计算，包括反应速率常数的推导和最终反应时间的求解。虽然计算步骤较多，但每个步骤都有明确的数学逻辑，不需要处理复杂多变量或非常规转换。" + }, + { + "idx": 275, + "question": "Analyze the influence of the chemical composition and structure of reactants on solid-phase reactions", + "answer": "The greater the interaction force between particles in the reactants, the lower the reaction capability; in the same reaction system, the solid-phase reaction rate is related to the proportion between the reactants; the special role of mineralizers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析反应物的化学组成和结构对固相反应的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析反应物化学组成和结构对固相反应的影响，涉及多个因素的相互作用和综合分析，需要理解反应机理并进行推理分析，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对固体相反应的化学组成和结构影响进行机理深度解释。需要综合运用材料科学、化学反应动力学等知识，分析粒子间作用力、反应物比例和矿化剂作用等多个因素之间的复杂关系。虽然不涉及跨学科整合或极端复杂的推导（如等级5的要求），但仍需深入理解反应机理并系统阐述，属于该题型中较高难度的题目。" + }, + { + "idx": 276, + "question": "The reaction of forming mullite from Al2O3 and SiO powders is controlled by diffusion and conforms to the Jander equation. The experiment was conducted under constant temperature conditions. When the reaction proceeded for 1 hour, it was measured that 15% of the reactants had reacted. In how much time will all the reactants be converted into products?", + "answer": "According to the Jander equation, [1-(1-0.15)^(1/3)]^2=k×1 ⇒ k=0.00278. The time required for the reaction to complete (G=1) is t=1/k=1/(2.78×10^(-3))=359.63h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程中使用了Jander方程进行推导和计算，最终得出具体的时间数值。 | 知识层次: 题目需要应用Jander方程进行多步计算，包括求解反应速率常数k和计算完全反应所需时间。虽然计算过程不复杂，但需要理解扩散控制的反应动力学和Jander方程的应用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用Jander方程进行多步计算，包括推导反应速率常数k和计算完全反应时间。虽然计算过程明确，但涉及公式转换和综合分析，属于中等偏上难度。" + }, + { + "idx": 277, + "question": "Analyze the effect of reaction temperature on solid-phase reactions", + "answer": "The higher the temperature, the stronger the thermal motion of particles, and the enhanced reaction and diffusion capabilities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析反应温度对固相反应的影响，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目要求分析反应温度对固相反应的影响，涉及热运动、反应能力和扩散能力的关联，需要综合分析温度与这些因素之间的关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求分析反应温度对固相反应的影响，但答案仅涉及温度对粒子热运动和反应扩散能力的基本影响，没有深入探讨反应机理、动力学或具体应用场景。因此，它属于综合分析说明的等级3，而非更复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 278, + "question": "Analyze the effect of mineralizers on solid-state reactions", + "answer": "The larger the lattice energy, the more complete and stable the structure, and the lower the reaction activity. Adding mineralizers can enhance solid-state reactions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析矿物化剂对固态反应的影响，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析矿化剂对固态反应的影响，涉及对反应活性和结构稳定性的理解，需要将多个概念（如晶格能、反应活性）关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求分析矿物化剂对固态反应的影响，但答案已经提供了明确的结论和基本原理（晶格能与结构稳定性、反应活性的关系）。学生需要理解并解释这些概念，但不需要进行多角度或深度关联性分析。解题步骤相对直接，主要涉及概念的解释和应用，符合等级3的综合分析和说明要求。" + }, + { + "idx": 279, + "question": "Analyze the influence of pressure and atmosphere on solid-phase reactions", + "answer": "For reactions between two solid phases, increasing pressure helps enlarge the contact area between particles, accelerates the mass transfer process, and increases the reaction rate; for solid-phase reactions involving liquid or gas phases, raising pressure does not show a positive effect and may even be counterproductive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析压力和气氛对固相反应的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析压力和气氛对固相反应的影响，涉及不同反应条件下的机理解释和综合分析，需要综合运用相关知识进行推理分析，思维过程较深。 | 难度: 在简答题的复杂分析题型中，该题目要求对压力和气相对固相反应的影响进行机理层面的解释。虽然涉及多个反应类型（固-固反应 vs 固-液/气反应），但分析框架相对明确，不需要考虑过于复杂的交互作用或极端条件。题目要求运用基本原理进行推理分析，但不需要进行多因素耦合作用的全面分析，因此属于机理深度解释等级（等级4），而非最复杂的全面分析等级（等级5）。" + }, + { + "idx": 280, + "question": "Analyze the influence of particle size and distribution on solid-phase reactions", + "answer": "The smaller the particle size, the faster the reaction rate; in the same reaction system, due to differences in material size, the reaction rate will be governed by different kinetic regimes; the presence of a small amount of larger-sized particles can significantly delay the completion of the reaction process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析颗粒尺寸和分布对固相反应的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求分析颗粒尺寸和分布对固相反应的影响，涉及反应速率和动力学机制的解释，需要综合运用材料科学和化学反应动力学的知识，进行推理分析和机理解释，思维过程深度要求较高。 | 难度: 在简答题-复杂分析题型中，该题目要求对固体相反应中颗粒尺寸和分布的复杂影响进行全面分析。需要综合运用动力学原理、反应机理和材料科学知识，解释不同颗粒尺寸对反应速率的差异化影响，并推理少量大颗粒如何延迟反应进程。这种多因素交互作用的分析要求显著高于简单的机理解释（等级4），属于该题型框架内对综合推理能力要求最高的复杂现象全面分析层级。" + }, + { + "idx": 281, + "question": "Analyze the effect of strain energy on the kinetics of solid-state phase transformations", + "answer": "Strain energy can influence the kinetics of phase transformation processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对固态相变动力学的影响，需要文字解释和论述，而不是选择、判断或计算。答案也以论述形式给出。 | 知识层次: 题目要求分析应变能对固态相变动力学的影响，这需要综合运用材料科学中的相变理论、热力学和动力学知识，进行推理分析和机理解释。涉及的知识点复杂且关联度高，思维过程要求深入理解应变能与相变驱动力、形核能垒等概念的相互作用。 | 难度: 在简答题-复杂分析题型中，该题目要求对\"应变能对固态相变动力学的影响\"进行机理深度解释。这需要考生：" + }, + { + "idx": 282, + "question": "According to the phase transition mechanism, what types can it be divided into?", + "answer": "According to the phase transition mechanism, it can be divided into diffusion-type phase transition, non-diffusion-type phase transition, and semi-diffusion-type phase transition. Phase transitions that rely on long-distance diffusion of atoms or ions are called diffusion-type phase transitions. Non-diffusion-type phase transitions refer to the movement of atoms or ions, but the relative displacement does not exceed the atomic spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据相变机制进行分类，并解释每种类型的定义，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查相变机制的分类和基本定义，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要回答相变机制的分类，但只需列举并简要说明扩散型、非扩散型和半扩散型相变的定义，不需要深入分析或比较不同相变类型的复杂关系。题目主要考察基础概念的记忆和简单解释，属于该题型中的中等难度。" + }, + { + "idx": 283, + "question": "If magnesium aluminate spinel is to be synthesized, the available raw materials are MgCO, Mg(OH)2, MgO, Al2O3·3H2O, γ-Al2O3, α-Al2O3. From the perspective of increasing the reaction rate, which raw materials should be selected? Please explain the reason.", + "answer": "It is better to use MgCO3, Mg(OH)2, and Al2O3·3H2O as raw materials. This is because MgCO3 and Mg(OH)2 can undergo thermal decomposition during the reaction, and Al2O3·3H2O undergoes dehydration and crystal transformation, resulting in nascent or amorphous substances with larger specific surface areas and lattice defects, thereby enhancing the reaction activity and accelerating the solid-state reaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求选择原料并解释原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从反应速率的角度选择原料，并解释原因。这需要综合运用材料科学中的反应动力学、热分解和晶体转化等知识，分析不同原料在反应过程中的行为及其对反应速率的影响。思维过程涉及多步推理和机理解释，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用材料科学知识，分析不同原料的热分解、脱水及晶型转变特性对反应活性的影响。需要深入理解反应机理（如新生/无定形物质的形成、比表面积和晶格缺陷的作用），并据此进行原料选择。虽然不涉及多因素交互作用的全面分析（等级5特征），但对反应机理的解释深度已达到等级4要求。" + }, + { + "idx": 284, + "question": "Analyze the effect of component changes on the driving force of solid-state phase transformation", + "answer": "The driving force for phase transformation is the difference in volume free energy between the new and old phases at the phase transition temperature (ΔG̃τ), and ΔG<0 is a necessary condition for the formation of the new phase. When two components mix to form a solid solution, the free energy of the mixed system changes. The magnitude of the driving force for phase transformation can be determined through the free energy-composition curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析成分变化对固态相变驱动力的影响，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析组分变化对固态相变驱动力的影响，涉及自由能-成分曲线的理解和应用，需要综合运用热力学原理和相变理论进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对固态相变驱动力进行机理深度解释，涉及自由能-成分曲线的理解和应用，需要综合运用热力学和相变原理进行分析。虽然不涉及多步骤复杂计算，但对概念的理解和机理的阐述要求较高，属于该题型中较高难度的题目。" + }, + { + "idx": 285, + "question": "Analyze the effect of strain energy on the thermodynamics of solid-state phase transformations", + "answer": "Strain energy can influence the magnitude of the phase transformation driving force.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对固态相变热力学的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析应变能对固态相变热力学的影响，这需要综合运用热力学原理、相变理论和应变能概念，进行机理层面的解释和推理分析。涉及多个知识点的深度关联和综合分析能力，超越了简单应用或中等应用层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对固态相变热力学中的应变能影响进行机理深度解释。需要综合运用材料热力学、相变动力学和弹性力学知识，分析应变能如何改变相变驱动力这一核心机理。虽然不涉及多因素耦合分析（等级5特征），但已超出基础概念描述，达到揭示内在物理机制的深度要求。" + }, + { + "idx": 286, + "question": "What is the difference between martensitic transformation and nucleation-growth transformation?", + "answer": "In the nucleation-growth process, there is a diffusion transformation, the composition of the parent phase and the crystalline phase can be the same or different, the transformation speed is relatively slow, and there is no obvious start and end temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种转变过程的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种相变过程的区别，涉及对相变机制的理解和对比分析，需要将相关概念关联起来进行综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对两种相变过程（马氏体相变和形核-生长相变）进行多角度的比较分析，涉及扩散行为、成分变化、转变速度以及温度特征等多个维度的论述。虽然不需要进行深度关联性分析（如与具体材料性能的关联），但需要系统性地组织不同方面的差异点，属于典型的多角度分析论述难度层级。" + }, + { + "idx": 287, + "question": "What are the characteristics of martensitic transformation?", + "answer": "Martensitic transformation is a first-order nucleation and growth phase transformation in which substitutional atoms undergo diffusionless shear displacement (uniform or non-uniform), resulting in shape change and surface relief, and possesses the characteristics of invariant plane strain. Features: it has shear uniformity and regularity, no atomic diffusion occurs, the transformation speed is fast, the transformation occurs within a certain range, and there is a large shear-type elastic strain energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查马氏体相变的基本特征和定义，属于对基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求对马氏体相变的特征进行解释和描述，涉及多个关键特征点的列举和简要说明，但不需要深入阐述复杂的概念体系或进行多层次的逻辑推理。属于概念解释和描述的中等难度级别。" + }, + { + "idx": 288, + "question": "Analyze the effect of surface energy on the kinetics of solid-state phase transformations", + "answer": "Surface energy can influence the kinetics of phase transformation processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析表面能对固态相变动力学的影响，需要文字解释和论述，而不是选择、判断或计算。答案也以论述形式给出。 | 知识层次: 题目要求分析表面能对固态相变动力学的影响，这需要综合运用表面能、相变动力学等多个知识点，并进行推理分析和机理解释。涉及的知识点复杂且关联度高，思维过程要求深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对表面能在固态相变动力学中的影响进行全面分析，涉及多物理场耦合、界面能理论、形核长大机理等复杂概念的综合运用。需要建立完整的理论框架并解释各因素间的相互作用机制，属于该题型下最高难度的复杂现象全面分析层级。" + }, + { + "idx": 289, + "question": "Analyze the influence of surface energy on the shape of new phases", + "answer": "Surface energy can influence the shape of new phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析表面能对新相形状的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析表面能对新相形状的影响，这需要综合运用表面能的概念、新相形成的机理以及形状变化的驱动因素。涉及多个知识点的关联和推理分析，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对表面能如何影响新相形状进行机理深度解释。这需要综合运用材料科学中的热力学和界面理论，分析表面能对各向异性生长的影响机制，属于需要深入理解和推理分析的层次，但尚未达到跨学科复杂现象全面分析的等级5要求。" + }, + { + "idx": 290, + "question": "Analyze the effect of strain energy on the shape of the new phase", + "answer": "Strain energy can influence the shape of the new phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对新相形状的影响，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求分析应变能对新相形状的影响，这需要综合运用材料科学中的相变理论、弹性力学和热力学知识，进行推理分析和机理解释。这超出了简单记忆或应用的范围，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对\"应变能对新相形状的影响\"进行机理深度解释，属于需要综合运用材料科学原理和推理分析的复杂问题。虽然不涉及多因素交互作用的全面分析（等级5），但已经超出了基础概念解释的范畴，需要深入理解应变能与相变形状之间的内在联系机制。" + }, + { + "idx": 291, + "question": "Analyze the influence of surface energy on the thermodynamics of solid-state phase transformations", + "answer": "The surface of a substance has surface tension α. To reversibly increase the surface area dA under constant temperature and pressure, work αdA is required. Since the work required equals the increase in the system's free energy, and this increase is due to the enlargement of the system's surface area, it is termed surface free energy or surface energy. Surface energy can influence the magnitude of the phase transformation driving force.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析表面能对固态相变热力学的影响，答案提供了详细的文字解释和论述，没有涉及计算、选择或判断对错的部分。 | 知识层次: 题目要求分析表面能对固态相变热力学的影响，涉及表面自由能的概念及其对相变驱动力的影响，需要综合运用热力学原理和表面科学知识进行推理分析，属于复杂分析层次。 | 难度: 在简答题中属于机理深度解释难度等级。题目要求分析表面能对固态相变热力学的影响，涉及表面自由能的概念及其对相变驱动力的影响。虽然题目没有要求全面分析复杂现象，但需要对表面能与相变热力学之间的机理进行深入解释，属于该题型内较高难度的题目。" + }, + { + "idx": 292, + "question": "Analyze the effect of undercooling variation on the driving force during solid-state phase transformation", + "answer": "Undercooling is the difference between the critical phase transformation temperature and the actual transformation temperature. The thermodynamic condition for phase transformation nucleation requires undercooling. The relationship between the driving force ΔG and undercooling ΔT is: ΔGg=-Lν(ΔT/T0)T, which further illustrates the thermodynamic condition for nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析过冷度变化对固态相变驱动力的影响，答案提供了详细的文字解释和论述，包括定义、热力学条件和公式说明，符合简答题的特征。 | 知识层次: 题目要求分析过冷度变化对固态相变驱动力的影响，涉及热力学条件的解释和驱动力的计算公式，需要综合运用热力学和相变理论进行推理分析，思维过程较深，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对固态相变中的过冷度变化对驱动力影响进行机理深度解释。需要综合运用热力学条件和相变理论，理解并推导驱动力与过冷度的关系公式。虽然不涉及复杂现象的全面分析，但对机理的解释深度要求较高，属于该题型中的较难题目。" + }, + { + "idx": 293, + "question": "What are the characteristics of the microstructure and properties obtained by spinodal decomposition?", + "answer": "The microstructure obtained by spinodal decomposition typically exhibits a quasi-periodic and interconnected composition modulation structure or a sponge-like organization, which is uniformly fine and can only be resolved under an electron microscope.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释spinodal分解获得的微观结构和性能特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目要求解释spinodal分解获得的微观结构和性能特征，这需要理解spinodal分解的基本原理，并将其与微观结构特征和性能关联起来。虽然不涉及复杂的计算或推理，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解spinodal分解的基本概念，并能描述其形成的微观结构特征和性能特点。虽然不需要多角度分析或深度关联性分析，但需要对相关知识点有较好的掌握，并能进行综合说明。" + }, + { + "idx": 294, + "question": "What is homogeneous nucleation?", + "answer": "Homogeneous nucleation occurs in a uniform medium, where the probability of nucleation is the same throughout the entire medium, independent of interfaces or defects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"homogeneous nucleation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即均匀成核的定义和特征，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答均相成核的基本定义，属于最基础的概念记忆性知识。不需要进行额外的解释或复杂概念的阐述，完全符合等级1\"基本定义简答\"的标准。在同题型内相比，这是最简单的难度等级。" + }, + { + "idx": 295, + "question": "Please analyze the influence of temperature on the thermodynamics and kinetics of phase transitions.", + "answer": "When the temperature decreases, the degree of undercooling increases, the nucleation barrier decreases, and the nucleation rate increases until reaching the maximum value; when the temperature continues to decrease, the liquid phase viscosity increases, and the diffusion rate of atoms or molecules decreases. Both excessively high and low temperatures are unfavorable for nucleation and growth rates, and only at a certain temperature can the maximum nucleation and growth rates be achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析温度对相变热力学和动力学的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析温度对相变热力学和动力学的影响，涉及多个概念的关联和综合分析，需要理解温度变化如何影响过冷度、成核势垒、成核速率、液相粘度以及原子或分子扩散速率等复杂过程。此外，还需要推理分析不同温度条件下成核和生长速率的变化趋势，属于综合运用和机理解释的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用热力学和动力学知识，深入解释温度对相变过程的双重影响（包括成核能垒、扩散速率等机理层面的分析），并需要整合多个变量（如过冷度、粘度等）之间的相互作用关系。这属于该题型下最高难度的\"复杂现象全面分析\"要求，需要学生具备系统性的知识整合能力和高阶推理能力。" + }, + { + "idx": 296, + "question": "What effect does a nucleating agent have on the critical nucleus radius r* during melt crystallization?", + "answer": "Using a nucleating agent can reduce ?s, thus r* decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释核化剂对临界核半径的影响，答案提供了简短的文字解释，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目涉及成核剂对临界核半径的影响，需要理解成核剂如何降低界面能（Δσ）进而影响r*的计算公式（r* = 2σ/ΔGv），属于多步概念关联和综合分析。虽然不涉及复杂计算，但需要将成核剂作用机制与经典成核理论结合分析，思维深度超过简单应用。 | 难度: 在简答题题型中，该题目属于中等应用层次，要求考生理解核化剂对临界核半径的影响机制，并能通过文字解释和论述说明这一过程。题目涉及多步概念关联和综合分析，但不需要进行多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 297, + "question": "Given that iron has a body-centered cubic lattice with a lattice constant a=0.305 nm, determine how many unit cells the critical nucleus consists of at an undercooling of 100°C.", + "answer": "Nucleus volume = (4/3)×3.14×(1.775×10⁻⁹)³ = 2.34×10⁻²⁶ m³\\nUnit cell volume = (0.305×10⁻⁹)³ = 2.83×10⁻²⁹ m³\\nNumber of unit cells = 2.34×10⁻²⁶/2.83×10⁻²⁹ = 8.25×10⁸", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定临界核中的晶胞数量，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目需要进行多步计算（临界核体积计算、晶胞体积计算、单位晶胞数量计算），并需要理解体心立方晶格参数与临界核形成的关系，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解临界晶核的概念，应用体积计算公式，并进行多步单位换算和数值计算。虽然不涉及复杂变量，但步骤较多且需要精确的数值处理能力。" + }, + { + "idx": 298, + "question": "The atomic weight of iron is 55.84, its density is 7.3g/cm³, its melting point is 1593°C, its heat of fusion is 11495J/mol, and the solid-liquid interface energy is 2.04×10⁻⁵J/cm². Calculate the critical nucleus size at an undercooling of 10°C.", + "answer": "ΔGᵥ = - (7.3×10³)/(55.84×10⁻³) × (11495×283)/1876 = -2.267×10⁸ J/m³\\nr* = - (2×2.04×10⁻⁵)/(-2.267×10⁸) = 1.8×10⁻⁷ m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个物理量的关联和综合分析，包括原子重量、密度、熔点、熔化热、界面能等，并需要应用临界核尺寸的计算公式。虽然不涉及复杂的推理分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用多个物理概念（如原子重量、密度、热力学参数）并进行多步计算。虽然涉及公式推导和单位转换，但整体计算过程相对清晰，属于中等偏上难度。" + }, + { + "idx": 299, + "question": "Why is a certain degree of undercooling or overheating required for phase transformation in the nucleation-growth mechanism? Under what conditions is undercooling needed, and under what conditions is overheating needed?", + "answer": "From the thermodynamic formula ΔG=ΔH-TΔS, at equilibrium, ΔG_V=ΔH-T_mΔS=0, ΔS=ΔH/T_m. T: equilibrium phase transition temperature; ΔH: heat of phase transition. At temperature T, the system is in a non-equilibrium state, then ΔG=ΔH-TΔS≠0. ΔG=ΔH(T_m-T)/T_m=ΔHΔT/T_m. For the phase transition to occur spontaneously, ΔG<0 must be satisfied, i.e., ΔTΔH<0. Therefore, ΔT≠0 must be achieved for the phase transition to occur. For exothermic processes such as crystallization and condensation, ΔH<0, then ΔT>0, T>0, undercooling is required. For endothermic processes such as evaporation and melting, ΔH>0, then ΔT<0, T>0, overheating is required.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在成核-生长机制中需要一定程度的过冷或过热，以及在什么条件下需要过冷或过热。答案提供了详细的文字解释和论述，包括热力学公式的应用和不同相变过程的条件分析，符合简答题的特征。 | 知识层次: 题目要求解释相变过程中过冷或过热的原因，并分析在不同条件下需要过冷或过热的具体情况。这涉及到热力学公式的应用（ΔG=ΔH-TΔS）、相变的热力学条件（ΔG<0）、以及不同相变过程（放热和吸热）的具体分析。需要综合运用热力学原理、相变机制和具体条件分析，属于复杂分析和推理的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用热力学公式（ΔG=ΔH-TΔS）进行机理推导，需要明确区分放热过程（ΔH<0）和吸热过程（ΔH>0）的不同热力学条件，并分别解释为何需要过冷（undercooling）和过热（overheating）。解题步骤涉及非平衡态热力学分析、自发过程判据（ΔG<0）的运用，以及相变温度与平衡温度的偏差（ΔT）的符号判断，逻辑链条完整且需要严密推导。该题目对学生的热力学基础、公式推导能力和相变机理理解深度均有较高要求，属于该题型下的最高难度等级。" + }, + { + "idx": 300, + "question": "What are the differences and similarities between spinodal decomposition and precipitation decomposition?", + "answer": "Spinodal decomposition involves the segregation through diffusion, decomposing a single solid solution into two solid solutions with the same structure as the parent phase but different compositions. Precipitation decomposition is the process of precipitating a second phase from a supersaturated solid solution. Their main differences are as follows: (1) Spinodal decomposition belongs to continuous phase transformation. It is a solid-state phase transformation without a thermodynamic energy barrier or nucleation. Precipitation decomposition is a nucleation-growth type phase transformation, with a thermodynamic energy barrier and a nucleation process. (2) In the early stages of spinodal decomposition, compositional fluctuations within the parent phase are gradually established, and the compositions of the two phases change continuously over time following a sinusoidal distribution pattern, eventually reaching the equilibrium phase composition. Once the nucleus of precipitation decomposition forms in the parent phase, its composition is that of the equilibrium phase, with little subsequent change. (3) Spinodal decomposition occurs uniformly in the parent phase; precipitation nuclei generally form at crystal defects. (4) The amplification process in spinodal decomposition occurs through uphill diffusion. The formation of precipitate nuclei occurs through downhill diffusion. (5) The two segregated regions in spinodal decomposition have an indistinct coherent interface. The precipitate phase and the parent phase have a distinct interface. (6) The microstructure of spinodal decomposition is regular, while that of precipitation decomposition is less uniform. Similarity: Both proceed through solute diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两种分解过程的异同点，答案提供了详细的文字解释和对比，符合简答题的特征。 | 知识层次: 题目要求对两种分解过程进行详细的比较和对比，涉及多个方面的差异和相似之处，需要深入理解和分析两种分解的机理、热力学和动力学特征。这需要综合运用材料科学中的相变理论、扩散机制和微观结构演变等知识，属于较高层次的认知能力要求。 | 难度: 在简答题的复杂分析层次中，该题目要求对两种分解机制进行全面的比较和相似性分析，涉及多个维度的机理解释（如热力学能垒、扩散方式、界面特性等）。需要综合运用相变理论、扩散原理和显微组织知识，解题步骤复杂且对知识整合能力要求极高，属于该题型下的最高难度等级。" + }, + { + "idx": 301, + "question": "What is heterogeneous nucleation?", + "answer": "Heterogeneous nucleation occurs at heterogeneous interfaces, such as container walls, bubble interfaces, or on foreign substances (impurities or nucleating agents).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"heterogeneous nucleation\"进行文字解释和论述，答案提供了详细的定义和例子，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，仅需回答异质成核的定义及其发生位置，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。题目没有要求解释机制、举例说明或与其他概念对比，仅需直接回忆\"heterogeneous nucleation\"的定义即可。在同为定义类简答题中，这是最基础的一级难度。" + }, + { + "idx": 303, + "question": "During the melt cooling and crystallization process, given the solid-liquid interface energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=2090 J/cm^3 at 900°C, calculate the critical nucleus radius.", + "answer": "The critical nucleus radius r* = -2γ_sl/△Gv = -2×5×10^-6/2090 = 4.78×10^-10 m = 0.478 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体计算，最终得出一个数值结果（临界核半径）。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目涉及直接套用公式进行简单计算，仅需理解临界核半径公式并代入给定数值即可完成，无需多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（临界核半径公式）并进行简单数值计算，无需任何额外步骤或概念理解。" + }, + { + "idx": 304, + "question": "During the melt cooling and crystallization process, given the solid-liquid interface energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=418 J/cm^3 at 1000°C, calculate the critical nucleus radius.", + "answer": "The critical nucleus radius r* = -2γ_sl/△Gv = -2×5×10^-6/418 = 2.39×10^-9 m = 2.39 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体计算，最终得出一个具体的数值结果（临界核半径），属于典型的计算题类型。 | 知识层次: 题目涉及直接套用公式进行简单计算，仅需理解临界核半径公式并代入给定数值即可，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（r* = -2γ_sl/△Gv）进行简单数值计算，无需任何公式组合或复杂推导步骤。题目提供的参数明确且计算过程仅涉及基本代数运算，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 305, + "question": "Given that iron has a body-centered cubic lattice with a lattice constant a=0.305nm, calculate the number of unit cells that make up the critical nucleus at an undercooling of 10°C.", + "answer": "Nucleus volume = (4/3)×3.14×(1.8×10⁻⁹)³ = 2.44×10⁻²⁶ m³\\nUnit cell volume = (0.305×10⁻⁹)³ = 2.83×10⁻²⁹ m³\\nNumber of unit cells = 2.44×10⁻²⁶/2.83×10⁻²⁹ = 8.61×10⁸", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶格常数、临界核体积和单位晶胞体积的计算，最终得出单位晶胞的数量。答案也是通过具体计算步骤得出的数值结果。 | 知识层次: 题目需要进行多步计算，包括临界核体积和单位晶胞体积的计算，并涉及概念关联（如临界核尺寸与过冷度的关系）。虽然不涉及复杂的综合分析或机理解释，但需要一定的理解和应用能力。 | 难度: 在计算题中属于综合性计算问题，需要理解临界核形成理论、晶格常数与体积的关系，并进行多步计算（包括体积计算和除法运算）。虽然计算步骤明确，但需要将多个概念关联起来，并正确应用公式，属于中等应用层次的计算题。" + }, + { + "idx": 306, + "question": "During the melt cooling and crystallization process, given the solid-liquid interfacial energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=2090 J/cm^3 at 900°C, calculate the energy required for the phase transition.", + "answer": "The energy required for the phase transition △G* = 16πγ_sl^3/3(△Gv)^2 = 16×3.14×(5×10^-6)^3/3×(2090)^2 = 3.24×10^-19 J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，属于对基础知识的直接运用。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式进行计算，无需额外的推导或组合多个公式。题目中已经给出了所有必要的参数，计算步骤简单明了，属于基本公式的直接应用。" + }, + { + "idx": 307, + "question": "During the melt cooling and crystallization process, given the solid-liquid interface energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=418 J/cm^3 at 1000°C, calculate the energy required for the phase transition.", + "answer": "The energy required for the phase transition △G* = 16πγ_sl^3/3(△Gv)^2 = 16×3.14×(5×10^-6)^3/3×(418)^2 = 1.19×10^-17 J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果。 | 知识层次: 题目主要涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析。虽然需要理解相变能量的概念，但计算过程相对直接，属于简单应用层次。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（△G* = 16πγ_sl^3/3(△Gv)^2）进行数值计算，无需多步骤推导或复杂公式组合。题目提供的参数明确且计算过程仅涉及基本代数运算，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 308, + "question": "When forming a cubic nucleus with edge length a in the liquid phase, determine the critical free energy change ΔG*", + "answer": "ΔGa* = -64γzs³/ΔGv² · ΔGv + 6 × 16γzs²/ΔGv² = 32γzs³/ΔGv²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算临界自由能变化ΔG*，答案给出了具体的计算公式和结果，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界自由能变化的计算过程，并综合应用相关公式进行推导。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来正确应用公式并完成计算。 | 难度: 在计算题中属于综合性计算问题，需要理解临界自由能变化的概念，并应用多步公式推导和计算。题目涉及多个变量（γ、zs、ΔGv）的综合处理，但计算步骤相对明确，属于中等偏上的难度水平。" + }, + { + "idx": 309, + "question": "When forming a cubic nucleus with edge length a in the liquid phase, determine the critical nucleus edge length a*", + "answer": "From ΔGa = ΔGv + ΔGs = a³ΔGv + 6a²γzs, setting dΔGa/da = 0, we obtain 3a²ΔGv + 12aγzs = 0. Therefore, a* = -4γzs/ΔGv", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式推导和数值计算来确定临界核边长a*，解答过程涉及数学运算和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界核形成的热力学原理，并应用导数求解极值问题。虽然计算过程不复杂，但需要将体积自由能和表面自由能的概念进行综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解临界核形成的基本概念，应用自由能变化的公式，并进行多步数学推导（求导和代数运算）。虽然涉及的知识点较为基础，但解题步骤较为复杂，需要综合分析能力。" + }, + { + "idx": 310, + "question": "Why is the ΔG* of a cube greater than that of a sphere?", + "answer": "When forming nuclei of the same volume, a³ = (4/3)πr³ ⇒ a > r. The surface area of a cube 6a² > the surface area of a sphere 4πr², therefore ΔG*cube > ΔG*sphere", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么立方体的ΔG*大于球体的ΔG*，答案通过数学推导和文字解释来论述这一现象，符合简答题的特征。 | 知识层次: 题目需要理解核化自由能（ΔG*）与几何形状的关系，涉及体积和表面积的计算，并进行比较分析。虽然计算步骤不多，但需要将多个概念（体积、表面积、自由能）关联起来，进行综合分析。 | 难度: 在简答题中属于中等难度，需要理解核形成自由能的概念，进行几何形状的比较分析，并通过数学关系推导得出结论。虽然涉及多步计算和概念关联，但解题步骤相对明确，属于典型的综合分析类题目。" + }, + { + "idx": 311, + "question": "Are there differences in the atomic stacking modes and packing densities between face-centered cubic and hexagonal close-packed metals? Please explain.", + "answer": "FCC stacks in the ABCABC sequence, while HCP stacks in the ABABAB sequence; there is no difference in packing density, both are 0.74.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释面心立方和六方密堆积金属的原子堆垛方式和堆积密度差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对FCC和HCP晶体结构的基本记忆，包括堆垛顺序和堆积密度的比较，属于基础概念的记忆和理解层面。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释面心立方和六方密堆积金属的原子堆垛模式和堆积密度差异，涉及基础概念的记忆和简单比较。虽然需要掌握两种晶体结构的堆垛序列和堆积密度计算，但不需要复杂的推导或体系阐述，属于该题型中的中等难度。" + }, + { + "idx": 312, + "question": "What is a crystal face family?", + "answer": "A crystal face family refers to the combination of crystal faces with the same arrangement of atoms or molecules in a crystal. Due to symmetry relationships, there are often more than one type of such faces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"crystal face family\"进行文字解释和论述，答案提供了概念的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查晶体面族的基本定义和对称性关系的记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"crystal face family\"的定义，并简要说明其特点（由于对称关系存在多种类型）。这比单纯背诵定义（等级1）要求更高，需要理解概念内涵，但不需要进行复杂的概念体系阐述（等级3）。属于该题型中中等偏基础的难度水平。" + }, + { + "idx": 313, + "question": "Which crystal planes are included in the cubic {111} plane family?", + "answer": "The cubic {111} plane family includes four planes: (111), (111), (111), (111).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释立方晶系{111}晶面族包含哪些晶面，答案需要文字描述和列举具体晶面，属于简答题类型。 | 知识层次: 题目考查对立方晶系中晶面族{111}包含的具体晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答立方晶系{111}晶面族包含的具体晶面，属于基础概念记忆层面的问题。只需准确回忆并列举四个(111)型晶面即可完成作答，无需进行概念解释或复杂体系阐述，符合等级1\"基本定义简答\"的特征。同类题型中，这比需要描述晶面指数确定方法（等级2）或分析不同晶面族衍射强度差异（等级3）的题目更为基础。" + }, + { + "idx": 314, + "question": "What is the (100) interplanar spacing of a face-centered cubic metal? (a is the lattice constant)", + "answer": "The interplanar spacing d=a/2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算面心立方金属的(100)晶面间距，需要使用公式d=a/2进行计算，答案是一个具体的数值结果。 | 知识层次: 题目考查的是面心立方金属(100)晶面间距的计算，只需要直接应用已知的晶面间距公式d=a/2进行计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式d=a/2进行计算，无需任何公式组合或复杂推导步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 315, + "question": "Compare interstitial solid solution and interstitial phase", + "answer": "Commonality: In both, the alloying elements are in interstitial positions and are themselves very small in size. Differences: Interstitial solid solution is a solid solution that retains the crystal structure of the solvent and has very low solubility, exhibiting tough and good plastic properties; interstitial phase is an intermediate phase (size-factor compound), with A and B atoms in proportional quantities, exhibiting hard properties and poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种不同的材料科学概念（间隙固溶体和间隙相），并详细解释它们的共同点和差异。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体和间隙相的基本概念的记忆和理解，包括它们的共同点和差异，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求比较间隙固溶体和间隙相的共同点和差异，涉及对两个基础概念的定义和特性的描述。虽然需要同时解释两个概念并进行对比，但知识点相对明确，解题步骤较为直接，属于中等难度的简答题。" + }, + { + "idx": 316, + "question": "The melting point of copper T_m=1385K, at an undercooling of △T=0.2T_m, crystalline copper is obtained through homogeneous nucleation. Calculate the critical nucleus radius at this temperature. (ΔH=1628J/cm³, γ=1.77×10⁻⁵J/cm²)", + "answer": "From ΔG_v = - (ΔH × ΔT) / T_m = - (1628 × 0.2 × 1385) / 1385 = -325.6 J/cm³. The critical nucleus radius γ* = - (2 × γ) / ΔG_v = - (2 × 1.77 × 10⁻⁵) / (-325.6) = 1.087 × 10⁻⁷ cm ≈ 1.087 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出临界核半径的数值结果。解答过程涉及公式应用和数值代入，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解过冷度的概念、应用临界核半径公式，并进行数值计算。虽然不涉及复杂的综合分析或推理，但需要将多个概念和公式关联起来进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如过冷度、临界核半径、热力学公式等），进行多步计算和综合分析。虽然计算步骤明确，但需要正确关联和运用多个物理量，属于中等偏上的难度。" + }, + { + "idx": 317, + "question": "How do dislocations enter crystals?", + "answer": "The increase in dislocations mainly relies on deformation, where dislocations continuously generate within grains through nucleation and multiplication.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释位错如何进入晶体，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查位错进入晶体的基本机制，主要依赖对位错产生和增殖的基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释位错如何进入晶体，涉及到位错的基本概念和产生机制，但不需要复杂的体系阐述或多步骤推理。回答需要理解位错的生成和增殖原理，属于基础概念记忆层次中的中等难度。" + }, + { + "idx": 318, + "question": "Explain the meaning of interstitial solid solution", + "answer": "An interstitial solid solution is a type of solid solution that retains the crystal structure of the solvent and has very low solubility. The alloying elements are located in the interstitial positions and are themselves very small in size. In terms of properties, it exhibits good toughness and ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙固溶体的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体这一基本概念的定义、形成条件和特性的记忆和理解，属于材料科学中的基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释间隙固溶体的含义，涉及对基本概念的定义和特性描述，但不需要复杂的体系阐述或多概念关联分析。回答需要包含晶体结构、溶解度、合金元素位置和材料性能等要点，属于中等深度但结构清晰的概念解释题。" + }, + { + "idx": 319, + "question": "Why is the strength of solid solutions often higher than that of pure metals?", + "answer": "Because the different sizes of the two types of atoms in the alloy cause lattice distortion, which hinders dislocation movement and results in solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么固溶体的强度通常高于纯金属，需要文字解释和论述，答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及原子尺寸差异导致的晶格畸变以及位错运动的阻碍，需要综合运用材料科学中的晶体缺陷和强化机制知识进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要解释原子尺寸差异导致的晶格畸变及其对位错运动的阻碍作用。这需要综合运用材料科学中的晶体缺陷和强化机制知识，属于机理深度解释的范畴，但尚未达到需要分析多因素交互作用的复杂现象全面分析程度。" + }, + { + "idx": 320, + "question": "What is the angle between the [100] and [111] crystallographic directions in face-centered cubic metals?", + "answer": "The angle between crystallographic planes cosφ=1/√3; φ=54.7°", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算[100]和[111]晶向之间的夹角，需要通过公式cosφ=1/√3进行数值计算，最终得出具体角度值54.7°。这属于典型的计算题特征。 | 知识层次: 题目需要应用基本的晶体学方向夹角公式进行计算，属于直接套用公式的简单计算类型，不需要多步推理或综合分析。 | 难度: 在计算题中属于基础难度，仅需直接应用单一公式（方向余弦公式）进行计算，无需多步推导或组合多个公式。解题步骤简单明确，属于该题型内最基础的难度等级。" + }, + { + "idx": 321, + "question": "What is the reason for the increase in strength caused by the proliferation of line defects and planar defects in crystals?", + "answer": "The reason is that the increase in both types of defects significantly hinders the movement of dislocations, thereby enhancing strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体中线缺陷和面缺陷增殖导致强度增加的原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及晶体缺陷对强度影响的机理分析，需要综合理解线缺陷和面缺陷对位错运动的阻碍作用，并进行推理解释，属于较高层次的认知能力要求。 | 难度: 在简答题中属于机理深度解释难度，需要理解线缺陷和面缺陷对位错运动的阻碍机制，并能综合运用晶体缺陷理论解释强度增强的原因。虽然不涉及多因素交互作用的全面分析，但对机理的解释深度要求较高。" + }, + { + "idx": 322, + "question": "If a crystal has a high density of line defects (dislocations) or planar defects (grain boundaries, twin boundaries, etc.), its strength will significantly increase. What are these phenomena called?", + "answer": "Called strain hardening and grain boundary strengthening (or fine-grain strengthening).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述现象的名称，答案也是以文字形式给出，没有提供选项或需要计算。 | 知识层次: 题目考查对材料科学中强化机制的基本概念的记忆和理解，即应变硬化和晶界强化的定义，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释两种现象（应变硬化和晶界强化/细晶强化），这需要学生对材料科学中的缺陷和强化机制有基本的理解和记忆。虽然涉及两个概念，但都属于基础概念，不需要复杂的体系阐述或深入分析，因此属于等级2。" + }, + { + "idx": 323, + "question": "How to increase the number of dislocations?", + "answer": "The number of dislocations can be increased by large deformation methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了简要的解释而非选择、判断或计算。 | 知识层次: 题目考查的是对位错数量增加方法的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答如何增加位错数量，答案只需简单列举大变形方法即可，不需要深入解释或复杂概念体系的阐述。这符合基础概念记忆的知识层次要求，属于该题型下最基础的难度等级。" + }, + { + "idx": 324, + "question": "Explain the meaning of interstitial phase", + "answer": "Interstitial phase is an intermediate phase (size-factor compound), and the number of A and B atoms is proportional. The alloy components are all in interstitial positions, with very small sizes themselves. In terms of properties, it exhibits high hardness and poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"interstitial phase\"的含义，需要文字解释和论述，答案形式为一段文字说明，符合简答题的特征。 | 知识层次: 题目考查对间隙相（interstitial phase）这一基本概念的定义和特性的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释间隙相（interstitial phase）的含义，涉及对其定义、组成和性质的描述。虽然需要一定的记忆和理解，但并不需要复杂的体系阐述或多层次的分析，属于中等难度的概念解释题。" + }, + { + "idx": 325, + "question": "Calculate the number of atoms in the critical nucleus for copper with a face-centered cubic crystal structure. (a=0.3615nm)", + "answer": "The volume of the critical nucleus V = (4/3) × π × (γ*)³ = (4/3) × 3.14 × (1.087 × 10⁻⁷)³ = 5.39 × 10⁻²¹ cm³. The unit cell volume V_cell = a³ = (0.3615 × 10⁻⁷)³ = 4.72 × 10⁻²³ cm³. The number of unit cells N = V / V_cell = 5.39 × 10⁻²¹ / 4.72 × 10⁻²³ ≈ 114. The number of atoms in a face-centered cubic unit cell is 4, so the number of atoms in the critical nucleus = 114 × 4 = 456.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算临界核的体积、单位晶胞的体积以及原子数量，最终得出临界核中的原子数。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括临界核体积计算、晶胞体积计算、晶胞数量计算以及最终原子数量计算。虽然涉及的是基本的公式应用，但需要综合运用多个概念和步骤，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算（包括临界核半径计算、单位晶胞体积计算、原子数量转换等），涉及晶体结构、临界核形成等概念的关联分析，但未达到复杂多变量计算的程度。" + }, + { + "idx": 326, + "question": "How is grain refinement achieved?", + "answer": "Grain refinement can be achieved by adding heterogeneous nucleating agents or using high cooling rates during solidification, or through large deformation, recrystallization, or phase transformation methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何实现晶粒细化，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释晶粒细化的方法，涉及多种工艺和原理的综合应用，需要理解不同方法的作用机制和关联性，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求对晶粒细化的方法进行综合分析和说明，涉及多个概念（如异质形核、高冷却速率、大变形、再结晶、相变等）的关联和解释。虽然需要一定的知识整合能力，但不需要进行多角度或深度关联性分析（等级4或5）。解题步骤相对直接，主要考察对材料科学基础知识的掌握和应用能力。" + }, + { + "idx": 327, + "question": "How to improve the degree of grain refinement?", + "answer": "The degree of grain refinement can be improved by adding heterogeneous nucleation agents or using high cooling rates during solidification, or through large deformation, recrystallization, or phase transformation methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何提高晶粒细化程度的问题，答案提供了多种方法的详细说明，符合简答题的特征。 | 知识层次: 题目要求对晶粒细化程度改善的方法进行解释和论述，涉及多种工艺方法（如添加异质形核剂、高冷却速率、大变形、再结晶、相变等）的综合应用，需要理解这些方法的基本原理及其对晶粒细化的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对晶粒细化的方法进行解释和论述，但答案涉及的概念和方法较为常见，如异质形核、快速冷却、大变形、再结晶和相变等，这些内容在材料科学基础课程中都有涉及。解题步骤相对直接，不需要进行复杂的多步计算或深度关联性分析，但需要综合运用所学知识进行说明。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 328, + "question": "What are the main mechanisms of metal plastic deformation at room temperature?", + "answer": "The main deformation mechanisms are slip and twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属在室温下的主要塑性变形机制，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查金属塑性变形的基本机制（滑移和孪生）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答金属塑性变形的基本机制（滑移和孪生），属于基础概念记忆层面的简答。不需要深入解释或复杂概念体系的阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 329, + "question": "Under the same degree of supercooling, compare the critical radius, critical nucleation work, and critical nucleus volume between homogeneous nucleation and heterogeneous nucleation. Which is larger?", + "answer": "The critical radius is the same; the critical nucleation work is higher for homogeneous nucleation; the critical nucleus volume is also larger for homogeneous nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较和解释不同条件下的临界半径、临界成核功和临界核体积，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较均相成核和非均相成核的临界半径、临界成核功和临界核体积，需要理解成核理论的基本概念，并能够应用这些概念进行综合分析。虽然涉及基础概念，但需要将多个概念关联起来进行比较和分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度。题目要求比较均相成核和非均相成核在相同过冷度下的临界半径、临界成核功和临界核体积，并指出哪个更大。这需要学生不仅理解成核的基本概念，还需要掌握两种成核方式的差异，并能进行综合分析。虽然不需要进行复杂的计算，但需要对多个相关概念进行关联和比较，属于中等应用层次的多角度分析。" + }, + { + "idx": 330, + "question": "Why is the liquid/solid interface front of an alloy more prone to undercooling during solidification compared to that of a pure metal?", + "answer": "The interface front of an alloy exhibits constitutional undercooling, where solute enrichment at the front raises the local melting point, making undercooling more likely to occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金在凝固过程中液/固界面前沿比纯金属更容易发生过冷的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及合金凝固过程中液/固界面前沿的过冷现象，需要解释溶质富集对局部熔点的影响，并分析其导致过冷的机理。这需要综合运用材料科学中的凝固理论、相图知识和热力学原理，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求解释合金凝固过程中液/固界面前沿比纯金属更容易发生过冷的原因，涉及溶质富集和局部熔点升高等复杂机理。虽然不需要全面分析多种影响因素（如温度梯度、生长速率等），但需要对\"成分过冷\"这一核心概念有深入理解，并能准确表述其物理机制。这比简单描述现象（等级3）要求更高，但尚未达到需要综合分析多种交互作用的最高难度（等级5）。" + }, + { + "idx": 331, + "question": "What is the main difference between slip and twinning?", + "answer": "The shear displacement produced by slip is an integer multiple of the atomic spacing, while that produced by twinning is a fraction of the atomic spacing; this leads to a series of other differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释slip和twinning的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对滑移和孪生这两种塑性变形机制的基本概念的理解和记忆，属于材料科学中晶体缺陷与变形的基础知识范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释滑移和孪生的主要区别，涉及对两种变形机制的基本理解，但不需要深入阐述复杂的概念体系或进行多层次的比较分析。回答需要明确区分两种机制的剪切位移特征，这属于对基础概念的扩展解释，但尚未达到复杂体系阐述的程度。" + }, + { + "idx": 332, + "question": "What are the morphological differences between typical metals (such as iron) and typical non-metals (such as silicon, graphite) when grown individually in the liquid phase?", + "answer": "Because they are rough interface (iron) and smooth interface (silicon, etc.) respectively, the former forms uniform equiaxed crystals or dendrites, while the latter forms regular polygons with angular shapes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属和非金属在液相生长时的形态差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属和非金属在液相生长时的形态差异，涉及界面粗糙度与晶体生长形态的关联，需要理解并应用材料科学中的晶体生长理论，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对金属和非金属在液相生长时的形态差异进行多角度分析论述。需要理解粗糙界面和平滑界面的概念，并能关联到晶体生长形态的具体表现（如等轴晶、枝晶与规则多边形）。虽然不涉及深度跨学科关联，但需要综合材料科学和晶体生长原理的知识进行较为全面的解释，属于该题型内较高难度的题目。" + }, + { + "idx": 333, + "question": "Give the basic conditions (driving force) for metal recrystallization.", + "answer": "There must be a certain amount of deformation stored energy and a certain temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属再结晶的基本条件（驱动力），答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查金属再结晶的基本条件，属于基本原理的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答金属再结晶的基本条件（驱动力），即变形储存能和一定温度，属于对基础概念的记忆性回答，不需要深入的解释或复杂的论述。在同类简答题中，这是最基础的知识点考察，符合等级1的标准。" + }, + { + "idx": 334, + "question": "What is the main difference between recrystallization and crystallization?", + "answer": "Recrystallization is only a microstructural change without structural transformation, driven by deformation stored energy; crystallization is the process of forming crystals from amorphous liquid, gas, or solid states.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对recrystallization和crystallization这两个基本概念的定义和区别的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分两个相关但不同的概念（recrystallization和crystallization），并解释它们的主要区别。这需要学生不仅记住定义，还要理解两者的驱动机制和形成过程。虽然不涉及复杂的概念体系阐述，但比单纯的基本定义简答要求更高，需要一定的理解和表达能力。" + }, + { + "idx": 335, + "question": "What are the upper and lower yield point effects (in pure iron or low-carbon steel)? What are the reasons?", + "answer": "Significant work hardening occurs during deformation at low temperatures (or high strain rates); a balance between hardening and softening (dynamic recovery) appears during deformation at medium temperatures (or medium strain rates); a distinct softening stage (dynamic recrystallization) occurs during deformation at high temperatures (or low strain rates).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释上下屈服点效应及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释上下屈服点效应的原因，涉及材料变形过程中的硬化、动态回复和动态再结晶等复杂机制，需要综合运用材料科学知识进行推理分析，思维过程深度较高。 | 难度: 在简答题-复杂分析题型中，该题目要求对纯铁或低碳钢的上下屈服点效应进行全面分析，涉及不同温度/应变率条件下的硬化、动态回复和动态再结晶等复杂现象的综合解释。需要深入理解材料变形机理，并能系统性地阐述多因素交互作用，属于该题型框架内最高难度的综合分析类问题。" + }, + { + "idx": 336, + "question": "What is the main difference between recrystallization and solid-state phase transformation?", + "answer": "Recrystallization is only a microstructural change without structural change, and the driving force is deformation stored energy; solid-state phase transformation is a structural change between solid/solid phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的主要区别，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对再结晶和固态相变这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分两个相关但不同的材料科学概念（再结晶和固态相变），需要解释各自的特点和驱动力的差异。虽然涉及两个概念的对比，但不需要深入阐述复杂机制或进行多步骤分析，主要考察对基础概念的理解和表达能力。相比等级1的纯定义复述题，该题需要更高层次的概念关联；但相比等级3需要系统阐述复杂概念体系的题目，其要求相对简单。" + }, + { + "idx": 337, + "question": "What are the main characteristics of allotriomorphic transformation?", + "answer": "Allotriomorphic transformation is primarily a phase change that occurs in pure components in the solid state, with no compositional changes, controlled by short-range diffusion processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释allotriomorphic transformation的主要特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对allotriomorphic transformation这一基本概念的定义和主要特征的理解和记忆，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求对allotriomorphic transformation的主要特征进行解释和描述，涉及相变的基本原理和特点，但不需要复杂的体系阐述或多概念整合。属于概念解释和描述层次，符合等级2的标准。" + }, + { + "idx": 338, + "question": "What is the main difference between crystallization and solid-state phase transformation?", + "answer": "Crystallization is the process of forming crystals from amorphous liquid, gas, or solid non-crystalline states; solid-state phase transformation is the structural change between solid/solid phases. The driving forces for both processes are the chemical free energy difference.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对两个概念进行解释和比较，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对结晶和固态相变这两个基本概念的定义和区分，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释两个基础概念的区别，并简要说明驱动力的共同点。这属于概念解释和描述的难度等级，需要学生对结晶和固态相变的基本定义有清晰理解，并能进行对比分析，但不需要深入阐述复杂机制或推导过程。" + }, + { + "idx": 339, + "question": "What are the main characteristics of martensitic transformation?", + "answer": "Martensitic transformation is a diffusionless, shear-type phase transformation that occurs in both pure metals and alloys, and is controlled by interface processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变的主要特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查马氏体相变的基本特征，属于定义和基本原理的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释马氏体相变的主要特征，属于概念解释和描述的难度级别。虽然需要记忆和理解相关概念，但并不涉及复杂的概念体系阐述或深入的分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 340, + "question": "What are the main characteristics of precipitation transformation?", + "answer": "Precipitation occurs in alloys, involves compositional changes, and is primarily controlled by long-range diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释沉淀转变的主要特征，答案以文字论述形式给出，没有选项、判断或计算要求。 | 知识层次: 题目考查的是对沉淀相变主要特征的基本概念记忆和理解，涉及合金中的沉淀现象、成分变化和扩散控制等基本原理，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释沉淀转变的主要特征，涉及合金中的沉淀现象、成分变化和长程扩散控制等概念。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或深入的分析，属于概念解释和描述的难度等级。" + }, + { + "idx": 341, + "question": "Briefly describe the effect of deformation amount on metal properties under uniaxial compression?", + "answer": "As the deformation amount increases, strength and hardness improve, while plasticity decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述变形量对金属性能的影响，需要文字解释和论述，答案也是以文字形式给出对现象的解释说明。 | 知识层次: 题目考查金属在单轴压缩下变形量对性能影响的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题中属于中等难度，需要解释变形量对金属性能的影响，涉及强度、硬度和塑性的变化，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 342, + "question": "Briefly describe the effect of deformation amount on the microstructure of metals under uniaxial compression (including changes in grain shape and dislocation substructure)?", + "answer": "From a lateral observation, as the deformation amount increases, the grains change from equiaxed to elongated, and the dislocations within the grains increase, forming dislocation tangles, subgrain boundaries, or new high-angle grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形量对金属微观结构的影响，包括晶粒形状和位错亚结构的变化。答案以文字解释和论述的形式呈现，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求描述变形量对金属微观结构的影响，涉及对晶粒形状和位错亚结构变化的综合分析。需要理解变形过程中晶粒的演变和位错行为的关联，属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要综合分析和说明金属在单轴压缩下变形量对微观结构的影响，包括晶粒形状变化和位错亚结构的演变。题目要求理解并关联多个概念，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 343, + "question": "Briefly describe the effect of deformation temperature on metal properties under uniaxial compression.", + "answer": "As the deformation temperature increases, the rates of both strength increase and plasticity decrease slow down.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形温度对金属性能的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释变形温度对金属性能的影响，需要理解温度与金属强度、塑性之间的关系，并进行综合分析。这涉及多个概念的关联和中等程度的分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于中等难度，需要理解变形温度对金属性能的影响，并进行综合分析和说明。题目要求简要描述，不需要多角度或深度关联性分析，但需要掌握相关概念并进行逻辑阐述。" + }, + { + "idx": 344, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? How many atoms are there in an FCC unit cell?", + "answer": "The number of atoms in an FCC unit cell is 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释常见的晶体结构参数，并回答FCC晶胞中的原子数量，需要文字解释和论述。 | 知识层次: 题目考查对晶体结构基本参数和面心立方晶胞原子数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答FCC晶胞中的原子数量（4个），这是晶体学中最基础的概念之一，不需要复杂的解释或论述。同题型内相比，这属于只需记忆基础知识点就能回答的简单问题，不涉及概念间的关联或深入分析。" + }, + { + "idx": 345, + "question": "Briefly describe the effect of deformation temperature on metal microstructure (including changes in grain shape and dislocation substructure) under uniaxial compression.", + "answer": "As the deformation temperature increases, the rate at which grains elongate slows down due to enhanced thermal activation, subgrain boundaries form more rapidly, subgrain size tends to stabilize, and even dynamic recrystallization structures may appear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述变形温度对金属微观结构的影响，需要文字解释和论述，而不是选择、判断或计算。答案也以文字形式呈现，解释了温度变化对晶粒形状和位错亚结构的具体影响。 | 知识层次: 题目要求分析变形温度对金属微观结构的影响，涉及多个方面的变化（晶粒形状、位错亚结构等），需要综合运用材料科学知识进行推理分析，解释温度变化对微观结构演变的机理，思维过程较为深入。 | 难度: 在简答题题型中，该题目要求对金属微观结构在变形温度影响下的变化进行机理深度解释，包括晶粒形状变化、亚晶界形成、亚晶尺寸稳定化以及动态再结晶结构的出现。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高难度的简答题。虽然题目没有要求全面分析所有可能的复杂现象，但对机理的解释深度要求较高，因此评为等级4。" + }, + { + "idx": 346, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the close-packed plane of an FCC unit cell?", + "answer": "Close-packed plane {111}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体结构的常见参数和FCC晶胞的密排面，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体结构基本参数和密排面的记忆，属于基础概念的记忆和理解 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求描述晶体结构（晶胞）的常见参数，并指出FCC晶胞的密排面。虽然需要记忆和解释基本概念，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 348, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the coordination number of an FCC unit cell?", + "answer": "Coordination number 12.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举常见的晶体结构参数，并回答FCC晶胞的配位数，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查晶体结构的基本参数和面心立方晶胞的配位数，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目仅要求回答晶体结构的基本参数和面心立方晶胞的配位数，属于最基础的定义性知识。题目不涉及概念解释或复杂体系阐述，仅需记忆性回答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 349, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What are the interstitial positions and their number in an FCC unit cell?", + "answer": "Interstitial positions (octahedral interstitial at the body center and equivalent positions) and number 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体结构（晶胞）的常见参数以及面心立方晶胞中的间隙位置和数量，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体结构的基本参数和间隙位置的定义及数量，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求描述晶体结构（晶胞）的常见参数以及面心立方晶胞中的间隙位置及其数量。虽然需要记忆和解释一些基本概念，但不需要复杂的体系阐述或多步骤推理。主要考察对基础概念的理解和简单应用，属于中等难度的简答题。" + }, + { + "idx": 350, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the stacking sequence of an FCC unit cell?", + "answer": "The stacking sequence is ABCABC.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述晶体结构的常见参数和FCC晶胞的堆垛顺序，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对晶体结构基本参数和面心立方(FCC)晶胞堆垛序列的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中，该题目属于概念解释和描述难度。题目要求描述晶体结构（晶胞）的常见参数和面心立方（FCC）晶胞的堆垛序列。虽然需要记忆一些基本概念和堆垛顺序，但不需要复杂的推导或深入的分析。相对于基本定义简答（等级1），它需要更多的解释和描述；但相对于复杂概念体系阐述（等级3），它的要求较为简单。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 351, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the packing density of an FCC unit cell?", + "answer": "Packing density 0.74.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释常见的晶体结构参数，并计算FCC晶胞的堆积密度，需要文字解释和论述。答案虽然给出了数值，但问题本身需要详细的解释和计算过程。 | 知识层次: 题目要求描述晶体结构的常见参数（基础概念记忆），并计算FCC晶胞的堆积密度（基本公式应用）。虽然涉及基础概念，但主要考查的是对堆积密度公式的直接套用和简单计算能力，属于简单应用层次。 | 难度: 在简答题中属于中等难度，需要理解并描述晶体结构的基本参数（如晶格常数、原子半径等），并应用几何关系计算面心立方结构的堆积密度。虽然计算过程相对直接，但需要清晰解释步骤和概念，属于应用方法说明的难度等级。" + }, + { + "idx": 352, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the atomic radius of an FCC unit cell?", + "answer": "The atomic radius is √2a/4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释常见的晶体结构参数，并给出FCC晶胞的原子半径计算公式，需要文字解释和论述。 | 知识层次: 题目要求描述晶体结构（晶胞）的常见参数，并计算面心立方晶胞的原子半径。这涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。虽然需要理解晶胞结构的基本概念，但主要考察的是对公式（原子半径与晶格常数a的关系）的应用能力。 | 难度: 在简答题中属于简单应用过程描述。题目要求描述晶体结构的常见参数并计算FCC晶胞的原子半径，主要涉及基本概念的直接应用和简单公式套用，解题步骤较为直接，不需要复杂的解释或深入的分析。" + }, + { + "idx": 353, + "question": "What is the main structural difference between (metal-based) solid solutions and intermediate phases?", + "answer": "Solid solutions retain the crystal structure of the pure metal, while the structure of intermediate phases is generally different from that of both constituent elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属基固溶体和中间相的主要结构差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属基固溶体和中间相结构差异的基本概念记忆和理解，属于材料科学中相图部分的基础知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述两个概念（固溶体和中间相）之间的主要结构差异，属于概念解释和描述的难度等级。虽然需要记忆和理解基本概念，但不需要进行复杂的体系阐述或多层次的分析，因此属于中等难度。" + }, + { + "idx": 354, + "question": "What are the main differences in properties between (metal-based) solid solutions and intermediate phases?", + "answer": "Solid solutions have good plasticity and toughness, while intermediate phases exhibit high strength but poorer toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述金属基固溶体和中间相在性能上的主要差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对固溶体和中间相基本性质差异的记忆和理解，属于基础概念层面的知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较两种材料（固溶体和中间相）的主要性能差异，这需要学生对这两种材料的基本性质有一定的理解和记忆，但不需要深入分析或阐述复杂的理论体系。回答时需要简要说明两者的塑性、韧性和强度等性能特点，属于基础概念记忆和简单比较的范畴，符合等级2的要求。" + }, + { + "idx": 355, + "question": "What is the main difference in bonding nature between (metal-based) solid solutions and intermediate phases?", + "answer": "The atoms in solid solutions are primarily bonded by metallic bonds, while intermediate phases are mainly bonded by covalent and ionic bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种材料之间的主要区别，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对固体溶液和中间相之间键合性质差异的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分两种材料（固溶体和中间相）的主要键合性质差异，需要考生掌握并解释金属键、共价键和离子键的基本概念及其在不同材料中的主导作用。虽然涉及多个键合类型的对比，但不需要深入阐述复杂机制或进行多层次的体系分析，属于基础概念的应用层面。" + }, + { + "idx": 356, + "question": "How does the dissolution of another element in a pure metal (assuming no new phase is formed) cause changes in properties due to microstructural changes?", + "answer": "The strength increases due to solid solution strengthening, while the plasticity decreases; the electrical resistance generally increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释溶解其他元素对纯金属性能的影响机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化对金属性能的影响，涉及多个概念（固溶强化、强度、塑性、电阻率）的关联和综合分析，需要理解固溶强化的机理及其对性能的具体影响，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解固溶强化的基本原理，并能关联其对强度和塑性的影响，同时还需解释电阻变化的原因。虽然涉及多个概念，但分析深度和关联性要求适中，属于综合分析说明的范畴。" + }, + { + "idx": 357, + "question": "After dissolving another element into a pure metal (assuming no new phase is formed), what microstructural changes will occur?", + "answer": "It causes lattice distortion, and the lattice constant will change; local segregation or ordering may occur, and even a superlattice can form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释溶解其他元素到纯金属中会发生的微观结构变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释溶解其他元素到纯金属中引起的微观结构变化，涉及晶格畸变、晶格常数变化、局部偏聚或有序化以及超晶格形成等概念的综合分析。这需要理解固溶体的基本概念，并能将这些概念关联起来进行多方面的解释，属于中等应用层次。 | 难度: 在简答题中，该题目要求考生不仅理解溶解元素对纯金属微观结构的影响，还需要分析多种可能的变化（如晶格畸变、晶格常数变化、局部偏聚或有序化、超晶格形成等）。这需要多角度的分析和论述，涉及多个概念的关联和综合应用，属于较高难度的简答题。" + }, + { + "idx": 358, + "question": "What are the microscopic mechanisms of diffusion?", + "answer": "The main microscopic mechanisms of diffusion are the interstitial mechanism and the substitutional mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散的微观机制，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查扩散的微观机制的基本概念和分类，属于基础概念的记忆和理解层面。 | 难度: 在简答题题型中，该题目要求解释扩散的微观机制，涉及对两种主要机制（间隙机制和置换机制）的描述和区分。这属于概念解释和描述的层次，比单纯的定义简答（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 359, + "question": "How does the interaction between point defects and dislocations affect mechanical properties?", + "answer": "At this point, the dislocations are pinned and difficult to move, increasing strength and producing upper and lower yield point effects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释点缺陷与位错相互作用对力学性能的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及点缺陷与位错的相互作用对力学性能的影响，需要深入理解缺陷与位错的交互机制，并分析其对材料强度等性能的具体影响。这属于对材料科学中复杂现象的机理解释和综合分析，需要较高的认知能力和深度思维。 | 难度: 在简答题题型中，该题目要求对点缺陷与位错相互作用对力学性能的影响进行机理深度解释。这需要综合运用材料科学中的缺陷理论和力学性能知识，进行推理分析和机理解释。虽然题目没有要求全面分析复杂现象，但对机理的解释深度要求较高，属于该题型中的较高难度等级。" + }, + { + "idx": 360, + "question": "Under normal circumstances, which mechanism diffuses faster?", + "answer": "Diffusion via the interstitial mechanism is faster, as interstitial atoms are smaller in size and do not require the presence of vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释哪种扩散机制更快，并提供了详细的文字解释作为答案，符合简答题的特征。 | 知识层次: 题目考查扩散机制的基础概念记忆和理解，仅需比较间隙扩散和空位扩散的基本原理和特点，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释并比较两种扩散机制（间隙扩散和空位扩散）的速度差异，需要考生理解并描述基本原理（间隙原子尺寸较小且不需要空位存在），但不需要进行复杂的概念体系阐述或深入分析。这比单纯回答基本定义（等级1）要求更高，但比涉及多个概念交互或复杂机理的题目（等级3）更简单。" + }, + { + "idx": 361, + "question": "Write a specific slip system for a face-centered cubic metal", + "answer": "Such as (111)[110]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出面心立方金属的具体滑移系，需要具体回答滑移面和滑移方向的组合（如(111)[110]），属于需要特定知识回答的简答题形式 | 知识层次: 题目考查对滑移系统这一基础概念的记忆和理解，要求写出面心立方金属的特定滑移系统，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答的难度等级。题目仅要求写出面心立方金属的一个特定滑移系，如(111)[110]，这属于对基础概念的记忆性回答，不需要额外的解释或复杂的概念体系阐述。在同类题型中，此题的知识点掌握深度要求较低，解题步骤简单，仅需回忆并写出标准答案即可。" + }, + { + "idx": 362, + "question": "For an alloy that has solidified with microscopic non-equilibrium segregation, what measures can be taken to accelerate diffusion and homogenize the alloy?", + "answer": "Heating and annealing, deformation followed by annealing, or increasing vacancy concentration through high-energy particle irradiation to enhance diffusion (though this is uneconomical and impractical).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述具体的措施来加速扩散和均匀化合金，答案提供了多种可能的解决方案，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求考生理解非平衡偏析的概念，并应用扩散和均质化的基本原理来提出解决方案。需要多步骤的思考，包括加热退火、变形后退火以及高能粒子辐照等方法的选择和解释，涉及概念关联和综合分析，但不需要深入的机理分析或创新设计。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求考生不仅理解非平衡偏析的概念，还需要综合运用扩散原理、热处理工艺、变形加工以及辐照效应等多方面知识，提出具体的均质化措施。解题步骤涉及多个技术路线的比较和选择（如加热退火、变形后退火、高能粒子辐照等），且需要评估不同方法的优缺点（如经济性和实用性）。这超出了单一知识点复述或简单分析的范畴，属于需要整合多个技术模块并论述其关联性的中高难度简答题。" + }, + { + "idx": 363, + "question": "Describe which solution of the second law of diffusion is applied in this process?", + "answer": "The sinusoidal solution can describe the concentration distribution during diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述哪种扩散第二定律的解适用于该过程，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目要求描述扩散第二定律的特定解在某一过程中的应用，需要理解扩散定律的基本原理，并能够将正弦解与具体的浓度分布情况关联起来。这涉及到多步的思维过程，包括对扩散定律的理解、特定解的选择以及其在具体过程中的应用分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求描述特定扩散定律的应用，但答案只需指出适用的正弦解并简要说明其在浓度分布描述中的作用，不需要进行多角度或深度关联性分析。解题步骤相对直接，主要考察对扩散定律特定解法的理解和应用能力。" + }, + { + "idx": 364, + "question": "Why do point defects (such as interstitial atoms or substitutional atoms) and line defects (such as dislocations) interact?", + "answer": "Point defects cause distortion, increasing local energy and creating an elastic strain field nearby; dislocations also exhibit this behavior, but the stress field state around dislocations varies at different positions, with some being compressive stress and others tensile stress. Point defects will aggregate onto dislocations to reduce strain energy, thereby lowering the system's energy. Dislocations that adsorb solute atoms represent a stable configuration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释点缺陷和线缺陷相互作用的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释点缺陷和线缺陷相互作用的机理，涉及应变场、应力状态、能量降低等概念的关联和综合分析，需要深入理解缺陷行为的物理本质并进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对点缺陷和线缺陷的相互作用机理进行深度解释，涉及弹性应变场、应力状态变化以及系统能量降低等综合概念。虽然不需要全面分析复杂现象（如多因素耦合），但需要准确描述缺陷间的能量驱动机制和稳定构型形成过程，属于机理深度解释层面的难度。" + }, + { + "idx": 365, + "question": "What are the types of deformation textures?", + "answer": "Textures are divided into sheet textures and fiber textures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释变形织构的类型，答案提供了文字解释和分类，符合简答题的特征 | 知识层次: 题目考查对变形织构类型的基本分类记忆，属于基础概念的记忆性知识 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述变形织构的分类（片状织构和纤维织构），不涉及概念解释或复杂体系阐述。" + }, + { + "idx": 366, + "question": "During the deformation of polycrystals, under a certain amount of deformation, why do some grains exhibit single slip while others exhibit multiple slips?", + "answer": "Hard-oriented stress axes induce multiple slips, such as <111>, <100>, <110> directions, while soft-oriented stress axes correspond to single slip, such as the <123> direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在变形过程中某些晶粒表现出单滑移而其他晶粒表现出多滑移，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目涉及多晶变形过程中不同晶粒的滑移行为差异，需要理解晶体取向与滑移系激活的关系，分析硬取向和软取向对应不同滑移行为的机理，属于综合运用晶体塑性理论和变形机制进行推理分析的复杂问题。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释多晶变形过程中不同晶粒表现出单滑移和多滑移的原因，涉及晶体取向与滑移系激活的复杂关系。需要综合运用晶体学、位错理论和力学响应知识进行推理分析，但尚未达到全面分析复杂现象的最高难度（如涉及多因素交互作用或动态过程）。" + }, + { + "idx": 367, + "question": "What is deformation texture?", + "answer": "The deformation process causes the grains to rotate, and finally certain crystallographic directions within each grain tend to become parallel. This preferred orientation due to deformation is called deformation texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"deformation texture\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"deformation texture\"这一基本概念的定义和简单解释，主要依赖记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的记忆性知识。题目仅涉及\"deformation texture\"这一单一概念的定义，不需要进行概念间的联系或复杂解释，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 368, + "question": "During the deformation of polycrystals, under a certain amount of deformation, why do some grains exhibit large slip amounts while others show small slip amounts?", + "answer": "When the orientation factor of a slip system in a grain relative to the force axis is large, slip initiates first; when the orientation factor is small, slip initiates later, resulting in different deformation amounts among grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶体变形过程中不同晶粒滑移量差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多晶变形过程中不同晶粒滑移量差异的原因，涉及滑移系取向因子与外力轴的关系，需要综合运用晶体学、位错理论和变形机制等知识进行推理分析，思维过程较深。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释多晶变形过程中不同晶粒滑移量差异的原因，需要综合运用晶体学取向因子、滑移系统激活条件等知识进行机理分析。虽然不涉及多因素交互作用的全面分析（等级5特征），但需要对变形机理有较深入的理解才能完整解答，符合等级4对机理解释深度的要求。" + }, + { + "idx": 369, + "question": "How to represent the fiber texture?", + "answer": "The fiber texture is represented as .", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何表示纤维织构，答案提供了具体的表示方法，属于需要文字解释的简答题类型 | 知识层次: 题目考查纤维织构的基本表示方法，属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答纤维织构的表示方法，属于基本定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可完成，符合等级1的基本定义简答标准。" + }, + { + "idx": 370, + "question": "Why is recrystallization annealing often required in actual production?", + "answer": "Continuous plastic deformation of the material causes severe work hardening, making further processing difficult; at the same time, the deformed structure is unstable, with poor toughness and plasticity, resulting in unsatisfactory service performance; moreover, the formation of strong deformation texture is also undesirable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在实际生产中经常需要再结晶退火，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释再结晶退火在实际生产中的必要性，涉及工作硬化、变形组织不稳定性和变形织构等多个概念的综合分析，需要理解这些概念之间的关联及其对材料性能的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解再结晶退火的基本概念，还需要综合分析其在生产实践中的多重作用。题目涉及工作硬化、组织结构稳定性、力学性能改善以及变形织构等多个相互关联的知识点，要求考生能够从不同角度进行论述，展示对材料加工过程中微观组织与宏观性能关系的深入理解。这超越了简单的概念复述(等级3)，但尚未达到需要跨学科知识整合的深度关联性分析(等级5)。" + }, + { + "idx": 371, + "question": "Which locations may be preferred nucleation sites?", + "answer": "Preferred nucleation sites include: original grain boundaries, newly formed high-angle grain boundaries during deformation or those gradually formed through subgrain growth, and the vicinity of second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释优先成核位置，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对成核位点这一基础概念的记忆和理解，答案中列举的是常见的成核位点类型，属于材料科学中的基本知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举并简要说明可能的首选成核位置，涉及对材料科学中成核现象的基本理解，但不需要深入分析或复杂的概念体系阐述。回答需要记忆和解释几个关键概念（如晶界、变形形成的高角度晶界、亚晶粒生长和第二相粒子附近），但不需要进行复杂的推理或综合多个概念。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 372, + "question": "Schottky defect", + "answer": "A vacancy defect formed by displaced atoms migrating to the outer surface under thermal equilibrium conditions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对Schottky defect进行文字解释和论述，答案是一个详细的定义描述，符合简答题的特征。 | 知识层次: 题目考查Schottky缺陷的基本定义和形成条件，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答Schottky defect的基本定义，属于最基础的概念记忆性知识。不需要进行额外的解释或描述，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 373, + "question": "What are the characteristics or features of recrystallization nucleation sites?", + "answer": "Locally high dislocation density/deformation stored energy, or significant differences in dislocation density; near high-mobility high-angle grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释再结晶成核位点的特征，答案提供了详细的文字描述和论述，符合简答题的特点 | 知识层次: 题目要求解释再结晶形核位点的特征，涉及对位错密度和晶界特性的理解，需要将多个概念关联起来进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解并说明再结晶形核位点的特征，涉及局部高位错密度/变形储存能或位错密度的显著差异，以及靠近高迁移率高角度晶界等概念。虽然需要一定的概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 374, + "question": "Briefly describe the laws of changes in material microstructure and properties during recovery and recrystallization annealing", + "answer": "As the annealing temperature increases or the annealing time prolongs, dislocation tangles in the deformed structure evolve into subgrains, which merge and grow; recrystallization nucleation and growth occur in areas of uneven deformation, with equiaxed grains replacing elongated deformed grains; followed by normal grain growth; in terms of properties, strength and hardness decrease, electrical resistance decreases; plasticity and toughness improve, and density increases. These processes are more pronounced during the recrystallization stage than during the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述材料在回复和再结晶退火过程中微观结构和性能变化的规律，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求描述材料在回复和再结晶退火过程中微观结构和性能变化的规律，这需要综合运用材料科学中的多个概念（如位错、亚晶、再结晶形核与长大等），并进行机理的解释和关联分析。回答不仅需要理解各个过程的基本原理，还需要分析这些过程如何相互影响以及如何导致性能的变化。这种深度和广度的要求超出了简单记忆或直接应用，属于复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对材料微观结构和性能在回复和再结晶退火过程中的变化规律进行机理深度解释。需要综合运用材料科学知识，分析位错结构演变、亚晶合并、再结晶形核与长大等复杂现象，并关联性能变化。虽然不涉及多因素交互作用的极端复杂性（等级5特征），但对机理描述的深度和完整性要求显著高于基础分析题。" + }, + { + "idx": 375, + "question": "Up-hill diffusion", + "answer": "Driven by the chemical potential gradient, solute diffuses from areas of low concentration to areas of high concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"Up-hill diffusion\"现象进行文字解释和论述，答案是以文字形式解释该现象的原理，符合简答题的特征。 | 知识层次: 题目要求解释\"Up-hill diffusion\"现象，这涉及对化学势梯度驱动下溶质从低浓度区向高浓度区扩散的机理分析，需要综合运用热力学和扩散理论进行推理解释，属于对复杂现象的综合分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求解释\"Up-hill diffusion\"这一非直观的扩散现象，需要深入理解化学势梯度的概念及其与常规浓度梯度的区别。虽然不涉及多因素综合分析（等级5的特征），但需要对扩散机理进行深度解释，包括驱动力的本质和反常扩散行为的原理，这已达到等级4的深度要求。" + }, + { + "idx": 376, + "question": "Center of gravity rule", + "answer": "For an alloy in three-phase equilibrium, its composition point must lie at the centroid position of the conjugate triangle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目陈述了一个材料科学中的规则（重心规则），答案是对该规则的文字解释和描述，不需要计算或选择，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对\"重心规则\"这一基本原理的记忆和理解，属于基础概念的记忆性知识，不涉及复杂计算或综合分析。 | 难度: 在简答题中属于中等难度，需要解释和描述一个具体的规则（重心规则），并说明其在三相平衡合金中的应用。虽然涉及一定的概念理解，但不需要复杂的体系阐述或深入的分析。" + }, + { + "idx": 377, + "question": "同质异构体", + "answer": "Chemical compositions are the same but form different crystal structures due to different thermodynamic conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"同质异构体\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征 | 知识层次: 题目考查同质异构体的基本定义和形成原因，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释同质异构体的定义及其形成原因，涉及基础概念的记忆和简单描述，但不需要复杂的体系阐述或多步骤推理。相比等级1的基本定义简答，它需要更多的解释性内容；相比等级3的复杂概念体系阐述，它的知识深度和解题复杂度较低。" + }, + { + "idx": 378, + "question": "Habit plane", + "answer": "During solid-state phase transformation, the new phase often begins to form on certain crystallographic planes of the parent phase, which are called habit planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Habit plane\"进行文字解释和论述，答案提供了详细的定义和背景信息，符合简答题的特征。 | 知识层次: 题目考查对\"habit plane\"这一基本概念的定义和简单解释，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答habit plane的定义，不需要进行概念解释或复杂体系阐述。答案直接引用教材中的基础定义即可完成作答，属于该题型内最基础的难度等级。" + }, + { + "idx": 379, + "question": "In the diamond structure, carbon is connected by (5) bonds, and the coordination number is (6).", + "answer": "(5) covalent; (6) 4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定类型的键和配位数，需要具体的关键词回答而非选择或判断 | 知识层次: 题目考查对金刚石结构中碳原子键合类型和配位数的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆并准确回答碳在金刚石结构中的键类型和配位数，无需深入解释或复杂论述。" + }, + { + "idx": 380, + "question": "There are two types of the most closely packed crystal structures: one is (1), with (2) atoms in each unit cell; the other is (3), with (4) atoms in each unit cell.", + "answer": "(1) ABC; (2) 4; (3) AB; (4) 2(or 6)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定的术语和数值，需要根据知识进行简短的填空回答，而不是从选项中选择或进行复杂的计算。 | 知识层次: 题目考查对最紧密堆积晶体结构类型及其单位晶胞中原子数量的基础概念记忆，属于定义和分类层面的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求填写两种最紧密堆积晶体结构的名称及其单胞中的原子数，这些都是材料科学中最基础的概念记忆内容，不需要进行概念解释或复杂体系阐述。解题过程仅需直接回忆教材中的基础定义即可完成，没有复杂的推理或分析步骤。" + }, + { + "idx": 381, + "question": "The driving force for solid-state phase transformation is (10), while the resistances are (11) and (12).", + "answer": "(10) free energy difference between new and old phases; (11) interface energy; (12) strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的术语或概念，需要学生对相关知识点的理解和记忆，属于简答题类型。答案不是从选项中选择，也不是判断对错或进行计算。 | 知识层次: 题目考查对固态相变驱动力和阻力的基本概念的记忆和理解，涉及自由能差、界面能和应变能等基础概念，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目要求填写固态相变的驱动力和阻力，答案直接对应基础概念记忆中的定义（自由能差、界面能、应变能），无需复杂解释或论述。在同类题型中，这属于最基础的知识点复现，解题步骤简单，仅需回忆相关定义即可完成。" + }, + { + "idx": 382, + "question": "Coincidence site lattice", + "answer": "Consider two identical and coinciding lattices $L_{1}$ and $L_{2}$. After rotating or translating $L_{2}$ relative to $L_{1}$, the lattices formed by the coinciding positions of the two lattices constitute a new periodic superlattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Coincidence site lattice\"进行文字解释和论述，答案提供了概念性的描述和定义，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对Coincidence site lattice（重合位置点阵）这一基本概念的定义和基本原理的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Coincidence site lattice\"的定义和形成过程，需要学生对相关概念有基本的理解和记忆，并能用文字进行描述。虽然涉及旋转和平移等操作，但整体仍属于对基础概念的解释范畴，不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 383, + "question": "The positional relationship between the screw dislocation line and the Burgers vector is (7), the positional relationship between the edge dislocation line and the Burgers vector is (8), and the dislocation whose dislocation line intersects obliquely with the Burgers vector is (9).", + "answer": "(7) parallel; (8) perpendicular; (9) mixed dislocation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定的术语来描述位错线与Burgers矢量之间的关系，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对位错类型与伯格斯矢量之间位置关系的基本概念记忆和理解，属于定义和分类层面的基础知识点。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并准确复述三种位错类型与伯格斯矢量的位置关系，无需解释或阐述复杂概念体系。题目直接考查基础概念记忆，属于该题型下最基础的难度层级。" + }, + { + "idx": 384, + "question": "The higher the diffusion temperature, the more conducive it is to diffusion.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查扩散温度与扩散速率之间关系的基本原理记忆，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆扩散温度与扩散速率的基本关系即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 385, + "question": "In the composition triangle of the A-B-C ternary system, for all alloys whose composition points lie on a line parallel to the AB side, the content of the (13) component is a fixed value.", + "answer": "(13) C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的成分名称（C），这属于需要简短文字回答的问题，而不是从多个选项中选择或判断对错。虽然答案很短，但题目没有提供选项，因此不属于选择题。 | 知识层次: 题目考查三元相图的基本概念和组成三角形的理解，属于基础概念的记忆和简单应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答三元相图中平行于AB边的线上合金的固定成分是什么（C组分），这属于对三元相图基本概念的直接记忆和简单应用，不需要进行概念解释或复杂体系阐述。" + }, + { + "idx": 386, + "question": "From a diffusion perspective, the mobility of low-angle grain boundaries is lower compared to that of high-angle grain boundaries.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶界扩散行为的基础概念记忆，仅需知道低角度晶界和高角度晶界在扩散中的相对迁移率差异即可判断，不涉及复杂分析或综合应用。 | 难度: 在判断题中属于中等难度，需要理解低角度晶界和高角度晶界在扩散过程中的迁移率差异这一概念，但不需要进行复杂的分析或比较多个概念。" + }, + { + "idx": 387, + "question": "The principle of zone refining is based on (16).", + "answer": "(16) Redistribution of solute during directional solidification of solid solution (fractional crystallization)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释区域精炼的原理，答案是一个文字解释，需要论述溶质在定向凝固过程中的再分配现象，符合简答题的特征。 | 知识层次: 题目考查对区域精炼原理这一基本概念的记忆和理解，属于材料科学中的基础理论知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释区域精炼的原理，需要考生理解并准确描述溶质在定向凝固过程中的再分配现象（分步结晶）。虽然涉及基本原理的记忆和解释，但不需要复杂的体系阐述或深入分析，属于中等难度的概念解释类简答题。" + }, + { + "idx": 388, + "question": "When stretching a single crystal, the slip plane is most prone to slip when it turns to an angle of (14) with the external force axis.", + "answer": "(14) 45°", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的角度值（45°），这属于需要简短回答的问题，而不是从多个选项中选择或判断对错。虽然看起来像填空题，但更符合简答题的特征，因为它需要理解材料科学中的概念来得出答案。 | 知识层次: 题目考查对单晶拉伸时滑移面最容易滑移的角度这一基本概念的记忆和理解，属于材料科学中的基础知识点。 | 难度: 在简答题题型中，该题目属于基础概念记忆类问题，仅需要回忆并复述\"单晶拉伸时滑移面最容易滑动的角度是45°\"这一基本原理。不需要进行概念解释或复杂体系阐述，符合等级1\"基本定义简答\"的标准。题目直接考查对单一知识点的记忆，解题步骤简单，属于该题型内最基础难度层级。" + }, + { + "idx": 389, + "question": "The decrease in volume free energy during the formation of a critical nucleus can only compensate for 1/3 of the newly added surface energy.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目给出一个陈述（The decrease in volume free energy during the formation of a critical nucleus can only compensate for 1/3 of the newly added surface energy），并要求判断对错（答案给出的是×表示错误），这符合判断题的特征。 | 知识层次: 题目涉及临界核形成过程中体积自由能和表面能量的关系，需要理解成核理论的基本原理，并能将自由能变化与表面能的关系进行定量分析。虽然不涉及复杂计算，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要理解临界核形成过程中体积自由能和表面能的关系，并进行综合分析判断。题目涉及多步概念关联和能量补偿比例的计算判断，超出了简单概念判断的范畴。" + }, + { + "idx": 390, + "question": "Both edge dislocations and screw dislocations have climb and glide motions.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案用×表示错误），符合判断题的特征 | 知识层次: 题目考查对位错类型及其运动方式的基本概念记忆和理解，属于基础概念层次 | 难度: 在判断题中属于中等难度，需要对位错的基本类型（刃型位错和螺型位错）及其运动方式（攀移和滑移）有准确的理解。虽然题目涉及的是基础概念，但需要区分两种位错类型的运动特点，比单纯记忆定义稍复杂。" + }, + { + "idx": 391, + "question": "Both thermoplastic and thermosetting plastics can be reused.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案以×表示错误，符合判断题的特征 | 知识层次: 题目考查对热塑性塑料和热固性塑料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对热塑性塑料和热固性塑料可重复使用性的基本概念理解，需要学生能够区分两种塑料的特性差异。虽然不涉及复杂概念或推理过程，但比单纯记忆定义的正误判断(等级1)要求更高一些，属于基础概念理解层面的判断。" + }, + { + "idx": 392, + "question": "In a binary system, the transformation that occurs at a certain temperature, L1 = L2 + α, is called (15) transformation.", + "answer": "(15) monotectic transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（monotectic transformation）来完成句子，而不是从多个选项中选择或进行判断、计算。这种形式更接近于简答题，需要考生回忆并填写正确的专业术语。 | 知识层次: 题目考查对二元系统中特定相变类型（monotectic transformation）的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并准确写出\"monotectic transformation\"这一特定术语即可完成作答，无需解释或阐述概念关系。该题完全符合基础概念记忆层级对术语再现的要求，是同类题型中最简单的考查形式。" + }, + { + "idx": 393, + "question": "Common strengthening methods for metallic materials include (17), (18), (19), and (20).", + "answer": "(17) Solid solution strengthening; (18) Grain refinement strengthening; (19) Second phase strengthening; (20) Work hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的强化方法名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目主要考查对金属材料常见强化方法的基本概念记忆，包括固溶强化、晶粒细化强化、第二相强化和加工硬化等基础知识的列举，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求列举金属材料的常见强化方法，不需要进行概念解释或复杂体系阐述。答案只需准确记忆并写出四种强化方式的英文名称即可，对知识点的掌握深度要求较低，解题步骤简单，属于该题型内最基础的难度等级。" + }, + { + "idx": 394, + "question": "The brittle phase is dispersed in granular form in the matrix of another phase, which is a microstructure state that is more beneficial to the strength and toughness of the material.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查对材料微观结构状态及其对性能影响的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在判断题中属于中等难度，虽然考察的是基础概念记忆，但需要理解\"脆性相以颗粒状分散在另一相基体中\"这一微观结构特征对材料强韧性的影响机制，比单纯记忆定义稍复杂，但不需要分析复杂概念陈述。" + }, + { + "idx": 395, + "question": "Grain boundaries with a misorientation angle less than $2^{\\circ}$ between adjacent grains are called high-angle grain boundaries.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为×表示错误），符合判断题的特征 | 知识层次: 题目考查对晶界分类的基本概念记忆，特别是低角度晶界和高角度晶界的定义，属于基础概念的记忆和理解。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对\"高角度晶界\"定义的记忆，无需理解或分析复杂概念，只需判断给定陈述是否符合基础定义。属于该题型中最基础的难度等级。" + }, + { + "idx": 396, + "question": "If the arrangement of atoms in the parent phase of an alloy is ordered, then after martensitic transformation, the arrangement of atoms in the martensite becomes disordered.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案以“×”表示错误，符合判断题的特征。 | 知识层次: 题目考查对马氏体相变后原子排列有序性的基本概念记忆和理解，属于基础概念层面的判断题。 | 难度: 在判断题中属于中等难度，需要理解马氏体相变的基本概念以及原子排列有序性的变化。虽然题目涉及的是基础概念，但需要考生对马氏体相变过程中原子排列的变化有一定的理解，而不仅仅是记忆定义。" + }, + { + "idx": 397, + "question": "What is the driving force for grain boundary migration?", + "answer": "The driving forces for grain boundary migration are: the stored energy of deformation and the chemical potential difference across the grain boundary caused by grain boundary curvature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述晶界迁移的驱动力，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目不仅要求记忆晶界迁移的驱动力，还需要理解其背后的机理（如变形储存能和化学势差），并解释这些因素如何共同作用。这涉及到多个概念的关联和综合分析，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅列举驱动力的类型（存储能和化学势差），还需要解释这些驱动力的产生原因（变形储存能和晶界曲率引起的化学势差）。这需要考生对晶界迁移的物理机制有较深入的理解，并能将多个概念联系起来进行解释，符合等级4对机理深度解释的要求。但题目未涉及多因素交互作用或动态过程分析等更复杂的层面，因此未达到等级5的复杂现象全面分析标准。" + }, + { + "idx": 398, + "question": "What is spinodal decomposition?", + "answer": "Spinodal decomposition is a special form of solid solution, where a single solid solution decomposes into two solid solutions with the same structure as the parent phase but different compositions through a diffusion clustering mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"spinodal decomposition\"进行文字解释和论述，答案提供了详细的定义和机制描述，符合简答题的特征。 | 知识层次: 题目考查对spinodal decomposition这一基础概念的定义和基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释spinodal decomposition的定义和基本原理，但不需要深入阐述复杂的概念体系或进行多层次的论述。虽然需要记忆和理解相关概念，但解题步骤相对简单，属于该题型中的中等难度。" + }, + { + "idx": 399, + "question": "Are the geometric conditions for the following dislocation reaction satisfied? Among them: b1=a/2[110], b2=a/6[12¯1], b3=a/6[211]", + "answer": "Geometric conditions: after the reaction b2+b3=a/6[12¯1]+a/6[211]=a/6[330]=a/2[110] before the reaction b1=a/2[110] the geometric conditions are satisfied", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求判断一个具体的陈述（位错反应的几何条件是否满足）是否正确，答案给出了明确的判断（几何条件满足）和验证过程，符合判断题的特征。 | 知识层次: 题目主要涉及位错反应的几何条件验证，通过简单的矢量相加和比较即可得出结论。虽然需要理解位错矢量的概念，但计算过程直接且无需多步推理或综合分析，属于基本公式应用和简单计算的范畴。 | 难度: 在判断题中属于中等难度，需要应用基本公式进行矢量计算和比较，但不需要复杂的推导或深入的概念理解。" + }, + { + "idx": 400, + "question": "What are the characteristics of the modulated structure?", + "answer": "The modulated structure exhibits a periodic pattern, with high dispersion, uniform distribution, and high connectivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释调制结构的特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对调制结构基本特征的理解和记忆，属于基础概念层次，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要回答多个特征（周期性、高分散性、均匀分布、高连通性），但这些都属于对调制结构的基本特性描述，不需要进行复杂的体系阐述或深入分析。题目主要考察对基础概念的记忆和简单归纳能力，符合等级2\"概念解释和描述\"的标准。" + }, + { + "idx": 401, + "question": "Explain the conditions for spinodal decomposition.", + "answer": "Conditions for spinodal decomposition: In a binary alloy phase diagram with a miscibility gap, the composition free energy curve has a range where ∂²G/∂x²<0, the temperature is sufficiently high for solute atoms to diffuse. (The decrease in free energy must be sufficient to overcome gradient energy and strain energy. This point is not required to be answered and will not be penalized.)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释spinodal decomposition的条件，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释spinodal分解的条件，涉及对二元合金相图、自由能曲线和扩散条件的理解，需要将多个概念关联起来进行综合分析。虽然不涉及复杂的计算或深度推理，但需要一定的理解和应用能力，超出了单纯的基础概念记忆。 | 难度: 在简答题中属于较高难度，需要理解并解释spinodal分解的条件，包括对二元合金相图中自由能曲线的二阶导数的理解，以及温度对扩散的影响。此外，题目还隐含了对梯度能和应变能的考虑，虽然不要求回答，但显示了问题的复杂性。这要求考生不仅掌握基本概念，还能进行多角度分析和论述。" + }, + { + "idx": 402, + "question": "What are the main factors affecting grain boundary migration?", + "answer": "The main factors affecting grain boundary migration rate: 1 solute atoms; 2 second-phase particles; 3 temperature; 4 orientation of grains on both sides of the grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响晶界迁移的主要因素，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对影响晶界迁移的主要因素的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列出并简要说明影响晶界迁移的主要因素，涉及多个基本概念（溶质原子、第二相粒子等）的列举和简单解释，但不需要深入分析或建立复杂的概念体系。这比单纯的定义简答（等级1）要求更高，但比需要系统阐述的复杂概念（等级3）要求低。" + }, + { + "idx": 403, + "question": "van der Waals bond", + "answer": "van der Waals bond: A physical bond formed by intermolecular attractive forces generated by instantaneous dipole moments and induced dipole moments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对van der Waals bond进行文字解释和论述，答案提供了详细的定义和形成机制，符合简答题的特征。 | 知识层次: 题目考查van der Waals bond的基本定义和形成原理，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目仅要求对van der Waals bond进行基本定义解释，属于最基础的概念记忆性知识。题目不涉及概念间的联系或复杂体系的阐述，仅需简单描述该键的形成机制即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 404, + "question": "Grain boundary", + "answer": "Grain boundary: The region of atomic misalignment at the interface where two grains meet.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Grain boundary\"这一术语进行文字解释和论述，答案是一个定义性的陈述，符合简答题的特征。 | 知识层次: 题目考查对\"Grain boundary\"这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不需要应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"Grain boundary\"进行基本定义回答，属于最基础的概念记忆层次。题目不涉及概念的解释、描述或复杂体系阐述，仅需简单回忆和复述定义即可完成作答，因此在该题型内属于最低难度等级。" + }, + { + "idx": 405, + "question": "Kirkendall effect", + "answer": "Kirkendall effect: A phenomenon in substitutional solid solutions where the relative diffusion of atoms of two components at different rates causes the migration of marker planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Kirkendall effect进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征 | 知识层次: 题目考查Kirkendall效应的定义和基本原理，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求对Kirkendall效应进行概念解释和描述，属于中等难度。虽然不需要阐述复杂的理论体系，但需要准确理解并表述该现象的基本原理和特征，比单纯的定义简答要求更高。" + }, + { + "idx": 406, + "question": "Tie line", + "answer": "Tie line: the line connecting the composition points of two equilibrium phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Tie line\"进行文字解释和定义，需要提供概念性的描述而非选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即Tie line的定义和基本含义，属于基础概念记忆层次。 | 难度: 在简答题中属于基本定义简答，仅需记忆并准确表述tie line的定义即可，不涉及复杂概念体系或深入解释。" + }, + { + "idx": 407, + "question": "Solid solution", + "answer": "Solid solution: When foreign components enter the crystal structure, occupying part of the host crystal phase's lattice sites or interstitial positions, while still maintaining a single crystal phase, such a crystal is called a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Solid solution\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对固体溶液（solid solution）这一基本概念的定义和特征的理解和记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答\"solid solution\"的基本定义，属于最基础的概念记忆性知识。题目不需要解释分类、原理或进行复杂阐述，仅需简单描述定义即可。在同题型（简答题）和同知识层次（基础概念记忆）下，这属于最基本的难度等级。" + }, + { + "idx": 408, + "question": "Is the energy condition for the following dislocation reaction satisfied? Where: b1=a/2[110], b2=a/6[12¯1], b3=a/6[211]", + "answer": "Energy condition: after the reaction |b2|^2+|b3|^2=(a^2/6^2)[1^2+2^2+(-1)^2]+(a^2/6^2)[2^2+1^2+1^2]=a^2/6+a^2/6=a^2/3 before the reaction |b1|^2=(a^2/2^2)(1^2+1^2)=a^2/2 the energy condition is satisfied and the dislocation reaction can proceed.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算来验证能量条件是否满足，解答过程中涉及到了具体的矢量计算和能量比较，属于典型的计算题类型。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错反应的能量条件，并进行具体的数值计算和比较。虽然计算过程相对直接，但需要对位错矢量的理解和能量条件的应用有一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解位错反应的能量条件，进行多步矢量计算和能量比较，涉及多个概念的综合应用和数值计算步骤。虽然计算过程明确，但需要较强的概念关联能力和综合分析能力。" + }, + { + "idx": 409, + "question": "Dislocation climb", + "answer": "Dislocation climb: The movement of an edge dislocation perpendicular to the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation climb\"进行文字解释和论述，答案是一个定义性的陈述，符合简答题的特征 | 知识层次: 题目考查的是位错攀移的基本定义，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"dislocation climb\"进行基本定义回答，属于最基础的概念记忆层面。题目不涉及概念间的关联性解释或复杂机制阐述，完全符合等级1\"基本定义简答\"的标准。同题型内相比，这比需要描述攀移驱动力的题目（等级2）或需要比较攀移与滑移机制的题目（等级3）简单得多。" + }, + { + "idx": 410, + "question": "Eutectoid transformation", + "answer": "Eutectoid transformation: The process in which a single solid phase simultaneously precipitates two new solid phases with different compositions and crystal structures is called eutectoid transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Eutectoid transformation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对eutectoid transformation这一基础概念的定义记忆和理解，属于材料科学相变中最基础的概念性知识，不涉及应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求对\"eutectoid transformation\"进行基本定义简答，属于最基础的概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需准确回忆并复述定义即可完成作答，符合等级1的基本定义简答标准。" + }, + { + "idx": 411, + "question": "Constitutional supercooling", + "answer": "Constitutional supercooling: During crystallization, the redistribution of solid and liquid phase compositions leads to the formation of a supercooled region in the liquid phase near the solid-liquid interface. This phenomenon is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Constitutional supercooling\"这一概念进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查的是对\"Constitutional supercooling\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及应用或分析层面的要求。 | 难度: 在简答题题型中，该题目要求对\"Constitutional supercooling\"进行概念解释和描述，需要理解并阐述结晶过程中固液相成分重新分布导致的现象。这属于概念解释和描述层次，比单纯的定义简答（等级1）要求更高，但不需要进行复杂概念体系的阐述（等级3）。题目在基础概念记忆的知识层次下，属于中等难度的简答题。" + }, + { + "idx": 413, + "question": "1. In the ionic crystal structure, the positive and negative ions form (1)", + "answer": "coordination polyhedron", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（coordination polyhedron）作为答案，属于需要简短文字回答的简答题类型 | 知识层次: 题目考查的是离子晶体结构中正负离子形成的基本概念，即配位多面体的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需回忆并写出\"coordination polyhedron\"这一特定术语即可，不需要进行概念解释或复杂体系阐述。题目直接考查对离子晶体结构中最基础组成单元的记忆，属于该题型内最基础的知识点考查。" + }, + { + "idx": 414, + "question": "For a carbon steel containing 0.1% carbon, carburized at 930‰, the carburized layer thickness is 0.4mm after 3 hours. Someone wants to obtain a 0.8mm carburized layer and plans to use 6 hours. Is this person's plan correct? Why?", + "answer": "$$ c{\\left(\\begin{array}{l l}{x,t}\\end{array}\\right)}=c_{1}+{\\left(\\begin{array}{l}{c_{8}-c_{1}}\\end{array}\\right)}{\\left(1-\\operatorname{erf}{\\frac{x}{2{\\sqrt{D t}}}}\\right)} $$ According to the problem, $c(\\textit{x}_{1},\\textit{t}_{1})=c(\\textit{x}_{2},\\textit{t}_{2})c_{s}$, and $c_{1}$ is a constant. Therefore, $$ \\operatorname{erf}{\\frac{x_{1}}{2{\\sqrt{D t_{1}}}}}=\\operatorname{erf}{\\frac{x_{2}}{2{\\sqrt{D t_{2}}}}} $$ Hence, $$ {\\frac{x_{1}}{2{\\sqrt{D t_{1}}}}}={\\frac{x_{2}}{2{\\sqrt{D t_{2}}}}}\\quad{\\frac{x_{1}}{\\sqrt{t_{1}}}}={\\frac{x_{2}}{\\sqrt{t_{2}}}},\\quad{\\frac{0.4}{\\sqrt{3}}}={\\frac{0.8}{\\sqrt{t_{2}}}} $$ $$ t_{2}={\\left({\\frac{0.8}{0.4}}\\times{\\sqrt{3}}\\right)}^{2}\\mathbf{h}=12\\mathbf{h} $$ Thus, the person's plan is incorrect.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来验证计划的正确性，解答过程中使用了扩散方程和误差函数进行数学推导和计算。 | 知识层次: 题目需要应用扩散方程和误差函数进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程和误差函数进行多步计算，涉及变量替换和公式推导，但未达到复杂多变量计算的程度。" + }, + { + "idx": 415, + "question": "1. In the ionic crystal structure, the distance between positive and negative ions depends on (2)", + "answer": "The sum of positive and negative ion radii", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释离子晶体结构中正负离子间距的决定因素，答案需要文字解释而非选择、判断或计算 | 知识层次: 题目考查的是离子晶体结构中正负离子间距与离子半径关系的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答离子晶体结构中正负离子间距的决定因素，属于最基础的定义性知识。只需记忆\"正负离子半径之和\"这一简单概念即可作答，无需解释或阐述复杂关系，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 416, + "question": "Multiple slip", + "answer": "Multiple slip: When the resolved shear stress on several slip systems is equal and simultaneously reaches the critical resolved shear stress, the phenomenon of simultaneous slip occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Multiple slip\"现象进行文字解释和论述，答案提供了概念性的描述而非选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即Multiple slip的定义和现象描述，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Multiple slip\"现象，需要理解并描述多个滑移系统同时达到临界分切应力的条件。虽然涉及多个滑移系统的概念，但不需要阐述复杂的理论体系或推导过程，属于中等难度的概念解释题。" + }, + { + "idx": 417, + "question": "3. The factors influencing the formation of substitutional solid solutions are _ (8)", + "answer": "Electronegativity", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写影响置换固溶体形成的因素，需要提供文字解释或论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对置换固溶体形成影响因素的基础概念记忆，主要涉及电负性等基本参数的认知，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答影响置换固溶体形成的因素，需要考生理解并描述相关概念（如电负性），但不需要进行复杂的体系阐述或多概念综合分析。这比单纯记忆基本定义（等级1）要求更高，但低于需要系统阐述复杂概念（等级3）的难度。" + }, + { + "idx": 418, + "question": "2. In polymer chains, the different spatial forms of molecules due to (4) are called conformations", + "answer": "Internal rotation of single bonds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个概念性的解释（Internal rotation of single bonds），而不是从多个选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查对聚合物链构象的基本概念的记忆和理解，涉及单键内旋转导致分子空间形态变化的基础知识，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回忆并准确写出\"Internal rotation of single bonds\"这一基础概念的定义，不需要进行额外的解释或论述。这符合等级1对基础概念记忆性知识的要求，解题步骤简单直接，仅需对相关术语有基本记忆即可完成。" + }, + { + "idx": 419, + "question": "2.The property of polymers that allows them to change conformation is called (5)", + "answer": "Flexibility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Flexibility）作为答案，而不是从多个选项中选择或判断对错，也不需要计算或公式应用。这种形式属于简答题，需要考生回忆并填写正确的术语。 | 知识层次: 题目考查聚合物基本性质的定义，属于基础概念的记忆和理解 | 难度: 在简答题题型中，此题属于基本定义简答的难度等级。题目仅要求回忆并写出聚合物能够改变构象的性质名称（Flexibility），不涉及概念解释或复杂体系阐述。这属于最基础的概念记忆层次，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 420, + "question": "3. The factors influencing the formation of substitutional solid solutions include _ (6)", + "answer": "Ionic size", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举影响置换固溶体形成的因素，需要文字解释和论述，答案形式为简短的文字描述 | 知识层次: 题目考查对形成置换固溶体的影响因素之一（离子尺寸）的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答影响置换固溶体形成的因素之一（离子尺寸），属于基础定义简答级别。题目不涉及概念解释或复杂体系阐述，仅需回忆单一知识点即可作答，符合等级1的基本定义简答特征。" + }, + { + "idx": 421, + "question": "1.In the ionic crystal structure, the coordination number depends on the (3) of the positive and negative ions", + "answer": "radius ratio", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（radius ratio）作为答案，而不是从多个选项中选择或进行判断/计算，符合简答题的特征 | 知识层次: 题目考查离子晶体结构中配位数与正负离子半径比的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题中属于基本定义简答，仅需回忆并写出\"radius ratio\"这一基础概念即可，无需展开解释或描述复杂关系。" + }, + { + "idx": 422, + "question": "3. The factors influencing the formation of substitutional solid solutions include _ (7)", + "answer": "Crystal structure type", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举影响置换固溶体形成的因素，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对置换固溶体形成影响因素的基础概念记忆，属于基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求列举影响置换固溶体形成的因素之一（晶体结构类型），不需要进行概念解释或复杂体系阐述，属于最基础的概念记忆性知识。" + }, + { + "idx": 423, + "question": "3. The factors influencing the formation of substitutional solid solutions include _ (9)", + "answer": "Electron concentration factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写影响置换固溶体形成的因素，需要简要的文字回答，而不是从选项中选择或判断对错，也不涉及计算。 | 知识层次: 题目考查的是影响置换固溶体形成的因素之一，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释影响置换固溶体形成的因素之一（电子浓度因素），属于概念解释和描述层次。虽然需要记忆特定知识点，但不需要复杂的体系阐述或多因素综合分析，因此属于中等难度（等级2）。" + }, + { + "idx": 424, + "question": "5. The two basic characteristics of martensitic transformation are (12)", + "answer": "Coherent shear", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答马氏体相变的基本特征，需要简要的文字解释和论述，而不是从选项中选择或判断对错。答案\"Coherent shear\"是一个简短的术语解释，符合简答题的特点。 | 知识层次: 题目考查马氏体相变的基本特征，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答马氏体相变的两个基本特征，答案\"Coherent shear\"是一个具体的、明确的定义性知识点，不需要复杂的解释或论述。这属于最基础的概念记忆层次，在简答题中属于最简单的类型。" + }, + { + "idx": 425, + "question": "6. Common methods for strengthening metal materials include: (15)", + "answer": "Dispersion strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属材料强化的常见方法，需要文字解释和论述，而不是从选项中选择或判断对错。答案\"Dispersion strengthening\"是一个具体的强化方法，但题目要求的是列举多种方法，因此更适合简答题形式。 | 知识层次: 题目考查金属材料强化方法的基本概念记忆，属于基础知识的直接回忆和列举，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，此题仅要求列举金属材料强化的常见方法之一（弥散强化），属于基础定义层面的简答。题目不要求解释原理或进行复杂论述，仅需记忆性知识即可作答，符合等级1\"基本定义简答\"的标准。相比需要概念解释（等级2）或体系阐述（等级3）的简答题，此题在同类题型中难度最低。" + }, + { + "idx": 426, + "question": "5. The two basic characteristics of martensitic transformation are (11)", + "answer": "Diffusionless transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答马氏体相变的基本特征，需要文字解释和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目考查马氏体相变的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答马氏体相变的两个基本特征之一，只需直接回忆并写出\"无扩散相变\"这一基础概念即可，无需进行额外的解释或论述。这符合等级1对基础概念记忆的要求，属于该题型下最简单的难度层级。" + }, + { + "idx": 427, + "question": "6. Common methods for strengthening metal materials include: (13)", + "answer": "Grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属材料的强化方法，答案需要提供具体的文字解释而非选择或判断 | 知识层次: 题目考查金属材料强化方法的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求列举金属材料的常见强化方法之一（晶粒细化强化），属于基础概念记忆层面的简单回答，无需深入解释或复杂论述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 428, + "question": "6.Common methods for strengthening metal materials include: (14)", + "answer": "Solid solution strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属材料强化的常见方法，需要文字解释和论述，而不是从选项中选择或判断对错。答案\"Solid solution strengthening\"是一个简短的文字回答，符合简答题的特征。 | 知识层次: 题目考查金属材料强化方法的基本概念记忆，属于基础概念和分类的记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举金属材料强化的常见方法，不需要进行概念解释或复杂体系阐述，属于最基础的概念记忆性知识。" + }, + { + "idx": 429, + "question": "4.The expression for the relationship between the diffusion coefficient, diffusion activation energy, and diffusion temperature is (10)", + "answer": "D=D0exp(-Q/RT)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出扩散系数、扩散激活能和扩散温度之间关系的表达式，需要提供具体的公式作为答案，属于简答题类型 | 知识层次: 题目考查扩散系数、扩散激活能和扩散温度之间关系的基本公式记忆，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需回忆并写出扩散系数与温度关系的标准表达式，不涉及概念解释或复杂推导，属于记忆性知识的最基础层级。" + }, + { + "idx": 430, + "question": "7. The typical ingot structure usually consists of (17)", + "answer": "Surface fine grain zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（\"Surface fine grain zone\"）作为答案，这属于需要简短文字回答的简答题类型，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查典型铸锭结构的基础概念记忆，仅需回忆和识别表面细晶区这一基本组成部分，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答\"典型铸锭结构通常包含\"的具体组成部分，属于基础概念记忆层面的简单问答。题目仅涉及单一知识点的直接回忆（表面细晶区），不需要概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。在同类记忆性简答题中属于最基础难度。" + }, + { + "idx": 431, + "question": "7.The typical ingot structure usually consists of (18)", + "answer": "columnar crystal zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（columnar crystal zone）作为答案，属于需要简短文字回答的类型，而非选择、判断或计算。 | 知识层次: 题目考查对典型铸锭结构的基本组成部分的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答\"柱状晶区\"这一基本定义，属于最基础的概念记忆性知识，不需要额外的解释或论述。与需要概念解释(等级2)或复杂体系阐述(等级3)的简答题相比，此题仅需直接回忆教材中的标准术语，属于该题型内最低难度等级。" + }, + { + "idx": 432, + "question": "Point defects are thermodynamically stable defects, and a certain number of equilibrium defects exist in crystals at a given temperature, also known as intrinsic defects.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对点缺陷（point defects）这一基本概念的记忆和理解，特别是关于热力学稳定性和本征缺陷的定义，属于基础概念记忆范畴。 | 难度: 在判断题中属于基本概念正误判断，仅需识别\"点缺陷是热力学稳定缺陷\"这一基础定义的正确性，无需深入理解或分析复杂概念。" + }, + { + "idx": 434, + "question": "7.Typical ingot structure usually has (19)", + "answer": "Central equiaxed crystal zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Central equiaxed crystal zone）来描述典型铸锭结构，这属于需要简短文字回答的问题类型，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查典型铸锭结构的基础概念记忆，属于材料科学中关于凝固组织的基本知识点，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回忆并写出典型铸锭结构的一个组成部分（中央等轴晶区），属于最基础的定义性知识。不需要解释或描述，更不需要复杂的概念体系阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 435, + "question": "Non-spontaneous nucleation still requires structural fluctuations, compositional fluctuations, and energy fluctuations.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），这是典型的判断题特征 | 知识层次: 题目考查对非自发成核所需条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目涉及非自发成核的基本要求（结构波动、成分波动和能量波动），需要学生对相关概念有一定理解才能正确判断，但不需要进行复杂的概念分析或综合应用。" + }, + { + "idx": 436, + "question": "The eutectic transformation occurs in systems where the liquid phase is completely miscible and the solid phase is completely immiscible.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用×表示错误），这是典型的判断题形式 | 知识层次: 题目考查共晶转变的基本概念，属于定义和基本原理的记忆性知识 | 难度: 在判断题中属于中等难度，需要理解共晶转变的基本概念以及液相和固相的互溶性关系，而不仅仅是记忆定义。" + }, + { + "idx": 437, + "question": "Polymers with simple structure, high regularity, and good symmetry are not prone to crystallization.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（对/错），答案以(×)形式明确表示该陈述是错误的，符合判断题的特征 | 知识层次: 题目考查对聚合物结晶基本原理的记忆和理解，属于基础概念层次 | 难度: 在判断题中属于中等难度，虽然考察的是基础概念记忆，但需要理解聚合物结晶性的影响因素（结构简单性、规则性和对称性），并判断题目陈述与这些基本原理的相符性。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念（等级3）的程度。" + }, + { + "idx": 438, + "question": "The reason why the carbon solubility of austenite is higher than that of ferrite is because the crystal interstices of austenite are larger.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用√表示正确），符合判断题的特征 | 知识层次: 题目考查对奥氏体和铁素体晶体结构中碳溶解度差异的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对奥氏体和铁素体碳溶解度差异原因的记忆，仅需判断晶体间隙大小的陈述是否正确，不涉及概念理解或复杂分析。属于该题型下最基础的难度等级。" + }, + { + "idx": 439, + "question": "8.The driving force for the coarsening of precipitates is (20)", + "answer": "The Gibbs free energy difference between different particles", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述沉淀物粗化的驱动力，答案是一个完整的句子解释，而不是选择、判断或计算。 | 知识层次: 题目考查对沉淀物粗化驱动力的基本概念的记忆和理解，即Gibbs自由能差这一基本原理。 | 难度: 在简答题题型中，该题目要求解释沉淀物粗化的驱动力，涉及对Gibbs自由能差这一基本概念的理解和描述。虽然需要一定的概念解释，但并不需要复杂的体系阐述或多步骤推理，属于概念解释和描述的难度等级。" + }, + { + "idx": 440, + "question": "In a ternary phase diagram, the degree of freedom at the eutectic temperature point is 0. At this time, it is a three-phase equilibrium.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（在共晶温度点自由度为零，此时为三相平衡），并要求判断该陈述的对错（答案给出×表示错误）。这符合判断题的特征。 | 知识层次: 题目考查对相图中自由度概念和三相平衡状态的基本理解，属于基础概念记忆范畴 | 难度: 在判断题中属于中等难度，需要理解相图的基本概念（如自由度、三相平衡）并正确应用，但不需要复杂的分析步骤。" + }, + { + "idx": 441, + "question": "During diffusion, solute atoms always migrate from high concentration to low concentration.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对或错），答案以(×)的形式给出，符合判断题的特征 | 知识层次: 题目考查扩散过程中溶质原子迁移方向的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基础概念正误判断。题目考察的是对扩散过程中溶质原子迁移方向这一基本概念的简单记忆，不需要复杂的理解或分析。在判断题的难度等级中，这属于最基础的等级1。" + }, + { + "idx": 442, + "question": "In the crystal structure of iodides, iodine occupies the corners of the cube and the body-centered position, so its structure type is body-centered lattice.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（碘在晶体结构中占据立方体角和体心位置，因此其结构类型为体心晶格），并要求判断该陈述的对错（答案给出×表示错误）。这符合判断题的特征。 | 知识层次: 题目考查晶体结构类型的基本概念记忆和理解，涉及简单的晶体结构分类知识，不需要复杂的分析或应用。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目仅考察对晶体结构类型（体心立方）这一基础概念的记忆，不需要深入理解或分析。学生只需记住碘在立方体中的位置分布即可判断对错，属于该题型中最简单的难度等级。" + }, + { + "idx": 443, + "question": "The yield strength σs of crystalline materials changes with the variation of the tensile axis relative to the crystal orientation.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用√表示正确），这是典型的判断题特征 | 知识层次: 题目考查的是对晶体材料屈服强度与晶体取向关系这一基本概念的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆晶体材料屈服强度与拉伸轴方向关系的基础定义即可作答，无需理解或分析复杂概念。在判断题题型内属于最基础的难度等级。" + }, + { + "idx": 444, + "question": "Generally speaking, during solid-state phase transformations, crystal defects in the parent phase can promote the formation of the new phase.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查的是关于固态相变中晶体缺陷作用的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对固态相变中晶体缺陷作用的基础概念记忆，无需深入理解或复杂推理，只需判断陈述是否符合基本原理即可。属于该题型下最基础的难度等级。" + }, + { + "idx": 445, + "question": "What is the total cost for carburizing 500 gears at 900°C (1173K) for 10 hours, given the cost is 1000 yuan per hour?", + "answer": "Total cost = 1000 yuan/h * 10 h = 10000 yuan", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（1000 yuan/h * 10 h）来得出总成本，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接应用和简单计算，无需多步推理或综合分析 | 难度: 在计算题中属于最简单难度，仅需单一公式直接计算（总成本=每小时成本×时间），无需任何公式组合或复杂步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 446, + "question": "What is the total cost for carburizing 500 gears at 1000°C (1273K) for 3.299 hours, given the cost is 1500 yuan per hour?", + "answer": "Total cost = 1500 yuan/h * 3.299 h = 4948.5 yuan", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（500 gears的处理时间乘以每小时的成本），答案是一个具体的数值结果（4948.5 yuan），符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接应用和简单计算，无需多步推理或综合分析 | 难度: 在计算题中属于最低难度，仅需单一公式直接计算（总成本=每小时成本×时间），无需任何公式转换或多步骤计算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 447, + "question": "What is the equivalent time required to achieve the same carburization depth at 1000°C (1273K) as 10 hours at 900°C (1173K), given Q=32900 cal/mol and R=1.987 cal?", + "answer": "t_1273 = D_1173 * t_1173 / D_1273 = 10 * exp[-32900/(1.987*1173)] / exp[-32900/(1.987*1273)] = 10 * exp(-14.1156) / exp(-13.0068) h = 10 * exp(-1.5089) h = 10 * 0.3299 h = 3.299 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及指数函数和温度转换，最终得出具体的时间数值。答案展示了详细的推导过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括扩散系数的计算和等效时间的推导，涉及公式应用和数值计算，需要理解扩散过程的基本原理和数学表达，但不需要复杂的推理或创新性思维。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程和Arrhenius公式进行多步计算，涉及温度转换、指数运算和单位换算，但未达到复杂多变量计算的程度。" + }, + { + "idx": 448, + "question": "Explain the reason for cold deformation strengthening of pure metals using dislocation theory", + "answer": "Strengthening reason: Dislocation intersection produces kinks and jogs, dislocation reactions produce immobile dislocations, and dislocation multiplication increases dislocation density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纯金属冷变形强化的原因，需要使用位错理论进行文字解释和论述，答案也是以文字形式呈现的论述内容。 | 知识层次: 题目要求运用位错理论解释纯金属冷变形强化的原因，涉及位错相互作用、位错反应和位错增殖等复杂机理的分析和综合运用，需要深入理解和推理分析多个相关概念及其关联性。 | 难度: 在简答题（需要文字解释和论述）题型中，该题目要求运用位错理论对纯金属冷变形强化机理进行深度解释。需要掌握位错运动、相互作用（如形成扭折和割阶）、位错反应产生不可动位错以及位错增殖等核心概念，并能将这些概念有机整合形成完整的机理解释框架。虽然不涉及多现象交叉分析（等级5特征），但对单一强化机理的阐述深度已达到等级4的\"机理深度解释\"要求，属于该题型中较高难度的理论分析题。" + }, + { + "idx": 449, + "question": "At which temperature is the carburization cost lower for processing 500 gears to achieve the same depth?", + "answer": "The cost at 1000°C (4948.5 yuan) is lower than at 900°C (10000 yuan), so 1000°C is more cost-effective.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种温度下的成本，并给出更经济的选择，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要比较不同温度下的成本效益，涉及多步计算和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在简答题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较两种温度下的成本，并进行简单的计算和解释，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 450, + "question": "What effect does a rough interface have on the crystal growth mode?", + "answer": "For a rough interface, continuous growth occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释粗糙界面对晶体生长模式的影响，答案提供了文字解释而非选择、判断或计算 | 知识层次: 题目考查晶体生长模式的基本概念，特别是粗糙界面对生长模式的影响，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目仅要求回答粗糙界面对晶体生长模式的基本影响，属于最基础的定义性知识。答案直接给出\"continuous growth occurs\"这一核心结论，无需展开解释或论述其他相关概念，符合等级1\"基本定义简答\"的标准。相比需要描述机制（等级2）或分析多因素相互作用（等级3）的简答题，本题的认知负荷最低。" + }, + { + "idx": 451, + "question": "Changes occurring during recrystallization annealing", + "answer": "Changes occurring: During annealing, the dislocation density decreases, deformed grains transform into equiaxed grains, residual stresses are eliminated, and strength and hardness are reduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释再结晶退火过程中发生的变化，答案以文字形式详细描述了这些变化，符合简答题的特征。 | 知识层次: 题目考查对再结晶退火过程中发生的变化的基本概念记忆和理解，包括位错密度减少、晶粒形状变化、残余应力消除以及强度和硬度降低等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要列举多个变化过程（位错密度降低、晶粒形态转变、残余应力消除、力学性能变化），但每个变化点都是基础概念的直接应用，不需要建立复杂的逻辑关系或进行深入分析。相比等级1的单纯定义复述，该题要求对再结晶退火过程有较全面的记忆性理解；相比等级3需要阐述机理或影响因素的要求，本题仍停留在现象描述的层面。" + }, + { + "idx": 452, + "question": "Approximate process parameters for recrystallization annealing", + "answer": "Process parameters: Heating temperature T=0.4Tm plus 100~200Ω, heating time depends on the specific furnace load and workpiece size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供近似的过程参数，答案以文字解释和论述的形式给出，没有涉及选择题的选项、判断题的对错判断或计算题的数值计算。 | 知识层次: 题目要求回答再结晶退火的近似工艺参数，涉及基本公式应用（T=0.4Tm）和简单参数范围（100~200Ω）的直接套用，属于简单应用层次。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求考生直接套用基本公式（0.4Tm）并给出温度范围，同时简单说明加热时间的影响因素。解题步骤简单直接，不需要深入分析或详细解释，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 453, + "question": "What is a rough interface?", + "answer": "Rough interface: It is a solid-liquid interface where the atomic arrangement on the solid-phase surface is uneven and rough, displaying no crystallographic plane characteristics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"rough interface\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对粗糙界面这一基本概念的定义和特征描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。题目直接询问\"rough interface\"的定义，答案只需简单描述其基本特征（固体表面原子排列不均匀、无结晶学平面特征），不需要进行概念解释或复杂体系阐述。在简答题的基础概念记忆类别中，这属于最简单的等级1难度。" + }, + { + "idx": 454, + "question": "What is a smooth interface?", + "answer": "Smooth interface: It is another type of solid-liquid interface where the atoms on the solid-phase interface are arranged into a flat atomic plane, specifically a certain crystallographic plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“smooth interface”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对平滑界面这一基本概念的定义和特征的理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层面。题目直接询问\"smooth interface\"的定义，答案只需简单描述其基本特征（固体相界面原子排列成平坦原子面），无需展开解释或与其他概念关联。在同题型框架内，这属于仅需记忆定义即可回答的初级难度问题。" + }, + { + "idx": 455, + "question": "How to completely eliminate work hardening? Explain the heat treatment method used", + "answer": "Method to eliminate work hardening: recrystallization annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何完全消除加工硬化，并说明使用的热处理方法，需要文字解释和论述。答案提供了方法但没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目不仅需要理解再结晶退火的基本概念（基础层次），还需要解释如何通过这种热处理方法消除加工硬化，涉及概念关联和综合分析（中等应用层次）。 | 难度: 在简答题题型中，该题目属于中等难度。虽然问题明确要求解释消除加工硬化的热处理方法（再结晶退火），但需要考生理解加工硬化的本质、再结晶退火的作用机理，并能将两者关联起来进行说明。这需要一定的概念关联和综合分析能力，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 456, + "question": "Can the perfect dislocation $\\pmb{b}_{1}$ in a face-centered cubic crystal decompose into partial dislocations $b_{2}, b_{3}?$ Given ${\\pmb b}_{1}=\\frac{a}{2}[\\stackrel{-}{1}10], {\\pmb b}_{2}=\\frac{a}{6}[\\stackrel{-}{1}2\\stackrel{-}{1}], {\\pmb b}_{3}=\\frac{a}{6}[\\stackrel{-}{2}11],$ state the reasons.", + "answer": "Geometric condition: $\\begin{array}{l}{{\\vec{b}_{1}=a/2\\cdot\\left[\\stackrel{\\rightharpoonup}{1}10\\right]}}\\ {{}}\\ {{\\vec{b}_{2}+\\stackrel{\\rightharpoonup}{b}_{3}=a/6\\cdot\\left[\\stackrel{\\rightharpoonup}{3}30\\right]=a/2\\cdot\\left[\\stackrel{\\rightharpoonup}{1}10\\right]}}\\end{array}$ Energy condition: $\\mid\\vec{b}_{1}\\mid^{2}=(a/2\\sqrt{1+1+0})^{2}=a^{2}/2$ $|\\vec{b}_{2}|^{2}+|\\vec{b}_{3}|^{2}=(a/6\\sqrt{1+4+1})^{2}+\\bigl(a/6\\sqrt{4+1+1}^{2}=a^{2}/3
Plate martensiteLenticular shape
Lath martensiteLong columnar shape with elliptical cross-section
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述板条马氏体和片状马氏体在三维形态上的差异，需要文字解释和论述，答案以表格形式呈现了两种马氏体的形态特征，符合简答题的特点。 | 知识层次: 题目主要考查对板条马氏体和片状马氏体三维形态差异的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求描述板条马氏体和片状马氏体的三维形态差异，这需要学生对两种马氏体的基本形态特征有清晰的理解和记忆，并能够用文字进行准确描述。虽然涉及两个概念的比较，但不需要深入分析或阐述复杂的概念体系，因此属于中等难度。" + }, + { + "idx": 462, + "question": "Screw dislocation", + "answer": "A dislocation where the dislocation line is parallel to the Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Screw dislocation\"进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是对螺型位错的定义和特征的认识。 | 难度: 在简答题题型中，该题目仅要求对\"Screw dislocation\"进行基本定义简答，属于最基础的概念记忆性知识。题目仅需回答位错线与伯格斯矢量平行的位错类型，不需要进行概念解释或复杂体系阐述，符合等级1的基本定义简答标准。" + }, + { + "idx": 463, + "question": "Explain the differences in metallographic structure between plate martensite and lath martensite", + "answer": "
Plate martensiteThe initially formed martensite needles traverse the austenite grains, while subsequently formed ones gradually become smaller. The plates are not parallel to each other. Those with C%>1.4% have a midrib
Lath martensiteThe original austenite grains are divided into several blocks, each consisting of several lath bundles, and each lath bundle is composed of many parallel lath martensites
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释板条马氏体和片状马氏体在金相组织上的差异，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求解释板条马氏体和片状马氏体在金相组织上的差异，这需要对马氏体相变机制、晶体结构、显微组织特征等有深入的理解和分析能力。答案中不仅描述了两种马氏体的形态特征，还涉及了它们的形成过程和相互关系，属于对多个概念的关联和综合分析。 | 难度: 在简答题题型中，该题目要求对两种马氏体的金相结构进行详细解释和比较，涉及复杂的显微组织特征描述和形成机理分析。虽然不需要进行跨学科的综合分析，但需要对马氏体转变有深入理解，并能准确描述其显微组织特征。这属于机理深度解释的范畴，但尚未达到需要综合分析多个复杂现象的最高难度。" + }, + { + "idx": 464, + "question": "Explain the difference in substructure between plate martensite and lath martensite", + "answer": "
Plate martensiteThere are a large number of twins in the middle of the martensite, and dislocations at the edges. The midrib is fine twins
Lath martensiteThere are high-density dislocations inside the martensite, forming dislocation cells
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释板条马氏体和片状马氏体的亚结构差异，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求解释板条马氏体和板状马氏体的亚结构差异，这需要对马氏体相变的微观机制有深入理解，涉及位错、孪晶等缺陷结构的综合分析，属于对材料微观结构的复杂分析。 | 难度: 在简答题题型中，该题目要求对两种马氏体的亚结构进行机理深度解释，需要综合运用材料科学知识分析孪晶和位错分布的差异。虽然不涉及多因素交互作用的复杂现象全面分析(等级5)，但已超出基础描述层面，属于需要深入理解晶体缺陷和相变机理的难度等级。" + }, + { + "idx": 466, + "question": "Sorbite", + "answer": "A product of medium-temperature pearlite transformation, composed of lamellar ferrite and cementite, with smaller interlamellar spacing and thinner layers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Sorbite\"进行解释和描述，需要文字论述其组成和特征，属于简答题类型 | 知识层次: 题目考查对Sorbite这一材料科学基本概念的记忆和理解，涉及定义和组成，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Sorbite\"的定义和组成，涉及中等温度珠光体转变产物的基本概念，需要描述其层状铁素体和渗碳体的结构特征以及层间距和层厚的特点。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或深入分析，属于该题型中的中等难度。" + }, + { + "idx": 467, + "question": "Cross-slip", + "answer": "The slip process transitions from one slip plane to another along the same slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Cross-slip\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查对Cross-slip这一基础概念的定义和基本过程的理解，属于记忆性知识范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于概念解释和描述难度，需要理解并描述cross-slip的过程，但不需要涉及复杂的概念体系或深入的分析。" + }, + { + "idx": 468, + "question": "Frenkel defect", + "answer": "The displacement of an atom to an interstitial site in the crystal lattice is called a Frenkel defect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对Frenkel defect进行文字解释和论述，答案提供了概念的定义和描述，符合简答题的特征。 | 知识层次: 题目考查Frenkel defect的基本定义，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答Frenkel defect的基本定义，属于最基础的概念记忆性知识。不需要进行额外的解释或描述，也不涉及复杂的概念体系阐述。因此，在同题型内属于最简单的等级1难度。" + }, + { + "idx": 469, + "question": "Pseudoeutectoid transformation", + "answer": "Pseudoeutectoid transformation: During non-equilibrium transformation, hypoeutectoid or hypereutectoid alloys near the eutectoid composition point exhibit a fully eutectoid microstructure upon completion of the transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"Pseudoeutectoid transformation\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对伪共析转变这一非平衡转变过程的理解和应用，需要将合金成分与共析点附近的关系、非平衡条件对显微组织的影响等概念进行关联分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对非平衡转变条件下的伪共析转变进行解释，涉及对亚共析或过共析合金在共析成分点附近的微观结构变化的综合分析。需要考生不仅理解基本概念，还能关联非平衡转变与平衡转变的差异，并解释微观结构的形成机制。这属于多角度分析论述的难度等级，比单纯的概念解释（等级3）更复杂，但尚未达到需要深度关联性分析（等级5）的程度。" + }, + { + "idx": 470, + "question": "Perfect dislocation", + "answer": "A dislocation whose Burgers vector equals a lattice vector is called a perfect dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Perfect dislocation\"进行定义和解释，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即完美位错的定义，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"perfect dislocation\"进行基本定义简答，属于最基础的概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接回忆并复述定义内容，符合等级1的难度标准。" + }, + { + "idx": 471, + "question": "Coordination polyhedron", + "answer": "The polyhedron formed by connecting the centers of atoms or ions directly bonded to a central atom or ion is called the coordination polyhedron of that atom or ion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Coordination polyhedron\"进行定义和解释，需要文字描述和论述，属于简答题类型。 | 知识层次: 题目考查对配位多面体这一基本概念的定义记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"coordination polyhedron\"这一基础概念进行定义性的回答，属于最基本的概念记忆层次。题目不涉及概念的解释、比较或应用，也不需要阐述相关概念体系，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最基础、最简单的题型要求。" + }, + { + "idx": 472, + "question": "4. According to the different atomic arrangement structures at the interface, what three types of interfaces can phase interfaces in solids be divided into?", + "answer": "Coherent, semi-coherent, incoherent", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举不同类型的界面，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对固体中相界面分类的基本概念记忆，仅需回答三种界面类型名称，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答三种界面类型的名称（Coherent, semi-coherent, incoherent），属于最基础的定义简答。题目不涉及概念解释或复杂体系阐述，仅测试学生对基础分类的记忆能力，符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最基础的知识点再现型问题。" + }, + { + "idx": 473, + "question": "1. How many independent slip systems must be activated for plastic deformation in polycrystalline materials?", + "answer": "5", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（5），但不需要计算过程或从多个选项中选择，属于需要简短回答的问题 | 知识层次: 题目考查的是关于多晶材料塑性变形所需独立滑移系统数量的基本概念记忆，属于材料科学中的基础知识点，不需要复杂的分析或应用。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并写出独立滑移系统的数量要求（5个），无需进行概念解释或复杂体系阐述，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 474, + "question": "The number-average relative molecular mass of polymers ( $\\overline{{{\\cal M}_{n}}}$ )", + "answer": "The relative molecular mass of polymers weighted by number, $\\widetilde{M_{n}}=\\sum_{i}{N_{i}M_{i}}/{\\sum{N_{i}}}$, where $N_{i}$ is the molar fraction of molecules with molecular weight $M_{i}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物的数均相对分子质量的定义，并给出了详细的公式和文字说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查聚合物数均相对分子质量的基本定义和计算公式，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答聚合物的数均相对分子质量的基本定义和计算公式，属于基础概念记忆的范畴。题目不需要复杂的解释或论述，仅需简单描述定义和公式即可。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 475, + "question": "2. During solid-state phase transformation nucleation, when the nucleus morphology is disk-shaped, it has the minimum what energy and the maximum what?", + "answer": "strain energy, interface", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求填写两个特定的能量类型（strain energy和interface），需要根据对固态相变成核过程中能量变化的理解来回答，属于简答题类型。 | 知识层次: 题目涉及固态相变中核形态的能量分析，需要理解应变能和界面能的概念及其在特定核形态下的变化，属于多概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解固态相变成核过程中的能量最小化和界面最大化概念，并进行综合分析说明。题目要求解释特定形态（盘状）下的能量和界面特性，涉及多步概念关联，但不需要过于深入的多角度或深度关联性分析。" + }, + { + "idx": 476, + "question": "Explain the differences in mechanical properties between plate martensite and lath martensite", + "answer": "
Plate martensiteHard and brittle
Lath martensiteStrong and tough
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种马氏体在机械性能上的差异，需要文字解释和论述。答案以表格形式呈现了对比信息，属于简答形式而非选择、判断或计算。 | 知识层次: 题目要求解释两种马氏体在机械性能上的差异，需要理解马氏体的微观结构特征及其与宏观性能的关联，属于概念关联和综合分析层次。虽然不涉及复杂计算，但需要将微观结构与宏观性能进行关联分析，思维深度高于简单记忆或直接套用。 | 难度: 在简答题题型中，该题目要求对两种马氏体的机械性能差异进行综合分析和说明。虽然需要理解并比较两种马氏体的特性，但不需要进行多角度或深度关联性分析，因此属于中等难度。" + }, + { + "idx": 477, + "question": "3. In solid-state crystals, diffusion can be classified into which two types based on whether new phase structures are formed during atomic diffusion?", + "answer": "Atomic diffusion and reactive diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和分类扩散类型，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对固态晶体中扩散类型的基本分类记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答扩散的两种分类类型，不需要进行概念解释或复杂阐述，仅需记忆性知识即可回答。这符合基础概念记忆的知识层次要求，且解题步骤非常简单直接。" + }, + { + "idx": 479, + "question": "7. What are the main structural types (subtypes) of silicate crystals?", + "answer": "Island, group (or ring), chain, layer, framework", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举硅酸盐晶体的主要结构类型，答案需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对硅酸盐晶体主要结构类型的基础分类记忆，属于基本概念的记忆性知识。 | 难度: 在简答题题型中，此题仅要求列举硅酸盐晶体的主要结构类型（亚型），属于基础概念记忆层次。题目不涉及解释、描述或复杂概念体系的阐述，仅需回忆并列出五个基本分类名称即可。在同类简答题中，这是最基础的定义性简答，无需任何分析或扩展说明。" + }, + { + "idx": 480, + "question": "6. In polymers, the different spatial forms of molecules caused by what are called conformations, and the property of polymers to change conformations is called what?", + "answer": "Single bond internal rotation, flexibility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物分子空间形态变化的原因和性质名称，需要文字解释和论述，答案也是以文字形式给出。 | 知识层次: 题目考查聚合物分子构象变化的基本概念和定义，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目仅要求回答基本定义和简单概念，属于最基础的记忆性知识。题目明确询问聚合物构象变化的原因和性质名称，答案直接对应教材中的基础定义（单键内旋转和柔顺性），无需展开解释或复杂论述。在同题型框架内，这属于仅需简单回忆即可作答的等级1难度。" + }, + { + "idx": 481, + "question": "What is the ground-state electron configuration of Cr (atomic number 24)?", + "answer": "1s22s22p63s23p63d54s1", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出铬（Cr）的基态电子排布，需要根据原子序数24和电子排布规则进行文字描述，答案是一个具体的电子排布式，而非选择、判断或计算。 | 知识层次: 题目考查对原子基态电子排布的基本概念记忆，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题中属于中等难度，需要理解并记忆电子排布的基本规则，并能够应用洪特规则解释铬的特殊电子构型。虽然不涉及复杂的概念体系阐述，但需要一定的概念解释和描述能力。" + }, + { + "idx": 482, + "question": "9.Linear polymers can be reused and are also called what kind of plastic; cross-linked polymers cannot be reused and are called what kind of plastic?", + "answer": "Thermoplastic, thermosetting", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述两种塑料的名称，而不是从选项中选择或判断对错，也不需要计算。答案也是以文字形式给出。 | 知识层次: 题目考查对线性聚合物和交联聚合物的基本分类和名称的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答两种塑料的分类名称（热塑性和热固性），不涉及概念解释或复杂体系阐述。这属于最基础的概念记忆性知识，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 483, + "question": "8. Intermetallic compounds typically include what controlled by electronegativity, close-packed phases primarily governed by atomic size, and what mainly controlled by electron concentration?", + "answer": "Normal valence compounds, topologically close-packed phases, electron compounds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答关于金属间化合物类型的问题，答案需要提供具体的术语和概念，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对金属间化合物分类的基本概念记忆，包括电负性控制的正价化合物、原子尺寸控制的密排相和电子浓度控制的电子化合物。这些都属于材料科学中基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述三类金属间化合物的控制因素，涉及多个概念但不需要深入阐述复杂体系。属于概念解释和描述级别，比基本定义简答稍难，但未达到复杂概念体系阐述的程度。" + }, + { + "idx": 484, + "question": "In the bainitic transformation, neither Fe nor C atoms undergo diffusion.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查贝氏体转变过程中Fe和C原子扩散行为的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 该判断题属于基础概念正误判断，仅需记忆bainitic相变的基本特征（Fe和C原子不扩散）即可作答，无需深入理解或分析。在判断题的基础概念记忆层次中属于最简单的直接正误判断类型。" + }, + { + "idx": 485, + "question": "In the solid-state crystal diffusion process, the direction of diffusing atom migration is always from high concentration to low concentration.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查固体晶体扩散过程中原子迁移方向的基本概念，属于对基本原理的记忆和理解。 | 难度: 该判断题属于基础概念正误判断，仅需记忆扩散过程的基本原理即可作答，无需深入理解或分析复杂概念，在同题型内属于最简单的难度等级。" + }, + { + "idx": 486, + "question": "The finer the grain size, the higher the strength and hardness of the crystal, and the better the plasticity and toughness.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查的是晶粒尺寸与材料力学性能（强度、硬度、塑性、韧性）之间关系的基本概念记忆，属于材料科学中最基础的知识点之一，不需要复杂的分析或计算。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆材料科学中关于晶粒尺寸与力学性能关系的基础知识即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 487, + "question": "During solid-state phase transformation, crystal defects in the parent phase hinder the formation of nuclei of the new phase.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（固态相变过程中母相晶体缺陷阻碍新相晶核形成），要求判断对错（√表示正确），符合判断题的特征。答案形式为简单的对错标记，不需要选择、计算或文字解释。 | 知识层次: 题目考查对固态相变过程中晶体缺陷对形核影响的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在判断题的基础概念记忆层次中，此题仅需判断关于固态相变中晶体缺陷对成核影响的基本陈述是否正确，属于最基础的正误判断，无需深入理解或分析复杂概念。" + }, + { + "idx": 489, + "question": "Component crystal types differ, but under specific conditions, they can also form infinitely miscible solid solutions.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案给出的是×，表示错误），符合判断题的特征 | 知识层次: 题目考查对晶体类型和固溶体形成条件的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解\"无限互溶固溶体\"的形成条件这一概念，并判断其在特定条件下的适用性。虽然不涉及复杂推理，但需要掌握晶体类型和固溶体形成条件的基本知识。" + }, + { + "idx": 490, + "question": "Polymers with simple structures, high regularity, and good symmetry are prone to crystallization.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物结晶基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，该题目属于最基本的难度等级。题目直接考察对聚合物结晶条件的记忆（简单结构、高规整性和良好对称性），只需判断陈述是否符合基础定义，无需任何推理或复杂概念分析。" + }, + { + "idx": 491, + "question": "Two edge dislocations with opposite signs and parallel dislocation lines on the same slip plane will move away from each other due to their interaction.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征 | 知识层次: 题目考查对位错相互作用的基础概念的记忆和理解，属于基本原理的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目涉及位错相互作用的基本原理，需要理解相反符号位错在同一滑移面上的运动趋势，而不仅仅是记忆定义或分类。虽然不涉及复杂概念或综合分析，但比单纯的正误判断要求更高的理解深度。" + }, + { + "idx": 492, + "question": "What is aging?", + "answer": "Aging: The precipitation process of a supersaturated solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语进行解释，答案以文字形式给出，属于简答题类型 | 知识层次: 题目考查对\"aging\"这一基础概念的定义记忆和理解，属于材料科学中相变基础知识的范畴，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。题目没有要求解释或描述概念，也没有涉及复杂概念体系的阐述，因此属于等级1难度。" + }, + { + "idx": 493, + "question": "In the cesium chloride structure, chlorine occupies the corner positions and the body center position of the cube, so its structure type is body-centered lattice.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（关于氯化铯结构的描述），并要求判断其正确性（答案为×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对氯化铯晶体结构类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解氯化铯晶体结构的基本概念，并能够区分体心立方晶格和简单立方晶格的区别。虽然题目涉及的是基础概念记忆，但需要对晶体结构有准确的理解才能正确判断。" + }, + { + "idx": 494, + "question": "What are the main morphological types of martensitic transformation products in steel?", + "answer": "(2) Morphology of transformation products: lath martensite (1 point); acicular martensite. (1 point)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并简要说明钢中马氏体转变产物的主要形态类型，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查马氏体转变产物的主要形态类型，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求列举钢中马氏体转变产物的主要形态类型，不需要进行概念解释或复杂体系阐述。答案只需直接写出两种形态名称（板条马氏体和针状马氏体），属于最基础的概念记忆性知识，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 495, + "question": "The reason why the carbon solubility of austenite is higher than that of ferrite is that the interstitial spaces in the austenite crystal structure are larger.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用√表示正确），符合判断题的特征 | 知识层次: 题目考查对奥氏体和铁素体中碳溶解度的基本概念记忆，以及晶体结构中间隙大小的理解，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，此题仅需判断关于奥氏体和铁素体碳溶解度的基本事实陈述是否正确，属于最基础的定义性知识判断，无需复杂推理或概念比较。" + }, + { + "idx": 496, + "question": "What processes does aging typically undergo?", + "answer": "Aging process: 1) Formation of GP zones. 2) Formation of a series of metastable intermediate phases that maintain coherency or semi-coherency with the parent phase. 3) Formation of stable precipitates. 4) Coarsening and growth of stable precipitates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释老化过程的具体步骤，答案以列举和描述的形式给出，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释时效过程的不同阶段，涉及多个步骤和概念关联，需要综合分析时效过程中相变和析出的顺序及其特点，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求解释和论述老化过程的不同阶段，但每个阶段的描述相对明确，且不需要进行多角度或深度关联性分析。解题步骤较为直接，主要涉及对老化过程各阶段的列举和简要说明，符合\"综合分析和说明\"的难度标准。" + }, + { + "idx": 497, + "question": "What are the intracrystalline substructures of martensitic transformation products in steel?", + "answer": "(3) Intracrystalline substructure: Lath martensite mainly consists of high-density dislocations (1 point); acicular martensite has high-density twins with some dislocations at the edges. (1 point)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体转变产物的晶内亚结构，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查马氏体转变产物的晶内亚结构，属于对基础概念的记忆和理解，如板条马氏体和针状马氏体的亚结构特征。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生描述马氏体转变产物的晶内亚结构，涉及两种马氏体的具体特征（位错和孪晶），但不需要复杂的体系阐述或深入分析。这比单纯的定义简答（等级1）要求更高，但比需要系统阐述多个相关概念的题目（等级3）简单。" + }, + { + "idx": 498, + "question": "What are the main characteristics of martensitic transformation in steel?", + "answer": "(1) Transformation characteristics: $\\textcircled{1}$ Diffusionless, neither Fe nor C atoms diffuse. (2 points) $\\textcircled{2}$ Coherent shear, with habit plane and orientation relationship between the new phase and parent phase. (2 points) $\\textcircled{3}$ Non-isothermal nature. (1 point) $\\textcircled{4}$ Incompleteness of martensitic transformation. (1 point)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变的主要特征，答案以文字论述的形式给出，没有选项或计算要求，符合简答题的特点。 | 知识层次: 题目考查马氏体相变的主要特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答马氏体转变的主要特征，涉及扩散、共格剪切、非等温性和转变不完全性等基本概念，需要对这些概念进行解释和描述，但不需要深入阐述复杂的理论体系或进行多层次的论证。因此，在简答题题型中属于中等难度。" + }, + { + "idx": 499, + "question": "What are the Burgers vector and dislocation properties of the generated dislocation?", + "answer": "The Burgers vector of the generated dislocation $\\widehat{b}_{3}$ is $a/2~[110]$, which is a pure edge dislocation. The slip plane (001) is not the slip plane of the face-centered cubic structure, so it is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述Burgers矢量和位错性质，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要理解Burgers矢量和位错性质的基本概念，还需要分析位错类型（纯刃型位错）和滑移面特性（非FCC结构的滑移面），涉及多个概念的关联和综合分析。 | 难度: 在简答题题型中，该题目要求考生不仅能够识别和理解Burgers矢量和位错性质的基本概念，还需要进行多步分析和综合判断。具体来说，考生需要：" + }, + { + "idx": 500, + "question": "What effect will this dislocation reaction have on the plastic deformation of the metal?", + "answer": "The dislocation reaction generates a sessile dislocation $\\pmb{a}/2$ [110], which will hinder the movement of dislocations on the (111) and (111) planes, resulting in significant strain hardening macroscopically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应对金属塑性变形的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错反应对金属塑性变形的影响，涉及位错运动的阻碍机制和宏观应变硬化现象的解释。这需要综合运用位错理论、塑性变形机制和材料力学性能的知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对位错反应及其对金属塑性变形的影响进行机理深度解释。需要综合运用位错理论、晶体学知识以及应变硬化机制，进行较为复杂的推理分析。虽然不涉及多系统交互或极端条件等更复杂的现象，但已超出基础概念复述的范畴，属于机理深度解释的难度层级。" + }, + { + "idx": 501, + "question": "What is the reason for age hardening?", + "answer": "Reason for age hardening: Dispersion precipitation of metastable phases, maintaining coherent or semi-coherent interfaces with the matrix phase, hindering dislocation movement in the matrix phase. 1) For deformable second-phase particles, dislocations cut through the second-phase particles, destroying the coherent or semi-coherent relationship between the second-phase particles and increasing the phase boundary area, while the second-phase particles themselves possess high strength. 2) For non-deformable second-phase particles, dislocations bypass the second-phase particles, leaving dislocation loops around them, increasing the dislocation line length and enhancing the resistance of the second-phase particles to subsequent dislocation movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释age hardening的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释时效硬化的原因，涉及亚稳相的弥散析出、与基体相的共格或半共格界面关系、位错运动的阻碍机制等复杂机理。需要综合运用材料科学中的相变理论、位错理论和强化机制等知识，进行深入的推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析年龄硬化的机理，包括可变形和非可变形第二相粒子的不同作用机制。需要深入理解相变、位错运动、界面关系等多个复杂概念，并能综合运用这些知识进行机理解释。题目涉及的知识点深度和解题步骤的复杂程度在该题型内属于最高难度等级。" + }, + { + "idx": 502, + "question": "Configuration of polymer chains", + "answer": "Configuration of polymer chains: The spatial geometric arrangement of atoms in polymers fixed by chemical bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对聚合物链的构型进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对聚合物链构型这一基本概念的定义和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对聚合物链的构型进行基本定义回答，属于最基础的概念记忆层面。题目不涉及概念间的关联性解释或复杂体系阐述，仅需直接复述定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 503, + "question": "How to overcome constitutional supercooling in single crystal growth?", + "answer": "To overcome constitutional supercooling, increase the temperature gradient and reduce the growth rate R.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何克服单晶生长中的组成过冷现象，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释如何克服单晶生长中的组分过冷现象，需要理解组分过冷的原理，并关联温度梯度和生长速率两个因素进行综合分析。这属于中等应用层次，涉及概念关联和综合分析，但不需要复杂的机理推导或创新设计。 | 难度: 在简答题中属于中等难度，需要理解并解释克服组分过冷的方法，涉及温度梯度和生长速率两个关键因素的综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 504, + "question": "What is constitutional supercooling? Explain its cause.", + "answer": "Due to the addition of a second component, the solidification point of the melt decreases at the solid-liquid interface, while the melt away from the interface maintains a higher melting point. Due to the presence of impurities, there is a distribution coefficient ko= Cs/CL at the solid-liquid interface, where the impurity concentration is higher than the average concentration C0. The concentration changes with distance as: CL=C0(1+(1-k0)/k0 e^(-R X/D)), where D is the diffusion coefficient, resulting in TL=Tm-mLC0(1+(1-k0)/k0 e^(-R X/D)). When the cooling rate of the melt is high, the liquid temperature falls below the solidification temperature, causing droplets to be surrounded by crystals and forming scattered particles. This phenomenon is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释\"constitutional supercooling\"的概念及其原因，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释constitutional supercooling的原因，涉及多个概念的关联和综合分析，包括固液界面的凝固点变化、杂质分布系数、浓度随距离的变化关系以及冷却速率的影响。需要深入理解并解释这些概念之间的相互作用和机理，属于复杂分析的层次。 | 难度: 在简答题的复杂分析层次中，该题目要求全面解释\"constitutional supercooling\"这一复杂现象，涉及多个关键概念（如分布系数、扩散系数、温度梯度等）的综合运用。解题需要完整推导浓度分布方程和温度分布方程，并解释其物理意义。这种需要建立数学模型并分析其物理含义的题目，在机理解释类简答题中属于最高难度级别。" + }, + { + "idx": 505, + "question": "Explain the reason why the dislocation $b_{1}=a/2\\\\big[10\\\\Bar{1}\\\\big]$ in the (111) plane of a face-centered cubic lattice metal and the dislocation $b_{2}=a/2[011]$ in the (111) plane can undergo a dislocation reaction.", + "answer": "The dislocation reaction $a/2{\\\\left[10{\\\\stackrel{\\\\leftarrow}{1}}\\\\right]}+a/2{\\\\left[011\\\\right]}\\\\rightarrow a/2{\\\\left[110\\\\right]}$ can occur for the following reasons: $\\\\textcircled{1}$ It satisfies the structural condition $\\\\vec{b}_{1}+\\\\vec{b}_{2}=\\\\vec{b}_{3}$. $\\\\textcircled{2}$ It satisfies the energy condition: $a^{2}/2+a^{2}/2>a^{2}/2_{\\\\circ}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两个位错发生位错反应的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释位错反应的原因，涉及位错矢量的结构条件和能量条件的综合分析，需要理解位错反应的基本原理，并能进行推理分析。这超出了简单记忆或基本应用，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释位错反应的原因，不仅需要理解位错的基本概念和反应条件，还需要综合运用结构条件和能量条件进行推理分析。虽然题目涉及的知识点较为复杂，但解题步骤相对明确，属于需要深入理解但不需要全面分析复杂现象的难度等级。" + }, + { + "idx": 506, + "question": "Magnesium oxide and aluminum oxide (solute) form a substitutional solid solution, write the defect equation.", + "answer": "Defect equation: Al2O3→MgO 2AlMg· + VMg'' + 3OOc", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷方程，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求写出缺陷方程，需要理解固溶体的形成机制和缺陷类型，并能够将铝氧化物在镁氧化物中的固溶过程转化为缺陷方程。这涉及到多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解固溶体的缺陷类型并正确书写缺陷方程，涉及多个概念的综合运用，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 507, + "question": "Dislocation slip", + "answer": "Dislocation slip: Under a certain stress, the movement of dislocations where the dislocation line moves along the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation slip\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对位错滑移的定义和基本原理的掌握。 | 难度: 在简答题题型中，该题目仅要求对\"Dislocation slip\"进行基本定义简答，属于最基础的概念记忆层次。题目不涉及概念间的关联性解释或复杂体系阐述，仅需单点知识回忆即可完成，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 508, + "question": "Can magnesium oxide and aluminum oxide (solute) form a continuous solid solution? Explain the reason.", + "answer": "They cannot form a continuous solid solution due to different crystal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述，答案提供了简短的文字解释，说明为什么不能形成连续固溶体 | 知识层次: 题目需要理解固溶体的形成条件，并分析两种氧化物的晶体结构差异对固溶体形成的影响，涉及概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解镁氧化物和铝氧化物的晶体结构差异，并进行综合分析说明为何不能形成连续固溶体。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 509, + "question": "Active oxygen", + "answer": "Active oxygen: oxygen in silicate structures with partially unsaturated valence.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Active oxygen\"进行定义和解释，答案是一个文字描述而非选择、判断或计算，符合简答题的特征。 | 知识层次: 题目考查对\"活性氧\"这一基础概念的定义和记忆，属于材料科学中基础概念的记忆性知识，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求对\"Active oxygen\"进行基本定义简答，属于最基础的概念记忆层面。题目不需要解释或描述相关概念，更不涉及复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 510, + "question": "Homogeneous nucleation", + "answer": "Homogeneous nucleation: The formation of nuclei in a homogeneous phase relying on conditions such as its own structural fluctuations and energy fluctuations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Homogeneous nucleation\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即均相成核的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"Homogeneous nucleation\"进行基本定义简答，属于最基础的概念记忆层次。题目不涉及概念间的关联解释或复杂体系阐述，仅需准确回忆并表述定义即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 511, + "question": "Equilibrium distribution coefficient", + "answer": "Equilibrium distribution coefficient: The ratio of the solute concentration in the solid phase to that in the liquid phase during equilibrium solidification.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Equilibrium distribution coefficient\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即平衡分配系数的定义，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆性知识，无需进一步解释或复杂阐述，符合等级1的标准。" + }, + { + "idx": 512, + "question": "What are the main influencing factors of constitutional supercooling?", + "answer": "The main influencing factors of constitutional supercooling include: melt cooling rate, impurity concentration C0, partition coefficient k0, diffusion coefficient D, growth rate R, and temperature gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述影响成分过冷的主要因素，答案以文字形式列出多个影响因素，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求列举并解释影响成分过冷的主要因素，涉及多个参数的关联和综合分析，需要理解各因素之间的相互作用及其对成分过冷的影响机制，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明多个影响因素，但不需要进行多角度或深度关联性分析。题目要求列举并简要解释影响成分过冷的主要因素，涉及多个概念但不需要复杂的推导或深入讨论各因素之间的相互作用。" + }, + { + "idx": 513, + "question": "Uphill diffusion", + "answer": "Uphill diffusion: Under the condition of chemical potential difference as the driving force, atoms diffuse from low concentration positions to high concentration positions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Uphill diffusion\"进行文字解释和论述，答案提供了概念的定义和条件说明，符合简答题的特征。 | 知识层次: 题目考查的是\"uphill diffusion\"这一现象的基本定义和驱动力的记忆性知识，属于基础概念层面的理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"uphill diffusion\"这一现象，需要考生不仅记住基本定义，还要理解并描述在特定条件下（化学势差作为驱动力）原子从低浓度向高浓度扩散的反常现象。这比单纯复述定义（等级1）要求更高，但不需要进行复杂概念体系的阐述（等级3）。题目考察的是对基础概念的理解和简单应用能力，属于该题型中的中等难度。" + }, + { + "idx": 514, + "question": "Stored energy", + "answer": "Stored energy: A small portion of the energy consumed during cold deformation exists within the deformed crystal in the form of elastic strain energy and structural defect energy, which is called stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Stored energy\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查存储能量的基本定义和构成，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答存储能量的基本定义，属于基础概念记忆的范畴。题目内容直接明确，不需要复杂的解释或论述，仅需简单描述存储能量的概念即可。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 515, + "question": "In face-centered cubic metals, can the dislocation b3 generated by the dislocation reaction b1 + b2 = b3 move on the slip plane?", + "answer": "The slip plane of face-centered cubic metals is {111}, and b3 is perpendicular to this crystal plane, so it cannot slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么位错b3不能在滑移面上移动，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解面心立方金属的滑移面{111}以及位错反应生成的b3位错的性质，并分析其与滑移面的关系。这涉及到多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型内，该题目要求对位错反应和滑移面性质进行多角度分析论述。需要理解面心立方金属的滑移面{111}特性，分析位错b3的伯氏矢量方向与滑移面的几何关系，并综合论述其不可滑移的原因。这超出了简单概念复述（等级3），但尚未达到需要深度关联多个理论体系的等级5要求。" + }, + { + "idx": 516, + "question": "Pseudo-eutectoid", + "answer": "Pseudo-eutectoid: During non-equilibrium transformation, hypoeutectoid or hypereutectoid alloys near the eutectoid composition point form a completely eutectoid microstructure by the end of the transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Pseudo-eutectoid\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征 | 知识层次: 题目考查对Pseudo-eutectoid这一基本概念的定义和特征的理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Pseudo-eutectoid\"这一概念，并描述其在非平衡转变过程中的表现。虽然需要理解并描述一个特定的冶金学现象，但并不涉及复杂的概念体系或深入的机理分析，属于中等难度的概念解释题。" + }, + { + "idx": 517, + "question": "How do crystal structure and solid solution type affect atomic diffusion in crystalline solids?", + "answer": "In crystal structures with smaller packing density, the activation energy for diffusion is lower, making diffusion easier to occur; in crystal structures with lower symmetry, the anisotropy of the diffusion coefficient is more pronounced; the activation energy for diffusion in interstitial solid solutions is much smaller than that in substitutional solid solutions, facilitating easier diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体结构和固溶体类型对原子扩散的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析晶体结构和固溶体类型对原子扩散的影响，涉及多个概念的关联和综合分析，需要理解扩散机制、晶体结构特征和固溶体类型之间的相互作用，并进行推理分析。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求综合运用晶体结构和固溶体类型的知识，深入分析其对原子扩散的影响机制。需要解释不同晶体结构（如堆积密度、对称性）对扩散激活能和扩散系数各向异性的影响，以及比较间隙固溶体和置换固溶体中扩散的难易程度。这种综合分析要求考生具备扎实的理论基础和较强的推理能力，能够将多个知识点有机结合起来进行深入论述，符合等级5的复杂现象全面分析要求。" + }, + { + "idx": 518, + "question": "Recrystallization", + "answer": "Recrystallization: The process in which deformed materials, upon heating, undergo the replacement of deformed grains by strain-free grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Recrystallization\"这一概念进行文字解释和论述，答案以定义形式呈现，符合简答题的特征。 | 知识层次: 题目考查对再结晶这一基本概念的定义和简单描述，属于基础概念的记忆和理解层面。 | 难度: 在简答题题型中，该题目仅要求对\"Recrystallization\"进行基本定义简答，属于最基础的概念记忆层次。题目不涉及概念解释、描述或复杂体系阐述，仅需准确回忆并表述定义即可，因此在该题型内属于最低难度等级。" + }, + { + "idx": 519, + "question": "How does temperature affect atomic diffusion in crystalline solids?", + "answer": "The higher the temperature, the greater the diffusion coefficient and the faster the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释温度对晶体固体中原子的扩散的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查温度对原子扩散影响的基本原理记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释温度对晶体固体中原子扩散的影响，涉及基础概念记忆层次的知识点。虽然需要一定的理解和解释能力，但不需要复杂的体系阐述或多步骤推理，属于中等难度的简答题。" + }, + { + "idx": 520, + "question": "In face-centered cubic metals, what types of dislocations are b1 = [101], b2 = (a/6)[1̄2̄1], b3 = (a/3)[1̄1̄1̄] respectively?", + "answer": "b1: unit dislocation; b2: Shockley partial dislocation; b3: Frank partial dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求识别不同类型的位错，并给出具体的分类名称，需要文字解释和论述，而不是简单的选择或判断。答案也是以文字形式给出具体的位错类型分类。 | 知识层次: 题目要求识别不同类型的位错，这需要理解位错的基本概念（如单位位错、Shockley部分位错、Frank部分位错）以及它们在面心立方金属中的具体表现形式。虽然涉及基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对不同类型的位错进行识别和分类，需要综合运用晶体结构和位错理论的知识。题目涉及多个位错矢量的分析，包括单位位错、Shockley部分位错和Frank部分位错，需要考生不仅掌握这些位错的定义，还要能够根据给定的矢量形式进行准确判断。此外，题目还要求考生理解面心立方金属中的位错行为，这需要一定的综合分析能力。虽然不涉及复杂的多角度论述，但解题步骤较为复杂，概念关联性强，因此在简答题中属于较高难度。" + }, + { + "idx": 522, + "question": "How do crystal defects affect atomic diffusion in crystalline solids?", + "answer": "The diffusion coefficient along grain boundaries is much greater than that of bulk diffusion; diffusion activation energy is smaller when occurring along dislocation pipes, thus dislocations accelerate diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体缺陷如何影响原子扩散，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释晶体缺陷对原子扩散的影响，涉及扩散系数和扩散激活能的变化，需要综合运用晶体缺陷和扩散机制的知识，进行推理分析和机理解释。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解晶体缺陷和原子扩散的基本概念，还需要深入分析不同类型缺陷（如晶界和位错）对扩散系数和激活能的具体影响机制。这需要综合运用材料科学中的扩散理论和缺陷理论，进行较为深入的推理和解释。虽然题目没有要求全面分析所有可能的复杂现象，但对机理的解释深度要求较高，因此属于等级4难度。" + }, + { + "idx": 524, + "question": "What changes occur in the microstructure of metals after plastic deformation?", + "answer": "After plastic deformation of metals, in terms of microstructure morphology, the originally equiaxed grains are elongated along the deformation direction. Under large deformation, grain boundaries may even appear fibrous. If hard and brittle second-phase particles or inclusions are present, they often distribute in a banded pattern along the deformation direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属在塑性变形后微观结构的变化，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目要求解释塑性变形后金属微观结构的变化，涉及多个概念（如晶粒形态变化、第二相分布等）的关联和综合分析，需要理解变形机制及其对微观结构的影响，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解塑性变形对金属微观结构的影响，并能够描述晶粒形态的变化以及第二相粒子的分布情况。虽然题目涉及多个概念，但不需要进行多角度或深度关联性分析，主要考察对基础知识的掌握和简单应用。" + }, + { + "idx": 525, + "question": "What changes occur in the properties of metal after plastic deformation?", + "answer": "In terms of properties, cold-deformed metal will undergo work hardening, manifested as a significant increase in strength and a noticeable decrease in plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属在塑性变形后性质的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属塑性变形后性能的变化，涉及工作硬化的概念及其对强度和塑性的影响。这需要理解塑性变形的机理，并将变形与性能变化关联起来，属于中等应用层次的知识。 | 难度: 在简答题中属于中等难度，需要理解金属塑性变形后的性能变化，并进行综合分析和说明。题目要求解释冷变形金属的加工硬化现象及其对强度和塑性的影响，涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 526, + "question": "In face-centered cubic metals, can the dislocation reaction b1 + b2 = b3 proceed, where b1 = [101], b2 = (a/6)[1̄2̄1], b3 = (a/3)[1̄1̄1̄]?", + "answer": "Geometric condition: b1 + b2 = (a/2)[101̄] + (a/6)[1̄2̄1] = (a/3)[1̄1̄1̄], b3 = (a/3)[1̄1̄1̄], satisfying the geometric condition; Energy condition: after the reaction |b3|² = (a²/9) × (√(1+1+1))² = a²/3, before the reaction Σ|bi|² = (a²/4) × (√(1+0+1))² + (a²/36) × (√(1+4+1))² = 2a²/3 > after the reaction |b3|²; satisfying the energy condition, the reaction b1 + b2 → b3 can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来判断位错反应是否可以进行，需要分析几何条件和能量条件，并给出详细的解释过程。答案中包含了详细的推导和解释，符合简答题的特征。 | 知识层次: 题目要求分析面心立方金属中的位错反应，需要综合运用几何条件和能量条件进行判断。涉及位错矢量的计算、反应前后的能量比较，以及反应是否可行的综合分析。这需要深入理解位错理论、晶体结构以及能量守恒原理，属于较高层次的认知能力和复杂分析。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求综合运用位错理论、晶体学知识以及能量条件分析，进行多步骤的几何条件和能量条件验证。解题过程需要深入理解面心立方金属中的位错反应机理，并能准确进行矢量运算和能量计算。这种综合性的分析和推理能力要求较高，符合等级5的复杂现象全面分析标准。" + }, + { + "idx": 527, + "question": "2. The symmetry elements of the internal structure of a crystal are (3), (4), and (5) in addition to c, Pλ, Ln, and Lin.", + "answer": "(3) Translation axis; (4) Glide plane; (5) Screw axis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的对称元素名称，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查晶体内部结构对称元素的基本概念记忆，属于定义和分类层面的基础知识点 | 难度: 在简答题中属于中等难度，需要解释和描述多个对称元素的概念，但不需要进行复杂的体系阐述或深入分析。题目要求记忆并简要说明晶体内部结构的对称元素，属于概念解释和描述的范畴。" + }, + { + "idx": 528, + "question": "After plastic deformation of metal, what changes occur in its structure?", + "answer": "Microstructurally, the density of defects (vacancies and dislocations) significantly increases. Due to the multiplication of dislocations during deformation and the intersection and interaction of dislocations during movement, dislocation tangles form, and the annihilation of dislocations with opposite signs results in a cellular structure. As the deformation increases, the number of dislocation cells increases, their size decreases, and the stored energy within the crystal rises.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对金属塑性变形后的结构变化进行详细的文字解释和论述，答案提供了详细的微观结构变化描述，符合简答题的特征。 | 知识层次: 题目要求解释金属塑性变形后微观结构的变化，涉及位错增殖、相互作用、位错缠结和胞状结构的形成等复杂机理，需要综合运用材料科学中的位错理论和变形机制知识，进行推理分析和机理解释。 | 难度: 在简答题中属于机理深度解释的难度等级。题目要求详细描述金属塑性变形后微观结构的变化，包括缺陷密度增加、位错缠结形成、位错湮灭导致的胞状结构形成等复杂机理。虽然不涉及多个复杂现象的综合分析（等级5），但需要对变形过程中的微观结构演变有深入理解，并能系统性地解释这些变化。这要求考生具备扎实的材料科学基础和较强的机理分析能力。" + }, + { + "idx": 529, + "question": "1. Kaolinite belongs to the layered silicate structure, with one layer being (1) and another layer being (2).", + "answer": "(1) silicon-oxygen tetrahedral layer; (2) aluminum-oxygen octahedral layer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个具体的结构名称，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查高岭石层状硅酸盐结构的基本组成，即硅氧四面体层和铝氧八面体层的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回忆并准确填写高岭石层状硅酸盐结构的两个基本组成部分（硅氧四面体层和铝氧八面体层），无需进行概念解释或复杂体系阐述。这完全符合基础概念记忆的知识层次要求，属于该题型内最基础的难度级别。" + }, + { + "idx": 530, + "question": "How does the third component affect atomic diffusion in crystalline solids?", + "answer": "Depending on the nature of the added third component, some promote diffusion while others hinder it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第三组分如何影响晶体固体中的原子扩散，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及原子扩散的机理分析，需要理解第三组分对扩散过程的影响机制，属于对材料科学中扩散现象的深入分析和解释，需要综合运用相关知识进行推理和机理探讨。 | 难度: 在简答题题型中，该题目要求对第三组分在晶体固体中对原子扩散的影响进行机理深度解释。这需要综合运用材料科学中的扩散理论、晶体缺陷知识以及合金化效应等概念，进行推理分析和机理解释。虽然题目没有要求全面分析所有可能的复杂现象，但对机理的解释深度要求较高，属于该题型中的较高难度等级。" + }, + { + "idx": 531, + "question": "5. When Ca0 is doped into ZrO2, where Ca2+ ions replace Zr4+ ions, due to the requirement of electrical neutrality, this substitution simultaneously creates a (9) defect, which can be represented by the (10) defect reaction equation.", + "answer": "(9) vacancy; (10) CaO→ZrO2CaZr′′+V0..+ O0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求填写空缺部分并写出缺陷反应方程，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解掺杂过程中的电荷平衡原理，并能够正确写出缺陷反应方程，涉及多步概念关联和综合分析。虽然不涉及复杂计算，但需要对缺陷化学有较深的理解和应用能力。 | 难度: 在简答题题型中，该题目要求考生不仅理解掺杂过程中的电荷平衡原理，还需要准确写出缺陷反应方程。这涉及到多步概念关联和综合分析，包括离子取代、电荷补偿机制以及缺陷化学符号的正确使用。虽然不需要进行深度关联性分析（如讨论材料性能影响），但已超出基础概念复述的范畴，属于需要多角度分析论述的中高难度题目。" + }, + { + "idx": 532, + "question": "Explain why the strength of polycrystalline materials increases with decreasing grain size.", + "answer": "During plastic deformation of polycrystalline materials, coarse grains have a higher number of dislocations piled up at grain boundaries, creating a larger stress field that can activate dislocation sources in adjacent grains, allowing deformation to continue. In contrast, fine grains have fewer dislocations piled up at grain boundaries, requiring a greater external force to activate dislocation sources in adjacent grains for deformation to proceed. Therefore, finer-grained materials need a larger external force to undergo plastic deformation, meaning the strength of the crystal increases with decreasing grain size. (5 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述多晶材料强度随晶粒尺寸减小而增加的原因，答案提供了详细的机理说明和结论，符合简答题的特征。 | 知识层次: 题目要求解释多晶材料强度随晶粒尺寸减小的机理，涉及位错堆积、应力场和塑性变形的综合分析，需要深入理解材料变形机制并进行推理分析。 | 难度: 在简答题（需要文字解释和论述）题型中，该题目属于机理深度解释难度。题目要求考生不仅理解晶粒尺寸与材料强度的关系，还需要深入解释位错堆积和应力场的形成机制，以及这些机制如何影响相邻晶粒的位错源激活。这需要综合运用材料科学中的位错理论和塑性变形知识，进行较为深入的推理分析。虽然题目没有要求多因素交互作用的全面分析（这是等级5的特征），但对单一机理的解释深度已达到较高要求。" + }, + { + "idx": 533, + "question": "4. The term 'segment' is used to describe the (8) property of polymers.", + "answer": "(8) flexibility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个描述聚合物性质的术语（flexibility），这属于需要提供特定单词或短语的简答题形式，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对聚合物基本性质术语的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回忆并填写\"segment\"在聚合物中的特定属性（flexibility），不需要进行概念解释或复杂阐述。这完全符合等级1对基础概念记忆的要求，是同类题型中最简单的表现形式。" + }, + { + "idx": 534, + "question": "8. Methods to strengthen metal materials include (16) strengthening, (17) strengthening, (18) strengthening, (19) strengthening.", + "answer": "(16) solid solution; (17) dislocation; (18) fine grain; (19) dispersion (or precipitate particles)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的强化方法名称，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目主要考查对金属材料强化方法的基本概念记忆，包括固溶强化、位错强化、细晶强化和弥散强化等基础知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写金属材料强化的四种基本方法，这属于基础概念记忆性知识，不需要进行复杂的解释或论述。学生只需回忆并写出相关术语即可完成作答，解题步骤简单，对知识点掌握深度的要求较低。" + }, + { + "idx": 535, + "question": "Syndiotactic", + "answer": "Syndiotactic: A polymer in which the substituents are alternately attached to opposite sides of the main chain plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Syndiotactic\"进行文字解释和论述，答案是一个详细的定义描述，符合简答题的特征。 | 知识层次: 题目考查对\"Syndiotactic\"这一聚合物结构的基本定义和概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"Syndiotactic\"这一术语进行基本定义解释，属于最基础的概念记忆层次。题目不涉及概念间的比较分析或复杂体系阐述，仅需简单回忆和表述定义内容，因此在该题型内属于最低难度等级。" + }, + { + "idx": 536, + "question": "What is the reason for age strengthening?", + "answer": "The reasons for age strengthening are as follows: First, when disc-shaped metastable phases precipitate and have a certain orientation relationship with the parent phase, large elastic strains are generated within the matrix, which can significantly strengthen the alloy. Second, when the alloy undergoes deformation, the interaction between dispersed particles and dislocations strengthens the alloy. If the precipitate particles are deformable, as dislocations cut through them, work is required to increase the surface area of the particles, thereby increasing the resistance to dislocation motion and strengthening the alloy. If the precipitate particles are strong and incoherent with the matrix, dislocation lines find it difficult to cut through the particles and will bypass them under applied stress, leaving dislocation loops. For the alloy to continue deforming, the stress exerted by the particles as dislocation lines bypass them must be overcome, requiring further increase in the applied stress, thus resulting in age strengthening of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释年龄强化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释时效强化的原因，涉及多个机理的综合分析，包括亚稳相析出、位错与析出相的相互作用、位错切割和绕过机制等。需要深入理解材料强化机制，并能将这些概念关联起来进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析年龄强化的多重机理，包括亚稳相析出与母相的取向关系、弹性应变强化、位错与析出粒子的交互作用（可变形粒子切割机制和不可变形粒子绕过机制）等复杂现象。解题需要综合运用材料科学原理进行多层次的机理解释和推理分析，属于该题型框架内最高难度的全面分析类题目。" + }, + { + "idx": 537, + "question": "Non-uniform nucleation", + "answer": "Non-uniform nucleation: The nucleation process during the cooling of a molten liquid that occurs on a certain interface within the parent phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Non-uniform nucleation\"进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征。 | 知识层次: 题目考查非均匀形核的基本定义和过程描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答，仅要求对\"Non-uniform nucleation\"这一概念进行简单的定义和描述，不需要深入的解释或复杂的论述。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 538, + "question": "7. Small-angle grain boundaries are composed of dislocations, among which symmetric tilt boundaries are composed of (14) dislocations, and twist boundaries are composed of (15) dislocations.", + "answer": "(14) edge; (15) screw", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定类型的位错名称（刃型位错和螺型位错），属于需要准确回答特定术语的简答题形式。虽然形式上类似填空题，但根据提供的题型选项，最接近的是简答题类型。 | 知识层次: 题目考查对小角度晶界和位错类型的基本概念记忆，属于定义和分类的记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求考生记忆并准确填写两种位错类型的名称（刃型位错和螺型位错），不需要进行概念解释或复杂体系阐述。这符合等级1对基础概念记忆性知识的要求，解题步骤简单直接，属于该题型内最基础的难度水平。" + }, + { + "idx": 539, + "question": "Polymorph", + "answer": "Polymorph: Crystals of the same chemical composition that form different structures under varying thermodynamic conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Polymorph\"这一术语进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查对多晶型（Polymorph）这一基本概念的定义和记忆，属于材料科学中晶体结构的基础知识，不涉及复杂分析或应用。 | 难度: 在简答题-基础概念记忆题型中，该题目要求解释\"Polymorph\"的定义并简要说明其形成条件。这属于概念解释和描述的难度等级，需要学生准确记忆专业术语的定义并理解其基本形成原理，但不需要进行复杂的体系阐述或深入分析。相比等级1的简单定义复述，此题要求稍高的理解深度；相比等级3的复杂概念体系，此题的知识点较为单一明确。" + }, + { + "idx": 540, + "question": "9.Linear polymers can be reused, also known as (20); cross-linked polymers cannot be reused and are called thermosetting plastics.", + "answer": "(20) Thermoplastic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语（Thermoplastic）来完成句子，属于简答题类型，需要根据上下文理解并给出正确的术语。 | 知识层次: 题目考查对聚合物分类的基本概念记忆，特别是线性聚合物和交联聚合物的区别及其术语的记忆。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写一个术语（Thermoplastic）并解释其与线性聚合物的关系，这仅涉及基础概念的记忆和简单应用，不需要深入的解释或复杂的论述步骤。" + }, + { + "idx": 541, + "question": "Deformation texture", + "answer": "Deformation texture: As the amount of plastic deformation increases, the phenomenon where a certain crystallographic orientation of the deformed polycrystal tends to become consistent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Deformation texture\"进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查对\"Deformation texture\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对\"变形织构\"进行文字解释和论述，需要理解并描述塑性变形过程中晶体学取向趋于一致的现象。这比单纯背诵基本定义（等级1）要求更高，但不需要阐述复杂的概念体系或进行多层次的逻辑推理（等级3）。题目主要考察对基础概念的理解和表达能力，属于该题型中的中等难度。" + }, + { + "idx": 542, + "question": "Peritectic transformation", + "answer": "Peritectic transformation: At a certain temperature, a liquid phase with a specific composition interacts with a solid phase of a specific composition to form a new solid phase with another specific composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Peritectic transformation\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对包晶转变（Peritectic transformation）这一基本概念的记忆和理解，属于材料科学相变中的基础概念，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释Peritectic transformation的定义和过程，属于概念解释和描述的难度等级。虽然需要记忆和描述特定温度下的相变过程，但并不涉及复杂的体系阐述或多步骤推理，因此属于中等难度。" + }, + { + "idx": 543, + "question": "Pearlite", + "answer": "Pearlite: The product of eutectoid transformation in iron-carbon alloys, it is a lamellar mixture of eutectoid ferrite and eutectoid cementite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Pearlite\"进行文字解释和论述，答案提供了详细的定义和组成描述，符合简答题的特征。 | 知识层次: 题目考查对珠光体（Pearlite）这一基本概念的定义和组成成分的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答pearlite的基本定义和组成，属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单直接的记忆性知识考查。" + }, + { + "idx": 544, + "question": "3. In a ternary phase diagram, the eutectic point is (6) phase equilibrium, and the degree of freedom is (7).", + "answer": "(6) four; (7) 0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的答案（如“four”和“0”），而不是从多个选项中选择或判断对错，也不需要复杂的计算或公式应用。 | 知识层次: 题目考查对三元相图中共晶点相平衡和自由度概念的记忆和理解，属于基础概念记忆范畴 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求填写两个关键术语（four和0），无需展开解释或论述。考察的是对三元相图中共晶点基本概念的记忆，属于最基础的概念性知识再现，解题步骤极其简单，符合等级1\"基本定义简答\"的特征。在同题型框架内，相比需要概念解释(等级2)或体系阐述(等级3)的简答题，此题的认知负荷和作答要求都是最低的。" + }, + { + "idx": 545, + "question": "Li Sheng", + "answer": "Li Sheng: The uniform shear process in which one part of a crystal moves relative to another along specific crystallographic planes and directions under the action of shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Li Sheng\"进行解释和论述，答案提供了详细的文字解释，符合简答题的特征 | 知识层次: 题目考查对Li Sheng（李生）这一基本概念的定义和记忆，属于材料科学中晶体变形的基础知识，不涉及复杂应用或分析。 | 难度: 在简答题题型中，这属于最基本的定义简答题目。题目要求直接复述\"Li Sheng\"的定义，不需要额外的解释、分析或复杂概念的阐述。完全符合基础概念记忆的知识层次要求，属于该题型内最简单的难度等级。" + }, + { + "idx": 546, + "question": "2. In face-centered cubic packing, the number of atoms in the unit cell is (5), it has (6) _ tetrahedral voids, (7) _ octahedral voids.", + "answer": "(5) 4; (6) 8; (7) 4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程，属于简答题类型。 | 知识层次: 题目考查面心立方堆积中原子数、四面体空隙和八面体空隙数量的记忆性知识，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆面心立方堆积中原子数、四面体空隙和八面体空隙的数量，不需要进行概念解释或复杂体系的阐述。这些知识点是材料科学中最基础的概念记忆内容，解题步骤简单直接，仅需回忆相关定义即可作答。" + }, + { + "idx": 547, + "question": "Spinodal decomposition", + "answer": "Spinodal decomposition: A transformation in which a solid solution decomposes into two solid solutions with the same structure as the parent phase but different compositions through uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Spinodal decomposition进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查Spinodal decomposition的基本定义和原理，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目要求对Spinodal decomposition进行概念解释和描述，包括其定义、过程和特点。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或深入的分析。因此，在简答题的基础概念记忆层次中属于中等难度。" + }, + { + "idx": 549, + "question": "Aging", + "answer": "Aging: The subsequent process of solute atom precipitation from a supersaturated solid solution at room temperature or above.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Aging\"这一概念进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征 | 知识层次: 题目考查对\"Aging\"这一基础概念的定义记忆和理解，属于材料科学中的基本术语和原理，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求对\"Aging\"这一基础概念进行定义性的回答，属于最基本的概念记忆层面。题目不涉及概念间的联系、分类比较或复杂原理阐述，完全符合等级1\"基本定义简答\"的标准。在同类定义型简答题中，这是最基础、最直接的考查形式。" + }, + { + "idx": 550, + "question": "1. Crystals can be classified into (1) crystal families, (2) crystal systems according to symmetry, with a total of (3) point groups and (4) space groups.", + "answer": "(1) 3; (2) 7; (3) 32; (4) 230", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。虽然答案简短，但属于需要记忆和准确回答的简答题类型。 | 知识层次: 题目考查晶体分类、对称性、点群和空间群等基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆晶体分类的基本数字（3个晶族、7个晶系、32个点群、230个空间群），无需解释或阐述概念间的逻辑关系。题目仅考察对基础分类数据的记忆能力，不涉及概念描述或体系构建。" + }, + { + "idx": 551, + "question": "6. The driving force for nucleation in solid-state phase transformation is (11), and the main resistances are (12) and (13).", + "answer": "(11) The difference in free energy between the new phase and the parent phase; (12) Interface energy; (13) Strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的术语或概念，而不是从多个选项中选择或判断对错。答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查固态相变中成核驱动力和主要阻力的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答固态相变中成核的驱动力和主要阻力，涉及基础概念的记忆和简单解释，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 553, + "question": "3. The three crystal zones of an ingot refer to (8), (9), and (10).", + "answer": "(8) surface fine grain zone; (9) columnar crystal zone; (10) central equiaxed coarse grain zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的术语名称，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对铸锭三个晶区的基本概念的记忆和理解，属于定义和分类的记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答铸锭的三个晶区名称，属于基础概念记忆性知识，不需要进行复杂的解释或论述。只需准确回忆并写出三个晶区的名称即可，解题步骤简单，对知识点的掌握深度要求较低。" + }, + { + "idx": 554, + "question": "5.After recrystallization is completed, grain growth can be divided into (14) grain growth and (15) grain growth.", + "answer": "(14) normal; (15) abnormal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空格的正确答案，需要学生对晶粒生长的类型有基本的理解并用文字回答，属于简答题类型。 | 知识层次: 题目考查对晶粒生长分类的基本概念记忆，属于材料科学中基础知识的直接回忆，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求填写两个特定类型的晶粒生长名称（正常晶粒生长和异常晶粒生长），不需要进行概念解释或复杂阐述。这属于最基础的概念记忆性知识，符合等级1的标准。" + }, + { + "idx": 555, + "question": "7.During martensitic transformation, the new phase often begins to form on a specific crystallographic plane of the parent phase, which is called (20).", + "answer": "(20) habit plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（habit plane）作为答案，属于需要简短文字回答的题目类型，而不是从多个选项中选择或进行判断或计算。 | 知识层次: 题目考查马氏体相变中基本概念\"惯习面\"的记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题中属于基本定义简答，仅需记忆并准确写出\"habit plane\"这一术语即可，无需解释或论述其形成机制或影响因素，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 556, + "question": "Given: When the grain size of annealed pure iron is 16 per $\\mathbf{\\chi}_{\\mathbf{m}\\mathbf{m}^{2}}$, the yield strength $\\sigma_{\\mathsf{s}}=100\\mathrm{N/\\Omega}$ $\\mathbf{m}\\mathbf{m}^{2}$; when the grain size is 4096 per $\\prime_{\\mathbf{m}\\mathbf{m}^{2}}$, $\\sigma_{\\mathrm{s}}=250\\mathrm{N}/\\mathrm{mm}^{2}$. Find the value of yield strength $\\pmb{\\sigma_{\\S}}$ when the grain size is 256 per $\\mathbf{m}\\mathbf{m}^{2}$.", + "answer": "According to the Hall-Petch formula: $\\sigma_{\\mathrm{s}}=\\sigma_{0}+K_{\\mathrm{y}}d^{-1/2}$, the yield strength $\\sigma_{\\mathbf{s}}$ of the material is calculated from the average grain size $^d$. Expressing the grain size in terms of the radius of an equal-area circle: $$d_{1}=(4A_{1}/\\pi)^{1/2}d_{2}=(4A_{2}/\\pi)^{1/2}$$$A_{1}$ and $A_{2}$ are the grain areas. Thus, $$\\sigma_{\\mathrm{s1}}=\\sigma_{0}+K_{\\mathrm{y}}d_{1}^{-1/2}\\sigma_{\\mathrm{s2}}=\\sigma_{0}+K_{\\mathrm{y}}d_{2}^{-1/2}$$Given that $A_{1}=1/16\\mathrm{mm}^{2}$, $A_{2}=1/4096\\mathrm{mm}^{2}$, $\\sigma_{\\mathrm{s}1}=100\\mathrm{N/mm}^{2}$, $\\sigma_{\\mathrm{s}2}=250\\mathrm{N}/\\mathrm{mm}^{2}$, substituting into the above equations yields $K_{\\mathrm{y}}=25{\\sqrt{2}}\\pi^{-1/4}\\mathrm{N}/\\mathrm{mm}^{3/2}$, $\\pmb{\\sigma_{0}}=50\\mathbf{N}/\\mathbf{m}\\mathbf{m}^{2}$. Then, with $A_{3}=1/256\\mathrm{mm}^{2}$, we find $\\sigma_{\\mathbf{s}3}=150\\mathbf{N}/\\mathbf{m}\\mathbf{m}^{2}$. (10 points)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（Hall-Petch公式）进行数值计算，以求解特定晶粒尺寸下的屈服强度。解答过程涉及代入数值、解方程和最终的计算结果，这些都是计算题的典型特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值代入和求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，涉及概念关联和综合分析。题目提供了两个已知条件，需要通过联立方程求解常数项，再应用于第三个情况。虽然计算步骤较多，但变量关系明确，属于该题型内中等偏上的难度水平。" + }, + { + "idx": 558, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of temperature.", + "answer": "Temperature. The higher the temperature, the greater the diffusion coefficient and the faster the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响原子扩散的因素并简要说明温度的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查原子扩散影响因素的基本概念记忆，特别是温度对扩散系数影响的基本原理理解，属于基础概念记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答影响原子扩散的因素并简要解释温度的影响，这需要理解基本概念（如扩散系数）并能够进行简单描述，但不需要复杂的体系阐述或多因素综合分析。" + }, + { + "idx": 559, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of the third component.", + "answer": "The third component. Depending on the nature of the added third component, some promote diffusion while others hinder it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响原子扩散的因素，并简要说明第三组分的影响，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目不仅要求列举影响原子扩散的因素（基础概念），还需要解释第三组元的具体影响（概念关联和综合分析），涉及多因素相互作用的理解和分析。 | 难度: 在简答题中属于中等难度，需要理解原子扩散的基本概念并分析第三组分的影响，但不需要深入的多角度或关联性分析。" + }, + { + "idx": 560, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of crystal defects.", + "answer": "Crystal defects. The diffusion coefficient along grain boundaries is much larger than that of bulk diffusion; the activation energy for diffusion along dislocation pipes is smaller, thus dislocations accelerate diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响原子扩散的因素并简要说明晶体缺陷的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求列举影响原子扩散的因素（基础概念），还需要解释晶体缺陷对扩散的具体影响（概念关联和综合分析）。这涉及到将晶体缺陷类型与扩散机制联系起来，并理解不同缺陷对扩散系数和活化能的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅列举影响原子扩散的因素，还需要解释晶体缺陷的具体影响。这涉及到多个概念的关联和综合分析，如晶界扩散系数与体扩散系数的比较、位错管道扩散的活化能等。虽然不需要进行深度关联性分析（如涉及多个学科交叉），但已经超出了基础概念复述的范畴，属于多角度分析论述的难度等级。" + }, + { + "idx": 561, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of crystal structure and solid solution type.", + "answer": "Crystal structure and solid solution type. In crystal structures with smaller packing density, the diffusion activation energy is lower, making diffusion easier to occur; in crystal structures with lower symmetry, the anisotropy of the diffusion coefficient is significant; the diffusion activation energy in interstitial solid solutions is much smaller than that in substitutional solid solutions, facilitating easier diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释影响原子扩散的因素，特别是晶体结构和固溶体类型的影响。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求列举影响原子扩散的因素（基础概念），还需要解释晶体结构和固溶体类型对扩散的具体影响（概念关联和综合分析）。这涉及到多个知识点的关联和一定程度的机理解释，超出了简单记忆或直接套用的范畴。 | 难度: 在简答题题型中，该题目要求对影响原子扩散的多个因素进行分析和论述，包括晶体结构和固溶体类型的具体影响。需要综合运用材料科学中的扩散理论、晶体结构知识以及固溶体特性，进行多角度的分析和解释。虽然不需要进行深度关联性分析，但要求对多个概念进行关联和综合说明，属于较高难度的简答题。" + }, + { + "idx": 562, + "question": "Analyze the changes in vacancies and dislocations in deformed metals during the recrystallization stage and their effects on properties.", + "answer": "Recrystallization stage: With the rearrangement of atoms during recrystallization, the dislocation density significantly decreases, the complex dislocation interactions generated during deformation disappear, the work hardening phenomenon vanishes, and the various properties of the deformed metal return to their pre-deformation state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析变形金属在再结晶阶段空位和位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析变形金属在再结晶阶段空位和位错的变化及其对性能的影响，涉及多个概念的关联和综合分析，需要理解再结晶过程中原子重排、位错密度变化、加工硬化消失等机理，并进行推理分析。这超出了简单记忆或基本应用，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对金属再结晶阶段的空位和位错变化及其对性能的影响进行全面分析。需要综合运用材料科学中的变形、再结晶、位错理论等知识，进行机理解释和现象分析。解题步骤涉及多个知识点的串联和深度推理，属于该题型内的高难度题目。" + }, + { + "idx": 563, + "question": "Briefly explain the disadvantages brought by the work hardening phenomenon", + "answer": "Disadvantages brought by the work hardening phenomenon: causes difficulty in plastic deformation. (3 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释加工硬化现象带来的缺点，需要文字解释和论述，答案也是以文字形式呈现的简答内容。 | 知识层次: 题目考查对加工硬化现象带来的不利影响的基本理解，属于基础概念的记忆和简单解释，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求简要说明加工硬化现象的缺点，属于基本定义简答级别。答案只需直接回忆并陈述一个关键点（导致塑性变形困难），无需深入解释或构建复杂概念体系，符合等级1对知识点掌握深度和解题步骤简单性的要求。" + }, + { + "idx": 564, + "question": "Analyze the changes of vacancies and dislocations in deformed metals during the recovery stage and their effects on properties.", + "answer": "Recovery stage: The vacancy concentration decreases to approach the equilibrium concentration, leading to a reduction in resistivity and an increase in crystal density. The mutual annihilation of dislocations with opposite signs on the same slip plane causes a slight decrease in dislocation density. During high-temperature recovery, edge dislocations undergo polygonization through slip and climb movements, resulting in the retention of work hardening. The strength and hardness slightly decrease, while residual stresses are essentially eliminated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析变形金属在回复阶段空位和位错的变化及其对性能的影响，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求分析变形金属在回复阶段空位和位错的变化及其对性能的影响，涉及多个概念的关联和机理解释，需要综合运用材料科学知识进行推理分析，思维过程深度要求较高。 | 难度: 在简答题（复杂分析类）中属于最高难度等级，因为该题目要求：" + }, + { + "idx": 565, + "question": "How to eliminate work hardening phenomenon", + "answer": "Subsequent recrystallization treatment is adopted to eliminate work hardening phenomenon. (3 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何消除加工硬化现象，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对消除加工硬化现象的基本方法的理解和简单应用，涉及热处理工艺的选择，属于直接套用已有知识解决常见问题的范畴，不需要复杂的分析或综合。 | 难度: 在简答题题型中，该题目属于应用方法说明难度等级。题目要求解释如何消除加工硬化现象，答案提供了具体的再结晶处理方法，但未涉及详细的操作步骤或实例说明。相比等级2的简单过程描述，该题目需要更深入的方法说明；但相比等级4的应用实例详细解释，又缺少具体的操作细节和实例支撑。因此在该题型内属于中等难度。" + }, + { + "idx": 566, + "question": "Briefly explain the benefits brought by the work hardening phenomenon", + "answer": "The benefits brought by the work hardening phenomenon: During the deformation process, the dislocation density increases, and interactions between dislocations occur (such as dislocation intersection, dislocation entanglement, etc.), leading to dislocation pile-up, thereby strengthening the metal material. It also makes the deformation of the metal material more uniform. (4 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释加工硬化现象带来的好处，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对加工硬化现象的基本概念和原理的理解，主要涉及位错密度增加、位错相互作用等基础知识的记忆和简单解释，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要解释加工硬化现象带来的好处，涉及对基本原理的记忆和简单阐述（如位错密度增加、位错相互作用等），但不需要构建复杂的知识体系或进行深入分析。这符合等级2对概念解释和描述的要求。" + }, + { + "idx": 567, + "question": "Given the diffusion constant of carbon in γ-Fe D0=2.0×10^-5m^2/s and the activation energy for diffusion Q=140×10^3J/mol, calculate the diffusion coefficient of carbon in γ-Fe at 927℃.", + "answer": "The diffusion coefficient of carbon in γ-Fe at 927℃: 15.99×10^-12m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散常数和活化能计算碳在γ-Fe中的扩散系数，需要使用Arrhenius方程进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及基本的数值代入和单位转换，不需要多步计算或复杂的概念关联。 | 难度: 在计算题中属于单一公式直接计算，只需要应用阿伦尼乌斯公式进行简单计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 568, + "question": "Given the diffusion constant of carbon in γ-Fe D0=2.0×10^-5m^2/s and the diffusion activation energy Q=140×10^3J/mol, calculate the diffusion coefficient of carbon in γ-Fe at 870℃.", + "answer": "The diffusion coefficient of carbon in γ-Fe at 870℃: 7.94×10^-12m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散常数和激活能计算碳在γ-Fe中的扩散系数，需要使用公式进行数值计算，答案也是一个具体的数值结果。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及基本公式套用和单位转换，不需要多步计算或复杂分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需套用阿伦尼乌斯公式（D = D0 * exp(-Q/RT)）进行简单数值计算，无需多步骤或复杂推导。" + }, + { + "idx": 569, + "question": "In a face-centered cubic crystal, a dislocation with Burgers vector b1= [101] meets a dislocation with b2= [121]. Can a dislocation reaction occur to form b3? Write the equation.", + "answer": "Geometric condition: b3=b1+b2= a/2[101]+a/6[121]=a/6[222]=a/3[111]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释并写出位错反应的方程式，答案需要文字解释和论述，而非简单的选择、判断或数值计算。 | 知识层次: 题目要求对位错反应进行几何条件分析，涉及多个位错矢量的叠加计算和简化，需要理解位错反应的基本原理并能够进行多步计算和综合分析。 | 难度: 在简答题中属于中等难度，需要理解位错反应的基本概念，进行矢量计算，并给出合理的解释。虽然涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 570, + "question": "Given the diffusion constant of carbon in γ-Fe D0=2.0×10^-5m^2/s and the activation energy for diffusion Q=140×10^3J/mol, how long is required to achieve the same carburizing thickness at 870°C as that obtained by carburizing for 10 hours at 927°C? (Ignore the difference in solubility of carbon in γ-Fe at different temperatures)", + "answer": "20.12 hours are required.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散常数、活化能、温度和时间的关系，最终需要计算出具体的时间数值。答案也是一个具体的数值结果（20.12 hours），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用阿伦尼乌斯公式计算不同温度下的扩散系数，然后根据扩散厚度与时间的关系进行求解。这需要理解扩散机制的基本原理，并能将不同概念（温度对扩散系数的影响、扩散厚度与时间的关系）关联起来进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散公式（Arrhenius方程）进行多步计算，涉及温度转换、时间计算和概念关联。虽然题目提供了必要的参数，但需要学生理解并正确应用公式，进行综合分析才能得出答案。" + }, + { + "idx": 571, + "question": "When $\\\\mathrm{Yb}\\\\mathrm{F}_{3}$ and $\\\\mathbf{NaF}$ are doped into $\\\\mathbf{CaF}_{2}$ crystals, if both ytterbium ions and sodium ions replace the cation positions, please write the defect reaction equation.", + "answer": "$\\\\mathrm{YbF}_{3}+\\\\mathrm{NaF}\\\\xrightarrow{\\\\mathrm{CaF}_{2}}\\\\mathrm{Yb}_{\\\\mathrm{Ca}}^{*}+\\\\mathrm{Na}_{\\\\mathrm{Ca}}^{\\\\prime}+4\\\\mathrm{F}_{\\\\mathrm{Fc}}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字解释和论述，答案形式为化学方程式，属于简答题类型 | 知识层次: 题目要求写出缺陷反应方程，需要理解掺杂过程中离子的取代位置和电荷平衡，涉及多步思考和概念关联，但不需要复杂的推理或深度机理分析。 | 难度: 在简答题中属于中等难度，需要理解缺陷化学的基本概念，并能够正确应用缺陷反应方程式的书写规则。题目涉及多步替换和电荷平衡的考虑，但不需要深入的多角度分析或复杂的关联性推理。" + }, + { + "idx": 572, + "question": "In a face-centered cubic crystal, indicate which types of dislocations b1, b2, and b3 belong to respectively", + "answer": "b1 is a perfect dislocation, b2 is a Shockley partial dislocation, and b3 is a Frank partial dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型的位错进行分类和解释，答案需要文字描述和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别不同类型的位错（完美位错、Shockley部分位错、Frank部分位错），这需要理解位错的基本概念及其在面心立方晶体中的具体表现。虽然涉及基础概念，但需要将概念与具体晶体结构关联起来进行分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对三种不同类型的位错进行识别和分类，需要综合运用晶体结构、位错理论等知识进行多角度分析。虽然不涉及复杂的计算，但需要对概念有深入理解并能准确关联到具体实例，属于中等应用层次中较高难度的题目。" + }, + { + "idx": 573, + "question": "How do dislocations strengthen metallic materials?", + "answer": "Dislocations can strengthen metallic materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错如何强化金属材料，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释位错如何强化金属材料，这涉及到位错与材料强度之间的相互作用机制，需要综合运用位错理论、塑性变形等知识进行推理分析，属于对材料科学中复杂现象的解释和理解。 | 难度: 在简答题题型中，该题目要求对位错强化金属材料的机理进行深度解释，涉及位错运动、相互作用以及强化机制的综合分析。虽然不需要全面分析复杂现象（如等级5的要求），但仍需要较高的知识掌握深度和推理能力，属于机理深度解释的难度等级。" + }, + { + "idx": 574, + "question": "Give two applications of solidification theory in the crystallization of metallic materials, and briefly explain them", + "answer": "Single crystal preparation. Using directional solidification technology to control the heat flow direction, enabling the metal to grow along a single crystal orientation, resulting in single crystals without grain boundaries, which are used in critical components such as high-temperature alloy blades.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出两个应用并简要解释，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求给出两个应用实例并简要解释，涉及对凝固理论的理解和实际应用，需要将理论知识与实际工艺（如定向凝固技术）相结合，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求给出两个应用并简要解释，但每个应用的解释需要一定的专业知识和理解，如单晶制备中的定向凝固技术及其原理。这需要学生能够将理论知识应用到具体实例中，并进行适当的解释。然而，题目并未要求深入分析或比较不同应用之间的关联性，因此难度属于等级3的综合分析和说明。" + }, + { + "idx": 575, + "question": "Give one application of solidification theory in the crystallization of metallic materials, and briefly explain it", + "answer": "Ingot structure control. By controlling the cooling rate and temperature gradient during solidification, the grain size and distribution of the ingot can be adjusted, thereby improving the mechanical properties of the metallic material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个应用实例并进行简要解释，需要文字论述而非选择、判断或计算 | 知识层次: 题目要求给出一个凝固理论在金属材料结晶中的应用实例，并简要解释其原理。这属于将基础理论（凝固理论）直接应用于具体场景（金属材料结晶），涉及基本概念的应用但不需要复杂的分析或多步骤推理。 | 难度: 在简答题中属于中等难度，需要学生理解并应用凝固理论的基本概念，解释其在金属材料结晶中的一个具体应用。题目要求简要说明控制冷却速率和温度梯度对铸锭结构的影响，这涉及到对理论知识的简单应用和解释，但不需要深入分析或复杂的推导过程。" + }, + { + "idx": 576, + "question": "Give three applications of solidification theory in the crystallization of metallic materials, and provide a brief explanation for each", + "answer": "Amorphous material preparation. By extremely rapid cooling (on the order of 10^6 K/s), the metal melt skips the crystallization stage and directly forms an amorphous structure, obtaining high-strength, corrosion-resistant amorphous alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举三个应用并简要解释每个应用，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举并简要解释凝固理论在金属材料结晶中的三个应用实例，这需要理解凝固理论的基本原理，并将其与金属材料的结晶过程联系起来进行分析。虽然不涉及复杂的计算或深度推理，但需要对概念进行关联和综合应用，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并应用凝固理论的基本概念，列举三个应用实例并进行简要解释。虽然不需要深入的多角度分析或深度关联性分析，但仍需对知识点有较好的掌握和综合运用能力。" + }, + { + "idx": 577, + "question": "In a face-centered cubic crystal, a dislocation with Burgers vector b1= [101] meets a dislocation with b2= [121]. Explain the reason whether the dislocation reaction can occur.", + "answer": "Energy condition: b1^2+b2^2= (a^2/4)(1+0+1)+(a^2/36)(1+4+1)=a^2/2+a^2/6=2a^2/3, b3^2= (a^2/9)(1+1+1)=a^2/3, b3^2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构的密排方向，答案是一个特定的晶体学方向<110>，这属于需要特定知识回答的简答题，不需要计算或选择选项 | 知识层次: 题目考查对FCC结构密排方向的基本概念记忆，只需记住<110>是FCC结构的密排方向即可回答，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答FCC结构的密排方向，属于最基础的定义性知识。不需要解释或论述，只需准确记忆晶体学方向指数即可。在同题型内，这比需要概念解释(等级2)或体系阐述(等级3)的题目简单得多，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 592, + "question": "Explain the term: grain boundary segregation", + "answer": "Grain boundary segregation: The enrichment phenomenon of solute atoms or impurity atoms at grain boundaries due to the difference in distortion energy between the grain interior and the grain boundaries or the presence of vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"grain boundary segregation\"，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"grain boundary segregation\"这一基本概念的定义和简单解释，属于基础概念记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"grain boundary segregation\"这一术语，需要考生理解并描述晶界偏析现象的基本原理和原因，包括溶质原子或杂质原子在晶界处的富集现象及其形成机制（晶内与晶界畸变能差异或空位存在）。这比单纯背诵定义（等级1）要求更高，但不需要进行复杂概念体系的阐述（等级3）。" + }, + { + "idx": 593, + "question": "The packing density of FCC structure is", + "answer": "0.74", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算FCC结构的堆积密度，需要应用相关公式进行数值计算，最终答案为具体数值0.74 | 知识层次: 题目考查FCC结构堆积密度的基本计算，仅需直接套用已知公式（堆积密度=原子体积/晶胞体积）进行计算，属于单一知识点的简单应用，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用FCC结构的堆积密度公式（74%）即可得出答案，无需任何中间步骤或公式组合。" + }, + { + "idx": 594, + "question": "The stacking sequence of the close-packed planes in an FCC structure is", + "answer": "ABCABC…", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述FCC结构的密排面堆垛顺序，答案需要文字解释和论述（ABCABC…），而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查对FCC结构密排面堆垛顺序的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回忆和复述FCC结构中层错堆积顺序这一基础定义，属于最基础的概念记忆层面。不需要解释或推导过程，也不涉及多个概念的关联分析，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要描述概念特征（等级2）或阐述复杂晶体结构体系（等级3）的题目简单得多。" + }, + { + "idx": 595, + "question": "In the FCC structure, when atoms are regarded as rigid spheres with radius r, the relationship between the atomic radius and the lattice constant a is", + "answer": "r=a", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释FCC结构中原子半径与晶格常数之间的关系，答案需要文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目考查FCC结构中原子半径与晶格常数之间关系的基本概念记忆，属于晶体学基础知识的直接应用，无需复杂计算或分析。 | 难度: 在简答题中属于基本定义简答，仅需记忆FCC结构中原子半径与晶格常数的基本关系式r=a√2/4（原答案有误，应为r=a√2/4），无需解释推导过程或涉及复杂概念体系。该题完全符合等级1\"基本定义简答\"的特征要求。" + }, + { + "idx": 596, + "question": "The number of atoms in the unit cell of an FCC structure is", + "answer": "4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构单位晶胞中的原子数量，答案是一个具体的数值（4），不需要计算或选择，属于直接回答的简答题类型。 | 知识层次: 题目考查面心立方（FCC）结构单位晶胞中原子数目的记忆，属于晶体结构的基础概念记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆FCC结构单位晶胞中的原子数即可回答，无需额外解释或复杂概念阐述。" + }, + { + "idx": 597, + "question": "The necessary condition for forming an ordered solid solution is", + "answer": "Slow cooling rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释形成有序固溶体的必要条件，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查形成有序固溶体的必要条件，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答形成有序固溶体的必要条件（慢冷速率），属于对单一基础概念的记忆性回答，不需要展开解释或描述复杂概念体系。在简答题的三个难度等级中，这属于最简单的第一等级。" + }, + { + "idx": 598, + "question": "The close-packed plane of FCC structure is", + "answer": "{111}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构的密排面，答案是一个具体的晶面指数{111}，属于需要直接回答的简答题形式，不需要选择或判断。 | 知识层次: 题目考查对FCC结构密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于基础概念记忆类问题，仅需回答FCC结构的密排面指数{111}，不需要额外的解释或论述。这符合等级1\"基本定义简答\"的标准，是同类题型中最简单的类型。" + }, + { + "idx": 601, + "question": "The coordination number of FCC structure is", + "answer": "12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构的配位数，答案是一个具体的数值（12），不需要从多个选项中选择，也不需要判断对错或进行复杂的计算。虽然答案简短，但属于需要记忆或理解概念后直接回答的类型，符合简答题的特征。 | 知识层次: 题目考查面心立方(FCC)晶体结构中配位数的基本概念记忆，属于晶体学中最基础的定义性知识，不需要计算或分析过程。 | 难度: 在简答题题型中，此题仅要求回答FCC结构的配位数这一基本定义，不需要额外的解释或论述。属于最基础的概念记忆性知识，解题步骤简单直接，只需回忆并写出标准答案即可。在同题型内属于最低难度等级。" + }, + { + "idx": 602, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the changes of alloy properties is that strength and hardness", + "answer": "increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对材料性质变化趋势进行简要描述，答案需要文字解释而非选择或判断 | 知识层次: 题目考查对有序固溶体转变后性能变化趋势的基础概念记忆和理解，属于材料科学中相变与性能关系的基本知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答\"强度\"和\"硬度\"的变化趋势，不需要进行概念解释或复杂体系阐述。答案只需记忆有序固溶体转变的基本性质变化即可，属于最基础的概念记忆性知识。" + }, + { + "idx": 603, + "question": "In the Fe-Fe3C phase diagram, what is the carbon content below which the material is considered steel?", + "answer": "2.11%C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（2.11%C），不需要计算或选择，属于简答题类型 | 知识层次: 题目考查对Fe-Fe3C相图中钢的定义这一基本概念的记忆，仅需知道钢的碳含量上限为2.11%C即可回答，不涉及复杂计算或分析。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆Fe-Fe3C相图中钢与铸铁的分界碳含量（2.11%C），无需解释或推导过程，属于最基础的概念记忆层次。" + }, + { + "idx": 604, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the change of alloy properties is: electrical conductivity", + "answer": "decreases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释无序固溶体转变为有序固溶体时合金导电性的变化趋势，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目需要理解无序固溶体向有序固溶体转变的基本原理，并分析这种转变对合金导电性能的影响。这涉及到对材料科学中固溶体有序化过程及其对性能影响的中等应用，需要将概念关联和综合分析能力。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及有序-无序转变对导电性的影响这一特定知识点，但只需进行单一概念的解释和简单趋势说明，不需要多角度分析或深度关联性论证。回答时需要理解有序化导致电子散射增加的机制，但不需要复杂的推导或多因素综合分析，符合\"综合分析和说明\"的等级特征。" + }, + { + "idx": 605, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the change of alloy properties is: plasticity", + "answer": "decreases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释有序固溶体转变对合金性能的影响趋势，答案需要文字描述\"decreases\"来表明塑性变化趋势，属于需要简要文字回答的简答题类型 | 知识层次: 题目要求解释无序固溶体转变为有序固溶体时合金塑性变化的趋势，这需要理解固溶体的基本概念（记忆），并能够将有序化过程与塑性变化（位错运动难度增加）进行关联分析（概念关联）。虽然不涉及复杂计算，但需要多步逻辑推理和材料性能变化的综合分析。 | 难度: 在简答题中属于中等难度，需要理解有序固溶体和无序固溶体的概念，并分析其转变对塑性性能的影响。虽然题目要求一定的概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 606, + "question": "In the Fe-Fe3C phase diagram, what carbon content is greater than that of cast iron?", + "answer": "2.11%C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（2.11%C），而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。虽然答案简短，但属于需要特定知识回答的简答题类型。 | 知识层次: 题目考查对Fe-Fe3C相图中铸铁碳含量的基本概念记忆，只需直接回忆相图中的关键点（2.11%C为铸铁与钢的分界点），无需应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求回答Fe-Fe3C相图中铸铁的碳含量临界值（2.11%C），属于基础定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆相图中的关键数据点，符合等级1\"基本定义简答\"的标准。在同题型内相比，其认知负荷最低，无需推导或分析过程。" + }, + { + "idx": 607, + "question": "The carbon content of ledeburite is", + "answer": "4.3%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（4.3%），不需要从多个选项中选择，也不需要判断对错或进行复杂的计算，属于需要直接给出简短答案的类型。 | 知识层次: 题目考查对ledeburite碳含量的基础概念记忆，属于定义性知识的直接回忆，无需复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答一个具体的数值（4.3%），属于最基本的概念记忆性知识，不需要任何解释或论述步骤。这是该题型下最简单的一类问题，仅需直接回忆教材或课堂中明确给出的定义性数据即可作答。" + }, + { + "idx": 608, + "question": "The crystal structure of austenite is", + "answer": "FCC", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答晶体结构的类型，答案是一个简短的术语（FCC），不需要从多个选项中选择，也不需要判断对错或进行数值计算。 | 知识层次: 题目考查对奥氏体晶体结构这一基础概念的记忆，属于材料科学中最基本的定义性知识，不需要复杂的分析或应用。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并准确回答奥氏体的晶体结构类型（FCC），无需额外解释或复杂概念阐述，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 609, + "question": "At room temperature, the equilibrium microstructure of hypoeutectoid steel is", + "answer": "ferrite and pearlite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述亚共析钢在室温下的平衡显微组织，答案需要提供具体的材料相名称（铁素体和珠光体），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对亚共析钢在室温下平衡显微组织的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于基础概念记忆类问题，仅需回答\"ferrite and pearlite\"两个术语，无需展开解释或论述。题目直接考察对亚共析钢室温平衡组织的记忆，不涉及概念间的关联或复杂体系阐述，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 610, + "question": "During the equilibrium solidification of alloys, the maximum carbon content in austenite is", + "answer": "2.11%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（2.11%），这属于需要直接给出答案的简答题形式，不需要选择、判断或计算过程 | 知识层次: 题目考查铁碳相图中奥氏体最大碳含量的记忆性知识，属于基础概念的记忆和理解层面，不需要复杂的计算或分析过程。 | 难度: 在简答题题型中，该题目仅要求回答一个具体的数值（2.11%），属于基础概念记忆层面的简单问题。不需要解释或论述，只需准确回忆教材或课堂中提到的关键数据点。这符合等级1\"基本定义简答\"的标准，是同类题型中最基础的知识点考察。" + }, + { + "idx": 611, + "question": "What is the carbon content of pearlite", + "answer": "0.77%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（0.77%），不需要从多个选项中选择，也不涉及判断对错或复杂的计算过程，属于简短的直接回答类型 | 知识层次: 题目考查对珠光体碳含量的基础概念记忆，属于材料科学中最基本的相图知识，不需要复杂的分析或计算。 | 难度: 在简答题中属于基本定义简答，仅需记忆并准确回答珠光体的碳含量这一具体数值，无需进行概念解释或复杂体系阐述。" + }, + { + "idx": 612, + "question": "What are the two basic phases that make up the room-temperature equilibrium structure of iron-carbon alloys", + "answer": "Ferrite (α)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释铁碳合金在室温下的平衡结构中的两个基本相，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查铁碳合金室温平衡结构的基本相组成，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于基本定义简答，仅需回忆并写出铁碳合金室温平衡结构的两个基本相（铁素体和渗碳体）的名称，无需深入解释或复杂论述。" + }, + { + "idx": 613, + "question": "From what is Fe3CI precipitated", + "answer": "Liquid phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释Fe3CI的沉淀来源，答案是一个简短的文字描述\"Liquid phase\"，属于需要简要说明的简答题类型 | 知识层次: 题目考查Fe3CI沉淀来源的基础概念记忆，仅需回答\"Liquid phase\"这一简单事实，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答Fe3CI的沉淀来源（液相），属于最基本的概念记忆性知识，不需要额外的解释或论述。题目直接考察学生对基础定义的掌握，没有涉及概念间的联系或复杂体系的阐述，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 615, + "question": "What are the two basic phases that make up the room-temperature equilibrium microstructure of iron-carbon alloys?", + "answer": "Cementite (Fe3C)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释铁碳合金室温平衡微观结构的基本相，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对铁碳合金室温平衡显微组织基本组成的记忆，仅需要回答两个基本相的名称，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并写出铁碳合金室温平衡组织的两个基本相（铁素体和渗碳体）的名称，无需深入解释或复杂论述。" + }, + { + "idx": 616, + "question": "From what is Fe3CII precipitated", + "answer": "Austenite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答Fe3CII是从什么中沉淀出来的，答案\"Austenite\"是一个简短的术语解释，不需要选择或判断，也不需要计算，符合简答题的特征。 | 知识层次: 题目考查Fe3CII从何种相中析出的基础概念记忆，属于材料科学中相变的基础知识点，仅需对奥氏体(Austenite)这一基本概念的记忆即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答Fe3CII是从什么中析出的，答案\"Austenite\"是材料科学中最基础的概念之一，不需要额外的解释或论述。这类问题主要考察学生对基础概念的记忆能力，不涉及复杂的概念体系或深入的解释要求，因此在简答题题型中属于最低难度等级。" + }, + { + "idx": 617, + "question": "According to the effect of cooling rate on metal microstructure, how should the solidification be controlled to obtain an amorphous structure?", + "answer": "To obtain an amorphous structure, the molten metal should be cooled at an extremely rapid rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何控制凝固以获得非晶结构，答案是一个简短的文字说明，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解冷却速率对金属微观结构的影响，并应用这一知识来论述如何通过控制凝固过程获得非晶结构。这涉及到概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于中等难度，需要理解冷却速率对金属微观结构的影响，并能综合分析得出获得非晶结构的条件。虽然涉及概念关联，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 618, + "question": "Cold working and hot working", + "answer": "Cold working and hot working: Generally distinguished based on the recrystallization temperature of metal materials. Processing above the recrystallization temperature is called hot working, while processing below the recrystallization temperature and at room temperature is called cold working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对冷加工和热加工进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查冷加工和热加工的基本定义和区分标准，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求解释冷加工和热加工的基本定义和区分标准，不涉及复杂的概念体系或深入的原理分析。回答只需记忆并复述金属材料的再结晶温度作为区分标准这一基础知识点即可，解题步骤简单，对知识掌握深度要求较低。" + }, + { + "idx": 619, + "question": "Crystal zone and zone axis", + "answer": "Crystal zone and zone axis: The collective term for various sets of crystal planes parallel to the same crystal direction is called a crystal zone, and the crystal direction parallel to these sets of crystal planes is called the zone axis.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“Crystal zone and zone axis”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查晶体学中晶带和晶带轴的基本定义和概念记忆，属于基础概念的理解和记忆范畴，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求对\"crystal zone\"和\"zone axis\"这两个基础概念进行定义性回答，属于最基本的概念记忆层面。题目不涉及概念间的关联解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。与其他需要展开论述或解释机制的简答题相比，此题只需准确回忆教材定义即可作答，是同类题型中最基础简单的类型。" + }, + { + "idx": 620, + "question": "Jog and kink", + "answer": "Jog and kink: During the movement of dislocations, certain dislocation intersection lines are formed after intersecting with other dislocations. If the dislocation line after intersection lies on the original slip plane of the dislocation, this dislocation line is called a kink. If the dislocation line after intersection is perpendicular to the original slip plane of the dislocation, this dislocation line is called a jog.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Jog和kink进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对位错运动中形成的jog和kink的基本定义和分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求解释\"jog\"和\"kink\"这两个位错运动中的概念，并区分它们的不同之处。虽然需要记忆和理解这两个专业术语的定义，但并不涉及复杂的理论体系或深入的分析。这比单纯背诵基本定义（等级1）要求稍高，但远未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 621, + "question": "Peritectoid reaction and eutectoid reaction", + "answer": "Peritectoid reaction and eutectoid reaction: The process in which two solid phases react to form one solid phase is called a peritectoid reaction, while the reaction in which one solid phase decomposes into two other solid phases is called a eutectoid reaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对两个专业术语进行文字解释和论述，答案提供了详细的定义和区分，符合简答题的特征。 | 知识层次: 题目考查对peritectoid reaction和eutectoid reaction这两个基本概念的定义和区分，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释两种反应的定义和区别，涉及基础概念的记忆和理解，但不需要复杂的体系阐述或深入分析。解题步骤相对简单，只需准确描述两种反应的基本定义即可。" + }, + { + "idx": 622, + "question": "From what is Fe3CIII precipitated", + "answer": "Ferrite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答Fe3CIII是从什么中沉淀出来的，答案\"Ferrite\"是一个简短的文字解释，没有提供选项或需要计算，符合简答题的特征。 | 知识层次: 题目考查Fe3CIII沉淀来源的基础概念记忆，仅需回答\"Ferrite\"这一基本知识点，无需深入分析或复杂推理。 | 难度: 在简答题-基础概念记忆题型中，该题目仅要求回答Fe3CIII的沉淀来源（Ferrite），属于最基本的定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆单一知识点即可作答，符合等级1的基本定义简答特征。" + }, + { + "idx": 623, + "question": "The carbon content of Fe3CI, Fe3CII, Fe3CIII is", + "answer": "6.69%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的碳含量数值，不需要计算或选择，属于直接回答的简答题类型 | 知识层次: 题目考查的是Fe3C（渗碳体）中碳含量的记忆性知识，属于基础概念的记忆和理解，不需要复杂的计算或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回忆并写出Fe3C（渗碳体）的碳含量这一具体数值（6.69%），不涉及概念解释或复杂体系阐述，属于最基础的概念记忆层级。" + }, + { + "idx": 624, + "question": "According to the influence of cooling rate on metal microstructure, how should the solidification be controlled to obtain metastable phases?", + "answer": "To obtain metastable phases, the cooling rate must far exceed the equilibrium cooling rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何通过控制冷却速率获得亚稳相，需要文字论述而非选择、判断或计算 | 知识层次: 题目要求理解冷却速率对金属微观结构的影响，并应用这一知识来控制凝固过程以获得亚稳相。这需要将多个概念（冷却速率、平衡条件、亚稳相形成）关联起来，并进行综合分析。虽然不涉及复杂计算或深度机理分析，但超出了简单记忆或直接套用的范畴。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要理解冷却速率对金属微观结构的影响，并解释如何通过控制凝固过程获得亚稳相，但题目并未要求多角度分析或深度关联性分析。解题步骤相对直接，主要涉及概念关联和综合分析，符合等级3的要求。" + }, + { + "idx": 625, + "question": "Columnar crystals and equiaxed crystals", + "answer": "Columnar crystals and equiaxed crystals: During the crystallization process of metal crystals, the elongated grains that preferentially grow along the heat dissipation direction are called columnar crystals, while if the grains grow without a preferred direction and the growth rates in all directions are roughly equal, the resulting grains are called equiaxed crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Columnar crystals and equiaxed crystals\"进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对柱状晶和等轴晶这两个基本概念的定义和形成过程的理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释柱状晶和等轴晶的定义及其形成过程，涉及基础概念的记忆和简单描述，但不需要复杂的体系阐述或多概念比较分析。" + }, + { + "idx": 626, + "question": "Explain the effect of grain boundaries on material deformation", + "answer": "Grain boundaries strengthen metal materials at room temperature but weaken them at high temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶界对材料变形的影响，需要文字解释和论述，答案也是以文字形式给出，没有选项或计算要求。 | 知识层次: 题目要求解释晶界对材料变形的影响机制，涉及不同温度条件下的相反效应，需要综合运用材料科学原理进行机理分析和推理，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对晶界影响材料变形的机理进行深度解释，涉及温度依赖性的双重效应分析。虽然不需要全面分析复杂现象（如多因素耦合作用），但需要准确区分和解释室温与高温下的相反作用机制，属于机理深度解释层级的典型题目。" + }, + { + "idx": 627, + "question": "According to the solidification theory, analyze the characteristics of typical ingot structure", + "answer": "The typical ingot structure features fine equiaxed crystals in the outer layer, columnar crystals extending inward from the surface, and coarse equiaxed crystals in the center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据凝固理论分析典型铸锭结构的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对典型铸锭结构特征的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目要求对典型铸锭结构的特征进行解释和描述，涉及基础概念的记忆和简单分类。虽然需要理解并描述多个结构特征（外层细等轴晶、柱状晶和中心粗等轴晶），但不需要复杂的分析或深入的概念体系阐述，属于概念解释和描述的难度等级。" + }, + { + "idx": 628, + "question": "What final heat treatment process can be used for overhead copper conductors (requiring certain strength) after processing for outdoor use? Why?", + "answer": "Overhead copper conductors for outdoor use require high strength, and recovery annealing is generally used to eliminate stress while retaining certain strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么选择特定的热处理工艺，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释特定热处理工艺的选择原因，涉及材料性能需求（强度）与工艺（恢复退火）的关联分析，需要理解工艺对材料性能的影响机制，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求考生综合分析和说明铜导体的最终热处理工艺选择及其原因，需要理解材料性能需求（高强度）与热处理工艺（恢复退火）之间的关联性。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析，解题步骤相对直接，属于该题型框架内的中等难度水平。" + }, + { + "idx": 629, + "question": "How to improve the strength of solid solution alloys?", + "answer": "Solid solution strengthening, work hardening, grain refinement strengthening, precipitation strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何提高固溶体合金的强度，答案提供了多种方法的名称，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求列举提高固溶体合金强度的方法，涉及多个强化机制（固溶强化、加工硬化、晶粒细化强化、沉淀强化）的综合应用。虽然不需要深入解释每个机制的机理，但需要理解这些机制的基本原理及其在材料强化中的作用，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目要求对固溶体合金强化方法进行多角度分析论述，涉及四种不同的强化机制（固溶强化、加工硬化、晶粒细化强化、沉淀强化）。需要考生不仅列举方法，还要理解每种方法的原理及其相互关系，属于需要综合运用材料科学知识的分析论述题。相比只需简单列举的3级题目，该题对知识整合和论述深度的要求更高；但相比需要深度关联性分析的5级题目，又不需要建立跨学科或超纲的理论关联。" + }, + { + "idx": 630, + "question": "What final heat treatment process can be used for decorative wires for indoor electric lights after processing? Why?", + "answer": "Decorative wires for indoor electric lights need to be easily deformable and have high electrical conductivity. Recrystallization annealing can be used to soften them and achieve high electrical conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么选择特定的热处理工艺，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要将材料的热处理工艺（再结晶退火）与特定应用场景（装饰性电线）的性能要求（易变形性和高导电性）进行关联分析，属于中等应用层次的知识运用。 | 难度: 在简答题中属于中等难度，需要理解材料的热处理工艺及其对性能的影响，并进行综合分析说明。题目要求解释为何选择再结晶退火作为最终热处理工艺，涉及材料软化与导电性的关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 631, + "question": "Give two examples to illustrate the phenomenon of uphill diffusion in metals", + "answer": "Examples of uphill diffusion in metals include the formation of Cottrell atmospheres and the spinodal decomposition process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出两个例子来说明金属中的上坡扩散现象，答案需要文字解释和具体实例，属于简答题类型 | 知识层次: 题目要求举例说明金属中的上坡扩散现象，需要理解上坡扩散的概念，并能将其与具体的金属现象（如Cottrell气团和旋节分解）关联起来。这涉及到对概念的理解和应用，以及多个知识点的综合运用，但不需要复杂的推理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解并解释两个具体的金属扩散现象（Cottrell atmospheres和spinodal decomposition），但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 632, + "question": "Briefly explain the effect of atomic diffusion on materials", + "answer": "The effects of atomic diffusion on materials include processes such as grain nucleation and growth in casting, grain boundary movement, oxidation, etc., all of which involve atomic diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释原子扩散对材料的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对原子扩散效应的基本概念记忆和理解，涉及的是基础现象和简单列举，不需要深入分析或综合应用 | 难度: 在简答题题型中，该题目要求解释原子扩散对材料的影响，涉及多个具体过程（如晶粒成核与生长、晶界移动、氧化等）的列举和简要说明。这属于概念解释和描述的层次，比单纯的定义简答（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 633, + "question": "Explain why solid solution alloys can grow in a dendritic manner under a positive temperature gradient during solidification, while pure metals cannot form dendritic crystals.", + "answer": "Due to solute redistribution causing constitutional supercooling, solid solution alloys can grow dendritically even under a positive temperature gradient during solidification; whereas pure metals require a negative temperature gradient to form dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液合金在正温度梯度下形成枝晶的原因，并对比纯金属的情况，需要详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶体合金在正温度梯度下形成枝晶的机理，并对比纯金属的凝固行为。这需要深入理解溶质再分配、成分过冷等概念，并综合分析温度梯度、晶体生长方式等影响因素。涉及多个概念的关联和机理层面的解释，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对固溶体合金和纯金属的凝固行为进行对比分析，涉及溶质再分配、成分过冷等复杂机理的解释。需要综合运用相变原理、热力学和动力学知识，全面分析不同条件下枝晶生长的形成机制。这种需要多学科知识整合和深度机理阐述的题目，在该题型内属于最高难度等级。" + }, + { + "idx": 634, + "question": "Explain the influence of grain boundaries on material properties", + "answer": "Grain boundaries affect various aspects of materials, possessing grain boundary energy, influencing the shape of second phases in polycrystalline materials. Grain boundaries can move, exhibit grain boundary segregation, undergo changes in grain boundary charge, bear load transfer effects, have low melting points and are prone to overheating. Grain boundaries serve as easy diffusion paths, facilitate nucleation, and are susceptible to corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶界对材料性能的影响，需要文字解释和论述，答案也以文字形式详细阐述了晶界的多种作用，符合简答题的特征。 | 知识层次: 题目要求解释晶界对材料性能的影响，涉及多个方面的效应（如能量、扩散、腐蚀等），需要将晶界的基本概念与材料性能进行关联分析，属于中等应用层次。虽然不涉及复杂计算，但需要对多个知识点进行综合理解和应用。 | 难度: 在简答题题型中，该题目要求多角度分析论述，涉及多个方面的材料科学知识，包括晶界能量、第二相形状、晶界运动、晶界偏析、晶界电荷变化、载荷传递效应、低熔点特性、扩散路径、成核作用以及腐蚀敏感性等。需要考生综合运用相关知识，进行较为全面的分析和论述，属于较高难度的简答题。" + }, + { + "idx": 635, + "question": "Metal glass", + "answer": "Metal glass: refers to a solid formed when metal solidifies from a liquid state, retaining the same structure as the liquid metal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Metal glass\"进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查金属玻璃的基本定义和形成过程，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求给出金属玻璃的定义，不需要进行概念解释或复杂体系阐述。这符合基础概念记忆的知识层次要求，是同类题型中最简单的类型。" + }, + { + "idx": 636, + "question": "Grain boundary segregation", + "answer": "Grain boundary segregation: The enrichment phenomenon of solute atoms or impurity atoms at grain boundaries due to the difference in distortion energy between the grain interior and grain boundaries or the presence of vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Grain boundary segregation\"进行文字解释和论述，答案提供了详细的定义和原因说明，符合简答题的特征。 | 知识层次: 题目考查对晶界偏析这一基本概念的定义和现象解释，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要准确表述晶界偏析的定义和原因，但不需要涉及复杂的概念体系或深入的分析。主要考察对基础概念的理解和记忆，属于中等难度的简答题。" + }, + { + "idx": 637, + "question": "Intermetallic compounds", + "answer": "Intermetallic compounds: Compounds formed between metals and metals, or between metals and certain non-metals, whose structure and composition differ from those of the pure metals forming the intermetallic compounds. They generally exhibit characteristics such as high melting points, high hardness, and significant brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Intermetallic compounds\"进行解释和论述，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对金属间化合物的基本定义和特性的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"Intermetallic compounds\"进行基本定义和简单特性描述，属于最基础的概念记忆层面。不需要解释形成机制、分类体系或应用场景等更深层次的内容，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 638, + "question": "Cottrell atmosphere", + "answer": "Cottrell atmosphere: the phenomenon of solute atoms aggregating around an edge dislocation. This atmosphere can impede dislocation motion, resulting in effects such as solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Cottrell atmosphere\"进行文字解释和论述，答案提供了详细的定义和影响，符合简答题的特征。 | 知识层次: 题目考查对Cottrell atmosphere这一基本概念的定义和简单解释，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求解释\"Cottrell atmosphere\"的定义及其作用，涉及对基本概念的理解和简单描述，但不需要深入分析或阐述复杂的概念体系。因此，在简答题的框架内，该题目属于中等难度。" + }, + { + "idx": 639, + "question": "Divorced eutectic", + "answer": "Divorced eutectic: In alloys with eutectic reactions, if the composition is far from the eutectic point, due to the large amount of primary crystals and the small amount of eutectic, the same phase in the eutectic as the primary crystals attaches to the primary crystals and grows, while the other phase in the eutectic appears separately distributed, causing the eutectic structure to lose its characteristic organizational features.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Divorced eutectic\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"divorced eutectic\"这一专业术语的定义和基本特征的理解和记忆，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目要求解释\"divorced eutectic\"的概念，并描述其在合金中的具体表现和形成原因。虽然需要一定的记忆和理解，但不需要涉及复杂的理论体系或多层次的分析。属于概念解释和描述的难度等级。" + }, + { + "idx": 640, + "question": "Twinning", + "answer": "Twinning: An important mode of plastic deformation in crystals. Under shear stress, one part of the crystal undergoes uniform shear relative to another part along specific crystallographic planes and directions, resulting in different orientations of adjacent crystal regions that are mirror-symmetrical across the twinning plane (twin boundary).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Twinning\"这一概念进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"Twinning\"这一基本概念的定义和基本原理的记忆和理解，属于材料科学中晶体变形的基础知识，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对\"Twinning\"这一概念进行解释，包括其作为塑性变形模式的作用、在剪切应力下的行为特征以及形成的晶体取向关系等。虽然需要描述多个方面，但都属于基础概念层面的解释，不需要进行复杂的体系阐述或深入分析。相比等级1的简单定义回答，该题目要求更全面的概念描述；但相比等级3需要阐述复杂概念体系的要求，该题目仍属于中等难度的概念解释题。" + }, + { + "idx": 641, + "question": "Explain the main factors affecting the diffusion coefficient in the equation", + "answer": "The main factors affecting the diffusion coefficient in the equation include temperature, crystal structure, crystal defects, type of solid solution, properties of the diffusing element, and concentration of the diffusing component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响扩散系数的主要因素，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目要求解释影响扩散系数的主要因素，涉及多个概念（如温度、晶体结构、缺陷等）的关联和综合分析，需要理解这些因素如何相互作用并影响扩散过程，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求列举并解释影响扩散系数的主要因素，但不需要进行多角度或深度关联性分析。回答该问题需要掌握相关概念并能进行综合说明，但不需要复杂的解题步骤或深入的理论推导。因此，在简答题的框架内，该题目属于综合分析和说明的难度水平。" + }, + { + "idx": 643, + "question": "Determine whether the dislocation reaction a/6[2\\overline{1}\\overline{1}] + a/6[\\overline{1}21] → a/6[110] can proceed in a face-centered cubic crystal?", + "answer": "With reference to the geometric and energy conditions, the dislocation reaction can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过几何和能量条件分析位错反应是否可行，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析位错反应在面心立方晶体中是否能够进行，需要综合运用几何条件和能量条件进行判断。这涉及到位错的基本概念、反应条件、晶体结构等多方面知识的综合应用和推理分析，思维过程较为复杂，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用位错几何条件（矢量守恒）和能量条件（Frank准则）进行机理分析，需要深入理解面心立方晶体中的位错反应机制，并能够全面评估反应可行性。这属于该题型框架内最高难度的复杂现象全面分析要求。" + }, + { + "idx": 644, + "question": "If the leading dislocations of two extended dislocations undergo the reaction a/6[2\\overline{1}\\overline{1}] + a/6[\\overline{1}21] → a/6[110], what effect will it have on the properties of face-centered cubic metals?", + "answer": "The dislocations become immobile after the reaction, affecting the work hardening mechanism and fracture properties of the crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应对面心立方金属性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及位错反应的机理分析及其对材料性能的影响，需要综合运用位错理论、晶体结构知识以及材料性能变化的推理分析。这要求考生不仅理解位错反应的基本原理，还需要分析位错反应后位错的可动性变化及其对材料宏观性能的影响，属于较高层次的认知能力。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于复杂现象全面分析的难度等级。题目要求考生不仅理解位错反应的基本原理，还需要综合运用晶体缺陷理论、面心立方金属的变形机制以及位错交互作用对材料性能的影响等多方面知识。解题过程涉及多个步骤的推理分析，包括位错反应的能量条件、反应后位错的可动性变化以及对宏观力学性能（如加工硬化和断裂行为）的机理解释。这要求考生具备扎实的理论基础和较高的综合分析能力，符合该题型内最高难度等级的标准。" + }, + { + "idx": 645, + "question": "Reaction diffusion", + "answer": "Reaction diffusion: The diffusion accompanied by chemical reactions that leads to the formation of new phases is called reaction diffusion. For example, when infiltrating elements diffuse from the metal surface into the interior and their concentration exceeds the solubility limit, new phases appear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Reaction diffusion\"进行定义和解释，并提供例子，这需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是反应扩散的基本定义和简单例子，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题中属于中等难度，需要解释反应扩散的定义并举例说明，涉及概念描述和具体实例的结合，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 646, + "question": "Write the expression for the unsteady-state diffusion equation", + "answer": "The expression for the unsteady-state diffusion equation is: ∂C/∂t = ∂(D(∂c/∂x))/∂x. If the diffusion coefficient D does not vary with concentration, it can be simplified to ∂C/∂t = D(∂²c/∂x²).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出非稳态扩散方程的表达式，并给出了详细的解释和简化条件，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对非稳态扩散方程表达式的记忆和基本理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要写出扩散方程的表达式，但题目已经给出了简化条件（扩散系数D不随浓度变化），降低了复杂度。相比等级1的基本定义简答，该题需要理解并描述方程的含义和简化条件，但不需要进行复杂概念体系的阐述（等级3要求）。" + }, + { + "idx": 647, + "question": "Point out the main factors affecting the recrystallization temperature of metals after cold deformation", + "answer": "The main factors affecting the recrystallization temperature of metals after cold deformation are: degree of deformation, trace impurities and alloying elements, metal grain size, heating time, heating rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响金属再结晶温度的主要因素，需要文字解释和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目主要考查对金属再结晶温度影响因素的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举影响金属再结晶温度的主要因素，这需要学生对相关基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目需要更多的知识点串联；相比等级3的复杂概念体系阐述，该题目又相对简单直接。因此在该题型内属于中等难度。" + }, + { + "idx": 648, + "question": "What are the main measures to obtain fine recrystallized grains, and why?", + "answer": "The main measures to obtain fine recrystallized grains are: increasing the degree of cold deformation, adding trace alloying elements, increasing the heating rate, and using fine-grained metals", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述获得细小再结晶晶粒的主要措施及其原因，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目不仅要求列举获得细晶再结晶的主要措施，还需要解释原因，涉及多步概念关联和综合分析。虽然不涉及复杂计算，但需要对材料科学中的再结晶过程有较深入的理解和应用能力。 | 难度: 在简答题题型中，该题目要求考生不仅列举获得细晶粒的主要措施，还需要解释原因，涉及多角度分析和论述。题目涵盖了冷变形程度、合金元素添加、加热速率和初始晶粒尺寸等多个因素的综合分析，需要考生具备较强的概念关联和综合分析能力，属于该题型中的较高难度等级。" + }, + { + "idx": 649, + "question": "Describe the main strengthening mechanisms that can be employed to strengthen Al-5%Cu alloy", + "answer": "The strengthening mechanisms for Al-5%Cu alloy are solid solution strengthening, precipitation strengthening, work hardening, and grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述铝合金的主要强化机制，需要文字解释和论述，答案给出了多个强化机制的详细说明，符合简答题的特征 | 知识层次: 题目要求描述铝合金的主要强化机制，需要理解并关联多个强化机制（固溶强化、沉淀强化、加工硬化和晶粒细化强化）的概念及其在Al-5%Cu合金中的应用。这涉及到对材料科学中强化机制的综合理解和应用，而不仅仅是简单的记忆或单一概念的套用。 | 难度: 在简答题题型中，该题目要求对Al-5%Cu合金的强化机制进行多角度分析论述。需要考生不仅列举出主要的强化机制（固溶强化、沉淀强化、加工硬化和晶粒细化强化），还需要理解并解释这些机制如何具体应用于该合金体系。这涉及到对材料科学中强化机制的综合理解，以及将这些概念与特定合金体系关联的能力。虽然不需要进行深度关联性分析（如讨论各机制间的交互作用或定量计算），但仍需展示出对多个强化机制的系统性认识和应用能力，因此属于该题型中的较高难度等级。" + }, + { + "idx": 650, + "question": "What is the relationship between the corrosion of engineering materials and bonding?", + "answer": "The essence of corrosion in engineering materials is the formation and destruction of bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释工程材料腐蚀与键合之间的关系，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释工程材料腐蚀与键合之间的关系，这需要综合运用材料科学中的腐蚀机理和化学键合理论，进行推理分析和机理解释。涉及的知识点较为复杂，需要深入理解腐蚀过程中的键形成和断裂机制，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对腐蚀现象与材料键合之间的关系进行机理层面的深度解释。虽然不涉及多因素交互作用的全面分析（等级5特征），但需要综合运用材料科学和化学键理论的知识，解释腐蚀过程中键的形成与断裂这一核心机理。这超越了简单的事实陈述（等级1-2）和基础原理说明（等级3），属于需要建立理论关联的机理解释层面。" + }, + { + "idx": 651, + "question": "Describe the main strengthening mechanisms that may be employed to strengthen the Al-5%Al2O3 composite material", + "answer": "The strengthening mechanisms for the Al-5%Al2O3 composite material are work hardening, fine grain strengthening, and dispersion strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述主要的强化机制，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求描述铝基复合材料的强化机制，涉及多个强化机制（加工硬化、细晶强化、弥散强化）的综合分析，需要理解这些机制的基本原理及其在复合材料中的相互作用，属于中等应用层次的知识。 | 难度: 在简答题中属于中等难度，需要理解并综合说明多种强化机制，但不需要深入分析各机制之间的相互作用或更复杂的关联性。" + }, + { + "idx": 652, + "question": "For industrial pure copper ingots with low stacking fault energy, after hot breakdown rolling at $T=0.5T_{\\\\xi\\\\sharp,\\\\xi}$ temperature, what methods can be adopted in the final process to obtain semi-hard products, and why?", + "answer": "To obtain semi-hard products, cold working followed by recovery annealing, or appropriate cold deformation after complete recrystallization annealing can be adopted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述具体的加工方法及其原理，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目要求分析工业纯铜锭在特定热轧条件下的后续处理方法，并解释原因。这需要综合理解材料的加工工艺（热轧、冷加工、退火等）、材料性能（半硬态产品的获得）以及微观结构演变（回复、再结晶等）之间的复杂关系。解答不仅需要应用多个知识点，还需要进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于机理深度解释难度等级。题目要求考生综合运用材料科学知识（如堆垛层错能、热加工温度选择、冷加工与退火工艺），并解释工艺选择背后的材料学机理（如位错运动、回复/再结晶行为）。虽然不需要多因素动态分析（等级5特征），但需要建立完整的因果逻辑链，属于该题型中较高阶的认知要求。" + }, + { + "idx": 653, + "question": "Describe the main strengthening mechanisms that can be employed for industrial pure aluminum", + "answer": "The main strengthening mechanisms for industrial pure aluminum are work hardening and grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述工业纯铝的主要强化机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对工业纯铝主要强化机制的基本概念记忆和理解，仅需列举和简要说明两种强化机制（加工硬化和晶粒细化强化），不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述工业纯铝的主要强化机制，涉及两个关键概念（加工硬化和晶粒细化强化）的解释。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或深入分析，属于概念解释和描述的中等难度级别。" + }, + { + "idx": 654, + "question": "For industrial pure copper ingots with low stacking fault energy, after hot breakdown rolling at $T=0.5T_{\\\\xi\\\\sharp,\\\\xi}$ temperature, what methods can be used in the final process to obtain soft-state products, and why?", + "answer": "To obtain soft-state products, cold working followed by recrystallization annealing can be used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述具体的工艺方法及其原理，答案需要文字说明而非选择、判断或计算。 | 知识层次: 题目要求分析低堆垛层错能工业纯铜锭在特定温度热轧后的软化处理方法，并解释原因。这需要综合运用材料加工工艺学、金属学原理（如再结晶退火机制）和材料性能控制等多方面知识，涉及机理层面的解释和工艺路线的合理选择，属于较高层次的综合分析能力。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用材料科学知识（包括热加工、冷加工、再结晶退火等工艺原理），需要深入理解低层错能工业纯铜的热变形行为及其后续处理对材料性能的影响机制。题目不仅要求提出具体方法（冷加工+再结晶退火），还需要解释为什么这种方法能获得软态产品，涉及位错运动、储存能释放、晶粒重组等多重机理的耦合分析，属于该题型下对知识整合和机理阐述要求最高的复杂现象全面分析层级。" + }, + { + "idx": 655, + "question": "What is work hardening?", + "answer": "The phenomenon where the flow stress of a metal increases with increasing strain during cold working is called work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述\"work hardening\"的概念，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，仅需要解释work hardening的定义和现象，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。不需要进行额外的解释或描述，也不涉及复杂概念体系的阐述。因此在该题型内属于最低难度等级。" + }, + { + "idx": 657, + "question": "How do the types of material bonding bonds affect the physical properties of materials?", + "answer": "The stronger the bonding bond, the higher the melting point, the smaller the thermal expansion coefficient, and the greater the density. Metals have luster, high electrical and thermal conductivity, good mechanical strength and plasticity, and a positive temperature coefficient of resistance, which are related to the metallic bonds of metals. Ceramics and polymers are generally non-conductive in the solid state, which is related to their non-metallic bonding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料键合类型如何影响物理性质，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释材料键合类型如何影响物理性质，涉及对不同键合类型（金属键、离子键、共价键等）的理解及其与材料性质（如熔点、导电性、机械强度等）的关联。这需要多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目要求对材料键合类型与物理性质之间的关系进行多角度分析论述。不仅需要解释不同键合类型对材料性质的具体影响，还需要举例说明金属、陶瓷和聚合物等不同材料的特性与其键合类型的关系。这种综合分析和对多个概念的关联性论述使得该题目在简答题中属于较高难度等级。" + }, + { + "idx": 658, + "question": "What are the adverse effects of texture on metal materials?", + "answer": "Texture induces anisotropy in metals, and anisotropy often causes difficulties in the processing and use of metals. Deep-drawn metal cups may develop ears. Polycrystalline metal rods with texture can significantly elongate after repeated heating and cooling cycles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释纹理对金属材料的不良影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释纹理对金属材料的不利影响，涉及纹理引起的各向异性及其在加工和使用中的具体表现（如深冲杯的耳状缺陷、多晶金属棒的热循环伸长）。这需要理解纹理的基本概念，并将其与实际应用中的现象关联起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释纹理对金属材料的不良影响，并需要列举具体现象（如深冲金属杯的耳状变形、多晶金属棒的热循环伸长等）。虽然涉及多个概念和现象，但不需要进行多角度或深度关联性分析，主要考察对纹理诱导各向异性及其后果的综合理解和说明能力。解题步骤相对直接，属于典型的综合分析说明类问题。" + }, + { + "idx": 659, + "question": "How do the types of material bonding affect the mechanical properties of materials?", + "answer": "The hardness of crystalline materials is related to the bonding of the crystals. Generally, crystals bonded by covalent bonds, ionic bonds, and metallic bonds have higher hardness than those bonded by molecular bonds. The greater the bonding energy between the bonds, the higher the elastic modulus. The strength of engineering materials is also somewhat related to the bonding energy. Generally, higher bonding energy results in higher strength. The plasticity of materials is also related to the type of bonding. Materials bonded by metallic bonds exhibit good plasticity, while those bonded by ionic or covalent bonds have difficulty undergoing plastic deformation, hence ceramic materials exhibit very poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料键合类型如何影响机械性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释不同类型的材料键合如何影响机械性能，涉及多个概念（如硬度、弹性模量、强度、塑性）的关联和综合分析，需要理解键合类型与性能之间的关系并进行多方面的论述。 | 难度: 在简答题题型中，该题目要求对材料键合类型与机械性能之间的关系进行多角度分析论述。需要综合理解不同键合类型（共价键、离子键、金属键、分子键）对硬度、弹性模量、强度和塑性的影响，并能够关联这些概念进行详细说明。虽然不需要进行深度关联性分析（如涉及更复杂的材料系统或极端条件），但已经超出了简单的概念解释，属于多角度分析论述的难度等级。" + }, + { + "idx": 660, + "question": "List the various possible mechanisms of work hardening", + "answer": "The mechanisms of work hardening are mainly the interactions between dislocations, such as the formation of jogs, dislocation intersection and entanglement, the interaction between moving dislocations and forest dislocations, the formation of Lomer-Cottrell locks, and the formation of solute atom atmospheres due to the interaction between solute atoms and dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列出各种可能的加工硬化机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举并解释加工硬化的多种机制，涉及位错之间的复杂相互作用（如割阶形成、位错交截和缠结、运动位错与林位错的相互作用、Lomer-Cottrell锁的形成、溶质原子与位错的相互作用形成溶质原子气团等）。这需要深入理解位错理论及其相互作用机制，属于对材料变形机理的综合分析和解释，思维深度和知识关联度较高。 | 难度: 在简答题中属于机理深度解释难度，需要详细列举并解释多种工作硬化机制，涉及位错相互作用、溶质原子与位错的交互等复杂概念，要求考生具备扎实的理论基础和综合分析能力。" + }, + { + "idx": 661, + "question": "Choose any material and describe its possible uses and processing methods.", + "answer": "Aluminum alloy is used to manufacture packaging containers such as beverage cans and food cans. For example, beverage companies like Coca-Cola and Pepsi extensively use aluminum alloy cans, which offer excellent sealing, corrosion resistance, and recyclability, ensuring beverage quality protection and convenience for consumers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求选择一个材料并描述其用途和加工方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述材料的用途和加工方法，属于对基础知识的直接应用，不需要复杂的分析或综合。回答中提到的铝合金属性及其在包装容器中的应用属于简单应用层面。 | 难度: 在简答题中属于中等难度，需要学生选择一个材料并描述其用途和加工方法。题目要求学生不仅知道材料的基本性质，还需要了解其实际应用和加工工艺，但不需要深入的分析或复杂的推理。答案中提供了具体的应用实例和加工方法的简要说明，符合应用方法说明的要求。" + }, + { + "idx": 662, + "question": "How does temperature affect the diffusion coefficient?", + "answer": "As temperature increases, the diffusion coefficient increases sharply.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释温度对扩散系数的影响，答案以文字论述形式给出，没有涉及选项选择、对错判断或数值计算 | 知识层次: 题目考查温度对扩散系数影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答温度对扩散系数影响的基本关系，属于最基础的定义简答。不需要解释扩散系数的定义、推导过程或涉及复杂的影响因素分析，仅需记忆并复述温度与扩散系数的正相关关系即可。因此在该题型和知识层次下属于最低难度等级。" + }, + { + "idx": 663, + "question": "What are the beneficial applications of texture in metallic materials?", + "answer": "In some cases, it is necessary to deliberately obtain certain textures to utilize their anisotropy, such as silicon steel sheets for transformers, high-voltage electronic aluminum foils for precision electronic capacitors, and interstitial-free steels used in automotive and mechanical sectors that require superior deep-drawing performance. For heat-treatable non-strengthening aluminum alloys, work hardening through cold deformation can be employed to strengthen the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纹理在金属材料中的有益应用，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释纹理在金属材料中的有益应用，并列举具体实例。这需要理解纹理的概念及其对材料性能的影响，并将这些概念与实际应用场景关联起来。虽然不涉及复杂的计算或深度机理分析，但需要一定的综合分析能力和知识点之间的关联。 | 难度: 在简答题题型中，该题目要求多角度分析论述金属材料织构的有益应用。需要考生不仅列举具体应用实例（如硅钢片、高压电子铝箔、无间隙原子钢等），还要解释这些应用中织构各向异性的作用机制，并关联冷变形强化等材料加工原理。这超出了简单概念复述（等级3），但尚未达到需要深度理论推导的等级5水平。" + }, + { + "idx": 664, + "question": "Explain the industrial applications of work hardening", + "answer": "Industrial applications of work hardening: During processing, the resistance of metal to plastic deformation continuously increases, making the metal brittle and necessitating multiple intermediate annealing processes, which requires more power consumption for cold working of the metal; work hardening provides the metal matrix with a certain ability to resist accidental overload; appropriate combination of work hardening and plastic deformation enables uniform plastic deformation of the metal, and some processing methods require the metal to have a certain degree of work hardening; work hardening is also one of the important means to strengthen metals, and for some pure metals, work hardening is a key method to improve strength; some components continuously harden on the surface under working conditions, meeting requirements for impact and wear resistance on the surface; after work hardening, the plasticity of materials decreases, improving machinability of materials such as low-carbon steel; the final properties of products can be controlled through cold working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释工作硬化的工业应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释工业应用，涉及多个方面的综合分析，包括金属加工过程中的变形、强化机制、性能控制等，需要将工作硬化的基本原理与实际工业应用场景相结合，进行中等程度的分析和应用。 | 难度: 在简答题题型中，该题目要求对工作硬化的工业应用进行多角度分析论述。题目不仅需要解释工作硬化的基本概念，还需要详细说明其在工业中的多种应用场景，包括金属加工、强度提升、表面处理等多个方面。此外，题目还要求考生能够综合分析工作硬化对不同材料性能的影响，如塑性、强度和加工性能等。这种多角度的分析和论述要求考生具备较高的知识整合能力和综合分析能力，因此在简答题题型中属于较高难度等级。" + }, + { + "idx": 665, + "question": "What are the methods for controlling the texture of metal materials?", + "answer": "One method to control texture is by regulating the processing and heat treatment regimes to obtain a processed structure with only slight texture and a fine-grained recrystallized structure. Additionally, altering the production process of rolled plates, combining intermediate recrystallization annealing during cold working with final recovery annealing can control texture. The cross-rolling method can also be employed. Controlling the hot rolling process of aluminum alloy sheets, multi-directional cross cold rolling, and corresponding annealing can reduce the formation of ears.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释控制金属材料织构的方法，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释和论述控制金属材料织构的方法，涉及多个工艺步骤（如热处理、轧制、退火等）的综合应用和概念关联，需要一定的综合分析能力，但不需要复杂的机理分析或创新设计。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求考生不仅列举控制金属材料织构的方法，还需要详细解释每种方法的原理和实施步骤，如调节加工和热处理制度、改变轧制工艺、采用交叉轧制法等。这需要考生具备对金属材料加工和热处理过程的深入理解，并能将不同方法进行关联和综合分析。虽然题目没有要求极其深入的关联性分析（如微观机制与宏观性能的关联），但多方法的列举和解释已经超出了简单的概念说明，属于中等偏上的难度。" + }, + { + "idx": 666, + "question": "How do crystal defects affect the diffusion coefficient?", + "answer": "The diffusion rate of atoms along line defects (dislocations) and planar defects (grain boundaries and free surfaces, etc.) is much greater than that of bulk diffusion within the crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶体缺陷如何影响扩散系数，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释晶体缺陷对扩散系数的影响，涉及多个概念（线缺陷、面缺陷、体扩散）的关联和综合分析，需要理解缺陷类型与扩散速率之间的关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释晶体缺陷如何影响扩散系数，需要理解晶体缺陷的类型（如线缺陷和面缺陷）以及它们对原子扩散速率的影响。虽然题目涉及多个概念（如位错、晶界、表面扩散等），但不需要进行复杂的多角度分析或深度关联性分析。解题步骤相对直接，主要是对已知概念的阐述和比较。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 667, + "question": "Briefly explain the role of the second phase during cold plastic deformation", + "answer": "The primary deformation modes of duplex alloys remain slip and twinning. Due to differences in the type, quantity, size, shape, distribution characteristics of the second phase in the alloy, as well as its interfacial bonding with the matrix, the influence of the second phase on plastic deformation is complex. If both phases in the duplex alloy are plastic, and the size and deformability of the second phase are similar to those of the matrix, the deformation of the alloy depends on the volume fraction of the two phases. If one phase is plastic and the other is hard and brittle, the plastic deformation of the alloy mainly depends on the presence of the hard and brittle phase. If the second phase is coarse or large-needle-shaped, deformation occurs only in the matrix, and the alloy's plasticity will not be high. If the second phase is continuously distributed along the grain boundaries of the solid solution, the alloy becomes very brittle and almost incapable of plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释第二相在冷塑性变形中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第二相在冷塑性变形中的作用，涉及多种情况的分析和综合，包括不同相的性质、尺寸、形状、分布及其对塑性变形的影响。这需要深入理解材料科学中的塑性变形机制，并能对不同条件下的变形行为进行推理和解释。 | 难度: 在简答题的复杂分析层次中，该题目要求全面分析第二相在冷塑性变形中的多重作用机制。需要综合考量第二相的类型、数量、尺寸、形状、分布特征以及与基体的界面结合等多种因素，并推理其对塑性变形的复杂影响模式。题目涉及多相合金变形行为的机理深度解释和条件分析，属于该题型内最高难度的综合现象分析类问题。" + }, + { + "idx": 668, + "question": "How does the anisotropy of crystals affect the diffusion coefficient?", + "answer": "The anisotropy of crystals also affects the diffusion coefficient, but this anisotropy gradually decreases with increasing temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体各向异性对扩散系数的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及晶体各向异性对扩散系数的影响机制，需要理解晶体结构、扩散机制以及温度对各向异性的影响，属于综合分析多个概念并解释其相互关系的复杂分析层次。 | 难度: 在简答题（复杂分析类）中，该题目要求解释晶体各向异性对扩散系数的影响机制，并涉及温度变化的动态分析。虽然不需要多因素交叉分析（如等级5要求的复杂现象全面分析），但仍需深入理解晶体结构特性与扩散动力学的关联性，属于机理深度解释范畴。" + }, + { + "idx": 669, + "question": "How does allotropic transformation affect the diffusion coefficient?", + "answer": "In metals with allotropic transformation, the diffusion coefficient changes significantly with the alteration of crystal structure, and the diffusion coefficient of solute atoms in BCC crystal structure is larger than that in FCC.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释同素异构转变如何影响扩散系数，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释同素异构转变对扩散系数的影响机制，涉及晶体结构变化与扩散行为的关联分析，需要综合运用材料科学中的相变理论和扩散理论进行机理层面的解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对同素异构转变如何影响扩散系数进行机理深度解释。需要综合运用晶体结构和扩散理论的知识，分析不同晶体结构（BCC和FCC）对扩散系数的影响，并解释其背后的物理机制。虽然不涉及多因素交互作用的全面分析，但对机理的解释要求较高，属于该题型中的较高难度题目。" + }, + { + "idx": 670, + "question": "What is the difference in diffusion activation energy between interstitial atoms and substitutional atoms?", + "answer": "The diffusion activation energy of interstitial atoms is much smaller than that of substitutional atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两种原子扩散激活能的差异，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对间隙原子和置换原子扩散激活能差异的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释间隙原子和置换原子在扩散激活能方面的差异，这需要对两种扩散机制的基本原理有一定理解，但不需要进行复杂的概念体系阐述或深入分析。属于基础概念记忆层次中需要简单解释的题目。" + }, + { + "idx": 671, + "question": "How does solute concentration affect the diffusion coefficient?", + "answer": "In many solid solution alloys, the diffusion coefficient of the solute increases with increasing concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释溶质浓度如何影响扩散系数，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及扩散系数与溶质浓度关系的理解，需要将扩散理论的基本概念与实际合金体系中的现象关联起来进行分析，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释溶质浓度对扩散系数的影响，但答案相对直接，主要涉及单一概念的应用和基本关系的说明。不需要多角度分析或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 672, + "question": "Explain the basic concept of dislocations", + "answer": "Dislocations are a type of arrangement defect in crystal structures, which can be divided into edge dislocations, screw dislocations, and mixed dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释位错的基本概念，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释位错的基本概念和分类，属于对晶体缺陷基础知识的记忆和理解，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答位错的基本定义和简单分类，属于最基础的概念记忆层面。不需要深入解释位错的形成机制、运动特性或对材料性能的影响等复杂内容，解题步骤极为简单，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 673, + "question": "How does the difference in properties between the diffusing element and the solvent metal affect the diffusion coefficient?", + "answer": "The greater the difference in properties between the diffusing element and the solvent metal, the larger the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释扩散系数与扩散元素和溶剂金属性质差异之间的关系，答案以文字论述形式给出，没有涉及计算或选择判断。 | 知识层次: 题目要求分析扩散元素与溶剂金属性质差异对扩散系数的影响，涉及概念关联和综合分析，需要理解扩散机制并应用相关原理进行解释，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解扩散系数与元素性质差异之间的关系，并进行综合分析和说明。题目要求解释性质差异对扩散系数的影响，涉及多步概念关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 674, + "question": "What is the effect of a third element on the diffusion of components in a binary alloy?", + "answer": "The third element that forms compounds with the components in the alloy hinders the diffusion of solute atoms, thereby reducing the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释第三元素对二元合金中组分扩散的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对第三元素在二元合金中扩散影响的分析，需要理解扩散机制、元素间相互作用以及扩散系数的变化，属于中等应用层次的知识。 | 难度: 在简答题中属于中等难度，需要理解第三元素对二元合金扩散的影响机制，并进行综合分析和说明。题目要求解释第三元素如何阻碍溶质原子的扩散，并降低扩散系数，这需要对扩散原理和合金成分相互作用有一定的理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 675, + "question": "Explain the effect of grain size on the mechanical properties of metal materials at room temperature", + "answer": "Room temperature strengthening. Fine grain strengthening can improve the strength and hardness of metal materials. The smaller the grain size, the more grain boundaries there are, and the greater the resistance to dislocation movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶粒尺寸对金属材料机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶粒尺寸对金属材料力学性能的影响，涉及晶界强化机制和位错运动的阻力等机理分析，需要综合运用材料科学中的多个概念并进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对晶粒尺寸影响金属材料力学性能的机理进行深度解释。需要综合运用材料科学知识，分析晶界与位错运动的相互作用机制，并建立晶粒尺寸与强度/硬度之间的定量关系（Hall-Petch关系）。虽然不涉及多因素交互作用的全面分析（等级5特征），但对单一机理的深入解释已超出基础理解层面，符合等级4的深度要求。" + }, + { + "idx": 676, + "question": "Explain the diffusion mechanism", + "answer": "The diffusion mechanisms mainly include: interstitial diffusion where solute atoms diffuse through interstices in interstitial solid solutions, and the vacancy mechanism where atoms exchange with vacancies to achieve diffusion in substitutional solid solutions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散机制，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目考查扩散机制的基本概念和分类，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释扩散机制，涉及两种主要扩散方式的描述（间隙扩散和空位扩散），属于概念解释和描述的难度等级。虽然需要记忆和解释基本原理，但不需要深入分析或构建复杂的概念体系，因此属于等级2。" + }, + { + "idx": 677, + "question": "Explain uphill diffusion", + "answer": "Uphill diffusion is a diffusion process where the diffusing element moves from a region of low concentration to a region of high concentration; examples include the formation of various solute atom atmospheres and the formation of eutectoid reaction products, both of which are uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释\"uphill diffusion\"的概念，并提供相关例子，这需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释uphill diffusion现象，需要理解扩散的基本原理并关联具体实例（如溶质原子氛围和共析反应产物的形成），涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求解释一个非直观的扩散现象（uphill diffusion），并需要提供具体实例来说明。这需要学生不仅理解基本扩散概念，还要能够关联到实际材料科学中的具体应用（如溶质原子氛围和共析反应产物的形成）。这种多角度分析和具体实例的论述要求，使得该题目在同题型中属于较高难度等级。" + }, + { + "idx": 678, + "question": "How does the effect of solute elements on the melting point of alloys influence the diffusion coefficient?", + "answer": "Solute elements that can lower the melting point of alloys (or cause a decrease in the liquidus line) will increase the diffusion coefficient; conversely, they will decrease the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释溶质元素对合金熔点的影响如何影响扩散系数，答案以文字解释和论述的形式给出，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释溶质元素对合金熔点的影响如何进一步影响扩散系数，这涉及多个概念的关联（熔点变化与扩散系数的关系）和机理解释（为什么熔点降低会增加扩散系数）。需要综合运用材料科学中的热力学和动力学知识，进行推理分析，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对溶质元素对合金熔点的影响与扩散系数之间的关系进行机理深度解释。需要综合运用材料科学中的相变理论和扩散理论，理解溶质元素如何通过改变熔点来影响原子迁移率，并能准确表述这种关系的物理机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述层面，属于需要深入机理解释的难度等级。" + }, + { + "idx": 679, + "question": "How to control the microstructure and properties of materials through deformation and heating?", + "answer": "Deformation can increase dislocation density, thereby enhancing material strength; heating can promote dislocation rearrangement and recrystallization, thereby refining grains and improving material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过变形和加热控制材料的微观结构和性能，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释变形和加热如何控制材料的微观结构和性能，涉及多个概念的关联（如位错密度、再结晶、晶粒细化等）和综合分析（变形和加热对材料性能的影响机制）。虽然不需要复杂的计算或创新设计，但需要理解并关联多个材料科学的基本原理，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对材料科学中的变形和加热对微观结构和性能的影响进行多角度分析论述。需要综合运用材料科学中的多个概念，如位错密度、晶粒细化、再结晶等，并进行关联性分析。虽然不需要进行深度关联性分析（等级5），但已经超出了简单的概念解释和说明（等级3），属于多角度分析论述的难度等级。" + }, + { + "idx": 681, + "question": "Explain the effect of grain size on the high-temperature mechanical properties of metallic materials", + "answer": "High-temperature weakening. Grain boundaries become weak points at high temperatures, excessively fine grains reduce high-temperature creep resistance, and appropriately coarsening grains is beneficial for high-temperature performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶粒尺寸对金属材料高温力学性能的影响，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求解释晶粒尺寸对金属材料高温力学性能的影响，涉及晶界在高温下的行为、晶粒尺寸与高温蠕变抗力的关系，以及晶粒适当粗化对高温性能的益处。这需要综合运用材料科学中的晶界理论、高温变形机制等知识，进行推理分析和机理解释，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对晶粒尺寸影响高温机械性能的机理进行深度解释，涉及晶界弱化、蠕变抗力等专业概念的综合运用。虽然未达到全面分析复杂现象的最高难度，但已明显超出基础概念描述层面，属于需要机理深度解释的中高难度题目。" + }, + { + "idx": 682, + "question": "How to control the grain size of materials in production", + "answer": "1. Use inoculation treatment or rapid cooling to refine grains during casting; 2. Control rolling process parameters to refine the microstructure during hot working; 3. Utilize alloy elements to pin grain boundaries and inhibit grain growth during recrystallization annealing; 4. Coordinate the relationship between cold deformation amount and heating temperature according to the recrystallization diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释如何控制材料生产中的晶粒尺寸，答案提供了多个步骤和方法的文字论述，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的多个知识点（如晶粒细化方法、热加工参数控制、合金元素作用、再结晶图等），并进行多步骤的分析和解释。虽然不涉及复杂的计算或创新设计，但需要对不同工艺条件下的晶粒尺寸控制方法有较深入的理解和关联应用。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度。题目要求从铸造、热加工、合金元素添加和冷变形与加热温度协调四个不同角度阐述控制晶粒尺寸的方法，需要考生综合运用材料加工和热处理知识，分析不同工艺阶段的控制要点。虽然不需要进行深度关联性分析（如不同方法之间的相互作用机制），但已明显超出单一角度说明的要求，属于需要系统整合多个知识点的中高难度简答题。" + }, + { + "idx": 683, + "question": "All symmetry elements present in macroscopic crystals must pass through the center of the crystal", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体对称元素基本概念的记忆和理解，属于基础概念记忆层次 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对\"宏观晶体对称元素必须通过晶体中心\"这一基础定义的记忆，无需复杂推理或概念延伸。属于晶体学中最基础的对称性知识，完全符合等级1对定义性知识直接判断的要求。" + }, + { + "idx": 684, + "question": "The symmetry characteristic of the cubic crystal system is having four 3-fold axes", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查立方晶系对称性特征的基础概念记忆，仅需判断陈述是否正确，不涉及复杂分析或应用。 | 难度: 在判断题中属于基本难度，仅需记忆立方晶系的对称性特征（四个3重轴）即可直接判断正误，不涉及概念理解或复杂陈述的分析。" + }, + { + "idx": 685, + "question": "The core of microscopic symmetry elements is the translation axis", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对微观对称元素核心概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在判断题中属于基本概念正误判断，仅需记忆微观对称元素的核心是平移轴这一基础概念即可作答，无需深入理解或分析。" + }, + { + "idx": 686, + "question": "Amorphous silicon prepared by CVD method also possesses the four general characteristics of glass", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（\"Amorphous silicon prepared by CVD method also possesses the four general characteristics of glass\"），并要求判断其正误（答案为×），这符合判断题的特征。题目没有提供多个选项，也不需要计算或文字解释，只需判断陈述的对错。 | 知识层次: 题目考查对非晶硅和玻璃基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该判断题属于基础概念正误判断，仅需记忆非晶硅和玻璃的基本特性即可作答，无需深入理解或复杂推理，在同题型内属于最简单的难度等级。" + }, + { + "idx": 687, + "question": "Summarize the applications of diffusion in materials science", + "answer": "The roles of atomic diffusion in materials include: nucleation and growth during crystal solidification; component undercooling in alloys; composition homogenization, retention of high-temperature microstructure characteristics during peritectic reaction non-equilibrium solidification, nucleation during solid-state phase transformation, grain boundary nucleation, grain boundary movement, grain boundary segregation, high-temperature creep, oxidation, welding, chemical heat treatment (such as carburization, nitriding, etc.), powder metallurgy, coating, and various other aspects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结扩散在材料科学中的应用，答案是一段详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求总结扩散在材料科学中的应用，涉及多个具体应用场景的列举和简要说明，需要理解扩散的基本原理并将其与不同材料科学领域的具体现象联系起来。虽然不涉及复杂的计算或深度分析，但需要对扩散在不同过程中的作用有较为全面的理解和综合应用能力。 | 难度: 在简答题题型中，该题目要求对扩散在材料科学中的应用进行多角度分析论述。需要考生不仅列举扩散的具体应用场景，还要理解这些应用背后的原理和相互关联。题目涉及的知识点较多，且需要综合分析扩散在不同材料过程中的作用，属于中等应用层次中较为复杂的题目。因此，在同题型内属于等级4的难度。" + }, + { + "idx": 688, + "question": "Order-disorder transformation refers to the transformation between crystals and non-crystals", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对\"有序-无序转变\"这一基本概念的定义记忆和理解，属于基础概念层面的判断题 | 难度: 在判断题的基础概念记忆层次中，该题目仅考察对\"有序-无序转变\"这一基本定义的理解，属于最基础的正误判断。题目陈述明确且单一，不需要复杂的分析或概念比较，完全符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 689, + "question": "A solid solution is an amorphous solid that has dissolved impurity components", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案给出的是×，表示错误），符合判断题的特征。 | 知识层次: 题目考查对固溶体（solid solution）基本定义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该判断题属于基础概念正误判断，仅需记忆固体溶液的定义即可判断陈述错误（固体溶液是晶体而非非晶态固体）。题目不涉及概念理解或复杂陈述，是最简单的判断题类型。" + }, + { + "idx": 690, + "question": "Most solid-phase reactions are controlled by diffusion rates", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（\"Most solid-phase reactions are controlled by diffusion rates\"），并要求判断其正误（答案给出的是\"×\"表示错误），这符合判断题的特征。 | 知识层次: 题目考查对固相反应控制机制这一基础概念的记忆和理解，属于基本原理的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，该题目属于中等难度。虽然涉及的是固态反应的基本原理（扩散控制），但需要学生理解\"大多数固态反应\"这一限定条件，并知道扩散速率确实是主要控制因素这一知识点。这比简单判断定义正误（等级1）要求更高，但尚未达到需要分析复杂概念陈述的等级3难度。" + }, + { + "idx": 691, + "question": "At low temperatures, the diffusion that generally occurs in crystals is intrinsic diffusion", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体中扩散类型的基础概念记忆，特别是低温条件下扩散类型的判断，属于定义和基本原理的记忆性知识。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆晶体在低温下的扩散类型即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 692, + "question": "In the wetting of solid-liquid interfaces, increasing the roughness of the solid surface necessarily improves wetting.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案以“×”表示错误，符合判断题的特征。 | 知识层次: 题目涉及固体-液体界面润湿的基本概念，但需要理解表面粗糙度对润湿性的影响，这需要将润湿理论与表面粗糙度的作用机制联系起来进行分析。虽然不涉及复杂的计算或深度推理，但需要综合理解润湿角、表面能等概念，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要综合分析固体表面粗糙度与润湿性之间的复杂关系。题目涉及界面科学中的多因素相互作用（如Wenzel和Cassie-Baxter状态），要求考生理解粗糙度并不总是改善润湿性（如超疏水表面的微纳结构）。这超出了简单概念判断（等级3），需要进行结果导向的综合分析。" + }, + { + "idx": 693, + "question": "Summarize the role of dislocations in materials", + "answer": "Dislocations can greatly influence the performance of materials, and their roles in materials are diverse: (1) The plastic deformation of metallic materials is accomplished through dislocation motion. (2) Dislocations have a distorted stress field around them, which can strengthen materials through mechanisms such as cutting or bypassing second-phase particles. Increasing dislocation density during cold working can also strengthen materials, as can the formation of Cottrell atmospheres. Additionally, mutual intersections during dislocation motion or the formation of jogs and Lomer-Cottrell locks can strengthen materials, thereby affecting their strength. (3) Dislocations influence the precipitation of second phases and have an impact on solid-state phase transformations such as nucleation mechanisms during recrystallization. (4) The areas around dislocations serve as preferential diffusion pathways.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结位错在材料中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对位错在材料中的多种作用进行综合论述，涉及塑性变形、强化机制、相变影响和扩散路径等多个方面，需要深入理解和分析位错与材料性能之间的复杂关系，属于综合运用和机理解释的层次。 | 难度: 在简答题题型中，该题目要求对位错在材料中的多重作用进行全面分析，涉及塑性变形、强化机制、相变影响和扩散路径等多个复杂现象的机理解释。需要综合运用材料科学知识进行深度推理和系统阐述，属于该题型内最高难度的复杂现象全面分析层级。" + }, + { + "idx": 694, + "question": "Sintering is a process that involves various physical and chemical changes", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Sintering is a process that involves various physical and chemical changes），并要求判断对错（答案给出×表示错误），符合判断题的特征。 | 知识层次: 题目考查对烧结过程的基本概念的理解，属于基础概念的记忆和识别，不涉及复杂的应用或分析。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆烧结过程的基本定义即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 695, + "question": "The collection of all symmetry elements in a crystal structure is called", + "answer": "The crystal structure with space group $\\bf{F m}3m$ belongs to the (2) crystal family and (3) crystal system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释或定义某个概念（\"The collection of all symmetry elements in a crystal structure is called\"），而答案提供了具体的空间群和晶体家族/系统的信息，属于文字解释和论述的形式。 | 知识层次: 题目考查对晶体结构对称元素集合的基本概念记忆，以及空间群与晶体家族、晶体系统分类的基础知识理解。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并准确回答晶体结构中所有对称元素的集合名称，不涉及复杂解释或体系阐述。" + }, + { + "idx": 696, + "question": "In the cubic crystal system, the possible types of space lattices are (a) P, I, C (b) P, I, F (c) P, C, F (d) F, I, C", + "answer": "The unit cell is (1)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，选项以(a)(b)(c)(d)形式给出，符合选择题的特征 | 知识层次: 题目考查立方晶系中可能的空间格子类型，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题中属于简单难度，仅需直接记忆立方晶系中可能的空间格子类型（P, I, F），无需进行复杂的概念辨析或深度理解。" + }, + { + "idx": 697, + "question": "Ionic crystals typically reduce their surface energy through the polarization deformation and rearrangement of surface ions. Among the following ionic crystals, the one with the smallest surface energy is (a) CaF2 (b) PbF2 (c) PbI2 (d) BaSO4 (e) SrSO4", + "answer": "The main reasons for clay charging are: (11) _, (12) _, and (13) _", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项（a-e）中选择具有最小表面能的离子晶体，符合选择题的特征。 | 知识层次: 题目要求考生理解离子晶体表面能的影响因素，并能够比较不同离子晶体的表面能大小。这需要考生掌握离子极化和离子重排的基本原理，并能够将这些概念应用到具体材料的选择中。虽然不涉及复杂的计算，但需要对多个概念进行关联和综合分析。 | 难度: 在选择题中属于较高难度，需要综合分析离子晶体的表面能影响因素，包括离子极化能力、离子半径、晶格结构等。题目要求比较不同离子晶体的表面能，涉及多个概念的关联和复杂判断过程，属于复杂分析过程的判断类型。" + }, + { + "idx": 698, + "question": "(a) Symmetry type (b) Point group (c) Collection of microscopic symmetry elements (d) Space group", + "answer": "When a small amount of $\\\\mathbf{CaO}$ is added to the $\\\\mathrm{Th}\\\\mathbf{O}_{2}$ lattice to form a solid solution, write the possible defect reaction equations and solid solution formulas: defect reaction equation (7) and corresponding solid solution formula (8). Defect reaction equation (9) and corresponding solid solution formula (10)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出缺陷反应方程和固溶体公式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求写出缺陷反应方程和相应的固溶体化学式，这需要理解缺陷化学的基本原理，并能够应用这些原理来分析具体的掺杂情况。虽然题目没有涉及复杂的计算或多步骤的推理，但需要将多个概念（如点缺陷、电荷平衡、化学计量等）关联起来，进行综合分析。因此，这属于中等应用层次。 | 难度: 在简答题题型中，该题目要求写出可能的缺陷反应方程和相应的固溶体化学式，这需要多角度分析论述。具体来说，题目涉及到了缺陷化学的知识，需要理解并应用缺陷反应的基本原理，同时考虑到不同掺杂情况下的可能反应。此外，还需要综合分析不同缺陷类型对固溶体化学式的影响，这增加了题目的复杂性和深度。因此，该题目在简答题题型中属于较高难度，需要多步计算、概念关联和综合分析能力。" + }, + { + "idx": 699, + "question": "In the face-centered cubic crystal structure, the close-packed plane is (a) {001} plane (b) {011} plane (c) {111} plane", + "answer": "The main reasons for clay charging are: (11) (12) and (13)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a）、（b）、（c）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查面心立方晶体结构中密排面的记忆，属于基础概念的记忆性知识 | 难度: 在选择题中属于中等偏下难度，需要理解面心立方晶体结构的基本概念，并能识别密排面。虽然涉及晶体学知识，但只需记忆常见的密排面{111}即可作答，无需复杂分析。" + }, + { + "idx": 700, + "question": "The four structural parameters $z$, $R$, $X$, and $Y$ of the $\\mathrm{Na}{2}\\mathrm{{\\bfO}}\\cdot\\mathrm{Ca}\\mathrm{{\\bfO}}\\cdot\\mathrm{Al}{2}\\mathrm{{\\bfO}}{3}\\cdot2\\mathrm{SiO}{2}$ glass", + "answer": "$,1.{\\surd};2.{\\surd};3.{\\searrow};4.\\times;5.\\times;6.\\times;7.{\\surd};8.\\times;9.\\times;10.\\times_{\\mathrm{~o~}}$ II. 1. b; 2. d; 3. a; 4. a; 5. c; 6. c; 7. (A) c、(B) a; 8. a、c; 9.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案形式为选项编号和对应的符号（如1.√; 2.√; 3.↘; 4.×等），符合选择题的特征。 | 知识层次: 题目考查对材料科学中玻璃结构参数的基本概念和分类的记忆，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解玻璃结构参数的基本概念，并进行简单的辨析和匹配。虽然题目涉及多个参数，但主要考察的是对基础知识的记忆和初步应用，不需要复杂的分析或深度理解。" + }, + { + "idx": 701, + "question": "In the thermodynamic relation of diffusion coefficient, $\\\\left(1+\\\\frac{\\\\partial{\\\\ln{\\\\gamma_{i}}}}{\\\\partial{\\\\ln{N_{i}}}}\\\\right)$ is called the thermodynamic factor of diffusion coefficient. In non-ideal mixing systems: when the thermodynamic factor of diffusion coefficient $>0$, the diffusion result causes the solute to (A); when the thermodynamic factor of diffusion coefficient $<0$, the diffusion result causes the solute to (B). (a) segregation occurs (b) concentration remains unchanged (c) concentration tends to be uniform", + "answer": "On the curve of glass properties changing with temperature, there are two characteristic temperatures (18) and (19), and the viscosities corresponding to these two characteristic temperatures are (20) and (21) respectively.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目提供了多个选项（A、B、C），并要求从中选择正确的答案来填空，符合选择题的特征。 | 知识层次: 题目考查对扩散系数热力学因子在不同条件下的应用理解，需要将热力学因子与扩散结果关联起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解非理想混合系统中扩散系数的热力学因子概念，并分析其正负值对溶质扩散结果的影响。题目涉及多个概念的关联和综合分析，要求考生具备较强的理论应用能力。" + }, + { + "idx": 702, + "question": "Network former", + "answer": "A substance with single bond energy $\\geq335\\mathrm{kJ/mol}$ that can form glass alone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Network former\"进行定义和解释，需要文字描述其特性（单键能量≥335kJ/mol并能单独形成玻璃），属于概念解释型的简答题。 | 知识层次: 题目考查对\"Network former\"这一基础概念的定义记忆和理解，属于材料科学中玻璃形成物质的基础知识范畴，不涉及应用或分析过程。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述网络形成体的定义和关键参数（单键能≥335kJ/mol），不需要额外的解释或复杂概念体系的阐述。" + }, + { + "idx": 703, + "question": "In the phase transformation of quartz, the one that belongs to reconstructive transformation is (a) $\\\\alpha\\\\cdot$ quartz $=====\\\\alpha\\\\cdot$ tridymite (b) $\\\\alpha\\\\cdot$ quartz $\\\\mathbf{\\\\mu}=====\\\\beta\\\\mathbf{\\\\sigma}$ quartz (c) $\\\\alpha\\\\cdot$ tridymite $=====\\\\alpha\\\\cdot$ quartz (d) $\\\\alpha\\\\cdot$-cristobalite $\\\\begin{array}{r}{======\\\\beta.}\\\\end{array}$ cristobalite", + "answer": "Intrinsic diffusion is the migration of particles caused by (22), and the activation energy of intrinsic diffusion consists of two parts: (23) and (24). The relationship between the diffusion coefficient and temperature is given by: (25).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对石英相变类型的基础概念记忆和理解，特别是重构型相变的识别，属于定义和分类层面的知识。 | 难度: 在选择题中属于中等偏下难度，需要理解石英相变的基本概念并区分重构型相变和位移型相变。题目提供了四个选项，考生需要识别哪种转变属于重构型相变，这需要对石英的相变类型有基本的理解和记忆。虽然涉及概念辨析，但不需要复杂的推理或深度分析。" + }, + { + "idx": 704, + "question": "First-order phase transition", + "answer": "During the phase transition, the chemical potentials of the two phases are equal, but the first-order partial derivatives of the chemical potential are not equal. A first-order phase transition involves latent heat and changes in volume.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“一级相变”进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对一级相变的基本概念和特征的理解和记忆，包括化学势的相等性、一级偏导数的不相等性以及涉及潜热和体积变化等基本原理。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释一级相变的基本特征，包括化学势的相等性、一级偏导数的不等性，以及涉及潜热和体积变化等关键概念。虽然需要记忆多个知识点，但不需要构建复杂的理论体系或进行深入推导，属于中等难度的概念性简答题目。" + }, + { + "idx": 705, + "question": "In the sintering process, the mass transfer method that only changes the pore shape without causing shrinkage of the green body is (a) surface diffusion (b) flow mass transfer (c) evaporation-condensation (d) grain boundary diffusion", + "answer": "Martensitic transformation has the following characteristics: (26), (27), (28), and (29)_, etc. IV. Term Explanation (15 points) (Choose five questions; if all are answered, only the first five will be graded) 1. Network former 2. First-order phase transition 3. Schottky defect 4. Polymorphism 5. Wetting 6. Homogeneous nucleation 7. Non-stoichiometric structural defects 8. Grain growth", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项（a, b, c, d）中选择一个正确的答案，符合选择题的特征。 | 知识层次: 题目考查烧结过程中物质传递方式的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解烧结过程中不同传质方式的特点，并能区分哪些方式会导致坯体收缩而哪些不会。虽然涉及多个概念，但只需进行简单的概念辨析即可选出正确答案。" + }, + { + "idx": 706, + "question": "Polymorphism", + "answer": "Substances with the same chemical composition can form crystals with different structures under different thermodynamic conditions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Polymorphism\"这一概念进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征 | 知识层次: 题目考查对多晶型现象的基本概念记忆和理解，属于定义性知识，不涉及应用或分析过程 | 难度: 在简答题题型中，该题目要求对多晶型现象进行概念解释和描述，需要理解并阐述物质在相同化学组成下因热力学条件不同而形成不同晶体结构的原理。这属于概念解释和描述的难度等级，比单纯的定义简答（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 707, + "question": "What are the characteristics of pore changes during secondary recrystallization", + "answer": "During secondary recrystallization, pores are encapsulated within the grains", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述二次再结晶过程中孔隙变化的特征，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目涉及对二次再结晶过程中孔隙变化的特征描述，需要理解再结晶的基本原理并能够关联孔隙与晶粒的关系，属于中等应用层次的知识点。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释二次再结晶过程中孔隙变化的特征，需要理解并描述孔隙被晶粒包裹的现象。虽然涉及一定的概念关联和综合分析，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 708, + "question": "Characteristics of grain growth", + "answer": "Grain growth is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution. Within the green body, grain sizes grow uniformly; during grain growth, pores remain at grain boundaries or grain boundary junctions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对晶粒生长的特性进行文字解释和论述，答案提供了详细的描述和定义，符合简答题的特征。 | 知识层次: 题目考查晶粒生长的基本概念和特征，属于定义和基本原理的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释晶粒生长的特征，涉及对基本概念的理解和描述，但不需要复杂的体系阐述或多步骤分析。答案涵盖了晶粒生长的定义、均匀性以及孔隙位置等关键点，属于对基础概念的扩展解释，符合等级2的要求。" + }, + { + "idx": 709, + "question": "Grain growth", + "answer": "is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Grain growth\"进行文字解释和论述，答案是一个完整的定义性陈述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即晶粒生长的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆性知识。题目明确要求解释\"Grain growth\"的定义，不需要额外的概念解释或复杂体系阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 711, + "question": "Wetting", + "answer": "When the Gibbs free energy of the system decreases after a solid comes into contact with a liquid, it is called wetting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“Wetting”进行定义和解释，答案以文字形式给出，属于简答题类型 | 知识层次: 题目考查对wetting这一基本概念的定义和Gibbs自由能变化的理解，属于基础概念的记忆和简单解释，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求复述wetting的基本定义，属于最基础的概念记忆层面。题目不涉及概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。与其他需要解释原理或描述特征的简答题相比，此题只需直接回忆单一概念定义，属于该题型内最基础难度。" + }, + { + "idx": 712, + "question": "What are the process characteristics of secondary recrystallization", + "answer": "It is an abnormal growth process where a few large grains grow at the expense of fine grains. It is the abnormal growth of individual grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释二次再结晶的过程特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对二次再结晶过程特性的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释和描述二次再结晶的过程特征，涉及对异常晶粒生长机制的理解，但不需要阐述复杂的理论体系或进行多概念比较。" + }, + { + "idx": 713, + "question": "Non-stoichiometric structural defects", + "answer": "The composition of certain compounds deviates from their stoichiometric ratio depending on the nature of the surrounding atmosphere and the magnitude of pressure. Such compounds are called non-stoichiometric compounds. The defects arising from the deviation in composition from the stoichiometric ratio are called non-stoichiometric structural defects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对非化学计量结构缺陷进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查非化学计量结构缺陷的基本定义和形成原因，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要解释非化学计量结构缺陷的定义和形成原因，但不需要涉及复杂的概念体系或深入的分析。题目主要考察对基础概念的记忆和理解，属于中等难度。" + }, + { + "idx": 714, + "question": "There are countless translational axes in the crystal structure", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体结构中平移轴的基本概念，属于基础概念的记忆和理解 | 难度: 在判断题的基础概念记忆层次中，此题仅需判断晶体结构中是否存在无数平移轴这一基本概念的正误，属于最基础的定义性知识判断，不需要深入理解或复杂推理。" + }, + { + "idx": 715, + "question": "Pauling's rules apply to all crystal structures", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Pauling's rules apply to all crystal structures），要求判断其正确性（答案为×表示错误），符合判断题的特征 | 知识层次: 题目考查对Pauling规则适用范围这一基础概念的记忆和理解，属于晶体结构领域的基本原理知识 | 难度: 在判断题中属于中等难度，需要理解Pauling规则的基本概念及其适用范围，而不仅仅是记忆定义。虽然不涉及复杂概念的判断，但需要对晶体结构理论有一定理解才能正确判断该陈述的错误性。" + }, + { + "idx": 716, + "question": "The ratio of the intercepts of a crystal plane on the three coordinate axes must be a simple integer ratio", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体平面在坐标轴上截距比的基本概念，属于基础概念的记忆和理解范畴。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆晶体平面截距比的基本定义即可作答，无需深入理解或复杂推理。" + }, + { + "idx": 717, + "question": "The two most closely packed arrangements of equal-sized spheres", + "answer": "There are mainly cubic closest packing and hexagonal closest packing; the cubic closest packing arrangement has the close-packed planes arranged in the sequence ABCABC..., while the hexagonal closest packing arrangement has the close-packed planes arranged in the sequence ABAB...", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种最紧密排列的等径球体排列方式，答案提供了详细的文字描述和比较，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对等径球体最紧密堆积方式的基本概念记忆，包括立方最紧密堆积和六方最紧密堆积的排列序列，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释两种最紧密堆积方式（立方最密堆积和六方最密堆积）及其排列序列，这需要学生对基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 718, + "question": "Types and quantitative relationship of voids", + "answer": "When equal-sized spheres are closely packed, the main types of voids are octahedral voids and tetrahedral voids. When $\\pmb{n}$ spheres are closely packed, there will be $\\textbf{\\em n}$ octahedral voids and $2n$ tetrahedral voids", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述空隙的类型和数量关系，答案提供了详细的文字解释和定量关系，符合简答题的特征。 | 知识层次: 题目考查对紧密堆积中空隙类型及其数量关系的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释紧密堆积中空隙的类型和数量关系，涉及基础概念的记忆和简单应用，但不需要复杂的体系阐述或多步骤推理。" + }, + { + "idx": 719, + "question": "The dislocation line of an edge dislocation is parallel to the slip direction.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断对错（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对刃型位错基本概念的记忆和理解，涉及位错线与滑移方向的关系，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆边缘位错的定义即可判断。题目直接考察边缘位错位错线与滑移方向的关系，属于最基础的定义性知识，无需复杂理解或分析。" + }, + { + "idx": 720, + "question": "Generally speaking, grain boundaries are the main diffusion channels for pores to reach the exterior of the sintered body.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶界作为烧结体中孔隙扩散主要通道这一基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，此题属于最基本的难度等级。题目直接考察对\"晶界是烧结体中孔隙扩散主要通道\"这一基础概念的记忆和正误判断，不需要额外的理解或分析步骤。属于单纯的定义性知识再现，符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 721, + "question": "What is the relationship between secondary recrystallization and the particle size of the raw material", + "answer": "Secondary recrystallization is also related to the particle size of the raw material", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释二次再结晶与原材料颗粒尺寸之间的关系，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及二次再结晶与原材料粒径之间的关系，需要理解两者之间的关联性并进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及了材料科学中的次级再结晶和原料颗粒尺寸的关系，但只需要进行概念关联和综合分析，而不需要多角度或深度关联性分析。解题步骤相对直接，主要考察对这两个概念之间关系的理解和简要论述。" + }, + { + "idx": 722, + "question": "Feldspar is a silicate crystal with a layered structure", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对长石（Feldspar）晶体结构的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 该判断题属于基础概念记忆层次，仅需判断\"长石是层状结构的硅酸盐晶体\"这一陈述的正误。题目直接考察对长石晶体结构这一基本概念的记忆，无需复杂推理或概念关联，在判断题中属于最简单的正误判断类型。" + }, + { + "idx": 723, + "question": "For some materials, no matter how fast the cooling rate is, it is impossible to form a glass", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（\"For some materials, no matter how fast the cooling rate is, it is impossible to form a glass\"），并要求判断其正误（答案给出的是×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对玻璃形成条件的基本概念的理解，属于基础概念记忆范畴，无需复杂分析或综合应用。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆材料科学中关于玻璃形成的基本原理即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 724, + "question": "The flow of clay slurry belongs to plastic flow", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The flow of clay slurry belongs to plastic flow），并要求判断其正确性（√），符合判断题的特征 | 知识层次: 题目考查对粘土浆流动性质的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆粘土浆的流动类型属于塑性流动这一基础概念即可作答，无需深入理解或分析。" + }, + { + "idx": 725, + "question": "The Jander equation has a wider applicable range than the Ginstling equation", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对Jander方程和Ginstling方程适用范围的基础概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在判断题中属于中等难度，需要理解Jander方程和Ginstling方程的基本概念及其适用范围，并进行比较判断。虽然不涉及复杂计算或推导，但需要对两个方程有基本的了解才能正确判断陈述的对错。" + }, + { + "idx": 726, + "question": "Non-stoichiometric structural defects are a type of impurity defect caused by doping", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对非化学计量结构缺陷类型的基本概念记忆和理解，属于基础概念层面的判断题 | 难度: 在判断题题型中，该题目属于概念理解的对错判断。题目考察的是对\"非化学计量结构缺陷\"这一专业概念的理解，需要学生能够区分杂质缺陷的不同类型及其成因。虽然不涉及复杂概念的判断，但比单纯的定义正误判断(等级1)要求更高，需要学生对材料缺陷分类有准确的理解。" + }, + { + "idx": 727, + "question": "At low temperatures, the diffusion that generally occurs in crystals is extrinsic diffusion", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查的是对晶体扩散类型的基础概念记忆，特别是低温条件下扩散类型的判断，属于定义和基本原理的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，该题目仅需判断\"低温下晶体中通常发生的扩散是外扩散\"这一基本定义的正确性，属于最基础的概念正误判断。不需要理解复杂概念或进行多步骤推理，完全符合等级1对基本概念记忆的要求。" + }, + { + "idx": 728, + "question": "Most solid-phase reactions are controlled by the diffusion rate.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对固相反应控制因素这一基本概念的记忆和理解，属于材料科学基础知识的范畴 | 难度: 在判断题中属于中等难度，需要理解\"固相反应\"和\"扩散速率控制\"这两个基本概念的关系，并判断其正确性。虽然不涉及复杂推理，但需要超越简单记忆的基础概念理解能力。" + }, + { + "idx": 729, + "question": "During the cooling process of the melt, the greater the degree of undercooling, the greater the overall crystallization rate", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对过冷度与结晶速率关系这一基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基本难度，仅需记忆并判断基础概念\"过冷度与结晶速率的关系\"这一简单陈述的正确性，无需理解复杂概念或进行多步骤分析。" + }, + { + "idx": 730, + "question": "A space lattice is formed by arranging in space with a regular repetition. (a) atoms (b) ions (c) geometric points (d) molecules", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)、(d)中选择一个正确答案 | 知识层次: 题目考查空间点阵的基本概念，要求从选项中识别出正确的定义（几何点的空间排列），属于基础概念的记忆和理解层面。 | 难度: 在选择题中属于简单难度，题目直接考察对空间点阵基本定义的记忆，只需识别几何点是构成空间点阵的基本单元，无需复杂辨析或深度理解。" + }, + { + "idx": 731, + "question": "In a narrow sense, the phase transition process is a physical change process", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对相变过程这一基础概念的记忆和理解，属于定义性知识的判断，不涉及复杂分析或综合应用。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆狭义相变过程的定义即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 733, + "question": "The crystal structure with point group $\\\\bf F m3m$ belongs to the crystal system. (a) cubic (b) hexagonal (c) tetragonal (d) orthorhombic", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体结构和点群分类的基础概念记忆，只需识别$F m3m$属于立方晶系即可，无需复杂分析或计算。 | 难度: 在选择题中属于简单难度，仅需识别点群符号$Fm3m$对应的晶系即可，属于直接记忆性知识，无需复杂辨析或深度理解。" + }, + { + "idx": 734, + "question": "In the $\\\\mathbf{ABO}_{3}$ (perovskite) type structure, B ions occupy (a) tetrahedral voids (b) octahedral voids (c) cubic voids (d) trigonal prismatic voids", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确的答案，符合选择题的特征。 | 知识层次: 题目考查对钙钛矿结构中离子占据空隙类型的基础概念记忆，属于定义性知识，无需复杂分析或计算。 | 难度: 在选择题中属于中等偏易难度，需要理解ABO3钙钛矿结构的基本组成和离子占据位置的概念，并进行简单辨析。虽然涉及晶体结构知识，但题目明确给出了结构类型，只需记忆B离子占据八面体空隙这一基本特征即可作答。" + }, + { + "idx": 735, + "question": "Montmorillonite belongs to which type of silicate structure. (a) Island silicate structure (b) Layered silicate structure (c) Chain silicate structure (d) Framework silicate structure", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择蒙脱石所属的硅酸盐结构类型，符合选择题的特征 | 知识层次: 题目考查对蒙脱石所属硅酸盐结构类型的基础概念记忆，属于分类知识的直接回忆 | 难度: 在选择题中属于中等偏下难度，需要理解蒙脱石的基本结构特征，并能够将其与不同类型的硅酸盐结构（如岛状、层状、链状、框架状）进行简单辨析。虽然涉及多个概念，但题目直接指向层状结构这一明确特征，不需要深度分析或复杂推理。" + }, + { + "idx": 736, + "question": "What property must the medium exhibit for slurry peptization? (a) Acidic (b) Alkaline (c) Neutral", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对浆料胶溶作用所需介质性质的基础概念记忆，仅需从给定选项中选择正确答案，不涉及复杂分析或应用。 | 难度: 在选择题中属于简单难度，仅需直接记忆基础概念（浆体胶溶所需的介质性质），无需理解或辨析复杂概念。" + }, + { + "idx": 737, + "question": "In the non-stoichiometric compound $\\\\operatorname{Cd}_{1+x}0$, the lattice defect present is (a) anion vacancy (b) cation vacancy (c) anion interstitial (d) cation interstitial", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（a-d）中选择关于非化学计量化合物Cd1+xO中存在的晶格缺陷类型的正确答案 | 知识层次: 题目考查非化学计量化合物中晶格缺陷类型的基本概念记忆，属于基础知识的直接应用，无需复杂分析或计算。 | 难度: 在选择题中属于中等难度，需要理解非化学计量化合物的缺陷类型，并进行简单辨析。虽然涉及基础概念记忆，但需要区分不同缺陷类型（如空位和间隙），属于概念理解和简单辨析的层次。" + }, + { + "idx": 738, + "question": "Which valence state of cations must be present in the exchange of originally adsorbed cations in clay for mud peptization? (d) Monovalent (e) Divalent (f) Trivalent", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项（d、e、f）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对粘土中阳离子交换和泥浆胶溶作用的基本概念记忆，只需知道单价比多价阳离子更有利于胶溶作用即可回答，不涉及复杂分析或应用。 | 难度: 在选择题中属于简单难度，仅需直接记忆粘土泥浆胶溶作用中最初吸附的阳离子交换所需的价态即可，无需理解或辨析其他概念。" + }, + { + "idx": 739, + "question": "The essence of crystals", + "answer": "is the periodic repetition of particles in three-dimensional space", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对晶体的本质进行文字解释和论述，答案是一个简短的陈述句，符合简答题的特征 | 知识层次: 题目考查晶体本质的基本概念记忆，即周期性重复排列的定义，属于基础概念记忆层次 | 难度: 该题目属于简答题中的基本定义简答，仅要求学生对晶体的本质进行简单的定义性回答，即\"粒子在三维空间中的周期性重复\"。这属于最基础的概念记忆，不需要额外的解释或复杂的概念体系阐述，符合等级1的难度标准。" + }, + { + "idx": 740, + "question": "What are the two types of arrangements in the closest packing of equal-sized spheres?", + "answer": "(2) Cubic close packing; (3) Hexagonal close packing", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两种最密堆积方式，需要文字回答而非选择或判断，且不涉及计算过程 | 知识层次: 题目考查对等径球体最密堆积两种排列方式的基础概念记忆，属于定义和分类层面的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答两种最密堆积方式的名称，不涉及概念解释或复杂体系阐述，属于最基础的概念记忆性知识。" + }, + { + "idx": 741, + "question": "In the closest packing of equal-sized spheres, what is the packing arrangement of cubic close packing?", + "answer": "(4) ABCABC……", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项编号形式给出 | 知识层次: 题目考查对立方紧密堆积（cubic close packing）排列方式的基础概念记忆，只需要记住ABCABC...的排列顺序即可回答，不涉及复杂计算或分析。 | 难度: 在选择题中属于简单难度，题目直接考察对立方密堆积排列方式的基础记忆（ABCABC...），不需要任何概念辨析或复杂理解，只需识别正确选项即可。" + }, + { + "idx": 742, + "question": "Ionic crystals usually reduce their surface energy through the polarization deformation and rearrangement of surface ions. Among the following ionic crystals, the one with the smallest surface energy is (a) $\\\\mathrm{CaF}{2}$ (b) $\\\\mathrm{Pb}\\\\mathrm{F}{2}$ c) $\\\\mathrm{Pb}\\\\mathbf{I}{2}$ (d) $\\\\mathbf{BaSO{4}}$ (e) SrsO4", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目要求考生理解离子晶体表面能的概念，并能够分析不同离子晶体的极化变形和离子重排对表面能的影响。这需要考生综合运用离子键性质、极化效应和晶体结构的知识，进行多步分析和比较，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析离子晶体的表面能影响因素，包括离子极化能力、离子半径、晶格结构等，并进行多步比较判断。题目涉及多个概念的综合应用，且需要深入理解离子晶体的表面能机制，属于复杂分析过程的判断。" + }, + { + "idx": 743, + "question": "In the closest packing of equal large spheres, what is the packing arrangement of hexagonal close packing?", + "answer": "(5) ABAB……", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案形式为选项编号加具体内容，符合选择题的特征 | 知识层次: 题目考查对六方最密堆积（hexagonal close packing）排列方式的基础概念记忆，属于对基本原理的记忆性知识。 | 难度: 在选择题中属于简单难度，题目仅考察对六方最密堆积（hexagonal close packing）排列方式的直接记忆，即ABAB……的层序排列。无需理解或辨析其他堆积方式，属于基础概念的直接识别。" + }, + { + "idx": 744, + "question": "The basis for classifying silicate crystals is (6)", + "answer": "[ $\\mathrm{Si}0{4}$ connection method", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释硅酸盐晶体分类的基础，需要文字描述硅氧四面体的连接方式，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对硅酸盐晶体分类基础的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答硅酸盐晶体分类的基础依据，即硅氧四面体的连接方式。这属于基础概念记忆层次中最简单的定义简答，无需深入解释或复杂论述，仅需准确回忆并写出关键术语即可。" + }, + { + "idx": 745, + "question": "In the face-centered cubic crystal structure, the close-packed plane is (7)", + "answer": "{111} plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的晶体学平面，需要专业知识但不需要计算或选择，答案形式为特定术语 | 知识层次: 题目考查面心立方晶体结构中密排面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆面心立方晶体结构中最密排面的晶面指数{111} plane，无需解释或复杂推导，属于最基础的概念记忆性知识。" + }, + { + "idx": 746, + "question": "After the interaction between water and clay, what can be formed around the clay colloidal particles as the distance increases: (8) what?", + "answer": "Firmly bound water", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述答案，答案是一个具体的术语（Firmly bound water），而不是从多个选项中选择或判断对错，也不需要计算。 | 知识层次: 题目考查粘土胶体颗粒周围水分子分布的基本概念，主要需要记忆和理解\"firmly bound water\"这一专业术语及其在材料科学中的定义，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目涉及基础概念记忆，但需要学生理解并描述\"Firmly bound water\"这一特定概念的形成过程及其与粘土胶体颗粒的关系，比单纯记忆定义(等级1)要求更高，但不需要进行复杂概念体系阐述(等级3)。" + }, + { + "idx": 747, + "question": "What is one of the main factors that determines the concentration of component defects?", + "answer": "Doping amount", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述一个主要因素，答案\"Doping amount\"是一个简短的文字回答，没有涉及选项选择、判断对错或数值计算 | 知识层次: 题目考查的是对掺杂量（doping amount）这一基本概念的记忆和理解，属于材料科学中缺陷浓度控制的基础知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答\"掺杂量\"这一基本定义，不需要进行概念解释或复杂体系阐述。属于最基础的定义简答级别，完全符合等级1\"基本定义简答\"的标准。题目仅测试学生对基础概念的记忆程度，不涉及任何解释性或分析性要求。" + }, + { + "idx": 748, + "question": "What are the two main factors that determine the concentration of component defects?", + "answer": "Solid solubility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释两个主要因素，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查的是对固体溶解度这一基本概念的记忆和理解，属于材料科学中缺陷浓度的基础概念。 | 难度: 在简答题题型中，该题目仅要求回答两个主要因素（Solid solubility），属于基本定义简答，不需要深入解释或复杂概念阐述。题目仅测试对基础概念的简单记忆，符合等级1的难度标准。" + }, + { + "idx": 749, + "question": "On the curve of glass properties changing with temperature, what is the first characteristic temperature?", + "answer": "Tg", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的术语(Tg)，不需要计算或选择，也不需要判断对错，符合简答题的特征 | 知识层次: 题目考查对玻璃特性温度曲线中第一个特征温度Tg的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答玻璃性能随温度变化的第一个特征温度（Tg），属于最基础的定义性知识。不需要解释或描述概念，更不需要复杂的概念体系阐述，完全符合等级1\"基本定义简答\"的标准。这是该题型下最简单的一类问题，只需记忆单一专业术语即可作答。" + }, + { + "idx": 750, + "question": "In the ${\\\\bf R O}\\\\mathrm{-SiO}{2}$ system, the order of the size of the immiscibility regions for: (1) $\\\\mathbf{Mg0-SiO}{2}$; (2) $\\\\mathbf{CaO}\\\\mathbf{-SiO}{2}$; (3) $\\\\mathbf{SrO}\\\\mathbf{-SiO}{2}$; (4) BaO$\\\\mathrm{SiO}_{2}$ is (a)$\\\\left(1\\\\right)>\\\\left(2\\\\right)>\\\\left(3\\\\right)>\\\\left(4\\\\right)$(b)(4)>(3)>(2)>(1)(c)$\\\\left(2\\\\right)>\\\\left(1\\\\right)>\\\\left(3\\\\right)>\\\\left(4\\\\right)$ (d $)(3)>(4)>(2)>(1)$", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择正确的顺序排列，符合选择题的特征 | 知识层次: 题目要求对不同氧化物-SiO2系统中的不混溶区域大小进行排序，需要理解离子半径对不混溶区域的影响，并综合分析多个系统的比较。这涉及到多步概念关联和综合分析，超出了简单记忆或基础概念的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于较高难度，需要综合分析多个因素。题目涉及RO-SiO2系统中不同氧化物的不混溶区域大小排序，要求考生掌握碱土金属氧化物（MgO、CaO、SrO、BaO）与SiO2相互作用的基本规律，并能将这些规律应用到具体系统中进行比较判断。解题过程需要理解离子半径对不混溶区域的影响，并能够将这些概念关联起来进行排序分析。虽然不涉及复杂计算，但需要较强的概念关联和综合分析能力。" + }, + { + "idx": 751, + "question": "On the curve of glass properties changing with temperature, what is the second characteristic temperature?", + "answer": "Tr", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的术语（Tr），不需要计算或选择，属于需要简短文字回答的简答题类型 | 知识层次: 题目考查对玻璃特性温度曲线中第二个特征温度（Tr）的基本概念记忆，属于定义性知识的直接回忆，不需要复杂的应用或分析。 | 难度: 在简答题-基础概念记忆题型中，此题仅要求回答玻璃特性温度曲线中的第二个特征温度的名称(Tr)，属于最基本定义层面的简答。不需要解释概念或描述变化规律，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要解释特征温度物理意义（等级2）或分析整条曲线变化机理（等级3）的题目简单得多。" + }, + { + "idx": 752, + "question": "As a result of what reason, 'compositional defects' are inevitably produced in the crystal structure?", + "answer": "Doping of non-equivalent ions", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案\"Doping of non-equivalent ions\"是一个具体选项，符合选择题的特征 | 知识层次: 题目考查对晶体结构中\"compositional defects\"产生原因的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题中属于中等偏下难度，需要理解\"compositional defects\"的基本概念以及非等价离子掺杂的影响，但不需要复杂的辨析或深度理解多个相关概念。" + }, + { + "idx": 753, + "question": "Methods to prevent secondary recrystallization", + "answer": "Methods to prevent secondary recrystallization: control sintering temperature, sintering time, control the uniformity of raw material particle size, and introduce sintering additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举防止二次再结晶的方法，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目要求列举防止二次再结晶的方法，涉及对烧结温度、时间、原料颗粒均匀性和烧结添加剂等多个因素的综合考虑，需要将多个概念关联起来进行分析和应用，但不需要进行复杂的机理解释或创新设计。 | 难度: 在简答题中属于中等难度，需要综合分析和说明多个防止二次再结晶的方法。题目要求考生理解并关联烧结温度、时间、原料粒径均匀性和烧结添加剂等概念，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 754, + "question": "After the interaction between water and clay, what can be found around the clay colloidal particles as the distance increases: (10) what?", + "answer": "Free water", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述，答案是一个简短的描述性回答（Free water），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查的是对粘土胶体颗粒与水相互作用后周围环境变化的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需回忆并写出\"Free water\"这一基础概念即可，无需进一步解释或论述。题目直接询问水与黏土相互作用后黏土胶体颗粒周围随着距离增加会出现什么，答案明确且单一，属于最基础的概念记忆层次。" + }, + { + "idx": 755, + "question": "After water interacts with clay, what can be found around the clay colloidal particles as the distance increases: (9) what?", + "answer": "Loosely bound water", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述\"what can be found around the clay colloidal particles as the distance increases\"，答案\"Loosely bound water\"是一个简短的文字回答，不需要计算或选择选项。 | 知识层次: 题目考查的是对粘土胶体颗粒周围水分子分布的基本概念记忆，属于基础概念的理解和记忆范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答\"Loosely bound water\"这一基本定义，属于最基础的概念记忆层次。题目没有要求解释或描述现象，也不需要阐述复杂的概念体系，完全符合等级1\"基本定义简答\"的标准。在同类型简答题中，这是最基础、最简单的难度级别。" + }, + { + "idx": 756, + "question": "Briefly describe the characteristics of grain growth", + "answer": "Characteristics of grain growth: Grain growth is a process during heat treatment of a strain-free material where the average grain size continuously increases without altering its distribution. Within the bulk, grain sizes grow uniformly; during grain growth, pores remain at grain boundaries or their junctions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述晶粒生长的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对晶粒生长特性的基本概念记忆和理解，不涉及复杂分析或综合应用 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述晶粒生长的特征，涉及对基本概念的理解和关键特征的列举，但不需要深入分析或构建复杂的概念体系。回答需要包含晶粒生长的定义、平均晶粒尺寸变化规律以及孔隙位置等基本特征，属于中等难度的概念解释类简答题。" + }, + { + "idx": 757, + "question": "Causes of secondary recrystallization", + "answer": "Causes of secondary recrystallization: uneven particle size of raw materials, excessively high sintering temperature, and too fast sintering rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释二次再结晶的原因，答案以文字解释的形式给出，没有选项、判断或计算要求 | 知识层次: 题目考查对二次再结晶原因的基本概念记忆和理解，涉及简单的分类和基本原理，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释二次再结晶的原因，涉及多个因素（原料颗粒大小不均、烧结温度过高、烧结速率过快）的列举和简要说明，但不需要深入分析各因素之间的相互作用或复杂机理。相比等级1的基本定义简答，需要更多的知识点记忆和简单关联；相比等级3的复杂概念体系阐述，则缺乏对原理的深度剖析或系统性论述。" + }, + { + "idx": 758, + "question": "Briefly describe the characteristics of secondary recrystallization", + "answer": "Characteristics of secondary recrystallization: it is an abnormal growth process where a few large grains grow at the expense of fine grains. It involves the abnormal growth of individual grains; during secondary recrystallization, pores are enclosed within the grains; secondary recrystallization is also related to the particle size of the raw material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述二次再结晶的特征，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目考查对二次再结晶特性的基本概念记忆和理解，涉及定义和简单特征描述，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求对二次再结晶的特征进行描述，涉及多个关键点的解释（异常生长过程、大晶粒消耗小晶粒、孔隙被晶粒包裹、与原料粒径的关系）。虽然不需要构建复杂的概念体系，但已经超出了简单定义回答的范畴，属于需要整合和解释的概念描述层级。" + }, + { + "idx": 759, + "question": "What is intrinsic diffusion?", + "answer": "Intrinsic diffusion: refers to the migration phenomenon caused by vacancies originating from the intrinsic thermal defects of the crystal. The activation energy of intrinsic diffusion consists of two parts: the vacancy formation energy and the particle migration energy. At high temperatures, intrinsic diffusion predominates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"intrinsic diffusion\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查基本概念的记忆和理解，即intrinsic diffusion的定义及其组成部分，属于基础概念记忆性知识。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释\"intrinsic diffusion\"的定义，并简要说明其组成和温度影响。虽然需要记忆和理解基本概念，但不需要阐述复杂的概念体系或进行深入分析。属于中等难度的概念解释题。" + }, + { + "idx": 760, + "question": "In the orthorhombic crystal system, the (001) plane must be perpendicular to the (110) plane", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征。不需要计算或解释，只需判断对错。 | 知识层次: 题目考查对正交晶系中晶面垂直关系的基础概念记忆和理解，不需要复杂的计算或分析。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然考查的是正交晶系的基本概念，但需要理解(001)和(110)晶面的空间关系，比单纯记忆定义稍复杂，但不需要进行复杂的推导或分析。" + }, + { + "idx": 761, + "question": "What is extrinsic diffusion?", + "answer": "Extrinsic diffusion: It is a migration phenomenon caused by vacancies generated from the doping of inequivalent impurity ions. The activation energy of extrinsic diffusion only includes the migration energy of mass points, and extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"extrinsic diffusion\"的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对\"extrinsic diffusion\"这一基本概念的定义和特征的理解和记忆，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释和描述\"extrinsic diffusion\"的概念，包括其产生原因、激活能量的组成以及在低温下的主导性。这属于概念解释和描述的层次，需要学生对相关概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入的分析。因此，在简答题题型内属于中等难度（等级2）。" + }, + { + "idx": 762, + "question": "What are the characteristics of extrinsic diffusion?", + "answer": "The activation energy of extrinsic diffusion only includes the energy of particle migration, and extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释外扩散的特征，答案提供了文字解释和论述，符合简答题的特点 | 知识层次: 题目考查的是对\"外扩散\"这一基本概念的特征记忆和理解，主要涉及定义和基本原理的阐述，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目要求解释外扩散的特征，涉及对基本概念的理解和描述，但不需要复杂的体系阐述或深入分析。属于概念解释和描述的难度级别。" + }, + { + "idx": 763, + "question": "In macroscopic crystals, the symmetry elements present must all pass through the center of the crystal", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断对错（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体对称性基本原理的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于判断题中的基础概念正误判断，仅需记忆晶体对称元素的基本定义即可作答，无需深入理解或复杂推理，在同题型内属于最简单级别。" + }, + { + "idx": 764, + "question": "What are the similarities between solid-phase sintering and liquid-phase sintering?", + "answer": "The driving force for sintering is surface energy in both cases, and the sintering process consists of stages such as particle rearrangement, pore filling, and grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种烧结过程的相似之处，答案以文字论述形式呈现，需要详细说明表面能驱动和烧结阶段等概念，符合简答题的特征。 | 知识层次: 题目要求比较两种烧结过程的相似性，涉及对烧结驱动力和烧结阶段的理解和关联，需要综合分析多个概念并进行比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求对固相烧结和液相烧结的相似性进行综合分析，但答案要点相对明确（驱动力和烧结阶段），不需要多角度或深度关联性分析。学生只需理解两种烧结方式的基本原理并找出共性即可回答，不需要进行复杂的推导或跨领域知识整合。" + }, + { + "idx": 765, + "question": "What are the characteristics of intrinsic diffusion?", + "answer": "The activation energy of intrinsic diffusion consists of two parts: vacancy formation energy and particle migration energy, and intrinsic diffusion dominates at high temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释intrinsic diffusion的特征，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算 | 知识层次: 题目考查对固有扩散（intrinsic diffusion）基本特征的理解和记忆，包括其激活能的组成部分以及在高温下的主导作用。这属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释本征扩散的特征，涉及激活能的组成部分（空位形成能和粒子迁移能）以及温度影响，这需要学生对基础概念有一定的理解和记忆，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 766, + "question": "Diamond, graphite, and carbon nanotubes are allotropes of carbon", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Diamond, graphite, and carbon nanotubes are allotropes of carbon），并要求判断其正确性（√），这是典型的判断题特征 | 知识层次: 题目考查对碳的同素异形体的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在判断题的基础概念记忆层次中，该题目仅要求识别碳的三种同素异形体（金刚石、石墨和碳纳米管）这一基本定义，属于最基础的正误判断，无需深入理解或复杂推理。" + }, + { + "idx": 767, + "question": "What are the differences between solid-phase sintering and liquid-phase sintering?", + "answer": "Due to the faster mass transfer rate by flow compared to diffusion, liquid-phase sintering has a higher densification rate and requires a lower sintering temperature. Additionally, the rate of the liquid-phase sintering process is also related to factors such as the amount of liquid phase, its properties (viscosity, surface tension, etc.), the wetting condition between the liquid and solid phases, and the solubility of the solid phase in the liquid phase. The factors influencing liquid-phase sintering are more complex than those in solid-phase sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述固相烧结和液相烧结之间的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较固相烧结和液相烧结的差异，涉及对两种烧结过程的理解和对比分析，需要综合考虑质量传输速率、烧结温度、液相性质等多个因素，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目要求对固相烧结和液相烧结进行多角度分析论述，涉及质量传输速率、致密化速率、烧结温度、液相性质（粘度、表面张力等）、润湿条件以及固相在液相中的溶解度等多个因素的综合考量。虽然不需要进行深度关联性分析（如跨学科知识整合），但需要考生对多个相关概念有较深入的理解，并能系统地比较和阐述这些因素对烧结过程的影响，因此属于该题型内较高难度的题目。" + }, + { + "idx": 771, + "question": "As long as the temperature is above 0K, point defects always exist in crystals", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体中点缺陷存在条件的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察晶体中点缺陷存在的基本原理（温度高于0K时必然存在点缺陷），属于定义性知识的记忆层面，不需要复杂的理解或推理过程。在判断题的基础概念记忆类别中，这是最基础级别的难度。" + }, + { + "idx": 772, + "question": "Fick's first law is applicable to solving unstable diffusion problems", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为×表示错误），符合判断题的特征 | 知识层次: 题目考查对Fick第一定律适用范围的记忆和理解，属于基础概念的记忆性知识 | 难度: 在判断题中属于基本概念正误判断，仅需记忆Fick第一定律的适用条件即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 773, + "question": "In the cubic crystal system, the possible types of space lattices are F, I, and C", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（立方晶系中可能的空间点阵类型为F、I和C），并要求判断其正误（答案为×），这符合判断题的特征。 | 知识层次: 题目考查立方晶系中空间点阵类型的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆类型中，此题仅需记忆立方晶系中可能的空间格子类型（F、I、P），题目故意遗漏P型并添加不存在的C型作为干扰。属于最基础的定义性知识正误判断，无需推导或复杂概念理解，符合等级1的单纯记忆性考查特征。" + }, + { + "idx": 775, + "question": "The critical radius of the nucleus $r_{k}$ decreases with increasing $\\Delta T$, making the phase transition easier to proceed.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（The critical radius of the nucleus $r_{k}$ decreases with increasing $\\Delta T$, making the phase transition easier to proceed），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查对临界核半径与过冷度关系的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解临界半径与过冷度ΔT的关系这一基本概念，并判断其变化趋势的正确性。虽然不涉及复杂推导，但需要对相变基础理论有清晰记忆。" + }, + { + "idx": 777, + "question": "Briefly describe the conditions for forming continuous substitutional solid solutions", + "answer": "The conditions for forming continuous substitutional solid solutions are: ionic size factor, the radius difference between the two substituting ions (r1-r2)/r1<15%; the two components must have exactly the same crystal structure type; continuous substitutional solid solutions can only form when the ionic valences are the same or when the total valence of composite substituting ions is equal; similar electronegativity and polarization properties", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述形成连续置换固溶体的条件，答案以文字解释和论述的形式给出，符合简答题的特征 | 知识层次: 题目考查对形成连续置换固溶体条件的基本概念记忆和理解，包括离子尺寸因素、晶体结构类型、离子价态和电负性等基本原理，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述形成连续置换固溶体的条件，涉及多个关键因素（离子尺寸、晶体结构、离子价态、电负性和极化性质），但不需要深入分析或复杂推导。虽然知识点较多，但都属于基础概念记忆层次，且答案结构清晰，属于该题型中的中等难度。" + }, + { + "idx": 778, + "question": "During the growth of crystals, there must be the presence of undercooling", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（During the growth of crystals, there must be the presence of undercooling），并要求判断其正误（答案给出×表示错误），这符合判断题的特征。 | 知识层次: 题目考查晶体生长过程中过冷现象的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆题型中，此题仅需判断\"晶体生长必须存在过冷度\"这一基本概念的正误，属于最基础的定义性知识判断，不需要理解复杂概念或进行多步骤分析。" + }, + { + "idx": 779, + "question": "For the same system, the nucleation barrier for heterogeneous nucleation ≤ the nucleation barrier for homogeneous nucleation.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对均相成核和非均相成核基本概念的理解，特别是成核能垒的比较，属于基础概念的记忆和简单理解范畴。 | 难度: 该题目属于判断题中最基础的难度等级，仅需记忆并判断\"异质形核能垒≤均质形核能垒\"这一基本概念的正确性，不涉及概念理解或复杂分析。在判断题题型内，这是最直接的概念正误判断类型。" + }, + { + "idx": 780, + "question": "Liquid phase sintering refers to a sintering process in which a liquid phase is present.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用×表示错误），这是典型的判断题特征 | 知识层次: 题目考查对液相烧结基本定义的记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目仅涉及\"液相烧结\"这一基础概念的定义，不需要深入理解或分析多个概念，只需记忆该定义的正确性即可。属于该题型下最基础的难度等级。" + }, + { + "idx": 781, + "question": "1. Network former", + "answer": "Network former: substances with single bond energy ≥335kJ/mol that can form glass independently.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Network former\"进行定义和解释，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对\"Network former\"这一基本概念的定义和分类的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答，仅要求准确记忆并复述\"Network former\"的定义，不涉及概念解释或复杂体系阐述。题目仅考察单一概念的记忆能力，属于该题型下最基础的难度等级。" + }, + { + "idx": 782, + "question": "2. First-order phase transition", + "answer": "First-order phase transition: During the phase transition, the chemical potentials of the two phases are equal, but the first-order partial derivatives of the chemical potential are not equal. A first-order phase transition involves latent heat and volume changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"First-order phase transition\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对一级相变的基本定义和特征的理解和记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目要求解释和描述一级相变的基本概念，包括化学势的相等性、一级偏导数的不等性以及涉及潜热和体积变化的特点。这属于概念解释和描述的难度等级，需要学生对相关概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。" + }, + { + "idx": 783, + "question": "3. Schottky defect", + "answer": "Schottky defect: When the lattice undergoes thermal vibration, some atoms with sufficient energy leave their equilibrium positions, migrate to the surface of the crystal, and leave vacancies at the original normal lattice sites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对Schottky defect进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查Schottky defect的基本定义和形成过程，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对Schottky defect进行基本定义简答，属于最基础的概念记忆层次。题目不涉及复杂解释或体系阐述，仅需回忆并复述定义内容即可，符合等级1的难度标准。" + }, + { + "idx": 784, + "question": "6.Polymorphism", + "answer": "Polymorphism: Substances with the same chemical composition can form crystals with different structures under different thermodynamic conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Polymorphism\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查对多晶型现象（Polymorphism）这一基础概念的定义和基本理解，属于材料科学中晶体结构的基础知识，主要依赖记忆和简单理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，此题仅要求回答多晶型的基本定义，属于最基础的概念记忆层面。不需要解释不同晶型之间的关系或形成条件等更深层次的内容，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 785, + "question": "4.Secondary recrystallization", + "answer": "Secondary recrystallization: is an abnormal growth process where a few large grains grow at the expense of fine grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Secondary recrystallization\"进行解释，答案是一个文字论述的定义，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶这一基础概念的定义和基本特征的理解和记忆，属于材料科学中的基础概念层次。 | 难度: 在简答题题型中，该题目仅要求对\"二次再结晶\"进行基本定义回答，属于最基础的概念记忆层面。题目不涉及概念间的关联性分析或复杂机制阐述，仅需复述教材中的核心定义即可完成作答，符合等级1\"基本定义简答\"的典型特征。" + }, + { + "idx": 786, + "question": "5. Inverse spinel structure", + "answer": "Inverse spinel structure: It belongs to the cubic crystal system, where oxygen ions can be considered as arranged in a cubic close packing. Divalent cation A fills the octahedral voids, while trivalent cation B fills half of the octahedral voids and half of the tetrahedral voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Inverse spinel structure\"进行文字解释和论述，答案提供了详细的晶体结构描述，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对反尖晶石结构的基本定义和组成排列的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释逆尖晶石结构的晶体系统、氧离子排列方式以及阳离子填充情况，但整体上仍属于对基础概念的记忆和简单描述，不需要复杂的推导或深入分析。相比等级1的基本定义简答，该题目需要更多的细节描述，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 787, + "question": "7. Lattice points", + "answer": "Space lattice: A series of equivalent points identified in the crystal structure must be arranged in a periodic repetition in three-dimensional space. A series of geometric points arranged in a periodic repetition in three-dimensional space is called a space lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“space lattice”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查空间点阵的基本定义和周期性排列的概念，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目仅要求对\"space lattice\"这一基础概念进行定义和简单描述，属于最基本的知识点记忆。题目不涉及概念间的联系或复杂体系阐述，仅需直接复述教材定义即可完成作答，符合等级1\"基本定义简答\"的特征。相比需要解释多个相关概念（等级2）或阐述完整理论体系（等级3）的简答题，此题的认知负荷和作答要求都最为基础。" + }, + { + "idx": 788, + "question": "8.Sintering", + "answer": "Sintering: A process in which one or more solid powders are formed and then heated to a certain temperature, causing them to shrink and become a dense, hard sintered body below the melting point temperature. Alternatively: Due to the mutual attraction of molecules (or atoms) in solids, heating causes the powder particles to bond, and through material migration and diffusion, the powder gains strength, leading to densification and recrystallization—this process is called sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Sintering\"这一概念进行详细的文字解释和论述，而不是从选项中选择、判断对错或进行数值计算。答案提供了关于烧结过程的详细描述，符合简答题的特征。 | 知识层次: 题目考查烧结过程的基本定义和原理，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释和描述烧结过程的基本原理和定义，但不需要涉及复杂的概念体系或深入的论述。题目要求对烧结过程进行较为详细的描述，包括加热、收缩、致密化等关键步骤，但并未要求对不同类型的烧结或高级理论进行阐述。" + }, + { + "idx": 789, + "question": "4. Briefly describe the characteristics of diffusionless phase transformation.", + "answer": "Characteristics of diffusionless phase transformation: shape change caused by uniform shear (change in crystal morphology); the new phase has the same chemical composition as the parent phase; it can occur at low temperatures with a fast transformation rate; there is a certain orientation relationship between the new phase and the parent phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述扩散无相变的特征，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查扩散无相变的基本特征，属于对基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述扩散无相变的特征，涉及多个关键点（如形状变化、化学成分一致性、低温快速转变、取向关系等），但不需要深入阐述或构建复杂概念体系。这符合等级2对知识点掌握深度和解题步骤的要求，属于中等偏基础的难度水平。" + }, + { + "idx": 790, + "question": "In a simple cubic crystal, if the direction of the dislocation line is [001] and $b=a$ [110], determine what type of dislocation this belongs to.", + "answer": "nan", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错的类型，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目要求根据给定的晶体结构和位错方向判断位错类型，需要理解位错的基本概念（如柏氏矢量和位错线方向）以及它们之间的关系。这涉及到多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解位错线方向与伯格斯矢量的关系，并进行综合分析。题目要求确定位错类型，涉及晶体学方向指数的理解和位错分类的知识，但不需要多角度或深度关联性分析。" + }, + { + "idx": 791, + "question": "2. The concentration of structural defects in non-stoichiometric compounds is related to the nature and pressure of the surrounding atmosphere. Analyze how the density of the non-stoichiometric compounds Fe1-xO and Zn1+xO will change if the partial pressure of the surrounding oxygen atmosphere is increased.", + "answer": "If the partial pressure of the surrounding oxygen atmosphere is increased, the value of x in the non-stoichiometric compound Fe1-xO increases, leading to an increase in the concentration of cation vacancies, which results in a decrease in the density of Fe1-xO. Similarly, if the partial pressure of the surrounding oxygen atmosphere is increased, the value of x in the non-stoichiometric compound Zn1+xO decreases, leading to a reduction in the concentration of interstitial cations, which also results in a decrease in the density of Zn1+xO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析非化学计量化合物Fe1-xO和Zn1+xO的密度如何随氧分压变化，答案需要详细的文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求分析非化学计量化合物中结构缺陷浓度与周围氧气分压的关系，并解释其对密度的影响。这需要综合运用非化学计量化合物的缺陷化学知识，理解缺陷类型（阳离子空位和间隙阳离子）与氧分压的关系，并进行推理分析。思维过程涉及多步逻辑推理和机理解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求分析非化学计量化合物Fe1-xO和Zn1+xO在氧分压增加时的密度变化，涉及对缺陷化学机理的深入理解和综合运用。需要考生掌握非化学计量化合物的缺陷类型（如阳离子空位和间隙阳离子）及其与周围气氛的关系，并能推理分析氧分压变化对缺陷浓度和材料密度的影响机制。这种综合运用多个知识点进行复杂现象分析的要求，在简答题中属于最高难度等级。" + }, + { + "idx": 792, + "question": "Explain what type of solid solution compound austenite in carbon steel belongs to", + "answer": "Austenite is an interstitial solid solution of carbon in γ-Fe", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释奥氏体在碳钢中属于哪种固溶体类型，需要文字解释和论述，答案也是以文字形式给出具体解释 | 知识层次: 题目考查对奥氏体这一基本概念的记忆和理解，属于材料科学中固溶体的基础分类知识 | 难度: 在简答题题型中，该题目仅要求回答奥氏体的基本定义和分类，属于最基础的概念记忆性知识。不需要额外的解释或复杂概念体系的阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 793, + "question": "Explain what type of solid solution compound Fe3C belongs to", + "answer": "Fe3C is an interstitial compound, belonging to the interstitial phase with a complex structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C属于哪种固溶体化合物，需要文字解释和论述，答案也以文字形式给出详细说明 | 知识层次: 题目考查对Fe3C类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释Fe3C属于哪种固溶体化合物，并给出其具体分类。这需要学生对固溶体化合物的分类有基本了解，并能准确描述Fe3C的结构特点。虽然涉及专业术语，但不需要复杂的推导或多概念整合，属于中等难度的概念解释题。" + }, + { + "idx": 794, + "question": "1. Briefly describe the characteristics of grain growth and secondary recrystallization, as well as the causes of secondary recrystallization and methods to prevent it.", + "answer": "Characteristics of grain growth: Grain growth is a process in which the average grain size of a strain-free material continuously increases during heat treatment without changing its distribution. The grain size grows uniformly within the body; during grain growth, pores remain at grain boundaries or grain boundary intersections. Characteristics of secondary recrystallization: It is an abnormal growth process where a few large grains grow at the expense of fine grains. It involves the abnormal growth of individual grains; during secondary recrystallization, pores are trapped inside the grains; secondary recrystallization is also related to the particle size of the raw material. Causes of secondary recrystallization: Non-uniform particle size of the raw material, excessively high sintering temperature, and too fast sintering rate. Methods to prevent secondary recrystallization: Control sintering temperature and time, ensure uniformity of raw material particle size, and introduce sintering additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶粒生长和二次再结晶的特征、二次再结晶的原因以及防止方法，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求描述晶粒生长和二次再结晶的特征，分析二次再结晶的原因及预防方法，涉及多个概念的关联和综合分析，需要理解并应用相关知识进行论述，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对晶粒生长和二次再结晶的特征进行描述，并分析二次再结晶的原因及预防方法。这需要综合多个概念（晶粒生长、二次再结晶、烧结条件等）进行多角度分析论述，涉及较深的知识点关联和综合分析能力。虽然不需要进行深度关联性分析（如等级5），但已超出基础说明（等级3）的范畴，属于多角度分析论述的难度等级。" + }, + { + "idx": 795, + "question": "Explain what type of solid solution compound ME2Si belongs to", + "answer": "ME2Si is an intermetallic compound", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释ME2Si属于哪种固溶体化合物，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对ME2Si化合物类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答ME2Si属于何种固溶体化合物，属于基本定义简答。题目仅涉及对\"intermetallic compound\"这一基础概念的记忆和简单应用，不需要进行概念解释或复杂体系阐述，符合等级1的基本定义简答特征。" + }, + { + "idx": 796, + "question": "Explain what type of solid solution compound Cu3Sn belongs to", + "answer": "Cu3Sn is an electron compound, an intermetallic compound with a specific electron concentration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Cu3Sn属于哪种固溶体化合物，需要文字解释和论述，答案也是以文字形式给出具体解释 | 知识层次: 题目考查对电子化合物这一基本概念的记忆和理解，属于材料科学中固溶体分类的基础知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释Cu3Sn属于哪种固溶体化合物类型，并需要说明其具体特征（电子化合物）。这属于概念解释和描述的难度级别，需要学生掌握相关定义并能进行简要阐述，但不需要复杂的体系分析或多层次的概念关联。" + }, + { + "idx": 797, + "question": "What factors influence the formation of amorphous metals? Why", + "answer": "Viscosity of liquid metal: the higher the viscosity, the more difficult the atomic diffusion, making it easier to retain the liquid metal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响非晶金属形成的因素，并需要文字解释和论述，答案提供了详细的解释而非选择或判断。 | 知识层次: 题目要求分析非晶金属形成的因素，并解释原因，涉及多个因素的相互作用和机理的解释，需要综合运用知识进行推理分析。 | 难度: 在简答题题型中，该题目要求对非晶态金属形成的因素进行机理深度解释，涉及液体金属粘度和原子扩散等复杂概念的综合运用。虽然题目没有要求全面分析所有影响因素（如冷却速率、合金成分等），但需要对核心机理进行深入阐述，因此属于等级4的难度。" + }, + { + "idx": 798, + "question": "In a simple cubic crystal, if the direction of the dislocation line is [112] and the Burgers vector is $b=a$ [110], determine the type of this dislocation.", + "answer": "Since the direction of the dislocation line is perpendicular to the direction of the Burgers vector, this dislocation is an edge dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错的类型，答案是基于对位错线和伯格斯矢量方向关系的分析得出的结论，而不是通过选择、判断或计算得出的。 | 知识层次: 题目需要理解位错线和伯格斯矢量的方向关系，并应用相关知识判断位错类型。这涉及多步思维过程，包括方向分析和概念关联，但不需要复杂的推理或深度理解。 | 难度: 在简答题中属于中等难度，需要理解晶体结构、位错类型和Burgers矢量的概念，并进行综合分析。题目要求判断位错类型，需要知道位错线与Burgers矢量的关系，并进行垂直性判断。虽然涉及多个概念，但解题步骤相对直接，属于综合分析和说明的范畴。" + }, + { + "idx": 799, + "question": "3. Briefly describe the main types and characteristics of solid-phase sintering and liquid-phase sintering, as well as the similarities and differences between solid-phase sintering and liquid-phase sintering.", + "answer": "Main types and characteristics of solid-phase sintering: Evaporation-condensation mass transfer, caused by the vapor pressure difference in different parts, does not result in shrinkage of the green body during the sintering process. Diffusion mass transfer, caused by the vacancy concentration difference in different parts of the particles, is the main method of mass transfer for most solid materials during sintering. Main types and characteristics of liquid-phase sintering: Flow mass transfer, which is the main method of mass transfer for most silicate materials during sintering, can be divided into viscous flow and plastic flow. Dissolution-precipitation mass transfer, where both solid and liquid phases exist, and the solid phase is soluble in the liquid phase. Similarities between solid-phase sintering and liquid-phase sintering: The driving force for sintering is surface energy, and the sintering process consists of stages such as particle rearrangement, pore filling, and grain growth. Differences: Due to the faster rate of flow mass transfer compared to diffusion, liquid-phase sintering has a higher densification rate and lower sintering temperature. Additionally, the rate of the liquid-phase sintering process is also related to factors such as the amount and properties of the liquid phase (viscosity, surface tension, etc.), the wetting condition between the liquid and solid phases, and the solubility of the solid phase in the liquid phase. The factors influencing liquid-phase sintering are more complex than those for solid-phase sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固相烧结和液相烧结的主要类型和特点，以及它们之间的异同点。答案以文字解释和论述的形式呈现，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求描述固相烧结和液相烧结的主要类型和特点，并比较它们的异同。这需要理解烧结的基本原理和不同类型烧结的机制，涉及多个概念的关联和综合分析。虽然不涉及复杂的计算或深度推理，但需要对烧结过程有较深入的理解和比较能力，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析和论述两种烧结类型的主要特征、相似点和差异点。题目不仅要求掌握固体相烧结和液相烧结的基本概念和类型，还需要深入理解它们的驱动机制、质量传递方式以及影响因素。此外，还需要对两种烧结过程进行多角度的比较，包括烧结速率、温度要求以及影响因素的复杂性等。这种题目要求考生具备较强的综合分析能力和概念关联能力，属于中等应用层次中的较高难度题目。" + }, + { + "idx": 800, + "question": "Please briefly describe the similarities and differences between interstitial solid solutions, interstitial phases, and interstitial compounds?", + "answer": "Similarity: small atoms dissolve. Differences: interstitial solid solutions retain the solvent (large atoms) lattice; interstitial phases and interstitial compounds alter the large atoms lattice, forming a new lattice. Interstitial phases have simple structures; interstitial compounds have complex structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述间隙固溶体、间隙相和间隙化合物的异同点，需要文字解释和论述，而不是选择、判断或计算。答案也以文字形式呈现，符合简答题的特征。 | 知识层次: 题目要求比较和区分三种间隙相关的材料科学概念（间隙固溶体、间隙相和间隙化合物），需要理解它们的相似点和不同点，并能够关联这些概念。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于较高难度，需要综合分析和比较三个相关但不同的概念（间隙固溶体、间隙相和间隙化合物）。题目要求不仅指出它们的相似之处（小原子溶解），还要详细说明它们之间的差异（晶格结构的变化和新结构的形成）。此外，还需要区分间隙相和间隙化合物的结构复杂性。这种多角度分析和论述的要求使得题目在同题型内属于较高难度等级。" + }, + { + "idx": 801, + "question": "What are the characteristics of various alloy strengthening methods?", + "answer": "Grain refinement strengthening, solid solution strengthening, multiphase strengthening, dispersion strengthening (age hardening), and work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述各种合金强化方法的特征，答案提供了多种强化方法的名称，但没有选项供选择，需要文字解释和论述。 | 知识层次: 题目考查对合金强化方法的基本分类和特征记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求列举并简要描述各种合金强化方法的特点，属于概念解释和描述的难度级别。虽然需要记忆多个强化方法的名称和基本特征，但不需要深入分析或比较这些方法之间的复杂关系，因此属于中等难度。" + }, + { + "idx": 802, + "question": "What is the physical significance of the critical nucleus?", + "answer": "The physical significance of the critical nucleus: the smallest embryo that can grow spontaneously (or, a nucleus with a radius equal to rk).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释临界核的物理意义，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对临界晶核物理意义的基本概念记忆和理解，属于定义性知识，不需要复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答临界核的物理意义，即最小的能够自发生长的晶核。这属于基础概念记忆层面的问题，只需直接回忆和复述定义即可，不需要进行概念解释或复杂体系阐述。在简答题的难度谱系中，这属于最基本的定义简答类型。" + }, + { + "idx": 803, + "question": "What are the methods of alloy strengthening?", + "answer": "Grain refinement strengthening, solid solution strengthening, multiphase strengthening, dispersion strengthening (age hardening), and work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释合金强化的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查合金强化方法的基本分类和记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举合金强化的方法，这需要学生对材料科学中的基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。虽然涉及多个强化方法，但每个方法都是基础概念，且题目并未要求详细解释每种方法的原理或应用场景，因此难度适中。" + }, + { + "idx": 804, + "question": "If it is an edge dislocation, determine the crystallographic plane indices of the half-atom plane and the crystallographic direction indices of the insertion direction.", + "answer": "The crystallographic plane indices of the half-atom plane are (110).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定晶体学平面指数和方向指数，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对边缘位错中半原子面晶面指数和插入方向晶向指数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要学生不仅记住位错的定义，还要能够具体应用晶体学知识（如晶面指数和晶向指数的确定）来解答问题。这比单纯的定义简答（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 805, + "question": "What are the sufficient conditions for the formation of a critical nucleus?", + "answer": "The sufficient conditions for the formation of a critical nucleus: (1) Formation of an embryo with r≥rk; (2) Acquisition of nucleation work with A≥A* (critical nucleation work).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述形成临界核的充分条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查临界核形成的充分条件，属于基本原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释临界核形成的充分条件，涉及两个关键条件的描述（胚胎尺寸和成核功），但不需要进行复杂的体系阐述或多概念整合。这属于对基础概念的理解和复述层面，符合等级2\"概念解释和描述\"的特征。" + }, + { + "idx": 806, + "question": "Please briefly describe the main factors affecting diffusion", + "answer": "The main factors affecting diffusion: (1) temperature; (2) crystal structure and type; (3) crystal defects; (4) chemical composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述影响扩散的主要因素，答案以文字解释和列举要点的方式呈现，符合简答题的特征。 | 知识层次: 题目考查对扩散影响因素的基本概念记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述影响扩散的主要因素，涉及多个基本概念（温度、晶体结构、缺陷、化学成分）的列举和简单解释，但不需要深入分析或建立复杂的概念体系。相比等级1的纯定义简答，需要更多的知识组织和表述能力；相比等级3的体系化阐述，其认知负荷和综合要求较低。" + }, + { + "idx": 807, + "question": "Briefly describe the growth mechanism of pure metal crystals", + "answer": "The crystal growth mechanism refers to the microscopic growth mode of crystals, which is related to the liquid-solid interface structure. For substances with rough interfaces, since about $50\\\\%$ of the atomic positions on the interface are vacant, these vacancies can accept atoms. Therefore, liquid atoms can individually enter the vacancies and connect with the crystal, causing the interface to advance perpendicularly along its normal direction, resulting in continuous growth. For crystals with smooth interfaces, growth does not occur through the attachment of individual atoms but rather through homogeneous nucleation, forming a two-dimensional nucleus one atomic layer thick on the crystallographic facet interface, creating a step between the new nucleus and the original interface. Individual atoms can then fill in the step, allowing the two-dimensional nucleus to grow laterally. Once the layer is filled, a new two-dimensional nucleus forms on the new interface, and the process repeats. If the smooth interface of the crystal has an exposed screw dislocation, the interface becomes a spiral surface, forming a step that never disappears. Atoms attach to the step, enabling crystal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述纯金属晶体的生长机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细描述纯金属晶体的生长机制，涉及液体-固体界面结构、粗糙界面和光滑界面的不同生长模式、二维核形成、螺旋位错等复杂概念。需要综合运用多个知识点，进行机理的解释和分析，思维过程深度要求较高。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求考生不仅理解纯金属晶体的生长机制，还需要综合运用界面结构、原子附着方式、二维核形成及螺旋位错等多个复杂概念进行详细解释。解题步骤涉及多个微观过程的描述和机理推理，对考生的知识深度和逻辑分析能力要求较高，符合等级5的标准。" + }, + { + "idx": 808, + "question": "What are the limitations of strain hardening as a strengthening method?", + "answer": "Strain hardening does not fundamentally change the properties of the alloy. Under certain conditions, such as temperature increase, strain hardening may be lost due to the occurrence of recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应变硬化的局限性，需要文字论述和解释，而不是选择、判断或计算 | 知识层次: 题目要求解释应变硬化的局限性，涉及对材料性能变化的理解和特定条件下（如温度升高）材料行为的分析。这需要将应变硬化的基本原理与实际应用中的限制条件相结合，属于中等应用层次的知识。 | 难度: 在简答题中属于中等难度，需要理解应变硬化的基本原理及其局限性，并能解释在特定条件下（如温度升高）应变硬化可能失效的原因。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 809, + "question": "According to the position of solute atoms in the lattice, into how many categories can solid solution phases be divided?", + "answer": "Based on the position of solute atoms in the lattice, solid solutions can be divided into substitutional solid solutions, such as the α phase in Al-Cu alloys; interstitial solid solutions, such as the α phase in Fe-C alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对固体溶液相进行分类，并举例说明，需要文字解释和论述，而不是简单的选择或判断。答案也提供了详细的分类和例子，符合简答题的特征。 | 知识层次: 题目考查固体溶液的分类这一基础概念的记忆和理解，属于定义和分类的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释和描述两种不同类型的固溶体（置换固溶体和间隙固溶体），并举例说明。虽然涉及基础概念记忆，但需要一定的理解和组织能力来完整回答。" + }, + { + "idx": 810, + "question": "What is the significance of strain hardening in production?", + "answer": "Strain hardening, also known as work hardening, can improve the strength and hardness of alloys. For example, cold-drawn steel wires are strengthened by utilizing the strain hardening effect. Especially for some alloys that cannot be strengthened by heat treatment, strain hardening is a very important strengthening method.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应变硬化的意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释应变硬化的定义（基础概念），还需要论述其在生产中的具体应用和重要性（概念关联和综合分析），涉及多步思维过程和对材料强化机制的理解。 | 难度: 在简答题中，该题目属于中等难度。虽然题目要求解释应变硬化的意义，但答案需要结合具体例子（如冷拔钢丝）和不同合金的强化方法进行说明。这要求考生不仅理解应变硬化的基本概念，还需要能够关联实际应用和不同材料的特点。然而，题目并未要求深入探讨应变硬化的微观机制或多角度比较不同强化方法，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 811, + "question": "During non-equilibrium solidification of solid solution alloys, sometimes microsegregation forms, and sometimes macrosegregation forms. What is the reason for this?", + "answer": "Microsegregation occurs within the range of a single grain and is caused by the slow diffusion rate during crystallization. Macrosegregation occurs throughout the entire part or sample and is caused by the redistribution of solute atoms during crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释微偏析和宏观偏析形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非平衡凝固过程中微观偏析和宏观偏析的形成原因，涉及对扩散速率、溶质原子再分布等机理的深入理解和综合分析，需要将多个概念关联起来进行推理分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释非平衡凝固过程中微观偏析和宏观偏析的形成原因，这需要深入理解凝固过程中的扩散机制和溶质原子再分配原理。虽然不需要进行复杂现象的全面分析（等级5），但需要对两种偏析现象的机理进行区分和详细解释，属于该题型中较高难度的题目。" + }, + { + "idx": 812, + "question": "What are the necessary conditions for an alloy to undergo precipitation hardening?", + "answer": "The necessary condition for precipitation hardening to occur is the availability of a supersaturated solid solution to facilitate the precipitation of a second phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释合金发生沉淀硬化的必要条件，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对沉淀硬化基本条件的记忆和理解，属于基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释合金发生沉淀硬化的必要条件，涉及对\"过饱和固溶体\"和\"第二相析出\"等基础概念的理解和描述，但不需要进行复杂的体系阐述或多概念整合。相比等级1的纯定义复述题，需要更多概念间的逻辑联系说明；相比等级3的复杂机理阐述题，其知识深度和论述要求较为基础。" + }, + { + "idx": 813, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], if the slip is caused by an edge dislocation, indicate the direction of the dislocation line.", + "answer": "Direction of the dislocation line: [112]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据给定的晶体结构和滑移系统，指出位错线的方向，答案需要具体的文字描述或方向指示，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求理解面心立方晶体的滑移系统和位错线方向的关系，需要将晶体几何学与位错理论相结合进行分析。虽然不涉及复杂的计算，但需要多步概念关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求分析面心立方晶体中可动滑移系(111)[110]由刃位错引起滑移时位错线的方向。解答需要综合运用晶体学、位错理论等知识，通过多步推导确定位错线方向为[112]。这需要学生不仅掌握基本概念，还要能够将不同知识点关联起来进行综合分析，比单纯的概念解释或简单计算更为复杂。同时，题目涉及晶体学指数的转换和位错几何关系的理解，这些都是材料科学中较为深入的内容。因此，在同为需要文字解释和论述的简答题中，该题目属于较高难度等级。" + }, + { + "idx": 814, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], please indicate the Burgers vector of the unit dislocation causing the slip.", + "answer": "Burgers vector; b=a/2 [110]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释并给出Burgers vector的具体表达式，需要文字说明和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求确定面心立方晶体中特定滑移系的单位位错的Burgers矢量，这需要理解晶体结构、滑移系和位错的基本概念，并能够将Burgers矢量的计算与晶体学方向关联起来。虽然涉及的知识点较为基础，但需要一定的综合分析能力来正确应用这些概念。 | 难度: 在简答题中属于中等难度，需要理解面心立方晶体的滑移系统和伯格斯矢量的概念，并进行简单的计算和解释。虽然题目涉及多个概念的综合运用，但解题步骤相对直接，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 816, + "question": "Explain the meaning of the rolling texture {110}<112> in face-centered cubic alloy α-brass.", + "answer": "It is a sheet texture. The {110}<112> texture indicates that the {110} plane is parallel to the rolling plane, and the <112> direction is parallel to the rolling direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释面心立方合金α-黄铜中轧制织构{110}<112>的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释面心立方合金α-黄铜中{110}<112>轧制织构的含义，涉及晶体学平面和方向的关联，需要理解织构的定义及其在材料中的具体表现。虽然不涉及复杂计算或深度推理，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释{110}<112>织构的含义，但只需要明确说明该织构的平面和方向与轧制面和轧制方向的关系即可。不需要进行多角度分析或深度关联性分析，属于综合分析和说明的范畴。" + }, + { + "idx": 817, + "question": "How many equivalent slip systems can be simultaneously activated when a face-centered cubic metal single crystal is stretched along [111]? And specifically write the indices of each slip system.", + "answer": "When an FCC-structured crystal is stretched along the [111] direction, there are 6 equivalent slip systems, which are: (111)[011], (111)[110], (111)[011], (111)[101], (111)[101], (111)[110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释并列举具体的滑移系统指数，需要文字描述和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求确定面心立方金属单晶在特定拉伸方向下的等效滑移系统数量，并具体写出每个滑移系统的指数。这需要理解滑移系统的基本概念，并能够应用晶体学知识进行综合分析，涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识、滑移系计算和方向分析。题目要求不仅计算等效滑移系数量，还需具体写出每个滑移系的指数，涉及多步计算和概念关联。相比简单概念解释类简答题，该题需要更深入的材料变形机制理解和空间想象能力，符合\"多角度分析论述\"的等级特征。" + }, + { + "idx": 819, + "question": "What is the Kirkendall effect in the process of alloy diffusion?", + "answer": "Kirkendall effect: As shown in Figure 1-4, a very thin molybdenum wire is applied as a marker on an FCC-structured α-brass (Cu+30%Zn) rod, and then copper is plated on the brass, enclosing the molybdenum wire between the brass and copper. Diffusion is carried out at a certain temperature. The molybdenum wire serves only as a marker and does not participate in the diffusion throughout the experiment. The diffusing components are copper and zinc, which form a substitutional solid solution. In the diffusion process of the substitutional solid solution, the markers placed at the original interface move towards the direction of the low-melting-point element, and the displacement distance exhibits a parabolic relationship with time. The reason for this phenomenon is that the low-melting-point component diffuses faster, while the high-melting-point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对Kirkendall效应进行详细的文字解释和论述，答案提供了具体的现象描述、实验过程和原因分析，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要详细描述其现象、原因和机制，涉及多步推理和综合分析。需要理解扩散过程中的原子交换不平衡及其对标记物移动的影响，属于对复杂现象的解释和分析。 | 难度: 在简答题-复杂分析题型中，该题目要求全面解释Kirkendall效应的机理，包括扩散过程中的原子交换不平衡、标记物移动方向与时间的关系等复杂现象。需要综合运用扩散理论、固溶体知识和动力学分析能力，属于该题型内最高难度的全面分析类题目。" + }, + { + "idx": 820, + "question": "How many types of two-dimensional lattices are there? Indicate their types and illustrate with diagrams.", + "answer": "There are 5 types of two-dimensional lattices, namely oblique, hexagonal, rectangular, centered rectangular, and square, as shown in Table 1-1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和描述二维晶格的类型，并辅以图示说明，这需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对二维晶格类型的基础概念记忆和分类理解，不需要复杂的分析或综合应用 | 难度: 在简答题题型中，该题目要求回答二维晶格的类型并配以图示说明，属于概念解释和描述的难度等级。虽然需要记忆五种晶格类型，但不需要深入分析或复杂推理，属于中等难度的简答题。" + }, + { + "idx": 821, + "question": "What are the main characteristics of Shockley partial dislocations in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "Shockley partial dislocation; Burgers vector is 1 <112> 6; dislocation nature is screw-type, edge-type, mixed-type; formation method is can only be formed through local slip of the crystal; motion state is even edge-type partial dislocations can only slip and cannot climb. Even screw-type partial dislocations cannot cross-slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Shockley partial dislocations的主要特征，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对Shockley不全位错的多个特征进行综合描述，包括位错名称、Burgers矢量、位错性质、形成方式和运动状态。这需要将多个相关概念进行关联和综合分析，而不仅仅是简单的记忆或理解。虽然不涉及复杂的计算或推理，但需要对位错理论有较深入的理解和应用能力。 | 难度: 在简答题中属于较高难度，需要综合多个知识点进行多角度分析论述。题目要求详细说明Shockley不全位错的五个主要特征（位错名称、柏氏矢量、位错性质、形成方式和运动状态），涉及FCC晶体结构、位错理论、滑移机制等多个概念的关联分析。虽然不需要进行数学计算，但需要对位错性质（螺型/刃型/混合型）和运动限制（滑移/攀移/交滑移）等专业概念有深入理解，并组织成连贯的论述。相比只需列举基本特征的等级3题目，本题需要更系统的知识整合能力。" + }, + { + "idx": 822, + "question": "What are the main characteristics of Frank partial dislocations in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "Frank partial dislocation; Burgers vector is 1/3 <111>; the nature of the dislocation is edge-type; the formation method involves inserting or removing a layer of {111} close-packed plane in a local region of the crystal; the motion state is that it can only climb, not glide.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释Frank partial dislocations在FCC晶体中的主要特征，包括多个方面的描述（如位错名称、Burgers矢量、位错性质、形成方法和运动状态）。答案需要以文字形式进行论述和解释，而不是选择、判断或计算。 | 知识层次: 题目考查Frank partial dislocations的基本特征，包括名称、Burgers矢量、位错性质、形成方法和运动状态，这些都是基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答Frank partial dislocations的多个特征，包括名称、Burgers矢量、位错性质、形成方法和运动状态。这些内容虽然涉及多个方面，但都属于基础概念的记忆和描述范畴，不需要进行复杂的体系阐述或深入分析。因此，在简答题题型内属于中等难度（等级2）。" + }, + { + "idx": 823, + "question": "What are the main characteristics of the Shockley partial dislocation in the extended dislocation of an FCC crystal? Include the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "Shockley partial dislocation in the extended dislocation; Burgers vector is 1 [112] 6 [121] 6; dislocation nature is mixed-type; formation method is the decomposition of a perfect dislocation into two parallel Shockley partial dislocations of screw-type, edge-type, and mixed-type, with a stacking fault region in between; motion state is glide-only. Climb or cross-slip can only occur after constriction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Shockley partial dislocation的主要特征，包括多个方面的描述（如Burgers vector、位错性质、形成方式等），答案需要以文字形式进行综合论述，而非选择、判断或计算。 | 知识层次: 题目要求对Shockley部分位错的主要特征进行详细描述，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态。这需要学生不仅记忆相关概念，还需要理解位错的性质和形成机制，并将这些知识点综合起来进行回答。虽然题目不涉及复杂的计算或推理，但需要学生对多个概念进行关联和综合分析，因此属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对Shockley不全位错的多个特征进行详细说明，包括位错名称、Burgers矢量、位错性质、形成方式以及运动状态。这需要学生不仅掌握相关概念，还需要能够将这些概念综合起来进行多角度分析。此外，题目还要求解释位错的形成机制和运动限制，这增加了问题的复杂性和深度。因此，该题目在简答题题型中属于较高难度，需要学生具备较强的综合分析能力。" + }, + { + "idx": 824, + "question": "What are the main characteristics of perfect dislocations in FCC crystals? Including dislocation name, Burgers vector, dislocation nature, dislocation formation mode, and motion state.", + "answer": "Perfect dislocations (relatively rare in actual crystals); Burgers vector is 1 <110> 2; dislocation nature is screw-type, edge-type, mixed-type; dislocation formation mode is local slip or local displacement; motion state is can slip or climb.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释完美位错在FCC晶体中的主要特征，包括位错名称、Burgers矢量、位错性质、位错形成方式和运动状态。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对FCC晶体中完美位错的基本特性的记忆和理解，包括位错名称、Burgers矢量、位错性质、形成方式及运动状态等基础概念，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述完美位错在FCC晶体中的主要特征，包括位错名称、伯格斯矢量、位错性质、形成方式和运动状态。虽然涉及多个概念，但都属于基础概念记忆范畴，不需要复杂的体系阐述或深入分析。题目要求的知识点较为明确，解题步骤相对直接，属于概念解释和描述的中等难度级别。" + }, + { + "idx": 825, + "question": "What are the main characteristics of the L-C sessile dislocation in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "L-C sessile dislocation (with multiple configurations); Burgers vector is for example—[110] 6; dislocation nature is screw-type, edge-type, mixed-type; formation method is obtained through Shockley partial dislocation synthesis (or dislocation reaction); motion state is immobile.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释L-C sessile dislocation的主要特征，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对L-C sessile dislocation的多个特征进行描述，包括Burgers向量、位错性质、形成方法和运动状态等，需要综合理解和应用多个相关概念，并进行一定的关联分析。虽然不涉及复杂的计算或深度推理，但需要将多个知识点整合起来回答，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对L-C sessile dislocation的多方面特性进行详细说明，包括名称、Burgers向量、位错性质、形成方法和运动状态。这需要学生不仅掌握相关概念，还能进行多角度的分析和论述，将多个知识点综合起来回答。虽然不涉及最复杂的深度关联性分析，但已经超出了简单的概念解释或单一知识点的应用，属于多角度分析论述的难度等级。" + }, + { + "idx": 826, + "question": "Using the standard projection diagram of a cubic crystal, explain the formation reason of the rolling texture {110}<112> in face-centered cubic alloy α-brass.", + "answer": "α-brass has an FCC structure, and its slip system is {111}<10\\overline{1}>. Under the action of tensile force along the rolling direction, the crystal slips and rotates. In the crystallographic coordinate system, if the tensile axis T1 is located in the 001-101-111 orientation triangle, the initial slip system is (111)[011], and the tensile axis turns toward the [011] direction, reducing the angle λ between the tensile axis and the slip direction. When the force axis reaches the common edge of the two orientation triangles, i.e., T2, double slip begins, and the slip system (111)[101] is also activated. The tensile axis turns both toward the [011] direction and the [101] direction, resulting in rotation along the common edge. When it reaches the [112] direction, since [101], [112], and [011] lie on the same great circle, the two λ angles simultaneously decrease to the minimum value, making [112] the final stable position. Thus, the <112> direction tends to align with the rolling direction. On the rolling plane, under the action of compressive force, if the compressive axis P1 is located in the 001-011-111 orientation triangle, the initial slip system is (111)[101], and the compressive axis turns toward the (111) plane, reducing the angle φ between the compressive axis and the slip plane. When the force axis reaches the common edge of the two orientation triangles, i.e., P2, double slip begins, and the slip system (111)[101] is also activated. The compressive axis turns both toward the (111) plane and the (111) plane, resulting in rotation along the common edge. When it reaches the (011) plane, since (111), (011), and (111) lie on the same great circle, the two φ angles simultaneously decrease to the minimum value, making (011) the final stable position. Thus, the (011) plane tends to become parallel to the rolling plane. As a result, the {110} plane becomes parallel to the rolling plane, and the <112> direction becomes parallel to the rolling direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释面心立方合金α-黄铜中轧制织构{110}<112>的形成原因，答案通过详细的文字论述和解释来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释面心立方合金α-黄铜中{110}<112>轧制织构的形成原因，涉及晶体滑移系统、应力作用下晶体的旋转机制、双滑移系统的激活以及最终稳定取向的形成。这需要综合运用晶体学知识、力学原理和织构形成机理，进行多步骤的推理和分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体学、材料变形机理和标准投影图知识，详细解释面心立方合金α-黄铜中{110}<112>轧制织构的形成原因。题目涉及多个复杂步骤的分析，包括初始滑移系统的确定、力轴的旋转过程、双滑移的激活条件以及最终稳定位置的判断。需要考生具备深厚的晶体学理论基础和空间想象能力，能够将抽象的理论知识与具体的变形过程相结合，属于该题型下最高难度的复杂现象全面分析题目。" + }, + { + "idx": 827, + "question": "What insights do the Kirkendall experiment results provide?", + "answer": "The practical significance of the Kirkendall effect includes: ① Revealing the intrinsic connection between macroscopic diffusion laws and microscopic diffusion mechanisms, which is universal; ② Directly refuting the exchange mechanism of substitutional solid solution diffusion and supporting the vacancy mechanism; ③ Each component in the diffusion system has its own diffusion coefficient; ④ The Kirkendall phenomenon often produces side effects, such as incomplete shrinkage leading to Kirkendall pores, etc. These side effects often have adverse impacts in practice and should therefore be controlled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对Kirkendall实验结果的见解进行详细解释和论述，答案提供了多个方面的深入分析，符合简答题的特征。 | 知识层次: 题目要求对Kirkendall实验结果的多个方面进行深入分析和解释，包括宏观与微观扩散机制的联系、对扩散机制的验证、扩散系数的独立性以及Kirkendall现象的副作用等。这需要综合运用扩散理论、微观机制理解以及实际应用中的影响分析，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对Kirkendall实验结果的多个方面进行机理深度解释，包括宏观与微观扩散的联系、反驳交换机制、支持空位机制、各组分扩散系数的独立性以及Kirkendall现象的副作用。这些内容需要综合运用扩散理论、理解实验现象背后的物理机制，并进行逻辑严密的论述，属于该题型中较高难度的题目。" + }, + { + "idx": 828, + "question": "Indicate the second main mechanism of alloy strengthening and explain its strengthening reason", + "answer": "Precipitation strengthening and dispersion strengthening. The compounds of alloying elements and matrix elements obtained through phase transformation processes in alloys, as well as hard particles mechanically mixed into the matrix material, both cause alloy strengthening, referred to as precipitation strengthening and dispersion strengthening, respectively. The effects of precipitation strengthening and dispersion strengthening are much greater than solid solution strengthening. When dislocations encounter second phases during movement, they need to cut through (small-sized particles in precipitation strengthening and particles in dispersion strengthening) or bypass (large-sized particles in precipitation strengthening) the second phases. Therefore, the second phases (precipitates and dispersoids) hinder dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第二种主要机制及其强化原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求识别合金强化的第二种主要机制（沉淀强化和弥散强化），还需要解释其强化原因，涉及位错运动与第二相颗粒的相互作用机制。这需要综合运用材料科学中的相变、位错理论等知识，进行机理层面的解释和分析，属于较高层次的认知要求。 | 难度: 在简答题中属于机理深度解释难度。题目要求不仅指出第二主要合金强化机制，还需要详细解释其强化原因，涉及相变过程和位错运动的复杂机理分析。虽然不需要全面分析所有可能的复杂现象，但对知识点的掌握深度和解释能力要求较高，属于该题型中偏难的水平。" + }, + { + "idx": 829, + "question": "Given that the recrystallization activation energy of a Cu-30%Zn alloy is 250 kJ/mol, and it takes 1 hour for this alloy to complete recrystallization at a constant temperature of 400°C, calculate how many hours it will take for this alloy to complete recrystallization at a constant temperature of 390°C.", + "answer": "According to the formula, t2/t1 = exp[-Q/R(1/T1 - 1/T2)] = exp[-250×10^3/8.314×(1/(400+273) - 1/(390+273))] = 1.962. Therefore, t2 = t1×1.962 = 1.962 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及使用给定的公式和参数进行计算，最终得出具体的时间数值。 | 知识层次: 题目需要进行多步计算，涉及公式的应用和温度单位的转换（摄氏度转开尔文），同时需要理解再结晶激活能的概念及其在计算中的作用。虽然计算过程较为直接，但需要一定的综合分析能力和对公式的理解。 | 难度: 在计算题中属于综合性计算问题，需要应用Arrhenius公式进行多步计算，涉及温度单位转换（℃→K）、对数运算和指数运算，同时要求对材料科学中的再结晶激活能概念有清晰理解。虽然计算步骤明确，但需要严谨的数值处理和单位一致性检查，属于中等偏上的综合计算难度。" + }, + { + "idx": 830, + "question": "Indicate the first main mechanism of alloy strengthening and explain its strengthening reason", + "answer": "Solid solution strengthening. The alloy element atoms dissolved in the lattice interstices or nodes, due to their size differing from the matrix atoms, generate a certain stress field that hinders dislocation movement; Cottrell atmospheres and Suzuki atmospheres, the former being interstitial atoms preferentially distributed in the tensile stress region of edge dislocations in BCC metals, producing a pinning effect on dislocations, the latter being alloy elements preferentially distributed in the stacking fault region of extended dislocations in FCC metals, reducing stacking fault energy, expanding the stacking fault region, making the slip of extended dislocations more difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第一种主要机制及其强化原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金强化的主要机制及其强化原因，涉及固溶强化、位错运动阻碍、Cottrell气团和Suzuki气团等复杂概念，需要综合运用材料科学知识进行机理分析和解释，思维深度较高。 | 难度: 在简答题-复杂分析题型中，该题目要求对合金强化的第一主要机制进行详细解释，并深入分析其强化原因。需要综合运用材料科学知识，包括固溶强化、位错理论、Cottrell气团和Suzuki气团等复杂概念，并进行机理深度解释和复杂现象全面分析。这种题目不仅要求掌握多个高级概念，还需要能够将这些概念有机结合起来，解释复杂的材料行为，因此在该题型内属于最高难度等级。" + }, + { + "idx": 831, + "question": "What is the practical significance of the Kirkendall effect?", + "answer": "The practical significance of the Kirkendall effect includes: ① It reveals the intrinsic connection between macroscopic diffusion laws and microscopic diffusion mechanisms, demonstrating universality; ② It directly refutes the exchange mechanism of substitutional solid solution diffusion and supports the vacancy mechanism; ③ Each component in a diffusion system has its own diffusion coefficient; ④ The Kirkendall phenomenon often produces side effects, such as incomplete shrinkage leading to Kirkendall voids, which can have adverse impacts in practice and should therefore be controlled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应的实际意义，答案提供了详细的文字论述和多个要点，符合简答题的特征 | 知识层次: 题目要求对Kirkendall效应的实际意义进行详细解释和论述，涉及多个方面的综合分析，包括宏观与微观扩散的联系、扩散机制的验证、扩散系数的特性以及实际应用中的副作用和控制。这需要深入理解扩散机制，并能将理论知识与实际应用相结合，属于较高层次的认知能力要求。 | 难度: 在简答题（复杂分析类）中属于最高难度等级，因为：" + }, + { + "idx": 832, + "question": "Indicate the third main mechanism of alloy strengthening and explain the reason for its strengthening", + "answer": "Grain boundary strengthening. According to the Hall-Petch formula, the relationship between the yield point σs and the grain diameter d is σs=σ0+K d^(-1/2). The essence is that additional stress is required for dislocations to cross grain boundaries. Therefore, low-temperature steels often adopt a fine-grained structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金强化的第三种主要机制及其强化原因，答案提供了详细的文字解释和论述，包括Hall-Petch公式的应用和晶界强化的本质说明，符合简答题的特征。 | 知识层次: 题目要求解释合金强化的第三种主要机制及其强化原因，涉及Hall-Petch公式的应用和晶界强化机理的理解。这需要将基本原理与具体现象关联，进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解合金强化的第三种主要机制（晶界强化），并能够解释其强化原理。题目要求考生掌握Hall-Petch公式，并能将公式与晶粒尺寸对材料强度的影响联系起来进行分析说明。虽然需要一定的概念关联和综合分析能力，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 833, + "question": "Explain the processes and characteristics of recovery, recrystallization, and grain growth when cold-deformed metal is heated.", + "answer": "When cold-deformed metal is heated, three processes occur sequentially: recovery, recrystallization, and grain growth. Their respective characteristics are as follows:\\n\\n(1) Characteristics of the recovery process\\n\\n① The microstructure does not change during recovery, and the elongated grains of the deformed state are still retained.\\n\\n② The recovery process completely eliminates the macroscopic (Type I) stresses caused by deformation and largely eliminates the microscopic (Type II) stresses.\\n\\n③ During recovery, the mechanical properties generally change little, with hardness and strength only slightly decreasing, plasticity slightly increasing, and certain physical properties changing significantly, such as resistivity decreasing markedly and density increasing.\\n\\n④ The stored energy from deformation is partially released during the recovery stage.\\n\\n(2) Characteristics of the recrystallization process\\n\\n① The microstructure changes, transforming from the elongated grains of cold deformation into new equiaxed grains.\\n\\n② The mechanical properties change drastically, with strength and hardness sharply decreasing and plasticity increasing, returning to the state before deformation.\\n\\n③ The stored energy from deformation is fully released during recrystallization, lattice distortions (Type III stresses) are eliminated, and dislocation density decreases.\\n\\n(3) Characteristics of the grain growth process\\n\\n① The grains grow larger.\\n\\n② It causes changes in some properties, such as decreases in strength, plasticity, and toughness.\\n\\n③ Along with grain growth, other structural changes occur, such as recrystallization texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释冷变形金属加热时的三个过程（回复、再结晶和晶粒长大）及其特征，答案以文字论述的形式呈现，没有选项、判断或计算要求，符合简答题的特征。 | 知识层次: 题目要求详细解释冷变形金属加热过程中的恢复、再结晶和晶粒长大三个阶段的特征和变化，涉及多个微观结构演变、力学性能变化和能量释放等复杂机理的综合分析，需要深入理解和关联多个材料科学概念，并进行系统性的解释和论述。 | 难度: 在简答题-复杂分析题型中，该题目要求全面解释冷变形金属加热时的三个连续过程（回复、再结晶和晶粒长大），并详细描述每个过程的微观结构变化、力学性能变化和能量释放等特征。这需要综合运用材料科学知识，进行机理深度解释和复杂现象全面分析，属于该题型下的最高难度等级。" + }, + { + "idx": 834, + "question": "Indicate the fourth main mechanism of alloy strengthening and explain the reason for its strengthening", + "answer": "Order strengthening. The dislocations in ordered alloys are superdislocations. To cause plastic deformation in the metal, both partial dislocations of the superdislocation need to move simultaneously, thus requiring greater external stress. The bonding force between dissimilar element atoms is stronger than that between similar element atoms, so the ordered arrangement of dissimilar atoms gives ordered alloys higher strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第四种主要机制并说明其强化原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金强化的第四种主要机制及其强化原因，涉及对超位错、塑性变形机制以及原子间结合力的综合分析。需要理解位错运动与材料强度的关系，并能解释有序合金中异种原子排列对强度的影响，属于机理层面的解释和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求解释合金强化的第四种主要机制（有序强化），并详细说明其强化原因。这需要学生不仅掌握有序强化的基本概念，还要理解超位错的运动机制、异种原子间的键合强度差异等深层次机理。虽然题目涉及多个复杂概念，但相比需要全面分析多种强化机制交互作用的题目（等级5），该题更侧重于单一机制的深度解释，因此属于等级4难度。" + }, + { + "idx": 835, + "question": "Explain the formation reasons of the surface fine grain zone in typical ingot structure", + "answer": "The surface fine grain zone has numerous nucleation sites, fast cooling rate, and large undercooling, growing dendritically in various directions, thus forming fine, equiaxed crystals. Due to the rapid crystallization of the fine grain zone, the released latent heat of crystallization cannot dissipate in time, causing the temperature at the liquid-solid interface to rise sharply. This quickly halts the development of the fine grain zone, resulting in a very thin shell of fine grain zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释典型铸锭结构中表面细晶区的形成原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释典型铸锭结构中表面细晶区的形成原因，涉及多个因素的相互作用（形核位点、冷却速率、过冷度等）以及结晶潜热对晶区发展的影响。需要综合运用材料科学中的凝固原理和热力学知识进行推理分析，解释现象背后的机理，属于较高层次的认知要求。 | 难度: 在简答题的复杂分析题型中，该题目要求对表面细晶区的形成原因进行机理深度解释。需要综合运用材料科学中的凝固理论、热力学和动力学知识，分析多个因素（如形核位点、冷却速率、过冷度、结晶潜热等）之间的相互作用，并解释其导致的微观结构特征。虽然不涉及跨学科整合或极端复杂的推导，但需要清晰的逻辑链条和准确的术语表述，属于该题型内较高难度的机理解释类题目。" + }, + { + "idx": 836, + "question": "Explain the formation reason of the central equiaxed crystal zone in typical ingot structure", + "answer": "The central equiaxed crystal zone forms due to the non-directional growth of crystal nuclei in the uniformly cooled central liquid. The crystal nuclei originate from two pathways: one is exogenous nuclei, including detached surface grains and broken dendrites; the other is endogenous nuclei, including homogeneous and heterogeneous nucleation in the undercooled liquid of the central region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释典型铸锭结构中中心等轴晶区的形成原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释典型铸锭结构中中心等轴晶区的形成原因，涉及晶体生长的非定向性、外生晶核和内生晶核的形成机制，需要综合运用材料科学中的凝固原理、晶体生长理论以及热力学和动力学知识进行推理分析。这需要较高的认知能力层次（分析/综合）和对多个知识点的深入理解与关联。 | 难度: 在简答题的复杂分析题型中，该题目要求对铸锭结构中中心等轴晶区的形成原因进行机理深度解释。需要综合运用晶体生长理论、形核机制（外生核与内生核）以及传热学知识，并解释非定向生长的具体条件。虽然不涉及多现象耦合分析（等级5特征），但对单一现象的机理阐述已达到较高深度，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 837, + "question": "Write the close-packed plane, interplanar spacing of close-packed planes, close-packed direction, and minimum unit length of the close-packed direction for an FCC crystal.", + "answer": "
FCC111}√3 a 3<110>√2 2 a
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细描述FCC晶体的密排面、密排面间距、密排方向及其最小单位长度，需要文字解释和论述，答案以表格形式呈现了具体参数，符合简答题的特征。 | 知识层次: 题目考查面心立方(FCC)晶体结构的基本特征，包括密排面、密排面间距、密排方向和密排方向的最小单位长度。这些都是材料科学中关于晶体结构的基础概念，主要依靠记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题中属于中等难度，需要记忆并解释FCC晶体的密排面、面间距、密排方向及其最小单位长度等概念，但不需要复杂的推导或阐述。" + }, + { + "idx": 838, + "question": "Write the close-packed plane, interplanar spacing of close-packed planes, close-packed direction, and minimum unit length of the close-packed direction for BCC crystals.", + "answer": "
BCC110}√2 D 2<111>√3 2 a
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细写出BCC晶体的密排面、密排面间距、密排方向及其最小单位长度，需要文字解释和论述，答案以表格形式呈现，属于简答题类型。 | 知识层次: 题目主要考查对BCC晶体结构的基本概念的记忆，包括密排面、密排面间距、密排方向及其最小单位长度等基础知识点，无需复杂计算或综合分析。 | 难度: 在简答题中属于中等难度，需要记忆并解释BCC晶体的密排面、面间距、密排方向及其最小单位长度等基本概念，但不需要进行复杂的体系阐述或推导。" + }, + { + "idx": 839, + "question": "Write the indices of the crystal plane family with an interplanar spacing of $0.1246\\\\mathrm{nm}$ in nickel (Ni) crystal. The lattice constant of nickel is $0.3524\\\\mathrm{nm}$.", + "answer": "The crystal structure and lattice of nickel (Ni) are face-centered cubic (FCC). The formula for the interplanar spacing in a cubic crystal is: $$d={\\\\frac{a}{\\\\sqrt{h^{2}+k^{2}+l^{2}}}}$$Thus, $$h^{2}+k^{2}+l^{2}=\\\\frac{a^{2}}{d^{2}}=\\\\frac{0.3524^{2}}{0.1246^{2}}\\\\approx8$$Since $\\\\smash{\\\\boldsymbol{h}_{3},\\\\boldsymbol{k}_{3},\\\\boldsymbol{l}}$ are all integers, the possible values for $\\\\smash{\\\\boldsymbol{h}_{3},\\\\boldsymbol{k}_{3},\\\\boldsymbol{l}}$ are: 0, 2, 2. Therefore, The indices of the crystal plane family that meet the requirement are {220}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶面指数，解答过程中涉及到了具体的数学计算和公式推导，最终得出具体的数值结果。 | 知识层次: 题目需要应用立方晶系晶面间距公式进行多步计算，并理解晶面指数的整数约束条件，涉及概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用晶体学中的公式进行多步计算，涉及对立方晶系中晶面间距的理解和整数解的推导。虽然计算过程较为直接，但需要综合运用多个概念和步骤，属于中等偏上的难度。" + }, + { + "idx": 840, + "question": "Write the close-packed plane, interplanar spacing of close-packed planes, close-packed direction, and the minimum unit length of the close-packed direction for HCP (M(a)>√8/3) crystals.", + "answer": "
HCP{0001}1 C 2<1120>D
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细写出HCP晶体的密排面、密排面间距、密排方向及其最小单位长度，需要文字解释和论述，答案形式为表格展示具体参数，符合简答题的特征。 | 知识层次: 题目主要考查对HCP晶体结构的基本概念的记忆，包括密排面、密排方向及其相关参数的定义和识别，不涉及复杂的计算或分析过程。 | 难度: 在简答题题型中，该题目要求回答HCP晶体的密排面、密排面间距、密排方向及其最小单位长度等具体参数，属于概念解释和描述的难度等级。虽然需要记忆多个具体参数，但不需要进行复杂的体系阐述或推导，因此属于等级2。" + }, + { + "idx": 841, + "question": "Indicate and explain the reverse transformation phenomenon in the characteristics of martensitic transformation", + "answer": "When martensite is heated at a sufficiently rapid rate, it can directly transform back to the high-temperature phase without decomposition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体转变中的逆向转变现象，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释马氏体逆转变现象，这需要理解马氏体相变的机理和条件，并能够分析加热速率对相变行为的影响。这涉及对相变动力学的深入理解和综合分析能力，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对马氏体逆转变现象进行机理层面的深度解释，需要综合运用相变理论、热力学和动力学知识。虽然不涉及多现象综合分析（等级5特征），但已超出基础概念复述的范畴，属于需要推导和机理解释的中高难度题目。在简答题的\"复杂分析\"知识层次中，该题更侧重单一现象的深度剖析而非多因素交叉分析，符合等级4的定位标准。" + }, + { + "idx": 842, + "question": "Explain the formation reason of columnar crystal zone in typical ingot structure", + "answer": "After the formation of the fine-grained zone, the mold wall temperature increases, heat dissipation slows down, the cooling rate of the liquid decreases, the undercooling reduces, and nucleation no longer occurs. The crystals with fast growth rates in the fine-grained zone can develop along the direction opposite to heat dissipation, which is perpendicular to the mold wall. Their lateral growth is hindered due to mutual interference, thus forming columnar crystals with well-developed primary axes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释典型铸锭结构中柱状晶区的形成原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释典型铸锭结构中柱状晶区的形成原因，涉及多个材料科学概念的关联和综合分析，如冷却速率、过冷度、形核和晶体生长方向的相互影响。需要深入理解热力学和动力学过程，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对柱状晶区的形成原因进行机理深度解释。需要综合运用凝固原理、热传导和晶体生长等多方面知识，分析温度梯度、冷却速率和晶体生长方向之间的相互作用机制。虽然不涉及多因素耦合分析（等级5特征），但需要对凝固过程中的微观组织演变进行较为深入的机理解释，符合等级4的要求。" + }, + { + "idx": 843, + "question": "Indicate and explain the surface relief and shear coherency in the characteristics of martensitic transformation", + "answer": "Martensitic transformation produces uniform shear or lattice shear, causing structural changes, resulting in surface relief phenomena on the specimen. The interface between martensite and the parent phase is a coherent interface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的表面浮雕和剪切共格特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体相变的表面浮雕和剪切共格性特征，涉及对相变机制的理解和分析，需要综合运用材料科学中的相变理论、晶体学知识以及界面特性等概念进行推理和解释。这超出了简单记忆或基本应用的范围，属于对复杂现象的深入分析和解释。 | 难度: 在简答题题型中，该题目要求对马氏体相变的表面浮凸和剪切共格性进行机理深度解释，涉及对相变过程中结构变化和界面特性的综合理解。虽然不需要全面分析复杂现象，但需要对相关机理有较深入的理解和阐述，属于较高难度的简答题。" + }, + { + "idx": 844, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of perfect dislocations in FCC crystals?", + "answer": "Perfect dislocation (relatively rare in actual crystals); 1 <110> 2; screw type, edge type, mixed type; local slip or local displacement; can slip or climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释FCC晶体中完美位错的多个特征（名称、伯氏矢量、位错性质、形成方法和运动状态），需要文字解释和论述，而不是简单的选择或判断。答案也以文字描述形式呈现，符合简答题的特征。 | 知识层次: 题目主要考查对FCC晶体中完美位错的基本概念的记忆和理解，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态等基础知识点，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求回答的内容较多（包括位错名称、伯氏矢量、位错性质、形成方式和运动状态），但这些都是FCC晶体中完美位错的基础概念和特性，属于记忆性知识范畴。不需要进行复杂的体系阐述或深入分析，只需准确描述各个概念即可。相比等级1的基本定义简答，该题目对知识点的掌握要求稍高，但尚未达到等级3的复杂概念体系阐述程度。" + }, + { + "idx": 845, + "question": "Point out and explain the strict orientation relationship between the new phase and the parent phase in the characteristics of martensitic transformation", + "answer": "The main orientation relationships between martensite and the parent phase are: 1 K·S relationship; 2 G-T relationship; 3 Nishiyama relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出并解释马氏体相变中新相与母相之间的严格取向关系，答案提供了三种主要取向关系的名称，但没有选项供选择，需要文字解释和论述。 | 知识层次: 题目要求指出并解释马氏体相变中新相与母相之间的严格取向关系，涉及多个具体关系（K·S关系、G-T关系、Nishiyama关系）的列举和解释。这需要学生对马氏体相变的基本概念有深入理解，并能关联不同取向关系的具体特征和应用背景，属于中等应用层次的知识要求。 | 难度: 在简答题中属于中等难度，需要理解马氏体相变的基本概念，并能列举和解释主要的取向关系（K·S关系、G-T关系、Nishiyama关系）。虽然不需要深入的多角度分析或深度关联性分析，但仍需综合说明这些关系的特征和意义。" + }, + { + "idx": 846, + "question": "Indicate and explain the internal substructure in the characteristics of martensitic transformation", + "answer": "In addition to lattice shear, martensitic transformation also involves lattice-invariant shear, accomplished through slip or twinning, resulting in the formation of dislocation or twin substructures within the martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的内部亚结构特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释马氏体相变的内部亚结构特征，涉及晶格剪切和晶格不变剪切的机制，以及位错或孪晶亚结构的形成过程。这需要深入理解相变机理，综合分析多种因素，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对马氏体相变的内部亚结构进行机理深度解释，涉及晶格剪切和晶格不变剪切的综合运用，以及位错或孪晶亚结构的形成机制。虽然不要求全面分析复杂现象，但需要对相变机理有深入理解，属于该题型中较高难度的题目。" + }, + { + "idx": 847, + "question": "Write the reaction equation for the decomposition of a perfect dislocation into an extended dislocation in a face-centered cubic (FCC) crystal, and analyze the possibility of the reaction.", + "answer": "Taking the (111) plane as an example, there are three reaction equations for the decomposition of a perfect dislocation into an extended dislocation on this plane: \\n(1) ${\\\\frac{1}{2}}[110]{-}{\\\\frac{1}{6}}[121]+{\\\\frac{1}{6}}[21\\\\overline{{1}}]$ Geometric condition: ${\\\\frac{1}{2}}[110]={\\\\frac{1}{6}}[121]+{\\\\frac{1}{2}}[21\\\\bar{1}]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\biggl[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\biggr]={\\\\frac{1}{3}}$ Therefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed. \\n(2) $\\\\frac{1}{2}[011]{\\\\rightarrow}\\\\frac{1}{6}[121]+\\\\frac{1}{6}[\\\\overline{{{1}}}12]$ Geometric condition: ${\\\\frac{1}{2}}[011]={\\\\frac{1}{6}}[121]+{\\\\frac{1}{2}}[\\\\overline{{{1}}}12]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\Big[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\Big]={\\\\frac{1}{3}}$ Therefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed. \\n(3) $\\\\frac{1}{2}[\\\\overline{{1}}01]{\\\\rightarrow}\\\\frac{1}{6}[\\\\overline{{1}}12]+\\\\frac{1}{6}[\\\\overline{{2}}\\\\overline{{1}}1]$ Geometric condition: $\\\\frac{1}{2}[\\\\overline{{1}}01]=\\\\frac{1}{6}[\\\\overline{{1}}12]+\\\\frac{1}{6}[\\\\overline{{2}}\\\\overline{{1}}1]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\Big[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\Big]={\\\\frac{1}{3}}$ \\nTherefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出反应方程并分析反应的可能性，答案提供了详细的反应方程和几何及能量条件的分析，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求写出面心立方晶体中完美位错分解为扩展位错的反应方程，并分析反应的可能性。这需要深入理解位错理论、几何条件和能量条件，并进行综合分析。涉及多个步骤的推理和计算，以及对晶体结构和位错行为的深刻理解。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体缺陷理论、位错反应原理和能量条件分析，涉及多个反应方程的推导和验证。解题步骤包括几何条件和能量条件的双重验证，需要深入理解FCC晶体结构和位错分解机理，属于该题型内最高难度的复杂现象全面分析。" + }, + { + "idx": 848, + "question": "Point out and explain the diffusionless characteristic of martensitic transformation", + "answer": "The transformation process involves no compositional change, with all participating atoms moving in a coordinated manner, maintaining unchanged relative positions between neighboring atoms, and the relative displacement being less than one atomic spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的无扩散特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体相变的无扩散特性，涉及原子协同运动的机理和相对位移的微观描述，需要深入理解相变机制并进行推理分析，属于复杂分析层次。 | 难度: 在简答题中属于机理深度解释难度，需要准确描述马氏体相变的无扩散特性，包括原子运动方式、相对位置保持等细节，并解释其背后的物理机制。这要求对相变理论有较深入的理解和综合运用能力，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 849, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of the L-C sessile dislocation in FCC crystals?", + "answer": "L-C sessile dislocation (with multiple configurations); for example—[110] 6; screw-type, edge-type, mixed-type; formed by the synthesis of Shockley partial dislocations (or dislocation reactions); cannot move", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释L-C sessile dislocation的多个属性（名称、Burgers矢量、位错性质、形成方法和运动状态），答案提供了具体的文字描述和解释，符合简答题的特征。 | 知识层次: 题目要求对L-C sessile dislocation的多个方面（如Burgers vector、位错性质、形成方法、运动状态）进行综合描述，涉及位错理论的多个概念及其关联，需要理解和应用位错反应和运动的基本原理，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对L-C sessile dislocation的多个方面（名称、Burgers矢量、位错性质、形成方法和运动状态）进行详细说明，并需要综合运用FCC晶体中位错的相关知识。题目涉及多步概念关联和综合分析，如理解Shockley部分位错的合成过程及其对L-C sessile dislocation形成的影响。此外，还需要解释位错的不同性质（螺型、刃型、混合型）及其运动状态的限制。这些要求使得该题目在简答题中属于较高难度，需要多角度分析论述。" + }, + { + "idx": 850, + "question": "Indicate and explain the habit plane and its invariance in the characteristics of martensitic transformation", + "answer": "Martensite forms on certain crystallographic planes of the parent phase, and these planes are called habit planes. The habit plane is an undistorted and non-rotating plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变中的惯习面及其不变性特征，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查马氏体相变中习惯面的定义和基本特征，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。题目要求解释马氏体相变中的惯习面及其不变性特征，需要考生不仅记住基本定义，还要能够描述惯习面的特性（如无畸变、不旋转等）。这比单纯复述定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。属于基础概念记忆题型中中等偏上的难度。" + }, + { + "idx": 851, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of the Shockley partial dislocation in FCC crystals?", + "answer": "Shockley partial dislocation; 1 <112> 6; screw-type, edge-type, mixed-type; can only be formed through local slip of the crystal; even edge-type partial dislocations can only slip, not climb. Even screw-type partial dislocations cannot cross-slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释和描述Shockley partial dislocation的多个方面，包括名称、Burgers向量、位错性质、形成方法和运动状态。答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求对Shockley partial dislocation的多个属性（名称、Burgers向量、位错性质、形成方式、运动状态）进行详细描述，涉及多个概念的关联和综合分析。虽然不涉及复杂计算或深度推理，但需要将多个知识点整合并准确表述，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对Shockley partial dislocation的多个方面进行详细说明，包括名称、Burgers向量、位错性质、形成方法和运动状态。这需要学生不仅掌握相关概念，还需要能够将这些概念关联起来进行综合分析。此外，题目还涉及到位错的具体行为和限制条件，这增加了问题的复杂性。虽然不需要进行深度关联性分析（如等级5所要求的），但多角度分析论述的要求使得该题目在同题型内属于较高难度。" + }, + { + "idx": 852, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of the Frank partial dislocation in FCC crystals?", + "answer": "Frank partial dislocation; 1 <111> 3; edge type; formed by inserting or removing a layer of {111} close-packed plane in a local region of the crystal; can only climb, cannot glide", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Frank partial dislocation的多个属性（名称、Burgers向量、位错性质、形成方法和运动状态），答案提供了详细的文字描述而非选择、判断或计算。 | 知识层次: 题目要求对Frank partial dislocation的多个属性进行综合描述，包括Burgers向量、位错性质、形成方法和运动状态，需要理解并关联多个概念，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求考生不仅需要准确识别Frank不全位错的名称、伯氏矢量、位错性质等基本概念，还需要理解其形成机制和运动状态。这涉及到对FCC晶体结构、位错理论以及塑性变形机制的深入理解，并要求考生能够将这些概念关联起来进行综合分析。虽然不需要进行复杂的数学计算，但需要清晰的物理概念和系统的知识整合能力，因此属于该题型内较高难度的题目。" + }, + { + "idx": 854, + "question": "When the vacancy equilibrium concentration in germanium crystals decreases by six orders of magnitude from $600\\\\%$ to $300\\\\mathrm{\\\\textperthousand}$, calculate the vacancy formation energy in germanium crystals (Boltzmann constant $k=8.617\\\\times10^{-5}\\\\mathrm{eV}/\\\\mathrm{K})$.", + "answer": "The equilibrium concentration formula for Schottky defects is: $$\\\\begin{array}{r l}&{\\\\mathrm{atsing~sefiell}\\\\eta+\\\\mathrm{fight}\\\\mathcal{R}\\\\Sigma\\\\Delta t:}\\\\ &{\\\\qquad\\\\overline{{C}}_{\\\\mathrm{s}}\\\\leq e\\\\Bigg\\\\{-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg\\\\}=\\\\mathrm{evel}\\\\Bigg(-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg)=\\\\mathrm{evel}\\\\Bigg(-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg)}\\\\ &{\\\\mathrm{atsin}}\\\\ &{\\\\frac{\\\\Delta C_{s}}{H\\\\mathcal{N}_{x}\\\\Gamma}=-\\\\mathrm{in}\\\\overline{{C}}_{s},}\\\\ &{\\\\frac{\\\\Delta C_{s}}{\\\\Delta W_{x}}\\\\Bigg(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\Bigg)=\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}-\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}}\\\\ &{\\\\Delta G_{s}=\\\\frac{\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}-\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}}{\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}}(k\\\\chi_{x})}\\\\ &{\\\\qquad-\\\\frac{1}{\\\\frac{\\\\mathrm{fim}}{2}-\\\\frac{1}{T_{2}}}\\\\frac{\\\\kappa_{\\\\mathrm{B}}\\\\lambda_{1}\\\\Gamma\\\\kappa_{\\\\mathrm{m}}t^{-1}}{-\\\\frac{1}{\\\\omega_{0}+2/3}}}\\\\ &{\\\\qquad\\\\frac{1}{3(\\\\omega+2/3)}-\\\\frac{1}{6(\\\\omega+2/3)}}\\\\ &{\\\\qquad\\\\nu\\\\neq\\\\ell\\\\geq\\\\frac{1}{\\\\mathrm{in}\\\\mathcal{L}_{x}\\\\Bigg\\\\{1,2,3\\\\}\\\\Gamma\\\\kappa_{\\\\mathrm{m}}\\\\mathcal{R}_{x}\\\\Bigg\\\\}.}\\\\end{array}$$ That is, $10^{5}\\\\mathrm{J}^{\\\\cdot}\\\\mathrm{mol}^{-1}$ in germanium crystals.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空位形成能，答案中包含了详细的公式推导和数值计算过程。 | 知识层次: 题目涉及多步计算和公式应用，需要理解Schottky缺陷的平衡浓度公式，并进行数值计算和温度转换。虽然不涉及复杂的推理分析或机理解释，但需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用Schottky缺陷的平衡浓度公式，进行多步计算和温度转换，涉及对数运算和能量单位的转换。虽然计算步骤较多，但公式应用和计算过程相对明确，属于中等偏上的难度。" + }, + { + "idx": 855, + "question": "Explain one of the main mechanisms of alloy strengthening from a microstructural perspective: solid solution strengthening, and provide examples", + "answer": "Solid solution strengthening occurs when alloying atoms dissolved in the lattice interstices or lattice points, due to their different sizes compared to the matrix atoms, create stress fields that hinder dislocation movement. Examples include Cottrell atmospheres and Suzuki atmospheres. The former refers to interstitial atoms preferentially distributing in the tensile stress region of edge dislocations in BCC metals, pinning the dislocations. The latter involves alloying elements preferentially distributing in the stacking fault regions of extended dislocations in FCC metals, reducing stacking fault energy, expanding the stacking fault region, and making the slip of extended dislocations more difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的主要机制之一（固溶强化），并从微观结构角度进行说明，同时提供例子。答案需要详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释固溶强化的主要机制，并提供具体例子（Cottrell和Suzuki气团）。这需要深入理解位错与溶质原子的相互作用机制，分析应力场对位错运动的阻碍作用，以及不同晶体结构（BCC/FCC）中的具体表现。解答过程涉及位错理论、晶体缺陷和合金强化机理的综合运用，属于需要推理分析和机理解释的复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对固溶强化的微观机理进行深度解释，包括位错与溶质原子的相互作用机制（如Cottrell和Suzuki气团），并需要结合BCC/FCC晶体结构特性分析其对位错运动的阻碍作用。虽然未涉及多机制交叉分析（如与析出强化对比），但已超出基础概念复述层面，属于机理深度解释范畴，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 856, + "question": "Explain the second main mechanism of alloy strengthening from the microstructure perspective: precipitation strengthening and dispersion strengthening, and provide examples", + "answer": "Alloy strengthening is caused by compounds of alloying elements and matrix elements obtained through phase transformation processes and hard particles mechanically mixed into the matrix material, which are referred to as precipitation strengthening and dispersion strengthening, respectively. The effects of precipitation strengthening and dispersion strengthening are far greater than those of solid solution strengthening. When dislocations encounter second phases during movement, they need to cut through (small-sized particles in precipitation strengthening and particles in dispersion strengthening) or bypass (large-sized particles in precipitation strengthening) the second phases. Therefore, the second phases (precipitates and dispersoids) hinder dislocation movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第二种主要机制，并从微观结构角度详细说明沉淀强化和弥散强化，同时提供例子。答案需要详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释合金强化的第二种主要机制（沉淀强化和弥散强化），并提供实例。这需要综合运用材料科学中的相变、位错理论、第二相强化等知识，进行机理分析和解释。不仅需要理解基本概念，还需要分析位错与第二相粒子的相互作用机制（切割或绕过），并能够举例说明，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对合金强化的两种主要机制（沉淀强化和弥散强化）从微观结构角度进行解释，并举例说明。这需要考生不仅理解基本概念，还需要深入掌握相关机理，如位错与第二相的相互作用（切割或绕过）。此外，题目还要求考生能够综合运用知识，分析不同强化机制的效果差异。虽然题目未要求极端复杂的推导或跨学科整合，但在简答题框架内仍属于机理深度解释的较高难度等级。" + }, + { + "idx": 857, + "question": "When an aluminum (Al) single crystal is stretched along the [123] direction to induce plastic deformation, determine the rotation law and rotation axis of the crystal during double slip.", + "answer": "During double slip, the specimen axis rotates toward [101], with the rotation axis being n1=[11¯2]×[10¯1]=[¯1¯1¯1], and also rotates toward [011], with the rotation axis being n2=[11¯2]×[01¯1]=[111]. Therefore, the resultant rotation axis is n=n1+ n2=[000], meaning the crystal orientation no longer changes and is only elongated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述晶体在双滑移过程中的旋转规律和旋转轴，答案提供了详细的文字解释和推导过程，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析铝单晶在双滑移过程中的旋转规律和旋转轴，涉及晶体塑性变形的机理、滑移系统的相互作用以及旋转轴的确定。这需要综合运用晶体学、塑性变形理论和向量运算等多方面知识，并进行推理分析，属于复杂分析的层次。 | 难度: 在简答题中属于最高难度等级，需要综合运用晶体塑性变形理论、滑移系分析、矢量运算等多方面知识。题目要求解释双滑移条件下的晶体旋转规律，涉及复杂的矢量叉乘运算和空间几何分析，最终还需综合两个旋转轴得出\"晶体取向不再变化\"的结论。这种需要多步骤推理和综合判断的机理解释题，在简答题题型中属于最复杂的分析层次。" + }, + { + "idx": 858, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Please determine the double slip systems.", + "answer": "When point F1 moves to point F2, double slip occurs. The double slip systems are:", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定双滑移系统，答案提供了具体的滑移系统描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求确定铝单晶在[123]方向拉伸变形时的双滑移系统，这需要深入理解晶体塑性变形机制、滑移系统的几何关系以及施密特因子计算等复杂概念。解答过程涉及多个知识点的综合运用和推理分析，包括晶体取向分析、滑移系统激活条件判断以及双滑移的几何条件确定，属于较高层次的综合分析能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体塑性变形理论、滑移系统分析以及方向向量计算等知识，解题步骤涉及多个复杂推理环节（如确定初始滑移系统、分析双滑移条件、验证滑移系统组合等），属于该题型框架内对综合分析和机理解释要求最高的复杂现象全面分析类题目。" + }, + { + "idx": 859, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Determine the rotation rule and rotation axis.", + "answer": "During single slip, the specimen axis should rotate towards [101], and the rotation axis is [12¯3]×[10¯1]=[¯1¯1¯1].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定旋转规则和旋转轴，答案提供了详细的推导过程和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求确定单晶铝在拉伸变形过程中的旋转规则和旋转轴，这需要综合运用晶体塑性变形的基本原理、滑移系统的选择、晶体取向变化等知识，并进行推理分析。解答过程涉及多个步骤的概念关联和综合分析，包括确定滑移方向、计算旋转轴等，思维深度要求较高。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 860, + "question": "Explain one of the main mechanisms of alloy strengthening from the microstructure perspective: order strengthening, and provide an example", + "answer": "In ordered alloys, dislocations are superdislocations. To induce plastic deformation in the metal, both partial dislocations of the superdislocation must move simultaneously, requiring greater external stress. The bonding force between atoms of different elements is stronger than that between atoms of the same element, so the ordered arrangement of dissimilar atoms imparts higher strength to ordered alloys. For example, high-strength nickel-based superalloys contain ordered precipitate phases Ni(Ti, Al), whose strengthening mechanisms include general precipitation strengthening and order strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的主要机制之一（有序强化），并提供例子。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求从微观结构角度解释合金强化的主要机制之一——有序强化，并提供一个实例。这需要深入理解有序合金中位错的行为、原子间相互作用以及强化机制的综合分析。此外，还需要将理论知识与实际应用（如镍基高温合金）相结合，展示对机理的深度理解和综合运用能力。 | 难度: 在简答题的复杂分析层次中，该题目要求对合金强化机制中的有序强化进行机理深度解释，并举例说明。这需要学生不仅理解有序合金的基本概念，还要掌握超位错、塑性变形机制以及不同元素原子间键合力的差异等较为深入的材料科学知识。虽然题目没有要求对比多种强化机制或进行更复杂的综合分析，但对单一机制的解释已经达到了机理深度解释的要求，因此在简答题的复杂分析层次中属于等级4难度。" + }, + { + "idx": 861, + "question": "Stretch the aluminum (Al) single crystal along the [123] direction to induce plastic deformation, determine the final orientation of the crystal.", + "answer": "The final orientation of the crystal is F2, namely [112].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过分析和论述确定晶体变形后的最终取向，答案需要文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求确定铝单晶在特定方向拉伸塑性变形后的最终取向，这需要理解晶体塑性变形机制、滑移系统激活、晶格旋转等复杂概念，并进行综合分析。涉及多个知识点的关联和推理分析，思维过程深度较高。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求对铝单晶沿[123]方向拉伸塑性变形后的最终取向进行确定，这需要综合运用晶体塑性变形理论、滑移系开动条件以及晶体取向变化规律等知识。解题过程中需要分析初始取向、可能的滑移系、转动规律等，并进行合理的推理和计算，最终得出[112]取向的结论。虽然不涉及多因素耦合等更复杂现象的分析，但对机理的理解和解释深度要求较高，因此属于等级4。" + }, + { + "idx": 862, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Determine the crystal orientation and shear strain at the onset of double slip.", + "answer": "It can be calculated as follows: L=l+γ(l⋅n)b Substituting into the above equation: [m] =[123] + [[123][][10] √3 1√2 Thus, v=1+γ4/√6=2, W=−3−γ4/√6 Solving gives v=2, w=−4, γ=√6/4 That is, the orientation at the onset of double slip is [112], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体取向和剪切应变，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目涉及晶体塑性变形中的双滑移起始条件计算，需要应用晶体学方向计算和剪切应变公式，进行多步计算和概念关联，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求确定晶体取向和剪切应变，涉及向量运算和方程求解，步骤较为复杂，但未达到多变量计算的最高难度。" + }, + { + "idx": 863, + "question": "Explain one of the three main mechanisms of alloy strengthening from a microstructural perspective: grain boundary strengthening, and provide an example", + "answer": "According to the Hall-Petch formula, the relationship between the yield point σs and the grain diameter d is σs=σ0+k d^(-1/2). The essence is that additional stress is required for dislocations to cross grain boundaries. Therefore, steels for low-temperature applications often adopt a fine-grained structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从微观结构角度解释合金强化的主要机制之一（晶界强化），并提供实例。答案通过文字解释和论述来回答问题，涉及公式引用和实际应用举例，符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释合金强化的主要机制之一——晶界强化，并提供一个例子。这需要理解Hall-Petch公式及其物理意义，同时能够将理论知识与实际应用（如低温用钢的细晶结构）联系起来。虽然涉及公式，但更强调概念的理解和应用，属于中等难度的应用层次。 | 难度: 在简答题中属于中等难度，需要理解合金强化的微观结构机制，并能够运用Hall-Petch公式进行解释。题目要求从微观结构角度分析晶界强化，并提供一个实例，这需要综合分析和说明的能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 864, + "question": "There are two edge dislocations 1 and 2 separated by a distance d, with Burgers vectors b₁ and b₂ respectively. Given the stress field of the edge dislocation as σ_x, σ_y, σ_z, τ_xy, determine the climb force on dislocation 2 due to dislocation 1.", + "answer": "The climb force f_{y,12} = σ_x b₂ = - (G b₁ b₂) / (2π(1-ν)) * (d(3x² + d²)) / (x² + d²)²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的应力场和Burgers向量计算位错2的攀移力，涉及数值计算和公式应用。答案给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错的应力场及其相互作用，并应用相关公式进行计算。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要理解位错的应力场和相互作用力的概念，并进行多步计算。虽然涉及多个变量和公式应用，但解题步骤相对明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 865, + "question": "There are two edge dislocations 1 and 2 separated by a distance d, with Burgers vectors b₁ and b₂, respectively. Given the stress field of an edge dislocation as σ_x, σ_y, σ_z, τ_xy, determine the glide force on dislocation 2 caused by dislocation 1.", + "answer": "The glide force f_{x,12} = -τ_{xy}b₂ = - (G b₁ b₂) / (2π(1-ν)) * (x(x² - d²)) / (x² + d²)²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的应力场和参数计算滑移力，涉及公式应用和数值计算，答案也给出了具体的计算公式和结果。 | 知识层次: 题目涉及两个刃位错之间的相互作用力计算，需要理解位错的应力场公式，并应用该公式进行多步计算。虽然题目给出了应力场公式，但仍需理解并正确应用公式来计算相互作用力，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解应力场公式并应用多步计算过程，涉及多个变量（距离d、Burgers向量b₁和b₂、材料常数G和ν）的综合分析，但未达到复杂多变量计算的最高难度。" + }, + { + "idx": 866, + "question": "Write the expression for the equilibrium concentration of point defects and indicate the physical meaning of each parameter.", + "answer": "The Schottky defect concentration Cs = exp(-ΔGs/RT), where Cs is the equilibrium concentration of Schottky point defects; ΔGs is the molar Gibbs free energy of formation for Schottky point defects; T is the thermodynamic temperature (K) of the system; R is the molar gas constant. The Frenkel defect concentration CF = exp(-ΔGF/RT), where CF is the equilibrium concentration of Frenkel point defects; ΔGF is the molar Gibbs free energy of formation for Frenkel point defects; T is the thermodynamic temperature (K) of the system; R is the molar gas constant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出点缺陷的平衡浓度表达式并解释每个参数的物理意义，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对Schottky和Frenkel点缺陷平衡浓度表达式的记忆，以及各参数物理意义的理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求写出点缺陷平衡浓度的表达式并解释各参数的物理意义，这需要学生对Schottky缺陷和Frenkel缺陷的基本概念有清晰理解，并能准确表述相关公式和参数含义。虽然涉及两个不同类型的点缺陷，但都属于基础概念的记忆和解释范畴，不需要进行复杂的推导或综合分析，因此属于该题型中的中等难度。" + }, + { + "idx": 867, + "question": "There are two single-crystal Zn rods (Zn has an HCP structure with c/a=1.86), with the axial direction [0001]. Now, under room temperature conditions, they are stretched along the axial direction. Analyze the possible deformation modes and write the corresponding slip systems or twinning systems (if activated).", + "answer": "When the Zn rod with the axial direction [0001] is stretched along the axial direction, the axial elongation occurs, which is opposite to the length change trend during twinning, so twinning is not possible. During stretching, the external force is along the axial direction [0001], perpendicular to the slip plane (0001), so the Schmid factor is 0, and slip cannot occur. Therefore, when the Zn rod with the axial direction [0001] is stretched along the axial direction, the Zn rod will fracture in a brittle manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析可能的变形模式并写出相应的滑移系统或孪生系统（如果被激活），这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析HCP结构Zn单晶在特定轴向拉伸条件下的变形模式，涉及对滑移系和孪生系激活条件的深入理解，需要综合运用晶体学、力学和材料变形机制的知识进行推理分析。解答过程需要判断Schmid因子、变形模式的可行性，并解释脆性断裂的原因，体现了较高的思维深度和综合分析能力。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用晶体结构、变形机制和力学原理进行深入分析。具体包括：" + }, + { + "idx": 868, + "question": "Write the expression for the relationship between the diffusion coefficient and temperature, and indicate the physical meaning of each parameter.", + "answer": "D=D0exp(-Q/RT), where D0 is the diffusion constant or frequency factor; Q is the diffusion activation energy (J/mol); T is the thermodynamic temperature of the system (K); R is the molar gas constant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出扩散系数与温度关系的表达式，并解释各参数的物理意义。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求写出扩散系数与温度关系的表达式并解释各参数的物理意义，这属于基本公式的直接应用和简单解释，不需要复杂的分析或多步计算。 | 难度: 在简答题中属于基础难度，仅要求写出扩散系数与温度关系的表达式并解释各参数物理意义，无需推导或实例说明，属于直接套用基本公式的简单应用过程描述。" + }, + { + "idx": 870, + "question": "What are the three typical zones of a metal ingot structure?", + "answer": "Chill zone, columnar crystal zone, and equiaxed crystal zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属铸锭结构的三个典型区域，需要用文字简要回答，不需要计算或选择，属于简答题类型 | 知识层次: 题目考查金属铸锭结构的三个典型区域的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题中属于基本定义简答，仅需记忆金属铸锭的三个典型区域名称（激冷区、柱状晶区、等轴晶区），无需深入解释或复杂分析，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 872, + "question": "Many precipitate phases have specific orientation relationships with the parent matrix. Analyze the reasons for the formation of such orientation relationships.", + "answer": "To achieve low interfacial energy, the atoms on the primary interface between the parent phase and the new phase must have a good matching relationship, which can only be realized under certain orientation conditions. Therefore, specific orientation relationships exist between the precipitate phase and the parent phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析特定取向关系形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析析出相与母相特定取向关系形成的原因，涉及界面能、原子匹配关系等机理的解释，需要综合运用材料科学中的相变、晶体学等知识进行推理分析，思维过程较为深入。 | 难度: 在简答题的复杂分析题型中，该题目要求对析出相与母相特定取向关系的形成原因进行机理深度解释。需要综合运用界面能、原子匹配等核心概念，并建立多因素间的逻辑关联。虽然不涉及多现象综合分析（等级5特征），但已超出基础概念复述层面，属于需要深入理解材料相变原理的机理分析题。" + }, + { + "idx": 873, + "question": "What is the Kirkendall effect", + "answer": "On an FCC-structured α-brass (Cu+30%Zn) rod, very fine molybdenum wires are applied as markers, and then copper is plated on the brass, enclosing the molybdenum wires between the brass and copper. Diffusion is carried out at a certain temperature. The molybdenum wires serve only as markers and do not participate in the diffusion throughout the experiment. The diffusing components are copper and zinc, which form a substitutional solid solution. During the diffusion process in a substitutional solid solution, the markers placed at the original interface move toward the direction of the lower melting point element, with the displacement distance following a parabolic relationship with time. The reason for this phenomenon is that the lower melting point component diffuses faster, while the higher melting point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应的定义和原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要详细描述实验过程、扩散机制以及不同元素扩散速率的差异对标记物移动的影响。这涉及对扩散过程的深入理解、多步骤的实验现象分析以及机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求详细解释Kirkendall效应的机理，包括扩散过程中的原子交换、标记物的移动方向与时间的关系，以及不同元素扩散速率的差异导致的宏观现象。这不仅需要深入理解扩散的基本原理，还需要能够综合运用这些知识来解释复杂的实验现象。此外，题目还涉及具体的材料系统（FCC结构的α黄铜和铜的扩散对）和实验细节（钼丝作为标记物），进一步增加了分析的复杂性和深度。因此，该题目在同题型内属于最高难度等级。" + }, + { + "idx": 874, + "question": "Propose three technical approaches to achieve the aforementioned zone enlargement, and briefly explain the theoretical basis.", + "answer": "1. Add refiners to promote heterogeneous nucleation; 2. Apply mechanical vibration to reduce dendrites and provide new nuclei; 3. Perform ultrasonic treatment or electromagnetic field treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提出三种技术方法并简要解释理论基础，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求提出三种技术方法并解释理论依据，涉及多步骤的思考和应用，需要将不同的技术手段与理论原理关联起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求提出三种技术方法并解释理论依据，涉及多角度分析和概念关联。虽然不需要深度关联性分析（等级5），但需要综合运用知识进行多步论述，超出了基础解释的范畴（等级3），属于中等偏上的难度。" + }, + { + "idx": 875, + "question": "What is the Kirkendall effect? Please explain it using diffusion theory.", + "answer": "Kirkendall effect: In the diffusion process of substitutional solid solutions, markers placed at the original interface move towards the direction of the low-melting-point element, with the movement rate following a parabolic relationship with time. The Kirkendall effect negates the exchange mechanism of diffusion in substitutional solid solutions and confirms the vacancy mechanism; different components in the system have different partial diffusion coefficients. Relatively speaking, the low-melting-point component diffuses faster, while the high-melting-point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应并用扩散理论进行说明，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要运用扩散理论进行机理分析，涉及不同组分的扩散系数差异和空位机制等复杂概念，需要综合理解和推理分析能力。 | 难度: 在简答题题型中，该题目要求对Kirkendall效应进行机理深度解释，涉及扩散理论、置换固溶体中的扩散机制以及空位机制等复杂概念的综合运用。需要考生不仅理解基本概念，还能进行推理分析，解释不同组分的扩散系数差异及其导致的宏观现象。这在该题型内属于较高难度的题目，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 876, + "question": "To obtain a casting with uniform composition and performance, which zone should be expanded?", + "answer": "To obtain a casting with uniform composition, the equiaxed crystal zone should be expanded.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释来回答问题，答案是一个简短的论述而非选择或判断 | 知识层次: 题目考查对铸造过程中晶区分布的基础概念记忆和理解，属于基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释如何获得成分均匀的铸件，并指出需要扩大等轴晶区。这需要学生对铸件组织分区（如等轴晶区、柱状晶区等）有基本理解，并能将特定区域（等轴晶区）与铸件性能（成分均匀性）建立联系。虽然涉及多个概念，但不需要复杂推导或体系化阐述，属于对基础概念的应用性解释。" + }, + { + "idx": 877, + "question": "Determine whether the following dislocation reaction can occur in FCC and confirm the reaction direction in the absence of external force: 1/6[112]+1/6[110]⇔1/3[111]", + "answer": "It can occur, to the left.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求判断位错反应是否可以在FCC中发生，并确认反应方向，需要文字解释和论述，答案形式为简短的文字说明而非选择或计算。 | 知识层次: 题目要求判断位错反应在FCC晶体中是否能够发生，并确定反应方向，这需要对位错反应的能量条件、晶体结构以及位错线方向有深入的理解和分析。此外，题目还要求在无外力作用下确认反应方向，这涉及到位错反应的驱动力和能量变化，属于综合运用和推理分析的范畴。 | 难度: 在简答题中属于机理深度解释难度，需要综合运用位错理论、晶体学知识进行矢量计算和能量分析，并判断反应方向。虽然不涉及多因素耦合分析，但对机理理解深度要求较高。" + }, + { + "idx": 878, + "question": "During the aging treatment of alloy A, metastable phases often precipitate first. Discuss the reasons why the equilibrium phase does not precipitate based on thermodynamic and kinetic theories.", + "answer": "The initial precipitation of metastable phases occurs because the interfacial energy between the equilibrium phase and the parent phase is high, whereas that between the metastable phase and the parent phase is low. Interfacial energy is the primary energy barrier for nucleation during solid-state phase transformation. Overcoming this nucleation barrier for the equilibrium phase often requires significant undercooling before noticeable nucleation can occur in the system. From a kinetic perspective, at a certain degree of undercooling, if the metastable phase forms much faster than the equilibrium phase, which forms much more slowly, the alloy will preferentially form metastable phases during aging treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于热力学和动力学理论讨论平衡相不析出的原因，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释和理论依据，符合简答题的特征。 | 知识层次: 题目要求基于热力学和动力学理论解释合金时效处理中亚稳相优先析出的原因，涉及界面能、形核势垒和过冷度等概念的关联分析，需要综合运用多个知识点进行机理层面的推理和解释，思维深度较高。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用热力学和动力学理论来解释合金时效处理中亚稳相优先析出的复杂现象。需要深入理解界面能、形核势垒和过冷度等核心概念，并能将这些概念有机结合起来进行机理分析。同时，题目要求从热力学和动力学两个维度进行论述，体现了对知识整合能力和综合分析能力的高要求，属于该题型下最高难度的题目类型。" + }, + { + "idx": 879, + "question": "Two batches of industrial pure aluminum samples were rolled with the same deformation amount on June 5 and June 9, respectively, and then subjected to recrystallization annealing simultaneously on the 9th. The experiment found that for the same annealing time, the temperatures required to complete recrystallization were different for the two batches of samples. Which batch do you think has a higher recrystallization temperature, and why?", + "answer": "The sample deformed on June 5 may have undergone partial recovery during storage, as the stored deformation energy decreases. To initiate recrystallization, it requires higher activation energy compared to the sample that was not stored. Therefore, the sample from June 5 has a higher recrystallization temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么两批样品的再结晶温度不同，并需要文字论述原因，答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的变形、储存能、回复和再结晶等概念，分析不同时间变形对再结晶温度的影响机制。这涉及到对材料微观结构变化的理解和推理分析，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解再结晶的基本概念，还需要综合运用材料存储过程中的回复现象、变形能储存与释放机制等知识进行推理分析。解题时需要建立时间-存储-回复-再结晶温度之间的完整逻辑链条，并准确解释不同批次样品性能差异的微观机理。虽然不涉及多因素交互作用的复杂现象分析（等级5特征），但对材料科学原理的掌握深度和机理解释能力要求较高，符合等级4的标准。" + }, + { + "idx": 880, + "question": "Briefly describe Pauling's rules", + "answer": "Pauling's rules: $\\textcircled{1}$ The coordination polyhedron rule: A coordination polyhedron of anions is formed around a cation. The distance between the cation and anion depends on the sum of their ionic radii, while the coordination number depends on the ratio of their ionic radii. $\\textcircled{2}$ The electrostatic valence rule: In forming an ionic bond, the number of valence electrons given by the cation equals the number received by the anion. $\\textcircled{3}$ The rule of polyhedron linkage: Coordination polyhedra tend to share vertices, followed by edges and faces. The higher the cation's valence and the lower its coordination number, the more pronounced this effect. $\\textcircled{4}$ In crystals containing more than one type of cation, the coordination polyhedra of anions around cations with higher valence and smaller coordination numbers tend to share vertices. $\\textcircled{5}$ The types of coordination polyhedra in a crystal tend to be minimal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Pauling's rules，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对Pauling's rules的基本概念的记忆和理解，包括其五个规则的描述，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求完整阐述Pauling的五条规则，涉及多个复杂概念体系的联动解释。相比简单定义题（等级1）或单一概念描述题（等级2），本题需要系统梳理不同规则间的逻辑关系（如配位多面体与静电价规则的关联），并准确表述各规则的核心要点（如配位多面体连接方式与阳离子价态的关系）。这种对晶体化学基础理论的整合性论述要求，符合该题型下最高难度等级的特征。" + }, + { + "idx": 881, + "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, determine the lattice constant a of diamond.", + "answer": "The nearest neighbor atomic spacing is 0.1544nm, i.e., the bond length d = 0.1544nm. In the diamond structure, the relationship between the bond length and the lattice constant is d = (a√3)/4, thus a = (4d)/√3 = (4 × 0.1544nm)/1.732 ≈ 0.3566nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（d = (a√3)/4）来确定晶格常数a，解答过程涉及具体的数学运算和单位转换，最终得出数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过已知的原子间距和钻石结构的几何关系来计算晶格常数。虽然需要理解钻石结构中的原子排列和几何关系，但整体思维过程较为直接，属于基本公式的套用和简单计算范畴。 | 难度: 在计算题中属于简单公式应用计算难度。题目只需要应用一个基本公式（d = (a√3)/4）并进行简单的代数运算即可得出结果。虽然需要理解金刚石结构中原子间距与晶格常数的关系，但解题步骤直接且无需组合多个公式或进行复杂推导。" + }, + { + "idx": 882, + "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, determine the coordination number C.N. of diamond.", + "answer": "In the diamond structure, each carbon atom forms covalent bonds with 4 nearest neighbor carbon atoms, so the coordination number C.N. = 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来确定金刚石结构中的配位数，答案提供了详细的解释和结论，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对金刚石晶体结构中配位数这一基本概念的记忆和理解，仅需直接回答配位数而不涉及计算或复杂分析。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述钻石结构中碳原子的配位数这一基本概念，无需额外解释或复杂推理步骤。" + }, + { + "idx": 883, + "question": "A compression test is conducted along the axial direction of an FCC metal single crystal specimen with a cross-sectional area of 10cm². The critical resolved shear stress is known to be 0.1kgf/mm², and the initial orientation of the rod axis is [215]. Please determine the double slip systems.", + "answer": "Double slip systems: (111)[011] + (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定双滑移系统，需要基于晶体学知识和施密特定律进行分析和论述，答案以文字形式给出具体的滑移系统组合，而非简单的选择、判断或数值计算。 | 知识层次: 题目要求确定双滑移系统，需要理解FCC晶体结构、滑移系统的基本原理，并能应用施密特定律进行多步计算和分析。虽然不涉及复杂的推理或创新设计，但需要综合运用多个知识点并进行适当的计算和判断。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识、滑移系计算和临界分切应力概念。解题过程涉及：1) 确定FCC晶体可能的滑移系；2) 计算施密特因子；3) 判断主次滑移系；4) 验证双滑移条件。要求考生能够将晶体取向、应力状态与滑移系激活条件进行多角度关联分析，并准确表述双滑移系统的判定依据。" + }, + { + "idx": 884, + "question": "Determine whether the following dislocation reaction can occur in FCC and confirm the reaction direction in the absence of external forces: 1/2[10−1]⇔1/6[2−1−1]+1/6[11−1]", + "answer": "It can occur, to the right.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否可以在FCC中发生，并确认反应方向，答案是一个明确的判断（\"It can occur, to the right\"），这符合判断题的特征。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应是否可行以及反应方向。这涉及到多步分析和概念关联，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在判断题题型中，该题目属于中等应用层次，需要综合运用位错反应的能量条件和几何条件进行多步分析。具体包括：1) 验证矢量守恒关系 2) 计算反应前后的能量变化 3) 判断反应方向性。这些步骤涉及多个概念的综合运用和计算验证，比简单的正误判断更为复杂，但尚未达到需要复杂推理过程的最高难度。" + }, + { + "idx": 885, + "question": "A single crystal specimen of an FCC metal with a cross-sectional area of 10cm² is subjected to a compression test along its axial direction. Given that the critical resolved shear stress is 0.1kgf/mm² and the initial orientation of the rod axis is [215], determine the crystal orientation (i.e., the direction of the rod axis) when double slip begins.", + "answer": "The crystal orientation when double slip begins is: [102].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定晶体取向，需要文字解释和论述，答案以特定方向表示，不涉及选择、判断或数值计算。 | 知识层次: 题目需要理解FCC金属的滑移系统、临界分切应力概念，并进行多步计算来确定双滑移开始时的晶体取向。这涉及晶体学方向的计算和综合分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学、力学和材料科学的知识。解题步骤包括确定滑移系统、计算施密特因子、分析双滑移条件等，涉及多步计算和概念关联。此外，题目要求对晶体取向变化进行综合分析，需要较强的空间想象能力和数学推导能力。" + }, + { + "idx": 886, + "question": "A single crystal test bar of an FCC metal with a cross-sectional area of 10 cm² is subjected to a compression test along the axial direction. The critical resolved shear stress is known to be 0.1 kgf/mm², and the initial orientation of the bar axis is [215]. Please determine the initial slip system (specific indices are required).", + "answer": "Initial slip system: (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定初始滑移系统（需要具体的指数），这需要文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目需要确定FCC金属的初始滑移系统，涉及晶体取向和临界分切应力的计算。这需要理解FCC晶体的滑移系统（如(111)[011]），并能将晶体取向[215]与滑移系统关联起来进行计算。虽然不涉及多步复杂计算，但需要对晶体学概念和力学性能有较好的理解和应用能力。 | 难度: 在简答题中属于中等难度，需要理解晶体滑移系统的基本概念，进行多步计算（包括确定滑移面和滑移方向），并综合分析初始取向与滑移系统的关系。虽然涉及多个步骤和概念关联，但解题路径相对明确，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 887, + "question": "Term explanation: Lattice distortion", + "answer": "In local regions, atoms deviate from their normal lattice equilibrium positions, causing lattice distortion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Lattice distortion\"进行解释，答案是以文字形式给出的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"Lattice distortion\"这一基本概念的定义记忆和理解，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"Lattice distortion\"进行基本定义解释，不需要展开描述或进行复杂概念体系的阐述。题目答案直接给出了该术语的核心定义，属于最基础的概念记忆层次，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 888, + "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, calculate the packing density ξ of diamond.", + "answer": "The diamond unit cell contains 8 atoms (each of the 8 corner atoms contributes 1/8, each of the 6 face-centered atoms contributes 1/2, and each of the 4 internal atoms contributes 1). The atomic radius r = d/2 = 0.0772nm. The packing density ξ = (total volume of atoms)/(volume of unit cell) = [(8 × (4/3)πr³)]/a³ = [8 × (4/3) × 3.1416 × (0.0772nm)³]/(0.3566nm)³ ≈ 0.34.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解金刚石的堆积密度，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算，包括原子半径的计算、单位晶胞体积的计算以及原子总体积的计算，并需要理解金刚石晶胞的结构和原子排列方式。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个概念和公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解钻石晶胞的结构、原子间距与半径的关系、晶胞体积计算以及堆积密度的概念。解题过程涉及多步计算和公式应用，包括原子半径计算、晶胞体积推导和堆积密度公式的综合运用。虽然计算步骤较多，但各步骤逻辑清晰，属于该题型内的中等偏上难度。" + }, + { + "idx": 889, + "question": "Determine whether the following dislocation reaction can proceed in FCC and confirm the reaction direction in the absence of external forces: 1/3[112]+1/2[111]⇔1/6[11−1]", + "answer": "The reaction cannot proceed.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否可以进行，并给出明确的结论（The reaction cannot proceed），这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应是否能够进行。这涉及到对位错能量和方向的综合分析，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要综合分析位错反应的能量条件和几何条件，涉及多步计算和概念关联，判断过程较为复杂。" + }, + { + "idx": 890, + "question": "If diffusion occurs in a Cu-Al diffusion couple, in which direction will the interface marker move?", + "answer": "When diffusion occurs in a Cu-Al diffusion couple, the interface marker will move toward the Al side.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述，答案是一个简短的文字解释，说明界面标记移动的方向，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解扩散偶中界面标记移动的原理，涉及不同元素扩散速率的比较和Kirkendall效应的应用，属于中等应用层次。需要将基本概念与具体现象关联，进行一定的综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及扩散偶的概念和界面标记移动方向的分析，但只需要基于基本的扩散原理和柯肯达尔效应进行解释，不需要进行多角度或深度关联性分析。解题步骤相对直接，主要考察对扩散偶中原子扩散行为的理解和简单应用。" + }, + { + "idx": 891, + "question": "A single crystal test bar of FCC metal with a cross-sectional area of 10cm² is subjected to a compression test along the axial direction. The critical resolved shear stress is known to be 0.1kgf/mm², and the initial orientation of the bar axis is [215]. Please determine the final stable orientation of the crystal (assuming the test bar does not fracture before reaching the stable orientation).", + "answer": "The final stable orientation of the crystal: [101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定晶体的最终稳定取向，答案是一个具体的取向[101]，而不是通过计算或选择得出的。解答过程需要理解晶体取向和临界分切应力的概念，属于需要文字解释的简答题类型。 | 知识层次: 题目需要应用临界分切应力和晶体取向的概念，进行多步计算和综合分析，以确定晶体的最终稳定取向。这涉及到对晶体滑移系统的理解和应用，以及如何通过计算和推理得出最终结果。虽然不需要复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学、力学和材料科学知识，进行多步计算和概念关联分析。题目要求确定FCC金属单晶在压缩测试中的最终稳定取向，涉及临界分切应力、晶体取向变化和滑移系统激活等复杂概念，解题步骤较为繁琐，需要深入理解和综合分析。" + }, + { + "idx": 892, + "question": "Term explanation: Burgers vector", + "answer": "An important vector describing the characteristics of a dislocation, which comprehensively reflects the magnitude and direction of the total distortion within the dislocation region; it also represents the amount of relative sliding of the crystal after the dislocation has swept through.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语\"Burgers vector\"进行解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对Burgers vector这一基本概念的定义和特性的记忆和理解，属于材料科学中位错理论的基础知识。 | 难度: 在简答题题型中，该题目要求对Burgers vector进行解释和描述，不仅需要记忆其基本定义，还需要理解其反映的物理意义和作用。虽然不涉及复杂的概念体系阐述，但比单纯的定义简答要求更高，属于概念解释和描述的难度等级。" + }, + { + "idx": 893, + "question": "A single crystal test bar of an FCC metal with a cross-sectional area of 10cm² is subjected to a compression test along the axial direction. Given that the critical resolved shear stress is 0.1kgf/mm² and the initial orientation of the bar axis is [215], determine the axial pressure P at the onset of double slip (without considering physical hardening).", + "answer": "P = (0.1×1000)/((√10/5)×(√10/5))×9.8N = 2450N.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定轴向压力P的值，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括临界分切应力的应用、晶体取向的计算以及轴向压力的确定。虽然不涉及复杂的综合分析或创新设计，但需要将多个概念关联起来并进行综合计算，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解临界分切应力、晶体取向、双滑移条件等概念，并进行多步计算和公式应用。虽然涉及多个知识点和计算步骤，但题目提供了明确的参数和方向，降低了部分复杂性。" + }, + { + "idx": 894, + "question": "Term explanation: phase diagram", + "answer": "A graphical representation describing the conditions for phase equilibrium or the coexistence relationships of phases; it can also be referred to as the geometric trajectory of thermodynamic parameters at equilibrium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语进行解释，需要文字描述和论述，而不是选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即对相图（phase diagram）的定义和基本描述的记忆。 | 难度: 在简答题题型中，该题目仅要求对\"phase diagram\"进行基本定义简答，属于最基础的概念记忆层次。题目答案直接给出了标准定义，不需要额外的解释、描述或复杂概念体系的阐述，完全符合等级1的难度标准。" + }, + { + "idx": 895, + "question": "A single crystal test bar of FCC metal with a cross-sectional area of 10 cm² is subjected to a compression test along the axial direction. The critical resolved shear stress is known to be 0.1 kgf/mm², and the initial orientation of the bar axis is [215]. Please answer the rotation law and rotation axis when slip begins.", + "answer": "Since it is compression, the rotation law is: F→[111], and the rotation axis is [215]×[111]=[633]=[211].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释旋转定律和旋转轴，答案提供了详细的文字解释和推导过程，而不是简单的选择、判断或数值计算。 | 知识层次: 题目需要理解FCC金属的滑移系统、临界分切应力概念，并应用施密特因子和旋转定律进行多步计算和综合分析，涉及概念关联和中等程度的思维深度。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识、应力分析和向量运算。解题步骤包括：1)理解压缩条件下的滑移系选择原则；2)正确应用施密特定律计算临界分切应力；3)确定晶体旋转规律；4)进行向量叉积运算确定旋转轴。整个过程需要将多个概念关联运用，并准确执行数学运算，属于多角度分析论述的范畴。" + }, + { + "idx": 896, + "question": "Term explanation: deformation texture", + "answer": "The phenomenon of crystallographic orientation preference occurring during polycrystalline deformation is called deformation texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"deformation texture\"进行解释说明，答案是以文字形式给出的定义性描述，符合简答题的特征 | 知识层次: 题目考查对\"deformation texture\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及应用或分析层面的要求。 | 难度: 在简答题题型中，该题目仅要求对\"deformation texture\"这一专业术语进行基本定义解释，属于最基础的概念记忆层次。题目不涉及概念的延伸描述、分类或与其他概念的关联分析，完全符合等级1\"基本定义简答\"的标准。在同类术语解释题中，这是最基础、最直接的考查形式。" + }, + { + "idx": 897, + "question": "Term explanation: Degree of supercooling", + "answer": "In the phase transformation process, after cooling to a certain temperature below the phase transition point, the transformation occurs. The difference between the equilibrium phase transition temperature and this actual transformation temperature is called the degree of supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语\"Degree of supercooling\"进行解释说明，答案是以文字形式给出的定义和解释，符合简答题的特征。 | 知识层次: 题目考查对\"Degree of supercooling\"这一基本概念的定义和解释，属于基础概念的记忆和理解层面，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要准确记忆\"过冷度\"的定义，但只需简要说明其物理意义（相变温度与实际转变温度的差值），不需要涉及复杂的概念体系或推导过程。相比等级1的纯定义复述题，此题要求稍高的理解性表述；相比等级3的多概念关联阐述题，此题的知识点较为单一。符合该题型下对基础概念进行扩展解释的中等难度特征。" + }, + { + "idx": 898, + "question": "Term explanation: Slip system", + "answer": "In a crystal, the combination of a slip plane and a slip direction on that plane is called a slip system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Slip system\"进行解释，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"slip system\"这一基本概念的定义记忆和理解，属于材料科学中晶体变形的基础知识，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"Slip system\"这一基础概念进行定义性解释，属于最基本的知识点记忆。题目不涉及概念的延伸解释、分类讨论或与其他概念的关联分析，完全符合等级1\"基本定义简答\"的标准。回答只需准确复述教材中的定义即可，无需任何扩展性论述或复杂思考过程。" + }, + { + "idx": 899, + "question": "Write the mathematical expression of Fick's first law and explain its significance.", + "answer": "In one dimension, J=-D(dc/dx). J: diffusion flux, the amount of substance diffusing per unit time through a unit area, g/s·m²; D: diffusion coefficient, m²/s; dc/dx: concentration gradient, g/m³. Its significance is that the amount of substance diffused is proportional to the concentration gradient of the substance and in the opposite direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出菲克第一定律的数学表达式并解释其意义，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查Fick第一定律的基本数学表达式及其物理意义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求写出菲克第一定律的数学表达式并解释其意义，这需要学生掌握基础概念的定义和基本原理，并能进行简单的解释和描述。虽然涉及数学表达式和物理量的解释，但整体上仍属于基础概念记忆的范畴，解题步骤相对简单，不需要复杂的分析或阐述。因此，在同题型内属于中等难度。" + }, + { + "idx": 900, + "question": "Term explanation: Twinning", + "answer": "Twinning refers to the shear process in which a crystal undergoes deformation by forming twins under stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对专业术语\"Twinning\"进行解释说明，需要提供文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Twinning这一基础概念的定义和基本过程的理解，属于材料科学中晶体变形的基础知识，主要依赖记忆和理解。 | 难度: 在简答题题型中，该题目要求对\"Twinning\"这一概念进行解释和描述，不仅需要记忆基本定义，还需要说明其形成过程和条件（如\"under stress\"）。这比单纯复述定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。题目考察的是对晶体变形机制的理解和表达能力，属于概念解释和描述的典型难度等级。" + }, + { + "idx": 901, + "question": "What are the general structural zones of an ingot? List their names.", + "answer": "It is divided into three crystal zones: chill zone, columnar crystal zone, and central equiaxed crystal zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出铸锭的一般结构区域名称，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对铸锭结构区域的基本分类和名称的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求列举铸锭的一般结构区域名称，属于基础概念记忆层面的问题。回答只需直接回忆并列出三个晶体区的名称（激冷区、柱状晶区和中心等轴晶区），无需进行概念解释或复杂体系阐述。与同类简答题相比，其知识掌握深度和解题步骤都最为简单，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 902, + "question": "Briefly describe the changes in mechanical properties of deformed metals during annealing", + "answer": "Hardness and strength decrease, elongation increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述变形金属在退火过程中机械性能的变化，需要用文字解释和论述，答案也是以文字形式给出关键变化点。 | 知识层次: 题目考查对金属退火过程中机械性能变化的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于基本定义简答，仅需记忆并简要描述变形金属在退火过程中机械性能的变化（硬度和强度降低、延伸率增加），无需深入解释或复杂概念体系的阐述。" + }, + { + "idx": 903, + "question": "Term explanation: secondary recrystallization", + "answer": "The phenomenon of abnormal growth of a few grains occurring when normal growth is inhibited after the completion of recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语\"secondary recrystallization\"进行解释，需要提供文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"二次再结晶\"这一基本概念的定义记忆和理解，属于材料科学中基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要准确记忆并表述二次再结晶的定义，但不需要涉及复杂的概念体系或深入的分析。相比基本定义简答（等级1），它要求对现象有更完整的描述；但相比需要阐述多个相关概念的复杂题目（等级3），其难度适中。" + }, + { + "idx": 904, + "question": "Briefly describe the changes in stored energy during the annealing process of deformed metals", + "answer": "The stored energy is gradually released.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述变形金属退火过程中储存能的变化，需要用文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对退火过程中储存能变化的基本概念的理解和记忆，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求简要描述变形金属退火过程中储存能的变化，属于基础概念记忆层面的回答。题目不涉及复杂概念体系或深入解释，仅需简单陈述\"储存能逐渐释放\"这一基本事实，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 905, + "question": "Briefly describe the changes in physical properties of deformed metal during annealing", + "answer": "Electrical resistance decreases, density increases. The changes in various properties during recrystallization are much more pronounced than during recovery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述变形金属在退火过程中物理性质的变化，答案以文字解释的形式给出，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对金属退火过程中物理性质变化的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求描述变形金属在退火过程中物理性质的变化，属于概念解释和描述的难度级别。虽然需要记忆和理解相关物理性质的变化，但不需要复杂的体系阐述或多步骤推理。题目涉及的知识点较为基础，属于材料科学中常见的退火过程效应描述。" + }, + { + "idx": 906, + "question": "Briefly describe the factors affecting the crystalline structure of ingots.", + "answer": "Factors affecting the crystalline structure of ingots: 1 Liquid superheat, the smaller the better; 2 Solidification temperature range, the larger the better, which is beneficial for dendrite fragmentation; 3 Temperature gradient, the smaller the more conducive to equiaxed crystals; 4 Alloy with low melting point, small temperature gradient; 5 Stirring or adding inoculants.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述影响铸锭晶体结构的因素，答案以文字解释和列举要点的方式呈现，符合简答题的特征。 | 知识层次: 题目要求简要描述影响铸锭晶体结构的因素，涉及多个因素的关联和综合分析，需要理解各因素之间的相互作用及其对晶体结构的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生从多个角度（如温度梯度、合金特性、工艺参数等）综合分析影响铸锭晶体结构的因素，并解释各因素的具体影响机制。这需要考生不仅掌握相关概念，还能进行多角度关联分析，属于较复杂的论述题，因此评为等级4。" + }, + { + "idx": 907, + "question": "Briefly describe the changes in the microstructure of deformed metal during the annealing process", + "answer": "As the annealing temperature increases or the time prolongs, subgrain coalescence and growth occur, followed by recrystallization nucleation and growth. The deformed grains with high dislocation density and elongated shape are replaced by equiaxed recrystallized grains free of dislocations, and then normal grain growth takes place.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形金属在退火过程中的微观结构变化，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求描述变形金属在退火过程中微观结构的变化，涉及多个阶段的转变（亚晶粒合并与生长、再结晶形核与生长、晶粒正常长大），需要理解并关联不同退火条件下的微观结构演变过程，属于中等应用层次的知识。 | 难度: 在简答题中属于中等难度，需要理解变形金属在退火过程中的微观结构变化，并能够分阶段描述这些变化。虽然涉及多个概念（如亚晶粒合并、再结晶、晶粒生长等），但不需要进行多角度或深度关联性分析，只需按顺序说明各阶段的变化即可。" + }, + { + "idx": 908, + "question": "Briefly describe the similarities between solid-state phase transformation and liquid-state phase transformation", + "answer": "Both are phase transformations, consisting of nucleation and growth. The critical radius and critical nucleation work have the same forms. The transformation kinetics are also the same.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述固态相变和液态相变的相似之处，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求比较固态相变和液态相变的相似性，涉及对两种相变过程的理解和关联分析，需要综合运用相变的基本原理（如形核和生长）进行比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较固态相变和液态相变的相似性，但答案只需要列举几个关键点（如成核与生长、临界半径和临界成核功的形式相同、相变动力学相同），并不需要深入的多角度分析或深度关联性分析。解题步骤相对简单，主要涉及基本概念的关联和综合说明，符合等级3的综合分析和说明要求。" + }, + { + "idx": 909, + "question": "Briefly describe the differences between solid-state phase transformation and liquid-state phase transformation", + "answer": "The nucleation resistance includes an additional strain energy term, leading to an increase in the critical radius and nucleation work for solid-state phase transformation; the new phase can appear in a metastable manner, with coherent, semi-coherent interfaces, specific orientation relationships, and heterogeneous nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固态相变和液态相变之间的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较固态相变和液态相变的差异，涉及成核阻力、应变能、临界半径、成核功、亚稳态、界面类型（共格、半共格）、取向关系以及异质成核等多个复杂概念的综合分析和解释。这需要深入理解相变机理，并能将这些概念关联起来进行推理分析，属于较高层次的认知要求。 | 难度: 在简答题中属于机理深度解释难度，需要准确区分固态相变和液态相变的差异，并解释固态相变中额外的应变能项对临界半径和形核功的影响，以及新相出现的特殊方式（如亚稳态、界面关系等）。这要求对相变机理有较深入的理解和综合运用能力，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 910, + "question": "Briefly describe the factors affecting diffusion.", + "answer": "1. Temperature. It follows the relationship D=D0e^(-Q/RT), where an increase in T leads to an increase in D; 2. Interfaces, surfaces, and dislocations. These serve as fast diffusion paths; 3. Third elements. They can have varying effects on binary diffusion, such as Mo and W reducing the diffusion coefficient of C in γ-Fe, Co and Si accelerating the diffusion of C, and Mn having little effect; 4. Crystal structure. In low-symmetry crystal structures, diffusion anisotropy exists, such as in hexagonal crystals where the diffusion coefficients parallel and perpendicular to the basal plane (0001) differ; 5. Melting point. Within the same alloy system, diffusion is slower in alloys with higher melting points and faster in those with lower melting points at the same temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述影响扩散的因素，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求简要描述影响扩散的因素，涉及多个知识点（温度、界面、第三元素、晶体结构、熔点）的综合分析，需要理解扩散机制并关联不同因素对扩散系数的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求多角度分析论述影响扩散的因素，涉及温度、界面、第三元素、晶体结构和熔点等多个方面。每个因素都需要详细解释和关联扩散机制，如温度与扩散系数的关系、不同晶体结构中的扩散各向异性等。虽然不需要进行深度关联性分析（如跨学科或多机制整合），但需要综合运用多个概念并进行详细说明，因此属于等级4的多角度分析论述难度。" + }, + { + "idx": 911, + "question": "What is the difference in the driving force for nucleation during recrystallization and solidification?", + "answer": "The driving force for nucleation during solidification is the chemical potential difference between the new and old phases, while the driving force for recrystallization is only the stored energy of deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种不同过程中成核驱动力的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种不同相变过程（再结晶和凝固）的成核驱动力，涉及多个概念的理解和关联。虽然答案相对明确，但需要理解化学势差和变形储存能的概念，并将它们与不同的相变过程联系起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。它要求考生理解并比较两种不同过程（再结晶和凝固）的成核驱动力，涉及多个概念（化学势差和变形储存能）的关联和综合分析。虽然需要一定的知识深度和概念关联能力，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 912, + "question": "What is the difference in orientation relationship between growth during recrystallization and growth during solidification?", + "answer": "During solidification growth, there is no orientation relationship with the parent phase, whereas during recrystallization growth, a specific orientation relationship may exist.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种生长过程中的取向关系差异，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目要求比较两种不同过程中晶体生长的取向关系，需要理解并关联再结晶和凝固过程中的晶体生长机制，属于中等应用层次的分析和概念关联。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释和比较两种不同的生长过程（再结晶和凝固）中的取向关系，但题目明确指出了比较的方向（取向关系），减少了分析的范围。学生需要理解并区分两种过程中取向关系的差异，这涉及到对材料科学中相变和再结晶基本概念的综合应用。然而，题目并未要求深入探讨取向关系的具体类型或机制，因此不需要多角度或深度关联性分析。" + }, + { + "idx": 913, + "question": "What is the difference in nucleation sites between recrystallization and solidification processes?", + "answer": "Solidification is often homogeneous nucleation; recrystallization nucleation occurs in existing deformation inhomogeneous regions, such as near grain boundaries, shear bands, deformation bands, and around second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种过程在成核位点上的差异，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求比较两种不同过程中的成核位点差异，涉及对再结晶和凝固过程的理解，需要将多个概念关联起来进行综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对两种不同过程（再结晶和凝固）的成核位点进行多角度分析论述。需要理解并比较两种过程的成核机制，涉及多个概念（如均匀成核、非均匀成核、变形不均匀区域等）的关联和综合分析。虽然不需要深度关联性分析（如涉及更复杂的材料科学理论），但仍需较深入的论述和比较，因此属于等级4难度。" + }, + { + "idx": 914, + "question": "5. Secondary recrystallization", + "answer": "A phenomenon where the normal growth process is inhibited after recrystallization, leading to abnormal growth of a few grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Secondary recrystallization\"这一现象进行文字解释和论述，答案是一个概念性的描述，没有选项、不需要判断对错或进行计算。 | 知识层次: 题目考查对二次再结晶这一基本概念的记忆和理解，属于定义性知识的直接回忆和简单解释，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。虽然需要学生对\"二次再结晶\"这一现象进行文字解释，但主要考察的是对基础概念的记忆和理解，不需要复杂的分析或体系阐述。题目要求描述现象的基本特征（正常生长受阻、少数晶粒异常生长），属于中等难度的概念解释题。" + }, + { + "idx": 915, + "question": "Briefly describe the inverse segregation in the macrosegregation of ingots", + "answer": "Inverse segregation: It still follows the distribution coefficient relationship, but after the formation of a large number of dendrites, the solute-enriched liquid phase will flow backward along the interdendritic channels to the vicinity of the initially solidified ingot surface, resulting in an abnormal composition distribution from the surface to the center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述逆偏析现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对逆偏析这一基本概念的定义和形成机理的记忆和理解，属于材料科学中基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述逆偏析现象，涉及对枝晶形成和溶质富集液相流动的基本原理的理解和描述，但不需要复杂的体系阐述或多层次分析。属于基础概念记忆层次中对现象的解释性回答，符合等级2的标准。" + }, + { + "idx": 916, + "question": "Briefly describe the gravity segregation in the macrosegregation of ingots", + "answer": "Gravity segregation: During solidification, the solid phase and the liquid phase have different densities, causing deposition or floating, which results in uneven composition between the lower and upper ends of the ingot, also on a macroscopic scale.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述重力偏析在铸锭宏观偏析中的表现，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对重力偏析这一基本概念的记忆和理解，涉及定义和基本原理的解释，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释重力偏析的定义和基本原理，并描述其在宏观偏析中的表现，但不需要深入分析复杂的概念体系或进行多方面的比较。" + }, + { + "idx": 917, + "question": "Briefly describe normal segregation in the macro-segregation of ingots", + "answer": "Normal segregation: refers to the phenomenon where the initially solidified portion has lower solute content and the later solidified portion has higher solute content, according to the alloy's distribution coefficient (assuming k0<1). Due to the large size of the ingot, the composition varies from the surface to the center, resulting in non-uniformity, and the segregation occurs on a macroscopic scale, known as macro-segregation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述宏观偏析中的正常偏析现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对宏观偏析中正常偏析现象的基本定义和原理的记忆和理解，属于基础概念层次。 | 难度: 在简答题中属于概念解释和描述难度。题目要求简要描述正常偏析现象，涉及合金分配系数和宏观偏析的基本原理，但不需要深入分析或复杂概念体系的阐述。属于对基础概念的记忆和简单解释层次。" + }, + { + "idx": 918, + "question": "4.Deformation texture", + "answer": "The phenomenon of crystallographic orientation preference occurring during polycrystalline deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Deformation texture\"进行文字解释和论述，答案提供了概念性的描述而非选择、判断或计算 | 知识层次: 题目考查的是对\"变形织构\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在简答题-基础概念记忆题型中，此题仅要求对\"变形织构\"进行基本定义回答，属于最基础的定义简答级别。题目仅需记忆性知识，不需要展开解释或描述相关机制，也不涉及复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 919, + "question": "3. Congruent solidification and incongruent solidification", + "answer": "Solidification without compositional change is called congruent solidification; conversely, solidification accompanied by compositional change is called incongruent solidification.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Congruent solidification\"和\"incongruent solidification\"这两个专业术语进行解释和区分，需要文字论述说明其定义和区别，符合简答题的特征。 | 知识层次: 题目考查对\"congruent solidification\"和\"incongruent solidification\"这两个基本概念的定义和区分，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对\"congruent solidification\"和\"incongruent solidification\"两个基本概念进行定义性回答，属于最基础的定义简答类型。题目不涉及概念的解释、比较或复杂体系的阐述，仅需要记忆并复述基本定义即可完成作答，因此在简答题题型中属于最低难度等级。" + }, + { + "idx": 920, + "question": "2.Grain boundaries and interfacial energy", + "answer": "A grain boundary is the interface between grains of the same composition and structure. Atoms at the interface are in a broken-bond state and possess excess energy. The average excess energy per unit area of the interface is called interfacial energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"晶界和界面能\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对晶界和界面能的基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对晶界和界面能的基本定义进行简要回答，属于最基础的概念记忆层面。题目不涉及概念间的联系或复杂体系的阐述，仅需直接复述教材中的基础定义即可完成作答，因此属于该题型内最低难度等级。" + }, + { + "idx": 921, + "question": "Analyze the crystallization process of an iron-carbon alloy with a carbon content of 0.12%", + "answer": "For steel with 0.12% carbon, when cooled from the liquid phase, δ-ferrite forms first. The compositions of the solid and liquid phases change according to the solidus and liquidus lines on the phase diagram. At the peritectic temperature of 1495°C, partial peritectic reaction occurs; the new phase γ-austenite nucleates on the pre-existing δ-ferrite and grows into both the δ-ferrite and liquid phase. After the reaction, the microstructure consists of two phases: δ-ferrite + γ-austenite. The relative amount of δ-ferrite is: (0.17-0.12)/(0.17-0.09)=62.5%. Upon further cooling, single-phase austenite is obtained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析铁碳合金的结晶过程，答案提供了详细的文字解释和论述，包括相变过程、温度变化和相组成计算，符合简答题的特征。 | 知识层次: 题目要求分析铁碳合金的结晶过程，涉及相图的理解、相变反应的描述以及简单的计算。虽然需要一定的概念关联和综合分析能力，但整体上仍属于中等应用层次，不需要过于复杂的推理或创新思维。 | 难度: 在简答题题型中，该题目属于较高难度等级。题目要求分析铁碳合金的结晶过程，涉及多个步骤和概念的综合运用，包括相变过程、相图解读、成分计算和微观结构演变。需要考生不仅理解基本概念，还能将这些概念关联起来进行多角度分析。此外，题目还要求进行具体的成分计算（62.5%的δ-ferrite），这增加了题目的复杂性和难度。因此，在简答题题型中，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 922, + "question": "What are the characteristics of the space lattice in the tetragonal crystal system?", + "answer": "The lattice parameters of the tetragonal crystal system are a≠b≠c, α=β=γ=90°.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释四方晶系的空间点阵特征，答案需要文字描述和论述，而非选择、判断或计算。 | 知识层次: 题目考查对四方晶系空间点阵基本特征的定义和记忆，属于晶体学基础概念范畴，不需要复杂分析或应用。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并复述四方晶系的空间点阵特征参数（a≠b≠c, α=β=γ=90°），不涉及概念解释或复杂体系阐述。" + }, + { + "idx": 923, + "question": "Briefly describe the types of defects in metal crystals", + "answer": "According to size, they can be divided into: point defects, such as solute, impurity atoms, vacancies; line defects, such as dislocations; planar defects, such as various grain boundaries, phase boundaries, surfaces, etc.; volume defects, such as pores, bubbles, etc. Volume defects are absolutely harmful to material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述金属晶体中的缺陷类型，答案提供了详细的文字解释和分类论述，符合简答题的特征。 | 知识层次: 题目考查金属晶体缺陷的基本分类和定义，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求简要描述金属晶体中的缺陷类型，并按照尺寸进行分类。虽然需要列举多种缺陷类型（点缺陷、线缺陷、面缺陷、体缺陷），但这些都是基础概念的记忆性知识，不需要复杂的分析或深入的论述。因此，在简答题的框架内，该题目属于中等难度，即等级2。" + }, + { + "idx": 924, + "question": "1. Edge dislocation and screw dislocation models", + "answer": "Cut the upper half of the crystal, insert half a crystal plane, and then bond it together; in this way, within a certain range near the centerline corresponding to the edge end, the atoms undergo regular misalignment. Its characteristic is that the upper half is under compression, and the lower half is under tension. This is the same as the scenario caused by edge dislocations in real crystals, known as the edge dislocation model. Similarly, cut the front half of the crystal, use the edge end as the boundary to make the left and right parts undergo a relative shear of one atomic spacing up and down, and then bond them together. At this time, near the boundary line between the sheared and unsheared regions, the atomic misalignment is similar to that of a real screw dislocation, known as the screw dislocation model.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对边缘位错和螺旋位错模型进行文字解释和论述，答案形式为详细的描述性文字，而非选择、判断或计算。 | 知识层次: 题目主要考查对刃型位错和螺型位错模型的基本概念和特征的理解和记忆，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求解释边缘位错和螺旋位错模型的基本原理和特征，虽然涉及两种位错模型的描述，但并未要求深入分析或比较复杂的理论体系。主要考察的是对基础概念的记忆和理解，属于中等难度的简答题。" + }, + { + "idx": 925, + "question": "Briefly describe the characteristics of the eutectic reaction in a binary system and calculate the degrees of freedom when its phases are in equilibrium.", + "answer": "The eutectic reaction is: the liquid phase simultaneously solidifies into two solid phases of different compositions, which grow cooperatively and generally form a lamellar structure. When the eutectic reaction occurs, the degrees of freedom are 0, meaning the compositions of the three phases are fixed, and the temperature is also fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述共晶反应的特点并计算自由度，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求描述共晶反应的基本特征（基础概念），还需要计算自由度（简单应用），并将两者结合起来进行综合分析。这涉及到多步思维过程和对相平衡概念的理解，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并描述共晶反应的特征，同时进行自由度计算。题目要求对概念进行综合分析和说明，但不需要多角度或深度关联性分析。" + }, + { + "idx": 926, + "question": "Briefly describe the characteristics of the peritectic reaction in a binary system and calculate the degrees of freedom at equilibrium for each phase.", + "answer": "The peritectic reaction is: a liquid phase reacts with a solid phase to form another solid phase, where the newly formed solid phase envelops the original solid phase. The reaction requires diffusion within the solid phase and proceeds relatively slowly. When a peritectic reaction occurs, the degrees of freedom are 0, meaning the compositions of the three phases are fixed, and the temperature is also fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述包晶反应的特征并计算平衡时的自由度，答案以文字解释和论述为主，没有涉及选项选择、判断对错或复杂数值计算。 | 知识层次: 题目不仅要求描述包晶反应的基本特征（基础概念），还需要计算平衡时各相的自由度（简单应用），涉及对相图知识的理解和应用。虽然计算部分相对直接，但需要将概念与计算结合起来，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合理解并描述相图反应特征（包晶反应机制、扩散限制等），同时进行自由度计算（吉布斯相律应用）。题目要求将理论描述与定量计算结合，并解释固定自由度条件下的相平衡状态，属于多角度分析论述题型中的典型代表。" + }, + { + "idx": 927, + "question": "Briefly describe the characteristics of the eutectoid reaction in a binary system and calculate the degrees of freedom when its phases are in equilibrium.", + "answer": "The eutectoid is similar to the eutectic, except that the parent phase is a solid phase, i.e., one solid phase simultaneously transforms into two other solid phases of different compositions. When the eutectoid reaction occurs, the degrees of freedom are 0, meaning the compositions of the three phases are fixed, and the temperature is also fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述共析反应的特征并计算自由度，答案包含文字解释和论述，没有涉及选项选择或数值计算 | 知识层次: 题目不仅要求描述共析反应的基本特征（基础概念），还需要计算自由度（简单应用），并将两者结合起来进行综合分析。这涉及到多步思维过程和对相平衡概念的理解与应用。 | 难度: 在简答题中属于中等难度，需要理解并描述共析反应的特征，同时进行自由度计算。题目涉及对相变过程的理解和热力学平衡条件的应用，但不需要多角度或深度关联性分析。" + }, + { + "idx": 928, + "question": "What are the characteristics of the space lattice in the cubic crystal system?", + "answer": "The lattice parameters of the cubic crystal system are a=b=c, α=β=γ=90°.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释立方晶系的空间点阵特征，答案提供了文字描述而非选择、判断或计算 | 知识层次: 题目考查立方晶系空间点阵的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答立方晶系的空间点阵特征，属于基本定义简答。题目涉及的知识点非常基础，只需要记忆立方晶系的晶格参数关系（a=b=c，α=β=γ=90°），不需要进行额外的解释或论述。在同类简答题中，这属于最简单的等级1难度。" + }, + { + "idx": 929, + "question": "Briefly describe the meaning of Fick's first law, write its expression, and indicate the physical meanings of the letters.", + "answer": "Fick's first law J=-D(dc/dx) J: diffusion flux, which is the amount of substance passing through a unit area per unit time, g/m²·s; D: diffusion coefficient, m²/s; dc/dx: concentration gradient, g/m⁴.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Fick第一定律的含义，写出其表达式，并解释字母的物理意义。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查Fick第一定律的基本定义、表达式以及各符号的物理意义，属于基础概念的记忆和理解层面，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述菲克第一定律的含义、写出其表达式并说明字母的物理意义。虽然需要记忆和理解基本概念，但不需要复杂的推导或深入的分析，属于中等难度的概念解释题。" + }, + { + "idx": 930, + "question": "Briefly explain the meaning of Fick's second law, write its expression, and indicate the physical meanings of the letters.", + "answer": "Fick's second law ∂c/∂t=∂/∂x(D∂c/∂x) ∂c/∂t: rate of concentration change over time, g/m³·s; ∂J/∂x: gradient of flux, g/m³·s.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释Fick第二定律的含义，写出其表达式，并说明字母的物理意义。答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Fick's第二定律的基本定义、表达式及其物理含义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释Fick's second law的含义并写出其表达式，同时说明各字母的物理意义。这要求学生对概念有一定的理解和记忆，但不需要复杂的推导或深入的分析。" + }, + { + "idx": 931, + "question": "What is the method of nucleation during the recrystallization process?", + "answer": "Recrystallization nucleation often occurs in existing regions of deformation inhomogeneity, such as near grain boundaries, shear bands, deformation bands, and around second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释再结晶过程中的成核方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对再结晶过程中成核方法的基本概念记忆和理解，涉及成核位置的典型区域，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释再结晶过程中形核的方法，需要考生理解并描述形核发生的具体位置和条件，如晶界、剪切带、变形带和第二相粒子周围等。虽然涉及多个概念，但不需要复杂的体系阐述或深入分析，属于中等难度的概念解释题。" + }, + { + "idx": 932, + "question": "What is a lattice parameter?", + "answer": "Lattice parameters are the fundamental parameters that describe the geometric shape of a unit cell, consisting of six parameters: the three edge lengths a, b, c and the three angles α, β, γ between them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“lattice parameter”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即晶格参数的定义和组成，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答晶格参数的基本定义，属于最基础的概念记忆性知识。不需要进行额外的解释或复杂概念的阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 933, + "question": "6.Hardenability and hardening capacity", + "answer": "Hardenability refers to the ability of an alloy to be quenched into martensite, mainly related to the critical cooling rate, with its magnitude represented by the depth of the hardened layer. Hardening capacity refers to the maximum hardness that can be achieved after quenching, primarily related to the carbon content of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对两个概念进行文字解释和论述，没有提供选项或要求判断对错，也不需要数值计算。 | 知识层次: 题目考查对Hardenability和hardening capacity这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释两个相关但不同的概念（hardenability和hardening capacity），并简要说明它们的主要影响因素。这需要学生对基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目要求更多的解释和描述；相比等级3的复杂概念体系阐述，该题目涉及的概念和解释相对简单直接。" + }, + { + "idx": 934, + "question": "Briefly describe the role and influence of grain boundaries on the plastic deformation of polycrystals", + "answer": "The slip planes on both sides of the grain boundary are not parallel. On one hand, grain boundaries act as obstacles to dislocation motion, causing pile-ups and strengthening; meanwhile, they necessitate the occurrence of multiple slip systems near the grain boundaries to accommodate the deformation on both sides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶界对多晶体塑性变形的作用和影响，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释晶界在多晶体塑性变形中的作用和影响，涉及晶界对位错运动的阻碍作用、位错堆积强化机制以及多滑移系的协调变形等复杂概念。需要综合运用材料科学中的位错理论、晶体塑性和多晶体变形机制等知识进行深入分析和解释，属于对多个知识点的综合运用和机理阐述。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求考生不仅理解晶界的基本概念，还需要深入分析晶界在多晶体塑性变形中的双重作用（阻碍位错运动与促进多滑移系激活），并能用专业术语准确描述这些机理。这需要考生具备将微观变形机制与宏观力学行为相联系的综合分析能力，属于复杂分析知识层次中的典型题目。" + }, + { + "idx": 935, + "question": "Briefly describe the characteristics of phase transformation resistance in solid-state phase transformations", + "answer": "The phase transformation resistance includes an additional term for strain energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述固态相变中相变阻力的特征，需要文字解释和论述，而不是选择、判断或计算。答案也以文字形式给出解释。 | 知识层次: 题目考查对相变阻力的基本概念的理解，仅需要记忆和简要解释相变阻力的一个特征（应变能项），不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求简要描述相变阻力的特征，且答案仅涉及一个基本概念（应变能）的简单提及。属于基础定义简答级别，无需深入解释或复杂概念体系的阐述，符合等级1的基本定义简答标准。" + }, + { + "idx": 936, + "question": "What is the main difference between nucleation and growth during solidification and nucleation and growth during recrystallization?", + "answer": "The driving force for nucleation and growth during solidification is the chemical potential difference between the new and old phases, while the driving force for nucleation and growth during recrystallization is solely the stored deformation energy. Nucleation during solidification is often homogeneous; nucleation during recrystallization typically occurs in existing regions of deformation inhomogeneity, such as near grain boundaries, shear bands, deformation bands, or around second-phase particles. During solidification growth, there is no orientation relationship with the parent phase, whereas during recrystallization growth, there may be a certain orientation relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两种过程中成核和生长的主要区别，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种不同过程中成核和生长的差异，涉及多个概念的综合分析和关联，需要理解驱动力的来源、成核方式的不同以及生长过程中的取向关系等，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要从多个角度（驱动力的差异、成核位置的差异、生长过程中的取向关系）进行对比分析，并综合论述两种不同过程中的关键区别。题目要求对固态相变和再结晶两个不同领域的成核与生长机制有较深入的理解和关联分析能力。" + }, + { + "idx": 937, + "question": "What is primary banded structure?", + "answer": "Primary banded structure is formed by dendrites during solidification and becomes banded after hot rolling; under CuCl2 etching, the dark bands are dendrite trunks (with less solute), while the light bands are often interdendritic regions enriched with impurities, also known as original bands.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"primary banded structure\"进行解释和描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对primary banded structure这一基本概念的定义和形成过程的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释primary banded structure的形成过程、组成特点以及蚀刻后的表现，涉及多个相关概念（如dendrites、hot rolling、CuCl2 etching等）的关联性描述，但不需要深入分析复杂机制或构建完整理论体系。相比等级1的纯定义简答，需要更多组织性表述；相比等级3的体系化阐述，其知识深度和逻辑复杂度仍较为基础。" + }, + { + "idx": 938, + "question": "What is secondary banded structure?", + "answer": "Secondary banding is a product of solid-state transformation. Under nitric acid alcohol etching, the white bands are proeutectoid ferrite, and the black bands are pearlite, also known as micro banded structure. Secondary banding only occurs on the basis of primary banding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary banded structure\"进行解释和描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对二次带状结构这一基本概念的定义和组成成分的记忆和理解，属于材料科学中的基础概念记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释和描述一个具体的材料科学概念（二次带状结构），包括其形成机制和组成成分。虽然不涉及复杂的体系阐述，但要求对相关术语（如先共析铁素体、珠光体）和基本原理有清晰的理解和记忆。" + }, + { + "idx": 939, + "question": "Analyze the causes of primary banded structure formation.", + "answer": "The formation of primary banded structure is related to dendrite formation during solidification and the hot rolling process, where the dark bands are dendrite trunks (with fewer solutes) and the white bands are interdendritic regions enriched with impurities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析带状结构形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析初生带状结构的形成原因，涉及凝固过程中的枝晶形成和热轧过程的综合作用，需要理解不同区域的成分差异及其形成机理。这需要综合运用材料科学中的凝固理论和加工工艺知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对初级带状结构的形成原因进行机理深度解释，涉及凝固过程中的枝晶形成和热轧工艺的综合分析。虽然不需要全面分析所有可能的复杂现象（如等级5的要求），但需要对特定机理有深入理解和准确表述，属于该题型中较高难度的题目。" + }, + { + "idx": 940, + "question": "Analyze the causes of secondary banded structure formation.", + "answer": "The formation of secondary banded structure is the result of solid-state transformation. The white bands are proeutectoid ferrite, and the black bands are pearlite, which must form on the basis of primary bands. These bands are all related to element segregation and the special distribution of inclusions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析二次带状结构形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析二次带状结构形成的机理，涉及固态相变、先共析铁素体和珠光体的形成，以及元素偏析和夹杂物分布等复杂因素的综合分析。这需要深入理解材料科学中的相变原理和显微组织形成机制，属于机理解释和综合分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对二次带状结构的形成原因进行机理深度解释。需要综合运用材料科学中的固态相变、元素偏析和夹杂物分布等知识，并进行推理分析。虽然涉及多个复杂概念，但尚未达到全面分析复杂现象的最高难度等级。" + }, + { + "idx": 941, + "question": "Briefly describe the characteristics of nucleation in solid-state phase transformations", + "answer": "Non-uniform nucleation, with specific orientation relationships, often forming coherent or semi-coherent interfaces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述固态相变中成核的特征，答案以文字解释和论述的形式给出，符合简答题的特点。 | 知识层次: 题目要求描述固态相变中形核的特征，涉及非均匀形核、特定取向关系以及共格或半共格界面的形成。这需要将多个概念关联起来进行综合分析，而不仅仅是基础概念的记忆。虽然不涉及复杂计算，但需要对形核机制和界面特性有一定的理解和应用能力。 | 难度: 在简答题中属于中等难度，需要理解固态相变中形核的基本特征，包括非均匀形核、特定取向关系以及相干或半相干界面的形成。虽然涉及多个概念，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 942, + "question": "Briefly describe the characteristics of growth in solid-state phase transformations", + "answer": "The occurrence of habit phenomena, i.e., there is a precipitation sequence; special/regular microstructural morphologies, such as lamellar, acicular.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述固态相变中生长的特征，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目考查对固态相变生长特性的基本概念记忆和理解，涉及现象和形态的描述，属于基础概念层次。 | 难度: 在简答题中属于中等难度，需要解释和描述生长在固态相变中的特征，包括习惯现象和特殊的微观结构形态。虽然不涉及复杂的体系阐述，但需要理解并准确描述相关概念，比单纯的定义简答要求更高。" + }, + { + "idx": 943, + "question": "Briefly describe the characteristics of metastable phases in solid-state phase transformations", + "answer": "The appearance of metastable phases serves to reduce the resistance to phase transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述亚稳态相的特征，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对亚稳相在固态相变中特性的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目要求对metastable phases的特性进行描述，属于概念解释和描述的难度级别。虽然需要一定的理解和记忆，但不需要复杂的体系阐述或多层次的分析，因此属于中等难度。" + }, + { + "idx": 944, + "question": "Describe the mechanism of crystal growth during solidification", + "answer": "There are three growth mechanisms: continuous growth, two-dimensional nucleation and lateral growth via steps, and growth via screw dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述晶体生长的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查晶体生长机制的基本分类和记忆，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目要求解释晶体生长的三种机制，属于概念解释和描述的难度等级。虽然需要记忆和描述多个机制，但不需要深入分析或比较复杂的理论体系，属于中等难度的概念性简答。" + }, + { + "idx": 945, + "question": "Briefly describe the macroscopic characteristics of the solidification process", + "answer": "The macroscopic characteristics during solidification are: a certain degree of undercooling is required, and significant latent heat of crystallization is released.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述凝固过程的宏观特征，答案以文字解释和论述的形式给出，符合简答题的特点。 | 知识层次: 题目考查对凝固过程宏观特征的基本概念记忆和理解，属于定义和基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要回答者理解并描述固化的宏观特征，但不需要复杂的分析或多概念的整合。题目要求的是对基础概念的记忆和简单解释，属于中等难度。" + }, + { + "idx": 946, + "question": "Briefly describe the role and influence of grain size on the plastic deformation of polycrystals", + "answer": "When grains are fine, the entire grain can deform more uniformly with fewer combinations of slip systems; when grains are coarse, different regions within the grain cannot coordinate with each other during deformation, requiring the activation of different combinations of slip systems, often leading to grain 'fragmentation,' where a large grain is 'fragmented' into several parts with different slip systems activated in each part. The effect on performance follows the Hall-Petch relationship σs=σ0+Kd−1/2, meaning the finer the grains, the more grain boundaries there are, and the more significant the hindrance of grain boundaries to moving dislocations, resulting in a greater increase in strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶粒尺寸对多晶体塑性变形的作用和影响，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释晶粒尺寸对多晶体塑性变形的影响，涉及晶粒变形机制、滑移系统的激活以及Hall-Petch关系的应用。这需要综合运用材料科学中的变形机理、晶界作用和强度理论，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题的复杂分析层次中，该题目要求对晶粒尺寸在多晶体塑性变形中的作用和影响进行机理深度解释。需要综合运用Hall-Petch关系、位错运动与晶界相互作用等概念，并能够解释晶粒细化与粗化对变形均匀性和强度的影响机制。虽然不涉及多因素交互作用的全面分析，但对单一因素的机理解释已达到较深层次，符合等级4的标准。" + }, + { + "idx": 947, + "question": "What is a solid solution?", + "answer": "A single homogeneous solid formed by solute atoms dissolving into the solvent lattice in atomic form; the lattice type of the solvent is retained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"solid solution\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点 | 知识层次: 题目考查对固溶体这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答固体溶液的基本定义，属于最基础的概念记忆性知识。不需要额外的解释或复杂概念体系的阐述，解题步骤简单直接，仅需回忆并复述定义即可。因此在该题型内属于等级1的基本定义简答难度。" + }, + { + "idx": 948, + "question": "List one method to increase the number of nuclei during the solidification process, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Increase the cooling rate to enhance the degree of undercooling. The phase transformation driving force is increased, thereby improving the nucleation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出一种方法并简要分析原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举增加凝固过程中晶核数量的方法并分析原因，涉及对凝固过程基本原理的理解和应用，需要将冷却速率与过冷度、相变驱动力和形核率等概念关联起来进行综合分析。虽然不涉及复杂计算或多步推理，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于中等难度，需要理解并解释增加冷却速率如何通过提高过冷度来增加形核率，涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 949, + "question": "What changes occur in the structure, mechanical properties, and physical properties of a solid solution compared to its pure solvent component?", + "answer": "Structural changes in solid solutions: lattice distortion, changes in lattice constants, segregation and short-range ordering, and even the formation of ordered solid solutions. Changes in mechanical properties: increased hardness and strength, decreased plasticity. Changes in physical properties: increased electrical resistance, decreased conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释固溶体与纯溶剂在结构、力学性能和物理性能方面的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对固溶体与纯溶剂在结构、力学性能和物理性能方面的变化进行比较和分析，涉及多个知识点的关联和综合分析，需要理解固溶体的基本概念并能够应用这些知识来解释具体的变化现象。虽然不涉及复杂的计算或深度推理，但需要对多个性能变化进行关联和解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对固体溶液的结构、力学性能和物理性能变化进行多角度分析论述。需要考生不仅掌握基本概念，还能将不同性质的变化进行关联性说明，并解释其内在原因。虽然不需要深度关联性分析（等级5），但已超出简单的概念解释或单一性质说明（等级3），属于需要综合运用知识进行多角度论述的中高难度题目。" + }, + { + "idx": 950, + "question": "List another method to increase the number of nuclei during solidification, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Add inoculants. They provide a large number of heterogeneous nucleation sites, increase the nucleation rate, and reduce the nucleation barrier.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出另一种增加凝固过程中晶核数量的方法，并简要分析晶核数量增加的原因。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求列举另一种增加凝固过程中晶核数量的方法，并简要分析原因。这需要理解凝固过程中的成核机制，并能够将异质成核的概念应用于具体情境（如添加孕育剂）。虽然涉及基础概念，但需要一定的概念关联和综合分析能力来解释为什么添加孕育剂会增加晶核数量。 | 难度: 在简答题中属于中等难度，需要理解并解释增加晶核数量的方法及其原理，涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 951, + "question": "List the third method to increase the number of nuclei during solidification, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Mechanical or electromagnetic stirring. Breaking dendrites to increase the number of nuclei or enhancing thermal activation energy drop, which improves the nucleation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出第三种增加凝固过程中晶核数量的方法，并简要分析晶核数量增加的原因。答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列出第三种增加凝固过程中晶核数量的方法，并简要分析晶核数量增加的原因。这需要理解凝固过程中的基本原理（如形核机制、枝晶破碎等），并能够将机械或电磁搅拌与形核过程关联起来。虽然涉及一定的记忆性知识，但更侧重于应用这些知识来解释现象，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并解释机械或电磁搅拌如何通过破坏枝晶或增强热激活能下降来增加晶核数量，涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 952, + "question": "Briefly describe the crystallization process of steel with a carbon content of 0.25%", + "answer": "The liquid phase first solidifies into ferrite, and a peritectic reaction occurs at 1495°C to form γ-austenite; upon further cooling, the remaining liquid phase precipitates γ-austenite again, which then transforms into single-phase austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述钢的结晶过程，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求描述钢的结晶过程，涉及多个相变步骤和温度点的记忆，需要理解相图的基本原理并能够关联不同相变过程，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求考生描述含碳量为0.25%钢的结晶过程，涉及多个相变步骤（液态→铁素体→包晶反应→奥氏体→单相奥氏体），需要考生理解并关联铁碳相图中的关键温度和相变反应。虽然不需要多角度或深度关联性分析（等级4或5），但要求对相变顺序和温度节点有清晰的认识，属于典型的综合分析说明类题目。" + }, + { + "idx": 953, + "question": "Briefly describe the meaning of continuous precipitation", + "answer": "Continuous precipitation: as the new phase forms, the composition of the parent phase continuously changes from a supersaturated state to a saturated state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述连续沉淀的含义，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对连续沉淀这一基本概念的定义和原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对\"continuous precipitation\"进行基本定义简答，属于最基础的概念记忆层面。题目不需要解释机制、举例说明或与其他概念进行比较，仅需回忆并复述定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 954, + "question": "What are the factors affecting solid solubility?", + "answer": "The factors affecting solid solubility include: 1. Atomic size factor. When the relative difference in atomic diameters between the solvent and solute is less than ±15%, there is a large substitutional solubility. 2. Electronegativity factor. The smaller the electronegativity difference between the solvent and solute, the greater the solubility; generally, a difference less than 0.4∼0.5 results in higher solubility. 3. Electron concentration factor. This has two aspects: one is the atomic valence effect, meaning for the same solvent metal, the higher the valence of the solute, the lower the solubility; the other is the relative valence effect, meaning the solubility of a high-valence solute in a low-valence solvent is higher than the opposite scenario.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响固溶度的因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是影响固溶度的基本因素，包括原子尺寸因素、电负性因素和电子浓度因素等基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题中属于复杂概念体系阐述难度，需要系统性地解释影响固溶度的三个关键因素（原子尺寸因素、电负性因素、电子浓度因素），每个因素都涉及具体的数值判断标准（如±15%的原子直径差、0.4∼0.5的电负性差）和机制分析（如原子价效应与相对价效应），要求考生对固溶理论有整合性掌握并能进行多维度论述。" + }, + { + "idx": 955, + "question": "Briefly describe the meaning of discontinuous precipitation", + "answer": "Discontinuous precipitation: also known as cellular precipitation, where an interface exists between the parent phase and the newly formed α phase. Across this interface, the parent phase discontinuously changes from supersaturated to saturated state, and the lattice parameter also changes discontinuously.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述不连续沉淀的含义，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对不连续沉淀（discontinuous precipitation）这一基本概念的定义和特征的理解和记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要准确描述不连续沉淀的定义和特征，但不需要深入分析其形成机制或与其他现象的关联，属于中等难度的概念性简答。题目要求考生理解并表述界面变化和状态转变的关键特征，但不需要进行复杂的理论推导或多概念整合。" + }, + { + "idx": 956, + "question": "Briefly describe the solid-state phase transformation process of steel with a carbon content of 0.25%", + "answer": "When cooled to about 800°C, proeutectoid α-ferrite precipitates from γ-austenite; at 727°C, the eutectoid reaction occurs, forming pearlite, and finally a ferrite plus pearlite structure is obtained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述钢的固态相变过程，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求描述钢的固态相变过程，涉及多个相变阶段（γ-austenite到α-ferrite的析出、共析反应形成珠光体等），需要将不同相变概念关联起来进行综合分析，并解释最终组织结构。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在简答题中属于中等难度，需要理解钢的固态相变过程，包括先共析铁素体的析出和共析反应，并能简要描述最终的组织结构。虽然涉及多个概念，但不需要深入分析或关联其他复杂因素。" + }, + { + "idx": 957, + "question": "Briefly describe metallic bond", + "answer": "The bonding force generated by the electrostatic interaction between free electrons and atomic nuclei.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述金属键的性质，答案以文字解释的形式给出，属于需要文字论述的简答题类型。 | 知识层次: 题目考查金属键的基本定义和原理，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目仅要求对金属键进行基本定义简答，属于最基础的概念记忆层面。题目不涉及概念解释或复杂体系阐述，仅需复现静电相互作用这一核心定义要素，符合等级1\"基本定义简答\"的典型特征。相比需要展开描述的等级2和体系化论述的等级3，此题在简答题框架内属于最低难度层级。" + }, + { + "idx": 958, + "question": "Briefly describe the critical resolved shear stress for slip", + "answer": "The minimum resolved shear stress required to initiate slip system movement; it is a constant value, related to the intrinsic properties of the material and independent of the orientation of external forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述临界分切应力的概念，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对临界分切应力这一基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求简要描述临界分切应力的定义，不涉及复杂的概念解释或体系阐述。答案直接给出了该术语的核心定义和基本特性，属于基础概念记忆层面的考查，符合等级1的难度标准。" + }, + { + "idx": 959, + "question": "Briefly describe intermediate phases", + "answer": "Phases formed between components in an alloy, which have structures different from those of the pure components. Located in the intermediate region of the phase diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述中间相，答案是一段文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对中间相（intermediate phases）这一基本概念的定义和特征的理解，属于基础概念记忆范畴，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求简要描述中间相的基本定义和位置，属于基础概念记忆层次，无需深入解释或复杂论述，符合等级1的基本定义简答标准。" + }, + { + "idx": 960, + "question": "Briefly describe martensitic transformation", + "answer": "The process follows a diffusionless, shear-type phase transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述马氏体相变的过程，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查马氏体相变的基本定义和特征，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目仅要求对马氏体相变进行基本定义简答，属于最基础的概念记忆层面。答案只需直接复述扩散型剪切相变的特征，无需展开解释或论述复杂机制，符合等级1\"基本定义简答\"的标准。相比需要描述相变条件/特点（等级2）或阐述晶体学取向关系（等级3）的题目，此题的认知负荷和作答要求最低。" + }, + { + "idx": 961, + "question": "Briefly describe the Bravais lattice", + "answer": "A lattice that considers not only the shape of the unit cell but also the positions of the lattice points (or: considers not only rotational symmetry but also translational symmetry, forming all lattice points after centering).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Bravais lattice，答案是一段文字解释，符合简答题的特征 | 知识层次: 题目考查对Bravais晶格这一基本概念的定义和特征的理解，属于材料科学中晶体结构的基础知识，主要依赖记忆和简单理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要准确描述Bravais晶格的定义和特征，但不需要深入阐述复杂的概念体系或进行多层次的论证。题目主要考察对基础概念的记忆和理解，属于中等难度的简答题。" + }, + { + "idx": 962, + "question": "Briefly describe the slip system", + "answer": "A slip system in a crystal refers to a combination of a slip plane and a slip direction on that plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述滑移系统，答案是一个文字解释和论述，没有涉及选择、判断或计算 | 知识层次: 题目考查对滑移系统这一基本概念的定义记忆和理解，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆性知识，不需要额外的解释或复杂描述。" + }, + { + "idx": 963, + "question": "According to the size of defects relative to the crystal dimensions and their range of influence, into which categories can defects be classified? Briefly describe the characteristics of these categories.", + "answer": "There are four categories: Point defects: Very small in all three dimensions, such as solute atoms, interstitial atoms, and vacancies. Line defects: Very small in two dimensions, but large in the third dimension, potentially extending through the entire crystal, referring to dislocations. Planar defects: Very small in one dimension but large in the other two dimensions, such as grain boundaries and phase boundaries. Volume defects: Relatively large in all three dimensions but not excessively so, such as second-phase particles and microscopic voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对缺陷进行分类并简要描述各类别的特征，答案以文字解释和论述的形式呈现，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查对晶体缺陷分类的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求对晶体缺陷进行分类并简要描述各类别的特征，这需要学生对点缺陷、线缺陷、面缺陷和体缺陷的基本概念有清晰的理解和记忆。虽然涉及多个分类，但每个分类的描述相对简单直接，不需要复杂的推理或深入的分析。因此，在简答题的框架内，该题目属于中等难度，主要考察学生对基础概念的掌握和表达能力。" + }, + { + "idx": 964, + "question": "Briefly describe segregation", + "answer": "The non-uniformity of chemical composition in alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述一个概念（segregation），答案是用文字解释该概念的非均匀性特征，符合简答题需要文字解释和论述的特点。 | 知识层次: 题目考查基本概念的记忆和理解，仅需要回答合金中化学成分不均匀性的定义，不涉及复杂分析或应用。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述合金中化学成分不均匀性的定义，不涉及概念解释或复杂体系阐述。" + }, + { + "idx": 965, + "question": "Briefly describe dislocations", + "answer": "It is a type of linear defect in crystals, characterized by a regular misalignment of atoms along a line; this defect is described by both a line direction and a Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述位错的定义和特征，答案以文字解释和论述的形式给出，符合简答题的特点。 | 知识层次: 题目考查晶体缺陷中位错的基本定义和特征，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求简要描述位错的定义和基本特征，属于基础概念记忆的范畴。题目仅需回答位错是一种线性缺陷及其基本描述要素（线方向和伯氏矢量），不需要深入解释或复杂概念体系的阐述，因此在该题型内属于最简单的等级1难度。" + }, + { + "idx": 966, + "question": "Briefly describe secondary recrystallization", + "answer": "The phenomenon of abnormal growth of a few grains that occurs when the normal growth process is inhibited after recrystallization is completed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述二次再结晶现象，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对二次再结晶现象的基本定义和特征的理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要准确记忆并表述二次再结晶的定义，但不需要涉及复杂的概念体系或深入分析。相比基本定义简答（等级1）需要更完整的描述，但比复杂概念阐述（等级3）的要求简单。" + }, + { + "idx": 967, + "question": "Briefly describe the recrystallization temperature", + "answer": "The minimum temperature at which a deformed metal just completes recrystallization within a certain time (generally 1h).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述再结晶温度的定义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对再结晶温度这一基本概念的记忆和理解，属于定义性的记忆性知识 | 难度: 在简答题题型中，该题目仅要求对\"再结晶温度\"这一基础概念进行简单定义回答，属于最基本的概念记忆层面。题目不涉及概念解释、比较或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最基础、最容易回答的题型，只需准确记忆教材定义即可作答。" + }, + { + "idx": 968, + "question": "What is the structural model that constitutes a small-angle grain boundary?", + "answer": "The structural model of a small-angle grain boundary is the dislocation model, for example, a symmetric tilt grain boundary is described by a set of parallel edge dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释小角度晶界的结构模型，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对小角度晶界结构模型的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要解释小角度晶界的结构模型，但仅涉及单一概念（位错模型）和一个具体例子（对称倾斜晶界），不需要复杂的体系阐述或多层次分析。相比等级1的基本定义简答，该题要求更深入的概念描述；相比等级3的复杂体系阐述，该题的解题步骤和知识点要求较为简单。" + }, + { + "idx": 970, + "question": "Discuss the relationship between crystal structure and space lattice.", + "answer": "The relationship between the two can be described as 'space lattice $^+$ basis $\\asymp$ crystal structure.' There are only 14 types of space lattices, while the basis can be infinitely varied, thus resulting in an infinite variety of specific crystal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求讨论晶体结构与空间点阵之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对晶体结构和空间点阵之间关系的基本概念的理解和记忆，涉及基础定义和分类，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求讨论晶体结构与空间点阵之间的关系，需要考生理解并解释这两个概念之间的联系，但不需要进行复杂的体系阐述或深入分析。答案中给出了基本的关系描述和简单的分类说明，符合等级2的要求。" + }, + { + "idx": 971, + "question": "The interface between grains in single-phase metals or alloys is generally called grain boundaries, which are usually divided into two categories: low-angle grain boundaries and high-angle grain boundaries. What is the basis for this classification?", + "answer": "The classification is based on the misorientation between the grains on either side of the boundary. Boundaries with a misorientation <15° are called low-angle grain boundaries, while those >15° are called high-angle grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶界分类的基础，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对晶界分类的基本概念的理解和记忆，主要涉及低角度晶界和高角度晶界的定义及其分类依据，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释晶界分类的基础，涉及对低角度晶界和高角度晶界的基本定义和区分标准（取向差角度）的记忆和理解。虽然需要一定的知识掌握，但不需要复杂的分析或多层次概念的整合，属于该题型中的中等难度。" + }, + { + "idx": 972, + "question": "How does temperature affect atomic diffusion in metals or alloys?", + "answer": "Temperature follows the relationship D=Doe-Q/RT, where an increase in temperature accelerates diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释温度如何影响金属或合金中的原子扩散，需要文字解释和论述，而不是从选项中选择或判断对错。答案提供了公式和解释，符合简答题的特征。 | 知识层次: 题目涉及扩散系数与温度的阿伦尼乌斯关系式应用，需要理解公式中各参数的含义及其相互关系，并能解释温度变化对扩散速率的影响机制。这属于多步概念关联和综合分析层次，但尚未达到复杂分析或高级综合所需的深度推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然需要理解并应用扩散方程D=Doe-Q/RT，但解题步骤相对直接，主要涉及温度对扩散系数的影响这一核心概念。题目不要求多角度分析或深度关联其他复杂概念，符合\"综合分析和说明\"的等级3标准。" + }, + { + "idx": 973, + "question": "What effects do interfaces, surfaces, and dislocations have on atomic diffusion in metals or alloys?", + "answer": "Interfaces, surfaces, and dislocations act as fast diffusion paths.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述界面、表面和位错对金属或合金中原子扩散的影响，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目要求解释界面、表面和位错对金属或合金中原子扩散的影响，这需要综合运用扩散机制、晶体缺陷和材料界面等多方面的知识，并进行推理分析和机理解释。 | 难度: 在简答题中，该题目要求对原子扩散机理进行深度解释，涉及多个关键因素（界面、表面、位错）的综合分析。虽然不需要全面分析复杂现象（如等级5的要求），但仍需展示对扩散路径机理的深入理解和系统阐述能力，属于机理深度解释的范畴。" + }, + { + "idx": 974, + "question": "How does the third component affect binary diffusion?", + "answer": "The third component can have different effects on binary diffusion, such as Mo and W reducing the diffusion coefficient of C in γ-Fe; Co and Si accelerating the diffusion of C; Mn and Ni having little effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第三组分对二元扩散的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析第三组分对二元扩散的影响，并列举了不同元素的具体作用，这需要综合运用扩散理论、理解不同元素在材料中的行为机制，并进行推理分析。这超出了简单记忆或基本应用，属于对扩散现象的复杂分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对第三组分对二元扩散的影响进行机理层面的解释，需要综合运用扩散理论和合金元素相互作用的知识。虽然题目给出了具体元素的影响示例，但需要考生理解并解释这些不同影响背后的物理机制（如晶格畸变、电子结构变化等），属于机理深度解释的难度等级。相比等级5的全面分析要求，本题聚焦于扩散系数变化的机理解释，尚未达到需要分析多因素耦合效应的最复杂程度。" + }, + { + "idx": 975, + "question": "What are the characteristics of nucleation in the solid-state phase transformation of metals?", + "answer": "Predominantly heterogeneous nucleation; exhibits specific orientation relationships; phase interfaces are often coherent or semi-coherent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述固态相变中成核的特征，答案提供了详细的文字描述而非选择或判断 | 知识层次: 题目要求解释固态相变中形核的特征，涉及异质形核、取向关系和相界面的共格/半共格特性等复杂概念，需要综合运用相变理论、晶体学和界面能等知识进行推理分析，思维深度较高。 | 难度: 在简答题题型中，该题目要求对固态相变中的成核特性进行机理深度解释，涉及异质成核、特定取向关系以及相界面的共格/半共格特性等复杂概念的综合运用。虽然不需要全面分析所有相关现象（如动力学因素或温度影响），但仍需展示对核心机理的深入理解，符合等级4的难度标准。" + }, + { + "idx": 976, + "question": "How does melting point affect atomic diffusion within the same alloy system?", + "answer": "Within the same alloy system, at the same temperature, diffusion is slower in alloys with higher melting points and faster in those with lower melting points.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释熔化点如何影响原子扩散，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求理解熔点与原子扩散之间的关系，并能在相同合金系统中进行比较分析。这需要将熔点与扩散速率的概念关联起来，并进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释和论述，但主要涉及单一概念（熔点与扩散速率的关系）的关联性分析，不需要多角度或深度关联性分析。解题步骤相对直接，只需说明熔点高低如何影响扩散速率即可，符合等级3的综合分析和说明要求。" + }, + { + "idx": 977, + "question": "Analyze and discuss the characteristics of microstructural and property changes during the recovery and recrystallization process of cold-worked metals or alloys after plastic deformation.", + "answer": "As the annealing temperature increases or time prolongs, subgrains merge and grow, recrystallization nucleation and growth occur, and equiaxed recrystallized grains with no (or low-density) dislocations replace elongated deformed grains with high dislocation density, followed by normal grain growth. The stored energy is gradually released, most notably during the recrystallization stage; hardness and strength decrease, while elongation increases; electrical resistance decreases and density improves. The changes in various properties during recrystallization are much more pronounced than during recovery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析和讨论冷加工金属或合金在塑性变形后的回复和再结晶过程中的微观结构和性能变化特征，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析和讨论冷加工金属或合金在回复和再结晶过程中的微观结构和性能变化特征，涉及多个阶段的微观结构演变、能量释放和性能变化的综合分析，需要深入理解材料科学中的相变和变形机制，并进行推理和解释。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求对冷加工金属或合金在回复和再结晶过程中的微观结构和性能变化进行全面分析。这涉及多个复杂现象的整合，包括亚晶合并与生长、再结晶形核与长大、位错密度变化、存储能量释放机制，以及硬度、强度、延伸率、电阻率和密度等多参数性能演变的关联性解释。题目不仅要求掌握各阶段的独立特征，还需理解其动态相互作用机理，属于复杂现象全面分析层级，符合该题型下的最高难度标准。" + }, + { + "idx": 978, + "question": "What are the main factors affecting the solubility of solid solutions?", + "answer": "The factors affecting the solubility of solid solutions include:\\n1. Atomic size factor. When the relative difference in atomic diameters between the solvent and solute is less than ±15%, it favors higher solubility in substitutional solid solutions; when the relative difference in diameters between the two elements exceeds 41%, it favors higher solubility in interstitial solid solutions.\\n2. Electronegativity factor. The smaller the electronegativity difference between the solvent and solute, the greater the solubility, generally less than 0.4–0.5 for higher solubility.\\n3. Electron concentration factor. This has two aspects: one is the atomic valence effect, where in the same solvent metal, the higher the valence of the solute, the lower the solubility; the other is the relative valence effect, where the solubility is higher when a high-valence solute dissolves into a low-valence solvent compared to the opposite scenario.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响固溶体溶解度的主要因素，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释影响固溶体溶解度的主要因素，涉及多个概念（原子尺寸因素、电负性因素、电子浓度因素）的关联和综合分析，需要理解这些因素如何相互作用并影响溶解度，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅列举影响固溶体溶解度的主要因素，还需要对每个因素进行详细解释和论述，包括原子尺寸因素、电负性因素和电子浓度因素的具体影响机制。这需要考生具备多角度分析论述的能力，能够将多个相关概念关联起来，并进行综合分析。虽然题目不涉及最复杂的深度关联性分析，但已经超出了简单的概念列举和说明，属于较高难度的简答题。" + }, + { + "idx": 979, + "question": "What is the difference in phase transformation resistance between the solid-state phase transformation of metals and the crystallization process of metals?", + "answer": "There is an additional term of strain energy in the phase transformation resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种相变过程之间的差异，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释金属固态相变和金属结晶过程在相变阻力上的差异，并指出应变能的额外作用。这需要深入理解相变机制、能量变化以及不同相变过程的特点，涉及多个概念的关联和综合分析，属于复杂分析的层次。 | 难度: 在简答题题型中，该题目要求对金属固态相变和结晶过程的相变阻力进行机理层面的深度解释，需要综合运用材料科学中的相变理论、能量分析等知识，并准确指出应变能这一关键差异因素。虽然不涉及多步骤计算或跨学科整合，但需要对专业概念有深刻理解才能完整回答，属于机理深度解释级别的难度。" + }, + { + "idx": 980, + "question": "Discuss the effect of aging temperature on the precipitation sequence of Al 4.5%Cu alloy", + "answer": "Increasing the aging temperature accelerates precipitation but reduces supersaturation and the driving force for phase transformation, potentially leading to direct precipitation of the equilibrium θ phase and weakening age-hardening capability; conversely, too low aging temperature prolongs the time required to achieve optimal performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论时效温度对Al 4.5%Cu合金析出序列的影响，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求分析时效温度对Al-Cu合金析出序列的影响机制，涉及相变动力学、热力学驱动力的综合考量，需要理解温度对析出相类型和强化效果的复杂作用关系，属于机理层面的解释性分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对Al-Cu合金时效温度与析出序列的关系进行全面分析，涉及多个相互作用的机理（如析出动力学、过饱和度、相变驱动力等），需要综合运用材料科学原理进行推理解释。题目不仅要求描述现象，还需要分析温度变化对析出路径和硬化性能的影响机制，属于该题型下最高难度的复杂现象全面分析。" + }, + { + "idx": 981, + "question": "How does crystal structure affect atomic diffusion in metals or alloys?", + "answer": "In crystal structures with low symmetry, there is anisotropy in diffusion coefficients, such as in hexagonal crystals where the diffusion coefficients parallel and perpendicular to the basal plane (0001) differ.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体结构如何影响原子扩散，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析晶体结构对原子扩散的影响，涉及晶体对称性与扩散系数的各向异性关系，需要综合运用晶体学和扩散理论的知识，进行机理层面的解释和推理分析。 | 难度: 在简答题题型中，该题目要求对晶体结构如何影响原子扩散进行机理深度解释，涉及晶体对称性和扩散系数的各向异性等复杂概念。虽然不需要全面分析所有可能的复杂现象，但需要对特定机理进行详细阐述，属于较高难度的简答题。" + }, + { + "idx": 982, + "question": "What are the characteristics of the phase transformation products in the solid-state phase transformation of metals?", + "answer": "There are metastable phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属固态相变产物的特征，需要文字论述而非选择、判断或计算 | 知识层次: 题目涉及金属固态相变产物的特征，需要理解相变的基本原理并能够关联不同相变产物的特性，属于中等应用层次。虽然答案给出了“亚稳相”这一特征，但完整的回答需要解释亚稳相的形成原因及其在相变中的作用，这需要一定的概念关联和综合分析能力。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及金属固态相变的产物特征，但答案仅提到亚稳相这一概念，并未要求深入分析相变机制、影响因素或多相共存等复杂内容。解题步骤相对简单，只需准确描述相变产物的基本特征即可，不需要多角度或深度关联性分析。因此在该题型框架内属于等级3的综合分析和说明难度。" + }, + { + "idx": 983, + "question": "Taking the Al-4.5%Cu alloy as an example, analyze the decomposition process of supersaturated solid solution (precipitation sequence).", + "answer": "After solution treatment of the Al-4.5%Cu alloy, aging at the optimal temperature of ~150°C will result in the precipitation sequence: GP zones are regions enriched with copper atoms; θ' is a metastable phase with a tetragonal structure, disk-shaped, precipitating along the {100} planes of the matrix, possessing coherent/semi-coherent interfaces with specific orientation relationships to the matrix; θ is a stable phase with a tetragonal structure, irregular in shape.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析过饱和固溶体的分解过程（沉淀序列），需要详细的文字解释和论述，答案也提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目要求分析Al-4.5%Cu合金过饱和固溶体的分解过程（析出序列），涉及多个析出相（GP区、θ'相、θ相）的形成条件、晶体结构、形貌特征以及与基体的界面关系。这需要综合运用材料科学中的相变理论、晶体学知识和析出强化机理，进行多层次的推理和解释，属于复杂分析层次。 | 难度: 在简答题中属于机理深度解释难度，需要详细描述Al-4.5%Cu合金过饱和固溶体的分解过程，包括GP区、θ'相和θ相的形成及其结构特征，涉及复杂的相变机理和界面关系分析。虽然不涉及多系统比较或跨学科整合，但对单一系统的机理解释要求较高。" + }, + { + "idx": 984, + "question": "What is the driving force for solid-state phase transformation?", + "answer": "The driving force for solid-state phase transformation is the free energy difference between the new and old phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释固态相变的驱动力，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查对固态相变驱动力的基本概念记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答固态相变的驱动力这一基本定义，属于最基础的概念记忆层面。不需要额外的解释或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 985, + "question": "Both allotropic transformation and recrystallization transformation occur through nucleation and growth mechanisms. What are the differences between them?", + "answer": "Allotropic transformation is a phase transition process, where the derivative of a certain thermodynamic quantity becomes discontinuous; recrystallization transformation is merely the reformation of grains and not a phase transition process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两种转变过程的区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求比较两种不同的转变机制（同素异构转变和再结晶转变），涉及对相变过程和非相变过程的理解，需要综合分析两种转变的异同点。虽然涉及基础概念，但需要将多个知识点关联起来进行分析，属于中等应用层次。 | 难度: 在简答题中，该题目要求对两种不同的转变机制进行比较分析，涉及对相变和非相变过程的理解，需要综合运用材料科学中的热力学和动力学知识。虽然题目提供了明确的比较点（成核与生长机制），但需要深入解释两者的本质区别，包括热力学量的不连续性和晶粒重组的概念。这超出了基础概念复述的范畴，属于多角度分析论述的难度等级。" + }, + { + "idx": 986, + "question": "What are the characteristics of solid-state phase transformation in metals in terms of growth?", + "answer": "Exhibits habit plane phenomena, with specific microstructural morphologies such as plate-like or needle-like.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属中固态相变的生长特性，答案提供了文字描述和论述，符合简答题的特征。 | 知识层次: 题目要求解释固态相变在金属中的生长特性，涉及习惯面现象和特定显微组织形态的形成，需要综合运用相变理论、晶体学知识和显微组织分析，属于复杂分析和机理解释的范畴。 | 难度: 在简答题题型中，该题目要求对固态相变的生长特性进行机理深度解释，涉及习惯面现象和特定显微组织形态的描述。虽然不需要全面分析复杂现象，但需要对相变机理有较深入的理解和解释能力，属于该题型中较高难度的题目。" + }, + { + "idx": 987, + "question": "How to eliminate or improve macrostructure defects in steel ingots?", + "answer": "Macro defects (chemical inhomogeneity, physical inhomogeneity, and structural inhomogeneity) are often interrelated. Generally, it is desirable to have as many and fine central equiaxed crystals as possible. Methods such as adding inoculants, increasing cooling rate, and enhancing liquid movement (e.g., electromagnetic stirring, mechanical stirring) can be used to refine grains and eliminate columnar crystals. In this way, macro segregation, shrinkage cavities, and gas bubbles associated with columnar/dendritic crystal zones are significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何消除或改善钢锭中的宏观结构缺陷，答案提供了详细的解决方法和原理说明，符合简答题的特征。 | 知识层次: 题目要求解释和论述如何消除或改善钢锭中的宏观结构缺陷，涉及多种方法的综合运用（如添加孕育剂、增加冷却速率、增强液体运动等），需要理解缺陷形成的机理以及不同方法对缺陷改善的作用机制。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对钢锭宏观缺陷的消除或改善方法进行机理深度解释。需要综合运用材料科学知识，分析宏观缺陷的成因（化学不均匀性、物理不均匀性、结构不均匀性），并提出具体的解决方案（如添加孕育剂、提高冷却速率、增强液体流动等）。此外，还需要解释这些方法如何通过细化晶粒和消除柱状晶来改善宏观偏析、缩孔和气孔等缺陷。这种要求机理解释和综合分析的题目在简答题中属于较高难度，但尚未达到最复杂的全面分析水平。" + }, + { + "idx": 988, + "question": "What are the common macrostructural defects in steel ingots?", + "answer": "Macro defects include: macrosegregation (such as normal segregation, inverse segregation, gravity segregation), banded structure, as well as shrinkage cavities, porosity, and blowholes. Strictly speaking, it also includes the structural inhomogeneity of the three-crystal zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释钢锭中常见的宏观结构缺陷，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对钢锭宏观缺陷类型的基本概念记忆和分类理解，不需要复杂的分析或综合应用 | 难度: 在简答题题型中，该题目要求解释和描述钢锭中常见的宏观结构缺陷，包括宏观偏析（如正常偏析、逆偏析、重力偏析）、带状组织以及缩孔、气孔等。虽然涉及多个概念，但都属于基础概念记忆范畴，不需要复杂的体系阐述或深入分析。因此，在简答题题型内属于中等难度（等级2）。" + }, + { + "idx": 989, + "question": "What is the driving force of recovery recrystallization?", + "answer": "The driving force of recovery recrystallization is deformation stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案是一个简短的文字描述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对恢复再结晶驱动力的基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答恢复再结晶的驱动力这一基础概念，不需要进行概念解释或复杂体系阐述，属于最基础的定义性知识记忆层面。" + }, + { + "idx": 990, + "question": "Please briefly describe the basic conditions for the crystallization of binary alloys.", + "answer": "Thermodynamic condition: $\\\\Delta G<0$; structural condition: $r>r^{*}$; energy condition: $A>\\\\Delta G_{\\\\mathrm{max}}$; composition condition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述二元合金结晶的基本条件，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对二元合金结晶基本条件的记忆和理解，属于基础概念和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述二元合金结晶的基本条件，涉及热力学条件、结构条件、能量条件和成分条件等多个概念，但不需要深入阐述或分析复杂的概念体系。回答时需要对这些条件进行基本的解释和描述，属于中等难度的简答题。" + }, + { + "idx": 991, + "question": "Describe the common internal and external interfaces in metal crystals.", + "answer": "They include grain boundaries, phase boundaries, surfaces, twin boundaries, and stacking faults. Grain boundaries are the interfaces between grains of the same type; phase boundaries are the interfaces between phases with different structures and compositions; surfaces are the interfaces between crystals and the atmosphere or external environment; twin boundaries are new interfaces formed after twinning, which are special high-angle grain boundaries and can be coherent or semi-coherent; low-energy stacking faults are new interfaces formed within a single-phase crystal due to anomalous changes in stacking sequence, which are also low-energy interfaces with energy levels similar to twin boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述金属晶体中常见的内部和外部界面，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查金属晶体中常见内部和外部界面的基本概念和分类，主要涉及记忆和理解这些界面的定义和特点，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求描述金属晶体中常见的内部和外部界面，包括晶界、相界、表面、孪晶界和堆垛层错等，并简要说明它们的定义和特点。虽然涉及多个概念，但每个概念的解释相对直接，不需要复杂的推理或综合多个知识体系。因此，在简答题题型内属于中等难度，即等级2。" + }, + { + "idx": 992, + "question": "Please briefly describe the microscopic mechanisms of diffusion.", + "answer": "Substitutional mechanism: including vacancy mechanism and direct exchange or ring exchange mechanisms, among which the vacancy mechanism is the primary one, while direct exchange and ring exchange mechanisms require high activation energy and generally only occur at high temperatures. Interstitial mechanism: including interstitial mechanism and interstitialcy mechanism, among which the interstitial mechanism is the primary one.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述扩散的微观机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查扩散的微观机制的基本概念记忆和理解，包括替代机制和间隙机制的分类及其主要类型，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，题目要求描述扩散的微观机制，包括置换机制和间隙机制的具体分类和特点。虽然涉及多个概念，但主要是对基础概念的解释和描述，不需要进行复杂的体系阐述或深入分析。" + }, + { + "idx": 993, + "question": "What are the factors that affect diffusion?", + "answer": "The main factors affecting diffusion include: temperature (the higher the temperature, the faster the diffusion rate); crystal structure and type (including packing density, solid solubility, anisotropy, etc.); crystal defects; chemical composition (including concentration, third element, etc.).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响扩散的因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查扩散影响因素的基本概念记忆和理解，属于基础概念层次，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释影响扩散的主要因素，涉及多个概念（如温度、晶体结构、晶体缺陷、化学成分等）的描述和解释。虽然需要列举和解释多个因素，但每个因素的解释相对直接，不需要深入分析或构建复杂的逻辑关系。因此，在简答题题型中属于中等难度（等级2），介于基本定义简答和复杂概念体系阐述之间。" + }, + { + "idx": 994, + "question": "Please briefly describe the mechanism of low-temperature recovery and its driving force", + "answer": "Low-temperature mechanism: corresponds to the disappearance of vacancies. Driving force: release of stored energy (mainly lattice distortion energy) generated during cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述低温回复的机制及其驱动力，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对低温回复机制及其驱动力这一基础概念的记忆和理解，属于材料科学中的基本原理知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释低温回复的机制及其驱动力，涉及概念解释和描述，但不需要复杂的体系阐述。属于概念解释和描述的中等难度水平。" + }, + { + "idx": 995, + "question": "What is the difference between kinks and jogs produced when two dislocations intersect?", + "answer": "The intersection of dislocations belongs to the interaction between dislocations, resulting in a bend on each other's dislocation line with a magnitude and direction equal to its Burgers vector. This bend is called a kink or a jog. A kink is the bend produced after intersection that lies on the original slip plane and does not affect the movement of the dislocation, making it easy to disappear. A jog is the bend that does not lie on the original slip plane and affects the slip of the dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释kinks和jogs的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对位错相互作用中kinks和jogs的基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释位错相交时产生的kinks和jogs的区别，需要考生理解并描述这两个概念的定义及其对位错运动的影响。虽然涉及多个概念，但不需要复杂的体系阐述或深入分析，属于中等难度的概念解释题。" + }, + { + "idx": 996, + "question": "Please briefly describe the mechanism of medium-temperature recovery and its driving force", + "answer": "Medium-temperature mechanism: corresponds to the slip (rearrangement, annihilation) of dislocations. Driving force: the release of stored energy (mainly lattice distortion energy) generated during cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述中温回复的机制及其驱动力，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求解释中等温度回复的机制及其驱动力，涉及位错的滑移、重排和湮灭等微观过程，以及储存能的释放等机理，需要综合运用材料科学中的变形和回复理论，进行推理分析和机理解释。 | 难度: 在简答题题型中，该题目要求对中温回复的机理和驱动力进行解释，涉及位错的滑移、重排和湮灭等概念，以及储存能的释放机制。虽然需要一定的综合分析和推理能力，但相对于全面分析复杂现象的等级5题目，该题目的深度和复杂性稍低，属于机理深度解释的等级4难度。" + }, + { + "idx": 997, + "question": "Please briefly describe the mechanism of high-temperature recovery and its driving force", + "answer": "High-temperature mechanism: corresponds to polygonization (dislocation slip + climb). Driving force: release of stored energy (mainly lattice distortion energy) generated during cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述高温回复的机制及其驱动力，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高温回复的机制及其驱动力，涉及位错滑移和攀移等多重概念的综合运用，需要深入理解材料变形和回复过程中的能量变化和微观结构演变，属于机理层面的解释和分析。 | 难度: 在简答题题型中，该题目要求对高温回复的机理进行深度解释，包括位错滑移和攀移的具体过程，以及驱动力的来源（储存能的释放）。这需要学生对材料科学中的位错理论和能量概念有较深入的理解，并能将这些概念综合运用来解释复杂现象。虽然题目没有要求全面分析所有相关因素（如不同材料的具体行为），但仍属于机理深度解释的范畴，因此在简答题题型中属于较高难度（等级4）。" + }, + { + "idx": 998, + "question": "Please analyze the characteristics and mechanisms of work hardening.", + "answer": "Work hardening: is the strengthening caused by the multiplication of dislocations due to plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析工作硬化的特性和机制，需要文字解释和论述，答案也提供了简要的解释说明，符合简答题的特征。 | 知识层次: 题目要求分析加工硬化的特征和机制，涉及对位错增殖等微观机制的深入理解和解释，需要综合运用材料科学知识进行推理分析，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对加工硬化的特性和机理进行深度解释，涉及位错增殖和塑性变形的综合理解。虽然不需要全面分析复杂现象（如等级5的要求），但仍需对材料科学中的核心机理进行准确描述和推理分析，属于该题型中较高难度的题目。" + }, + { + "idx": 999, + "question": "Please analyze the characteristics and mechanisms of grain refinement strengthening.", + "answer": "Grain refinement strengthening: It is caused by the increase in the number of grains and the decrease in their size, which increases the resistance to continuous dislocation slip, leading to strengthening. At the same time, the dispersion of slip also enhances plasticity. This strengthening mechanism is the only one that can simultaneously increase both strength and plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶粒细化强化的特性和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析晶粒细化强化的特性和机制，涉及对材料强化机理的深入理解和解释，需要综合运用材料科学中的相关概念和原理，进行推理分析。这超出了简单记忆或基本应用的范畴，属于复杂分析的层次。 | 难度: 在简答题中属于机理深度解释难度，需要详细阐述晶粒细化强化的特征和机制，包括晶粒数量增加、尺寸减小对位错滑移阻力的影响，以及同时提高强度和塑性的独特机制。这要求考生不仅理解基本概念，还能进行机理层面的深入分析和解释。" + }, + { + "idx": 1000, + "question": "Assuming that the slip system that can be activated in a face-centered cubic crystal is (111)[011], if the slip dislocation is a pure edge dislocation, please indicate the direction of its dislocation line.", + "answer": "The direction of the dislocation line for a pure edge dislocation is perpendicular to $\\vec{b}$ and lies on the slip plane, which is [211].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案需要详细说明位错线的方向及其与滑移面和滑移方向的关系，而不是简单的选择或判断。 | 知识层次: 题目需要理解面心立方晶体中的滑移系统概念，并能够将位错线与滑移方向的关系进行综合分析。虽然涉及基础概念，但需要通过多步推理和概念关联来确定位错线的方向，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度。题目要求不仅需要理解面心立方晶体中的滑移系统（111）[011]，还需要明确纯刃位错的性质，即位错线方向必须垂直于柏氏矢量且位于滑移面上。解题过程中需要综合运用晶体学方向指数计算、位错基本性质分析，并通过向量叉积确定[211]方向。这种需要多步骤计算和概念关联的综合性分析，在简答题中属于较高难度层级。" + }, + { + "idx": 1001, + "question": "Assuming that the active slip system in a face-centered cubic crystal is (111)[011], if the slip dislocation is a pure screw dislocation, what is the direction of the dislocation line?", + "answer": "The dislocation line of a pure screw dislocation is parallel to $\\\\vec{b}$, which is [011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错线的方向，答案提供了详细的解释和方向说明，符合简答题的特征。 | 知识层次: 题目考查对纯螺型位错线方向与伯格斯矢量关系的记忆和理解，属于基础概念的直接应用 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答纯螺型位错线的方向，这只需要记忆和理解位错线方向与柏氏矢量平行的基本原理即可。不需要进行复杂的概念解释或体系阐述，属于该题型内最基础的难度级别。" + }, + { + "idx": 1002, + "question": "Please analyze the characteristics and mechanisms of solid solution strengthening.", + "answer": "Solid solution strengthening: Due to solute atoms impeding dislocation motion. Includes elastic interaction (Cottrell atmosphere), electrical interaction (Suzuki atmosphere), and chemical interaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析固溶强化的特性和机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析固溶强化的特性和机制，涉及多种相互作用（弹性、电性、化学）对位错运动的阻碍作用，需要综合运用材料科学知识进行机理解释和综合分析，思维深度要求较高。 | 难度: 在简答题题型中，该题目要求对固溶强化的特性和机理进行解释，涉及弹性相互作用、电相互作用和化学相互作用等多个方面。虽然题目没有要求极其深入的分析，但需要对相关概念有较好的理解，并能综合运用这些知识进行解释。因此，在简答题题型中属于机理深度解释的难度等级。" + }, + { + "idx": 1003, + "question": "Assuming that the active slip system in a face-centered cubic crystal is (111)[011], please provide the Burgers vector of the unit dislocation for the slip.", + "answer": "The Burgers vector of the unit dislocation is ${\\vec{b}}={\\frac{a}{2}}$ [011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供Burgers vector的具体表达式，需要基于材料科学知识进行解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对Burgers向量基本概念的记忆和理解，需要知道在面心立方晶体中单位位错的Burgers向量如何表示，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并描述面心立方晶体中特定滑移系(111)[011]的位错柏氏向量，需要掌握基本的晶体学知识和位错理论，但不需要进行复杂的推导或体系阐述。解题步骤主要是回忆和应用基本公式，属于中等难度的概念性简答题。" + }, + { + "idx": 1004, + "question": "Please analyze the characteristics and mechanisms of dispersion strengthening (age strengthening).", + "answer": "Dispersion strengthening (age strengthening): It is the strengthening caused by fine dispersed second phases hindering dislocation motion. This includes the shearing mechanism and the bypassing mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析分散强化（时效强化）的特性和机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析弥散强化（时效强化）的特性和机理，涉及对位错运动阻碍的详细机制（剪切机制和绕过机制）的解释。这需要综合运用材料科学中的强化理论，理解不同机制的作用原理，并进行机理层面的深入分析，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对分散强化（时效强化）的特性和机理进行解释，涉及剪切机制和绕过机制的具体分析。虽然题目没有要求非常深入的机理探讨，但仍需要综合运用相关知识进行推理和解释，属于机理深度解释的难度等级。" + }, + { + "idx": 1005, + "question": "Please analyze the characteristics and mechanisms of multiphase strengthening.", + "answer": "Multiphase strengthening: When the relative content of the second phase is on the same order of magnitude as the matrix, strengthening occurs. The degree of strengthening depends on the quantity, size, distribution, and morphology of the second phase, and if the strength of the second phase is lower than that of the matrix, it may not contribute to strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析多相强化的特性和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析多相强化的特性和机制，涉及多因素的相互作用（如第二相的数量、尺寸、分布和形态），需要综合运用材料科学知识进行推理和解释，思维过程较为深入。 | 难度: 在简答题题型中，该题目要求对多相强化的特性和机理进行详细解释，涉及第二相的数量、尺寸、分布和形态等多个因素的综合分析。虽然不需要全面分析复杂现象，但需要对机理进行深度解释，属于较高难度的简答题。" + }, + { + "idx": 1006, + "question": "If a piece of iron is heated from room temperature 20°C to 850°C, then cooled very quickly to 20°C, calculate the change in the number of vacancies before and after the treatment (assuming the energy required to form 1 mole of vacancies in iron is 104600J).", + "answer": "$$ \\\\cdot\\\\frac{c_{850\\\\mathrm{PC}}}{c_{20\\\\mathrm{PC}}}=\\\\frac{A\\\\mathrm{e}^{-\\\\frac{\\\\Delta E}{k\\\\cdot(850+273)}}}{A\\\\mathrm{e}^{-\\\\frac{\\\\Delta E}{k\\\\cdot(20+273)}}}=\\\\mathrm{e}^{-\\\\frac{104675}{1123\\\\times8.31}\\\\frac{104675}{293\\\\times8.31}}=6.3\\\\times10^{13}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括温度转换、玻尔兹曼因子计算和指数运算，同时需要理解空位形成能与温度的关系。虽然不涉及复杂的机理分析或创新设计，但需要综合应用热力学和缺陷化学的知识。 | 难度: 在计算题中属于综合性计算问题，需要应用热力学公式进行多步计算，涉及温度转换、指数运算和单位换算，同时需要理解空位形成能的概念并将其与温度变化关联起来。虽然计算步骤较多，但整体思路清晰，属于中等偏上的难度。" + }, + { + "idx": 1007, + "question": "From the perspective of bonding, analyze the characteristics of metallic materials", + "answer": "Metallic materials: Primarily bonded by metallic bonds, most metals exhibit high strength and hardness, along with good plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合角度分析金属材料的特性，需要文字解释和论述，答案也是以文字形式给出对金属材料特性的分析说明 | 知识层次: 题目要求从键合角度分析金属材料的特性，涉及对金属键的理解、材料性能与键合关系的综合分析，以及推理分析能力，属于较高层次的认知要求。 | 难度: 在简答题中，该题目要求从键合角度分析金属材料的特性，涉及对金属键的理解和材料性能的关联解释。虽然不需要全面分析复杂现象，但需要对机理进行一定深度的解释，属于机理深度解释的难度等级。" + }, + { + "idx": 1008, + "question": "From the perspective of bonding, analyze the characteristics of polymer materials", + "answer": "Polymer materials: primarily covalent bonds within molecules, with intermolecular forces mainly consisting of molecular bonds and hydrogen bonds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合角度分析高分子材料的特性，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求从键合的角度分析高分子材料的特性，需要综合运用化学键理论、分子间作用力等知识，进行推理分析和机理解释，涉及多个概念的关联和深度理解。 | 难度: 在简答题-复杂分析题型中，该题目要求从键合角度深入分析高分子材料的特性，涉及分子内共价键和分子间作用力（分子键和氢键）的机理解释。虽然不需要全面分析复杂现象，但需要对键合类型及其对材料性能的影响有较深的理解和解释能力，属于机理深度解释的难度等级。" + }, + { + "idx": 1009, + "question": "What are the common characteristics of the two major types of ceramic crystalline phases?", + "answer": "(1) The bonding is primarily ionic, with a certain proportion of covalent bonding; (2) They have a definite composition that can be expressed by an exact chemical formula; (3) They exhibit typical non-metallic properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释陶瓷晶相的常见特征，答案以文字形式列出多个要点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查陶瓷晶相的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举陶瓷晶体相的常见特征，涉及对基础概念的记忆和简单解释，但不需要复杂的体系阐述或多层次分析。虽然需要回答三个具体特征，但每个特征都是基础概念的直接应用，没有涉及复杂的推理或综合判断。" + }, + { + "idx": 1010, + "question": "From the perspective of bonding types, analyze the characteristics of composite materials", + "answer": "Composite materials: artificial combinations of the above three basic materials, with a wide variety of bonding types and significant performance differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合类型的角度分析复合材料的特点，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求从键合类型的角度分析复合材料的特性，这需要理解不同键合类型的基本原理，并将这些原理与复合材料的性能关联起来进行分析。虽然不涉及复杂的计算或创新设计，但需要多步的概念关联和综合分析，超出了单纯记忆或简单应用的层次。 | 难度: 在简答题题型内，该题目要求从键合类型的角度分析复合材料的特性，这需要考生综合理解不同键合类型的特点，并将其与复合材料的性能差异进行关联分析。虽然不需要进行深度关联性分析（等级5），但需要多角度论述（等级4），包括对基本材料键合类型的理解、复合材料的人工组合特性以及性能差异的解释。因此，该题目在简答题题型内属于较高难度。" + }, + { + "idx": 1011, + "question": "What are the two major categories of ceramic crystal phases?", + "answer": "Oxide ceramics and silicate ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述两种主要的陶瓷晶体相类别，答案提供了具体的分类名称而非选择或判断 | 知识层次: 题目考查陶瓷晶体相的两大主要分类，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答陶瓷晶相的两大主要类别，属于基础定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可作答，因此属于该题型内最低难度等级。" + }, + { + "idx": 1012, + "question": "What are the characterization methods for dislocation density?", + "answer": "There are two methods: volume density, which is the length of dislocation lines per unit volume; and surface density, which is the number of dislocation lines perpendicularly passing through a unit area.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释位错密度的表征方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对位错密度表征方法的基本概念记忆和理解，仅需回答两种方法的定义和简单描述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释位错密度的表征方法，涉及两个具体方法的定义和简要说明，但不需要深入分析或复杂的概念体系阐述。这比基本定义简答（等级1）要求更高，但低于需要复杂概念体系阐述（等级3）的题目。" + }, + { + "idx": 1013, + "question": "From the perspective of bonding, analyze the characteristics of ceramic materials", + "answer": "Ceramic materials: primarily covalent and ionic bonds, hard, brittle, difficult to deform, high melting point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从键合角度分析陶瓷材料的特性，需要文字解释和论述，答案也是以文字形式呈现的简要论述。 | 知识层次: 题目考查陶瓷材料的基本键合特性及其相关性质，属于基础概念的记忆和理解，不涉及复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求从键合角度分析陶瓷材料的特性，涉及对共价键和离子键的基本理解以及这些键合方式对材料性能的影响。虽然需要一定的概念解释和描述，但不需要复杂的体系阐述或深入的分析。属于概念解释和描述的中等难度级别。" + }, + { + "idx": 1014, + "question": "Compare the activation energies of substitutional diffusion and interstitial diffusion.", + "answer": "In comparison, the activation energy of interstitial diffusion is smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种扩散方式的激活能，需要文字解释和论述，答案也是以文字形式给出比较结果，而非选择、判断或计算。 | 知识层次: 题目要求比较两种扩散机制的激活能，需要理解并关联替代扩散和间隙扩散的基本概念，分析其差异，并进行综合比较。这超出了单纯记忆的层次，属于中等应用水平。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较两种扩散机制的激活能，但只需要进行基本的概念对比和简单解释，不需要深入的多角度分析或复杂的关联性论述。解题步骤相对直接，主要考察对基础概念的理解和应用能力。" + }, + { + "idx": 1015, + "question": "For cold-rolled pure copper sheets, if high strength is required, what heat treatment should be performed?", + "answer": "To maintain high strength, low-temperature annealing should be performed to allow only recovery and eliminate residual stresses.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应该进行何种热处理以获得高强度，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求根据冷轧纯铜板材的性能需求选择适当的热处理方法，涉及材料加工工艺与性能关系的综合分析，需要理解冷加工后的材料状态及不同热处理工艺（如低温退火）对材料性能的影响机制，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解冷轧纯铜板材的性能特点，并关联热处理工艺（低温退火）与强度保持的关系。题目要求综合分析材料加工工艺与性能的关联性，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1016, + "question": "For cold-rolled pure copper sheets, what heat treatment should be performed if further cold rolling to reduce thickness is required?", + "answer": "To continue cold deformation, high-temperature annealing should be conducted to induce recrystallization and soften the microstructure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应该进行何种热处理以继续冷轧，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解冷轧纯铜板材的加工硬化现象，并应用再结晶退火的知识来解决问题。这涉及到材料加工工艺与微观结构变化之间的关联，属于中等应用层次，需要综合分析冷变形和热处理的关系，但不需要深入机理分析或创新设计。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要学生理解冷轧纯铜板材的热处理原理，并能够关联再结晶和软化微观结构的概念。虽然题目涉及多步思考和概念关联，但并不需要多角度分析或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 1017, + "question": "What is the physical meaning of diffusion activation energy?", + "answer": "The physical meaning of diffusion activation energy is the energy barrier that must be overcome during atomic jumps, which is the obstruction posed by surrounding atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散激活能的物理意义，答案需要文字解释和论述，没有提供选项或要求计算。 | 知识层次: 题目考查扩散激活能的基本概念和物理意义的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释扩散激活能的物理意义，这需要学生对基础概念有一定的理解和记忆，但不需要复杂的体系阐述或多步骤推理。属于对单一概念进行解释的中等难度题目。" + }, + { + "idx": 1018, + "question": "Analyze the effect of cold plastic deformation on the microstructure of alloys", + "answer": "1) Microstructure: 1 Formation of fibrous structure, grains are elongated along the deformation direction; 2 Formation of dislocation cells; 3 Grain rotation forms deformation texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金微观结构的影响，需要详细的文字解释和论述，答案也以列举和描述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金微观结构的影响，涉及多个微观结构变化的解释（如纤维结构形成、位错胞形成、变形织构等），需要综合运用材料科学中的塑性变形理论、位错理论和织构形成机理等知识进行推理分析，思维过程深度较高。 | 难度: 在简答题中属于机理深度解释难度，需要详细描述冷塑性变形对合金微观结构的具体影响，包括纤维结构的形成、位错胞的形成以及变形织构的形成。这些知识点要求考生不仅掌握基本概念，还需要理解变形过程中的微观机制，并能系统性地阐述这些变化。虽然不涉及多个复杂现象的交叉分析，但对机理的解释深度要求较高，因此属于等级4。" + }, + { + "idx": 1019, + "question": "Given a certain low-carbon steel with $\\sigma_{0}=64\\mathrm{kPa}$, $K=393.7\\mathbf{k}\\mathbf{Pa}\\cdot\\mu\\mathbf{m}^{\\frac{1}{2}}$, and a grain diameter of $50\\mu\\mathrm{m}$, what is the yield strength of this low-carbon steel?", + "answer": "According to the Hall-Petch formula: $$\\sigma_{\\mathrm{s}}=\\sigma_{0}+K d^{-{\\frac{1}{2}}}=(64+393.7\\times50^{-{\\frac{1}{2}}})\\mathbf{kPa}=(64+55.68)\\mathbf{kPa}=119.7\\mathbf{kPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的参数和公式（Hall-Petch公式）进行数值计算，最终得出一个具体的数值结果（yield strength）。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查Hall-Petch公式的直接应用和简单计算，不需要多步推理或综合分析，属于基本公式的直接套用和数值计算。 | 难度: 在计算题中属于最低难度，仅需直接套用Hall-Petch公式进行单一计算，无需多步推导或组合公式。题目提供了所有必要参数，计算过程仅涉及基本代数运算和单位换算，完全符合等级1\"单一公式直接计算\"的标准特征。" + }, + { + "idx": 1020, + "question": "Given that for carbon diffusion in γ-Fe, D0=2.0×10^(-5)m²/s, Q=1.4×10^5J/mol, gas constant R=8.314J/(mol·K), calculate the diffusion coefficient D927°C at 927°C.", + "answer": "D927°C = D0 * exp(-Q / (R * T)) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * (927 + 273))) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * 1200)) = 2.0×10^(-5) * exp(-14.033) ≈ 2.0×10^(-5) * 8.315×10^(-7) ≈ 1.663×10^(-11) m²/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数D的具体数值，属于典型的计算题类型。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及基本公式的套用和单位转换，不需要多步计算或复杂分析。 | 难度: 在计算题中属于最简单难度，只需要直接套用单一扩散系数公式（D = D0 * exp(-Q/RT)），进行简单的单位换算（摄氏度转开尔文）和数值计算。所有参数都已明确给出，无需额外推导或组合多个公式。" + }, + { + "idx": 1021, + "question": "Calculate the packing density of the most densely packed plane in a BCC crystal.", + "answer": "The most densely packed plane in BCC is the {110} plane, and its area is: $A=a\\\\times{\\\\sqrt{2}}a={\\\\sqrt{2}}a^{2}$ \\n\\nThe area occupied by atoms on the {110} plane (two atoms) is: $$A^{\\\\prime}=2\\\\times\\\\pi R^{2}=2\\\\pi{\\\\left(\\\\frac{\\\\sqrt{3}}{4}a\\\\right)}^{2}=\\\\frac{3}{8}\\\\pi a^{2}$$ The packing density: $d=\\\\frac{A^{\\\\prime}}{A}=\\\\frac{3}{8\\\\sqrt{2}}\\\\pi=0.8332$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了面积计算、原子半径与晶格常数的关系以及最终的密度计算，这些都是典型的计算题特征。答案给出了具体的计算步骤和最终数值结果，符合计算题的特点。 | 知识层次: 题目需要进行多步计算，包括确定最密排面、计算面积、计算原子占据面积以及最终的堆积密度计算。虽然涉及基本概念（如BCC结构、堆积密度），但需要将这些概念关联起来进行综合分析，思维过程有一定的深度要求。 | 难度: 在计算题中属于综合性计算问题，需要理解BCC晶体结构、最密排面的确定、面积计算以及原子半径与晶格常数的关系等多个概念，并进行多步计算和综合分析。虽然计算步骤较多，但每一步都有明确的公式和方法可循，不需要处理复杂多变量或非常规计算。" + }, + { + "idx": 1022, + "question": "Given that for carbon diffusion in γ-Fe, D0=2.0×10^(-5)m²/s, Q=1.4×10^5J/mol, gas constant R=8.314J/(mol·K), calculate the diffusion coefficient D1027°C at 1027°C.", + "answer": "D1027°C = D0 * exp(-Q / (R * T)) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * (1027 + 273))) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * 1300)) = 2.0×10^(-5) * exp(-12.953) ≈ 2.0×10^(-5) * 2.394×10^(-6) ≈ 4.788×10^(-11) m²/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及扩散系数的计算，需要代入给定的参数并使用阿伦尼乌斯公式进行计算。答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式（阿伦尼乌斯方程）的直接应用和简单计算，涉及温度单位转换和指数运算，但不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用阿伦尼乌斯公式进行简单的数值代入和计算，无需多个公式组合或复杂的解题步骤。" + }, + { + "idx": 1023, + "question": "Analyze the effect of cold plastic deformation on the energy of the alloy system", + "answer": "(4) The system energy includes two parts: 1 The lattice distortion caused by a large number of defects generated during cold deformation increases the distortion energy; 2 The microscopic and macroscopic internal stresses caused by uneven deformation between grains and different parts of the workpiece. These two parts are collectively referred to as stored energy, with the former being the primary. The changes in microstructure and properties caused by cold deformation prepare the alloy for subsequent recovery and recrystallization in terms of both structure and energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金系统能量的影响，答案提供了详细的文字解释和论述，包括两部分能量的变化及其对后续恢复和再结晶的影响，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金系统能量的影响，涉及多个方面的综合理解，包括缺陷导致的晶格畸变、微观和宏观内应力、储存能的概念及其在后续回复和再结晶中的作用。这需要深入理解材料变形过程中的微观机制和能量变化，并进行综合分析和解释。 | 难度: 在简答题题型中，该题目要求对冷塑性变形对合金系统能量的影响进行机理深度解释。需要分析两部分能量变化（晶格畸变能和储存能），并解释这些变化如何为后续回复和再结晶提供结构和能量准备。虽然不涉及多因素交互作用的全面分析，但需要对材料变形机理有较深入的理解，属于机理深度解释的难度等级。" + }, + { + "idx": 1024, + "question": "Analyze the effect of cold plastic deformation on the mechanical properties of alloys", + "answer": "(2) Mechanical properties: The dislocation density increases, dislocations become entangled with each other, and the resistance to movement increases, resulting in work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金力学性能的影响，涉及位错密度增加、位错纠缠和加工硬化等机理的解释。这需要综合运用材料科学中的变形机制和力学性能相关知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对冷塑性变形对合金力学性能的影响进行机理深度解释。需要综合运用材料科学知识，分析位错密度增加、位错纠缠以及加工硬化等现象的机理。虽然题目涉及的知识点较为专业，但解题步骤相对明确，属于需要深入理解但不需要全面分析复杂现象的等级4难度。" + }, + { + "idx": 1025, + "question": "Calculate the multiple of change in the diffusion coefficient when the temperature increases from 927°C to 1027°C.", + "answer": "Multiple of change = D1027°C / D927°C = (4.788×10^(-11)) / (1.663×10^(-11)) ≈ 2.88 times", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算扩散系数的变化倍数），并给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需套用扩散系数与温度的关系公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需要应用扩散系数的温度变化公式进行简单计算，无需多个公式组合或复杂推导，属于最基础的计算题类型。" + }, + { + "idx": 1026, + "question": "Analyze the effect of cold plastic deformation on the physical and chemical properties of alloys", + "answer": "(3) Physical and chemical properties: The changes are complex, mainly affecting electrical conductivity, thermal conductivity, chemical activity, chemical potential, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金物理和化学性质的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析冷塑性变形对合金物理和化学性质的影响，涉及多个性质的复杂变化（如电导率、热导率、化学活性等），需要综合运用材料科学知识进行推理分析和机理解释，思维过程深度要求较高。 | 难度: 在简答题-复杂分析题型中，该题目要求分析冷塑性变形对合金物理化学性质的影响，涉及多个性质的变化（电导率、热导率、化学活性等）及其机理解释。虽然不需要全面分析所有可能的复杂现象（如等级5的要求），但仍需深入理解材料变形与性质变化的关联机制，属于机理深度解释的范畴。" + }, + { + "idx": 1027, + "question": "Analyze the characteristics of grain boundaries from the structural features of grain boundaries", + "answer": "Structural features of grain boundaries: The atomic arrangement is relatively disordered and contains a large number of defects. Characteristics of grain boundaries: (3) Numerous defects such as dislocations and vacancies—high grain boundary diffusion rate. (6) Enrichment of trace elements and impurities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶界的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析晶界的结构特征及其特性，涉及多个概念的关联和综合分析，如原子排列的无序性、缺陷的存在、扩散速率以及微量元素富集等。这需要学生不仅理解晶界的基本概念，还能将这些概念联系起来进行中等程度的分析和应用。 | 难度: 在简答题题型中，该题目要求从结构特征出发分析晶界的特性，涉及多个知识点的关联和综合分析。需要考生不仅理解晶界的结构特征（如原子排列无序、缺陷多等），还要能够将这些特征与晶界的实际特性（如高扩散率、微量元素富集等）进行逻辑关联和论述。这种多角度分析和论述的要求，使得该题目在同题型中属于较高难度等级（等级4）。虽然不需要进行深度关联性分析（等级5），但已经超出了简单的概念说明或单一特征描述（等级3）。" + }, + { + "idx": 1028, + "question": "Analyze the characteristics of grain boundaries from the perspective of their energy features", + "answer": "Energy features of grain boundaries: Atoms have higher energy and stronger activity compared to the grain interior. Characteristics of grain boundaries: (1) Grain boundary—distortion—grain boundary energy—transformation to a lower energy state—grain growth, grain boundary straightening—reduction in grain boundary area. (2) Hindering dislocation movement—increase in σb—grain refinement strengthening. (4) High grain boundary energy and complex structure—easily meeting the conditions for solid-state phase transformation—primary site for solid-state phase transformation. (5) Poor chemical stability—grain boundaries are prone to corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶界的特性，并从能量特征的角度进行论述。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从能量特征的角度分析晶界的特性，涉及多个方面的综合分析，包括晶界能量、晶粒生长、位错运动阻碍、固态相变条件以及化学稳定性等。这需要深入理解晶界的能量特征及其对材料性能的影响，并进行多方面的关联和推理分析，属于复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析晶界的能量特征及其对材料性能的多方面影响。需要综合运用材料科学原理，解释晶界能量与晶界行为、力学性能、相变行为和化学稳定性之间的复杂关系。解题步骤涉及多个知识点的深度整合和机理解释，属于该题型内最高难度的复杂现象全面分析类型。" + }, + { + "idx": 1029, + "question": "Dislocation", + "answer": "Dislocation: A one-dimensional or linear defect in a crystal, known as a dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征 | 知识层次: 题目考查对位错（dislocation）这一基本概念的定义和简单描述，属于基础概念的记忆和理解层面，不涉及复杂应用或分析。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述位错的基本定义，不涉及概念解释或复杂体系阐述，属于该题型内最低难度等级。" + }, + { + "idx": 1030, + "question": "Coordination number", + "answer": "Coordination number: In a crystal structure, the number of atoms that are adjacent to and equidistant from any given atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Coordination number\"进行文字解释和论述，答案是一个定义性的描述，不需要选择、判断或计算。 | 知识层次: 题目考查的是配位数这一基本概念的定义，属于材料科学中晶体结构的基础知识，主要依赖记忆和理解，无需复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"Coordination number\"进行基本定义回答，属于最基础的概念记忆性知识，不需要额外的解释或复杂概念体系的阐述。" + }, + { + "idx": 1031, + "question": "Crystal face family", + "answer": "Crystal face family: Groups of equivalent crystal faces with the same symmetrical relationship (atomic arrangement and distribution, interplanar spacing) are called a crystal face family, denoted by hll.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Crystal face family\"进行文字解释和论述，答案提供了概念的定义和特征描述，符合简答题的特点 | 知识层次: 题目考查晶体学中晶面族的基本定义和符号表示，属于基础概念的记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答晶体面族的定义和符号表示，不涉及概念解释或复杂体系阐述。这属于最基础的概念记忆层次，符合等级1的简单定义类问题特征。" + }, + { + "idx": 1033, + "question": "Heterogeneous nucleation", + "answer": "Heterogeneous nucleation: The formation of crystal nuclei in liquid metal preferentially occurs on the surfaces of foreign substances (mold walls or impurities) or at locations with temperature inhomogeneity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Heterogeneous nucleation\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对\"异质形核\"这一基础概念的定义和基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对\"heterogeneous nucleation\"进行定义和基本描述，涉及对核心概念的理解和简要解释，但不需要深入分析或阐述复杂的概念体系。这比单纯背诵定义（等级1）要求稍高，但远低于需要系统阐述多个相关概念的等级3题目。" + }, + { + "idx": 1034, + "question": "Compositional supercooling", + "answer": "Compositional supercooling: During the solidification of an alloy solution, the theoretical solidification temperature remains unchanged, and the degree of supercooling is entirely determined by the distribution of solute components. This type of supercooling is called compositional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Compositional supercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查的是对compositional supercooling这一基本概念的定义和解释，属于基础概念的记忆和理解层面，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。题目要求解释\"compositional supercooling\"的定义和基本原理，但不需要阐述复杂的相关概念体系或进行深入分析。虽然需要准确记忆专业术语的定义，但整体上仍属于基础概念记忆范畴，解题步骤相对简单，符合等级2的难度标准。" + }, + { + "idx": 1035, + "question": "Pseudoeutectic", + "answer": "Pseudoeutectic: The eutectic structure obtained from an alloy of non-eutectic composition is called pseudoeutectic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Pseudoeutectic\"进行解释和定义，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对伪共晶（Pseudoeutectic）这一基本概念的定义记忆和理解，属于材料科学中相图与凝固部分的基础知识点，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答类型。题目仅要求对\"Pseudoeutectic\"这一术语进行定义性的回答，不需要额外的解释、描述或复杂概念体系的阐述。这符合等级1的标准，即只需记忆并复述基础概念的定义即可完成作答。" + }, + { + "idx": 1037, + "question": "Please indicate the method and principle of vibration refinement for grain refinement in metallic materials.", + "answer": "Vibration refinement. By solidifying the molten metal under vibration, the nucleation rate of the liquid phase is increased on one hand, and the growing crystals are fragmented on the other hand, thereby providing more crystallization nuclei, thus achieving the purpose of grain refinement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动细化晶粒的方法和原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释振动细化晶粒的方法和原理，涉及对金属材料凝固过程中振动作用的综合分析，包括提高形核率和晶体破碎的机理，需要深入理解和推理分析多个概念之间的关联。 | 难度: 在简答题-复杂分析题型中，该题目要求对振动细化的方法和原理进行机理深度解释。需要综合运用金属凝固理论、形核机制和晶体生长等知识，并能够清晰地阐述振动如何影响形核率和晶体破碎过程。虽然不涉及多因素交互作用的全面分析，但对机理的解释要求较高，属于该题型中的较难题目。" + }, + { + "idx": 1038, + "question": "Law of the center of gravity", + "answer": "Law of the center of gravity: In a ternary alloy phase diagram, if $R$ decomposes into three phases $\\alpha,~\\beta,$ $\\gamma$, then the concentration point of $R$ phase must be located at the center of gravity of $\\Delta\\alpha\\beta\\gamma$ (which is the weight center of gravity of the three phases, not the geometric center of the triangle). Moreover, the weight of $R$ phase has the following relationship with the weights of $\\alpha$, $\\beta$, and $\\gamma$ phases: $$ \\begin{array}{r l}&{w_{R}\\times R d=w_{\\alpha}\\times\\alpha d}\\ &{w_{R}\\times R e=w_{\\beta}\\times\\beta e}\\ &{w_{R}\\times R f=w_{\\gamma}\\times\\gamma f}\\end{array}$$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对“Law of the center of gravity”进行解释和论述，答案提供了详细的文字描述和公式说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及三元合金相图中重心定律的应用，需要理解并应用重心定律进行多步计算和概念关联。虽然题目给出了具体的公式，但需要理解其物理意义和几何关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求对三元合金相图中的重心定律进行文字解释和论述，这需要深入理解相图的基本概念和重心定律的物理意义。其次，题目涉及多步计算和概念关联，需要综合运用几何和物理知识来分析相变过程。此外，题目还要求建立重量关系方程，这增加了解题的复杂程度。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 1040, + "question": "Please indicate the method of adding nucleating agents to refine the grain size of metal materials and its principle.", + "answer": "Adding nucleating agents. Before the melt solidifies, some fine nucleating agents are added and dispersed in the melt to serve as ready-made substrates required for heterogeneous nucleation, thereby significantly increasing the number of nuclei and markedly refining the grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释添加成核剂的方法及其原理，需要文字解释和论述，而不是选择、判断或计算。答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求解释添加成核剂细化金属材料晶粒的方法及其原理，涉及对成核剂作用机制的理解和实际应用的分析，需要将基本概念与实际操作相结合，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释添加成核剂细化金属材料晶粒的方法及其原理，涉及对成核剂作用机制的理解和描述。虽然需要一定的概念关联和综合分析能力，但解题步骤相对直接，不需要多角度或深度关联性分析。因此，在简答题题型内属于等级3的综合分析和说明难度。" + }, + { + "idx": 1041, + "question": "Analyze the reason why the solubility of carbon in austenite is greater than that in ferrite.", + "answer": "Austenite is a face-centered cubic crystal, while ferrite is a body-centered cubic crystal. In both face-centered cubic and body-centered cubic structures, carbon atoms are located in their octahedral interstitial sites. The size of the octahedral interstitial site in face-centered cubic is: $0.535\\\\mathring{\\\\mathbf{A}}^{\\\\odot}$, while in body-centered cubic, it is: 0.129A. Therefore, it can be seen that the solubility of carbon in austenite is much greater than that in ferrite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析碳在奥氏体和铁素体中溶解度差异的原因，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析碳在奥氏体和铁素体中溶解度差异的原因，涉及晶体结构、间隙位置尺寸的计算和比较，需要综合运用材料科学中的晶体学知识和溶解度原理，进行推理分析和机理解释。 | 难度: 在简答题的复杂分析题型中，该题目要求对晶体结构和间隙位置进行深度解释，并比较不同晶体结构对碳溶解度的具体影响。虽然题目涉及的知识点较为专业，但解题步骤相对直接，主要依赖于对晶体结构间隙尺寸的理解和比较，因此属于机理深度解释的等级4难度。" + }, + { + "idx": 1042, + "question": "Please list more than three methods to improve the strength of metal materials and explain their principles.", + "answer": "(1) Grain refinement strengthening. The principle is: increasing the number of grains to enhance the hindering effect of grain boundaries on moving dislocations, thereby achieving strengthening. (2) Solid solution strengthening. This involves dissolving solute atoms into the base metal, causing lattice distortion in the base metal, which inhibits the activity of dislocation sources and improves the strength of the base metal. (3) Work hardening. When a crystal undergoes deformation, dislocations inside the crystal pile up or become entangled, making them difficult to move, thereby strengthening the crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出并解释多种提高金属材料强度的方法，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求列出并解释三种提高金属材料强度的方法及其原理，涉及多个概念（晶粒细化强化、固溶强化、加工硬化）的关联和综合分析，需要理解各方法的原理及其对材料性能的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求列举并解释三种提高金属材料强度的方法，但每种方法的原理解释较为直接，不需要进行复杂的多角度分析或深度关联性分析。学生只需掌握基本的材料强化机制，并能够清晰地表述这些机制即可。因此，该题目在简答题题型中属于等级3的综合分析和说明难度。" + }, + { + "idx": 1043, + "question": "Write all the crystallographic directions included in the <110> direction family in the cubic crystal system.", + "answer": "[110], [101], [011], [110], [101], [011], totaling 6 crystallographic directions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中<110>方向族包含的所有晶向方向，需要文字描述和具体方向列举，不涉及选择、判断或数值计算。 | 知识层次: 题目考查立方晶系中<110>方向族包含的所有晶向的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求列举立方晶系中<110>方向族包含的所有晶向方向。虽然需要记忆立方晶系的基本对称性和方向族的概念，但不需要深入解释或推导过程。相比等级1的基本定义简答，该题目需要理解方向族的对称性关系，但不需要进行复杂的概念体系阐述，因此属于等级2难度。" + }, + { + "idx": 1044, + "question": "Write all the crystallographic directions included in the <123> direction family in the cubic crystal system.", + "answer": "[123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], totaling 24 crystallographic directions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举立方晶系中<123>方向族包含的所有结晶学方向，需要文字描述和具体列举，不涉及选择、判断或数值计算。 | 知识层次: 题目要求列举立方晶系中<123>方向族的所有晶向，这需要应用立方晶系晶向指数的对称性规则进行简单变换和列举，属于基本规则的应用，不需要复杂的分析或综合。 | 难度: 在简答题中属于中等难度，需要理解立方晶系中方向族的概念，并能够列举出所有可能的排列组合。虽然题目要求的是基本公式应用和简单计算，但需要学生掌握立方晶系中方向指数的对称性规则，并能正确列举出所有24个等效方向。这比简单的方向指数计算（等级2）要复杂一些，但不需要更深入的解释或实例分析（等级4）。" + }, + { + "idx": 1045, + "question": "Analyze the reasons for the formation of the iron-carbon dual phase diagram from a thermodynamic perspective", + "answer": "Thermodynamic analysis reveals that the total free energy of graphite is lower than that of Fe3C. Therefore, graphite is the more stable phase, while Fe3C is a metastable phase. Hence, the Fe-Fe3C system is commonly referred to as the metastable system, and the Fe-C system is called the stable system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从热力学角度分析铁碳双相图形成的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从热力学角度分析铁碳双相图形成的原因，涉及自由能比较、稳定相与亚稳相的区别，以及系统分类的深层机理解释。这需要综合运用热力学原理、相图知识，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求从热力学角度分析铁碳双相图形成的原因，涉及对自由能、稳定相和亚稳相等热力学概念的深度理解。虽然题目没有要求全面分析所有复杂现象，但需要对机理进行较为深入的解释，包括比较石墨和Fe3C的自由能差异，并推导出稳定系统和亚稳系统的结论。这属于机理深度解释的范畴，因此评为等级4。" + }, + { + "idx": 1046, + "question": "Analyze the equilibrium crystallization process of the Fe-0.4%C alloy and indicate the phase composition at room temperature", + "answer": "When C%=0.4%, the Fe-C alloy cools to room temperature, and the phase constituents are α+Fe3C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的相组成，需要文字解释和论述，答案给出了具体的相组成但没有选项或计算过程 | 知识层次: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的相组成，这需要理解Fe-C相图的基本原理，并能将特定成分（0.4%C）与相图关联起来，进行多步分析和综合判断。虽然不涉及复杂计算，但需要对相变过程和相组成有较深入的理解和应用能力。 | 难度: 在简答题中属于中等难度，需要理解Fe-C合金的平衡结晶过程，并能正确分析相组成。虽然涉及多步计算和概念关联，但题目较为直接，只需说明最终相组成即可，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1047, + "question": "Please indicate the methods and principles of refining metal grain size by increasing undercooling.", + "answer": "Increase undercooling. Since the number of grains is directly proportional to the nucleation rate N and inversely proportional to the grain growth rate Vg, increasing N/Vg can refine the grains. Moreover, when undercooling is increased, although both N and Vg increase, the rate of increase in N is faster than that in Vg. Therefore, N/Vg increases with the increase in undercooling, meaning the grains become finer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释方法和原理，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释通过增加过冷度来细化金属晶粒的方法和原理，涉及成核速率和晶粒生长速率的关系，以及过冷度对两者的影响。这需要综合运用材料科学中的相变理论、成核与生长动力学等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题 - 需要文字解释和论述的题型中，该题目属于机理深度解释的难度等级。题目要求考生不仅理解增加过冷度对金属晶粒细化的影响，还需要解释其中的机理，包括成核速率和晶粒生长速率的变化关系。这需要考生具备扎实的理论基础和综合分析能力，能够将多个概念联系起来进行解释。虽然题目没有涉及更复杂的现象或更深入的分析，但在该题型内已经属于较高难度的题目。" + }, + { + "idx": 1048, + "question": "Analyze the cause of the iron-carbon dual phase diagram from a kinetic perspective", + "answer": "From a kinetic analysis, since Fe3C contains 6.69% carbon, while graphite contains 100% carbon, and the carbon content of commonly used steel materials is less than 5%. Thus, the compositional fluctuation required to form the graphite phase is much larger than that for Fe3C, meaning that forming graphite nuclei is much more difficult than forming Fe3C nuclei.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从动力学角度分析铁碳双相图的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从动力学角度分析铁碳双相图形成的原因，涉及Fe3C和石墨相形成的核化难易比较，需要综合运用动力学原理、相变理论和成分波动概念进行推理分析，属于复杂分析层次。 | 难度: 在简答题中属于机理深度解释难度，需要从动力学角度分析铁碳双相图的形成原因，涉及Fe3C和石墨相形成的成分波动差异，以及成核难易程度的比较。虽然题目要求综合运用知识进行推理分析，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 1049, + "question": "Analyze the equilibrium crystallization process of the Fe-0.4%C alloy and indicate the microstructure constituents at room temperature", + "answer": "When C%=0.4%, the microstructure constituents of the Fe-C alloy upon cooling to room temperature are P+α", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的微观结构组成，需要文字解释和论述，答案也是以文字形式给出。 | 知识层次: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的微观组织组成物，这需要理解Fe-C相图的基本原理，并能将相图知识应用于具体成分的合金分析。虽然涉及基础概念，但需要将多个知识点（相图解读、相变过程、组织组成物识别）关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的微观组织组成，但答案相对直接，主要涉及相图的基本应用和简单解释。解题步骤包括识别合金在相图中的位置、分析冷却过程中的相变以及最终组织的确定。虽然需要一定的概念关联和综合分析能力，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 1050, + "question": "Calculate the content of pearlite in the microstructure of an Fe-0.4%C alloy", + "answer": "The content of pearlite in the microstructure: P%=[(0.4-0.0218)/(0.77-0.0218)]×100%=50.55%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解珠光体含量，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，直接套用杠杆定律公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（杠杆定律）进行一步计算，无需任何公式组合或复杂推导过程。题目中所有参数均已明确给出，计算过程仅涉及基本代数运算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 1051, + "question": "Calculate the graphite content in Fe-3.6%C alloy", + "answer": "The graphite content is: wG = (3.6 - 0.68) / (100 - 0.68) × 100% ≈ 2.94%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过计算得出的具体数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，仅需直接套用给定的公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（石墨含量计算公式）并进行简单数值计算，无需多步骤推导或复杂公式组合。" + }, + { + "idx": 1052, + "question": "Analyze the crystallization process of Fe-3.6%C alloy to obtain a pearlite matrix gray iron structure", + "answer": "For the Fe-3.6%C alloy, to obtain a pearlite matrix gray cast iron structure, according to the Fe-graphite phase diagram, the crystallization process is as follows: L↔γA, L↔(γ+G)3, γ↔G, γ↔(α+Fe3C)JE.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析Fe-3.6%C合金的结晶过程以获得珠光体基体的灰铸铁结构，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析Fe-3.6%C合金的结晶过程以获得珠光体基体的灰铸铁结构，涉及Fe-石墨相图的理解和应用，需要综合运用相变知识、相图分析以及结晶过程的推理分析，思维过程较深，知识点关联度高。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析Fe-3.6%C合金的结晶过程，涉及Fe-石墨相图的理解和应用，需要综合运用相变机理知识，解释多个相变反应步骤（L↔γA, L↔(γ+G)3, γ↔G, γ↔(α+Fe3C)JE），并最终推导出珠光体基体的灰铸铁结构。这种题目不仅要求对相图有深入理解，还需要对相变过程进行机理层面的解释，属于该题型内最高难度的复杂现象全面分析。" + }, + { + "idx": 1053, + "question": "If the aforementioned alloy undergoes directional solidification in a 100cm long horizontal round mold, assuming no diffusion in the solid phase during solidification and complete mixing of the liquid composition, and the lines in the phase diagram can be simplified as straight lines, calculate the length of the ledeburite structure at the end of solidification. It is known that the length of the δ phase is 28.75cm, the length of the γ phase is 70.08cm, and the total length is 100cm.", + "answer": "The length of the ledeburite structure is: (100-28.75-70.08)cm=1.17cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，根据已知条件（δ相和γ相的长度）通过减法运算得出ledeburite结构的长度，答案以具体数值形式呈现，符合计算题的特征。 | 知识层次: 题目主要涉及基本的数值计算和简单的公式应用，不需要多步计算或复杂的概念关联。解题过程主要是根据已知数据直接进行减法运算，属于简单应用层次。 | 难度: 在计算题中属于最简单难度，仅需单一公式直接计算（简单的减法运算），无需复杂公式应用或多步骤推导。题目中所有必要数值均已给出，解题过程仅需一步减法操作即可完成。" + }, + { + "idx": 1055, + "question": "If the above alloy undergoes directional solidification in a horizontal round mold with a length of 100 cm, assuming no diffusion in the solid phase during solidification and complete mixing of the liquid composition, and the lines in the phase diagram can be simplified as straight lines, calculate the length of the δ phase at the end of solidification. Given C0=0.4, K0=0.09/0.53=0.1698.", + "answer": "Using the formula: Cs=K0C0(1-Z/L)^(K0-1). Substituting the known conditions into the formula gives: 0.09=0.1698×0.4×(1-Z1/100)^(0.1698-1). Calculation yields: 0.09/0.06792=(1-Z1/100)^(-0.8302). Further calculation: 1.325=(1-Z1/100)^(-0.8302). (1-Z1/100)^0.8302=1/1.325=0.7547. 1-Z1/100=0.7125. Z1=28.75 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及代入已知条件和逐步计算，最终得出具体数值结果。 | 知识层次: 题目需要进行多步计算和公式应用，涉及相图简化假设和成分分布计算，需要一定的综合分析能力，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用公式并进行多步计算。题目涉及相图简化、扩散假设和成分混合等概念的综合运用，解题步骤包括公式代入、指数运算和代数求解，但未达到复杂多变量计算的程度。" + }, + { + "idx": 1056, + "question": "If the aforementioned alloy undergoes directional solidification in a horizontal cylindrical mold with a length of 100 cm, assuming no diffusion in the solid phase during solidification and complete mixing of the liquid composition, and the lines in the phase diagram can be simplified as straight lines, calculate the length of the γ phase at the end of solidification. Given L2=(100-28.75)cm=71.25cm, C0'=0.53, K0'=2.11/4.3=0.4907.", + "answer": "Using the formula: Cs=K0C0(1-Z/L)^(K0-1). Substituting the known conditions into the formula gives: 2.11=0.4907×0.53×(1-Z2/71.25)^(0.4907-1). Calculation yields: 2.11/0.26007=(1-Z2/71.25)^(-0.5093)=8.1132. (1-Z2/71.25)^0.5093=1/8.1132=0.12326. 1-Z2/71.25=0.0164. Z2=70.08 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及多个步骤的数学运算和公式代入，最终得出具体的数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解定向凝固过程中的成分分布规律，并运用给定的参数进行数值计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用相图知识和数学计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和公式推导，涉及相图简化假设和成分分布计算，但未达到复杂多变量计算的程度。" + }, + { + "idx": 1058, + "question": "Interstitial phase", + "answer": "Interstitial phase: A compound formed between non-metal atoms (X) and transition metal atoms, when the ratio of atomic radii of the metal element (M) to the non-metal element (X) $R_{\\\\mathrm{X}}/R_{\\\\mathrm{M}}<0.59$, the non-metal atoms are located in the interstices of the metal atoms and exhibit a relatively simple crystal structure, it is called an interstitial phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Interstitial phase”进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对interstitial phase这一基本概念的定义和特征的理解和记忆，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"interstitial phase\"的定义及其形成条件，涉及非金属原子与过渡金属原子的半径比、晶体结构等基本概念，但不需要进行复杂的概念体系阐述或深入分析。属于基础概念记忆层次中需要一定解释和描述的难度水平。" + }, + { + "idx": 1059, + "question": "Critical nucleus", + "answer": "Critical nucleus: In a metal liquid, an embryo with a radius larger than the critical radius rk can stably grow and is called a critical nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Critical nucleus\"这一概念进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对\"Critical nucleus\"这一基础概念的定义和基本特性的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并复述\"critical nucleus\"的定义，无需深入解释或复杂论述。题目要求的知识深度和解题步骤都极为基础，符合等级1的特征。" + }, + { + "idx": 1060, + "question": "Phase boundary contact rule", + "answer": "Phase boundary contact rule: In a phase diagram, the difference in the number of phases between adjacent phase regions is 1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Phase boundary contact rule\"进行文字解释和论述，答案以简短的文字形式给出定义，符合简答题的特征。 | 知识层次: 题目考查的是相图中相边界接触规则的基本定义和原理，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求回答相边界接触规则的基本定义，属于最基础的概念记忆性知识。题目不涉及概念的解释、描述或复杂体系的阐述，仅需直接回忆并陈述定义即可，因此在该题型内属于最低难度等级。" + }, + { + "idx": 1061, + "question": "Write all the crystal planes included in the {110} crystal plane family in the cubic crystal system", + "answer": "(110)(101)(011)(110)(101)(011), totaling 6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中{110}晶面族包含的所有晶面，答案需要以文字形式列出具体的晶面指数，属于简答题类型。 | 知识层次: 题目考查立方晶系中{110}晶面族包含的所有晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求列举立方晶系中{110}晶面族包含的所有晶面，属于概念解释和描述的难度等级。虽然需要记忆晶面族的组成，但不需要进行复杂的推导或阐述多个相关概念体系。解题步骤相对直接，只需正确应用立方晶系的对称性原理即可完成。" + }, + { + "idx": 1063, + "question": "Write all the crystal planes included in the {112} crystal plane family of the cubic crystal system", + "answer": "(112)(112)(1 12)(11 2) + (121)(121)(1 21)(12 1) + (211)(211)(2 11)(21 1), totaling 12.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中{112}晶面族包含的所有晶面，需要文字解释和论述，答案形式为列举具体的晶面符号，属于简答题类型。 | 知识层次: 题目考查对立方晶系中晶面族{112}包含的所有晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要理解晶体平面族的概念并列举所有可能的平面，但不需要复杂的推导或解释。" + }, + { + "idx": 1064, + "question": "If the slip plane of a body-centered cubic crystal is {110} and the slip direction is [111], write out the specific slip systems.", + "answer": "(110)[1 11], (10 1)[1 11], (011)[1 11]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出具体的滑移系统，需要文字解释和论述，而不是简单的选择、判断或计算。答案也是以文字形式呈现的具体滑移系统。 | 知识层次: 题目要求写出具体的滑移系统，需要理解体心立方晶体的滑移面和滑移方向的概念，并能够应用这些知识来确定具体的滑移系统。这涉及到多步思考和概念关联，但不需要复杂的综合分析或创新应用。 | 难度: 在简答题中属于中等难度，需要理解晶体滑移系统的基本概念，并能够正确识别和写出具体的滑移面和滑移方向组合。虽然题目给出了滑移面和滑移方向，但需要学生掌握体心立方晶体的滑移系统知识，并能正确列举出所有可能的组合。这需要一定的综合分析能力，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1065, + "question": "Write all the crystal planes included in the {123} crystal plane family in the cubic crystal system", + "answer": "(123)(123)(123)(123) + (132)(132)(132)(132) + (213)(213)(213)(213) + (231)(231)(231)(231) + (312)(312)(312)(312) + (321)(321)(321)(321), totaling 24.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列举立方晶系中{123}晶面族包含的所有晶面，答案是通过文字描述和列举具体晶面来完成的，不需要计算或选择，属于需要具体回答的简答题类型。 | 知识层次: 题目要求学生在立方晶系中写出{123}晶面族包含的所有晶面，这需要理解晶面指数的对称性操作和立方晶系的对称性特点。虽然不涉及复杂的计算或推理，但需要将基本概念（晶面指数、晶面族）与立方晶系的对称操作（如旋转、镜像）结合起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求写出立方晶系中{123}晶面族的所有晶面，这需要学生不仅理解晶面指数的概念，还需要掌握晶面族的定义和计算方法。其次，解题过程中需要进行多步计算和排列组合，包括考虑所有可能的指数排列和符号变化，这增加了题目的复杂性。此外，题目还要求学生能够综合运用晶体学知识，正确识别和列出所有等效晶面，这需要较高的综合分析能力。因此，在简答题题型中，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 1067, + "question": "Given that copper has an FCC structure with an atomic radius of $0.1278\\\\mathrm{nm}$, calculate its density. (The atomic weight of copper is 63.5, and the Avogadro constant is $0.602\\\\times10^{24}$)", + "answer": "Given that the Cu lattice has an FCC structure, meaning the unit cell contains 4 atoms, to find its density ρ, we only need to calculate the ratio of the mass of the atoms in the unit cell to the volume of the unit cell: $$\\\\rho={\\\\frac{n M}{N_{A}(2{\\\\sqrt{2}}r)^{3}}}={\\\\frac{4\\\\times63.5\\\\times10^{-3}}{0.602\\\\times10^{24}\\\\times(2{\\\\sqrt{2}}\\\\times0.1278\\\\times10^{-9})^{3}}}\\\\mathrm{kg/m^{3}}\\\\approx8933\\\\mathrm{kg/m^{3}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜的密度，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据FCC结构的原子半径计算密度，属于直接套用公式和数值计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用FCC结构的已知参数（原子半径）和基本物理常数（阿伏伽德罗常数）来计算密度，解题步骤明确且直接，仅需套用单一公式并完成单位换算。虽然涉及立方计算，但整体计算过程属于该题型中的常规操作，没有复杂的推导或多步骤组合计算要求。" + }, + { + "idx": 1068, + "question": "Describe the phase transformation process, products, and reaction conditions along the HJB horizontal line in the phase diagram", + "answer": "The HJB horizontal line undergoes a peritectic reaction: L_B + δ_H ⇌ γ_J; product: austenite (A)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述相变过程、产物和反应条件，需要文字解释和论述，答案也是以文字形式给出详细解释，符合简答题的特征。 | 知识层次: 题目要求描述相变过程、产物及反应条件，涉及相图中特定水平线的包晶反应，需要理解相图的基本原理并能够关联不同相（L_B、δ_H、γ_J）之间的关系，属于中等应用层次。虽然不涉及复杂计算，但需要对相图有较深入的理解和综合分析能力。 | 难度: 在简答题题型中，该题目要求对相图中的HJB水平线进行详细的相变过程、产物和反应条件的描述，涉及多步计算、概念关联和综合分析。需要考生不仅理解基本的相变概念，还要能够将这些概念与具体的相图分析结合起来，进行多角度的论述。因此，该题目在简答题题型中属于较高难度，需要较深的知识掌握和分析能力。" + }, + { + "idx": 1069, + "question": "If the slip plane of a body-centered cubic crystal is {123} and the slip direction is [111], write out the specific slip systems.", + "answer": "(123)[1 11], (213)[1 11], (231)[1 11], (31 2)[1 11], (132)[1 11], (32 1)[1 11]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出具体的滑移系统，需要列举出所有可能的滑移面和滑移方向的组合，属于需要具体列举和解释的简答题类型。 | 知识层次: 题目要求写出具体的滑移系统，需要理解体心立方晶体的滑移面和滑移方向的概念，并能够进行多步分析和组合。虽然不涉及复杂的计算或推理，但需要对晶体学知识有一定的理解和应用能力，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求写出具体的滑移系统，需要理解体心立方晶体的滑移面和滑移方向的概念，并能够综合分析不同滑移面的组合。解题步骤包括确定滑移面和滑移方向，然后列举所有可能的滑移系统组合，这需要一定的综合分析能力和对晶体学知识的深入理解。因此，在简答题题型中，该题目属于较高难度等级。" + }, + { + "idx": 1070, + "question": "Assuming carbon atoms are all located in the octahedral interstices of γ-Fe, calculate the maximum proportion of octahedral interstices occupied by carbon atoms in γ-Fe. (The atomic weight of iron is 55.85, and the Avogadro constant is 0.602×10^24)", + "answer": "In the γ-Fe phase, the maximum carbon concentration C_max = 2.11%. Given that γ-Fe has an FCC structure with n = 4, there are 400 Fe atoms per 100 unit cells. The mass fraction of Fe is: w_Fe = 1 - 2.11% = 97.89%. The total mass is: M = (400 × 55.85) / 0.9789 = 22821.5. The number of carbon atoms is: n_c = (M × C_max) / M_c = (22821.5 × 0.0211) / 12 = 40. Thus, there are 40 carbon atoms per 100 unit cells.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了质量分数、总质量、碳原子数量等具体计算步骤，最终得出数值结果。 | 知识层次: 题目需要进行多步计算，涉及FCC结构的原子数量计算、质量分数的转换以及碳原子数量的推导，需要综合运用材料科学中的晶体结构和相图知识。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解γ-Fe的FCC结构、碳原子在八面体间隙中的占据情况，并进行多步计算，包括质量分数转换、原子数量计算等。虽然涉及多个概念和步骤，但整体计算过程较为直接，没有过于复杂的变量或推导，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 1071, + "question": "Describe the phase transformation process, products, and reaction conditions along the ECF line in the phase diagram", + "answer": "The ECF line undergoes a eutectic reaction: L_C ⇌ γ_E + Fe3C; the product is: ledeburite (Ld)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述相变过程、产物和反应条件，需要文字解释和论述，答案也以文字形式呈现了具体的相变反应和产物。 | 知识层次: 题目要求描述相变过程、产物及反应条件，涉及相图中ECF线的共晶反应，需要理解相图的基本原理并能够关联不同概念（如共晶反应、莱氏体等），属于中等应用层次。虽然不涉及复杂计算，但需要综合分析相图信息并解释反应过程，思维深度高于简单记忆或直接套用。 | 难度: 在简答题中属于中等难度，需要理解并描述相变过程、产物及反应条件，涉及多个概念的关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1072, + "question": "Describe the phase transformation process, products, and reaction conditions along the PSK line in the phase diagram", + "answer": "The PSK line undergoes a eutectoid reaction: γ_S ⇌ α_P + Fe3C; product: pearlite (P)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述相变过程、产物和反应条件，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求描述相变过程、产物及反应条件，涉及多个概念的综合应用和分析，需要理解相图的基本原理并能够关联不同知识点，但不需要进行复杂的推理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解相图中的PSK线、共析反应的概念，并能准确描述反应过程、产物及条件。虽然涉及多个概念的综合运用，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1073, + "question": "Density", + "answer": "Density: The ratio of the volume occupied by atoms in a unit cell to the volume of the unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Density\"进行文字解释和论述，答案提供了详细的定义，符合简答题的特征。 | 知识层次: 题目考查密度的基本定义和概念记忆，属于基础概念层次，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答。题目要求的是对\"密度\"这一基础概念的定义进行简单的文字解释，不需要深入的概念描述或复杂的概念体系阐述。在同类题型中，这种仅需记忆和复述基本定义的题目属于最低难度等级。" + }, + { + "idx": 1074, + "question": "Non-steady state diffusion", + "answer": "Non-steady state diffusion: diffusion where both the concentration gradient and the diffusion flux vary with time and distance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Non-steady state diffusion\"进行文字解释和论述，答案提供了概念的定义和特征描述，属于需要文字解释的简答题类型。 | 知识层次: 题目考查非稳态扩散的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求对\"Non-steady state diffusion\"进行基本定义简答，属于最基础的概念记忆层面。题目不需要解释或描述相关概念，也不涉及复杂概念体系的阐述，仅需直接回忆并写出定义即可，因此在该题型内属于最低难度等级。" + }, + { + "idx": 1076, + "question": "Critical nucleation work", + "answer": "Critical nucleation work: the increment of free energy when forming a critical nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Critical nucleation work\"进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对\"Critical nucleation work\"这一基础概念的定义记忆和理解，属于材料科学中相变理论的基础知识点，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"Critical nucleation work\"进行基本定义简答，属于最基础的概念记忆性知识。题目不需要额外的解释、描述或复杂概念体系的阐述，仅需直接回忆并写出定义即可，因此在简答题题型内属于最低难度等级。" + }, + { + "idx": 1077, + "question": "Calculate the relative content of each phase when an alloy containing 0.40% C is cooled to room temperature under equilibrium conditions.", + "answer": "Relative content of each phase: w_α=(6.69-0.40)/(6.69-0.0008)×100%=94%; w_Fe3C=1-w_α=1-94%=6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金中各相的相对含量，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目要求应用杠杆定律进行简单的两相含量计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目只需要应用杠杆定律公式进行单一计算步骤，没有涉及多个公式的组合或复杂推导过程。虽然需要理解相图的基本概念，但计算本身是直接套用公式的简单应用。" + }, + { + "idx": 1078, + "question": "Calculate the relative content of each microstructural constituent in an alloy containing 0.40% C when it is cooled to room temperature under equilibrium conditions.", + "answer": "The relative content of each microstructural constituent: w_P=(0.40-0.0218)/(0.77-0.0218)×100%=50.5%; w_a=1-w_P=1-50.5%=49.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金中各微观结构组成的相对含量，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及铁碳相图中杠杆定律的直接套用，不需要多步计算或复杂分析。 | 难度: 在计算题中属于简单公式应用计算难度，仅需应用杠杆定律公式进行一步计算，不需要多个公式组合或复杂推导。虽然需要理解相图概念，但计算过程直接明了，属于该题型中的基础难度级别。" + }, + { + "idx": 1079, + "question": "Extended dislocation", + "answer": "Extended dislocation: In FCC crystals, a perfect dislocation is difficult to exist due to its high energy and will automatically decompose into two partial dislocations and a stacking fault in between, forming the so-called extended dislocation configuration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Extended dislocation进行解释和论述，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对扩展位错这一基本概念的定义和形成原因的理解，属于材料科学中晶体缺陷的基础知识，主要涉及记忆和简单解释，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释扩展位错的定义及其在FCC晶体中的形成机制，涉及基本概念的记忆和简单原理的阐述，但不需要复杂的体系化分析或深入推导。相比等级1的纯定义简答，该题需要更多解释性内容；相比等级3的复杂体系阐述，该题的认知负荷和知识整合要求较低。" + }, + { + "idx": 1080, + "question": "Write all the crystal planes included in the {110} plane family of the cubic crystal system.", + "answer": "(110), (101), (011), (110), (101), (011).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举立方晶系中{110}晶面族包含的所有晶面，答案需要以文字形式列出具体的晶面指数，属于简答题类型。 | 知识层次: 题目考查立方晶系中{110}晶面族包含的所有晶面，属于基础概念的记忆和理解，不需要复杂的计算或分析。 | 难度: 在简答题题型中，该题目属于基础概念记忆类，仅需要列举立方晶系{110}晶面族中包含的所有晶面。不需要进行复杂的解释或论述，只需准确回忆并写出相关晶面指数即可。解题步骤简单，仅涉及基本定义和分类的记忆，符合等级1的基本定义简答要求。" + }, + { + "idx": 1081, + "question": "Write all the crystal planes included in the {111} crystal plane family in the cubic crystal system.", + "answer": "(111), (1̄11), (11̄1), (111̄).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出立方晶系中{111}晶面族包含的所有晶面，答案需要列举具体的晶面指数，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目考查对立方晶系中{111}晶面族包含的所有晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求写出立方晶系中{111}晶面族包含的所有晶面，这只需要记忆立方晶系中晶面族的基本定义和符号规则即可完成，不需要进行概念解释或复杂体系的阐述。解题步骤简单直接，仅需列举出所有可能的晶面符号变体。" + }, + { + "idx": 1083, + "question": "Write all the crystal planes included in the {123} crystal plane family of the cubic crystal system.", + "answer": "(123), (123), (123), (123), (132), (132), (132), (132), (213), (213), (213), (213), (231), (231), (231), (231), (312), (312), (312), (312), (321), (321), (321), (321).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列举立方晶系中{123}晶面族的所有晶面，答案是一系列具体的晶面指数，需要理解和应用晶体学知识来解答，属于需要具体回答的简答题类型。 | 知识层次: 题目要求列出立方晶系中{123}晶面族的所有晶面，这需要对晶面指数的排列组合有深入理解，并能够正确应用对称性原理来生成所有等效晶面。虽然不涉及复杂的计算或综合分析，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要理解立方晶系中晶面族的定义，掌握晶面指数的排列组合方法，并能正确列举所有可能的晶面变体。解题过程涉及多步计算和综合分析，要求学生对晶体学概念有较深的理解和应用能力。" + }, + { + "idx": 1084, + "question": "Are the shapes of the room-temperature tensile curves of low-carbon steel and aluminum alloy the same?", + "answer": "The shapes of the room-temperature tensile curves of low-carbon steel and aluminum alloy are not the same.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Are the shapes...the same?\"），答案直接给出了对错判断（\"are not the same\"），符合判断题的特征。 | 知识层次: 题目考查对低合金钢和铝合金室温拉伸曲线形状差异的基础概念记忆，属于材料力学性能的基本知识范畴，不需要复杂的分析或推理。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。只需记忆低合金钢和铝合金的室温拉伸曲线形状不同这一基础事实即可作答，不涉及概念理解或复杂分析，符合等级1的简单记忆性特征。" + }, + { + "idx": 1086, + "question": "For annealed low-carbon steel with a grain size of NA=16 grains/mm², its yield strength σs=100MPa; when NA=4096 grains/mm², σs=250MPa. Calculate the yield strength when NA=250 grains/mm².", + "answer": "According to the Hall-Petch formula: $\\sigma_{\\mathrm{s}}=\\sigma_{0}+K d^{-1/2}$. Since $N_{A}$ is inversely proportional to the square of the grain diameter $\\pmb{d}$, we have: Furthermore, it can be solved that $$\\begin{array}{c}{{\\displaystyle{\\sigma_{\\mathrm{s}}=100}{\\mathrm{MPa}}=\\sigma_{0}+K{d_{1}}^{-1/2}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=250}{\\mathrm{MPa}}=\\sigma_{0}+K{d_{2}}^{-1/2}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=\\sigma_{0}+K{d_{3}}^{-1/2}}}}\\ {{\\displaystyle{d_{2}}/d_{1}=1/16\\qquadd_{3}/d_{1}=4/5~\\sqrt{10}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=149}{\\mathrm{MPa}}}}\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和公式（Hall-Petch公式）进行数值计算，最终得出一个具体的数值结果（149MPa）。解答过程涉及公式应用和数学运算，符合计算题的特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义及其相互关系，并进行适当的数学推导和计算。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式要复杂一些。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式并进行多步计算和变量转换。题目提供了两个已知条件，要求考生建立方程组并求解第三个未知情况，涉及反比关系和平方根运算。虽然计算过程较为直接，但需要理解晶粒尺寸与屈服强度的关系，并正确进行单位转换和代数运算，属于中等偏上的难度。" + }, + { + "idx": 1087, + "question": "What are the characteristics of the room temperature tensile curve of low-carbon steel?", + "answer": "Low-carbon steel exhibits distinct upper and lower yield points due to the presence of Cottrell atmospheres.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释低碳钢室温拉伸曲线的特征，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对低碳钢室温拉伸曲线特征的基本概念记忆和理解，特别是上下屈服点的存在及其原因（Cottrell气团），属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。虽然需要解释低碳钢室温拉伸曲线的特征，但主要涉及的是基本原理的记忆和简单描述，不需要复杂的体系阐述或多步骤分析。题目要求回答的是低碳钢拉伸曲线的典型特征（上下屈服点）及其原因（Cottrell气团的存在），属于对基础概念的理解和表述，没有涉及更深层次的理论推导或综合分析。" + }, + { + "idx": 1088, + "question": "Assuming carbon atoms are all located in the octahedral interstices of γ-Fe, at 1000°C, 1.7 weight percent of carbon atoms are dissolved in γ-Fe. Calculate how many carbon atoms are present in 100 unit cells and determine the proportion of octahedral interstices occupied by carbon atoms (the atomic weight of iron is 55.85, and the atomic weight of carbon is 12.01).", + "answer": "γ-Fe has a face-centered cubic structure, with 4 Fe atoms and 4 octahedral interstices per unit cell. Let the number of carbon atoms in one unit cell be $A$, then: Solving gives $A=0.32$ $$\\frac{100A\\times12.01}{100\\times4\\times55.85+100A\\times12.01}=1.7\\%$$ Thus, the number of carbon atoms in 100 unit cells is: $0.32\\times100=32$ The proportion of octahedral interstices occupied by C atoms: $$A/4=0.32/4=0.08=8\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及碳原子数量计算和八面体间隙占据比例的计算，答案也给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括质量百分比与原子数量的转换，以及单位晶胞中碳原子占据八面体间隙的比例计算。这需要理解面心立方结构的基本性质、间隙位置的概念，并能综合应用这些知识进行数值计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在计算题-中等应用题型中，该题目属于综合性计算问题。需要理解面心立方结构中的间隙位置概念，掌握重量百分比与原子数量的转换关系，并进行多步计算（包括单位转换、比例计算和间隙占有率计算）。虽然计算过程明确，但涉及多个概念的综合应用和单位协调，属于该题型内中等偏上的难度水平。" + }, + { + "idx": 1090, + "question": "Critical resolved shear stress", + "answer": "Critical resolved shear stress: When $\\sigma_{0}=\\sigma_{\\mathfrak{s}}$, the crystal begins to slip, and the resolved shear stress in the slip direction at this point is called the critical resolved shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Critical resolved shear stress\"进行文字解释和论述，答案提供了概念的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对临界分切应力的基本定义和概念的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目仅要求对\"Critical resolved shear stress\"这一基础概念进行定义和简单解释，属于最基本的概念记忆性知识。题目没有要求深入分析或与其他概念建立联系，解题步骤也非常简单，只需直接回忆并陈述定义即可。在同为概念定义的简答题中，这属于最基础级别的难度。" + }, + { + "idx": 1091, + "question": "What are the characteristics of the room temperature tensile curve of aluminum alloy?", + "answer": "Aluminum alloy does not exhibit a distinct yield point phenomenon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和描述铝合金在室温下的拉伸曲线特征，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对铝合金室温拉伸曲线特性的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述铝合金室温拉伸曲线的特征，属于概念解释和描述的难度等级。虽然需要记忆铝合金不表现出明显屈服点现象这一特性，但不需要深入阐述复杂的概念体系或进行多步骤的推理分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 1095, + "question": "Cross-slip can enable multiple slip systems in crystals", + "answer": "Cross-slip is the process where a dislocation line transfers from one slip plane to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Cross-slip\"这一概念进行文字解释和论述，答案是一个定义性的陈述句，符合简答题的特征。 | 知识层次: 题目考查对cross-slip这一基本概念的定义和简单解释，属于基础概念的记忆和理解层面，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"cross-slip\"这一基础概念进行定义性回答，属于最基本的概念记忆层次。题目不涉及概念间的关联解释或复杂体系阐述，仅需直接回忆并写出定义即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1096, + "question": "Interstitial solid solutions and interstitial compounds both belong to interstitial phases.", + "answer": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vector of the dislocation line, respectively. For a curved dislocation line, its Burgers vector remains constant, but the properties vary along different sections depending on the geometric relationship between the direction vector of the dislocation line and the Burgers vector.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个关于间隙相的分类观点（间隙固溶体和间隙化合物都属于间隙相），而答案部分实际上给出了另一个完全不同的关于位错Burgers矢量的陈述。这表明题目本身可能是一个判断题，要求判断初始陈述的正确性，而答案给出了一个看似无关的正确答案，这符合判断题中\"判断陈述对错\"的特征。不过需要指出的是，题目和答案之间缺乏直接关联性，这可能是一个出题错误。 | 知识层次: 题目考查对间隙固溶体和间隙化合物的基本分类和定义的理解，属于基础概念的记忆性知识。 | 难度: 在判断题中属于较高难度，题目涉及多个复杂概念（间隙固溶体、间隙化合物、间隙相）的区分和关系判断，需要深入理解这些概念的定义和相互关系，而不仅仅是简单的正误判断。此外，题目陈述的准确性需要基于对材料科学中相变和晶体缺陷理论的扎实掌握。" + }, + { + "idx": 1097, + "question": "For metals or alloys without phase transformation in the solid state, their grain size cannot be changed unless remelted.", + "answer": "For metals or alloys without phase transformation in the solid state, their grain size can also be changed through plastic deformation and recrystallization treatment without remelting.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性。答案指出了原陈述的错误，并提供了正确的信息，这是典型的判断题特征。 | 知识层次: 题目考查对金属或合金晶粒尺寸变化方式的基本概念记忆和理解，涉及相变、塑性变形和再结晶处理等基础知识点，无需复杂分析或综合应用。 | 难度: 在判断题中属于中等难度，需要理解金属或合金的晶粒尺寸变化机制，包括塑性变形和再结晶处理的作用，而不仅仅是记忆基本定义。题目涉及对概念理解的深度判断，而非简单的正误识别。" + }, + { + "idx": 1098, + "question": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vectors of the dislocation lines, respectively, so a curved dislocation line has different properties.", + "answer": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vectors of the dislocation lines, respectively. For a curved dislocation line, its Burgers vector remains constant, but the properties vary along the line as the geometric relationship between the direction vector of the dislocation line and the Burgers vector changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对位错的性质进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求理解刃位错和螺位错的Burgers矢量与位错线方向矢量的几何关系，并能够分析曲线位错线上性质的变化。这需要将多个概念关联起来进行综合分析，而不仅仅是记忆基本概念或进行简单应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求对刃型位错和螺型位错的柏氏矢量与位错线方向向量的关系进行解释，并进一步说明弯曲位错线的性质变化。这需要掌握位错的基本概念，并能进行简单的综合分析。虽然涉及多个概念，但不需要进行复杂的多角度分析或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 1099, + "question": "Calculate the planar density of the (100) plane in a face-centered cubic crystal, given the atomic radius r=(√2/4)a", + "answer": "For the (100) plane of a face-centered cubic crystal, there are 2 atoms. The planar density is calculated as: 2×π(√2/4 a)^2 / a^2 = 2π×1/8 = π/4 = 0.785", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和公式推导，最终给出一个数值结果。 | 知识层次: 题目需要理解面心立方晶体结构特点，正确识别(100)面上的原子数，并应用平面密度计算公式进行多步推导和数值计算，涉及概念关联和综合分析能力。 | 难度: 在计算题中属于多步骤计算过程难度。题目要求计算面密度，涉及原子半径与晶格常数的关系、平面原子数的确定以及面积计算，但步骤明确且无复杂变量。相比等级3的综合性问题，该题计算过程较为直接，属于该题型内中等偏下的难度。" + }, + { + "idx": 1100, + "question": "Calculate the planar density of the (110) plane in a face-centered cubic crystal, given the atomic radius r=(√2/4)a", + "answer": "For the (110) plane of a face-centered cubic crystal, there are 2 atoms. The planar density is calculated as: 2×π(√2/4 a)^2 / (√2 a×a) = 2π×1/8 / √2 = √2/8 π = 0.56", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出一个数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括理解面心立方晶体的(110)平面原子排列、计算平面密度公式的应用，以及数学运算的综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解面心立方晶体结构、(110)平面的原子排列方式，正确应用平面密度计算公式，并进行多步数值计算和单位转换。虽然计算过程明确，但涉及多个晶体学概念的综合应用和较复杂的数学运算，在同类计算题中属于中等偏上难度。" + }, + { + "idx": 1101, + "question": "A metal test bar with a length of 20cm and a cross-sectional area of 4cm² is fixed at the upper end and subjected to a tensile force of 980N at the lower end. Find the angle θ at which the shear stress is maximum.", + "answer": "The angle θ at which the shear stress is maximum is 45°.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定条件下剪切应力达到最大值时的角度。答案是通过计算得出的具体数值（45°），而不是从选项中选择或简单的对错判断。 | 知识层次: 题目涉及基本的应力计算和公式应用，需要理解剪切应力的概念并应用简单的三角函数关系来确定最大剪切应力对应的角度。虽然需要一定的计算步骤，但整体上属于直接套用基本公式和简单计算的范畴。 | 难度: 在计算题中属于简单公式应用计算，需要理解剪切应力与角度的关系，并应用单一公式（τ = σ/2 * sin(2θ)）进行计算，但需要知道在θ=45°时sin(2θ)取得最大值1这一关键点。虽然涉及基本概念的理解，但计算步骤直接且单一。" + }, + { + "idx": 1102, + "question": "Calculate the planar density of the (111) plane in a face-centered cubic crystal, given the atomic radius r=(√2/4)a", + "answer": "For the (111) plane of a face-centered cubic crystal, there are 2 atoms. The planar density is calculated as: 2π(√2/4 a)^2 / (1/2 √2 a×√2 a×sin60°) = 2π×1/8 / (√3/2) = π/(2√3) = 0.90", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出一个具体的数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括平面密度的计算、原子半径与晶格常数的关系、几何关系的应用等，涉及中等程度的综合分析和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解面心立方晶体结构、(111)晶面的原子排布、平面密度的计算公式，并进行多步骤的数学推导和计算。虽然不涉及多变量，但需要综合运用几何知识和代数运算能力，在同类题型中属于中等偏上难度。" + }, + { + "idx": 1103, + "question": "A metal test bar with a length of 20cm and a cross-sectional area of 4cm² is fixed at the upper end, and a tensile force of 980N is applied at the lower end. Calculate the normal stress and shear stress on a plane that forms a 0° angle with the central axis of the metal test bar.", + "answer": "When θ=0°: normal stress σθ=0; shear stress τθ=0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用（计算正应力和剪应力），答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及基本的应力计算，仅需直接应用公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅要求计算法向应力和剪应力，且直接给出了角度为0°的特殊情况，此时应力均为0，无需复杂计算或公式组合。属于基本公式应用、简单计算、直接套用的范畴。" + }, + { + "idx": 1106, + "question": "A metal test bar with a length of 20cm and a cross-sectional area of 4cm² is fixed at the upper end and subjected to a tensile force of 980N at the lower end. Determine the general expressions for the normal stress and shear stress on a plane that forms an angle θ° with the central axis of the metal test bar.", + "answer": "Normal stress σθ=σsin²θ; shear stress τθ=(σ/2)sin2θ, where σ=P/A=980N/4cm²=2450000Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定金属测试棒在特定角度下的正应力和剪应力，答案给出了具体的计算公式和数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及应力公式的直接套用和角度变换，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用基本公式（正应力和剪应力公式）并进行简单计算，但不需要多个公式组合或复杂推导。题目直接给出了受力情况和几何参数，解题步骤较为直接。" + }, + { + "idx": 1107, + "question": "Indicate which plane among (100), (110), and (111) in a face-centered cubic crystal is the close-packed plane", + "answer": "The (111) plane has the highest packing density (0.90), so the close-packed plane in a face-centered cubic crystal is the (111) plane", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的平面选项（(100)、(110)、(111)）中选择一个正确答案，即哪个是面心立方晶体中的密排面。答案明确指出了(111)平面是密排面，符合选择题的特征。 | 知识层次: 题目考查对晶体结构中密排面的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题中属于中等偏下难度，需要理解面心立方晶体中不同晶面的堆积密度概念，并能简单比较(100)、(110)、(111)三个晶面的堆积密度差异。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，而非单纯的直接记忆。" + }, + { + "idx": 1108, + "question": "Interstitial compound", + "answer": "Interstitial compound: When small solute atoms such as C, H, O, N, etc. are distributed in the interstices of the solvent atomic structure, altering the crystal structure of the solvent atoms, and the composition can generally be represented by a chemical formula, such a phase is called an interstitial compound.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Interstitial compound\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对间隙化合物（interstitial compound）这一基本概念的定义和特征的理解和记忆，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要学生对\"Interstitial compound\"进行定义和解释，但内容相对基础，主要涉及基本概念的记忆和简单描述，不需要复杂的分析或体系阐述。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 1109, + "question": "Number of atoms per unit cell", + "answer": "Number of atoms per unit cell: In the spatial structure of a crystal, a unit cell is adjacent to 26 other unit cells. Therefore, the atoms at the 8 corners, 12 edges, and 6 faces of the unit cell are shared with other unit cells, and only the atoms inside the unit cell entirely belong to this unit cell. The sum of the fractional contributions of the shared atoms and the actual number of atoms belonging to this unit cell is called the number of atoms per unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Number of atoms per unit cell”进行文字解释和论述，答案提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目主要考查对晶体结构中单位晶胞原子数的基本概念的理解和记忆，包括原子在晶胞中的位置及其共享情况，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释单位晶胞中的原子数量，涉及共享原子的分数贡献和实际原子数量的概念。虽然需要理解并描述晶体结构中的共享机制，但不需要复杂的推导或深入的概念体系阐述，属于基础概念记忆层次中的中等难度。" + }, + { + "idx": 1110, + "question": "Degree of supercooling", + "answer": "Degree of supercooling: Under rapid cooling conditions, when a metallic material cools to its melting point temperature, it does not solidify immediately but begins to solidify at a lower temperature. The difference between the actual solidification temperature and the melting point temperature is referred to as the degree of supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Degree of supercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查的是对\"过冷度\"这一基本概念的定义和简单解释，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求解释\"degree of supercooling\"的定义，不需要进行概念间的比较或复杂体系的阐述。回答仅需记忆并复述基础概念即可，属于该题型内最基础的难度等级。" + }, + { + "idx": 1112, + "question": "The Burgers vector of edge dislocations and screw dislocations changes with the direction vector of the dislocation line.", + "answer": "Wrong! The Burgers vector of an edge dislocation is perpendicular to the direction vector of the dislocation line; the Burgers vector of a screw dislocation is parallel to the direction vector of the dislocation line.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个观点（The Burgers vector of edge dislocations and screw dislocations changes with the direction vector of the dislocation line），并要求判断其正确性。答案明确指出了该陈述是错误的，并给出了正确解释。这符合判断题的特征，即判断陈述的对错并给出解释。 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是刃位错和螺位错的Burgers矢量与位错线方向矢量之间的关系。这属于材料科学中关于位错的基础知识，不需要复杂的分析或应用。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对刃型位错和螺型位错的柏氏矢量与位错线方向向量关系的理解，需要掌握两种位错的基本定义和特征，但不需要进行复杂的推理或综合分析。这比单纯记忆定义的基本概念正误判断（等级1）要求略高，但低于需要判断复杂概念陈述的等级3。" + }, + { + "idx": 1113, + "question": "Both austenite and pearlite are solid solutions of carbon in $\\alpha-\\mathrm{\\bfFe}$ with a body-centered cubic structure.", + "answer": "Wrong! Austenite is a solid solution of carbon in $\\gamma.$ -Fe with a face-centered cubic structure, while pearlite is a two-phase structure composed of ferrite and cementite.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Both austenite and pearlite are solid solutions of carbon in α-Fe with a body-centered cubic structure），并要求判断其正确性。答案明确指出该陈述是错误的，并提供了正确的解释。这符合判断题的特征，即判断陈述的对错并给出理由。 | 知识层次: 题目考查对奥氏体和珠光体这两种材料的基本概念和结构的记忆和理解，属于基础概念记忆的范畴。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对奥氏体和珠光体这两种材料结构的准确理解，需要考生不仅知道它们的基本定义，还要能区分它们的晶体结构和组成相。虽然不涉及复杂概念的组合判断，但比单纯记忆性知识的判断要求更高。" + }, + { + "idx": 1114, + "question": "Strain aging", + "answer": "Strain aging: After the first stretching, if a second stretching is performed immediately, the yield stage does not appear on the stress-strain curve. However, if the low-carbon steel specimen after the first stretching is left at room temperature for a period of time before the second stretching, the yield stage reappears on the stress-strain curve. Nevertheless, the yield strength upon re-yielding is higher than that during the initial yielding. This experimental phenomenon is called strain aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Strain aging\"这一现象进行文字解释和论述，答案提供了详细的描述和说明，符合简答题的特征。 | 知识层次: 题目考查对\"应变时效\"这一基本概念的记忆和理解，需要解释其定义和现象特征，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释应变时效现象，包括其定义、实验现象和基本原理，但不需要涉及复杂的理论推导或多概念交叉分析。虽然需要记忆和理解相关知识点，但整体仍属于基础概念记忆层次，解题步骤相对直接。" + }, + { + "idx": 1115, + "question": "The diffusion of solute atoms always proceeds from regions of high concentration to regions of low concentration.", + "answer": "Wrong! The accurate statement is that the diffusion of solute atoms always proceeds from regions of high chemical potential to regions of low chemical potential. Only in this way can the driving force of reactive diffusion be satisfactorily explained.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目给出一个陈述（扩散总是从高浓度到低浓度），并要求判断其正确性。答案明确指出该陈述是错误的，并给出了正确的表述。这符合判断题的特征，即判断给定陈述的真伪并解释原因。 | 知识层次: 题目不仅需要理解扩散的基本概念，还需要理解化学势在扩散过程中的作用，这涉及到概念的关联和综合分析。虽然题目形式是判断题，但需要考生能够将扩散现象与化学势的概念联系起来，并进行一定的推理分析。 | 难度: 在判断题中属于较高难度，不仅需要判断陈述的对错，还需要理解扩散过程的本质（化学势而非浓度梯度驱动），并能解释反应扩散的驱动力。这涉及多步概念关联和综合分析能力，超越了简单的正误判断。" + }, + { + "idx": 1116, + "question": "Both martensitic transformation and bainitic transformation are diffusionless solid-state phase transformations.", + "answer": "Wrong! Martensitic transformation is a diffusionless solid-state phase transformation, while bainitic transformation involves both a diffusionless shear process and a diffusive atomic transport process, they are not the same.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性，答案明确指出了陈述的错误之处并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对马氏体相变和贝氏体相变的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在判断题中属于中等难度，需要理解并区分两种相变过程（马氏体相变和贝氏体相变）的本质差异。虽然题目涉及基础概念记忆，但要求考生不仅知道定义，还要能够辨别两种相变在扩散性方面的区别，这超出了简单的正误判断（等级1），属于概念理解的对错判断（等级2）。" + }, + { + "idx": 1117, + "question": "In the iron-carbon phase diagram, the horizontal line where the eutectoid reaction occurs has two-phase regions both above and below it, which does not conform to the phase region contact rule.", + "answer": "Wrong! The horizontal line where the eutectoid reaction occurs in the iron-carbon phase diagram represents a three-phase equilibrium reaction, which is actually a three-phase region. Thus, the difference in the number of phases between the two-phase regions above and below the horizontal line is still 1, still conforming to the phase region contact rule.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目陈述了一个关于铁碳相图的观点，并要求判断其正确性。答案明确指出了原陈述的错误，并解释了正确的情况，符合判断题的特征。 | 知识层次: 题目涉及铁碳相图中共析反应的水平线及其相区接触规则的理解和应用，需要将相图的基本概念与相区接触规则进行关联分析，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要深入理解铁碳相图中的共析反应及其相区接触规则，综合分析水平衡线上下相区的变化情况，并判断陈述是否符合相区接触规则。这涉及到多步概念关联和综合分析，超出了简单的正误判断。" + }, + { + "idx": 1118, + "question": "In terms of the lattice constant, what is the atomic diameter in an FCC crystal structure?", + "answer": "The close-packed direction in an FCC structure is [110]. In the unit cell, there are two atoms along the [110] direction, so the atomic diameter is (√2/2)a.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出原子直径，涉及公式应用和数值计算（如√2/2*a），答案呈现为具体计算结果而非选择或判断。 | 知识层次: 题目需要应用FCC晶体结构的基本知识，通过简单的几何关系和公式计算原子直径，属于基本公式的直接应用和简单计算。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要理解FCC晶体结构的[110]方向原子排列方式，并应用简单的几何关系（√2/2）进行计算。虽然需要一定的晶体学基础知识，但计算过程直接，仅涉及单一公式的应用，没有复杂的推导或多步骤计算。" + }, + { + "idx": 1119, + "question": "Why cannot the lever rule be used to analyze the relative amounts of phases in a vertical section of a ternary equilibrium phase diagram?", + "answer": "The vertical section of a ternary equilibrium phase diagram is a pseudo-binary phase diagram, and the composition points of the equilibrium phases cannot be determined on this vertical section. Therefore, the lever rule cannot be used to calculate the relative amounts of phases on the vertical section of a ternary equilibrium phase diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么杠杆规则不能用于分析三元平衡相图中垂直截面的相比例，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解三元相图中垂直截面的性质，并分析杠杆规则在此情境下的适用性，涉及多个概念的关联和综合分析。 | 难度: 在简答题题型中，该题目要求对垂直截面和杠杆规则的应用进行多角度分析论述。需要理解垂直截面在相图中的性质（伪二元相图），并解释为何杠杆规则在此情况下不适用。这涉及到对相图概念的综合理解和应用，比简单的概念解释更复杂，但尚未达到深度关联性分析的程度。" + }, + { + "idx": 1120, + "question": "Describe the characteristics of grain growth at temperatures of 760‰ and 870‰ and their engineering applications.", + "answer": "At 760‰ held for 1 hour, the grain size only grows to 0.0516mm. Comparing 0.0516mm with 0.05mm indicates that there is little change in this case, and the grains have basically not grown. However, at 870‰ held for 1 hour, the grain size grows to 0.069mm. Comparing 0.069mm with 0.05mm shows a 37% increase in grain size, indicating significant growth in this case. Therefore, when heating at relatively high temperatures, special attention must be paid to grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述晶粒生长的特性及其工程应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述晶粒生长在不同温度下的特性及其工程应用，涉及对晶粒生长现象的理解、数据的比较分析以及实际应用的综合考虑。虽然不需要复杂的机理分析或创新设计，但需要将理论知识与实际数据相结合，进行多步分析和关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解晶粒生长的基本概念，并进行温度影响下的比较分析。题目要求对不同温度下的晶粒生长情况进行描述和对比，并简要说明工程应用中的注意事项。虽然涉及多步计算和概念关联，但分析和说明的深度较为基础，没有要求多角度或深度关联性分析。" + }, + { + "idx": 1121, + "question": "Phase", + "answer": "Phase: In alloys, a homogeneous component with the same state of aggregation, the same crystal structure, essentially the same composition, and clearly defined interfaces separating it from other parts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Phase\"这一概念进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"相\"这一基础概念的定义和特征的理解，属于材料科学中最基础的概念记忆和描述性知识，不涉及应用或分析层面的要求。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求解释\"Phase\"这一基础概念的定义，内容较为直接，仅需记忆和复述材料科学中的标准定义即可，不需要进行概念间的比较或复杂体系的阐述。这符合等级1对基础概念记忆性知识的要求。" + }, + { + "idx": 1122, + "question": "If the carbon content is 0.8% in high-carbon steel with an initial grain size of 0.05mm, calculate the grain size and its growth value after holding at 870‰ for 1 hour. The formula D^(1/n) - D0^(1/n) = c t can be used for calculation, where at 870‰, the constant c is 2×10^(-8), n is 0.2, D and D0 are grain sizes in mm, and t is time in min.", + "answer": "At 870‰ for 1h: D^(1/0.2) - D0^(1/0.2) = 2×10^(-8)×60; D^5 - D0^5 = 1.2×10^(-6); D^5 = 0.05^5 + 1.2×10^(-6) = 3.125×10^(-7) + 12×10^(-7) = 15.13×10^(-7); D = (15.13×10^(-7))^(1/5) mm = 0.069mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，最终得出具体的数值结果（0.069mm），属于典型的计算题特征。 | 知识层次: 题目需要进行多步计算，涉及公式的应用和数值的代入，同时需要对晶粒生长公式的理解和运用。虽然计算过程较为直接，但需要一定的综合分析能力和对公式参数的准确理解。 | 难度: 在计算题题型中，该题目属于综合性计算问题。虽然题目提供了明确的公式和参数，但需要完成多步骤的计算过程，包括指数运算和单位转换。同时，题目要求对材料科学中的晶粒生长机制有一定理解，能够正确应用公式并处理初始条件。相比简单的单步计算题（等级2）更为复杂，但尚未达到需要处理多变量或非线性关系的最高难度（等级4）。" + }, + { + "idx": 1123, + "question": "If the carbon content is 0.8% in high-carbon steel with an original grain size of 0.05mm, calculate the grain size and its growth value after holding at 760‰ for 1 hour. The formula D^(1/n) - D0^(1/n) = c t can be used for calculation, where at 760‰, the constant c is 6×10^(-16), n is 0.1, D and D0 are grain sizes in mm, and t is time in minutes.", + "answer": "Holding at 760‰ for 1h: D^(1/0.1) - D0^(1/0.1) = 6×10^(-16)×60; D^10 - D0^10 = 3.6×10^(-14); D^10 = 3.6×10^(-14) + D0^10 = 0.05^10 + 3.6×10^(-14) = 9.77×10^(-14) + 3.6×10^(-14) = 13.4×10^(-14); D = (13.4×10^(-14))^(1/10) = 5.16×10^(-2) mm = 0.0516mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，以确定晶粒尺寸及其生长值。解答过程涉及代入数值、进行数学运算和最终得出具体数值结果，这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算，包括指数运算和单位转换，同时需要理解并应用给定的公式。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式要复杂一些，需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用给定的公式进行多步计算，涉及指数运算和单位转换，但整体计算过程较为直接，没有涉及复杂多变量或高难度数学技巧。" + }, + { + "idx": 1124, + "question": "Use the phase rule to explain why a ternary alloy can exhibit four-phase equilibrium", + "answer": "The phase rule formula is f=c-p+1, where f, c, p represent degrees of freedom, number of components, and number of phases, respectively. For a ternary alloy, when f reaches its minimum value of 0, the number of phases p is 4, indicating that four-phase equilibrium can occur. However, at this point, the degrees of freedom f is 0, meaning the compositions of all phases and the temperature are fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用相律解释三元合金可以呈现四相平衡的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求应用相律公式解释三元合金的四相平衡现象，涉及多步推理和概念关联（相律公式应用、自由度计算、相平衡条件分析），需要综合分析能力，但不需要创新或深度机理探讨。 | 难度: 在简答题题型中，该题目属于较高难度。首先，它要求考生熟练掌握相律公式并能正确代入数值（c=3时f=0推导出p=4）。其次，需要理解自由度为零时的物理意义（各相成分和温度固定）。最后，题目要求将相律理论应用于实际的三元合金系统，这需要将抽象理论与具体材料体系相结合进行综合分析。虽然不需要进行多角度或跨领域的深度关联分析，但已超出基础概念复述的范畴，属于需要多步推导和系统说明的中高难度简答题。" + }, + { + "idx": 1125, + "question": "Why can the lever rule be used to analyze the relative content of each phase in the horizontal section of a ternary equilibrium phase diagram", + "answer": "On the horizontal section (i.e., the four-phase equilibrium plane) of a ternary equilibrium phase diagram, the composition of each phase and the temperature are all determined, so the lever rule can be used to analyze the relative content of each phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么杠杆规则可以用于分析三元平衡相图中水平截面上各相的相对含量，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释杠杆定律在三元平衡相图水平截面中的应用，涉及对相图的理解和杠杆定律的应用，需要将基本原理与具体情境结合进行分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及三元平衡相图的水平截面和杠杆规则的应用，但答案只需要对基本原理进行综合分析和说明，不需要多角度分析或深度关联性分析。解题步骤相对直接，主要考察对杠杆规则在特定条件下适用性的理解。" + }, + { + "idx": 1127, + "question": "Packing density", + "answer": "Packing density: It represents the ratio of the volume occupied by atoms in a unit cell to the volume of the unit cell, and is a parameter to measure the tightness of atomic arrangement. The higher the packing density, the tighter the atomic arrangement in the crystal, and the denser the crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Packing density\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对\"packing density\"的定义和意义的解释，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"packing density\"进行基本定义和简单解释，属于最基础的概念记忆性知识。题目不涉及复杂概念体系或深入分析，仅需回忆并表述定义及其基本意义，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1128, + "question": "In terms of the lattice constant, what is the atomic diameter in the HCP crystal structure?", + "answer": "The close-packed direction in the HCP structure is [11 20], along which one atom is arranged, so the atomic diameter is a.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释HCP晶体结构中原子的直径与晶格常数的关系，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对HCP晶体结构中原子直径的基本概念记忆和理解，仅需知道密排方向上的原子排列方式即可得出答案，不涉及复杂计算或综合分析。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆HCP晶体结构中密排方向与晶格常数的关系即可作答，不涉及复杂概念解释或体系阐述。" + }, + { + "idx": 1130, + "question": "In terms of lattice constant, what is the atomic diameter in a BCC crystal structure?", + "answer": "The close-packed direction in BCC structure is [111]. In the unit cell, there are two atoms along the [111] direction, so the atomic diameter is (√3/2)a.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（涉及BCC晶体结构的晶格常数和原子直径的关系）来得出具体答案，解答过程需要运用√3/2a这样的数学计算。 | 知识层次: 题目需要应用BCC晶体结构的基本知识，通过简单的几何关系计算原子直径，属于基本公式应用和简单计算范畴。 | 难度: 在计算题中属于简单公式应用计算难度。题目虽然需要理解BCC晶体结构的[111]方向原子排列方式，但本质上只需要套用单一公式（原子直径=(√3/2)a）进行计算，不需要多个公式组合或复杂推导。解题步骤仅需识别密排方向、理解单位细胞中的原子分布关系，并应用基本几何关系计算，属于该题型内中等偏下的难度水平。" + }, + { + "idx": 1132, + "question": "The typical crystal structure types of metals are (1), (2), and (3). What are their names?", + "answer": "(1) fcc; (2) bcc; (3) hcp;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的晶体结构类型名称，需要文字回答而非选择或判断 | 知识层次: 题目考查对金属典型晶体结构类型的基本概念记忆，仅需回答fcc、bcc和hcp三种结构的名称，不涉及应用或分析。 | 难度: 该题目属于简答题中的基本定义简答类型，仅要求回忆并列出金属的三种典型晶体结构名称（fcc、bcc、hcp），无需进行概念解释或复杂阐述。在基础概念记忆的知识层次下，这是最基础的知识点考察，解题步骤简单直接，符合等级1的难度标准。" + }, + { + "idx": 1134, + "question": "What is the movement of dislocations perpendicular to the slip plane called?", + "answer": "Climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用简短的文字回答特定概念的定义或名称，不需要选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即位错运动中的“攀移”这一术语的定义，属于材料科学中位错理论的基础知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（位错垂直于滑移面的运动称为攀移），属于最基础的概念记忆层次。不需要解释机制或影响因素，解题步骤仅涉及单一术语的回忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1135, + "question": "According to the phase rule, what is the maximum number of equilibrium phases in a ternary system?", + "answer": "4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律回答三元系统中平衡相的最大数量，需要理论知识的应用和简短的文字解释，答案是一个具体的数值而非选择或判断。 | 知识层次: 题目考查对相律这一基本原理的记忆和理解，属于基础概念层面的知识。虽然涉及三元系统，但只需要直接应用相律公式F=C-P+2（其中F=0时P最大），不需要复杂的分析或综合。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目直接考察对相律在多元系统中最大平衡相数的记忆性知识，不需要额外的概念解释或复杂体系阐述，仅需准确回忆并写出三元系统的最大平衡相数即可。这符合基础概念记忆的知识层次要求，解题步骤简单直接。" + }, + { + "idx": 1136, + "question": "Solid solution strengthening", + "answer": "Solid solution strengthening: When a solid solution is formed, the solvent lattice becomes distorted due to the dissolution of solute atoms. The stress field of the solute atoms interacts with dislocations, hindering their movement and increasing the resistance to dislocation motion. This results in a critical resolved shear stress much higher than that of pure metals, making the activation of slip systems more difficult compared to pure metals. Consequently, the material's resistance to plastic deformation increases, leading to higher hardness and strength, while plasticity and toughness decrease. This phenomenon is known as solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"Solid solution strengthening\"这一现象进行详细的文字解释和论述，答案提供了完整的定义、机制和影响，符合简答题的特征。 | 知识层次: 题目要求对固溶强化的机理进行详细解释，涉及溶质原子与位错的相互作用、临界分切应力的变化以及对材料性能的影响等多方面的综合分析。这需要深入理解材料科学中的位错理论和强化机制，并进行推理分析，属于复杂分析的层次。 | 难度: 在简答题题型中，该题目要求对固溶强化现象进行机理深度解释，涉及溶剂晶格畸变、溶质原子应力场与位错的相互作用、临界分切应力的变化以及对材料性能的影响等多个方面的综合分析。虽然题目没有要求进行多现象对比或跨领域分析（这将是等级5的特征），但需要对材料科学中的核心强化机制有深入理解，并能够系统地阐述其物理本质和宏观表现，因此在简答题-复杂分析类别中属于较高难度（等级4）。" + }, + { + "idx": 1137, + "question": "According to the phase rule, what is the degree of freedom when the ternary system has the maximum number of equilibrium phases?", + "answer": "Zero", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据相律解释三元系统在最大平衡相数时的自由度，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目涉及相律的应用，需要理解三元系统在最大平衡相数时的自由度计算，属于多步计算和概念关联的中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解相律的基本概念，还需要能够将其应用于三元系统并推导出最大平衡相数时的自由度。这涉及到多步计算和概念关联，需要综合分析相律的各个组成部分及其相互关系。此外，题目还隐含了对相图知识的理解，要求考生能够将理论知识与实际应用相结合，进行较为深入的分析论述。因此，在简答题题型中，该题目属于较高难度等级。" + }, + { + "idx": 1138, + "question": "What is the movement of dislocations on the slip plane called?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用简短的文字回答特定概念的定义或名称，不需要选择或判断，也不需要计算 | 知识层次: 题目考查基本概念的记忆和理解，即位错在滑移面上的运动称为滑移（Slip），属于材料科学中基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需回忆并准确表述\"slip\"这一基础概念的定义，无需额外解释或复杂论述。题目直接考查对位错运动基本术语的记忆，属于该题型内最基础的知识点要求。" + }, + { + "idx": 1139, + "question": "According to the phase rule, what does the maximum number of equilibrium phases in a ternary system appear as on the phase diagram?", + "answer": "Plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释相律在三元系统中的最大平衡相数在相图中的表现形式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对相律这一基本概念的记忆和理解，特别是关于三元系统中最大平衡相数的表现形式。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目直接考察对相律在三元系统中最大平衡相数的记忆性知识，仅需回答\"Plane\"这个关键词即可，不需要进行概念解释或复杂体系阐述。这符合基础概念记忆层次的知识要求，解题步骤简单直接。" + }, + { + "idx": 1140, + "question": "What kind of motion cannot be performed by a screw dislocation?", + "answer": "Climb", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案\"Climb\"是一个具体的选项，符合选择题的特征 | 知识层次: 题目考查对位错运动类型的基础概念记忆，特别是对螺位错运动限制的理解，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解螺位错的基本运动方式（滑移和攀移）并进行简单辨析。虽然不涉及复杂概念区分，但需要掌握位错运动的基本原理才能正确选择\"攀移\"作为答案。" + }, + { + "idx": 1141, + "question": "The typical crystal structure types of metals are (1), (2), and (3), and what are their corresponding coordination numbers?", + "answer": "(4) 12; (5) 8; (6) 12;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的晶体结构类型和对应的配位数，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查金属典型晶体结构类型及其配位数的记忆，属于基础概念的记忆性知识 | 难度: 在简答题中属于基本定义简答，仅需记忆金属的典型晶体结构类型及其对应的配位数，无需深入解释或复杂论述。" + }, + { + "idx": 1142, + "question": "What is the slip plane of face-centered cubic metals?", + "answer": "{111}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的晶面（{111}），属于需要特定知识点的简短回答，不需要计算或选择，也不涉及判断对错。 | 知识层次: 题目考查面心立方金属滑移面的基本概念记忆，属于晶体结构的基础知识，仅需直接回忆或理解基本定义即可回答。 | 难度: 在简答题题型中，此题属于最基础的定义简答类型。题目仅要求回答面心立方金属的滑移面，这是材料科学中最基本的晶体学知识之一，不需要任何解释或论述。在\"基础概念记忆\"知识层次下，此题仅测试学生对单一晶体学参数的记忆，不涉及概念解释或复杂体系阐述，因此属于等级1难度。" + }, + { + "idx": 1143, + "question": "What is the slip direction of face-centered cubic metals?", + "answer": "<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答面心立方金属的滑移方向，答案是一个具体的晶体学方向<110>，属于需要特定知识点的简短回答，不需要计算或选择。 | 知识层次: 题目考查面心立方金属滑移方向的基本概念记忆，属于材料科学晶体结构的基础知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答面心立方金属的滑移方向，不需要额外的解释或论述。这是材料科学中最基础的概念记忆问题，属于该题型内最简单的难度等级。" + }, + { + "idx": 1144, + "question": "How many slip systems can be formed in face-centered cubic metals?", + "answer": "12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答面心立方金属中可以形成的滑移系统数量，答案是一个具体的数值（12），不需要计算过程或选项选择，属于需要直接回答的简答题类型。 | 知识层次: 题目考查面心立方金属滑移系统数量的记忆性知识，属于基础概念的记忆和理解范畴，不需要复杂的计算或分析过程。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答面心立方金属中可以形成的滑移系统数量，不需要进行概念解释或复杂体系阐述。这是对基础概念记忆的直接考察，解题步骤简单，仅需回忆相关知识点即可作答。" + }, + { + "idx": 1145, + "question": "The unit of diffusion flux is (24)", + "answer": "(24)1/cm2·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写扩散通量的单位，需要直接写出答案而非选择或判断，属于简答题类型 | 知识层次: 题目考查扩散通量的单位这一基本概念的记忆，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题-需要文字解释和论述的题型中，此题仅要求回答扩散通量的单位，属于最基础的定义性知识。不需要进行概念解释或复杂阐述，完全符合等级1\"基本定义简答\"的标准。在同类题型中，这是最简单的一类问题，只需记忆单位表达式即可作答。" + }, + { + "idx": 1146, + "question": "The symbol for diffusion flux is (25), indicating that diffusion proceeds from high concentration to low concentration.", + "answer": "(25) negative sign", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个符号（negative sign）来回答问题，属于需要简短文字回答的题目类型 | 知识层次: 题目考查对扩散通量符号及其物理意义的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，此题仅要求记忆并写出扩散通量的符号及其物理意义，属于最基本的概念记忆层面。不需要进行概念解释或复杂阐述，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这属于最基础的知识点考察，解题步骤仅需直接回忆教材定义即可完成。" + }, + { + "idx": 1147, + "question": "The first law of diffusion applies to steady-state diffusion, and its mathematical expression can be written as (23).", + "answer": "(23) J=-Ddc/dx", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个数学表达式作为答案，属于简答题中的填空类型，需要根据知识写出具体表达式而非选择或判断 | 知识层次: 题目考查对扩散第一定律的基本概念和数学表达式的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求写出第一扩散定律的数学表达式，属于最基础的概念记忆性知识，不需要进行概念解释或复杂阐述。在同类简答题中，这是最基础级别的难度，只需准确回忆公式即可完成作答。" + }, + { + "idx": 1148, + "question": "What is the conceptual difference in recrystallization?", + "answer": "Recrystallization refers to the transformation of a substance from one structure to another in the solid state, which is a solid-state phase transition process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对概念进行解释和论述，答案以文字形式呈现，没有提供选项或需要计算。 | 知识层次: 题目考查对再结晶这一基础概念的定义和基本理解，属于记忆性知识范畴，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求对\"recrystallization\"进行基本定义简答，属于最基础的概念记忆层面。题目不涉及概念间的比较、解释或复杂体系阐述，仅需直接回忆并复述定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1149, + "question": "What is the conceptual difference in crystallization?", + "answer": "Crystallization—The process by which a metal transitions from a liquid to a solid state is called solidification, and since the solid metal is a crystal, solidification is also referred to as crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对概念进行解释和论述，答案提供了详细的文字说明，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对结晶化基本概念的记忆和理解，涉及金属从液态到固态转变的定义和术语解释，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。题目明确要求解释\"crystallization\"的定义，答案直接给出了该术语的标准定义，不需要额外的解释或论述。这符合等级1\"基本定义简答\"的标准，是同类题型中最简单的类型。" + }, + { + "idx": 1150, + "question": "What is constitutional supercooling?", + "answer": "During the solidification of a solid solution alloy, the distribution of solute in the liquid phase changes, which alters the alloy's melting point. Even if the actual temperature distribution remains unchanged, the degree of supercooling at the solid-liquid interface front will vary. Therefore, the supercooling of a solid solution alloy is determined by both the changing alloy melting point and the actual temperature distribution. This type of supercooling caused by changes in liquid phase composition is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"constitutional supercooling\"进行文字解释和论述，答案提供了详细的定义和形成机制说明，符合简答题的特征。 | 知识层次: 题目考查对\"constitutional supercooling\"这一基本概念的定义和原理的理解，属于基础概念记忆范畴。答案主要解释了该现象的定义和形成原因，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"constitutional supercooling\"这一概念，需要考生理解并描述合金凝固过程中液相成分变化导致的过冷现象。虽然涉及多个相关概念（如固溶体合金、熔点变化、温度分布等），但主要考察的是对单一核心概念的解释能力，不需要构建复杂的理论体系或进行深入分析。相比等级1的基本定义简答，该题目要求更详细的概念描述；相比等级3的复杂概念体系阐述，该题目又相对简单直接。" + }, + { + "idx": 1151, + "question": "What effect does constitutional supercooling have on crystal growth morphology?", + "answer": "During the crystallization of solid solutions, constitutional supercooling significantly influences the morphology of crystal growth, leading to the formation of cellular structures or even dendritic crystals even under a positive temperature gradient. Specifically, without constitutional supercooling, the interface advances in a planar manner; with slight constitutional supercooling, the interface becomes cellular; and with substantial constitutional supercooling, the interface turns dendritic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释 constitutional supercooling 对晶体生长形态的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对constitutional supercooling如何影响晶体生长形态的详细解释，需要理解并分析其在不同条件下的具体表现（如平面、蜂窝状、树枝状等）。这要求综合运用相关概念，进行机理的解释和推理分析，属于较高层次的认知能力。 | 难度: 在简答题-复杂分析题型中，该题目要求对constitutional supercooling这一复杂现象进行全面分析，包括其对晶体生长形态的具体影响机制（从平面到细胞状再到枝晶状的转变）。这需要综合运用材料科学中的相变理论、热力学和动力学知识，并进行深入的推理分析。题目不仅要求描述现象，还需要解释背后的机理，属于该题型下最高难度的考查要求。" + }, + { + "idx": 1152, + "question": "What are the differences and connections among crystallization, recrystallization, and grain growth?", + "answer": "The differences and connections among the three: Crystallization and recrystallization involve phase transformation processes, while grain growth does not; crystallization, recrystallization, and grain growth are all processes of nucleation and growth. The driving force for crystallization and recrystallization is the free energy difference between the reactant phase and the product phase, whereas for grain growth, it is the stored energy. After grain growth, strength and hardness decrease while ductility and toughness improve, whereas recrystallization involves allotropic transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述结晶、再结晶和晶粒生长之间的区别和联系，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求区分和联系结晶、再结晶和晶粒长大这三个过程，涉及多个概念的关联和综合分析。需要理解每个过程的驱动机制、相变特性以及对材料性能的影响，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目要求对三个相关但不同的材料科学过程（结晶、再结晶和晶粒生长）进行多角度分析论述。需要明确区分它们的差异（如相变过程、驱动力来源）和联系（如成核与生长机制），并说明各自对材料性能的影响。这种综合分析超越了简单的概念对比（等级3），但尚未达到需要深度关联性分析（等级5）的程度，因此属于多角度分析论述的等级4难度。" + }, + { + "idx": 1153, + "question": "Briefly describe the differences between solid solution alloys and pure metals during the crystallization process.", + "answer": "During crystallization, the interface of pure metals is rough and grows under a positive temperature gradient. Since heat is dissipated through the solid mold wall as the crystal grows, the solid-liquid interface is isothermal. If dynamic undercooling is achieved, the interface moves forward. If a small protrusion locally extends into the overheated liquid phase, it will be melted, and the interface remains straight, resulting in planar crystal growth. During solid solution crystallization, compositional undercooling occurs, creating a compositionally undercooled zone ahead of the solid-liquid interface. If any small protrusion extends into this undercooled zone, it will continue to grow due to the undercooling. The interface cannot remain straight and stable, leading to the formation of dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固溶体合金和纯金属在结晶过程中的差异，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释和论述固溶体合金与纯金属在结晶过程中的差异，涉及动态过冷、成分过冷、界面稳定性等复杂概念，需要综合运用结晶学原理和材料科学知识进行推理分析，思维过程深度要求较高。 | 难度: 在简答题题型中，该题目要求对纯金属和固溶体合金的结晶过程进行机理深度解释，涉及界面生长、温度梯度、成分过冷等多个复杂概念的综合运用和推理分析。虽然未达到全面分析复杂现象的最高难度（等级5），但已明显超出基础描述层面，属于需要深入理解结晶学原理并整合多个知识点的中高难度题目。" + }, + { + "idx": 1155, + "question": "Analyze the changes of vacancies and dislocations during the low-temperature recovery stage and their effects on properties", + "answer": "During the low-temperature recovery stage, the primary phenomenon is the disappearance of vacancies. The large number of vacancies generated after cold deformation are drastically reduced through various mechanisms, including vacancy migration to surfaces or grain boundaries, recombination of vacancies with interstitial atoms, interaction between vacancies and dislocations, and aggregation of vacancies into vacancy clusters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析低温回复阶段空位和位错的变化及其对性能的影响，需要详细的文字解释和论述，符合简答题的特征。答案也提供了详细的文字描述，而非选择、判断或计算。 | 知识层次: 题目要求分析低温回复阶段空位和位错的变化及其对性能的影响，涉及多个机制的相互作用（空位迁移、复合、聚集等）以及对材料性能的综合影响，需要综合运用知识进行推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析低温回复阶段的空位和位错变化及其对性能的影响。需要综合运用多个机理（空位迁移、复合、相互作用和聚集）进行推理分析，并解释这些变化如何影响材料性能。这种深度和广度的要求在该题型内属于最高难度等级。" + }, + { + "idx": 1156, + "question": "Explain the reason why the strength is higher and the plasticity is better when the grain size is smaller during plastic deformation of polycrystalline metals.", + "answer": "The reason why the strength is higher and the plasticity is better when the grain size is smaller during plastic deformation of polycrystalline metals is as follows: Due to the fine grains, the slip planes available for dislocation pile-up in each grain are shorter, and the number of piled-up dislocations $_{n}$ is also smaller. The stress concentration caused by dislocation pile-up is small and dispersed, making it more difficult to activate dislocation sources in adjacent grains, thus resulting in higher yield strength. With fine and numerous grains, under the same external force, the number of grains in favorable slip orientations increases, allowing more grains to participate in slip. The slip amount is dispersed among various grains, and the stress concentration is small. This reduces the likelihood of cracking during metal deformation, enabling a larger plastic deformation before fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶金属塑性变形时晶粒尺寸较小导致强度和塑性提高的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多晶金属塑性变形中晶粒尺寸对强度和塑性的影响机制，涉及位错堆积、应力集中、滑移面等多个概念的关联和综合分析，需要深入理解材料变形机理并进行推理分析。 | 难度: 在简答题题型中，该题目要求对多晶金属塑性变形过程中晶粒尺寸对强度和塑性的影响进行机理深度解释。需要综合运用位错理论、应力集中、晶粒取向等知识，分析细晶强化和塑性改善的具体机制。虽然不涉及最复杂的多因素交互作用分析，但需要清晰的逻辑链条和准确的术语表达，属于机理深度解释等级。" + }, + { + "idx": 1157, + "question": "Analyze the changes of vacancies and dislocations during the medium-temperature recovery stage and their effects on properties", + "answer": "During the medium-temperature recovery stage, the increase in temperature facilitates the glide of dislocations. Dislocations with opposite signs on the same slip plane attract and annihilate each other, not only reducing the number of dislocations within subgrains but also significantly decreasing the tangled dislocations in cell walls. The rearrangement becomes more ordered, and the cell walls become clearer, forming recovered subgrains. This stage is primarily characterized by the glide of dislocations, leading to dislocation recombination, the annihilation of dislocations with opposite signs, and the growth of subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对中温回复阶段空位和位错的变化及其对性能的影响进行分析和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目要求分析中温回复阶段空位和位错的变化及其对性能的影响，涉及位错的滑移、重组、湮灭以及亚晶粒的形成等复杂机理，需要综合运用材料科学中的位错理论和回复机制进行推理分析，思维过程深度要求较高。 | 难度: 在简答题 - 需要文字解释和论述的题型中，该题目属于复杂分析的知识层次，要求综合运用、推理分析和机理解释。题目涉及中等温度回复阶段空位和位错的变化及其对性能的影响，需要深入理解位错的滑移、重组、湮灭以及亚晶粒的形成等复杂现象，并进行全面的分析。此外，解题步骤较为复杂，需要系统地阐述多个相互关联的机理和现象，因此在该题型内属于最高难度等级。" + }, + { + "idx": 1158, + "question": "Analyze the changes of vacancies and dislocations during the high-temperature recovery stage and their effects on properties", + "answer": "During the high-temperature recovery stage, the kinetic conditions for dislocation motion are more sufficient, and slip is accompanied by climb, causing the dislocation densities on multiple slip planes to tend to equalize. The interactions between dislocations lead to a uniform distribution of dislocations on the same slip plane with roughly equal spacing, forming regularly arranged dislocation walls perpendicular to the slip plane, a process known as polygonization. The dislocation walls formed by polygonization constitute small-angle grain boundaries, which divide the original grains into several subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高温回复阶段空位和位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高温回复阶段空位和位错的变化及其对性能的影响，涉及多个概念的关联和机理解释，需要综合运用材料科学知识进行推理分析。 | 难度: 在简答题题型中，该题目要求对高温回复阶段的空位和位错变化及其对性能的影响进行全面分析。需要综合运用材料科学中的位错理论、回复机制和性能关系等知识，进行深入的推理和解释。题目涉及多个复杂概念的整合，如位错运动、多边形化过程、小角度晶界形成等，并要求将这些机制与材料性能变化联系起来。这种综合分析和机理深度解释的要求，使得该题目在同题型内属于最高难度等级。" + }, + { + "idx": 1159, + "question": "Annealing", + "answer": "Annealing: A heat treatment process in which a metal or its alloy is heated above the phase transition temperature, held for a period of time, and then cooled at a relatively slow rate to obtain a nearly equilibrium microstructure is called annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Annealing\"这一术语进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对退火（Annealing）这一基本热处理工艺的定义和基本原理的记忆和理解，属于材料科学中的基础概念。 | 难度: 在简答题题型中，该题目仅要求回答\"Annealing\"的基本定义，属于最基础的概念记忆性知识。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。题目直接考查对专业术语的定义记忆，不涉及任何扩展性解释或应用分析，是同类题型中最简单的类型。" + }, + { + "idx": 1161, + "question": "A cylindrical face-centered cubic single crystal with a diameter of 1mm has its tensile axis aligned with the [001] direction of the crystal. Determine its equivalent slip systems.", + "answer": "When the crystal is FCC and the force axis is in the [001] direction, among the 12 slip systems, the [110] crystal direction is perpendicular to the force axis, while the others have equal angles with the force axis, and 4 slip systems are also equivalent. Therefore, the equivalent slip systems are 8 in total. Specifically, they are (111)[101], (111)[011], (111)[101], (111)[011], (111)[10 1], (111)[011], (11 1)[011], and (11 1)[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定等效滑移系统，答案提供了详细的解释和具体的滑移系统列表，属于需要文字论述的简答题类型。 | 知识层次: 题目要求确定等效滑移系统，需要理解FCC晶体的滑移系统及其与拉伸轴方向的关系，涉及多步分析和概念关联，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识（FCC结构、滑移系统、晶向关系）进行多步分析，并准确识别等效滑移系统的几何关系。解题过程涉及晶体方向的垂直性判断、角度计算以及等效性论证，要求较强的空间想象力和概念关联能力。虽然不需要深度关联性分析（如跨学科或多物理场耦合），但已超出基础概念复述层面，属于多角度分析论述级别。" + }, + { + "idx": 1165, + "question": "Hardenability", + "answer": "Hardenability: refers to the tendency of steel to obtain martensite structure during quenching (i.e., the ability of steel to be hardened).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Hardenability\"这一术语进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对\"Hardenability\"这一基本概念的定义和简单解释，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对\"Hardenability\"这一基础概念进行定义性回答，属于最基本的概念记忆层次。题目不涉及概念间的关联分析或复杂体系阐述，仅需复述教材中的标准定义即可完成作答，符合等级1\"基本定义简答\"的典型特征。" + }, + { + "idx": 1167, + "question": "The typical crystal structure types of metals are (1), (2), and (3)", + "answer": "(1) FCC; (2) BCC; (3) HCP", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写典型的金属晶体结构类型，答案需要列举具体的结构名称（FCC, BCC, HCP），属于简答题的形式，不需要选择或判断对错，也不需要计算。 | 知识层次: 题目考查金属典型晶体结构类型的基础概念记忆，仅需回忆FCC、BCC和HCP三种基本结构名称，不涉及应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求列举金属的典型晶体结构类型，属于基础概念记忆的范畴。题目不需要解释或描述这些结构的特点，也不需要阐述复杂的概念体系。因此，在同题型内属于最简单的难度等级，即基本定义简答。" + }, + { + "idx": 1168, + "question": "A cylindrical face-centered cubic single crystal with a diameter of 1mm has its tensile axis aligned with the [001] direction of the crystal. If the tensile force at yield is 0.5N, what is the resolved shear stress on the slip system?", + "answer": "Ω=cosλcosφ=√2/2×1/√3=√6/6 τ=P/AΩ=0.5/π(1/2)^2×√6/6MPa=0.26MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解剪切应力，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括确定滑移系统的方向余弦、计算分切应力，并应用相关公式进行数值求解。这需要理解晶体取向、滑移系统以及分切应力的概念，并将这些概念关联起来进行综合分析。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体取向、滑移系统、分切应力等概念，并进行多步计算和公式应用。虽然计算步骤较多，但每个步骤相对明确，没有涉及复杂多变量或非常规解法。" + }, + { + "idx": 1169, + "question": "What type of solid solution is ferrite?", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述铁素体的固溶体类型，答案\"Interstitial\"是一个简短的术语回答，属于简答题形式 | 知识层次: 题目考查对铁素体（ferrite）类型的基本概念记忆，属于材料科学中固溶体分类的基础知识，无需复杂分析或推理。 | 难度: 在简答题题型中，该题目仅要求回答\"ferrite\"属于哪种固溶体类型，属于基础定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可作答，符合等级1的基本定义简答标准。" + }, + { + "idx": 1170, + "question": "The typical coordination numbers for metal crystal structures should be (4), (5), and (6)", + "answer": "(4) 12; (5) 8; (6) 12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值作为答案，而不是从给定的选项中选择或判断对错，也不需要复杂的计算过程。答案的形式是直接填写数值，类似于简答题的回答方式。 | 知识层次: 题目考查金属晶体结构中配位数的基本概念记忆，属于定义和分类的记忆性知识 | 难度: 在简答题题型中，该题目仅要求记忆金属晶体结构的典型配位数，属于最基础的定义性知识回答。不需要解释或描述概念，更不需要构建复杂的概念体系。完全符合等级1\"基本定义简答\"的标准，是该题型中最简单的难度层级。" + }, + { + "idx": 1171, + "question": "Martensite is a supersaturated solid solution of carbon in what?", + "answer": "α-Fe", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的概念或术语（α-Fe），不需要从多个选项中选择，也不需要计算或判断对错，符合简答题的特征 | 知识层次: 题目考查马氏体的基本定义和组成，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆类问题，仅需回答\"α-Fe\"这一简单事实性知识，不需要进行概念解释或复杂阐述。题目直接询问马氏体的基本组成，属于该题型下最基础的定义简答级别。" + }, + { + "idx": 1172, + "question": "What type of solid solution is formed when the radius of solute atoms differs significantly from that of solvent atoms?", + "answer": "Interstitial", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个可能的固体溶液类型中选择正确答案，答案\"Interstitial\"是其中一个选项 | 知识层次: 题目考查对固溶体类型的基本概念记忆和理解，特别是间隙固溶体的定义和形成条件，属于基础概念记忆层次。 | 难度: 在选择题中属于中等偏下难度，需要理解固溶体的基本分类（置换型和间隙型）以及原子半径差异对固溶体类型的影响。虽然涉及概念理解，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 1173, + "question": "What type of solid solution can be formed when the atomic radius of the solute is similar to that of the solvent?", + "answer": "Substitutional", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个术语而非从多个选项中选择或简单的对错判断，也不涉及数值计算。 | 知识层次: 题目考查对固溶体类型的基本概念记忆和理解，特别是当溶质和溶剂原子半径相似时形成的置换固溶体。这属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（置换型固溶体），属于最基础的概念记忆层面。不需要解释或描述，更不涉及复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1177, + "question": "What are the two metallographic morphologies of martensite in quenched steel?", + "answer": "Lath martensite and acicular martensite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举淬火钢中马氏体的两种金相形态，答案需要文字解释和论述，而非选择或判断 | 知识层次: 题目考查对马氏体两种金相形态的基本分类记忆，属于基础概念的记忆性知识，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并准确复述马氏体的两种金相形态名称（板条马氏体和针状马氏体），不涉及概念解释或复杂体系阐述。该题目完全符合基础概念记忆的知识层次要求，是同类题型中最基础的考查形式。" + }, + { + "idx": 1178, + "question": "The solid-liquid interface of crystals is divided into smooth interface and rough interface. According to the growth speed from slow to fast, the growth methods are (13), (14), and (15) in order.", + "answer": "(13) Two-dimensional nucleation growth; (14) Crystal defect growth; (15) Vertical growth", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的生长方法名称，属于需要文字解释和论述的简答题类型。答案不是从选项中选择，而是需要根据知识填写具体术语。 | 知识层次: 题目考查晶体生长方式的基本分类和顺序记忆，属于基础概念的记忆性知识 | 难度: 在简答题中属于中等难度，需要记忆并理解晶体生长方式的分类及其顺序，但不需要复杂的解释或论述。" + }, + { + "idx": 1179, + "question": "The two basic types of dislocations are (22) and (23)", + "answer": "(22) edge dislocation; (23) screw dislocation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个基本类型的位错名称，需要具体的文字回答而非选择或判断 | 知识层次: 题目考查位错的基本类型（刃位错和螺位错）的记忆和理解，属于材料科学中最基础的概念性知识 | 难度: 在简答题题型中，该题目仅要求回答两种基本位错类型的名称，属于最基础的定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可完成，符合等级1的基本定义简答标准。" + }, + { + "idx": 1180, + "question": "During austenite nucleation, not only (10) fluctuations and (11) fluctuations are required, but also (12) fluctuations are needed", + "answer": "(10) structure; (11) energy; (12) composition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的术语（structure, energy, composition）来补充句子，属于需要提供简短答案的填空题形式，而非选择题、判断题或计算题。 | 知识层次: 题目考查对奥氏体形核过程中所需波动类型的基础概念记忆，属于定义和基本原理的记忆性知识 | 难度: 在简答题中属于中等难度，需要理解并记忆多个相关概念（结构、能量、成分波动），并进行简要解释和描述，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 1181, + "question": "The relationship between the direction of the dislocation line of an edge dislocation and the Burgers vector is (24)", + "answer": "(24) perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释刃位错的位错线方向与伯格斯矢量之间的关系，答案\"perpendicular\"是一个简短的文字描述，符合简答题的特征 | 知识层次: 题目考查对刃位错中位错线与伯格斯矢量方向关系的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答边缘位错的位错线方向与伯格斯矢量之间的关系，属于基础定义简答。题目仅涉及单一概念的记忆性知识，不需要解释或描述，更不需要复杂概念体系的阐述。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 1182, + "question": "Ferritic stainless steel is (27)", + "answer": "(27) 1Cr17", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的材料名称（1Cr17），属于需要简短回答的填空题形式，不需要选择或判断，也不涉及计算。 | 知识层次: 题目考查对铁素体不锈钢基本分类的记忆，仅需回忆1Cr17这一特定牌号，不涉及复杂分析或应用过程 | 难度: 在简答题题型中，该题目仅要求回答\"Ferritic stainless steel\"的具体牌号\"1Cr17\"，属于基础概念记忆层面的简单回答，无需解释或描述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1183, + "question": "The typical steel grade of martensitic stainless steel is (25）", + "answer": "（25）1Cr13", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的钢号作为答案，属于需要简短文字回答的类型，不需要选择或判断 | 知识层次: 题目考查对马氏体不锈钢典型钢号的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆特定钢种的代表性牌号（1Cr13），无需解释或描述概念内涵，属于最基础的概念记忆层级。" + }, + { + "idx": 1184, + "question": "The typical steel grade of austenitic stainless steel is (26)", + "answer": "(26) 1Cr18Ni9Ti", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的钢号作为答案，而不是从多个选项中选择或判断对错，也不需要计算。答案形式为简短的文字回答。 | 知识层次: 题目考查对奥氏体不锈钢典型钢号的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆类，仅需回忆并写出典型奥氏体不锈钢的牌号（1Cr18Ni9Ti），无需进行概念解释或复杂体系阐述。题目仅测试学生对基本材料分类的记忆能力，属于该题型下最简单的难度等级。" + }, + { + "idx": 1185, + "question": "Uphill diffusion refers to the diffusion of atoms from (28) to (29). The reason for uphill diffusion is the existence of (30) in the alloy system.", + "answer": "(28) low concentration; (29) high concentration; (30) chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定位置的答案（28）、（29）、（30），这些答案需要基于对\"uphill diffusion\"概念的理解，属于简答性质的填空题，而非选择、判断或计算。 | 知识层次: 题目考查对uphill diffusion基本概念的记忆和理解，包括扩散方向和原因，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释和描述基本概念（上坡扩散的定义和原因），但不需要复杂的体系阐述或深入分析。题目要求记忆并简要说明基本原理（化学势梯度），属于概念解释和描述的范畴。" + }, + { + "idx": 1187, + "question": "Discuss the characteristics exhibited by pure metals during the solidification process and explain the reasons?", + "answer": "During crystallization, the interface of a pure metal is rough and grows under a positive temperature gradient. Since heat is dissipated through the solid mold wall as the crystal grows, the solid-liquid interface remains isothermal. If a dynamic undercooling is achieved, the interface advances forward. If a small protrusion locally extends into the overheated liquid phase, it will be melted, keeping the interface straight, and the crystal grows in a planar manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论纯金属在凝固过程中表现出的特性并解释原因，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的解释和描述，符合简答题的特征。 | 知识层次: 题目要求讨论纯金属在凝固过程中的特性并解释原因，涉及对凝固过程中界面行为、温度梯度、动态过冷等复杂现象的综合分析和机理解释，需要较高的认知能力和深度理解。 | 难度: 在简答题-复杂分析题型中，该题目要求对纯金属凝固过程中的界面特征和生长机理进行深度解释，涉及温度梯度、动态过冷等专业概念的运用，需要综合材料科学和热力学知识进行推理分析，但尚未达到多因素交互作用的复杂现象全面分析程度。" + }, + { + "idx": 1188, + "question": "Discuss the characteristics exhibited by solid solution alloys during the solidification process and explain the reasons?", + "answer": "During the crystallization of a solid solution, constitutional supercooling occurs, leading to the formation of a constitutionally supercooled zone ahead of the solid-liquid interface. If any small protrusion appears on the interface, it will extend into the constitutionally supercooled zone and continue to grow by obtaining supercooling. As a result, the interface cannot remain flat and stable, leading to the formation of dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论固溶体合金在凝固过程中的特性并解释原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论固溶体合金在凝固过程中的特性并解释原因，涉及凝固过程中的成分过冷、固液界面稳定性以及枝晶形成等复杂机理的分析和解释。这需要综合运用材料科学中的凝固理论、热力学和动力学知识，进行深入的推理和分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对固溶体合金凝固过程中的特性进行机理深度解释，涉及组成过冷、枝晶形成等专业概念的详细阐述。虽然不需要像等级5那样进行多因素全面分析，但需要对凝固界面稳定性这一核心机理有深入理解，并能够逻辑清晰地解释枝晶形成的全过程，这已经达到了该题型内较高的机理解释要求。" + }, + { + "idx": 1189, + "question": "What is the main difference between the first type and the second type of temper brittleness?", + "answer": "The first type of temper brittleness is irreversible, while the second type is reversible. The first type of temper brittleness is caused by the precipitation of discontinuous thin-shell carbides along the interfaces of martensite laths or plates during martensite decomposition. The second type of temper brittleness is caused by the segregation of impurity elements such as Sb, Sn, P, and As to the original austenite grain boundaries during tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种回火脆性的主要区别，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释两种回火脆性的主要区别，涉及不可逆与可逆性、碳化物析出和杂质元素偏析等机理。需要综合分析材料微观结构变化与性能的关系，属于对复杂现象的机理解释和对比分析。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求解释两种回火脆性的主要区别，不仅需要明确区分两者的可逆性差异，还需要深入分析各自的形成机理，包括第一类回火脆性中不连续薄壳碳化物的析出和第二类回火脆性中杂质元素的偏聚。这种题目要求考生具备扎实的材料科学基础，能够综合运用知识进行推理分析，并对复杂现象进行全面解释，因此在简答题题型中属于最高难度等级。" + }, + { + "idx": 1190, + "question": "What is the first type of temper brittleness?", + "answer": "The brittleness that occurs during tempering between 250~400°C is called low-temperature temper brittleness, also known as the first type of temper brittleness. The first type of temper brittleness is irreversible temper brittleness, which is caused by the discontinuous thin-shell-like carbides precipitated along the interface of martensite laths or plates during martensite decomposition, reducing the fracture strength of grain boundaries and making them the path for crack propagation, thus leading to brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是第一种回火脆性，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对回火脆性类型的基本概念记忆和理解，包括其温度范围、不可逆性以及形成机理等基础知识点。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释第一类回火脆性的定义、温度范围、不可逆性以及产生机理，涉及多个知识点的串联，但不需要构建复杂的理论体系或进行深入分析。相比等级1的简单定义复述，该题需要更系统的概念描述；相比等级3的复杂理论阐述，该题对知识整合的要求相对有限。" + }, + { + "idx": 1191, + "question": "How to solve the difficulties caused by work hardening in subsequent processing?", + "answer": "Recrystallization annealing can be used to eliminate the difficulties caused by work hardening in subsequent processing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何解决加工硬化带来的困难，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及工作硬化的后续处理问题，需要通过理解工作硬化的基本原理，并结合再结晶退火的概念来解决问题。这需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求解释和论述，但答案相对直接，主要涉及单一概念（再结晶退火）的应用。不需要多角度分析或深度关联性分析，只需综合说明再结晶退火如何解决加工硬化带来的困难即可。因此，在简答题的框架内，该题目属于综合分析和说明的难度水平。" + }, + { + "idx": 1192, + "question": "What is the second type of temper brittleness?", + "answer": "The brittleness that occurs during tempering between 450~650℃ is called high-temperature temper brittleness, also known as the second type of temper brittleness. The second type of temper brittleness is reversible. The main reason for its occurrence is that impurity elements such as Sb, Sn, P, and As segregate to the original austenite grain boundaries during tempering, weakening the atomic bonding force at the austenite grain boundaries and reducing the grain boundary fracture strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释什么是第二种回火脆性，并需要详细说明其特点和原因，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目不仅要求记忆第二类回火脆性的定义和温度范围，还需要解释其可逆性特征和机理性原因（杂质元素在奥氏体晶界的偏聚行为及其对断裂强度的影响），涉及材料科学中相变、晶界偏聚和断裂机理的关联分析，属于需要综合运用知识进行机理解释的复杂分析层次。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求不仅解释第二类回火脆性的定义，还需要详细说明其发生的温度范围、可逆性特点，以及杂质元素偏聚导致晶界弱化的具体机理。这需要考生综合运用材料科学知识，进行多层次的推理分析，并准确表述复杂的材料失效机制，完全符合等级5对\"复杂现象全面分析\"的要求。" + }, + { + "idx": 1193, + "question": "Analyze the changes of vacancies during the low-temperature recovery stage and their impact on properties", + "answer": "During the low-temperature recovery stage, the main manifestation is the disappearance of vacancies. The large number of vacancies generated after cold deformation are drastically reduced through mechanisms such as vacancies migrating to surfaces or grain boundaries, recombination of vacancies with interstitial atoms, interaction of vacancies with dislocations, and aggregation of vacancies into vacancy clusters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析低温回复阶段空位的变化及其对性能的影响，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和机制描述，符合简答题的特征。 | 知识层次: 题目要求分析低温回复阶段空位的变化及其对性能的影响，涉及空位的迁移、复合、相互作用和聚集等复杂机制，需要综合运用材料科学中的缺陷理论和性能关系进行推理分析，思维深度较高。 | 难度: 在简答题的复杂分析题型中，该题目要求对低温回复阶段的空位变化及其对性能的影响进行机理深度解释。虽然题目涉及多个机制（空位迁移、与间隙原子的复合、与位错的相互作用、空位团簇的形成），但并未要求将这些机制与具体材料性能变化建立复杂的定量关系或跨尺度分析，因此属于等级4的机理深度解释范畴，而非等级5的全面复杂现象分析。" + }, + { + "idx": 1194, + "question": "The typical crystal structures of metals are (1), (2), and (3)", + "answer": "(1) body-centered cubic; (2) face-centered cubic; (3) close-packed hexagonal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写典型的金属晶体结构名称，需要文字回答而非选择或判断 | 知识层次: 题目考查金属典型晶体结构的基本概念记忆，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举金属的典型晶体结构，不需要进行概念解释或复杂体系阐述，属于最基础的概念记忆性知识。在同类简答题中，这是最基础、最简单的类型，仅需回忆和列举三个标准答案即可。" + }, + { + "idx": 1195, + "question": "Analyze the changes in dislocations during the high-temperature recovery stage and their impact on properties", + "answer": "During the high-temperature recovery stage, the kinetic conditions for dislocation motion are more sufficient, involving both slip and climb, which leads to a tendency for the dislocation densities on multiple slip planes to become equal. The interactions between dislocations cause the dislocations on the same slip plane to distribute uniformly with roughly equal spacing, forming regularly arranged dislocation walls perpendicular to the slip plane, a process known as polygonization. The dislocation walls formed by polygonization are small-angle grain boundaries, which divide the original grain into several subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高温回复阶段位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高温回复阶段位错的变化及其对性能的影响，涉及位错运动、多边形化过程、小角度晶界的形成等多个复杂概念的综合运用和机理解释，需要深入理解和推理分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求分析高温回复阶段位错的变化及其对性能的影响，涉及到位错运动、多边形化过程以及小角度晶界的形成等复杂机理。虽然题目没有要求全面分析所有可能的复杂现象，但对机理的解释需要较深入的理解和综合运用知识的能力，因此在简答题题型中属于较高难度。" + }, + { + "idx": 1196, + "question": "In homogeneous nucleation, assuming the nucleus shape is a cube with side length a, given σ and ΔGv, find the critical nucleus side length", + "answer": "The critical nucleus side length is (-4σ)/ΔGv", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（σ和ΔGv）进行计算，并应用公式来求解临界核边长，最终答案是一个具体的数值表达式（(-4σ)/ΔGv），这符合计算题的特征。 | 知识层次: 题目要求应用给定的公式（σ和ΔGv）进行直接计算，属于基本公式应用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（临界核尺寸公式）进行计算，无需任何公式组合或复杂推导步骤。题目明确给出了所有必要参数（σ和ΔGv），解题过程仅涉及基本代数运算。" + }, + { + "idx": 1197, + "question": "Analyze the changes in dislocations during the medium-temperature recovery stage and their impact on properties", + "answer": "During the medium-temperature recovery stage, the increase in temperature facilitates the glide of dislocations. Dislocations of opposite signs on the same slip plane attract and annihilate each other, not only reducing the number of dislocations within the subgrains but also significantly decreasing the tangled dislocations in the cell walls. This leads to a rearrangement into a more regular configuration, resulting in clearer cell walls and the formation of recovery subgrains. In this stage, the primary phenomena are the glide of dislocations, leading to their recombination, the annihilation of dislocations of opposite signs, and the growth of subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错在中温回复阶段的变化及其对性能的影响，需要详细的文字解释和论述，答案也提供了详细的描述和分析，符合简答题的特征。 | 知识层次: 题目要求分析中温回复阶段位错的变化及其对性能的影响，涉及位错的运动、重组、湮灭以及亚晶的形成等复杂机理的解释和综合分析。这需要深入理解位错理论、回复过程的动力学以及材料性能的变化机制，属于较高层次的认知能力和复杂分析。 | 难度: 在简答题（复杂分析类）中属于机理深度解释难度等级。该题目要求考生不仅描述位错变化现象，还需要解释位错滑移、重组、湮灭等微观机制对亚晶形成的影响，涉及位错动力学和回复亚结构演变等较深层次的材料科学原理。虽然不需要像等级5那样进行多因素耦合分析，但需要建立清晰的因果链条和机理模型，属于需要运用专业理论进行系统性解释的中高难度题目。" + }, + { + "idx": 1198, + "question": "What kind of motion can an edge dislocation undergo?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释位错可以进行的运动类型，答案需要文字解释而非选择或判断 | 知识层次: 题目考查位错运动类型的基本概念记忆，属于材料科学中位错理论的基础知识，仅需回忆边缘位错的主要运动方式（滑移）即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答边缘位错的基本运动类型（滑移），属于最基础的定义性知识。不需要解释或描述概念，更无需复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于直接调用记忆性知识就能作答的题目。" + }, + { + "idx": 1199, + "question": "What other motion can an edge dislocation undergo?", + "answer": "Climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用简短的文字回答位错的其他运动方式，答案\"Climb\"是一个术语而非选项，属于需要专业知识解释的简答题类型 | 知识层次: 题目考查位错运动的基本概念，特别是边缘位错的攀移运动，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目仅要求回答\"edge dislocation\"可以进行的另一种运动形式（climb），属于基本定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可作答，符合等级1的基本定义简答标准。" + }, + { + "idx": 1200, + "question": "When a copper single crystal is stretched, if the force axis is in the [001] direction and the critical resolved shear stress is 0.64 MPa, what tensile stress is required to initiate slip in the crystal?", + "answer": "Since copper is face-centered cubic, the slip plane is {111} and the slip direction is <110>. Given that the force axis is [001], the four slip directions [110] and [1-10] are excluded, leaving eight equivalent slip systems. γ = 45°. cosλ = cos45° = √2/2. cosφ = |1×0 + 1×0 + 1×0| / (√(1² + 1² + 1²) × √(0² + 0² + 1²)) = √3/3. The formula is σ = τ / Ω = 0.64 / (cosλ cosφ) = 1.57 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的拉伸应力，解答过程中涉及到了三角函数计算和临界分切应力的应用，最终得出具体的数值结果。 | 知识层次: 题目需要理解晶体滑移系统的基本原理，并应用临界分切应力的概念进行多步计算。涉及晶体学方向的计算和三角函数应用，需要综合分析不同滑移系统的几何关系，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构、滑移系统、临界分切应力等概念，并进行多步骤计算（包括方向余弦计算、分切应力公式应用等）。虽然计算过程明确，但需要综合运用多个知识点和公式，属于中等偏上的难度。" + }, + { + "idx": 1201, + "question": "What kind of motion can a screw dislocation undergo?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和描述某种运动类型，答案需要文字说明而非选择或判断 | 知识层次: 题目考查对位错运动类型的基本概念记忆，仅需回答\"滑移\"这一基础概念，无需深入分析或综合应用。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并准确写出\"滑移\"这一基本概念即可，无需展开解释或描述复杂机制，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 1202, + "question": "Why can screw dislocations only undergo glide motion?", + "answer": "Because it does not have a fixed half-atom plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么螺型位错只能进行滑移运动，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对位错运动基本原理的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释为什么螺型位错只能进行滑移运动，这需要理解位错的基本概念和运动机制，但不需要涉及复杂的理论推导或多概念整合。答案只需简要说明螺型位错没有固定的半原子面这一关键特征即可，属于对单一概念的深入解释范畴。" + }, + { + "idx": 1203, + "question": "The corresponding number of atoms per unit cell is (4), (5), and (6)", + "answer": "(4) 2; (5) 4; (6) 6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写对应的数值答案，属于需要简短回答的问题，答案形式为具体数值而非选择或判断 | 知识层次: 题目考查对单位晶胞中原子数量的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求记忆并写出特定晶胞中的原子数量，属于最基础的定义性知识回答。不需要解释或推导过程，完全基于对基础概念的记忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1204, + "question": "During the crystallization of a solid solution, nucleation requires both (13) fluctuations and (14) fluctuations, as well as (15) fluctuations.", + "answer": "(13) structure; (14) energy; (15) composition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定的术语（结构、能量、组成）来完成句子，属于需要文字回答的简答题形式，而非选择题、判断题或计算题。 | 知识层次: 题目考查对结晶过程中成核所需的基本概念的记忆，包括结构、能量和成分的波动，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释和描述多个相关概念（结构、能量和成分波动），但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 1205, + "question": "In homogeneous nucleation, assuming the nucleus shape is a cube with side length a, given σ and ΔGv, find the critical nucleation work", + "answer": "The critical nucleation work is 32σ³/ΔGv²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（σ和ΔGv）和公式应用来计算临界成核功，答案是一个具体的数值计算结果（32σ³/ΔGv²），符合计算题的特征。 | 知识层次: 题目需要理解均匀成核的基本概念，并应用给定的几何形状（立方体）和参数（σ和ΔGv）进行多步计算，推导临界成核功的表达式。这涉及到概念关联和综合分析，而不仅仅是简单的公式套用或基础概念记忆。 | 难度: 在计算题中属于综合性计算问题，需要理解均匀成核理论中的临界成核功概念，应用给定的表面能σ和体积自由能变化ΔGv，进行多步骤的公式推导和计算。虽然题目给出了核的形状和边长，但仍需综合分析并正确应用公式来求解临界成核功，体现了中等应用层次的知识要求。" + }, + { + "idx": 1206, + "question": "The characteristics of polycrystalline plastic deformation are (18)ity, (19)ity, and (20)ity.", + "answer": "(18) non-simultaneous; (19) coordinated; (20) non-uniform", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定的单词或短语来完成句子，而不是从给定的选项中选择或进行判断、计算。虽然形式上类似于填空题，但更符合简答题的特征，因为需要理解并准确描述材料科学中的概念。 | 知识层次: 题目考查对多晶塑性变形特征的基础概念记忆，仅需回忆并填写三个特性词汇，不涉及应用或分析过程。 | 难度: 在简答题题型中，该题目要求考生回忆并填写三个关键特征，属于概念解释和描述的范畴。虽然需要记忆多个术语，但不需要深入阐述或构建复杂的概念体系，因此属于中等难度。" + }, + { + "idx": 1207, + "question": "When a crystal undergoes tensile slip, the slip plane is driven to rotate, attempting to align parallel to the (16), while the slip direction also rotates to coincide with the (17) direction.", + "answer": "(16) direction of the force axis; (17) maximum resolved shear stress", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求填写特定的术语或概念（如“direction of the force axis”和“maximum resolved shear stress”），属于需要文字解释和论述的简答题形式。 | 知识层次: 题目涉及晶体滑移过程中滑移面和滑移方向的旋转机制，需要理解滑移面与力轴方向的关系以及滑移方向与最大分切应力方向的关系。这需要对晶体塑性变形的基本原理有较好的理解，并能将多个概念关联起来进行分析。虽然不涉及复杂的计算或深度推理，但需要一定的综合分析能力。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及晶体滑移过程中的两个关键旋转方向（力轴方向和最大分切应力方向），但只需进行基本的概念关联和综合分析即可回答。题目不需要多角度分析论述（等级4）或深度关联性分析（等级5），主要考察对晶体滑移机制的理解和应用能力。" + }, + { + "idx": 1208, + "question": "Burgers vector", + "answer": "Burgers vector: A physical quantity used to describe the lattice distortion caused by dislocations. The magnitude of this vector represents the strength of the dislocation, indicating the total extent of lattice distortion, while its direction represents the direction of lattice point distortion. Generally, the larger this vector is, the greater the degree of crystal distortion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Burgers vector进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查Burgers vector的基本定义和物理意义的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释Burgers vector的定义、物理意义及其方向和大小的含义，这需要学生对相关概念有一定的理解和记忆，但不需要复杂的推导或深入的分析。相比于等级1的基本定义简答，该题目要求更详细的描述；而相比于等级3的复杂概念体系阐述，该题目涉及的知识点较为单一，不需要构建复杂的知识框架。因此，该题目在简答题题型中属于中等难度。" + }, + { + "idx": 1210, + "question": "What is the equilibrium distribution coefficient?", + "answer": "Equilibrium distribution coefficient: During the crystallization of solid solution alloys, selective crystallization occurs. Therefore, under equilibrium conditions at a certain temperature, the ratio of the solid phase composition to the liquid phase composition is called the equilibrium distribution coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"equilibrium distribution coefficient\"进行文字解释和论述，答案提供了详细的定义和背景信息，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即平衡分布系数的定义和基本原理，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"equilibrium distribution coefficient\"的定义及其在特定条件下的应用，涉及基础概念的记忆和简单描述，但不需要复杂的体系阐述或多概念交叉分析。这符合等级2对概念解释和描述的要求，比单纯的定义简答（等级1）稍复杂，但未达到需要系统阐述多个相关概念的等级3难度。" + }, + { + "idx": 1211, + "question": "What is the physical meaning of the equilibrium partition coefficient?", + "answer": "This parameter reflects the partition coefficient of solute between solid and liquid phases and the degree of influence of solute on the alloy's melting point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释平衡分配系数的物理意义，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查平衡分配系数的物理意义这一基本概念的理解，属于定义和基本原理的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释平衡分配系数的物理意义，这需要学生理解并描述该参数在材料科学中的具体含义和作用，但不需要进行复杂的体系阐述或多概念整合。该难度高于简单定义复述（等级1），但低于需要深入分析或综合多个概念的题目（等级3）。" + }, + { + "idx": 1215, + "question": "Why is carburization chosen in γ-Fe around 930‰, where the diffusion coefficient increases with carbon content?", + "answer": "In γ-Fe, the diffusion coefficient increases with carbon content", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在γ-Fe中碳含量增加时扩散系数会增加，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要解释为什么在γ-Fe中碳含量增加时扩散系数增大，并选择特定的温度（930‰）进行渗碳处理。这涉及到扩散机制的理解、碳含量对扩散系数的影响以及温度选择的综合考虑，属于复杂分析和机理解释的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求对γ-Fe中碳扩散系数随碳含量变化的机理进行深度解释，需要综合运用材料科学和扩散理论的知识，分析碳化处理的温度选择与扩散行为的关系。虽然不涉及多因素交互作用的全面分析，但对单一现象的机理解释要求较高，属于机理深度解释的难度等级。" + }, + { + "idx": 1216, + "question": "Why can a larger concentration gradient be formed in γ-Fe near 930‰ during carburization?", + "answer": "A larger concentration gradient can be formed", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在特定条件下会形成更大的浓度梯度，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释在特定温度下γ-Fe中形成较大浓度梯度的原因，这需要综合运用扩散理论、相图知识以及温度对扩散系数的影响等多方面知识，并进行推理分析。涉及的知识点较为复杂且关联度高，思维过程需要深入分析和解释机理。 | 难度: 在简答题-复杂分析题型中，该题目要求对γ-Fe在特定温度下的碳浓度梯度形成机理进行深度解释。需要综合运用相变理论、扩散动力学和热力学知识，分析温度对碳溶解度及扩散速率的影响机制。虽然不涉及多因素交互作用的全面分析（等级5要求），但已超出基础概念解释层面，属于需要机理深度解释的等级4难度。" + }, + { + "idx": 1217, + "question": "Why does metal slip occur on the closest-packed planes and directions?", + "answer": "The slip in metal crystals occurs on the closest-packed planes and directions under external force because the atomic spacing is the smallest and the bonding force is the strongest on these planes, while the distance between two adjacent closest-packed planes is the largest and the bonding force is the weakest. It can be inferred that the resistance to slip is the smallest between the closest-packed atomic planes, requiring the least external force. Therefore, the closest-packed atomic planes and directions become the slip planes and slip directions for crystal slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属滑移发生在最密排面和方向的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属滑移在最密排面和方向上发生的原因，涉及原子间距、键合力以及滑移阻力的综合分析。需要理解晶体结构、原子间相互作用以及外力作用下的行为机制，属于对材料科学原理的深入理解和推理分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释金属滑移发生在最密排面和方向的原因，需要综合运用晶体结构、原子间作用力等知识进行推理分析。虽然不涉及多个复杂现象的全面分析（等级5），但需要对金属滑移的微观机理有较深入的理解和解释能力，符合等级4的标准。" + }, + { + "idx": 1218, + "question": "Why is carburization performed in γ-Fe around 930‰, where the diffusion coefficient increases with temperature at high temperatures?", + "answer": "At high temperatures, the diffusion coefficient increases with temperature, so high temperatures are chosen. However, excessively high temperatures can cause significant grain growth in austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在γ-Fe中进行渗碳处理时选择930‰左右的温度，答案提供了文字解释和论述，说明高温下扩散系数增加但过高温度会导致晶粒粗化，属于需要文字解释的简答题类型。 | 知识层次: 题目要求解释在特定温度下进行渗碳的原因，涉及扩散系数与温度的关系以及晶粒生长的综合影响。这需要综合运用扩散理论、相变知识和材料性能变化的机理分析，属于复杂分析和推理的范畴。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释为什么在γ-Fe中进行渗碳处理时选择930‰左右的温度，并需要说明扩散系数随温度升高而增加的原因，同时还要考虑过高温度对奥氏体晶粒长大的影响。这需要综合运用扩散原理、相变知识和材料加工工艺的理解，进行多方面的推理分析。虽然不涉及最复杂的现象全面分析（等级5），但已经超出了基础概念解释的范畴，属于需要深入机理阐述的难度等级。" + }, + { + "idx": 1219, + "question": "Dislocations belong to crystal defects and also to line defects.", + "answer": "~\\\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Dislocations belong to crystal defects and also to line defects），并要求判断其正确性（答案：~\\\\surd~表示正确）。这是典型的判断题形式，不需要选择或计算，只需判断陈述的真伪。 | 知识层次: 题目考查对晶体缺陷分类的基本概念记忆，仅需判断位错是否属于线缺陷这一基础知识点，不涉及复杂分析或应用。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对晶体缺陷分类的记忆，只需判断\"位错属于晶体缺陷也属于线缺陷\"这一陈述是否正确，不需要进行复杂的概念理解或分析。这属于该题型中最基础的知识点考察。" + }, + { + "idx": 1220, + "question": "Peritectic transformation refers to the transformation in which a liquid phase interacts with a solid phase, enveloping the original solid phase to form another new solid phase.", + "answer": "~\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（包晶转变的定义），并要求判断其正确性（答案标记为正确符号~\\surd~），这符合判断题的特征 | 知识层次: 题目考查对包晶转变（peritectic transformation）这一基本概念的记忆和理解，属于定义性知识的判断，不涉及复杂分析或应用。 | 难度: 在判断题中属于中等难度，需要准确理解包晶转变的定义和过程，判断陈述是否正确。虽然涉及基础概念记忆，但需要对定义有较深入的理解才能正确判断。" + }, + { + "idx": 1221, + "question": "Materials with different crystal lattices have different slip systems, thus their tendency to deform also varies.", + "answer": "~\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个事实，并要求判断其正确性（答案标记为~\\surd~表示正确），符合判断题的特征。 | 知识层次: 题目考查晶体结构和滑移系统的基本概念记忆，属于基础知识的理解层面。 | 难度: 在判断题中属于中等难度，需要理解晶体结构和滑移系统的基本概念，并能够判断不同晶格结构对变形倾向的影响。虽然不涉及复杂概念的判断，但需要一定的概念理解能力。" + }, + { + "idx": 1222, + "question": "The higher the dislocation density, the larger the Burgers vector of the corresponding dislocation.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案形式为\"~\\\\times~\"表示错误，符合判断题的特征 | 知识层次: 题目考查对位错密度和伯格斯矢量这两个基本概念的理解，属于基础概念的记忆和简单关联判断，不需要复杂的分析或综合应用。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆并理解位错密度与伯格斯矢量的基本关系即可作答，无需复杂推理或概念交叉分析。" + }, + { + "idx": 1223, + "question": "Generally, the higher the activation energy for atomic diffusion in a crystal, the larger the diffusion coefficient and the faster the diffusion rate.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案标记为~\\\\times~表示错误），符合判断题的特征 | 知识层次: 题目考查对原子扩散激活能与扩散系数之间关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解激活能与扩散系数之间的关系，而不仅仅是记忆基本定义。虽然题目涉及的是基础概念，但需要对概念之间的相互作用有一定的理解才能正确判断。" + }, + { + "idx": 1224, + "question": "Stacking faults result from the local presence of an extra half atomic plane in the crystal lattice.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（~\\\\times~表示错误），符合判断题的特征 | 知识层次: 题目考查堆垛层错的基本概念，属于晶体缺陷的基础知识，主要测试对定义的理解和记忆。 | 难度: 在判断题中属于中等难度，虽然考察的是基础概念记忆，但需要理解\"堆垛层错\"的定义及其形成机制（额外半原子面的存在），比单纯记忆定义类判断题（等级1）要求更高的概念理解深度。" + }, + { + "idx": 1225, + "question": "Metal solidification occurs through two processes: nucleation of the solid phase and grain growth. During the grain growth process, the liquid-solid interface of pure metals (such as Fe, Ni, Cu, Au, etc.) generally remains smooth.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个关于金属凝固过程中液固界面特性的观点，并要求判断其正确性（答案标记为~\\\\times~表示错误），符合判断题的特征。 | 知识层次: 题目考查对金属凝固过程中液固界面形态的基础概念记忆，属于基本原理的记忆性知识，无需复杂分析或计算。 | 难度: 在判断题中属于中等难度，需要理解金属凝固过程中的基本概念（成核和晶粒生长）以及纯金属液固界面的特性。虽然题目涉及的是基础概念，但需要对\"纯金属液固界面通常保持平滑\"这一具体现象有准确记忆和理解，比单纯判断定义正误（等级1）要求更高，但又不涉及复杂概念的组合判断（等级3）。" + }, + { + "idx": 1226, + "question": "Non-equilibrium crystallization refers to the crystallization of an alloy under actual cooling conditions where the cooling rate is relatively high, deviating from equilibrium conditions. Under non-equilibrium conditions, the composition of the newly formed solid solution after a homogeneous transformation is inhomogeneous.", + "answer": "~\\\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案使用了判断题的标记符号~\\\\surd~），符合判断题的特征 | 知识层次: 题目考查非平衡结晶的基本概念和定义，属于基础概念的记忆和理解范畴。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对非平衡结晶这一基础概念的理解，需要判断在非平衡条件下形成的固溶体成分是否均匀这一具体陈述的正确性。虽然涉及专业术语，但属于材料科学基础概念的典型应用，不需要复杂的分析推理过程，符合等级2\"概念理解的对错判断\"的特征。" + }, + { + "idx": 1227, + "question": "What is the essential difference between recrystallization and secondary recrystallization?", + "answer": "Recrystallization refers to the process in which a cold-worked metal is heated to a certain temperature, and new distortion-free equiaxed grains are regenerated within the deformed structure, restoring the properties to the softened state before cold working. Secondary recrystallization refers to the phenomenon where, after recrystallization annealing, the metal is held at a higher temperature or for a longer time, causing a very few grains to rapidly consume other grains and grow, resulting in the entire metal being composed of a few exceptionally large grains that are tens to hundreds of times larger than those after recrystallization. The essential difference between the two: Recrystallization is a process of nucleation and growth, while secondary recrystallization is only a growth process. The driving force for recrystallization is stored energy, whereas for secondary recrystallization, it is interfacial energy. After recrystallization, strength and hardness decrease while plasticity and toughness increase, whereas after secondary recrystallization, the material's strength, plasticity, and toughness all decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两个概念之间的本质区别，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅要求解释recrystallization和secondary recrystallization的基本概念，还需要比较两者的本质区别，包括过程、驱动力和性能变化。这涉及到多个概念的关联和综合分析，超出了单纯记忆的范畴，属于中等应用层次。 | 难度: 在简答题中，该题目要求对再结晶和二次再结晶的本质区别进行多角度分析论述。不仅需要解释两者的定义和过程，还需要比较它们的驱动力、微观机制以及对材料性能的影响。这种综合分析的要求使得该题目在同题型内属于较高难度等级。" + }, + { + "idx": 1228, + "question": "Due to the varying degrees of tightness in the regular arrangement of atoms in different directions, the spacing between atoms and the bonding forces between them differ, resulting in different properties in different directions. Therefore, most metals and alloys also exhibit anisotropic characteristics.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个关于金属和合金各向异性特性的观点，并要求判断其正确性（答案标记为~\\\\times~，表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对金属和各向异性特性的基本概念的理解和记忆，不涉及复杂的应用或分析过程。 | 难度: 在判断题中属于中等难度，需要理解金属和合金的各向异性特性及其原因，涉及原子排列紧密程度、原子间距和键合力的概念，但不需要进行复杂的分析或比较。" + }, + { + "idx": 1229, + "question": "Iron-carbon alloy equilibrium phase diagram: (1) Contains peritectic transformation. (2) Contains eutectic transformation. (3) Contains congruent transformation. (4) Contains monotectic transformation. (5) Contains precipitation transformation of solid solution.", + "answer": "(1)(2)(3)(5)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的陈述，答案是从(1)-(5)选项中选择正确的组合(1)(2)(3)(5)，符合选择题的特征 | 知识层次: 题目考查对铁碳合金平衡相图中不同类型相变的基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题中属于较高难度，需要考生对铁碳合金平衡相图中的多种相变类型（包晶、共晶、同成分、偏晶、固溶体析出）有深入理解，并能准确区分和识别这些概念。题目要求考生同时掌握多个相变类型的特征，并进行综合判断，属于复杂概念区分题。" + }, + { + "idx": 1230, + "question": "Solid-state diffusion: (1) The diffusion of iron atoms in steel belongs to self-diffusion and is unrelated to the concentration gradient. (2) The diffusion of alloying elements in steel belongs to hetero-diffusion; in the absence of a chemical gradient, it is related to the concentration gradient. (3) The first law of diffusion is only applicable to steady-state diffusion conditions, hence it cannot be used to accurately determine the diffusion coefficient of carbon during the carburization process of steel. (4) Up-hill diffusion is solely related to the chemical gradient of the diffusing element and is unrelated to the concentration gradient. (5) The multiplication of dislocations is achieved through the diffusion movement of atoms.", + "answer": "(1)(4)(5)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目给出多个陈述，要求判断哪些陈述是正确的（即(1)(4)(5)），这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目涉及扩散类型的区分（自扩散与异扩散）、扩散定律的适用条件以及上坡扩散的机制，需要理解多个概念并进行关联分析。虽然不涉及复杂计算，但需要对扩散理论有较深入的理解和综合判断能力。 | 难度: 在判断题题型中，该题目属于综合分析结果判断难度。题目涉及多个扩散相关概念的判断（自扩散、异扩散、扩散第一定律、上坡扩散、位错增殖机制），需要考生综合运用扩散理论知识，对5个独立陈述进行正误分析。不仅需要理解每个概念的定义和适用条件，还需要判断概念之间的关联性（如浓度梯度与化学梯度的区别），并识别题目中设置的干扰项（如第3条对扩散定律适用条件的误导性表述）。这种需要同时处理多个概念关联和综合分析判断的题目，在同题型中属于较高难度层级。" + }, + { + "idx": 1231, + "question": "Steel with a carbon content below the composition of point $S$ in the Fe-C phase diagram cannot obtain a completely pearlitic structure under any composition or condition.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目需要理解Fe-C相图中点S的含义，并分析不同碳含量下钢的组织转变可能性，涉及相图知识的应用和综合分析能力 | 难度: 在判断题中属于较高难度，需要综合分析Fe-C相图中点S的含义、珠光体形成的条件以及碳含量对相变的影响。题目涉及多步概念关联和综合分析，要求考生不仅理解相图的基本知识，还需要判断在不同碳含量和条件下能否获得完全珠光体结构。这比单纯判断单一概念的正误（等级3）更为复杂，但尚未达到需要复杂推理过程（等级5）的程度。" + }, + { + "idx": 1232, + "question": "Austenite in steel: \\n\\n(1) Can be represented as a $\\upgamma$-solid solution with dissolved carbon atoms. \\n\\n(2) Can be represented as an $\\alpha$-solid solution with dissolved carbon atoms. \\n(3) Exhibits good plasticity both at room temperature and high temperatures. \\n(4) Has ferromagnetism. \\n(5) Has paramagnetism.", + "answer": "(1) (3)(5)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案形式为选择特定编号的选项 | 知识层次: 题目考查对奥氏体（Austenite）基本特性的记忆和理解，包括其晶体结构（γ-固溶体）、塑性特性以及磁性特征。这些都属于材料科学中的基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度。题目考察对奥氏体基本特性的记忆和理解，需要区分γ固溶体和α固溶体的概念，并了解其磁学性质。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析推理。相比简单识别类题目(等级1)需要更深一层的概念理解，但尚未达到需要综合多个复杂概念的等级3难度。" + }, + { + "idx": 1234, + "question": "Fracture characteristics of metals: (1) One form of brittle fracture is transgranular cleavage. (2) Cleavage fractures mainly exhibit river patterns. (3) The propagation direction of micro-cracks can be determined by the flow direction of the rivers, i.e., the convergence direction of the rivers indicates the crack propagation direction. (4) Some materials exhibit tongue patterns in their ductile fracture surfaces. (5) Ductile fractures mainly manifest as intergranular dimple fracture forms.", + "answer": "(2) (3) (5)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出多个陈述句，要求判断哪些陈述是正确的（即选择正确的陈述作为答案）。这符合判断题的特征，即判断给定陈述的真伪。 | 知识层次: 题目考查金属断裂特征的基础概念记忆，包括脆性断裂和韧性断裂的形貌特征及其判断标准，属于定义和分类的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目涉及金属断裂特性的多个基本概念，如脆性断裂的穿晶解理、解理断裂的河流花样、微裂纹扩展方向的判断以及韧性断裂的韧窝形貌等。虽然这些概念属于基础记忆性知识，但需要考生对断裂特征有较为准确的理解才能正确判断陈述的对错，特别是关于河流花样与裂纹扩展方向关系的判断(3)和韧性断裂主要表现形式的判断(5)需要更深一层的理解。因此该题在同题型内属于中等难度(等级2)。" + }, + { + "idx": 1235, + "question": "The typical coordination numbers for metal crystal structure types are (4), (5), and (6)", + "answer": "(4) 12; (5) 8; (6) 12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值作为答案，而不是从给定的选项中选择或判断对错。虽然答案简短，但需要根据知识记忆或理解来填写具体数值，符合简答题的特征。 | 知识层次: 题目考查金属晶体结构中配位数的基本概念记忆，属于对基础知识的直接回忆和简单理解。 | 难度: 在简答题题型中，该题目仅要求记忆金属晶体结构的典型配位数，属于基础概念记忆层面的简单回答。题目不涉及概念解释或复杂体系阐述，仅需直接回忆并填写数字，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1236, + "question": "In polycrystals, grain boundaries are classified into large-angle and small-angle grain boundaries. What is the meaning of the angle?", + "answer": "The misorientation between adjacent grains", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"angle\"的含义进行文字解释和论述，答案是一个定义性的陈述，不需要计算或选择 | 知识层次: 题目考查对晶界角度定义的基本概念记忆和理解，属于材料科学中晶体结构的基础知识 | 难度: 在简答题题型中，该题目仅要求回答基本定义（晶界角度的含义），属于最基础的概念记忆层面。不需要解释或描述相关概念，更不需要阐述复杂体系。同类题型中，这属于只需直接回忆教材定义的简单问题。" + }, + { + "idx": 1237, + "question": "What are the types of small-angle grain boundaries classified according to their characteristics?", + "answer": "Twist, tilt, and coincidence", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释小角度晶界的分类类型，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对小角度晶界分类的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目仅要求列举小角度晶界的分类类型（Twist, tilt, and coincidence），属于基础概念记忆层面的直接问答。不需要进行概念解释或复杂体系阐述，符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单的直接回忆型问题。" + }, + { + "idx": 1238, + "question": "In polycrystals, grain boundaries are divided into large-angle and small-angle grain boundaries. What is the typical identification angle for distinguishing between large-angle and small-angle grain boundaries?", + "answer": "10°", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（10°），不需要从多个选项中选择，也不需要计算或判断对错，属于简答题类型。 | 知识层次: 题目考查对晶界分类的基本概念的记忆，即大角度晶界和小角度晶界的区分标准，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基础概念记忆类问题，仅需回答一个具体的角度数值（10°）来区分大角度和小角度晶界。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。这类问题在简答题中是最基础的类型，只需记忆关键数值即可作答。" + }, + { + "idx": 1239, + "question": "When an embryo appears in an undercooled liquid, what can the total free energy change ΔG be written as?", + "answer": "ΔG=VΔGV+σS", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出自由能变化的表达式，需要文字解释和公式应用，属于需要简要回答的问题 | 知识层次: 题目要求写出总自由能变化的表达式，涉及基本公式的应用，属于直接套用公式的简单应用层次。虽然需要理解自由能变化的概念，但不需要多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述，题目要求直接写出总自由能变化的表达式，涉及基本公式的直接套用，不需要复杂的解释或实例说明。解题步骤简单，仅需回忆并写出公式即可，对知识点的掌握深度要求较低。" + }, + { + "idx": 1240, + "question": "What does the size of the critical nucleus radius depend on?", + "answer": "ΔGV and σ", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释临界核半径大小依赖于哪些因素，答案给出了具体的依赖因素（ΔGV and σ），这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查临界核半径大小的基本概念，仅需要记忆和理解ΔGV（体积自由能变化）和σ（表面能）这两个基本参数对临界核半径的影响，不涉及复杂的应用或分析过程。 | 难度: 在简答题-基础概念记忆题型中，该题目仅要求回答临界核半径尺寸的两个依赖因素(ΔGV和σ)，属于最基本的概念要素回忆，不需要任何解释或论述。这完全符合等级1\"基本定义简答\"的标准，是同类题型中最基础的知识点再现要求。" + }, + { + "idx": 1241, + "question": "When dΔG/dr=0, what is the obtained 'r' value called?", + "answer": "Critical nucleus radius", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释特定概念（critical nucleus radius），需要文字回答而非计算或选择 | 知识层次: 题目考查对临界核半径这一基本概念的记忆和理解，属于材料科学中相变理论的基础知识点，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求回答一个特定的术语\"Critical nucleus radius\"，属于基础定义简答。题目不需要解释或描述概念，更不需要复杂概念体系的阐述，仅需记忆性知识即可回答。因此在该题型和知识层次下属于最低难度等级。" + }, + { + "idx": 1242, + "question": "What does a decrease in 'r' imply about the nucleation rate?", + "answer": "Increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"r\"减小对形核率的影响，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对成核速率与半径'r'关系的基本概念理解，属于基本原理的记忆性知识 | 难度: 在简答题题型中，此题属于基本定义简答级别。题目仅要求回答\"r\"减小对形核率的影响，属于单一概念的直接应用，不需要解释或论述复杂关系。在基础概念记忆层次中，这是最基础的知识点回忆型问题，解题步骤简单直接。" + }, + { + "idx": 1243, + "question": "According to the phase rule, what is the maximum number of equilibrium phases in a binary system?", + "answer": "17", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律解释二元系统中最大平衡相数，需要理论知识的文字解释和论述，答案形式为具体数值但需要理论支持。 | 知识层次: 题目考查对相律这一基本原理的记忆和理解，属于基础概念层面的知识。虽然涉及二元系统，但只需要直接应用相律公式F=C-P+2即可得出最大平衡相数，不需要复杂的计算或分析过程。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并复述相律在二元系统中的具体数值（F=C-P+2，当自由度F=0时P=4），无需解释概念或进行复杂推导。题目直接考察基础概念的记忆性知识，属于该题型内最低难度层级。" + }, + { + "idx": 1244, + "question": "According to the phase rule, what is the degree of freedom when the number of equilibrium phases in a binary system is at its maximum?", + "answer": "18", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目涉及相律的应用，需要根据给定的条件（二元系统中平衡相的最大数量）进行计算以确定自由度。答案是一个具体的数值（18），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目考查相律公式的直接应用，需要理解相律的基本概念并进行简单的数值计算，属于基本公式应用和简单计算范畴。 | 难度: 在计算题中属于最简单难度，只需直接套用相律公式F=C-P+2（其中C=2，P=3）即可得出自由度F=1。题目明确给出了二元系统（C=2）和最大平衡相数（P=3）的条件，计算过程仅涉及单一公式的直接代入，无需任何推导或复杂计算步骤。" + }, + { + "idx": 1245, + "question": "What is the movement of an edge dislocation on the slip plane called?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述，答案是一个简短的术语，没有提供选项或需要判断对错，也不需要数值计算。 | 知识层次: 题目考查对位错运动基本概念的记忆和理解，属于材料科学中基础的定义性知识 | 难度: 在简答题题型中，该题目仅要求回答边缘位错在滑移面上的运动名称，属于最基本的概念记忆性知识，无需解释或论述复杂概念体系，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1246, + "question": "According to the phase rule, what is the maximum number of equilibrium phases in a binary system represented on the phase diagram?", + "answer": "19", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据相律解释二元系统中平衡相的最大数量，需要理论知识的文字解释和论述，答案是一个具体的数值（19），但解答过程需要理论推导而非单纯计算或选择。 | 知识层次: 题目考查对相律这一基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要理解相律的基本概念并应用到二元系统中，但不需要复杂的推导或阐述多个相关概念体系。" + }, + { + "idx": 1247, + "question": "What is the movement of an edge dislocation perpendicular to the slip plane called?", + "answer": "Climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述特定概念（边缘位错垂直于滑移面的运动），答案是一个专业术语（Climb），不需要选择或判断，也不需要计算。 | 知识层次: 题目考查对位错运动基本概念的记忆和理解，特别是边缘位错垂直于滑移面运动的特定术语\"climb\"。这属于基础概念记忆范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，此题仅要求回答边缘位错垂直于滑移面运动的名称（攀移），属于最基础的定义简答。不需要解释概念或阐述复杂体系，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要描述位错运动机制（等级2）或分析攀移的原子尺度过程（等级3）要简单得多。" + }, + { + "idx": 1249, + "question": "What are the usual slip planes for face-centered cubic metals?", + "answer": "{111}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答面心立方金属的常见滑移面，答案需要提供具体的晶面指数{111}，属于需要简短回答的简答题类型。 | 知识层次: 题目考查对面心立方金属滑移面的基本概念记忆，属于晶体结构的基础知识范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答面心立方金属常见的滑移面，属于最基础的定义性知识，不需要额外的解释或论述。在基础概念记忆层次中，这是最简单的直接回忆型问题，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1252, + "question": "Under what conditions is the first law of diffusion only applicable?", + "answer": "Steady state", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释在什么条件下第一扩散定律适用，需要文字解释和论述，答案形式为简短的文字描述而非选择、判断或计算。 | 知识层次: 题目考查对扩散第一定律适用条件的基本概念记忆和理解，属于基础知识的直接应用 | 难度: 在简答题题型中，该题目仅要求回答\"稳态\"这一基本定义，属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这是最直接、最简单的回答要求。" + }, + { + "idx": 1253, + "question": "What is the relationship between diffusion flux and concentration gradient?", + "answer": "Proportional", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散通量与浓度梯度之间的关系，答案需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查扩散通量与浓度梯度关系的基本概念记忆，属于菲克第一定律的基础知识，不需要复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答扩散通量与浓度梯度之间的基本关系（正比关系），属于最基础的定义性知识回答。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最基础、最简单的难度级别。" + }, + { + "idx": 1254, + "question": "What is the basic condition expressed by the first law of diffusion?", + "answer": "dc/dt=0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第一扩散定律的基本条件，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对扩散第一定律基本条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题仅要求回答扩散第一定律的基本条件表达式，属于最基础的定义性知识。不需要进行概念解释或复杂阐述，只需准确记忆并写出公式dc/dt=0即可。符合等级1\"基本定义简答\"的标准，是该题型内最简单的难度级别。" + }, + { + "idx": 1255, + "question": "What is the direction of diffusion flow from what concentration to what concentration?", + "answer": "From high concentration to low concentration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释扩散流动的方向和浓度关系，答案是一个简短的文字描述而非选择、判断或计算 | 知识层次: 题目考查扩散方向的基本概念记忆，仅需回答从高浓度到低浓度的简单原理，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答扩散流动的基本方向，属于最基础的定义性知识。不需要解释或描述概念，更不需要构建复杂的概念体系。只需记忆并复述\"从高浓度到低浓度\"这一基本事实即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1257, + "question": "What is annealing twin? Explain its formation mechanism.", + "answer": "Annealing twin is a type of twin, which refers to the formation of lamellar twins with straight interfaces inside grains after cold deformation and recrystallization annealing in certain face-centered cubic metals, such as Cu, Ni, nickel alloys, and austenitic steels. These twin interfaces are on the {111} planes. Since they appear only after annealing, they are called annealing twins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释\"annealing twin\"的概念及其形成机制，需要详细的文字解释和论述，符合简答题的特征。答案提供了完整的定义和形成过程说明，没有涉及选择、判断或计算。 | 知识层次: 题目不仅要求解释退火孪晶的定义，还需要阐述其形成机制，涉及材料科学中的晶体结构、变形和再结晶过程等复杂概念的综合理解和分析。 | 难度: 在简答题中属于机理深度解释难度，需要准确描述退火孪晶的定义并详细解释其形成机制，涉及晶体结构、冷变形和再结晶过程等复杂概念的综合运用。虽然不需要进行多因素交互作用的全面分析，但对材料科学基础知识的掌握和机理阐述能力要求较高。" + }, + { + "idx": 1258, + "question": "What is the kinking mechanism in the analysis of the mechanisms and manifestations of plastic deformation in materials?", + "answer": "When a crystal can neither slip nor undergo twinning, it can undergo plastic deformation through kinking. Its characteristic is that the orientation of the kinked crystal undergoes asymmetric changes. The dislocation mechanism refers to the process where, during plastic deformation, edge dislocations of the same sign accumulate in other regions due to dislocation motion. The convergence of dislocations generates bending stress, causing the crystal lattice to bend and kink, thereby forming a kinked region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释kinking机制在材料塑性变形中的表现和作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释kinking机制在材料塑性变形中的作用和表现，涉及晶体变形机制、位错运动和应力分析等多个复杂概念的综合运用和推理分析。需要深入理解位错机制与晶体变形的关系，并进行机理的解释，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对塑性变形中的kinking机制进行全面分析，涉及晶体取向变化、位错运动、应力产生等多重机理的综合解释。需要深入理解位错理论并能系统阐述复杂变形现象的因果关系，属于该题型下最高难度的全面分析类问题。" + }, + { + "idx": 1260, + "question": "What is the slip mechanism in the analysis of the mechanisms and manifestations of plastic deformation in materials?", + "answer": "Slip is the relative movement of a crystal along the slip direction on the slip plane under the action of shear stress. Its dislocation mechanism is as follows: Due to the periodicity of the crystal lattice structure, when a dislocation moves along the slip plane, the energy at the dislocation center also undergoes periodic changes, causing the dislocation movement to encounter lattice resistance. However, in actual crystals, at a certain temperature, when the dislocation line moves from an energy valley position to an adjacent energy valley position, it does not simultaneously overcome the energy peak along its entire length. With the assistance of thermal activation energy, part of it can overcome the peak first, while the dislocation line forms a dislocation kink. Subsequently, the movement of the dislocation, aided by the kinked dislocation line, can easily shift sideways, resulting in a significant reduction in the stress required for the entire dislocation line to slip. During the slip process, in addition to lattice resistance, the resistance generated by the interaction between dislocations, the kinks and jogs formed after dislocation intersections, and the resistance caused by interactions between dislocations and other crystal defects all contribute to resistance, leading to crystal strengthening during slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释滑移机制及其在塑性变形中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释滑移机制及其在塑性变形中的作用，涉及晶体结构、位错运动、能量变化、热激活能等多个复杂概念的关联和综合分析。需要深入理解位错运动的机理，并能解释滑移过程中的各种阻力来源及其对晶体强化的影响，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对滑移机制进行全面的机理解释和综合分析。需要深入理解晶体结构、位错运动、能量变化、热激活等多个复杂概念，并能将这些概念有机结合起来解释滑移过程中的各种现象。此外，题目还要求分析位错与其他晶体缺陷的相互作用及其对材料强化的影响，这需要更高层次的综合推理和分析能力。因此，在同题型内属于最高难度等级。" + }, + { + "idx": 1261, + "question": "What is the twinning mechanism in the analysis of the mechanisms and manifestations of plastic deformation in materials?", + "answer": "Twinning is a mode of plastic deformation that occurs when a crystal cannot undergo slip. It also involves the relative motion of the crystal along the twinning direction and twinning plane under shear stress. The difference from slip is that twinning is a uniform shear deformation, and the two parts of the twin crystal form a mirror-symmetric relationship. The dislocation mechanism lies in the fact that after the sliding of a partial dislocation in the crystal, parallel and adjacent crystal planes undergo stacking faults, resulting in the formation of a twin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述孪生机制在材料塑性变形中的作用和表现，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释孪生机制在材料塑性变形中的作用和表现，涉及晶体变形机制、位错运动、堆垛层错等复杂概念的综合分析和关联。需要深入理解孪生与滑移的区别，以及孪晶形成的微观机理，属于对材料变形机制的深度解释和分析。 | 难度: 在简答题题型中，该题目要求对孪生机制进行深度解释，涉及晶体塑性变形的复杂机理，包括孪生方向、孪生平面的相对运动，以及与滑移的区别。此外，还需要解释位错机制和堆垛层错的形成，这些都需要综合运用材料科学的知识进行推理分析。虽然题目没有要求全面分析所有可能的复杂现象，但对机理的解释深度和完整性要求较高，因此属于等级4。" + }, + { + "idx": 1264, + "question": "What is a twin crystal? Explain its formation mechanism.", + "answer": "A twin crystal refers to two crystals (or two parts of one crystal) forming a mirror-symmetric orientation relationship along a common crystal plane, and these two parts are called twin crystals. The formation of twin crystals is due to uniform shear occurring throughout the twin region during twinning deformation, where the relative displacement of each crystal layer is caused by the movement of a partial dislocation. Taking face-centered cubic crystals as an example, the formation of twin crystals requires the generation of stacking faults. For instance, face-centered cubic crystals are stacked in the order of ABCABC··· on the 111 plane, which can be represented as △△△△△⋯. If the stacking sequence is reversed starting from a certain layer, becoming ABCACBACBA·.……., i.e., △△△∇∇∇∇⋯, the upper and lower parts of the crystal form a mirror-symmetric twin relationship. It can be observed that the ···CAC part corresponds to a stacking fault, followed by stacking in the reversed order, which still belongs to the normal FCC stacking sequence but is exactly opposite to the sequence of the crystal part before the fault, thus forming a symmetric relationship. This process is caused by the movement of a partial dislocation (Shockley partial dislocation).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释双晶的定义及其形成机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释双晶的定义，还需要详细阐述其形成机制，包括剪切变形、部分位错的运动以及堆垛顺序的变化等复杂过程。这需要深入理解晶体结构和缺陷，并进行推理分析，属于综合运用和机理解释的层次。 | 难度: 在简答题题型中，该题目要求对双晶的形成机制进行深入解释，涉及晶体结构、堆垛顺序、部分位错运动等复杂概念的综合运用和推理分析。题目不仅要求描述双晶的定义，还需要详细阐述其形成过程中的微观机制，如面心立方晶体中的堆垛层错和Shockley部分位错的运动。这种对复杂现象的全面分析和机理解释，在简答题题型中属于最高难度等级。" + }, + { + "idx": 1265, + "question": "From the perspective of bonding, discuss why metals generally exhibit higher plasticity or ductility compared to inorganic non-metals.", + "answer": "The bonding in metallic materials is primarily metallic bonding, while transition metals exhibit a mix of metallic and covalent bonding. Inorganic non-metallic materials are mainly bonded through ionic and covalent bonds. Metallic bonding is characterized by electron delocalization, where free electrons can move throughout the crystal, giving the bond no saturation or directionality. Due to the absence of saturation and directionality, each atom can potentially bond with more atoms and tends to form low-energy close-packed structures. When metals undergo deformation under force, the relative positions of atoms change without breaking the metallic bonds, which grants metals excellent ductility. Ionic bonding involves ions as the bonding units, where the bond is maintained by electrostatic attraction between positive and negative ions. This bond is strong, making it difficult for free electrons to move. Covalent bonds are formed between two or more atoms with similar electronegativity through shared electron pairs. Each bond has a fixed orientation, coordination numbers are relatively small, and the bonds are strong. Shared electron pairs between adjacent atoms cannot move freely, giving covalent bonds directionality and saturation, which generally results in poor plasticity and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合角度讨论金属与无机非金属的塑性差异，需要详细的文字解释和论述，答案也呈现了较长的论述形式，符合简答题的特征。 | 知识层次: 题目要求从化学键的角度分析金属与无机非金属材料塑性差异的机理，涉及多种化学键特性的对比分析（金属键、离子键、共价键），需要综合运用材料科学和化学键理论的知识进行推理和解释，思维深度达到机理层面。 | 难度: 在简答题题型中，该题目要求从键合角度深入解释金属与无机非金属塑性差异的机理。需要综合运用金属键、离子键和共价键的特性知识，分析电子行为对材料宏观性能的影响，并建立键合特性与塑性表现之间的因果关系链。虽然不涉及多因素交叉分析（如温度/缺陷等），但对键合本质的理解深度和机理解释的完整性要求较高，属于机理深度解释级别。" + }, + { + "idx": 1269, + "question": "When a spherical embryo with radius r appears in an undercooled liquid, what is the critical nucleus radius?", + "answer": "-2σ/ΔGv", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算临界核半径，答案是一个公式表达式，需要通过材料科学中的相关公式进行计算得出结果 | 知识层次: 题目考查对临界核半径公式的直接应用，仅需套用给定公式进行计算，不涉及多步计算或复杂分析。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了临界核半径的公式（-2σ/ΔGv），只需要简单套用即可得出答案，不需要额外的公式组合或复杂的计算步骤。这符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 1270, + "question": "When a spherical crystal embryo with radius r appears in an undercooled liquid, what happens to the number of nucleation events as r* decreases?", + "answer": "Increases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释当球形晶胚半径r*减小时成核事件数量的变化情况，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目涉及晶体成核理论中临界半径(r*)的概念理解，需要将临界半径变化与成核事件数量建立关联。虽然不涉及复杂计算，但需要理解热力学驱动力与表面能之间的平衡关系，属于需要综合分析概念的中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求分析球形晶核半径r*减小时对形核事件数量的影响，需要理解形核理论中的临界半径概念及其与形核率的关系。解题步骤涉及概念关联和综合分析，但不需要多角度或深度关联性分析。因此，在简答题的框架内，该题目属于综合分析和说明的难度水平。" + }, + { + "idx": 1271, + "question": "The solubility of substitutional solid solutions is related to atomic size factor, (4), electron concentration factor, and (5).", + "answer": "4) electronegativity factor; (5) crystal structure factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分的内容，需要根据材料科学知识进行文字解释和补充，而不是从给定的选项中选择或进行数值计算。 | 知识层次: 题目考查对固溶体溶解度影响因素的基本概念记忆，包括原子尺寸因素、电负性因素、电子浓度因素和晶体结构因素等基础知识的掌握。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生回忆并填写两个与固溶体溶解度相关的因素（电负性因素和晶体结构因素），这需要考生对基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目对知识点的掌握要求稍高，但仍在基础概念记忆的范围内。" + }, + { + "idx": 1273, + "question": "The typical crystal structure types of metals are fcc, bcc, and hcp, with coordination numbers of (1), (2), and (3) respectively.", + "answer": "(1) 12; (2) 8; (3) 12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值作为答案，而不是从给定的选项中选择或判断对错，也不需要复杂的计算过程。虽然答案简短，但属于填空题类型，更接近简答题的范畴。 | 知识层次: 题目考查金属典型晶体结构类型及其配位数的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答类型。题目仅要求记忆金属晶体结构类型及其配位数，不需要进行概念解释或复杂体系阐述。知识点掌握深度要求低，解题步骤简单，仅需直接回忆并填写数字答案，符合等级1的基本定义简答特征。" + }, + { + "idx": 1274, + "question": "When a spherical embryo with radius r appears in an undercooled liquid, what is the critical nucleation work?", + "answer": "-1/3σS = 16πσ³/3ΔGv²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算临界成核功，答案是一个具体的公式表达式，需要通过数值计算和公式应用来解答。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界成核功的计算方法，并综合运用表面能和体积自由能变化的概念。虽然公式可以直接套用，但需要理解其物理意义和推导过程，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解临界成核功的概念，应用表面能和体积自由能变化的公式，并进行多步推导和计算。虽然涉及多个物理量的关联，但计算步骤相对明确，没有过于复杂的变量处理。" + }, + { + "idx": 1275, + "question": "Intermediate phase", + "answer": "Intermediate phase: Refers to a new phase formed by the interaction between alloy components when the solid solubility limit of the solid solution is exceeded. This phase has a lattice structure and properties completely different from any of the components and exhibits metallic characteristics. Since it is often located in the middle of the phase diagram, it is also called an intermediate phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Intermediate phase”进行文字解释和论述，答案提供了详细的定义和特性描述，符合简答题的特征。 | 知识层次: 题目考查对“中间相”这一基本概念的定义和特性的记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目要求对\"intermediate phase\"进行概念解释和描述，包括其形成原因、结构特性以及在相图中的位置等。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或多概念关联分析，属于中等难度的概念解释题。" + }, + { + "idx": 1276, + "question": "During the crystallization process of solid solution alloys, the laws of nucleation and grain growth are followed, but unlike pure metals, what additional fluctuation is required during nucleation?", + "answer": "composition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在固溶体合金结晶过程中，除了纯金属的成核和晶粒生长规律外，还需要什么额外的波动。答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对固溶体合金结晶过程中成核规律的理解，需要将纯金属的成核规律与固溶体合金的特殊性进行比较分析，涉及多概念关联和中等程度的综合分析能力。虽然不涉及复杂计算，但需要理解成分波动这一额外要求的内在机理。 | 难度: 在简答题中属于中等难度，需要理解固溶体合金结晶过程中的成核规律，并能指出与纯金属相比所需的额外成分波动。虽然涉及概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1277, + "question": "During the crystallization process of solid solution alloys, in what process does the composition fluctuation during nucleation occur?", + "answer": "Variable temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述结晶过程中成分波动的发生过程，答案形式为文字描述而非选择、判断或计算 | 知识层次: 题目涉及固溶体合金结晶过程中的成分波动现象，需要理解成核过程中的热力学和动力学机制，属于对材料科学中相变理论的深度理解和综合分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对固溶体合金结晶过程中的成分波动现象进行机理层面的深度解释。需要综合运用相变动力学、扩散理论和形核理论等知识，分析变温过程中成分波动的产生机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念描述，达到机理解释的深度要求，符合等级4的标准。" + }, + { + "idx": 1278, + "question": "What is the growth mode of crystals related to?", + "answer": "Interface structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目是一个开放式问题，要求解释晶体生长模式与什么相关，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查晶体生长模式与界面结构关系的基本概念记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目要求解释晶体生长模式与界面结构的关系，属于概念解释和描述的难度级别。虽然需要一定的专业基础知识，但不需要进行复杂的概念体系阐述或深入分析，因此属于中等难度。" + }, + { + "idx": 1279, + "question": "During the crystallization process of a solid solution alloy, what kind of diffusion is always accompanied?", + "answer": "Heterogeneous atoms (solute atoms)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释在固溶体合金结晶过程中伴随的扩散类型，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查的是对结晶过程中扩散类型的基础概念记忆和理解，属于材料科学中相变和扩散的基本原理范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（异质原子扩散），属于最基础的概念记忆层面，不需要解释或阐述复杂概念体系，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1280, + "question": "What is the crystal growth morphology related to?", + "answer": "Interface structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要文字解释和论述晶体生长形态与界面结构的关系，而不是从选项中选择或判断对错 | 知识层次: 题目考查晶体生长形态与界面结构关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答晶体生长形态与什么相关，答案只需给出\"界面结构\"这一基本概念即可，不需要进行额外的解释或论述。这属于最基础的概念记忆层次，在简答题中属于最简单的类型。" + }, + { + "idx": 1281, + "question": "The growth morphology of crystals is related to what distribution at the interface front?", + "answer": "Temperature gradient", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体生长形态与界面前沿分布的关系，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目考查晶体生长形态与界面前沿温度梯度分布的关系，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答晶体生长形态与界面前沿的温度梯度分布相关，属于基础概念的直接回忆和简答。不需要深入解释或复杂的概念体系阐述，符合等级1的基本定义简答标准。" + }, + { + "idx": 1283, + "question": "According to the phase rule, the maximum number of equilibrium phases when the degrees of freedom in a ternary system are zero is", + "answer": "4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目涉及相律的应用，需要根据给定的自由度条件（自由度为零）进行计算，得出最大平衡相数。答案是一个具体的数值（4），需要通过公式推导或计算得出。 | 知识层次: 题目考查相律公式的直接应用，仅需将自由度为零的条件代入公式计算最大平衡相数，属于基本公式套用和简单计算范畴 | 难度: 在计算题中属于最低难度，直接套用相律公式F=C-P+2（其中F为自由度，C为组分数，P为相数），题目已给出自由度F=0和组分数C=3，只需简单代入计算即可得出P=5。但题目答案给出的是4，说明可能存在对相律公式理解的偏差（如未考虑压力因素），不过就解题过程而言仍属于单一公式直接计算的简单题型。" + }, + { + "idx": 1284, + "question": "According to the phase rule, when the degrees of freedom in a ternary system are zero, it is represented on the phase diagram as", + "answer": "plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律知识进行概念性回答，需要用文字解释相图中自由度为零时的表示方式，答案\"plane\"是一个简短的描述性回答，符合简答题的特征。 | 知识层次: 题目考查对相律基础概念的记忆和理解，特别是关于自由度为零时在相图中的表示方式，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（相律在三元系统中的自由度为零时的相图表示），不需要进行概念解释或复杂体系阐述。属于最基础的定义简答级别，只需记忆性知识即可回答。" + }, + { + "idx": 1285, + "question": "When a single crystal undergoes plastic deformation, the common methods are (15), (16), and (17).", + "answer": "(15) Slip; (16) Twinning; (17) Kinking", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的变形方法名称，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对单晶塑性变形常见方法的基础概念记忆，仅需回答滑移、孪生和扭折这三个基本术语，无需深入解释或分析。 | 难度: 在简答题题型中，该题目仅要求回忆并列举单晶塑性变形的三种基本方法（滑移、孪生、扭折），属于最基础的定义性知识复现，无需解释或阐述概念间关系，符合等级1\"基本定义简答\"的标准。相比需要描述机制（等级2）或分析交互作用（等级3）的简答题，本题仅测试记忆准确度。" + }, + { + "idx": 1286, + "question": "The negative sign of the diffusion flux indicates that diffusion proceeds from high concentration to low concentration, and the driving force for diffusion in this process is (20)", + "answer": "Chemical potential gradient (chemical force)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散过程的驱动力，并给出了一个具体的答案（化学势梯度），这需要文字解释和论述，而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查扩散过程中驱动力的基本概念记忆，即化学势梯度（化学力），属于基础概念的记忆和理解层面。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目直接询问扩散过程的驱动力，答案\"Chemical potential gradient (chemical force)\"是基础概念记忆层面的内容，无需复杂解释或论述。同题型内相比，仅需回忆单一知识点即可作答，属于最基础的难度层级。" + }, + { + "idx": 1287, + "question": "After cold deformation, the control of grain size after recrystallization is related to the degree of cold deformation, original grain size, recrystallization temperature, and impurities, among others. Among these, what is (21)?", + "answer": "Degree of cold deformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的因素中选择一个特定的因素（degree of cold deformation），而不是从多个选项中选择或进行判断、计算。答案需要简洁的文字回答。 | 知识层次: 题目考查对冷变形后晶粒尺寸控制因素的基础概念记忆，仅需识别并回答\"Degree of cold deformation\"这一基本影响因素，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答\"degree of cold deformation\"这一单一因素，属于基本定义简答。题目没有要求解释或阐述多个概念之间的关系，也不需要复杂的分析过程，仅需记忆并识别关键因素即可。因此在该题型和知识层次下属于最简单的难度等级。" + }, + { + "idx": 1288, + "question": "The first law of diffusion applies to steady-state diffusion, and its mathematical expression can be written as (19)", + "answer": "J=-Ddc/dx", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出扩散第一定律的数学表达式，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查菲克第一定律的基本表达式，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，此题属于基本定义简答的难度等级。题目仅要求写出第一扩散定律的数学表达式，不涉及概念解释或复杂体系阐述。该知识点属于基础概念记忆层次，只需直接回忆公式即可完成作答，解题步骤简单，对能力要求较低。" + }, + { + "idx": 1289, + "question": "Dynamic recovery and dynamic recrystallization refer to deformation at high temperatures, where (18) occurs simultaneously during the deformation process.", + "answer": "(18) work hardening and softening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写一个术语（work hardening and softening）来补全句子，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查动态回复和动态再结晶的基本概念，属于高温变形过程中的基础现象记忆和理解 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生解释动态回复和动态再结晶的定义，并指出在高温变形过程中同时发生的现象（加工硬化和软化）。这需要考生对相关概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 1290, + "question": "After cold deformation, the control of grain size after recrystallization is related to the degree of cold deformation, original grain size, (22), and impurities, etc. What is (22)?", + "answer": "Recrystallization temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写一个特定的术语（Recrystallization temperature），属于需要文字回答的简答题类型，而非从选项中选择或判断对错。 | 知识层次: 题目考查的是对再结晶过程中影响晶粒尺寸因素的基本概念记忆，包括冷变形程度、原始晶粒尺寸、再结晶温度和杂质等。这属于基础概念的记忆和理解层次，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释和描述多个相关概念（冷变形程度、原始晶粒尺寸、再结晶温度、杂质等）之间的关系，但不需要进行复杂的体系阐述。" + }, + { + "idx": 1291, + "question": "When a crystal is subjected to external forces, the moving dislocations inside it will intersect, resulting in the formation of jogs and kinks. What is the length of these jogs and kinks the same as that of the intersecting dislocations?", + "answer": "The magnitude of the Burgers vector", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个具体的概念（The magnitude of the Burgers vector），而不是从多个选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查对位错运动中形成的jogs和kinks的基本概念的理解，特别是它们与Burgers矢量长度的关系。这属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释位错运动中形成的jogs和kinks的长度特征，需要理解并描述Burgers矢量的概念及其与位错几何特征的关系。虽然涉及基础概念的记忆，但需要将多个概念联系起来进行解释，比单纯复述定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1292, + "question": "If the slip of the jog is inconsistent with the slip of the main dislocation line, the main dislocation line will drag the jog to produce climb motion, resulting in what phenomenon?", + "answer": "Jog hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述一个现象（jog hardening），答案是一个术语，需要通过文字解释来理解其含义和背后的机制。 | 知识层次: 题目涉及位错运动中的复杂现象，需要理解位错与割阶的相互作用机制，并分析由此产生的攀移运动及其对材料性能的影响。这需要综合运用位错理论的知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解位错运动的基本概念，还需要分析位错线与jog之间的相互作用机制，以及由此产生的jog硬化现象。这需要综合运用位错理论、晶体缺陷动力学等知识，进行较为深入的机理解释，符合等级4的要求。" + }, + { + "idx": 1293, + "question": "What does secondary recrystallization conceptually refer to?", + "answer": "Secondary recrystallization refers to the phenomenon where, after recrystallization annealing, a metal subjected to higher temperatures or prolonged holding times experiences a few grains rapidly consuming other grains and growing, resulting in the entire metal being composed of a small number of exceptionally large grains that are tens to hundreds of times larger than the post-recrystallization grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“secondary recrystallization”进行概念性的解释，答案需要文字论述和详细说明，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶这一基础概念的定义和现象描述，属于记忆和理解层次的知识点，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释和描述一个具体的材料科学概念，但不需要涉及复杂的体系或深入的分析。题目要求对二次再结晶进行概念性描述，属于基础概念记忆的范畴，但需要一定的理解和表达能力来准确阐述现象。" + }, + { + "idx": 1294, + "question": "What does recrystallization conceptually refer to as a process?", + "answer": "Recrystallization refers to the process in which a substance transforms from one structure to another in the solid state, i.e., an allotropic transformation reaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对recrystallization的概念进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对再结晶这一基本概念的定义和简单解释，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对\"recrystallization\"这一概念进行基本定义简答，属于最基础的概念记忆层次。题目不涉及概念间的关联解释或复杂体系阐述，仅需直接复现教材中的定义性描述即可完成作答，符合等级1\"基本定义简答\"的标准特征。" + }, + { + "idx": 1295, + "question": "Why does pure metal grow in a planar manner during solidification under a positive temperature gradient?", + "answer": "During crystallization, the interface of pure metal is rough and grows under a positive temperature gradient. As the crystal grows, heat is dissipated through the solid mold wall, making the solid-liquid interface isothermal. If dynamic undercooling is achieved, the interface moves forward. If there is a small protrusion locally on the interface extending into the superheated liquid phase, the protrusion will be melted, so the interface remains straight; the crystal grows in a planar manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纯金属在正温度梯度下凝固时为何以平面方式生长，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要解释纯金属在正温度梯度下凝固时的平面生长机制，涉及界面粗糙度、热传导、动态过冷等概念的关联和综合分析，要求对凝固过程的机理进行深入理解和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对纯金属凝固过程中的界面行为进行机理深度解释。需要综合运用热力学、晶体生长理论等知识，分析温度梯度、界面粗糙度、动态过冷等多因素相互作用，并推导出平面生长模式的必然性。虽然不涉及多现象交叉分析（等级5特征），但已超出基础概念复述层面，属于典型的机理解释类难题。" + }, + { + "idx": 1297, + "question": "What are the differences in the nucleation and growth processes among recrystallization, primary recrystallization, and secondary recrystallization?", + "answer": "Recrystallization and primary recrystallization involve nucleation and growth processes; secondary recrystallization only involves a growth process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述不同再结晶过程中的成核和生长过程的差异，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目要求比较不同再结晶过程的成核和生长机制，涉及多个概念的关联和综合分析，需要理解并应用材料科学中的相变和再结晶原理，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对三种再结晶过程（再结晶、初次再结晶和二次再结晶）的成核和生长过程进行比较分析。这需要学生不仅理解每个过程的基本概念，还需要能够从多个角度（如成核机制、生长条件、微观结构变化等）进行综合论述。虽然题目没有要求深度关联性分析（如与材料性能的关系），但多角度的比较和分析已经超出了基础概念的记忆和简单解释，属于较高难度的简答题。" + }, + { + "idx": 1298, + "question": "Why do solid solution alloys usually grow in a dendritic manner during solidification under a positive temperature gradient?", + "answer": "During the crystallization of solid solutions, constitutional supercooling occurs, leading to a constitutionally supercooled zone ahead of the solid-liquid interface. If any small protrusion exists on the interface, it will extend into the constitutionally supercooled zone and continue to grow as it gains supercooling. Therefore, the interface cannot remain flat and stable, resulting in dendritic growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液合金在正温度梯度下凝固时通常以枝晶方式生长的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶体合金在正温度梯度下凝固时通常以枝晶方式生长的原因，涉及凝固过程中的成分过冷、固液界面稳定性以及枝晶生长的机理。这需要综合运用凝固理论、热力学和动力学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对固溶体合金凝固过程中的枝晶生长进行机理深度解释。需要综合运用凝固理论、成分过冷概念以及界面稳定性分析等知识，解题步骤涉及多个关键概念的串联和逻辑推理。虽然不涉及最复杂的多因素交互分析（如等级5要求的全面现象分析），但已超出基础概念复述层面，属于需要深入理解并整合专业知识的较高难度题目。" + }, + { + "idx": 1299, + "question": "Discuss the theory of grain refinement strengthening from the mechanism of plastic deformation in materials.", + "answer": "In the strengthening theories of materials, grain refinement strengthening is the only method that can simultaneously improve both the strength and toughness of materials. The specific explanation is as follows: Due to the fine grains, the slip planes available for dislocation pile-up are shorter, and the number of piled-up dislocations is smaller. The stress concentration caused by dislocation pile-up is dispersed among various grains, thereby increasing the yield strength. On the other hand, because the grains are fine, under the same external force, there are more grains in favorable slip directions, and the stress is distributed among the grains. Even under large plastic deformation, the material maintains its good performance without cracking, thus improving the toughness. In summary, grain refinement strengthening can enhance the comprehensive mechanical properties of materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论晶粒细化强化的理论，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从塑性变形机制的角度讨论晶粒细化强化的理论，涉及对位错堆积、应力集中、屈服强度和韧性等多方面概念的综合理解和分析。需要深入理解晶粒细化对材料力学性能的影响机制，并进行推理和解释，属于复杂分析的层次。 | 难度: 在简答题题型中，该题目要求对晶粒细化强化的机理进行深入解释，并综合运用塑性变形理论进行分析。题目不仅要求掌握晶粒细化对强度和韧性的影响机制，还需要理解位错堆积、应力分布等复杂现象，并进行全面的推理分析。这种综合运用和机理深度解释的要求，使得该题目在同题型内属于最高难度等级。" + }, + { + "idx": 1300, + "question": "What are the differences in the driving forces among recrystallization, primary recrystallization, and secondary recrystallization?", + "answer": "The driving force for recrystallization is the free energy difference between the new and old phases, for primary recrystallization it is the stored energy, and for secondary recrystallization it is the interfacial energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述不同再结晶过程的驱动力差异，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求区分三种再结晶过程的驱动力，涉及多个相关概念的关联和综合分析，需要理解不同再结晶过程的机制及其能量差异，属于中等应用层次。 | 难度: 在简答题题型内，该题目要求对三种再结晶过程的驱动力进行多角度分析论述。需要理解并区分自由能差、储存能和界面能等不同概念，并能够将这些概念与具体的再结晶过程关联起来。虽然不需要进行深度关联性分析（如与材料性能的关系），但已超出简单概念解释的范畴，属于需要综合分析和比较的中高难度题目。" + }, + { + "idx": 1301, + "question": "Why do metal crystals always slide along the slip plane and slip direction during the slip process?", + "answer": "The slip of metal crystals is the result of dislocation movement, and the dislocation movement is mainly subjected to the resistance of the crystal lattice. In the crystal, the greater the interplanar spacing between the densest atomic planes, and the smaller the atomic spacing in the most closely packed direction, the smaller the sliding resistance when dislocations slide along the slip plane and slip direction. Therefore, metal crystals always slide along the slip plane and slip direction during the slip process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属晶体在滑移过程中为何总是沿滑移面和滑移方向滑动，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属晶体滑移过程中沿特定滑移面和滑移方向的原因，涉及位错运动、晶格阻力、原子密排面和方向间距等概念的关联和综合分析，需要深入理解并解释其机理。 | 难度: 在简答题的复杂分析层次中，该题目要求对金属晶体滑移过程的机理进行深度解释，涉及位错运动、晶格阻力、原子面间距和方向等多方面知识的综合运用和推理分析。虽然题目没有要求对复杂现象进行全面分析，但对机理的解释深度和知识点的掌握要求较高，因此属于等级4难度。" + }, + { + "idx": 1302, + "question": "What are the differences in the effects of recrystallization and secondary recrystallization on material properties?", + "answer": "After recrystallization, strength and hardness decrease while plasticity and toughness improve; after secondary recrystallization, the material's strength, plasticity, and toughness all decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述再结晶和二次再结晶对材料性能的不同影响，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求比较两种再结晶过程对材料性能的影响，涉及多个性能指标的变化分析，需要理解再结晶和二次再结晶的基本原理，并将这些原理与材料性能变化关联起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对两种再结晶过程（再结晶和二次再结晶）对材料性能的影响进行多角度分析论述。需要考生不仅理解两种再结晶的基本概念，还需要综合分析它们对强度、硬度、塑性和韧性等不同性能的具体影响，并进行比较。这种题目要求考生具备较强的概念关联和综合分析能力，属于该题型中的较高难度等级。" + }, + { + "idx": 1303, + "question": "What is the structure of austenite?", + "answer": "Austenite: An interstitial solid solution of carbon in γ-Fe, with a face-centered cubic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释奥氏体的结构，答案提供了详细的文字描述和定义，符合简答题的特征 | 知识层次: 题目考查对奥氏体结构这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答奥氏体的基本定义和晶体结构，属于最基础的概念记忆性知识。不需要解释或阐述复杂概念体系，仅需直接回忆并陈述定义即可，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 1304, + "question": "What are the differences in the phase transformation processes among recrystallization, primary recrystallization, and secondary recrystallization?", + "answer": "Recrystallization involves a phase transformation process, while primary recrystallization and secondary recrystallization do not involve a phase transformation process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述不同再结晶过程之间的相变差异，答案需要文字描述和详细解释，而非选择、判断或计算。 | 知识层次: 题目要求比较三种再结晶过程的相变差异，涉及多个概念的关联和综合分析，需要理解并应用材料科学中的相变和再结晶知识，但不需要进行复杂的推理或创新应用。 | 难度: 在简答题中属于较高难度，需要综合分析和比较多个概念（recrystallization、primary recrystallization、secondary recrystallization），并准确说明它们在相变过程中的差异。题目要求不仅理解每个概念，还需要进行多角度的论述和比较，涉及中等应用层次的知识综合运用。" + }, + { + "idx": 1305, + "question": "What type of structure is cementite?", + "answer": "Cementite: an interstitial compound formed by iron and carbon, belonging to the orthorhombic system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释cementite的结构类型，答案提供了详细的文字描述和分类信息，属于需要文字解释的简答题类型 | 知识层次: 题目考查对渗碳体（cementite）这一基本概念的定义和分类的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答水泥体的基本定义和晶体结构分类，属于最基础的概念记忆层面。不需要解释或描述复杂关系，只需准确回忆并陈述定义性内容，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这属于直接调用记忆内容即可完成的题目类型。" + }, + { + "idx": 1306, + "question": "At room temperature, bending a lead plate makes it increasingly harder, but after some time, bending it again makes the lead plate as soft as it was initially. Why? Please explain this phenomenon.", + "answer": "At room temperature, bending a lead plate makes it increasingly harder due to work hardening, which increases the strength and hardness of the lead plate. After some time, because the melting point of lead is relatively low, recrystallization softening occurs at room temperature, causing its hardness to decrease again.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释一个现象，答案需要文字解释和论述，没有提供选项或要求计算。 | 知识层次: 题目要求解释一个涉及材料科学中变形和再结晶的复杂现象，需要综合运用工作硬化和再结晶软化的机理进行推理分析，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用材料科学中的工作硬化和再结晶软化机理，解释铅板在室温下弯曲后的硬度变化现象。需要深入理解金属塑性变形和回复过程的微观机制，并能将理论知识与实际现象联系起来进行推理分析。这种综合运用多个知识点解释复杂现象的要求，在该题型内属于最高难度等级。" + }, + { + "idx": 1307, + "question": "What kind of structure is ferrite?", + "answer": "Ferrite: an interstitial solid solution of carbon in α-Fe, with a body-centered cubic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对ferrite的结构进行文字解释和论述，答案提供了详细的描述，符合简答题的特征 | 知识层次: 题目考查对铁素体基本概念的记忆和理解，包括其定义和晶体结构类型，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答ferrite的基本定义和结构特征，属于最基础的概念记忆性知识。题目不涉及复杂解释或体系阐述，仅需直接回忆并复述教材中的基础定义即可完成作答，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 1308, + "question": "The solubility of substitutional solid solutions is related to atomic size factor, (1), electron concentration factor, and (2).", + "answer": "(1) electronegativity factor; (2) crystal structure factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写两个空缺的内容，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对固溶体溶解度相关因素的基础概念记忆，包括原子尺寸因素、电负性因素、电子浓度因素和晶体结构因素。这些都属于材料科学中固溶体的基本原理和分类知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生回忆并解释固溶体溶解度的相关因素，包括原子尺寸因素、电子浓度因素等，并补充缺失的两个因素。这需要考生对基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入的分析。因此，该题目在简答题题型中属于中等难度。" + }, + { + "idx": 1309, + "question": "A decrease in $r^{}$ means the number of nucleation sites (4).", + "answer": "increases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（increases）来完整句子，属于需要简短文字回答的简答题类型 | 知识层次: 题目考查的是对成核位点与半径关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答级别。题目仅要求回答\"r*减小意味着形核位点数量如何变化\"这一简单概念，不需要进行概念解释或复杂体系阐述。答案只需直接给出\"增加\"这个基础概念记忆即可，完全符合等级1对定义性知识点的考查要求。" + }, + { + "idx": 1310, + "question": "When a spherical embryo with radius $r$ appears in an undercooled liquid, the resulting critical nucleus radius is (3).", + "answer": "$\\\\frac{-2\\\\sigma}{\\\\Delta G_{V}}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式计算临界核半径，答案是一个具体的数学表达式，需要应用材料科学中的相关公式进行计算。 | 知识层次: 题目要求应用临界核半径的基本公式进行计算，属于直接套用公式的简单应用，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式$\\frac{-2\\sigma}{\\Delta G_{V}}$进行计算，无需任何变形或组合步骤。题目明确给出了公式编号(3)，属于典型的\"单一公式直接计算\"类型。" + }, + { + "idx": 1311, + "question": "Homogeneous nucleation of crystal nuclei relies on (5) providing atomic clusters with $r>r^{*}$ to act as nuclei.", + "answer": "Structural fluctuations", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体核均匀成核的机制，答案\"Structural fluctuations\"是一个概念性的文字解释，而非选择、判断或计算。这属于需要简要论述的简答题类型。 | 知识层次: 题目考查对均相成核过程中结构波动作用的基本概念记忆和理解，属于基本原理的记忆性知识 | 难度: 在简答题中属于基本定义简答，仅需回忆并准确写出\"Structural fluctuations\"这一术语即可完成作答，无需解释或展开论述。题目考查的是对均质形核基础概念的记忆能力，属于该题型下最基础的难度层级。" + }, + { + "idx": 1312, + "question": "Homogeneous nucleation of crystal nuclei relies on (6) to provide nucleation work equivalent to the interfacial energy (7).", + "answer": "energy fluctuation; 1/3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要填写特定的术语和数值，属于简答题类型，要求回答具体内容而非选择或判断 | 知识层次: 题目考查均相成核的基本概念，包括成核功和界面能的关系，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释均匀成核过程中能量波动的作用以及界面能的比例关系，这需要对基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 1313, + "question": "Dynamic recovery and dynamic recrystallization refer to the simultaneous occurrence of (15) during deformation.", + "answer": "(15) softening and strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语或短语来完整句子，而不是从多个选项中选择或进行判断、计算。答案需要简要的文字描述来补充完整句子。 | 知识层次: 题目考查动态回复和动态再结晶的基本概念，属于对材料变形过程中同时发生的软化与应变硬化现象的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求填写一个基本定义的关键词组合（softening and strain hardening），属于最基础的定义简答层级。题目没有要求解释动态回复和动态再结晶的机制或相互关系，仅测试对术语定义的记忆程度，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1314, + "question": "What kind of diffusion always accompanies the crystallization process of solid solution alloys?", + "answer": "Dissimilar atoms", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散类型与结晶过程的关系，答案需要文字说明而非选择或判断 | 知识层次: 题目考查对扩散类型在合金结晶过程中伴随现象的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，此题仅要求回答\"Dissimilar atoms\"这一基本定义，不需要进行概念解释或复杂体系阐述。属于最基础的定义简答级别，符合等级1的\"基本定义简答\"特征。题目直接考查学生对固态溶液合金结晶过程中伴随扩散类型的记忆，不涉及任何分析或推理过程。" + }, + { + "idx": 1315, + "question": "What mainly occurs during the high-temperature recovery of cold-worked metals?", + "answer": "Polygonization", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释高温恢复过程中主要发生的现象，答案需要提供文字解释而非选择或判断。 | 知识层次: 题目考查的是冷加工金属在高温回复过程中主要发生的现象（多边形化），属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释\"多边形化\"这一概念及其在金属高温回复过程中的作用，但不需要涉及复杂的概念体系或深入的分析。" + }, + { + "idx": 1316, + "question": "What is the main phenomenon during the low-temperature recovery of cold-worked metals?", + "answer": "The disappearance of point defects", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释低温回复冷加工金属的主要现象，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查冷加工金属低温回复过程中的主要现象，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答低温回复过程中的主要现象，属于基础概念的直接回忆。不需要进行概念解释或复杂体系阐述，仅需记忆\"点缺陷消失\"这一基本定义即可作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1320, + "question": "During the plastic deformation of metals, after twinning occurs, the crystal orientations on both sides of the twin plane exhibit (11), and the crystal undergoes (12) shear.", + "answer": "(11) symmetric relationship; (12) uniform", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定的术语（symmetric relationship; uniform）来完成句子，属于需要简短文字回答的题目类型，不需要从多个选项中选择或进行判断、计算。 | 知识层次: 题目考查金属塑性变形中孪晶现象的基本概念，包括孪晶面两侧晶体取向的对称关系和均匀剪切的特征，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答的是金属塑性变形中孪晶现象的两个基本特征（对称关系和均匀剪切），这些都是基础概念的记忆性知识，不需要深入的解释或复杂的论述。同题型内相比，该题目仅需直接回忆和复述定义，不涉及概念间的联系或体系化阐述，因此属于最低难度等级。" + }, + { + "idx": 1321, + "question": "Briefly describe the growth mechanism of pure metal crystals and its relationship with the microstructure of the solid/liquid interface.", + "answer": "The solid/liquid interface of pure metal crystals is generally a rough interface. Therefore, for pure metal crystals, during the growth process, they usually grow according to the vertical growth mode of the rough interface. Since nearly $50\\\\%$ of the positions on the interface are vacant, the addition of liquid-phase atoms is not restricted by position, which facilitates continuous filling of atoms, thereby enabling the solid/liquid interface to grow rapidly along the normal direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述纯金属晶体的生长机制及其与固/液界面微观结构的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释纯金属晶体的生长机制及其与固/液界面微观结构的关系，涉及对界面粗糙度、原子填充过程和生长模式的综合分析。这需要深入理解晶体生长机理，并能将微观结构与宏观生长行为联系起来，属于对复杂机理的解释和分析。 | 难度: 在简答题中属于机理深度解释难度等级。题目要求描述纯金属晶体的生长机制及其与固/液界面微观结构的关系，涉及对粗糙界面垂直生长模式的理解，以及原子填充过程的解释。虽然不需要全面分析复杂现象，但需要对晶体生长机理有较深入的理解和清晰的论述能力。" + }, + { + "idx": 1324, + "question": "Dendritic segregation", + "answer": "Dendritic segregation: It is a type of microsegregation in materials, where under non-equilibrium cooling conditions, the newly formed solid solution grains after a homogeneous transformation exhibit non-uniform composition within. The initially crystallized core contains more high-melting-point component atoms, while the later crystallized outer regions contain more low-melting-point component atoms. Typically, solid solution crystals grow in a dendritic manner, resulting in the dendrite arms containing more high-melting-point components and the interdendritic regions containing more low-melting-point component atoms. This leads to compositional inhomogeneity within the same grain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Dendritic segregation\"进行详细的文字解释和论述，答案提供了概念定义、形成机制和具体表现，符合简答题的特征。 | 知识层次: 题目考查的是对Dendritic segregation这一基本概念的定义和描述，属于材料科学中关于微观偏析的基础知识，主要依赖记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。题目要求解释\"Dendritic segregation\"的定义、形成原因及其在材料中的表现，涉及非平衡冷却条件下的微观偏析现象。虽然需要描述多个相关概念（如高熔点组分和低熔点组分的分布、枝晶生长方式等），但整体仍属于基础概念的记忆和解释范畴，不需要进行复杂的概念体系阐述或深入分析。" + }, + { + "idx": 1326, + "question": "Explain the source and morphological characteristics of Fe3CI", + "answer": "Fe3CI: originates from the liquid phase, appearing as white elongated strips.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3CI的来源和形态特征，需要文字解释和论述，答案也以文字形式呈现。 | 知识层次: 题目考查Fe3CI的来源和形态特征的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求解释Fe3CI的来源和形态特征，属于概念解释和描述的层次。虽然需要记忆和描述具体知识点，但不需要复杂的逻辑推理或多概念整合，因此属于中等难度。" + }, + { + "idx": 1327, + "question": "Explain the origin and morphological characteristics of Fe3CII", + "answer": "Fe3CII: Originates from the austenite precipitation reaction, generally distributed in a network-like pattern along grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Fe3CII的起源和形态特征，需要文字解释和论述，属于简答题类型 | 知识层次: 题目要求解释Fe3CII的起源和形态特征，涉及奥氏体析出反应和晶界分布模式，需要理解相关概念并关联分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解Fe3CII的起源和形态特征，并进行综合分析和说明。题目要求解释其来源和分布模式，涉及对相变过程的理解和显微组织特征的描述，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1328, + "question": "According to the reaction temperature from high to low, sequentially write the reaction formulas of the three-phase equilibrium reactions in the Fe-Fe3C alloy system", + "answer": "L0.53 + δ0.09 → γ0.17 (1495°C)\\nL4.3 → γ2.11 + Fe3C (1148°C)\\nγ0.77 → α0.0218 + Fe3C (727°C)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求按照温度从高到低的顺序写出Fe-Fe3C合金系统中的三相平衡反应式，答案以反应式和温度的形式给出，需要理解和记忆相关知识点并进行排序，属于简答题类型。 | 知识层次: 题目主要考查对Fe-Fe3C合金系统中三相平衡反应及其反应温度的记忆，属于基础概念的记忆性知识。虽然需要按照温度顺序排列反应式，但不需要复杂的分析或综合应用。 | 难度: 在简答题中属于复杂概念体系阐述难度，需要掌握Fe-Fe3C合金系统的三相平衡反应及其温度顺序，涉及多个反应公式的记忆和温度数据的准确对应，解题步骤较为复杂，对知识点的掌握深度要求较高。" + }, + { + "idx": 1329, + "question": "Explain the origin and morphological characteristics of Fe3CIII", + "answer": "Fe3CIII: Originates from the precipitation reaction of ferrite, generally distributed in a network pattern along grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3CIII的来源和形态特征，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Fe3CIII的起源和形态特征的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释Fe3CIII的起源和形态特征，涉及对特定材料科学概念的记忆和理解，但不需要复杂的体系阐述或多步骤推理。答案提供了明确的定义和分布特征，符合该难度等级对知识掌握和表达能力的要求。" + }, + { + "idx": 1330, + "question": "Explain the origin and morphological characteristics of Fe3C eutectoid", + "answer": "Fe3C eutectoid: The cementite in the eutectoid product pearlite, generally distributed in a lamellar form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C共析体的起源和形态特征，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Fe3C共析体的基本概念和形态特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释Fe3C共析体的起源和形态特征，属于概念解释和描述的难度等级。虽然需要记忆基本定义，但还需要对形态特征进行简要描述，比单纯复述定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1331, + "question": "Explain the origin and morphological characteristics of Fe3C eutectic", + "answer": "Fe3C eutectic: The cementite in the eutectic product ledeburite, which generally exists as the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C共晶的起源和形态特征，需要文字解释和论述，答案也以文字形式给出，符合简答题的特征。 | 知识层次: 题目考查对Fe3C共晶体的基本概念和形态特征的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释Fe3C共晶的起源和形态特征，这需要学生对相关概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入的分析。答案提供了基本的定义和描述，符合等级2的要求。" + }, + { + "idx": 1332, + "question": "Explain the temperature range and alias of the first type of temper brittleness", + "answer": "The brittleness that occurs when tempering between 250~400Ω is called low-temperature temper brittleness, also known as the first type of temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释温度范围和别称，需要文字解释和论述 | 知识层次: 题目考查对第一类回火脆性的温度范围和别名的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义和温度范围，属于最基础的概念记忆性知识。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。题目答案直接给出定义和数值范围，没有涉及任何扩展性论述要求。" + }, + { + "idx": 1333, + "question": "Explain the reversibility of the second type of temper embrittlement", + "answer": "The second type of temper embrittlement is reversible.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"The second type of temper embrittlement is reversible\"），答案直接给出了对错判断（\"is reversible\"），符合判断题的特征。 | 知识层次: 题目考查对第二类回火脆性可逆性的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目仅涉及基础概念的正误判断（第二类回火脆性的可逆性），不需要深入理解或分析复杂概念，属于最基础的概念记忆层次。" + }, + { + "idx": 1334, + "question": "Explain the reversibility of the first type of temper embrittlement", + "answer": "The first type of temper embrittlement is irreversible temper embrittlement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第一类回火脆性的可逆性，需要文字解释和论述，答案也提供了简要的文字说明。 | 知识层次: 题目考查对第一类回火脆性可逆性的基本概念记忆和理解，属于定义和分类层面的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答第一类回火脆性的可逆性这一基本定义，属于最基础的概念记忆层面。不需要进行额外的解释或复杂概念体系的阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1335, + "question": "Briefly describe one of the essential reasons for the high hardness of martensite: the characteristics of its crystal structure", + "answer": "The crystal structure of martensite is body-centered tetragonal, lacking closely packed slip planes that facilitate dislocation movement, thus making dislocation slip difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的原因之一，即其晶体结构的特点。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对马氏体晶体结构特征的基本概念记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目要求解释马氏体高硬度的晶体结构原因，涉及对体心四方晶体结构特征及其与位错运动关系的描述。这超出了基本定义（等级1）的范围，但尚未达到需要阐述复杂概念体系（等级3）的程度，属于概念解释和描述的中等难度（等级2）。" + }, + { + "idx": 1336, + "question": "Explain the cause of the first type of temper brittleness", + "answer": "The first type of temper brittleness occurs due to the precipitation of discontinuous thin-shell-like carbides along the interfaces of martensite laths or plates during martensite decomposition, which reduces the fracture strength of grain boundaries, making them the path for crack propagation and thus leading to brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第一类回火脆性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第一类回火脆性的原因，涉及马氏体分解过程中碳化物析出及其对晶界断裂强度的影响机制，需要深入理解材料微观组织演变与力学性能之间的关系，属于机理层面的解释和分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释第一类回火脆性的原因，涉及马氏体分解过程中碳化物析出的具体机制及其对晶界断裂强度的影响。这需要考生不仅掌握相关概念，还需要理解微观组织变化与宏观性能之间的关系，并进行一定程度的推理分析。虽然题目没有要求全面分析复杂现象，但对机理的解释深度要求较高，因此属于等级4。" + }, + { + "idx": 1337, + "question": "Explain the temperature range and alias of the second type of temper brittleness", + "answer": "The brittleness that occurs when tempering between 450~650°C is called high-temperature temper brittleness, also known as the second type of temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第二类回火脆性的温度范围和别名，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对第二类回火脆性的温度范围和别名的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并复述特定温度范围和别称，不涉及复杂概念体系或深入解释。" + }, + { + "idx": 1338, + "question": "Explain the cause of the second type of temper brittleness", + "answer": "The cause of the second type of temper brittleness is the segregation of impurity elements such as Sb, Sn, P, and As to the original austenite grain boundaries during tempering, which weakens the atomic bonding force at the austenite grain boundaries and reduces the grain boundary fracture strength. This is the main reason for the occurrence of the second type of temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第二类回火脆性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第二类回火脆性的原因，涉及杂质元素在晶界的偏聚及其对原子结合力和晶界断裂强度的影响。这需要综合运用材料科学中的相变、晶界行为和杂质效应等知识，进行机理层面的分析和解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对第二类回火脆性的原因进行机理深度解释，涉及杂质元素偏聚、晶界结合力减弱等专业概念的阐述。虽然不需要进行多因素交互作用的全面分析（等级5要求），但需要准确描述特定机理并解释其对材料性能的影响，属于该题型中较高难度的题目。" + }, + { + "idx": 1339, + "question": "Briefly describe the third essential reason for the high hardness of martensite: grain boundary strengthening mechanism", + "answer": "Whether it is the laths of lath martensite or the plates of plate martensite, they are all very fine, and the grain boundary strengthening mechanism also plays a significant role.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第三个主要原因，即晶界强化机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体高硬度的第三个重要原因——晶界强化机制，需要理解马氏体的微观结构（板条或片状）与晶界强化的关系，属于概念关联和综合分析层次。虽然不涉及复杂计算，但需要对材料强化机制有较深入的理解和应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释马氏体高硬度的第三个原因——晶界强化机制，但答案只需要简要描述晶粒细化的现象及其对硬度的贡献，不需要深入分析多个因素或进行复杂的关联性论述。这符合等级3的综合分析和说明要求，但未达到等级4的多角度分析或等级5的深度关联性分析的标准。" + }, + { + "idx": 1340, + "question": "Briefly describe the second essential reason for the high hardness of martensite: the solid solution strengthening mechanism", + "answer": "Ferrite typically contains only 0.03% carbon atoms, while the carbon content in martensite is the same as that of the material itself. Therefore, martensite contains a large number of supersaturated carbon atoms, making solid solution strengthening one of the primary mechanisms for the high hardness of martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第二个主要原因，即固溶强化机制，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释马氏体高硬度的第二个主要原因，即固溶强化机制。这需要理解马氏体中碳原子的过饱和状态及其对硬度的影响，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求考生理解并简要描述马氏体高硬度的第二个主要原因——固溶强化机制。虽然需要考生掌握固溶强化的概念，并能够将其与马氏体的碳含量联系起来，但题目并未要求深入分析或关联其他复杂概念。解题步骤相对直接，只需解释碳原子的过饱和状态如何导致固溶强化即可。因此，在简答题题型中，该题目属于综合分析说明的难度等级。" + }, + { + "idx": 1343, + "question": "How does the concentration of a solid solution affect the diffusion coefficient?", + "answer": "The higher the concentration, the easier the diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固体溶液浓度对扩散系数的影响，答案需要文字论述和解释，没有提供选项或要求计算 | 知识层次: 题目涉及固体溶液浓度对扩散系数的影响，需要理解扩散机制和浓度之间的关系，并进行概念关联和综合分析。虽然不涉及复杂计算，但需要对扩散过程有较深入的理解，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解固体溶液浓度与扩散系数的关系，并进行简单的综合分析说明。虽然涉及概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1344, + "question": "How does the type of solid solution affect the diffusion coefficient?", + "answer": "Different solid solutions have different atomic diffusion and mechanisms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液类型如何影响扩散系数，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目要求分析不同类型固溶体对扩散系数的影响机制，需要综合运用扩散理论、固溶体特性以及原子扩散机制的知识，进行推理分析和机理解释。这超出了简单记忆或应用层面，属于较复杂的综合分析。 | 难度: 在简答题中属于机理深度解释难度，需要理解不同类型固溶体的原子扩散特性及其影响机制，并进行较为详细的论述。虽然不涉及复杂现象的全面分析，但仍需综合运用相关知识进行推理和解释。" + }, + { + "idx": 1345, + "question": "How does crystal structure affect the diffusion coefficient?", + "answer": "Different structures result in different diffusion coefficients.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶体结构如何影响扩散系数，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释晶体结构如何影响扩散系数，这需要理解晶体结构与扩散机制之间的关系，并进行概念关联和综合分析。虽然不涉及复杂的计算或深度推理，但需要多步思考和解释，超出了基础概念记忆和简单应用的范畴。 | 难度: 在简答题中属于中等难度，需要理解晶体结构对扩散系数的影响，并进行综合分析和说明。题目要求解释不同结构如何导致不同的扩散系数，涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1346, + "question": "How does chemical composition affect the diffusion coefficient?", + "answer": "The addition of chemical elements hinders diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释化学组成如何影响扩散系数，需要文字论述而非选择、判断或计算 | 知识层次: 题目涉及化学组成对扩散系数的影响，需要理解扩散的基本原理，并能够分析不同化学元素如何阻碍扩散过程。这需要将扩散理论与具体化学元素的作用联系起来，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释化学组成对扩散系数的影响，但答案较为直接，仅需说明添加化学元素会阻碍扩散这一基本概念。不需要多角度分析或深度关联其他复杂概念，符合等级3的综合分析和说明要求。" + }, + { + "idx": 1347, + "question": "Briefly describe the fourth essential reason for the high hardness of martensite: the transformation strengthening mechanism", + "answer": "During martensitic transformation, substructures with high lattice defect density are created within the crystal. The high-density dislocation networks in lath martensite and the fine twins in plate martensite both hinder dislocation motion, thereby causing strengthening through transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第四个原因，即转变强化机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体高硬度的第四个重要原因——相变强化机制，涉及马氏体相变过程中亚结构的形成及其对位错运动的阻碍作用。这需要综合运用相变原理、晶体缺陷理论和强化机制等多方面知识，并进行机理层面的分析和解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对马氏体高硬度的第四个原因——相变强化机制进行描述。这需要考生不仅理解马氏体相变的基本概念，还需要掌握相变过程中产生的亚结构（如高位错密度的板条马氏体和细小的孪晶）对位错运动的阻碍作用。虽然题目没有要求全面分析所有相关现象，但需要对机理进行深度解释，属于该题型中的较高难度等级。" + }, + { + "idx": 1348, + "question": "Briefly describe the fifth essential reason for the high hardness of martensite: the aging strengthening mechanism", + "answer": "After the formation of martensite, carbon and alloy element atoms diffuse and segregate or precipitate to dislocations or other crystal defects, pinning the dislocations and making them difficult to move, thereby increasing the hardness and strength of martensite through aging strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第五个主要原因，即时效强化机制，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释马氏体高硬度的第五个重要原因——时效强化机制，涉及碳和合金元素原子的扩散、偏聚或析出到位错或其他晶体缺陷的过程，以及这些过程如何钉扎位错并增加硬度。这需要深入理解材料科学中的相变、扩散、位错理论和强化机制等多个复杂概念的综合运用和机理解释。 | 难度: 在简答题题型中，该题目要求对马氏体高硬度的第五个关键原因——时效强化机制进行描述。这需要考生不仅理解马氏体的基本特性，还需要掌握碳和合金元素原子扩散、偏聚或析出到位错或其他晶体缺陷的机理，以及这些过程如何钉扎位错并阻碍其运动从而增加硬度和强度的详细过程。这种题目要求考生具备较深的机理理解和综合运用知识的能力，属于机理深度解释的难度等级。" + }, + { + "idx": 1349, + "question": "A stress of 70MPa is applied in the [001] direction of an FCC crystal. Which slip system in the crystal will activate first?", + "answer": "The resolved shear stress on the (111)[10-1] slip system is 28.58MPa, while the (1-11)[110] slip system does not slip. Therefore, the (111)[10-1] slip system activates first.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪个滑移系统会首先激活，并给出了具体的计算结果和结论。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求计算FCC晶体中不同滑移系的分切应力，并判断哪个滑移系会首先激活。这涉及多步计算（如分切应力计算）和概念关联（如滑移系的选择和激活条件），需要综合分析不同滑移系的几何关系和应力状态。虽然不涉及复杂的机理或创新应用，但比简单应用更深入。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求分析FCC晶体在特定应力方向下的滑移系统激活情况，涉及以下多步骤分析：1) 理解FCC晶体结构和滑移系统；2) 计算不同滑移系统的分解剪应力；3) 比较不同滑移系统的分解剪应力大小；4) 判断哪个滑移系统会首先激活。这些步骤需要综合应用晶体学、材料力学和滑移系统相关知识，并进行定量计算和比较分析，符合多角度分析论述的要求。" + }, + { + "idx": 1350, + "question": "Analyze the essential similarities between work hardening, fine grain strengthening, solid solution strengthening, and second-phase strengthening", + "answer": "Similarities: All involve hindering dislocation movement, increasing the resistance to dislocation glide, thereby strengthening the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析四种强化机制的相似性，需要文字解释和论述，而不是选择、判断或计算。答案也是以文字形式阐述相似点，符合简答题的特征。 | 知识层次: 题目要求分析四种强化机制的相似性，涉及对材料强化机理的深入理解和综合分析，需要将不同强化方式的共同点进行关联和推理，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对四种不同的材料强化机制进行综合分析和比较，需要深入理解每种强化机制的微观机理，并找出它们共同的作用原理。这涉及到复杂的材料科学知识，包括位错理论、晶体结构、相变等，并且需要将这些知识综合运用来解释现象。此外，题目还要求考生能够清晰地表达这些复杂的概念和相互关系，这对考生的分析能力和表达能力都有较高要求。因此，在简答题题型中，该题目属于最高难度等级。" + }, + { + "idx": 1351, + "question": "Analyze the fundamental differences of grain refinement strengthening", + "answer": "Grain refinement strengthening: increases grain boundaries, enlarges the range of dislocation pile-up.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶粒细化强化的基本原理，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析晶粒细化强化的基本原理，涉及对晶界和位错堆积范围的理解，需要综合运用材料科学中的强化机制知识，进行推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对晶粒细化强化的基本原理进行深度解释，涉及晶界增加和位错堆积范围扩大等机理分析。虽然不需要全面分析复杂现象，但需要对材料强化机制有较深入的理解和解释能力，属于机理深度解释层次的难度。" + }, + { + "idx": 1352, + "question": "A stress of 70 MPa is applied in the [001] direction of an FCC crystal. Determine the resolved shear stress on the (1-11)[110] slip system.", + "answer": "Substitute into the formula: τ=σcosφcosλ, where cosλ=|a u+b v+c w|/(√(a²+b²+c²)√(u²+v²+w²)), cosφ=|a h+b k+c l|/(√(a²+b²+c²)√(h²+k²+l²)). For the (1-11)[110] slip system, since cosλ=0, this slip system does not slip under the applied stress.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（τ=σcosφcosλ）来确定分解剪应力，解答过程涉及具体的数学运算和晶体学参数代入，属于典型的计算题类型。 | 知识层次: 题目需要应用晶体学中的方向指数和面指数知识，进行多步计算（包括方向余弦计算和剪切应力公式应用），并理解滑移系统的几何关系。虽然计算过程明确，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式和概念（如方向余弦、剪切应力公式），并进行多步计算。虽然计算过程明确，但需要正确理解晶体学方向和滑移系统的关系，属于中等偏上的难度。" + }, + { + "idx": 1353, + "question": "According to solidification theory, what is the fundamental principle of grain refinement by vibration and stirring?", + "answer": "Vibration and stirring. Vibration and stirring can input additional energy into the liquid to provide nucleation work, promoting nucleation. On the other hand, they can cause crystallized crystals to fragment under the impact of liquid flow, increasing the number of nuclei.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动和搅拌对晶粒细化的基本原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释振动和搅拌细化晶粒的基本原理，涉及凝固理论中的成核和晶体破碎机制，需要综合运用多个概念进行推理分析，思维过程较为深入。 | 难度: 在简答题的复杂分析层次中，该题目要求对凝固理论中的晶粒细化机理进行深度解释。需要综合运用振动和搅拌对液态金属的影响原理，包括额外能量输入提供形核功、以及液态流动导致晶体破碎增加形核数量这两个关键机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述，达到了机理深度解释的等级4要求。" + }, + { + "idx": 1354, + "question": "According to solidification theory, what is the fundamental principle of refining grain size by increasing undercooling?", + "answer": "Increasing undercooling. Grain size depends on the relative relationship between nucleation rate and grain growth velocity. When undercooling is significantly high, the increase rate of nucleation surpasses that of grain growth, thus enhancing undercooling ensures N > G and widens the gap between them, leading to grain refinement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释凝固理论中通过增加过冷度细化晶粒的基本原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释通过增加过冷度细化晶粒的基本原理，涉及成核速率与晶粒生长速度的相对关系，需要综合运用凝固理论中的概念进行推理分析，思维过程较为深入。 | 难度: 在简答题题型中，该题目要求对凝固理论中的晶粒细化机理进行深度解释，涉及成核速率与晶粒生长速度的相对关系分析，以及过冷度对这两个参数的影响机制。虽然不需要进行多因素交叉分析（如等级5要求的复杂现象全面分析），但需要准确运用专业术语和理论推导，属于机理深度解释层面的难度。" + }, + { + "idx": 1355, + "question": "According to solidification theory, what is the fundamental principle of grain refinement through modification treatment?", + "answer": "Modification treatment. That is, adding a modifier to the molten metal before pouring to promote heterogeneous nucleation and increase the number of nuclei, thereby refining the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述材料科学中的基本原理，答案需要文字描述和详细解释，符合简答题的特征。 | 知识层次: 题目考查对凝固理论和晶粒细化基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释晶粒细化的基本原理，涉及异质形核和晶核数量增加的概念，但不需要复杂的体系阐述或深入分析。属于对基础概念的理解和简要描述层次。" + }, + { + "idx": 1356, + "question": "Describe the behavior and manifestations of crystal defects in metals during the recovery stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects in this stage.", + "answer": "Recovery: Line defects remain largely unchanged, point defects significantly decrease, mechanical properties remain unchanged, while corresponding physicochemical properties alter; the driving force is stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述晶体缺陷在金属回复阶段的行为和表现，以及相应的材料性能和驱动力，需要文字解释和论述。答案也是以文字形式给出解释，而非选择、判断或计算。 | 知识层次: 题目要求描述晶体缺陷在金属回复阶段的行为和表现，并解释驱动力的来源，这需要将多个概念（晶体缺陷、回复阶段、材料性能变化、驱动力）进行关联和综合分析。虽然不涉及复杂的计算或创新应用，但需要对材料科学中的基本原理有较深入的理解和应用能力。 | 难度: 在简答题题型中，该题目要求对晶体缺陷在金属回复阶段的行为和表现进行描述，并解释驱动力的来源。这需要学生不仅掌握晶体缺陷的基本概念，还需要理解回复阶段的微观机制及其对材料性能的影响。此外，题目还要求综合分析驱动力的来源，涉及多个知识点的关联和应用。虽然不需要进行深度关联性分析（如等级5），但需要多角度分析论述，因此属于等级4难度。" + }, + { + "idx": 1357, + "question": "Analyze the fundamental differences in solid solution strengthening", + "answer": "Solid solution strengthening: solute atoms gather along dislocations and pin them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析固溶强化的基本原理，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析固溶强化的基本原理，涉及溶质原子与位错的相互作用机制，需要深入理解和解释材料强化的微观机理，属于复杂分析和推理分析的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求对固溶强化的基本原理进行机理层面的解释，需要综合运用材料科学知识分析溶质原子与位错的相互作用机制。虽然不涉及多因素交互作用的全面分析（等级5要求），但已超出基础概念描述，进入机理深度解释层面，符合等级4标准。" + }, + { + "idx": 1358, + "question": "Analyze the essential differences in second-phase strengthening", + "answer": "Second-phase strengthening: The dispersed strengthening phase particles force dislocations to cut through or bypass the strengthening phase particles, and the additional work required constitutes the dislocation mechanism of dispersed phase strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析第二相强化的本质差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析第二相强化的本质差异，涉及位错机制和强化相颗粒的相互作用，需要综合运用材料科学中的位错理论和强化机制知识，进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于较高层次的认知要求。 | 难度: 在简答题中属于机理深度解释难度，需要准确描述第二相强化的位错机制，并解释强化相颗粒如何阻碍位错运动。这要求对材料强化机理有较深入的理解，并能清晰表述复杂的物理过程。虽然不涉及多因素综合分析，但对单一机理的解释深度要求较高。" + }, + { + "idx": 1359, + "question": "Analyze the effect of cold deformation degree on recrystallized grain size.", + "answer": "When the cold deformation degree is less than the critical deformation degree, the grains after recrystallization basically remain in the state before cold deformation. Due to the minimal stored energy, recrystallization does not actually occur, so the cold deformation degree has no relation to the size of recrystallized grains. When the cold deformation degree increases to the critical deformation degree, the stored energy from cold deformation is sufficient to drive recrystallization. However, because the overall deformation degree is small and uneven, only a few areas with higher deformation degrees can form nuclei and grow. At this point, since $G>>N$, only a few nuclei form and rapidly grow, resulting in the largest grain size after recrystallization. Beyond the critical deformation degree, the cold deformation degree is inversely proportional to the recrystallized grain size. When the deformation degree reaches a certain level, the grain size remains essentially unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷变形程度对再结晶晶粒尺寸的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析冷变形程度对再结晶晶粒尺寸的影响，涉及多个阶段的变形程度与晶粒尺寸的关系，需要理解存储能量、临界变形程度、晶核形成和生长等概念，并进行综合分析。答案中详细解释了不同变形程度下的再结晶行为，包括临界变形程度前后的变化，以及晶粒尺寸的变化趋势，体现了对机理的深入理解和推理分析能力。 | 难度: 在简答题中属于复杂现象全面分析的难度等级。该题目要求考生不仅理解冷变形程度对再结晶晶粒尺寸的基本影响，还需要详细解释临界变形程度前后的不同机理，包括存储能量、形核与生长速率的关系（$G>>N$），以及变形程度达到一定水平后的稳定现象。这种综合分析需要考生具备深入的材料科学知识和高阶推理能力，符合等级5的标准。" + }, + { + "idx": 1361, + "question": "At what temperature or temperature range is eutectic cementite formed through what reaction? And write the reaction equation.", + "answer": "Eutectic cementite: 1148°C, eutectic reaction, L→(γ+Fe3C) eutectic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求回答具体的温度范围和反应类型，并写出反应方程式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对共晶反应温度、产物和反应方程式的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要记忆并解释特定温度下的共晶反应及其产物，但不需要复杂的体系阐述或深入分析。题目要求回答具体的温度范围和反应方程，属于概念解释和描述的范畴。" + }, + { + "idx": 1362, + "question": "Describe the behavior and manifestations of crystal defects in metals during the cold deformation stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects at this stage.", + "answer": "Cold deformation: Crystal defects including point defects, line defects, and planar defects all increase significantly, leading to work hardening and corresponding changes in physical and chemical properties; the driving force is the externally applied resolved shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体缺陷在冷变形阶段的行为和表现，并解释驱动力的来源，需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求描述晶体缺陷在冷变形阶段的行为和表现，并解释驱动这些缺陷运动的驱动力，这需要综合运用晶体缺陷理论、材料变形机制和力学原理进行深入分析和解释。不仅涉及多个知识点的关联，还需要对机理解释和推理分析的能力。 | 难度: 在简答题-复杂分析题型中，该题目要求对晶体缺陷在冷变形阶段的行为和表现进行详细描述，并解释其驱动力的机理。这需要综合运用材料科学的知识，深入理解晶体缺陷的类型、冷变形对材料性能的影响，以及外应力在缺陷运动中的作用。虽然题目涉及多个知识点，但并未要求对复杂现象进行全面分析或跨学科整合，因此属于机理深度解释的等级4。" + }, + { + "idx": 1363, + "question": "Describe the behavior and manifestations of crystal defects in metals during the recrystallization stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects at this stage.", + "answer": "Recrystallization: Line defects significantly decrease, and the material exhibits softening; the driving force is stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体缺陷在金属再结晶阶段的行为和表现，以及相应的材料性能，并解释推动这些晶体缺陷运动的驱动力。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求描述晶体缺陷在金属再结晶阶段的行为和表现，并解释相应的材料性能变化，以及推动这些晶体缺陷运动的驱动力。这需要综合运用晶体缺陷、再结晶过程和材料性能变化的知识，进行推理分析和机理解释，涉及多个知识点的关联和深度理解。 | 难度: 在简答题中属于机理深度解释难度，需要详细描述晶体缺陷在再结晶阶段的行为和表现，并解释其驱动力的来源。题目要求综合运用材料科学知识，进行推理分析和机理解释，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 1364, + "question": "Describe the behavior and manifestations of crystal defects in metals during the grain growth stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects at this stage.", + "answer": "Grain growth: planar defects significantly decrease; the driving force is the total interfacial free energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体缺陷在金属晶粒生长阶段的行为和表现，以及相应的材料特性，并解释促进这些晶体缺陷运动的驱动力。这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了简短的论述性回答，符合简答题的特征。 | 知识层次: 题目要求描述晶界缺陷在晶粒生长阶段的行为和表现，并解释驱动这些缺陷运动的驱动力，这需要综合运用晶体缺陷、晶粒生长机制和热力学驱动力等多方面的知识，进行深入的机理分析和解释。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于机理深度解释难度等级。题目要求描述晶界缺陷在晶粒长大阶段的行为和表现，并解释驱动这些缺陷运动的驱动力，这需要综合运用晶体缺陷、界面能和热力学等多方面知识进行机理层面的解释。虽然题目未要求对比不同阶段的缺陷行为或量化分析驱动力大小（否则可能达到等级5），但已明显超出基础概念复述的范畴，属于需要深入理解并逻辑阐述的复杂分析题。" + }, + { + "idx": 1365, + "question": "At what temperature or temperature range is tertiary cementite formed, and through what reaction? Also, write the reaction equation.", + "answer": "Tertiary cementite: <727°C, secondary precipitation reaction, α→Fe3CIII.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释温度范围、反应类型并写出反应方程式，需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对三级渗碳体形成温度范围及反应类型的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答温度范围、反应类型并写出反应方程式，涉及对相变过程的基本理解和记忆，但不需要复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题需要更多的概念整合和反应机理描述，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 1366, + "question": "At what temperature or temperature range is primary cementite formed, and through what reaction? Also, write the reaction equation.", + "answer": "Primary cementite: >1148°C, eutectic reaction, L→Fe3C1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释初级渗碳体的形成温度范围及反应类型，并写出反应方程式，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对初级渗碳体形成温度范围、反应类型及反应方程的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要回答温度范围和反应类型，并写出反应方程式。虽然涉及基础概念记忆，但需要将多个知识点整合回答，比单纯的定义简答要求更高。" + }, + { + "idx": 1367, + "question": "Analyze the fundamental differences in work hardening", + "answer": "Work hardening: Possible mechanisms include dislocation pile-up, forest dislocation resistance, and the consumption of external force work through the formation of jogs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析并解释工作硬化的基本差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析加工硬化的基本差异，涉及位错堆积、森林位错阻力等机制的解释，需要综合运用材料科学中的位错理论和塑性变形知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对加工硬化的基本差异进行深入分析，涉及多种可能的机制（如位错堆积、森林位错阻力、外部力功的消耗等）。这需要考生不仅理解这些概念，还需要能够综合运用和解释这些机理之间的相互作用。虽然题目没有要求全面分析所有可能的复杂现象，但对机理的深度解释要求较高，因此在简答题题型中属于等级4难度。" + }, + { + "idx": 1368, + "question": "What types of cementite may exist in iron-carbon alloys?", + "answer": "Primary cementite, eutectic cementite, secondary cementite, eutectoid cementite, tertiary cementite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举铁碳合金中可能存在的渗碳体类型，答案以文字形式给出具体分类，不需要计算或判断对错，属于简答题类型。 | 知识层次: 题目考查铁碳合金中不同类型渗碳体的分类记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举铁碳合金中可能存在的渗碳体类型，这需要学生对相关基础概念有清晰的记忆和理解，但不需要进行复杂的体系阐述或深入分析。虽然涉及多个专业术语，但都属于基础概念记忆范畴，解题步骤相对直接，符合等级2的描述要求。" + }, + { + "idx": 1369, + "question": "What are the differences in morphology, size, and distribution of primary cementite?", + "answer": "Regular strip shape, coarse, distributed on the ledeburite matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和描述primary cementite在形态、尺寸和分布上的差异，答案提供了文字描述而非选择、判断或计算。 | 知识层次: 题目考查对初级渗碳体的形态、尺寸和分布等基本特征的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求解释和描述初级渗碳体的形态、尺寸和分布特征，属于概念解释和描述的范畴。虽然需要记忆具体的形态特征和分布情况，但不需要进行复杂的体系阐述或深入分析，因此属于中等难度。" + }, + { + "idx": 1371, + "question": "At what temperature or temperature range is secondary cementite formed, and through what reaction? Also, write the reaction equation.", + "answer": "Secondary cementite: 1148~727°C, secondary precipitation reaction, γ→Fe3CII.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释二次渗碳体的形成温度范围、反应类型，并写出反应方程式，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对二次渗碳体形成温度范围及反应方程的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释温度范围、反应类型并写出反应方程，涉及多个知识点的整合，但不需要复杂的概念体系阐述。" + }, + { + "idx": 1372, + "question": "What are the differences in morphology, size, and distribution of eutectic cementite?", + "answer": "Acts as the continuous matrix of ledeburite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述共晶渗碳体的形态、尺寸和分布差异，需要文字描述而非选择、判断或计算。答案也是以文字解释的形式给出。 | 知识层次: 题目要求分析共晶渗碳体的形态、尺寸和分布差异，这需要理解共晶组织的形成机制，并能将多个概念（如形态、尺寸、分布）关联起来进行综合分析。虽然不涉及复杂的计算或创新设计，但需要一定的认知深度和多步思考。 | 难度: 在简答题题型中，该题目要求对共晶渗碳体的形态、尺寸和分布差异进行多角度分析论述。这需要学生不仅掌握相关概念，还需要能够综合分析不同特征之间的关联性，并能够清晰地表达这些差异。虽然不需要进行深度关联性分析（如等级5），但已经超出了简单的概念解释或单一特征说明（如等级3），因此属于等级4难度。" + }, + { + "idx": 1374, + "question": "What are the differences in morphology, size, and distribution of tertiary cementite?", + "answer": "Discontinuous granular, small amount, distributed at ferrite grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释三级渗碳体的形态、尺寸和分布差异，答案提供了文字描述而非选择、判断或计算。 | 知识层次: 题目考查对三级渗碳体的形态、尺寸和分布等基本特征的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答关于三次渗碳体的形态、尺寸和分布的差异，这需要学生对相关概念有一定的理解和记忆，但不需要复杂的体系阐述或深入的分析。答案涉及对基本特征的描述，属于中等难度的简答题。" + }, + { + "idx": 1375, + "question": "What effect does eutectic cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness but reduces toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释共晶渗碳体对铁碳合金机械性能的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求理解共晶渗碳体对铁碳合金机械性能的影响，涉及多个概念的关联和综合分析，需要将材料微观结构与宏观性能联系起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求分析共晶渗碳体对铁碳合金机械性能的影响，但答案相对直接，只需说明硬度和韧性的变化。不需要多角度分析或深度关联其他概念，符合等级3的综合分析和说明要求。" + }, + { + "idx": 1376, + "question": "What are the differences in morphology, size, and distribution of secondary cementite?", + "answer": "It is distributed at the original austenite grain boundaries that have transformed into pearlite. When the amount is small, it appears as discontinuous granular; when the amount is large, it forms a continuous network.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和描述二次渗碳体的形态、尺寸和分布差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对二次渗碳体的形态、尺寸和分布进行描述和分析，涉及多个概念的关联和综合分析，需要理解材料微观结构的变化及其影响因素，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解二次渗碳体的形态、尺寸和分布特点，并能结合珠光体转变过程进行综合分析。题目要求对材料微观组织的形成机制有一定理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1377, + "question": "What effect will primary cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness but reduces toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释初级渗碳体对铁碳合金机械性能的影响，需要文字解释和论述，而不是从选项中选择或简单判断对错。答案提供了简短的文字解释，符合简答题的特征。 | 知识层次: 题目要求理解初级渗碳体对铁碳合金机械性能的影响，涉及多个概念（硬度、韧性）的关联和综合分析，需要一定的应用和分析能力，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求分析初生渗碳体对铁碳合金机械性能的影响，需要考生理解渗碳体的特性及其对硬度和韧性的作用机制。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析，解题步骤相对直接。" + }, + { + "idx": 1379, + "question": "What effect will tertiary cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness and strength but reduces toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释第三渗碳体对铁碳合金机械性能的影响，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目需要理解三次渗碳体对铁碳合金机械性能的影响，涉及硬度、强度和韧性的变化，属于概念关联和综合分析的中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对铁碳合金中三次渗碳体对机械性能的影响进行解释，但只需进行基本的综合分析和说明，无需多角度或深度关联性分析。回答需要理解渗碳体的作用及其对硬度、强度和韧性的影响，但解题步骤相对直接，属于该题型内的标准难度。" + }, + { + "idx": 1380, + "question": "What effect does secondary cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness but reduces toughness; discontinuous granular form enhances strength, while continuous network form reduces strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释二次渗碳体对铁碳合金机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释二次渗碳体对铁碳合金机械性能的影响，涉及多个概念的关联和综合分析，如硬度、韧性、强度等，需要理解不同形态（不连续颗粒状和连续网状）对性能的不同影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对二次渗碳体对铁碳合金机械性能的影响进行多角度分析论述。不仅需要解释硬度和韧性的变化，还需区分不同形态（颗粒状和网状）对强度的具体影响。这涉及多个概念的关联和综合分析，属于中等应用层次中的较高难度，符合等级4的多角度分析论述要求。" + }, + { + "idx": 1381, + "question": "Using dislocation theory, explain one of the reasons for work hardening in pure metal single crystals.", + "answer": "Dislocation intersections occur, and the resulting jogs impede dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释纯金属单晶加工硬化的原因，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求运用位错理论解释纯金属单晶加工硬化的原因，涉及位错交截和位错运动的阻碍机制。这需要深入理解位错理论，并能将理论知识与实际现象关联起来进行分析和解释，属于较高层次的认知能力。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求运用位错理论解释纯金属单晶加工硬化的原因，属于机理深度解释的难度等级。虽然题目聚焦于位错交割这一具体机制，但需要学生准确描述位错相互作用产生的割阶如何阻碍位错运动，这涉及对位错理论的深入理解和应用。相比等级5要求的复杂现象全面分析（如同时考虑多种硬化机制及其交互作用），该题目对知识整合的要求相对集中，因此属于等级4难度。" + }, + { + "idx": 1382, + "question": "What is the phenomenon of work hardening in metals?", + "answer": "The phenomenon where the applied flow stress continuously increases with the increase of strain during the plastic deformation of metallic materials is called work hardening. Alternatively, the phenomenon where the strength and hardness of metallic materials increase, while the plasticity and toughness decrease after cold plastic deformation, is called work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"work hardening\"现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对金属加工硬化现象的基本定义和特征的理解和记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释工作硬化现象，需要考生理解并描述金属材料在塑性变形过程中流动应力随应变增加而持续增加的现象，或者冷塑性变形后强度和硬度增加而塑性和韧性降低的现象。虽然涉及一定的专业术语和概念，但不需要复杂的体系阐述或多层次分析，属于中等难度的概念解释题。" + }, + { + "idx": 1383, + "question": "Using dislocation theory, what is the second reason for the work hardening of pure metal single crystals?", + "answer": "Dislocation reactions occur, forming immobile dislocations that hinder dislocation motion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释纯金属单晶加工硬化的第二个原因，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求运用位错理论解释纯金属单晶加工硬化的第二个原因，涉及位错反应形成不可动位错并阻碍位错运动的机理。这需要深入理解位错理论，并能将理论知识与实际现象关联起来进行推理分析，属于复杂分析层次。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求运用位错理论解释纯金属单晶加工硬化的第二个原因，涉及位错反应形成不可动位错并阻碍位错运动的机理。这属于机理深度解释的范畴，需要学生对位错理论有扎实的理解，并能将理论知识与实际现象联系起来进行解释。虽然不涉及多因素综合分析（等级5），但已超出基础概念复述的层面，属于该题型内较高难度的题目。" + }, + { + "idx": 1385, + "question": "Critical deformation degree", + "answer": "Critical deformation degree is the minimum pre-cold deformation required for metal to undergo recrystallization at a given temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Critical deformation degree\"进行文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对临界变形度这一基本概念的定义和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基础概念的定义，属于最基本的知识点记忆。不需要额外的解释、描述或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1386, + "question": "What are the beneficial aspects of the work hardening characteristics of metals for the use of metal materials?", + "answer": "As a means to improve the strength of metal materials; facilitating the plastic forming of metal materials; enabling metal parts to resist accidental overload.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属材料加工硬化特性的有益方面，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属加工硬化特性的有益方面，涉及对金属材料强度提升、塑性成形和抗过载能力的综合分析。虽然不需要复杂的计算或深度机理分析，但需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明金属材料的加工硬化特性及其应用。题目要求考生理解加工硬化的概念，并能够从提高材料强度、促进塑性成形和抵抗意外过载三个角度进行论述。虽然涉及多个知识点，但不需要进行深度关联性分析或多角度复杂论述。" + }, + { + "idx": 1387, + "question": "Unit cell", + "answer": "The unit cell is the most basic unit that constitutes a crystal lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"unit cell\"进行文字解释和论述，答案是一个简短的文字描述，符合简答题的特征 | 知识层次: 题目考查晶体学中最基础的概念——晶胞的定义，属于基础概念的记忆和理解层次，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答单位晶胞的基本定义，属于最基础的概念记忆性知识。不需要进行额外的解释或描述，解题步骤非常简单，仅需直接回忆并复述定义即可。因此在该题型和知识层次下属于最低难度等级。" + }, + { + "idx": 1388, + "question": "Calculate the coordination number of the cation in the compound MgO, given r(Mg2+)=0.078nm, r(O2-)=0.132nm", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数值进行计算，以确定MgO中阳离子的配位数，解答过程涉及数值计算和公式应用，最终答案为具体数值6。 | 知识层次: 题目要求应用离子半径比公式计算配位数，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，只需要直接应用半径比公式计算配位数，无需多个公式组合或复杂步骤。题目提供了明确的离子半径数据，计算过程简单直接。" + }, + { + "idx": 1389, + "question": "Using dislocation theory, what is the third reason for the work hardening of pure metal single crystals?", + "answer": "Dislocation multiplication occurs, and the increase in dislocation density further enhances the resistance to dislocation motion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释纯金属单晶加工硬化的第三个原因，答案需要文字解释和论述，属于简答题类型 | 知识层次: 题目要求运用位错理论解释纯金属单晶加工硬化的第三个原因，涉及位错增殖和位错密度增加对位错运动阻力的影响。这需要深入理解位错理论，并能将其与材料力学性能的变化机制联系起来，属于机理层面的解释和分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求运用位错理论解释纯金属单晶加工硬化的第三个原因，涉及到位错增殖和密度增加对位错运动阻力的影响。这需要学生对位错理论有较深入的理解，并能将理论知识与实际现象联系起来进行解释。虽然题目没有要求全面分析复杂现象，但需要对特定机理进行详细阐述，因此属于等级4难度。" + }, + { + "idx": 1391, + "question": "Unit dislocation", + "answer": "A unit dislocation is a dislocation whose Burgers vector equals a lattice vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Unit dislocation\"进行文字解释和论述，答案提供了定义性的描述，符合简答题的特征。 | 知识层次: 题目考查对单位位错（unit dislocation）这一基本概念的定义记忆，属于材料科学中位错理论的基础知识，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答单位位错的基本定义，属于最基础的概念记忆性知识。题目不涉及概念的解释、比较或复杂体系的阐述，仅需直接复述定义即可完成作答，因此属于该题型内最低难度等级。" + }, + { + "idx": 1392, + "question": "What are the adverse effects of the work hardening characteristics of metals on the use of metal materials?", + "answer": "It makes the metal difficult to undergo further cold plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属加工硬化特性的不利影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析加工硬化特性对金属材料使用的不利影响，需要理解加工硬化的基本原理，并将其与实际应用中的问题关联起来，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及金属材料的工作硬化特性及其不利影响，但答案仅需简要说明其对冷塑性变形的限制作用，无需多角度分析或深度关联其他概念。解题步骤相对简单，主要考察对工作硬化基本概念的理解和应用。" + }, + { + "idx": 1393, + "question": "Calculate the coordination number of the cation in the compound Cr2O3, given r(Cr3+)=0.064nm, r(O2-)=0.132nm", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数据进行数值计算，应用配位数计算公式，最终得出具体的数值结果6。这符合计算题的特征。 | 知识层次: 题目要求计算Cr2O3中阳离子的配位数，涉及离子半径比的计算和配位数判断，属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用离子半径比公式（r+/r-）来计算配位数，且给定的离子半径数据可以直接代入公式得出结果，无需额外的复杂步骤或公式组合。" + }, + { + "idx": 1394, + "question": "Calculate the coordination number of the cation in the compound CaF2, given r(Ca2+)=0.106nm and r(F-)=0.133nm", + "answer": "8", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数值进行计算，以确定CaF2中阳离子的配位数，答案是一个具体的数值（8），需要通过公式或计算得出。 | 知识层次: 题目要求应用离子半径比和配位数之间的基本关系进行计算，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要根据给定的离子半径数据，直接应用配位数计算公式（半径比规则）即可得出结果，无需多个公式组合或复杂的推导步骤。" + }, + { + "idx": 1395, + "question": "Calculate the coordination number of the cation in the compound K2O, given r(K+)=0.132nm, r(O2-)=0.132nm", + "answer": "12", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数值计算配位数，需要应用相关公式进行数值计算，最终得出具体数字答案12 | 知识层次: 题目需要应用离子半径比和配位数之间的基本关系进行计算，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，只需要直接应用半径比公式计算配位数，无需多个公式组合或复杂步骤。题目中给出的离子半径相同，可以直接套用简单的配位数计算公式得出结果。" + }, + { + "idx": 1396, + "question": "Determine whether the following statement is correct: After recovery annealing of cold-deformed metal, its mechanical properties can return to the state before deformation.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征。 | 知识层次: 题目考查对冷变形金属恢复退火后机械性能变化的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然题目涉及的是基础概念（恢复退火对冷变形金属力学性能的影响），但需要学生理解恢复退火和再结晶的区别，以及它们对材料性能的不同影响。这比简单记忆定义（等级1）要求更高，但又不涉及多个概念的复杂分析（等级3）。学生需要知道恢复退火只能部分消除内应力，而不能完全消除加工硬化效应，才能使力学性能恢复到变形前的状态。" + }, + { + "idx": 1397, + "question": "What basic conditions must be met for atomic diffusion in solids?", + "answer": "Atomic diffusion in solids requires the presence of a chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释原子扩散在固体中发生的基本条件，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查原子扩散的基本条件，属于基本原理的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答原子扩散的基本条件，即化学势梯度的存在，不需要进行概念解释或复杂体系阐述。这属于最基础的概念记忆性知识，符合等级1的难度标准。" + }, + { + "idx": 1398, + "question": "According to the concentration distribution of the diffusing component, what are the basic types of diffusion?", + "answer": "Self-diffusion and interdiffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的基本类型，需要文字回答，而不是选择、判断或计算 | 知识层次: 题目考查扩散的基本类型分类，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答扩散的基本类型（自扩散和互扩散），属于最基础的定义简答。不需要额外的解释或复杂概念阐述，完全符合等级1\"基本定义简答\"的标准。在同类记忆性知识简答题中，这是最基础、最直接的考查形式。" + }, + { + "idx": 1399, + "question": "Determine whether the following statement is correct: Edge dislocations can undergo cross-slip.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了正确与否的判断（Incorrect），符合判断题的特征。 | 知识层次: 题目考查对位错基本行为（刃位错能否发生交滑移）的记忆和理解，属于基础概念范畴 | 难度: 在判断题中属于中等难度，需要理解边缘位错的基本特性及其滑移机制，虽然不涉及复杂概念，但需要将定义性知识与具体现象（交滑移）进行关联判断，比单纯记忆定义（等级1）要求更高。" + }, + { + "idx": 1400, + "question": "According to the path of atomic diffusion, what are the basic types of diffusion?", + "answer": "Bulk diffusion, grain boundary diffusion, dislocation diffusion, surface diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举原子扩散的基本类型，答案以文字形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查原子扩散路径的基本分类，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题中属于基本定义简答，仅需回忆并列举扩散的基本类型，无需深入解释或复杂论述，符合基础概念记忆的要求。" + }, + { + "idx": 1401, + "question": "Determine whether the following statement is correct: The distinction between hot (deformation) working and cold (deformation) working of metals is based on the temperature of the deformation process.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出\"Incorrect\"表明该陈述是错误的，符合判断题的特征。 | 知识层次: 题目考查金属热加工和冷加工的基本定义和分类，属于基础概念的记忆和理解范畴。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目仅考察对金属热加工和冷加工定义的基本记忆，不需要深入理解或分析多个概念。属于该题型内最基础的难度等级。" + }, + { + "idx": 1402, + "question": "Determine whether the following statement is correct: Recrystallization is a process of nucleation and core growth, therefore it is a phase transformation process.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征。 | 知识层次: 题目考查对再结晶过程是否属于相变过程这一基本概念的理解和记忆，不涉及复杂分析或综合应用。 | 难度: 在判断题中属于中等难度，虽然涉及的是基础概念记忆，但需要理解\"再结晶\"过程的本质（形核与晶核生长）以及其与\"相变过程\"的定义关系，不能仅靠字面记忆判断。考生需明确再结晶是组织重构而非相结构改变，属于概念理解层面的判断。" + }, + { + "idx": 1403, + "question": "Determine whether the following statement is correct: The growth of recrystallization nuclei is accompanied by the movement of grain boundaries, so the driving force is grain boundary energy.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案直接给出了对错判断（Incorrect），符合判断题的特征 | 知识层次: 题目涉及再结晶核生长和晶界移动的驱动力的判断，需要理解再结晶过程中的能量变化和晶界行为，属于对基本原理的综合应用和分析，但不需要复杂的推理或创新思维。 | 难度: 在判断题中属于较高难度，需要综合分析再结晶核生长过程中的驱动力来源，涉及对晶界能和应变能等概念的理解和关联判断。题目不仅要求判断陈述的正误，还需要理解再结晶驱动力与晶界移动之间的关系，属于综合分析结果判断的层次。" + }, + { + "idx": 1404, + "question": "According to the microscopic mechanism of diffusion, what are the basic types of diffusion?", + "answer": "Interstitial diffusion and vacancy diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的基本类型，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查扩散机制的基本分类，属于基础概念的记忆和理解层面，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答扩散的基本类型（间隙扩散和空位扩散），属于最基础的定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可完成，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1405, + "question": "Determine whether the following statement is correct: Point defects in crystals are a type of thermodynamic equilibrium defect, while dislocations are not thermodynamic equilibrium defects.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Correct\"这一判断结果，符合判断题的特征 | 知识层次: 题目考查对晶体缺陷类型及其热力学平衡性质的基本概念记忆和理解，属于基础概念记忆层次。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然题目涉及晶体缺陷的基本概念，但需要考生理解点缺陷和位错在热力学平衡状态下的不同性质，而不仅仅是记忆定义。这比单纯判断基本概念正误（等级1）稍难，但不需要进行复杂概念陈述的判断（等级3）。" + }, + { + "idx": 1406, + "question": "According to the relationship between the diffusion direction of components and their concentration gradient direction, what are the basic types of diffusion?", + "answer": "Downhill diffusion and uphill diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的基本类型，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查扩散基本类型的记忆和理解，属于基础概念的分类和定义范畴 | 难度: 在简答题题型中，该题目仅要求回答扩散的基本类型，属于基础定义简答。题目直接询问分类结果，不需要进行概念解释或复杂体系阐述，符合等级1的基本定义简答要求。" + }, + { + "idx": 1407, + "question": "According to whether new phases are formed during diffusion, what are the basic types of diffusion?", + "answer": "Single-phase diffusion and reactive diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据扩散过程中是否形成新相来分类扩散的基本类型，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查扩散基本类型的记忆和理解，属于基础概念的分类知识 | 难度: 在简答题题型中，该题目仅要求回答扩散的基本类型（单相扩散和反应扩散），属于最基础的定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可作答，符合等级1\"基本定义简答\"的标准。在同题型内属于最基础难度层级。" + }, + { + "idx": 1408, + "question": "In interstitial solid solutions, by what mechanism do solute atoms diffuse?", + "answer": "In interstitial solid solutions, solute atoms diffuse by the interstitial mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对扩散机制进行文字解释和论述，答案以简短的文字形式给出，没有选项或计算要求。 | 知识层次: 题目考查对间隙固溶体中溶质原子扩散机制的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义和机制，属于最基础的概念记忆性知识，不需要额外的解释或复杂概念体系的阐述。解题步骤简单，仅需直接回忆并陈述\"间隙扩散机制\"这一单一知识点即可。" + }, + { + "idx": 1409, + "question": "In substitutional solid solutions, by what mechanism do solute atoms diffuse?", + "answer": "In substitutional solid solutions, solute atoms diffuse by the vacancy mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述溶质原子在置换固溶体中的扩散机制，答案是一个完整的句子解释，不需要选择、判断或计算。 | 知识层次: 题目考查对置换固溶体中溶质原子扩散机制的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（空位扩散机制），属于最基础的概念记忆层面。不需要解释或阐述复杂概念体系，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这属于直接调用记忆性知识即可作答的典型低难度题目。" + }, + { + "idx": 1410, + "question": "What type of diffusion is the growth of uniform austenite grains?", + "answer": "The growth of uniform austenite grains belongs to self-diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对特定概念（self-diffusion）进行解释和论述，而不是从选项中选择或判断对错，也不需要数值计算 | 知识层次: 题目考查对扩散类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"均匀奥氏体晶粒生长\"所属的扩散类型，需要学生理解并描述自扩散(self-diffusion)的概念，但不需要进行复杂的体系阐述或深入分析。这比单纯记忆基本定义(等级1)要求更高，但低于需要阐述多个相关概念的复杂问题(等级3)。" + }, + { + "idx": 1411, + "question": "What type of diffusion does the homogenization of intracrystalline segregation during diffusion annealing belong to?", + "answer": "The homogenization of intracrystalline segregation during diffusion annealing belongs to interdiffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对扩散退火过程中晶内偏析的均匀化类型进行解释，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查扩散类型的基本概念记忆和分类理解，属于基础概念记忆层次 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释扩散退火过程中晶内偏析均匀化的扩散类型，需要学生对\"interdiffusion\"这一概念有明确的理解和描述能力，但不需要进行复杂的概念体系阐述或深入分析。这属于基础概念记忆层次中需要一定解释能力的题目，但解题步骤和知识点掌握深度要求适中。" + }, + { + "idx": 1412, + "question": "By what mechanism do metal materials conduct heat?", + "answer": "Metal materials mainly conduct heat through free electrons", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属材料导热的具体机制，答案以文字论述形式给出，不需要选择、判断或计算 | 知识层次: 题目考查金属材料导热的基本机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答金属材料导热的基本机制，答案只需简单提及自由电子的作用即可，不需要深入解释或描述复杂概念体系。这符合基础概念记忆的知识层次要求，属于该题型内最基础的难度等级。" + }, + { + "idx": 1413, + "question": "Will thermoplastic with a lower glass transition temperature (Tg) exhibit 'work hardening' after deformation? Please briefly explain.", + "answer": "Thermoplastics with a lower glass transition temperature will exhibit 'work hardening' after deformation. This is because as the degree of deformation increases, the molecular chains gradually align along the direction of the external force, leading to strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对现象进行解释和论述，答案提供了详细的文字说明，符合简答题的特征 | 知识层次: 题目要求解释热塑性塑料在变形后表现出\"加工硬化\"现象的原因，涉及玻璃化转变温度与分子链排列的关系，需要将多个概念关联并进行综合分析。虽然不涉及复杂计算，但需要对材料变形机理有一定理解，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解玻璃化转变温度与应变硬化之间的关系，并进行综合分析说明。题目要求解释热塑性塑料在变形后是否表现出\"加工硬化\"现象，并简要说明原因。这涉及到对材料科学中基本概念的理解和应用，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1414, + "question": "What is the electron magnetic moment?", + "answer": "The electron magnetic moment refers to the orbital magnetic moment generated by the electron's motion around the nucleus and the spin magnetic moment produced by the electron's spin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对电子磁矩进行解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查电子磁矩的基本定义和组成，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目要求解释电子磁矩的概念，包括轨道磁矩和自旋磁矩两部分。这属于概念解释和描述的难度等级，需要学生对相关概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。" + }, + { + "idx": 1415, + "question": "Will ceramic materials exhibit 'work hardening' after deformation? Please briefly explain.", + "answer": "Ceramic materials will not exhibit 'work hardening' after deformation, because ceramic materials cannot undergo plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对陶瓷材料是否表现出\"work hardening\"进行简要解释，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查对陶瓷材料基本特性的记忆和理解，即陶瓷材料是否能够发生塑性变形以及是否表现出加工硬化现象。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释陶瓷材料为何不会表现出\"加工硬化\"现象，需要理解并描述陶瓷材料的基本特性（如缺乏塑性变形能力）与加工硬化之间的关系。虽然涉及基本原理的记忆，但不需要复杂的体系阐述或多概念交叉分析，属于中等难度的概念解释类简答题。" + }, + { + "idx": 1416, + "question": "By what mechanism do polymer materials conduct heat?", + "answer": "Polymer materials mainly conduct heat through molecular conduction", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料传导热量的机制，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查聚合物材料导热机制的基本概念，属于基本原理的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述聚合物材料导热的基本机制（分子传导），无需深入解释或复杂概念体系的阐述。题目仅考察对基础概念的记忆能力，不涉及分析或综合等高阶认知技能。" + }, + { + "idx": 1417, + "question": "What conditions must be satisfied for spontaneous dislocation reactions?", + "answer": "Geometric conditions and energy conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释自发位错反应必须满足的条件，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目要求解释位错反应的自发条件，涉及几何条件和能量条件的综合分析，需要理解位错反应的基本原理并关联多个概念，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释和论述两个主要条件（几何条件和能量条件），但不需要进行多角度或深度关联性分析。题目要求的知识点掌握深度适中，解题步骤相对直接，主要考察对基本概念的理解和应用能力。" + }, + { + "idx": 1418, + "question": "What is atomic magnetic moment?", + "answer": "Atomic magnetic moment refers to the total magnetic moment composed of the orbital magnetic moment and the spin magnetic moment of electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对原子磁矩进行文字解释和论述，答案提供了详细的定义和组成部分，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即原子磁矩的定义和组成，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答原子磁矩的基本定义，属于最基础的概念记忆层面。不需要解释或描述相关概念之间的关系，也不涉及复杂概念体系的阐述。解题步骤简单直接，只需回忆并复述定义即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1419, + "question": "The bonding type of a material determines the level of its elastic modulus. What type of bond predominates in oxide ceramic materials, how strong is the bonding, and thus how is their elastic modulus?", + "answer": "Oxide ceramic materials are predominantly ionic bonded, with strong bonding, hence their elastic modulus is relatively high.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释氧化物陶瓷材料的主要键合类型、键合强度及其对弹性模量的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对氧化物陶瓷材料中主要键合类型及其对弹性模量影响的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释氧化物陶瓷材料的主要键合类型、键合强度及其对弹性模量的影响，这需要学生对基本概念（如离子键、键合强度与弹性模量的关系）有一定的理解和记忆，并进行简单的逻辑连接。虽然涉及多个知识点，但不需要复杂的体系阐述或深入分析，因此属于等级2。" + }, + { + "idx": 1420, + "question": "What is the difference in the conduction mechanisms between intrinsic semiconductors and doped semiconductors?", + "answer": "In intrinsic semiconductors, the charge carriers participating in conduction are electrons in the conduction band and an equal number of holes in the valence band, with the Fermi level located at the center of the band gap. In doped semiconductors, the charge carriers participating in conduction are electrons in the conduction band and an unequal number of holes in the valence band, with the Fermi level not located at the center of the band gap—either shifting upward (as in $\\mathbf{n}$-type semiconductors) or downward (as in p-type semiconductors).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释本征半导体和掺杂半导体的导电机制差异，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求解释本征半导体和掺杂半导体的导电机制差异，涉及多个概念的关联和综合分析，如费米能级位置、载流子类型和数量等，需要一定的理解和应用能力，但不需要复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目要求对半导体传导机制进行多角度分析论述。需要同时解释本征半导体和掺杂半导体的传导机制差异，包括载流子类型、数量关系以及费米能级位置的变化。这涉及多个概念的关联和综合分析，超出了基础概念解释的范畴，但尚未达到需要深度关联性分析的等级5水平。" + }, + { + "idx": 1421, + "question": "The type of bonding in a material determines the level of its elastic modulus. What type of bond is present along the molecular chains of polymer materials, and what type of bond exists between the molecular chains, hence how is their elastic modulus?", + "answer": "The bonds along the molecular chains of polymer materials are covalent bonds, and the bonds between the molecular chains are molecular bonds, hence their elastic modulus is the lowest.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物材料中分子链内和分子链间的键类型及其对弹性模量的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对聚合物材料中键合类型及其对弹性模量影响的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题中属于中等难度，需要解释两种不同类型的化学键（共价键和分子键）及其对材料弹性模量的影响。虽然涉及多个概念，但题目明确指出了需要回答的内容，且不需要进行复杂的推导或深入的分析。" + }, + { + "idx": 1422, + "question": "What is the relationship between the magnetic properties of a substance and the filling of electrons outside the atomic nucleus?", + "answer": "Substances with completely filled electron shells in atoms are diamagnetic; substances with unfilled electron shells in atoms are paramagnetic or ferromagnetic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释电子填充与物质磁性之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是关于物质磁性与电子填充状态之间关系的基本概念记忆和理解，属于定义和分类的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释物质的磁性与原子核外电子填充状态的关系，涉及对顺磁性、抗磁性和铁磁性等基本概念的理解和描述。虽然需要一定的知识整合，但不需要复杂的体系阐述或深入分析，属于中等难度的概念解释类简答题。" + }, + { + "idx": 1423, + "question": "Write the names and reaction formulas of all possible three-phase equilibrium reactions in a binary phase diagram.", + "answer": "Eutectic reaction: $\\\\operatorname{L}{\\\\overrightarrow{\\\\longrightarrow}}\\\\alpha+\\\\beta$ Eutectoid reaction: $\\\\gamma\\\\mathrm{=}\\\\mathrm{=}\\\\alpha+\\\\beta$ Monotectic reaction: $\\\\mathrm{L}_{1}\\\\longrightarrow\\\\mathrm{L}_{2}+\\\\updelta$ Syntectic reaction: $\\\\updelta\\\\rightleftharpoons\\\\mathbf{L}+\\\\upgamma$ Peritectic reaction: $\\\\mathbf{L}+\\\\alpha{\\\\stackrel{\\\\rightharpoonup}{\\\\longrightarrow}}\\\\beta$ Peritectoid reaction: $\\\\gamma+\\\\alpha{\\\\stackrel{\\\\textstyle}{\\\\longrightarrow}}\\\\beta$ Syntectic reaction: $\\\\mathrm{L}_{1}+\\\\mathrm{L}_{2}\\\\stackrel{\\\\rightharpoonup}{\\\\longrightarrow}\\\\delta$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出所有可能的三相平衡反应名称和反应式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对二元相图中三相平衡反应类型及其反应式的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求列举并写出所有可能的三相平衡反应名称和反应式，涉及多个复杂概念（共晶、共析、偏晶、合晶、包晶、包析等）的准确记忆和区分。需要考生掌握完整的二元相图反应类型体系，并能准确表述各反应的特征方程式。这超出了基础定义简答（等级1）和单一概念解释（等级2）的范畴，属于需要对复杂概念体系进行系统阐述的高阶要求。" + }, + { + "idx": 1424, + "question": "By what mechanism do ceramic materials conduct heat?", + "answer": "Ceramic materials primarily conduct heat through phonons", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释陶瓷材料传导热量的机制，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查陶瓷材料导热机制的基本概念，仅需记忆和理解\"phonons\"这一基本原理即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答陶瓷材料导热的主要机制（声子传导），不涉及概念解释或复杂体系阐述。这属于最基础的概念记忆性知识，符合等级1对定义性知识点的要求。" + }, + { + "idx": 1425, + "question": "What is an extended dislocation? Please give an example.", + "answer": "A dislocation configuration consisting of two partial dislocations and a stacking fault sandwiched between them. For example, in face-centered cubic crystals, $\\\\frac{a}{6}$ [121] $^+$ stacking fault $+{\\\\frac{a}{6}}$ [211].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"extended dislocation\"进行定义并举例说明，答案提供了详细的文字解释和具体例子，符合简答题的特征。 | 知识层次: 题目考查扩展位错的基本定义和示例，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释扩展位错的定义并举例说明，涉及概念解释和具体实例描述。虽然需要记忆和理解相关概念，但不需要复杂的体系阐述或深入分析，属于中等难度的概念解释题。" + }, + { + "idx": 1426, + "question": "What is the intrinsic magnetic moment of a substance?", + "answer": "The intrinsic magnetic moment of a substance refers to the sum of all atomic magnetic moments in the absence of an external magnetic field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“intrinsic magnetic moment”进行文字解释和论述，答案提供了概念的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对\"本征磁矩\"这一基本概念的定义和记忆，属于材料科学中磁学基础知识的范畴，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。不需要进行概念解释或复杂体系阐述，仅需直接复述\"本征磁矩\"的定义即可。符合等级1\"基本定义简答\"的标准，是该题型中最简单的难度级别。" + }, + { + "idx": 1427, + "question": "Which is the most closely packed plane in a face-centered cubic crystal?", + "answer": "111", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别最密排面，需要专业知识判断而非计算或选择，答案以特定晶面指数形式给出 | 知识层次: 题目考查对晶体结构中密排面的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答最密排面的晶面指数（111），属于基础概念记忆层面的直接问答。不需要解释或论述密排面的形成原理、堆积方式等深层概念，也不涉及多步骤推导或复杂概念体系阐述。同类简答题中属于最基础的晶格几何知识再现，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1428, + "question": "What is the most close-packed direction in a face-centered cubic crystal?", + "answer": "<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的晶体学方向（<110>），虽然答案简短，但需要基于对晶体结构的理解进行解释，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对晶体结构中密排方向的基础概念记忆，仅需回忆面心立方晶体中最密排方向为<110>，无需复杂分析或计算。 | 难度: 在简答题题型中，该题目属于基础概念记忆层次，仅需回答最密排方向<110>即可，不需要额外的解释或论述步骤。这符合等级1\"基本定义简答\"的标准，是同类题型中最简单的类型。" + }, + { + "idx": 1429, + "question": "The type of bonding in a material determines the level of its elastic modulus. What type of bond predominates in metallic materials, how strong is the bonding, and consequently, what is their elastic modulus like?", + "answer": "Metallic materials are primarily bonded by metallic bonds, which are relatively weak, resulting in a lower elastic modulus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属材料中的主要键合类型、键合强度及其对弹性模量的影响，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查金属材料中主要键合类型及其对弹性模量的影响，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释金属材料中的主要键合类型、键合强度及其对弹性模量的影响，这需要学生对金属键的基本概念及其性质有一定的理解和记忆，但不需要复杂的体系阐述或多概念综合分析。" + }, + { + "idx": 1430, + "question": "Which is the most closely packed plane of a body-centered cubic crystal?", + "answer": "110", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求识别最紧密堆积的晶面，需要基于晶体结构的知识进行解释和论述，答案虽然简短但需要理论支持。 | 知识层次: 题目考查对体心立方晶体最密排面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目涉及晶体结构的基础概念，但需要学生不仅记忆最密排面的指数（110），还需要理解体心立方晶体中不同晶面的堆积密度差异。这比单纯回答定义（等级1）要求更高的理解，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1431, + "question": "The commonly used method to refine grains in casting processes is (19)", + "answer": "(19) Increasing the cooling rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个简短的答案（\"Increasing the cooling rate\"），而不是从多个选项中选择或进行判断/计算。虽然看起来像填空题，但更符合简答题的特征，因为需要特定知识来回答。 | 知识层次: 题目考查的是铸造过程中细化晶粒的常用方法，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，此题属于基本定义简答级别。题目仅要求回忆铸造工艺中细化晶粒的常用方法（增加冷却速率），不需要进行概念解释或复杂体系阐述。答案直接对应基础概念记忆层次，解题步骤简单，属于该题型内最基础的难度等级。" + }, + { + "idx": 1432, + "question": "What is the most densely packed direction in a body-centered cubic crystal?", + "answer": "<111>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答最密排方向，答案是一个晶体学方向<111>，不需要计算或选择，属于需要特定知识点的简短回答 | 知识层次: 题目考查对体心立方晶体中最密堆积方向的基本概念记忆，属于晶体学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答最密排方向，不需要解释或推导过程，属于晶体学中最基础的概念记忆内容。在\"基础概念记忆\"知识层次中，这是最直接的知识点复现，没有涉及概念关联或体系化阐述的要求。" + }, + { + "idx": 1433, + "question": "What is the most closely packed direction in a hexagonal close-packed crystal?", + "answer": "<1120>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的晶体学方向，需要专业知识来识别最紧密堆积方向，答案是一个晶体学方向符号，属于简答题类型 | 知识层次: 题目考查对六方密堆积晶体中最密排方向的基础概念记忆，属于晶体学中的基本知识点，不需要复杂的分析或计算。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回答最密排方向的具体指数，不需要进行概念解释或复杂体系阐述。在六方密堆积晶体结构中，<1120>方向是最基础、最直接需要记忆的密排方向之一，属于晶体学中最基础的知识点。" + }, + { + "idx": 1434, + "question": "A metal with finer grains has (16)_ strength and hardness compared to the same metal with coarser grains", + "answer": "(16) higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（higher）来补全句子，属于简答题类型，需要根据知识进行简要回答而非选择或判断 | 知识层次: 题目考查金属晶粒尺寸与力学性能关系的基本概念记忆，属于材料科学中最基础的知识点，仅需记忆和理解Hall-Petch关系即可作答。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求记忆并复述金属晶粒尺寸与力学性能的基本关系（细晶强化原理），不需要进行概念解释或复杂体系阐述。答案只需填写\"higher\"这个单一关键词，完全属于定义性知识的直接回忆，没有推理或分析要求。在同题型内属于最基础的难度等级。" + }, + { + "idx": 1435, + "question": "Ferrite is a solid solution of carbon in what type of iron?", + "answer": "α", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的术语（α铁），不需要从多个选项中选择，也不需要判断对错或进行数值计算，符合简答题的特征。 | 知识层次: 题目考查对铁素体（Ferrite）基本定义的记忆，即碳在α铁中的固溶体。这属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（α铁），属于最基础的概念记忆层面，无需解释或描述其他相关内容，解题步骤极其简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1436, + "question": "Metals with finer grains have _ (17) plasticity and toughness than the same metals with coarser grains", + "answer": "(17) better", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（better）来补全句子，属于简短的文字回答形式，不需要选择、判断或计算 | 知识层次: 题目考查金属晶粒尺寸对塑性和韧性影响的基本概念记忆，属于材料科学基础知识的直接应用，不需要复杂分析或多步推理。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求填写一个关键词（better）来补全关于晶粒尺寸与金属性能关系的常识性表述，不需要展开解释或论述。考查的是对\"细晶强化\"这一基础概念的机械记忆，属于材料科学中最基础的知识点之一。在简答题的三个难度等级中，这明显是最基础的等级1难度。" + }, + { + "idx": 1437, + "question": "Which is the most closely packed plane in a hexagonal close-packed crystal?", + "answer": "(0001)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别最密排面，答案是一个特定的晶面指数(0001)，不需要计算或选择，属于需要特定知识回答的简答题类型 | 知识层次: 题目考查对六方密堆积晶体中最密排面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并准确回答最密排面的晶面指数(0001)，不涉及概念解释或复杂体系阐述，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 1438, + "question": "The commonly used method for refining grains in casting processes is (20)", + "answer": "(20) Adding nucleating agents", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个简短的答案（\"Adding nucleating agents\"），而不是从多个选项中选择、判断对错或进行数值计算 | 知识层次: 题目考查对铸造过程中细化晶粒常用方法的基础概念记忆，属于基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答类型，仅需记忆并准确回答\"Adding nucleating agents\"这一基础概念即可，无需进行概念解释或复杂体系阐述。题目直接考察对铸造工艺中晶粒细化常用方法的记忆，属于该题型内最基础的知识点考察。" + }, + { + "idx": 1439, + "question": "The commonly used method for refining grains in casting processes is (21)", + "answer": "(21) stirring or vibration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个简短的答案（stirring or vibration），而不是从多个选项中选择或判断对错，也不需要计算或详细论述。 | 知识层次: 题目考查铸造过程中细化晶粒的常用方法，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答铸造过程中常用的细化晶粒方法，答案（搅拌或振动）是基础概念的直接记忆，不需要解释或论述复杂原理。这符合等级1对定义性知识简单回忆的要求。" + }, + { + "idx": 1440, + "question": "What is the solid solution method of carbon in ferrite?", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释碳在铁素体中的固溶方式，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查碳在铁素体中的固溶方式，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答碳在铁素体中的固溶方式这一基础概念，不需要进行概念解释或复杂体系阐述。答案\"Interstitial\"是材料科学中最基础的概念之一，属于记忆性知识范畴，符合等级1对知识点掌握深度和解题步骤简单性的要求。" + }, + { + "idx": 1441, + "question": "A metal with finer grains exhibits this phenomenon compared to the same metal with coarser grains, which is called (18) strengthening", + "answer": "(18) fine grain", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（fine grain）来补全句子，属于需要简短文字回答的题目类型 | 知识层次: 题目考查对细晶强化这一基础概念的简单记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写一个特定的术语（fine grain strengthening），这只需要学生对材料科学中的基本概念有记忆即可回答，不需要进行深入的解释或复杂的论述。因此，在简答题的框架内，这道题的难度较低，属于等级1。" + }, + { + "idx": 1442, + "question": "For an edge dislocation line, what is the relationship between its climb direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释边缘位错线的攀移方向与其Burgers矢量之间的关系，答案需要文字描述（\"Perpendicular\"），属于简答题类型 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是刃位错的攀移方向与伯氏矢量之间的关系。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（位错攀移方向与伯氏矢量的关系），属于最基础的概念记忆层面，无需解释或论述复杂概念体系。" + }, + { + "idx": 1443, + "question": "For a screw dislocation line, what is the relationship between its Burgers vector and the dislocation line?", + "answer": "Parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺位错线的Burgers矢量与位错线之间的关系，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对螺位错基本性质的理解，即其柏氏矢量与位错线方向的关系，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目仅要求回答螺位错的柏氏矢量与位错线的关系（平行），属于最基础的定义性知识，无需解释或论述过程，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于仅需记忆即可作答的入门级问题。" + }, + { + "idx": 1444, + "question": "What strengthening mechanism results in the change of ferrite properties?", + "answer": "Solid solution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种强化机制导致铁素体性能变化，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查的是对铁素体性能变化强化机制的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答一个基本定义（固溶强化机制），属于最基础的概念记忆层面，无需解释或展开论述，符合等级1\"基本定义简答\"的标准。相比需要描述机理（等级2）或分析多因素交互作用（等级3）的简答题，此题仅需直接回忆单一术语，是同类题型中最简单的表现形式。" + }, + { + "idx": 1445, + "question": "There are five possible types of cementite in iron-carbon alloys, listed in order of formation temperature from high to low: (22) cementite, (23) cementite, (24) cementite, (25) cementite, and (26) cementite.", + "answer": "(22) primary; (23) eutectic; (24) secondary; (25) eutectoid; (26) tertiary;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定术语（如primary, eutectic等）来完整描述不同类型的cementite，属于需要文字回答的简答题形式，而非选择题或判断题。 | 知识层次: 题目考查对铁碳合金中不同类型渗碳体的分类和形成温度顺序的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求考生回忆并列举五种不同类型渗碳体的形成温度顺序及其名称。虽然涉及多个概念的记忆，但不需要深入解释或复杂推理，属于概念解释和描述的难度级别。" + }, + { + "idx": 1446, + "question": "For a screw dislocation line, what is the relationship between its cross-slip motion direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺丝位错线的交叉滑移运动方向与Burgers矢量之间的关系，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对螺型位错基本性质的理解，特别是其滑移方向与伯格斯矢量之间的关系，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目仅要求回答基本定义关系（\"Perpendicular\"），属于最基础的概念记忆层面，无需解释或论述复杂机制。同类题型中，这属于直接调用单一知识点的最低难度级别。" + }, + { + "idx": 1447, + "question": "For an edge dislocation line, what is the relationship between the direction of its slip motion and the Burgers vector?", + "answer": "Parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释刃位错线的滑移方向与伯格斯矢量之间的关系，需要文字论述而非选择或判断 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是刃位错的滑移方向与伯氏矢量之间的关系，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答刃位错滑移方向与伯氏矢量的关系（平行），不涉及概念解释或复杂体系阐述，属于最基础的概念记忆性知识。在同类简答题中，这是最直接、最简单的回答要求。" + }, + { + "idx": 1448, + "question": "Compared to pure iron, how do the plasticity and toughness of ferrite change?", + "answer": "Lower", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的塑性和韧性变化，需要文字论述而非简单选择或判断 | 知识层次: 题目考查对纯铁和铁素体塑性及韧性差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求比较纯铁和铁素体的塑性和韧性变化，答案只需给出\"Lower\"这一简单结论，无需展开解释或论述。这完全属于基础概念记忆层面的问题，在简答题中是最基础、最简单的类型。" + }, + { + "idx": 1449, + "question": "Compared to pure iron, how do the strength and hardness of ferrite change?", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的强度和硬度变化，答案需要文字论述而非简单选择或判断 | 知识层次: 题目考查对纯铁和铁素体强度与硬度差异的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对纯铁和铁素体的强度硬度进行简单比较，属于最基础的定义性知识问答。题目不涉及概念解释或复杂体系阐述，仅需记忆性回答\"Higher\"即可，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1450, + "question": "For a screw dislocation line, what is the relationship between its slip direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺位错线的滑移方向与伯格斯矢量之间的关系，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对螺位错滑移方向与伯格斯矢量关系的基本概念记忆和理解，属于材料科学中位错理论的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，此题仅要求回答螺型位错线的滑移方向与伯氏矢量之间的关系（垂直），属于最基本的概念记忆性知识。不需要额外的解释或论述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最基础的知识点考察，不涉及概念解释或复杂体系阐述。" + }, + { + "idx": 1451, + "question": "For an edge dislocation line, what is the relationship between its Burgers vector and the dislocation line?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释刃位错线的Burgers矢量与位错线之间的关系，答案需要文字描述（\"Perpendicular\"），属于简答题类型 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是柏氏矢量与位错线方向关系的定义性知识，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（柏氏矢量与位错线的关系），属于最基础的概念记忆层面，不需要额外的解释或复杂论述，符合等级1的基本定义简答标准。" + }, + { + "idx": 1452, + "question": "For a mixed dislocation line, what is the relationship between its Burgers vector and the dislocation line?", + "answer": "Neither perpendicular nor parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释混合位错线的柏氏矢量与位错线之间的关系，需要文字描述而非选择、判断或计算 | 知识层次: 题目考查对混合位错线的基本概念的理解，即其Burgers矢量与位错线方向的关系，属于基础概念的记忆和理解范畴。 | 难度: 在简答题中属于中等难度，需要理解混合位错线的概念，并明确其柏氏矢量与位错线之间的关系。虽然不涉及复杂的推导或计算，但需要对基本概念有一定的理解和描述能力，属于概念解释和描述的范畴。" + }, + { + "idx": 1453, + "question": "After cold plastic deformation, the strength and hardness of metal (40)", + "answer": "increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答金属在冷塑性变形后的强度和硬度变化，答案是一个简短的描述性词语\"increase\"，符合简答题的特征。 | 知识层次: 题目考查金属冷塑性变形后强度和硬度变化的基本概念记忆，属于基础概念层次，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答，仅需记忆金属冷塑性变形后强度和硬度的变化趋势，无需深入解释或复杂论述。属于该题型内最基础的难度等级。" + }, + { + "idx": 1454, + "question": "After cold plastic deformation of metal, its plasticity and toughness (41)", + "answer": "decrease", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对金属冷塑性变形后的塑性和韧性变化进行简要回答，答案形式为简短的文字描述，而非选择、判断或计算。 | 知识层次: 题目考查金属冷塑性变形后性能变化的基本概念记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答金属冷塑性变形后塑性和韧性的变化，属于基础概念记忆层面的直接简答。不需要解释原因或描述机制，仅需记忆\"decrease\"这一标准答案即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1455, + "question": "For a mixed dislocation line, what is the relationship between the direction of its slip motion and the dislocation line?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释混合位错线的滑移方向与位错线之间的关系，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对混合位错线滑移运动方向与位错线方向关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答混合位错线滑移运动方向与位错线的关系，属于基础定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆基本原理即可作答，符合等级1的基本定义简答标准。" + }, + { + "idx": 1456, + "question": "After metal undergoes cold plastic deformation, this phenomenon is called (42) strengthening or (43)", + "answer": "deformation; work hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空白处的术语，需要考生回忆并准确写出专业术语，属于简答题类型 | 知识层次: 题目考查金属冷塑性变形后的强化现象的基本概念记忆，即变形强化和加工硬化的术语。这属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并填写两个基础术语（变形强化和加工硬化），无需解释或论述概念关系。题目仅测试对冷塑性变形后现象的术语记忆，属于该题型下最基础的知识点考查。" + }, + { + "idx": 1457, + "question": "For metals that have undergone pre-cold plastic deformation, (44) annealing should be performed before further cold plastic deformation to improve their (45)", + "answer": "recrystallization; plasticity and toughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求填写特定的术语（recrystallization; plasticity and toughness）来回答问题，属于需要简短文字回答的简答题类型。 | 知识层次: 题目要求将冷塑性变形和退火处理的概念关联起来，并理解再结晶退火对金属塑性和韧性的影响，属于中等应用层次的知识点。需要综合分析冷变形和热处理之间的关系，而不仅仅是记忆基础概念。 | 难度: 在简答题中属于中等难度，需要理解金属冷塑性变形后的再结晶退火过程及其对材料性能的影响。题目要求考生综合运用材料科学知识，解释为何在进一步冷塑性变形前需要进行再结晶退火，并说明其对塑性和韧性的改善作用。虽然涉及多个概念，但不需要深入的多角度分析或复杂的关联性论述。" + }, + { + "idx": 1458, + "question": "For metals that have undergone pre-cold plastic deformation, recrystallization annealing should be performed before further cold plastic deformation, and the annealing temperature is (46)", + "answer": "0.4Tm", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（0.4Tm），这属于需要简短回答的问题，而不是从多个选项中选择或判断对错。虽然涉及数值，但不需要复杂的计算过程，因此归类为简答题更合适。 | 知识层次: 题目考查的是对金属材料再结晶退火温度的基本概念记忆，即0.4Tm这一特定数值的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并准确写出特定数值（0.4Tm）即可完成作答，不涉及概念解释或复杂知识体系推导。该题完全符合基础概念记忆层级的特征，答案具有唯一性且无需展开论述，属于该题型下最基础的难度等级。" + }, + { + "idx": 1459, + "question": "For cold-formed components, (47) annealing should be performed promptly after forming to remove (48) and prevent the components from (49) or (50) during use.", + "answer": "stress relief; residual internal stress; deformation; cracking", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的专业术语（如stress relief, residual internal stress等）来补全句子，属于需要文字解释和论述的简答题类型。虽然形式上类似填空题，但涉及专业概念解释，更符合简答题特征。 | 知识层次: 题目考查对冷成型后热处理工艺的基本概念记忆，包括退火类型（应力消除退火）及其目的（消除残余内应力、防止变形和开裂）。这些都属于材料科学中的基础概念和基本原理，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释和描述多个相关概念（应力消除、残余内应力、变形和开裂），并理解它们之间的逻辑关系，但不需要复杂的体系阐述。" + }, + { + "idx": 1460, + "question": "What effect do second-phase particles have on the plastic deformation of alloys? Use dislocation theory to explain the mechanism.", + "answer": "Key points: They increase the strength of the alloy and the flow resistance during plastic deformation. This is because the resistance increases when dislocations cut through deformable second-phase particles or bypass non-deformable second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释第二相粒子对合金塑性变形的影响，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释第二相粒子对合金塑性变形的影响机制，涉及位错与第二相粒子的相互作用（切割或绕过）及其对强度和流动阻力的影响。这需要深入理解位错理论、塑性变形机制以及第二相粒子的性质，并进行综合分析和推理解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求运用位错理论解释第二相粒子对合金塑性变形的影响机制，涉及较深的理论分析和综合运用能力。虽然题目提供了明确的方向（位错理论），但需要考生理解并解释位错与可变形/不可变形第二相粒子的相互作用机制，属于机理深度解释的范畴。相比更基础的简答题（如定义或简单描述），该题目对知识掌握深度和推理能力的要求更高，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 1461, + "question": "What is intrinsic semiconductor?", + "answer": "A semiconductor with high purity and no doped impurities is called an intrinsic semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"intrinsic semiconductor\"进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对\"本征半导体\"这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不涉及应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层面。不需要解释或描述相关概念，也不涉及复杂的概念体系阐述。符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1463, + "question": "The direction of crystal slip is the direction of dislocation line movement within the slip plane.", + "answer": "False", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（False），符合判断题的特征 | 知识层次: 题目考查晶体滑移方向与位错线运动方向关系的基本概念记忆和理解，属于材料科学基础知识点。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆晶体滑移方向与位错线运动方向的关系这一基础定义即可作答，无需深入理解或分析复杂概念。在同题型内属于最简单的难度等级。" + }, + { + "idx": 1464, + "question": "What is a doped semiconductor?", + "answer": "A semiconductor formed by intentionally adding a small amount of impurity elements to an intrinsic semiconductor is called a doped semiconductor. If the doping element is from Group VA in the periodic table, it forms an n-type semiconductor; if the doping element is from Group IIIA, it forms a p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对掺杂半导体进行定义和解释，答案提供了详细的文字描述和分类说明，符合简答题的特征。 | 知识层次: 题目考查半导体掺杂的基本概念和分类，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目要求对掺杂半导体进行定义和分类解释，涉及基础概念的记忆和简单描述。虽然需要区分n型和p型半导体，但整体仍属于概念解释和描述的范畴，未达到复杂概念体系阐述的深度。" + }, + { + "idx": 1465, + "question": "What is the difference in Fermi levels between intrinsic semiconductors and doped semiconductors?", + "answer": "The Fermi level of an intrinsic semiconductor is located at the center of the band gap, while the Fermi level of a doped semiconductor is not at the center of the band gap. The Fermi level of an n-type semiconductor shifts upward relative to the center of the band gap, and the Fermi level of a p-type semiconductor shifts downward relative to the center of the band gap.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述本征半导体和掺杂半导体的费米能级差异，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目不仅要求记忆半导体费米能级的基本概念，还需要理解并解释掺杂对费米能级位置的影响，涉及不同半导体类型的比较分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并解释Fermi能级在半导体中的位置变化，涉及对n型和p型半导体掺杂效应的基本分析，但不需要深入探讨能带结构或掺杂浓度的具体计算。" + }, + { + "idx": 1466, + "question": "A pure edge dislocation loop can form in a crystal.", + "answer": "True", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（True/False），符合判断题的特征 | 知识层次: 题目考查对位错基本类型的记忆和理解，属于基础概念层次 | 难度: 在判断题的基础概念记忆层次中，该题目仅需判断\"纯刃位错环可以在晶体中形成\"这一基本概念的正误，属于最基础的定义性知识判断，不需要深入理解或分析复杂概念。" + }, + { + "idx": 1467, + "question": "What is the difference between the carriers in intrinsic semiconductors and doped semiconductors?", + "answer": "The carriers in intrinsic semiconductors are electrons in the conduction band and holes in the valence band, with an equal number of electrons and holes. In doped semiconductors, the carriers are also electrons in the conduction band and holes in the valence band, but the number of electrons and holes is not equal. In n-type semiconductors, the number of electrons is greater than the number of holes, while in p-type semiconductors, the number of holes is greater than the number of electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释本征半导体和掺杂半导体中载流子的区别，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对半导体载流子类型和数量的基本概念记忆和理解，属于定义和分类层面的知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释本征半导体和掺杂半导体中载流子的区别，涉及基础概念的记忆和简单对比，但不需要复杂的体系阐述或深入分析。虽然需要区分n型和p型半导体的载流子数量差异，但整体仍属于对基础概念的描述性回答范畴。" + }, + { + "idx": 1468, + "question": "A screw dislocation line can only undergo glide motion, not climb motion.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct/Incorrect），符合判断题的特征。答案只需给出对错判断，不需要解释或计算。 | 知识层次: 题目考查对位错运动方式（滑移和攀移）这一基本概念的记忆和理解，属于材料科学中晶体缺陷的基础知识范畴，不需要复杂的分析或综合应用。 | 难度: 该题目属于判断题中最基础的难度等级，仅需对螺丝位错线的基本运动方式（滑移和攀移）进行正误判断，不涉及概念理解或复杂分析，完全属于定义性知识的记忆范畴。" + }, + { + "idx": 1469, + "question": "In a binary alloy phase diagram, the greater the distance between the liquidus and solidus lines, the worse the fluidity of the alloy.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对二元合金相图中液相线和固相线距离与合金流动性关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然涉及二元合金相图的基础概念，但需要理解液相线和固相线间距与合金流动性的关系，比单纯记忆定义稍复杂，但不需要进行多概念比较或复杂推理。" + }, + { + "idx": 1470, + "question": "The presence of vacancies always increases the free energy of a crystal.", + "answer": "False", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（True/False），答案直接给出了False，符合判断题的特征。 | 知识层次: 题目考查对晶体缺陷中空位概念的基本理解，属于基础概念的记忆和判断 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆晶体中空位对自由能影响的基础概念即可作答，无需深入理解或分析。在判断题的基础概念记忆层次中属于最简单的等级。" + }, + { + "idx": 1471, + "question": "The presence of dislocations always increases the free energy of a crystal.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对位错基本性质的理解，属于晶体缺陷的基础概念记忆性知识 | 难度: 在判断题的基础概念记忆层次中，该题目属于最基本的正误判断。仅需记忆\"位错会增加晶体自由能\"这一基础概念即可作答，不涉及概念理解或复杂陈述的判断。属于该题型下最基础的难度等级。" + }, + { + "idx": 1472, + "question": "The driving force for the growth of recrystallization nuclei is the reduction of deformation stored energy, while the driving force for the growth of recrystallized grains is the reduction of total grain boundary energy.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对再结晶过程中驱动力这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在判断题中属于中等难度，需要理解两个不同的驱动力的概念（变形储存能和晶界能），并判断其陈述的正确性。虽然不涉及复杂推理，但需要对基础概念有清晰的理解才能准确判断。" + }, + { + "idx": 1473, + "question": "In essence, a twin is also a stacking fault", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对孪晶和堆垛层错这两个基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解\"孪晶\"和\"堆垛层错\"这两个基础概念之间的关系，而不仅仅是记忆定义。题目考察的是对晶体缺陷分类的理解程度，比单纯判断定义正误(等级1)要求更高，但又不涉及复杂概念分析(等级3)。" + }, + { + "idx": 1474, + "question": "Under the condition of no solid-phase diffusion and complete liquid-phase mixing, constitutional supercooling cannot occur during the solidification of solid solutions.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目涉及对固溶体凝固过程中成分过冷现象的理解，需要结合无固相扩散和完全液相混合的条件进行综合分析，属于中等应用层次的知识。 | 难度: 在判断题中属于较高难度，需要综合分析固溶体凝固过程中的多个条件（无固相扩散、完全液相混合）与成分过冷现象之间的因果关系，涉及对相变理论和扩散原理的深入理解，属于综合分析结果判断类型。" + }, + { + "idx": 1475, + "question": "In the vertical section of a ternary phase diagram, the lever rule cannot be used to determine the mass fractions of the three equilibrium phases.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对三元相图中杠杆规则应用范围的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解杠杆规则在三元相图中的适用条件，而不仅仅是记忆基本定义。虽然不涉及复杂概念，但需要对概念有一定的理解才能正确判断。" + }, + { + "idx": 1476, + "question": "At 727°C, the maximum carbon content in the equilibrium state of iron-carbon alloy is w_C=0.0218% for ferrite and w_C=0.77% for austenite. Where are the carbon atoms located in the ferrite and austenite crystals?", + "answer": "The carbon atoms are located at the centers of the flattened octahedral interstitial sites in ferrite crystals and at the centers of the regular octahedral interstitial sites in austenite crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释碳原子在铁素体和奥氏体晶体中的位置，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对铁碳合金中碳原子在铁素体和奥氏体晶体中位置的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求考生记忆并描述铁碳合金中碳原子在铁素体和奥氏体晶体中的具体位置，这需要掌握晶体结构的基本概念和碳原子的固溶位置，但不需要进行复杂的体系阐述或多概念综合分析。" + }, + { + "idx": 1477, + "question": "Explain the characteristics of grain growth process during heating of cold-deformed metals", + "answer": "Grain growth. It causes some property changes, such as decreases in strength, plasticity, and toughness. Along with grain growth, other structural changes also occur, such as recrystallization texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释冷变形金属加热过程中晶粒生长的特性，需要文字解释和论述，答案也提供了详细的文字描述和解释。 | 知识层次: 题目要求解释冷变形金属加热过程中的晶粒生长特性，并涉及性能变化和其他结构变化（如再结晶织构）。这需要综合运用材料科学中的相变、变形和再结晶等知识，进行机理分析和推理，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对晶粒生长过程进行机理深度解释，涉及冷变形金属加热过程中的结构变化和性能变化。虽然不需要全面分析所有可能的复杂现象，但需要对晶粒生长、再结晶织构等概念有深入理解，并能解释其对材料性能的影响。这属于机理深度解释的范畴，因此评为等级4。" + }, + { + "idx": 1478, + "question": "Using the constitutional undercooling theory, explain the relationship between the casting properties (fluidity, distribution characteristics of shrinkage porosity) of an alloy and the vertical distance between the liquidus and solidus lines in its phase diagram.", + "answer": "The casting properties (fluidity, distribution characteristics of shrinkage porosity) of an alloy are related to the vertical distance between the liquidus and solidus lines in its phase diagram. The larger the vertical distance, the poorer the fluidity of the alloy, and the more likely shrinkage porosity is to be distributed dispersedly. The condition for constitutional undercooling is given by: $\\\\frac{-m C_{0}(1-k_{0})}{D k_{0}}$, where G is the actual temperature gradient in the liquid ahead of the liquid/solid interface, R is the velocity of the liquid/solid interface movement, $\\\\pmb{D}$ is the diffusion coefficient of solute atoms in the liquid phase, $\\\\mathbf{\\abla}m$ is the slope of the liquidus line in the alloy phase diagram, $C_{0}$ is the composition of the alloy, and $k_{0}$ is the equilibrium partition coefficient of the alloy. It can be proven that $\\\\frac{\\\\mathrm{-}m C_{0}~\\\\left(1-k_{0}\\\\right)}{k_{0}}$ in the above equation is the vertical distance between the liquidus and solidus lines for the $C_{0}$ alloy in its phase diagram. Clearly, the larger the vertical distance between the liquidus and solidus lines, the greater the tendency for constitutional undercooling in the alloy, and the more the liquid/solid interface tends to grow dendritically. This hinders the fluidity of the alloy melt and also causes dispersed shrinkage porosity to form in the interdendritic regions due to insufficient feeding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用成分过冷理论解释合金铸造性能与相图中液相线和固相线垂直距离之间的关系，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求运用成分过冷理论解释合金铸造性能与相图中液相线和固相线垂直距离的关系，涉及多概念关联、公式推导和机理解释，需要深入分析和综合运用知识。 | 难度: 在简答题中属于最高难度等级，需要综合运用相图知识、凝固理论和成分过冷理论，进行复杂的机理解释和现象分析。题目要求深入理解液固相线垂直距离与合金铸造性能的关系，并推导成分过冷条件公式中的相关参数，涉及多个变量的相互作用和物理意义的解释。解题步骤复杂，需要将理论知识与实际铸造现象联系起来，对学生的综合分析和推理能力要求极高。" + }, + { + "idx": 1479, + "question": "For the equilibrium state of T12 steel (w_C=1.2%), write its phase constituents at room temperature and calculate the mass fraction of each phase constituent.", + "answer": "Phase constituents: α+Fe3C. w_α=(6.69-1.2)/(6.69-0.0008)×100%≈82.07%. w_Fe3C=(1.2-0.0008)/(6.69-0.0008)×100%≈17.93%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算质量分数，需要应用公式进行数值计算，答案也以数值结果呈现 | 知识层次: 题目主要考查对铁碳相图的基本理解和杠杆定律的简单应用，涉及单一公式的直接套用和基本计算步骤，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用杠杆定律进行单一计算步骤，仅需代入铁碳相图中的固定数值（6.69%和0.0008%）即可完成质量分数计算，无需多公式组合或复杂推导过程。虽然涉及相组成判断，但T12钢的室温相组成（α+Fe3C）属于基础知识范畴。整体符合等级2\"简单公式应用计算\"的特征。" + }, + { + "idx": 1480, + "question": "Explain the characteristics of the recovery process when cold-deformed metal is heated", + "answer": "During the recovery process, the microstructure does not change, and the elongated grains in the deformed state are still maintained. The recovery process completely eliminates the macroscopic first-class stresses caused by deformation and removes most of the microscopic second-class stresses. Generally, mechanical properties change little during recovery, with hardness and strength slightly decreasing, plasticity slightly improving, and some physical properties undergoing significant changes—resistivity notably decreases, while density increases. The deformation-stored energy is partially released during the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷变形金属加热时回复过程的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释冷变形金属加热时回复过程的特征，涉及微观结构、应力消除、机械性能和物理性能变化等多方面的综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和综合分析，思维过程有一定深度要求。 | 难度: 在简答题中属于中等难度，需要对冷变形金属加热时的回复过程进行综合分析和说明。题目要求解释回复过程的特征，包括微观结构的变化、应力的消除、机械性能和物理性能的变化等。虽然涉及多个概念和性能指标，但不需要进行多角度或深度关联性分析，主要考察对回复过程基本特征的理解和综合描述能力。" + }, + { + "idx": 1481, + "question": "Qualitatively compare the elastic modulus of ceramic materials, metal materials, and polymer materials", + "answer": "Among the three types of materials, ceramic materials have the highest elastic modulus, metal materials have the next highest elastic modulus, and polymer materials have the lowest elastic modulus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对三种材料的弹性模量进行定性比较，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对陶瓷、金属和聚合物材料弹性模量的基本概念记忆和简单比较，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要比较三种材料的弹性模量，但仅涉及基础概念的记忆和简单对比，不需要深入分析或复杂推导。解题步骤仅需回忆并列举三类材料的典型弹性模量范围即可完成，属于该题型中中等偏下的认知要求。" + }, + { + "idx": 1482, + "question": "At 727°C, the maximum carbon content in the equilibrium iron-carbon alloy is w_C=0.0218% for ferrite, while the carbon content in austenite is w_C=0.77%. Explain why the carbon content differs so greatly between the two.", + "answer": "Because the radius of the flat octahedral interstitial sites in the ferrite crystal is much smaller than that of the regular octahedral interstitial sites in the austenite crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种晶体结构中碳含量差异的原因，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目要求解释铁素体和奥氏体中碳含量差异的原因，涉及晶体结构中间隙位置的几何特征及其对碳溶解度的影响。这需要深入理解晶体结构、间隙固溶体理论以及不同相的结构差异，属于对多个知识点的综合运用和机理解释。 | 难度: 在简答题中属于机理深度解释难度等级。该题目要求考生不仅掌握铁碳合金的基本相图知识，还需要深入理解晶体结构中不同间隙位置对碳溶解度的机理影响。需要综合运用晶体学、相变原理和材料科学基础知识进行解释，涉及对铁素体和奥氏体晶体结构的比较分析，属于需要深入机理解释的复杂分析题型。" + }, + { + "idx": 1483, + "question": "Explain the role of Cottrell atmosphere in strengthening metals", + "answer": "Cottrell atmosphere: In BCC crystals (such as carbon steel), small-sized atoms like C and N preferentially distribute in the tensile stress region of edge dislocations, pinning the dislocations. To move the dislocations, they must be torn away from the pinning effect, requiring additional stress, thereby increasing the material's strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Cottrell atmosphere在金属强化中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Cottrell atmosphere在金属强化中的作用机制，涉及位错与间隙原子的相互作用、应力场分析以及材料强化的基本原理。这需要综合运用多个概念，进行推理分析，并解释其背后的物理机制，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求解释Cottrell atmosphere在金属强化中的作用，涉及BCC晶体结构、位错理论以及溶质原子与位错的相互作用等复杂概念。虽然不需要全面分析多个复杂现象，但需要对相关机理有深入的理解和清晰的表达能力，因此属于等级4。" + }, + { + "idx": 1484, + "question": "There is a face-centered cubic single crystal with a right-handed screw dislocation on the (11) plane, whose Burgers vector is a/2 [101], and another right-handed screw dislocation on the (111) plane, whose Burgers vector is a/2 [011]. These two dislocations meet at the intersection line of the two slip planes and form a new perfect dislocation. Explain what type of dislocation the newly formed perfect dislocation is, whether this dislocation can glide, and why?", + "answer": "Since the dislocation line is the intersection line of the two slip planes, the dislocation line is [1 0 -1]. It can be seen that the dislocation line is neither parallel nor perpendicular to the Burgers vector, so the newly formed dislocation is a mixed-type dislocation. Given the dislocation line and Burgers vector of the newly formed dislocation, their cross product yields the normal vector of the slip plane for the new dislocation, which is [1 -1 1]. The slip plane of this dislocation is (1 -1 1). Because this slip plane is a close-packed plane in the face-centered cubic structure, the dislocation can glide.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释新形成的位错类型、能否滑移及其原因，答案通过文字论述和解释来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求综合运用位错理论中的Burgers向量、位错线方向、滑移面等概念，通过向量运算和晶体学分析，判断新形成位错的类型及其可动性。这需要深入理解位错的性质和滑移机制，并进行多步骤的推理和分析。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用位错理论、晶体几何学和滑移机制的知识，进行多步骤的推理分析。具体包括：" + }, + { + "idx": 1485, + "question": "From the perspective of bonding in materials, analyze the reasons for the differences in elastic modulus among ceramic materials, metal materials, and polymer materials", + "answer": "The magnitude of a material's elastic modulus depends on the strength of the bonding within the material. Ceramic materials are bonded by strong ionic or covalent bonds, hence their elastic modulus is very large; metal materials are bonded by weaker metallic bonds, hence their elastic modulus is smaller; in polymer materials, the molecular chains are bonded by strong covalent bonds, but the chains themselves are bonded by very weak secondary bonds, hence their elastic modulus is very small.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从材料键合的角度分析陶瓷、金属和聚合物材料弹性模量差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从材料键合的角度分析陶瓷、金属和聚合物材料弹性模量差异的原因，涉及对不同材料键合类型的深入理解和综合分析，需要运用键合理论解释宏观性能差异，属于复杂分析和机理解释的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求从材料键合角度对三类材料的弹性模量差异进行机理深度解释。需要综合运用离子键/共价键/金属键/次级键等键合理论，分析不同键合强度对宏观力学性能的影响机制，并横向比较三类材料的键合特征差异。虽然不涉及多因素交互作用的复杂现象分析，但对键合机理的掌握深度和解释逻辑的严密性要求较高，属于机理深度解释层级的典型题目。" + }, + { + "idx": 1487, + "question": "Explain the role of Suzuki atmosphere in strengthening metals", + "answer": "Suzuki atmosphere: In FCC crystals (such as stainless steel), alloying elements like Ni and α preferentially distribute in stacking fault regions, reducing the stacking fault energy and expanding the extended dislocation zone. To move these extended dislocations, additional stress is required, thereby increasing the material's strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Suzuki atmosphere在金属强化中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Suzuki atmosphere在金属强化中的作用机制，涉及FCC晶体结构、合金元素分布、堆垛层错能变化以及位错运动等复杂概念的综合分析和关联。需要深入理解材料微观结构与宏观性能之间的关系，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对Suzuki atmosphere的机理进行深度解释，涉及FCC晶体结构、合金元素分布、堆垛层错能变化以及位错运动等多个专业概念的整合分析。虽然不需要进行复杂现象的全面分析（等级5），但需要考生具备扎实的材料科学基础和机理推导能力，属于机理深度解释的难度等级。" + }, + { + "idx": 1488, + "question": "For the equilibrium state of T12 steel (w_C=1.2%), write its room temperature microstructure constituents and calculate the mass fraction of each constituent.", + "answer": "Microstructure constituents: P+Fe3CⅡ. w_P=(6.69-1.2)/(6.69-0.77)×100%≈92.74%. w_Fe3CⅡ=(1.2-0.77)/(6.69-0.77)×100%≈7.26%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算质量分数，并给出了具体的计算公式和数值结果，符合计算题的特征。 | 知识层次: 题目要求计算T12钢在室温下的显微组织成分及其质量分数，主要涉及基本公式的应用和简单计算。虽然需要理解相图和杠杆定律，但整体思维过程较为直接，属于基本公式的直接套用和简单计算范畴。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算T12钢在室温下的组织组成物及其质量分数，主要涉及杠杆定律的直接应用。虽然需要理解相图基本概念和进行简单计算，但解题步骤明确，仅需套用单一公式（杠杆定律）即可完成，无需多个公式组合或复杂推导。" + }, + { + "idx": 1489, + "question": "Which hazardous substances are prohibited by the EU RoHS Directive (now enacted as a regulation) that came into effect on July 1, 2006? What are their maximum allowable concentrations?", + "answer": "Prohibited substances include lead (Pb, 0.1%), mercury (Hg, 0.1%), cadmium (Cd, 0.01%), hexavalent chromium (Cr+6, 0.1%), polybrominated biphenyls (PPB, 0.1%), and polybrominated diphenyl ethers (PBDE, 0.1%).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出欧盟RoHS指令禁止的有害物质及其最大允许浓度，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对欧盟RoHS指令中禁止的有害物质及其最大允许浓度的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目要求列举欧盟RoHS指令禁止的有害物质及其最大允许浓度，这仅需要记忆性知识，无需进行概念解释或复杂体系阐述。回答仅需直接回忆并列出具体物质名称和数值即可，不涉及任何分析或推理过程。" + }, + { + "idx": 1490, + "question": "There is a face-centered cubic single crystal with a right-handed screw dislocation on the (11) plane, whose Burgers vector is a/2 [101], and another right-handed screw dislocation on the (111) plane, whose Burgers vector is a/2 [011]. These two dislocations meet at the intersection line of the two slip planes and form a new perfect dislocation. If a tensile stress of 17.2MPa is applied along the [010] crystal direction, calculate the force per unit length acting on the newly formed perfect dislocation and indicate its direction (given the lattice constant a=0.2nm).", + "answer": "cosφ=1/√3, cosλ=1/√2. According to Schmid's law, the resolved shear stress acting on the slip direction of the newly formed dislocation's slip plane is τ0=17.2×1/√3×1/√2 MPa=7.0MPa. Therefore, the force per unit length acting on the dislocation line is f=τb=(0.2×10^-9×7×10^6)/√2 N/m=10^-3 N/m. Its direction is perpendicular to the dislocation line direction [101], pointing towards the unslipped region.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括使用Schmid's law计算分解剪应力，以及计算单位长度上的力。答案提供了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用Schmid定律计算分解剪应力，计算单位长度上的力，并确定力的方向。这涉及到多个概念的关联和综合分析，但不需要进行复杂的机理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解位错相互作用、Schmid定律的应用以及力的计算。题目涉及多步计算过程，包括确定分解剪切应力、计算位错力的大小和方向，并且需要综合分析多个概念（如位错性质、晶体学方向、应力分解等）。虽然计算步骤明确，但需要较强的概念关联能力和空间想象能力来正确应用公式和确定方向。" + }, + { + "idx": 1492, + "question": "What are the main solder systems that can replace lead-containing solders?", + "answer": "The main alternatives to lead-containing solders are: Sn-Ag-Cu, Sn-Zn, Sn-Bi, and Sn-In systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并解释可以替代含铅焊料的主要焊料系统，答案提供了具体的焊料系统名称，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对无铅焊料系统的基本分类和记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于基本定义简答，仅需列举几种替代铅焊料的主要系统，无需深入解释或复杂分析。" + }, + { + "idx": 1493, + "question": "Explain the characteristics of the recrystallization process during heating of cold-deformed metals", + "answer": "The microstructure undergoes changes, transforming from elongated grains due to cold deformation into new equiaxed grains. Mechanical properties change drastically, with strength and hardness sharply decreasing and plasticity increasing, returning to the state before deformation. The stored energy from deformation is fully released during recrystallization, eliminating the three types of stresses (lattice distortion) and reducing dislocation density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释冷变形金属加热过程中再结晶过程的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷变形金属加热过程中再结晶过程的特性，涉及微观结构变化、机械性能变化、储存能量释放等多个方面的综合分析。需要理解再结晶的机理，关联变形和再结晶过程中的能量变化和位错密度变化，属于对材料科学中复杂现象的深入分析和解释。 | 难度: 在简答题的复杂分析层次中，该题目要求对冷变形金属再结晶过程的微观结构变化、力学性能转变以及能量释放机制进行机理深度解释。虽然不涉及多因素交互作用的全面分析（等级5特征），但需要系统整合位错理论、储能释放和晶粒演变等核心概念，属于该题型内对机理解释要求较高的题目。" + }, + { + "idx": 1494, + "question": "A single crystal (BCC) with a rod axis [213] is stretched along the direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the initial slip system.", + "answer": "The single crystal has a BCC structure, and [213] lies within the orientation triangle [001]~[1¯11]~[101]. Therefore, the initial slip system is (011)[111].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定初始滑移系统，答案提供了详细的解释和推导过程，而不是简单的选择或判断。 | 知识层次: 题目需要理解BCC晶体结构、滑移面和滑移方向的概念，并能够将给定的晶向[213]定位到标准三角形中，进而确定初始滑移系统。这涉及到多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于较高难度，需要综合运用晶体结构、滑移系统、取向三角形等多方面知识，并进行多步计算和概念关联分析。题目要求确定初始滑移系统，涉及对BCC晶体结构的深入理解、取向三角形的应用以及滑移方向的判断，解题步骤较为复杂，需要较强的综合分析能力。" + }, + { + "idx": 1495, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the double slip system.", + "answer": "The double slip system is (011)[111]－(011)[111].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定双滑移系统，答案是一个具体的滑移系统描述，而不是选择、判断或计算。 | 知识层次: 题目要求确定双滑移系统，需要理解BCC晶体结构、滑移面和滑移方向的关系，并进行综合分析。虽然不涉及复杂计算，但需要将多个概念关联起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度。解题需要综合运用晶体学知识（BCC结构、滑移系确定）、矢量运算（确定滑移方向与拉伸轴的夹角）、以及双滑移系统的判定逻辑。具体表现为：1) 需要从给定的[213]方向推导出两个等效滑移系；2) 要求理解{110}滑移面上<111>滑移方向的对称性关系；3) 需通过施密特因子计算确认激活的滑移系组合。这些步骤超出了基础的概念复述（等级3），但尚未达到需要建立跨领域关联的深度分析（等级5）。" + }, + { + "idx": 1496, + "question": "What is the closest packed direction in a body-centered cubic crystal?", + "answer": "<111>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的晶体学方向（<111>），虽然答案简短，但需要理解晶体结构和密排方向的概念，属于需要专业知识解释的简答题类型 | 知识层次: 题目考查对体心立方晶体中最密排方向的基本概念记忆，属于晶体学中的基础知识点，不需要复杂的分析或计算。 | 难度: 在简答题题型中，该题目仅要求回答最密排方向，属于基础概念记忆的范畴，不需要额外的解释或论述。题目直接考查对体心立方晶体结构的定义性知识，解题步骤简单，只需回忆特定知识点即可作答。在同题型内属于最基本的难度等级。" + }, + { + "idx": 1499, + "question": "What is the reason for age hardening in Al-4.5%Cu alloy?", + "answer": "The reasons for age hardening are: first, when the precipitated metastable disk-shaped phase has a certain orientation relationship with the parent phase, it generates significant elastic strain in the matrix, which can markedly strengthen the alloy; second, when the alloy undergoes deformation, the interaction between dispersed particles and dislocations strengthens the alloy. If the precipitate particles are deformable, the work required to increase the surface energy of the particles when dislocations cut through them raises the resistance to dislocation motion, thereby strengthening the alloy. If the precipitate particles are strong and coherent with the matrix, the dislocation lines find it difficult to cut through the particles and will bypass them under applied stress, leaving dislocation loops. For the alloy to continue deforming, the stress exerted by the particles as the dislocation lines bypass them must be overcome, requiring further increase in the applied stress, meaning the alloy achieves age hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金时效硬化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金时效硬化的原因，涉及多个机制的综合分析，包括析出相与母相的取向关系、弹性应变、位错与析出粒子的相互作用等。需要深入理解材料科学中的相变、位错理论和强化机制，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对Al-4.5%Cu合金的时效硬化机理进行全面分析。需要综合运用材料科学中的相变理论、位错理论、强化机制等多个知识点，并详细解释两种不同的强化机制（可变形颗粒切割机制和不可变形颗粒绕过机制）。解题步骤涉及多个理论层面的推导和解释，对学生的知识整合能力和机理分析能力要求很高，属于该题型内最高难度的复杂现象全面分析类题目。" + }, + { + "idx": 1502, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the shear strain γₒ at the onset of double slip.", + "answer": "Using L = l + γ(l⋅n)b, let L = [u0w], then L = [2¯13] + 4γ[111]/√6. From this, it can be determined that u = 3, w = 4, γ = √6/4. Therefore, the crystal orientation is [304], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定剪切应变γₒ，解答过程中涉及向量运算和具体数值计算，最终给出数值结果√6/4。 | 知识层次: 题目需要进行多步计算和概念关联，包括晶体取向、滑移面和剪切应变等综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体塑性变形的基本概念，应用多步计算和公式推导，涉及向量运算和几何关系的综合分析。虽然计算步骤较多，但整体思路清晰，属于中等偏上的难度。" + }, + { + "idx": 1503, + "question": "How do the strength and hardness of a metal with finer grains compare to the same metal with coarser grains", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对金属晶粒尺寸对强度和硬度的影响进行文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查金属晶粒尺寸对强度和硬度影响的基本原理记忆和理解，属于材料科学中的基础概念。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较金属晶粒尺寸对强度和硬度的影响，这需要理解晶粒细化对金属力学性能的基本原理，但不需要复杂的体系阐述或深入分析。属于基础概念记忆层次中需要简单解释的范畴。" + }, + { + "idx": 1505, + "question": "How do the plasticity and toughness of a metal with finer grains compare to the same metal with coarser grains", + "answer": "Better", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属晶粒尺寸对塑性和韧性的影响，需要文字论述和解释，而不是简单的选择或判断。答案\"Better\"过于简略，通常需要更详细的解释来回答这类问题。 | 知识层次: 题目要求比较金属晶粒尺寸对塑性和韧性的影响，需要理解晶粒细化对材料性能的基本原理，并进行概念关联和综合分析。虽然不涉及复杂计算，但需要多步推理和解释，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解晶粒尺寸对金属塑性和韧性的影响，并进行综合分析和说明。虽然涉及多步概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1506, + "question": "Compared with pure iron, how do the plasticity and toughness of ferrite change", + "answer": "Lower", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的塑性和韧性变化，答案需要文字说明而非简单选择或判断 | 知识层次: 题目考查的是对纯铁和铁素体在塑性和韧性方面差异的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答纯铁与铁素体在塑性和韧性方面的比较结果，属于最基本的概念记忆性知识。题目不需要解释或论述变化原因，也不涉及复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1507, + "question": "What is the reason for the change in properties of ferrite compared to pure iron", + "answer": "Solid solution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铁素体与纯铁性能变化的原因，需要文字解释和论述，答案\"Solid solution\"是一个概念性的简短回答，符合简答题的特征 | 知识层次: 题目要求解释铁素体与纯铁性能差异的原因，涉及固溶体的概念及其对性能的影响，需要理解固溶体的基本原理并将其应用于具体材料体系的分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求解释铁素体与纯铁性能差异的原因，涉及固溶体概念的应用。虽然需要将材料科学原理与具体现象关联（综合分析），但不需要多角度论证或深度关联其他知识体系。解题步骤主要是：1) 明确铁素体的定义 2) 解释固溶强化机制 3) 对比纯铁性能。这符合等级3\"综合分析和说明\"的要求，但未达到等级4需要的多角度分析或等级5的深度关联性分析。" + }, + { + "idx": 1508, + "question": "What is the phenomenon called when a metal with finer grains exhibits higher strength and hardness but lower plasticity and toughness compared to the same metal with coarser grains?", + "answer": "Grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释一个现象的名称，答案需要文字描述而非选择或判断，且不需要计算步骤 | 知识层次: 题目考查对晶粒细化强化现象的基本概念记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答的是\"Grain refinement strengthening\"这一现象的名称，属于基础概念记忆的范畴，不需要进行复杂的解释或论述。只需准确回忆并写出该专业术语即可，符合等级1对知识点掌握深度和解题步骤简单的要求。" + }, + { + "idx": 1509, + "question": "Ferrite is a solid solution of carbon in what－Fe", + "answer": "α", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的术语（α-Fe）作为答案，属于需要简短回答的问题，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查对铁素体基本定义的记忆，仅需知道铁素体是碳在α-Fe中的固溶体这一基础概念即可回答，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答，仅需记忆并准确回答碳在α-Fe中的固溶体名称即可，无需额外解释或复杂概念阐述，符合等级1的难度标准。" + }, + { + "idx": 1510, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the final orientation of the test rod (assuming the rod does not fracture before reaching a stable orientation).", + "answer": "Let the stable orientation be [u′0w′]. To satisfy n = [000], it is required that [u′0w′] × ([111] ± [1¯11]) = [000], which implies u′ = w′. Therefore, the final stable orientation is [101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定单晶棒的最终取向，答案给出了详细的推导过程和结论，符合简答题的特征。 | 知识层次: 题目要求确定单晶棒在塑性变形后的最终取向，涉及晶体学方向、滑移面以及稳定取向的计算。需要综合运用晶体学知识、向量运算和塑性变形机制的理解，进行推理分析。思维过程要求较高，涉及多步计算和概念关联。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体学、塑性变形和矢量运算等知识，解题步骤涉及多个复杂推理环节（如确定滑移系、建立稳定取向条件、求解矢量方程），且需要对BCC晶体结构和滑移机理有深度理解。这完全符合等级5\"复杂现象全面分析\"的标准，属于该题型框架内的最高难度级别。" + }, + { + "idx": 1511, + "question": "Compared with pure iron, how do the strength and hardness of ferrite change", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的强度和硬度变化，答案需要文字论述而非简单选择或判断。 | 知识层次: 题目考查对纯铁和铁素体强度和硬度差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求对纯铁和铁素体的强度与硬度进行简单比较，属于基础概念记忆的范畴。回答仅需给出\"Higher\"这一结论，无需展开解释或论述，因此在该题型内属于最基本的难度等级。" + }, + { + "idx": 1512, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the rotation law and rotation axis during the slip process.", + "answer": "During double slip, the specimen axis on one hand rotates towards [111], with the rotation axis n₁ = [304] × [111] = [413], and on the other hand also rotates towards [1¯11]; the rotation axis n₂ = [304] × [1¯11] = [41¯3]; the resultant rotation axis is [020] i.e., [010], so after double slip, point F moves along the edge [001]－[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定旋转定律和旋转轴，答案提供了详细的文字描述和推导过程，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求确定单晶拉伸过程中的旋转规律和旋转轴，涉及双滑移系统的综合分析、晶体学方向的矢量运算（叉积计算）以及滑移过程中的晶体旋转机制解释。这需要深入理解BCC晶体结构、滑移系统特性、晶体塑性变形机制，并进行多步骤的矢量运算和综合分析，属于复杂分析层次的题目。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体学、塑性变形和几何分析等多方面知识。解题过程需要：" + }, + { + "idx": 1513, + "question": "For an edge dislocation line, the direction of its slip motion is (18) to the Burgers vector", + "answer": "(18) parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（parallel）来补全句子，属于简答题的范畴，需要根据知识进行简短回答而非选择或判断。 | 知识层次: 题目考查对位错滑移方向与伯格斯矢量关系的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求考生记忆并复述刃位错滑移方向与伯氏矢量的关系这一基础概念，无需解释或描述，更不需要复杂概念体系的阐述。符合等级1\"基本定义简答\"的全部特征。" + }, + { + "idx": 1514, + "question": "What are the common methods for refining grains in casting processes (the second method)", + "answer": "Adding nucleating agents, stirring or vibration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举常见的晶粒细化方法，答案需要文字解释和论述，而不是选择或判断 | 知识层次: 题目考查的是对铸造过程中晶粒细化常见方法的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求对铸造过程中细化晶粒的常见方法进行解释和描述，属于概念解释和描述的难度等级。虽然需要记忆多个方法（添加形核剂、搅拌或振动），但不需要深入阐述复杂的概念体系或进行多步骤的推理分析，因此属于等级2。" + }, + { + "idx": 1515, + "question": "What is the common method to refine grains in casting process (the first method)", + "answer": "Increase the cooling rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答一个具体的问题，答案是一个简短的解释或方法名称，不需要从多个选项中选择或进行复杂的计算 | 知识层次: 题目考查的是铸造过程中细化晶粒的基本方法，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答铸造过程中细化晶粒的常见方法（第一种方法），答案只需直接回忆\"提高冷却速率\"这一基础概念即可，无需进行概念解释或复杂体系阐述。在知识层次上属于最基础的定义性记忆内容，解题步骤和思维深度要求都很低，完全符合等级1的基本特征。" + }, + { + "idx": 1516, + "question": "For an edge dislocation line, its Burgers vector is __(17)__ to the dislocation line", + "answer": "(17) perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（perpendicular）来描述位错线与伯格斯矢量之间的关系，属于需要简短文字回答的类型 | 知识层次: 题目考查对位错基本性质的理解，特别是伯格斯矢量与位错线方向的关系，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（刃位错的柏氏矢量方向），属于最基础的概念记忆层面。题目无需解释或描述，更不需要复杂概念体系阐述，完全符合等级1\"基本定义简答\"的标准。在同题型内，其难度显著低于需要概念解释（等级2）或体系阐述（等级3）的简答题。" + }, + { + "idx": 1517, + "question": "For an edge dislocation line, its climb direction is _（19）_ to the Burgers vector", + "answer": "（19）perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（perpendicular）作为答案，属于简短的文字回答形式，不需要选择或判断对错，也不涉及计算过程。 | 知识层次: 题目考查对位错基本性质的理解，特别是刃位错攀移方向与伯氏矢量之间的关系，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回忆并填写边缘位错线的攀移方向与伯格斯矢量之间的关系，属于对基础概念的直接记忆和简单应用，不需要额外的解释或复杂的概念体系阐述。" + }, + { + "idx": 1518, + "question": "What type of solid solution is ferrite formed by carbon in α-Fe", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释碳在α-Fe中形成的固溶体类型，需要文字解释而非选择或判断，答案\"Interstitial\"是简短的文字回答而非计算或选择结果。 | 知识层次: 题目考查对铁素体（ferrite）中碳原子在α-Fe中形成的固溶体类型的基本概念记忆，属于基础概念和分类的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答\"Interstitial\"这一基本定义，属于最基础的概念记忆层次。不需要额外的解释或描述，更不需要复杂概念体系的阐述。在同为简答题-基础概念记忆的题型框架内，这是最简单的直接定义回答类型，完全符合等级1的标准。" + }, + { + "idx": 1519, + "question": "For a screw dislocation line, its Burgers vector is _（20） to the dislocation line", + "answer": "（20） parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（parallel）来补全句子，属于需要简短文字回答的类型，没有提供选项供选择，也不涉及判断或计算。 | 知识层次: 题目考查对螺型位错线与其柏氏矢量方向关系的基本概念记忆，属于材料科学中位错理论的基础知识点，无需复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求记忆并填写基本定义（柏氏矢量与位错线的相对方向关系），属于最基础的概念记忆层级。题目无需解释或论述，完全符合等级1\"基本定义简答\"的标准，是同类题型中最简单的表现形式。" + }, + { + "idx": 1520, + "question": "For a screw dislocation line, the direction of its slip motion is _（21）_ to the Burgers vector", + "answer": "（21）perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（perpendicular）来回答问题，属于简答题的形式，需要根据知识进行简要回答而非选择或判断 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是关于螺型位错滑移方向与伯氏矢量关系的知识点，属于基础概念记忆范畴。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述螺型位错滑移方向与伯氏向量的垂直关系，无需解释或复杂论述，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 1521, + "question": "After cold plastic deformation, the strength and hardness of metal (23)—", + "answer": "(23) increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词来回答问题，属于简短的文字回答形式，不需要从多个选项中选择或进行复杂的计算。 | 知识层次: 题目考查金属冷塑性变形后强度和硬度变化的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题属于最基本的概念记忆题，仅需回答\"increase\"这个关键词，不需要任何解释或论述。题目考查的是对冷塑性变形后金属性能变化这一基础概念的记忆，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最简单直接的记忆性题目。" + }, + { + "idx": 1522, + "question": "After cold plastic deformation, the plasticity and toughness of metal (24)", + "answer": "(24) decrease", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答金属在冷塑性变形后的塑性和韧性变化，答案是一个简短的描述性词语\"decrease\"，属于简答题的特征 | 知识层次: 题目考查金属在冷塑性变形后性能变化的基本概念记忆，属于基础概念的记忆性知识，不需要复杂的分析或推理。 | 难度: 在简答题题型中，该题目仅要求回答金属冷塑性变形后塑性和韧性的变化，属于基本定义简答。题目仅涉及单一概念的记忆性知识，不需要解释或复杂阐述，符合等级1的基本定义简答标准。" + }, + { + "idx": 1523, + "question": "For cold-formed components, (29)__ annealing should be performed promptly after forming to remove (30)__ and prevent deformation or cracking during use.", + "answer": "(29) stress relief; (30) residual internal stress", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定术语（stress relief和residual internal stress）来完成句子，属于填空题类型，而填空题在分类上更接近简答题（short_answer），因为都需要准确的专业知识回答而非选择或判断。 | 知识层次: 题目考查对冷成型后热处理工艺的基本概念记忆，特别是应力消除退火和残余内应力的术语理解，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写两个特定的术语（应力消除退火和残余内应力），这些是材料科学中的基础概念，属于记忆性知识。解题步骤简单，只需回忆并准确填写术语即可，不需要进行复杂的解释或论述。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 1524, + "question": "After metal undergoes cold plastic deformation, this phenomenon is called (25) strengthening or (26) __", + "answer": "(25) deformation; (26) work hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个特定的术语（deformation和work hardening），属于需要简短文字回答的题目类型，没有提供选项或需要判断对错，也不涉及计算。 | 知识层次: 题目考查金属冷塑性变形后的强化现象的基本概念记忆，属于定义性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写两个金属加工领域的基础术语（变形强化和加工硬化），属于对定义性知识的直接回忆，无需展开解释或论述。在同类简答题中，这属于最基础的知识点考察，解题步骤仅涉及术语提取，不涉及概念关联或体系化阐述。" + }, + { + "idx": 1525, + "question": "For a screw dislocation line, the direction of its cross-slip motion is __(22)__ to the Burgers vector", + "answer": "(22) perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（\"perpendicular\"）来补全句子，而不是从多个选项中选择或进行判断。这符合简答题的特征，即需要提供简短而精确的答案。 | 知识层次: 题目考查对螺型位错运动方向与伯格斯矢量关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回忆并填写螺丝位错线交叉滑移方向与伯格斯矢量之间的基本关系（垂直），不涉及概念解释或复杂体系阐述。这是对基础概念记忆的直接考察，符合等级1的简单记忆性知识要求。" + }, + { + "idx": 1527, + "question": "Give examples of the basic strengthening forms of materials", + "answer": "The basic strengthening forms of materials include: solid solution strengthening, strain hardening, precipitation strengthening and dispersion strengthening, grain refinement strengthening, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举材料的基本强化形式，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对材料强化基本形式的记忆和理解，属于基础概念和分类的记忆性知识 | 难度: 在简答题题型中，该题目要求列举材料的基本强化形式，属于概念解释和描述的难度等级。虽然需要记忆多个强化形式，但不需要深入阐述其机理或进行复杂的概念体系分析，因此属于中等难度。" + }, + { + "idx": 1528, + "question": "Provide the Hall-Petch formula and explain the meaning and units of each physical quantity in the formula.", + "answer": "The Hall-Petch formula describes the relationship between yield strength and grain size. The formula is σ_s=σ_0+K·d^(-1/2). In the formula, σ_0 (MPa) and K (MPa·m^(1/2)) are constants; d is the grain diameter (m); σ_s is the yield strength (MPa).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供Hall-Petch公式并解释公式中每个物理量的含义和单位，这需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Hall-Petch公式的基本概念记忆，包括公式中各物理量的含义和单位，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要记忆Hall-Petch公式及其各物理量的含义和单位，但不需要进行复杂的推导或阐述多个概念之间的关系。题目主要考察对基础概念的记忆和理解，属于该题型中的中等难度。" + }, + { + "idx": 1529, + "question": "Provide the grain boundary segregation formula and explain the meaning and units of each physical quantity in the formula", + "answer": "The grain boundary segregation formula is C_gb=C_0·exp(-ΔE/kT)=C_0exp(-Q/RT). In the formula, C_gb and C_0 represent the grain boundary concentration and grain center concentration, respectively (both can use the same units, such as mass percentage concentration or volume concentration); ΔE is the interaction energy (eV); Q is the molar interaction energy (J), which reflects the change in grain boundary energy caused by segregation; R is the gas constant (J/K); k is the Boltzmann constant (eV/K); T is the absolute temperature (K).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提供公式并解释每个物理量的含义和单位，这需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求提供晶界偏析公式并解释每个物理量的含义和单位，这涉及到对公式的理解和应用，以及概念之间的关联。虽然需要记忆公式和物理量的定义，但更强调对公式中各物理量之间关系的理解和解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求提供晶界偏析公式并解释每个物理量的含义和单位，这需要学生掌握相关概念并能进行综合说明。虽然涉及多个物理量和单位，但解释相对直接，不需要进行多角度或深度关联性分析。因此，在简答题的框架内，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 1530, + "question": "Explain the strengthening mechanism of solid solution strengthening", + "answer": "Solid solution strengthening: For both substitutional atoms and interstitial atoms, under suitable conditions, atomic segregation may occur to form atmospheres. For substitutional lattices, when solute atoms are larger than solvent atoms, solute atoms tend to accumulate in the expanded region of edge dislocations; conversely, they accumulate in the compressed region. Interstitial atoms always tend to accumulate in the expanded region. This phenomenon of diffusion-driven accumulation near dislocations is called Cottrell atmosphere. The Cottrell atmosphere has a pinning effect on dislocations, thereby increasing strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固溶强化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及原子偏聚、柯氏气团形成及其对位错的钉扎效应等复杂过程，需要综合运用材料科学中的位错理论和扩散知识进行推理分析，属于对原理的深入理解和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对固溶强化的机理进行深度解释，涉及置换型和间隙型溶质原子的行为差异、柯垂尔气团的形成机制以及对位错的钉扎效应等专业概念的综合运用。虽然不需要进行跨学科或多因素交互作用的全面分析（这是等级5的特征），但需要对材料科学中的位错理论有扎实理解，并能清晰阐述微观机制与宏观性能的关联性，符合等级4\"机理深度解释\"的典型特征。" + }, + { + "idx": 1531, + "question": "Explain the strengthening mechanism of work hardening", + "answer": "Work hardening: During the plastic deformation of cold-worked metals, a large number of dislocations are formed. Some of these dislocations become immobile dislocations, thereby increasing their resistance to mobile dislocations. This makes further deformation of the material difficult, resulting in work hardening or strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释加工硬化的强化机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释加工硬化的强化机制，涉及位错理论、塑性变形过程中位错的相互作用及其对材料性能的影响。这需要综合运用材料科学中的位错理论、变形机制等知识，进行机理层面的解释和分析，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对加工硬化机理进行深度解释，涉及位错运动、阻碍机制等专业概念的准确运用，需要综合材料变形理论进行推理分析。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述层面，属于机理深度解释范畴。" + }, + { + "idx": 1532, + "question": "Explain the strengthening mechanisms of precipitation strengthening and dispersion strengthening", + "answer": "Precipitation strengthening and dispersion strengthening: A supersaturated solid solution undergoes decomposition upon temperature decrease or during prolonged holding (aging). The aging process is often complex; for example, in aluminum alloys, GP zones form first during aging, followed by the precipitation of transition phases (θ′′ and θ′), and finally the formation of thermodynamically stable equilibrium phases (θ). Fine precipitates dispersed in the matrix hinder dislocation motion, thereby producing a strengthening effect. This is known as 'precipitation strengthening' or 'age hardening'.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释沉淀强化和弥散强化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释沉淀强化和弥散强化的机制，涉及对材料微观结构演变的理解、位错运动与第二相颗粒相互作用的分析，以及不同强化机制的对比和综合。这需要综合运用材料科学知识，进行机理层面的深入解释和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对沉淀强化和弥散强化机理进行深度解释，涉及多相转变过程（如GP区、过渡相、平衡相的形成）及其对位错运动的阻碍机制。虽然不需要比较不同强化机制或分析极端条件（如高温变形），但仍需系统描述相变序列和强化原理，属于机理深度解释级别。" + }, + { + "idx": 1533, + "question": "What is the thermodynamic condition for uphill diffusion to occur?", + "answer": "The thermodynamic condition for uphill diffusion to occur is ∂²G/∂x²<0.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释热力学条件，答案需要文字描述和公式表达，属于简答题类型 | 知识层次: 题目需要理解热力学条件（∂²G/∂x²<0）与上坡扩散现象之间的关联，涉及多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目要求考生不仅理解热力学基本概念（如吉布斯自由能G），还需要掌握二阶偏导数的物理意义及其与扩散行为的关系。解题时需要综合分析热力学不稳定条件（∂²G/∂x²<0）与扩散方向的反常关联性，涉及多步骤的逻辑推导和概念关联。相较于只需简单定义或单步计算的简答题（等级3），该题需要更系统的论述框架，但尚未达到需要引入跨学科知识或建立复杂模型的深度关联性分析（等级5）。" + }, + { + "idx": 1534, + "question": "What is uphill diffusion?", + "answer": "Uphill diffusion refers to the process where substances diffuse from regions of low concentration to regions of high concentration, resulting in an increased concentration gradient. Examples include the copper-rich clusters formed in the early stages of aging in aluminum-copper alloys and the solute-enriched regions formed during spinodal decomposition in certain alloy solid solutions. The true driving force for uphill diffusion is the chemical potential gradient, not the concentration gradient. Although diffusion leads to an increase in the concentration gradient, the chemical potential gradient actually decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"uphill diffusion\"进行文字解释和论述，答案提供了详细的定义、示例和原理说明，符合简答题的特征。 | 知识层次: 题目不仅要求解释uphill diffusion的定义，还需要论述其背后的驱动力（化学势梯度而非浓度梯度），并举例说明实际材料系统中的现象（如铝铜合金中的富铜团簇和旋节分解中的溶质富集区）。这需要综合运用多个概念，进行机理层面的解释和关联分析，思维深度较高。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求解释uphill diffusion的概念，并举例说明其在材料科学中的具体应用，同时需要深入分析其驱动力是化学势梯度而非浓度梯度。这需要考生具备扎实的材料科学基础，能够综合运用知识进行推理分析，并对复杂现象进行机理解释。此外，题目还要求考生能够将理论与实际例子相结合，展示出对材料科学中复杂现象的全面理解。因此，该题目在同题型内属于最高难度等级。" + }, + { + "idx": 1535, + "question": "Recrystallization annealing", + "answer": "Recrystallization annealing: For plastically deformed metals, during the reheating process, when the temperature exceeds the recrystallization temperature, new grains with low defect density are formed, restoring properties such as strength to their pre-deformation levels, while the phase structure remains unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Recrystallization annealing\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查的是对再结晶退火这一基本概念的记忆和理解，包括其定义、发生条件和效果，属于材料科学中的基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。题目要求解释再结晶退火的定义和基本原理，涉及对塑性变形金属在加热过程中新晶粒形成和性能恢复的描述。虽然需要一定的知识掌握，但不需要复杂的体系阐述或多概念整合，属于中等难度的概念解释题。" + }, + { + "idx": 1536, + "question": "Crystal", + "answer": "Crystal: A solid composed of atoms, molecules, or ions arranged in a regular periodic pattern", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Crystal\"进行定义和解释，需要文字描述和论述，属于简答题类型 | 知识层次: 题目考查晶体这一基本概念的定义，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目仅要求对\"Crystal\"这一基础概念进行简单的定义回答，属于最基本的概念记忆性知识，不需要额外的解释或复杂论述。符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1537, + "question": "Taking Al-4.5% Cu alloy as an example, explain the aging process and the changes in its properties (hardness).", + "answer": "After quenching, the aluminum alloy forms a supersaturated solid solution. Subsequent heating and holding cause the sequential precipitation of GP zones, θ'', θ', and θ phases within the solid solution. The formation of GP zones increases the material's hardness (the first aging peak). Prolonged aging leads to the dissolution of GP zones and a decrease in hardness. The formation of θ'' further increases the hardness (the second aging peak). When θ'' completely dissolves and transforms into θ' and θ' transforms into θ, the hardness begins to decline.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5% Cu合金的时效过程及其性能变化，答案以文字论述形式详细描述了时效过程中各相的形成及其对硬度的影响，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5% Cu合金的时效过程及其硬度变化，涉及多个相变阶段（GP区、θ''、θ'和θ相）的形成和溶解，以及这些变化对材料性能的影响。这需要综合运用材料科学中的相变理论、时效强化机理等知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对Al-4.5% Cu合金的时效过程进行机理深度解释，包括过饱和固溶体的形成、GP区、θ''、θ'和θ相的析出顺序及其对硬度的影响。需要综合运用材料科学知识，理解相变动力学和性能变化的关联，并进行详细的推理分析。虽然题目涉及多个步骤和相变过程，但未达到全面分析复杂现象的最高难度，因此属于等级4。" + }, + { + "idx": 1538, + "question": "Taking the tensile curve of low-carbon steel as an example, use dislocation theory to explain the yield phenomenon", + "answer": "The yield of low-carbon steel is due to the fact that carbon in low-carbon steel is an interstitial atom, which interacts with dislocations in ferrite to form solute atom atmospheres, known as Cottrell atmospheres. These atmospheres have a pinning effect on dislocations, and only under higher stress can dislocations break away from the pinning of solute atoms, manifesting as the upper yield point on the stress-strain curve. Once dislocations are unpinned and continue to glide, less stress is required, which appears as the lower yield point and the horizontal plateau on the stress-strain curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释低碳钢的屈服现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢的屈服现象，涉及位错与间隙原子的相互作用、柯氏气团的形成及其对位错的钉扎效应，以及应力-应变曲线上的上、下屈服点和水平平台的出现机制。这需要深入理解位错理论、固溶强化机制以及材料力学行为的微观机理，属于对多个概念的关联和综合分析，思维过程较为复杂。 | 难度: 在简答题中，该题目要求运用位错理论解释低碳钢的屈服现象，涉及Cottrell气团的形成及其对位错的钉扎作用，需要机理深度解释。虽然题目没有要求全面分析复杂现象，但需要对位错与间隙原子的相互作用有深入理解，并能够清晰地阐述屈服点的产生机制，因此在简答题中属于较高难度。" + }, + { + "idx": 1539, + "question": "Please explain the effect of stacking fault energy level on the cross-slip of screw dislocations", + "answer": "For metals with high stacking fault energy, during deformation, perfect dislocations are less likely to dissociate. When encountering obstacles, they can continue moving through cross-slip until they meet other dislocations and form tangles. In contrast, for metals with low stacking fault energy, their perfect dislocations easily dissociate into configurations consisting of two partial dislocations and a stacking fault, making cross-slip difficult and resulting in poor mobility of dislocation configurations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释堆垛层错能水平对螺位错交叉滑移的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释堆垛层错能对螺位错交滑移的影响机制，涉及位错理论、材料变形行为等概念的深入理解和综合分析，需要将多个知识点关联起来进行推理和解释，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对堆垛层错能水平对螺位错交滑移的影响进行机理深度解释。需要综合运用位错理论、晶体缺陷知识，并分析不同能量水平下的位错行为差异。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念解释层面，属于需要深入理解位错运动机制的题目。" + }, + { + "idx": 1540, + "question": "Give the Hall-Petch formula and explain the meaning and units of each physical quantity in the formula", + "answer": "The Hall-Petch formula describes the relationship between yield strength and grain size. The formula is: σ_s = σ_0 + K·d^(-1/2). In the formula, σ_0 (MPa) is a constant; K (MPa·m^(1/2)) is a constant; d (m) is the grain diameter; σ_s (MPa) is the yield strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Hall-Petch公式并解释公式中每个物理量的含义和单位，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对Hall-Petch公式的记忆，包括公式中各物理量的含义和单位，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释Hall-Petch公式及其各物理量的含义和单位，属于概念解释和描述的难度等级。虽然需要记忆公式和各个物理量的定义，但不需要进行复杂的推导或深入分析，相对较为基础。" + }, + { + "idx": 1542, + "question": "Give the one-dimensional form of Fick's second law and explain the meaning and units of each physical quantity in the formula", + "answer": "The one-dimensional form of Fick's second law is: ∂C/∂t = D·∂²C/∂x². In the formula, C (g/cm³) is the concentration; D (cm²/s) is the diffusion coefficient; t (s) is the time; x (cm) is the distance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Fick's第二定律的一维形式，并解释公式中每个物理量的含义和单位。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查Fick's第二定律的一维形式及其物理量的含义和单位，属于基础概念的记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题中属于中等难度，需要解释Fick's second law的一维形式，并说明公式中每个物理量的含义和单位。这涉及到对基本概念的理解和描述，但不需要复杂的推导或深入的分析。" + }, + { + "idx": 1544, + "question": "Taking the tensile curve of low-carbon steel as an example, use dislocation theory to explain the phenomenon of work hardening", + "answer": "When deformation continues, the stress increases again due to a significant rise in the number of dislocations, a phenomenon known as work hardening. This occurs because cold-deformed metals generate a large number of dislocations during plastic deformation, some of which become immobile dislocations. These immobile dislocations increase resistance to mobile dislocations, making further deformation of the material more difficult, resulting in work hardening or strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用位错理论解释低碳钢拉伸曲线中的加工硬化现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢拉伸曲线中的加工硬化现象，涉及位错运动、相互作用及其对材料变形抗力的影响，需要综合运用材料科学中的位错理论和塑性变形机制进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求运用位错理论解释低碳钢拉伸曲线中的加工硬化现象。这需要深入理解位错运动和相互作用机理，并能将理论知识与实际材料行为联系起来。虽然题目涉及单一核心概念（加工硬化），但需要系统性地解释位错增殖、固定位错形成及其对材料变形抗力的影响，属于机理深度解释层面的要求。相比等级5的复杂现象全面分析，该题目不需要整合多个理论体系或分析多因素耦合效应。" + }, + { + "idx": 1545, + "question": "5．Extended dislocation", + "answer": "A complete dislocation dissociates into two partial dislocations and the stacking fault between them, and this dislocation configuration is called an extended dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Extended dislocation\"进行解释和论述，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对扩展位错这一基本概念的定义和描述，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目仅要求对\"Extended dislocation\"进行基本定义简答，属于最基础的概念记忆性知识。题目不涉及概念解释、描述或复杂体系阐述，仅需直接回忆并复述定义内容，因此在该题型内属于最低难度等级。" + }, + { + "idx": 1546, + "question": "Please explain the effect of stacking fault energy on the work hardening rate of metals", + "answer": "For screw dislocations, cross-slip allows two screw dislocations of opposite signs (left and right) on the same slip plane to meet and annihilate each other, thereby reducing the dislocation multiplication rate. For metals with low stacking fault energy, cross-slip of dislocations is difficult, resulting in a high dislocation multiplication rate during deformation and an increased work hardening rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释堆垛层错能对金属加工硬化率的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释堆垛层错能对金属加工硬化率的影响机制，涉及位错运动、交滑移等复杂概念的综合分析和推理。需要深入理解位错行为与材料性能之间的关系，并进行机理层面的解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求解释堆垛层错能对金属加工硬化率的影响，涉及位错运动、交滑移等复杂概念，需要考生深入理解并解释这些机理之间的相互关系。虽然题目没有要求全面分析多个复杂现象，但对机理的解释深度要求较高，因此属于等级4。" + }, + { + "idx": 1547, + "question": "Using Al-4.5%Cu alloy as an example, explain the microstructural transformation during 130% aging", + "answer": "After quenching, the aluminum alloy forms a supersaturated solid solution. Subsequent heating and holding will cause the sequential precipitation of GP zones, θ′′, θ′, and θ phases within the solid solution. Among these, α and θ are equilibrium phases; GP zones, θ′′, and θ′ are metastable phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金在130%时效过程中的微观结构转变，需要详细的文字描述和论述，而不是选择、判断或计算。答案提供了详细的相变过程描述，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金在130%时效过程中的微观结构转变，涉及多个相变阶段（GP区、θ′′、θ′和θ相）的形成和演变，需要综合运用材料科学中的相变理论、热力学和动力学知识进行分析和解释。这需要深入理解相变机制、平衡相和亚稳相的区别，以及时效处理对材料性能的影响，属于较高层次的认知能力和复杂分析。 | 难度: 在简答题题型中，该题目要求对Al-4.5%Cu合金在130%时效过程中的微观结构转变进行机理深度解释。需要学生掌握从过饱和固溶体到平衡相和亚稳相的序列析出过程，并理解各相的形成条件和特点。虽然题目涉及多个相变阶段，但不需要进行复杂的现象全面分析或跨学科综合运用，因此属于等级4的难度。" + }, + { + "idx": 1548, + "question": "Taking the Al-4.5%Cu alloy as an example, explain the hardness changes during the 130% aging process", + "answer": "The formation of GP zones will increase the hardness of the material (the first aging peak). After prolonged aging, the GP zones dissolve, and the hardness decreases. The formation of θ′′ causes the hardness to continue increasing (the second aging peak). When θ′′ completely dissolves and transforms into θ′ and θ′ transforms into θ, the hardness begins to decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金在130%时效过程中硬度变化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金在130%时效过程中硬度的变化，涉及GP区、θ′′、θ′和θ相的形成与溶解，需要综合运用材料科学中的相变理论、时效硬化机理等知识，进行多步骤的推理分析和机理解释。 | 难度: 在简答题题型中，该题目要求对Al-4.5%Cu合金在130%时效过程中的硬度变化进行机理深度解释。需要考生理解并描述GP区、θ′′、θ′和θ相的形成与溶解过程及其对硬度的影响，涉及多个相变阶段和硬度变化的因果关系。虽然不需要进行复杂现象的全面分析（如考虑温度、时间等多因素交互作用），但仍需对时效硬化的微观机理有较深入的理解和清晰的表述能力，属于机理深度解释的难度等级。" + }, + { + "idx": 1549, + "question": "1. Pearlitic transformation", + "answer": "The phase transformation in which the austenite of Fe-C alloy simultaneously transforms into the eutectoid structure of ferrite and cementite below the eutectoid transformation temperature during cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Pearlitic transformation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征 | 知识层次: 题目考查对珠光体相变这一基础概念的定义和基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对珠光体相变进行基本定义简答，属于基础概念记忆层次。题目仅涉及单一概念的定义，无需深入解释或复杂概念体系的阐述，解题步骤简单直接，符合等级1的基本定义简答标准。" + }, + { + "idx": 1550, + "question": "2. Intermediate phase", + "answer": "A compound formed by two pure components with a structure different from theirs, whose composition lies between the two pure components.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Intermediate phase\"进行文字解释和论述，答案是一个详细的定义说明，而不是选择、判断或计算。 | 知识层次: 题目考查对中间相（intermediate phase）这一基本概念的定义和特征的理解，属于材料科学中相图部分的基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对\"中间相\"这一概念进行解释和描述，需要考生理解并准确表达其定义和特征。虽然涉及基础概念记忆，但相比简单的定义复述（等级1），它要求更深入的概念解释和描述（等级2），但尚未达到需要阐述复杂概念体系的程度（等级3）。" + }, + { + "idx": 1551, + "question": "4.Coordination number", + "answer": "The number of nearest neighbor atoms around any lattice node atom in the crystal lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Coordination number\"进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征。 | 知识层次: 题目考查的是晶体学中配位数的基本定义，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。题目直接询问\"配位数\"的定义，答案只需简单描述晶体格点中原子的最近邻原子数量，无需进一步解释或复杂论述。这符合等级1\"基本定义简答\"的标准，是同类题型中最简单的难度级别。" + }, + { + "idx": 1552, + "question": "3.Solid solution strengthening", + "answer": "The presence of solute atoms in the solid solution causes lattice distortion of the solvent, thereby hindering dislocation motion and increasing its strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Solid solution strengthening”进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查固溶强化的基本概念和原理，属于对基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释固溶强化的基本原理，涉及对溶质原子引起晶格畸变并阻碍位错运动的理解。虽然需要一定的材料科学基础知识，但不需要复杂的体系阐述或多步骤推理，属于中等难度的概念解释题。" + }, + { + "idx": 1553, + "question": "7. Up-hill diffusion", + "answer": "The diffusion of atoms from a low concentration to a high concentration region, driven by the chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Up-hill diffusion\"进行文字解释和论述，答案提供了概念的定义和驱动机制说明，符合简答题的特征。 | 知识层次: 题目考查对\"Up-hill diffusion\"这一基本概念的定义和驱动机制的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目要求解释\"上坡扩散\"的概念，属于概念解释和描述的难度等级。虽然需要理解化学势梯度这一驱动因素，但不需要阐述复杂的理论体系或进行多步骤分析，因此属于中等难度的概念解释题。" + }, + { + "idx": 1554, + "question": "6. Eutectic transformation", + "answer": "The transformation in a binary alloy where a single liquid phase simultaneously transforms into two different solid phases at a constant temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Eutectic transformation\"进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征 | 知识层次: 题目考查对共晶转变这一基本概念的记忆和理解，属于定义性知识，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要准确表述共晶转变的定义和特征，但不需要深入分析或阐述复杂的概念体系。题目主要考察对基础概念的记忆和理解，属于中等难度。" + }, + { + "idx": 1555, + "question": "8. Aging of aluminum alloys", + "answer": "After high-temperature solution treatment, aluminum alloys are rapidly cooled to form a supersaturated solid solution, followed by the precipitation of metastable phases during subsequent heating and holding processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对铝合金时效过程进行文字解释和论述，答案提供了详细的工艺过程和相变描述，符合简答题的特征 | 知识层次: 题目涉及铝合金时效处理的多步过程（高温固溶处理、快速冷却、亚稳相析出），需要理解概念之间的关联和综合分析，但不需要复杂的机理推理或创新设计。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释铝合金的时效过程，涉及高温固溶处理、快速冷却形成过饱和固溶体以及后续加热保温过程中亚稳相的析出。虽然需要综合多个步骤进行说明，但知识点相对明确，解题步骤较为直接，属于典型的综合分析类简答题。不需要多角度或深度关联性分析，因此符合等级3的标准。" + }, + { + "idx": 1556, + "question": "Based on the relationship between dislocation motion and crystal slip, analyze the relationship between the Burgers vector of a pure screw dislocation and the direction of the dislocation line", + "answer": "The Burgers vector is parallel to the direction of the dislocation line", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述分析位错运动与晶体滑移之间的关系，并具体说明纯螺型位错的Burgers矢量与位错线方向的关系。答案也是以文字形式给出解释，而非选择、判断或计算。 | 知识层次: 题目考查对纯螺型位错的Burgers矢量与位错线方向关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述Burgers矢量与位错线方向的关系这一基础概念，无需额外解释或复杂论述。" + }, + { + "idx": 1557, + "question": "10. First-order phase transition", + "answer": "A phase transition where the free energies of the old and new phases are equal before and after the transition, but their first-order partial derivatives are unequal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"First-order phase transition\"进行文字解释和论述，答案形式为一段描述性文字，符合简答题的特征。 | 知识层次: 题目考查一级相变的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释一级相变的定义，涉及自由能和其一阶偏导数的关系，虽然需要理解并记忆相关概念，但不需要进行复杂的体系阐述或多概念比较分析。因此属于中等难度。" + }, + { + "idx": 1559, + "question": "9. Recrystallization", + "answer": "For plastically deformed metals, during the reheating process, when the temperature exceeds the recrystallization temperature, new grains with low defect density are formed, restoring their properties such as strength to the pre-deformation level, while the phase structure remains unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对再结晶过程进行文字解释和论述，答案提供了详细的描述，符合简答题的特征 | 知识层次: 题目考查对再结晶这一基本概念的记忆和理解，包括再结晶温度、新晶粒的形成及其对材料性能的影响，属于材料科学中的基础概念。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释再结晶过程的基本原理和结果，包括温度条件、晶粒变化和性能恢复等关键点，但不需要深入阐述复杂的概念体系或进行多层次的逻辑推理。这符合等级2对概念解释和描述的要求，比单纯的定义简答（等级1）稍复杂，但未达到需要系统阐述多个相关概念的等级3难度。" + }, + { + "idx": 1560, + "question": "State Fick's second law (one-dimensional) and explain the meaning and units of each physical quantity in the formula", + "answer": "Fick's second law (one-dimensional): ∂C/∂t=D(∂²C/∂x²). In the formula, C is the concentration (g/cm³); D is the diffusion coefficient (cm²/s); t is the time (s); x is the distance (cm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fick第二定律的公式，并说明每个物理量的含义和单位，这需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对Fick第二定律的基本记忆和理解，包括公式中各物理量的含义和单位，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要记忆Fick's第二定律的公式，但更重要的是能够解释公式中每个物理量的含义和单位。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。题目考察的是对基础概念的理解和表达能力，属于该题型中的中等难度。" + }, + { + "idx": 1564, + "question": "Based on the relationship between dislocation motion and crystal slip, analyze the relationship between the Burgers vector of a pure edge dislocation and the direction of dislocation line motion", + "answer": "The Burgers vector is parallel to the direction of dislocation line motion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析位错运动与晶体滑移之间的关系，并解释纯刃位错的Burgers矢量与位错线运动方向的关系，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析刃型位错的Burgers矢量与位错线运动方向之间的关系，这需要理解位错运动的基本原理，并将多个概念（Burgers矢量、位错线运动方向）进行关联和综合分析。虽然不涉及复杂的计算或深度推理，但需要一定的概念理解和应用能力。 | 难度: 在简答题中属于中等难度，需要理解位错运动与晶体滑移的关系，并分析纯刃位错的Burgers矢量与位错线运动方向的关系。虽然题目涉及概念关联和综合分析，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 1567, + "question": "Describe the main characteristics of martensitic transformation.", + "answer": "The fundamental characteristics of martensitic transformation are as follows (primarily the first two points): (1) Diffusionless nature. During martensitic transformation, atomic diffusion is not required, and there is no process of atomic mixing or remixing. The new phase M has exactly the same chemical composition as the parent phase A. (2) Shear nature. Specifically manifested as: $\\textcircled{1}$ Coordinated consistency of transformation: $\\mathbf{A}{\\longrightarrow}\\mathbf{M}$ $\\mathbf{FCC}{\\rightarrow}\\mathbf{BCC}$ ). Through the coordinated movement of atoms (shear), the crystal structure changes from FCC to BCC. The displacement distance of atoms is less than the interatomic spacing. $\\textcircled{2}$ Surface relief effect. On a polished surface, if martensitic transformation occurs, a surface relief effect will be produced during shear. This is due to the lattice deformation causing shape changes in the transformation region. $\\textcircled{3}$ Habit plane. M always precipitates on specific crystallographic planes of the parent phase, accompanied by the shear of the M phase transformation, generally parallel to this plane. This plane is shared by the matrix and the M phase and is called the habit plane. $\\textcircled{4}$ A definite crystallographic orientation relationship exists between the new phase and the parent phase. Two well-known orientation relationships (for steel M transformation) are the K-S relationship and the Nishiyama relationship. In practical materials, martensitic transformation usually deviates from these relationships by a few degrees. (3) Lattice distortion accompanies martensitic transformation. (4) Martensitic transformation has a start temperature $M_{\\mathrm{s}}$ and a finish temperature $M_{\\mathrm{f}}$ (or $M_{z}$ ).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述马氏体相变的主要特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求详细描述马氏体相变的主要特征，涉及扩散性、剪切性质、晶格畸变等多个方面，需要综合运用材料科学中的相变理论、晶体学知识，并进行机理解释。这需要较高的认知能力层次，包括理解、应用、分析和综合。 | 难度: 在简答题题型中，该题目要求对马氏体相变的主要特征进行全面且深入的描述，涉及多个复杂概念和机理解释。具体包括扩散性、剪切性（协调一致性、表面浮凸效应、惯习面、晶体学取向关系）、晶格畸变以及相变温度等。这些内容不仅需要考生具备扎实的基础知识，还需要能够综合运用和推理分析，属于该题型内的高难度题目。" + }, + { + "idx": 1568, + "question": "1. Precipitation (secondary crystallization)", + "answer": "The separation of another solid phase from a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对专业术语进行文字解释和论述，答案是一个定义性的文字描述，不需要计算或选择 | 知识层次: 题目考查的是对\"precipitation (secondary crystallization)\"这一基本概念的定义记忆和理解，属于材料科学中相变的基础知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目要求的是对\"Precipitation (secondary crystallization)\"这一基础概念的直接定义回答，不需要额外的解释或复杂的概念体系阐述。这符合等级1的标准，即仅需记忆和复述基本定义即可完成作答。" + }, + { + "idx": 1569, + "question": "Briefly describe the recovery process of deformed metal during heating and the changes in its microstructure and properties", + "answer": "When the temperature is below the recrystallization temperature, the main processes include the reduction in the concentration of point defects, the elimination of internal stresses, and the change in dislocation configuration, with no alteration in the optical microstructure; at this stage, mechanical properties such as strength, hardness, and plasticity remain largely unchanged, but electrical resistance decreases significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形金属在加热过程中的回复过程及其微观结构和性能的变化，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求描述金属在加热过程中的回复过程及其微观结构和性能的变化，涉及多个概念（点缺陷、内应力、位错构型等）的关联和综合分析，需要理解并应用相关知识来解释现象，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解金属变形后的恢复过程，并能够描述不同温度下的微观结构变化和性能变化。虽然涉及多个概念，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1570, + "question": "Briefly describe the recrystallization process of deformed metal during heating and the changes in its microstructure and properties", + "answer": "After reaching or exceeding the recrystallization temperature, new grains with low defect density will form within the original deformed grains, and the grains are basically equiaxed. At this time, mechanical properties such as strength and physical properties quickly recover to the levels before deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述变形金属在加热过程中的再结晶过程及其微观结构和性能的变化，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对再结晶过程的基本概念和原理的记忆和理解，涉及变形金属在加热过程中的微观结构和性能变化，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述变形金属在加热过程中的再结晶过程及其微观结构和性能的变化，这需要对再结晶的基本原理和过程有一定的理解和记忆，但不需要进行复杂的体系阐述或多概念的整合分析。答案中提到的\"新晶粒形成\"、\"低缺陷密度\"、\"等轴晶\"以及\"力学性能恢复\"等关键点，都属于基础概念的解释和描述范畴。" + }, + { + "idx": 1571, + "question": "2. Space group", + "answer": "A symmetry group formed by the combination of all symmetry elements (including microscopic symmetry elements) in a crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Space group\"进行文字解释和论述，答案是一个完整的定义性陈述，不需要选择、判断或计算。 | 知识层次: 题目考查对空间群这一基本概念的定义记忆，属于晶体学中最基础的概念性知识，仅需回忆和表述标准定义即可完成作答，不涉及任何应用或分析层面的要求。 | 难度: 在简答题题型中，该题目仅要求对\"Space group\"这一基础概念进行定义性回答，属于最基础的定义简答级别。题目不涉及概念间的关联解释或复杂体系阐述，仅需记忆性知识即可完成，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1572, + "question": "8. Dynamic recrystallization", + "answer": "The phenomenon where deformation and recrystallization occur simultaneously above the recrystallization temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dynamic recrystallization\"这一现象进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征。 | 知识层次: 题目考查动态再结晶的基本定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对\"Dynamic recrystallization\"这一概念进行基本定义简答，属于最基础的概念记忆层面。题目不需要解释或描述相关机制，也不涉及复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。在同类定义型简答题中，这是最基础、最简单的难度级别。" + }, + { + "idx": 1573, + "question": "Give examples of the basic strengthening mechanisms of materials", + "answer": "The basic strengthening mechanisms of materials include: solid solution strengthening, work hardening, grain refinement strengthening, and dispersion strengthening. Specific examples: carbon forms a solid solution in ferrite, causing solid solution strengthening; the hardness of pure aluminum sheets increases after repeated processing, and the strength of cold-drawn steel wires significantly improves; modification treatment can refine the strength of cast aluminum alloys, mainly due to grain refinement; the carbides in granular pearlite play the role of dispersion strengthening, and additionally, the finely dispersed carbides in tempered martensite have a good strengthening effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出材料强化机制的例子，答案提供了详细的文字解释和论述，包括具体的例子和机制说明，符合简答题的特征。 | 知识层次: 题目考查对材料强化机制的基本概念的记忆和理解，包括固溶强化、加工硬化、晶粒细化强化和弥散强化等基本原理及其具体例子。 | 难度: 在简答题题型中，该题目要求对材料强化机制的基本概念进行解释和描述，并提供具体例子。虽然需要记忆和理解多个强化机制，但不需要深入分析或构建复杂的概念体系。因此，在简答题的框架内，该题目属于中等难度，即等级2。" + }, + { + "idx": 1574, + "question": "5. Austenite", + "answer": "An interstitial solid solution of carbon dissolved in γ-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Austenite\"进行定义和解释，答案是一个简短的文字描述，符合简答题的特征。 | 知识层次: 题目考查对奥氏体（Austenite）这一基本概念的定义记忆，属于材料科学中最基础的概念之一，不需要复杂的分析或应用。 | 难度: 在简答题题型中，此题属于基本定义简答的难度等级。题目要求回答的是奥氏体的定义，即碳在γ-Fe中的间隙固溶体。这属于基础概念记忆层次，只需要学生准确回忆并复述定义即可，不需要进行概念解释或复杂体系的阐述。在同类简答题中，这是最基础、最简单的类型。" + }, + { + "idx": 1575, + "question": "4. Constitutional supercooling", + "answer": "During crystallization, the phenomenon where a supercooled zone forms in the liquid phase near the solid-liquid interface due to the redistribution of components between the solid and liquid phases is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Constitutional supercooling\"这一现象进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对constitutional supercooling这一现象的基本定义和形成原因的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释和描述一个具体的现象（constitutional supercooling），包括其形成原因和基本过程。虽然不涉及复杂的推导或多概念整合，但需要准确理解并表述该现象的定义和基本原理，比单纯背诵定义（等级1）要求更高。" + }, + { + "idx": 1576, + "question": "In NaCl-type crystals, what type of voids are entirely filled by Na+ ions?", + "answer": "Octahedral", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答特定类型的空隙名称，需要文字解释和论述，而不是从选项中选择或进行判断/计算 | 知识层次: 题目考查对NaCl晶体结构中空隙类型的基础概念记忆，仅需知道Na+离子占据八面体空隙这一基本事实即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答NaCl型晶体中Na+离子占据的空隙类型，属于基础概念记忆的直接简答。题目不涉及概念解释或复杂体系阐述，仅需回忆并写出\"Octahedral\"这一特定术语即可，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 1577, + "question": "6．Critical deformation", + "answer": "The minimum pre-deformation required to cause recrystallization in a metal material when heated above the recrystallization temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Critical deformation\"这一专业术语进行文字解释和论述，答案是一个定义性的陈述，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查Critical deformation的基本定义和概念，属于金属材料再结晶过程中的基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"Critical deformation\"这一基础概念进行定义性回答，属于最基本的概念记忆层面。题目不涉及概念间的联系或复杂解释，完全符合等级1\"基本定义简答\"的标准。在同类定义型简答题中，这是最基础、最直接的提问方式，无需展开论述或分析。" + }, + { + "idx": 1578, + "question": "Explain in detail one of the strengthening mechanisms (using solid solution strengthening as an example)", + "answer": "Dislocation theory explanation of solid solution strengthening: It is necessary to elaborate on the hindering effect of various strengthening factors on dislocation motion to improve material strength. For example, whether substitutional atoms or interstitial atoms, under suitable conditions, may undergo atomic segregation to form atmospheres. For substitutional lattices, when solute atoms are larger in diameter than solvent atoms, solute atoms tend to accumulate in the expanded region of edge dislocations; conversely, they accumulate in the compressed region. Interstitial atoms always tend to accumulate in the expanded region. This phenomenon of diffusion-induced enrichment near dislocations is called the Cottrell atmosphere. The Cottrell atmosphere has a pinning effect on dislocations, increasing the resistance to dislocation motion, thereby enhancing strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释一种强化机制（以固溶强化为例），答案提供了详细的文字解释和论述，包括位错理论和Cottrell气氛的概念，这符合简答题的特征，即需要文字解释和论述。 | 知识层次: 题目要求详细解释固溶强化的位错理论机制，包括柯垂尔气团的形成原理及其对位错运动的阻碍作用。这需要深入理解位错与溶质原子的相互作用，分析不同原子尺寸对位错应力场的影响，并综合运用扩散理论和位错理论来解释强化机理。这种对微观机制的详细阐述和推理分析属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对固溶强化机制进行详细的机理解释，涉及位错理论、柯垂尔气团等专业概念的深入阐述。虽然不需要进行多因素交叉分析（如等级5要求的复杂现象全面分析），但需要对单一强化机制进行机理层面的深度解释，符合等级4\"机理深度解释\"的标准。题目要求将抽象的理论知识与具体材料行为相联系，并组织成连贯的论述，在同题型中属于较高难度的考查要求。" + }, + { + "idx": 1579, + "question": "What type of void does the Cs+ ion occupy in CsCl crystal?", + "answer": "Cubic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释Cs+离子在CsCl晶体中占据的空隙类型，答案\"Cubic\"是一个简短的描述性回答，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查对CsCl晶体结构中Cs+离子占据的空隙类型的基本概念记忆，属于晶体学基础知识的直接回忆。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答Cs+离子在CsCl晶体中占据的空隙类型（立方空隙），不需要进行概念解释或复杂体系阐述。这属于晶体结构中最基础的概念记忆，符合等级1对定义性知识点的直接回忆要求。" + }, + { + "idx": 1580, + "question": "9. Spinodal decomposition", + "answer": "A transformation in which a solid solution decomposes into two solid solutions with the same structure as the parent phase but different compositions through uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Spinodal decomposition\"进行文字解释和论述，答案是一个详细的定义描述，符合简答题的特征 | 知识层次: 题目考查Spinodal decomposition的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释Spinodal decomposition的定义和基本过程，属于概念解释和描述的难度等级。虽然需要理解\"uphill diffusion\"等专业术语，但不需要进行复杂的概念体系阐述或深入分析，因此属于等级2。" + }, + { + "idx": 1581, + "question": "10. Habit plane", + "answer": "During solid-state phase transformation, the new phase often forms along specific atomic planes of the parent phase. The parent phase crystal plane that is parallel to the main plane of the new phase is called the habit plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Habit plane\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对“habit plane”这一基本概念的定义和解释，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求对\"habit plane\"这一基础概念进行定义和简单描述，属于最基本的概念记忆性知识，无需复杂解释或体系阐述。符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1582, + "question": "7. Deformation texture", + "answer": "As the amount of plastic deformation increases, the phenomenon where a certain crystallographic orientation of different grains in a polycrystal tends to become consistent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Deformation texture\"这一概念进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查对\"变形织构\"这一基础概念的定义和现象描述，属于材料科学中晶体变形行为的基本原理记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对\"变形织构\"这一概念进行文字解释和论述，需要理解并描述塑性变形过程中晶粒取向趋于一致的现象。虽然涉及一定的专业术语和原理，但不需要阐述复杂的体系或进行深入分析，符合等级2对概念解释和描述的要求。" + }, + { + "idx": 1583, + "question": "3. Dislocation intersection", + "answer": "The phenomenon where dislocations moving on different slip planes meet and cut through each other during motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation intersection\"现象进行文字解释和论述，答案以描述性文字呈现，符合简答题的特征 | 知识层次: 题目考查位错相交的基本定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求对\"dislocation intersection\"这一基础概念进行简单的文字定义和描述，不需要深入解释或复杂的概念体系阐述。这符合等级1标准中对定义性知识的记忆要求，属于该题型内最基础的难度层级。" + }, + { + "idx": 1584, + "question": "1. The macroscopic symmetry elements of crystals include (1), (2), (3), (4), and (5)", + "answer": "(1) center of symmetry; (2) axis of symmetry; (3) plane of symmetry; (4) rotoinversion axis; (5) rotoreflection axis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举晶体的宏观对称元素，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查晶体宏观对称元素的基本概念记忆和分类，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求列举晶体的宏观对称元素，只需要记忆和复述基础概念，不需要进行深入的解释或复杂的论述。这种类型的题目在简答题中是最基础的，主要考察学生对基本概念的记忆能力。" + }, + { + "idx": 1585, + "question": "In fluorite, what type of voids are entirely occupied by F- ions?", + "answer": "Tetrahedral", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字回答特定类型的空隙（voids），答案是一个专业术语\"Tetrahedral\"，不需要计算或选择，属于简答性质 | 知识层次: 题目考查对氟化钙晶体结构中空隙类型的基础概念记忆，只需知道F-离子占据的是四面体空隙即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（氟离子占据的空隙类型），无需解释或描述概念，更不需要复杂概念体系的阐述。属于最基础的概念记忆性知识，符合等级1的标准。" + }, + { + "idx": 1586, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (11)", + "answer": "(11) interstitial mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（interstitial mechanism）作为答案，属于需要简短文字回答的简答题类型 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，此题仅要求回忆并写出扩散机制的基本名称（间隙机制），属于最基础的定义性知识复现。不需要解释机制原理或比较不同机制，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要描述机制特点（等级2）或分析多种机制适用条件（等级3）的题目简单得多。" + }, + { + "idx": 1587, + "question": "In the heterogeneous nucleation model, what value of the contact angle θ between the nucleus and the substrate plane cannot promote nucleation?", + "answer": "π", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求选择一个特定的接触角θ值（π）作为不能促进成核的答案，这符合选择题的特征，即从多个可能的选项中选择一个正确答案。 | 知识层次: 题目考查对异质成核模型中接触角θ的基本概念记忆，只需要知道θ=π时无法促进成核这一基本原理即可回答，无需复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解接触角θ与异质形核之间的关系，并能识别π弧度（180度）时无法促进形核的特殊情况。虽然涉及基础概念记忆，但需要一定的概念理解才能正确选择答案。" + }, + { + "idx": 1588, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (12)", + "answer": "(12) interstitial mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体固体中扩散的微观机制，需要文字描述和论述，答案形式为简短的术语填空而非选择或计算 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题-基础概念记忆题型中，此题仅要求回答扩散机制的具体名称（填隙机制），属于最基础的定义简答级别。不需要解释或阐述，完全符合等级1\"基本定义简答\"的标准。相比需要描述机制特点（等级2）或比较多种扩散机制（等级3）的题目，此题的记忆要求最为基础。" + }, + { + "idx": 1589, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (13)", + "answer": "(13) vacancy mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体固体中扩散的微观机制，需要文字描述具体的扩散机制（空位机制），属于简答题类型 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆类，仅需回答扩散机制的具体名称（空位机制），无需展开解释或论述。相比需要描述概念特征（等级2）或构建复杂理论体系（等级3）的简答题，此题仅考查单一术语的识记，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1590, + "question": "In the heterogeneous nucleation model, when the contact angle θ between the nucleus and the substrate plane is π/2, what fraction of the homogeneous nucleation energy is the nucleation energy?", + "answer": "Half", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定条件下（接触角θ=π/2）异质形核能与均质形核能的比例关系，答案需要文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目涉及异质成核模型中的能量计算，需要理解接触角与成核能的关系，并进行简单的数学推导（cos(π/2)=0导致能量减半），属于多步骤的概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解异质成核模型中的接触角概念，并能将其与均质成核能量进行关联计算。虽然涉及多步计算和概念关联，但题目给出了具体的接触角值（π/2），降低了分析复杂度，属于典型的综合分析类问题。" + }, + { + "idx": 1591, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (14)", + "answer": "(14) exchange mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的微观机制，答案需要文字描述具体的机制名称（exchange mechanism），属于简答题类型 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答扩散的微观机制之一（交换机制），属于基础概念记忆层面的简单回忆，不需要解释或论述。同类题型中，这属于最基本的知识点复现要求，解题步骤仅涉及单一术语的提取，难度最低。" + }, + { + "idx": 1592, + "question": "Small-angle grain boundaries are composed of dislocations, among which symmetric tilt grain boundaries are composed of what type of dislocations?", + "answer": "Edge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答特定类型的位错（Edge），需要简要的文字解释而非选择、判断或计算 | 知识层次: 题目考查对称倾斜晶界由何种位错组成的基础概念记忆，属于材料科学中晶界和位错的基本知识，不需要复杂的推理或综合分析。 | 难度: 在简答题题型中，该题目仅要求回答对称倾斜晶界由何种位错组成，属于基础概念记忆层面的直接简答。题目不涉及概念解释或复杂体系阐述，仅需回忆并写出\"Edge\"这一单字答案，符合等级1\"基本定义简答\"的标准。在同类记忆性简答题中属于最基础难度层级。" + }, + { + "idx": 1593, + "question": "Small-angle grain boundaries are composed of dislocations, among which twist boundaries are composed of what type of dislocations?", + "answer": "Screw", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答特定类型的位错（screw），需要简要的文字解释，而不是从多个选项中选择或判断对错，也不涉及计算。 | 知识层次: 题目考查对晶界类型及其位错组成的基础概念记忆，属于材料科学中晶体缺陷章节的基础知识点，仅需识别扭转晶界由螺型位错组成这一事实性知识，无需复杂推理或综合分析。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并回答特定类型位错（螺位错）的名称，无需解释或论述其形成机制或与其他概念的关联。" + }, + { + "idx": 1594, + "question": "1. What is aging treatment?", + "answer": "The process of treating the precipitation of a supersaturated solid solution is called aging treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"aging treatment\"进行文字解释和论述，答案是一个定义性的简短描述，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即\"aging treatment\"的定义和基本原理，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层面。题目没有要求解释原理、分类或应用场景，仅需直接复述\"aging treatment\"的定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1595, + "question": "6．Adsorption occurring on solid surfaces can be divided into two types: (17) and (18).", + "answer": "(17) Physical adsorption; (18) Chemical adsorption", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空白处的答案，需要根据知识进行文字回答，而不是选择、判断或计算。 | 知识层次: 题目考查固体表面吸附的分类，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，此题属于基本定义简答类型。题目仅要求填写两种吸附类型的名称，不需要进行概念解释或复杂阐述。考察的是对基础概念（物理吸附和化学吸附）的简单记忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1599, + "question": "What is the difference in deformation mode between slip and twinning, the two mechanisms of metal plastic deformation?", + "answer": "The slip process involves the relative sliding of one part of the crystal relative to another, while the twinning process involves the uniform shear of one part of the crystal relative to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查金属塑性变形中滑移和孪生两种机制的基本概念和区别，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释两种金属塑性变形机制（滑移和孪生）的变形模式差异，需要学生对这两个基础概念有清晰的理解，并能用文字准确描述其区别。虽然涉及两个概念的比较，但不需要深入分析或构建复杂的概念体系，因此属于中等难度（等级2）。" + }, + { + "idx": 1600, + "question": "Explain the reason for the shape memory effect produced by martensitic transformation", + "answer": "The fundamental reasons are the diffusionless nature, coherent shear characteristics, and reversible transformation of martensitic transformation. During the cooling process of the parent phase, external stress induces martensitic transformation, utilizing the pseudoelasticity of martensitic transformation to produce macroscopic deformation. During the heating process, when the temperature exceeds the reverse transformation temperature of martensitic transformation, shape recovery occurs along with the reverse transformation of thermoelastic martensite, completing the shape memory process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变产生形状记忆效应的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体相变产生形状记忆效应的原因，涉及扩散性、相干剪切特性和可逆相变等复杂机理，需要综合运用材料科学知识进行推理分析，思维过程深度较高。 | 难度: 在简答题-复杂分析题型中，该题目要求对马氏体相变的形状记忆效应进行机理深度解释。需要综合运用扩散特性、相干剪切特征和可逆相变等核心概念，并完整描述冷却/加热过程中的相变机制与宏观变形的关系。虽然不涉及多系统交互或跨学科整合（等级5特征），但已超出基础概念复述层面，属于对单一复杂现象的机理性剖析，符合等级4的深度要求。" + }, + { + "idx": 1601, + "question": "3. In practical applications, what treatment methods can be used to eliminate age hardening? Why?", + "answer": "Age hardening can be eliminated through reversion treatment or re-solution treatment. This is because the second phase precipitated during aging will dissolve back into the solid solution during reversion treatment or re-solution treatment. When the precipitated phase has already become a stable phase, only solution treatment can be used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释消除时效硬化的处理方法及其原因，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释消除时效硬化的处理方法及其原理，涉及多个概念（时效硬化、回归处理、固溶处理）的关联和综合分析，需要理解不同处理方法的适用条件和作用机制，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解年龄硬化的基本概念，还需要掌握消除年龄硬化的具体方法（回火处理或再溶解处理）及其背后的原理（第二相溶解回固溶体）。此外，题目还要求考生能够区分在不同情况下（如沉淀相已成为稳定相时）适用的处理方法。这种多角度分析论述的要求使得该题目在简答题中属于较高难度等级。" + }, + { + "idx": 1603, + "question": "What is the difference in continuity between the two metal plastic deformation mechanisms of slip and twinning?", + "answer": "The slip process can proceed continuously while the twinning process cannot proceed continuously.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制（滑移和孪生）在连续性方面的差异，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查对金属塑性变形两种机制（滑移和孪生）的基本概念记忆和理解，特别是它们连续性的差异。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目涉及两个金属塑性变形机制的比较，但只需简要说明滑移和孪生过程的连续性差异即可，不需要深入阐述复杂概念体系或进行多步骤分析。这符合等级2对概念解释的基本要求，但尚未达到等级3的复杂程度。" + }, + { + "idx": 1604, + "question": "What is the difference in critical shear stress between the two metal plastic deformation mechanisms of slip and twinning?", + "answer": "The critical shear stress required for twinning is much greater than that for slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制（滑移和孪生）在临界剪切应力上的差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属塑性变形两种机制（滑移和孪生）的基本概念记忆和理解，特别是临界剪切应力的差异这一基本原理。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释两种金属塑性变形机制（滑移和孪生）在临界剪切应力方面的差异，这需要学生对这两种机制的基本概念有一定理解，并能进行比较描述。虽然涉及两个概念的对比，但不需要复杂的体系阐述或深入分析，因此属于中等难度。" + }, + { + "idx": 1605, + "question": "2. Explain the reasons for strengthening through aging treatment.", + "answer": "During the precipitation process of a supersaturated solid solution, the initially formed metastable precipitates maintain coherent or semi-coherent interfaces with the matrix phase. If the precipitate particles possess high strength, they will cause the gliding dislocations to bend and bypass the second-phase particles, leaving dislocation loops behind. This increases the dislocation line length, and both the second-phase particles and the dislocation loops enhance the resistance to subsequent dislocation motion, resulting in second-phase strengthening. If the precipitate particles can undergo deformation, new phase interfaces will form, disrupting the coherent (or semi-coherent) interfaces between the precipitates and the matrix phase. The slip planes will experience misfit, potentially destroying the ordered arrangement. In summary, macroscopic strengthening is achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释时效处理强化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释时效处理强化的原因，涉及析出相与基体相的界面关系、位错运动机制、强化机理等复杂概念的综合分析和推理。需要深入理解材料微观结构与宏观性能之间的关系，并进行多层次的机理解释。 | 难度: 在简答题的复杂分析题型中，该题目要求全面解释时效强化的多个机理（包括共格/半共格界面、位错绕过机制、位错环形成、有序排列破坏等），需要综合运用材料科学原理进行多层次的推理分析。题目不仅考察单一知识点，还要求将多个复杂现象串联成完整的强化机制解释，属于该题型框架内最高难度的综合分析类题目。" + }, + { + "idx": 1606, + "question": "What is the difference between the effects of slip and twinning, these two metal plastic deformation mechanisms, on the crystal orientation relationship?", + "answer": "The twinning process alters the crystal orientation relationship. The slip process does not change the crystal orientation relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制对晶体取向关系的影响，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对金属塑性变形机制（滑移和孪生）对晶体取向关系影响的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要区分两种塑性变形机制（滑移和孪生）对晶体取向关系的影响，但仅涉及基础概念的对比，不需要深入分析或复杂体系阐述。解题步骤相对简单，只需准确描述两种机制的基本差异即可。" + }, + { + "idx": 1607, + "question": "What are the causes and movement characteristics of Shockley partial dislocations in face-centered cubic crystals?", + "answer": "In face-centered cubic crystals, Shockley partial dislocations are generated by non-uniform slip. They can be edge dislocations, screw dislocations, or mixed dislocations, and are capable of slipping.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Shockley partial dislocations在面心立方晶体中的成因和运动特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Shockley不全位错的成因和运动特性，涉及非均匀滑移的机理、位错类型（刃型、螺型、混合型）及其滑移能力，需要综合运用位错理论和晶体结构知识进行推理分析和机理解释，思维深度较高。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析Shockley不全位错的成因和运动特性，涉及非均匀滑移的机理解释、不同类型位错（刃型、螺型、混合型）的区分以及滑移能力的阐述。这需要综合运用晶体缺陷理论、滑移系统知识，并进行多层次的机理推理，属于该题型框架内最高难度的复杂现象全面分析要求。" + }, + { + "idx": 1608, + "question": "7．The main resistances to solid-state phase transformation are (19) and (20)", + "answer": "(19) interfacial energy; (20) elastic strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个主要阻力，需要文字解释和论述，答案形式为填空式的简答形式 | 知识层次: 题目考查对固态相变主要阻力的基本概念记忆，即界面能和弹性应变能，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答固态相变的主要阻力，只需要记忆并准确写出两个基本概念（界面能和弹性应变能）即可，无需进行额外的解释或论述。这符合基础概念记忆的知识层次要求，解题步骤简单直接，属于该题型内最基础的难度水平。" + }, + { + "idx": 1609, + "question": "What is a perfect dislocation?", + "answer": "A dislocation whose Burgers vector equals a lattice vector is called a perfect dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"perfect dislocation\"进行文字解释和论述，答案提供了定义性的文字描述，符合简答题的特征。 | 知识层次: 题目考查对完美位错这一基本概念的定义记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答一个基本定义，即\"完美位错\"的概念。属于最基础的定义简答类问题，不需要额外的解释或复杂概念体系的阐述，符合等级1的基本定义简答标准。" + }, + { + "idx": 1610, + "question": "What are the differences in the roles of slip and twinning as two mechanisms of metal plastic deformation during plastic deformation?", + "answer": "Slip is the primary mechanism of plastic deformation. When the slip system is unfavorable for slip deformation to occur, twinning can alter the orientation of the slip system relative to the external force, enabling further slip deformation to proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制（滑移和孪生）在塑性变形过程中的作用差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种金属塑性变形机制（滑移和孪生）在塑性变形过程中的不同作用，并涉及机制之间的相互作用和条件分析。这需要综合运用相关知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题（复杂分析类）中属于机理深度解释难度。题目要求对比两种塑性变形机制（滑移和孪生）的作用差异，需要深入理解晶体结构、位错运动、取向变化等材料科学核心机理，并能解释两者在变形过程中的协同作用。虽然不涉及多系统交互或动态过程分析（等级5特征），但已超出基础概念复述层面，属于需要整合多个知识模块进行机理阐述的中高难度题目。" + }, + { + "idx": 1611, + "question": "What is the shape memory effect?", + "answer": "When certain metal materials are deformed and then heated above a specific temperature, the deformed metal materials return to their pre-deformation shape. This phenomenon is called the shape memory effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"shape memory effect\"进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查形状记忆效应的基本定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答形状记忆效应的基本定义，不需要进行额外的解释或描述，也不需要涉及复杂的概念体系。学生只需记忆并准确复述该现象的定义即可完成作答，属于该题型内最基础的难度级别。" + }, + { + "idx": 1612, + "question": "What are the formation and movement characteristics of Frank partial dislocations in face-centered cubic crystals?", + "answer": "Frank partial dislocations are caused by the removal or insertion of a close-packed plane, and their Burgers vector is perpendicular to the slip plane. Therefore, Frank partial dislocations cannot glide but can only climb.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Frank partial dislocations的形成和运动特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Frank不全位错的形成和运动特性，涉及位错理论中的高级概念（如Burgers矢量方向与滑移面的关系、位错攀移机制等），需要综合运用晶体结构、位错理论和缺陷动力学知识进行机理层面的分析解释，属于对专业知识的深度理解和复杂应用。 | 难度: 在简答题的复杂分析题型中，该题目要求对Frank不全位错的形成和运动特性进行机理深度解释。需要综合运用晶体结构、位错理论和扩散机制等知识，解释为什么Frank不全位错只能攀移而不能滑移。虽然不涉及多个复杂现象的全面分析（等级5），但需要对位错行为的物理本质有深入理解，属于机理深度解释的难度等级。" + }, + { + "idx": 1613, + "question": "Metallic bond", + "answer": "The bonding force between metal atoms formed by the interaction between metal cations and free electrons is called metallic bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对金属键进行文字解释和论述，答案以文字形式给出，没有选项或计算要求 | 知识层次: 题目考查金属键的基本定义和形成原理，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答金属键的基本定义，属于最基础的概念记忆层面。题目不涉及概念解释或复杂体系阐述，仅需简单复述定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1614, + "question": "Interstitial solid solution", + "answer": "When the solute atoms are relatively small, they can enter the interstitial sites of the solvent lattice, and the solid solution formed in this way is called an interstitial solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Interstitial solid solution\"进行文字解释和论述，答案提供了详细的定义和形成机制，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体这一基本概念的定义和形成条件的记忆和理解，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。题目仅涉及\"间隙固溶体\"这一单一概念的定义，不需要进行额外的解释或复杂概念的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1615, + "question": "Schottky vacancy", + "answer": "A vacancy formed by the migration of a displaced atom to the outer surface or internal interface (such as grain boundaries, etc.) is called a Schottky vacancy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对Schottky vacancy进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征 | 知识层次: 题目考查Schottky空位的定义，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述Schottky vacancy的定义，不涉及复杂概念解释或体系阐述。" + }, + { + "idx": 1616, + "question": "The _（3）__ of an atom or ion refers to the number of atoms directly adjacent to it in the crystal structure or the number of all hetero-ions combined with it.", + "answer": "（3）coordination number", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（coordination number）来完成句子，这属于简答题的范畴，需要考生回忆并准确写出相关概念。 | 知识层次: 题目考查的是对\"coordination number\"这一基本概念的记忆和理解，属于定义性知识，不涉及复杂应用或分析。 | 难度: 在简答题中属于基本定义简答，仅需要回忆并准确写出\"coordination number\"这一术语的定义，无需额外解释或复杂概念阐述。题目直接给出了定义的关键部分，属于最基础的概念记忆层次。" + }, + { + "idx": 1617, + "question": "The equilibrium concentration of point defects increases with the rise of __ (4).", + "answer": "(4) temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（temperature）来补全句子，属于简答题的范畴，需要简短的回答而非选择或计算。 | 知识层次: 题目考查点缺陷平衡浓度与温度关系的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回忆并填写一个基本概念（温度对点缺陷平衡浓度的影响），属于最基础的定义性知识。无需解释或论述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要描述缺陷形成机制（等级2）或分析多种因素相互作用（等级3）的题目简单得多。" + }, + { + "idx": 1618, + "question": "When titanium oxide is oxygen-deficient, the following reaction can occur: $\\\\mathrm{TiO}_{2}-\\\\frac{1}{2}0_{2}{\\\\rightarrow}\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}+\\\\mathrm{V}_{0}^{\\\\ast}$. Please correctly write the defect equation and explain the meaning of each term.", + "answer": "The defect equation is $2\\\\mathrm{TiO}_{2}-\\\\frac{1}{2}0_{{2}}{\\\\rightarrow}2\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}+\\\\mathrm{V}_{0}^{\\\\ast}+30_{0}$. $\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}$: Titanium dioxide loses oxygen, generating $\\\\mathbb{T}^{3+}$ occupying the $\\\\mathbf{Ti}^{4+}$ lattice site, with an effective charge of -1. $\\\\mathbf{V}_{0}^{*}$: Oxygen vacancy, with an effective charge of $^{+2}$. $0_{\\\\mathfrak{o}}$: Oxygen still occupies the oxygen lattice site.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求正确写出缺陷方程并解释每个术语的含义，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求正确书写缺陷方程并解释各项含义，涉及多步概念关联和综合分析。需要理解氧缺陷反应机理、电荷补偿原理以及缺陷符号表示方法，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要正确书写缺陷方程并解释每个术语的含义，涉及多步计算和概念关联，综合分析能力要求较高。" + }, + { + "idx": 1621, + "question": "The process in which a single solid phase simultaneously precipitates two new solid phases with different compositions and crystal structures is called (8)__ transformation", + "answer": "(8) eutectoid", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（eutectoid transformation），而不是从多个选项中选择或判断对错，也不需要计算。这种形式属于简答题，需要考生回忆并写出正确的术语。 | 知识层次: 题目考查对eutectoid transformation这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回忆并填写一个特定的专业术语（eutectoid transformation），不需要进行概念解释或复杂体系阐述。这符合基础概念记忆层次的要求，属于该题型内最简单的难度等级。" + }, + { + "idx": 1622, + "question": "If different atomic planes in a crystal are represented by letters such as A, B, C, D, etc., the stacking sequence of atoms in a face-centered cubic crystal is _(1)_, and the stacking sequence of atoms in a hexagonal close-packed crystal is _(2)_.", + "answer": "(1) ABCABCABC...; (2) ABABAB.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的堆叠序列，需要文字描述而非选择或判断，且答案形式为简短的文字序列。 | 知识层次: 题目考查晶体结构中面心立方和六方密堆积原子堆垛顺序的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求记忆并复述面心立方和六方密堆积两种晶体结构的原子堆垛序列，不涉及概念解释或复杂体系阐述。这是晶体学中最基础的堆垛顺序记忆知识点，在简答题框架内属于最基础的难度等级。" + }, + { + "idx": 1624, + "question": "The formation of nuclei in a homogeneous liquid phase through conditions such as structural fluctuations and energy fluctuations is called (10) nucleation", + "answer": "(10) homogeneous", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（homogeneous nucleation）来完成句子，而不是从多个选项中选择、判断对错或进行数值计算。这种形式更接近于简答题，需要考生回忆并填写正确的专业术语。 | 知识层次: 题目考查基本概念的记忆和理解，即均相成核的定义，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写一个特定的术语（homogeneous）来完成关于成核现象的定义，这仅需要学生对基础概念的记忆，不需要进行解释或描述。因此，在简答题的框架内，这属于最简单的难度等级。" + }, + { + "idx": 1625, + "question": "What is the driving force for nucleation in solid-state phase transformations?", + "answer": "The difference in free energy between the new phase and the parent phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案是一个简短的文字描述而非选择、判断或计算 | 知识层次: 题目考查固态相变中成核驱动力的基本概念，仅需记忆和理解自由能差这一基本原理，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（自由能差），属于最基础的概念记忆层面。不需要展开解释或描述复杂机制，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要解释成核能垒（等级2）或阐述形核动力学（等级3）的问题简单得多。" + }, + { + "idx": 1626, + "question": "The imperfect dislocation caused by inserting or removing a close-packed plane is called _ (7) _ imperfect dislocation", + "answer": "(7) Frank", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Frank）来补全句子，属于需要准确回忆和填写特定知识点的简答题类型。 | 知识层次: 题目考查对Frank不完全位错这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，此题仅要求填写一个特定术语（Frank），属于最基础的定义性知识回忆。不需要解释或描述概念，更不涉及复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1627, + "question": "Given that the yield strength of industrial pure copper is $\\\\sigma{\\\\mathrm{s}}=70\\\\mathrm{MPa}$, with a grain size of $N{\\\\mathbf{A}}=18$ per $\\\\nearrow\\\\mathbf{mm}^{2}$; when $N{\\\\mathbf{A}}=4025$ per $/\\\\mathbf{m}\\\\mathbf{m}^{2}$, $\\\\pmb{\\\\sigma{\\\\mathrm{s}}=95\\\\mathrm{MPa}}$; calculate the yield strength ${\\\\pmb{\\\\sigma}}{\\\\mathfrak{s}}$ when $N{\\\\mathrm{A}}=260$ per $\\\\scriptstyle\\\\left/\\\\mathbf{mm}^{2}\\\\right.$.", + "answer": "The relationship between grain size and yield strength satisfies the Hall-Petch formula, i.e., $$ \\\\sigma_{\\\\mathrm{s}}=\\\\sigma_{0}+K d^{-1/2} $$ Representing grain size by the diameter of an equal-area circle, thus $$ \\\\begin{array}{c}{{d=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{N_{\\\\mathrm{a}}}\\\\right)^{1/2}}}\\\\\\\\ {{d_{1}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{18}\\\\right)^{1/2}=0.22\\\\mathrm{mm}}}\\\\\\\\ {{d_{2}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{4025}\\\\right)^{1/2}=1.45\\\\times10^{-2}\\\\mathrm{mm}}}\\\\\\\\ {{d_{3}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{260}\\\\right)^{1/2}=5.71\\\\times10^{-2}\\\\mathrm{mm}}}\\\\\\\\ {{\\\\sigma_{\\\\mathrm{s}1}=\\\\sigma_{0}+K d_{1}^{\\\\mathrm{\\\\Gamma}-1/2},\\\\sigma_{\\\\mathrm{s}2}=\\\\sigma_{0}+K d_{2}^{\\\\mathrm{\\\\Gamma}-1/2}}}\\\\end{array} $$ Substituting ${\\\\pmb\\\\sigma}_{\\\\mathrm{s}1}=70\\\\mathrm{MPa},{\\\\pmb\\\\sigma}_{\\\\mathrm{s}2}=95\\\\mathrm{MPa}$ to solve for $K=0.13\\\\mathrm{MPa\\\\cdot m^{1/2}},\\\\sigma_{0}=61.3\\\\mathrm{MPa}$, hence $\\\\sigma_{\\\\mathrm{s}}=78.3\\\\mathrm{MPa}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解屈服强度，涉及Hall-Petch公式的应用和具体数值的代入计算 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值代入和求解，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，包括晶粒尺寸转换、公式推导和参数求解。虽然计算步骤较多，但每个步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 1628, + "question": "Negative temperature gradient", + "answer": "In the liquid phase at the crystallization front, the distribution where the temperature gradually decreases from the solid-liquid interface toward the interior of the liquid phase is called a negative temperature gradient", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Negative temperature gradient\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征 | 知识层次: 题目考查对负温度梯度这一基本概念的定义和描述，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，即\"负温度梯度\"的概念。不需要进行额外的解释或描述，更不需要复杂的概念体系阐述。属于最基础的定义简答类型，符合等级1的标准。" + }, + { + "idx": 1629, + "question": "A dislocation whose Burgers vector equals a lattice vector is called __ (5)_", + "answer": "(5) perfect dislocation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语来补全句子，需要根据知识储备写出正确答案，而不是从选项中选择或判断对错。答案是一个专业术语\"perfect dislocation\"，属于简答形式。 | 知识层次: 题目考查对位错类型的基本概念记忆，特别是Burgers vector与晶格向量关系的定义，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（perfect dislocation的定义），属于最基础的概念记忆层面。不需要解释或描述，更不需要复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1630, + "question": "In the equilibrium phase diagram of an alloy, to determine the proportions of the various phases present in the alloy at a certain temperature and composition, the __(9)__ rule can be applied using an isothermal tie line for calculation.", + "answer": "(9) lever", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写一个特定的术语（lever rule）来完成句子，虽然答案简短，但需要理解概念并准确应用，属于简答题的范畴。 | 知识层次: 题目考查杠杆法则在相图中的应用，属于基本公式的直接套用，不需要复杂的分析或综合过程。 | 难度: 在简答题中属于简单应用过程描述，仅需直接套用杠杆规则的概念，无需深入解释或实例说明。题目要求的知识点掌握深度和解题步骤复杂度较低，符合等级2的标准。" + }, + { + "idx": 1631, + "question": "What are the main resistances to nucleation in solid-state phase transformations?", + "answer": "Interfacial energy and elastic strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述固态相变中成核的主要阻力，答案以文字形式给出，没有选项或计算要求。 | 知识层次: 题目考查对固态相变中成核阻力的基本概念的记忆和理解，主要涉及界面能和弹性应变能这两个基础概念，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要回答两个主要阻力（界面能和弹性应变能），但不需要深入阐述复杂的概念体系或进行多层次的论述。题目主要考察对基础概念的记忆和理解，属于中等难度的简答题。" + }, + { + "idx": 1632, + "question": "In face-centered cubic crystals, the partial dislocation caused by (6)__ is called the Shockley partial dislocation", + "answer": "(6) non-uniform slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（\"non-uniform slip\"）来完成句子，这需要学生对相关概念有准确的理解和记忆，属于简答题类型。虽然形式上类似于填空题，但本质上需要学生对材料科学中的专业术语有深入理解，因此归类为简答题更为合适。 | 知识层次: 题目考查对Shockley部分位错这一基本概念的记忆和理解，属于材料科学中晶体缺陷的基础知识范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回忆并填写一个特定的术语（\"non-uniform slip\"），属于基础概念记忆层面的直接提问。不需要解释或论述，符合等级1\"基本定义简答\"的标准，是同类题型中最简单的类型。" + }, + { + "idx": 1633, + "question": "The dislocation that can produce cross-slip must be a _ (20) dislocation", + "answer": "screw-type", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写一个特定的术语（screw-type）作为答案，而不是从多个选项中选择或判断对错，也不需要计算或详细论述。 | 知识层次: 题目考查对位错类型（刃型位错和螺型位错）的基本概念记忆，特别是螺型位错能够产生交滑移的特性。这属于基础概念的记忆和理解层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要理解\"cross-slip\"和\"screw-type dislocation\"的概念关系，但不需要进行复杂的概念体系阐述。题目考查的是对位错类型及其特性的基本理解，属于中等难度的概念解释题。" + }, + { + "idx": 1634, + "question": "The adsorption occurring on the surface of solids can be divided into two types: (15) and (16).", + "answer": "(15) Physical adsorption; (16) Chemical adsorption", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个特定类型的吸附，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查固体表面吸附的基本分类，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答两种吸附类型的名称，属于最基础的定义简答。题目不涉及概念解释或复杂体系阐述，仅测试学生对基础分类的记忆能力，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1635, + "question": "According to the different atomic arrangement structures at the interface, the phase interfaces in solids can be divided into _(17), (18), and (19) interfaces.", + "answer": "(17) coherent; (18) incoherent; (19) semi-coherent", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定术语来完成句子，需要学生对材料科学中的相界面类型有准确的理解和记忆，属于需要文字回答的简答题类型。 | 知识层次: 题目考查对固体中相界面分类的基础概念记忆，属于定义和分类的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写固体中相界面的三种分类，这属于基础概念的记忆性知识，不需要进行复杂的解释或论述。学生只需回忆并准确写出三种相界面的名称即可，解题步骤简单，对知识点的掌握深度要求较低。" + }, + { + "idx": 1636, + "question": "If 6kg of austenite with a carbon content of w_c=0.45% is slowly cooled below 727%, what is the proeutectoid phase?", + "answer": "If 6kg of austenite with a carbon content of w_c=0.45% is slowly cooled below 727%, the proeutectoid phase is proeutectoid ferrite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释在特定条件下形成的相变产物，需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对铁碳相图中奥氏体冷却转变的基本概念记忆，特别是对先共析相（proeutectoid phase）的理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并描述在特定条件下（6kg奥氏体，碳含量0.45%，缓慢冷却至727℃以下）的先共析相是什么。这需要考生掌握铁碳相图的基本知识，能够识别给定碳含量下的相变过程，并准确描述先共析相的形成。虽然涉及一定的相图知识，但不需要复杂的体系阐述或深入分析，因此属于等级2难度。" + }, + { + "idx": 1637, + "question": "Plastic deformation of metal polycrystals requires at least (14) independent slip systems to be activated", + "answer": "(14) five", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的数值（14）并补充说明（five），这需要简要的文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查金属多晶体塑性变形所需独立滑移系统数量的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答类型。题目仅要求回忆并写出金属多晶体塑性变形所需的独立滑移系统数量（14个），属于最基础的概念记忆性知识，无需解释或论述。在简答题的三个难度等级中，这属于最简单的等级1。" + }, + { + "idx": 1638, + "question": "What changes occur in the microstructure of plastically deformed metals?", + "answer": "The strengthening factors of martensite include the interstitial solid solution strengthening effect of carbon atoms; the pinning effect of C atom clusters on dislocations; C atoms entering the flattened octahedral centers of the martensite crystal structure, causing asymmetric lattice expansion (forming a distorted dipole stress field), resulting in strong interstitial solid solution strengthening; and the strengthening effects of grain boundaries, dislocations, and twins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释塑性变形金属微观结构的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释塑性变形金属微观结构的变化，涉及多种强化机制的综合分析，包括固溶强化、位错钉扎效应、晶格畸变应力场等复杂机理的关联解释，需要深入理解材料变形过程中的微观结构演变和多种强化因素的相互作用。 | 难度: 在简答题的复杂分析题型中，该题目要求对塑性变形金属的微观结构变化进行全面分析，涉及多个强化机制的详细解释和相互作用。需要综合运用材料科学知识，进行深入的推理分析和机理解释，属于该题型内最高难度的题目。" + }, + { + "idx": 1639, + "question": "What is the total amount of ferrite and cementite in kilograms in the final room-temperature equilibrium microstructure?", + "answer": "According to the lever rule, the amounts of ferrite and cementite in the final room-temperature equilibrium microstructure are m_α=(6.70-0.45)/(6.70-0.022)×100%×6kg=5.64kg, m_Fe3C=(0.45-0.022)/(6.70-0.022)×100%×6kg=0.36kg, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算铁素体和渗碳体的总量，答案中包含了具体的数值计算过程和公式应用（杠杆定律），符合计算题的特征。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及铁碳相图中铁素体和渗碳体的成分比例计算，需要理解相图的基本原理并进行数值运算，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆规则进行多步计算，涉及成分转换和百分比计算，同时需要理解铁碳相图的基本概念。虽然计算步骤明确，但需要综合运用多个知识点并保持计算准确性，属于中等偏上的难度。" + }, + { + "idx": 1640, + "question": "What changes occur in the properties of plastically deformed metals?", + "answer": "The strength and toughness of martensite are closely related to its carbon content, microstructure morphology, and substructure. In iron-carbon alloys, when the carbon content wc<0.3%, lath martensite forms with a dislocation substructure, exhibiting lower strength but good plasticity and toughness; when wc>1.0%, plate martensite forms with a twin substructure, showing high strength but poor plasticity and toughness; for 0.3%2)$ in the crystal structure, crystals are divided into lower (no higher-order axis), intermediate (one higher-order axis), and higher (more than one higher-order axis) crystal families.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对晶体家族进行分类并解释分类依据，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体家族的基本分类标准，属于对基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求对晶体家族进行分类，但只需要基于单一标准（高阶轴数量）进行划分，不需要涉及复杂的概念体系或深入的分析。相比等级1的基本定义简答，该题目需要稍多的解释和描述，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 1654, + "question": "Phase equilibrium", + "answer": "The chemical potentials of each phase in the system are equal, and the chemical potentials of each component in each phase are equal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对相平衡的概念进行文字解释和论述，答案提供了详细的描述而非选择、判断或计算。 | 知识层次: 题目考查相平衡的基本概念，即化学势在相平衡中的条件，属于基本原理的记忆和理解。 | 难度: 在简答题题型中，该题目仅要求回答相平衡的基本定义，即化学势相等的条件。这属于最基础的概念记忆，不需要额外的解释或复杂概念的阐述。因此在该题型和知识层次下属于最低难度等级。" + }, + { + "idx": 1655, + "question": "Electronic compound", + "answer": "Belongs to intermetallic compounds, where the electron concentration, defined as the ratio of the total number of valence electrons to the total number of atoms, is approximately 1.4 when the alloy reaches its maximum solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对电子化合物进行解释和论述，答案提供了详细的文字描述和定义，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对电子化合物（Electronic compound）的基本定义和特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释电子化合物的定义及其关键参数（电子浓度），并说明其在合金中的特定条件（最大溶解度时约为1.4）。虽然涉及具体数值，但整体仍属于对基础概念的解释，不需要复杂推导或多层次概念整合，符合等级2的特征。" + }, + { + "idx": 1658, + "question": "Steady-state diffusion", + "answer": "A diffusion process in which the concentration at any point in the diffusion system does not change with time", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Steady-state diffusion\"进行文字解释和论述，答案是一个定义性的陈述，不需要选择、判断或计算 | 知识层次: 题目考查对稳态扩散这一基本概念的记忆和理解，不需要复杂的应用或分析，仅需解释定义即可。 | 难度: 在简答题题型中，该题目仅要求对\"Steady-state diffusion\"进行基本定义回答，不需要额外的解释或描述，属于最基础的概念记忆性知识。题目内容直接明确，解题步骤简单，只需回忆并写出定义即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1659, + "question": "Dynamic recrystallization", + "answer": "The phenomenon where deformation and recrystallization occur simultaneously above the recrystallization temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Dynamic recrystallization\"这一现象进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征。 | 知识层次: 题目考查动态再结晶这一基础概念的定义，属于记忆和理解层次的知识点，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要准确记忆动态再结晶的定义，但不需要阐述复杂的概念体系或进行多步骤分析。题目要求的是对单一现象的基本解释，属于该题型中中等偏下的难度水平。" + }, + { + "idx": 1662, + "question": "A slip plane and a (7) on it form a slip system", + "answer": "(7) slip direction", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个专业术语(slip direction)来补全句子，属于需要特定知识点的简答形式，而非从给定选项中选择或判断对错。 | 知识层次: 题目考查对滑移系统基本概念的简单记忆，仅需回答滑移方向这一基础概念即可完成作答，不涉及任何应用或分析过程。 | 难度: 在简答题题型中，该题目属于基本定义简答，仅需记忆并准确填写\"slip direction\"这一术语即可完成作答。题目仅考察对滑移系统基本组成的记忆，不涉及概念解释或复杂体系阐述，符合等级1的难度标准。" + }, + { + "idx": 1663, + "question": "In a solid solution, when solute atoms and solvent atoms occupy fixed positions respectively, and the ratio of solute atoms to solvent atoms in each unit cell is constant, this ordered structure is called _ (6)—", + "answer": "(6) superlattice", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（superlattice）作为答案，而不是从多个选项中选择或进行判断或计算。这种形式属于简答题，需要考生回忆并填写正确的专业术语。 | 知识层次: 题目考查对有序结构（超晶格）这一基本概念的记忆和理解，属于定义性知识，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基础定义\"superlattice\"，属于最基础的概念记忆层面。不需要解释或描述概念，更不需要复杂阐述，完全符合等级1\"基本定义简答\"的标准。在同类定义型简答题中，这是最基础、最直接的考查形式。" + }, + { + "idx": 1664, + "question": "The three crystal zones of an ingot refer to the fine crystal zone near the inner wall of the mold, _ (10) __, and the equiaxed coarse crystal zone at the center of the ingot", + "answer": "(10) columnar crystal zone growing perpendicular to the mold wall", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（columnar crystal zone growing perpendicular to the mold wall）来补全句子，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对铸锭三个晶区的基本概念的记忆和理解，特别是对柱状晶区的描述，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目要求填写的是铸锭三个晶区中的特定名称（柱状晶区），属于最基础的概念记忆范畴，无需解释或论述。同题型内相比，仅需回忆教材中的标准分类术语，不涉及概念间的逻辑关系或复杂体系阐述。" + }, + { + "idx": 1665, + "question": "Given carburization for 10 hours at 927°C, calculate the time t2 required to achieve the same carburization thickness at 870°C. Known values: D1=15.99×10^-12 m²/s, D2=7.94×10^-12 m²/s.", + "answer": "According to D1/D2 = t2/t1, t2 = (D1/D2) t1 = (15.99×10^-12 / 7.94×10^-12) × 10 h = 2.014 × 10 h = 20.14 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及使用已知的扩散系数和时间来计算新的时间，属于典型的计算题。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及扩散系数的比值计算，思维过程较为直接，无需多步推理或综合分析。 | 难度: 在计算题中属于简单应用难度，仅需直接套用已知公式D1/D2 = t2/t1进行简单数值计算，无需多步骤推导或组合公式。虽然涉及单位换算（小时与秒），但题目已给出明确已知条件，计算过程仅需一步代数运算，符合等级2\"简单公式应用计算\"的特征。" + }, + { + "idx": 1666, + "question": "Crystals can be classified into seven crystal systems based on the order and number of rotation axes and rotoinversion axes: cubic crystal system, trigonal crystal system, tetragonal crystal system, —(1), —(2)—, —(3), and _(4).", + "answer": "(1) Hexagonal crystal system; (2) Orthorhombic crystal system; (3) Monoclinic crystal system; (4) Triclinic crystal system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写缺失的晶体系统名称，答案需要提供具体的文字内容而非选择或判断。解答方式是通过回忆或知识补充来完成空缺部分，属于简答题类型。 | 知识层次: 题目考查对晶体系统分类的基本概念记忆，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写七个晶系中的四个空缺，属于对基础概念的记忆性知识，不需要进行复杂的解释或论述。解题步骤简单，只需回忆并填写正确的晶系名称即可。因此，在该题型内属于最低难度等级。" + }, + { + "idx": 1667, + "question": "The manner in which the crystal interface advances into the liquid phase during crystallization is called __（8）—, which is related to the microscopic structure of the liquid-solid interface", + "answer": "（8）crystal growth mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个专业术语（crystal growth mechanism）来完整句子，属于需要文字回答的简答题类型，不需要选择或计算。 | 知识层次: 题目考查的是结晶过程中晶体界面推进方式的基本概念记忆，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（crystal growth mechanism），属于最基础的概念记忆层次。题目直接给出了定义的关键词提示（\"the manner in which the crystal interface advances\"），不需要额外的解释或论述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1670, + "question": "At phase equilibrium, the number of phases in the system can be calculated using the relationship between the degrees of freedom of the system, －（9）__, and the number of external factors that can influence the equilibrium state of the system", + "answer": "（9）number of components", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（number of components）来补全句子，而不是从多个选项中选择或进行判断。这需要学生对相关概念有准确的理解和记忆，属于简答题类型。 | 知识层次: 题目考查对相平衡中自由度、组分数和相数之间关系的基本概念记忆，属于基础概念的记忆和理解层面。 | 难度: 在简答题中属于基本定义简答，仅需记忆并准确填写相平衡中的基本概念（组分数），无需解释或阐述复杂关系。" + }, + { + "idx": 1671, + "question": "The _ (5) of an atom or ion refers to the number of atoms directly adjacent to it in the crystal structure or the number of all hetero-ions combined with it.", + "answer": "(5) Coordination number", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（coordination number），属于需要简短文字回答的类型，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查的是\"配位数\"这一基本概念的定义，属于晶体学中最基础的概念记忆和理解范畴，不需要进行计算或综合分析。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并准确写出\"配位数\"的定义即可，不涉及概念解释或复杂体系阐述。题目明确给出了定义框架，只需填充核心术语，属于该题型内最基础级别的记忆性考查。" + }, + { + "idx": 1672, + "question": "Linear polymers can be reused and are called (19)__ plastics", + "answer": "(19) thermoplastic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（thermoplastic）作为答案，属于需要简短文字回答的题目类型 | 知识层次: 题目考查对线性聚合物分类的基本概念记忆，只需要回答\"热塑性塑料\"这一术语，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求填写一个特定术语（热塑性塑料），不需要进行概念解释或复杂阐述。这属于最基础的概念记忆层次，符合等级1的简单定义类简答要求。" + }, + { + "idx": 1673, + "question": "Cross-linked polymers cannot be reused and are called (20)__ plastics", + "answer": "(20) thermosetting", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定术语来完成句子，属于需要提供简短文字答案的类型，而非从选项中选择或判断对错 | 知识层次: 题目考查对交联聚合物分类的基本概念记忆，只需要回忆\"热固性塑料\"这一术语即可完成填空，不涉及复杂理解或应用。 | 难度: 在简答题-基础概念记忆题型中，此题仅要求填写一个特定术语（热固性塑料），属于最基本的定义性知识回忆。题目没有要求解释概念或阐述原理，仅需识别并填写标准术语，符合等级1\"基本定义简答\"的标准。相比需要展开解释的等级2题目或需要系统阐述的等级3题目，此题在同类题型中属于最低难度层级。" + }, + { + "idx": 1674, + "question": "After recrystallization is completed, grain growth can be divided into (17) _ grain growth and _ (18) grain growth.", + "answer": "(17) normal; (18) abnormal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空白处的单词，属于需要补充完整句子的简答题形式，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对再结晶后晶粒生长类型的基本概念记忆，属于定义和分类的基础知识。 | 难度: 在简答题题型中，该题目仅要求填写两个基本术语（normal和abnormal grain growth），属于最基础的定义性知识回忆。题目没有要求解释现象机制或比较两种生长方式的差异，完全符合等级1\"基本定义简答\"的特征。在同类记忆性简答题中，这是最基础的难度层级，只需准确回忆教材中的分类表述即可作答。" + }, + { + "idx": 1675, + "question": "Given the ionic radius of O2- is 0.14nm and that of Fe3+ is 0.069nm, calculate their radius ratio and predict what type of crystal structure can be formed.", + "answer": "Fe2O3, R+/R-=0.069/0.140=0.492, which also falls within the range of 0.414～0.732, has 6-coordination, A2X3 structure, trigonal crystal system.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算半径比）并应用晶体结构预测的知识，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及简单的半径比计算和基于半径比范围预测晶体结构类型，属于基本公式应用和直接套用已知规则的范畴，不需要多步计算或复杂分析。 | 难度: 在计算题中属于简单应用级别，主要涉及单一公式的直接应用（半径比计算）和基本晶体结构判断。虽然需要理解半径比与配位数的关系，但解题步骤明确且计算简单，属于该题型内中等偏下的难度。" + }, + { + "idx": 1676, + "question": "Compare the number of valence electrons in CaO and MgO, and determine whether CaO-MgO meets the electron concentration condition for forming a solid solution.", + "answer": "CaO and MgO have the same number of valence electrons, meeting the electron concentration condition for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较CaO和MgO的价电子数，并判断是否满足形成固溶体的电子浓度条件，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目主要考查对CaO和MgO的价电子数是否相同这一基本概念的记忆，以及是否满足形成固溶体的电子浓度条件这一基本原理的理解。不需要复杂的计算或深入的分析，属于基础概念的记忆和简单应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目涉及两个化合物的比较，但核心只需回答关于价电子数的基本概念和固溶体形成的电子浓度条件，不需要复杂的推导或深入分析。解题步骤相对简单，主要考察对基础概念的记忆和理解，属于该题型中的中等难度。" + }, + { + "idx": 1677, + "question": "The methods for strengthening metal materials include (13) _ strengthening, (14) strengthening, (15) strengthening, _ (16) strengthening", + "answer": "(13) solid solution; (14) dislocation; (15) fine grain; (16) dispersion (or precipitate particles)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的强化方法名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查金属材料强化方法的基本概念记忆，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题中属于中等难度，需要记忆并准确填写金属材料强化的四种主要方法。虽然不涉及复杂的概念体系阐述，但需要掌握多个相关术语（固溶强化、位错强化、细晶强化、弥散强化/沉淀强化）及其基本定义，比单纯回答单一概念的定义（等级1）要求更高。" + }, + { + "idx": 1678, + "question": "Analyze the crystal structures of CaO and MgO, and determine whether CaO-MgO meets the crystal structural conditions for forming a solid solution.", + "answer": "Both CaO and MgO have FCC NaCl-type crystal structures, which meet the crystal structural conditions for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析CaO和MgO的晶体结构，并判断它们是否符合形成固溶体的晶体结构条件。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析两种氧化物的晶体结构并判断它们是否满足形成固溶体的结构条件，这涉及对晶体结构类型的理解和应用，以及综合分析能力。虽然知识点相对明确，但需要将多个概念关联起来进行判断，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解CaO和MgO的晶体结构特点，并进行综合分析判断是否符合固溶体形成的晶体结构条件。虽然涉及多个概念，但解题步骤相对直接，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1679, + "question": "What is the difference between slip and twinning in terms of deformation continuity?", + "answer": "The slip process can proceed continuously while the twinning process cannot proceed continuously.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述滑移和孪生在变形连续性方面的区别，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对材料变形机制中滑移和孪生两种基本概念的区别理解，属于基础概念的记忆和对比分析，不需要复杂的应用或推理过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较滑移和孪生两种变形机制的连续性差异，需要理解并解释两种机制的基本特征，但不需要深入分析复杂的概念体系或进行多层次的论述。这比单纯的定义简答（等级1）要求更高，但低于需要系统阐述多个相关概念的复杂题目（等级3）。" + }, + { + "idx": 1680, + "question": "Compare the electronegativity of Ca and Mg, and determine whether CaO-MgO meets the electronegativity condition for forming a solid solution. (The electronegativity of Ca is 1.0, and that of Mg is 1.2)", + "answer": "The electronegativity of Ca is 1.0, and that of Mg is 1.2. Their electronegativity values are close and within the same period, meeting the electronegativity condition for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较Ca和Mg的电负性，并判断CaO-MgO是否符合形成固溶体的电负性条件，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较Ca和Mg的电负性，并判断CaO-MgO是否符合形成固溶体的电负性条件。这涉及基本概念的应用（电负性）和简单判断（电负性差值是否在允许范围内），不需要多步计算或复杂分析。 | 难度: 在简答题中属于简单应用过程描述。题目要求比较Ca和Mg的电负性，并判断CaO-MgO是否符合形成固溶体的电负性条件。解题步骤直接，只需简单比较给定的电负性数值（1.0 vs 1.2）并引用基本规则（电负性相近可形成固溶体）。无需深入分析或复杂计算，属于该题型框架内的基础难度。" + }, + { + "idx": 1681, + "question": "Based on the above conditions, determine what type of solid solution CaO-MgO can form.", + "answer": "Due to the excessive size difference (28%), CaO-MgO cannot form a continuous solid solution but instead forms a limited-type solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于给定条件判断CaO-MgO形成的固溶体类型，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目需要理解固溶体的形成条件（如尺寸差异的限制），并应用这些条件来分析CaO-MgO系统的固溶体类型。这涉及到多步推理和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要理解固溶体的形成条件（如尺寸差异的影响），但解题步骤相对直接，主要是基于给定的尺寸差异百分比（28%）来判断固溶体类型。题目要求综合分析尺寸差异对固溶体形成的影响，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 1682, + "question": "Based on the radius difference between Ca2+ and Mg2+ ions, calculate and determine whether CaO-MgO meets the size condition for forming a continuous solid solution. (The radii of Ca2+ and Mg2+ ions are known to be 0.1nm and 0.072nm, respectively)", + "answer": "Size difference calculation: (0.1 - 0.072) / 0.1 = 28%. The size difference exceeds 15%, thus it does not meet the size condition for forming a continuous solid solution.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于已知的离子半径数据进行计算（计算尺寸差异百分比），并根据计算结果判断是否符合形成连续固溶体的尺寸条件。答案中包含具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目要求基于已知离子半径进行简单的百分比计算，并直接应用固溶体形成的尺寸条件规则（15%阈值），属于基本公式应用和直接套用范畴，无需多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，仅需套用单一公式（半径差百分比计算公式）进行直接计算，无需多步骤推导或复杂公式组合。题目直接给出了离子半径数据，计算过程仅涉及减法与除法，属于基础级别的数值计算题型。" + }, + { + "idx": 1683, + "question": "What is the difference between slip and twinning in terms of deformation modes?", + "answer": "The slip process involves the relative sliding of one part of the crystal relative to another, while the twinning process involves the uniform shear of one part of the crystal relative to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种变形模式的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对晶体变形模式中滑移和孪生的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分两种变形模式（滑移和孪生）的基本定义和特点，但不需要深入分析复杂机制或进行多层次的比较。回答时需要准确描述两种变形过程的差异，这属于对基础概念的理解和表述能力范畴，符合等级2的要求。" + }, + { + "idx": 1684, + "question": "What is the difference in critical shear stress between slip and twinning?", + "answer": "The critical shear stress required for twinning is much greater than that for slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种现象（slip和twinning）在临界剪切应力方面的差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对滑移和孪生的临界剪切应力的基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求对两种变形机制（滑移和孪生）的关键参数进行比较解释，属于概念解释和描述层次。虽然需要记忆基础概念，但不需要构建复杂的概念体系或进行多步骤推导，因此属于中等难度（等级2）。" + }, + { + "idx": 1685, + "question": "How does the influence of slip and twinning on crystal orientation relationships differ?", + "answer": "The twinning process alters the crystal orientation relationship. The slip process does not change the crystal orientation relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述滑移和孪晶对晶体取向关系的影响差异，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目需要理解并比较两种晶体变形机制（滑移和孪生）对晶体取向关系的影响，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解并比较两种不同的晶体变形机制（滑移和孪生）对晶体取向关系的影响。虽然题目涉及的概念较为基础，但需要学生能够清晰地解释两者的区别，并进行简单的综合分析。不需要多角度或深度关联性分析，因此属于等级3。" + }, + { + "idx": 1687, + "question": "What are the differences in the roles of slip and twinning in the mechanisms of plastic deformation?", + "answer": "Slip is the primary mechanism of plastic deformation. When the slip system is unfavorable for slip deformation to occur, twinning can alter the orientation of the slip system relative to the external force, enabling further slip processes to take place.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述滑移和孪生在塑性变形机制中的不同作用，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释滑移和孪生在塑性变形机制中的不同作用，涉及多个概念的关联和综合分析，需要理解两种机制的相互作用及其在变形过程中的具体应用。 | 难度: 在简答题题型中，该题目要求对两种塑性变形机制（滑移和孪生）进行多角度分析论述。不仅需要解释各自的作用，还需要说明它们之间的相互作用和影响。这涉及到对材料科学中塑性变形机制的深入理解，以及在不同条件下的行为变化。因此，该题目在简答题中属于较高难度，需要综合分析和多角度论述。" + }, + { + "idx": 1689, + "question": "How does the type of bonding affect the physical properties of materials?", + "answer": "The type of bonding has a significant impact on the physical properties of materials. Metallic bonds impart metallic luster, high electrical and thermal conductivity, and a positive temperature coefficient of resistance; ceramics and polymers bonded by non-metallic bonds generally do not conduct electricity in the solid state. The stronger the bond, the higher the melting point of the material, the smaller the coefficient of thermal expansion, and the greater the density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述不同类型的键合如何影响材料的物理性质，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释不同类型化学键对材料物理性质的影响，涉及多个概念（金属键、非金属键）与物理性质（导电性、熔点、热膨胀系数等）的关联分析，需要中等程度的综合理解和应用能力。 | 难度: 在简答题题型中，该题目属于较高难度。它要求考生不仅理解不同类型的化学键（如金属键、离子键、共价键等），还需要将这些键的类型与材料的多种物理性质（如导电性、热膨胀系数、密度等）进行多角度的关联分析。此外，题目还要求考生能够综合说明这些关系，而不仅仅是列举或简单描述。因此，在简答题的框架内，该题目需要较深的概念理解和综合分析能力，符合等级4的标准。" + }, + { + "idx": 1690, + "question": "How does the type of bonding affect the mechanical properties of materials?", + "answer": "The type of bonding significantly affects the mechanical properties of materials. Crystals bonded by covalent, ionic, and metallic bonds are generally harder than those bonded by molecular forces. The greater the bond energy, the higher the elastic modulus. Materials with metallic bonds usually exhibit good plasticity, while those with ionic and covalent bonds (such as ceramics) are difficult to undergo plastic deformation and have poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述不同类型的键合如何影响材料的机械性能，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释不同类型化学键对材料力学性能的影响，涉及多个概念（共价键、离子键、金属键、分子力）的关联和综合分析，需要理解不同键合类型与材料性能（硬度、弹性模量、塑性）之间的关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对不同类型的化学键如何影响材料的机械性能进行多角度分析论述。需要考生不仅理解各种化学键的基本特性，还要能够关联到具体的机械性能（如硬度、弹性模量、塑性等），并进行综合比较。这种题目超出了简单概念复述的层次，属于需要整合多个知识点并展开论述的中高难度简答题。" + }, + { + "idx": 1691, + "question": "How does the magnitude of bond energy affect the properties of materials?", + "answer": "The magnitude of bond energy directly influences material properties. The higher the bond energy, the greater the material's strength typically is. Additionally, high bond energy usually leads to a high melting point, low thermal expansion coefficient, and high density. The corrosion of engineering materials is essentially a process of bond formation and destruction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释键能大小如何影响材料性质，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释键能大小如何影响材料性能，涉及多个性能指标（强度、熔点、热膨胀系数、密度）与键能的关联，需要综合分析键能与这些性能之间的关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对材料科学中的键能概念进行多角度分析论述。需要理解键能与材料强度、熔点、热膨胀系数和密度等性质之间的关系，并能综合这些因素进行解释。此外，题目还涉及腐蚀过程的本质，这需要更深层次的概念关联和综合分析能力。因此，该题目在简答题题型中属于较高难度，符合等级4的标准。" + }, + { + "idx": 1692, + "question": "Explain your understanding of the relationship between the composition and properties of materials.", + "answer": "The properties of materials are closely related to their chemical composition. The mechanical properties of materials are often highly sensitive to their structure, and any minor changes in the structure can lead to significant variations in performance. For example, the presence of carbon atoms in steel plays a crucial role in its properties, and even trace amounts of alloying elements in many metallic materials can significantly affect their performance. However, different materials composed of the same element, such as graphite and diamond made from carbon, exhibit different properties. Some polymers with identical chemical compositions can have vastly different properties due to their distinct internal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料组成与性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料组成与性能之间的关系，涉及对材料结构、成分和性能之间关联的理解和分析。虽然不涉及复杂的计算或推理，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对材料组成与性能的关系进行多角度分析论述。不仅需要理解化学组成对性能的影响，还需要举例说明不同结构导致的性能差异，涉及多个知识点的关联和综合分析。虽然不需要深度关联性分析，但已超出基础概念解释的范畴，属于中等偏上的难度。" + }, + { + "idx": 1693, + "question": "Using the dislocation theory of plastic deformation, explain why the strength of metallic materials increases with finer grain size.", + "answer": "During plastic deformation of metallic polycrystalline materials, coarse grains accumulate a larger number of dislocations at grain boundaries, creating a significant stress field that can activate dislocation sources in adjacent grains, allowing deformation to continue. In contrast, fine grains accumulate fewer dislocations at grain boundaries, requiring a greater external force to activate dislocation sources in adjacent grains for deformation to proceed. Therefore, finer-grained materials require a larger external force to undergo plastic deformation, meaning that the strength of the material increases with finer grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释金属材料强度随晶粒尺寸减小而增加的现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释晶粒尺寸对金属材料强度的影响，涉及塑性变形的机理分析、位错与晶界的相互作用等复杂概念，需要综合理解和推理分析能力。 | 难度: 在简答题的题型框架内，该题目要求运用位错理论解释晶粒尺寸对金属材料强度的影响机理。需要深入理解位错在晶界处的积累行为及其对相邻晶粒变形的影响，属于机理深度解释的范畴。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述，需要综合运用位错理论和塑性变形知识进行逻辑推导，符合等级4对知识整合与机理解释的要求。" + }, + { + "idx": 1695, + "question": "How do different types of bonding affect the hardness of crystalline materials?", + "answer": "The hardness of crystalline materials is closely related to the type of bonding. Crystals bonded by covalent, ionic, and metallic bonds generally exhibit higher hardness than those bonded by molecular bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释不同键合类型如何影响晶体材料的硬度，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查不同类型键合对晶体材料硬度影响的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释不同键合类型如何影响晶体材料的硬度，这需要理解并描述共价键、离子键、金属键和分子键的基本特性及其对硬度的影响。虽然涉及多个概念，但不需要深入分析或构建复杂的概念体系，主要考察对基础概念的记忆和简单应用。" + }, + { + "idx": 1697, + "question": "Given: When the grain size of annealed pure iron is 16 per mm², the yield strength σₛ = 100 MPa. When the grain size is 4096 per mm², σₛ = 250 MPa. Find the value of yield strength σₛ when the grain size is 256 per mm².", + "answer": "According to the Hall-Petch formula, σₛ = σ₀ + Kd⁻¹ᐟ², the yield strength σₛ of the material is calculated from the average grain size d. The grain size is represented by the radius of an equal-area circle, i.e., d₁ = (4A₁/π)¹ᐟ², d₂ = (4A₂/π)¹ᐟ², where A₁ and A₂ are the grain areas. Thus, σₛ₁ = σ₀ + Kd₁⁻¹ᐟ², σₛ₂ = σ₀ + Kd₂⁻¹ᐟ². Given A₁ = 1/16 mm², A₂ = 1/4096 mm², σₛ₁ = 100 MPa, σₛ₂ = 250 MPa, we find K = 25√2 π⁻¹ᐟ⁴ MPa·mm¹ᐟ², σ₀ = 50 MPa. Then, with A₃ = 1/256 mm², we find σₛ₃ = 150 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（Hall-Petch公式）进行数值计算，以求解特定晶粒尺寸下的屈服强度。解答过程涉及代数运算和公式应用，最终得出具体的数值结果（150 MPa）。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值求解。虽然不涉及复杂的机理分析或创新应用，但需要一定的综合分析能力和计算技巧。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸条件下的强度计算，并需要求解公式中的常数项。虽然计算过程较为直接，但需要对材料科学中的晶粒尺寸与强度关系有较好的理解，并能够正确应用数学公式进行推导和计算。" + }, + { + "idx": 1698, + "question": "Explain your understanding of the relationship between the structure and properties of materials.", + "answer": "The internal structure of materials can be divided into different levels, including atomic structure, the arrangement of atoms, as well as microstructure and structural defects. If the same crystalline material has its grain or 'phase' morphology and distribution altered, its properties can be significantly improved. Whether it is metals, ceramics, semiconductors, polymers, or composite materials, their development is closely related to structure. Only by understanding and controlling the structure of materials can we achieve the desired material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料结构与性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料结构与性能之间的关系，这需要对不同层次的结构（原子结构、微观结构等）有深入理解，并能综合分析这些结构如何影响材料的性能。这涉及到多个概念的关联和推理分析，属于较高层次的认知能力。 | 难度: 在简答题-复杂分析题型中，该题目要求对材料结构与性能的关系进行机理深度解释。需要综合运用原子结构、微观结构等多层次知识，并分析不同材料类别的结构-性能关联性。虽然不涉及跨学科整合或前沿研究分析（等级5特征），但对材料科学基础原理的理解深度和系统阐述能力要求较高，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 1699, + "question": "Explain your overall understanding of the relationship between a material's composition, microstructure, processing, and properties.", + "answer": "The relationship between a material's composition, microstructure, processing, and properties is very close and mutually influential. The ultimate goal of materials scientists is to design reasonable compositions and formulate optimal production processes based on final requirements, thereby producing materials that meet the specifications. Only by understanding and controlling the structure of materials can the desired material properties be achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料组成、微观结构、加工和性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料组成、微观结构、加工和性能之间的复杂关系，需要综合运用多个概念并进行推理分析，涉及深层次的理解和关联，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对材料科学中的核心关系进行机理深度解释。需要考生综合运用材料组成、微观结构、加工工艺和性能之间的相互作用知识，并能够系统性地阐述这些要素之间的相互影响机制。虽然不涉及最复杂的跨学科综合分析（等级5要求），但已经超出了基础概念描述的范畴，属于需要深入理解材料科学原理的题目类型。" + }, + { + "idx": 1700, + "question": "Choose any material and explain its possible uses and processing methods.", + "answer": "For example, Al-Mg alloy. As a machinable, non-heat-treatable structural material, it is widely used in aircraft, lightweight marine structural materials, load-bearing components in the transportation industry, and welded containers for chemical engineering due to its good weldability, excellent corrosion resistance, and plasticity. Based on the intended use of the material, the alloy composition is designed, and ingredients are prepared considering factors such as burning loss. For instance, Al5Mg alloy sheets can be melted in a resistance crucible furnace at around 750°C under laboratory conditions. After refining, degassing, and slag removal, the alloy is cast in a metal mold at 720°C, homogenized at 430-470°C for 10-20 hours, hot-rolled at 380-450°C, and then cold-rolled to the required thickness. Stabilization treatment is performed in a resistance furnace, followed by shearing to the desired dimensions or machining into standard specimens for various microstructure and performance tests.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求选择一个材料并解释其可能的用途和加工方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求选择一个材料并解释其用途和加工方法，这需要将材料的基本特性与其实际应用场景和加工工艺关联起来。虽然涉及多个步骤和概念，但主要是基于已有知识的直接应用和综合分析，不需要深入的机理分析或创新设计。 | 难度: 在简答题中属于较高难度，需要多角度分析论述。题目要求选择一种材料并详细解释其用途和加工方法，涉及材料性能、应用领域、成分设计、熔炼工艺、热处理、成型工艺等多个方面的综合分析。答案中不仅列举了具体应用场景，还详细描述了从合金设计到最终成品的完整工艺流程，包括温度控制、时间参数等专业技术细节，体现了对材料科学知识的深度掌握和综合应用能力。" + }, + { + "idx": 1701, + "question": "Explain your understanding of the relationship between material processing and properties.", + "answer": "The preparation/synthesis and processing of materials are not only essential means to control their composition and structure but also endow materials with specific dimensions and shapes. For example, steel can undergo heat treatments such as annealing, quenching, and tempering to alter its internal structure and achieve desired properties. Cold-rolled silicon steel sheets, through complex processing steps, can align grains in a specific orientation, significantly reducing iron loss. The blades of aircraft engines can be cast with controlled solidification to form single-crystal blades, eliminating grain boundaries and greatly enhancing their operating temperature and performance. Optical fibers must not only be drawn into micron-level thin strands but also have their refractive index distribution controlled from the inside out. Sometimes it can be said that without a breakthrough in synthesis and processing, there would be no new material. For instance, the development of rapid cooling processing methods led to the creation of amorphous metal alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料加工与性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料加工与性能之间的关系，涉及多个加工方法（如热处理、冷轧、铸造、拉丝等）对材料微观结构和性能的影响，需要综合运用材料科学知识进行推理分析和机理解释。答案中不仅列举了具体实例，还说明了加工方法如何改变材料结构并赋予特定性能，体现了对材料加工与性能关系的深度理解和综合分析能力。 | 难度: 在简答题-复杂分析题型中，该题目要求对材料加工与性能关系进行全面分析，涉及多种加工方法（如热处理、冷轧、铸造、拉丝等）及其对材料微观结构和宏观性能的影响机制。需要综合运用材料科学原理，解释不同加工工艺如何导致特定性能变化，并举例说明突破性加工技术对新材料开发的关键作用。这种深度机理解释和复杂现象分析的要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 1702, + "question": "What are traditional materials and advanced materials (new materials)?", + "answer": "There is a wide variety of materials. Those that are mature, mass-produced in industry, and widely used are called traditional materials or basic materials, such as steel, cement, and plastics. On the other hand, those that are under development and possess excellent properties and application prospects are referred to as advanced materials or new materials. Traditional materials can become new materials by adopting new technologies and improving performance, while new materials eventually become traditional materials after long-term production and application.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对传统材料和先进材料进行定义和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目考查传统材料和先进材料的基本定义和分类，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释传统材料和先进材料（新材料）的定义，并简要说明它们之间的关系和转化过程。虽然需要一定的记忆和理解，但不需要复杂的分析或深入的论述，属于中等难度的概念解释题。" + }, + { + "idx": 1703, + "question": "For two types of diffusion with activation energies of E1= 83.7 kJ/mol and E2=251 kJ/mol, how does the diffusion rate change when the temperature increases from 25°C to 600°C?", + "answer": "From D=D0exp(-Q/RT): when the temperature increases from 298K to 873K, the diffusion rate D increases by 4.6×10^9 and 9.5×10^28 times, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（阿伦尼乌斯方程）来求解扩散速率的变化，答案给出了具体的计算结果。 | 知识层次: 题目需要应用扩散速率公式进行多步计算，涉及不同温度下的扩散速率变化比较，需要理解公式中各参数的含义并进行数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度单位转换、指数运算和不同激活能条件下的结果比较。虽然计算步骤明确，但需要较强的概念理解和数值处理能力，属于中等偏上的难度。" + }, + { + "idx": 1704, + "question": "What are the new technologies for aluminum alloy preparation?", + "answer": "The new technologies for aluminum alloy preparation include: hot top casting, air gap casting and electromagnetic casting technology, aluminum alloy electromagnetic casting and rolling technology, large aluminum alloy profile extrusion technology, extra-wide aluminum alloy medium-thick plate rolling technology, semi-solid metal forming technology, and aluminum alloy microstructure prediction and performance control technology.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举和描述铝合金制备的新技术，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目要求列举并简要描述铝合金制备的新技术，涉及多个技术名称及其应用，需要一定的知识关联和综合分析能力，但不需要深入的分析或创新应用。 | 难度: 在简答题中属于中等难度，需要综合分析和说明多种新技术，但不需要进行多角度或深度关联性分析。题目要求列举并简要解释铝制备的新技术，涉及多个技术点，但每个技术点的解释较为直接，不需要复杂的论述或深入的理论分析。" + }, + { + "idx": 1705, + "question": "Explain the commonly used diffusion mechanisms.", + "answer": "The commonly used diffusion mechanisms are the vacancy mechanism and the interstitial mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释常见的扩散机制，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查扩散机制的基本分类和定义，属于基础概念的记忆和理解层面，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答两种常见的扩散机制（空位机制和间隙机制），属于基本定义简答范畴。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可完成，符合等级1的难度标准。" + }, + { + "idx": 1706, + "question": "What effect does activation energy have on the sensitivity of diffusion rate to temperature changes?", + "answer": "The higher the activation energy, the greater the sensitivity of the diffusion rate to temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释激活能对扩散速率敏感性的影响，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目需要理解激活能对扩散速率温度敏感性的影响，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求分析激活能对扩散速率温度敏感性的影响，需要理解激活能的概念及其与扩散速率的关系，并进行综合分析和说明。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析，因此属于等级3难度。" + }, + { + "idx": 1707, + "question": "What effect does an edge dislocation have on the diffusion process?", + "answer": "An edge dislocation can be regarded as a pipe, which can accelerate the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释边缘位错对扩散过程的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释位错对扩散过程的影响机制，需要理解位错的结构特征及其作为快速扩散通道的作用原理，涉及位错理论和扩散动力学的综合分析，属于机理层面的解释。 | 难度: 在简答题中属于机理深度解释难度，需要理解位错理论及其对扩散过程的影响机制，并能准确描述位错作为扩散通道的作用。虽然不涉及多因素交互作用的全面分析，但对单一机理的解释深度要求较高。" + }, + { + "idx": 1708, + "question": "Please analyze with examples the influence of material processing on the service performance of materials.", + "answer": "The material processing process has a significant and complex impact on the service performance of materials. Materials must also undergo reasonable technological processes to be prepared into materials with practical value. Through rational and economical synthesis and processing methods, many new materials can be continuously created, or the composition and structure of many traditional materials can be altered and precisely controlled, further exploring and enhancing material properties. The preparation/synthesis and processing of materials not only impart certain dimensions and shapes to materials but are also essential means to control their composition and structure. For example, steel can undergo heat treatments such as annealing, quenching, and tempering to alter its internal structure and achieve desired properties. Cold-rolled silicon steel sheets can significantly reduce iron loss through complex processing steps that align grains in a specific orientation. The blades of aircraft engines can be made into single-crystal blades through solidification control during casting, eliminating grain boundaries and greatly improving their service temperature and performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过例子分析材料加工对材料服役性能的影响，答案提供了详细的文字解释和论述，包括具体的例子和加工方法的影响，符合简答题的特征。 | 知识层次: 题目要求分析材料加工对材料服役性能的影响，并提供实例进行解释。这需要综合运用材料科学的知识，理解加工工艺如何改变材料的组成和结构，进而影响其性能。此外，还需要进行推理分析，解释不同加工方法（如热处理、冷轧、凝固控制）如何具体影响材料的性能，如钢铁的热处理、硅钢片的晶粒取向控制、单晶叶片的制备等。这种题目不仅要求对材料加工和性能有深入的理解，还需要能够将多个知识点关联起来进行综合分析，属于复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对材料加工过程对服役性能的影响进行全面分析，涉及多种加工工艺（如热处理、冷轧、铸造控制）及其对材料微观结构和性能的具体影响机制。需要综合运用材料科学知识，进行多因素推理和机理解释，并提供具体实例（如钢的热处理、硅钢片加工、单晶叶片制备）来支撑论述。这种深度和广度的分析要求在该题型内属于最高难度等级。" + }, + { + "idx": 1709, + "question": "What is the connection between new materials and new processes?", + "answer": "Currently, new materials are often associated with new processing technologies. For example, amorphous metal alloys can be prepared through processing methods such as rapid cooling or mechanical alloying, whereas previously it was unknown that metals could be made amorphous. Other examples include spray deposition technology, semi-solid processing technology, and net-shape thin-strip continuous casting technology, all of which are new processing techniques. For certain polymer materials, the use of extrusion filament processes has significantly increased the specific strength and specific stiffness of organic fibers. Additionally, new optical fiber materials are prepared using CVD + melting or ion exchange methods, among others.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释新材料与新工艺之间的联系，答案提供了详细的文字论述和多个例子来支持观点，符合简答题的特征。 | 知识层次: 题目要求解释新材料与新工艺之间的联系，需要理解新材料的特点和新工艺的原理，并进行概念关联和综合分析。虽然不涉及复杂的计算或深度推理，但需要对多种材料和工艺有一定的了解，并进行适当的比较和举例说明。 | 难度: 在简答题题型中，该题目要求多角度分析论述新材料与新工艺之间的联系，涉及多个具体实例（如非晶态金属合金、喷涂沉积技术、半固态加工技术等）的综合分析。虽然不需要进行深度关联性分析，但需要考生展示对材料科学领域新工艺技术的广泛了解和概念关联能力，属于中等偏上的难度等级。" + }, + { + "idx": 1710, + "question": "How to control and improve the microstructure in metal materials through heat treatment?", + "answer": "The microstructure of metal materials can be altered through heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过热处理控制和改善金属材料的微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求通过热处理控制和改善金属材料的微观结构，这需要综合运用材料科学中的相变理论、热处理工艺参数（如温度、时间、冷却速率）的影响机制，以及不同金属材料的特性。回答需要深入分析热处理过程中的微观结构演变机理，并可能涉及多种热处理方法的比较和选择，属于较高层次的综合分析和推理。 | 难度: 在简答题中属于最高难度等级，因为题目要求对金属材料微观结构的控制和改善进行全面分析，涉及复杂的热处理工艺和机理解释。需要综合运用材料科学知识，深入理解相变、晶粒生长等微观机制，并能系统性地论述不同热处理参数对微观结构的影响。这种题目不仅要求掌握基础概念，还需要具备将理论知识应用于实际问题的能力，属于复杂现象全面分析的范畴。" + }, + { + "idx": 1711, + "question": "How do dislocations affect the plastic deformation ability of metal materials?", + "answer": "The plastic deformation of metals is achieved through the movement of dislocations, therefore the strengthening methods for metal materials can be realized by altering the number of dislocations in the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错如何影响金属材料的塑性变形能力，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及位错对金属材料塑性变形能力的影响机制，需要综合运用位错理论、塑性变形原理以及强化方法等多方面知识进行推理分析和机理解释，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对位错如何影响金属材料塑性变形能力进行机理深度解释。需要综合运用材料科学知识，理解位错运动与塑性变的关系，并能逻辑清晰地阐述强化方法的原理。虽然不涉及多因素交互作用的复杂现象分析，但已超出基础概念复述层面，属于需要深入理解材料变形机制的等级。" + }, + { + "idx": 1712, + "question": "How to control and improve the microstructure in metallic materials through processing methods?", + "answer": "The microstructure of metallic materials can be altered through various processing methods, such as cooling rate and method during casting, temperature gradient, and the magnitude and method of pressure processing after casting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过加工方法控制和改善金属材料的微观结构，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求通过加工方法控制和改善金属材料的微观结构，涉及多种加工方法的综合应用和概念关联，需要多步分析和综合理解不同加工参数对微观结构的影响。 | 难度: 在简答题题型中，该题目要求对金属材料微观结构的控制和改善方法进行多角度分析论述。需要考生综合运用材料加工工艺知识，包括铸造、压力加工等多个环节的影响因素，并能够系统性地阐述不同加工方法对微观结构的具体影响机制。这超出了简单列举或单一概念解释的层次，但尚未达到需要深度跨学科关联分析的等级5水平。" + }, + { + "idx": 1713, + "question": "How to control and improve the grain size in metal materials through additives?", + "answer": "The grain size of metal can be altered by additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述如何通过添加剂控制和改善金属材料的晶粒尺寸，答案也需要详细的解释和论述，而不是简单的选择或判断。 | 知识层次: 题目涉及通过添加剂控制和改善金属材料晶粒尺寸的方法，需要理解添加剂的作用机制、晶粒尺寸的影响因素以及如何通过添加剂调控这些因素。这需要多步分析和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对金属材料中晶粒尺寸的控制和改善进行多角度分析论述。需要考生不仅理解添加剂对晶粒尺寸的影响机制，还要能够综合不同添加剂的作用、添加量的控制、工艺条件的配合等多方面因素进行论述。这超出了简单的概念解释或单一因素分析，属于较复杂的综合分析层次，因此在该题型内属于较高难度等级。" + }, + { + "idx": 1714, + "question": "Describe the deformation behavior and characteristics of a certain type of material you are familiar with.", + "answer": "Metallic materials typically undergo elastic deformation and plastic deformation stages during tensile deformation, and may eventually fracture. In each single crystal of metallic materials, the primary deformation mode is slip, while some metals may also exhibit twinning deformation during deformation. The microscopic mechanisms of both slip and twinning deformation can be explained using the concept of dislocations. Polycrystalline materials, due to the blocking effect of grain boundaries and the differences in orientation between adjacent grains, generally hinder dislocation motion, making deformation more difficult compared to single-crystal materials. Single-phase solid solution alloys exhibit solid solution strengthening due to the presence of solute atoms. Body-centered cubic metals show yield phenomena and strain aging during tensile deformation. The plastic deformation characteristics of multiphase alloys are related to the quantity, size, and distribution of the second phase. Generally, fine, dispersed, and uniformly distributed second phases enhance alloy strength, making deformation more difficult. Metallic materials often exhibit work hardening during deformation, accompanied by changes in microstructure and other physical and chemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述某种材料的变形行为和特征，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述特定材料的变形行为和特征，涉及弹性变形、塑性变形、滑移、孪生变形、位错概念、晶界效应、固溶强化、屈服现象、应变时效、多相合金的塑性变形特征以及加工硬化等多个知识点。答案需要对不同变形阶段的微观机制进行解释，并综合分析不同材料结构（如单晶、多晶、单相固溶体、多相合金）对变形行为的影响。这需要综合运用材料科学的知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对金属材料的变形行为进行全面分析，涉及多个复杂概念和机理的综合运用。具体包括弹性变形、塑性变形、滑移、孪生、位错理论、晶界效应、固溶强化、屈服现象、应变时效、多相合金变形特性以及加工硬化等多个方面。不仅需要深入理解每个概念，还需要能够将这些概念有机结合起来，解释材料变形过程中的复杂现象。这种综合性的分析和解释要求在该题型内属于最高难度等级。" + }, + { + "idx": 1715, + "question": "How to control and improve the microstructure in metal materials by selecting compositions?", + "answer": "By selecting compositions to determine the appropriate microstructure, different compositions of metals can yield pure metals, single-phase solid solution alloys, and multi-phase alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述如何通过选择成分来控制和改善金属材料的微观结构，答案提供了详细的解释和分类，符合简答题的特征。 | 知识层次: 题目要求通过选择成分来控制金属材料的微观结构，涉及多相合金、单相固溶体等概念的综合应用，需要理解不同成分对微观结构的影响，并进行综合分析。这超出了简单记忆或直接套用的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在简答题中属于中等难度，需要综合分析和说明不同成分对金属材料微观结构的影响。题目要求考生理解并解释如何通过选择成分来控制微观结构，涉及纯金属、单相固溶体合金和多相合金等概念，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1716, + "question": "Talk about your understanding of high-strength materials.", + "answer": "For structural materials, one of the most important performance indicators is strength. Strength refers to a material's ability to resist deformation and fracture. Improving the strength of a material can save materials and reduce costs. When utilizing the mechanical properties of materials, people always hope that the materials used have sufficient strength. They aim to reasonably apply and develop material strengthening methods to tap into the potential of material performance. Theoretically, there are two approaches to increasing the strength of metal materials: one is to completely eliminate internal dislocations and other defects, bringing its strength close to the theoretical strength. Although it is currently possible to produce high-strength metal whiskers without dislocations, practical applications remain challenging because the high strength obtained this way is unstable, highly sensitive to operational effects and surface conditions, and the strength drops significantly once dislocations occur. Therefore, in production practice, the primary approach to strengthening metals is to introduce a large number of defects to hinder dislocation movement. For example, common strengthening methods for metal materials include solid solution strengthening, grain refinement strengthening, second-phase particle strengthening, and deformation strengthening. By comprehensively applying these strengthening methods, it is possible to approach the theoretical strength from another perspective. For instance, in iron and titanium, up to 38% of the theoretical strength can be achieved. Some new high-strength aluminum alloys, such as Al-Li alloys, Al-Cu-Mg series alloys, Al-Zn-Mg series alloys, high-Zn-content Al-Zn-Mg alloys, Al-Mg-Sc series alloys, Al-Zn-Mg-Sc series alloys, and aluminum matrix composites, have achieved high strength and other comprehensive properties through various strengthening methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对高强材料进行理解和论述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求对高强材料的理解进行详细论述，涉及多种强化方法的综合运用、理论强度的探讨以及实际应用中的挑战。这需要深入理解材料强化的机理，并能综合分析不同强化方法的优缺点及其在实际材料中的应用。此外，答案中还提到了多种高强铝合金的具体例子，展示了知识的广度和深度，符合复杂分析的要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对高强材料进行全面深入的分析和解释。需要综合运用材料科学中的多种强化机理（如固溶强化、细晶强化、第二相粒子强化等），并结合实际应用案例（如Al-Li合金等）进行论述。题目不仅考察对单一强化机制的理解，更要求考生能够系统性地整合不同强化方法的协同作用，并联系理论强度与实际应用之间的差距。这种需要多维度综合分析和机理深度解释的要求，在简答题中属于最高难度等级。" + }, + { + "idx": 1717, + "question": "What is the effect of the interaction between dislocations and solute atoms on the properties of metallic materials?", + "answer": "The interaction between dislocations and solute atoms in alloys forms Cottrell atmospheres, leading to yield phenomena and strain aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错与溶质原子相互作用对金属材料性能的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释位错与溶质原子相互作用的机理（Cottrell气团形成）及其对金属材料性能的影响（屈服现象和应变时效），这需要综合运用位错理论、固溶强化机理等知识进行深入分析和解释，属于机理层面的复杂分析。 | 难度: 在简答题题型中，该题目要求对位错与溶质原子相互作用的机理进行深度解释，涉及Cottrell气团的形成及其对材料性能的影响。虽然题目没有要求全面分析所有可能的复杂现象，但需要对特定机理进行详细阐述，属于机理深度解释的难度等级。" + }, + { + "idx": 1718, + "question": "What is the effect of dislocations on the nucleation of the second phase?", + "answer": "Dislocations are preferential sites for the nucleation of the second phase, and typically the second phase can nucleate and grow preferentially at dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释位错对第二相形核的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及位错对第二相形核的影响，需要理解位错作为形核位点的机制，并关联位错与第二相形核的关系，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求解释位错对第二相形核的影响，需要考生理解位错作为形核位点的作用机制，并能进行综合分析和说明。虽然涉及概念关联，但不需要多角度或深度关联性分析，解题步骤相对直接，符合等级3的综合分析和说明要求。" + }, + { + "idx": 1719, + "question": "How to control and improve the microstructure in metallic materials through rapid solidification and powder metallurgy?", + "answer": "Non-equilibrium microstructures can be obtained through rapid solidification and powder metallurgy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过快速凝固和粉末冶金控制和改善金属材料的微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及通过快速凝固和粉末冶金技术控制和改善金属材料的微观结构，这需要对非平衡微观结构的形成机理、工艺参数的影响以及不同技术之间的关联有深入的理解和分析能力。回答需要综合运用材料科学原理，解释技术如何影响微观结构，并进行推理分析，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对快速凝固和粉末冶金两种工艺如何控制和改善金属材料的微观结构进行全面分析。需要综合运用材料科学原理，解释非平衡微观结构的形成机理，并比较两种工艺的优缺点及其对微观结构的影响。这种深度和广度的分析要求属于该题型下的最高难度等级。" + }, + { + "idx": 1720, + "question": "Describe the solidification process of a certain type of material you are familiar with.", + "answer": "After the solidification process, metallic materials usually form crystals, so the solidification process of metallic materials is also called the crystallization process. The crystallization of metals generally consists of two stages: nucleation and subsequent growth. Nucleation in metals typically occurs on the basis of small-sized ordered atomic clusters (embryos) in the metal melt, where atomic diffusion leads to the formation of stable nuclei capable of growth. Thus, the nucleation process of pure metals generally requires meeting energy and structural conditions, while alloy nucleation also requires certain compositional conditions. The subsequent growth of metal nuclei usually requires a small degree of undercooling, with atoms diffusing toward the nuclei to facilitate growth. During the growth process, the crystallization interface is rough, so the growth rate of metals is generally rapid. The structure of the crystallization interface, temperature gradient, and crystallization speed influence the shape and size of the resulting grains. For alloys, this process can also lead to issues such as compositional segregation after crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述某种材料的凝固过程，需要详细的文字解释和论述，而不是选择、判断或计算。答案提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目要求描述特定材料的凝固过程，涉及金属材料的结晶过程，包括成核和生长两个阶段，以及能量、结构和成分条件。答案详细解释了这些过程，并讨论了结晶界面结构、温度梯度和结晶速度对晶粒形状和尺寸的影响，以及合金可能出现的成分偏析问题。这需要综合运用多个概念，进行推理分析和机理解释，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对金属材料的凝固过程进行机理深度解释，涉及成核、生长、结晶界面结构等多个关键概念的综合运用和推理分析。虽然题目没有要求对比不同材料或极端条件下的复杂现象，但对金属凝固机理的解释已经达到了较深的层次，符合等级4的标准。" + }, + { + "idx": 1721, + "question": "What effect does constitutional supercooling have on the solidification structure of alloys?", + "answer": "The occurrence of constitutional supercooling phenomenon will cause multicomponent alloys to develop cellular or dendritic structures even under a positive temperature gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释constitutional supercooling对合金凝固结构的影响，需要文字论述和解释，而不是选择、判断或计算 | 知识层次: 题目涉及对合金凝固过程中成分过冷现象及其对凝固组织影响的机理解释，需要综合运用材料科学中的凝固理论、相变原理和显微组织形成机制等知识，进行推理分析和综合解释。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求对\"成分过冷\"这一复杂现象进行机理层面的深度解释，需要综合运用相变动力学和凝固理论的知识，并准确描述其对合金凝固组织的影响机制。虽然不涉及多因素交叉分析（等级5特征），但已超出基础概念复述层面，属于需要深入理解并阐述物理本质的难度等级。" + }, + { + "idx": 1722, + "question": "Why does constitutional supercooling occur during the solidification of multicomponent alloys?", + "answer": "During the solidification of multicomponent alloys, elements with higher melting points solidify first. If the alloy is not sufficiently stirred, elements with lower melting points will become enriched at the solidification interface front, lowering the actual solidification temperature of the liquid phase there. Even under a positive temperature gradient, the degree of supercooling at the solidification interface front may increase with distance from the interface. This phenomenon is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释一个现象（constitutional supercooling）的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多组分合金凝固过程中的成分过冷现象，涉及多个概念的关联和机理的深入分析，需要综合运用材料科学中的凝固理论和热力学知识，思维过程较为复杂。 | 难度: 在简答题题型中，该题目要求对多组分合金凝固过程中的成分过冷现象进行全面分析，涉及多个知识点的综合运用和机理解释。需要深入理解凝固过程中的元素分布、温度梯度以及界面现象等复杂因素，并能够清晰地阐述其相互作用和影响。这种复杂现象全面分析的要求使得该题目在同题型内属于最高难度等级。" + }, + { + "idx": 1723, + "question": "Summarize the grain boundary strengthening mechanism in the application of dislocation theory in materials science, considering the factors affecting the strength of metal materials", + "answer": "Grain boundary strengthening, according to the Hall-Petch formula, essentially means that additional stress is required for dislocations to cross grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对晶界强化机制进行总结，并考虑影响金属材料强度的因素，这需要详细的文字解释和论述。答案提供了基于Hall-Petch公式的解释，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释晶界强化机制，并考虑影响金属材料强度的因素，涉及多个概念的关联和综合分析，需要深入理解材料科学中的强化机制及其背后的物理原理。 | 难度: 在简答题题型中，该题目要求对晶界强化机制进行深度解释，并需要结合位错理论和Hall-Petch公式进行论述。虽然题目涉及的知识点较为复杂，但并未要求对多个复杂现象进行全面分析或提出新的理论解释，因此属于机理深度解释的等级4难度。" + }, + { + "idx": 1724, + "question": "Combining the factors affecting the strength of metal materials, summarize the solid solution strengthening mechanism in the application of dislocation theory in materials science", + "answer": "The possible dislocation mechanisms of solid solution strengthening mainly include the pinning of dislocations by solute atom atmospheres, which increases the resistance to dislocation slip. Examples include the Cottrell atmosphere and Snoek atmosphere resulting from the elastic interaction between solute atoms and dislocations, as well as the Suzuki atmosphere arising from the interaction between solute atoms and extended dislocations, which increases the stacking fault width, making dislocation constriction and cross-slip more difficult. The segregation and short-range order formed by solute atoms raise the energy when dislocations pass through and disrupt these configurations, thereby increasing the resistance to dislocation motion. Additionally, the electrostatic interaction between solute atoms and dislocations generates resistance to dislocation slip, enhancing the material's strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结固溶强化机制并应用位错理论进行论述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求结合影响金属材料强度的因素，总结固溶强化的位错理论机制，涉及多个位错机制的解释和综合分析，需要深入理解位错与溶质原子的相互作用，并进行机理的详细阐述。这属于对材料科学中复杂概念的综合运用和推理分析。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求综合运用材料科学中的多个高级概念（如位错理论、固溶强化机制、Cottrell/Snoek/Suzuki气氛等），并需要将这些概念有机联系起来解释复杂的材料强化现象。解题时需要：" + }, + { + "idx": 1725, + "question": "What is the basic principle of grain refinement by adding a modifier?", + "answer": "The basic principle of grain refinement by a modifier is that the modifier itself or the reaction between the modifier and elements in the alloy can form dispersed phases that serve as nucleation sites for alloy precipitation. These dispersed phases can form coherent interfaces with very low interfacial energy with the solidifying phase of the alloy, enabling heterogeneous nucleation of the alloy on these dispersed phases, thereby achieving the purpose of grain refinement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本原理，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目考查晶粒细化基本原理的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释晶粒细化的基本原理，涉及对改性剂作用机制的理解和描述，但不需要复杂的体系阐述或多层次的概念整合。属于基础概念记忆层次中需要一定解释能力的题目，但未达到复杂概念体系阐述的深度。" + }, + { + "idx": 1726, + "question": "Given the vacancy formation energy of aluminum is 0.76 eV/vacancy, and the lattice constant of aluminum at 25°C is 0.405 nm, calculate the vacancy concentration in aluminum at 25°C (vacancies/cm3).", + "answer": "Let the lattice constant of aluminum be a=0.405 nm. From the problem, the number of unit cells per unit crystal volume is 1/a3. Since aluminum has an FCC structure, the number of atoms per unit cell is 4, so the number of lattice sites per unit volume is N=4/a3. The vacancy concentration is Cv=Ae^(-Qv/RT), where A is a material constant, usually taken as A=1; the vacancy formation energy Qv=0.76 eV, and 1 eV=1.602×10-19 J; R=8.31 J/mol·K is the gas constant; and T is the thermodynamic temperature. At 25°C, T=(273+25) K=298 K. Substituting into the formula, the vacancy concentration in aluminum at this temperature is n=8.34×10^9 vacancies/cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了单位转换、公式代入和具体计算步骤，最终得出一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括单位转换、晶体结构知识、热力学公式应用等，需要综合分析能力和对材料科学基础知识的理解。虽然不涉及复杂的推理或创新设计，但超出了简单直接套用公式的范围。 | 难度: 在计算题中属于综合性计算问题，需要应用多个物理常数（如气体常数、电子伏特转换）、理解晶体结构参数（FCC晶胞原子数）、掌握阿伦尼乌斯公式变形应用，并进行多步骤单位换算（从nm到cm、eV到J）。虽然计算过程明确，但涉及跨学科概念整合和单位系统转换，在中等应用层次的计算题中属于典型综合型题目。" + }, + { + "idx": 1727, + "question": "Based on the factors affecting the strength of metal materials, summarize the dispersion strengthening mechanism in the application of dislocation theory in materials science", + "answer": "Dispersion strengthening also strengthens materials by hindering dislocation movement, such as the Orowan mechanism where dislocations bypass harder, incoherent second-phase particles with the matrix, and the cutting mechanism where dislocations cut through softer, coherent second-phase particles with the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于金属材料强度的因素，总结弥散强化机制在材料科学中位错理论的应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于金属材料强度影响因素，运用位错理论总结弥散强化机制，涉及多个概念的关联和综合分析，需要深入理解位错运动与第二相颗粒的相互作用机制（如Orowan机制和切割机制），属于复杂分析和机理解释的范畴。 | 难度: 在简答题中属于机理深度解释难度，需要综合运用位错理论和强化机制知识，解释分散强化如何通过阻碍位错运动来增强材料强度，涉及Orowan机制和切割机制的具体分析，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 1730, + "question": "Summarize the work hardening mechanism in the application of dislocation theory in materials science based on the factors affecting the strength of metallic materials", + "answer": "Various possible mechanisms for work hardening include the theory of parallel dislocation hardening due to interactions between parallel dislocations on the slip plane, and the theory of forest dislocation strengthening caused by the cutting of forest dislocations on other slip planes by dislocations on the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于位错理论总结金属材料强度影响因素中的加工硬化机制，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求基于位错理论总结金属材料中的加工硬化机制，并涉及影响强度的因素。这需要深入理解位错相互作用机制（如平行位错和森林位错强化理论），并能综合分析不同因素对材料强度的影响。思维过程需要将理论知识与实际应用相结合，进行机理层面的解释和论述，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用位错理论解释金属材料强化机制，涉及平行位错强化和林位错强化两种复杂机理的对比分析。需要考生深入理解位错相互作用原理，并能系统性地阐述不同强化机制之间的关系，属于该题型下对知识整合和机理解释要求最高的复杂现象全面分析级别。" + }, + { + "idx": 1732, + "question": "Explain which locations are likely to be the preferred nucleation sites for recrystallization", + "answer": "The preferred nucleation sites are: original grain boundaries, newly formed high-angle grain boundaries during deformation or gradually formed high-angle grain boundaries through subgrain growth, and the vicinity of second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释再结晶过程中优先形核的位置，需要文字解释和论述，答案提供了详细的文字说明而非选择、判断或计算。 | 知识层次: 题目要求解释再结晶过程中优先形核的位置，这需要理解再结晶的基本原理，并能够将形核位置与材料变形过程中的微观结构变化（如晶界、亚晶生长、第二相粒子等）联系起来。虽然不涉及复杂的计算或深度机理分析，但需要对多个概念进行综合应用和简单分析。 | 难度: 在简答题题型中，该题目要求考生不仅列举出再结晶的优先形核位置，还需要解释这些位置为何成为优先形核点的原因。这涉及到对变形过程中微观结构演变的理解，以及第二相粒子对再结晶形核的影响。考生需要将多个概念（如晶界、亚晶粒生长、第二相粒子等）关联起来进行综合分析，属于多角度分析论述的难度等级。" + }, + { + "idx": 1733, + "question": "What is a modifier?", + "answer": "A substance that can change the phase composition, phase morphology, or grain size of an alloy's as-cast structure by adding a small amount, thereby altering the properties of the cast alloy, is called a modifier.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"modifier\"进行定义和解释，需要文字论述而非选择或判断 | 知识层次: 题目考查对\"modifier\"这一基本概念的定义和功能的理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答\"modifier\"的定义，不需要进行概念解释或复杂体系阐述。答案直接给出了明确的定义，属于基础概念记忆层次中最简单的类型，符合等级1的标准。" + }, + { + "idx": 1734, + "question": "Given the vacancy formation energy of aluminum is 0.76 eV/vacancy, and the lattice constant of aluminum at 25°C is 0.405 nm, at what temperature will the vacancy concentration in aluminum be 1000 times that at 25°C?", + "answer": "Let the vacancy concentration at 25°C be n1=8.34×10^9 vacancies/cm3, and the vacancy concentration after 1000 times be n2=8.34×10^12 vacancies/cm3. According to the vacancy concentration formula Cv=Ae^(-Qv/RT), we have n2/n1=e^(Qv/R(1/T1-1/T2)). Substituting n2=1000n1, Qv=0.76eV=0.76×1.602×10-19J, R=8.31J/mol·K, T1=298K, we solve for T2≈434K. Therefore, the vacancy concentration in aluminum at approximately 434K is 1000 times that at 25°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解特定温度下的空位浓度变化，答案涉及具体的计算过程和数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用空位浓度公式并进行温度转换，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于中等偏上难度，需要应用多步公式推导和数值计算，涉及温度转换、能量单位换算和指数方程求解等综合技能，但未达到复杂多变量计算的程度。" + }, + { + "idx": 1735, + "question": "Briefly describe the laws of changes in material structure and properties during recovery and recrystallization annealing of metals after cold deformation", + "answer": "As the annealing temperature increases or the annealing time prolongs, dislocation tangles in the deformed structure evolve into subgrains, which then merge and grow; recrystallization nucleation and growth occur in areas of uneven deformation, with equiaxed grains replacing elongated deformed grains; followed by normal grain growth. In terms of properties, strength and hardness decrease, electrical resistance decreases; plasticity and toughness improve. These processes are more pronounced during the recrystallization stage than the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述金属冷变形后回复和再结晶退火过程中材料结构和性能变化的规律，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释冷变形金属在回复和再结晶退火过程中组织与性能变化的规律，涉及多个阶段的微观结构演变（位错缠结→亚晶→再结晶形核与长大→晶粒正常长大）及其对应的性能变化（强度、硬度、电阻率、塑性和韧性）。这需要综合运用材料科学中的位错理论、再结晶动力学和性能-结构关系等知识，进行机理层面的解释和关联分析，思维深度要求较高。 | 难度: 在简答题题型中，该题目要求对金属冷变形后的回复和再结晶退火过程中组织与性能变化的规律进行描述，涉及机理深度解释。虽然题目提供了明确的答题方向（如位错缠结演变为亚晶、再结晶形核与长大、性能变化等），但需要综合运用材料科学知识，对多个过程进行连贯分析，并解释其内在联系。相较于更基础的简答题（如单一概念解释），该题目对知识掌握深度和逻辑表达能力的要求更高，属于机理深度解释的等级4难度。" + }, + { + "idx": 1739, + "question": "Summarize the order strengthening mechanism in the application of dislocation theory in materials science based on the factors affecting the strength of metallic materials", + "answer": "Order strengthening: In ordered alloys, dislocations are superdislocations. To induce plastic deformation in the metal, both partial dislocations of the superdislocation must move simultaneously, requiring greater external stress. The bonding force between dissimilar element atoms is stronger than that between similar element atoms, so the ordered arrangement of dissimilar atoms imparts higher strength to ordered alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对有序强化机制进行总结和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目要求基于位错理论解释有序强化的机理，涉及对位错运动、原子间作用力等概念的深入理解，并需要综合分析有序合金中位错行为与材料强度的关系。这属于对材料科学原理的复杂分析和机理解释层次。 | 难度: 在简答题题型中，该题目要求对有序强化机制进行机理深度解释，涉及超位错的概念、塑性变形的条件以及异种元素原子间结合力的影响。虽然题目没有要求对复杂现象进行全面分析，但需要对多个相关概念进行综合运用和推理分析，因此在简答题中属于较高难度等级。" + }, + { + "idx": 1740, + "question": "The space lattice is an abstraction derived from the ____ in the crystal structure. a. atoms b. ions c. geometric points d. equivalent points", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对空间点阵这一基础概念的记忆和理解，需要区分抽象几何点与实际原子/离子位置的关系，属于晶体学中最基础的定义性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解\"空间点阵\"这一基础概念，并能够区分\"几何点\"和\"等效点\"这两个相近选项。虽然不涉及复杂计算或推导，但需要对晶体学基本概念有一定理解才能正确选择。" + }, + { + "idx": 1741, + "question": "According to the law of rational indices, the coordinate axes in a crystal structure should be selected in the direction of . a．mutually perpendicular b．close-packed planes c．rows in the crystal", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c中选择正确答案，符合选择题的特征 | 知识层次: 题目考查晶体结构中坐标轴选择方向的基本概念记忆，属于晶体学基础知识的直接应用，不需要复杂的分析或推理过程。 | 难度: 在选择题中属于中等难度，需要理解晶体结构中的有理指数定律，并能够区分不同选项的含义。虽然题目涉及的是基础概念记忆，但需要对\"rows in the crystal\"这一特定概念有明确的理解，而不是简单的记忆。" + }, + { + "idx": 1742, + "question": "Point out the main differences between recrystallization, crystallization, and solid-state phase transformation", + "answer": "Recrystallization is only a microstructural change without structural change, and its driving force is deformation stored energy; crystallization is the process of forming crystals from amorphous liquid, gas, or solid states; solid-state phase transformation is a structural change between solid/solid phases. The driving forces for the latter two are both chemical free energy differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述三个概念之间的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对recrystallization、crystallization和solid-state phase transformation这三个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题中属于中等难度，需要解释和描述多个相关概念（recrystallization, crystallization, solid-state phase transformation）及其区别，包括驱动力的不同。虽然涉及多个概念，但每个概念的定义和区别相对明确，不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 1743, + "question": "A crystal structure with space group Fm3m belongs to the _ crystal family and crystal system. a. high b. intermediate c. low d. cubic e. hexagonal f. tetragonal g. orthorhombic", + "answer": "a d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了多个选项供选择 | 知识层次: 题目考查对晶体结构和空间群分类的基础概念记忆，属于对晶体家族和晶体系统的基本分类知识的直接应用。 | 难度: 在选择题中属于中等难度，需要理解空间群Fm3m对应的晶体家族和晶体系统，并进行简单辨析。虽然题目涉及基础概念记忆，但需要将空间群与晶体家族和系统对应起来，比单纯记忆定义稍复杂。" + }, + { + "idx": 1744, + "question": "In the non-stoichiometric compound ZrO2-x, the lattice defect present is a. anion vacancy b. cation vacancy c. anion interstitial d. cation interstitial", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查非化学计量化合物中晶格缺陷类型的基本概念记忆，只需识别ZrO2-x中的缺陷类型为阴离子空位，属于基础概念的记忆和理解层面。 | 难度: 在选择题中属于中等难度，需要理解非化学计量化合物的缺陷类型并进行简单辨析。虽然题目涉及的是基础概念记忆，但需要考生对阴离子空位、阳离子空位、间隙缺陷等概念有一定的理解和区分能力，而不仅仅是简单的记忆。" + }, + { + "idx": 1745, + "question": "a≠b≠c,α≠β≠γ crystals belong to the crystal system. a. cubic b. hexagonal c. tetragonal d. orthorhombic", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查晶体系统分类的基本概念记忆，只需记住不同晶体系统的晶格参数特征即可作答 | 难度: 在选择题中属于中等偏易难度，需要理解晶体系统的基本分类原则，并能根据题目给出的条件（a≠b≠c,α≠β≠γ）进行简单辨析。虽然涉及多个参数，但属于基础概念的直接应用，不需要复杂的推理过程。" + }, + { + "idx": 1746, + "question": "The melt is a mixture of . a. polymers with the same degree of polymerization and free alkali b. various polymers with different degrees of polymerization c. various oligomers d. various high polymers", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查对聚合物熔体组成的基本概念记忆，只需理解不同聚合度聚合物的混合状态即可作答，不涉及复杂分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解\"melt\"的基本概念和组成，并能区分不同聚合物的特征。虽然涉及多个选项的辨析，但核心概念相对明确，不需要复杂的推理过程。" + }, + { + "idx": 1747, + "question": "In UO2 crystals, the diffusion of O2- proceeds via the mechanism. a. vacancy b. interstitial c. dopant point defect", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a. vacancy b. interstitial c. dopant point defect）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对UO2晶体中O2-扩散机制的基础概念记忆，属于对基本原理和分类的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解UO2晶体中O2-的扩散机制，并在空缺、间隙和掺杂点缺陷三个选项中进行简单辨析。虽然涉及基础概念记忆，但需要对不同扩散机制有一定理解才能正确选择。" + }, + { + "idx": 1748, + "question": "During liquid-solid phase transformation, the heterogeneous nucleation barrier is related to the contact angle θ. When , the heterogeneous nucleation barrier is reduced by half compared to the homogeneous nucleation barrier. a.θ=0° b.θ=45° c.θ=90° d.θ=180°", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目涉及液固相变过程中的异质成核能垒与接触角的关系，需要理解异质成核和均质成核能垒的计算公式及其关系，并进行简单的数学推导（如能垒减半的条件）。这属于中等应用层次，需要将基本概念与简单计算相结合，但不需要复杂的综合分析或深度推理。 | 难度: 在选择题中属于较高难度，需要理解异质形核与均质形核的能量壁垒关系，掌握接触角θ对形核能的影响机制，并能进行定量计算（需知道异质形核能降低为均质形核能一半时的θ=90°这一关键点）。题目涉及相变热力学和几何因子综合分析，解题步骤包含概念关联和数值关系推导，在同题型中属于复杂分析过程的判断。" + }, + { + "idx": 1749, + "question": "In a ternary system phase diagram, if there are n boundary lines, then the number of connecting lines that can be drawn in this phase diagram is . a. 3 b. n - 1 c. n d. n+1", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案 | 知识层次: 题目考查对三元相图中边界线和连接线数量关系的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解三元系统相图中边界线和连接线的基本概念，并进行简单的数量关系推理。虽然涉及一定的概念理解，但不需要复杂的分析或深度辨析。" + }, + { + "idx": 1750, + "question": "Most solid-phase reactions are in a. chemical reaction kinetics range b. diffusion kinetics range c. transition range", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对固相反应动力学范围的基本概念记忆，属于基础知识的直接回忆和识别。 | 难度: 在选择题中属于中等偏下难度，需要理解固体相反应的基本动力学范围概念，并进行简单辨析。虽然不涉及复杂概念的区分，但需要掌握扩散动力学范围与化学反应动力学范围的区别，属于概念理解和简单辨析的层次。" + }, + { + "idx": 1751, + "question": "In the sintering process, the mass transfer method that only gradually increases the strength of the green body without causing shrinkage of the green body is a. lattice diffusion b. flow mass transfer c. evaporation-condensation d. dissolution-precipitation", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（a. lattice diffusion b. flow mass transfer c. evaporation-condensation d. dissolution-precipitation）中选择正确答案 | 知识层次: 题目考查对烧结过程中不同传质方式特点的基础概念记忆和理解，特别是蒸发-冷凝传质方式的特性。 | 难度: 在选择题中属于中等偏下难度，需要理解烧结过程中不同传质方式的特点，并能区分导致收缩和不导致收缩的传质机制。虽然涉及多个概念，但选项间的区分度较为明显，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 1752, + "question": "There are types of spatial lattice forms that may correspond to the seven crystal systems.", + "answer": "14", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的数字（14），而不是从多个选项中选择或判断对错，也不需要复杂的计算或公式应用。这符合简答题的特征，即需要简洁的回答。 | 知识层次: 题目考查对晶体系统与空间格子类型对应关系的基础概念记忆，属于分类和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答晶体系统对应的空间格子类型数量，属于基础定义简答。题目仅涉及记忆性知识，不需要解释或描述概念，更不需要复杂概念体系的阐述。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 1754, + "question": "In the closest packing of equal-sized spheres, which crystal plane should the close-packed planes of cubic close packing be parallel to?", + "answer": "(111)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别特定的晶体平面，答案是一个具体的晶体学平面指数（111），这需要基于对晶体结构的理解和记忆，而不是从多个选项中选择或进行数值计算。虽然答案简短，但属于需要特定知识的简答题类型。 | 知识层次: 题目考查对立方紧密堆积中密排面平行晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答最密堆积面在立方最密堆积中的晶面指数，属于基础概念记忆层面的问题。题目不涉及复杂解释或论述，只需直接回忆并写出(111)晶面指数即可，符合等级1\"基本定义简答\"的标准。在同类型简答题中，这属于最基础的知识点考查。" + }, + { + "idx": 1755, + "question": "The unit cell is (2), whose _(3)_ and (4)_ are consistent with the corresponding unit parallelepiped.", + "answer": "(2) the smallest unit that can fully reflect the characteristics of the crystal structure; (3) shape; (4) size", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写空缺部分，需要文字解释和论述来回答问题，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对晶胞基本概念的记忆和理解，包括晶胞的定义和特征（形状和大小），属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写晶体结构中最基本单元的定义及其相关特征（形状和大小），这些都是晶体学中最基础的概念记忆性知识，不需要复杂的解释或论述。解题步骤简单，只需准确回忆并填写教材中的标准定义即可，符合等级1对知识点掌握深度和解题复杂度的要求。" + }, + { + "idx": 1756, + "question": "When a cubic close packing is formed by n spheres, what is the number of tetrahedral voids?", + "answer": "2n", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要计算立方紧密堆积中四面体空隙的数量，答案是一个具体的数值（2n），解答过程涉及材料科学中的晶体结构计算。 | 知识层次: 题目需要应用立方密堆积中四面体空隙数量的基本公式（2n），属于直接套用公式的简单计算，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于最低难度，仅需直接套用立方密堆积中四面体空隙数量与球体数量的基本关系公式（2n），无需任何额外计算步骤或公式组合。" + }, + { + "idx": 1757, + "question": "In the thermodynamic relation of diffusion coefficient, $\\\\left(1+\\\\frac{\\\\partial\\\\mathrm{ln}\\\\gamma_{i}}{\\\\partial\\\\mathrm{ln}N_{\\\\mathrm{i}}}\\\\right)$ is called the thermodynamic factor of diffusion coefficient. In a non-ideal mixing system: when the thermodynamic factor of diffusion coefficient > 0, the diffusion result causes the solute to ____; when the thermodynamic factor of diffusion coefficient < 0, the diffusion result causes the solute to ____. a. segregate b. concentration remains unchanged c. concentration tends to be uniform", + "answer": "c a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了多个选项（a. segregate b. concentration remains unchanged c. concentration tends to be uniform）并要求选择正确的填空内容。 | 知识层次: 题目考查对扩散系数热力学因子概念的理解及其在非理想混合系统中的具体应用，需要将热力学因子与扩散结果关联起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解非理想混合系统中的热力学因子概念，并分析其对扩散结果的影响。题目要求考生能够将热力学因子与扩散行为联系起来，进行复杂分析过程的判断。虽然不需要多步计算，但需要对概念有较深的理解和综合分析能力。" + }, + { + "idx": 1758, + "question": "When n spheres form a cubic close packing, what is the number of octahedral voids?", + "answer": "n", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释立方密堆积中八面体空隙的数量，需要文字解释和论述，答案形式为简短的文字回答 | 知识层次: 题目考查立方密堆积中八面体空隙数量的基本概念记忆，属于晶体学基础知识的直接应用，无需复杂计算或分析。 | 难度: 在简答题中属于基本定义简答，仅需记忆立方密堆积中八面体空隙的数量与球体数量的关系，无需复杂解释或概念体系阐述。" + }, + { + "idx": 1759, + "question": "What is the viscosity corresponding to the characteristic temperature Tf?", + "answer": "(19)108dPa·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（108dPa·s），这属于需要直接给出答案的简答题形式，而不是选择题、判断题或需要进行复杂计算的计算题。 | 知识层次: 题目考查的是特征温度Tf对应的粘度值这一基本概念的记忆，属于定义性知识的直接回忆，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回答特定温度Tf对应的粘度数值，属于基础概念记忆层面的直接问答，不需要进行概念解释或复杂体系阐述。在同类简答题中，这是最基础级别的难度，只需记忆特定数值即可作答。" + }, + { + "idx": 1760, + "question": "The crystal structure is related to its (10) (11) and (12).", + "answer": "(10) chemical composition; (11) relative size of particles; (12) polarization properties", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的文字答案（化学组成、颗粒相对大小、极化性质），而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查晶体结构与其化学组成、粒子相对大小和极化性质之间关系的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目要求解释晶体结构与其化学组成、粒子相对大小和极化性质之间的关系。虽然需要记忆多个相关概念，但不需要深入阐述复杂的概念体系或进行多步骤的推理。属于概念解释和描述的难度水平。" + }, + { + "idx": 1761, + "question": "The reason why a base-centered lattice cannot exist in the cubic system is _(9)", + "answer": "If a base-centered lattice existed in the cubic system, the characteristic 4L3 symmetry of the cubic system would no longer exist, which does not conform to the symmetry characteristics of the cubic system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述为什么在立方晶系中不能存在底心点阵，答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释为什么底心点阵不能存在于立方晶系中，这需要深入理解立方晶系的对称性特征（如4L3对称性）以及点阵类型对对称性的影响。这涉及到多个概念的关联和综合分析，属于对晶体学原理的推理分析和机理解释。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释为什么在立方晶系中不能存在底心点阵，需要深入理解立方晶系的对称性特征（如4L3对称性）以及点阵类型对对称性的影响。这需要综合运用晶体学知识，进行推理分析，并给出机理解释。虽然不涉及复杂现象的全面分析，但对机理的解释深度要求较高，因此属于等级4难度。" + }, + { + "idx": 1762, + "question": "When 6 mol% of MgO is added to the UO2 lattice to form a substitutional solid solution, write its solid solution formula", + "answer": "U0.94Mg0.06O1.94", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出固溶体的化学式，需要根据给定的摩尔百分比进行计算和表达，属于需要文字解释和论述的简答题类型。答案的形式是化学式，而非数值计算或选择判断。 | 知识层次: 题目主要考查学生对固溶体化学式书写的基本理解和简单应用能力，涉及简单的摩尔百分比计算和化学式平衡，不需要复杂的推理或多步骤分析。 | 难度: 在简答题中属于简单应用过程描述难度。题目要求将给定的摩尔百分比转换为固溶体化学式，这只需要基本的化学计量计算和简单的替换规则应用。解题步骤明确且直接，不需要深入的解释或复杂的推理过程。在同类简答题中，这属于基础级别的应用题目。" + }, + { + "idx": 1763, + "question": "In the wetting of solid-liquid interfaces, what is the second method to improve wetting?", + "answer": "Increase the surface energy of the solid", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述改善固体-液体界面润湿的第二种方法，答案以文字形式给出，没有提供选项或要求计算。 | 知识层次: 题目考查对固体-液体界面润湿改善方法的基础概念记忆，属于基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答改善固液界面润湿的第二种方法，即增加固体表面能。这需要学生对润湿现象和表面能概念有基本的理解和记忆，并能简要解释其原理。相比等级1的基本定义简答，该题目需要更多的概念理解和描述能力，但不需要进行复杂的概念体系阐述（等级3）。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 1764, + "question": "What is the viscosity corresponding to the characteristic temperature Tg?", + "answer": "(18)1013dPa·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（1013dPa·s），这个数值是材料科学中关于玻璃化转变温度(Tg)对应的特征粘度值，属于需要记忆或理解的知识点回答，不需要计算或选择过程。 | 知识层次: 题目考查的是对特征温度Tg对应的粘度值这一基本概念的记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答一个具体的数值（1013dPa·s），属于最基础的定义性知识记忆。不需要解释概念或进行论述，完全符合等级1\"基本定义简答\"的标准。这是该题型下最简单的一类问题，仅测试学生对特征温度Tg对应粘度的记忆程度。" + }, + { + "idx": 1765, + "question": "In the wetting of solid-liquid interfaces, what is the third method to improve wetting?", + "answer": "Altering the surface roughness of the solid", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释第三种改善固体-液体界面润湿的方法，答案提供了具体的文字解释，符合简答题的特征。 | 知识层次: 题目涉及固体-液体界面润湿性的改善方法，需要理解润湿性的基本原理，并能够关联表面粗糙度对润湿性的影响。这需要多步思考和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解固体-液体界面润湿的基本概念，并能够综合分析和说明改善润湿的第三种方法。虽然题目涉及的知识点较为具体，但不需要多角度分析或深度关联性分析，主要考察对表面粗糙度改变这一方法的理解和阐述能力。" + }, + { + "idx": 1766, + "question": "7. The reason why glass is isotropic is (15)", + "answer": "The long-range disorder of the glass structure exhibits statistical homogeneity macroscopically", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释玻璃各向同性的原因，答案是一段论述性的文字解释，符合简答题的特征 | 知识层次: 题目考查对玻璃各向同性原因的基本概念理解，主要涉及玻璃结构的宏观统计均匀性这一基本原理的记忆和简单解释，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释玻璃各向同性的原因，需要考生理解并描述玻璃结构的无序性及其宏观统计均匀性这一概念，但不需要进行复杂的概念体系阐述或深入分析。这属于对基础概念的理解和简单应用，符合等级2的要求。" + }, + { + "idx": 1767, + "question": "In the wetting of solid-liquid interfaces, one of the methods to improve wetting is?", + "answer": "Reduce the solid-liquid interfacial energy", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案来改善固液界面润湿的方法 | 知识层次: 题目考查对固体-液体界面润湿改进方法的基本概念记忆，仅需知道降低固液界面能是改善润湿的一种方法即可回答，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于简单难度，题目直接考察对固体-液体界面润湿改善方法的记忆，答案明确且无需复杂分析，属于基础概念的直接识别。" + }, + { + "idx": 1768, + "question": "When 6 mol% of MgO is added to the UO2 lattice to form a substitutional solid solution, write the defect reaction equation.", + "answer": "MgO→UO2Mg0′′+O0+V0∗", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求写出缺陷反应方程，需要理解固溶体的形成机制和缺陷化学的基本原理，并能够将这些概念应用到具体的材料体系中。这涉及到多步的思考和概念关联，但不需要进行复杂的推理或创新性的设计。 | 难度: 在简答题中属于中等难度，需要理解缺陷反应的基本原理，并能够正确写出反应方程式。虽然涉及多步概念关联，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 1769, + "question": "What are the two characteristic temperatures on the curve of glass properties changing with temperature?", + "answer": "(16) Tg; (17) Tf", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答两个特征温度的名称，答案以简短的词语形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查对玻璃性质变化曲线中两个特征温度（Tg和Tf）的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答两个特定的温度点（Tg和Tf），不需要进行额外的解释或论述。这属于最基础的概念记忆，符合等级1的标准。" + }, + { + "idx": 1770, + "question": "10. What type of solid solution can albite Na(AlSi3O8) and anorthite Ca(Al2Si2O8) form?", + "answer": "Continuous substitutional solid solution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释albite和anorthite能形成哪种类型的固溶体，答案需要文字描述（Continuous substitutional solid solution），而非从选项中选择或简单判断对错，也不涉及计算过程。 | 知识层次: 题目需要理解固溶体的类型和形成条件，并能够将这一概念应用到具体的矿物系统中。虽然不涉及复杂的计算或推理，但需要对固溶体的连续性和置换性有清晰的理解，并能将这一概念与具体的矿物组成联系起来。这超出了单纯记忆的层次，属于中等应用水平。 | 难度: 在简答题中属于中等难度，需要理解固溶体的基本概念，并能分析长石系列矿物（如钠长石和钙长石）的晶体化学特征。虽然题目不涉及多步计算，但需要对固溶体类型（连续置换型固溶体）有明确认识，并能将矿物学知识与材料科学原理结合进行综合分析。相比简单回忆型简答题（等级1-2）或需要多角度深度论述的题目（等级4-5），此题主要考察单一知识点的应用和解释能力。" + }, + { + "idx": 1771, + "question": "11．The crystallographic characteristics of martensitic transformation are manifested as: _（26）_, etc.", + "answer": "（26）the presence of habit plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（\"the presence of habit plane\"）来补充句子，这属于需要简短文字回答的简答题类型。题目没有提供选项，也不是判断对错或计算题。 | 知识层次: 题目考查马氏体相变的晶体学特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基础概念记忆层次，仅需回忆马氏体相变的晶体学特征之一（惯习面存在性），无需展开解释或论述。解题步骤仅涉及单一知识点的直接提取，符合等级1\"基本定义简答\"的标准，是该题型框架内最基础的问题形式。" + }, + { + "idx": 1772, + "question": "11. The crystallographic characteristics of martensitic transformation are manifested as: _（27）_, etc.", + "answer": "（27）strict orientation relationship", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的术语（\"strict orientation relationship\"）来补充句子，属于需要简短文字回答的题目类型。 | 知识层次: 题目考查马氏体相变的晶体学特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答马氏体相变的晶体学特征之一（严格的取向关系），属于基础概念记忆层面的直接简答。题目不涉及概念解释或复杂体系阐述，仅需回忆单一知识点即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1773, + "question": "11. The crystallographic characteristics of martensitic transformation are manifested as: _(28)_, etc.", + "answer": "(28) maintaining coherent relationship", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的概念或特征（如maintaining coherent relationship），这需要学生对马氏体相变的晶体学特征有一定的理解和记忆，属于简答题类型。 | 知识层次: 题目考查马氏体相变的晶体学特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答马氏体相变的晶体学特征之一（保持共格关系），属于基础概念记忆层面的直接简答，不需要展开解释或复杂论述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1774, + "question": "10. What ions in plagioclase Na(AlSi3O8) and what ions in anorthite Ca(Al2Si2O8) can substitute for each other?", + "answer": "Na+ and Si4+ in plagioclase can substitute for Ca2+ and Al3+ in anorthite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种矿物中哪些离子可以相互替代，需要文字解释和论述，答案也是以文字形式给出，而非选择、判断或计算。 | 知识层次: 题目涉及离子替代的概念，需要理解不同矿物中离子的化学性质和替代机制，属于多步概念关联和综合分析。虽然不涉及复杂计算，但需要对化学键和晶体结构有一定理解，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解离子替代的概念，并能正确识别和匹配不同矿物中的可替代离子。虽然涉及多步分析和概念关联，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 1776, + "question": "A green body with an initial particle size of 5μm is sintered for 2h to reach x/r=0.1. If sintering continues until x/r=0.2 (without considering grain growth), what is the required sintering time when material transport occurs via dissolution-precipitation?", + "answer": "128h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要应用烧结动力学公式进行数值计算，通过初始条件(x/r=0.1)和最终要求(x/r=0.2)来计算所需的烧结时间(128h)，属于典型的计算题类型。 | 知识层次: 题目涉及多步计算和公式应用，需要理解烧结过程中x/r比与时间的关系，并应用溶解-沉淀机制的动力学方程进行计算。虽然不需要复杂的机理分析或创新设计，但需要将概念与计算相结合，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解溶解-沉淀机制下的烧结动力学方程，并进行多步计算（包括初始条件的应用和比例关系的推导）。虽然不涉及复杂多变量，但需要将理论知识与数值计算相结合，属于中等应用层次的计算题。" + }, + { + "idx": 1777, + "question": "There is a green body with an initial particle size of 5μm. After sintering for 2h, x/r=0.1. If sintering proceeds until x/r=0.2 (without considering grain growth), what is the required sintering time when material transport is dominated by viscous flow?", + "answer": "8h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算，涉及公式应用（x/r与时间的关系），最终答案为具体数值（8h），属于典型的计算题。 | 知识层次: 题目涉及多步计算和概念关联，需要理解烧结动力学中的x/r比例关系，并应用相关公式进行时间计算，但不需要复杂的机理分析或创新应用。 | 难度: 在计算题中属于多步骤计算过程难度。题目涉及烧结动力学的基本公式应用（x/r与时间的关系），但仅需单变量（时间）的简单比例推导（x/r从0.1到0.2对应时间平方关系），无需处理多变量或复杂边界条件。解题步骤明确：1) 识别黏性流动机制下x/r∝t^(1/2)的关系；2) 根据比例关系直接计算时间倍数（0.2/0.1=2→2²=4倍原始时间）。虽需概念关联（烧结动力学与传输机制），但计算逻辑线性且无附加条件干扰，符合等级2\"多步骤计算\"而非更高等级的综合/复杂要求。" + }, + { + "idx": 1778, + "question": "There is a green body with an initial particle size of 5μm. After sintering for 2h, x/r=0.1. If sintering continues until x/r=0.2 (without considering grain growth), what is the required sintering time when the material transport is dominated by evaporation-condensation?", + "answer": "16h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及烧结时间和粒子尺寸变化的关系，最终答案为具体数值（16h），属于典型的计算题。 | 知识层次: 题目涉及多步计算和公式应用，需要理解蒸发-凝聚机制对烧结过程的影响，并运用相关公式进行时间计算。虽然不涉及复杂的机理分析或创新设计，但需要综合理解和应用多个概念来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要理解蒸发-凝聚主导的物质传输机制，并应用烧结动力学公式进行多步计算（包括初始条件的转换和时间的平方关系推导）。虽然不涉及复杂多变量，但需要将理论概念与数学推导紧密结合，属于中等偏上的综合难度。" + }, + { + "idx": 1779, + "question": "A green body has an initial particle size of 5μm. After sintering for 2h, x/r=0.1. If sintering proceeds until x/r=0.2 (without considering grain growth), what is the required sintering time when the process is driven by diffusion mass transfer?", + "answer": "64h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要应用扩散传质的相关公式进行数值计算，最终得出一个具体的数值答案（64h）。解答过程涉及公式推导和计算步骤，属于典型的计算题。 | 知识层次: 题目涉及多步计算和公式应用，需要理解烧结过程中扩散质量传递的动力学关系，并能够将初始条件与最终条件相关联进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散质量转移的基本原理，应用烧结动力学公式（如x/r与时间的关系），并进行多步计算（从初始条件推导时间指数关系，再求解新条件下的时间）。虽然不涉及复杂多变量，但需要将理论公式与具体数值计算结合，属于中等应用层次的计算题。" + }, + { + "idx": 1781, + "question": "Component defect", + "answer": "3. Component defect: In solid solutions with non-equivalent substitution, in order to maintain the electrical neutrality of the crystal, vacancies or interstitial ions are inevitably generated in the crystal. This type of crystal defect is called a component defect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“component defect”进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查的是对组分缺陷这一基本概念的定义和形成原因的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"component defect\"的定义及其产生原因，涉及对非等价替代固溶体中电中性维持机制的理解。虽然需要阐述晶体缺陷的产生原理，但不需要构建复杂的理论体系或进行多层次的逻辑推导，属于中等难度的概念解释题。" + }, + { + "idx": 1782, + "question": "Degrees of freedom in phase diagrams", + "answer": "Degrees of freedom in phase diagrams: In a phase equilibrium system, the independent variables that can be arbitrarily changed within a certain range without causing the disappearance of old phases or the formation of new phases are called degrees of freedom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“相图中的自由度”进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查相图中自由度的定义，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要准确表述相图中的自由度定义，但不需要进行复杂的概念体系阐述或多层次分析，仅需对基础概念进行清晰说明即可。" + }, + { + "idx": 1783, + "question": "Inverse spinel structure", + "answer": "Inverse spinel structure: It belongs to the cubic crystal system, where oxygen ions can be considered to be arranged in a cubic close-packed structure. Divalent cations A occupy octahedral sites, while trivalent cations B are half-filled in octahedral sites and half-filled in tetrahedral sites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Inverse spinel structure\"进行文字解释和论述，答案提供了详细的晶体结构描述，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对反尖晶石结构的基本定义和离子分布的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释反尖晶石结构的基本组成和离子分布，涉及晶体结构、离子占据位置等基础概念，但不需要复杂的体系阐述或多层次分析。学生需要准确记忆并清晰表述相关知识点，属于中等难度的概念解释类简答题。" + }, + { + "idx": 1784, + "question": "Electrokinetic potential of clay colloids", + "answer": "Electrokinetic potential of clay colloids: When charged clay colloids are dispersed in water, a diffuse double layer forms at the interface between the colloidal particles and the liquid phase. The adsorption layer and the diffuse layer carry opposite charges, and the potential difference between them during relative movement is called the electrokinetic potential.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Electrokinetic potential of clay colloids\"进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对粘土胶体电动力学电位的基本概念和形成机理的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释粘土胶体的电动电位现象，涉及扩散双电层的形成、吸附层与扩散层的关系以及电位差的定义。虽然需要理解多个相关概念，但不需要构建复杂的理论体系或进行深入分析，主要考察对基础概念的理解和描述能力。" + }, + { + "idx": 1785, + "question": "Pb has a face-centered cubic structure with an atomic radius of 0.1750 nm. Calculate the volume of its unit cell.", + "answer": "V = a³ = (2√2r)³ = 0.1212 nm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用面心立方结构的边长公式和体积公式）来求解单位晶胞的体积，答案是一个具体的数值计算结果。 | 知识层次: 题目考查基本公式应用和简单计算，仅需套用面心立方结构的边长与原子半径关系公式（a = 2√2r）并进行立方计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用面心立方结构的边长与原子半径关系公式a=2√2r，然后进行简单的立方计算即可得到结果。无需多个公式组合或复杂推导。" + }, + { + "idx": 1786, + "question": "The chemical composition of a glass is: 24mol% Na2O, 12mol% Al2O3, 64mol% SiO2. Calculate the four structural parameters Z, R, X, and Y of this glass.", + "answer": "Converted to 6Na2O·3Al2O3·16SiO2; Z=4; R=2.17; Y=3.66; X=0.34.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解四个结构参数（Z, R, X, Y），答案给出了具体的计算结果，这符合计算题的特征。 | 知识层次: 题目需要将化学组成转换为摩尔比例，并应用多个结构参数计算公式进行多步计算。涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要将化学组成转换为摩尔比例，然后应用结构参数公式进行多步计算。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有复杂的多变量处理。" + }, + { + "idx": 1787, + "question": "The defect concentration of the non-stoichiometric compound TiO2-x is related to the nature and partial pressure of the surrounding atmosphere. When the oxygen partial pressure is increased, explain through calculation what changes will occur in the density of TiO2-x.", + "answer": "As the value of x in TiO2-x increases, its density decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算解释TiO2-x密度的变化，答案提供了文字解释和论述，而非简单的数值计算或选择判断。 | 知识层次: 题目要求通过计算解释非化学计量化合物TiO2-x的缺陷浓度与周围气氛氧分压的关系，并分析其对密度的影响。这涉及多步计算和概念关联，需要综合分析氧分压变化对缺陷浓度和材料密度的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度等级。题目要求通过计算解释非化学计量化合物TiO2-x的缺陷浓度与周围气氛氧分压的关系，并进一步分析密度变化。这需要学生：" + }, + { + "idx": 1788, + "question": "In the manufacturing of Al2O3 ceramics, the particle size of the raw material is 2μm. After holding at the sintering temperature for 30min, the measured grain size is 10μm. What will be the grain size in μm after holding at the same sintering temperature for 2h?", + "answer": "d1=20μm(D2=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要应用公式（D2=kt）进行数值计算，以确定晶粒尺寸的变化，属于典型的计算题类型。 | 知识层次: 题目主要考查对晶粒生长公式（D²=kt）的简单应用，只需进行一步计算即可得出结果，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目虽然涉及烧结过程中晶粒生长的动力学计算，但仅需直接套用D2=kt公式进行简单代数运算即可得出结果，不需要多个公式组合或复杂推导过程。属于基本公式应用层级，但比单一公式直接计算（如仅代入一个变量）略复杂，因此评为等级2。" + }, + { + "idx": 1789, + "question": "The defect concentration of the non-stoichiometric compound Zn1+xO is related to the nature and partial pressure of the surrounding atmosphere. When the oxygen partial pressure is increased, explain through calculation what changes will occur in the density of Zn1+xO.", + "answer": "ZnO↔Zni+2e'+1/2O2; Zn1+xO; the concentration of zinc interstitial ions is inversely proportional to the oxygen partial pressure. When the oxygen partial pressure increases, the x value in Zn1+xO decreases, resulting in a reduction of its density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算解释Zn1+xO密度的变化，答案提供了详细的化学反应方程式和文字解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解非化学计量化合物Zn1+xO的缺陷浓度与氧分压的关系，并通过化学反应方程式和浓度关系进行多步计算和综合分析，涉及概念关联和中等程度的思维深度。 | 难度: 在简答题中属于较高难度，需要结合化学反应平衡、缺陷化学和材料密度变化进行多角度分析论述。题目要求通过计算解释氧分压变化对Zn1+xO密度的影响，涉及多个概念关联和综合分析步骤，超出了基础概念说明的范畴。" + }, + { + "idx": 1790, + "question": "To inhibit grain growth, 0.2% MgO was added to the raw powder, and the temperature was held for 2 hours at the same sintering temperature. What is the grain size in μm?", + "answer": "d2=16μm (D³=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式（D³=kt）和参数（d2=16μm）进行数值计算，最终得出晶粒尺寸的具体数值。这符合计算题的特征，即需要应用公式和数值计算来解决问题。 | 知识层次: 题目主要涉及基本公式（D³=kt）的直接应用和简单计算，不需要多步推理或综合分析，属于对已有知识的直接套用。 | 难度: 在计算题中属于最简单难度，只需要直接套用单一公式（D³=kt）进行简单数值计算，无需多步骤推导或组合公式。题目已经给出所有必要参数，计算过程直接明了。" + }, + { + "idx": 1791, + "question": "Conditions necessary for mud peptization", + "answer": "① The medium must be alkaline, ② Monovalent alkali metal cations must exchange with the higher-valent ions originally adsorbed on the clay, ③ Polymerization of anions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出泥浆胶溶的必要条件，答案以文字解释和论述的形式给出，没有提供选项或要求判断对错，也不需要数值计算。 | 知识层次: 题目考查泥浆胶溶作用的基本条件，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列出泥浆胶溶的必要条件，涉及多个关键点（碱性介质、单价阳离子交换、阴离子聚合），但不需要深入阐述各条件之间的相互作用或复杂机制。相比等级1的基本定义简答，它需要更全面的知识点回忆；但相比等级3的复杂体系阐述，其解题步骤和逻辑链条较为直接，属于中等难度的概念描述题。" + }, + { + "idx": 1792, + "question": "Structurally compare the arrangement of silicon-oxygen frameworks in silicate crystals and silicate glasses", + "answer": "In silicate crystals, the silicon-oxygen frameworks are arranged in an orderly manner according to certain symmetrical rules; in silicate glasses, the arrangement of silicon-oxygen frameworks is disordered.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对硅酸盐晶体和硅酸盐玻璃中硅氧骨架的排列进行结构性比较，需要文字解释和论述，而不是选择、判断或计算。答案也以文字形式呈现，解释了两种材料中硅氧骨架排列的有序性和无序性。 | 知识层次: 题目主要考查对硅酸盐晶体和玻璃中硅氧骨架排列方式的基本概念记忆和理解，属于基础概念层次的认知能力要求。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较硅酸盐晶体和硅酸盐玻璃中硅氧骨架的排列方式，需要考生理解并描述两种材料的结构特点，但不需要深入分析或阐述复杂的理论体系。虽然涉及两个概念的比较，但都属于基础概念的记忆和简单应用，解题步骤相对直接，符合等级2的标准。" + }, + { + "idx": 1793, + "question": "Briefly describe the mechanism of slurry peptization", + "answer": "Due to the difference in electrical charges on the edge and face surfaces of plate-like clay particles, face-face, edge-face, or edge-edge associations occur, forming a certain structure in the slurry that increases flow resistance. The peptization process of the slurry involves breaking down this internal structure, transforming edge-face and edge-edge associations into face-face arrangements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述浆料胶溶的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释浆料胶溶的机制，涉及颗粒表面电荷差异和结构变化，需要综合运用电化学、胶体化学和流变学知识，进行机理分析和推理。 | 难度: 在简答题题型中，该题目要求对粘土颗粒的电荷差异及其在浆料中的结构形成和破坏机制进行深度解释。虽然不涉及多个复杂现象的全面分析（等级5），但需要对特定机理有深入理解和清晰表述，属于机理深度解释的范畴。" + }, + { + "idx": 1794, + "question": "Structurally compare the distribution characteristics of extra-framework metal ions in silicate crystals and silicate glasses", + "answer": "In silicate crystals, the extra-framework metal ions occupy certain positions in the lattice; whereas in silicate glasses, the network-modifying ions are statistically distributed within the voids of the framework, balancing the negative charge of oxygen.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对硅酸盐晶体和硅酸盐玻璃中的额外骨架金属离子分布特征进行结构性比较，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较硅酸盐晶体和玻璃中金属离子的分布特性，涉及对两种材料结构的理解以及它们之间的对比分析。这需要将多个概念关联起来进行综合分析，而不仅仅是记忆或简单应用。虽然不涉及复杂的机理或创新设计，但需要一定的思维深度和知识关联。 | 难度: 在简答题题型内，该题目要求对硅酸盐晶体和玻璃中的金属离子分布特征进行多角度分析论述。需要理解晶体结构中的固定位置与玻璃中统计分布的区别，并解释电荷平衡机制。这超出了基础概念复述（等级3），但尚未达到需要深度关联其他学科知识的等级5水平。" + }, + { + "idx": 1795, + "question": "Compare the conditions for the substitution of extra-framework cations in silicate crystals and silicate glasses from a structural perspective", + "answer": "In silicate crystals, isomorphous substitution can only occur when the radius of the foreign cation is similar to that of the cation in the crystal; in silicate glasses, extra-framework cations can undergo substitution regardless of their radius, as long as electrical neutrality is maintained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从结构角度比较硅酸盐晶体和硅酸盐玻璃中额外骨架阳离子的取代条件，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求从结构角度比较硅酸盐晶体和玻璃中额外骨架阳离子的取代条件，涉及对晶体和玻璃结构的深入理解，以及不同条件下取代机制的对比分析。需要综合运用材料科学知识，进行推理和解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求从结构角度比较硅酸盐晶体和玻璃中阳离子取代的条件，涉及机理深度解释。虽然不需要全面分析复杂现象，但需要对晶体和玻璃的结构差异有深入理解，并能解释不同条件下阳离子取代的机理。这属于机理深度解释的难度等级。" + }, + { + "idx": 1796, + "question": "Structurally compare the characteristics of oxide composition ratios in silicate crystals and silicate glasses", + "answer": "In crystals, the original components (oxides) have simple fixed quantitative ratios between each other; whereas in glasses, oxides are mixed in almost any proportion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对硅酸盐晶体和硅酸盐玻璃中氧化物组成比例的结构特征进行比较，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较硅酸盐晶体和玻璃中氧化物组成比例的结构特征，涉及对晶体和玻璃结构的理解以及两者之间的对比分析。虽然不涉及复杂计算或深度机理分析，但需要综合运用多个概念并进行关联分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对氧化物组成比例在硅酸盐晶体和玻璃中的结构特性进行比较，但答案相对直接，主要涉及对固定比例和任意比例的描述。不需要多角度或深度关联性分析，只需进行基本的综合分析和说明即可。因此，在简答题的框架内，该题目属于等级3的难度。" + }, + { + "idx": 1798, + "question": "What are the diffusion coefficient, activation energy, and characteristics of intrinsic diffusion?", + "answer": "The activation energy of intrinsic diffusion consists of two parts: vacancy formation energy and particle migration energy, with intrinsic diffusion dominating at high temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散系数、活化能和本征扩散的特征，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释本征扩散的扩散系数、激活能及其特性，涉及对扩散机制的理解和概念关联，需要综合分析扩散过程中的能量组成（空位形成能和粒子迁移能）及其温度依赖性，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对内在扩散的扩散系数、活化能和特性进行多角度分析论述。需要综合理解空缺形成能和粒子迁移能的概念，并说明其在高温条件下的主导作用。这涉及到多个概念的关联和综合分析，属于该题型中较高难度的题目。" + }, + { + "idx": 1799, + "question": "Briefly describe the difference between grain growth and secondary recrystallization", + "answer": "Grain growth is the continuous increase in average grain size, with uniform grain size growth, and pores remaining at grain boundaries or grain boundary intersections; secondary recrystallization is the abnormal growth of individual grains, with pores being trapped inside the grains. Secondary recrystallization is also related to the particle size of the raw material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述晶粒生长和二次再结晶的区别，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对晶粒生长和二次再结晶这两个基本概念的记忆和理解，需要区分它们的定义和特征，属于基础概念记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释两个概念的区别，并涉及一些细节描述（如孔隙位置、原料粒径影响）。虽然不涉及复杂体系阐述，但已超出单纯的定义复述，需要对概念有较清晰的理解和对比能力。" + }, + { + "idx": 1800, + "question": "What are the diffusion coefficient, activation energy, and characteristics of extrinsic diffusion?", + "answer": "The activation energy of extrinsic diffusion only includes the migration energy of particles, and extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散系数、激活能和外扩散的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释扩散系数、激活能以及外扩散的特性，涉及多个概念的关联和综合分析，需要理解外扩散在低温下的主导作用及其激活能的组成，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对扩散系数、激活能和外扩散特性进行多角度分析论述。需要综合理解外扩散在低温下的主导作用及其与迁移能的关系，涉及概念关联和综合分析，属于较高难度的简答题。" + }, + { + "idx": 1802, + "question": "Discuss the grain growth process based on the limiting grain size", + "answer": "The grain growth process is briefly described.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论晶粒生长过程，需要文字解释和论述，答案形式为简要描述，符合简答题的特征 | 知识层次: 题目要求讨论基于限制晶粒尺寸的晶粒生长过程，这需要对晶粒生长的机理、影响因素以及限制条件进行深入分析和综合理解，涉及多概念的关联和推理分析。 | 难度: 在简答题题型中，该题目要求对晶粒生长过程进行基于限制晶粒尺寸的讨论，这需要机理深度解释和综合运用相关知识。虽然题目提供了简要描述，但完整的回答需要涉及晶粒生长的驱动力、动力学以及限制因素等多个方面，属于该题型中较高难度的题目。" + }, + { + "idx": 1805, + "question": "What are grain growth and secondary recrystallization?", + "answer": "Grain growth is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution. Within the body, grain sizes grow uniformly, and during grain growth, pores remain at grain boundaries or their intersections. Secondary recrystallization is an abnormal growth process where a few large grains grow at the expense of fine grains, representing the abnormal growth of individual grains. During secondary recrystallization, pores become trapped inside the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"grain growth\"和\"secondary recrystallization\"这两个概念进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对晶粒生长和二次再结晶这两个基本概念的定义和特征的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。虽然涉及两个相关概念（grain growth和secondary recrystallization），但每个概念的解释都较为直接，主要要求考生记忆并准确表述定义和基本特征，不需要进行复杂的比较分析或深入阐述概念间的相互作用。题目要求的知识深度处于基础概念记忆层次，符合等级2的标准。" + }, + { + "idx": 1806, + "question": "In the orthorhombic system, the possible types of space lattices are a.P, I, C b.P, 1, F c.P, C, F d.P, F, 1, C", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，选项以字母编号形式给出，答案也是选项编号 | 知识层次: 题目考查对正交晶系可能的空间格子类型的基础概念记忆，属于晶体学分类的基本知识，不需要复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要记忆并理解正交晶系中可能的空间格子类型（P, F, I, C），但不需要进行复杂的比较分析。选项中的干扰项（如\"1\"）较为明显，容易排除。" + }, + { + "idx": 1807, + "question": "In the spinel (MgAl2O4) structure, O2- forms a cubic close packing, and Mg2+ ions fill a. 1/2 of the tetrahedral voids b. 1/2 of the octahedral voids c. 1/8 of the tetrahedral voids d. 1/8 of the octahedral voids", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对尖晶石结构中离子占据空隙类型和比例的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏易难度，需要理解尖晶石结构中离子填充的基本原理，并能区分四面体和八面体空隙的填充比例。虽然涉及多个概念，但属于基础晶体学知识的直接应用，无需复杂推导。" + }, + { + "idx": 1808, + "question": "Kaolinite belongs to the layered silicate structure, and its structural feature is a. two-layer type trioctahedral structure b. three-layer type trioctahedral structure c. two-layer type dioctahedral structure d. three-layer type dioctahedral structure", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案 | 知识层次: 题目考查对高岭石（Kaolinite）结构特征的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要考生对高岭石的结构特征有基本理解和记忆，但不需要复杂的分析或比较。题目涉及对层状硅酸盐结构类型的区分，属于基础概念记忆和理解范畴，但比简单识别概念略复杂。" + }, + { + "idx": 1809, + "question": "In the non-stoichiometric compound Cd1+xO, the type of non-stoichiometric structural defect present is a. anion vacancy b. cation vacancy c. anion interstitial d. cation interstitial", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对非化学计量化合物中缺陷类型的基本概念记忆和理解，属于基础知识点。 | 难度: 在选择题中属于中等难度，需要理解非化学计量化合物的缺陷类型，并区分阴离子空位、阳离子空位、阴离子间隙和阳离子间隙等概念。虽然题目涉及基础概念记忆，但需要对不同类型的缺陷有一定的辨析能力。" + }, + { + "idx": 1810, + "question": "Among various layered silicate structures, the unit cell parameters that are similar are a.a0 and b0 b.a0 and c0 c.c0 and b0 d.c0", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对层状硅酸盐结构单元晶胞参数的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在选择题中属于中等偏下难度，需要理解层状硅酸盐结构的基本单元参数概念，并进行简单的参数对应关系辨析。虽然涉及多个参数比较，但选项设置较为直接，不需要复杂的分析过程。" + }, + { + "idx": 1812, + "question": "The viscosity corresponding to the glass transition temperature Tg is a.108dPa·s b.1010dPa·s c.1011dPa·s d.1013dPa·s", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对玻璃转变温度Tg对应粘度值的基础概念记忆，属于定义性知识的直接回忆。 | 难度: 该题目属于基础概念记忆的选择题，仅需直接回忆玻璃转变温度Tg对应的粘度值即可选出正确答案，无需进行概念理解或辨析，属于最简单的记忆性知识考查。" + }, + { + "idx": 1814, + "question": "In the sintering process, the mass transfer method that only changes the pore shape without causing shrinkage of the green body is a. diffusion mass transfer b. flow mass transfer c. evaporation-condensation mass transfer d. grain boundary diffusion", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查烧结过程中物质传递方式的基本概念记忆，只需要识别蒸发-凝聚传质的特点即可作答，不涉及复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解烧结过程中不同传质方式的特点，并能区分蒸发-凝聚传质与其他传质方式的区别。虽然涉及多个概念，但选项间的区分度较为明显，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 1815, + "question": "Pauling's rules apply to (1)__ crystal structures.", + "answer": "(1) ionic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（ionic）来完成句子，这属于需要简短文字回答的简答题类型 | 知识层次: 题目考查对Pauling规则适用对象的基本概念记忆，属于晶体结构分类的基础知识，仅需简单回忆即可作答。 | 难度: 该题目属于简答题中的基本定义简答类型，仅需回忆Pauling规则适用的晶体结构类型（离子晶体），无需进行概念解释或复杂体系阐述。在基础概念记忆层次中，这是最基础的记忆性知识考查，符合等级1的难度标准。" + }, + { + "idx": 1816, + "question": "In the phase diagram of a ternary condensed system, if there are n boundary lines, the number of connection lines in this phase diagram must be a. (n+1) lines b. (n-1) lines c. n lines d. none", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a. (n+1) lines b. (n-1) lines c. n lines d. none）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对三元相图中边界线和连接线数量关系的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解相图中的边界线和连接线的基本概念，并进行简单的辨析。虽然题目涉及的是基础概念记忆，但需要一定的理解才能正确选择答案。" + }, + { + "idx": 1817, + "question": "In the calculation of solid-state reactions, the Ginstling equation has a wider range of applicability than the Jander equation, and the biggest difference between the two is a. Different calculation methods b. The former is solved by the unstable diffusion equation c. Different geometric models", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对Ginstling方程和Jander方程之间差异的基础概念记忆，主要涉及两种方程的不同几何模型，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要对Ginstling方程和Jander方程的基本区别有所理解，但不需要深入分析复杂的计算过程或推导。题目主要考察对两种方程几何模型差异的记忆和简单辨析。" + }, + { + "idx": 1819, + "question": "The essence of a crystal is (2)", + "answer": "(2) Particles are arranged in a periodic repetition in three-dimensional space", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(2)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查晶体本质的基本概念记忆，仅需理解晶体中粒子在三维空间周期性排列的定义，不涉及应用或分析。 | 难度: 在选择题中属于简单难度，题目直接考察对晶体本质的基础概念记忆，只需识别\"粒子在三维空间中周期性排列\"这一基本定义，无需进行复杂辨析或深度理解。" + }, + { + "idx": 1820, + "question": "When selecting the unit parallelepiped of a space lattice, the primary principle is _ (3)", + "answer": "(3) The symmetry of the unit parallelepiped should conform to the symmetry of the entire space lattice", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案部分给出了一个明确的选项（3），符合选择题的特征 | 知识层次: 题目考查对空间晶格单位平行六面体选择原则的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，虽然需要理解空间晶格和单位平行六面体的对称性关系，但题目明确给出了关键概念\"symmetry\"，且选项(3)直接对应基本原理，不需要复杂的辨析过程。相比等级1的直接记忆题，需要稍高层次的概念理解，但未达到等级3的多概念深度区分要求。" + }, + { + "idx": 1821, + "question": "One of the conditions for clay slurry peptization is (6)", + "answer": "The medium is alkaline", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的条件，答案是一个简短的陈述，不需要从多个选项中选择，也不涉及计算或判断对错。 | 知识层次: 题目考查粘土浆料胶溶条件的基本概念记忆，仅需回忆碱性介质这一基本条件，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并写出粘土浆料胶溶作用的一个条件（介质呈碱性），不需要进行概念解释或复杂体系阐述，属于最基础的概念记忆层次。" + }, + { + "idx": 1822, + "question": "同质多晶现象是指 (4)", + "answer": "（4）chemical substances with the same composition form crystals with different structures under different thermodynamic conditions", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案给出了一个明确的选项编号(4)和对应的解释，符合选择题的特征 | 知识层次: 题目考查对同质多晶现象这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不需要应用或分析。 | 难度: 在选择题中属于中等偏下难度，虽然需要理解同质多晶现象的定义，但题目直接给出了明确的定义描述，只需进行简单的概念理解和辨析即可选出正确答案。不需要进行复杂的概念区分或深度理解。" + }, + { + "idx": 1823, + "question": "A crystal with space group Fm3m has a (5)_ structure.", + "answer": "(5) face-centered cubic structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（face-centered cubic structure）作为答案，属于需要简短文字回答的题目类型 | 知识层次: 题目考查对晶体结构空间群与对应结构类型的基础概念记忆，仅需识别Fm3m空间群对应的face-centered cubic结构，属于定义和分类的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答的难度等级。题目仅要求识别并写出Fm3m空间群对应的晶体结构类型（面心立方结构），属于最基础的概念记忆性知识，不需要额外的解释或论述步骤。在简答题框架内，这是最直接和简单的回答形式。" + }, + { + "idx": 1824, + "question": "Glass has the following general properties: (12)", + "answer": "Isotropic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对玻璃的一般性质进行描述，答案需要提供文字解释（Isotropic），而不是从多个选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目考查玻璃基本性质（各向同性）的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目仅要求回答\"玻璃的一般特性\"这一基本定义，属于最基础的概念记忆层面。不需要解释或描述，更不需要复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1825, + "question": "One of the conditions for the peptization of clay slurry is (8)", + "answer": "Polymerization of anions", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，括号中的数字(8)暗示这是选择题的第8个选项 | 知识层次: 题目考查粘土浆体胶溶条件的基本概念记忆，属于定义性知识的直接回忆 | 难度: 在选择题中属于中等偏下难度，虽然需要理解\"peptization of clay slurry\"的基本概念和条件，但答案\"Polymerization of anions\"是其中一个较为直接的条件，不需要复杂的辨析或深度理解多个相关概念。" + }, + { + "idx": 1826, + "question": "What type of diffusion problem does Fick's first law apply to?", + "answer": "Steady-state diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释Fick's first law适用的扩散问题类型，答案是一个简短的文字描述（Steady-state diffusion），不需要计算或从多个选项中选择。 | 知识层次: 题目考查对Fick第一定律适用条件的基本概念记忆，属于基础概念记忆性知识，无需复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答\"Steady-state diffusion\"这一基本定义，属于最基础的概念记忆层面。不需要进行额外的解释或描述，更不需要构建复杂的概念体系。在同题型内，这属于最简单的等级1难度，相当于直接回忆教材中的定义性内容。" + }, + { + "idx": 1827, + "question": "What type of diffusion problems is Fick's second law applicable to solve?", + "answer": "Non-steady-state diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释Fick's second law适用的扩散问题类型，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对Fick第二定律适用范围的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答Fick's second law适用的扩散问题类型，属于基础定义简答。题目直接考察对非稳态扩散这一基本概念的识记，无需进行概念解释或复杂体系阐述，符合等级1的基本定义简答标准。" + }, + { + "idx": 1828, + "question": "One of the conditions for the peptization of clay slurry is (7)", + "answer": "Exchange of original cations with monovalent alkali metal cations", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释粘土浆体胶溶的条件之一，答案是一个具体的文字解释，而不是从多个选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查的是粘土浆体胶溶条件的基本概念记忆，属于对基本原理和条件的直接回忆和简单理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释粘土浆体胶溶的条件之一，即原始阳离子与单价碱金属阳离子的交换。这需要学生对胶溶的基本原理和相关概念有一定的理解和记忆，但不需要复杂的体系阐述或深入的分析。因此，在简答题题型内，该题目属于中等难度。" + }, + { + "idx": 1829, + "question": "The vacancy mechanism of diffusion refers to (11)", + "answer": "(11) When vacancies exist in the lattice, the diffusion mode of mass points mediated by vacancy migration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对空缺扩散机制进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对空位扩散机制这一基本概念的记忆和理解，属于定义性知识的直接回忆和简单解释，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答空缺扩散机制的基本定义，属于最基础的概念记忆层面。题目没有要求解释相关原理或进行复杂概念体系的阐述，仅需直接回忆并复述定义内容，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 1830, + "question": "Glass has the following general properties: (13)", + "answer": "Metastability", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对玻璃的一般性质进行描述，答案\"Metastability\"是一个简短的文字解释，符合简答题的特征。 | 知识层次: 题目考查对玻璃一般性质的基础概念记忆，特别是其亚稳态特性的理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答\"Metastability\"这一基本定义，属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。题目仅考察学生对玻璃一般特性的最基础记忆，没有涉及任何解释性或分析性要求。" + }, + { + "idx": 1831, + "question": "Glass has the following general properties: (14)", + "answer": "The transformation process is reversible and gradual", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对玻璃的一般性质进行描述，答案是一个陈述句，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查玻璃的一般性质，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回答玻璃的一般特性之一（转变过程可逆且渐进），不需要进行概念解释或复杂体系阐述。答案直接来自基础概念记忆，不涉及分析或推理过程，符合等级1对知识点掌握深度和解题步骤简单的要求。" + }, + { + "idx": 1832, + "question": "What is the migration of particles caused by intrinsic diffusion?", + "answer": "Vacancies generated by intrinsic thermal defects", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释粒子迁移的原因，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对\"本征扩散\"这一基础概念的理解，需要记忆并解释由本征热缺陷导致的粒子迁移机制，属于基本原理的记忆性知识。 | 难度: 在简答题的基础概念记忆题型中，该题目仅要求回答\"空位由本征热缺陷产生\"这一基本定义，不需要进行概念解释或复杂体系阐述。属于最基础的定义简答级别，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1833, + "question": "Glass has the following general properties: (15)", + "answer": "Continuous change in properties during transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对玻璃的一般性质进行描述，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查玻璃的一般性质，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要学生回忆并表述玻璃的基本特性，但不需要进行复杂的体系阐述或多概念整合。题目要求的是对\"continuous change in properties during transformation\"这一特定性质的描述，属于基础概念记忆层次中的中等难度，比单纯的定义简答(等级1)要求更高一些，但尚未达到需要系统阐述多个相关概念的等级3难度。" + }, + { + "idx": 1834, + "question": "What are the two components of the activation energy for intrinsic diffusion?", + "answer": "Vacancy formation energy and particle migration energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释内在扩散的激活能的两个组成部分，需要用文字进行简要回答，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查对激活能组成部分的基础概念记忆和理解，属于基本原理的记忆性知识 | 难度: 在简答题中属于中等难度，需要解释和描述两个关键概念（空位形成能和粒子迁移能），但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 1835, + "question": "What factors primarily determine the concentration of component defects?", + "answer": "Doping amount", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释决定组分缺陷浓度的主要因素，需要文字解释和论述，而不是从选项中选择或简单判断对错 | 知识层次: 题目考查的是对组分缺陷浓度决定因素的基本概念记忆和理解，属于材料科学中缺陷化学的基础知识范畴。 | 难度: 在简答题题型中，该题目仅要求回答\"掺杂量\"这一基本定义，属于最基础的概念记忆层面。题目不需要解释或描述概念，更不需要阐述复杂体系，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最简单直接的记忆性知识考查。" + }, + { + "idx": 1837, + "question": "What is the relationship between the diffusion coefficient of intrinsic diffusion and temperature?", + "answer": "D=D0exp(-(ΔHf/2 + ΔHm)/RT)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释扩散系数与温度之间的关系，答案给出了具体的公式表达式，需要文字解释和论述来阐明这个关系 | 知识层次: 题目涉及扩散系数与温度关系的公式应用，需要理解扩散激活能的概念，并将ΔHf和ΔHm与温度关联起来。虽然公式本身可以直接套用，但需要理解其物理意义和推导过程，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解扩散系数与温度的关系，并能够正确写出阿伦尼乌斯方程形式的扩散系数表达式。虽然涉及多个概念（ΔHf、ΔHm、R、T等），但主要是对公式的记忆和应用，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1838, + "question": "What factors does the concentration of component defects mainly depend on?", + "answer": "Solid solubility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释影响组分缺陷浓度的因素，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对组分缺陷浓度影响因素的基础概念记忆，主要涉及固溶度这一基本原理的理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答\"component defects浓度主要取决于什么因素\"，答案只需给出\"Solid solubility\"这一基本定义即可，不需要进行概念解释或复杂体系阐述。这完全符合等级1\"基本定义简答\"的标准，属于该题型下最简单的难度级别。" + }, + { + "idx": 1839, + "question": "What are the four main mass transfer mechanisms in sintering?", + "answer": "(23) Evaporation-condensation mass transfer; (24) Diffusion mass transfer; (25) Flow mass transfer; (26) Dissolution-precipitation mass transfer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举烧结过程中的四种主要传质机制，答案以文字形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查烧结过程中四种主要传质机制的记忆和分类，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题中属于基本定义简答，仅需回忆并列举四种主要的烧结传质机制，无需深入解释或复杂论述。题目考查的是基础概念的记忆能力，不涉及概念间的关联或复杂体系阐述。" + }, + { + "idx": 1840, + "question": "What is the relationship between △L/L and sintering time in the mass transfer process?", + "answer": "(29) △L/L∝t", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释烧结过程中△L/L与时间的关系，需要文字论述和解释，答案虽然给出了比例关系，但需要理解其背后的物理意义和推导过程。 | 知识层次: 题目涉及烧结过程中质量传递的基本关系，需要理解△L/L与时间t之间的比例关系，并能够应用这一原理进行分析。虽然不涉及复杂的计算或深度推理，但需要对概念进行关联和综合理解，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及烧结过程中的质量传递概念，但只需要学生理解并说明△L/L与烧结时间t之间的比例关系（△L/L∝t），不需要进行多角度或深度关联性分析。解题步骤相对简单，主要考察学生对基本概念的理解和应用能力。" + }, + { + "idx": 1841, + "question": "What is the relationship between △L/L and sintering time in the evaporation-condensation mass transfer process?", + "answer": "(27) △L/L=0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释△L/L与烧结时间在蒸发-凝聚传质过程中的关系，需要文字论述而非简单选择或判断 | 知识层次: 题目涉及烧结过程中蒸发-凝聚传质机制的理解，需要将质量转移过程与烧结时间的关系进行概念关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解蒸发-凝聚传质过程的基本原理，并能够分析烧结时间与尺寸变化率（△L/L）之间的关系。虽然题目涉及多步计算和概念关联，但答案较为直接，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1842, + "question": "What is the relationship between △L/L and sintering time in the dissolution-precipitation mass transfer process?", + "answer": "(30) △L/L∝t^(1/3)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释△L/L与烧结时间的关系，答案给出了一个比例关系式，需要文字解释和论述来支持这个结论。 | 知识层次: 题目涉及溶解-沉淀传质过程中△L/L与烧结时间的关系，需要理解并应用t^(1/3)的幂律关系。这属于中等应用层次，因为它需要将理论知识与实际烧结过程关联起来，并进行一定的综合分析，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在简答题中属于中等难度，需要理解溶解-沉淀传质过程的基本原理，并能将烧结时间与尺寸变化关系进行综合分析。虽然涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1847, + "question": "Connection rule", + "answer": "Connection rule: In a ternary system, if the boundary (or its extension) between two adjacent phase regions (primary crystallization regions) intersects with the corresponding connecting line (or its extension), then this intersection point is the temperature maximum on that boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释\"Connection rule\"的定义和应用，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求理解和应用三元系统中的连接规则，涉及相区边界和连接线的交点判断，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于较高难度。题目要求解释三元系统中的连接规则，并说明边界与连接线交点的温度最大值的意义。这需要学生不仅理解三元相图的基本概念，还需要能够综合分析相边界和连接线的关系，并解释其热力学含义。解题步骤涉及多步逻辑推理和概念关联，属于需要多角度分析论述的题目。" + }, + { + "idx": 1849, + "question": "Sintering", + "answer": "Sintering: A process in which one or more solid powders are formed and then heated to a certain temperature, causing them to shrink and become a dense, hard sintered body below the melting point temperature. Alternatively: Due to the mutual attraction of molecules (or atoms) in solids, heating causes the powder particles to bond, and through material migration and diffusion, the powder gains strength, leading to densification and recrystallization—this process is called sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Sintering\"这一概念进行详细的文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对烧结（Sintering）这一基本概念的记忆和理解，要求解释其定义和基本原理，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对\"Sintering\"进行定义和基本原理的解释，虽然需要一定的记忆和理解，但不需要复杂的体系阐述或多步骤分析。属于该题型中中等偏基础的难度水平。" + }, + { + "idx": 1850, + "question": "To inhibit grain growth, 0.1% grain growth inhibitor is added. If the holding time is also 2h, what is the grain size?", + "answer": "d2=16μm(D3=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要应用给定的公式（d2=16μm(D3=kt)）进行数值计算，以确定晶粒尺寸，属于典型的计算题类型。 | 知识层次: 题目主要涉及基本公式的直接应用（D3=kt）和简单计算，不需要多步推理或综合分析，属于基础知识的简单应用层面。 | 难度: 在计算题中属于最简单难度，只需要直接套用单一公式（D3=kt）进行数值计算，无需任何公式组合或复杂步骤。题目中所有参数都已给出，计算过程仅涉及基本代数运算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 1851, + "question": "Calculate the four structural parameters Z, R, X, and Y of the glass Na2O·CaO·Al2O3·2SiO2", + "answer": "1.Z=4; R=9/4=2.25; X=0.5; Y=3.5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算玻璃的四个结构参数Z、R、X和Y，答案给出了具体的数值计算结果，解答过程需要应用相关公式和数值计算。 | 知识层次: 题目要求计算玻璃的四个结构参数，涉及多步计算和概念关联，需要理解结构参数的定义及其相互关系，并进行综合分析。虽然不涉及复杂的推理分析或机理解释，但比简单应用更复杂。 | 难度: 在计算题中属于综合性计算问题，需要掌握玻璃结构参数的计算方法，涉及多个步骤的公式应用和数值计算，包括Z、R、X、Y四个参数的综合求解，但未达到复杂多变量计算的难度水平。" + }, + { + "idx": 1852, + "question": "Write the solid solution formula corresponding to 20mol% YF3 doped into CaF2", + "answer": "Ca0.8Y0.2F2.2, Ca0.7Y0.2F2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出固溶体的化学式，需要根据掺杂比例进行化学式的推导和书写，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解固溶体的概念，并能够根据掺杂比例进行多步计算，推导出正确的化学式。这涉及到对固溶体形成机制的理解以及化学计量学的应用，属于中等难度的应用题目。 | 难度: 在简答题中属于中等难度，需要理解固溶体的概念并正确应用电荷平衡原则进行计算。题目要求将20mol% YF3掺杂到CaF2中，需要考虑到Y3+取代Ca2+时的电荷补偿问题，并正确写出固溶体的化学式。虽然涉及多步计算和概念关联，但解题步骤相对明确，属于中等应用层次的要求。" + }, + { + "idx": 1853, + "question": "From the perspective of crystal chemistry, discuss the rationality of the defect reaction equation for doping 20mol% YF3 into CaF2", + "answer": "From the viewpoint of crystal chemistry, the substitution of Y3+ for Ca2+ will generate cation vacancies or interstitial fluoride ions to maintain electrical neutrality, both of these defect reactions are reasonable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从晶体化学的角度讨论掺杂YF3到CaF2中的缺陷反应方程的合理性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从晶体化学的角度讨论掺杂YF3到CaF2中的缺陷反应方程的合理性，涉及离子取代、电荷平衡和缺陷类型的综合分析。这需要深入理解晶体化学原理，能够分析不同缺陷反应的可能性及其对电中性的影响，属于较高层次的推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求从晶体化学角度分析掺杂缺陷反应方程的合理性，涉及离子取代、电荷平衡和缺陷类型等机理的深度解释。虽然不需要全面分析复杂现象（如多种缺陷相互作用或动力学过程），但需要综合运用晶体化学原理进行推理分析，因此属于机理深度解释的等级4难度。" + }, + { + "idx": 1854, + "question": "Try to write the defect reaction equation for 20mol% YF3 doped into CaF2", + "answer": "2.YF3→CaF2YCa*+Fi'+2FF, 2YF3→CaF22YCa*+VCa''+6FF", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求写出掺杂缺陷反应方程，需要理解缺陷化学的基本原理，并能够应用这些原理来推导具体的反应方程。这涉及到多步思考和概念关联，但不需要过于复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求写出缺陷反应方程，这需要深入理解掺杂过程中的缺陷类型和电荷平衡。其次，题目涉及20mol% YF3掺杂到CaF2中，需要综合考虑掺杂浓度对缺陷反应的影响，并正确写出两种可能的缺陷反应方程。这要求考生不仅掌握基本的缺陷化学知识，还需要能够进行多步分析和综合判断。此外，题目还隐含了对电荷平衡和缺陷符号的熟练掌握，这些都是该题型中较为复杂的要求。因此，该题目在简答题中属于多角度分析论述的难度等级。" + }, + { + "idx": 1855, + "question": "A certain powder compact has an average particle size of 2μm. After sintering to the highest temperature and holding for 0.5h, the measured grain size is 10μm. If the holding time is extended to 2h, what will the grain size be?", + "answer": "d1=20μm(D2=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要应用公式（D2=kt）进行数值计算来求解最终的晶粒尺寸，属于典型的计算题类型 | 知识层次: 题目需要应用晶粒生长动力学公式(D²=kt)进行多步计算，涉及时间与晶粒尺寸的关联分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解晶粒生长动力学公式（D2=kt）并正确应用，涉及多步计算和概念关联。虽然公式本身不复杂，但需要综合分析初始条件和时间变化对晶粒尺寸的影响，属于中等应用层次的计算题。" + }, + { + "idx": 1856, + "question": "Give two examples of forming continuous substitutional solid solutions", + "answer": "PbTiO3-PbZrO3, albite-orthoclase, MgO-NiO, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两个形成连续置换固溶体的例子，答案需要提供具体的材料组合名称，属于开放式回答的简答题类型。 | 知识层次: 题目考查对连续置换固溶体基本概念的记忆和理解，仅需列举实例，无需深入分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求列举两个形成连续置换固溶体的例子，属于基础概念记忆层面的简单回答。不需要进行概念解释或复杂体系阐述，仅需回忆并列举相关实例即可完成作答，因此属于该题型内最低难度等级。" + }, + { + "idx": 1857, + "question": "For an AB-type compound crystal with a face-centered cubic structure, the molecular weight of the AB compound is 26, and its measured density is 2.6g/cm3. Based on this, calculate the unit cell parameter of the AB crystal.", + "answer": "The number of formula units per unit cell Z=4, the number of AB molecules in 1mol is 2.6/26×N0=6.02×1022; the number of unit cells=6.02/4×1022=1.5×1022; 1.5×1022V=1.5×1022a3=1021nm3, thus a=0.41nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的分子量和密度计算晶胞参数，解答过程涉及数值计算和公式应用，最终给出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括分子量的计算、单位晶胞中分子数的确定、单位晶胞体积的计算等，涉及多个概念的综合应用和关联分析。虽然不需要复杂的推理或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、分子量计算、单位晶胞参数推导等多步骤计算过程，同时涉及阿伏伽德罗常数等概念的综合运用，解题步骤较为复杂但未达到多变量计算的程度。" + }, + { + "idx": 1859, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, how many octahedral voids are there?", + "answer": "There are a total of 4 octahedral voids in the NaCl unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求回答一个具体的问题，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对NaCl晶胞中八面体空隙数量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要理解面心立方紧密堆积结构中的空隙类型及其数量，并能够准确描述NaCl晶胞中的八面体空隙数量。虽然不涉及复杂的概念体系阐述，但需要一定的概念解释和描述能力。" + }, + { + "idx": 1860, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, how many tetrahedral voids are there?", + "answer": "There are a total of 8 tetrahedral voids in the NaCl unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求回答一个具体的问题，答案是一个明确的数值，不需要从多个选项中选择，也不涉及判断对错或复杂的计算过程。 | 知识层次: 题目考查对NaCl晶胞中四面体空隙数量的记忆性知识，属于基础概念的记忆和理解范畴，不需要复杂的计算或分析。 | 难度: 在简答题中属于中等难度，需要理解并解释面心立方紧密堆积结构中四面体空隙的数量，涉及对晶体结构基本概念的记忆和简单应用，但不需要复杂的推导或阐述。" + }, + { + "idx": 1861, + "question": "What is martensitic transformation?", + "answer": "Martensitic transformation refers to a phase transformation that occurs at an extremely rapid speed through the shear of a discrete volume of a crystal under the action of external stress. Martensitic transformation is one of the basic forms of solid-state phase transformations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“马氏体转变”进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查基本概念的记忆和理解，主要涉及马氏体相变的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答马氏体相变的基本定义，属于最基础的概念记忆性知识。题目不涉及复杂解释或体系阐述，仅需简单描述相变的特征和基本形式，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1862, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, where are the tetrahedral void positions located?", + "answer": "In the NaCl unit cell, the tetrahedral voids are located along the body diagonal direction of the unit cell. They are formed by the corner Cl- ions and the point Cl- ions in the three adjacent edges, constituting the tetrahedral voids, which are also the centers of the 8 small cubes. There are a total of 8 tetrahedral voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释NaCl晶胞中四面体空隙的位置，答案提供了详细的文字描述和位置说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对NaCl晶胞中四面体空隙位置的基础概念记忆和理解，属于晶体结构中的基本知识点，不需要复杂的计算或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释NaCl面心立方密堆积结构中四面体空隙的位置，需要学生对晶体结构的基本概念有一定的理解和记忆，并能进行清晰的文字描述。虽然涉及多个离子位置关系的描述，但不需要复杂的推导或体系阐述，属于中等难度的概念解释题。" + }, + { + "idx": 1863, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, where are the octahedral void positions located?", + "answer": "In the NaCl structure, Cl- forms a face-centered cubic close packing, and Na+ occupies all the octahedral voids. The positions of the octahedral voids include one at the center of the unit cell, and the midpoint of each edge is also an octahedral void position, totaling 12. The number of such voids belonging to this unit cell is 12 × 1/4 = 3. Therefore, there are a total of 4 octahedral voids in the NaCl unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释NaCl单位晶胞中八面体空隙的位置，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释NaCl结构中八面体空隙的位置，并计算其数量。这需要理解面心立方紧密堆积结构、八面体空隙的定义，以及如何计算单位晶胞中的空隙数量。虽然涉及基础概念，但需要将这些概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解面心立方紧密堆积结构中的八面体空隙位置，并进行简单的计算和解释。虽然涉及多步计算和概念关联，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 1864, + "question": "Briefly describe the crystallographic characteristics of martensitic transformation.", + "answer": "The crystallographic characteristics of martensitic transformation include: a strict orientation relationship between the new phase and the parent phase during the transformation, maintenance of a coherent relationship through shear, the presence of a habit plane that remains undistorted and unrotated before and after the transformation, and macroscopic continuity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体相变的晶体学特征，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述马氏体相变的晶体学特征，涉及多个概念（如取向关系、共格关系、惯习面等）的关联和综合分析，需要理解这些特征之间的相互作用和整体表现，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对马氏体相变的晶体学特征进行多角度分析论述，包括新相与母相的取向关系、剪切过程中的共格关系、习惯面的特性以及宏观连续性等。这些内容需要综合多个概念并进行深入解释，属于该题型内较高难度的题目。" + }, + { + "idx": 1865, + "question": "What is grain growth?", + "answer": "Grain growth is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution. Within the bulk, grain sizes grow uniformly, and pores remain at grain boundaries or grain boundary junctions during grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"grain growth\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对晶粒生长这一基本概念的定义和特征的理解，属于基础概念记忆范畴，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"grain growth\"的定义和基本过程，需要学生理解并描述材料科学中的这一基础概念，但不需要进行复杂的体系阐述或深入分析。这比单纯的定义简答(等级1)要求更高一些，但尚未达到需要阐述复杂概念体系(等级3)的程度。" + }, + { + "idx": 1866, + "question": "What causes secondary recrystallization?", + "answer": "The causes of secondary recrystallization: uneven particle size of the raw material, excessively high sintering temperature, and too fast sintering rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释二次再结晶的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解二次再结晶的原因，并分析材料不均匀性、烧结温度和速率等因素的影响，涉及多个概念的关联和综合分析。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求解释和论述二次再结晶的原因，但答案涉及的因素（原料颗粒大小不均、烧结温度过高、烧结速率过快）相对明确且直接关联，不需要进行多角度或深度关联性分析。解题步骤主要是列举和简要解释已知的因果关系，属于综合分析说明的范畴，但尚未达到需要多角度论证或深度关联其他概念的复杂程度。" + }, + { + "idx": 1867, + "question": "What are the methods to prevent secondary recrystallization?", + "answer": "Methods to prevent secondary recrystallization: control sintering temperature, sintering time, control the uniformity of raw material particle size, introduce sintering additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举防止二次再结晶的方法，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目要求列举防止二次再结晶的方法，涉及对材料加工过程中温度、时间、原料均匀性和添加剂等参数的控制，需要理解二次再结晶的机理及其影响因素，并进行综合分析。这超出了基础概念的记忆，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明多个防止二次再结晶的方法，包括控制烧结温度、烧结时间、原料颗粒均匀性以及引入烧结添加剂等。虽然涉及多个概念，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 1868, + "question": "What is secondary recrystallization?", + "answer": "Secondary recrystallization is an abnormal growth process where a few large grains grow at the expense of fine grains, representing the abnormal growth of individual grains. During secondary recrystallization, pores are enclosed within the grains, and it is also related to the particle size of the raw material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary recrystallization\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查的是对二次再结晶这一基本概念的记忆和理解，包括其定义、特征和影响因素，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释次级再结晶的定义及其相关特征，涉及对基础概念的理解和描述，但不需要复杂的体系阐述或多步骤推理。属于该题型内中等偏下的难度水平。" + }, + { + "idx": 1869, + "question": "Among the seven crystal systems, the number of crystal systems belonging to the highest crystal category is A.1 B.2 C.3 D.4", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案 | 知识层次: 题目考查对晶体系统分类的基础概念记忆，只需知道最高晶系的数量即可作答，不涉及复杂分析或应用。 | 难度: 在选择题中属于简单难度，仅需直接记忆七种晶系中属于最高晶系的数目（立方晶系1个），无需理解或辨析其他概念。" + }, + { + "idx": 1870, + "question": "The crystal structure with point group L6L27PC belongs to the crystal system. A. Cubic B. Hexagonal C. Tetragonal D. Orthorhombic", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体结构点群和晶系分类的基础概念记忆，属于直接套用已知知识的选择题 | 难度: 在选择题中属于中等偏下难度，需要理解点群符号的含义并对应到正确的晶系分类，但不需要复杂的分析或计算。" + }, + { + "idx": 1871, + "question": "Kaolinite belongs to the silicate of . A. Chain structure B. Layered structure C. Framework structure D. Island structure", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对高岭石（Kaolinite）所属硅酸盐结构类型的基础概念记忆，属于对材料分类的基本知识点的直接考察。 | 难度: 在选择题中属于简单难度，题目直接考察高岭石的结构类型，属于基础概念的记忆性知识，无需复杂分析或概念辨析，只需识别正确答案即可。" + }, + { + "idx": 1872, + "question": "The crystal structure of diamond is , and the coordination number of carbon atoms is A. face-centered cubic lattice B. simple cubic lattice C. body-centered cubic lattice D. 3 E. 4 F. 6 G. 8", + "answer": "A, E", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案由选项字母组成。 | 知识层次: 题目考查对金刚石晶体结构和碳原子配位数的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏易难度，需要理解金刚石的晶体结构类型和配位数的基本概念，并进行简单辨析。虽然涉及两个知识点（晶体结构和配位数），但都是基础概念记忆层面的内容，不需要复杂的分析或深度理解。" + }, + { + "idx": 1873, + "question": "Most solid-phase reactions fall into A. Chemical reaction kinetics range B. Diffusion kinetics range C. Transition range", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个选项中选择最合适的答案，符合选择题的特征 | 知识层次: 题目考查对固相反应动力学范围分类的基本概念记忆，属于基础知识的直接应用。 | 难度: 在选择题中属于中等偏下难度，需要理解固体相反应的基本分类概念，并能区分化学动力学和扩散动力学的适用范围。虽然不涉及复杂计算，但需要对基础概念有一定理解才能正确选择。" + }, + { + "idx": 1874, + "question": "When water-based substances melt into a liquid state, their volume undergoes the phenomenon of . A. expansion B. contraction C. no change", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查对水基物质熔化时体积变化现象的基础概念记忆，属于基本原理的记忆性知识，无需复杂分析或计算。 | 难度: 在选择题中属于简单难度，仅需直接记忆水基物质融化时的体积变化现象（收缩），无需进行概念辨析或复杂理解。" + }, + { + "idx": 1875, + "question": "At low temperatures, the diffusion that generally occurs in solid materials is A. Intrinsic diffusion B. Extrinsic diffusion C. Random diffusion", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个选项（A. Intrinsic diffusion, B. Extrinsic diffusion, C. Random diffusion）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对固体材料中扩散类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题中属于中等偏下难度，需要理解低温和扩散类型的基本概念，并进行简单辨析。题目考察的是对\"extrinsic diffusion\"在低温条件下的典型特征的记忆和理解，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 1876, + "question": "Among the following types of crystals, the order of forming interstitial solid solutions is A. zeolite > CaF2 > TiO2 > MgO B. MgO > TiO2 > CaF2 > zeolite C. CaF2 > TiO2 > MgO > zeolite D. TiO2 > MgO > CaF2 > zeolite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的晶体形成间隙固溶体的顺序，答案形式为选项编号，符合选择题的特征。 | 知识层次: 题目考查对晶体形成间隙固溶体顺序的基础概念记忆，属于对基本原理的记忆性知识，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要对晶体形成间隙固溶体的基本原理有一定理解，并能对不同晶体类型的间隙固溶能力进行简单辨析。题目涉及多个晶体类型的比较，但选项排列规律性较强，正确答案A的排序符合晶体结构开放程度的基本规律（沸石>CaF2>TiO2>MgO），有一定材料科学基础的考生可以通过排除法得出正确答案。" + }, + { + "idx": 1877, + "question": "Substances that easily form glass often have bond types such as . A. Ionic bond B. Metallic bond C. Polar covalent bond D. Covalent bond", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对玻璃形成物质键型的基础概念记忆和理解，属于材料科学中关于键型分类的基本知识点 | 难度: 在选择题中属于中等难度，需要理解玻璃形成物质与键合类型之间的关系，并对不同键合类型进行简单辨析。虽然题目涉及基础概念记忆，但需要一定的理解能力来区分极性共价键与其他键合类型的区别。" + }, + { + "idx": 1878, + "question": "The viscosity corresponding to the glass transition temperature Tf is A.105dPa·s B.109dPa·s C.1011dPa·s D.1013dPa·s", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择与玻璃转变温度Tf对应的粘度值，属于典型的选择题形式 | 知识层次: 题目考查玻璃转变温度Tf对应的粘度值这一基础概念的记忆，属于定义性知识的直接回忆。 | 难度: 在选择题中属于简单难度，仅需直接记忆玻璃转变温度对应的粘度值即可选出正确答案，无需复杂理解或分析。" + }, + { + "idx": 1879, + "question": "When a small amount of CaO is doped into ThO2, write the possible defect reaction equation (7)", + "answer": "7) CaO → CaTh'' + O0 + V0''", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出可能的缺陷反应方程式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求写出掺杂CaO到ThO2中的缺陷反应方程，这需要理解缺陷化学的基本原理，并能够应用这些原理来推导具体的缺陷反应。虽然不涉及复杂的计算或多步骤推理，但需要对缺陷类型和符号表示有较好的理解，并能够正确应用这些知识来写出反应方程。这超出了简单记忆或直接套用的层次，属于中等应用水平。 | 难度: 在简答题中属于中等难度，需要理解掺杂过程中的缺陷反应，并正确书写缺陷反应方程式。虽然不需要多角度分析或深度关联性分析，但仍需综合应用材料科学中的缺陷化学知识，进行一步推理和书写。" + }, + { + "idx": 1880, + "question": "Under the same system and the same degree of supercooling, the heterogeneous nucleation rate is always the homogeneous nucleation rate. A. Greater than or equal to B. Less than or equal to C. Equal to D. Not necessarily", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C、D）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对异质成核和均质成核速率比较的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解异质成核和均质成核的基本概念，并进行简单的比较分析。题目考察的是对两种成核速率关系的记忆和理解，不需要复杂的推导或深度分析。" + }, + { + "idx": 1881, + "question": "How many space groups can appear in crystal structures?", + "answer": "230", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目问的是晶体结构中可能出现的空间群数量，答案是一个具体的数字（230），不需要计算过程或选择选项，属于需要直接回答的简答题类型 | 知识层次: 题目考查对晶体结构中空间群数量的记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答一个具体的数字（230），属于最基础的定义性记忆问题。不需要任何解释、描述或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。在同类记忆性简答题中，这是最简单直接的考查方式。" + }, + { + "idx": 1882, + "question": "When a small amount of CaO is doped into ThO2, write the corresponding solid solution formula (9)", + "answer": "9) Th1-xCaxO2-x", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出相应的固溶体化学式，需要根据掺杂规则进行推导和书写，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据掺杂情况写出固溶体化学式，需要理解掺杂对晶体结构的影响，并应用缺陷化学的知识进行公式推导。这涉及到多步思考和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解掺杂的概念并正确应用电荷平衡原则来推导固溶体化学式。虽然涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1883, + "question": "What is a space group?", + "answer": "The collection of all symmetry elements in a crystal structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"space group\"进行文字解释和论述，答案是一个定义性的陈述，不需要选择、判断或计算 | 知识层次: 题目考查对空间群这一基本概念的定义和记忆，属于基础概念层次 | 难度: 在简答题题型中，该题目仅要求回答空间群的基本定义，属于最基础的概念记忆性知识。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这属于最直接、最简单的回答要求。" + }, + { + "idx": 1884, + "question": "Fick's first law can be directly applied to solve the problem of . A．steady-state diffusion B．non-steady-state diffusion C．any diffusion", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对Fick第一定律适用条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆的选择题，仅需识别Fick's first law的直接应用场景（稳态扩散），无需进行概念辨析或复杂理解，属于最简单的直接记忆型题目。" + }, + { + "idx": 1885, + "question": "When a small amount of CaO is doped into ThO2, write the possible defect reaction equation (8)", + "answer": "8) 2CaO → CaTh'' + Cai'' + 2O0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出可能的缺陷反应方程式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求写出掺杂CaO到ThO2中的缺陷反应方程，这需要理解掺杂过程中的缺陷化学原理，并能够正确应用缺陷化学的表示方法。虽然不涉及复杂的计算或综合分析，但需要将基本概念与具体情境相结合，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解掺杂反应的基本原理，并能正确写出缺陷反应方程。虽然涉及多步计算和概念关联，但题目给出了明确的掺杂条件和产物要求，降低了分析难度。" + }, + { + "idx": 1886, + "question": "When a small amount of CaO is doped into ThO2, write the corresponding solid solution formula (10)", + "answer": "10) Th1-xCa2xO2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出相应的固溶体化学式，需要根据掺杂规则进行文字和符号的组合表达，属于需要特定知识应用的简答题类型。 | 知识层次: 题目需要理解掺杂固溶体的化学式书写规则，并能够正确应用电荷平衡原理进行多步推导，属于中等应用层次。虽然不涉及复杂计算，但需要综合分析掺杂离子的价态和位置取代关系。 | 难度: 在简答题中属于中等难度，需要理解掺杂的概念并正确写出固溶体的化学式，涉及电荷平衡和原子替换的综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1887, + "question": "4. Melt is a high-energy state of matter existing above the liquidus temperature, and during the cooling process of the melt, three different phase transition processes can occur: (11), (12), and (13).", + "answer": "(11) Crystallization; (12) Vitrification; (13) Phase separation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写三个不同的相变过程，需要文字解释和论述，而不是从选项中选择或判断对错。答案形式为简短的文字描述，符合简答题的特征。 | 知识层次: 题目考查对熔体冷却过程中三种相变过程的基本概念记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题中属于中等难度，需要解释和描述三个不同的相变过程，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 1888, + "question": "Crystals have basic properties such as (1) (2) (3) and (4).", + "answer": "1) Symmetry; (2) Crystallographic homogeneity; (3) Anisotropy; (4) Self-confinement (or minimal internal energy property)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写晶体的基本性质，需要文字解释和列举具体特征，属于简答题类型 | 知识层次: 题目考查晶体基本性质的记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，此题属于基本定义简答的难度等级。题目仅要求列举晶体的四个基本性质，不需要进行概念解释或复杂阐述。回答此类问题主要依靠对基础概念的记忆，解题步骤简单直接，符合该题型下最基础的知识掌握要求。" + }, + { + "idx": 1889, + "question": "5．According to the thermodynamic theory of diffusion, the driving force of the diffusion process is", + "answer": "chemical potential gradient", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散过程的驱动力，需要文字回答，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查扩散过程驱动力的基本概念记忆，即化学势梯度，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题仅要求回答扩散过程的驱动力，属于基本定义简答。题目仅涉及单一基础概念（化学势梯度）的记忆，不需要解释或复杂阐述，符合等级1对定义性知识点的直接回忆要求。" + }, + { + "idx": 1890, + "question": "Wetting is an important behavior at the solid-liquid interface, and one of the methods to improve wetting is (16)", + "answer": "Reduce the solid-liquid interfacial energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求提供一个简短的文字答案来解释如何改善润湿行为，而不是从多个选项中选择或进行判断或计算 | 知识层次: 题目考查对润湿行为及其改善方法的基本概念记忆，仅需回答降低固液界面能这一基本原理，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答改善润湿的一种方法，即\"降低固液界面能\"，这是基础概念记忆层面的知识点，不需要进行概念解释或复杂体系阐述。同类题型中，该题仅涉及单一知识点的直接回忆，解题步骤简单，符合等级1的基本定义简答特征。" + }, + { + "idx": 1891, + "question": "5. According to the thermodynamic theory of diffusion, the condition for reverse diffusion to occur is", + "answer": "<0 or the thermodynamic factor of the diffusion coefficient is less than 0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释热力学扩散理论中反向扩散发生的条件，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断或数值计算。 | 知识层次: 题目涉及热力学扩散理论中的反向扩散条件，需要理解扩散系数的热力学因子及其与扩散方向的关系。这需要对扩散机制有深入的理解和综合分析能力，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对热力学扩散理论中的反向扩散条件进行机理深度解释，涉及热力学因子和扩散系数的复杂关系。虽然不需要全面分析复杂现象（等级5），但需要综合运用热力学和扩散理论的知识进行推理分析，属于该题型中较高难度的题目。" + }, + { + "idx": 1892, + "question": "7. Martensitic transformation has the following characteristics: (19) etc.", + "answer": "(19) Presence of habit plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举马氏体相变的特征，需要文字解释和论述，答案形式为简短的文字描述而非选择或判断 | 知识层次: 题目考查马氏体相变的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，此题属于基本定义简答的难度等级。题目仅要求回答马氏体相变的一个特征（存在惯习面），属于对基础概念的记忆性知识考查，无需深入解释或复杂阐述。" + }, + { + "idx": 1893, + "question": "Wetting is an important behavior at the solid-liquid interface, one of the methods to improve wetting is (18)", + "answer": "Changing surface roughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供一个简短但具体的答案来回答问题，而不是从多个选项中选择或进行判断。答案\"Changing surface roughness\"是一个简短的陈述，符合简答题的特征。 | 知识层次: 题目考查的是对润湿行为改善方法的简单应用，需要理解润湿的基本概念并知道改变表面粗糙度是一种改善方法，属于直接套用基础知识的范畴，不需要复杂的分析或综合。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求直接回答改善润湿行为的一种方法，即改变表面粗糙度，不需要复杂的解释或实例说明。知识点掌握深度要求较低，解题步骤简单，仅需直接套用基本概念即可回答。因此，在该题型内属于较低难度等级。" + }, + { + "idx": 1894, + "question": "7．Martensitic transformation has the following characteristics: (20) etc.", + "answer": "(20) Orientation relationship", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举马氏体相变的特征，需要文字解释和论述，答案\"(20) Orientation relationship\"是简答形式而非选择或判断 | 知识层次: 题目考查马氏体相变的基本特征之一，即取向关系，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目仅要求回答马氏体相变的一个特征（取向关系），属于最基本的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最基础的知识点考察形式。" + }, + { + "idx": 1895, + "question": "Wetting is an important behavior at the solid-liquid interface, one of the methods to improve wetting is (17)", + "answer": "Increase the surface energy of the solid (remove the adsorbed film on the solid surface)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释如何改善润湿行为，答案提供了文字解释而非选择或计算，符合简答题的特征。 | 知识层次: 题目考查对润湿行为及其改善方法的基础概念记忆，属于基本原理的记忆性知识 | 难度: 在简答题中属于中等难度，需要解释和描述改善润湿的方法，涉及对表面能和吸附膜等基础概念的理解和应用，但不需要复杂的体系阐述。" + }, + { + "idx": 1897, + "question": "8.The characteristic of reversible polymorphic transformation is: (23)", + "answer": "(23) The polymorphic transformation temperature is lower than the melting points of both crystal forms", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项编号(23)给出，符合选择题的特征 | 知识层次: 题目考查对可逆多晶型转变特征的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，虽然需要理解可逆多晶型转变的特征，但题目明确给出了关键判断标准（转变温度低于两种晶型的熔点），只需进行简单的概念辨析即可作答，不需要复杂的分析过程。" + }, + { + "idx": 1901, + "question": "What are the main mass transfer mechanisms in solid-state sintering?", + "answer": "(28) Evaporation-condensation mass transfer; (29) Diffusion mass transfer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举主要的固态烧结中的质量传递机制，答案以文字形式给出，没有选项或计算要求。 | 知识层次: 题目考查固体烧结过程中主要传质机制的基本概念记忆和理解，属于基础概念的分类和基本原理的列举。 | 难度: 在简答题题型中，该题目要求回答固体烧结过程中的主要传质机制，属于概念解释和描述的难度等级。虽然需要记忆和列举两种主要传质机制（蒸发-凝聚传质和扩散传质），但不需要深入分析或比较这些机制的复杂关系或应用场景。因此，在简答题题型中属于中等难度。" + }, + { + "idx": 1902, + "question": "What are the main mass transfer mechanisms in liquid phase sintering?", + "answer": "(30) Flow mass transfer; (31) Dissolution-precipitation mass transfer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释液相烧结中的主要传质机制，答案提供了两种机制的简要描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查液相烧结中主要传质机制的分类和基本原理，属于基础概念的记忆和理解 | 难度: 在简答题中，该题目要求解释和描述两种主要的液相烧结传质机制，属于概念解释和描述的难度等级。虽然需要记忆和区分两种机制，但并不涉及复杂的概念体系阐述或深入的分析，因此属于等级2。" + }, + { + "idx": 1905, + "question": "Glass phase separation", + "answer": "3. Glass phase separation: A homogeneous glass phase may, within certain temperature and composition ranges, separate into two mutually insoluble or partially soluble glass phases that coexist. This phenomenon is called glass phase separation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Glass phase separation\"这一现象进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对玻璃相分离这一基本概念的定义和现象描述，属于基础概念的记忆和理解层次，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释玻璃相分离的定义和基本现象，虽然需要一定的理解和记忆，但不需要深入阐述复杂的概念体系或进行多层次的论证。属于基础概念记忆范畴内的中等难度。" + }, + { + "idx": 1906, + "question": "Unit parallelepiped", + "answer": "Unit parallelepiped: In a space lattice, the parallelepiped selected according to the selection principle is called the unit parallelepiped.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Unit parallelepiped\"进行定义和解释，答案以文字论述的形式给出，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即对\"Unit parallelepiped\"的定义进行解释，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"Unit parallelepiped\"进行基本定义回答，属于最基础的概念记忆层面。题目不涉及概念的解释、描述或复杂体系的阐述，仅需要学生准确回忆并复述定义内容。在同题型内，这属于最简单的难度等级。" + }, + { + "idx": 1907, + "question": "Tangent rule", + "answer": "4. Tangent rule: Draw a tangent at a certain point on the boundary line and intersect it with the corresponding connecting line. If the intersection point lies on the connecting line, it indicates that the boundary at that point has a eutectic property; if the intersection point lies on the extension of the connecting line, it indicates that the boundary at that point has a peritectic property, and the crystalline phase farther from the intersection point is peritectically consumed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对Tangent rule进行文字解释和论述，答案提供了详细的描述和判断标准，属于简答题类型。 | 知识层次: 题目要求解释Tangent rule的应用，涉及边界线性质的判断和结晶相行为的分析，需要多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对切线规则进行多角度分析论述，不仅需要解释切线规则的基本概念，还需要结合共晶和包晶性质进行综合分析。题目涉及的知识点掌握深度要求较高，解题步骤较为复杂，需要将多个概念关联起来进行论述，因此在简答题题型中属于较高难度等级。" + }, + { + "idx": 1912, + "question": "Normal spinel structure", + "answer": "5. Normal spinel structure: It belongs to the cubic crystal system, in which oxygen ions can be regarded as arranged in cubic close packing, divalent cations A fill one-eighth of the tetrahedral voids, and trivalent cations B fill half of the octahedral voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Normal spinel structure进行文字解释和论述，答案提供了详细的描述和结构特点，符合简答题的特征。 | 知识层次: 题目考查对Normal spinel结构的基本定义和晶体学特征的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释Normal spinel structure的基本组成和排列方式，包括立方晶系、氧离子的立方密堆积排列、二价和三价阳离子占据的间隙位置等。虽然需要记忆和解释多个概念，但并不涉及复杂的概念体系阐述或深入的分析推理，因此属于中等难度。" + }, + { + "idx": 1914, + "question": "Write the defect reaction equation for the formation of a solid solution of YF3 in CaF2 (atomic weights are Y88.9, Ca40.0, F19.0)", + "answer": "2.YF3→CaF2YCa·+Fi′+2FF Ca0,8Y0,2F2,2 2YF3→CaF22YCa∗+V Ca′′+6FF Ca0,7Y0,2F2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求写出YF3在CaF2中形成固溶体的缺陷反应方程，这需要理解缺陷化学的基本原理，并能够应用这些原理来推导具体的缺陷反应。虽然不涉及复杂的计算，但需要多步的概念关联和综合分析，包括缺陷类型的选择和电荷平衡的考虑。因此，这属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求写出YF3在CaF2中形成固溶体的缺陷反应方程，这涉及到对缺陷化学的深入理解。其次，解题过程中需要综合考虑多种可能的缺陷类型（如间隙、空位、置换等），并正确写出相应的缺陷反应方程。此外，题目还涉及到原子量的计算，增加了解题的复杂性。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 1915, + "question": "When 20 mol% YF3 is added to CaF2 to form a solid solution, the experimentally measured density of the solid solution is 3.64 g/cm3, and the lattice parameter at this time is a=0.55 nm. Calculate and determine the type of this solid solution. (The atomic weights are Y 88.9, Ca 40.0, F 19.0).", + "answer": "The unit cell of the fluorite-type crystal structure contains 4 CaF2, ρ_vacancy=3.34 g/cm3; ρ_interstitial=3.65 g/cm3; ρ_interstitial is close to the measured ρ=3.65 g/cm3, so under these conditions, an interstitial solid solution is formed.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（如密度、晶格参数等）并应用公式来确定固溶体类型，答案中包含了具体的计算过程和结果比较，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度计算和比较，以及根据计算结果判断固溶体类型。这涉及到对固溶体概念的理解、密度公式的应用以及实验数据的分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算并确定固溶体类型，涉及密度计算、晶格参数应用以及固溶体类型的判断。虽然计算步骤较多，但每一步都有明确的公式和逻辑关系，属于中等应用层次的计算题。" + }, + { + "idx": 1916, + "question": "Explain the formation conditions and characteristics of structural defects in anion interstitial non-stoichiometric compounds", + "answer": "Under oxidizing atmosphere, low valence state changes to high valence state, p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释阴离子间隙非化学计量化合物的结构缺陷形成条件和特征，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求解释阴离子间隙非化学计量化合物的结构缺陷形成条件和特征，涉及氧化气氛下的价态变化和半导体类型，需要综合运用材料科学、缺陷化学和半导体物理的知识，进行机理分析和推理。 | 难度: 在简答题题型中，该题目要求对非化学计量化合物中的结构缺陷形成条件和特征进行解释，涉及氧化气氛下的价态变化和半导体类型判断。这需要综合运用材料科学、固体化学和半导体物理等多学科知识，进行机理深度解释和复杂现象全面分析。相比同题型的其他问题，该题目对知识整合能力和推理分析能力的要求更高，属于该题型内的最高难度等级。" + }, + { + "idx": 1917, + "question": "In the non-stoichiometric compound FexO, Fe3+/Fe2+=0.1. Determine the value of x in the non-stoichiometric compound FexO.", + "answer": "According to the reaction formula Fe_xO → Fe2O3 → Fe0 → 2Fe_Fe^· + V_Fe^′′ + 3O_∘; Fe_1-3y^2+ Fe_2y^3+ O, let y be the mole fraction of Fe3+, then 2y/(1-3y) = 0.1. Solving gives y = 1/23 ≈ 0.043. The value of x is 1 - y = 1 - 0.043 ≈ 0.957.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定非化学计量化合物FexO中的x值，解答过程中涉及化学反应方程式的建立和代数方程的求解，最终得出数值结果。 | 知识层次: 题目需要进行多步计算和概念关联，包括非化学计量比化合物的理解、离子价态的计算以及化学平衡的建立和求解。虽然不涉及复杂的机理或创新设计，但需要综合运用多个知识点进行中等难度的计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要理解非化学计量化合物的概念，建立反应方程式，进行多步计算和变量求解。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有过于复杂的变量或高阶数学要求。" + }, + { + "idx": 1918, + "question": "In the non-stoichiometric compound FexO, Fe3+/Fe2+=0.1. Find the vacancy concentration in the non-stoichiometric compound FexO.", + "answer": "According to the reaction formula Fe_xO → Fe2O3 → Fe0 → 2Fe_Fe^· + V_Fe^′′ + 3O_∘; Fe_1-3y^2+ Fe_2y^3+ O, let y be the mole fraction of Fe3+, then 2y/(1-3y) = 0.1. Solving gives y = 1/23 ≈ 0.043. The vacancy concentration is y/(1 + x), where x = 1 - y = 0.957, thus the vacancy concentration is 0.043 / (1 + 0.957) ≈ 2.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过化学反应公式和数学计算来确定非化学计量化合物FexO中的空位浓度，解答过程涉及建立方程、求解未知数和数值计算。 | 知识层次: 题目需要进行多步计算和概念关联，包括化学反应式的理解、摩尔分数的计算以及空缺浓度的推导。虽然不涉及复杂的机理分析或创新应用，但需要综合运用多个知识点进行中等难度的计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要理解非化学计量化合物的概念，建立反应方程式，进行多步代数计算，并最终求解空位浓度。虽然计算过程较为复杂，但步骤明确，属于该题型内中等偏上的难度水平。" + }, + { + "idx": 1919, + "question": "Briefly describe the reasons for the formation of structural defects in non-stoichiometric compounds", + "answer": "Reasons for formation: presence of variable valence elements, changes in the nature of the surrounding atmosphere.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述非化学计量化合物中结构缺陷形成的原因，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目考查非化学计量化合物中结构缺陷形成的基本原因，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求简要描述非化学计量化合物中结构缺陷的形成原因，涉及对可变价元素和周围气氛变化等基本概念的理解和解释，但不需要复杂的体系阐述或多层次分析。" + }, + { + "idx": 1920, + "question": "Explain the formation conditions and characteristics of structural defects in anion vacancy-type non-stoichiometric compounds", + "answer": "Under reducing atmosphere, high valence state changes to low valence state, n-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结构缺陷的形成条件和特征，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求解释阴离子空位型非化学计量化合物的结构缺陷形成条件和特征，涉及还原气氛下的价态变化和半导体类型转变，需要综合运用材料科学、固体化学和半导体物理的知识，进行机理分析和推理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对非化学计量化合物的结构缺陷形成条件和特征进行机理层面的深度解释。需要综合运用材料科学、缺陷化学和半导体物理等多学科知识，分析还原气氛下变价机制及其对材料性能的影响。虽然不涉及多变量交互作用的全面分析（等级5特征），但已明显超出基础概念解释层面，属于需要深入机理分析的难度等级。" + }, + { + "idx": 1921, + "question": "Explain the formation conditions and characteristics of structural defects in cation interstitial non-stoichiometric compounds", + "answer": "Under reducing atmosphere, high valence state changes to low valence state, n-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释阳离子间隙非化学计量化合物的结构缺陷形成条件和特征，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求解释阳离子间隙非化学计量化合物的结构缺陷形成条件和特征，涉及缺陷化学、半导体物理等多学科知识的综合运用，需要深入理解缺陷形成的机理及其对材料性能的影响，属于复杂分析和推理的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求对非化学计量化合物中阳离子间隙缺陷的形成条件和特征进行机理层面的深度解释。需要综合运用半导体物理、缺陷化学和热力学知识，分析还原气氛下的价态变化与半导体类型的关系，属于需要机理深度解释的等级4难度。虽然不涉及多因素交互作用的全面分析（等级5），但已超出基础概念描述层面。" + }, + { + "idx": 1922, + "question": "Explain the formation conditions and characteristics of structural defects in cation vacancy-type non-stoichiometric compounds", + "answer": "Under oxidizing atmosphere, low valence state changes to high valence state, p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释阳离子空位型非化学计量化合物的结构缺陷形成条件和特征，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释结构缺陷的形成条件和特征，涉及氧化气氛下价态变化和半导体类型的分析，需要综合运用材料科学原理进行推理和机理解释，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对非化学计量化合物中阳离子空位型结构缺陷的形成条件和特征进行全面分析。需要综合运用热力学、缺陷化学和半导体物理等多学科知识，解释氧化气氛下价态转变与半导体类型的关系。这种深度机理解释和复杂现象分析的要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 1923, + "question": "Given a powder compact with an average particle size of 5μm, after sintering for 2 hours, the neck growth rate x/r=0.1. If grain growth is not considered, how much time is needed to sinter the compact to a neck growth rate x/r=0.2 via material transport by flow?", + "answer": "The formula for material transport by flow: x/r = k r^(-1/2) t^(1/2). Substituting x/r=0.1, r=5μm, t=2h to solve for k: 0.1 = k (5)^(-1/2) (2)^(1/2), yielding k. Then substituting x/r=0.2, r=5μm, and k to solve for t: 0.2 = k (5)^(-1/2) t^(1/2), yielding t=8h. Material transport by flow requires 8h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需时间，答案中给出了具体的计算步骤和结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，需要将已知条件代入公式求解常数k，然后再用同样的公式计算新的时间。整个过程不需要多步计算或复杂的概念关联，属于简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度。题目仅需套用单一公式x/r = k r^(-1/2) t^(1/2)进行两次代入计算（先求k再求t），虽然涉及两个计算步骤，但都属于直接套用公式的简单运算，不需要多个公式组合或复杂推导。在计算题题型中，这属于典型的二级难度（简单公式应用计算）。" + }, + { + "idx": 1924, + "question": "Please explain what a perfect dislocation is", + "answer": "Perfect dislocation: The Burgers vector is an integer multiple of the lattice vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"perfect dislocation\"的概念，需要文字解释和论述，答案也是以文字形式给出定义，符合简答题的特征。 | 知识层次: 题目考查对完美位错这一基本概念的定义和记忆，属于材料科学中晶体缺陷的基础知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"perfect dislocation\"进行基本定义简答，不需要深入的解释或复杂的论述。题目直接询问定义，且答案仅需提供一个简单的陈述（Burgers vector与晶格矢量的关系），这符合等级1\"基本定义简答\"的标准。在同类题型中，这属于最基础的知识点掌握要求，解题步骤极为简单，仅需记忆性知识即可完成。" + }, + { + "idx": 1926, + "question": "Why do primitive, face-centered, and body-centered lattices exist in the cubic system, but not base-centered lattices?", + "answer": "The characteristic of the cubic system is the presence of 4L3 axes, which exist in the primitive, face-centered, and body-centered lattices of the cubic system. If a base-centered lattice were to exist in the cubic system, the 4L3 axes would not be possible in such a lattice. Therefore, the base-centered lattice does not conform to the symmetry characteristics of the cubic system and cannot exist in it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在立方晶系中存在原始、面心和体心点阵，而不存在底心点阵。答案通过文字论述和解释来回答，没有涉及选择、判断或计算。 | 知识层次: 题目需要深入理解立方晶系的对称性特征（4L3轴），并分析不同晶格类型（原始、面心、体心）如何满足这些对称性要求。同时，需要推理为什么底心晶格不符合立方晶系的对称性特征，涉及对称性原理的复杂分析和综合运用。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解立方晶系的基本特征（如4L3轴的存在），还需要分析不同晶格类型（原始、面心、体心）如何满足这些对称性特征，并推理为什么底心晶格不符合立方晶系的对称性要求。这需要综合运用晶体学知识和对称性分析能力，属于较高层次的机理解释题目。" + }, + { + "idx": 1927, + "question": "Please write the Burgers vector of the shortest unit dislocation in BCC crystals", + "answer": "BCC: a/2<111>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出BCC晶体中最短单位位错的Burgers向量，答案需要特定的知识表达（a/2<111>），属于简答题类型，不需要计算或选择。 | 知识层次: 题目考查对BCC晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆BCC晶体中最短单位位错的Burgers矢量表达式a/2<111>，无需额外解释或复杂推导，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 1928, + "question": "Given a powder compact with an average particle size of 5μm, after sintering for 2 hours, the neck growth ratio x/r=0.1. If grain growth is not considered, how much time is required to sinter the compact to a neck growth ratio x/r=0.2 through diffusion mass transport?", + "answer": "Diffusion mass transport formula: x/r = k r^(-3/5) t^(1/5). Substituting x/r=0.1, r=5μm, t=2h to solve for k: 0.1 = k (5)^(-3/5) (2)^(1/5), yielding k. Then substituting x/r=0.2, r=5μm and k to solve for t: 0.2 = k (5)^(-3/5) t^(1/5), yielding t=64h. Diffusion mass transport requires 64h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解烧结时间，涉及代入已知条件和求解未知变量，答案也是具体的数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解扩散质量传输公式并能够进行变量替换和求解。虽然不涉及复杂的机理分析或创新应用，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散质量传输公式进行多步计算，包括求解常数k和最终时间t。虽然涉及的概念和计算步骤较多，但题目提供了明确的公式和初始条件，使得解题路径相对清晰。相比更复杂的多变量计算问题，此题在计算题中属于中等难度。" + }, + { + "idx": 1929, + "question": "Please write the Burgers vector of the shortest unit dislocation in HCP crystals", + "answer": "HCP: a/3<11\\\\bar{2}0>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出HCP晶体中最短单位位错的Burgers矢量，答案需要特定的晶体学方向表示（a/3<11\\\\bar{2}0>），属于需要特定知识回答的简答题类型。 | 知识层次: 题目考查对HCP晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆HCP晶体中最短单位位错的Burgers矢量表达式a/3<11\\\\bar{2}0>，无需解释或推导过程，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 1930, + "question": "What is the difference between intrinsic diffusion and extrinsic diffusion?", + "answer": "The activation energy of intrinsic diffusion consists of both vacancy formation energy and particle migration energy, while the activation energy of extrinsic diffusion only includes particle migration energy; intrinsic diffusion dominates at high temperatures, whereas extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述内在扩散和外在扩散的区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求区分两种扩散机制并解释其激活能构成及温度依赖性，涉及概念关联和综合分析，需要理解扩散机制的基本原理并能够进行比较分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解并解释两种扩散机制的区别，包括激活能量的组成和温度依赖性的差异。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1931, + "question": "Compare the similarities between solid-phase sintering and liquid-phase sintering", + "answer": "The similarities between solid-phase sintering and liquid-phase sintering: the driving force for sintering is surface energy in both cases, and the sintering process consists of stages such as particle rearrangement, pore filling, and grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种烧结过程的相似之处，答案以文字解释和论述的形式呈现，没有选项、判断对错或数值计算的需求。 | 知识层次: 题目要求比较两种烧结过程的相似性，涉及对烧结驱动力和阶段的理解和关联分析，需要综合运用多个知识点进行比较和论述，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较两种烧结过程的相似性，但答案已经提供了明确的相似点（驱动力和烧结阶段），并且这些相似点属于材料科学中的基础概念。解题步骤相对直接，只需列举和简要解释这些相似点，不需要进行多角度或深度关联性分析。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 1932, + "question": "Please explain what is a partial dislocation", + "answer": "Partial dislocation: The Burgers vector is not an integer multiple of the lattice vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释部分位错的概念，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对部分位错（partial dislocation）这一基本概念的定义记忆和理解，不涉及复杂计算或综合分析，仅需掌握其基本特征即可回答。 | 难度: 在简答题题型中，该题目仅要求回答部分位错的基本定义，即Burgers向量与晶格向量的关系。这属于最基础的概念记忆，不需要额外的解释或复杂论述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1933, + "question": "How does the thermal motion of atoms affect diffusion?", + "answer": "The enhancement of thermal motion will increase the jump distance, jump probability, and jump frequency of atoms, thereby increasing the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释热运动如何影响扩散，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释原子热运动对扩散的影响，涉及多个概念（热运动、扩散系数、跳跃距离等）的关联和综合分析，需要理解扩散机制并应用相关知识进行解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及热运动对扩散的影响，但答案只需要解释热运动如何通过增加原子的跳跃距离、跳跃概率和跳跃频率来提高扩散系数。这需要理解基本概念并进行简单的综合分析，但不需要多角度或深度关联性分析。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 1935, + "question": "How to distinguish between hot deformation and cold deformation of metals?", + "answer": "It is distinguished based on the relationship between the deformation temperature and the recrystallization temperature. Deformation above the recrystallization temperature is hot deformation, and vice versa is cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来区分金属的热变形和冷变形，答案提供了详细的解释而非选择、判断或计算。 | 知识层次: 题目考查对金属热变形和冷变形的基本定义和分类的记忆和理解，涉及基本原理（再结晶温度）的应用，但不需要复杂的分析或综合。 | 难度: 在简答题题型中，该题目仅要求回答基本定义和分类标准，属于最基础的概念记忆层次。题目仅涉及\"热变形\"和\"冷变形\"两个概念的区分标准（再结晶温度），不需要展开解释或论述相关原理，解题步骤简单直接，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1936, + "question": "Please write the Burgers vector of the shortest unit dislocation in an FCC crystal", + "answer": "FCC: a/2<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出FCC晶体中最短单位位错的Burgers矢量，答案需要特定的符号表示（a/2<110>），属于需要特定知识回答的简答题形式，不需要计算或选择。 | 知识层次: 题目考查对FCC晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，此题属于基本定义简答级别。题目仅要求写出FCC晶体中最短单位位错的Burgers矢量，不需要进行概念解释或复杂体系阐述。这是晶体学中最基础的记忆性知识，属于该题型内最简单的难度等级。" + }, + { + "idx": 1937, + "question": "It is known that atomic radius is related to crystal structure. When the coordination number decreases, how does the atomic radius change? Why?", + "answer": "The radius contracts. If the radius remains unchanged, a decrease in coordination number would cause an increase in crystal volume. To minimize volume change, the atomic radius will contract.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要文字解释和论述原子半径如何随配位数变化及其原因，答案提供了详细的解释而非选择或判断。 | 知识层次: 题目不仅要求理解原子半径与配位数之间的关系，还需要解释为什么配位数减少会导致原子半径收缩，涉及晶体体积变化的机理分析。这需要综合运用材料科学中的晶体结构和原子半径概念，进行推理和解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对原子半径与配位数关系的机理进行深度解释，涉及晶体结构变化对原子半径的影响机制。虽然不需要全面分析复杂现象，但需要综合运用晶体学和原子半径的知识，进行推理分析并给出合理的机理解释，因此属于机理深度解释的等级4难度。" + }, + { + "idx": 1938, + "question": "Discuss the conditions and characteristics of dissolution-precipitation mass transfer", + "answer": "The conditions for dissolution-precipitation mass transfer are: a considerable amount of liquid phase, high solubility of the solid phase in the liquid phase, and the liquid phase can wet the solid phase; the characteristics are: dissolution at particle contact points and deposition on flat surfaces, dissolution of small grains and deposition on large grains, and the mass transfer process is also a grain growth process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求讨论溶解-沉淀传质的条件和特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求讨论溶解-沉淀传质的条件和特征，涉及多个概念的综合分析，如液相条件、固相溶解性、润湿性等，以及传质过程的特征描述。这需要理解并关联多个知识点，进行中等程度的分析和应用。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求讨论溶解-沉淀传质的条件和特征，涉及多个概念的综合分析，如液相的存在、固相的溶解度、润湿性等条件，以及溶解和沉积的具体特征。虽然需要一定的概念关联和综合分析能力，但题目并未要求深入的多角度分析或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 1939, + "question": "Homogeneous nucleation and heterogeneous nucleation have the same critical nucleus radius, and the critical nucleation work for heterogeneous nucleation is also equal to one-third of the surface energy. Why is heterogeneous nucleation easier than homogeneous nucleation?", + "answer": "Because in heterogeneous nucleation, impurities or mold cavities act as part of the nucleus. That is to say, fewer atoms need to be mobilized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要文字解释和论述，说明为什么异相成核比均相成核更容易，答案也是以文字解释的形式给出，没有涉及计算或选择。 | 知识层次: 题目需要解释为什么异质成核比均质成核更容易，涉及临界核半径和成核功的概念，以及杂质或模具空腔在成核过程中的作用。这需要综合运用多个概念，进行推理分析和机理解释，属于复杂分析层次。 | 难度: 在简答题 - 需要文字解释和论述的题型中，该题目属于机理深度解释的难度等级。题目要求解释为什么异质成核比均质成核更容易，需要综合运用表面能、临界核半径和成核功等概念，并进行推理分析。虽然题目提供了部分关键信息（如临界核半径相同、异质成核功为表面能的三分之一），但解答需要进一步解释杂质或模具空腔如何作为核的一部分，从而减少需要调动的原子数量。这种解释需要对成核机理有较深的理解，但尚未达到复杂现象全面分析的最高难度等级。" + }, + { + "idx": 1940, + "question": "For metals without phase transformation in the solid state, how to refine grain size through hot working without remelting?", + "answer": "Perform hot working to induce dynamic recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何通过热加工细化晶粒，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解热加工过程中动态再结晶的概念，并将其应用于金属晶粒细化的具体情境。这涉及对金属热加工行为和再结晶机制的综合理解，而不仅仅是基础概念的简单记忆或直接套用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及金属热加工和动态再结晶的概念，但解答相对直接，只需简要说明通过热加工诱导动态再结晶来细化晶粒尺寸。不需要多角度分析或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 1941, + "question": "For metals without phase transformation in the solid state, can the grain size be refined without remelting?", + "answer": "Yes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Yes/No），符合判断题的特征 | 知识层次: 题目需要理解金属晶粒细化的基本原理，并应用这些知识来判断在没有固态相变的情况下是否可以通过其他方法（如塑性变形、热处理等）细化晶粒。这涉及到对材料科学中晶粒细化机制的综合理解，而不仅仅是基础概念的记忆。 | 难度: 在判断题中属于较高难度，需要综合分析金属固态相变和晶粒细化工艺的知识。题目涉及对无固态相变金属的晶粒细化方法的理解，需要考生掌握塑性变形、再结晶等冷加工工艺原理，并能判断这些方法是否属于非重熔工艺。这比简单的概念正误判断（等级3）要求更高的知识整合能力。" + }, + { + "idx": 1942, + "question": "In an FCC crystal, does the dislocation reaction a/2[10-1] + a/6[-121] → a/3[11-1] satisfy the energy condition?", + "answer": "Energy condition: |a/2√2|^2 + |a/6√6|^2 = (a²/2 + a²/6) = 2a²/3 > a²/3, the energy condition is satisfied.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以验证位错反应是否满足能量条件。答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（矢量长度计算、能量比较），并需要理解位错反应的能量条件这一概念。虽然计算本身不复杂，但需要将多个知识点关联起来进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解位错反应的能量条件，进行多步矢量计算和能量比较，涉及晶体结构和位错理论的知识综合应用。虽然计算过程明确，但需要正确应用公式和概念关联，属于中等偏上的难度。" + }, + { + "idx": 1943, + "question": "In an FCC crystal, does the dislocation reaction a/2[10-1] + a/6[-121] → a/3[11-1] satisfy the geometric conditions?", + "answer": "Geometric conditions: b1 + b2 = (1/2 - 1/6)a + (0 + 2/6)b + (-1/2 + 1/6)c = 1/3a + 1/3b - 1/3c = a/3[11-1], satisfying the geometric conditions.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个具体的陈述（位错反应是否满足几何条件）的对错，答案给出了明确的判断依据和结论，符合判断题的特征。 | 知识层次: 题目涉及FCC晶体中位错反应的几何条件判断，需要理解位错矢量的概念，进行矢量相加的计算，并验证是否满足几何条件。这属于多步计算和概念关联的中等应用层次。 | 难度: 在判断题中属于较高难度，需要综合运用晶体学知识进行多步矢量计算和几何条件验证。题目要求不仅理解位错反应的基本概念，还要准确进行矢量加减运算并判断结果是否符合几何条件。这超出了简单正误判断的范畴，属于需要综合分析的计算型判断题。" + }, + { + "idx": 1944, + "question": "For metals without phase transformation in the solid state, if not remelted, how to refine grains through cold deformation and recrystallization?", + "answer": "By performing significant cold deformation followed by recrystallization at an appropriate temperature to obtain fine grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的步骤和原理说明，符合简答题的特征。 | 知识层次: 题目考查对冷变形和再结晶过程的理解和应用，需要将多个概念（冷变形、再结晶温度、晶粒细化）关联起来进行分析，并给出合理的操作步骤。这属于中等应用层次，需要一定的综合分析能力。 | 难度: 在简答题题型中，该题目属于中等应用层次，要求考生理解冷变形和再结晶的基本概念，并能综合说明如何通过这两个步骤细化晶粒。虽然需要一定的综合分析能力，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 1945, + "question": "What is texture?", + "answer": "Texture is the phenomenon where crystal planes and orientations in a crystal tend to align uniformly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"texture\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即texture的定义和基本现象描述，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。不需要额外的解释、描述或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1946, + "question": "Compare the differences between solid-phase sintering and liquid-phase sintering", + "answer": "Differences: Due to the faster mass transfer rate by flow compared to diffusion, liquid-phase sintering has a higher densification rate and lower sintering temperature. Additionally, the rate of the liquid-phase sintering process is also related to factors such as the amount of liquid phase, its properties (viscosity, surface tension, etc.), the wetting condition between the liquid and solid phases, and the solubility of the solid phase in the liquid phase. The factors affecting liquid-phase sintering are more complex than those for solid-phase sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较两种烧结过程的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较固相烧结和液相烧结的差异，涉及对两种烧结过程的理解和对比分析，需要综合考虑质量传递速率、烧结温度、液相性质等多方面因素，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目要求对固相烧结和液相烧结进行多角度的比较分析，涉及多个关键因素如传质速率、液相性质、润湿条件和溶解度等。虽然不需要进行深度关联性分析，但需要综合多个概念并进行详细论述，属于多角度分析论述的难度等级。" + }, + { + "idx": 1947, + "question": "What is equilibrium crystallization?", + "answer": "Equilibrium crystallization refers to crystallization that occurs at a very slow rate, with sufficient diffusion in both the liquid and solid phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"equilibrium crystallization\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对equilibrium crystallization这一基本概念的定义记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。学生只需回忆并复述\"equilibrium crystallization\"的定义即可，不需要进行额外的解释、描述或复杂概念体系的阐述。这符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1948, + "question": "What is non-equilibrium crystallization?", + "answer": "Non-equilibrium crystallization refers to crystallization that occurs under conditions of relatively fast crystallization rates and insufficient diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对非平衡结晶进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查非平衡结晶的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答非平衡结晶的基本定义，属于最基础的概念记忆层面。不需要展开解释或描述相关机制，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1949, + "question": "It is known that for a certain crystal at 500°C, 1 vacancy can form for every 10^10 atoms. What is the vacancy formation energy of this crystal? (Given: the constant A=0.0539 for this crystal, Boltzmann constant k=1.381×10^-23 J/K)", + "answer": "$$ x\\\\begin{array}{c}{{c=A\\\\exp\\\\enspace\\\\big(\\\\enspace-\\\\frac{\\\\Delta E_{V}}{k T}\\\\big)}}\\\\ {{\\\\Delta E_{V}=-k T\\\\mathrm{ln}\\\\frac{c}{A}=\\\\mathrm{-\\\\enspace\\\\left[1.381\\\\times10^{-23}\\\\times\\\\enspace\\\\left(500+273\\\\right)\\\\right]\\\\enspace\\\\mathrm{ln}\\\\frac{10^{-10}}{0.0539}\\\\mathrm{\\\\scriptsize\\\\mathrm{~J}}}}}\\\\\\\\ {{=1.068\\\\times10^{-20}\\\\times17.8=1.9\\\\times10^{-19}\\\\mathrm{\\\\scriptsize{\\\\times10^{-19}}}}}\\\\\\\\ \\n $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出空缺形成能的具体数值。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用阿伦尼乌斯公式进行空位形成能的计算，涉及对数运算和单位转换，需要理解公式中各参数的含义及其相互关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解空位形成能的概念，并应用阿伦尼乌斯公式进行多步计算。题目涉及对数运算、单位转换和常数代入，但步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 1950, + "question": "What are the application conditions of the first law of diffusion?", + "answer": "The application condition of the first law of diffusion is steady-state diffusion, that is, diffusion independent of time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第一扩散定律的应用条件，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对扩散第一定律应用条件的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答第一扩散定律的应用条件，属于基础定义简答。题目不涉及复杂的概念解释或体系阐述，仅需记忆并复述基本原理即可完成作答，因此属于该题型内最低难度等级。" + }, + { + "idx": 1951, + "question": "What types of textures are included?", + "answer": "Textures include recrystallization texture and deformation texture. Among them, deformation texture further includes fiber texture and sheet texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举不同类型的纹理，答案提供了详细的文字解释和分类说明，符合简答题的特征。 | 知识层次: 题目考查对纹理类型的基本分类和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答纹理的类型，并进一步解释变形纹理的细分类型。这需要学生对基础概念有一定的记忆和理解，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目对知识点的掌握要求稍高，但尚未达到等级3的复杂概念体系阐述程度。" + }, + { + "idx": 1952, + "question": "What are the common phase structures in solids?", + "answer": "The common phase structures in solids include: solid solution (element), compound, ceramic crystalline phase, amorphous phase, and molecular phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释常见的固体相结构，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查固体中常见相结构的基本分类和定义，属于基础概念的记忆和理解范畴，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目要求列举并简要说明固体中常见的相结构，属于概念解释和描述的难度级别。虽然需要记忆多个相结构的名称，但不需要深入阐述其形成机制或相互关系，因此不属于复杂概念体系阐述的等级3。同时，由于题目明确要求列举常见相结构，相比仅回答基本定义的等级1题目，其难度略高，属于等级2。" + }, + { + "idx": 1953, + "question": "2. Please calculate the angle between (111) and (111) in a simple cubic crystal.", + "answer": "$${{\\\\cos\\\\alpha=\\\\frac{h_{1}h_{2}+k_{1}k_{2}+l_{1}l_{2}}{\\\\sqrt{h_{1}^{2}+k_{1}^{2}+l_{1}^{2}\\\\sqrt{h_{2}^{2}+k_{2}^{2}+l_{2}^{2}}}}\\\\mathrm{\\\\textstyle=\\\\frac{1-1+1}{\\\\sqrt{3}\\\\times\\\\sqrt{3}}=\\\\frac{1}{3}}}}\\\\ {{\\\\alpha=70^{\\\\circ}32^{\\\\prime}\\\\quad\\\\qquad\\\\quad}}\\\\end{array} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算简单立方晶体中(111)和(111)晶面之间的夹角，答案给出了具体的计算过程和数值结果，涉及公式应用和数值计算。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用已知的晶体学公式计算两个晶面之间的夹角。虽然需要理解晶面指数的含义和夹角公式的推导，但整体上是一个直接套用公式的计算过程，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需套用晶面夹角公式，代入(111)和(111)的晶面指数进行简单计算即可得出结果，无需额外的公式组合或复杂推导步骤。" + }, + { + "idx": 1955, + "question": "What is a substitutional solid solution?", + "answer": "An alloy phase where solute atoms replace solvent atoms while maintaining the solvent structure is called a substitutional solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"substitutional solid solution\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对置换固溶体这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆性知识。题目仅需直接回忆并复述\"substitutional solid solution\"的定义，无需进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1956, + "question": "For cases where the concentration gradient changes over time, can the first law of diffusion be applied?", + "answer": "The first law of diffusion can also be applied to non-steady-state diffusion, but it must be modified.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对非稳态扩散情况下第一扩散定律的应用进行解释和论述，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目涉及扩散第一定律在非稳态条件下的应用，需要理解定律的基本原理并能够进行概念关联和综合分析，以解释其在变化浓度梯度情况下的适用性。这超出了简单记忆或直接套用的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求对非稳态扩散情况下第一扩散定律的应用进行分析和说明，需要理解扩散定律的基本概念，并能将其扩展到变化条件下的应用。虽然题目涉及概念关联和综合分析，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 1957, + "question": "What are the factors affecting the solubility of substitutional solid solutions?", + "answer": "The influencing factors include: ①Atomic size; ②Crystal structure; ③Electronegativity; ④Electron concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响置换固溶体溶解度的因素，答案以文字解释和论述的形式呈现，没有提供选项或要求计算。 | 知识层次: 题目考查对置换固溶体溶解度影响因素的基础概念记忆和理解，主要涉及原子尺寸、晶体结构、电负性和电子浓度等基本因素的列举，不需要深入的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要列举多个影响因素，但每个因素都是基础概念记忆层面的知识点，不需要进行复杂的概念体系阐述或深入分析。题目要求的是对基本原理的记忆和简单解释，符合等级2的特征。" + }, + { + "idx": 1958, + "question": "How does constitutional supercooling affect the growth morphology of solid solutions?", + "answer": "In the absence of constitutional supercooling, the solid solution grows in a planar manner, forming equiaxed crystals; with a small degree of supercooling, cellular structures form; with a large degree of constitutional supercooling, dendritic crystals form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释constitutional supercooling对固溶体生长形态的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对constitutional supercooling如何影响固溶体生长形态的机理解释，需要理解并分析不同冷却条件下晶体生长的变化过程，属于对复杂现象的综合分析和机理解释。 | 难度: 在简答题中属于机理深度解释难度，需要理解并详细描述constitutional supercooling对固溶体生长形态的影响机制，涉及不同条件下的晶体生长模式变化，要求对材料科学中的晶体生长理论有较深入的理解和综合运用能力。" + }, + { + "idx": 1959, + "question": "What are the conditions for forming an infinite solid solution?", + "answer": "The same crystal structure of the two components is a necessary condition for forming an infinite solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释形成无限固溶体的条件，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对无限固溶体形成条件的基本概念记忆和理解，主要涉及晶体结构相同这一必要条件的知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释形成无限固溶体的条件，这需要学生对材料科学中的固溶体概念有一定理解，并能准确描述关键条件（相同晶体结构）。虽然涉及基本原理，但不需要复杂的推导或多概念整合，属于基础概念记忆层次中的中等难度。" + }, + { + "idx": 1960, + "question": "What is the difference in diffusion coefficients between substitutional diffusion and interstitial diffusion?", + "answer": "The interstitial diffusion coefficient is independent of vacancy concentration, whereas the substitutional diffusion coefficient is related to vacancy concentration (can be expressed by a formula). Generally, the interstitial diffusion coefficient is greater than the substitutional diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种扩散系数的区别，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求比较两种扩散机制的扩散系数差异，涉及对扩散机制的理解和关联分析，需要解释两者与空位浓度的关系并进行一般性比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释和比较两种扩散机制的扩散系数差异，涉及对基本概念的理解和关联分析。虽然需要综合多个知识点（如空位浓度对扩散系数的影响），但不需要进行多角度或深度关联性分析。解题步骤相对直接，主要要求对概念的理解和清晰表达。" + }, + { + "idx": 1961, + "question": "An FCC crystal yields under a normal stress of 2MPa in the [123] direction. The activated slip system has been measured as (111)[101]. Determine the resolved shear stress τ that activates this slip system.", + "answer": "$$ \\\\begin{array}{l}\\\\cos\\\\phi=\\\\frac{[\\\\overline{1}23]}{|[\\\\overline{1}23]|}\\\\cdot\\\\frac{[111]}{|[111]|}=\\\\frac{-1+2+3}{\\\\sqrt{14}\\\\sqrt{3}}=0.617\\\\\\\\ \\\\cos\\\\lambda=\\\\frac{[\\\\overline{1}23]}{|[\\\\overline{1}23]|}\\\\cdot\\\\frac{[\\\\overline{1}01]}{|[\\\\overline{1}01]|}=\\\\frac{1+0+3}{\\\\sqrt{14}\\\\sqrt{2}}=0.756\\\\end{array}$$ $$\\\\tau=2\\\\times0.617\\\\times0.756\\\\mathrm{MPa}=0.933\\\\mathrm{MPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定解析剪切应力τ，答案中包含了具体的数学计算过程和最终的计算结果。 | 知识层次: 题目需要进行多步计算，包括方向余弦的计算和剪切应力的求解，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（如方向余弦、剪切应力公式）并进行多步计算。虽然计算过程明确，但需要正确理解并关联晶体学方向和应力分解的概念，属于中等偏上的难度。" + }, + { + "idx": 1962, + "question": "In a diffusion couple, if it is interstitial diffusion, will the Kirkendall effect occur? Why?", + "answer": "It will not occur. Because interstitial diffusion considers the directional flow of interstitial atoms and does not account for substitutional diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要文字解释和论述，说明间隙扩散是否会导致Kirkendall效应及其原因，而不是简单的选择或判断。 | 知识层次: 题目不仅需要理解间隙扩散和置换扩散的基本概念，还需要分析Kirkendall效应的发生条件，并进行机理上的解释。这涉及到多个概念的关联和综合分析，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对Kirkendall效应和间隙扩散机制进行机理层面的深度解释。虽然不需要涉及多因素交互作用的全面分析（等级5特征），但需要准确理解两种扩散机制的本质区别，并能逻辑清晰地阐述间隙扩散为何不会产生Kirkendall效应。这需要将晶体缺陷理论与扩散动力学知识进行整合推理，符合等级4对机理深度解释的要求。相比只需描述现象的等级3题目更具挑战性，但尚未达到需要讨论温度/浓度梯度等多因素影响的等级5复杂度。" + }, + { + "idx": 1963, + "question": "At room temperature, a sheet of iron (with a melting point of 1538°C) is bent back and forth. What phenomenon will occur as the bending continues? Why?", + "answer": "According to T_recrystallization = (0.35–0.45)T_melting, the processing of Fe at room temperature is cold working. Therefore, as bending proceeds, the sheet undergoes work hardening, and continued deformation leads to fracture of the iron sheet.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释现象发生的原因，答案提供了详细的文字解释和论述，没有选项、计算或判断对错的要求。 | 知识层次: 题目需要理解冷加工和再结晶温度的概念，并应用公式T_recrystallization = (0.35–0.45)T_melting进行计算和判断。同时需要解释工作硬化和断裂的机理，涉及多个概念的关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解冷加工和再结晶温度的概念，并进行简单的计算和综合分析。题目要求解释现象及其原因，涉及多步推理和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1964, + "question": "Please compare the similarities between binary eutectic transformation and peritectic transformation", + "answer": "Similarities: isothermal and constant composition transformation; both appear as horizontal lines on the phase diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较二元共晶转变和包晶转变的相似之处，需要文字解释和论述，答案也是以文字形式呈现的简答形式。 | 知识层次: 题目考查对二元共晶转变和包晶转变这两个基本概念的记忆和理解，要求比较它们的相似性，属于基础概念的记忆和简单对比。 | 难度: 在简答题题型中，该题目要求对二元共晶转变和包晶转变的相似性进行比较和解释，涉及两个基本概念的理解和对比。虽然需要一定的概念记忆和解释能力，但并不需要复杂的体系阐述或多层次的分析。因此，在简答题题型中属于中等难度（等级2）。" + }, + { + "idx": 1965, + "question": "When bending a tin plate (with a melting point of 232°C) back and forth at room temperature, what phenomenon will occur as the bending proceeds? Why?", + "answer": "According to T_recrystallization=(0.35～0.45)Tm, the processing of Sn at room temperature is considered hot working. Therefore, as bending proceeds, dynamic recrystallization occurs in the Sn plate, allowing it to be bent for an extended period.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象并论述原因，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要综合运用动态再结晶理论（T_recrystallization=(0.35～0.45)Tm）和热加工概念，分析锡板在室温弯曲过程中的现象。这涉及材料科学中的相变理论、热力学计算以及微观组织演变机理的解释，属于需要深度推理分析和综合运用的复杂问题。 | 难度: 在简答题题型中，该题目要求对动态再结晶现象进行机理深度解释，需要综合运用材料科学中的热加工概念、再结晶温度计算公式以及实际应用场景分析。虽然不涉及多学科交叉或极端复杂的推导过程，但需要对材料行为有深入理解并能准确关联理论公式与实际现象，属于该题型内较高难度的机理解释类题目。" + }, + { + "idx": 1966, + "question": "What is solid solution strengthening? Please briefly describe its strengthening mechanism.", + "answer": "Solid solution strengthening is the phenomenon where solute atoms impede dislocation motion, thereby enhancing the strength of the alloy. The main mechanisms include: ① Cottrell atmosphere, where the elastic stress field of solute atoms hinders dislocation motion; ② Suzuki atmosphere, where solute atoms reduce the stacking fault energy of the matrix, causing dislocations to decompose into extended dislocations and impeding dislocation cross-slip or climb; ③ Electrical interaction, where charged solute atoms form electrostatic interactions with dislocations, hindering dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固溶强化的概念及其强化机制，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目不仅要求解释固溶强化的定义，还需要详细描述其强化机制，包括Cottrell atmosphere、Suzuki atmosphere和电相互作用等多个方面。这需要学生对相关概念有深入的理解，并能综合运用这些知识进行机理分析和解释。思维过程涉及多个知识点的关联和综合分析，属于较高层次的认知要求。 | 难度: 在简答题-需要文字解释和论述的题型中，该题目属于机理深度解释难度。题目要求不仅定义固溶强化现象，还需要详细描述其三种主要强化机制（Cottrell atmosphere、Suzuki atmosphere和Electrical interaction），这需要学生对位错理论、合金强化机理有较深入的理解，并能综合运用这些知识进行机理层面的解释。虽然不涉及多机制交互作用的复杂分析（等级5特征），但已超出基础概念解释的范畴，属于需要机理深度阐述的中高难度题目。" + }, + { + "idx": 1967, + "question": "Please compare the differences between binary eutectic transformation and peritectic transformation", + "answer": "Differences: eutectic is a decomposition-type reaction, peritectic is a synthesis-type reaction; the eutectic line is entirely a solidus line, while only part of the peritectic line is a solidus line; the eutectic triangle is above the horizontal line, the peritectic triangle is below the horizontal line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较二元共晶转变和包晶转变的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对二元共晶转变和包晶转变的基本概念和差异的记忆和理解，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较二元共晶转变和包晶转变的差异，涉及对两种相变反应类型的基本理解和描述，但不需要深入分析复杂概念体系或进行多步骤推导。答案中列举的差异点属于相图基础知识的直接应用，符合该题型对概念解释能力的要求。" + }, + { + "idx": 1968, + "question": "Please write out the crystal planes included in the {110} and {100} crystal plane families in the cubic crystal system, respectively.", + "answer": "{110}: (110) (101) (011) (110) (101) (011) {100}: (100) (010) (001) (001) (010) (100)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出立方晶系中{110}和{100}晶面族包含的具体晶面，需要列举和解释具体的晶面指数，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目考查立方晶系中晶面族的记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但需要学生准确写出立方晶系中{110}和{100}晶面族包含的所有晶面，这涉及到对晶面指数的理解和记忆。相比于简单的定义简答（等级1），该题目需要学生掌握晶面族的对称性关系，并能正确列举所有等效晶面。但相比于需要复杂概念体系阐述的题目（等级3），该题目仍属于概念解释和描述的范畴。" + }, + { + "idx": 1969, + "question": "Please compare the distortion energy of the two dislocations b1= a/2[111] and b2=a[100] in FCC crystals, which one is greater.", + "answer": "∣b₁∣=a/2√(1+1+1)=√3/2a ∣b₂∣=a√(1+0+0)=a Therefore, the distortion energy of b1 is smaller.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算两个位错的畸变能，并通过数值比较得出结果。解答过程中涉及矢量模的计算和比较，属于典型的计算题。 | 知识层次: 题目要求计算两个位错的畸变能，涉及基本的矢量模计算和公式应用，属于直接套用公式的简单计算题。 | 难度: 在计算题中属于简单公式应用计算难度，虽然需要计算两个矢量的模并进行比较，但仅涉及基本的矢量模公式和简单代数运算，无需多个公式组合或复杂推导。" + }, + { + "idx": 1970, + "question": "When CN=6, the ionic radius of Na+ is 0.097nm, what is its radius when CN=4?", + "answer": "0.088nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的离子半径和配位数变化，通过计算得出新的离子半径。答案是一个具体的数值（0.088nm），需要通过公式或经验关系进行计算得出。 | 知识层次: 题目需要应用已知的离子半径与配位数关系进行简单计算，属于基本公式的直接套用，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于最低难度，只需要直接套用单一公式（离子半径与配位数的关系公式）进行计算，无需额外的步骤或复杂的公式组合。" + }, + { + "idx": 1971, + "question": "Nickel has a face-centered cubic structure with an atomic radius of r_Ni=0.1246 nm. Determine how many atoms are present in 1 mm^2 on the (100) plane of nickel.", + "answer": "6.1×10^13 atoms/mm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及原子半径、晶面密度等材料科学计算，最终需要得出具体的数值结果（6.1×10^13 atoms/mm^2）。 | 知识层次: 题目需要应用面心立方结构的几何关系计算原子密度，涉及多步计算（晶面原子密度计算、单位面积原子数换算）和概念关联（原子半径与晶格参数的关系），但不需要复杂的综合分析或机理解释。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于综合性计算问题。解题过程需要理解面心立方结构、(100)晶面的原子排列方式，正确应用原子半径与晶格常数的关系公式，并进行单位换算和多步计算。虽然不涉及复杂变量，但需要将晶体学知识与数学计算能力综合运用，符合等级3\"综合性计算问题\"的特征。相比单纯套用公式的题目(等级2)更具综合性，但尚未达到需要处理多变量或非常规计算的等级4难度。" + }, + { + "idx": 1973, + "question": "In the <100> direction of copper (fcc, a=0.361nm), what is the linear density of atoms?", + "answer": "The linear density of Cu atoms is 2.77×10^6 atoms/mm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铜在<100>方向上的线性原子密度，需要应用晶体结构相关的公式进行数值计算，最终给出具体的数值结果。答案也是以数值形式呈现的。 | 知识层次: 题目要求计算铜在<100>方向的线性原子密度，涉及基本的晶体结构知识（fcc晶格）和简单的公式应用（线性密度计算）。虽然需要理解晶格参数和方向的概念，但计算过程直接，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用线性密度的基本公式（原子数/长度）进行计算，且铜的晶格常数和方向已经给出，无需额外的公式组合或复杂步骤。" + }, + { + "idx": 1974, + "question": "Write the equivalent crystal planes included in the crystal plane families {100}, {110}, {111}, {112} in cubic crystals.", + "answer": "{100}=(100)+(010)+(001), totaling 3 equivalent planes. {110}=(110)+(1̅10)+(101)+(1̅01)+(011)+(01̅1), totaling 6 equivalent planes. {111}=(111)+(1̅11)+(11̅1)+(111̅), totaling 4 equivalent planes. {112}=(112)+(1̅12)+(11̅2)+(112̅)+(121)+(121)+(121)+(121)+(211)+(211)+(211)+(211), totaling 12 equivalent planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出立方晶体中特定晶面族的等效晶面，答案需要列举所有等效晶面，属于需要详细解释和列举的简答题类型。 | 知识层次: 题目考查对立方晶体中晶面族等效晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要理解晶体平面家族的概念并列举出等效平面，但不需要深入分析或复杂推导。" + }, + { + "idx": 1975, + "question": "In the <100> direction of iron (bcc, a=0.286nm), what is the linear density of atoms?", + "answer": "The linear density of Fe atoms is 3.50×10^6 atoms/mm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铁在<100>方向上的线性原子密度，需要应用晶体结构参数（bcc, a=0.286nm）进行数值计算，答案给出了具体的计算结果（3.50×10^6 atoms/mm），符合计算题的特征。 | 知识层次: 题目需要应用线性密度的基本公式进行计算，涉及晶体结构参数（晶格常数）的直接套用和简单数值计算，属于基本公式应用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算<100>方向的线性密度，直接套用线性密度公式（原子数/长度）即可得出结果，无需多个公式组合或复杂推导。" + }, + { + "idx": 1977, + "question": "Determine whether the following dislocation reaction can proceed: $a[100]\\\\rightarrow\\\\frac{a}{2}[101]+\\\\frac{a}{2}[10{\\\\overline{{1}}}]$", + "answer": "No. Energy condition: $\\\\sum b_{\\\\mathbb{M}}^{2}=\\\\sum b_{E}^{2}=a^{2}$, the energy on both sides is equal.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个位错反应是否能够进行，答案直接给出了“No”的判断结果，并提供了能量条件的解释。这符合判断题的特征，即对陈述的对错进行判断。 | 知识层次: 题目需要应用位错反应的能量条件进行计算和判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在判断题中属于较高难度，需要理解位错反应的能量条件，并进行多步计算和综合分析。题目要求判断位错反应是否能进行，涉及能量守恒的计算和概念关联，比简单的正误判断更复杂。" + }, + { + "idx": 1978, + "question": "The atomic packing density of magnesium, like all hcp metals, is 0.74. Calculate the volume of the unit cell of magnesium. Given the density of Mg ρMg=1.74 Mg/m³, relative atomic mass of 24.31, and atomic radius r=0.161 nm.", + "answer": "The volume of the unit cell is Vuc=0.14 nm³ (or 1.4×10⁻²⁸ m³).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（密度、相对原子质量、原子半径）和公式（原子堆积密度与晶胞体积的关系）进行数值计算，最终得出晶胞体积的具体数值。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括原子堆积密度、密度公式应用、单位换算等综合分析，涉及对hcp结构参数的理解和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、原子质量与体积的关系，并进行单位换算。虽然计算步骤明确，但涉及多个物理量的关联和转换，属于中等偏上的难度。" + }, + { + "idx": 1979, + "question": "Nickel has a face-centered cubic structure with an atomic radius of r_Ni=0.1246 nm. Determine the number of atoms per 1 mm^2 on the (110) plane of nickel.", + "answer": "1.14×10^13 atoms/mm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定镍在(110)平面上每平方毫米的原子数，答案是一个具体的数值结果。 | 知识层次: 题目需要理解面心立方结构的几何特征，计算(110)平面的原子密度，涉及多步计算和概念关联，包括原子半径与晶格参数的关系、平面原子密度的计算等，需要综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解面心立方结构的几何关系，计算晶面间距，并应用原子密度公式进行多步计算。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有复杂变量或高级数学工具需求。" + }, + { + "idx": 1980, + "question": "Determine whether the following dislocation reaction can occur: $\\\\frac{a}{3}[112]+\\\\frac{a}{2}[111]\\\\rightarrow\\\\frac{a}{6}[11\\\\overline{{{1}}}]$", + "answer": "No. Geometric condition: $\\\\sum b_{\\\\mathbb{H}}=\\\\frac{a}{b}[557],\\\\sum b_{\\\\mathbb{H}}=\\\\frac{a}{b}[11\\\\overline{{1}}]$, cannot be satisfied.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个位错反应是否能够发生，答案直接给出了“No”的判断，并提供了几何条件的验证。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目需要应用位错反应的基本原理进行几何条件的验证，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在判断题中属于较高难度，需要综合运用位错几何条件和反应规则进行多步计算和判断。题目要求评估位错反应是否满足几何条件，涉及矢量运算和反应前后守恒性的综合分析，超出了简单正误判断的范畴。" + }, + { + "idx": 1981, + "question": "The density of quartz (SiO2) is 2.65 Mg/m3. How many silicon atoms (and oxygen atoms) are there in 1 m3?", + "answer": "5.29×10^28 silicon atoms /m3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（密度、摩尔质量等）来确定1立方米石英中硅原子和氧原子的数量，答案以具体数值形式给出。 | 知识层次: 题目需要进行基本的密度和摩尔质量计算，涉及简单的公式应用和单位转换，属于直接套用基本概念和公式的范畴。虽然需要理解硅和氧原子的比例关系，但整体思维过程较为直接，不涉及多步复杂计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算硅和氧原子的数量，需要应用密度和摩尔质量的基本公式，并进行简单的单位转换和数值计算。虽然涉及多个步骤（如计算摩尔数、应用阿伏伽德罗常数等），但所有步骤都是直接套用基本公式，没有复杂的组合或推导过程。因此，在同题型内属于等级2难度。" + }, + { + "idx": 1982, + "question": "At $800^{\\circ}\\mathrm{C}$, one atom in $10^{10}$ atoms has sufficient energy to move within the solid, while at $900^{\\circ}\\mathrm{C}$, only one atom in $10^{9}$ atoms does. Calculate the activation energy (J/atom).", + "answer": "$0.4\\times10^{-18}~\\mathrm{J}/$ atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解激活能（J/atom），答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度与激活能的关系，需要理解并关联相关概念，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，但步骤清晰且变量较少，未达到复杂多变量计算的难度。" + }, + { + "idx": 1983, + "question": "If a face-centered cubic crystal has a unit dislocation with b=a/2[1̄01] and a partial dislocation with b=a/6[121̄], these two dislocations meet and undergo a dislocation reaction. Can this reaction proceed? Why?", + "answer": "It can proceed. Because it satisfies both the geometric condition: ∑bH=∑bE=a/3[1̄11], and the energy condition: ∑bM²=2/3a²>∑bE²=1/3a².", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两个位错相遇后反应是否能够进行，并给出原因。答案提供了详细的几何条件和能量条件的分析，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及位错反应的几何条件和能量条件的综合分析，需要理解位错反应的基本原理，并能应用这些原理进行推理和判断。这要求对位错理论有较深的理解，并能将多个概念（如位错的几何条件和能量条件）结合起来进行分析，属于较高层次的认知能力。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用位错理论、晶体学知识以及能量守恒原理进行多步骤推理。具体表现为：" + }, + { + "idx": 1984, + "question": "When the radii of silicon and oxygen in quartz (SiO2) are 0.038 nm and 0.114 nm respectively, what is the packing density (assuming the atoms are spherical)?", + "answer": "0.33", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算石英的堆积密度），并给出了具体的原子半径数据，需要使用公式进行计算。答案是一个具体的数值（0.33），符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要根据给定的原子半径计算堆积密度，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算，只需要应用简单的几何公式计算原子的体积比，无需多个公式组合或复杂步骤。" + }, + { + "idx": 1985, + "question": "Determine whether the following dislocation reaction can proceed: $\\\\frac{a}{2}[10\\\\overline{{{1}}}]+\\\\frac{a}{6}[\\\\overline{{{1}}}21]\\\\rightarrow\\\\frac{a}{3}[11\\\\overline{{{1}}}]$", + "answer": "Yes. Geometric condition: $\\\\sum b_{\\\\tt H}=\\\\sum b_{\\\\tt G}=\\\\frac{\\\\alpha}{3}[11\\\\overline{{1}}]$; energy condition: $\\\\sum b_{\\\\mathbb{H}}^{2}={\\\\frac{2}{3}}a^{2}>$ $\\\\sum b_{E}^{2}={\\\\frac{1}{3}}a^{2}.$", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能够进行，答案给出了明确的判断（Yes）以及相应的几何条件和能量条件验证，符合判断题的特征。 | 知识层次: 题目需要应用位错反应的能量条件和几何条件进行判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在判断题中属于较高难度，需要综合运用几何条件和能量条件进行多步计算和综合分析，判断位错反应是否能够进行。" + }, + { + "idx": 1986, + "question": "Given the Burgers vector b=0.25 nm, if the misorientation angle θ of a symmetric tilt grain boundary is 10°, calculate the distance between dislocations at the grain boundary.", + "answer": "When θ=10°, D=1.4 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的Burgers向量和取向差角计算晶界位错间距，需要应用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目考查基本公式应用（Burgers vector与位错间距的关系公式）和简单计算，无需多步推导或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的Burgers矢量与位错间距的关系公式D=b/θ（θ以弧度表示），进行简单的单位转换和数值计算即可得出答案。不需要多个公式组合或复杂的推导过程，符合等级1的标准。" + }, + { + "idx": 1987, + "question": "Determine whether the following dislocation reaction can proceed: $a[100]\\\\rightarrow\\\\frac{a}{2}[111]+\\\\frac{a}{2}[1\\\\overline{{{11}}}]_{\\\\circ}$.", + "answer": "No. Energy condition: $\\\\sum b_{\\\\mathbb{H}}^{2}=a^{2}<\\\\sum b_{\\\\mathbb{H}}^{2}={\\\\frac{3}{2}}a^{2}$, meaning the energy increases after the reaction.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能进行，答案直接给出\"是\"或\"否\"的判断结果，并附带能量条件的解释说明。这符合判断题的特征，即对某个陈述或现象进行对错判断。 | 知识层次: 题目需要应用位错反应的能量条件进行判断，涉及多步计算和概念关联，需要综合分析位错反应前后的能量变化，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要理解位错反应的能量条件，进行多步计算（计算反应前后的位错能量），并综合分析能量变化对反应可行性的影响。这超出了简单的概念判断，需要结合计算和理论分析才能得出结论。" + }, + { + "idx": 1988, + "question": "What conclusion can be drawn from the calculation results?", + "answer": "When θ=10°, the distance between dislocations is only 5∼6 atomic spacings, indicating that the dislocation density is too high at this point. This suggests that the model is no longer applicable when the θ angle is large.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据计算结果得出结论，答案是通过文字解释和论述来回答的，没有涉及选项选择、判断对错或数值计算 | 知识层次: 题目需要根据计算结果进行分析和解释，涉及多步计算和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要基于计算结果进行综合分析并说明模型适用性的限制条件。题目要求将数值计算结果与理论模型关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1989, + "question": "Calculate the shear stress required for slip to occur in a nickel crystal with this F-R dislocation source. Given that for Ni, G=7.9×10^10 Pa, a=0.350 nm.", + "answer": "τ_Ni=1.95×10^7 Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算剪切应力），并给出了具体的材料参数（G和a）和公式应用（F-R dislocation source），答案也是一个具体的数值结果（τ_Ni=1.95×10^7 Pa）。 | 知识层次: 题目需要应用弗兰克-瑞德位错源公式进行多步计算，涉及剪切模量、晶格常数等参数的关联使用，并需要理解位错运动的基本原理，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用弗兰克-瑞德位错源公式进行多步计算，涉及剪切模量、晶格常数等参数的代入和转换，同时需要理解位错运动的基本原理。虽然计算过程明确，但需要将多个概念关联起来综合分析，属于中等偏上的难度水平。" + }, + { + "idx": 1990, + "question": "If the dislocation density in a certain crystal is known to be ρ=10^6~10^7 cm/cm^3, and the average length of F-R dislocation sources measured experimentally is 10^-4 cm, determine the number of F-R dislocation sources in the dislocation network.", + "answer": "Assuming that the dislocation lines in the crystal are entangled and mutually pinned, the possible number of dislocation sources is n= ρ/L=10^10~10^11 per cm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的数值（位错密度和平均长度）进行计算，以确定F-R位错源的数量。答案涉及数值计算和公式应用（n= ρ/L），符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的位错密度和平均长度直接计算F-R位错源的数量。虽然需要理解位错密度的概念和F-R位错源的定义，但整体上是一个直接的数值计算过程，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的公式n=ρ/L进行简单计算，无需多个公式组合或复杂的解题步骤。直接套用公式即可得出答案，属于该题型内最基础的难度水平。" + }, + { + "idx": 1991, + "question": "Given the Burgers vector b=0.25 nm, if the misorientation angle θ of the symmetric tilt grain boundary is 1°, calculate the distance between dislocations at the grain boundary.", + "answer": "When θ=1°, D=14 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的Burgers向量和错向角度计算晶界位错间距，需要应用公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用（Burgers vector与位错间距的关系公式），只需要一步计算即可得出结果，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（D = b/θ）进行简单数值计算，无需额外的公式组合或复杂步骤。" + }, + { + "idx": 1992, + "question": "If a piece of iron is heated to $850^{\\\\circ}\\\\mathrm{C}$ and then rapidly cooled to $20^{\\\\circ}\\\\mathrm{C}$, calculate how many times the number of vacancies should increase before and after the treatment (assuming the energy required to form one mole of vacancies in iron is 104600J)", + "answer": "$0.616\\\\times10^{14}$ times", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算空位数量增加的倍数），需要使用公式（空位形成能相关公式），且答案以具体数值形式给出（0.616×10^14倍），这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算（包括温度转换、公式应用等），涉及概念关联（空位形成能与温度的关系），需要综合分析不同温度下的空位浓度变化。虽然计算过程明确，但需要理解并应用相关公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用热力学公式（如Arrhenius方程）进行多步计算，涉及温度转换、指数运算和单位统一等步骤。虽然计算过程明确，但需要将多个物理概念（如空位形成能、温度效应）关联起来综合分析，属于中等应用层次的计算题。" + }, + { + "idx": 1993, + "question": "Among the three common crystal structures of metals, which structure cannot serve as a space lattice?", + "answer": "Hexagonal close-packed structure", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从三种常见的金属晶体结构中选择一个不能作为空间点阵的结构，属于从多个选项中选择正确答案的类型 | 知识层次: 题目考查对金属常见晶体结构及其空间点阵特性的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题题型内，此题需要理解三种常见金属晶体结构（面心立方、体心立方和六方密堆）的基本概念，并能区分空间点阵的定义。虽然需要一定的概念辨析能力，但不需要复杂的分析过程，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 1994, + "question": "In the expression for calculating the force on dislocation motion, $f=\\tau b$, what does $\\tau$ refer to?", + "answer": "The resolved shear stress of the external force in the slip direction on the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号$\\tau$的含义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对材料科学中基本概念的记忆和理解，即$\\tau$在位错运动力计算中的定义和含义。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答的是$\\tau$的定义，即外力在滑移方向上的分解剪应力，这是一个基础概念的记忆性知识，不需要复杂的解释或论述。在简答题的框架内，这类问题通常是最简单的，只需直接回忆和陈述定义即可。" + }, + { + "idx": 1995, + "question": "If a face-centered cubic crystal has a unit dislocation with b=α/2[1̄01] and a partial dislocation with b=a/6[121̄], these two dislocations meet and undergo a dislocation reaction. Write the Burgers vector of the resulting dislocation and specify the type of the resulting dislocation.", + "answer": "bŝ=a/3[1̄11]; this dislocation is a Frank partial dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出反应后的位错的Burgers向量并指定其类型，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求对位错的Burgers向量进行计算和反应产物的判断，涉及多步计算和概念关联，需要综合分析能力。虽然不涉及复杂的机理解释或创新应用，但超出了简单记忆或直接套用的范畴。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识、位错理论以及矢量运算能力。具体表现为：1) 需要准确理解面心立方晶体中全位错和部分位错的Burgers矢量表示；2) 必须正确进行位错反应计算（矢量叠加）；3) 需要识别并判断生成位错的类型（Frank部分位错）；4) 整个过程涉及多步概念关联和综合分析。虽然不需要进行多角度论述，但解题步骤的复杂性和概念关联性明显高于基础简答题。" + }, + { + "idx": 1996, + "question": "What is the difference between a space lattice and a crystal lattice?", + "answer": "A crystal lattice, also known as a crystal structure, refers to the specific arrangement of atoms; whereas a space lattice abstracts atoms as pure geometric points by ignoring their volume.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对空间点阵和晶体点阵这两个基本概念的定义和区别的理解，属于基础概念的记忆和辨析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分空间点阵和晶体点阵这两个基础概念，并简要说明它们之间的关系。虽然需要一定的理解记忆，但不需要深入分析或构建复杂的概念体系，属于中等难度的概念解释类简答题。" + }, + { + "idx": 1997, + "question": "How are jogs generally formed on dislocation lines?", + "answer": "Intersection of dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释位错线上jog的形成方式，需要文字解释和论述，答案也是以简短文字形式给出 | 知识层次: 题目考查位错线上jog形成的基本概念，仅需记忆和理解位错相交的基本原理，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（jogs的形成方式），属于最基础的概念记忆层面。不需要解释机制或描述过程，仅需直接给出\"位错相交\"这一核心知识点，符合等级1\"基本定义简答\"的标准。相比需要展开论述的简答题（如解释jogs对位错运动的影响），此题在同类题型中难度最低。" + }, + { + "idx": 1998, + "question": "Can a dislocation loop be formed by inserting a columnar half-atom plane in a crystal?", + "answer": "No. Because a dislocation loop can only be formed when the crystal inside the loop undergoes slip while the crystal outside does not.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"Can a dislocation loop be formed...\"），答案直接给出了对错判断（\"No\"）并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对位错环形成条件的基本概念记忆和理解，属于材料科学中晶体缺陷的基础知识。 | 难度: 在判断题中属于中等难度，需要理解位错环的形成机制这一概念，并判断题目陈述的正确性。虽然不涉及复杂计算或多概念交叉，但需要对晶体缺陷的基本原理有一定理解才能正确作答。" + }, + { + "idx": 1999, + "question": "When a dislocation is subjected to force, its motion direction is everywhere perpendicular to the dislocation line and can vary during movement. What should be the direction of the relative sliding of the crystal?", + "answer": "It is always the direction of the Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个具体的解释性陈述，而非选择、判断或计算。 | 知识层次: 题目需要理解位错运动的基本原理，并能够将位错线方向、运动方向与晶体滑移方向（Burgers矢量方向）进行关联分析。这涉及多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解位错运动的基本概念（如位错线、Burgers矢量）并进行综合分析。题目要求将位错运动方向与晶体相对滑动方向关联起来，涉及多步概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2000, + "question": "The atomic radius is related to the crystal structure. How does the atomic radius change when the coordination number of the crystal structure decreases?", + "answer": "The atomic radius contracts. This is because the atom tries to maintain the volume it occupies as unchanged or with minimal change [the volume occupied by the atom $V_{A}=$ the volume of the atom () + the interstitial volume]. When the coordination number of the crystal structure decreases, the interstitial volume increases. To maintain the balance of the above equation, the atomic radius must contract.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释原子半径如何随配位数变化，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅要求理解原子半径与晶体结构的关系，还需要解释原子半径随配位数变化的机理，涉及体积平衡和间隙体积变化的综合分析，思维过程较为深入。 | 难度: 在简答题中属于机理深度解释难度，需要综合运用晶体结构、原子半径和配位数之间的关系，并进行逻辑推理和机理解释。题目要求解释原子半径随配位数减少而收缩的原因，涉及体积守恒和间隙体积变化的平衡，需要较深入的理解和分析能力。" + }, + { + "idx": 2001, + "question": "What is the interface with the lowest interfacial energy?", + "answer": "Coherent interface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种界面具有最低的界面能，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对界面能基本概念的记忆和理解，特别是不同类型界面（如共格界面）的界面能特性。这属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答最低界面能的界面类型（共格界面），属于最基础的定义性知识，无需解释或论述。符合等级1\"基本定义简答\"的标准，是同类题型中最简单的考查形式。" + }, + { + "idx": 2002, + "question": "Is the statement 'Small-angle grain boundaries are all formed by edge dislocations arranged into walls' correct?", + "answer": "No. Twist boundaries are formed by crossed screw dislocations of the same sign.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的正确性（'Small-angle grain boundaries are all formed by edge dislocations arranged into walls'），并且答案直接给出了该陈述是错误的（No），并提供了简要的解释。这符合判断题的特征，即判断陈述的对错并提供简要说明。 | 知识层次: 题目考查对晶界类型及其形成机制的基本概念记忆和理解，属于材料科学中关于晶体缺陷的基础知识。 | 难度: 在判断题中属于中等难度，虽然题目涉及的是基础概念记忆，但需要区分不同类型的小角度晶界形成机制（刃型位错墙与螺型位错交叉），这超出了单纯的定义记忆，需要对概念有更深入的理解才能正确判断。" + }, + { + "idx": 2003, + "question": "A subgrain boundary is composed of $n$ edge dislocations with a misorientation of $0.057^{\\\\circ}$. Assuming there is no interaction between the dislocations before forming the subgrain boundary, by what factor does the distortion energy change after forming the subgrain boundary (given $R{=}10^{-4}$, $r_{0}=b=10^{-8}$; after forming the subgrain boundary, $$ R=D\\\\approx{\\\\frac{b}{\\\\theta}})?", + "answer": "The distortion energy is 0.75 times the original value (indicating that the dislocation energy decreases after forming the subgrain boundary).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定变形能的变化因子。解答过程涉及物理参数的代入和数学运算，最终得出一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用位错能量公式并理解亚晶界形成前后能量变化的关系，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要应用位错理论中的多个公式（如位错间距D=b/θ），进行多步能量计算（包括单个位错能量和亚晶界形成后的能量对比），并理解能量变化与位错排列的关系。虽然不涉及复杂多变量计算，但需要将多个概念关联并综合分析，符合等级3\"综合性计算问题\"的标准。" + }, + { + "idx": 2004, + "question": "What are the characteristics of atomic arrangement in ordered alloys?", + "answer": "An ordered solid solution, where atoms of each component occupy their respective Bravais sublattices, known as sublattices. The entire solid solution forms a complex lattice composed of the sublattices of each component, also referred to as a superlattice or superstructure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释有序合金中原子排列的特征，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查有序合金中原子排列的基本特征，属于对基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释有序合金中原子的排列特征，但主要涉及基础概念记忆层面的知识，包括Bravais亚晶格、超晶格等术语的定义。不需要进行复杂的概念体系阐述或深入分析，解题步骤相对直接，属于该题型中的中等难度。" + }, + { + "idx": 2005, + "question": "What is the relationship between the atomic arrangement and bonding in ordered alloys?", + "answer": "This arrangement is related to the bonding energy (bond) between atoms. The greater the bonding energy, the less likely the atoms are to combine. If the bonding energy between dissimilar atoms is less than that between similar atoms, i.e., E_{A B}<(E_{A A}+E_{B B})/2, then the solute atoms will exhibit partially ordered or completely ordered arrangements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释原子排列与键合之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释原子排列与键合能之间的关系，并涉及不同原子间键合能的比较和有序排列的形成条件。这需要综合运用键合能的概念，进行推理分析，并解释其机理，属于较高层次的认知能力。 | 难度: 在简答题中属于机理深度解释难度等级。题目要求解释原子排列与键合能之间的关系，并涉及有序合金中原子排列的机理分析。需要综合运用键合能概念、原子间相互作用原理，并进行逻辑推理来阐述部分有序或完全有序排列的条件。虽然不涉及多因素交叉分析，但对机理的解释深度要求较高，符合等级4的标准。" + }, + { + "idx": 2006, + "question": "Why do many ordered alloys become disordered at high temperatures?", + "answer": "The driving force for ordering is the mixing energy parameter (=AB一 (ε^{m}=ε_{A B}-1/2(E_{A A}+E_{B B}))ε^{m}<0, while the resistance to ordering is the configurational entropy; increasing temperature enhances the contribution of the latter to the free energy (-T S), and beyond a certain critical temperature, the disordered solid solution becomes more stable, causing the ordered solid solution to disappear and transform into a disordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么有序合金在高温下会变得无序，答案提供了详细的文字解释和论述，涉及热力学概念和能量参数的分析，符合简答题的特征。 | 知识层次: 题目需要解释有序合金在高温下无序化的原因，涉及混合能参数和构型熵的概念，以及温度对自由能的影响。这需要综合运用热力学和材料科学的知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题中属于机理深度解释难度，需要综合运用热力学和材料科学知识，解释有序合金在高温下无序化的机理。题目要求理解混合能参数和构型熵的相互作用，并分析温度对自由能的影响，涉及较深的理论推导和概念整合。虽然不涉及多步骤复杂计算，但对原理的深入理解和准确表述要求较高。" + }, + { + "idx": 2007, + "question": "Analyze the type of solid solution formed by H in α-Fe and γ-Fe, their locations, and the solubility (mole fraction). The atomic radii of the elements are as follows: H: 0.046 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "H forms an interstitial solid solution in α-Fe. Due to the significant difference in size factors, the solubility (mole fraction) is very small. The location of H in α-Fe is mostly at the octahedral interstitial centers. The solubility decreases rapidly with decreasing temperature. In γ-Fe, H also forms an interstitial solid solution, located at the octahedral interstitial centers, with slightly higher solubility than in α-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析H在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，答案需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析氢在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，涉及多个概念的关联和综合分析。需要理解间隙固溶体的形成条件、原子半径的影响、不同晶格结构中间隙位置的区别，以及温度对溶解度的影响。虽然不涉及复杂的计算或机理的深入解释，但需要对多个知识点进行综合应用和分析。 | 难度: 在简答题题型中，该题目要求对H在α-Fe和γ-Fe中的固溶体类型、位置以及溶解度进行多角度分析论述。需要综合运用原子半径差异、间隙位置选择以及温度对溶解度的影响等多个概念，并进行关联性分析。虽然不涉及复杂的计算，但需要对材料科学中的固溶体理论有较深的理解和应用能力，属于该题型中较高难度的题目。" + }, + { + "idx": 2008, + "question": "The known solid solubility limits (mole fractions) of elements such as Cd, Zn, Sn, and Sb in Ag are x_Cd=42.5×10^-2, x_Zn=20×10^-2, x_Sn=12×10^-2, x_Sb=7×10^-2, respectively, and their atomic diameters are 0.3042 nm, 0.314 nm, 0.316 nm, 0.3228 nm, while Ag is 0.2883 nm. Analyze the reasons for the differences in their solid solubility limits (mole fractions).", + "answer": "When the atomic size factors are similar, the solid solubility limits (mole fractions) of the above elements in Ag are influenced by the atomic valence factor, i.e., the valence electron concentration e/a is an important factor determining the solid solubility limit (mole fraction). Their valences are 2, 3, 4, and 5, respectively, while Ag is 1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析不同元素在银中的固溶度差异的原因，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析不同元素在银中的固溶度差异原因，涉及原子尺寸因素和原子价因素的关联分析，需要综合运用材料科学中的固溶度理论、原子尺寸效应和价电子浓度概念进行推理和解释，思维过程较为深入和复杂。 | 难度: 在简答题（复杂分析类）中属于最高难度等级。该题目要求综合运用原子尺寸因素、价电子浓度(e/a)理论、固溶度机理等多维度知识体系进行深度解释。需要考生：" + }, + { + "idx": 2009, + "question": "Calculate the electron concentration at the solid solubility limit (mole fraction) for Cd, Zn, Sn, and Sb, given their valences are 2, 3, 4, and 5 respectively, Ag is 1, and the solid solubility limits (mole fractions) are x_Cd=42.5×10^-2, x_Zn=20×10^-2, x_Sn=12×10^-2, x_Sb=7×10^-2", + "answer": "The electron concentration at the solid solubility limit can be calculated using the formula c=Z_A(1-x_B)+Z_Bx_B. Here, Z_A and Z_B are the numbers of valence electrons for components A and B respectively; x_B is the mole fraction of component B. The electron concentration for Cd=1×(1-0.425)+2×0.425=1.43; for Zn=1×(1-0.20)+3×0.20=1.42; for Sn=1×(1-0.12)+4×0.12=1.39; for Sb=1×(1-0.07)+5×0.07=1.31.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，解答过程涉及多个步骤的数学运算，最终得出具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，无需多步推理或综合分析。虽然需要理解电子浓度的概念，但整体上属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度。题目虽然涉及多个元素的电子浓度计算，但每个计算都是独立且直接套用同一个公式c=Z_A(1-x_B)+Z_Bx_B，没有复杂的推导或组合计算步骤。虽然需要处理多个数据点，但每个计算步骤都是重复性的简单运算，因此属于等级2难度。" + }, + { + "idx": 2010, + "question": "Analyze the type of solid solution formed by N in α-Fe and γ-Fe, their locations, and the solubility (mole fraction). The atomic radii of the elements are as follows: N: 0.071 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "N forms an interstitial solid solution in α-Fe, with a maximum solubility (mole fraction) of about 0.1×10^-2 at 590°C, decreasing to 0.001×10^-2 at room temperature. In α-Fe, N is mostly located at the octahedral interstitial sites. In γ-Fe, N forms an interstitial solid solution, located at the octahedral interstitial sites, with a maximum solubility (mass fraction) of about 2.8×10^-2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析N在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度（摩尔分数），需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析N在α-Fe和γ-Fe中的固溶体类型、位置以及溶解度，涉及多个概念的综合应用和关联（如固溶体类型、间隙位置、溶解度随温度变化等），需要多步分析和理解，但不需要复杂的机理推理或创新设计。 | 难度: 在简答题题型中，该题目属于较高难度。题目要求分析N在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度（摩尔分数），这需要综合运用多个知识点，包括固溶体的分类、间隙位置的选择、溶解度的影响因素等。此外，题目还涉及温度对溶解度的影响，以及不同晶体结构（α-Fe和γ-Fe）对间隙原子位置的影响，需要进行多角度分析和论述。虽然题目没有要求进行复杂的计算，但需要对相关概念有深入的理解和关联性分析，因此在简答题题型中属于较高难度。" + }, + { + "idx": 2011, + "question": "The intermetallic compound AlNi has a CsCl-type structure with a lattice constant of $a=0.288\\\\mathrm{~nm}$. Calculate its density (the relative atomic mass of Ni is 58.71, and the relative atomic mass of Al is 26.98).", + "answer": "Density $\\\\rho=5.97~\\\\mathrm{g}/\\\\mathrm{cm}^{3}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解密度，答案是一个具体的数值结果。 | 知识层次: 题目要求应用基本公式（密度计算公式）进行简单计算，涉及晶格常数和相对原子质量的直接套用，无需多步推理或综合分析。 | 难度: 在计算题中，该题目属于单一公式直接计算的难度等级。题目要求计算密度，只需要应用密度公式 $\\rho = \\frac{m}{V}$，并结合晶格常数计算体积，再根据化学式 AlNi 计算质量。整个过程仅涉及基本公式的直接应用和简单数值计算，无需多个公式组合或复杂推导，因此属于该题型内最低的难度等级。" + }, + { + "idx": 2012, + "question": "Analyze the type of solid solution formed by C in α-Fe and γ-Fe, their locations, and the solubility (mole fraction). The atomic radii of the elements are as follows: C: 0.077 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "In α-Fe, C forms an interstitial solid solution, with the maximum solubility (mole fraction) reaching 0.0218×10^-2 at 727°C and decreasing to 0.006×10^-2 at room temperature. The location of C in α-Fe is mostly at the octahedral interstitial centers. In γ-Fe, C forms an interstitial solid solution located at the octahedral interstitial centers, with the maximum solubility (mass fraction) being 2.11×10^-2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析碳在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，并给出详细的解释和论述。答案提供了详细的文字解释和具体数据，符合简答题的特征。 | 知识层次: 题目要求分析碳在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，涉及多个概念的综合应用，包括固溶体类型的判断、间隙位置的选择以及溶解度的计算。虽然不需要复杂的推理或创新设计，但需要对材料科学中的基本概念有较深的理解，并能将这些概念关联起来进行分析。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求分析C在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度（摩尔分数），这涉及到多个概念的关联和综合分析。具体来说，需要理解间隙固溶体的概念、不同晶格结构中间隙位置的区别、以及温度对溶解度的影响。此外，还需要掌握原子半径对固溶体类型的影响，并能将理论知识与具体数据（如原子半径和溶解度数据）结合起来进行分析。这些要求使得该题目在同题型中属于较高难度。" + }, + { + "idx": 2013, + "question": "Why can only the two components of substitutional solid solutions mutually dissolve infinitely, while interstitial solid solutions cannot?", + "answer": "This is because when a solid solution forms, the dissolution of solute atoms causes lattice distortion in the solvent structure, thereby increasing the system's energy. The greater the difference in atomic size between the solute and solvent, the more severe the lattice distortion, leading to higher distortion energy, lower structural stability, and smaller solubility. Generally, the lattice distortion caused by solute atoms in interstitial solid solutions is more significant, so they cannot mutually dissolve infinitely but only have limited solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么置换固溶体可以无限互溶而间隙固溶体不能，需要详细的文字解释和论述，答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释置换固溶体和间隙固溶体在无限互溶方面的差异，涉及晶格畸变、系统能量变化、原子尺寸差异对溶解度的影响等复杂机理分析。需要综合运用材料科学中的固溶体理论、晶体结构知识以及热力学原理进行推理和解释，思维过程较为深入。 | 难度: 在简答题题型中，该题目要求对固溶体机理进行深度解释，涉及晶格畸变、系统能量变化等复杂概念的综合运用。虽然不需要全面分析多种复杂现象（如等级5的要求），但需要准确描述两种固溶体的溶解差异及其根本原因，体现了对材料科学基础理论的深入理解和机理阐述能力。" + }, + { + "idx": 2014, + "question": "The density of ZnS is $4.1~\\\\mathrm{Mg}/\\\\mathrm{m}^{3}$, calculate the distance between the centers of the two ions based on this", + "answer": "The distance between the centers of the two ions is $0.234\\\\mathrm{~n}\\\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的密度数据进行数值计算，应用相关公式来求解离子中心间距，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式应用和简单计算，需要根据密度计算离子间距，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于简单公式应用计算，需要应用密度公式和晶体结构的基本知识，但不需要多个公式组合或复杂推导。解题步骤相对直接，属于该题型内的中等偏低难度。" + }, + { + "idx": 2015, + "question": "The maximum solid solubility (mole fraction) of carbon in γ-Fe is x_C=8.9×10^-2. Given that C atoms occupy octahedral interstitial sites, calculate the percentage of octahedral interstitial sites occupied by C atoms.", + "answer": "The percentage of octahedral interstitial sites occupied by C atoms is 10.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳原子占据八面体间隙的百分比），并给出了具体的计算步骤和最终数值答案（10.2%）。解答过程需要应用材料科学中的相关公式和概念，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，涉及固溶体最大溶解度概念的应用以及晶格间隙位置的计算，需要将多个概念关联并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解固溶体、间隙位置和摩尔分数等概念，并进行多步计算和综合分析。虽然计算步骤不算特别复杂，但需要将多个知识点关联起来，并正确应用公式。" + }, + { + "idx": 2016, + "question": "Calculate the distance between the center of a sodium ion and its nearest neighboring positive ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.393nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子与其最近邻正离子之间的距离），并给出了具体的离子半径数据，最终答案是一个具体的数值（0.393nm），符合计算题的特征。 | 知识层次: 题目要求应用基本的离子半径数据进行简单计算，直接套用公式（离子间距=阳离子半径+阴离子半径），属于单一步骤的数值计算，无需多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目仅需要应用离子半径相加的基本公式（Na+半径 + Cl−半径 = 距离），无需额外的公式组合或复杂计算步骤，属于该题型内最基础的难度水平。" + }, + { + "idx": 2017, + "question": "The maximum solid solubility (mole fraction) of nitrogen in γ-Fe is x_N=10.3×10^-2. Given that N atoms occupy octahedral interstitial sites, calculate the percentage of octahedral interstitial sites occupied by N atoms.", + "answer": "The percentage of octahedral interstitial sites occupied by N atoms is 12.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算氮原子占据八面体间隙的百分比），并给出了具体的数值和公式应用（最大固溶度和间隙位置）。答案也是一个具体的数值结果（12.5%），这些都是计算题的典型特征。 | 知识层次: 题目需要应用给定的最大固溶度和氮原子占据八面体间隙位的信息进行简单的百分比计算，属于基本公式应用和直接套用的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用给定的最大固溶度数据（x_N=10.3×10^-2）和八面体间隙位点占据的简单比例关系（1个N原子占据1个八面体间隙位点），通过直接计算即可得出结果。不需要多个公式组合或复杂推导，属于最基础的计算题类型。" + }, + { + "idx": 2019, + "question": "Calculate the distance between the center of a sodium ion and the next nearest Cl− ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.482nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子和氯离子之间的距离），并给出了具体的半径数据，需要使用公式进行计算。答案是一个具体的数值（0.482nm），符合计算题的特征。 | 知识层次: 题目需要应用基本的离子半径概念和简单的几何计算（立方体对角线公式），属于直接套用公式和数值计算的范畴，不涉及多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算，只需要应用晶体结构中离子间距的基本公式（即离子半径之和乘以√2）即可得出结果，无需复杂步骤或多公式组合。" + }, + { + "idx": 2020, + "question": "Analyze the type of solid solution formed by B in α-Fe and γ-Fe, its location, and the solubility (mole fraction). The atomic radii of the elements are as follows: B: 0.091 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "In α-Fe, due to the larger atomic size of B, it is more difficult to dissolve interstitially, sometimes partially dissolving substitutionally, forming interstitial or substitutional solid solutions, with relatively low solubility. In γ-Fe, B forms an interstitial solid solution, located at the center of octahedral interstitial sites, with slightly higher solubility than in α-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析B在α-Fe和γ-Fe中形成的固溶体类型、位置和溶解度，答案需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析B在α-Fe和γ-Fe中形成的固溶体类型、位置及溶解度，涉及原子半径差异对固溶体类型的影响、间隙和置换固溶体的形成条件以及溶解度的比较。这需要综合运用固溶体的基本概念、晶体结构知识以及原子尺寸效应的理解，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求多角度分析论述，涉及原子半径比较、固溶体类型判断、溶解位置确定以及溶解度差异解释。需要综合运用材料科学基础中的固溶体理论和晶体结构知识，并进行多步逻辑推理。虽然不涉及复杂计算，但对概念关联性和综合分析能力要求较高，属于该题型框架内较难的题目。" + }, + { + "idx": 2021, + "question": "Calculate the distance between the center of a sodium ion and the third nearest Cl− ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.622nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子与第三近邻氯离子之间的距离），需要应用晶体结构中的几何关系公式，且答案是一个具体的数值（0.622nm），这些都是计算题的典型特征。 | 知识层次: 题目要求进行基本的数值计算和公式应用，涉及离子半径和晶体结构的基本概念，但计算过程相对直接，不需要多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于简单公式应用计算。题目要求计算NaCl晶体中钠离子与第三近邻氯离子之间的距离，主要涉及晶体结构的基本理解和简单几何关系的应用。虽然需要理解晶体的面心立方结构和离子排列方式，但计算过程相对直接，只需应用基本的几何关系和给定的离子半径。因此，在同类题型中属于中等难度（等级2）。" + }, + { + "idx": 2022, + "question": "A common polymer has C2H2Cl2 as its monomer, with an average molecular weight of 60000u (using the relative atomic masses of the elements as Ar(C)=12, Ar(H)=1, Ar(Cl)=35.5). What is its degree of polymerization?", + "answer": "The degree of polymerization is n = 60000 / 97 = 620", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（分子量计算和聚合度求解），并应用了公式（聚合度=聚合物分子量/单体分子量），答案以具体数值形式呈现。 | 知识层次: 题目主要考查基本公式应用和简单计算，即通过分子量和单体分子量的比值计算聚合度，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需使用分子量除以单体分子量这一基本公式，计算步骤简单直接，无需组合多个公式或进行复杂推导。" + }, + { + "idx": 2023, + "question": "A solid solution contains xMgO=30/10−2 and xLiF=70/10−2. What are the mass fractions of Li+, Mg2+, F−, and O2−?", + "answer": "wLi+=16/10−2, wMg2+=24/10−2, wF−=44/10−2, wO2−=16/10−2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定各个离子的质量分数，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行基本的质量分数计算，涉及简单的公式应用和数值计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要计算质量分数，涉及基本的摩尔分数转换和质量分数公式的应用，但不需要复杂的多步骤计算或公式组合。解题步骤相对直接，属于该题型内的中等偏低难度。" + }, + { + "idx": 2024, + "question": "A ceramic insulator contains $1\\\\%$ (by volume) of pores after sintering, with the pores being cubes of side length $13.7\\\\mathrm{mm}$. If during the manufacturing process, the powder can be pressed to contain $24\\\\%$ pores, what should the size of the mold be?", + "answer": "The size of the mold should be $l=15.0\\\\mathrm{~mm}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定模具的尺寸。答案给出了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及孔隙率和尺寸变化的关联分析，需要综合运用材料科学中的烧结和成型原理，但不需要进行复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解孔隙率与尺寸的关系，进行多步计算和单位转换，涉及体积百分比和尺寸调整的综合分析。虽然计算步骤明确，但需要将多个概念关联起来解决问题。" + }, + { + "idx": 2025, + "question": "The theoretical strength of amorphous materials is calculated to be $G/6\\\\sim G/4$, where $G$ is the shear modulus. Given $\\\\nu=0.25$, estimate the theoretical strength of glass (an amorphous material) based on its elastic properties (given $E=70~000~\\\\mathrm{MPa}$).", + "answer": "Therefore, the theoretical strength ranges between 0.4E and 0.4E, that is, $$4~900\\\\sim7~000~\\\\mathrm{MPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的弹性模量（E=70 000 MPa）和泊松比（ν=0.25），通过公式计算玻璃的理论强度范围。解答过程涉及数值计算和公式应用，最终给出具体的数值结果（4 900~7 000 MPa）。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的弹性模量E和泊松比ν计算理论强度范围。虽然需要理解理论强度的概念和公式，但整体过程较为直接，无需多步计算或复杂分析。 | 难度: 在计算题中属于简单应用层次，需要应用基本公式（如剪切模量与弹性模量的关系）并进行简单计算。虽然涉及多个步骤（计算G，然后应用理论强度范围），但每一步都是直接的公式套用和数值代入，没有复杂的推导或组合计算。因此，在同题型内属于等级2难度。" + }, + { + "idx": 2026, + "question": "Calculate the distance between the centers of sodium ions at the nearest identical positions in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.393nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子之间的距离），并给出了具体的半径数据，最终答案是一个具体的数值（0.393nm），符合计算题的特征。 | 知识层次: 题目要求应用给定的离子半径数据进行简单计算，直接套用公式即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用离子半径相加的简单公式（Na+半径 + Cl−半径）即可得出答案，无需多个步骤或复杂计算。" + }, + { + "idx": 2027, + "question": "An organic compound has the composition ${w_{\\mathrm{C}}=62.1/10^{-2}}$, ${w_{\\mathrm{H}}}=10.3/1\\\\time10^{-2}$, $\\\\varpi_{0}=27.6/10^{-2}$. Try to write the possible name of the compound.", + "answer": "\\\\mathrm{{C}:\\\\mathrm{{H}:\\\\mathrm{{O}=\\\\frac{62.\\\\mathrm{{1}}}{12.\\\\mathrm{{,011}}}:\\\\frac{10.\\\\mathrm{{3}}}{1.\\\\mathrm{{007}\\\\mathrm{{97}}}}:\\\\frac{27.6}{15.\\\\mathrm{{9994}}}=5.2:10.2:1.7\\\\approx3:6:10.4:1.7\\\\approx3:6:1.74:\\\\mathrm{{8}.\\\\mathrm{{1}:\\\\mathrm{{7}}}}}}} Therefore, the possible compound is $\\\\mathrm{CH}_{3}\\\\mathrm{COCH}_{3}$ (acetone).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的元素组成比例推断可能的有机化合物名称，并通过计算和解释得出答案。答案需要文字解释和论述，而不仅仅是选择或判断。 | 知识层次: 题目涉及基本的化学组成计算和简单的比例转换，需要应用基本的化学计量知识，但不需要复杂的分析或综合推理。 | 难度: 在简答题中属于简单应用过程描述难度。题目要求根据给定的元素组成比例计算并推导可能的有机化合物名称，主要涉及基本公式应用和简单计算，解题步骤直接且明确，无需复杂的推理或深入的概念理解。因此，在同题型内属于较低难度等级。" + }, + { + "idx": 2028, + "question": "Assuming the density of MgO is 3.6 g/cm3 and the density of LiF is 2.6 g/cm3, what is the density of the solid solution?", + "answer": "The density of the solid solution ρ=2.9 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的密度数据进行数值计算，应用相关公式来求解固体溶液的密度，答案是一个具体的计算结果(2.9 g/cm3)，这符合计算题的特征。 | 知识层次: 题目涉及基本的密度计算和简单的公式应用，不需要多步计算或复杂的概念关联，属于直接套用基本公式的简单应用层次。 | 难度: 在计算题中属于最低难度，仅需直接套用单一密度计算公式，无需多步骤推导或复杂公式组合。题目提供了所有必要数据，计算过程仅涉及基本算术运算，属于典型的\"单一公式直接计算\"类型。" + }, + { + "idx": 2029, + "question": "A common polymer has C2H2Cl2 as its monomer, with an average molecular weight of 60000u (using the relative atomic masses of the elements as Ar(C)=12, Ar(H)=1, Ar(Cl)=35.5). Calculate the mass of the monomer.", + "answer": "The mass of the monomer is 12×2 + 1×2 + 35.5×2 = 97u/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算单体的质量），答案是通过公式应用和数值计算得出的具体数值（97u/mol）。 | 知识层次: 题目仅涉及基本公式应用和简单计算，即通过给定的化学式和相对原子质量直接计算单体的分子量，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需套用基本分子量计算公式，无需复杂步骤或多公式组合。" + }, + { + "idx": 2030, + "question": "What are the types of silicate structures", + "answer": "Silicates are divided into the following categories: (1) silicates containing finite silicon-oxygen groups; (2) chain silicates; (3) layer silicates; (4) framework silicates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举硅酸盐结构的类型，答案以文字形式详细描述了不同类型的硅酸盐结构，符合简答题的特征。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念的记忆和理解，不涉及复杂分析或综合应用 | 难度: 在简答题题型中，该题目要求对硅酸盐结构进行分类并简要说明各类别，属于概念解释和描述的难度级别。虽然需要记忆多个分类，但不需要深入阐述或分析复杂概念体系，因此属于中等难度。" + }, + { + "idx": 2031, + "question": "Why can rapid changes in external temperature cause many ceramic devices to crack or break?", + "answer": "Because most ceramics are mainly composed of crystalline and glass phases, and the thermal expansion coefficients of these two phases differ significantly. When rapidly cooled from high temperatures, the different contractions of each phase generate internal stresses sufficient to cause the ceramic devices to crack or break.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷器件在外部温度快速变化时开裂或断裂的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷器件在温度快速变化时开裂或断裂的机理，涉及陶瓷材料中晶相和玻璃相的热膨胀系数差异及其导致的内部应力，需要综合运用材料科学知识进行推理分析和机理解释，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对陶瓷材料的热膨胀系数差异及其导致的内部应力进行机理深度解释。虽然不需要涉及多个复杂因素的交互作用（如等级5要求的全面分析），但需要准确理解并阐述两相热膨胀差异与开裂现象的因果关系，属于该题型中较高层次的机理解释难度。" + }, + { + "idx": 2032, + "question": "A polymeric material contains polyvinyl chloride, with 900 monomers in one molecule. If each molecule can be stretched into a linear molecule, calculate the theoretically maximum strain that can be achieved for this polymer (assuming the bond length of each C-C bond is $0.154\\\\mathrm{nm}$).", + "answer": "The theoretically maximum strain is $3380\\\\%$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算最大应变），并给出了具体的数值条件（单体数量、键长等），最终答案是一个具体的数值结果（3380%），这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算（计算分子链长度和应变），并需要理解聚合物分子链的构象和应变的概念。虽然计算本身不复杂，但需要将多个概念关联起来进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解聚合物分子链的拉伸原理，进行多步计算（包括单体数量、键长、总长度和应变计算），并正确应用应变公式。虽然计算步骤较多，但变量相对单一，不涉及复杂多变量或高级数学工具，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 2033, + "question": "Describe the thermodynamic conditions of crystallization phase transition", + "answer": "Analysis of the change in system free energy during crystallization phase transition shows that the thermodynamic condition for crystallization is ΔG<0. From the change in free energy per unit volume ΔGB=-LmΔT/Tm, it can be seen that only when ΔT>0 can ΔGg<0 be achieved. That is, only undercooling can make ΔG<0.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述结晶相变的热力学条件，答案通过文字解释和论述了系统自由能变化和过冷度的关系，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析结晶相变的热力学条件，涉及系统自由能变化的理论推导和解释，需要综合运用热力学原理和相变理论进行推理分析，思维过程较为深入。 | 难度: 在简答题题型中，该题目要求对结晶相变的热力学条件进行详细解释，涉及系统自由能变化、单位体积自由能变化公式推导以及过冷度的概念。虽然不需要进行复杂现象的全面分析（等级5），但需要对热力学机理进行深度解释（等级4），包括公式的物理意义和推导逻辑。这要求学生具备扎实的热力学基础和一定的公式推导能力，属于该题型中较高难度的题目。" + }, + { + "idx": 2034, + "question": "Describe the structural conditions of crystalline phase transformation", + "answer": "The structural fluctuations present in the liquid serve as the foundation for nucleation during crystallization. Therefore, structural fluctuations are the essential structural condition required for the crystallization process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体相变的结构条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述晶体相变的结构条件，涉及对液态结构波动与成核过程之间关系的深入理解和分析，需要综合运用结晶过程的基本原理和结构变化的机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对结晶过程中的结构条件进行机理深度解释，涉及结构波动与成核基础的关系。虽然不需要全面分析复杂现象，但需要对结晶机理有较深入的理解和阐述，属于该题型内较高难度的题目。" + }, + { + "idx": 2035, + "question": "Polyvinyl chloride eccC2H3Cl∂n is dissolved in an organic solvent, with its C-C bond length set at 0.154nm, and the number of bonds in the chain x=2n. For a molecule with a molecular mass of 28500g, what is its root mean square length?", + "answer": "Root mean square length 4.65nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及分子质量、键长和链长等参数的计算，最终要求得出一个具体的数值结果（4.65nm）。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目需要进行多步计算，包括分子量的计算、键数的确定以及均方根长度的公式应用，涉及概念关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解高分子链的构象统计概念，应用均方末端距公式（根号下n乘以键长平方），并进行多步单位换算和数值计算。题目涉及分子量到聚合度的转换（n=M/M0）、键数计算（x=2n）以及最终的开方运算，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2036, + "question": "For a copolymer ABS with equal mass fractions of each component, what is the ratio of the monomers (A—acrylonitrile; B—butadiene; S—styrene)?", + "answer": "The mole fractions of the monomers are \\n\\n$$\\nx_{\\\\#Z\\\\#}=20/10^{-2},\\\\quad x_{\\\\sf T\\\\lceil-w\\\\rceil}=40/10^{-2},\\\\quad x_{\\\\#\\\\mathbb{W}\\\\#\\\\mathbb{W}}=40/10^{-2}\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算共聚物ABS中各单体的摩尔分数比例，需要通过数值计算和公式应用来得出答案。答案以数学表达式形式呈现，显示了具体的计算结果。 | 知识层次: 题目需要计算共聚物中单体的摩尔分数，涉及多步计算和不同单体分子量的概念关联，需要综合分析质量分数和分子量的关系。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用质量分数与摩尔分数之间的转换关系，涉及多步计算和概念关联。虽然题目给出了各组分质量分数相等的条件，但需要计算不同单体的摩尔质量并进行综合比较，属于中等应用层次中较为复杂的题目。" + }, + { + "idx": 2037, + "question": "Polyvinyl chloride C2H3Cln is dissolved in an organic solvent, with its C-C bond length set at 0.154nm, and the number of bonds in the chain x=2n. If the root mean square length is only half of that in (1), what is the molecular mass?", + "answer": "The molecular mass M=7125g.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定分子质量。答案给出了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括理解聚氯乙烯的分子结构、键长和链的均方根长度的关系，以及分子质量的计算。这需要将多个概念关联起来并进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解高分子链的构象统计概念，应用均方末端距公式，并进行多步计算和单位转换。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有复杂多变量或高级数学工具需求。" + }, + { + "idx": 2038, + "question": "Given that the relative atomic mass of Cu is 63.5 and its density is 8.9 g/cm^3, find the number of atoms in the critical nucleus.", + "answer": "n≈261", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的相对原子质量和密度计算临界核中的原子数，需要数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目需要应用相对原子质量和密度等基本概念，进行多步计算来求解临界核中的原子数。这涉及到公式的应用和数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要结合相对原子质量和密度进行多步计算，并理解临界核的概念。虽然计算步骤较多，但每个步骤相对明确，没有涉及复杂多变量或高度抽象的推导过程。" + }, + { + "idx": 2039, + "question": "If the maximum undercooling during the solidification of pure nickel is 0.18 times its melting point $(t_{\\\\mathrm{m}}=1453^{\\\\circ}\\\\mathrm{C})$, calculate the driving force for solidification. $(\\\\Delta H=-18075.\\\\mathrm{J/mol})$", + "answer": "The driving force for solidification $\\\\Delta G=-3~253.5~\\\\mathrm{J/mol},$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的最大过冷度和熔化温度计算凝固驱动力，属于直接套用公式的简单应用。 | 难度: 在计算题中属于简单公式应用计算难度，需要理解并应用基本的驱动力和过冷度关系公式，但不需要多个公式组合或复杂推导。" + }, + { + "idx": 2040, + "question": "What are the main bonding types in ceramic materials?", + "answer": "The main bonding types in ceramic materials are ionic bonds and covalent bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释陶瓷材料中的主要键合类型，答案以文字形式给出解释和论述，不需要选择、判断或计算。 | 知识层次: 题目考查陶瓷材料中主要键合类型的基本概念记忆，仅需回答离子键和共价键这两种基本分类，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答陶瓷材料的主要键合类型，属于基本定义简答。题目仅涉及两个基本概念（离子键和共价键）的列举，不需要深入解释或复杂论述，符合等级1的难度标准。" + }, + { + "idx": 2041, + "question": "Discuss the energy conditions of crystalline phase transformation", + "answer": "From the critical nucleus formation work oS, it can be seen that when a critical nucleus is formed, 1/3 of the surface energy must still be provided by energy fluctuations in the liquid.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论晶体相变的能量条件，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求讨论晶体相变的能量条件，涉及临界核形成功和表面能等概念的综合运用，需要理解能量波动在相变过程中的作用，并进行机理上的解释。这需要较高的分析能力和对相关概念的深入理解。 | 难度: 在简答题题型中，该题目要求对晶体相变的能量条件进行机理深度解释，涉及临界核形成功和表面能量的概念，需要综合运用热力学和相变理论进行推理分析。虽然不涉及最复杂的多因素交互作用分析（等级5），但对机理的解释深度和理论推导要求较高，属于该题型中的较高难度题目。" + }, + { + "idx": 2042, + "question": "Describe the kinetic conditions of crystalline phase transformation", + "answer": "The kinetic condition is that the temperature of the liquid at the liquid-solid interface front Tir_k have the potential to nucleate; while embryos with r=r_k may either disappear or grow stably. Therefore, an embryo with radius r_k is called a critical nucleus. Its physical meaning is that the short-range ordered atomic clusters emerging in the undercooled liquid can become nuclei and grow when their size r≥r_k.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"critical nucleus\"进行解释和论述，答案提供了详细的文字描述和物理意义的阐述，符合简答题的特征。 | 知识层次: 题目考查对临界核（critical nucleus）这一基本概念的定义和物理意义的记忆和理解，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目要求对\"critical nucleus\"进行解释和描述，包括其物理意义和形成条件。虽然涉及一些基本原理（如自由能与胚胎半径的关系），但整体仍属于概念解释和描述的范畴，未达到复杂概念体系阐述的深度。因此属于等级2难度。" + }, + { + "idx": 2049, + "question": "What is the quantitative relationship between the critical nucleus radius r_k and the undercooling ΔT?", + "answer": "The critical nucleus radius r_k, whose size is related to the undercooling, is given by r_k=(2σT_m)/(L_m)×1/ΔT", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定量描述临界核半径r_k与过冷度ΔT之间的关系，并给出了具体的计算公式，需要应用公式进行计算和推导 | 知识层次: 题目涉及基本公式的直接应用，需要理解临界核半径与过冷度之间的定量关系，并进行简单的公式代入计算。虽然需要理解概念，但主要考察的是对给定公式的应用能力，属于简单应用层次。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式r_k=(2σT_m)/(L_m)×1/ΔT进行计算，无需任何公式组合或复杂推导步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2050, + "question": "What is dynamic undercooling?", + "answer": "During crystal growth, a certain degree of undercooling in the liquid ahead of the liquid-solid interface is required to satisfy (dN/dt)F>(dN/dt)M. This undercooling is called dynamic undercooling (ΔTl=Tm−Ti), which is a necessary condition for crystal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"dynamic undercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查动态过冷（dynamic undercooling）的基本定义和其在晶体生长中的基本原理，属于基础概念的记忆和理解范畴。 | 难度: 在简答题中属于中等难度，需要解释动态过冷的概念及其在晶体生长中的作用，涉及基本原理的记忆和简单描述，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 2051, + "question": "What are the characteristics of ingot structure?", + "answer": "In the ingot structure, there are generally 3 crystal zones. (1) The outermost layer is the fine-grained zone. Its formation is due to the lower temperature of the mold wall and the larger undercooling of the liquid, resulting in a higher nucleation rate. (2) The middle layer is the columnar crystal zone. Its formation is mainly due to the increase in the temperature of the mold wall, where the growth rate of crystal nuclei is greater than the nucleation rate, and heat dissipation is more favorable in the direction perpendicular to the mold wall. In the fine-grained zone, grains with favorable orientations preferentially grow into columnar crystals. (3) The center is the equiaxed crystal zone. Its formation is due to the further increase in mold wall temperature and the further decrease in liquid undercooling, where the directional heat dissipation of the remaining liquid is no longer obvious, and it is in a state of uniform cooling. At the same time, unmelted impurities, broken dendrites, etc., tend to concentrate in the remaining liquid, all of which promote the formation of equiaxed crystals. It should be noted that not all ingot structures have 3 crystal zones. Due to different solidification conditions, an ingot may only have one type of crystal zone or only two types of crystal zones.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释和描述铸锭结构的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对铸锭结构特征的基础概念记忆和理解，包括三个晶体区的形成原因和特点，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目要求详细解释和论述铸锭结构的三个晶体区及其形成原因，涉及多个概念和复杂的形成机制。需要考生不仅记忆各个晶体区的定义，还要理解其背后的热力学和动力学原理，并能系统性地阐述整个铸锭结构的形成过程。这超出了简单的定义或概念解释，属于复杂概念体系的阐述，因此属于该题型下的最高难度等级。" + }, + { + "idx": 2052, + "question": "Point out the errors in the following concepts and correct them: (1) The so-called degree of undercooling refers to the difference between the temperature at which a plateau appears on the cooling curve during crystallization and the melting point; while the dynamic degree of undercooling refers to the difference between the actual temperature of the liquid phase during crystallization and the melting point.", + "answer": "The difference between the actual crystallization temperature on the cooling curve and the melting point; the difference between the temperature of the liquid at the liquid-solid interface front and the melting point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也是以文字形式给出修正后的概念，符合简答题的特征。 | 知识层次: 题目考查对\"过冷度\"和\"动态过冷度\"这两个基本概念的定义理解和记忆，属于材料科学基础概念范畴，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求指出并纠正两个相关但不同的概念（过冷度和动态过冷度），需要学生对这两个概念有清晰的理解和区分能力。虽然涉及两个概念，但都属于基础概念记忆层次，不需要复杂的体系阐述或深入分析，因此属于等级2难度。" + }, + { + "idx": 2054, + "question": "What is undercooling?", + "answer": "The temperature difference between the actual crystallization temperature and the theoretical crystallization temperature is called undercooling (ΔT=Tm−Tn). It is required by the thermodynamic conditions of phase transformation. Only when ΔT>0 can the condition that the free energy of the solid phase is lower than that of the liquid phase be achieved. The free energy difference between the liquid and solid phases is the driving force for crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"undercooling\"进行文字解释和论述，答案提供了详细的定义和原理说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即undercooling的定义及其在相变热力学条件中的作用。虽然涉及自由能差的概念，但整体上属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释undercooling的定义，并简要说明其热力学条件和结晶驱动力。虽然涉及一些基本原理（如自由能差），但整体仍属于基础概念的记忆和解释范畴，不需要复杂的体系阐述或多层次概念整合。相较于仅回答基本定义的等级1题目，此题需要更深入的概念描述，但未达到等级3要求的复杂体系阐述程度。" + }, + { + "idx": 2055, + "question": "What is critical undercooling?", + "answer": "In an undercooled liquid, the degree of undercooling at which an embryo can form with a radius equal to the critical nucleus radius is called the critical undercooling (ΔT∗). Clearly, when the actual undercooling ΔT<ΔT∗, even the largest embryo in the undercooled liquid is smaller than the critical nucleus radius, making nucleation difficult. Only when ΔT>ΔT∗ can homogeneous nucleation occur. Therefore, critical undercooling is required for nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对关键术语进行解释和论述，答案提供了详细的文字说明和概念阐述，符合简答题的特征。 | 知识层次: 题目考查对临界过冷度（critical undercooling）这一基本概念的定义和解释，属于基础概念的记忆和理解范畴。虽然涉及一些简单的逻辑关系（如ΔT与ΔT∗的比较），但整体上仍属于对基本原理的阐述，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释临界过冷度的定义及其在形核过程中的作用，涉及基本原理的记忆和简单应用，但不需要复杂的体系阐述或多概念综合分析。" + }, + { + "idx": 2056, + "question": "Analyze the basic conditions for the formation of single crystals", + "answer": "The basic condition for forming a single crystal is to ensure that only one nucleus is generated (or only one nucleus can grow) during the crystallization of liquid metal, which then grows into a single crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求分析和解释单晶形成的基本条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查单晶形成的基本条件，属于基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求分析单晶形成的基本条件，需要解释\"确保只有一个晶核生成或生长\"这一核心概念，但不需要深入阐述复杂机制或多因素影响。相比等级1的简单定义回答，它需要一定的理解和组织能力；但相比等级3的体系化阐述，其知识深度和复杂度要求较低，属于该题型中的中等难度。" + }, + { + "idx": 2057, + "question": "Given the melting point of Cu tm=1083°C, latent heat of fusion Lm=1.88×10^3 J/cm^3, and specific surface energy σ=1.44×10^5 J/cm^2. Calculate the critical nucleus radius for homogeneous nucleation of Cu at 853°C.", + "answer": "rk=9.03×10^-10 m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数（熔点、潜热、表面能）和温度条件，应用相关公式计算临界核半径。答案是一个具体的数值结果（9.03×10^-10 m），这表明解答过程需要进行数值计算和公式应用。 | 知识层次: 题目需要应用临界核半径公式进行计算，涉及多个物理参数的代入和单位转换，属于多步计算和概念关联的中等应用层次。虽然不涉及复杂的综合分析或推理，但需要理解公式中各参数的含义及其相互关系。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式（临界核半径公式、温度转换等），涉及多步计算和概念关联（如表面能、潜热、温度差等），但未达到复杂多变量计算的程度。" + }, + { + "idx": 2058, + "question": "Point out the errors in the following concepts and correct them: (2) During metal crystallization, atoms transition from a disordered arrangement in the liquid phase to an ordered arrangement in the solid phase, which reduces the entropy of the system, making it a spontaneous process.", + "answer": "Reduces the free energy of the system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念错误并进行修正，需要文字解释和论述，而不是简单的选择或判断。答案也以文字形式呈现，解释了错误并提供了正确的表述。 | 知识层次: 题目考查对金属结晶过程中热力学基本概念的理解和记忆，主要涉及熵和自由能的变化，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求指出并纠正一个关于金属结晶过程中熵变化的错误概念，并给出正确答案。这需要学生对金属结晶的基本原理有一定的理解和记忆，能够识别并纠正错误表述，但不需要进行复杂的体系阐述或深入分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 2059, + "question": "Point out the errors in the following concept and correct them: (8) During the crystallization of certain castings, due to the faster cooling rate, the homogeneous nucleation rate N1 increases, and the heterogeneous nucleation rate N2 also increases. Therefore, the total nucleation rate is N=N1+N2.", + "answer": "Then the total nucleation rate is N=N2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案部分也提供了详细的解释说明，符合简答题的特征。 | 知识层次: 题目要求识别并纠正关于结晶过程中均匀成核和非均匀成核速率关系的错误概念，需要理解成核机制的基本原理，并能够分析不同成核方式之间的关系。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目要求对结晶过程中的成核速率概念进行多角度分析。需要理解均质成核和非均质成核的相互作用关系，并指出原概念的逻辑错误（简单相加的错误）。同时需要给出正确的结论（N=N2），这涉及到对成核机制的综合理解和应用。相比简单的概念辨析题（等级3），本题需要更深入的概念关联和错误分析能力，但尚未达到需要深度关联性分析的等级5水平。" + }, + { + "idx": 2060, + "question": "Point out the errors in the following concepts and correct them: (4) The maximum structural fluctuations appearing in the liquid phase at any temperature are nuclei.", + "answer": "Under a certain degree of undercooling (>ΔT*).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也是以文字形式给出的修正说明。 | 知识层次: 题目要求指出并纠正错误概念，涉及对液相中结构波动和成核条件的理解，需要将多个概念关联起来进行分析和判断。这超出了单纯记忆的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在简答题中属于较高难度，需要指出错误概念并进行修正，同时要求理解\"最大结构波动\"和\"晶核\"的概念及其在液相中的关系。题目还涉及特定条件（过冷度>ΔT*）的说明，需要多角度分析论述这些概念之间的关联。" + }, + { + "idx": 2061, + "question": "To obtain metallic glass, why is it generally necessary to choose binary systems with a steep liquidus line and thus a low eutectic temperature?", + "answer": "Metallic glass is obtained by ultra-rapid cooling methods, which suppress the liquid-solid crystallization process, resulting in an amorphous structure with exceptional properties. Glass is an undercooled liquid. This type of liquid has high viscosity and low atomic mobility, making crystallization difficult. For example, polymer materials (silicates, plastics, etc.) can achieve a glassy state under normal cooling conditions. Metals, however, are different. Due to the low viscosity of liquid metals, they rapidly crystallize when cooled below the liquidus line, thus requiring extremely high cooling rates (estimated >10^10 °C/s) to achieve a glassy state. To obtain metallic glass at lower cooling rates, the stability of the liquid must be increased, allowing it to exist over a wider temperature range. Experiments have shown that when the liquidus line is steep, resulting in a low eutectic temperature, the stability of the liquid is enhanced. Therefore, such binary systems (e.g., Fe-B, Fe-C, Fe-P, Fe-Si, etc.) are selected. To improve performance, other elements (e.g., Ni, Mo, Cr, Co, etc.) can be added. This type of metallic glass can be obtained at cooling rates of 10^5–10^6 °C/s.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在获得金属玻璃时通常需要选择具有陡峭液相线和低共晶温度的二元系统，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目不仅要求理解金属玻璃的基本概念和形成条件，还需要分析二元系统中液相线斜率与共晶温度的关系，以及如何通过选择特定系统来增强液体稳定性。这涉及到多步推理、概念关联和机理解释，属于复杂分析的层次。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用金属玻璃形成的多个关键概念（如液体稳定性、冷却速率、粘度、原子迁移率等），并需要深入解释二元系统选择与液体稳定性之间的机理关系。解题步骤涉及多个知识点的串联分析（从基本定义到实验现象再到性能优化），且需要引用具体合金体系作为例证。这种对复杂现象的全面分析和多层级推理要求，在简答题中属于最高难度等级。" + }, + { + "idx": 2062, + "question": "Point out the errors in the following concept and correct them: (5) The so-called critical nucleus is the size of the embryo when the decrease in the system's free energy fully compensates for the increase in surface free energy.", + "answer": "The decrease in the system's free energy should compensate for 2/3 of the surface free energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也是以文字形式给出修正后的正确概念。 | 知识层次: 题目要求识别并纠正关于临界核概念的错误表述，需要理解自由能变化与表面自由能之间的定量关系（2/3补偿关系），这超出了单纯记忆基本概念的范畴，属于需要将概念关联并进行定量分析的中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解临界核的概念，并能够指出原表述中的错误（自由能补偿比例错误），同时给出正确的补偿比例（2/3）。这要求学生对成核理论有较好的理解，并能进行概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2063, + "question": "Derive the K.A. Jackson equation formula", + "answer": "The so-called equilibrium structure of an interface refers to the most stable state of the interface under the condition of minimum interfacial energy. The essence of the problem is to analyze the relative change in interfacial free energy when the interface becomes rough. For this purpose, the following assumptions are made: (1) The equilibrium between the liquid and solid phases is under isothermal conditions; (2) The structures of the liquid and solid phases are identical near the interface; (3) Only configurational entropy is considered, while vibrational entropy is neglected. Let $N$ be the total number of atomic positions on the liquid-solid interface, with $n$ being the number of solid-phase atomic positions, and the occupation fraction $x=\\\\frac{n}{N}$; the vacancy fraction on the interface is $1-x$, and the number of vacancies is $N(1-x)$. The formation of vacancies causes changes in internal energy and structural entropy, leading to a corresponding change in surface Gibbs free energy: $$\\\\Delta G_{\\\\mathrm{s}}=\\\\Delta H-T\\\\Delta S=(\\\\Delta u+P\\\\Delta S)-T\\\\Delta S\\\\approx\\\\Delta u-T\\\\Delta S$$ The increase in internal energy due to the formation of $N(1-x)$ vacancies is determined by the product of the number of broken solid bonds and the bond energy of a pair of atoms. The change in internal energy is: $$\\\\Delta u=N\\\\xi L_{\\\\mathrm{~m~}}x(1-x)$$ Here, $\\\\boldsymbol{\\\\xi}$ is related to the crystal structure and is called the crystallographic factor. Next, the entropy change is calculated. From the definition of entropy change, we have: $$\\\\Delta S=k\\\\ln w=k\\\\ln\\\\frac{N!}{(N x)![N-(N x)]!}=k\\\\ln\\\\frac{N!}{(N x)![N(1-x)]!}$$ Using Stirling's approximation, when $N$ is large, we obtain: $$\\\\Delta S=-k N[x\\\\mathrm{ln}x+(1-x)\\\\mathrm{ln}(1-x)]$$ Finally, the total change in free energy on the liquid-solid interface is calculated as: $$\\\\Delta G_{\\\\mathrm{s}}=\\\\Delta u-T_{\\\\mathrm{m}}\\\\Delta S=N\\\\hat{\\\\xi}L_{\\\\mathrm{m}}x(1-x)+k T_{\\\\mathrm{m}}N[x\\\\mathrm{ln}x+(1-x)\\\\mathrm{ln}(1-x)]$$ Thus: $$\\\\frac{\\\\Delta G_{\\\\mathrm{S}}}{N k T_{\\\\mathrm{m}}}=\\\\frac{\\\\xi L_{\\\\mathrm{m}}}{k T_{\\\\mathrm{m}}}x(1-x)+x\\\\mathrm{ln}x+(1-x)\\\\mathrm{ln}(1-x)$$ $$\\\\alpha=\\\\frac{\\\\xi L_{\\\\mathrm{~m~}}}{k T_{\\\\mathrm{~m~}}}$$ Therefore: $$\\\\frac{\\\\Delta G_{\\\\mathrm{S}}}{N k T_{\\\\mathrm{m}}}=\\\\alpha x\\\\left(1-x\\\\right)+x{\\\\ln x+(1-x)\\\\ln(1-x)}$$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求推导K.A. Jackson方程公式，答案通过文字解释和数学推导详细论述了界面自由能变化的计算过程，符合简答题的特征。 | 知识层次: 题目要求推导K.A. Jackson方程，涉及多个假设条件、能量变化计算、熵变推导以及综合运用热力学和统计力学知识。需要深入理解界面自由能的概念，并能将内能变化与熵变结合起来进行综合分析。此外，还需要运用Stirling近似等数学工具，体现了较高的认知层次和复杂的思维过程。 | 难度: 在简答题-复杂分析题型中，该题目要求全面理解界面平衡结构的物理本质，涉及多个假设条件的建立、热力学参数的推导、熵变计算以及自由能变化的综合分析。解题过程需要运用统计热力学、晶体学知识和数学近似方法（如Stirling公式），步骤复杂且需要严谨的逻辑推导。这完全符合该题型下\"复杂现象全面分析\"的最高难度标准，要求考生具备深厚的理论基础和综合分析能力。" + }, + { + "idx": 2064, + "question": "Point out the errors in the following concepts and correct them: (6) In liquid metal, any embryo that emerges with a radius smaller than the critical nucleus radius cannot nucleate, but as long as there is sufficient energy fluctuation to provide the nucleation work, nucleation is still possible.", + "answer": "Nucleation cannot occur, even if there is sufficient energy fluctuation to provide it, nucleation still cannot occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断并纠正概念中的错误，答案直接指出了原陈述的错误并给出了正确说法，符合判断题的特征 | 知识层次: 题目考查对临界核半径和成核能等基本概念的理解和记忆，属于材料科学中相变基础知识的范畴 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目要求考生不仅能够识别基本概念的正误（如临界核半径的作用），还需要理解能量波动与成核可能性之间的逻辑关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念陈述（等级3）的程度。" + }, + { + "idx": 2065, + "question": "Point out the errors in the following concept and correct them: (7) Measuring the maximum undercooling during the crystallization of a pure metal casting, where the measured value is basically consistent with the calculated value using the formula ΔT=0.2Tm.", + "answer": "Measure the effective undercooling during homogeneous nucleation of a pure metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别并纠正关于纯金属结晶过程中最大过冷度测量和计算的错误概念，涉及对均质形核和有效过冷度的理解。这需要将理论公式与实际测量相结合，进行概念关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求不仅指出概念错误（最大过冷度测量），还需要纠正为均质形核的有效过冷度概念，并解释两者差异。这涉及多步分析：1)识别原始公式适用场景的局限性；2)理解均质/非均质形核的物理机制差异；3)建立熔化温度与临界形核过冷度的理论关联。相比基础概念辨析题（等级3），需要结合形核理论和实际测量条件进行多角度论述，但未达到需要引入界面能等深度参数分析的等级5要求。" + }, + { + "idx": 2066, + "question": "Point out the errors in the following concepts and correct them: (3) At any temperature, the maximum structural fluctuations appearing in liquid metals are all embryos.", + "answer": "In undercooled liquids, the maximum structural fluctuations appearing in liquid metals are all embryos.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出并纠正概念错误，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对液体金属中结构波动和胚胎概念的基本理解和记忆，属于基础概念的纠正和解释 | 难度: 在简答题中属于中等难度，需要对概念进行解释和描述，并指出错误之处进行修正。虽然涉及基础概念记忆，但需要一定的理解和分析能力，而不仅仅是简单的定义复述。" + }, + { + "idx": 2067, + "question": "Point out the errors in the following concepts and correct them: (14) During the growth of pure metals, regardless of whether the liquid-solid interface is rough or smooth, the liquid-phase atoms are connected one by one along the vertical direction of the solid-phase surface.", + "answer": "If the liquid-solid interface is rough, its liquid-phase atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对纯金属生长过程中液固界面原子连接方式的基本概念的理解和记忆，属于基础概念层面的知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求指出并纠正关于纯金属生长过程中液-固界面原子连接方式的错误概念，需要学生对界面粗糙度与原子连接方式的关系有基本理解，并能够准确描述正确的物理机制。这比单纯记忆定义(等级1)要求更高，但不需要进行复杂概念体系的阐述(等级3)，属于中等难度的概念解释题。" + }, + { + "idx": 2068, + "question": "Point out the errors in the following concepts and correct them: (10) From the calculation formula of heterogeneous nucleation work A_hetero = A_g(2-3cosθ+cos³θ), it can be seen that when the wetting angle θ=0°, the nucleation work for heterogeneous nucleation is the largest.", + "answer": "The nucleation work for heterogeneous nucleation is the smallest.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求指出概念错误并改正，本质上是对给定陈述的判断和修正，符合判断题的特征 | 知识层次: 题目考查对异质形核功公式的理解和记忆，需要判断在特定接触角条件下形核功的变化趋势，属于基础概念的记忆和理解范畴。 | 难度: 在判断题题型中，这道题目属于基本概念正误判断。题目直接考察对异质形核功公式的理解，只需要记忆公式中润湿角θ=0°时的结论即可判断正误，不需要复杂的推理或分析。属于该题型中最基础的难度等级。" + }, + { + "idx": 2069, + "question": "Point out the errors in the following concept and correct them: (12) Heterogeneous nucleation is always easier than homogeneous nucleation because the former uses foreign particles as the crystallization core, unlike the latter which forms an interface and causes an increase in free energy.", + "answer": "Because the former uses foreign particles as the substrate, the nucleation work is smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式呈现，解释了异质成核的优势原因。 | 知识层次: 题目要求指出并纠正关于异质成核和均质成核的错误概念，需要理解两种成核方式的区别及其自由能变化的原理。这涉及到概念的关联和综合分析，而不仅仅是基础概念的记忆。 | 难度: 在简答题中属于中等难度，需要理解并分析异质成核和均质成核的概念差异，指出原陈述中的错误并进行修正。虽然题目涉及的概念较为基础，但需要综合运用知识进行说明和论述，符合等级3的综合分析和说明要求。" + }, + { + "idx": 2070, + "question": "Point out the errors in the following concept and correct them: (11) In order to produce a batch of sand castings with significant thickness variations and require uniform grain size, it can be satisfied by merely adding nucleating agents in the process.", + "answer": "It can be satisfied by merely accelerating the cooling of thicker sections (such as adding chills) in the process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案提供了具体的修正建议，属于需要文字表述的解答方式。 | 知识层次: 题目要求指出并纠正一个关于铸造工艺的错误概念，涉及对晶粒尺寸控制和冷却速率调节的理解。这需要将多个概念（如成核剂的作用、冷却速率对晶粒尺寸的影响、厚薄截面差异处理）进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求不仅指出错误概念，还需要进行修正并提供合理的解释。这涉及到对铸造工艺中晶粒尺寸控制的多方面理解，包括冷却速率、成核剂的作用以及不同厚度截面的处理方式。需要考生综合运用知识进行分析论述，比单纯的概念解释（等级3）更复杂，但尚未达到需要深度关联多个学科知识的等级5难度。" + }, + { + "idx": 2071, + "question": "Point out the errors in the following concepts and correct them: (13) When studying the process of refining grains in a certain metal, the main focus is to find nucleating agents with low melting points and lattice constants similar to those of the metal, as their nucleation catalytic efficiency is the highest.", + "answer": "The main focus is to find those with high melting points, and.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出概念中的错误并改正，这类似于判断题中判断陈述的对错并给出正确说法。答案部分直接指出了原陈述的错误并提供了正确的表述，符合判断题的特征。 | 知识层次: 题目考查对晶粒细化过程中形核剂选择的基本概念的理解和记忆，涉及形核剂的熔点和晶格常数等基本特性，属于基础概念的记忆和判断。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目要求判断关于晶粒细化过程中成核剂选择标准的陈述是否正确，并指出错误之处。这需要考生对晶粒细化原理和成核剂选择标准有基本的理解和记忆，但不需要进行复杂的分析或推理。因此，该题目在判断题题型中属于中等难度（等级2）。" + }, + { + "idx": 2072, + "question": "Point out the errors in the following concept and correct them: (9) If 10,000 nucleation agents are added to an undercooled liquid, then 10,000 grains will form after crystallization.", + "answer": "then tens of thousands of grains will form after crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对成核剂作用的基本概念的理解，需要纠正一个常见的误解，即每个成核剂不一定对应一个晶粒。这属于基础概念的记忆和理解层面，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。虽然题目涉及基础概念记忆，但需要学生理解成核剂的作用机制，并能够指出原始陈述中的错误（将成核剂数量与晶粒数量简单等同的错误假设）。这比单纯复述定义（等级1）要求更高，但不需要构建复杂的概念体系（等级3）。" + }, + { + "idx": 2073, + "question": "Point out the errors in the following concepts and correct them: (18) When a nucleation agent is added to liquid pure metal, its growth morphology always appears dendritic.", + "answer": "Its growth morphology will not change.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对成核剂添加后金属生长形态变化的基本概念的理解和记忆，属于基础概念层面的知识。 | 难度: 在简答题中属于概念解释和描述难度，需要理解成核剂对纯金属生长形态的影响，并指出错误概念。虽然涉及基础概念记忆，但需要一定的解释能力，比单纯的定义简答（等级1）稍复杂，但不需要复杂概念体系阐述（等级3）。" + }, + { + "idx": 2074, + "question": "Point out the errors in the following concepts and correct them: (15) Regardless of the temperature distribution, common pure metals always grow with a dendritic interface.", + "answer": "Only under negative temperature gradient conditions, common pure metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对纯金属生长形态基础概念的理解和记忆，仅需识别并纠正关于枝晶生长条件的错误表述，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，需要理解并解释纯金属生长条件的基本概念，但不需要复杂的体系阐述或深入分析。题目要求指出错误并修正，涉及对温度梯度与金属生长关系的理解，属于概念解释和描述的范畴。" + }, + { + "idx": 2075, + "question": "Point out the errors in the following concept and correct them: (17) It is impossible to observe the dendritic growth process of extremely pure metals, so the dendritic growth morphology is merely a speculation.", + "answer": "The growth process can be observed through experimental methods, such as pouring off the remaining liquid of the crystallizing metal or performing overall quenching, so the dendritic growth morphology is not a speculation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求指出并纠正一个关于金属枝晶生长观察的错误概念，需要理解枝晶生长的基本原理以及相关的实验方法（如淬火技术）。这涉及到对概念的理解和应用，以及将理论知识与实验技术相结合的能力，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求指出并纠正一个错误概念，需要学生具备对金属结晶过程中枝晶生长观察方法的理解。虽然涉及实验方法的描述，但不需要多角度或深度关联性分析，主要考察对基础概念的理解和简单应用能力。解题步骤相对直接，只需说明实验观察方法并纠正错误观点即可。" + }, + { + "idx": 2076, + "question": "Point out the errors in the following concepts and correct them: (16) The microstructure morphology of a saturated aqueous solution of ammonium chloride and pure metal at the end of crystallization is the same, with the former exhibiting dendritic crystals and the latter also exhibiting dendritic crystals.", + "answer": "The microstructure morphology at the end of crystallization is different; the former exhibits dendritic crystals (with water between the branches), while the latter exhibits individual (blocky) grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行改正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式呈现，解释了两种结晶形态的不同之处。 | 知识层次: 题目考查对结晶过程中微观结构形态的基础概念理解，需要区分不同物质在结晶结束时的形态差异，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求指出并纠正关于结晶过程微观结构形态的错误概念，需要学生对两种不同结晶过程（饱和溶液与纯金属）的微观结构差异有清晰的理解和描述。虽然涉及基础概念记忆，但需要一定的解释和对比分析能力，比单纯的定义简答（等级1）要求更高，但不需要复杂的概念体系阐述（等级3）。" + }, + { + "idx": 2077, + "question": "In the Al-Mg alloy, $x_{\\\\mathrm{Mg}}=0.05$, calculate the mass fraction of Mg ($w_{\\\\mathrm{Mg}}$) in the alloy (given that the relative atomic mass of Mg is 24.31 and Al is 26.98).", + "answer": "$w_{\\\\mathrm{Mg}}=0.0453$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算镁的质量分数），并给出了具体的原子质量和摩尔分数，需要使用公式进行推导和计算。答案也是一个具体的数值结果。 | 知识层次: 题目涉及基本的摩尔分数与质量分数的转换计算，仅需套用简单公式即可完成，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用质量分数的基本公式进行计算，无需多个公式组合或复杂的解题步骤。给定的摩尔分数和相对原子质量可以直接套用公式得出结果，属于该题型内最基础的难度水平。" + }, + { + "idx": 2078, + "question": "Point out the errors in the following concepts and correct them: (21) Pure metal crystallization grows in a dendritic morphology or a planar morphology, which is unrelated to the melting entropy of the metal.", + "answer": "Because it is also related to the structure of the liquid-solid interface (α=ξΔSm/k), i.e., it is related to the melting entropy of the metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释来纠正错误概念。 | 知识层次: 题目要求指出概念错误并进行修正，涉及对金属结晶形态与熔化熵关系的理解，需要将多个概念（如液-固界面结构、熔化熵等）进行关联分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求不仅指出概念错误，还需要解释错误原因并给出正确表述，涉及液体-固体界面结构（α=ξΔSm/k）与熔化熵的关系。这需要学生综合理解晶体生长形态与热力学参数的内在联系，并能够进行多步骤的概念关联分析，比单纯的概念辨析题（等级3）要求更高，但尚未达到需要建立复杂理论模型的深度关联性分析（等级5）。" + }, + { + "idx": 2079, + "question": "Point out the errors in the following concepts and correct them: (20) From a macroscopic perspective, if the liquid-solid interface is straight, it is called a smooth interface structure; if it is zigzag like metal, it is called a rough interface structure.", + "answer": "The straight one is called a rough interface structure; the zigzag one is called a smooth interface structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出并纠正概念错误，需要文字解释和论述，而不是简单的选择或判断。答案也提供了详细的文字解释来纠正错误概念。 | 知识层次: 题目考查对液体-固体界面结构基本概念的记忆和理解，需要区分平滑界面和粗糙界面的定义，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求指出并纠正关于液体-固体界面结构的错误概念，这需要学生对平滑界面和粗糙界面的定义有清晰的理解，并能准确区分两者的特征。虽然题目涉及基础概念的记忆，但需要学生进行一定的解释和描述，而不仅仅是简单的定义复述。因此，该题目在简答题题型中属于中等难度。" + }, + { + "idx": 2080, + "question": "Point out the errors in the following concepts and correct them: (23) During metal crystallization, the dynamic undercooling required for crystal growth is sometimes greater than the critical undercooling required for nucleation.", + "answer": "The dynamic undercooling is smaller than the critical undercooling required for nucleation.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断并纠正错误概念，答案直接指出原陈述的错误并给出正确表述，符合判断题的特征 | 知识层次: 题目考查金属结晶过程中动态过冷度和临界过冷度的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目涉及金属结晶过程中动态过冷度和临界过冷度的比较，需要学生对这两个概念有清晰的理解才能正确判断。虽然不涉及复杂概念的判断，但比单纯记忆定义的基本概念正误判断（等级1）要求更高，需要理解概念之间的关系。" + }, + { + "idx": 2081, + "question": "Point out the errors in the following concepts and correct them: (22) During the crystallization of actual metals, the nucleation rate increases with the increase of undercooling, and after exceeding a certain maximum value, the opposite change occurs.", + "answer": "increases, but due to the limited undercooling capacity of metals, it does not exceed a certain maximum value.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式呈现，解释了概念的正确理解。 | 知识层次: 题目要求指出并纠正关于金属结晶过程中形核率与过冷度关系的错误概念，需要理解形核率随过冷度变化的规律，并能够分析实际金属结晶过程中的限制因素。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于中等难度，需要理解金属结晶过程中的成核速率与过冷度的关系，并能够指出错误并进行修正。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2082, + "question": "Should high carbon steel or low carbon steel be used to manufacture automobile fenders?", + "answer": "High carbon steel. Because high carbon steel has high strength and can withstand greater impact force without deformation. In contrast, low carbon steel is softer and more prone to deformation under force.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述为什么选择高碳钢而不是低碳钢来制造汽车挡泥板，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求对不同类型碳钢的性能进行比较分析，并基于实际应用场景（汽车挡泥板）做出材料选择决策。这需要理解碳含量与材料性能的关系，并能将材料特性与实际工程需求进行关联分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对高碳钢和低碳钢的性能进行比较分析，但只需要从强度和抗变形能力两个主要方面进行论述即可，不需要涉及更复杂的多角度分析或深度关联性分析。解题步骤相对直接，符合等级3的综合分析和说明要求。" + }, + { + "idx": 2083, + "question": "At 800°C, which phases exist in Fe-0.002C steel?", + "answer": "α phase, γ phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别在特定温度下存在的相，答案需要列出具体的相名称（α phase, γ phase），属于需要简短回答的简答题类型。 | 知识层次: 题目考查对铁碳相图中不同温度下相组成的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆铁碳相图中特定温度下的相组成，无需解释或推导过程。" + }, + { + "idx": 2084, + "question": "Calculate the relative amounts of secondary cementite, eutectic cementite, and eutectoid cementite in ledeburite", + "answer": "In ledeburite, the relative amount of Fe_3C_I is 10.15%, the relative amount of Fe_3C_3tan is 41.21%, and the relative amount of eutectoid Fe:C is 3.9%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算特定成分的相对含量，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要计算不同形态的渗碳体在莱氏体中的相对含量，涉及多步计算和概念关联，需要理解并应用相图和相关公式，属于中等应用层次。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要理解ledeburite的组成结构，区分不同类型的cementite（二次渗碳体、共晶渗碳体和共析渗碳体），并应用相关相图知识进行多步计算。虽然计算过程不涉及复杂变量，但需要对多个概念进行关联分析，综合运用相图知识和定量计算能力，因此在计算题的中等应用层次中属于中等偏上难度。" + }, + { + "idx": 2085, + "question": "Calculate the relative amounts of cementite and ferrite in the pearlite microstructure", + "answer": "In pearlite, the relative amount of F is 9.38%, and the relative amount of Fe_3C_## is 1.22%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算珠光体微观结构中渗碳体和铁素体的相对含量，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及相对简单的计算步骤和直接套用公式，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用杠杆定律（lever rule）来计算珠光体中铁素体和渗碳体的相对含量，无需多个公式组合或复杂计算步骤。" + }, + { + "idx": 2086, + "question": "In the Al-Cu phase diagram, given $K=0.16$, $m=3.2$. If the solidification rate of the casting is $R=3\\\\times10^{-4}~\\\\mathrm{cm/s}$, the temperature gradient is $G=30^{\\\\circ}\\\\mathrm{C}/\\\\mathrm{cm}$, and the diffusion coefficient is $D=3\\\\times10^{-5}~\\\\mathrm{cm}^{2}/\\\\mathrm{s}$, find the extreme value of $\\\\scriptstyle{\\\\mathcal{W}}_{\\\\mathrm{Cu}}$ in the alloy that maintains planar interface growth.", + "answer": "$w_{\\\\mathrm{Cu}}^{\\\\mathrm{C}_{0}}=\\\\frac{G D}{R m}\\\\frac{K}{1-K}=0.1744$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出一个具体的数值结果。答案是一个计算得出的数值，而不是选择、判断或文字解释。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、凝固速率、温度梯度等概念，并综合应用公式进行计算，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式和参数进行多步计算，涉及相图、扩散系数、温度梯度等概念的关联分析，但尚未达到复杂多变量计算的程度。" + }, + { + "idx": 2087, + "question": "Point out the errors in the following concept and correct them: (19) When a pure metal crystallizes and grows vertically, its interface is sometimes smooth and sometimes rough, growing alternately.", + "answer": "The interface is of the rough type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对金属结晶界面类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要理解并解释金属结晶界面类型的概念，并指出题目中的错误。虽然不涉及复杂的概念体系阐述，但需要一定的概念解释和描述能力，比单纯的基本定义简答要难一些。" + }, + { + "idx": 2088, + "question": "Based on microstructural analysis, the volume of graphite in a gray cast iron accounts for 12%, and the volume of ferrite accounts for 88%. Determine the value of ωC (given that the density of graphite ρG=2.2 g/cm³, and the density of ferrite ρα=7.8 g/cm³).", + "answer": "ωC=0.037.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ωC的值，答案是一个具体的数值结果。解答过程需要运用给定的密度数据和体积百分比进行计算，符合计算题的特征。 | 知识层次: 题目涉及基本的体积分数和密度计算，需要应用给定的公式进行简单的数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用密度和体积分数的基本公式来计算碳的质量分数，但仅涉及单一公式的直接应用和简单代数运算，无需多个公式组合或复杂推导。" + }, + { + "idx": 2089, + "question": "Calculate the relative amounts of pearlite, secondary cementite, and ledeburite in the microstructure of an iron-carbon alloy with a carbon content of w_c=0.04 after metastable cooling to room temperature.", + "answer": "In the microstructure, the relative amount of P is 10.6%, the relative amount of Fe_3C_∥ is 3.10%, and the relative amount of L_d′ is 86.3%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算铁碳合金中珠光体、二次渗碳体和莱氏体的相对含量，需要通过数值计算和公式应用来得出具体百分比结果。答案也以具体数值形式呈现，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及铁碳合金相图中不同相的相对含量计算，需要理解相图的基本原理并应用杠杆定律进行综合分析。虽然不涉及复杂的机理分析或创新应用，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆定律进行多步计算，涉及多个相（珠光体、二次渗碳体、莱氏体）的相对含量计算，并需要理解铁碳相图的相关概念。虽然计算步骤较多，但属于典型的相图应用问题，在同类题型中属于中等偏上的难度。" + }, + { + "idx": 2090, + "question": "At 800°C, what are the compositions of the α phase and γ phase in Fe-0.002C steel?", + "answer": "α: wC=0.0001, wFe=0.9999; γ: wC=0.0046, wFe=0.9954.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算在特定温度下Fe-0.002C钢中α相和γ相的组成，需要应用相图和相关公式进行数值计算，答案以具体数值形式给出。 | 知识层次: 题目需要应用铁碳相图的基本知识，通过查图或简单计算确定两相的成分，属于基本公式应用和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目要求根据给定的温度（800°C）和钢的成分（Fe-0.002C），直接从相图中读取或应用简单的相平衡公式得出α相和γ相的成分。解题步骤简单，仅需基本的相图知识或简单公式应用，无需复杂的计算或公式组合。" + }, + { + "idx": 2091, + "question": "How to obtain the mass and Cu content of solid α3 by heating solid α2 to melting and slowly cooling it to 920°C, then pouring off the liquid?", + "answer": "Reheat α2 to melting, slowly cool to 920°C, pour off the liquid, leaving only α3, with a mass of 260g and w_Cu≈0.02.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字描述如何通过加热和冷却过程获得特定成分的固体α3，并给出其质量和铜含量。答案提供了详细的步骤和结果，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及多步操作（加热、冷却、倾倒）和综合分析（确定α3的质量和Cu含量），需要理解相变过程和成分变化，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及多步操作（加热、冷却、倾倒液体）和综合计算（质量与铜含量），但解题步骤相对明确，且答案可以直接从题目描述中推导得出。题目要求对相图概念和物质分离过程有一定理解，但不需要进行过于复杂的多角度分析或深度关联性分析。因此，在简答题的框架内，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 2092, + "question": "How to obtain the mass and Cu content of solid α4 by heating solid α3 to melting and slowly cooling it to 935°C before pouring off the liquid?", + "answer": "Heat α3 to melting again, slowly cool it to 935°C, pour off the liquid, leaving only α4, with a mass of 180g and a Cu content of w_Cu≈0.013.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来描述如何通过加热和冷却过程获得固体α4的质量和铜含量，答案也以文字形式详细说明了操作步骤和结果。 | 知识层次: 题目涉及多步操作（加热、冷却、倾倒液体）和综合分析（计算质量和Cu含量），需要理解相图概念并将其应用于具体情境，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并应用相图知识进行多步计算和综合分析。题目要求通过加热、冷却和分离步骤来获取特定固体的质量和成分，涉及对相变过程的理解和实际操作步骤的描述。虽然需要一定的概念关联和计算能力，但解题步骤相对明确，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2093, + "question": "Assuming the Cu content in α phase at 100°C can be considered zero, calculate how many copper atoms are present in each θ particle, given that the atomic radius of Al is 0.143 nm.", + "answer": "Approximately 150 Cu atoms per θ particle.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算每个θ粒子中的铜原子数量），并给出了具体的物理参数（Al的原子半径），最终答案是一个具体的数值（约150个铜原子）。这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及原子半径和相组成的关联分析，需要综合运用材料科学中的相图和晶体结构知识，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要结合相图知识、原子半径计算和单位转换等多步骤计算过程，同时涉及概念关联和综合分析能力。虽然不需要处理复杂多变量，但解题步骤和知识整合要求较高。" + }, + { + "idx": 2094, + "question": "How to obtain the mass and Cu content of solid α2 by heating solid α1 to melting, slowly cooling to 900°C, and pouring off the liquid?", + "answer": "Heat the solid (α1) in (1) to melting, slowly cool to 900°C, pour off the liquid, and the remaining solid α2 has a weight of 390g with w_Cu≈0.03.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来描述如何通过加热、冷却和倒出液体来获得固体α2的质量和铜含量，答案提供了具体的步骤和结果，属于简答题类型。 | 知识层次: 题目涉及多步操作（加热、冷却、倾倒）和综合分析（计算质量百分比），需要理解相变过程和成分变化，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及多步操作（加热、冷却、分离）和计算（质量与铜含量），但整体解题思路较为直接，主要考察对相变过程的理解和基本计算能力。不需要进行多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 2095, + "question": "At 800°C, what are the fractions of α phase and γ phase in Fe-0.002C steel?", + "answer": "nα=0.58, nγ=0.42.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算在800°C下Fe-0.002C钢中α相和γ相的比例，答案给出了具体的数值结果（nα=0.58, nγ=0.42），这表明需要通过数值计算和相图应用来解答问题。 | 知识层次: 题目需要应用铁碳相图和相关公式进行多步计算，涉及相平衡的概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析铁碳合金在特定温度下的相组成。虽然计算步骤明确，但需要正确关联多个概念才能得出准确结果。" + }, + { + "idx": 2096, + "question": "A eutectic reaction in the Mg-Ni system is given by $$ \\\\operatorname{L}_{w_{\\\\mathrm{Ni}}=0.235}\\\\frac{570^{\\\\circ}\\\\mathrm{C}}{\\\\Longleftarrow}\\\\alpha_{(\\\\#\\\\mathbb{M}_{\\\\operatorname{g}})}+\\\\mathrm{Mg}_{2}\\\\mathrm{Ni}_{w_{\\\\mathrm{Ni}}=0.546} $$ Let $\\\\omega_{\\\\mathrm{Ni}}^{1}=C_{1}$ be a hypoeutectic alloy and $\\\\boldsymbol{w_{\\\\mathrm{Ni}}^{2}}=C_{2}$ be a hypereutectic alloy. The mass fraction of the proeutectic phase in these two alloys is equal, but the total amount of $\\\\upalpha$ in alloy $\\\\mathrm{C}_{1}$ is 2.5 times that in alloy $\\\\mathrm{C}_{2}$. Calculate the compositions of $\\\\mathrm{C}_{1}$ and $\\\\mathrm{C}_{2}$.", + "answer": "The composition of alloy $C_{1}$ is $w_{\\\\mathrm{Mg}}=0.873$, $w_{\\\\mathrm{Ni}}=0.127$. The composition of alloy $\\\\mathrm{C}_{2}$ is $w_{\\\\mathrm{Mg}}=0.66,w_{\\\\mathrm{Ni}}=0.368$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定两种合金的组成，答案给出了具体的数值结果，解答过程需要运用相图计算和质量分数等材料科学知识。 | 知识层次: 题目涉及多步计算和概念关联，需要理解共晶反应的基本原理，并应用杠杆定律进行质量分数的计算。虽然不涉及复杂的推理分析或机理解释，但需要综合分析合金成分与相组成之间的关系，属于中等应用层次。 | 难度: 在计算题中属于复杂多变量计算难度，需要综合运用杠杆定律、相图分析以及多步代数运算。题目涉及：" + }, + { + "idx": 2097, + "question": "If there is a certain Cu-Ag alloy (w_Cu=0.075, w_Ag=0.925) weighing 1000g, how can the mass of solid α1 and its Cu content be obtained by heating it above 900°C to melt, then slowly cooling to 850°C and pouring off the liquid part?", + "answer": "When 1000g of this alloy is heated above 900°C to melt, then slowly cooled to 850°C and the liquid part is poured off, the remaining solid α1 weighs 780g with a w_Cu≈0.055.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算固体α1的质量和铜含量），并应用相图相关知识来解答，最终给出具体的数值结果。 | 知识层次: 题目涉及多步计算（相图应用、杠杆定律计算、成分分析），需要理解Cu-Ag合金相图的基本原理并应用杠杆定律进行具体计算，属于中等难度的应用题型。虽然不涉及复杂的机理分析或创新设计，但需要综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括质量平衡和成分计算），并综合分析冷却过程中的相变行为。虽然不涉及复杂多变量计算，但要求对合金相变过程有较深理解，属于中等偏上的难度。" + }, + { + "idx": 2098, + "question": "Under equilibrium cooling conditions, a carbon steel obtains a microstructure containing 50% pearlite and 50% ferrite. What is the mass fraction of carbon in this alloy?", + "answer": "x=wC=0.385", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解碳的质量分数，答案是一个具体的数值结果（x=wC=0.385），这表明解答过程涉及计算步骤而非选择或判断。 | 知识层次: 题目需要应用铁碳相图的知识，通过珠光体和铁素体的比例反推碳含量，涉及多步计算和相图分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图、杠杆定律的应用，并进行多步计算。虽然不涉及复杂多变量，但需要将多个概念关联起来综合分析。" + }, + { + "idx": 2099, + "question": "14. At 550°C, an aluminum-copper alloy solid solution with composition x_Cu=0.02 is quenched and then reheated to 100°C to precipitate θ phase (CuAl2). The θ phase forms many small particles dispersed in the alloy with an average particle spacing of 5.0 nm. Approximately how many particles are formed in 1 mm³ of the alloy?", + "answer": "Approximately 8×10^24 particles/m³ (equivalent to 8×10^15 particles/mm³).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算1 mm³合金中形成的θ相颗粒数量），答案以具体数值形式给出，且涉及单位换算（从m³到mm³），这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算，包括理解固溶体成分、析出相的形成和分布，以及应用粒子间距计算粒子数量的公式。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和进行数值计算。 | 难度: 在计算题中属于综合性计算问题，需要理解固溶体、相变和析出相的概念，进行多步计算（包括粒子间距与体积浓度的转换），并应用适当的公式来估算粒子数量。虽然计算步骤明确，但涉及多个物理概念的关联和综合分析，属于中等偏上的难度。" + }, + { + "idx": 2100, + "question": "A carbon steel, under equilibrium cooling conditions, obtains a microstructure consisting of 50% pearlite and 50% ferrite. Question: If this alloy is heated to 730°C, what microstructure will be obtained under equilibrium conditions?", + "answer": "The microstructure will be F+A", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定温度下材料的微观结构变化，答案需要文字描述（F+A表示铁素体和奥氏体的混合结构），属于需要简要说明的简答题类型。 | 知识层次: 题目需要理解铁碳相图的基本原理，并能够应用相图分析特定温度下的相组成。虽然不涉及多步计算，但需要将概念关联起来进行综合分析，判断在730°C时的相组成。这超出了简单记忆或直接套用的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在简答题中属于中等难度，需要理解铁碳相图、平衡冷却和加热条件下的相变过程，并进行综合分析。虽然涉及多步概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2101, + "question": "Under equilibrium cooling conditions, a carbon steel obtains a microstructure consisting of 50% pearlite and 50% ferrite. If it is heated to 850°C, what microstructure will be obtained?", + "answer": "Entirely austenite (A) microstructure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定温度下材料的微观结构变化，答案需要文字描述（Entirely austenite (A) microstructure），而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目需要理解铁碳相图的基本原理，并能够根据给定的条件（50%珠光体和50%铁素体）推断出钢的碳含量。然后，需要应用相图知识分析在850°C加热时的相变过程，得出完全奥氏体化的结论。这涉及多步推理和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及多步计算和概念关联（如平衡冷却条件、相变温度、微观结构变化等），但解题步骤相对直接，主要需要考生理解相图的基本原理和钢在加热过程中的相变行为。题目要求综合分析初始条件和加热后的结果，但不需要进行多角度或深度关联性分析。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 2102, + "question": "Point out the errors in the following concept and correct them: Repeatedly 'melting and solidifying' a solid solution alloy rod and using directional rapid solidification can effectively purify the metal.", + "answer": "Repeatedly perform zone melting and use directional slow solidification.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别和纠正关于金属纯化方法的错误概念，涉及对区域熔炼和定向凝固原理的理解和应用。需要将基础概念与实际操作相结合，进行多步骤的分析和判断，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求不仅指出错误概念，还需要进行纠正并解释原理。这涉及对区域熔炼和定向凝固技术的深入理解，需要综合分析材料纯化过程中的热力学和动力学因素。相比只需简单概念辨析的题目（等级3），本题需要多角度论述技术原理和操作要点，属于较高难度的应用分析题。" + }, + { + "idx": 2103, + "question": "Point out the errors in the following concept and correct them: Although the crystallization rate of solid solution alloys is very fast, at a certain moment during solidification, the chemical potentials of components A and B in the liquid and solid phases are equal.", + "answer": "At the phase interface, the chemical potentials of components A and B in the liquid and solid phases are equal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求指出并纠正关于固溶体合金结晶速率和化学势平衡的错误概念，这需要深入理解相变过程中的热力学平衡条件，并能够分析化学势在液固两相中的平衡关系。这涉及到对相变机理的综合分析和推理，属于复杂分析的层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求学生不仅能够识别概念错误，还需要准确理解并阐述相平衡时化学势相等的条件，这涉及到对相变热力学原理的深入掌握。虽然题目本身表述较为简洁，但需要学生具备扎实的理论基础和逻辑推理能力，能够准确指出错误并给出正确的表述。相较于更简单的概念辨析题，该题目对知识点的掌握深度要求更高，但尚未达到需要全面分析复杂现象的最高难度。" + }, + { + "idx": 2104, + "question": "Point out the errors in the following concepts and correct them: In the solid solution alloy, whether during equilibrium or non-equilibrium crystallization, the liquid phase composition at the liquid-solid interface changes along the average liquid composition line; the solid phase composition changes along the average solid composition line.", + "answer": "The liquid phase composition at the liquid-solid interface changes along the liquidus line; the solid phase composition changes along the solidus line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出并纠正概念中的错误，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式呈现，解释了正确的概念。 | 知识层次: 题目要求识别并纠正关于固溶体合金结晶过程中液相和固相成分变化路径的错误概念，需要理解平衡和非平衡结晶的基本原理，并能够将液相线和固相线的概念与实际变化路径关联起来。这涉及到对相图知识的应用和综合分析，而不仅仅是基础概念的记忆。 | 难度: 在简答题中属于中等难度，需要理解并分析固溶体合金结晶过程中液固界面成分变化的规律，指出错误概念并给出正确表述。虽然涉及多个概念（平衡/非平衡结晶、液固界面成分变化、液相线和固相线），但不需要进行多角度或深度关联性分析，主要考察对基本概念的理解和正确应用。" + }, + { + "idx": 2105, + "question": "Point out the errors in the following concepts and correct them: On the eutectic line, the lever rule can be used to calculate the relative amount of the eutectic. Since the eutectic line belongs to the three-phase region, the lever rule is not only applicable to the two-phase region but also to the three-phase region.", + "answer": "However, the lever rule is only applicable to the two-phase region, so the relative amount of the eutectic is actually calculated in the two-phase region.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断并纠正错误概念，答案明确指出原陈述的错误并给出正确解释，符合判断题的特征 | 知识层次: 题目考查对杠杆规则适用范围的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断。虽然题目涉及杠杆定律的应用范围这一基础概念，但需要考生理解杠杆定律仅适用于两相区而非三相区这一具体规则。相比单纯记忆定义的等级1题目，此题需要更深一层的概念理解，但尚未达到需要分析复杂概念陈述的等级3难度。" + }, + { + "idx": 2106, + "question": "Point out the error in the following concept and correct it: In the directional solidification process of a solid solution alloy rod, the faster the liquid-solid interface advances, the more severe the macrosegregation in the rod.", + "answer": "the less severe the macrosegregation in the rod.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个概念陈述的对错，并给出正确的表述。这符合判断题的特征，即判断陈述的正确性并给出修正。答案形式也是直接指出错误并给出正确表述，不需要选择或计算。 | 知识层次: 题目考查对定向凝固过程中宏观偏析形成机理的理解和应用，需要将凝固速率与偏析程度的关系进行综合分析，属于中等应用层次的知识。 | 难度: 在判断题题型中，此题属于综合分析结果判断难度。题目要求不仅需要识别出原陈述的错误（多步过程判断），还需要基于对定向凝固过程和宏观偏析形成机理的深入理解，推导出正确的结论（液体-固体界面推进速度与宏观偏析严重程度的反向关系）。这涉及到对凝固动力学和溶质再分配原理的综合应用，超越了简单的正误判断，属于该题型中较高难度的题目。" + }, + { + "idx": 2107, + "question": "Given the solid solubility equation of carbon in α-Fe in equilibrium with cementite as $$ w_{\\mathrm{C}}^{\\alpha}=2.55\\exp{\\frac{-11.3\\times10^{3}}{R T}} $$, assuming the solid solubility equation of carbon in austenite is similar to this equation, write this equation based on the Fe-Fe3C phase diagram.", + "answer": "Let the solid solubility equation of C in γ be $$ w_{\\mathrm{c}}^{\\gamma}=A\\exp\\bigl(-\\frac{Q}{R T}\\bigr) $$ Taking the logarithm of both sides, we get $$ \\ln w_{\\mathrm{c}}^{\\gamma}=\\ln A-\\frac{Q}{R T} $$ From the Fe-Fe3C phase diagram, we have $\\ln0.77=\\ln A-{\\frac{Q}{R\\times1000}}$ $$ \\ln2.11=\\ln A-{\\frac{Q}{R\\times1~421}}\\quad. $$ Combining these two equations, we obtain $Q=28\\mathrm{kJ}$, $A=22,3$, thus $$ w_{\\mathrm{c}}^{\\mathrm{r}}=22.3\\exp\\Bigl(-\\frac{2.8\\times10^{3}}{R T}\\Bigr) $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的固溶度方程和Fe-Fe3C相图，通过数学推导和计算得出新的固溶度方程。解答过程中涉及对数运算、方程联立求解以及参数确定，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和公式应用，需要从给定的固溶度方程出发，结合Fe-Fe3C相图的数据进行推导和计算。虽然题目给出了部分方程形式，但需要学生理解并应用对数变换、联立方程求解等数学工具，以及理解相图中的关键点（如0.77和2.11的含碳量）与方程参数的关系。这超出了简单套用公式的范畴，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解Fe-Fe3C相图的相关知识，进行多步计算和公式应用，包括对数变换、联立方程求解等步骤。虽然不涉及复杂多变量计算，但需要综合分析能力和对相图数据的准确理解。" + }, + { + "idx": 2108, + "question": "Point out the incorrect concept and correct it: In solid solution grains, dendritic segregation exists, the composition of the main axis differs from that of the interdendritic regions, so the entire grain is not a single phase.", + "answer": "Therefore, the entire grain is a single phase.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出错误概念并纠正，类似于判断陈述的对错并给出正确说法 | 知识层次: 题目考查对固溶体晶粒中枝晶偏析和单相概念的基本理解，属于基础概念的记忆和判断。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目要求识别并纠正关于固溶体晶粒中枝晶偏析的错误概念，需要理解枝晶偏析对晶粒相组成的影响。虽然涉及基础概念，但需要一定的理解深度来正确判断和纠正错误陈述，因此属于等级2。" + }, + { + "idx": 2109, + "question": "Point out the incorrect concept and correct it: In Ni-Cu alloy castings with uneven thickness, thin sections tend to form dendritic structures after crystallization, while thick sections tend to form cellular structures.", + "answer": "After crystallization, thin sections tend to form cellular structures, while thick sections tend to form dendritic structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出错误概念并进行纠正，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求识别并纠正Ni-Cu合金铸造中结晶结构形成的错误概念，涉及对结晶过程中冷却速率与微观结构关系的理解。这需要将基础概念（如枝晶和胞状结构的形成条件）与实际应用（不同截面厚度对冷却速率的影响）相结合，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解Ni-Cu合金铸造过程中不同厚度截面的结晶结构差异，并能准确指出错误概念并进行修正。这涉及到对结晶过程中冷却速率与微观结构关系的理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2110, + "question": "Point out the incorrect concept and correct it: Using circulating water to cool the metal mold is beneficial for obtaining a columnar crystal zone to improve the compactness of the casting.", + "answer": "It is not beneficial for obtaining a columnar crystal zone.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个概念的正确性（\"Point out the incorrect concept and correct it\"），并给出正确判断（\"It is not beneficial for obtaining a columnar crystal zone\"），这符合判断题的特征。 | 知识层次: 题目考查对金属铸造过程中柱状晶区形成条件的基础概念记忆和理解，属于基本原理的记忆性知识范畴。 | 难度: 在判断题题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（金属铸造中的晶体结构形成），但需要考生理解\"柱状晶区\"的形成条件与冷却方式的关系，并能够判断\"循环水冷却金属模具\"对柱状晶区形成的实际影响。这比简单判断定义正误（等级1）要求更高的概念理解，但尚未达到需要分析复杂概念陈述（等级3）的程度。" + }, + { + "idx": 2111, + "question": "Point out the error in the following concept and correct it: In the Fe-Fe3C system alloys, only hypereutectoid steels have secondary cementite in their equilibrium crystallization structure.", + "answer": "Only when the iron-carbon alloy with a carbon mass fraction of 0.0077 < w_c < 0.043 undergoes equilibrium crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字解释来纠正错误概念。 | 知识层次: 题目要求识别并纠正一个关于Fe-Fe3C系统合金中二次渗碳体形成的错误概念，需要理解不同碳含量范围内的相变行为，并能够将概念关联到具体的碳含量范围。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目要求考生不仅能够识别概念错误，还需要准确修正并给出具体的碳含量范围。这涉及到对Fe-Fe3C相图的深入理解、平衡结晶过程的分析，以及不同碳含量合金的组织特征的综合判断。解题步骤包括错误识别、概念修正和具体条件说明，属于多角度分析论述的难度等级。" + }, + { + "idx": 2112, + "question": "Point out the errors in the following concept and correct them: From the condition for constitutional supercooling <0, c=0. The left eutectoid steel rod is divided into volume elements with thickness d, so the carbon content per unit area is c0 d. Considering only the effect of this volume element, it is equivalent to an instantaneous plane source diffusion problem. After diffusion time t, the concentration at point P(x) at a distance ξ from this volume element is cξ=(c0 dξ)/(2√(πDt))exp(-ξ²/(4Dt)). Using the superposition principle, the total concentration at point P at time t should be the sum of contributions from all volume elements, i.e., c(x,t)=(c0)/(2√(πDt))∫_x^∞exp(-ξ²/(4Dt))dξ=(c0)/√π∫_(x/√π)^∞exp(-η²)dη. Here, η=ξ/2√Dt; erf(β)=2/√π∫_0^βe^(-η²)dη. erf(β) is the error function, and its values are given in Table 5-1. Note that erf(β)=∫_β^∞e^(-η²)dη=∫_0^∞e^(-η²)dη-∫_0^βe^(-η²)dη=√π/2[1-erf(β)]. Thus, c(x,t)=c0/2 erf(x²/(2√Dt)), as shown in Figure 5-7. When x<0, the concentration increases with |x|; when x>0, the concentration decreases with x; at x=0, when t>0, c=c0/2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析浓度分布曲线随时间的变化，涉及数值计算和公式应用，如误差函数和积分计算，属于典型的计算题类型。 | 知识层次: 题目涉及扩散偶的浓度分布随时间变化的分析，需要综合运用扩散理论、误差函数、叠加原理等知识，进行多步计算和推理分析。解题过程包括初始条件的设定、体积元素的处理、瞬时平面源扩散问题的等效、浓度分布的积分求解以及误差函数的应用，思维深度和复杂度较高。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于机理相关复杂计算难度。题目不仅要求掌握扩散理论的基本公式，还需要理解并应用误差函数（erf）这一高等数学工具，同时涉及积分变换和叠加原理的综合运用。解题步骤包括建立数学模型、进行积分变换、查表应用等多个复杂环节，且需要对扩散机理有深入理解才能正确建立方程。相比同题型中简单的数值代入计算题（等级3），该题在数学工具和物理概念的综合应用上要求更高，但尚未达到需要创新性方法或解决矛盾条件的高难度综合计算（等级5）水平。" + }, + { + "idx": 2141, + "question": "In a ternary system during diffusion, can a three-phase coexistence region appear within the diffusion layer? Why?", + "answer": "A three-phase coexistence region cannot exist within the diffusion layer of a ternary system. The reasons are as follows: If three-phase equilibrium coexistence occurs in a ternary system, the compositions of the three phases are fixed, and the chemical potentials of the same component in different phases are equal, resulting in a zero chemical potential gradient, making diffusion impossible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对三元系统中扩散层内三相共存区域的存在性进行解释和论述，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目要求分析三元系统中扩散层内三相共存的可能性，并解释其原因。这需要综合运用扩散理论、相平衡原理和化学势概念，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求对三元系统中的扩散现象进行深入分析，涉及多相平衡、化学势梯度等复杂概念的综合运用。需要考生不仅理解基本理论，还要能够将这些理论联系起来，解释为什么三相共存区域不可能出现在扩散层中。这种题目要求考生具备较高的推理分析能力和对复杂现象的全面理解能力，因此在简答题题型中属于最高难度等级。" + }, + { + "idx": 2142, + "question": "For NaCl crystals doped with a small amount of $\\\\mathrm{Cd}^{2+}$, the number of $\\\\mathrm{Na^{+}}$ vacancies related to Schottky defects at high temperatures is much higher than that related to $\\\\mathrm{Cd}^{2+}$, so intrinsic diffusion dominates. At low temperatures, the vacancies caused by the presence of $\\\\mathrm{Cd}^{2+}$ ions can accelerate the diffusion of $\\\\mathrm{Na^{+}}$ ions. Analyze how the transition point temperature in Figure 5-5 would shift if the concentration of $\\\\mathrm{Cd}^{2+}$ is reduced.", + "answer": "The transition point shifts toward lower temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析掺杂浓度变化对转变温度的影响，并给出解释性答案，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求分析掺杂浓度变化对扩散机制转变温度的影响，涉及缺陷化学、扩散机制和温度效应的综合理解和推理分析。需要将Schottky缺陷和掺杂缺陷对空位浓度的影响联系起来，并理解它们在不同温度区间对扩散的贡献变化。这种分析需要较高的认知能力和对材料科学原理的深入理解。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求分析掺杂浓度变化对过渡点温度的影响，需要综合理解Schottky缺陷、掺杂效应以及扩散机制等复杂概念。虽然不涉及多因素交互作用的全面分析（等级5），但需要对材料科学中的缺陷化学和扩散动力学有较深入的理解，并能进行逻辑推理和机理解释。" + }, + { + "idx": 2143, + "question": "Point out the errors in the following concept: (1) If there is no diffusion flow in a solid, it means that atoms are not diffusing.", + "answer": "Even if there is no macroscopic diffusion flow in a solid, diffusion still occurs due to the migration jumps of atomic thermal vibrations. Self-diffusion in pure substances is a typical example.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行解释，答案提供了详细的文字论述来解释为什么原概念是错误的，这符合简答题的特征。 | 知识层次: 题目考查对扩散基本概念的理解，特别是关于扩散流和原子扩散的区别。虽然需要一定的理解能力，但主要涉及基础概念的记忆和解释，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求指出并解释一个常见的概念错误，需要学生理解扩散的基本原理（如原子热振动导致的迁移跳跃）并能举例说明（如纯物质的自扩散现象）。虽然涉及基础概念的记忆，但需要一定的理解和应用能力，比单纯复述定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2144, + "question": "In a ternary system during diffusion, can a two-phase coexistence region appear within the diffusion layer? Why?", + "answer": "A two-phase coexistence region can exist within the diffusion layer of a ternary system. The reasons are as follows: In a ternary system, when two phases coexist, due to the degree of freedom being 2, at a constant temperature, the composition of the coexisting phases can change. This disrupts the chemical potential balance of the same component atoms in the two phases, leading to diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行解释和论述，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目涉及三元系统中扩散层的两相共存区域现象，需要解释其存在的原因。这要求对相平衡、自由度概念、化学势平衡以及扩散机制的综合理解和分析。不仅需要理解基本概念，还需要将这些概念关联起来进行推理和解释，属于较高层次的认知能力。 | 难度: 在简答题中属于机理深度解释难度，需要理解并解释三元系统中扩散层内两相共存区的形成机理，涉及化学势平衡和自由度变化的复杂概念，要求较高的综合分析和推理能力。" + }, + { + "idx": 2145, + "question": "Point out the error in the following concept: (2) Because the direction of each jump of solid atoms is random, the diffusion flux is zero under any circumstances.", + "answer": "The direction of each jump of atoms is random. Only when the system is in thermal equilibrium, the probability of atoms jumping in any direction is equal. At this time, although there is atomic migration (i.e., diffusion), there is no macroscopic diffusion flow. If the system is in a non-equilibrium state, there must be a gradient of thermodynamic potential in the system (specifically expressed as concentration gradient, chemical potential gradient, strain energy gradient, etc.). The probability of atoms jumping in the direction of decreasing thermodynamic potential will be greater than that in the direction of increasing thermodynamic potential. As a result, macroscopic diffusion flow occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行详细的文字解释和论述，答案形式为一段完整的文字说明，而非选择、判断或计算。 | 知识层次: 题目要求分析扩散现象中的错误概念，并详细解释原子跳跃的随机性与宏观扩散流之间的关系。这需要深入理解扩散机制、热力学平衡与非平衡状态的区别，以及各种梯度对扩散的影响。解答过程涉及多个概念的关联和综合分析，属于对复杂机理的解释和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对扩散现象的微观机理进行深度解释，需要综合运用热力学、统计物理和扩散理论的知识。虽然不涉及多系统交互或动态过程分析（等级5特征），但需要准确区分平衡态与非平衡态下的扩散行为差异，并解释宏观扩散流的产生条件，属于机理深度解释范畴。" + }, + { + "idx": 2146, + "question": "Point out the error in the following concept: (3) The atomic arrangement at grain boundaries is disordered, and there are no vacancies, so atoms diffusing by the vacancy mechanism cannot diffuse at grain boundaries.", + "answer": "The atomic arrangement at grain boundaries is disordered, similar to that in amorphous phases, and the atomic packing density is much lower than inside the grains, resulting in weaker constraints on atoms. The energy and vibration frequency ν of grain boundary atoms are significantly higher than those of intragranular atoms. Therefore, atoms at grain boundaries have higher mobility. The grain boundary diffusion coefficient is also significantly higher than the intragranular diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行解释，答案通过文字论述详细说明了晶界扩散的特性，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析晶界扩散机制的错误概念，并解释晶界原子排列和扩散行为的关系。这需要综合运用晶界结构、扩散机制和原子动力学等多方面知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求不仅指出概念错误，还需要详细解释晶界扩散的机理，包括原子排列、能量状态、振动频率等多方面因素的综合分析。这需要学生对晶界结构和扩散机制有深入的理解，并能将这些知识点有机结合起来进行论述。虽然题目没有要求对比不同扩散机制或涉及更复杂的计算，但其对机理解释的深度要求仍属于较高水平。" + }, + { + "idx": 2147, + "question": "Point out the error in the following concept: (4) In an interstitial solid solution, the higher the solute concentration, the more interstitial sites are occupied by the solute, leaving fewer vacant interstitial sites for diffusion, i.e., the value of $_z$ decreases, leading to a reduction in the diffusion coefficient.", + "answer": "In fact, this scenario is impossible. The solubility of solute atoms in an interstitial solid solution is very limited. Even in a supersaturated state, the number of solute atoms is several orders of magnitude smaller than the total number of interstitial sites in the crystal. Therefore, the interstitial sites around the solute atoms can be considered entirely vacant. That is, for a given crystal structure, 𝓏 is a constant.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出一个概念的错误，答案明确判断了原陈述的错误性并给出了正确解释，符合判断题的特征 | 知识层次: 题目考查对间隙固溶体基本概念的理解，特别是间隙位置和扩散系数的关系，属于基础概念的记忆和理解范畴。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度。题目考察的是对间隙固溶体基本概念的理解，需要考生明确间隙固溶体中溶质原子浓度与间隙位置占用情况的关系。虽然涉及基础概念，但需要一定的理解深度才能判断陈述的错误所在，因此属于等级2难度。" + }, + { + "idx": 2148, + "question": "For a pre-annealed metal polycrystal, the relationship between true stress σ_T and true strain ε_T in the uniform plastic deformation stage of the true stress-strain curve is given by σ_T=Kε_T^n, where K is the strength coefficient and n is the strain hardening exponent. If there are two metals A and B with roughly equal K values, but n_A=0.5 and n_B=0.2, which metal has higher hardening capability and why?", + "answer": "Since σ_T=Kε_T^n, then dσ_T=n Kε_T^(n-1)dε_T, and θ=dσ_T/dε_T=n Kε_T^(n-1). From this equation, it can be seen that when ε_T<1 and 0n_B, metal B has a higher dislocation density at the same plastic strain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两种金属在相同塑性应变下的位错密度差异，答案提供了详细的文字解释和逻辑推理，符合简答题的特征。 | 知识层次: 题目要求综合运用应变硬化指数和位错密度的关系，通过给定的公式和条件进行推理分析，解释不同金属在相同塑性应变下的位错密度差异。这需要深入理解应变硬化机制和位错理论，并进行逻辑推理和综合分析。 | 难度: 在简答题中属于机理深度解释难度等级。该题目要求考生综合运用应变硬化指数、位错密度与应力关系的知识，通过数学推导和物理机理分析，比较两种金属在相同塑性应变下的位错密度差异。解题过程涉及对σ_T=Kε_T^n公式的理解、应变硬化指数n对位错密度ρ的影响机制（σ_T∝√ρ）的掌握，以及当ε_T<1时的特殊情况分析。虽然不需要进行多因素交互作用的全面分析（等级5要求），但需要对变形机理有较深入的理解和推导能力，符合等级4的深度解释要求。" + }, + { + "idx": 2152, + "question": "For a face-centered cubic crystal, the movable slip system is (111)[110]. If the slip is caused by a pure edge dislocation, indicate the direction of the dislocation line.", + "answer": "The dislocation line lies on the slip plane (111). Let the direction of the dislocation line be [uow], then u+v-w=0; the dislocation line is perpendicular to b, i.e., perpendicular to [110], so -u+v=0. From the above two equations, u:v:w=1:1:2, thus the direction of the dislocation line is [112].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错线的方向，答案给出了详细的推导过程和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解面心立方晶体的滑移系统，并应用几何关系推导位错线方向。涉及多步计算和概念关联，需要综合分析滑移面、位错线和柏氏矢量的几何关系。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识、位错理论和向量运算。解题步骤包括：1) 理解面心立方晶体滑移系概念；2) 分析纯刃位错特性；3) 建立并求解方向向量方程组；4) 进行规范化处理得出最终方向指数。整个过程涉及多个知识点的关联运用和较为复杂的数学推导，超出了基础概念应用的范畴。" + }, + { + "idx": 2153, + "question": "If the surface of a single crystal copper is exactly the {100} crystal plane, assuming the crystal can slip on various slip systems, discuss the possible morphology of slip lines (the orientation of slip lines and the angles between them) that may be observed on the surface.", + "answer": "Copper crystal has a face-centered cubic lattice, and its slip systems are {111}<110>. If the surface of the single crystal copper is the {100} crystal plane, when plastic deformation occurs, the slip lines appearing on the crystal surface should be the intersection lines of {111} and {100}, which are <110>. That is, the slip lines observed on the crystal surface are either parallel to each other or intersect at a 90° angle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论单晶铜表面滑移线的可能形态，包括滑移线的取向和它们之间的角度，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析面心立方晶体铜在特定晶面（{100}）上的滑移线形态，需要理解晶体滑移系统（{111}<110>）与表面晶面的几何关系，并推导出滑移线的可能取向和角度关系。这涉及多步概念关联和综合分析，但不需要复杂的机理或创新应用。 | 难度: 在简答题题型内，该题目属于多角度分析论述难度。需要学生掌握面心立方晶体的滑移系统知识，理解{100}晶面与{111}滑移面的空间几何关系，并能推导出滑移线的可能取向和夹角关系。解题过程涉及晶体学知识的综合应用和空间想象能力，比单纯的概念解释题(等级3)要求更高，但尚未达到需要深度关联性分析(等级5)的程度。" + }, + { + "idx": 2154, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], indicate the direction of dislocation line movement during slip in the cases of pure edge dislocation and pure screw dislocation.", + "answer": "In the case of pure edge dislocation, the direction of dislocation line movement is parallel to b; in the case of pure screw dislocation, the direction of dislocation line movement is perpendicular to b.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述纯刃位错和纯螺位错在位错线运动中的方向，答案以文字解释的形式给出，没有涉及计算或选择判断。 | 知识层次: 题目要求分析面心立方晶体中特定滑移系统下纯刃位错和纯螺位错的位错线运动方向，需要理解位错类型与滑移方向的关系，并能够将基本概念应用于具体晶体结构中。这涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对纯刃位错和纯螺位错在特定滑移系统中的运动方向进行多角度分析论述。需要综合理解位错类型、滑移系统几何关系以及柏氏矢量的方向性，并准确描述运动方向与柏氏矢量的空间关系。这超出了简单概念复述（等级3），但尚未达到需要深度关联其他晶体缺陷理论的最高难度（等级5）。" + }, + { + "idx": 2155, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], if the slip is caused by pure screw dislocations, indicate the direction of the dislocation line.", + "answer": "The dislocation line lies on the slip plane and is parallel to b, so the direction of the dislocation line is [110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案需要详细说明位错线的方向，而不是简单的选择或判断。 | 知识层次: 题目要求理解面心立方晶体滑移系的概念，并能够将纯螺位错的性质与滑移方向关联起来。需要多步分析和概念关联，但不需要复杂的综合或创新应用。 | 难度: 在简答题中属于中等难度，需要理解晶体结构、滑移系统和位错线方向的概念，并进行综合分析。题目要求明确位错线的方向，需要将滑移面和滑移方向的知识结合起来，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2156, + "question": "When a tensile force is applied along the [0001] direction of a hexagonal close-packed single crystal, what are the possible deformations and the primary mode of deformation?", + "answer": "The slip plane of hexagonal close-packed metals is (0001), and the resolved shear stress on the slip plane in the [0001] direction is zero, so the single crystal cannot slip. During tension, the possible deformations of the single crystal are elastic deformation or subsequent brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述可能的变形和主要变形模式，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解六方密堆积单晶的滑移面和方向，并分析在特定方向施加拉力时的变形机制。这涉及多个概念的关联和综合分析，包括滑移面的确定、分切应力的计算以及可能的变形模式。虽然不涉及复杂的计算，但需要对材料变形行为有较深入的理解和分析能力。 | 难度: 在简答题中，该题目要求考生不仅理解六方密堆积单晶的基本滑移机制，还需要分析在特定方向（[0001]方向）施加拉力时的变形可能性。这涉及到对晶体滑移面、分切应力计算以及弹性变形和脆性断裂的综合理解。题目要求考生进行多角度分析，包括滑移面的选择、分切应力的计算以及可能的变形模式，因此属于较高难度的简答题。" + }, + { + "idx": 2157, + "question": "A 20m long aluminum rod with a diameter of 14.0mm is drawn through a die with an aperture of 12.7mm. Calculate the cold working rate that this aluminum rod will undergo.", + "answer": "The cold working rate (CW) can be expressed as the percentage reduction in cross-sectional area caused by plastic deformation, i.e., CW=[π×(14.0/2)^2-π×(12.7/2)^2]/[π×(14.0/2)^2]=18%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解冷加工率，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的直径变化计算冷加工率。虽然需要理解冷加工率的定义，但整体过程是直接套用公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需套用单一公式（面积变化率公式）进行直接计算，无需多步推导或组合公式。题目明确给出了所有必要参数，计算过程仅涉及基本代数运算，属于典型的\"直接套用公式\"类题目。" + }, + { + "idx": 2158, + "question": "The critical resolved shear stress of an aluminum single crystal at room temperature is $7.9\\\\times10^{5}~\\\\mathrm{Pa}$. If a tensile test is performed on an aluminum single crystal specimen at room temperature with the tensile axis in the [123] direction, and the possible activated slip system is (111)[101], determine the stress required to cause the specimen to yield.", + "answer": "The aluminum crystal has a face-centered cubic lattice, and its slip system is $\\\\{111\\\\}<110>$. When performing a tensile test on an aluminum single crystal: $$ \\\\sigma_{s}=\\\\frac{\\\\tau_{\\\\mathrm{c}}}{\\\\cos\\\\varphi\\\\cos\\\\lambda} $$ Given $\\\\tau_{\\\\mathrm{c}}=7.9\\\\times10^{5}~\\\\mathrm{Pa}$, when the external force axis direction is [123], the possible activated slip system is (111)[101]. Thus, $\\\\varphi$ is the angle between [123] and the normal [111] of the (111) crystal plane, and $\\\\lambda$ is the angle between [123] and [101]. $$ \\\\mathrm{cos}\\\\varphi={\\\\frac{{\\\\overline{{1}}}+2+3}{\\\\sqrt{14}\\\\times\\\\sqrt{3}}}={\\\\frac{4}{\\\\sqrt{42}}} $$ $$ \\\\cos\\\\lambda={\\\\frac{1+0+3}{\\\\sqrt{14}\\\\times{\\\\sqrt{2}}}}={\\\\frac{2}{\\\\sqrt{7}}} $$ Therefore, $$ \\\\sigma_{\\\\mathrm{s}}=\\\\frac{7.9\\\\times10^{5}}{\\\\frac{4}{\\\\sqrt{42}}\\\\times\\\\frac{2}{\\\\sqrt{7}}}=1.69\\\\times10^{6}~\\\\mathrm{Pa} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定应力值，解答过程中涉及角度计算和应力公式的应用，最终给出具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要计算临界分切应力并应用施密特定律，同时需要理解晶体取向和滑移系统的几何关系。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体学方向、滑移系统、临界分切应力等概念，并进行多步计算（包括方向余弦计算和应力公式应用）。虽然计算过程明确，但涉及多个知识点的综合应用和较复杂的数学运算，属于中等偏上的难度。" + }, + { + "idx": 2159, + "question": "For a pre-annealed metal polycrystal, the relationship between true stress σ_T and true strain ε_T in the uniform plastic deformation stage of the true stress-strain curve is given by σ_T=Kε_T^n, where K is the strength coefficient and n is the strain hardening exponent. Derive the mathematical relationship between the strain hardening exponent n and the strain hardening rate θ=dσ_T/dε_T.", + "answer": "The definition of the strain hardening rate θ is θ=dσ_T/dε_T. From σ_T=Kε_T^n, we obtain dσ_T/dε_T=n Kε_T^(n-1), that is, θ=n Kε_T^(n-1). Further derivation yields θ=n(σ_T/ε_T^n)ε_T^(n-1)=n(σ_T/ε_T).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过推导和解释来建立数学关系，答案包含详细的推导过程和文字解释，属于需要论述和解释的简答题类型。 | 知识层次: 题目要求从给定的应力-应变关系出发，通过微分推导出应变硬化指数与应变硬化速率之间的数学关系。这涉及到对公式的理解和应用，以及多步的数学推导过程。虽然题目没有涉及复杂的综合分析或创新应用，但需要一定的概念关联和数学操作能力，超出了简单应用的范畴。 | 难度: 在简答题中属于中等难度，需要理解应变硬化指数和应变硬化速率的概念，并进行多步数学推导。虽然涉及公式推导和概念关联，但步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 2160, + "question": "If the surface of a single crystal copper is the {111} crystal plane, assuming that the crystal can slip on various slip systems. Discuss the possible morphology of slip lines on the surface (the orientation of slip lines and the angles between them).", + "answer": "When the outer surface of a copper single crystal is the {111} family of crystal planes, the slip lines appearing on the surface are <110>, which are either parallel to each other or intersect at an angle of 60°.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论单晶铜表面滑移线的可能形态（滑移线的取向和它们之间的角度），需要文字解释和论述，而不是选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求分析单晶铜在特定晶面上的滑移线形态，涉及晶体滑移系统的基本原理（记忆和理解）以及滑移方向与晶面关系的综合分析（应用和分析）。需要将晶体学知识（如滑移系、晶面指数）与实际观察现象（滑移线方向和角度）关联起来，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析晶体滑移系统的几何关系，理解{111}晶面上<110>滑移方向的排列方式，并准确描述滑移线的可能取向和夹角（60°）。这要求将晶体学知识与实际观察现象进行多角度关联，并准确论述其空间几何关系。" + }, + { + "idx": 2161, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], indicate the Burgers vector of the unit dislocation causing the slip (taking the lattice constant a=0.2nm).", + "answer": "The Burgers vector of the unit dislocation causing the slip is b=a/2[110], which is the vector represented by the line connecting two adjacent atoms along the slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释并给出Burgers vector的具体表达式，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求根据给定的晶体结构和滑移系统，应用基本的Burgers向量计算公式（b=a/2[110]）来确定单位位错的Burgers向量。这属于直接套用基本公式的简单应用，不需要多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述难度。题目要求直接应用FCC晶体滑移系的基本知识，通过已知的晶格常数和滑移方向计算伯格斯矢量。解题步骤简单明确，只需套用基本公式b=a/2[110]即可得出答案，无需深入分析或多步推导。" + }, + { + "idx": 2162, + "question": "When a compressive force is applied along the [0001] direction of a hexagonal close-packed single crystal, what are the possibilities of deformation and the primary mode of deformation?", + "answer": "The slip plane of hexagonal close-packed metals is (0001), and the resolved shear stress on the slip plane in the [0001] direction is zero, so the single crystal cannot slip. During compression, after elastic deformation, twinning may occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下材料的变形可能性及主要变形模式，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目需要理解六方密堆积单晶的滑移面和方向，以及在外力作用下的变形机制。涉及弹性变形和孪生变形的概念关联，需要综合分析压缩方向与滑移面的关系，判断变形可能性。虽然不涉及复杂计算，但需要多步推理和概念关联。 | 难度: 在简答题中属于较高难度，需要综合理解六方密堆积单晶的变形机制，包括滑移面和孪生的概念，并能分析在特定方向（[0001]）下的应力状态和变形可能性。题目要求多角度分析论述，涉及弹性变形后的孪生变形机制，需要较强的概念关联和综合分析能力。" + }, + { + "idx": 2163, + "question": "Calculate the volume fraction of the Fe3C phase in 40 steel, given the mass fraction of carbon ωC=0.004", + "answer": "φFe3C=0.004/0.069=0.06", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Fe3C相的体积分数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的质量分数到体积分数的转换计算，仅需直接应用给定的公式和数据进行简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（体积分数=质量分数/Fe3C中碳的质量分数）进行简单计算，无需多步推导或复杂公式组合。" + }, + { + "idx": 2164, + "question": "The movable slip system of a certain face-centered cubic crystal is (111)[110]. Assuming a shear stress of magnitude 0.7MPa acts on this slip system, calculate the magnitude and direction of the force per unit length on a unit edge dislocation and a unit screw dislocation (take the lattice constant a=0.2nm).", + "answer": "Under the applied shear stress τ, the magnitude of the force per unit length on the dislocation line is F=τb, and the direction is perpendicular to the dislocation line. Here, |b|=√((a/2)^2+(a/2)^2)=√2/2a, so F=τb=0.7×√2/2a=0.7×√2×0.2×10^-9/2=9.899×10^-11MN/m. The direction of F is perpendicular to the dislocation line; the direction of F is also perpendicular to the dislocation line.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算力的大小和方向）并应用相关公式（F=τb），答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算伯格斯矢量的长度和应用公式计算力的大小，同时需要理解力的方向与位错线的关系。这涉及到概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解位错的基本概念、掌握剪切应力与位错力的关系，并进行多步计算。题目涉及了晶格常数的应用、位错力的计算以及方向的确定，但并未涉及复杂多变量或高阶数学处理，因此属于等级3。" + }, + { + "idx": 2165, + "question": "Calculate the interparticle spacing λ, given the number of Fe3C particles per unit volume NV=1.43×1013", + "answer": "λ=NV-1/3=(1.43×1013)-1/3=0.24×10-5m=2.4μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算interparticle spacing λ），并给出了具体的计算步骤和公式应用（λ=NV-1/3），最终得出数值结果。这完全符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析，属于简单应用层次。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（λ=NV-1/3）进行简单数值计算，无需任何公式组合或复杂推导步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2166, + "question": "Calculate the number of Fe3C particles per unit volume NV, given the volume fraction of Fe3C phase φFe3C=0.06 and the spherical particle radius r=10×10-6m", + "answer": "NV=φFe3C/(4/3πr3)=0.06/(4/3π×(10×10-6)3)≈1.43×1013", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及体积分数和球形颗粒体积的计算，属于单一知识点的直接套用，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式进行数值计算，无需多个公式组合或复杂步骤。题目明确给出了所有必要参数，且计算过程简单直接。" + }, + { + "idx": 2167, + "question": "Calculate the Burgers vector b of α-Fe, given the lattice constant of α-Fe a=0.28nm", + "answer": "b=√3/2a=√3/2×0.28=0.25nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers vector b），并给出了具体的计算公式和步骤，最终得出数值结果。这符合计算题的特征。 | 知识层次: 题目要求应用基本公式（Burgers vector的计算公式）进行简单计算，无需多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（Burgers vector计算公式b=√3/2a）进行简单数值计算，无需任何公式组合或复杂推导步骤，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 2168, + "question": "Calculate the shear strength τ of 40 steel, given the shear modulus of iron GFe=7.9×1010Pa, Burgers vector b=0.25nm, and particle spacing λ=2.4μm", + "answer": "τ=Gb/λ=7.9×1010×2.5×10-10/2.4×10-5=8.23×105Pa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（剪切模量、Burgers矢量、粒子间距）进行数值计算，应用公式τ=Gb/λ来求解剪切强度，答案是一个具体的数值计算结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的参数代入公式计算剪切强度，不需要多步计算或复杂的概念关联。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（τ=Gb/λ）并进行简单数值计算，无需任何变形或组合步骤。所有给定参数均为直接代入，解题过程不涉及任何复杂推导或多步骤分析。" + }, + { + "idx": 2169, + "question": "Give the relationship between the lattice resistance to dislocation motion and the crystal structure.", + "answer": "τ_p≈(2G/(1-ν))exp[-(2πa)/((1-ν)b)]≈(2G/(1-ν))exp(-2πw/b) where w is the dislocation width (w=a/(1-ν)), a is the interplanar spacing of the slip plane, b is the atomic spacing in the slip direction, and ν is the Poisson's ratio.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求给出晶格对位错运动的阻力与晶体结构之间的关系，答案提供了详细的公式和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释晶格对位错运动的阻力与晶体结构之间的关系，并给出了具体的数学表达式。这需要深入理解位错理论、晶体结构参数（如晶面间距、泊松比）以及它们之间的相互作用机制。解答不仅需要记忆公式，还需要分析各参数的意义及其对阻力的影响，属于综合运用和推理分析的层次。 | 难度: 在简答题题型中，该题目属于复杂分析层次，要求综合运用多个材料科学概念（如晶格阻力、位错运动、晶体结构参数等），并进行机理深度解释和数学推导。解题步骤涉及多个变量的关系推导和物理意义解释，对学生的综合推理能力和专业知识深度要求极高，符合\"复杂现象全面分析\"的标准。" + }, + { + "idx": 2170, + "question": "What is single slip? What are the characteristics of its slip lines?", + "answer": "Single slip refers to the slip occurring on only one slip system. The slip lines appear as a series of parallel straight lines. This is because in single slip, only one set of slip systems is active, where all slip planes are parallel to each other and the slip directions are identical.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"single slip\"及其滑移线特征进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查单滑移的基本定义及其滑移线特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要解释\"single slip\"的定义，但仅要求描述其滑移线特征（平行直线），不涉及多个概念关联或复杂机理阐述。相比等级1的纯定义复述题，需要更多理解性描述；但相比等级3需要系统阐述多个相关概念的题目，其知识深度和解题复杂度仍较为基础。" + }, + { + "idx": 2171, + "question": "For annealed pure iron with a grain size of $N_{\\\\mathrm{A}}=16$ grains/mm², its yield strength $\\\\sigma_{\\\\textrm{s}}=100$ MPa; when $N_{\\\\mathrm{A}}=4~096$ grains/mm², $\\\\sigma_{\\\\mathrm{s}}=250\\\\mathrm{MPa}$. Calculate $\\\\sigma_{s}$ when $N_{\\\\mathrm{A}}=250$ grains/mm².", + "answer": "Let the average grain diameter be $d$, and the number of grains per square millimeter be $N_{\\\\mathrm{A}}$. It can be proven that $$ d=\\\\sqrt{\\\\frac{8}{3\\\\pi N_{\\\\mathrm{A}}}} $$ Therefore, $$ d_{1}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times16}}=0.053\\\\mathrm{~mm} $$ $$ d_{2}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times4~096}}=2.072\\\\times10^{-4}~\\\\mathrm{mm} $$ $$ d_{3}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times250}}=3.395\\\\times10^{-3}\\\\mathrm{mm} $$ Substituting into the Hall-Petch formula, $$ \\\\begin{array}{l}{\\\\left\\\\{100=\\\\sigma_{0}+K(0.053)^{-1/2}\\\\right.} \\\\\\\\ {\\\\left.250=\\\\sigma_{0}+K(2.072\\\\times10^{-4})^{-1/2}\\\\right.}\\\\end{array} $$ Solving gives $$ \\\\sigma_{0}=90\\\\mathrm{MPa} $$ Therefore, when $N_{\\\\mathrm{A}}=250$ grains/mm² and $d=3.395\\\\times10^{-3}\\\\mathrm{mm}$, $$ \\\\sigma_{\\\\mathrm{s}}=90+2.303\\\\times(3.395\\\\times10^{-3})^{-1/2}=129.5~\\\\mathrm{MPa} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解屈服强度，解答过程中涉及多个步骤的计算和公式代入，符合计算题的特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值求解，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，包括转换晶粒尺寸、建立方程组求解常数、最后代入新条件计算屈服强度。虽然计算过程明确，但涉及多个步骤和概念的综合应用，相比简单的单步计算题更具挑战性。" + }, + { + "idx": 2172, + "question": "Given that the critical resolved shear stress τc for the {111}[110] slip system in pure copper is 1MPa, what stress should be applied in the [001] direction to produce slip in the [101] direction on the (111) plane?", + "answer": "For cubic crystals, the angle between two crystallographic directions [u1v1w1] and [u2v2w2] is given by cosφ=(u1u2+v1v2+w1w2)/(√(u1²+v1²+w1²)*√(u2²+v2²+w2²)). Therefore, the angle between the normal direction [111] of the slip plane (111) and the tensile axis [001] is cosφ=(1×0+1×0+1×1)/(√(1²+1²+1²)*√(0²+0²+1²))=1/√3=0.577. The angle between the slip direction [101] and the tensile axis [001] is cosλ=(1×0+0×0+1×1)/(√(1²+0²+1²)*√(0²+0²+1²))=1/√2=0.707. The applied stress σ=τc/(cosφcosλ)=1/(0.577×0.707)=2.45MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，涉及角度计算和应力计算，最终需要得出具体的应力数值（2.45MPa）。答案展示了完整的计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算两个方向之间的角度，并应用临界分切应力公式来求解所需的应力。这涉及到对晶体学方向的理解和公式的应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用晶体学角度计算公式进行多步骤计算，并综合理解临界分切应力与施密特因子的关系。虽然计算过程明确，但涉及多个概念关联和综合分析，属于中等偏上难度。" + }, + { + "idx": 2173, + "question": "When stretching a copper single crystal, if the direction of the tensile axis is [001], $\\\\sigma=10^{6}$ Pa. Calculate the force on the screw dislocation line with Burgers vector $b=$ $\\\\frac{a}{2}$ [101] on the (111) plane $(a_{\\\\mathrm{Cu}}=0.36\\\\mathrm{nm})$.", + "answer": "Let the resolved shear stress of the applied tensile stress along the [101] direction on the (111) slip plane be $\\\\tau$, then $$ x \\\\tau=\\\\sigma{\\\\cos}\\\\varphi{\\\\cos}\\\\lambda\\n $$\\n where, $\\\\varphi$ is the angle between [001] and the normal [111] of the (111) plane, $\\\\lambda$ is the angle between [001] and the [101] direction. \\n\\nSo $$ \\\\tau=10^{6}\\\\times{\\\\frac{1}{{\\\\sqrt{1}}\\\\times{\\\\sqrt{3}}}}\\\\times{\\\\frac{1}{\\\\sqrt{2}}}=4.0825\\\\times10^{5}{\\\\mathrm{~Pa}}\\n $$\\n If the force on the screw dislocation line is $F_{\\\\mathrm{d}}$, then $$ F_{\\\\mathrm{d}}=\\\\tau b=4.0825\\\\times10^{5}\\\\times{\\\\frac{\\\\sqrt{2}}{2}}\\\\times0.36\\\\times10^{-9}=1.039\\\\times10^{-4}~{\\\\mathrm{N/m}}\\n $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及应力、角度和力的计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括确定分解剪切应力、计算角度关系、应用基本公式求解力的大小。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如Burgers向量、剪切应力、晶体方向等），进行多步骤计算（包括角度计算、应力分解、单位转换等），但整体计算过程相对直接，没有涉及过于复杂的变量或高阶数学工具。" + }, + { + "idx": 2174, + "question": "What is cross-slip? What are the characteristics of its slip lines?", + "answer": "Cross-slip refers to the simultaneous or alternating slip of two or more slip planes along a common slip direction. Their slip lines are usually zigzag or wavy. This is the result of screw dislocations repeatedly 'expanding' on different slip planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"cross-slip\"进行定义并描述其滑移线特征，需要文字解释和论述，符合简答题的特征。答案提供了概念解释和特征描述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对交叉滑移这一基本概念的定义及其特征的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"cross-slip\"的定义并描述其滑移线特征，需要考生对位错运动的基本原理有一定理解，但不需要进行复杂的概念体系阐述或深入分析。题目涉及的知识点相对明确，解题步骤主要是回忆和简单组织相关概念，符合等级2\"概念解释和描述\"的要求。" + }, + { + "idx": 2175, + "question": "Give examples of the impact of Lüders bands on industrial production and methods to prevent them.", + "answer": "Lüders bands can cause the surface of workpieces made from low-carbon thin steel sheets to become rough and uneven during stamping and forming. The solution, based on the strain aging principle, involves subjecting the steel sheet to a slight cold rolling process (e.g., 1%∼2% reduction) before stamping to eliminate the yield point, followed by stamping and forming. Alternatively, adding small amounts of Ti, Al, C, and N to the steel to form compounds can also eliminate the yield point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求给出Lüders bands对工业生产的影响实例以及预防方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Lüders bands对工业生产的影响及预防方法，涉及多个概念的关联和综合分析。需要理解Lüders bands的形成机制及其对材料性能的影响，并基于应变时效原理提出解决方案。此外，还需要了解通过冷轧或添加合金元素来消除屈服点的具体方法。这些内容超出了基础概念记忆和简单应用的范围，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解Lüders bands的基本概念，还需要分析其对工业生产的具体影响，并提出预防方法。这涉及到多角度的分析论述，包括材料科学原理（应变时效）和实际工业应用（冷轧工艺和合金添加）。此外，解题步骤较为复杂，需要考生综合运用多个知识点进行解答，符合等级4的多角度分析论述要求。" + }, + { + "idx": 2176, + "question": "How is texture formed?", + "answer": "After cold working, the orientations of metal grains exhibit certain relationships. For instance, certain crystal planes or directions become parallel to each other and also parallel to an external reference direction of the component. Such an orientation distribution is called preferred orientation or simply texture. The formation of texture is not limited to cold working, but here it mainly refers to deformation texture. In terms of both orientation and properties, polycrystalline materials with texture lie between single crystals and completely randomly oriented polycrystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释纹理的形成过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对\"texture\"这一基本概念的记忆和理解，包括其形成过程和特点。虽然涉及了一些解释，但整体上属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释纹理的形成过程，涉及冷加工后金属晶粒取向的关系，以及变形纹理的基本概念。虽然需要一定的记忆和理解，但并不需要阐述复杂的理论体系或多步骤的推导过程，属于中等难度的概念解释题。" + }, + { + "idx": 2177, + "question": "What is multiple slip? What are the characteristics of its slip lines?", + "answer": "Multiple slip refers to the simultaneous or alternating slip of two or more different slip systems. Their slip lines are either parallel or intersect at a certain angle. This is because certain crystal structures have specific slip systems, and there are certain angles between the slip planes and slip directions of these slip systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"multiple slip\"进行定义并描述其滑移线的特征，需要文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对\"multiple slip\"这一基本概念的定义及其特征的理解和记忆，属于材料科学中晶体变形的基础知识，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，题目要求解释multiple slip的定义并描述其滑移线特征，涉及基础概念记忆和简单描述，但不需要复杂的概念体系阐述或深入分析。" + }, + { + "idx": 2178, + "question": "For face-centered cubic crystals, it is generally required to have five independent slip systems for slip to occur. Is this conclusion correct? Please explain the reason and the conditions under which this conclusion applies.", + "answer": "This conclusion is correct. Because generally, representing a deformation requires nine strain components, i.e., $$ \\\\mathfrak{\\\\varepsilon}_{i j}=\\\\left|\\\\begin{array}{l l l}{\\\\varepsilon_{x x}}&{\\\\mathfrak{\\\\varepsilon}_{x y}}&{\\\\mathfrak{\\\\varepsilon}_{x z}}\\\\\\\\{\\\\mathfrak{\\\\varepsilon}_{y y}}&{\\\\mathfrak{\\\\varepsilon}_{y x}}&{\\\\mathfrak{\\\\varepsilon}_{y z}}\\\\\\\\{\\\\mathfrak{\\\\varepsilon}_{z z}}&{\\\\mathfrak{\\\\varepsilon}_{z x}}&{\\\\mathfrak{\\\\varepsilon}_{z y}}\\\\end{array}\\\\right| $$ but $\\\\varepsilon_{x y}=\\\\varepsilon_{y x}, \\\\varepsilon_{y z}=\\\\varepsilon_{z y}, \\\\varepsilon_{z x}=\\\\varepsilon_{x z}$; thus, there are only six components left. Since the deformation is required to be uniform and continuous, the volume remains unchanged before and after deformation, i.e., $\\\\Delta V{=}_{\\\\epsilon_{x x}}+\\\\epsilon_{y y}+\\\\epsilon_{z z}{=}0$. With this constraint, there are only five independent strain components. Each independent strain component is generated by an independent slip system; therefore, five independent slip systems are needed to produce five independent strain components. When applying this conclusion, attention must be paid to the size of the crystal. The volume cannot be too small; it must be larger than the spacing between slip bands so that the plastic deformation can be considered uniform. However, the volume cannot be too large either; it must remain within the range of linear plastic deformation, such as not exceeding the size of a single grain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结论的正确性及其适用条件，答案通过文字论述和公式说明来详细解释原因，符合简答题的特征。 | 知识层次: 题目不仅要求解释面心立方晶体需要五个独立滑移系统的原因，还需要分析应变张量的独立分量和体积不变条件，并讨论结论适用的条件。这涉及多个概念的关联、数学推导和综合分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2180, + "question": "How is fibrous structure formed?", + "answer": "After cold working of materials, in addition to transforming the disordered orientation of polycrystalline materials into materials with preferred orientation, it also causes deformation of insoluble impurities, second phases, and various defects in the material. Since grains, impurities, second phases, and defects are all elongated into fibrous shapes along the main deformation direction of the metal, it is called fibrous structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对纤维结构的形成进行文字解释和论述，答案提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目要求解释纤维状结构的形成机制，涉及冷加工过程中多晶体材料、不溶杂质、第二相和缺陷的变形行为，需要综合运用材料科学中的变形机制、晶体取向和缺陷理论进行推理分析，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对纤维结构的形成机理进行深度解释，涉及冷加工对多晶材料取向、不溶杂质、第二相和缺陷的影响，需要综合运用材料科学知识进行推理分析。虽然不涉及最复杂的多因素交互作用分析，但对机理的解释深度已达到等级4的要求。" + }, + { + "idx": 2181, + "question": "What is the difference between fibrous structure and texture?", + "answer": "Fibrous structure is formed by grains, impurities, second phases, defects, etc., being elongated into fibrous shapes along the main deformation direction of the metal; whereas texture refers to the certain orientation relationship among grains after cold working, where certain crystal planes or directions are parallel to each other and all parallel to an external reference direction of the component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对纤维结构和织构这两个基本概念的定义和区别的理解，属于基础概念的记忆和解释，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分两个相关但不同的材料科学概念（纤维结构和织构），需要考生对这两个概念有清晰的理解并能准确描述其差异。虽然涉及两个概念的比较，但不需要深入分析或复杂推导，主要考察基础概念的记忆和表述能力，符合等级2的特征。" + }, + { + "idx": 2182, + "question": "Explain why crystal slip usually occurs on the most closely packed atomic planes and directions.", + "answer": "As can be seen from the relation, the larger the value of a, the smaller the τ_p, so the slip plane should be the one with the largest interplanar spacing, i.e., the most closely packed atomic plane; the smaller the value of b, the smaller the τ_p, so the slip direction should be the most closely packed atomic direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体滑移通常发生在最密排原子面和方向的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶体滑移通常发生在最密排原子面和方向的原因，这需要综合运用材料科学中的晶体结构、滑移系统、临界分切应力等知识，并进行推理分析。答案中涉及了晶面间距与临界分切应力的关系，以及滑移面和滑移方向的选择原理，体现了对多个概念的关联和综合分析能力。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释晶体滑移为何通常发生在最密排原子面和方向上，需要综合运用材料科学中的晶体结构、滑移系统选择标准等知识，并通过推理分析得出答案。虽然题目涉及的知识点较为基础，但需要将多个概念联系起来进行解释，属于对机理的深度理解层面，因此属于等级4。" + }, + { + "idx": 2183, + "question": "Use dislocation theory to explain the yield phenomenon of low-carbon steel.", + "answer": "The yield phenomenon of low-carbon steel can be explained by dislocation theory. Since low-carbon steel is an alloy based on ferrite, carbon (nitrogen) atoms in ferrite interact with dislocations and tend to aggregate in the tensile stress regions of dislocation lines to reduce the distortion energy of the system, forming Cottrell atmospheres that 'pin' the dislocations, thereby increasing σs. Once dislocations break free from the pinning of these atmospheres, they can continue to move under lower stress, leading to the appearance of the lower yield point on the stress-strain curve. For a specimen that has already yielded, if it is unloaded and immediately reloaded in tension, the yield point does not reappear because the dislocations have already escaped the pinning of the atmospheres. However, if the unloaded specimen is left for a long time or slightly heated before retesting, the solute atoms will diffuse back and re-aggregate around the dislocation lines to form atmospheres, causing the yield phenomenon to reappear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释低碳钢的屈服现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢的屈服现象，涉及位错与溶质原子的相互作用、柯氏气团的形成及其对位错的钉扎作用、应力-应变曲线上的屈服点现象等复杂机理的分析和解释。需要综合运用位错理论、扩散理论和材料力学性能的知识，进行深入的推理和机理阐述，属于复杂分析层次。 | 难度: 在简答题（复杂分析类）中，该题目要求综合运用位错理论解释低碳钢屈服现象，涉及Cottrell气团形成、位错钉扎与脱钉机制、应力-应变曲线特征以及时效/热处理对屈服现象的影响等多个复杂概念的联动分析。需要考生不仅掌握各知识点细节，还能建立跨知识点逻辑链条解释宏观力学行为，属于该题型下对机理深度和现象全面性要求最高的复杂分析层级。" + }, + { + "idx": 2184, + "question": "What effect does fibrous structure have on the properties of metals?", + "answer": "Generally speaking, fibrous structure makes the longitudinal (fiber direction) strength of metals higher than the transverse strength. This is because on the cross-section, the cross-sectional area of brittle, low-strength 'components' such as impurities, second phases, and defects is small, while on the longitudinal section, the cross-sectional area is large. When parts bear large loads or are subjected to impact and alternating loads, this anisotropy may pose significant risks.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维结构对金属性能的影响，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释纤维结构对金属性能的影响机制，涉及多因素综合分析（杂质、第二相、缺陷等）和各向异性原理的深入解释，需要将材料微观结构与宏观性能关联，属于机理层面的推理分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解纤维结构对金属性能的影响，还需要解释其背后的机理（如纵向与横向强度的差异原因），并涉及多相材料、缺陷等复杂概念的交叉分析。虽然不需要达到全面分析复杂现象的程度（等级5），但已超出基础概念复述的范畴，属于需要综合运用材料科学知识进行推理分析的深度解释题目。" + }, + { + "idx": 2185, + "question": "Briefly analyze the essential similarities and differences in work hardening", + "answer": "Work hardening is caused by dislocation pile-up, entanglement, and their interactions, which hinder further dislocation movement, with the flow stress σd=αGb√ρ", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析加工硬化的基本相似性和差异性，需要文字解释和论述，答案也以文字形式给出解释和公式说明。 | 知识层次: 题目要求分析加工硬化的本质相似性和差异性，涉及位错堆积、缠结及其相互作用的机理解释，需要综合运用位错理论和流变应力公式进行推理分析，思维深度和知识关联度较高。 | 难度: 在简答题题型中，该题目要求对加工硬化的本质相似性和差异进行简要分析，涉及位错堆积、缠结及其相互作用的机理解释，并给出了流变应力的公式。这需要学生不仅理解位错理论的基本概念，还需要能够综合运用这些知识来解释现象，属于机理深度解释的难度等级。虽然题目没有要求全面分析复杂现象，但对机理的解释已经达到了较高的深度要求。" + }, + { + "idx": 2186, + "question": "Briefly analyze the essential similarities and differences of solid solution strengthening", + "answer": "Solid solution strengthening results from the interaction between dislocations and solute atoms, namely the Cottrell atmosphere hindering dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析固溶强化的基本相似点和差异点，需要文字解释和论述，属于简答题类型。 | 知识层次: 题目要求分析固溶强化的本质相似性和差异性，涉及对位错与溶质原子相互作用的深入理解（Cottrell atmosphere机制），需要综合运用材料强化机理知识进行机理解释和对比分析，属于需要推理分析和综合运用的复杂分析层次。 | 难度: 在简答题题型中，该题目要求对固溶强化的基本相似性和差异进行简要分析，涉及位错与溶质原子相互作用的机理解释（Cottrell atmosphere）。虽然不需要全面分析复杂现象，但需要机理层面的深度解释，属于该题型中较高难度的题目，符合等级4的标准。" + }, + { + "idx": 2187, + "question": "What effect does texture have on the properties of metals?", + "answer": "Due to texture-induced anisotropy in metals, it often causes inconvenience in metal processing. For example, cold-rolled magnesium sheets develop a (0001)<11\\overline{2}0> texture, making them prone to cracking during further processing; earing in deep-drawn metal cups; thermal cycling growth of metals, etc. However, in some cases, it also has beneficial aspects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纹理对金属性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释织构对金属性能的影响，并举例说明其不利和有利方面。这需要综合运用织构、各向异性、金属加工等概念，进行机理分析和实际应用关联，涉及多知识点的综合和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2188, + "question": "Briefly analyze the essential similarities and differences of grain refinement strengthening", + "answer": "Grain refinement strengthening occurs because the atoms at grain boundaries are irregularly arranged, with many impurities and defects, resulting in higher energy that hinders dislocation movement, σs=σ0+Kd−1/2; moreover, when grains are fine, deformation is uniform, stress concentration is low, and cracks are less likely to initiate and propagate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析晶粒细化强化的本质相似性和差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析晶粒细化强化的本质相似性和差异，涉及对晶界原子排列、位错运动阻碍机制、应力集中和裂纹扩展等多方面因素的综合理解和分析，需要深入理解材料科学中的强化机制并进行推理解释。 | 难度: 在简答题题型中，该题目要求对晶粒细化强化的机理进行深度解释，涉及原子排列、位错运动、应力分布等多个方面的综合分析和推理。虽然题目没有要求全面分析所有相关现象，但对机理的解释需要较高的知识掌握深度和逻辑推理能力，属于该题型中的较高难度等级。" + }, + { + "idx": 2189, + "question": "Briefly analyze the essential similarities and differences of dispersion strengthening", + "answer": "Dispersion strengthening occurs because dislocations bypass or cut through second-phase particles, requiring additional energy (such as surface energy or misfit energy); meanwhile, the elastic stress field around the particles interacts with dislocations, hindering their movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析分散强化的本质相似性和差异，需要文字解释和论述，而不是选择、判断或计算。答案也是以文字形式呈现的论述。 | 知识层次: 题目要求分析弥散强化的本质相似性和差异性，涉及位错与第二相颗粒的相互作用机制（如绕过或切割颗粒的能量需求、弹性应力场对位错运动的阻碍），需要综合运用材料科学中的位错理论和强化机制知识，进行机理层面的解释和对比分析，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对分散强化的机理进行深度解释，涉及位错与第二相粒子的相互作用、能量变化等复杂概念。虽然不需要全面分析所有相关现象，但需要对机理有较深入的理解和清晰的表述，属于机理深度解释的难度等级。" + }, + { + "idx": 2190, + "question": "When the bubble density in tungsten wire increases from 100/cm² to 400/cm², the tensile strength can approximately double, because bubbles can hinder dislocation motion. Analyze the mechanism by which bubbles impede dislocation motion.", + "answer": "The mechanism by which bubbles hinder dislocation motion is that when dislocations pass through bubbles, they cut the bubbles, increasing the area of the bubble-metal interface. This requires additional external shear stress to perform work, thereby enhancing the strength of tungsten metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析气泡阻碍位错运动的机制，需要文字解释和论述，答案也是以文字形式详细解释了机制，符合简答题的特征。 | 知识层次: 题目要求分析气泡阻碍位错运动的机制，涉及位错与气泡的相互作用、界面能变化以及外部应力需求等复杂概念，需要深入理解和综合分析材料微观结构与力学性能的关系。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求分析气泡阻碍位错运动的机制，需要综合运用材料科学中的位错理论和界面能概念，解释气泡如何通过增加界面面积来阻碍位错运动。虽然题目给出了部分背景信息（气泡密度增加导致强度提升），但解答需要深入理解位错与气泡相互作用的微观机制，并准确表述这一过程如何导致宏观力学性能的变化。这比简单的概念复述或单一原理应用（等级3）要求更高，但尚未达到需要分析多因素耦合或建立复杂模型的全面分析难度（等级5）。" + }, + { + "idx": 2191, + "question": "Given the Burgers vector of a dislocation as b, the bubble radius as r, and the specific interfacial energy between the bubble and metal as σ, determine the increment of shear stress Δτ.", + "answer": "The increased interfacial area between the bubble and metal after the dislocation cuts the bubble is A=2rb. The increment of interfacial energy is 2rbσ. If the increment of shear stress for a dislocation cutting one bubble is Δτ', then the work done by the stress is Δτ'b. Therefore, 2rbσ=Δτ'b, Δτ'=2rσ. When the bubble density is n, the total increment of shear stress Δτ=nΔτ'=2nrσ. It can be seen that the increment of shear stress is proportional to the bubble density.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（Burgers vector、bubble radius、specific interfacial energy）进行计算，并推导出剪切应力的增量。解答过程中涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（计算增加的界面面积、界面能增量、单个气泡引起的剪切应力增量，最后计算总剪切应力增量），涉及多个概念（Burgers矢量、界面能、剪切应力）的关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解多个概念（Burgers矢量、界面能、剪切应力增量）并进行关联分析。解题步骤涉及多步计算（面积增量、能量增量、应力增量计算），但变量关系相对明确（线性比例关系）。相比简单单步计算题（等级2）更复杂，但尚未达到需要处理复杂多变量或非线性关系的等级4难度。" + }, + { + "idx": 2192, + "question": "Why is the actual tensile strength of ceramics lower than the theoretical yield strength?", + "answer": "This is due to the unavoidable microscopic voids present during the sintering of ceramic powders. During cooling or thermal cycling, thermal stresses generate microcracks, and surface cracks caused by corrosion result in ceramics, unlike metals, having inherent microcracks. At the crack tip, severe stress concentration occurs. According to elastic mechanics estimates, the maximum stress at the crack tip has already reached the theoretical fracture strength or theoretical yield strength (because ceramic crystals have very few mobile dislocations, and dislocation motion is extremely difficult, so once the yield strength is reached, fracture occurs). Conversely, one can calculate the nominal stress at which the crystal fractures when the maximum stress at the crack tip equals the theoretical yield strength, and this value is extremely close to the actual measured tensile strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的实际拉伸强度低于理论屈服强度，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要深入分析陶瓷材料实际拉伸强度低于理论屈服强度的原因，涉及微观缺陷、应力集中、弹性力学估算等多个复杂概念的综合运用和机理解释，思维过程要求较高的推理分析能力。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析陶瓷实际拉伸强度低于理论屈服强度的复杂现象。需要综合运用弹性力学、晶体缺陷理论、烧结工艺等多领域知识，解释微观缺陷与宏观性能的关联机制。解题步骤涉及应力集中计算、理论强度推导、材料行为对比等复杂推理过程，属于该题型框架内对综合分析和机理解释能力要求最高的等级。" + }, + { + "idx": 2193, + "question": "This shows, what effect does recovery have on recrystallization?", + "answer": "After polygonization, the dislocation energy decreases, reducing the stored energy and thereby diminishing the driving force for subsequent recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释恢复对再结晶的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释恢复对再结晶的影响机制，涉及位错能量变化、储存能量减少以及再结晶驱动力减小的因果关系分析，需要综合运用材料科学中的位错理论和再结晶原理进行推理和解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求分析回复过程对再结晶的影响机制，需要理解位错多边形化、储存能变化等概念，并解释其对再结晶驱动力的影响。虽然不涉及多因素综合分析（等级5），但需要对材料变形与回复过程的机理有较深入的理解，属于需要机理解释的中高难度简答题。" + }, + { + "idx": 2194, + "question": "Given that the elastic modulus of sintered alumina is $370\\\\mathrm{GPa}$ when its porosity is $5\\\\%$, if the elastic modulus of another sintered alumina is $270~\\\\mathrm{GPa}$, calculate its porosity.", + "answer": "The relationship between the elastic modulus $E$ of ceramic materials and their pore volume fraction $\\\\varphi$ can be expressed as $$ E=E_{\\\\circ}(1-1.9\\\\varphi+0.9\\\\varphi^{2}) $$ where $E_{0}$ is the elastic modulus of the material without pores. Given that when $\\\\varphi=0.05$, $E=370~\\\\mathrm{GPa}$, thus $$ E_{\\\\circ}={\\\\frac{E}{1-1.9{\\\\varphi}+0.9{\\\\varphi}^{2}}}={\\\\frac{370}{1-1.9\\\\times0.05+0.9\\\\times(0.05)^{2}}}=407.8{\\\\mathrm{~GPa}} $$ When $E=270$ GPa, $$ 270=407.8(1-1.9\\\\varphi+0.9\\\\varphi^{2}) $$ which simplifies to $$ 0.9\\\\varphi^{2}-1.9\\\\varphi+0.338=0 $$ Therefore, $$ \\\\varphi=0.196=19.6\\\\% $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数值计算另一个烧结氧化铝的孔隙率。解答过程涉及数值代入、方程求解和百分比计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式的推导和求解二次方程，涉及对弹性模量与孔隙率关系的理解和应用，需要综合分析已知条件并正确运用数学工具解决问题。 | 难度: 在计算题中属于综合性计算问题，需要应用给定的公式进行多步计算，包括求解二次方程。虽然涉及的概念和公式较为直接，但解题步骤较为复杂，需要一定的综合分析能力。与更简单的单步计算题相比，难度较高；但与涉及多变量或更复杂数学工具的题目相比，难度适中。" + }, + { + "idx": 2195, + "question": "Why is the compressive strength of ceramics always higher than the tensile strength?", + "answer": "The compressive strength of ceramics is generally about 15 times the tensile strength. This is because under tension, when a crack reaches the critical size, it becomes unstable and propagates rapidly, leading to fracture; whereas under compression, cracks either close or propagate steadily and slowly, turning parallel to the compression axis. In other words, under tension, the tensile strength of ceramics is determined by the maximum crack size in the crystal, while the compressive strength is determined by the average size of the cracks.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的抗压强度总是高于抗拉强度，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释陶瓷压缩强度高于拉伸强度的机理，涉及裂纹在不同应力状态下的行为差异，需要综合运用材料科学中的断裂力学知识，进行推理分析和机理解释。这超出了简单记忆或基本应用，属于对复杂现象的综合分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求考生不仅理解陶瓷材料压缩强度和拉伸强度的差异现象，还需要深入解释其背后的微观机理（如裂纹扩展行为的不同模式）。这需要综合运用材料断裂力学知识，分析不同应力状态下裂纹行为的差异，并准确描述临界裂纹尺寸与强度之间的关系。虽然不需要进行多因素交互作用的全面分析（等级5要求），但已超出基础概念解释层面，属于需要深入理解材料失效机理的题目。" + }, + { + "idx": 2196, + "question": "A subgrain boundary is composed of several edge dislocations with a misorientation of 0.057 degrees. Assuming there is no interaction between the dislocations before polygonization, by what factor does the distortion energy change after the formation of the subgrain?", + "answer": "The energy per unit length of a dislocation line is W_I = (G b^2) / (4π(1-ν)) * ln(R/r_0), where r_0 is the radius of the dislocation core region and R is the radius of the maximum range of the dislocation stress field. If we take r_0 ≈ b = 10^-8 cm and R ≈ 10^-4 cm, then before polygonization, W_D = (G b^2) / (4π(1-ν)) * ln(10^4). After polygonization, R = D = b / θ = 10^-8 / 10^-3 = 10^-5 cm, and W_31* = (G b^2) / (4π(1-ν)) * ln(10^3). Thus, W_I* / W_I1 = ln(10^3) / ln(10^4) = 0.75.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解亚晶界形成后畸变能的变化因子，答案中包含了具体的公式推导和数值计算过程。 | 知识层次: 题目需要进行多步计算，包括应用位错能量公式、对数运算和比例计算，同时需要理解位错多边形化前后的能量变化机制。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式并进行多步计算。题目涉及位错能量计算、多边形化过程的理解以及对数运算的综合应用，虽然计算过程明确但需要较强的概念关联能力。相比简单代入公式的等级2题目更复杂，但尚未达到需要处理多变量或非线性关系的等级4难度。" + }, + { + "idx": 2197, + "question": "Given that the recovery activation energy of a zinc single crystal is $20000\\\\mathrm{J/mol}$, removing $2\\\\%$ of the work hardening at $50^{\\\\circ}\\\\mathrm{C}$ requires $13\\\\textup{d}$; how much should the temperature be increased to remove the same amount of work hardening in $5\\\\textrm{min}$?", + "answer": "When cold-plastically deformed metal undergoes recovery, if the recovery amount $R$ (in this case, the removed portion of work hardening) is constant, the relationship between the required recovery time $t$ and the recovery temperature $T$ can be expressed as $$ \\\\ln t=a+{\\\\frac{Q}{R}}{\\\\frac{1}{T}}$$ where $a$ is a constant; $\\\\boldsymbol{Q}$ is the recovery activation energy. Accordingly, we have $$ \\\\frac{t_{1}}{t_{2}}=\\\\exp\\\\biggl[-\\\\frac{Q}{R}\\\\Bigl(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\Bigr)\\\\biggr]$$ From the problem statement, $$ T_{2}=-50^{\\\\circ}C=223\\\\mathrm{~K~}$$ $$ t_{2}=13~\\\\mathrm{d}=18~500~\\\\mathrm{min},\\\\quad Q=20~000~\\\\mathrm{J/mol}$$ When $t_{1}=5\\\\mathrm{min}$ is required, then $$ {\\\\frac{5}{18500}}{=}\\\\exp\\\\Bigl[-{\\\\frac{20000}{2}}\\\\Bigl({\\\\frac{1}{223}}-{\\\\frac{1}{T_{1}}}\\\\Bigr)\\\\Bigr]$$ $$ {\\\\frac{1}{T_{1}}}={\\\\frac{1}{223}}-{\\\\frac{\\\\ln3700}{10000}}$$ Therefore, the recovery temperature $$ T_{1}=273\\\\mathrm{~K~}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及激活能、温度和时间的关系，最终需要计算出具体的温度值。答案展示了详细的数学推导和计算过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式的转换和应用，需要理解恢复激活能与温度和时间的关系，并进行综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解恢复激活能的概念，并应用对数关系式进行多步计算。题目涉及温度单位转换、时间单位统一、以及对数运算，但不需要处理复杂多变量或非常规数学方法。" + }, + { + "idx": 2198, + "question": "The strength of OFHC copper (oxygen-free high-conductivity copper) can be increased by more than 2 times after cold drawing deformation. If the safety factor for allowable stress is taken as 2, calculate the service life of an OFHC copper component working at $130^{\\\\circ}\\\\mathrm{C}$. (Given: $A=10^{12}1/\\\\operatorname*{min}, \\\\frac{Q}{R}=$ $1.5\\\\times10^{4}~\\\\mathrm{K}, t_{0.5}$ is the time required for 50% recrystallization)", + "answer": "Since OFHC copper operates at $130^{\\\\circ}C$, with a strength design safety factor of 2, for cold-worked and strengthened materials, only 50% recrystallization is allowed, i.e., $$ \\\\begin{array}{r}{\\\\frac{1}{t_{0.5}}=A\\\\mathrm{exp}\\\\left(-\\\\frac{Q}{R T}\\\\right)} \\\\ {\\\\mathrm{lg}(A t_{0.5})=\\\\frac{Q}{R T}\\\\mathrm{lg}\\\\mathrm{~e~}}\\\\end{array}$$ $A=10^{12}~1/\\\\operatorname*{min}{},\\\\frac{Q}{R}=1.5\\\\times10^{4}~\\\\mathrm{K}{},T=130^{\\\\circ}\\\\mathrm{C}=403~\\\\mathrm{K}$. Therefore, $$ t_{0.5}=14497\\\\mathrm{min}=242\\\\mathrm{h}$$ Thus, the service life of OFHC copper under these working conditions is $242\\\\mathrm{~h~}$ \\\\lg(10^{12}t_{0.5})={\\\\frac{1.5\\\\times10^{4}}{403}}\\\\times0.4342$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及具体的物理量计算和公式推导，最终得出一个具体的数值结果（242小时）。 | 知识层次: 题目涉及多步计算和概念关联，需要应用Arrhenius方程进行数值计算，并结合材料科学中的再结晶理论进行综合分析。虽然不涉及复杂的推理或创新设计，但需要理解温度、时间和再结晶百分比之间的关系，并进行适当的单位转换和公式变形。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式并进行多步骤计算。题目涉及材料科学中的再结晶动力学，要求理解并正确应用阿伦尼乌斯方程，同时需要进行单位转换和对数运算。虽然计算过程较为直接，但需要综合运用多个概念和步骤，因此在同类计算题中属于中等偏上的难度。" + }, + { + "idx": 2199, + "question": "What is the difference between crazing and cracking?", + "answer": "Crazing is different from cracking. The two open surfaces of a crack are completely empty, whereas the surfaces of a craze consist of highly oriented fiber bundles and voids, which still retain some strength. The formation of crazes is due to localized yielding and cold drawing of the material under tensile stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两个概念的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对材料科学中基本概念（crazing和cracking）的记忆和理解，主要涉及定义和基本特征的描述，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分两个相关但不同的概念（crazing和cracking），并解释它们之间的关键差异。虽然需要一定的理解和记忆，但不需要复杂的分析或多层次的概念体系阐述。主要考察对基础概念的理解和表达能力，属于中等难度的简答题。" + }, + { + "idx": 2200, + "question": "The melting point of iron is known to be 1,538℃, estimate the minimum recrystallization temperature of iron", + "answer": "The minimum recrystallization temperature of iron is T_r=0.4×(1,538+273)=723 K", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计铁的再结晶温度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的应用和简单计算，仅需将已知的熔点转换为绝对温度后套用0.4的系数即可得到结果，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需套用单一已知公式（Tr=0.4×Tm）进行单位换算和简单乘法运算，无需理解复杂概念或进行多步骤推导。题目直接给出了铁的熔点数据，且计算过程不涉及任何变量转换或条件判断，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2201, + "question": "Based on the minimum recrystallization temperature of iron, 723 K, select the recrystallization annealing temperature for iron", + "answer": "The recrystallization annealing temperature for iron T=823∼923 K", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的最低再结晶温度选择铁的再结晶退火温度，答案需要文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求基于铁的再结晶温度（723 K）选择再结晶退火温度，属于基本公式应用和直接套用。虽然需要理解再结晶退火温度通常比再结晶温度高100-200 K，但整体思维过程较为简单，属于简单应用层次。 | 难度: 在简答题中属于简单应用过程描述，题目直接给出了铁的最低再结晶温度723K，并要求选择再结晶退火温度。答案直接套用了基本公式（通常再结晶退火温度比最低再结晶温度高100-200K），解题步骤简单，无需深入解释或复杂计算。" + }, + { + "idx": 2202, + "question": "Given that the melting point of copper is 1,083℃, estimate the minimum recrystallization temperature of copper", + "answer": "The minimum recrystallization temperature of copper is T_r=0.4×(1,083+273)=542 K", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（估计铜的最低再结晶温度），并给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用（0.4×Tm），仅需简单计算和单位转换，不需要多步推理或综合分析 | 难度: 在计算题中属于最低难度，仅需套用单一公式（Tr=0.4×(Tm+273)）进行直接计算，无需任何推导或组合运算。所有参数均为已知条件，计算过程仅涉及基本四则运算，属于典型的等级1直接计算题。" + }, + { + "idx": 2203, + "question": "Based on the minimum recrystallization temperature of copper being 542 K, determine the recrystallization annealing temperature for copper", + "answer": "The recrystallization annealing temperature for copper T=643∼743 K", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的最低再结晶温度（542 K）进行计算，以确定铜的再结晶退火温度范围（643∼743 K）。解答过程涉及数值计算和温度范围的确定，符合计算题的特征。 | 知识层次: 题目需要应用已知的铜的最低再结晶温度（542 K）来计算再结晶退火温度范围（643~743 K），属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目仅需根据已知的铜最低再结晶温度542K，直接套用再结晶退火温度的计算公式（通常为1.2~1.4倍最低再结晶温度），进行简单乘法运算即可得出结果。不需要多个公式组合或复杂推导，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 2204, + "question": "Pure zirconium requires 40 h and 1 h of isothermal annealing at $553^{\\\\circ}\\\\mathrm{C}$ and $627^{\\\\circ}\\\\mathrm{C}$ respectively to complete recrystallization. Calculate the recrystallization activation energy of this material.", + "answer": "From Equation (7-6) in Section 7.3: $$Therefore$$ Q=R\\\\ln\\\\frac{t_{1}}{t_{2}}\\\\bigg/\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}\\\\Big)$$ Substituting the known values, we get $$ Q={\\\\frac{8.31\\\\ln{\\\\frac{40}{1}}}{{\\\\frac{1}{553+273}}-{\\\\frac{1}{627+273}}}}=3.08\\\\times10^{5}~\\\\mathrm{J/mol}$$ \\\\ln{\\\\frac{t_{1}}{t_{2}}}=\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}\\\\Big)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解再结晶激活能，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式的变形和数值代入，同时需要理解再结晶激活能的概念及其与温度和时间的关系。虽然不涉及复杂的综合分析或机理解释，但比简单的公式应用要求更高。 | 难度: 在计算题中属于综合性计算问题，需要应用Arrhenius方程进行多步计算，涉及温度单位转换（摄氏转开尔文）、对数运算和单位换算。虽然计算步骤明确，但需要正确理解并关联再结晶动力学概念，属于中等应用层次的计算题。" + }, + { + "idx": 2205, + "question": "For metals and alloys that do not undergo phase transformations in the solid state, can their grain size be changed without remelting? What methods can be used to alter it?", + "answer": "Yes. It can be achieved through cold deformation followed by recrystallization annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对金属和合金的晶粒尺寸变化方法进行解释和论述，答案提供了具体的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解金属和合金的晶粒尺寸变化的基本概念，还需要应用冷变形和再结晶退火的方法来改变晶粒尺寸。这涉及到多步骤的过程和概念之间的关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解金属和合金的晶粒尺寸变化原理，并能够综合运用冷变形和再结晶退火的概念来解答问题。虽然涉及多步操作和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2206, + "question": "A cold-drawn steel wire rope was used to hoist a large workpiece into a furnace and was heated together with the workpiece to $1,000^{\\circ}\\mathrm{C}$. Upon completion of heating, when the workpiece was lifted out, the steel wire rope broke. Analyze the reason for this.", + "answer": "The processing of the cold-drawn steel wire rope is a cold-working process. Due to work hardening, the strength and hardness of the steel wire increase, thereby enhancing its load-bearing capacity. When heated, if the temperature exceeds its recrystallization temperature, the steel wire rope undergoes recrystallization, leading to a reduction in strength and hardness. Once the external load exceeds its load-bearing capacity, it will break.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢丝绳断裂的原因，答案提供了详细的文字解释和论述，涉及冷加工、加工硬化、再结晶等概念，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要综合运用材料科学中的冷加工、加工硬化、再结晶等概念，分析钢丝绳在高温下的性能变化及其断裂原因。这涉及到多个知识点的关联和深层次的机理解释，属于复杂分析的范畴。 | 难度: 在简答题中属于机理深度解释难度等级。该题目要求考生不仅理解冷拔钢丝绳的加工工艺和性能变化，还需要解释高温对其性能的影响机制，包括再结晶过程及其对强度和硬度的具体影响。虽然不涉及多个复杂现象的交叉分析，但对单一现象的机理解释要求较高，需要综合运用材料科学知识进行推理和论述。" + }, + { + "idx": 2207, + "question": "There are three types of ingots: pure Ti, Al, and Pb. It is known that the melting point of Ti is 1672°C, with a hexagonal close-packed structure below 883°C and a face-centered cubic structure above 883°C; the melting point of Al is 660°C, with a face-centered cubic structure; the melting point of Pb is 328°C, with a face-centered cubic structure. Determine the order of their rolling difficulty at room temperature (20°C).", + "answer": "At room temperature, Pb is the easiest to roll, followed by Al, and Ti is the most difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据给定的材料特性和条件，通过文字解释和论述来确定不同金属在室温下的轧制难度顺序，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目需要综合运用金属的晶体结构、相变温度和室温下的力学性能等知识，进行多步分析和比较，以确定不同金属在室温下的轧制难度。这涉及到对材料科学中多个概念的理解和应用，但不需要进行复杂的计算或深入的机理分析。 | 难度: 在简答题中属于中等难度，需要综合分析不同金属的晶体结构和力学性能，并结合室温条件进行排序。虽然涉及多个概念（如晶体结构、熔点、塑性变形能力），但解题步骤相对直接，主要考察对基础知识的掌握和应用能力，无需进行深度关联性分析或多角度论述。" + }, + { + "idx": 2208, + "question": "What measures should be taken for A1 and Ti to enable them to be rolled into thin sheets?", + "answer": "For A1 and Ti, intermediate annealing (i.e., recrystallization annealing) should be employed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取的措施，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解A1和Ti的加工特性，并应用中间退火（再结晶退火）的概念来解决实际问题。这涉及到材料加工过程中的多步操作和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及A1和Ti的轧制工艺，但只需要考生掌握基本的金属加工知识（如中间退火和再结晶退火的应用），并进行简单的综合说明即可。不需要多角度分析或深度关联性分析，解题步骤相对直接，符合等级3\"综合分析和说明\"的标准。" + }, + { + "idx": 2209, + "question": "Given that brass containing ${w_{\\\\mathrm{Zn}}}=0.30$ requires $^{1\\\\textrm{h}}$ to complete recrystallization at a constant temperature of $400^{\\\\circ}\\\\mathrm{C}$, and $2\\\\textrm{h}$ at $390^{\\\\circ}\\\\mathrm{C}$, calculate the time required to complete recrystallization at a constant temperature of $420^{\\\\circ}\\\\mathrm{C}$.", + "answer": "The rate of recrystallization is given by $Q$ is the activation energy for recrystallization) Let $t$ be the time required to complete recrystallization, then$$ $$ \\\\begin{array}{r}{\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}=\\\\ln\\\\frac{t_{2}}{t_{1}}}\\\\\\\\ {\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{3}}=\\\\ln\\\\frac{t_{3}}{t_{1}}}\\\\end{array}$$ Substituting $T_{1}=673~\\\\mathrm{K},t_{1}=1~\\\\mathrm{h};T_{2}=663~\\\\mathrm{K},t_{2}=2~\\\\mathrm{h};T_{3}=693~\\\\mathrm{K}$ into the above equations, we obtain$$ t_{3}\\\\approx0.26~\\\\mathrm{h}$$ That is, completing recrystallization at a constant temperature of $420^{\\\\circ}\\\\mathrm{C}$ requires approximately $0,26\\\\mathrm{~h~}$ \\\\begin{array}{c}{{V_{\\\\parallel\\\\parallel}t=1}}\\\\\\\\ {{A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{1}}}t_{1}=A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{2}}}t_{2}=A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{3}}}t_{3}}}\\\\\\\\ {{-\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}\\\\Big)=\\\\ln\\\\frac{t_{2}}{t_{1}}}}\\\\\\\\ {{-\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{3}}\\\\Big)=\\\\ln\\\\frac{t_{3}}{t_{1}}}}\\\\end{array}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在特定温度下完成再结晶所需的时间。答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解再结晶速率与温度的关系，并通过给定的温度和时间数据推导出新的条件下的时间。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度和时间的关系转换，以及对数运算。虽然计算步骤较多，但题目提供了明确的初始条件和公式框架，属于中等应用层次的计算题。" + }, + { + "idx": 2210, + "question": "Design an experimental method to determine the variation of recrystallization nucleation rate $\\dot{N}$ with time at a certain temperature (T).", + "answer": "The recrystallization nucleation rate $\\dot{N}$ can be determined using the metallographic method. Specific steps: Heat a batch of specimens deformed with a large strain to a certain temperature (T) and hold, then quench one specimen at regular time intervals t. Observe the prepared metallographic samples under a microscope and count the number of recrystallization nuclei N. After obtaining a set of data (several points), plot an N-t graph. The slope at each point on the N-t curve represents the recrystallization nucleation rate $\\dot{N}$ of the material at temperature T for different holding times.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计一个实验方法并详细描述步骤，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的实验步骤和数据处理方法，符合简答题的特征。 | 知识层次: 题目要求设计一个实验方法来测定再结晶形核速率随时间的变化，这需要综合运用材料科学的知识，包括对再结晶过程的理解、实验设计能力、数据分析和解释能力。此外，还需要考虑实验的可行性和准确性，以及对结果的优化和解释。这属于高级综合层次，因为它不仅要求对基础知识的深入理解，还需要创新应用和设计优化的能力。 | 难度: 在简答题-高级综合题型中，该题目要求设计完整的实验方法并解释原理，涉及创新应用和深度理解。需要综合运用金属学、热处理、显微分析等多领域知识，并具备实验设计能力。解题步骤复杂，需考虑时间变量控制、数据采集与处理、曲线分析等环节，远超同类题型中常规理论解释题的难度要求。" + }, + { + "idx": 2211, + "question": "Design an experimental method to determine the variation of growth linear velocity G with time at a certain temperature (T).", + "answer": "The growth linear velocity G can be determined using the metallographic method. Specific steps: Perform metallographic observation on a set of quenched samples from the nucleation rate experiment, measure the linear dimension D of the largest nucleus in each sample (representing different holding times), plot a D-t graph, and the slope at each point on the D-t curve represents the growth linear velocity G at temperature T for different holding times.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计一个实验方法并详细描述步骤，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求设计实验方法来确定生长线性速度G随时间的变化，这需要综合运用材料科学的知识，包括实验设计、数据分析和结果解释。这涉及到对材料生长机制的深度理解，以及对实验技术的优化和创新应用。 | 难度: 在简答题（需要文字解释和论述）题型中，该题目属于高级综合知识层次，要求设计完整的实验方法并解释原理。具体表现为：" + }, + { + "idx": 2212, + "question": "When cold-drawn copper wires are used as overhead conductors (requiring certain strength), what final heat treatment process should be adopted?", + "answer": "Stress relief annealing (low-temperature annealing) should be adopted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释并论述应采取的热处理工艺，答案以文字解释形式给出，而非选择、判断或计算。 | 知识层次: 题目要求根据铜线的冷加工状态和作为架空导体的强度要求，选择合适的最终热处理工艺。这需要理解冷加工对材料性能的影响、不同热处理工艺的作用，以及如何通过热处理在满足强度要求的同时消除残余应力。涉及多步概念关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解冷拉铜线的特性和应用场景，并结合强度要求选择合适的最终热处理工艺。虽然涉及概念关联和综合分析，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 2213, + "question": "Can metal castings refine grain size through recrystallization annealing?", + "answer": "Recrystallization annealing must be applied to materials that have undergone cold plastic deformation processing, with the purpose of improving the microstructure and properties of the material after cold deformation. The temperature of recrystallization annealing is relatively low, generally below the critical point. If recrystallization annealing is applied to castings, their microstructure will not undergo phase transformation, nor will there be a driving force for the formation of new nuclei (such as stored energy from cold deformation, etc.), so new grains will not form, and grain refinement cannot be achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对金属铸件是否可以通过再结晶退火细化晶粒进行解释和论述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要理解再结晶退火的基本概念，还需要分析其在金属铸件中的应用限制，涉及微观结构变化、相变驱动力等机理的解释，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求考生不仅理解再结晶退火的基本原理，还需要综合运用材料科学知识分析铸造组织的特性。题目涉及冷变形与铸造组织的本质区别、再结晶驱动力来源等深层次机理解释，需要考生进行逻辑严密的推理分析。虽然未达到最高等级要求的跨学科或多因素全面分析，但已属于需要深度机理解释的较难题型。" + }, + { + "idx": 2215, + "question": "Point out the unreasonable aspects of the above process and formulate a reasonable grain refinement process", + "answer": "Under the condition of 80% deformation, annealing at 150°C for 1h can refine its grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出不合理之处并提出合理的晶粒细化工艺，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求指出不合理之处并设计合理的晶粒细化工艺，需要综合运用材料科学知识进行推理分析，涉及变形条件、退火温度和时间等多因素的综合考虑，思维过程较深。 | 难度: 在简答题-复杂分析题型中，该题目要求考生不仅指出不合理之处，还需要设计合理的晶粒细化工艺并解释机理。这需要综合运用材料科学知识（如变形量、退火温度和时间对晶粒尺寸的影响）和推理分析能力（判断工艺参数的合理性）。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础描述层面，达到了机理深度解释的难度水平。" + }, + { + "idx": 2216, + "question": "To refine the grain of a pure aluminum part, it was cold deformed by 5% and then annealed at 650°C for 1 hour, but the structure coarsened instead. Analyze the reason for this.", + "answer": "Since the deformation of the aluminum part was under the critical deformation degree, only a few recrystallization nuclei could form during annealing, resulting in extremely coarse grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析原因，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要综合运用材料科学中的变形、再结晶和晶粒生长等知识，分析冷变形程度与临界变形度的关系，以及退火过程中晶粒长大的机理。这涉及多步骤的推理和综合分析，超出了简单记忆或直接应用的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用金属学原理（临界变形度、再结晶形核机制）解释反常现象（退火后晶粒粗化）。解题需完成以下复杂步骤：1) 识别5%冷变形低于临界变形度这一关键条件；2) 推导有限形核导致异常晶粒长大的机理；3) 关联650℃高温退火对粗化的促进作用。这需要将变形工艺参数-微观组织演变-热处理条件三者建立系统关联，属于该题型下对综合分析能力和机理深度解释要求最高的层级。" + }, + { + "idx": 2217, + "question": "Explain the meanings of N0, G0, Qg, Qn and their influencing factors.", + "answer": "N0 and G0 are constants in the Arrhenius equation; Qn is the activation energy for recrystallization nucleation; Qg is the activation energy for recrystallized grain growth. Qn and Qg are mainly influenced by deformation amount, metal composition, metal purity, and original grain size. When the deformation amount exceeds 5%, Qn and Qg are approximately equal. For high-purity metals, the value of Qg is roughly equivalent to the activation energy for grain boundary self-diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个术语的含义及其影响因素，需要文字解释和论述，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目要求解释多个专业术语（N0, G0, Qg, Qn）的含义及其影响因素，涉及Arrhenius方程中的常数、再结晶成核和晶粒生长的活化能等概念。需要理解这些术语的定义，并能分析它们与变形量、金属成分、纯度及原始晶粒尺寸等因素的关联。虽然不涉及复杂计算，但需要对多个概念进行综合理解和应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求解释多个专业术语（N0, G0, Qg, Qn）的含义及其影响因素，并需要综合分析这些因素之间的关系。题目不仅涉及基础概念的理解，还需要对金属材料的变形、成分、纯度及原始晶粒尺寸等多方面因素进行论述，属于多角度分析论述的难度等级。" + }, + { + "idx": 2218, + "question": "When cold-drawn copper wire is used as lamp filament wire (requiring good toughness), what final heat treatment process should be adopted?", + "answer": "Recrystallization annealing (high-temperature annealing) should be adopted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取何种最终热处理工艺，并给出了具体的答案（再结晶退火），这需要文字解释和论述，而不是从选项中选择或简单的判断对错。 | 知识层次: 题目要求根据铜丝的具体应用场景（灯丝需要良好的韧性）选择合适的最终热处理工艺，这涉及到对冷加工和热处理工艺对材料性能影响的理解，以及如何通过再结晶退火来恢复材料的韧性。这需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解冷拉铜丝作为灯丝材料时的性能要求（韧性），并关联到再结晶退火工艺的作用（恢复塑性、消除加工硬化）。虽然涉及概念关联和综合分析，但不需要多角度论述或深度关联性分析，解题步骤相对明确。" + }, + { + "idx": 2219, + "question": "To refine the grain size of a pure aluminum part, the cold deformation was increased to 80%, followed by annealing at 650°C for 1 hour, but coarse grains were still obtained. Analyze the reason.", + "answer": "The reason is the inappropriate selection of recrystallization annealing temperature (the temperature was too high). According to the estimation of T_rec ≈ 0.4T_melt, where T_melt = 100°C, the recrystallization temperature should not exceed 200°C. Since annealing was performed at 650°C for 1 hour, the grains remained coarse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析原因并提供解释，答案通过文字论述解释了为什么在650°C退火后晶粒仍然粗大，涉及材料科学中的再结晶温度概念，但没有涉及计算、选择或判断对错。 | 知识层次: 题目需要理解再结晶温度的计算方法（T_rec ≈ 0.4T_melt），并分析实际工艺参数（650°C）与理论计算值（200°C）的差异，属于多步计算和概念关联的中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。题目要求考生不仅需要理解再结晶退火温度的概念，还需要进行多步计算（如T_rec ≈ 0.4T_melt的计算），并将计算结果与实际操作条件进行综合分析。此外，题目还要求考生能够解释为什么高温退火会导致晶粒粗大，这需要对材料科学中的晶粒生长机制有较深的理解。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 2220, + "question": "Compare the differences in dislocation motion between stress relief annealing and dynamic recovery processes.", + "answer": "In the stress relief annealing process, dislocations rearrange through climb and glide, transitioning from a high-energy state to a low-energy state; in the dynamic recovery process, it is through cross-slip of screw dislocations and climb of edge dislocations that opposite-sign dislocations cancel each other out, maintaining a dynamic balance between dislocation multiplication rate and dislocation annihilation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较两种不同过程中位错运动的差异，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求比较两种不同热处理过程中位错运动的差异，涉及到位错攀移、滑移、交叉滑移等复杂机制的解释，需要综合运用位错理论、热力学和动力学知识进行分析和推理，属于对材料科学中位错行为的深度理解和机理解释。 | 难度: 在简答题的复杂分析题型中，该题目要求对两种不同热处理过程中的位错运动机制进行机理深度解释。需要综合运用位错理论、热激活过程等知识，并比较两种过程的异同。虽然不涉及多因素交互作用的全面分析（等级5特征），但对机理描述的深度要求明显高于基础概念题（等级3），属于需要精准表述专业机理的难度层级。" + }, + { + "idx": 2221, + "question": "A low-carbon steel part has developed banded structure, how to eliminate or improve the banded structure through heat treatment methods?", + "answer": "For materials that have developed banded structure, heating in the single-phase region and normalizing treatment can eliminate or improve it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述如何通过热处理方法消除或改善带状组织，答案提供了具体的处理方法和解释，符合简答题的特征。 | 知识层次: 题目要求通过热处理方法来消除或改善带状组织，需要理解带状组织的形成原因以及热处理工艺（如单相区加热和正火处理）对其影响。这涉及到多步概念关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解带状组织的形成原因，并能够综合分析和说明通过热处理（如单相区加热和正火处理）来消除或改善带状结构的方法。虽然涉及多步概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2222, + "question": "How to distinguish dynamic and static recovery, and dynamic and static recrystallization from the microstructure", + "answer": "During static recovery, clear subgrain boundaries can be observed, while static recrystallization forms equiaxed grains. In contrast, dynamic recovery forms cellular substructures, and dynamic recrystallization produces dislocation-tangled cells within equiaxed grains, which are finer than those formed by static recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来区分动态和静态恢复以及动态和静态再结晶的微观结构特征，答案提供了详细的文字描述而非选择、判断或计算。 | 知识层次: 题目要求区分动态和静态回复以及动态和静态再结晶的微观结构特征，需要理解并应用相关概念，进行多步分析和比较，涉及概念关联和综合分析。虽然不涉及复杂计算，但需要对不同条件下的微观结构变化有较深入的理解和对比分析能力。 | 难度: 在简答题题型中，该题目要求对动态和静态恢复、动态和静态再结晶的微观结构特征进行多角度分析论述。需要考生不仅掌握相关概念，还能从微观结构特征上进行对比和综合分析，涉及多个知识点的关联和应用。虽然不需要进行深度关联性分析，但解题步骤较为复杂，要求考生具备较强的综合分析能力。" + }, + { + "idx": 2223, + "question": "A low-carbon steel part requires isotropy, but a relatively obvious banded structure forms after hot working. How can the formation of banded structure be mitigated or eliminated by controlling the hot working process?", + "answer": "First, avoid deformation in the two-phase region; second, reduce the content of impurity elements; third, use high-temperature diffusion annealing to eliminate element segregation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过控制热加工过程来减轻或消除带状结构的形成，答案提供了具体的步骤和措施，属于简答题类型。 | 知识层次: 题目要求通过控制热加工过程来减轻或消除带状结构的形成，需要综合运用材料科学中的相变、元素偏析和热加工工艺等知识。解答涉及多步分析和概念关联，如避免两相区变形、减少杂质元素含量和使用高温扩散退火等，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求考生不仅理解带状结构的形成原因，还需要从多个方面（避免两相区变形、减少杂质元素含量、高温扩散退火）提出具体的控制措施，并进行关联性分析。这需要考生具备综合分析能力和对热加工工艺的深入理解，属于中等应用层次中较高的难度。" + }, + { + "idx": 2224, + "question": "Assuming the recrystallization temperature is defined as the temperature at which 95% recrystallization is completed within 1h, according to the Arrhenius equations Ṅ=N0exp(−Qn/RT) and G=G0exp(−Qg/RT), it can be inferred that the recrystallization temperature will be a function of G and Ṅ. Determine the functional relationship between the recrystallization temperature and G0, N0, Qg, Qn.", + "answer": "According to the J-M equation, if the temperature at which 95% recrystallization is completed within 1h is defined as TF, then 0.95=1−exp(−π/3 ṄG3t0^4). Therefore, t0=(2.86/ṄG3)^1/4. Substituting the Arrhenius equations, we obtain N0G0^3exp(−(Qn+3Qg)/RTF)=k. Rearranging gives TF=(Qn+3Qg)/(R ln(N0G0^3/k))=k′(Qn+3Qg). This equation represents the functional relationship between TF and N0, G0, Qn, Qg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据给定的Arrhenius方程推导出再结晶温度与G0、N0、Qg、Qn之间的函数关系，涉及公式应用和推导过程，属于计算题。答案展示了具体的推导步骤和最终的函数关系式，符合计算题的特征。 | 知识层次: 题目需要综合运用Arrhenius方程和J-M方程，进行多步推导和公式变换，涉及多个变量的关联分析，要求较高的推理能力和综合分析能力。 | 难度: 在计算题中属于机理相关复杂计算难度。题目要求综合运用Arrhenius方程和J-M方程，推导出再结晶温度与多个参数（G0, N0, Qg, Qn）之间的函数关系。解题步骤涉及多个公式的联立和变换，需要深入理解材料科学中的再结晶机理和动力学过程。虽然不需要数值计算，但推导过程复杂，对知识点的掌握深度和逻辑推理能力要求较高，属于该题型中较难的题目。" + }, + { + "idx": 2225, + "question": "Determine whether the following statement is correct. (1) Appropriate recrystallization annealing can refine the grain size of metal castings.", + "answer": "Incorrect. Only for metals that have undergone cold deformation (with significant deformation) can the grain size be refined through appropriate recrystallization annealing.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案明确指出了陈述的错误并给出了解释 | 知识层次: 题目不仅需要理解再结晶退火的基本概念，还需要将其与金属冷变形条件关联起来进行综合分析，判断在何种情况下可以细化晶粒。这涉及到多步逻辑推理和概念关联，超出了单纯记忆的范畴。 | 难度: 在判断题中属于较高难度，需要理解金属冷变形和再结晶退火之间的关系，并能综合分析不同条件下（如铸造状态与冷变形状态）晶粒细化的可能性。题目不仅考察基础概念，还要求考生能够区分不同工艺条件下的材料行为，属于综合分析结果判断的范畴。" + }, + { + "idx": 2226, + "question": "Why do metallic materials exhibit better mechanical properties after hot working compared to the as-cast state?", + "answer": "During hot working, metallic materials undergo dynamic deformation, dynamic recovery, and recrystallization processes. The columnar crystal zones and coarse equiaxed crystal zones disappear and are replaced by finer equiaxed grains. Many dispersed shrinkage pores and microcracks in the original ingot vanish due to mechanical welding effects, and microsegregation is also reduced to some extent through compression and diffusion. Consequently, the material's density and mechanical properties (especially plasticity and toughness) are improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属材料在热加工后机械性能改善的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属材料在热加工后机械性能改善的机理，涉及动态变形、动态回复和再结晶等复杂过程，以及晶粒细化、微裂纹愈合和微偏析减少等多因素综合分析。需要深入理解材料科学原理，并进行推理和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对热加工过程中金属材料的动态变形、动态回复和再结晶等复杂机理进行深度解释，并需要综合论述这些过程如何改善材料的机械性能。虽然不涉及多因素交互作用的全面分析（等级5特征），但对机理的解释深度和知识整合能力要求较高，符合等级4的标准。" + }, + { + "idx": 2227, + "question": "Determine whether the following view is correct. (7) Recovery, recrystallization, and grain growth are all processes of nucleation and growth, and their driving force is the stored energy.", + "answer": "Incorrect. Only the recrystallization process is a nucleation and growth process, and its driving force is the stored energy.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断给定的观点是否正确，答案直接给出了对错判断并解释了原因，符合判断题的特征。 | 知识层次: 题目需要理解恢复、再结晶和晶粒长大这三个过程的本质及其驱动力，并能够区分它们之间的差异。这涉及到多个概念的关联和综合分析，而不仅仅是简单的记忆或直接应用。 | 难度: 在判断题中属于较高难度，需要综合分析三个不同过程（Recovery, recrystallization, grain growth）的机制和驱动力，并准确判断只有recrystallization符合题目描述。这要求对材料科学中相变和微观结构演变有较深入的理解，并能区分相似但不同的概念。" + }, + { + "idx": 2228, + "question": "Determine whether the following statement is correct. (3) Polygonization causes the scattered dislocations to gather together to form dislocation walls, and the superposition of dislocation stress fields increases the lattice distortion.", + "answer": "Incorrect. During the polygonization process, the vacancy concentration decreases and dislocations recombine, causing dislocations of opposite signs to cancel each other out, reducing dislocation density and thereby alleviating lattice distortion.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，并给出了明确的判断结果（Incorrect）和解释，符合判断题的特征。 | 知识层次: 题目涉及对多边形化过程中位错行为的理解，需要将位错重组、应力场叠加和晶格畸变等概念进行关联分析，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要综合分析多边形化过程中位错重组和应力场叠加的复杂关系，涉及多步概念关联和结果判断。" + }, + { + "idx": 2229, + "question": "Determine whether the following statement is correct. (4) For any metal that undergoes cold deformation followed by recrystallization annealing, the grain size can be refined.", + "answer": "Incorrect. If the metal is deformed at the critical deformation degree, the grain size will coarsen after recrystallization annealing.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了正确与否的判断并解释了原因，符合判断题的特征。 | 知识层次: 题目不仅需要理解冷变形和再结晶退火的基本概念，还需要分析临界变形程度对晶粒尺寸的影响，涉及多步概念关联和综合分析。 | 难度: 在判断题中属于较高难度，需要理解冷变形和再结晶退火的多步过程，并综合分析临界变形度对晶粒尺寸的影响。题目不仅要求判断陈述的对错，还需要掌握特定条件下的反常现象（临界变形度导致晶粒粗化），这超出了基础概念判断的范畴，属于综合分析结果判断的难度等级。" + }, + { + "idx": 2230, + "question": "The tungsten filament in a light bulb operates at very high temperatures, leading to significant grain growth. When large grains spanning the filament form, the filament becomes brittle under certain conditions and may fracture due to stresses caused by thermal expansion during heating and cooling. Find a method to extend the lifespan of the tungsten filament.", + "answer": "Dispersed, particulate second phases (such as $\\\\mathrm{ThO}_{2}$) can be introduced into the tungsten filament to restrict grain growth. If the volume fraction of $\\\\mathrm{ThO}_{2}$ is $\\\\varphi$ and the radius is $r$, the limiting grain size $R = \\\\frac{4r}{3\\\\varphi(1+\\\\cos\\\\alpha)}$ (where $\\\\alpha$ is the contact angle). By selecting appropriate values of $\\\\varphi$ and $r$ to minimize $R$, grain growth can be effectively halted. Since grain refinement significantly reduces the brittleness of the filament, it becomes less prone to fracture, thereby effectively extending its lifespan.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提出一个方法来延长钨丝寿命，答案通过文字解释和论述给出了具体的解决方案，包括引入第二相颗粒和相关的理论依据，没有涉及选择、判断或计算。 | 知识层次: 题目要求综合运用材料科学知识（如晶粒生长限制机制、第二相粒子作用原理）进行推理分析，并涉及定量公式的应用（晶粒尺寸限制公式）和参数优化设计（选择适当的φ和r值）。这需要深入理解晶粒生长与材料性能的关系，并能够解释机理性解决方案，属于较高层次的认知要求。 | 难度: 在简答题（需要文字解释和论述）的题型框架下，该题目属于复杂分析的知识层次，要求综合运用材料科学原理（如晶粒生长限制机制、第二相粒子作用）、进行定量公式推导（晶粒尺寸限制公式），并关联实际工程问题（灯丝脆性断裂的解决方案）。解题需分步骤逻辑推演：从问题现象（大晶粒导致脆性）→理论依据（Zener钉扎效应）→公式参数优化（φ和r的选择）→最终工程效果（寿命延长），体现了对复杂现象的全面分析能力，符合该题型下的最高难度标准。" + }, + { + "idx": 2231, + "question": "Determine whether the following view is correct. (5) The recrystallization temperature of a certain aluminum alloy is 320°C, indicating that this alloy can only undergo recovery below 320°C, while recrystallization must occur above 320°C.", + "answer": "Incorrect. Recrystallization is not a phase transformation. Therefore, it can occur over a wide temperature range.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断给定的观点是否正确，答案直接给出了对错判断并简要解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶温度及其相关基础概念的记忆和理解，属于材料科学中的基本概念范畴。 | 难度: 在判断题中属于中等难度，需要理解\"recrystallization\"的基本概念及其温度范围特性，但不需要进行复杂的概念比较或分析。题目考察的是对再结晶过程本质的理解，而非简单记忆定义。" + }, + { + "idx": 2232, + "question": "Determine whether the following statement is correct. (2) Dynamic recrystallization only occurs under hot deformation conditions, therefore, metals deformed at room temperature will not undergo dynamic recrystallization.", + "answer": "Incorrect. The recrystallization temperature of some metals is below room temperature, so deformation at room temperature is also considered hot deformation, and dynamic recrystallization can occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了判断结果（Incorrect）并解释了原因，符合判断题的特征。 | 知识层次: 题目不仅需要理解动态再结晶的基本概念，还需要结合金属的再结晶温度与室温的关系进行综合分析，判断在特定条件下动态再结晶是否会发生。这涉及到多个概念的关联和应用，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要理解动态再结晶的条件及其与温度的关系，并能综合分析不同金属的再结晶温度范围与室温变形的关联。题目涉及多步概念关联和综合分析，超出了基础判断题的简单正误判断。" + }, + { + "idx": 2233, + "question": "Determine whether the following statement is correct. (6) The melting point of 20# steel is lower than that of pure iron, so its recrystallization temperature is also lower than that of pure iron.", + "answer": "Incorrect. The presence of trace solute atoms (wC=0.002 in 20# steel) hinders the recrystallization of the metal, thereby increasing its recrystallization temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案明确指出该陈述是错误的，并提供了简要的解释。这符合判断题的特征。 | 知识层次: 题目不仅需要理解纯铁和20#钢的熔点差异，还需要分析微量溶质原子对再结晶温度的影响，涉及多个概念的关联和综合分析。 | 难度: 在判断题中属于较高难度，需要综合分析合金元素对金属性能的影响，理解溶质原子对再结晶温度的阻碍作用，并正确关联熔点和再结晶温度的关系。题目涉及多个概念的关联和综合分析，超出了简单正误判断的范畴。" + }, + { + "idx": 2234, + "question": "Determine whether the following view is correct. (8) The greater the deformation of the metal, the more likely the recrystallization mechanism of grain boundary bulging nucleation will occur.", + "answer": "Incorrect. When the cold deformation degree of the metal is small, uneven deformation is more likely to occur in adjacent grains, that is, the dislocation density differs, making the recrystallization mechanism of grain boundary bulging nucleation more likely to occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个陈述是否正确（Determine whether the following view is correct），并且答案明确给出了判断结果（Incorrect）以及解释。这符合判断题的特征，即判断陈述的对错并提供简要解释。 | 知识层次: 题目涉及金属变形与再结晶机制的关联分析，需要理解变形程度与晶界凸出形核机制之间的关系，并进行综合判断。这超出了基础概念的记忆，属于中等应用层次，需要一定的概念关联和综合分析能力。 | 难度: 在判断题中属于较高难度，需要综合分析金属变形程度与再结晶机制之间的关系，理解不均匀变形和位错密度差异对晶界凸起形核机制的影响，并进行多步逻辑推理才能得出正确结论。" + }, + { + "idx": 2235, + "question": "Determine whether the following view is correct. (9) Normal grain growth is the consumption of small grains by large grains, while abnormal growth is the consumption of large grains by small grains.", + "answer": "Incorrect. Normal grain growth is uniform growth driven by interface curvature, whereas abnormal growth is non-uniform growth where large grains consume small grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述是否正确，答案明确给出了对错判断并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对正常晶粒生长和异常晶粒生长这两个基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解正常晶粒生长和异常晶粒生长的定义及其区别，而不仅仅是记忆基本概念。虽然题目涉及的是基础概念，但需要对两种生长机制有清晰的理解才能正确判断陈述的对错。" + }, + { + "idx": 2236, + "question": "Determine whether the following statement is correct. (10) The second-phase particles in an alloy generally can hinder recrystallization but promote grain growth.", + "answer": "Incorrect. The second-phase particles in an alloy generally can hinder recrystallization and also impede grain growth.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的正确性，答案直接给出了对错判断并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对合金中第二相粒子对再结晶和晶粒生长影响的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对合金中第二相粒子作用的理解，需要掌握第二相粒子对再结晶和晶粒长大的影响这一基础概念。虽然涉及两个相关过程（再结晶和晶粒长大），但都属于材料科学基础知识的记忆和理解范畴，不需要复杂的分析或推理。相比单纯的定义判断（等级1）稍难，但远未达到需要处理复杂概念陈述的等级3难度。" + }, + { + "idx": 2237, + "question": "Determine whether the following statement is correct. (13) Recrystallization is a nucleation-growth process, so it is also a phase transformation process.", + "answer": "Incorrect. Although recrystallization is a nucleation-growth process, the crystal lattice type does not change, so it is not a phase transformation process.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案明确指出了陈述的错误并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶和相变这两个基本概念的理解和区分，属于基础概念的记忆和辨析 | 难度: 在判断题中属于中等难度，需要理解\"再结晶\"和\"相变\"两个概念的定义及其区别。虽然题目涉及的是基础概念，但需要考生准确区分\"晶格类型改变\"这一关键特征，属于概念理解层面的对错判断，而非简单的正误记忆。" + }, + { + "idx": 2238, + "question": "Determine whether the following statement is correct. (11) Recrystallization texture is the deformation texture retained during the recrystallization process.", + "answer": "Incorrect. Recrystallization texture is the texture formed during the recrystallization (primary, secondary) process of cold-deformed metals. It is formed on the basis of deformation texture, with two scenarios: one is retaining the original deformation texture, and the other is the disappearance of the original deformation texture, replaced by a new recrystallization texture.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的正确性（Determine whether the following statement is correct），答案明确给出了判断结果（Incorrect）并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶织构这一基础概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对\"再结晶织构\"这一专业概念的理解，需要区分其与\"变形织构\"的本质差异。虽然不涉及复杂推理，但要求准确掌握材料科学中这两个易混淆概念的定义关系，比单纯记忆性判断（等级1）要求更高的概念辨析能力。" + }, + { + "idx": 2239, + "question": "In Fe-Si steel (with $\\\\mathrm{{\\\\tau}}\\\\mathrm{{{w}}}_{\\\\mathrm{{Si}}}$ being 0.03), the measured diameter of $\\\\mathrm{MnS}$ particles is $0.4\\\\mu\\\\mathrm{m}$, and the number of particles per $1~\\\\mathrm{m}\\\\mathrm{m}^{2}$ is $2\\\\times10^{5}$. Calculate the effect of $\\\\mathrm{MnS}$ on the austenite grain growth during normal heat treatment of this steel (i.e., calculate the austenite grain size).", + "answer": "Let the number of $\\\\mathrm{MnS}$ particles per unit volume be $N_{\\\\mathrm{V}}(1/\\\\mathrm{m}\\\\mathrm{m}^{3})$. Given the number of MnS particles per unit area $N_{\\\\mathrm{A}}=$ $2\\\\times10^{5}~1/\\\\mathrm{m}\\\\mathrm{m}^{2}$ and the particle diameter $d=0.4~\\\\mu\\\\mathrm{m}$. According to the principles of quantitative metallography, $$ N_{\\\\mathrm{A}}=d N_{\\\\mathrm{v}} $$ The volume fraction of MnS is $$ \\\\varphi={\\\\frac{1}{6}}\\\\pi d^{3}N_{\\\\mathrm{v}}={\\\\frac{1}{6}}\\\\pi d^{2}N_{\\\\mathrm{A}}= $$ $$ \\\\frac{1}{6}\\\\pi\\\\times(0.4\\\\times10^{-3})^{2}\\\\times2\\\\times10^{5}=0.0167 $$ Therefore, during the heating of this steel, due to the effect of $\\\\mathrm{MnS}$ particles, the limiting size for austenite grain growth is $$ \\\\overline{{\\\\cal D}}_{\\\\mathrm{lim}}=\\\\frac{4r}{3\\\\varphi}=\\\\frac{4\\\\times0.2}{3\\\\times0.016~7}=16~\\\\mu\\\\mathrm{m} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及多个计算步骤和公式推导，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括从单位面积粒子数推导单位体积粒子数，计算体积分数，并应用公式计算奥氏体晶粒生长的极限尺寸。这涉及到定量金相学原理和晶粒生长限制机制的综合应用，需要概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解定量金相学原理，进行多步公式推导和数值计算，涉及粒子数量、体积分数和晶粒生长限制尺寸的综合分析。虽然计算步骤较多，但每个步骤相对明确，没有涉及复杂多变量或高阶数学运算。" + }, + { + "idx": 2240, + "question": "If σ_α/β=200×10^-3 J/m^2, what is the total interfacial energy per cubic meter of the alloy? What is the total interfacial energy per mole of the alloy (V_m=10^-5 m^3/mol)?", + "answer": "The total interfacial energy per cubic meter of the alloy is 1.2×10^8×200×10^-3=240×10^5 J/m^3. The interfacial energy per mole of the alloy is γ=1.2×10^8×200×10^-3×10^-5=240 J/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以求得合金的单位体积界面能和单位摩尔界面能。答案也展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的界面能数值代入公式进行计算，并完成单位转换。虽然涉及两步计算（每立方米和每摩尔），但每一步都是直接套用公式，不需要复杂的分析或综合。 | 难度: 在计算题中属于简单公式应用计算难度。题目虽然涉及单位换算和两个问题的计算，但本质上都是直接套用给定的公式和数值进行计算，没有复杂的推导或多步骤组合。属于基本公式应用范畴，符合等级2\"简单公式应用计算\"的标准。" + }, + { + "idx": 2241, + "question": "If the interfacial energy is the same as (3), how much driving force for phase transformation remains in the alloy?", + "answer": "420.8-240=180.8 J/mol. That is, after overcoming the interfacial energy during the phase transformation, there remains a driving force of 180.8 J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（420.8-240=180.8 J/mol）并应用公式来求解相变驱动力，答案以具体数值形式呈现，符合计算题的特征。 | 知识层次: 题目涉及基本的数值计算和公式应用，仅需简单的减法运算和单位转换，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需单一公式直接计算（简单减法运算），无需复杂公式组合或多步骤推导，完全符合等级1\"单一公式直接计算\"的定义特征。题目明确给出所有已知数值，解题过程仅需执行420.8-240的基础算术操作，属于该题型下最基础的计算类型。" + }, + { + "idx": 2242, + "question": "Determine whether the following view is correct. (12) When the deformation is large and relatively uniform, the grains after recrystallization tend to undergo normal growth, otherwise, abnormal growth is more likely to occur.", + "answer": "Incorrect. Normal grain growth is the process of uniform grain growth that occurs during continued heating or holding after recrystallization is completed; whereas abnormal grain growth is the process of non-uniform grain growth that occurs under certain conditions (i.e., stable grains after recrystallization, the presence of a few grains favorable for growth, and high-temperature heating) following normal grain growth.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断给定的观点是否正确，答案明确指出了该观点是错误的，并解释了原因。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对再结晶后晶粒生长行为的理解，需要将变形条件与晶粒生长模式关联起来，并区分正常生长和异常生长的条件。这涉及多个概念的综合应用和一定程度的分析判断。 | 难度: 在判断题中属于较高难度，需要综合分析再结晶后的晶粒生长过程，区分正常生长和异常生长的条件，并理解题目中描述的变形条件对生长模式的影响。这涉及多步概念关联和条件判断，超出了基础正误判断的范畴。" + }, + { + "idx": 2243, + "question": "The carbon in iron, c0=wC=0.0001, E=-0.5 eV, calculate the critical temperature for solute segregation.", + "answer": "c=c0exp(-E/kT), when complete solute segregation occurs, c=wx=1, T=T∥s, 1=c0exp(-E/kT), then T∥⊥=-E/kln(1/c0). Substituting c0=wC=0.0001, E=-0.5 eV=-1.602×10^-19×0.5 J, T∥∥=(1.602×10^-19×0.5)/(1.381×10^-23×ln(1/0.0001))=629 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的数值代入和公式推导，最终得出一个具体的温度值。 | 知识层次: 题目涉及多步计算和公式应用，需要理解溶质偏析的临界温度计算原理，并正确代入数值进行计算。虽然计算过程较为直接，但需要理解公式的物理意义和单位转换，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用公式进行多步计算，并理解概念关联。题目涉及能量单位转换、对数运算和临界温度的综合计算，步骤较为复杂，但未达到多变量计算的复杂程度。" + }, + { + "idx": 2244, + "question": "In the regular melt α, the total driving force ΔG for the precipitation of β can be approximately expressed as ΔG=RT[x_o ln(x_o/x_e)+(1-x_o)ln((1-x_o)/(1-x_e))]-2Ω(x_o-x_e)^2. Given T=600K, x_o=0.1, x_e=0.02, Ω=0, use this expression to estimate the total driving force for α→α′+β.", + "answer": "Given T=600K, x_o=0.1, x_e=0.02, R=8.31 J/(mol·K). ΔG=RT[x_o ln(x_o/x_e)+(1-x_o)ln((1-x_o)/(1-x_e))]=8.31×600×[0.1 ln(0.1/0.02)+(1-0.1)ln((1-0.1)/(1-0.02))]=420.8 J/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式和参数进行数值计算，最终得出一个具体的数值结果（ΔG=420.8 J/mol），符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需将给定数值代入公式进行计算即可。 | 难度: 在计算题中属于最低难度，只需要直接套用给定的单一公式进行数值计算，无需额外的公式组合或复杂推导。题目已经提供了所有必要的参数和明确的公式，计算过程仅涉及基本对数运算和乘法。" + }, + { + "idx": 2245, + "question": "Using classical nucleation theory, calculate the shape factor η of a new phase when a cubic nucleus is formed by $n$ atoms during a solid-state phase transformation.", + "answer": "According to classical nucleation theory, during a solid-state phase transformation, the change in the system's free energy is given by $$ \\\\Delta G=n\\\\Delta G_{V}+S\\\\gamma+n E_{s}$$ where $\\\\Delta G_{V}$ is the free energy difference per atom between the old and new phases; S is the surface area of the nucleus; $\\\\gamma$ is the average surface energy; $E_{s}$ is the strain energy per atom in the nucleus; $n$ is the number of atoms in the nucleus. Assuming the density of the new phase is $\\\\rho$ and the relative atomic mass is $M,$ the volume occupied per gram-atom of the new phase material is $M/\\\\rho;$ the volume occupied per atom of the new phase is $M/(\\\\rho N_{0});$ the volume of a nucleus with $n$ atoms is $n M/(\\\\rho N_{0})$. If a cubic nucleus is formed, its edge length is $(n M/(\\\\rho N_{\\\\circ}))^{1/3}$, and the surface area of the nucleus is $6(n M/(\\\\rho N_{\\\\circ}))^{2/3}$. Thus, the shape factor $$\\\\eta=(M/(\\\\rho N_{\\\\circ}))^{2/3}$$ and the free energy change is $$ \\\\Delta G=n\\\\Delta G_{V}+6(M/(\\\\rho N_{\\\\L_{0}}))^{2/3}n^{2/3}\\\\gamma+n E_{s}$$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用经典成核理论计算立方核的形状因子η，涉及数值计算和公式应用，答案中给出了具体的计算步骤和公式推导。 | 知识层次: 题目涉及多步计算和概念关联，需要理解经典成核理论中的自由能变化公式，并应用密度、相对原子质量等参数进行推导和计算。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点进行中等难度的计算和公式应用。 | 难度: 在计算题中属于综合性计算问题，需要应用经典成核理论进行多步推导和计算。题目涉及自由能变化、表面能、应变能等多个概念的关联，并要求计算立方核的形状因子。虽然计算步骤明确，但需要综合运用多个公式和概念，属于中等偏上的难度。" + }, + { + "idx": 2246, + "question": "If an alloy has β-phase precipitates with a spacing of 50 nm after heat treatment, calculate the total area of α/β interfaces per cubic meter (assuming the precipitates are cubes).", + "answer": "The number of β precipitates is n_β=1/(50×10^-9)^3=8×10^21. The surface area of each β is S_β=6×(50×10^-9)^2=1.5×10^-14 m^2. The total interface area in 1 m^3 is S_A=8×10^21×1.5×10^-14=1.2×10^8 m^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算β相沉淀物的数量和表面积）并应用公式（计算总界面面积），答案呈现为具体的计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算沉淀物的数量和表面积，然后将这些结果综合起来计算总的界面面积。这涉及到对材料科学中相变和界面概念的理解，以及数学计算能力。虽然不需要复杂的推理或机理解释，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解相界面概念、进行多步计算（包括体积和表面积计算），并正确应用单位换算。虽然计算步骤明确，但涉及纳米尺度的单位转换和三维空间关系的理解，对概念关联和计算准确性要求较高。" + }, + { + "idx": 2247, + "question": "During solid-state phase transformation, assuming the new phase nucleus is spherical and the volume free energy change per atom ΔGv=200ΔT/Tc (J/cm³), the critical transformation temperature Tc=1000K, the strain energy Es=4 J/cm³, the coherent interface energy γ_coherent=40×10⁻⁷ J/cm², and the incoherent interface energy γ_incoherent=400×10⁻⁷ J/cm², calculate ΔT when ΔG_coherent* = ΔG_incoherent*.", + "answer": "Let ΔG_coherent* = ΔG_incoherent*, then (40×10⁻⁷)³ / (200×ΔT/1000 - 4)² = (400×10⁻⁷)³ / (200×ΔT/1000)². Solving gives ΔT ≈ 21K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及多个参数的代入和方程的求解，最终得出一个具体的数值结果（ΔT ≈ 21K）。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用体积自由能变化、应变能和界面能等概念，并通过公式推导和数值计算求解临界温度差ΔT。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和计算技巧。 | 难度: 在计算题中属于综合性计算问题，需要理解多个概念（如体积自由能变化、应变能、界面能等）并进行多步计算和综合分析。题目要求平衡两种不同界面能条件下的临界转变温度差ΔT，涉及公式推导和数值求解，但解题步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 2248, + "question": "For zinc in copper, c0=wZn=0.0001, E=-0.12 eV, calculate the critical temperature for solute segregation.", + "answer": "c=c0exp(-E/kT). When complete solute segregation occurs, c=wx=1, T=T∥s, 1=c0exp(-E/kT), then T∥⊥=-E/kln(1/c0). Substituting c0=wZn=0.0001, E=-0.12 eV=-1.602×10^-19×0.12 J, T∥∥=(1.602×10^-19×0.12)/(1.381×10^-23×ln(1/0.0001))=151 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界温度，答案中包含了具体的计算步骤和数值代入，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式变换、数值代入和单位转换，涉及对溶质偏聚临界温度的理解和计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解溶质偏析的概念，应用公式进行多步计算，包括单位转换和自然对数的处理。虽然计算步骤明确，但涉及多个物理量的综合运用和单位转换，属于中等偏上的难度。" + }, + { + "idx": 2249, + "question": "Analyze the main reasons for dislocations promoting nucleation, focusing on the case where the new phase nucleates on the dislocation line", + "answer": "When the new phase nucleates on the dislocation line, the dislocation disappears at the nucleation site, and the released elastic strain energy reduces the nucleation work, thereby promoting nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错促进形核的主要原因，并针对新相在位错线上形核的情况进行论述。答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错促进形核的主要原因，并聚焦于新相在位错线上形核的情况。这需要理解位错的弹性应变能与形核功之间的关系，涉及位错消失和能量释放的机理解释。这种分析需要综合运用位错理论、形核理论和能量学原理，属于较高层次的推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对位错促进形核的机理进行深度解释，涉及弹性应变能释放与形核功降低的因果关系分析。虽然不需要全面分析复杂现象（如多因素交互作用），但需要准确理解位错消失与能量变化的物理机制，属于机理深度解释层面的难度。" + }, + { + "idx": 2251, + "question": "During the solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the time required to achieve a $50\\\\%$ transformation.", + "answer": "$$ \\\\varphi=1-\\\\exp\\\\Bigl(-\\\\textstyle{\\\\frac{\\\\pi}{3}}\\\\dot{N}G^{3}t^{4}\\\\Bigr)$$ $$ 50\\\\%=1-\\\\exp\\\\Bigl(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\Bigr)$$ $$ 0.6931={\\\\frac{\\\\pi}{3}}\\\\times1000\\\\times(3\\\\times10^{-5})^{3}t^{4}$$ $$ t^{4}=2.45\\\\times10^{10}$$ $$ t=395\\\\mathrm{~s~}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出时间值。答案展示了详细的数值计算步骤和公式应用过程，符合计算题的特征。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，涉及对数运算和指数函数的处理，同时需要理解相变动力学中的成核率和生长速率概念。虽然计算过程较为直接，但需要一定的综合分析能力和对公式的理解。 | 难度: 在计算题中属于综合性计算问题，需要应用Johnson-Mehl方程进行多步计算，包括对数变换、数值代入和求解四次方根。虽然计算步骤较多，但每一步都是直接的数学操作，没有涉及复杂的概念关联或高级数学技巧。因此，在计算题题型内属于中等难度。" + }, + { + "idx": 2252, + "question": "Analyze the resistance to solid-state phase transformation.", + "answer": "The resistance to nucleation during solid-state phase transformation arises from the interfacial energy $E_{\\\\gamma}$ introduced by the formation of an interface between the new-phase nucleus and the matrix, as well as the volumetric strain energy (i.e., elastic energy) $E_{\\\\mathrm{e}}$. The interfacial energy $E_{\\\\gamma}$ consists of two parts: one is the chemical energy caused by changes in the strength and quantity of like and unlike bonds when forming the new-phase interface in the parent phase, referred to as the chemical term of the interfacial energy; the other is the interfacial strain energy caused by the mismatch of interfacial atoms and the resulting strain in atomic spacing, referred to as the geometric term of the interfacial energy. The strain energy $E_{\\\\mathrm{e}}$ arises because the formation of the new phase in the parent phase, due to their differing specific volumes, induces volumetric strain. This volumetric strain is typically accommodated by elastic strain between the new phase and the parent phase, resulting in volumetric strain energy. Overall, as the size of the new-phase nucleus increases and the new phase grows, $(E_{\\\\gamma}+E_{e})$ will increase. Of course, $E_{\\\\gamma}$ and $E_{\\\\mathrm{e}}$ can also adjust to each other through factors such as the precipitation location, particle shape, and interface state of the new phase to minimize $(E_{\\\\gamma}+E_{e})$. When the parent phase is liquid, there is no issue of volumetric strain energy, and the interfacial energy of a solid phase is much higher than that of a liquid-solid interface. In comparison, the resistance to solid-state phase transformation is greater.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对固态相变阻力进行分析和解释，答案提供了详细的文字论述，解释了界面能和应变能的来源及其影响，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析固态相变过程中的阻力来源，涉及界面能和应变能的概念及其相互作用，需要综合运用多个知识点进行推理和解释。答案中详细讨论了界面能的化学和几何部分、应变能的来源，以及它们如何相互调整以最小化总能量，体现了对复杂机理的深入理解和分析能力。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。题目要求对固态相变过程中的阻力进行全面分析，涉及多个复杂概念（界面能、应变能）的详细解释和相互作用机制。需要考生综合运用材料科学原理，分析不同能量项的来源、组成及其相互调整机制，还要对比液态相变的情况。这种深度机理解释和复杂现象综合分析的要求，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 2253, + "question": "Analyze the driving force for particle coarsening when spherical second-phase particles precipitate from the solid solution.", + "answer": "Assume spherical β particles with radius r precipitate in the α parent phase, with volume V and β/α interfacial area S. The free energy can be expressed as $$ where G_V and E_s are the chemical free energy and elastic strain energy per unit volume of the new phase, respectively, and γ is the specific interfacial energy. The chemical potential of a certain component, such as the solute component, can be expressed as G = V(G_V + E_s) + Sγ $$ where Ω is the molar volume, i.e., the volume of the new phase corresponding to one mole of solute atoms. From the above two equations, we obtain $$ μ = Ω(G_V + E_s) + Ω(∂S/∂V)γ $$ where ∂S/∂V is the increase in surface area per unit volume increase. For spherical particles, we have Thus, $$ ∂S/∂V = d(4πr²)/d(4/3πr³) = 2/r $$ $$ μ = Ω(G_V + E_s) + 2Ωγ/r $$ Clearly, the chemical potential of solute atoms in spherical particles depends on the particle radius r. The smaller r is, the higher μ becomes, making such particles less stable. Assume two spherical β particles with radii r₁ and r₂ (r₁ > r₂) precipitate in the parent phase and are adjacent to each other. The difference in their chemical potentials is $$ Δμ = μ₂ - μ₁ = 2Ωγ(1/r₂ - 1/r₁) $$ This is the driving force for solute atoms to diffuse from smaller particles to larger ones, leading to particle coarsening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析球形第二相粒子从固溶体中析出时的粗化驱动力，答案通过文字解释和公式推导进行了详细论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析第二相粒子粗化的驱动力，涉及化学自由能、弹性应变能和界面能等概念的关联，需要推导化学势与粒子半径的关系，并解释扩散机制。这需要综合运用多个知识点进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用热力学、材料科学和数学推导知识，全面分析粒子粗化的驱动机理。具体表现为：" + }, + { + "idx": 2254, + "question": "Analyze the main reasons why dislocations promote nucleation, focusing on the scenario where dislocations do not disappear and adhere to the new phase interface", + "answer": "The dislocations do not disappear and instead adhere to the new phase interface, becoming part of the dislocations in the semi-coherent interface, compensating for the mismatch. This reduces the energy, thereby decreasing the energy required for nucleus formation and promoting nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错促进形核的主要原因，并针对特定情景进行论述。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错促进形核的主要原因，并特别关注位错不消失且附着在新相界面的情况。这需要深入理解位错与新相界面的相互作用机制，以及能量降低对形核过程的促进作用。涉及多个概念的关联和综合分析，思维过程较为深入，属于复杂分析层次。 | 难度: 在简答题的复杂分析题型中，该题目要求对位错促进形核的机理进行深度解释，涉及位错在相界面的行为、能量补偿机制等专业概念的综合运用。虽然不需要全面分析所有可能的复杂现象（如多因素耦合作用），但需要对核心机理进行清晰阐述，符合等级4\"机理深度解释\"的要求。相比等级5的\"全面分析\"，该题更聚焦于位错-界面相互作用的单一机制解析。" + }, + { + "idx": 2255, + "question": "Analyze the main reasons for dislocations promoting nucleation in the case where the composition of the new phase differs from that of the parent phase", + "answer": "When the composition of the new phase differs from that of the parent phase, the segregation of solute atoms along dislocation lines (forming Cottrell atmospheres) facilitates the precipitation of the new phase and also promotes nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析新相与母相成分不同时位错促进形核的主要原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错促进新相形核的主要原因，涉及溶质原子在位错线上的偏聚（Cottrell气团）及其对新相析出的影响，需要综合运用位错理论、相变原理和扩散知识进行机理层面的解释和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用材料科学中的相变理论、位错理论和溶质原子偏析等知识，深入解释位错促进新相形核的机理。需要考生不仅理解Cottrell气团的概念，还要能够分析溶质原子偏析如何降低形核能垒，并阐述成分差异对新相形核的影响机制。这种需要多知识点整合和机理深度解释的题目，在该题型框架内属于最高难度等级。" + }, + { + "idx": 2256, + "question": "During the solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ of the new phase are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the maximum transformation rate during the phase transformation.", + "answer": "$$ \\\\frac{\\\\mathrm{d}\\\\varphi}{\\\\mathrm{d}t}=\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ Substitute $t_{\\\\mathrm{max}}=403$ into the above equation to calculate the maximum transformation rate.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体步骤包括对给定的Johnson-Mehl方程进行微分，并代入具体数值计算最大转变速率。答案也展示了具体的计算过程和结果。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，包括求导和极值分析，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用给定的Johnson-Mehl方程进行多步计算，包括求导和数值代入。虽然涉及的概念和公式较为明确，但解题步骤较为复杂，需要综合分析能力和对相变动力学的理解。" + }, + { + "idx": 2257, + "question": "What is the main difference between precipitation decomposition and spinodal decomposition in the formation of precipitated phases?", + "answer": "The main difference between the two in the formation of precipitated phases lies in the nucleation driving force and the compositional change of the new phase. During precipitation transformation, the formation of the new phase requires significant concentration fluctuations, and the composition of the new phase changes abruptly compared to the parent phase, resulting in interfacial energy. This necessitates a larger nucleation driving force to overcome the interfacial energy, meaning a greater degree of undercooling is required. In contrast, spinodal decomposition does not involve a nucleation process or abrupt compositional changes; any small concentration fluctuation can lead to the formation and growth of the new phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种分解过程的主要区别，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求解释两种分解机制在析出相形成过程中的主要区别，涉及对成核驱动力和成分变化的深入理解，需要综合分析两种机制的物理本质和差异，属于机理层面的解释和推理分析。 | 难度: 在简答题的复杂分析层次中，该题目要求对两种分解机制进行全面的对比分析，涉及成核驱动力、成分变化、界面能等多个专业概念的深度解释和机理阐述。解题需要综合运用材料科学相变理论，进行多维度推理分析，属于该题型框架下最高难度的复杂现象全面分析类型。" + }, + { + "idx": 2258, + "question": "The following equation represents the change in the system's free energy caused by the formation of a crystal embryo containing $n$ atoms. $$ \\\\Delta G=-\\\\:b n\\\\left(\\\\Delta G_{V}-E_{\\\\mathrm{s}}\\\\right)+a n^{2/3}\\\\gamma_{\\\\upalpha/\\\\upbeta} $$ where $\\\\Delta G_{V}$ is the free energy change per unit volume of the crystal embryo; $\\\\gamma_{\\\\mathfrak{a}/\\\\mathfrak{g}}$ is the interfacial energy; $E_{\\\\mathrm{s}}$ is the strain energy; $a, b$ are coefficients whose values are determined by the shape of the crystal embryo. \\n\\nFind the values of $a$ and $b$ when the crystal embryo is spherical. If $\\\\Delta G_{V}, \\\\gamma_{\\\\scriptscriptstyle\\\\alpha/\\\\beta}, E_{s}$ are all constants, derive the nucleation energy $\\\\Delta G^{*}$ for a spherical nucleus.", + "answer": "If precipitation occurs simultaneously throughout the parent phase, and the composition of the parent phase changes continuously with the formation of the new phase, but the grain morphology and orientation remain unchanged, it is called continuous precipitation. \\n\\nIn contrast to continuous precipitation, when precipitation occurs, the solid solution within a certain surrounding range immediately changes from a supersaturated state to a saturated state, forming a distinct interface with the original composition of the parent phase. After nucleation at grain boundaries, it grows into the grain interior in an alternating lamellar distribution. Not only does the composition change abruptly at the interface, but the orientation also changes. This is discontinuous precipitation. The main difference lies in the length of the diffusion path. In the former, the diffusion field extends over a considerable distance, while in the latter, the diffusion distance is on the order of the lamellar spacing (generally less than $1~\\\\mu\\\\mathrm{m}$). \\n\\nDiscontinuous precipitation has the following characteristics: \\n\\n(1) At the interface between the precipitate and the matrix, the composition is discontinuous; the interfaces between the precipitate and the matrix are all high-angle incoherent interfaces, indicating that the crystal orientation is also discontinuous. (2) Cellular precipitates usually nucleate at the grain boundaries of the matrix $({\\\\alpha^{\\\\prime}})$ and always grow into one of the adjacent grains of the $\\\\alpha^{'}$ phase. (3) During the growth of cellular precipitates, the redistribution of solute atoms is achieved through interfacial diffusion between the precipitate and the parent phase, with the diffusion distance typically less than $1~\\\\mu\\\\mathrm{m}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式推导和数值计算来求解特定条件下的系数（a和b）以及成核能（ΔG*），属于典型的计算题。答案部分虽然包含了一些解释性内容，但核心要求是通过数学推导和计算得出具体结果。 | 知识层次: 题目要求推导球形晶核的成核能，涉及多步计算和公式应用，需要理解自由能变化方程中各参数的含义及其相互关系，并进行适当的数学推导。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体核形成的自由能变化公式，并推导球形晶核的成核能。题目涉及多个变量和系数的计算，需要综合运用材料科学和热力学知识，进行多步推导和计算。虽然公式明确，但需要理解各参数的物理意义并进行适当的数学处理，属于中等偏上的难度。" + }, + { + "idx": 2259, + "question": "In the process of solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the time at which the phase transformation rate is the fastest.", + "answer": "$$ \\\\varphi=1-\\\\exp\\\\Bigl(-\\\\textstyle{\\\\frac{\\\\pi}{3}}\\\\dot{N}G^{3}t^{4}\\\\Bigr)$$ $$ \\\\frac{\\\\mathrm{d}\\\\varphi}{\\\\mathrm{d}t}=\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ $$ \\\\frac{\\\\mathrm{d}^{2}\\\\varphi}{\\\\mathrm{d}t^{2}}=-\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)^{2}\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)+\\\\left(\\\\frac{12}{3}\\\\pi\\\\dot{N}G^{3}t^{2}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ ${\\\\frac{\\\\mathrm{d}^{2}\\\\varphi}{\\\\mathrm{d}t^{2}}}=0$ , i.e.,$$ -\\\\left({\\\\frac{4}{3}}\\\\pi{\\\\dot{N}}G^{3}t^{3}\\\\right)^{2}+\\\\left({\\\\frac{12}{3}}\\\\pi{\\\\dot{N}}G^{3}t^{2}\\\\right)=0$$ $$ t_{\\\\mathrm{max}}=\\\\left(\\\\frac{9}{4\\\\pi\\\\dot{N}G^{3}}\\\\right)^{1/4}=\\\\left[\\\\frac{9}{4\\\\times3.14\\\\times1000\\\\times(3\\\\times10^{-5})^{3}}\\\\right]^{\\\\frac{1}{4}}=403$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出具体的时间数值。解答过程涉及导数和方程求解，属于典型的计算题特征。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，包括求导和求解方程，涉及对相变动力学的基本理解和公式的综合应用，但不需要复杂的推理或创新性思维。 | 难度: 在计算题中属于综合性计算问题，需要应用Johnson-Mehl方程进行多步推导和计算，包括求导、解方程和数值计算。虽然涉及的概念和步骤较多，但整体思路清晰，属于中等难度的计算题。" + }, + { + "idx": 2260, + "question": "What is the difference between continuous and discontinuous precipitation?", + "answer": "If precipitation occurs simultaneously throughout the parent phase, and the composition of the parent phase changes continuously with the formation of the new phase, but the grain morphology and orientation remain unchanged, it is called continuous precipitation. In contrast to continuous precipitation, when precipitation occurs, the solid solution within a certain range around it immediately changes from a supersaturated state to a saturated state, forming a distinct interface with the original composition of the parent phase. After nucleation at grain boundaries, it grows into the grain interior with an alternating lamellar distribution. Not only does the composition change abruptly at the interface, but the orientation also changes, which is called discontinuous precipitation. The main difference lies in the length of the diffusion path. In the former, the diffusion field extends over a considerable distance, while in the latter, the diffusion distance is only on the order of the lamellar spacing (generally less than 1 μm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释连续和不连续析出的区别，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对连续和非连续沉淀的基本定义和区别的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于复杂概念体系阐述难度。题目不仅要求区分连续和非连续析出的定义，还需要详细解释两者的形成机制、微观结构变化以及扩散路径差异。这涉及多个相关联的概念整合和对比分析，超出了简单定义或单一概念描述的范畴，属于该题型内较高难度的知识综合运用题。" + }, + { + "idx": 2261, + "question": "Describe the precipitation sequence of Al-Cu alloy", + "answer": "The precipitation sequence of Al-Cu alloy is: GP zones → θ′′ metastable phase → θ′ metastable phase → θ phase (equilibrium phase)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述Al-Cu合金的析出序列，需要文字解释和论述，答案以文字形式给出，没有选项、判断或计算要求。 | 知识层次: 题目考查Al-Cu合金沉淀序列的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要记忆多个相变阶段（GP zones → θ′′ → θ′ → θ），但不需要深入分析相变机制或影响因素，属于基础概念记忆性知识的直接应用。相比等级1的简单定义题更复杂，但比等级3的复杂概念体系阐述题更基础。" + }, + { + "idx": 2262, + "question": "What are the main characteristics of discontinuous precipitation?", + "answer": "Discontinuous precipitation has the following characteristics: (1) At the interface between the precipitate and the matrix, the composition is discontinuous; the interfaces between the precipitate and the matrix are all high-angle non-coherent interfaces, indicating that the crystal orientation is also discontinuous. (2) Cellular precipitates usually nucleate at the grain boundaries of the matrix (α') and always grow into one of the adjacent grains of the α' phase. (3) When cellular precipitates grow, the partitioning of solute atoms is achieved through their interfacial diffusion between the precipitate phase and the parent phase, with the diffusion distance typically less than 1 μm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释不连续沉淀的主要特征，答案以文字论述形式给出，没有选项选择、对错判断或数值计算的要求。 | 知识层次: 题目主要考查对不连续析出（discontinuous precipitation）基本特征的记忆和理解，包括界面特性、形核位置和生长机制等基础概念，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于复杂概念体系阐述难度等级。该题目不仅要求考生记忆不连续析出的基本特征，还需要理解并阐述多个相互关联的复杂概念，包括界面成分不连续性、高角度非共格界面、晶界成核机制以及溶质原子分配方式等。回答时需要组织多个知识点并建立逻辑关联，这超出了简单定义或单一概念解释的范畴，符合等级3对复杂概念体系阐述的要求。" + }, + { + "idx": 2263, + "question": "What is the essence of aging?", + "answer": "The essence of aging is the process of separating a new phase from a supersaturated solid solution, usually caused by temperature changes. The microstructure after aging consists of a matrix and precipitates. The matrix has the same crystal structure as the parent phase but differs in composition and lattice constants, while the precipitates can have different crystal structures and compositions from the parent phase. Due to variations in the properties, size, shape, and distribution of the precipitates in the microstructure, the performance of the alloy can change significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"aging\"的本质进行文字解释和论述，答案提供了详细的定义和微观结构变化的描述，符合简答题的特征。 | 知识层次: 题目不仅要求解释时效的本质，还需要详细描述时效过程中微观结构的变化及其对合金性能的影响。这涉及到对时效机理的深入理解、微观组织与性能关系的综合分析，以及晶体结构和成分变化的推理分析，属于较高层次的认知能力要求。 | 难度: 在简答题题型中，该题目要求对时效处理的本质进行全面的分析，包括微观结构的组成、晶体结构的变化以及性能的影响等多个方面。这需要考生具备深厚的材料科学知识，能够综合运用多个概念进行推理分析，并对复杂现象进行全面的解释。因此，该题目在简答题题型中属于最高难度等级。" + }, + { + "idx": 2264, + "question": "For a φ5mm carbon steel sample with a carbon mass fraction of w_c=0.003, after heating and quenching at 860°C, the sample is tempered. How will the microstructure change during the tempering process?", + "answer": "For carbon steel with w_c=0.003, when tempered below 200°C, the changes in microstructure morphology are minor, and the hardness change is also small. However, the tendency for carbon atoms to segregate near dislocation lines increases. When the tempering temperature exceeds 250°C, cementite precipitates between laths or along dislocation lines, leading to a decrease in strength and plasticity. When the tempering temperature reaches 300~400°C, lamellar or rod-shaped cementite precipitates, causing a significant reduction in hardness and strength, while plasticity begins to increase. During tempering at 400~700°C, the carbides undergo aggregation, growth, and spheroidization, and the α phase undergoes recovery and recrystallization. At this stage, hardness and strength gradually decrease, while plasticity gradually increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述碳钢在回火过程中微观结构的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对碳钢在回火过程中的微观结构变化进行详细解释，涉及多个温度阶段和相应的微观结构演变机制。这需要综合运用材料科学中的相变理论、碳原子扩散行为、位错理论等知识，并进行推理分析。思维过程需要深入理解不同温度下微观结构变化的机理，属于复杂分析和机理解释的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求对碳钢回火过程中的微观结构变化进行全面分析，涉及多个温度阶段的详细机理解释和现象描述。需要综合运用材料科学知识，包括相变理论、位错理论、碳化物析出与聚集机制等，并进行多步骤推理分析。这种深度和广度的知识整合要求，以及复杂现象的全面解释能力，符合该题型下的最高难度等级标准。" + }, + { + "idx": 2265, + "question": "If a new phase in a solid-state phase transformation precipitates from the parent phase as spherical particles, and the change in free energy per unit volume is $10^{8}\\\\mathrm{~J~}\\\\cdot\\\\mathrm{~m~}^{-3}$, the specific surface energy is $1~\\\\mathrm{J}\\\\cdot\\\\mathrm{m}^{-2}$, and the strain energy is negligible, calculate the diameter of the new phase particles when the surface energy is $1\\\\%$ of the volume free energy.", + "answer": "Diameter $2r=6\\\\times10^{-6}\\\\mathrm{~m~}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解新相粒子的直径，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及自由能变化、表面能等概念的关联，并需要综合分析表面能与体积自由能的关系来确定粒子直径。虽然不涉及复杂的机理分析或创新设计，但超出了简单公式套用的范畴。 | 难度: 在计算题中属于多步骤计算过程难度。题目涉及自由能、表面能和应变能的概念，但计算步骤相对直接，主要是应用公式和单位转换。虽然需要理解概念关联，但计算过程并不复杂，没有涉及多变量或高级数学技巧。" + }, + { + "idx": 2266, + "question": "Describe the characteristics of diffusionless phase transformation.", + "answer": "Diffusionless phase transformation has the following characteristics: (1) There is a shape change caused by uniform shear, resulting in a change in the crystal's external form. (2) Since the phase transformation process is diffusionless, the new phase and the parent phase have the same chemical composition. (3) There is a certain crystallographic orientation relationship between the parent phase and the new phase. (4) The phase boundary moves extremely fast, approaching the speed of sound.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述无扩散相变的特征，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述扩散型相变的特征，涉及多个关键特性的列举和解释，需要理解相变过程中的晶体结构变化、化学组成保持、取向关系以及相界移动速度等概念。虽然不涉及复杂的计算或深度推理，但需要对多个相关概念进行综合理解和关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对扩散less相变的多个特征进行详细描述和关联分析。需要考生不仅掌握基本概念，还要能够整合晶体结构变化、化学成分一致性、取向关系以及相界移动速度等多个方面的知识，并进行多角度的论述。这超出了简单的概念复述（等级3），但尚未达到需要深度关联其他学科知识或进行复杂推导的等级5水平。" + }, + { + "idx": 2267, + "question": "Describe the basic characteristics of the possible precipitates in Al-Cu alloys", + "answer": "GP zones are disc-shaped, with a thickness of 0.3~0.6nm and a diameter of about 8nm, formed on the {100} planes of the parent phase. Their lattice is the same as that of the matrix α (fcc) and is fully coherent with the α phase. The θ′′ transition phase is disc-shaped, with a thickness of 2nm and a diameter of 30~40nm, formed on the {100} planes of the parent phase. It has a tetragonal lattice with lattice constants a=b=0.404nm, c≈0.78nm, and is fully coherent with the matrix. However, due to the difference in lattice constants along the Z-axis, there is about 4% mismatch, creating an elastic coherency strain field around θ′′. The θ′ transition phase also forms on the {100} planes of the matrix, with a tetragonal structure and lattice constants a=b=0.404nm, c=0.58nm, and its nominal composition is CuAl2. Due to the large mismatch along the Z-axis, it can only maintain partial coherence with the matrix. The θ phase has a tetragonal structure with lattice constants a=b=0.607nm, c=0.487nm. This equilibrium precipitate phase is completely incoherent with the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述Al-Cu合金中可能析出相的基本特征，答案以文字解释和论述的形式详细说明了GP区、θ′′过渡相、θ′过渡相和θ相的结构特征、晶格常数以及与基体的共格关系，符合简答题的特征。 | 知识层次: 题目要求描述Al-Cu合金中可能析出相的基本特征，涉及多个析出相（GP zones、θ′′、θ′、θ）的形态、晶体结构、晶格常数以及与基体的共格关系等。这需要理解并关联多个知识点，进行综合分析，而不仅仅是简单的记忆或单一概念的应用。虽然不涉及复杂的计算或深度推理，但需要对不同析出相的特征进行比较和关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对Al-Cu合金中可能析出的沉淀相的基本特征进行多角度分析论述。需要详细描述GP区、θ′′过渡相、θ′过渡相和θ相的形状、尺寸、晶体结构、晶格常数以及与基体的共格关系等多个方面的特征，并解释其中的差异和关联。这种综合分析和对多个概念的理解与关联，使得该题目在同题型内属于较高难度等级。" + }, + { + "idx": 2268, + "question": "Why do transition phases appear during the precipitation process?", + "answer": "Transition phases appear during the precipitation process because the system requires a series of intermediate transition phases to gradually reduce free energy during the transformation from a supersaturated solid solution to the equilibrium phase. These transition phases, with their crystal structures and compositions intermediate between GP zones and the equilibrium phase, can reduce nucleation work and strain energy, making the phase transformation process easier to proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释过渡相在析出过程中出现的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释过渡相在析出过程中出现的机理，涉及自由能降低、晶体结构中间态、形核功和应变能等复杂概念的综合分析，需要深入理解相变热力学和动力学原理，并进行多因素关联推理。 | 难度: 在简答题-复杂分析题型中，该题目要求对过渡相在沉淀过程中出现的机理进行深度解释，涉及自由能降低、中间过渡相的作用、晶体结构与成分的中间性、形核功和应变能的降低等多个专业概念的综合运用和推理分析。虽然题目没有要求对复杂现象进行全面分析（如多因素交互影响或动态过程模拟），但已超出基础概念复述层面，属于机理深度解释的范畴。" + }, + { + "idx": 2269, + "question": "For carbon steel samples with carbon mass fractions of w_c=0.003 and w_C=0.012 and a diameter of φ5mm, both heated at 860°C and then quenched, explain the microstructure morphology, fine structure, and composition obtained after quenching.", + "answer": "Heated at 860°C, both steels are in the single-phase region (refer to the Fe-Fe3C phase diagram), and after quenching, both form martensite. The carbon steel with w_C=0.012 contains a certain amount of retained austenite. For the carbon steel with w_c=0.003, the martensite composition is w_c=0.003, with a lath-like morphology and a fine structure of dislocations. For the carbon steel with w_c=0.012, the martensite composition is w_c=0.012, with an acicular morphology and a fine structure of twins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释淬火后获得的微观结构形态、精细结构和成分，需要详细的文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目要求解释不同碳含量钢在淬火后的显微组织形态、精细结构和成分，需要结合Fe-Fe3C相图进行分析，并理解马氏体转变的基本原理。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对两种不同碳含量的钢在相同热处理条件下的微观结构、精细结构和成分进行详细分析和论述。需要综合运用Fe-Fe3C相图知识、马氏体转变原理以及不同碳含量对马氏体形态和精细结构的影响等多方面知识。此外，还需要区分和解释两种钢在淬火后微观结构的差异（如板条状马氏体与针状马氏体、位错与孪晶亚结构等），并说明残留奥氏体的存在情况。这种多角度、综合分析的要求使得该题目在同题型中属于较高难度等级。" + }, + { + "idx": 2270, + "question": "Referring to the composite material in the previous question. Given that the yield strength of steel is 280 MPa and the yield strength of copper is 140 MPa. What is the maximum tensile load the composite material can withstand without undergoing plastic deformation?", + "answer": "The maximum tensile force is F⊥=Fcu+Fst=(140×10^6 N/m^2)×(2.4×10^−6 m^2)+(260×10^6 N/m^2)×(0.8×10^−6 m^2)=540 N", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的材料强度和面积数据来求解最大拉伸载荷，答案也是通过具体计算得出的数值结果。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，仅需将给定的材料参数代入公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目虽然涉及两种材料的强度计算，但本质上只需要分别套用各自的屈服强度公式（F=σ×A）进行独立计算，最后简单相加即可。不需要复杂的公式组合或推导过程，解题步骤清晰直接，属于该题型框架内的基础难度级别。" + }, + { + "idx": 2271, + "question": "For a φ5mm carbon steel sample with a carbon mass fraction of w_c=0.012, after quenching at 860°C and then tempering, how will the microstructure change during the tempering process?", + "answer": "For carbon steel with w_c=0.012, when tempered below 100°C, carbon atoms form carbon-rich regions; during tempering at 100~200°C, a large number of fine carbides precipitate, resulting in a slight increase in hardness; during tempering at 200~300°C, retained austenite transforms into tempered martensite (or bainite), causing an increase in hardness, but at the same time, the hardness of martensite decreases, so overall, the hardness change is minimal; when tempered above 300°C, carbides continue to precipitate, followed by carbide growth and spheroidization, while the α phase undergoes recovery and recrystallization, leading to a decrease in hardness and an increase in toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述碳钢在回火过程中微观结构的变化过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细解释碳钢在回火过程中微观结构的变化，涉及多个温度阶段的相变和性能变化，需要综合运用材料科学中的相变理论、碳化物析出和长大机制、以及力学性能变化的知识。这需要深入的理解和综合分析能力，属于复杂分析的层次。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求考生综合运用材料科学知识，详细解释碳钢在回火过程中微观结构的变化机理，涉及多个温度区间和相应的相变过程。考生需要深入理解碳原子扩散、碳化物析出、残余奥氏体转变以及α相回复再结晶等复杂现象，并能够系统性地阐述这些变化对材料性能的影响。这种题目不仅要求考生掌握广泛的知识点，还需要具备较强的逻辑推理和综合分析能力，因此在简答题题型中属于最高难度等级。" + }, + { + "idx": 2272, + "question": "Referring to the composite material in the previous question. Given that the yield strength of steel is 280 MPa and the yield strength of copper is 140 MPa. If the composite material is subjected to tension, which metal will yield first?", + "answer": "Since the stress ratio is 1.86, when the stress on steel is 140 MPa, the stress on copper is also 140 MPa. Therefore, copper will yield first.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答哪个金属会先屈服，而不是从选项中选择或进行数值计算。 | 知识层次: 题目涉及简单的应力比较和材料屈服强度的基本概念应用，仅需直接比较两种金属的屈服强度并得出结论，无需多步计算或复杂分析。 | 难度: 在简答题中属于简单应用过程描述，仅需直接应用给定的应力比和屈服强度数据进行比较，无需复杂的推导或解释。解题步骤简单，仅需一步比较即可得出结论。" + }, + { + "idx": 2273, + "question": "A steel wire with a diameter of 0.89 mm has σ_ss=980 MPa and σ_sb=1,130 MPa. There is also an aluminum alloy with σ_as=255 MPa and σ_ab=400 MPa. Their densities are known to be ρ_s=7.85 g/cm³ and ρ_a=2.7 g/cm³, respectively. If the aluminum wire is to bear the same maximum load without deformation, how much heavier or lighter is it compared to the steel wire (expressed as a percentage)?", + "answer": "σ_ss=φ_max/A_s=980, σ_as=φ_max/A_a=255. From these two equations, we know A_s/A_a=255/980. A_a=3.84A_s. m_a/m_s=(3.84×2.7)/(1×7.85)=1.32. 1.32-1=0.32=32%. This aluminum wire is 32% heavier than the steel wire.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来比较两种材料的重量差异，答案中包含了具体的计算过程和百分比结果。 | 知识层次: 题目需要进行多步计算，包括应力与面积的关系推导、不同材料的性能比较，以及密度和质量的综合计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行中等难度的应用分析。 | 难度: 在计算题中属于综合性计算问题，需要理解材料强度与截面积的关系，进行多步计算（包括比例转换和密度计算），并综合分析两种材料的性能差异。虽然涉及多个变量，但计算步骤相对清晰，属于中等应用层次中的典型问题。" + }, + { + "idx": 2274, + "question": "A steel wire with a diameter of 0.89 mm has σ_ss=980 MPa and σ_sb=1,130 MPa. Another aluminum alloy has σ_as=255 MPa and σ_ab=400 MPa. Their densities are known to be ρ_s=7.85 g/cm³ and ρ_a=2.7 g/cm³, respectively. What if they do not break?", + "answer": "σ_sb=φ_max/A_s=1,130, σ_ab=φ_max/A_a=400. From the above two equations, A_s/A_a=400/1,130. A_a=2.825A_s. m_a/m_s=(2.825×2.7)/(1×7.85)=0.97. 0.97-1=-0.03=-3%. That is, the aluminum wire is 3% lighter than the steel wire.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目给出了具体的材料参数和条件，要求通过数值计算和公式应用来比较两种材料的重量差异。解答过程中涉及到了面积比、密度比等计算步骤，最终得出具体的百分比结果(-3%)，这些都是计算题的典型特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用材料力学性能参数（抗拉强度、密度）进行比值计算和比较分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解材料力学的基本概念（如屈服强度、抗拉强度、密度等），并进行多步计算和公式应用。题目涉及两种材料的比较，需要综合分析并建立比例关系，但计算过程相对直接，没有涉及复杂多变量或高级数学技巧。" + }, + { + "idx": 2275, + "question": "Referring to the composite material in the previous question. Given that the elastic modulus of steel is 205 GPa and the elastic modulus of copper is 110 GPa. What is the elastic modulus of this composite material?", + "answer": "E=(φE)st+(φE)cu=0.25×(205000 MPa)+0.75×(110000 MPa)=130000 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的弹性模量数据和公式进行数值计算，最终得出复合材料的弹性模量。答案是通过具体的计算步骤和公式应用得出的数值结果，符合计算题的特征。 | 知识层次: 题目考查基本公式的直接应用和简单计算，仅需将给定的弹性模量和体积分数代入公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（混合法则）进行简单数值计算，无需多步推导或复杂公式组合。题目明确给出了所有必要参数，计算过程仅涉及基本算术运算。" + }, + { + "idx": 2276, + "question": "Please derive the rule of mixtures for the longitudinal elastic modulus of a fiberglass composite fishing rod (composed of longitudinally aligned glass fibers and polyester resin as the bonding fiber).", + "answer": "The derivation assumes that the two constituent materials have the same Poisson's ratio, and the transverse strain is negligible. Under longitudinal loading, the strains of the two components must be equal, i.e., $$ {\\\\varepsilon}_{\\\\mathfrak{g}1}={\\\\varepsilon}_{\\\\mathfrak{m}}={\\\\varepsilon}_{\\\\mathfrak{p}\\\\mathfrak{r}}$$ $$ {\\\\frac{F/f_{\\\\mathrm{^{gl}}}}{E_{\\\\mathrm{gl}}}}={\\\\frac{F/A}{E_{\\\\mathrm{m}}}}={\\\\frac{F/f_{\\\\mathrm{pr}}}{E_{\\\\mathrm{pr}}}}$$ where $E_{\\\\mathrm{m}}$ is the elastic modulus of the mixture; $_{\\\\mathrm{g1}}$ represents glass fiber; pr represents resin fiber; $A$ is the total cross-sectional area (can be considered as 1), and $f$ is the cross-sectional area (or volume) fraction of different materials. Then, $$ \\\\begin{array}{c}{F_{\\\\mathrm{g1}}=\\\\frac{f_{\\\\mathrm{g1}}E_{\\\\mathrm{g1}}F}{E_{\\\\mathrm{m}}}}\\\\\\\\ {F_{\\\\mathrm{pr}}=\\\\frac{f_{\\\\mathrm{pr}}E_{\\\\mathrm{pr}}F}{E_{\\\\mathrm{m}}}}\\\\end{array}$$ Since $F=F_{\\\\mathrm{gl}}+F_{\\\\mathrm{pr}}$, it follows that $$ F=\\\\frac{(f_{\\\\mathrm{gl}}E_{\\\\mathrm{gl}}+f_{\\\\mathrm{pr}}+E_{\\\\mathrm{pr}})F}{E_{\\\\mathrm{m}}}$$ $$ E_{\\\\mathrm{m}}=f_{\\\\mathrm{g1}}E_{\\\\mathrm{g1}}+f_{\\\\mathrm{pr}}E_{\\\\mathrm{pr}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导纤维增强复合材料纵向弹性模量的混合规则，涉及公式推导和数学运算，答案展示了详细的推导过程和最终公式，属于典型的计算题。 | 知识层次: 题目要求推导复合材料纵向弹性模量的混合规则，涉及多步计算和概念关联，需要理解应变相等假设、力的平衡以及体积分数的应用。虽然不涉及复杂的机理分析或创新设计，但需要综合运用基本概念和公式进行推导。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如弹性模量、应变、体积分数等），进行多步推导和计算。虽然涉及多个变量和公式，但整体逻辑清晰，步骤明确，属于中等偏上的难度。" + }, + { + "idx": 2277, + "question": "From the perspective of wettability, should β-SiC whiskers or Al2O3 short fibers be selected as the reinforcement for aluminum matrix composites? It is known that the wettability of molten aluminum on β-SiC is higher than that on Al2O3.", + "answer": "The wettability of molten aluminum on β-SiC is higher than that on Al2O3. From the perspective of wettability, β-SiC whiskers should be selected as the reinforcement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从润湿性角度分析并选择增强材料，需要文字解释和论述，答案也以文字形式给出，没有选项或计算要求。 | 知识层次: 题目要求从润湿性角度分析并选择增强材料，涉及对润湿性概念的理解和应用，需要综合分析已知条件（熔融铝在β-SiC上的润湿性优于Al2O3）并做出合理选择。虽然不涉及复杂计算，但需要关联概念和进行简单推理，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求从润湿性角度分析并选择增强材料，需要理解润湿性的概念，并能将已知的润湿性数据与材料选择关联起来。虽然涉及多步分析和概念关联，但不需要进行复杂的多角度或深度关联性分析，因此属于综合分析和说明的难度等级。" + }, + { + "idx": 2278, + "question": "Calculate the critical length Lc of β-SiC whiskers, given a diameter of 0.5μm, tensile strength of 70000MPa, and interfacial shear strength τy approximated by the matrix yield strength of 76MPa.", + "answer": "For β-SiC whiskers, the critical length Lc = (0.5×10^-6 × 70000) / (2 × 38) = 460.5×10^-6 m = 460.5μm. Since the actual length of 70μm is less than Lc, the fibers do not achieve the maximum strengthening effect.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（直径、拉伸强度、界面剪切强度）进行数值计算，应用公式求解临界长度Lc，答案呈现为具体的计算结果和单位转换，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及材料力学性能参数的应用和综合分析，需要理解临界长度的概念及其与纤维增强效果的关系，但不需要进行复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用公式并进行多步计算，同时涉及材料力学和复合材料的基本概念。虽然计算步骤明确，但需要理解临界长度的定义及其对材料性能的影响，属于中等应用层次的计算题。" + }, + { + "idx": 2279, + "question": "Calculate the critical length Lc of Al2O3 short fibers, given a diameter of 10μm, tensile strength of 2275MPa, and interfacial shear strength τy approximated by the matrix yield strength of 76MPa.", + "answer": "For Al2O3 short fibers, the critical length Lc = (10×10^-6 × 2275) / (2 × 38) = 299.3×10^-6 m = 299.3μm. Since the actual length of 4mm is greater than Lc, the fibers can achieve maximum strengthening effect.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（直径、拉伸强度、界面剪切强度）应用特定公式进行计算，最终得出临界长度Lc的数值结果。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的参数和公式计算临界长度，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用临界长度公式Lc = (d×σf)/(2×τy)进行简单数值代入和单位换算，无需多步骤推导或复杂概念整合。所有参数均已明确给出，计算过程仅涉及基本代数运算，符合等级1对\"直接套用公式\"的定义。" + }, + { + "idx": 2281, + "question": "Predict the strength σLu of an Al2O3 short fiber reinforced composite at a volume fraction φf=0.1, given the fiber stress σf=2190MPa and the matrix yield strength σy=76MPa.", + "answer": "For Al2O3 short fiber composites, the strength σLu = σf × φf + σy × (1 - φf) = 2190 × 0.1 + 76 × 0.9 = 386MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体计算，最终得出一个数值结果。解答过程涉及数值代入和运算，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及的知识点较为基础，思维过程较为直接，无需多步计算或综合分析。 | 难度: 在计算题-简单应用题型中，该题目属于单一公式直接计算的等级1难度。题目仅需套用复合材料强度的基本混合法则公式σLu = σf × φf + σy × (1 - φf)，代入给定数值即可得到结果，无需额外的公式组合或复杂计算步骤。" + }, + { + "idx": 2282, + "question": "Calculate the critical volume fraction φtr of β-SiC whisker reinforced composite, given the matrix tensile strength σm=186MPa, yield strength σy=76MPa, and average fiber stress σf=5320MPa.", + "answer": "For β-SiC whiskers, the critical volume fraction φtr = (σm - σy) / (σf - σy) = (186 - 76) / (5320 - 76) = 0.021.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出一个具体的数值结果（临界体积分数φtr），这符合计算题的特征。 | 知识层次: 题目要求直接套用给定的公式进行数值计算，涉及基本的公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式进行简单数值计算，无需任何额外的步骤或复杂的公式组合。题目中给出的参数明确，计算过程直接，属于基本公式应用和简单计算的范畴。" + }, + { + "idx": 2283, + "question": "Calculate the fiber stress σf of Al2O3 short fibers when the length exceeds the critical length, given the fiber tensile strength σfa=2275MPa, critical length Lc=299.3μm, and actual length L=4mm.", + "answer": "For Al2O3 short fibers, the fiber stress σf = (1 - Lc/(2L)) × σfa = (1 - 299.3×10^-6/(2 × 4000×10^-6)) × 2275 = 2190MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数值代入和计算步骤，最终得出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。解题过程只需套用给定的公式并代入数值进行计算，属于简单应用层次。 | 难度: 在计算题中属于最简单等级，仅需直接套用单一公式进行数值计算，无需多步骤推导或组合多个公式。题目明确给出了所有必要参数，且计算过程仅涉及基本代数运算，属于典型的\"单一公式直接计算\"类型。" + }, + { + "idx": 2284, + "question": "Predict the strength σLu of a β-SiC whisker-reinforced composite with a volume fraction φf=0.1, given the average fiber stress σf=5320MPa and the matrix yield strength σy=76MPa.", + "answer": "For the β-SiC whisker composite, the strength σLu = σf × φf + σy × (1 - φf) = 5320 × 0.1 + 76 × 0.9 = 700MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出一个数值结果。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，无需多步推理或综合分析，仅需将给定数值代入公式即可得出结果。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（混合法则）进行简单数值计算，无需任何变形或组合步骤。题目中所有参数均已明确给出，计算过程仅涉及基本乘法和加法运算。" + }, + { + "idx": 2285, + "question": "Calculate the critical volume fraction φtr of Al2O3 short fiber reinforced composite, given the matrix tensile strength σm=186MPa, yield strength σy=76MPa, and fiber stress σf=2190MPa.", + "answer": "For Al2O3 short fibers, the critical volume fraction φtr = (σm - σy) / (σf - σy) = (186 - 76) / (2190 - 76) = 0.052.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出一个数值结果。答案展示了完整的计算过程和最终结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需理解公式并代入数值进行计算。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式进行简单数值计算，无需多步骤推导或复杂公式组合。题目明确给出了所有必要参数，且公式应用直接明了。" + }, + { + "idx": 2286, + "question": "A steel wire (with a diameter of $1~\\\\mathrm{mm}$) is coated with a layer of copper (total diameter of $2~\\\\mathrm{mm}$). What is the thermal expansion coefficient of this composite material? The elastic modulus of steel is $E_{\\\\mathrm{st}}{=}205~\\\\mathrm{GPa}$, and that of copper is $E_{\\\\mathrm{cu}}{=}110~\\\\mathrm{GPa}$; their expansion coefficients are $\\\\alpha_{\\\\mathrm{st}}=1.1\\\\times10^{-6}/\\\\mathsf{\\\\Pi}^{\\\\circ}\\\\mathsf{C}, \\\\alpha_{\\\\mathrm{Cu}}=17\\\\times10^{-6}/\\\\mathsf{\\\\Pi}^{\\\\circ}\\\\mathsf{C}$ respectively.", + "answer": "Under no-load conditions, the composite material satisfies $(\\\\Delta l/L)_{\\\\mathrm{st}}=(\\\\Delta l/L)_{\\\\mathrm{cu}}$, and the forces $F_{\\\\mathrm{Cu}}=-F_{\\\\mathrm{st}}$. If $\\\\Delta t= 1^{\\\\circ}\\\\mathrm{C}$, then $$ A_{\\\\mathrm{Cu}}=\\\\pi(\\\\frac{d}{2})^{2}=(\\\\pi/4)(0.002\\\\mathrm{m})^{2}-0.8\\\\times10^{-6}\\\\mathrm{m}^{2}=2.4\\\\times10^{-6}\\\\mathrm{m}^{2}$$ $$ (\\\\Delta l/L)_{\\\\mathrm{st}}=(\\\\Delta l/L)_{\\\\mathrm{cu}}$$ $$ \\\\begin{array}{r}{\\\\left[\\\\alpha\\\\Delta t+(F/A)/E\\\\right]_{\\\\ast}=\\\\left[\\\\alpha\\\\Delta t+(F/A)/E\\\\right]_{\\\\mathrm{cu}}}\\\\end{array}$$ $$ 1\\\\times10^{-6})\\\\times1+{\\\\frac{F_{\\\\mathrm{st}}/(0.8\\\\times10^{-6}{\\\\mathrm{m}}^{2})}{205\\\\times10^{9}{\\\\mathrm{N/m}}^{2}}}=(17\\\\times10^{-6})\\\\times1+{\\\\frac{-F_{\\\\mathrm{st}}/(2.4\\\\times10^{-6}{\\\\mathrm{m}}^{2})}{110\\\\times10^{9}{\\\\mathrm{N/m}}^{2}}}$$ When $\\\\Delta t=1~^{\\\\circ}C$, then $$ (\\\\Delta l/L)_{\\\\mathrm{cu}}=(17\\\\times10^{-6}/^{9}\\\\mathbb{C}\\\\times1^{9}\\\\mathbb{C})+\\\\frac{=0.61~\\\\mathrm{N}/(2.4\\\\times10^{-6}~\\\\mathrm{m}^{2})}{110\\\\times10^{9}~\\\\mathrm{N/m}^{2}}=15\\\\times10^{-6}$$ Thus, the thermal expansion coefficient of the composite material is $$ \\\\overline{{\\\\alpha}}=15\\\\times10^{-6}/^{\\\\circ}\\\\mathrm{C}$$ $A_{\\\\mathrm{st}}=\\\\pi(\\\\frac{d}{2})^{2}=(\\\\pi/4)(0.001~\\\\mathrm{m})^{2}=0.8\\\\times10^{-6}~\\\\mathrm{m}^{2}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的膨胀系数，答案中包含了详细的数学推导和计算过程。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用热膨胀系数、弹性模量等知识，并进行综合分析。虽然不需要深度推理或创新应用，但计算过程较为复杂，涉及多个公式的应用和联立求解。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料的膨胀行为，应用热膨胀系数和弹性模量的概念，进行多步计算和平衡条件的分析。虽然涉及多个变量和公式，但步骤相对清晰，属于中等偏上的难度。" + }, + { + "idx": 2287, + "question": "Calculate the average stress σf of β-SiC whiskers when the critical length is not reached, given the matrix yield strength σy=76MPa, fiber length L=70μm, and diameter df=0.5μm.", + "answer": "For β-SiC whiskers, the average stress σf = (τy × L) / df = (σy × L) / (2 × df) = (76 × 70×10^-6) / (2 × 0.5×10^-6) = 5320MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出一个具体的数值结果。答案展示了完整的计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，无需多步推理或综合分析，仅需理解公式并代入数值进行计算。 | 难度: 在计算题中属于简单公式应用计算难度。题目直接给出了所需公式σf = (σy × L) / (2 × df)，只需将已知数值代入即可完成计算。虽然涉及单位换算(μm到m)，但这是材料科学计算中的基本操作。解题过程仅需1个核心公式和3个计算步骤，不需要公式推导或多公式组合，符合等级2\"简单公式应用计算\"的特征。" + }, + { + "idx": 2288, + "question": "A contact device is made of silver-tungsten composite material. Its production process involves first creating a porous tungsten powder metallurgy blank, and then infiltrating pure silver into the pores. Before silver infiltration, the density of the tungsten compact is 14.5 g/cm³. Calculate the mass fraction of silver in the blank after infiltration. The densities of pure tungsten and pure silver are 19.3 g/cm³ and 10.49 g/cm³, respectively. Assume the tungsten blank is very thin and entirely composed of open pores.", + "answer": "The mass fraction of silver after infiltration is wAg = (0.25 × 10.49) / (0.25 × 10.49 + 0.75 × 19.3) = 15.4%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及密度、质量分数等物理量的计算，最终给出一个具体的百分比数值作为答案。 | 知识层次: 题目需要进行多步计算，包括计算钨的体积分数、银的体积分数以及最终的质量分数，涉及多个物理概念的关联和综合运用，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解多步计算过程并应用密度和孔隙率的概念。题目涉及质量分数的计算，需要先计算钨的体积分数和孔隙率，再计算银的质量分数。虽然步骤较多，但每个步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 2289, + "question": "A contact device is made of silver-tungsten composite material. Its production process involves first creating a porous tungsten powder metallurgy blank, then infiltrating pure silver into the pores. Before silver infiltration, the density of the tungsten compact is 14.5 g/cm³. Calculate the volume fraction of the pores. The density of pure tungsten is known to be 19.3 g/cm³. Assume the tungsten blank is very thin and all pores are open.", + "answer": "The pore density ρ_pore is obviously zero. Therefore, φ_pore = 1 - φ_tungsten = 1 - (ρc / ρ_tungsten) = 1 - (14.5 / 19.3) = 0.25", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解孔隙的体积分数，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的密度值计算孔隙的体积分数。虽然需要理解孔隙和基体材料的关系，但计算过程直接且步骤单一，属于典型的简单应用层次。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（体积分数计算公式）并进行简单数值计算，无需多步推导或组合公式。题目中所有必要参数均已明确给出，解题思路直接明了。" + }, + { + "idx": 2290, + "question": "In randomly oriented short fiber composites, what is the relationship between the value of $\\\\frac{L_{\\\\mathrm{c}}}{L}$ and the number of pulled-out fibers and fractured fibers on the composite fracture surface? Please explain.", + "answer": "If the fiber strength variability is not significant, for a single ideal straight short fiber, the probability of fracture occurring at any location is equal. In the composite, for a segment of the composite with the same fiber length, the probability of fracture occurring at any location is also equal. The probability that the fracture occurs at a distance less than $L_{\\\\mathrm{c}}/2$ from the fiber end should be $L_{\\\\mathrm{c}}/L$ (where $L$ is the fiber length). When the fracture occurs at a distance less than $L_{\\\\mathrm{c}}/2$ from the fiber end, the fiber will not fracture but will instead be pulled out from the matrix. This probability is the same for any fiber. Therefore, $L_{\\\\mathrm{c}}/L$ represents the probability of fiber pull-out on the fracture surface of the short fiber composite, and $1-L_{\\\\mathrm{c}}/L$ represents the probability of fiber fracture on the fracture surface, meaning the number of fractured fibers is the total number of fibers on the fracture surface multiplied by $(1-L_{\\\\mathrm{c}}/L)$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释短纤维复合材料中纤维断裂和拔出的关系，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释短纤维复合材料中断裂表面纤维拔出和断裂数量与临界长度比（Lc/L）的关系，涉及概率分析、临界长度的概念理解、以及复合材料断裂机理的综合运用。需要深入理解纤维断裂和拔出的条件，并进行逻辑推理和综合分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用材料力学和概率统计知识，深入解释短纤维复合材料断裂表面的纤维拔出与断裂比例关系。需要理解临界长度Lc的概念，建立概率模型，并推导出Lc/L与拔出/断裂纤维数量的定量关系。这种需要多学科知识整合和机理深度解释的题目，在同题型中属于最高难度等级。" + }, + { + "idx": 2291, + "question": "What is the role and mechanism of particle (granular) reinforcement?", + "answer": "Particle reinforcement: Hard particles with a diameter of 1~50 μm are added to the matrix. The particles can bear part of the load, but the matrix bears the main load. The particles restrict the deformation of the matrix through mechanical constraint. Properly sized and uniformly distributed particles can effectively strengthen the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释粒子增强的作用和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释粒子增强的基本概念，还需要论述其作用机制（如机械约束、载荷分配等），涉及多个知识点的关联和综合分析，思维过程要求较高。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求解释颗粒增强的作用和机理，涉及对颗粒尺寸、分布、载荷分担以及基体变形限制等多个方面的综合理解。虽然不需要进行复杂现象的全面分析，但需要对材料强化机制有较深入的理解和解释能力，属于该题型中较高难度的题目。" + }, + { + "idx": 2292, + "question": "What role does the matrix play in composite materials?", + "answer": "The matrix primarily serves to fix and adhere the reinforcement, transferring the applied load to the reinforcement through the interface while also bearing a small portion of the load itself. The matrix acts like a separator, keeping the reinforcements apart. When some reinforcements are damaged or fractured, cracks are prevented from propagating from one reinforcement to another. During the processing and use of composite materials, the matrix also protects the reinforcements from chemical interactions with the environment and physical damage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对复合材料中基体的作用进行详细的文字解释和论述，答案提供了多方面的功能描述，符合简答题的特征。 | 知识层次: 题目考查对复合材料中基体作用的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释复合材料中基体的作用，涉及多个功能点（固定增强体、传递载荷、隔离保护等），但不需要深入分析或整合复杂概念体系。属于对基础概念的理解和串联表述，符合等级2的特征。" + }, + { + "idx": 2293, + "question": "Briefly describe the classification of different reinforcement particle sizes in composite materials and their strengthening mechanisms.", + "answer": "From the perspective of structural units and scales in composite materials, reinforcement particles with sizes of 1~50 μm are called particle-reinforced composites, those with sizes of 0.01~0.1 μm are called dispersion-strengthened composites, and those at submicron to nanometer scales are called fine composites, each with distinct strengthening mechanisms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述复合材料中不同增强颗粒尺寸的分类及其强化机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对复合材料中不同增强颗粒尺寸分类及其强化机制的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生简要描述复合材料中不同增强颗粒尺寸的分类及其强化机制，涉及多个概念的定义和基本原理的记忆，但不需要进行复杂的体系阐述或深入分析。考生只需准确回忆并组织相关知识即可回答，属于中等难度的概念解释类简答题。" + }, + { + "idx": 2294, + "question": "What role does the interface play in composite materials?", + "answer": "The interface serves to coordinate the deformation of the matrix and the reinforcement. Through the interface, the stress from the matrix can be transferred to the reinforcement. The matrix and reinforcement are bonded via the interface, but the bonding strength must be appropriate—neither too strong nor too weak. Excessive bonding strength can reduce the toughness of the composite material, while insufficient bonding strength fails to transfer stress effectively, making the interface prone to cracking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释复合材料中界面的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释复合材料中界面的作用，涉及多个概念的关联和综合分析，如应力传递、变形协调和结合强度的影响。虽然不涉及复杂计算，但需要对界面行为的机理有一定理解，并能够综合不同因素进行论述。 | 难度: 在简答题题型中，该题目要求对复合材料界面的作用进行多角度分析论述。不仅需要解释界面的基本功能（如协调变形和传递应力），还需要深入讨论界面结合强度的适宜性及其对材料性能的影响（如韧性和开裂倾向）。这种综合分析超出了简单的概念解释，涉及多个相关因素的权衡和相互作用，属于该题型内较高难度的题目。" + }, + { + "idx": 2295, + "question": "In a glass fiber reinforced nylon composite, the volume fraction of E-glass fiber is 0.3. The elastic moduli of E-glass and nylon are 72.4 GPa and 2.76 GPa, respectively. Calculate the fraction of the load borne by the fibers in the composite.", + "answer": "If the interface bonding is good, the strain of the composite under force should be equal to that of the matrix and the fibers, i.e., $$ \\\\varepsilon_{\\\\mathrm{c}}={\\\\frac{\\\\sigma_{\\\\mathrm{c}}}{E_{\\\\mathrm{c}}}}=\\\\varepsilon_{\\\\mathrm{m}}={\\\\frac{\\\\sigma_{\\\\mathrm{m}}}{E_{\\\\mathrm{m}}}}=\\\\varepsilon_{\\\\mathrm{f}}={\\\\frac{\\\\sigma_{\\\\mathrm{f}}}{E_{\\\\mathrm{f}}}} $$ Thus, $$ \\\\frac{\\\\sigma_{\\\\mathrm{f}}}{\\\\sigma_{\\\\mathrm{m}}}=\\\\frac{E_{\\\\mathrm{f}}}{E_{\\\\mathrm{m}}}=\\\\varepsilon_{\\\\mathrm{f}}=\\\\frac{72.4~\\\\mathrm{GPa}}{2.76~\\\\mathrm{GPa}}=26.25 $$ The fraction of the load borne by the fibers is $$ \\\\varphi=\\\\frac{\\\\sigma_{\\\\mathrm{f}}}{\\\\sigma_{\\\\mathrm{f}}+\\\\sigma_{\\\\mathrm{m}}}=\\\\frac{1}{1+\\\\frac{\\\\sigma_{\\\\mathrm{m}}}{\\\\sigma_{\\\\mathrm{f}}}}=\\\\frac{1}{1+\\\\frac{1}{26.25}}=0.96 $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，涉及弹性模量的计算和负载分配比例的推导，最终需要得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及复合材料中纤维和基体的弹性模量比较，以及载荷分配的计算。虽然计算过程相对直接，但需要理解复合材料的基本力学行为和应变相等的假设，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料力学的基本概念（等应变假设），进行多步公式推导和数值计算，涉及弹性模量比较和载荷分配比例计算。虽然计算过程明确，但需要将多个概念关联并正确应用公式，属于中等偏上的复杂度。" + }, + { + "idx": 2296, + "question": "What is the role and mechanism of dispersion strengthening?", + "answer": "Dispersion strengthening: mainly applied to metal matrices, by adding hard particles such as Al2O3, TiC, SiC, etc., with particle sizes around 0.01~0.1μm. These particles dispersed in the metal or alloy can effectively hinder the movement of dislocations, providing significant strengthening effects, but the matrix remains the primary load-bearing component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释分散强化的作用和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释分散强化的定义和基本原理，还需要详细说明其作用机制（如阻碍位错运动）和实际应用（如添加特定颗粒）。这涉及对材料科学中强化机制的深入理解和综合分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对分散强化的作用和机理进行深度解释，涉及金属基体中添加硬质颗粒的具体类型、尺寸范围，以及这些颗粒如何阻碍位错运动从而提供强化效果。虽然题目没有要求全面分析复杂现象，但对机理的解释需要一定的深度和细节，属于机理深度解释的等级。" + }, + { + "idx": 2297, + "question": "Given a hard alloy containing WC, TiC, TaC, and Co with mass fractions of 0.25, 0.15, 0.05, and 0.05, respectively. Their densities are $15.77\\\\mathrm{g/cm^{3}}, 4.94\\\\mathrm{g/cm^{3}}, 14.5\\\\mathrm{g/cm^{3}}, 8.9\\\\mathrm{g/cm^{3}}$. Calculate the density of this composite material.", + "answer": "The density can be calculated using $\\\\rho_{\\\\mathrm{c}}=\\\\rho_{\\\\mathrm{wc}}\\\\varphi_{\\\\mathrm{wc}}+\\\\rho_{\\\\mathrm{Tic}}\\\\varphi_{\\\\mathrm{Tic}}+\\\\rho_{\\\\mathrm{Tac}}\\\\varphi_{\\\\mathrm{TaC}}+\\\\rho_{\\\\mathrm{co}}\\\\varphi_{\\\\mathrm{co}}$. Convert the mass fractions to volume fractions, i.e., $$ $$ \\\\begin{array}{l}{\\\\displaystyle{\\\\varphi_{\\\\mathrm{\\\\tiny~\\\\mathrm{{TC}}}}=\\\\frac{\\\\frac{15}{4.94}}{8.70}=0.349}}\\\\ {~}\\\\ {\\\\displaystyle{\\\\varphi_{\\\\mathrm{\\\\tiny~\\\\mathrm{{Tac}}}}=\\\\frac{\\\\frac{5}{14.5}}{8.70}=0.040}}\\\\ {~}\\\\ {\\\\displaystyle{\\\\varphi_{\\\\mathrm{\\\\tiny~{co}}}=\\\\frac{\\\\frac{5}{8.90}}{8.70}=0.064}}\\\\end{array}$$ $$ \\\\rho\\\\mathrm{c}=\\\\sum\\\\rho_{i}\\\\varphi_{i}=11.5~\\\\mathrm{g/cm}^{3}$$ \\\\varphi\\\\mathrm{wc}={\\\\frac{\\\\frac{25}{15.77}}{{\\\\frac{25}{15.77}}+{\\\\frac{15}{4.94}}+{\\\\frac{5}{14.5}}+{\\\\frac{5}{8.9}}}}={\\\\frac{4.76}{8.70}}=0.547$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的密度，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量分数到体积分数的转换，以及最终密度的综合计算。虽然不涉及复杂的推理分析或机理解释，但需要理解和应用多个概念和公式，并进行综合计算。 | 难度: 在计算题中属于综合性计算问题，需要掌握多步计算和概念关联。题目要求将质量分数转换为体积分数，并进行多组分复合材料的密度计算，涉及多个变量的处理和综合分析。虽然计算步骤较多，但每一步都有明确的公式指导，因此属于中等偏上的难度。" + }, + { + "idx": 2298, + "question": "What role does the reinforcement play in composite materials?", + "answer": "From the perspective that the reinforcement in structural composites mainly bears the load, it is generally required that the reinforcement has high strength and high modulus. The volume fraction of the reinforcement and its bonding performance with the matrix greatly influence the properties of the composite material. The combined action of the reinforcement, matrix, and interface can alter the toughness, fatigue resistance, creep resistance, impact resistance, and other properties of the composite material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释复合材料中增强体的作用，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查复合材料中增强体的基本作用及其对材料性能的影响，属于基础概念的记忆和理解范畴。虽然涉及一些性能的关联，但整体上是对基本原理和作用的描述，不需要复杂的分析或综合。 | 难度: 在简答题题型中，该题目要求解释增强体在复合材料中的作用，涉及基本概念的解释和描述，包括增强体的功能、性能要求及其对复合材料性能的影响。虽然需要一定的知识整合，但并未涉及复杂概念体系的阐述或深入分析，属于概念解释和描述的难度等级。" + }, + { + "idx": 2299, + "question": "Briefly describe the relationship between the size of composite material specimens and their strength.", + "answer": "The larger the composite material specimen, the higher the probability of defects, and the lower the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述复合材料试样尺寸与其强度之间的关系，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查复合材料尺寸与强度关系的基本概念，属于对基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求对复合材料尺寸与强度之间的关系进行解释和描述，涉及基础概念的理解和简单逻辑推理。虽然需要一定的记忆性知识，但不需要复杂的体系阐述或深入分析，属于概念解释和描述的难度等级。" + }, + { + "idx": 2300, + "question": "Briefly describe in which aspects the size effect of fiber-reinforced composites is manifested.", + "answer": "The fiber failure probability F(σ)=1-exp(-α lσ^β) and the average fiber strength σ̄=(αl)^(-1/β)𝒯(1+1/β) are both related to the fiber length l. The performance of fiber-reinforced composites is not only related to the fiber length but also to the fiber aspect ratio l/d, as well as the thickness of the composite plate. These are all manifestations of the size effect in composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述纤维增强复合材料尺寸效应的表现方面，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释纤维增强复合材料尺寸效应的表现方面，涉及纤维长度、长径比和复合材料板厚度等多个因素的综合分析。虽然包含基本概念，但需要将这些概念关联起来进行解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解纤维增强复合材料尺寸效应的基本概念，还需要掌握纤维失效概率和平均纤维强度的数学表达式，并能够从纤维长度、长径比以及复合材料板厚度等多个角度进行分析论述。这需要考生具备较强的综合分析能力和概念关联能力，属于多角度分析论述的难度等级。" + }, + { + "idx": 2301, + "question": "What is the role and mechanism of fiber reinforcement?", + "answer": "Fiber reinforcement: 1) Continuous fiber reinforcement can be explained by the rule of mixtures, where the load and modulus are primarily determined by the fibers. Since the strength and modulus of the fibers are much higher than those of the matrix and exceed the critical fiber volume fraction, they provide reinforcement, and the interfacial bonding should be moderate. 2) In short fiber and whisker reinforced composites, the fiber length should be greater than the critical length, or the aspect ratio should exceed the critical value. The fibers are the main contributors to strength and modulus, as their strength and modulus are much higher than those of the matrix, and the interfacial bonding should be moderate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维增强的作用和机制，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释纤维增强的作用和机理，涉及多种复合材料体系（连续纤维、短纤维和晶须增强）的强化机制分析，需要理解临界纤维体积分数、临界长度、长径比等概念及其相互关系，并进行综合推理和机理解释。这超出了简单记忆或基本应用层面，属于需要综合分析材料行为与机理的复杂问题。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求详细解释纤维增强的作用和机理，包括连续纤维增强和短纤维/晶须增强的不同机制。需要运用混合法则、临界纤维体积分数、临界长度等概念进行综合分析和解释，涉及多个知识点的综合运用和推理分析。虽然题目没有要求对复杂现象进行全面分析，但对机理的解释深度要求较高，因此属于等级4。" + }, + { + "idx": 2302, + "question": "What are the requirements for forming a composite, and can any two materials form a composite material after combination? What are the requirements for interfacial bonding strength?", + "answer": "To form a composite material, the two materials must establish a certain bonding strength at the interface. The interfacial bonding strength can generally be divided into physical bonding strength and chemical bonding strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释复合材料形成的条件以及界面结合强度的要求，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查复合材料形成的基本要求以及界面结合强度的基本概念，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释复合材料形成的基本要求以及界面结合强度的分类，涉及基础概念的记忆和简单分类，但不需要进行复杂的概念体系阐述或深入分析。这符合等级2对概念解释和描述的要求。" + }, + { + "idx": 2303, + "question": "Explain the significance of the critical volume fraction", + "answer": "The significance of the critical volume fraction: when the fiber volume fraction is greater than the critical volume fraction, the strength of the composite material is higher than that of the matrix. When the fiber volume fraction is less than the critical volume fraction, the strength of the composite material is lower than that of the matrix, and no reinforcement effect is achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释临界体积分数的意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对临界体积分数这一基本概念的理解和记忆，属于基础概念层次 | 难度: 在简答题题型中，该题目要求解释临界体积分数的意义，涉及概念解释和描述，但不需要复杂的体系阐述。题目要求对临界体积分数的作用进行说明，属于基础概念记忆层次，但需要一定的理解和表述能力，因此在简答题中属于中等难度。" + }, + { + "idx": 2304, + "question": "Compare the critical volume fractions of continuous fiber and short fiber reinforced composites", + "answer": "Continuous fiber: φ_Cr=(σ_mu−σ_m∗)/(σ_fu−σ_m), where σ_mu and σ_fu are the tensile strengths of the matrix and fiber, respectively; σ_m∗ is the stress borne by the matrix when the fiber reaches its fracture strain. Short fiber: φ_cr=(σ_mu−σ_m∗)/(σ_f−σ_m∗), where σ_f is the average stress of the fiber. Since σ_f is less than σ_fu, the critical volume fraction of short fibers is greater than that of continuous fibers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较连续纤维和短纤维增强复合材料的临界体积分数，并给出了详细的公式解释和论述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较连续纤维和短纤维增强复合材料的临界体积分数，涉及多个概念（如拉伸强度、基体应力等）的关联和综合分析，需要理解公式中各参数的含义并进行比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求比较连续纤维和短纤维增强复合材料的临界体积分数，不仅需要理解两种纤维增强机制的区别，还需要掌握相关的计算公式和参数含义。解题过程中需要分析两种情况下临界体积分数的差异及其原因，涉及多步计算和概念关联，综合分析要求较高。因此，在简答题题型中属于较高难度等级。" + }, + { + "idx": 2305, + "question": "Explain why in short-fiber composites with $LL_c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导随机取向短纤维复合材料中φ_min的关系表达式，涉及公式推导和计算步骤，答案给出了具体的数学表达式和条件说明，符合计算题的特征。 | 知识层次: 题目要求推导随机取向短纤维复合材料中φ_min的关系表达式，涉及多步计算和概念关联（如σ_Lu、σ_fu、σ_mu等参数的关联），需要综合分析材料的力学行为和纤维长度的影响（L>L_c条件）。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力来整合不同概念和公式。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料强度理论中的多个概念（临界纤维长度L_c、纤维体积分数φ_f、基体和纤维强度等），并正确关联这些概念进行多步推导。虽然不涉及复杂多变量计算，但要求对公式中各参数的物理意义有清晰认识，并能正确应用边界条件（L>L_c）。相比简单代入计算题（等级2）更具综合性，但尚未达到需要处理多个交互变量的复杂程度（等级4）。" + }, + { + "idx": 2312, + "question": "What are the requirements for compounding? Can any two materials form a composite material after compounding? What are the requirements for dissolution and wetting bonding?", + "answer": "For dissolution and wetting bonding, the matrix must wet the reinforcement, and mutual diffusion and dissolution should occur to form a bond. For reaction bonding, the matrix and reinforcement should react to form favorable interfacial products, whose thickness must be controlled below a critical value.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对复合材料的制备要求、溶解和润湿结合的条件进行文字解释和论述，答案也是以文字形式详细解释相关概念和条件，符合简答题的特征。 | 知识层次: 题目要求解释复合材料的复合要求、溶解和润湿结合的条件，涉及多个概念的关联和综合分析，需要理解基本原理并能够进行多步推理和解释，但不需要创新或深度设计优化。 | 难度: 在简答题题型中，该题目要求考生不仅理解复合材料的复合要求，还需要详细解释溶解和润湿结合的具体条件。这涉及到多个概念的关联和综合分析，如润湿性、扩散、溶解以及界面反应等。此外，题目还要求考生能够论述反应结合的条件和界面产物的控制，这需要多角度的分析和论述，超出了简单的概念解释或单一知识点的应用。因此，在简答题题型中，该题目属于较高难度等级。" + }, + { + "idx": 2313, + "question": "If unidirectional continuous fibers are unevenly distributed but all well-aligned in parallel, will it affect the elastic modulus? Please explain.", + "answer": "No effect. The modulus of the composite material $\\\\boldsymbol{E}_{\\\\mathrm{{L}}}=\\\\varphi_{\\\\mathrm{{f}}}\\\\boldsymbol{E}_{\\\\mathrm{{f}}}+\\\\varphi_{\\\\mathrm{{m}}}\\\\boldsymbol{E}_{\\\\mathrm{{m}}}$ varies linearly with the fiber volume percentage. Areas with dense fiber arrangement have a higher elastic modulus, while areas with sparse fiber arrangement have a lower elastic modulus. However, the linear relationship is additive, and the overall average modulus still equals the elastic modulus of a composite material with uniformly arranged fibers of the same volume fraction, meaning there is no effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释不均匀分布但平行排列的单向连续纤维是否会影响弹性模量，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解复合材料弹性模量的计算公式，并能够分析纤维分布不均匀但对齐情况下对整体弹性模量的影响。虽然涉及基本公式的应用，但需要一定的概念关联和综合分析能力，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解复合材料弹性模量的计算公式，并能解释不均匀分布但平行排列的纤维对整体弹性模量的影响。虽然题目涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析，主要考察对基本公式的理解和应用能力。" + }, + { + "idx": 2314, + "question": "In what aspects should matrix modification be considered to improve interface bonding?", + "answer": "Matrix modification", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在哪些方面应考虑基体改性以改善界面结合，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求从多个方面考虑基体改性以改善界面结合，这需要对材料科学中的界面相互作用、改性方法和性能优化有深入的理解和综合分析能力。回答此问题需要结合不同改性策略的机理和效果，进行推理和解释，属于复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对基体改性的多个方面进行全面分析，涉及界面结合的机理解释和综合运用知识的能力。需要深入理解材料科学中的界面现象，并能系统性地论述改性方法及其对界面性能的影响机制。这种要求超出了简单的知识点回忆或单一概念解释，属于该题型下最高难度的复杂现象全面分析层次。" + }, + { + "idx": 2315, + "question": "When unidirectional continuous composites are subjected to longitudinal stress and the fibers fracture, what length will the fibers break into, and analyze why this type of fracture occurs.", + "answer": "The fibers will break into short segments with lengths of $L_{\\\\mathrm{c}}$ or $2L_{\\\\mathrm{c}}$. According to the shear-lag theory analysis, when the short fiber length is $L_{\\\\mathrm{c}}$, the maximum normal stress in the fiber can reach the fiber fracture stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维断裂的长度和原因，答案提供了理论分析和文字解释，符合简答题的特征。 | 知识层次: 题目不仅要求解释纤维断裂的长度（涉及剪切滞后理论的应用），还需要分析这种断裂类型发生的原因，这需要对复合材料力学行为有深入的理解和综合分析能力。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求分析单向连续复合材料在纵向应力作用下纤维断裂的长度及其断裂机理，涉及剪切滞后理论（shear-lag theory）的综合运用和推理分析。学生需要深入理解纤维断裂的临界长度（Lc）概念，并能解释为什么纤维会断裂成特定长度（Lc或2Lc）。这种题目不仅考察学生对基础理论的掌握，还要求他们能够将理论应用于具体现象的解释，属于该题型内较高难度的题目。" + }, + { + "idx": 2316, + "question": "How to select reasonable composite processes and conditions for improving interface bonding?", + "answer": "Select reasonable composite processes and conditions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何选择合理的复合工艺和条件来改善界面结合，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求选择合理的复合工艺和条件来改善界面结合，这需要综合运用材料科学知识，包括对不同复合工艺的理解、界面结合机理的分析，以及工艺参数对界面性能的影响。这涉及到多因素的权衡和优化，属于复杂分析和推理的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求对复合材料界面结合的工艺和条件选择进行机理深度解释。需要综合运用材料科学、工艺学和界面科学的知识，分析不同工艺参数对界面性能的影响机制，并给出合理的工艺选择依据。这属于该题型中较高难度的要求，但尚未达到全面分析复杂现象的最高难度等级。" + }, + { + "idx": 2317, + "question": "Derive the relational expression for φ_min in continuous fiber reinforced composites", + "answer": "For continuous fiber reinforcement, from σ_Lu=σ_fuφ_f+σ_m*(1-φ_f)=σ_mu(1-φ_f), we can obtain φ_min=φ_f=(σ_mu-σ_m*)/(σ_fu+σ_mu-σ_m*)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导连续纤维增强复合材料中φ_min的关系表达式，答案涉及公式推导和数值计算，属于典型的计算题类型。 | 知识层次: 题目需要理解连续纤维增强复合材料的强度理论，并应用多个公式进行推导和计算。虽然不涉及复杂的综合分析或创新应用，但需要多步计算和概念关联，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解连续纤维增强复合材料的强度关系，并应用多个公式进行推导。解题步骤包括理解σ_Lu的表达式、推导φ_min的表达式，涉及多个变量的计算和概念关联，但不需要处理复杂多变量情况。" + }, + { + "idx": 2318, + "question": "What aspects should be considered for fiber surface modification to improve interfacial bonding?", + "answer": "Fiber surface modification", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述纤维表面改性应考虑的方面，答案需要文字描述而非选择、判断或计算 | 知识层次: 题目要求分析纤维表面改性的多个方面以改善界面结合，这需要综合运用材料科学、表面化学和力学等多学科知识，进行推理分析和机理解释。回答时需要深入理解界面相互作用机制，并能够关联不同改性方法的效果和原理，属于较高层次的认知要求。 | 难度: 在简答题（复杂分析类）中属于最高难度等级。该题目要求考生全面考虑纤维表面改性的多个方面（如化学处理、物理处理、环境因素等），并深入分析这些改性方法如何改善界面结合的机理。需要综合运用材料科学、表面化学和力学等多学科知识，进行系统性论述和推理分析，符合\"复杂现象全面分析\"的等级标准。" + }, + { + "idx": 2319, + "question": "In a Kevlar fiber-epoxy resin composite, the fiber volume fraction is 0.3, the density of epoxy resin is 1.25 g/cm³, and the density of Kevlar fiber is 1.44 g/cm³. Calculate the density of this composite material.", + "answer": "The density is ρ=1.31 g/cm³. Calculation process: ρ_L=1.25×0.7+1.44×0.3=1.3078 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，通过给定的纤维体积分数和密度数据计算复合材料的密度，答案也提供了具体的计算过程和结果。 | 知识层次: 题目仅涉及基本公式应用（混合法则）和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一复合密度公式（混合法则），无需任何变形或分步计算。题目中所有参数均已给出，仅需进行简单加权平均运算即可得出结果，属于典型的\"单一公式直接计算\"类型。" + }, + { + "idx": 2320, + "question": "Nickel is alloyed with Th having ${\\\\boldsymbol{w}}_{\\\\mathrm{Th}}$ of 0.01 to form an alloy, which is then made into powder, pressed into the desired shape, and sintered into the final product, during which Th is completely oxidized. Calculate the volume fraction of $\\\\mathrm{ThO}_{2}$ produced in this Th-Ni material. Given the density of $\\\\mathrm{ThO}_{2}$ is $9.86~\\\\mathrm{g/cm^{3}}$, Ni is $8.98~\\\\mathrm{g/cm}^{3}$, and Th is $11.72~\\\\mathrm{g/cm}^{3}$.", + "answer": "The volume fraction of $\\\\mathrm{ThO}_{2}$ is $0.0084 (0.84\\\\%)$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及密度、质量分数和体积分数的计算，最终需要得出具体的数值结果。答案也是一个具体的数值，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将质量分数转换为体积分数，并考虑氧化反应对材料组成的影响。虽然不涉及复杂的推理分析或机理解释，但需要综合运用密度计算和化学反应的知识。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及质量分数转换为摩尔数、氧化反应的计算、密度与体积的转换等多个步骤，但并未涉及复杂多变量或非常规公式的应用。" + }, + { + "idx": 2321, + "question": "In a Kevlar fiber-epoxy resin composite, the fiber volume fraction is 0.3, the elastic modulus of the epoxy resin is 31 GPa, and the elastic modulus of the Kevlar fiber is 124 GPa. Calculate the modulus parallel to the fiber direction.", + "answer": "The modulus in the fiber direction is 58.9 GPa. Calculation process: E_T=0.3×124+0.7×31=58.9 GPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和材料性能参数的代入计算。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需理解复合材料模量的混合法则并进行数值计算。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用简单的混合法则公式（E_T = V_f * E_f + V_m * E_m）进行直接计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 2323, + "question": "If manufacturing a continuous aluminum fiber cable with epoxy resin as the matrix and a volume fraction of 0.30, predict the electrical conductivity of the cable. The electrical conductivity of aluminum is $3.8\\\\times10^{7}~\\\\mathrm{S/m}$, and the electrical conductivity of epoxy resin is $10^{-11}~\\\\mathrm{S/m}$.", + "answer": "$1.14\\\\times10^{5}~\\\\mathrm{{S/m}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来预测电缆的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的体积分数和电导率数据，直接套用混合材料的电导率计算公式来求解。不需要多步计算或复杂的概念关联，思维过程较为直接。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用简单的混合规则公式（如并联模型）来计算复合材料的电导率，无需多个公式组合或复杂的推导步骤。计算过程直接且明确，属于基本公式应用和简单计算的范畴。" + }, + { + "idx": 2324, + "question": "Why are most covalent solids low-density materials?", + "answer": "Most covalent solids have low packing density because the interatomic bonds are constrained by bond saturation and directionality.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么大多数共价固体是低密度材料，需要文字解释和论述，答案提供了详细的解释说明原因，符合简答题的特征。 | 知识层次: 题目要求解释共价固体低密度的原因，涉及对共价键特性（如键饱和性和方向性）的理解及其对材料密度的影响机制的分析。这需要综合运用材料科学中的键合理论和晶体结构知识，进行推理和解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释共价固体的低密度特性，涉及键饱和性和方向性对堆积密度的影响，需要考生综合运用化学键理论和固体物理知识进行推理分析。虽然不涉及多因素交互作用的复杂现象全面分析（等级5），但对机理的解释深度已超出基础概念描述，属于该题型中较高难度的题目。" + }, + { + "idx": 2325, + "question": "According to solidification theory, how does adding a nucleating agent refine the grains of a casting?", + "answer": "After adding a nucleating agent, it can promote heterogeneous nucleation in the undercooled liquid. This not only increases the substrates required for heterogeneous nucleation but also reduces the critical nucleus radius, both of which will increase the number of nuclei, thereby refining the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释添加成核剂如何细化铸件晶粒，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释添加成核剂如何细化铸件晶粒的机理，涉及凝固理论中的异质成核、临界晶核半径等概念的关联和综合分析，需要深入理解并推理分析成核剂的作用机制。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解添加成核剂的基本作用，还需要深入解释其对晶粒细化的具体机理，包括促进异质形核、增加形核基底、减小临界晶核半径等多个方面。这需要考生具备扎实的理论基础和综合分析能力，能够将多个知识点有机结合起来进行解释。虽然题目没有要求对复杂现象进行全面分析，但对机理的解释深度要求较高，因此在简答题题型中属于等级4难度。" + }, + { + "idx": 2326, + "question": "In an aluminum specimen, the dislocation density within the grains was measured to be 2×10^12 m^−2. Assuming all dislocations are edge dislocations and are entirely concentrated at subgrain boundaries (i.e., low-angle grain boundaries), with their Burgers vector b=a/2⟨110⟩. If the cross-sections of the subgrain boundaries are all regular hexagons, and the tilt angle between subgrains is 2°, calculate the dislocation spacing at the subgrain boundary (given the lattice constant of aluminum a=0.404 nm).", + "answer": "The dislocation spacing D is calculated by the formula D = b / θ, where b is the Burgers vector and θ is the tilt angle. The Burgers vector b = (√2/2) × 0.404 nm = 0.286 nm. The tilt angle θ = 2° = 2 × (3.14/180) rad = 0.0349 rad. Therefore, D = 0.286 nm / 0.0349 = 8.188 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及具体的物理量（如Burgers vector、tilt angle）和数学运算（如角度转换、除法运算），最终得出一个具体的数值结果（dislocation spacing）。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错密度、Burgers向量、小角度晶界等概念，并应用公式进行数值计算。虽然计算过程相对直接，但需要综合多个知识点进行分析和计算。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如位错密度、伯格斯矢量、倾斜角等），进行多步计算（包括单位转换和公式应用），并综合分析几何关系（六边形截面假设）。虽然不涉及复杂多变量计算，但步骤较多且需要概念关联，因此在该题型内属于中等偏上难度。" + }, + { + "idx": 2329, + "question": "Why are metals high-density materials?", + "answer": "The bonding in metal crystals has neither directionality nor saturation requirements, so atoms are packed as closely as possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属为何是高密度材料，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查金属晶体结构的基本概念和键合特性的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释金属高密度的原因，涉及金属键的基本特性（无方向性和饱和性）及其对原子堆积方式的影响。虽然需要理解并表述相关概念，但不需要构建复杂的理论体系或进行多层次的逻辑推导，属于中等难度的概念解释题。" + }, + { + "idx": 2330, + "question": "Both silver and aluminum have face-centered cubic lattices, and their atomic radii are very close, $r_{\\\\text{Ag}}=0.288\\\\mathrm{~nm}$ $r_{\\\\text{Al}}=0.286\\\\mathrm{nm}$, but they cannot form infinite solid solutions in the solid state. Explain the reason. (Northwestern Polytechnical University postgraduate entrance exam question)", + "answer": "For substitutional solid solutions, the solute and solvent having the same crystal structure type and similar atomic radii are necessary conditions for forming infinite solid solutions. However, the $15\\\\%$ rule indicates that when $|\\\\delta|>15\\\\%$, the solid solubility (mole fraction) becomes very small, showing that when the size factor is within a favorable range for forming infinite solid solutions, its importance becomes secondary, meaning the extent of solid solubility depends on other factors. Here, the valence factor is crucial. Because the valence of $\\\\text{Ag}$ is 1, while that of Al is 3, i.e., the solid solubility of a high-valence element as a solute in a low-valence element is greater than that of a low-valence element in a high-valence element. Therefore, silver and aluminum cannot form infinite solid solutions in the solid state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释银和铝不能形成无限固溶体的原因，答案通过文字论述和解释给出了详细的理由，涉及晶体结构、原子半径、价电子因素等多方面的分析，符合简答题的特征。 | 知识层次: 题目不仅需要理解面心立方晶格和原子半径的概念，还需要分析固溶体形成的条件（如15%规则），并进一步结合价电子因素进行综合解释。这涉及到多个知识点的关联和深层次的机理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅掌握固溶体的基本形成条件（如晶体结构类型和原子半径相似性），还需要理解并应用15%规则和价电子因素来解释为什么银和铝不能形成无限固溶体。这需要考生具备综合运用材料科学知识的能力，能够将多个概念（如晶体结构、原子尺寸因素、价电子效应）结合起来进行推理分析，并给出合理的机理解释。虽然题目没有涉及过于复杂的计算或实验数据，但对理论知识的深度理解和应用要求较高，因此在简答题中属于较高难度等级。" + }, + { + "idx": 2331, + "question": "According to solidification theory, how does increasing the undercooling ΔT refine the grain size of castings?", + "answer": "Increase the undercooling ΔT. As ΔT increases, both N and Vs increase, but the growth rate of N is greater than that of Vs. Therefore, the value of N/Vs increases, meaning z increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释增加过冷度ΔT如何细化铸件晶粒尺寸，需要文字解释和论述，答案提供了详细的解释过程，符合简答题的特征。 | 知识层次: 题目要求解释增加过冷度ΔT如何细化铸件晶粒尺寸的机理，涉及凝固理论中的成核率N和生长速率Vs的变化及其相互关系，需要综合运用多个概念进行推理分析，思维过程较深。 | 难度: 在简答题题型中，该题目要求对凝固理论中的过冷度与晶粒尺寸关系进行机理深度解释。需要综合运用凝固动力学知识，分析形核率(N)与生长速度(Vs)的相对变化关系，并推导出z值的变化趋势。虽然不涉及多因素交互作用的复杂现象全面分析(等级5)，但已经超出了基础概念复述的范畴，属于需要深入理解并解释内在机理的题目。" + }, + { + "idx": 2332, + "question": "According to solidification theory, how does vibration crystallization refine the grain size of castings?", + "answer": "Vibration crystallization, on one hand, provides the energy required for nucleation, and on the other hand, can break the growing crystals to form more crystallization nuclei, thereby refining the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动结晶如何细化铸件晶粒，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及振动结晶对晶粒细化的机理解释，需要综合运用凝固理论和晶体生长原理进行分析和推理，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对振动结晶的机理进行深度解释，涉及成核能量和晶体破碎两个关键过程的综合论述。虽然不需要全面分析复杂现象（等级5），但需要运用固体凝固理论进行推理分析，属于机理深度解释的难度等级。" + }, + { + "idx": 2333, + "question": "Why are ionic solids medium-density materials?", + "answer": "The structural unit of an ionic crystal is an electrically neutral molecule composed of a set of positive and negative ions. The stacking of ions in ionic crystals must consider the role of electrical charge. In actual ionic crystals, the radii of positive and negative ions differ significantly. Generally, the negative ions are stacked in a cubic or hexagonal close-packed arrangement, while the smaller positive ions fill the gaps in this close-packed structure. This filling method of positive ions can uniformly separate the negative ions, increasing the distance between them so they no longer contact each other. Such a stacking structure can achieve higher packing density than covalently bonded crystals while satisfying the requirement of alternating arrangement of oppositely charged ions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么离子固体是中等密度材料，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释离子固体中等密度的原因，涉及离子晶体的结构单元、离子堆垛方式以及电荷作用等概念的综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和解释，思维过程有一定的深度要求。 | 难度: 在简答题题型中，该题目要求考生不仅理解离子晶体的基本结构特征，还需要综合分析离子半径差异对晶体堆积方式的影响，以及这种堆积方式如何导致中等密度的结果。题目涉及多步逻辑推理和概念关联，需要考生从多个角度（如离子半径、堆积方式、电荷平衡等）进行论述，属于该题型中较高难度的题目。" + }, + { + "idx": 2334, + "question": "What type of solid solution is formed when hydrogen atoms dissolve in aluminum?", + "answer": "The crystal structure of aluminum is fcc. From the appendix, the radius of the hydrogen atom is found to be rH=0.046nm, and the radius of the aluminum atom is rAl=0.143nm. The radius ratio rH/rAl=0.046/0.143=0.32.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释氢原子溶解在铝中形成的固溶体类型，答案通过文字解释和计算过程来论述，属于需要文字解释的简答题类型。 | 知识层次: 题目需要理解固溶体的分类标准，并应用原子半径比的计算来判断固溶体类型。这涉及多步计算和概念关联，但不需要复杂的推理或综合分析。 | 难度: 在简答题中属于中等难度，需要理解固溶体的基本概念，掌握原子半径的计算方法，并能将计算结果与固溶体类型进行关联分析。题目要求考生进行多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2335, + "question": "Given that the recrystallization activation energy of a Cu-Zn alloy (w_Zn=0.30) is 250 kJ/mol, and this alloy takes 1 hour to complete recrystallization at a constant temperature of 400°C, how many hours does it take for this alloy to complete recrystallization at a constant temperature of 390°C? (Shanghai Jiao Tong University postgraduate entrance exam question)", + "answer": "Given T_1=400°C=673 K, t_1=1 h, T_2=390°C=663 K, Q=2.5×10^5 J/mol. Let the time required to complete recrystallization at 390°C be t_2, then from A e^(-Q/(R T_1 )) t_1=A e^(-Q/(R T_2 )) t_2, we get t_1/t_2=e^[-Q/R (1/T_2 -1/T_1 )]=e^[-2.5×10^5/8.31×(1/663-1/673)]=0.509. Therefore, t_2=1.96 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及激活能、温度和时间的关系，最终需要计算出具体的时间数值。答案也展示了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解再结晶激活能的概念，并运用阿伦尼乌斯方程进行温度和时间关系的推导。虽然计算过程较为直接，但需要综合运用多个知识点，包括单位转换、对数运算和指数函数的应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、指数运算和比例关系推导。虽然计算过程明确，但需要综合理解再结晶动力学概念并正确应用公式，属于中等偏上的难度。" + }, + { + "idx": 2336, + "question": "Assuming the lattice constant of the alloy solid solution changes linearly with the increase of Zn atoms, and given the atomic radii of Cu and Zn are r_Cu=0.128nm and r_Zn=0.133nm respectively, find the average atomic radius r of the alloy with x_Zn=3%.", + "answer": "The average atomic radius r is r = r_Cu + (r_Zn - r_Cu) × 3% = 0.128 + (0.133 - 0.128) × 0.03 nm = 0.1282 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和原子半径数据来求解合金的平均原子半径。答案是通过具体的计算步骤得出的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，只需要根据给定的原子半径和百分比进行线性插值计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一线性公式进行计算，无需任何变形或组合步骤。题目明确给出所有参数和计算路径，仅需执行基础算术运算即可得到答案。" + }, + { + "idx": 2337, + "question": "Given the diffusion constant of carbon in γ-Fe, D₀ = 2.0 × 10⁻⁵ m²·s⁻¹, and the activation energy for diffusion, Q = 1.4 × 10⁵ J/mol (R = 8.31 J/(mol·K)). Under the condition of a carbon potential Cₚ = 1.1% C, carburization of 20# steel is performed at 880°C. To achieve the same effect as carburizing at 927°C for 5 hours, how long should the carburization time be? (Huazhong University of Science and Technology postgraduate entrance exam question)", + "answer": "T₁ = 927°C = 1200 K. From D = D₀ exp(−Q/RT), we have D₁ = D₁₂₀₀ = 2.0 × 10⁻⁵ exp(−1.4 × 10⁵ / (8.31 × 1200)) = 1.6 × 10⁻¹¹ m²·s⁻¹. T₂ = 880°C = 1153 K. D₂ = D₁₁₅₃ = 2.0 × 10⁻⁵ exp(−1.4 × 10⁵ / (8.31 × 1153)) = 0.902 × 10⁻¹¹ m²·s⁻¹. Therefore, tₓ = (1.6 × 10⁻¹¹ × 5) / (0.902 × 10⁻¹¹) = 9 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散常数的计算和时间的调整，最终需要得出具体的时间数值。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和温度对扩散系数的影响，进行综合分析。虽然不涉及复杂的推理分析或机理解释，但需要理解扩散过程的基本原理，并进行数值计算和比较。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散公式进行多步计算，涉及温度转换、扩散系数计算以及时间换算。虽然计算步骤较多，但每一步都有明确的公式指导，且不需要处理复杂的多变量关系。" + }, + { + "idx": 2338, + "question": "Calculate the packing density of a crystal structure with a coordination number of 6 for a monoatomic substance", + "answer": "When the coordination number of a monoatomic substance is 6, it forms a simple cubic structure, where the atomic radius r1=a1×7. The packing density η=(1×(4/3)πr3)/a3=(4πa3)/(3×8×a3)=0.523", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算堆积密度），答案中包含了具体的计算公式和数值运算过程，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的协调数和晶体结构类型直接套用公式计算堆积密度，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需要应用简单立方结构的堆积密度公式，计算步骤直接且无需组合多个公式或进行复杂推导。" + }, + { + "idx": 2339, + "question": "Where should hydrogen atoms be located in the aluminum lattice? Why?", + "answer": "The octahedral interstice is larger than the tetrahedral interstice, so hydrogen atoms reside in the octahedral interstice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释氢原子在铝晶格中的位置及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解氢原子在铝晶格中的位置（基础概念），还需要解释为什么选择八面体间隙而不是四面体间隙（涉及间隙大小的比较和原子尺寸的考量），这属于多步概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解铝晶格中四面体和八面体间隙的概念，并能通过比较间隙大小来解释氢原子的位置选择。虽然涉及多步分析和概念关联，但不需要进行复杂的多角度或深度关联性分析。" + }, + { + "idx": 2340, + "question": "Calculate the ratio of the atomic radius when the coordination number of the elemental atom is 6 to that when the coordination number is 12.", + "answer": "Since the molar volumes are equal for coordination numbers 6 and 12, according to the packing density relation: η12Vmol=(4NAπr123)/3, η6Vmol=(4NAπr63)/3. Dividing the two equations gives: r6/r12=(η6/η12)1/3=(0.52/0.74)1/3=0.89", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，并应用了公式来求解原子半径的比率。答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及不同配位数下的原子半径比的计算，需要理解配位数与堆积效率的关系，并应用相关公式进行推导和计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用配位数与原子半径的关系，进行多步计算和公式推导。虽然不涉及复杂多变量计算，但需要综合分析概念和数值计算步骤，属于中等偏上的难度。" + }, + { + "idx": 2341, + "question": "The measured lattice constant a=0.3795nm and density of 14.213g/cm^3 for the Cu-40%Au solid solution. Calculate and explain what type of solid solution this alloy is. The relative atomic mass of Au is found to be 196.97 from the appendix.", + "answer": "The average weight per atom A in the Cu-40%Au solid solution is (63.55×0.6+196.97×0.4)/(6.0238×10^23)g=1.941×10^-22g. The number of atoms per unit cell n is calculated as a^3×ρ/A=(0.3795×10^-7)^3×14.213/1.941×10^-22=4.002. Both Cu and Au have a face-centered cubic structure, with 4 atoms per unit cell. The calculation yields 4.002 atoms per unit cell, where the decimal is due to calculation and measurement errors, thus this is a substitutional solid solution.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（如计算平均原子重量、单位晶胞中的原子数等）并应用公式来解决问题，最终得出合金类型的结论。答案中包含详细的数学计算过程和解释，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括原子质量加权平均、单位晶胞原子数计算等），并需要结合晶体结构知识（面心立方结构）进行综合分析。虽然不涉及复杂的机理或创新设计，但需要一定的概念关联和误差分析能力。 | 难度: 在计算题中属于综合性计算问题。题目要求进行多步计算（包括平均原子质量计算、单位晶胞原子数计算），需要正确应用密度公式和晶体结构知识，同时需要理解并关联固溶体类型的概念。虽然计算步骤明确，但涉及单位转换和误差分析，对综合能力要求较高，符合等级3的\"综合性计算问题\"特征。" + }, + { + "idx": 2342, + "question": "The density of copper is 8.96g/cm^3, calculate the lattice constant and atomic radius of copper. The relative atomic mass of copper is found to be 63.55 from the appendix, and the Avogadro constant is 6.0238×10^23.", + "answer": "The mass of each Cu atom is A_Cu=63.55/(6.0238×10^23)g=10.55×10^-23g. Cu has an fcc structure, with each unit cell containing 4 atoms. Let the lattice constant of the unit cell be a, the mass of one unit cell is the mass of 4 Cu atoms, so a^3×ρ=4×A_Cu, i.e., a=(4×A_Cu/ρ)^1/3=(4×10.55×10^-23/8.96)^1/3cm=0.3611×10^-7cm=0.3611nm. The relationship between the atomic radius r and the lattice constant a in an fcc structure is r=a×√2/4, so the atomic radius of Cu is r_Cu=0.3611×√2/4nm=0.1277nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜的晶格常数和原子半径，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量计算、晶格常数计算和原子半径计算，并且需要理解面心立方结构（fcc）的基本原理和公式应用。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要掌握密度、晶格常数、原子半径之间的关系，并应用fcc结构的相关知识进行多步计算。题目涉及多个概念的综合运用和较为复杂的计算过程，但并未达到复杂多变量计算的程度。" + }, + { + "idx": 2343, + "question": "Given that the alloy is a face-centered cubic solid solution with an average atomic radius r=0.1282nm, find the average lattice constant a", + "answer": "The average lattice constant a is a = 4r / √2 = 4 × 0.1282 / √2 nm = 0.3625 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（4r / √2）来求解平均晶格常数a，答案是一个具体的数值结果（0.3625 nm），符合计算题的特征。 | 知识层次: 题目考查基本公式的直接应用（面心立方晶格常数与原子半径的关系公式），仅需简单计算即可得出结果，无需多步推理或综合分析 | 难度: 在计算题中属于最简单难度等级，仅需直接套用单一公式（a = 4r / √2）进行一步计算，无需任何公式组合或复杂推导过程，完全符合等级1\"单一公式直接计算\"的标准特征。" + }, + { + "idx": 2344, + "question": "Given the relative atomic masses of Cu and Zn are 63.55 and 65.38 respectively, the Avogadro constant is 6.0238×10^23, and x_Zn=3%, find the average mass of component atoms A in the alloy solid solution.", + "answer": "The average mass of component atoms A is A = (63.55 × 0.97 + 65.38 × 0.03) / (6.0238 × 10^23) g = 10.56 × 10^-23 g", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以求得合金固溶体中组分原子的平均质量。答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的原子质量和百分比计算合金中组元原子的平均质量。虽然需要理解相对原子质量和阿伏伽德罗常数的概念，但整体上是一个直接的数值计算过程，不需要多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，只需要单一公式（加权平均）的直接计算，解题步骤简单明了，无需复杂推导或组合多个公式。题目直接给出了所有必要参数，仅需套用公式即可得出结果。" + }, + { + "idx": 2345, + "question": "Given the lattice constant a=0.3625nm of a face-centered cubic solid solution and the average atomic mass A=10.56×10^-23g of the component atoms, calculate the theoretical density ρ of the alloy.", + "answer": "The theoretical density ρ is ρ = 4A / a^3 = 4 × 10.56 × 10^-23 / (0.3625 × 10^-7)^3 g·cm^-3 = 8.87 g·cm^-3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的晶格常数和平均原子质量，应用公式计算合金的理论密度，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及面心立方晶体的理论密度计算，需要直接套用公式ρ = 4A / a^3进行计算，无需多步推理或综合分析。 | 难度: 在计算题-简单应用类别中，该题目仅需直接套用单一公式（ρ = 4A / a^3）进行数值计算，无需公式推导或多步骤转换。所有参数均已明确给出，计算过程仅涉及基本单位换算（nm→cm），属于该题型框架内最基础的难度等级。" + }, + { + "idx": 2346, + "question": "Based on the above calculation results, explain the relationship between the atomic radius and volume change when pure iron transforms from bcc to fcc structure at 17°C.", + "answer": "From the calculated results above, it can be seen that if the atomic radius remains unchanged before and after the transformation, the volume change after the transformation would be very large, which is inconsistent with the actual measured results and also contradicts the nature of metallic bonds. Therefore, for the same metal, the atomic radius of different structures should change to minimize the volume change as much as possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于计算结果解释原子半径与体积变化之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释原子半径与体积变化之间的关系，涉及晶体结构转变过程中的原子半径变化和体积变化的综合分析。需要理解金属键的性质、晶体结构的特点，并进行推理分析，以解释实际观察到的现象与理论计算之间的差异。这属于较高层次的认知能力，需要综合运用多个概念并进行深入分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求基于计算结果分析原子半径与体积变化的关系，并解释为什么原子半径需要变化以最小化体积变化。这需要综合运用晶体结构、金属键性质和相变知识，进行推理分析并给出合理的机理解释。虽然题目提供了部分计算背景，但需要学生深入理解并解释现象背后的物理机制，属于较高层次的综合分析和解释能力要求。" + }, + { + "idx": 2347, + "question": "Pure iron transforms from bcc structure to fcc structure at 17°C, with a volume reduction of 1.06%. Calculate the relative change in atomic radius.", + "answer": "The relative change in atomic radius is (r_f - r_b)/r_b = 1 - 1/0.9758 = -2.47%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解原子半径的相对变化，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用晶体结构转变的知识，进行多步计算（体积变化与原子半径的关系），并需要理解bcc和fcc结构的几何关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解bcc和fcc晶体结构的几何关系，应用体积变化公式推导原子半径变化，并进行多步计算。虽然不涉及复杂变量，但需要将晶体结构知识与数学计算紧密结合，属于中等偏上的综合计算难度。" + }, + { + "idx": 2348, + "question": "Assuming the atomic radius remains unchanged before and after the transformation, calculate the volume change of pure iron when it transforms from bcc to fcc structure at 17°C.", + "answer": "Assuming the atomic radius remains unchanged before and after the transformation, the volume change after the transformation is (a_f^3 - 2a_b^3)/(2a_b^3) = ((4r_f/√2)^3 - 2(4r_b/√3)^3)/(2(4r_b/√3)^3) = ((4/√2)^3 - 2(4/√3)^3)/(2(4/√3)^3) = -8.196%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算纯铁从bcc到fcc结构的体积变化），答案给出了具体的计算过程和数值结果（-8.196%），需要使用晶体结构参数和数学公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及bcc和fcc结构的晶格常数与原子半径的关系，以及体积变化的计算。虽然不需要复杂的推理分析，但需要综合应用多个概念和公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解bcc和fcc晶体结构的关系，掌握晶格常数与原子半径的换算公式，并进行多步计算。虽然题目给出了原子半径不变的简化条件，但仍需要正确应用几何关系建立体积变化公式，并完成精确的数值计算。这比简单的单步计算题（等级2）更复杂，但尚未达到需要处理多变量或非线性关系的等级4难度。" + }, + { + "idx": 2349, + "question": "Calculate the theoretical density of CsCl", + "answer": "The experimentally measured density is 3.99 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算CsCl的理论密度，需要使用公式和数值计算，答案给出了具体的数值结果。 | 知识层次: 题目要求计算CsCl的理论密度，这涉及基本公式的应用和简单计算，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用晶体密度计算公式（ρ=Z×M/(a³×N_A)），其中晶胞参数a可通过离子半径求和获得，且CsCl结构Z=1。计算过程不涉及公式组合或复杂推导，属于单一公式直接计算类型。" + }, + { + "idx": 2350, + "question": "Pure iron transforms from bcc structure to fcc structure at 17°C, with a volume reduction of 1.06%. Calculate the atomic radius of the bcc structure based on the atomic radius of the fcc structure.", + "answer": "Let the lattice constant of the bcc structure be a_b, and the lattice constant of the fcc structure be a_f. When transforming from bcc to fcc, the volume reduces by 1.06%: since each bcc unit cell contains 2 atoms, and the fcc unit cell contains 4 atoms, 2 bcc unit cells transform into 1 fcc unit cell. Therefore, (a_f^3 - 2a_b^3)/(2a_b^3) = -1.06/100, solving for a_f = (2×(100 - 1.06)/100)^(1/3)×a_b = 1.255a_b. The atomic radius of the bcc structure r_b = √3a_b/4, and the atomic radius of the fcc structure r_f = √2a_f/4. Substituting a_f = 1.255a_b, we get r_b = (√3a_b)/4 = (√3a_f)/(4×1.255) = (√3×4r_f)/(4×1.255×√2) = 0.9758r_f.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解bcc结构的原子半径，解答过程中涉及到了体积变化、晶格常数转换和原子半径的计算，这些都是典型的计算题特征。 | 知识层次: 题目需要进行多步计算，涉及bcc和fcc晶体结构的转换关系、体积变化计算以及原子半径的推导。虽然不涉及复杂的机理分析或创新设计，但需要综合运用晶体结构知识和数学计算能力，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构转变的概念，进行多步计算和公式应用，涉及体积变化、晶格常数转换和原子半径计算等多个步骤，但未达到复杂多变量计算的级别。" + }, + { + "idx": 2351, + "question": "Iron carbide Fe3C is an orthorhombic intermetallic compound with lattice constants of a=0.4514nm, b=0.5080nm, c=0.6734nm, and a density of 7.65g/cm³. Determine the number of iron and carbon atoms in the unit cell.", + "answer": "From the appendix, the atomic masses of Fe and C are found to be 55.85g/mol and 12g/mol, respectively. The mass of each Fe and C atom is A_Fe = [55.85/(6.023×10^23)]g = 9.273×10^-23g, A_C = [12/(6.023×10^23)]g = 1.992×10^-23g. The atomic ratio of Fe to C is 3:1. Assuming there are n C atoms in the unit cell, there should be 3n Fe atoms. The density of Fe3C is ρ_Fe3C = (n × A_Fe + 3n × A_C) / V_unit cell. Therefore, 7.65 = [(9.273 × 3n + 1.992n) × 10^-23] / [0.4514 × 10^-7 × 0.5080 × 10^-7 × 0.6734 × 10^-7] = [29.811 × 10^-23 × n] / [1.544 × 10^-22]. Solving for n gives n = [7.65 × 1.544 × 10^-22] / [29.811 × 10^-23] = 3.97. Thus, there are 4 C atoms and 3 × 4 = 12 Fe atoms in the unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞中的铁和碳原子数量，解答过程中涉及密度、晶格常数和原子质量的计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括原子质量计算、密度公式应用、单位换算和数值求解，同时需要理解晶胞结构和原子比例的概念。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行计算和推理。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算单位晶胞中的铁和碳原子数量，涉及密度、晶格常数、原子质量等多个参数的关联计算，解题步骤较为复杂，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2352, + "question": "Predict the crystal structure of CsCl", + "answer": "From the appendix, the electronegativities of Cs and Cl are found to be 0.82 and 3.16, respectively: the ionic radii are r(Cs+)=0.165 nm, r(Cl-)=0.181 nm. The electronegativity difference ΔEN=3.16-0.82=2.34, the ionic bond character is 75%, the covalent character is 25%, primarily ionic bonding. The ratio of anion radius to cation radius r(Cs+)/r(Cl-)=0.165/0.181=0.912. From the data given in Table 3-5 in the text, the cation should occupy the interstitial site at the center of a cube formed by the anions, corresponding to CN(Cl-)=8; the ratio of the number of anions to cations is 1:1, so CN(Cs+)=8. This crystal structure should be a simple cubic structure, with Cl- at the cube corners and Cs+ at the cube center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过分析和解释来预测CsCl的晶体结构，答案提供了详细的论述和计算过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要应用离子半径比和电负性差等基本概念，通过查表和计算确定晶体结构，涉及多步推理和综合分析，但不需要复杂的机理解释或创新设计。 | 难度: 在简答题中属于中等难度，需要理解多个概念（如电负性、离子半径、配位数等）并进行综合分析。题目要求通过计算离子半径比和电负性差，结合表格数据推断晶体结构，涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2353, + "question": "Brass $(77,77)$ has a B2 structure, with a $z_{17}$ to $C11$ atomic ratio of 46:54. At $450-20=20$, if $900\\\\div\\\\cdots$ of the ($112$ 1/2, 1/2) positions are occupied by copper atoms, what percentage of the $(0,0,0)$ positions are occupied by copper atoms?", + "answer": "The stoichiometric composition of $C112.77$ is $5(\\\\angle17)=500^{\\\\circ}$. In the stoichiometric alloy, the ($112$, $117$, $112$) positions are entirely occupied by copper atoms, and the $(0,0,0)$ positions are entirely occupied by zinc atoms. Currently, the ratio of $217$ to $Cu$ atoms is $46:54$, and at $450-40$, $90\\\\%$ of the ($112$, 1/2, 1/2) positions are occupied by copper atoms. Thus, in the alloy, $\\\\sum11$ atoms have $0.5\\\\times0.0=4500$ located at the (1/2, 1/2, 1/2) positions. The remaining $0.54-0.45=0.00$ are located at the (0, 0, 0) positions, meaning $0.09/0.5=180\\\\dot{0}$ of the (0, 0, 0) positions are occupied by $c_{11}$ atoms. This can also be verified in the opposite direction. From the calculation results above, it shows that in the alloy, $z u$ atoms have $0.5-0.45=500$ located at the ($112$ 1/2, 1/2) positions and $0.5\\\\times(1-1).18)=410.0$ located at the (0, 0, 0) positions. Therefore, the content of $z_{1}$ in the alloy should be $0.41+0.05=4600$, which matches the given alloy composition.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目涉及复杂的数值计算和公式应用，需要根据给定的原子比例和位置占有率进行一系列数学运算来得出最终百分比结果。答案中展示了详细的计算步骤和验证过程，符合计算题的特征。 | 知识层次: 题目涉及复杂的晶体结构分析、原子位置占据率的计算、合金成分的推导，需要综合运用材料科学中的晶体学知识、化学计量学计算以及多步骤的逻辑推理。解题过程不仅需要理解B2结构的基本概念，还需要进行多步数值计算和综合分析，属于较高层次的认知要求。 | 难度: 在计算题-复杂分析题型中，该题目属于高难度综合计算等级。题目涉及复杂的晶体结构分析、原子位置占据率的计算、以及合金成分的推理验证。解题步骤需要综合运用材料科学、晶体学和数学计算知识，包括理解B2结构、原子位置比例计算、温度影响分析等多个复杂环节。同时，题目还要求反向验证计算结果，进一步增加了综合分析的难度。这种需要多步骤推理和综合知识应用的题目在该题型内属于最高难度级别。" + }, + { + "idx": 2354, + "question": "(2) Calculate the theoretical density of CsCl.", + "answer": "First, calculate the lattice constant from the ionic radii. Since the crystal structure is simple cubic, the diagonal length of the cube should be the sum of the diameters of the negative and positive ions, i.e., equal to $2(0.181+0.165)\\\\mathrm{nm}=0.692$ nm. The diagonal length equals $\\\\sqrt{3}a$, so $a=0.692/\\\\sqrt{3}=0.3995$ nm. From the appendix, the relative atomic masses of Cl and Cs are $35.45$ and $132.91$, respectively. The mass of each Cl and Cs atom is $35.45/6.023\\\\times10^{23}=5.885\\\\times10^{-23}$ g and $132.91/6.023\\\\times10^{23}=2.207\\\\times10^{-22}$ g. A unit cell contains one Cl ion and one Cs ion, so the theoretical density of CsCl is $\\\\rho_{\\\\text{(CsCl)}}=\\\\frac{5.885\\\\times10^{-23}+2.207\\\\times10^{-22}}{(0.3995\\\\times10^{-7})^{3}}\\\\text{g/cm}^{3}=4.38\\\\text{g/cm}^{3}$. The calculated theoretical density is slightly higher than the experimentally measured density, possibly because the estimated lattice constant is smaller than the actual value.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解CsCl的理论密度，解答过程中涉及了多个计算步骤和公式应用，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括从离子半径计算晶格常数、利用相对原子质量计算单个原子的质量、最后计算理论密度。虽然每一步都是基本的公式应用，但需要将这些步骤综合起来才能得到最终结果。此外，题目还涉及对计算结果与实验值差异的简单解释，显示出一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算CsCl的理论密度，涉及晶格常数的计算、原子质量的转换、单位体积内原子数的确定等多个步骤。虽然计算过程较为复杂，但每一步都有明确的公式和逻辑关系，属于中等应用层次的计算题。" + }, + { + "idx": 2355, + "question": "Calculate the packing density of the CsCl crystal structure (assuming ions are in contact along the body diagonal).", + "answer": "The CsCl crystal has a simple cubic structure. The radii of the Cs⁺ and Cl⁻ ions are r_Cs⁺ = 0.165 nm and r_Cl⁻ = 0.181 nm, respectively. Assuming the ions are in contact along the body diagonal, the diagonal length d = 2(r_Cs⁺ + r_Cl⁻) = 2(0.165 + 0.181) nm = 0.692 nm. The lattice constant a = d/√3 = 0.692 nm/√3 = 0.3995 nm. A unit cell contains one Cs⁺ ion and one Cl⁻ ion, so the packing density η_CsCl of the CsCl crystal structure is η_CsCl = [4π(r_Cs⁺³ + r_Cl⁻³)/3] / a³ = [4π(0.165³ + 0.181³)] / (3 × 0.3995³) = 0.685.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶体结构的密度计算，需要具体步骤和数值结果。 | 知识层次: 题目需要多步计算（包括离子半径求和、体对角线计算、晶格常数推导、堆积密度公式应用），并需要理解CsCl晶体结构特征和离子接触条件，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶体结构、离子半径、几何关系等概念，并进行多步计算（包括对角线长度计算、晶格常数推导、体积计算和最终密度计算）。虽然计算步骤较多，但每一步都有明确的公式和逻辑关系，属于中等应用层次的计算题。" + }, + { + "idx": 2356, + "question": "Why do commercial oxides such as windows and beverage glass require the addition of CaO to SiO2?", + "answer": "CaO cannot form a network in glass. Calcium ions have only one functionality, and Ca2+ has only two functionalities. When they are added to the SiO2 network and connected with oxygen ions, they inevitably break a primary bond of the network, reducing the density of primary bonds in the network and thereby lowering the glass transition temperature. For general wide-mouth bottles and window glass, which are used at low temperatures, they do not require an excessively high glass transition temperature Tg. A low Tg makes the product easier to handle and reduces costs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么商业氧化物如窗户和饮料玻璃需要添加CaO到SiO2中，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释CaO在商业氧化物玻璃中的作用机制，涉及网络形成体与非网络形成体的概念、离子功能性的理解、玻璃结构变化对玻璃转变温度的影响等多方面的综合分析。需要深入理解玻璃结构化学原理，并能将这些原理与实际应用（如降低Tg以降低成本）联系起来，属于复杂分析和机理解释的范畴。 | 难度: 在简答题的复杂分析题型中，该题目要求对CaO在SiO2网络中的作用机理进行深度解释，涉及网络结构、离子功能性和玻璃转变温度的关系。虽然不需要全面分析复杂现象，但需要综合运用材料科学知识进行推理和解释，属于机理深度解释的难度等级。" + }, + { + "idx": 2357, + "question": "Is the glass transition temperature of ordinary window glass above or below room temperature?", + "answer": "The glass transition temperature of ordinary window glass should be above room temperature. If it were below room temperature, the glass would remain in a liquid state at room temperature, albeit with high viscosity and some fluidity, meaning the atoms would still be delocalized. Consequently, it could not maintain a fixed shape at room temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（玻璃转变温度是否高于室温），答案给出了明确的判断和解释，符合判断题的特征 | 知识层次: 题目考查对玻璃转变温度这一基本概念的记忆和理解，以及其在室温下的状态判断，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆玻璃转变温度的基本定义及其与室温的关系即可作答，无需深入理解或复杂分析。" + }, + { + "idx": 2358, + "question": "What is the role of SiO2 in commercial oxide glasses?", + "answer": "SiO2 oxide satisfies Zachariasen's rules and can form a large-scale three-dimensional glass network, acting as the network former in glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释SiO2在商业氧化物玻璃中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对SiO2在商业氧化物玻璃中作用的基本概念记忆和理解，涉及Zachariasen规则和网络形成体的基本知识，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释SiO2在商业氧化物玻璃中的作用，涉及对Zachariasen规则和网络形成体概念的理解和描述，但不需要复杂的体系阐述或多层次分析。属于基础概念记忆层次中的中等难度。" + }, + { + "idx": 2359, + "question": "What is the relationship between functionality and the structural morphology of polymers?", + "answer": "If the functionality of a polymer monomer equals 2, the monomer can only form long molecular chains without branches, resulting in a linear structure. If the functionality equals 3 or is greater than 3, during polymerization, one functionality of a trifunctional monomer provides covalent cross-linking with another molecular chain, forming a network, which is a three-dimensional structure. Such a polymer is essentially a single molecule with an extremely large molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物功能性与结构形态之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释聚合物功能性与结构形态之间的关系，涉及功能性的定义（基础概念）以及其对聚合物链结构的影响（线性与三维网络结构的形成）。这需要理解功能性的概念并将其应用于解释不同结构形态的形成过程，属于概念关联和综合分析的中等应用层次。 | 难度: 在简答题中，该题目要求考生不仅理解聚合物功能性与结构形态的基本概念，还需要能够关联不同功能性的单体在聚合过程中形成的不同结构（线性与三维网络）。此外，题目要求考生能够解释功能性与结构形态之间的因果关系，并进行多步分析（如从功能性推导出可能的聚合结构）。虽然题目不涉及复杂的计算，但需要综合分析和论述，属于中等偏上的难度。" + }, + { + "idx": 2360, + "question": "Why are the atomic masses of Si and Al very close (28.09 and 26.98, respectively), while the densities of SiO2 and Al2O3 differ significantly (2.55 g/cm³ and 3.95 g/cm³, respectively)? Explain this difference using crystal structure and Pauling's rules.", + "answer": "The ionic radii of silicon, aluminum, and oxygen are r_Si4+=0.039 nm, r_Al3+=0.057 nm, and r_O2-=0.132 nm, respectively. The radius ratio of silicon to oxygen is 0.295, and that of aluminum to oxygen is 0.431. Therefore, silicon ions occupy the tetrahedral interstices of oxygen ions, while aluminum ions occupy the octahedral interstices of oxygen ions. Si is located at the center of an oxygen-coordinated tetrahedron with a coordination number (CN) of 4. Si is tetravalent, so the electrostatic bond strength S=4/4=1. O2- is divalent, i.e., Z-=2. According to Pauling's second rule, since Z-=∑S_i=2, the summation index i is 2, meaning each O2- at the tetrahedron vertex is shared by two tetrahedra. Thus, silicon-oxygen tetrahedra share all vertices, forming a three-dimensional framework structure of silicates. Because one oxygen ion is connected to only two silicon ions, such a low coordination number prevents SiO2 from achieving close packing, resulting in a generally open silicate structure. Al is located at the center of an oxygen-coordinated octahedron with a coordination number (CN) of 6. Al is trivalent, so the electrostatic bond strength S=3/6=0.5. O2- is divalent, i.e., Z-=2. According to Pauling's second rule, since Z-=∑S_i=2, the summation index i is 4, meaning each O2- at the octahedron vertex is shared by four octahedra. Because one oxygen ion is connected to four aluminum ions, close packing is possible. Oxygen ions are arranged in a hexagonal close-packed structure, with aluminum ions occupying the octahedral interstices. Since the number of atoms and octahedral interstices in a hexagonal close-packed structure are equal, 1/3 of the octahedral interstices remain unfilled. Because SiO2 has a relatively open structure and Al2O3 has a relatively close-packed structure, despite the very similar atomic masses of Si and Al, the densities of SiO2 and Al2O3 differ significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释原子质量相近但密度差异显著的原因，并运用晶体结构和鲍林规则进行详细论述。答案提供了详细的文字解释和理论分析，符合简答题的特征。 | 知识层次: 题目要求解释Si和Al原子质量相近但SiO2和Al2O3密度差异显著的原因，涉及晶体结构和Pauling规则的综合运用。需要分析离子半径比、配位数、静电键强度等概念，并关联到晶体结构的紧密程度，属于复杂分析和机理解释的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体结构和鲍林规则进行深度机理解释。需要考生掌握离子半径比、配位数、静电键强度等概念，并能将这些概念有机结合，解释密度差异的根本原因。解题步骤涉及多个知识点的串联和复杂推理，属于该题型下最高难度的题目类型。" + }, + { + "idx": 2361, + "question": "How to compare the density difference between SiO2 and Al2O3 by calculating the packing density?", + "answer": "The relative atomic mass of SiO2 is 16. For SiO2, the mass of each SiO2 molecule is A_SiO2=(28.09+2×16)/(6.023×10^23) g=9.977×10^-23 g. The number of SiO2 molecules per cm³ is n_SiO2=ρ_SiO2/A_SiO2=2.55/9.977×10^-23=2.556×10^22 per cm³. The number of Si4+ and O2- ions per cm³ are n_Si4+=2.556×10^22 per cm³ and n_O2-=5.112×10^22 per cm³, respectively. The packing density of SiO2 is η_SiO2=(n_Si4+×4πr_Si4+^3/3 + n_O2-×4πr_O2-^3/3)/1=(4π/3)(2.556×0.039^3 + 5.112×0.132^3)×10^22×10^-21=0.577. For Al2O3, the mass of each Al2O3 molecule is A_Al2O3=(2×26.98+3×16)/(6.023×10^23) g=1.693×10^-22 g. The number of Al2O3 molecules per cm³ is n_Al2O3=ρ_Al2O3/A_Al2O3=3.95/1.693×10^-22=2.330×10^22 per cm³. The number of Al3+ and O2- ions per cm³ are n_Al3+=4.660×10^22 per cm³ and n_O2-=6.990×10^22 per cm³, respectively. The packing density of Al2O3 is η_Al2O3=(n_Al3+×4πr_Al3+^3/3 + n_O2-×4πr_O2-^3/3)/1=(4π/3)(4.660×0.057^3 + 6.990×0.132^3)×10^22×10^-21=0.714. Since η_Al2O3=0.714 is greater than η_SiO2=0.577, the density of Al2O3 is greater than that of SiO2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算SiO2和Al2O3的堆积密度来比较它们的密度差异。答案中包含了详细的数值计算过程，如相对原子质量的计算、分子数的计算、离子数的计算以及堆积密度的计算，这些都是计算题的典型特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算分子质量、分子数、离子数以及堆积密度，并进行综合分析比较。虽然不涉及复杂的推理分析或创新应用，但需要一定的理解和应用能力来正确执行这些步骤。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算SiO2和Al2O3的堆积密度，涉及相对原子质量、分子质量、离子数量、离子半径等多个变量的计算，并最终比较两者的密度差异。虽然计算步骤较多，但每一步的计算方法相对明确，没有涉及过于复杂的变量或概念。因此，在计算题中属于中等偏上的难度。" + }, + { + "idx": 2362, + "question": "Is the glass transition temperature of rubber band polymers above or below room temperature?", + "answer": "The glass transition temperature of rubber band polymers is below room temperature. This is because rubber band polymers exhibit significant elasticity at room temperature; if they were in a glassy state at room temperature, they would not display elasticity but rather brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释橡胶带聚合物的玻璃化转变温度与室温的关系，并提供详细的论述说明原因，这符合简答题的特征。答案不仅给出了结论，还进行了详细的解释和论证。 | 知识层次: 题目需要理解玻璃化转变温度的概念，并将其应用到具体材料（橡胶带聚合物）在室温下的行为分析中。虽然涉及基本概念，但更侧重于将概念应用于具体情境，属于简单应用层次。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求解释橡胶带聚合物的玻璃化转变温度与室温的关系，并简要说明原因。虽然需要理解玻璃化转变温度的概念及其对材料性能的影响，但不需要复杂的推导或多步骤分析。答案直接套用了基本概念，解释过程较为简单明了。" + }, + { + "idx": 2363, + "question": "Why do commercial oxides such as windows and beverage glass require the addition of Na2O to SiO2?", + "answer": "Na2O cannot form a network in glass. Sodium ions have only one functionality, Na+ has only one functionality. When they are added to the SiO2 network and connected with oxygen ions, they inevitably break a primary bond of the network, reducing the density of primary bonds in the network and thereby lowering the glass transition temperature. For general wide-mouth bottles and window glass, which are used at low temperatures, they do not require an excessively high glass transition temperature Tg. A low Tg makes the products easier to handle and reduces costs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么商业氧化物如窗户和饮料玻璃需要添加Na2O到SiO2中，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释Na2O在商业氧化物玻璃中的作用机制，涉及网络结构、离子功能性和玻璃转变温度等概念的关联和综合分析。需要理解并解释Na2O如何影响SiO2网络结构，以及这种影响如何导致玻璃性质的改变，属于机理层面的解释和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对玻璃网络结构的形成和改性机理进行深度解释。需要综合运用材料科学中的玻璃结构理论、离子功能性和网络改性等知识，分析Na2O在SiO2网络中的作用及其对玻璃性能的影响。虽然不涉及多因素交互作用的全面分析，但对单一机理的解释要求较高，属于机理深度解释的难度等级。" + }, + { + "idx": 2364, + "question": "The copolymer contains PVC (polyvinyl chloride — $T_{2}H_{2}C-1-$) and PVA (polyvinyl alcohol —CHO—). The mass fraction of PVC is $1\\\\Psi_{\\\\mathrm{W}_{\\\\mathrm{E}}}=\\\\mathrm{B},5\\\\Psi_{\\\\mathrm{W}}$, and the mass fraction of PVA is $14^{\\\\circ}=15^{\\\\circ}$. Determine the mole fractions of PVC and PVA.", + "answer": "First, calculate the molar masses of PVC and PVA. The relative atomic mass of C is 12.0I, $\\\\mathsf{H}$ is 1.008, Cl is 35.45, and O is $16.00$. The molar mass of PVC is $(2\\\\times12+3\\\\times1+35.45)\\\\underline{{{\\\\mathrm{g}}}}/110|=62.45\\\\underline{{{\\\\mathrm{g}}}}/1101$. The molar mass of PVA is $(4\\\\times12+6\\\\times1+2\\\\times16)\\\\mathrm{g/mol}=86\\\\mathrm{g/mol}$. In $100\\\\underline{{\\\\underline{{\\\\mathbf{I}}}}}$ of the polymer, there are $85/62,45=1,36\\\\mathrm{PVC}$ moles and $15:80=0.174$ PVA moles. Therefore, the mole fraction of PVC in the polymer, Ac, and the mole fraction of PVC, $f^{\\\\prime}(x)$, are: $$ f_{\\\\mathrm{vc}}={\\\\frac{1.36}{1.36+0.174}}=0.887\\\\qquadf_{\\\\mathrm{vA}}={\\\\frac{0.174}{1.36+0.174}}=0.113$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定PVC和PVA的摩尔分数，解答过程中涉及摩尔质量的计算、质量分数到摩尔数的转换以及最终的摩尔分数计算，这些都是典型的计算题特征。答案也以数值结果和公式应用的形式呈现。 | 知识层次: 题目需要进行多步计算，包括摩尔质量的计算、质量分数到摩尔分数的转换，以及最终的摩尔分数计算。虽然不涉及复杂的推理或综合分析，但需要正确应用多个基本概念和公式，并进行适当的数值计算。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算共聚物中PVC和PVA的摩尔分数，涉及摩尔质量计算、质量分数转换以及摩尔分数的综合计算。虽然计算步骤较多，但每一步的计算相对直接，没有涉及复杂多变量或高级数学工具，因此属于中等难度。" + }, + { + "idx": 2365, + "question": "A lightly cross-linked rubber band is stretched several times its original length and returns to its original length after the force is removed. If the stretched rubber band is placed below its glass transition temperature, what will happen to its length after the force is removed? Why?", + "answer": "When the stretched rubber band is placed below its glass transition temperature, it transitions into a glassy state. The glass transition causes the atoms to change from delocalized to localized (solidification), so it cannot return to its original length after the external force is removed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象并论述原因，答案形式为文字解释和论述，没有提供选项或要求计算。 | 知识层次: 题目要求分析橡胶带在玻璃化转变温度以下的行为变化，并解释其机理。这需要综合理解橡胶的弹性行为、玻璃化转变的概念以及温度对材料性能的影响，涉及多个知识点的关联和深入分析。 | 难度: 在简答题中属于机理深度解释难度。题目要求考生不仅要理解橡胶的玻璃化转变现象，还需要解释其微观机理（原子从离域态到局域态的转变）及其宏观表现（无法恢复原长）。这需要综合运用高分子物理知识，并能将微观结构与宏观性能联系起来进行推理分析，符合等级4对机理深度解释的要求。" + }, + { + "idx": 2366, + "question": "In the copolymer of PVC vinyl chloride $(C_{2}H_{3}C)$ and PVA vinyl alcohol $(C_{4}H_{5}C)_{2}$, the ratio of vinyl chloride to vinyl alcohol is 10:1. If the average molar mass of the copolymer molecular chain is $\\lvert5000\\rvert\\lvert\\bar{\\mathbf{g}}/17\\rvert\\lvert\\bar{\\mathbf{U}}\\rvert$, find its degree of polymerization (DP).", + "answer": "First, calculate the molar mass of the repeating unit. In question 49, the molar masses of PVC and PVA were determined to be $\\bar{6}\\bar{2}.45\\bar{5}\\bar{5}^{\\prime}\\bar{1}710\\bar{1}$ and $86\\\\mathrm{g/mol}$, respectively. In this copolymer, the ratio of PVC to PVA is 10:1, so the molar mass of the repeating unit is $111$ $$\\\\begin{array}{l l}{{}}&{{M=\\\\displaystyle\\\\frac{10}{11}\\\\mathrm{PVC}\\\\mathrm{\\\\Ddot{H}^{\\\\sharp}J}\\\\frac{\\\\mathrm{s}\\\\mathrm{s}}{\\\\mathrm{1}}\\\\mathrm{s}^{\\\\prime}\\\\mathrm{H}\\\\overline{{{\\\\mathcal{T}}}}^{\\\\sharp}\\\\mathrm{IW}\\\\mathrm{E}\\\\mathrm{H}+\\\\displaystyle\\\\frac{1}{11}\\\\mathrm{PVA}\\\\mathrm{\\\\Ddot{H}^{\\\\sharp}}}}\\\\ {{}}&{{=\\\\displaystyle[\\\\frac{10}{11}\\\\mathrm{6}2.45+\\\\frac{1}{11}86]\\\\mathrm{g}/\\\\mathrm{mol}=\\\\mathrm{64.6}\\\\mathrm{g}/\\\\mathrm{mol}}}\\\\end{array}$$ The degree of polymerization (DP) of the copolymer is: DP = molar mass of the copolymer / molar mass of the repeating unit = 16000g/mol / 64.6g/mol = 248", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚合度（DP），答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算共聚物的重复单元摩尔质量，并综合应用聚合度公式。虽然计算过程较为直接，但需要理解共聚物组成比例对重复单元摩尔质量的影响，并进行综合分析。 | 难度: 在计算题中属于综合性计算问题。题目需要计算共聚物的重复单元摩尔质量，涉及多步计算和概念关联（如摩尔质量计算、比例分配、聚合度计算）。虽然计算步骤较多，但每个步骤相对明确，没有涉及复杂多变量或非常规计算方法，因此属于该题型内的中等偏上难度。" + }, + { + "idx": 2367, + "question": "After washing and drying clothes containing artificial fibers, the clothes shrink. Please explain.", + "answer": "The fiber polymers in clothes made of artificial fibers are stretched and have a certain crystalline state. When the clothes are washed, the stretched state is removed, causing the polymer chains to return to a curled state. This is because the value of the curled state is greater than that of the stretched state, resulting in the clothes shrinking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释人工纤维衣物洗涤后缩水的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释人工纤维衣物洗涤后缩水的机理，涉及聚合物链的拉伸状态、结晶态变化以及能量状态比较等复杂概念的综合分析和推理。这需要深入理解材料科学中的高分子物理行为，并能够将这些概念关联起来进行解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释人工纤维衣物洗涤后缩水的机理，涉及聚合物链的拉伸状态、结晶态变化以及能量状态比较等专业概念。虽然不需要进行多因素综合分析（如等级5要求的复杂现象全面分析），但需要对材料科学中的高分子行为有较深入的理解，并能用专业术语准确描述这一物理过程。这比简单描述现象（等级3）要难，但比需要同时分析温度、湿度等多重因素的题目（等级5）略简单。" + }, + { + "idx": 2369, + "question": "Calculate the equilibrium vacancy concentration in a Cu crystal at |000|.", + "answer": "The equilibrium vacancy concentration in metals is x_s = exp(ΔS_f / k_B) * exp(-ΔH_f / (k_B * T)).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Cu晶体中的平衡空位浓度，答案给出了具体的计算公式和变量说明，需要应用公式进行数值计算。 | 知识层次: 题目要求应用给定的公式进行数值计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用给定的单一公式进行计算，无需额外的公式组合或复杂推导。题目明确给出了计算公式，且不涉及多步骤运算或变量转换，属于最基本的公式应用级别。" + }, + { + "idx": 2370, + "question": "A transparent PET film remains generally transparent when stretched slowly at room temperature. However, if stretched at $130^{\\circ}$, it becomes opaque. Why?", + "answer": "The glass transition temperature of PET (polyethylene terephthalate) is $10-C$. Stretching at $130^{\\circ}$, which is above the glass transition temperature, allows molecular chains to flow more easily. External stretching can promote polymer crystallization, and crystallization reduces transparency, with opacity increasing as crystallinity rises. However, slow stretching at room temperature (below the glass transition temperature) makes crystallization difficult for the polymer, so it retains its transparency.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么PET薄膜在不同温度下拉伸时透明性会发生变化，答案提供了详细的文字解释和论述，涉及材料科学中的玻璃转变温度和结晶行为，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释PET薄膜在不同温度下拉伸时的透明性变化，涉及玻璃化转变温度、分子链流动性和结晶行为等复杂概念的综合分析。需要理解温度对聚合物分子运动的影响，以及结晶度与透明性的关系，属于机理层面的解释和推理分析。 | 难度: 在简答题（复杂分析类）中，该题目属于机理深度解释难度等级。题目要求考生不仅掌握PET材料的玻璃化转变温度这一基本概念，还需要理解温度对分子链运动性的影响、外力诱导结晶的机理，以及结晶度与透明度的关系等多重知识点的综合运用。虽然不需要进行跨学科整合（如涉及化学反应动力学等），但需要建立清晰的因果逻辑链条来解释实验现象，属于对单一材料体系进行较深层次机理解释的典型题目。" + }, + { + "idx": 2371, + "question": "According to the $F E=F e=C$ phase diagram, calculate the relative amounts of phases in an iron-carbon alloy at room temperature under equilibrium conditions, where the mass fraction of carbon is $0.14$.", + "answer": "At room temperature, the equilibrium phases of the iron-carbon alloy are $\\alpha$-Fe (the mass fraction of carbon is $0.008$) and $Fe_3C$ (the mass fraction of carbon is $6.67$). Therefore, for an alloy with a mass fraction of carbon of $0.14$ at room temperature under equilibrium conditions, the relative amounts (mass fractions) of the $\\alpha$-Fe phase and the $Fe_3C$ phase are: $$ A^{\\alpha}=\\frac{6.67-0.14}{6.67-0.008}=98.62\\% \\qquad A^{Fe_3C}=1-98.62\\%=1.38\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相图计算铁碳合金在室温下的相组成比例，需要应用杠杆定律进行数值计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要考查对铁碳相图的基本理解和杠杆定律的直接应用，涉及简单的数值计算和公式套用，不需要多步推理或综合分析。 | 难度: 在计算题题型中，该题目属于简单公式应用计算。题目直接给出了相图的基本信息，并明确要求使用杠杆定律计算两相比例。解题步骤清晰明确，仅需套用单一公式（杠杆定律）进行简单代数运算即可得出结果，无需多步骤推导或复杂公式组合。在同题型（相图计算类）中属于基础难度级别，符合等级2\"简单公式应用计算\"的标准。" + }, + { + "idx": 2372, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the relative amount of eutectoid (pearlite) in an iron-carbon alloy with a carbon mass fraction of $0.14$ at room temperature under equilibrium conditions.", + "answer": "The microstructure of an alloy with a carbon mass fraction of $0.14$ at room temperature under equilibrium conditions consists of $\\\\alpha$-Fe and eutectoid (pearlite). The microstructure can be approximately considered the same as after the eutectoid transformation. At the eutectoid temperature, the carbon composition of $\\\\alpha$-Fe is $0.022$, and the carbon composition of the eutectoid structure is $0.76$. Therefore, the relative amount of eutectoid in the microstructure of an alloy with a carbon mass fraction of $0.14$ at room temperature is: $$ A^{P}=\\\\frac{0.14-0.022}{0.76-0.022}=10.58\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据铁碳相图进行具体的数值计算，应用杠杆定律公式来求解共析体（珠光体）的相对含量，答案给出了详细的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及相图的理解和杠杆定律的应用，需要综合分析合金成分与相组成的关系，属于中等应用层次。 | 难度: 在计算题中属于多步骤计算过程难度。题目要求根据铁碳相图计算共析体（珠光体）的相对含量，涉及相图数据的查找、杠杆定律的应用以及简单的代数计算。虽然需要理解相图概念和掌握杠杆定律，但计算步骤相对直接，不涉及复杂多变量或高级数学工具，属于该题型内中等偏下的难度。" + }, + { + "idx": 2373, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the percentage of cementite precipitated from all primary phases relative to the total system (the entire system) for an iron-carbon alloy with a carbon mass fraction of $3.6$ at the eutectoid temperature.", + "answer": "For an alloy with a carbon mass fraction of $3.6$ just after solidification, the relative amount of all phases (including primary phases and phases in the eutectic) is: $$ A^{\\\\Psi}=\\\\frac{6.67-3.6}{6.67-2.14}=67.77\\\\%$$ During the cooling process, the relative amount of $Fe_3C$ precipitated from the primary phases relative to the total system is: $$ A^{tFe_3C}=67.77\\\\% \\\\times 23.35\\\\%=15.82\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的百分比计算和相图分析，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及相图分析和公式应用，需要理解相图的基本原理和计算方法，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解相图的基本概念，掌握杠杆定律的应用，并进行多步计算。题目要求计算从所有初生相中析出的渗碳体相对于整个系统的百分比，涉及初生相和共晶相的相对量计算，以及冷却过程中的相变分析。虽然计算步骤较多，但每一步都有明确的公式和方法可循，属于中等应用层次的计算题。" + }, + { + "idx": 2374, + "question": "Assuming an ionic crystal has monovalent cations and anions, with a cation vacancy formation energy of 2000, an anion vacancy formation energy of 101-1'tra01, and a cation interstitial formation energy of 30k=1,17701, calculate the relative concentration of Schottky defects.", + "answer": "The formation energy of a Schottky defect is the sum of the cation vacancy formation energy and the anion vacancy formation energy, which is (20+40) kJ/mol = 60 kJ/mol. The relative concentration of Schottky defects is exp(-60×10^3/RT). For example, at room temperature (300K), the above ratio equals 0.018.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的能量值进行计算，最终得出Schottky缺陷的相对浓度，涉及数值计算和公式应用（如指数计算和能量求和）。答案也展示了具体的计算过程和结果。 | 知识层次: 题目需要理解Schottky缺陷的形成机制，并应用相关公式进行多步计算，包括能量求和和浓度计算。虽然涉及基础概念，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在计算题中属于综合性计算问题，需要理解Schottky缺陷的形成机制，正确应用形成能的概念，并进行多步计算（包括能量求和与指数计算）。题目涉及多个能量参数的整合和温度相关的计算，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2375, + "question": "According to the $F E=F e=C$ phase diagram, calculate the relative amounts of phases in an iron-carbon alloy with a carbon mass fraction of $3.6$ under equilibrium conditions at room temperature.", + "answer": "At room temperature, the equilibrium phases of the iron-carbon alloy are $\\alpha$-Fe (carbon mass fraction is $0.008$) and $Fe_3C$ (carbon mass fraction is $6.67$). Therefore, for an alloy with a carbon mass fraction of $3.6$ under equilibrium conditions at room temperature, the relative amount (mass fraction) of the $\\alpha$-Fe phase and the relative amount of the $Fe_3C$ phase are: $$ A^{\\alpha}=\\frac{6.67-3.6}{6.67-0.008}=46.08\\% \\qquad A^{Fe_3C}=1-46.08\\%=53.92\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据铁碳相图计算特定成分合金在室温下的相组成比例，答案通过具体数值计算得出，涉及公式应用和百分比计算，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图的基本原理并应用杠杆定律进行计算，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析相组成与成分关系。虽然计算过程明确，但涉及多个知识点的关联应用，属于中等偏上难度。" + }, + { + "idx": 2376, + "question": "Assuming an ionic crystal has monovalent cations and anions, with a cation vacancy formation energy of 2000, anion vacancy formation energy of 101-1'tra01, and cation interstitial formation energy of 30k=1,17701, calculate the relative concentration of Frenkel defects.", + "answer": "The formation energy of Frenkel defects is the sum of the cation vacancy formation energy and the cation interstitial formation energy, which is (20+30) kJ/mol = 50 kJ/mol. The relative concentration of Frenkel defects is exp(-50×10^3/RT).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及能量计算和浓度计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要理解Frenkel缺陷的形成机制，并应用相关公式进行多步计算（包括能量求和和指数计算），涉及概念关联和综合分析。虽然不涉及复杂的推理或创新，但超出了简单套用公式的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解Frenkel缺陷的形成机制，正确识别并应用相关能量参数（阳离子空位形成能和阳离子间隙形成能），进行多步骤计算（能量求和、指数计算），并正确应用玻尔兹曼分布公式。虽然不涉及复杂多变量，但需要概念关联和综合分析能力。" + }, + { + "idx": 2377, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the percentage of the final transformed eutectoid in the eutectic structure relative to the total system for an iron-carbon alloy with a carbon mass fraction of $3.6$.", + "answer": "The percentage of phases in the eutectic structure is: $$ A_{6}^{7}=\\\\frac{6.67-4.3}{6.67-2.14}=52.3\\\\%$$ Therefore, the percentage of the final transformed eutectoid in the eutectic structure is: $$ A_{G}^{P}=67.6\\\\% \\\\times 52.3\\\\% \\\\times (1-23.35\\\\%)=27.1\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据铁碳相图进行数值计算，应用公式来求解最终转变的共析体在共晶结构中的百分比，答案也给出了具体的计算过程和数值结果。 | 知识层次: 题目需要进行多步计算，涉及相图的理解和公式应用，需要综合分析不同相的比例关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括百分比计算和相组成分析），并综合应用杠杆定律和相变知识。虽然计算步骤明确，但涉及多个概念关联和综合分析，属于中等偏上的难度。" + }, + { + "idx": 2379, + "question": "Can all parts of a dislocation loop be screw dislocations? Why?", + "answer": "The Burgers vector of a screw dislocation is parallel to the dislocation line. A single dislocation has only one Burgers vector, and a dislocation loop cannot be parallel to one direction everywhere. Therefore, a dislocation loop cannot have all its parts as screw dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么位错环的所有部分不能都是螺位错，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对位错环的性质进行深入分析，涉及位错线的方向与Burgers矢量的关系，需要综合运用位错理论的基本概念进行推理和解释，思维过程较为复杂。 | 难度: 在简答题题型中，该题目要求对位错环的性质进行机理深度解释，需要综合运用位错理论中的Burgers矢量和位错线方向的关系进行推理分析。虽然不涉及多个复杂现象的全面分析，但需要对位错环的几何特性有深入理解，并能够逻辑清晰地解释为什么位错环不能全部由螺型位错组成。这在该题型内属于较高难度的题目。" + }, + { + "idx": 2380, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the relative amounts of the primary phase (austenite) and eutectic in an iron-carbon alloy with a carbon mass fraction of $3.6$ just after solidification is completed.", + "answer": "Just after solidification is completed, the carbon compositions of the primary phase and eutectic structure are $2.14$ and $4.3$ respectively. Therefore, the relative amounts of the primary phase and eutectic just after solidification are: $$ A^{\\\\gamma}=\\\\frac{4.3-3.6}{4.3-2.14}=32.4\\\\% \\\\qquad A^{0}=1-32.4\\\\%=67.6\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据相图进行数值计算，应用杠杆定律来求解各相的相对含量，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解相图、应用杠杆定律计算相对量，并关联不同相的概念。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析碳含量与相组成的关系。虽然计算步骤明确，但涉及多个知识点的关联应用，属于中等偏上的难度。" + }, + { + "idx": 2381, + "question": "MgO dissolves into Al2O3 to form a solid solution. Assuming Mg2+ replaces Al3+, write the reaction equation using Kroger-Vink notation.", + "answer": "2MgO forms 2MgAl' + V..O + 2OOX through Al2O3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Kroger-Vink符号写出反应方程式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求使用Kroger-Vink符号表示MgO溶解到Al2O3中的反应方程，这需要理解缺陷化学的基本原理和符号表示方法，并能够将具体离子替换情况转化为规范的缺陷反应方程。虽然不涉及多步计算，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求使用Kroger-Vink符号表示固溶反应，这需要学生不仅理解离子取代的机制，还要掌握缺陷化学的表示方法。题目涉及多步概念关联和综合分析，包括电荷平衡、缺陷类型识别和符号书写规范。相比同题型中更基础的简答题，该题目需要更深入的知识应用和逻辑推导，属于较高难度的多角度分析论述题。" + }, + { + "idx": 2382, + "question": "MgO dissolves into Al2O3 to form a solid solution, assuming the formation of cation interstitials. Write the reaction equation using Kroger-Vink notation.", + "answer": "3MgO forms 3Mg••i + 2V•Al + 3OO× through Al2O3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Kroger-Vink符号写出反应方程式，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求使用Kroger-Vink符号表示固溶体形成反应，涉及对缺陷化学的理解和符号系统的应用。虽然需要记忆Kroger-Vink符号的基本规则，但更重要的是能够将这些规则应用到具体的化学反应中，并理解缺陷的形成机制。这属于中等应用层次，因为它需要将多个概念（固溶体、缺陷化学、Kroger-Vink符号）关联起来，并进行适当的分析和应用。 | 难度: 在简答题题型中，该题目需要多角度分析论述。首先，学生需要理解MgO溶解在Al2O3中形成固溶体的过程，并假设形成阳离子间隙。其次，学生需要掌握Kroger-Vink符号的正确使用方法，包括电荷和位置的表示。最后，学生需要将化学反应过程转化为Kroger-Vink符号的方程，这需要综合分析和多步推理。因此，该题目在简答题题型中属于较高难度，需要学生具备较深的知识掌握和综合分析能力。" + }, + { + "idx": 2383, + "question": "Assuming a monovalent cation and anion in an ionic crystal, the cation vacancy formation energy is 2000, the anion vacancy formation energy is 101-1'tra01, the cation interstitial formation energy is 30k=1,17701, calculate the concentration ratio of Schottky defects to Frenkel defects.", + "answer": "The concentration ratio of Schottky defects to Frenkel defects is exp(-60×10^3/RT)/exp(-50×10^3/RT)=exp(-10×10^3/RT). For example, at room temperature (300K), the above ratio equals 0.018.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Schottky缺陷与Frenkel缺陷的浓度比，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解Schottky缺陷和Frenkel缺陷的形成能，并应用相关公式计算浓度比。虽然计算过程较为直接，但需要综合分析不同缺陷的形成能及其对浓度比的影响。 | 难度: 在计算题中属于综合性计算问题，需要理解Schottky缺陷和Frenkel缺陷的形成能概念，并正确应用相关公式进行多步计算。题目涉及多个能量值的处理和温度变量的引入，但计算步骤相对明确，属于中等应用层次。" + }, + { + "idx": 2384, + "question": "At which temperature is the equilibrium vacancy concentration 10 times that at 1000K?", + "answer": "The ratio of vacancy concentrations at two different temperatures T1 and T2 is x_r(T2)/x_r(T1) = exp[-ΔH_f / k_B * (1/T2 - 1/T1)]. Let T1 = 1000K, and the vacancy concentration at T2 be 10 times that at T1, then ln10 = -ΔH_f / k_B * (1/T2 - 1/1000). 1/T2 = (1/1000 - k_B * ln10 / ΔH_f) K^-1. From textbook Table 6-1, ΔH_f for Cu is 1.22 eV, and k_B = 8.61×10^-5 eV·K^-1. Substituting these values into the equation gives 1/T2 = (1/1000 - 8.61×10^-5 * ln10 / 1.22) K^-1 = 8.375×10^-4 K^-1. Therefore, T2 = 1144 K. That is, the vacancy concentration at 1144 K is 10 times that at 1000 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解特定温度下的空位浓度比，解答过程中涉及对数运算、物理常数代入和单位转换等计算步骤，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用公式进行数值计算，并综合分析不同温度下的空位浓度关系。虽然不涉及复杂的推理分析或创新应用，但需要理解空位浓度的温度依赖性和相关物理常数的应用。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及平衡空位浓度的计算，需要应用公式并代入已知数值进行求解。虽然计算步骤较多，但每一步都是基于明确的物理概念和数学操作，没有涉及复杂多变量或高度抽象的推理。因此，在计算题题型中属于中等偏上的难度等级。" + }, + { + "idx": 2385, + "question": "Can all parts of a dislocation loop be edge dislocations? Why?", + "answer": "The Burgers vector of an edge dislocation is perpendicular to the dislocation line. If the Burgers vector is perpendicular to the plane of the dislocation loop, then every part of the dislocation loop is an edge dislocation. The slip plane of such a dislocation is the prismatic plane formed by the dislocation loop and the direction of the Burgers vector. This type of dislocation is also called a prismatic dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么位错环的所有部分都可以是刃位错，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要对位错环的性质进行深入分析，涉及Burgers矢量与位错线方向的关系，以及位错环在不同位置的位错类型变化。这需要综合运用位错理论的基本概念，进行推理分析，解释为什么在某些条件下位错环的所有部分都可以是刃位错。思维过程涉及多个概念的关联和综合分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求考生不仅理解位错环的基本概念，还需要掌握刃型位错的柏氏矢量与位错线的关系，并能综合运用这些知识解释位错环各部分均为刃型位错的条件。此外，题目还涉及棱柱位错的概念和滑移面的确定，需要考生进行较为深入的机理分析和推理。虽然题目没有要求全面分析复杂现象，但对知识点的掌握深度和综合运用能力要求较高，因此在简答题题型中属于机理深度解释的难度等级。" + }, + { + "idx": 2386, + "question": "Explain how to use the method of measuring density to determine which reaction is correct when MgO dissolves into Al2O3 to form a solid solution", + "answer": "By experimentally measuring the crystal lattice constants, calculate the theoretical densities under two defect scenarios and compare them with the measured density. First, calculate the number of ions in the unit cell for each type of defect based on the solid solution concentration, then use the lattice constants obtained from X-ray experiments to calculate the densities for both cases. The defect mode corresponding to the theoretical density closest to the measured density is the correct one.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何使用密度测量方法来确定正确的反应，答案提供了详细的文字解释和论述，包括实验步骤和理论计算，没有涉及选择、判断或数值计算。 | 知识层次: 题目要求通过实验测量和理论计算相结合的方法，分析两种缺陷情景下的密度差异，并据此判断正确的反应机制。这需要综合运用晶体学、缺陷化学和密度计算等多方面知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求综合运用晶体学、缺陷化学和密度计算等多方面知识，通过实验数据（X射线衍射结果）进行理论推导和比较分析。解题步骤涉及多个复杂环节：理解固溶体缺陷类型、计算单位晶胞离子数、利用晶格常数计算理论密度、与实测密度对比验证等。这需要考生具备高阶的综合分析能力和机理解释能力，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 2387, + "question": "In a simple cubic crystal, the Burgers vector of dislocation (2) is $b^{(2)}=a[0,10]$, and the tangent direction of the dislocation line is $l^{(2)}=[001]$. Identify the type of this dislocation and the slip plane of the dislocation. If the slip plane is not unique, explain the constraints on the slip plane.", + "answer": "For dislocation (2), since the Burgers vector is perpendicular to the dislocation line, it is an edge dislocation. The slip plane is the plane that contains both the Burgers vector and the dislocation line, so the slip plane of dislocation (2) should be the (100) plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，需要分析Burgers矢量和位错线方向的关系，并确定位错类型和滑移面。答案也以文字解释的形式给出，没有涉及计算或选择选项。 | 知识层次: 题目要求识别位错类型并确定滑移面，涉及位错基本概念的理解（如柏氏矢量与位错线的关系）以及晶体几何的应用（确定滑移面）。虽然不涉及复杂的计算或多步骤推理，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解位错的基本概念（如Burgers向量和位错线方向的关系），并能正确判断位错类型（刃位错）。此外，还需要确定滑移面，并解释其唯一性或约束条件。虽然涉及多步分析和概念关联，但不需要过于复杂的推导或深度关联性分析。" + }, + { + "idx": 2388, + "question": "The vacancy formation energy is 75 kJ/mol, and the crystal is quenched from 1000K to room temperature (approximately 300K). The Burgers vector h of the edge dislocation is about 0.25 nm. What is the osmotic force experienced by the dislocation?", + "answer": "When there is an unbalanced vacancy concentration, the chemical force per unit length on an edge dislocation is Fs=(kBT/h²)ln(x/x̄), where kB is the Boltzmann constant, T is the temperature, h is the Burgers vector, x is the actual vacancy concentration, and x̄ is the equilibrium vacancy concentration. The equilibrium vacancy concentration at different temperatures is x=exp(-Gf/kBT). Therefore, the vacancy concentrations at 1000K and 300K are exp(-Gf/1000kB) and exp(-Gf/300kB), respectively. The normal stress σs on the edge dislocation when the crystal is quenched from 1000K to 300K is σs=(kB300/h³)(Gf/R)(1/300-1/1000)=(300/(0.25×10⁻⁹)³)×(75000/6.02×10²³)(1/300-1/1000)Pa=5.43×10⁹Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解位错所受的渗透力，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解空位形成能、平衡空位浓度、位错受力等概念，并应用相关公式进行综合分析。虽然不涉及复杂的推理分析或创新应用，但需要一定的思维深度和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解多个概念（如空位形成能、平衡空位浓度、位错受力等）并进行多步计算。题目涉及公式应用和数值计算，但步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 2389, + "question": "The vacancy formation energy is 75 kJ/mol, the crystal is quenched from 1000 K to room temperature (approximately 300 K), and the Burgers vector h of the edge dislocation is about 0.25 nm. Estimate whether the dislocation can climb.", + "answer": "The climb stress σs acting on the dislocation is 5.43×10⁹ Pa, which is close to the theoretical shear strength of general metals, so the dislocation will climb.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计位错是否能攀移，答案中给出了具体的计算结果（5.43×10⁹ Pa）并基于此得出结论，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（如计算爬升应力），并需要将空位形成能、温度变化和伯格斯矢量等概念关联起来综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（如空位形成能、温度变化、Burgers矢量）并进行多步计算（如计算攀移应力），同时需要综合分析结果与理论剪切强度的关系。虽然步骤较多，但变量相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 2390, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the relative amounts of phases in an iron-carbon alloy at room temperature under equilibrium conditions, where the mass fraction of carbon is $1.20$.", + "answer": "At room temperature, the equilibrium phases of the iron-carbon alloy are $\\alpha$-Fe (with a mass fraction of carbon of $0.008$) and $Fe_3C$ (with a mass fraction of carbon of $6.67$). Therefore, for an alloy with a mass fraction of carbon of $1.20$, the relative amounts (mass fractions) of the $\\alpha$-Fe phase and the $Fe_3C$ phase at room temperature under equilibrium conditions are: $$ A^{\\alpha}=\\frac{6.67-1.2}{6.67-0.008}=82.11\\% \\qquad A^{Fe_3C}=1-82.11\\%=17.89\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据铁碳相图计算特定成分合金在室温下的相组成比例，需要应用杠杆定律进行数值计算，答案给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图的基本知识，进行多步计算和概念关联，包括杠杆法则的应用和相组成的综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析相组成与碳含量的关系。虽然涉及多步骤计算，但变量相对单一（仅碳含量），未达到复杂多变量计算的等级4标准。" + }, + { + "idx": 2392, + "question": "A face-centered cubic single crystal undergoes tensile deformation with the tensile axis along [001]. Determine the force on a dislocation with Burgers vector $b{=}a[\\overline{{\\textbf{\\vert}}}0\\mathbf{\\vert}]/2$ and line direction $t$ parallel to [121] in the slip direction. The lattice constant is given as $=0.35\\\\pi m$.", + "answer": "The force $F$ per unit length of the dislocation line in the slip plane is the product of the resolved shear stress $=5$ in the slip direction of the applied stress field and the Burgers vector $h$: $F_{n}=n+$. Under uniaxial tension (stress $(\\overline{o})$), $\\\\tau=\\\\sigma\\\\mathrm{cos}\\\\lambda\\\\cos\\\\varphi$, where $\\\\lambda$ is the angle between the tensile axis and the Burgers vector, and $11\\\\pi$ is the angle between the tensile axis and the normal to the slip plane. Since $b{=}a[\\overline{{\\textbf{l}}}()]\\\\backslash2$ and $t$ is parallel to [121], the slip plane is the plane containing both the Burgers vector and the dislocation line, hence the slip plane is (111). Therefore, 2 is the angle between [001]-[101], and $42$ is the angle between [001]-[111]. Using the crystallographic angle formula for cubic systems, $$\\\\cos\\\\lambda={\\\\frac{1}{\\\\sqrt{1}\\\\sqrt{1+1}}}={\\\\frac{1}{\\\\sqrt{2}}}\\\\qquad\\\\cos\\\\varphi={\\\\frac{1}{\\\\sqrt{1}\\\\sqrt{1+1+1}}}={\\\\frac{1}{\\\\sqrt{3}}}$$ Thus, $=\\\\sigma/\\\\sqrt{6}=0.408\\\\sigma$, and the magnitude of $11$ is $\\\\alpha\\\\sqrt{2}/2=0.36\\\\times10^{-9}\\\\times\\\\sqrt{2}/2=2.55\\\\times10^{-10}\\\\mathrm{m}$. Finally, $$ F_{\\\\mathrm{g}}=\\\\tau b=0.408\\\\times2.55\\\\times10^{-10}\\\\sigma\\\\mathrm{N}/\\\\mathrm{m}=1.04\\\\times10^{-10}\\\\sigma\\\\mathrm{N}/\\\\mathrm{m}$$ where the unit of $\\\\frac{1}{a^{2}}$ is $\\\\mathsf{P}_{\\\\perp}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定位错上的力，涉及多个步骤的计算和晶体学角度的应用，最终需要得出一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括晶体学角度计算、Burgers向量的确定、滑移面的识别以及力的计算。虽然不需要复杂的推理分析或创新应用，但需要综合运用多个概念和公式进行中等难度的计算。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及晶体学角度计算、应力分解、位错力计算等多个步骤，且需要正确理解并应用相关公式。虽然计算过程较为直接，但需要综合分析多个概念和步骤，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 2394, + "question": "In a crystal, there is a pair of parallel edge dislocations on the slip plane. How large should their spacing be to prevent movement due to their interaction? Assume the slip resistance (shear stress) of the dislocation is $\\\\square A^{\\\\prime\\\\prime}\\\\approx10^{5}Pa$, $1=0.3$, $G=5\\\\times10^{10}Pa$ (express the answer in terms of b).", + "answer": "Two parallel edge dislocations (denoted as A and B), with dislocation A located on the $\\\\underline{{\\\\underline{{\\\\pi}}}}$ axis of the coordinate frame. The force per unit length exerted by dislocation A on parallel dislocation B at position $(x,y)$ in the slip direction is F. Since both dislocations are on the same slip plane, the force is $F_{s}^{\\\\mathrm{A\\\\toB}}=\\\\frac{G b^{2}}{2\\\\pi(1-\\\\nu)}\\\\frac{1}{x}$ G²1, where x is the distance between the two dislocations. When this force equals or exceeds the resistance $\\\\cdot E_{1}b$ that the dislocation must overcome to slip, the two dislocations can slide. Therefore, when $$\\\\leq\\\\frac{\\\\vec{\\\\left(r\\\\right)}^{h}}{\\\\underline{{\\\\vec{2}\\\\pi(1-\\\\nu^{\\\\prime})}}}\\\\frac{1}{\\\\tau_{\\\\perp}}$$, the two dislocations will slide. That is, $$ \\\\displaystyle{x\\\\leq\\\\frac{G b}{2\\\\pi(1-\\\\nu)}\\\\frac{1}{\\\\tau_{\\\\mathrm{pe}}}}{=\\\\frac{5\\\\times10^{10}b}{2\\\\pi(1-0.3)}\\\\frac{1}{9.8\\\\times10^{5}}}{=1.16\\\\times10^{4}b}$$. If the two dislocations have the same sign, they will move toward each other until the distance between them is less than the calculated $^\\\\texttt{I}$ and then remain stationary. If the two dislocations have opposite signs, they will attract and annihilate each other when the distance between them is less than the calculated $x$. The two dislocations will remain stationary only if the distance between them is greater than $\\\\gamma^{-}$. The force in the climb direction is 0, so no climb will occur regardless of the distance between the two dislocations.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定两个平行刃位错之间的间距，以防止它们因相互作用而移动。解答过程中涉及到了具体的公式推导和数值代入计算，最终给出了一个具体的数值结果（1.16×10^4b）。这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错相互作用力的公式，并将其与临界应力条件相结合进行计算。虽然不涉及复杂的推理分析或机理解释，但需要综合应用多个知识点进行中等难度的计算。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如位错相互作用力、滑移阻力等），进行多步骤的计算和综合分析。虽然涉及公式应用和数值计算，但整体思路清晰，步骤明确，属于中等偏上的难度。" + }, + { + "idx": 2395, + "question": "If the resistance (shear stress) that dislocation slip needs to overcome is 9.8×10^5 Pa for copper, the shear modulus G of copper is 4×10^10 Pa, and the lattice constant is 0.55 nm. How thick is the low-dislocation-density layer on the surface of copper? It is known that copper has a face-centered cubic structure, and the Burgers vector length is 0.36/√2 nm = 0.255 nm.", + "answer": "Due to the effect of the surface image force, dislocations near the surface are subjected to the image force F_im. When the image force is greater than or equal to the dislocation slip resistance, the dislocation slips out of the surface, reducing the dislocation density on the surface. Taking a screw dislocation as an example, the image force F_im per unit length parallel to the surface is F_im = τ_in b = G b^2 / (4π d), where d is the distance of the dislocation from the surface. When F_im equals the dislocation slip resistance, the corresponding d is the thickness of the low-dislocation-density layer on the surface. Therefore, d ≤ G b / (4π τ_⊥). The thickness of the low-dislocation-density layer for copper is d = (4×10^10 × 0.255×10^-9) / (4π × 9.8×10^5) m = 8.28×10^-7 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解低位错密度层的厚度，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如剪切应力、剪切模量、位错滑移阻力、表面镜像力等），需要综合分析不同参数之间的关系，但不需要进行复杂的推理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解多个概念（如剪切应力、剪切模量、位错滑移阻力、表面镜像力等）并进行多步计算。题目要求将理论公式与实际数值计算相结合，涉及单位转换和综合分析，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2396, + "question": "Assuming the resistance (shear stress) that dislocation slip needs to overcome is 1.5×10^8 Pa for 30-51=Fe alloy, the shear modulus G for 3% Si-Fe alloy is 3.5×10^11 Pa, and the lattice constant is 0.28 nm. How thick is the low-dislocation-density layer near the surface of the 3% Si-Fe alloy? It is known that iron-silicon alloy has a body-centered cubic structure, and the Burgers vector length is 0.28√3/2 nm = 0.242 nm.", + "answer": "Due to the effect of surface image force, dislocations near the surface are subjected to the image force F_im. When the image force is greater than or equal to the resistance to dislocation slip, the dislocation slips out of the surface, reducing the dislocation density near the surface. Taking a screw dislocation as an example, the image force F_im per unit length parallel to the surface is F_im = τ_in b = G b^2 / (4π d), where d is the distance of the dislocation from the surface. When F_im equals the resistance to dislocation slip, d represents the thickness of the low-dislocation-density layer near the surface. Therefore, d ≤ G b / (4π τ_⊥). The thickness of the low-dislocation-density layer for the iron-silicon alloy is d = (3.5×10^11 × 0.242×10^-9) / (4π × 1.5×10^8) m = 4.88×10^-8 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解低位错密度层的厚度，答案中包含了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如表面镜像力、位错滑移阻力等），需要综合分析已知条件并推导出低位错密度层的厚度。虽然不涉及复杂的机理分析或创新设计，但思维过程要求一定的深度和逻辑性。 | 难度: 在计算题中属于综合性计算问题，需要理解表面镜像力的概念，掌握Burgers向量的计算，正确应用剪切模量和剪切应力的关系，并进行多步数值计算。虽然涉及多个概念和公式，但步骤相对明确，属于该题型内的中等偏上难度。" + }, + { + "idx": 2397, + "question": "A simple cubic crystal has a screw dislocation with $b=[001]$ on the (100) plane. An edge dislocation with $b=[010]$ on the (001) plane intersects with it. After the intersection, do kinks or jogs form on the two dislocations?", + "answer": "After the intersection of the two dislocations, a small segment of dislocation with the same magnitude and direction as the Burgers vector of the other dislocation is left on each dislocation. If this small segment lies on the slip plane of the original dislocation, it is a kink; otherwise, it is a jog. Let dislocation A be the screw dislocation with $b=[001]$ on the (100) plane, and dislocation B be the edge dislocation with $b=[010]$ on the (001) plane. After the intersection of dislocation A and dislocation B, dislocation A produces a small segment of dislocation in the [010] direction. The slip plane of dislocation A is (100), and [010]·[100]=0, meaning the small segment lies on the slip plane of dislocation A, so it is a kink. On dislocation B, a small segment of dislocation in the [001] direction is produced. The slip plane of dislocation B is (001), and [001]·[001]=1, meaning the small segment does not lie on the slip plane of dislocation B, so it is a jog.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来分析两种位错相交后形成的结构类型（kink或jog），需要详细说明判断依据和过程，属于需要文字解释的简答题类型。 | 知识层次: 题目涉及位错交互作用的复杂分析，需要理解位错的性质（如螺位错和刃位错）、伯格斯矢量的方向、滑移面的关系，以及kink和jog的形成机制。解答过程需要综合运用这些概念进行推理分析，判断位错段是否位于滑移面上，从而确定形成的是kink还是jog。这超出了简单应用或中等应用的范畴，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用位错理论、晶体学知识和向量分析能力，涉及多个知识点的深度整合。解题需要分步骤分析两种位错的相互作用机理，判断kink和jog的形成条件，并进行严格的向量点积验证。这种需要多维度推理和机理解释的题目，在同题型中属于最高难度等级。" + }, + { + "idx": 2398, + "question": "In a face-centered cubic crystal, there are two dislocations with their Burgers vectors $b$ and the planes on which they are gliding as follows: Dislocation A has $b^{[i]}=a[0]1]12$ and glides on the (111) plane; Dislocation B has $b^{(h)}=a[10\\overline{{1}}]/2$ and glides on the (111) plane. If the two dislocations are parallel, what are the tangent vectors of these two dislocations?", + "answer": "Since the (111) and (111) planes intersect, when the dislocations on these two planes are parallel to each other, the direction of the dislocation line can only be the line of intersection of the two planes. Using the zone law, it is easy to determine that the line of intersection of the (111) and (111) planes is [110], so the tangent vectors of the two dislocation lines are [110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定两个位错的切线向量，答案提供了详细的推导过程和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解面心立方晶体中的位错性质，应用晶面相交的几何关系（带轴定律）来确定位错线的方向。虽然涉及多个概念（位错的柏氏矢量、滑移面、位错线方向），但解题过程主要是基于几何关系的推导和应用，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识（如面心立方结构、位错性质、晶面交线计算）进行多步分析。题目要求：" + }, + { + "idx": 2400, + "question": "In a Ni single crystal, there is a dislocation with Burgers vector b=a[0]12 on the (11T) plane. The lattice constant a=0.35 nm. What is the length of the dislocation's Burgers vector?", + "answer": "Solution: The Ni crystal has an fcc structure, and the Burgers vector b is of the [110]/2 type. Therefore, the length of the Burgers vector is b=a√2/2=0.35√2/2=0.254 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算位错的Burgers矢量的长度，需要通过数值计算和公式应用来得出结果。答案中给出了具体的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目主要考查对Burgers vector长度计算的基本公式应用，涉及简单的数值计算和直接套用公式，不需要多步计算或综合分析。 | 难度: 在计算题-简单应用类别中，此题仅需直接套用单一公式（Burgers矢量长度公式b=a√2/2）进行简单数值计算，无需多步骤推导或公式组合，属于该题型内最基础的难度等级。" + }, + { + "idx": 2401, + "question": "In a face-centered cubic crystal, there are two dislocations with their Burgers vectors $b$ and the planes they are gliding on as follows: Dislocation A has $b^{[i]}=a[0]1]12$ and glides on the (111) plane; Dislocation B has $b^{(h)}=a[10\\\\overline{{1}}]/2$ and glides on the (111) plane. Can they react when they meet during gliding? What is the Burgers vector of the resulting dislocation after the reaction? What is the glide plane?", + "answer": "If the two dislocations meet and react, the reaction equation is $${\\\\frac{a}{2}}[011]+{\\\\frac{a}{2}}[10{\\\\overline{{1}}}]\\\\rightarrow{\\\\frac{a}{2}}[110]$$. The sum of the squares of the Burgers vectors of the two dislocations before the reaction is $a^{2}/2+a^{2}/2=a^{2}$, and the square of the Burgers vector of the resulting dislocation after the reaction is $=2-17$. According to the Frank criterion, this reaction reduces energy, so the reaction can proceed. Since the direction of the resulting dislocation line is [110] and the Burgers vector direction is [110], its glide plane is (001).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两个位错相遇时是否会发生反应，并描述反应后的位错矢量和滑移面。答案提供了详细的反应方程、能量变化分析以及滑移面的确定，这些都是基于理论解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目涉及位错反应的能量判据（Frank准则）、位错滑移面的确定以及位错线的方向分析，需要综合运用材料科学中的位错理论和晶体学知识进行推理分析。解答过程不仅需要计算位错反应的Burgers向量，还需要判断反应的能量变化和确定新位错的滑移面，思维过程较为复杂。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体学、位错理论及能量准则进行多步骤推理。具体表现为：" + }, + { + "idx": 2402, + "question": "In a face-centered cubic crystal, there are two dislocations with their Burgers vectors $b$ and the planes on which they are gliding as follows: Dislocation A has $b^{[i]}=a[0]1]12$ and glides on the (111) plane; Dislocation B has $b^{(h)}=a[10\\overline{{1}}]/2$ and glides on the (111) plane. Does the generation of such dislocations make them easier or more difficult to glide, and why?", + "answer": "The glide plane of the generated dislocation is not the original glide planes of the two dislocations, the (111) plane and the (111) plane, and its glide plane (001) is not the easiest glide plane for the fcc structure, so this dislocation is difficult to glide.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么生成的位错更容易或更难滑移，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析面心立方晶体中位错的滑移行为，涉及位错伯格斯矢量、滑移面以及位错反应的复杂分析。需要综合运用晶体学、位错理论等知识，理解位错滑移的难易程度与滑移面的关系，并进行推理和解释。这超出了简单应用和中等应用的范围，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用位错理论、晶体学知识以及滑移系分析能力。解题需要：1) 准确识别FCC结构中伯氏矢量的晶体学特征；2) 分析不同滑移面的相对易动性；3) 理解位错反应后新位错的滑移面特性；4) 结合FCC结构中最易滑移面(111)的特性进行对比论证。这些要求涉及多维度的理论整合与机理解释，属于该题型下最高层级的复杂现象全面分析。" + }, + { + "idx": 2403, + "question": "The density of a crystal with NaCl-type structure is 3.55g/cm³, what should its Burgers vector be?", + "answer": "In NaCl-type structures, the common dislocation Burgers vector is of the <110>/2 type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释NaCl型晶体结构中位错的Burgers向量类型，答案提供了文字解释而非计算或选择。 | 知识层次: 题目需要理解NaCl型晶体结构的基本特征，并应用Burgers矢量的相关知识进行判断。虽然不涉及复杂的计算或多步骤推理，但需要将晶体结构与位错理论中的Burgers矢量类型联系起来，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解NaCl型晶体结构的基本特征，并能够将密度与Burgers矢量的概念关联起来。虽然题目涉及多步计算和概念关联，但解题步骤相对明确，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2404, + "question": "The shear modulus of Ni is G=75 GPa, and the intrinsic stacking fault energy is γ=150 mJ/m². Calculate the equilibrium width of dislocation extension.", + "answer": "Since the perfect dislocation before decomposition is an edge dislocation, the equilibrium width d₀ of the extended dislocation is d₀=Gb²/(8πγ)×(2+ν)/(1−ν)=75×10⁹×(0.147×10⁻⁹)²/(8π×150×10⁻³)×(2+1/3)/(1−1/3) m=1.505×10⁻⁹ m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的材料参数和公式进行数值计算，最终得出一个具体的数值结果。答案展示了完整的计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及材料科学中的基本公式应用（如剪切模量、堆垛层错能等），并需要理解位错扩展宽度的概念及其计算方法。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式和概念（如剪切模量、堆垛层错能、位错扩展宽度等），并进行多步计算。虽然计算过程较为直接，但涉及多个物理量的转换和综合运用，属于中等偏上的难度。" + }, + { + "idx": 2405, + "question": "Calculate the length of the Burgers vector for a NaCl-type structure crystal, given the lattice constant a=0.4151 nm.", + "answer": "The Burgers vector b=a√2/2=0.4151×√2/2 nm=0.2935 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers vector的长度），并给出了具体的公式和步骤，最终得出数值结果。 | 知识层次: 题目要求直接应用Burgers向量的计算公式，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（Burgers vector计算公式）进行简单数值计算，无需多步骤推导或复杂公式组合。解题过程仅涉及基本代数运算和平方根计算，属于该题型中最基础的层级。" + }, + { + "idx": 2406, + "question": "If the dislocation is an edge dislocation, can it decompose into an extended dislocation? Write the decomposition reaction equation.", + "answer": "As long as the stacking fault energy is sufficiently low, any type of perfect dislocation on the {111} plane can decompose into an extended dislocation. If the given perfect dislocation decomposes into an extended dislocation, the reaction equation is a/2[101]→a/6[112]+a/6[21̅1]. This is because the decomposition into an extended dislocation involves the perfect dislocation splitting into two Shockley partial dislocations, whose Burgers vectors are of the a/6<112> type, with a Burgers vector length of b=a√6/6=0.35√6/6 nm=0.147 nm. Additionally, the slip planes of the dislocations before and after decomposition remain the original slip plane. Therefore, when writing the reaction equation, two points must be ensured: (1) the Burgers vectors of the two Shockley partial dislocations must lie on the (111) plane; (2) the Burgers vector must be conserved in the decomposition equation, meaning the Burgers vector of the dislocation before decomposition equals the sum of the Burgers vectors of the two dislocations after decomposition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释边缘位错是否可以分解为扩展位错，并写出分解反应方程。答案提供了详细的文字解释和论述，包括分解条件和反应方程的推导过程，符合简答题的特征。 | 知识层次: 题目要求对位错分解的机理进行深入分析，包括分解条件（堆垛层错能足够低）、分解反应方程的书写（需要考虑Burgers矢量的守恒和方向）、以及分解前后位错的性质变化（如滑移面的保持）。这需要综合运用位错理论、晶体学知识以及Burgers矢量的计算，属于复杂分析和推理的范畴。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求不仅写出分解反应方程，还需要解释分解的条件、分解后的位错类型、柏氏向量的计算和守恒原理，以及分解前后滑移面的关系。这些要求综合了多个知识点，并需要深入理解位错分解的机理，属于该题型中较高难度的题目。" + }, + { + "idx": 2407, + "question": "Verify the correctness of the calculation: The radius of Mg²⁺ ion is 0.078 nm, the radius of O²⁻ ion is 0.132 nm, and the lattice constant of NaCl-type structure is the sum of the diameters of one cation and one anion.", + "answer": "The lattice constant a=2(0.078+0.132) nm=0.420 nm, which is basically consistent with the result of 0.4151 nm calculated based on density.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，验证晶格常数的正确性，并给出了具体的计算过程和结果比较。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，即通过给定的离子半径计算晶格常数，并验证其正确性。不需要多步计算或综合分析，属于基础概念的直接应用。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（半径和与晶格常数的关系）进行简单加法运算，无需任何复杂推导或多步骤计算，完全符合等级1\"单一公式直接计算\"的定义。" + }, + { + "idx": 2408, + "question": "After polishing and etching lithium fluoride polycrystals, etch pits arranged in straight lines with a spacing of 10μm were observed. After applying shear stress, grain boundary dislocations moved perpendicular to the grain boundary plane. Explain the structure of the grain boundary.", + "answer": "The crystal structure of lithium fluoride is a √3-1<1 type structure, and its slip plane is {0}11}. The etch pits reveal the outcrops of dislocations, and the straight-line arrangement of the etch pits indicates that this line is a set of parallel dislocation outcrops, which is a small-angle grain boundary with a dislocation spacing of 10μm. Since the grain boundary dislocations all move perpendicular to the boundary, it indicates that only a set of like-signed dislocations form the grain boundary, which can only be edge dislocations, and the slip plane of the dislocations is perpendicular to the grain boundary. Assuming the dislocation slip plane is (110), then the grain boundary plane is (110), and the Burgers vector of the dislocations can only be [1¯1¯1]¯1¯2. Therefore, this is a symmetric tilt grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶界的结构，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释晶界的结构，涉及位错排列、晶界类型判断、位错运动方向分析等多个复杂概念的综合运用。需要理解位错与晶界的关系、位错类型对晶界性质的影响，并进行逻辑推理和机理解释，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体结构、位错理论和晶界机制知识进行深度推理。解题需要：" + }, + { + "idx": 2409, + "question": "Using the etch pit method, the distance between small-angle grain boundary etch pits was measured to be $[5,8][11]$. X-ray diffraction measured the misorientation between the two grains as 30 ($1\\\\because=0.000280$). What is the magnitude of the Burgers vector of the dislocations in the grain boundary?", + "answer": "Assuming the relationship between the dislocation spacing $n$, the Burgers vector $b$, and the misorientation in the grain boundary can be approximately estimated by the following formula: $$ D={\\\\frac{\\\\tilde{b}}{\\\\theta}} $$. Based on the given data, the Burgers vector $b$ is calculated as $$b=D\\\\pmb{\\\\theta}=6.87\\\\times10^{3}\\\\times30\\\\times0.0002\\\\&(\\\\pi/180)\\\\mathrm{nm}=1.00\\\\mathrm{nm}$$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出Burgers vector的具体数值。解答过程涉及公式应用和单位转换，属于典型的计算题。 | 知识层次: 题目需要应用公式进行多步计算，涉及对位错间距、Burgers向量和晶界取向差之间关系的理解，并需要进行单位转换和数值计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个概念和步骤来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要应用公式进行多步计算，并理解小角度晶界位错间距与位错柏氏矢量之间的关系。题目涉及测量数据的处理、单位转换以及公式推导，但不需要处理复杂多变量或高级数学工具。" + }, + { + "idx": 2410, + "question": "Given the density of a crystal with NaCl-type structure is 3.55 g/cm³, calculate its unit cell lattice constant. A unit cell contains 4 cations and 4 anions, the relative atomic mass of Mg is 24.31, and that of O is 16.", + "answer": "According to the density formula ρ=4(24.31+16)/(a³×6.022×10²³), solving for the lattice constant a=[4(24.31+16)/(3.55×6.022×10²³)]^(1/3) cm=4.151×10⁻⁸ cm=0.4151 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶格常数，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的密度和相对原子质量计算晶格常数。虽然涉及单位换算和代数运算，但整体上属于直接套用公式的范畴，不需要多步计算或复杂的概念关联。 | 难度: 在计算题中属于简单应用难度，仅需直接套用密度公式并进行简单的代数运算即可求解。题目提供了所有必要参数，且计算步骤明确，无需多公式组合或复杂推导。" + }, + { + "idx": 2411, + "question": "Based on the calculation results at 700°C and 550°C, find the average bonding energy between sulfur atoms and 12 iron atoms (express the answer in kJ/mol and eV).", + "answer": "Averaging over these two temperatures yields -ΔG=69 kJ/mol=0.71 eV. If it is approximately assumed that the distortion energy of sulfur atoms at grain boundaries is negligible, then this value can be considered as the bonding energy between sulfur atoms and Fe atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于计算结果找出硫原子与12个铁原子之间的平均键能，并需要将答案以kJ/mol和eV两种单位表示。解答过程涉及数值计算和单位转换，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（基于不同温度下的计算结果求平均值），并涉及能量单位的转换（kJ/mol到eV），同时需要理解并应用热力学参数（ΔG）与键能之间的关系。虽然题目提供了部分假设条件（忽略晶界硫原子的畸变能），但仍需综合分析计算结果与物理意义，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要基于两个温度下的计算结果进行平均值的求解，并涉及单位转换（kJ/mol到eV）。虽然计算步骤不算特别复杂，但需要理解热力学概念（ΔG）与键能的关系，并做出合理假设（忽略晶界畸变能）。这比简单的单步计算题要求更高，但尚未达到涉及多变量或复杂模型的等级4难度。" + }, + { + "idx": 2412, + "question": "At 700°C (973K), the enrichment rate of sulfur at the grain boundaries of iron is 7170. Estimate the bonding energy between sulfur atoms and iron (answer in kJ/mol and eV).", + "answer": "Since the concentrations at the grain boundaries and within the grains are both much smaller than 1, the simplified formula for concentration segregation is used: -ΔG=8.314×973×ln7170=71.8 kJ/mol =71.8×10^3/(6.022×10^23×1.603×10^-19) eV=0.74 eV", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，最终需要给出具体的数值答案（kJ/mol和eV），解答过程涉及公式推导和单位换算，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解浓度偏析的简化公式并进行单位转换，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联（如浓度简化公式、能量单位转换等），但尚未涉及复杂多变量计算。题目要求将热力学公式与单位换算结合，体现了中等应用层次的知识整合能力。" + }, + { + "idx": 2413, + "question": "At 550°C (823K), the enrichment rate of sulfur at the grain boundaries of γ-Fe is 15700. Estimate the bonding energy between sulfur atoms and iron (provide the answer in kJ/mol and eV).", + "answer": "Since the concentrations at both the grain boundaries and within the grains are much smaller than 1, the simplified formula for concentration segregation is used: -ΔG=8.314×823×ln15700=66.1 kJ/mol =66.1×10^3/(6.022×10^23×1.603×10^-19) eV=0.68 eV", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计硫原子与铁之间的键能，并提供了具体的计算步骤和单位转换，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括使用公式计算能量转换，并涉及浓度和温度的概念关联。虽然计算过程相对直接，但需要理解和应用热力学公式，并进行单位转换，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求从给定的富集率推导出键能，涉及对数运算、单位转换和物理常数的应用，但计算步骤相对明确，没有引入复杂变量或需要高级数学工具。" + }, + { + "idx": 2414, + "question": "A Cu (a=0.3615nm) thin film is deposited on an Au (a=0.4079nm) substrate, and their mismatch is relaxed by misfit dislocations at the interface. If the interface is the (100) plane, determine the magnitude of the Burgers vector of the misfit dislocations and the dislocation spacing.", + "answer": "If the (100) plane is taken as the interface, the two phases remain parallel to each other along the [110] direction at the interface, and their mismatch δ is still 0.121, so the spacing of the misfit dislocations is also 2.256nm. Since the grain boundary dislocations relax the mismatch along the [110] direction, the Burgers vector of the dislocations is [110]/2, and thus the dislocation line is along the [110] direction. There are two [110] directions on the (100) plane, so there are two sets of misfit dislocations on the interface, perpendicular to the [110] directions and mutually forming a 90° angle.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定Burgers矢量的幅度和位错间距，涉及晶格常数和失配度的计算，答案中包含具体的数值结果和方向分析，属于典型的计算题特征。 | 知识层次: 题目涉及多步计算（如计算错配度和位错间距）、概念关联（如界面错配与位错的关系）以及综合分析（如确定位错的Burgers矢量和位错线方向）。虽然不需要复杂的机理分析或创新设计，但需要一定的理解和应用能力来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要理解晶格失配、位错间距和Burgers矢量的概念，并进行多步计算和综合分析。题目涉及多个知识点的关联应用，解题步骤较为复杂，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2415, + "question": "If the Burgers vector magnitude of a grain boundary dislocation is 0.253nm, what is the misorientation between the two sides of the grain boundary?", + "answer": "The misorientation between the two grains at the grain boundary is θ = b/D = (0.253 × 10^-9)/(10 × 10^-6) × (180/π) = 1.45 × 10^-3 degrees.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶界两侧的取向差，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及Burgers矢量和晶界错向角的直接关系，计算过程直接套用公式即可完成，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式θ = b/D进行简单数值计算，无需多步骤推导或复杂公式组合。题目明确给出了所有必要参数，且计算过程仅涉及基本单位换算和三角函数应用，属于典型的\"单一公式直接计算\"类型。" + }, + { + "idx": 2417, + "question": "Consider a two-dimensional rectangular crystal with side lengths $L_{1}$ and $L_{\\\\pm}$ $L_{1}$ and $L_{\\\\perp}$. The interfacial energies for the two sides are $71$ and p, respectively. If the interfacial area remains constant ($L_{1}L_{1}=$ constant), prove that the equilibrium shape satisfies the relation $L_{1}/L_{2}=m g/y_{2}$.", + "answer": "The total surface energy of this crystal is $E=2(L_{1}y+L_{2}y_{2})$. At equilibrium shape, the following relation holds: $$ \\\\mathrm{d}E=2(L_{1}\\\\mathrm{d}\\\\gamma_{1}+\\\\gamma_{1}\\\\mathrm{d}L_{1}+L_{2}\\\\mathrm{d}\\\\gamma_{2}+\\\\gamma_{2}\\\\mathrm{d}L_{2})=0 $$ Since $72$ and $79$ are independent of length, the equation simplifies to $$ \\\\gamma_{1}\\\\mathrm{d}L_{1}+\\\\gamma_{1}\\\\mathrm{d}L_{2}=0 $$ Given that the area $[1L]=$ constant, i.e., $\\\\angle1\\\\mathrm{d}L_{2}+L_{2}\\\\mathrm{d}L_{1}=0$, substituting this relation into the above equation yields $L_{1}:L_{2}=m:21$. Q.E.D.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数学推导和公式应用来证明一个关系式，解答过程中涉及到了微分和代数运算，属于典型的计算题类型。 | 知识层次: 题目需要多步计算和概念关联，包括表面能的计算、平衡条件的推导以及面积恒定条件的应用。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和应用能力来推导出最终的形状关系。 | 难度: 在计算题中属于综合性计算问题，需要理解表面能的概念，应用微分和约束条件进行多步推导。题目涉及变量替换和代数运算，但步骤相对清晰，没有过于复杂的数学处理。" + }, + { + "idx": 2418, + "question": "Two parallel low-angle tilt boundaries have misorientation angles of 6 and degrees, respectively. Is it possible for these two boundaries to merge into a single boundary with a misorientation angle of $\\\\theta_{1}+\\\\theta_{2}$?", + "answer": "The energy of a low-angle grain boundary is $$ \\\\gamma_{_\\\\mathrm{\\\\scriptsize{ab}}}=\\\\gamma_{_0}\\\\theta(\\\\mathcal{A}^{\\\\mathrm{\\\\scriptsize{r}}}-\\\\ln\\\\theta) $$ where $M^{\\\\prime}$ is a constant. The energy before the merging of the two boundaries is $$ \\\\gamma_{\\\\bar{0}}\\\\theta_{\\\\bar{1}}(A^{\\\\prime}-\\\\ln\\\\theta_{1})+\\\\gamma_{\\\\bar{0}}\\\\theta_{\\\\bar{z}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\bar{z}}) $$ The energy after merging is: $$ \\\\gamma_{\\\\mathrm{o}}(\\\\theta_{\\\\mathrm{i}}+\\\\theta_{\\\\mathrm{z}})[A^{\\\\prime}-\\\\mathrm{ln}(\\\\theta_{\\\\mathrm{i}}+\\\\theta_{\\\\mathrm{z}})] $$ The energy difference $\\\\bar{A}E$ before and after merging is: $$ \\\\begin{array}{r l}&{\\\\Delta E=\\\\gamma_{\\\\mathrm{0}}(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})[A^{\\\\prime}-\\\\ln(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})]-\\\\gamma_{\\\\mathrm{0}}\\\\theta_{\\\\mathrm{1}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\mathrm{1}})-\\\\gamma_{\\\\mathrm{0}}\\\\theta_{\\\\mathrm{2}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\mathrm{2}})} &{\\\\qquad=\\\\gamma_{\\\\mathrm{0}}A^{\\\\prime}(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}-\\\\theta_{\\\\mathrm{1}}-\\\\theta_{\\\\mathrm{2}})-\\\\gamma_{\\\\mathrm{0}}[(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})\\\\ln(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})-\\\\theta_{\\\\mathrm{1}}\\\\ln\\\\theta_{\\\\mathrm{1}}-\\\\theta_{\\\\mathrm{2}}\\\\ln\\\\theta_{\\\\mathrm{2}}]} &{\\\\qquad=\\\\gamma_{\\\\mathrm{0}}[\\\\theta_{\\\\mathrm{1}}\\\\ln\\\\frac{\\\\theta_{\\\\mathrm{1}}}{\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}}+\\\\theta_{\\\\mathrm{2}}\\\\ln\\\\frac{\\\\theta_{\\\\mathrm{2}}}{\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}}]}\\\\end{array} $$ Because $y=\\\\frac{1}{2}$ $C A$ and $C H_{2}$ are both positive, $\\\\left|\\\\Pi\\\\right|\\\\left|\\\\hat{H}_{l}\\\\right|\\\\left|\\\\hat{H}_{1}+\\\\hat{H}_{2}\\\\right|\\\\right|$ and $\\\\|\\\\bar{\\\\boldsymbol{\\\\Pi}}\\\\|\\\\hat{\\\\cal{Q}}^{\\\\prime}(\\\\hat{\\\\cal{Q}}_{1}+\\\\hat{\\\\cal{Q}}_{2})\\\\|$ are both less than 0. This process reduces energy, so it can proceed. In fact, during the recovery process of deformed materials, a large number of such processes occur, namely the coarsening of subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案中包含了详细的公式推导和能量变化的分析，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及低角度晶界的能量计算和合并过程的能量变化分析，需要综合运用晶界能量公式、对数运算和能量差计算，并进行机理解释。思维过程需要深入理解晶界能量变化的物理意义，并能够推导出能量差表达式，最终解释材料回复过程中的亚晶粗化现象。这属于复杂分析和机理解释的层次。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目不仅要求考生掌握低角度晶界的能量公式，还需要综合运用能量变化分析、对数运算以及热力学过程推理。解题步骤涉及多个公式推导和能量比较，最后还需要结合材料科学中的实际现象（亚晶粒粗化）进行解释。这种深度和广度的要求明显超出了简单的机理解释，达到了复杂现象全面分析的标准。" + }, + { + "idx": 2419, + "question": "Which side does the marker wire in the diffusion couple move towards?", + "answer": "Because D_Zn > D_Cu, the marker plane moves towards the Cu side.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释扩散偶中标记线的移动方向，并给出了基于扩散系数的解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解扩散偶中标记线的移动原理，并应用扩散系数差异（D_Zn > D_Cu）进行分析，属于多步概念关联和综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要理解扩散偶中标记线的移动原理，并能够比较两种金属的扩散系数（D_Zn > D_Cu），但解题步骤相对直接，主要涉及单一概念的应用和简单分析。不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 2420, + "question": "A diffusion couple is formed by pure copper and a Zn=10° alloy with w(Zn)=3000. A marker wire is inserted at the bonding interface. After annealing at 7851 for 56 days, the marker wire is found to have moved 0.0105πm, with x(Zn)=200 at the marker plane, a concentration gradient (∂x_Zn/∂x)=-0.089 mm^-1, and ∫_{0}^{0.27} x dN_Zn=0.016 mm. Calculate the interdiffusion coefficient D̃ for the alloy with concentration x(Zn)=22.74°.", + "answer": "The diffusion duration is 56 days, i.e., t=56d=56×24×3600s=4838400s. Based on the given data, the interdiffusion coefficient D̃ is: D̃ = (-1)/(2t (dC/dx)) ∫_0^∞ x dC = (-0.016 mm)/(-2×4838400s×0.089 mm^-1) = 1.869×10^-8 mm^2 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了时间单位转换、积分计算和扩散系数的求解，这些都是典型的计算题特征。答案给出了具体的计算步骤和结果，符合计算题的特点。 | 知识层次: 题目需要进行多步计算，包括时间单位转换、浓度梯度计算和积分运算，同时需要理解和应用扩散系数的计算公式。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和步骤来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及扩散偶、标记线移动、浓度梯度等多个概念的综合应用，并需要进行数值积分和单位转换。虽然计算步骤明确，但需要较强的综合分析能力和对扩散理论的深入理解，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 2421, + "question": "To remove hydrogen from the system through palladium membrane diffusion, it is known that the diffusion coefficient of hydrogen in palladium at $500^{\\\\circ}C$ is $1.0\\\\times10^{-8}177^{-15}$. The hydrogen concentrations on both surfaces of a palladium plate are maintained at $2.4 kg/m^{3}$ and $0.61-2^{7}m^{3}$. Under steady-state diffusion, calculate the amount of hydrogen passing through a palladium plate with an area of $0.277^{2}$ and a thickness of $5\\\\pi\\\\pi\\\\pi$ per hour (expressed in $k=1$).", + "answer": "Since this is a steady-state thin-film diffusion problem, and the diffusion coefficient does not vary with concentration, the concentration distribution within the film is linear. According to the problem statement, substituting the corresponding values, the concentration gradient within the film is calculated as: $$\\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}=\\\\frac{0.6-2.4}{5\\\\times10^{-3}}kg/m^{4}=-360\\\\mathrm{kg/m^{-4}}$$ The one-dimensional steady-state problem can be solved using the first law of diffusion: $$J=-D{\\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}}$$ The amount of hydrogen passing through the palladium plate with an area of $0.2171^{3}$ per hour is: $$Q=J\\\\times A\\\\times t=-D{\\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}}.A t=1.0\\\\times10^{-8}\\\\times360\\\\times0.2\\\\times3600\\\\mathrm{kg}=2.592\\\\times10^{-3}\\\\mathrm{kg}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决稳态扩散问题，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律进行综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律进行多步计算，涉及浓度梯度的计算、扩散通量的求解以及最终质量流量的转换。虽然题目提供了明确的参数和公式，但需要学生正确理解并应用这些概念，同时进行单位转换和数值计算，步骤较为复杂，属于中等偏上的难度。" + }, + { + "idx": 2422, + "question": "Assuming that at 1000°C, atoms diffuse through an Al2O3 crystal a distance x in 3h, estimate the time required for Al atoms to diffuse through the same Al2O3 crystal a distance of 9x.", + "answer": "Since the diffusion distance is proportional to the square root of time, when the diffusion distance is 9x, the required time is t2 = (9x)^2 / x^2 * 3h = 243h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过扩散距离与时间的关系公式来估算所需时间，答案也是具体的数值计算结果。 | 知识层次: 题目主要考查扩散距离与时间关系的简单公式应用，仅需一步计算即可得出结果，属于基本公式的直接套用。 | 难度: 在计算题中属于简单公式应用计算难度。题目仅需应用扩散距离与时间平方根成正比的基本公式（x∝√Dt），通过简单的代数运算即可得出答案。虽然需要理解扩散距离与时间的关系，但不需要组合多个公式或进行复杂推导，解题步骤清晰直接。" + }, + { + "idx": 2423, + "question": "A $C_{5}^{5}$ Fe plate with a thickness of $1.2\\\\pi m m$. One side is carburizing and the other side is decarburizing atmosphere, with surface concentrations of $\\\\mathrm{Pr}(C)=0.01200$ and $1+1(1-)=0.007500$, respectively. At $750-10$, when steady-state diffusion is achieved in the plate, the measured diffusion flux is $1.4\\\\times10^{-8}k g/m^{2}\\\\cdot5$. Find the diffusion coefficient of carbon at this temperature. $\\\\mathrm{{.}_{W}(C)=0.8\\\\%\\\\equiv60k g/m^{3})}$", + "answer": "First, convert the mass concentration to volume concentration. Since $\\\\begin{array}{r}{w(\\\\mathbf{C})=0,8\\\\%=60\\\\mathrm{kg/m^{3}}}\\\\end{array}$, the volume concentrations of $\\\\mathbb{C}_{1}{=}\\\\mathrm{w}(\\\\mathbb{C})=0,012\\\\%$ and $\\\\mathrm{C_{2}}{=}{}_{\\\\mathrm{W}}(\\\\mathrm{C}){=}0.00750/\\\\$ are: $$ C_{1}=\\\\frac{0.012}{0.8}\\\\times60=0.9\\\\mathrm{kg\\\\cdotm^{-3}}\\\\quad C_{2}=\\\\frac{0.0075}{0.8}\\\\times60=0.5625\\\\mathrm{kg\\\\cdotm^{-3}}$$ This is a one-dimensional steady-state diffusion problem, and the diffusion coefficient does not vary with concentration, so the concentration distribution in the plate is linear. Based on the given data, the concentration gradient in the plate can be calculated: $$ \\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}=\\\\frac{0.5625-0.9}{1.2\\\\times10^{-3}}\\\\mathrm{kg/m^{4}}=-281.25\\\\mathrm{kg/m^{4}}$$ According to the one-dimensional steady-state diffusion equation, the diffusion coefficient is $$ {\\\\cal D}=-J{\\\\frac{\\\\mathrm{d}\\\\mathrm{r}}{\\\\mathrm{d}C}}=1.4\\\\times10^{\\\\mathrm{~8}}\\\\times{\\\\frac{1}{281.25}}\\\\mathrm{m}^{2}/\\\\mathrm{s}=4.98\\\\times10^{-11}\\\\mathrm{m}^{2}/\\\\mathrm{s}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散系数，解答过程中涉及浓度转换、浓度梯度计算以及扩散系数的推导，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将质量浓度转换为体积浓度，应用一维稳态扩散方程计算扩散系数，并进行浓度梯度的计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点和进行多步计算。 | 难度: 在计算题中属于综合性计算问题，需要进行多步计算和概念关联。题目涉及浓度转换、浓度梯度计算以及扩散系数的求解，需要综合运用多个知识点和公式。虽然计算步骤较多，但每一步都较为明确，没有过于复杂的变量或概念，因此在同类题型中属于中等难度。" + }, + { + "idx": 2424, + "question": "A diffusion couple is composed of pure copper and a Zn=10° alloy with w(Zn)=3000. A marker wire is inserted at the bonding interface. After annealing at 7851 for 56 days, the marker wire is found to have moved 0.0105πm. The marker plane has x(Zn)=200, the concentration gradient (∂x_Zn/∂x)=-0.089 mm^-1, and ∫_{0}^{0.27} x dN_Zn=0.016 mm. Determine the intrinsic diffusion coefficients of Zn and Cu in the alloy with x(Zn)=22.74°.", + "answer": "The velocity of the marker plane movement v = marker displacement / (2×time) = 0.0105 mm / (2×4838400s) = 1.085×10^-9 mm/s. According to the relations v = (D_Cu - D_Zn) (dx_Zn/dy) and D̃ = (x_Zn D_Cu + x_Cu D_Zn), at the marker plane where x_Zn=0.22, the simultaneous equations are: (D_Cu - D_Zn)×(-0.089 mm^-1) = 1.085×10^-9 mm/s and (0.22 D_Cu + 0.78 D_Zn) = 1.869×10^-8 mm^2 s^-1. Solving the simultaneous equations yields: D_Zn = 2.137×10^-8 mm^2 s^-1, D_Cu = 0.918×10^-8 mm^2 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算标记平面的移动速度、建立联立方程并求解扩散系数等步骤。答案提供了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散理论中的多个公式（如扩散系数与浓度梯度的关系、互扩散系数等），并通过联立方程求解。虽然不需要复杂的机理分析或创新设计，但需要综合理解和应用多个知识点进行计算。 | 难度: 在计算题中属于复杂多变量计算难度，需要处理多个变量（浓度梯度、时间、位移等）并建立联立方程求解。题目涉及扩散偶实验数据的综合处理，要求准确应用扩散系数关系式并进行数值解算，解题步骤复杂且对计算精度要求高。" + }, + { + "idx": 2425, + "question": "Calculate the diffusion rate of AI through Al2O3 at a temperature 10 times that at 1000°C (i.e., find D(T)=10D(1000°C)). The activation energy Q for AI diffusion in Al2O3 crystal is known to be 477 kJ/mol.", + "answer": "According to the relationship between diffusion coefficient and temperature D = D0 exp(-Q/RT), let T1=1000°C=1273K, and find the temperature T2 where D(T2)=10D(T1). From 10 = exp(-Q/R (1/T2 - 1/T1)), we get 1/T2 = 1/T1 - (R ln10)/Q = 1/1273K - (8.314*ln10)/477000 = 7.454×10^-4 K^-1. Therefore, T2=1341.6K, and the temperature increases by 68.6K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（扩散系数与温度的关系公式）来求解特定温度下的扩散速率，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要应用扩散系数的温度依赖关系公式，进行多步计算和温度转换，涉及对公式的理解和数值计算能力，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题。题目需要应用扩散系数与温度的Arrhenius关系式，进行多步数学推导和计算，包括对数运算和温度转换。虽然不涉及多变量，但需要准确理解物理概念并正确执行代数运算步骤，属于中等偏上的计算复杂度。" + }, + { + "idx": 2426, + "question": "The turbine blade is oxidized as metal atoms reach the metal surface through oxide diffusion and react with oxygen to form oxides. This material forms a $B H//H T$ thick oxide layer after $50\\\\textcircled{<}107$. What is the thickness of the oxide layer after 100h at the same temperature?", + "answer": "This process involves two sub-processes: diffusion of metal atoms in the oxide layer and the reaction of metal atoms with oxygen. Because diffusion is slow, the entire process is controlled by diffusion. The diffusion distance $l$ and diffusion time $^ Ḋ t Ḍ$ follow a square root relationship, i.e., $l=11$ after $5-50=50$ holding time $\\\\lfloor0\\\\rfloor_{\\\\lfloor1\\\\rfloor}$, forming $3[1171(l)$. Then, the oxide layer thickness $l-$ after $\\\\lvert[\\\\rvert]\\\\rvert\\\\lvert\\\\chi\\\\rvert/\\\\lvert\\\\chi\\\\rvert)$ is $$ I_{\\\\mathrm{{z}}}=I_{\\\\mathrm{{|\\\\sqrt{\\\\frac{t_{\\\\mathrm{z}}}{t_{\\\\mathrm{l}}}}=8\\\\sqrt{\\\\frac{100}{10}}\\\\mu\\\\mathrm{{m}=25.3\\\\upmu5}}}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氧化层的厚度，答案中包含了具体的计算公式和数值代入过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解扩散控制过程以及扩散距离与时间的关系，并应用平方根关系进行计算。虽然计算本身不复杂，但需要综合分析扩散控制和反应过程的关系。 | 难度: 在计算题中属于综合性计算问题。题目涉及扩散控制的氧化层生长过程，需要理解扩散距离与时间的平方根关系，并进行多步计算。虽然计算本身不复杂，但需要正确关联概念和公式应用，属于中等应用层次的计算题。" + }, + { + "idx": 2427, + "question": "At what temperature can the contribution of grain boundary diffusion be neglected?", + "answer": "From the data, it can be seen that at 1200K, the difference between Dapp and D1 is already very small, and the special contribution of grain boundary diffusion can be neglected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么温度下晶界扩散的贡献可以被忽略，答案提供了具体的温度并解释了原因，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解晶界扩散的概念，并能根据数据判断在特定温度下晶界扩散的贡献是否可以忽略。这涉及到对扩散机制的理解和数据的综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要综合分析实验数据（Dapp与D1的差异）并理解晶界扩散的特殊贡献，但解题步骤相对明确，主要涉及温度对扩散机制影响的单一维度分析。相比需要多角度论证或深度关联不同理论的题目（等级4-5），本题更侧重基础概念的应用和实验现象的解读，符合等级3\"综合分析和说明\"的标准。" + }, + { + "idx": 2428, + "question": "If the diameter of polyester (PET) carpet fibers is doubled to 100 microns, how much time is required for water, dye, and dye bags to penetrate to the center of the fiber, respectively?", + "answer": "The penetration depth is 50 microns. The time required for water to penetrate to the center of the fiber is t=(50×10^-6)^2/(2×1.0×10^-12)=1250 s; the time required for dye to penetrate to the center of the fiber is t=(50×10^-6)^2/(2×1.0×10^-13)=12500 s; the time required for dye bags to penetrate to the center of the fiber is t=(50×10^-6)^2/(2×1.0×10^-14)=125000 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解水、染料和染料袋渗透到纤维中心所需的时间，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用扩散方程计算渗透时间，属于直接套用公式的简单应用层次。虽然涉及不同物质的扩散系数，但计算过程单一且直接，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目虽然涉及三个不同的物质（水、染料、染料袋）的渗透时间计算，但每个计算都直接套用相同的扩散公式t=d²/(2D)，仅需替换不同的扩散系数D值。解题步骤高度重复，不需要公式组合或复杂推导，属于基本公式的直接应用。" + }, + { + "idx": 2429, + "question": "In polycrystalline ceramics, does diffusion predominantly occur along grain boundaries or through the lattice?", + "answer": "Grain boundaries are fast paths for diffusion, so in polycrystals, if the temperature is not too high, grain boundary diffusion predominates. However, at very high temperatures, the difference between grain boundary diffusion and lattice diffusion diminishes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对扩散机制进行解释和论述，答案提供了详细的文字解释，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目不仅需要理解晶界扩散和晶格扩散的基本概念，还需要分析温度对扩散机制的影响，涉及多因素的综合考虑和概念关联。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及多晶陶瓷中扩散路径的综合分析，但只需比较晶界扩散和晶格扩散在不同温度条件下的主导性，不需要多角度或深度关联性分析。解题步骤相对直接，主要考察对扩散机制和温度影响的基本理解与应用能力。" + }, + { + "idx": 2430, + "question": "Both Ge and Cu exhibit self-diffusion via a vacancy mechanism. When diffusion occurs at comparable temperatures, which one has a larger self-diffusion coefficient? Why?", + "answer": "Referring to Appendix B of the materials, the melting points of Ge and $[\\\\frac{\\\\pi}{2}]$ are $\\\\textcircled{1}17.57.757$ and $108.1.575\\\\times$, respectively. At first glance, it might seem that Cu's self-diffusion coefficient is lower than Ge's at comparable temperatures. However, $111$ crystal is metallically bonded, while Ge crystal is covalently bonded. Covalent bonds are much stronger than metallic bonds. Therefore, in reality, $\\\\sum11$'s self-diffusion coefficient is higher than Ge's.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来比较Ge和Cu的自扩散系数，并说明原因。答案中包含了详细的解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要综合运用材料科学中的扩散机制、键合类型和熔点等知识，进行推理分析。不仅要求理解自扩散系数的概念，还需要比较不同键合类型对扩散行为的影响，并解释原因。这涉及到多个概念的关联和深层次的机理解释，属于复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用材料科学中的扩散机理、晶体结构和键合性质等知识，进行多层次的推理分析。具体体现在：" + }, + { + "idx": 2431, + "question": "Is the diffusion in oxide ceramics a vacancy exchange mechanism or a rotary exchange mechanism?", + "answer": "The bonding in oxide ceramics is ionic bonding, and the diffusion mechanism in ionic crystals is primarily the vacancy exchange mechanism. The activation energy for the rotary exchange mechanism is too high and often disrupts the ionic bonding, so it cannot be the diffusion mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散机制的类型，并提供了详细的文字解释和论述，而不是从多个选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目要求分析氧化物陶瓷中的扩散机制，涉及对离子晶体中扩散机理的理解和比较，需要综合运用材料科学中的扩散理论和晶体缺陷知识，进行推理分析，解释为什么空位交换机制是主要扩散机制，而旋转交换机制由于活化能过高和破坏离子键而不适用。这超出了基础概念记忆和简单应用的层次，属于复杂分析的范畴。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅掌握氧化物陶瓷中扩散的基本机制，还需要理解离子键合对扩散机制选择的影响，并能比较空位交换机制和旋转交换机制的活化能差异。这需要综合运用材料科学和固体物理的知识，进行一定深度的推理分析，但尚未达到全面分析复杂现象的最高难度等级。" + }, + { + "idx": 2433, + "question": "The diameter of polyester (PET) carpet fiber is 50 micrometers, immersed in a dye bath containing water, dye, and dye bags at boiling temperature. The diffusion coefficients of water, dye, and dye bags are 1.0×10^-12 m²/s, 1.0×10^-13 m²/s, and 1.0×10^-14 m²/s, respectively. Estimate the time required for water, dye, and dye bags to penetrate into the center of the fiber.", + "answer": "Using the simple one-dimensional diffusion distance-time relationship l=√(2Dt) for approximate estimation, the penetration depth is 25 micrometers. The time required for water to penetrate into the fiber center is t=(25×10^-6)^2/(2×1.0×10^-12)=312.5 s; the time required for dye to penetrate into the fiber center is t=(25×10^-6)^2/(2×1.0×10^-13)=3125 s; the time required for dye bags to penetrate into the fiber center is t=(25×10^-6)^2/(2×1.0×10^-14)=31250 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用扩散距离-时间关系公式 l=√(2Dt)）来估算水、染料和染料袋渗透到纤维中心所需的时间。答案提供了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式（一维扩散距离-时间关系）的直接应用和简单计算，无需多步推理或综合分析。虽然需要理解扩散系数的概念，但整体思维过程较为直接，属于基础知识的简单应用层面。 | 难度: 在计算题中属于最低难度，仅需直接套用单一扩散公式l=√(2Dt)进行简单数值计算，无需公式组合或复杂推导。题目明确给出了所有必要参数，计算过程仅涉及基本代数运算，属于典型的\"直接套用公式型\"计算题。" + }, + { + "idx": 2434, + "question": "Given the volume diffusion coefficient of silver D1=7.2×10^-5 exp(-190 kJ/mol / (R T)) m²·s^-1 and the grain boundary diffusion coefficient Db=1.4×10^-5 exp(-90 kJ/mol / (R T)) m²·s^-1, with a grain size of 7×10^-5 m and a grain boundary thickness of 5×10^-10 m, calculate the effective diffusion coefficient Dapp at temperatures 577°C, 727°C, and 0.776 Tm.", + "answer": "The apparent diffusion coefficient of a polycrystal containing grain boundaries is expressed as Dapp=f Db + (1-f) D1, where f is the fraction of defects (grain boundaries). Assuming the grains are cubes with side length a equivalent to the grain diameter, each face of the cube is shared by adjacent cubes, so there are only 3 grain boundaries per cube, hence f≈3δ/d=7.5×10^-5. The calculation results are as follows: Temperature K: 800, 1000, 1200; D (m²·s^-1): 2.82×10^-17, 8.5×10^-15, 3.86×10^-13; Db (m²·s^-1): 1.86×10^-11, 2.78×10^-10, 1.69×10^-9; Dapp (m²·s^-1): 1.42×10^-15, 2.94×10^-14, 5.13×10^-13; Dapp/D: 50.47, 3.44, 1.33.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出不同温度下的有效扩散系数Dapp的具体数值。解答过程涉及多个步骤的计算和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散系数的公式，理解晶界扩散和体积扩散的区别，并进行温度转换和有效扩散系数的综合计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用有效扩散系数的概念，进行多步计算（包括温度转换、指数计算、比例计算等），同时需要综合分析晶界扩散和体积扩散的贡献。虽然计算步骤较多，但题目提供了明确的公式和参数，降低了部分难度。" + }, + { + "idx": 2435, + "question": "How is texture formed in crystals?", + "answer": "A crystal is a three-dimensionally periodic ordered arrangement, which has a certain orientation relative to a reference coordinate. The orientations of the grains in a polycrystal have an orientation distribution relative to the reference coordinate. If the orientation distribution of the polycrystal deviates from a random distribution, texture is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体中织构的形成过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查晶体织构形成的基本概念和定义，主要涉及对晶体取向分布的理解和记忆，属于基础概念层次的知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求解释晶体中织构的形成，涉及晶体结构、晶粒取向分布等基础概念，但不需要复杂的体系阐述或深入分析。回答需要清晰地描述取向分布与随机分布的偏离如何导致织构形成，属于对基本原理的记忆和简单应用。" + }, + { + "idx": 2436, + "question": "The critical resolved shear stress of aluminum is $2.40\\\\approx10^{5}$ Pa. When the tensile axis is [001], what is the tensile stress required to cause yielding?", + "answer": "The relationship between tensile stress $\\\\sqrt{h}$ and the resolved shear stress on the slip system is =coscos, where and are the angles between the tensile direction and the slip direction and the normal to the slip plane, respectively. The crystal structure of aluminum is fcc, and the slip system is $11117=110.3$. When the tensile axis is [001], since it is perpendicular to [110] and [110], the resolved shear stress on the slip systems composed of them is 0, and they will not activate. The geometric relationship between the [001] axis and its slip systems is equivalent, and their resolved shear stresses are equal. Taking the (111)[011] slip system as an example, the tensile stress required to cause yielding is calculated. The cosine of the angle $\\\\varphi$ between [001] and the slip plane normal [111], cos$\\\\varphi$, and the cosine of the angle $\\\\lambda$ between [001] and the slip direction [011], cos$\\\\lambda$, are respectively $$ \\\\cos\\\\varphi={\\\\frac{1}{\\\\sqrt{1}{\\\\sqrt{3}}}}={\\\\frac{1}{\\\\sqrt{3}}}\\\\cos\\\\lambda={\\\\frac{1}{\\\\sqrt{1}{\\\\sqrt{2}}}}={\\\\frac{1}{\\\\sqrt{2}}}$$ When the critical resolved shear stress $\\\\frac{\\\\sqrt{1}}{2}=\\\\frac{1}{2}$ is $2.40\\\\times0^{-}10^{5}Pa$, the corresponding stress $\\\\alpha$ is the yield stress: $$ \\\\sigma_{\\\\circ}={\\\\frac{\\\\tau_{\\\\circ}}{\\\\cos\\\\varphi\\\\cos\\\\lambda}}=2.4\\\\times10^{5}\\\\times{\\\\sqrt{3}}\\\\times{\\\\sqrt{2}}\\\\mathbf{Pa}=5.89\\\\times10^{5}\\\\mathbf{Pa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定所需的拉伸应力，解答过程中涉及到了角度计算、余弦值计算以及临界剪切应力的应用，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括角度计算、临界分切应力与拉伸应力的转换，以及对FCC晶体滑移系统的理解。虽然涉及基础概念，但需要综合应用多个知识点进行计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要理解临界分切应力的概念，掌握晶体学方向的计算方法，并进行多步骤的数学运算。虽然涉及多个概念和计算步骤，但整体思路清晰，属于中等应用层次的计算题。" + }, + { + "idx": 2437, + "question": "For a face-centered cubic crystal stretched along the [131] axis, determine the resolved shear stress of the slip system (111)[10-1]. The tensile stress is 6.9×10^5 Pa", + "answer": "For the slip system (111)[10-1], the cosine of the angle between [131] and the slip plane normal [111] is cosφ=5/(√3×√11)=0.870; the cosine of the angle between [131] and the slip direction [10-1] is cosλ=(1×1 + 3×0 + 1×(-1))/(√11×√(1+0+1))=0/(√11×√2)=0. The resolved shear stress τ=6.9×10^5×0.870×0 Pa=0 Pa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定滑移系的分切应力，解答过程涉及角度计算和应力分解，最终给出具体数值结果。 | 知识层次: 题目需要多步计算（包括方向余弦计算和应力分解），涉及晶体学方向指数的理解和应用，以及剪切应力公式的综合运用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体学中的方向指数和平面指数，掌握剪切应力分解的计算方法，并进行多步计算。虽然计算步骤较多，但变量相对较少，且不需要处理复杂的多变量情况。" + }, + { + "idx": 2438, + "question": "Mg2+ diffuses in MgO. What concentration of trivalent cation impurities needs to be added near the melting point of 2800°C to ensure that Mg2+ mainly diffuses via the non-intrinsic vacancy mechanism?", + "answer": "When the concentration of non-intrinsic vacancies exceeds that of intrinsic vacancies, the non-intrinsic vacancy mechanism becomes the dominant diffusion mechanism. In MgO crystals, the formation enthalpy of Schottky defects is ΔH = 6 eV (as shown in Table 6-2 of the textbook). Thus, the equilibrium concentration of Schottky vacancies at 2800°C is: xv ≈ exp(-ΔHc / 2kBT) = exp(-6 / (2 × 8.62 × 10^-5 × 3073)) = 1.206 × 10^-5. If the non-intrinsic vacancy concentration exceeds this equilibrium intrinsic vacancy concentration, diffusion will primarily occur via the non-intrinsic vacancy mechanism. Now, by adding trivalent cations, every two trivalent cations replacing two Mg2+ ions will generate one cation vacancy. To achieve a non-intrinsic cation vacancy concentration of 1.206 × 10^-5, the required trivalent cation concentration x is: x = 2 × 1.206 × 10^-5 = 2.412 × 10^-5. Therefore, at 2800°C, for Mg2+ in MgO to mainly diffuse via the non-intrinsic vacancy mechanism, the trivalent cation impurity concentration must exceed 2.412 × 10^-5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定所需的杂质浓度，解答过程中涉及到了热力学参数的计算和化学计量关系的推导，最终给出了具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解非本征空位机制、计算本征空位浓度，并通过添加三价阳离子的浓度来影响扩散机制。虽然计算过程较为直接，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及Schottky缺陷形成焓的计算、非本征空位浓度的确定以及三价阳离子掺杂浓度的推导，步骤较为复杂，但未涉及多变量或高度抽象的数学处理。" + }, + { + "idx": 2439, + "question": "For a face-centered cubic crystal stretched along the [131] axis, determine the resolved shear stress on the slip system (111)[0-11]. The tensile stress is 6.9×10^5 Pa.", + "answer": "According to the relationship between tensile stress and resolved shear stress on the slip system, τ=σcosλcosφ. For the slip system (111)[0-11], the cosine of the angle between [131] and the slip plane normal [111], cosφ, and the cosine of the angle between [131] and the slip direction [0-11], cosλ, are: cosφ=(1×1 + 3×1 + 1×1)/(√(1+1+1)×√(1+9+1))=5/(√3×√11)=0.870; cosλ=(1×0 + 3×(-1) + 1×1)/(√(1+9+1)×√(0+1+1))=-2/(√11×√2)=-0.426. The resolved shear stress τ=6.9×10^5×0.870×(-0.426) Pa=-2.56×10^5 Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（τ=σcosλcosφ）来确定解析剪切应力，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要计算角度余弦并应用剪切应力公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算面心立方晶体在特定拉伸方向下的分解剪应力，涉及矢量点积、角度计算和应力分解公式的综合应用。虽然计算步骤明确，但需要正确理解和关联晶体学方向指数、滑移系统等概念，并准确执行多步数学运算，属于该题型内中等偏上的难度。" + }, + { + "idx": 2441, + "question": "What are the similarities between crystal texture and polymer texture in a broad sense?", + "answer": "In a broad sense, the textures of the two are similar.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对晶体织构和聚合物织构的相似性进行文字解释和论述，答案也是以文字形式呈现的简要回答 | 知识层次: 题目要求比较晶体和聚合物织构的相似性，这需要理解两者的基本概念，并进行概念关联和综合分析。虽然不涉及复杂计算或深度推理，但需要一定的思维深度来比较和解释两者的相似性。 | 难度: 在简答题中属于中等难度，需要对晶体和聚合物织构的概念有基本理解，并能进行简单的比较和综合分析。题目要求从广义角度分析两者的相似性，需要一定的概念关联能力，但不需要深入的多角度或深度关联性分析。" + }, + { + "idx": 2442, + "question": "How is texture formed in polymers?", + "answer": "Under the action of tensile force on polymers, the molecular chains in the amorphous regions of the polymer become ordered in one-dimensional or two-dimensional directions. In the crystalline regions (folded lamellae), the layers rotate to orient along the tensile axis, meaning the direction of the molecular chains and the orientation of the crystalline blocks are not randomly distributed, thus forming the polymer texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物中纹理的形成过程，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释聚合物中织构形成的机理，涉及分子链在非晶区和晶区的有序排列和取向变化，需要综合运用材料科学中的聚合物结构、结晶行为和力学变形等知识，进行推理分析和机理解释。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求详细描述聚合物纹理形成的机理，涉及非晶区和晶区的分子链排列变化，需要综合运用聚合物结构和力学行为的知识进行推理分析。虽然不涉及多因素交互作用的全面分析（等级5），但对单一现象的机理解释已达到较高深度要求。" + }, + { + "idx": 2443, + "question": "For a ceramic oxide, in which temperature ranges does the vacancy diffusion mechanism occur as intrinsic or extrinsic?", + "answer": "If the ceramic oxide is a solid solution, the incorporation of solutes with different valences will generate extrinsic point defects. The concentration of intrinsic point defects changes drastically with temperature, while the concentration of extrinsic point defects does not vary with temperature. Therefore, at low temperatures, the concentration of extrinsic vacancies is higher than that of intrinsic vacancies, and this difference becomes more pronounced as the temperature decreases. Thus, in the low-temperature range, the extrinsic vacancy diffusion mechanism dominates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷氧化物中空位扩散机制在何种温度范围内表现为本征或外征，答案通过文字论述解释了不同温度下本征和外征空位的浓度变化及其对扩散机制的影响，属于需要文字解释和论述的简答题。 | 知识层次: 题目要求分析陶瓷氧化物中空位扩散机制在不同温度范围内的主导类型（本征或外征），需要综合运用点缺陷化学、扩散机制和温度影响等多方面知识进行推理分析。解答过程涉及本征缺陷和外征缺陷的浓度随温度变化的对比，以及由此导致的扩散机制转变，属于对复杂概念的深度理解和综合分析。 | 难度: 在简答题（复杂分析类）中，该题目要求综合运用材料科学中的点缺陷理论、扩散机制和温度影响等多方面知识，进行机理解释和现象分析。需要考生不仅掌握基础概念，还要能够将不同知识点串联起来，解释温度范围对扩散机制的影响差异。这种综合推理和深度分析的要求，符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 2444, + "question": "What changes occur in polymer texture when heated?", + "answer": "Heating can cause oriented polymers to disorient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物在加热时发生的纹理变化，需要文字描述和论述，而不是选择、判断或计算 | 知识层次: 题目考查聚合物在加热时纹理变化的基本概念，主要涉及记忆和理解聚合物受热后取向变化的原理，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释聚合物在加热时发生的纹理变化，需要理解并描述聚合物取向和热效应的基本原理，但不需要涉及复杂的相互作用或多步骤分析。这比简单定义类问题（等级1）要求更高的理解深度，但尚未达到需要系统阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2445, + "question": "What are the differences in the formation mechanisms between crystal texture and polymer texture?", + "answer": "Polycrystalline texture is formed by the deformation and rotation of grains under force, while polymer texture is formed by the ordered arrangement and distribution of molecular chains under force, along with the rotational orientation of crystalline blocks in the amorphous region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体织构和聚合物织构的形成机制差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较晶体织构和聚合物织构的形成机制，涉及不同材料体系（金属/聚合物）的微观结构演变机理分析。需要综合理解晶粒变形/旋转机制与分子链有序排列/晶区取向的差异，属于多知识点关联的机理对比分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对晶体织构和高分子织构的形成机理进行深度解释，涉及多晶体的晶粒变形旋转与高分子链有序排列等专业概念的对比分析。虽然不需要全面分析复杂现象(等级5)，但需要准确描述两种不同材料体系的织构形成机制差异，属于机理深度解释范畴(等级4)。" + }, + { + "idx": 2446, + "question": "The possible slip planes for a body-centered cubic crystal are {110}, {112}, and {123}. If the slip direction is [1-11], what are the specific slip systems?", + "answer": "The slip direction of a slip system must lie on its slip plane. According to the crystallographic zone law, when the slip direction is [1-1 1], for the {110} slip plane, the possible slip planes are (110), (011), and (10-1). For the {112} slip plane, the possible slip planes are (121), (21-1), and (-112). For the {123} slip plane, the possible slip planes are (132), (231), (32-1), (-123), (-213), and (31-2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定具体的滑移系统，而不是从选项中选择或进行数值计算。答案提供了详细的解释和列举，符合简答题的特征。 | 知识层次: 题目需要应用晶体学中的滑移面和滑移方向的知识，通过晶带定律进行多步分析和计算，确定具体的滑移系统。这涉及到概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识（如晶面指数、滑移系定义、晶带定律）进行多步分析。题目要求不仅识别符合条件的滑移面，还需通过计算验证滑移方向是否位于各滑移面上，涉及多个晶面族的系统性排查（3类滑移面共需验证12种组合）。相比同题型的3级题目（如单一滑移系判断），本题目对空间几何关系的理解深度和计算复杂度显著提升，属于需要多角度分析论述的层级。" + }, + { + "idx": 2447, + "question": "When using X-ray detection, how does the diffraction of polycrystalline texture appear?", + "answer": "The diffraction of polycrystalline texture appears as the diffraction rings of polycrystals becoming discontinuous rings, and in extreme cases, turning into diffraction spots like those of single crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释X射线检测中多晶织构的衍射现象，答案提供了详细的文字描述和解释，符合简答题的特征。 | 知识层次: 题目需要理解多晶织构在X射线衍射中的表现，并解释衍射环不连续甚至转变为衍射点的现象。这涉及对X射线衍射原理和多晶织构特性的综合理解，以及不同结构衍射模式的关联分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解多晶织构的衍射现象，并能描述其衍射环的变化特征。虽然涉及一定的综合分析，但不需要多角度或深度关联性分析，主要考察对基本概念的理解和应用能力。" + }, + { + "idx": 2448, + "question": "What is the critical curvature radius of particles that substantially affects the solubility of Fe3C in α-Fe? Given the interfacial energy of Fe3C is 0.71 J/m², and the molar volume of Fe is 23.4×10^-6 m³/mol.", + "answer": "When the particle curvature radius is large (e.g., 1000nm), the solubility already approaches the equilibrium concentration. When the curvature radius exceeds this size, it no longer has a substantial effect on solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释临界曲率半径对Fe3C在α-Fe中溶解度的影响，并提供相关参数，答案以文字解释的形式给出，而非计算或选择。 | 知识层次: 题目涉及界面能和摩尔体积的概念应用，需要理解临界曲率半径对溶解度的影响，并进行一定的综合分析。虽然不涉及复杂的多步计算，但需要将多个概念关联起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。题目要求考生不仅需要理解Gibbs-Thomson效应与溶解度之间的关系，还需要进行多步计算（如临界曲率半径的计算），并综合分析界面能和摩尔体积对溶解度的影响。此外，题目还要求考生能够解释为什么超过一定曲率半径后溶解度不再显著变化，这需要多角度的分析论述。因此，在简答题题型内，该题目属于等级4难度。" + }, + { + "idx": 2449, + "question": "The equilibrium solubility of Fe3C in α-Fe measured by internal friction method is given by C=0.736exp(-4850/T), where T is the temperature. Determine the equilibrium solubility of Fe3C in α-Fe at 627°C (i.e., 900K).", + "answer": "C∞=0.736exp(-4850/T)=0.736exp(-4850/900)=3.36×10^-3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式进行数值计算，以确定Fe3C在α-Fe中的平衡溶解度。答案是通过代入温度值到公式中计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目仅需将给定温度代入公式进行简单计算，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用给定的单一公式进行数值计算，无需额外的公式组合或复杂步骤。" + }, + { + "idx": 2450, + "question": "When using X-ray detection, how does the diffraction of polymer texture appear?", + "answer": "The diffuse rings of polymer texture consist of diffuse peaks (rather than the discrete reflections observed in crystals).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物纹理在X射线检测中的衍射表现，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对聚合物X射线衍射图案的基本特征的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释聚合物纹理在X射线检测中的衍射表现，涉及对聚合物纹理衍射环和漫射峰的基本概念描述，但不需要复杂的体系阐述或多步骤推理。属于对基础概念的记忆和简单应用范畴。" + }, + { + "idx": 2451, + "question": "At 627°C (i.e., 900K), what is the solubility of Fe3C particles with a radius of 100nm in α-Fe? The interfacial energy of Fe3C is known to be 0.71 J/m², and the molar volume of Fe is 23.4×10^-6 m³/mol.", + "answer": "Cr=C∞(1+(2×23.4×10^-6×0.71)/(8.314×900×100×10^-9))=3.36×10^-3(1+4.440×10^-9/100×10^-9)=3.509×10^-3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出具体的溶解度数值。答案展示了详细的公式应用和计算过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解溶解度与界面能、温度、粒子半径之间的关系，并进行数值计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式和概念（如溶解度公式、界面能、摩尔体积等），并进行多步数值计算。虽然计算步骤较多，但题目提供了所有必要参数，且没有涉及过于复杂的变量关系，因此属于该题型内的中等偏上难度。" + }, + { + "idx": 2453, + "question": "For the allotropic transformation of a pure metal $(x\\\\rightarrow\\\\beta)$, at a certain degree of undercooling, the volume Gibbs free energy difference between the two phases is $7\\\\times10^{8} kJ/m^{3}$, and the interfacial energy is $0.5 J/m^{2}$. If the strain energy of nucleation is neglected, calculate the critical nucleus size and the critical nucleation work for forming a cubic nucleus.", + "answer": "For a cubic nucleus, the critical edge length $a^{*}=-\\\\frac{4\\\\gamma}{\\\\Delta G_{V}}=\\\\frac{4\\\\times0.6}{7\\\\times10^{8}}m=3.428\\\\times10^{-9}m$. The critical nucleation work is $\\\\Delta G^{*}=\\\\frac{1}{3}\\\\gamma A^{*}=\\\\frac{1}{3}\\\\times6\\\\times(3.428\\\\times10^{-9})^{2}\\\\times0.6J=1.44\\\\times10^{-17}J$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及临界核尺寸和临界成核功的计算，答案以具体数值形式呈现。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界核尺寸和临界成核功的计算方法，并应用相关公式进行综合分析。虽然题目提供了具体数值，但计算过程需要一定的理解和分析能力，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用临界核尺寸和临界成核功的计算公式，涉及多步计算和概念关联。虽然题目提供了明确的参数，但需要正确应用公式并注意单位转换，属于中等应用层次的计算题。" + }, + { + "idx": 2456, + "question": "For the allotropic transformation of pure metal $(x\\\\rightarrow\\\\beta)$, at a certain degree of undercooling, the volume Gibbs free energy difference between the two phases is $7\\\\times10^{8} kJ/m^{3}$, and the interfacial energy is $0.5 J/m^{2}$. If the strain energy of nucleation is neglected, calculate the critical nucleus size and the critical nucleation energy for the formation of a disk-shaped nucleus with a diameter $(D)$ to thickness $(1)$ ratio $(D//)$ of 20.", + "answer": "For the disk-shaped nucleus, the critical nucleus diameter $D^{*}=-\\\\frac{88}{3}\\\\frac{\\\\gamma}{\\\\Delta G_{V}}=\\\\frac{88\\\\times0.6}{3\\\\times7\\\\times10^{8}}m=2.514\\\\times10^{-8}m$. The critical nucleation energy is $\\\\Delta G^{*}=[-\\\\frac{\\\\pi}{80}\\\\times(2.514\\\\times10^{-8})^{3}\\\\times7\\\\times10^{8}+\\\\frac{11\\\\pi}{20}\\\\times(2.514\\\\times10^{-8})^{2}\\\\times0.6]J=2.184\\\\times10^{-16}J$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及临界核尺寸和临界成核能量的具体计算过程，答案也给出了具体的数值结果和单位。 | 知识层次: 题目涉及多步计算和公式应用，需要理解临界核尺寸和临界成核能量的概念，并进行数值计算。虽然题目提供了具体的公式和数值，但需要正确应用这些公式并理解其背后的物理意义，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步公式推导和数值计算，涉及体积自由能差、界面能等概念的综合分析，但未达到复杂多变量计算的难度。" + }, + { + "idx": 2457, + "question": "Assuming the shear moduli G of the parent phase and the precipitate phase are the same, and the parent phase is an isotropic continuous medium. If a coherent nucleus forms, derive the expression for the size at which the spherical nucleus loses coherency during growth.", + "answer": "For a spherical nucleus, the sum of the misfit strain energy and interfacial energy before the loss of coherency is (4/3)πr^3×4Gδ^2+4πr^2γ_ci0. After losing coherency, there is no misfit strain energy, and the interfacial energy becomes 4πr^2γ_m. Let the critical size for losing coherency be r*. At this size, the energies of the coherent and incoherent states should be equal, hence (4/3)π(r*)^3×4Gδ^2+4π(r*)^2γ_ci0=4π(r*)^2γ_m. Solving this gives r*=3(γ_m−γ_ci0)/(4Gδ^2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导球形核在生长过程中失去共格性时的尺寸表达式，需要通过公式应用和数值计算来解决问题。答案中包含了具体的数学推导和公式应用，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，涉及应变能和界面能的计算，以及临界尺寸的推导，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如剪切模量、应变能、界面能等），进行多步骤的公式推导和计算，但尚未涉及复杂多变量的情况。" + }, + { + "idx": 2458, + "question": "The equilibrium melting point of nickel is 172515, the solid phase ρ̄=0.6cm³/1770l, the liquid/solid interface energy y=2.25×10⁻⁵·50⁻⁷. If the radius of the spherical particle is 1cm, how much is the melting point reduced? Assume the molar melting ΔHₘ=[Γ̄Γ̄ḠḠJ†m0]", + "answer": "The melting point Tᵣ of a crystal with a curvature radius of 1cm is Tᵣ = Tₘ - (2γVₛTₘ)/(rΔHₘ). Substituting the data gives Tᵣ = 1728K - (2×6.6×2.25×10⁻⁵×1728)/(1×18066)K ≈ 1727.99K, ΔT = 0.01K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中需要代入具体数值并使用给定的公式来计算熔点降低的数值。答案给出了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。虽然涉及一些参数和单位转换，但整体上属于对给定公式的直接套用和数值代入。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要套用给定的公式，代入已知数值进行简单计算即可得出结果，无需多个公式组合或复杂的推导过程。" + }, + { + "idx": 2460, + "question": "Estimate the number of atomic clusters containing 60 atoms in 1cm³ of copper at its melting point temperature. The atomic volume of liquid copper is 1.6×10⁻²⁹m³, the surface energy is 0.177J/m², and the melting point is 1356K.", + "answer": "According to nᵢ = n exp(-ΔG / k_B T), first calculate the energy ΔG₆₀ of a 60-atom cluster. The radius of the cluster r = (3×60×1.6×10⁻²⁹ / 4π)^(1/3), and the surface area A₆₀ = 4πr² = 4π(3×60×1.6×10⁻²⁹ / 4π)^(2/3). ΔG₆₀ = A₆₀γ = 4π(3×60×1.6×10⁻²⁹ / 4π)^(2/3)×0.177 = 8.33×10⁻¹⁹J. The number of atoms per cm³ n = 1 / (1.6×10⁻²³) = 6.25×10²² cm⁻³. n₆₀ = 6.25×10²² exp(-8.33×10⁻¹⁹ / (1.38×10⁻²³×1356)) = 2.91×10³ cm⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及原子簇数量估算、能量计算、半径和表面积计算等步骤，最终需要得出具体的数值结果。答案展示了完整的计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子团簇半径和表面积的计算、能量计算以及最终的数量估算。虽然涉及多个公式的应用，但整体思路较为直接，不需要复杂的推理或深度分析。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算原子团簇的数量，涉及原子体积、表面能、自由能变化等多个物理量的综合运用，并需要正确应用指数公式和单位转换。虽然计算步骤明确，但需要较强的综合分析能力和对物理概念的深入理解，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 2461, + "question": "What is the ratio of nucleation rates between intragranular coherent disc-shaped nucleation and grain boundary incoherent double spherical cap-shaped nucleation? Given the grain diameter Π=10^-3 m, temperature T=1000 K, and Boltzmann constant k=1.38×10^-23 J/K.", + "answer": "The calculation process for the nucleation rate ratio I2/I1 is as follows: I2/I1 = (d/L)exp[-(ΔGb* - ΔG*)/kT] = (10^-9/10^-3)exp[-(2.615×10^-18 - 1.26×10^-18)/(1.38×10^-23×1000)] = 2.27×10^-49. The result shows that the nucleation rate for intragranular coherent nucleation is higher than that for grain boundary incoherent nucleation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用公式进行数值计算，并理解不同形核机制的能量差异。虽然计算过程较为直接，但需要对形核理论有较好的理解，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及两种不同形核机制的速率比计算，需要应用形核能垒公式、Boltzmann因子以及几何参数转换。虽然计算步骤明确，但需要综合理解形核理论、能量计算和指数运算，属于中等应用层次的计算题。" + }, + { + "idx": 2462, + "question": "AI-Mg substitutional solid solution, estimate the misfit strain energy generated by solute atoms $1\\\\cdot11$, expressed in $\\\\|\\\\cdot\\\\|\\\\Pi\\\\mathbb{O}\\\\|^{-1}$ and $E V_{1}$ per atom. State the assumptions used in your estimation. The atomic radius of AI is $0.14317171$, shear modulus $G=2.5\\\\times10^{10}P a$, and Mg's $\\\\therefore\\\\frac{1}{2}$ axis length is $0.32\\\\mathrm{nm}$.", + "answer": "Assumption $\\\\boxed{1}$ the matrix is an isotropic continuous medium, $121$ solute atoms are far apart, and the stress field of each solute atom does not overlap. The misfit strain energy generated by solute atoms $N/E$ can be estimated using the following formula: \\n\\n$$ \\n\\\\Delta G_{x}=4G\\\\delta^{2}F^{\\\\prime} \\n$$ \\n\\nwhere $0.51$ lattice misfit is \\n\\n$$ \\n\\\\delta=\\\\frac{r_{\\\\mathrm{{Mg}}}-r_{\\\\mathrm{{Al}}}}{r_{\\\\mathrm{{Al}}}}=\\\\frac{0.16-0.143}{0.143}=0.1189 \\n$$ \\n\\n$\\\\int\\\\limits_{a}^{b}$ is the atomic volume of AI: \\n\\n$$ \\n\\\\begin{array}{l}{{{\\\\displaystyle{\\\\cal V}=\\\\frac{4}{3}\\\\pi v_{\\\\mathrm{Al}}^{3}=\\\\frac{4}{3}\\\\pi(0.143\\\\times10^{-9})^{3}=1.225\\\\times10^{-29}m^{3}}}}\\\\ {{{\\\\mathrm{}}}}\\\\ {{{\\\\Delta G_{\\\\mathrm{sl}}}=4G\\\\delta^{2}V=4\\\\times2.5\\\\times10^{10}\\\\times(0.1189)^{2}\\\\times1.225\\\\times10^{-29}J/a t=1.73\\\\times10^{-20}J/a t}}\\\\end{array} \\n$$ \\n\\nTherefore, \\n\\nsince $\\\\mathsf{I e V}{=}1.602\\\\times10^{-19}J$, \\n\\n$$ \\n\\\\Delta G_{*}=1.73\\\\times10^{-20}/1.602\\\\times10^{-19}{\\\\mathrm{~eV/at}}=0.108{\\\\mathrm{~eV/at}} \\n$$ \\n\\nMultiply the value expressed in $\\\\int\\\\limits_{0}^{1}\\\\frac{2}{c}d t$ by Avogadro's number $N_{10}$ to obtain the value in $\\\\vert11770-5\\\\vert$ units: \\n\\n$$ \\n\\\\Delta G_{_{x t}}=1.73\\\\times10^{-20}\\\\times6.025\\\\times10^{23}\\\\mathrm{J/mol}=10.4\\\\times10^{3}\\\\mathrm{J/mol} \\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括估计错配应变能、使用给定的公式和参数进行计算，并最终得出具体的数值结果。答案中包含了详细的数学推导和单位转换，这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算，包括原子半径差计算、应变能公式应用、单位转换等，涉及多个概念的综合应用和数值计算，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如固溶体、错配应变能、各向同性介质假设等），进行多步骤计算（包括原子半径差计算、应变能公式应用、单位转换等），并涉及单位换算和常数应用（如阿伏伽德罗常数）。虽然计算过程明确，但需要较强的概念关联和综合分析能力。" + }, + { + "idx": 2463, + "question": "Estimate the number of clusters containing 10 atoms in 1cm³ of copper at its melting point temperature. The atomic volume of liquid copper is 1.6×10⁻²⁹m³, the surface energy is 0.177J/m², and the melting point is 1356K.", + "answer": "According to nᵢ = n exp(-ΔG / k_B T), first calculate the energy ΔG₁₀ of a 10-atom cluster. The radius of the cluster r = (3×10×1.6×10⁻²⁹ / 4π)^(1/3), and the surface area A₁₀ = 4πr² = 4π(3×10×1.6×10⁻²⁹ / 4π)^(2/3). ΔG₁₀ = A₁₀γ = 4π(3×10×1.6×10⁻²⁹ / 4π)^(2/3)×0.177 = 2.52×10⁻¹⁹J. The number of atoms per cm³ n = 1 / (1.6×10⁻²³) = 6.25×10²² cm⁻³. n₁₀ = 6.25×10²² exp(-2.52×10⁻¹⁹ / (1.38×10⁻²³×1356)) = 8.85×10¹⁰ cm⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子团簇半径和表面积的计算、能量计算以及最终数量的估算。虽然涉及多个公式的应用，但整体思路较为直接，不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式进行多步计算，包括原子体积转换、表面能计算、热力学公式应用等。虽然计算步骤较多，但每个步骤都有明确的物理意义和数学逻辑，属于中等应用层次的计算题。" + }, + { + "idx": 2464, + "question": "Given that the shear moduli G of the parent phase and the precipitate phase are the same, and the parent phase is an isotropic continuous medium. If a coherent nucleus forms, derive the expression for the size at which the disc-shaped nucleus loses coherence during growth.", + "answer": "For a disc-shaped nucleus, let the radius be r and the thickness be t. Before coherence is lost, the sum of the misfit strain energy and the interfacial energy is πr^2t×4Gδ^2+2πr^2γ_ci0+2πrtγ_in. After coherence is lost, there is no misfit strain energy, and the disc interface changes from coherent to incoherent, so the energy becomes 2πr^2γ_in+2πrtγ_in. At the critical size, the energies of coherent and incoherent states should be equal, i.e., πr^2t*×4Gδ^2+2πr^2γ_ci0+2πrt*γ_in=2πr^2γ_in+2πrt*γ_in. Solving gives t*=(γ_in−γ_ci0)/(2Gδ^2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导一个表达式，涉及公式应用和数值计算，最终给出一个具体的数学表达式作为答案。 | 知识层次: 题目需要多步计算和概念关联，涉及应变能和界面能的计算，以及临界条件的推导，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相干与非相干状态的能量变化，并建立等式求解临界尺寸。涉及多步计算和概念关联，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2465, + "question": "For heterogeneous nucleation at grain boundaries (double spherical cap shape, with all interfaces being incoherent), what is the critical nucleus formation energy ΔGb*? Given the contact angle θ=50°, nucleation driving force ΔG1=5×10^8 J/m^3, and incoherent interface energy γin=0.5 J/m^2.", + "answer": "The calculation process for the critical nucleus formation energy ΔGb* is as follows: First, calculate the shape factor f(θ) = 0.5×(2-3cos50°+cos^3 50°) = 0.3125. The critical nucleus radius for homogeneous nucleation (spherical shape) rin* = 2γin/ΔG1 = 2×0.5/(5×10^8) m = 2×10^-9 m. The critical nucleus formation energy for homogeneous nucleation ΔGin* = (16π/3)(γin^3)/(ΔG1^2) = (16π/3)(0.5^3)/(5×10^8)^2 J = 8.37×10^-18 J. The critical nucleus formation energy for heterogeneous nucleation ΔGb* = f(θ)ΔGin* = 8.37×10^-18×0.3125 J = 2.615×10^-18 J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界核形成能ΔGb*，解答过程中涉及多个计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解异质成核的形状因子、临界核半径和临界核形成能量的计算，并综合应用这些概念来求解最终的临界核形成能量。虽然计算过程较为直接，但需要理解和应用多个公式，并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解异质成核的概念，掌握形状因子计算、临界核半径推导、均质成核能量计算等多个步骤，并最终通过关联公式得出结果。虽然计算过程涉及多个步骤，但每个步骤的公式应用相对明确，没有过于复杂的变量处理，因此属于该题型内的中等难度。" + }, + { + "idx": 2466, + "question": "What is the critical nucleation energy ΔG* when nucleation occurs as coherent disc-shaped particles within grains? Given the ratio of disc diameter to thickness D/N=10, the nucleation driving force ΔG1=5×10^8 J/m^3, the coherent interfacial energy γco=0.05×(1/17)^2, and the incoherent interfacial energy γin=0.5 J/m^2.", + "answer": "The calculation process for the critical nucleation energy ΔG* is as follows: The relationship between the disc radius r and thickness t is t = r/5. The disc volume equals πr^2t = πr^3/5. The disc top surface area equals πr^2, and the disc side surface area equals 2πrt = 2πr^2/5. The energy required for nucleation ΔG is ΔG = (πr^3/5)ΔG1 + 2πr^2γco + (2πr^2/5)γin. Differentiating with respect to r and setting it to zero, the critical size r* = (4×5γco + 4γin)/(3ΔG1) = (4×5×0.05 + 4×0.5)/(3×5×10^8) m = 2×10^-9 m. Substituting r* back into the ΔG equation, we obtain ΔG* = [-(π(2×10^-9)^3)/5 ×5×10^8 + 2π×(2×10^-9)^2×0.05 + (2π(2×10^-9)^2)/5×0.5] J = 1.26×10^-18 J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及多个步骤的数学运算和物理公式的推导，最终得出一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界成核能量的计算过程，并综合应用相关公式和参数进行计算。虽然不涉及复杂的推理分析或机理解释，但需要一定的综合分析能力来整合各个参数和步骤。 | 难度: 在计算题中属于综合性计算问题，需要理解多个概念（临界形核能、界面能等），进行多步计算（包括几何关系转换、能量方程建立、微分求极值等），并综合分析不同能量项的贡献。虽然计算过程明确，但涉及多个变量和公式的综合应用，属于中等偏上的难度水平。" + }, + { + "idx": 2467, + "question": "What is the interdiffusion coefficient D for the A-B binary system at 550K with molar fractions x_A=0.6 and x_B=0.4, given D_B^AB=9×10^-12 cm²/s, D_A^AB=2×10^-12 cm²/s, and d²G/dx_B²=-95.325?", + "answer": "The interdiffusion coefficient D is calculated as D = (x_A * D_B^AB + x_B * D_A^AB) * (x_A * x_B / (R * T)) * (d²G/dx_B²) = (0.6 * 2×10^-16 + 0.4 * 9×10^-16) * (0.6 * 0.4 / (8.314 * 550)) * (-95.325) m²/s = -2.4×10^-18 m²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（-2.4×10^-18 m²/s），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个参数的代入和公式的综合应用，包括摩尔分数的计算、扩散系数的加权平均、热力学参数的引入等，需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式和概念进行多步计算，包括摩尔分数、扩散系数、热力学参数等，并进行单位转换和综合分析。虽然计算步骤较多，但每个步骤相对明确，没有涉及过于复杂的变量或高深的数学处理。" + }, + { + "idx": 2468, + "question": "What are the similarities between polymer crystallization and metal crystallization in terms of the crystallization process?", + "answer": "Polymer crystallization and metal crystallization follow the general phase transition rules: 1 The crystallization process consists of nucleation and growth processes: (1) 1/2 Heterogeneous nucleation is dominant: (1-1) The kinetic equation has the same form as the Avrami equation: 4 Large undercooling results in small grain size. 5 The melting point of small particles is lower than that of large particles, exhibiting a Gibbs-Thomson-like effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对聚合物结晶和金属结晶的相似性进行文字解释和论述，答案提供了详细的比较和分析，符合简答题的特征。 | 知识层次: 题目要求比较聚合物结晶和金属结晶过程的相似性，涉及多个概念（如成核、生长、动力学方程、Gibbs-Thomson效应等）的关联和综合分析，需要理解并应用这些概念来解释现象，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对聚合物结晶和金属结晶过程进行多角度的比较分析，涉及成核与生长过程、动力学方程形式、过冷度影响以及吉布斯-汤姆逊效应等多个方面的关联性论述。虽然不需要进行深度关联性分析（等级5），但已超出基础说明（等级3）的要求，属于需要综合多个概念并进行详细论述的中高难度题目。" + }, + { + "idx": 2469, + "question": "For a silicon-containing low-alloy steel ingot with dendritic segregation and a dendrite arm spacing of 500μm, diffusion annealing is performed at 1200°C. To reduce the segregation amplitude to 10% of its original value, how long should the holding time be for carbon? Given that the diffusion coefficient of carbon in austenite at 1200°C is 2.23×10^(-6)cm^2/s.", + "answer": "When dendritic segregation exists, the solute composition is distributed with the dendrite arm spacing as the period, where the period l is 500μm=0.05cm. According to the trigonometric series solution of the diffusion equation, the concentration amplitude decays with a decay factor, i.e., C=C¯+C0sin(πx/l)exp(-π^2Dt/l^2). If the amplitude decays to 1/10 of its original value, then exp(-π^2Dt/l^2)=0.1. Therefore, the required time for carbon is: t=l^2/(π^2D)ln0.1=-(0.025)^2/(π^2×2.23×10^(-6))ln0.1s=65.3s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的保温时间，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程的解和衰减因子公式，进行综合分析并计算所需时间。虽然不涉及复杂的机理分析或创新设计，但需要理解和应用多个概念并进行数值计算。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散方程的解、三角函数分布、衰减因子等概念，并进行多步计算（包括单位转换、对数运算等）。虽然涉及多个概念和计算步骤，但整体思路清晰，属于中等应用层次中的典型问题。" + }, + { + "idx": 2470, + "question": "What cooling rate v is required to avoid spinodal decomposition at 550K when cooling from 850K to 550K, given the required time t=173.6 s?", + "answer": "The cooling rate v must be greater than (850K - 550K) / 173.6 s = 1.44 K/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（冷却速率的计算），并给出了具体的公式应用（温度差除以时间）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式应用和简单计算，即冷却速率的计算，不需要多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（冷却速率=温度差/时间）进行一步计算，无需任何公式组合或复杂推导，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2471, + "question": "What are the main differences in crystallization ability between polymer crystallization and metal crystallization?", + "answer": "Only thermoplastic polymers can crystallize. These polymers have a linear structure, and the crystallization process involves the arrangement of molecular chains from disorder to order, with no fixed melting temperature. Due to factors such as the long molecular chains, complex structure, and high melt viscosity of polymers, most polymer crystallizations are much slower than metal crystallizations and cannot fully crystallize, typically achieving a crystallinity of around 50%. The degree of crystallinity is closely related to the molecular structure of the polymer, and the more complex the structure, the more difficult it is to crystallize, often leading to the formation of a glassy state. Therefore, the ability of a polymer to form a crystalline state has an inverse relationship with its ability to form a glassy state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物结晶与金属结晶的主要区别，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求对聚合物和金属的结晶能力进行对比分析，涉及分子结构、结晶过程、熔融温度、结晶速度、结晶度等多个方面的综合考量。需要深入理解聚合物和金属结晶的机理，并能解释不同因素对结晶能力的影响。此外，还需要分析聚合物结晶与玻璃态形成之间的关系，体现了较高的综合分析能力和机理理解深度。 | 难度: 在简答题的复杂分析层次中，该题目要求对聚合物和金属的结晶能力进行全面比较，涉及分子结构、结晶过程、熔融温度、结晶速度、结晶度等多个方面的综合分析和推理。需要深入理解聚合物和金属的结晶机理，并能解释复杂现象如玻璃态形成与结晶能力的逆相关性。这种深度和广度的分析要求在该题型内属于最高难度等级。" + }, + { + "idx": 2472, + "question": "What is the time t required for spinodal decomposition to occur over a diffusion distance of λ_m/2=50 nm (with λ_m=100 nm) at 550K, given the interdiffusion coefficient D=-2.4×10^-18 m²/s?", + "answer": "The time t required is calculated as t = (λ_m/2)² / (6D) = (50×10^-9)² / (6 * 2.4×10^-18) s = 173.6 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，并给出了具体的计算公式和步骤，最终得出一个具体的数值答案。这符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及将已知数值代入公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式进行简单数值计算，无需多步骤推导或复杂公式组合。题目明确给出了所有必要参数和公式形式，解题过程仅涉及基本代数运算。" + }, + { + "idx": 2473, + "question": "A low-alloy steel ingot containing silicon exhibits dendritic segregation with a dendrite arm spacing of 500μm. After diffusion annealing at 1200°C, the segregation amplitude is reduced to 10% of its original value. How long should the holding time be for the silicon element? Assume the diffusion coefficient of silicon in austenite at 1200°C is 7.03×10^(-11)cm^2/s.", + "answer": "When dendritic segregation exists, the solute composition is distributed with the dendrite arm spacing as the period, where the period l is 500μm=0.05cm. According to the trigonometric series solution of the diffusion equation, the concentration amplitude decays with a decay factor, i.e., C=C¯+C0sin(πx/l)exp(-π^2Dt/l^2). If the amplitude decays to 1/10 of its original value, then exp(-π^2Dt/l^2)=0.1. Therefore, the required time for the Si element is: t=l^2/(π^2D)ln0.1=-(0.025)^2/(π^2×7.03×10^(-11))ln0.1s=2.07×10^6s. Since Si in Fe is a substitutional solute atom while C is an interstitial solute atom, the diffusion rate of Si atoms is much slower than that of C, so the homogenization time for Si is several orders of magnitude slower than that for C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解硅元素的保温时间，答案中包含了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解扩散方程的解及其应用，同时需要将理论公式与具体数值计算相结合。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来推导和计算所需的保温时间。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散方程的解、三角函数级数解、衰减因子等概念，并进行多步计算（包括单位转换、对数运算等）。虽然涉及多个步骤和概念关联，但整体计算过程相对直接，没有涉及复杂多变量或高阶数学工具，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 2475, + "question": "If two such subgrain boundaries merge to form one new subgrain boundary, by how much does the misorientation increase?", + "answer": "If two such subgrain boundaries merge to form one new subgrain boundary, the dislocation density at the grain boundary doubles. Since the misorientation is proportional to the dislocation density, the misorientation becomes 2 × 10^-3 radians.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出具体的数值结果（misorientation的增加量），并且答案中给出了具体的计算过程和数值（2 × 10^-3 radians），符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，只需要理解位错密度与取向差的关系并进行直接套用计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接应用单一公式（misorientation与dislocation density的比例关系）进行简单计算，无需组合多个公式或进行复杂推导。" + }, + { + "idx": 2476, + "question": "If the stored energy is mainly contributed by dislocations, establish the relationship between dislocation density and critical nucleus size.", + "answer": "The energy of a dislocation per unit length is approximately Gb^2. Let the dislocation density be ρ, then the dislocation energy per unit volume is ρGb^2. If the stored energy E is mainly contributed by dislocations, the relationship between the critical nucleus radius and dislocation density is r* = 4γ/(ρGb^2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求建立关系并解释，答案提供了详细的文字解释和公式推导，属于需要文字论述的简答题类型。 | 知识层次: 题目需要理解位错能量与临界核尺寸之间的关系，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在简答题中属于较高难度，需要综合运用多个概念（如位错能量、临界核尺寸、储存能等）进行多步计算和关联分析。题目要求建立位错密度与临界核尺寸之间的定量关系，涉及公式推导和物理意义的解释，属于多角度分析论述的范畴。虽然不需要深度关联性分析（如跨学科或多机制耦合），但已超出基础概念应用的难度。" + }, + { + "idx": 2477, + "question": "How much energy is released before and after the merging?", + "answer": "The grain boundary energy per unit area after merging is 2θ E0(A - ln2θ), the energy of the two grain boundaries before merging is 2θ E0(A - lnθ), and the relative value of released energy after merging ΔE is ΔE = (2θ E0(A - lnθ) - 2θ E0(A - ln2θ))/(2θ E0(A - lnθ)) = (ln2θ - lnθ)/(0.5 - lnθ) = (ln(2 × 10^-3) - ln10^-3)/(0.5 - ln10^-3) = 9.35%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解晶界能量变化的概念，并进行数值计算和相对能量释放的推导。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和对公式的理解应用。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个公式，进行多步骤的计算过程，包括对数运算和能量变化的相对值计算。虽然涉及的概念和计算步骤较多，但并未达到复杂多变量计算的级别。" + }, + { + "idx": 2478, + "question": "A copper block subjected to large cold deformation has a stored energy of 2×10^5 J·m^-3, and the typical value of high-angle boundary energy is 0.5 J·m^-2. According to the classical homogeneous nucleation theory, what is the critical nucleus size for recrystallization?", + "answer": "According to classical nucleation theory, the critical nucleus radius r* = 2γ/ΔG, where γ is the boundary energy and ΔG is the stored energy per unit volume. Substituting the boundary energy and stored energy, we obtain r* = (2×0.5)/(2×10^5) m = 5×10^-7 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和数据进行数值计算，最终得出一个具体的数值结果（临界核尺寸）。解答过程涉及公式应用和单位换算，符合计算题的特征。 | 知识层次: 题目主要涉及经典均质形核理论的基本公式应用和简单计算，即通过给定的边界能和储存能直接套用公式计算临界核尺寸。虽然需要理解相关概念，但思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（r* = 2γ/ΔG）进行数值代入计算，无需任何公式变换或多步骤推导。题目中所有参数均为已知条件，且计算过程仅涉及基本代数运算，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 2479, + "question": "What are the basic characteristics of the Bravais lattice?", + "answer": "It has periodicity and symmetry, and each node is an equivalent point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释Bravais晶格的基本特征，答案需要文字描述其周期性和对称性等特性，属于简答题类型。 | 知识层次: 题目考查对Bravais晶格基本特征的记忆和理解，属于基础概念的定义和分类范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答Bravais晶格的基本特征，属于最基础的定义性知识。答案只需列出两个核心特征（周期性和对称性）即可，无需展开解释或论述。这符合等级1\"基本定义简答\"的标准，是同类题型中最简单的类型。" + }, + { + "idx": 2480, + "question": "If a nucleus with a radius of 2×10^-9 m is to be formed, what should the dislocation density at the nucleation site be? (G=4×10^10 Pa, b=0.25×10^-9 m)", + "answer": "If a nucleus with a radius of 2×10^-9 m is to be formed, the required dislocation density ρ is: ρ = 4γ/(r*Gb^2) = (4×0.5)/(2×10^-9×4×10^10×(0.25×10^-9)^2) m^-2 = 4×10^17 m^-2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解位错密度，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式的应用和参数的代入，需要理解位错密度与核形成半径之间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步公式推导和数值计算，涉及材料科学中的位错密度、核形成半径等概念的关联分析，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2481, + "question": "Demonstrate why there are no fewer than 14 Bravais lattices", + "answer": "For any one of the 14 lattices, it is impossible to find a method of connecting nodes to form a new unit cell while preserving the symmetry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来证明为什么布拉维晶格不少于14种，答案也是通过论述形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释为什么存在不少于14种Bravais点阵，这需要深入理解晶体对称性和点阵理论，涉及对称操作、空间群和点阵类型的综合分析。解答需要推理分析，说明为什么无法通过连接节点形成新的单位晶胞同时保持对称性，这超出了简单记忆或应用，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求解释为什么存在不少于14种布拉维格子，这需要综合运用晶体学知识、对称性分析以及单元构造原理。解题过程中不仅需要掌握布拉维格子的基本概念，还需要深入理解对称操作对晶格类型的影响，并能通过逻辑推理证明14种格子的完备性。这种深度和广度的知识运用在简答题中属于最高难度级别。" + }, + { + "idx": 2482, + "question": "Comment on the possibility of classical nucleation. It is known that the dislocation density of heavily worked metallic materials is approximately 10^15 m^-2.", + "answer": "The dislocation density of heavily worked metallic materials is approximately 10^15 m^-2, making the formation of a critical nucleus of such size essentially impossible. The critical nucleus radius for classical nucleation discussed above is 5×10^-7 m, clearly indicating that nucleation cannot occur via the classical nucleation mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对经典成核的可能性进行评论，并提供已知条件（位错密度）。答案通过文字解释和论述来说明为什么经典成核机制不可能发生，符合简答题的特征。 | 知识层次: 题目要求对经典成核理论进行评论，并结合位错密度数据进行推理分析，需要综合运用成核理论、位错密度对成核的影响等知识，进行机理的解释和论证。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求考生结合已知的位错密度数据（10^15 m^-2）和临界晶核半径（5×10^-7 m）进行推理分析，解释经典形核理论在此条件下的不可行性。这需要考生：" + }, + { + "idx": 2483, + "question": "The subgrain boundaries formed after polygonization contain π edge dislocations, and the misorientation between subgrains is 10^-3 radians. Assuming there is no interaction between dislocations before polygonization, how much energy is released after polygonization (expressed as a percentage)? (The grain boundary energy E⊥-E0θ(A-1)=β, where A is set to 0.5)", + "answer": "Before polygonization, the dislocations have no interaction, meaning their energy is the same as when they exist independently. Assuming the dislocations are edge dislocations, the total energy E1 of these π dislocations when they exist separately is πEe, where Ee is the energy per unit length of an edge dislocation: Ee = (μb^2)/(4π(1-ν)) ln(R/r0) ≈ 10θ E0, where E0 = μb^2/(4π(1-ν)), and the approximation ln(R/r0) = 10 is used. After polygonization, the energy Eb of the grain boundary formed by these π dislocations per unit area is Eb = E0θ(0.5 - lnθ). The relative energy released per unit area of the grain boundary before and after polygonization compared to E1 is ΔE/E1 = (E1 - Eb)/E1 = (10θ E0 - E0θ(0.5 - lnθ))/(10θ E0) = (10 - 0.5 + ln10^-3)/10 = 25.99%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及能量释放的百分比计算，解答过程包含多个公式推导和数值代入步骤。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错能量、晶界能量公式的应用，并进行综合计算。虽然不涉及复杂的推理分析或创新设计，但需要一定的综合分析能力来解决问题。 | 难度: 在计算题题型中，该题目属于综合性计算问题。题目要求进行多步计算，包括理解位错能量公式、晶界能量公式，并进行数值计算和百分比转换。虽然涉及的概念和公式较为明确，但需要将这些概念关联起来并进行综合分析，因此在该题型内属于中等偏上的难度。" + }, + { + "idx": 2484, + "question": "What is the lattice constant?", + "answer": "The lengths a, b, c of the three adjacent edges in a unit cell and the angles α, β, γ between these edges determine the size and shape of the unit cell. These six parameters are called the lattice constants.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释什么是晶格常数，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查基本概念的记忆和理解，即晶格常数的定义和描述，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，即\"lattice constant\"是什么。不需要进行概念解释或复杂体系阐述，属于最基础的定义简答级别。题目答案直接给出了晶格常数的定义，没有涉及更深层次的理解或应用，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2485, + "question": "Demonstrate why there are no more than 14 Bravais lattices", + "answer": "If each crystal system includes four types of lattices: simple, face-centered, body-centered, and base-centered, the seven crystal systems would yield 28 Bravais lattices. However, some of these 28 can be connected to form one of the 14 lattices without changing the symmetry. For example, a body-centered monoclinic lattice can be connected to form a base-centered monoclinic lattice, so it is not a new lattice type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来证明为什么不超过14种布拉维点阵，答案提供了详细的解释和例子，符合简答题的特征。 | 知识层次: 题目要求解释为什么布拉维晶格不超过14种，这需要深入理解晶体系统的对称性和晶格类型之间的关系，并进行逻辑推理和综合分析。答案中提到的将28种可能的晶格类型简化为14种的过程，涉及对晶体对称性和晶格变换的复杂分析，属于较高层次的认知能力要求。 | 难度: 在简答题中属于机理深度解释难度，需要综合运用晶体学知识，解释Bravais晶格数量限制的深层原因，涉及对称性分析和晶格类型转换的推理过程。虽然不需要全面分析复杂现象，但对机理的解释要求较高。" + }, + { + "idx": 2486, + "question": "Write the specific indices of all equivalent crystal planes in the {123} plane family of the cubic crystal system", + "answer": "{123}=(123)+(123̄)+(1̄23)+(12̄3)+(132)+(13̄2)+(1̄32)+(132̄)+(213)+(21̄3)+(2̄13)+(213̄)+(231)+(231̄)+(2̄31)+(23̄1)+(312)+(31̄2)+(3̄12)+(312̄)+(321)+(321̄)+(3̄21)+(32̄1)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出立方晶系中{123}晶面族的所有等效晶面指数，答案需要列举所有可能的等效晶面，属于需要详细列举和解释的简答题类型。 | 知识层次: 题目要求列出立方晶系中{123}晶面族的所有等效晶面指数，这需要理解晶面指数的定义和立方晶系的对称性操作（如旋转、反射等），并能够应用这些对称性操作生成所有等效晶面。虽然不涉及复杂的计算或综合分析，但需要多步的对称性操作和概念关联，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要深入理解立方晶系中晶面指数的对称性，并能够系统地列举所有等效晶面。解题步骤涉及多个概念的综合应用，包括晶面指数的变换、对称操作的理解以及等效晶面的识别。此外，题目要求完整的列举，需要较高的逻辑性和系统性，属于多角度分析论述的难度等级。" + }, + { + "idx": 2487, + "question": "Using BCC, FCC, and hexagonal lattices as examples, explain the similarities and differences between unit cells and primitive cells.", + "answer": "Both unit cells and primitive cells can reflect the periodicity of the lattice, meaning that infinite stacking of unit cells or primitive cells can reconstruct the entire lattice. However, unit cells are required to reflect the symmetry of the lattice, and the smallest volume unit under this premise is the unit cell; whereas primitive cells only require the smallest volume, and the primitive cells of Bravais lattices contain only one lattice point. For example: in a BCC unit cell, the number of lattice points is 2, while in a primitive cell it is 1; in an FCC unit cell, the number of lattice points is 4, while in a primitive cell it is 1; in a hexagonal lattice unit cell, the number of lattice points is 3, while in a primitive cell it is 1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来说明单位晶胞和原胞的异同点，答案提供了详细的文字描述和具体例子，符合简答题的特征。 | 知识层次: 题目要求解释和比较单元晶胞和原胞的异同，涉及对BCC、FCC和六方晶格的具体分析。这需要理解晶格周期性和对称性的基本概念，并能将这些概念应用到具体的晶格类型中。虽然不涉及复杂的计算或推理，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要多角度分析论述。题目要求解释单元晶胞和原胞的异同，并以BCC、FCC和六方晶格为例进行说明。这不仅需要理解单元晶胞和原胞的基本概念，还需要掌握不同晶格类型的结构特点，并能进行综合分析和比较。此外，题目还要求从对称性和最小体积两个角度进行论述，增加了分析的深度和复杂性。" + }, + { + "idx": 2488, + "question": "Calculate the length of the [10 0] crystal direction in a hexagonal crystal (in units of lattice constants a and c)", + "answer": "The formula for the length of the [10 0] crystal direction in a hexagonal crystal: L = a", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算晶向长度），并给出了具体的公式应用（L = a），符合计算题的特征。 | 知识层次: 题目要求直接套用已知公式计算六方晶体中[10 0]晶向的长度，属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（L = a）进行计算，无需任何额外步骤或公式组合。该题目完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2489, + "question": "Write all the equivalent crystallographic direction indices in the <123> direction family of the cubic crystal system", + "answer": "<123>=[123]+[1̄23]+[12̄3]+[123̄]+[132]+[1̄32]+[13̄2]+[132̄]+[213]+[2̄13]+[21̄3]+[213̄]+[231]+[2̄31]+[23̄1]+[231̄]+[312]+[3̄12]+[31̄2]+[312̄]+[321]+[3̄21]+[32̄1]+[321̄]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举立方晶系中<123>方向族的所有等效结晶学方向指数，需要详细列出所有可能的组合，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目要求列出立方晶系中<123>方向族的所有等效晶向指数，这属于对基本概念的简单应用。虽然需要理解晶向指数的定义和立方晶系的对称性，但主要是直接套用规则进行计算和列举，不需要复杂的分析或综合。 | 难度: 在简答题中属于中等难度，需要理解立方晶系中等效晶向指数的概念，并能够系统地列举所有可能的排列组合。虽然题目要求的是基本公式应用和简单计算，但由于需要考虑到所有可能的正负排列和顺序排列，解题步骤相对复杂，需要一定的逻辑思维和系统性。" + }, + { + "idx": 2490, + "question": "Calculate the length of the [11 0] crystal direction in a hexagonal crystal (in units of lattice constants a and c)", + "answer": "The formula for the length of the [11 0] crystal direction in a hexagonal crystal: L = a√3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方晶体中[11 0]晶向的长度，需要使用特定的公式进行数值计算，答案给出了具体的计算公式和结果形式。 | 知识层次: 题目要求应用基本公式计算六方晶体中特定晶向的长度，属于直接套用公式的简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需套用已知的六方晶系方向长度公式L = a√3，无需任何额外推导或组合计算步骤，属于最基础的计算题类型。" + }, + { + "idx": 2491, + "question": "Calculate the length of the [0001] direction in a hexagonal crystal (in units of lattice constants a and c)", + "answer": "Formula for the length of the [0001] direction in a hexagonal crystal: L = c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方晶体中[0001]方向的长度，需要使用公式进行数值计算，答案是一个具体的数值结果（L = c），符合计算题的特征。 | 知识层次: 题目仅需要直接应用已知的公式（L = c）来计算[0001]方向的长度，无需多步计算或综合分析，属于基本公式的直接套用。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（L = c）进行计算，无需任何额外步骤或公式组合，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2492, + "question": "Calculate the lengths L (in units of the unit cell edge a) of low-index crystallographic directions with indices not exceeding 3 in cubic crystals.", + "answer": "The length of a crystallographic direction is given by L=a·sqrt(u²+v²+w²), yielding:\\n<100>: 1\\n<110>: √2\\n<111>: √3\\n<200>: 2\\n<210>: √5\\n<211>: √6\\n<220>: 2√2\\n<221>: 3\\n<300>: 3\\n<310>: √10\\n<311>: √11\\n<222>: 2√3\\n<320>: √13\\n<321>: √14\\n<322>: √17\\n<330>: 3√2\\n<331>: √19\\n<332>: √22\\n<333>: 3√3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算立方晶体中低指数晶向的长度，并给出了具体的计算公式和结果，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的方向指数计算长度，属于直接套用公式的范畴。虽然需要计算多个方向，但每个计算步骤都是独立的，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式L=a·sqrt(u²+v²+w²)进行计算，无需任何公式组合或复杂推导步骤，所有方向的计算方法完全相同，属于典型的单一公式直接计算类型。" + }, + { + "idx": 2493, + "question": "How many lattice constants are there in each crystal system?", + "answer": "
Crystal SystemRelationships among a, b, c, α, β, γNumber of Lattice Constants
Triclinica≠b≠c, α≠β≠γ≠90°6 (a, b, c, α, β, γ)
Monoclinica≠b≠c, α=γ=90°≠β or α=β=90°≠γ4 (a, b, c, γ or a, b, c, β)
Orthorhombica≠b≠c, α=β=γ=90°3 (a, b, c)
Tetragonala=b≠c, α=β=γ=90°2 (a, c)
Cubica=b=c, α=β=γ=90°1 (a)
Hexagonala=b≠c, α=β=90°, γ=120°2 (a, c)
Rhombohedrala=b=c, α=β=γ≠90°2 (a, α)
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释每个晶体系统中的晶格常数数量，答案以表格形式详细列出了各个晶体系统的参数关系和晶格常数数量，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对不同晶系中晶格常数数量的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求回答每个晶系中的晶格常数数量，但需要考生对七大晶系的基本特征（如轴长和夹角关系）有清晰记忆和理解。相比等级1的简单定义复述（如\"什么是晶格常数\"），该题需要更系统的知识组织能力；但相比等级3的复杂体系阐述（如解释晶系间的转换关系），该题的认知负荷相对较低，属于中等难度的概念解释题。" + }, + { + "idx": 2494, + "question": "Calculate the interplanar spacings (in units of the unit cell edge length a) for low-index planes with indices not exceeding 3 in a cubic crystal.", + "answer": "The interplanar spacing is given by d=a/sqrt(h²+k²+l²), yielding:\\n{100}: 1\\n{110}: √2/2\\n{111}: √3/3\\n{200}: 1/2\\n{210}: √5/5\\n{211}: √6/6\\n{220}: √2/4\\n{221}: 1/3\\n{300}: 1/3\\n{310}: √10/10\\n{311}: √11/11\\n{222}: √3/6\\n{320}: √13/13\\n{321}: √14/14\\n{322}: √17/17\\n{330}: √2/6\\n{331}: √19/19\\n{332}: √22/22\\n{333}: √3/9", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算立方晶体中低指数晶面的晶面间距，需要使用公式d=a/sqrt(h²+k²+l²)进行数值计算，答案也是具体的计算结果。 | 知识层次: 题目主要考查对立方晶体晶面间距公式的直接应用和简单计算，涉及的知识点较为基础，计算过程直接套用公式即可完成，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用单一公式d=a/sqrt(h²+k²+l²)进行计算，但需要针对多个不同晶面指数（hkl）进行重复计算。虽然计算量较大，但每个计算步骤都是直接套用公式，不需要多个公式组合或复杂推导。这符合等级2\"简单公式应用计算\"的标准，比单一公式直接计算（等级1）稍复杂，但远未达到多个公式组合计算（等级3）的难度。" + }, + { + "idx": 2495, + "question": "Based on the stacking characteristics of FCC and HCP crystals, demonstrate that the sizes of octahedral and tetrahedral interstices in these two types of crystals must be the same.", + "answer": "Examining the (111) close-packed planes of FCC crystals and the (0001) close-packed planes of HCP crystals, it is found that the atomic arrangements of the two are identical. Further studying the adjacent two layers of close-packed planes reveals no difference in the way the layers fit together. In fact, only when examining three adjacent layers can the distinction between FCC and HCP be observed. However, both octahedral and tetrahedral interstices are only related to two layers of close-packed atoms. Therefore, for these two types of interstices, the microscopic environments provided by FCC and HCP are exactly the same, and their sizes must also be identical.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来证明FCC和HCP晶体中八面体和四面体间隙的大小必须相同，答案提供了详细的文字分析和论述，符合简答题的特征。 | 知识层次: 题目要求通过分析FCC和HCP晶体的堆垛特性，证明两种晶体中八面体和四面体间隙的大小必须相同。这需要深入理解晶体结构、堆垛顺序以及间隙形成的微观环境，涉及多步推理和综合分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对FCC和HCP晶体结构的堆垛特性进行深入分析，并推导出八面体和四面体间隙尺寸相同的结论。这需要综合运用晶体学知识，理解密排面的原子排列方式，以及不同堆垛方式对间隙尺寸的影响。解题过程中需要从微观环境的角度进行推理分析，涉及多层密排面的堆垛关系，属于该题型内对机理深度解释和复杂现象全面分析要求较高的题目。" + }, + { + "idx": 2497, + "question": "Calculate the angles between low-index crystallographic directions with indices not exceeding 3 in cubic crystals (presented in a list)", + "answer": "Use the crystallographic direction angle formula cosθ=(u1u2+v1v2+w1w2)/sqrt((u1²+v1²+w1²)*(u2²+v2²+w2²)) to calculate. The angle between two crystallographic direction families may have multiple values depending on the selected directions. The specific calculation results need to list all crystallographic direction combinations with indices not exceeding 3 and their corresponding angles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用特定的公式进行数值计算，并列出所有符合条件的晶向组合及其对应的角度，这符合计算题的特征。 | 知识层次: 题目要求应用立方晶体中晶向夹角的计算公式，涉及多步计算和不同晶向组合的综合分析，需要理解晶向指数的含义并正确应用公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题。题目要求计算立方晶体中低指数晶向（指数不超过3）之间的夹角，涉及多个步骤：首先需要列出所有指数不超过3的晶向组合，然后应用晶向夹角公式进行计算。由于不同晶向组合可能对应多个夹角值，需要综合考虑所有可能的组合及其计算结果。虽然计算本身基于标准公式，但组合数量较多且需要系统性地处理，属于中等偏上的复杂度。" + }, + { + "idx": 2498, + "question": "Compare the obtained results with the previous question", + "answer": "The obtained results are exactly the same as the previous question, only the crystal plane indices {hkl} are replaced with [uvw]. Superficially, this is because the formula for the angle between crystal directions is identical to that for the angle between crystal planes. Upon deeper analysis, it is found that the crystal direction [uvw] is the normal direction of the crystal plane (hkl), forming a perpendicular relationship. Therefore, the angle between two crystal planes is always equal to the angle between crystal directions with the same indices.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对结果进行比较和分析，需要文字解释和论述，答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求比较结果，还需要深入分析晶体方向与晶面之间的垂直关系，并解释角度公式相同的原因。这涉及概念的关联、综合分析以及机理解释，属于较高层次的认知能力。 | 难度: 在简答题-需要文字解释和论述的题型中，该题目属于机理深度解释的难度等级。题目要求不仅比较结果，还需要解释表面现象背后的晶体学原理（晶向与晶面的垂直关系），并推导出普遍规律（晶面夹角等于对应晶向夹角的机理）。这需要学生综合运用晶体学知识进行推理分析，但尚未达到需要处理多因素交互作用的复杂现象全面分析程度（等级5）。" + }, + { + "idx": 2499, + "question": "Derive the four-index zone equation from the three-index zone equation of the hexagonal crystal system.", + "answer": "The three-index zone equation for the hexagonal crystal system is $H\\\\sqcup+K V+L W=0$; the plane (H K L) is converted to four-index $(\\\\textsf{h k i}\\\\textsf{l})$, with $\\\\forall=h,\\\\quad\\\\forall=k,\\\\quad\\\\mathsf{L}=1$; the direction [U $\\\\pmb{\\\\upnu}$ W] is converted to four-index $[u\\\\textbf{v t}\\\\pmb{w}]$, with $\\\\Psi=2{\\\\mathsf{u}}+{\\\\mathsf{v}},\\\\quad\\\\forall{\\\\mathsf{{\\\\mathbf{\\\\bar{\\\\alpha}}}}}2{\\\\mathsf{v}}+{\\\\mathsf{u}},\\\\quad\\\\forall{\\\\mathsf{I}}={\\\\mathsf{w}};$; substituting into the zone equation, we get ${\\\\sf h}\\\\left(2{\\\\sf u}+{\\\\sf v}\\\\right)+{\\\\sf k}\\\\left(2{\\\\sf v}+{\\\\sf u}\\\\right)+{\\\\sf I}{\\\\sf w}=0;$; substituting $\\\\dag=-(h+k)$, $\\\\mathtt{t=-\\\\tau(u+v)}$ into the above equation, we obtain ${\\\\mathsf{h}}{\\\\mathsf{u}}+{\\\\mathsf{k}}{\\\\mathsf{v}}+{\\\\mathsf{i}}{\\\\mathsf{t}}+{\\\\mathsf{I}}{\\\\mathsf{w}}=0{\\\\mathsf{c}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从三指数晶带方程推导出四指数晶带方程，涉及公式转换和数学推导，属于计算题类型。答案展示了详细的推导步骤和数学运算过程，符合计算题的特征。 | 知识层次: 题目需要将三指数晶带方程转换为四指数晶带方程，涉及多步计算和概念关联，包括指标转换和公式推导，需要一定的综合分析能力。虽然不涉及复杂的推理分析或创新应用，但比简单应用更复杂。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多步转换公式，涉及多个变量的替换和推导过程，但尚未达到复杂多变量计算的最高难度。" + }, + { + "idx": 2500, + "question": "What is the bonding type of graphite?", + "answer": "Within the same layer of graphite, the bonding is covalent, while between adjacent layers, the bonding is van der Waals forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释石墨的键合类型，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查石墨中不同层间和层内键合类型的基本概念记忆和理解，属于材料科学中关于碳材料键合类型的基础知识。 | 难度: 在简答题题型中，该题目要求解释石墨的两种不同键合类型（层内共价键和层间范德华力），属于概念解释和描述的难度等级。虽然涉及两个不同的键合概念，但都属于基础概念记忆范畴，不需要复杂的体系阐述或深入分析，因此属于等级2。" + }, + { + "idx": 2501, + "question": "What is the crystal structure of diamond?", + "answer": "The crystal structure of diamond is FCC with tetrahedral interstices, where carbon atoms are located at the bonding points of the FCC lattice and four non-adjacent tetrahedral interstice positions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钻石的晶体结构，答案提供了详细的文字描述和论述，而不是从选项中选择或简单的对错判断，也不需要数值计算。 | 知识层次: 题目考查对金刚石晶体结构的基本概念记忆，仅需回答其FCC结构和碳原子位置的基本描述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释金刚石的晶体结构，涉及FCC晶格和四面体间隙的概念描述。虽然需要记忆基本概念和结构特征，但不需要进行复杂的体系阐述或深入分析，属于概念解释和描述级别的难度。" + }, + { + "idx": 2502, + "question": "What is the bonding type in diamond?", + "answer": "In diamond, carbon atoms are bonded by covalent bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钻石中的键合类型，答案需要文字描述和论述，而不是选择、判断或计算 | 知识层次: 题目考查对金刚石中碳原子键合类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答金刚石中的键合类型，这是材料科学中最基础的概念之一，只需记忆碳原子通过共价键结合即可。不需要额外的解释或复杂概念体系的阐述，完全符合等级1对基础概念记忆的要求。" + }, + { + "idx": 2503, + "question": "What are the performance characteristics of diamond?", + "answer": "Diamond has high hardness and a dense structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钻石的性能特征，答案以文字论述形式给出，没有选项或计算要求 | 知识层次: 题目考查对钻石性能特征的基础概念记忆和理解，属于材料科学中最基本的物理性质认知范畴 | 难度: 在简答题题型中，该题目仅要求回答钻石的基本性能特征（高硬度和致密结构），属于最基础的定义性知识回答。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。题目仅考察学生对材料基本属性的记忆程度，不涉及任何分析或综合能力要求。" + }, + { + "idx": 2504, + "question": "What is the reason for the difference in property changes between short-period elements and long-period elements?", + "answer": "This is because the number of subshell electrons in the long-period transition elements also affects the properties of the elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释元素性质差异的原因，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释短周期元素和长周期元素性质变化差异的原因，涉及对元素周期表中不同周期元素电子排布的理解，以及电子排布如何影响元素性质的综合分析。这需要将多个概念（如周期表结构、电子排布、元素性质）关联起来进行解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对短周期元素和长周期元素性质差异的原因进行解释，涉及对元素周期表结构、电子排布以及性质变化规律的综合理解。需要考生不仅掌握基础概念，还能将不同知识点（如主族元素与过渡元素的电子排布特点）进行关联分析，并组织语言进行多角度的论述。虽然不需要达到深度关联性分析（等级5）的程度，但已超出简单概念复述（等级3）的要求，属于需要一定综合分析能力的题目。" + }, + { + "idx": 2505, + "question": "What are the performance characteristics of graphite?", + "answer": "Graphite has a loose structure and certain electrical conductivity, and is commonly used as a lubricant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释石墨的性能特点，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查石墨的基本性能特征，属于对材料基本性质的理解和记忆，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释石墨的性能特征，属于概念解释和描述的难度等级。虽然需要记忆石墨的基本特性（如松散结构和导电性），但不需要深入分析或构建复杂的理论体系。题目主要考察对基础概念的理解和简单应用，符合等级2的标准。" + }, + { + "idx": 2506, + "question": "Derive the conversion formula between the lattice constant $a_{R}$ in rhombohedral axes and the lattice constant $\\pmb{a}_{\\sf H}$ in hexagonal axes for a rhombohedral crystal.", + "answer": "Under $\\pmb{a}_{\\sf H}$, bH, $\\pmb{\\mathbb{G H}}$, $a_{R}=1/s$ [1 1], so the lattice constant $a_{R}=\\mathsf{L}$ $\\begin{array}{r l}&{=\\mathsf{a_{H}}\\bullet\\mathsf{s q r t}(\\mathsf{U}^{2}+\\mathsf{V}^{2}+\\mathsf{W}^{2}\\mathsf{c_{H}}^{2}/\\mathsf{a_{H}}^{2}-\\mathsf{U V})}\\ &{=\\V_{3}\\vee(3\\mathsf{a_{H}}^{2}+\\mathsf{c_{H}}^{2}),}\\end{array}$ Since ${\\pmb{\\upalpha}}_{\\aleph}$ is the angle between the crystallographic directions $\\%$ [1 1] and $\\%$ [121], the lattice constant $\\texttt{a}_{\\texttt{R}}$ $\\begin{array}{r l}{=\\mathsf{a r c o s}(c_{\\mathsf{G}_{\\mathsf{H}}}{}^{2}/\\mathsf{a}_{\\mathsf{H}}{}^{2}{}-3/2)/(3+\\mathsf{c}_{\\mathsf{H}}{}^{2}/\\mathsf{a}_{\\mathsf{H}}{}^{2})}\\ {=\\mathsf{a r c o s}(}&{(2\\mathsf{c}_{\\mathsf{H}}{}^{2}{}-3\\mathsf{a}_{\\mathsf{H}}{}^{2})/(6\\mathsf{a}_{\\mathsf{H}}{}^{2}+2\\mathsf{c}_{\\mathsf{H}}{}^{2}))\\circ}\\end{array}$ ) gives a H = aR·sqrt (2(1-cosα)); $c_{H}=a_{R}\\cdot\\mathsf{s q r t}(3(1+2\\cos\\theta)\\circ$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导晶格常数之间的转换公式，涉及数值计算和公式应用，答案中包含了具体的数学推导和公式变换，符合计算题的特征。 | 知识层次: 题目要求推导晶格常数在不同坐标系之间的转换公式，涉及多步计算和概念关联，需要理解晶格结构的基本原理并能够综合应用数学和晶体学知识。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在计算题中属于复杂多变量计算难度等级。题目要求推导晶格常数转换公式，涉及多个变量（a_R、a_H、c_H）和复杂的数学运算（包括向量运算、三角函数和平方根计算）。解题步骤需要综合运用晶体学知识和数学推导能力，属于该题型框架内的高难度问题。" + }, + { + "idx": 2507, + "question": "Why do the properties of elements change periodically with atomic number?", + "answer": "Because the properties of elements are mainly determined by the number of outer valence electrons, and the number of valence electrons changes periodically with atomic number, thus reflecting the periodic changes in the properties of elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素性质随原子序数周期性变化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对元素性质周期性变化的基本原理的理解和记忆，主要涉及外层价电子数与元素性质的关系，属于基础概念的记忆和理解层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释元素性质随原子序数周期性变化的原因，涉及对价电子数与元素性质关系的理解，需要基础概念记忆和简单逻辑推导，但不需要复杂的概念体系阐述或深入分析。" + }, + { + "idx": 2508, + "question": "What are the differences in the property changes between short-period elements and long-period elements?", + "answer": "The properties of long-period elements change more continuously and gradually, while the properties of short-period elements differ more significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述短周期元素和长周期元素在性质变化上的差异，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对短周期和长周期元素性质变化差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较短周期元素和长周期元素在性质变化上的差异，需要学生对元素周期表的基本概念有一定理解，并能进行简单的对比分析。虽然涉及多个概念，但不需要深入阐述复杂的概念体系，属于中等难度的简答题。" + }, + { + "idx": 2509, + "question": "Given the lattice constants of $\\mathsf{\\Omega}\\mathsf{a}-\\mathsf{A l}\\mathsf{\\Omega}_{2}\\mathsf{0}_{3}$ (rhombohedral crystal) as $\\mathtt{a}_{\\mathsf{R}}={\\mathsf{5}}.$ .12$\\mathring{\\mathbf{A}}$ 、 $a_{\\scriptscriptstyle\\textsf{R}}=55^{\\circ}17^{\\circ}$ ’, find its lattice constants $\\pmb{a}_{\\sf H}$ and $\\mathbf{GHo}$ in the hexagonal axes.", + "answer": "Using the formula from the previous question and substituting the values of aR and $\\texttt{a}_{\\texttt{R}}$, we obtain $a_{\\scriptscriptstyle\\ H}={\\bf\\nabla}4.75\\mathrm{~\\AA~}$ 、 $\\pmb{\\upalpha}_{\\mathsf{H}}=12.97\\mathrm{~\\AA~}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶格常数和角度，应用公式计算出六方晶系的晶格常数。答案中展示了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及晶格常数在不同坐标系下的转换，需要理解并应用相关公式，同时需要一定的综合分析能力来正确转换和计算数值。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和公式转换，涉及晶体结构参数的转换和综合分析。虽然题目提供了必要的参数，但需要正确理解和应用转换公式，并进行准确的计算，属于中等偏上的难度。" + }, + { + "idx": 2510, + "question": "What is the crystal structure of graphite?", + "answer": "The crystal structure of graphite is a simple hexagonal lattice, with carbon atoms located at the lattice points.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释石墨的晶体结构，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对石墨晶体结构这一基本概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答石墨的晶体结构，属于基本定义简答。题目不涉及复杂的概念解释或体系阐述，仅需记忆并复述简单的晶体结构描述即可。因此，在同题型和知识层次下，该题目属于最低难度等级。" + }, + { + "idx": 2511, + "question": "Derive the conversion formula between the lattice constant $\\\\mathfrak{a}_{R}$ in rhombohedral axes and the lattice constant $\\\\pmb{\\\\complement H}$ in hexagonal axes for a rhombohedral crystal.", + "answer": "In $\\\\pmb{a}_{\\\\sf H}$, $b_H$, $\\\\pmb{\\\\mathbb{G H}}$, $a_{R}=1/s$ [1 1], so the lattice constant $a_{R}=\\\\mathsf{L}$ $\\\\begin{array}{r l}&{=\\\\mathsf{a_{H}}\\\\bullet\\\\mathsf{s q r t}(\\\\mathsf{U}^{2}+\\\\mathsf{V}^{2}+\\\\mathsf{W}^{2}\\\\mathsf{c_{H}}^{2}/\\\\mathsf{a_{H}}^{2}-\\\\mathsf{U V})}\\\\ &{=\\\\V_{3}\\\\vee(3\\\\mathsf{a_{H}}^{2}+\\\\mathsf{c_{H}}^{2}),}\\\\end{array}$ Also, since ${\\\\pmb{\\\\upalpha}}_{\\\\aleph}$ is the angle between the crystallographic directions $\\\\%$ [1 1] and $\\\\%$ [121], the lattice constant $\\\\texttt{a}_{\\\\texttt{R}}$ $\\\\begin{array}{r l}{=\\\\mathsf{a r c o s}(c_{\\\\mathsf{G}_{\\\\mathsf{H}}}{}^{2}/\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2}{}-3/2)/(3+\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}/\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2})}\\\\ {=\\\\mathsf{a r c o s}(}&{(2\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}{}-3\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2})/(6\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2}+2\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}))\\\\circ}\\\\end{array}$ ) gives $a_H = a_R\\\\cdot\\\\sqrt{2(1-\\\\cos\\\\alpha)}$; $c_{H}=a_{R}\\\\cdot\\\\mathsf{s q r t}(3(1+2\\\\cos\\\\theta)\\\\circ$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导晶格常数之间的转换公式，涉及数学推导和公式应用，答案中包含了具体的数学运算和公式转换，符合计算题的特征。 | 知识层次: 题目要求推导晶格常数在不同晶系之间的转换公式，涉及多步计算和概念关联，需要综合分析晶格几何关系和坐标变换。虽然不涉及复杂的机理或创新设计，但需要一定的理解和应用能力来关联不同晶系的结构参数。 | 难度: 在计算题中属于复杂多变量计算难度，需要处理多个晶格常数之间的转换关系，涉及复杂的数学推导和三角函数应用。题目要求同时考虑rhombohedral和hexagonal两种晶系参数，并建立它们之间的精确数学关系，这需要深入理解晶体几何学原理和熟练的数学运算能力。解题过程中涉及多个转换步骤和变量关系，属于该题型内的高难度题目。" + }, + { + "idx": 2512, + "question": "Calculate the angles between low-index crystal planes with indices not exceeding 3 in cubic crystals (presented in a list). Why are the angles independent of the lattice constant?", + "answer": "Using the crystal plane angle formula $\\\\cos\\\\phi=(h_{1}h_{2}+k_{1}k_{2}+1,1,2)/\\\\{(h_{1}^{2}+k_{1}^{2}+1,^{2})\\\\ast(h_{2}^{2}+k_{2}^{2}+1,^{2}))$ to calculate. There may be multiple angles between two crystal plane families depending on the selected planes, only one is listed below, others are not discussed here.
cos in[100}[110}[111}[210}[211}[221}{310}
[100}1√2/2√3/32√5/5√ 6/32/33√10/10
[110}1√6/33√10/10√3/22√2/32√5/5
[111}1√15/52√2/35 √3/92√30/15
[210}1√30/62√5/57 √2/10
[211}17 √6/187 √15/30
[221}14√10/15
[310}1
The remaining results are omitted.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用晶体平面角度公式进行计算，并给出了具体的计算步骤和结果表格，属于典型的计算题类型。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用晶体平面角度公式计算立方晶体中低指数晶面之间的角度。虽然需要理解公式的含义，但整体上属于直接套用公式进行计算的任务，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，主要涉及单一公式的直接套用和简单计算。虽然题目要求计算多个晶面间的夹角，但每个计算步骤都是重复应用相同的晶体平面夹角公式，没有涉及多个公式的组合或复杂推导。此外，题目明确给出了计算公式，降低了理解难度。因此，在同题型内属于等级2难度。" + }, + { + "idx": 2513, + "question": "Discuss the significance of atomic radius in covalent crystals and its influencing factors, with examples", + "answer": "For covalent crystals, the atomic radius is defined as half the distance between the nearest neighboring atomic nuclei of the same element in the crystal. The type of bonding between atoms in covalent crystals—whether single, double, or triple bonds—will affect the atomic radius, so the largest single-bond atomic radius r(1) is generally used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论共价晶体中原子半径的意义及其影响因素，并提供例子。答案需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求讨论原子半径在共价晶体中的意义及其影响因素，并举例说明。这需要理解原子半径的定义，分析不同类型化学键对原子半径的影响，并能将概念与实际例子关联起来。虽然涉及基础概念，但需要一定的综合分析能力和知识点的关联运用，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要多角度分析论述。题目要求讨论共价晶体中原子半径的意义及其影响因素，并举例说明。这涉及到对原子半径定义的理解、不同类型化学键对原子半径的影响、以及实际例子的应用。解题步骤包括概念解释、因素分析、实例关联等多个环节，需要综合运用材料科学知识进行深入论述。" + }, + { + "idx": 2514, + "question": "Discuss the significance of atomic radius in metal crystals and its influencing factors, and provide examples for illustration", + "answer": "For metal crystals, the atomic radius is defined as half the distance between the nuclei of nearest-neighbor atoms in the crystal of the same element. In metal crystals, the coordination number affects the atomic radius. For example, α-Fe (CN=8) has an atomic radius 3% smaller than that of γ-Fe (CN=12). Generally, the atomic radius for CN=12 is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论金属晶体中原子半径的重要性及其影响因素，并提供示例进行说明。答案以文字解释和论述的形式呈现，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求讨论原子半径在金属晶体中的重要性及其影响因素，并提供实例说明。这需要理解原子半径的定义，分析配位数对原子半径的影响，并通过具体例子（如α-Fe和γ-Fe）进行说明。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对金属晶体中原子半径的意义及其影响因素进行多角度分析论述，包括定义、配位数的影响以及具体实例的说明。这需要学生不仅掌握相关概念，还能进行综合分析并举例说明，属于较高难度的要求。" + }, + { + "idx": 2515, + "question": "Discuss the significance of atomic radius in molecular crystals of nonmetals and its influencing factors, with examples provided.", + "answer": "For molecular crystals of nonmetals, there exist two atomic radii: one is the covalent radius, and the other is the van der Waals atomic radius (half the distance between adjacent molecules). For example, in the chlorine molecular crystal, the two radii are 0.099nm and 0.180nm, respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论非金属分子晶体中原子半径的意义及其影响因素，并提供例子。答案通过文字解释和具体例子进行论述，符合简答题的特征。 | 知识层次: 题目要求讨论非金属分子晶体中原子半径的意义及其影响因素，并提供例子。这需要理解原子半径的概念（包括共价半径和范德华半径），并能将其应用于具体实例（如氯分子晶体）。虽然涉及基础概念，但需要将这些概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对非金属分子晶体中的原子半径进行多角度分析论述，包括共价半径和范德华半径的定义、区别及其影响因素，并通过具体例子（如氯分子晶体）进行说明。这需要学生不仅掌握相关概念，还能进行综合分析，展示对知识点的深入理解和应用能力。因此，在简答题题型内属于较高难度等级。" + }, + { + "idx": 2516, + "question": "Explain the term: component", + "answer": "Each element (metal, non-metal) that constitutes an alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"component\"，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对\"component\"这一基本术语的定义记忆和理解，属于材料科学中最基础的概念性知识 | 难度: 在简答题题型中，该题目仅要求对基础术语\"component\"进行简单定义回答，属于最基本的概念记忆层次。题目不涉及概念间的关联性解释或复杂体系阐述，仅需直接回忆教材中的标准定义即可完成作答，符合等级1\"基本定义简答\"的典型特征。" + }, + { + "idx": 2517, + "question": "Explain the term: alloy", + "answer": "A material formed by the chemical bonding of a metal with one or more other elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"alloy\"，答案是一个文字解释和论述，没有选项、判断或计算要求。 | 知识层次: 题目考查对合金这一基本概念的定义记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，此题仅要求对\"alloy\"这一术语进行基本定义回答，属于最基础的概念记忆层面。题目不涉及概念间的关联解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同题型内相比，该题无需展开描述或分析，是金属材料学中最基础的定义性知识。" + }, + { + "idx": 2518, + "question": "Explain the term: sublattice", + "answer": "The respective Bravais lattices occupied by the constituent atoms in an ordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"sublattice\"，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对\"sublattice\"这一基本概念的定义记忆和理解，属于材料科学中晶体结构的基础知识范畴 | 难度: 在简答题题型中，该题目仅要求对\"sublattice\"这一术语进行基本定义回答，属于最基础的概念记忆层面。不需要进行概念间的关联解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最基础的知识点考察，解题步骤仅需直接回忆定义即可。" + }, + { + "idx": 2519, + "question": "Explain the term: intermetallic compound", + "answer": "A compound formed between metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"intermetallic compound\"，需要文字解释和论述，而不是从选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查对\"intermetallic compound\"这一基本术语的定义记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求对\"intermetallic compound\"进行基本定义简答，属于最基础的概念记忆层面。题目不涉及概念解释、特征描述或复杂体系阐述，仅需回忆并复述简单定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2520, + "question": "Explain the term: microstructure", + "answer": "Under certain external conditions, the collective of several different phases that constitute an alloy of a certain composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"microstructure\"，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对\"microstructure\"这一基本概念的定义和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答\"microstructure\"的基本定义，属于最基础的概念记忆性知识。题目不涉及概念间的关联解释或复杂体系阐述，仅需直接回忆教材或课堂中的标准定义即可完成作答，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 2521, + "question": "Discuss the significance of atomic radius in ionic crystals and its influencing factors, with examples provided.", + "answer": "For ionic crystals, the sizes of cations and anions are represented by ionic radii r+ and r-, respectively. Assuming that the same ion has the same radius in different ionic crystals, the ionic radius can be roughly determined. However, the ionic radius is only an approximate concept, as electrons cannot completely detach from the cation. Therefore, many ionic bonds have more or less covalent character. When this feature is particularly prominent, the significance of the ionic radius becomes less precise.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论离子晶体中原子半径的重要性及其影响因素，并提供例子。答案是一段详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求讨论离子晶体中原子半径的意义及其影响因素，并提供例子。这需要综合运用离子半径的概念、离子键的性质以及共价特性的影响，进行推理分析和机理解释。涉及的知识点较为复杂，且需要关联多个概念进行综合分析，思维过程的深度要求较高。 | 难度: 在简答题中属于机理深度解释难度等级。该题目要求讨论离子晶体中原子半径的意义及其影响因素，并提供实例。这需要学生不仅理解离子半径的基本概念，还要能够解释其在离子晶体中的具体应用和局限性，包括离子半径的近似性、共价特性的影响等。此外，题目还要求提供实例，这进一步增加了回答的复杂性和深度。因此，该题目在简答题中属于机理深度解释的难度等级。" + }, + { + "idx": 2523, + "question": "Explain the term: solid solution", + "answer": "The atoms of the solute and the solvent occupy a common Bravais lattice, and this lattice type is the same as that of the solvent; the content of the components can vary within a certain range without causing a change in the lattice type. Metal or non-metal compounds possessing these two properties are called solid solutions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"solid solution\"，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"solid solution\"这一基本概念的定义和特性的记忆和理解，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目要求解释\"solid solution\"这一概念，不仅需要给出基本定义，还需要描述其关键特征（如共同Bravais晶格、组分含量可变范围等）。这超出了单纯记忆定义的等级1要求，但尚未达到需要阐述复杂概念体系的等级3水平。题目主要考察对基础概念的理解和描述能力，属于典型的等级2概念解释题。" + }, + { + "idx": 2524, + "question": "Explain the term: phase", + "answer": "A portion or region within an alloy that has the same (or continuously varying) composition, structure, and properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"phase\"进行文字解释和论述，答案是一个详细的定义，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即对\"phase\"这一术语的定义进行解释，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求对\"phase\"这一基础概念进行定义性回答，属于最基础的定义简答级别。题目不涉及概念间的关联性解释或复杂体系阐述，仅需记忆并复述教材中的标准定义即可完成作答，符合等级1\"基本定义简答\"的全部特征。" + }, + { + "idx": 2525, + "question": "Explain the term: electronegativity", + "answer": "A parameter indicating the ability of an element to attract electrons when forming compounds or solid solutions with other elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"electronegativity\"，答案是一个文字解释和论述，没有涉及选项选择、判断对错或数值计算 | 知识层次: 题目考查基本概念的记忆和理解，仅要求解释电负性的定义，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求对\"electronegativity\"这一基础概念进行基本定义简答，不需要额外的解释或描述。题目直接询问术语的定义，属于最基础的概念记忆层次，没有涉及概念间的联系或复杂体系阐述。" + }, + { + "idx": 2526, + "question": "Explain the term: electron concentration", + "answer": "The average number of valence electrons per atom in an alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"electron concentration\"，需要文字解释和论述，答案提供了定义性的描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，仅要求解释\"electron concentration\"的定义，不涉及应用或分析。 | 难度: 在简答题题型中，该题目仅要求对\"electron concentration\"这一基础概念进行简单定义回答，属于最基本的概念记忆层次。题目不涉及概念间的联系或复杂解释，仅需直接复述定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2527, + "question": "Explain the term: superstructure (superlattice)", + "answer": "A complex lattice composed of the sublattices of each component in an ordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"superstructure (superlattice)\"，答案是一个文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"superstructure (superlattice)\"这一术语的基本定义和概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"superstructure (superlattice)\"这一术语进行基本定义解释，属于最基础的概念记忆层面。题目不涉及概念间的关联分析或复杂体系阐述，仅需简单回忆并复述定义即可完成作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2530, + "question": "How to theoretically determine the order-disorder transition temperature (Curie temperature)?", + "answer": "Theoretically, the transition temperature of ordered alloys can be determined by the relationship between the strength of metallic bonds and the magnitude of the average molecular free energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过理论方法解释如何确定有序-无序转变温度（居里温度），答案提供了理论解释和论述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求从理论上确定有序-无序转变温度（居里温度），涉及金属键强度和平均分子自由能之间的关系。这需要综合运用材料科学中的热力学、统计力学和固体物理知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用金属键强度与分子自由能的关系来解释有序-无序转变温度（居里温度）的理论确定方法。这需要对材料科学中的相变理论有深入理解，并能将多个复杂概念（如键合强度、自由能、相变温度）进行综合分析和推理。这种全面分析复杂现象的要求，在该题型框架内属于最高难度等级。" + }, + { + "idx": 2531, + "question": "Briefly describe the influence of electronegativity difference on solid solubility according to the Hume-Rothery rules", + "answer": "If the electronegativity difference between alloy components is large, the solid solubility is extremely small.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述电负性差异对固溶度的影响，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则中电负性差对固溶度影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目要求解释电负性差异对固溶度的影响，属于概念解释和描述的层次。虽然需要理解Hume-Rothery规则的基本原理，但不需要复杂的体系阐述或多步骤推理，因此属于中等难度。" + }, + { + "idx": 2532, + "question": "Briefly describe the practical significance of the Hume-Rothery rules", + "answer": "Although the Hume-Rothery rules are only negative rules, qualitative or semi-quantitative rules, and the latter three are limited to specific situations, they summarize some patterns of alloy solid solubility, helping to predict the extent of solid solubility. Thus, they are highly useful for determining the properties and heat treatment behavior of alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述Hume-Rothery规则的实际意义，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求对Hume-Rothery规则的实际意义进行解释和论述，涉及对规则的理解、应用及其在合金固溶度预测中的综合分析，需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于中等难度，需要理解Hume-Rothery规则的基本概念，并能简要说明其实际意义和应用价值。虽然不需要深入的多角度分析或深度关联性分析，但要求对规则的性质和局限性有一定的认识，并能将其与合金性能预测联系起来进行综合分析。" + }, + { + "idx": 2533, + "question": "Briefly describe the law of solid solubility of specific group elements in the Hume-Rothery rules", + "answer": "The solid solubility of solute elements from groups 11B to VB in solvent elements of group IB is the same (θ/a=1.36), regardless of the specific element types.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Hume-Rothery规则中特定族元素的固溶度定律，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对Hume-Rothery规则中特定组元素固溶度定律的基本概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述Hume-Rothery规则中特定族元素固溶度的规律，需要学生对这一基本原理有一定的理解和记忆，并能用文字进行准确表述。虽然涉及特定元素族的固溶度规律，但不需要复杂的推导或深入分析，属于中等难度的概念解释题。" + }, + { + "idx": 2534, + "question": "Briefly describe the influence of atomic valence on solid solubility according to the Hume-Rothery rules", + "answer": "The solid solubility of two elements is related to their atomic valence. The solubility of a high-valence element in a low-valence element is greater than that of a low-valence element in a high-valence element.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述原子价对固溶度的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则中原子价对固溶度影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述原子价对固溶度的影响，这需要理解Hume-Rothery规则中的一个具体方面，并进行适当的文字解释。虽然涉及基本原理，但不需要复杂的体系阐述或多步骤推理，属于中等难度的概念解释题。" + }, + { + "idx": 2535, + "question": "Briefly describe the influence of atomic radius difference on solid solubility according to the Hume-Rothery rules", + "answer": "If the difference in atomic radii of the elements forming the alloy exceeds 14%~15%, the solid solubility is extremely limited.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述原子半径差异对固溶度的影响，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则中原子半径差异对固溶度影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要理解Hume-Rothery规则中关于原子半径差对固溶度的影响，但不需要进行复杂的概念体系阐述或深入分析。题目要求简要描述基本原理，属于中等难度的概念解释题。" + }, + { + "idx": 2536, + "question": "Using the Darken-Gurry diagram to analyze elements that may have relatively high solid solubility in Mg", + "answer": "Possible elements include Cd, Nb, Ti, Ce, Hf, Zr, Am, P, Sc, and lanthanides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Darken-Gurry图分析元素在Mg中的固溶度，答案给出了可能的元素列表，属于需要文字解释和论述的简答题形式。 | 知识层次: 题目要求使用Darken-Gurry图来分析元素在Mg中的固溶度，这需要理解Darken-Gurry图的基本原理，并能够将多个元素的性质（如原子半径和电负性）与Mg进行比较和关联。虽然不需要复杂的计算或深入的机理分析，但需要对多个概念进行综合应用和判断，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要运用Darken-Gurry图进行多元素分析，涉及多个概念关联和综合判断，且需要对元素性质有较深入的理解。" + }, + { + "idx": 2537, + "question": "What is the relationship between the mechanical properties of a solid solution and those of its pure components? Please provide a qualitative explanation.", + "answer": "The strength and hardness of a solid solution are often higher than those of its components, while the plasticity is lower. This is because: (1) For interstitial solid solutions, solute atoms tend to preferentially distribute along dislocation lines, forming interstitial atom 'atmospheres' that firmly pin the dislocations, thereby strengthening the material; (2) For substitutional solid solutions, solute atoms are usually uniformly distributed within the lattice, causing lattice distortion, which increases the resistance to dislocation motion, though this strengthening effect is relatively smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对固溶体与其纯组元机械性能之间的关系进行定性解释，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求对固溶体机械性能与其纯组分之间的关系进行定性解释，涉及对固溶强化机理的理解和分析，包括间隙固溶体和置换固溶体的不同强化机制。这需要综合运用材料科学中的位错理论、晶格畸变等概念，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对固溶体的力学性能与其纯组元之间的关系进行定性解释，涉及对间隙固溶体和置换固溶体的强化机理的深入理解。需要综合运用材料科学中的位错理论、晶格畸变等概念，并进行推理分析。虽然题目没有要求定量计算或复杂的实验数据分析，但对机理的解释需要一定的深度和逻辑性，属于机理深度解释的难度等级。" + }, + { + "idx": 2538, + "question": "What is Vegard's law?", + "answer": "Experiments have found that when two isomorphous salts form a continuous solid solution, the lattice constant of the solid solution has a linear relationship with the composition, meaning the lattice constant is proportional to the concentration of any component. This is Vegard's law.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Vegard's law的定义和内容，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Vegard's law这一基本概念的定义和基本原理的记忆和理解，不涉及应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释Vegard's law的定义和基本原理，但不需要阐述复杂的理论体系或进行多层次的论证。题目主要考察对基础概念的记忆和理解，属于中等难度的简答题。" + }, + { + "idx": 2539, + "question": "Briefly describe the influence of crystal structure on solubility according to the Hume-Rothery rules", + "answer": "Only when the two components have the same crystal structure can they form an infinite (or continuous) solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述晶体结构对溶解度的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对Hume-Rothery规则中晶体结构对溶解度影响的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求根据Hume-Rothery规则简要描述晶体结构对溶解度的影响，需要学生理解并解释基本原理，但不需要进行复杂的体系阐述或多概念综合分析。这属于对基础概念的理解和简单应用，符合等级2的特征。" + }, + { + "idx": 2540, + "question": "Why do real solid solutions often not conform to Vegard's law?", + "answer": "Because Vegard's law reflects the influence of composition on the structure of alloy phases, but the structure of alloy phases is affected not only by composition but also by other factors (such as electron concentration, electronegativity, etc.), which cause real solid solutions to deviate from Vegard's law.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么实际固溶体不符合Vegard定律，答案提供了详细的文字解释和论述，涉及多个影响因素的分析，符合简答题的特征。 | 知识层次: 题目要求解释实际固溶体偏离Vegard定律的原因，涉及多个影响因素（电子浓度、电负性等）的综合分析，需要深入理解合金相结构的复杂机制并进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对Vegard定律的局限性进行机理深度解释，需要综合运用电子浓度、电负性等多重因素分析合金相结构的影响机制。虽然不涉及跨学科整合(等级5特征)，但已超出基础概念复述，达到需要建立多因素关联推理的层次，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 2541, + "question": "What is the relationship between the physical properties of a solid solution and those of the pure components? Please provide a qualitative explanation.", + "answer": "The electrical, thermal, magnetic, and other physical properties of a solid solution also change continuously with composition, but generally not in a linear relationship. This is because solute atoms usually disrupt the original physical properties of the solvent. However, when the alloy is in an ordered state, the physical properties undergo abrupt changes, exhibiting superior physical performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对固体溶液与纯组分的物理性质关系进行定性解释，答案提供了详细的文字论述而非选择、判断或计算。 | 知识层次: 题目要求对固溶体物理性质与纯组分之间的关系进行定性解释，涉及多个物理性质（电、热、磁等）的综合分析，以及有序态对性质影响的机理说明。这需要深入理解固溶体的微观结构和性质变化机制，属于综合运用和推理分析的层次。 | 难度: 在简答题题型中，该题目要求对固溶体的物理性质与纯组分之间的关系进行定性解释，涉及多个物理性质（电、热、磁等）的综合分析，并需要理解固溶体有序状态对物理性质的突变影响。虽然不需要定量计算，但需要对材料科学中的固溶体机理有较深的理解，属于机理深度解释的难度等级。" + }, + { + "idx": 2542, + "question": "Discuss the general rules of oxide structures.", + "answer": "An important characteristic of oxide structures is the close packing of oxygen ions. In most simple oxide structures, oxygen ions are arranged in face-centered cubic, hexagonal close-packed, or approximately close-packed simple cubic configurations, while the cations occupy octahedral interstitial sites, tetrahedral interstitial sites, or the body center of the simple cubic lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求讨论氧化物结构的一般规则，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对氧化物结构基本规则的理解和记忆，涉及氧离子排列方式和阳离子占据位置的基础知识，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求讨论氧化物结构的一般规则，涉及氧离子的紧密堆积方式以及阳离子的占据位置等基本概念。虽然需要一定的记忆和理解，但并不需要复杂的体系阐述或多层次的概念整合，属于中等难度的概念解释类题目。" + }, + { + "idx": 2543, + "question": "Analyze the crystal structure of rutile using Pauling's rules", + "answer": "For rutile: (1) The cation-anion radius ratio is 0.48. According to Table 2-8 on page 104 of the textbook, it can be seen that the anion polyhedron is an octahedron, and the cation coordination number is 6; (2) Z+=4, Z-=2, so CN-=CN+•Z-/Z+=6/2=3.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析金红石的晶体结构，并应用Pauling规则进行解释。答案提供了详细的文字解释和计算过程，符合简答题的特征，即需要文字解释和论述。 | 知识层次: 题目要求应用Pauling's rules分析金红石的晶体结构，涉及多步计算（如阳离子-阴离子半径比、配位数计算）和概念关联（如配位数与电荷平衡的关系），需要综合分析能力。虽然不涉及复杂的推理或创新设计，但超出了简单记忆或直接套用的层次。 | 难度: 在简答题题型中，该题目要求对晶体结构进行多角度分析，包括应用Pauling规则、计算配位数、分析离子半径比等。虽然不涉及最复杂的深度关联性分析，但需要综合运用多个概念和计算步骤，属于较高难度的简答题。" + }, + { + "idx": 2544, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of the main factors determining their structures and theoretical foundations.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Electronegativity, electron shell theoryElectron concentration, electron theoryComponent atomic radius ratio, topologyComponent atomic radius ratio, spatial geometry
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型的金属间化合物进行总结和比较，需要文字解释和论述，答案以表格形式呈现了不同化合物的理论基础和决定因素，符合简答题的特征。 | 知识层次: 题目要求对不同类型金属间化合物的结构决定因素和理论基础进行比较和总结，这需要综合运用多个知识点，进行推理分析和机理解释。涉及的知识点复杂且关联度高，思维过程要求深入。 | 难度: 在简答题题型中，该题目要求综合运用多个知识点（包括价化合物、电子化合物、TCP相和间隙相）进行深度比较分析，涉及电子理论、拓扑学、空间几何等多学科理论。需要考生不仅掌握各化合物的结构决定因素，还要理解其背后的理论基础，并能系统性地进行对比阐述。这种复杂现象全面分析的要求在简答题中属于最高难度等级。" + }, + { + "idx": 2545, + "question": "Describe Pauling's rules regarding the structure of ionic compounds", + "answer": "(1) A coordination polyhedron of anions is formed around the cation, with the distance between the cation and anion determined by the sum of their ionic radii, and the coordination number determined by the ratio of the cation to anion radii; (2) The number of valence electrons provided by the cation equals the number of valence electrons received by the anion, hence Z+/CN+=Z-/CN-; (3) In a coordination structure, when coordination polyhedra share edges, especially faces, their stability decreases, and this effect is more pronounced for cations with higher valence and lower coordination numbers; (4) In crystals containing more than one type of cation, the coordination polyhedra of anions around cations with higher valence and smaller coordination numbers tend to connect by sharing vertices; (5) The types of coordination polyhedra in a crystal tend to be minimized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述Pauling关于离子化合物结构的规则，需要文字解释和论述，答案以列举要点形式呈现，符合简答题的特征 | 知识层次: 题目考查对Pauling规则的基本概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求完整阐述Pauling的五条规则，涉及多个复杂概念及其相互关系。需要考生不仅记忆每条规则的内容，还要理解离子半径比、配位数、配位多面体连接方式等概念之间的逻辑关联。相比只需回答基本定义(等级1)或简单概念解释(等级2)的简答题，该题目要求对复杂概念体系进行系统阐述，属于该题型内的高难度题目。" + }, + { + "idx": 2546, + "question": "Summarize and compare the performance characteristics of various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds)", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Non-metallic or semiconducting propertiesDistinct metallic characteristicsHard and brittle phases, Cr3Si-type structure alloys mostly exhibit superconducting propertiesWide mutual solid solubility range, distinct metallic properties, very high melting points, extremely high hardness and brittleness
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型的金属间化合物的性能特征进行总结和比较，需要文字解释和论述，答案以表格形式呈现了详细的比较内容，符合简答题的特征。 | 知识层次: 题目要求对不同类型金属间化合物的性能特征进行总结和比较，这需要将多个概念关联起来进行综合分析，而不仅仅是记忆单个概念。虽然不涉及复杂的计算或机理分析，但需要对各类化合物的特性有较深入的理解和对比能力，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对多种金属间化合物的性能特征进行总结和比较，涉及多个概念的综合分析和论述。需要掌握不同化合物的特性，并能进行多角度的对比分析，属于较高难度的简答题。" + }, + { + "idx": 2547, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of their constituent elements.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Metal and metal, metal and metalloidElements, Group VII (ironSmall metal elementsGroup metal elements and atomic radii
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，需要文字解释和论述，而不是选择、判断或计算。答案以表格形式呈现，但本质上是对各类化合物的描述和比较，属于简答题范畴。 | 知识层次: 题目要求对不同类型的金属间化合物进行总结和比较，涉及多个概念（价化合物、电子化合物、TCP相、间隙相等）的关联和综合分析，需要理解各类型化合物的组成元素特点并进行对比，属于中等应用层次的知识要求。 | 难度: 在简答题题型中，该题目要求对多种金属间化合物（价化合物、电子化合物、TCP相、间隙相等）的组成元素进行总结和比较。这需要学生不仅掌握每种化合物的基本定义和特性，还要能够进行多角度的分析和论述，包括不同化合物之间的异同点。这种综合分析能力的要求使得该题目在同题型中属于较高难度等级（等级4）。" + }, + { + "idx": 2548, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of their structural characteristics", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Transfer or sharing to form stable 8-electronStructure mainly determined by electron concentrationStacked in a certain order by close-packed tetrahedronsFCC or CPH structure, metalloid atoms located in tetrahedral
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，需要文字解释和论述，答案以表格形式呈现了各类化合物的结构特征，属于简答题类型 | 知识层次: 题目要求对不同类型的金属间化合物进行总结和比较，涉及多个概念的综合分析和关联，需要理解各类化合物的结构特征并进行对比，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对多种金属间化合物（价化合物、电子化合物、TCP相、间隙相）的结构特征进行总结和比较。这需要学生不仅掌握每种化合物的基本概念，还需要能够进行多角度的分析和论述，包括电子转移、电子浓度、堆垛方式以及晶体结构等方面的综合比较。这种题目在中等应用知识层次中属于较高难度，因为它要求学生对多个相关概念有深入理解，并能进行系统的关联性分析。" + }, + { + "idx": 2549, + "question": "What are the main types of silicate structures?", + "answer": "The main types of silicate structures can be classified according to the spatial arrangement of silicon-oxygen tetrahedra into: island, chain, sheet, and framework.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举硅酸盐结构的主要类型，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，属于基础知识点，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举并简要说明硅酸盐结构的主要类型，不需要深入的解释或复杂的论述。知识点掌握深度要求较低，解题步骤简单，只需记忆和复述基础分类即可。" + }, + { + "idx": 2550, + "question": "Given that the outer surface of a copper single crystal sample is (111), analyze the possible angles between slip lines that may appear on this outer surface when the crystal undergoes slip at room temperature.", + "answer": "The possible slip planes are the {111} family of crystal planes, and their intersections with the (111) plane may be [ 10], [0 1], [10 ], so the slip lines are either parallel or at a 60-degree angle to each other.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析铜单晶样品在特定条件下可能出现的滑移线角度，需要基于晶体学知识进行文字解释和论述，而不是简单的选择、判断或计算。答案也以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目要求分析铜单晶样品在特定表面(111)上可能出现的滑移线角度，需要理解晶体滑移的基本原理（{111}滑移面族），并能将这些概念应用于具体晶体取向的分析。虽然不涉及复杂计算，但需要将晶体学概念与几何分析相结合，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析晶体滑移面和表面取向的关系，推导可能的滑移线角度，并解释其几何关系。题目要求考生不仅掌握基本的晶体学知识，还需要能够将不同概念（如滑移面、表面取向、滑移线方向）关联起来进行多角度分析。解题步骤涉及确定滑移面族、计算与表面的交线、推导可能的夹角等多个环节，复杂度较高。" + }, + { + "idx": 2551, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of bonding types.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Ionic or covalent bondsPrimarily metallic bondsMetallic bondsMixed type: metallic bonds between metal atoms, and covalent bonds between metal and metalloid atoms
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型的金属间化合物进行总结和比较，需要文字解释和论述，答案以表格形式呈现了详细的比较内容，符合简答题的特征。 | 知识层次: 题目要求对不同金属间化合物（价化合物、电子化合物、TCP相、间隙相）的键合类型进行总结和比较，这需要理解各类化合物的基本概念，并能进行概念关联和综合分析。虽然不涉及复杂的计算或推理，但需要对多种化合物的键合类型进行对比和归纳，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对四种不同类型的金属间化合物进行总结和比较，涉及多种键合类型的分析和论述。需要考生具备较深的知识掌握和多角度分析能力，能够综合运用所学知识进行详细解释和比较。虽然不需要进行深度关联性分析（等级5），但已经超出了简单的概念说明（等级3），属于多角度分析论述的难度等级。" + }, + { + "idx": 2552, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the initial slip system.", + "answer": "The aluminum single crystal has an FCC structure, and [2 3] lies within the orientation triangle [001]―[1 1]―[101]. Therefore, the initial slip system is (111)[0 1].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过分析和解释来确定初始滑移系统，答案需要文字描述和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解FCC结构的滑移系统，并能够将给定的方向[2 3]定位到标准三角形中，进而确定初始滑移系统。这涉及到多步分析和概念关联，需要一定的空间想象力和对晶体学知识的应用能力。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求确定铝单晶在特定方向受力时的初始滑移系统，需要学生掌握FCC结构的基本知识、取向三角形的概念，并能进行多步分析和综合判断。虽然涉及多个概念和步骤，但不需要进行深度关联性分析或多角度论述，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 2553, + "question": "Write all possible slip systems for an FCC crystal at room temperature (specific crystallographic plane and direction indices are required).", + "answer": "There are a total of 12 possible slip systems: (111)[10 ], (111)[01 ], (111)[1 0], ( 11)[110], ( 11)[0 1], ( 11)[101], (1 1)[110], (1 1)[10 ], (1 1)[011], (11 )[011], (11 )[101], (11 )[1 0].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举所有可能的滑移系统，需要提供具体的晶面和晶向指数，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对FCC晶体滑移系统的基本概念记忆，需要准确写出特定晶面和晶向指数，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要记忆并列举FCC晶体的12个滑移系统，包括具体的晶面和晶向指数。虽然不需要复杂的推导或解释，但要求对晶体结构的基本概念有清晰的理解和记忆。" + }, + { + "idx": 2554, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) from typical examples.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
MgSe, Pt2P, Mg2Si, MnS, MgS, MnAsCuZn, CusZn8, CuZn3MgCu2, MgZn2, MgNi2 (Laves phases), Fe-Cr alloys (phases), Cr3SiFe4N, Fe2N, NaH, TiH2 (simple); Fe3C, Cr23C6, Fe4W2C (complex)
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，并提供典型例子。答案以表格形式呈现，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求总结和比较不同类型的金属间化合物，涉及多个概念（价化合物、电子化合物、TCP相、间隙相等）的关联和综合分析。虽然需要记忆一些典型例子，但更侧重于对这些化合物的分类、特点和典型实例的综合理解和比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对多种金属间化合物进行总结和比较，涉及多个概念（如价化合物、电子化合物、TCP相、间隙相等）的综合分析。题目不仅需要列举典型例子，还需要对这些化合物的特性和差异进行多角度的论述。这种要求超出了简单的概念回忆或单一分析，属于需要多步概念关联和综合分析的难度等级。因此，在同题型内属于较高难度（等级4）。" + }, + { + "idx": 2555, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the rotation rule and the rotation axis.", + "answer": "The specimen axis turns toward [0 1], and the rotation axis is [2 1 3]×[0 1 1]=[2 1 2], i.e., [1 ].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定旋转规则和旋转轴，答案提供了详细的推导过程和结果，属于需要文字解释的简答题类型。 | 知识层次: 题目需要理解晶体取向和旋转规则，并应用向量叉积计算旋转轴，涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要理解晶体学方向指数的计算、向量叉积的应用以及旋转规则的推导。解题步骤涉及多步计算和概念关联，要求综合分析能力。虽然不需要深度关联性分析，但相比同类简答题，其计算和推导过程更为复杂，属于多角度分析论述的难度等级。" + }, + { + "idx": 2556, + "question": "If tension is applied along the [110] direction of an FCC crystal, please write down the possible activated slip systems.", + "answer": "There are four possible activated slip systems, which are (111)[101], (111)[011], (111)[110], (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出可能的激活滑移系统，需要文字解释和列举具体的滑移系统，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求学生在理解FCC晶体结构和滑移系统的基础上，应用施密特定律来确定在特定方向施加张力时可能激活的滑移系统。这需要学生将多个概念（如晶体方向、滑移面和滑移方向）关联起来，并进行综合分析，而不仅仅是记忆或简单应用。 | 难度: 在简答题中，该题目属于较高难度。首先，题目要求分析FCC晶体在特定方向受力时的滑移系统激活情况，这需要对FCC晶体结构、滑移系统的基本概念有深入理解。其次，解题过程需要综合运用晶体学知识，包括确定滑移面和滑移方向，并分析它们与施加应力方向的几何关系。此外，题目还要求列举所有可能的滑移系统，这需要系统性的思考和验证。虽然不需要进行复杂的数学计算，但概念关联和综合分析的要求较高，因此在该题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 2557, + "question": "Using computer verification, it is determined that the image rule for slip systems applies to both FCC crystals and BCC crystals with {110}<111> slip systems. (Hint: For any given external force direction, use a computer to calculate the orientation factors for all equivalent slip systems.)", + "answer": "μ=cosλcosφ, calculate μ for all equivalent slip systems, and it can be found that μ_max must correspond to the slip system selected by the image rule.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用计算机验证并计算取向因子μ（μ=cosλcosφ）对于所有等效滑移系统，并找到μ_max对应的滑移系统。这涉及到具体的数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目要求使用计算机验证滑移系统的取向因子计算，涉及多步计算和概念关联（如滑移系统、取向因子、图像规则等），需要综合分析不同滑移系统的计算结果，但不需要进行复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用公式μ=cosλcosφ进行多步计算，并对所有等效滑移系统进行计算比较，同时需要理解图像规则的概念及其在FCC和BCC晶体中的应用。虽然计算过程较为直接，但涉及多个滑移系统的综合分析，因此属于中等偏上的难度。" + }, + { + "idx": 2558, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the double slip system.", + "answer": "The double slip system is (111)[0 1]－( 1)[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定双滑移系统，需要基于晶体学知识和方向分析进行文字解释和论述，答案是一个具体的滑移系统组合而非数值计算结果或简单判断。 | 知识层次: 题目要求确定双滑移系统，需要理解晶体滑移的基本原理，并能够应用施密特定律（Schmid's Law）来分析给定方向的应力作用。这涉及到多步计算和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要多步计算和概念关联。具体来说，解题过程涉及确定铝单晶的滑移系统，需要理解晶体学方向、滑移面和滑移方向的概念，并进行综合分析以确定双滑移系统。虽然不需要深度关联性分析，但需要多角度分析论述，因此难度等级为4。" + }, + { + "idx": 2560, + "question": "If a single crystal aluminum rod with a diameter of $5mm$ starts to slip when a tensile force of 40N is applied along the rod axis [123], find the critical resolved shear stress of aluminum during slipping.", + "answer": "Single crystal aluminum has an FCC structure, and the slip system is {111}<110>. Using the imaging rule, the slip plane and slip direction are determined to be (11)[101]. The angles between them and the axis are respectively: $$ \\begin{array}{r l}&{\\mathtt{cos}\\Phi=\\left[123\\right]\\bullet[\\overline{{1}}11]/(\\left|\\left[123\\right]\\right|\\left[\\overline{{1}}11\\right]|)=4/\\surd42;}\\ &{\\mathtt{cos}\\mathtt{\\lambda}=\\left[123\\right]\\bullet[101]/(\\left|\\left[123\\right]\\right|\\left[101\\right]|)=2/\\surd7;}\\end{array} $$ Therefore, the critical resolved shear stress τc = $\\mathsf{\\bar{cos}\\lambda cos\\Phi/A_{0}=\\lambda\\cdots=0.95MPa}.$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界分解剪切应力，解答过程中涉及角度计算、应力公式应用等数值运算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括确定滑移面和滑移方向、计算角度、应用临界分切应力公式等。虽然涉及的概念和公式较为基础，但需要综合运用多个知识点并进行较为复杂的计算过程。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求确定临界分解剪应力，涉及晶体结构分析、滑移系统确定、角度计算以及应力公式应用。虽然步骤较多，但每个步骤相对明确，属于该题型内的中等偏上难度。" + }, + { + "idx": 2561, + "question": "What are the basic characteristics of silicate structures?", + "answer": "The basic characteristics of silicate structures include: (1) The fundamental structural unit of silicates is the [SiO4] tetrahedron, with silicon atoms located in the interstices of the oxygen tetrahedron; (2) Each oxygen can be shared by at most two [SiO4] tetrahedra; (3) [SiO4] tetrahedra can exist isolated in the structure or be interconnected by sharing vertices; (4) The Si-O-Si bond forms a bent line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述硅酸盐结构的基本特征，答案以文字形式详细列出了多个特点，符合简答题的特征。 | 知识层次: 题目考查对硅酸盐结构基本特征的记忆和理解，属于基础概念和基本原理的范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答硅酸盐结构的基本特征，涉及对[SiO4]四面体结构单元、氧原子共享规则、四面体连接方式以及Si-O-Si键型的描述。这些内容属于材料科学基础概念，需要学生记忆并理解相关知识点，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目需要更多的解释和描述；相比等级3的复杂概念体系阐述，该题目的知识点较为集中且不涉及多层次的逻辑推导。" + }, + { + "idx": 2562, + "question": "If a single crystal of aluminum is stretched along the [2 3] direction, determine the final orientation (stable orientation) of the crystal.", + "answer": "From (5), it can be seen that the final orientation of the crystal is [1 2].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定铝单晶在拉伸后的最终取向，需要解释和论述晶体取向的变化过程，答案给出了具体的取向结果但没有提供选项或计算步骤，属于需要文字解释的简答题类型。 | 知识层次: 题目需要理解晶体拉伸过程中的取向变化，并应用相关原理进行多步分析和计算，涉及概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解晶体拉伸的基本概念，进行多步计算和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2563, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the crystal orientation and shear strain at the onset of double slip.", + "answer": "Using L=ds/+dt dt∨(/⋅↗)db, let L=[u u w], then L=[2 1 3]+4Y[0 1 1]/√6, from which it can be determined that u=2, v=4, γ=√6/4. Therefore, the crystal orientation is [2 4], i.e., [1 2], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体取向和剪切应变，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，涉及晶体取向和剪切应变的综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体取向和剪切应变的概念，进行多步计算和综合分析。题目涉及向量运算和公式应用，但步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 2564, + "question": "Niobium single crystal has a BCC structure, with [2 3] located in the orientation triangle [001]―[1 1]―[101]. What is the initial slip system?", + "answer": "The initial slip system is (0 1)[111].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定初始滑移系统，需要基于晶体结构和取向三角形的知识进行解释和论述，答案是一个具体的滑移系统描述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求确定铌单晶的初始滑移系统，需要理解BCC结构的滑移系统特点，并能够将给定的晶向定位在取向三角形中，进而确定最可能的滑移系统。这涉及到多步分析和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。需要学生掌握BCC晶体结构的滑移系统知识，能够正确识别取向三角形中的晶向，并通过综合分析确定初始滑移系统。解题过程涉及多步计算和概念关联，要求学生对晶体学知识有较深的理解和应用能力。" + }, + { + "idx": 2565, + "question": "Change the tension in the previous question to compression, determine the initial slip system", + "answer": "[2 3] is located in the orientation triangle [001]―[1 1]―[101], so the initial slip system is (111)[0 1]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过分析晶体取向和应力状态来确定初始滑移系统，需要文字解释和论述，而不是简单的选择、判断或计算。答案给出了具体的滑移面和滑移方向，属于简答形式。 | 知识层次: 题目要求将张力条件改为压缩条件，并确定初始滑移系统。这需要理解晶体滑移系统的基本原理，并能根据不同的应力条件（张力或压缩）进行分析和判断。虽然涉及基础概念，但需要多步思考和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等应用难度。题目要求将张力改为压缩后确定初始滑移系统，涉及多步计算和概念关联。虽然需要综合分析，但解题步骤相对明确，不需要多角度或深度关联性分析。因此，在同类简答题中属于等级3的综合分析和说明难度。" + }, + { + "idx": 2566, + "question": "Change the tension in the previous question to compression, determine the double slip system", + "answer": "The double slip system is (111)[0 1]－(1 1)[011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过改变条件（从张力变为压缩）来确定双滑移系统，答案是一个具体的滑移系统描述，需要基于材料科学知识进行解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求将拉伸条件改为压缩条件后确定双滑移系统，这需要对晶体滑移系统的基本原理有理解，并能根据不同的应力条件（拉伸或压缩）进行综合分析。虽然不涉及复杂的计算或深度推理，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要进行多步计算和概念关联。题目要求改变应力状态（从张力到压缩）并确定双滑移系统，这需要学生理解晶体滑移系统的基本原理，并能综合分析不同应力状态下的滑移系统选择。此外，答案涉及具体的滑移面和滑移方向，需要学生具备一定的空间想象能力和对晶体结构的深入理解。因此，该题目在简答题中属于多角度分析论述的难度等级。" + }, + { + "idx": 2567, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the rotation law and rotation axis of the crystal during double slip.", + "answer": "During double slip, the specimen axis rotates towards [0 1], with the rotation axis n1=[1 1 2]×[0 1 1]=[1 1 1], and simultaneously rotates towards [101], with the rotation axis n2=[1 1 2]×[101]=[1 1 1]. The resultant rotation axis is [000], so the crystal no longer rotates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释双滑移过程中晶体的旋转规律和旋转轴，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析铝单晶在双滑移过程中的旋转规律和旋转轴，涉及晶体学方向、滑移系统相互作用以及旋转轴的矢量计算。这需要综合运用晶体塑性变形的基本原理、矢量运算和滑移系统的相互作用分析，属于较高层次的认知能力要求，涉及多步骤推理和综合分析。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体学、力学和材料科学知识，进行多步骤推理和机理解释。需要同时处理双滑移系统的旋转定律和旋转轴计算，并最终推导出晶体停止旋转的结论。这种综合分析和复杂现象解释的要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 2568, + "question": "The sample axis is rotated to [111], what is the rotation axis?", + "answer": "The rotation axis is [2 1 3]×[111]=[4 1 3].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行向量叉乘计算来得出旋转轴的具体数值，属于需要数值计算和公式应用的计算题。答案给出了具体的计算结果[4 1 3]，这进一步确认了这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及向量叉积的应用，需要理解旋转轴的概念和计算方法，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解向量叉积的概念并进行多步计算，涉及数值运算和公式应用，但不需要处理复杂多变量情况。" + }, + { + "idx": 2569, + "question": "Change the tension in the previous question to compression, determine the specimen axis rotation direction and rotation axis", + "answer": "The specimen axis rotation direction is [111], and the rotation axis is $[2\\bar{1}3]\\times[111]=[\\bar{4}13]$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定试样轴的旋转方向和旋转轴，答案给出了具体的旋转方向和旋转轴的计算结果，属于需要文字解释和论述的简答题。 | 知识层次: 题目要求在改变应力条件（从张力变为压缩）后，确定试样轴的旋转方向和旋转轴。这需要理解晶体学方向的概念，并能进行向量叉积计算。虽然涉及一定的计算步骤和概念关联，但不需要复杂的推理或深度理解。 | 难度: 在简答题题型中，该题目需要学生不仅理解材料科学中的晶体学概念，还需要进行多步计算和综合分析。具体来说，题目要求学生改变应力状态（从张力到压缩），并在此基础上确定晶体轴的旋转方向和旋转轴。这涉及到对晶体学方向的深入理解、向量运算的应用以及综合分析能力。虽然题目提供了部分计算步骤，但学生仍需具备较强的概念关联和计算能力才能完整解答。因此，在简答题的中等应用层次中，该题目属于较高难度，需要多角度分析论述。" + }, + { + "idx": 2570, + "question": "Change the tension in the previous question to compression, and calculate the crystal orientation and shear strain", + "answer": "Using $A=a-\\textsf{v}(a\\cdot b)n,$, let $\\textsf{A}=\\textsf{[u0w]}$, we get $\\mathsf{A}=[2\\bar{1}3]-4\\lor[111]/\\surd6$. From this, it can be seen that $\\scriptstyle{\\boldsymbol{\\mathsf{u}}}=3$, $v=4$, $\\gamma=-\\sqrt{6/4}$, so the crystal orientation is [304], and the shear strain is - $\\surd6/4$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行具体的数值计算（计算晶体取向和剪切应变），并给出了详细的公式应用过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶体取向和剪切应变的计算，涉及公式应用和概念关联，需要一定的综合分析能力。虽然不涉及复杂的推理分析或机理解释，但比简单应用更复杂。 | 难度: 在计算题中属于综合性计算问题，需要应用公式进行多步计算，并理解晶体取向和剪切应变的概念。题目要求改变张力为压缩，并重新计算晶体取向和剪切应变，涉及多个变量的调整和综合分析。虽然计算步骤较多，但并未达到复杂多变量计算的级别。" + }, + { + "idx": 2571, + "question": "Change the tension in the previous question to compression, analyze the rotation of the specimen axis and the resultant rotation axis during double slip.", + "answer": "During double slip, the specimen axis rotates towards [111], with the rotation axis $\\mathsf{n}_{1}=[304]\\times[111]=[\\bar{4}13]$, and simultaneously rotates towards [1 1], with the rotation axis $n_{2}=[304]\\times[1\\overline{{{1}}}1]=[41\\overline{{{3}}}]$. The resultant rotation axis is [020], i.e., [010], so after double slip, point F moves along the edge [001]－[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析双滑移过程中试样轴和旋转轴的变化，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析双滑移过程中试样轴和旋转轴的变化，涉及多个方向的旋转和合成，需要综合运用晶体滑移理论、向量运算和空间几何知识，进行推理分析和机理解释。 | 难度: 在简答题题型中，该题目属于复杂分析层次，要求综合运用材料科学中的双滑移理论，进行详细的机理解释和推理分析。题目不仅要求理解双滑移过程中试样轴的旋转方向，还需要计算旋转轴的具体方向，并最终确定合成旋转轴的方向。这一过程涉及多个步骤的复杂计算和空间想象能力，对学生的综合分析和推理能力要求较高，因此在简答题题型中属于最高难度等级。" + }, + { + "idx": 2572, + "question": "What is a double slip system?", + "answer": "The double slip system is (0 1)[111]－(011)[1 1].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"double slip system\"进行解释，答案提供了具体的晶体学表示，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对双滑移系统这一基本概念的记忆和理解，属于材料科学中晶体塑性变形的基础知识，不需要复杂的应用或分析。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述双滑移系统的定义和具体滑移系组合，不涉及概念解释或复杂体系阐述。" + }, + { + "idx": 2573, + "question": "Change the tension in the previous question to compression, and determine the stable orientation", + "answer": "Let the stable orientation be $[\\\\boldsymbol{\\\\mathbf{u}}^{},~\\\\boldsymbol{\\\\mathbf{0}}\\\\boldsymbol{\\\\mathbf{w}}^{}~]$. To make $\\\\boldsymbol{\\\\mathsf{n}}=[000]$, it is required that $\\\\begin{array}{r l}{[\\\\mathbf{u}^{\\\\prime}}&{{}0\\\\mathbf{w}^{\\\\prime}]\\\\times([111]+[1\\\\bar{1}1])}\\\\end{array}$ $=[000]$, i.e., $\\\\begin{array}{r l}{\\\\upmu^{\\\\prime}}&{{}=\\\\upmu^{\\\\prime}}\\\\end{array}$. Therefore, the stable orientation is [101]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过分析和计算确定稳定的取向，答案给出了具体的取向结果并附有推导过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要将张力条件改为压缩条件，并确定稳定取向。这涉及多步计算和概念关联，包括取向的数学表达和条件推导，属于中等应用层次。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和应用能力。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求将之前的张力条件改为压缩条件，这需要对材料力学中的应力状态有深入理解。其次，确定稳定取向需要多步计算和概念关联，包括向量运算和应力分析。最后，题目要求综合分析不同应力状态下的取向变化，这需要较强的逻辑推理和数学推导能力。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 2574, + "question": "Using L=ds/+ds†(′⋅η)b, let L=[u 0 w], find the crystal orientation and shear strain.", + "answer": "L=[2 1 3]+4∨[111]/√6, from which it can be seen that u=3, v=4, γ=√6/4, so the crystal orientation is [304], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和条件进行数值计算，最终得出晶体取向和剪切应变的数值结果。答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解晶体取向和剪切应变的概念，并进行数值计算和综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于复杂多变量计算难度，需要理解并应用多个公式，进行多步骤的数值计算和综合分析，涉及晶体取向和剪切应变的复杂计算。" + }, + { + "idx": 2575, + "question": "Assuming the stable orientation is [u′, 0 w′], what should the stable orientation be to make n=[000]?", + "answer": "To make n=[000], it is required that [u′ 0 w′]×([111]+[1 1 1])=[000], i.e., u′=u′’, thus the stable orientation is [101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定稳定取向的条件，答案提供了详细的推导过程和结论，符合简答题的特征。 | 知识层次: 题目需要理解晶体取向的概念，并应用向量叉乘的数学知识进行多步计算和综合分析，以确定稳定取向的条件。这涉及概念关联和中等复杂度的计算过程。 | 难度: 在简答题题型内，该题目属于较高难度。首先需要理解晶体取向和向量运算的基本概念，其次需要进行多步计算和综合分析（如向量叉乘运算和方程求解）。题目要求将抽象概念与具体计算相结合，并推导出稳定取向的条件，这超出了基础概念应用的范畴，属于需要多角度分析论述的层次。但尚未达到需要深度关联性分析（如跨章节知识整合）的最高难度。" + }, + { + "idx": 2576, + "question": "During double slip, the specimen axis turns towards [111] and [1 1]. What is the resultant rotation axis? Along which direction does point F move after double slip?", + "answer": "During double slip, the specimen axis turns towards [111] with a rotation axis n1=[304]×[111]=[4 1 3], and simultaneously turns towards [1 1] with a rotation axis n2=[304]×[1 1 1]=[4 1 3]. The resultant rotation axis is [020], i.e., [010]. Therefore, after double slip, point F moves along the edge [001]－[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释双滑移过程中试样轴的旋转轴和点F的运动方向，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目需要理解双滑移过程中试样轴的旋转方向，并计算合成旋转轴，涉及多步计算和概念关联。虽然不涉及复杂的机理分析，但需要综合运用晶体学知识和向量运算，属于中等应用层次。 | 难度: 在简答题题型中，该题目需要多步计算（如旋转轴的计算）和概念关联（如双滑移的旋转轴合成），同时要求综合分析（如确定点F的运动方向）。这些要求超出了基础概念的直接应用，属于中等应用层次中的较高难度，符合等级4的多角度分析论述标准。" + }, + { + "idx": 2577, + "question": "Practice has shown that highly cold-rolled magnesium sheets tend to crack during deep drawing. Analyze the reasons for this.", + "answer": "After cold rolling, magnesium sheets develop a (0001)<11 0> texture. When stress is applied parallel or perpendicular to the sheet surface, the orientation factor is zero, resulting in almost no plasticity, making further processing prone to cracking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷轧镁板在深冲过程中容易开裂的原因，需要文字解释和论述，答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷轧镁板在深冲过程中易开裂的原因，涉及晶体学织构（(0001)<11 0>）与塑性变形机制的关联性解释，需要综合材料变形机理、晶体取向因子计算（零塑性条件）等专业知识进行机理层面的推理分析，属于对多学科知识的深度整合与应用。 | 难度: 在简答题-复杂分析题型中，该题目要求对冷轧镁板深冲开裂现象进行全面分析，涉及晶体学取向因子计算和塑性变形机理的深度解释。需要综合运用材料科学、晶体学和力学知识，解释特定织构(0001)<11 0>与加工性能的关系，并推导出取向因子为零导致塑性丧失的结论。这种需要多学科知识整合和机理深度解释的题目，在该题型内属于最高难度等级。" + }, + { + "idx": 2578, + "question": "It is known that the critical resolved shear stress required for twinning in magnesium single crystals is several times larger than that for slip. When a magnesium single crystal is stretched along the [0001] direction, what is the deformation mode of the crystal?", + "answer": "The slip systems of magnesium single crystals are (0001)<11-20> and {10-10}<11-20>, and the possible slip directions are all perpendicular to [0001], so slip does not occur in this case; c/a=1.62<√3, so [0001] is in the obtuse angle region of K1 and K2, and twinning will increase during deformation. Therefore, twinning occurs when stretched along the [0001] direction, and twinning changes the crystal orientation, which may further lead to slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁单晶在[0001]方向拉伸时的变形模式，答案提供了详细的文字解释和论述，包括滑移系统和孪生机制的分析，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析镁单晶在特定拉伸方向下的变形模式，需要综合理解滑移和孪生的临界分切应力、晶体取向变化以及可能的后续变形机制。这涉及多个概念的关联和推理分析，思维过程较为复杂。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用镁单晶的滑移和孪生机制知识，分析特定晶体方向拉伸时的变形模式。需要理解临界分切应力差异、滑移系统几何限制、c/a比值对孪生的影响等多重因素，并推导出孪生导致晶体取向变化的后续效应。解题过程涉及晶体学方向分析、变形机制比较和变形过程推演，属于该题型中最复杂的综合分析层次。" + }, + { + "idx": 2579, + "question": "Can inserting an additional columnar half-atom plane in a crystal form a dislocation loop? Why?", + "answer": "A dislocation loop cannot be formed. Assuming a dislocation loop could form, it would consist entirely of edge dislocations. According to l⊥b, the Burgers vector $\\pmb{b}$ at each point of the loop should be along the radial direction, meaning the $\\pmb{b}$ at different points on the loop would vary. This contradicts the fact that a single dislocation line has only one $\\pmb{b}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么插入额外的柱状半原子平面不能形成位错环，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要深入理解位错环的形成机制和伯格斯矢量的性质，涉及位错理论的综合分析，以及推理分析为什么插入额外的半原子面不能形成位错环。这需要将多个概念关联起来，并进行逻辑推理，属于复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体缺陷理论（位错环形成条件）、矢量分析（Burgers vector方向性）和逻辑推理（矛盾论证），涉及以下高难度特征：" + }, + { + "idx": 2580, + "question": "Highly cold-rolled aluminum sheets will form a well-developed {001}<100> texture (cube texture) after high-temperature annealing. If such an aluminum sheet is deep-drawn into a cup, how many ears will be produced?", + "answer": "Eight ears will be produced during deep drawing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在深冲过程中会产生特定数量的耳朵，需要基于材料科学知识进行文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解冷轧铝板在高温退火后形成的{001}<100>织构（立方织构）的特性，并分析这种织构在深冲过程中的影响，预测产生的耳数量。这涉及到材料织构与成形性能的关联，需要综合运用材料科学和塑性加工的知识进行推理分析，属于复杂分析的层次。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求考生不仅理解冷轧铝板在高温退火后形成的立方织构（cube texture），还需要综合运用材料科学和金属塑性加工的知识，推理分析这种织构在深冲过程中的表现，即产生多少个耳朵（ears）。这涉及到对织构、塑性变形机理和深冲工艺的综合理解，解题步骤复杂，需要深入的理论基础和实际应用能力。因此，在简答题题型中，该题目属于最高难度等级。" + }, + { + "idx": 2581, + "question": "What is the fundamental reason for the formation of deformation texture (or processing texture)?", + "answer": "The fundamental reason for the formation of deformation texture is that during processing, each grain slips along certain slip planes and rotates according to specific rules, causing the slip direction to align with the principal strain direction or the slip plane to align with the compression plane. Therefore, when the deformation is sufficiently large, the slip directions or slip planes of a large number of grains will become parallel to the tensile direction or compression plane, thus forming the texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释变形织构形成的基本原因，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求解释变形织构形成的根本原因，涉及晶粒滑移和旋转的机理分析，需要综合运用材料科学中的晶体学、塑性变形等知识进行推理和解释，思维过程较深。 | 难度: 在简答题中属于机理深度解释难度，需要详细阐述变形织构形成的根本原因，涉及晶粒滑移、旋转规则以及与主应变方向的对应关系等复杂机理。虽然不需要全面分析所有相关现象，但对知识点的掌握深度和解释能力要求较高。" + }, + { + "idx": 2582, + "question": "What is texture (or preferred orientation)?", + "answer": "After cold working, the orientations of metal grains exhibit a certain relationship, and such a distribution of orientations is called preferred orientation, i.e., texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"texture (or preferred orientation)\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即对\"texture (or preferred orientation)\"的定义进行解释，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆性知识。题目不需要解释或描述复杂概念，也不涉及多步骤的论述过程，完全符合等级1\"基本定义简答\"的标准。在同类型简答题中，这是最基础、最简单的难度级别。" + }, + { + "idx": 2584, + "question": "In a simple cubic crystal, pure bending of the (010) plane around the [001] axis will form what type of dislocation (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[010]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求详细解释和描述在简单立方晶体中纯弯曲(010)平面绕[001]轴会形成什么类型的位错，并具体说明位错线的方向和Burgers矢量。答案需要文字描述和具体说明，而不是简单的选择或判断。 | 知识层次: 题目要求理解晶体中的位错类型、位错线方向和伯格斯矢量的关系，需要将纯弯曲变形与位错形成机制联系起来，属于中等应用层次。需要多步分析和概念关联，但不需要复杂的推理或创新。 | 难度: 在简答题中属于中等难度，需要理解晶体结构、位错类型和伯格斯矢量的概念，并进行综合分析。题目要求明确位错线的方向和伯格斯矢量，涉及多步概念关联和具体说明，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2585, + "question": "For a simple cubic crystal, pure bending of the (110) plane around the [001] axis will form what type of dislocations (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[100] or a[010]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求详细解释和论述，答案需要文字描述和具体说明，而不是简单的选择或判断 | 知识层次: 题目要求分析简单立方晶体中特定平面弯曲形成的位错类型，需要理解位错的基本概念（如位错线方向和Burgers向量），并能将其应用到具体晶体结构中。这涉及多步推理和概念关联，但不需要复杂的综合分析或创新应用。 | 难度: 在简答题中属于中等难度，需要理解晶体结构、位错类型和伯格斯矢量的概念，并进行综合分析。题目要求明确位错线的方向和伯格斯矢量，涉及多步概念关联和具体计算，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2586, + "question": "FCC crystal, pure bending occurs on the (110) plane around the [001] axis, what kind of dislocations will form (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[110]/2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释和论述FCC晶体在特定条件下形成的位错类型、位错线方向和Burgers矢量，答案需要文字描述和具体参数，而非简单的选择、判断或计算。 | 知识层次: 题目需要理解FCC晶体结构、纯弯曲变形机制、位错类型及其Burgers矢量的确定，涉及多个概念的关联和综合分析。虽然不涉及复杂的计算，但需要对晶体学方向和位错性质有较深入的理解和应用能力。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识、位错理论和力学分析能力。具体表现为：1) 需要准确识别FCC晶体(110)面和[001]轴的几何关系；2) 要理解纯弯曲变形与位错形成机制的关联；3) 必须正确推导出刃型位错的线方向[001]和柏氏矢量a[110]/2；4) 要求将晶体滑移系与外加应力状态进行综合分析。这超越了简单记忆或单一步骤计算，需要多角度分析论述能力。" + }, + { + "idx": 2587, + "question": "When a simple cubic crystal is twisted by an angle θ around the [001] axis, what kind of dislocation will form (specify the direction of the dislocation line and the Burgers vector)?", + "answer": "Screw type, dislocation line direction=[001], Burgers vector=a[001]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求详细解释和描述在特定条件下形成的位错类型、位错线方向和Burgers矢量，需要文字论述而非简单选择或判断。 | 知识层次: 题目需要理解晶体扭曲后形成的位错类型，并具体指出位错线的方向和Burgers矢量。这涉及到对位错基本概念的掌握（如螺型位错的定义），以及将这些概念应用到具体晶体学方向的分析中。虽然不需要复杂的推理或创新，但需要将多个概念关联起来进行综合分析。 | 难度: 在简答题中属于中等难度，需要理解晶体扭曲和位错形成的基本概念，并能正确关联位错类型、位错线方向和伯格斯矢量的关系。虽然题目涉及多步分析和概念关联，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 2589, + "question": "When the crystal around an edge dislocation contains excess interstitial atoms, how will the dislocation climb?", + "answer": "Negative climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释边缘位错在含有过量间隙原子时的攀移行为，答案\"Negative climb\"是一个专业术语的解释，属于需要文字说明的简答题类型。 | 知识层次: 题目涉及位错攀移机制的理解和应用，需要将间隙原子的存在与位错运动方向关联起来进行分析。虽然不涉及复杂计算，但需要理解位错攀移的基本原理及其与点缺陷的相互作用，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解位错攀移的基本概念，并能将间隙原子的存在与位错攀移方向关联起来进行分析说明。虽然涉及概念关联，但不需要多角度或深度分析。" + }, + { + "idx": 2590, + "question": "When the crystal around an edge dislocation contains an excess of vacancies, how will the dislocation climb?", + "answer": "Positive climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错攀移的具体方向，需要文字说明和论述，而不是简单的选择或判断 | 知识层次: 题目涉及位错攀移机制与空位过剩的相互作用，需要综合运用位错理论和扩散知识进行机理分析，属于需要推理分析和综合解释的复杂问题。 | 难度: 在简答题（需要文字解释和论述）的题型框架下，该题目属于机理深度解释的难度等级。题目要求考生不仅要理解刃位错和空位的基本概念，还需要综合运用这些知识来分析空位过量对位错攀移方向的影响机制。这涉及到对晶体缺陷行为的深入理解以及微观机理的解释能力，属于该题型中较高难度的题目，但尚未达到需要全面分析复杂现象的最高难度等级。" + }, + { + "idx": 2591, + "question": "When the crystal around an edge dislocation contains vacancies below the equilibrium concentration, how will the dislocation climb?", + "answer": "Negative climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错在特定条件下的行为，需要文字解释和论述，答案形式为简短的专业术语而非选择或判断。 | 知识层次: 题目涉及位错攀移机制与空位浓度关系的深入理解，需要综合运用位错理论和热力学知识进行推理分析，属于对材料科学中位错行为的复杂机理解释。 | 难度: 在简答题（复杂分析类）中，该题目要求考生不仅理解刃位错和空位浓度的基本概念，还需要综合运用非平衡态空位浓度对位错攀移方向的影响机制。题目涉及晶体缺陷动力学和热力学平衡的综合分析，属于需要机理深度解释的难度等级。虽然不需要全面分析复杂现象（如多种缺陷交互作用），但已超出基础概念应用的范畴，属于该题型中较高难度的题目。" + }, + { + "idx": 2592, + "question": "A screw dislocation with $b=a/2$ [10] moves on the (111) plane. If it encounters an obstacle during motion and undergoes cross-slip, please identify the cross-slip system.", + "answer": "∵ All planes containing the direction of the screw dislocation are slip planes, ∴ For the FCC crystal slip plane (111), only (111) and (11 ) contain $I=b={\\\\sf a}/2$ [10]. ∴ If cross-slip occurs, it must be from the (111) plane to the (11 ) plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来识别交叉滑移系统，答案提供了详细的推导过程和逻辑解释，属于需要文字论述的简答题类型。 | 知识层次: 题目涉及位错运动、滑移面和交叉滑移系统的综合分析，需要理解FCC晶体结构、位错性质以及滑移面的几何关系，并进行推理分析以确定交叉滑移系统。这超出了简单记忆或直接应用的范围，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体学、位错理论和滑移系统知识，进行多步骤推理分析。需要理解螺位错特性、FCC晶体滑移面选择机制，并准确判断交叉滑移系统。解题过程涉及空间几何关系的推导和晶体学指数的精确计算，属于该题型下对知识深度和逻辑推理要求最高的复杂现象全面分析类题目。" + }, + { + "idx": 2593, + "question": "A closed dislocation loop lies on the slip plane of a prism with a square cross-section. The two sides of the square are along the x and y axes, and the Burgers vector is along the z-axis. If the dislocation loop can only glide, determine the equilibrium shape of the dislocation loop and the critical stress for initiation under the stress distribution condition τxz = τyz = τ = const. (Assume the line tension is approximately constant.)", + "answer": "f = (σ ⋅ b) × υ = (u - v)τbk; the initiation stress τp = 2G exp(-2πw/b)/(1-υ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定位错环的平衡形状和临界应力，需要通过公式计算和数值分析来解答。答案给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目涉及复杂的力学分析、应力分布条件下的平衡形状确定、临界应力计算，需要综合运用位错理论、应力分析、能量平衡等知识，并进行多步推理和计算。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于高难度综合计算。题目涉及复杂的位错环平衡形状分析、临界应力计算，需要综合运用位错理论、应力分析和材料力学知识。解题步骤包括理解位错环在滑移面上的行为、建立应力平衡方程、推导临界应力表达式等多个复杂环节，对知识掌握深度和综合应用能力要求极高。" + }, + { + "idx": 2594, + "question": "If the applied stress is uniformly distributed, find the net force acting on any dislocation loop.", + "answer": "In general, the formula for the force on a dislocation is ${\\mathsf{d}}F=({\\textsf{\\sigma}}\\cdot{\\textsf{\\em b}})\\times{\\mathsf{d}}/,$. Since the applied stress is uniformly distributed, $\\pmb{\\upsigma}$ and $\\pmb{b}$ are both constants. Therefore, the net force on any dislocation loop is $\\oint\\mathbf{d}F=\\oint{\\bigl(}\\upsigma\\bullet b{\\bigr)}\\times\\mathbf{d}/={\\bigl(}\\upsigma\\bullet b{\\bigr)}\\oint\\mathbf{d}/={\\bigl(}\\upsigma$ • $b)\\times0=0.$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式应用和积分计算来求解作用在任何位错环上的净力，答案展示了具体的数学推导过程，属于典型的计算题类型。 | 知识层次: 题目涉及多步计算和概念关联，需要理解应力分布均匀性对位错环净力的影响，并应用积分公式进行综合分析。虽然计算过程相对直接，但需要对位错力和应力分布有较深的理解。 | 难度: 在计算题中属于中等偏上难度，需要理解并应用多个概念（如应力分布、位错力公式、环路积分等），并进行多步骤的计算和综合分析。虽然题目给出了均匀应力分布的简化条件，但仍需正确应用积分运算和矢量运算，对学生的综合能力有一定要求。" + }, + { + "idx": 2595, + "question": "When the crystal around an edge dislocation contains interstitial atoms below the equilibrium concentration, how will the dislocation climb?", + "answer": "Positive climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和理解位错攀移的概念，答案是一个简短的文字解释而非选择或判断 | 知识层次: 题目涉及位错攀移机制的分析，需要理解间隙原子浓度与位错运动的关系，并进行推理分析。这超出了简单记忆或应用层面，属于需要综合运用知识进行机理解释的复杂分析层次。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于\"机理深度解释\"难度等级。题目要求考生不仅要理解刃位错和间隙原子的基本概念，还需要分析非平衡浓度条件下位错攀移的微观机制，并推导出正向攀移的结论。这需要综合运用晶体缺陷理论和热力学知识，属于对机理的深入解释层面，但尚未达到需要多因素交互分析的\"复杂现象全面分析\"等级。" + }, + { + "idx": 2596, + "question": "Derive the elastic energy formula for a mixed dislocation.", + "answer": "$\\\\begin{array}{r l}&{\\\\mathsf{E}=\\\\mathsf{E}_{\\\\mathsf{o}1}\\\\left(\\\\mathcal{V}\\\\right)+\\\\mathsf{E}_{\\\\mathsf{e}1}\\\\left(\\\\frac{\\\\mathsf{i}\\\\mathcal{R}}{\\\\mathsf{s}\\\\mathsf{t}_{\\\\mathrm{A}}}\\\\right)=\\\\mathsf{G b}^{2}|\\\\mathsf{s}\\\\mathsf{i n}^{2}\\\\mathsf{a}\\\\star|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)/\\\\left[4\\\\pi\\\\left(1-\\\\upsilon\\\\right)\\\\right]+\\\\mathsf{G b}^{2}|\\\\mathsf{c o s}^{2}\\\\mathsf{a}\\\\star|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)}\\\\ &{\\\\mathrm{~\\\\ensuremath~{\\\\left/~\\\\left(4\\\\pi\\\\right)~\\\\tau~=~\\\\mathsf{Gb}^2|\\\\tau~\\\\left(1-\\\\upsilon\\\\cos^2\\\\theta\\\\right)~\\\\cdot~|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)~\\\\middle/~\\\\left[4\\\\pi\\\\left(1-\\\\upsilon\\\\right)\\\\right]~\\\\right.~}}\\\\end{array}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导混合位错的弹性能量公式，涉及公式应用和推导过程，答案呈现为数学表达式和推导步骤，属于计算题的范畴。 | 知识层次: 题目要求推导混合位错的弹性能量公式，涉及多步计算、概念关联和综合分析。需要理解位错的基本性质、弹性理论的应用以及数学推导能力，属于较高层次的认知要求。 | 难度: 在计算题中，该题目属于机理相关复杂计算。题目要求推导混合位错的弹性能量公式，涉及多个物理概念的综合运用（如弹性模量、位错性质、角度关系等），需要深入理解位错机理并进行多步骤的数学推导。虽然不涉及最高难度的综合计算（如多物理场耦合），但已超出基础分析性计算范畴，属于需要机理理解和复杂公式应用的等级。" + }, + { + "idx": 2598, + "question": "What kind of a pair of dislocations is equivalent to a row of vacancies (or a row of interstitial atoms)?", + "answer": "When the half-atomic planes of a positive edge dislocation and a negative edge dislocation lie on the same plane, leaving out one atomic site in between will form a row of vacancies, while overlapping one atomic site will form a row of interstitial atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪种位错对等价于空位行或间隙原子行，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释位错对与空位或间隙原子行的等效性，涉及位错理论中的正负刃位错相互作用及其对晶体缺陷形成的影响。这需要深入理解位错的性质、相互作用机制以及它们与点缺陷的关系，属于对多个概念的关联分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用位错理论、点缺陷形成机理等知识，进行深度推理和全面分析。需要解释正负刃位错半原子面相互作用如何导致空位或间隙原子列的等效性，涉及多个知识点的交叉运用和复杂现象的机理阐述，属于该题型内最高难度的综合分析和机理解释类题目。" + }, + { + "idx": 2599, + "question": "On the (111) plane of a copper single crystal, there is a right-handed screw dislocation with $b=a/2$ [10 ], where $a=0.36\\\\mathsf{n m}$. Now, a tensile stress of $10^{6}\\\\mathsf{P a}$ is applied along the [001] direction. Find the force acting on the screw dislocation.", + "answer": "Using the Peach-Koehler formula, we obtain \\n\\n$$\\n{f}=(\\\\sigma\\\\cdot b)\\\\times\\\\upsilon\\n$$\\n\\n$$\\n\\\\begin{array}{r l}&{\\\\langle\\\\left[\\\\begin{array}{l}{\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}}\\\\ {\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}}\\\\end{array}\\\\right]\\\\bullet\\\\frac{\\\\bar{\\\\mathbb{a}}}{2}\\\\left[\\\\begin{array}{l}{1}\\\\ {\\\\bar{\\\\mathbb{O}}}\\\\ {-1}\\\\end{array}\\\\right]\\\\rangle\\\\times\\\\frac{\\\\sqrt{2}}{2}\\\\left[\\\\begin{array}{l}{1}\\\\ {\\\\bar{\\\\mathbb{O}}}\\\\ {-1}\\\\end{array}\\\\right]=\\\\frac{\\\\rho}{(-\\\\sqrt{2/4})\\\\mathsf{a}\\\\upsigma_{z}j},}\\\\end{array}\\n$$\\n\\nThus, $\\\\pounds=1.27\\\\times10^{-4}$ N/m, and the direction is along the negative $\\\\pmb{\\\\ y}$-axis.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Peach-Koehler公式）来求解作用在螺位错上的力，答案给出了具体的计算过程和最终数值结果。 | 知识层次: 题目需要应用Peach-Koehler公式进行多步计算，涉及应力张量、伯格斯矢量以及位错线方向的向量运算，需要综合分析力和方向的计算过程。虽然不涉及复杂的机理解释或创新设计，但计算步骤和概念关联较为复杂，超出了简单应用的范围。 | 难度: 在计算题中属于综合性计算问题难度。题目需要应用Peach-Koehler公式进行多步计算，涉及应力张量、伯格斯矢量、位错线方向等多个变量的运算，并要求理解晶体学方向指数的转换关系。虽然计算过程较为系统，但不需要处理复杂多变量情况，因此属于等级3的综合性计算问题。" + }, + { + "idx": 2600, + "question": "Estimate the equilibrium width of an extended dislocation in Al. Given the lattice constant of Al a = 0.404 nm, shear modulus G = 3×10^6 N/cm^2, and stacking fault energy γ_I = 166×10^-6 J/m^2.", + "answer": "Al has a face-centered cubic structure, and the equilibrium width of an extended dislocation d_0 = G a^2 / (24πγ_I). Substituting the data: d_0 = (3×10^6 N/cm^2) × (0.404×10^-9 m)^2 / (24π × 166×10^-6 J/m^2) = 3.91×10^-7 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目需要应用材料科学中的基本公式（扩展位错平衡宽度公式），并进行多步单位换算和数值计算。虽然公式直接给出，但涉及单位转换和具体数值代入，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用特定公式并进行多步计算。题目涉及材料科学中的位错理论，要求掌握剪切模量、晶格常数和堆垛层错能之间的关系。虽然计算步骤明确，但需要对物理概念有较深理解才能正确应用公式。相比简单代入计算（等级2），本题需要更全面的概念关联和单位转换能力，但尚未达到复杂多变量计算（等级4）的程度。" + }, + { + "idx": 2601, + "question": "Which four quantum numbers can determine the spatial position and energy of an electron in an atom?", + "answer": "Principal quantum number n, orbital angular momentum quantum number li, magnetic quantum number mi, and spin angular momentum quantum number si", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答四个量子数的名称，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对四个量子数及其作用的基本概念的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在简答题中属于基本定义简答难度，仅需回忆并列举四个量子数的名称，无需深入解释或阐述复杂概念体系。题目要求的知识点非常基础，属于量子力学中最基本的记忆性内容。" + }, + { + "idx": 2602, + "question": "Estimate the equilibrium width of an extended dislocation in Cu. Given: lattice constant of Cu a = 0.361 nm, shear modulus G = 5×10^6 N/cm^2, stacking fault energy γ_I = 45×10^-6 J/m^2.", + "answer": "Cu has a face-centered cubic structure, and the equilibrium width of an extended dislocation d_0 = G a^2 / (24πγ_I). Substituting the data: d_0 = (5×10^6 N/cm^2) × (0.361×10^-9 m)^2 / (24π × 45×10^-6 J/m^2) = 1.92×10^-6 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及到的知识点较为基础，思维过程较为直接，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用一个明确的公式（d_0 = G a^2 / (24πγ_I)），并直接代入给定的数值进行计算。无需多个公式组合或复杂的推导步骤，属于最基础的计算题类型。" + }, + { + "idx": 2603, + "question": "In multi-electron atoms, what principles should the arrangement of extranuclear electrons follow?", + "answer": "The principle of lowest energy, Pauli exclusion principle, Hund's rule.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释多电子原子中核外电子排布遵循的原则，答案以文字形式给出，需要论述和解释相关原理，而非选择、判断或计算。 | 知识层次: 题目考查对多电子原子核外电子排布遵循的基本原则的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答多电子原子中核外电子排布遵循的原则，涉及三个基本原理（能量最低原理、泡利不相容原理、洪德规则）的列举和简要说明。虽然需要记忆多个概念，但不需要深入阐述概念间的复杂关系或进行推导论证，属于基础概念记忆性知识的应用范畴。" + }, + { + "idx": 2604, + "question": "In the periodic table, what are the differences in atomic structure of elements in the same period from left to right?", + "answer": "From left to right, the nuclear charge increases sequentially, and the atomic radius gradually decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素在同一周期中从左到右的原子结构差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查元素周期表中同一周期元素原子结构变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释同一周期内元素原子结构的变化规律，涉及核电荷和原子半径两个关键概念的变化趋势。虽然需要理解并描述两个相关概念的变化关系，但不需要进行复杂的体系阐述或跨概念比较，属于中等偏基础的简答题难度。" + }, + { + "idx": 2605, + "question": "In the periodic table, how do the properties of elements in the same main group change from top to bottom?", + "answer": "From top to bottom, the ionization energy decreases, the ability to lose electrons increases, the ability to gain electrons decreases, the metallic character increases, and the non-metallic character decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素在同一主族中从上到下性质的变化趋势，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对元素周期表中主族元素性质变化规律的基础概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释元素在同一主族中从上到下性质的变化趋势，涉及多个相关概念（如电离能、金属性、非金属性等）的联动变化，但不需要构建复杂的理论体系或进行深入分析。这符合等级2对概念间关联性描述的要求，但未达到等级3的复杂体系阐述标准。" + }, + { + "idx": 2606, + "question": "In the periodic table, what are the common characteristics of atomic structures for elements in the same main group?", + "answer": "Elements in the same main group have the same number of outer electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释元素在同一主族中的共同特征，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对元素周期表中主族元素原子结构共同特征的基本概念记忆和理解，仅需要回答外层电子数相同这一基本原理，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答同一主族元素的原子结构共同特征，即外层电子数相同。这属于最基础的概念记忆，不需要解释或论述复杂概念体系，解题步骤也非常简单直接。在同题型内属于最低难度等级。" + }, + { + "idx": 2607, + "question": "Why is the relative atomic mass of an element not always a whole number?", + "answer": "Because different isotopes contain varying numbers of neutrons (while having the same number of protons), elements with multiple isotopes in different abundances have a relative atomic mass that is not a whole number.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么元素的相对原子质量不总是整数，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对同位素和相对原子质量这一基础概念的理解，主要涉及记忆和简单解释，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释相对原子质量不为整数的原因，涉及同位素和丰度的基本概念，但不需要复杂的推导或体系阐述。解题步骤相对直接，只需说明同位素的存在及其对平均原子质量的影响即可，属于中等难度的概念解释类简答题。" + }, + { + "idx": 2608, + "question": "Estimate the equilibrium width of extended dislocations in stainless steel. Given the lattice constant of stainless steel a = 0.356 nm, shear modulus G = 10×10^6 N/cm^2, and stacking fault energy γ_I = 15×10^-6 J/m^2.", + "answer": "Stainless steel has a face-centered cubic structure, and the equilibrium width of extended dislocations d_0 = G a^2 / (24πγ_I). Substituting the data: d_0 = (10×10^6 N/cm^2) × (0.356×10^-9 m)^2 / (24π × 15×10^-6 J/m^2) = 1.12×10^-5 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的物理参数和公式进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。虽然需要理解扩展位错的概念，但解题过程主要是将给定数值代入公式进行计算，属于简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用一个明确的公式（d_0 = G a^2 / (24πγ_I)），并进行简单的数值代入和计算。不需要多个公式组合或复杂的推导步骤，属于该题型内最基础的难度级别。" + }, + { + "idx": 2609, + "question": "In the periodic table, what are the differences in atomic structure from top to bottom for elements in the same main group?", + "answer": "From top to bottom, the number of electron shells increases, and the atomic radius becomes larger.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释同一主族元素从上到下原子结构的变化，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对元素周期表中同一主族元素原子结构变化的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释同一主族元素从上到下原子结构的变化，涉及电子层数和原子半径两个基本概念的变化描述。虽然需要理解并表述两个相关概念的变化规律，但不需要进行复杂的体系阐述或深入分析，属于中等难度的概念解释类简答题。" + }, + { + "idx": 2610, + "question": "In the periodic table, what common characteristics do the atomic structures of elements in the same period have?", + "answer": "Elements in the same period have the same number of electron shells outside the atomic nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释元素在同一周期中的共同特征，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对元素周期表中同一周期元素原子结构共同特征的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答元素周期表中同一周期元素的原子结构共同特征，即电子层数相同。这属于最基础的概念记忆，不需要解释或描述复杂概念体系，解题步骤也非常简单直接。" + }, + { + "idx": 2611, + "question": "What are isotopes?", + "answer": "Substances that occupy the same position in the periodic table, although their masses are different, yet their chemical properties are the same, are called isotopes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对isotopes进行文字解释和论述，答案提供了详细的定义和特性描述，符合简答题的特征。 | 知识层次: 题目考查同位素的基本定义和特性，属于基础概念的记忆和理解 | 难度: 在简答题题型中，该题目仅要求回答同位素的基本定义，属于最基础的概念记忆层次。不需要解释或描述复杂的概念关系，也不涉及多步骤的推理过程。在同题型框架内，这是最简单的难度等级。" + }, + { + "idx": 2612, + "question": "In the periodic table, how do the properties of elements change from left to right within the same period?", + "answer": "From left to right, ionization energy increases, the ability to lose electrons decreases, the ability to gain electrons increases, metallic character weakens, and non-metallic character strengthens.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素周期表中同一周期内元素性质的变化趋势，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对元素周期表中同一周期内元素性质变化规律的基础概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释元素周期表中同一周期内元素性质的变化趋势，涉及多个相关概念（如电离能、得失电子能力、金属性/非金属性）的联动描述，但不需要深入分析机制或构建复杂概念体系。属于对基础规律的系统性表述，符合等级2对\"概念解释和描述\"的要求。" + }, + { + "idx": 2613, + "question": "The atomic number of chromium is 24, and it has a total of 4 isotopes: 4.31% of Cr atoms contain 26 neutrons, 83.76% contain 28 neutrons, 9.55% contain 29 neutrons, and 2.38% contain 30 neutrons. Calculate the relative atomic mass of chromium.", + "answer": "$A{\\tau}=0.0431\\times(24+26)+0.8376\\times(24+28)+0.0955\\times(24+29)$ $+0.0238\\times(24+30)=52.057$ 1-6 $A", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铬的相对原子质量，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式应用和简单计算，涉及同位素丰度和相对原子质量的计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求根据给定的同位素丰度和中子数计算相对原子质量，涉及基本的加权平均计算和简单的加法运算。虽然需要处理多个同位素的数据，但每个步骤都是直接套用公式，没有复杂的推导或组合计算。因此在该题型内属于等级2难度。" + }, + { + "idx": 2614, + "question": "The atomic number of tin is 50, and except for the 4f subshell, all other inner electron subshells are filled. Determine the number of valence electrons in tin from the perspective of atomic structure.", + "answer": "1s²2s²2p63s²3p63d104s²4p64d105s²5p²; the number of valence electrons in tin is 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从原子结构的角度确定锡的价电子数，并给出了详细的电子排布作为答案。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对原子结构和电子排布的基本概念的记忆和理解，需要根据原子序数写出电子排布式并确定价电子数，属于基础概念记忆性知识。 | 难度: 在简答题中属于中等难度，需要根据给定的原子序数和电子排布规则写出完整的电子排布式，并从中识别出价电子数。虽然涉及基本的电子排布知识，但需要一定的理解和应用能力，而不仅仅是简单的定义记忆。" + }, + { + "idx": 2615, + "question": "Given that the atomic number of an element is 32, based on the knowledge of atomic electronic structure, write its electron configuration.", + "answer": "1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据原子电子结构知识写出电子排布式，需要文字解释和论述，答案形式为电子排布式而非数值计算或选择判断 | 知识层次: 题目考查对原子电子结构基础知识的记忆，仅需根据原子序数32直接写出电子排布式，不涉及复杂计算或综合分析。 | 难度: 在简答题中，该题目要求根据原子序数写出电子排布式，属于概念解释和描述的难度等级。虽然需要掌握电子排布的基本规则和能级顺序，但不需要复杂的推导或解释，属于中等难度的简答题。" + }, + { + "idx": 2616, + "question": "The atomic number of copper is 29, its relative atomic mass is 63.54, and it has two isotopes, Cu63 and Cu65. Calculate the percentage content of the two copper isotopes.", + "answer": "$A{\\\\mathrm{r}}=63.54=63x+65\\\\times(1-x);\\\\quad x={\\\\frac{65-63.54}{2}}=0.73\\\\rightarrow73\\\\mathcal{V}_{0}\\\\left(\\\\mathrm{Cu}^{\\\\mathrm{63}}\\\\right);$ $1-x=0.27\\\\substack{\\\\rightarrow27\\\\%(\\\\mathrm{Cu}^{65})}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种铜同位素的百分比含量，答案展示了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，通过设定变量并解方程来求解同位素的百分比含量，属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算，只需要使用一个简单的代数方程来求解同位素的百分比含量。虽然涉及基本的代数运算，但步骤直接且无需多个公式组合。" + }, + { + "idx": 2618, + "question": "What are the characteristics of physical bonds (van der Waals forces)?", + "answer": "Physical bonds: secondary bonds, also known as van der Waals forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释物理键（范德华力）的特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对物理键（范德华力）基本特征的定义和分类的记忆性知识，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答物理键（范德华力）的基本定义和别名，属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这是最基础的知识点考察形式。" + }, + { + "idx": 2619, + "question": "Given that the atomic number of an element is 32, based on its electron configuration, indicate which period it belongs to.", + "answer": "The fourth period", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于电子构型判断元素所属周期，需要文字解释和论述，答案形式为简短文字回答而非选择或计算 | 知识层次: 题目考查对元素周期表周期划分的基本概念记忆和理解，仅需根据原子序数32确定电子排布并对应到周期表的位置，属于基础概念记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需根据原子序数32直接对应到第四周期，无需复杂解释或概念体系阐述。题目仅考查基础周期表排列的记忆性知识，解题步骤简单直接。" + }, + { + "idx": 2620, + "question": "The atomic number of platinum is 78, it has only 9 electrons in the 5d subshell and no electrons in the 5f subshell. How many electrons are there in the 6s subshell of Pt?", + "answer": "$\\\\mathrm{ls^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{10}4s^{2}4p^{6}4d^{10}4f^{14}5s^{2}5p^{6}5d^{9}6s^{1}};$ $2+8+18+32+17=77;\\\\quad78-77=1$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定铂原子6s子壳层中的电子数，答案涉及电子排布和简单的减法运算，属于需要数值计算和公式应用的题目类型。 | 知识层次: 题目需要进行简单的电子排布计算，涉及基本的电子排布规则和简单的减法运算，属于基本公式应用和直接套用的范畴。虽然需要理解电子排布的基本原理，但整体思维过程较为直接，不涉及多步计算或复杂的概念关联。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用电子排布的基本规则和原子序数的概念，但解题步骤较为直接，只需按照电子填充顺序进行计算并验证总数。虽然涉及多个电子层的排布，但核心计算步骤单一，属于该题型框架内的中等偏低难度。" + }, + { + "idx": 2621, + "question": "How many types of bonds exist between atoms?", + "answer": "There are 5 types of bonds between atoms: metallic bond, ionic bond, covalent bond, physical bond (van der Waals force), hydrogen bond.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释原子间存在的键类型，答案以文字形式详细说明了五种键的类型，属于需要文字解释和论述的简答题。 | 知识层次: 题目考查原子间键合类型的基本分类和记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求列举并简要说明五种原子间键的类型，属于概念解释和描述的难度等级。虽然需要记忆多种键的类型，但不需要深入分析或比较这些键的特性，也不涉及复杂的概念体系阐述。因此，在简答题的基础概念记忆层次中，属于中等难度。" + }, + { + "idx": 2622, + "question": "Given that the atomic number of an element is 32, based on its electron configuration, identify which group it belongs to.", + "answer": "Group IVA", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的原子序数和电子构型识别元素所属的族，需要文字解释和论述，而不是从选项中选择或简单的判断对错。 | 知识层次: 题目要求根据原子序数32推导元素的电子排布并确定其所属族，这需要应用基本的电子排布规则和周期表分组知识。虽然涉及一定的推理步骤，但属于直接应用基础概念进行简单推导的范畴，不需要复杂的综合分析或深度理解。 | 难度: 在简答题中属于简单应用过程描述难度。题目要求根据原子序数32写出电子排布并判断所属族，属于直接套用电子排布规则的基础操作。解题步骤明确且单一（写出电子排布→判断外层电子数→对应周期表族），不需要额外解释或复杂推理。在同类简单应用型简答题中，这属于最基础的难度层级。" + }, + { + "idx": 2624, + "question": "Given that the atomic number of an element is 32, determine the strength of its metallic character based on its electron configuration.", + "answer": "Metalloid Ge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据元素的原子序数和电子构型判断其金属性强度，需要文字解释和论述，答案形式为简短的文字描述（Metalloid Ge），而非选择、判断或计算。 | 知识层次: 题目要求根据元素的原子序数确定其金属性强度，涉及电子排布的理解和应用。需要学生掌握元素周期表的基本规律，并能将电子排布与金属性关联起来进行综合分析。虽然不涉及复杂的计算或推理，但需要多步思维过程，包括识别元素、分析电子排布、判断金属性等，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用原子序数、电子排布、元素周期表规律等多方面知识，并准确判断元素的金属性强度。解题步骤涉及电子排布推导、周期表位置分析、金属性判断标准应用等复杂环节，且需对过渡区元素（类金属）的特殊性质有深入理解。" + }, + { + "idx": 2626, + "question": "Given that the relative atomic mass of Si is 28.09, if there are 5×10^10 electrons capable of free movement in 100g of Si, calculate the proportion of freely moving electrons to the total number of valence electrons.", + "answer": "Number of atoms = (100 / 28.09) × 6.023 × 10^23 = 2.144 × 10^24; Number of valence electrons = 4 × number of atoms = 4 × 2.144 × 10^24 = 8.576 × 10^24; Proportion = (5 × 10^10) / (8.576 × 10^24) = 5.830 × 10^-15", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算原子数量、价电子数量以及自由电子与总价电子的比例。答案也是通过具体计算得出的数值结果。 | 知识层次: 题目需要进行多步计算，包括摩尔质量转换、原子数量计算、价电子总数计算以及比例计算。虽然不涉及复杂的综合分析或推理，但需要将多个概念（摩尔质量、阿伏伽德罗常数、价电子数）关联起来进行计算，思维过程有一定的深度要求。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算自由电子与总价电子的比例，涉及相对原子质量、阿伏伽德罗常数、价电子数等多个概念的综合应用，计算步骤包括原子数计算、价电子总数计算和比例计算，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2627, + "question": "What does the short-range structure (primary structure) of polymer chain include?", + "answer": "Chemical structure, atomic arrangement in the molecular chain, bonding sequence of structural units, branching, cross-linking, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物链的短程结构（一级结构）包括哪些内容，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对聚合物短程结构（一级结构）的基本概念的记忆和理解，包括化学结构、分子链中的原子排列、结构单元的键合顺序、支化和交联等基础内容，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释聚合物链的短程结构（一级结构）所包含的内容，涉及多个具体要素（化学结构、分子链中的原子排列、结构单元的键合顺序、支化、交联等）。虽然需要列举多个要点，但都属于基础概念的记忆性知识，不需要深入分析或复杂推理，因此属于等级2（概念解释和描述）。" + }, + { + "idx": 2628, + "question": "The density of Al2O3 is 3.8g/cm3, calculate how many atoms are present in 1 mm3?", + "answer": "The relative molecular mass of Al2O3 M=26.98×2+16×3=101.96, the number of atoms in 1mm3 is 1×3.8×10-3/101.96×6.023×1023×5=1.12×1020", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及密度的计算、相对分子质量的计算以及阿伏伽德罗常数的应用，最终得出一个具体的数值结果。答案也展示了详细的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括相对分子质量的计算、单位转换、摩尔质量与阿伏伽德罗常数的应用，以及最终原子数的计算。虽然每个步骤都是基础概念的应用，但整体过程需要概念关联和综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握密度、摩尔质量、阿伏伽德罗常数等多个概念，并进行多步计算和单位转换，但不需要处理复杂多变量。" + }, + { + "idx": 2629, + "question": "Although the relative molecular mass of HF is relatively low, please explain why the boiling temperature of HF (19.4 ℃) is higher than that of HCl (-85 ℃)?", + "answer": "This is because the intermolecular force in HF is hydrogen bonding, while that in HCl is van der Waals force. The bond energy of hydrogen bonding is higher than that of van der Waals force, so the boiling point of HF is higher than that of HCl.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释HF沸点高于HCl的原因，答案需要文字解释和论述，涉及分子间作用力的类型和能量比较，属于简答题类型。 | 知识层次: 题目考查对氢键和范德华力这两种分子间作用力的基本概念的理解，以及它们对物质沸点影响的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释氢键和范德华力的概念，并比较它们的键能差异对沸点的影响。虽然涉及基础概念记忆，但需要一定的概念解释和描述能力，而不仅仅是简单的定义复述。" + }, + { + "idx": 2631, + "question": "Given that the relative atomic mass of Si is 28.09, if there are 5×10^10 electrons capable of free movement in 100g of Si, calculate the proportion of covalent bonds that must be broken.", + "answer": "Number of covalent bonds = number of atoms = 2.144 × 10^24; Number of covalent bonds to be broken = (5 × 10^10) / 2 = 2.5 × 10^10; Proportion = (2.5 × 10^10) / (2.144 × 10^24) = 1.166 × 10^-14", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算共价键的数量、需要断裂的共价键数量以及比例。答案也是以数值形式呈现的。 | 知识层次: 题目需要进行多步计算，包括原子数量计算、共价键数量计算以及比例计算，涉及基本公式应用和概念关联，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算共价键断裂的比例，涉及相对原子质量、电子数量、共价键数量等多个概念的综合运用，解题步骤包括计算原子数量、共价键数量以及最终的比例计算。虽然计算过程较为直接，但需要理解和关联多个概念，因此在计算题中属于中等偏上的难度。" + }, + { + "idx": 2632, + "question": "What does the long-range structure (secondary structure) of polymer chain structures include?", + "answer": "Relative molecular mass and its distribution, chain flexibility and conformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物链结构的远程结构（二级结构）包括哪些内容，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查聚合物链长程结构（二级结构）的基本组成要素，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释聚合物长程结构（二级结构）所包含的内容，涉及相对分子质量及其分布、链柔性和构象等概念。虽然需要记忆多个知识点，但都属于基础概念的解释和描述，不需要复杂的体系阐述或深入分析。因此，在简答题题型中属于中等难度（等级2）。" + }, + { + "idx": 2633, + "question": "The density of Al2O3 is 3.8g/cm3, calculate how many atoms are contained in 1g?", + "answer": "The relative molecular mass of Al2O3 M=26.98×2+16×3=101.96, the number of atoms contained in 1g is 1/101.96×6.023×1023×5=2.95×1022", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算1g Al2O3中的原子数量），需要应用公式（相对分子质量计算、阿伏伽德罗常数应用等），且答案以具体数值形式呈现。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，包括相对分子质量的计算和阿伏伽德罗常数的应用，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用相对分子质量的计算公式和阿伏伽德罗常数的概念，但解题步骤较为直接，仅需套用公式并进行简单乘法运算即可得出结果。不需要多个公式的组合或复杂的推导过程。" + }, + { + "idx": 2634, + "question": "The percentage of ionic character in the bonding between elements A and B can be approximately expressed by the following formula: IC(%)=[1-e^(-0.25(x_A-x_B)^2)]×100, where x_A and x_B are the electronegativity values of elements A and B, respectively. Given that the electronegativities of In and Sb are 1.7 and 1.9, respectively, calculate the IC(%) for InSb.", + "answer": "For InSb: IC(%)=[1-e^(-0.25)(1.9-1.7)^2]×100=1.0%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和电负性值进行数值计算，最终得出一个具体的百分比数值，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析，仅需理解并应用给定的公式即可得出结果。 | 难度: 在计算题中属于最低难度等级，仅需直接套用给定的单一公式进行简单数值计算，无需任何公式组合或复杂步骤。题目明确提供了所有必要参数和公式，计算过程仅涉及基本代数运算和指数函数应用。" + }, + { + "idx": 2635, + "question": "Explain the characteristics of thermoplastic polymer materials from the perspective of polymer chain structure", + "answer": "Thermoplastic polymers have linear and branched polymer chain structures, which soften upon heating and can be repeatedly processed and reshaped", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释热塑性聚合物材料的特性，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对热塑性聚合物链结构特征的基本概念记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目要求解释热塑性聚合物材料的特点，并从聚合物链结构的角度进行描述。这属于概念解释和描述的难度等级，需要学生对热塑性聚合物的链结构有基本的理解，并能用文字进行简要说明。题目不涉及复杂的概念体系或深入的机理分析，因此属于等级2。" + }, + { + "idx": 2636, + "question": "The percentage of ionic character in the bonding between elements A and B can be approximately calculated using the following formula: IC(%)=[1-e^(-0.25(x_A-x_B)^2)]×100, where x_A and x_B are the electronegativity values of elements A and B, respectively. Given that the electronegativities of Ti and O are 1.5 and 3.5, respectively, calculate the IC(%) for TiO2.", + "answer": "For TiO2: IC(%)=[1-e^(-0.25)(3.5-1.5)^2]×100=63.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，最终得出一个具体的百分比数值（63.2%），符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，仅需将给定的电负性值代入公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需套用给定的公式并代入已知数值进行计算，无需额外的步骤或复杂的推理过程。" + }, + { + "idx": 2637, + "question": "The chemical behavior of S sometimes resembles that of a hexavalent element, while other times it resembles a tetravalent element. Please explain the reason for this behavior of S.", + "answer": "The outermost electrons of S are 3s²3p⁴. When S combines with H to form H₂S, it accepts 2 electrons, and since S has 6 valence electrons in its outer shell, it behaves as a hexavalent element. When S combines with O to form SO₂, it provides 4 electrons, thus behaving as a tetravalent element.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释硫元素化学行为的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释硫元素在不同化合物中表现出不同化合价的原因，涉及对硫原子电子排布的理解以及在不同化学反应中电子行为的分析。这需要将基础概念（如电子排布）与实际化学反应中的行为联系起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对硫元素在不同化合物中的化学行为进行多角度分析论述。需要理解硫的电子构型（3s²3p⁴）及其在不同反应中的电子行为（接受或提供电子），并关联到其表现出的不同化合价（六价和四价）。这种综合分析和对概念的多角度论述使得该题目在简答题中属于较高难度等级。" + }, + { + "idx": 2638, + "question": "Explain the characteristics of thermosetting polymer materials from the perspective of polymer chain structure", + "answer": "Thermosetting polymers have a three-dimensional (cross-linked network) polymer chain structure, are insoluble in any solvent, and cannot be melted. Once set, their shape cannot be altered and they cannot be recycled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从聚合物链结构的角度解释热固性聚合物材料的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对热固性聚合物材料特性的基本概念记忆和理解，主要涉及聚合物链结构的定义和基本特性描述，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释热固性聚合物材料的特性，并从聚合物链结构的角度进行描述。这属于概念解释和描述的难度等级，需要学生对热固性聚合物的基本特性有一定的理解和记忆，但不需要进行复杂的体系阐述或多概念比较分析。题目要求的知识点掌握深度适中，解题步骤相对直接，属于该题型内的中等难度。" + }, + { + "idx": 2639, + "question": "Determine whether [-110] lies on the (111) plane", + "answer": "Using the zone law: h u + k v + l w = 0, here 1×(-1) + 1×1 + 1×0 = 0, thus [-110] lies on the (111) plane.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求判断一个陈述的对错（即[-110]是否在(111)平面上），答案通过应用晶体学中的区域定律（zone law）进行验证，最终给出明确的判断结果。 | 知识层次: 题目考查了晶向和晶面关系的简单应用，通过直接套用区带定律（zone law）公式进行一步计算即可得出结论，不需要多步推理或综合分析。 | 难度: 在判断题中属于中等难度，需要应用晶体学中的区带定律（zone law）进行公式计算和结果判断。虽然计算过程简单（仅需三个乘法运算和一个加法运算），但需要正确理解并应用公式，属于公式应用过程判断的难度等级。" + }, + { + "idx": 2640, + "question": "Calculate the number-average relative molecular mass $\\overline{M}_{n}$ of this polymer material, given the molecular weight range, average molecular weight M, and molecular number fraction.", + "answer": "The number-average relative molecular mass $\\overline{M}_{n} = \\sum x_{i}M_{i} = 375 + 2000 + 3850 + 6075 + 5500 + 2600 + 750 = 21150$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的分子量范围、平均分子量和分子数分数来计算聚合物的数均相对分子质量，答案是通过数值计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目主要考查基本公式（数均分子量公式）的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算，只需要套用单一公式（数均分子量公式）并进行简单的数值累加，无需多个公式组合或复杂推导步骤。虽然涉及多个数据点的计算，但每个步骤都是直接应用基础公式，属于该题型内的基础难度水平。" + }, + { + "idx": 2641, + "question": "Calculate the linear density in the [-110] direction", + "answer": "The formula for linear density is K = (4 × r) / l, where r = (√2 × a) / 4, l = √2 × a. Substituting gives K = (4 × (√2 × a / 4)) / (√2 × a) = 1. Therefore, the linear density in the [-110] direction is 1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中使用了具体的公式和数值代入，最终得出计算结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解线性密度的定义并正确代入数值进行计算，但不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用线性密度的基本公式，并进行简单的数值代入和计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 2642, + "question": "Label the coordinates of all points on the (111) plane in a face-centered cubic unit cell", + "answer": "The coordinates of all points on the (111) plane in a face-centered cubic unit cell include: (0,0,0), (1,0,0), (0,1,0), (0,0,1), (1,1,0), (1,0,1), (0,1,1), (1,1,1).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出面心立方晶胞中(111)面上所有点的坐标，答案需要以文字形式详细描述所有坐标点，属于需要具体解释和列举的简答题类型。 | 知识层次: 题目要求标注面心立方晶胞中(111)面上所有点的坐标，这需要理解晶面指数的基本概念并应用坐标定位，属于直接套用基础知识的简单应用。 | 难度: 在简答题中属于中等难度，需要理解(111)平面的定义并正确应用面心立方晶胞的坐标表示方法。题目要求列出所有点坐标，涉及基本公式应用和简单计算，但需要一定的空间想象能力来确认所有符合条件的点。" + }, + { + "idx": 2643, + "question": "Calculate the weight-average relative molecular mass $\\overline{M}_{w}$ of this polymer material, given the average molecular weight M and mass fraction.", + "answer": "The weight-average relative molecular mass $\\overline{M}_{w} = \\sum w_{i}M_{i} = 150 + 1250 + 3150 + 6525 + 7150 + 4225 + 750 = 23200.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的平均分子量和质量分数计算聚合物的重量平均相对分子质量，答案是通过数值计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目考查基本公式的直接应用和简单计算，仅需套用重量平均相对分子质量公式并进行数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于基础难度，仅需直接套用单一公式（重量平均分子量公式）并进行简单的数值计算，无需多步骤推导或复杂公式组合。" + }, + { + "idx": 2644, + "question": "There is a copolymer ABS (A—acrylonitrile, B—butadiene, S—styrene), with the same mass fraction for each monomer. Calculate the mole fraction of each monomer.", + "answer": "Acrylonitrile (—C2H3CN—) monomer has a relative molecular mass of 53; butadiene (—C2H3C2H3—) monomer has a relative molecular mass of 54; styrene (—C2H3C6H5—) monomer has a relative molecular mass of 104. Assuming each weighs 1 g, then acrylonitrile has 1/53 mol, butadiene has 1/54 mol, and styrene has 1/104 mol. Therefore, the mole fractions of the monomers are: x_acrylonitrile = (1/53) / (1/53 + 1/54 + 1/104) = 40.1%; x_butadiene = (1/54) / (1/53 + 1/54 + 1/104) = 39.4%; x_styrene = (1/104) / (1/53 + 1/54 + 1/104) = 20.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算每个单体的摩尔分数，涉及数值计算和公式应用（如摩尔分数的计算公式）。答案提供了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将质量分数转换为摩尔分数，但计算过程直接，无需多步推理或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用基本公式进行简单计算。题目要求计算共聚物中各单体的摩尔分数，涉及相对分子质量和摩尔分数的基本概念，但计算步骤较为直接，只需套用摩尔分数公式并进行简单的数值运算。虽然涉及多个单体的计算，但每个步骤都是基础且独立的，没有复杂的公式组合或高级概念的应用。" + }, + { + "idx": 2645, + "question": "An organic compound consists of $\\\\mathbf{\\\\pi}\\\\mathbf{\\\\pi}(\\\\mathbf{C})$ at $62.1\\\\%$, $w(\\\\mathrm{H})$ at $\\\\mathtt{10.3\\\\%}$, and $\\\\boldsymbol{\\\\mathbf{\\\\hat{\\\\rho}}}\\\\mathbf{\\\\hat{\\\\rho}}\\\\mathbf{\\\\hat{\\\\rho}}$ at $27.6\\\\%$. Try to deduce the name of the compound.", + "answer": "The mole fractions of each component are $$ x_{\\\\mathrm{C}}=\\\\frac{62.1}{12.011}=5.2$$ $$ x_{{\\\\scriptscriptstyle\\\\mathrm{H}}}=\\\\frac{10,3}{1.008}{=}10,2$$ $$ x_{0}=\\\\frac{27\\\\cdot6}{16}=1.7$$ $$ \\\\begin{array}{r l}{\\\\mathrm{~C~}^{:}\\\\mathrm{~H~}^{:}\\\\mathrm{~O}=5.2:10.2:1.7\\\\approx3:6:1\\\\quad}&{{}\\\\mathrm{~H~}\\\\stackrel{\\\\mathrm{~O~}\\\\mathrm{~H~}}{\\\\longrightarrow}\\\\mathrm{C}-\\\\mathrm{C}-\\\\mathrm{H}}\\\\\\\\ {\\\\mathrm{~H~}^{:}\\\\mathrm{~H~}\\\\stackrel{\\\\mathrm{~O~}\\\\mathrm{~H~}}{\\\\longrightarrow}\\\\mathrm{~H~}}&{{}\\\\mathrm{~H~}\\\\stackrel{\\\\mathrm{~H~}}{\\\\longrightarrow}\\\\mathrm{~H~}}\\\\end{array}$$ Therefore, the possible compound is $\\\\mathrm{CH}_{3}\\\\mathrm{COCH}_{3}$ (acetone).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算各元素的摩尔分数来推导化合物的名称，涉及数值计算和公式应用。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括摩尔分数的计算和比例简化，同时需要将计算结果与有机化合物的结构关联起来，综合分析得出可能的化合物名称。这涉及到数值计算、公式应用和概念关联，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要进行多步计算（包括摩尔分数计算、比例简化、分子式推导），同时需要将计算结果与有机化学知识关联（识别官能团和常见有机化合物）。虽然计算步骤明确，但需要综合运用化学计量学和有机化学知识来推导最终答案，符合等级3的\"综合性计算问题\"标准。" + }, + { + "idx": 2646, + "question": "Calculate the number-average degree of polymerization $n_{\\\\eta}$ of this polymer material, given the number-average relative molecular mass $\\\\overline{M}_{n}$ and the mass of each repeating unit.", + "answer": "The mass of each repeating unit $\\\\overline{m} = 2 \\\\times 12.01 + 3 \\\\times 1.008 + 35.45 = 62.50$. The number-average degree of polymerization $n_{\\\\eta} = \\\\frac{\\\\overline{M}_{n}}{\\\\overline{m}} = \\\\frac{21150}{62.50} = 338$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚合物的数均聚合度，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的数均相对分子质量和重复单元的质量来计算数均聚合度。虽然需要理解相关概念，但计算过程直接且无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（$n_{\\\\eta} = \\\\frac{\\\\overline{M}_{n}}{\\\\overline{m}}$）进行计算，无需任何公式组合或复杂推导步骤。所有给定参数均为直接提供，计算过程仅涉及基础的四则运算。" + }, + { + "idx": 2647, + "question": "High-density polyethylene can be chlorinated by replacing hydrogen atoms in the structural units with chlorine atoms. If 8% of the hydrogen atoms in polyethylene are replaced by chlorine, calculate the mass fraction of chlorine that needs to be added.", + "answer": "From the previous question, it is known that the structural unit of polyethylene contains 2 C atoms and 4 H atoms. If 8% of the H atoms are replaced by Cl atoms, the mass fraction of Cl that needs to be added is $$ \\\\begin{array}{r}{\\\\overbrace{2\\\\times A_{c}+4\\\\times(0.08\\\\times A_{\\\\mathrm{G}}+0.92\\\\times A_{\\\\mathrm{H}})}^{4\\\\times0.08\\\\times A_{\\\\mathrm{G}}}=\\\\overbrace{2\\\\times12.01+4\\\\times(0.08\\\\times35.45+0.921\\\\times1.001\\\\times1.001\\\\times1.001\\\\times1.001\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01}^{4\\\\times0.08\\\\times35.45}}\\\\\\\\ {=0,290=29.0\\\\%\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氯的质量分数，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算，包括原子质量的计算、百分比替换的计算以及质量分数的计算。虽然涉及的概念和公式相对基础，但需要综合运用这些知识并进行适当的数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解聚乙烯结构单元的概念，进行多步计算（包括原子质量计算、百分比替换计算和最终质量分数计算），并正确应用化学计量关系。虽然不涉及复杂变量，但步骤较多且需要精确计算，属于中等偏上难度。" + }, + { + "idx": 2648, + "question": "It is known that pure titanium at 20°C is α-Ti (hcp structure), with lattice constants a=0.2951nm and c=0.4679nm. Calculate the interplanar spacing of the (112) plane.", + "answer": "For the hcp structure, when h+2k=3n (n=0,1,2,3...), and l is an odd number, there is an additional plane. d_(112)=1/√[(4/3)((h²+hk+k²)/a²)+(l/c)²]=1/√[(4/3)((1²+1×1+1²)/0.2951²)+(2/0.4679)²]=0.1248nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解(112)晶面的面间距，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及hcp结构的晶面间距公式应用，需要理解晶面指数的含义以及hcp结构的特殊性（如附加平面的条件）。虽然计算过程较为直接，但需要对hcp结构有较好的理解，并正确应用公式。 | 难度: 在计算题中属于综合性计算问题，需要应用hcp结构的特定公式进行多步计算，涉及晶面间距的复杂推导和数值代入。虽然不需要处理多变量，但要求对晶体结构有较深理解并能正确应用公式。" + }, + { + "idx": 2650, + "question": "It is known that pure titanium at 900°C is β-Ti (bcc structure) with a lattice constant a=0.3307nm. Calculate the interplanar spacing of the (112) plane.", + "answer": "For the bcc structure, there is an additional plane when h+k+l=odd number. d_(112)=a/√(h²+k²+l²)=0.3307/√(1²+1²+2²)=0.135nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解(112)晶面的晶面间距，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即直接套用已知的晶格常数和晶面间距公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（d=a/√(h²+k²+l²)）进行简单数值计算，无需任何公式组合或复杂推导步骤。题目明确给出了所有必要参数（晶格常数和晶面指数），解题过程仅涉及基本代数运算。" + }, + { + "idx": 2651, + "question": "Given that pure titanium at 900°C is β-Ti (bcc structure) with a lattice constant a=0.3307nm, calculate the (001) interplanar spacing.", + "answer": "For the (001) plane of bcc structure, d_(001)=1/2×a/√1²=1/2×0.3307/1=0.1653nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算(001)晶面间距），并应用了晶体学公式（d_(001)=1/2×a/√1²），最终给出数值结果（0.1653nm），符合计算题的特征。 | 知识层次: 题目考查基本公式的直接应用和简单计算，仅需套用已知的晶面间距公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（d_(hkl) = a / √(h² + k² + l²)）进行计算，无需额外步骤或复杂推导。题目明确给出了所有必要参数，且计算过程简单直接。" + }, + { + "idx": 2652, + "question": "Indicate the crystal plane with the largest interplanar spacing in a face-centered cubic crystal", + "answer": "From the above calculation results, it is known that the (111) crystal plane, which has the densest atomic arrangement, has the largest interplanar spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出具有最大晶面间距的晶面，并给出了解释性的答案，这需要文字解释和论述，而不是从选项中选择或简单的判断对错。 | 知识层次: 题目考查的是对晶体面间距这一基础概念的记忆和理解，特别是面心立方晶体中不同晶面间距的比较。虽然需要一定的计算，但主要是基于基本公式的直接应用和记忆性知识。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（面心立方晶体的晶面间距），但需要学生理解并解释为什么(111)晶面具有最大的晶面间距，而不仅仅是简单地记忆定义。这要求学生能够将原子排列密度与晶面间距的关系联系起来，并进行简要的论述。相比于等级1的基本定义简答，该题目需要更多的概念解释和描述，但尚未达到等级3的复杂概念体系阐述水平。" + }, + { + "idx": 2653, + "question": "Calculate the interplanar spacing and planar density of the (100) plane in a face-centered cubic crystal", + "answer": "In a face-centered cubic crystal, when (h k l) are not all odd or all even, there are additional planes. d_(100)=1/2*a/sqrt(1^2+0+0)=0.5a; K_100=((1/4×4+1)πr^2)/a^2=(2πr^2)/((4/sqrt(2))r)^2=0.785", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算面心立方晶体中(100)晶面的晶面间距和面密度，解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶面间距的计算和平面密度的计算，同时需要理解面心立方晶体的结构特点和相关公式的应用。这涉及到对晶体结构的基本概念的理解以及公式的正确应用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解面心立方晶体的结构特点，正确应用晶面间距公式，并进行多步计算。同时还需要掌握平面密度的计算方法，涉及多个概念的综合运用和数值计算。虽然计算步骤较多，但变量相对单一，没有涉及复杂多变量情况。" + }, + { + "idx": 2654, + "question": "Using the method of analytic geometry, how to determine the crystallographic direction indices of the intersection line between two crystal planes in a cubic crystal system", + "answer": "Let there be two non-parallel crystal planes (h1,k1,l1) and (h2,k2,l2) in a cubic crystal system, and their intersection line is [u v w]. According to geometric relations, this crystallographic direction should lie on both crystal planes simultaneously, hence the following system of equations can be obtained: h1u+k1v+l1w=0, h2u+k2v+l2w=0. Solving the above system of equations yields u:v:w=(k1l2-l1k2):(l1h2-h1l2):(h1k2-h1h2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过解析几何方法确定立方晶系中两个晶面交线的晶向指数，解答过程涉及建立方程组并求解，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目需要运用解析几何方法解决晶体学问题，涉及多步计算和概念关联（晶体平面指数与方向指数的关系），需要综合分析两个晶体平面的方程来求解交线的方向指数。虽然不涉及复杂的机理或创新设计，但比简单应用更深入，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体几何关系并建立方程组，通过多步计算求解方向指数。虽然涉及多个变量，但解题步骤相对明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 2655, + "question": "Using the method of analytic geometry, how to determine the crystallographic plane indices defined by two crystallographic directions in a cubic crystal system", + "answer": "Assume there are two non-parallel crystallographic directions [u1,v1,w1] and [u2,v2,w2] in the crystal. The crystallographic plane indices defined by them are (hkl). According to the zone law, we have the equation system: u1h+v1k+w1l=0, u2h+v2k+w2l=0. Solving the above equations yields h:k:l=(v1w2-w1v2):(w1u2-u1w2):(u1v2-v1u2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过解析几何方法计算确定立方晶系中由两个晶向定义的晶面指数，解答过程涉及方程组的建立和求解，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目需要应用解析几何方法解决晶体学问题，涉及多步计算（建立方程组并求解）和概念关联（晶带定律的应用），但不需要复杂的综合分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用晶体学中的区域定律，建立方程组并求解。虽然计算步骤相对明确，但涉及多个变量的交叉计算和概念关联，属于中等应用层次的多步计算问题。" + }, + { + "idx": 2656, + "question": "Using the method of analytic geometry, how to determine the angle θ between two crystallographic directions in a cubic crystal system", + "answer": "Let the two crystallographic directions in the cubic crystal system be [u1,v1,w1] and [u2,v2,w2]. From the scalar product of vectors, we know: [u1,v1,w1]·[u2,v2,w2]=|[u1,v1,w1]|·|[u2,v2,w2]|·cosθ. Therefore, the angle θ between the two crystallographic directions can be obtained from its cosine value: cosθ=(u1u2+v1v2+w1w2)/(√(u1²+v1²+w1²)·√(u2²+v2²+w2²)), θ=arccos(cosθ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶系中两个晶向之间的夹角，答案涉及向量点积和模的计算，最终需要通过数值计算得出角度值，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过向量点积公式计算两个晶向之间的夹角。虽然需要理解立方晶系中晶向的表示方法，但整体上是一个直接的公式套用和计算过程，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，仅需直接套用向量点积公式和反余弦函数计算角度，无需多个公式组合或复杂推导。解题步骤清晰且直接，符合等级2\"简单公式应用计算\"的标准。" + }, + { + "idx": 2657, + "question": "Calculate the interplanar spacing and planar density of the (110) plane in a face-centered cubic crystal.", + "answer": "In a face-centered cubic crystal, when (h k l) are not all odd or all even, there is an additional plane. d_(110)=1/2*a/sqrt(1^2+1^2+0)=0.354a; K_110=((1/4×4+1/2×2)πr^2)/(sqrt(2)*a^2)=(2πr^2)/(sqrt(2)(4/sqrt(2))r)^2=0.555", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行具体的数值计算（计算晶面间距和面密度），并应用了相关公式（d_(110)的计算和平面密度的公式），答案也给出了具体的计算结果。这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶面间距的计算和平面密度的计算，涉及面心立方晶体的结构特点和数学公式的应用，需要综合理解和分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解面心立方晶体的结构特点，正确应用晶面间距公式，并进行多步计算。同时还需要考虑平面密度的计算，涉及原子位置和面积的综合分析。虽然计算步骤较多，但各步骤相对明确，属于该题型内的中等偏上难度。" + }, + { + "idx": 2658, + "question": "Using the method of analytic geometry, how to determine the angle θ between two crystal planes in a cubic crystal system", + "answer": "Let there be two crystal planes (h1,k1,l1) and (h2,k2,l2) in the cubic crystal system. The angle θ between them is the angle between their respective normals [h1,k1,l1] and [h2,k2,l2]. Therefore, cosθ=(h1h2+k1k2+l1l2)/(√(h1²+k1²+l1²)·√(h2²+k2²+l2²)), and the angle θ between the two crystal planes is θ=arccos(cosθ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶系中两个晶面之间的夹角θ，答案给出了具体的计算公式和步骤，涉及数值计算和公式应用。 | 知识层次: 题目需要应用解析几何的方法，通过多步计算（包括向量点积和模的计算）来确定两个晶面之间的夹角。虽然公式可以直接套用，但需要理解晶面指数与法向量的关系，并进行综合计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解立方晶系中晶面指数的概念，掌握向量点积公式，并能正确应用反余弦函数求解角度。虽然计算步骤明确，但涉及多个概念的综合应用和公式推导，属于中等偏上的难度。" + }, + { + "idx": 2659, + "question": "Calculate the interplanar spacing and planar density of the (111) plane in a face-centered cubic crystal.", + "answer": "In a face-centered cubic crystal, when (h k l) are not all odd or all even, there are additional planes. d_(111)=a/sqrt(1^2+1^2+1^2)=0.577a; K_111=((1/6×3+1/2×3)πr^2)/(sqrt(3)/4*(sqrt(2)a)^2)=(2πr^2)/(sqrt(3)/4(sqrt(2)*4/sqrt(2))r)^2=0.907", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的数学计算和晶体学公式的使用，如计算晶面间距和面密度。答案也给出了具体的计算过程和结果。 | 知识层次: 题目需要应用晶体学中的面间距计算公式和面密度计算方法，涉及多步计算和概念关联，如理解面心立方晶体的特点、计算面间距d_(111)以及面密度K_111。虽然不涉及复杂的推理分析或创新设计，但需要综合运用多个知识点进行中等难度的计算。 | 难度: 在计算题中属于综合性计算问题，需要理解面心立方晶体的结构特点，掌握晶面间距和平面密度的计算公式，并进行多步骤的数值计算和单位转换。虽然不涉及复杂多变量，但需要将多个概念关联起来综合分析，属于中等偏上的难度。" + }, + { + "idx": 2660, + "question": "Using Cu's ka (λ=0.1542 nm), the first line of Cr's X-ray diffraction spectrum was measured at 2θ=64.6°. If the lattice constant a of (bcc) Cr is 0.2885 nm, find the Miller indices corresponding to these spectral lines.", + "answer": "According to the formula d_hkl=a/sqrt(h^2+k^2+l^2)=λ/(2sinθ), if 2θ=64.6°, then h^2+k^2+l^2={(2sin(64.6°/2)×0.2885)/0.1542}^2=3.9976≈4. Therefore, this plane is (200), or (020) or (002).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的数据和公式求解Miller indices，答案展示了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算（包括布拉格定律的应用、晶面间距公式转换、角度计算等），并需要将X射线衍射原理与晶体结构知识关联起来。虽然不涉及复杂的综合分析或创新设计，但已超出简单套用公式的范畴，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用布拉格定律和晶面间距公式进行多步计算，并理解立方晶系的对称性特点。虽然计算步骤较多，但变量关系明确，属于中等应用层次中较为典型的综合分析题。" + }, + { + "idx": 2661, + "question": "The crystal structure of Ni is face-centered cubic, and its atomic radius is r=0.1243nm. Calculate the lattice constant of Ni.", + "answer": "a=4r/sqrt(2)=4×0.1243/sqrt(2)=0.3516(nm)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（a=4r/sqrt(2)）来求解晶格常数，答案是一个具体的数值结果（0.3516nm），符合计算题的特征。 | 知识层次: 题目仅需应用基本公式（a=4r/sqrt(2)）进行一步计算，无需多步推理或综合分析，属于典型的简单应用类型。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（a=4r/sqrt(2)）进行数值计算，无需任何变形或组合公式，解题步骤简单直接。" + }, + { + "idx": 2664, + "question": "The crystal structure of Ni is face-centered cubic, with an atomic radius of r=0.1243nm and a lattice constant of a=0.3516nm. Calculate the density of Ni.", + "answer": "ρ=4Ar/(a³×NA)=4×58.69/((3.516×10^-8)^3×6.023×10^23)=8.967(g/cm³)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镍的密度，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及晶体结构参数和密度的直接计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用密度计算公式，并代入给定的原子半径和晶格常数等已知数值进行简单计算。无需多个公式组合或复杂推导，属于基础级别的计算题。" + }, + { + "idx": 2665, + "question": "One of the allotropes of Mn has a cubic structure with a lattice constant a of 0.632 nm, an atomic radius r of 0.122 nm, and 20 atoms in the unit cell. What is its packing density?", + "answer": "The packing density K = (20 * (4/3) * π * r³) / a³. Substituting the data: K = (20 * (4/3) * π * (0.122)^3) / (0.632)^3 = 0.466.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解材料的堆积密度，答案是通过具体计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及原子半径、晶格常数和堆积密度的直接套用，不需要多步计算或复杂分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（堆积密度公式）进行数值计算，无需任何公式组合或复杂推导步骤。题目中所有参数均已直接给出，计算过程仅涉及基本代数运算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2666, + "question": "The lattice constant of Cr is $\\mathbf{a=0.2884nm}$, and the density is $\\rho{=}7.19\\mathrm{g}/\\mathrm{cm}^{3}$. Determine the crystal structure of $\\mathrm{Cr}$ at this time.", + "answer": "p= $\\rho{=}\\frac{n A_{\\tau}}{a\\times N_{\\mathrm{A}}}\\Rightarrow n=\\frac{\\rho a^{3}N_{\\mathrm{A}}}{A_{\\tau}}{=}\\frac{7.19\\times(2.884\\times10^{-8})^{3}\\times6.023\\times10^{23}}{52.0}{=}1.9977\\approx2$, hence it is a bcc structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体的结构，解答过程中涉及密度、晶格常数等物理量的计算，最终通过计算结果得出结论。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，通过已知的晶格常数和密度计算晶体结构类型，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用密度公式和晶体结构的基本概念，但计算步骤较为直接，仅涉及单一公式的套用和简单数值计算。" + }, + { + "idx": 2667, + "question": "In indium with a tetragonal structure, the relative atomic mass A_r=114.82, atomic radius r=0.1625 nm, lattice constants a=0.3252 nm, c=0.4946 nm, and density ρ=7.286 g/cm³. What is the packing fraction of In?", + "answer": "K=(2×(4/3)πr³)/(a²c)=(2×(4/3)π(0.1625)^3)/((0.3252)^2×0.4946)=0.6873.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，答案是通过具体的数学运算得出的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及原子半径、晶格常数和密度的直接套用，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算，仅需套用单一公式（堆积分数公式）并进行数值计算，无需多个公式组合或复杂推导。虽然涉及单位转换和基本代数运算，但步骤直接且明确。" + }, + { + "idx": 2668, + "question": "In indium with a tetragonal structure, the relative atomic mass A_r=114.82, atomic radius r=0.1625 nm, lattice constants a=0.3252 nm, c=0.4946 nm, and density ρ=7.286 g/cm³. How many atoms are there in the unit cell of In?", + "answer": "n=(ρa²c×N_A)/A_r=(7.286×(3.252×10^-8)^2×(4.946×10^-8)×6.023×10^23)/114.82=1.9991≈2. Therefore, there are 2 atoms in the unit cell of In.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的参数和密度公式计算出单位晶胞中的原子数，答案以数值结果呈现。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的密度、晶格常数和相对原子质量等参数，直接套用公式计算单位晶胞中的原子数。虽然需要理解公式的含义和单位转换，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于简单应用难度，需要应用密度公式进行数值计算，但仅涉及单一公式的直接套用和简单代数运算，无需多个公式组合或复杂推导。" + }, + { + "idx": 2669, + "question": "One of the allotropes of Mn has a cubic structure with a lattice constant a of 0.632nm, ρ of 7.26g/cm³, and Ar of 54.94. How many atoms are there in the Mn unit cell?", + "answer": "According to the formula ρ = (n * Ar) / (a³ * NA), it can be derived that n = (ρ * a³ * NA) / Ar. Substituting the data: n = (7.26 * (6.32 * 10^-8)^3 * 6.023 * 10^23) / 54.94 = 20.091 ≈ 20. Therefore, there are 20 atoms in each unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞中的原子数量，答案涉及具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括单位转换、公式推导和数值代入，同时需要理解晶体结构、密度计算和原子量等概念的综合应用。虽然不涉及复杂的推理分析或创新设计，但已超出简单直接套用公式的范畴。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式进行多步计算，涉及单位转换、立方运算和科学计数法的处理，同时需要理解晶格常数、密度和原子量的概念及其相互关系。虽然计算过程较为直接，但步骤较多且需要精确操作，属于中等偏上的难度。" + }, + { + "idx": 2670, + "question": "The crystal structure of Mo is body-centered cubic, with a lattice constant $a{=}0.3147{\\mathrm{~nm}}$. Determine the atomic radius $\\\\scriptstyle{\\\\mathcal{r}}_{\\\\circ}$ of Mo.", + "answer": "$$ \\\\alpha{=}\\\\frac{4r}{\\\\sqrt{3}}\\\\Rightarrow r{=}\\\\frac{\\\\sqrt{3}}{4}\\\\alpha{=}\\\\frac{\\\\sqrt{3}}{4}\\\\times0.3147{=}0.1363(\\\\mathrm{nm})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定Mo的原子半径，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目考查基本公式的应用和简单计算，仅需套用体心立方晶体结构的原子半径计算公式即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用体心立方晶体的原子半径公式$r=\\frac{\\sqrt{3}}{4}a$，将已知的晶格常数$a=0.3147\\mathrm{~nm}$代入即可得到结果。整个过程不涉及多个公式组合或复杂计算步骤，是最基础的计算题类型。" + }, + { + "idx": 2671, + "question": "Compared with question 1, explain the reasons for the difference.", + "answer": "Reasons for the difference: different crystal structures and different atomic radii; when the coordination number of atoms in the crystal structure decreases, the atomic radius contracts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释差异的原因，答案需要文字解释和论述，没有提供选项或要求计算 | 知识层次: 题目要求解释晶体结构和原子半径差异的原因，涉及对晶体结构变化与原子半径关系的深入理解和分析，需要综合运用相关概念进行推理和解释。 | 难度: 在简答题题型中，该题目要求对晶体结构和原子半径差异进行机理深度解释，需要综合运用材料科学知识进行推理分析。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述层面，达到了对晶体学原理的深入解释要求，符合等级4的难度标准。" + }, + { + "idx": 2672, + "question": "If the atomic fraction of Zn dissolved in a Cu crystal is 10%, what is the maximum additional atomic fraction of Sn that can be dissolved?", + "answer": "1.36=(1(100-10-x3)+2×10+4x3)/100, solving gives x3=8.67, meaning a maximum of 8.67% Sn can be additionally dissolved.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的原子分数和公式求解最大可溶解的Sn原子分数。答案是通过具体计算得出的数值结果。 | 知识层次: 题目需要进行多步计算和公式应用，涉及原子分数的溶解极限计算，需要理解并关联不同元素的溶解机制，但不需要复杂的推理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如原子分数、溶解极限等），进行多步计算和公式推导。虽然涉及变量求解，但整体计算过程相对直接，没有过于复杂的变量关系或高阶数学要求。" + }, + { + "idx": 2673, + "question": "What is the maximum atomic fraction of Zn or Sn that can be dissolved in Cu-Zn and Cu-Sn solid solutions?", + "answer": "The limiting electron concentration for Cu-based solid solutions is 1.36. For the Cu-Zn solid solution, 1.36=(1(100-x1)+2x1)/100→x1=36, so the maximum solubility is 36% Zn; for the Cu-Sn solid solution, 1.36=(1(100-x2)+4x2)/100→x2=12, so the maximum solubility is 12% Sn.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定Zn和Sn在Cu基固溶体中的最大溶解度。答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及电子浓度的概念应用和公式推导，需要理解电子浓度与溶解度之间的关系，并进行数值计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要理解电子浓度概念并应用公式进行多步计算。题目涉及两个不同的固溶体系统（Cu-Zn和Cu-Sn），需要分别计算最大溶解度，但计算过程相对直接，没有涉及复杂变量或高级数学技巧。" + }, + { + "idx": 2674, + "question": "According to X-ray diffraction measurements, at 912°C, the lattice parameter a of α-Fe is 0.2892 nm, and that of γ-Fe is 0.3633 nm. Calculate the volume expansion when γ-Fe transforms into α-Fe.", + "answer": "fcc: r = sqrt(2)/4 * a = sqrt(2)/4 * 0.3633 = 0.1284 nm; bcc: r = sqrt(3)/4 * a = sqrt(3)/4 * 0.2892 = 0.1251 nm; ΔV = (1/2 * (0.2892)^3 - 1/4 * (0.3633)^3) / (1/4 * (0.3633)^3) = 0.87%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶格参数转换和体积变化计算，答案以具体数值结果呈现。 | 知识层次: 题目需要进行多步计算，包括晶格参数转换和体积变化计算，涉及fcc和bcc晶体结构的几何关系理解，以及体积膨胀率的公式应用。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶体结构参数的计算方法，理解fcc和bcc结构的原子半径与晶格参数的关系，并进行多步计算和综合分析。虽然计算步骤较多，但每一步的计算相对明确，不需要处理复杂多变量或高度抽象的数学推导。" + }, + { + "idx": 2675, + "question": "Cementite (Fe3C) is an interstitial compound with an orthorhombic crystal structure. Its lattice constants are a=0.4514nm, b=0.508nm, c=0.6734nm, and its density ρ=7.66g/cm³. Determine the number of Fe and C atoms per unit cell of Fe3C.", + "answer": "Assume the number of C atoms in the Fe3C unit cell is x, then the number of Fe atoms is 3x. ρ = (x Ar(C) + 3 × Ar(Fe)) / (a b c × NA), 7.66 = (x × 12.011 + 3x × 55.85) / (4.514 × 5.08 × 6.743 × 10^-24 × 6.023 × 10^23). x = (7.66 × 4.514 × 5.08 × 6.734 × 0.602) / (12.011 + 3 × 55.85) = 3.968 ≈ 4. 3x = 12. Therefore, in the Fe3C compound, each unit cell contains 4 C atoms and 12 Fe atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定Fe3C晶胞中的Fe和C原子数量，答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、原子量的代入、单位换算等，同时需要理解晶胞结构和化学计量比的概念。虽然不涉及复杂的推理分析或机理解释，但计算过程较为复杂，需要综合运用多个知识点。 | 难度: 在计算题中属于综合性计算问题，需要结合晶体结构、密度公式和原子量进行多步计算，涉及单位换算和近似处理，但计算过程相对直接，没有引入复杂变量或高级数学工具。" + }, + { + "idx": 2676, + "question": "According to the hard sphere model of crystals, if the diameter of the spheres remains unchanged, calculate the volume expansion when Fe transforms from fcc to bcc.", + "answer": "a_fcc = 4 / sqrt(2) * r ⇒ V_fcc = a_fcc^3 = 64 / (2 * sqrt(2)) * r^3；a_bcc = 4 / sqrt(3) * r ⇒ V_bcc = a_bcc^3 = 64 / (3 * sqrt(3)) * r^3；ΔV = (1/2 * 64 / (3 * sqrt(3)) * r^3 - 1/4 * 64 / (2 * sqrt(2)) * r^3) / (1/4 * 64 / (2 * sqrt(2)) * r^3) = 9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行具体的数值计算，涉及晶体结构转变时的体积变化计算，答案给出了详细的公式推导和计算结果。 | 知识层次: 题目需要应用晶体结构的硬球模型，进行多步计算（fcc和bcc的晶格常数计算、体积计算、体积变化率计算），并理解fcc和bcc的原子堆积方式差异。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解fcc和bcc晶体结构的几何关系，正确应用硬球模型公式，并进行多步数值计算和单位转换。虽然不涉及复杂变量，但需要将多个概念关联并准确执行计算步骤，在同类计算题中属于中等偏上难度。" + }, + { + "idx": 2677, + "question": "What is an interstitial phase? Explain its characteristics from the perspective of crystal structure.", + "answer": "Interstitial phases are intermediate phases dominated by atomic size factors. They are formed when nonmetal elements with smaller atomic radii occupy the interstitial sites of the lattice, yet the lattice of the interstitial phase differs from that of any of their constituent elements. Their composition can fluctuate within a certain range. However, the constituent elements generally have a specific atomic ratio, which can be represented by a chemical formula. When rB/rA < 0.59, interstitial phases usually form, characterized by a simple crystal structure, extremely high melting points, and hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙相的概念及其晶体结构特征，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的文字描述，符合简答题的特点。 | 知识层次: 题目主要考查对间隙相（interstitial phase）的基本定义和晶体结构特征的理解和记忆，属于基础概念的记忆性知识。虽然涉及一些晶体结构的描述，但整体上是对基本概念的阐述，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释间隙相的定义及其晶体结构特征，属于概念解释和描述的难度等级。虽然需要记忆和解释一些基本原理，但不需要复杂的体系阐述或多步骤推理。" + }, + { + "idx": 2678, + "question": "Given that the ionic radii of K⁺ and Cl⁻ are 0.133nm and 0.181nm respectively, and KCl has a CsCl-type structure, calculate its density ρ.", + "answer": "ρ = (Aₜ(K) + Aₜ(Cl)) / [(2(rₖ⁺ + rCl⁻) / √3)³ × Nₐ] = (39.102 + 35.453) / [(2 × (0.133 + 0.181) / √3)³ × 6.023 × 10²³ × 10⁻²⁴] = 2.597 g/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的离子半径和晶体结构类型，应用公式进行密度计算，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括离子半径的加和、晶体结构参数的计算、密度的推导等，涉及多个概念的综合应用和公式的灵活运用，但不需要复杂的推理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解离子半径与晶体结构的关系，应用CsCl型结构的几何关系，进行多步计算，包括单位转换和密度公式的正确应用。虽然步骤较多，但每个步骤相对明确，属于该题型内的中等偏上难度。" + }, + { + "idx": 2679, + "question": "MgO has a NaCl-type structure. The ionic radius of Mg2+ is 0.078nm, and the ionic radius of O2- is 0.132nm. Calculate the density (ρ) of MgO.", + "answer": "ρ = 4[Ar(Mg) + Ar(O)] / (2rMg + 2rO)^3 × NA = 4 × 24.31 + 4 × 16.00 / 8 × (0.78 + 1.32)^3 × 10^-24 × 6.023 × 10^23 = 3.613 g/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的离子半径和晶体结构信息，应用公式进行密度计算，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括晶体结构、离子半径、密度计算公式的应用，以及单位转换和常数代入的综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用晶体结构知识、离子半径概念、密度计算公式，并进行多步单位换算和数值计算。虽然计算过程明确，但涉及多个概念的综合运用和单位转换的精确性要求，属于中等偏上难度。" + }, + { + "idx": 2680, + "question": "A solid solution contains x(MgO) at 30% and x(LiF) at 70%. Calculate the mass fractions of Li1+, Mg2+, F1-, and O2-. The relative atomic masses of Mg, O, Li, and F are 24.31, 16.00, 6.94, and 19.00, respectively.", + "answer": "w(Li+) = (0.7 × 6.94) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 16%\\nw(Mg2+) = (0.3 × 24.31) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 24%\\nw(F-) = (0.7 × 19) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 44%\\nw(O2-) = (0.3 × 16) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 16%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以求出各离子的质量分数。答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目涉及基本公式应用和简单计算，需要根据给定的摩尔分数和相对原子质量进行直接套用和计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算固体溶液中各离子的质量分数，涉及基本的摩尔分数与质量分数的转换计算，但只需要套用单一的质量分数公式（w = (x × M) / Σ(x × M)）即可完成。虽然需要分别计算四种离子的质量分数，但每个计算步骤都是重复相同的简单公式应用，没有复杂的推导或多步骤组合计算要求。" + }, + { + "idx": 2681, + "question": "MgO has a NaCl-type structure. The ionic radius of Mg2+ is 0.078nm, and the ionic radius of O2- is 0.132nm. Calculate the packing fraction (K) of MgO.", + "answer": "K = [4 × (4/3)πrMg^3 + 4 × (4/3)πrO^3] / (2rMg + 2rO)^3 = [16/3π × (0.78^3 + 1.32^3)] / [8 × (0.78 + 1.32)^3] = 0.627", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体的数学计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及离子半径和堆积分数的直接计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算MgO的堆积分数，直接套用已知的离子半径和堆积分数公式即可完成计算。虽然涉及多个离子的体积计算，但所有步骤都是基于单一公式的直接应用，没有复杂的推导或多步骤组合计算。因此在该题型内属于等级2难度。" + }, + { + "idx": 2682, + "question": "What is an interstitial solid solution? Explain its characteristics from the perspective of crystal structure.", + "answer": "An interstitial solid solution is formed when solute atoms are distributed in the interstitial sites of the solvent lattice. The solute atoms that form interstitial solid solutions are usually non-metallic elements with atomic radii smaller than 0.1nm, such as H, B, C, N, O, etc. The interstitial solid solution retains the crystal structure of the parent phase (solvent), and its composition can fluctuate within a certain solubility limit, but cannot be expressed by a molecular formula.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙固溶体的定义及其晶体结构特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对间隙固溶体这一基本概念的定义和特征的理解，属于基础概念记忆范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释间隙固溶体的定义及其晶体结构特征，属于概念解释和描述的难度级别。虽然需要记忆一些基本概念（如间隙固溶体的形成条件和典型溶质元素），但不需要进行复杂的体系阐述或多概念综合分析，因此属于中等难度。" + }, + { + "idx": 2683, + "question": "A solid solution contains x(MgO) at 30% and x(LiF) at 70%. If the density of MgO is 3.6 g/cm3 and the density of LiF is 2.6 g/cm3, what is the density of this solid solution?", + "answer": "The density of the solid solution ρ = 0.3 × 3.6 + 0.7 × 2.6 = 2.9 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（密度加权平均）来求解固溶体的密度，答案是一个具体的计算结果而非选择或论述。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，只需要将给定的摩尔分数和密度代入线性组合公式即可得到结果，无需多步计算或复杂分析。 | 难度: 在计算题题型中，该题目属于单一公式直接计算的难度等级。题目仅需要应用简单的加权平均公式（ρ = x₁ρ₁ + x₂ρ₂）进行计算，无需额外的公式组合或复杂转换。所有给定参数都是直接可用的，计算步骤简单明了，属于该题型中最基础的难度级别。" + }, + { + "idx": 2684, + "question": "What are interstitial compounds? Explain their characteristics from the perspective of crystal structure.", + "answer": "Interstitial compounds belong to intermediate phases dominated by atomic size factors. They are formed when non-metal elements with smaller atomic radii occupy the interstitial sites of the crystal lattice, yet the lattice of interstitial compounds differs from that of any of their constituent elements. Their composition can vary within a certain range. However, the constituent elements generally maintain a specific atomic ratio, which can be represented by a chemical formula. When rB/rA≥0.59, interstitial compounds form, exhibiting a complex crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙化合物的定义及其晶体结构特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对间隙化合物的基本定义和晶体结构特征的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求不仅解释间隙化合物的定义，还需要从晶体结构的角度阐述其特征，涉及多个知识点的综合运用和较深入的理解。这超出了简单的定义复述或概念描述，属于复杂概念体系的阐述，因此在该题型内属于较高难度等级。" + }, + { + "idx": 2685, + "question": "Given the ionic radii of K⁺ and Cl⁻ are 0.133nm and 0.181nm respectively, and KCl has a CsCl-type structure, calculate its packing fraction κ.", + "answer": "κ = [(4/3)πrₖ⁺³ + (4/3)πrCl⁻³] / [2(rₖ⁺ + rCl⁻) / √3]³ = [(4/3)π(0.133³ + 0.181³)] / [2(0.133 + 0.181) / √3]³ = 0.728", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的离子半径和晶体结构类型，应用特定的公式进行数值计算来求解堆积分数κ。答案展示了完整的计算过程和最终数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括体积计算和晶体结构参数的应用，同时需要理解CsCl型结构的几何关系。虽然不涉及复杂的推理分析，但需要综合运用离子半径和晶体结构知识进行计算。 | 难度: 在计算题题型中，该题目属于综合性计算问题。虽然题目提供了明确的离子半径和晶体结构类型，但需要学生掌握CsCl型结构的几何关系，正确应用立方体对角线长度与离子半径的关系，并进行多步的数学计算。这需要将晶体结构知识与数学计算能力相结合，属于中等偏上的难度水平。相比简单的单步计算题（等级2）更为复杂，但尚未达到需要处理多变量或非常规计算的最高难度（等级4）。" + }, + { + "idx": 2686, + "question": "In a ZrO2 solid solution, for every 6 Zr4+ ions, 1 Ce3+ ion is added to form a cubic lattice of ZrO2. If these cations form an fcc structure and the O2- ions occupy the tetrahedral interstitial sites, calculate how many O2- ions are needed for 100 cations.", + "answer": "The total charge of 100 cations = (100/7) × (6×4 + 1×2) = 371.4, so 371.4/2 = 185.7 O2- ions are required to balance this charge.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定需要多少O2-离子来平衡100个阳离子的电荷。答案通过具体的计算步骤得出数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解固溶体中的电荷平衡和晶体结构（fcc和间隙位置），并进行综合计算以确定所需的O2-离子数量。 | 难度: 在计算题中属于综合性计算问题，需要理解电荷平衡的概念，进行多步计算，并综合分析离子比例和电荷关系。虽然计算步骤较多，但每一步的逻辑清晰，属于中等应用层次的计算题。" + }, + { + "idx": 2687, + "question": "What is glass?", + "answer": "The so-called glass refers to an amorphous solid that has a glass transition temperature. The difference between glass and other amorphous states lies in the presence or absence of a glass transition temperature. The glassy state also refers to amorphous metals and alloys (amorphous metal), which are essentially supercooled liquid metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“glass”进行定义和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，主要涉及玻璃的定义和基本特性，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释玻璃的定义，并进一步区分玻璃与其他非晶态物质的差异，涉及玻璃转变温度的概念。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或深入分析，属于中等难度的概念解释题。" + }, + { + "idx": 2688, + "question": "In the ZrO2 solid solution, cations form an fcc structure, and O2- ions are located at tetrahedral interstitial sites. Given that 100 cations form 25 unit cells, and each unit cell has a total of 8 tetrahedral interstitial sites, calculate the percentage of tetrahedral interstitial sites occupied by O2- ions.", + "answer": "Since the fcc structure contains 4 atoms per unit cell, 100 cations form 25 unit cells. Each unit cell has a total of 8 tetrahedral interstitial sites, so the percentage of tetrahedral interstitial sites occupied by O2- ions is 185.7/(25×8)=92.9%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，通过给定的条件和单位细胞的结构参数来计算氧离子占据四面体间隙的百分比。答案是通过具体的数学运算得出的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位细胞数量计算、间隙位置总数计算以及百分比计算，同时需要理解fcc结构和间隙位置的基本概念，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解fcc结构的基本概念（如单位细胞中的原子数和间隙位置数量），进行多步计算（包括单位细胞数量计算和间隙位置总数计算），并最终综合分析得出百分比结果。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有引入复杂变量或高级数学工具。" + }, + { + "idx": 2689, + "question": "Given that the number-average relative molecular weight of linear polytetrafluoroethylene is 5×10^5, its C-C bond length is 0.154 nm, and the bond angle θ is 109°, calculate its root-mean-square length.", + "answer": "The root-mean-square length r=d√N=0.154×√(1.0×10^4)=15.4 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（分子量、键长、键角）进行数值计算，应用公式（均方根长度公式）得出具体数值结果（15.4 nm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解分子量的概念、键长和键角的关系，并应用公式计算均方根长度。这需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（如分子量、键长、键角）并进行多步计算（包括开方运算和单位转换），但计算过程相对直接，不涉及复杂多变量或高级数学工具。" + }, + { + "idx": 2690, + "question": "Polypropylene is polymerized from propylene, with the chemical formula C3H6. Crystalline polypropylene belongs to the monoclinic crystal system, with lattice constants α = 0.665 nm, b = 2.096 nm, c = 0.65 nm, α = γ = 90°, β = 99.3°, and a density ρ = 0.91 g/cm³. Calculate the number of C and H atoms in the unit cell of crystalline polypropylene.", + "answer": "Assuming there are x C atoms in the polypropylene unit cell, then there are 2x H atoms. The volume of the unit cell is $$ V = a b c \\\\sin \\\\beta $$ $$ \\\\rho = \\\\frac{x \\\\cdot 12.011 + 2x \\\\cdot 1.008}{(6.65 \\\\times 10^{-8})(20.96 \\\\times 10^{-8})(6.5 \\\\times 10^{-8}) \\\\sin 99.3 \\\\times 6.023 \\\\times 10^{23}} = 0.91 $$ $$ x = \\\\frac{0.91 \\\\times 6.65 \\\\times 2.096 \\\\times 6.5 \\\\times \\\\sin 99.3 \\\\times 6.023}{12.011 + 2 \\\\times 1.008} = 34.936 \\\\approx 35 $$ $$ 2x = 2 \\\\times 35 = 70 $$ Therefore, the C3H6 unit cell contains 35 C atoms and 70 H atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞中的碳和氢原子数量，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括体积计算、密度公式应用以及三角函数的使用，同时需要理解晶体结构和化学组成之间的关系。虽然不涉及复杂的推理或创新设计，但需要综合运用多个知识点进行计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要应用晶体学参数、密度公式和化学计量关系进行多步计算，涉及单位换算和三角函数应用，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2691, + "question": "The ionic radii of $\\\\mathrm{Al}^{3+}$ and $\\\\mathrm{O}^{2-}$ are $0.051\\\\mathrm{nm}$ and $0.132\\\\mathrm{nm}$ respectively. Determine the coordination number of $\\\\mathbf{Al}_{2}\\\\mathbf{O}_{3}$.", + "answer": "The ratio of the two ionic radii is $\\\\frac{0.051}{0.132}{=}0.386$. The coordination number (CN) of an ionic crystal depends on the ratio of the cation to anion radii. Referring to the table, when $\\\\frac{r_{+}}{r_{-}}$ is between $0.225\\\\sim0.414$, the CN is 4. The shape of the anion polyhedron is tetrahedral.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算离子半径比来确定配位数，解答过程中涉及数值计算和查表应用，符合计算题的特征。 | 知识层次: 题目需要应用离子半径比与配位数关系的表格进行简单计算和直接套用，属于基本公式应用和简单计算的范畴。 | 难度: 在计算题中属于简单应用难度，需要应用基本的离子半径比公式并参考表格确定配位数，解题步骤较为直接，但需要理解离子半径比与配位数的关系。" + }, + { + "idx": 2692, + "question": "Diamond is a crystalline form of carbon with a lattice constant α = 0.357 nm. When it transforms into the graphite (ρ = 2.25 g/cm³) structure, calculate the change in volume.", + "answer": "The crystal structure of diamond is a complex face-centered cubic structure, with each unit cell containing a total of 8 carbon atoms. The density of diamond is $$ ρ = (8 × 12) / ((0.357 × 10⁻⁷)³ × 6.023 × 10²³) = 3.503 (g/cm³) $$. For 1 g of carbon, when it is in the diamond structure, its volume is $$ V₁ = 1 / 3.503 = 0.285 (cm³) $$. When it is in the graphite structure, its volume is $$ V₂ = 1 / 2.25 = 0.444 (cm³) $$. Therefore, the volume expansion when transforming from diamond to graphite is = (V₂ - V₁) / V₁ = (0.444 - 0.285) / 0.285 ≈ 55.8%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及密度计算、体积计算以及百分比变化等具体数值运算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶体结构分析、密度计算和体积变化计算，涉及多个概念的综合应用和关联分析。虽然不涉及复杂的推理或机理解释，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构、密度计算、体积变化等多个概念，并进行多步计算和综合分析。虽然计算步骤较多，但每一步的计算相对明确，没有涉及复杂多变量或高难度数学处理，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 2693, + "question": "Given that the number-average relative molecular weight of linear polytetrafluoroethylene is 5×10^5, the C-C bond length is 0.154 nm, and the bond angle θ is 109°, calculate its total chain length L.", + "answer": "For a linear polymer, the total chain length L depends on the bond length d between atoms, the number of bonds N, and the angle θ between adjacent bonds, i.e., L=Ndsin(θ/2). For polytetrafluoroethylene, each chain unit has 2 C atoms and 4 F atoms. First, calculate its degree of polymerization πn=M/m=5×10^5/(2×12.01+4×19.00)=5×10^3. Each chain unit has 2 C atoms, so each chain unit has two C-C main bonds. Therefore, the total number of bonds in this polymer is N=2πn=2×5×10^3=1.0×10^4. If each C-C bond length d=0.154 nm and bond angle θ=109°, then L=Ndsin(θ/2)=1.0×10^4×0.154×sin(109°/2)=1253.738 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及分子量、键长、键角等参数的计算，最终需要得出一个具体的数值结果。答案中详细展示了计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算聚合度、键的数量，并应用公式计算总链长。虽然涉及的知识点较为基础，但需要综合运用多个概念和步骤来完成计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握聚合物链长度计算的基本公式，并能正确关联聚合度、键长和键角等概念。解题过程涉及多步计算，包括聚合度的计算、键数的确定以及最终链长的计算，但不需要处理复杂多变量或非常规条件。" + }, + { + "idx": 2694, + "question": "What are the main differences between amorphous and crystalline substances in terms of internal atomic arrangement and properties?", + "answer": "From the perspective of internal atomic arrangement, the fundamental characteristic of a crystalline structure is that atoms are arranged periodically in three-dimensional space, exhibiting long-range order, whereas the atomic arrangement in amorphous materials lacks long-range order. In terms of properties, crystals have fixed melting points and anisotropy, while amorphous materials do not have fixed melting points and are isotropic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述非晶态和晶态物质在内部原子排列和性质上的主要差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对非晶态和晶态物质内部原子排列和性质差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释非晶态和晶态物质在原子排列和性质上的主要差异，这需要学生对两种物质的基本概念有清晰的理解，并能进行对比描述。虽然涉及多个知识点（原子排列和性质差异），但不需要复杂的体系阐述或深入分析，属于中等难度的概念解释题。" + }, + { + "idx": 2695, + "question": "Calculate the theoretical density of α-Fe (given a=0.286nm for α-Fe, Ar(Fe)=55.85, NA=6.023×10²³)", + "answer": "ρtheoretical=2×Ar(Fe)/(a³×NA)=2×55.85/((2.86×10⁻⁸)³×6.023×10²³)=7.9276(g/cm³)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出一个具体的密度值，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及晶体结构参数和密度的基本计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算，仅需套用密度计算公式并代入给定数值，无需复杂步骤或多公式组合。" + }, + { + "idx": 2696, + "question": "Calculate the packing density of the diamond structure.", + "answer": "Diamond is the most typical covalent crystal, entirely bonded by covalent bonds. Its crystal structure belongs to a complex fcc structure, where each C atom (d=0.1544 nm) has 4 equidistant nearest neighbors, conforming to the 8-N rule. The distance between the nearest neighbors is equivalent to the bond length. Based on the crystal structure of diamond, it can be determined that: Therefore, $$ a={\\frac{4\\times0.1544}{\\sqrt{3}}}=0.3566({\\mathrm{nm}})$$ $$ {\\cal K}=\\frac{8\\times\\frac43\\pi r^{3}}{a^{3}}=\\frac{8\\times\\frac43\\pi\\left(\\frac{0.1544}{2}\\right)^{3}}{(0.3566)^{3}}=0.34$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要理解金刚石结构的基本特征，应用几何关系和数学公式进行多步计算，包括确定晶格常数和堆积密度。虽然涉及基础概念，但计算过程需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解金刚石结构的晶体学特征，应用几何关系推导晶格常数，并进行多步数值计算。虽然不涉及多变量交互，但需要将晶体结构知识与数学计算能力结合，解题步骤较为复杂，属于该题型中的中等偏上难度。" + }, + { + "idx": 2697, + "question": "Calculate the theoretical packing density of α-Fe (given rFe=0.1241nm, a=0.286nm)", + "answer": "Ktheoretical=8/3×π×rFe³/a³=8/3×π×(0.1241)³/(0.286)³=0.6844", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目要求直接应用给定的公式进行数值计算，属于基本公式应用和简单计算的范畴，无需多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目仅要求套用已知的晶体学参数（rFe和a）到给定的理论堆积密度公式中进行计算，无需额外的公式组合或复杂的推导步骤。计算过程直接且明确，属于该题型中最基础的难度水平。" + }, + { + "idx": 2698, + "question": "If in fcc Cu, 1 out of every 500 atoms is missing, and its lattice constant is 0.3615 nm, calculate the density of Cu.", + "answer": "$$ \\\\rho{=}\\\\frac{4\\\\times\\\\left(1-\\\\frac{1}{500}\\\\right)63.54}{(3.615\\\\times10^{-8})^{3}\\\\times6.023\\\\times10^{23}}{=}8.915({\\\\mathrm{g/cm}}^{3})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及密度计算和缺陷浓度的考虑，答案以具体数值形式给出。 | 知识层次: 题目需要进行多步计算，包括考虑晶格缺陷（空位）对原子数量的影响，应用密度计算公式，并进行单位转换和数值计算。这需要理解面心立方结构、空位缺陷的概念，并能将这些概念与密度计算结合起来，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解面心立方结构、缺陷浓度、密度计算公式等多个概念，并进行多步计算和单位转换。虽然计算步骤较多，但每一步都较为直接，没有涉及复杂变量或高级数学工具。" + }, + { + "idx": 2699, + "question": "There is a glass containing soda, with a mass fraction of SiO2 at 80% and Na2O at 20%. Calculate the fraction of non-bridging O atoms.", + "answer": "According to the problem, assume there is 100g of glass, containing 80g of SiO2 and 20g of Na2O. First, calculate their molar fractions: The amount of SiO2 is 80/(28.09+2×16.00)=1.331(mol) ⇒ x_SiO2=80.47%. The amount of Na2O is 20/(2×22.99+16.00)=0.323(mol) ⇒ x_Na2O=19.53%. Now, using 100mol as the basis, then: 80.47SiO2 = 80.47Si + 160.94O 19.53Na2O = 39.06Na + 19.53O Since each Na+ produces one non-bridging oxygen ion, there are 39.06 non-bridging oxygen atoms, while the bridging oxygen atoms are: (160.94 + 19.53) - 39.06 = 141.41 The fraction of non-bridging oxygen atoms is then: 39.06/180.47 = 0.216", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及摩尔分数计算、原子数量统计以及比例计算等具体数值运算步骤。 | 知识层次: 题目需要进行多步计算，包括摩尔分数计算、氧原子分类和比例计算，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算非桥氧原子的比例，涉及摩尔分数计算、原子平衡和比例推导等多个步骤。虽然计算过程较为直接，但需要综合运用化学计量和玻璃结构知识，属于中等难度的计算题。" + }, + { + "idx": 2700, + "question": "Given the vibration frequency of atoms around a vacancy in Cu as 1×10¹³ s⁻¹, ΔEv as 0.15×10⁻¹⁸ J, and exp(ΔSm/k) approximately 1, calculate the migration frequency of vacancies at room temperature 27°C (300K).", + "answer": "ν=ν₀zexp(−ΔEv/kT)exp(ΔSm/k), ν₃₀₀=1×10¹³×12×exp(−0.15×10⁻¹⁸/(1.38×10⁻²³×300))×1=2.207×10⁻² s⁻¹", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体数值的代入和计算，最终给出一个具体的数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解空位迁移频率的计算方法，并正确应用给定的参数和公式进行计算。虽然公式直接给出，但需要正确代入数值并进行指数运算，涉及中等程度的认知能力和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用多个物理概念（振动频率、活化能、熵变）并进行多步计算（包括指数运算和单位转换）。虽然公式已给出，但需要正确理解每个参数的含义并准确代入数值，涉及中等深度的概念关联和综合分析能力。" + }, + { + "idx": 2701, + "question": "Given that the vibration frequency of atoms around a vacancy in Cu is 1×10¹³ s⁻¹, ΔEv is 0.15×10⁻¹⁸ J, and exp(ΔSm/k) is approximately 1, calculate the migration frequency of vacancies at 700K.", + "answer": "ν=ν₀zexp(−ΔEv/kT)exp(ΔSm/k), ν₇₀₀=1×10¹³×12×exp(−0.15×10⁻¹⁸/(1.38×10⁻²³×700))×1=2.165×10⁷ s⁻¹", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的公式和参数进行数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算，题目提供了所有必要的参数和公式，只需要直接套用给定的公式并进行简单的数值计算即可得出结果。虽然涉及指数运算，但整体步骤明确且无需额外的推导或组合多个公式。" + }, + { + "idx": 2702, + "question": "Calculate the actual packing density of α-Fe (given that for every 200 iron atoms there is 1 H atom, rFe=0.1241nm, rH=0.036nm, a=0.286nm)", + "answer": "K actual=8/3×π×(rFe³+rH³/200)/a³=8/3×π×((0.1241)³+(0.036)³/200)/(0.286)³=0.6845", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体的数学运算得出的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子半径的立方计算、比例换算以及最终密度的计算，涉及多个概念的综合应用，但不需要复杂的推理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算实际堆积密度，涉及原子半径、晶格常数和杂质原子的综合考量，但计算步骤相对明确，没有涉及复杂多变量或高阶数学处理。" + }, + { + "idx": 2703, + "question": "Calculate the actual density of α-Fe (given that for every 200 iron atoms there is 1 H atom, Ar(H)=1.008, a=0.286nm, NA=6.023×10²³)", + "answer": "ρ_actual=2×(Ar(Fe)+1/200×Ar(H))/(a³×NA)=2×(55.85+1.008/200)/((2.86×10⁻⁸)³×6.023×10²³)=7.9283(g/cm³)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及原子量、晶格常数和密度公式的使用，答案是一个具体的数值计算结果。 | 知识层次: 题目需要进行多步计算，包括原子质量的计算、单位转换（纳米到厘米）、密度公式的应用，以及考虑杂质原子（H）对密度的影响。这需要综合运用多个知识点并进行关联分析，但不需要进行复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要结合晶体结构、化学计量比和密度公式进行多步计算，涉及单位换算和综合分析，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2704, + "question": "To dissolve MgF2 into LiF, what type of vacancies (anion or cation) need to be introduced into LiF?", + "answer": "To dissolve MgF2 into LiF by replacing Mg2+ with Li+, anion vacancies must be introduced to balance the charge and maintain the original MgF2 structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述溶解MgF2到LiF中需要引入哪种类型的空位，答案提供了详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解溶解过程中的电荷平衡原理，并分析引入何种空位来维持结构稳定性，涉及多步概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解溶解过程中的电荷平衡原理，并能够综合分析引入空位的类型以维持结构稳定性。虽然涉及多步思考和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2705, + "question": "In a diffusion experiment of a certain crystal, it was found that at 500°C, 1 in 10^10 atoms had sufficient activation energy to jump out of their equilibrium positions and enter interstitial positions; at 600°C, this ratio increased to 10^9. Calculate the activation energy required for this jump.", + "answer": "The thermal activation process can generally be described by the famous Arrhenius equation. Let E be the energy required to form an interstitial atom, so the ratio of the number of atoms n with energy exceeding the average energy to the total number of atoms N is C = n/N = A e^(-E/kT), where A is the proportionality constant, k is the Boltzmann constant, and T is the absolute temperature. Taking the logarithm of both sides, we have ln C = ln A - E/kT. Solving the simultaneous equations gives ln 10^(-10) = ln A - E/(1.38×10^(-23)×773) and ln 10^(-9) = ln A - E/(1.38×10^(-23)×873). Thus, ln A = -2.92, E = 2.14×10^(-19) (J).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来求解激活能，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及对数运算和联立方程求解，同时需要理解热激活过程的基本原理。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题难度。题目需要应用Arrhenius方程进行多步计算，涉及对数运算、联立方程求解以及单位转换。虽然计算步骤明确，但需要综合运用热激活、玻尔兹曼常数等概念，并对温度单位进行转换（摄氏转开尔文）。相比简单代入公式的题目（等级2），本题需要更深入的概念理解和计算能力，但尚未达到复杂多变量计算（等级4）的程度。" + }, + { + "idx": 2706, + "question": "The density of $\\\\mathbf{M}_{\\\\mathbf{g}}\\\\mathbf{O}$ is $3.58\\\\:\\\\mathbf{g}/\\\\mathrm{cm}^{3}$, and its lattice constant is $0.42\\\\mathfrak{n m}$. Determine the number of Schottky defects per unit cell of $\\\\mathbf{M}_{\\\\mathbf{g}}\\\\mathrm{O}$.", + "answer": "Let the number of Schottky defects per unit cell be x. $$ \\\\rho{=}\\\\frac{(4-x)\\\\times\\\\left[A_{\\\\mathrm{r}}(\\\\mathrm{M}g)+A_{\\\\mathrm{r}}(\\\\mathrm{O})\\\\right]}{a^{3}N_{\\\\mathrm{A}}}$$ $$ x=4-{\\\\frac{\\\\rho\\\\alpha^{3}N_{\\\\mathrm{{A}}}}{A_{\\\\mathrm{{r}}}(\\\\mathrm{Mg})+A_{\\\\mathrm{{r}}}(\\\\mathrm{O})}}=4-{\\\\frac{3.58\\\\times(4.2\\\\times10^{-8})^{3}\\\\times6.023\\\\times10^{23}}{24.31+16.00}}=0.0369$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶格中的肖特基缺陷数量，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及密度、晶格常数、阿伏伽德罗常数等概念的综合应用，并需要理解Schottky缺陷的概念及其在晶体中的计算方法。虽然不涉及复杂的推理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶格常数概念、阿伏伽德罗常数以及原子量数据进行多步计算。虽然计算过程较为直接，但涉及多个物理概念的关联和综合分析，属于中等偏上的难度。" + }, + { + "idx": 2707, + "question": "If LiF is dissolved in MgF2, what type of vacancies (anion or cation) must be introduced into MgF2?", + "answer": "To dissolve LiF into MgF2, where Mg2+ replaces Li+, cation vacancies must be introduced because the valence charges of the replaced ion and the newly added ion must be equal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在溶解LiF到MgF2时需要引入特定类型的空位，答案提供了详细的文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解溶解过程中的离子替换机制，并分析价态平衡对空位形成的影响。这涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目需要多角度分析论述。首先，学生需要理解溶解过程中的离子替换机制，明确LiF和MgF2的晶体结构差异。其次，必须分析电荷平衡问题，考虑引入空位的类型（阴离子或阳离子）以维持电中性。此外，题目还涉及对离子价态和晶体缺陷的综合理解，要求学生在多个概念之间建立关联并进行逻辑推理。这些因素使得该题目在简答题中属于较高难度等级。" + }, + { + "idx": 2708, + "question": "At 700°C, what is the proportion of atoms with sufficient energy?", + "answer": "According to the Arrhenius equation, ln C = ln A - E/kT. Given ln A = -2.92, E = 2.14×10^(-19) J, k = 1.38×10^(-23) J/K, and T = 973 K. Substituting these values yields ln C = -2.92 - (2.14×10^(-19))/(1.38×10^(-23)×973). The calculation gives C = n/N = 6×10^(-9).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（C = n/N = 6×10^(-9)），符合计算题的特征。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及对数运算和指数转换，需要理解方程中各参数的含义及其相互关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用Arrhenius方程进行多步计算，涉及对数运算、单位转换和指数计算，但变量关系相对明确，没有过于复杂的推导过程。" + }, + { + "idx": 2709, + "question": "Given that Al has an fcc crystal structure with a lattice constant α=0.405 nm, and the vacancy concentration at 550°C is 2×10-6, calculate the average spacing between these vacancies if they are uniformly distributed in the crystal.", + "answer": "The number of lattice points in $1~\\\\mu\\\\mathrm m^{3}$ volume of Al is $$ N={\\\\frac{1}{a^{3}}}\\\\times4\\\\Rightarrow{\\\\frac{1}{(0.405\\\\times10^{-6})^{3}}}=6.021\\\\times10^{10}$$ Therefore, the number of vacancies in $1~\\\\mu\\\\mathrm m^{3}$ volume is $$ n_{V}=\\\\mathrm{CN}=6.021\\\\times10^{10}\\\\times2\\\\times10^{-6}=1.204\\\\times10^{5}$$ Assuming the vacancies are uniformly distributed in the crystal, the average spacing between them is $$ L=\\\\sqrt[3]{\\\\frac{1}{n_{v}}}=\\\\sqrt[3]{\\\\frac{1}{1.204\\\\times10^{5}}}=0.02025(\\\\mu\\\\mathrm{m})=20.25\\\\mathrm{nm}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的数学运算和单位转换，最终给出了具体的计算结果。 | 知识层次: 题目需要进行多步计算，包括晶格点数量计算、空位浓度应用以及平均间距的推导，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解fcc晶体结构、空位浓度概念，并进行多步计算（包括晶格点数量计算、空位数量计算和平均间距计算）。虽然计算步骤较多，但每个步骤都相对直接，没有涉及复杂变量或高级数学工具，因此属于该题型内的中等难度。" + }, + { + "idx": 2710, + "question": "Given that W at 20℃ has one vacancy per 10^23 unit cells, and each unit cell contains 2 W atoms, calculate the vacancy concentration C at 20℃.", + "answer": "C_20 = 1 / (2 × 10^23) = 5 × 10^-24.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以得出空缺浓度的具体数值。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要将给定的数值代入公式进行计算即可，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（空缺浓度=空缺数/总原子数）并进行简单数值计算，无需任何公式组合或复杂推导步骤。" + }, + { + "idx": 2711, + "question": "The activation energy required to form a vacancy in a certain crystal is 0.32×10^-18 J. At 800°C, there is one vacancy per 1×10^4 atoms. At what temperature will there be one vacancy per 10^3 atoms?", + "answer": "According to the Arrhenius equation: $$ \\\\ln{\\\\frac{n}{N}}=\\\\ln A-{\\\\frac{E}{{k}\\\\ T}}$$ Substituting the known conditions into the equation: $$ \\\\ln10^{-4}=\\\\ln A-\\\\frac{0.32\\\\times10^{-18}}{1.38\\\\times10^{-23}\\\\times1073}$$ We obtain: $$ \\\\ln A=12.4$$ And: $$ {\\\\bf{In}}10^{-3}=12.4-\\\\frac{0.32\\\\times10^{-18}}{1.38\\\\times10^{-23}\\\\times\\\\mathit{T}}.$$ Therefore: $$ \\\\operatorname{T}=1201\\\\operatorname{K}=928^{\\\\circ}{\\\\mathbb{C}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来求解温度，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及对数运算和温度转换，需要理解方程中各参数的含义及其相互关系，并进行综合分析。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范围。 | 难度: 在计算题中属于综合性计算问题，需要应用Arrhenius方程进行多步计算，涉及对数运算和温度转换，同时需要理解激活能和空位浓度的关系。虽然计算步骤明确，但需要较强的综合分析能力和数值计算技巧。" + }, + { + "idx": 2712, + "question": "When the temperature increases from 20℃ to 1020℃, the lattice constant expands by (4 × 10^-4)%, and the density decreases by 0.012%. Assuming the total mass remains unchanged, calculate the total volume change rate ΔV/V.", + "answer": "(1 + ΔV/V) × (1 - 0.00012) = 1 → ΔV/V ≈ 0.012%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解体积变化率ΔV/V，涉及百分比变化和密度与体积的关系计算，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要理解密度和体积之间的关系，并进行直接套用计算即可。不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要理解热膨胀和密度变化的基本概念，并应用简单的百分比变化公式进行计算。虽然涉及两个不同的物理量（晶格常数和密度），但计算步骤相对直接，不需要复杂的公式组合或高级数学技巧。" + }, + { + "idx": 2713, + "question": "For a cubic crystal with side length L, derive the volume change rate ΔV0/V0 due to thermal expansion when the temperature increases from T1 to T2.", + "answer": "ΔV0/V0 = (L + ΔL)^3 - L^3 / L^3 = 3 × (ΔL/L).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式推导和数值计算来求解体积变化率，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目要求应用基本的体积变化公式和热膨胀概念进行简单计算，涉及直接套用公式和一步推导，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求推导体积变化率，但实际只需应用线性热膨胀的基本概念（ΔL/L）并扩展到三维情况（3 × (ΔL/L)）。解题步骤仅涉及单一公式的简单变形和直接套用，无需复杂推导或多公式组合。" + }, + { + "idx": 2714, + "question": "The vacancy formation energy (E_v) and interstitial atom formation energy (E_i) of Al are 0.76 eV and 3.0 eV, respectively. Calculate the ratio of the equilibrium concentration of vacancies to the equilibrium concentration of interstitial atoms in Al at 500°C.", + "answer": "At 500°C: C_V/C_i = e^((1/(8.617×10^-5×773))(3.0-0.76)) = e^33.63 = 4.026×10^14", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及能量和浓度的计算，答案也是通过具体计算得出的数值结果。 | 知识层次: 题目需要应用缺陷形成能的基本概念，进行多步计算（温度转换、玻尔兹曼分布公式应用、指数运算），并理解空位与间隙原子平衡浓度比的计算原理。虽然不涉及复杂的机理分析，但需要综合运用多个知识点并进行数值计算。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式（如Arrhenius方程）并进行多步计算（温度转换、能量差计算、指数运算）。虽然计算步骤明确，但涉及概念关联和综合分析，对知识掌握深度和计算准确性要求较高。" + }, + { + "idx": 2715, + "question": "Solve the equations to find the vacancy formation energy Ev and entropy Sv.", + "answer": "Ev = 1.45 eV, Sv = 3.3 × 10^-4 eV.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过解方程来计算空位形成能Ev和熵Sv，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要解方程来计算空位形成能Ev和熵Sv，涉及多步计算和概念关联，需要理解相关公式并正确应用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（如能量和熵的计算）并进行多步计算。虽然涉及公式应用和数值计算，但步骤和变量数量尚未达到复杂多变量计算的程度。" + }, + { + "idx": 2716, + "question": "Assuming the vacancy concentration at T1 is negligible compared to T2, calculate the equilibrium vacancy concentration Cv at 1020℃.", + "answer": "Cv = ΔV0/V0 - ΔVa/Va = 3 × (ΔL/L - Δa/a) = (0.012% - 3 × 4 × 10^-4%) = 1 × 10^-4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算（包括温度比较、浓度计算和代数运算），并需要理解空位浓度的物理意义及其与温度的关系。虽然不涉及复杂的机理分析或创新设计，但需要综合应用多个概念和公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如空位浓度、晶格参数变化等），进行多步骤的计算和综合分析。虽然不涉及复杂多变量计算，但需要将不同物理量关联起来，属于中等偏上的难度。" + }, + { + "idx": 2717, + "question": "Using the vacancy concentrations at 20℃ and 1020℃, set up the equations to solve for the vacancy formation energy Ev and entropy Sv.", + "answer": "5 × 10^-24 = exp(Sv/k) × exp[-Ev/(293k)], 1 × 10^-4 = exp(Sv/k) × exp[-Ev/(1293k)].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的温度和空位浓度建立方程来求解空位形成能Ev和熵Sv，需要应用公式进行数值计算。答案给出了具体的方程形式，表明这是一个需要计算和公式应用的题目。 | 知识层次: 题目需要设置和求解关于空位形成能和熵的方程，涉及多步计算和概念关联，包括温度对空位浓度的影响以及相关公式的应用，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如空位浓度、形成能、熵）来建立方程，并进行多步骤的计算。虽然涉及多个变量和公式，但整体解题思路较为明确，属于中等应用层次的计算题。" + }, + { + "idx": 2718, + "question": "When the temperature decreases from 600°C to 300°C, the equilibrium vacancy concentration in $\\mathtt{Ge}$ crystal decreases by 6 orders of magnitude. Calculate the vacancy formation energy in the Ge crystal.", + "answer": "$$ \\\\begin{array}{r l}&{\\\\frac{C_{\\\\tau_{1}}}{C_{\\\\tau_{2}}}=\\\\frac{1}{10^{6}}=\\\\frac{A\\\\exp\\\\left(-\\\\frac{E_{\\\\mathrm{v}}}{k T_{1}}\\\\right)}{A\\\\exp\\\\left(-\\\\frac{E_{\\\\mathrm{v}}}{k T_{2}}\\\\right)}=\\\\mathrm{e}^{\\\\frac{\\\\varepsilon_{\\\\mathrm{v}}}{k}\\\\left(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\right)}-\\\\ln10^{6}}\\\\ &{\\\\qquad=\\\\frac{E_{\\\\mathrm{v}}}{\\\\frac{1}{k}\\\\left(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\right)}}\\\\ &{E_{\\\\mathrm{v}}=\\\\frac{-\\\\ln10^{6}}{\\\\frac{1}{873}-\\\\frac{1}{573}}=\\\\frac{-13,8\\\\times8,617\\\\times10^{-5}}{1.145\\\\times10^{-3}-1.745\\\\times10^{-3}}=1.98\\\\mathrm{(eV)}}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺形成能，答案中包含了详细的数学推导和计算过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解平衡空位浓度与温度的关系，并能够正确应用自然对数和指数函数进行转换。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用平衡浓度公式进行多步推导和计算，涉及对数运算和单位转换，但变量和计算步骤相对明确，没有过于复杂的多变量处理。" + }, + { + "idx": 2719, + "question": "Derive the volume change rate ΔVa/Va due to lattice constant expansion when the temperature increases from T1 to T2.", + "answer": "ΔVa/Va = (a + Δa)^3 - a^3 / a^3 = 3 × (Δa/a).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求推导体积变化率，涉及数值计算和公式应用，答案以数学表达式形式呈现 | 知识层次: 题目涉及基本的体积变化率计算，仅需应用简单的公式和代数运算，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（体积变化率公式）并进行简单代数运算（立方展开和近似处理），无需多步推导或复杂计算。题目明确给出了温度变化导致的晶格常数变化量Δa，解题过程仅需一步线性近似处理即可得到结果。" + }, + { + "idx": 2720, + "question": "If the positive direction of a dislocation line is defined as the original opposite direction, will the Burgers vector of this dislocation change?", + "answer": "According to the method of determining the Burgers vector of a dislocation by the Burgers circuit, the Burgers vector of this dislocation will reverse.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（即Burgers矢量是否会改变），答案直接给出了明确的判断结果（会反向），符合判断题的特征。 | 知识层次: 题目考查对Burgers向量基本概念的理解和记忆，涉及位错线方向改变时Burgers向量的变化情况，属于基础概念的记忆和简单应用。 | 难度: 在判断题中属于中等难度，需要理解Burgers矢量的定义和Burgers circuit方法，并能正确应用这些概念来判断方向改变对Burgers矢量的影响。虽然不涉及复杂的概念组合或分析，但需要一定的概念理解而非简单的记忆。" + }, + { + "idx": 2721, + "question": "If the positive direction of a dislocation line is defined as the original opposite direction, does the type and nature of the dislocation change?", + "answer": "The type and nature of this dislocation do not change.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个陈述的对错（\"does the type and nature of the dislocation change?\"），并且答案直接给出了明确的判断（\"do not change\"），符合判断题的特征。 | 知识层次: 题目考查对位错线方向定义及其对位错类型和性质影响的基本概念记忆和理解，不涉及复杂分析或应用。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆和理解位错线的定义及其性质是否随方向改变而变化。题目直接考察基础概念的记忆，无需复杂推理或分析，因此在判断题题型内属于最简单的难度等级。" + }, + { + "idx": 2722, + "question": "The vacancy formation energy (E_v) and interstitial atom formation energy (E_i) of Al are 0.76 eV and 3.0 eV, respectively. Calculate the ratio of the equilibrium concentration of vacancies to the equilibrium concentration of interstitial atoms in Al at room temperature (20℃).", + "answer": "At 20℃: C_V/C_i = e^((1/(8.617×10^-5×293))(3.0-0.76)) = e^88.72 = 3.395×10^38", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算空位与间隙原子平衡浓度比），需要使用给定的公式和参数（形成能、温度等），最终得出一个具体的数值结果。答案也展示了完整的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括温度转换、公式应用和指数运算，同时需要理解空位和间隙原子的平衡浓度概念及其与形成能的关系。虽然不涉及复杂的综合分析或机理解释，但超出了简单应用的范围，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式（空位形成能、间隙原子形成能、平衡浓度比计算），涉及温度单位转换（℃→K）和指数运算，同时要求对固体缺陷理论有清晰理解。虽然计算步骤明确，但综合了多个概念和计算环节，在同类计算题中属于中等偏上难度。" + }, + { + "idx": 2723, + "question": "Assume there is an edge dislocation with Burgers vector b in the [0-10] direction gliding along the (100) plane. If another edge dislocation with Burgers vector in the [010] direction moves through the (001) plane, will this dislocation form a kink or a jog when passing through the aforementioned dislocation?", + "answer": "Kink", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述两个位错相互作用时形成的是kink还是jog，答案需要文字说明而非简单选择或判断 | 知识层次: 题目要求分析两种位错在特定滑移面上的相互作用，并判断形成的是kink还是jog。这需要深入理解位错的性质、Burgers向量的方向、滑移面的选择以及位错交截的机制。涉及多个概念的关联和综合分析，思维过程较为复杂，属于对位错理论的深度应用和推理分析。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于复杂分析层次中的最高难度等级。原因如下：" + }, + { + "idx": 2724, + "question": "Assume there is an edge dislocation with a b in the [0-10] direction gliding along the (100) crystal plane. If a screw dislocation with a b direction of [100] gliding on the (001) crystal plane passes through the aforementioned dislocation, will it form a kink or a jog?", + "answer": "Jog", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两个选项（kink或jog）中选择正确答案，符合选择题的特征。 | 知识层次: 题目需要理解位错的基本概念（如刃位错和螺位错的性质和运动方式），并能够分析两种位错相互作用时的结果（形成kink还是jog）。这涉及到多个概念的关联和综合分析，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要综合理解位错运动、滑移面、柏氏矢量方向等概念，并分析两种位错相互作用时的几何关系。解题过程涉及多步空间想象和概念关联判断，属于复杂分析过程的判断题型。" + }, + { + "idx": 2725, + "question": "There are two left-handed screw dislocation lines, each with an energy of $E_{1}$. When they approach infinitely close, what is the total energy?", + "answer": "Since the strain energy of a dislocation is proportional to $b^{2}$, and the energies of like-signed screw dislocations are the same, their Burgers vectors must be identical. If they approach infinitely close and merge into a new dislocation with a Burgers vector of 2b, the total energy should be $4E_{1}$. However, in reality, this dislocation reaction cannot proceed because the energy increases after merging. Moreover, like dislocations repel each other, and the repulsive force between two like-signed dislocations will prevent them from approaching infinitely close.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目需要文字解释和论述，解答过程涉及对位错能量和相互作用的分析，而不仅仅是计算或选择正确答案。 | 知识层次: 题目需要理解位错的基本性质（如应变能与Burgers矢量的平方成正比），并分析两个同号位错接近时的能量变化和相互作用。这涉及到位错之间的相互作用机制和能量变化的综合分析，需要较高的推理分析和机理解释能力。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求综合运用位错理论、能量计算和反应机理的知识，不仅需要计算合并后的能量变化，还需要解释为什么这种合并在实际中不会发生。此外，题目还涉及到位错间的相互作用力分析，要求考生具备深入的理论基础和逻辑推理能力。这些要求使得该题目在同题型中属于最高难度等级。" + }, + { + "idx": 2726, + "question": "Are the types of dislocations the same at each point on a dislocation loop?", + "answer": "Judging by the angle between the dislocation line and the Burgers vector, if the Burgers vector of a dislocation loop is perpendicular to the dislocation line at each point on the loop, then the nature of the dislocations is the same at each point on the loop, all being edge dislocations; however, if the Burgers vector of the dislocation loop is parallel to the plane where the dislocation line lies, then some are pure edge dislocations, some are pure screw dislocations, and others are mixed dislocations; when the Burgers vector intersects the dislocation loop line at a certain angle, although each point on this dislocation loop is a mixed dislocation, the edge and screw components at each point are different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对位错环上各点位错类型是否相同进行解释和论述，答案提供了详细的文字说明和分析，符合简答题的特征。 | 知识层次: 题目要求分析位错环上各点位错类型的异同，涉及到位错线与伯格斯矢量之间角度的关系，需要综合运用位错的基本概念、分类以及不同类型位错的特征，进行推理分析和机理解释。这超出了简单记忆或直接应用的层次，属于较为复杂的综合分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对位错环上各点位错类型进行全面的机理分析，涉及布尔格斯矢量与位错线角度关系的多情景推理，需要综合运用位错理论并解释不同条件下的位错性质变化。其解题复杂度（需分三种情况讨论）和知识整合深度（需同时处理刃型、螺型及混合位错的转换关系）均达到该题型的最高要求标准。" + }, + { + "idx": 2727, + "question": "Indicate the nature types of the three dislocations in the dislocation reaction $$ \\frac{a}{2}[10\\overline{{{1}}}] + \\frac{a}{6}[\\overline{{{1}}}21] \\rightarrow \\frac{a}{3}[11\\overline{{{1}}}] $$?", + "answer": "Referring to the Thompson tetrahedron, this dislocation reaction corresponds to $\\begin{array}{r l r l r l r l r l}{{\\bf C}{\\bf A}}&{{}}&{+}&{{}{\\bf a}{\\bf C}}&{}&{{}\\searrow}&{}&{{\\bf a}{\\bf A}}\\end{array}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应的性质类型，答案提供了详细的文字解释和参考模型（Thompson tetrahedron），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据Thompson四面体分析位错反应的类型，需要理解位错反应的基本原理，并能将具体的位错矢量与Thompson四面体中的符号对应起来。这涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于较高难度，需要运用Thompson四面体模型进行多步分析，涉及位错反应的类型判断和符号转换，要求对晶体学方向和位错性质有较深理解，并能在三维空间中进行概念关联和综合分析。" + }, + { + "idx": 2728, + "question": "Calculate the dislocation density ρ when the shear strength is $42\\mathrm{MPa}$.", + "answer": "The dislocation density ρ can be calculated using the formula ρ = (τ̄/αGb)^2, where α is a constant (typically taken as 0.5). Substituting τ̄ = 42×10^6 Pa, G = 50×10^9 Pa, and b = 3.12×10^-10 m, we obtain ρ = (42×10^6 / (0.5×50×10^9×3.12×10^-10))^2 ≈ 7.3×10^12 m^-2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（dislocation density ρ）。答案中展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需代入已知数值进行计算即可。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用一个基本公式（ρ = (τ̄/αGb)^2）并进行简单的数值代入和计算，无需多个公式组合或复杂的推导步骤。" + }, + { + "idx": 2729, + "question": "Given that the lattice constant of a $\\\\mathrm{\\\\hat{Cu}}$ crystal is $a=0.35\\\\mathrm{nm}$, the shear modulus $G=4\\\\times10^{4}MPa$, and there is a dislocation with Burgers vector $\\\\pmb{\\\\mathscr{b}}==\\\\frac{a}{2}[\\\\overline{{1}}01]$, where the dislocation line direction is [-101], calculate the strain energy of this dislocation.", + "answer": "Based on the relationship between the Burgers vector and the dislocation line, it is known that this dislocation is a screw dislocation, and its strain energy is $$ \\\\begin{array}{r}{E=\\\\frac{G b^{2}}{4\\\\pi}\\\\mathrm{ln}\\\\frac{{R}}{r_{\\\\mathrm{0}}}}\\\\end{array}$$ $r_{0}\\\\approx b-{\\\\frac{\\\\sqrt{2}}{2}}a=0.707\\\\times0.35\\\\times10^{-6}=2.475\\\\times10^{-10}({\\\\mathrm{m}})$ $R{\\\\approx}1\\\\times10~^{\\\\circ}\\\\mathrm{m}$ $E={\\\\frac{4\\\\times10^{10}\\\\times(2.475\\\\times10^{-16})^{2}}{4\\\\pi}}\\\\ln{\\\\frac{10^{-2}}{2.475\\\\times10^{-10}}}=3.415\\\\times10^{-9}(\\\\mathrm{N}\\\\cdot\\\\mathrm{m}/\\\\mathrm{m})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶格常数、剪切模量、Burgers矢量等参数的计算，最终需要得出位错的应变能。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，包括确定位错类型（螺位错）、计算应变能公式的应用、以及相关参数的推导和计算。虽然不需要复杂的推理分析或创新应用，但需要综合运用材料科学中的位错理论和弹性力学知识进行中等难度的计算。 | 难度: 在计算题中属于综合性计算问题，需要理解位错的基本概念（如Burgers矢量、位错线方向等），正确判断位错类型（螺型位错），并应用应变能公式进行多步计算。虽然计算过程涉及对数运算和单位转换，但整体思路清晰，属于该题型内中等偏上的难度。" + }, + { + "idx": 2730, + "question": "In fcc, can the dislocation reaction $$ \\\\frac{a}{2}[10\\\\overline{{{1}}}] + \\\\frac{a}{6}[\\\\overline{{{1}}}21] \\\\rightarrow \\\\frac{a}{3}[11\\\\overline{{{1}}}] $$ proceed?", + "answer": "Dislocation reaction geometric condition: $b_{1}+b_{2}=\\\\Big(\\\\frac{1}{2}-\\\\frac{1}{6}\\\\Big)a+\\\\frac{2}{6}b+\\\\Big(-\\\\frac{1}{2}+\\\\frac{1}{6}\\\\Big)c=\\\\frac{1}{3}a+\\\\frac{1}{3}b-\\\\frac{1}{3}c=\\\\frac{a}{3}[11\\\\bar{1}]$ Energy condition: $\\\\left|{\\\\frac{a}{2}}{\\\\surd2}\\\\right|^{2}+\\\\left|{\\\\frac{a}{6}}{\\\\surd6}\\\\right|^{2}=\\\\Bigl({\\\\frac{a^{2}}{2}}+{\\\\frac{a^{2}}{6}}\\\\Bigr)>\\\\frac{a^{2}}{3}$ Therefore $\\\\frac{a}{2}[10\\\\overline{{{1}}}]+\\\\frac{a}{6}[\\\\overline{{{1}}}21]{\\\\rightarrow}\\\\frac{a}{3}[11\\\\overline{{{1}}}]$ The dislocation reaction can proceed.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目涉及位错反应的几何条件和能量条件的计算，需要通过数值计算和公式应用来验证反应是否可以进行。答案中包含了具体的数学运算和公式推导，符合计算题的特征。 | 知识层次: 题目涉及位错反应的几何条件和能量条件的计算，需要多步计算和综合分析，包括矢量运算和能量比较，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解位错反应的几何条件和能量条件，并进行多步计算和综合分析。虽然计算步骤较多，但涉及的变量和概念相对明确，属于中等应用层次。" + }, + { + "idx": 2731, + "question": "Given the stacking fault energy Y=0.01 J/m², shear modulus G=7 × 10^10 Pa, lattice constant α=0.3 nm, Poisson's ratio v=0.3 for an fcc crystal, determine the equilibrium separation distance between the two partial dislocations $\\frac{a}{6}[11\\vec{2}]$ and $\\frac{a}{6}[2\\overline{{{1}}}\\overline{{{1}}}]$.", + "answer": "$d_{\\mathrm{s}}\\approx\\frac{G b^{\\mathrm{2}}}{24\\pi\\gamma}$ $b{=}{\\frac{a}{n}}{\\sqrt{1^{2}+1^{2}+2^{2}}}{=}{\\frac{\\sqrt{6}}{6}}a,$ $$ d_{*}\\approx\\frac{7\\times10^{10}\\times\\frac{1}{6}\\times(0.3\\times10^{-9})^{2}}{24\\times3.1416\\times0.01}=1.3926\\times10^{-9}(\\mathrm{m})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数和公式进行数值计算，最终得出一个具体的数值结果。答案中包含了详细的公式推导和计算步骤，符合计算题的特征。 | 知识层次: 题目需要应用多个公式进行多步计算，包括计算伯格斯矢量、应用堆垛层错能公式等，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式和概念（如堆垛层错能、剪切模量、晶格常数、泊松比等），进行多步骤计算，包括伯格斯矢量的计算和最终平衡分离距离的推导。虽然计算过程较为直接，但涉及多个物理量的综合运用和单位转换，属于中等偏上的难度。" + }, + { + "idx": 2732, + "question": "The dislocation spacing of a Ni crystal is ${\\\\bf2000n m}$. Assuming each dislocation is caused by an additional (110) atomic plane, calculate the $\\\\pmb\\\\theta$ angle of the small-angle grain boundary.", + "answer": "The interplanar spacing of (110) is $d_{110}=\\\\frac{1}{2}\\\\times\\\\frac{\\\\alpha}{\\\\sqrt{1^{2}+1^{2}+0}}=\\\\stackrel{0.35238}{2\\\\sqrt{2}}=0.1246(\\\\mathrm{nm})$. $$ \\\\sin\\\\frac{\\\\theta}{2}=\\\\frac{d_{110}}{\\\\cal{I}}=\\\\frac{0.1246}{2000}=6.23\\\\times10^{-5},$$ $$ \\\\theta{=0.003569527^{\\\\circ}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的数学运算和物理公式的使用，最终得出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的位错间距和晶面间距计算小角度晶界的角度。虽然需要理解位错和晶界的基本概念，但整体上是一个直接的公式套用和数值计算过程，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（小角度晶界公式）并进行简单数值计算。题目明确给出了所有必要参数（位错间距和晶面间距），无需额外推导或组合多个公式。解题步骤仅涉及代入数值和基本三角函数运算，属于该题型中最基础的直接计算类型。" + }, + { + "idx": 2733, + "question": "Can the new dislocation generated by the dislocation reaction $$ \\\\frac{a}{2}[10\\\\overline{{{1}}}] + \\\\frac{a}{6}[\\\\overline{{{1}}}21] \\\\rightarrow \\\\frac{a}{3}[11\\\\overline{{{1}}}] $$ move on the slip plane?", + "answer": "The dislocation line of the new dislocation $\\\\frac{a}{3}[11\\\\overline{{{1}}}]$ is located at the intersection of (111) and (111) planes on the (001) plane, and it is a pure edge dislocation. Since the (001) plane is a non-close-packed plane in fcc, it cannot move and is a fixed dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释新生成的位错是否能在滑移面上移动，答案提供了详细的文字解释和论述，说明位错线的位置和性质，并得出结论。这符合简答题的特征，即需要文字解释和论述。 | 知识层次: 题目涉及位错反应、位错类型判断、滑移面分析以及晶体结构知识的综合运用，需要深入理解位错的性质和运动机制，并进行推理分析。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求综合运用位错反应、滑移面分析、晶体结构知识，并进行推理分析来解释新位错能否在滑移面上移动。需要深入理解位错性质、滑移机制以及面心立方晶体结构特点，解题步骤复杂，对知识掌握深度和综合分析能力要求较高。" + }, + { + "idx": 2734, + "question": "In an aluminum specimen, the dislocation density within the grains was measured to be 5×10^9/cm². Assuming all dislocations are concentrated on the subgrain boundaries; each subgrain has a regular hexagonal cross-section. The misorientation angle between subgrains is 5°, and if all dislocations are edge dislocations with b = a/2 [101], the magnitude of the Burgers vector is equal to 2×10^-10 m. Calculate the dislocation spacing on the subgrain boundary.", + "answer": "D = b / (2 sin(θ/2)) ≈ b / θ = (2×10^-10) / 0.087 = 23×10^-10 m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，最终得出一个具体的数值结果。答案是通过一系列计算步骤得出的，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用Burgers矢量和位错间距的关系公式，以及角度转换和数值计算。虽然不涉及复杂的综合分析或机理解释，但需要理解位错密度、Burgers矢量和位错间距之间的关联，并进行适当的数学运算。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（如位错密度、位错类型、Burgers向量、亚晶界取向差角等）并进行多步计算。虽然公式应用明确，但涉及参数转换和角度近似处理，对材料科学基础知识的掌握和计算能力有一定要求。" + }, + { + "idx": 2735, + "question": "If this stress determines the shear strength of the material, to achieve a strength value of $\\\\frac{G}{100}$, and given that $G=50\\\\mathrm{GPa}$, $a=0.36\\\\mathrm{nm}$, what should the value of $D$ be?", + "answer": "According to $\\\\overline{\\\\tau} = \\\\frac{G}{100}$, substituting $\\\\overline{\\\\tau} = \\\\frac{Gb}{D}$ yields $D = 100b$. The Burgers vector $b = \\\\frac{a\\\\sqrt{3}}{2} = \\\\frac{0.36\\\\times10^{-9}\\\\times\\\\sqrt{3}}{2} \\\\approx 3.12\\\\times10^{-10}\\\\mathrm{m}$, therefore $D = 100\\\\times3.12\\\\times10^{-10} = 3.12\\\\times10^{-8}\\\\mathrm{m}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解D的值，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的数值代入公式进行计算，并理解Burgers向量的概念。虽然涉及多步计算，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求直接套用已知公式$\\overline{\\tau} = \\frac{Gb}{D}$，并进行简单的代数变换和数值计算。虽然需要计算Burgers向量b的值，但这只是一个简单的几何计算步骤。整体解题过程仅涉及一个主要公式的直接应用和简单计算，没有复杂的推导或多步骤运算，因此属于等级2难度。" + }, + { + "idx": 2736, + "question": "The lattice constant of a copper single crystal is $a=0.36\\\\mathfrak{n m}$. When the copper single crystal sample is subjected to tensile deformation at a constant strain rate, the true strain of the sample is $6\\\\%$ after $\\\\mathtt{3s}$. If the average velocity of dislocation motion is $4\\\\times10^{-3}~\\\\mathrm{cm/s}$, calculate the average dislocation density in the crystal.", + "answer": "① The two nodes in the dislocation network and the dislocation segments between them can act as F-R sources, and the shear stress required for dislocation multiplication is the minimum shear stress required to activate the F-R source; $$ D=\\\\frac{G b}{\\\\tau}$$ ② $$ D=\\\\frac{G b}{\\\\tau}=\\\\frac{G b}{\\\\frac{G}{100}}=100b=100~\\\\frac{\\\\sqrt{2}}{2}a=25.5\\\\left(\\\\mathrm{nm}\\\\right)$$ ③ For a three-dimensional dislocation network $$ \\\\rho={\\\\frac{2}{D^{2}}}=2\\\\left({\\\\frac{\\\\tau}{G b}}\\\\right)^{2}=2\\\\left({\\\\frac{42\\\\times10^{6}}{50\\\\times10^{8}\\\\times2.55\\\\times10^{-8}}}\\\\right)^{2}=2.17\\\\times10^{9}{\\\\mathrm{cm}}^{-2}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解平均位错密度，答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，包括应变、位错运动速度、位错密度等材料科学中的核心概念。需要综合运用这些概念和公式进行计算，但不需要进行复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及晶体学参数、应变率、位错运动速度等多个变量，并要求综合应用Frank-Read源激活条件、位错密度公式等知识进行推导和计算。虽然计算步骤明确，但需要正确理解物理概念并准确应用公式，属于中等偏上的难度。" + }, + { + "idx": 2737, + "question": "The average distance between nodes of the entangled three-dimensional dislocation network in a copper single crystal is $D$. Calculate the stress $\\overline{\\tau}$ required for dislocation multiplication.", + "answer": "The stress $\\overline{\\tau}$ required for dislocation multiplication can be calculated by the formula $\\overline{\\tau} = \\frac{Gb}{D}$, where $G$ is the shear modulus and $b$ is the Burgers vector of the dislocation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式进行数值计算，解答过程涉及具体的物理量（剪切模量G、Burgers矢量b）和数学运算，属于典型的计算题类型。 | 知识层次: 题目要求直接应用公式$\\overline{\\tau} = \\frac{Gb}{D}$进行计算，属于基本公式的直接套用，不需要多步计算或复杂分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式$\\overline{\\tau} = \\frac{Gb}{D}$进行计算，无需任何公式组合或复杂推导步骤。题目明确给出了所有必要参数（G、b、D）的物理意义，计算过程仅涉及基本代数运算，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 2738, + "question": "In an aluminum sample, the dislocation density inside the grains is measured to be 5×10^9/cm². Assuming all dislocations are concentrated on the subgrain boundaries; each subgrain has a regular hexagonal cross-section. The misorientation angle between subgrains is 5°, and if all dislocations are edge dislocations, with b = a/2 [101], where the magnitude of the Burgers vector equals 2×10^-10 m, calculate the average size of the subgrains.", + "answer": "The area of a regular hexagon S = (3/2)√3 a², and the total perimeter is 6a. The number of subgrains per unit area n = 1/S. The dislocation density ρ = 5×10^13 = (1/S) × 6a × (1/D) × (1/2). Solving gives a = 1×10^-5 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解亚晶粒的平均尺寸，答案中包含了具体的计算过程和数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用位错密度、亚晶界结构、位错类型和Burgers矢量等知识，并进行数值计算和公式推导。虽然不涉及复杂的机理解释或创新设计，但需要一定的综合分析能力。 | 难度: 在计算题题型中，该题目属于综合性计算问题。题目要求进行多步计算，包括几何面积计算、单位转换、密度公式应用等。虽然涉及多个概念（如位错密度、亚晶界、伯格斯矢量等），但计算步骤相对明确，没有涉及复杂多变量或高阶数学工具。在同类计算题中属于中等偏上难度，符合等级3\"综合性计算问题\"的标准。" + }, + { + "idx": 2739, + "question": "If an extra (111) plane is embedded, causing a small-angle grain boundary tilted by 1° in α-Fe, calculate the average distance between the dislocations.", + "answer": "The lattice constant of α-Fe crystal $$ \\\\alpha=\\\\frac{4r_{\\\\mathrm{Fe}}}{\\\\sqrt{3}}=\\\\frac{4\\\\times0.1241}{\\\\sqrt{3}}=0.2866(\\\\mathrm{nm})$$ $$x d_{111}={\\\\frac{a}{\\\\sqrt{{{1}}^{2}+{{1}}^{2}+{{1}}^{2}}}}={\\\\frac{0.2866}{\\\\sqrt{3}}}=0.16547({\\\\mathrm{nm}})$$ $$ \\\\sin{\\\\frac{\\\\theta}{2}}={\\\\frac{d_{\\\\mathrm{{111}}}}{\\\\it{l}}}$$ $$ \\\\begin{array}{r}{\\\\lambda=\\\\frac{d_{\\\\mathrm{{n1}}}}{\\\\sin\\\\frac{\\\\theta}{2}}=\\\\frac{0.16547}{\\\\sin\\\\left(\\\\frac{1}{2}\\\\right)^{\\\\circ}}=18.9615(\\\\mathrm{nm})}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶格常数计算、晶面间距计算以及三角函数的应用，涉及多个概念的综合运用和关联分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式进行多步计算，包括晶格常数计算、晶面间距计算以及小角度晶界位错间距的计算。虽然涉及的概念和计算步骤较多，但整体思路清晰，属于中等应用层次的计算题。" + }, + { + "idx": 2740, + "question": "To achieve homogeneous nucleation at 2045K, by how much must the atmospheric pressure be increased? Given the volume change during solidification ΔV= -0.26 cm^3/mol (1J=9.87×10^6 cm^3·Pa)", + "answer": "For homogeneous nucleation to occur at 1726K, an undercooling of 319°C is required. To achieve this, the pressure must be increased to raise the solidification temperature of pure nickel from 1726K to 2045K: dP/dT=ΔH/TΔV. Integrating this equation: ∫1.013×10^5^P dP=∫1726^2045 ΔH/TΔV dT P-1.013×10^5=ΔH/ΔV ln2045/1726=18075/0.26×9.87×10^5×ln2045/1726=116366×10^5(Pa). Thus, when P=116366×10^5-1.013×10^5=116365×10^5(Pa), homogeneous nucleation can occur at 2045K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如dP/dT=ΔH/TΔV的积分计算）来确定需要增加的大气压力值，答案给出了具体的计算过程和最终数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用热力学公式（dP/dT=ΔH/TΔV）并进行积分运算，同时需要理解均匀成核的条件和压力对凝固温度的影响。虽然计算过程较为复杂，但主要基于已有公式和已知条件进行推导，不需要进行创新或深度分析。 | 难度: 在计算题中属于复杂多变量计算难度，需要运用热力学公式进行多步积分运算，涉及压力、温度、体积变化等多个变量的综合计算，同时要求对物理概念有深入理解并正确应用单位换算。解题过程包含公式推导、积分运算和数值计算，步骤复杂且容错率低。" + }, + { + "idx": 2741, + "question": "It is known that liquid pure nickel undergoes homogeneous nucleation at an undercooling of 319°C under 1.013×10^5 Pa (1 atm). Given the critical nucleus radius as 1 nm, the melting point of pure nickel as 1726 K, the heat of fusion Lm = 18075 J/mol, and the molar volume V = 6.6 cm^3/mol, calculate the liquid-solid interfacial energy and the critical nucleation work for pure nickel.", + "answer": "Since r* = 2σ/ΔGv = 2σTm/LmΔT = 2σTm V/ΔHmΔT, and for solidification, ΔGv = LmΔT/Tm, thus σ = r*ΔGv/2V = r*ΔHmΔT/2VTm = 1×10^-7 × 18075 × 319 / 2 × 1726 × 6.6 = 2.53×10^-5 (J/cm^2) = 0.253 (J/m^2). ΔG* = 16πσ^3Tm^2Vs^2 / 3ΔHm^2ΔT^2 = 16 × 3.14 × (2.53×10^-5)^3 × 1726^2 × 6.6^2 / 3 × 18075^2 × 319^2 = 1.06×10^-18 (J).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数和公式进行数值计算，最终得出液体-固体界面能和临界成核功的具体数值。答案展示了详细的公式推导和计算过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解临界核半径与界面能的关系，以及临界成核功的计算。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个已知参数进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式并进行多步计算。题目涉及临界核半径、液固界面能、临界成核功等多个概念的综合运用，计算过程较为复杂，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2742, + "question": "Explain why polymers crystallized at lower temperatures have a wider melting range, and vice versa.", + "answer": "When polymers crystallize at lower temperatures, the mobility of molecular chains is poor, resulting in less perfect crystals with a greater variation in perfection. Crystals with more defects will melt at lower temperatures, while those with fewer defects will melt at higher temperatures, leading to a wider melting range. Conversely, when polymers crystallize at higher temperatures, the mobility of molecular chains is stronger, resulting in more perfect crystals with less variation in perfection. Therefore, the melting range is narrower.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物在不同温度下结晶时熔融范围变化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释聚合物结晶温度与熔融范围之间的关系，涉及分子链的移动性、晶体完美度变化以及缺陷对熔融行为的影响。这需要综合运用多个概念，进行推理分析和机理解释，思维过程较为深入。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求解释聚合物在不同温度下结晶时熔融范围变化的机理，需要综合运用高分子结晶理论、分子链运动性以及晶体缺陷等知识进行推理分析。虽然不涉及多因素交互作用的复杂现象全面分析（等级5），但需要对结晶温度与晶体完美度、熔融行为之间的内在关系进行深入解释，属于较高层次的机理阐述题。" + }, + { + "idx": 2743, + "question": "Calculate the axial ratio c/a of an ideal close-packed hexagonal crystal structure", + "answer": "c/a=√(8/3)=1.633", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算轴向比c/a），并给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目要求应用基本公式进行简单计算，直接套用理想密排六方晶体结构的轴向比公式，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（c/a=√(8/3)）进行简单数值计算，无需任何推导或组合公式步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2744, + "question": "Indicate the close-packed plane of an ideal hexagonal close-packed crystal structure", + "answer": "The close-packed plane is {0001}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出密排面，答案需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对理想六方密堆积晶体结构中密排面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答类型。题目仅要求指出理想六方密堆积晶体结构的密排面，答案直接给出{0001}晶面，无需额外解释或复杂推导。这属于最基础的概念记忆性知识，符合等级1的难度标准。" + }, + { + "idx": 2745, + "question": "Calculate the change in the melting point of tin when the pressure increases to $500\\\\times10^{5}\\\\mathbf{Pa}$. It is known that at $\\\\mathfrak{10}^{5}\\\\mathbf{Pa}$, the melting point of tin is $505~\\\\mathrm{K}$, the heat of fusion is $7196\\\\mathrm{J/mol}$, the molar mass is $118.8\\\\times10^{-3}~\\\\mathrm{kg/mol}$, the density of solid tin is $\\\\small7.30\\\\times10^{3}~\\\\mathrm{kg/m^{3}}$, and the volume change during melting is $+2.7\\\\%$.", + "answer": "The molar volume of tin $$ V_{\\\\mathrm{m}}={\\\\mathrm{molar mass}}/\\\\mathrm{density}={\\\\frac{118.7\\\\times10^{-3}}{7.30\\\\times10^{3}}}=1.626\\\\times10^{-5}(\\\\mathrm{m}^{3}/\\\\mathrm{mol})$$ $$ \\\\begin{array}{r}{\\\\Delta V_{\\\\mathrm{m}}=0.027\\\\times1.626\\\\times10^{-5}}\\\\\\\\ {=4.39\\\\times10^{-7}\\\\left(\\\\mathrm{m}^{3}/\\\\mathrm{mol}\\\\right)}\\\\end{array}$$ Assuming $\\\\Delta V_{\\\\mathfrak{m}}$ and $\\\\Delta H_{\\\\pmb{\\\\upmu}}$ remain constant within the considered temperature range, and $\\\\Delta T{\\\\ll}T$ $$ \\\\begin{array}{c}{{\\\\frac{\\\\Delta\\\\phi}{\\\\Delta T}=\\\\frac{\\\\Delta H_{\\\\mathrm{m}}}{T\\\\cdot\\\\Delta V_{\\\\mathrm{m}}}=\\\\frac{7196}{505\\\\times4.39\\\\times10^{-7}}}}\\\\\\\\ {{=3.25\\\\times10^{7}(\\\\mathrm{N}\\\\cdot\\\\mathrm{m}^{-2}\\\\cdot\\\\mathrm{K}^{\\\\mathrm{\\\\Delta_{\\\\parallel}}})}}\\\\end{array}$$ Then $$ \\\\Delta T={\\\\frac{(500-1)\\\\times10^{5}}{3.25\\\\times10^{7}}}=1.54(\\\\mathrm{K})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及多个步骤的数学运算和物理公式的使用，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括摩尔体积的计算、体积变化的计算、熔点变化公式的应用等，涉及多个概念的综合运用和关联分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用多个物理概念（如摩尔体积、热力学关系）并进行多步计算。题目涉及压力对熔点的影响，需要理解克拉珀龙方程并正确代入数值。虽然计算步骤较多，但每个步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 2746, + "question": "Determine the solidification velocity $R$ required to maintain a planar liquid-solid interface during directional solidification of an 8% B binary alloy. Given the temperature gradient $G=225^{\\\\circ}C$/cm, the diffusion coefficient of component B $D=2\\\\times10^{-4}$ cm²/s, the equilibrium partition coefficient $\\\\pmb{k}_{0}=0.3$, and the slope of the binary alloy liquidus line $m=0.142^{\\\\circ}C$/%, which means the temperature decreases by $0.142^{\\\\circ}C$ for every 1% increase in B solute concentration.", + "answer": "nan", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（温度梯度、扩散系数、分配系数、液相线斜率）进行数值计算，以确定维持平面液固界面所需的凝固速度。解答过程需要应用相关公式和计算步骤，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及温度梯度、扩散系数、平衡分配系数和液相线斜率等多个参数的关联应用，需要综合分析这些参数对凝固速度的影响，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如温度梯度、扩散系数、平衡分配系数、液相线斜率等），进行多步计算和综合分析。虽然不涉及复杂多变量计算，但需要将多个参数关联起来求解固液界面保持平面所需的凝固速度，属于中等应用层次的计算题。" + }, + { + "idx": 2747, + "question": "What is the experimental method for determining the critical resolved shear stress of a crystal?", + "answer": "Experimental method: 1) Select an appropriate orientation in the single crystal to ensure that the initial slip of the crystal is single slip. 2) Determine the orientation of the crystal's tensile direction to obtain the orientation factor. 3) Use τc=σscosφcosλ and the σs from the tensile curve, along with the orientation factor, to calculate the τs, the type of crystal, purity, test temperature, strain rate, and other factors affecting the resolved shear stress τc value.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释实验方法，答案提供了详细的步骤和论述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释实验方法并涉及多步计算和概念关联，如选择晶体取向、确定取向因子、使用公式计算临界分切应力等，需要综合分析不同因素对结果的影响。 | 难度: 在简答题中属于较高难度，需要多角度分析论述。题目要求详细描述实验方法，包括晶体取向的选择、取向因子的确定、计算公式的应用，以及影响因素的考虑。解题步骤较为复杂，涉及多个概念的综合运用和关联分析，对学生的理解深度和综合分析能力要求较高。" + }, + { + "idx": 2748, + "question": "In a copper crystal, when the a/2[101] dislocation on the (111) plane reacts with the a/2[011] dislocation on the (11-1) plane, write the dislocation reaction equation and determine the direction of the reaction.", + "answer": "[101]+[011]a2/2+a2/2>a2/2 , the reaction proceeds to the right", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出位错反应方程并确定反应方向，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求写出位错反应方程并确定反应方向，这需要理解位错的基本概念（如柏氏矢量、位错线方向）以及位错反应的规则。虽然涉及基础概念，但需要将这些概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识、位错反应原理和矢量运算能力。解题步骤包括：(1)正确识别位错柏氏矢量 (2)理解不同滑移面的空间关系 (3)进行矢量叠加计算 (4)判断反应方向性 (5)用专业术语规范表述。整个过程涉及多个概念关联和综合分析，比单纯记忆性简答要求更高，但尚未达到需要深度关联性分析的等级5水平。" + }, + { + "idx": 2749, + "question": "The $c/a$ ratio for an ideal hexagonal close-packed metal is ", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（B） | 知识层次: 题目考查对理想六方密堆积金属的$c/a$比值的记忆，属于基础概念的记忆性知识 | 难度: 在选择题的基础概念记忆层次中，该题目属于最简单的等级。只需要直接记忆理想六方密堆积金属的c/a比值（√8/3≈1.633）即可作答，不需要任何概念辨析或复杂理解过程。这是典型的定义性知识点的直接考查。" + }, + { + "idx": 2750, + "question": "Indicate the close-packed directions of an ideal hexagonal close-packed crystal structure", + "answer": "The close-packed directions are (11-20)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出理想六方密堆积晶体结构的密排方向，答案需要提供具体的晶体学方向（11-20），这属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对理想六方密堆积晶体结构中密排方向的基本概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求指出密排方向，不需要进行概念解释或复杂体系阐述，只需记忆并准确写出HCP结构的密排方向(11-20)即可。这属于最基础的概念记忆性知识，解题步骤简单直接，符合等级1的基本特征。" + }, + { + "idx": 2751, + "question": "In a copper crystal, when the a/2[101] dislocation on the (111) plane reacts with the a/2[011] dislocation on the (11-1) plane, describe the nature of the new dislocation.", + "answer": "The new dislocation b=a/2[110] is a unit dislocation in the face-centered cubic structure; the direction of the dislocation line is along the intersection line [110] of the two crystal planes (111) and (111), so the dislocation is of edge type; the slip plane is (001), which is not a close-packed plane, hence it is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述新位错的性质，答案提供了详细的文字解释和论述，包括位错类型、方向和滑移面等特征，符合简答题的特点。 | 知识层次: 题目要求分析位错反应后新位错的性质，涉及位错线方向、滑移面判断以及位错类型的确定，需要综合运用位错理论、晶体几何和材料力学知识，进行多步骤推理和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体结构、位错反应和滑移系统等多方面知识，进行机理深度解释和复杂现象全面分析。具体表现为：" + }, + { + "idx": 2752, + "question": "Cesium chloride (CsCl) has an ordered body-centered cubic structure, which belongs to (A) body-centered cubic lattice (B) face-centered cubic lattice (C) simple cubic lattice", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体结构分类的基本概念记忆，只需识别CsCl的晶体结构类型即可作答，不涉及复杂分析或计算。 | 难度: 在选择题中属于中等难度，需要理解CsCl的结构类型并进行简单辨析。虽然题目涉及的是基础概念记忆，但需要区分body-centered cubic结构和simple cubic lattice的区别，不能仅靠简单记忆直接得出答案。" + }, + { + "idx": 2753, + "question": "The [001] direction in a cubic crystal is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项字母形式给出 | 知识层次: 题目考查对立方晶体中[001]方向的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需识别和记忆立方晶体中[001]方向的基本概念，无需进行复杂辨析或深度理解。" + }, + { + "idx": 2754, + "question": "In the hexagonal crystal system, the interplanar spacing of (11-20) plane is (1010) plane spacing.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（A） | 知识层次: 题目考查六方晶系中晶面间距的基本概念记忆，属于晶体学基础知识的直接应用，无需复杂计算或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解六方晶系中晶面间距的基本概念，并能简单辨析(11-20)和(1010)晶面的关系。虽然涉及晶面指数的理解，但不需要复杂的计算或深度推导，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 2755, + "question": "In a crystal, the defect formed by creating a vacancy while simultaneously generating an interstitial atom is called", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（答案：B） | 知识层次: 题目考查晶体缺陷的基本概念记忆，即Frenkel缺陷的定义，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，虽然需要理解晶体缺陷的基本概念（空位和间隙原子），但题目描述直接对应\"Frenkel defect\"这一特定术语，属于基础概念记忆范畴。相比等级1的直接名词识别题稍复杂，但不需要进行多概念比较分析。" + }, + { + "idx": 2756, + "question": "Fick's first law describes the characteristics of steady-state diffusion, where the concentration does not vary with . \\n\\n(A) distance (B) time (C) temperature", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)中选择正确答案 | 知识层次: 题目考查Fick第一定律的基本概念记忆，要求识别稳态扩散中浓度不随时间变化的特性，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆Fick第一定律的基本定义，即稳态扩散中浓度不随时间变化。无需进行概念辨析或复杂理解，属于基础概念识别的范畴。" + }, + { + "idx": 2757, + "question": "The ordered structure formation temperature of any alloy is _____ the disordered structure formation temperature. (A) Lower than (B) Higher than (C) May be lower or higher than", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查合金有序结构和无序结构形成温度的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解有序结构和无序结构形成的温度关系这一基本概念，并进行简单辨析。虽然不涉及复杂概念的区分，但需要一定的知识掌握深度，而非简单的概念识别。" + }, + { + "idx": 2758, + "question": "The twinning plane of a face-centered cubic crystal is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项C作为答案 | 知识层次: 题目考查面心立方晶体孪晶面的基本概念记忆，属于晶体学中的基础定义性知识，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解面心立方晶体的孪晶面概念，并进行简单辨析。虽然不涉及复杂概念的区分，但需要一定的晶体学基础知识。" + }, + { + "idx": 2759, + "question": "There is a dislocation loop on the crystal slip plane, and a shear stress $\\\\boldsymbol{\\\\tau}$ is applied in the direction of its Burgers vector. What is the minimum radius required for the dislocation loop to remain stable in the crystal?", + "answer": "The force acting on the ds arc segment of the dislocation line: $\\\\pmb{\\\\tau}\\\\cdot\\\\pmb{b}\\\\cdot\\\\mathbf{d}\\\\mathscr{s}.$ At the same time, the line tension on the dislocation line: $T{\\\\approx}\\\\alpha\\\\cdot G\\\\cdot b^{2}$ , where the horizontal component: $2(\\\\alpha G b^{2})\\\\sin\\\\frac{\\\\mathrm{d}\\\\theta}{2}$ Thus, $$ \\\\mathrm{d}s=r\\\\mathrm{d}{\\\\theta},\\\\sin\\\\frac{\\\\mathrm{d}\\\\theta}{2}\\\\approx\\\\frac{\\\\mathrm{d}\\\\theta}{2}$$ When the two forces reach equilibrium, they are equal, i.e., Therefore, $$ \\\\begin{array}{c}{{\\\\tau\\\\bullet b\\\\bullet\\\\mathrm{d}s=2(a G b^{2}){\\\\frac{\\\\mathrm{d}\\\\theta}{2}}}}\\\\\\\\ {{\\\\tau\\\\bullet b\\\\bullet r_{c}\\\\bullet\\\\mathrm{d}\\\\theta=a G b^{2}\\\\mathrm{d}\\\\theta}}\\\\\\\\ {{r_{\\\\bullet}={\\\\frac{a G b}{\\\\tau}}}}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算位错环在晶体中保持稳定的最小半径，答案通过公式推导和数值计算得出，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错环的稳定性条件，应用线张力和剪切应力的平衡关系，进行公式推导和综合分析。虽然不涉及复杂的推理分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解位错环的受力平衡条件，应用线张力公式，并进行多步推导计算。题目涉及晶体位错的基本概念、受力分析和平衡条件建立，解题过程需要综合运用多个知识点和数学推导步骤，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2760, + "question": "In a body-centered cubic structure, can a dislocation with Burgers vector $a[100]$ decompose into $\\frac{a}{2}[111]+\\frac{a}{2}[1\\overline{1}\\overline{1}]$? (A) No (B) Yes (C) Possible", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目提供了多个选项（A、B、C），要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目涉及位错分解的矢量分析，需要理解体心立方结构中位错的Burgers矢量分解规则，并进行矢量运算验证。这需要综合运用晶体结构、位错理论和矢量运算的知识，属于复杂分析层次。 | 难度: 在选择题的复杂分析题型中，该题目属于深度推理判断难度。题目要求考生不仅掌握体心立方结构中位错的基本概念，还需要深入理解Burgers矢量的分解原理和晶体学限制条件。解题过程涉及多个步骤的推理分析：1) 验证矢量分解的数学可行性；2) 判断分解后的部分位错是否符合晶体学能量条件；3) 考虑体心立方结构的滑移系限制。这种需要综合运用晶体缺陷理论和矢量运算能力的题目，在同题型中属于最高难度等级。" + }, + { + "idx": 2761, + "question": "In substitutional solid solutions, the general mode of atomic diffusion is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项标记（C）作为答案 | 知识层次: 题目考查的是置换固溶体中原子扩散的一般模式，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解\"置换固溶体\"和\"原子扩散\"的基本概念，并能将两者联系起来。虽然不涉及复杂计算或多步骤推理，但需要一定的概念辨析能力，比单纯记忆定义稍难。" + }, + { + "idx": 2762, + "question": "The condition for an alloy to develop constitutional supercooling during solidification is . (where $T_{\\\\ L}$ is the solidification start temperature of the alloy with composition $C_{\\\\mathrm{L}}$)", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案，符合选择题的特征。 | 知识层次: 题目考查合金凝固过程中成分过冷条件的判断，需要理解成分过冷的概念及其与合金凝固温度梯度的关系，属于中等应用层次的知识点。虽然不涉及复杂计算，但需要综合分析合金成分和温度场的关系。 | 难度: 在选择题中属于较高难度，需要理解合金凝固过程中的多个概念（如成分过冷、凝固起始温度等），并综合分析温度梯度和成分分布的关系。题目要求考生能够将理论知识与实际凝固条件联系起来，进行较为复杂的判断分析。" + }, + { + "idx": 2763, + "question": "The driving force for atomic diffusion is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项字母形式给出 | 知识层次: 题目考查原子扩散驱动力的基本概念记忆，属于定义和基本原理的记忆性知识 | 难度: 在选择题中属于简单难度，仅需直接记忆基础概念（原子扩散的驱动力）即可作答，无需理解或辨析其他选项。" + }, + { + "idx": 2764, + "question": "When a critical nucleus forms, the reduction in volume free energy can only compensate for the surface energy by ", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项B作为答案 | 知识层次: 题目考查的是关于临界核形成时体积自由能和表面能之间关系的基本概念记忆和理解，属于材料科学中的基础理论知识。 | 难度: 在选择题中属于中等偏下难度，需要理解临界核形成时体积自由能和表面能的关系，并进行简单辨析。虽然涉及基本概念，但不需要复杂的分析或深度理解多个相关概念。" + }, + { + "idx": 2765, + "question": "In the Kirkendall effect, the main reason for marker drift is the diffusion couple's ", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案形式为选项字母（C） | 知识层次: 题目考查Kirkendall效应的基本概念和原因，属于对基本原理的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解Kirkendall效应的基本原理和标记漂移的原因，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 2766, + "question": "What is the critical resolved shear stress for crystal slip?", + "answer": "The minimum resolved shear stress required for alternate slip in the slip systems of a crystal is called the critical resolved shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释\"critical resolved shear stress\"的概念，答案是一个完整的定义性陈述，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查对临界分切应力这一基本概念的定义记忆和理解，属于材料科学中晶体变形的基础知识，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆性知识。题目不涉及概念的解释、描述或复杂体系的阐述，仅需直接回忆并复述临界分切应力的定义即可。因此在该题型内属于最低难度等级。" + }, + { + "idx": 2767, + "question": "The difference between cast iron and carbon steel lies in the presence of", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案形式为单个选项（A） | 知识层次: 题目考查对铸铁和碳钢之间差异的基本概念记忆，仅需识别两者在成分上的关键区别点，属于基础概念记忆范畴。 | 难度: 在选择题中属于简单难度，仅需识别铸铁和碳钢的基本区别（碳含量），属于直接记忆的基础概念，无需复杂分析或深度理解。" + }, + { + "idx": 2768, + "question": "The effective distribution coefficient $K_{i}$ represents the degree of mixing in the liquid phase, and its value range is . (where $K_{\\circ}$ is the equilibrium distribution coefficient)", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（B） | 知识层次: 题目考查对有效分布系数$K_{i}$的定义及其取值范围的基本概念记忆，属于基础概念的记忆和理解层次。 | 难度: 该题目属于选择题中的概念理解和简单辨析难度。虽然题目涉及到了有效分布系数和平衡分布系数的概念，但只需要理解两者之间的关系以及有效分布系数的取值范围即可选出正确答案。不需要进行复杂的分析或深度理解多个概念之间的关系。" + }, + { + "idx": 2769, + "question": "In a binary alloy phase diagram, the lever rule for calculating the relative amounts of two phases can only be applied in", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查对二元合金相图中杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解杠杆规则的应用条件，但不需要复杂的辨析或深度理解多个概念。" + }, + { + "idx": 2770, + "question": "According to the vertical section of a ternary phase diagram, one can", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出了一个陈述并要求从选项中选择正确答案（选项B），符合选择题的特征 | 知识层次: 题目考查对三元相图垂直截面图的基本理解和记忆，属于基础概念层面的知识。 | 难度: 在选择题中属于中等偏下难度，需要理解三元相图垂直截面的基本概念，并进行简单辨析。题目考察的是对基础概念的理解和应用，但不需要复杂的分析或深度推理。" + }, + { + "idx": 2771, + "question": "In a ternary phase diagram, the isothermal section of a three-phase region is always a connected triangle, with its vertices touching", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对三元相图中三相区等温截面形状的基础概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解三元相图中三相区的等温截面特征，并进行简单辨析。虽然题目涉及基础概念记忆，但需要对相图结构有一定理解才能正确选择答案。" + }, + { + "idx": 2772, + "question": "In the ternary composition triangle, alloys whose compositions lie on the have equal contents of the two components represented by the other two vertices. (A) The perpendicular bisector passing through the vertex of the triangle (B) Any straight line passing through the vertex of the triangle (C) A straight line passing through the vertex of the triangle and forming a $45^{\\circ}$ angle with the opposite side", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对三元相图中特定组成线的基本概念的理解和记忆，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解三元相图的基本概念和几何特征，但不需要复杂的分析或计算。题目考察的是对特定几何线（角平分线）的理解，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 2773, + "question": "How many equivalent slip systems are there when a face-centered cubic metal single crystal is stretched along [001]? And specifically write out the indices of each slip system.", + "answer": "When an fcc-structured crystal is stretched along the [001] axis, there are a total of 8 equivalent slip systems, which are: (111)[011], (111)[101], (111)[011], (111)[101], (1 11)[011], (1 11)[101], (111)[101], (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求具体写出每个滑移系的指数，需要详细的文字解释和列举，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解面心立方金属的滑移系统概念，并能够具体列出在特定拉伸方向下的等效滑移系统。这涉及到对晶体结构和滑移系统之间关系的理解，以及如何在不同方向上识别等效滑移系统。虽然不需要复杂的计算或深入的分析，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于较高难度，需要综合运用晶体学知识，包括理解fcc晶体的滑移系统、等效滑移面的确定、滑移方向的判断，并能准确写出所有等效滑移系统的指数。解题过程涉及多步分析和概念关联，要求学生对晶体结构和滑移机制有较深入的理解。" + }, + { + "idx": 2775, + "question": "Carburizing steel in a carbon-rich environment can harden the surface of the steel. It is known that during this carburizing heat treatment at 1000°C, the carbon content decreases from x=5% to x=4% at a distance of 1∼2mm from the surface of the steel. First, the content of solute carbon atoms should be converted from atomic fraction to volume fraction, so the number of atoms per unit volume of the solvent iron must be determined. The density of γ-Fe at 1000°C is known to be =7.63g/cm³.", + "answer": "ρ=7.63×(6.023×10^23)/55.85=8.23×10^22 at/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及将原子分数转换为体积分数，并计算单位体积内的原子数量。答案是一个具体的数值计算结果。 | 知识层次: 题目需要进行多步计算，包括单位转换和公式应用，涉及原子分数到体积分数的转换，以及密度和原子量的计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算步骤。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要完成多步计算过程，包括单位转换、密度计算以及原子数计算，同时需要理解碳含量变化与距离的关系。虽然涉及多个步骤和概念，但计算过程相对直接，没有涉及复杂多变量或高级数学工具，因此在计算题中属于中等难度。" + }, + { + "idx": 2776, + "question": "Given that the recrystallization activation energy of a $\\mathtt{C u}{\\sim}30\\%\\mathtt{Z n}$ alloy is $250\\mathrm{kJ/mol}$, and it takes 1 hour for this alloy to complete recrystallization at a constant temperature of $400^{\\circ}C$, calculate how many hours it will take for this alloy to complete recrystallization at a constant temperature of $390\\mathrm{\\textperthousand}$.", + "answer": "Solution: Using the formula $$ \\frac{t_{2}}{t_{1}}{=}\\ e^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{2}}\\right)},$$ thus $$ \\begin{array}{r l}&{\\frac{t_{2}}{t_{1}}{=}\\exp\\Big({-}\\frac{Q}{R}\\Big(\\frac{1}{T_{1}}{-}\\frac{1}{T_{2}}\\Big)\\Big)}\\ &{\\quad\\quad{=}\\exp\\Big({-}\\frac{250\\times10^{3}}{8.314}\\Big(\\frac{1}{400+273}{-}\\frac{1}{390+273}\\Big)\\Big)}\\ &{\\quad{=}1.962}\\end{array}$$ Therefore, it will take 1.962 hours.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案给出了具体的计算过程和最终数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解并运用阿伦尼乌斯公式进行温度和时间关系的转换。虽然计算过程较为直接，但需要将温度转换为绝对温度并进行指数运算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用公式进行多步计算，涉及温度转换和指数运算，但步骤清晰且变量较少，属于中等偏上难度。" + }, + { + "idx": 2777, + "question": "Based on the diffusion coefficients at 1223K and 1136K, calculate the activation energy Q for interstitial atom diffusion in face-centered cubic metals. The diffusion coefficient at 1223K is 4.34×10⁻⁸m²/s, and at 1136K it is 1.78×10⁻⁸m²/s.", + "answer": "According to Arrhenius' law, D = D₀exp(-Q/RT). For two temperatures, we have: D₁/D₂ = exp[(-Q/R)(1/T₁ - 1/T₂)]. Substituting the data: 4.34×10⁻⁸ / 1.78×10⁻⁸ = exp[(-Q/8.314)(1/1223 - 1/1136)]. Solving gives: Q ≈ 1.2×10⁵J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的扩散系数和温度数据，通过Arrhenius方程计算激活能Q，需要进行数值计算和公式应用。答案也展示了具体的计算过程和结果。 | 知识层次: 题目需要应用Arrhenius定律进行多步计算，涉及对数运算和温度转换，需要将扩散系数与温度关联起来综合分析，但不需要进行复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用Arrhenius定律进行多步计算，涉及对数运算和温度倒数处理，但变量和计算步骤相对明确，属于中等偏上的难度。" + }, + { + "idx": 2778, + "question": "At a temperature of 1223K, calculate the diffusion coefficient of interstitial atoms in a face-centered cubic metal. The thickness of the metal film is 0.25mm, the end face area is 1000mm², the rate of interstitial atoms passing through the film is 0.0025g/s, and the solubility of interstitial atoms in the film is 14.4kg/m³.", + "answer": "According to Fick's first law, the formula for calculating the diffusion coefficient D is: D = -J * Δx / Δρ. Here, J = v / A = 0.0025g/s / 1000mm² = 0.0025×10⁻³kg/s / 10⁻³m² = 0.0025kg/(m²·s). Δx = 0.25mm = 0.25×10⁻³m. Δρ = 0 - 14.4kg/m³ = -14.4kg/m³. Therefore, D = -0.0025kg/(m²·s) * 0.25×10⁻³m / (-14.4kg/m³) ≈ 4.34×10⁻⁸m²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散系数，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用Fick第一定律进行多步计算，涉及单位转换和公式推导，但不需要复杂的综合分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用菲克第一定律进行多步计算，涉及单位转换和负号处理，但整体计算过程较为直接，没有涉及复杂多变量或高阶数学运算。" + }, + { + "idx": 2779, + "question": "According to Fick's first law, calculate the influx J (atoms/m²s) of carbon atoms entering the steel in the near-surface region.", + "answer": "J=−D(Δρ/Δx)=−(2.98×10⁻¹¹)×(−8.23×10^29)=2.45×10^19 at/(m²s)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据Fick's first law进行数值计算，并给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查菲克第一定律的直接应用，涉及简单的数值计算和公式套用，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用Fick's first law的单一公式进行计算，无需任何公式组合或复杂转换。题目中所有参数均已给出，仅需执行简单的代数运算即可得到结果。" + }, + { + "idx": 2780, + "question": "The homogeneous nucleation rate of pure metals can be expressed by the following equation: $$ \\\\dot{N}=A\\\\exp\\\\Bigl(-\\\\frac{\\\\Delta G^{*}}{k T}\\\\Bigr)\\\\exp\\\\Bigl(-\\\\frac{Q}{k T}\\\\Bigr)$$ where $A\\\\approx10^{35}\\\\mathfrak{s e x p}\\\\left\\\\{-\\\\frac{Q}{k T}\\\\right\\\\}\\\\approx10^{-2}\\\\mathfrak{s}$, $\\\\Delta G^{*}$ is the critical nucleation work; $\\\\pmb{k}$ is the Boltzmann constant, with a value of $1.38\\\\times10^{-23}\\\\mathrm{J}/\\\\mathrm{K}$. \\n\\n$\\\\textcircled{1}$ Assuming undercooling $\\\\Delta T$ is $20\\\\mathrm{\\\\mathcal{C}}$ and ${\\\\bf 200}\\\\%$, interfacial energy $\\\\sigma{=}2\\\\times10^{-5}~\\\\mathrm{J/cm^{2}}$, heat of fusion $\\\\Delta H_{\\\\mathrm{m}}=$ $\\\\mathrm{12600J/mol}$, melting point $\\\\mathcal{T}_{\\\\mathbf{m}}{=}1000\\\\:\\\\mathrm{K}$, molar volume $V{=}6~\\\\mathrm{cm}^{3}/\\\\mathrm{mol}$, calculate the homogeneous nucleation rate $\\\\dot{N}$. \\n\\n$\\\\textcircled{2}$ If it is heterogeneous nucleation, with the contact angle between the nucleus and impurity $\\\\pmb{\\\\theta}\\\\mathrm{=}60^{\\\\circ}$, how does $\\\\dot{N}$ change? What is $\\\\Delta T$? \\n\\n$\\\\textcircled{3}$ Derive the relationship between $\\\\neq^{*}$ and $\\\\mathbf{\\\\Delta}\\\\pmb{\\\\Delta}^{T}$, and calculate $\\\\begin{array}{l}{\\\\underbrace{\\\\Delta\\\\mathcal{T}}_{\\\\mathcal{T}_{\\\\infty}}}\\\\end{array}$ when $r^{*}=1{\\\\mathrm{~nm}}$.", + "answer": "$$ \\\\begin{array}{l}{{\\\\dot{N}=A\\\\exp\\\\Bigl(-\\\\frac{\\\\Delta G^{*}}{{\\\\dot{k}}T}\\\\Bigr)\\\\exp\\\\Bigl\\\\{-\\\\frac{Q}{k t}\\\\Bigr\\\\}}}\\\\ {{{}}}\\\\ {{=10^{35}\\\\times10^{-2}\\\\times\\\\exp\\\\Bigl(-\\\\frac{16\\\\pi\\\\sigma^{3}}{3\\\\Delta G_{v}^{2}k T}\\\\Bigr)}}\\\\ {{{}}}\\\\ {{=10^{33}\\\\times\\\\exp\\\\Bigl(-\\\\frac{16\\\\pi\\\\sigma^{3}T_{\\\\mathrm{a}}^{2}V^{2}}{3k T\\\\Delta{\\\\dot{H}}^{2}\\\\Delta{\\\\dot{T}}^{2}}\\\\Bigr)}}\\\\end{array}$$ $\\\\textcircled{1}$ \\n\\nWhen $\\\\Delta T=20\\\\mathrm{~C~}$: $$ {\\\\dot{N}}{=}10^{33}\\\\exp\\\\Bigl[{-\\\\frac{16\\\\times3.14\\\\times(2\\\\times10^{-5})^{3}\\\\times1000^{2}\\\\times6^{2}}{3\\\\times1.38\\\\times10^{-23}\\\\times800\\\\times12600^{2}\\\\times200^{2}}}\\\\Bigr]$$ $\\\\textcircled{2}$ When $\\\\theta=60^{\\\\circ}$: The heterogeneous nucleation free energy $$ \\\\Delta G_{\\\\mathrm{in}}^{*}=\\\\Delta G^{*}\\\\ \\\\Bigl(\\\\frac{2-3\\\\mathrm{cos}60^{\\\\circ}+\\\\mathrm{cos}^{3}60^{\\\\circ}}{4}\\\\Bigr)=0.156\\\\Delta G^{*}.$$ When $\\\\Delta T{=}20\\\\mathrm{~C~}$, $\\\\dot{N}=10^{33}\\\\exp(-0.156\\\\times5615,8)=0$. When $\\\\Delta{\\\\cal T}{=}200\\\\Upsilon$, $\\\\dot{N}{=}10^{33}\\\\exp(-0.156\\\\times68.79){=}2.2\\\\times10^{28}\\\\left({\\\\mathrm{cm}}^{-3}{\\\\mathrm{s}}^{-1}\\\\right)$. Assuming undercooling is $\\\\Delta T,T{=}T_{\\\\infty}{-}\\\\Delta T$, according to the given conditions: $$ 1=10^{33}\\\\exp\\\\Bigl(-\\\\frac{16\\\\times3.14\\\\times200^{3}\\\\times1000^{2}\\\\times6^{2}}{3\\\\times1.38\\\\times10^{-16}\\\\times(12600\\\\times10^{7})^{2}(1000-\\\\Delta T)\\\\Delta T^{2}}\\\\times0.156\\\\Bigr)$$ or $$ 10^{-33}=\\\\exp\\\\Bigl(-\\\\frac{3.43\\\\times10^{8}}{(1000-\\\\Delta T)\\\\Delta T^{2}}\\\\Bigr)$$ Taking the logarithm of both sides: $$ 75.98={\\\\frac{3.43\\\\times10^{8}}{(1000-\\\\Delta T)\\\\Delta T^{2}}}$$ $$ (1000-\\\\Delta T)\\\\Delta T^{\\\\circ}=4.51\\\\times10^{6}$$ Thus: $$ \\\\Delta T\\\\approx70^{\\\\circ}C$$ $\\\\textcircled{3}$ $$ r^{\\\\bullet}=\\\\frac{2\\\\sigma}{\\\\Delta G}=\\\\frac{2\\\\sigma T_{\\\\mathrm{m}}V}{\\\\Delta H\\\\Delta T}$$ $$ {\\\\frac{\\\\Delta\\\\mathrm{T}}{\\\\mathrm{T}_{\\\\mathrm{m}}}}={\\\\frac{2\\\\sigma V}{\\\\Delta H r^{\\\\ast}}}$$ When $r^{*}=1\\\\mathrm{nm}$: $$ \\\\frac{\\\\Delta T}{T_{\\\\mathrm{m}}}=\\\\frac{2\\\\times200\\\\times6}{12600\\\\times10^{7}\\\\times1\\\\times10^{-7}}=0.19$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算均质成核速率、异质成核条件下的变化以及推导关系式并计算特定条件下的过冷度。答案中包含了详细的数学运算和公式推导过程。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用公式进行计算，并理解均质成核和非均质成核的区别及其对成核速率的影响。虽然题目提供了具体的公式和参数，但需要学生能够正确应用这些公式进行计算，并理解不同条件下的变化。此外，题目还要求推导关系式，这需要一定的综合分析能力。 | 难度: 在计算题中属于复杂多变量计算难度，需要处理多个物理参数和复杂的指数运算，涉及多步骤推导和数值计算，包括临界成核功、界面能、熔化热等概念的关联应用，以及异质成核条件下的接触角修正计算。题目还要求在不同过冷度条件下进行对比分析，并推导关键参数关系式，综合计算要求高。" + }, + { + "idx": 2781, + "question": "Calculate the diffusion coefficient D of carbon in γ-Fe. Given the diffusion coefficient of carbon in γ-Fe D₀=2.0×10⁻⁵ m²/s, activation energy Q=142 kJ/mol, and temperature T=1000℃.", + "answer": "D=D₀e^(−Q/RT)=2.0×10⁻⁵×exp(−142000/(8.314×1273))=2.98×10⁻¹¹ m²/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出扩散系数的具体数值，属于典型的计算题类型。 | 知识层次: 题目要求直接套用扩散系数的计算公式进行计算，涉及基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了扩散系数的计算公式和所有必要的参数（D₀、Q、T），只需要将这些数值代入公式并进行简单的指数运算即可得到结果。不需要额外的步骤或复杂的推导，属于最基础的计算题类型。" + }, + { + "idx": 2782, + "question": "Approximately consider (number of carbon atoms + number of iron atoms) ≈ number of iron atoms, calculate the rate of change of carbon atom number Δρ/Δx at a distance of 1∼2mm from the steel surface.", + "answer": "Δρ/Δx=(5%−4%)×(8.23×10^22)/(1−2)×10^6×10^3=−8.23×10^29 at/m⁴", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳原子数的变化率Δρ/Δx），并给出了具体的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及碳原子和铁原子数量的近似处理，以及浓度梯度的计算。虽然计算过程相对直接，但需要对材料科学中的浓度梯度概念有一定的理解，并能正确应用相关公式进行计算。这属于中等难度的应用题目，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解碳原子和铁原子的数量关系，进行多步计算，并应用公式求解变化率。虽然计算步骤较多，但概念关联和综合分析的要求使其在同类题型中处于中等偏上难度。" + }, + { + "idx": 2783, + "question": "Given a diffusion couple composed of pure chromium and pure iron, after 1 hour of diffusion, the Matano plane moved by 1.52×10^(-3) cm. It is known that the ratio of the square of the distance moved by the Matano plane to the diffusion time is a constant. Determine the moving speed of the Matano plane.", + "answer": "According to the given conditions: x²/t = k, the moving speed of the Matano plane vₐ = dx/dt = k/(2x) = x/(2t) = (1.52×10^(-3))/(2×3600) cm/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定Matano平面的移动速度。答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的条件和公式进行直接套用和数值计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式x²/t = k，并通过简单代数变换得到速度表达式vₐ = x/(2t)。题目已给出所有必要参数，计算仅涉及基本单位换算（小时转秒）和一次除法运算，无需任何多步骤推导或复杂公式组合。" + }, + { + "idx": 2785, + "question": "There is a silicon single crystal wafer with a thickness of 0.5 mm. On one end face, every 10^7 silicon atoms contain two atoms, while the other end face has an increased concentration of gallium after treatment. Determine how many gallium atoms per 10^7 silicon atoms are required on this face to achieve a concentration gradient of 2×10^26 atoms/m³·m. The lattice constant of silicon is 0.5407 nm.", + "answer": "Silicon has a diamond structure, with 8 atoms per unit cell. Therefore, the volume corresponding to 10^7 atoms is: V = (10^7 / 8) × a₀³ = (10^7 / 8) × (0.5407 × 10^-9)^3 = 1.976 × 10^-22 m³. Let x be the number of gallium atoms per 10^7 silicon atoms on this end face. Then: Δρ/Δx = [(x / V) - (2 / V)] / (0.5 × 10^-3) = 2 × 10^26. x = 2 + 0.5 × 10^-3 × 2 × 10^26 × 1.976 × 10^-22 = 21.76 ≈ 22. Thus, this end face must contain 22 gallium atoms per 10^7 silicon atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算体积、浓度梯度等，最终得出具体的数值答案。解答过程涉及多个步骤的数学运算和物理公式的应用。 | 知识层次: 题目需要进行多步计算，包括单位晶胞体积的计算、浓度梯度的计算以及最终求解所需的镓原子数量。虽然题目涉及基本的晶体结构和浓度梯度概念，但需要将这些概念关联起来进行综合分析，并应用相关公式进行计算。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及晶体结构、浓度梯度计算和单位转换，解题步骤较为复杂，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2786, + "question": "A carbon steel with w(C)=0.1% is carburized at 930°C, reaching a carbon concentration of 0.45% at a depth of 0.05cm. For all times t>0, the carburizing atmosphere maintains a surface composition of 1%. Assuming D=0.2×10^(-5) exp(-140000/RT)(m²/s), calculate the carburizing time.", + "answer": "From Fick's second law, the solution is w=w_s-(w_s-w_0)erf(x/(2√(Dt))). Substituting the data gives (1%-0.45%)/(1%-0.1%)=erf(0.05/(2√(Dt))), i.e., 0.61=erf(0.05/(2√(Dt))). Looking up the table yields 0.05/(2√(Dt))=0.61, and D=0.2×exp(-140000/(8.314×1203))=1.67×10^(-7)(cm²/s). Therefore, the carburizing time t≈1.0×10^3(s).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Fick's second law）来求解渗碳时间，答案给出了具体的计算过程和最终的时间结果。 | 知识层次: 题目需要应用Fick第二定律进行多步计算，包括查表、数值代入和单位转换，涉及扩散系数的计算和误差函数的应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用菲克第二定律进行多步计算，涉及查表、公式转换和数值计算。虽然步骤较多，但每一步都有明确的指导方向，属于中等偏上的难度。" + }, + { + "idx": 2787, + "question": "If w(C)=0.3% is specified as the measure of carburization layer thickness, how many times is the carburization layer thickness after 10h at 930°C compared to that after 10h at 870°C?", + "answer": "x₉₃₀/x₈₇₀=√(D₉₃₀t₉₃₀)/√(D₈₇₀t₈₇₀). Since t₉₃₀=t₈₇₀, D₉₃₀=1.67×10^(-7)(cm²/s), D₈₇₀=0.2×exp(-140000/(8.314×1143))=8.0×10^(-8)(cm²/s). Therefore, x₉₃₀/x₈₇₀=√(D₉₃₀)/√(D₈₇₀)=√(1.6×10^(-7)/7.9×10^(-8))=1.45.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散系数和时间的平方根关系，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括扩散系数的计算和比较，以及应用菲克第二定律的公式来求解渗碳层厚度的比值。这需要理解扩散过程的基本原理，并能正确应用相关公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散系数公式并进行多步计算，包括温度转换、指数运算和平方根运算。虽然计算过程明确，但涉及多个物理概念的综合运用和数值处理，在同题型内属于中等偏上难度。" + }, + { + "idx": 2788, + "question": "Given the initial carbon concentration of plain carbon steel w0=0.85%, after heating to 900°C and holding in air for 1h, the outer carbon concentration drops to zero. If the required carbon concentration in the outer layer of the part is 0.8%, how much depth should be turned off the surface? (D=1.1×10−7cm2/s)", + "answer": "From w=w0erf(β), we get 0.80=0.85erf(x/(2√Dt)) → erf(x/(2√Dt))=0.94. Checking the error function table gives x/(2√Dt)=1.33. Calculating √Dt=√(1.1×10−7×3600)=0.0199 cm. Solving for x gives x=1.33×2×0.0199=0.053 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及碳浓度、扩散系数和误差函数的使用，最终需要计算出具体的深度值。答案展示了详细的数学推导和计算过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和误差函数表进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要应用误差函数（erf）的概念，进行多步骤的数值计算，包括查表和代数运算。虽然涉及的知识点较为明确，但解题过程需要综合运用扩散方程和误差函数的知识，并进行准确的计算步骤，因此在同类计算题中属于中等偏上的难度。" + }, + { + "idx": 2789, + "question": "Derive the solution to the decarburization diffusion equation, assuming that at t>0, ρ=0 at x=0. The initial conditions are known as t=0, x≥0, ρ=ρ0; boundary conditions are t>0, x=0, ρ=0; x=∞, ρ=ρ0.", + "answer": "From Fick's second law, the general solution is obtained (assuming D is independent of ρ): ρ=A1∫0βexp(−β2)dβ+A2. Initial condition t=0, x≥0, ρ=ρ0, β=x/(2√Dt). Boundary condition t>0, x=0, ρ=0 → 0=A1∫0βexp(−β2)dβ+A2 → A2=0. Combined equation: ρ0=A1√π/2+A2 → A1=2ρ0/√π. Substituting into the general solution: ρ=2ρ0/√π∫0βexp(−β2)dβ=ρ0erf(β). Dividing by the alloy density gives w=w0erf(β).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导脱碳扩散方程的解，涉及数值计算和公式应用，答案展示了具体的推导过程和数学计算步骤。 | 知识层次: 题目需要应用Fick第二定律进行多步计算，涉及边界条件和初始条件的处理，以及误差函数的应用。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用Fick第二定律进行多步推导，涉及边界条件和初始条件的处理，以及误差函数的应用。虽然计算步骤较多，但每个步骤相对明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 2790, + "question": "If the depth of the diffusion layer is doubled, how much time is required?", + "answer": "From the relation x=A√(Dt), we have x₁=A√(Dt₁) and x₂=A√(Dt₂). Dividing the two equations gives (x₂²)/(x₁²)=(Dt₂)/(Dt₁). When the temperature is the same, D₁=D₂, thus t₂=(x₂²)/(x₁²)×t₁=(0.1²)/(0.05²)×1.0×10^4=4.0×10^4 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解扩散方程并直接套用公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目仅涉及单一扩散公式的变形和比例计算，解题步骤清晰直接，无需多公式组合或复杂推导。虽然需要理解公式含义并进行平方运算，但整体仍属于该题型内的基础应用层级。" + }, + { + "idx": 2791, + "question": "Calculate the root mean square displacement of the total migration of carbon atoms $\\\\sqrt{\\\\overline{R_{n}^{2}}}$, given the jump frequency of carbon atoms as $\\\\Gamma=1.7\\\\times10^{9}/\\\\mathrm{s}$, the jump distance as $2.53\\\\times10^{-10}\\\\mathrm{m}$, and the time as $4\\\\mathrm{h}$.", + "answer": "$\\\\sqrt{\\\\overline{R_{n}^{2}}}=\\\\sqrt{n}\\\\cdot r=\\\\sqrt{1.7\\\\times10^{9}\\\\times4\\\\times3600}\\\\times2.53\\\\times10^{-10}=1.25\\\\times10^{-3}\\\\mathrm{m}\\\\approx1.3\\\\mathrm{mm}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（跳跃频率、跳跃距离和时间）进行数值计算，应用公式求解碳原子的均方根位移。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括时间单位转换、公式应用（根均方位移公式）和数值计算，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散理论中的根均方位移公式，涉及多步计算（包括时间单位转换、平方根运算等），并需要正确关联跳跃频率、跳跃距离和时间等概念。虽然计算过程明确，但需要较强的概念理解和数值处理能力，属于中等偏上的难度。" + }, + { + "idx": 2792, + "question": "Given a diffusion couple composed of pure chromium and pure iron, it is known that when the mole fraction x_Cr=0.478, ∂x/∂z=126/cm, and the interdiffusion coefficient D=1.43×10^(-8) m²/s, find the intrinsic diffusion coefficients D_Cr and D_Fe of chromium and iron.", + "answer": "According to the Kirkendall effect, the marker velocity vₐ = (D_Cr - D_Fe)×126. The interdiffusion coefficient D = x_Fe D_Cr + x_Cr D_Fe → 0.478 D_Fe + (1-0.478) D_Cr = 1.43×10^(-8) m²/s. By solving these two equations together with the marker velocity vₐ at the Matano plane, we obtain D_Cr = 2.23×10^(-9) cm²/s and D_Fe = 0.56×10^(-9) cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出具体的扩散系数数值，属于典型的计算题。 | 知识层次: 题目需要应用Kirkendall效应和扩散系数的相关公式，进行多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用Kirkendall效应和扩散系数公式进行多步计算，涉及多个变量和概念关联，但步骤相对明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 2793, + "question": "For pure iron carburized at $950\\\\mathrm{\\\\textperthousand}$, it is desired to achieve a carbon content of $\\\\mathfrak{w}{1}\\\\left(\\\\mathbb{C}\\\\right)=0,9\\\\%$ at a depth of $0.1\\\\mathrm{mm}$. Assuming the surface carbon content remains at $w{2}\\\\left(\\\\mathsf{C}\\\\right)=1.20\\\\%$, and the diffusion coefficient $D_{\\\\mathtt{Y F e}}{=}10^{{-}10}\\\\ensuremath{\\\\mathbf{m}}^{2}/\\\\mathbf{s},$, calculate the minimum carburization time required to meet this requirement.", + "answer": "$$\\\\begin{array}{c}{\\\\frac x{2\\\\sqrt{D t}}=0,8163}}\\\\ {{{\\\\mathrm x}=2\\\\times0.8163\\\\times\\\\sqrt{1.1\\\\times10^{-1}\\\\times3600}}}\\\\ {{{\\\\mathrm x}=0.032\\\\mathrm{(cm)}}}\\\\ {{{\\\\mathrm w}_{2}-{\\\\mathrm w}_{1}=\\\\mathrm{erf}\\\\left({\\\\frac{x}{2\\\\sqrt{D t}}}\\\\right)}}\\\\ {{{\\\\mathrm x}_{2}-{\\\\mathrm w}_{0}=\\\\mathrm{erf}\\\\left({\\\\frac{0.1\\\\times10^{-3}}{2\\\\sqrt{10^{-10}\\\\times t}}}\\\\right)}}\\\\end{array}$$ $$\\\\operatorname{erf}{\\\\Big(}{\\\\frac{5}{\\\\sqrt{t}}}{\\\\Big)}=0.25$$ Look up the table to find $$\\\\frac{5}{\\\\sqrt{t}}\\\\approx0.2763,$$ hence $$t\\\\approx327(\\\\mathrm{s})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小渗碳时间，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和误差函数表进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程和误差函数进行多步计算，涉及查表和数值求解，但步骤相对明确，没有引入过多复杂变量或非常规概念。" + }, + { + "idx": 2794, + "question": "There are two diffusion reactions with activation energies of Q_1=83.7 kJ/mol and Q_2=251 kJ/mol, respectively. Observe the effect of increasing the temperature from 25°C to 600°C on the diffusion with an activation energy of Q_2=251 kJ/mol, and comment on the results.", + "answer": "From D=D_0 exp(-Q/RT), we get D_873/D_298=exp[-251000/(8.314)×(298-873)/(873×298)]=9.5×10^28. For the temperature increase from 298K to 873K, the diffusion rate D increases by 9.5×10^28 times, showing that the higher the activation energy, the more sensitive the diffusion rate is to temperature.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算扩散速率的变化，并给出具体的数值结果。答案中包含了详细的公式应用和数值计算过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算（温度转换、扩散系数公式应用、指数计算）和概念关联（激活能与温度对扩散速率的影响），需要综合分析不同温度下的扩散速率变化，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，并理解温度变化对扩散速率的影响。虽然计算步骤明确，但涉及较高阶的数学运算（指数函数）和单位转换（温度从°C到K），且需要对物理概念（活化能与温度敏感性的关系）有较深理解。在同题型内属于中等偏上难度，但未达到复杂多变量计算的等级4标准。" + }, + { + "idx": 2795, + "question": "Determine whether the formula D=D0exp(-Q/RT) is applicable to the diffusion coefficient data of carbon in α-Ti; if applicable, calculate the diffusion constant D0 and activation energy Q", + "answer": "By plotting D against temperature (converted to absolute temperature), it was found that lgD has a linear relationship with 1/T, thus satisfying the formula D=D0exp(-Q/RT). The slope is Q/(2.3R), and the calculated Q=2.3×R×0.92×10^4=175.9 kJ/mol. For T=1009 K (736℃), D736=2×10^-13 m^2/s. Substituting into the formula gives lgD0=lgD+Q/(2.3R)×1/T=lg(2×10^-13)+175900/(2.3×8.314×1009)≈-3.58, therefore D0=2.62×10^-4 m^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求应用公式D=D0exp(-Q/RT)进行数值计算，包括确定扩散常数D0和激活能Q，并通过数据分析和数学运算得出具体数值结果。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的公式进行多步计算，包括绘制图表、确定线性关系、计算斜率和截距，以及代入数值求解扩散常数和激活能。这涉及到对公式的理解和综合应用，但不需要进行复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散系数的温度依赖性公式，进行对数转换和线性拟合，计算斜率和截距以确定激活能和扩散常数，涉及多步计算和概念关联，但未达到复杂多变量计算的级别。" + }, + { + "idx": 2796, + "question": "Calculate the diffusion activation energy Q1 of polycrystalline silver at 700°C (based on the given data).", + "answer": "From the equation -10.72-(-12) = -Q_1/R (1.10×10^-3 -1.30×10^-3) lge, the solution gives Q_1 = 122.4 kJ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出扩散激活能Q1的具体数值。答案展示了计算过程和最终结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散激活能的计算公式，并进行多步计算和数据处理，涉及对Arrhenius方程的理解和应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求基于给定数据进行扩散激活能的计算，涉及公式应用和单位转换，但未达到复杂多变量计算的级别。" + }, + { + "idx": 2797, + "question": "Calculate the diffusion coefficient of carbon in α-Ti at 500℃", + "answer": "Using the formula lgD500=lgD0-Q/(2.3×R)×1/T=lg(2.62×10^-4)-175.9×10^3/(2.3×8.314×773)=-3.58-11.90=-15.48, thus D500≈3.31×10^-16 m^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算碳在α-Ti中的扩散系数，答案涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及扩散系数的公式应用和温度转换，需要理解公式中各参数的含义及其相互关系，并进行对数运算和单位转换，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散系数公式并进行多步计算，包括对数运算、单位转换和温度换算。虽然计算过程较为直接，但需要正确理解和使用公式中的各个参数，并确保单位一致性，属于中等偏上的难度。" + }, + { + "idx": 2798, + "question": "Calculate the total migration distance $S$ of carbon atoms, given the carbon atom jump frequency as $\\Gamma=1.7\\times10^{9}/\\mathrm{s}$, jump distance as $2.53\\times10^{-10}\\mathrm{m}$, and time as $4\\mathrm{h}$.", + "answer": "$4\\mathrm{h}=4\\times3600\\mathrm{s}$, $S=\\Gamma \\cdot t \\cdot r=1.7\\times10^{9}\\times4\\times3600\\times2.53\\times10^{-10}=6193\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（碳原子跳跃频率、跳跃距离和时间）进行数值计算，应用公式来求解碳原子的总迁移距离。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过给定的参数（跳变频率、跳变距离和时间）直接套用公式计算迁移距离，无需多步计算或复杂的概念关联。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（迁移距离公式S=Γ·t·r）并进行单位换算和简单数值计算，无需多步骤推导或复杂公式组合。所有参数均已明确给出，解题过程仅涉及基本代数运算。" + }, + { + "idx": 2799, + "question": "Calculate the total migration distance S of carbon atoms at 20%, given the transition frequency r=2.1×10^-9/s, transition step length of 2.53×10^-10m, and time of 4h.", + "answer": "S=Γ·t·r=2.1×10^-9×4×3600×2.53×10^-10=7.65×10^-15m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出一个具体的数值结果。答案的形式是一个计算过程和一个具体的数值，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及迁移距离的计算公式，只需将给定的数值代入公式即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式进行计算，无需多个公式组合或复杂步骤。题目中给出的参数明确，计算过程简单，属于基本公式应用和直接数值计算的范畴。" + }, + { + "idx": 2800, + "question": "Indicate approximately in which temperature range grain boundary diffusion dominates.", + "answer": "In the low-temperature region (when 1/T is large), the lnD value of grain boundary diffusion is higher than that of bulk diffusion, and grain boundary diffusion dominates at this time. As the temperature increases (1/T decreases), the two curves will intersect, and in the high-temperature region above the intersection point, bulk diffusion will dominate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在哪个温度范围内晶界扩散占主导地位，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解晶界扩散和体扩散在不同温度下的相对优势，并解释其变化趋势。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解晶界扩散和体扩散的概念，并能分析温度变化对两种扩散机制的影响。题目要求综合说明在不同温度区域哪种扩散机制占主导，并解释原因，涉及多步分析和概念关联，但不需要过于深入的多角度或深度关联性分析。" + }, + { + "idx": 2801, + "question": "Calculate the root mean square displacement $\\sqrt{\\overline{R_{n}^{2}}}$ of carbon atoms at $20\\%$, given the transition frequency is $r=2.1\\times10^{-9}/\\mathrm{s}$, the transition step length is $2.53\\times10^{-10}\\mathrm{m}$, and the time is $4\\mathrm{h}$.", + "answer": "$\\sqrt{\\overline{R_{n}^{2}}}=\\sqrt{n}\\cdot r=\\sqrt{2.1\\times10^{-9}\\times4\\times3600}\\times2.53\\times10^{-10}=1.39\\times10^{-12}\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算并应用公式来求解碳原子的均方根位移，答案也是通过具体计算得出的数值结果。 | 知识层次: 题目需要进行多步计算，包括时间单位转换、平方根计算以及公式应用，涉及对扩散理论的理解和数值计算能力，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解扩散理论中的均方位移公式，正确代入多个变量（频率、步长、时间）并进行单位转换和开方运算。虽然计算步骤明确，但涉及多步推导和单位统一，对概念理解和计算准确性要求较高，符合等级3的综合性计算特征。" + }, + { + "idx": 2802, + "question": "Calculate the diffusion activation energy Q2 for single-crystal silver (based on the given data).", + "answer": "From equation 8-14 = -Q_2/R lge (0.8×10^-3 -1.39×10^-3), we obtain Q_2 = 194.5 kJ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出扩散激活能Q2的具体数值（194.5 kJ），这符合计算题的特征。 | 知识层次: 题目涉及扩散激活能的计算，需要应用公式进行多步计算，并理解扩散机制与温度的关系。虽然计算过程较为直接，但需要对相关概念和公式有一定的理解和应用能力，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散激活能公式并进行多步计算，涉及对数运算和单位转换，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2803, + "question": "For grain boundary diffusion and bulk diffusion, assuming the diffusion activation energy Q_AF≈1/2 Q_AF, plot the curve of InD versus the reciprocal of temperature 1/T.", + "answer": "According to the Arrhenius equation D = D_0 exp(-Q/RT), taking the logarithm gives lnD = lnD_0 - Q/(RT). For grain boundary diffusion (Q_gb) and bulk diffusion (Q_bulk), when Q_gb ≈ 1/2 Q_bulk, both lnD vs 1/T curves are straight lines, with the grain boundary diffusion line having a smaller slope.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求绘制曲线并解释其物理意义，需要文字解释和论述，而不是简单的选择、判断或计算 | 知识层次: 题目要求根据阿伦尼乌斯方程绘制扩散系数与温度倒数的关系曲线，并比较晶界扩散和体扩散的斜率差异。这需要理解扩散激活能的概念，并能应用阿伦尼乌斯方程进行多步分析和比较，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解Arrhenius方程并能够进行对数转换和斜率分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2804, + "question": "Introducing high-valence W6+ into NiO will generate vacancies of which ions?", + "answer": "Vacancies of cations (Ni) will be generated. (Principle of electroneutrality)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释引入高化合价W6+对NiO中离子空位的影响，并基于电中性原理进行文字论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解电中性原则，并应用该原则分析高价态W6+引入NiO后对阳离子空位的影响。这涉及多步推理和概念关联，但不需要复杂的机理分析或创新设计。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及电中性原理和离子空位生成机制，但解题过程主要依靠单一核心概念（电中性原则）的直接应用，不需要多角度分析或深度关联性分析。学生只需理解高价W6+取代Ni2+会导致阳离子空位补偿电荷失衡这一关键点即可作答，符合\"综合分析和说明\"的等级要求。" + }, + { + "idx": 2806, + "question": "In NiO, introducing high-valence W6+, how many vacancies will each W6+ generate?", + "answer": "Each W6+ introduction generates 2 Ni2+ vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释高价位W6+在NiO中引入时会产生多少个空位，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解高价位离子掺杂对氧化物缺陷的影响，涉及电荷平衡和缺陷化学的基本原理，需要进行多步推理和计算来确定每个W6+引入后产生的Ni2+空位数量。这属于中等应用层次，需要将概念关联并进行综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及多步计算和概念关联（如高价位掺杂和空位生成的关系），但解题步骤相对明确，主要需要学生理解W6+掺杂对NiO晶体结构的影响，并能正确推导出每个W6+引入会生成2个Ni2+空位。这需要一定的综合分析能力，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 2807, + "question": "Explain why the diffusion activation energy of polycrystals is lower than that of single crystals.", + "answer": "Polycrystals have grain boundaries, and the 'short-circuit' diffusion effect of grain boundaries increases the diffusion rate, thus resulting in a lower diffusion activation energy. The diffusion in single crystals is purely bulk diffusion, which has a higher activation energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶体的扩散激活能低于单晶体的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多晶和单晶扩散激活能的差异，涉及晶界扩散和体扩散的机理分析，需要综合运用扩散理论和晶体结构知识进行推理和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对多晶和单晶的扩散激活能差异进行机理深度解释。需要综合运用晶界扩散和体扩散的知识，分析\"短路扩散\"效应的物理本质，并建立与激活能的定量关系。虽然不涉及多因素交互作用的全面分析(等级5)，但已超出基础概念复述层面，属于需要深入理解扩散机理的题目。" + }, + { + "idx": 2808, + "question": "Compare the oxidation resistance of NiO and W-doped NiO (i.e., NiO-WO3), which one is better?", + "answer": "Due to the introduction of W, the vacancy concentration increases, making it easier for oxygen in the air and Ni2+ ions in the oxide to migrate in and out of the surface, thereby increasing the oxidation rate. As a result, the oxidation resistance is reduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较NiO和W掺杂NiO的氧化抗性，并解释哪一种更好。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较NiO和W掺杂NiO的氧化抗性，并解释其机理。这需要理解掺杂对材料性能的影响，分析氧空位浓度变化对氧化速率的影响，以及离子迁移的机制。涉及多个概念的关联和综合分析，思维过程较为深入。 | 难度: 在简答题中属于较高难度，需要深入理解掺杂对材料氧化行为的影响机制，并能够解释W掺杂如何通过增加空位浓度来促进氧和Ni2+离子的迁移，从而降低抗氧化性能。这要求综合运用材料科学和固态化学的知识，进行机理深度解释。" + }, + { + "idx": 2809, + "question": "The yield strength of the Mg alloy is 180MPa, and E is 45GPa. Under the maximum load, what is the elongation per mm of this magnesium plate?", + "answer": "ε=σ/E=180×10^6/45×10^9=0.004", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用（使用σ=Eε公式计算应变），答案是一个具体的数值结果。 | 知识层次: 题目考查基本公式（胡克定律σ=Eε）的直接应用和简单计算，仅需一步数值代入和单位转换，无需多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用这一题型中，该题目属于等级1难度。题目仅需直接应用单一公式（ε=σ/E）进行计算，无需额外的步骤或公式组合。计算过程简单，仅涉及基本单位转换和除法运算，属于最基础的公式直接套用类型。" + }, + { + "idx": 2810, + "question": "Explain the reason for the difference in diffusion coefficients between Al and O in Al2O3.", + "answer": "Because in Al2O3, the ionic radius of the cation Al is smaller than that of the anion O, the activation energy for Al diffusion in Al2O3 is lower than that for O diffusion in Al2O3. Therefore, the diffusion coefficient of the former is greater than that of the latter.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al和O在Al2O3中扩散系数差异的原因，答案通过文字论述和解释给出，符合简答题的特征。 | 知识层次: 题目要求解释Al和O在Al2O3中扩散系数的差异原因，涉及离子半径、活化能等概念的关联分析，需要综合运用扩散机制和材料结构知识进行推理和解释，思维过程较深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对Al2O3中Al和O扩散系数的差异进行机理深度解释。需要综合运用离子半径、活化能等概念，并理解这些因素如何影响扩散系数。虽然不涉及多因素交互作用的全面分析，但对扩散机理的解释要求较高，属于该题型中的较难题目。" + }, + { + "idx": 2811, + "question": "Given the diffusion coefficient of O in Al2O3, D0(O) = 0.19 m^2/s, and the activation energy Q = 636 kJ/mol, calculate its diffusion coefficient D at a temperature of 2000 K.", + "answer": "D = D0 * exp(-Q / (R * T)) = 0.19 * exp(-636000 / (8.314 * 2000)) = 4.7×10^-18 m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散系数、活化能和温度，应用阿伦尼乌斯公式进行数值计算，最终得出扩散系数的具体数值。答案是一个具体的计算结果，而非选择、判断或文字解释。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及扩散系数的计算，需要直接套用阿伦尼乌斯公式进行数值计算，无需多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了所需的扩散系数公式和所有必要的参数（D0、Q、R、T），只需要进行简单的数值代入和指数运算即可得到结果。没有涉及多个公式的组合或复杂的推导过程，符合等级1的标准。" + }, + { + "idx": 2812, + "question": "Given the diffusion coefficient of Al in Al2O3, D0(Al) = 2.8×10^-3 m^2/s, and the activation energy Q = 477 kJ/mol, calculate its diffusion coefficient D at a temperature of 2000 K.", + "answer": "D = D0 * exp(-Q / (R * T)) = 2.8×10^-3 * exp(-477000 / (8.314 * 2000)) = 9.7×10^-16 m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的扩散系数和激活能，通过公式计算特定温度下的扩散系数。解答过程涉及数值计算和公式应用，最终给出一个具体的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及扩散系数的计算，需要直接套用阿伦尼乌斯公式进行数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一扩散公式（D = D0 * exp(-Q/(R*T))），所有参数均已明确给出，计算过程仅涉及基本指数运算，无需任何推导或多步骤处理，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2813, + "question": "The yield strength of Mg alloy is 180MPa, E is 45GPa, find the maximum load that will not cause plastic deformation of a 10mm×2mm Mg plate.", + "answer": "F=σA=180×10^6×10×2×10^-6=3600(N)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用（使用屈服强度和弹性模量计算最大载荷），答案是一个具体的数值计算结果。 | 知识层次: 题目考查基本公式（应力=力/面积）的直接应用和简单计算，仅需一步转换和数值代入，无需多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（F=σA）进行数值计算，无需任何公式组合或复杂推导步骤。题目提供的参数直接对应公式变量，计算过程仅涉及基本单位换算和乘法运算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2814, + "question": "A nickel-based alloy sample with a cross-section of 10mm×10mm and a length of 40mm was subjected to a tensile test, and the results are shown in the table below. Calculate its yield strength σ0.2.", + "answer": "σ0.2 can be obtained from the stress-strain curve of the tensile test, which is 1000 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出镍基合金的屈服强度σ0.2，需要应用材料力学中的应力-应变关系和相关公式进行计算。答案给出了具体的数值结果（1000 MPa），符合计算题的特征。 | 知识层次: 题目要求根据拉伸试验结果计算屈服强度σ0.2，属于基本公式应用和简单计算范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目要求根据给定的应力-应变曲线直接读取屈服强度σ0.2的值，无需进行复杂的公式应用或多步骤计算，仅需理解屈服强度的定义并正确识别曲线上的对应点即可完成。" + }, + { + "idx": 2815, + "question": "A Gu–30%Zn brass plate is cold rolled by 25%, reducing its thickness to 1 cm. Subsequently, the plate is further reduced to a thickness of 0.6 cm. Calculate the total cold deformation degree.", + "answer": "Cold deformation degree = (A0 - AF) / A0 × 100%, 25% = (h w - 1 w) / (h w) × 100%, h = 4/3 cm. Total deformation degree = (4/3 w - 0.6 w) / (4/3 w) × 100% = 55%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定总的冷变形程度。解答过程中涉及到了百分比计算和公式推导，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括初始厚度的推导和总变形程度的计算，涉及公式的应用和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求先根据初始冷轧条件计算原始厚度，再计算总变形程度，涉及多个公式应用和综合分析步骤，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2816, + "question": "Analyze the effect of polymer molecular weight on the viscous flow temperature", + "answer": "When the molecular weight is smaller, the internal frictional resistance between molecular chains is reduced, making the relative movement of molecular chains easier, thus lowering the viscous flow temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析聚合物分子量对粘流温度的影响，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求分析聚合物分子量对粘流温度的影响，涉及分子链间摩擦阻力和相对运动的关联分析，需要理解分子量变化对材料性能的具体影响机制，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释聚合物分子量对粘流温度的影响机制，但主要涉及单一概念（分子量与链段运动性的关系）的因果分析，不需要多角度或跨领域的深度关联。解题步骤为：1) 识别分子量变化的影响 2) 说明分子链摩擦阻力的变化 3) 推导出粘流温度变化趋势，属于典型的\"综合分析和说明\"层级。相比需要讨论结晶度、添加剂等多因素影响的题目（等级4），或需要结合Arrhenius方程进行定量分析的题目（等级5），本题的认知负荷相对较低。" + }, + { + "idx": 2817, + "question": "What are the changes in properties of a Gu–30%Zn brass sheet after cold rolling?", + "answer": "After cold rolling, the strength and hardness of the brass sheet increase, while plasticity and toughness decrease, which is the phenomenon of work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷轧后黄铜板材性能的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷轧后黄铜板材性能的变化，涉及材料加工工艺与性能关系的综合分析，需要理解加工硬化现象及其对强度、硬度、塑性和韧性的影响。虽然不涉及复杂计算，但需要关联多个概念并进行逻辑解释，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解冷轧对黄铜板材性能的影响，并能够综合说明强度、硬度、塑性和韧性的变化。虽然涉及多个性能指标的变化，但不需要进行多角度或深度关联性分析，主要考察对工作硬化现象的基本理解和应用。" + }, + { + "idx": 2818, + "question": "There is an aluminum wire with a length of 5 m and a diameter of 3 mm. Given that the elastic modulus of aluminum is 70 GPa, find the total length of the wire under a tensile force of 200 N.", + "answer": "Within the elastic range, stress and strain obey Hooke's law ${\\pmb\\sigma}{=}{\\pmb E}{\\pmb\\varepsilon}$, and $\\mathsf{e}=\\frac{\\boldsymbol{\\ell}-\\boldsymbol{l}_{0}}{\\boldsymbol{l}_{0}}{=}\\frac{\\frac{\\boldsymbol{F}}{A}}{E}$. Therefore, $$l=l_{0}+\\frac{F}{E A}l_{\\circ}=l_{0}\\left(1+\\frac{F}{E A}\\right)=5\\left[1+\\frac{200}{70\\times10^{3}\\times\\frac{\\pi}{4}(3\\times10^{-3})^{2}}\\right]$$$$=5.00202(\\mathrm{m})=5002.02(\\mathrm{mm})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝线在拉伸力作用下的总长度，答案展示了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式（胡克定律）的直接应用和简单计算，不需要多步推理或综合分析，属于基础知识的直接应用层面。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于简单公式应用计算。题目直接应用了Hooke's law和应变公式，计算步骤较为直接，没有涉及多个公式的组合或复杂的推导过程。虽然需要进行单位转换和数值计算，但整体难度在该题型内属于中等偏下。" + }, + { + "idx": 2819, + "question": "There is a nickel-based alloy specimen with a cross-section of 10mm×10mm and a length of 40mm. The tensile test results are shown in the table below. Calculate its tensile strength σb.", + "answer": "σb = 127600 / (10 × 10 × 10^-6) = 1.276 GPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，通过给定的数据和公式计算出拉伸强度σb的值。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即通过给定的力和面积计算拉伸强度，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于最简单难度，仅需单一公式（σb=F/A）直接计算，且题目已提供所有必要数据，无需额外转换或推导步骤。属于基本公式套用级别，完全符合等级1\"单一公式直接计算\"的定义。" + }, + { + "idx": 2820, + "question": "It is known that the porosity of sintered $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ is $5\\\\%$, and its $E=370\\\\mathrm{GPa}$. If another sintered $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ has $E=270\\\\mathrm{GPa}$, find its porosity.", + "answer": "The relationship between the $\\\\pmb{E}$ of ceramic materials and their pore volume fraction $\\\\varphi$ can be expressed by the following equation: $$E=E_{\\\\circ}(1-1.9\\\\varphi+0.9\\\\varphi^{2})$$where $E_{0}$ is the elastic modulus of the material without pores. Substituting the known conditions into the above equation, we obtain $$E_{\\\\circ}={\\\\frac{E}{1-1.9{\\\\varphi}+0.9{\\\\varphi}^{2}}}={\\\\frac{370\\\\times10^{\\\\vartheta}}{1-1.9\\\\times0.05+0.9\\\\times(0.05)^{2}}}=407.8({\\\\mathrm{GPa}})$$$$270\\\\times10^{9}=407.8\\\\times10^{9}(1-1.9\\\\varphi_{1}+0.9\\\\varphi_{1})$$Thus, $\\\\varphi_{1}=19.61\\\\%$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解孔隙率，答案中展示了具体的计算步骤和公式代入过程，符合计算题的特征。 | 知识层次: 题目需要应用给定的公式进行多步计算，涉及数值代入和求解过程，需要理解弹性模量与孔隙率之间的关系，并进行综合分析。虽然不涉及复杂的推理或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要应用给定的公式进行多步计算，包括求解无孔隙材料的弹性模量E0，再代入新的弹性模量值求解孔隙率。虽然计算步骤较多，但公式直接给出，且不涉及复杂变量或迭代求解，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 2821, + "question": "A nickel-based alloy specimen with a cross-section of 10mm×10mm and a length of 40mm was subjected to a tensile test, and the results are shown in the table below. Calculate its elastic modulus E.", + "answer": "E = (86200 / (10 × 10 × 10^-6)) / ((40.2 - 40) / 40) = 172.4 GPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解弹性模量E，答案也是一个具体的数值计算结果。 | 知识层次: 题目要求应用基本公式（弹性模量计算公式）进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中，该题目属于单一公式直接计算的难度等级。题目要求计算弹性模量E，只需要应用基本的弹性模量公式E = (F/A) / (ΔL/L)，其中F/A是应力，ΔL/L是应变。题目提供了所有必要的数值，计算过程简单直接，无需多个公式组合或复杂推导。因此，在该题型内属于最简单的难度等级。" + }, + { + "idx": 2822, + "question": "A nickel-based alloy specimen with a cross-section of 10mm×10mm and a length of 40mm was subjected to a tensile test, and the results are shown in the table below. Calculate its elongation δ.", + "answer": "δ = (50.2 - 40) / 40 = 25.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解伸长率δ，答案是一个具体的计算结果（25.5%），符合计算题的特征。 | 知识层次: 题目仅需应用基本的伸长率计算公式进行一步计算，不涉及多步运算或复杂分析，属于简单应用层次。 | 难度: 在计算题中属于最低难度等级，仅需应用单一伸长率公式δ=(L-L0)/L0进行直接计算，无需任何公式组合或复杂推导，属于基础力学性能计算中最简单的类型。题目已明确给出原始长度和最终长度，计算过程仅涉及一步减法与除法运算。" + }, + { + "idx": 2823, + "question": "Analyze the influence of molecular chain flexibility on the viscous flow temperature of polymers", + "answer": "From the relationship between chain segments and the energy barrier difference (potential barrier) Lp=l exp{Δε/kT}, it can be seen that the better the molecular chain flexibility, the lower the potential barrier (Δε) for internal rotation, and the shorter the flow unit segments. According to the segmental motion mechanism of polymer flow, flexible molecules require smaller free volume space for flow, thus viscous flow can occur at relatively lower temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析分子链柔顺性对聚合物粘流温度的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析分子链柔顺性对聚合物粘流温度的影响，涉及分子链段运动机制、能垒差（势垒）与温度的关系等复杂概念的综合运用和推理分析。需要理解分子链柔顺性与势垒的关系，并将其与粘流温度的变化联系起来，思维过程较为深入。 | 难度: 在简答题-复杂分析题型中，该题目要求对分子链柔性与粘流温度的关系进行机理深度解释。需要综合运用聚合物流动的链段运动机制、自由体积理论等知识，并推导能垒差与流动单元段长的定量关系。虽然不涉及多因素交互作用的全面分析(等级5特征)，但已超出基础概念解释层面，属于需要深入理解分子运动机理的难度层级。" + }, + { + "idx": 2824, + "question": "Given that the glass transition temperature of polyethylene is $T_{\\\\mathrm{g}}=-68~\\\\mathrm{^\\\\circ C}$, that of polyoxymethylene is $\\\\mathcal{T}_{\\\\varepsilon}=-83^{\\\\circ}\\\\mathrm{C}$, and that of polydimethylsiloxane is $T_{\\\\mathrm{{s}}}=-128^{\\\\circ}\\\\mathrm{{C}}$, analyze the general relationship between the flexibility of polymer chains and their $T_{\\\\mathfrak{s}}$.", + "answer": "The repeating unit structure of polyethylene is: —CH2—CH2—; the repeating unit structure of polyoxymethylene is: —$\\\\mathbf{CH_{3}}$—O—, and the repeating unit structure of polydimethylsiloxane is: —Si$\\\\mathbf{CH_{3}}$$\\\\mathbf{CH_{3}}$—O—. Since the internal rotation of the Si—O bond is easier than that of the C—O bond, and the internal rotation of the C—O bond is easier than that of the C—C bond, the easier the internal rotation, the better the flexibility of the molecular chain. It can thus be concluded that as flexibility increases, the temperature $T_{g}$ decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析聚合物链的柔韧性与玻璃化转变温度之间的关系，并提供文字解释和论述。答案中给出了详细的分子结构分析和理论解释，符合简答题的特征。 | 知识层次: 题目要求分析聚合物链的柔韧性与玻璃化转变温度（Tg）之间的关系，涉及多个聚合物材料的比较和内部旋转能力的解释。这需要综合运用材料科学中的高分子物理知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题中属于机理深度解释难度，需要理解聚合物链柔性与玻璃化转变温度的关系，并分析不同化学键内旋转难易程度对链柔性的影响。题目要求综合运用高分子物理知识，解释现象背后的机理，属于较复杂的分析推理题。" + }, + { + "idx": 2825, + "question": "An aluminum rod with a length of 20m and a diameter of 14mm is drawn through a die with an aperture of 12.7mm. Calculate the length of the aluminum rod after drawing.", + "answer": "During the deformation process, the total volume remains unchanged. Let the length after drawing be L, then π(14.0/2)^2×20×10^3 = π(12.7/2)^2×L×10^3, L=24.3m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝棒在拉伸后的长度，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即利用体积不变原理进行单步计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅涉及体积不变原理的直接应用，使用一个简单的几何公式（圆柱体积公式）即可解决，无需多个公式组合或复杂计算步骤。解题过程直接套用公式并代入数值，属于该题型内最基础的难度水平。" + }, + { + "idx": 2826, + "question": "A 14mm diameter aluminum rod is drawn through a die with an aperture of 12.7mm. Calculate the cold working rate that this aluminum rod will undergo.", + "answer": "The cold working rate is the reduction in cross-sectional area: φ=[π(14.0/2)^2-π(12.7/2)^2]/π(14.0/2)^2=18%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解冷加工率，答案是一个具体的百分比数值，需要通过计算得出。 | 知识层次: 题目涉及基本的公式应用和简单计算，即通过给定的直径计算横截面积的变化率，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需套用单一公式（面积变化率公式）进行直接计算，无需多步推导或组合公式。题目提供了所有必要参数，计算过程仅涉及基本代数运算，属于典型的\"直接套用公式\"类型。" + }, + { + "idx": 2827, + "question": "Determine the engineering strain εe and true strain εT when the length increases from L to 1.1L, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (1.1 - 1)L / L = 10%; εT = ln(1.1L / L) = 9.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（工程应变和真实应变），并应用相关公式（工程应变公式和真实应变公式）。答案以数值结果呈现，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即工程应变和真实应变的计算，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一工程应变和真实应变的定义公式，进行简单数值计算。题目没有涉及多步骤运算或公式组合，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2828, + "question": "Determine the engineering strain εe and true strain εT when compressed from h to 0.9h, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (0.9 - 1)h / h = -10%; εT = ln(0.9h / h) = -10.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（工程应变和真实应变）并应用相关公式，答案也以具体计算结果呈现。虽然最后需要解释哪种应变更好反映变形特性，但主要考察的是计算能力。 | 知识层次: 题目涉及基本的应变计算公式应用，仅需直接套用工程应变和真实应变的定义公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（工程应变和真实应变公式）进行简单数值计算，无需组合公式或复杂推导。解题步骤仅涉及基本代数运算和对数运算，属于该题型内最基础的应用层级。" + }, + { + "idx": 2829, + "question": "Determine the engineering strain εe and true strain εT when elongating from L to 2L, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (2 - 1)L / L = 100%; εT = ln(2L / L) = 69.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算工程应变和真实应变）并应用相关公式（工程应变和真实应变的定义公式），答案也以数值结果呈现。虽然题目最后要求解释哪种应变更好反映真实变形特性，但主要部分仍是计算任务。 | 知识层次: 题目要求应用工程应变和真实应变的基本公式进行计算，并比较两者的差异。虽然涉及两个不同的应变定义，但计算过程直接且无需多步推理或综合分析，属于基本公式的直接应用。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（工程应变和真实应变的定义公式）进行简单计算，无需组合多个公式或进行复杂推导。" + }, + { + "idx": 2830, + "question": "Determine the engineering strain εe and true strain εT when compressed from h to 0.5h, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (0.5 - 1)h / h = -50%; εT = ln(0.5h / h) = -69.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（工程应变和真实应变），并应用相关公式（应变计算公式）。答案也以数值结果呈现，符合计算题的特征。 | 知识层次: 题目要求应用工程应变和真实应变的公式进行计算，属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算，需要掌握工程应变和真实应变的基本公式，并进行直接套用和简单计算。虽然涉及两个公式，但都是基础且直接的应用，没有复杂的组合或推导过程。" + }, + { + "idx": 2831, + "question": "Compare the differences between engineering strain and true strain under tension and compression, and explain which one better reflects the true deformation characteristics", + "answer": "εT ≠ εe, the larger the deformation, the greater the difference between εT and εe. Comparing the cases of elongation to 2L and compression to 0.5h, the absolute values of true strain are equal, while the absolute values of engineering strain are not equal. Therefore, true strain better reflects the true deformation characteristics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较和解释工程应变和真实应变在拉伸和压缩下的差异，并说明哪一种更能反映真实的变形特性。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较工程应变和真实应变在拉伸和压缩情况下的差异，并解释哪一种更能反映真实的变形特性。这需要理解两种应变的概念，进行对比分析，并给出合理的解释。虽然不涉及复杂的计算或深度推理，但需要多步的概念关联和综合分析，因此属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对工程应变和真实应变在拉伸和压缩情况下的差异进行比较，并解释哪一种更能反映真实的变形特性。这需要多角度分析论述，包括理解两种应变的定义、计算差异、在不同变形条件下的表现，以及综合判断哪种应变更准确反映变形特性。虽然不涉及深度关联性分析，但需要综合运用多个概念和计算步骤，因此属于等级4的难度。" + }, + { + "idx": 2832, + "question": "For a pre-annealed metallic polycrystal, the true stress-strain curve in the plastic region can be approximately expressed as ∇σ_T= kε_T^n, where k and n are empirical constants; known as the strength coefficient and strain hardening exponent, respectively. Derive the mathematical relationship between the strain hardening exponent n and the strain hardening rate (θ=dσ_T/dε_T).", + "answer": "θ=dσ_T/dε_T=n kε_T^(n-1). Substituting σ_T=kε_T^n, we obtain θ=nσ_T/ε_T.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导数学关系式，涉及公式应用和数学运算，答案以数学表达式呈现 | 知识层次: 题目需要理解应变硬化指数和应变硬化速率之间的关系，并进行多步推导和公式应用，涉及概念关联和综合分析。 | 难度: 在计算题中属于多步骤计算过程难度。题目要求从给定的应力-应变关系出发，通过求导和代数替换推导出应变硬化指数与应变硬化率之间的关系。虽然涉及微分和变量替换，但步骤明确且计算过程直接，不需要处理复杂多变量或高级数学技巧，符合等级2的多步骤计算特征。" + }, + { + "idx": 2833, + "question": "For a pre-annealed metal polycrystal, the true stress-strain curve in the plastic region can be approximately expressed as ∇σ_T= kε_T^n, where k and n are empirical constants, referred to as the strength coefficient and strain hardening exponent, respectively. If there are two materials, A and B, with roughly equal k values, but n_A=0.5 and n_B=0.2, which material has higher hardening capability and why?", + "answer": "For σ_T=kε_T^n, dσ_T=n kε_T^(n-1)dε_T, so dσ_T/dε_T=n kε_T^(n-1). When ε_T<1, if 0. Along which direction of tension (or compression) will slip not occur?", + "answer": "Based on the characteristics of the slip systems in the magnesium oxide structure, slip will not occur only when tension (or compression) is applied along a direction perpendicular to all (110) planes. From the standard projection diagram of the cubic crystal system (001), it can be seen that there is no pole that is $90^\\mathfrak{o}$ away from all (110) poles. Therefore, for magnesium oxide, there is no direction of tension (or compression) that will not cause slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，没有提供选项或要求进行数值计算，而是需要基于材料科学知识进行分析和描述。 | 知识层次: 题目要求分析MgO晶体在特定应力方向下的滑移行为，需要综合运用晶体学知识（如标准投影图）和滑移系统特性进行推理分析。涉及多步骤逻辑判断（如判断是否存在与所有(110)面垂直的方向），并需要解释滑移不发生的条件，属于复杂分析层次。 | 难度: 在简答题（复杂分析类）中属于最高难度等级。该题目要求：" + }, + { + "idx": 2838, + "question": "A cross-slip system consists of one slip direction and two crystallographic planes containing this slip direction, such as the (101) [111] (110) in bcc crystals. Write down three other cross-slip systems of the same type for bcc crystals.", + "answer": "From the standard projection diagram of the cubic crystal system (001), it can be found that the other three cross-slip systems of the same type for bcc crystals are: (101) [111] (110), (011) [111] (110), (110) [111] (101).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出三个其他交叉滑移系统，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求学生在理解bcc晶体滑移系统的基础上，通过标准投影图找出其他类似的交叉滑移系统。这需要学生不仅记忆基本的滑移系统概念，还需要理解滑移方向和晶面之间的关系，并能够应用这些知识进行综合分析。虽然题目不涉及复杂的计算或深度推理，但需要一定的概念关联和多步思考。 | 难度: 在简答题中属于中等难度，需要理解交叉滑移系统的概念，并能从标准投影图中识别出其他符合条件的滑移系统。虽然题目要求写出三个其他交叉滑移系统，但解题步骤相对直接，主要涉及对晶体学知识的应用和综合分析，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2839, + "question": "For a bcc crystal with a critical resolved shear stress of 60MPa on the (110)[111] slip system, how much stress must be applied in the [001] direction to initiate slip?", + "answer": "Vector dot product:\\n[001] direction:\\na⋅b=|a|⋅|b|cosθ⇒cosθ=(a⋅b)/(|a|⋅|b|)=(a1b1+a2b2+a3b3)/(√(a1²+a2²+a3²)⋅√(b1²+b2²+b3²))\\ncosλ=1/(1×√3)=1/√3,\\ncosφ=0/(1×√2)=0\\nσ=τt/(cosλcosφ)=60/((1/√3)×0)=∞,\\nTherefore, slip cannot be initiated in this direction no matter how much stress is applied.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如向量点积和临界分切应力公式）来确定在特定方向上需要施加的应力值，以启动滑移。答案中包含了具体的数学推导和计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括向量点积、方向余弦计算和临界分切应力公式的应用。虽然不涉及复杂的综合分析或创新应用，但需要理解晶体滑移系统的基本原理，并能正确应用相关公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体滑移系统的概念，掌握向量点积的计算方法，并能正确应用临界分切应力公式。解题步骤包括方向余弦计算、分切应力公式应用以及特殊情况分析，涉及多步计算和概念关联，但不需要处理复杂多变量情况。" + }, + { + "idx": 2841, + "question": "For a Cu single crystal, the stress σ corresponding to 1% plastic deformation is 40 MPa. From the standard projection diagram of the cubic crystal system (001), it is found that when the tensile axis is [111], the activated slip systems are (111)[011] and another 5 equivalent slip systems. The orientation factor for activating any one of these slip systems can be calculated as cosφcosλ=1/3×2/√6=2/3√6. Determine the dislocation density after 1% plastic deformation. Given τ0=700 kPa, G=42×10^3 MPa, b=0.256 nm, α=0.4.", + "answer": "τ=σcosφcosλ=40×2/3√6=10.80 MPa. From τ=τ0+αGb√ρ, the dislocation density can be calculated as ρ=((τ−τ0)/αGb)^2=((10.89×10^3−700)/(0.4×42×10^6×0.256×10^−9))^2=5.61×10^8 cm−2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定位错密度，解答过程中涉及多个计算步骤和公式代入，最终得出具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括应力与位错密度的关系、晶体滑移系统的激活、取向因子的计算等，需要综合分析多个知识点并进行数值计算。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及应力计算、取向因子应用、位错密度公式推导等多个步骤，且需要综合分析晶体滑移系统、材料常数等参数。虽然计算过程明确，但步骤较多且需要准确应用公式，属于中等偏上的难度。" + }, + { + "idx": 2842, + "question": "The critical resolved shear stress of a single crystal at room temperature is $\\\\tau_{\\\\mathfrak{c}}=7.9\\\\times10^{5}~\\\\mathrm{Pa}$. If a tensile test is performed on an aluminum single crystal sample at room temperature with the tensile axis in the [123] direction, calculate the stress required to cause the sample to yield.", + "answer": "Al has an fcc crystal structure, and its slip system is $\\\\{111\\\\}\\\\langle110\\\\rangle$. When the external force axis is [123], according to the standard projection diagram of the cubic crystal system, the first activated slip system is (111)[101]. Therefore, $\\\\phi$ is the angle between [123] and the normal [111] of the (111) crystal plane, and $\\\\lambda$ is the angle between [123] and [101]. Thus, $$\\\\cos\\\\phi{=}\\\\frac{-1+2+3}{\\\\sqrt{14}\\\\times\\\\sqrt{3}}=\\\\frac{4}{\\\\sqrt{42}}$$ $$\\\\cos\\\\lambda{=}\\\\frac{1+0+3}{\\\\sqrt{14}\\\\times\\\\sqrt{2}}=\\\\frac{2}{\\\\sqrt{7}}$$ $$\\\\sigma_{\\\\mathrm{{s}}}=\\\\frac{\\\\tau_{C}}{\\\\cos{\\\\phi}\\\\cos\\\\lambda}=\\\\frac{7.9\\\\times10^{5}}{\\\\frac{4}{\\\\sqrt{42}}\\\\times\\\\frac{2}{\\\\sqrt{7}}}=1.69({\\\\mathrm{MP}}a)$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及角度计算、应力计算等具体数值操作，最终给出一个具体的应力值作为答案。 | 知识层次: 题目需要进行多步计算，包括确定滑移系统、计算角度、应用临界分切应力公式等，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构、滑移系统、角度计算等多个概念，并进行多步计算和综合分析。虽然涉及的知识点较多，但计算步骤相对明确，属于中等应用层次。" + }, + { + "idx": 2843, + "question": "For a bcc crystal with a critical resolved shear stress of ${60}\\\\mathbf{M}\\\\mathbf{Pa}$ on the (110)[111] slip system, how much stress must be applied in the [001] and [010] directions to initiate slip?", + "answer": "$A C$ and $A^{\\\\prime}C^{\\\\prime}$ are the distances between two adjacent slip planes in the crystal before and after stretching, respectively. Since the distance between slip planes remains unchanged before and after stretching, i.e., $A C{=}A^{\\\\prime}C^{\\\\prime}$, we have \\n$$\\n\\\\epsilon={\\\\frac{A^{\\\\prime}B^{\\\\prime}-A B}{A B}}={\\\\frac{{\\\\frac{A^{\\\\prime}C^{\\\\prime}}{\\\\sin30^{\\\\circ}}}-{\\\\frac{A C}{\\\\sin45^{\\\\circ}}}}{\\\\frac{A C}{\\\\sin45^{\\\\circ}}}}\\n$$\\n\\n$$\\n={\\\\frac{2-{\\\\sqrt{2}}}{\\\\sqrt{2}}}=41.4\\\\%\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算在特定方向上施加的应力以引发滑移，答案中包含了详细的数学推导和数值计算过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括临界分切应力的计算、晶体学方向的确定以及应力分量的计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用材料科学中的基本概念和公式进行中等难度的应用。 | 难度: 在计算题中属于综合性计算问题，需要理解临界分切应力的概念，并应用施密特定律进行多步计算。题目涉及晶体滑移系统的方向分析和应力分解，需要将多个概念关联起来进行综合分析。虽然计算步骤明确，但需要对晶体学方向有较好的理解才能正确应用公式。" + }, + { + "idx": 2844, + "question": "When a single crystal sample of Mg is subjected to tensile testing, the three slip directions form angles of $38^{\\\\circ}, 45^{\\\\circ}, 85^{\\\\circ}$ with the tensile axis, respectively, while the normal to the basal plane forms an angle of $60^{\\\\circ}$ with the tensile axis. If plastic deformation is first observed at a tensile stress of $2.05\\\\,\\\\mathrm{MPa}$, what is the critical resolved shear stress of $\\\\mathrm{Mg}$?", + "answer": "The slip plane of $\\\\mathrm{Mg}$ is the (0001) plane (basal plane). According to the resolved shear stress formula $\\\\tau = \\\\sigma \\\\cos\\\\lambda \\\\cos\\\\phi$, when $\\\\phi$ is fixed at $60^{\\\\circ}$, the smaller $\\\\lambda$ is, the larger $\\\\tau$ becomes. Therefore, under tensile stress, the crystal slips along the slip direction that forms a $38^{\\\\circ}$ angle with the tensile axis, resulting in plastic deformation. Thus, the critical resolved shear stress of $\\\\mathrm{Mg}$ is $$\\\\tau_{\\\\mathrm{c}} = \\\\sigma_{\\\\mathrm{s}} \\\\cos\\\\lambda \\\\cos\\\\phi = 2.05 \\\\times \\\\cos60^{\\\\circ} \\\\times \\\\cos38^{\\\\circ}$$ $$= 2.05 \\\\times 0.5 \\\\times 0.788 = 0.8077\\\\,(\\\\mathrm{MPa})$$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解临界分切应力，解答过程中涉及到了具体的数学运算和公式推导。 | 知识层次: 题目主要考查临界分切应力的基本公式应用，涉及简单的角度计算和数值代入。虽然需要理解滑移方向和滑移面的概念，但整体思维过程较为直接，属于基本公式的直接套用和简单计算。 | 难度: 在计算题中属于简单公式应用计算难度。题目虽然涉及角度选择和临界分切应力的概念，但解题过程仅需套用单一公式（分切应力公式），并进行简单的三角函数计算。不需要多个公式组合或复杂推导，属于该题型内中等偏下的难度水平。" + }, + { + "idx": 2845, + "question": "For FCC and BCC metals during plastic deformation, the relationship between flow stress and dislocation density ρ is given by τ=τ0+αGb√ρ, where τ0 is the stress required for dislocation motion without interference from other dislocations, i.e., the shear stress without work hardening, G is the shear modulus, b is the Burgers vector of the dislocation, and α is a material-dependent constant, α=0.3∼0.5. If a Cu single crystal has τ0=700 kPa, initial dislocation density ρ0=10^5 cm−2, G=42×10^3 MPa, b=0.256 nm, α=0.4, what is the critical resolved shear stress?", + "answer": "τ=τ0+αGb√ρ0=700+0.4×42×10^6×0.256×10^−9×√10^9=836 kPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（临界分切应力）。解答过程涉及公式应用和单位换算，属于典型的计算题类型。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的公式和参数进行数值计算，无需多步推理或综合分析。虽然涉及一些材料科学的基本概念（如临界分切应力、位错密度等），但解题过程主要是套用公式和代入数值，属于简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目直接给出了所需的公式τ=τ0+αGb√ρ，并且所有参数都已明确提供，只需要将这些数值代入公式进行简单的计算即可得到答案。没有涉及多个公式的组合或复杂的推导过程，属于最基础的计算题类型。" + }, + { + "idx": 2846, + "question": "Indicate the easy slip plane and easy slip direction of Cu crystal, and calculate the slip plane spacing, atomic spacing in the slip direction, and lattice resistance. (Given G_Cu=48.3GPa, ν=0.3)", + "answer": "Cu has an fcc structure, with the easy slip plane being {111} and the easy slip direction being <110>. The slip plane spacing d_(111)=a/√3, and the atomic spacing in the slip direction b=√2/2a. The lattice resistance τ_PN=(2×48.3×10^9)/(1-0.3)×exp[-2π(a/√3)/((1-0.3)(√2/2)a)]=90.45MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行具体的数值计算（计算滑移面间距、滑移方向原子间距和晶格阻力），并给出了计算公式和参数（G_Cu=48.3GPa, ν=0.3），答案也展示了完整的计算过程和结果。这符合计算题的特征。 | 知识层次: 题目需要理解Cu晶体的fcc结构，识别易滑移面和方向，并应用公式计算滑移面间距、原子间距和晶格阻力。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶体结构、滑移系、晶面间距计算、晶向间距计算以及晶格阻力计算等多个知识点，并进行多步骤的数值计算和公式应用。虽然涉及多个概念和计算步骤，但整体流程较为明确，属于中等应用层次的计算题。" + }, + { + "idx": 2847, + "question": "Calculate the volume fraction φ_Fe3C of the Fe3C phase in 40 steel, given the mass fraction of carbon w_c=0.004.", + "answer": "φ_Fe3C = 0.004 / 0.0667 = 0.06", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Fe3C相的体积分数），并给出了具体的质量分数和计算公式，答案也是通过数值计算得出的具体数值。 | 知识层次: 题目考查基本公式应用和简单计算，直接套用质量分数和体积分数的转换公式，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（体积分数=质量分数/相密度比）进行一步计算，无需任何推导或组合公式。解题步骤极其简单，属于基础概念的直接应用。" + }, + { + "idx": 2848, + "question": "Indicate the easy slip plane and easy slip direction of α-Fe crystal, and calculate the slip plane spacing, atomic spacing in the slip direction, and lattice resistance. (Given G_α-Fe=81.6GPa, ν=0.3)", + "answer": "α-Fe has a bcc structure, with the slip plane being {110} and the easy slip direction being <111>. The slip plane spacing d_(110)=a/√2, and the atomic spacing in the slip direction b=√3/2a. The lattice resistance τ_PN=(2×81.6×10^9)/(1-0.3)×exp[-2π(a/√2)/((1-0.3)(√3/2)a)]=152.8MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算滑移面间距、滑移方向上的原子间距和晶格阻力，涉及数值计算和公式应用。答案中给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要理解α-Fe晶体的bcc结构，识别易滑移面和滑移方向，并应用给定参数进行多步计算（包括滑移面间距、滑移方向原子间距和晶格阻力的计算）。这涉及到概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构、滑移面和滑移方向的概念，并进行多步计算，包括滑移面间距、原子间距和晶格阻力的计算。虽然涉及多个步骤和公式应用，但整体计算过程相对明确，属于中等应用层次。" + }, + { + "idx": 2849, + "question": "Calculate the shear strength τ of 40 steel, given that the shear modulus of Fe is G=7.9×10^4 MPa, the lattice constant of α-Fe is a=0.28 nm, and the average spacing of Fe3C particles is λ=41.2 μm.", + "answer": "τ = (G * b) / λ = (G * (√3/2) * a) / λ = (7.9×10^4 * (√3/2) * 0.28×10^-3) / 41.2 = 0.465 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及剪切模量、晶格常数和粒子间距的综合应用，需要理解材料力学性能与微观结构之间的关系，并正确应用公式进行计算。虽然计算过程较为直接，但需要关联多个概念和参数，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（剪切模量、晶格常数、粒子间距）并进行多步计算（包括单位转换和公式推导）。虽然计算步骤较多，但变量关系明确，公式应用直接，因此属于中等偏上难度而非最复杂的多变量计算问题。" + }, + { + "idx": 2850, + "question": "A single crystal of A1 is made into a tensile specimen (with a cross-sectional area of 9 mm²) for room-temperature tensile testing. The tensile axis forms an angle of $36.7^{\\\\circ}$ with [001], $19.1^{\\\\circ}$ with [011], and $22.2^{\\\\circ}$ with [111]. The load at the onset of yielding is 20.4 N. Determine the resolved shear stress on the primary slip system.", + "answer": "From the known tensile axis direction, the primary slip system can be determined as (111)[101] using the standard projection diagram of the cubic crystal system (001). Let the stress axis direction be $[u\\\\tau\\\\mathbf{w}]$. From the given conditions, we have $$\\\\cos36.7^{\\\\circ}=\\\\frac{w}{\\\\sqrt{u^{2}+v^{2}+w^{2}}}$$$$\\\\cos19.1^{\\\\circ}=\\\\frac{v+w}{\\\\sqrt{2}\\\\sqrt{u^{2}+v^{2}+w^{2}}}$$$$\\\\cos22.2^{\\\\circ}={\\\\frac{u+v+w}{{\\\\sqrt{3}}{\\\\sqrt{{u}^{2}+{v}^{2}+{w}^{2}}}}}$$Let $u^{2}+v^{2}+w^{2}=1$, then solving gives $\\\\scriptstyle\\\\pmb{u}=0.26$, $v{=}0.54$, ${\\\\mathfrak{w}}{=}0.80$. Thus, $\\\\cos\\\\lambda={\\\\frac{0.26+0.80}{\\\\sqrt{2}}}=0.75$ $$\\\\cos\\\\phi=\\\\frac{-0.26+0.54+0.80}{\\\\sqrt{3}}=0.62$$$$\\\\tau=\\\\sigma\\\\cos\\\\lambda\\\\cos\\\\phi=\\\\frac{20.4}{9\\\\times10^{-6}}\\\\times0.75\\\\times0.62=1.01(\\\\mathrm{MPa})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定解析剪切应力，解答过程中涉及多个步骤的数学运算和方向余弦的计算，最终得出具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要确定主滑移系统、计算方向余弦、应用分解剪应力公式等综合分析过程，但不需要复杂的机理解释或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求确定主滑移系统并计算分解剪应力，涉及方向余弦的计算、应力分解和材料科学中的晶体学知识。虽然计算步骤明确，但需要综合应用多个概念和公式，属于中等偏上的难度。" + }, + { + "idx": 2851, + "question": "Calculate the average spacing λ of Fe3C particles, given the number of Fe3C particles per unit volume N_v=1.43×10^13 1/m^3.", + "answer": "λ = (1 / N_v)^(1/3) = (1 / 1.43×10^13)^(1/3) = 4.12×10^-5 m = 41.2 μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算并应用公式来求解Fe3C颗粒的平均间距λ，答案也是通过计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目仅涉及单一公式的直接套用和简单数值计算，不需要多步推导或综合分析，属于基本公式应用范畴。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（λ = (1 / N_v)^(1/3)）并进行简单数值计算，无需任何变形或组合步骤，完全符合等级1\"单一公式直接计算\"的定义。" + }, + { + "idx": 2852, + "question": "Given that a straight dislocation line in an alloy is hindered by second-phase particles with a spacing of $\\\\pmb{\\\\lambda}$ during its motion, prove that the shear stress required for the dislocation to continue moving via the bypass mechanism is: 2T-Bln(2), where T is the line tension; b is the Burgers vector; $_{!G}$ is the shear modulus; $\\\\pmb{\\\\gamma}_{0}$ is the radius of the second-phase particle; and $B$ is a constant.", + "answer": "Strengthening effect of non-deformable particles: When a moving dislocation encounters non-deformable particles, it will be blocked, causing the dislocation line to bend around them. Since the dislocation has line tension $\\\\pmb{T}$, bending the dislocation line requires overcoming the effect of its line tension. The shear stress required for the dislocation line to bypass particles with spacing $\\\\lambda$ is The line tension of a dislocation is analogous to the surface tension of a liquid and can be represented by the energy per unit length of the dislocation. The energy per unit length of the dislocation $T=E=\\\\frac{G b^{2}}{4\\\\pi k}\\\\ln\\\\frac{\\\\bar{R}}{r_{0}}$ Gn. Substituting this into the above equation, then", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过公式推导和计算来证明一个具体的剪切应力表达式，涉及材料科学中的位错理论和强化机制，需要应用给定的参数和公式进行推导和计算。 | 知识层次: 题目要求证明一个关于位错绕过第二相粒子所需的剪切应力的公式，这涉及到位错理论、线张力概念、Burgers矢量、剪切模量等多个复杂概念的关联和综合分析。此外，还需要理解位错绕过粒子的机制，并进行多步推导和公式应用，体现了较高的认知能力层次和思维深度。 | 难度: 在计算题-复杂分析题型中，该题目属于机理相关复杂计算难度。题目要求证明位错绕过第二相颗粒所需的剪切应力公式，涉及位错线张力、柏氏矢量、剪切模量等多个材料科学核心概念的整合运用。解题过程需要：" + }, + { + "idx": 2853, + "question": "For an Al2O3 specimen with a circular cross-section in a three-point bending test, the cross-sectional radius r=3.5mm, the span between the two supports is 50mm, and it fractures under a load of 950N. Calculate the fracture strength σfs of the material.", + "answer": "σfs = (Ff * L) / (π * r^3) = (950 * 50 * 10^-3) / (π * (3.5 * 10^-3)^3) = 352.6 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体数值代入和运算，最终给出一个具体的计算结果。 | 知识层次: 题目考查基本公式的直接应用和简单计算，涉及三点弯曲测试的断裂强度公式，计算过程直接套用公式即可完成，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目直接给出了所有必要的参数（载荷、跨距、半径），只需套用三点弯曲测试的断裂强度公式σfs = (Ff * L) / (π * r^3)即可完成计算，无需额外的公式组合或复杂推导。计算过程仅涉及基本代数运算和单位换算，属于该题型下最基础的难度级别。" + }, + { + "idx": 2854, + "question": "For an Al2O3 specimen with a square cross-section of side length 12mm in a three-point bending test, the distance between the two supports is 40mm. Given the material's fracture strength σfs=352.6 MPa, find the load at fracture Ff.", + "answer": "Ff = (2 * σfs * b^3) / (3 * L) = (2 * 352.6 * 10^6 * (12 * 10^-3)^3) / (3 * 40 * 10^-3) = 10154.9 N", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解断裂载荷Ff，答案是一个具体的数值结果，解答过程涉及公式代入和单位转换，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及三点弯曲测试中的断裂强度公式直接套用和单位换算，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目直接给出了所需的公式和参数，只需要进行简单的数值代入和计算即可得到结果，无需额外的推导或组合多个公式。" + }, + { + "idx": 2855, + "question": "Calculate the number of Fe3C particles per unit volume N_v, given the volume fraction of Fe3C phase φ_Fe3C=0.06 and the radius of spherical cementite particles r=10×10^-6 m.", + "answer": "N_v = φ_Fe3C / (4/3 * π * r^3) = 0.06 / (4/3 * π * (10×10^-6)^3) ≈ 1.43×10^13 (1/m^3)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，并给出了具体的公式应用步骤和最终的计算结果。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需理解体积分数和球形体积公式即可完成计算。 | 难度: 在计算题中属于单一公式直接计算，仅需套用给定公式并代入已知数值即可得出结果，无需额外的推导或组合多个公式。" + }, + { + "idx": 2856, + "question": "For many polymer materials, their tensile strength σi is a function of the number-average relative molecular mass Mn̅: the formula is given by σi = σ0 - A / Mn̅, where σ0 is the tensile strength at infinite molecular weight, and A is a constant. Given two types of poly(methyl methacrylate) with number-average relative molecular masses of 4×10^4 and 6×10^4, the corresponding tensile strengths are 107 MPa and 170 MPa, respectively. Determine the tensile strength σb when the number-average relative molecular mass is 3×10^4.", + "answer": "The equations are: 107 = σ0 - A / (4×10^4), 170 = σ0 - A / (6×10^4). Solving these gives σ0 = 296 MPa and A = 7.56×10^6. Therefore, σb = σ0 - A / Mn̅ = 296 - 7.56×10^6 / (3×10^4) = 44 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（44 MPa）。解答过程涉及解方程组和代入计算，符合计算题的特征。 | 知识层次: 题目需要应用给定的公式进行多步计算，涉及解方程组和数值代入，需要一定的综合分析能力，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要建立并解方程组，涉及多步计算和概念关联。虽然计算过程相对直接，但需要理解公式含义并正确应用，属于中等应用层次中的典型题目。" + }, + { + "idx": 2857, + "question": "The recovery activation energy of iron is $88.9\\\\mathrm{kJ/mol}$. If cold-deformed iron is subjected to recovery treatment at $400^{\\\\circ}\\\\mathrm{C}$ to retain 60% of its work hardening, it takes $160\\\\mathfrak{min}$. How much time is needed to achieve the same effect with recovery treatment at $450\\\\mathrm{~C~}$?", + "answer": "$$\\\\frac{t_{1}}{t_{2}}=\\\\mathrm{e}^{-{\\\\frac{Q}{R}(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}})}} , t_{2}={\\\\frac{t_{1}}{\\\\mathrm{e}^{-{\\\\frac{\\\\mathrm{{Q}}}{\\\\scriptscriptstyle{R}}}\\\\big({\\\\frac{1}{T_{2}}}-{\\\\frac{1}{T_{1}}}\\\\big)}}}}={\\\\frac{160}{\\\\mathrm{e}^{-{\\\\frac{80.5}{831}}\\\\big({\\\\frac{1}{723}}-{\\\\frac{1}{673}}\\\\big)}}}=59(\\\\operatorname*{min})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要应用公式进行数值计算，答案给出了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解恢复激活能的概念，并能够正确应用阿伦尼乌斯公式进行温度和时间关系的计算。虽然计算过程较为直接，但需要对公式进行适当变形和单位转换，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、能量单位转换和指数运算。虽然计算步骤明确，但需要正确理解和关联多个概念（如活化能、温度对恢复速率的影响），并准确执行数值计算。相比更简单的单步计算题（等级2），此题要求更高的综合分析能力，但尚未达到复杂多变量计算（等级4）的难度。" + }, + { + "idx": 2858, + "question": "Briefly describe the characteristics of plastic deformation in ceramic materials (crystalline).", + "answer": "In general, compared to metallic materials and high molecular materials, ceramic materials appear hard and brittle, which is determined by the type of bonding between their atoms. The atoms in ceramic materials are usually bonded by ionic or covalent bonds. In covalently bonded ceramics, atoms are bonded through shared electron pairs, exhibiting directionality and saturation, with relatively high bond energy. During plastic deformation, the movement of dislocations inevitably disrupts the covalent bonds between atoms, resulting in significant lattice resistance (Peierls-Nabarro force). Therefore, covalently bonded ceramics exhibit hard and brittle characteristics. For ionically bonded ceramic materials, there are two scenarios: single crystals (such as NaCl, FeO, etc.) can undergo considerable plastic deformation under compressive stress at room temperature. However, polycrystalline ionically bonded ceramics are often brittle and prone to crack formation at grain boundaries. This is because ionic crystals require alternating positive and negative ion arrangements. Under external forces, when a dislocation moves by one atomic spacing, the strong Coulombic repulsion between like-charged ions makes dislocation movement along directions perpendicular or parallel to the ionic bonds extremely difficult. However, if the dislocation moves along a $45^{\\circ}$ direction rather than horizontally, adjacent crystal planes remain mutually attracted by Coulombic forces during the slip process, resulting in relatively good plasticity. Nevertheless, during the deformation of polycrystalline ceramics, adjacent grains must deform in a coordinated and mutually constrained manner. Due to the limited number of slip systems in ceramics, this is difficult to achieve, leading to cracking at grain boundaries and ultimately brittle fracture. On the other hand, during the heating and cooling processes of sintered ceramic materials, the presence of thermal stresses often leads to the formation of microcracks. Additionally, factors such as corrosion can cause surface cracks. Therefore, inherent cracks are always present to some extent in ceramic materials. Under external forces, severe stress concentration occurs at crack tips. According to elastic mechanics estimates, the maximum stress at a crack tip can reach the theoretical fracture strength. Moreover, since ceramic crystals have few mobile dislocations and dislocation movement is difficult, brittle fracture often occurs once the yield strength is reached. Of course, under tensile or compressive conditions, the mechanical properties of ceramic materials also differ significantly, with compressive strength typically being higher than tensile strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述陶瓷材料塑性变形的特点，答案通过文字解释和论述详细说明了陶瓷材料的塑性变形特性，包括共价键和离子键陶瓷的不同表现、多晶陶瓷的脆性原因等，符合简答题的特征。 | 知识层次: 题目要求对陶瓷材料的塑性变形特性进行详细描述，涉及多种键合类型（离子键和共价键）对塑性变形的影响，以及单晶和多晶陶瓷的不同行为。需要综合分析位错运动、晶界效应、热应力等多方面因素，并解释其机理。这需要较高的认知能力和深度理解，属于复杂分析层次。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求对陶瓷材料的塑性变形特性进行全面分析，涉及共价键和离子键陶瓷的不同变形机理、单晶与多晶的区别、位错运动的限制因素、热应力与微裂纹的影响等多方面内容。解题需要综合运用材料科学、晶体学、力学等多学科知识，并进行深度机理解释和复杂现象分析，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 2859, + "question": "The tensile strength of brittle materials can be expressed by the following formula: \\n\\n$$\\n\\\\sigma_{\\\\mathrm{m}}=2\\\\sigma_{\\\\mathrm{0}}\\\\bigg(\\\\frac{\\\\ell}{r}\\\\bigg)^{\\\\frac{1}{2}}\\n$$\\n\\nWhere, $\\\\sigma_{0}$ is the nominal applied tensile stress; $l$ is the length of the surface crack or half the length of an internal crack; $r$ is the radius of curvature at the crack tip; and $\\\\sigma_{\\\\infty}$ is actually the maximum stress caused by stress concentration at the crack tip. Now assume that the critical length of the surface crack in $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ ceramic is $l = 2\\\\times10^{-3}\\\\mathrm{mm}$, its theoretical fracture strength is $\\\\frac{E}{10}$, where $E$ is the elastic modulus of the material and is $393\\\\mathrm{GPa}$. Calculate: When a tensile stress of $275\\\\mathrm{MPa}$ is applied to the $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ ceramic specimen, what is the critical radius of curvature $r_{\\\\mathfrak{c}}$ at the crack tip that causes fracture?", + "answer": "When the tensile stress reaches the fracture strength of the material ($\\\\frac{E}{10}$), $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ fractures, therefore:\\n\\n$$\\n\\\\frac{E}{10}=2\\\\sigma_{\\\\circ}\\\\left(\\\\frac{\\\\lambda}{r}\\\\right)^{\\\\frac{1}{2}}\\\\Rightarrow r=\\\\frac{400\\\\ l\\\\sigma_{0}^{2}}{E^{2}}\\n$$\\n\\n$$\\nr_{\\\\mathrm{c}}={\\\\frac{400l\\\\sigma_{0}^{2}}{E^{2}}}={\\\\frac{400\\\\times2\\\\times10^{-3}\\\\times(275)^{2}}{(393\\\\times10^{3})^{2}}}=3.9\\\\times10^{-7}(\\\\mathrm{mm})=0.39(\\\\mathrm{nm})\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（临界半径）。解答过程涉及公式推导和单位换算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式的变形和数值代入，同时需要理解断裂强度与裂纹尺寸之间的关系。虽然不涉及复杂的机理分析或创新应用，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要理解公式中各变量的物理意义，进行多步推导和数值计算，涉及单位转换和临界条件的应用。虽然计算步骤明确，但需要综合分析能力和对材料断裂强度概念的理解。" + }, + { + "idx": 2860, + "question": "Given that the yield strengths of pure iron with average grain diameters of $\\\\boldsymbol{1}\\\\mathfrak{mm}$ and $0.0625\\\\mathbf{mm}$ are 112.7MPa and 196$\\\\mathbf{MPa}$ respectively, what is the yield strength of pure iron with an average grain diameter of $0.0196\\\\mathrm{mm}$?", + "answer": "$$\\\\tau={\\\\frac{G b}{\\\\lambda}}={\\\\frac{G{\\\\frac{\\\\sqrt{3}}{2}}a}{\\\\lambda}}={\\\\frac{7.9\\\\times10^{19}\\\\times{\\\\frac{\\\\sqrt{3}}{2}}\\\\times0.28\\\\times10^{-9}}{41.2\\\\times10^{-6}}}=0.465(\\\\mathrm{MPa})$$\\n\\n$$\\\\left\\\\{\\\\begin{array}{l}{{112,7=\\\\sigma_{\\\\circ}+k(1\\\\times10^{\\\\circ})^{-\\\\frac{1}{2}},}}\\\\ {{}}\\\\ {{196=\\\\sigma_{\\\\circ}+k(0.0625\\\\times10^{\\\\circ})^{-\\\\frac{1}{2}}}}\\\\end{array}\\\\right.,$$\\n\\nThe solution is\\n\\n$$\\\\begin{array}{l}{{\\\\pmb{\\\\mathscr{s}}}_{\\\\mathscr{0}}=84,935(\\\\mathrm{MPa})}\\\\ {\\\\backslash_{\\\\pmb{\\\\mathscr{k}}}=0.878}\\\\end{array}$$\\n\\nTherefore, $\\\\sigma_{\\\\ast}=84.935+0.878(0.0196\\\\times10^{-3})^{-\\\\frac{2}{2}}=283.255(\\\\mathrm{MPa})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据计算纯铁在不同晶粒直径下的屈服强度，解答过程中涉及公式应用和数值计算，最终需要得出具体的数值结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及解方程组和数值代入，需要理解屈服强度与晶粒尺寸的关系，并进行综合分析。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，涉及联立方程求解和参数代入。虽然计算过程较为直接，但需要正确理解材料科学中的晶粒尺寸与屈服强度的关系，并准确执行数学运算。相比更简单的单步计算题（等级2），此题需要更多的综合分析能力，但尚未达到复杂多变量计算（等级4）的难度。" + }, + { + "idx": 2861, + "question": "Explain the phenomenon where the cross-sectional area of the neck remains essentially unchanged during uniaxial stretching of polymers.", + "answer": "Many polymers often exhibit instability in uniform deformation during plastic deformation. For example, when a polymer sample is subjected to a uniaxial tensile test, the stress initially increases linearly with strain, and the specimen is uniformly elongated. After the yield point, the strain at a certain part of the specimen suddenly increases faster than the overall strain, causing the originally uniform cross-section to become non-uniform, forming one or several necks. As deformation continues, the necking zone expands and extends along the length of the specimen until the entire specimen's cross-section becomes uniformly thinner. During this deformation process, the stress remains almost constant. This is because, after exceeding the yield strength, the specimen undergoes plastic deformation, and work hardening occurs at the necking region. XRD analysis proves that, whether in the amorphous or crystalline state, the macromolecules in the polymer gradually align along the direction of the external force as deformation increases. Due to the directionality of bonds (mainly covalent bonds), strain hardening occurs after alignment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物在单轴拉伸过程中颈缩现象的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释聚合物在单轴拉伸过程中颈缩现象的机理，涉及塑性变形、屈服点、应变硬化等多个概念的关联和综合分析。需要理解高分子链的排列和键合特性对材料行为的影响，并进行推理分析。这超出了简单记忆或基本应用的范围，属于对复杂现象的机理解释。 | 难度: 在简答题的复杂分析题型中，该题目要求全面分析聚合物单轴拉伸过程中的颈缩现象及其机理。需要综合运用材料科学、力学和聚合物结构知识，解释从屈服点到颈缩扩展的全过程，包括应力-应变关系、分子取向变化和应变硬化等复杂现象。这种深度机理解释和全面现象分析在简答题中属于最高难度等级。" + }, + { + "idx": 2862, + "question": "Explain how pre-deformation degree, original grain size, and metal purity affect the recrystallization temperature.", + "answer": "From the above analysis, it can be seen that increasing the pre-deformation degree and refining the original grain size will cause the $\\boldsymbol{T}_{\\mathtt{R}}$ to decrease. The influence of impurities on $T_{\\mathbf{R}}$ is dual. If the presence of impurities increases the distortion energy and this factor dominates, then metals with lower purity will have a lower $T_{\\tt R}$. Conversely, if the presence of impurities slows down interface migration and this factor dominates, then metals with higher purity will have a lower $T_{\\tt R}$. Different impurity atoms have different effects on $T_{\\mathbf{R}}$. Generally, the presence of a small amount of impurity atoms will hinder the recrystallization of the metal, thereby causing $T_{8}$ to rise, and the extent of the increase varies depending on the type of impurity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释预变形程度、原始晶粒尺寸和金属纯度对再结晶温度的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释预变形程度、原始晶粒尺寸和金属纯度对再结晶温度的影响，涉及多个因素的相互作用和机理分析。需要综合运用材料科学中的变形、再结晶和杂质影响等知识，进行推理和综合分析，属于复杂分析层次。 | 难度: 在简答题的复杂分析题型中，该题目要求全面分析预变形程度、原始晶粒尺寸和金属纯度对再结晶温度的影响，涉及多个因素的相互作用和双重影响机制。需要深入理解材料科学中的再结晶机理，并能综合运用知识进行推理分析。题目不仅要求解释单一因素的影响，还需要考虑不同条件下主导因素的变化，属于该题型内最高难度的复杂现象全面分析。" + }, + { + "idx": 2863, + "question": "Given that the yield strength of industrial pure copper is ${\\\\pmb{\\\\sigma{s}}}=70~{\\\\bf M}{\\\\bf P}{\\\\bf a}$, its grain size is $N{\\\\mathrm{A}}=18$ per $'\\\\mathbf{m}\\\\mathbf{m}^{2}$, and when $N{\\\\mathbf{A}}=$ $\\\\bf{4025}$ per $\\\\scriptstyle{\\\\prime}{\\\\mathbf{m}\\\\mathbf{m}^{2}}$, ${\\\\pmb{\\\\sigma}}{\\\\mathsf{S}}={\\\\pmb{95}}\\\\mathbf{M}\\\\mathbf{P}{\\\\bf a}$. Calculate ${\\\\pmb\\\\sigma_{\\\\mathfrak{s}}}$ when $N{\\\\mathbf{A}}=260$ per $\\\\scriptstyle{\\\\left/{\\\\mathfrak{m m}}^{2}\\\\right.}$.", + "answer": "Let the average grain diameter be $^{d}$, and the number of grains per $\\\\scriptstyle\\\\mathtt{m m}^{2}$ be $N_{\\\\Lambda}$. It can be proven that: Thus $$d=\\\\sqrt{\\\\frac{8}{3\\\\pi N_{\\\\Lambda}}}$$$$d_{1}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times\\\\mathrm{i}8}}=0.217(\\\\mathrm{mm})$$$$d_{2}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times4025}}=1.452\\\\times10^{-2}(\\\\mathrm{mm})$$$$d_{3}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times260}}=5.714\\\\times10^{-2}(\\\\mathrm{mm})$$Substituting into the Hall-Petch formula: Solving $$\\\\left\\\\{\\\\begin{array}{l l}{{70=\\\\sigma_{0}+k(0,217\\\\times10^{-3})^{-\\\\frac{1}{2}}}}\\\\ {{95=\\\\sigma_{0}+k(1,452\\\\times10^{-5})^{-\\\\frac{1}{2}}}}\\\\end{array}\\\\right.$$$$\\\\begin{array}{r}{\\\\sigma_{0}=61,3\\\\mathrm{MPa},\\\\quad k=0,1285}\\\\end{array}$$$$\\\\sigma_{5}=61,3+0.1285\\\\times(5,714\\\\times10^{-5})^{-\\\\frac{1}{2}}=78.3(\\\\mathrm{MPa})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch公式）来求解特定条件下的屈服强度，答案中包含了详细的数学推导和计算结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及晶粒尺寸与屈服强度的关系，需要理解公式中各参数的含义并进行数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，包括求解平均晶粒直径、建立方程组求解材料常数、最终代入计算目标强度值。虽然计算步骤较多，但每个步骤都有明确的计算方法，且不涉及复杂变量或高级数学技巧，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 2864, + "question": "There is currently a $\\\\phi{\\\\ell\\\\mathrm{mm}}$ aluminum wire that needs to be finally processed into $\\\\phi{\\\\mathrm{0.5mm}}$ aluminum material. However, to ensure product quality, the cold working amount of this aluminum material cannot exceed $85\\\\%$. How to formulate a reasonable processing procedure?", + "answer": "Cold working amount $=\\\\frac{\\\\Delta A}{A}=\\\\frac{A_{0}-A_{1}}{A_{0}}=\\\\frac{\\\\frac{\\\\pi}{4}d_{0}^{2}-\\\\frac{\\\\pi}{4}\\\\times d_{1}^{2}}{\\\\frac{\\\\pi}{4}\\\\times d_{0}^{2}}=1-\\\\left(\\\\frac{d_{1}}{d_{0}}\\\\right)^{2}=85\\\\%$\\n$$\\nd_{1}=\\\\sqrt{1-0.85}\\\\times6=2.324(\\\\mathrm{mm}),\\\\quad d_{2}=\\\\sqrt{0.15}\\\\times2.324=0.9(\\\\mathrm{mm}),\\n$$\\n\\n$$\\nd_{3}=\\\\sqrt{0.15}\\\\times0.9=0.348(\\\\mathrm{mm})\\n$$\\n\\nTherefore, the $\\\\phi{\\\\mathrm{6mm}}$ aluminum wire can first be cold drawn to $\\\\phi{\\\\mathrm{2.324mm}}$, followed by recrystallization annealing to eliminate work hardening. Then, it is cold drawn to $\\\\phi_{\\\\mathrm{0.9mm}}$, followed by another recrystallization annealing, and finally cold drawn to $\\\\phi_{\\\\mathrm{0.5mm}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定合理的加工步骤。答案中包含了具体的计算过程和公式推导，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括冷加工量的计算、多次冷加工和再结晶退火的安排，以及直径变化的综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合应用能力和步骤规划。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求制定合理的加工流程，涉及冷加工量的计算、多次冷拉和再结晶退火的安排，需要综合分析材料加工的限制条件和工艺步骤。虽然计算本身不涉及复杂多变量，但步骤较多且需要合理规划，属于中等偏上的难度。" + }, + { + "idx": 2865, + "question": "After cold working, the dislocation density of $\\\\mathbf{A}\\\\mathbf{g}$ is $10^{12}/\\\\mathfrak{c m}^{2}$. Assuming that the recrystallization nucleus moves from a high-angle grain boundary into the deformed matrix, find the minimum radius of curvature for the bulging grain boundary $\\\\scriptstyle\\\\left(\\\\mathbf{A}\\\\mathbf{g}_{:}G=30\\\\mathrm{GPa},b=0.3\\\\mathrm{nm},\\\\gamma=0.4\\\\mathrm{J}/\\\\mathrm{m}^{2}\\\\right)$.", + "answer": "The driving force $F$ for the movement of the $\\\\mathbf{Ag}$ recrystallization nucleus from a high-angle grain boundary into the deformed matrix is the stored energy from cold working, $F= G b^{2}\\\\left(\\\\rho_{1}-\\\\rho_{0}\\\\right)$. Since $\\\\rho_{1}\\\\gg\\\\rho_{0}$, $\\\\scriptstyle{F\\\\approx G b^{2}\\\\rho_{1}}$. The bulged grain boundary is subjected to a force $f$ directed toward its center of curvature. When the radius of curvature of the bulge is $R$, $f= \\\\frac{2\\\\gamma}{R},f$ $\\\\scriptstyle{\\\\dot{F}}$ $R_{\\\\mathrm{min}}$ $f$ $F$ $$F{=}f,$$$$G\\\\delta^{2}\\\\rho_{\\\\mathrm{f}}=\\\\frac{2\\\\gamma}{R_{\\\\mathrm{rein}}}$$$$R_{\\\\mathrm{aia}}={\\\\frac{2\\\\gamma}{G b^{2}\\\\rho_{1}}}={\\\\frac{2\\\\times0.4}{30\\\\times10^{8}\\\\times(3\\\\times10^{-10})^{2}\\\\times10^{16}}}=2.9\\\\times10^{-8}({\\\\mathrm{m}})=29({\\\\mathrm{nm}})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小曲率半径，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解冷加工后的位错密度、再结晶核的形成、晶界弯曲的驱动力等概念，并综合运用这些知识进行计算。虽然题目提供了必要的公式和参数，但需要将这些概念和公式结合起来进行综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个材料科学概念（如位错密度、再结晶驱动力、晶界曲率等），进行多步骤的公式推导和数值计算。虽然涉及多个变量和公式，但整体计算过程相对直接，没有过于复杂的数学处理或高难度的概念整合。" + }, + { + "idx": 2866, + "question": "A factory used a cold-drawn steel wire rope to lift a large steel component into a heat treatment furnace. Due to a momentary oversight, the wire rope was not removed but was heated together with the component to $860~\\\\mathrm{{^\\\\circC}}$. When the holding time was reached and the furnace door was opened to lift out the component, the wire rope broke. Analyze the cause.", + "answer": "The cold-drawn steel wire rope is made by twisting cold-drawn steel wires with large deformation. The cold work hardening during the processing significantly improves the strength and hardness of the steel wires, enabling them to bear heavy loads. However, when heated to ${\\\\tt860^{\\\\circ}C}$, the temperature far exceeds the recrystallization temperature of the wire rope, leading to recovery and recrystallization phenomena. The effect of work hardening completely disappears, and the strength and hardness are greatly reduced. When used for lifting again, once the load exceeds its bearing capacity, it inevitably leads to the fracture of the wire rope.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢丝绳断裂的原因，答案提供了详细的文字解释和论述，涉及材料科学中的冷加工硬化、再结晶现象等概念，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析冷拔钢丝绳在高温下断裂的原因，涉及冷加工硬化、回复与再结晶等材料科学原理的综合运用和推理分析。需要理解冷加工硬化对材料性能的影响，以及高温下回复和再结晶过程如何消除加工硬化效应，导致材料性能下降。这种分析需要较深的理解和综合运用多个材料科学概念的能力。 | 难度: 在简答题的复杂分析题型中，该题目要求对冷拔钢丝绳的热处理过程进行机理深度解释。需要综合运用材料科学中的冷加工硬化、再结晶温度、强度与硬度变化等知识，并推理分析加热至860℃后钢丝绳性能变化的完整机理。虽然不涉及多因素交互作用的全面分析（等级5特征），但对单一材料现象的机理解释已达到较高深度，符合等级4的标准。" + }, + { + "idx": 2867, + "question": "When moving dislocations are pinned, their average spacing is $\\scriptstyle{\\ell=\\rho^{-{\\frac{1}{2}}}(\\rho}$ is the dislocation density). It is given that a $\\mathtt{Cu}$ single crystal has been strain-hardened to the extent that the resolved shear stress acting on the crystal is 14MPa. Given $G=40\\mathrm{GPa},b=0,256$ $\\scriptstyle{\\mathtt{n m}}$, calculate the dislocation density of the $\\mathtt{Cu}$ single crystal.", + "answer": "After moving dislocations are pinned, a dislocation segment of length $\\boldsymbol{\\ell}$ can act as a dislocation source, and the resolved shear stress required to activate this dislocation source is $$\\tau_{\\mathrm{c}}=\\frac{G b}{l},$$$$14\\times10^{6}=\\frac{40\\times10^{9}\\times0.256\\times10^{-9}}{\\rho^{-\\frac{1}{2}}},$$$$\\rho{=1.869\\times10^{12}(\\mathrm{m}^{-2})}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（位错密度）。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目需要应用位错理论中的公式进行多步计算，涉及位错密度与剪切应力的关系，并需要进行单位转换和代数运算。虽然不涉及复杂的综合分析或推理，但比简单的直接套用公式更复杂。 | 难度: 在计算题中属于综合性计算问题，需要理解位错钉扎的概念，应用剪切应力公式，并进行多步数值计算和单位转换。虽然涉及多个步骤和概念关联，但整体计算过程相对直接，没有引入复杂变量或高级数学工具。" + }, + { + "idx": 2868, + "question": "Based on the equation $t_{0.95}=\\\\left[\\\\frac{2.85}{\\\\dot{N}G^{3}}\\\\right]^{\\\\frac{1}{4}}$, derive the functional relationship between the recrystallization temperature $T_{R}$ and $G_{0},N_{0},Q_{g}$ and $Q_{n}$.", + "answer": "$t_{0.95}=\\\\Big[\\\\frac{2.85}{\\\\tilde{N}\\\\bar{G}^{3}}\\\\Big]^{\\\\frac{1}{4}}=\\\\Big[\\\\frac{2.85}{N_{0}G_{0}^{3}}\\\\Big]^{\\\\frac{1}{4}}\\\\:\\\\mathrm{exp}\\\\Big(\\\\frac{Q_{n}+3Q_{\\\\ell}}{4k T}\\\\Big)$. Substituting $T=T_{\\\\parallel}\\\\circ\\\\mathcal{t}_{0,85}=1$, we get $$\\\\exp\\\\Big(\\\\frac{Q_{n}+3Q_{s}}{4k T_{\\\\mathrm{R}}}\\\\Big)=\\\\Big[\\\\frac{2,85}{N_{0}G_{0}^{3}}\\\\Big]^{-\\\\frac{1}{4}},\\\\frac{Q_{n}+3Q_{\\\\mathrm{g}}}{4k T_{\\\\mathrm{R}}}=-\\\\frac{1}{4}\\\\ln\\\\frac{2.85}{N_{0}G_{0}^{3}},$$ Therefore, $T_{\\\\mathbb{R}}=-\\\\frac{Q_{n}+3Q_{g}}{k\\\\ln\\\\Bigl(\\\\frac{2.85}{N_{0}G_{0}^{3}}\\\\Bigr)}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于给定的方程推导出再结晶温度与其他参数之间的函数关系，涉及公式变换和数学推导，属于典型的计算题类型。答案展示了详细的推导过程和最终的数学表达式，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，涉及公式推导和变量替换，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于复杂多变量计算难度，需要处理多个变量（G0, N0, Qg, Qn）的综合关系，进行多步推导和指数对数转换，最终建立复杂的函数关系式。解题过程涉及多个物理概念的关联和综合应用，对学生的公式推导能力和综合分析能力要求较高。" + }, + { + "idx": 2869, + "question": "Given that the Tm of Fe is 1538°C, estimate the minimum recrystallization temperature of Fe.", + "answer": "According to the empirical formula, the recrystallization temperature Tr≈0.4Tm. Therefore, the minimum recrystallization temperature of Fe is Tr=0.4×(1538+273)=724.4(K)=451.4(°C). In production, to improve efficiency, the actual recrystallization annealing temperature in factories is usually selected as Tr+(100~200)(°C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的熔点和经验公式进行数值计算，最终得出再结晶温度的具体数值。答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要考查对经验公式的直接应用和简单计算，涉及将熔点转换为绝对温度并进行基本乘法运算，属于基本公式的直接套用和简单计算范畴。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（Tr≈0.4Tm）进行简单数值计算，无需多步骤推导或复杂公式组合。题目明确给出了所有必要参数（Tm值）和计算路径，属于基础级别的公式应用类计算题。" + }, + { + "idx": 2870, + "question": "Given that the Tm of Cu is 1083°C, estimate the minimum recrystallization temperature of Cu.", + "answer": "According to the empirical formula, the recrystallization temperature Tr≈0.4Tm. Therefore, the minimum recrystallization temperature of Cu is Tr=0.4×(1083+273)=542.4(K)=269.4(°C). In production, to improve efficiency, the actual recrystallization annealing temperature in factories is usually set at Tr+(100~200)(°C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计铜的最低再结晶温度，答案中包含了具体的计算步骤和结果。 | 知识层次: 题目主要考查对经验公式的直接应用和简单计算，涉及将熔点转换为开尔文温度并进行基本运算，属于基本公式的直接套用和简单计算范畴。 | 难度: 在计算题中属于最低难度，仅需直接套用单一经验公式（Tr≈0.4Tm）并进行简单单位换算，无需多步骤计算或复杂公式组合。题目明确给出了所有必要参数（Cu的Tm值），且计算过程不涉及任何推导或条件判断，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 2871, + "question": "Given a $1~\\\\mathrm{cm}^{3}$ brass sample annealed at $700\\\\textcircled{1}$ with an initial grain diameter of $2.16\\\\times10^{-3}~\\\\mathrm{cm}$, the grain boundary energy of brass is $0.5J/\\\\mathfrak{m}^{2}$. A calorimeter measured a total heat release of 0.035J after holding for $2\\\\mathtt{h}$. Determine the grain size after holding for $2\\\\mathtt{h}$.", + "answer": "Assuming the heat released after holding for $2\\\\textrm{h}$ is due to grain growth, where the reduction in total grain boundary area releases energy. From quantitative metallography, the relationship between the interfacial area per unit volume $S_{V}$ and the grain diameter $d$ on the cross-section is $S_{v}={\\\\frac{2}{d}}$. Therefore, $$\\\\scriptstyle Q={\\\\Big(}{\\\\frac{2}{d_{1}}}-{\\\\frac{2}{d_{2}}}{\\\\Big)}\\\\gamma,\\\\quad{\\\\frac{1}{d_{2}}}={\\\\frac{1}{d_{1}}}-{\\\\frac{Q}{2\\\\gamma}}$$Substituting the corresponding data, we obtain $$d_{z}=8.9\\\\times10^{3}(\\\\mathrm{cm)}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶粒尺寸，解答过程中涉及了具体的公式推导和数值代入计算，最终给出了具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及定量金相学中的界面面积与晶粒直径的关系公式应用，以及能量释放与晶界面积变化的关系。虽然计算过程较为直接，但需要理解和应用多个概念，并进行适当的代数运算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如晶界能、晶粒尺寸与界面面积的关系）进行多步计算。题目涉及公式推导和数值代入，但计算步骤相对明确，属于中等应用层次。" + }, + { + "idx": 2872, + "question": "Industrial pure aluminum was rolled into strips with large deformation at room temperature, and the measured room-temperature mechanical properties were those of the cold-worked state. It was found from the table that the recrystallization temperature of industrial pure aluminum is $T_{\\\\mathbb{F}}=150~\\\\mathrm{\\\\textdegree}$. However, when the aforementioned industrial pure aluminum strip was heated to $100^{\\\\circ}C$, held for 16 days, and then cooled to room temperature before measuring its strength again, a significant decrease in strength was observed. Please explain the reason.", + "answer": "The recrystallization temperature of industrial pure aluminum $T_{\\\\mathbb{R}}=150^{\\\\circ}C$ found in the table refers to the temperature at which recrystallization is completed after annealing for $^\\\\textrm{\\\\scriptsize1h}$. In reality, besides the annealing temperature, the holding time also affects the recrystallization process. For metal materials subjected to large cold deformation, even when annealed at $T{<}T_{\\\\mathbb{R}}$, recrystallization can still occur if the holding time is sufficient. Two methods can be used to determine this: $\\\\textcircled{1}$ metallographic examination; $\\\\textcircled{2}$ substituting the known $T_{1},t_{1},t_{2},Q$ into the formula $\\\\frac{t_{1}}{t_{2}}=\\\\mathrm{e}^{-\\\\frac{Q}{R}(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}})}$ to solve for $\\\\pmb{T_{2}}$, and comparing it with $100\\\\mathrm{\\\\mathcal{C}}$ to determine whether recrystallization has occurred.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象的原因，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目需要解释工业纯铝在低于再结晶温度下长时间加热后强度显著下降的原因，涉及再结晶过程的温度和时间因素的综合影响，以及可能的实验验证方法。这要求对金属材料的再结晶机制有深入理解，并能将理论知识与实际现象联系起来进行分析和解释。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目不仅要求解释工业纯铝在低于再结晶温度下长时间保温后强度显著下降的现象，还需要综合运用金属学中的再结晶理论、时间-温度等效原理，以及可能的定量计算（如Arrhenius公式的应用）。此外，题目还隐含了对实验条件（保温时间）与标准条件（1小时）差异的对比分析，要求考生具备较高的知识整合能力和逻辑推理能力。这种深度和广度的要求使得该题目在同题型中属于最高难度等级。" + }, + { + "idx": 2873, + "question": "Given that H70 brass [w(Zn)=30%] requires 1 hour to complete recrystallization at a constant temperature of 400°C, and 2 hours at 390°C, calculate the time required to complete recrystallization at a constant temperature of 420°C.", + "answer": "Recrystallization is a thermally activated process, so the recrystallization rate; v_R = A exp(-Q/RT), and the recrystallization rate is inversely proportional to the time t required to achieve a certain volume fraction, i.e., v_R ∝ 1/t. 1/t = A' exp(-Q/RT) When recrystallization of the same degree occurs at two different constant temperatures, t1/t2 = e^(-Q/R (1/T2 - 1/T1)) Taking the natural logarithm on both sides: ln(t1/t2) = -Q/R (1/T2 - 1/T1). Similarly, ln(t1/t3) = -Q/R (1/T3 - 1/T1). Thus, (ln(t1/t2)) / (ln(t1/t3)) = (1/T2 - 1/T1) / (1/T3 - 1/T1) Substituting the corresponding data, we obtain t3 = 0.26 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在420°C下完成再结晶所需的时间，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，包括应用Arrhenius方程和自然对数变换，同时需要理解再结晶过程的温度依赖性。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解再结晶的热激活过程并应用阿伦尼乌斯方程进行多步计算。题目要求将不同温度下的时间关系进行转换和推导，涉及对数运算和温度倒数处理，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2874, + "question": "Explain how the following factors affect $G_{0},N_{0},Q_{8}$, and $Q_{n}$: degree of pre-deformation; original grain size; metal purity.", + "answer": "The driving force for primary recrystallization is the distortion energy of the crystal after deformation. The transition of the crystal from the high-energy state after distortion to the low-energy state of annealing is a spontaneous trend. However, this change in energy state requires atoms to overcome a potential barrier $\\\\Delta E$, the height of which depends on the lattice distortion energy after deformation. When the distortion energy is high, $\\\\Delta E$ decreases, and the nucleation and growth activation energies $\\\\mathbf{Q}_{\\\\mathfrak{n}}, \\\\mathbf{Q}_{\\\\mathfrak{g}}$ both decrease, thereby accelerating the recrystallization rate. Therefore, all factors affecting the distortion energy after deformation will influence $\\\\mathbf{Q}_{\\\\mathbf{n}}, \\\\mathbf{Q}_{\\\\mathbf{\\\\tilde{g}}}$, and $T_{\\\\mathsf{R}}$. From the above analysis, within a certain range of deformation, the higher the degree of pre-deformation and the finer the original grain size, the greater the distortion energy after deformation, and the lower $Q_{\\\\mathfrak{n}}, Q_{\\\\mathfrak{g}}$ will be. The effect of metal purity on $\\\\mathbf{Q}_{\\\\mathrm{n}}, \\\\mathbf{Q}_{\\\\mathrm{g}}$ can be considered from two aspects. On one hand, impurities increase the distortion energy, reducing $Q_{\\\\mathrm{n}}$ and $\\\\mathbf{Q}_{\\\\mathrm{g}}$. On the other hand, impurities also hinder interface migration, increasing $\\\\mathbf{\\\\hat{Q}}_{\\\\mathrm{n}}, \\\\mathbf{\\\\hat{Q}}_{\\\\mathrm{g}}$. These two opposing effects coexist, and the dominant one determines the outcome. $\\\\aleph_{\\\\mathfrak{g}}\\\\mathrm{G}_{\\\\mathfrak{o}}$ is only related to the intrinsic nature of the metal and is not significantly affected by the degree of pre-deformation, original grain size, or metal purity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个因素如何影响特定参数（$G_{0},N_{0},Q_{8}$, 和 $Q_{n}$），答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求解释多个因素（预变形程度、原始晶粒尺寸、金属纯度）对再结晶过程中关键参数（G0, N0, Q8, Qn）的影响机制，涉及变形能、激活能、界面迁移等复杂概念的关联分析，需要综合运用材料科学原理进行推理和解释，思维深度和综合分析要求较高。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用多个材料科学概念（变形能、再结晶驱动力、晶界迁移等），并分析三个不同因素（预变形程度、原始晶粒尺寸、金属纯度）对四个关键参数（G0, N0, Q8, Qn）的复杂影响机制。需要建立多因素之间的相互作用关系，解释对立效应的共存（如杂质同时降低和升高激活能的双重作用），并区分内在性质与外部因素的影响。这种需要同时处理多个变量、机制解释和矛盾效应分析的要求，代表了该题型下的最高难度水平。" + }, + { + "idx": 2875, + "question": "In a metal with a dislocation density of $\\\\mathrm{10^{12}/cm^{2}}$ after cold deformation, there exist second-phase particles that do not aggregate or grow upon heating, with a volume fraction $\\\\varphi{=}1\\\\%$ and a radius of $1\\\\mu\\\\mathfrak{m}$. Can the presence of these second-phase particles completely prevent recrystallization of this metal upon heating? (Given $G{=}10^{5}\\\\mathrm{MPa}$, $\\\\pmb{b=0.3\\\\mathrm{nm}}$, and interfacial energy ${\\\\pmb\\\\sigma}{=}0,5\\\\mathrm{J}/\\\\uppi^{2}$.)", + "answer": "The driving force for recrystallization $$F=G b^{2}\\\\left(\\\\rho-\\\\rho_{\\\\circ}\\\\right)\\\\approx G b^{2}\\\\rho=10^{11}\\\\times(3\\\\times10^{-10})^{2}\\\\times10^{16}=9\\\\times10^{7}({\\\\mathrm{N/m}}^{2})$$The resistance to recrystallization $$f={\\\\frac{3\\\\varphi}{2r}}{\\\\sigma}={\\\\frac{3}{2}}\\\\times{\\\\frac{0.01}{{\\\\bar{1}}\\\\times}}{\\\\frac{0.01}{10^{-6}}}\\\\times0.5=7.5\\\\times10^{3}({\\\\mathrm{N/m^{2}}})$$$F{\\\\gg}f$, so the presence of these second-phase particles cannot completely prevent recrystallization.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用公式计算驱动力和阻力，并进行比较分析。虽然不涉及复杂的推理或机理解释，但需要综合运用材料科学中的位错密度、第二相粒子等知识。 | 难度: 在计算题中属于综合性计算问题，需要理解多个概念（如位错密度、第二相粒子、再结晶驱动力和阻力等），进行多步骤计算（包括驱动力和阻力的计算），并进行综合分析比较（判断驱动力是否远大于阻力）。虽然计算过程相对直接，但涉及多个物理量的关联和单位转换，属于中等偏上的难度。" + }, + { + "idx": 2876, + "question": "For an Fe-3%Si alloy containing MnS particles with a radius of 0.05μm and a volume fraction of 0.01, during the annealing process below 850°C, when the average grain diameter of the matrix reaches 6μm, normal grain growth stops. Analyze the reason for this phenomenon.", + "answer": "For silicon steel sheets containing MnS particles with a radius of 0.05μm and a volume fraction of 0.01 during recrystallization, the limiting grain diameter is calculated as: D_lim = (4r)/(3φ) = (4/3) × (0.05/0.01) = 6.67μm. It is precisely due to the presence of these dispersed particles that when the silicon steel sheet is annealed below 850°C, normal grain growth stops once the average grain diameter of the matrix reaches 6μm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析现象的原因，答案提供了详细的文字解释和论述，涉及理论分析和公式应用，但主要侧重于解释和论述而非单纯的计算或选择。 | 知识层次: 题目需要应用Zener钉扎理论公式计算极限晶粒尺寸，并结合材料科学中的第二相粒子钉扎效应进行分析。虽然涉及多步计算和概念关联，但整体上仍属于对已知理论和公式的直接应用，不需要复杂的推理或创新性思维。 | 难度: 在简答题中属于中等难度，需要理解晶粒生长和分散粒子钉扎效应的概念，并进行简单的计算和综合分析。题目要求分析正常晶粒生长停止的原因，涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2877, + "question": "Briefly describe the driving forces of primary recrystallization and secondary recrystallization", + "answer": "The driving force of primary recrystallization is the elastic distortion energy of the matrix, while the driving force of secondary recrystallization comes from the reduction of interfacial energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述两种再结晶的驱动力，需要文字解释和论述，属于简答题类型 | 知识层次: 题目考查对初级再结晶和次级再结晶驱动力的基本概念记忆和理解，属于定义和基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述初级再结晶和次级再结晶的驱动力，涉及两个相关但不同的概念，需要考生理解并区分两者的驱动机制。虽然不需要复杂的推导或综合分析，但比单纯的定义简答（等级1）要求更高的概念理解和表达能力。" + }, + { + "idx": 2878, + "question": "W has a very high melting point (Tm=3410°C) and is often chosen as the heating element for incandescent light bulbs. However, when large grains spanning the filament exist, the filament becomes brittle and may fracture under the thermal shock of frequent switching. Please introduce a method to extend the filament's lifespan.", + "answer": "Factors affecting the normal growth of recrystallized grains, besides temperature, include the presence of finely dispersed second-phase particles, which play a significant role in grain boundary migration. For example, ThO2 second-phase particles can be formed in the tungsten filament to hinder grain growth during high-temperature operation. If the volume fraction of ThO2 particles is φ and the particle radius is r, the limiting grain size is given by: Dlim=4r/(3φ(1+cosα)), where α is the contact angle. Therefore, by selecting appropriate φ and r, Dlim can be minimized. Grain refinement can enhance strength while maintaining a high level of toughness, effectively extending the filament's service life.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求介绍一种方法来延长灯丝的寿命，答案提供了详细的文字解释和论述，包括影响因素、具体方法和理论依据，符合简答题的特征。 | 知识层次: 题目要求解释如何通过添加第二相颗粒来抑制晶粒生长，从而延长钨丝灯丝的寿命。这涉及到对晶粒生长机制的理解、第二相颗粒的作用机理以及相关公式的应用。需要综合运用材料科学中的多个概念，进行推理分析，并解释其中的机理性问题。思维过程要求较高，涉及多方面的知识关联和综合分析。 | 难度: 在简答题题型中，该题目要求对复杂现象进行全面分析，涉及多个知识点的综合运用和深度解释。具体来说，题目不仅要求解释钨灯丝寿命延长的机理，还需要引入第二相颗粒（如ThO2）对晶粒生长的抑制作用，并给出具体的数学表达式（Dlim=4r/(3φ(1+cosα))）来说明如何通过控制体积分数φ和颗粒半径r来限制晶粒尺寸。此外，还需要理解晶粒细化对强度和韧性的影响，并综合这些因素来提出延长灯丝寿命的方法。这种深度和广度的分析要求，使得该题目在简答题题型中属于最高难度等级。" + }, + { + "idx": 2879, + "question": "In engineering, it is often considered that the grain size of steel does not grow when heated to 760°C, but will significantly grow at 870°C. If the original grain diameter of the steel is 0.05 mm, the empirical formula for grain growth is D^(1/n)−D0^(1/n)=c t, where D is the grain diameter after growth; D0 is the original grain diameter; c is the proportionality constant; t is the holding time. Given that at 760°C, n=0.1, c=6×10^(−16), find the grain diameter of steel with a carbon content of 0.8% after holding at 760°C for 1 hour.", + "answer": "At 760°C: D^(1/n)=D0^(1/n)+c t=(0.05)^10+6×10^(−16)×60=13.37×10^(−14). D=0.0516(mm). Therefore, the grain has essentially not grown.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出具体的数值结果（grain diameter）。解答过程涉及代入数值、计算和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。虽然需要理解晶粒生长的经验公式，但计算过程相对直接，属于简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目提供了明确的公式和所有必要的参数，只需要将数值代入公式进行简单计算即可得到结果。不需要多个公式的组合或复杂的推导过程，解题步骤非常直接。" + }, + { + "idx": 2880, + "question": "How to distinguish between cold and hot working?", + "answer": "The recrystallization temperature is the dividing line between cold and hot working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何区分冷加工和热加工，答案提供了文字解释而非选择、判断或计算 | 知识层次: 题目考查冷加工和热加工的基本区分标准，即再结晶温度的概念，属于基础概念的记忆和理解。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并复述冷热加工的分界线（再结晶温度）这一单一概念，无需解释或展开论述。题目仅考察基础概念的记忆能力，不涉及概念间的关联或复杂体系阐述。" + }, + { + "idx": 2881, + "question": "In practice, it is often considered that the grain size of steel will significantly grow when heated to 870°C. If the original grain diameter of the steel is 0.05 mm, the empirical formula for grain growth is D^(1/n)−D0^(1/n)=c t, where D is the grown grain diameter; D0 is the original grain diameter; c is the proportional constant; t is the holding time. Given that at 870°C, n=0.2, c=2×10^(−8), find the grain diameter of steel with 0.8% carbon content after holding at 870°C for 1 hour.", + "answer": "At 870°C: D^5=(0.05)^5+2×10^(−8)×60=1.513×10^(−6) D=0.0686(mm). Compared to the original grain diameter, it has significantly grown (approximately 37%).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求应用给定的经验公式进行数值计算，以求解钢的晶粒直径。解答过程涉及代入数值、计算和最终得出数值结果，符合计算题的特征。 | 知识层次: 题目需要应用给定的经验公式进行多步计算，涉及数值代入和指数运算，同时需要理解晶粒生长的基本概念和公式中各参数的含义。虽然计算过程较为直接，但需要一定的综合分析能力和对公式的理解。 | 难度: 在计算题中属于综合性计算问题，需要应用给定的经验公式进行多步计算，包括指数运算和单位转换。虽然公式已提供，但需要正确理解并代入数值，涉及中等程度的综合分析能力。" + }, + { + "idx": 2882, + "question": "Assuming we add Na2O with w(Na2O)=10% to SiO2, please calculate the ratio of oxygen to silicon.", + "answer": "There are 90at% SiO2 and 10at% Na2O, so O:Si = (0.9×2 + 0.1) : 0.9 = 2.111. Since O:Si = 2.111 < 2.5, there is a good tendency for glass formation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算氧与硅的比例），并应用了化学计量公式，最终给出了具体的计算结果。这符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的成分比例计算氧硅比，属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算氧硅比，涉及基本公式应用和简单计算，但需要理解原子百分比转换和氧硅比的概念。虽然比单一公式直接计算稍复杂，但仍属于简单公式应用范畴，不需要多个公式组合计算。" + }, + { + "idx": 2883, + "question": "In a eutectic reaction of the Mg-Ni system, let C1 be the hypoeutectic alloy and C2 be the hypereutectic alloy. The mass fractions of the proeutectic phases in these two alloys are equal. Find the relationship between C1 and C2.", + "answer": "According to the lever rule, the mass fractions of the proeutectic phases are: α_pro=(23.5-C1)/23.5 β_pro=(C2-23.5)/(54.6-23.5) Given that α_pro=β_pro, combining the above equations yields: C2=54.6-1.323C1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过杠杆定律进行数值计算，并建立C1和C2之间的关系式。解答过程涉及公式应用和代数运算，最终得出具体的数学关系式。 | 知识层次: 题目需要应用杠杆法则进行多步计算，并建立两个合金成分之间的关系。虽然不涉及复杂的机理分析或创新设计，但需要综合理解和运用相图知识，进行中等难度的数学推导和计算。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆定律进行多步计算，并建立两个合金成分之间的关系。虽然不涉及复杂多变量计算，但需要综合分析概念关联和公式应用，属于中等应用层次的计算题。" + }, + { + "idx": 2884, + "question": "What are the main differences in the microstructure between dynamic recrystallization and static recrystallization?", + "answer": "Although the microstructure after dynamic recrystallization also consists of equiaxed grains, the grain boundaries are serrated, and the grains contain subgrains divided by dislocation tangles. This differs from the grains produced by static recrystallization, which have a very low dislocation density. Therefore, the strength and hardness of dynamically recrystallized structures with the same grain size are higher than those of statically recrystallized ones. The grain size after dynamic recrystallization is proportional to the flow stress. Additionally, the lower the strain rate and the higher the deformation temperature, the larger and more complete the grains after dynamic recrystallization will be.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释动态再结晶和静态再结晶在微观结构上的主要差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较动态再结晶和静态再结晶的微观结构差异，涉及对两种再结晶过程的理解、微观结构的详细描述（如晶界形态、亚晶结构、位错密度等）、以及力学性能差异的解释。这需要综合运用材料科学中的再结晶理论、位错理论和力学性能知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题的复杂分析层次中，该题目要求全面分析动态再结晶和静态再结晶的微观结构差异，涉及多个复杂概念的综合运用（如位错密度、亚晶结构、流变应力关系等），需要深入理解材料变形机理并解释温度、应变速率等参数对晶粒尺寸的影响。这种综合性的机理解释和现象分析在同类题型中属于最高难度等级。" + }, + { + "idx": 2885, + "question": "What is a copolymer?", + "answer": "A polymer formed by the polymerization of two or more monomers is called a copolymer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语进行文字解释和论述，答案是一个定义性的陈述，没有提供选项或需要计算。 | 知识层次: 题目考查对共聚物（copolymer）这一基本概念的定义记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答copolymer的基本定义，属于最基础的概念记忆。不需要额外的解释、描述或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2886, + "question": "In a eutectic reaction of the Mg-Ni system, let C1 be the hypoeutectic alloy and C2 be the hypereutectic alloy. The total amount of α in alloy C1 is 2.5 times that in alloy C2. Determine the compositions of C1 and C2.", + "answer": "Let the total amount of α in C1 be α1, then: α1=(54.6-C1)/54.6 Let the total amount of α in C2 be α2, then: α2=(54.6-C2)/54.6 According to the given condition, α1=2.5α2, that is: (54.6-C1)/54.6=2.5*(54.6-C2)/54.6 Substituting C2=54.6-1.323C1 into the above equation, we can solve for: C1=w(Ni)=12.7% C2=w(Ni)=37.8%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解合金C1和C2的组成，答案中展示了具体的计算过程和最终数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解共晶反应、杠杆定律的应用，并进行代数方程的求解。虽然不涉及复杂的综合分析或创新应用，但比简单的公式应用和直接套用更复杂。 | 难度: 在计算题中属于综合性计算问题，需要理解共晶反应的基本概念，应用杠杆定律进行多步计算，并建立方程求解未知变量。虽然计算过程较为直接，但需要综合运用多个知识点和步骤，属于中等偏上的难度。" + }, + { + "idx": 2887, + "question": "If O:Si ≈ 2.5 is the criterion for glass-forming tendency, what is the maximum amount of Na2O that can form a glass?", + "answer": "Let the maximum content of Na2O be x, and SiO2 = 1 - x. According to (x + 2(1 - x)) / (1 - x) ≤ 2.5, we get (2 - x) / (1 - x) ≤ 2.5. Further derivation yields 1 + 1 / (1 - x) ≤ 2.5; 1 / (1 - x) ≤ 1.5; 1 - x ≥ 1 / 1.5; x ≤ 1 / 3. Therefore, the maximum amount of Na2O that can form a glass is 1/3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最大Na2O含量，答案涉及数学推导和不等式求解，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和公式推导，涉及对玻璃形成倾向标准的理解和应用，需要将化学计量关系转化为数学表达式并进行求解。虽然不涉及复杂的综合分析或创新设计，但超出了简单直接套用公式的层次。 | 难度: 在计算题中属于综合性计算问题，需要理解玻璃形成倾向的判据（O:Si ≈ 2.5），建立正确的数学模型（(x + 2(1 - x)) / (1 - x) ≤ 2.5），并进行多步代数推导和不等式求解。虽然不涉及多变量，但需要较强的概念关联和综合分析能力，属于该题型内的中等偏上难度。" + }, + { + "idx": 2888, + "question": "Based on the shown CaO·ZrO2 phase diagram, write down all the isothermal three-phase transformations.", + "answer": "There are three isothermal three-phase transformations in the shown ZrO2-σ·CaO phase diagram: peritectic reaction: L+T-ZrO3→C-ZrO2; eutectic reaction: L→(C-ZrO2+ZrCaO3); eutectoid reaction: T-ZrO2→M-ZrO2+C-ZrO2; where L represents liquid phase, T represents tetragonal, C represents cubic, M represents monoclinic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据相图写出所有等温三相转变反应，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的反应描述和相变类型，符合简答题的特征。 | 知识层次: 题目要求基于相图识别等温三相转变，需要理解相图的基本原理和三相反应的类型（包晶、共晶、共析），并能将相图中的信息与这些概念关联起来。这需要一定的综合分析能力，而不仅仅是基础概念的记忆。 | 难度: 在简答题中属于较高难度，需要综合分析和说明多个相变反应，包括识别和解释不同类型的等温三相转变（包晶反应、共晶反应和共析反应）。此外，题目要求对相图中的不同相（液相、四方相、立方相和单斜相）有深入理解，并能准确关联和描述它们之间的转变过程。这种题目不仅考查了知识点的掌握深度，还要求考生能够进行多角度的分析和论述。" + }, + { + "idx": 2889, + "question": "What is a homopolymer?", + "answer": "A polymer formed by the polymerization of a single monomer is called a homopolymer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"homopolymer\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查对聚合物基本分类中均聚物（homopolymer）定义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述单一概念的定义，无需额外解释或复杂论述。题目直接询问\"什么是均聚物\"，答案只需给出标准定义即可，不涉及概念间的关联或体系化阐述。" + }, + { + "idx": 2890, + "question": "Using the data from the previous question, assuming the alloy composition is Al-0.5%Cu and there is no convection in the liquid, calculate the temperature gradient required to maintain a planar solid-liquid interface.", + "answer": "G≥(m w0 R(1-k0))/(D k0)=(320×0.005×3×10^-4×(1-0.16))/(3×10^-5×0.16)=84℃/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是一个具体的计算结果（84℃/cm），涉及到了公式推导和数值代入。 | 知识层次: 题目需要进行多步计算，涉及公式应用和参数代入，需要理解温度梯度与合金成分、扩散系数等参数之间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解合金凝固理论中的多个概念（如成分过冷、分配系数、扩散系数等），并正确应用公式进行多步骤计算。题目涉及多个变量的综合运用和单位转换，但计算过程相对直接，没有过于复杂的推导或迭代步骤。" + }, + { + "idx": 2891, + "question": "Using the data from the previous question, assuming the alloy composition is Al-2%Cu and there is no liquid convection, calculate the interface temperature at the beginning of solidification", + "answer": "T=T0-m(w0/k0)=660.37-320×(0.02/0.16)=620.37℃", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果 | 知识层次: 题目要求基于给定的合金成分和条件，应用简单的公式进行计算。虽然需要理解相图的基本概念和凝固过程，但计算过程直接且仅涉及单一公式的套用，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级，仅需套用给定公式进行简单数值计算，无需多个步骤或复杂推理。" + }, + { + "idx": 2893, + "question": "What is homoaddition polymerization?", + "answer": "A polymerization reaction involving a single monomer is called homoaddition polymerization, abbreviated as homoaddition; the resulting polymer has the same composition as its monomer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"homoaddition polymerization\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对homoaddition polymerization的定义和基本特征的掌握。 | 难度: 在简答题题型中，该题目仅要求对基础概念进行定义和简单解释，属于最基础的定义简答级别。题目仅涉及单一概念的记忆和复述，不需要进行概念间的比较或复杂体系的阐述，符合等级1的基本特征。" + }, + { + "idx": 2894, + "question": "What is co-condensation?", + "answer": "The polycondensation reaction involving two or more monomers is called co-condensation polymerization, abbreviated as co-condensation, and the resulting polymer composition differs from the monomers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"co-condensation\"进行解释说明，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对\"co-condensation\"这一术语的定义和基本特征的掌握。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答\"co-condensation\"的定义，不需要进行概念解释或复杂概念体系的阐述。答案可以直接从记忆中获得，不需要额外的分析或推理步骤。在同类题型中，这是最基础的知识点掌握要求。" + }, + { + "idx": 2895, + "question": "Briefly describe the advantages of polymer alloying", + "answer": "Through alloying, polymers can overcome certain performance weaknesses of single-component polymers (homopolymers). For example, polypropylene (PP) is prone to brittle fracture at low temperatures, but blending with butadiene rubber (BR) can significantly improve the toughness of polypropylene. It can also broaden the applications of polymers. For instance, blending polyethylene (PE) with different densities can produce foam plastics with various properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述聚合物合金化的优点，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求对聚合物合金化的优势进行简要描述，涉及对单一组分聚合物性能弱点的理解以及通过合金化改善性能的具体例子。这需要将多个概念（如聚合物性能、合金化原理、应用实例）进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解聚合物合金化的基本概念，并通过具体例子说明其优势。题目要求综合分析不同聚合物合金化的效果，但不需要深入探讨机理或多角度分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 2896, + "question": "Calculate the relative amounts (in mol%) of monoclinic ZrO2 solid solution (Monoclinic ZrO2 SS) and cubic ZrO2 solid solution (Cubic ZrO2 SS) at room temperature for a CaO–ZrO2 ceramic with w(CaO)=4%. Assume that the solubilities of monoclinic ZrO2 solid solution and cubic ZrO2 solid solution at room temperature are 2mol% CaO and 15mol% CaO, respectively.", + "answer": "Using the conversion formula between mole fraction and mass fraction, the mole fraction corresponding to w(Ca)=4% can be calculated: xA = (wA/ArA)/(wA/ArA + wB/ArB) = (4/(40+16))/(4/(40+16) + 96/(91+16×2)) ≈ 0.08; thus, 4wt% CaO = 8mol% CaO. Moreover, it can be observed from the figure that the solubility limit changes little below 900°C, yielding: monoclinic phase % = (xcub - x)/(xcub - xmono) × 100% = (15 - 8)/(15 - 2) × 100% = 53.8%; cubic phase % = (x - xmono)/(xcub - xmono) × 100% = (8 - 2)/(15 - 2) × 100% = 46.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种ZrO2固溶体的相对含量，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括摩尔分数转换和相组成计算，同时需要理解固溶体的溶解度概念及其在相组成计算中的应用。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行数值计算和结果解释。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及质量分数与摩尔分数的转换、相图分析以及杠杆定律的应用，步骤较为复杂，但未涉及多变量或高级数学工具，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 2897, + "question": "Using the data from the previous question, assuming the alloy composition is Al-0.5%Cu and there is no liquid convection, calculate the interface temperature at the beginning of solidification", + "answer": "T=T0-m(w0/k0)=660.37-320×(0.005/0.16)=650.37℃", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及合金凝固过程中界面温度的计算，属于对基础知识的直接运用，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要套用给定的公式T=T0-m(w0/k0)，代入已知数值进行简单计算即可得出结果，无需额外的公式组合或复杂的解题步骤。" + }, + { + "idx": 2898, + "question": "What is a quasicrystal?", + "answer": "Quasicrystals lack translational symmetry but are a type of solid atomic aggregation state that exhibits periodic order similar to crystalline materials. In three-dimensional space, they possess not only 5-fold symmetry axes but also 8, 10, or 12-fold symmetry axes, with diffraction patterns showing non-crystallographic symmetry. Most quasicrystalline phases are metastable and can only be obtained through rapid solidification methods. It is well known that periodic tiling of a plane can be achieved with equilateral triangles, squares, or regular hexagons, whereas regular pentagons cannot tile the plane without overlaps or gaps.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"quasicrystal\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查准晶体的基本定义、对称性特征和形成条件等基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目要求解释准晶体的定义和基本特征，包括其对称性和形成条件。虽然需要描述多个知识点，但都属于基础概念记忆范畴，不需要进行复杂的体系阐述或深入分析。因此，在同题型内属于中等难度（等级2）。" + }, + { + "idx": 2899, + "question": "Briefly describe the characteristics of nanomaterials from the perspective of internal microstructure.", + "answer": "Nanomaterials refer to materials that have at least one dimension in the three-dimensional space at the nanoscale or are composed of them as basic units. According to dimensionality, the basic units of nanomaterials can be divided into three categories: (1) Zero-dimensional, meaning all three spatial dimensions are at the nanoscale, such as nanopowder materials; (2) One-dimensional, meaning two dimensions in space are at the nanoscale, such as nanowires, nanorods, nanotubes, etc.; (3) Two-dimensional, meaning one dimension in three-dimensional space is at the nanoscale, such as ultrathin films, multilayer films, and superlattices. Due to the ultrafine size of nanoparticles, they are on the same order of magnitude as the wavelength of light waves, neutron wavelength, mean free path, etc., resulting in quantum size effects, small size effects, surface effects, macroscopic quantum tunneling effects, and when the volume fraction exceeds $50\\%$, the influence of grain boundary structure causes nanomaterials to exhibit unique mechanical, physical, and chemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述纳米材料从内部微观结构角度的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目主要考查对纳米材料基本概念的记忆和理解，包括其定义、分类和基本特性。虽然涉及一些效应和性质，但整体上属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于复杂概念体系阐述难度等级。题目不仅要求考生掌握纳米材料的基本定义和分类（零维、一维、二维），还需要理解并解释纳米材料特有的量子尺寸效应、小尺寸效应、表面效应、宏观量子隧道效应等复杂概念，以及这些效应对材料性能的影响。此外，答案还涉及纳米材料在体积分数超过50%时的晶界结构影响，这需要考生对材料科学有较深入的理解和综合运用能力。因此，在简答题题型内，该题目属于较高难度等级。" + }, + { + "idx": 2900, + "question": "A ternary alloy with mass fractions of 40% A, 30% B, and 30% C forms a three-phase equilibrium at the eutectic temperature. The compositions of the three phases are as follows: liquid phase (50% A, 40% B, 10% C), α phase (85% A, 10% B, 5% C), and β phase (10% A, 20% B, 70% C). Calculate the fractions of the liquid phase, α phase, and β phase.", + "answer": "First, draw a concentration triangle and mark the compositions of each phase. The alloy composition point is: L% = (57 - 30) / (57 - 10) × 100% = 57.4%; α% = (40 - 35) / (85 - 35) × 100% = 10%; β% = 100% - 57.4% - 10% = 32.6%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解各相的比例，答案给出了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及浓度三角形的绘制和标记各相组成，然后应用杠杆定律计算各相的质量分数。这需要理解三元相图的基本原理，并能将概念与计算相结合，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握三元相图的基本概念，进行多步计算和综合分析。题目要求绘制浓度三角形并应用杠杆定律计算各相比例，涉及多个变量和步骤，但未达到复杂多变量计算的程度。" + }, + { + "idx": 2901, + "question": "Briefly describe the methods of polymer alloying", + "answer": "The preparation methods of polymer alloys can be divided into physical methods and chemical methods. Physical blending methods include dry powder blending, melt blending, and latex blending, with melt blending being the most commonly used. Chemical blending methods mainly include copolymerization-blending and interpenetrating polymer network methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述聚合物合金化的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对聚合物合金制备方法的基本分类和简单描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述聚合物合金化的方法，涉及物理和化学方法的分类及具体方法的列举，但不需要深入分析或复杂的概念体系阐述。这属于对基础概念的记忆和简单解释，符合等级2的要求。" + }, + { + "idx": 2902, + "question": "Why can stretching improve the crystallinity of crystalline polymers?", + "answer": "From $\\Delta G{=}\\Delta H{-}T\\Delta S$, it is known that the free energy $\\Delta G$ must be less than zero for the crystallization process to proceed spontaneously. When a substance transitions from an amorphous state to a crystalline state, the arrangement of molecules changes from disordered to ordered, which always results in a decrease, i.e., $\\Delta S{<}0$. In this case, $-T\\Delta S{>}0$, while $\\Delta H{<}0$ (exothermic). To ensure $\\Delta G{<}0$, it is necessary that $|\\Delta H|>T|\\Delta S|$. For some polymers transitioning from the amorphous phase to the crystalline phase, $\\vert\\Delta S\\vert$ is large, while the thermal effect of crystallization $\\Delta H$ is small. To satisfy $\\mid\\Delta H\\mid>T\\mid\\Delta S\\mid$, there are only two approaches: lowering $T$ or reducing $\\{\\Delta S\\}$. However, excessively lowering the temperature makes molecular movement difficult, potentially leading to a glassy state instead of crystallization. To reduce $\\mid\\Delta S\\mid$, stretching the polymer before crystallization can be employed, which imparts a certain degree of order to the polymer chains in the amorphous phase. This reduces the corresponding $|\\Delta S|$ during crystallization, enabling the process. Therefore, for crystalline polymers, stretching is beneficial for increasing crystallinity. For example: natural rubber takes decades to crystallize at room temperature, but when stretched, it crystallizes in just a few seconds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对“为什么拉伸可以提高结晶聚合物的结晶度”进行详细的文字解释和论述，答案中包含了热力学公式的分析、分子排列变化的描述以及实际例子的说明，符合简答题的特征。 | 知识层次: 题目要求解释拉伸如何提高结晶性聚合物的结晶度，涉及自由能变化、熵变、焓变等热力学概念的综合运用，需要深入理解聚合物结晶的机理，并通过推理分析解释拉伸对结晶过程的影响。答案中不仅引用了热力学公式，还结合了分子排列和运动性的变化，进行了多层次的综合分析，属于复杂分析层次。 | 难度: 在简答题的复杂分析题型中，该题目属于最高难度等级。题目要求综合运用热力学原理（ΔG=ΔH-TΔS）、聚合物结晶机理、分子运动学等多方面知识进行深度解释。解题需要：" + }, + { + "idx": 2903, + "question": "The crystallization activation energy of amorphous alloys can be determined using the Ozawa plotting method, which utilizes the linear relationship between the crystallization temperature $\\scriptstyle{\\mathcal{T}}_{\\mathbf{z}}$ and the heating rate $^{a}$ measured under different continuous heating conditions. The $\\pmb{T_{x}}$ values for the pre-crystallization phase $\\alpha{\\boldsymbol{-}}\\mathbf{\\overline{{F}}}\\mathbf{e}$ of the amorphous FenBsSis alloy have been measured as shown in the table below. Calculate the activation energy.", + "answer": "Based on the data in the table, plot the graph (see Figure 42), which approximates a straight line. Using the least squares method, the equations of the straight lines are fitted as follows: \\n$$\\n\\\\ln{\\\\frac{T_{x}}{a}}={\\\\frac{46}{T_{x}}}-53\\n$$\\n$$\\n\\\\ln{\\\\frac{T_{x}}{a}}={\\\\frac{49}{T_{x}}}-57\\n$$\\nFrom the slope of the straight lines, the activation energy for the precipitation stage of the ${\\\\mathfrak{a}}{\\\\mathfrak{F}}{\\\\mathfrak{e}}$ pre-crystallization phase is determined to be $(382\\\\sim407)\\\\mathrm{kJ/mol}_{\\\\circ}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式计算激活能，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用Ozawa绘图法进行多步计算，包括绘制图表、拟合直线方程，并通过斜率确定活化能。这涉及到公式应用、数据处理和综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解Ozawa绘图法的基本原理，进行多步计算（包括数据绘图、直线拟合、斜率分析等），并关联结晶活化能的概念。虽然涉及多变量计算，但步骤相对明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 2904, + "question": "Explain why crystal structures do not possess 5-fold or higher than 6-fold symmetry axes?", + "answer": "5-fold or higher than 6-fold symmetry axes cannot satisfy the condition of identical surroundings around lattice points, lack translational symmetry, and thus cannot achieve a regularly periodic arrangement of crystal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么晶体结构不具备5重或高于6重的对称轴，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释晶体结构中不存在5重或高于6重对称轴的原因，涉及对晶体对称性、平移对称性和周期性排列的深入理解，需要综合运用晶体学原理进行推理分析，属于复杂分析层次。 | 难度: 在简答题中，该题目要求对晶体结构的对称性进行机理深度解释，涉及对晶格点周围环境一致性和平移对称性的理解。虽然不需要全面分析复杂现象，但需要综合运用晶体学原理进行推理分析，属于较高难度的简答题。" + }, + { + "idx": 2905, + "question": "How to describe the quasicrystalline structure?", + "answer": "The quasicrystalline structure cannot be represented by a unit cell like crystals, meaning it cannot achieve periodicity through translation operations. Currently, the more commonly used model is the tiling method to characterize quasicrystalline structures. For example, a 5-fold symmetric quasicrystalline structure can be constructed using two types of rhombuses with equal side lengths and angles of 36 and 144 degrees (narrow), and 72 and 108 degrees (wide), following specific matching rules.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对quasicrystalline structure进行描述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述准晶结构的特点和构造方法，涉及对非周期性结构的理解和特定模型（如tiling方法）的应用。需要将基本概念与实际构造方法相结合，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对准晶结构进行多角度分析论述。不仅需要解释准晶结构无法用晶胞表示的特性，还需说明目前常用的表征方法（拼图法），并以5次对称准晶结构为例具体描述构建方式。这涉及到对非周期性结构、对称性匹配规则等概念的关联理解，解题步骤较为复杂，属于该题型中较高难度的综合分析题。" + }, + { + "idx": 2906, + "question": "Briefly describe the influencing factors of the glass transition temperature of polymers.", + "answer": "There are many factors affecting the glass transition temperature, usually including (1) chain flexibility; (2) the influence of intermolecular forces; (3) the effect of copolymerization; (4) the influence of plasticizers, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述聚合物玻璃化转变温度的影响因素，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对聚合物玻璃化转变温度影响因素的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求简要描述聚合物玻璃化转变温度的影响因素，但需要考生理解和记忆多个相关概念（如链柔性、分子间力、共聚效应、增塑剂等），并能够进行简要的解释和描述。这比仅回答基本定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 2907, + "question": "Briefly describe the method of determining phase boundaries in polymer phase diagrams using scattered light intensity.", + "answer": "For multiphase polymer blends, when the size of the dispersed phase is comparable to the wavelength of visible light (i.e., several hundred nanometers), the scattered light intensity method can be used for measurement. When visible light passes through such materials, strong light scattering occurs, resulting in turbidity. In a single-phase system, there is no abrupt change in scattered light intensity. Therefore, for a binary polymer with composition w, if it is single-phase at low temperatures and undergoes a phase transition to two phases upon heating to a certain temperature ${\\\\bf\\\\cal I}_{1}$, the curve of scattered light intensity versus temperature will show an abrupt change. The temperature at this abrupt change point is often referred to as the 'cloud point,' which is the phase transition temperature. Similarly, the corresponding $T_{2}$ for ${\\\\mathfrak{w}}_{2}$ and $T_{3}$ for $w_{3}$ can be measured. By plotting the cloud points of blends with different compositions against their compositions, the phase boundaries can be obtained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述一种方法（使用散射光强度确定聚合物相图中的相界），答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释如何通过散射光强度方法确定聚合物相图中的相边界，涉及多步概念关联和综合分析。需要理解散射光强度与相变的关系，以及如何通过测量不同组成下的浊点来绘制相边界。这超出了简单记忆或直接套用的范畴，但尚未达到需要深度推理或创新应用的复杂分析或高级综合层次。 | 难度: 在简答题中属于中等难度，需要理解多相聚合物体系中光散射强度的变化与相变的关系，并能解释如何通过测量不同组成下的浊点来确定相边界。题目涉及的概念和步骤较为明确，但需要一定的综合分析能力来阐述整个过程。" + }, + { + "idx": 2908, + "question": "What is the glass transition temperature of a polymer?", + "answer": "Amorphous linear polymers can be divided into three states based on their mechanical properties at different temperatures: glassy state, high elastic state, and viscous flow state. At lower temperatures, the thermal motion of molecules is limited, preventing not only the movement of entire macromolecular chains but also the movement of chain segments or even individual chain units, causing the entire macromolecule to lose flexibility. In this state, the polymer resembles ordinary silicate glass in a supercooled liquid state, hence it is called the glassy state. The highest temperature (Tg) at which a polymer exhibits the glassy state is called the glass transition temperature, which is the temperature at which the polymer transitions from the high elastic state to the glassy state. During the glass transition, in addition to discontinuous and significant changes in mechanical properties such as the elastic modulus (E) of the polymer, other properties like the expansion coefficient, heat capacity, and dielectric constant also undergo notable changes. Therefore, the glass transition is not a thermodynamic phase transition but rather a state transition under non-equilibrium conditions, which can be regarded as a volume relaxation process. The glass transition temperature is an extremely important property of polymeric materials and serves as the dividing line between plastics and rubbers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释玻璃化转变温度的定义和相关概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对聚合物玻璃化转变温度的基本概念、定义及其相关特性的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对玻璃化转变温度进行解释和描述，包括其定义、相关状态转变以及重要性。虽然涉及多个概念，但主要是基础概念的记忆和解释，不需要复杂的分析或推导。相较于等级1的基本定义简答，该题目需要更详细的描述，但未达到等级3的复杂概念体系阐述程度。" + }, + { + "idx": 2909, + "question": "Due to the incompleteness of crystallization, crystalline and amorphous regions always coexist in crystalline polymers. The volume fraction crystallinity and density of two crystalline polytetrafluoroethylene samples have been measured as φ₁=51.3%, φ₂=74.2% and ρ₁=2.144 g/cm³, ρ₂=2.215 g/cm³, respectively. Calculate the densities of completely crystalline and completely amorphous polytetrafluoroethylene.", + "answer": "The density of a crystalline polymer ρ = φρ_c + (1-φ)ρ_a, where ρ_c and ρ_a are the densities of the crystalline and amorphous parts of the polymer, respectively, and φ is the volume fraction of the crystalline part. Solving the simultaneous equations: 2.144 = 0.513ρ_c + (1-0.513)ρ_a, 2.215 = 0.742ρ_c + (1-0.742)ρ_a, we obtain ρ_c = 2.296 g/cm³ and ρ_a = 1.984 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出完全结晶和非结晶聚四氟乙烯的密度。解答过程涉及建立和求解联立方程，属于典型的计算题类型。 | 知识层次: 题目需要应用密度与结晶度的关系公式，并通过解联立方程来计算完全结晶和非结晶区域的密度。这涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用密度与结晶度的关系公式，并建立联立方程进行求解。虽然计算步骤较多，但涉及的数学运算和概念关联较为直接，没有引入复杂变量或高级数学工具。因此在该题型内属于中等偏上的难度等级。" + }, + { + "idx": 2910, + "question": "At the same temperature, when the α phase (85% A, 10% B, 5% C) and β phase (10% A, 20% B, 70% C) each account for 50%, estimate the composition of the alloy.", + "answer": "Let the alloy composition be x, which must lie on the line connecting the α-β phase composition points. According to the lever rule: (α/β) = (x - 10%) / (85% - x) = 1; solving gives x = 47.5% A; then, from the concentration triangle, B = 14.5% and C = 38% are obtained.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用（如杠杆定律），最终得出合金成分的具体数值。 | 知识层次: 题目需要应用杠杆规则进行多步计算，同时需要理解相图的基本原理和浓度三角形的概念。虽然计算过程相对直接，但涉及多个成分的综合分析和关联，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆定律进行多步计算，同时涉及浓度三角形的概念关联和综合分析。虽然计算过程较为明确，但需要理解多个概念并进行综合运用，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 2911, + "question": "For an Al-Cu alloy with an atomic fraction of Cu at 4.6%, after solution treatment at 550°C, the α phase contains x(Cu)=2%. When reheated to 100°C and held for a period, the precipitated θ phase spreads throughout the entire alloy volume. The θ phase has an fcc structure with r=0.143nm, and the average spacing between θ particles is 5nm. If the Cu atoms in the α phase can be neglected after θ precipitation, how many Cu atoms does each θ particle contain?", + "answer": "The fcc structure has 4 atoms per unit cell, a=4r/√2=4×0.143/√2=0.404nm. Since x(Cu)=2%, the number of Cu atoms per cm³=0.02×4/(4.04×10⁻⁸)³=1.213×10²¹ atoms/cm³. Therefore, the number of Cu atoms per θ phase particle=1.213×10²¹/8×10¹⁸=151.6 atoms/particle", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算单位晶胞参数、铜原子数量等，最终得出每个θ相粒子包含的铜原子数。答案也以数值结果呈现，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位晶胞的计算、原子浓度的计算以及粒子间距的转换，同时需要理解固溶体和析出相的概念及其相互关系。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及固溶体成分计算、晶体结构参数推导、原子密度计算以及粒子间距与数量的关系，需要综合分析多个材料科学概念并应用相关公式。虽然计算步骤明确，但需要较强的逻辑串联能力和对材料相变过程的理解，在同题型内属于中等偏上难度。" + }, + { + "idx": 2912, + "question": "The concentration fluctuation equation for spinodal decomposition is given by $C-C_{0}=\\\\mathtt{e}^{R(\\\\lambda)t}\\\\cos{\\\\frac{2\\\\pi}{\\\\lambda}{Z}}$. Find the critical wavelength, where $R(\\\\lambda)=-M\\\\frac{4\\\\pi^{2}}{\\\\lambda}\\\\biggl[\\\\vert G^{\\\\prime}+2\\\\eta Y+\\\\frac{8\\\\pi^{2}K}{\\\\lambda^{2}}\\\\biggr]$; M is the interdiffusion mobility; $\\\\eta$ is the mismatch due to concentration gradient; $Y=\\\\frac{E}{(1-\\\\nu)}$ ($E$ is the elastic modulus, $\\\\nu$ is the Poisson's ratio); $K$ is a constant; $\\\\lambda$ is the wavelength; $Z$ is the distance; $t$ is the time; $\\\\vert G^{\\\\prime}={\\\\frac{\\\\partial^{2}\\\\dot{G_{s}}}{\\\\partial x^{2}}}$ ($G_{s}$ is the free energy of the solid solution, $_x$ represents the composition of the solid solution).", + "answer": "When $R\\\\langle\\\\lambda\\\\rangle=0$, \\n\\n$$\\nC-C_{\\\\mathrm{0}}=\\\\cos\\\\frac{2\\\\pi}{\\\\lambda}Z\\n$$\\n\\nAt this point, the composition fluctuation does not change with time, meaning spinodal decomposition does not occur. Spinodal decomposition can only occur when $R\\\\langle\\\\lambda\\\\rangle>0$, i.e., the $\\\\lambda$ value when $R(\\\\lambda)=0$ is the critical wavelength $\\\\lambda_{c}$. Therefore, \\n\\n$$\\nG^{\\\\prime\\\\prime}+2\\\\eta Y+\\\\frac{8\\\\pi^{2}K}{\\\\lambda_{\\\\odot}^{2}}=0\\n$$\\n\\n$$\\n\\\\lambda_{\\\\mathrm{{c}}}=\\\\Bigl[\\\\frac{-8\\\\pi^{2}K}{\\\\vec{G}^{\\\\eta}+2\\\\eta Y}\\\\Bigr]^{\\\\frac{3}{2}}\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和条件，计算临界波长（critical wavelength）。解答过程涉及公式推导和数值计算，符合计算题的特征。 | 知识层次: 题目涉及复杂的数学推导和物理概念的综合应用，需要深入理解spinodal分解的机理，并通过多步计算和综合分析来求解临界波长。 | 难度: 在计算题中属于机理相关复杂计算难度。题目涉及多个复杂概念的综合运用（如spinodal分解、浓度波动方程、临界波长计算等），需要理解并整合扩散动力学、弹性力学和热力学参数。解题步骤要求推导临界条件（R(λ)=0）并解出λ_c的表达式，涉及对二阶导数、弹性模量复合项的处理。虽然不涉及数值计算，但公式推导和机理解释的复杂度明显高于基础计算题，属于需要深入理解材料相变机理的中高难度问题。" + }, + { + "idx": 2913, + "question": "After quenching 1.2% steel to obtain martensite and a small amount of retained austenite structure, what changes will occur when heated to 300°C and held for 2h?", + "answer": "The retained austenite decomposes and transforms into α plus fine carbides, and the martensite also decomposes into α plus fine carbides, with the original martensite morphology becoming less distinct.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释加热和保温后材料结构的变化，答案提供了详细的文字描述和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目涉及钢的淬火后组织变化（马氏体和残余奥氏体）在加热过程中的相变行为，需要理解相变机理、组织演变过程，并能综合分析温度和时间对组织转变的影响。这需要较高的认知能力和对材料科学原理的深入理解。 | 难度: 在简答题-复杂分析题型中，该题目要求对淬火钢在回火过程中的组织转变机理进行深度解释。需要综合运用相变动力学、碳化物析出规律等专业知识，分析马氏体和残余奥氏体在300°C回火时的分解过程，并准确描述组织形态变化。虽然不涉及多因素交互作用的全面分析（等级5特征），但对单一温度下的相变机理解释已达到较深层次，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 2914, + "question": "An Al-Cu alloy with an atomic fraction of Cu at 4.6% undergoes solution treatment at 550°C, resulting in the α phase containing x(Cu)=2%. After reheating to 100°C and holding for a period, θ phase precipitates uniformly throughout the alloy volume. The θ phase has an fcc structure with r=0.143 nm, and the average spacing between θ particles is 5 nm. Calculate the number of θ phase particles per cm³ in the alloy.", + "answer": "Assuming each θ phase particle occupies a volume of 5 nm³, the number of θ particles is 1/(5×10⁻⁷)³=8×10¹⁸ particles/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定θ相颗粒的数量。答案提供了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解相变过程、计算粒子间距和体积，并最终推导出单位体积内的粒子数量。这需要综合运用材料科学中的相变知识和数学计算能力，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图、固溶体成分计算、晶体结构参数转换等多步骤概念，并应用体积计算和单位转换进行综合分析。虽然计算步骤明确，但涉及多个知识点的关联和综合运用，属于中等偏上的难度。" + }, + { + "idx": 2915, + "question": "An Al-Cu alloy with an atomic fraction of 2% Cu is rapidly cooled from 520°C to 27°C and held for 3 hours, forming G.P. zones with an average spacing of 1.5×10^-6 cm. Given that the diffusion coefficient of Cu in Al at 27°C is D=2.3×10^-25 cm²/s, and assuming the process is diffusion-controlled, estimate the quenched vacancy concentration of the alloy.", + "answer": "According to the vacancy concentration formula Cv=C0 exp(-Qv/RT), given the vacancy formation energy Qv=82.811 kJ/mol, temperature T=793 K, and R=8.314 J/(mol·K), the quenched vacancy concentration is Cv=2.3 exp(-82811/(8.314×793))=8.069×10^-6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果。答案中展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解扩散控制的析出过程，并应用扩散系数和空位浓度公式进行综合分析。虽然计算过程较为直接，但需要将多个概念（如扩散、空位浓度、G.P.区形成）结合起来，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散系数和空位浓度公式进行多步计算，涉及温度转换、能量单位统一和指数运算。虽然计算步骤明确，但需要综合理解材料科学中的扩散和空位形成概念，并正确应用相关公式。" + }, + { + "idx": 2916, + "question": "During solid-state phase transformation, assuming the volume free energy change per atom is ΔGB=200ΔT/Tc, in units of J/cm³, the critical transformation temperature Tc=1000K, strain energy ε=4J/cm³, coherent interface energy σ_coherent=4.0×10⁻⁶ J/cm², and incoherent interface energy σ_incoherent=4.0×10⁻⁵ J/cm², calculate the ratio of critical nucleation work ΔG_coherent* to ΔG_incoherent* when ΔT=50°C.", + "answer": "The nucleation work for a spherical nucleus is ΔG_coherent*=16πσ³/3(ΔGB−ε)², and if the interface is incoherent, the strain energy can be neglected, with the nucleation work being ΔG_incoherent*=16πσ³/3ΔGB². The ratio ΔG_coherent*/ΔG_incoherent*=ΔGB²σ_coherent³/(ΔGB−ε)²σ_incoherent³ =[(200×50/1000)²×(4.0×10⁻⁶)³]/[(200×50/1000−4)²×(4.0×10⁻⁵)³]=2.777×10⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及多个物理量的代入和运算，最终需要得出一个具体的数值结果。答案中展示了详细的计算步骤和最终结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相变过程中的能量变化、临界成核功的计算公式，并能够正确应用这些公式进行数值计算。虽然题目提供了具体的公式和参数，但需要综合运用这些信息来解决问题，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相变过程中的能量变化、临界成核功的计算公式，并进行多步数值计算和变量替换。题目涉及体积自由能变化、应变能、相干与非相干界面能等多个概念的综合应用，计算步骤较多但逻辑清晰，属于中等应用层次的计算题。" + }, + { + "idx": 2917, + "question": "For a quenched alloy, precipitation begins to form from the supersaturated solid solution after aging at $15^{\\\\circ}\\\\mathrm{C}$ for 1h. If aging is performed at $100^{\\\\circ}\\\\mathrm{C}$, precipitation starts after $1\\\\mathfrak{min}$. To prevent precipitation within 1 day after quenching, at what temperature should the alloy be maintained? (Hint: Apply the Arrhenius rate equation)", + "answer": "Rate $=A\\\\exp\\\\Bigl\\\\{-\\\\frac{Q}{R T}\\\\Bigr\\\\}$, so $\\\\ln t=A+\\\\frac{Q}{R T}$. Substituting the data, we obtain $Q{=}4.24\\\\times10^{4}~\\\\mathrm{J/mol}$. Substituting again, we get $\\\\pmb{T=243K(-30^{\\\\circ}C)}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解，涉及Arrhenius速率方程的使用，最终需要计算出一个具体的温度值。答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用Arrhenius速率方程进行多步计算，涉及对数变换和温度转换，需要一定的综合分析能力。虽然计算过程较为直接，但需要理解并正确应用公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯速率方程进行多步计算，涉及对数运算和温度转换，同时需要理解时效处理与析出动力学的关系。虽然计算步骤明确，但需要综合运用材料科学和数学知识，属于中等偏上的难度。" + }, + { + "idx": 2918, + "question": "After quenching 1.2% steel to obtain martensite and a small amount of retained austenite structure, what changes will occur when heated to 180°C and held for 2 hours?", + "answer": "Fine carbides begin to precipitate from the martensite laths, which are easily etched and appear dark.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释热处理过程中组织结构的变化，需要文字描述和论述，而不是选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目涉及淬火后钢的组织变化（马氏体和残余奥氏体）以及加热过程中的相变行为（碳化物析出），需要理解马氏体回火的基本原理和显微组织变化，属于多步概念关联和综合分析。虽然不涉及复杂计算，但需要对材料热处理过程有较深入的理解。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及了淬火后的钢在加热过程中的组织变化，但主要考察的是对马氏体和残余奥氏体在回火过程中行为的基本理解。解题步骤相对直接，只需描述在180°C回火2小时后马氏体析出细小碳化物的现象，并解释其易于腐蚀而呈现暗色的原因。不需要进行多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 2919, + "question": "Under the given conditions, prove the following relationship holds: ΔFπr²=(1/6)Gϕ̂²πh_max[8r−9h_max], where ΔF is the free energy difference between austenite and martensite.", + "answer": "The equation −ΔFπr²+(4/3)Gϕ̂²πrh_max−(3/2)Gϕ̂²πh_max²=0 is derived from the equilibrium condition dΔF_t/dh=0. Multiplying both sides by πr² and rearranging yields ΔFπr²=(1/6)Gϕ̂²πh_max[8r−9h_max].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求证明一个特定的关系式成立，需要通过数学推导和公式应用来完成。答案展示了具体的推导步骤和公式变换，符合计算题的特征。 | 知识层次: 题目涉及自由能差的计算和推导，需要理解相变过程中的能量平衡条件，并通过多步数学推导和公式变换来证明给定的关系式。这要求综合运用热力学、材料相变和数学推导的知识，属于较高层次的认知能力。 | 难度: 在计算题中属于机理相关复杂计算难度，需要综合运用自由能差、弹性应变能和平衡条件等概念，通过多步推导和公式变换才能得出最终关系式。解题步骤涉及物理意义的理解和数学处理的结合，在同题型内属于较高难度。" + }, + { + "idx": 2920, + "question": "In the face-centered cubic (fcc) structure of aluminum crystal, the coordination number of each aluminum atom on the (111) plane is (A)12 (B) 6 (C) 4 (D) 3", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C、D）中选择正确答案 | 知识层次: 题目考查面心立方结构中(111)面上原子的配位数这一基本概念的记忆和理解，属于晶体学基础知识的直接应用。 | 难度: 在选择题中属于中等难度，需要理解面心立方结构中(111)面的配位数概念，并进行简单辨析。虽然不涉及复杂计算，但需要对晶体结构有一定理解才能正确选择。" + }, + { + "idx": 2921, + "question": "Given the density of fully crystalline polytetrafluoroethylene ρ_c = 2.296 g/cm³ and the density of completely amorphous polytetrafluoroethylene ρ_a = 1.984 g/cm³, calculate the crystallinity of a polytetrafluoroethylene sample with a density of 2.26 g/cm³.", + "answer": "Crystallinity φ = (ρ - ρ_a)/(ρ_c - ρ_a) = (2.26 - 1.984)/(2.296 - 1.984) = 0.276/0.312 = 0.885, thus φ = 88.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的密度数据和公式进行数值计算，最终得出结晶度的百分比，属于典型的计算题。 | 知识层次: 题目需要应用给定的公式进行简单的数值计算，属于基本公式的直接套用，不需要多步计算或复杂的概念关联。 | 难度: 在计算题中属于最简单等级，仅需直接套用单一公式进行数值计算，无需任何变形或组合运算。题目给出了所有必要参数，解题步骤仅涉及基本代数运算，属于该题型内最基础的计算类型。" + }, + { + "idx": 2922, + "question": "In cubic crystals, the (110) and (211) planes belong to the same zone axis.", + "answer": "D", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目陈述了一个关于立方晶体中平面和区域轴关系的命题，要求判断其正确性（对错），答案以单个字母\"D\"给出，符合判断题的特征。 | 知识层次: 题目需要理解立方晶体中晶面属于同一晶带轴的条件，涉及晶面指数和晶带轴关系的综合分析，属于中等应用层次。 | 难度: 在判断题中属于较高难度，需要综合分析立方晶体中晶面与晶带轴的关系。解题步骤涉及理解晶带轴的定义、计算晶面指数与晶带轴的关系，并进行多步验证才能判断陈述的正确性。这超出了简单概念判断的范畴，属于需要综合应用晶体学知识的分析性判断。" + }, + { + "idx": 2924, + "question": "In polyethylene polymer materials, the C一H chemical bond belongs to (A) metallic bond (B) ionic bond (C) covalent bond (D) hydrogen bond", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(A)(B)(C)(D)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚乙烯材料中C-H化学键类型的基本概念记忆，属于基础化学键分类知识的直接应用，无需复杂分析或推理。 | 难度: 在选择题中属于简单难度，仅需直接记忆聚乙烯中C一H化学键的类型（共价键），无需复杂辨析或深度理解。" + }, + { + "idx": 2925, + "question": "After quenching, 1.2% steel obtains a martensite and a small amount of retained austenite structure. What changes will occur when heated to 680°C and held for 2 hours?", + "answer": "Carbides are distributed in granular form within the ferrite matrix, resulting in a granular pearlite structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释材料在特定热处理条件下的结构变化，答案提供了详细的文字描述而非选择、判断或计算。 | 知识层次: 题目要求分析淬火后钢在加热过程中的组织转变，涉及马氏体、残余奥氏体以及回火过程中碳化物的析出和分布，需要多步概念关联和综合分析。虽然不涉及复杂计算，但需要对材料相变和热处理过程有较深入的理解和应用能力。 | 难度: 在简答题中属于中等难度，需要理解淬火后的组织转变过程，并分析加热至680°C并保温2小时后的组织变化。题目涉及多个概念（马氏体、残余奥氏体、粒状珠光体）的关联，但不需要过于复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 2926, + "question": "When a pure metal undergoes an allotropic transformation during cooling from high temperature to room temperature with volume expansion, the atomic coordination number of the low-temperature phase is ___ that of the high-temperature phase. (A) Lower (B) Higher (C) The same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对同素异构转变过程中原子配位数变化的基本概念记忆和理解，属于材料科学基础知识的直接应用，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等难度，需要理解同素异构转变的基本概念，并能够将体积变化与配位数变化联系起来进行简单辨析。虽然不涉及复杂计算或多步骤推理，但需要一定的概念理解而非纯粹记忆。" + }, + { + "idx": 2927, + "question": "The packing density of a simple cubic crystal is (A) $100\\\\%$ (B) $65\\\\%$ (C) $52\\\\%$ (D) $58\\\\%$", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)、(D)中选择正确答案 | 知识层次: 题目考查简单立方晶体堆积密度的基本概念记忆，属于晶体结构的基础知识，不需要复杂的计算或分析。 | 难度: 在选择题中属于简单难度，直接考察对简单立方晶体堆积密度的记忆，无需复杂计算或概念辨析，属于基础概念的直接回忆。" + }, + { + "idx": 2929, + "question": "In substitutional solid solution alloys, the diffusion of solute atoms is achieved through . (A) Atomic exchange mechanism (B) Interstitial diffusion mechanism (C) Vacancy mechanism", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于置换固溶体合金中溶质原子扩散机制的正确描述 | 知识层次: 题目考查对置换固溶体中溶质原子扩散机制的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题中属于中等难度，需要理解固溶体扩散的基本机制，并对不同扩散机制（如原子交换、间隙扩散和空位扩散）进行简单辨析。虽然不涉及复杂概念的区分，但需要一定的概念理解和记忆。" + }, + { + "idx": 2930, + "question": "The flexibility of polymer materials mainly depends on the mobility of . (A) Main chain segments (B) Side groups (C) Functional groups or atoms within side groups", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于聚合物材料柔韧性主要依赖因素的正确选项 | 知识层次: 题目考查聚合物材料柔韧性的基本原理，即主链段的运动性，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等难度，需要理解聚合物材料柔韧性的主要来源，并对主链段、侧基和功能基团的作用进行简单辨析。虽然不涉及复杂概念的区分，但需要一定的概念理解能力。" + }, + { + "idx": 2931, + "question": "Two parallel screw dislocations, when their Burgers vectors are in the same direction, the interaction force between them is (A) zero (B) repulsive (C) attractive", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于两个平行螺型位错间相互作用力的正确答案 | 知识层次: 题目考查对平行螺型位错相互作用力的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于中等难度，需要理解平行螺型位错之间的相互作用力方向，并能够根据Burgers矢量的方向进行简单辨析。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力。" + }, + { + "idx": 2932, + "question": "In ionic crystals, if Schottky defects are formed in a local region, the concentration of cation vacancies in this region is equal to . \\n\\n(A) Anion vacancy concentration (B) Interstitial anion concentration (C) Interstitial cation concentration", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查离子晶体中肖特基缺陷的基本概念，即阳离子空位浓度与阴离子空位浓度的关系，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解Schottky缺陷的基本概念，即阳离子空位和阴离子空位同时成对出现，因此阳离子空位浓度等于阴离子空位浓度。虽然需要一定的概念理解，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 2933, + "question": "Among the three crystal structures of fcc, bcc, and hcp materials, the one most prone to forming twins during plastic deformation is (A) fcc (B) bcc (C) hcp", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从三个选项（A、B、C）中选择最易形成孪晶的晶体结构，符合选择题的特征 | 知识层次: 题目考查对晶体结构（fcc、bcc、hcp）及其塑性变形行为的基础概念记忆，特别是关于孪生倾向性的基本知识。 | 难度: 在选择题中属于中等偏下难度，需要理解三种晶体结构（fcc、bcc、hcp）的基本特性，并知道hcp材料在塑性变形时更容易形成孪晶。虽然涉及多个概念，但主要是对基础知识的记忆和简单辨析，不需要复杂的分析过程。" + }, + { + "idx": 2934, + "question": "For a lenticular martensite plate with thickness h and radius r, the volume can be approximated as πr²h, and the volume of the surrounding strain field can be taken as (4/3)πr³−πr²h. The strain energy per unit volume in the strain field can be expressed as (Gϕ̂²h²)/(2r²) (where G is the shear modulus and ϕ̂ is the shear angle). Assuming the diameter of the plate remains unchanged during martensite growth, explain that when the plate thickens, the thickness cannot exceed a maximum value h_max due to the limitation imposed by strain energy.", + "answer": "If the semi-coherent interface energy is negligible, the change in the system's free energy during martensite plate growth is ΔF_t=−ΔFπr²h+Gϕ̂²h²((4/3)πr³−πr²h)/(2r²). Given that the diameter remains unchanged, setting dΔF_t/dh=0 yields −ΔFπr²+(4/3)Gϕ̂²πrh_0−(3/2)Gϕ̂²πh_0²=0. Simplifying this gives ΔFr²=(1/6)Gϕ̂²h_0[8r−9h_0], where h_0 is the h_max.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体片增厚时厚度不能超过最大值的原理，并提供详细的推导过程和结论，这属于需要文字解释和论述的简答题类型。答案中包含公式推导和理论解释，符合简答题的特征。 | 知识层次: 题目要求解释马氏体片增厚过程中厚度不能超过最大值的限制，涉及应变能的计算和自由能变化的分析。需要综合运用材料科学中的应变能概念、自由能变化计算以及数学推导（求导和简化方程）来解决问题。这需要深入理解马氏体相变的机理，并能将多个概念和数学工具结合起来进行推理分析。 | 难度: 在简答题题型中，该题目属于复杂分析层次，需要综合运用多个概念（如应变能、自由能变化、半共格界面能等）进行深度推理和机理解释。解题步骤涉及复杂的数学推导和物理概念的综合应用，包括对自由能变化的微分处理和对最大厚度条件的推导。这要求考生不仅掌握相关理论知识，还需要具备较强的逻辑推理和数学运算能力。因此，在同题型内属于最高难度等级。" + }, + { + "idx": 2935, + "question": "The dislocation that cannot undergo climb motion is (A) Shockley partial dislocation (B) Frank partial dislocation (C) edge perfect dislocation", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查位错类型及其运动特性的基本概念记忆，属于对材料科学基础知识的直接考察，不需要复杂的分析或应用过程。 | 难度: 在选择题中属于中等偏下难度，需要理解不同类型位错（Shockley部分位错、Frank部分位错、刃型全位错）的基本特性，并辨析它们能否发生攀移运动。虽然涉及多个概念，但只需掌握位错的基本定义和运动特性即可作答，不需要复杂的分析过程。" + }, + { + "idx": 2936, + "question": "When a deformed material is reheated and undergoes recovery and recrystallization phenomena, the significant decrease in point defect concentration occurs during (A) recovery stage (B) recrystallization stage (C) grain growth stage", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对材料科学中恢复和再结晶过程中点缺陷浓度变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解恢复和再结晶过程中点缺陷浓度变化的基本概念，并进行简单辨析。虽然涉及两个阶段（恢复和再结晶），但主要考察对恢复阶段点缺陷减少这一特定知识点的掌握，不需要复杂的分析或深度理解多个概念的交互作用。" + }, + { + "idx": 2937, + "question": "A sample composed of three components is analyzed by X-ray diffraction (XRD) in air to study its phase transformation with temperature changes. The maximum number of coexisting phases that can be recorded is .", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（C）作为答案 | 知识层次: 题目考查对相律（Gibbs Phase Rule）这一基础概念的记忆和理解，即最大共存相数的确定，属于材料科学中的基本原理记忆性知识。 | 难度: 在选择题中属于简单难度，仅需记忆X射线衍射分析中相变研究的基本原理，即最大共存相数可以直接从基础概念中得出，无需复杂理解或辨析。" + }, + { + "idx": 2938, + "question": "After welding A and A-B alloy, the Kirkendall effect occurs, and the interface is measured to move towards the A sample. Then (A) The diffusion rate of component A is greater than that of component B (B) The opposite of (A) (C) The diffusion rates of components A and B are the same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于Kirkendall效应的正确答案 | 知识层次: 题目考查Kirkendall效应的应用，需要理解扩散速率差异对界面移动方向的影响，涉及概念关联和综合分析，但不需要复杂的推理或创新思维。 | 难度: 在选择题中属于较高难度，需要理解Kirkendall效应的基本原理，并能通过界面移动方向推断扩散速率的相对大小。这涉及到对扩散机制的综合分析，以及对实验现象的准确解读，属于复杂分析过程的判断。" + }, + { + "idx": 2939, + "question": "The Peierls-Nabarro force for dislocation slip is smaller.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出了一个陈述并要求从选项中选择正确答案（选项A），符合选择题的特征 | 知识层次: 题目考查Peierls-Nabarro力的基本概念记忆，属于对定义和基本原理的记忆性知识 | 难度: 在选择题中属于简单难度，仅需直接记忆Peierls-Nabarro力的基本特性即可作答，无需概念辨析或深度理解。" + }, + { + "idx": 2940, + "question": "The fundamental reason for diffusion to occur in materials is (A) temperature change (B) concentration gradient (C) chemical potential gradient", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查扩散现象的基本原理，属于对化学势梯度这一基础概念的简单记忆和理解，不需要复杂的应用或分析过程。 | 难度: 在选择题中属于中等难度，需要理解扩散的基本原理，并能够区分浓度梯度和化学势梯度这两个相关但不完全相同的概念。虽然题目考察的是基础概念记忆，但需要对概念有一定的理解和辨析能力。" + }, + { + "idx": 2941, + "question": "The relationship between the probability of annealing twin formation and the stacking fault energy of the crystal is (A) unrelated, only dependent on the annealing temperature and time (B) crystals with low stacking fault energy have a higher probability of forming annealing twins (C) crystals with high stacking fault energy have a higher probability of forming annealing twins", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体堆垛层错能与退火孪晶形成概率关系的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解堆垛层错能与退火孪晶形成概率之间的关系，并进行简单辨析。虽然涉及基础概念记忆，但需要将两个概念联系起来思考，比单纯记忆定义稍复杂。" + }, + { + "idx": 2942, + "question": "During the nucleation stage of solidification, only when the radius of the nucleus equals or exceeds the critical size can it become a crystallization core. When the formed nucleus has a radius equal to the critical size, the free energy change of the system is", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查的是凝固过程中成核阶段的基本概念，即临界尺寸核的形成与系统自由能变化的关系。这属于对基本原理的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解临界尺寸的概念及其与系统自由能变化的关系，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 2943, + "question": "A factory used 9Mn2V steel to make plastic molds, requiring a hardness of 58~63 HRC. After oil quenching at 790°C and tempering at 200~220°C, brittle fractures often occurred during use. Later, the process was changed to heating at 790°C followed by isothermal treatment in a nitrite salt bath at 260~280°C for 4 hours and then air cooling. Although the hardness decreased to 50 HRC, the service life was significantly improved. Please analyze the reason.", + "answer": "After quenching and low-temperature tempering, the 9Mn2V steel mainly obtains a tempered structure of plate martensite. Since the substructure of plate martensite consists of twins and microcracks exist during its formation, the brittleness is relatively high. Isothermal quenching in nitrite salt produces lower bainite, whose matrix ferrite has a substructure of high-density dislocations and no microcracks, resulting in significantly reduced brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述分析工艺改变后性能改善的原因，答案提供了详细的材料科学原理和微观结构变化的解释，符合简答题的特征。 | 知识层次: 题目要求分析材料在不同热处理条件下的组织变化及其对性能的影响，涉及对马氏体和贝氏体组织的深入理解，以及这些组织如何影响材料的硬度和韧性。需要综合运用材料科学知识进行推理分析，解释工艺改变后性能变化的原因。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2944, + "question": "In a binary system composed of A and B, when α and β phases are in equilibrium, the relationship between composition (x) and free energy (G) for the two components is (A) $G^{\\\\alpha}=G^{\\\\beta}$ (B) $\\\\mathrm{d}G^{\\\\circ}/\\\\mathrm{d}x=\\\\mathrm{d}G^{\\\\beta}/\\\\mathrm{d}x$ (C) $G_{\\\\tt A}=G_{\\\\tt B}$", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项（A、B、C）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查二元系统中两相平衡时自由能与成分的关系，需要理解自由能曲线的切线条件（公切线法则），涉及多概念关联和综合分析能力。虽然不涉及复杂计算，但需要理解热力学平衡条件的推导过程，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解相平衡条件下自由能的概念，并能正确应用化学势相等的原理（dG/dx相等）来判断两相平衡条件。题目涉及多步概念关联和综合分析，比单纯记忆性选择题（等级1-2）或单一概念应用（等级3）更为复杂，但尚未达到需要复杂推导或高难度综合应用（等级5）的程度。" + }, + { + "idx": 2945, + "question": "The relationship between the growth velocity (vg) of a certain crystal during solidification and the dynamic undercooling (ΔTx) at the liquid-solid interface front is vg proportional to ΔTx^2. This crystal belongs to which growth mechanism? (A) Continuous growth (B) Growth via screw dislocations (C) Two-dimensional nucleation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确的晶体生长机制，符合选择题的特征 | 知识层次: 题目需要理解晶体生长机制的基本概念，并能够将给定的数学关系（vg ∝ ΔTx^2）与特定的生长机制（螺位错生长）联系起来。这涉及到多步的概念关联和综合分析，而不仅仅是简单的记忆或直接套用。 | 难度: 在选择题中属于较高难度，需要理解晶体生长机制中的动态过冷概念，并能将数学关系式(vg ∝ ΔTx²)与特定生长机制(螺位错生长)建立关联。解题过程涉及多步概念分析和综合判断，比单纯记忆性选择题要求更高，但尚未达到最复杂的理论推导或跨学科综合应用水平。" + }, + { + "idx": 2946, + "question": "When most of the latent heat of crystallization can be dissipated through the liquid phase during ingot solidification, the main solid microstructure is (A) dendritic crystal (B) columnar crystal (C) spherulite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目需要理解结晶过程中潜热散失与微观结构形成的关系，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要综合分析凝固过程中的热传导机制与微观结构形成的关联。题目不仅要求掌握\"枝晶\"、\"柱状晶\"、\"球晶\"等基本概念，还需要理解潜热耗散途径对凝固组织的影响机制，涉及多步逻辑推理和相变动力学的应用分析。相比单纯记忆性选择题(等级1-2)，本题需要将传热原理与凝固理论相结合进行判断，属于复杂分析过程的判断类型。" + }, + { + "idx": 2947, + "question": "The dislocation that can undergo cross-slip must be (A) edge dislocation (B) screw dislocation (C) mixed dislocation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查位错类型的基本概念记忆和理解，特别是关于螺位错（screw dislocation）能够进行交叉滑移的特性。这属于材料科学中位错理论的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要理解位错的基本类型及其特性，特别是螺位错可以进行交叉滑移的特性。虽然涉及概念理解，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 2948, + "question": "In ionic crystals, the diffusion rate of cations is (A) faster than that of anions (B) slower than that of anions (C) neither A nor B is correct", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了三个选项（A、B、C），要求从中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查离子晶体中阳离子和阴离子扩散速率的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题的基础概念记忆层次中，该题目属于最简单的等级1。题目直接考察对离子晶体中阳离子扩散速率的基本记忆，无需任何概念辨析或复杂理解，只需识别并回忆\"阳离子扩散通常比阴离子快\"这一基础知识点即可作答。" + }, + { + "idx": 2949, + "question": "In an fcc crystal, there is a perfect dislocation with a Burgers vector of 1/2[011] on the (111) plane. When it decomposes into an extended dislocation, the leading dislocation is 1/6[121]. Determine the possible dislocation decomposition reaction and evaluate the possibility of decomposition using the structural condition and energy condition.", + "answer": "The possible dislocation reaction on the (111) plane is 1/2[011](b_{4})→1/6[\\\\overline{1}21](b_{5})+1/6[112](b_{6}). Energy condition: b_{4}^{2}=1/2, b_{5}^{2}+b_{6}^{2}=1/3. b_{4}^{2}>b_{5}^{2}+b_{6}^{2}, decomposition is feasible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定可能的位错分解反应，并使用结构条件和能量条件评估分解的可能性。答案提供了详细的文字解释和论述，包括位错反应的具体形式和能量条件的计算，符合简答题的特征。 | 知识层次: 题目要求分析位错分解的可能反应，并评估其可行性，涉及结构条件和能量条件的综合运用。需要理解位错分解的机理，进行多步推理和综合分析，属于较高层次的认知能力要求。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用晶体缺陷理论、位错分解反应的结构条件和能量条件进行深入分析。解题步骤包括确定可能的位错分解反应、验证结构条件（矢量守恒）、计算能量条件（比较分解前后位错线能量），并最终评估分解的可行性。这需要学生对位错理论有深刻理解，并能灵活运用数学和物理原理进行复杂现象的分析，属于该题型内最高难度的题目类型。" + }, + { + "idx": 2951, + "question": "When two leading dislocations 1/6[2\\overline{1}\\overline{1}] and 1/6[\\overline{1}21] move on their respective slip planes and meet, a new dislocation reaction occurs. Determine the possible dislocation reaction.", + "answer": "When b_{2} and b_{5} meet and react: b_{2}+b_{5}→1/6[110], forming a stair-rod dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错反应的可能结果，而不是从选项中选择、判断对错或进行数值计算。答案也以文字形式给出了具体的位错反应过程和结果。 | 知识层次: 题目要求分析两个位错在滑移面上相遇时可能发生的位错反应，需要综合运用位错理论、晶体学知识以及位错反应的判断标准，进行推理分析和机理解释。这涉及到多个概念的关联和较深的思维过程。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用位错理论、晶体学知识以及反应机理分析能力。具体表现为：" + }, + { + "idx": 2952, + "question": "When the crystal growth mechanism of Ge (germanium) follows the two-dimensional nucleation model, if the nuclei formed at the liquid-solid interface are cylindrical with each nucleus height h = 0.25 nm, calculate the critical nucleus diameter d*. (Given: melting point Tm = 1231 K, heat of fusion = 750000 kJ/m³, surface energy per unit area = 5.5×10⁻² J/m², undercooling during solidification ΔT = 0.01 Tm)", + "answer": "ΔG = π(d/2)²hΔGv + πdhσ\\n\\n∂ΔG/∂d = 0 yields\\nπ(d/2)hΔGv + πhσ = 0\\nd* = -2σ/ΔGv\\nSince ΔGv = -LvΔT/Tm\\nThus, d* = 2σTm/(LvΔT)\\nSubstituting the values gives d* = 14.7 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界核直径d*，答案中包含了具体的计算步骤和数值代入过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解二维成核模型、应用临界核直径公式、代入给定参数进行数值计算，并理解表面能和过冷度对临界核直径的影响。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解二维成核模型的概念，正确应用临界核直径公式，并进行多步骤的数值计算。题目涉及热力学参数（如熔化热、表面能）和凝固条件（如过冷度）的综合运用，但计算过程相对直接，没有涉及复杂多变量或迭代计算。" + }, + { + "idx": 2953, + "question": "According to the relationship d²=kt and k=17.6μm²/min, find the grain diameter d after annealing for 90 minutes.", + "answer": "d = √(17.6μm²/min × 90min) = √1584μm² = 39.8μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和数学运算，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析，属于对已知公式的简单应用。 | 难度: 在计算题中属于单一公式直接计算，仅需套用给定的公式d²=kt并进行简单的平方根运算，无需额外的公式组合或复杂步骤。" + }, + { + "idx": 2956, + "question": "According to the relationship d²=kt and k=17.6μm²/min, find the grain diameter d after annealing for 60 minutes.", + "answer": "d = √(17.6μm²/min × 60min) = √1056μm² = 32.5μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和数学运算，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于等级1难度。题目仅需直接套用单一公式d²=kt，并进行简单的平方根计算即可得出答案。没有涉及多个公式的组合或复杂的推导过程，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2957, + "question": "The main reason why it is difficult to form a single-phase structure in polymer alloys is that the alloy has (A) smaller mixing entropy (B) opposite to (A) (C) smaller mixing heat", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对聚合物合金形成单相结构困难原因的基本概念记忆，属于基本原理的记忆性知识 | 难度: 在选择题中属于中等难度，需要理解聚合物合金形成单相结构的基本原理，并对混合熵和混合热的概念进行简单辨析。虽然题目涉及基础概念记忆，但需要一定的理解能力来区分不同因素对单相结构形成的影响。" + }, + { + "idx": 2958, + "question": "Carbon atoms take 10 hours to diffuse into the surface of pure iron material at ${800}^{\\\\circ}\\\\mathrm{C}$ to a depth of $0.1\\\\mathfrak{c m}$. Calculate the time required to achieve the same carbon depth at $900^{\\\\circ}\\\\mathrm{C}$. (The diffusion activation energy of carbon atoms in fcc iron is $137520\\\\mathrm{J/mol}$.)", + "answer": "Since $D{=}D_{0}\\\\exp(-Q/R T)$, substituting the values gives $D_{800}/D_{500}{=}0.27$. The diffusion depth $x^{2}/(4D t)=$ constant. Substituting the values gives $t_{900}=2.7\\\\mathrm{hr}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解时间，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和温度对扩散系数的影响公式，并进行综合分析。虽然计算过程较为直接，但需要理解扩散深度与时间的关系，并正确应用阿伦尼乌斯方程，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程和温度对扩散系数的影响进行多步计算，涉及概念关联和综合分析，但未达到复杂多变量计算的级别。" + }, + { + "idx": 2959, + "question": "Explain the phenomenon of melting with increasing temperature in polymer crystals.", + "answer": "Crystalline polymer materials exhibit a relatively wide melting temperature range (melting range) during the melting process. The reasons are as follows: (1) The crystallization rate of polymers is slow, and the usual cooling rate cannot ensure sufficient diffusion of chain segments in the polymer to form well-developed crystals; (2) When the temperature increases, less perfect crystals melt first at lower temperatures due to their thin lamellae and high defect content, while more perfect crystals melt within a higher temperature range. This results in the phenomenon of melting with increasing temperature; (3) Slower cooling rates during crystallization can narrow the melting range.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物晶体随温度升高熔化的现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释聚合物晶体随温度升高熔融的现象，涉及聚合物结晶速率、晶体缺陷、熔融温度范围等多个复杂因素的关联分析，需要综合运用聚合物结晶理论和热力学知识进行机理解释，思维过程具有较高的深度要求。 | 难度: 在简答题（复杂分析类）中，该题目要求对聚合物晶体熔融现象进行机理深度解释。需要综合运用结晶动力学、热力学和聚合物结构知识，分析晶体缺陷、熔融温度范围与冷却速率的关系。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念描述，进入机理层面的解释，符合等级4对\"机理深度解释\"的要求。" + }, + { + "idx": 2961, + "question": "In the hexagonal crystal system, the interplanar spacing of $(11\\\\overline{2}0)$ is $(10\\\\overline{1}0)$ interplanar spacing.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了明确的选项（A）作为答案。 | 知识层次: 题目考查六方晶系中间距的计算，需要应用基本的晶体学公式进行计算，属于直接套用公式的简单应用。 | 难度: 在选择题中属于简单难度，只需要直接应用六方晶系晶面间距公式进行计算比较，无需公式变形或多步骤选择。" + }, + { + "idx": 2962, + "question": "In the seven polymorphic forms of $\\\\mathrm{{SiO}}_{2}$, there are two types of transformations: one is displacive transformation, and the other is reconstructive transformation. The activation energy required for displacive transformation is _____ that for reconstructive transformation. (A) greater than (B) less than (C) equal to", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对两种相变类型（位移型转变和重构型转变）的基本概念记忆，特别是对它们所需活化能的相对大小的理解。这属于基础概念的记忆和简单比较，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，题目考察的是对两种转化类型（displacive transformation和reconstructive transformation）的基本概念理解，需要记忆并简单比较两者的活化能大小。虽然涉及两个概念的区分，但不需要复杂的分析或深度理解，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 2963, + "question": "According to the relationship between grain diameter and annealing time d²=kt, given that the grain diameter is 23μm after annealing for 30 minutes, find the value of the constant k.", + "answer": "k = (23μm)² / 30min = 529μm² / 30min = 17.6μm²/min", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体计算，最终得出一个数值结果（k = 17.6μm²/min），符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析 | 难度: 在计算题中属于最低难度等级，仅需直接套用给定公式d²=kt进行单一数值计算，无需任何公式转换或多步骤运算。题目明确提供了所有必要参数，计算过程仅涉及基本平方运算和除法，属于最基础级别的公式应用类计算题。" + }, + { + "idx": 2965, + "question": "According to the Hall-Petch equation σ=σ₀+kd⁻¹/², given that when annealed for 30 minutes σ=112MPa, d=23μm, and when annealed for 60 minutes σ=103MPa, d=32.5μm, find the values of the constants σ₀ and k.", + "answer": "Set up the system of equations: 112MPa = σ₀ + k×(23μm)⁻¹/² 103MPa = σ₀ + k×(32.5μm)⁻¹/² The solutions are: σ₀ = 55.3MPa, k = 272MPa·μm¹/²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出σ₀和k的具体数值。解答过程涉及建立方程组和求解，属于典型的计算题。 | 知识层次: 题目需要应用Hall-Petch方程进行多步计算，建立方程组并求解未知数，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要建立并解方程组，涉及多步计算和概念关联，但未达到复杂多变量计算的难度。" + }, + { + "idx": 2967, + "question": "In a body-centered cubic structure with a lattice constant of $\\pmb{\\alpha}$, can a dislocation with a Burgers vector of a[100] decompose into $\\frac{a}{2}[111]+\\frac{a}{2}[1\\overline{{{1}}}\\overline{{{1}}}]$? (A) No (B) Yes (C) Possibly", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目需要理解体心立方结构中的位错分解原理，并应用Burgers矢量的几何关系进行分析。虽然不涉及复杂的计算，但需要将多个概念（位错、Burgers矢量、晶体结构）关联起来进行综合判断。 | 难度: 在选择题中属于较高难度，需要理解体心立方结构、位错分解的条件以及Burgers矢量的计算。题目要求考生不仅掌握基本概念，还需要进行复杂的矢量分析和能量计算来判断位错分解的可能性。这涉及到多步计算和概念关联，属于复杂分析过程的判断。" + }, + { + "idx": 2968, + "question": "In $\\\\mathrm{Ti}\\\\Omega_{2}$, when a portion of $\\\\mathrm{^{\\\\circ}Ti^{\\\\circ}}$ is reduced to $\\\\mathrm{Ti^{3+}}$, to balance the charge, there appears \\n\\n(A) oxygen ion vacancy (B) titanium ion vacancy (C) cation vacancy", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目涉及电荷平衡和缺陷化学的基本原理，需要理解Ti3+的形成如何影响晶格中的缺陷类型，并进行简单的逻辑推理。虽然不涉及复杂的计算或多步骤分析，但需要将多个概念关联起来进行综合判断。 | 难度: 在选择题中属于较高难度，需要理解晶体缺陷和电荷平衡的概念，并进行综合分析。题目涉及钛离子还原和氧空位的形成，需要考生具备一定的材料科学基础知识和逻辑推理能力。虽然不需要复杂的计算，但需要对材料缺陷化学有较深的理解，属于多步概念关联和综合分析的题目。" + }, + { + "idx": 2970, + "question": "From the symmetry of the repeating structural unit (mer) of polymers, the one that is most prone to crystallization is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择最易结晶的聚合物结构单元，答案给出的是选项B，符合选择题的特征 | 知识层次: 题目考查对聚合物结构单元对称性与结晶倾向性关系的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物结晶的基本原理和对称性概念，并进行简单辨析。虽然涉及基础概念记忆，但需要对不同结构单元的对称性进行比较判断，比纯粹的记忆题稍复杂。" + }, + { + "idx": 2971, + "question": "According to the Hall-Petch formula σ=σ₀+kd⁻¹/², given σ₀=55.3MPa, k=272MPa·μm¹/², d=39.8μm, find the yield strength σ after annealing for 90 minutes.", + "answer": "σ = 55.3MPa + 272MPa·μm¹/² × (39.8μm)⁻¹/² = 55.3MPa + 272MPa·μm¹/² × 0.1585μm⁻¹/² = 55.3MPa + 43.1MPa = 98.4MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果（yield strength σ）。解答过程涉及公式应用和逐步计算，符合计算题的特征。 | 知识层次: 题目主要考查对Hall-Petch公式的直接应用和简单计算，涉及数值代入和基本数学运算，无需多步推理或综合分析。 | 难度: 在计算题中属于基础难度，仅需直接套用Hall-Petch单一公式进行简单数值计算，无需公式组合或复杂转换，解题步骤仅涉及基本代数运算和单位换算。" + }, + { + "idx": 2972, + "question": "In the Kirkendall effect, the main reason for marker shift in a diffusion couple is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项和对应的答案 | 知识层次: 题目考查Kirkendall效应的基本原理和定义，属于基础概念的记忆和理解层面。 | 难度: 在选择题中属于中等偏下难度，需要理解Kirkendall效应的基本原理和标记物移动的原因，但不需要进行复杂的比较分析或深度推理。" + }, + { + "idx": 2973, + "question": "When forming a critical nucleus, the decrease in volume free energy can only compensate for the surface energy by", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查的是关于临界核形成过程中体积自由能和表面能之间关系的基本概念记忆和理解，属于材料科学中的基础理论知识点。 | 难度: 在选择题中属于中等偏下难度，需要理解临界核形成过程中体积自由能和表面能的关系，并进行简单辨析。虽然涉及基础概念记忆，但需要一定的理解才能正确选择答案。" + }, + { + "idx": 2975, + "question": "In substitutional solid solutions, the mode of atomic diffusion is generally", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（C） | 知识层次: 题目考查的是置换固溶体中原子扩散方式的基本概念记忆，属于材料科学中最基础的知识点之一，不需要复杂的分析或计算。 | 难度: 在选择题中属于简单难度，题目直接考察对置换固溶体中原子扩散方式的基础概念记忆，无需复杂分析或概念辨析，只需识别正确答案即可。" + }, + { + "idx": 2976, + "question": "The difference between cast iron and carbon steel lies in the presence or absence of (A) ledeburite (B) pearlite (C) ferrite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对铸铁和碳钢微观组织差异的基本概念记忆，特别是莱氏体（ledeburite）的存在与否这一关键区分点，属于基础概念的记忆和理解范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解铸铁和碳钢的基本区别，并能够识别莱氏体的存在与否是关键差异点。虽然涉及概念辨析，但不需要复杂的分析过程。" + }, + { + "idx": 2977, + "question": "In binary phase diagrams, the lever rule for calculating the relative amounts of two phases can only be used in", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（B） | 知识层次: 题目考查对二元相图中杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解杠杆规则的应用条件，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 2978, + "question": "Network polymers cannot exhibit", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（C） | 知识层次: 题目考查对网络聚合物特性的基本概念记忆，属于定义和分类层面的基础知识点。 | 难度: 在选择题中属于中等偏下难度，需要理解网络聚合物的基本特性并与其他类型聚合物进行简单区分。虽然不涉及复杂概念的深度理解，但需要一定的概念辨析能力，不能仅靠简单记忆作答。" + }, + { + "idx": 2979, + "question": "In the ionic compound $\\\\mathbf{MgO}$, the cation most likely to replace $\\\\mathbf{Mg}^{2+}$ in the compound (given the radii (nm) of each cation: (${\\\\bf Mg}^{2+}$) 0.066, ($\\\\mathbb{C}a^{2+}$) 0.099, ($\\\\mathrm{Li^{+}}$) 0.066, ($\\\\mathbf{Fe}^{\\\\mathbf{2+}}$) 0.074) is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的多个选项中选择最可能替换Mg2+的阳离子，答案以选项形式给出（C）。 | 知识层次: 题目需要理解离子半径对离子替换的影响，并综合分析多个离子的半径数据来选择最合适的替换离子。这涉及到多步推理和概念关联，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于较高难度，需要综合考虑离子半径、电荷匹配以及晶体结构稳定性等多个因素。题目要求考生不仅掌握离子半径的概念，还需要理解离子替换的规则（如电荷守恒和半径相近原则），并进行综合分析判断。虽然不需要复杂的计算，但涉及多步逻辑推理和概念关联，属于复杂分析过程的判断。" + }, + { + "idx": 2980, + "question": "In the concentration equilateral triangle of a ternary phase diagram, for alloys whose composition lies on , the content of the two components represented by the other two vertices is equal. (A) The perpendicular bisector passing through the vertex of the triangle (B) Any straight line passing through the vertex of the triangle (C) A straight line passing through the vertex of the triangle and forming a $45^{\\\\circ}$ angle with the opposite side", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对三元相图等边三角形浓度图中特定直线（通过顶点的垂直平分线）的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解三元相图中等边三角形的组成线概念，并能区分不同通过顶点的直线的含义。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，不是直接记忆就能解答的题目。" + }, + { + "idx": 2981, + "question": "According to the Clausius-Clapeyron equation, as pressure increases, the temperature at which Y-Fe transforms into $\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}$", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案（答案：B），符合选择题的特征 | 知识层次: 题目考查Clausius-Clapeyron方程的基本应用，需要理解方程的含义并能够根据压力变化推断相变温度的变化，属于直接套用基本公式的简单应用。 | 难度: 在选择题中属于简单难度，直接考察Clausius-Clapeyron方程的基本应用，无需变形或多步骤计算，仅需理解压力与相变温度的关系即可选择正确答案。" + }, + { + "idx": 2982, + "question": "Given erf(0.71)=0.68, find the value of x/(2√(Dt)).", + "answer": "x/(2√(Dt)) = 0.71.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的erf函数值和公式关系进行数值计算，最终得出x/(2√(Dt))的具体数值。解答过程涉及数学计算和公式应用，符合计算题的特征。 | 知识层次: 题目仅需要直接应用给定的误差函数值erf(0.71)=0.68，通过简单的公式应用即可得出x/(2√(Dt))的值，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用给定的erf函数值，无需任何公式转换或多步骤计算。题目已经明确给出了erf(0.71)=0.68的关系，要求解的x/(2√(Dt))直接对应erf函数的参数0.71，属于单一公式直接计算的范畴。" + }, + { + "idx": 2983, + "question": "Calculate the diffusion coefficient D of carbon at 920°C, given the activation energy for diffusion is 133984 J/mol and D0=0.23 cm²/s.", + "answer": "D = D0 × exp(-Q/(RT)) = 0.23 × exp(-133984/(8.314 × (273 + 920))) = 3.12 × 10^-7 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（扩散系数D）。解答过程涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目主要考查基本公式（阿伦尼乌斯方程）的直接应用和简单计算，不需要多步推理或综合分析，属于典型的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算难度，仅需套用阿伦尼乌斯公式进行简单数值计算，无需多步骤推导或复杂公式组合。" + }, + { + "idx": 2984, + "question": "In polymer materials, what is the bond between molecules (secondary bond)?", + "answer": "Molecular bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料中分子间的键（次级键）是什么，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查的是聚合物材料中分子间键（次级键）的基本概念记忆，属于基础概念的定义和分类范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答分子间键的基本定义（分子键），属于最基础的概念记忆层面。不需要解释或描述相关概念，更不涉及复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于直接回忆教科书定义的最简单类型。" + }, + { + "idx": 2985, + "question": "Polymer materials are", + "answer": "Materials with polymer compounds as the main component", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述聚合物材料的定义，答案是一个简短的文字描述，没有选项或计算要求 | 知识层次: 题目考查对聚合物材料基本定义的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答聚合物材料的基本定义，属于最基础的概念记忆。题目不涉及解释或描述，更不需要复杂的概念体系阐述。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 2986, + "question": "Calculate the carburizing time t, given x=0.2 cm, D=3.12 × 10^-7 cm²/s.", + "answer": "t = (x/(2 × 0.71))² / D = (0.2/(2 × 0.71))² / (3.12 × 10^-7) = 17.7 hours.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出一个数值结果（17.7 hours），符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的数值代入公式进行直接计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要直接套用给定的公式进行计算，没有涉及多个公式的组合或复杂的解题步骤。知识点掌握深度要求较低，解题步骤简单明了，属于该题型内最基础的难度水平。" + }, + { + "idx": 2987, + "question": "What are the two synthesis methods of polymer materials", + "answer": "Addition polymerization and condensation polymerization", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答两种聚合物材料的合成方法，答案以文字解释的形式给出，不需要选择或计算 | 知识层次: 题目考查聚合物材料的两种合成方法，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答两种聚合物材料的合成方法名称，属于最基础的定义性知识回忆。题目不要求解释或比较这两种方法，也不涉及任何复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最简单的类型，只需记忆两个专业术语即可作答。" + }, + { + "idx": 2988, + "question": "Using the carburization equation to calculate the value of erf(x/(2√(Dt))), given the surface carbon content ρs=1.2%, initial carbon content ρ0=0.1%, and target carbon content ρ(x,t)=0.45%.", + "answer": "erf(x/(2√(Dt))) = (ρs - ρ(x,t))/(ρs - ρ0) = (1.2 - 0.45)/(1.2 - 0.1) = 0.682.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用碳化方程进行数值计算，涉及公式应用和具体数值的代入计算，最终得出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，属于对碳化方程的直接套用。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要直接套用给定的carburization方程，进行简单的数值代入和计算，无需额外的公式组合或复杂的解题步骤。" + }, + { + "idx": 2989, + "question": "Into what categories can polymer materials be classified by application", + "answer": "Plastics, rubber, fibers, adhesives, coatings", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答聚合物材料按应用分类的类别，答案形式为列举具体分类名称而非选择或判断 | 知识层次: 题目考查对聚合物材料按应用分类的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答类型。题目仅要求列举聚合物材料按应用分类的几大类别，不需要进行概念解释或复杂体系阐述。答案只需记忆性知识即可完成，不涉及分析或推理过程，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 2990, + "question": "In polymer materials, what is the atomic bonding between molecules (primary valence force)?", + "answer": "Covalent bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料中分子间的原子键合类型，需要文字回答，而不是从选项中选择或判断对错。 | 知识层次: 题目考查聚合物材料中分子间原子键合的基本概念，即共价键的定义和记忆性知识，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答基本的定义（共价键），属于最基础的概念记忆层面，不需要解释或描述，更不需要复杂的概念体系阐述。因此在该题型和知识层次下属于等级1难度。" + }, + { + "idx": 2991, + "question": "Thermosetting plastics mainly have (5) molecular chains.", + "answer": "(5) three-dimensional network", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（three-dimensional network）来描述热固性塑料的分子链结构，属于需要简短文字回答的题目类型 | 知识层次: 题目考查热固性塑料分子链结构的基本概念记忆，属于定义和分类的基础知识。 | 难度: 在简答题题型中，此题属于基本定义简答，仅需记忆热固性塑料的主要分子链结构（三维网络）即可回答。题目不涉及概念解释或复杂体系阐述，符合等级1的难度标准。" + }, + { + "idx": 2992, + "question": "Due to the very long molecular chains, how is the relationship between secondary valence forces and primary valence forces often?", + "answer": "Greater than", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释分子链中次级价力和主价力之间的关系，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对高分子材料中次级价力和主价力关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释高分子链中次级价力与主价力的关系，需要理解并描述长分子链导致的分子间作用力变化这一概念，但不需要进行复杂的概念体系阐述或深入分析。这比单纯记忆定义（等级1）要求更高，但低于需要系统阐述多个相关概念的题目（等级3）。" + }, + { + "idx": 2993, + "question": "The geometric shapes of macromolecular chains are (1), (2), (3).", + "answer": "(1) Linear; (2) Branched; (3) Network", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举大分子链的几何形状，答案需要提供具体的文字描述（线性、支化、网状），属于需要文字回答的简答题类型。 | 知识层次: 题目考查对高分子链几何形状的基本分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求列举高分子链的几何形状，属于最基础的定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可完成，符合等级1的基本定义简答特征。" + }, + { + "idx": 2994, + "question": "Thermoplastics mainly have (4) molecular chains.", + "answer": "(4) linear", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的单词（linear）来描述热塑性塑料的分子链结构，这属于需要简短文字回答的问题类型 | 知识层次: 题目考查热塑性塑料分子链结构的基本概念记忆，属于定义和分类的基础知识。 | 难度: 在简答题题型中，此题属于最基本的概念记忆题，仅需回忆并写出热塑性塑料的主要分子链类型（线性）。不需要解释或论述，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最基础的知识点考察，对学生的要求仅限于记忆层面。" + }, + { + "idx": 2995, + "question": "The basic motion units corresponding to the three mechanical states of linear amorphous polymers are (4), (5), (6)", + "answer": "(4) chain segments or side groups; (5) chain segments; (6) macromolecular chains", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写三个空格的答案，每个空格需要具体的术语或概念，属于简答题类型，需要文字解释和论述。 | 知识层次: 题目考查对线性无定形聚合物三种力学状态对应基本运动单元的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答线性无定形聚合物三种机械状态对应的基本运动单元，需要学生对相关概念有清晰的理解和记忆，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目涉及多个相关概念的区分和对应关系，属于中等难度的概念解释类题目。" + }, + { + "idx": 2996, + "question": "The three mechanical states of linear amorphous polymers are (1), (2), (3)", + "answer": "(1) Glassy state; (2) High elastic state; (3) Viscous flow state", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举线性无定形聚合物的三种力学状态，答案需要提供具体的状态名称，属于简答题类型，不需要计算或选择选项。 | 知识层次: 题目考查对线性无定形聚合物三种力学状态的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举线性无定形聚合物的三种力学状态，无需进行概念解释或复杂阐述。答案直接对应教材中的基础分类记忆点，属于该题型内最基础的知识再现型问题。" + }, + { + "idx": 2997, + "question": "The aging of polymer materials involves structural changes such as (1) and (2).", + "answer": "(1) cross-linking; (2) scission", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的结构变化名称（cross-linking和scission），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对聚合物材料老化过程中结构变化的基本概念记忆，仅需回答两种常见变化（交联和断裂），无需深入分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回忆并列举聚合物材料老化过程中的两种结构变化（交联和断裂），不需要进行概念解释或复杂体系阐述。这符合基础概念记忆的知识层次要求，属于该题型内最基础的难度等级。" + }, + { + "idx": 2998, + "question": "The three mechanical states corresponding to linear amorphous polymers are the usage states of (7), (8), and (9)", + "answer": "(7) plastic; (8) rubber; (9) flow resin", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写三个机械状态的名称，需要文字回答而非选择或判断，属于简答题类型。 | 知识层次: 题目考查线性无定形聚合物三种力学状态的基本概念记忆，属于基础概念记忆性知识 | 难度: 在简答题中属于基本定义简答，仅需记忆线性无定形聚合物的三种力学状态名称，无需深入解释或复杂论述。" + }, + { + "idx": 2999, + "question": "What are the mechanical states of high polymers with larger molecular weight that are not completely crystalline?", + "answer": "(1) Glassy state; (2) High elastic state; (3) Leathery state; (4) Viscous flow state", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择高聚物在非完全结晶状态下的力学状态，符合选择题的特征 | 知识层次: 题目考查对高分子材料机械状态的基本分类和记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解高聚物的机械状态分类，并对不同状态进行简单辨析。虽然涉及多个选项，但都属于基础概念记忆范畴，无需复杂的分析或深度理解。" + }, + { + "idx": 3000, + "question": "What are the usage states corresponding to these mechanical states?", + "answer": "(5)Plastic; (6)Rubber; (7)Flow resin", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释不同机械状态对应的使用状态，答案以文字形式给出，需要简要描述而非选择或计算。 | 知识层次: 题目考查对不同机械状态对应的使用状态的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对机械状态对应的使用状态进行基本定义简答，属于最基础的概念记忆层次。题目仅涉及三个术语的直接对应关系，不需要解释或描述概念，更不需要进行复杂概念体系的阐述。在同类简答题中，这属于最简单的知识再现型题目。" + }, + { + "idx": 3001, + "question": "What usually breaks first when a polymer material fractures under force?", + "answer": "Covalent bonds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料在受力断裂时通常首先断裂的化学键类型，需要文字解释和论述，而不是从多个选项中选择或判断对错。答案\"Covalent bonds\"是一个简短的文字回答，符合简答题的特征。 | 知识层次: 题目考查聚合物材料断裂时共价键断裂的基本概念记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，此题仅要求回答聚合物材料断裂时最先断裂的化学键类型（共价键），属于最基础的定义性知识。不需要解释或论述断裂机制、影响因素等更深层次内容，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要描述断裂过程（等级2）或分析不同聚合物断裂行为差异（等级3）的题目简单得多。" + }, + { + "idx": 3002, + "question": "The five major engineering plastics are (1), (2), (3), (4), (5).", + "answer": "(1)Polyoxymethylene; (2)Polyamide; (3)Polycarbonate; (4)ABS; (5)Polysulfone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写五种主要工程塑料的名称，属于需要列举具体材料的简答题形式，不需要选择或判断，也不需要计算。 | 知识层次: 题目考查对五大工程塑料名称的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆类，仅需列举五大工程塑料的名称，无需解释或论述其特性、应用或相互关系。题目要求的知识点掌握深度较浅，解题步骤简单，仅需直接回忆并填写五个专有名词，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3003, + "question": "Rubber exhibits (1) physical state at -70℃.", + "answer": "(1)glass transition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（glass transition）来描述橡胶在-70℃时的物理状态，属于需要简短文字回答的类型 | 知识层次: 题目考查对橡胶在低温下物理状态变化的基础概念记忆，即玻璃化转变温度的定义和基本理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答橡胶在-70℃时的物理状态变化，属于基础定义简答。题目直接考察学生对\"玻璃化转变\"这一基本概念的识记能力，无需进行概念解释或复杂体系阐述。在同类基础概念记忆型简答题中，这是最基础的难度等级。" + }, + { + "idx": 3004, + "question": "When a factory used a nylon rope sling that had been in stock for two years, a fracture accident occurred even though the load-bearing capacity was far greater than the lifting stress. The reason for the fracture was (1).", + "answer": "(1)aging", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释断裂原因，并提供文字答案（aging），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对材料老化这一基本概念的理解和简单应用，需要将储存时间与材料性能变化联系起来，但不需要复杂的分析或计算过程。 | 难度: 在简答题中属于简单应用过程描述，题目直接给出了现象和结果，只需要考生识别出材料老化的基本概念并填写关键词\"aging\"，无需复杂推理或多步骤分析。符合等级2\"简单应用过程描述\"的标准，属于该题型框架内的基础难度。" + }, + { + "idx": 3005, + "question": "The mechanical properties of polymers are mainly determined by their degree of polymerization, crystallinity, and intermolecular forces.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），这是典型的判断题特征 | 知识层次: 题目考查对聚合物机械性能决定因素的基础概念记忆，仅需识别三个关键因素（聚合度、结晶度和分子间作用力）的正确性，不涉及应用或分析过程。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆聚合物机械性能的主要决定因素，无需深入理解或分析复杂概念。" + }, + { + "idx": 3006, + "question": "Linear polymers with high molecular weight exhibit glassy (or crystalline) state, high elastic state, and viscous flow state. Three-dimensional polymers with high crosslinking density do not possess high elasticity or viscous flow state.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物状态和交联密度影响的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解线性聚合物和三维交联聚合物的基本性质及其在不同状态下的表现。虽然题目涉及的是基础概念，但需要对两种不同类型的聚合物进行比较判断，比单纯记忆单个概念的难度稍高。" + }, + { + "idx": 3007, + "question": "ABS plastic is an engineering material with excellent comprehensive properties.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（ABS塑料是具有优异综合性能的工程材料），并要求判断其正确性（答案给出√表示正确），这符合判断题的特征。 | 知识层次: 题目考查对ABS塑料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，该题目仅涉及ABS塑料基本特性的正误判断，属于最基础的定义性知识验证，无需复杂理解或推理过程。" + }, + { + "idx": 3008, + "question": "Engineering polymers can be divided into five major types based on performance: (1), for example: (2) belongs to the (3) category, for example (4) belongs to the (5) category, for example (6) belongs to the (7) category, for example (8) belongs to the (9) category, for example (10) belongs to the (11) category.", + "answer": "(1)plastics, rubber, fibers, adhesives, coatings; (2)polyamide; (3)plastics; (4)styrene-butadiene rubber; (5)rubber; (6)polyester fiber; (7)fibers; (8)epoxy adhesive; (9)adhesives; (10)phenolic resin coating; (11)coatings", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的分类和示例，需要文字解释和论述，而不是选择或判断对错 | 知识层次: 题目主要考查对工程聚合物五大分类及其代表性材料的记忆和理解，属于基础概念的记忆性知识，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，题目要求考生记忆并分类五种主要工程聚合物类型及其代表性例子。虽然涉及多个知识点，但每个知识点都是基础概念记忆，不需要复杂的概念体系阐述或深入的解释。解题步骤相对直接，只需准确回忆和匹配分类与例子即可。" + }, + { + "idx": 3009, + "question": "Silicate glass, mica, and asbestos belong to which category of compounds? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确的化合物类别，符合选择题的特征。 | 知识层次: 题目考查对无机聚合物分类的基本概念记忆和理解，只需识别给定的材料属于哪一类化合物，不涉及复杂分析或应用。 | 难度: 在选择题中属于简单难度，仅需识别和记忆常见无机聚合物的例子，无需复杂辨析或深度理解。" + }, + { + "idx": 3010, + "question": "To which category of compounds do silicone resins and silicone rubbers belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Element-organic compounds D. Inorganic polymers", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对硅树脂和硅橡胶所属化合物类别的基本概念记忆，属于定义和分类的基础知识。 | 难度: 在选择题中属于中等难度，需要理解硅树脂和硅橡胶的分类，并与其他选项中的概念进行简单辨析。虽然涉及基础概念记忆，但需要对不同类别化合物有一定的理解才能正确选择。" + }, + { + "idx": 3011, + "question": "To which category of compounds do nylon and polysulfone belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对聚合物分类的基本概念记忆，只需识别尼龙和聚砜属于杂链有机聚合物这一知识点，不涉及复杂分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解有机聚合物的分类概念并进行简单辨析。题目考察的是对聚合物分类的基本理解，但需要区分碳链和杂链聚合物的差异，属于概念理解和简单辨析的层次。" + }, + { + "idx": 3012, + "question": "To which category of compounds do Teflon (polytetrafluoroethylene) and Plexiglas (polymethyl methacrylate) belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物基本分类的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物分类的基本概念并进行简单辨析。题目考察的是对常见聚合物类别的记忆和识别，但需要区分不同选项的含义（如碳链聚合物与杂链聚合物的区别），属于概念理解和简单辨析的范畴。" + }, + { + "idx": 3013, + "question": "The form of polymer with the lowest expansion coefficient is (1). A. Linear B. Branched C. Crosslinked", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查聚合物结构类型（线性、支化、交联）与膨胀系数关系的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆聚合物形态与膨胀系数之间的关系，无需复杂辨析或深度理解。题目明确询问最低膨胀系数的聚合物形态，答案（交联型）是基础概念的直接应用。" + }, + { + "idx": 3014, + "question": "The usage state of synthetic fibers is (). A. Crystalline state B. Glassy state C. High elastic state D. Viscous flow state", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C、D）中选择一个正确答案 | 知识层次: 题目考查对合成纤维使用状态这一基础概念的简单记忆和理解，属于材料科学中最基础的知识点，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏易难度，需要理解合成纤维的使用状态这一概念，并能区分玻璃态与其他状态（如晶态、高弹态、粘流态）的不同。虽然涉及多个概念的辨析，但题目明确指向了记忆性知识点，不需要复杂的推理过程。" + }, + { + "idx": 3015, + "question": "The elasticity of a polymer is related to which temperature? A. $T_{\\\\mathrm{m}}$ B. $T_{_{8}}$ C. $T_{t}$ D.Ta", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择与聚合物弹性相关的温度，答案形式为选项中的一个字母，符合选择题的特征。 | 知识层次: 题目考查对聚合物弹性相关温度的基本概念记忆，只需识别$T_t$（转变温度）与聚合物弹性的关系，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物弹性与温度的基本关系，并能够区分不同温度符号的含义（如Tm、Tg、Tt等），但不需要复杂的分析或深度推理。" + }, + { + "idx": 3016, + "question": "The usage state of plastic is (). A. Crystalline state B. Glassy state C. High elastic state D. Viscous flow state", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查塑料使用状态的基本概念记忆，属于对材料科学中聚合物状态分类的基础知识点的直接考察，不需要复杂的分析或应用。 | 难度: 在选择题中属于简单难度，仅需直接记忆塑料的基本使用状态（玻璃态）即可作答，无需概念辨析或深度理解。" + }, + { + "idx": 3017, + "question": "The close-packed {111} planes of the face-centered cubic (fcc) structure are stacked in the sequence ABCABC..., while the close-packed {0001} planes of the hexagonal close-packed (hcp) structure are stacked in the sequence ABABAB.... Explain how and by introducing what type of dislocations the fcc structure can be entirely transformed into the hcp structure.", + "answer": "Accordingly, if the C-layer atoms are moved to the E position (or E2, E positions, all referring to projection positions), the arrangement of the C atomic layer can be changed to that of the A atomic layer. If the B atomic layer is correspondingly moved at this time, it will change to the arrangement of the C atomic layer, and the A-layer atoms will change to the arrangement of the B layer. Therefore, introducing a partial dislocation of $\\frac{a}{6}(11\\overline{2})$ (or $\\frac{a}{6}(1\\overline{2}1)$, or $\\frac{a}{6}(211)$) into the second layer of the ABCABC... stacking and allowing it to sweep through the third layer and subsequent layers can change the atomic arrangement to ABABCABC.... Then, introducing the same dislocation into the fourth layer and performing the same operation can change the atomic arrangement to ABABABCABC..., and so on, resulting in the ABABAB... stacking sequence. In summary, by introducing partial dislocations of $\\frac{a}{6}(11\\overline{2})$ (or $\\frac{a}{6}(1\\overline{2}1)$, or $\\frac{a}{6}(211)$) into every second layer (111) plane (where n = 1, 2, 3,...) of the fcc structure's ABCABC... stacking, i.e., introducing a partial dislocation every other layer in the (111) plane, the stacking sequence can be changed to ABABAB..., thereby transforming it into the hcp stacking structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来说明如何通过引入位错将面心立方结构完全转变为六方密排结构，答案提供了详细的解释和论述过程，符合简答题的特征。 | 知识层次: 题目要求解释如何通过引入特定类型的位错将面心立方结构完全转变为六方密排结构，这需要对晶体结构、位错类型及其作用机制有深入的理解和分析能力。解答过程涉及复杂的推理和机理解释，属于综合运用和复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3018, + "question": "When a polymer material is subjected to force, the elasticity achieved by the elongation of bond length is (1). A. Ordinary elasticity B. High elasticity C. Viscoelasticity D. Forced elasticity", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案 | 知识层次: 题目考查对聚合物材料弹性类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物材料受力时的弹性类型，并进行简单辨析。虽然涉及基础概念记忆，但需要区分普通弹性、高弹性、粘弹性和强制弹性等不同概念，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 3019, + "question": "The one that is easier to obtain a crystalline structure is (1). B. Branched molecules A. Linear molecules C. Three-dimensional molecules", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查对分子结构与结晶性关系的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题中属于中等偏下难度，需要理解线性分子和支链分子在结晶性方面的基本差异，但不需要复杂的分析过程。题目考察的是对分子结构影响结晶性这一基础概念的简单辨析，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 3020, + "question": "If crystalline regions exist in polymer materials, then their melting point is (1). A. Fixed B. A temperature softening range C. Above the glass transition temperature D. Above the flow temperature", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查聚合物材料中结晶区域熔点与玻璃化转变温度关系的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解聚合物材料中结晶区的熔点特性，并能够将其与玻璃化转变温度进行比较分析。虽然题目涉及基础概念记忆，但需要一定的概念理解和简单辨析能力。" + }, + { + "idx": 3021, + "question": "The plasticity of a polymer is related to which temperature? A. $T_{\\mathrm{m}}$ B. $T_{_{8}}$ C. $T_{t}$ D.Ta", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对聚合物塑性相关温度的基本概念记忆，属于基础概念的记忆性知识 | 难度: 在选择题中属于简单难度，仅需直接记忆聚合物塑性与温度的关系，无需复杂辨析或深度理解。题目直接考察基础概念的记忆，选项明确且答案直接对应知识点。" + }, + { + "idx": 3022, + "question": "Comparison of mechanical properties, the (1) of polymers is better than that of metal materials. A. Stiffness B. Strength C. Impact strength (toughness) D. Specific strength", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（A、B、C、D）中选择最合适的答案来填空，符合选择题的特征 | 知识层次: 题目考查对聚合物和金属材料机械性能基本概念的记忆和理解，特别是关于比强度（specific strength）这一基础概念的掌握。 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物和金属材料在机械性能上的差异，并对特定强度（specific strength）这一概念有基本认识。虽然涉及概念比较，但不需要复杂的分析过程。" + }, + { + "idx": 3023, + "question": "When a polymer material is subjected to force, the elasticity achieved by the movement of chain segments is (2). A. Ordinary elasticity B. High elasticity C. Viscoelasticity D. Forced elasticity", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物材料弹性类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题中属于中等偏易难度，需要对聚合物材料受力时的弹性类型有基本理解和简单辨析能力。题目考察的是链段运动产生的高弹性这一特定概念，虽然需要区分几种弹性类型，但选项之间的区分度较为明显，属于基础概念理解和简单辨析范畴。" + }, + { + "idx": 3024, + "question": "To improve the strength of polymers, how many 'alloying' methods are there?", + "answer": "Physical modification: mainly involves adding fillers to alter the physical and mechanical properties of polymers. For example, after treatment, asbestos used as a filler for polypropylene can increase tensile strength by 60% and flexural strength by 100%. Chemical modification: through copolymerization, block, grafting, blending, and compounding methods, polymers can acquire new properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述改善聚合物强度的“合金化”方法，答案提供了详细的文字解释和论述，包括物理改性和化学改性两种方法的具体例子和效果，符合简答题的特征。 | 知识层次: 题目要求解释聚合物增强的两种主要方法（物理改性和化学改性），并举例说明。这需要理解不同改性方法的基本原理和实际应用，涉及多步骤的概念关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目要求考生不仅列举聚合物强化的\"合金化\"方法，还需要对物理改性和化学改性进行详细解释，并提供具体例子。这需要考生具备多角度分析能力，能够将理论知识与实际应用案例相结合，属于较复杂的综合分析论述题。" + }, + { + "idx": 3025, + "question": "What is the aging of polymers?", + "answer": "The phenomenon where polymer materials gradually degrade in performance and eventually lose their use value due to external factors such as oxygen, light, heat, mechanical force, water vapor, and microorganisms during long-term storage and use is called aging. The fundamental cause of aging is the cross-linking and scission of polymer molecular chains under the influence of external factors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对聚合物老化的现象进行解释和论述，答案提供了详细的文字描述和原因分析，符合简答题的特征。 | 知识层次: 题目考查聚合物老化的基本定义和原因，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释聚合物老化的现象，并简要说明其根本原因。虽然需要记忆和理解相关概念，但并不涉及复杂的概念体系阐述或多步骤的推理过程。属于基础概念记忆层次中的中等难度。" + }, + { + "idx": 3026, + "question": "Explain the role of crosslinking and how it alters the structure and properties of polymers.", + "answer": "The so-called crosslinking reaction refers to the process in which polymers, under external factors, transform from a linear structure to a three-dimensional network structure, leading to increased strength, brittleness, and improved chemical stability. The crosslinking reaction makes polymer materials harder, more brittle, and even prone to cracking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释交联的作用及其对聚合物结构和性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对交联反应的基本定义及其对聚合物结构和性能影响的基础概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释交叉连接的概念及其对聚合物结构和性能的影响，但不需要深入探讨复杂的反应机制或多种交叉连接类型的比较。" + }, + { + "idx": 3027, + "question": "What are the steps involved in the production process of ceramic materials?", + "answer": "(4) Preparation of raw materials; (5) Forming of the green body; (6) Sintering of the product", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释陶瓷材料生产过程的步骤，答案以文字形式列出具体步骤，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查陶瓷材料生产过程中基本步骤的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求解释陶瓷材料生产过程中的几个关键步骤，属于概念解释和描述的难度等级。虽然需要记忆多个步骤，但每个步骤本身是基础概念，不需要深入阐述或分析复杂关系，因此属于中等难度。" + }, + { + "idx": 3028, + "question": "How to prevent the aging of polymers?", + "answer": "Currently, there are three measures taken to prevent aging.\\n① Modify the structure of the polymer. For example, chlorinating polyvinyl chloride can improve its thermal stability.\\n② Add anti-aging agents. Incorporating organic compounds such as salicylate esters, benzophenones, and carbon black into polymers can prevent photo-oxidation.\\n③ Surface treatment. Coating the surface of polymer materials with metals (such as silver, copper, nickel) or spraying anti-aging coatings (such as paint, paraffin) as protective layers isolates the material from air, light, water, and other aging-inducing media to prevent aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何防止聚合物老化，答案提供了详细的文字解释和论述，包括三种具体措施及其原理，符合简答题的特征。 | 知识层次: 题目要求解释防止聚合物老化的多种措施，涉及结构改性、添加抗老化剂和表面处理等不同方法的综合应用。需要理解每种方法的原理和适用条件，并进行一定的分析和关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释和论述如何防止聚合物老化，但答案提供了三个明确的措施，并给出了具体的例子和解释。这需要学生对聚合物的老化机制有一定的理解，并能将不同的防止方法与具体的例子联系起来。然而，题目并未要求深入分析每种方法的原理或比较不同方法的优缺点，因此难度属于等级3的综合分析和说明。" + }, + { + "idx": 3029, + "question": "What are the advantages and disadvantages of parts made entirely of plastic?", + "answer": "Advantages: Good chemical stability, excellent corrosion resistance, high specific strength, good friction and wear properties, good insulation. Disadvantages: Low strength and elastic modulus, low hardness, cold flow phenomenon, poor heat resistance, large expansion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举塑料制品的优缺点，需要文字解释和论述，而不是选择、判断或计算。答案也以文字形式呈现，详细说明了塑料的优缺点。 | 知识层次: 题目主要考查对塑料材料优缺点的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举塑料制品的优缺点，涉及多个基本特性的记忆和简单解释，但不需要深入分析或构建复杂概念体系。虽然需要列举多个点，但每个点都是基础概念的直接应用，没有跨概念整合或高阶思维要求。" + }, + { + "idx": 3030, + "question": "To improve the toughness of polymers, how many 'alloying' methods are there?", + "answer": "Chemical modification; methods such as copolymerization, block, grafting, blending, and compounding are used to endow polymers with new properties. For example, ABS plastic is a type of plastic with excellent comprehensive performance obtained through ternary copolymerization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和列举提高聚合物韧性的“合金化”方法，答案提供了详细的文字解释和具体例子，符合简答题的特征。 | 知识层次: 题目要求列举并解释改善聚合物韧性的多种“合金化”方法，涉及多种技术（如共聚、嵌段、接枝、共混和复合）的综合应用，需要理解这些方法的基本原理及其对聚合物性能的影响。虽然不涉及复杂的计算或深度机理分析，但需要对多个概念进行关联和综合应用。 | 难度: 在简答题中属于中等难度，需要综合分析和说明多种\"alloying\"方法，并举例说明其应用。题目要求考生理解并关联多个概念（如共聚、嵌段、接枝等），但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3031, + "question": "What are the three categories of ceramic materials?", + "answer": "(1)Glass; (2)Ceramics; (3)Glass-ceramics", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举陶瓷材料的三个类别，答案以简短的文字形式给出，不需要选择或判断对错，也不需要计算。 | 知识层次: 题目考查陶瓷材料的基本分类记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求列举陶瓷材料的三个基本分类，属于最基础的定义简答类型。不需要进行概念解释或复杂体系阐述，仅需记忆性知识即可完成作答。在同题型框架内，这是最基础的难度等级。" + }, + { + "idx": 3032, + "question": "When designing plastic parts, compared to metals, list four limiting factors.", + "answer": "Low strength, low hardness, low elastic modulus, cold flow phenomenon, poor heat resistance, large expansion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举塑料零件设计中的限制因素，答案以文字解释和论述的形式呈现，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查对塑料材料限制因素的基本概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举塑料相比金属的四个限制因素，这需要学生对塑料和金属的基本性能差异有清晰的记忆和理解。虽然涉及多个知识点（如强度、硬度、弹性模量等），但不需要深入分析或复杂的概念体系阐述，只需准确回忆和简要描述这些性能差异即可。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 3033, + "question": "The Tg of the glass phase in ceramics is (5).", + "answer": "(5)Glass transition temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Glass transition temperature）作为答案，这属于需要简短文字回答的题目类型 | 知识层次: 题目考查对玻璃相变温度（Tg）这一基础概念的记忆和理解，属于材料科学中的基本定义和分类知识。 | 难度: 在简答题-基础概念记忆题型中，此题仅要求回答\"玻璃化转变温度\"这一基本定义，无需解释或描述概念，属于最简单的定义性简答。符合等级1\"基本定义简答\"的标准，是该题型框架内最基础的问题类型。" + }, + { + "idx": 3034, + "question": "The Tf of the glass phase in ceramics is (6).", + "answer": "(6) viscous flow temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语（viscous flow temperature）作为答案，属于需要简短文字回答的类型，而不是从选项中选择或判断对错。 | 知识层次: 题目考查的是玻璃相在陶瓷中的粘流温度（Tf）这一基本概念的记忆，属于定义性知识的直接回忆，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基础概念记忆类，仅需回答\"viscous flow temperature\"这一术语的定义，无需进行额外的解释或论述。题目直接考查学生对Tf（玻璃相转变温度）这一基本概念的识记能力，属于该题型内最基础的难度等级。" + }, + { + "idx": 3035, + "question": "Rubber is an excellent damping material and friction material due to its outstanding (1). A. High elasticity B. Viscoelasticity C. Plastic D. Anti-friction", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对橡胶材料基本特性的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题中属于简单难度，仅需直接识别橡胶的高弹性特性，无需复杂辨析或深度理解其他选项概念。" + }, + { + "idx": 3036, + "question": "The roles of the glass phase in ceramics are (1), (2), (3), and (4).", + "answer": "(1) bonding dispersed crystalline phases; (2) reducing sintering temperature; (3) inhibiting grain growth; (4) filling pores", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举玻璃相在陶瓷中的作用，答案以文字解释的形式给出，需要简要说明多个要点，符合简答题的特征。 | 知识层次: 题目考查对玻璃相在陶瓷中作用的基本概念记忆和理解，属于基础知识的直接回忆和列举，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求列举玻璃相在陶瓷中的四个作用，属于概念解释和描述的难度等级。虽然需要记忆多个知识点，但不需要进行复杂的逻辑推理或体系阐述，属于中等难度的简答题。" + }, + { + "idx": 3037, + "question": "The basic raw materials of traditional ceramics are (1), (2), and (3), and its structure is composed of (4), (5), and (6).", + "answer": "(1) clay; (2) quartz; (3) feldspar; (4) crystalline phase; (5) glass phase; (6) gas phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的材料名称和结构组成，需要文字回答而非选择或判断，属于简答题类型 | 知识层次: 题目考查传统陶瓷的基本原材料和结构组成，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写传统陶瓷的基本原材料和结构组成，这些都是基础概念的记忆性知识，不需要进行解释或描述。同题型内，这类直接回忆和填写基本定义的题目属于最简单的难度等级。" + }, + { + "idx": 3038, + "question": "The structure of glass is an irregular network formed by silicon-oxygen tetrahedra in space.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述句并要求判断其正确性（用√表示正确），这是典型的判断题特征 | 知识层次: 题目考查对玻璃结构的基本概念记忆，即硅氧四面体在空间中形成不规则网络的定义性知识。 | 难度: 在判断题的基础概念记忆层次中，此题仅需判断玻璃结构的基本定义是否正确，属于最基础的正误判断。题目直接陈述了硅氧四面体形成不规则网络这一基本事实，无需深入理解或分析复杂概念，符合等级1的基本概念正误判断标准。" + }, + { + "idx": 3039, + "question": "What type of alloy is YT30?", + "answer": "Tungsten-cobalt-titanium alloy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答YT30合金的类型，需要提供具体的文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对YT30合金类型的基本概念记忆，属于定义和分类层面的记忆性知识，不需要复杂的分析或应用过程。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答YT30合金的类型，即钨钴钛合金，属于基础概念记忆性知识，无需进行概念解释或复杂体系阐述。解题步骤简单直接，仅需回忆并准确写出合金分类名称即可。" + }, + { + "idx": 3040, + "question": "Which compounds can be used to prepare high-temperature ceramics?", + "answer": "(1) Oxides; (2) Carbides; (3) Nitrides; (4) Borides; (5) Silicides", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择可以用于制备高温陶瓷的化合物，答案给出了多个具体选项供选择 | 知识层次: 题目考查对高温陶瓷制备材料的分类和基本概念的简单记忆，属于基础概念记忆性知识 | 难度: 该题目属于基础概念记忆的选择题，仅需识别和记忆哪些化合物可以用于制备高温陶瓷，无需进行概念辨析或深度理解。在同类题型中属于最简单的直接记忆类型。" + }, + { + "idx": 3041, + "question": "What are the main components of YT30 alloy?", + "answer": "WC, TiC, and Co", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举YT30合金的主要成分，答案以文字形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查对YT30合金主要成分的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答YT30合金的主要成分，属于基础概念记忆层面的问题。题目不需要解释或描述这些成分的作用或相互关系，仅需简单列举，因此在该题型内属于最基本的难度等级。" + }, + { + "idx": 3042, + "question": "What can YT30 alloy be used to make?", + "answer": "Cutting tool edges", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字简要回答YT30合金的用途，不需要选择、判断或计算，符合简答题的特征 | 知识层次: 题目考查对YT30合金用途的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答YT30合金的基本用途，属于最基础的定义简答级别。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3043, + "question": "Oxide ceramics have a close-packed structure and exhibit high melting points and chemical stability due to strong ionic bonds.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对氧化物陶瓷基本特性的记忆和理解，包括其结构特点和化学稳定性的原因，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基础难度，仅需对氧化物陶瓷的基本特性（如紧密堆积结构、高熔点和化学稳定性）进行正误判断，不涉及复杂概念或推理过程。" + }, + { + "idx": 3044, + "question": "What are the main bonding types of these compounds?", + "answer": "(6) Covalent bond; (7) Ionic bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释化合物的主要键合类型，答案以文字形式给出，需要简要描述键合类型，符合简答题的特征 | 知识层次: 题目考查对化合物主要键合类型（共价键和离子键）的基本概念记忆和分类理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目仅要求列举化合物的主要键合类型，属于基础概念记忆层面的简单回答。题目不要求解释或描述键合类型的特征或原理，也不需要阐述复杂的概念体系，仅需直接回忆并写出键合类型的名称即可。因此，在同题型内属于最基本的难度等级。" + }, + { + "idx": 3045, + "question": "Ceramic materials can be used as high-temperature materials and also as wear-resistant materials.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Ceramic materials can be used as high-temperature materials and also as wear-resistant materials），并要求判断对错（答案：√），符合判断题的特征 | 知识层次: 题目考查对陶瓷材料基本应用领域的记忆和理解，属于基础概念的记忆性知识 | 难度: 在判断题中属于基本概念正误判断，仅需记忆陶瓷材料的基本用途即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 3046, + "question": "What type of chemical bond is primarily found in nitrides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择关于氮化物主要化学键类型的正确答案 | 知识层次: 题目考查对氮化物中主要化学键类型的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解氮化物的化学键类型并进行简单辨析。虽然题目涉及基础概念记忆，但需要考生对不同类型的化学键有一定的理解才能正确选择答案。" + }, + { + "idx": 3047, + "question": "Ceramic materials can be used as cutting tool materials, and can also be used as thermal insulation materials.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Ceramic materials can be used as cutting tool materials, and can also be used as thermal insulation materials），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查对陶瓷材料基本用途的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该判断题属于基础概念正误判断，仅需记忆陶瓷材料的基本用途即可作答，无需深入理解或分析复杂概念。在判断题题型中属于最简单的难度等级。" + }, + { + "idx": 3048, + "question": "What type of chemical bond is primarily found in oxides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确答案 | 知识层次: 题目考查对氧化物中主要化学键类型的基础概念记忆，属于定义和分类层面的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆氧化物中主要存在的化学键类型（离子键），无需进行概念辨析或复杂分析。" + }, + { + "idx": 3049, + "question": "Ceramic materials have low tensile strength but high compressive strength.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查对陶瓷材料基本力学性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，该题目仅涉及陶瓷材料的基本力学性能（低抗拉强度、高抗压强度）的正误判断，属于最基础的定义性知识考察，无需复杂推理或概念关联。同类题型中属于最简单直接的判断层级。" + }, + { + "idx": 3050, + "question": "The porosity of special ceramics is (4). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(4)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对特殊陶瓷孔隙率这一基础概念的记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆特殊陶瓷的孔隙率数值范围即可选出正确答案，无需概念辨析或复杂分析。" + }, + { + "idx": 3051, + "question": "The porosity of cermet is (1). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对cermet材料孔隙率范围的基础概念记忆，属于定义性知识的直接回忆，无需复杂分析或计算。 | 难度: 在选择题中属于简单难度，仅需直接记忆cermet的孔隙率范围即可作答，无需概念辨析或深度理解。" + }, + { + "idx": 3052, + "question": "The porosity of ordinary ceramics is (2). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(2)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查普通陶瓷孔隙率的基本概念记忆，属于对材料特性的基础知识点掌握。 | 难度: 在选择题中属于简单难度，仅需直接记忆普通陶瓷的孔隙率范围即可选出正确答案，无需概念辨析或深度理解。" + }, + { + "idx": 3053, + "question": "The porosity of thermal insulation material is (3). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(3)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对热绝缘材料孔隙率基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆热绝缘材料的孔隙率范围即可选出正确答案，无需复杂理解或辨析过程。" + }, + { + "idx": 3054, + "question": "What are the main types of special ceramics? Options: A. Cement B. Alumina C. Silicon carbide D. Boron nitride E. Refractory materials F. Household ceramics G. Silicon nitride H. Glass", + "answer": "B,C,D,E,G", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择特殊陶瓷的主要类型，答案给出了具体选项的组合，符合选择题的特征 | 知识层次: 题目考查对特殊陶瓷主要类型的基础概念记忆，属于分类性知识点的直接回忆，不涉及应用或分析过程。 | 难度: 在选择题中属于中等偏下难度，虽然需要记忆特殊陶瓷的主要类型，但选项中的干扰项（如水泥、家用陶瓷、玻璃）与特殊陶瓷的差异较为明显，只需基础的概念理解和简单辨析即可正确作答。" + }, + { + "idx": 3055, + "question": "What can alumina ceramic be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "C,E", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项字母组合，符合选择题的特征。 | 知识层次: 题目考查对氧化铝陶瓷常见用途的基础概念记忆，只需从给定选项中识别出正确应用场景，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要理解氧化铝陶瓷的基本应用领域并进行简单辨析。虽然题目涉及多个选项，但主要考察对材料基本用途的记忆和简单区分，不需要复杂的分析过程。" + }, + { + "idx": 3056, + "question": "What can SiC ceramics be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对SiC陶瓷应用领域的基础概念记忆，只需从给定选项中选择正确的应用场景，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要理解SiC陶瓷的基本特性及其常见应用场景，并对选项进行简单辨析。虽然涉及多个选项，但各选项之间的区分度较为明显，不需要进行复杂的比较分析。" + }, + { + "idx": 3057, + "question": "What can silicon nitride ceramics be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "A,D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项列表和答案。 | 知识层次: 题目考查对氮化硅陶瓷基本应用场景的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题中属于中等偏下难度，需要理解硅氮化物陶瓷的基本应用领域，并对选项中的工具类型进行简单辨析。虽然涉及多个选项，但知识点相对基础，属于材料科学中常见的应用记忆内容。" + }, + { + "idx": 3058, + "question": "What are included in traditional ceramics? Options: A. Cement B. Alumina C. Silicon carbide D. Boron nitride E. Refractory materials F. Household ceramics G. Silicon nitride H. Glass", + "answer": "A,F,H", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对传统陶瓷分类的基础概念记忆，只需识别哪些选项属于传统陶瓷类别，不涉及复杂分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解传统陶瓷的定义和分类，并能从选项中识别出属于传统陶瓷的材料（如水泥、家用陶瓷、玻璃），同时排除现代陶瓷材料（如氧化铝、碳化硅、氮化硼、氮化硅）。虽然需要一定的概念理解和简单辨析，但不需要复杂的区分或深度理解。" + }, + { + "idx": 3059, + "question": "What material is suitable for a thermocouple sheath? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramics D.Manganese brass", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择适合用于热电偶护套的材料，答案形式为单一选项。 | 知识层次: 题目考查对热电偶套管材料选择的基本概念记忆，只需知道高温陶瓷适合高温环境即可选出正确答案，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于中等偏易难度，需要理解热电偶护套材料的基本要求（如耐高温性能），并能从选项中排除明显不合适的材料（如PVC和锰黄铜），但不需要复杂的分析或深度理解多个概念。" + }, + { + "idx": 3060, + "question": "What type of chemical bond is primarily found in carbides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对碳化物中主要化学键类型的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解碳化物的化学键类型并进行简单辨析。虽然题目涉及基础概念记忆，但需要区分不同类型的化学键（共价键、离子键等），而不仅仅是直接识别。" + }, + { + "idx": 3061, + "question": "What material is suitable for the handle of a test pen? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramic D.Manganese brass", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最适合用于测试笔手柄的材料，答案形式为单一选项选择 | 知识层次: 题目考查对材料基本特性和应用场景的记忆，只需要知道聚氯乙烯(PVC)具有绝缘性和适合做手柄的特性即可选择正确答案，不需要复杂的分析或计算。 | 难度: 在选择题中属于简单难度，只需要直接记忆测试笔手柄的常见材料（聚氯乙烯）即可选出正确答案，无需概念辨析或复杂分析。" + }, + { + "idx": 3062, + "question": "What material is suitable for steam turbine blades? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramics D.Manganese brass", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择最适合用于蒸汽轮机叶片的材料，答案形式为选项编号，符合选择题的特征 | 知识层次: 题目考查对特定应用场景下材料选择的基本知识，需要理解不同材料的特性和适用环境，但不需要复杂的分析或多步推理。 | 难度: 在选择题中属于简单难度，只需要直接应用材料科学基础知识选择适合高温环境的材料，无需复杂计算或多步骤推理" + }, + { + "idx": 3063, + "question": "In which fields can ceramic materials be applied?", + "answer": "Applied in insulation, wear resistance, corrosion resistance, and high-temperature resistant parts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举陶瓷材料的应用领域，答案以文字解释和论述的形式给出，没有提供选项或要求进行判断或计算。 | 知识层次: 题目考查陶瓷材料应用领域的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求列举陶瓷材料的应用领域，不需要深入解释或复杂概念体系的阐述。回答仅需记忆性知识，属于最基础的简答要求。" + }, + { + "idx": 3064, + "question": "What is special ceramics?", + "answer": "To improve the performance of ordinary ceramics, it was found that the impurities brought by natural raw materials were quite unfavorable. Therefore, high-purity artificially synthesized raw materials were adopted, and the forming and sintering processes of ordinary ceramics were followed to produce new types of ceramics. These ceramics are called special ceramics, such as oxide ceramics and piezoelectric ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“special ceramics”进行解释和论述，答案提供了详细的文字描述和例子，符合简答题的特征。 | 知识层次: 题目考查特殊陶瓷的定义和基本特点，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释特殊陶瓷的定义及其特点，包括其与传统陶瓷的区别、使用的原材料和生产工艺等。虽然需要一定的记忆和理解，但不需要复杂的分析或阐述多个相关概念体系。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 3065, + "question": "What are the similarities and differences in composition between traditional ceramics and special ceramics?", + "answer": "Similarities and differences in composition: a) Traditional ceramics are made from clay, feldspar, and quartz as raw materials. b) Special ceramics: They are formed and sintered using traditional processes with artificially synthesized raw materials (various compounds with no or fewer impurities, such as oxides, nitrides, carbides). Their compositional characteristic is fewer impurities compared to traditional ceramics, and since artificially synthesized powders are used, the composition can be adjusted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释传统陶瓷和特种陶瓷在成分上的相似性和差异性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对传统陶瓷和特种陶瓷组成的基本概念记忆和理解，涉及两者的原材料和组成特点，属于基础知识的对比和描述，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释和描述传统陶瓷和特种陶瓷在成分上的相似性和差异性。虽然题目涉及两个概念的比较，但知识点相对基础，主要考察对材料组成的基本理解和记忆，不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 3066, + "question": "Why are ceramic materials brittle?", + "answer": "The brittleness of ceramic materials is influenced by both microstructural factors and macroscopic organization. From a microstructural perspective, the bonding in ceramic materials is ionic. If relative displacement occurs in ionic crystals, the electrical balance is lost, leading to the destruction of the ionic bonds, which is why materials bonded by ionic bonds are brittle. From a macroscopic organizational standpoint, ceramic materials contain a large number of pores (5%~10%), which reduce the load-bearing area when the ceramic is under stress, with pores being particularly prone to stress concentration. In summary, ceramic materials are brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷材料脆性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从微观结构和宏观组织两个角度综合分析陶瓷材料的脆性，涉及离子键的特性、电平衡的破坏以及孔隙对应力集中的影响。这需要深入理解材料科学中的键合理论和微观结构对宏观性能的影响，并进行多方面的推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对陶瓷材料的脆性进行全面的机理解释，涉及微观结构（离子键特性）和宏观组织（孔隙影响）两个层面的综合分析。解题需要深入理解材料科学原理，并能将不同层面的因素有机整合，属于该题型下的最高难度等级。" + }, + { + "idx": 3067, + "question": "What are the characteristics of ceramic materials?", + "answer": "Main performance characteristics: high hardness, high wear resistance, high elastic modulus, relatively high compressive strength, excellent high-temperature strength, good insulation, excellent high-temperature oxidation resistance, and good corrosion resistance. The disadvantages are high brittleness and low impact toughness. Solving the problem of ceramic toughening is the key to its application in the mechanical industry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对陶瓷材料的特性进行文字解释和论述，答案提供了详细的性能特点和缺点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查陶瓷材料的基本性能特点的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举陶瓷材料的主要性能特点，并简要说明其优缺点和应用关键点。虽然需要记忆多个性能指标，但不需要深入分析或建立复杂的概念体系，属于基础概念记忆层面的中等难度要求。" + }, + { + "idx": 3068, + "question": "What is traditionally referred to as 'ceramics'?", + "answer": "Ordinary ceramics are inorganic polycrystalline solid materials obtained by processing natural silicate minerals (such as clay, feldspar, and quartz) through raw material processing—forming—sintering. Therefore, this type of ceramics is also called silicate ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“ceramics”进行定义和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对传统陶瓷定义和基本组成的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答传统陶瓷的基本定义和组成材料，属于最基础的概念记忆层面。不需要进行概念间的比较或复杂体系阐述，只需直接复述教材中的基础定义即可完成作答。在同题型框架内，这属于最简单的等级1难度。" + }, + { + "idx": 3069, + "question": "Why is the tensile strength of ceramics often much lower than the theoretical strength?", + "answer": "Due to the splitting effect of pores and stress concentration during tension, the tensile strength of ceramics is lower than the theoretical strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的抗拉强度通常比理论强度低，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷拉伸强度低于理论强度的原因，涉及孔隙效应和应力集中等复杂机理的分析，需要综合运用材料科学知识进行推理和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求考生不仅理解陶瓷材料的基本性能特点，还需要深入分析孔隙和应力集中对拉伸强度的具体影响机制。这涉及到对材料微观结构与宏观性能关系的综合理解，属于机理深度解释的范畴。虽然不需要全面分析所有影响因素（如晶界、缺陷类型等），但仍需展示对关键机理的掌握和解释能力，因此属于等级4难度。" + }, + { + "idx": 3070, + "question": "What is reaction sintering?", + "answer": "Reaction sintering is a process in which ceramic powders of various compounds (such as Si, Si-SiN4 powder, etc.) are pressed into shape and then subjected to special chemical treatment during sintering to obtain ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"reaction sintering\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查反应烧结的基本定义和过程，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求对\"reaction sintering\"进行基本定义回答，属于最基础的概念记忆层次。题目不涉及复杂概念体系或需要深入解释，仅需简单描述该工艺过程即可。在同为\"基础概念记忆\"知识层次的简答题中，这是最基础、最简单的类型。" + }, + { + "idx": 3071, + "question": "What is wood composed of?", + "answer": "(1) Cellulose; (2) Lignin", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答木材的组成成分，答案以列举形式给出，属于需要简要回答的简答题类型 | 知识层次: 题目考查木材的基本组成成分，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求列举木材的主要组成成分（纤维素和木质素），属于最基本的概念记忆层面。不需要解释或描述这些成分的特性或相互关系，也不涉及复杂的概念体系阐述。因此，在同题型内属于最简单的难度等级。" + }, + { + "idx": 3072, + "question": "What is hot pressing sintering?", + "answer": "Hot pressing sintering is a method that uses ceramic powders of various compounds as raw materials, adds a small amount of additives, loads them into graphite molds, and sinters and forms under high temperature and high pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"hot pressing sintering\"进行解释和论述，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对热压烧结这一基本概念的定义和基本原理的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释热压烧结的定义和基本原理，但不需要深入阐述复杂的概念体系或进行多方面的比较分析。回答需要包含基本的定义和简单的过程描述，符合等级2的要求。" + }, + { + "idx": 3073, + "question": "What is gray cast iron composed of?", + "answer": "(3) steel matrix; (4) graphite", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案给出了多个选项中的正确组合 | 知识层次: 题目考查对灰铸铁组成的基本概念记忆，只需知道灰铸铁由钢基体和石墨组成即可回答，不涉及复杂分析或应用。 | 难度: 在选择题题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生同时掌握\"gray cast iron\"的两种组成成分（钢基体和石墨），这比单纯记忆单一成分的概念要求更高。题目不需要复杂的分析过程，但需要对铸铁材料的基本组成有明确的理解和记忆，属于概念理解和简单辨析的层次。" + }, + { + "idx": 3074, + "question": "What are the advantages and disadvantages of reaction sintering?", + "answer": "The porosity of reaction-sintered ceramics is as high as 20%~30%, so their strength is not as good as that of hot-pressed sintered ceramics. However, reaction-sintered ceramics can often be machined during chemical processing, making them suitable for producing heat-resistant, wear-resistant, corrosion-resistant insulating products with complex shapes and high dimensional accuracy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释反应烧结的优缺点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析反应烧结的优缺点，涉及对材料性能（如孔隙率、强度）和加工特性（如可加工性、适用性）的综合理解与比较，需要将多个概念关联起来进行中等程度的分析。 | 难度: 在简答题题型中，该题目要求对反应烧结的优缺点进行多角度分析论述，涉及材料性能（孔隙率、强度）、加工特性（可加工性）以及应用场景（复杂形状、高尺寸精度产品）的综合考量。虽然不需要进行深度关联性分析（如与其他烧结工艺的微观机理对比），但已超出基础概念说明的范畴，属于需要整合多个知识点的中高难度简答题。" + }, + { + "idx": 3075, + "question": "What are the advantages and disadvantages of hot pressing sintering?", + "answer": "Hot pressing sintered ceramics are limited by the mold shape and can only process simple-shaped wear-resistant and high-temperature-resistant products (e.g., cutting tools). However, hot pressing sintered ceramics have higher strength, are dense, and have extremely low porosity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释热压烧结的优点和缺点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析热压烧结的优缺点，涉及对材料性能、工艺限制等多方面因素的综合考虑和关联分析，需要一定的理解和应用能力，但不需要复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目要求对热压烧结的优缺点进行多角度分析论述。需要考生不仅列举出热压烧结的优点（如高强度、致密性、低孔隙率）和缺点（如模具形状限制、只能加工简单形状的产品），还需要对具体应用场景（如切削工具）进行关联说明。这种综合分析的要求使得该题目在同题型内属于较高难度等级。" + }, + { + "idx": 3076, + "question": "In fiber composites, what should the length of carbon fiber be", + "answer": "Tall", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案\"Tall\"是一个选项 | 知识层次: 题目考查对纤维复合材料中碳纤维长度的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆碳纤维在复合材料中的长度要求这一基础概念，无需进行概念辨析或深度理解。题目考察的是对\"tall\"这一特定术语的记忆，属于最基础的概念识别层次。" + }, + { + "idx": 3077, + "question": "In fiber-reinforced composites, the fibers with relatively good performance are mainly (1), (2), (3), (4).", + "answer": "(1)glass fiber; (2)carbon fiber; (3)boron fiber; (4)silicon carbide fiber", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举纤维增强复合材料中性能较好的纤维类型，答案以列举形式给出，属于需要文字回答的简答题类型。 | 知识层次: 题目考查对纤维增强复合材料中常用高性能纤维种类的记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答类型。题目仅要求列举四种性能较好的纤维材料名称，不需要进行概念解释或复杂体系阐述。这种记忆性知识点的考察在简答题中属于最基础的难度层级，符合等级1\"基本定义简答\"的标准特征。" + }, + { + "idx": 3078, + "question": "In fiber composite materials, how should the diameter of carbon fibers be", + "answer": "Small", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释碳纤维直径的选择，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查的是对碳纤维直径在纤维复合材料中作用的基本概念记忆和理解，属于基础知识的范畴。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答碳纤维直径的基本要求（\"Small\"），不需要进行概念解释或复杂体系阐述。这属于最基础的概念记忆性知识，在简答题框架内属于最低难度等级。" + }, + { + "idx": 3079, + "question": "In fiber composites, what should be the range of carbon fiber volume content", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对碳纤维体积含量的范围进行解释，答案需要文字描述而非选择或判断 | 知识层次: 题目涉及纤维复合材料中碳纤维体积含量的范围，需要理解复合材料的基本原理和性能优化，属于中等应用层次的知识。虽然答案简单（Higher），但解释和论述需要综合分析不同体积含量对材料性能的影响，涉及多步思考和概念关联。 | 难度: 在简答题题型中，该题目属于中等应用层次，要求考生理解碳纤维体积含量的概念，并能进行综合分析和说明。虽然题目给出了明确的答案方向（Higher），但仍需要考生解释为什么碳纤维体积含量应该较高，涉及材料性能、力学特性等方面的综合分析。相比于只需简单回忆或直接应用公式的题目，该题目需要更多的概念关联和解释，但不需要进行多角度或深度关联性分析，因此属于等级3难度。" + }, + { + "idx": 3080, + "question": "When designing fiber-reinforced composites, for a matrix with lower toughness, the coefficient of expansion of the fiber can be what? A. Slightly lower B. Very different C. Slightly higher D. The same", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案，符合选择题的特征 | 知识层次: 题目涉及纤维增强复合材料的设计，需要理解基体韧性与纤维膨胀系数之间的关系，并进行综合分析。虽然题目是选择题，但需要对材料性能的相互作用有一定理解，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解纤维增强复合材料中基体和纤维的热膨胀系数匹配原则，并分析基体韧性较低时的最佳匹配方案。虽然涉及多概念综合，但解题步骤相对直接，属于典型的中等应用层次选择题。" + }, + { + "idx": 3081, + "question": "Tungsten-cobalt carbide is a composite material of (3) and (4)", + "answer": "(3)WC; (4)Co", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的材料名称（WC和Co），需要根据知识进行简短的文字回答，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查对钨钴碳化物复合材料的基本组成成分的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求填写复合材料的具体成分（WC和Co），不需要进行概念解释或复杂阐述，属于最基础的概念记忆性知识。" + }, + { + "idx": 3082, + "question": "In fiber-reinforced composites, the smaller the fiber diameter, the better the fiber reinforcement effect.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对纤维增强复合材料中纤维直径与增强效果关系的基本概念的理解，属于基础概念记忆范畴。 | 难度: 该判断题属于基础概念正误判断，仅需记忆纤维增强复合材料中纤维直径与增强效果的基本关系即可作答，无需深入理解或分析复杂概念。在同题型内属于最简单的难度等级。" + }, + { + "idx": 3083, + "question": "What materials can be used to manufacture the vehicle body itself? Options: A. Carbon fiber resin composite material B. Thermosetting fiberglass C. Boron fiber resin composite material", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项字母 | 知识层次: 题目考查对车辆制造材料的基本概念和分类的记忆，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解不同材料类型的基本特性并进行简单辨析。虽然题目涉及的是基础概念记忆，但需要考生对碳纤维树脂复合材料、热固性玻璃纤维和硼纤维树脂复合材料有一定的区分能力，而不仅仅是简单的记忆。" + }, + { + "idx": 3084, + "question": "Fiberglass is a composite material of (1) and (2)", + "answer": "(1) Resin; (2) Glass fiber", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的材料名称，需要文字回答而非选择或判断 | 知识层次: 题目考查对复合材料基本组成的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆并准确填写两种材料的名称，无需解释或阐述复杂概念体系。" + }, + { + "idx": 3085, + "question": "The reinforcing effect is best when the diameter of the fine particle phase in fine-grained composites is (1). A. $<0.01~\\\\mu\\\\mathrm{m}$ B.0.01\\\\~0.1-pm $\\\\mathrm{C.}>0.1\\\\mu m$", + "answer": "(1)B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对细颗粒复合材料中细颗粒相直径范围的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解复合材料中细颗粒相直径对增强效果的影响，并进行简单辨析。虽然涉及具体数值范围记忆，但选项间的区分度较明显，属于基础概念理解范畴。" + }, + { + "idx": 3086, + "question": "In order to achieve high strength in composite materials, the elastic modulus of the fibers must be very high.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（关于复合材料中纤维弹性模量的要求），并要求判断该陈述的对错（答案给出√表示正确）。这符合判断题的特征，即判断陈述的真伪。 | 知识层次: 题目考查对复合材料强度与纤维弹性模量关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对复合材料强度与纤维弹性模量关系的记忆性知识，不需要复杂的理解或分析过程，只需判断陈述是否符合基础定义。这符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 3087, + "question": "When designing fiber composites, for a matrix with good plasticity, how can the coefficient of expansion of carbon fiber be? A. Slightly lower B. Very different C. Slightly higher D. The same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从选项（A. Slightly lower B. Very different C. Slightly higher D. The same）中选择正确答案 | 知识层次: 题目涉及复合材料设计中基体与纤维的热膨胀系数匹配问题，需要理解材料性能之间的相互作用和设计原则，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解复合材料设计中基体与纤维的热膨胀系数匹配原则，并分析不同选项的合理性。题目涉及材料科学中的基本概念关联，但不需要复杂的计算或高难度的综合应用。" + }, + { + "idx": 3088, + "question": "What materials can be used to manufacture rocket supports? Options: A. Carbon fiber resin composite B. Thermosetting fiberglass C. Boron fiber resin composite", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对火箭支撑材料的基本概念记忆，只需从给定选项中选择正确答案，不需要复杂的分析或计算。 | 难度: 在选择题的基础概念记忆题型中，此题需要考生理解不同复合材料的基本特性及其在火箭支撑结构中的应用。虽然选项都是复合材料，但需要考生对硼纤维树脂复合材料的特殊性能（如高强度、高模量）有基本认知才能正确选择。这比单纯记忆定义（等级1）要求更高，但尚未达到需要复杂概念区分（等级3）的程度。" + }, + { + "idx": 3089, + "question": "What are the commonly used reinforcing fibers?", + "answer": "Glass fiber, carbon fiber, boron fiber, aramid fiber, silicon carbide fiber", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举常用的增强纤维，答案以列举形式给出，不需要计算或判断对错，属于简答题类型。 | 知识层次: 题目考查对常用增强纤维种类的记忆性知识，属于基础概念的分类记忆，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求列举常见的增强纤维类型，属于最基础的定义性知识回忆。题目不要求解释纤维特性或应用场景，也不需要比较不同纤维的优劣，完全符合等级1\"基本定义简答\"的标准。在同类简答题中，这是最基础、最简单的题型表现。" + }, + { + "idx": 3090, + "question": "What types can composites be divided into according to the category of matrix materials?", + "answer": "Non-metal matrix composites and metal matrix composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据基体材料类别对复合材料进行分类，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查复合材料根据基体材料分类的基本概念记忆，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答复合材料根据基体材料分类的基本类型，属于最基础的定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可完成，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3091, + "question": "What materials can be used to manufacture helicopter propeller blades? Options: A. Carbon fiber resin composite B. Thermosetting fiberglass C. Boron fiber resin composite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对直升机螺旋桨叶片制造材料的基础概念记忆，只需从给定选项中选择正确答案，无需复杂分析或推理。 | 难度: 在选择题中属于中等偏下难度，需要理解直升机螺旋桨叶片材料的基本特性，并对碳纤维树脂复合材料、热固性玻璃纤维和硼纤维树脂复合材料进行简单辨析。虽然涉及材料选择，但知识点相对明确，属于基础概念理解和简单应用范畴。" + }, + { + "idx": 3092, + "question": "What is the reinforcement mechanism of fiber-reinforced composites?", + "answer": "Fiber-reinforced composites are formed by combining high-strength, high-modulus continuous (long) fibers or discontinuous (short) fibers with a matrix (resin, metal, ceramic, etc.). When the composite material is subjected to force, the high-strength, high-modulus reinforcing fibers bear most of the load, while the matrix primarily acts as a medium to transfer and disperse the load.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释纤维增强复合材料的增强机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查纤维增强复合材料的基本增强机制，属于基本原理的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。题目要求解释纤维增强复合材料的增强机制，涉及基本概念和原理的描述，但不需要复杂的体系阐述或多层次的分析。学生需要理解并表述纤维和基体的作用，但不需要深入探讨不同纤维类型或基体材料的详细差异。" + }, + { + "idx": 3093, + "question": "What types can composites be classified into based on the types of reinforcing materials?", + "answer": "Fiber-reinforced composites, particle-reinforced composites, and laminated composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释复合材料根据增强材料类型的分类，答案需要文字描述不同类型的复合材料，属于简答题类型。 | 知识层次: 题目考查复合材料基于增强材料类型的基本分类记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求列举复合材料基于增强材料类型的分类，属于基础概念记忆层面的简单回答。题目不涉及概念解释或复杂体系阐述，仅需直接回忆并列出分类名称即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3094, + "question": "What are the factors affecting the widespread application of composite materials?", + "answer": "Composite materials refer to multiphase materials artificially synthesized from two or more materials with different properties through various processing methods. Composites not only retain the optimal characteristics of their constituent materials but also exhibit new properties after combination. For example, the fracture energy of glass fibers is only 7.5×10^-2 J, while common resins have a fracture energy of about 2.26×10^-2 J. However, the composite material composed of glass fibers and thermosetting resins, known as thermosetting fiberglass, achieves a fracture energy as high as 17.6 J, with strength significantly higher than that of resins and brittleness much lower than that of glass fibers. It is evident that 'compositing' has become an important means to improve material performance. Therefore, composite materials are attracting increasing attention, and the development and application of new composite materials are becoming more widespread.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响复合材料广泛应用的因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析影响复合材料广泛应用的因素，涉及对复合材料性能、优缺点及其应用背景的综合理解。虽然题目提供了复合材料的基本定义和性能示例，但回答需要进一步关联实际应用中的挑战和限制，如成本、加工难度、环境适应性等，属于中等应用层次的分析和综合。 | 难度: 在简答题题型中，该题目要求对复合材料的广泛应用影响因素进行多角度分析论述。需要考生不仅理解复合材料的基本概念和性能特点，还要能够综合分析影响其应用的技术、经济、环境等多方面因素。题目涉及的知识点较为深入，且需要将不同领域的知识进行关联和整合，属于中等应用层次中较高难度的题目。" + }, + { + "idx": 3095, + "question": "What are the performance characteristics of carbon fiber?", + "answer": "Low density, high strength and modulus. It has good high and low temperature performance, high chemical stability; small thermal expansion coefficient, high thermal conductivity, good electrical conductivity and self-lubrication. Its disadvantages are high brittleness and susceptibility to oxidation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释碳纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查碳纤维性能特征的基础概念记忆和理解，属于材料科学中常见材料特性的基本知识点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要列举碳纤维的性能特点，但主要考察的是对基础概念的记忆和简单描述，不需要进行复杂的体系阐述或深入分析。题目要求回答的内容相对明确，属于该题型中中等偏下的难度水平。" + }, + { + "idx": 3096, + "question": "What are the performance characteristics of fiberglass?", + "answer": "The density is 2.4~2.7g/cm³, similar to aluminum. The tensile strength is dozens of times higher than that of bulk glass and even higher than that of bulk high-strength alloy steel. The elastic modulus is 5~8 times higher than that of other artificial fibers, and the elongation is lower than that of other organic fibers. It has relatively high heat resistance, good corrosion resistance, and excellent chemical stability to other solvents. It is easy to produce and inexpensive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述纤维玻璃的性能特点，答案提供了详细的文字描述和性能参数，符合简答题的特征。 | 知识层次: 题目主要考查对纤维玻璃性能特点的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求对纤维玻璃的性能特点进行解释和描述，涉及多个性能指标（如密度、拉伸强度、弹性模量等）的具体数值和比较，但不需要深入分析或构建复杂的概念体系。属于概念解释和描述层次，符合等级2的标准。" + }, + { + "idx": 3097, + "question": "Through what means can the performance of composite materials be further improved and their application scope expanded?", + "answer": "Composite materials refer to multiphase materials artificially synthesized from two or more materials with different properties through various process methods. Composite materials not only retain the optimal characteristics of their constituent materials but also possess new properties resulting from their combination. For example, the fracture energy of glass fiber is only 7.5×10^-2J, while that of commonly used resin is about 2.26×10^-2J. However, the composite material composed of glass fiber and thermosetting resin, known as thermosetting fiberglass, has a fracture energy as high as 17.6J, with its strength significantly higher than that of resin and its brittleness much lower than that of glass fiber. It is evident that 'compositing' has become an important means to improve material performance. Therefore, composite materials are attracting increasing attention, and the development and application of new composite materials are becoming more widespread.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的解释和例子，符合简答题的特征。 | 知识层次: 题目要求对复合材料的性能提升和应用扩展进行深入分析和综合论述，涉及多方面的知识关联和推理分析，需要综合运用材料科学原理和实际应用案例进行解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对复合材料的性能提升机理进行深度解释，需要综合运用材料科学知识，分析不同组分材料的特性及其复合后的协同效应。题目涉及断裂能等专业概念的定量对比，并要求通过具体案例（玻璃纤维增强树脂）说明复合材料的性能优势，属于机理深度解释层面的要求。" + }, + { + "idx": 3098, + "question": "What are the performance characteristics of boron fibers?", + "answer": "Boron fibers have a high melting point, high strength, high elastic modulus, and good oxidation resistance and corrosion resistance. Their disadvantages include high density, large diameter, complex production process, high cost, and expensive price.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释硼纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目主要考查对硼纤维性能特点的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要列举硼纤维的性能特点，但主要涉及基础概念的记忆和简单描述，不需要复杂的分析或体系阐述。题目要求的知识点掌握深度适中，解题步骤相对直接，符合等级2的标准。" + }, + { + "idx": 3099, + "question": "What are the performance characteristics of silicon carbide fibers?", + "answer": "High melting point, high strength, high modulus ceramic fibers, mainly used to reinforce metals and ceramics. The outstanding feature is excellent high-temperature strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释硅碳纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对碳化硅纤维性能特征的基础概念记忆和理解，包括其熔点、强度、模量等基本特性及其主要应用领域，不涉及复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答碳化硅纤维的性能特点，需要解释其高熔点、高强度、高模量等特性，并说明其主要应用领域和突出特点。这比单纯的定义简答（等级1）要求更高的理解和描述能力，但不需要进行复杂概念体系的阐述（等级3）。" + }, + { + "idx": 3100, + "question": "What are the performance characteristics of aramid fiber?", + "answer": "Its most notable characteristics are high specific strength and specific modulus. It has low density, good toughness, better heat resistance than glass fiber, excellent fatigue resistance, corrosion resistance, insulation properties, and processability, and is inexpensive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释芳纶纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对芳纶纤维性能特征的基础概念记忆和理解，属于材料特性的基本知识范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举芳纶纤维的性能特点，虽然需要记忆多个特性（如高强度、低密度、耐热性等），但不需要深入分析或建立复杂的概念体系。回答时只需按照记忆的知识点进行罗列和简要说明，属于基础概念记忆的扩展应用，符合等级2的描述性要求。" + }, + { + "idx": 3101, + "question": "What is the reinforcement mechanism of particle-reinforced composites?", + "answer": "The reinforcement mechanism of particle-reinforced composites is divided into two types: 1. Dispersion-strengthened composites are materials formed by dispersing and uniformly distributing particles (less than 0.1 micrometers) of one or several materials within the matrix material. The reinforcement mechanism of such composites is: under external forces, the matrix of the composite primarily bears the load, while the uniformly dispersed reinforcing particles hinder the movement of dislocations causing collective plastic deformation (e.g., the bypass mechanism in metal matrices) or molecular chain movement (in polymer matrices). The strengthening effect is related to particle diameter and volume fraction; the smaller the particle size and the higher the volume fraction, the better the strengthening effect. Typically, particle diameters range from 0.01 to 0.1 micrometers, and volume fractions range from 1% to 15%. 2. Particle-reinforced composites are materials formed by bonding metal oxides, carbides, or nitrides, which have good heat resistance and high hardness but poor impact resistance, using metals or polymer binders. These materials combine the advantages of high hardness and heat resistance of ceramics with the benefits of low brittleness and good impact resistance, demonstrating outstanding composite effects. Since the reinforcing particles are relatively large (greater than 1 micrometer), they do not significantly hinder dislocation slip (in metal matrices) or molecular chain movement (in polymer matrices), so the strengthening effect is not significant. Particle-reinforced composites are primarily used not to enhance strength but to improve wear resistance or overall mechanical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释粒子增强复合材料的增强机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细解释粒子增强复合材料的增强机制，涉及两种不同类型的复合材料及其各自的强化机理。需要深入理解分散强化和颗粒增强的区别，以及它们在承受外力时的行为差异。此外，还需要分析颗粒大小、体积分数对强化效果的影响，以及不同基体材料（金属或聚合物）中的强化机制。这种题目不仅需要记忆基本概念，还需要综合运用知识进行机理分析和解释。 | 难度: 在简答题题型中，该题目要求对粒子增强复合材料的增强机理进行深度解释，涉及分散强化和颗粒增强两种机制的综合分析。需要考生理解并阐述不同尺寸颗粒对材料性能的影响，以及它们在金属基体和聚合物基体中的具体作用机理。虽然题目提供了详细的知识点，但要求考生能够将这些知识点有机结合起来，进行逻辑清晰的论述，属于机理深度解释的难度等级。" + }, + { + "idx": 3102, + "question": "Elastic alloys can be divided into two major categories: (1) and (2).", + "answer": "(1) High elastic alloys; (2) Constant elastic alloys", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个类别的名称，需要文字回答而非选择或判断 | 知识层次: 题目考查对弹性合金分类的基本概念记忆，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目仅要求记忆和列举弹性合金的两大基本分类，属于最基础的定义性知识复现。题目不涉及概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的特征。同类题型中，这比需要解释分类标准（等级2）或论述性能差异（等级3）的题目简单得多。" + }, + { + "idx": 3103, + "question": "What is the development direction of materials science?", + "answer": "In the 21st century, materials science will inevitably develop towards high functionality, ultra-high performance, complexity (compositing and complicating), refinement, ecological environmentalization, and intelligence, based on the rapid advancement of science and technology, thereby making greater contributions to the material civilization of human society.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对材料科学的发展方向进行文字解释和论述，答案提供了详细的描述和展望，符合简答题的特征。 | 知识层次: 题目要求对材料科学的发展方向进行综合性的论述，涉及多个高级概念（如高功能性、超高性能、复杂性、精细化、生态环境化和智能化）的综合运用和深度理解，需要基于科技快速发展的背景进行推理分析，并对未来发展趋势做出贡献性预测，体现了创新应用和深度理解的认知能力层次。 | 难度: 在简答题中属于较高难度，需要综合运用高级材料科学知识，对材料科学发展方向进行系统性的论述和分析。题目要求考生不仅掌握材料科学的基本概念，还需要对未来的发展趋势有深入的理解和创新性的思考。虽然不需要进行实验设计或具体计算，但需要对多个发展方向进行整合和逻辑阐述，体现了较高的综合能力和前瞻性思维。" + }, + { + "idx": 3104, + "question": "Commonly used expansion materials are divided into three categories: (1), (2), (3).", + "answer": "(1) Low expansion materials; (2) Controlled expansion materials; (3) High expansion materials", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举三种常见的膨胀材料类别，答案需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对膨胀材料分类的基础概念记忆，属于定义和分类的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举三种常用的膨胀材料分类，不需要进行概念解释或复杂体系阐述。答案直接对应教材中的基础分类记忆点，解题步骤简单，仅需回忆并准确写出三类名称即可。在同题型框架内，这属于最基础的知识点再现型问题。" + }, + { + "idx": 3105, + "question": "High elastic alloys have (1). A. high elastic limit and high elastic modulus B. high elastic limit and low elastic modulus C. low elastic limit and high elastic modulus D. low elastic limit and low elastic modulus", + "answer": "(1)B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案 | 知识层次: 题目考查对高弹性合金基本特性的记忆和理解，即高弹性极限和低弹性模量的组合。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解高弹性合金的基本特性（高弹性极限和低弹性模量）并进行简单辨析，但不需要复杂的分析或深度理解多个概念之间的关系。" + }, + { + "idx": 3106, + "question": "Below the critical temperature Tc, superconductors possess complete (1) what property?", + "answer": "Electrical conductivity", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字回答超导体在临界温度Tc以下具有的特定性质，答案是一个简短的术语\"Electrical conductivity\"，不需要选择、判断或计算 | 知识层次: 题目考查超导体在临界温度以下的基本性质，即完全导电性（零电阻），属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答超导体在临界温度以下的一个基本属性（完全导电性），属于最基础的定义性知识，不需要解释或论述过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3107, + "question": "Below the critical temperature Tc, superconductors exhibit complete (2) what property?", + "answer": "Diamagnetism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用一个专业术语（Diamagnetism）来填空回答问题，属于需要简短文字回答的简答题类型 | 知识层次: 题目考查对超导体在临界温度以下表现出的基本特性的记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答一个基础概念（完全抗磁性），属于对定义性知识的直接回忆。不需要解释或描述，更不需要复杂概念体系的阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3108, + "question": "Shape memory alloys utilize the characteristics of (1) and (2) of the material to achieve shape recovery.", + "answer": "(1) superelasticity; (2) shape memory effect", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个特定的材料特性名称，属于需要简短文字回答的题目类型 | 知识层次: 题目考查形状记忆合金的基本特性（超弹性和形状记忆效应）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求填写两个特定的术语（超弹性和形状记忆效应），这些是形状记忆合金的基础概念记忆性知识，不需要深入的解释或复杂的论述。同题型内相比，解题步骤简单，仅需回忆和准确填写术语即可，属于最基础的难度水平。" + }, + { + "idx": 3109, + "question": "Resistance materials can be divided into (1), (2), and (3) according to their characteristics and applications.", + "answer": "(1) Precision resistance materials; (2) Film resistance materials; (3) Electric heating materials", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的分类名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对电阻材料分类的基本概念记忆，属于定义和分类的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举电阻材料的三种分类，不需要进行概念解释或复杂体系阐述，仅需记忆性知识即可完成作答。" + }, + { + "idx": 3110, + "question": "Hydrogen storage alloys are alloys that form hydrogen-containing solid solutions by absorbing hydrogen, and under certain conditions, these alloys decompose to release hydrogen", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查氢存储合金的基本定义和功能，属于基础概念的记忆和理解 | 难度: 在判断题题型中，该题目仅涉及基础概念的正误判断，即氢存储合金的定义和基本特性。题目陈述直接明确，无需复杂推理或概念间的比较分析，属于最基础的记忆性知识判断。" + }, + { + "idx": 3111, + "question": "The temperature coefficient of resistance (1) of resistive materials. A. The larger the better B. The smaller the better C. No requirement on size", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查对电阻材料温度系数基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念记忆的选择题，仅需直接回忆温度系数电阻的基本特性即可作答，无需进行概念辨析或深度理解。在同类题型中属于最简单的直接记忆型题目。" + }, + { + "idx": 3112, + "question": "Shape memory alloy components undergo plastic deformation in the (1) state and recover their original shape after (2). A. Martensite Heating transforms into parent phase B. Parent phase Cooling transforms into martensite C. Martensite Staying for several days D. Parent phase Heating transforms into new parent phase", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了多个选项供选择 | 知识层次: 题目考查形状记忆合金的基本概念和相变过程，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解形状记忆合金的基本相变原理（马氏体和母相的相互转变），并能区分加热和冷却过程对相变的影响。虽然涉及两个空格的填空，但选项表述清晰，只需掌握基础概念即可正确选择。" + }, + { + "idx": 3113, + "question": "The active layer and passive layer of a thermostatic bimetal strip are respectively (1). A. Constant expansion alloy and high expansion alloy B. High expansion alloy and constant expansion alloy C. Constant expansion alloy and low expansion alloy D. High expansion alloy and low expansion alloy", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查对热双金属片主动层和被动层材料的基本分类和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解热双金属片的基本组成（主动层和被动层）及其对应的材料特性（高膨胀合金和低膨胀合金），但不需要复杂的分析或深度理解多个相关概念。" + }, + { + "idx": 3114, + "question": "What characteristics do high-elastic alloys have?", + "answer": "These alloys require a high elastic limit σe and a low elastic modulus E, meaning a high σe/E ratio, which minimizes the elastic after-effect of components and ensures stable operation. Additionally, they must possess high fatigue strength and good workability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释高弹性合金的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高弹性合金的特性，涉及多个性能指标（弹性极限、弹性模量、疲劳强度、加工性）的综合分析，需要理解这些性能之间的关联及其对材料性能的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求解释高弹性合金的特性，涉及弹性极限、弹性模量、疲劳强度和可加工性等多个概念的综合分析。虽然需要关联多个知识点，但不需要进行深度关联性分析或多角度论述，因此属于综合分析和说明的难度等级。" + }, + { + "idx": 3115, + "question": "What are the characteristics of future materials science research?", + "answer": "Currently, due to the increasing demand for new materials, there is a desire to enhance theoretical predictability and reduce blind experimentation in materials development as much as possible. Objectively, the in-depth development of modern fundamental sciences such as physics and chemistry has provided many new principles and concepts. More importantly, advancements in computer information processing technology, as well as various material preparation and characterization techniques, have led to some new features in materials development and design. 1) In terms of the microscopic structure design of materials, the focus will shift from the microstructural level (-1μm) to the molecular and atomic levels (1~10nm) and the electronic level (0.1~1nm) (developing micrometer and nanometer materials). 2) The conceptual idea of mixing organic, inorganic, and metallic materials at the atomic and molecular levels to form so-called 'hybrid' (Hybrid) materials, exploring new pathways for synthetic materials. 3) In the development of new materials, based on databases and knowledge repositories, computers are used to predict the properties of new materials and simulate the relationship between the microscopic structure and properties of new materials. 4) In-depth research into the production processes of materials under various conditions, employing new thinking and adopting new technologies to develop new materials, such as the design of semiconductor superlattice materials, exemplified by 'bandgap engineering' or 'atomic engineering.' This involves controlling the electronic structure of materials to create multilayer heterostructure periodic materials composed of alternating ultrathin layers of different semiconductors, thereby greatly advancing the development of semiconductor lasers. 5) Selecting key objectives and organizing multidisciplinary efforts to jointly design certain new materials, such as the concept and practice of 'functionally graded' materials (FGM) proposed according to the requirements of aerospace thermal protection materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"未来材料科学研究的特征\"进行详细的文字解释和论述，答案提供了多个方面的详细描述，符合简答题的特点。 | 知识层次: 题目要求对材料科学未来研究的特点进行综合分析和深度理解，涉及多个复杂概念（如微观结构设计、混合材料、计算机预测、生产工艺研究、多学科合作等）的综合运用和创新应用。需要将不同领域的知识进行整合，并提出前瞻性的观点和设计思路。 | 难度: 在简答题题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 3116, + "question": "What are the categories of high elastic alloys?", + "answer": "High elastic alloys can be divided into steel, copper alloys, nickel-based and cobalt-based alloys by composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对高弹性合金的分类进行文字解释和论述，答案提供了详细的分类说明，符合简答题的特征。 | 知识层次: 题目考查高弹性合金的分类，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举高弹性合金的分类，不需要进行概念解释或复杂体系阐述。答案直接给出了按成分划分的四个类别，属于最基础的概念记忆性知识，符合等级1对知识点掌握深度和解题步骤简单的要求。" + }, + { + "idx": 3117, + "question": "What are the characteristics of constant expansion alloys?", + "answer": "Materials with a certain coefficient of expansion within a specific temperature range are called constant expansion materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释恒定膨胀合金的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对恒定膨胀合金特性的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在简答题中属于基本难度，仅需回答材料的定义和基本特性，不涉及复杂的概念解释或体系阐述。题目要求的知识点掌握深度较浅，解题步骤简单，属于基础概念记忆的范畴。" + }, + { + "idx": 3118, + "question": "What is resistive material?", + "answer": "Materials used in physical components that serve a resistive function in circuits are called resistive materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"resistive material\"进行文字解释和定义，答案提供了概念性的描述而非选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即电阻材料的定义和基本功能。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。不需要解释或描述复杂概念，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3119, + "question": "What is the main use of controlled expansion alloys?", + "answer": "This type of material is used in the electric vacuum industry to seal with glass, ceramics, etc., requiring its expansion coefficient to match that of the sealed material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释controlled expansion alloys的主要用途，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对控制膨胀合金主要用途的基础概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生解释控制膨胀合金的主要用途，并简要说明其应用原理（膨胀系数匹配）。这需要考生不仅记住基本定义，还要理解材料特性与应用场景的关系，属于对基础概念的延伸性解释，但不需要复杂的概念体系阐述。" + }, + { + "idx": 3120, + "question": "What are the characteristics of resistance materials?", + "answer": "The general requirements are high and stable resistance values, a small temperature coefficient of resistance, and sufficient mechanical strength, while also requiring a small thermoelectric potential with copper, good corrosion resistance, and ease of machining and welding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释电阻材料的特性，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对电阻材料特性的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目要求解释电阻材料的特性，涉及多个具体特征（如高且稳定的电阻值、小的温度系数、足够的机械强度等），需要学生对相关概念有一定的理解和记忆，并进行适当的描述和解释。虽然不涉及复杂的概念体系阐述，但比单纯的定义简答要求更高，因此属于等级2。" + }, + { + "idx": 3121, + "question": "What is the critical temperature Tc of a superconductor?", + "answer": "The temperature at which the resistance abruptly drops to zero is called the superconducting transition temperature or critical temperature Tc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释什么是超导体的临界温度Tc，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查超导体临界温度Tc的基本定义，属于基础概念的记忆和理解层面，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求回答超导体临界温度Tc的基本定义，属于最基础的概念记忆性知识。不需要额外的解释或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3122, + "question": "What is a superconductor?", + "answer": "Generally, the DC resistivity of metals decreases as temperature drops, and near absolute zero, the resistivity no longer continues to decline but approaches a finite value. However, the DC resistivity of certain conductors suddenly drops to zero at a specific low temperature, a phenomenon known as zero resistance or superconductivity. Objects exhibiting such superconducting properties are typically referred to as superconductors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对超导体进行定义和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对超导体这一基本概念的定义和特性的记忆和理解，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求解释超导体的定义和基本现象，涉及对零电阻和超导性的描述，但不需要深入探讨复杂的理论体系或进行多层次的阐述。因此，它比基本定义简答（等级1）稍复杂，但未达到复杂概念体系阐述（等级3）的要求。" + }, + { + "idx": 3123, + "question": "What are the main uses of superconductors?", + "answer": "Superconductors can not only be used in superconducting generators, but also prove effective in applications such as superconducting motors, superconducting power transmission, superconducting energy storage, maglev trains, magnetohydrodynamic power generation, and nuclear fusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举超导体的主要用途，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对超导体主要用途的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求列举超导体的主要用途，属于概念解释和描述的难度等级。虽然需要记忆多个应用场景，但不需要深入阐述复杂的概念体系或进行多层次的逻辑推理，因此属于中等难度。" + }, + { + "idx": 3124, + "question": "Explain the basic concept and terminology: Superstructure", + "answer": "Superstructure: The lattice constant of an ordered solid solution differs from that of a disordered solid solution, resulting in additional diffraction lines on the X-ray diffraction pattern, known as superstructure lines. Therefore, an ordered solid solution is also referred to as a superstructure or superlattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对超结构（Superstructure）这一基本概念的定义和术语的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求解释\"Superstructure\"的基本概念和术语，答案提供了定义并解释了其与X射线衍射图案的关系。虽然涉及一些专业术语（如\"lattice constant\"、\"ordered solid solution\"等），但整体上仍属于对单一概念的描述性解释，不需要复杂的体系阐述或多概念关联分析。" + }, + { + "idx": 3125, + "question": "Explain the basic concept and terminology: uphill diffusion", + "answer": "Uphill diffusion: The diffusion of atoms from a region of low concentration to a region of high concentration is called uphill diffusion, and the driving force for uphill diffusion is the chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释基本概念和术语，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即\"uphill diffusion\"的定义和驱动力的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求解释基本概念和术语\"uphill diffusion\"，属于最基础的定义简答。题目不涉及复杂的概念体系阐述或深入的分析，仅需要记忆和复述基本定义和驱动力的简单说明。在基础概念记忆的知识层次下，这是最直接和简单的回答要求。" + }, + { + "idx": 3126, + "question": "What is the shape memory mechanism of shape memory alloys?", + "answer": "After heating and quenching, shape memory alloy materials obtain thermoelastic martensite. The interface between this martensite and the parent phase has good coherency, so the martensite phase continuously shrinks and grows during heating and cooling. When the temperature exceeds the As point, the martensite undergoes plastic transformation into the parent phase. If pressure is applied in the martensitic state, the martensite lattice orientation changes, resulting in deformation. This deformed martensite undergoes reversible phase transformation upon heating, reverting to the parent phase state, causing the entire lattice to restore its original form, thereby eliminating the deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释形状记忆合金的形状记忆机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释形状记忆合金的形状记忆机制，涉及热弹性马氏体相变、相界面共格性、温度诱导的可逆相变等复杂机理，需要综合运用材料科学原理进行推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求全面分析形状记忆合金的复杂现象。需要综合运用材料科学、相变机理和热力学知识，详细解释马氏体相变、热弹性行为、晶格取向变化等多重机制之间的相互作用。解题步骤涉及多个知识点的串联和深度推理，要求考生不仅能描述现象，还要能解释各阶段转变的物理本质及其相互关系，属于该题型框架内最高难度的综合分析题。" + }, + { + "idx": 3127, + "question": "Explain the basic concept and terminology: symmetric tilt boundary", + "answer": "Symmetric tilt boundary: Formed by a series of edge dislocations with parallel Burgers vectors and the same sign arranged vertically. The two sides of the boundary are symmetric, and the misorientation between the two grains is very small. It is the simplest type of low-angle grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释对称倾斜晶界的基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对称倾斜晶界的基本概念和术语的定义，属于基础概念的记忆和理解层面。 | 难度: 在简答题题型中，该题目要求解释对称倾斜晶界的基本概念和术语，涉及定义、形成机制和特点的描述。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或多层次概念分析，属于概念解释和描述的中等难度。" + }, + { + "idx": 3128, + "question": "What is the shape memory mechanism of shape memory polymers?", + "answer": "The shape memory mechanism of polymers is the radiation crosslinking reaction that occurs when polymers are exposed to high-energy radiation. When the temperature exceeds the melting point and enters the high elastic state region, the crystals melt, allowing the polymer's shape to be arbitrarily altered by applying external force. If the temperature is then cooled below the crystalline melting point, the polymer chains become 'frozen' due to recrystallization, fixing the shape. Once the temperature rises above the melting point again (or above the glass transition temperature for polymers like polyvinyl chloride), the polymer returns to its original shape, demonstrating the shape memory effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释形状记忆聚合物的形状记忆机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释形状记忆聚合物的形状记忆机制，涉及辐射交联反应、高弹态区域、晶体熔融、外力作用、再结晶和形状恢复等多个复杂概念的综合分析和关联。需要深入理解聚合物在不同温度下的行为变化及其对形状记忆效应的影响，属于对机理的详细解释和推理分析。 | 难度: 在简答题题型中，该题目要求对形状记忆高分子的机理进行深度解释，涉及辐射交联反应、高弹态、结晶熔融、玻璃化转变等多个复杂概念的串联分析。虽然不需要达到全面分析复杂现象的等级5要求，但需要综合运用高分子物理知识进行机理层面的详细阐述，属于机理深度解释的等级4难度。" + }, + { + "idx": 3129, + "question": "Explain the basic concept and terminology: dendritic segregation", + "answer": "Dendritic segregation: During non-equilibrium solidification, the initially solidified solid solution contains more high-melting-point components, while the later solidified solid solution contains more low-melting-point components. This results in non-uniform chemical composition within the grain, known as intracrystalline segregation. Since solid solutions often grow in a dendritic manner, it is also called dendritic segregation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即dendritic segregation的定义和基本原理，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"dendritic segregation\"这一专业术语的基本概念，需要考生理解并描述非平衡凝固过程中的成分偏析现象，包括先凝固部分和后凝固部分的成分差异，以及由此产生的晶内偏析。虽然涉及专业术语和特定过程，但主要考察的是对基础概念的记忆和简单解释能力，不需要进行复杂的概念体系阐述或深入分析。因此，在同题型内属于中等难度（等级2）。" + }, + { + "idx": 3130, + "question": "Explain the basic concept and terminology: Twinning", + "answer": "Twinning: One of the important forms of cold plastic deformation, occurring as a uniform shear within the crystal, always along certain crystallographic planes and directions. After deformation, the deformed part and the undeformed part exhibit a mirror-symmetric orientation relationship, hence this type of plastic deformation is called twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即Twinning的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Twinning\"的基本概念和术语，需要考生不仅记住定义，还要能够描述其发生机制（均匀剪切）、特定条件（沿特定晶面和方向）以及变形后的特征（镜像对称关系）。这比单纯复述定义（等级1）要求更高，但不需要进行复杂概念体系的阐述（等级3）。题目考察的是对基础概念的理解和表达能力，属于该题型中的中等难度。" + }, + { + "idx": 3131, + "question": "Explain the basic concept and terminology: Modification treatment", + "answer": "Modification treatment: Before casting metal or alloy, adding certain solid-phase substances that can promote heterogeneous nucleation or hinder the growth of crystal nuclei into the molten metal to refine the grains of the casting is called modification treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释基本概念和术语，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即\"Modification treatment\"的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对\"Modification treatment\"进行基本定义简答，属于最基础的概念记忆层次。题目不涉及复杂概念体系或需要展开论述，仅需准确回忆并表述定义即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3132, + "question": "Explain the basic concept and terminology: superplasticity", + "answer": "Superplasticity: Under specific conditions, metallic materials can achieve exceptionally large elongation rates when stretched, sometimes even reaching 1000%. This property is called superplasticity. During superplastic deformation, the strain rate sensitivity index m is very high, with m≈0.5, whereas for ordinary metallic materials it is only 0.01~0.04.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，要求解释superplasticity的定义和基本特性，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释超塑性的基本概念和术语，包括定义、特性（如伸长率和应变率敏感性指数m）以及普通金属材料的对比。虽然需要记忆和理解相关概念，但并不涉及复杂的概念体系阐述或多层次的分析，因此属于中等难度。" + }, + { + "idx": 3133, + "question": "Explain the basic concept and terminology: Dynamic recovery", + "answer": "Dynamic recovery: During hot deformation of high stacking fault energy metallic materials, due to the narrow width of extended dislocations, they are prone to constriction and cross-slip. Therefore, high-temperature recovery occurs simultaneously during hot deformation, hence it is called dynamic recovery. It is the primary or sole softening mechanism for high stacking fault energy metallic materials during hot deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释动态回复的基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查动态恢复的基本概念和术语的定义，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要解释动态恢复的基本概念和术语，但不需要涉及复杂的体系阐述或多层次分析。题目要求对高堆垛层错能金属材料在热变形过程中的动态恢复现象进行描述，属于对单一概念的深入解释，符合等级2的标准。" + }, + { + "idx": 3135, + "question": "Compare the roles of twinning and slip in the plastic deformation process", + "answer": "The direct contribution of twinning to plastic deformation is not as significant as that of slip. However, since twinning alters the crystal orientation, it can enable slip systems originally in hard orientations to rotate into soft orientations and participate in slip. This is particularly important for hexagonal close-packed metals with fewer slip systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较孪生和滑移在塑性变形过程中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较孪生和滑移在塑性变形过程中的作用，不仅需要理解两种机制的基本概念，还需要分析它们之间的相互作用以及对晶体取向的影响。这涉及到对塑性变形机理的深入理解和综合分析，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对两种塑性变形机制（孪生和滑移）进行机理层面的比较分析，需要深入理解晶体取向变化对滑移系统激活的影响机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念解释层面，属于需要机理深度解释的等级4难度。题目特别强调了对六方密堆积金属这种特殊情况的机理解释，体现了对知识点掌握深度的要求。" + }, + { + "idx": 3136, + "question": "What is secondary recrystallization (abnormal growth)?", + "answer": "After recrystallization is completed, continued heating or holding may lead to discontinuous grain growth, where the growth of most grains is inhibited, while a few grains grow rapidly, which is called abnormal growth, also known as secondary recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“secondary recrystallization (abnormal growth)”进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶（异常生长）这一基本概念的定义和解释，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释\"二次再结晶（异常生长）\"的定义和过程，但不需要涉及复杂的概念体系或深入的分析。题目主要考察对基础概念的记忆和理解，属于中等难度的简答题。" + }, + { + "idx": 3137, + "question": "Briefly explain the differences between twinning and slip in the plastic deformation process", + "answer": "Twinning causes a uniform shear in a portion of the crystal, while slip is concentrated on the slip plane; twinning changes the orientation of a portion of the crystal, whereas slip does not alter the crystal orientation; the twinning elements are usually different from the slip systems; the critical shear stress for twinning is much higher than that for slip, the stress-strain curve for twinning is serrated, while that for slip is smooth; the deformation rate of twinning is far higher than that of slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释孪生和滑移在塑性变形过程中的差异，答案通过文字解释和论述的方式详细说明了两种变形机制的不同点，符合简答题的特征。 | 知识层次: 题目要求解释孪生和滑移在塑性变形过程中的差异，涉及多个方面的比较和分析，需要理解两种变形机制的基本原理并能够进行概念关联和综合分析。虽然不涉及复杂的计算或深度推理，但需要对两种机制有较深入的理解和比较能力。 | 难度: 在简答题题型内，该题目要求多角度分析论述，涉及多个关键差异点的比较（如变形机制、晶体取向变化、临界剪切应力等），需要综合运用材料科学知识进行详细解释，属于较高难度的综合分析类题目。" + }, + { + "idx": 3138, + "question": "Determine whether the dislocation reaction $\\frac{1}{2}[111]\\rightarrow\\frac{1}{8}[110]+\\frac{1}{4}[112]+\\frac{1}{8}[110]=0.$ 110] can proceed, and why?", + "answer": "$$ \\Sigma b_{\\mathbb{H}}=\\Sigma b_{\\mathbb{E}}=\\frac{1}{2}[111]$$Thus, this dislocation reaction satisfies the geometric condition$$ x\\Sigma b_{j j}^{2}=\\frac{3}{4}>\\Sigma b_{j j}^{2}=\\frac{1+1}{64}+\\frac{1+1+4}{16}+\\frac{1+1}{64}=\\frac{7}{16} $$Therefore, it also satisfies the energy condition, so this dislocation reaction can proceed spontaneously.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算验证位错反应是否满足几何条件和能量条件，答案中包含了具体的矢量计算和能量比较，属于典型的计算题类型。 | 知识层次: 题目需要进行多步计算（包括矢量运算和能量条件验证），并需要理解位错反应的几何条件和能量条件，涉及概念关联和综合分析。虽然不涉及复杂的机理分析或创新设计，但已超出简单应用的范围。 | 难度: 在计算题中属于综合性计算问题，需要理解位错反应的基本原理，进行矢量计算和能量条件验证。虽然计算步骤较多，但每个步骤相对明确，属于中等应用层次的多步计算和综合分析。" + }, + { + "idx": 3139, + "question": "It is known that the stacking fault energy of a certain stainless steel is very low, γ=0.013 J/m². It is cold-pressed with a reduction of 8%, followed by recrystallization annealing. Briefly describe its recrystallization nucleation mechanism.", + "answer": "At a reduction of 8%, the nucleation mechanism is the bow-out nucleation mechanism. Due to the small deformation amount and non-uniform deformation, the dislocation density between adjacent grains varies significantly. A small segment of the remaining original grain boundary will suddenly bow out towards the side with higher dislocation density. The swept small region releases all stored energy, and this area can become the recrystallization nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述再结晶成核机制，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释不锈钢在特定条件下的再结晶成核机制，涉及变形量、位错密度差异、晶界弓出等复杂概念的综合运用和机理解释，需要深入理解和分析材料变形与再结晶过程的相互作用。 | 难度: 在简答题中属于机理深度解释难度，需要理解低堆垛层错能不锈钢的形变特性，并准确描述特定变形量(8%)下的再结晶成核机制。题目要求综合运用位错理论、变形不均匀性和晶界迁移机制等知识，解释弓出成核机制的具体过程，属于对材料变形与再结晶机理的深入分析。" + }, + { + "idx": 3140, + "question": "What are the conditions for the occurrence of secondary recrystallization (abnormal growth)?", + "answer": "The conditions for its occurrence are the presence of recrystallization texture, second-phase particles, or surface thermal grooves.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述二次再结晶（异常生长）发生的条件，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对二次再结晶（异常生长）发生条件的理解，需要综合多个因素（再结晶织构、第二相粒子、表面热沟槽）进行分析，属于中等应用层次。虽然不涉及复杂计算，但需要对相关概念进行关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解并综合说明二次再结晶发生的条件，涉及多个概念（再结晶织构、第二相粒子、表面热沟）的关联，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 3142, + "question": "γ-Fe has a lattice constant α=0.3633nm slightly above 910 ℃, find the atomic radius of γ-Fe", + "answer": "The atomic radius of γ-Fe r=√2/4×a=√2/4×0.3633=0.1284nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用晶格常数计算原子半径）来得出具体数值结果，答案是一个具体的计算结果（0.1284nm），符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要套用已知的公式（原子半径与晶格常数的关系）进行一步计算即可得出结果，不需要多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（原子半径与晶格常数的关系公式）进行一步计算，无需任何变形或组合计算步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 3143, + "question": "For α-Fe slightly below 910°C, the lattice constant α=0.2892nm, find the atomic radius of α-Fe", + "answer": "The atomic radius of α-Fe r=√3/4×a=√3/4×0.2892=0.1252nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（√3/4×a）来求解α-Fe的原子半径，答案是一个具体的数值结果（0.1252nm），符合计算题的特征。 | 知识层次: 题目要求应用基本公式（原子半径与晶格常数的关系）进行简单计算，无需多步推理或综合分析，属于直接套用公式的简单应用。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（原子半径与晶格常数的关系公式）进行一步计算，无需任何变形或组合运算。解题步骤仅包含代入数值和开方运算，属于基础晶体学知识的直接应用。" + }, + { + "idx": 3144, + "question": "It is known that the stacking fault energy of a certain stainless steel is very low, γ=0.013 J/m². After cold pressing deformation with reductions of 8% and 60%, recrystallization annealing is performed. Explain the difference in grain size after recrystallization annealing between the two cases. Why?", + "answer": "After recrystallization annealing, with a reduction of 8%, the deformation is near the critical deformation level. The small deformation amount results in low stored energy and a small driving force for recrystallization. Although recrystallization can occur, the nucleation rate is low, leading to very coarse grains. With a reduction of 60%, the stored energy is high, the driving force for recrystallization is large, and the nucleation rate is high, resulting in fine grains after recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种情况下再结晶退火后晶粒尺寸的差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的多个概念（如堆垛层错能、冷变形、再结晶退火等），分析不同变形量对再结晶晶粒尺寸的影响机制，涉及存储能、形核率等深层次原理的解释和推理过程。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解冷变形和再结晶退火的基本概念，还需要深入分析不同变形量对储存能、再结晶驱动力和形核率的影响，进而解释晶粒尺寸差异的机理。这需要综合运用材料科学中的变形、储存能、再结晶动力学等知识，并进行逻辑推理和机理解释，属于该题型中较高难度的题目。" + }, + { + "idx": 3145, + "question": "The volume change rate during the γ-Fe→α-Fe transformation (given the lattice constant of γ-Fe α=0.3633nm, and the lattice constant of α-Fe α=0.2892nm)", + "answer": "The volume change rate ΔV=(Vα-Vγ)/Vγ=(0.2892³×1/2-0.3633³×1/4)/(0.3633³×1/4)≈0.886", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶格常数计算γ-Fe→α-Fe相变过程中的体积变化率，需要应用具体的数值计算和公式推导，答案以数值结果呈现。 | 知识层次: 题目涉及多步计算和概念关联，需要理解γ-Fe和α-Fe的晶体结构（面心立方和体心立方），并正确应用体积计算公式。虽然计算本身不复杂，但需要对晶体结构和相变有基本理解，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解γ-Fe和α-Fe的晶体结构差异，正确应用晶格常数计算体积变化，并进行多步数值计算。虽然不涉及复杂变量，但要求对材料相变和晶体学有较好的掌握。" + }, + { + "idx": 3146, + "question": "In has a tetragonal structure with lattice constants a=0.3252 nm, c=0.4946 nm, atomic radius r=0.1625 nm, and number of atoms per unit cell n=2. Calculate the packing density.", + "answer": "The packing density K=(n×v)/V=(2×(4/3)π(0.1625)³)/(0.3252²×0.4946)≈0.687.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将已知参数代入公式进行数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的球体体积公式和晶胞体积公式，进行简单的数值代入和计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 3148, + "question": "The lattice constant of a copper crystal is $a=0.362\\mathrm{nm},$ the density is $\\rho=8.98~\\mathrm{g/cm}^{3},$ and the relative atomic mass is 63.55. Determine the crystal structure of copper.", + "answer": "From the physical meaning of density $\\rho=\\frac{6.023\\times10^{23}}{(0.362\\times10^{-7})^{3}}=8.98(g/\\mathrm{cm}^{3})$ n. Solving gives $n=3.997{\\approx}4.$ A cubic unit cell with 4 atoms corresponds to a face-centered cubic structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定铜的晶体结构，解答过程中涉及到了密度的计算和单位晶胞中原子的数量，最终通过计算结果推断出晶体结构。 | 知识层次: 题目需要多步计算（密度公式应用、单位换算、原子数计算）和概念关联（晶格常数与晶体结构的关系），涉及对立方晶胞中原子数的综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解晶格常数、密度和相对原子质量之间的关系，并进行多步计算。虽然计算步骤较为明确，但需要将多个物理概念关联起来，综合分析才能得出正确的晶体结构。这在该题型内属于中等偏上的难度。" + }, + { + "idx": 3149, + "question": "Given the density of amorphous polyethylene ρa=0.854 g/cm³, and the density of typical commercial low-density polyethylene ρ=0.920 g/cm³, calculate the volume fraction of the crystalline region φc", + "answer": "The volume fraction of the crystalline region φc = (ρ - ρa) / (ρc - ρa) = (0.92 - 0.854) / (1.01 - 0.854) ≈ 42.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及密度和体积分数的直接套用，无需多步计算或复杂分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要套用一个已知公式（φc = (ρ - ρa) / (ρc - ρa)），代入给定的数值进行计算即可，无需额外的推导或组合多个公式。解题步骤简单直接，属于该题型中最基础的难度级别。" + }, + { + "idx": 3150, + "question": "Using analytical geometry to determine the angle between two crystal planes $h_{1}k_{1}l_{1}$ and $h_{2}k_{2}l_{2}$ in a cubic crystal", + "answer": "Let the two crystal planes in the cubic system be $h_{1}k_{1}l_{1}$ and $h_{2}k_{2}l_{2}$, and the angle between them be $\\phi$, then $$ \\cos\\phi={\\frac{h_{1}h_{2}+k_{1}k_{2}+l_{1}l_{2}}{\\sqrt{h_{1}^{2}+k_{1}^{2}+l_{1}^{2}}\\cdot\\sqrt{h_{2}^{2}+k_{2}^{2}+l_{2}^{2}}}} $$ Therefore, $$ \\phi=\\operatorname{arccos}(\\cos\\phi) $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶体中两个晶面之间的夹角，答案给出了具体的计算公式和步骤，属于需要数值计算和公式应用的类型。 | 知识层次: 题目主要涉及立方晶系中两个晶面间夹角的计算，直接应用给定的公式进行计算。虽然需要理解晶面指数的含义和几何关系，但整体上是一个基本的公式应用和简单计算过程，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用解析几何方法计算立方晶体中两个晶面之间的夹角，直接套用给定的余弦公式即可完成计算。虽然涉及反余弦运算，但整个过程仅需应用单一标准公式，无需多步骤推导或组合多个公式，因此属于等级2难度。" + }, + { + "idx": 3151, + "question": "In has a tetragonal structure, with a relative atomic mass Ar=114.82, lattice constants a=0.3252 nm, c=0.4946 nm, atomic radius r=0.1625 nm, density ρ=7.286 g/cm³. Determine the number of atoms per unit cell of In.", + "answer": "From the density expression ρ=(n×114.82)/((0.3252×10⁻⁷)²×0.4946×10⁻⁷×6.023×10²³)≈7.286, the number of atoms per unit cell is obtained as n≈1.999, n=2, which should be a body-centered tetragonal structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定每个晶胞中的原子数，答案涉及具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，通过给定的密度表达式和已知参数直接计算单位晶胞中的原子数，无需多步计算或复杂分析。 | 难度: 在计算题中属于简单公式应用计算难度，仅需套用密度公式进行数值计算，解题步骤较为直接，不涉及多个公式的组合或复杂推导。" + }, + { + "idx": 3152, + "question": "Using analytical geometry to determine the angle between two crystallographic directions [$u_{1}v_{1}w_{1}$] and [$u_{2}v_{2}w_{2}$] in a cubic crystal", + "answer": "Let the two crystallographic directions in the cubic system be [$u_{1}v_{1}w_{1}$] and [$u_{2}v_{2}w_{2}$], and the angle between them be θ, then $$ \\\\cos\\\\theta={\\\\frac{\\\\left[u_{1}v_{1}w_{1}\\\\right]\\\\cdot\\\\left[u_{2}v_{2}w_{2}\\\\right]}{|\\\\left[u_{1}v_{1}w_{1}\\\\right]|\\\\cdot|\\\\left[u_{2}v_{2}w_{2}\\\\right]|}}={\\\\frac{u_{1}u_{2}+v_{1}v_{2}+w_{1}w_{2}}{{\\\\sqrt{u_{1}^{2}+v_{1}^{2}+w_{1}^{2}}}\\\\cdot{\\\\sqrt{u_{2}^{2}+v_{2}^{2}+w_{2}^{2}}}}} $$ Therefore $$ \\\\theta=\\\\operatorname{arccos}(\\\\cos\\\\theta) $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶体中两个晶向之间的夹角，答案中给出了具体的计算公式和步骤，需要数值计算和公式应用。 | 知识层次: 题目主要涉及基本的向量点积公式在立方晶体中的应用，属于直接套用公式进行计算的情况，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用解析几何方法计算立方晶体中两个晶向之间的夹角，主要涉及向量点积公式和模的计算。虽然需要理解晶向指数的概念，但计算过程仅需套用单一公式（向量点积公式），且不需要额外的推导或复杂变换。相比等级1的直接计算题，本题需要理解晶向指数的含义；相比等级3的多公式组合计算题，本题的计算步骤更为简单直接。" + }, + { + "idx": 3153, + "question": "In stable ZrO2 material, cations form an fcc structure, and anions occupy tetrahedral interstitial sites. If 20 mol% CaO is added, calculate how many anions are needed for 100 cations?", + "answer": "Since the amount of CaO added to ZrO2 is 20 mol%, the total charge number for 100 cations is 20×2 + 80×4 = 360. To maintain electrical neutrality, the required number of O2− anions is 360 ÷ 2 = 180.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算需要的阴离子数量），并应用了电荷平衡的原理。答案是通过具体的数学运算得出的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括理解fcc结构、电荷平衡计算以及掺杂比例的应用，需要综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解电荷平衡的概念，进行多步计算（包括摩尔百分比转换、电荷总数计算和电荷平衡求解），并综合分析掺杂对晶体结构的影响。虽然不涉及复杂多变量，但步骤和概念关联性较强。" + }, + { + "idx": 3154, + "question": "In stable ZrO2 material, cations form an fcc structure, and anions occupy tetrahedral interstitial sites. If 20 mol% CaO is added, calculate the percentage of occupied tetrahedral interstitial sites.", + "answer": "Zr4+ and Ca2+ cations occupy the face-centered cubic lattice sites. 100 cations can form 25 unit cells, with a total of 25×8=200 tetrahedral interstitial sites. Therefore, the percentage of occupied tetrahedral interstitial sites is 180÷200=90%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算占据四面体间隙的百分比），并给出了具体的计算步骤和公式应用（如单位晶胞数量、四面体间隙总数等）。答案也是一个具体的数值结果（90%），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位细胞数量、间隙位置数量以及百分比计算，同时需要理解阳离子和阴离子的位置关系以及掺杂对结构的影响。这涉及到概念关联和综合分析，超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要理解fcc结构、间隙位置、掺杂比例等多个概念，并进行多步计算和综合分析。虽然计算步骤明确，但需要将多个知识点关联起来才能正确解答。" + }, + { + "idx": 3155, + "question": "Determine the crystallographic direction in the diamond structure defined by the points (0,0,0) and $(\\\\frac{3}{4},\\\\frac{3}{4},\\\\frac{1}{4})$, and find the crystallographic plane perpendicular to this direction.", + "answer": "Subtract the coordinates of the two points, then reduce them to a set of coprime integers. The direction indices are [331]. Since it is a cubic system, the crystallographic plane with the same indices is perpendicular to the direction, i.e., (331) is perpendicular to [331].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定晶体学方向并找到与之垂直的晶面，需要通过文字解释和论述来解答，而不是简单的选择、判断或数值计算。 | 知识层次: 题目需要多步计算（坐标相减、约简为互质整数）和概念关联（立方晶系中方向与垂直晶面的关系），涉及对晶体学方向指数和晶面指数的综合分析能力。 | 难度: 在简答题中属于中等难度，需要理解晶体学方向指数的计算方法，并能够正确进行坐标相减和约简操作。此外，还需要掌握立方晶系中方向指数与晶面指数的垂直关系。虽然涉及多步计算和概念关联，但步骤相对明确，不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 3156, + "question": "It is known that polyethylene belongs to the body-centered orthorhombic structure, with lattice constants a=0.740nm, b=0.493nm, c=0.253nm, and two molecular chains passing through a unit cell. Calculate the density ρc of fully crystalline polyethylene.", + "answer": "Polyethylene (C2H4) is produced through addition polymerization, with its repeating unit being CH2-CH2. Considering one repeating unit as a lattice point, it can be determined that each unit cell contains two repeating units. Therefore, the density ρc of fully crystalline polyethylene can be calculated as ρc = 2(12×2 + 1×4) / (6.023×10^23) / (0.740×0.493×0.253)×10^-21 ≈ 1.01 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解完全结晶聚乙烯的密度，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括分子量的计算、单位晶胞体积的计算以及密度的计算，同时需要理解晶格常数和单位晶胞的概念，并能够将这些概念关联起来进行综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的理解和应用能力。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构、单位晶胞的概念，掌握密度的计算公式，并进行多步数值计算。虽然计算过程较为直接，但需要对材料科学中的晶体学知识有一定掌握，属于中等应用层次的计算题。" + }, + { + "idx": 3157, + "question": "The density of $\\\\mathrm{CaF}_{2}$ is $\\\\rho=3.18~\\\\mathrm{g/cm}^{3}$, the relative atomic mass of $\\\\mathrm{Ca}$ is $A_{\\\\mathrm{r}}=40.08$, and the relative atomic mass of $\\\\mathrm{F}$ is $A_{\\\\mathrm{r}}=19.00$. Find the lattice constant $a$.", + "answer": "From the structure of $\\\\mathrm{CaF}_{2}$, it is known that the unit cell contains 4 $\\\\mathrm{Ca}^{2+}$ ions and 8 $\\\\mathrm{F^{-}}$ ions. Therefore, the relationship between its density and the lattice constant is as follows: $$ x\\\\rho=\\\\frac{4\\\\times\\\\frac{40.08+19\\\\times2}{6.023\\\\times10^{23}}}{a^{3}}\\\\approx3.18 $$ Solving the above equation gives $a=0.546(\\\\mathrm{nm})$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶格常数a，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括理解晶体结构、计算单位晶胞中的离子数量、应用密度公式，并进行数值求解。这需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构、密度与晶格常数的关系，并进行多步计算。题目涉及单位晶胞中离子数量的确定、摩尔质量的计算、阿伏伽德罗常数的应用以及最终解方程的步骤，综合了多个概念和计算过程，但未达到复杂多变量计算的级别。" + }, + { + "idx": 3158, + "question": "Given the density of amorphous polyethylene ρa=0.854 g/cm³, the density of typical commercial low-density polyethylene ρ=0.920 g/cm³, and the density of fully crystalline polyethylene ρc=1.01 g/cm³, calculate the mass fraction of the crystalline region wc", + "answer": "The mass fraction of the crystalline region wc = ρc(ρ - ρa) / ρ(ρc - ρa) = 1.01×(0.92 - 0.854) / 0.92×(1.01 - 0.854) ≈ 46.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的密度数据和公式进行数值计算，最终得出结晶区域的质量分数。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用密度与结晶度的关系公式进行多步计算，涉及不同密度值的综合运用和概念关联，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式并进行多步计算，涉及多个密度值的关联和综合分析，但计算过程相对直接，没有过于复杂的变量或步骤。" + }, + { + "idx": 3159, + "question": "What type of alloy phase does CuZn belong to, and what are its structural characteristics?", + "answer": "CuZn is an electron compound, c13=3.12, with a body-centered cubic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释CuZn合金的相类型和结构特征，需要用文字进行描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对CuZn合金相类型和结构特征的基本概念记忆，属于定义和分类的记忆性知识。 | 难度: 在简答题题型中，该题目要求解释CuZn合金的相类型及其结构特征，属于概念解释和描述的难度等级。虽然需要记忆具体的电子化合物类型（c13=3.12）和晶体结构（体心立方），但不需要进行复杂的体系阐述或多步骤推理，因此属于中等难度。" + }, + { + "idx": 3160, + "question": "What type does the alloy phase Fe3C belong to, and what are its structural characteristics?", + "answer": "Fe3C is a complex lattice interstitial compound with an orthorhombic crystal system. Its unit cell contains 12 iron atoms and 4 carbon atoms. The iron atoms are arranged in a close-packed manner, forming octahedrons, with carbon atoms located in the octahedral interstitial sites. The corner atoms of the octahedrons are shared by two adjacent octahedrons, and there is a certain orientation between the octahedrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C合金相的类型和结构特征，答案提供了详细的文字描述和论述，没有涉及选择、判断或计算。 | 知识层次: 题目主要考查对Fe3C合金相的类型和结构特征的基本概念记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目要求考生不仅需要记忆Fe3C的基本分类（复杂间隙化合物），还需要详细描述其晶体结构特征（正交晶系、晶胞组成、原子排列方式等）。这涉及到对晶体结构知识的系统掌握和准确表述，属于复杂概念体系阐述的范畴，因此在简答题题型中属于较高难度等级。" + }, + { + "idx": 3161, + "question": "What type of alloy phase is VC, and what are its structural characteristics?", + "answer": "VC is an interstitial phase, where V occupies the lattice points of a face-centered cubic lattice, and C occupies all the octahedral interstitial sites. It belongs to the face-centered cubic lattice and has a NaCl-type structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释VC合金相的类型和结构特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对合金相类型和结构特征的基本概念记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目要求解释VC合金相的类型及其结构特征，属于概念解释和描述的难度等级。虽然需要记忆和描述具体的晶体结构（面心立方和NaCl型结构），但不需要进行复杂的体系阐述或多层次的概念关联。因此，在简答题的基础概念记忆层次中属于中等难度。" + }, + { + "idx": 3162, + "question": "What type of alloy phase is ZrFe2, and what are its structural characteristics?", + "answer": "ZrFe2 is a Laves phase among the topologically close-packed phases, with a complex cubic structure. The smaller iron atoms form small tetrahedrons, and the vertices of these tetrahedrons are interconnected to form a network. The larger Zr atoms are located in the gaps between the small tetrahedrons formed by Fe atoms and themselves form a diamond structure. This structure only contains tetrahedral gaps, so its packing density is higher than that of the face-centered cubic structure formed by equal-sized steel balls.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释ZrFe2合金相的类型和结构特征，答案提供了详细的文字描述和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目不仅需要识别ZrFe2为Laves相（基础概念记忆），还需要描述其结构特征（小四面体网络、Zr原子位置、堆积密度比较等），涉及多个概念的关联和综合分析。虽然不涉及复杂计算或深度机理分析，但已超出单纯记忆层面，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对ZrFe2合金相的类型和结构特征进行多角度分析论述。不仅需要识别Laves相这一特定相类型，还需详细描述其复杂的立方结构、原子排列方式（小四面体网络和Zr原子的间隙位置）、以及由此产生的高堆积密度特性。这涉及到对拓扑密堆相结构原理的深入理解，以及将抽象的结构概念转化为具体的空间描述能力，属于典型的多角度分析论述要求。" + }, + { + "idx": 3163, + "question": "Calculate the number of atoms N in 1 cm³ of copper, given that the density of copper is 8.9 g/cm³, the relative atomic mass is 63.5, and Avogadro's number is 6.02×10²³.", + "answer": "N = (6.02×10²³ × 8.9) / 63.5 ≈ 0.84×10²³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及密度、相对原子质量和阿伏伽德罗常数的计算，答案也是具体的数值结果。 | 知识层次: 题目需要应用基本的密度、相对原子质量和阿伏伽德罗常数公式进行计算，属于直接套用公式的简单计算题，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目只需要套用密度、相对原子质量和阿伏伽德罗常数的基本公式进行计算，解题步骤清晰直接，无需多个公式组合或复杂转换。虽然涉及单位换算和指数运算，但在该题型框架内仍属于基础级别的计算要求。" + }, + { + "idx": 3164, + "question": "Calculate the number of vacancies n in 1 cm³ of copper at 1000°C, given the average vacancy concentration C≈6.27×10⁻⁵ and the number of atoms N≈0.84×10²³.", + "answer": "n = N × C = 0.84×10²³ × 6.27×10⁻⁵ ≈ 5.27×10¹⁸", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过计算得出的具体数值。 | 知识层次: 题目涉及基本的公式应用和简单计算，直接套用给定的数值进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式（n = N × C）并进行简单数值计算，无需任何额外的步骤或复杂的公式组合。" + }, + { + "idx": 3165, + "question": "The vacancy formation energy of copper is 1.7×10⁻¹⁹ J. Calculate the average vacancy concentration C at 1000°C, given the Boltzmann constant K=1.38×10⁻²³ J/K.", + "answer": "The average vacancy concentration C = e^(-Ev/KT) = exp{- (1.7×10⁻¹⁹) / (1.38×10⁻²³ × 1273)} ≈ 6.27×10⁻⁵", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式（C = e^(-Ev/KT)）和参数（Ev, K, T）来求解平均空位浓度C。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及Boltzmann公式的直接套用和数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（玻尔兹曼分布公式）进行数值计算，无需多步骤推导或复杂公式组合。题目提供了所有必要参数，计算过程仅涉及基本指数运算，属于该题型内最基础的直接应用类题目。" + }, + { + "idx": 3166, + "question": "To dissolve MgF2 into LiF, what type of vacancies should be introduced into LiF?", + "answer": "Dissolving MgF2 into LiF, i.e., replacing Li+ with Mg2+, generates cation vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释溶解MgF2到LiF中时需要引入的空位类型，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解溶解过程中离子替换的机制，并分析由此产生的空位类型。这涉及到对晶体缺陷和离子替换的基本原理的应用，以及将不同概念（溶解、离子替换、空位形成）关联起来进行分析。虽然不需要复杂的计算或深度推理，但需要一定的概念理解和综合分析能力。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及离子替换和空位形成的概念，但解题步骤相对直接，主要是理解Mg2+替换Li+后电荷平衡的需要导致阳离子空位的形成。不需要多角度分析或深度关联其他复杂概念，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3168, + "question": "Given that Cr has a body-centered cubic structure, with a lattice constant a=0.2885 nm, density ρ=7.10 g/cm³, and relative atomic mass A=51.996, calculate the number of vacancies in Cr per 10⁶ lattice points.", + "answer": "The fraction of vacancies is x. From the definition of density, xρ=(2×(51.996)/(6.023×10²³)×(1−x))/(2.885³×10⁻²⁴)=7.10. Solving gives x=1−(2.885³×10⁻²⁴×7.10×6.023×10²³)/(2×51.996)≈0.0126. Therefore, the number of vacancies per 10⁶ lattice points is 10⁶×0.0126=12,600 (vacancies).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Cr中每10⁶个晶格点的空位数，答案涉及具体的数学计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换、代数求解等，并需要理解体心立方结构的原子排列和空位概念。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶体结构知识、相对原子质量概念，并进行多步计算和代数求解。虽然涉及多个概念和步骤，但计算过程相对直接，没有引入复杂变量或高级数学工具，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 3169, + "question": "The temperature increases from $T_{1}$ to $T_{2}$. The relative change in lattice parameter measured by X-ray diffraction method is $\\frac{\\Delta a}{a}=($4\\times10^{6}$）%. For a cube with side length L, the measured value is =0.004%. Find the vacancy concentration at temperature T2.", + "answer": "$$ xC_{v}=\\frac{\\Delta N}{N}=3\\Bigl[\\frac{\\Delta L}{L}-\\frac{\\Delta a}{a}\\Bigr]=3(0.004\\%-0.0004\\%)=1.08\\times10^{-4} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括相对变化量的计算和公式应用，同时需要理解晶格参数变化与空位浓度之间的关系，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解相对变化的概念，进行多步计算（包括百分比转换和差值计算），并正确应用公式求解空位浓度。虽然涉及多个步骤，但变量和计算过程相对明确，没有过于复杂的推导或高难度数学处理。" + }, + { + "idx": 3170, + "question": "Two edge dislocations with opposite signs on the same slip plane have Burgers vectors of b. If they approach infinitely close, what is the total energy?", + "answer": "When two edge dislocations with opposite signs approach infinitely close, they annihilate each other, and the total energy becomes zero.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释两个位错接近时的能量变化情况，答案提供了文字解释和论述，没有涉及计算或选择选项。 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是关于位错湮灭现象的基础知识 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求记忆并复述两个相反符号刃位错相互靠近时的能量变化结果，不涉及概念解释或复杂体系阐述。解题过程仅需调用基础概念记忆性知识，无需分析推理或多步骤计算，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 3171, + "question": "Two positive edge dislocations on the same slip plane, each with a Burgers vector b, when they approach infinitely close, what is the total energy?", + "answer": "When two positive edge dislocations approach infinitely close, it is equivalent to the energy of a single large dislocation with a Burgers vector 2b, W=α⋅G(2b)²=4αGb²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算两个正刃位错无限接近时的总能量，需要通过公式应用和数值计算得出结果，答案给出了具体的计算过程和最终数值结果。 | 知识层次: 题目需要理解位错的基本概念（Burgers vector和能量关系），并应用公式进行多步计算（从单个位错能量推导到两个位错合并后的能量）。虽然计算过程不复杂，但需要将两个位错的接近等效为一个大的位错，并进行能量计算，这涉及到概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解位错能量公式的应用，并能将两个位错的接近等效为一个位错的情况进行计算。虽然计算步骤不算特别复杂，但需要对位错能量概念有较深的理解，并能正确应用公式进行综合分析。" + }, + { + "idx": 3172, + "question": "Two positive edge dislocations on the same slip plane, with Burgers vector b and separated by a distance L, when L is much larger than the magnitude of the Burgers vector, what is the total energy?", + "answer": "When the two edge dislocations are far apart, the total energy equals the sum of their individual energies, regardless of whether they are like or unlike dislocations, given by W=W1+W2=2αGb2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个刃位错在特定条件下的总能量，答案提供了理论解释和公式应用，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对位错能量基本公式的直接应用，仅需理解位错能量公式并简单相加，无需多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述。题目要求直接套用基本公式（位错能量公式）进行计算，且解题步骤简单（仅需将两个位错的能量相加）。虽然需要理解位错能量的概念，但不需要深入分析或复杂推导，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 3173, + "question": "The density of $\\\\mathrm{CaF}_{2}$ is $\\\\rho=3.18~\\\\mathrm{g/cm}^{3}$, the lattice constant is $a=0.5463\\\\mathrm{nm}$, and the relative atomic masses of Ca and F are 40.08 and 19.00, respectively. Calculate the number of Schottky vacancies in the unit cell of CaF2.", + "answer": "To maintain electrical neutrality, in the $\\\\mathrm{CaF}_{2}$ ionic crystal, for every Schottky defect formed, one $\\\\mathrm{Ca}^{2+}$ and two $\\\\mathbf{F}^{-}$ must be lost simultaneously. Let the number of Schottky defects in the unit cell be $x$, then $$ x\\\\rho=\\\\frac{\\\\left(4-x\\\\right)\\\\left(40.08+19\\\\times2\\\\right)/6.023\\\\times10^{23}}{5.463^{3}\\\\times10^{-24}}\\\\approx3.18\\\\left({\\\\mathrm{g}}/{\\\\mathrm{cm}^{3}}\\\\right) $$ Therefore, $$ x=4-\\\\frac{6.023\\\\times10^{23}\\\\times3.18\\\\times5.463^{3}\\\\times10^{-24}}{40.08+19.00\\\\times2}\\\\approx6.10\\\\times10^{-4}\\\\uparrow $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了密度、晶格常数、相对原子质量等数据的计算，最终得出Schottky空位的数量。答案展示了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位换算、以及缺陷化学中的电荷平衡考虑。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要理解Schottky缺陷的概念，进行多步计算，包括密度、晶格常数和相对原子质量的综合应用。虽然计算过程较为复杂，但题目提供了所有必要的数据和明确的解题路径，因此属于中等偏上的难度。" + }, + { + "idx": 3174, + "question": "Given that the dislocation line Φt of a newly formed Frank partial dislocation lies on the (111) plane, with b = a/3 [111] perpendicular to the (111) plane, explain why this dislocation is a sessile dislocation.", + "answer": "The plane determined by b and t is certainly not the close-packed plane of the face-centered cubic structure, hence this dislocation cannot glide and is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来说明为什么给定的位错是固定位错，而不是从选项中选择、判断对错或进行数值计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释为什么Frank部分位错是固着位错，需要综合运用位错理论、晶体结构知识以及位错运动机制的分析。涉及到位错线方向、柏氏矢量与滑移面的关系，以及对面心立方结构密排面的理解，属于综合分析层次。 | 难度: 在简答题中属于机理深度解释难度等级。该题目要求考生不仅理解位错的基本概念，还需要综合运用面心立方结构、位错运动和柏氏矢量的知识，解释为什么特定的Frank部分位错是不可滑移的。需要考生具备较强的推理分析能力和对晶体缺陷机理的深入理解，但尚未达到全面分析复杂现象的最高难度。" + }, + { + "idx": 3175, + "question": "Estimate the strain energy of a 1cm long edge dislocation (r0=1nm, R=1cm, μ=5×10^10Pa, b=0.25nm, ν=1/3)", + "answer": "The strain energy per unit length of an edge dislocation is WE=(W/L)E=μb^2/[4π(1−ν)]ln(R/r0). The strain energy of a 1cm edge dislocation is WI={[5×10^10×(0.25×10^-9)^2]/[4×3.14×(1−1/3)]}×10^-2×ln[(1×10^-2)/(1×10^-9)]=6×10^-11J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案也是通过具体计算得出的数值结果 | 知识层次: 题目需要进行多步计算，包括公式应用、单位转换和对数运算，同时需要理解应变能的概念和边缘位错的基本原理。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用给定的公式进行多步计算，包括对数运算和单位转换，同时需要理解应变能的概念及其与材料参数的关系。虽然计算步骤较多，但公式直接给出，减少了推导的复杂性。" + }, + { + "idx": 3176, + "question": "Indicate the radius of the region that accounts for half of the energy (r0=1nm, R=1cm)", + "answer": "Let the radius of the region accounting for half of the dislocation energy be r, Wr/W1=ln(r/r0)/ln[(1×10^-2)/r0]=ln[r/(1×10^-9)]/ln[(1×10^-2)/(1×10^-9)]=1/2. Solving gives r=10^-5.5=10^-6×10^0.5=3.16×10^-6m=3.16μm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定半径的值，解答过程中涉及对数运算和单位转换，最终给出具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及对数运算和单位转换，需要理解位错能量的分布概念并应用相关公式进行求解。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式要复杂一些。 | 难度: 在计算题中属于综合性计算问题，需要理解能量分布的概念，应用对数公式进行多步计算，并正确转换单位。虽然计算步骤较多，但每一步都有明确的逻辑关系，属于中等偏上的难度。" + }, + { + "idx": 3177, + "question": "The lattice constant of α-Fe is $a=0.28664\\mathrm{nm}.$ When two adjacent grains form a symmetric tilt boundary with a tilt angle of 1°, calculate the spacing $D$ of the edge dislocations.", + "answer": "The Burgers vector of the unit dislocation in a body-centered cubic structure is $b=\\frac{a}{2}\\textcircled{111},$ so $b={\\frac{\\sqrt{3}}{2}}a.$ Using the formula $$ D={\\frac{b}{\\theta}}={\\frac{\\sqrt{3}}{2}}\\times0.28664/0.0175\\approx14.183{\\mathrm{~nm}} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解间距D，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要理解对称倾斜晶界的几何关系，应用Burgers矢量的计算公式，并进行多步数值计算。虽然不涉及复杂的机理分析或创新设计，但需要将多个概念关联起来并进行综合计算，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解体心立方结构中的位错概念，应用Burgers矢量的计算公式，并进行多步骤的数值计算。题目涉及的知识点较为深入，解题步骤包括公式推导和数值代入，但整体计算过程相对直接，没有涉及复杂多变量的情况。因此，在同题型内属于中等偏上的难度。" + }, + { + "idx": 3179, + "question": "Explain the concept of critical undercooling", + "answer": "In an undercooled liquid, the degree of undercooling at which an embryo can form with a radius equal to the critical nucleus radius is called the critical undercooling (ΔT*). Clearly, when the actual undercooling ΔT<ΔT*, the largest embryo size in the undercooled liquid is still smaller than the critical nucleus radius, making nucleation difficult; only when ΔT>ΔT* can homogeneous nucleation occur. Therefore, critical undercooling is required for nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"critical undercooling\"的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对临界过冷度这一基本概念的定义和原理的理解，属于基础概念记忆范畴，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释临界过冷度的概念，并简要说明其与形核条件的关系。虽然涉及基本原理的记忆和理解，但不需要复杂的体系阐述或多概念交叉分析，属于中等难度的概念解释题。" + }, + { + "idx": 3180, + "question": "Explain the concept of dynamic undercooling", + "answer": "During crystal growth, a certain degree of undercooling in the liquid ahead of the solid/liquid interface is required to satisfy (dN/dt)F > (dN/dt)M. This undercooling is called dynamic undercooling (ΔTc = Tm − Ti), which is a necessary condition for crystal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释动态过冷的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查动态过冷（dynamic undercooling）这一基本概念的定义和基本原理，属于基础概念的记忆和理解范畴。 | 难度: 在简答题中属于中等难度，需要解释动态过冷的概念及其在晶体生长中的作用，但不需要深入阐述复杂的概念体系或进行多层次的论证。" + }, + { + "idx": 3181, + "question": "Given that the unit dislocation a/2 [101] can combine with the Shockley partial dislocation [121] to form a Frank partial dislocation, determine the Burgers vector of the newly formed Frank partial dislocation.", + "answer": "The Burgers vector of the newly formed Frank partial dislocation is b, where b = a/2 [101] + a/6 [121] = a/3 [111].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过矢量加法计算新形成的Frank部分位错的Burgers矢量，需要应用具体的数值计算和公式推导。答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要理解位错的基本概念，并应用矢量加法规则进行多步计算，涉及不同位错类型的关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解位错组合的概念，掌握Burgers矢量的计算方法，并进行多步向量运算。虽然计算过程明确，但需要将多个概念关联起来综合分析，符合等级3的难度标准。" + }, + { + "idx": 3182, + "question": "Analyze whether a screw dislocation with Burgers vector $b=\\frac{a}{2}$ [overline{{1}}10] moving on the (111) plane in a face-centered cubic crystal can cross-slip onto one of the (111), (11overline{1}), or (overline{1}11) planes when obstructed. Why?", + "answer": "For the screw dislocation with $b=\\frac{a}{2}[\\overline{{1}}10]$, the dislocation line $t=\\left[\\overline{{1}}10\\right]$. Since [\\overline{{1}}10] $[\\overline{{1}}10]=0$, the [\\overline{{1}}10] direction lies on the (11overline{1}) plane, meaning $t$ is also on the (11overline{1}) plane. Therefore, the intersection line of (111) and (11overline{1}) planes is [\\overline{{1}}10], so the screw dislocation with $b=\\frac{a}{2}$ [\\overline{{1}}10] can cross-slip onto the (11overline{1}) plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析一个具体的材料科学现象（位错的交叉滑移），并解释其原因。答案提供了详细的文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求分析螺位错在面心立方晶体中的交滑移行为，涉及位错线方向、滑移面几何关系以及交滑移条件的综合判断。需要深入理解位错理论、晶体几何学以及交滑移机制，并进行多步骤的逻辑推理和综合分析。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。题目要求综合运用晶体学、位错理论和滑移系统知识，进行多步骤推理分析。具体难点包括：" + }, + { + "idx": 3183, + "question": "Explain the concept of undercooling", + "answer": "The temperature difference between the actual crystallization temperature and the theoretical crystallization temperature is called the undercooling (ΔT=Tm−Tn). It is required by the thermodynamic conditions of phase transformation. Only when ΔT>0 can the condition that the free energy of the solid phase is lower than that of the liquid phase be achieved. The free energy difference between the liquid and solid phases is the driving force for crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"undercooling\"的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对\"undercooling\"这一基础概念的定义和基本原理的理解，属于材料科学中相变热力学的基础知识范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"undercooling\"的概念，涉及定义、基本原理和必要的公式说明，但不需要复杂的体系阐述或多层次分析。属于基础概念记忆性知识，但需要一定的理解和表述能力。" + }, + { + "idx": 3186, + "question": "Directly observing the aluminum sample, the dislocation density within the grains is ρ=5×10^13/m^2. If the angle between subgrains is 5°, estimate the dislocation spacing at the interface (the lattice constant of aluminum a=2.8×10^-10m).", + "answer": "Using the formula D≈b/θ, where b is the magnitude of the Burgers vector of the dislocation and D is the dislocation spacing, the Burgers vector b=[101], so b_Al=a/2×√2=2.8×10^-10×√2/2≈1.98×10^-10m. θ=5/57.3=0.087, substituting into the expression for D, we obtain D=2.28×10^-9m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计位错间距，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括Burgers向量的计算、角度的转换以及最终代入公式求解。虽然公式直接给出，但需要理解并正确应用相关概念和计算方法，涉及一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解位错密度、亚晶界角度与位错间距的关系，并应用Burgers矢量的计算公式。解题过程涉及多步计算和概念关联，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3187, + "question": "Describe the structural conditions of crystalline phase transition", + "answer": "The structural fluctuations present in the liquid are the basis for the formation of crystal nuclei during crystallization, therefore, structural fluctuations are the necessary structural conditions for the crystallization process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述晶体相变的结构条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对结晶过程中结构波动这一基本概念的理解和记忆，属于基础概念层面的知识。 | 难度: 在简答题题型中，该题目要求对\"结晶相变的结构条件\"进行解释和描述，涉及基础概念的记忆和简单阐述。虽然需要理解结构波动与结晶过程的关系，但不需要复杂的体系阐述或多层次分析，属于概念解释和描述级别的难度。" + }, + { + "idx": 3188, + "question": "Direct observation of an aluminum specimen shows a dislocation density within the grains of ρ=5×10^13/m^2. If the angle between subgrains is 5°, estimate the average size of the subgrains (the lattice constant of aluminum is a=2.8×10^-10m).", + "answer": "Assuming all dislocations are concentrated on the subgrain boundaries and each subgrain is a regular hexagon with side length a and area S. S=1/2×a×√3/2×a×6=3√3/2×a^2. The number of subgrains per unit area is n=1/S. Substituting the values of D and S gives 1/2×6a×1/2.28×10^-9×1/(3/2×√3×a^2)=5×10^13. Finally, a=1.01×10^-5m is obtained, so the average subgrain size d=2a=2.02×10^-5m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计亚晶粒的平均尺寸，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算和概念关联，包括对位错密度、亚晶界角度和晶格常数的综合分析，并应用几何公式进行推导和计算。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要理解位错密度和亚晶界角度的关系，应用几何公式进行多步计算，并综合分析多个概念。虽然计算步骤较多，但变量关系相对明确，属于中等偏上的难度。" + }, + { + "idx": 3189, + "question": "Under the same negative temperature gradient, why does Pb crystallize into dendritic crystals, while the crystallization interface of Si is flat?", + "answer": "Under the same negative temperature gradient, Pb is a metallic element with a rough interface. Therefore, it grows into dendritic crystals continuously in the direction perpendicular to the liquid-solid interface. In contrast, Si is a non-metallic element with a smooth interface, and it grows into crystals with flat interfaces through discontinuous lateral growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在相同的负温度梯度下，Pb和Si的结晶形态不同，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的晶体生长理论，分析不同元素（金属Pb和非金属Si）在相同负温度梯度下的结晶行为差异。涉及界面粗糙度、生长机制（连续垂直生长与不连续侧向生长）等复杂概念的关联和解释，要求较高的推理分析和机理解释能力。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求解释在相同负温度梯度下，Pb和Si结晶形态差异的原因，这需要综合运用金属与非金属的界面特性、晶体生长机理等知识进行深入分析。解题步骤涉及对粗糙界面和平滑界面的理解，以及不同生长方式的对比，要求考生具备较高的推理分析和机理解释能力。因此，在同题型内属于最高难度等级。" + }, + { + "idx": 3190, + "question": "In the symmetric tilt grain boundary of face-centered cubic metal $\\\\mathrm{Cu}$, the spacing between two positive edge dislocations is $D=1000\\\\mathrm{nm}$. Assuming the extra half-plane of the edge dislocation is the (110) plane and $d_{110}=0.1278\\\\mathrm{~nm}$, find the tilt angle $\\\\theta$ of the tilt grain boundary.", + "answer": "The unit dislocation of the face-centered cubic structure is $b=\\\\frac{a}{2}\\\\langle110\\\\rangle$. Since the {110} plane has an extra atomic plane, $b=2d_{110}=2\\\\times0.1278=0.2556\\\\mathrm{nm}$. The tilt angle $\\\\theta$ of the tilt grain boundary can be calculated using the following deformation formula: $$ \\\\theta\\\\approx\\\\frac{b}{D}=\\\\frac{0.2556}{1000}=2.556\\\\times10^{-4}\\\\times\\\\frac{180}{\\\\pi}\\\\approx0.0146^{\\\\circ} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解倾斜角θ，答案中包含了具体的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的间距和位错信息直接套用公式计算倾斜角度，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（θ≈b/D）进行简单数值计算，无需任何公式组合或复杂推导步骤。题目中所有参数均为已知条件，且计算过程仅涉及基本单位换算（弧度转角度），完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 3191, + "question": "Given: the melting point of aluminum Tm=993K, the volumetric heat of fusion Lm=1.836×10^9 J/m^3, the solid-liquid interface specific surface energy σ=93 mJ/m^2, and the atomic volume V0=1.66×10^-29 m^3. Considering the solidification of liquid aluminum at 1 atm, when the undercooling ΔT=19℃, calculate the critical nucleus size r*.", + "answer": "The critical nucleus size r* = (2σ Tm) / (Lm ΔT) = (2 × 93 × 10^-3 × 993) / (1.836 × 10^9 × 19) = 9.45 × 10^-8 m = 94.5 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（临界核尺寸r*），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联，如临界核尺寸的计算需要理解并应用相关公式，同时需要将多个给定的参数进行综合分析。虽然计算过程较为直接，但需要一定的理解和应用能力。 | 难度: 在计算题中属于综合性计算问题，需要理解临界核尺寸的概念，并正确应用公式进行多步计算。题目涉及多个物理量的代入和单位转换，但计算过程相对直接，没有复杂的变量关系或高级数学技巧要求。" + }, + { + "idx": 3192, + "question": "What are the characteristics of the outermost crystal zone in the ingot structure?", + "answer": "The outermost layer is a fine equiaxed grain zone. Its formation is due to the lower temperature of the mold wall, which results in a larger undercooling of the liquid and thus a higher nucleation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述铸锭结构中最外层晶区的特征，答案提供了详细的文字解释，符合简答题的特点。 | 知识层次: 题目考查对铸锭结构中最外层晶区特征及其形成原因的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答铸锭结构中最外层晶区的特征及其形成原因，涉及对基本概念的理解和简单解释，但不需要复杂的体系阐述或多步骤推理。虽然需要记忆一些关键术语（如\"fine equiaxed grain zone\"）和基本原理（如\"undercooling\"和\"nucleation rate\"），但整体上仍属于基础概念的解释范畴。" + }, + { + "idx": 3193, + "question": "Given: The solid-liquid interface specific surface energy of aluminum σ=93 mJ/m^2, and the free energy change per unit volume ΔGV=-3.51×10^7 J/m^3. Calculate the free energy change ΔGr* (nucleation work) at the critical nucleus size r* during the transition from liquid to solid.", + "answer": "ΔGr* = (16π σ^3) / (3 ΔGV^2) = (16π × (93 × 10^-3)^3) / (3 × (-3.51 × 10^7)^2) = 3.47 × 10^-15 J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体数值的代入和计算，最终给出一个具体的数值结果。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及到的认知能力主要是理解和应用，不需要复杂的分析或综合过程。虽然需要代入数值进行计算，但整个过程是直接的，没有涉及多步推理或深度理解。 | 难度: 在计算题中属于最简单难度，仅需直接套用单一公式进行数值计算，无需多步骤推导或组合多个公式。题目明确给出了所有必要参数，且公式应用非常直接。" + }, + { + "idx": 3194, + "question": "Briefly describe the mechanism of crystal growth.", + "answer": "The mechanism of crystal growth refers to the microscopic growth mode of crystals, which is related to the structure of the liquid/solid interface. For substances with rough interfaces, approximately $50\\\\%$ of the atomic positions on the interface are vacant. These vacancies can accept atoms, allowing liquid atoms to individually occupy the vacancies and connect with the crystal. The interface moves perpendicularly along its normal direction, exhibiting continuous growth. For crystals with smooth interfaces, growth does not occur through the attachment of individual atoms. Instead, it proceeds via homogeneous nucleation, forming a two-dimensional nucleus one atomic layer thick on the crystallographic facet interface. This creates a step between the new nucleus and the original interface. Individual atoms can then fill in the step, enabling lateral growth of the two-dimensional nucleus. Once the layer is filled, a new two-dimensional nucleus forms on the new interface, and the process repeats. If the smooth interface of a crystal has an exposed screw dislocation, the interface becomes a spiral surface, forming a step that never disappears. Atoms attach to this step, allowing the crystal to grow.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶体生长的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细描述晶体生长的微观机制，涉及粗糙界面和平滑界面的不同生长方式，以及二维成核和螺旋位错等复杂概念。需要综合运用材料科学中的晶体生长理论，进行机理的解释和推理分析，思维过程深度较高。 | 难度: 在简答题的题型框架内，该题目要求对晶体生长的机制进行深度解释，涉及粗糙界面和平滑界面的不同生长模式，以及二维成核和螺旋位错等复杂概念。虽然题目没有要求全面分析所有可能的生长现象，但对机理的解释需要综合运用多个知识点，并进行推理分析，因此属于等级4的难度。" + }, + { + "idx": 3195, + "question": "What are the characteristics of the central equiaxed grain zone in the ingot structure?", + "answer": "The center is the equiaxed grain zone. Its formation is due to the further increase in mold wall temperature and the further decrease in liquid undercooling, resulting in the heat dissipation directionality of the remaining liquid becoming less obvious and the liquid being in a state of uniform cooling. At the same time, unmelted impurities, broken dendrites, etc., tend to concentrate in the remaining liquid, all of which promote the formation of equiaxed grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述中心等轴晶区的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释中心等轴晶区的形成原因，涉及多个因素的相互作用（温度变化、液体过冷度、散热方向性、杂质和枝晶碎片的影响），需要综合分析这些因素如何共同促进等轴晶的形成。虽然不涉及复杂计算，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求考生解释和论述铸锭结构中中心等轴晶区的特征，涉及多步概念关联和综合分析。虽然需要理解铸锭凝固过程中的温度梯度、过冷度变化以及杂质和枝晶碎片的影响，但不需要进行多角度或深度关联性分析。因此，在简答题题型中，该题目属于综合分析和说明的难度等级。" + }, + { + "idx": 3196, + "question": "Analyze the basic conditions for the formation of single crystals.", + "answer": "The basic condition for forming a single crystal is to ensure that only one nucleus is produced (or only one nucleus can grow) when the liquid metal crystallizes, and it grows into a single crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求分析单晶形成的基本条件，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查单晶形成的基本条件，属于基本原理的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求分析单晶形成的基本条件，但答案主要涉及对基本原理的记忆和简单解释，不需要复杂的体系阐述或多步骤推理。相比等级1的基本定义简答，该题需要稍多的概念描述，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 3197, + "question": "Given: The volumetric latent heat of fusion for aluminum Lm=1.836×10^9 J/m^3, melting point Tm=993K, undercooling ΔT=19℃. Calculate the change in volumetric free energy ΔGV during the transformation from liquid to solid.", + "answer": "ΔGV = (-Lm ΔT) / Tm = (-1.836 × 10^9 × 19) / 993 = -3.51 × 10^7 J/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体数值的代入和运算，最终给出一个具体的计算结果。 | 知识层次: 题目要求直接套用给定的公式进行数值计算，涉及基本的公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式ΔGV = (-Lm ΔT)/Tm进行数值代入计算，无需任何公式转换或多步骤推导，完全符合等级1\"单一公式直接计算\"的特征。题目提供的参数完整且单位统一，计算过程不涉及复杂数学运算或单位换算。" + }, + { + "idx": 3198, + "question": "Given the liquid-solid interfacial energy of pure liquid nickel σ=2.53×10^-5 J/cm^2, the critical nucleus radius r*=1 nm, the melting point of pure nickel Tm=1726 K, the heat of fusion ΔLm=18075 J/mol, the molar volume Vs=6.6 cm^3/mol, and the undercooling ΔT=319 K, calculate the critical nucleation work ΔG*.", + "answer": "ΔG*=(16πσ^3·Tm^2·Vs^2)/(3·Lm^2·ΔT^2)=(16×3.14×(2.53×10^-5)^3×1726^2×6.6^2)/(3×18075^2×319^2)=1.06×10^-18 (J)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（ΔG*），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和多个参数的关联应用，需要理解临界成核功的计算公式，并正确代入各个参数进行综合计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式和概念（如临界核半径、熔化热、摩尔体积等），并进行多步数值计算。虽然步骤明确，但涉及多个变量的综合运用和单位转换，对学生的计算能力和概念关联能力要求较高。" + }, + { + "idx": 3199, + "question": "How does vibration crystallization refine grain size?", + "answer": "Vibration, on one hand, provides the energy required for nucleation, and on the other hand, can fracture growing crystals, thereby increasing more crystallization nuclei and refining the grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动结晶如何细化晶粒尺寸，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释振动结晶细化晶粒的机理，涉及能量供给、形核过程和晶体断裂等多个概念的综合运用和推理分析，需要深入理解振动对结晶过程的影响机制，属于复杂分析层次。 | 难度: 在简答题中，该题目属于机理深度解释难度。题目要求考生不仅理解振动结晶的基本概念，还需要解释振动如何通过提供成核能量和破碎晶体来细化晶粒尺寸。这需要综合运用材料科学中的结晶理论和机械作用原理，进行较为深入的机理分析。虽然不涉及复杂现象的全面分析（如多因素耦合或动态过程模拟），但对单一机理的解释深度要求较高，属于简答题中的较高难度。" + }, + { + "idx": 3200, + "question": "Does the ingot structure necessarily have three crystal zones?", + "answer": "It should be pointed out that not all ingot structures have three crystal zones. Due to different solidification conditions, an ingot may only have one type of crystal zone or only two types of crystal zones.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目以疑问句形式提出一个陈述（\"Does the ingot structure necessarily have three crystal zones?\"），答案明确判断该陈述的正确性（\"not all ingot structures have three crystal zones\"），符合判断题的特征。 | 知识层次: 题目考查对铸锭结构基本概念的记忆和理解，涉及晶体区的分类和形成条件，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对铸锭结构晶体区域数量的理解，需要学生掌握不同凝固条件下可能出现的晶体区域变化，而非简单记忆定义。虽然涉及基础概念，但需要一定的理解深度才能正确判断陈述的对错，因此属于等级2难度。" + }, + { + "idx": 3201, + "question": "What are the characteristics of the intermediate crystal zone in the ingot structure?", + "answer": "The intermediate zone consists of columnar crystals. Its formation is primarily due to the increase in mold wall temperature, where the growth rate of crystal nuclei exceeds the nucleation rate, and heat dissipation is more favorable in the direction perpendicular to the mold wall. In the fine crystal zone, preferentially oriented grains grow into columnar crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释中间晶区的特征，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对铸锭结构中中间晶区特征的基础概念记忆和理解，包括其形成原因和晶体生长方向等基本原理。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释中间晶区的特征及其形成原因，涉及对柱状晶形成机制的理解，但不需要复杂的体系阐述或深入分析。回答需要结合基本原理进行解释，但知识点相对明确，属于中等难度的概念解释题。" + }, + { + "idx": 3203, + "question": "According to solidification theory, what are the basic approaches to refining grains?", + "answer": "From solidification theory, it is known that the number of grains per unit volume during crystallization, z, depends on two factors: the nucleation rate N and the crystal growth rate Vg, i.e., z∝N/Vg. The basic approaches include increasing undercooling, adding nucleating agents (modification treatment), and vibration crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述基本的晶粒细化方法，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从凝固理论出发，解释细化晶粒的基本方法，涉及对成核速率和晶体生长速率的理解，以及如何通过增加过冷度、添加形核剂和振动结晶等方法实现晶粒细化。这需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并解释凝固理论中的基本概念（如形核率和晶体生长速率），并列举几种细化晶粒的基本方法。虽然涉及多个概念，但不需要深入分析或复杂的关联性论述。" + }, + { + "idx": 3204, + "question": "How does increasing undercooling refine grains?", + "answer": "Increasing the undercooling ΔT causes both N and Vg to increase, but the growth rate of N is greater than that of Vg. Therefore, the value of N/Vg increases, meaning z becomes larger.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释undercooling如何细化晶粒，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释过冷度增加如何细化晶粒，涉及成核率(N)和生长速率(Vg)的变化关系及其对晶粒尺寸(z)的影响。这需要综合运用成核与生长理论，分析不同参数间的相互作用，并进行机理层面的解释，属于较高层次的认知要求。 | 难度: 在简答题中属于机理深度解释难度，需要理解并解释过冷度增加对晶粒细化的影响机制，包括形核率N和生长速率Vg的变化关系，并推导出N/Vg比值的变化。这要求对凝固理论有较深入的理解和综合运用能力。" + }, + { + "idx": 3205, + "question": "How does adding a nucleating agent (modification treatment) refine the grain size?", + "answer": "After adding a nucleating agent, it can promote heterogeneous nucleation in the undercooled liquid. It not only increases the substrates required for heterogeneous nucleation but also reduces the critical nucleus volume, both of which will increase the number of nuclei, thereby refining the grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释添加成核剂如何细化晶粒尺寸，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释成核剂如何细化晶粒的机理，涉及异质成核、临界晶核体积等概念的关联和综合分析，需要深入理解并推理分析成核剂的作用机制。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解成核剂的作用原理，还需要解释其对晶粒细化的具体机制，包括促进异质形核和减小临界晶核体积两个方面。这需要考生具备扎实的材料科学基础知识和一定的综合分析能力，能够将多个概念联系起来进行逻辑清晰的阐述。虽然题目涉及的知识点较为专业，但并未要求对复杂现象进行全面分析或提出创新性见解，因此属于等级4而非等级5。" + }, + { + "idx": 3206, + "question": "A Cu-30%Zn brass cold-rolled sheet undergoes 25% cold deformation, resulting in a thickness of 1cm. Find the original thickness Lo.", + "answer": "From (Lo - 1)/Lo = 25%, solving gives Lo = 4/3 cm ≈ 1.333 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解原始厚度Lo，答案是通过数学计算得出的具体数值结果。 | 知识层次: 题目仅涉及基本公式应用和简单计算，通过给定的变形百分比和最终厚度直接套用公式求解原始厚度，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用简单的百分比变形公式 (Lo - 1)/Lo = 25%，并通过一步代数运算即可求解原始厚度Lo。无需多个公式组合或复杂计算步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 3207, + "question": "Compress the above-mentioned cold-rolled sheet from 1cm thickness to 0.6cm, and find the true linear strain e.", + "answer": "e = ln(0.6/(4/3)) ≈ -80%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算真实线性应变e），并给出了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式（真实应变公式）的直接应用和简单计算，不需要多步推理或综合分析 | 难度: 在计算题中属于最低难度，只需要直接套用单一公式（真实线性应变公式e = ln(final thickness/initial thickness)）并进行简单数值计算即可得出结果，无需任何额外的公式组合或复杂步骤。" + }, + { + "idx": 3208, + "question": "A specimen with an original gauge length of L0 is stretched to L. Determine the engineering linear strain and true linear strain during the stretching process.", + "answer": "Engineering linear strain ε = (L - L0) / L0; true linear strain e = ln(L / L0)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式计算工程线应变和真实线应变，答案给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目要求直接应用工程应变和真实应变的定义公式进行计算，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目仅涉及单一公式的直接计算（工程线性应变和真实线性应变），无需组合多个公式或进行复杂推导，属于最基础的难度等级。" + }, + { + "idx": 3209, + "question": "Compress the above-mentioned cold-rolled sheet from 1cm thickness to 0.6cm, calculate the total engineering strain ε.", + "answer": "ε = (0.6 - 4/3)/(4/3) ≈ -55%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算总工程应变ε），并给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目仅需应用基本的工程应变公式进行计算，属于直接套用公式的简单应用，不涉及多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用工程应变公式ε=(l-l0)/l0进行计算，无需任何额外步骤或公式组合。题目中所有参数均已明确给出，计算过程简单直接。" + }, + { + "idx": 3210, + "question": "Can close-packed hexagonal metal magnesium produce cross-slip? What is the slip direction?", + "answer": "In addition to the (0001) $<11$ $\\overline{2}0>$ slip system, magnesium also has $|10\\overline{{1}}1\\}<11\\overline{{2}}0$ > slip systems, and the slip direction is always $<11\\overline{{2}}0:$, so cross-slip can occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁金属是否能够产生交叉滑移以及滑移方向是什么，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅要求理解镁的滑移系统基本概念，还需要分析交叉滑移的可能性及其滑移方向，涉及多个滑移系统的关联和综合分析，思维过程较为深入。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅了解镁的滑移系统，还需要解释交叉滑移的产生机制和滑移方向的具体含义。这需要考生具备扎实的晶体学知识，能够综合运用多个概念进行推理分析，并清晰地表达出滑移方向的晶体学指数及其在交叉滑移中的作用。虽然题目没有要求全面分析复杂现象，但对机理的解释深度要求较高，因此属于等级4难度。" + }, + { + "idx": 3211, + "question": "A 20m long aluminum rod with a diameter of 14.0mm is drawn through a die with an aperture of 12.7mm. Calculate the true strain experienced by this aluminum rod.", + "answer": "True strain e=ln(L/L0)=ln(24.3/20)=19.47%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用（计算真实应变），答案给出了具体的计算过程和结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即使用真实应变公式进行计算，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的真实应变公式e=ln(L/L0)，并进行简单的对数运算即可得出结果，不需要额外的公式组合或复杂的推导过程。" + }, + { + "idx": 3212, + "question": "A 20m long aluminum rod with a diameter of 14.0mm is drawn through a die with an aperture of 12.7mm. Calculate the engineering linear strain experienced by this aluminum rod.", + "answer": "The engineering strain ε=(L-L0)/L0=21.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算工程线性应变），并给出了具体的数值结果（21.5%），这符合计算题的特征。 | 知识层次: 题目主要考查基本公式（工程应变公式）的直接应用和简单计算，无需多步推理或综合分析，属于典型的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用工程线性应变的基本公式ε=(L-L0)/L0，并进行简单的数值代入和计算，无需多个公式组合或复杂推导。" + }, + { + "idx": 3214, + "question": "Compress the above stretched specimen from L to L0, and calculate the engineering linear strain and true linear strain during the compression process.", + "answer": "Engineering linear strain ε = (L0 - L) / L; true linear strain e = ln(L0 / L)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算公式和结果形式，符合计算题的特征。 | 知识层次: 题目要求应用基本的工程应变和真实应变公式进行计算，属于直接套用公式的简单应用，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求直接套用工程应变和真实应变的定义公式进行计算，不需要多个公式组合或复杂推导。虽然涉及两个公式，但都是基础定义式，计算步骤简单直接，属于该题型内的中等偏下难度。" + }, + { + "idx": 3216, + "question": "Given: The critical nucleus size of aluminum r*=94.5 nm, atomic volume V0=1.66×10^-29 m^3. Calculate the number of atoms Nr* in a nucleus with radius r*.", + "answer": "Nr* = (4/3 π r*^3) / V0 = (4/3 π × (94.5 × 10^-9)^3) / (1.66 × 10^-29) = 2.12 × 10^8", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及使用给定的公式和数据进行计算，最终得出一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需将给定的数值代入公式进行计算即可，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（球体体积公式）并进行简单数值计算，无需任何额外的概念理解或步骤组合。" + }, + { + "idx": 3218, + "question": "Given that the critical resolved shear stress of pure aluminum is τ_c = 0.79 MPa, the question is: To produce slip in the [110] direction on the (1̅11) plane, what magnitude of force should be applied in the [001] direction?", + "answer": "The slip plane is (1̅11), the slip direction is [110], and the force axis is [001]. Then, cosφ = 1/√3; cosλ = 0/√2 = 0. Since λ = 90°, σ_S = τ_c / (cosλ · cosφ) = ∞. Therefore, when the force axis is in the [001] direction, the (111)[110] slip system will not be activated.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定在特定方向上施加的力的大小，解答过程中涉及到了临界分切应力、方向余弦等计算步骤，最终得出数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界分切应力的概念，并应用施密特因子（Schmid factor）进行计算。虽然计算过程不算特别复杂，但需要综合分析力轴方向、滑移面和滑移方向之间的关系，并正确应用公式。这超出了简单应用的范围，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解临界分切应力的概念，正确识别滑移面和滑移方向，并应用施密特定律进行计算。虽然计算步骤相对明确，但需要综合分析几何关系和物理概念，属于中等偏上的难度。" + }, + { + "idx": 3219, + "question": "The surface of a copper single crystal is parallel to {001}. If a tensile force is applied along the [001] direction, and the measured critical resolved shear stress is $\\overline{{\\tau_{c}}}=0.7$ MPa, determine the stress at which the material yields.", + "answer": "The force is applied along the [001] direction, which is in a soft orientation with 8 equivalent slip systems. Taking one of them, (111)[overline{1}01], we have: $$ \\cos\\lambda={\\frac{1}{\\sqrt{2}}};\\cos\\varphi={\\frac{1}{\\sqrt{3}}} $$ $$ \\sigma_{S}={\\frac{\\tau_{c}}{\\cos\\lambda\\cdot\\cos\\varphi}}={\\frac{0.7}{{\\frac{1}{\\sqrt{2}}}\\cdot{\\frac{1}{\\sqrt{3}}}}}=1.715~{\\mathrm{MPa}} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定材料屈服时的应力，解答过程中涉及到了三角函数计算和临界分切应力的应用，最终给出了具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括确定滑移系统、计算方向余弦、应用临界分切应力公式等，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于多步骤计算过程难度。题目需要应用临界分切应力的概念，并通过方向余弦计算应力，涉及两个步骤的计算。虽然需要理解晶体取向和滑移系统的概念，但计算过程相对直接，没有涉及复杂的多变量或综合分析。" + }, + { + "idx": 3220, + "question": "A face-centered cubic single crystal is stretched with [131] as the force axis. When the tensile stress is 1×10^7Pa, determine the resolved shear stress on the (111)[1\\\\overline{1}0] slip system.", + "answer": "For the (111)[1\\\\overline{1}0] slip system, cosφ=5√33/33; cosλ=-√22/11. Therefore, τ3=1×10^7×(5√33/33)×(-√22/11)=3.7×10^6Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定分解剪应力，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用晶体学中的滑移系统概念，进行多步计算（包括方向余弦计算和分解剪应力公式应用），涉及概念关联和综合分析能力，但不需要复杂的推理或创新性思维。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体学方向指数、滑移系统、分解剪应力等概念，并进行多步向量计算和三角函数运算。虽然计算过程明确，但涉及多个知识点的综合应用和较复杂的数学运算，属于该题型内中等偏上的难度。" + }, + { + "idx": 3223, + "question": "In the compression test of a magnesium single crystal at room temperature, the [0001] direction coincides with the compression axis. Assuming that the critical resolved shear stress for twinning on the (10\\\\overline{1}2) plane is 10 times that for slip on the (0001) plane, denoted as $\\\\tau_{\\\\mathrm{e}}$, determine whether the crystal will undergo twinning or slip when the compressive stress is sufficiently large, and explain why.", + "answer": "If the compression axis coincides with the [0001] direction, since the slip directions of different slip systems in magnesium are the same, all being <11\\\\overline{2}0> directions, and the slip directions are all perpendicular to the [0001] direction, $\\\\cos\\\\lambda=0$. Therefore, $\\\\sigma_{S}=\\\\frac{\\\\sigma_{C}}{\\\\cos\\\\lambda\\\\cos\\\\phi}=\\\\infty$. No matter how large the pressure is, slip cannot occur. However, the twinning plane is {10\\\\overline{1}2}, and the twinning direction is {10\\\\overline{1}2}. When compressed along the [0001] direction, there is a resolved shear stress. When the external force reaches a certain value, twinning will occur along {10\\\\overline{1}2}<\\\\overline{1}011>{10\\\\overline{1}2}. In this example, the resolved shear stress for twinning has already reached 10 times $\\\\tau_{C}$, so twinning deformation can occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下晶体将发生孪生还是滑移，并说明原因。答案提供了详细的文字解释和论述，没有涉及计算或选择选项，符合简答题的特征。 | 知识层次: 题目要求分析镁单晶在特定压缩轴方向下的变形机制选择，涉及滑移和孪生的临界分切应力比较、晶体学方向计算（Schmid因子分析）、以及变形机制的竞争关系。需要综合运用晶体塑性理论、Schmid定律、以及镁晶体特定滑移/孪生系统的知识进行机理层面的解释，属于需要深度推理和综合分析的问题。 | 难度: 在简答题题型中，该题目属于复杂分析层次，要求综合运用晶体学知识、力学原理和变形机制进行深度推理。具体表现为：" + }, + { + "idx": 3224, + "question": "A copper single crystal is subjected to tension with the tensile axis along the [001] direction and σ=10^6 Pa. Calculate the force acting on a screw dislocation line with Burgers vector b=(a/2)[1̄01] on the (111) plane. Given a_Cu=0.36 nm.", + "answer": "The tensile stress is applied along the [001] direction. On the (111) slip plane, the resolved shear stress along the [1̄01] direction is τ=σcosφcosλ, where cosφ=1/√3, cosλ=1/√2, and σ=10^6 Pa. Thus, τ=10^6×(1/√3)×(1/√2)≈4.08×10^5 Pa. The force per unit length on the dislocation line is F_d=τb=4.08×10^5×(√2/2)×0.36×10^(-9)≈1.04×10^(-4) N/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及应力分解、剪切应力计算和位错线受力计算等具体运算步骤。答案给出了完整的计算过程和具体数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应力分解、剪切应力计算以及力的计算，涉及多个概念（如Burgers向量、滑移面、分解剪切应力等）的关联和综合应用。虽然不涉及复杂的推理或创新设计，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算位错线上的力，涉及应力分解、方向余弦计算、伯格斯矢量应用等多个步骤，但整体计算过程清晰，属于中等应用层次中的典型问题。" + }, + { + "idx": 3225, + "question": "A copper single crystal is subjected to tensile stress with the tensile axis along the [001] direction and σ=10^6 Pa. Calculate the force on the edge dislocation line with Burgers vector b=(a/2)[1̄01] on the (111) plane. Given a_Cu=0.36 nm.", + "answer": "The tensile stress is applied along the [001] direction. On the (111) slip plane, the resolved shear stress along the [1̄01] direction is τ=σcosφcosλ, where cosφ=1/√3, cosλ=1/√2, and σ=10^6 Pa. Thus, τ=10^6×(1/√3)×(1/√2)≈4.08×10^5 Pa. The force per unit length on the dislocation line is F_d=τb=4.08×10^5×(√2/2)×0.36×10^(-9)≈1.04×10^(-4) N/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及应力分解、剪切应力计算以及位错线受力计算，最终需要得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括应力分解、剪切应力计算以及力对位错线的作用计算。同时需要理解晶体学方向、滑移面和位错伯格斯矢量的概念及其相互关系。虽然不涉及复杂的机理分析或创新设计，但需要综合应用多个知识点进行计算和分析。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体学方向指数、分解剪切应力计算、位错受力公式等多个概念，并进行多步骤的数值计算和单位转换。虽然计算过程明确，但涉及多个物理概念的关联应用，属于该题型内中等偏上的难度。" + }, + { + "idx": 3226, + "question": "What are the practical applications of fracture toughness K_IC in mechanical design?", + "answer": "1. Given the working stress σ and the fracture toughness K_IC of the material, the maximum allowable crack size a_c in the workpiece can be estimated. 2. Given the crack size a and the working stress σ, the stress intensity factor K_I during operation can be determined to provide a theoretical basis for reasonable material selection. 3. Given K_IC and the existing crack size a, the maximum allowable stress σ can be determined. If the working stress is less than this stress, the crack will not propagate; otherwise, the crack will become unstable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述断裂韧性K_IC在机械设计中的实际应用，答案提供了详细的文字解释和论述，没有涉及计算或选择选项。 | 知识层次: 题目要求应用断裂韧性K_IC的概念进行实际工程问题的分析，涉及多个步骤的计算和概念关联（如工作应力、裂纹尺寸、应力强度因子的关系），需要综合理解和应用相关知识，但不需要进行复杂的机理分析或创新设计。 | 难度: 在简答题题型中，该题目要求多角度分析论述，涉及多个实际应用场景的综合分析。需要考生不仅理解断裂韧性K_IC的基本概念，还要能够将其与工作应力、裂纹尺寸等参数关联起来，进行多步计算和综合分析。此外，题目还要求考生能够从不同角度（如材料选择、裂纹稳定性评估等）进行论述，体现了较高的知识掌握深度和解题步骤复杂程度。因此，在该题型内属于较高难度等级。" + }, + { + "idx": 3227, + "question": "Describe the process of extended dislocation cross-slip from the (111) plane to the (111) plane in a face-centered cubic structure.", + "answer": "When the extended dislocation on the (111) plane encounters obstacles during slip, it can constrict to form a screw-type perfect dislocation. The dislocation reaction is $$\\\\frac{a}{6}[\\\\bar{1}2\\\\bar{1}]+\\\\frac{a}{6}[\\\\bar{2}11]-\\\\frac{a}{2}[\\\\bar{1}10]$$The formed screw dislocation has a Burgers vector $b=\\\\frac{a}{2}$ [\\\\overline{1}10], and the dislocation line $t=[\\\\overline{{1}}10]$. It can cross-slip onto the (11\\\\overline{1}) plane and spread out, forming an extended dislocation on the (11\\\\overline{1}) plane, i.e., $\\\\frac{a}{2}[\\\\overline{{{110}}}]\\\\rightarrow\\\\frac{a}{6}[\\\\overline{{{21}}}\\\\overline{{{1}}}]+\\\\frac{a}{6}[\\\\overline{{{1}}}21]$. This extended dislocation can continue to move on the (11\\\\overline{1}) plane or constrict again to cross-slip back onto the (111) plane and spread out once more.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述面心立方结构中扩展位错从(111)面到(111)面的交滑移过程，答案提供了详细的文字解释和位错反应方程式，属于需要论述和解释的简答题类型。 | 知识层次: 题目要求描述面心立方结构中扩展位错从(111)面到(111)面的交滑移过程，涉及位错反应、伯格斯矢量计算、位错线方向分析以及在不同滑移面上的扩展和收缩机制。这需要综合运用位错理论、晶体学知识以及位错运动的动力学分析，属于复杂分析和机理解释的范畴。 | 难度: 在简答题的复杂分析题型中，该题目要求全面分析扩展位错的交滑移过程，涉及多个位错反应步骤和晶体学平面的转换。需要深入理解FCC结构中的位错行为、Burgers矢量的计算以及交滑移的机理。解题步骤复杂，要求综合运用位错理论和晶体学知识进行推理分析，属于该题型下的最高难度等级。" + }, + { + "idx": 3229, + "question": "What is called fracture toughness K_IC?", + "answer": "K_IC is the critical value of the stress intensity factor for a Type I crack, representing the fracture toughness in terms of stress intensity factor under linear elastic conditions, with the unit MPa*m^0.5.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"fracture toughness K_IC\"进行文字解释和论述，答案提供了详细的定义和单位说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即断裂韧性K_IC的定义及其在I型裂纹中的临界应力强度因子作用，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释K_IC的定义和意义，但不需要深入阐述复杂的概念体系或进行多层次的论证。题目主要考察对基础概念的记忆和理解，属于中等难度的简答题。" + }, + { + "idx": 3230, + "question": "Describe the similarities between twinning and slip", + "answer": "The similarities between slip and twinning are that both are fundamental modes of crystal plastic deformation, both occur as shear under shear stress along certain crystallographic planes and directions, and the crystal structure type remains unchanged before and after deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述孪生和滑移之间的相似性，需要文字解释和论述，答案也是以文字形式详细阐述了两者的共同点。 | 知识层次: 题目考查对晶体塑性变形基本模式（孪生和滑移）的相似性的记忆和理解，属于基础概念的对比和阐述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求比较两种晶体塑性变形方式的相似性，但答案仅需列举几个关键相似点（如都是基本变形模式、都需要剪切应力、晶体结构保持不变等），不需要深入分析或构建复杂概念体系。这比单纯的定义简答（等级1）要求稍高，但远未达到需要系统阐述（等级3）的程度。" + }, + { + "idx": 3231, + "question": "In the actual crystallization process of metals, nucleation occurs in two ways: homogeneous nucleation and heterogeneous nucleation. Since homogeneous nucleation requires higher nucleation energy, heterogeneous nucleation is predominantly observed.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查金属结晶过程中两种成核方式的基本概念和特点，属于基础概念的记忆和理解。 | 难度: 在判断题中属于基本概念正误判断，仅需识别\"均质形核需要更高形核能\"这一基础概念的正确性，无需理解复杂关系或进行多步骤推理，属于该题型下最基础的难度等级。" + }, + { + "idx": 3232, + "question": "Some solid solutions with certain atomic ratios are disordered solid solutions at high temperatures, and may transform into ordered solid solutions when cooled below a certain critical temperature. Once the ordering transition occurs, it can lead to abrupt changes in certain properties.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对固溶体有序-无序转变这一基本概念的记忆和理解，属于材料科学中相变的基础知识，不涉及复杂分析或综合应用。 | 难度: 在判断题中属于中等难度，需要理解\"无序固溶体\"和\"有序固溶体\"的概念及其转变条件，并判断陈述的正确性。虽然不涉及复杂分析，但需要一定的概念理解而非简单记忆。" + }, + { + "idx": 3233, + "question": "Describe the differences between twinning and slip", + "answer": "The differences are as follows: twinning causes a uniform shear in a portion of the crystal, while slip is concentrated only on certain slip planes. During slip, the slipped and unslipped parts of the crystal have the same phase, whereas the twinned part and the matrix have different phases, exhibiting a special mirror-symmetry relationship. In twinning deformation, the atomic displacement is less than the atomic spacing in the twinning direction, being a fractional multiple of the atomic spacing; during slip deformation, the distance atoms move is an integer multiple of the atomic spacing in the slip direction. Similar to slip, twinning elements are also related to the crystal structure, but the twinning plane and twinning direction in the same structure can differ from the slip plane and slip direction. The critical resolved shear stress for twinning is much higher than that for slip. The stress-strain curve for twinning deformation differs from that of slip, showing serrated fluctuations, mainly because the shear stress required for twinning 'nucleation' is greater than the stress needed for twinning boundary propagation. Generally, slip occurs first, and twinning deformation occurs only when slip becomes difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述孪生和滑移之间的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述孪生和滑移的差异，涉及多个方面的比较，包括剪切分布、相变关系、原子位移、临界分切应力等。这需要理解并关联多个概念，进行综合分析，而不仅仅是记忆基础概念。虽然不涉及复杂的计算或深度推理，但需要对材料变形机制有较好的理解和应用能力。 | 难度: 在简答题题型中，该题目要求对两种晶体变形机制（孪生和滑移）进行多角度的比较分析，涉及多个关键差异点的详细论述。需要考生不仅理解基本概念，还要能够综合应用材料科学中的晶体结构、变形机制等知识，进行系统的对比和解释。题目还要求考生能够联系实际现象（如应力-应变曲线的差异）进行说明，体现了较高的综合分析能力要求。因此，在同题型内属于较高难度等级。" + }, + { + "idx": 3234, + "question": "Using the three-axis system to index the crystallographic plane indices and direction indices of a hexagonal close-packed structure, the resulting indices for the same family of planes or directions are different.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（关于六方密堆积结构的三轴系统索引结果），并要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查对六方密堆积结构晶体学平面指数和方向指数标定方法的基础概念记忆，属于对基本原理的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解六方密堆积结构的三轴系统索引概念，并判断同一族晶面或方向在不同索引方式下的结果差异。虽然涉及基础概念记忆，但需要一定的概念理解能力才能正确判断陈述的对错。" + }, + { + "idx": 3235, + "question": "During the crystallization of liquid metal, the degree of undercooling required to form an embryo equal to the critical nucleus radius in the undercooled liquid is called the critical undercooling.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案以√表示正确），符合判断题的特征 | 知识层次: 题目考查对临界过冷度这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在判断题的基础概念记忆层次中，此题属于最基本的定义正误判断。题目直接考查\"临界过冷度\"的定义，只需记忆相关概念即可判断对错，无需理解或分析复杂关系。属于该题型下最基础难度级别。" + }, + { + "idx": 3236, + "question": "At room temperature, the plastic deformation modes of metal polycrystals are A. Slip, twinning, creep B. Slip, twinning, kinking C. Slip, climb, cross-slip D. Slip, twinning, grain boundary sliding", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查金属多晶体在室温下的塑性变形模式的基本概念记忆，属于对基础知识的直接回忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解金属多晶体在室温下的塑性变形模式，并对选项中的概念进行简单辨析。虽然涉及多个变形模式（滑移、孪生、扭折），但这些都是基础概念，不需要复杂的分析或深度理解。" + }, + { + "idx": 3237, + "question": "The relationship between the yield strength and grain size of No. 10 steel was measured as follows: when the grain diameter was $400\\\\mu m$, $\\\\partial_{\\\\mathfrak{s}}=86$ MPa, and when the grain diameter was $5\\\\mu\\\\mathrm{m}$, $\\\\sigma_{\\\\mathrm{s}}=242$ MPa. Determine the yield strength when the average grain diameter is $50~\\\\mu\\\\mathrm{m}$.", + "answer": "Using the Hall-Petch formula $\\\\sigma_{S}=\\\\sigma_{0}+k d^{-\\\\frac{1}{2}}$, the system of equations is obtained as: $$186=\\\\sigma_{0}+k(400\\\\times10^{-6})^{-\\\\frac{1}{2}}$$ $$1242=\\\\sigma_{0}+k(5\\\\times10^{-6})^{-\\\\frac{1}{2}}$$ Solving gives: $$k=0.393;\\\\sigma_{0}=66.25\\\\mathrm{MPa}$$ Substituting $d=50\\\\times10^{-6}(\\\\mathrm{m})$ into the Hall-Petch formula: $$\\\\sigma_{S}=66.25+0.393(50\\\\times10^{-6})^{-\\\\frac{1}{2}}\\\\approx121.83~\\\\mathrm{MPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和公式（Hall-Petch公式）进行数值计算，最终得出一个具体的数值结果（121.83 MPa）。解答过程涉及建立方程组、求解参数以及代入计算，这些都是计算题的典型特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，包括建立方程组、求解常数、代入新条件计算等步骤。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式建立方程组并求解两个未知数（σ0和k），然后代入新的晶粒尺寸进行计算。虽然涉及多步骤计算，但整体思路清晰，属于该题型内中等偏上的难度水平。" + }, + { + "idx": 3238, + "question": "The main mechanism of high-temperature recovery is A. Dislocation slip and cross-slip B. Dislocation climb and polygonization C. Polygonization and subgrain coalescence D. Bulge nucleation and subgrain coalescence", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查高温回复的主要机制，属于基本原理的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆的选择题，需要考生理解高温回复的主要机制，并对选项中的概念进行简单辨析。虽然涉及多个专业术语（位错攀移、多边形化等），但答案选项B直接对应高温回复的主要机制，不需要复杂的推理过程。相比等级1的直接记忆题稍难，但尚未达到需要深度理解和复杂区分的等级3难度。" + }, + { + "idx": 3239, + "question": "Among the following alloy phase structures, the one with high melting point, high hardness, great brittleness, and simple crystal structure is A. Topologically close-packed phase B. Interstitial compound with complex lattice structure C. Electron compound D. Interstitial phase", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对合金相结构基本特性的记忆和理解，包括熔点、硬度、脆性和晶体结构等基础概念，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要对合金相结构的基本特性有一定理解，并能区分不同相结构的特点。题目虽然涉及多个特性（高熔点、高硬度等），但选项间的区分度较为明显，特别是对\"间隙相\"特性的记忆要求属于基础概念理解层面。" + }, + { + "idx": 3240, + "question": "Using the Peierls-Nabarro formula, explain why slip in crystals usually occurs on the closest-packed planes and in the closest-packed directions.", + "answer": "During room temperature deformation, since the grain boundary strength is higher than that within the grain, the finer the grains, the more grain boundaries are contained per unit volume, resulting in a better strengthening effect. According to the Hall-Petch formula, $\\sigma_{s}=\\sigma_{0}+k d^{-\\frac{1}{2}},$ the smaller the grain diameter $d$, the higher $\\sigma_{S}$ becomes, which is known as fine-grain strengthening. Each grain in a polycrystal is surrounded by other grains, so deformation is not isolated and requires neighboring grains to coordinate and adapt to the shape changes of plastically deformed grains. Plastic deformation must involve multiple slip systems from the outset. The finer the grains, the better the deformation coordination, and thus the better the plasticity. Additionally, finer grains reduce the severity of stress concentrations caused by dislocation pile-ups, which can delay crack initiation. The tortuous grain boundaries hinder crack propagation, contributing to improved strength and plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体滑移通常发生在最密排面和最密排方向的原因，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求使用Peierls-Nabarro公式解释晶体滑移现象，涉及对位错理论、晶体结构、滑移系统选择等复杂概念的综合运用和机理分析。需要深入理解公式背后的物理意义，并能将多个材料科学原理关联起来进行推理和解释。 | 难度: 在简答题的复杂分析层次中，该题目要求综合运用Peierls-Nabarro公式、晶体滑移原理和材料强化机制等多方面知识进行深度解释。需要考生不仅理解公式本身，还要能够将理论公式与实际晶体变形行为（如位错运动、滑移系选择等）建立联系，并推导出密排面和密排方向的优势滑移机制。这种需要多知识点整合、机理推导和现象解释的题目，在简答题中属于最高难度等级。" + }, + { + "idx": 3241, + "question": "The driving force for atomic diffusion is A. Concentration gradient of components B. Temperature gradient C. Chemical potential gradient of components", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查原子扩散驱动力的基本概念记忆，属于材料科学中扩散现象的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解原子扩散的基本概念并区分浓度梯度、温度梯度和化学势梯度这三个相关但不同的概念。虽然不涉及复杂计算或多步骤推理，但需要对基础概念有一定的理解才能正确选择化学势梯度作为驱动力。" + }, + { + "idx": 3242, + "question": "When polycrystalline metal is heated to a relatively high temperature and held, the grains will grow. The grain growth mode is A. Subgrain coalescence and growth B. Grain boundary bowing outward and growth C. Grain boundary moving toward the curvature center D. Movement of Y junctions", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从四个选项中选择关于晶粒生长模式的正确答案 | 知识层次: 题目考查对晶粒生长模式的理解和应用，需要将晶界移动的基本原理与具体现象（晶粒生长）关联起来，属于中等应用层次。虽然涉及基础概念，但需要一定的综合分析能力来理解晶界移动的方向和机制。 | 难度: 在选择题中属于中等难度，需要理解晶粒生长的基本概念和机制，并能够区分不同生长模式的特点。虽然题目涉及多个概念，但选项之间的区分度较高，只要掌握了晶粒生长的基本原理，就能做出正确选择。不需要复杂的计算或高难度的综合分析。" + }, + { + "idx": 3243, + "question": "In the cubic system, the relationship between the crystal plane (hkl) and the crystal direction [hkl] is A. [hkl]//(hkl) B. [hkl] is perpendicular to (hkl) C. No definite relationship", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查立方晶系中晶面与晶向关系的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体学中晶面和晶向的基本关系，并进行简单辨析。虽然不涉及复杂计算或多步骤推理，但需要对立方晶系中晶面与晶向的垂直关系有明确认知，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 3244, + "question": "Which of the following statements about dislocation loops is correct? A. A dislocation loop cannot be entirely edge dislocation everywhere. B. A dislocation loop can be entirely edge dislocation everywhere. C. A dislocation loop must simultaneously contain both edge dislocation and screw dislocation. D. A dislocation loop must simultaneously contain edge dislocation, screw dislocation, and mixed dislocation.", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C、D）中选择关于位错环的正确陈述，符合选择题的特征。 | 知识层次: 题目考查对位错环基本概念的记忆和理解，特别是位错环中位错类型的分布情况，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要对位错环的基本性质有一定理解，并能区分边缘位错和螺型位错的概念。题目考察的是对位错环类型的基本辨析能力，不需要复杂的分析或深度理解。" + }, + { + "idx": 3245, + "question": "The correct order of coordination numbers for the following alloy phases from small to large is A.SiC、NaCl、a-Fe、Cu B.a-Fe、SiC、Cu、NaClC.a-Fe、Cu、SiC、NaCl D.SiC、a=Fe、NaCl、Cu", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确的配位数顺序，符合选择题的特征 | 知识层次: 题目考查对合金相配位数顺序的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解并比较不同合金相的配位数概念，但不需要复杂的计算或深度分析。主要考察对基础概念的记忆和简单辨析能力。" + }, + { + "idx": 3246, + "question": "Which of the following statements about zone melting is correct? A. For alloys with $K_{0}<1$, the solute is enriched at the end, and the beginning is purified; for alloys with $K_{0}>1$, the solute is enriched at the beginning, and the end is purified. B. For alloys with $K_{0}<1$, the solute is enriched at the beginning, and the end is purified; for alloys with $K_{0}>1$, the solute is enriched at the end, and the beginning is purified. C. Regardless of $K_{0}<1$ or $K_{0}>1$, the solute is enriched at the beginning. D. Regardless of $K_{0}<1$ or $K_{0}>1$, the solute is enriched at the end.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择关于区域熔炼的正确陈述，符合选择题的特征 | 知识层次: 题目考查对区域熔炼基本原理的记忆和理解，特别是关于分配系数K0对溶质分布影响的直接应用。 | 难度: 在选择题中属于中等难度，需要理解分区熔炼的基本原理和分配系数K0的概念，并能区分K0<1和K0>1时溶质分布的不同情况。虽然题目涉及的概念较为基础，但需要考生对概念进行简单辨析，而不是简单的记忆识别。" + }, + { + "idx": 3247, + "question": "Carburize industrial pure iron at 920°C. If the carbon concentration on the workpiece surface remains constant, i.e., w_C=1.2%, the diffusion coefficient D=1.5×10^-11 m^2/s, and carburize for 10h. If the carburized layer depth is defined as the distance from the surface to where the carbon mass fraction is 0.2%, find the carburized layer depth?", + "answer": "Substitute C_x=0.2 into the formula C_x=1.2[1-erf(6.8×10^2x)]. Referencing the error function table, Z≈6.8×10^2x=0.9784, the layer depth is x=0.00144m=1.44mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的参数和公式求解渗碳层深度，答案也是具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和误差函数表进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程和误差函数表进行多步计算，涉及参数替换和单位转换，但计算过程相对直接，没有涉及复杂多变量或高阶数学工具。" + }, + { + "idx": 3248, + "question": "Carburize industrial pure iron at 920°C. If the carbon concentration on the workpiece surface remains constant, i.e., w_C=1.2%, with a diffusion coefficient D=1.5×10^-11 m^2/s, and carburize for 10 hours. Determine the surface carbon concentration distribution?", + "answer": "Let the carburizing depth be x. Substituting C_0=0, C_s=1.2, D=1.5×10^-11 m^2/s, and t=36000s into the formula (C_s-C_x)/(C_s-C_0)=erf(x/(2√(Dt))), the surface carbon concentration distribution is obtained as C_x=1.2[1-erf(6.8×10^2x)].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定表面碳浓度分布，解答过程中涉及到了具体的数值代入和公式运算，最终给出了具体的计算结果。 | 知识层次: 题目需要进行多步计算，包括代入公式和求解误差函数，涉及扩散系数的应用和碳浓度分布的计算，需要一定的综合分析能力。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在计算题中属于综合性计算问题。题目涉及扩散方程的应用、误差函数的理解以及多步骤的数值计算。虽然题目提供了明确的参数和公式，但需要学生正确理解并应用这些概念，进行综合分析才能得出正确答案。这比简单的单步计算题（等级2）更复杂，但尚未达到涉及复杂多变量或高度抽象概念的等级4难度。" + }, + { + "idx": 3249, + "question": "Please design an experimental plan to measure the recrystallization activation energy of a metal sheet cold-rolled by 75%.", + "answer": "Subject the cold-rolled specimen to isothermal recrystallization at different temperatures, and for each recrystallization temperature, determine the time t required to achieve a certain recrystallized volume fraction x_V. Since the recrystallization rate of cold-deformed metal V_rec ∝ 1/t = A′ e^(-Q_R/RT), take the logarithm of both sides: ln(1/t) = ln A′ - Q_R/RT The relationship between ln(1/t) and 1/T is linear. Plot this line using experimental data, and the slope of the line can be used to determine the recrystallization activation energy Q_R.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计一个实验方案来测量金属板材的再结晶活化能，答案提供了详细的实验步骤和理论依据，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求设计实验方案来测量金属板材的再结晶活化能，涉及实验设计、数据分析和机理解释。需要综合运用材料科学知识，包括再结晶动力学、热力学和实验方法，并进行优化设计。这需要深度理解和创新应用，属于高级综合层次。 | 难度: 在简答题题型中，该题目属于最高难度等级。它要求学生不仅理解金属再结晶的基本原理，还需要设计一个完整的实验方案来测量激活能。这涉及到实验设计、数据处理和理论推导的综合能力。具体来说，学生需要：" + }, + { + "idx": 3250, + "question": "Describe the recovery mechanism at medium temperatures of 0.3~0.5Tm", + "answer": "At medium-temperature recovery of 0.3~0.5Tm, dislocations glide on slip planes, causing dislocations of opposite signs to meet and annihilate, reducing dislocation density, rearranging and recombining within dislocation tangles, and regularizing subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述中等温度下的恢复机制，答案是一段详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释中等温度下的回复机制，涉及位错运动、湮灭、重排和亚晶粒的规律化等复杂过程，需要综合运用材料科学中的位错理论和回复机制知识，进行推理分析和机理解释。 | 难度: 在简答题题型中，该题目要求对中等温度下的恢复机制进行机理深度解释，涉及位错运动、湮灭、重排和亚晶粒规则化等多个复杂概念的综合运用。虽然不需要全面分析所有相关现象，但需要对特定温度范围内的恢复过程有深入理解，属于机理深度解释的难度等级。" + }, + { + "idx": 3251, + "question": "Describe the recovery mechanisms at high temperatures above 0.5Tm", + "answer": "At high temperatures above 0.5Tm, in addition to dislocation slip, recovery can also occur through climb, with the primary mechanism being polygonization, forming low-angle grain boundaries. After polygonization, subgrain coalescence and growth still exist. Subgrain coalescence can be achieved through the movement of Y-nodes, which requires dislocation climb, slip, and cross-slip to accomplish.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述高温下的恢复机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述高温下的回复机制，涉及位错滑移、攀移、多边形化、亚晶合并和生长等多个复杂过程，需要综合运用材料科学中的位错理论和高温变形机制知识，进行机理的解释和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对高温恢复机制进行全面深入的机理解释，涉及多种复杂的材料科学概念（如位错攀移、多边形化、亚晶合并等）及其相互作用。需要考生综合运用热力学、动力学和晶体缺陷理论进行系统分析，并准确描述微观结构演变过程。这完全符合等级5\"复杂现象全面分析\"的标准，是该题型下最高难度的考查要求。" + }, + { + "idx": 3252, + "question": "Adding thorium oxide particles with a size of 10-50nm to nickel, after 40% rolling, the material exhibits high high-temperature strength. Explain the reason.", + "answer": "According to the recrystallization theory of two-phase alloys, if the second-phase particles are very fine (less than $0.3\\\\mu m$) and the spacing is small (less than $1\\\\:\\\\mu\\\\mathrm{m}$), the second-phase particles will inhibit the formation of recrystallization nuclei. In this case, the added second-phase particles are smaller than $0.3\\\\mu m$, so adding a certain volume fraction of thorium oxide can improve high-temperature performance. This is because before the formation of recrystallization nuclei, the growth of sub-nuclei encounters the obstruction of second-phase particles, inhibiting the formation of recrystallization nuclei and preventing recrystallization from occurring, so that recrystallization does not occur even before melting. Therefore, during high-temperature operation, the dislocation density remains high, resulting in high deformation resistance. Additionally, thorium oxide particles hinder the movement of dislocations, increasing the resistance to plastic deformation, thereby enhancing high-temperature performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料在高温下表现出高强度性能的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释纳米级氧化钍颗粒增强镍基合金高温强度的机理，涉及多相合金再结晶理论、第二相粒子阻碍作用、位错运动机制等多个知识点的综合运用和深入分析，需要较高的推理能力和机理解释能力。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于复杂现象全面分析的难度等级。题目要求综合运用材料科学中的多相合金再结晶理论、第二相粒子强化机制、高温强度影响因素等多个知识点，并进行深度机理解释和逻辑推理。解题过程需要：" + }, + { + "idx": 3253, + "question": "For an Fe-3% (Si) alloy containing MnS particles, when the particle radius is $0.05\\\\mu m$ and the volume fraction is approximately 1%, annealing below 850℃ results in the cessation of normal grain growth when the average grain diameter of the matrix is $6\\\\mu m$. Analyze the reason for this phenomenon.", + "answer": "According to the formula for calculating the limiting average grain size: $$\\\\overline{{D}}_{\\\\mathrm{lim}}=\\\\frac{4r}{3\\\\varphi}=\\\\frac{4\\\\times0.05}{3\\\\times0.01}=6.7~\\\\mu\\\\mathrm{m}$$ The dispersed particles exert a pinning effect on grain boundary migration. When the driving force for grain boundary migration provided by grain boundary energy equals the resistance to grain boundary migration caused by the dispersed particles, the limiting grain size is reached. Further holding does not increase the grain size, as calculated by $\\\\overline{{D}}_{\\\\mathrm{lim}}=6.7~\\\\mu m$. During annealing, the average matrix diameter is 6 μm, which is already close to $\\\\overline{{D}}_{\\\\mathrm{lim}}$, so grain growth becomes extremely slow and nearly stops.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析现象的原因，答案提供了详细的文字解释和论述，包括公式应用和理论分析，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的晶粒生长理论、第二相粒子钉扎效应以及相关公式计算，进行机理分析和解释。涉及多步计算（极限晶粒尺寸公式推导）、概念关联（粒子钉扎效应与晶界迁移的平衡）以及综合分析（实验现象与理论计算的对比）。思维过程要求深入理解材料微观结构演变机制，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅掌握晶粒生长和粒子钉扎效应的基本概念，还需要运用公式计算极限晶粒尺寸，并解释粒子钉扎效应如何影响晶界迁移和晶粒生长。此外，考生需要将计算结果与实际观察到的现象（6 μm接近计算值6.7 μm）联系起来，进行合理的机理分析。虽然题目涉及的知识点较为专业，但解题步骤相对明确，属于该题型中要求机理解释但不需要多因素综合分析的题目。" + }, + { + "idx": 3254, + "question": "What are the conditions for the occurrence of secondary recrystallization?", + "answer": "The conditions for abnormal grain growth are that normal grain growth is strongly hindered by dispersed phase particles, texture, surface energy grooves, etc., and the number of grains that can grow is small, resulting in a significant difference in grain size, which leads to abnormal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述二次再结晶发生的条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释二次再结晶发生的条件，涉及多个因素的相互作用（如分散相颗粒、织构、表面能槽等）以及它们如何阻碍正常晶粒生长并导致异常生长。这需要对概念的综合理解和多因素分析，属于中等应用层次。 | 难度: 在简答题中，该题目属于较高难度，需要考生理解并综合多个概念（如分散相颗粒、织构、表面能沟槽等对晶粒生长的阻碍作用），并分析这些因素如何共同导致异常晶粒生长。此外，题目要求解释次级再结晶发生的条件，这需要对材料科学中的相变和微观结构演变有较深入的理解和关联性分析。因此，该题目在简答题题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 3255, + "question": "What is called secondary recrystallization?", + "answer": "The growth of grains after recrystallization is further divided into normal growth and abnormal growth. The abnormal growth of grains is also called discontinuous growth or secondary recrystallization. Secondary recrystallization is a special mode of grain growth where the growth of most grains in the matrix is suppressed, while a few grains grow rapidly, significantly increasing the size difference between grains until these rapidly growing grains come into complete contact with each other.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary recrystallization\"进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查的是对\"二次再结晶\"这一基本概念的定义和解释，属于材料科学中基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释secondary recrystallization的定义和特征，但不需要阐述复杂的理论体系或进行深入分析。题目主要考察对基础概念的记忆和理解，属于中等难度的简答题。" + }, + { + "idx": 3256, + "question": "Describe the recovery mechanism at low temperatures of 0.1~0.3Tm", + "answer": "Recovery at 0.1~0.3Tm low temperatures primarily involves the movement of point defects, where vacancies and interstitial atoms migrate to grain boundaries or dislocations and annihilate, the recombination of vacancies and interstitial atoms, and the aggregation of vacancies to form vacancy pairs or vacancy clusters, leading to a significant reduction in point defect density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述低温下的恢复机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释低温恢复机制，涉及点缺陷的迁移、湮灭和聚集等复杂过程，需要综合运用材料科学中的缺陷理论和热力学知识，进行机理层面的分析和解释。这超出了简单记忆或基本应用的范畴，属于需要深入理解和推理的复杂分析层次。 | 难度: 在简答题的复杂分析题型中，该题目要求对低温恢复机制进行机理深度解释，涉及点缺陷的运动、湮灭和聚集等多个具体过程。虽然不需要全面分析复杂现象，但需要对材料科学中的微观机制有深入理解和准确描述，属于机理深度解释的难度等级。" + }, + { + "idx": 3257, + "question": "After high-temperature recovery, several edge dislocations form a subgrain boundary with a misorientation of $0.057^{\\\\circ}$. Assuming there is no interaction between these dislocations, what is the ratio of the distortion energy after forming the subgrain to the original energy? (Given the core radius of the dislocation $r_{0}\\\\approx$ $b\\\\approx10^{-8}\\\\mathrm{cm}$, and the effective radius of the dislocation stress field before forming the subgrain $R=10^{-4}\\\\mathrm{cm}$.)", + "answer": "Given the core radius of the dislocation $r_{0}=b\\\\approx10^{-8}~\\\\mathrm{cm}$ and the effective radius of the dislocation stress field $R=10^{-4}$ $\\\\mathrm{{cm}}$, since the total length of dislocations remains unchanged before and after forming the subgrain, the ratio of the energy per unit dislocation line before and after forming the subgrain is equal to the ratio of the energy before and after polygonization. The energy per unit dislocation line is $$ W_{E}=\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}\\\\ln\\\\frac{R}{r_{0}}=\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}\\\\ln10^{4} $$ After polygonization, the edge dislocations are arranged perpendicular to the slip plane with a spacing of $D$, so the effective radius of the dislocation $R$ becomes $D$. From the formula $R=D=\\\\frac{b}{\\\\theta}=\\\\frac{10^{-8}}{10^{-3}}=10^{-5}$, the energy per unit dislocation line after polygonization is $$ W_{E}^{\\\\prime}={\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}}\\\\cdot\\\\ln{\\\\frac{10^{-5}}{10^{-8}}}={\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}}\\\\cdot\\\\ln10^{3} $$ $$ \\\\frac{W_{E}^{\\\\prime}}{W_{E}}=\\\\frac{\\\\ln{10^{3}}}{\\\\ln{10^{4}}}=\\\\frac{3}{4} $$ This shows that after polygonization, the dislocation energy decreases, reducing the stored energy and also the driving force for recrystallization.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及能量比的计算，并给出了具体的计算步骤和公式推导。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联，如计算能量比和考虑位错排列的影响，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解位错能量计算的基本原理，应用多步公式推导，并进行对数运算和比例计算。虽然涉及的概念和计算步骤较多，但整体逻辑清晰，属于中等应用层次的计算题。" + }, + { + "idx": 3258, + "question": "Given that brass with a zinc mass fraction of 30% takes 1 hour to complete recrystallization at a constant temperature of 400°C, and 2 hours at 390°C, calculate how much time is needed to complete recrystallization at a constant temperature of 420°C.", + "answer": "Recrystallization of cold-deformed metal is also a thermally activated process, and the recrystallization rate follows the Arrhenius equation $$ V_{\\overline{{\\{\\}}}}=A^{\\prime}\\cdot\\mathrm{e}^{-Q/R T} $$ Since $V_{\\overrightarrow{\\vert\\overrightarrow{\\vert\\cdot}\\vert}}$ is inversely proportional to the time $\\scriptstyle t$ required to achieve a certain volume fraction $x_{\\upsilon}$, i.e., $V_{\\mathrm{\\#}}\\propto1/t$, we have $$ \\frac{1}{t_{1}}=A\\mathrm{e}^{-\\frac{Q}{R T_{1}}};\\frac{1}{t_{2}}=A\\mathrm{e}^{-\\frac{Q}{R T_{2}}};\\frac{1}{t_{3}}=A\\mathrm{e}^{-\\frac{Q}{R T_{3}}} $$ From the above three equations, dividing them pairwise yields $$ \\frac{t_{2}}{t_{1}}=\\mathrm{e}^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{2}}\\right)};\\quad\\frac{t_{3}}{t_{1}}=\\mathrm{e}^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{3}}\\right)} $$ Taking the natural logarithm and then dividing gives $$ \\frac{\\ln(t_{2}/t_{1})}{\\ln(t_{3}/t_{1})}=\\frac{1/T_{1}-1/T_{2}}{1/T_{1}-1/T_{3}} $$ Substituting $T_{1}=673~\\mathrm{K},t_{1}=1~\\mathrm{h};~T_{2}=663~\\mathrm{K},t_{2}=2~\\mathrm{h};~T_{3}=693~\\mathrm{K}$ into the above equation, we obtain $t_{3}=0.27$ h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来求解在特定温度下完成再结晶所需的时间。答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用Arrhenius方程进行温度和时间关系的推导，并进行数值计算。虽然不涉及复杂的机理分析或创新设计，但需要综合理解和应用热激活过程的基本原理。 | 难度: 在计算题中属于综合性计算问题，需要应用Arrhenius方程进行多步计算，涉及温度和时间的关系转换，以及对数运算。虽然计算步骤较多，但整体思路清晰，属于中等应用层次的计算题。" + }, + { + "idx": 3259, + "question": "How to prolong the lifespan of tungsten filaments by adding second-phase particles?", + "answer": "Finely dispersed high-melting-point second-phase particles can be added to the tungsten filaments. The second phase can effectively hinder grain growth, with the limiting grain size Dlim=4r/3f. When the particle size r is smaller and the volume fraction f of the added particles is larger, the limiting grain size becomes smaller, preventing the formation of large grains that span the filament. This mitigates grain boundary weakening at high temperatures, thereby preventing brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过添加第二相颗粒延长钨丝寿命，答案提供了详细的文字解释和论述，包括机制和影响因素，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释如何通过添加第二相颗粒延长钨丝寿命，涉及多步推理和机理解释，包括第二相颗粒对晶粒生长的阻碍作用、限制晶粒尺寸的计算公式（Dlim=4r/3f）以及高温下晶界弱化的缓解机制。这需要综合运用材料科学知识进行深入分析和解释。 | 难度: 在简答题题型中，该题目要求对钨丝寿命延长的机理进行深度解释，涉及第二相颗粒的添加、晶粒生长的阻碍以及晶界弱化的防止等多个方面的综合分析和推理。虽然题目没有要求全面分析复杂现象，但对机理的解释需要较高的知识掌握深度和逻辑推理能力，因此在简答题题型中属于等级4的难度。" + }, + { + "idx": 3260, + "question": "A factory was conducting solution treatment on the jaw plates of a crusher made of high manganese steel. After heating at 1100°C, the plates were suspended with cold-drawn steel wires and transported by a crane to the quenching water tank. During transportation, the steel wire suddenly broke. This wire was new and had no defects. Analyze the cause of the steel wire fracture.", + "answer": "Due to work hardening, the cold-drawn steel wire has high strength and strong load-bearing capacity. However, when heated by the red-hot jaw plate, once the temperature rises above $T_{\\overrightarrow{\\mathbb{H}}}$, recrystallization occurs, causing a decrease in strength. As a result, the wire can no longer bear the weight of the jaw plate, leading to fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢丝断裂的原因，答案提供了详细的文字解释和论述，涉及材料科学中的工作硬化、再结晶等概念，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要综合运用材料科学中的冷加工硬化、再结晶温度、强度变化等知识，分析高温环境下钢丝性能变化导致断裂的机理。涉及多概念关联和推理分析，思维过程较为复杂。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求分析冷拔钢丝断裂的原因，涉及多个知识点，包括冷加工硬化、高温下的再结晶现象、材料强度变化等。解题步骤较为复杂，需要综合运用材料科学知识进行推理分析，解释断裂的机理。此外，题目还要求考虑实际生产环境中的温度影响，进一步增加了分析的难度。因此，在简答题题型内，该题目属于最高难度等级。" + }, + { + "idx": 3261, + "question": "What is superplasticity?", + "answer": "When metallic materials are stretched under certain conditions, their elongation can reach over 200%, or even exceed 1000%. This property is called superplasticity. During superplastic deformation, the true stress-true strain conforms to the relation: σT(εT,T)=C·ε̇T^m, where m is called the strain rate sensitivity constant. When m=0.3-0.8, the material can exhibit superplasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"superplasticity\"这一概念进行文字解释和论述，答案提供了详细的定义和相关公式说明，符合简答题的特征 | 知识层次: 题目考查对超塑性这一基本概念的定义和特性的记忆和理解，涉及基本原理和简单公式的介绍，但不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释超塑性的定义，并简要描述其相关参数和条件，但不需要深入阐述复杂的理论体系或推导过程。虽然涉及一些公式和参数，但整体仍属于基础概念的记忆和理解范畴，符合等级2的要求。" + }, + { + "idx": 3262, + "question": "How to extend the life of tungsten wire by adding oxides of potassium, aluminum, silicon, etc.?", + "answer": "Adding oxides of potassium, aluminum, silicon, etc., which vaporize during sintering to form bubbles. During processing, these bubbles elongate along the direction of processing. These small bubbles distributed along the axial direction can also act as obstacles to grain boundary migration, allowing grains to grow only parallel to the axis of the tungsten wire. This results in elongated large grains along the axis, preventing the formation of large grains that span the cross-section of the tungsten wire, thereby improving high-temperature performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过添加氧化物延长钨丝寿命，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释通过添加氧化物延长钨丝寿命的机理，涉及多步过程（烧结、气泡形成、晶界迁移阻碍、晶粒生长控制等），需要综合运用材料科学知识进行推理分析，思维深度较高。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求解释如何通过添加钾、铝、硅等氧化物来延长钨丝的寿命，并详细描述其机理和效果。这需要综合运用材料科学的知识，理解烧结过程中的气泡形成、晶界迁移的阻碍作用以及晶粒生长的控制机制。此外，还需要推理分析这些现象如何共同作用以提高钨丝的高温性能。这种深度和广度的要求使得该题目在同题型内属于最高难度等级。" + }, + { + "idx": 3263, + "question": "How to achieve superplasticity?", + "answer": "Superplasticity can be divided into three categories: structural superplasticity, transformation superplasticity, and other types of superplasticity. Structural superplasticity should meet three conditions: (1) Ultra-fine, equiaxed, and stable grains, with grain size generally not exceeding 10μm. (2) Deformation temperature is typically in the range of (0.5∼0.7)Tm. (3) A certain strain rate, with the optimal superplastic deformation rate being 10^-4∼10^-2s^-1 or 10^-3∼10^-2min^-1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对超塑性（superplasticity）的实现方式进行解释和论述，答案提供了详细的分类和条件说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目不仅要求记忆超塑性的分类和基本条件，还需要理解并应用这些条件（如晶粒尺寸、变形温度、应变速率等）来解释如何实现超塑性。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆。 | 难度: 在简答题题型中，该题目要求对超塑性进行分类并详细说明结构超塑性的三个条件，涉及多个知识点的综合分析和论述。虽然不需要进行深度关联性分析，但需要对不同类别的超塑性有清晰的理解，并能系统性地阐述结构超塑性的具体要求，属于多角度分析论述的难度等级。" + }, + { + "idx": 3264, + "question": "As an economic measure, using pure lead instead of lead-tin alloy to make solder for brazing iron, how is the wettability of pure lead on iron?", + "answer": "The wettability of pure lead on iron is poor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释纯铅在铁上的润湿性，答案以文字形式给出解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对纯铅润湿性这一基本概念的记忆和理解，属于材料表面性能的基础知识范畴，不需要复杂的分析或计算过程。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆纯铅在铁上的润湿性表现即可回答，无需解释原理或进行复杂概念阐述。" + }, + { + "idx": 3265, + "question": "As an economic measure, using pure lead instead of lead-tin alloy to make solder for brazing iron, how does the melting point of pure lead compare to that of lead-tin alloy?", + "answer": "The melting point of pure lead is higher than that of Sn-Pb alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较纯铅和铅锡合金的熔点，并需要文字解释和论述，答案也是以文字形式给出，没有提供选项或要求计算。 | 知识层次: 题目考查的是纯铅和铅锡合金熔点比较的基础概念记忆，属于基本原理的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。虽然需要记忆纯铅和铅锡合金的熔点关系这一基础概念，但不需要进行复杂的体系阐述或深入分析。题目要求对两种材料的熔点进行比较并给出结论，属于对基本原理的记忆性知识应用，符合等级2的标准。" + }, + { + "idx": 3270, + "question": "What factors constitute the resistance to phase transformation?", + "answer": "The resistance to phase transformation consists of strain energy and interface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释构成相变阻力的因素，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查相变阻力的基本构成要素（应变能和界面能），属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释两个关键因素（应变能和界面能）并简要说明它们如何构成相变阻力，但不需要深入阐述复杂概念体系或进行多步骤分析。" + }, + { + "idx": 3272, + "question": "What are the main characteristics of diffusion-type phase transformations?", + "answer": "The fundamental characteristics of diffusion-type phase transformations are: $\\textcircled{1}$ Atomic diffusion occurs during the phase transformation, and the transformation rate is controlled by diffusion, i.e., determined by the diffusion speed. $\\textcircled{2}$ In alloy phase transformations, the compositions of the new phase and the parent phase are often different. $\\textcircled{3}$ There is only volume change caused by the difference in specific volume between the new phase and the parent phase, with no shape alteration. Phase transformations such as allotropic transformation in pure metals, polymorphic transformation in solid solutions, precipitation transformation, eutectoid transformation, spinodal decomposition, and ordering transformation all belong to diffusion-type phase transformations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散型相变的主要特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查扩散型相变的基本特征，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求对扩散型相变的主要特征进行全面阐述，涉及多个关键点（原子扩散、成分差异、体积变化等）以及具体相变类型的列举。这超出了简单定义或单一概念解释的范畴，属于需要整合多个知识点并进行系统论述的复杂概念体系阐述。在基础概念记忆层次中，这属于较高难度的题目类型。" + }, + { + "idx": 3273, + "question": "Explain the influence of crystal defects on the nucleation of solid-state phase transformations in metals.", + "answer": "During solid-state phase transformations, various crystal defects present in the parent phase, such as grain boundaries, dislocations, and vacancies, significantly promote the transformation. The new phase often preferentially nucleates at defect sites, and crystal defects have a substantial impact on processes such as nucleus growth and component diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体缺陷对金属固态相变成核的影响，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求解释晶体缺陷对固态相变成核的影响，涉及多个晶体缺陷类型（如晶界、位错、空位）与相变过程的相互作用，需要综合运用材料科学中的相变理论、缺陷理论和扩散理论进行推理分析，并解释其机理。这属于较高层次的认知能力，要求对多个知识点进行关联和综合分析。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求对晶体缺陷如何影响固态相变成核进行机理深度解释。虽然不涉及多因素交互作用的全面分析（等级5特征），但需要综合运用材料科学原理，说明不同缺陷类型（晶界/位错/空位）对成核过程的具体影响机制，并阐述其对核生长和扩散的作用原理。这超越了简单列举缺陷类型的描述（等级3），属于需要建立因果关系的机理解释层面。" + }, + { + "idx": 3274, + "question": "What is the actual grain size of austenite?", + "answer": "The size of austenite grains obtained under a specific heat treatment condition is generally referred to as the actual grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述\"actual grain size of austenite\"的概念，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对奥氏体实际晶粒尺寸这一基本概念的记忆和理解，属于材料科学中的基础概念范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答奥氏体实际晶粒尺寸的基本定义，属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单直接的记忆性知识考查。" + }, + { + "idx": 3275, + "question": "What is the reason for the formation of a 'precipitate-free zone' near grain boundaries in age-hardening alloys?", + "answer": "In the case of the decomposition of a supersaturated solid solution, when rapidly cooled from a high temperature, along with the solute atoms being supersaturatedly retained in the solid solution, a large number of supersaturated vacancies are also retained. These vacancies, on one hand, promote the diffusion of solute atoms and, on the other hand, act as nucleation sites for precipitates, facilitating heterogeneous nucleation and causing the precipitates to disperse throughout the matrix. When observing the distribution of precipitates in age-hardening alloys, a 'precipitate-free zone' is often seen near grain boundaries, where no precipitates are visible. This is because the supersaturated vacancies near the grain boundaries diffuse to the grain boundaries and disappear, so no heterogeneous nucleation or precipitation occurs in this region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释“precipitate-free zone”形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释\"precipitate-free zone\"的形成原因，涉及多个材料科学概念的关联和综合分析，包括过饱和固溶体的分解、空位的扩散、异质成核等机理。需要深入理解这些概念之间的相互作用，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对\"无沉淀区\"的形成机理进行全面分析，涉及多个关键概念的综合运用（如过饱和固溶体分解、空位扩散、异质形核等）。解题时需要系统性地解释空位在晶界处的消失如何导致局部区域沉淀抑制，并建立完整的因果链条。这种对复杂现象的多层次机理解释要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 3276, + "question": "What is the reason for the appearance of transition phases during the solid-state phase transformation of metals?", + "answer": "During solid-state phase transformations, metastable phases often form first to reduce surface energy, thus frequently resulting in transition phases. For example, when the undercooling is significant, the critical size for the formation of the new phase is very small, and the new phase per unit volume has a large surface area, so the interfacial energy poses a substantial barrier to nucleation. In such cases, transition phases with low interfacial energy and coherent interfaces are more likely to form to reduce the nucleation work and facilitate nucleation. An example is the ε-carbide in lower bainite in steel, which forms a coherent interface with the matrix. During the tempering of martensite in steel, to reduce the interfacial energy generated by carbide formation, ε-carbide, which is coherent with the martensite, forms as a transition phase at lower tempering temperatures. As the tempering temperature increases, the value of ΔG_B rises, and cementite, which is incoherent with the matrix, gradually forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对金属固态相变过程中过渡相出现的原因进行解释和论述，答案提供了详细的文字解释和例子，符合简答题的特征。 | 知识层次: 题目要求解释固态相变过程中过渡相出现的原因，涉及多个概念的综合运用（如表面能、临界尺寸、界面能、形核功等），需要深入理解相变机理，并结合具体例子（如钢中的ε-碳化物）进行分析和推理。这超出了简单记忆或基本应用的范围，属于复杂分析和机理解释的层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对金属固态相变中的过渡相形成机理进行全面分析，涉及多个复杂概念的综合运用（如表面能、临界尺寸、界面能、形核功等），并通过具体实例（ε-碳化物、马氏体回火过程）进行机理解释。题目不仅需要深入理解相变热力学和动力学原理，还要求能够将这些原理与具体材料现象联系起来，属于该题型下最高难度的复杂现象全面分析层级。" + }, + { + "idx": 3277, + "question": "What is the initial grain size of austenite?", + "answer": "In the heating transformation, when the transformation from pearlite to austenite has just been completed, the size of the austenite grains is called the initial grain size of austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释初始奥氏体晶粒尺寸的定义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对奥氏体初始晶粒尺寸这一基本概念的定义和记忆，属于基础概念的理解和复述，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答基础定义，属于最基础的概念记忆性知识。题目仅涉及\"初始晶粒尺寸\"这一单一概念的定义，不需要进行解释或论述复杂概念体系，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3278, + "question": "Describe the formation process of austenite", + "answer": "Austenite formation process: a) Formation of austenite nuclei; b) Growth of austenite nuclei; c) Dissolution of residual cementite; d) Homogenization of austenite composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述奥氏体的形成过程，需要文字解释和论述，答案给出了详细的步骤说明，符合简答题的特征。 | 知识层次: 题目考查对奥氏体形成过程的基本概念记忆，包括成核、生长、残余渗碳体溶解和成分均匀化等步骤，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目要求描述奥氏体的形成过程，涉及多个步骤的解释和描述，但不需要深入分析或复杂的概念体系阐述。属于概念解释和描述的难度等级。" + }, + { + "idx": 3280, + "question": "What is the inherent grain size of austenite?", + "answer": "According to the former national metallurgical industry standard, the grain size measured after heating the steel to 930°C ± 10°C, holding for 8 hours, and then cooling is called the inherent grain size. This grain size is used to indicate the tendency of austenite grain growth during heating.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是奥氏体的固有晶粒尺寸，答案提供了详细的定义和测量方法，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对奥氏体固有晶粒尺寸这一基本概念的记忆和理解，主要涉及定义和测量方法的描述，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"inherent grain size of austenite\"的定义和测量方法，需要考生回忆并组织相关概念知识，但不需要进行复杂的体系阐述或深入分析。这比简单定义回答（等级1）要求更高，但低于需要系统阐述多个相关概念的题目（等级3）。题目主要考察对特定冶金学概念的记忆和理解程度。" + }, + { + "idx": 3281, + "question": "Compare the differences in the microstructure transformation zones between the CCT diagram and TTT diagram of eutectoid carbon steel.", + "answer": "The CCT diagram of eutectoid carbon steel only has the high-temperature pearlite transformation zone and the low-temperature martensite transformation zone, without the intermediate-temperature bainite transformation zone. In the CCT diagram, the Ps curve (pearlite start transformation line) and Pf curve (pearlite finish transformation line) shift to the lower right.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较和分析两种微观结构转变区的差异，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求比较CCT图和TTT图的微观结构转变区域差异，涉及多个概念（珠光体、马氏体、贝氏体转变区）的关联和综合分析，需要理解不同冷却条件下相变的差异，并解释曲线移动的原因。这超出了简单记忆的范畴，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对CCT和TTT图的微观结构转变区进行多角度比较分析，涉及高温珠光体转变区、低温马氏体转变区以及贝氏体转变区的存在与否，还需要解释Ps和Pf曲线的移动方向。这需要学生不仅掌握相关概念，还要能够进行综合论述和比较，属于该题型中较高难度的题目。" + }, + { + "idx": 3282, + "question": "Why is the activation energy for atoms crossing an incoherent interface much smaller than that for crossing a semicoherent interface?", + "answer": "$u=\\delta V_{0}\\mathrm{exp}\\big(-\\Delta\\mathrm{G/kT}\\big)$. For an incoherent interface, the $\\Delta G$ value equals the activation energy for grain boundary diffusion; whereas for a semicoherent interface, it can be considered roughly equal to the activation energy of atoms in the $\\beta$ phase (actually slightly smaller). Therefore, the activation energy for atoms crossing an incoherent interface is much smaller than that for crossing a semicoherent interface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么非共格界面的原子跨越激活能比半共格界面小，答案提供了详细的文字解释和理论依据，属于需要论述的简答题类型。 | 知识层次: 题目需要综合运用材料科学中的界面理论、扩散机制和热力学知识，进行推理分析和机理解释。涉及不同界面类型（非共格和半共格）的扩散激活能差异，需要深入理解界面结构与扩散行为的关系，并进行比较分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解激活能的概念，还需要分析不同类型界面（非共格界面和半共格界面）对原子扩散的影响机制。解题过程中需要综合运用材料科学中的界面理论、扩散理论和热力学知识，解释为什么非共格界面的激活能远小于半共格界面。虽然题目给出了公式提示，但需要考生深入理解公式中各参数的物理意义及其在不同界面条件下的差异，这体现了对知识点的深度掌握和机理分析能力的要求。" + }, + { + "idx": 3283, + "question": "What is the significance of the TTT diagram for eutectoid carbon steel in practical heat treatment?", + "answer": "The isothermal transformation C-curve (TTT curve) can determine the process parameters during isothermal heat treatment of steel, namely the isothermal temperature, isothermal time, and the microstructure after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释TTT图的实际意义，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求解释TTT图在实际热处理中的意义，涉及对等温热处理过程参数（温度、时间）和最终显微组织的综合分析，需要将基础概念与实际应用相结合，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然需要解释TTT图的实际应用意义，但主要涉及单一知识点的综合说明（如确定等温热处理参数），不需要多角度或深度关联性分析。解题步骤为：1) 明确TTT图定义 2) 说明其在热处理中的具体应用 3) 总结微观组织关系，符合该题型对\"综合分析和说明\"的要求。" + }, + { + "idx": 3284, + "question": "Methods for controlling austenite grain size", + "answer": "Methods for controlling austenite grain size: a) Establish appropriate heating specifications, including controlling heating temperature and holding time, rapid short-term heating; b) Control carbon content within a certain range and add a certain amount of alloying elements that hinder austenite grain growth, such as: Al, V, Ti, Zr, Nb, etc.; c) Consider the influence of the original microstructure, such as lamellar pearlite being more prone to coarsening than spheroidized pearlite during heating.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释控制奥氏体晶粒尺寸的方法，答案提供了详细的文字解释和论述，没有选项、判断或计算要求。 | 知识层次: 题目要求解释控制奥氏体晶粒尺寸的方法，涉及多个控制因素（加热规范、合金元素、原始组织）的综合应用，需要理解各因素的作用机制并关联实际工艺，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目要求多角度分析论述控制奥氏体晶粒尺寸的方法，涉及加热规范、合金元素添加和原始组织影响等多个方面。虽然不需要深度关联性分析，但需要综合运用材料科学知识进行较为全面的解释，属于中等应用层次中较高难度的题目。" + }, + { + "idx": 3285, + "question": "Under what conditions can austenite transform into lamellar pearlite?", + "answer": "When the austenitizing temperature is high, the holding time is long, the composition of austenite is uniform, and the cooling rate is fast, lamellar pearlite is prone to form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么条件下奥氏体会转变为层状珠光体，答案需要文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目需要理解奥氏体向层状珠光体转变的条件，涉及多个因素的关联分析（温度、时间、成分均匀性和冷却速率），属于中等应用层次的知识点。虽然不需要复杂的计算或深度机理分析，但需要对材料科学中的相变过程有较好的理解和综合应用能力。 | 难度: 在简答题中属于中等难度，需要综合理解奥氏体转变为层状珠光体的条件，包括温度、时间、成分均匀性和冷却速率等多个因素，并进行简要说明和论述。虽然涉及多个概念，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 3286, + "question": "What is pearlite interlamellar spacing?", + "answer": "The distance between the centers of two adjacent cementite (or ferrite) plates in lamellar pearlite, or the total thickness of a pair of ferrite and cementite plates, is called pearlite interlamellar spacing, denoted as S0.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"pearlite interlamellar spacing\"的定义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对珠光体片层间距这一基本概念的定义和记忆，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆性知识。题目明确要求解释\"pearlite interlamellar spacing\"的定义，答案直接给出了该术语的标准定义和表示符号，不需要额外的解释或论述。这符合等级1\"基本定义简答\"的标准，是同类题型中最简单的类型。" + }, + { + "idx": 3287, + "question": "What are the main characteristics of diffusionless phase transformations?", + "answer": "Characteristics of diffusionless phase transformations: $\\textcircled{1}$ There is a shape change caused by uniform shear, as the atoms undergo collective coordinated motion during the phase transformation, resulting in a change in the crystal's external shape. If a polished specimen surface is prepared in advance, a relief effect will appear on the polished surface after this transformation occurs. The presence of this relief can be observed under a metallographic microscope. $\\textcircled{2}$ The phase transformation does not require diffusion, and the chemical composition of the new phase is the same as that of the parent phase. $\\textcircled{3}$ There is a specific crystallographic orientation relationship between the new phase and the parent phase. $\\textcircled{4}$ The phase boundary moves extremely fast, approaching the speed of sound. The martensitic transformation in steel and some alloys (Fe-Ni, Cu-Al, Ni-Ti) is a diffusionless phase transformation. Some pure metals (such as zirconium, titanium, lithium, cobalt) also undergo diffusionless phase transformations during allotropic transformations at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散无相变的主要特征，答案以文字论述形式给出，详细描述了多个特征点，符合简答题的特点。 | 知识层次: 题目要求解释扩散相变的主要特征，涉及多个方面的综合分析，包括形状变化、无扩散特性、晶体学取向关系以及相变速度等。这些内容不仅需要记忆和理解，还需要将多个概念关联起来进行综合分析，解释其背后的机理和现象。此外，题目还提到了具体的应用实例（如钢中的马氏体相变），进一步增加了分析的复杂性。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求详细解释扩散less相变的主要特征，涉及多个复杂概念的综合运用，如均匀剪切导致的形状变化、无扩散过程、特定晶体学取向关系以及相界移动速度等。此外，还需要举例说明实际应用（如钢中的马氏体相变），这要求考生不仅理解机理，还能进行综合分析和实际应用举例。因此，在简答题题型中，该题目属于最高难度等级。" + }, + { + "idx": 3288, + "question": "What is martensite?", + "answer": "The supersaturated solid solution formed by carbon in α-Fe is called martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"martensite\"进行定义和解释，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即马氏体的定义，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆。题目仅涉及单一术语的定义，不需要解释或描述相关概念，也不涉及复杂概念体系的阐述。因此，在同题型和知识层次下，该题目属于等级1难度。" + }, + { + "idx": 3289, + "question": "What is the significance of the CCT diagram of eutectoid carbon steel in practical heat treatment?", + "answer": "The CCT curve can determine the heat treatment process parameters of steel during continuous cooling, such as the critical quenching cooling rate, quenching medium, and microstructure after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释CCT图的实际意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求理解CCT图的实际应用，涉及热处理工艺参数的确定和显微组织的关联分析，需要多步概念关联和综合分析能力。 | 难度: 在简答题题型中，该题目要求考生不仅理解CCT图的基本概念，还需要能够将其与实际热处理工艺参数（如临界淬火冷却速率、淬火介质选择）和最终显微组织关联起来。这需要考生具备多角度分析能力，能够将理论知识综合应用到实际场景中，属于中等应用层次中较高难度的题目。" + }, + { + "idx": 3290, + "question": "What is the effect of pearlite interlamellar spacing and pearlite colonies on mechanical properties?", + "answer": "The lower the formation temperature, the smaller the size of pearlite colonies and interlamellar spacing, the finer the pearlite structure, and the higher the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释珠光体层间距和珠光体团对机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释珠光体片层间距和珠光体团对力学性能的影响，涉及多个概念（珠光体结构、力学性能）的关联和综合分析，需要理解温度对微观结构的影响及其与宏观性能的关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解珠光体层间距和珠光体团对机械性能的影响，还需要综合分析温度、组织细化与强度之间的关系。这涉及到多步概念关联和综合分析，属于中等应用层次中较高难度的题目。虽然不需要进行深度关联性分析（如涉及更复杂的材料系统或极端条件），但已经超出了基础概念解释的范畴，需要考生展示较强的知识整合能力。" + }, + { + "idx": 3291, + "question": "What are the main characteristics of various types of solid-state phase transformations in metals?", + "answer": "
Classification of solid-state phase transformationsCharacteristics of phase transformations
Allotropic transformation in pure metalsChanges from one crystal structure to another with temperature or pressure variation, involving nucleation and growth processes
Polymorphic transformation in solid solutionsSimilar to allotropic transformation, such as Y in Fe-Ni alloys
Precipitation transformationDecomposition of supersaturated solid solutions, precipitating metastable or stable secondary phases
Eutectoid transformationA single phase decomposes into two phases with different structures through eutectoid transformation, such as Y→α+FeC in Fe-C alloys
Peritectoid transformationTwo phases with different structures transform into another phase through peritectoid transformation, such as α+Y→β in Ag-Al alloys, often leaving residual α phase
Martensitic transformationNo change in composition between the new and old phases during transformation; atoms undergo coordinated rearrangement (shear) without diffusion, maintaining strict orientation relationships and coherency, with surface relief effects observable on polished surfaces
Massive transformationChanges in crystal structure of metals or alloys without composition change between new and old phases, characterized by nucleation and growth with minimal diffusion, rapid growth via incoherent interface migration, producing irregular massive products, as seen in pure iron, low-carbon steel, Cu-Al alloys, and Cu-Ga alloys
Bainitic transformationOccurs in steel and many non-ferrous alloys, combining features of martensitic and diffusional transformations, resulting in composition changes; in steel, bainitic transformation is considered to proceed via coherent shear of iron atoms and diffusion of carbon atoms
Spinodal decompositionA non-nucleation decomposition process where a solid solution decomposes into two phases with the same crystal structure but different compositions (continuously varying within a certain range)
Order-disorder transformationTransition of alloy elements from random to ordered arrangement without structural change
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释各种固态相变的主要特征，需要详细的文字描述和论述，答案以表格形式呈现了不同类型相变的特征说明，符合简答题的特点。 | 知识层次: 题目要求对不同类型的固态相变进行分类并解释其特点，涉及多个相变类型的关联和综合分析，需要理解各种相变的基本原理和特征，并进行比较和归纳。虽然包含记忆性内容，但更强调对概念的理解和应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对多种固态相变类型进行详细描述和特征分析，涉及多个复杂概念的综合运用和关联。虽然不需要进行深度关联性分析（等级5），但需要多角度论述不同相变类型的特征，属于较高难度的综合分析题。" + }, + { + "idx": 3292, + "question": "Under what conditions can austenite transform into granular pearlite?", + "answer": "When the austenitizing temperature is low, the holding time is short, the heating transformation is incomplete, the composition of austenite is non-uniform, and subsequently during cooling, the pearlite transformation isothermal temperature is high, the isothermal time is sufficiently long, or the cooling rate is extremely slow, granular pearlite is prone to form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在什么条件下奥氏体会转变为粒状珠光体，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释奥氏体转变为粒状珠光体的具体条件，涉及多个因素的相互作用和转变机理的分析，需要综合运用材料科学中的相变知识和热力学原理，进行推理和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用多个材料科学原理（如奥氏体化条件、珠光体转变机制、等温时间与冷却速率的关系），并需要系统性地解释非均匀成分、不完全相变等复杂现象的交互作用。解题步骤涉及多变量条件分析和机理解释，属于该题型框架内对综合分析和深度机理要求最高的难度等级。" + }, + { + "idx": 3293, + "question": "What is a pearlite colony?", + "answer": "In lamellar pearlite, the region where ferrite and cementite are alternately arranged in layers with roughly the same orientation is called a pearlite colony or pearlite nodule.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"pearlite colony\"的概念，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对珠光体团（pearlite colony）这一基本概念的定义和描述，属于材料科学中相变和显微组织的基础知识，主要依赖记忆和理解，不涉及复杂应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释珍珠岩团的定义，但仅涉及基本概念的记忆和简单描述，不需要复杂的体系阐述或多步骤推理。属于该题型中对基础概念掌握程度的常规考查。" + }, + { + "idx": 3295, + "question": "What factors influence the interlamellar spacing of pearlite and the pearlite colony?", + "answer": "They are mainly influenced by the formation temperature of pearlite. The lower the temperature, the smaller the pearlite colony size and the smaller the interlamellar spacing of pearlite, such as S0=8.02/ΔGT×10^3(nm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响珠光体片层间距和珠光体团尺寸的因素，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要理解珠光体片层间距和珠光体团尺寸的基本概念，还需要应用温度变化对它们的影响规律，并涉及公式的应用和综合分析。这属于中等应用层次，需要将多个概念关联起来进行分析。 | 难度: 在简答题题型中，该题目要求考生不仅理解珍珠体的层间距和团簇尺寸的影响因素，还需要能够解释温度变化对这些参数的具体影响，并引用公式进行说明。这涉及到多步计算和概念关联，属于中等应用层次中的较高难度。虽然不需要进行深度关联性分析，但需要多角度分析论述，因此评为等级4。" + }, + { + "idx": 3296, + "question": "Compare the diffusivity during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, both iron and carbon atoms can diffuse; in bainitic transformation, carbon atoms diffuse while iron atoms do not; in martensitic transformation, neither iron nor carbon atoms diffuse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对不同相变过程中的扩散性进行比较和解释，答案以文字论述形式给出，没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目要求比较三种不同相变过程中的扩散性，涉及对扩散机制的理解和不同相变过程特点的综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求比较三种相变过程中的扩散性，但主要考察的是对基本概念的理解和简单对比，不需要进行多角度或深度关联性分析。解题步骤相对直接，只需分别说明每种相变中碳原子和铁原子的扩散情况即可。" + }, + { + "idx": 3297, + "question": "Is the statement that the strength and hardness of martensite mainly depend on the mass fraction of carbon correct? Why?", + "answer": "Incorrect. The hardness of martensite primarily depends on the carbon content (mass fraction), but the strength of martensite not only depends on its hardness but also on the morphology of martensite and the size of martensite laths (or plates).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，并解释原因。答案明确指出了陈述的部分正确性，并提供了详细的解释。 | 知识层次: 题目不仅需要理解马氏体的硬度和强度与碳含量的关系，还需要分析马氏体形态和板条尺寸对强度的影响，涉及多个概念的关联和综合分析。 | 难度: 在判断题中属于较高难度，不仅需要判断陈述的对错，还需要综合分析多个因素（碳含量、马氏体形态、板条尺寸）对强度和硬度的不同影响，涉及多步概念关联和结果判断。" + }, + { + "idx": 3298, + "question": "Compare the formation temperatures of bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "Pearlitic transformation occurs in the high-temperature region (below A), bainitic transformation occurs in the medium-temperature region (below B), and martensitic transformation occurs in the low-temperature region (below Ms).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较三种相变的形成温度，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对三种相变温度范围的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较三种相变的形成温度范围，需要考生掌握并准确描述珠光体相变、贝氏体相变和马氏体相变各自发生的温度区间（高温区、中温区和低温区）。虽然涉及多个概念，但不需要深入分析相变机理或建立复杂的概念体系，主要考察基础概念的记忆和简单对比能力。" + }, + { + "idx": 3299, + "question": "Compare the transformation processes and leading phases of bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "The leading phase of pearlitic transformation is FeC, the leading phase of bainitic transformation is the a phase, and the leading phase of martensitic transformation is not clearly specified.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三种不同的相变过程及其主导相，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求比较三种不同的相变过程及其主导相，涉及多个概念的关联和综合分析，需要理解每种相变的基本原理和特点，并进行对比分析。虽然不涉及复杂的计算或深度推理，但需要一定的知识整合能力。 | 难度: 在简答题题型中，该题目要求对三种不同的相变过程（贝氏体、珠光体和马氏体）的转变过程和主导相进行比较分析。这需要考生不仅掌握每种相变的基本概念，还需要理解它们之间的差异和联系。题目涉及的知识点较为深入，需要多角度分析论述，包括相变机制、主导相的形成条件等。虽然不需要进行深度关联性分析（如与材料性能的具体关联），但综合分析和说明的要求较高，因此属于等级4难度。" + }, + { + "idx": 3300, + "question": "Compare the coherency during the transformations of bainite, pearlite, and martensite", + "answer": "Pearlite transformation has no coherency, while bainite and martensite transformations have shear coherency and produce surface relief.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较贝氏体、珠光体和马氏体相变过程中的共格性，需要文字解释和论述不同相变过程的共格性特点，答案也是以文字形式给出解释。 | 知识层次: 题目要求比较贝氏体、珠光体和马氏体相变过程中的共格性，这需要深入理解不同相变机制的微观过程及其差异。不仅需要记忆各种相变的基本特征，还需要分析相变过程中的晶体学变化和界面特性，涉及多个概念的关联和综合运用。此外，答案中提到的剪切共格性和表面浮雕效应需要机理层面的解释，体现了较高的认知层次和思维深度。 | 难度: 在简答题题型中，该题目要求对三种不同相变的共格性进行对比分析，涉及机理层面的解释。虽然不需要全面分析复杂现象（如等级5的要求），但需要深入理解相变过程中的共格性差异及其产生的原因，属于机理深度解释的范畴。" + }, + { + "idx": 3301, + "question": "Compare the lattice shear during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "Pearlitic transformation involves no lattice shear, while bainitic transformation and martensitic transformation involve lattice shear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较三种相变过程中的晶格剪切现象，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求比较三种相变过程中的晶格剪切现象，涉及多个概念（bainitic、pearlitic、martensitic transformation）的关联和综合分析，需要理解相变机制并能够区分不同相变类型的特征。这超出了单纯记忆基础概念的层次，但尚未达到需要深度推理或创新应用的复杂分析或高级综合层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较三种相变过程中的晶格剪切现象，但答案相对直接，只需明确区分珠光体相变无晶格剪切，而贝氏体和马氏体相变涉及晶格剪切。不需要深入的多角度分析或复杂的关联性论述，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3302, + "question": "Is the statement that the plasticity and toughness of martensite mainly depend on its substructure correct? Why?", + "answer": "Yes. The plasticity and toughness of martensite mainly depend on its substructure.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个陈述的正确性（\"Is the statement...correct?\"），并且答案直接给出了对错判断（\"Yes\"）和简要解释，这符合判断题的特征。 | 知识层次: 题目要求分析马氏体的塑性和韧性与其亚结构的关系，这需要深入理解马氏体的微观结构及其对力学性能的影响机制。不仅需要记忆马氏体的基本特性，还需要综合分析亚结构（如位错密度、孪晶等）如何具体影响其塑性和韧性，属于机理层面的解释和推理分析。 | 难度: 在判断题的机理解释正误判断类型中，该题目属于较高难度。题目不仅要求判断陈述的对错，还需要理解马氏体的塑性及韧性与其亚结构的关系这一较为复杂的材料科学机理。这需要综合运用材料科学知识，进行推理分析，才能正确判断并解释原因。因此，在同题型内属于等级4的难度。" + }, + { + "idx": 3303, + "question": "What is the microstructural transformation of quenched steel during tempering at 20-100°C?", + "answer": "Carbon segregation in martensite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在20-100°C回火过程中的微观结构转变，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及淬火钢在回火过程中的微观结构转变，需要理解马氏体中碳的偏聚现象，并关联回火温度范围与微观结构变化的关系。虽然不涉及复杂计算，但需要对材料科学中的相变和扩散机制有中等程度的理解和应用能力。 | 难度: 在简答题中属于中等难度，需要理解淬火钢在回火过程中的微观结构转变，并能够解释碳在马氏体中的偏聚现象。虽然题目涉及的概念较为基础，但需要学生能够将理论知识与实际应用相结合，进行一定的综合分析。" + }, + { + "idx": 3304, + "question": "Compare the distribution of alloying elements in bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, alloying elements are redistributed through diffusion, while in bainitic transformation and martensitic transformation, alloying elements do not diffuse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同相变过程中合金元素的分布进行比较和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目要求比较三种不同相变过程中合金元素的分布情况，涉及对扩散行为的理解和不同相变机制的综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和比较，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要比较三种不同的相变过程（珠光体、贝氏体、马氏体）中合金元素的分布情况，并解释扩散行为的不同。这要求对相变机制有深入理解，并能进行多角度分析论述。虽然不需要深度关联性分析（如与材料性能的关联），但仍需综合多个概念并进行比较说明。" + }, + { + "idx": 3305, + "question": "Compare the mechanical properties of upper bainite and lower bainite", + "answer": "Generally, the hardness and strength of lower bainite are higher than those of upper bainite, and the plasticity and toughness of lower bainite are also higher than those of upper bainite. Lower bainite has good comprehensive mechanical properties and better toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较上贝氏体和下贝氏体的力学性能，需要文字解释和论述，答案也是以文字形式详细说明了两者的性能差异，符合简答题的特征。 | 知识层次: 题目要求比较上贝氏体和下贝氏体的力学性能，需要理解两种组织的形成机制及其对性能的影响，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求比较两种贝氏体的机械性能，但答案主要涉及基本概念的对比和简单结论的陈述，不需要深入的多角度分析或复杂的关联性论证。解题步骤主要是回忆和列举两种贝氏体的性能差异，属于典型的综合分析说明类简答题。" + }, + { + "idx": 3306, + "question": "Compare the hardness of the transformation products of bainite transformation, pearlite transformation, and martensite transformation", + "answer": "The pearlite transformation product has low hardness, the bainite transformation product has medium hardness, and the martensite transformation product has high hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对不同相变产物的硬度进行比较和描述，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对不同相变产物硬度特性的基础概念记忆和简单比较，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要比较三种不同转变产物的硬度，但主要考察的是对基础概念的记忆和理解，不需要复杂的分析或阐述。题目要求的知识点相对明确，解题步骤较为直接，属于该题型中的中等难度。" + }, + { + "idx": 3307, + "question": "What is the microstructural transformation of quenched steel during tempering at 250-400°C?", + "answer": "Transformation of carbides", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在250-400°C回火时的微观结构转变，需要文字描述和论述，答案形式为简短的文字解释（Transformation of carbides），而非选择、判断或计算。 | 知识层次: 题目考查对淬火钢回火过程中微观结构转变的理解和应用，需要将温度范围与碳化物转变相关联，属于中等应用层次的知识。虽然不涉及复杂计算，但需要综合分析温度区间与相变的关系，比单纯记忆基础概念要求更高。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及的是材料科学中较为基础的热处理知识，但需要考生理解并解释淬火钢在回火过程中的微观结构转变，特别是碳化物的转变。这要求考生不仅掌握相关概念，还需要能够进行一定的综合分析，将理论知识与实际应用相结合。然而，题目并未要求多角度或深度关联性分析，因此难度等级为3。" + }, + { + "idx": 3308, + "question": "Compare the microstructures of the transformation products of bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "The product of pearlitic transformation is a+FeC (lamellar), the product of upper bainitic transformation is y→a+FeC (non-lamellar), the product of lower bainitic transformation is Ya+e-carbide (non-lamellar), and the two most typical products of martensitic transformation are lath-shaped and plate-shaped.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较不同转变产物的微观结构，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较不同相变产物的显微结构，涉及多个相变过程的概念关联和综合分析，需要理解并应用相变的基本原理，但不需要进行复杂的推理或创新性思考。 | 难度: 在简答题中属于较高难度，需要综合分析和比较三种不同的相变产物（贝氏体、珠光体和马氏体）的微观结构特征。题目要求不仅描述各自的产物形态（如层状、非层状、板条状等），还需要理解不同相变过程的本质差异。这涉及多步概念关联和综合分析能力，属于中等应用层次中较复杂的题目。" + }, + { + "idx": 3309, + "question": "Compare the completeness of isothermal transformation for bainite transformation, pearlite transformation, and martensite transformation", + "answer": "Pearlite transformation can be completely transformed, some bainite transformations can be completely transformed while others cannot, and martensite transformation cannot be completely transformed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对不同类型转变的完整性进行比较和解释，答案以文字论述形式给出，没有固定选项或简单对错判断，符合简答题的特征。 | 知识层次: 题目要求比较三种相变（贝氏体、珠光体、马氏体）的等温转变完整性，需要理解每种相变的基本原理和特点，并进行综合分析。这涉及到多步概念关联和比较，而不仅仅是简单的记忆或直接套用。 | 难度: 在简答题中属于中等难度，需要对三种相变（贝氏体、珠光体、马氏体）的等温转变完整性进行比较分析。题目要求综合运用相变动力学知识，但不需要深入探讨微观机制或进行多角度论述。解题步骤涉及基本概念关联和简单对比，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3310, + "question": "Explain the application of upper bainite and lower bainite in production", + "answer": "a) Isothermal quenching of bainite (lower bainite) is often used to replace quenching + low-temperature tempering; b) Ultra-high strength steel obtains a composite structure of bainite (lower) + martensite to achieve the best combination of strength and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释上贝氏体和下贝氏体在生产中的应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释上贝氏体和下贝氏体在生产中的应用，涉及对贝氏体形成条件、性能特点的理解，以及如何根据需求选择不同类型的贝氏体。需要将概念与实际生产应用相结合，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对上下贝氏体的应用进行多角度分析论述。需要理解贝氏体的形成条件、性能特点，并结合实际生产中的热处理工艺（如等温淬火）和材料设计（如超高强度钢的复合组织）进行综合分析。虽然不涉及深度关联性分析（如微观机制与宏观性能的定量关联），但需要展示对多个相关概念的掌握和应用能力，属于该题型内较高难度的题目。" + }, + { + "idx": 3311, + "question": "What is the microstructure transformation of quenched steel during tempering at 100-250°C?", + "answer": "Decomposition of martensite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在100-250°C回火时的微观结构转变，需要文字解释和论述，答案\"Decomposition of martensite\"是一个简短的文字描述而非选择或判断。 | 知识层次: 题目考查对淬火钢在回火过程中微观结构转变的理解，需要将马氏体分解的概念与特定温度范围（100-250°C）联系起来，属于中等应用层次。这需要一定的概念关联和综合分析能力，而不仅仅是基础概念的记忆。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及具体的温度范围（100-250°C）和明确的相变过程（马氏体分解），但答案相对直接且不需要多角度分析或深度关联其他复杂概念。学生需要掌握马氏体在回火过程中的基本转变知识，并能准确描述这一特定温度范围内的微观结构变化。解题步骤较为简单，主要考察对基础概念的理解和准确表述能力，不需要进行复杂的综合分析或多步骤推理。" + }, + { + "idx": 3312, + "question": "What is the microstructural transformation of quenched steel during tempering at 200-300°C?", + "answer": "Transformation of retained austenite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在200-300°C回火时的微观结构转变，答案需要文字描述和论述，而不是选择、判断或计算 | 知识层次: 题目考查对淬火钢在回火过程中微观结构转变的理解，需要将回火温度范围与具体的相变过程（残余奥氏体转变）联系起来，属于中等应用层次的知识。这需要学生不仅记住基础概念，还要理解温度与相变的关系，并进行简单的综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及具体的微观结构转变（残余奥氏体转变），但只需要单一知识点的解释和论述，不需要多角度或深度关联性分析。解题步骤相对简单，主要考察对特定温度区间回火过程中钢的微观结构变化的理解和描述能力。" + }, + { + "idx": 3313, + "question": "What is temper brittleness?", + "answer": "When some steels are tempered within a certain temperature range, their impact toughness significantly decreases compared to being tempered at lower temperatures. This embrittlement phenomenon is called temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"temper brittleness\"进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即回火脆性的定义和基本现象，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。题目明确询问\"什么是回火脆性\"，答案只需给出定义性描述，无需展开解释或涉及复杂概念体系。这符合等级1\"基本定义简答\"的标准，是同类题型中最简单的类型。" + }, + { + "idx": 3314, + "question": "What is the microstructure transformation of quenched steel during tempering at 400-600°C?", + "answer": "Cementite aggregation and growth, and recovery and recrystallization of α phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释淬火钢在400-600°C回火过程中的微观结构转变，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释淬火钢在400-600°C回火过程中的微观结构转变，涉及多个相变过程（渗碳体聚集与长大、α相回复与再结晶）的机理分析，需要综合运用相变动力学、晶体缺陷和显微组织演变等知识进行深入解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅了解淬火钢在回火过程中的微观结构变化，还需要详细解释渗碳体的聚集和生长以及α相的回复和再结晶过程。这需要考生具备扎实的材料科学基础知识和综合运用能力，能够将多个知识点联系起来进行推理分析。虽然题目没有要求全面分析复杂现象，但对机理的解释深度要求较高，因此在简答题题型中属于等级4难度。" + }, + { + "idx": 3315, + "question": "Describe the microstructure type, obtaining conditions, characteristics, and mechanical properties of medium-temperature tempered steel", + "answer": "Medium-temperature tempering Tempered troostite 350-500°C High elastic limit", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述中温回火钢的微观结构类型、获得条件、特征和机械性能，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了多个方面的信息，符合简答题的特征。 | 知识层次: 题目要求描述中温回火钢的微观结构类型、获得条件、特征和力学性能，涉及多个知识点的关联和综合分析，需要理解回火温度与组织性能的关系，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明多个知识点，包括微观结构类型、获得条件、特征和力学性能，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3316, + "question": "Describe the types of low-temperature tempered structures in steel, the conditions for obtaining them, their structural characteristics, and mechanical properties", + "answer": "Low-temperature tempering Tempered martensite 150-250°C High hardness, high wear resistance", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述钢中低温回火组织的类型、获得条件、结构特征和机械性能，需要详细的文字解释和论述，而不是选择、判断或计算。答案提供了简要的信息，但完整的回答需要更详细的描述。 | 知识层次: 题目要求描述低温回火组织的类型、获得条件、结构特征和力学性能，涉及多个知识点的关联和综合分析，需要理解不同条件对组织性能的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对低溫回火钢的结构类型、获得条件、结构特征和机械性能进行多角度分析论述。需要综合多个知识点，包括热处理工艺条件、显微组织特征和性能关联性，并能够系统性地阐述这些要素之间的关系。相较于只需简单说明的题目，该题目对知识整合和逻辑表达能力的要求更高，属于该题型中较难的题目。" + }, + { + "idx": 3317, + "question": "Describe the microstructure type, obtaining conditions, characteristics, and mechanical properties of steel after high-temperature tempering", + "answer": "High-temperature tempering Tempered sorbite 500-650℃ Good combination of strength and toughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述高温回火后钢的微观结构类型、获得条件、特征和机械性能，需要文字解释和论述，答案也以简短的文字形式呈现。 | 知识层次: 题目要求描述高温回火后钢的微观结构类型、获得条件、特征和力学性能，涉及多个概念的综合应用和分析，需要理解不同条件对钢性能的影响，并进行关联性描述。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要描述多个方面的内容（微观结构类型、获得条件、特征和机械性能），但这些内容在材料科学中属于基础知识点，且题目已经给出了明确的框架（高温回火后的钢）。回答时需要综合分析和说明，但不需要进行多角度或深度关联性分析。因此，在简答题题型中属于等级3的难度。" + }, + { + "idx": 3318, + "question": "Compare the approximate diffusion distances/mm of carbon atoms during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, the diffusion distance of carbon atoms is greater than 10mm; in bainitic transformation, the diffusion distance of carbon atoms is 0~10mm; in martensitic transformation, the diffusion distance of carbon atoms is 0mm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较不同相变过程中碳原子的扩散距离，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较不同相变过程中碳原子的扩散距离，涉及对珠光体、贝氏体和马氏体相变过程的理解，需要综合分析不同相变机制对扩散距离的影响。虽然不涉及复杂计算，但需要对多个概念进行关联和比较，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并比较三种不同相变过程中碳原子的扩散距离。题目要求综合分析不同相变过程的扩散特性，但不需要进行多角度或深度关联性分析。解题步骤相对直接，主要是对已知概念的应用和比较。" + }, + { + "idx": 3319, + "question": "Indicate the main purpose of normalizing 20 steel gears and the microstructure after normalizing", + "answer": "Normalizing of 20 steel: improve machinability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释正常化处理20钢齿轮的主要目的以及处理后的显微组织，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对20钢正火处理的主要目的及其微观结构的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。虽然需要回答两个部分（目的和微观结构），但都属于基础概念记忆层次，不需要复杂的分析或推理。题目要求的知识点相对明确，属于对基本原理的记忆性回答，没有涉及复杂概念体系的阐述或深入分析。" + }, + { + "idx": 3320, + "question": "Explain the factors affecting the depth of the hardened layer.", + "answer": "The depth of the hardened layer is related to factors such as the hardenability of the steel, the size of the workpiece, and the cooling capacity of the quenching medium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响硬化层深度的因素，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响硬化层深度的因素，涉及多个概念（钢的淬透性、工件尺寸、淬火介质冷却能力）的关联和综合分析，需要理解这些因素之间的相互作用，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明多个因素（如钢的淬透性、工件尺寸和淬火介质的冷却能力）对硬化层深度的影响，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3321, + "question": "Indicate the main purpose of normalizing T12 steel file and the structure after normalizing", + "answer": "T12 steel file: Normalizing eliminates the network carbide and prepares for spheroidizing annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释T12钢文件的主要正火目的及正火后的结构，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释T12钢正火的主要目的和正火后的组织，这需要理解正火工艺的基本原理及其对钢组织的影响，涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解T12钢正火的主要目的和后续组织变化，并进行综合分析说明。题目要求解释正火的作用（消除网状碳化物）和后续处理（为球化退火做准备），涉及多步概念关联，但不需要过于深入的多角度分析或深度关联性分析。" + }, + { + "idx": 3322, + "question": "What is the hardenability of steel?", + "answer": "The hardenability of steel refers to the ability of steel to obtain martensite during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"hardenability of steel\"进行解释，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即钢的淬透性的定义，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求回答基础定义，属于最基础的概念记忆层次。不需要展开解释或描述复杂概念体系，仅需直接复述钢的淬透性定义即可。在同题型内属于最简单的等级1难度。" + }, + { + "idx": 3323, + "question": "How to suppress temper brittleness?", + "answer": "Methods to suppress temper brittleness: For the first type of temper brittleness, due to its irreversibility, it can only be avoided by tempering outside the embrittlement temperature range; if tempering must be performed within this temperature range, isothermal quenching can be used; adding Si to shift the low-temperature temper embrittlement range to higher temperatures, etc. Methods to suppress high-temperature temper brittleness: a) Rapid cooling after high-temperature tempering; b) Reducing the content of impurity elements in the steel; c) Adding appropriate amounts of Mo or W to the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释如何抑制回火脆性，答案提供了多种方法的详细描述和论述，符合简答题的特征。 | 知识层次: 题目要求解释如何抑制回火脆性，涉及多种方法和原理的综合应用，需要理解不同方法的适用条件和效果，并进行综合分析。虽然不涉及复杂的计算或深度机理分析，但需要对相关概念进行关联和选择合适的方法。 | 难度: 在简答题题型中，该题目要求对两种不同类型的回火脆性（第一类回火脆性和高温回火脆性）分别提出抑制方法，涉及多个知识点和解决方案。需要考生不仅理解回火脆性的概念，还要掌握具体的抑制措施，并能从材料成分、热处理工艺等多角度进行分析和论述。虽然不需要进行深度关联性分析（如机理研究或实验设计），但要求的知识点掌握深度和解题步骤复杂程度高于简单的概念解释或单一措施说明，因此属于多角度分析论述的难度等级。" + }, + { + "idx": 3325, + "question": "What are the types and characteristics of temper brittleness?", + "answer": "There are mainly two types of temper brittleness, namely low-temperature temper brittleness and high-temperature temper brittleness. Low-temperature temper brittleness, also known as the first type of temper brittleness, occurs to varying degrees in almost all industrial steels and is independent of the cooling rate after tempering. Therefore, it is also called irreversible temper brittleness (i.e., it occurs whether cooled rapidly or slowly). High-temperature temper brittleness, also known as the second type of temper brittleness, is characterized by its occurrence only in steels with specific compositions. Whether temper brittleness occurs depends on the cooling rate after tempering, i.e., it appears with slow cooling after tempering but not with rapid cooling, hence it is also called reversible temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释和论述回火脆性的类型和特征，答案提供了详细的文字描述和分类说明，符合简答题的特点。 | 知识层次: 题目主要考查对回火脆性的类型和特点的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生解释和描述两种回火脆性的类型及其特征，涉及基础概念的记忆和简单分类。虽然需要解释两种类型的区别和特点，但不需要深入分析或阐述复杂的理论体系，因此属于中等难度。" + }, + { + "idx": 3326, + "question": "Explain the factors affecting hardenability.", + "answer": "Hardenability mainly depends on the carbon content of martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响淬透性的因素，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对淬透性影响因素的基本概念记忆和理解，主要涉及碳含量对马氏体形成的影响这一基本原理。 | 难度: 在简答题题型中，该题目要求解释影响淬透性的因素，属于概念解释和描述的难度等级。虽然涉及多个因素（如碳含量、合金元素、冷却速率等），但题目仅要求基本解释而非深入分析各因素的相互作用或定量关系，因此属于中等难度。" + }, + { + "idx": 3327, + "question": "Describe the purpose of quenching", + "answer": "Quenching can significantly improve the strength and hardness of steel. Combined with tempering at different temperatures, it can achieve a balance of strength, hardness, and toughness to meet various requirements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述淬火的目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查淬火的基本目的和效果，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求描述淬火的目的，并简要说明其与回火结合的作用。虽然需要解释基本原理和应用，但不需要深入分析或阐述复杂的概念体系，属于中等难度的简答题。" + }, + { + "idx": 3328, + "question": "What are the types of quenching methods", + "answer": "The quenching methods include: 1. Single-liquid quenching; 2. Dual-liquid quenching; 3. Graded quenching; 4. Isothermal quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举淬火方法的类型，答案以文字解释和论述的形式给出，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查淬火方法的基本分类和记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求列举淬火方法的类型，属于基本定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆性知识即可回答，符合等级1的难度标准。" + }, + { + "idx": 3329, + "question": "There is a 20 steel workpiece with a diameter of φ12mm, which is carburized and then air-cooled, followed by normal quenching and tempering. Analyze the microstructure from the surface to the core of the workpiece after carburizing and air-cooling, and after quenching and tempering.", + "answer": "After air-cooling: P + Fe3CI, P, P + F; After quenching and tempering: M⊥+ FeC, tempered M, tempered M + F.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析工件从表面到核心的微观结构变化，需要详细的文字解释和论述，答案也以描述性文字呈现，符合简答题的特征。 | 知识层次: 题目要求分析从表面到核心的微观结构变化，涉及多个热处理步骤（渗碳、空冷、淬火、回火）的综合影响，需要深入理解相变机理和材料在不同冷却条件下的行为。这需要综合运用知识进行推理分析，而不仅仅是记忆或简单应用。 | 难度: 在简答题-复杂分析题型中，该题目要求对热处理工艺（渗碳、空冷、淬火、回火）后的显微组织从表层到心部进行全面分析，涉及多个相变过程和显微组织识别（P、Fe3C、M、F等），需要综合运用材料科学原理进行机理解释和推理分析。这种深度和广度的要求在该题型中属于最高难度等级。" + }, + { + "idx": 3330, + "question": "After quenching T8 steel wire to 275°C and holding for 1s, indicate its phase and composition.", + "answer": "Undercooled austenite (w_C=0.77%)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述材料的相和成分，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解T8钢的相变行为，结合具体的热处理条件（淬火到275°C并保温1秒）来判断其相组成和成分。这涉及到对钢的相变动力学和C曲线的理解，属于中等应用层次的知识。 | 难度: 在简答题中属于中等难度，需要理解淬火工艺对钢的组织转变的影响，并能准确判断特定温度和时间下的相组成。题目要求将温度、时间和钢的化学成分关联起来，综合分析得出正确的相和成分，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3331, + "question": "After quenching T8 steel wire to 20°C and holding, indicate its phases and composition.", + "answer": "M+A′ (w_C=0.77% in M, A′)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出淬火后T8钢的相组成和成分，答案需要文字解释和论述相的类型和成分，而不是选择、判断或计算。 | 知识层次: 题目要求分析T8钢在特定热处理条件下的相组成和成分，需要理解钢的相变原理和相图知识，并能够将理论知识与具体条件相结合进行综合分析。虽然不涉及复杂计算，但需要多步概念关联和综合分析能力。 | 难度: 在简答题中属于中等难度，需要理解T8钢的淬火过程、相变原理以及马氏体和残余奥氏体的形成条件。题目要求分析特定温度下的相组成和成分，涉及对钢的C曲线、相变动力学和成分分配的综合理解，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3333, + "question": "When complete austenitization of steel is required, is the original structure better with coarse granular pearlite or fine lamellar pearlite?", + "answer": "Fine lamellar pearlite is better.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么细片状珠光体比粗粒状珠光体更适合完全奥氏体化，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目涉及对奥氏体化过程中原始组织影响的综合分析，需要理解珠光体形态（粗粒状与细片状）对奥氏体化过程的影响机制，属于中等应用层次的知识运用。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要考生理解并关联多个概念（如奥氏体化、珠光体形态对相变的影响等），并进行综合分析。虽然题目涉及多步思考（比较粗粒珠光体和细片珠光体的奥氏体化效率），但不需要多角度或深度关联性分析（如结合具体工艺参数或相变动力学）。因此，在简答题的框架内，该题目符合等级3的综合分析和说明要求。" + }, + { + "idx": 3334, + "question": "Explain why the initial structure with fine lamellar pearlite is better using the austenite isothermal formation mechanism.", + "answer": "Increasing the dispersion of carbides can accelerate the transformation from pearlite to austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么初始结构具有细片状珠光体更好，并涉及奥氏体等温形成机制。答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释初始细片层珠光体结构在奥氏体等温形成机制中的优势，需要综合运用相变机理、组织性能关系等知识进行推理分析，涉及多概念关联和机理解释。 | 难度: 在简答题题型中，该题目要求对珠光体向奥氏体转变的机理进行深度解释，涉及等温形成机制和碳化物分散度的综合影响。虽然不需要全面分析复杂现象（等级5），但需要运用专业知识进行机理层面的推理和解释，属于机理深度解释的难度等级。" + }, + { + "idx": 3335, + "question": "After quenching T8 steel wire to 550°C and holding for 1s, indicate its phase and composition.", + "answer": "B⊥[F(w_C=0.0218%)+Fe3C(w_C=6.69%)]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的相和组成，需要文字解释和论述，答案形式为相和组成的描述，而非选择、判断或计算。 | 知识层次: 题目需要理解T8钢的相变行为，结合Fe-C相图分析550°C等温淬火后的相组成，涉及多步概念关联和综合分析。虽然不涉及复杂计算，但需要对相变机理和相图有较好的理解才能正确回答。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求分析T8钢在特定热处理条件下的相组成和成分，这需要综合运用相图知识、热处理原理和成分计算。其次，解题步骤较为复杂，需要先确定550°C对应的相区，然后根据杠杆定律计算各相的成分和相对含量。此外，题目还隐含了对珠光体转变动力学的理解（1s保温时间暗示非平衡态）。这些因素使得该题在简答题中需要多角度分析和论述，超出了基础概念复述的范畴，但尚未达到需要深度关联不同知识体系的最高难度。" + }, + { + "idx": 3336, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for normalizing φ25 hot-rolled eutectoid steel.", + "answer": "Normalizing: 780°C holding for 1h, air cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定热处理条件（温度、时间、冷却速率等），需要文字解释和论述，答案给出了具体的处理条件和方式，属于简答题类型。 | 知识层次: 题目要求确定热轧共析钢的正火热处理条件，涉及温度、时间和冷却速率等参数的选择。这需要应用基本的热处理知识，但不需要复杂的计算或深入的分析。答案直接给出了标准化的处理条件，属于简单应用范畴。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求确定热轧共析钢的正火热处理条件，答案直接给出了温度、时间和冷却方式，没有涉及复杂的计算或深入的理论解释。解题步骤简单，只需直接套用基本的热处理知识即可完成。因此，在同题型内属于较低难度等级。" + }, + { + "idx": 3337, + "question": "Indicate the main purpose of normalizing a small shaft made of 45 steel and the microstructure after normalizing", + "answer": "Small shaft made of 45 steel: Using normalizing instead of quenching and tempering as the final heat treatment can achieve good comprehensive mechanical properties similar to those obtained through quenching and tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释正常化处理的主要目的和微观结构，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释正火处理的主要目的和微观结构，需要将热处理工艺与材料性能、微观结构变化进行关联分析，属于中等应用层次的知识。 | 难度: 在简答题题型中，该题目要求考生不仅理解45钢小轴正火的主要目的，还需要说明正火后的组织状态，并与调质处理的效果进行对比分析。这涉及到多个概念的关联和综合分析，需要考生具备一定的材料科学知识深度和应用能力。虽然题目没有要求极其深入的关联性分析，但已经超出了基础概念解释的范畴，属于多角度分析论述的难度等级。" + }, + { + "idx": 3338, + "question": "After heating T8 steel wire to 870°C and holding for 1h, indicate its phase and composition.", + "answer": "Austenite, w_C=0.77%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据热处理条件判断钢的相和成分，需要专业知识解释和论述，答案以文字形式给出具体相和成分值，而非选择或计算。 | 知识层次: 题目考查对T8钢在特定热处理条件下的相变和成分的基础概念记忆，仅需回忆和识别标准条件下的相组成和碳含量，不涉及复杂分析或计算。 | 难度: 在简答题中属于中等难度，需要理解并描述特定热处理条件下的相变结果和成分，涉及基础概念的应用但不需要复杂体系阐述。" + }, + { + "idx": 3339, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for φ25 hot-rolled eutectoid steel during annealing.", + "answer": "Annealing: hold at 760°C for 1h, furnace cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定热处理条件（温度、时间、冷却速率等），答案需要提供具体的参数和文字说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据给定的材料（φ25热轧共析钢）和热处理工艺（退火）直接套用标准的热处理条件（温度、时间、冷却方式等），属于对基础知识的直接应用，不需要多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述。题目要求直接套用基本的热处理知识，给出具体的温度、时间和冷却方式，不需要复杂的解释或推导。解题步骤简单，仅需回忆并写出标准的热处理条件即可。" + }, + { + "idx": 3340, + "question": "There is a batch of approximately 10,000 pieces of 45 steel gears, which are subjected to relatively low contact stress but require good wear resistance on the teeth and minimal heat treatment deformation. What surface treatment should be selected for these parts? Why?", + "answer": "High-frequency surface quenching. After high-frequency surface quenching, the surface hardness is 1-2 HRC higher than conventional quenching, providing good wear resistance. Additionally, since high-frequency surface quenching results in minimal heat treatment deformation, this process is selected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述选择某种表面处理的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求根据具体工况（低接触应力、高耐磨性、最小热处理变形）选择表面处理方法，并解释原因。这需要综合理解高频表面淬火的特性（如硬度提升和变形控制）与材料性能要求之间的关联，属于中等应用层次的分析和选择过程。 | 难度: 在简答题中属于中等难度，需要综合分析和说明。题目要求选择适当的表面处理方法，并解释原因。虽然涉及多个概念（如接触应力、耐磨性、热处理变形等），但解题步骤相对直接，主要是基于给定的条件进行合理选择，并进行简要解释。不需要多角度或深度关联性分析。" + }, + { + "idx": 3341, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for spheroidizing annealing of φ25 hot-rolled eutectoid steel.", + "answer": "Spheroidizing annealing: hold at 780°C for 1h, air cool; hold at 680-700°C for 1h, air cool.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定热处理条件（温度、时间、冷却速率等），答案需要提供具体的工艺参数和文字说明，属于需要详细解释和论述的简答题类型。 | 知识层次: 题目要求确定球化退火的热处理条件，涉及温度、时间和冷却速率等参数的设定，需要综合理解球化退火的原理和具体工艺参数的选择，属于中等应用层次。虽然答案给出了具体的参数，但需要理解这些参数背后的原理和选择依据，而不仅仅是记忆。 | 难度: 在简答题中属于中等难度，需要理解并应用热处理的多个步骤和条件，包括温度、时间和冷却速率等参数的综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3342, + "question": "If a $\\phi5\\$ hot-rolled steel specimen is heated to 650℃, held isothermally for 15s, and then quenched in water, can the isothermal transformation curve be used to analyze the final microstructure obtained?", + "answer": "No. The isothermal transformation curve describes the transformation of undercooled austenite. The hot-rolled eutectoid steel heated to 650℃ does not undergo austenitization.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（\"can the isothermal transformation curve be used...\"），答案直接给出了明确的判断（\"No\"）并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对等温转变曲线基本概念的理解，即等温转变曲线描述的是过冷奥氏体的转变，而题目中热轧共析钢加热到650℃并未发生奥氏体化。这属于基础概念的记忆和理解。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对等温转变曲线适用条件的理解，需要学生掌握等温转变曲线的基本定义（仅适用于过冷奥氏体转变）以及能够判断热轧共析钢在650℃加热时不会发生奥氏体化这一关键点。虽然涉及基础概念的应用，但不需要进行复杂的概念组合或推导，因此属于该题型中的中等难度。" + }, + { + "idx": 3343, + "question": "In eutectoid steel, both pearlite and tempered martensite (assuming tempered at 400°C) are composed of ferrite and carbides. Why do the morphology of ferrite and the number of internal defects in tempered martensite differ from those in pearlite?", + "answer": "The pearlite in eutectoid carbon steel is lamellar, consisting of F plates (with a low number of internal defects) + Fe3C plates. After tempering at 400°C, the martensite structure becomes tempered troostite, F45 + Fe3C45, which is acicular ferrite and fine granular cementite. The ferrite in pearlite is lamellar with a low number of crystal defects (dislocations, twins), whereas the tempered martensite contains acicular ferrite, where the number of crystal defects is much higher than in pearlite due to quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在共析钢中，珠光体和回火马氏体（400°C回火）中的铁素体形态和内部缺陷数量不同，需要详细的文字解释和论述。答案提供了详细的微观结构描述和原因分析，符合简答题的特征。 | 知识层次: 题目要求解释珠光体和回火马氏体中铁素体形态和内部缺陷数量的差异，涉及相变过程、显微组织演变和晶体缺陷的复杂分析。需要综合运用相变理论、显微组织特征和缺陷形成机制进行推理和解释，思维深度较高。 | 难度: 在简答题-复杂分析题型中，该题目要求对珠光体和回火马氏体的微观结构差异进行深度机理解释，涉及晶体缺陷、相变过程等多重知识点的综合运用。需要考生同时掌握淬火-回火工艺对马氏体缺陷的影响、共析钢相变特征等跨章节知识，并能准确对比两种组织的形貌与缺陷密度差异。这种需要整合多个复杂概念并建立因果关系的题目，在该题型框架内属于最高难度级别。" + }, + { + "idx": 3344, + "question": "When hypereutectoid steel is slowly cooled from the austenite region, secondary cementite precipitates along the austenite grain boundaries in a network pattern. How can the network cementite be eliminated by heating above Ac cm followed by quenching and subsequent treatment?", + "answer": "Heating above Ac cm followed by quenching results in martensite and retained austenite, which is then tempered at high temperature to obtain spheroidized pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过热处理消除网状渗碳体，答案提供了详细的步骤和原理说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释如何通过热处理消除网状渗碳体，涉及多个热处理步骤（加热、淬火、回火）的综合运用，以及相变机理的解释（马氏体、残余奥氏体、球化珠光体的形成）。这需要深入理解材料科学中的相变原理和热处理工艺，并进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用相变原理、热处理工艺知识，并完整解释从加热到最终组织的转变机理。需要分步骤分析：1) Ac cm以上加热的相变目的；2) 淬火形成的亚稳组织；3) 回火过程中的球化机制。这种多阶段、多机理的整合分析要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 3345, + "question": "Among the various types of steel currently used in industry, cold-drawn high-carbon steel wire has the highest strength (up to 3000 MPa). This type of wire is generally obtained by first undergoing austenitization, followed by isothermal treatment in a lead bath at 500°C, and then cold drawing. Analyze the reasons for the high strength of this material.", + "answer": "When high-carbon steel undergoes isothermal treatment at 550°C after austenitization, the interlamellar spacing of pearlite can be made very small. Subsequent cold drawing not only increases the dislocation density in the ferrite of the pearlite, causing work hardening and subgrain refinement, but also further reduces the interlamellar spacing of the pearlite, thereby achieving high strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高碳钢丝高强度的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析高碳钢冷拔钢丝高强度的原因，涉及多个材料科学概念的综合运用，包括奥氏体化、等温处理、珠光体层间距、位错密度、加工硬化、亚晶粒细化等。需要将这些概念关联起来，进行推理分析和机理解释，思维过程较为深入和复杂。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用材料科学中的相变理论、加工硬化机理和显微组织控制等多方面知识。解题需要分步骤解释：(1)奥氏体化处理的作用 (2)等温处理的珠光体片层细化机制 (3)冷拉拔对位错密度和亚晶粒的影响 (4)最终强度提升的综合机理。这种需要多维度分析并建立各工艺环节间因果关系的题目，在简答题中属于最高难度的复杂现象全面分析类型。" + }, + { + "idx": 3346, + "question": "In eutectoid steel, both pearlite and tempered martensite (assuming tempered at 400°C) consist of ferrite and carbide. Why do the morphology and dispersion of carbides in tempered martensite differ from those in pearlite?", + "answer": "The carbides in pearlite exhibit a lamellar morphology with low dispersion, whereas the carbides in martensite are fine particles with high dispersion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体和珠光体中的碳化物形态和分布不同，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释两种不同微观结构中碳化物的形态和分散差异，需要综合运用相变动力学、显微组织形成机理等知识进行推理分析，涉及多个概念的关联和深入理解。 | 难度: 在简答题（复杂分析类）中，该题目要求对珠光体和回火马氏体中碳化物的形态和分布差异进行机理层面的深度解释。需要综合运用相变动力学、显微组织演变等知识，分析不同热处理条件下碳化物的形成机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础描述层面，属于需要机理推导的中高难度题目。" + }, + { + "idx": 3347, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the iron-carbon phase diagram?", + "answer": "The iron-carbon phase diagram can only be used to determine the microstructure under equilibrium cooling conditions and is not applicable for predicting the normalizing effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对铁碳相图在预测正火效果中的适用性进行文字解释和论述，答案提供了详细的解释而非简单的选择或判断。 | 知识层次: 题目要求应用铁碳相图的知识来分析正火效果，需要理解相图的局限性，并关联实际热处理过程，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求考生理解铁碳相图的应用范围，并能够分析其在特定热处理工艺（正火）中的适用性。虽然题目涉及的知识点较为基础，但需要考生进行综合分析和说明，将相图知识与实际工艺条件联系起来。解题步骤包括：1) 明确铁碳相图的适用条件（平衡冷却）；2) 分析正火工艺的非平衡特性；3) 得出相图不适用的结论。这种要求概念关联和综合分析的题目，在简答题中属于等级3的难度。" + }, + { + "idx": 3348, + "question": "Compare the advantages and disadvantages of various quenching methods", + "answer": "1. Single-liquid quenching: This method is widely used, simple to operate, and easy to mechanize. The drawback is that some steel parts are prone to deformation and cracking when water-quenched, while oil quenching may result in insufficient hardness. 2. Dual-liquid quenching: This method is difficult to control. 3. Graded quenching: During quenching, the internal temperature of the workpiece is uniform, and the structural transformation occurs almost simultaneously, thereby reducing internal stress and significantly lowering the tendency for deformation and cracking. However, it is only suitable for workpieces with strict deformation requirements and smaller dimensions. 4. Isothermal quenching: Workpieces treated by this method exhibit high strength and hardness, as well as good plasticity and toughness. Additionally, the quenching stress is low, and deformation is minimal. It is mostly used for workpieces with complex shapes, smaller dimensions, and higher precision requirements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较不同淬火方法的优缺点，需要详细的文字解释和论述，而不是选择、判断或计算。答案提供了对各种淬火方法的详细描述，符合简答题的特征。 | 知识层次: 题目要求比较不同淬火方法的优缺点，需要对各种淬火方法的基本原理和应用场景有较深入的理解，并进行综合分析。虽然涉及一些基础概念的记忆，但更侧重于对不同方法的应用效果和适用条件的分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对多种淬火方法进行多角度的优缺点分析，涉及不同方法的操作复杂性、适用条件、工件性能影响等多个维度。需要考生不仅掌握每种方法的基本概念，还要能够进行综合比较和论述，属于该题型中较高难度的题目。" + }, + { + "idx": 3349, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the isothermal transformation curve?", + "answer": "Using the isothermal transformation curve can only provide an approximate estimation of the normalizing effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对等温转变曲线在预测正火效果中的适用性进行解释和论述，答案提供了文字解释而非选择、判断或计算 | 知识层次: 题目要求评估等温转变曲线在预测共析钢棒材正火效果中的适用性，这需要理解等温转变曲线的基本原理并将其应用于具体情境。虽然不涉及复杂的计算或深度机理分析，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然需要理解并应用等温转变曲线来预测正火效果，但解题过程主要涉及单一知识点的综合分析和说明，不需要多角度分析或深度关联性分析。题目要求对等温转变曲线的适用性进行解释，属于概念关联和综合分析的范畴，但步骤和复杂程度相对适中。" + }, + { + "idx": 3350, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the continuous cooling transformation curve?", + "answer": "To predict the microstructure and hardness after cooling, the continuous cooling transformation curve should be used, as normalizing is a continuous cooling process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释连续冷却转变曲线在预测正火效果中的适用性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求将连续冷却转变曲线的知识应用于预测正火效果，涉及概念关联和综合分析，需要理解正火过程与连续冷却转变曲线的关系，并解释其适用性。 | 难度: 在简答题中属于中等难度，需要理解连续冷却转变曲线的应用场景，并能将其与正火工艺的冷却过程关联起来进行分析说明。题目要求考生综合运用材料科学知识来解释现象，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3351, + "question": "Suppose the microstructure of an alloy consists of multiple two-phase lamellar eutectic domains with different orientations and uniform distribution. The actual interlamellar spacing in each domain is equal. How should this interlamellar spacing be determined under a metallographic microscope?", + "answer": "Measure the minimum interlamellar spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述如何确定层间距，答案是一个简短的文字说明而非选择、判断或计算 | 知识层次: 题目需要理解两相层状共晶组织的微观结构特征，并应用金相显微镜测量技术来确定层间距。虽然涉及基础概念，但需要综合分析不同取向的层状结构，并选择正确的测量方法（最小层间距），这属于中等应用层次的知识运用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求考生综合运用材料科学知识，理解多相层状共晶组织的微观结构特征，并说明在显微镜下测量层间距的正确方法。虽然需要一定的综合分析能力，但解题步骤相对明确（只需说明测量最小层间距的原理），不需要进行多角度或深度关联性分析。这符合等级3\"综合分析和说明\"的标准，比单纯记忆性简答题（等级1-2）要求更高，但尚未达到需要复杂论述的等级4-5水平。" + }, + { + "idx": 3352, + "question": "In eutectoid steel, both pearlite and tempered martensite (assuming tempered at 400°C) are composed of ferrite and carbide. Why is the strength of tempered martensite higher than that of the strongest pearlite?", + "answer": "The morphology of ferrite and the number of internal defects differ between the two. In pearlite, the ferrite is lamellar with fewer crystal defects (dislocations, twins), whereas in tempered martensite, the ferrite is acicular, and the number of crystal defects is much higher due to quenching. The morphology and dispersion of carbides also differ. In pearlite, the carbides are lamellar with low dispersion, while in martensite, the carbides are fine particles with high dispersion. Thus, the strength of tempered martensite is higher than that of the strongest pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体的强度高于最强的珠光体，答案提供了详细的文字解释和论述，涉及两种组织的形态和内部缺陷差异，符合简答题的特征。 | 知识层次: 题目要求解释两种不同微观组织（珠光体和回火马氏体）的强度差异，涉及对晶体缺陷、碳化物形态和分散度的综合分析。需要深入理解淬火和回火过程对微观结构的影响，以及这些结构特征如何影响材料的力学性能。这属于对材料科学原理的复杂分析和推理。 | 难度: 在简答题的复杂分析层次中，该题目要求对珠光体和回火马氏体的微观结构进行深度对比，涉及晶体缺陷、碳化物形态与分布等多重因素的综合分析。需要学生不仅掌握基础概念，还要具备将不同知识点串联起来解释复杂现象的能力，属于该题型框架内的最高难度等级。" + }, + { + "idx": 3353, + "question": "Suppose the microstructure of a certain alloy consists of spherical second-phase particles and a matrix. If the actual diameters of the second-phase particles are all equal, how should the particle size be determined under a metallographic microscope?", + "answer": "Measure the diameter of the largest particle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来确定粒子尺寸的测量方法，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查对金相显微镜下测量第二相颗粒尺寸的基本方法的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆并复述一个简单的操作步骤（测量最大颗粒的直径），不需要进行概念解释或复杂体系的阐述。这符合基础概念记忆的知识层次要求，且解题步骤极为简单，属于该题型内最低难度级别。" + }, + { + "idx": 3354, + "question": "Using the fact that pearlite, proeutectoid ferrite, and proeutectoid cementite preferentially precipitate at austenite grain boundaries, propose a method for determining the austenite grain size of steel with a carbon mass fraction of 0.8%.", + "answer": "After austenitization, isothermally hold near the knee of the C-curve until partial pearlite transformation occurs (e.g., around 10%), then quench. Since pearlite preferentially nucleates and grows at austenite grain boundaries, the grain boundaries will appear as dark pearlite, while the grain interiors will be less etchable martensite. This allows convenient measurement of austenite grain size under a microscope. Alternatively, this microstructure can be obtained by cooling at an appropriate rate after austenitization (e.g., oil quenching for specimens about 10mm thick). For better control, a rod-shaped specimen can be austenitized with one end immersed in water while the rest cools in air. This creates a range of cooling rates along the rod's length, ensuring there will always be a section where pearlite precipitates along austenite grain boundaries with martensite in the grain interiors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提出一种方法并详细解释其原理和步骤，答案以论述形式给出，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求综合运用材料科学中的相变原理、显微组织观察和实验设计等多方面知识，通过分析珠光体、先共析铁素体和先共析渗碳体在奥氏体晶界优先析出的现象，提出测定奥氏体晶粒尺寸的方法。这需要深入理解相变动力学、显微组织形成机制，并能设计合理的实验方案，属于复杂分析和综合运用的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用相变原理、显微组织观察技术和实验设计能力。解题需要：1) 理解珠光体优先形核机制；2) 设计包含等温转变和连续冷却的复合热处理工艺；3) 解释多相组织的形成机理；4) 提出两种不同的实验方案（等温法和连续冷却法）并比较其优劣。这种需要整合多个高级概念并设计实验方案的题目，在复杂分析类简答题中属于最高难度等级。" + }, + { + "idx": 3356, + "question": "A heat-treated part is made of 55 steel with an effective thickness of 10 mm, requiring a quenched and tempered hardness of HRC 32-37. Using oil quenching and tempering can also achieve the hardness specified in the drawing. Analyze whether this treatment method is reasonable.", + "answer": "Generally speaking, it is not reasonable. Because oil quenching will result in a large amount of lamellar pearlite transformation products. Although the hardness after tempering falls within the required range, the overall mechanical properties are inferior to those of tempered martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析热处理方法的合理性，答案提供了详细的解释和论述，说明为什么油淬火和回火方法不合理，并比较了机械性能的差异。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析热处理方法的合理性，涉及对55钢油淬和回火后组织转变的理解，以及不同组织对机械性能影响的综合分析。需要将材料的热处理工艺、组织转变和性能要求关联起来进行判断，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求考生不仅理解55钢的热处理工艺（油淬和回火），还需要分析其合理性，并对比不同组织（层状珠光体和回火马氏体）对机械性能的影响。这需要考生综合运用材料科学知识，进行多步推理和比较分析，属于中等应用层次中较为复杂的题目。" + }, + { + "idx": 3357, + "question": "Classify according to the interaction between alloying elements and carbon, and indicate which elements are weak carbide-forming elements", + "answer": "Weak carbide-forming elements: manganese", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对合金元素与碳的相互作用进行分类，并指出哪些是弱碳化物形成元素，需要文字解释和论述，答案也是以文字形式给出具体元素名称。 | 知识层次: 题目考查对合金元素与碳相互作用分类的基础概念记忆，特别是弱碳化物形成元素的识别，属于基本概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并列举弱碳化物形成元素（锰），无需解释或阐述复杂概念体系。题目要求的知识深度和解题步骤都极为基础。" + }, + { + "idx": 3359, + "question": "Classify according to the interaction between alloying elements and carbon, and indicate which elements do not form carbides", + "answer": "Non-carbide forming elements: nickel, silicon, cobalt, aluminum, copper, boron, nitrogen, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对合金元素与碳的相互作用进行分类，并指出哪些元素不形成碳化物，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对合金元素与碳相互作用分类的记忆，以及非碳化物形成元素的列举，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求分类并列举不与碳形成碳化物的元素，这主要涉及对基础概念的记忆和简单列举，不需要深入的解释或复杂的论述。因此，在简答题的框架内，该题目属于最低难度等级。" + }, + { + "idx": 3360, + "question": "When hypereutectoid steel is slowly cooled from the austenite region, secondary cementite will precipitate along the austenite grain boundaries in a network form. How can the network cementite be eliminated by heating above Ac cm followed by air cooling and subsequent treatment?", + "answer": "Heating above Ac cm followed by air cooling to obtain a pseudo-eutectoid structure, then performing high-temperature tempering or spheroidizing annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的处理步骤和方法，而不是选择、判断或计算。 | 知识层次: 题目需要理解过共析钢冷却过程中的二次渗碳体析出行为，并应用热处理知识（加热至Ac cm以上、空冷、后续处理）来消除网状渗碳体。这涉及多步热处理工艺的选择和组合，需要对相关概念进行关联和综合分析，但不需要进行复杂的机理推理或创新设计。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求考生理解并解释多个热处理步骤（加热、空冷、回火或球化退火）及其对网状渗碳体的消除作用，这需要综合运用材料科学中的相变知识和热处理原理。其次，题目涉及伪共析组织的形成和后续处理，要求考生能够关联不同概念并分析其相互作用。此外，解题步骤较为复杂，需要考生具备较强的综合分析能力和知识应用能力。因此，在简答题题型中，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 3361, + "question": "What are the ways to improve the strength of materials", + "answer": "The strengthening effects of alloying elements in steel mainly include the following four methods: solid solution strengthening, grain boundary strengthening, second-phase strengthening, and dislocation strengthening. By applying these four methods individually or in combination, the strength of steel can be effectively improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述提高材料强度的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释和论述提高材料强度的四种方法，这需要理解每种方法的基本原理及其在钢中的应用，属于多概念关联和综合分析。虽然不涉及复杂计算或深度机理分析，但需要将不同强化机制联系起来进行论述，超出了单纯记忆基础概念的层次。 | 难度: 在简答题题型中，该题目要求考生不仅列举四种强化方法，还需要解释每种方法的作用机制及其在提高钢材强度中的具体应用。这涉及到多角度分析论述，需要考生综合运用材料科学中的多个概念，并能够清晰地表达它们之间的关联性。虽然题目没有要求极其深入的关联性分析，但已经超出了简单列举和说明的范畴，属于中等偏上的难度。" + }, + { + "idx": 3362, + "question": "Discuss the factors affecting the plasticity of materials", + "answer": "The main factors affecting the plasticity of steel include: (1) the influence of solute atoms; (2) the influence of grain size; (3) the influence of the second phase; (4) the influence of dislocation strengthening, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论影响材料塑性的因素，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求讨论影响材料塑性的多个因素，涉及不同概念（如溶质原子、晶粒尺寸、第二相、位错强化等）的关联和综合分析，需要理解这些因素如何相互作用并影响材料的塑性行为，属于中等应用层次。 | 难度: 在简答题中，该题目要求对影响材料塑性的多个因素进行多角度分析论述，包括溶质原子、晶粒尺寸、第二相和位错强化等。虽然不需要进行深度关联性分析，但需要综合多个概念并进行较为详细的解释，属于中等偏上的难度。" + }, + { + "idx": 3363, + "question": "Discuss the factors affecting the strength of materials", + "answer": "The mechanical properties of materials are related to their chemical composition, internal microstructure, inclusions and surface microstructure, as well as stress state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论影响材料强度的因素，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求讨论影响材料强度的因素，涉及多个概念（化学成分、内部微观结构、夹杂物和表面微观结构以及应力状态）的关联和综合分析，需要理解这些因素如何相互作用来影响材料的机械性能。这超出了单纯记忆基础概念的层次，但尚未达到需要复杂分析或创新应用的高级综合层次。 | 难度: 在简答题题型中，该题目要求对影响材料强度的多个因素进行多角度分析论述，包括化学成分、内部微观结构、夹杂物和表面微观结构以及应力状态等。这需要考生不仅理解各个因素的基本概念，还需要能够综合这些因素进行关联性分析，展示出对材料强度影响机制的深入理解。虽然题目没有要求进行深度关联性分析（如探讨各因素之间的相互作用机制），但多角度分析的要求已经超出了简单的概念解释或单一因素讨论，因此属于等级4难度。" + }, + { + "idx": 3364, + "question": "Classify according to the interaction between alloying elements and carbon, and indicate which elements are strong carbide-forming elements. What are the performance characteristics of strong carbides?", + "answer": "Strong carbide-forming elements: titanium, zirconium, vanadium, niobium. Strong carbides are relatively stable, with high melting points, high hardness, and relatively high brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对合金元素与碳的相互作用进行分类，并指出哪些是强碳化物形成元素，以及强碳化物的性能特点。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目主要考查对强碳化物形成元素的分类及其性能特点的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求分类并指出强碳化物形成元素，同时描述强碳化物的性能特征。这需要学生对相关概念有清晰的理解和记忆，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目需要更多的解释和描述；相比等级3的复杂概念体系阐述，该题目的知识点和解题步骤相对简单。" + }, + { + "idx": 3365, + "question": "What is alloy cementite, and how does its performance compare with cementite", + "answer": "Alloy cementite is formed when alloying elements dissolve into cementite. Alloy cementite has higher stability than ordinary cementite and exhibits a more significant strengthening effect on the steel matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是合金渗碳体，并比较其性能与普通渗碳体的差异，需要文字解释和论述，属于简答题类型。 | 知识层次: 题目考查合金渗碳体的基本定义及其与普通渗碳体的性能比较，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释合金渗碳体的定义及其性能比较，属于概念解释和描述的范畴。虽然需要记忆基本定义，但还需要对性能差异进行简要说明，比单纯的定义简答（等级1）稍复杂，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 3366, + "question": "Why can shot peening and surface rolling significantly improve the fatigue limit of materials?", + "answer": "Shot peening and surface rolling can create a very thin work-hardened layer on the surface of the workpiece, which not only has a higher yield limit but also contains significant compressive stress (400-500 MPa). This weakens the effect of tensile stress on the surface and delays the formation of surface cracks, thereby significantly improving the fatigue limit of the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么喷丸和表面滚压能显著提高材料的疲劳极限，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释shot peening和surface rolling如何通过产生表面硬化层和压应力来改善材料的疲劳极限，涉及多个概念的关联和机理解释，需要综合运用材料科学知识进行推理分析。 | 难度: 在简答题中属于机理深度解释难度，需要理解并解释表面处理工艺（喷丸和表面滚压）如何通过形成加工硬化层和引入压应力来改善材料的疲劳极限。这涉及到材料科学中的多个概念，如加工硬化、残余应力、疲劳裂纹形成等，并要求将这些概念综合起来进行解释。虽然不需要全面分析复杂现象，但需要对机理有较深入的理解和阐述。" + }, + { + "idx": 3367, + "question": "Describe the role of alloying elements in ordinary low-alloy steels", + "answer": "Adding alloying elements such as manganese is to improve the strength of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述合金元素在普通低合金钢中的作用，需要文字解释和论述，答案也提供了相关的文字解释。 | 知识层次: 题目考查对合金元素在普通低合金钢中作用的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题中，该题目要求解释合金元素在普通低合金钢中的作用，属于概念解释和描述的难度等级。虽然需要一定的记忆和理解，但不需要复杂的体系阐述或多步骤推理，属于中等难度的简答题。" + }, + { + "idx": 3368, + "question": "What elements are commonly used to improve hardenability?", + "answer": "Cr, Ni, Mn, Si, B", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举常见的元素，答案是一系列元素名称，不需要计算或选择，属于简答题类型 | 知识层次: 题目考查对提高淬透性常用元素的基本记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆层次，仅需列举常见元素名称即可完成作答。不需要进行概念解释或复杂体系阐述，符合等级1\"基本定义简答\"的标准。题目答案明确且简短，在同类简答题中属于最基础难度级别。" + }, + { + "idx": 3369, + "question": "Discuss the approaches to improve the plasticity of materials", + "answer": "Approaches to improve plasticity: (1) Adding small amounts of alloying elements such as titanium and vanadium to steel can fix carbon and nitrogen and form carbides or nitrides, thereby improving the plasticity of steel. (2) Refining grain size is beneficial for enhancing plasticity. (3) When strengthening with a second phase, the quantity, size, shape, and distribution of carbides can be controlled by combining alloying with tempering and spheroidization treatments; reducing the number of inclusions in steel and controlling their morphology. (4) When strengthening through cold deformation, adding trace elements such as titanium, vanadium, and zirconium to fix interstitial atoms and prevent their segregation to dislocations can improve the plasticity of steel to some extent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论改善材料塑性的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论提高材料塑性的多种方法，涉及合金元素添加、晶粒细化、第二相强化和冷变形强化等多个方面，需要综合运用材料科学知识进行机理解释和综合分析。这需要深入理解材料塑性改善的多种途径及其背后的科学原理，属于复杂分析和综合运用的层次。 | 难度: 在简答题题型中，该题目要求对提高材料塑性的多种方法进行详细解释和机理分析。虽然题目涉及多个知识点，但每个方法的解释相对独立，且不需要进行复杂的现象综合或跨领域分析。因此，在简答题的复杂分析层次中，属于机理深度解释的等级4难度。" + }, + { + "idx": 3370, + "question": "Why are carburizing steels mostly used to manufacture gears for automobile and tractor gearboxes and rear axle gears?", + "answer": "Their working conditions are demanding, requiring high toughness in the core and high hardness on the surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么渗碳钢主要用于制造汽车和拖拉机变速箱齿轮和后桥齿轮，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释渗碳钢在特定应用中的选择原因，涉及材料性能与工作条件的关联分析，需要理解材料性能（高韧性和高硬度）与具体应用（汽车和拖拉机齿轮箱）之间的关系，属于中等应用层次的分析。 | 难度: 在简答题中属于中等难度，需要理解并综合说明渗碳钢在特定应用中的性能要求，包括核心韧性和表面硬度的双重需求，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3371, + "question": "What is the reason why alloying elements improve hardenability?", + "answer": "It shifts the C-curve to the right and reduces the critical cooling rate for quenching", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素提高淬透性的原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释合金元素提高淬透性的原因，涉及对C曲线移动和临界冷却速率变化的机理分析，需要综合运用材料科学中的相变理论和合金化原理进行推理和解释，属于复杂分析层次。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求对合金元素提高淬透性的机理进行深度解释，涉及C曲线右移和临界冷却速率降低的因果关系分析。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述（等级3），属于需要综合材料相变动力学知识的机理阐述题，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 3372, + "question": "What are the ways to improve the strength and toughness of mild steel?", + "answer": "The way to improve is solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述提高低碳钢强度和韧性的方法，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目要求解释和论述提高低碳钢强度和韧性的方法，涉及多个概念（如固溶强化）的关联和综合分析，需要理解材料强化机制并应用这些知识来解决问题，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对提高低碳钢强度和韧性的方法进行多角度分析论述。虽然答案提供了一个具体方法（固溶强化），但题目本身隐含需要考生考虑多种强化机制（如细晶强化、位错强化、第二相强化等）及其对强度和韧性的综合影响。这需要将材料科学基础理论进行关联应用，并比较不同方法的优缺点，属于典型的多角度分析论述要求。相比只需简单列举方法的等级3题目，该题需要更系统的知识整合能力。" + }, + { + "idx": 3373, + "question": "What is the reason why alloying elements improve the tempering stability of steel?", + "answer": "Non-carbide forming elements have the effect of delaying the decomposition of martensite. This is because they can dissolve into ε-carbide and stabilize it, slowing down the aggregation rate of carbides. Compared to carbon steel, the final decomposition temperature of martensite may be delayed to 350-500℃, which is 100-150℃ higher than that of carbon steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素提高钢的回火稳定性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素提高钢的回火稳定性的机理，涉及非碳化物形成元素对马氏体分解的延迟作用、ε-碳化物的稳定化以及碳化物聚集速率的减缓等复杂过程。这需要综合运用材料科学中的相变理论、合金化原理和热力学知识，进行深入的推理分析和机理解释。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目要求对合金元素提高钢的回火稳定性的机理进行深度解释。需要综合运用材料科学知识，理解非碳化物形成元素如何溶解到ε-碳化物中并稳定它，从而延缓马氏体分解的过程。此外，还需要比较合金钢与碳钢在最终分解温度上的差异。这种题目不仅要求掌握基础概念，还需要进行机理层面的推理和分析，属于该题型中较高难度的题目。" + }, + { + "idx": 3374, + "question": "What elements are commonly used to improve the tempering stability of steel?", + "answer": "Common elements: Si, Co.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举常见的元素来改善钢的回火稳定性，答案以文字形式给出，不需要计算或选择，属于简答题类型 | 知识层次: 题目考查对钢的回火稳定性改善常用元素的基本记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求列举常见的元素（Si, Co），属于基础概念记忆层面的回答，不需要额外的解释或论述。与同题型中需要详细解释或复杂概念阐述的题目相比，该题目对知识点掌握深度和解题步骤的要求都非常基础，因此属于等级1难度。" + }, + { + "idx": 3375, + "question": "Compare the heat treatment process characteristics of hot work die steel and alloy quenched and tempered steel.", + "answer": "The heat treatment processes for both are quenching + high temperature tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较两种钢材的热处理工艺特性，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求比较两种钢材的热处理工艺特点，需要理解并关联淬火和高温回火的基本概念，同时进行综合分析。虽然不涉及复杂计算，但需要对不同材料的热处理工艺有一定深度的理解和比较能力，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对两种钢材的热处理工艺特性进行比较分析，涉及多步计算、概念关联和综合分析。虽然答案给出了基本的热处理工艺（淬火+高温回火），但题目要求更深入的比较和论述，如工艺参数差异、组织性能变化等，属于多角度分析论述的难度等级。" + }, + { + "idx": 3376, + "question": "What are the characteristics of the heat treatment process for high-speed steel?", + "answer": "The most prominent features of the process are the very high quenching heating temperature, high tempering temperature, multiple tempering cycles, and the use of preheating during quenching heating.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释高速钢热处理工艺的特点，答案以文字论述形式给出，没有选项或计算要求。 | 知识层次: 题目要求解释高速钢热处理工艺的特点，涉及多个关键参数（淬火加热温度、回火温度、多次回火循环等）的综合描述，需要将不同概念关联起来进行说明，属于中等应用层次。虽然不涉及复杂计算或深度机理分析，但需要对工艺参数有较好的理解和综合表达能力。 | 难度: 在简答题题型中，该题目要求对高速钢热处理工艺的特点进行多角度分析论述，涉及多个关键步骤（如高温淬火、多次回火等）的综合说明，并需要解释工艺参数设置的原理。虽然不需要进行深度关联性分析（如微观机理），但已超出基础概念复述的范畴，属于中等偏上的应用型难度。" + }, + { + "idx": 3377, + "question": "Why are 40CrNiMo and 37SiMnCrMoV steels (25mm in diameter) in the normalized state difficult to machine? Please consider the most economical method to improve machinability.", + "answer": "The high carbon content and the presence of alloying elements result in excessive hardness in the normalized state, making machining difficult. The most economical method to improve machinability is annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么特定钢材在正火状态下难以加工，并提出最经济的改善方法。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解合金钢在正火状态下的硬度问题，并分析其对加工性能的影响。同时，需要综合考虑经济性和加工性能改进方法，涉及多步分析和概念关联。虽然不涉及复杂计算，但需要对材料性能和处理工艺有较深入的理解和应用。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求分析两种特定钢材在正火状态下难以加工的原因，这需要考生对钢材成分、热处理状态及其对机械加工性能的影响有深入理解。其次，题目还要求提出最经济的改善加工性能的方法，这需要考生综合考虑多种可能的解决方案，并评估其经济性。这种多角度分析和综合论述的要求使得该题目在同题型中属于较高难度等级。" + }, + { + "idx": 3378, + "question": "How to select the microstructure state of steel for machine parts based on their service conditions?", + "answer": "For less critical parts where the comprehensive mechanical properties are not highly demanded, normalize to obtain ferrite + pearlite. For parts requiring good surface wear resistance and high contact fatigue resistance, while the entire part bears impact loads and the core demands higher toughness, carburizing, quenching, and low-temperature tempering can be applied, resulting in a surface of martensite with high hardness and wear resistance, and a core of ferrite + pearlite with higher toughness. For parts requiring higher comprehensive mechanical properties, apply quenching and tempering to obtain tempered sorbite. Carbon steels and alloy steels with relatively high carbon content can be used to manufacture springs, and the heat treatment process of quenching and medium-temperature tempering should be adopted to achieve tempered troostite. Bearings should be made of rolling bearing steel, treated with quenching and low-temperature tempering to obtain tempered martensite with high hardness and wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于服务条件选择钢材的微观结构状态，答案提供了详细的文字解释和论述，涉及不同零件和热处理工艺的选择，符合简答题的特征。 | 知识层次: 题目要求根据不同的服役条件选择钢材的微观组织状态，涉及多个热处理工艺及其对应的组织与性能关系。这需要综合理解不同热处理工艺的原理、应用场景及其对材料性能的影响，属于中等应用层次。虽然不涉及复杂的计算或深度机理分析，但需要将多个概念关联起来进行综合分析。 | 难度: 在简答题题型中，该题目要求多角度分析论述，涉及不同工况下钢材微观结构的选择及其对应的热处理工艺。需要综合考虑多种机械性能要求（如耐磨性、疲劳抗力、韧性等）与微观结构之间的关系，并针对不同零件类型（如弹簧、轴承等）提出具体的热处理方案。这种综合分析能力和多知识点关联的要求，使得该题目在简答题中属于较高难度等级。" + }, + { + "idx": 3379, + "question": "What is the role of carbon and alloying elements in high-speed steel?", + "answer": "The purpose of high carbon content is to form carbides with carbide-forming elements such as Cr, W, Mo, and V, and to ensure a strong martensitic matrix to enhance the hardness and wear resistance of the steel. W, Mo, and V primarily improve the red hardness of the steel, as the carbides formed by these elements have high hardness and produce a 'secondary hardening' effect, thereby significantly enhancing the steel's red hardness, hardness, and wear resistance. Cr mainly improves the hardenability of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释碳和合金元素在高速钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释碳和合金元素在高速钢中的作用，涉及多个元素的协同效应和机理解释，需要综合分析不同元素对钢性能的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅能够列举碳和合金元素在高速钢中的作用，还需要解释这些元素如何通过形成碳化物和影响基体组织来提升钢的性能。这涉及到多步的概念关联和综合分析，如碳与不同合金元素的交互作用、碳化物的类型及其对性能的影响、以及二次硬化效应的机制等。虽然题目没有要求极其深入的关联性分析（如微观结构演变或热力学计算），但已经超出了基础概念复述的范畴，属于需要多角度分析论述的中高难度题目。" + }, + { + "idx": 3380, + "question": "Describe the role of carbon in low-alloy steel", + "answer": "Low carbon content is to ensure the plasticity, toughness and weldability of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述碳在低合金钢中的作用，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查碳在低合金钢中的作用这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求解释碳在低合金钢中的作用，属于概念解释和描述的难度等级。虽然需要一定的专业知识来阐述碳含量对钢的性能影响，但并不涉及复杂的概念体系或多层次的论述。因此，在简答题的基础概念记忆层次中，属于中等难度。" + }, + { + "idx": 3381, + "question": "Why are medium carbon (alloy) steels mostly used to manufacture gearbox gears for machine tools?", + "answer": "Their working conditions are much better than those of automobiles, requiring certain toughness in the core and higher hardness on the surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么中碳（合金）钢常用于制造机床变速箱齿轮，答案提供了文字解释和论述，说明其工作条件和性能要求，符合简答题的特征。 | 知识层次: 题目需要理解中等碳钢的特性及其在特定工作条件下的应用，涉及材料性能与工作条件的综合分析，但不需要复杂的机理解释或创新设计。 | 难度: 在简答题题型中，该题目属于较高难度。题目要求考生不仅理解中碳合金钢的基本特性，还需要结合齿轮箱齿轮的实际工作条件进行多角度分析。具体来说：" + }, + { + "idx": 3382, + "question": "How to select the carbon content in steel for machine parts based on their service conditions?", + "answer": "For non-critical parts with low requirements for comprehensive mechanical properties, medium carbon steel can be selected. For parts requiring good surface wear resistance and high contact fatigue resistance, while the entire part withstands impact loads and the core requires high toughness, carburizing steel, i.e., low carbon steel or low carbon alloy steel, should be selected. For parts requiring high comprehensive mechanical properties, quenched and tempered steel, i.e., medium carbon steel or medium carbon alloy steel, should be selected. Carbon steel and alloy steel with higher carbon content can be used to manufacture springs. Bearings should be made of rolling bearing steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于服务条件选择钢材的碳含量，答案提供了详细的文字解释和论述，说明不同情况下应选择的钢材类型，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据不同的服役条件选择钢材的碳含量，需要综合考虑多种因素（如机械性能要求、耐磨性、疲劳抗力等），并进行概念关联和综合分析。虽然不涉及复杂计算，但需要对不同钢材的特性和应用场景有较深入的理解和应用能力。 | 难度: 在简答题题型中，该题目要求考生根据不同的服役条件选择钢材的碳含量，涉及多个知识点（如不同碳含量钢材的机械性能、耐磨性、疲劳抗力等）的综合分析和关联。题目不仅要求考生理解各种钢材的特性，还需要能够将这些特性与具体的服役条件对应起来，进行多角度的论述。虽然不需要进行深度关联性分析（如微观组织与性能的关系），但解题步骤较为复杂，需要综合考虑多个因素，因此在简答题中属于较高难度。" + }, + { + "idx": 3383, + "question": "Compare the alloying characteristics of hot-work die steel and alloy quenched and tempered steel, and analyze the similarities and differences in the roles of alloying elements.", + "answer": "The main alloying elements (Si, Mn, Cr, Ni, B, etc.) in quenched and tempered steel primarily enhance the hardenability of the steel; the auxiliary elements (W, Mo, V, Ti) mainly refine the austenite grain size, thereby refining the ferrite grain size in tempered sorbite. Hot-work die steel often contains alloying elements such as Cr, Mn, Si, Mo, W, and V to improve the steel's hardenability, tempering stability, and wear resistance, while also suppressing secondary temper brittleness. Cr, Si, and W enhance fatigue resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较和分析两种钢材的合金化特性，以及合金元素的相似和不同作用，需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种不同类型钢的合金化特性，并分析合金元素作用的异同点。这需要综合运用材料科学中的合金化原理、相变理论以及不同合金元素的作用机制，进行深入的推理分析和机理解释。涉及的知识点复杂且关联度高，思维过程要求深度分析和综合判断。 | 难度: 在简答题的复杂分析层次中，该题目要求对两种不同类型钢材的合金化特性进行全面比较，并深入分析合金元素作用的异同。这需要综合运用材料科学知识，包括合金元素对钢性能的影响机理、热处理工艺与微观组织的关系等。解题步骤涉及多个知识点的整合和对比分析，对学生的综合推理能力和机理解释能力要求很高，属于该题型框架内的最高难度等级。" + }, + { + "idx": 3384, + "question": "What is the approximate quenching process in the manufacturing route of round dies made from 9SiCr steel?", + "answer": "Quenching process: Heating temperature 850-870°C (oil quenching).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释具体的淬火工艺参数，答案需要文字描述具体的加热温度和淬火介质，属于简答题类型 | 知识层次: 题目考查的是对特定材料（9SiCr钢）淬火工艺参数的记忆和应用，属于直接套用工艺参数的知识点，不需要复杂的分析或综合过程。 | 难度: 在简答题中属于简单应用过程描述，只需直接回答淬火工艺的温度范围和介质，不需要额外的解释或详细步骤分析。题目要求的知识点较为基础，解题步骤简单，属于该题型内较低难度的题目。" + }, + { + "idx": 3385, + "question": "The large screwdriver requires the shank to be fine pearlite and the tip to be tempered martensite, with only one external heat source. How should it be processed?", + "answer": "Overall normalizing, local quenching + low-temperature tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过热处理工艺实现不同部位的组织要求，答案提供了具体的处理步骤，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求综合运用热处理知识（正火、局部淬火+低温回火）来实现不同部位的组织要求，需要理解不同热处理工艺对材料组织的影响，并进行推理分析。这涉及多步骤的工艺设计和组织-性能关系的综合分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3386, + "question": "What is the purpose of quenching and tempering in the process route of making round dies from 9SiCr steel?", + "answer": "Quenching and tempering are to obtain tempered martensite, ensuring high hardness and high wear resistance after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火和回火在9SiCr钢制圆模工艺路线中的目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对淬火和回火工艺目的的理解，需要将材料科学中的相变原理与具体工艺（9SiCr钢制圆模）相结合，属于概念关联和综合分析层次。虽然不涉及复杂计算，但需要理解热处理工艺对材料性能的影响机制。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及热处理工艺中的淬火和回火两个步骤，但只需要解释其目的和最终获得的组织性能（回火马氏体、高硬度和耐磨性），不需要进行多角度或深度关联性分析。解题步骤相对直接，主要考察对基础热处理概念的理解和应用。" + }, + { + "idx": 3387, + "question": "The bolts on the gear hobbing machine should have been made of 45 steel, but T12 steel was mistakenly used, and the annealing process for 45 steel was followed. What structure will be obtained in this case? What will be the performance?", + "answer": "Annealing: The structure will be lamellar pearlite and networked carbides. Steel with such a structure is prone to deformation and cracking during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下材料的结构和性能变化，答案提供了详细的文字解释和论述，没有涉及选择题的选项、判断题的对错判断或计算题的数值计算。 | 知识层次: 题目需要理解不同钢材（45钢和T12钢）的组成和性能差异，以及退火工艺对不同钢材结构的影响。这涉及到多步概念关联和综合分析，包括钢材的相变行为、退火工艺对微观结构的影响，以及这些结构对材料性能的影响。虽然不涉及复杂的计算或创新设计，但需要一定的推理和分析能力来解答。 | 难度: 在简答题中属于较高难度，需要综合运用材料科学知识分析错误选材和热处理工艺的影响。题目要求考生：" + }, + { + "idx": 3388, + "question": "The bolts on the gear hobbing machine should have been made of 45 steel, but T12 steel was mistakenly used. The high-temperature tempering process for 45 steel was still applied. What microstructure will be obtained in this case? What will be the performance?", + "answer": "High-temperature tempering: The microstructure consists of coarse tempered sorbite and retained austenite; Performance: Poor toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下获得的微观结构和性能，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解不同钢材（45钢和T12钢）在高温回火后的显微组织和性能变化，涉及多步概念关联和综合分析。虽然不涉及复杂计算，但需要对材料科学中的热处理原理和显微组织有较深入的理解和应用能力。 | 难度: 在简答题中属于较高难度，需要综合运用材料科学知识分析错误选材和热处理工艺对微观组织和性能的影响，涉及多步概念关联和性能预测。" + }, + { + "idx": 3389, + "question": "What is the general process of spheroidizing annealing in the manufacturing process of round dies made from 9SiCr steel?", + "answer": "Spheroidizing annealing process: heating temperature 790-810°C, isothermal temperature 700-720°C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释球化退火的一般过程，答案提供了具体的温度范围，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及具体的热处理工艺参数（加热温度和等温温度），需要理解spheroidizing annealing的基本原理并将其应用到特定材料（9SiCr steel）和特定应用（round dies manufacturing）中。虽然答案给出了具体的温度范围，但需要理解这些参数的选择是基于材料特性和工艺要求，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并描述具体的工艺参数和步骤，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3390, + "question": "What is the approximate tempering process in the process route of round dies made of 9SiCr steel?", + "answer": "Tempering process: 160-180°C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的回火工艺温度范围，需要提供具体的数值答案，属于简答题类型 | 知识层次: 题目考查的是对9SiCr钢圆模回火工艺温度范围的基础记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题的基础概念记忆题型中，该题目仅要求回答具体的回火温度范围（160-180°C），属于最基本的定义性知识复现。不需要进行概念解释或体系阐述，完全符合等级1\"基本定义简答\"的特征。同类题型中，这属于对单一数值参数的直接回忆，是热处理工艺中最基础的知识点之一。" + }, + { + "idx": 3391, + "question": "A batch of carbon tool steel workpieces were found to have insufficient hardness after quenching. It is estimated that either surface decarburization occurred or the cooling rate during quenching was too low. How to quickly determine the cause of the problem.", + "answer": "Metallographic examination.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来快速确定问题的原因，答案“Metallographic examination”是一个简短的解决方案描述，而不是从多个选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目要求通过金相检验快速确定硬度不足的原因，涉及对表面脱碳和淬火冷却速率不足的综合分析，需要将理论知识应用于实际问题解决，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析两种可能的原因（表面脱碳和淬火冷却速率过低）并提出快速确定问题的方法（金相检验）。虽然涉及多个概念，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 3392, + "question": "What is the purpose of spheroidizing annealing in the process route of making round dies with 9SiCr steel?", + "answer": "Spheroidizing annealing is to eliminate forging stress, obtain spheroidized pearlite and carbides, reduce hardness to facilitate machining, prepare the microstructure for quenching, and minimize deformation and cracking during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对spheroidizing annealing的目的进行文字解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求解释球化退火在9SiCr钢制圆模工艺路线中的目的，涉及消除锻造应力、获得球化珠光体和碳化物、降低硬度以利于加工、为淬火准备组织以及减少淬火变形和开裂等多个方面。这需要将球化退火的基本原理与具体工艺路线中的多个步骤和目的关联起来，进行多方面的综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅理解球化退火的基本目的，还需要综合说明其在9SiCr钢制圆模具体工艺路线中的多重作用（消除应力、获得球状组织、降低硬度、为淬火做准备、减少淬火变形等）。这需要将材料热处理原理与具体工艺应用深度结合，属于多角度分析论述的难度等级。" + }, + { + "idx": 3393, + "question": "Briefly describe the alloying principle of stainless steel.", + "answer": "Alloying principle: Adding alloying elements to form a stable, dense, and strong protective film on the surface of the steel, obtaining a single-phase structure in the steel, and increasing the electrode potential of the solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述不锈钢的合金化原理，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查不锈钢合金化原理的基本概念，主要涉及记忆和理解合金元素的作用及其对不锈钢性能的影响，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述不锈钢的合金化原理，涉及对合金元素作用、保护膜形成、单相结构和电极电位提升等基本概念的解释，但不需要深入分析或复杂体系阐述。这属于基础概念记忆层次中需要一定理解和组织能力的题目，但未达到复杂概念体系阐述的深度。" + }, + { + "idx": 3394, + "question": "The bolts on the gear hobbing machine should have been made of 45 steel, but T12 steel was mistakenly used instead, and the quenching process for 45 steel was still applied. What microstructure will be obtained in this case? What will the properties be like?", + "answer": "Quenching: The microstructure will consist of martensite, a significant amount of retained austenite, and a small amount of carbide. Properties: Martensite is hard and brittle, retained austenite has low hardness, resulting in non-uniform properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下（材料错误和热处理工艺）会得到什么显微组织和性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析不同钢材在相同淬火工艺下的微观组织形成及其性能影响，涉及材料选择、热处理工艺与微观组织的关系、性能预测等多方面知识的综合运用和推理分析。需要深入理解钢的淬透性、合金元素对相变的影响以及微观组织与性能的关联机制。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用材料科学知识进行多层次的推理分析。具体表现为：" + }, + { + "idx": 3395, + "question": "Why is Cr12MoV steel not stainless steel?", + "answer": "Because Cr is the main factor that makes steel corrosion-resistant. It can increase the electrode potential of steel. If its mass fraction is small (below 13 %), the electrode potential cannot be significantly increased, nor can a single-phase structure be formed, so the corrosion resistance of the steel cannot be significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Cr12MoV钢为什么不锈钢的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释Cr12MoV钢为什么不具备不锈钢的特性，涉及铬含量对钢的电极电位和腐蚀性能的影响机制，需要综合运用材料科学中的腐蚀原理和合金元素作用的知识进行推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对Cr12MoV钢的耐腐蚀性能进行机理深度解释，涉及电极电位、相结构等专业概念的运用，需要综合材料科学和腐蚀原理知识进行推理分析。虽然不需要全面分析复杂现象（如等级5的要求），但已超出基础概念解释层面，属于需要深入理解材料性能与成分关系的难度等级。" + }, + { + "idx": 3396, + "question": "After the wire drawing die made of high-carbon high-chromium steel wears out, the inner hole has a slight oversize. What heat treatment can be used to reduce the inner hole diameter?", + "answer": "Water quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述一种热处理方法，答案需要文字解释而非选择或判断 | 知识层次: 题目要求考生理解高碳高铬钢的热处理工艺及其对尺寸的影响，需要将材料的热处理原理与实际应用场景相结合，属于中等应用层次。考生需要知道水淬可以引起材料收缩，从而减小内孔直径，这涉及到多步思考和概念关联。 | 难度: 在简答题题型中，该题目属于中等应用层次，要求考生理解高碳高铬钢的特性、热处理工艺对尺寸的影响以及水淬的具体作用。虽然需要综合分析多个概念，但解题步骤相对直接，不需要多角度或深度关联性分析。因此，在简答题的框架内属于等级3的综合分析和说明难度。" + }, + { + "idx": 3397, + "question": "Why can't Cr12MoV steel be turned into stainless steel through heat treatment?", + "answer": "Because Cr is the main factor that makes steel corrosion-resistant. It can increase the electrode potential of the steel. If its mass fraction is small (below 13 %), the electrode potential cannot be significantly increased, nor can a single-phase structure be formed, so the corrosion resistance of the steel cannot be significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Cr12MoV钢不能通过热处理变成不锈钢，答案提供了详细的文字解释和论述，涉及材料科学原理和具体参数（如Cr的质量分数），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释Cr12MoV钢不能通过热处理转变为不锈钢的原因，涉及Cr元素对钢的耐腐蚀性能的影响机制，包括电极电位的变化和单相结构的形成条件。这需要综合运用材料科学中的合金元素作用原理、热处理对材料性能的影响以及腐蚀机制等多方面知识，进行推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对Cr12MoV钢的热处理限制进行机理深度解释。需要综合运用材料科学知识（如Cr元素对电极电位的影响、相结构形成条件等），并建立因果关系链说明为何无法通过热处理转变为不锈钢。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述层面，属于需要深入理解合金元素作用机制的典型等级4题目。" + }, + { + "idx": 3398, + "question": "Analyze the special effects of alloying elements (such as Cr, Mo, W, etc.) on improving the thermal strength of steel", + "answer": "Alloying elements (Cr, Mo, W, etc.) can increase the recrystallization temperature of steel, thereby improving its thermal strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析合金元素对钢热强度的特殊影响，需要文字解释和论述，而不是选择、判断或计算。答案也提供了文字解释，符合简答题的特征。 | 知识层次: 题目要求分析合金元素对钢热强度的特殊影响，涉及多种合金元素（Cr、Mo、W等）的作用机制，需要综合运用材料科学知识进行推理分析和机理解释，思维过程深度要求较高。 | 难度: 在简答题-复杂分析题型中，该题目要求对合金元素（Cr、Mo、W等）提高钢热强度的特殊效应进行机理深度解释。虽然题目给出了具体方向（提高再结晶温度），但仍需要考生综合运用材料科学知识，分析不同合金元素的作用机理及其对热强度的具体影响。这需要考生具备扎实的理论基础和一定的推理分析能力，但尚未达到全面分析复杂现象的最高难度等级。" + }, + { + "idx": 3399, + "question": "How is the range of high, medium, and low carbon steels usually divided?", + "answer": "High carbon steel: wC>0.60%, medium carbon steel: wC=0.25%~0.60%, low carbon steel: wC≤0.25%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释高、中、低碳钢的范围划分，答案以文字形式给出具体数值范围，属于需要文字解释的简答题类型 | 知识层次: 题目考查对高、中、低碳钢分类标准的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆并复述高、中、低碳钢的碳含量范围划分标准，不涉及概念解释或复杂体系阐述。这是该题型中最基础的知识点记忆要求，解题步骤简单直接，属于该题型框架内的最低难度级别。" + }, + { + "idx": 3400, + "question": "Analyze the special role of alloying elements (such as Cr, Si, Al, etc.) in improving the thermal stability of steel", + "answer": "Alloying elements (Cr, Si, Al, etc.) form dense protective oxide films at high temperatures, preventing the oxidation of steel and thereby enhancing thermal stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析合金元素在提高钢的热稳定性中的特殊作用，需要文字解释和论述，答案也是以论述形式给出，符合简答题的特征。 | 知识层次: 题目要求分析合金元素在提高钢的热稳定性中的特殊作用，涉及多种元素的协同效应、氧化膜形成机理以及高温环境下的保护机制。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对合金元素（Cr、Si、Al等）在提高钢的热稳定性方面的特殊作用进行机理深度解释。需要考生理解并阐述这些元素如何形成致密的保护性氧化膜，以及这一过程如何防止钢的氧化从而增强热稳定性。这涉及到对高温氧化机理和合金元素作用的深入理解，属于该题型中较高难度的题目，但尚未达到需要全面分析复杂现象的最高难度。" + }, + { + "idx": 3401, + "question": "What elements is carbon steel composed of?", + "answer": "Carbon steel is mainly composed of Fe and C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答碳钢由哪些元素组成，答案以文字解释形式给出，不需要选择、判断或计算 | 知识层次: 题目考查碳钢的基本组成元素，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆碳钢的主要组成元素（Fe和C），无需深入解释或描述概念关系，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 3402, + "question": "What are the characteristics of carbon steel and alloy steel in terms of performance?", + "answer": "Carbon steel is inferior to alloy steel in mechanical, physical, and chemical properties such as strength, wear resistance, toughness, and corrosion resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述碳钢和合金钢在性能上的特点，答案提供了详细的文字说明而非选择、判断或计算。 | 知识层次: 题目考查对碳钢和合金钢性能特点的基础概念记忆和理解，属于材料科学中钢材分类和基本性能的入门知识。 | 难度: 在简答题中属于中等难度，需要解释和描述碳钢和合金钢的性能特点，并进行简单的比较分析。虽然涉及多个性能指标，但不需要深入阐述复杂的概念体系或进行详细的论证。" + }, + { + "idx": 3403, + "question": "Why do the dimensions of some measuring tools change during storage and use?", + "answer": "The reason for the dimensional changes of measuring tools during storage and use is: due to the excessive amount of retained austenite after quenching and tempering, stress relaxation occurs during storage and use, causing the retained austenite to transform, thereby leading to dimensional changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么测量工具的尺寸在储存和使用过程中会发生变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释测量工具尺寸变化的原因，涉及淬火和回火后的残余奥氏体、应力松弛以及相变等复杂机理。这要求对材料科学中的相变理论和应力松弛有深入理解，并能将这些概念关联起来进行综合分析。思维过程需要推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释测量工具尺寸变化的原因，涉及淬火和回火后残余奥氏体的应力松弛和相变过程。这需要考生具备深入的材料科学知识，能够理解并解释复杂的材料行为机理。虽然题目没有要求全面分析多种复杂现象，但对机理的解释深度要求较高，因此属于等级4。" + }, + { + "idx": 3404, + "question": "What are the commonly used elements in alloy steel?", + "answer": "Alloy steel is mainly composed of elements such as Si, Mn, Cr, Ni, Mo, and V, in addition to Fe and C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举合金钢中常用的元素，答案以文字解释和论述的形式给出，没有提供选项或需要计算。 | 知识层次: 题目考查合金钢中常用元素的基础概念记忆，仅需列举常见元素名称，不涉及复杂分析或应用。 | 难度: 在简答题中属于基本定义简答，仅需列举合金钢中常用的元素，无需深入解释或复杂概念体系阐述。题目要求的知识点掌握深度较浅，解题步骤简单，属于该题型内最基础的难度等级。" + }, + { + "idx": 3405, + "question": "Explain the meaning of the steel grade 4Cr13", + "answer": "4Cr13 is a martensitic stainless steel, wc=0.4%, w=13%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢号4Cr13的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对钢材牌号的基本概念记忆和理解，包括成分和分类，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目要求解释4Cr13钢号的含义，只需记忆并复述钢号中各元素的含量及其代表的材料类型（马氏体不锈钢），不涉及概念间的联系或复杂体系的阐述。属于最基础的概念记忆层次，符合等级1的标准。" + }, + { + "idx": 3406, + "question": "How is the range of high, medium, and low alloy steels usually divided?", + "answer": "High alloy steel: wMe>10%, medium alloy steel: wMe=5%~10%, low alloy steel: wMe<5%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释高、中、低合金钢的范围划分，答案提供了具体的百分比范围，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对高、中、低合金钢分类标准的记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答高、中、低合金钢的划分标准，属于基础定义简答。题目不涉及概念解释或复杂体系阐述，仅需记忆并准确复述分类标准即可完成作答。在同题型内属于最基础的难度等级。" + }, + { + "idx": 3407, + "question": "What measures can be taken to ensure the long-term dimensional stability of measuring tools?", + "answer": "The method of cold treatment after quenching can be adopted to reduce the amount of retained austenite and achieve long-term dimensional stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出措施来确保测量工具的长期尺寸稳定性，答案提供了具体的处理方法并进行了简要解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释冷处理方法对测量工具长期尺寸稳定性的影响，涉及热处理工艺与材料性能的关联，需要理解残余奥氏体与尺寸稳定性的关系，属于中等应用层次的知识运用。 | 难度: 在简答题中属于中等难度，需要理解淬火后冷处理的概念及其对残余奥氏体的影响，并能综合说明该方法如何实现长期尺寸稳定性。虽然涉及多步概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3408, + "question": "Explain the meaning of the steel grade 16Mn", + "answer": "16Mn is a low-alloy structural steel, wc=0.16%, 10Mn=1.4%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释16Mn钢的含义，答案提供了文字解释和具体成分数据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对钢材牌号16Mn的基本概念记忆和理解，包括其成分和分类，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释16Mn钢的含义，但仅涉及基本成分（wc=0.16%，10Mn=1.4%）和分类（低合金结构钢），不需要深入分析或复杂概念体系的阐述。相较于等级1的基本定义简答，该题需要更多的描述性内容，但未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 3409, + "question": "Explain the meaning of the steel grade 20CrMnTi", + "answer": "20CrMnTi is a carburizing steel with wc=0.20%, wMn=1%, wCr=0.3%, wC=1.1%, wTi=0.09%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释20CrMnTi钢的含义，答案提供了详细的成分说明和文字解释，符合简答题的特征。 | 知识层次: 题目考查对钢材牌号含义的记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释20CrMnTi钢的含义，需要考生记忆并准确描述该钢种的化学成分及其含量范围。虽然涉及多个元素及其含量，但属于基础概念记忆范畴，不需要进行复杂的概念体系阐述或深入分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 3410, + "question": "Compare the alloying direction of high-temperature structural steel and room-temperature structural steel", + "answer": "The alloying direction of high-temperature structural steel focuses on adding elements that improve thermal strength and thermal stability (such as Cr, Mo, W, Si, Al, etc.), while the alloying direction of room-temperature structural steel pays more attention to improving strength, toughness, and other room-temperature properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种钢材的合金化方向，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求比较两种不同类型结构钢的合金化方向，涉及对不同合金元素作用的理解和应用，需要综合分析高温和室温条件下材料性能的需求差异，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对两种结构钢的合金化方向进行比较，但只需要进行基本的综合分析和说明，不需要多角度或深度关联性分析。解题步骤相对直接，主要涉及对两种钢合金化元素及其作用的解释和对比。" + }, + { + "idx": 3411, + "question": "Explain the meaning of the steel grade 08F", + "answer": "08F is a plain carbon structural steel, wc=0.08% rimmed steel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢号08F的含义，答案需要文字解释和论述，没有提供选项或要求计算 | 知识层次: 题目考查对钢材牌号基本概念的记忆和理解，仅需解释08F的含义和成分，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求解释钢号08F的含义，答案只需给出基本成分（wc=0.08%）和钢种类型（沸腾钢）即可，不涉及复杂概念体系或深入分析。这完全符合基础概念记忆层次的要求，是同类题型中最简单的考查形式。" + }, + { + "idx": 3412, + "question": "What is the meaning of the commonly referred terms 'ordinary steel', 'quality steel', and 'high-quality steel'?", + "answer": "It mainly refers to the difference in the mass fraction of phosphorus and sulfur. Ordinary steel: $w_{P}\\\\leqslant0.045\\\\%$ $w_{\\\\mathrm{S}}\\\\leqslant0.05\\\\%;$ quality steel: $\\\\scriptstyle w_{\\\\mathrm{P}}\\\\leq0.035\\\\%,w_{\\\\mathrm{S}}\\\\leq0.035\\\\%;$ high-quality steel: $w_{\\\\mathrm{P}}{\\\\le}0.025\\\\%$ $w_{\\\\mathrm{S}}{\\\\leq}0.025\\\\%$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语的含义，答案提供了详细的文字说明和具体数值，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对普通钢、优质钢和高级优质钢的基本定义和分类的记忆，主要涉及磷和硫的质量分数标准，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求解释\"ordinary steel\"、\"quality steel\"和\"high-quality steel\"三个术语的含义，并给出具体的磷硫含量标准。这属于最基础的概念记忆和简单分类，不需要进行概念间的比较或深入解释，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3413, + "question": "Explain the meaning of the steel grade T12A", + "answer": "T12A is a carbon tool steel, wc=1.2% high-grade quality steel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢号T12A的含义，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对钢材牌号T12A的基本定义和成分的记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求回答基本定义（T12A钢的碳含量和品质等级），属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单直接的记忆性知识考查。" + }, + { + "idx": 3414, + "question": "Explain the meaning of the steel grade 9SiCr", + "answer": "9SiCr is a low-alloy tool steel with wc=0.9%, ws=1%, Wc=1.1%, wMn=0.45%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号9SiCr的含义，答案提供了详细的成分描述和文字解释，符合简答题的特征。 | 知识层次: 题目考查对特定钢号9SiCr的基本成分和分类的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释9SiCr钢的含义，需要记忆并准确表述其化学成分和分类（低合金工具钢），但不需要深入分析或比较多个概念体系。这属于基础概念记忆层次中的中等难度，比单纯的定义简答（等级1）要求稍高，但远未达到复杂概念体系阐述（等级3）的程度。" + }, + { + "idx": 3415, + "question": "Explain the meaning of the steel grade 1Cr18Ni9Ti", + "answer": "1Cr18Ni9Ti is an austenitic stainless steel, wc=0.1%, wc=18%, WN=9%, wv=0.7%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释1Cr18Ni9Ti钢的含义，答案提供了详细的成分和特性描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对不锈钢牌号命名规则和成分的基本记忆，属于基础概念的记忆和理解层次，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释1Cr18Ni9Ti钢号的含义，需要学生记忆并描述该钢种的化学成分（如碳含量0.1%、铬含量18%、镍含量9%等）及其所属类别（奥氏体不锈钢）。虽然需要记忆多个数据点，但不需要深入阐述复杂概念体系或进行多步骤推理，符合等级2\"概念解释和描述\"的特征。相比等级1的纯定义复述（如仅回答\"这是奥氏体不锈钢\"），该题对记忆准确性和细节描述的要求略高，但未达到等级3的体系化阐述要求。" + }, + { + "idx": 3416, + "question": "Explain the meaning of the steel grade 3Cr2W8", + "answer": "3Cr2W8V is a hot extrusion die steel with wc=0.3%, wcr=2.5%, ww=8%, and wv=0.3%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号3Cr2W8的含义，答案提供了详细的成分说明和文字解释，符合简答题的特征 | 知识层次: 题目考查对钢材牌号命名规则和成分的基本记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释钢材牌号3Cr2W8的含义，需要考生记忆并准确描述该钢材的化学成分（碳、铬、钨、钒的含量）及其用途（热挤压模具钢）。虽然涉及多个元素含量的记忆，但整体仍属于基础概念记忆范畴，不需要复杂的推导或体系阐述。相比等级1的基本定义简答，该题需要更详细的概念解释，但未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 3417, + "question": "Explain the meaning of the steel grade Cr12MoV", + "answer": "Cr12MoV is a cold work die steel with wc=1.55%, wc=12%, WM=0.5%, wy=0.25%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Cr12MoV钢的含义，答案提供了详细的化学成分和用途说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对特定钢号Cr12MoV的基本成分和分类的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释特定钢号Cr12MoV的含义，涉及化学成分的列举和基本用途说明。这属于概念解释和描述的范畴，需要记忆特定元素含量和钢种分类知识，但不需要复杂的体系阐述或深入分析。相比等级1的纯定义复述（如仅回答\"冷作模具钢\"），该题需要更具体的成分描述；相比等级3的复杂概念体系（如解释合金元素相互作用机理），该题的认知要求较为基础。" + }, + { + "idx": 3418, + "question": "Explain the meaning of the steel grade 00Cr18Ni10", + "answer": "00Cr18Ni10 is an austenitic stainless steel, with Wc≤0.03%, WCr=18%, WNi=10%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢材牌号00Cr18Ni10的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对不锈钢牌号命名规则的基本概念记忆和理解，需要解释牌号中各元素的含义及其含量范围，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对钢号00Cr18Ni10的基本成分进行解释，属于最基础的定义简答。题目仅涉及单一概念的记忆性知识（化学成分百分比），不需要进行概念间的联系或复杂阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3419, + "question": "Explain the meaning of the steel grade W6Mo5Cr4V2", + "answer": "W6Mo5Cr4V2 is a high-speed steel, wc=0.85%, ww=6%, WMo=5%, wc=4%, wv=3%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释W6Mo5Cr4V2钢号的含义，答案提供了详细的成分说明和文字解释，符合简答题的特征。 | 知识层次: 题目考查对高速钢牌号W6Mo5Cr4V2的基本成分和含义的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释特定钢号的成分含义，需要记忆并准确表述各元素含量，但不需要深入分析或复杂推导。属于基础概念记忆层次中的中等难度，比单纯的定义简答（等级1）稍复杂，但远未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 3420, + "question": "Which commonly used alloying elements belong to the γ-phase field narrowing elements?", + "answer": "Niobium, boron, and zirconium narrow the γ-phase field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举特定类型的合金元素，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对γ相区缩小元素的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。虽然需要列举具体的合金元素（Niobium, boron, zirconium），但不需要深入分析其作用机制或与其他概念的关联。题目主要考察对γ相区缩小元素这一基础概念的掌握程度，属于中等偏下的记忆性知识要求。" + }, + { + "idx": 3421, + "question": "Explain the meaning of the steel grade 5CrMnMo", + "answer": "5CrMnMo is a hot forging die steel, wc=0.5%, 0.75Cr, 10Mm=1.4%, wMo=0.25%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释5CrMnMo的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对钢材牌号的基本概念记忆和理解，包括化学成分的表示方法和含义，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释5CrMnMo钢的含义，需要考生记忆并描述该钢种的成分及其用途（热锻模具钢）。虽然涉及多个元素含量的记忆，但整体仍属于基础概念记忆范畴，不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 3422, + "question": "Explain the meaning of the steel grade GCr15SiMn", + "answer": "GCr15SiMn is a rolling bearing steel, wc=1.5%, Wc=1%, wsi=0.5%, WM=1.05%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号GCr15SiMn的含义，答案提供了详细的文字解释和成分说明，属于需要文字论述的简答题类型。 | 知识层次: 题目考查对特定钢号GCr15SiMn的基本成分和分类的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要记忆具体的化学成分和百分比，但不需要复杂的推理或体系阐述。题目要求解释钢号GCr15SiMn的含义，属于对基础概念的记忆和简单描述，符合等级2的标准。" + }, + { + "idx": 3423, + "question": "Which commonly used alloying elements belong to the γ-phase expanding elements?", + "answer": "Nickel, manganese, cobalt, carbon, nitrogen, and copper expand the γ-phase region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举γ相扩展元素，答案以文字形式给出具体元素名称，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对γ相扩展元素的记忆和分类，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举并解释γ相扩展元素，这需要学生对合金元素的基本分类和相图知识有一定记忆和理解，但不需要进行复杂的体系阐述或多概念交叉分析。属于基础概念记忆层次中需要稍加解释的类型，符合等级2的标准。" + }, + { + "idx": 3424, + "question": "Which of these elements can form infinite solid solutions with Fe? What are the conditions?", + "answer": "Manganese, nickel, and cobalt can form infinite solid solutions with γ-Fe. Whether alloying elements expand or contract the γ region mainly depends on factors such as their lattice type, atomic size, electronic structure, and electrochemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪些元素可以与Fe形成无限固溶体，并说明条件。答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目不仅需要记忆哪些元素能与Fe形成无限固溶体，还需要理解并解释形成条件（如晶格类型、原子尺寸、电子结构等），涉及多个概念的关联和综合分析。 | 难度: 在简答题题型中，该题目属于较高难度等级。题目要求不仅列举能与γ-Fe形成无限固溶体的元素，还需要说明形成条件，涉及多个关键因素的分析（晶格类型、原子尺寸、电子结构、电化学性质等）。这需要学生对固溶体形成原理有深入理解，并能综合运用材料科学基础知识进行多角度论述。相比只需简单解释的简答题（等级3），本题需要更系统的知识整合和更全面的分析论述能力。" + }, + { + "idx": 3425, + "question": "Which commonly used alloying elements belong to the elements that close the γ region?", + "answer": "Silicon, chromium, tungsten, molybdenum, phosphorus, vanadium, titanium, and aluminum close the γ region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举出能够关闭γ区域的常用合金元素，答案以列举形式给出，需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对合金元素分类的基本概念记忆，只需回答哪些元素会关闭γ区域，不需要深入分析或解释其机理。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求列举出关闭γ区域的常见合金元素，不需要进行概念解释或复杂体系阐述。回答仅需记忆性知识，无需深入分析或推理步骤，符合等级1的基本定义简答特征。" + }, + { + "idx": 3426, + "question": "Explain the meaning of the steel grade 55Si2Mn", + "answer": "55Si2Mn is a spring steel, wc=0.55%, ws=1.75%, WMn=0.75%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢材牌号的含义，答案提供了详细的成分说明，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对钢材牌号命名规则的基本概念记忆和理解，只需解释牌号中各元素的含义及其含量，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求解释钢号55Si2Mn的含义，答案仅需提供该钢种的类型（弹簧钢）及其主要化学成分百分比，属于最基础的概念记忆性知识，无需深入解释或复杂论述。" + }, + { + "idx": 3427, + "question": "What is the practical significance of these elements' influence on the γ region?", + "answer": "Its engineering practical significance: For example, to ensure that the steel has good corrosion resistance (such as stainless steel), it is necessary to obtain a single-phase structure at room temperature. This is achieved by applying the above-mentioned principles, controlling the types and amounts of alloying elements to obtain single-phase austenite or ferrite and other single structures in the steel under room temperature conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释元素的γ区域影响的工程实际意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素对γ区影响的工程实际意义，需要将基本原理与实际应用相结合，涉及多步概念关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在简答题中属于中等难度，需要综合分析和说明元素对γ区的影响及其工程实践意义。题目要求理解合金元素对钢相结构的影响，并能结合实际应用（如不锈钢的单相结构需求）进行解释。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3428, + "question": "Explain the meaning of the steel grade ZGMn13", + "answer": "ZGMn13 is a high manganese wear-resistant steel, wc=1.15%, wMn=13%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释ZGMn13钢的含义，答案提供了详细的成分和特性描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对特定钢号ZGMn13的基本定义和成分的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求解释ZGMn13钢的基本含义和化学成分，属于基础概念记忆的范畴。题目不涉及复杂的概念体系或深入的论述，仅需简单回答定义和关键参数即可。因此，在同题型内属于最基本的难度等级。" + }, + { + "idx": 3429, + "question": "What are the differences in heat treatment processes between alloy steel and carbon steel?", + "answer": "Due to the influence of alloying elements on critical temperature, point E, and point S, the heat treatment temperature of alloy steel differs from that of carbon steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢和碳钢在热处理过程中的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较合金钢和碳钢的热处理工艺差异，涉及合金元素对临界温度、E点和S点的影响，需要理解并关联多个概念，进行综合分析。这超出了简单记忆或直接套用的层次，但尚未达到复杂分析或高级综合所需的深度推理和创新应用。 | 难度: 在简答题题型中，该题目要求对合金钢和碳钢的热处理工艺差异进行多角度分析论述。需要考生理解合金元素对临界温度、E点和S点的影响，并能够综合这些因素说明热处理温度的差异。这超出了简单的概念复述或单一因素分析，属于需要整合多个知识点的中等偏上难度题目。" + }, + { + "idx": 3430, + "question": "What are the forms of alloying elements in steel?", + "answer": "The forms of alloying elements in steel are: (1) dissolved in ferrite, austenite, or martensite, existing as solute; (2) forming strengthening phases; (3) existing in a free state; (4) forming non-metallic inclusions with impurities such as oxygen, nitrogen, and sulfur in the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释合金元素在钢中的存在形式，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查合金元素在钢中存在形式的基本分类和记忆，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举合金元素在钢中的存在形式，涉及多个具体分类（如固溶体、强化相、游离态等），但不需要深入阐述各形式间的相互作用机制或复杂原理。虽然比单纯的定义简答（等级1）要求更高，但尚未达到需要系统阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 3431, + "question": "Explain the practical significance of commonly added alloying elements in steel by combining their effects on the heating transformation of steel.", + "answer": "Effect on heating transformation: Alloying elements (except nickel and cobalt) can slow down the austenitization process and inhibit austenite grain growth; Significance: Except for manganese steel, alloy steels are less prone to overheating during heating, which is beneficial for obtaining fine martensite after quenching, appropriately increasing heating temperature to enhance hardenability, and reducing the tendency of deformation and cracking during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素在钢中的实际意义，并结合其对钢加热转变的影响进行论述。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求结合合金元素对钢加热转变的影响来解释其实际意义，这需要综合运用材料科学中的相变理论、合金元素作用机理等知识，进行推理分析和机理解释。不仅涉及多个知识点的关联，还需要深入理解合金元素对钢性能的影响机制，属于较高层次的认知要求。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用合金元素对钢加热转变的影响机理，并推导出实际生产中的多重意义（如过热控制、淬火组织优化、变形控制等）。需要同时掌握材料相变理论和工程应用知识，并能建立多因素间的逻辑关联，属于该题型下对综合分析能力要求最高的复杂现象全面分析层级。" + }, + { + "idx": 3432, + "question": "What is the influence law of alloying elements on the critical temperature, E point, and S point of the iron-carbon phase diagram?", + "answer": "After the addition of alloying elements, they affect the critical temperature, E point, and S point. Elements that expand the austenite region generally lower the A3 and A1 temperatures and shift the S point and E point to the lower left; elements that shrink the austenite region generally raise the A3 and A1 temperatures and shift the S point and E point to the upper left.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素对铁碳相图中临界温度、E点和S点的影响规律，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析合金元素对铁碳相图中临界温度、E点和S点的影响规律，涉及多个概念的综合应用和关联分析，需要理解合金元素对相图的具体影响机制，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合理解合金元素对铁碳相图中临界温度、E点和S点的影响规律，并进行多角度分析论述。题目要求不仅说明影响方向（如升高或降低温度），还需解释元素对相区的影响（扩大或缩小奥氏体区）及其对相图关键点的具体移动方向（如左下或左上）。这需要学生掌握较深的概念关联和综合分析能力，属于多角度分析论述的层次。" + }, + { + "idx": 3433, + "question": "Explain the meaning of the steel grade 38CrMoAlA", + "answer": "38CrMoAlA is a nitriding-specific steel (quenched and tempered steel), wc=0.38%, wc=1.00%, WM=0.2%, 0A=0.9%, wsi=0.3%, wM=0.45%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释38CrMoAlA钢的含义，答案提供了详细的文字解释和成分说明，属于需要文字论述的简答题类型。 | 知识层次: 题目考查对特定钢号成分和分类的记忆，属于基础概念的记忆性知识 | 难度: 在简答题中属于中等难度，需要解释钢号的含义并列举各元素含量，但不需要深入分析或复杂推导。" + }, + { + "idx": 3434, + "question": "Explain the practical significance of adding common alloying elements to steel based on their influence on the kinetic curves during the cooling transformation of steel.", + "answer": "Influence on cooling transformation: The addition of alloying elements (except cobalt and aluminum) shifts the position of the isothermal transformation C-curve of undercooled austenite to the right. Strong carbide-forming elements not only shift the C-curve to the right but also alter its shape, resulting in the separation of the pearlite and bainite transformation curves. Therefore, the effects of adding alloying elements are: (1) improving hardenability; (2) carbide-forming elements can also enhance the wear resistance, tempering stability, and red hardness of steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素对钢冷却转变动力学曲线的影响及其实际意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素对钢冷却转变动力学曲线的影响及其实际意义，涉及多概念关联（如C曲线移动、碳化物形成元素的作用）、机理解释（硬度和耐磨性提升机制）以及综合分析（合金元素对钢性能的多重影响），属于需要深度理解和推理分析的复杂分析层次。 | 难度: 在简答题的复杂分析层次中，该题目要求综合运用合金元素对钢冷却转变动力学曲线的影响机理，解释其实际意义。需要深入理解C曲线的移动和形状变化，以及这些变化如何具体改善钢的性能（如淬透性、耐磨性等）。这种全面分析复杂现象的要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 3435, + "question": "What is the difference between the microstructure of alloy steel and carbon steel after heat treatment?", + "answer": "There are also differences in the microstructure after heat treatment, for example, 4Cr13, due to Cr shifting the E point to the left, its microstructure becomes that of a hypereutectoid steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢和碳钢在热处理后的微观结构差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较合金钢和碳钢在热处理后的微观结构差异，并举例说明Cr元素对微观结构的影响。这需要理解合金元素对相图的影响（如E点移动），并能将这一知识应用到具体合金（4Cr13）的分析中。涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中，该题目要求对合金钢和碳钢的热处理后的显微组织差异进行多角度分析论述。需要理解Cr元素对相图的影响（E点左移），并能具体举例说明（如4Cr13转变为过共析钢组织）。这涉及材料科学中的相变原理、合金元素作用机制等综合知识，解题步骤较为复杂，属于该题型框架内较高难度的题目。" + }, + { + "idx": 3436, + "question": "Combining ordinary low-alloy high-strength steels of different strength levels, explain the characteristics of their compositional changes?", + "answer": "While using Mn for solid solution strengthening, the carbon mass fraction was adjusted and the types of alloying elements were increased.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同强度级别的普通低合金高强度钢的成分变化特点，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释不同强度级别低合金高强度钢的成分变化特点，涉及对合金元素作用的综合分析（如Mn的固溶强化作用、碳含量调整和其他合金元素的增加），需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析和论述不同强度级别低合金高强度钢的成分变化特点，涉及多种合金元素的调整和相互作用，要求考生具备较强的概念关联和综合分析能力。" + }, + { + "idx": 3437, + "question": "Combining ordinary low-alloy high-strength steels of different strength grades, explain the role of each element in them?", + "answer": "The role of alloying elements in hot-rolled steel: solution strengthening; in normalized steel: in addition to solution strengthening, it also plays a role in dispersion strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同元素在低合金高强度钢中的作用，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释不同强度等级低合金高强度钢中各元素的作用，涉及多种元素的强化机制（固溶强化和弥散强化）在不同热处理状态（热轧和正火）下的表现。需要将合金元素的作用与材料处理工艺和性能关联起来，属于多概念关联和综合分析。 | 难度: 在简答题中属于较高难度，需要综合分析和论述不同强度等级低合金高强度钢中各元素的作用，涉及溶液强化和弥散强化等多重机制，要求考生能够从多角度进行解释和关联分析。" + }, + { + "idx": 3438, + "question": "What are the carbon contents of engineering structural steel, carburizing steel, quenched and tempered steel, spring steel, and bearing steel?", + "answer": "The mass fraction of carbon in engineering structural steel is relatively low, mostly ranging from 0.1% to 0.2%. The mass fraction of carbon in carburizing steel is generally 0.1% to 0.25%. The mass fraction of carbon in most quenched and tempered steels ranges from 0.25% to 0.5%. The mass fraction of carbon in spring steel is generally 0.6% to 0.9%. The mass fraction of carbon in bearing steel ranges from 0.95% to 1.15%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对不同类型钢材的碳含量进行描述和解释，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目主要考查对不同类型钢材碳含量的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举五种不同类型钢材的碳含量范围，这需要学生对各类钢材的基本特性有清晰的记忆和理解。虽然涉及多个知识点，但每个知识点都是基础概念的记忆性内容，不需要复杂的分析或推理过程。解题步骤主要是回忆和列举，没有涉及概念间的复杂关联或深入阐述。因此，在简答题题型框架内属于中等难度（等级2）。" + }, + { + "idx": 3439, + "question": "What are the main reasons for the different carbon contents in engineering structural steel, carburizing steel, quenched and tempered steel, spring steel, and bearing steel?", + "answer": "Engineering structural steel is mainly used for engineering structures, where the strength requirement is not high, but the weldability requirement is high, so the mass fraction of carbon is low. The carbon content of carburizing steel cannot be high to ensure high toughness in the core. Quenched and tempered steel should have good comprehensive mechanical properties after quenching and tempering, meaning not only high strength but also good toughness, so medium carbon steel is used. Spring steel requires high elastic limit and fatigue strength, so the mass fraction of carbon cannot be too low, but if it is too high, brittleness increases. Bearing steel requires high hardness and high wear resistance, so a high mass fraction of carbon is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同钢材中碳含量差异的主要原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同类型钢材的碳含量差异进行解释，涉及多个概念的综合分析和关联，需要理解不同钢材的性能要求与碳含量之间的关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求考生不仅理解不同种类钢材的基本特性，还需要分析碳含量与材料性能之间的关联性，并从工程应用的角度进行综合论述。这需要考生具备较强的概念关联能力和综合分析能力，能够从多个角度（如力学性能、工艺性能、应用场景等）进行深入分析，因此属于该题型框架内较高的难度等级。" + }, + { + "idx": 3440, + "question": "If 20CrMnTi is used as carburizing steel, what are the differences in its mechanical properties, process performance, and process characteristics? Why?", + "answer": "20CrMnTi is a medium-hardenability carburizing steel used for manufacturing larger-sized parts that bear moderate loads. The carburizing temperature is 930~950°C, the quenching temperature is 870~890°C (oil quenching), and the tempering temperature is 190°C. The differences mainly result from the types and contents of alloying elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释20CrMnTi作为渗碳钢在机械性能、工艺性能和工艺特性上的差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析20CrMnTi作为渗碳钢在机械性能、工艺性能和工艺特性方面的差异，并解释原因。这需要理解合金元素的类型和含量对材料性能的影响，涉及多步分析和概念关联，但不需要过于复杂的推理或创新应用。 | 难度: 在简答题中属于较高难度，需要从机械性能、工艺性能和工艺特点三个维度进行多角度分析论述，并解释合金元素类型和含量对性能差异的影响机制，涉及材料科学、热处理工艺和合金化原理的综合运用。" + }, + { + "idx": 3441, + "question": "If 20Cr is used as carburizing steel, what are the differences in its mechanical properties, process performance, and process characteristics? Why?", + "answer": "20Cr is a low hardenability carburizing steel, suitable for manufacturing small wear-resistant parts with low stress. The carburizing temperature is 900~920°C, the quenching temperature is 860~890°C (water quenching or oil quenching), and the tempering temperature is 180°C. The differences are mainly due to the influence of the types and content of alloying elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释20Cr作为渗碳钢在机械性能、工艺性能和工艺特性上的差异，并说明原因。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析20Cr作为渗碳钢在机械性能、工艺性能和工艺特性上的差异，并解释原因。这需要理解合金元素类型和含量对材料性能的影响，涉及多步分析和概念关联，但不需要过于复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对20Cr钢的机械性能、工艺性能和工艺特点进行多角度的分析论述，涉及合金元素类型和含量的影响，需要综合运用材料科学和热处理知识进行详细解释。虽然不涉及深度关联性分析，但已超出基础概念解释的范畴，属于中等偏上的难度。" + }, + { + "idx": 3442, + "question": "If Cr12MoV steel is selected to manufacture cold work molds, what heat treatment process should be formulated? Why?", + "answer": "For Cr12MoV steel used in cold work molds, the heat treatment process is the primary hardening method: quenching at 980～1030‰ and tempering at 200-270°C. Reason: The primary hardening method of Cr12MoV steel can provide the steel with high hardness and wear resistance, minimal heat treatment deformation, and most molds made of Cr12MoV steel without special requirements adopt this method.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Cr12MoV钢用于冷作模具时应采用的热处理工艺及其原因，答案提供了详细的工艺参数和理论依据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据特定材料（Cr12MoV钢）的应用场景（冷作模具）制定热处理工艺，并解释原因。这涉及多步分析：首先需要理解该材料的特性，其次要结合冷作模具的使用要求（高硬度、耐磨性、低变形），最后综合这些因素选择合适的热处理工艺（淬火+低温回火）。虽然不需要复杂的机理分析或创新设计，但需要将材料特性、工艺参数和应用需求关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明Cr12MoV钢的热处理工艺及其原因。题目要求考生理解该钢种的特性和应用场景，并能够关联热处理工艺与材料性能之间的关系。虽然涉及多步概念关联，但不需要进行多角度或深度关联性分析，因此属于等级3。" + }, + { + "idx": 3443, + "question": "What are the differences in heat treatment between engineering structural steel, carburizing steel, quenched and tempered steel, spring steel, and bearing steel? Why?", + "answer": "Engineering structural steel is used in the hot-rolled normalized state. Carburizing steel undergoes carburizing, quenching + low-temperature tempering. Quenched and tempered steel uses medium-carbon steel and is subjected to quenching and tempering. Spring steel undergoes quenching + medium-temperature tempering. Bearing steel undergoes quenching + low-temperature tempering. Engineering structural steel is mainly used for engineering structures where high strength is not required, but good weldability is essential, hence it is used in the hot-rolled normalized state. Carburized parts require certain toughness in the core, so carburizing, quenching + low-temperature tempering is applied. Quenched and tempered parts should possess good comprehensive mechanical properties after treatment, meaning not only high strength but also good toughness, hence quenching and tempering is used. Spring parts require high elastic limit and fatigue strength, so quenching + medium-temperature tempering is applied. Bearings require high hardness and wear resistance, hence quenching + low-temperature tempering is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型钢材的热处理差异进行详细解释和论述，答案提供了详细的文字说明和原因分析，符合简答题的特征。 | 知识层次: 题目要求对不同类型钢材的热处理工艺进行详细比较，并解释其背后的原因。这需要综合运用材料科学中的热处理原理、材料性能要求以及实际应用场景等多方面知识，进行推理分析和机理解释。不仅涉及记忆和理解，还需要深入分析和综合应用相关知识。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求考生综合运用材料科学知识，对不同类型钢材的热处理工艺进行详细解释，并分析其背后的机理和原因。这不仅需要掌握各种钢材的基本热处理工艺，还需要理解这些工艺如何影响材料的性能和应用场景。此外，题目还要求考生进行推理分析，解释为什么不同的钢材需要采用不同的热处理工艺，这进一步增加了题目的复杂性和难度。因此，该题目在简答题题型中属于最高难度等级。" + }, + { + "idx": 3444, + "question": "If Cr12MoV steel is selected to manufacture a stamping die with certain hot hardness requirements, what heat treatment process should be formulated? Why?", + "answer": "When Cr12MoV steel is used to make a stamping die with certain hot hardness requirements, the secondary hardening method can be adopted, i.e., quenching at 1050～1100℃ followed by multiple tempering at 500-520℃, which can increase the hardness to 60～62HRC. Reason: The secondary hardening method of Cr12MoV steel is suitable for applications with higher working temperatures (400～500℃) or requiring hot hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Cr12MoV钢的热处理工艺及其原因，答案提供了详细的工艺步骤和理论依据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析Cr12MoV钢的热处理工艺选择，并解释其原理。这需要综合运用材料科学知识，包括钢的热处理工艺、二次硬化机制、热硬度要求等，并进行推理分析。题目不仅考查了基本概念的记忆，还要求深入理解材料性能与工艺之间的关系，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于复杂分析的知识层次，要求综合运用材料科学知识、推理分析热处理工艺选择的原因，并进行机理解释。具体来说，题目不仅要求考生掌握Cr12MoV钢的热处理工艺参数（如淬火和回火温度），还需要理解二次硬化方法的适用条件及其背后的科学原理（如高温工作环境下的热硬度需求）。这种需要多维度分析和深度解释的题目，在简答题中属于最高难度等级。" + }, + { + "idx": 3445, + "question": "Explain the microstructural changes of high-speed steel during heat treatment", + "answer": "Annealing not only reduces hardness, facilitating machining, but also obtains a granular structure with uniformly distributed carbides, preparing the microstructure for subsequent quenching; quenching results in martensite + granular carbides + a considerable amount of retained austenite; triple tempering yields tempered martensite + granular carbides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释高速钢在热处理过程中的微观结构变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高速钢在热处理过程中的微观结构变化，涉及多个热处理步骤（退火、淬火、回火）及其对应的微观结构转变（如马氏体、碳化物分布、残余奥氏体等）。这需要综合运用材料科学知识，理解不同热处理工艺对微观结构的影响机制，并进行推理分析。因此，该题目属于复杂分析层次。 | 难度: 在简答题的复杂分析题型中，该题目要求对高速钢热处理过程中的微观结构变化进行机理深度解释。需要综合运用相变理论、碳化物分布知识，并详细描述从退火到淬火再到三次回火的完整工艺链中的组织演变过程。虽然不涉及多因素交互作用的全面分析（等级5特征），但对各阶段微观结构转变的机理解释已达到较高深度，符合等级4的深度解释要求。" + }, + { + "idx": 3446, + "question": "Since high-speed steel already has good red hardness, why is high-speed steel generally not used for die-casting molds, and why was the steel grade 3Cr2W8V developed?", + "answer": "Although high-speed steel has high hardness, high wear resistance, and red hardness, its toughness and thermal fatigue properties are inferior to those of 3Cr2W8V, so high-speed steel is not used for die-casting molds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么高速钢不用于压铸模具以及3Cr2W8V钢的开发原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解高速钢和3Cr2W8V钢的基本性能特点，还需要分析比较它们的韧性、热疲劳性能等综合性能差异，并解释为什么这些差异导致高速钢不适合用于压铸模具。这涉及到多个概念的关联和综合分析，以及性能与应用的推理分析。 | 难度: 在简答题题型中，该题目要求对高速钢和3Cr2W8V钢的性能进行对比分析，并解释为什么高速钢不适用于压铸模具。这需要考生不仅掌握两种材料的基本性能特点，还需要理解红硬性、韧性和热疲劳性能等专业概念，并能进行机理层面的解释。虽然题目涉及的知识点较为专业，但并未要求对复杂现象进行全面分析或提出创新性见解，因此属于等级4的难度。" + }, + { + "idx": 3447, + "question": "Describe the basis for formulating the heat treatment process of high-speed steel", + "answer": "The basis is the chemical composition and the transformation curve of undercooled austenite in high-speed steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述高速钢热处理工艺制定的基础，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目要求解释高速钢热处理工艺制定的基础，涉及化学成分和过冷奥氏体转变曲线的知识。这需要将多个概念关联起来进行综合分析，而不仅仅是记忆或简单应用。虽然不涉及复杂的计算或深度推理，但需要一定的理解和应用能力来整合相关知识。 | 难度: 在简答题中属于中等难度，需要理解高速度钢的化学成分和过冷奥氏体转变曲线这两个关键概念，并进行综合分析来说明热处理工艺制定的依据。虽然涉及多个知识点，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3448, + "question": "List several types of ledeburitic steel you are familiar with?", + "answer": "High-speed steel, Cr12, Cr12MoV, etc. all belong to ledeburitic steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出几种熟悉的莱氏体钢类型，答案以文字形式列举具体例子，属于需要简要回答的简答题类型。 | 知识层次: 题目考查对莱氏体钢（ledeburitic steel）分类的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求列举几种莱氏体钢的常见类型，属于最基本的概念记忆和简单列举。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单的知识再现型问题。" + }, + { + "idx": 3449, + "question": "If 20Cr2Ni4W is used as carburizing steel, what are the differences in its mechanical properties, process performance, and process characteristics? Why?", + "answer": "20Cr2Ni4W is a high-hardenability carburizing steel used for manufacturing heavy-duty, large-section components requiring high wear resistance and good toughness. The carburizing temperature is 900~950°C, the quenching temperature is 880°C, and a secondary quenching is performed at 780°C, with a tempering temperature of 190°C. The differences are mainly due to the influence of the types and contents of alloying elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释20Cr2Ni4W作为渗碳钢在机械性能、工艺性能和工艺特性方面的差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析20Cr2Ni4W作为渗碳钢在机械性能、工艺性能和工艺特性方面的差异，并解释原因。这需要综合运用材料科学知识，包括合金元素的影响、热处理工艺对性能的影响等，涉及多方面的概念关联和推理分析。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求对20Cr2Ni4W作为渗碳钢的机械性能、工艺性能和工艺特性进行全面的比较分析，并解释其原因。这需要综合运用材料科学、热处理工艺和合金元素影响等多方面的知识，进行深入的推理和机理解释。解题步骤复杂，涉及多个知识点的综合应用，对学生的分析能力和知识掌握深度要求较高。因此，在同题型内属于最高难度等级。" + }, + { + "idx": 3450, + "question": "5CrNiMo, 3Cr2W8V, and H11 (or H13) all belong to hot-work die steels. Are there any differences in their usage? Why?", + "answer": "Yes, there are differences. Their total alloying element contents are low-alloy (5CrNiMo), medium-alloy (H11), and high-alloy (3Cr2W8V), respectively. 5CrNiMo is used for hot forging dies, H11 replaces 3Cr2W8V for small and medium-sized mechanical forging dies and hot extrusion dies with relatively low operating temperatures, while 3Cr2W8V is used for hot extrusion dies. The reason for their differences in usage lies in the varying types and amounts of alloying elements, which result in different levels of thermal strength, thermal fatigue resistance, and high-temperature oxidation resistance, hence their different applications.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同热作模具钢的使用差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同热作模具钢的使用差异进行分析，涉及合金元素含量、热强度、热疲劳抗力和高温抗氧化性等概念的关联和综合比较，需要中等程度的认知能力和综合分析。 | 难度: 在简答题题型中，该题目要求对三种热作模具钢的使用差异进行多角度分析论述。需要考生不仅掌握每种钢材的合金元素含量和分类（低、中、高合金），还需理解这些差异如何导致热强度、热疲劳抗力和高温抗氧化性能的不同，从而影响其具体应用场景。此外，题目还要求解释为什么H11可以替代3Cr2W8V在某些情况下使用，这需要更深入的材料性能比较和应用条件分析。因此，该题目在简答题中属于较高难度，需要综合分析和多角度论述。" + }, + { + "idx": 3451, + "question": "What is the most notable characteristic of ledeburitic steel?", + "answer": "Its most notable characteristic is the presence of eutectic ledeburite structure in the as-cast microstructure, with high hardness, high wear resistance, and red hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释ledeburitic steel的最显著特征，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对ledeburitic steel最显著特征的基础概念记忆和理解，涉及材料的基本微观结构和性能特点，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释ledeburitic steel的最显著特征，涉及对特定微观结构（共晶ledeburite）及其性能特点（高硬度、高耐磨性等）的描述。虽然需要记忆特定术语和概念，但不需要深入分析或阐述复杂的概念体系，属于基础概念记忆层面的中等难度要求。" + }, + { + "idx": 3452, + "question": "What is the most prominent weakness of ledeburitic steel?", + "answer": "The weakness is the coarse carbides, uneven distribution, and high brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释莱氏体钢的主要弱点，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对ledeburitic steel弱点的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答莱氏体钢的主要弱点，涉及对材料特性的基本理解和记忆，但不需要复杂的体系阐述或深入分析。答案需要列举多个相关特性（粗大碳化物、不均匀分布、高脆性），属于对基础概念的多点描述，但整体仍属于记忆性知识范畴。" + }, + { + "idx": 3453, + "question": "If Cr12MoV steel is selected to manufacture measuring tools, what heat treatment process should be formulated? Why?", + "answer": "When Cr12MoV steel is used to make measuring tools, it can be quenched at 1050～1100°C, tempered multiple times at 550～600°C, and then subjected to nitriding or carbonitriding to achieve high wear resistance, corrosion resistance, and dimensional stability. Reason: Cr12MoV steel, after quenching + high-temperature tempering (quenching and tempering) followed by nitriding or carbonitriding, is commonly used for making measuring tools due to its high wear resistance, corrosion resistance, and relatively high dimensional stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Cr12MoV钢制造测量工具时应采用的热处理工艺及其原因，答案提供了详细的工艺步骤和理论依据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求制定热处理工艺并解释原因，涉及多步热处理过程（淬火、多次回火、氮化或碳氮共渗）的选择和组合，需要理解不同工艺步骤对材料性能（耐磨性、耐腐蚀性、尺寸稳定性）的影响。这需要中等程度的综合分析能力，而非简单的记忆或单一概念的应用。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求不仅说明Cr12MoV钢制造测量工具的热处理工艺，还需要解释选择该工艺的原因。这涉及到对材料性能、热处理工艺及其对最终性能影响的多方面综合分析。虽然题目没有要求深度关联性分析（如与其他材料的对比或更复杂的工艺优化），但已经超出了基础概念说明的范畴，属于需要多角度分析论述的中高难度题目。" + }, + { + "idx": 3454, + "question": "What are the types of heat-resistant steels?", + "answer": "Commonly used heat-resistant steels are roughly divided into three categories according to their microstructure in the normalized state: pearlitic steel, martensitic steel, and austenitic steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举热阻钢的类型，答案提供了详细的分类和描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对热阻钢分类的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对热阻钢的类型进行分类并简要说明分类依据（正火状态下的显微组织）。这属于概念解释和描述的难度级别，需要学生记忆并理解基础分类知识，但不需要深入分析或阐述复杂概念体系。相比等级1的基本定义简答，该题需要更多的知识组织和表述能力，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 3455, + "question": "Based on the alloy composition of oxidation-resistant steel, analyze how the steel meets different thermal stability requirements.", + "answer": "Alloying elements such as chromium, silicon, and aluminum are added to oxidation-resistant steel. These elements have a high affinity for oxygen, so they are preferentially oxidized, forming a dense, high-melting-point oxide film that firmly covers the steel surface. This isolates the metal from external oxidizing gases, preventing further oxidation. The amount of alloying elements added varies, resulting in different levels of oxidation resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析合金成分如何满足热稳定性需求，答案通过文字解释和论述了合金元素的作用机制和效果，属于需要详细文字解释的简答题类型。 | 知识层次: 题目要求分析合金元素如何通过形成氧化膜来满足不同的热稳定性需求，涉及多元素的相互作用、氧化机理的解释以及不同氧化抵抗水平的综合分析。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题-需要文字解释和论述的题型中，该题目属于机理深度解释的难度等级。题目要求分析合金元素如何通过形成氧化膜来满足不同的热稳定性需求，这需要深入理解合金元素的氧化机理及其对钢的热稳定性的影响。虽然题目涉及的知识点较为专业，但解答过程相对直接，主要依赖于对合金元素作用的机理解释，而不需要复杂的多因素综合分析或跨领域的知识整合。因此，在简答题的框架内，该题目属于机理深度解释的等级4难度。" + }, + { + "idx": 3456, + "question": "Why is it still necessary to develop ledeburitic steel?", + "answer": "Because it has high hardness, high wear resistance, and red hardness, this steel is developed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么需要开发ledeburitic钢，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释莱氏体钢的开发必要性，涉及对其性能特点（高硬度、高耐磨性、红硬性）的理解和应用，需要将材料性能与实际应用需求关联起来进行分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释和论述ledeburitic steel的必要性，但答案相对直接，主要涉及该材料的几个关键性能特点（高硬度、高耐磨性和红硬性）。不需要多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3457, + "question": "Based on the role of alloying elements used in stainless steel, analyze the main characteristics of martensitic stainless steel? What are the main shortcomings? How to prevent or overcome them?", + "answer": "Martensitic stainless steel belongs to chromium stainless steel. As the carbon content increases, the strength, hardness, and wear resistance of the steel improve, but the corrosion resistance decreases, because carbon forms chromium carbides with chromium, preventing its potential from rising. To enhance corrosion resistance and mechanical properties, quenching and tempering are usually performed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析马氏体不锈钢的主要特性、主要缺点以及如何预防或克服这些缺点，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释，符合简答题的特点。 | 知识层次: 题目要求分析马氏体不锈钢的主要特性及其主要缺点，并提出预防或克服这些缺点的方法。这需要综合运用材料科学知识，理解合金元素的作用机制，分析材料性能与微观结构的关系，并进行推理和解释。涉及的知识点较为复杂，且需要关联多个概念进行综合分析。 | 难度: 在简答题中属于最高难度等级，需要综合运用材料科学知识进行复杂现象全面分析。题目要求：" + }, + { + "idx": 3458, + "question": "Based on the role of alloying elements used in stainless steel, analyze the main characteristics of ferritic stainless steel? What are the main shortcomings? How to prevent or overcome them?", + "answer": "Ferritic stainless steel also belongs to chromium stainless steel. Its structure remains unchanged from room temperature to high temperature (960～1100‰), and it has strong resistance to atmospheric and acid corrosion. However, if the grain coarsens during heating, it cannot be refined by heat treatment methods and can only be improved through plastic deformation and recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析铁素体不锈钢的主要特性、主要缺点以及如何预防或克服这些缺点，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析铁素体不锈钢的主要特性及其主要缺点，并提出预防或克服这些缺点的方法。这需要理解铁素体不锈钢的基本特性（如铬含量、结构稳定性、耐腐蚀性等），分析其缺点（如晶粒粗化问题），并综合运用材料科学知识提出解决方案（如塑性变形和再结晶）。这涉及多步分析和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对铁素体不锈钢的主要特性、主要缺点以及预防或克服方法进行多角度分析论述。需要综合运用材料科学知识，理解合金元素的作用机制，分析晶粒粗化的原因及其影响，并提出相应的解决方案。这种题目不仅要求对基础概念的掌握，还需要能够进行关联性分析和实际应用思考，因此在简答题中属于较高难度。" + }, + { + "idx": 3459, + "question": "Based on the role of alloying elements used in stainless steel, analyze the main characteristics of austenitic stainless steel? What are the main shortcomings? How to prevent or overcome them?", + "answer": "Austenitic stainless steel belongs to nickel-chromium steel, which has excellent corrosion resistance and heat resistance. However, intergranular corrosion may occur at 450~850°C. It is usually prevented by reducing the mass fraction of carbon, adding elements that can form stable carbides (such as Ti), and applying appropriate heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析奥氏体不锈钢的主要特性和主要缺点，并提出预防或克服方法，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求分析奥氏体不锈钢的主要特性、主要缺点以及预防或克服这些缺点的方法，涉及多个知识点的综合运用和推理分析。需要理解合金元素的作用、不锈钢的腐蚀机制以及相应的预防措施，思维过程较为深入和复杂。 | 难度: 在简答题的复杂分析层次中，该题目要求对奥氏体不锈钢的主要特性、主要缺点及其预防或克服方法进行全面分析。需要综合运用材料科学知识，包括合金元素的作用、腐蚀机理、热处理工艺等多方面内容，并进行推理分析。题目不仅要求解释现象，还需要提出具体的解决方案，涉及的知识点深度和解题步骤的复杂程度较高，属于该题型内的较高难度等级。" + }, + { + "idx": 3460, + "question": "What are the different application scenarios for austenitic stainless steel, wear-resistant steel, and quenched tool steel?", + "answer": "Wear-resistant steel is used to make working parts that withstand strong impact and pressure, such as bulldozer blades and railway switches. Quenched tool steel is used in situations that do not require withstanding strong impact pressure but demand high wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对不同类型钢材的应用场景进行文字解释和论述，答案提供了详细的描述而非选择或判断，符合简答题的特征。 | 知识层次: 题目要求对不同类型钢材的应用场景进行解释和论述，属于对基础知识的直接应用，不需要复杂的分析或综合。主要考查学生对不同类型钢材特性的理解和简单应用能力。 | 难度: 在简答题中属于中等难度，需要理解三种钢材的基本特性并说明其应用场景，但不需要深入分析或复杂的推理过程。" + }, + { + "idx": 3461, + "question": "How is tool steel further classified?", + "answer": "Tool steel is divided into: cutting tool steel, die steel, and measuring tool steel. Cutting tool steel is divided into: carbon tool steel, low-alloy tool steel, and high-speed steel. Die steel is divided into: cold work die steel and hot work die steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对工具钢的分类进行详细解释，答案提供了具体的分类和子分类，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对工具钢分类的基本概念记忆和理解，不涉及复杂分析或综合应用 | 难度: 在简答题题型中，该题目要求对工具钢的分类进行解释和描述，涉及多个子类的划分，但不需要深入阐述每个子类的具体特性或应用场景。属于概念解释和描述的难度等级，比基本定义简答更复杂，但尚未达到复杂概念体系阐述的要求。" + }, + { + "idx": 3462, + "question": "How to overcome the weaknesses of ledeburitic steel?", + "answer": "By repeatedly forging to break down the coarse carbides and distribute them uniformly, which can also reduce brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何克服莱氏体钢的弱点，答案提供了具体的解决方法和原理，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解ledeburitic steel的弱点（粗大碳化物分布不均和脆性），并应用锻造工艺来改善这些弱点。这涉及到多步工艺的理解和应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释如何克服莱氏体钢的弱点，需要考生理解莱氏体钢的特性（如粗大碳化物和脆性）以及锻造工艺对其微观结构的影响。虽然涉及多步概念关联（材料特性与加工工艺的关系），但不需要进行多角度或深度关联性分析，主要聚焦于单一解决方案的说明。因此符合等级3\"综合分析和说明\"的标准。" + }, + { + "idx": 3463, + "question": "Discuss the microstructural characteristics and processing techniques of ZGMn13", + "answer": "ZGMn13 is a wear-resistant steel with an austenitic microstructure at room temperature. Whether in the as-cast, forged, or hot-rolled condition, carbides precipitate along the austenite grain boundaries, reducing the steel's toughness and wear resistance. Therefore, water toughening treatment must be performed. After water toughening, it exhibits good toughness. During subsequent use, under strong compressive stress, martensitic transformation occurs, thereby increasing its wear resistance. Hence, this type of steel is used in applications subject to strong compressive stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论ZGMn13的微观结构特征和加工技术，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论ZGMn13的微观结构特征和加工技术，涉及多个知识点的综合运用，包括材料的微观结构（奥氏体、碳化物析出）、加工工艺（水韧处理）及其对性能的影响（韧性、耐磨性）。需要深入理解材料在不同处理条件下的行为变化，并解释其背后的机理（如马氏体转变）。这种分析需要较高的认知能力和对材料科学原理的深入理解。 | 难度: 在简答题题型中，该题目要求对ZGMn13的微观结构特征和加工技术进行详细解释，包括其在不同加工条件下的行为、水韧化处理的作用以及使用过程中的相变机理。这需要考生具备较深的知识掌握和综合分析能力，能够将多个知识点串联起来进行解释。虽然题目没有要求对复杂现象进行全面分析（如等级5），但需要机理深度解释，因此属于等级4难度。" + }, + { + "idx": 3464, + "question": "Discuss the microstructural characteristics and processing techniques of Cr12-type cold-work die steel", + "answer": "Cr12 is a type of cold-work die steel, with Cr as the main alloying element, which significantly enhances hardenability and wear resistance. Due to the high content of alloying elements, the as-cast microstructure contains eutectic carbides. Therefore, repeated forging is required to break down the carbides and improve their distribution and brittleness. After forging, spheroidizing annealing is performed, followed by quenching + low-temperature tempering to obtain tempered martensite, which provides high hardness and wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论Cr12型冷作模具钢的微观结构特征和加工技术，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论Cr12型冷作模具钢的显微组织特征和加工工艺，涉及多个知识点的综合运用，包括合金元素的作用、显微组织的形成机制、热处理工艺的选择及其对性能的影响等。需要深入理解材料科学原理，并进行推理分析，解释工艺与组织性能之间的关系。 | 难度: 在简答题中属于机理深度解释难度等级。题目要求讨论Cr12型冷作模具钢的显微组织特征和加工工艺，需要深入理解合金元素的作用、铸态组织中的共晶碳化物、反复锻造的作用、球化退火以及淬火+低温回火工艺对组织性能的影响。虽然不涉及多因素交互作用的复杂现象全面分析，但需要对材料科学中的相变机理和工艺-组织-性能关系有较深入的理解和解释能力。" + }, + { + "idx": 3465, + "question": "What is the difference between the purpose of quenching for austenitic stainless steel and wear-resistant steel compared to that of general steel?", + "answer": "The purpose of quenching for austenitic stainless steel and wear-resistant steel is to obtain a single-phase, uniform austenitic structure, preventing the formation of secondary phases that could cause intergranular corrosion. Therefore, the quenching of austenitic stainless steel is referred to as solution treatment, while for wear-resistant steel, the quenching process, which results in a single austenitic structure with high plasticity and toughness, is also known as water toughening treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述淬火对奥氏体不锈钢和耐磨钢与普通钢的不同目的，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释淬火对奥氏体不锈钢和耐磨钢的不同目的，涉及不同材料的热处理工艺及其背后的原理，需要理解并关联多个概念（如单相奥氏体结构、晶间腐蚀、固溶处理、水韧处理等），并进行综合分析。这超出了基础概念的记忆，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合理解不同钢材的淬火目的及其微观结构变化，并进行多角度分析论述。题目要求解释奥氏体不锈钢和耐磨钢的淬火目的与普通钢的区别，涉及多个专业概念（如单相奥氏体组织、固溶处理、水韧处理等）的关联和综合分析，解题步骤较为复杂，需要深入的知识掌握和论述能力。" + }, + { + "idx": 3466, + "question": "How is structural steel further subdivided?", + "answer": "Structural steel is divided into: engineering structural steel and mechanical component steel. Engineering structural steel is further divided into: ordinary carbon structural steel and ordinary low-alloy steel. Mechanical component steel is divided into: carburizing steel, quenched and tempered steel, spring steel, and rolling bearing steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对结构钢的进一步分类进行文字解释和论述，答案提供了详细的分类说明，符合简答题的特征。 | 知识层次: 题目考查对结构钢分类的基本概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于复杂概念体系阐述。题目要求不仅列出结构钢的主要分类（工程结构钢和机械零件钢），还需要进一步细分每个大类下的具体类型（如普通碳素结构钢、普通低合金钢、渗碳钢、调质钢等）。这需要考生掌握完整的分类体系并准确回忆多个专业术语，属于该题型内对记忆广度和组织能力要求较高的题目。" + }, + { + "idx": 3467, + "question": "Why does alloy steel have less heat treatment deformation than carbon steel?", + "answer": "The addition of alloying elements (except C) increases the hardenability of the steel, so when obtaining the same structure, alloy steel can choose a slower cooling medium, resulting in less heat treatment deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢比碳钢热处理变形小的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金钢比碳钢热处理变形小的原因，涉及合金元素对淬透性的影响、冷却介质选择与组织转变的关系等机理分析，需要综合运用材料科学原理进行推理和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对合金钢和碳钢的热处理变形差异进行机理深度解释。需要综合运用材料科学知识，分析合金元素对淬透性的影响，并推理冷却介质选择与热处理变形的关系。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述，属于需要深入机理解释的等级4难度。" + }, + { + "idx": 3468, + "question": "For a machine tool spindle made of 40Cr steel, the core requires good strength and toughness (200-300HB), while the journal needs to be hard and wear-resistant (HRC54-58). What preparatory heat treatment should be selected?", + "answer": "Preparatory heat treatment: Quenching + high-temperature tempering, tempered sorbite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述选择特定预备热处理的原因，答案提供了详细的文字解释而非选择或计算 | 知识层次: 题目需要综合运用材料科学知识，包括对40Cr钢的热处理工艺选择、不同部位性能要求的理解，以及如何通过淬火和高温回火获得所需的强度和韧性。这涉及到多步思考和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明。题目要求考生理解40Cr钢的热处理工艺，并能够根据不同的性能要求（芯部的强度和韧性、轴颈的硬度和耐磨性）选择合适的预备热处理工艺。虽然涉及多个概念（淬火、高温回火、回火索氏体等），但不需要进行多角度分析或深度关联性分析，解题步骤相对直接。" + }, + { + "idx": 3469, + "question": "Is it reasonable to use Q235 steel after quenching and tempering treatment? Why?", + "answer": "No, it is not reasonable. Because Q235 is an ordinary-quality carbon structural steel with high sulfur and phosphorus content, it is generally used in the hot-rolled state. Due to its low carbon content, high S and P content, poor quality, and low hardenability, even in the quenched and tempered state, its performance will not improve significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对是否合理使用Q235钢进行淬火和回火处理进行解释，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解Q235钢的基本特性（碳含量、硫磷含量等）及其对热处理效果的影响，并综合分析淬火回火处理对性能改善的局限性。这涉及多个概念的关联和中等程度的分析判断。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对Q235钢的性能和热处理工艺进行综合分析，但主要考察的是对基础概念的理解和应用，如碳含量、硫磷含量对钢材性能的影响，以及淬火回火处理的基本原理。解题步骤相对直接，不需要进行多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3470, + "question": "Why does alloy steel have better mechanical properties than carbon steel?", + "answer": "The addition of alloying elements and appropriate heat treatment can improve or enhance the mechanical properties of steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么合金钢比碳钢具有更好的机械性能，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解合金元素和热处理对钢机械性能的影响，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解合金钢和碳钢的基本概念，并能够解释合金元素和热处理对机械性能的影响。虽然涉及一定的综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3471, + "question": "How is steel classified by use?", + "answer": "Steel is classified by use into structural steel, tool steel, and special performance steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答，答案是一个简短的文字描述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对钢材按用途分类的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求对钢材按用途分类进行简单列举，不需要深入解释或复杂概念体系的阐述。答案直接对应教材中的基础分类记忆点，属于该题型下最基础的知识再现要求。" + }, + { + "idx": 3472, + "question": "How are special property steels further classified?", + "answer": "Special property steels are divided into: stainless steel, heat-resistant steel, and wear-resistant steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对特殊性能钢进行进一步分类，答案以文字解释和列举的形式给出，符合简答题的特征。 | 知识层次: 题目考查特殊性能钢的分类，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答特殊性能钢的进一步分类，属于基本定义简答。题目仅涉及记忆性知识，无需深入解释或复杂概念体系阐述，符合等级1的难度标准。" + }, + { + "idx": 3473, + "question": "Why do alloy tool steels have higher wear resistance and hot hardness than carbon steels?", + "answer": "Alloy tool steels contain certain alloying elements that form alloy carbides with the carbon in the steel. These alloy carbides have high hardness and high melting points, which is why alloy tool steels exhibit higher wear resistance and hot hardness than carbon steels.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金工具钢比碳钢具有更高耐磨性和热硬度的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金工具钢相对于碳钢具有更高耐磨性和热硬度的原因，涉及合金元素与碳形成合金碳化物的机理，需要理解合金元素的作用及其对材料性能的影响。这属于中等应用层次，需要将多个概念（合金元素、碳化物、耐磨性、热硬度）关联起来进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解合金工具钢和碳钢的基本概念，并能够解释合金元素如何形成合金碳化物以及这些碳化物对性能的影响。虽然涉及多个概念的关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3476, + "question": "There is a W18Cr4V steel disc milling cutter, please arrange its processing route.", + "answer": "Processing route: Blanking and forging → Spheroidizing annealing → Cutting → Quenching + High-temperature tempering (three times) → Finishing → Assembly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述一个加工路线，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求安排W18Cr4V钢制圆盘铣刀的加工路线，涉及多个加工步骤的选择和顺序安排，需要理解材料的热处理工艺和机械加工流程，并进行综合分析。虽然不涉及复杂的计算或创新设计，但需要对不同加工步骤的关联和影响有一定的理解，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明。题目要求安排W18Cr4V钢制圆盘铣刀的加工路线，涉及多个加工步骤的顺序安排和热处理工艺的选择。虽然不需要多角度分析或深度关联性分析，但需要对材料加工工艺有较好的理解和综合应用能力。" + }, + { + "idx": 3477, + "question": "For a machine tool spindle made of 40Cr steel, the core requires good strength and toughness (200-300HB), while the journal needs to be hard and wear-resistant (HRC54-58). Describe the microstructure after preparatory heat treatment.", + "answer": "Microstructure after preparatory heat treatment: tempered sorbite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述预备热处理后的微观结构，需要文字解释和论述，而不是选择、判断或计算。答案\"tempered sorbite\"是对微观结构的简要描述，符合简答题的特征。 | 知识层次: 题目主要考查对材料热处理后微观组织的基本概念记忆，即40Cr钢经过预备热处理后得到的回火索氏体组织。这属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求描述特定材料经过预备热处理后的微观结构，需要考生掌握40Cr钢的基本热处理知识以及相关微观组织的定义。虽然涉及具体材料的应用场景，但核心答题内容仍属于对\"tempered sorbite\"这一基础概念的描述，不需要进行多概念关联或复杂体系阐述。" + }, + { + "idx": 3478, + "question": "Compare the compositional characteristics of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V.", + "answer": "
Steel gradeCompositional characteristics
9SiCrwc=0.9%, wsiWcr<1.5%
Cr12wc=2.15%, wc=12%
5CrMnMowc=0.5%, wc=0.75%, wM=0.9% WMo=0.21%
W18Cr4Vwc=0.75%, ww=18%, wc=4%, wv=1.2%
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较四种合金工具钢的成分特征，答案以表格形式详细列出了每种钢的具体成分含量，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对不同合金工具钢成分特征的记忆和基本理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较四种合金工具钢的成分特征，但主要考察的是对基础概念的记忆和简单描述，不需要进行复杂的解释或论述。学生只需回忆并列出每种钢的主要成分及其含量即可，不需要深入分析或比较这些成分对性能的影响。因此，在简答题题型中，该题目属于等级2，即概念解释和描述的难度水平。" + }, + { + "idx": 3479, + "question": "What is the difference between the wear resistance principle of wear-resistant steel and that of quenched tool steel?", + "answer": "The wear resistance principle of wear-resistant steel is that the single austenite structure is subjected to strong impact and pressure during work, resulting in stress-induced martensite and work hardening, which greatly increases the wear resistance of the steel. Quenched tool steel obtains high hardness and high wear resistance tempered martensite through quenching + low-temperature tempering, giving the steel high wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种钢材的耐磨原理差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种不同钢材的耐磨原理，涉及材料微观结构转变（如应力诱导马氏体、加工硬化）和热处理工艺（淬火+低温回火）对性能的影响机制。这需要综合运用材料科学知识，进行机理层面的对比分析，属于较高层次的认知要求。 | 难度: 在简答题中属于机理深度解释难度，需要详细阐述两种钢材的耐磨机理，并对比其差异。题目要求综合运用材料科学知识，解释应力诱导马氏体转变和工作硬化等复杂现象，以及淬火+低温回火对工具钢性能的影响。虽然不涉及多因素交互作用的全面分析，但对机理的解释深度要求较高。" + }, + { + "idx": 3480, + "question": "Compare the heat treatment processes of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V", + "answer": "
Steel gradeHeat treatment
9SiCrQuenching + low tempering
Cr12Quenching + low tempering
5CrMnMoQuenching + high tempering
W18Cr4VQuenching + high tempering
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较四种合金工具钢的热处理工艺，答案以表格形式呈现了每种钢材的具体热处理方式，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较四种合金工具钢的热处理工艺，涉及对不同钢种热处理工艺的理解和应用，需要综合分析不同钢种的特性和相应的热处理工艺选择，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对四种合金工具钢的热处理工艺进行比较分析，涉及多个知识点（不同钢种的热处理工艺特点）的综合运用。需要考生不仅掌握每种钢的具体热处理工艺（淬火+低温回火/高温回火），还要能够进行横向对比分析，说明不同工艺选择的原理差异。这超出了简单知识点复述（等级3），但尚未达到需要深度关联材料科学原理（如相变动力学、合金元素作用机制等）的等级5水平。属于需要多角度分析论述的中高难度简答题。" + }, + { + "idx": 3481, + "question": "Compare the properties of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V", + "answer": "
Steel gradeProperties
9SiCrHigh strength and high wear resistance
Cr12High strength and high wear resistance
5CrMnMoBest comprehensive mechanical properties
W18Cr4VHigh strength and high wear resistance
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较四种合金工具钢的性能，答案以表格形式呈现了每种钢的性能特点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较四种合金工具钢的性能，需要理解每种钢的基本特性并进行综合分析，涉及多概念关联和性能对比，但不需要深入机理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解四种合金工具钢的基本性能并进行综合比较分析。题目要求对每种钢材的性能进行简要说明，但不需要深入探讨其微观结构或热处理工艺等更复杂的关联因素。解题步骤主要是识别和比较不同钢材的关键性能指标，属于概念关联和综合分析的基本应用层次。" + }, + { + "idx": 3482, + "question": "Explain the purposes of each hot working process.", + "answer": "Spheroidizing annealing: Eliminate forging stress, spheroidize carbides to reduce hardness and improve machinability, preparing for quenching. Quenching: To obtain martensite, maintaining high hardness and wear resistance. Tempering: Adjust properties, eliminate quenching stress, and reduce retained austenite (A′).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释每个热加工过程的目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释每种热加工工艺的目的，涉及多个工艺步骤（球化退火、淬火、回火）及其具体作用，需要理解各工艺的原理和相互关系，并进行综合分析。虽然不涉及复杂计算或深度机理分析，但需要将多个知识点关联起来进行解释，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并解释多个热加工工艺的目的，并进行综合分析。题目要求对每种工艺的作用进行说明，涉及多个概念和步骤的关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3483, + "question": "Compare the uses of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V.", + "answer": "
Steel gradeUse
9SiCrTaps, dies, drill bits
Cr12Large-sized cold work dies
5CrMnMoSmall hot forging dies
W18Cr4VHigh-speed cutting dies
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较四种合金工具钢的用途，答案以表格形式详细列出了每种钢材的具体应用，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对不同合金工具钢用途的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要记忆四种合金工具钢的具体用途，但不需要深入分析或比较它们的性能特点或应用场景的复杂性。题目要求的是基础概念的记忆和简单列举，没有涉及复杂的概念体系阐述或深入的原理分析。" + }, + { + "idx": 3484, + "question": "Is tempering high-speed steel at 560°C considered quenching and tempering treatment? Why?", + "answer": "No. Quenching and tempering treatment refers to high-temperature tempering (typically 500~650°C) after quenching to obtain tempered sorbite structure, which provides good comprehensive mechanical properties. However, tempering high-speed steel at 560°C aims to achieve dispersion hardening and secondary quenching phenomena, improving hardness and wear resistance, with the microstructure being tempered martensite + a small amount of retained austenite + carbides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么高速钢在560°C回火不被认为是调质处理，需要文字解释和论述，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高速钢在560°C回火是否属于调质处理，需要综合运用材料热处理知识，理解不同热处理工艺的目的和机理，分析调质处理与高速钢回火的本质区别，涉及多概念关联和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对高速钢回火工艺进行全面的机理分析，需要综合运用相变理论、材料强化机制等多方面知识，并区分常规调质处理与高速钢特殊回火工艺的本质差异。解题需完成：1) 明确调质处理的定义和目的 2) 分析560°C回火对高速钢的特殊作用 3) 对比两种工艺的显微组织差异 4) 解释性能差异的根源。这种需要多维度交叉分析且涉及专业机理深度解释的题目，在同题型中属于最高难度层级。" + }, + { + "idx": 3486, + "question": "Can one prolonged tempering at 560°C replace three tempering processes at 560°C?", + "answer": "No. Because a single tempering is difficult to completely eliminate retained austenite, multiple tempering processes are required to reduce the retained austenite to the minimum amount. Moreover, each subsequent tempering can eliminate the internal stress generated by the transformation of austenite into martensite during the previous tempering.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目以疑问句形式提出一个陈述（是否可以用一次长时间回火替代三次回火），答案明确判断该陈述是错误的，并给出了解释。这符合判断题的特征，即对某个陈述进行真伪判断并说明理由。 | 知识层次: 题目涉及回火工艺对残余奥氏体消除的影响机制，需要理解多次回火过程中奥氏体向马氏体转变的机理以及内应力的产生与消除过程。这需要对材料相变和热处理工艺有较深入的理解和分析能力，属于机理解释和综合分析层次。 | 难度: 在判断题的复杂分析题型中，该题目属于深度分析结论判断难度。题目不仅要求判断陈述的对错，还需要理解并解释热处理过程中残余奥氏体的消除机制、多次回火的必要性以及应力消除的机理。这需要综合运用材料科学知识进行推理分析，并给出机理层面的解释，因此属于该题型内的最高难度等级。" + }, + { + "idx": 3487, + "question": "What is the role of carbon in high-speed steel?", + "answer": "The role of carbon in high-speed steel: high carbon content, generally with a mass fraction of 0.7% to 1.5%, is to ensure the formation of alloy carbides with alloying elements, obtaining a martensite matrix plus carbides during quenching to improve the hardness and wear resistance of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释碳在高速钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释碳在高速钢中的作用，涉及合金元素与碳的相互作用、马氏体基体的形成以及碳化物对硬度和耐磨性的影响。这需要理解多个概念之间的关联，并进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求解释碳在高速钢中的作用，涉及对碳含量范围、合金碳化物形成机制、马氏体基体与碳化物的相互作用等概念的综合理解。虽然需要关联多个知识点，但不需要进行多角度或深度关联性分析（等级4-5的要求），解题步骤相对直接，属于典型的综合分析和说明类题目。" + }, + { + "idx": 3488, + "question": "Why is the quenching temperature of W18Cr4V steel as high as 1280°C?", + "answer": "The two elements that have the greatest impact on the hot hardness of high-speed steel are W and V. Their solubility in austenite only increases significantly above 1000°C. At 1270~1280°C, the austenite contains wW=7%~8%, wCr=4%, and wV=1%. If the temperature is higher, the austenite grains will rapidly grow and coarsen, and the retained austenite in the quenched state will also increase rapidly, thereby reducing the hardness of the high-speed steel and increasing brittleness. This is the main reason why the quenching temperature is generally set at 1270~1280°C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么W18Cr4V钢的淬火温度高达1280°C，答案提供了详细的文字解释和论述，涉及材料科学中的热硬度和溶解度等概念，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释W18Cr4V钢的淬火温度高达1280°C的原因，涉及多个元素的溶解度与温度的关系、奥氏体晶粒生长和粗化、残余奥氏体含量对硬度的影响等复杂机理的综合分析和推理。需要深入理解材料科学中的相变、合金元素作用和热处理工艺之间的关联，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对高速钢淬火温度的设定进行全面的机理解释和现象分析。需要综合运用材料科学中的溶解度、晶粒生长、奥氏体转变等多方面知识，并解释温度选择与材料性能之间的复杂关系。这种深度和广度的分析要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 3489, + "question": "Why does W18Cr4V steel need to undergo three tempering cycles at 560°C after quenching?", + "answer": "Because W18Cr4V steel contains about 20%~25% retained austenite in the quenched state, which is difficult to fully eliminate with a single tempering. Three tempering cycles can reduce the retained austenite to a minimum (about 15% remains after the first tempering, 3%~5% after the second, and 1%~2% after the third). Each subsequent tempering also relieves the internal stress generated by the transformation of austenite into martensite during the previous tempering. The tempered microstructure consists of tempered martensite + a small amount of retained austenite + carbides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么W18Cr4V钢需要在淬火后进行三次560°C的回火处理，答案提供了详细的文字解释和论述，说明了残余奥氏体的变化和回火的作用，符合简答题的特征。 | 知识层次: 题目要求解释W18Cr4V钢在淬火后需要进行三次回火的原因，涉及残余奥氏体的转变、内应力的消除以及显微组织的演变等多个方面的综合分析。需要理解回火过程中残余奥氏体向马氏体的转变机制、每次回火对残余奥氏体含量的影响以及内应力的变化等复杂机理。这超出了简单记忆或基本应用的范围，属于对材料热处理过程的深入分析和解释。 | 难度: 在简答题题型中，该题目要求对W18Cr4V钢的热处理过程进行复杂现象全面分析。需要综合运用材料科学知识，解释多次回火的必要性、残余奥氏体转变机理以及内部应力变化过程。题目涉及多个相互关联的复杂概念（残余奥氏体含量变化、马氏体转变、碳化物析出等），并要求将这些概念整合成一个完整的机理解释。这超出了简单记忆或单一概念解释的范畴，属于该题型下最高难度的综合分析类题目。" + }, + { + "idx": 3490, + "question": "What is the role of alloying elements in high-speed steel?", + "answer": "The role of alloying elements in high-speed steel: W improves the red hardness of the steel, Cr enhances hardenability, Mo reduces the second type of temper brittleness, Co delays the precipitation and aggregation of carbides during tempering, that is, improves tempering stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素在高速钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素在高速钢中的作用，涉及多个元素的特定功能及其相互作用，需要理解并关联不同元素对材料性能的影响，属于中等应用层次的知识。 | 难度: 在简答题中属于较高难度，需要多角度分析论述合金元素在高速钢中的作用，涉及多个元素的特定功能及其相互作用，要求考生具备综合分析和概念关联的能力。" + }, + { + "idx": 3491, + "question": "Can austenitic stainless steel be strengthened by heat treatment?", + "answer": "No. Because after quenching (solution treatment), austenitic stainless steel undergoes no phase transformation, and all second-phase particles dissolve into the austenite. As a result, its hardness and strength drop to the lowest level after quenching, so it cannot be strengthened by heat treatment.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述性问题，要求判断\"奥氏体不锈钢是否可以通过热处理强化\"这一陈述的正确性。答案明确给出了\"否\"的判断，并提供了相应的解释。这符合判断题的特征，即对某个陈述进行对错判断。 | 知识层次: 题目考查对奥氏体不锈钢热处理强化原理的基础概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然题目涉及的是基础概念记忆层面的知识（奥氏体不锈钢的热处理强化原理），但需要考生不仅记住\"奥氏体不锈钢不能通过热处理强化\"这一结论，还需要理解其背后的原因（无相变、第二相粒子溶解等基本原理）。这比单纯判断基本概念正误（等级1）要求更高，但尚未达到需要判断复杂概念陈述（等级3）的程度。" + }, + { + "idx": 3492, + "question": "How to improve the corrosion resistance of steel?", + "answer": "Methods to improve the corrosion resistance of steel: (a) Increase the electrode potential of the metal. (b) Make the metal easier to passivate. (c) Obtain a single-phase structure with uniform chemical composition, microstructure, and metal purity, aiming to avoid the formation of microcells.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何提高钢的耐腐蚀性，答案提供了详细的文字解释和论述，而不是从选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目要求对提高钢材耐腐蚀性的方法进行解释和论述，涉及多个概念（如电极电位、钝化、单相结构等）的关联和综合分析，需要理解基本原理并能够应用这些知识来解决问题。虽然不涉及复杂计算，但需要对材料科学中的多个概念进行整合和应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对提高钢材耐腐蚀性的方法进行多角度分析论述。需要考生不仅列举具体方法（如增加电极电位、促进钝化、获得单相结构等），还要解释这些方法背后的原理和相互关系。这涉及到对金属腐蚀机制、电化学原理和材料微观结构的综合理解，属于中等应用层次中较复杂的综合分析要求，因此评定为等级4。" + }, + { + "idx": 3493, + "question": "What are the characteristics of cast iron and carbon steel in terms of mechanical properties?", + "answer": "Cast iron has low tensile strength, compressive strength similar to steel with the same matrix, and poor plasticity and toughness; carbon steel has higher strength and better plasticity and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述铸铁和碳钢在机械性能方面的特点，答案提供了详细的文字描述和比较，符合简答题的特征。 | 知识层次: 题目考查对铸铁和碳钢机械性能基本概念的记忆和理解，属于基础概念记忆范畴 | 难度: 在简答题题型中，该题目要求对两种材料的机械性能进行解释和描述，涉及多个特性的比较（如强度、塑性、韧性等），但不需要构建复杂的理论体系或深入分析。属于概念解释和描述级别，符合等级2的标准。" + }, + { + "idx": 3494, + "question": "How to distinguish between 45 steel and HT150 metals through metallographic examination", + "answer": "Metallographic examination", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述如何通过金相检验区分45钢和HT150金属，答案形式为文字描述而非选择、判断或计算。 | 知识层次: 题目要求通过金相检验区分45钢和HT150金属，这需要理解两种材料的金相组织特征，并能将金相观察结果与材料特性关联起来。虽然不涉及复杂计算，但需要综合分析金相组织的差异，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度等级。原因如下：" + }, + { + "idx": 3495, + "question": "What measures should be taken to improve the strength of stainless steel?", + "answer": "Measures: Work hardening. Some martensitic stainless steels (such as 4Cr13) can be strengthened through heat treatment (quenching + low-temperature tempering).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述提高不锈钢强度的措施，答案提供了具体的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求考生理解不锈钢强化的基本原理（如加工硬化和热处理），并能够关联不同强化方法（如马氏体不锈钢的热处理工艺）。这需要多步概念关联和综合分析能力，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求对不锈钢强化措施进行综合分析和说明，涉及工作硬化和热处理（淬火+低温回火）两种具体方法。虽然需要关联材料科学中的强化机制概念，但解题步骤相对明确，不需要多角度或深度关联性分析。在同类简答题中，该题目对知识掌握深度和综合分析能力的要求适中，符合等级3的标准。" + }, + { + "idx": 3496, + "question": "What method is used to strengthen austenitic stainless steel in production?", + "answer": "Work hardening is commonly used to strengthen it in production.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种方法用于强化奥氏体不锈钢，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对奥氏体不锈钢强化方法的基础概念记忆，即冷加工硬化（work hardening）这一基本原理的应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答\"work hardening\"这一基本方法名称，无需展开解释其原理或与其他强化方法的比较。符合等级1\"基本定义简答\"的特征，属于该题型下最基础的记忆性知识考查。" + }, + { + "idx": 3497, + "question": "How to distinguish between 45 steel and HT150 metals through macroscopic fracture analysis", + "answer": "Macroscopic fracture analysis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来区分两种金属的宏观断裂分析，答案形式为文字描述而非选择、判断或计算。 | 知识层次: 题目要求通过宏观断口分析区分45钢和HT150金属，这需要理解两种材料的断口特征及其与材料性能的关系，涉及多步观察和综合分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要从宏观断口特征（如晶粒大小、断口形貌、颜色等）对两种完全不同类型的材料（碳钢和铸铁）进行多角度对比分析，涉及金属学原理与工程材料知识的综合运用，且需准确描述区分依据。" + }, + { + "idx": 3498, + "question": "What are the compositional characteristics of stainless steel?", + "answer": "The compositional characteristics of stainless steel are: (a) Low carbon content: Most w_C = (0.1-0.2)%. C has a strong affinity with Cr, and C and Cr can form a series of complex compounds, reducing the corrosion resistance of the steel. (b) Stainless steel generally contains a high amount of chromium (the mass fraction of Cr in martensitic and ferritic stainless steels is greater than 13%, and the mass fraction of Cr in austenitic stainless steel is greater than 18%) and a high amount of nickel (the mass fraction of Ni in austenitic stainless steel is greater than 8%). (c) The carbon content is generally low, with the mass fraction of C in austenitic and ferritic stainless steels being relatively low (<0.1%).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释不锈钢的成分特征，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查不锈钢的成分特征，属于基础概念的记忆和理解，不需要复杂的计算或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答不锈钢的成分特征，涉及多个关键成分（碳、铬、镍）的含量范围及其作用，但不需要深入分析或复杂推导。虽然需要记忆具体数值和分类标准，但整体仍属于基础概念记忆范畴，解题步骤相对直接。" + }, + { + "idx": 3499, + "question": "Why is it often easy to form white iron on the surface layer and thin-walled areas of the same casting?", + "answer": "Because the undercooling degree is large and the cooling rate is fast at the surface layer and thin-walled areas, it is easy to obtain white iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么在铸件的表层和薄壁区域容易形成白口铁，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解白口铁形成的条件（过冷度和冷却速率），并将这些概念与铸件表面层和薄壁区域的特点联系起来进行分析。虽然不涉及复杂计算，但需要多步概念关联和综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及的知识点（白口铁的形成条件）较为基础，但需要学生理解并关联冷却速率、过冷度等概念，并能够综合分析这些因素对铸铁组织的影响。解题步骤包括识别关键因素（表面层和薄壁区域的特点）并解释其与白口铁形成的关系，属于综合分析和说明的范畴，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3500, + "question": "Compare the composition of HT150 and annealed 20 steel", + "answer": "Composition: a) HT150: w_C=(2.5~4)%, w_Si=(1~2.5)%, w_Mn=(0.5~1.3)%, w_P≤0.3%, w_S≤0.15%. b) 20 steel: w_C=(0.17~0.24)%, w_Mn=(0.35~0.65)%, w_Si=(0.17~0.37)%, w_P≤0.035%, w_S≤0.035%. Composition difference: The mass fractions of C, Si, P, and S are higher in cast iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种材料的成分，答案提供了详细的成分对比和差异分析，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对HT150和20钢两种材料成分的记忆和基本理解，属于基础概念的记忆性知识，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较两种材料的成分，并指出主要差异，这需要学生对HT150和20钢的基本成分有清晰的记忆，并能进行简单的对比分析。虽然涉及多个成分的比较，但不需要复杂的推理或深入的概念阐述，因此属于等级2难度。" + }, + { + "idx": 3501, + "question": "What is the main difference between cast iron and carbon steel?", + "answer": "The main difference between carbon steel and cast iron lies in the carbon content and the form of carbon present. The carbon content in cast iron is greater than 2.11%, while that in carbon steel is greater than 0.0218% but less than 2.11%. In carbon steel, apart from a portion dissolved in ferrite, all other carbon exists in the form of Fe3C. In cast iron, a small amount of carbon is dissolved in ferrite, while most of the carbon exists in the form of graphite (gray cast iron) or Fe3C (white cast iron). The microstructure is not entirely the same, leading to differences in properties (both processing and service performance).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释cast iron和carbon steel的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对碳钢和铸铁的基本定义、碳含量范围以及碳存在形式的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释两种材料的主要区别，包括碳含量和碳的存在形式，并简要说明其对性能的影响。虽然涉及多个概念，但不需要深入分析或复杂推理，主要考察基础概念的记忆和理解。" + }, + { + "idx": 3502, + "question": "What are the process characteristics of high-speed steel?", + "answer": "Process characteristics of high-speed steel: a) Two-stage preheating: reduces thermal stress, minimizes deformation and cracking. b) High quenching temperature: ensures full dissolution of W and V into austenite, allowing alloy carbides to precipitate during tempering, thereby ensuring red hardness. c) Graded quenching: reduces deformation and cracking. d) 560‰ tempering: achieves maximum hardness with secondary hardening and secondary quenching phenomena. e) Triple tempering: reduces retained austenite from over 20% after quenching to approximately 1%–2%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释高速钢的工艺特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高速钢的工艺特性，涉及多个工艺步骤（如预热、淬火、回火等）及其原理和效果，需要将多个概念关联起来进行综合分析。虽然不涉及复杂计算或深度机理分析，但需要对工艺参数和材料性能之间的关系有较好的理解，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对高速钢的工艺特性进行多角度分析论述。需要考生不仅理解各个工艺步骤（如两段预热、高淬火温度、分级淬火等）的具体作用，还要能够综合这些步骤之间的关联性及其对材料性能的影响（如红硬性、二次硬化等）。此外，题目还涉及较为专业的术语和概念（如残留奥氏体的控制），要求考生具备一定的综合分析能力。虽然不需要进行深度关联性分析（如等级5所要求的），但已超出基础说明的范畴，属于多角度分析论述的中高难度水平。" + }, + { + "idx": 3503, + "question": "Is Cr12MoV a stainless steel?", + "answer": "Cr12MoV is not a stainless steel, it is a cold work die steel. The w_Cr of stainless steel is ≥13%.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断\"Cr12MoV是否为不锈钢\"这一陈述的对错，答案直接给出了明确的判断结果和依据，符合判断题的特征。 | 知识层次: 题目考查对不锈钢和冷作模具钢的基本定义和分类的记忆，以及铬含量这一关键指标的掌握情况，属于基础概念记忆层次。 | 难度: 在判断题中属于中等难度，需要理解不锈钢的基本定义（铬含量≥13%）并能够将其与冷作模具钢（Cr12MoV）进行区分。虽然题目涉及的是基础概念记忆，但需要对两种钢材的分类标准有一定理解才能准确判断。" + }, + { + "idx": 3504, + "question": "Compare the compressive strength of HT150 and annealed 20 steel", + "answer": "The tensile strength and hardness of the two are not much different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的压缩强度，答案需要文字解释和论述两种材料的性能差异，属于需要详细说明的简答题类型。 | 知识层次: 题目要求比较两种材料的压缩强度，涉及对材料性能的理解和综合分析，需要关联不同材料的热处理状态与力学性能的关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较两种材料的压缩强度，但答案涉及到了拉伸强度和硬度的比较，这需要学生理解材料性能的多方面关联。解题步骤包括识别材料类型、回忆相关性能参数、进行对比分析，但不需要复杂的计算或深入的理论推导。综合分析的要求使其略高于基础概念题，但尚未达到需要多角度或深度关联性分析的高难度水平。" + }, + { + "idx": 3505, + "question": "Why does cast iron with a chemical composition of 'three lows' (low carbon, silicon, and manganese content) and 'one high' (high sulfur content) tend to form white iron during production?", + "answer": "Because both carbon and silicon are graphitization-promoting elements, their low content facilitates the formation of white iron structure. Although manganese is a graphitization-inhibiting element, its low mass fraction cannot counteract the effect of sulfur, making the sulfur's role in inhibiting graphitization more pronounced and thus favoring the production of white cast iron. Since sulfur is a graphitization-inhibiting element, low carbon, silicon, and manganese combined with high sulfur content easily lead to the formation of white iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么特定成分的铸铁容易形成白口铁，需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释铸铁中特定化学成分对白口铁形成的影响机制，涉及多个元素的相互作用和石墨化过程的抑制与促进，需要综合运用材料科学中的相变原理和合金元素作用的知识，进行推理分析和机理解释。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用多个材料科学概念（如石墨化促进/抑制元素的作用机理），并需要深入理解化学成分与微观结构形成的因果关系。解题过程涉及多变量交互作用的推理分析（如低锰含量与高硫含量的对抗效应），以及对生产实际中白口铁形成条件的全面解释。这完全符合等级5\"复杂现象全面分析\"的标准，属于该题型框架内最高难度的题目类型。" + }, + { + "idx": 3506, + "question": "Compare the microstructures of HT150 and annealed 20 steel", + "answer": "Microstructure: a) HT150: F+P+G (graphite); b) 20 steel: F+P.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种材料的微观结构，答案需要文字解释和论述两种材料的微观结构特点，属于简答题类型。 | 知识层次: 题目主要考查对HT150和20钢两种材料微观结构的基础概念记忆，属于定义和分类层面的知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求对两种材料的微观结构进行比较和描述，涉及基础概念的记忆和简单解释。虽然需要同时掌握HT150和20钢的微观结构特征，但不需要深入分析或复杂的概念体系阐述，属于概念解释和描述的难度等级。" + }, + { + "idx": 3507, + "question": "Compare the welding performance of HT150 and annealed 20 steel", + "answer": "The welding performance of 20 steel is better than that of HT150.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的焊接性能，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的焊接性能，需要理解材料的基本性质（如HT150和20钢的成分、组织）以及焊接性能的影响因素（如碳当量、热处理状态等）。这涉及到多步分析和概念关联，但不需要深入的机理解释或创新设计。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要比较两种材料的焊接性能，但主要涉及对材料基本性能的理解和简单对比，不需要深入的多角度分析或复杂的关联性论述。解题步骤相对直接，属于典型的综合分析说明题。" + }, + { + "idx": 3508, + "question": "Compare the hardness of HT150 and annealed 20 steel", + "answer": "The tensile strength and hardness are not significantly different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的硬度，答案需要文字解释和论述，而不是简单的选择、判断或计算 | 知识层次: 题目要求比较两种材料的硬度，涉及对材料性能（如硬度和拉伸强度）的理解和关联分析。虽然不需要复杂的计算或深度机理分析，但需要综合运用材料科学的基本知识来比较和解释不同材料状态下的性能差异。这属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要比较两种材料的硬度，但题目已经给出了明确的比较对象（HT150和退火20钢）和结论（抗拉强度和硬度差异不大）。回答时需要简要说明两种材料的基本性质和热处理状态的影响，但不需要深入分析微观组织或进行复杂的计算。主要考察对材料基本性能的理解和简单比较能力，属于综合分析说明的等级3难度。" + }, + { + "idx": 3509, + "question": "Compare the anti-friction properties of HT150 and annealed 20 steel", + "answer": "HT150 has better anti-friction properties than 20 steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的抗摩擦性能，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的抗摩擦性能，需要理解HT150和20钢的基本特性，并分析退火处理对20钢性能的影响。这涉及多步概念关联和综合分析，但不需要深入机理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较两种材料的抗摩擦性能，但只需要进行基本的材料性能对比和简单分析，不需要多角度或深度关联性分析。解题步骤相对直接，主要涉及对HT150和20钢性能的理解和比较。" + }, + { + "idx": 3510, + "question": "In the graphitization process of cast iron, if the first stage is completely graphitized and the second stage is partially graphitized, what kind of microstructure cast iron is obtained?", + "answer": "F+P+G (graphite)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述特定条件下获得的铸铁微观结构，答案需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目需要理解铸铁石墨化过程的两个阶段及其对最终显微组织的影响，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解铸铁石墨化过程的两个阶段及其对最终组织的影响，并能正确描述获得的微观结构。虽然涉及多步概念关联，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 3511, + "question": "In the graphitization process of cast iron, if the first stage is completely graphitized and the second stage is not graphitized, what type of cast iron structure is obtained?", + "answer": "P+G (graphite)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答，答案形式为简短的文字描述（P+G (graphite)），而非选择、判断或计算。 | 知识层次: 题目考查对铸铁石墨化过程的基础概念记忆和理解，只需知道不同石墨化阶段对应的铸铁结构类型即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要考生理解铸铁石墨化过程的两个阶段及其对最终组织的影响，但只需简要说明\"P+G（石墨）\"这一特定结构即可，不需要深入分析或阐述复杂概念体系。题目考查的是对基础概念的记忆和简单应用，符合等级2的特征。" + }, + { + "idx": 3512, + "question": "Compare the machinability of HT150 and annealed 20 steel", + "answer": "The machinability of HT150 is better than that of 20 steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的可加工性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的机械加工性能，需要理解材料性能与加工性能之间的关系，并能够综合分析不同材料状态（HT150和退火20钢）对加工性能的影响。这涉及到多步分析和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要比较两种材料的机械加工性能，但主要涉及基本概念的理解和简单对比，不需要深入的多角度分析或复杂的关联性论述。解题步骤相对直接，只需说明HT150的机械加工性能优于20钢即可，不需要展开复杂的计算或深入的理论分析。" + }, + { + "idx": 3513, + "question": "Please indicate the type of cast iron and heat treatment method that should be used for the machine tool bed, and why?", + "answer": "Machine tool bed: gray cast iron, (as-cast) HT250, stress relief annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释选择特定铸铁类型和热处理方法的理由，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目要求选择适合机床床身的铸铁类型和热处理方法，并解释原因。这需要将材料性能（如灰铸铁的减震性和HT250的强度）与具体应用需求（机床床身需要高刚性和尺寸稳定性）相关联，进行多因素综合分析。虽然不涉及复杂计算，但需要理解材料特性与应用场景的匹配关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅需要正确选择铸铁类型和热处理方法，还需要解释为什么这种选择适用于机床床身。这涉及到对铸铁材料性能、机床床身的工作条件以及热处理方法作用的综合分析。虽然不需要进行深度关联性分析（如等级5所要求的），但需要从多个角度（材料性能、应用场景、工艺效果）进行论述，因此属于等级4的多角度分析论述难度。" + }, + { + "idx": 3514, + "question": "Compare the casting properties of HT150 and annealed 20 steel", + "answer": "The casting properties of HT150 are better than those of 20 steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的铸造性能，并给出解释性的答案，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较两种材料的铸造性能，需要理解HT150和20钢的基本特性，并分析其铸造性能的差异。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求比较HT150和退火20钢的铸造性能，需要考生理解两种材料的基本特性（如HT150是铸铁而20钢是碳钢），并能综合分析铸造性能的关键因素（如流动性、收缩性等）。虽然涉及多概念关联，但不需要深入探讨微观机制或进行复杂计算，属于典型的综合分析和说明类题目。" + }, + { + "idx": 3515, + "question": "Compare the tensile strength of HT150 and annealed 20 steel", + "answer": "The tensile strength of 20 steel is much higher than that of HT150.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种材料的拉伸强度，答案需要文字解释和论述，而不是简单的选择、判断或计算 | 知识层次: 题目要求比较两种材料的拉伸强度，属于对材料性能指标的直接应用，不需要复杂的分析或多步计算，只需基于已知的材料性能数据进行简单对比。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求比较两种材料的拉伸强度，只需要直接应用材料性能的基本知识，不需要复杂的计算或深入的分析。解题步骤简单，仅需陈述已知的材料性能差异即可。在同题型内，这属于较为基础的难度等级。" + }, + { + "idx": 3516, + "question": "Compare the forgeability of HT150 and annealed 20 steel", + "answer": "The forgeability of 20 steel is better than that of HT150 (HT150 cannot be forged).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的可锻性，并给出解释和论述，答案形式为文字解释而非选择、判断或计算。 | 知识层次: 题目要求比较两种材料的可锻性，需要理解材料的基本性质（如HT150的铸造特性与20钢的锻造特性）并进行综合分析。虽然不涉及复杂计算，但需要对材料性能有一定深度的理解和应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较两种材料的可锻性，但答案需要综合理解HT150和20钢的材料特性，并解释为什么20钢的可锻性更好。这涉及到对材料热处理和机械性能的基本理解，但不需要深入的多角度分析或复杂的关联性论述。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 3517, + "question": "In the graphitization process of cast iron, if the first stage is completely graphitized and the second stage is completely graphitized, what type of cast iron structure is obtained?", + "answer": "F+G (graphite)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个简短的描述性回答（F+G (graphite)），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查铸铁石墨化过程的基本概念和最终组织类型的记忆，属于基础概念记忆范畴 | 难度: 在简答题题型中，该题目仅要求回答一个具体的结构类型（F+G），属于基础定义简答级别。题目没有要求解释或描述石墨化过程或不同类型铸铁的区别，仅需记忆性知识即可回答。因此在该题型内属于最低难度等级。" + }, + { + "idx": 3518, + "question": "Please specify the type of cast iron and heat treatment method that should be used for diesel engine crankshafts, and why?", + "answer": "Crankshaft: ductile iron, QT800-2, quenching and tempering treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述特定材料选择和热处理方法的理由，答案提供了详细的文字说明而非简单的选择或判断 | 知识层次: 题目要求选择特定类型的铸铁和热处理工艺，并解释原因。这需要将材料性能（如球墨铸铁QT800-2的特性）与工程应用（柴油机曲轴的工作条件）相关联，进行多因素综合分析。虽然不涉及复杂计算，但需要理解材料选择与热处理的相互作用原理，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用材料科学知识进行多角度分析论述。题目要求不仅指定铸铁类型（球墨铸铁QT800-2）和热处理工艺（淬火+回火），还需要解释选择原因，涉及材料性能、工艺特点与曲轴工况要求的深度关联分析。解题步骤包括：1) 识别曲轴关键性能需求（强度、韧性、耐磨性）；2) 匹配材料特性（球墨铸铁的强度-韧性平衡）；3) 论证热处理工艺选择（通过淬火+回火获得回火索氏体组织）；4) 结合具体牌号QT800-2说明力学性能指标。这种需要建立\"工况-性能-材料-工艺\"完整逻辑链的论述题，在简答题中属于对综合分析能力要求较高的类型。" + }, + { + "idx": 3519, + "question": "Please indicate the type of cast iron and heat treatment method that should be used for plowshares, and why?", + "answer": "Plowshare: white cast iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述选择特定铸铁类型和热处理方法的理由，需要文字解释而非选择、判断或计算。 | 知识层次: 题目要求选择特定类型的铸铁和热处理方法来满足犁铧的使用需求，这需要理解不同铸铁类型的特性及其与热处理方法的关联，并进行综合分析以确定最适合的材料和工艺组合。虽然不涉及复杂计算，但需要对材料性能和应用场景有较深入的理解和关联分析。 | 难度: 在简答题题型中，该题目要求不仅指出正确的铸铁类型（白口铸铁），还需要解释选择该材料的原因，并涉及热处理方法的说明。这需要学生综合运用材料选择、性能要求和热处理知识，进行多角度的分析论述。相比只需简单回答的简答题（等级3），该题目对知识关联性和论述深度有更高要求，但尚未达到需要深度关联性分析的等级5水平。" + }, + { + "idx": 3520, + "question": "Please indicate the type of cast iron and heat treatment method that should be used for the hydraulic pump housing, and why?", + "answer": "Hydraulic pump housing: malleable cast iron, KΠ2650-02, graphitizing annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释选择特定铸铁类型和热处理方法的理由，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目要求选择适当的铸铁类型和热处理方法，并解释原因。这需要理解不同铸铁的特性、热处理方法及其对材料性能的影响，属于多概念关联和综合分析的应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅需要识别适用的铸铁类型和热处理方法，还需要解释为什么选择这些特定的材料和工艺。这涉及到多角度的分析论述，包括材料性能、应用场景和工艺选择的合理性。虽然不需要深度关联性分析（等级5），但已经超出了简单的概念关联和说明（等级3），因此属于等级4难度。" + }, + { + "idx": 3521, + "question": "Please specify the type of cast iron and heat treatment method that should be used for ball mill liners, and why?", + "answer": "Ball mill liners: alloy nodular cast iron (such as medium manganese cast iron).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述选择特定铸铁类型和热处理方法的理由，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目要求选择特定类型的铸铁和热处理方法来满足球磨机衬板的应用需求，这需要理解不同铸铁类型的性能特点及其与热处理方法的关联。虽然涉及基础概念的记忆，但更侧重于应用这些知识进行合理选择和解释，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用材料科学知识，包括材料选择（合金球墨铸铁）、热处理工艺（如中锰铸铁处理）以及应用场景（球磨机衬板）的多角度分析论述，并解释其背后的材料性能原理。" + }, + { + "idx": 3522, + "question": "Can aluminum alloys be strengthened through martensitic transformation like steel? Why?", + "answer": "No. Because aluminum alloys only undergo solubility changes during heating and cooling in the solid state, without allotropic transformation. Therefore, they can only be strengthened by quenching + aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么铝合金不能通过马氏体转变强化，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要综合运用材料科学中的相变理论、合金强化机制等知识，分析铝合金和钢在强化方式上的本质区别。不仅要求理解马氏体相变的概念，还需要解释铝合金为何不能通过该机制强化，并正确指出其强化方法（淬火+时效）。这涉及多知识点关联和机理解释，属于较高层次的综合分析能力。 | 难度: 在简答题-复杂分析题型中，该题目要求对铝合金和钢的强化机制进行机理层面的对比解释。需要掌握：1) 马氏体相变的基本原理；2) 铝合金固态相变特性；3) 两种材料强化路径的本质区别。虽然不涉及多因素交互作用(等级5特征)，但需要准确描述晶体结构变化限制和时效强化机理，属于需要机理深度解释的等级4难度。" + }, + { + "idx": 3523, + "question": "Explain the alloying principles of aluminum alloys", + "answer": "Alloying principles of aluminum alloys: Commonly added elements: Cu, Mg, Zn, Si, Mn", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释铝合金的合金化原理，答案提供了文字解释和列举了常见的添加元素，符合简答题的特征。 | 知识层次: 题目主要考查对铝合金合金化原理的基本概念和常用添加元素的记忆，属于基础概念记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释铝合金的合金化原理，涉及常见添加元素的基本记忆和简单描述。虽然需要列举具体元素并简要说明其作用，但不需要深入分析合金化机制或复杂相互作用，属于概念解释和描述的难度等级。" + }, + { + "idx": 3524, + "question": "Explain the role of Cu element in aluminum alloys", + "answer": "Copper in aluminum not only significantly enhances the room temperature strength of aluminum alloys through solid solution strengthening and precipitation strengthening, but also improves the heat resistance of aluminum alloys. Therefore, copper is a primary alloying element in high-strength aluminum alloys and heat-resistant aluminum alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铜元素在铝合金中的作用，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求解释铜元素在铝合金中的作用，涉及固溶强化和沉淀强化等概念的综合应用，需要理解并关联多个知识点，但不需要进行复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释铜元素在铝合金中的作用，涉及固溶强化和沉淀强化两个关键概念，并需要综合分析铜对铝合金室温和高温性能的影响。虽然需要关联多个概念，但不需要进行多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 3525, + "question": "Explain the role of Mn element in aluminum alloys", + "answer": "Manganese has low solubility in aluminum, resulting in limited solid solution strengthening capability. The second phase MnAl6 in the Al-Mn system has electrochemical properties similar to aluminum, providing good corrosion resistance. Therefore, manganese is often added to rust-proof aluminum alloys, with its wMn generally not exceeding 2%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Mn元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Mn元素在铝合金中的作用，涉及溶解度、固溶强化、第二相形成和腐蚀性能等多个概念的综合分析。虽然不需要复杂的计算或深度推理，但需要理解并关联多个知识点，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求解释Mn元素在铝合金中的作用，涉及溶解度、固溶强化、第二相MnAl6的电化学性质以及腐蚀性能等概念的综合分析。虽然需要关联多个知识点，但不需要进行多角度或深度关联性分析（等级4或5）。解题步骤相对直接，主要要求对相关概念的理解和串联，符合等级3\"综合分析和说明\"的标准。" + }, + { + "idx": 3526, + "question": "Explain the role of Si element in aluminum alloys", + "answer": "Similar to manganese, silicon has low solubility in aluminum, resulting in limited solid solution strengthening and insignificant precipitation strengthening effects. Therefore, it primarily relies on excess phase strengthening. The binary Al-Si system alloy has a low eutectic point, making it suitable for casting, and serves as the foundational alloy series for cast aluminum alloys, with wSi typically ranging from 10% to 13%. Silicon and magnesium can form Mg2Si precipitates in aluminum, which exhibit excellent strengthening effects. Hence, silicon can also be added as a precipitation strengthening element to magnesium-aluminum alloys, with its addition amount usually not exceeding wSi (1.0~1.2)%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释硅元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释硅元素在铝合金中的作用，涉及多个知识点（固溶强化、沉淀强化、共晶点等）的综合分析，需要理解硅在不同铝合金体系中的具体应用和效果，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对Si元素在铝合金中的作用进行多角度分析论述。需要理解并解释Si在铝合金中的多种作用机制，包括固溶强化、析出强化和过剩相强化等，并结合具体的合金系统（如Al-Si二元合金和Mg-Al合金）进行综合分析。此外，还需要涉及具体的成分范围（如wSi的百分比）和相形成（如Mg2Si析出相）的细节。这种要求超出了简单的概念解释，需要进行较为深入的多角度分析，因此在简答题中属于较高难度。" + }, + { + "idx": 3527, + "question": "Explain the role of Mg element in aluminum alloys", + "answer": "Magnesium has a good solid solution strengthening effect in aluminum, which can increase the strength of aluminum while also reducing its density. The precipitation strengthening effect of magnesium-aluminum alloys is not significant, but they exhibit good corrosion resistance and can be used as corrosion-resistant alloys. Magnesium cannot serve as the main additive element for high-strength aluminum alloys alone; it must be combined with other elements to fully utilize its effects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释镁元素在铝合金中的作用，涉及对镁的固溶强化效应、密度影响、腐蚀性能以及与其他元素的协同作用的综合分析。这需要理解镁在铝合金中的多种效应，并能够关联不同概念进行解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对镁元素在铝合金中的作用进行多角度分析论述，包括固溶强化效应、密度影响、沉淀强化效应、耐腐蚀性能以及与其他元素的协同作用。这需要考生不仅掌握相关概念，还能综合分析镁元素的多重作用机制，并论述其在实际应用中的限制和条件。因此，该题目在简答题题型中属于较高难度，符合等级4的标准。" + }, + { + "idx": 3528, + "question": "What is the difference between natural aging and artificial aging of aluminum alloys?", + "answer": "The process of spontaneous strengthening of the alloy at room temperature is called natural aging, while the aging process carried out at a certain heating temperature is called artificial aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释自然时效和人工时效的区别，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对自然时效和人工时效的基本定义和区别的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答自然时效和人工时效的基本定义，属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，仅需直接复述定义即可完成作答，因此属于该题型内最低难度等级。" + }, + { + "idx": 3529, + "question": "Can aluminum alloys be surface strengthened by carburizing or nitriding? Why?", + "answer": "No. Because the solubility of C and N in aluminum is very low, especially since aluminum has a strong affinity for oxygen, forming a very dense oxide film on the surface. This prevents the active atoms from being absorbed by the surface during carburizing or nitriding. Even if the active atoms are absorbed by the surface, the dense oxide film hinders the diffusion of these absorbed atoms toward the core. Therefore, aluminum alloys cannot be surface strengthened by carburizing or nitriding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么铝合金不能通过渗碳或渗氮进行表面强化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解铝及其合金的基本性质（如氧化膜的形成和碳、氮的溶解度），还需要分析这些性质如何影响表面强化工艺（如渗碳和氮化）的可行性。这涉及到多个概念的关联和综合运用，以及对机理的解释和推理分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求不仅回答是否可以进行表面强化，还需要详细解释为什么不能进行碳化或氮化处理。这涉及到对铝及其合金的物理和化学性质的深入理解，包括碳和氮在铝中的溶解度、铝与氧的亲和力以及表面氧化膜对扩散的影响。这些知识点需要综合运用材料科学的基础理论，并进行逻辑推理和机理分析，因此在简答题中属于较高难度。" + }, + { + "idx": 3530, + "question": "Taking A1-4Cu alloy as an example, explain the changes in microstructure and properties during the aging process.", + "answer": "Aging refers to the phenomenon where the supersaturated solid solution of aluminum alloy obtained after quenching decomposes over time at a certain temperature, leading to an increase in the strength and hardness of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释A1-4Cu合金在时效过程中微观结构和性能的变化，需要详细的文字论述和解释，符合简答题的特征。答案也提供了详细的文字解释，而非选择、判断或计算。 | 知识层次: 题目要求解释A1-4Cu合金在时效过程中微观结构和性能的变化，涉及对时效现象的理解、微观结构变化的描述以及性能变化的关联分析。这需要将多个概念（如过饱和固溶体、时效强化等）进行关联，并进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析和论述A1-4Cu合金在时效过程中的微观结构和性能变化。题目要求不仅解释时效现象，还需具体说明合金的强化机制和微观结构演变，涉及多步概念关联和综合分析。虽然不涉及复杂的数学计算，但对材料科学基础知识的掌握深度要求较高，属于该题型内需要多角度分析论述的难度等级。" + }, + { + "idx": 3531, + "question": "Explain the role of Zn element in aluminum alloys", + "answer": "Zinc has a high solubility in aluminum and exhibits strong solid solution strengthening capability. A small amount of zinc (wZn=(0.4~0.8)%) can enhance the strength and corrosion resistance of aluminum alloys. In multi-component aluminum alloys, zinc serves as an element that forms precipitation strengthening phases, significantly improving the precipitation strengthening effect of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释锌元素在铝合金中的作用，需要文字解释和论述，答案提供了详细的描述和说明，符合简答题的特征。 | 知识层次: 题目要求解释锌元素在铝合金中的作用，涉及锌的溶解度、固溶强化能力以及对合金强度和耐腐蚀性的影响。这需要理解锌在铝合金中的行为，并关联多个概念（如固溶强化、沉淀强化）进行综合分析。虽然不涉及复杂计算或深度机理分析，但需要多步概念关联和中等程度的综合分析能力。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求解释锌元素在铝合金中的作用，涉及对溶解度、固溶强化、腐蚀性能以及多组分合金中沉淀强化相形成的综合分析。虽然需要关联多个概念，但不需要进行多角度或深度关联性分析（等级4或5的要求）。解题步骤主要是对锌元素在铝合金中的几种关键作用进行说明和论述，属于典型的综合分析和说明类型题目。" + }, + { + "idx": 3532, + "question": "What is the principle for selecting natural aging or artificial aging?", + "answer": "The principles for choosing between artificial aging and natural aging are: ① Determine the aging method (natural or artificial) based on the working temperature of the part; ② Consider the required aging strengthening effect for the part; ③ Take into account the type of aluminum alloy, batch size of the workpiece, production efficiency, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释选择自然时效或人工时效的原则，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释选择自然时效或人工时效的原则，涉及多个因素的考虑（工作温度、强化效果、铝合金类型等），需要综合分析不同条件下的适用性，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生进行多角度分析论述，涉及工作温度、强化效果、铝合金类型、工件批量等多个因素的关联考虑。虽然不需要进行深度关联性分析（如跨学科或复杂系统分析），但需要综合多个技术参数进行系统说明，属于该题型中较高难度的要求。" + }, + { + "idx": 3533, + "question": "How many types of titanium alloys are there?", + "answer": "Titanium alloys are classified into α titanium alloys, α+β titanium alloys, and β titanium alloys", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钛合金的分类，答案提供了详细的文字说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查钛合金的基本分类记忆，属于基础概念的记忆和理解，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目要求回答钛合金的分类，属于概念解释和描述的难度等级。虽然需要记忆三种钛合金的分类，但不需要深入阐述其复杂原理或相互关系，属于中等难度的概念性简答题。" + }, + { + "idx": 3534, + "question": "Briefly describe the generation of solid solution strengthening and provide examples", + "answer": "Solid solution strengthening refers to the increase in strength by adding alloying elements to form solid solutions with aluminum. Commonly used alloying elements include Cu, Mg, Zn, Si, etc. These elements can form limited solid solutions with aluminum and have significant solubility, resulting in effective solid solution strengthening, thus serving as the primary alloying elements in aluminum alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述固溶强化的产生并提供例子，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对固溶强化这一基本概念的记忆和理解，以及常见合金元素的举例，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述固溶强化的产生原理并提供例子，这需要学生对固溶强化的基本概念有一定理解，并能列举相关合金元素作为实例。虽然涉及多个知识点（定义、原理、实例），但不需要深入分析或构建复杂的概念体系，符合等级2对概念解释和描述的要求。" + }, + { + "idx": 3535, + "question": "Briefly describe the generation of dispersion strengthening and provide examples", + "answer": "Excess phase (second phase) strengthening: When the content of alloying elements in an alloy exceeds the solubility limit, there will be some undissolved second phases present in the matrix (solid solution), also known as excess phases. In aluminum alloys, excess phases are mostly hard and brittle intermetallic compounds, which also hinder dislocation movement, increasing the strength and hardness of the alloy while reducing its plasticity and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述分散强化的产生并提供例子，答案通过文字解释和论述来回答问题，没有涉及选择、判断或计算。 | 知识层次: 题目考查对分散强化生成的基本概念的记忆和理解，包括定义、基本原理和简单例子，不涉及复杂的应用或分析。 | 难度: 在简答题题型框架内，该题目属于概念解释和描述难度等级。题目要求简要描述弥散强化的产生原理并举例说明，这需要学生掌握基础概念（如第二相、溶解度极限等）并能进行简单的原理阐述。虽然涉及多个概念点的联系，但不需要构建复杂的理论体系或进行深入分析，符合等级2\"概念解释和描述\"的特征。相比等级1的纯定义复述，该题需要一定的理解性记忆；相比等级3的体系化阐述，其知识整合要求较为基础。" + }, + { + "idx": 3536, + "question": "Briefly describe the differences between solution strengthening, dispersion strengthening, and age strengthening", + "answer": "Solution strengthening improves strength by forming solid solutions with alloying elements and the matrix; dispersion strengthening enhances strength by impeding dislocation movement through undissolved second phases (excess phases); age strengthening is achieved by heat treatment to form supersaturated solid solutions and precipitate transition phases or transition zones. Both solution strengthening and age strengthening involve solid solutions, but age strengthening requires subsequent heat treatment processes, while dispersion strengthening does not rely on heat treatment but rather on the formation of second phases due to alloying elements exceeding solubility limits.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述三种强化机制的区别，答案通过文字解释和论述来回答，没有选项、判断或计算的要求。 | 知识层次: 题目要求解释三种强化机制的区别，涉及多个概念的理解和关联，需要综合分析不同强化方法的原理和条件，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析和比较三种强化机制（固溶强化、弥散强化和时效强化）的异同点。题目要求不仅描述每种机制的基本原理，还要指出它们之间的关键区别（如是否涉及热处理、第二相形成方式等）。这需要学生对材料强化机制有较深入的理解，并能进行多角度的关联分析。虽然不需要达到深度关联性分析（等级5）的程度，但已明显超出简单概念复述的范畴。" + }, + { + "idx": 3537, + "question": "Compare the microstructure, properties, and heat treatment characteristics of brass.", + "answer": "
MaterialMicrostructurePropertiesHeat Treatment
Brassα (Cu-Zn solid solution) or α+βExcellent corrosion resistance, thermal conductivity, good cold (or hot) working propertiesStress relief annealing
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较黄铜的微观结构、性能和热处理特性，需要详细的文字解释和论述，答案以表格形式呈现了相关信息，符合简答题的特征。 | 知识层次: 题目要求比较黄铜的微观结构、性能和热处理特性，需要综合多个知识点进行分析和关联，涉及多步思考和概念的综合运用，但不需要深度推理或创新设计。 | 难度: 在简答题题型中，该题目要求对黄铜的微观结构、性能和热处理特性进行多角度的分析和论述。需要综合运用材料科学知识，对不同方面进行关联性说明，并详细解释各特性之间的关系。虽然不涉及深度关联性分析（等级5），但已超出基础的综合分析（等级3），属于多角度分析论述的难度等级。" + }, + { + "idx": 3538, + "question": "Compare the microstructure, properties, and heat treatment characteristics of bronze.", + "answer": "
MaterialMicrostructurePropertiesHeat treatment
Bronzea (Cu-Sn) or (a+0) eutectoidExcellent casting performance, corrosion resistance, hot and cold pressure processing performance, certain wear resistance and antifriction properties, can be used as bearing alloyQuenching + aging (beryllium bronze)
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较青铜的微观结构、性能和热处理特性，答案以表格形式详细列出了这些方面的具体内容，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较青铜的微观结构、性能和热处理特性，涉及多个知识点的关联和综合分析，需要理解不同特性之间的关系并进行多方面的论述，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对青铜的微观结构、性能和热处理特性进行多角度的分析和论述。需要综合运用材料科学的知识，对不同方面进行详细说明，并能够关联这些特性之间的关系。虽然不涉及深度关联性分析，但需要较为全面的知识掌握和综合分析能力，因此属于等级4的难度。" + }, + { + "idx": 3539, + "question": "How to choose tin-based and lead-based babbitt alloys?", + "answer": "Tin-based bearing alloys are suitable for high-speed bearings. Lead-based bearing alloys are mostly used for small and low-speed ordinary machinery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释如何选择锡基和铅基巴氏合金，答案提供了文字解释和论述，说明两种合金的适用场景，符合简答题的特征。 | 知识层次: 题目考查对锡基和铅基巴氏合金选择的基本概念记忆和理解，涉及它们的适用场景分类，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对两种轴承合金的应用场景进行解释和描述，属于概念解释和描述的难度等级。虽然需要记忆和区分两种合金的基本特性，但不需要深入分析或构建复杂的概念体系，因此属于中等难度。" + }, + { + "idx": 3540, + "question": "Briefly describe the occurrence of age strengthening and provide examples", + "answer": "Age strengthening (precipitation strengthening): The main heat treatment method for strengthening aluminum alloys is solution treatment (quenching) followed by aging. To achieve strong precipitation hardening effects, certain conditions must be met: the elements added to aluminum should have a high ultimate solubility, and this solubility should significantly decrease with temperature reduction; after quenching, a supersaturated solid solution should form, which can precipitate uniform and dispersed coherent or semi-coherent transition zones or transition phases during aging, creating a strong strain field in the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述时效强化的发生过程并提供例子，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求解释时效强化的发生机制，并举例说明。这需要综合运用材料科学中的相变、固溶体、沉淀相等多个知识点，进行机理分析和解释。同时，还需要理解时效强化的条件和过程，涉及较深的思维过程和知识关联度。 | 难度: 在简答题题型中，该题目要求对时效强化现象进行机理层面的解释，包括固溶处理、淬火、时效过程以及相关条件的具体描述。虽然不涉及多个复杂现象的交叉分析（等级5特征），但需要对材料强化机理有较深入的理解和系统阐述，属于机理深度解释的范畴。" + }, + { + "idx": 3541, + "question": "Compare the microstructure, properties, and heat treatment characteristics of cupronickel.", + "answer": "
MaterialMicrostructurePropertiesHeat treatment
Cupronickelα (Cu-Ni solid solution)Good strength, excellent plasticity allowing hot and cold deformation, good corrosion resistance, high resistivityStress relief annealing
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较铜镍合金的微观结构、性能和热处理特性，需要文字解释和论述，答案以表格形式呈现了详细的比较内容，符合简答题的特征。 | 知识层次: 题目要求比较铜镍合金的微观结构、性能和热处理特性，涉及多个知识点的关联和综合分析，需要理解材料科学中的基本概念并能进行中等程度的综合应用。 | 难度: 在简答题题型中，该题目要求对cupronickel的微观结构、性能和热处理特性进行多角度的分析和论述。需要综合运用材料科学知识，对不同方面进行关联性说明，并能够清晰表达。虽然不需要进行深度关联性分析（等级5），但已经超出了基础说明的范畴（等级3），属于需要多角度分析论述的中高难度题目。" + }, + { + "idx": 3542, + "question": "What are the characteristics of the microstructure, properties, and applications of typical α titanium alloys?", + "answer": "Microstructure: α or α + trace intermetallic compounds (annealed microstructure); Property characteristics: lower room temperature strength compared to other types of titanium alloys, but highest creep strength among titanium alloys at high temperatures (500~600°C), excellent corrosion resistance, good weldability, and retains good plasticity and toughness even at ultra-low temperatures (-253°C); Applications: parts with low strength requirements working below 500°C, pressure vessel materials in aerospace.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述α钛合金的微观结构、性能特点和应用领域，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对α钛合金的微观结构、性能特点和应用进行综合描述，涉及多个知识点的关联和综合分析，需要理解材料性能与微观结构的关系，并能够将理论知识应用到具体情境中。 | 难度: 在简答题题型中，该题目要求对α钛合金的微观结构、性能特点和应用进行多角度的分析和论述。需要综合理解多个概念（如微观结构、力学性能、高温性能、耐腐蚀性等），并将这些概念关联起来进行详细说明。此外，题目还要求对不同应用场景下的性能优势进行具体分析，这增加了答题的复杂性和深度。因此，在简答题题型中，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 3543, + "question": "What are the characteristics of the microstructure, properties, and applications of typical β titanium alloys?", + "answer": "Microstructure: β (quenched structure); Property characteristics: high strength, excellent stamping performance, can be strengthened by quenching and aging; Applications: parts working below 350°C, compressor blades, aircraft components", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对典型β钛合金的微观结构、性能和应用进行文字解释和论述，答案提供了详细的描述而非选择或判断。 | 知识层次: 题目要求对β钛合金的微观结构、性能特点和应用进行综合描述，涉及多个知识点的关联和综合分析，需要理解材料性能与微观结构的关系，并能够结合实际应用场景进行论述。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在简答题题型中，该题目要求对β钛合金的微观结构、性能特点和应用进行多角度分析论述。需要综合理解材料科学中的相变、强化机制和工程应用等多个概念，并进行关联性分析。虽然不涉及深度关联性分析（如与其他合金体系的对比或热力学计算），但仍需较全面的知识掌握和逻辑组织能力，属于该题型内较高难度的题目。" + }, + { + "idx": 3544, + "question": "What are the characteristics of Babbitt alloy in terms of lubrication principle?", + "answer": "It belongs to friction under the lubricating film. In terms of lubrication principle, it relies on the lubricating film formed between the shaft and the bearing bush to reduce the friction coefficient, thereby minimizing wear between the shaft and the bearing bush.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Babbitt合金在润滑原理方面的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Babbitt合金在润滑原理方面的基本特性，属于对材料基本原理和特性的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目要求解释Babbitt合金的润滑原理特点，涉及概念解释和描述，但不需要复杂的体系阐述。属于中等难度，需要理解并表述润滑膜的形成和作用机制，但不需要深入分析或比较多个相关概念。" + }, + { + "idx": 3545, + "question": "The twinning plane of a face-centered cubic crystal is ( ) A.(112} B.{110} C.111", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查面心立方晶体孪晶面的基本概念记忆，属于对晶体学基础知识的直接回忆和识别。 | 难度: 在选择题中属于中等偏下难度，需要理解面心立方晶体的孪晶面概念，并对常见晶面族{112}、{110}、{111}进行简单辨析。虽然不涉及复杂计算，但需要掌握基本的晶体学知识才能正确选择。" + }, + { + "idx": 3546, + "question": "What are the differences between tin-based and lead-based Babbitt alloys?", + "answer": "Tin-based bearing alloy: It has a small coefficient of expansion, good embeddability and friction reduction, excellent toughness, thermal conductivity, and corrosion resistance, making it suitable for high-speed bearings. Lead-based bearing alloy: Its strength, hardness, wear resistance, and toughness are lower than those of tin-based alloys, but it is inexpensive and commonly used in small and low-speed ordinary machinery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两种Babbitt合金的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对两种Babbitt合金的基本特性和应用的理解和记忆，不涉及复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求对两种Babbitt合金的基本特性进行比较和描述，涉及多个性能参数的对比。虽然需要记忆和解释多个概念，但不需要构建复杂的逻辑体系或深入分析机理，属于概念解释和描述的中等难度级别。" + }, + { + "idx": 3547, + "question": "What are the characteristics of the microstructure, properties, and applications of typical α+β titanium alloys?", + "answer": "Microstructure: α+β (annealed microstructure); Property characteristics: high strength, good plasticity, stable microstructure at 400°C, high creep strength, good plasticity and resistance to seawater and thermal stress corrosion at low temperatures; Applications: parts working below 400°C, manufacturing of aircraft engine blades, rocket engines", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对典型α+β钛合金的微观结构、性能和应用特点进行文字解释和论述，答案提供了详细的文字描述而非选择或计算。 | 知识层次: 题目要求对α+β钛合金的微观结构、性能特点和应用进行综合描述，涉及多个知识点的关联和综合分析，需要理解材料性能与微观结构的关系，并能够结合实际应用场景进行论述。 | 难度: 在简答题题型内，该题目要求对α+β钛合金的微观结构、性能特点和应用进行多角度的分析和论述。需要综合理解材料科学中的多个概念，如微观结构对性能的影响、不同温度下的性能表现以及具体应用场景的选择依据。虽然不需要进行深度关联性分析，但需要较为全面的知识掌握和逻辑组织能力，属于较高难度的简答题。" + }, + { + "idx": 3548, + "question": "Why is Babbitt alloy wear-resistant?", + "answer": "Because the structural characteristic of tin-based bearing alloy is the distribution of hard particles on a soft matrix. If the structure of the bearing alloy consists of hard particles distributed on a soft matrix, during operation, the soft matrix will wear and become recessed, causing the hard particles to protrude from the matrix. This reduces the contact area between the shaft and the bearing bush, while the recesses can store lubricating oil, lowering the friction coefficient between the shaft and the bearing bush and reducing wear. Additionally, the soft matrix can withstand impact and vibration, allowing the shaft and bearing bush to fit well together and also embed small foreign hard particles, ensuring the shaft journal is not scratched, thus providing excellent wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Babbitt合金耐磨的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解Babbitt合金的基本结构特征，还需要分析其在实际工作条件下的磨损机制、润滑原理以及对外界冲击和振动的适应性。这涉及到多个知识点的综合运用和深入分析，属于复杂分析的层次。 | 难度: 在简答题题型中，该题目要求对Babbitt合金的耐磨机理进行全面分析，涉及结构特性、磨损过程、润滑机制以及抗冲击性能等多个方面的综合解释。需要考生具备深入的材料科学知识，能够将理论知识与实际应用相结合，进行复杂的推理和解释。这种全面分析的要求使得该题目在同题型内属于最高难度等级。" + }, + { + "idx": 3549, + "question": "In a crystal, the defect formed by simultaneously creating a vacancy and an interstitial atom is called ( ). A. Schottky defect B. Frenkel defect C. Interstitial defect", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查晶体缺陷的基本概念记忆，特别是Schottky缺陷和Frenkel缺陷的定义和区分，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体缺陷的基本概念并进行简单辨析。题目考察的是Frenkel缺陷的定义，虽然需要区分Schottky缺陷和Frenkel缺陷，但概念相对明确，属于基础概念记忆和理解范畴。" + }, + { + "idx": 3550, + "question": "The difference between cast iron and carbon steel lies in the presence or absence of ( )", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（A） | 知识层次: 题目考查铸铁和碳钢的基本区别，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题题型中，此题属于基础概念的直接记忆和识别。题目仅考察铸铁与碳钢的最基本区别（是否存在某种成分），不需要进行概念辨析或深度理解，符合等级1\"简单概念识别，直接记忆\"的标准。同类选择题中，这是最基础的知识点考察形式。" + }, + { + "idx": 3551, + "question": "In a body-centered cubic structure with lattice constant a, can a dislocation with Burgers vector $a$ [100] decompose into $\\frac{a}{2}$ [111] + $\\frac{a}{2}$ [1-1-1]? ( )", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（A） | 知识层次: 题目涉及位错分解的判断，需要理解Burgers矢量的概念和立方晶体结构中的位错反应，并进行简单的矢量计算和能量分析。这属于中等应用层次，需要多步计算和概念关联。 | 难度: 在选择题中属于较高难度，需要理解位错分解的基本原理，进行矢量分解计算，并判断是否符合能量条件和几何条件。题目涉及多个概念的综合应用和复杂分析过程，属于复杂分析过程的判断类型。" + }, + { + "idx": 3552, + "question": "Someone said: 'A precipitation-hardening alloy can be softened by water quenching at an appropriate temperature.' Is this statement correct? Explain.", + "answer": "A precipitation-hardening alloy cannot be softened by water quenching at an appropriate temperature. The reason is that when heated to a high temperature, it forms a single solid solution structure. Rapid cooling results in a single solid solution, which, although not very hard at this stage, will subsequently undergo precipitation hardening. Therefore, a precipitation-hardening alloy can only be softened through an aging process.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求判断陈述的对错，并解释原因。答案中明确指出了陈述的错误，并提供了详细的解释。 | 知识层次: 题目不仅需要理解沉淀硬化合金的基本原理，还需要分析水淬工艺对材料性能的影响机制，并解释为什么水淬不能软化该合金而需要时效处理。这涉及对材料相变、热处理工艺和性能变化之间复杂关系的深入理解和综合分析。 | 难度: 在判断题 - 判断陈述的对错这一题型中，该题目属于深度分析结论判断难度。题目不仅要求判断陈述的正确性，还需要解释背后的机理，涉及对沉淀硬化合金的热处理过程和微观结构变化的深入理解。解题步骤复杂，需要综合运用材料科学知识进行推理分析，解释为什么水淬不能软化沉淀硬化合金，以及正确的软化方法。因此，在同题型内属于最高难度等级。" + }, + { + "idx": 3553, + "question": "Please list several examples of strengthening alloys during the casting process", + "answer": "For example, the inoculation treatment of gray cast iron (adding about $4\\%$ ferrosilicon or calcium-silicon alloy to the molten iron during casting for inoculation treatment), and the modification treatment of aluminum-silicon alloys (adding a modifier $\\frac{2}{3}\\mathrm{{NaF}+}$ $\\frac13\\mathrm{NaCl}$ to the alloy melt before pouring)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举几个例子来说明铸造过程中强化合金的方法，答案提供了具体的实例和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求列举铸造过程中强化合金的具体例子，涉及对特定处理方法的记忆和简单应用，不需要复杂的分析或综合。虽然需要理解处理方法的原理，但主要考查的是对已知知识的直接应用和列举能力。 | 难度: 在简答题中属于较高难度，题目要求不仅列举强化合金的具体例子，还需要详细解释每个例子的具体处理方法和添加物比例。这需要学生对铸造过程中的合金强化技术有深入的理解和记忆，并能准确描述具体的工艺参数和材料配比。相比简单的概念描述或单一方法说明，这种要求多个实例详细解释的题目在该题型内难度较高。" + }, + { + "idx": 3554, + "question": "In substitutional solid solutions, the general mode of atomic diffusion is (). \\n\\nA. Atomic exchange mechanism B. Interstitial mechanism C. Vacancy mechanism", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确答案 | 知识层次: 题目考查的是对置换固溶体中原子扩散机制的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解替代固溶体中原子扩散的基本机制，并在几个选项中做出简单辨析。虽然涉及基础概念记忆，但需要区分不同扩散机制（空位机制、间隙机制等），属于概念理解和简单辨析的层次。" + }, + { + "idx": 3555, + "question": "Fick's first law describes the characteristics of steady-state diffusion, where the concentration does not vary with ( ). \\n\\nA. distance B. time C. temperature", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查Fick第一定律的基本概念，即稳态扩散中浓度不随时间变化的特性，属于基础概念的记忆和理解。 | 难度: 在选择题中属于简单难度，直接考察对Fick第一定律基本概念的记忆，只需识别出稳态扩散中浓度不随时间变化这一关键点，无需复杂辨析或深度理解。" + }, + { + "idx": 3556, + "question": "When a critical nucleus forms, the decrease in volume free energy can only compensate for ( ) of the surface energy.", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了多个选项（虽然具体选项未列出，但答案标记为B表明是选择题） | 知识层次: 题目考查对临界核形成时体积自由能和表面能关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解临界核形成时体积自由能与表面能量的补偿关系，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 3557, + "question": "In the Kirkendall effect, the main reason for marker drift is ( ) in the diffusion couple.", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项字母形式给出 | 知识层次: 题目考查Kirkendall效应的基本概念和原因的记忆，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏易难度，需要理解Kirkendall效应的基本原理和标记漂移的原因，但不需要进行复杂的概念区分或深度分析。" + }, + { + "idx": 3558, + "question": "In cubic crystals, the (110) and (211) planes belong to the same () zone.", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（D） | 知识层次: 题目需要理解立方晶体中晶面指数的概念，并能够应用晶带定律（zone law）来判断(110)和(211)平面是否属于同一晶带。这涉及到多步计算和概念关联，需要综合分析晶面指数和晶带轴的关系，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解立方晶系中晶面指数的概念，掌握晶带轴的计算方法，并能综合分析(110)和(211)平面的共同晶带轴。这涉及到多步计算和概念关联，比单纯记忆概念的选择题要复杂。" + }, + { + "idx": 3559, + "question": "In a binary phase diagram, the lever rule for calculating the relative amounts of two phases can only be applied in ().", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项B作为答案 | 知识层次: 题目考查对杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题中属于中等偏下难度，需要理解杠杆规则的应用条件，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 3560, + "question": "In the concentration triangle of a ternary phase diagram, alloys whose compositions lie on the () have equal contents of the two components represented by the other two vertices.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对三元相图浓度三角形中特定组成线（等含量线）的基础概念记忆和理解，属于基本概念的记忆性知识。 | 难度: 在选择题中属于简单难度，题目直接考察对三元相图浓度三角形中特定位置的定义记忆，无需复杂理解或辨析，只需识别并回忆基础概念即可作答。" + }, + { + "idx": 3561, + "question": "When a pure metal undergoes allotropic transformation during cooling from high temperature to room temperature with volume expansion, the atomic coordination number of the low-temperature phase is () compared to that of the high-temperature phase.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查同素异构转变过程中原子配位数变化的基本概念记忆，属于对基础概念的理解和记忆层次，不涉及复杂计算或综合分析。 | 难度: 在选择题中属于中等难度，需要理解同素异构转变的基本概念以及原子配位数的变化规律，并进行简单辨析。题目涉及高温相和低温相的体积变化与配位数的关系，需要一定的概念理解而非纯粹记忆。" + }, + { + "idx": 3562, + "question": "The packing density of a simple cubic crystal is ( ). \\n\\nA. $100\\\\%$ B.65% C.52% D.58%", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，且答案形式为选项中的一个（C）。 | 知识层次: 题目考查简单立方晶体堆积密度的基本概念记忆，属于晶体学基础知识的直接回忆。 | 难度: 在选择题中属于简单难度，仅需记忆简单立方晶体的堆积密度这一基础概念，无需复杂理解或辨析。" + }, + { + "idx": 3563, + "question": "When the deformed material is heated up again, recovery and recrystallization phenomena occur, then the significant decrease in point defect concentration happens during ().", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（虽然具体选项未列出，但答案标记为A表明是选择题形式） | 知识层次: 题目考查对材料科学中恢复和再结晶现象的基本概念记忆，特别是点缺陷浓度变化与这些现象的关系，属于基础概念的记忆和理解层面。 | 难度: 在选择题中属于中等偏下难度，需要理解恢复和再结晶过程中点缺陷浓度的变化，但不需要复杂的辨析或深度理解多个概念。" + }, + { + "idx": 3564, + "question": "For two parallel screw dislocations, when their Burgers vectors are in the same direction, the interaction force between them is (). \\n\\nA. zero B. repulsive C. attractive", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择关于两个平行螺型位错之间相互作用力的正确答案 | 知识层次: 题目考查对平行螺型位错相互作用力的基本理解，需要应用位错相互作用的基本原理来判断力的方向，属于直接套用基本概念的简单应用。 | 难度: 在选择题中属于简单难度，只需要直接应用平行螺型位错相互作用力的基本概念，无需公式变形或多步骤推理。题目明确给出了Burgers矢量同向的条件，可直接套用\"同向相斥\"的结论。" + }, + { + "idx": 3565, + "question": "The dislocations that can undergo cross-slip must be (). \\n\\nA. Edge dislocation B. Screw dislocation C. Mixed dislocation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查位错类型的基本概念记忆，特别是关于螺型位错（screw dislocation）的特性，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解位错的基本类型（刃型位错、螺型位错、混合位错）及其特性，并能简单辨析哪种位错可以进行交滑移。虽然涉及概念理解，但不需要复杂的分析或深度推理。" + }, + { + "idx": 3566, + "question": "The dislocation that cannot undergo climb motion is (). \\n\\nA. Shockley partial dislocation B. Frank partial dislocation C. Edge full dislocation", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查位错类型及其运动特性的基本概念记忆，属于对位错分类和基本特性的直接考察，不需要复杂的分析或推理过程。 | 难度: 在选择题中属于中等偏下难度，需要理解位错的基本类型及其运动特性，并进行简单辨析。题目考察的是对Shockley部分位错、Frank部分位错和刃型全位错运动特性的区分，但不需要复杂的推理或深度理解。" + }, + { + "idx": 3567, + "question": "The fundamental reason for diffusion to occur in materials is ( ). \\n\\nA. Temperature changes B. Concentration gradient exists C. Chemical potential gradient exists", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查扩散现象的基本原理，属于对化学势梯度这一基础概念的简单记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解扩散的基本原理并区分温度变化、浓度梯度和化学势梯度这三个概念。虽然不涉及复杂计算或深度推理，但需要对材料科学基础概念有一定理解才能正确选择化学势梯度作为扩散的根本原因。比直接记忆定义稍难，但比需要综合分析多个因素的题目简单。" + }, + { + "idx": 3569, + "question": "The relationship between the probability of annealing twin formation and the stacking fault energy of a crystal is ( ). \\n\\nA. Unrelated, only depends on annealing temperature and time\\nB. Crystals with low stacking fault energy have a higher probability of forming annealing twins\\nC. Crystals with high stacking fault energy have a higher probability of forming annealing twins", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查了堆垛层错能与退火孪晶形成概率之间的关系，需要理解两者之间的关联性并进行综合分析，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解堆垛层错能和退火孪晶形成概率之间的关系，并进行概念关联分析。虽然不涉及多步计算，但需要对材料科学中的基本概念有较好的掌握才能正确选择。" + }, + { + "idx": 3570, + "question": "Temperature indicators are sometimes produced from a coiled metal strip that uncoils a specific amount when the temperature increases. How does this work?", + "answer": "Bimetallic materials are produced by bonding two materials having different coefficients of thermal expansion to one another, forming a laminar composite. When the temperature changes, one of the materials will expand or contract more than the other material. This difference in expansion or contraction causes the bimetallic material to change shape; if the original shape is that of a coil, then the device will coil or uncoil, depending on the direction of the temperature change.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释双金属材料的工作原理，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释双金属材料的工作原理，涉及两种材料的热膨胀系数差异及其导致的形状变化，需要理解概念并关联实际应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及双金属材料的热膨胀原理，但解答过程主要围绕单一核心概念展开，不需要多角度分析或深度关联性分析。解题步骤包括解释双金属材料的构成、热膨胀差异导致的形变机制，以及具体应用场景的说明，这些都属于概念关联和综合分析的范畴，但尚未达到多角度或深度分析的要求。" + }, + { + "idx": 3571, + "question": "From what kind of material would the temperature indicator be made?", + "answer": "The temperature indicator is made from bimetallic materials, which consist of two materials with different coefficients of thermal expansion bonded together.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释温度指示器的材料类型，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对温度指示器材料的基本概念记忆，即双金属材料的定义和基本原理，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释温度指示器的材料类型及其基本原理，涉及对bimetallic materials的定义和热膨胀系数差异的描述。虽然需要一定的概念理解和记忆，但不需要复杂的体系阐述或多步骤推理，属于中等难度的概念解释类简答题。" + }, + { + "idx": 3572, + "question": "What are the important properties that the material in the temperature indicator must possess?", + "answer": "In order for the material to perform well, the two materials must have very different coefficients of thermal expansion and should have high enough modulus of elasticity so that no permanent deformation of the material occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释材料在温度指示器中必须具有的重要性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释温度指示器材料必须具有的重要性能，涉及热膨胀系数和弹性模量的概念关联和综合分析，需要理解这些性能如何共同作用以实现材料的功能，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解材料的热膨胀系数和弹性模量的概念，并说明这些性能如何影响温度指示器的功能。虽然题目要求综合分析，但不需要多角度或深度关联性分析，只需对关键性能进行说明和论述。" + }, + { + "idx": 3573, + "question": "What properties should the head of a carpenter's hammer possess?", + "answer": "The striking face and claws of the hammer should be hard-the metal should not dent or deform when driving or removing nails. Yet these portions must also possess some impact resistance, particularly so that chips do not flake off the striking face and cause injuries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释木工锤头应具备的性能，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求分析木工锤头应具备的性能，涉及硬度与抗冲击性的平衡，需要理解材料性能与使用场景的关联，属于中等应用层次的知识运用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求分析锤头的性能，但答案只需要综合说明硬度和抗冲击性两个关键属性，并简要解释其重要性。不需要多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3574, + "question": "How would you manufacture a hammer head?", + "answer": "The head for a carpenter's hammer is produced by forging, a metalworking process; a simple steel shape is heated and formed in several steps while hot into the required shape. The head is then heat treated to produce the required mechanical and physical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何制造锤头，答案提供了详细的文字描述和步骤说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释制造锤头的具体工艺步骤（锻造和热处理），涉及金属加工工艺的多个步骤和概念关联，需要综合分析材料加工方法和热处理对性能的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释和论述制造锤头的具体过程，但涉及的知识点较为基础，主要包括锻造和热处理两个主要步骤。解题步骤相对简单，不需要多角度或深度关联性分析。因此，在简答题题型内，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 3575, + "question": "Aluminum foil used for storing food weighs about 0.3g per square inch. How many atoms of aluminum are contained in one square inch of foil?", + "answer": "6.69 × 10^{21} atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及单位转换和摩尔计算，答案是一个具体的数值结果。 | 知识层次: 题目需要进行基本的单位转换和摩尔质量计算，涉及简单的公式应用和数值计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用摩尔质量和阿伏伽德罗常数的基本公式，并进行简单的单位转换和数值计算。虽然涉及多个步骤，但每一步都是直接套用基本公式，没有复杂的组合或推导过程。因此，在计算题题型内属于等级2难度。" + }, + { + "idx": 3576, + "question": "Using the densities and atomic weights, calculate the number of atoms per cubic centimeter in lead.", + "answer": "3.3 × 10^22 atoms/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过密度和原子量计算铅中每立方厘米的原子数，需要数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目要求使用密度和原子量进行简单的数值计算，属于基本公式的直接应用，不需要多步计算或复杂的概念关联。 | 难度: 在计算题中属于单一公式直接计算的难度等级，只需要应用密度和原子重量的基本公式进行简单计算即可得出结果，无需多个公式组合或复杂步骤。" + }, + { + "idx": 3577, + "question": "Using the densities and atomic weights, calculate the number of atoms per cubic centimeter in lithium.", + "answer": "4.63 × 10^22 atoms/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过密度和原子量计算锂中每立方厘米的原子数，需要数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目需要应用密度和原子质量的基本公式进行计算，属于直接套用公式的简单应用，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于基础难度，仅需直接套用密度和原子量的基本公式进行单一计算，无需组合多个公式或进行复杂转换。解题步骤仅涉及单位换算和简单除法，符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 3578, + "question": "Using data, calculate the number of iron atoms in one ton (2000 pounds).", + "answer": "9.79 × 10^{27} atoms/ton", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用数据进行数值计算（计算铁原子数量），答案是一个具体的数值结果（9.79 × 10^{27} atoms/ton），符合计算题的特征。 | 知识层次: 题目需要进行基本的单位转换和摩尔质量计算，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用基本公式（如摩尔质量和阿伏伽德罗常数）进行直接计算，虽然涉及单位换算（吨到克），但解题步骤较为直接，无需多个公式组合或复杂推导。" + }, + { + "idx": 3579, + "question": "Using data, calculate the volume in cubic centimeters occupied by one mole of boron.", + "answer": "4.7 cm^{3}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算硼的摩尔体积），答案是一个具体的数值（4.7 cm³），需要使用公式和数据来完成计算。 | 知识层次: 题目要求进行基本的数值计算和公式应用，涉及摩尔体积的计算，属于直接套用基本公式的简单应用层次。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目仅需直接套用摩尔体积公式（体积=质量/密度）进行单一计算步骤。题目提供的数据可直接代入公式得出结果，无需多步转换或组合公式，属于最基础的直接计算类型。" + }, + { + "idx": 3580, + "question": "In order to plate a steel part having a surface area of 200 in.^2 with a 0.002 in. thick layer of nickel, how many atoms of nickel are required?", + "answer": "5.98 x 10^23 atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及表面面积、厚度和原子数量的转换，答案是一个具体的数值结果（5.98 x 10^23 atoms），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算镍的体积、质量，然后转换为摩尔数，最后计算原子数。这涉及到多个概念（如密度、摩尔质量、阿伏伽德罗常数）的关联和综合应用，需要一定的分析和计算能力。 | 难度: 在计算题题型中，这道题目属于综合性计算问题。它需要学生掌握多个步骤的计算过程，包括计算镍的体积、质量、摩尔数，最后转换为原子数。虽然涉及的概念和公式（如密度、摩尔质量、阿伏伽德罗常数）都是基础内容，但需要将这些概念关联起来并进行综合分析。题目没有复杂的变量或特殊条件，因此不属于最高难度的复杂多变量计算问题。" + }, + { + "idx": 3581, + "question": "In order to plate a steel part having a surface area of 200 in.^2 with a 0.002 in. thick layer of nickel, how many moles of nickel are required?", + "answer": "0.994 mol ni required", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算镍的摩尔数），涉及公式应用（面积、厚度与体积的关系，以及密度和摩尔质量的计算），答案是一个具体的数值结果（0.994 mol ni required）。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及面积、厚度和摩尔数的转换，属于直接套用公式的简单应用层次。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于简单公式应用计算。虽然需要应用密度、摩尔质量等基本概念，但解题步骤较为直接，仅需套用公式进行计算，无需多个公式组合或复杂转换。因此，在同题型内属于等级2难度。" + }, + { + "idx": 3582, + "question": "Suppose an element has a valence of 2 and an atomic number of 27 . Based only on the quantum numbers, how many electrons must be present in the 3 d energy level?", + "answer": "7 electrons.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要基于量子数进行计算，以确定3d能级中的电子数。解答过程涉及数值计算和公式应用，答案是一个具体的数值（7 electrons）。 | 知识层次: 题目需要应用量子数相关知识进行多步计算，涉及电子排布规则和能级填充顺序的综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解原子结构、量子数和电子排布规则，并进行多步计算。题目要求基于量子数确定3d能级中的电子数，涉及对元素电子构型的分析和推导，属于中等应用层次的计算题。" + }, + { + "idx": 3583, + "question": "Calculate the fraction of bonding of MgO that is ionic.", + "answer": "the fraction of bonding of mgo that is ionic is 0.734. so bonding is mostly ionic.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算MgO的离子键比例），答案给出了具体的计算结果（0.734），符合计算题的特征。 | 知识层次: 题目要求计算MgO的离子键比例，涉及基本公式应用和简单计算，属于直接套用已知方法进行数值计算的范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅要求计算MgO的离子键比例，直接套用电负性差与离子键比例的对应关系公式即可得出结果，无需多步推导或复杂公式组合。" + }, + { + "idx": 3584, + "question": "Would you expect MgO or magnesium to have the higher modulus of elasticity? Explain.", + "answer": "( MgO has ionic bonds, which are strong compared to the metallic bonds in Mg. A higher force will be required to cause the same separation between the ions in MgO compared to the atoms in Mg. Therefore, MgO should have the higher modulus of elasticity. In Mg, E=6 × 10^{6} psi; in MgO, E=30 × 10^{6} psi.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么MgO的弹性模量比镁高，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求学生比较两种材料的弹性模量，并解释其差异的原因。这需要理解离子键和金属键的性质差异，并将这些概念应用到具体材料中进行分析。虽然不涉及复杂的计算或多步骤推理，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于中等难度，需要理解并比较两种不同化学键（离子键和金属键）的性质，并解释其对弹性模量的影响。虽然涉及概念关联和综合分析，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 3585, + "question": "Calculate the atomic radius in cm for a BCC metal with a0=0.3294 nm and one atom per lattice point.", + "answer": "1.426 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算原子半径），并给出了具体的公式应用（BCC结构的关系式），答案是一个具体的数值结果。 | 知识层次: 题目需要应用BCC晶体结构的几何关系公式（4r = √3a0）进行一步计算，属于基本公式的直接套用和简单计算，不涉及多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用BCC金属的原子半径公式（r = √3 * a0 / 4）并进行单位转换，无需多步推导或组合公式。" + }, + { + "idx": 3586, + "question": "Calculate the atomic radius in cm for an FCC metal with a0=4.0862 A and one atom per lattice point.", + "answer": "1.4447 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算原子半径），需要使用公式（FCC结构的原子半径与晶格常数关系公式），且答案是一个具体的数值结果。 | 知识层次: 题目要求应用FCC晶体结构的几何关系公式进行一步计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用FCC金属原子半径与晶格常数a0的关系公式（r = a0√2/4），进行单一公式的直接计算，无需多步骤或复杂推导。" + }, + { + "idx": 3587, + "question": "Determine the crystal structure for a metal with a0=4.9489 Å, r=1.75 Å and one atom per lattice point.", + "answer": "fcc", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定金属的晶体结构，需要根据给定的晶格常数、原子半径和每个格点的原子数进行判断，答案是一个具体的晶体结构类型（fcc），属于需要简短回答的问题。 | 知识层次: 题目要求根据给定的晶格常数和原子半径确定晶体结构，这需要应用基本的晶体结构计算公式和概念（如配位数、原子堆积方式等），属于直接套用公式和基本概念的应用层面，不需要多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述难度，题目要求直接应用晶体结构的基本公式（原子半径与晶格常数的关系）进行计算，解题步骤明确且单一，仅需套用fcc结构的判定条件即可得出答案，无需深入解释或复杂推理。" + }, + { + "idx": 3588, + "question": "Determine the crystal structure for a metal with a0=0.42906 nm, r=0.1858 nm and one atom per lattice point.", + "answer": "bcc", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过给定的晶格常数(a0)和原子半径(r)进行计算，以确定晶体结构类型。解答过程涉及数值计算和公式应用，最终得出bcc结构的结论。 | 知识层次: 题目需要应用基本的晶体结构计算公式，通过给定的晶格常数和原子半径来确定晶体结构类型。这属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用晶体结构的基本公式（如原子半径与晶格常数的关系）进行简单计算即可得出答案，无需多个公式组合或复杂步骤。" + }, + { + "idx": 3589, + "question": "The density of potassium, which has the BCC structure and one atom per lattice point, is 0.855 g/cm3. The atomic weight of potassium is 39.09 g/mol. Calculate the lattice parameter.", + "answer": "5.3355 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如密度公式、BCC结构参数计算等）来求解晶格参数，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的密度计算公式和BCC结构的几何关系进行一步到两步的数值计算，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用密度公式和BCC结构的几何关系，但步骤较为直接，不涉及多个公式的组合或复杂推导。" + }, + { + "idx": 3590, + "question": "The density of potassium, which has the BCC structure and one atom per lattice point, is 0.855 g/cm3. The atomic weight of potassium is 39.09 g/mol. Calculate the atomic radius of potassium.", + "answer": "2.3103 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如密度、原子量和晶体结构的关系）来求解钾的原子半径，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括利用密度和原子质量计算晶格常数，再根据BCC结构计算原子半径。这需要理解BCC结构的特点和原子半径与晶格常数的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用BCC结构的相关公式（如原子半径与晶格常数的关系）、密度公式，并进行单位换算和多步计算。虽然不涉及复杂变量，但要求对多个物理概念的综合理解和准确计算。" + }, + { + "idx": 3591, + "question": "The density of thorium, which has the FCC structure and one atom per lattice point, is 11.72 g/cm³. The atomic weight of thorium is 232 g/mol. Calculate the lattice parameter.", + "answer": "5.0856 x 10⁻⁸ cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如密度公式和FCC结构参数关系）来求解晶格参数，答案是一个具体的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及密度、原子量和晶格参数之间的直接关系，无需多步计算或复杂分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算FCC结构的晶格参数，涉及密度、原子量和阿伏伽德罗常数的基本公式应用。虽然需要理解FCC结构的特点和单位换算，但整体解题步骤较为直接，属于该题型内中等偏下的难度。" + }, + { + "idx": 3593, + "question": "A metal having a cubic structure has a density of 2.6g / {cm}^{3}, an atomic weight of 87.62g / mol, and a lattice parameter of 6.0849 Å. One atom is associated with each lattice point. Determine the crystal structure of the metal.", + "answer": "fcc.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定金属的晶体结构。具体步骤包括计算单位晶胞中的原子数，然后根据计算结果判断晶体结构类型（如fcc、bcc等）。答案是一个具体的晶体结构类型，但需要通过计算得出，而不是从多个选项中选择或简单的对错判断。 | 知识层次: 题目需要应用密度计算公式，结合立方晶系的晶格参数和原子量，进行多步计算来确定晶体结构。这涉及到对晶体结构、密度计算和单位换算的综合理解，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶体结构知识，并进行多步计算和综合分析。虽然涉及多个概念和步骤，但计算过程相对直接，没有过于复杂的变量或推导。" + }, + { + "idx": 3594, + "question": "A metal having a cubic structure has a density of 1.892g / {cm}^{3}, an atomic weight \\mathrm{of} 132.91g / mol, and a lattice parameter of € 1.13 Å. One atom is associated with each lattice point. Determine the crystal structure of the \\mathrm{metal}.", + "answer": "bcc.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过计算密度、原子量和晶格参数来确定晶体的结构，涉及数值计算和公式应用。答案虽然给出了bcc，但需要通过计算得出这一结论。 | 知识层次: 题目需要应用密度计算公式，涉及多步计算和概念关联（如晶格参数、原子量与晶体结构的关系），需要综合分析已知条件来确定晶体结构类型。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶体结构知识，并进行多步计算和综合分析。虽然涉及多个概念和步骤，但计算过程相对直接，没有过于复杂的变量或推导。" + }, + { + "idx": 3595, + "question": "Indium has a tetragonal structure with a_{0}=0.32517nm and c_{0}=0.49459nm. The density is 7.286g / {cm}^{3} and the atomic weight is 114.82g / mol. Does indium have the simple tetragonal or body-centered tetragonal structure?", + "answer": "body-centered tetragonal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算和分析确定铟的晶体结构类型（简单四方或体心四方），需要文字解释和论述，而不仅仅是选择或判断对错。 | 知识层次: 题目需要应用晶体结构的基本知识，进行多步计算（如晶胞体积、原子数计算等），并将计算结果与理论值对比，综合分析得出晶体结构类型。这涉及多个概念的关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在简答题中属于中等难度，需要理解晶体结构的基本概念，进行多步计算（如晶胞体积、原子数等），并将计算结果与理论值进行对比分析，最终得出结论。虽然涉及一定的综合分析，但解题步骤相对明确，属于该题型框架内的典型难度。" + }, + { + "idx": 3596, + "question": "Bismuth has a hexagonal structure, with a0=0.4546 nm and c0=1.186 nm. The density is 9.808 g/cm3 and the atomic weight is 208.98 g/mol. Determine the volume of the unit cell.", + "answer": "0.21226 nm3 or 2.1226 x 10^-22 cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞的体积，答案是一个具体的数值结果。 | 知识层次: 题目主要考查基本公式应用和简单计算，即通过给定的晶格参数计算单位晶胞体积，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于最简单难度，只需要直接套用单位体积计算公式（体积=底面积×高），无需任何公式组合或复杂转换。题目提供了所有必要参数，计算过程仅涉及基本乘法运算，属于单一公式直接计算类型。" + }, + { + "idx": 3598, + "question": "Gallium has an orthorhombic structure, with a0=0.45258 nm, b0=0.45186 nm, and c0=0.76570 nm. The atomic radius is 0.1218 nm. The density is 5.904 g/cm3 and the atomic weight is 69.72 g/mol. Determine the number of atoms in each unit cell.", + "answer": "8 atoms/cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶体结构参数、原子半径、密度和原子重量进行数值计算，最终确定每个晶胞中的原子数。解答过程需要应用相关公式和计算步骤，答案是一个具体的数值结果（8 atoms/cell）。 | 知识层次: 题目需要多步计算和概念关联，包括晶体结构参数、原子半径、密度和原子量的综合分析，通过公式推导计算单位晶胞中的原子数，涉及中等程度的思维过程和应用能力。 | 难度: 在计算题中属于综合性计算问题，需要应用晶体结构、密度和原子量的知识，进行多步计算和综合分析。虽然涉及多个变量和公式，但步骤相对明确，属于中等应用层次。" + }, + { + "idx": 3599, + "question": "Gallium has an orthorhombic structure, with a0=0.45258 nm, b0=0.45186 nm, and c0=0.76570 nm. The atomic radius is 0.1218 nm. The density is 5.904 g/cm3 and the atomic weight is 69.72 g/mol. Determine the packing factor in the unit cell.", + "answer": "0.387.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶胞的堆积因子，答案是一个具体的数值结果(0.387)，这符合计算题的特征。 | 知识层次: 题目需要多步计算，包括单位晶胞体积计算、原子体积计算以及堆积因子的计算，涉及多个概念的综合应用和关联分析。虽然不涉及复杂的推理或机理解释，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算晶胞的堆积因子，涉及晶格参数、原子半径、密度和原子量等多个变量的综合运用，需要理解晶体结构的基本概念并进行数值计算。虽然计算步骤明确，但需要较高的综合分析能力。" + }, + { + "idx": 3600, + "question": "Beryllium has a hexagonal crystal structure, with a0=0.22858 nm and c0=0.35842 nm. The atomic radius is 0.1143 nm, the density is 1.848 g/cm3, and the atomic weight is 9.01 g/mol. Determine the number of atoms in each unit cell.", + "answer": "2 atoms/cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如晶体结构参数、密度、原子量等）来确定每个晶胞中的原子数，最终需要给出具体的数值结果（2 atoms/cell）。 | 知识层次: 题目需要应用基本的晶体结构参数（如晶格常数、原子半径）和密度公式来计算单位晶胞中的原子数。虽然涉及多个参数，但计算过程直接且公式应用明确，属于基本公式应用和简单计算的范畴。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用单位晶胞中原子的数量与晶体结构参数、原子半径、密度和原子重量之间的关系，直接套用公式即可得出答案。不需要多个公式组合或复杂的计算步骤。" + }, + { + "idx": 3601, + "question": "Beryllium has a hexagonal crystal structure, with a0=0.22858 nm and c0=0.35842 nm. The atomic radius is 0.1143 nm, the density is 1.848 g/cm3, and the atomic weight is 9.01 g/mol. Determine the packing factor in the unit cell.", + "answer": "0.77", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶胞的堆积因子，答案是一个具体的数值（0.77），解答过程需要运用材料科学中的晶体结构知识和相关计算公式。 | 知识层次: 题目需要多步计算（包括晶胞体积、原子体积、堆积因子计算等），涉及晶体结构参数和密度等概念的关联应用，并需要综合分析计算结果。虽然不涉及复杂的机理分析或创新设计，但思维过程比简单套用公式更深入。 | 难度: 在计算题中属于综合性计算问题，需要应用晶体结构、原子半径、密度和原子重量等多个概念，并进行多步计算。虽然计算步骤明确，但需要综合分析和正确应用公式，属于中等偏上的难度。" + }, + { + "idx": 3602, + "question": "A typical paper clip weighs 0.59g and consists of BCC iron. Calculate the number of unit cells in the paper clip.", + "answer": "3.185 × 10^21 cells", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算纸夹中铁的BCC晶胞数量），需要应用材料科学中的晶体结构知识和相关公式，最终答案为具体数值结果。 | 知识层次: 题目需要进行基本的单位换算和公式应用（BCC铁的单位细胞质量计算），属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在计算题-简单应用类别中，该题目属于简单公式应用计算。虽然需要知道BCC铁的单位细胞质量和相关公式，但解题步骤相对直接，主要是单位换算和单一公式的套用。相比等级1的直接计算题稍复杂，但不需要多个公式组合，因此属于等级2难度。" + }, + { + "idx": 3603, + "question": "A typical paper clip weighs 0.59g and consists of BCC iron. Calculate the number of iron atoms in the paper clip.", + "answer": "6.37 × 10^21 atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（根据质量计算原子数量）和公式应用（使用阿伏伽德罗常数和BCC结构相关知识）来求解，最终答案是一个具体的数值结果。 | 知识层次: 题目需要进行基本的单位换算和公式应用（摩尔质量计算），但仅涉及单一步骤的计算过程，不需要多步推理或综合分析。主要考查学生对摩尔概念和原子量计算的直接应用能力。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算铁原子数量，需要应用摩尔质量和阿伏伽德罗常数的基本公式，并进行简单的单位转换和乘法运算。虽然涉及多个步骤（质量转摩尔、摩尔转原子数），但每一步都是直接套用基础公式，没有复杂的组合或推导过程。" + }, + { + "idx": 3604, + "question": "Determine the planar density for BCC lithium in the (100) plane.", + "answer": "planar density = 0.0812 x 10^16 points/cm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算BCC锂在(100)晶面上的平面密度，需要应用相关公式进行数值计算，最终答案是一个具体的数值结果。 | 知识层次: 题目要求计算BCC锂在(100)面的平面密度，主要涉及基本公式应用和简单计算，属于直接套用平面密度公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用BCC晶体的平面密度公式进行计算，无需组合多个公式或进行复杂推导，解题步骤简单直接。" + }, + { + "idx": 3605, + "question": "Determine the packing fraction for BCC lithium in the (100) plane.", + "answer": "packing fraction = 0.589", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算BCC锂在(100)面的堆积分数，需要应用晶体结构的相关公式进行数值计算，最终给出具体的数值结果0.589。这符合计算题的特征。 | 知识层次: 题目要求计算BCC锂在(100)面的堆积分数，主要涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算BCC锂在(100)面的堆积分数，这需要应用基本的堆积分数公式，并理解BCC结构在特定晶面上的原子排列。虽然需要理解晶体结构的基本概念，但计算过程直接，仅需单一公式的应用和简单数值计算，不需要多个公式的组合或复杂推导。" + }, + { + "idx": 3606, + "question": "Determine the planar density for BCC lithium in the (110) plane.", + "answer": "planar density = 0.1149 x 10^16 points/cm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(110)平面上的平面密度，需要应用相关公式进行数值计算，最终给出具体的数值结果。答案也是一个具体的数值，符合计算题的特征。 | 知识层次: 题目需要理解BCC晶体的结构特点，掌握(110)平面的原子排列方式，并应用平面密度的计算公式进行多步计算。这涉及到概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题-需要数值计算和公式应用题型中，该题目属于综合性计算问题。需要掌握BCC晶体结构、(110)平面的原子排列、平面密度的计算公式等多个概念，并进行多步计算和综合分析。虽然计算过程相对明确，但涉及多个知识点的关联应用，因此在该题型内属于中等偏上难度。" + }, + { + "idx": 3607, + "question": "Determine the packing fraction for BCC lithium in the (110) plane.", + "answer": "packing fraction = 0.833", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(110)平面的堆积分数，需要应用晶体结构和几何知识进行数值计算，答案是一个具体的数值结果（0.833），符合计算题的特征。 | 知识层次: 题目需要理解BCC晶体的结构特点，计算(110)平面的原子排列和面积，并应用packing fraction的公式进行计算。这涉及多步计算和概念关联，但不需要复杂的推理或深度分析。 | 难度: 在计算题中属于综合性计算问题，需要理解BCC晶体结构、(110)平面的原子排列，并应用几何关系计算堆积分数。涉及多步计算和概念关联，但不需要处理复杂多变量。" + }, + { + "idx": 3608, + "question": "Determine the planar density for BCC lithium in the (111) plane.", + "answer": "planar density = 0.0469 x 10^16 points/cm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(111)晶面上的平面密度，需要应用相关公式进行数值计算，最终给出具体的数值结果。 | 知识层次: 题目需要理解BCC晶体结构、(111)晶面的原子排列，并应用平面密度的计算公式进行多步计算，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解BCC晶体结构、(111)晶面的原子排列，并应用平面密度公式进行多步计算。虽然不涉及复杂多变量，但需要将多个概念关联并正确执行计算步骤。" + }, + { + "idx": 3609, + "question": "Determine the packing fraction for BCC lithium in the (111) plane.", + "answer": "packing fraction = 1/2 / 0.866 a0^2 sqrt(3) a0 / 4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(111)面的堆积分数，答案涉及数值计算和公式应用，属于典型的计算题。 | 知识层次: 题目要求计算BCC锂在(111)面的堆积分数，需要理解BCC晶体结构、晶面指数、堆积分数的概念，并应用相关公式进行多步计算。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点进行计算，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要理解BCC晶体结构、(111)平面的几何特征，并应用多步数学计算（包括面积计算和原子排列分析）。虽然不涉及复杂多变量，但需要将晶体学知识与数学推导相结合，属于中等应用层次的多步骤计算过程。" + }, + { + "idx": 3610, + "question": "Which, if any, of these planes is close packed in BCC lithium?", + "answer": "there is no close-packed plane in bcc structures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目实际上是在判断\"BCC锂中是否存在密排面\"这一陈述的正确性，答案为明确的判断性陈述（不存在），符合判断题的特征。虽然题目以疑问句形式出现，但本质是要求判断某个晶体学概念的正确性。 | 知识层次: 题目考查对BCC晶体结构中密排面存在与否的基础概念记忆和理解，属于晶体学基本知识的直接应用。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度。虽然题目涉及BCC结构的基础概念，但需要学生理解\"close-packed plane\"的定义及其在BCC结构中的特殊性，这比简单的正误判断(等级1)要求更高的概念理解深度，但又不涉及复杂概念陈述(等级3)。" + }, + { + "idx": 3611, + "question": "Suppose that FCC rhodium is produced as a 1-mm thick sheet, with the (111) plane parallel to the surface of the sheet. How many (111) interplanar spacings d_{111} thick is the sheet? See Appendix A for necessary data.", + "answer": "the sheet is 4.563 × 10^{6} d_{111} spacings thick.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定1-mm厚的FCC铑片中(111)晶面间距d_{111}的数量。答案是一个具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括查找附录数据、应用晶体学公式计算(111)面间距，并进行单位转换和最终厚度计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要结合材料科学中的晶体结构知识（FCC结构、(111)晶面间距计算）和单位换算进行多步计算。题目要求将实际厚度转换为晶面间距的数量，涉及查表数据应用和公式推导，但计算过程相对直接，没有复杂变量或高级数学工具需求。" + }, + { + "idx": 3612, + "question": "In a FCC unit cell, how many d_{111} are present between the 0,0,0 point and the 1,1,1 point?", + "answer": "3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算FCC晶胞中特定晶面间距的数量，需要应用晶体学知识和数值计算，答案是一个具体的数值（3），符合计算题的特征。 | 知识层次: 题目需要理解FCC晶胞的结构特点，应用晶面间距的概念，并进行多步计算来确定d_{111}的数量。这涉及到对晶体学基础知识的理解和应用，以及一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解FCC晶格结构、晶面间距计算原理，并能正确应用d_{hkl}公式进行多步推导。题目要求从(0,0,0)点到(1,1,1)点之间的d_{111}数量计算，涉及晶面间距的几何关系分析和三维空间想象能力，比简单的单步计算题更复杂，但尚未达到需要处理多变量或非常规条件的等级4难度。" + }, + { + "idx": 3613, + "question": "Determine the minimum radius of an atom that will just fit into the tetrahedral interstitial site in FCC nickel.", + "answer": "0.2797 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定原子半径的最小值，需要使用公式和已知参数进行计算，最终给出具体的数值结果（0.2797 Å）。 | 知识层次: 题目需要应用晶体结构（FCC）和间隙位置（四面体间隙）的知识，进行多步计算（包括原子半径和间隙半径的关系），并需要理解几何关系来求解最小半径。这超出了简单应用的范围，但不需要复杂的分析或综合。 | 难度: 在计算题中属于综合性计算问题，需要理解FCC晶体结构中四面体间隙的几何关系，应用原子半径与间隙半径的公式，并进行多步计算。虽然不涉及复杂多变量，但需要将晶体学概念与数学计算相结合，属于中等应用层次中的较难题目。" + }, + { + "idx": 3614, + "question": "Determine the minimum radius of an atom that will just fit into the octahedral interstitial site in BCC lithium.", + "answer": "0.629 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定原子半径，需要应用材料科学中的晶体结构相关公式进行计算，最终给出具体的数值结果(0.629 Å)。 | 知识层次: 题目需要进行多步计算，涉及BCC晶体结构中八面体间隙位置的计算，需要理解间隙位置几何关系并应用相关公式，属于中等应用层次。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于综合性计算问题。题目要求确定BCC锂中八面体间隙的最小原子半径，涉及多步计算和概念关联，包括晶体结构分析、间隙位置几何关系计算以及原子半径的推导。虽然计算过程相对明确，但需要综合运用多个知识点和公式，因此在该题型内属于中等偏上难度。" + }, + { + "idx": 3615, + "question": "What is the radius of an atom that will just fit into the octahedral site in FCC copper without disturbing the crystal structure?", + "answer": "0.529 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算一个原子半径的具体数值，需要应用晶体结构和几何关系的公式进行计算，答案是一个具体的数值（0.529 Å），符合计算题的特征。 | 知识层次: 题目需要应用FCC晶体结构中八面体间隙的计算公式，并理解原子半径与间隙半径的关系。虽然计算过程相对直接，但需要理解晶体结构的基本原理和间隙位置的概念，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解FCC晶体结构、八面体间隙的概念，并应用原子半径与晶格常数的关系进行多步计算。虽然计算步骤明确，但需要将多个概念关联起来综合分析，属于中等应用层次中的典型问题。" + }, + { + "idx": 3616, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{Y}_{2} \\mathrm{O}_{3}.", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用相关公式和数值计算，答案是一个具体的数值（6），符合计算题的特征。 | 知识层次: 题目要求使用离子半径数据来确定配位数，这涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要根据离子半径比直接套用公式确定配位数，但不需要多个公式组合或复杂计算步骤。" + }, + { + "idx": 3617, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{UO}_{2}.", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用离子半径数据和配位数计算规则进行数值计算，最终得出具体数值答案6。 | 知识层次: 题目要求使用离子半径数据来确定配位数，这涉及基本的公式应用和简单计算，属于直接套用已知规则和数据的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接应用离子半径数据确定配位数，无需复杂计算或公式组合。" + }, + { + "idx": 3618, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{BaO}.", + "answer": "8", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用离子半径数据来确定配位数，需要基于给定的数据进行计算和判断，最终给出一个具体的数值答案。这符合计算题的特征。 | 知识层次: 题目要求使用离子半径数据来确定配位数，这涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要根据离子半径直接确定配位数，无需多个公式组合或复杂计算步骤，属于最基础的计算题类型。" + }, + { + "idx": 3619, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{Si}_{4} N_{4}.", + "answer": "4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据离子半径确定配位数，这需要通过数值计算和公式应用来得出具体数值（4），属于需要计算和分析的题目类型。 | 知识层次: 题目需要应用离子半径数据来确定配位数，属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用离子半径确定配位数，这需要应用基本的配位数判断规则（如半径比规则），但不需要复杂的公式组合或多步计算。属于直接套用简单公式即可解决的题型。" + }, + { + "idx": 3620, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{GeO}_{2}.", + "answer": "4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要一定的解释和论述，而不仅仅是简单的计算或选择。答案虽然是一个数字，但需要基于理论知识和分析得出。 | 知识层次: 题目要求根据离子半径确定配位数，这需要应用基本的离子半径与配位数关系的知识，属于直接套用已有规则进行简单判断的范畴。虽然需要一定的理解，但不需要多步计算或综合分析。 | 难度: 在简答题中属于较低难度，仅需要根据给定的离子半径数据直接套用配位数判断规则，无需复杂的解释或推导过程。解题步骤简单明确，属于基本公式的直接应用范畴。" + }, + { + "idx": 3621, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{MnO}.", + "answer": "6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要解释和论述判断过程，答案是一个具体的数值而非选择或判断对错 | 知识层次: 题目要求根据离子半径确定配位数，需要理解离子半径与配位数的关系，并进行一定的分析和计算。这涉及到多步思维过程，包括查找离子半径数据、计算半径比、并根据半径比确定配位数。虽然不涉及复杂的综合分析或创新应用，但比简单的记忆或直接套用公式要复杂一些。 | 难度: 在简答题中属于中等难度，需要理解离子半径与配位数的关系，并进行简单的计算和综合分析。虽然涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3622, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{MgS}.", + "answer": "6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用材料科学知识进行解释和论述，答案虽然是一个数字，但解答过程需要理论分析和判断。 | 知识层次: 题目要求根据离子半径确定配位数，这需要理解离子半径与配位数之间的关系，并应用相关规则（如半径比规则）进行计算和判断。虽然涉及基础概念，但需要一定的分析和综合能力来得出正确的配位数。 | 难度: 在简答题中属于中等难度，需要理解离子半径与配位数的关系，并进行简单的计算和综合分析。虽然涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3623, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{KBr}.", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要使用数值计算和公式应用来得出具体数值答案6 | 知识层次: 题目需要应用离子半径数据来确定配位数，属于基本公式应用和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级，只需要根据给定的离子半径数据直接套用协调数计算公式即可得出结果，无需复杂的步骤或多公式组合。" + }, + { + "idx": 3624, + "question": "Would you expect NiO to have the cesium chloride, sodium chloride, or zinc blende structure?", + "answer": "sodium chloride structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三种晶体结构（cesium chloride, sodium chloride, zinc blende）中选择NiO最可能的结构类型，答案明确给出了一个选项（sodium chloride structure），符合选择题的特征。 | 知识层次: 题目考查对NiO晶体结构的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解NiO的晶体结构特点，并能够与常见的三种晶体结构（CsCl、NaCl、ZnS）进行简单辨析。虽然不需要复杂的计算或推导，但需要对几种典型晶体结构有一定的记忆和理解基础。" + }, + { + "idx": 3625, + "question": "For NiO with sodium chloride structure, determine the lattice parameter.", + "answer": "4.02 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定NiO的晶格参数，答案是一个具体的数值（4.02 Å），这表明需要应用相关公式和数值计算来解决问题。 | 知识层次: 题目要求根据已知的NiO晶体结构（氯化钠结构）确定晶格参数，这属于基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于等级1难度。题目仅要求直接应用已知的NaCl结构晶格参数公式进行计算，无需组合多个公式或进行复杂推导。解题步骤简单，只需套用基本公式并代入已知数值即可得出结果，符合单一公式直接计算的特征。" + }, + { + "idx": 3626, + "question": "For NiO with sodium chloride structure, determine the density.", + "answer": "7.64 \\mathrm{g/cm}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定NiO的密度，需要使用相关公式和数值计算，最终给出具体的数值结果7.64 g/cm³。 | 知识层次: 题目需要应用晶体结构知识（NaCl结构）和密度计算公式，涉及原子量、晶格常数等参数的查找和计算，属于多步计算和概念关联的综合应用。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要掌握晶体结构、晶格常数计算、摩尔质量转换以及密度公式应用等多个知识点，并进行多步骤的关联计算。虽然不涉及复杂变量或高级数学工具，但要求对材料科学基础概念的综合运用能力，符合等级3\"综合性计算问题\"的标准。" + }, + { + "idx": 3627, + "question": "For NiO with sodium chloride structure, determine the packing factor.", + "answer": "0.678.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算NiO的堆积因子，需要应用相关公式进行数值计算，最终给出一个具体的数值结果（0.678）。 | 知识层次: 题目要求计算NiO的堆积因子，这需要应用基本的晶体结构知识（如NaCl结构）和堆积因子的计算公式。虽然涉及一定的理解，但主要是直接套用公式进行计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用NaCl结构的堆积因子公式（4*(V_atom)/V_unit cell）并进行简单的数值计算即可得出结果，无需多个公式组合或复杂推导。" + }, + { + "idx": 3628, + "question": "Would you expect \\mathrm{UO}_{2} to have the sodium chloride, zinc blende, or fluoride structure?", + "answer": "fluorite structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个选项（sodium chloride, zinc blende, or fluoride structure）中选择一个正确答案。 | 知识层次: 题目考查对常见晶体结构类型（如氯化钠、闪锌矿、萤石结构）的记忆和理解，以及特定化合物（UO2）对应晶体结构的直接识别能力，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解UO2的晶体结构特点，并能与几种典型结构（NaCl、闪锌矿、萤石）进行简单辨析。虽然涉及记忆性知识，但需要对不同结构类型有一定理解才能正确选择。" + }, + { + "idx": 3629, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the lattice parameter.", + "answer": "5.2885 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定UO2的晶格参数，答案是一个具体的数值（5.2885 Å），这表明需要通过数值计算和公式应用来解决问题。 | 知识层次: 题目要求计算UO2的晶格参数，属于直接应用已知的数值和公式进行计算，不需要多步推理或综合分析，思维过程较为直接。 | 难度: 在计算题中属于最低难度，仅需直接套用已知的晶格参数公式进行计算，无需额外的公式组合或复杂步骤。题目明确给出了材料类型和结构，直接引用已知数据即可完成计算。" + }, + { + "idx": 3630, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the density.", + "answer": "12.13 {g/cm}^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定UO2的密度，需要应用材料科学中的密度计算公式，答案是一个具体的数值结果。 | 知识层次: 题目需要计算UO2的密度，涉及晶体结构（萤石结构）的理解、晶胞参数的计算、原子质量和数量的确定，以及密度的多步计算。这需要将多个概念关联起来并进行综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶体结构（萤石结构）的知识、摩尔质量计算、晶胞参数与密度的关系等多步骤计算过程，并需要综合分析多个概念才能得出最终结果。" + }, + { + "idx": 3631, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the packing factor.", + "answer": "The packing factor is pf = 0.624.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定UO2的堆积因子，答案是一个具体的数值结果（0.624），这需要应用相关的公式和数值计算过程。 | 知识层次: 题目要求计算UO2的堆积因子，属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，只需要直接套用单一公式（如晶体结构的堆积因子公式）进行简单计算即可得出结果，无需多个公式组合或复杂推导。" + }, + { + "idx": 3632, + "question": "Would you expect BeO to have the sodium chloride, zinc blende, or fluorite structure?", + "answer": "BeO has the zinc blende structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三种晶体结构（sodium chloride, zinc blende, fluorite）中选择BeO最可能具有的结构类型，属于从多个选项中选择正确答案的题型。 | 知识层次: 题目考查对BeO晶体结构的基础概念记忆，属于对材料晶体结构分类的基本知识掌握。 | 难度: 在选择题中属于中等难度，需要理解BeO的晶体结构特点，并能与钠氯化物、闪锌矿和萤石结构进行简单辨析。虽然不涉及复杂计算或深度推理，但需要对几种晶体结构有基本的概念理解和记忆。" + }, + { + "idx": 3633, + "question": "Based on the zinc blende structure of BeO, determine the lattice parameter.", + "answer": "The lattice parameter is 3.8567 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于锌矿结构的BeO确定晶格参数，需要通过数值计算和公式应用来得出具体数值（3.8567 Å），答案是一个具体的计算结果。 | 知识层次: 题目要求基于闪锌矿结构的BeO计算晶格参数，属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需根据已知的锌矿结构BeO的晶格参数直接给出数值，无需进行复杂的公式应用或多步骤计算，属于最基础的计算题类型。" + }, + { + "idx": 3634, + "question": "Based on the zinc blende structure of BeO, determine the density.", + "answer": "The density is 2.897 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于闪锌矿结构的BeO计算密度，需要应用公式和数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要理解闪锌矿结构（zinc blende structure）的特征，应用晶体密度计算公式，并进行多步计算。这涉及晶体学基本概念与密度计算的结合，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解锌矿结构的基本概念，掌握晶格常数与密度的关系公式，进行多步计算（包括单位换算和数值代入），并正确应用原子量和阿伏伽德罗常数等参数。虽然计算过程明确，但涉及多个物理概念的关联和综合分析，属于中等偏上的难度等级。" + }, + { + "idx": 3635, + "question": "Based on the zinc blende structure of BeO, determine the packing factor.", + "answer": "The packing factor is 0.684.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于闪锌矿结构的BeO计算其堆积因子，需要应用相关公式和数值计算，最终给出具体的数值结果0.684。 | 知识层次: 题目需要理解锌矿结构（zinc blende structure）的晶体学特征，并应用几何关系计算堆积因子（packing factor）。这涉及多步计算和概念关联，包括原子半径、晶胞参数和几何关系的综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解锌矿结构的特点，掌握晶胞参数与原子半径的关系，并应用堆积因子的计算公式。虽然计算步骤较多，但不需要处理复杂多变量，属于中等偏上的难度。" + }, + { + "idx": 3636, + "question": "Would you expect CsBr to have the sodium chloride, zinc blende, fluorite, or cesium chloride structure?", + "answer": "CsBr is expected to have the cesium chloride structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的几种晶体结构（sodium chloride, zinc blende, fluorite, cesium chloride）中选择CsBr最可能的结构类型 | 知识层次: 题目考查对晶体结构类型的基本记忆和理解，只需要根据CsBr的组成元素判断其可能采取的晶体结构类型，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解离子晶体的结构类型及其影响因素，并进行简单辨析。虽然涉及多个结构类型，但主要考察的是对离子半径比和配位数的基本理解，不需要复杂的分析步骤。" + }, + { + "idx": 3637, + "question": "Based on the cesium chloride structure, determine the lattice parameter for CsBr.", + "answer": "The lattice parameter a0 = 4.1916 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于氯化铯结构确定CsBr的晶格参数，需要进行数值计算和公式应用。答案给出了具体的数值结果（4.1916 Å），这表明解答过程涉及计算步骤。 | 知识层次: 题目要求基于已知的氯化铯结构确定CsBr的晶格参数，这属于基本公式应用和简单计算，不需要多步计算或综合分析，只需直接套用相关公式即可得出结果。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（晶格参数与离子半径关系公式）进行简单计算，无需多步骤推导或复杂公式组合。解题过程仅涉及基本离子半径数据的查找和代数运算，符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 3638, + "question": "Based on the cesium chloride structure, determine the density for CsBr.", + "answer": "The density ρ = 4.8 g/cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于氯化铯结构计算CsBr的密度，需要应用公式和进行数值计算，最终给出具体的密度数值作为答案。 | 知识层次: 题目需要基于CsCl结构进行密度计算，涉及多步计算（如晶格常数确定、单位晶胞质量计算等）和概念关联（晶体结构、密度公式等），属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解CsCl结构模型，应用晶格常数与密度的关系公式，并进行多步单位换算和数值计算。虽然计算步骤明确，但涉及晶体结构概念与计算过程的综合运用，属于中等偏上难度。" + }, + { + "idx": 3639, + "question": "Based on the cesium chloride structure, determine the packing factor for CsBr.", + "answer": "The packing factor pf = 0.693.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于氯化铯结构计算CsBr的堆积因子，需要应用公式和进行数值计算，最终给出一个具体的数值结果（0.693）。 | 知识层次: 题目需要基于CsCl结构进行多步计算（包括离子半径比计算、晶格常数确定、体积计算等），涉及晶体结构概念与数学计算的综合应用，但不需要复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解CsCl结构特点，正确应用几何关系推导离子半径比，并通过多步计算得出堆积因子。虽然不涉及复杂变量，但需要将晶体结构知识与数学计算相结合，属于中等偏上的综合计算难度。" + }, + { + "idx": 3640, + "question": "Calculate the planar packing fraction (ppf) on the (110) plane for ZnS (with the zinc blende structure).", + "answer": "0.492", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算ZnS在(110)晶面上的平面堆积分数(ppf)，需要应用相关公式进行数值计算，最终答案是一个具体的数值(0.492)，符合计算题的特征。 | 知识层次: 题目需要计算(110)面的平面堆积分数(ppf)，涉及锌矿结构的晶体学知识、原子位置确定、面积计算等多步操作。虽然计算过程有明确公式，但需要理解晶体结构特征并正确应用几何关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解ZnS的晶体结构（锌闪锌矿结构），正确识别(110)平面的原子排列，应用几何关系计算原子面积和平面面积，并进行多步计算。虽然不涉及复杂变量，但需要综合运用晶体学和几何知识，属于中等应用层次的计算题。" + }, + { + "idx": 3641, + "question": "Calculate the planar packing fraction (ppf) on the (110) plane for CaF2 (with the fluorite structure).", + "answer": "0.699", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算平面堆积分数），需要使用公式和具体数值计算，最终给出一个数值结果（0.699），这符合计算题的特征。 | 知识层次: 题目要求计算CaF2在(110)晶面上的平面堆积分数(ppf)，这需要理解氟化钙的晶体结构（萤石结构），并能够正确识别和计算特定晶面上的原子排列和堆积密度。这涉及到多步计算和概念关联，包括晶面指数的理解、原子位置的确定以及堆积分数的计算公式应用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解CaF2的晶体结构、确定(110)平面的原子排列、计算原子半径和平面面积，并进行多步计算。虽然不涉及复杂多变量，但步骤较多且需要概念关联，属于中等偏上难度。" + }, + { + "idx": 3642, + "question": "MgO, which has the sodium chloride structure, has a lattice parameter of 0.396 nm. Determine the planar density and the planar packing fraction for the (111) plane of MgO. What ions are present on this plane?", + "answer": "(111) plane:\n- planar density (p.d.): 0.1473 x 10^16 points/cm^2\n- planar packing fraction (ppf): 0.202\n- ions present: mg^2+ and o^2-", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（如平面密度和平面堆积分数）并应用相关公式，答案也以数值形式给出，符合计算题的特征。 | 知识层次: 题目涉及多步计算（晶格参数转换、平面密度计算、平面堆积分数计算）和概念关联（需要理解NaCl晶体结构、(111)面的离子排列方式），需要综合分析能力。虽然不涉及创新或深度机理分析，但已超出简单套用公式的范畴。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶体结构、平面密度和平面堆积分数的计算方法，并进行多步计算和综合分析。题目要求确定(111)平面的离子组成，增加了概念关联的复杂度。" + }, + { + "idx": 3644, + "question": "A diffracted x-ray beam is observed from the (220) planes of iron at a 2 \\theta angle of 99.1^{\\circ} when x-rays of 0.15418nm wavelength are used. Calculate the lattice parameter of the iron.", + "answer": "0.2865nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（布拉格定律）来求解铁的晶格参数，答案是一个具体的数值（0.2865nm），符合计算题的特征。 | 知识层次: 题目需要应用布拉格定律进行多步计算，涉及晶体学平面间距与晶格参数的关系，需要理解衍射角、波长和晶格参数之间的关联，并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用布拉格定律（nλ=2d sinθ）和晶面间距公式（d=a/√(h²+k²+l²)）进行多步计算，并正确关联衍射角、波长和晶格参数等概念。虽然计算步骤明确，但需要综合分析能力和对晶体结构的理解，属于中等应用层次。" + }, + { + "idx": 3645, + "question": "Calculate the number of vacancies per {cm}^{3} expected in copper at 1080^{\\circ} C (just below the melting temperature). The activation energy for vacancy formation is 20,000 cal/mol.", + "answer": "4.97 × 10^{19} vacancies/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铜在特定温度下的空位数量），并应用相关公式（激活能和温度的关系）。答案是一个具体的数值结果（4.97 × 10^{19} vacancies/cm^3），符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及激活能和温度对空位浓度的影响，需要将概念关联并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及单位转换和指数运算，但变量和计算步骤相对明确，属于中等偏上难度。" + }, + { + "idx": 3646, + "question": "The fraction of lattice points occupied by vacancies in solid aluminum at 660^{\\circ} C is 10^{-3}. What is the activation energy required to create vacancies in aluminum?", + "answer": "12800 cal/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解激活能，答案是一个具体的数值结果(12800 cal/mol)，这符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式计算空位形成能，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，并理解空位形成能与温度的关系。虽然计算步骤明确，但需要将多个概念（空位浓度、活化能、温度）关联起来综合分析，属于中等偏上的难度。" + }, + { + "idx": 3647, + "question": "The density of a sample of HCP beryllium is 1.844 g/cm³ and the lattice parameters are a₀=0.22858 nm and c₀=0.35842 nm. Calculate the fraction of the lattice points that contain vacancies.", + "answer": "0.0008", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶格空位分数，答案是一个具体的数值结果（0.0008），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解HCP晶体结构、密度计算、空位分数计算等概念，并进行综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的计算步骤和概念关联。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于综合性计算问题。题目要求考生掌握HCP晶体结构参数与密度之间的关系，能够正确应用晶格常数和密度公式进行多步计算，并最终推导出空位分数。虽然计算步骤明确，但需要综合运用晶体学知识和数学推导能力，属于该题型内中等偏上的难度水平。" + }, + { + "idx": 3649, + "question": "BCC lithium has a lattice parameter of 3.5089 × 10^-8 cm and contains one vacancy per 200 unit cells. Calculate the number of vacancies per cubic centimeter.", + "answer": "1.157 × 10^20 vacancies/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定每立方厘米的空位数。答案是一个具体的数值结果，需要通过计算得出。 | 知识层次: 题目需要进行多步计算，包括计算单位晶胞体积、确定单位晶胞数量以及最终计算空位浓度，涉及概念关联和综合分析。虽然计算过程相对直接，但需要理解和应用BCC结构的基本知识以及空位浓度的计算方法。 | 难度: 在计算题中属于综合性计算问题，需要理解BCC晶体结构、晶格参数与体积的关系，以及缺陷浓度的计算。解题步骤包括单位转换、单位晶胞体积计算、缺陷密度推导等多步操作，但未涉及复杂变量或高级数学工具。" + }, + { + "idx": 3650, + "question": "BCC lithium has a lattice parameter of 3.5089 × 10^-8 cm and contains one vacancy per 200 unit cells. Calculate the density of Li.", + "answer": "0.532 g/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如晶格参数和空位密度计算）来求解锂的密度，答案是一个具体的数值结果（0.532 g/cm³），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算单位晶胞的质量、考虑空位对密度的影响，以及应用密度公式进行综合计算。这需要理解BCC结构的特点、空位的概念以及密度的计算方法，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握BCC结构、密度计算公式、空位浓度概念，并进行多步计算（包括单位换算、原子质量应用、空位影响修正等）。虽然计算步骤明确，但涉及多个概念的关联和综合分析，属于中等偏上难度。" + }, + { + "idx": 3651, + "question": "FCC lead has a lattice parameter of 0.4949 nm and contains one vacancy per 500 Pb atoms. Calculate the density.", + "answer": "the density is 11.335 g/cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如晶格参数和空位浓度计算密度）来得出具体的数值结果（11.335 g/cm3），属于典型的计算题。 | 知识层次: 题目需要进行多步计算，包括晶格参数与密度的关系、空位浓度的计算以及密度的最终求解，涉及概念关联和综合分析。虽然计算过程较为直接，但需要理解FCC结构、空位对密度的影响以及相关公式的应用，属于中等应用层次。 | 难度: 在计算题中属于多步骤计算过程难度。题目需要应用FCC晶格参数计算理论密度，然后结合空位浓度修正实际密度。虽然涉及晶格参数、原子质量、阿伏伽德罗常数等多个概念，但计算步骤明确且无复杂变量交互，属于典型的中等多步计算问题。" + }, + { + "idx": 3652, + "question": "FCC lead has a lattice parameter of 0.4949 nm and contains one vacancy per 500 Pb atoms. Calculate the number of vacancies per gram of Pb.", + "answer": "the number of vacancies per gram of pb is 5.82 × 10^18 vacancies/g.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及晶格参数和空位浓度的计算，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的晶格参数和空位浓度进行数值计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用FCC晶格参数和空位浓度的基本公式，但仅涉及单一公式的直接套用和简单数值计算，无需多个公式的组合或复杂推导。解题步骤包括计算单位晶胞体积、铅原子质量以及空位数量，这些步骤在同类题型中属于基础操作。" + }, + { + "idx": 3653, + "question": "A niobium alloy is produced by introducing tungsten substitutional atoms in the BCC structure; eventually an alloy is produced that has a lattice parameter of 0.32554nm and a density of 11.95g / {cm}^{3}. Calculate the fraction of the atoms in the alloy that are tungsten.", + "answer": "0.345", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钨原子在合金中的比例，答案是一个具体的数值（0.345），这表明需要运用材料科学中的相关公式和计算步骤来解决问题。 | 知识层次: 题目需要进行多步计算，包括晶格参数与密度的关系、原子质量的计算以及原子分数的求解。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个概念和公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用密度计算公式、晶格参数与原子半径的关系，并进行多步代数运算和单位转换。虽然不涉及复杂多变量，但需要将多个材料科学概念关联起来综合分析，属于中等偏上的难度水平。" + }, + { + "idx": 3654, + "question": "Tin atoms are introduced into a FCC copper crystal, producing an alloy with a lattice parameter of 3.7589 × 10^{-8} cm and a density of 8.772g / {cm}^{3}. Calculate the atomic percentage of tin present in the alloy.", + "answer": "11.95%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如密度、晶格参数和原子百分比的计算）来求解锡的原子百分比，答案是一个具体的数值（11.95%），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括利用晶格参数计算晶胞体积、应用密度公式计算平均原子质量、结合铜和锡的原子质量计算锡的原子百分比。这需要综合运用多个概念和公式，并进行适当的代数运算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目涉及FCC晶体结构、密度计算、原子百分比等知识点，要求综合分析能力。虽然计算步骤明确，但需要正确理解和应用多个物理化学概念，属于中等偏上的难度。" + }, + { + "idx": 3655, + "question": "We replace 7.5 atomic percent of the chromium atoms in its BCC crystal with tantalum. X-ray diffraction shows that the lattice parameter is 0.29158nm. Calculate the density of the alloy.", + "answer": "8.265g / {cm}^{3}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解合金的密度，答案是一个具体的数值结果（8.265g/cm³），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子百分比替换的计算、晶格参数的应用以及密度的综合计算，涉及多个概念的关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解合金成分替换的概念、BCC晶体结构参数的应用、密度计算公式的运用，并进行多步计算。虽然涉及多个知识点和步骤，但整体计算过程相对直接，没有过于复杂的变量或推导过程。" + }, + { + "idx": 3656, + "question": "Suppose we introduce one carbon atom for every 100 iron atoms in an interstitial position in BCC iron, giving a lattice parameter of 0.2867 nm. For the Fe-C alloy, find the density.", + "answer": "7.89 g/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Fe-C合金的密度，答案是一个具体的数值（7.89 g/cm³），这表明解答过程涉及计算步骤而非选择或判断。 | 知识层次: 题目需要进行多步计算，包括计算单位晶胞中的原子数、考虑碳原子的添加对密度的影响，以及应用密度公式进行计算。这需要理解BCC结构的基本原理，并能将多个概念（如晶格参数、原子质量、原子数等）关联起来进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要掌握BCC结构、晶格参数与密度的关系、原子质量计算等多个概念，并进行多步计算和单位转换。虽然计算步骤明确，但涉及多个知识点的综合应用，属于中等偏上的难度。" + }, + { + "idx": 3657, + "question": "Suppose we introduce one carbon atom for every 100 iron atoms in an interstitial position in BCC iron, giving a lattice parameter of 0.2867 nm. For the Fe-C alloy, find the packing factor.", + "answer": "0.681", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Fe-C合金的堆积因子，答案是一个具体的数值（0.681），这表明需要进行计算和推导。 | 知识层次: 题目需要进行多步计算，包括确定晶胞中的原子数、计算原子体积和晶胞体积，并应用堆积因子的公式。虽然不涉及复杂的推理或综合分析，但需要理解BCC结构、间隙位置和堆积因子的概念，并进行适当的数值计算。 | 难度: 在计算题中属于综合性计算问题，需要理解BCC结构、间隙位置、晶格参数和堆积因子的概念，并进行多步计算。虽然计算步骤明确，但需要将多个材料科学概念关联起来综合分析，属于中等应用层次的计算题。" + }, + { + "idx": 3658, + "question": "The density of BCC iron is 7.882 g/cm³ and the lattice parameter is 0.2886 nm when hydrogen atoms are introduced at interstitial positions. Calculate the atomic fraction of hydrogen atoms.", + "answer": "0.004", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氢原子的原子分数，答案是一个具体的数值（0.004），解答过程需要涉及密度、晶格参数等物理量的计算。 | 知识层次: 题目需要多步计算和概念关联，包括密度计算、晶格参数应用以及原子分数的推导，涉及BCC结构特性和间隙原子位置的理解，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶格参数与原子数的关系，并进行多步计算和单位转换。虽然不涉及复杂变量，但需要将多个概念关联并综合分析，属于中等偏上的难度。" + }, + { + "idx": 3659, + "question": "The density of BCC iron is 7.882 g/cm³ and the lattice parameter is 0.2886 nm when hydrogen atoms are introduced at interstitial positions. Calculate the number of unit cells required on average that contain hydrogen atoms.", + "answer": "123.5", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算单位晶胞数量），并给出了具体的数值答案（123.5），符合计算题的特征。 | 知识层次: 题目需要应用BCC晶体结构的基本知识，进行密度和晶格参数的计算，并进一步推导出含有氢原子的晶胞数量。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解BCC结构、密度计算、晶格参数与氢原子分布的关系，并进行多步计算和综合分析。虽然不涉及复杂多变量，但步骤较多且需要概念关联，因此属于等级3。" + }, + { + "idx": 3660, + "question": "Suppose one Schottky defect is present in every tenth unit cell of MgO. MgO has the sodium chloride crystal structure and a lattice parameter of 0.396 nm. Calculate the number of anion vacancies per cm3.", + "answer": "1.61 × 10^21 vacancies/cm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算每立方厘米的阴离子空位数），涉及公式应用（单位晶胞体积计算、缺陷浓度计算等），且答案以具体数值形式给出。 | 知识层次: 题目需要理解Schottky缺陷的概念，应用晶格参数计算单位体积内的缺陷数量，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解Schottky缺陷的概念、单位晶胞的计算、以及密度转换等多步骤过程。虽然不涉及复杂多变量，但需要综合应用晶体结构和缺陷知识进行准确计算。" + }, + { + "idx": 3661, + "question": "Suppose one Schottky defect is present in every tenth unit cell of MgO. MgO has the sodium chloride crystal structure and a lattice parameter of 0.396 nm. Calculate the density of the ceramic.", + "answer": "4.205 g/cm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算MgO陶瓷的密度），涉及公式应用（如密度计算公式、晶格参数与体积的关系等），答案是一个具体的数值（4.205 g/cm^3），这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算，包括晶胞体积计算、缺陷浓度计算以及密度公式的综合应用，涉及概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解Schottky缺陷的概念，掌握晶格参数与密度的关系，并进行多步计算。虽然计算步骤较多，但涉及的变量和概念相对明确，没有过于复杂的多变量处理。" + }, + { + "idx": 3662, + "question": "ZnS has the zinc blende structure. If the density is 3.02 g/cm3 and the lattice parameter is 0.59583 nm, determine the number of Schottky defects per unit cell.", + "answer": "0.0535 defects per unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞中的肖特基缺陷数量，答案是一个具体的数值结果，解答过程涉及密度、晶格参数等物理量的计算。 | 知识层次: 题目需要应用密度和晶格参数计算缺陷数量，涉及多步计算和概念关联，包括晶体结构、密度公式和缺陷浓度的综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶体结构、密度计算、缺陷浓度等多个概念，并进行多步计算和综合分析。虽然不涉及复杂多变量计算，但解题步骤较为复杂，需要较高的概念关联能力。" + }, + { + "idx": 3664, + "question": "Calculate the length of the Burgers vector in BCC niobium", + "answer": "b = 2.853 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers矢量的长度），需要使用相关公式和材料参数，最终给出具体数值结果（2.853 Å），符合计算题的特征。 | 知识层次: 题目要求计算BCC结构中柏氏矢量的长度，这涉及基本的晶体结构知识和简单的公式应用（如晶格常数与柏氏矢量的关系），属于直接套用基本公式的简单计算题。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，此题属于单一公式直接计算。题目仅要求计算BCC结构中Burgers矢量的长度，直接套用已知的晶格常数公式即可得出结果，无需多个步骤或复杂推导。" + }, + { + "idx": 3665, + "question": "Calculate the length of the Burgers vector in FCC silver", + "answer": "b = 2.889 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算FCC银中Burgers矢量的长度，需要通过数值计算和公式应用来得出具体数值结果（2.889 Å），符合计算题的特征。 | 知识层次: 题目要求计算FCC银的Burgers矢量长度，这需要应用基本的晶体学公式（b = a√2/2）和已知的晶格常数进行计算。虽然需要理解Burgers矢量的概念，但计算过程是直接的、单步的，不需要复杂的分析或多步推理。 | 难度: 在计算题中属于最简单难度，只需要直接应用FCC晶体中Burgers向量的计算公式b=a√2/2（a为晶格常数），并代入银的已知晶格常数a=4.09Å进行简单计算即可得到结果。整个过程仅涉及单一公式的直接套用和基本算术运算，不需要任何推导或组合计算步骤。" + }, + { + "idx": 3666, + "question": "Calculate the length of the Burgers vector in diamond cubic silicon", + "answer": "b = 3.840 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers vector的长度），答案是一个具体的数值结果（3.840 Å），这符合计算题的特征。 | 知识层次: 题目需要计算Burgers矢量的长度，这涉及到对晶体结构（金刚石立方硅）的理解、晶格常数的应用以及矢量计算。虽然计算本身不复杂，但需要理解Burgers矢量的定义及其在特定晶体结构中的表达，属于多步计算和概念关联的中等应用层次。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于综合性计算问题。解题需要掌握Burgers向量的概念、金刚石立方结构的晶体学知识，以及相关计算公式的应用。虽然计算步骤不算特别复杂，但需要将多个概念关联起来进行综合分析，这比单纯的多步骤计算（等级2）要求更高，但尚未达到涉及复杂多变量计算（等级4）的程度。因此在该题型内属于中等偏上的难度。" + }, + { + "idx": 3667, + "question": "A single crystal of an FCC metal is oriented so that the direction is parallel to an applied stress of 5000 psi. Calculate the resolved shear stress acting on the (111) slip plane in the [T] slip direction.", + "answer": "the resolved shear stress acting on the (111) slip plane in the [T] slip direction is 0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算在特定条件下作用于(111)滑移面的分解剪应力，需要通过数值计算和公式应用来求解。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用晶体学中的施密特定律（Schmid's Law）来计算分解剪切应力，涉及多步计算和概念关联（如FCC晶体的滑移系、方向余弦计算等），但不需要复杂的综合分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体取向、应力分解和剪切应力计算等多个概念，并进行多步计算和综合分析。虽然题目给出了具体数值，但需要正确应用公式和方向关系才能得出结果。" + }, + { + "idx": 3669, + "question": "A single crystal of an FCC metal is oriented so that the direction is parallel to an applied stress of 5000 psi. Which slip system(s) will become active first?", + "answer": "the slip systems that will become active first are λ011 and λ101.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求识别在特定应力条件下首先激活的滑移系统，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目要求确定FCC金属单晶在特定应力方向下首先激活的滑移系统，这需要理解FCC晶体的滑移系统、施密特因子计算以及应力方向与滑移系统的相互作用。虽然不涉及复杂的多步计算或深度推理，但需要综合分析晶体取向、应力方向和滑移系统的几何关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度等级。首先，题目要求分析FCC金属单晶在特定应力方向下的滑移系统激活顺序，这需要综合运用晶体学、应力分析和滑移系统选择的知识。其次，解题过程涉及多个步骤：确定可能的滑移系统、计算各滑移系统的Schmid因子、比较并确定最先激活的系统。此外，还需要理解并应用临界分切应力概念。这些要求使得该题目在简答题中属于需要多角度分析论述的难度等级。" + }, + { + "idx": 3670, + "question": "A single crystal of a BCC metal is oriented so that the direction is parallel to the applied stress. If the critical resolved shear stress required for slip is 12,000 psi, calculate the magnitude of the applied stress required to cause slip to begin in the [1,-1,1] direction on the (110) slip plane.", + "answer": "the magnitude of the applied stress required to cause slip to begin in the [1,-1,1] direction is: on the (110) slip plane: σ = ∞", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定施加应力的大小，涉及临界分切应力和晶体取向的计算，答案以数值形式给出。 | 知识层次: 题目需要进行多步计算，包括确定滑移面和滑移方向的关系，计算施密特因子，并应用临界分切应力公式。这需要理解晶体取向、滑移系统和应力分解的概念，并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体取向、临界分切应力、滑移系选择等概念，并进行多步计算和综合分析。题目涉及向量点积计算、施密特因子求解以及应力转换等步骤，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3673, + "question": "The strength of titanium is found to be 65,000 psi when the grain size is 17 x 10^-6 m and 82,000 psi when the grain size is 0.8 x 10^-6 m. Determine the constants in the Hall-Petch equation.", + "answer": "the constants in the hall-petch equation are k = 19.4 psi/sqrt(d) and σ_o = 60,290 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch方程）来确定常数，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用Hall-Petch方程进行多步计算，涉及两个不同条件下的数据求解常数，需要一定的综合分析能力和公式应用技巧。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch方程进行多步计算，涉及数据代入、方程求解和常数确定。虽然计算过程相对直接，但需要对材料科学中的Hall-Petch关系有清晰理解，并能正确关联实验数据与理论公式。" + }, + { + "idx": 3674, + "question": "The strength of titanium is found to be 65,000 psi when the grain size is 17 x 10^-6 m and 82,000 psi when the grain size is 0.8 x 10^-6 m. Determine the strength of the titanium when the grain size is reduced to 0.2 x 10^-6 m.", + "answer": "the strength of the titanium when the grain size is reduced to 0.2 x 10^-6 m is 103,670 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch关系）来确定钛的强度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的强度计算，需要理解晶粒尺寸与材料强度的关系并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，涉及对数运算和代数求解。虽然计算步骤明确，但需要正确理解晶粒尺寸与强度的关系，并准确执行单位转换和数值代入。相比简单代入公式的题目（等级2），本题需要更强的综合分析能力，但尚未达到复杂多变量计算的等级4难度。" + }, + { + "idx": 3675, + "question": "For an ASTM grain size number of 8, calculate the number of grains per square inch at a magnification of 100.", + "answer": "128 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算每平方英寸的晶粒数），并应用ASTM晶粒尺寸公式，答案是一个具体的数值结果（128 grains/in.^2），符合计算题的特征。 | 知识层次: 题目需要应用ASTM晶粒度计算公式进行一步计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级，只需要应用ASTM晶粒度计算公式N=2^(n-1)（其中n为晶粒度数），将n=8代入即可得到结果，无需额外步骤或复杂计算。" + }, + { + "idx": 3676, + "question": "For an ASTM grain size number of 8, calculate the number of grains per square inch with no magnification.", + "answer": "1.28 × 10^6 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算ASTM晶粒尺寸为8时每平方英寸的晶粒数量，需要应用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目需要应用ASTM晶粒尺寸计算公式进行简单计算，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用ASTM晶粒度计算公式N=2^(n-1)（其中n为晶粒度数），进行简单的指数运算即可得到结果，无需任何公式转换或多步骤计算。" + }, + { + "idx": 3677, + "question": "Determine the ASTM grain size number if 20 grains/square inch are observed at a magnification of 400 .", + "answer": "the astm grain size number is 9.3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（根据观察到的晶粒数量和放大倍数）来确定ASTM晶粒度数值，答案是一个具体的计算结果（9.3），这符合计算题的特征。 | 知识层次: 题目要求应用ASTM晶粒度计算公式进行简单数值计算，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用ASTM grain size number的基本公式进行计算，无需多个公式组合或复杂的解题步骤。" + }, + { + "idx": 3678, + "question": "Determine the ASTM grain size number if 25 grains/square inch are observed at a magnification of 50 .", + "answer": "the astm grain size number is n = 3.6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（根据观察到的晶粒数量和放大倍数）来确定ASTM晶粒度数值，答案是一个具体的数值结果（n = 3.6），符合计算题的特征。 | 知识层次: 题目需要应用ASTM晶粒度计算公式进行简单计算，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用ASTM grain size number的基本公式进行计算，但不需要多个公式组合或复杂转换。题目直接给出了观察到的晶粒数量和放大倍数，只需套用公式即可得出结果。" + }, + { + "idx": 3679, + "question": "Calculate the angle \\theta of a small-angle grain boundary in FCC aluminum when the dislocations are 5000 Å apart. (See Figure 4-18 and equation in Problem 4-46.)", + "answer": "\\theta = 0.0328^{\\circ}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算小角度晶界的角度），并给出了具体的参数（位错间距5000 Å）和公式参考，最终答案为具体数值（0.0328°），符合计算题的特征。 | 知识层次: 题目要求应用给定的公式进行简单的数值计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 该题目属于计算题中的简单应用层次，仅需直接套用给定公式进行单一数值计算。题目明确提供了所需公式（Problem 4-46中的方程），且计算步骤仅涉及将已知参数（位错间距5000 Å）代入公式求出θ值，无需多步骤推导或组合多个公式。在同题型（基本公式直接套用类计算题）中属于最基础难度等级。" + }, + { + "idx": 3680, + "question": "Atoms are found to move from one lattice position to another at the rate of 5 × 10^{5} jumps/s at 400^{\\circ} C when the activation energy for their movement is 30,000 cal/mol. Calculate the jump rate at 750^{\\circ} C.\n\\section*{", + "answer": "the jump rate at 750^{\\circ} C is 1.08 × 10^{9} jumps/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在750^{\\circ} C时的跳跃速率，答案是一个具体的数值结果。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度变化对原子跳跃速率的影响，需要理解活化能的概念并进行对数运算和指数运算，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、对数运算和指数计算。虽然步骤明确，但需要综合理解和正确应用相关概念，属于中等偏上的难度。" + }, + { + "idx": 3681, + "question": "The number of vacancies in a material is related to temperature by an Arrhenius equation. If the fraction of lattice points containing vacancies is 8 × 10^{-5} \\mathrm{at} 600^{\\circ} C, determine the fraction at 1000^{\\circ} C.", + "answer": "the fraction at 1000^{\\circ} C is 0.00155.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过Arrhenius方程进行数值计算，以确定在不同温度下的空位分数。解答过程涉及公式应用和具体数值计算，最终给出一个具体的数值答案。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及温度变化对空位分数的影响，需要理解方程中各参数的含义并进行数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用Arrhenius方程进行多步计算，涉及温度转换和指数运算，同时需要理解材料科学中空位浓度与温度的关系。虽然计算过程较为直接，但需要综合运用多个概念和公式，属于中等偏上的难度。" + }, + { + "idx": 3682, + "question": "The diffusion coefficient for Cr+3 in Cr2O3 is 6x10^-15 cm^2/s at 727C and is 1x10^-9 cm^2/s at 1400C. Calculate the activation energy q.", + "answer": "the activation energy q is 59,230 cal/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如阿伦尼乌斯方程）来求解激活能q，答案是一个具体的数值结果（59,230 cal/mol），符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，需要理解扩散系数与温度的关系，并能够正确关联和计算活化能。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和数学处理技巧。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，但步骤明确且无复杂变量。" + }, + { + "idx": 3683, + "question": "The diffusion coefficient for Cr+3 in Cr2O3 is 6x10^-15 cm^2/s at 727C and is 1x10^-9 cm^2/s at 1400C. Calculate the constant d0.", + "answer": "the constant d0 is 0.055 cm^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用相关公式计算出常数d0的值。答案是一个具体的数值结果，需要通过计算得出。 | 知识层次: 题目需要应用扩散系数的Arrhenius方程进行多步计算，涉及对数运算和温度转换，需要理解扩散系数与温度的关系，并进行综合分析以求解常数d0。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，但变量关系明确，步骤清晰。" + }, + { + "idx": 3684, + "question": "A 0.2-mm thick wafer of silicon is treated so that a uniform concentration gradient of antimony is produced. One surface contains 1 Sb atom per 10^8 Si atoms and the other surface contains 500 Sb atoms per 10^8 Si atoms. The lattice parameter for Si is 5.407 A. Calculate the concentration gradient in (a) atomic percent Sb per cm.", + "answer": "-0.02495 at% sb/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定浓度梯度。解答过程涉及单位转换和数学运算，最终需要给出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括浓度转换和梯度计算，涉及原子百分比的概念应用和单位转换，需要将材料科学的基本概念与数学计算相结合，但不需要复杂的推理或创新思维。 | 难度: 在计算题中属于综合性计算问题，需要理解浓度梯度的概念，进行多步计算（包括单位转换和百分比计算），并正确应用晶格参数等材料科学基础知识。虽然计算步骤明确，但涉及多个概念的关联和综合分析，属于中等偏上的难度。" + }, + { + "idx": 3686, + "question": "When a Cu-Zn alloy solidifies, one portion of the structure contains 25 atomic percent zinc and another portion 0.025mm away contains 20 atomic percent zinc. The lattice parameter for the FCC alloy is 3.63 x 10^-8 cm. Determine the concentration gradient in (a) atomic percent Zn per cm.", + "answer": "-2000 at% zn/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（浓度梯度）并应用相关公式，答案是一个具体的数值结果（-2000 at% zn/cm），符合计算题的特征。 | 知识层次: 题目主要涉及浓度梯度的基本计算，需要应用简单的公式（浓度差除以距离）并进行单位转换。虽然涉及单位换算，但整体计算过程直接且无需多步推理或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用浓度梯度的基本公式进行计算，但不需要多个公式组合或复杂推导。题目提供了所有必要的数据，只需直接套用公式即可得出结果。" + }, + { + "idx": 3688, + "question": "A 0.001 -in. BCC iron foil is used to separate a high hydrogen gas from a low hydrogen gas at 650^{\\circ} C .5 × 10^{8} H atoms / {cm}^{3} are in equilibrium with the hot side of the foil, while 2 × 10^{3} H atoms / {cm}^{3} are in equilibrium with the cold side. Determine the concentration gradient of hydrogen.", + "answer": "-1969 × 10^{8} h atoms/cm^3·cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氢的浓度梯度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及浓度梯度的计算，需要应用基本的扩散公式进行简单计算。虽然涉及温度和浓度的概念，但计算过程直接，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算，需要应用浓度梯度公式进行直接计算，但不需要多个公式组合或复杂推导。" + }, + { + "idx": 3689, + "question": "A 0.001 -in. BCC iron foil is used to separate a high hydrogen gas from a low hydrogen gas at 650^{\\circ} C .5 × 10^{8} H atoms / {cm}^{3} are in equilibrium with the hot side of the foil, while 2 × 10^{3} H atoms / {cm}^{3} are in equilibrium with the cold side. Determine the flux of hydrogen through the foil.", + "answer": "0.33 × 10^{8} h atoms/cm^2·s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氢通过铁箔的流量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用菲克第一定律进行多步计算，涉及浓度梯度、扩散系数等概念的综合运用，并需要理解边界条件和单位转换，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（如菲克第一定律）进行多步计算，涉及浓度梯度、扩散系数等概念的综合分析。虽然计算步骤较多，但变量关系明确，属于中等应用层次的计算题。" + }, + { + "idx": 3690, + "question": "A 1-mm sheet of FCC iron is used to contain nitrogen in a heat exchanger at 1200^{\\circ} C. The concentration of N at one surface is 0.04 atomic percent and the concentration at the second surface is 0.005 atomic percent. Determine the flux of nitrogen through the foil in N atoms / {cm}^{2}·s.", + "answer": "the flux of nitrogen through the foil is 7.57 × 10^{12} n atoms/cm^2 \\cdot s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如菲克第一定律）来确定氮通过铁箔的扩散通量，答案是一个具体的数值结果。 | 知识层次: 题目需要应用菲克第一定律进行扩散通量的计算，涉及多步计算和概念关联，包括浓度梯度、扩散系数等参数的确定和综合运用，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（菲克第一定律）进行多步计算，涉及浓度梯度、扩散系数和温度关系的概念关联，但变量和计算步骤相对明确，未达到复杂多变量计算的等级4标准。" + }, + { + "idx": 3691, + "question": "A 4-cm-diameter, 0.5-mm-thick spherical container made of BCC iron holds nitrogen at 700^{\\circ} C. The concentration at the inner surface is 0.05 atomic percent and at the outer surface is 0.002 atomic percent. Calculate the number of grams of nitrogen that are lost from the container per hour.", + "answer": "the nitrogen lost from the container per hour is 1.245 × 10^{-3} \\, \\text{g/h}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氮气从容器中每小时流失的克数，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括浓度差计算、扩散系数确定、扩散通量计算以及单位转换等。虽然不涉及复杂的机理分析或创新设计，但需要综合运用扩散定律和材料性质知识，属于中等难度的应用题型。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（如菲克第一定律）、几何参数转换（球形容器的表面积计算）、浓度单位转换（原子百分比到实际浓度）、时间单位转换等多步骤计算过程，同时涉及材料科学（BCC铁）和热力学（高温条件）的综合知识。虽然计算步骤明确，但需要较强的概念关联和综合分析能力，符合等级3的综合性计算问题特征。" + }, + { + "idx": 3692, + "question": "A BCC iron structure is to be manufactured that will allow no more than 50g of hydrogen to be lost per year through each square centimeter of the iron at 400^{\\circ} C. If the concentration of hydrogen at one surface is 0.05 H atom per unit cell and is 0.001 H atom per unit cell at the second surface, determine the minimum thickness of the iron.", + "answer": "the minimum thickness of the iron is 0.179 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和浓度梯度的计算，最终要求得出一个具体的数值结果（0.179 cm）。 | 知识层次: 题目需要进行多步计算，包括扩散系数的确定、菲克第一定律的应用以及单位转换等。虽然不涉及复杂的机理分析或创新设计，但需要综合运用材料科学中的扩散知识和数学计算能力，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律、单位转换和多步计算。题目涉及BCC晶体结构、氢原子浓度梯度、扩散通量限制等概念的关联分析，但未达到复杂多变量计算的程度。解题步骤包括：1)计算浓度梯度 2)确定扩散系数 3)应用菲克第一定律 4)单位换算和厚度求解，符合等级3\"综合性计算问题\"的特征。" + }, + { + "idx": 3693, + "question": "Determine the maximum allowable temperature that will produce a flux of less than 2000 H atoms / {cm}^{2}·s through a BCC iron foil when the concentration gradient is -5 × 10^{16} atoms / {cm}^{3}·{cm}. (Note the negative sign for the flux.)", + "answer": "the maximum allowable temperature is 75k (-198^{\\circ} C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定最大允许温度，答案是一个具体的数值结果（75k），这符合计算题的特征。 | 知识层次: 题目需要应用扩散定律（Fick's first law）进行多步计算，涉及浓度梯度、温度与扩散系数的关系（Arrhenius方程），并需要理解负号表示的物理意义。虽然不涉及复杂机理分析，但需要综合运用多个概念和公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（如菲克第一定律）并结合温度对扩散系数的影响公式（如阿伦尼乌斯方程）。解题步骤包括：1) 根据给定通量和浓度梯度计算扩散系数；2) 通过材料常数和温度关系反推最大允许温度。涉及多步计算和概念关联，但未达到复杂多变量计算的程度（如需要同时优化多个参数或处理非线性关系）。" + }, + { + "idx": 3694, + "question": "Compare the rate at which oxygen ions diffuse in \\mathrm{Al}_{2} \\mathrm{O}_{3} with the rate at which aluminum ions diffuse in \\mathrm{Al}_{2} \\mathrm{O}_{3} at 1500^{\\circ} C. Explain the difference.", + "answer": "the diffusion rate of oxygen ions in \\mathrm{al}_{2}\\mathrm{o}_{3} at 1500^{\\circ}C is 3.47 × 10^{-16} {cm}^{2}/s, while the diffusion rate of aluminum ions is 2.48 × 10^{-13} {cm}^{2}/s. the difference in diffusion rates is due to the ionic radii: the oxygen ion has a larger radius (1.32 Å) compared to the aluminum ion (0.51 Å), making it easier for the smaller aluminum ion to diffuse in the ceramic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较两种离子的扩散速率并解释差异，答案提供了具体的扩散速率数据和基于离子半径的解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目不仅要求比较氧离子和铝离子在氧化铝中的扩散速率，还需要解释两者差异的原因。这涉及到离子半径对扩散速率的影响机制，需要综合运用扩散理论和离子半径的知识进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求比较两种离子在相同条件下的扩散速率，并解释差异的原因。这需要学生掌握扩散速率的影响因素（如离子半径）、晶体结构对扩散的影响，并能综合运用这些知识进行机理分析。虽然不涉及多变量交互作用或复杂现象全面分析（等级5），但已超出基础概念复述或简单比较（等级1-3）的范畴，属于需要深入理解并解释机理的难度层次。" + }, + { + "idx": 3695, + "question": "Compare the diffusion coefficients of carbon in BCC iron at the allotropic transformation temperature of 912^{\\circ} C and explain the difference.", + "answer": "the diffusion coefficient of carbon in bcc iron at 912^{\\circ} C is 1.51 × 10^{-6} cm^{2} / s, while in fcc iron it is (1.92 × 10^{-7} cm^{2} / s). the packing factor of the bcc lattice (0.68) is less than that of the fcc lattice; consequently, atoms are expected to be able to diffuse more rapidly in the bcc iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较并解释碳在BCC铁中的扩散系数差异，答案提供了具体的数值和详细的解释，需要文字论述而非简单选择或计算。 | 知识层次: 题目不仅要求记忆扩散系数的具体数值，还需要解释不同晶体结构（BCC和FCC）对扩散系数的影响，涉及晶体结构、原子堆积因子和扩散机制的综合分析。这需要深入理解材料科学中的扩散现象和晶体结构特性，并进行推理分析。 | 难度: 在简答题中属于机理深度解释难度，需要考生掌握扩散系数的概念、晶体结构对扩散的影响，并能解释BCC和FCC结构在原子堆积密度上的差异如何导致扩散系数的不同。题目要求对比具体数值并给出理论解释，涉及多个知识点的综合运用和推理分析。" + }, + { + "idx": 3696, + "question": "Iron containing 0.05 % C is heated to 912 degrees C in an atmosphere that produces 1.20 % C at the surface and is held for 24 h. Calculate the carbon content at 0.05 cm beneath the surface if the iron is BCC.", + "answer": "For BCC iron, the carbon content at 0.05 cm beneath the surface is 0.95 % C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳含量），并涉及公式应用（扩散方程等），答案以具体数值形式给出。 | 知识层次: 题目需要进行多步计算，包括理解碳在BCC铁中的扩散行为，应用菲克第二定律进行数值计算，并综合分析时间和距离对碳含量的影响。这需要一定的概念关联和综合分析能力，但不需要进行复杂的机理推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解碳扩散的基本原理，应用菲克第二定律进行多步计算，并综合分析初始条件、边界条件和材料相结构（BCC）的影响。虽然涉及多个变量和步骤，但计算过程相对直接，没有过于复杂的数学处理或迭代求解。" + }, + { + "idx": 3697, + "question": "Iron containing 0.05 % C is heated to 912 degrees C in an atmosphere that produces 1.20 % C at the surface and is held for 24 h. Calculate the carbon content at 0.05 cm beneath the surface if the iron is FCC.", + "answer": "For FCC iron, the carbon content at 0.05 cm beneath the surface is 0.95 % C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳含量），并应用相关公式（FCC铁的碳扩散计算）。答案给出了具体的计算结果（0.95 % C），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及碳在FCC铁中的扩散问题，需要应用扩散方程和相关公式，同时需要理解碳含量随时间和位置变化的规律。这属于中等应用层次，需要概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律和多步计算，涉及碳浓度梯度的理解和FCC结构的影响，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3698, + "question": "What temperature is required to obtain 0.50% C at a distance of 0.5mm beneath the surface of a 0.20% C steel in 2h, when 1.10% C is present at the surface? Assume that the iron is FCC.", + "answer": "the required temperature is 1180k or 907^{\\circ} C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定条件下的温度值，答案给出了具体的数值结果（1180k或907°C），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的应用和温度与扩散系数的关系，需要综合分析材料成分、时间和距离等因素，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（如菲克第二定律）进行多步计算，涉及碳浓度梯度、扩散系数与温度的关系（如阿伦尼乌斯方程）等概念的综合运用。虽然计算步骤较多，但变量关系明确，属于典型的中等应用难度。" + }, + { + "idx": 3699, + "question": "A 0.15% C steel is to be carburized at 1100^{\\circ} C, giving 0.35% C at a distance of 1mm beneath the surface. If the surface composition is maintained at 0.90% C, what time is required?", + "answer": "the required time is 51 \\mathrm{min}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及碳扩散时间的计算，答案以具体数值形式给出。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和菲克第二定律进行综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（如Fick第二定律）进行多步计算，涉及浓度梯度、扩散系数和时间的综合求解。虽然计算过程明确，但需要正确关联多个概念并执行数值计算，属于中等偏上的复杂度。" + }, + { + "idx": 3700, + "question": "A 0.02% C steel is to be carburized at 1200^{\\circ} C in 4h, with a point 0.6mm beneath the surface reaching 0.45% C. Calculate the carbon content required at the surface of the steel.", + "answer": "the carbon content required at the surface of the steel is 0.53% C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钢表面的碳含量，答案是一个具体的数值结果（0.53% C），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及碳扩散方程的公式应用和数值计算，需要理解碳浓度分布的概念，并能够将给定条件代入公式求解表面碳含量。这属于中等应用层次，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律进行多步计算，涉及浓度梯度、扩散系数等概念的关联分析，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3701, + "question": "A 1.2% C tool steel held at 1150^{\\circ} C is exposed to oxygen for 48h. The carbon content at the steel surface is zero. To what depth will the steel be decarburized to less than 0.20% C ?", + "answer": "0.177 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定脱碳深度，答案是一个具体的数值（0.177 cm），这表明需要进行计算才能得出结果。 | 知识层次: 题目需要进行多步计算，涉及碳扩散深度的公式应用和数值计算，需要理解扩散原理和边界条件的设定，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律进行多步计算，涉及碳浓度梯度的理解和边界条件的设定，同时需要将理论公式与实际问题关联求解。虽然计算过程明确，但需要对材料科学中的扩散现象有较深的理解才能正确建立数学模型并求解。" + }, + { + "idx": 3702, + "question": "A 0.80% C steel must operate at 950^{\\circ} C in an oxidizing environment, where the carbon content at the steel surface is zero. Only the outermost 0.02 cm of the steel part can fall below 0.75% C. What is the maximum time that the steel part can operate?", + "answer": "the maximum time that the steel part can operate is 2.9 min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定钢部件在特定条件下的最大操作时间。答案是一个具体的数值（2.9 min），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及碳扩散方程的公式应用和边界条件的设定，需要综合分析材料表面碳含量变化与时间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律进行多步计算，涉及碳浓度分布分析和时间计算，但变量和条件相对明确，没有过于复杂的多变量交互。" + }, + { + "idx": 3703, + "question": "A steel with \\mathrm{BBC} crystal structure containing 0.001%N is nitrided at 550^{\\circ} C for 5h. If the nitrogen content at the steel surface is 0.08%, determine the nitrogen content at 0.25mm from the surface.", + "answer": "the nitrogen content at 0.25mm from the surface is 0.049% n.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如扩散方程）来确定特定位置的氮含量，答案以具体数值形式给出。 | 知识层次: 题目需要应用扩散定律进行多步计算，涉及浓度梯度的理解和公式应用，需要综合分析扩散距离与时间的关系，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律进行多步计算，涉及浓度梯度、扩散系数等概念的综合运用，但未达到复杂多变量计算的级别。" + }, + { + "idx": 3704, + "question": "What time is required to nitride a 0.002N steel to obtain 0.12%N at a distance of 0.002 in. beneath the surface at 625^{\\circ} C ? The nitrogen content at the surface is 0.15%.\n\\[\n\\begin{array}{l}\n", + "answer": "12.8 min", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算氮化所需的时间，涉及数值计算和公式应用，答案是一个具体的数值（12.8 min），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数代入，需要理解氮化过程的基本原理和扩散机制，但不需要进行复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律和多步计算，涉及浓度梯度、距离和温度等变量的综合分析，但未达到复杂多变量计算的等级。" + }, + { + "idx": 3705, + "question": "We currently can successfully perform a carburizing heat treatment at 1200^{\\circ} C in 1h. In an effort to reduce the cost of the brick lining in our furnace, we propose to reduce the carburizing temperature to 950^{\\circ} C. What time will be required to give us a similar carburizing treatment?", + "answer": "9.95 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如扩散方程）来确定在950°C下达到与1200°C相同渗碳效果所需的时间。答案是一个具体的数值（9.95 h），需要通过计算得出。 | 知识层次: 题目需要进行多步计算，涉及温度和时间的关系，需要应用扩散定律（如Arrhenius方程）来推导和计算不同温度下的等效处理时间。这需要理解扩散过程的基本原理，并能将概念关联到实际问题的解决中。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（如Arrhenius方程）进行多步计算，涉及温度和时间的关系转换，并需要综合分析不同温度下的扩散系数变化。虽然计算过程明确，但需要理解概念关联和进行适当的数值推导，属于中等应用层次的计算题。" + }, + { + "idx": 3706, + "question": "During freezing of a Cu-Zn alloy, we find that the composition is nonuniform. By heating the alloy to 600^{\\circ} C for 3 hours, diffusion of zinc helps to make the composition more uniform. What temperature would be required if we wished to perform this homogenization treatment in 30 minutes?", + "answer": "667°c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在30分钟内完成均匀化处理所需的温度。答案是一个具体的数值（667°C），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的应用和温度与时间关系的转换，需要理解扩散机制并关联相关公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散公式（如Arrhenius方程）进行多步计算，涉及温度和时间变量的转换，并需要对合金均匀化处理的概念有较深理解。虽然计算步骤明确，但需要综合分析不同参数之间的关系，属于中等偏上的难度。" + }, + { + "idx": 3707, + "question": "A ceramic part made of MgO is sintered successfully at 1700 degrees C in 90 minutes. To minimize thermal stresses during the process, we plan to reduce the temperature to 1500 degrees C. Which will limit the rate at which sintering can be done: diffusion of magnesium ions or diffusion of oxygen ions?", + "answer": "diffusion of oxygen is the slower of the two, due to the larger ionic radius of the oxygen.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释为什么氧离子的扩散是限制因素，涉及材料科学中的离子扩散机制和离子半径的影响，答案需要文字论述而非简单选择或判断。 | 知识层次: 题目要求分析MgO陶瓷烧结过程中不同离子扩散速率对烧结速率的影响，涉及离子扩散机制、离子半径对扩散速率的影响等复杂概念，需要综合运用材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对陶瓷烧结过程中的离子扩散机制进行深度解释，涉及对不同离子扩散速率的比较分析，并需要基于离子半径等材料科学原理进行推理。虽然不需要全面分析复杂现象（如等级5的要求），但需要机理层面的深入理解和解释，因此属于等级4难度。" + }, + { + "idx": 3708, + "question": "A ceramic part made of MgO is sintered successfully at 1700 degrees C in 90 minutes. To minimize thermal stresses during the process, we plan to reduce the temperature to 1500 degrees C. What time will be required at the lower temperature?", + "answer": "the time required at the lower temperature is 955 min or 15.9 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在较低温度下所需的时间。答案给出了具体的数值结果（955 min或15.9 h），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及烧结温度与时间的关系，需要应用相关公式进行综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用烧结动力学相关公式（如Arrhenius方程）进行多步计算，涉及温度和时间变量的转换，并要求对陶瓷烧结工艺有基本理解。虽然计算过程明确，但需要正确关联概念和选择适当的计算步骤，属于中等应用层次中的典型问题。" + }, + { + "idx": 3709, + "question": "A 850-lb force is applied to a 0.15-in. diameter nickel wire having a yield strength of 45,000 psi and a tensile strength of 55,000 psi. Determine whether the wire will plastically deform.", + "answer": "the wire will plastically deform (48,100 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算应力并与屈服强度比较），答案给出了具体的计算结果（48,100 psi），属于典型的计算题特征。 | 知识层次: 题目涉及基本的应力计算和材料强度比较，仅需应用基本公式（应力=力/面积）并进行简单比较，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求应用应力公式（应力=力/面积）进行单一计算，并比较计算结果与材料的屈服强度。虽然需要单位换算（磅力转psi）和直径转面积的计算，但整个过程仅涉及一个核心公式的直接应用，没有多步骤或复杂推导。" + }, + { + "idx": 3710, + "question": "A 850-lb force is applied to a 0.15-in. diameter nickel wire having a yield strength of 45,000 psi and a tensile strength of 55,000 psi. Determine whether the wire will experience necking.", + "answer": "no necking will occur (48,100 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算应力并与材料的屈服强度和抗拉强度比较）来判断是否会发生颈缩现象。答案给出了具体的计算结果（48,100 psi），表明这是一个基于计算的题目。 | 知识层次: 题目需要应用基本公式（应力计算）进行简单计算，并比较结果与材料的屈服强度和抗拉强度。虽然涉及多个概念（应力、屈服强度、抗拉强度），但计算过程直接，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算应力并与屈服强度和抗拉强度进行比较，虽然涉及基本公式应用和简单计算，但不需要多个公式组合或复杂推导。解题步骤包括：1) 计算横截面积；2) 计算应力；3) 与给定强度值比较。这些步骤都是直接套用公式即可完成，属于该题型内的中等偏低难度。" + }, + { + "idx": 3711, + "question": "A force of 100000 N is applied to a 10mm × 20mm iron bar having a yield strength of 400 MPa. Determine whether the bar will plastically deform.", + "answer": "the bar will plastically deform because the applied stress of 500 MPa exceeds the yield strength of 400 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算应力）和公式应用（应力=力/面积），并根据计算结果判断是否发生塑性变形。答案给出了具体的计算过程和结论，符合计算题的特征。 | 知识层次: 题目需要应用基本公式计算应力，并与已知的屈服强度进行比较，属于直接套用公式和简单计算的范畴，无需多步计算或综合分析。 | 难度: 该题目属于计算题中的单一公式直接计算类型。解题过程仅需计算应力（应力=力/面积），并与给定的屈服强度进行比较。整个过程仅涉及一个基本公式的应用和简单数值计算，无需多个公式组合或复杂推导，因此属于该题型内最基础的难度等级。" + }, + { + "idx": 3712, + "question": "A force of 100000 N is applied to a 10mm × 20mm iron bar having a tensile strength of 480 MPa. Determine whether the bar will experience necking.", + "answer": "the bar will experience necking because the applied stress of 500 MPa exceeds the tensile strength of 480 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算施加的应力）并与材料的抗拉强度进行比较，以确定是否发生颈缩。答案中包含了具体的计算过程和结论，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用（应力计算）和简单比较（应力与抗拉强度），属于直接套用公式和简单计算的范畴，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用应力公式（应力=力/面积）计算出施加的应力，然后与给定的抗拉强度进行比较即可得出结论。解题步骤简单直接，无需多个公式组合或复杂计算。" + }, + { + "idx": 3713, + "question": "Calculate the maximum force that a 0.2 -in. diameter rod of \\mathrm{Al}_{2} \\mathrm{O}_{3}, having a yield strength of 35,000 psi, can withstand with no plastic deformation. Express your answer in pounds and Newtons.", + "answer": "the maximum force the rod can withstand is 1100 lb or 4891 n.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算最大受力），需要使用公式（应力=力/面积），且答案以具体数值形式给出（1100 lb或4891 N），这些都是计算题的典型特征。 | 知识层次: 题目涉及基本公式应用（计算最大受力）和简单计算（直径转换为面积后套用屈服强度公式），不需要多步计算或综合分析，属于直接套用基础力学公式的简单应用类型。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的应力公式（应力=力/面积），通过已知的屈服强度和直径计算出最大承受力。解题步骤简单直接，无需多个公式组合或复杂计算过程。" + }, + { + "idx": 3714, + "question": "A force of 20,000 N will cause a 1 cm × 1 cm bar of magnesium to stretch from 10 cm to 10.045 cm. Calculate the modulus of elasticity in GPa.", + "answer": "the modulus of elasticity is 44.4 GPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（计算弹性模量）来得出具体数值答案（44.4 GPa），属于典型的计算题类型。 | 知识层次: 题目要求应用基本公式（弹性模量计算公式）进行简单计算，涉及直接套用公式和单位转换，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用胡克定律（应力=弹性模量×应变）这一基本公式，通过给定的力和变形数据直接计算弹性模量。解题步骤简单明确，无需多个公式组合或复杂转换，符合等级1的单一公式直接计算特征。" + }, + { + "idx": 3715, + "question": "A force of 20,000 N will cause a 1 cm × 1 cm bar of magnesium to stretch from 10 cm to 10.045 cm. Calculate the modulus of elasticity in psi.", + "answer": "the modulus of elasticity is 6.44 × 10^6 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的弹性模量，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（胡克定律）进行单步计算，属于直接套用公式的简单应用类型，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于简单公式应用计算。题目要求计算弹性模量，需要应用基本的应力-应变公式，并进行单位转换（从N/cm²到psi）。虽然涉及单位转换，但整体解题步骤较为直接，属于简单应用层次中的中等难度。" + }, + { + "idx": 3716, + "question": "A polymer bar's dimensions are 1 in . × 2 in. × 15 in. The polymer has a modulus of elasticity of 600,000 psi. What force is required to stretch the bar elastically to 15.25 in.?", + "answer": "the force required is 200,000 lb.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的力，答案是一个具体的数值结果（200,000 lb），符合计算题的特征。 | 知识层次: 题目涉及基本的弹性模量公式应用和简单的数值计算，不需要多步推理或综合分析，属于直接套用公式的简单应用。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用胡克定律（Hooke's Law）的基本公式F = E * (ΔL/L) * A，其中E、ΔL、L和A都是直接给出的或可以通过简单计算得到。无需多个公式组合或复杂转换，解题步骤非常直接。" + }, + { + "idx": 3717, + "question": "An aluminum plate 0.5 cm thick is to withstand a force of 50,000N with no permanent deformation. If the aluminum has a yield strength of 125 MPa, what is the minimum width of the plate?", + "answer": "the minimum width of the plate is 8 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及材料力学性能参数（屈服强度）和受力分析，最终要求计算最小宽度。答案是一个具体的数值结果（8 cm），符合计算题的特征。 | 知识层次: 题目涉及基本的应力计算和公式应用，仅需直接套用屈服强度公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用屈服强度的基本公式（应力=力/面积），并进行简单的代数变形和单位换算即可求解。解题步骤直接且无需组合多个公式或复杂计算。" + }, + { + "idx": 3718, + "question": "(a) A 3-in.-diameter rod of copper is to be reduced to a 2-in.-diameter rod by being pushed through an opening. To account for the elastic strain, what should be the diameter of the opening? The modulus of elasticity for the copper is 17 × 10^{6} psi and the yield strength is 40,000 psi.", + "answer": "the diameter of the opening should be 1.995 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定开口的直径。答案是一个具体的数值结果（1.995 in.），这表明解答过程涉及计算。 | 知识层次: 题目需要进行多步计算，涉及弹性应变和材料性能的综合分析，需要理解并应用胡克定律和屈服强度的概念，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解弹性应变的概念，应用胡克定律进行多步计算，并综合考虑材料的弹性模量和屈服强度。虽然计算过程较为直接，但需要正确关联多个物理量并准确应用公式，属于中等偏上的难度。" + }, + { + "idx": 3719, + "question": "A 0.4-in. diameter, 12-in-long titanium bar has a yield strength of 50,000 psi, a modulus of elasticity of 16x10^6 psi, and Poisson's ratio of 0.30. Determine the length of the bar when a 500-lb load is applied.", + "answer": "the final length of the bar is 12.00298 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如应力、应变、胡克定律等）来确定棒材在受力后的最终长度，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本公式的直接应用（胡克定律计算应变和长度变化），仅需单步计算和简单变形，无需多概念关联或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用胡克定律（Hooke's Law）来计算伸长量，然后加上原始长度得到最终长度。计算过程简单直接，不涉及多个公式的组合或复杂的推导步骤。" + }, + { + "idx": 3721, + "question": "A three-point bend test is performed on a block of ZrO2 that is 8 in. long, 0.50 in. wide, and 0.25 in. thick and is resting on two supports 4 in. apart. When a force of 400 lb is applied, the specimen deflects 0.037 in. and breaks. Calculate the flexural strength.", + "answer": "flexural strength = 76,800 psi", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（三点弯曲测试公式）来求解弯曲强度，答案是一个具体的数值结果（76,800 psi），属于典型的计算题特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即三点弯曲测试中弯曲强度的计算。虽然需要理解测试条件和公式，但计算过程直接且无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目直接给出了三点弯曲测试的基本参数，只需要套用弯曲强度的公式进行计算即可，无需额外的步骤或复杂的公式组合。" + }, + { + "idx": 3722, + "question": "A three-point bend test is performed on a block of ZrO2 that is 8 in. long, 0.50 in. wide, and 0.25 in. thick and is resting on two supports 4 in. apart. When a force of 400 lb is applied, the specimen deflects 0.037 in. and breaks. Calculate the flexural modulus, assuming that no plastic deformation occurs.", + "answer": "flexural modulus = 22.14 x 10^6 psi", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解flexural modulus（弯曲模量），答案是一个具体的数值结果（22.14 x 10^6 psi），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用三点弯曲测试的公式来计算弯曲模量，涉及对材料力学性能的理解和综合分析。虽然计算过程相对直接，但需要正确应用公式并理解各个参数的含义，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用三点弯曲测试的公式进行多步计算，涉及长度、宽度、厚度、力和挠度等多个变量的综合处理，同时要求理解弹性变形的基本概念。虽然计算步骤明确，但需要正确关联各个参数并准确应用公式，属于中等偏上的难度。" + }, + { + "idx": 3723, + "question": "A three-point bend test is performed on a block of silicon carbide that is 10 cm long, 1.5 cm wide, and 0.6 cm thick and is resting on two supports 7.5 cm apart. The sample breaks when a deflection of 0.09mm is recorded. Calculate the force that caused the fracture. The flexural modulus for silicon carbide is 480 GPa. Assume that no plastic deformation occurs.", + "answer": "the force that caused the fracture is 1327 n.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及三点弯曲测试的力学计算，最终需要得出一个具体的力值作为答案。 | 知识层次: 题目需要进行多步计算，涉及弯曲模量的应用、挠度与力的关系计算，需要综合分析材料力学性能参数和几何尺寸的影响，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用三点弯曲测试的公式，涉及多步计算和概念关联，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3724, + "question": "A three-point bend test is performed on a block of silicon carbide that is 10 cm long, 1.5 cm wide, and 0.6 cm thick and is resting on two supports 7.5 cm apart. The sample breaks when a deflection of 0.09mm is recorded. Calculate the flexural strength. The flexural modulus for silicon carbide is 480 GPa. Assume that no plastic deformation occurs.", + "answer": "the flexural strength is 276 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用（计算弯曲强度），答案是一个具体的数值结果（276 MPa），解答过程需要运用材料力学中的弯曲强度公式。 | 知识层次: 题目需要进行多步计算，包括应用三点弯曲测试的公式计算弯曲强度，涉及对材料力学性能的理解和公式的正确应用。虽然不涉及复杂的推理或综合分析，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要应用三点弯曲测试的公式，涉及多个步骤的计算（包括力臂、弯矩、截面惯性矩等），并需要理解材料力学中的基本概念如弯曲强度和弯曲模量。虽然计算过程较为直接，但需要综合运用多个知识点和公式，属于中等偏上的难度。" + }, + { + "idx": 3725, + "question": "A thermosetting polymer containing glass beads is required to deflect 0.5mm when a force of 500 N is applied. The polymer part is 2 cm wide, 0.5 cm thick, and 10 cm long. If the flexural modulus is 6.9 GPa, determine the minimum distance between the supports.", + "answer": "the minimum distance between the supports is 41 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最小支撑距离，答案是一个具体的数值结果（41 mm），符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解弯曲模量的概念并将其应用于梁的挠度计算中。虽然计算过程较为直接，但需要正确选择和组合相关公式（如梁的挠度公式），并进行单位转换和数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用材料力学中的弯曲变形公式，进行多步计算和单位转换。题目涉及多个参数（力、尺寸、模量）的综合运用，但计算过程相对直接，没有涉及复杂变量或非线性关系。" + }, + { + "idx": 3726, + "question": "Will the polymer fracture if its flexural strength is 85 MPa? Assume that no plastic deformation occurs.", + "answer": "the applied stress is 61.5 MPa, which is less than the flexural strength of 85 MPa; the polymer is not expected to fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来判断聚合物是否会断裂，答案提供了详细的解释和比较，符合简答题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，只需比较施加应力与弯曲强度的大小关系，无需多步计算或综合分析。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求根据给定的弯曲强度和应用应力进行比较，判断聚合物是否会断裂。解题步骤简单直接，仅需套用基本公式和进行简单的数值比较，无需深入分析或多步骤推理。因此，在简答题的简单应用层次中，该题目属于较低难度。" + }, + { + "idx": 3727, + "question": "(b) The flexural modulus of alumina is 45 × 10^{6} psi and its flexural strength is 46,000 psi. A bar of alumina 0.3 in. thick, 1.0 in. wide, and 10 in. long is placed on supports 7 in. apart. Determine the amount of deflection at the moment the bar breaks, assuming that no plastic deformation occurs.", + "answer": "the deflection at the moment the bar breaks is 0.0278 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氧化铝棒断裂时的挠度，答案是一个具体的数值结果（0.0278 in.），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用弯曲模量和弯曲强度的公式，计算梁的挠度，并假设无塑性变形。这需要理解材料力学的基本原理，并能将这些原理应用于具体问题中。虽然不涉及复杂的综合分析或创新设计，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要应用多个公式（如弯曲模量、弯曲强度、挠度公式）并进行多步计算。题目涉及材料力学的基本概念和综合分析能力，但计算过程相对直接，没有涉及复杂多变量或高阶数学运算。" + }, + { + "idx": 3728, + "question": "A Brinell hardness measurement, using a 10-mm-diameter indenter and a 500-kg load, produces an indentation of 4.5mm on an aluminum plate. Determine the Brinell hardness number (HB) of the metal.", + "answer": " hb = 29.8 ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定Brinell硬度数（HB），答案是一个具体的数值结果（29.8），这表明解答过程涉及计算步骤和公式运用。 | 知识层次: 题目要求直接应用Brinell硬度计算公式进行数值计算，属于基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用Brinell硬度的基本公式进行计算，无需多个公式组合或复杂步骤。解题过程仅涉及简单的数值代入和算术运算，符合等级1的标准。" + }, + { + "idx": 3729, + "question": "When a 3000-kg load is applied to a 10-mm-diameter ball in a Brinell test of a steel, an indentation of 3.1mm is produced. Estimate the tensile strength of the steel.", + "answer": "the tensile strength of the steel is 194,000 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来估计钢的抗拉强度，答案是一个具体的数值结果。 | 知识层次: 题目主要涉及布氏硬度测试的基本公式应用和简单计算，需要将已知的载荷、压头直径和压痕直径代入公式进行计算，得出抗拉强度。虽然需要一定的理解和应用能力，但计算过程相对直接，不涉及多步计算或复杂的概念关联。 | 难度: 在计算题中属于简单公式应用计算，需要理解布氏硬度测试的基本原理并应用相关公式进行计算，但不需要多个公式组合或复杂推导。" + }, + { + "idx": 3730, + "question": "A ceramic matrix composite contains internal flaws as large as 0.001 cm in length. The plane strain fracture toughness of the composite is 45 MPa / m and the tensile strength is 550 MPa. Will the flaw cause the composite to fail before the tensile strength is reached? Assume that f=1.", + "answer": "the applied stress required for the crack to cause failure is 11,354 MPa. the tensile strength of the composite is 550 MPa. any failure of the ceramic should be expected due to the massive overload, not because of the presence of the flaws.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算裂纹导致失效所需的应力），并应用断裂力学公式（K_IC = f * σ * √(πa)）。答案给出了具体的计算结果和比较过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用断裂力学公式计算临界应力，并将计算结果与材料的拉伸强度进行比较。虽然计算过程相对直接，但需要理解断裂韧性和裂纹尺寸之间的关系，以及如何将这些概念应用于实际材料失效分析。这超出了简单应用的范围，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，并综合分析计算结果与材料性能的关系。题目涉及平面应变断裂韧性和裂纹尺寸的计算，要求考生能够正确应用公式并理解计算结果的实际意义。虽然计算步骤明确，但需要对概念有较深的理解才能正确解答。" + }, + { + "idx": 3731, + "question": "An aluminum alloy that has a plane strain fracture toughness of 25,000 psi \\sqrt{m}. fails when a stress of 42,000 psi is applied. Observation of the fracture surface indicates that fracture began at the surface of the part. Estimate the size of the flaw that initiated fracture. Assume that f=1.1.", + "answer": "the size of the flaw that initiated fracture is 0.093 \\text{ in}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计缺陷的大小，答案是一个具体的数值结果，解答过程需要运用材料科学中的断裂力学公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及平面应变断裂韧性和应力应用的公式关联，需要综合分析已知条件并应用正确的公式来估算缺陷尺寸。虽然计算过程不复杂，但需要理解相关概念和公式的适用条件。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及应力强度因子和缺陷尺寸的关系，并需要理解表面缺陷的几何修正因子。虽然计算步骤明确，但需要对相关概念有较好的掌握才能正确应用公式。" + }, + { + "idx": 3732, + "question": "A polymer that contains internal flaws 1mm in length fails at a stress of 25 MPa. Determine the plane strain fracture toughness of the polymer. Assume that f=1.", + "answer": "the plane strain fracture toughness of the polymer is 0.99 \\text{mpa} \\sqrt{m}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（平面应变断裂韧性公式）来求解聚合物的平面应变断裂韧性，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本公式的直接应用（断裂韧性公式K_IC = σ√(πa)），仅需简单计算和参数代入，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用平面应变断裂韧性的基本公式（K_IC = σ√(πa)），并将给定的应力（25 MPa）和缺陷长度（1mm）直接代入即可得到结果。无需多个公式组合或复杂计算步骤，属于最基础的计算题类型。" + }, + { + "idx": 3733, + "question": "A ceramic part for a jet engine has a yield strength of 75,000 psi and a plane strain fracture toughness of 5,000 psi / in. To be sure that the part does not fail, we plan to assure that the maximum applied stress is only one third the yield strength. We use a nondestructive test that will detect any internal flaws greater than 0.05 in. long. Assuming that f=1.4, does our nondestructive test have the required sensitivity? Explain.", + "answer": "the length of internal flaws is 2a = 0.013 in. our nondestructive test can detect flaws as small as 0.05 in. long, which is not smaller than the critical flaw size required for failure. thus our ndt test is not satisfactory.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述非破坏性测试是否具有所需的灵敏度，答案包含计算过程和文字解释，而不仅仅是简单的选择或判断。 | 知识层次: 题目需要进行多步计算（计算最大允许应力、临界缺陷尺寸等），并综合分析非破坏性检测的灵敏度是否满足要求。虽然不涉及复杂的机理分析或创新设计，但需要将多个概念和计算步骤关联起来进行判断。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目涉及多个材料科学的核心概念，如屈服强度、平面应变断裂韧性和非破坏性测试的灵敏度。其次，解题过程需要多步计算，包括计算最大允许应力、临界裂纹尺寸，并与非破坏性测试的检测能力进行比较。此外，题目要求综合分析这些计算结果，并给出明确的解释和结论。虽然题目没有要求深度关联性分析（如考虑温度效应或疲劳加载等更复杂因素），但其多角度分析论述的要求使其在简答题中属于较高难度等级。" + }, + { + "idx": 3734, + "question": "To survive for one million cycles under conditions that provide for equal compressive and tensile stresses, what is the fatigue strength, or maximum stress amplitude, required?", + "answer": "The fatigue strength at one million cycles is 22 mpa.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供一个具体的数值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的疲劳强度值，需要根据材料科学知识进行解释或论述。 | 知识层次: 题目要求根据给定的条件（一百万次循环）直接应用疲劳强度的概念，并给出具体的数值答案。这属于基本公式应用和简单计算的范畴，不需要多步计算或复杂的综合分析。 | 难度: 在简答题中属于简单应用过程描述，题目要求直接应用疲劳强度的基本概念和公式进行计算，解题步骤简单明确，无需深入分析或详细解释。" + }, + { + "idx": 3735, + "question": "What are the maximum stress, the minimum stress, and the mean stress on the part during its use under conditions that provide for equal compressive and tensile stresses?", + "answer": "The maximum stress is +22 mpa, the minimum stress is -22 mpa, and the mean stress is 0 mpa.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述最大应力、最小应力和平均应力的具体数值，答案以文字形式给出具体数值，没有涉及计算步骤或选择判断。 | 知识层次: 题目要求计算最大应力、最小应力和平均应力，属于基本公式应用和简单计算，直接套用应力分析的基本原理即可得出答案，不需要多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述难度，题目要求直接应用基本公式计算最大应力、最小应力和平均应力，解题步骤简单明确，无需深入解释或详细论述。" + }, + { + "idx": 3736, + "question": "What effect would the frequency of the stress application have on the fatigue strength, maximum stress, minimum stress, and mean stress?", + "answer": "A high frequency will cause heating of the polymer. As the temperature of the polymer increases, the fatigue strength will decrease. If the applied stress is not reduced, then the polymer will fail in a shorter time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释频率对疲劳强度、最大应力、最小应力和平均应力的影响，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求分析应力频率对疲劳强度、最大应力、最小应力和平均应力的影响，并解释其机理（如高频导致聚合物发热进而影响疲劳强度）。这需要综合运用材料科学和力学知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求分析应力频率对疲劳强度、最大应力、最小应力和平均应力的影响，并解释其背后的机理（如高频导致聚合物发热进而影响疲劳强度）。这需要综合运用材料科学和力学知识，进行推理分析，并详细解释现象背后的物理机制。虽然题目涉及多个变量，但并未要求全面分析复杂现象的所有可能情况，因此属于等级4而非等级5。" + }, + { + "idx": 3737, + "question": "The activation energy for self-diffusion in copper is 49,300 cal / mol. A copper specimen creps as t 0.002 N / fn .-h when a stress of 15,000 psi is applied at 600^{\\circ} C. If the creep rate of copper is dependent on self-diffusion, determine the creep rate if the temperature is 800^{\\circ} C.", + "answer": "the creep rate is 0.4, N / in·h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（涉及激活能、温度变化对蠕变速率的影响）来求解特定温度下的蠕变速率，最终答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用阿伦尼乌斯公式进行温度对蠕变速率的影响分析，并理解自扩散与蠕变速率之间的关系。虽然计算过程较为直接，但需要综合理解和应用多个概念。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、应力分析和扩散系数的综合应用。虽然步骤明确，但需要较强的概念关联和数值计算能力。" + }, + { + "idx": 3738, + "question": "When a stress of 20000 psi is applied to a material heated to 900^{\\circ} C, rupture occurs in 25000h. If the activation energy for rupture is 35000 cal / mol, determine the rupture time if the temperature is reduced to 800^{\\circ} C.", + "answer": "the rupture time at 800^{\\circ} C is 101660h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如阿伦尼乌斯方程）来确定断裂时间，答案是一个具体的数值结果（101660h），属于典型的计算题特征。 | 知识层次: 题目需要应用Larson-Miller参数公式进行多步计算，涉及温度转换、激活能的应用以及对数运算，需要将概念关联并进行综合分析。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、活化能概念和数值代入，但步骤相对明确，没有涉及复杂多变量或非常规计算。" + }, + { + "idx": 3739, + "question": "Using the data in Figure 7-27 for an iron-chromium-nickel alloy, determine the activation energy Q_{r} for rupture in the temperature range 980 to 1090^{\\circ} C.", + "answer": "the activation energy q_{r} is 117,000 \text{ cal/mol}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表数据计算激活能Q_{r}，需要应用公式和数值计算，答案是一个具体的数值结果(117,000 cal/mol)，这些都是计算题的典型特征。 | 知识层次: 题目需要从图表中提取数据，应用公式进行多步计算，并理解活化能的概念及其在材料科学中的意义。这涉及中等程度的认知能力和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要从图表中提取数据、应用相关公式（如阿伦尼乌斯方程）进行多步计算，并理解活化能的概念及其在材料科学中的意义。虽然涉及多个步骤和概念关联，但计算过程相对直接，没有涉及复杂多变量或高级数学工具。" + }, + { + "idx": 3740, + "question": "Using the data in Figure 7-27 for an iron-chromium-nickel alloy, determine the constant m for rupture in the temperature range 980 to 1090^{\\circ} C.", + "answer": "the constant m for rupture is 3.9.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表数据确定常数m的值，需要通过计算和数据分析得出具体数值3.9，符合计算题的特征。 | 知识层次: 题目要求根据图表数据进行计算，涉及多步分析和温度范围内的参数确定，需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用给定的数据图表（Figure 7-27），进行多步计算以确定常数m。题目涉及温度范围的综合分析，要求对材料科学中的合金性能有较深的理解，并能够将概念与数值计算相结合。虽然计算步骤不算极其复杂，但需要较强的概念关联和综合分析能力，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 3741, + "question": "A 0.25-in.-thick copper plate is to be cold worked 63%. Find the final thickness.", + "answer": " t_{f} = 0.0925 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最终厚度，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的冷加工变形计算，只需应用简单的公式进行一步计算即可得到结果，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用冷加工变形公式（t_f = t_0*(1-CW%)）进行一步计算，无需多步骤推导或组合公式，属于该题型下最基础的难度级别。" + }, + { + "idx": 3742, + "question": "A 0.25-in.-diameter copper bar is to be cold worked 63%. Find the final diameter.", + "answer": "the final diameter is 0.152 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最终的直径，答案是一个具体的数值结果，解答过程涉及材料科学中的冷加工变形计算。 | 知识层次: 题目涉及基本的冷加工变形计算，只需要应用简单的公式进行一步计算即可得出结果，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅需应用冷加工变形公式（面积变化与直径的关系），无需多步骤推导或组合公式。解题过程仅涉及一次代数运算，属于该题型内最基础的难度层级。" + }, + { + "idx": 3743, + "question": "A 2-in.-diameter copper rod is reduced to 1.5 in. diameter, then reduced again to a final diameter of 1 in. In a second case, the 2-in.-diameter rod is reduced in one step from 2 in. to a 1 in. diameter. Calculate the% CW for both cases.", + "answer": "75% in both cases.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算% CW），并应用相关公式，答案以数值形式呈现。 | 知识层次: 题目主要涉及冷加工变形百分比（%CW）的基本公式应用和简单计算，虽然需要分步计算，但每一步都是直接套用公式，不需要复杂的综合分析或推理过程。 | 难度: 在计算题中属于简单应用难度，需要应用冷加工变形（%CW）的基本公式进行计算。虽然题目描述了两种不同的加工路径，但计算过程都是直接套用公式，没有涉及多个公式的组合或复杂推导。解题步骤相对简单，只需理解并应用%CW的计算方法即可得出结果。" + }, + { + "idx": 3744, + "question": "Suppose that liquid nickel is undercooled until homogeneous nucleation occurs. Calculate the critical radius of the nucleus required. Assume that the lattice parameter of the solid FCC nickel is 0.356 nm.", + "answer": "the critical radius of the nucleus required is 6.65 × 10^-8 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界核半径，答案是一个具体的数值结果（6.65 × 10^-8 cm），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及临界核半径的计算公式应用，需要理解均相成核的概念，并将晶格参数与临界半径的计算关联起来。虽然不涉及复杂的综合分析或机理解释，但比简单的直接套用公式更复杂。 | 难度: 在计算题中属于综合性计算问题，需要理解均匀成核理论、临界半径公式的应用，并进行多步计算。题目涉及晶格参数转换、表面能和体积自由能差等概念的综合运用，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3745, + "question": "Suppose that liquid nickel is undercooled until homogeneous nucleation occurs. Calculate the number of nickel atoms in the nucleus. Assume that the lattice parameter of the solid FCC nickel is 0.356 nm.", + "answer": "the number of nickel atoms in the nucleus is 109 atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算镍原子在核中的数量），并给出了具体的参数（FCC镍的晶格参数）。答案是一个具体的数值（109 atoms），这表明需要通过公式和计算来得出结果。 | 知识层次: 题目需要多步计算和概念关联，包括理解均质成核的概念、计算晶胞体积、确定每个晶胞中的原子数，以及综合这些信息来计算核中的原子总数。虽然不涉及复杂的推理分析或机理解释，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解均匀成核的概念，应用FCC晶格参数计算晶胞体积，并进一步推导出原子数量。涉及多步计算和概念关联，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3746, + "question": "Suppose that liquid iron is undercooled until homogeneous nucleation occurs. Calculate the critical radius of the nucleus required. Assume that the lattice parameter of the solid BCC iron is 2.92 Å.", + "answer": "10.128 × 10⁻⁸ cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算临界核半径），并给出了具体的物理参数（BCC铁的晶格参数），最终答案是一个具体的数值结果（10.128 × 10⁻⁸ cm），这符合计算题的特征。 | 知识层次: 题目需要应用均相形核理论中的临界半径计算公式，涉及多步计算和概念关联（如晶格参数与临界半径的关系），但不需要复杂的综合分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解均匀成核理论、临界半径公式的应用，并涉及晶格参数与临界半径的转换计算。虽然计算步骤明确，但需要将多个物理概念和公式结合起来进行综合分析，属于中等偏上的难度。" + }, + { + "idx": 3747, + "question": "Suppose that liquid iron is undercooled until homogeneous nucleation occurs. Calculate the number of iron atoms in the nucleus. Assume that the lattice parameter of the solid BCC iron is 2.92 Å.", + "answer": "350 atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铁原子在核中的数量），并给出了具体的计算参数（BCC铁的晶格参数为2.92 Å），最终答案为具体数值（350 atoms），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算晶胞体积、每个晶胞中的原子数以及核中的原子数，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的计算步骤和概念理解。 | 难度: 在计算题中属于综合性计算问题，需要理解均匀成核的概念，应用BCC晶体结构的知识，进行多步计算（包括体积计算、原子数估算等），并综合分析多个参数。虽然不涉及复杂多变量，但步骤较多且需要概念关联，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 3748, + "question": "Suppose that solid nickel was able to nucleate homogeneously with an undercooling of only 22^{\\circ} C. How many atoms would have to group together spontaneously for this to occur? Assume that the lattice parameter of the solid FCC nickel is 0.356nm.", + "answer": "1.136 × 10^{6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解自发成核所需的原子数量，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括理解均相成核的概念、应用临界核尺寸公式、计算晶胞体积和原子数，并最终综合这些信息得出结果。这需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算自发成核所需的原子数量，涉及晶格参数、均质成核理论以及相关公式的综合运用。虽然计算步骤较多，但题目提供了必要的参数和明确的求解目标，因此属于中等难度。" + }, + { + "idx": 3749, + "question": "Suppose that solid iron was able to nucleate homogeneously with an undercooling of only 15^{\\circ} C. How many atoms would have to group together spontaneously for this to occur? Assume that the lattice parameter of the solid BCC iron is 2.92 Å.", + "answer": "7.676 × 10^{6} atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定自发成核所需的原子数量。答案是一个具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要多步计算和概念关联，包括理解均质形核理论、计算临界形核半径、应用BCC晶体结构参数计算原子数等，涉及多个知识点的综合应用。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算铁原子在特定过冷度下自发成核所需的原子数量，涉及晶体结构参数、成核理论公式和单位换算等知识点。虽然计算步骤明确，但需要综合运用多个概念并进行数值推导，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 3750, + "question": "Calculate the fraction of solidification that occurs dendritically when iron nucleates at 10 degrees Celsius undercooling. The specific heat of iron is 5.78 J/cm^3·°C.", + "answer": "0.0333", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算凝固分数），并给出了具体的物理参数（比热容）和条件（过冷度），最终答案为具体的数值结果（0.0333），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及凝固分数和过冷度的概念关联，需要综合分析热力学参数（如比热容）来计算结果，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用热力学公式进行多步计算，涉及过冷度、比热容等概念的关联分析，但计算过程相对直接，没有涉及复杂多变量或迭代计算。" + }, + { + "idx": 3752, + "question": "Calculate the fraction of solidification that occurs dendritically when iron nucleates homogeneously. The specific heat of iron is 5.78 J/cm^3·°C.", + "answer": "all dendritically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释铁均匀成核时枝晶凝固的比例，答案需要文字解释而非数值计算或选择选项 | 知识层次: 题目主要考查对铁凝固过程中枝晶形成的基本概念的理解和记忆，不需要复杂的计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求回答一个基本概念（铁均匀形核时的凝固方式），无需解释或论述复杂概念体系。答案直接给出\"all dendritically\"这一简单结论，属于基础定义简答级别，符合等级1的基本特征。" + }, + { + "idx": 3753, + "question": "Calculate the fraction of solidification that occurs dendritically when silver nucleates at 10 degrees Celsius undercooling. The specific heat of silver is 3.25 J/cm^3·°C.", + "answer": "0.0237", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算银在10度过冷度下发生枝晶凝固的分数），需要使用给定的物理参数（比热容）和公式进行计算，最终答案为具体数值0.0237，符合计算题的特征。 | 知识层次: 题目需要应用特定的热力学公式进行多步计算，涉及固相分数和过冷度的关系，需要理解固溶体凝固的基本原理并进行综合分析。虽然计算过程不复杂，但需要将多个概念关联起来，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用热力学和凝固理论的知识，进行多步计算和概念关联。题目要求计算银在特定过冷度下的枝晶凝固分数，涉及比热容和凝固潜热的综合运用，但计算步骤相对明确，没有复杂多变量的干扰。" + }, + { + "idx": 3755, + "question": "Calculate the fraction of solidification that occurs dendritically when silver nucleates homogeneously. The specific heat of silver is 3.25 J/cm^3·°C.", + "answer": "0.842", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算银的凝固分数），并给出了具体的物理参数（比热容），最终答案为数值结果（0.842），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及固相分数计算和热力学参数的应用，需要将特定概念与公式关联起来综合分析，但不需要复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解固相分数和热力学概念，进行多步计算和综合分析，但不需要处理复杂多变量。" + }, + { + "idx": 3756, + "question": "A 2-in. cube solidifies in 4.6 min. Calculate (a) the mold constant in Chvorinov's rule. Assume that n=2.", + "answer": "the mold constant in chvorinov's rule is 41.48 min/in^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Chvorinov's rule）来求解模具常数，答案是一个具体的数值结果（41.48 min/in^2），符合计算题的特征。 | 知识层次: 题目要求直接应用Chvorinov's rule进行简单的数值计算，仅涉及基本公式的直接套用和单步计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，只需要直接套用Chvorinov's rule的单一公式进行计算，无需多个公式组合或复杂步骤。题目明确给出了所有必要参数，计算过程简单直接。" + }, + { + "idx": 3757, + "question": "A 2-in. cube solidifies in 4.6 min. Calculate (b) the solidification time for a 0.5 in. x 0.5 in. x 6 in. bar cast under the same conditions. Assume that n=2.", + "answer": "the solidification time for the bar is 0.60 min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和条件来求解固结时间，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，需要根据给定的条件直接套用凝固时间公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用相同的凝固条件（n=2）和已知的立方体凝固时间来计算条形铸件的凝固时间。虽然需要理解凝固时间与体积/表面积比的关系，但解题步骤相对直接，仅需套用已知公式并进行简单计算即可得出结果。不需要多个公式组合或复杂推导。" + }, + { + "idx": 3758, + "question": "A 5-cm diameter sphere solidifies in 1050s. Calculate the solidification time for a 0.3 cm × 10 cm × 20 cm plate cast under the same conditions. Assume that n=2.", + "answer": "the solidification time for the plate is 31.15s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以求解不同形状物体的凝固时间，答案也是一个具体的数值结果。 | 知识层次: 题目需要应用凝固时间计算公式，并进行多步计算（从球体推导到平板），涉及不同几何形状的体积/表面积比转换，需要概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用固结时间公式并进行多步计算，包括体积与表面积比的转换和不同几何形状的参数调整。虽然计算过程明确，但需要理解并关联多个概念，如固结时间与几何形状的关系，以及n值的应用。" + }, + { + "idx": 3759, + "question": "Calculate the diameter of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the diameter of the riser d ≥ 6.67 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的直径），并给出了具体的公式应用条件（H/D比例），答案也是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及铸造工艺中缩孔防止的基本原理和圆柱形冒口尺寸的计算公式应用，需要理解H/D比的概念并将其应用于实际计算中，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算圆柱形冒口的直径以防止铸件收缩，涉及H/D比的概念和具体公式应用。虽然计算步骤明确，但需要综合理解铸造原理和几何关系，属于中等应用层次的计算题。" + }, + { + "idx": 3760, + "question": "Calculate the height of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the height of the riser h ≥ 10 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的高度），并给出了具体的公式应用（H/D比例），答案也是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要根据给定的H/D比例和铸件尺寸进行直接计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用H/D比的基本公式进行计算，但不需要多个公式组合或复杂推导。解题步骤较为直接，属于该题型框架内的中等偏低难度。" + }, + { + "idx": 3761, + "question": "Calculate the volume of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the volume of the riser v ≥ 349 in.^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的体积），并给出了具体的参数和条件（H/D比为1.5），答案也是一个具体的数值结果（349 in.^3），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解圆柱形冒口的几何关系（H/D=1.5）以及防止收缩所需的体积计算，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用圆柱体体积公式、理解H/D比的概念，并进行多步计算来求解。虽然涉及多个概念和步骤，但计算过程相对直接，没有引入复杂变量或高级数学工具，因此在同类题型中属于中等难度。" + }, + { + "idx": 3762, + "question": "Calculate the diameter of the cylindrical riser required to prevent shrinkage in a 1 in. x 6 in. x 6 in. casting if the H/D of the riser is 1.0.", + "answer": "the diameter of the riser must be at least 2.25 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的直径），并给出了具体的计算条件和要求（H/D比例为1.0），答案也是一个具体的数值结果（2.25英寸）。这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及铸造收缩预防和圆柱形冒口尺寸设计，需要理解H/D比的概念并应用相关公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解铸造收缩原理、掌握圆柱形冒口设计公式（H/D=1.0约束条件），并完成多步体积计算与尺寸换算。虽然计算过程明确，但涉及铸造工艺参数的综合应用，比简单代入公式的题目（等级2）更具挑战性，但尚未达到需要处理多变量耦合的复杂程度（等级4）。" + }, + { + "idx": 3763, + "question": "Calculate the height of the cylindrical riser required to prevent shrinkage in a 1 in. x 6 in. x 6 in. casting if the H/D of the riser is 1.0.", + "answer": "the height of the riser must be at least 2.25 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的高度），并给出了具体的公式应用条件（H/D=1.0），答案也是一个具体的数值结果（2.25 in.）。 | 知识层次: 题目需要进行多步计算，包括确定铸造件的体积和表面积，计算模数，并应用H/D比例来确定冒口的高度。这涉及到概念关联和综合分析，而不仅仅是简单的公式应用或基础概念记忆。 | 难度: 在计算题中属于综合性计算问题，需要理解铸造收缩原理、掌握圆柱形冒口设计公式（H/D比），并进行多步骤计算（包括体积计算、收缩补偿计算和几何比例转换）。虽然计算过程明确，但需要将多个工程概念关联应用，属于中等应用层次的计算题。" + }, + { + "idx": 3764, + "question": "Calculate the volume of the cylindrical riser required to prevent shrinkage in a 1 in. x 6 in. x 6 in. casting if the H/D of the riser is 1.0.", + "answer": "the volume of the riser must be at least 8.95 in^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的体积），并且答案是一个具体的数值结果（8.95 in^3），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及铸造收缩预防和冒口设计的基本原理应用，需要理解H/D比的概念并正确计算体积，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要理解铸造收缩原理、圆柱形冒口设计公式（H/D=1.0），并完成多步体积计算（包括铸件模数计算和冒口尺寸换算）。虽然计算过程明确，但需要将多个工程概念关联应用，属于中等应用层次的计算题。" + }, + { + "idx": 3765, + "question": "A 4-in-diameter sphere of liquid copper is allowed to solidify, producing a spherical shrinkage cavity in the center of the casting. Determine the volume and diameter of the shrinkage cavity in the copper casting.", + "answer": "shrinkage volume: 1.709 in.^{3}; diameter of shrinkage cavity: 1.30 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定收缩腔的体积和直径，答案以具体数值形式给出，涉及公式应用和计算过程。 | 知识层次: 题目需要进行多步计算，包括体积计算和直径转换，并需要理解凝固过程中的收缩现象。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解铜的凝固收缩原理，应用体积收缩率公式进行多步计算，并综合分析得出最终结果。虽然涉及多步骤计算，但变量相对单一，不涉及复杂多变量计算。" + }, + { + "idx": 3766, + "question": "A 4-in-diameter sphere of liquid iron is allowed to solidify, producing a spherical shrinkage cavity in the center of the casting. Determine the volume and diameter of the shrinkage cavity in the iron casting.", + "answer": "shrinkage volume: 1.139 in.^{3}; diameter of shrinkage cavity: 1.30 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定收缩腔的体积和直径，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解液态铁凝固过程中的收缩现象，并应用体积计算和几何关系来确定收缩腔的体积和直径。这超出了简单公式应用的范围，但不需要复杂的综合分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解液体铁凝固过程中的收缩原理，应用体积收缩率公式进行多步计算，并综合分析得出最终结果。虽然涉及的概念和计算步骤较多，但整体流程较为明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 3767, + "question": "A 4-in. cube of a liquid metal is allowed to solidify. A spherical shrinkage cavity with a diameter of 1.49 in. is observed in the solid casting. Determine the percent volume change that occurs during solidification.", + "answer": "the percent volume change that occurs during solidification is 2.7%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定凝固过程中的体积变化百分比，答案是一个具体的数值结果（2.7%），这符合计算题的特征。 | 知识层次: 题目涉及基本的体积计算和百分比变化的公式应用，属于直接套用基本公式进行简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，需要计算液体金属凝固前后的体积变化，并应用百分比公式进行计算。虽然涉及体积计算和百分比转换，但步骤较为直接，仅需套用基本公式即可完成。" + }, + { + "idx": 3768, + "question": "A 2 cm x 4 cm x 6 cm magnesium casting is produced. After cooling to room temperature, what is the volume of the shrinkage cavity at the center of the casting?", + "answer": "the volume of the shrinkage cavity at the center of the casting is 46.03 cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算镁铸件冷却至室温后中心缩孔的体积，需要通过数值计算和公式应用来得出具体数值的答案。 | 知识层次: 题目需要进行多步计算，包括理解镁合金的收缩率、计算初始体积和最终体积，以及应用相关公式来确定收缩腔的体积。这需要将多个概念关联起来并进行综合分析，而不仅仅是简单的公式套用或基础概念的记忆。 | 难度: 在计算题中属于综合性计算问题，需要理解镁合金的收缩特性，应用体积收缩率公式，并进行多步计算。题目涉及材料科学中的实际应用场景，要求将理论知识与数值计算相结合，但未达到复杂多变量计算的难度。" + }, + { + "idx": 3769, + "question": "A 2 cm x 4 cm x 6 cm magnesium casting is produced. After cooling to room temperature, what is the percent shrinkage that must have occurred during solidification?", + "answer": "the percent shrinkage that must have occurred during solidification is 4.1%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算镁铸件在凝固过程中的收缩百分比，需要应用相关公式进行数值计算，答案是一个具体的数值结果（4.1%），符合计算题的特征。 | 知识层次: 题目涉及基本的百分收缩率计算，仅需套用简单的收缩率公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用镁的已知收缩率（4.1%）即可得出答案，无需复杂计算或多公式组合。" + }, + { + "idx": 3770, + "question": "A 2 in. × 8 in. × 10 in. iron casting is produced and, after cooling to room temperature, is found to weigh 43.9 lb. Determine the percent shrinkage that must have occurred during solidification.", + "answer": "The percent shrinkage that must have occurred during solidification is 3.4%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算铁铸件的收缩百分比），并应用相关公式来得出具体数值结果（3.4%）。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及简单的密度计算和百分比计算，属于直接套用基本公式的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的密度公式和百分比变化公式，计算步骤简单直接，无需多个公式组合或复杂推导。" + }, + { + "idx": 3771, + "question": "A 2 in. × 8 in. × 10 in. iron casting is produced and, after cooling to room temperature, is found to weigh 43.9 lb. Determine the number of shrinkage pores in the casting if all of the shrinkage occurs as pores with a diameter of 0.05 in.", + "answer": "The number of shrinkage pores in the casting is 83,354 pores.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定收缩孔的数量。答案是一个具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括密度计算、体积计算和孔隙数量计算，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及体积计算、密度应用、孔隙体积转换等多个步骤，但计算过程相对直接，没有涉及复杂变量或高级数学工具。" + }, + { + "idx": 3772, + "question": "Liquid magnesium is poured into a 2 cm × 2 cm × 24 cm mold and, as a result of directional solidification, all of the solidification shrinkage occurs along the length of the casting. Determine the length of the casting immediately after solidification is completed.", + "answer": "the length of the casting immediately after solidification is completed is 23.04 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定铸造件在凝固完成后的长度。答案是一个具体的数值结果（23.04 cm），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用基本的凝固收缩公式进行计算，属于直接套用公式的简单应用，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用简单的体积收缩公式进行计算，没有涉及多个公式的组合或复杂的解题步骤。" + }, + { + "idx": 3773, + "question": "A liquid cast iron has a density of 7.65 g/cm3. Immediately after solidification, the density of the solid cast iron is found to be 7.71 g/cm3. Determine the percent volume change that occurs during solidification.", + "answer": "the percent volume change during solidification is 0.77%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（密度变化）来确定体积变化的百分比，需要应用公式进行计算，最终给出一个具体的数值结果（0.77%）。 | 知识层次: 题目需要进行基本的密度计算和百分比变化计算，仅涉及单一公式的直接应用和简单数值运算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用密度与体积关系的基本公式，通过简单代数运算即可得出结果，无需多步骤或复杂推导。" + }, + { + "idx": 3774, + "question": "Does the cast iron expand or contract during solidification?", + "answer": "the cast iron contracts during solidification.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（cast iron在凝固时是膨胀还是收缩），答案直接给出了对错判断（contracts during solidification）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对铸铁凝固过程中体积变化这一基本概念的记忆和理解，属于材料科学基础知识的范畴。 | 难度: 在判断题的基础概念记忆题型中，该题目仅需判断铸铁凝固时的体积变化这一基本物理性质，属于最基础的定义性知识判断，无需复杂推理或概念交叉分析。" + }, + { + "idx": 3775, + "question": "The solubility of hydrogen in liquid aluminum at 715^{\\circ} C is found to be 1 cm^{3} / 100g \\mathrm{Al}. If all of this hydrogen precipitated as gas bubbles during solidification and remained trapped in the casting, calculate the volume percent gas in the solid aluminum.", + "answer": "2.699%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定固铝中气体的体积百分比。答案是一个具体的数值结果（2.699%），这表明需要通过计算得出。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及溶解度概念和体积百分比计算，但不需要多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用溶解度数据和简单的体积百分比公式进行计算，无需多个公式组合或复杂的解题步骤。" + }, + { + "idx": 3776, + "question": "Based on Hume-Rothery's conditions, would the system Au-Ag be expected to display unlimited solid solubility? Explain.", + "answer": "Yes", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件进行解释说明，答案需要文字论述而非简单选择或判断 | 知识层次: 题目要求基于Hume-Rothery规则分析Au-Ag体系的固溶度，需要理解并应用多个条件（原子尺寸、电负性、价电子浓度、晶体结构）进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求基于Hume-Rothery条件进行分析，但只需要对Au-Ag系统的基本特性进行综合说明即可，不需要多角度或深度关联性分析。解题步骤相对直接，主要涉及对Hume-Rothery规则的理解和应用。" + }, + { + "idx": 3777, + "question": "Based on Hume-Rothery's conditions, would the system Al-Cu be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Hume-Rothery条件在Al-Cu系统中的适用性，并给出结论。答案需要文字解释和论述，而不仅仅是选择或判断对错。 | 知识层次: 题目要求应用Hume-Rothery规则来分析Al-Cu系统的固溶度，需要理解并关联多个条件（如原子尺寸、电负性、价电子浓度等）进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等应用层次，要求考生理解Hume-Rothery规则并能够将其应用于具体合金系统（Al-Cu）的分析。需要考生进行多步思考：首先回忆Hume-Rothery的四个条件，然后分别评估Al和Cu在这些条件上的匹配程度，最后得出结论。虽然需要概念关联和综合分析，但不需要进行多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 3778, + "question": "Based on Hume-Rothery's conditions, would the system Al-Au be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于Hume-Rothery条件解释Al-Au系统是否显示无限固溶性，需要文字解释和论述，而不仅仅是简单的选择或判断。答案\"No\"只是结论部分，完整的回答需要包含解释说明。 | 知识层次: 题目要求基于Hume-Rothery规则分析Al-Au体系的固溶度问题，需要理解并应用多个条件（如原子尺寸、电负性、价电子浓度等）进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对Hume-Rothery规则进行多角度分析论述。学生需要：" + }, + { + "idx": 3779, + "question": "Based on Hume-Rothery's conditions, would the system U-W be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于Hume-Rothery规则进行解释说明，答案需要文字论述而非简单选择或判断 | 知识层次: 题目要求基于Hume-Rothery规则对U-W系统的固溶度进行分析和解释，需要综合运用多个条件（如原子尺寸、电负性、价电子浓度等）进行推理判断，涉及概念关联和机理解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求基于Hume-Rothery规则对U-W系统的固溶度进行判断和解释，需要综合运用多个材料科学原理（如原子尺寸因素、电负性、价电子浓度等）进行推理分析，并给出机理层面的解释。虽然不需要进行复杂现象的全面分析（等级5），但已超出基础概念应用的难度，属于需要深入理解并能系统阐述的题目类型。" + }, + { + "idx": 3780, + "question": "Based on Hume-Rothery's conditions, would the system Mo-Ta be expected to display unlimited solid solubility? Explain.", + "answer": "Yes", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件解释Mo-Ta系统是否显示无限固溶性，需要文字解释和论述，而不仅仅是简单的选择或判断。答案\"Yes\"只是结论部分，完整的解答需要详细说明原因。 | 知识层次: 题目要求应用Hume-Rothery规则来分析Mo-Ta系统的固溶度，需要理解并应用多个条件（原子尺寸、电负性、价电子浓度、晶体结构）进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求应用Hume-Rothery规则进行判断，但只需要对Mo-Ta系统的基本性质（如原子半径、晶体结构、电负性等）进行分析和关联，不需要进行多角度或深度关联性分析。解题步骤相对直接，属于典型的综合分析和说明类型题目。" + }, + { + "idx": 3781, + "question": "Based on Hume-Rothery's conditions, would the system Nb-W be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于Hume-Rothery条件解释Nb-W系统是否显示无限固溶性，需要文字解释和论述，而不仅仅是简单的选择或判断。答案\"No\"只是结论部分，完整的回答需要解释为什么不符合Hume-Rothery条件。 | 知识层次: 题目要求应用Hume-Rothery规则来评估Nb-W系统的固溶度，需要理解并应用多个条件（如原子尺寸、电负性、晶体结构等）进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求基于Hume-Rothery规则对Nb-W系统的固溶度进行多角度分析论述。需要综合考量原子尺寸因素、电负性差异、晶体结构匹配度等多个条件，并解释为何该系统不符合无限固溶的条件。这超出了简单概念复述（等级3）的要求，但尚未达到需要深度关联其他理论体系（等级5）的程度。" + }, + { + "idx": 3782, + "question": "Based on Hume-Rothery's conditions, would the system Mg-Zn be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery规则解释Mg-Zn系统是否具有无限固溶度，需要文字解释和论述，而不仅仅是简单的选择或判断。答案\"No\"只是结论部分，完整的回答需要包含解释说明。 | 知识层次: 题目要求基于Hume-Rothery规则分析Mg-Zn系统的固溶度，需要理解并应用多个条件（如原子尺寸、电负性、价电子浓度等）进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解Hume-Rothery规则的基本条件，并能将其应用到具体合金系统中进行分析和说明。虽然不需要多角度或深度关联性分析，但仍需进行综合判断和解释。" + }, + { + "idx": 3783, + "question": "Based on Hume-Rothery's conditions, would the system Mg-Cd be expected to display unlimited solid solubility? Explain.", + "answer": "Yes", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件进行解释说明，需要文字论述和解释，而不仅仅是选择或判断。答案\"Yes\"只是结论部分，完整的解答需要包含详细的解释过程。 | 知识层次: 题目要求应用Hume-Rothery规则分析Mg-Cd体系的固溶度问题，需要理解并应用多个条件（原子尺寸、电负性、价电子浓度、晶体结构）进行综合分析判断，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及Hume-Rothery规则的应用，但只需要对Mg-Cd系统进行基本分析，包括原子尺寸、电负性、价电子数和晶体结构等因素的综合考量。不需要进行多角度或深度关联性分析，解题步骤相对直接，属于典型的综合分析说明类题目。" + }, + { + "idx": 3784, + "question": "Suppose 1 at% of the following elements is added to copper (forming a separate alloy with each element) without exceeding the solubility limit. Which one would be expected to give the higher strength alloy? For copper: r_Cu=1.278 Å (a) Au: r=1.442, φr=+12.8% (b) Mn: r=1.12, φr=-12.4% (c) Sr: r=2.151, φr=+68.3% (d) Si: r=1.176, φr=-8.0% (e) Co: r=1.253, φr=-2.0%", + "answer": "The Cu-Sr alloy would be expected to be strongest (largest size difference).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择一个能产生更高强度合金的元素，答案明确给出了一个选项作为正确答案。 | 知识层次: 题目要求考生理解固溶强化原理，并能够根据原子半径差异（φr）判断哪种合金元素会产生更强的强化效果。这需要将基本概念（固溶强化）与给定数据（原子半径和百分比差异）结合起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合考虑原子半径差异百分比（φr）对固溶强化效果的影响，并理解尺寸差异与合金强度的关系。解题过程涉及多个概念的综合分析（固溶强化机制、原子尺寸效应、溶解度限制等），且需要比较不同元素的参数差异才能得出正确结论。虽然不需要复杂计算，但需要较强的材料科学理论基础和综合分析能力。" + }, + { + "idx": 3785, + "question": "Is any of the alloying elements expected to have unlimited solid solubility in copper? For copper: r_Cu=1.278 Å (a) Au: r=1.442, φr=+12.8% (b) Mn: r=1.12, φr=-12.4% (c) Sr: r=2.151, φr=+68.3% (d) Si: r=1.176, φr=-8.0% (e) Co: r=1.253, φr=-2.0%", + "answer": "The Cu-Au alloy satisfies Hume-Rothery's conditions and might be expected to display complete solid solubility-in fact it freezes like an isomorphous series of alloys, but a number of solid-state transformations occur at lower temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择哪个合金元素在铜中具有无限固溶度，答案也明确指出Cu-Au合金满足条件，属于选择题的特征。 | 知识层次: 题目需要应用Hume-Rothery规则（包括原子半径差、电负性、价电子浓度等）来分析合金元素的固溶度，涉及多步判断和概念关联，但不需要复杂的推理或创新思维。 | 难度: 在选择题中属于较高难度，需要综合运用Hume-Rothery规则（包括原子半径差、电负性、价电子数等条件）对多个合金元素进行逐一分析判断。解题过程涉及：" + }, + { + "idx": 3786, + "question": "Suppose 1 at% of the following elements is added to copper (forming a separate alloy with each element) without exceeding the solubility limit. Which one would be expected to give the higher strength alloy? (a) Au (b) Mn (c) Sr (d) Si (e) Co", + "answer": "(c)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择一个能够提高铜合金强度的元素，答案是从给定的选项中选择一个正确答案。 | 知识层次: 题目要求考生理解合金元素对铜强度的影响，并能够综合分析不同元素的固溶强化效果。这需要考生不仅记住各元素的基本性质，还要能够应用固溶强化的原理进行比较和分析，属于中等应用层次。 | 难度: 该题目属于需要复杂分析过程的判断题。解题时需要综合考虑多个因素：" + }, + { + "idx": 3787, + "question": "Which of these alloying elements is expected to have unlimited solid solubility in copper? (a) Au (b) Mn (c) Sr (d) Si (e) Co", + "answer": "(a)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项（a-e）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对合金元素在铜中固溶度原理的应用，需要理解Hume-Rothery规则（原子尺寸、电负性、价电子数等因素）并综合分析各选项元素的特性，属于中等应用层次的知识运用。 | 难度: 在选择题中属于较高难度，需要综合运用Hume-Rothery固溶度规则（原子尺寸因素、电负性、价电子浓度、晶体结构匹配）进行复杂分析判断。题目考察对铜基合金体系特性的深入理解，要求考生能排除干扰项（如Mn、Co等常见合金元素），识别出Au与Cu具有相同的FCC结构和相近的原子参数这一关键特征。" + }, + { + "idx": 3788, + "question": "Which of the following oxides is expected to have the largest solid solubility in \\mathrm{Al}_{2} \\mathrm{O}_{3} ?\n(a) \\mathrm{Y}_{2} \\mathrm{O}_{3} (b) \\mathrm{Cr}_{2} \\mathrm{O}_{3} (c) \\mathrm{Fe}_{2} \\mathrm{O}_{3}", + "answer": "\\mathrm{cr}_{2} \\mathrm{o}_{3} is expected to have the largest solid solubility in \\mathrm{al}_{2} \\mathrm{o}_{3}; in fact, they are completely soluble in one another.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择具有最大固溶度的氧化物，符合选择题的特征 | 知识层次: 题目需要理解氧化物在Al2O3中的固溶度原理，并分析不同氧化物的离子半径和价态匹配性，属于中等应用层次。虽然不涉及复杂计算，但需要综合分析多个因素才能得出正确结论。 | 难度: 在选择题中属于较高难度，需要综合考虑氧化物晶体结构、离子半径匹配度以及固溶度原理等多个因素。题目要求考生不仅要掌握各氧化物的基本性质，还要理解固溶度背后的晶体化学原理（如Hume-Rothery规则），并能对不同氧化物与Al2O3的相容性进行系统比较。解题过程涉及多个分析步骤：首先需要识别所有选项都是三价金属氧化物，然后比较它们与Al2O3的晶体结构匹配性（Cr2O3与Al2O3同为刚玉结构），最后还要考虑离子半径差异（Cr3+与Al3+半径最接近）。这种需要多维度综合分析的选择题，在同题型中属于较复杂的判断类题目。" + }, + { + "idx": 3789, + "question": "How many grams of nickel must be added to 500 grams of copper to produce an\nalloy that contains 50 wt% \\alpha at 1300^{\\circ} C ?", + "answer": "541.7g ni", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算需要添加的镍的质量），答案是一个具体的数值（541.7g ni），解答过程需要应用相关的材料科学公式和计算方法。 | 知识层次: 题目需要进行多步计算，涉及合金成分与相图的关系，需要理解相图的基本原理并应用相关公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括质量分数转换和合金成分计算），并综合分析给定条件下的相组成。虽然不涉及复杂多变量，但步骤较多且需要准确应用公式。" + }, + { + "idx": 3790, + "question": "How many grams of MgO must be added to 1kg of NiO to produce a ceramic that has a solidus temperature of 2200^{\\circ} C ?", + "answer": "332g of mgo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定需要添加的MgO的质量。答案是一个具体的数值（332g of mgo），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要多步计算和概念关联，涉及固相线温度与成分的关系，需要综合分析相图数据并应用相关公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（如质量分数转换、成分比例计算等），并综合应用材料科学基础知识。虽然不涉及复杂多变量，但解题步骤和概念关联要求较高，属于该题型内的中等偏上难度。" + }, + { + "idx": 3791, + "question": "We would like to produce a MgO-\\mathrm{FeO} ceramic that is 30 wt% solid at 2000^{\\circ} C. Determine the original composition of the ceramic in wt%.", + "answer": "56.9 wt% feo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定陶瓷的原始组成（wt%），需要应用相关公式和计算方法，最终给出具体的数值结果（56.9 wt% FeO）。 | 知识层次: 题目需要进行多步计算，涉及相图分析和成分计算，需要将概念关联并进行综合分析。虽然不涉及复杂的机理解释或创新设计，但比简单应用更复杂。 | 难度: 在计算题中属于综合性计算问题，需要应用相图知识、质量平衡计算和温度-成分关系分析。虽然计算步骤明确，但涉及多步推导和概念关联，需要综合分析能力。相比简单单步计算题（等级2）更复杂，但尚未达到需要处理多变量交互作用的等级4难度。" + }, + { + "idx": 3792, + "question": "A Nb-W alloy held at 2800°C is partly liquid and partly solid. If possible, determine the composition of each phase in the alloy.", + "answer": "l: 49% w; α: 70% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成，答案给出了具体的数值结果，这表明需要进行数值计算和公式应用来解决问题。 | 知识层次: 题目涉及相图的应用和两相区成分的计算，需要理解相图的基本原理并进行多步计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要运用相图知识进行多步计算和综合分析，涉及成分确定和相平衡概念的应用，但不需要处理复杂多变量情况。" + }, + { + "idx": 3794, + "question": "A Nb-W alloy contains 55% α at 2600°C. Determine the composition of each phase.", + "answer": "l: 22% w; α: 42% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定各相的组成，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相组成和成分的确定，需要综合分析相图中的信息并进行数值计算。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要运用相图知识进行多步计算，包括确定相组成和成分比例，涉及概念关联和综合分析。虽然计算步骤明确，但需要正确理解相图和应用杠杆定律，属于中等偏上的难度水平。" + }, + { + "idx": 3795, + "question": "A Nb-W alloy contains 55% α at 2600°C. Determine the original composition of the alloy.", + "answer": "33% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金的原始成分，答案是一个具体的数值（33% w），解答过程需要运用材料科学中的相图和相关计算。 | 知识层次: 题目需要进行多步计算，涉及相图分析和成分确定，需要将概念关联并进行综合分析。虽然不涉及复杂的推理或创新应用，但超出了简单公式直接套用的范畴。 | 难度: 在计算题（需要数值计算和公式应用）的中等应用层次中，该题目属于综合性计算问题。解题过程需要理解相图概念、进行多步计算（包括质量平衡和相组成分析），并关联多个知识点（如杠杆法则的应用）。虽然不涉及复杂多变量计算，但需要综合分析能力和对材料相变原理的深入理解，因此属于等级3难度。" + }, + { + "idx": 3796, + "question": "Suppose a 1200-lb bath of a Nb-40 wt % W alloy is held at 2800 degrees C. How many pounds of tungsten can be added to the bath before any solid forms?", + "answer": "212 additional pounds of W must be added before any solid forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定需要添加多少磅的钨才能避免固体形成。答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及合金成分和相图的应用，需要综合分析温度、成分和相变之间的关系，但不需要进行复杂的推理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括质量平衡和成分转换），并综合分析合金体系的相变条件。虽然涉及多个计算步骤，但尚未达到复杂多变量计算的程度。" + }, + { + "idx": 3798, + "question": "Suppose a crucible made of pure nickel is used to contain 500g of liquid copper at 1150^{\\circ} C. Describe what happens to the system as it is held at this temperature for several hours. Explain.", + "answer": "cu dissolves ni until the cu contains enough ni that it solidifies completely. when 10% ni is dissolved, freezing begins with x = 55.5 \\text{g ni}. when 18% ni is dissolved, the bath is completely solid with x = 109.8 \\text{g ni}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述和解释系统在特定条件下的变化过程，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求描述和解释在高温下镍坩埚与液态铜之间的相互作用及其随时间的变化过程，涉及溶解、固溶体形成和凝固等复杂现象。需要综合运用相图知识、溶解动力学和热力学原理进行推理分析，解释系统行为的变化机制。 | 难度: 在简答题-复杂分析题型中，该题目要求对金属溶解和凝固的复杂现象进行全面分析。需要综合运用相图知识、质量平衡计算和机理解释能力，解题步骤涉及多阶段推理和定量计算，属于该题型框架内的最高难度等级。" + }, + { + "idx": 3799, + "question": "A NiO-60 mol% MgO ceramic is allowed to solidify. Determine the composition of the first solid to form under equilibrium conditions.", + "answer": "80% mgo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定在平衡条件下形成的第一个固体的成分，需要应用相图和相关公式进行数值计算。答案以百分比形式给出，表明需要进行具体的数值计算。 | 知识层次: 题目需要理解相图的基本原理，并应用杠杆定律进行多步计算来确定固相成分，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念并进行多步计算。题目要求确定平衡条件下首晶形成的成分，涉及相图分析和杠杆定律应用，但不需要处理复杂多变量。" + }, + { + "idx": 3800, + "question": "A NiO-60 mol% MgO ceramic is allowed to solidify. Determine the composition of the last liquid to solidify under equilibrium conditions.", + "answer": "35% mgo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定在平衡条件下最后凝固的液体的成分，需要应用相图和相关公式进行数值计算，最终给出具体的百分比数值作为答案。 | 知识层次: 题目需要理解相图的基本原理，并能够进行多步计算来确定最后凝固液体的成分。这涉及到对相图的理解、平衡条件的应用以及数值计算，属于中等应用层次。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于综合性计算问题。题目要求确定NiO-MgO陶瓷在平衡凝固条件下最后凝固液体的成分，这需要理解相图概念、杠杆定律的应用以及多步计算过程。虽然不涉及复杂多变量计算，但需要将相图知识与具体计算步骤相结合，属于中等应用层次中较为综合的题目。" + }, + { + "idx": 3801, + "question": "A Nb-35% W alloy is allowed to solidify. Determine the composition of the first solid to form under equilibrium conditions.", + "answer": "55% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定在平衡条件下形成的第一个固体的成分，需要应用相图和相关公式进行计算，答案是一个具体的数值（55% w），属于计算题的特征。 | 知识层次: 题目要求根据给定的合金成分和平衡凝固条件，应用相图或杠杆定律计算初始凝固固相的成分。这属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用杠杆定律或相图的基本原理，直接计算第一个固相形成的成分，无需复杂的步骤或多公式组合。" + }, + { + "idx": 3802, + "question": "A Nb-35% W alloy is allowed to solidify. Determine the composition of the last liquid to solidify under equilibrium conditions.", + "answer": "18% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金在平衡条件下最后凝固的液体成分，需要应用相图和相关公式进行数值计算，答案是一个具体的数值（18% w）。 | 知识层次: 题目需要运用相图知识进行多步计算，涉及平衡条件下合金凝固过程中液相成分的变化分析，需要理解相图的基本原理并能够进行相关计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析合金凝固过程中的成分变化。虽然计算步骤不算极其复杂，但需要将多个概念关联起来才能正确求解。" + }, + { + "idx": 3803, + "question": "An intermetallic compound is found for 10 wt% \\mathrm{Si} in the Cu-Si phase diagram. Determine the formula for the compound.", + "answer": "\\mathrm{sicu}_{4}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据给定的条件（10 wt% Si在Cu-Si相图中）确定化合物的化学式，需要一定的分析和推理过程，答案是一个具体的化学式（SiCu4），而不是简单的选择、判断或数值计算。 | 知识层次: 题目需要根据相图信息进行多步计算和概念关联，包括理解相图的基本原理、计算原子百分比、推导化合物的化学式等，涉及中等程度的综合分析和应用能力。 | 难度: 在简答题中属于中等难度，需要理解相图的基本概念，进行质量百分比到原子百分比的转换，并推导出化合物的化学式。虽然涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3804, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the composition of the first solid to form.", + "answer": "8% Sn", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定特定合金在凝固过程中第一个固体的成分，需要基于相图和合金知识进行解释和论述，答案是一个具体的数值（8% Sn），但解答过程需要文字说明和理论支持。 | 知识层次: 题目需要理解相图的基本原理，并能够根据给定的合金成分在相图上确定初始凝固固相的成分。这涉及到对相图的理解和应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及相图和合金凝固的基本概念，但解题步骤相对直接，只需根据相图确定初始凝固相的成分。不需要多角度分析或深度关联性分析，但需要综合理解和应用相图知识。" + }, + { + "idx": 3805, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the liquidus temperature, solidus temperature, solvus temperature, and freezing range of the alloy.", + "answer": "liquidus temperature =290 c, solidus temperature =240 c, solvus temperature =170 c, freezing range =50 c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定合金的多个温度参数（liquidus temperature, solidus temperature, solvus temperature, freezing range），答案以具体数值形式给出，需要应用材料科学中的相图和相关公式进行计算。 | 知识层次: 题目要求根据给定的合金成分（Pb-15% Sn）计算液线温度、固线温度、固溶线温度和凝固范围。这些计算主要基于相图的基本理解和直接应用，不需要多步计算或复杂的概念关联。虽然需要理解相图的基本概念，但主要考察的是对相图中特定点的查找和简单计算能力。 | 难度: 在计算题中属于最低难度，仅需根据给定的合金成分直接查相图或套用已知数据即可得出所有温度参数，无需任何公式推导或多步骤计算。所有答案均可通过单一数据源（如相图）直接读取，属于典型的\"单一公式直接计算\"类型。" + }, + { + "idx": 3806, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the amounts and compositions of each phase at 260 c.", + "answer": "l: 30% sn, α: 12% sn; % l=17%, % α=83%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-15% Sn合金在260°C凝固时各相的含量和成分，答案给出了具体的数值计算结果（% l=17%, % α=83%），这需要应用相图和相关公式进行计算。 | 知识层次: 题目需要运用杠杆定律进行多步计算，涉及相图分析和成分确定，需要理解相图的基本原理并能够关联不同概念进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析各相成分和比例。虽然涉及多步骤计算，但变量关系明确，属于典型的中等应用层次问题。" + }, + { + "idx": 3807, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the amounts and compositions of each phase at 183 c.", + "answer": "α: 15% sn; 100% α", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定Pb-15% Sn合金在183°C凝固时各相的数量和组成，这需要通过相图分析和计算来确定各相的比例和成分。答案给出了具体的数值结果（α: 15% sn; 100% α），表明需要进行计算和相图应用。 | 知识层次: 题目涉及基本的相图应用和简单的成分计算，属于直接套用相图知识进行基本公式应用的范畴，不需要多步计算或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目仅要求根据给定的合金成分和温度，直接应用相图或相组成公式得出结果，无需复杂的计算步骤或多公式组合。" + }, + { + "idx": 3808, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the amounts and compositions of each phase at 25 c.", + "answer": "α: 2% pb, β: 100% sn; % α=87%, % β=13%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Pb-15% Sn合金在25°C时各相的含量和组成，答案给出了具体的数值计算结果（α: 2% pb, β: 100% sn; % α=87%, % β=13%），这表明解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目涉及基本的相图应用和简单的百分比计算，属于直接套用相图数据和基本公式的应用层次，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，需要运用杠杆定律进行简单的相组成计算，但不需要复杂的公式组合或多步骤推导。解题过程涉及基本相图知识（Pb-Sn相图）和单一公式（杠杆定律）的直接应用，属于该题型框架内的中等偏下难度。" + }, + { + "idx": 3809, + "question": "Consider a Pb-35% Sn alloy. Determine if the alloy is hypoeutectic or hypereutectic.", + "answer": "hypoeutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过分析合金成分来判断其类型（hypoeutectic或hypereutectic），需要基于相图知识进行文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对合金成分分类（hypoeutectic或hypereutectic）的基本概念记忆和理解，仅需根据给定的成分比例判断其相对于共晶点的位置，无需复杂计算或分析。 | 难度: 在简答题题型中，该题目仅要求判断合金是亚共晶还是过共晶，属于基本定义简答。题目仅涉及对共晶点成分的记忆和简单比较，不需要复杂的概念解释或体系阐述，符合等级1的基本定义简答标准。" + }, + { + "idx": 3810, + "question": "Consider a Pb-35% Sn alloy. Determine the composition of the first solid to form during solidification.", + "answer": "14% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在凝固过程中第一个固体的成分，需要应用相图和相关公式进行计算，最终给出具体的数值答案（14% Sn）。 | 知识层次: 题目需要应用相图知识进行简单的数值计算，直接套用相图数据即可得出答案，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，只需要单一公式（杠杆定律或相图直接读取）直接计算即可得出答案，无需复杂步骤或多公式组合。" + }, + { + "idx": 3811, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each phase at 184°C.", + "answer": "α: 19% sn, l: 61.9% sn, % α = 63%, % l = 37%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定各相的数量和组成，答案给出了具体的数值计算结果，解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相组成和相对量的确定，需要综合分析相图数据和运用杠杆定律进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析各相组成和比例。虽然涉及多个步骤，但变量和计算过程相对明确，没有过于复杂的多变量交互。" + }, + { + "idx": 3812, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each base at 182°C.", + "answer": "α: 19% sn, β: 97.5% sn, % α = 80%, % β = 20%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在182°C时各相的量和组成，需要使用相图和杠杆定律进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要关联多个概念并进行综合分析。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要应用相图知识进行多步计算，包括确定相组成和相对量，涉及概念关联和综合分析。虽然计算步骤明确，但需要正确理解相图并准确应用杠杆定律，属于中等偏上的难度。" + }, + { + "idx": 3813, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each microconstituent at 182°C.", + "answer": "primary α: 19% sn, % primary α = 63%, eutectic: 61.9% sn, % eutectic = 37%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在182°C时各微组成物的含量和成分，涉及数值计算和相图应用。答案给出了具体的百分比和成分，表明需要进行计算和推导。 | 知识层次: 题目需要多步计算和概念关联，包括相图的理解、杠杆定律的应用以及微组成分的确定，涉及综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括杠杆定律的应用）和综合分析各微组成分的含量与成分。虽然计算步骤较多，但变量相对明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 3814, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each phase at 25°C.", + "answer": "α: 2% sn, β: 100% sn, % α = 66%, % β = 34%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在25°C时各相的数量和组成，答案给出了具体的数值计算结果（% α = 66%, % β = 34%），这需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相组成和相对量的确定，需要综合分析合金成分和相图信息。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要应用相图知识进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析。虽然计算过程不涉及复杂多变量，但需要正确理解相图并准确应用杠杆定律，属于中等偏上的难度水平。" + }, + { + "idx": 3815, + "question": "Consider a Pb-70% Sn alloy. Determine if the alloy is hypoeutectic or hypereutectic.", + "answer": "hypereutectic", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断合金是亚共晶还是过共晶，答案是一个明确的判断结果（hypereutectic），类似于判断题中对陈述真伪的判断。 | 知识层次: 题目考查对合金成分分类的基本概念记忆，只需根据Pb-Sn相图判断给定成分位于共晶点哪一侧即可，无需复杂计算或分析。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。只需记忆Pb-Sn合金相图中70% Sn的组成位置相对于共晶点的关系即可判断，无需复杂推理或概念交叉应用。属于最基础的定义性知识考查。" + }, + { + "idx": 3816, + "question": "Consider a Pb-70% Sn alloy. Determine the composition of the first solid to form during solidification.", + "answer": "98% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在凝固过程中首先形成的固体的成分。这涉及到相图的应用和成分的计算，答案是一个具体的数值（98% Sn），需要通过相图分析和计算得出。 | 知识层次: 题目需要应用相图知识进行简单的数值计算，直接套用Pb-Sn相图数据即可得出答案，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于最简单难度，仅需直接套用相图数据（Pb-Sn相图中的液相线和固相线交点），无需复杂计算或多步骤推导，属于单一公式直接计算类型。" + }, + { + "idx": 3817, + "question": "Consider a Pb-70% Sn alloy. Determine the amounts and compositions of each phase at 184 degrees C.", + "answer": "beta: 97.5% sn, l: 61.9% sn, % beta = 22.8%, % l = 77.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在184°C时各相的数量和组成，答案给出了具体的数值计算结果（% beta = 22.8%, % l = 77.2%），这表明解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目需要运用相图知识进行多步计算，涉及相组成和相对量的确定，需要综合分析相图数据并应用杠杆定律进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括杠杆法则的应用）和综合分析成分与温度的关系。虽然涉及多个步骤，但变量和计算过程相对明确，属于中等应用层次中的典型问题。" + }, + { + "idx": 3819, + "question": "Consider a Pb-70% Sn alloy. Determine the amounts and compositions of each microconstituent at 182 degrees C.", + "answer": "primary beta: 97.5% sn, % primary beta = 22.8%, eutectic: 61.9% sn, % eutectic = 77.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在182°C时各微组成物的含量和成分，答案给出了具体的数值计算结果，涉及相图分析和杠杆定律的应用。 | 知识层次: 题目需要根据相图进行多步计算，涉及相组成和比例的确定，需要综合分析相图信息并应用杠杆定律进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括杠杆定律的应用）和综合分析成分比例。虽然不涉及复杂多变量计算，但解题步骤较为复杂，需要将多个知识点关联运用。" + }, + { + "idx": 3820, + "question": "Consider a Pb-70% Sn alloy. Determine the amounts and compositions of each phase at 25 degrees C.", + "answer": "alpha: 2% sn, beta: 100% sn, % alpha = 30%, % beta = 70%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定各相的数量和组成，涉及数值计算和相图应用，答案给出了具体的数值结果。 | 知识层次: 题目涉及基本的相图应用和简单的杠杆法则计算，属于直接套用公式和基本概念的应用层次，不需要复杂的分析或多步推理。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求确定Pb-70% Sn合金在25°C时的各相组成和含量，这需要应用杠杆法则进行计算。虽然涉及两个相（alpha和beta）的组成和相对量，但计算过程直接，只需套用杠杆法则公式，无需复杂的多步骤计算或公式组合。因此，在计算题题型内属于等级2难度。" + }, + { + "idx": 3821, + "question": "Consider an Al-4% Si alloy. Determine if the alloy is hypo eutectic or hyper eutectic.", + "answer": "hypo eutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过分析合金成分来判断其属于亚共晶还是过共晶，需要基于材料科学知识进行解释和论述，答案形式为简短的文字描述而非计算或选择。 | 知识层次: 题目考查对合金分类（hypo eutectic或hyper eutectic）的基本概念记忆和理解，仅需根据Si含量与共晶点比较即可判断，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目仅要求判断合金是亚共晶还是过共晶，属于基本定义简答。题目仅涉及基础概念记忆，无需复杂解释或论述，解题步骤简单直接，符合等级1的难度标准。" + }, + { + "idx": 3822, + "question": "Consider an Al-4% Si alloy. Determine the composition of the first solid to form during solidification.", + "answer": "1% si", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定合金凝固过程中第一个固体的成分，涉及相图和成分计算，需要应用材料科学中的相变知识进行数值计算。答案是一个具体的数值结果（1% Si），表明这是一个需要计算的题目。 | 知识层次: 题目需要应用基本的相图知识和杠杆定律进行计算，属于基本公式应用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，仅需直接应用杠杆定律或平衡相图的基本公式进行单一计算，无需多步骤推导或复杂公式组合。题目明确给出合金成分，只需查找相图中对应点的固相线成分即可得出答案。" + }, + { + "idx": 3823, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each phase at 578 degrees C.", + "answer": "alpha: 1.65% si, l: 12.6% si, % alpha=78.5%, % l=21.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定各相的含量和组成，答案给出了具体的数值结果，涉及相图的应用和计算过程。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相的成分和相对量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括成分读取、杠杆定律应用等），并综合分析各相的比例和成分。虽然涉及多个步骤，但变量关系相对明确，未达到复杂多变量计算的程度。" + }, + { + "idx": 3824, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each phase at 576 degrees C.", + "answer": "alpha: 1.65% si, beta: 99.83% si, % alpha=97.6%, % beta=2.4%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定各相的数量和组成，答案给出了具体的数值计算结果，涉及相图分析和成分计算，属于典型的计算题类型。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相组成和相对量的确定，需要综合分析合金成分和温度对相变的影响，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用相图知识进行多步计算，包括确定相组成和相对量，涉及概念关联和综合分析，但未达到复杂多变量计算的级别。" + }, + { + "idx": 3825, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each microconstituent at 576 degrees C.", + "answer": "primary alpha: 1.65% si, % primary alpha=78.5%, eutectic: 12.6% si, % eutectic=21.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Al-4% Si合金在576°C时各微组成物的含量和成分，答案给出了具体的数值计算结果，涉及相图应用和百分比计算，属于典型的计算题类型。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相组成和相对含量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用相图知识进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析，但未达到复杂多变量计算的级别。" + }, + { + "idx": 3826, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each phase at 25 degrees C.", + "answer": "alpha: 0% si, beta: 100% si, % alpha=96%, % beta=4%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定各相的含量和组成，答案给出了具体的数值计算结果（% alpha=96%, % beta=4%），属于典型的计算题特征。 | 知识层次: 题目涉及基本的相图计算和简单的百分比计算，属于直接套用相图知识和基本公式的应用层次，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用杠杆法则（lever rule）这一基本公式，通过简单的代数计算即可得出各相的含量和成分。解题步骤直接且无需组合多个公式或进行复杂推导，符合等级1的定义。" + }, + { + "idx": 3827, + "question": "Consider a Al-25% Si alloy. Determine if the alloy is hypo eutectic or hyper eutectic.", + "answer": "hyper eutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来判断合金的类型，答案形式为文字描述而非选择或计算 | 知识层次: 题目考查对合金分类（hypo eutectic或hyper eutectic）的基本概念记忆和理解，只需要根据给定的成分（Al-25% Si）与共晶点成分进行比较即可判断，不需要复杂的计算或分析。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆Al-Si合金的共晶成分（12.6% Si）并比较给定成分（25% Si）即可判断属于过共晶（hyper eutectic）。题目不涉及复杂概念体系或解释性论述，属于最基础的定义应用层级。" + }, + { + "idx": 3828, + "question": "Consider a Al-25% Si alloy. Determine the composition of the first solid to form during solidified.", + "answer": "100% si", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定合金凝固时第一个固体的成分，需要根据相图知识进行解释和论述，答案是一个具体的成分值而非计算或选择。 | 知识层次: 题目需要理解相图的基本原理，并能够应用杠杆定律进行多步计算，确定在凝固过程中首先形成的固相成分。这涉及到对相图的理解和简单计算，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解相图的基本概念，并能根据给定的合金成分确定初生相的组成。虽然题目涉及多步计算和概念关联，但解题步骤相对直接，主要考察对相图的理解和应用能力，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3829, + "question": "Consider a Al-25% Si alloy. Determine the amounts and compositions of each phase at 578 degrees C.", + "answer": "β: 99.83% si, l: 12.6% si, %l: 85.8%, %β: 14.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定合金中各相的含量和组成，答案给出了具体的数值结果，解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相的成分和相对量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括杠杆法则的应用）和综合分析成分与相比例。虽然涉及多个步骤，但计算过程相对明确，属于该题型内中等偏上的难度。" + }, + { + "idx": 3831, + "question": "Consider a Al-25% Si alloy. Determine the amounts and compositions of each microconstituent at 576 degrees C.", + "answer": "primary β: 99.83% si, % primary β: 14.2%; eutectic: 12.6% si, % eutectic: 85.8%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的含量和成分，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要运用相图知识进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于综合性计算问题。题目要求确定Al-25% Si合金在576°C时各微组成物的含量和成分，涉及多步计算和相图分析。虽然不需要处理复杂多变量，但需要理解相图、应用杠杆定律，并进行多步计算和概念关联，因此在该题型内属于中等偏上的难度。" + }, + { + "idx": 3832, + "question": "Consider a Al-25% Si alloy. Determine the amounts and compositions of each phase at 25 degrees C.", + "answer": "α: 0% si, β: 100% si, %α: 75%, %β: 25%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Al-25% Si合金在25°C时各相的含量和组成，答案给出了具体的数值计算结果（%α: 75%, %β: 25%），这需要应用相图和相关公式进行计算。 | 知识层次: 题目涉及基本的相图应用和简单的百分比计算，属于直接套用相图数据和基本公式的应用层次，不需要复杂的分析或综合。 | 难度: 在计算题中属于最简单等级，只需要直接应用杠杆法则单一公式进行计算，无需复杂推导或多步骤运算。题目给出了明确的温度(25°C)和合金成分(Al-25%Si)，可以直接从相图中读取各相成分(α相0%Si，β相100%Si)，然后套用杠杆法则公式计算相比例。整个过程仅涉及基础概念和单一公式的直接应用。" + }, + { + "idx": 3833, + "question": "A Pb-Sn alloy contains 45% alpha and 55% beta at 100C. Determine the composition of the alloy.", + "answer": "56.15% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金的成分，答案是一个具体的数值（56.15% sn），解答过程需要运用相图和相关计算。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析相组成与成分的关系。虽然不涉及复杂多变量，但解题步骤和概念关联要求较高，符合等级3的标准。" + }, + { + "idx": 3834, + "question": "Is the alloy hypoeutectic or hypereutectic?", + "answer": "hypoeutectic", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从\"hypoeutectic\"或\"hypereutectic\"两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对合金分类（亚共晶或过共晶）这一基本概念的识别和记忆，属于基础概念层面的知识。 | 难度: 在选择题中属于中等偏下难度，需要理解\"hypoeutectic\"和\"hypereutectic\"这两个概念的定义，并能根据题目给出的信息进行简单辨析。虽然不涉及复杂计算或多步骤推理，但比单纯记忆定义要稍微复杂一些。" + }, + { + "idx": 3835, + "question": "An Al-Si alloy contains 85 % α and 15 % β at 500°C. Determine the composition of the alloy.", + "answer": "15.85% Si", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金的成分，答案是一个具体的数值（15.85% Si），解答过程需要运用材料科学中的相图和相关计算。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及成分与相比例的关系，需要综合分析相图数据和公式应用。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于综合性计算问题。题目要求根据相图或相关公式，通过多步计算（如杠杆定律的应用）来确定合金成分，涉及概念关联和综合分析。虽然计算步骤不算极其复杂，但需要学生理解相图的基本原理并能正确应用相关公式，因此在该题型内属于中等偏上的难度等级。" + }, + { + "idx": 3837, + "question": "A Pb-Sn alloy contains 23% primary \\alpha and 77% eutectic microconstituent. Determine the composition of the alloy.", + "answer": "x = 52% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过计算来确定合金的成分，涉及数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，并关联相图知识综合分析合金成分，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析初生相和共晶相的组成比例。虽然不涉及复杂多变量，但解题步骤和概念关联要求较高，属于该题型内的中等偏上难度。" + }, + { + "idx": 3838, + "question": "An Al-Si alloy contains 15% primary \\beta and 85% eutectic microconstituent. Determine the composition of the alloy.", + "answer": "25.71% si", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金的成分，答案是一个具体的数值（25.71% si），解答过程需要运用材料科学中的相图知识和计算方法。 | 知识层次: 题目需要进行多步计算，涉及相图分析和成分计算，需要理解合金相组成与成分之间的关系，并应用杠杆定律进行计算。虽然不涉及复杂的推理分析或机理解释，但需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算（包括杠杆定律应用和成分推导），并综合分析相组成与整体成分的关系。虽然不涉及复杂变量，但步骤间的逻辑衔接和计算精度要求较高。" + }, + { + "idx": 3839, + "question": "Observation of a microstructure shows that there is 28% eutectic and 72% primary β in an Al-Li alloy. Determine the composition of the alloy and whether it is hypoeutectic or hypereutectic.", + "answer": "17.46% li, hypereutectic", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金的成分（17.46% Li）并判断其是亚共晶还是过共晶（hypereutectic），需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用杠杆定律进行多步计算，并关联相图知识判断合金成分和类型，涉及概念关联和综合分析。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要应用杠杆定律进行多步计算，同时需要理解共晶反应和初生相的概念，并综合分析计算结果来判断合金属于亚共晶还是过共晶。虽然计算过程不涉及复杂多变量，但需要将多个概念和计算步骤有机结合，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 3840, + "question": "Observation of a microstructure shows that there is 28% eutectic and 72% primary β in an Al-Li alloy. How much α and β are in the eutectic microconstituent?", + "answer": "% α_est = 64% and % β_est = 36%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定α和β在共晶微结构中的百分比，答案以具体数值形式给出，需要基于材料科学中的相图和相关计算知识进行解答。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分比例计算，需要理解共晶反应和相组成的概念，并进行综合分析。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要理解相图概念，进行多步计算（包括计算共晶组成和初生相比例），并综合分析相组成。虽然不涉及复杂多变量计算，但需要将多个概念关联应用，属于中等偏上的难度水平。" + }, + { + "idx": 3841, + "question": "Calculate the total amount of alpha and beta in a Pb-50% Sn alloy at 182°C.", + "answer": "total amount of alpha = 60.5%, beta = 39.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算得出alpha和beta相的具体百分比含量，需要使用相图或相关公式进行计算，答案以具体数值形式呈现。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及杠杆定律的应用和相组成的综合分析，需要理解相图的基本原理并能够进行关联计算，属于中等应用层次。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要运用相图知识确定相组成，进行杠杆定律计算，涉及多步计算和概念关联。虽然计算过程明确，但需要综合分析合金成分和温度条件，属于中等偏上的难度。" + }, + { + "idx": 3842, + "question": "Calculate the amount of each microconstituent in a Pb-50% Sn alloy at 182°C.", + "answer": "microconstituents: primary alpha = 27.7%, eutectic = 72.3%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算Pb-50% Sn合金在182°C时各微组成物的含量，需要通过相图或相关公式进行数值计算，最终给出具体的百分比结果。答案也是以数值形式呈现的。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及微组成分的百分比计算，需要理解相图的基本原理并正确应用杠杆定律，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析不同微成分的比例关系。虽然计算过程明确，但需要将多个知识点关联运用，属于中等偏上的难度。" + }, + { + "idx": 3843, + "question": "What fraction of the total alpha in the alloy is contained in the eutectic microconstituent?", + "answer": "fraction of total alpha in the eutectic microconstituent f = 0.54.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算合金中共晶微结构中α相所占的比例，答案给出了具体的数值计算结果（f = 0.54），这表明需要通过数值计算和公式应用来解答。 | 知识层次: 题目涉及多步计算和概念关联，需要理解合金中相的组成和分布，并应用杠杆定律等原理进行综合分析。虽然计算过程相对直接，但需要对材料科学中的相图和微观组织有较深的理解。 | 难度: 在计算题中属于综合性计算问题，需要理解合金相图的概念，应用杠杆定律进行多步计算，并综合分析各相的比例关系。虽然计算步骤明确，但需要将多个概念关联起来才能正确求解，因此在该题型内属于中等偏上的难度。" + }, + { + "idx": 3844, + "question": "Recommend an artificial age-hardening heat treatment for a Cu-1.2% Be alloy (see Figure 12-34). Include appropriate temperatures.", + "answer": "For the Cu-1.2% Be alloy, solution treat between 530°C and 870°C (typical at 780°C), quench, and age below 530°C (typical at 330°C).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推荐一个具体的热处理工艺，并包括适当的温度参数，这需要文字解释和论述，而不是从选项中选择或简单的对错判断。答案提供了详细的处理步骤和温度范围，符合简答题的特点。 | 知识层次: 题目要求根据相图推荐具体的热处理工艺参数（包括温度范围），需要理解Cu-Be合金的时效硬化原理，并能将相图信息转化为实际操作参数。这涉及多步思考（固溶处理+淬火+时效）和概念关联（相图解读与热处理工艺的对应关系），但不需要复杂的机理分析或创新设计。 | 难度: 在简答题中属于中等难度，需要理解Cu-Be合金的时效硬化原理，并能够根据相图选择合适的固溶处理和时效温度。虽然涉及多步操作和温度选择，但不需要深入分析微观机制或多角度论述，属于典型的综合分析说明类题目。" + }, + { + "idx": 3845, + "question": "Compare the amount of the γ2 precipitate that forms by artificial aging at 400°C with the amount of the precipitate that forms by natural aging for a Cu-1.2% Be alloy.", + "answer": "The amount of γ2 precipitate at 400°C is 5.4%, and at room temperature, it is 8.5%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种不同条件下沉淀物的形成量，并给出了具体的数值结果。虽然答案包含了具体数据，但问题的核心在于对不同条件下沉淀物形成的比较和解释，这需要一定的文字描述和论述，而不仅仅是简单的计算或选择。因此，这属于简答题类型。 | 知识层次: 题目要求比较两种不同时效条件下γ2析出相的含量，涉及对时效处理温度与析出相形成关系的理解，以及具体数据的应用和分析。虽然不涉及复杂的机理或创新设计，但需要综合理解时效处理对合金析出行为的影响，并进行简单的数据比较和分析。 | 难度: 在简答题中属于中等难度，需要理解γ2沉淀的形成机制，并进行多步计算和综合分析。题目要求比较不同温度下的沉淀量，涉及概念关联和计算，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3846, + "question": "For an Fe-0.35% C alloy, determine the temperature at which austenite first begins to transform on cooling.", + "answer": "795°C", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定特定合金在冷却过程中奥氏体开始转变的温度，这需要参考铁碳相图或相关相变温度的计算公式，属于需要数值计算和公式应用的题目。答案是一个具体的温度数值（795°C），表明需要通过计算或查表得出结果。 | 知识层次: 题目要求根据给定的合金成分（Fe-0.35% C）和铁碳相图，确定奥氏体开始转变的温度。这主要涉及直接查阅相图或应用相关公式进行计算，属于基本公式应用和简单计算的范畴，不需要多步计算或复杂分析。 | 难度: 在计算题-简单应用题型中，此题属于单一公式直接计算的难度等级。题目仅需根据Fe-C相图直接查找0.35%C对应的A3线温度（795°C），不需要任何公式推导或多步骤计算，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 3847, + "question": "For an Fe-0.35% C alloy, determine the primary microconstituent that forms.", + "answer": "primary α-ferrite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定合金的主要微观组成，答案需要给出具体的相名称（primary α-ferrite），属于需要特定知识回答的简答题形式 | 知识层次: 题目要求根据给定的合金成分（Fe-0.35% C）直接应用铁碳相图知识来判断主要微观组成物（primary α-ferrite），属于对基础知识的直接应用，不需要复杂的分析或多步推理。 | 难度: 在简答题中属于简单应用过程描述难度，只需要根据给定的合金成分直接套用铁碳相图知识即可得出答案，无需复杂的解释或计算步骤。" + }, + { + "idx": 3848, + "question": "For an Fe-0.35% C alloy, determine the composition and amount of each phase present at 728°C.", + "answer": "α: 0.0218% C, 56.1% γ: 0.77% C, 43.9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，涉及数值计算和相图应用 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分转换，需要理解铁碳相图中各相区的含义并正确应用相关公式，属于中等难度的应用题型。 | 难度: 在计算题-需要数值计算和公式应用的中等应用层次中，该题目属于综合性计算问题。需要学生掌握铁碳相图的基本知识，能够正确识别728°C时的相组成，并运用杠杆定律进行多步计算。虽然计算过程相对明确，但需要综合运用多个概念和计算步骤，因此在该题型内属于中等偏上难度。" + }, + { + "idx": 3849, + "question": "For an Fe-0.35% C alloy, determine the composition and amount of each phase present at 726°C.", + "answer": "α: 0.0218% C, 93.3% Fe3C: 6.67% C, 4.9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要应用相图和相关公式进行计算，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图进行多步计算，包括确定相组成和相对量，涉及杠杆法则的应用和相图分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆法则进行多步计算，并理解相图中各相的概念及其相互关系。虽然计算步骤较多，但变量相对固定，不涉及复杂多变量计算。" + }, + { + "idx": 3850, + "question": "For an Fe-0.35% C alloy, determine the composition and amount of each microconstituent present at 726°C.", + "answer": "primary α: 0.0218% C, 56.1% pearlite: 0.77% C, 43.9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的成分和含量，需要应用相图和相关公式进行计算，答案以具体数值形式呈现。 | 知识层次: 题目需要应用铁碳相图进行多步计算，涉及相组成和相对量的确定，需要综合分析相图中不同区域的组成关系，并运用杠杆定律进行计算。这超出了简单应用的范围，但尚未达到需要复杂分析或创新设计的程度。 | 难度: 在计算题中属于综合性计算问题，需要应用相图知识进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析，但未达到复杂多变量计算的级别。" + }, + { + "idx": 3851, + "question": "For an Fe-1.15% C alloy, determine the temperature at which austenite first begins to transform on cooling.", + "answer": "880 degrees c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定特定合金在冷却过程中奥氏体开始转变的温度，这需要参考铁碳相图或相关计算公式来确定具体数值。答案是一个具体的温度值（880°C），表明需要通过计算或查表得出结果。 | 知识层次: 题目要求根据给定的合金成分（Fe-1.15% C）确定奥氏体开始转变的温度，这主要涉及铁碳相图的基本应用和简单查找。虽然需要理解相图的基本概念，但主要任务是直接应用相图中的信息或基本公式来确定温度，不需要多步计算或复杂的综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要根据Fe-C相图直接查找对应碳含量的合金在冷却时奥氏体开始转变的温度，无需复杂计算或多公式组合应用。" + }, + { + "idx": 3852, + "question": "For an Fe-1.15% C alloy, determine the primary microconstituent that forms.", + "answer": "primary Fe3C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定合金中的主要微观组成物，答案需要文字描述（primary Fe3C），而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查对Fe-C合金相图中基本概念的记忆和理解，特别是对特定成分合金在冷却过程中形成的初生相（primary microconstituent）的识别。这属于基础概念记忆范畴，不需要复杂的分析或计算。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求识别并写出特定合金（Fe-1.15% C）的主要微观组成相（primary Fe3C），不需要进行概念解释或复杂体系阐述。这属于最基础的概念记忆层次，符合等级1的标准。" + }, + { + "idx": 3853, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each phase present at 728 degrees C.", + "answer": "Fe3C: 6.67% C, 6.4%; gamma: 0.77% C, 93.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要应用相图和相关公式进行数值计算，答案以具体数值形式给出。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要理解相图的基本原理并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用相图知识进行多步计算和概念关联。题目要求确定特定温度下合金中各相的成分和含量，涉及杠杆定律的应用和相图解读，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3854, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each phase present at 720 degrees C.", + "answer": "alpha: 0.0218% C, 83%; Fe3C: 6.67% C, 17%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要使用相图和杠杆定律进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图进行多步计算，包括确定相组成和相对量，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要运用杠杆定律进行多步计算，涉及相图解读和成分转换，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3855, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each microconstituent present at 726 degrees C.", + "answer": "primary Fe3C: 6.67% C, 6.4%; pearlite: 0.77% C, 93.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的成分和含量，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定合金在特定温度下的相组成和各相的相对含量，涉及杠杆定律的应用和相变点的判断，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆定律进行多步计算，涉及相图分析和成分转换，但不需要处理复杂多变量。" + }, + { + "idx": 3856, + "question": "A steel contains 8 % cementite and 92 % ferrite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 0.53 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算来估计钢中的碳含量，涉及数值计算和公式应用（如杠杆定律），答案是一个具体的数值结果（0.53% c）。 | 知识层次: 题目需要应用基本的杠杆法则（lever rule）来计算钢中的碳含量，属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用杠杆定律（lever rule）来计算钢中的碳含量，步骤简单直接，无需多个公式组合或复杂推导。" + }, + { + "idx": 3857, + "question": "Is the steel hypoeutectoid or hypereutectoid?", + "answer": "the steel is hypoeutectoid.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断钢是亚共析钢还是过共析钢，属于二元判断类型，答案只需给出正确结论即可 | 知识层次: 题目考查对钢的分类（亚共析钢或过共析钢）这一基本概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。只需要记忆钢的共析分类定义（亚共析钢和过共析钢的区别）即可作答，不涉及概念理解或复杂分析。属于该题型内最基础的难度等级。" + }, + { + "idx": 3858, + "question": "A steel contains 18 % cementite and 82 % ferrite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 1.20 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计钢的碳含量，涉及数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图知识点的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于多步骤计算过程难度。题目需要应用杠杆法则（lever rule）来计算钢中的碳含量，涉及对铁碳相图的理解和基本公式的应用。虽然需要多步计算，但步骤相对明确，不涉及复杂变量或高级综合分析，属于该题型内的中等偏低难度。" + }, + { + "idx": 3860, + "question": "A steel contains 18 % pearlite and 82 % primary ferrite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 0.156 %c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计钢的碳含量，答案是一个具体的数值结果（0.156 %c），这需要应用相关的材料科学公式和计算方法。 | 知识层次: 题目需要应用铁碳相图和相关公式进行多步计算，涉及相组成与碳含量的关联分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解铁碳相图、杠杆定律的应用，并进行多步计算来估计碳含量。虽然计算步骤明确，但需要综合运用多个概念和公式，属于中等应用层次中的较高难度。" + }, + { + "idx": 3862, + "question": "A steel contains 94 % pearlite and 6 % primary cementite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 1.124 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计钢的碳含量，答案是一个具体的数值（1.124 % c），需要使用公式和数值计算来解答。 | 知识层次: 题目需要应用杠杆定律（lever rule）进行多步计算，涉及相图中珠光体和初生渗碳体的比例关系，需要理解相图的基本原理并进行综合分析。虽然计算过程不复杂，但需要关联多个概念并进行适当的数值推导。 | 难度: 在计算题中属于综合性计算问题，需要理解珠光体和初生渗碳体的比例关系，并应用杠杆定律进行多步计算。虽然计算步骤明确，但需要将多个概念关联起来综合分析，属于中等应用层次的计算题。" + }, + { + "idx": 3864, + "question": "A steel contains 55% \\alpha and 45% \\gamma at 750^{\\circ} C. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 0.281% C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计钢的碳含量，答案是一个具体的数值结果（0.281% C），这表明需要进行数值计算和公式应用。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的相比例和温度来估算碳含量，涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、进行多步计算和综合分析，但不需要处理复杂多变量。" + }, + { + "idx": 3865, + "question": "A steel contains 96% \\gamma and 4% \\mathrm{Fe}_{3} C at 800^{\\circ} C. Estimate the carbon content of the steel.\n\\[\n\\begin{array}{l}\n\\text {", + "answer": "the carbon content of the steel is 1.15% C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计钢的碳含量，涉及数值计算和公式应用，答案以具体数值形式给出。 | 知识层次: 题目需要进行多步计算，涉及相图的应用和碳含量的估算，需要理解相图的基本原理并进行综合分析。虽然计算过程相对直接，但需要关联多个概念和步骤，属于中等应用层次。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要应用杠杆定律（Lever Rule）进行多步计算，涉及相图知识点的关联和综合分析。虽然计算步骤明确，但要求对相图概念有较深理解，并正确关联各相成分。相较于简单单步计算（等级2），该题目需要更多概念整合和计算准确性，但未达到复杂多变量计算（等级4）的难度水平。" + }, + { + "idx": 3866, + "question": "A steel is heated until 40% austenite, with a carbon content of 0.5%, forms. Estimate the temperature.", + "answer": "the temperature is about 760 degrees c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计温度，涉及数值计算和材料科学中的相变知识。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的奥氏体比例和碳含量来估算温度。这涉及到多步计算和概念关联，需要综合分析相图中的相关区域和温度范围，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、碳含量与温度的关系，并进行多步计算和综合分析。虽然计算步骤不算极其复杂，但需要将多个知识点关联应用，属于中等偏上的难度。" + }, + { + "idx": 3867, + "question": "A steel is heated until 40% austenite, with a carbon content of 0.5%, forms. Estimate the overall carbon content of the steel.", + "answer": "the overall carbon content of the steel is 0.212% c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计钢的总体碳含量，答案是一个具体的数值结果，解答过程需要应用材料科学中的相关公式和计算步骤。 | 知识层次: 题目需要进行多步计算（计算奥氏体中的碳含量和整体碳含量的关系），并需要理解相图中碳含量的分配原理，属于中等应用层次。 | 难度: 在计算题题型中，该题目属于综合性计算问题。需要理解奥氏体形成比例与碳含量的关系，并应用杠杆定律进行多步计算。虽然计算过程相对直接，但需要将材料科学概念与数学计算相结合，属于中等应用层次中的典型题目。相比简单的单步计算（等级2），该题需要更多的概念关联和综合分析能力，但尚未达到复杂多变量计算（等级4）的程度。" + }, + { + "idx": 3868, + "question": "An isothermally transformed eutectoid steel is found to have a yield strength of 410 MPa. Estimate the transformation temperature.", + "answer": "transformation temperature =615 C", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计转变温度，答案是一个具体的数值结果（615 C），这表明需要进行计算推导而非选择或判断。 | 知识层次: 题目需要应用材料科学中的相变温度与力学性能关系知识，通过已知的屈服强度估算转变温度。这涉及多步计算和概念关联，需要综合分析材料的相变行为与力学性能之间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相变温度与材料性能的关系，并应用相关公式进行多步计算。虽然不涉及复杂多变量，但需要综合分析材料科学中的关键概念和参数。" + }, + { + "idx": 3869, + "question": "An isothermally transformed eutectoid steel is found to have a yield strength of 410 MPa. Estimate the interlamellar spacing in the pearlite.", + "answer": "1 / lambda=60,000 or lambda=1.67 × 10^-5 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计珠光体的层间距，答案给出了具体的数值计算结果（1 / lambda=60,000 or lambda=1.67 × 10^-5 cm），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用材料科学中的基本公式（如Hall-Petch关系或类似的强度与微观结构关系）进行多步计算，涉及对珠光体层间距与屈服强度之间关系的理解。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算步骤，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解珠光体片层间距与屈服强度的关系公式，并进行多步计算和单位转换。虽然计算过程不涉及复杂变量，但需要将理论知识与实际数值计算相结合，属于中等偏上的难度。" + }, + { + "idx": 3870, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 38", + "answer": "600 degrees C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定转变温度和微观组成，需要解释和论述如何根据硬度值HRC 38来确定这些参数，而不仅仅是选择一个选项或进行简单的计算。答案的形式也表明需要更详细的解释。 | 知识层次: 题目要求根据硬度值确定转变温度和显微组织，需要理解共析钢的相变行为、硬度与组织的关系，并进行综合分析。这涉及多步推理和概念关联，但不需要复杂的机理分析或创新设计。 | 难度: 在简答题中属于中等难度，需要理解相变温度与硬度的关系，并进行多步计算和综合分析。题目要求确定特定硬度下的转变温度和微观组织，涉及对相图的理解和硬度与组织关系的应用，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3871, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 42", + "answer": "400 degrees C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定转变温度和微观组织，需要文字解释和论述，答案形式为具体数值但需要结合材料科学知识进行解释。 | 知识层次: 题目要求根据硬度值确定共析钢的转变温度和显微组织，这需要理解相变温度与硬度之间的关系，并能够将硬度值对应到特定的转变温度范围。这涉及到多步推理和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合运用相变温度、硬度与微观组织的关系等知识，并进行多步计算和概念关联分析。虽然涉及多个知识点，但解题路径相对明确，不需要多角度或深度关联性分析。" + }, + { + "idx": 3872, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 48", + "answer": "340 degrees C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定转变温度和微观组织，需要文字解释和论述，答案形式为具体数值而非选项或简单判断 | 知识层次: 题目要求根据硬度值确定转变温度和显微组织，需要综合运用相变温度与硬度关系的知识，进行多步分析和判断，涉及概念关联和综合分析。 | 难度: 在简答题中属于较高难度，需要综合运用相变温度、硬度与微观组织的关系等知识，通过多步计算和概念关联才能得出正确答案。题目要求不仅确定温度，还需说明对应的微观组织，涉及深度分析和论述。" + }, + { + "idx": 3874, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 800^{\\circ} C for 1h, quenched to 350^{\\circ} C and held for 750s, and finally quenched to room temperature.", + "answer": "HRC =47 and the microstructure is all baninite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，需要文字解释和论述，而不是选择、判断或计算。答案提供了具体的硬度和微观结构描述，符合简答题的特征。 | 知识层次: 题目要求描述特定热处理条件下钢的硬度和显微组织，涉及对钢的热处理过程、相变行为以及显微组织与性能关系的理解。需要综合运用热处理知识、相变原理和显微组织分析能力，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求描述共析钢经过多步热处理后的硬度和显微组织，涉及加热、等温淬火和最终淬火等多个步骤的综合分析。需要考生理解并关联奥氏体化、贝氏体转变等概念，并能准确预测最终组织和性能。虽然不涉及最复杂的深度关联性分析，但解题步骤和概念关联的复杂度较高，属于中等应用知识层次中的较高难度。" + }, + { + "idx": 3875, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 700^{\\circ} C, quenched to 650^{\\circ} C and held for 500s, and finally quenched to room temperature.", + "answer": "HRC =25 and the microstructure is all pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求描述特定热处理条件下共析钢的硬度和显微组织，涉及对相变过程的理解和热处理工艺对材料性能的影响。需要综合运用相图知识、CCT/TTT曲线以及相变产物的识别能力，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解热处理过程中的相变行为，并综合分析温度、时间和冷却速率对钢的硬度和微观结构的影响。题目涉及多步计算和概念关联，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 3876, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 300^{\\circ} C, quenched to 300^{\\circ} C and held for 10s, and finally quenched to room temperature.", + "answer": "HRC=66 and the microstructure is all martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求理解并应用钢的热处理过程对硬度和微观结构的影响，涉及多步热处理工艺（加热、淬火、保温、再淬火）与最终组织（马氏体）和性能（硬度）的关联。需要综合分析不同温度下的相变行为，但不需要深入机理或创新设计。 | 难度: 在简答题中属于较高难度，需要综合运用相变动力学和TTT图知识，分析多步热处理工艺对显微组织和硬度的影响，并准确描述最终产物。解题步骤涉及加热、等温保持和淬火三个关键阶段的相变过程判断，且需要关联马氏体转变的临界条件。" + }, + { + "idx": 3877, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 1000^{\\circ} C, quenched to 3010^{\\circ} C and held for 10 s, quenched to room temperature, and then reheated to 400^{\\circ} C before finally cooling to room temperature again.", + "answer": "HRC=42 and the microstructure is all tempered martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及多个热处理步骤和相变过程，需要综合运用材料科学知识来分析钢的微观结构和硬度变化。解答需要理解加热、淬火、回火等工艺对钢的组织和性能的影响，并进行推理分析。此外，题目还要求解释最终的组织和硬度，这需要对马氏体回火过程有深入的理解。因此，该题目属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用相变原理、热处理工艺参数与显微组织演变的关联性，涉及多阶段相变路径分析（奥氏体化→淬火→等温转变→回火）。解题需要精确推导非平衡组织转变序列（如马氏体形成条件、回火马氏体转变机理），并定量关联硬度与组织特征。其复杂程度显著高于单一步骤热处理分析（等级4），属于需要完整热力学/动力学知识体系整合的典型难题。" + }, + { + "idx": 3878, + "question": "Describe the complete heat treatment required to produce a quenched and tempered eutectoid steel having a tensile strength of at least 125,000 psi. Include appropriate temperatures.", + "answer": "Austenitize at approximately 750^{\\circ} C,\nQuench to below 130^{\\circ} C (the M_{\\gamma} temperature)\nTemper at 620^{\\circ} C or less.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述完整的热处理过程，包括适当的温度，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求描述完整的热处理工艺，包括具体的温度参数，需要综合运用材料科学中的相变知识、热处理原理和材料性能之间的关系。虽然涉及基础概念，但需要将多个知识点关联起来，进行多步分析和应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅需要掌握热处理的基本步骤（如奥氏体化、淬火、回火），还需要具体说明温度范围，并关联到材料的性能要求（抗拉强度至少125,000 psi）。这涉及到多步操作的综合分析，以及对材料科学中相变和性能关系的深入理解。虽然不需要极复杂的推导或创新性解决方案，但要求考生能够将理论知识与实际工艺参数紧密结合，属于多角度分析论述的难度等级。" + }, + { + "idx": 3879, + "question": "What is the austenitizing temperature required to produce a quenched and tempered eutectoid steel with a HRC hardness of less than 50?", + "answer": "Austenitize at approximately 75 degrees Celsius.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释并给出具体的温度值作为答案，而不是从选项中选择或进行判断，也不需要复杂的计算过程。 | 知识层次: 题目需要理解奥氏体化温度与钢的硬度的关系，并应用热处理知识进行综合分析，涉及多步推理和概念关联，但不需要复杂的机理分析或创新设计。 | 难度: 在简答题中属于较高难度，需要综合运用材料科学知识，包括理解钢的热处理工艺、相变温度、硬度与热处理参数的关系等。题目要求考生不仅知道奥氏体化温度的概念，还需要能够关联具体钢种（共析钢）的热处理参数与最终性能（HRC硬度）的关系，并进行多步分析和论述。此外，题目还隐含了对回火工艺的理解，因为单纯淬火后的共析钢硬度通常高于50HRC，要达到低于50HRC的硬度必须进行回火处理。这种需要将多个概念和工艺步骤关联起来的综合分析要求，在简答题中属于较高难度。" + }, + { + "idx": 3880, + "question": "What is the quenching temperature required to produce a quenched and tempered eutectoid steel with a HRC hardness of less than 50?", + "answer": "Quench to below the M_gamma (less than 130 degrees Celsius).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释淬火温度的具体要求，答案提供了具体的温度范围（低于130摄氏度）和条件（低于M_gamma），属于需要文字解释和论述的简答题形式。 | 知识层次: 题目需要理解淬火温度与钢的硬度和组织转变之间的关系，涉及M_gamma温度的概念，并需要综合分析这些因素来确定合适的淬火温度。这超出了简单记忆或直接应用的范围，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求考生不仅掌握淬火温度和硬度之间的关系，还需要理解马氏体转变温度（M_gamma）的概念，并能综合分析这些知识来解答问题。题目涉及多步概念关联和综合分析，属于中等应用层次中的较高难度，需要考生进行多角度分析论述。" + }, + { + "idx": 3881, + "question": "What is the tempering temperature range required to produce a quenched and tempered eutectoid steel with a HRC hardness of less than 50?", + "answer": "Temper at a temperature higher than 330 degrees Celsius, but less than 727 degrees Celsius.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述具体的回火温度范围，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目需要理解回火温度与硬度之间的关系，并综合应用相图知识和硬度标准进行判断，属于多步分析和概念关联的中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求考生不仅掌握回火温度对硬度影响的基本概念，还需要综合分析共析钢的相变温度（727°C）和硬度控制下限（HRC<50）之间的关系。解题过程涉及：" + }, + { + "idx": 3882, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of a material property? (a) Density (b) Annealing (c) Forging (d) Single-crystal (e) Crystalline", + "answer": "(a) Density", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对材料性能基本概念的记忆和理解，仅需识别出密度是材料性能的典型例子，属于基础概念记忆范畴。 | 难度: 在选择题中属于简单难度，仅需识别材料属性的基本概念（如密度），无需复杂辨析或深度理解其他选项（如加工工艺或结构特征）。" + }, + { + "idx": 3883, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of material processing?(a) Extrusion(b) Crystalline(c) Amorphous(d) Glassy (e) Elastic Modulus", + "answer": "(a)Extrusion", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料加工处理基本概念的识别和记忆，只需从选项中选出与材料加工直接相关的术语，无需深入分析或综合应用。 | 难度: 在选择题中属于简单难度，题目直接考察对\"material processing\"这一基础概念的识别和记忆，只需从选项中选出最符合定义的答案，无需复杂辨析或深度理解。" + }, + { + "idx": 3884, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of material structure? (a) Single-phase (b) Elastic Modulus (c) Sintering (d) Magnetic Permeability (e) Brittle", + "answer": "(a)Single-phase", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料结构这一基础概念的记忆和理解，要求从选项中识别出最能代表材料结构的例子，属于基础概念记忆范畴。 | 难度: 在选择题中属于简单难度，仅需识别材料结构的基本概念（单相），无需深入理解或辨析其他选项。其他选项涉及性能（b,d,e）或加工（c），与题目要求的\"结构\"直接关联性低，属于基础概念记忆层次。" + }, + { + "idx": 3885, + "question": "Which class of material is generally associated with the highest density values at room temperature? (a) Composites (b) Ceramics (c) Metals (d) Polymers", + "answer": "(c) Metals", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择最符合题意的答案，属于典型的选择题形式 | 知识层次: 题目考查对不同类别材料基本性质（密度）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于最简单难度，仅需直接回忆材料科学中最基础的密度知识（金属通常密度最高），无需任何概念辨析或推理过程。这是最基础的概念记忆型题目。" + }, + { + "idx": 3886, + "question": "By how many orders of magnitude (powers of ten, approximately) does density vary for metals? (a) 0.13 (b) 1.3 (c) 13 (d) 130", + "answer": "(b)1.3", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a）0.13、（b）1.3、（c）13、（d）130中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对金属密度变化范围的基础概念记忆，只需要知道金属密度的数量级变化即可回答，不涉及复杂计算或综合分析。 | 难度: 在选择题中属于中等偏下难度，需要理解金属密度的基本概念和数量级范围，并进行简单的数量级比较。虽然不需要复杂的计算或深度分析，但需要对金属密度变化范围有基本的记忆和理解。" + }, + { + "idx": 3887, + "question": "The atomic mass of an atom may be expressed as the sum of the masses of (a) Electrons (b) Neutrons (c) Protons (d) Choose all that apply.", + "answer": "(b) Neutrons and (c) Protons", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，并且答案明确指出了正确的选项组合(b)和(c)。 | 知识层次: 题目考查原子质量的基本概念，即原子质量主要由质子和中子的质量决定，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解原子质量的基本构成（质子和中子），并排除电子这一干扰选项。虽然涉及基本概念记忆，但需要简单的概念辨析能力。" + }, + { + "idx": 3888, + "question": "The nucleus of an atom contains electrons?", + "answer": "No, the nucleus of an atom does not contain electrons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案直接给出了判断结果（No）并解释了原因 | 知识层次: 题目考查原子结构的基本概念记忆，只需要知道原子核由质子和中子组成而不包含电子这一基础知识即可作答，不涉及任何应用或分析过程。 | 难度: 在判断题题型中，该题目属于最基本的概念正误判断。仅需记忆原子核的基本组成（质子和中子）即可判断\"原子核含有电子\"这一陈述是错误的，不涉及概念理解或复杂推理过程。这是判断题中最基础的知识点考察，符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 3889, + "question": "The nucleus of an atom contains neutrons?", + "answer": "Yes, the nucleus of an atom contains neutrons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个简单的陈述句，要求判断其正确性（Yes/No），符合判断题的特征 | 知识层次: 题目考查原子核基本组成的记忆性知识，属于基础概念层次 | 难度: 在判断题题型中，该题目属于最基本的概念正误判断。仅需记忆原子核的基本组成（包含中子）这一基础知识点即可作答，无需理解或分析复杂概念，解题步骤极为简单。在同题型框架内，这是最基础的难度等级。" + }, + { + "idx": 3890, + "question": "The nucleus of an atom contains protons?", + "answer": "Yes, the nucleus of an atom contains protons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个简单的陈述句，要求判断其正确性（\"Yes\"表示正确），符合判断题的特征。 | 知识层次: 题目考查原子核组成的基本概念记忆，仅需知道原子核包含质子这一基础事实即可回答，无需应用或分析。 | 难度: 在判断题题型中，该题目属于最基本的概念正误判断，仅需记忆原子核的基本组成即可作答，无需理解或分析复杂概念。" + }, + { + "idx": 3891, + "question": "The atomic number of an electrically neutral atom is equal to the number of:(a) protons (b) electrons (c) neutrons (d)Choose all that apply.", + "answer": "(b)electrons.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，并且提供了明确的选项(a)-(d)供选择 | 知识层次: 题目考查原子序数与电子数关系的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题中属于简单难度，仅需直接记忆原子数与电子数的关系，无需复杂辨析或深度理解。" + }, + { + "idx": 3892, + "question": "Hafnium has six naturally occurring isotopes: 0.16% of { }^{174} Hf, with an atomic weight of 173.940 amu; 5.26% of { }^{176} Hf, with an atomic weight of 175.941 amu ; 18.60% of { }^{177} Hf, with an atomic weight of 176.943 amu ; 27.28% of { }^{178} Hf, with an atomic weight of 177.944 amu ; 13.62% of { }^{179} Hf, with an atomic weight of 178.946 amu;. and 35.08% of { }^{180} Hf, with an atomic weight of 179.947 amu. Calculate the average atomic weight of Hf. Give your answer to three decimal places.", + "answer": "the average atomic weight of hf is 178.485 amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（各同位素的原子质量与其丰度的加权平均）来求解铪的平均原子量，且答案以具体数值形式给出（178.485 amu），符合计算题的特征。 | 知识层次: 题目要求计算铪的平均原子量，涉及基本公式应用（加权平均计算）和简单数值计算，无需多步推理或综合分析，属于直接套用基础知识的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目要求计算铪的平均原子量，只需要应用加权平均的公式，将各同位素的原子量乘以其自然丰度后相加即可。解题步骤简单明确，无需多个公式组合或复杂计算，属于基本公式应用和直接套用的范畴。" + }, + { + "idx": 3893, + "question": "Bromium has two naturally occurring isotopes: { }^{79} Br, with an atomic weight of 78.918 amu, and { }^{81} Br, with an atomic weight of 80.916 amu. If the average atomic weight for Br is 79.903 amu, calculate the fraction-of-occurrences of these two isotopes.Give your answer to three decimal places.", + "answer": "the fraction-of-occurrence of { }^{79}\\mathrm{br} is 0.507, and the fraction-of-occurrence of { }^{81}\\mathrm{br} is 0.493.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种同位素的出现分数，答案以数值形式给出，需要精确到三位小数。 | 知识层次: 题目涉及基本公式应用和简单计算，通过设定方程求解同位素丰度，属于直接套用和简单计算范畴，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用加权平均公式进行简单代数运算，但不需要多个公式组合或复杂推导。" + }, + { + "idx": 3894, + "question": "An element that has the electron configuration 1 s^{2} 2 s^{2} 2 p^{6} has how many electrons? Enter numeric values only.", + "answer": "9", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的电子构型计算电子总数，需要数值计算，答案也是数值形式。 | 知识层次: 题目考查电子排布的基本概念和简单计算，仅需根据给定的电子排布式直接数出电子总数，属于基本公式应用和简单计算范畴。 | 难度: 在计算题中属于最低难度，仅需直接累加电子排布中的电子数（1s² + 2s² + 2p⁶ = 2+2+5=9），无需公式转换或多步骤计算，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 3895, + "question": "The electrons that occupy the outermost filled shell are called electrons.", + "answer": "The electrons that occupy the outermost filled shell are called valence electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（valence electrons）来补全句子，属于需要简短文字回答的简答题类型 | 知识层次: 题目考查基本概念的记忆和理解，仅需回答最外层电子的名称，不涉及复杂分析或应用。 | 难度: 在简答题中属于基本定义简答，仅需回忆并准确填写\"valence electrons\"这一基础概念术语，无需解释或论述其他相关内容。题目直接考察最基础的定义记忆，属于该题型内最低难度等级。" + }, + { + "idx": 3896, + "question": "When all the electrons in an atom occupy the lowest possible energy states, the atom is said to be in its: (a)ground state(b)ionized state (c) cold state (d) regular state", + "answer": "(a)ground state", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)ground state(b)ionized state (c) cold state (d) regular state中选择正确答案 | 知识层次: 题目考查原子能态的基本概念记忆，仅需识别\"最低能量状态\"对应的术语\"ground state\"，属于基础概念记忆层次。 | 难度: 在选择题中属于简单难度，仅需直接记忆基础概念（原子基态的定义）即可选出正确答案，无需理解或辨析其他选项。" + }, + { + "idx": 3897, + "question": "How many p electrons at the outermost orbital do the Group VIIA elements have?", + "answer": "5 p electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的知识点（VIIA族元素最外层p电子数），答案是一个简短的陈述（5 p electrons），不需要计算或选择，属于需要直接回答的简答题类型。 | 知识层次: 题目考查对元素周期表VIIA族元素最外层p电子数的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答VIIA族元素最外层p电子数量这一基础概念记忆性问题，无需解释或描述相关概念，更不需要阐述复杂概念体系。解题步骤极其简单，只需直接回忆并写出答案即可，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 3898, + "question": "To what group in the periodic table would an element with atomic number 119 belong?(a) Group 0 (or 18) (b) Group IA (or 1) (c) Group IIA (or 2) (d) Group VIIA (or 17)", + "answer": "(b) Group IA (or 1)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对元素周期表分组的基本概念的记忆和理解，只需根据原子序数判断元素所属的族，不需要复杂的应用或分析。 | 难度: 在选择题中属于中等难度，需要理解元素周期表的分组规则，并能够根据原子数推断元素所属的组别。虽然题目涉及的是基础概念记忆，但需要一定的理解和应用能力，而不仅仅是简单的记忆。" + }, + { + "idx": 3899, + "question": "Calculate the energy of attraction between a cation with a valence of +2 and an anion with a valence of -2 , the centers of which are separated by a distance of 3.7nm.", + "answer": "-2.5 × 10^{-19} J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算离子间的吸引能），答案是一个具体的数值结果（-2.5 × 10^{-19} J），需要使用公式进行计算。 | 知识层次: 题目要求应用基本公式（库仑定律）进行简单计算，仅涉及单一概念的直接应用，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算，仅需应用库仑定律公式进行简单数值代入和计算，无需多步骤或复杂推导。" + }, + { + "idx": 3900, + "question": "Materials whose constituent particles are bound by which type of bond are generally expected to have the lowest melting temperatures?(a) Covalent(b) Metallic(c) Ionic(d) Van der Waals(e) Hydrogen", + "answer": "(d) Van der Waals", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案明确给出了选项编号和内容 | 知识层次: 题目考查对不同类型化学键及其性质的基本概念的记忆和理解，特别是范德华力与其他化学键在熔点方面的差异。 | 难度: 在选择题中属于简单难度，仅需直接记忆不同类型化学键的基本特性即可作答，无需进行概念辨析或复杂分析。题目明确询问哪种键型通常具有最低熔点，属于基础概念的直接考察。" + }, + { + "idx": 3901, + "question": "Calculate % IC of the interatomic bonds for the intermetallic compound TiAl3.", + "answer": "0%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算TiAl3金属间化合物的离子键百分比(% IC)，需要应用相关公式进行数值计算，最终得出0%的数值结果。这符合计算题的特征，即需要数值计算和公式应用。 | 知识层次: 题目要求计算TiAl3的离子键百分比，这需要应用基本的离子键计算公式，属于直接套用公式的简单计算。虽然涉及基本概念的理解，但主要考察的是基本公式的应用能力，不需要多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于最简单的等级1。题目仅要求直接应用离子键百分比（%IC）的计算公式，且由于TiAl3是金属间化合物，其%IC计算结果固定为0%，不需要任何复杂计算或公式组合。解题步骤极其简单，只需知道金属键的%IC特性即可得出答案，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 3902, + "question": "On the basis of this result what type of interatomic bonding would you expect to be found in TiAl3 ? (a) van der Waals (b) ionic (c) metallic (d) covalent", + "answer": " (c)metallic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确的原子间键合类型，符合选择题的特征。 | 知识层次: 题目考查对金属间化合物TiAl3中原子键合类型的基础概念记忆，属于对基本键合类型分类的理解和识别。 | 难度: 在选择题中属于中等偏下难度，需要理解金属键的基本概念，并能将其应用于具体化合物（TiAl3）的键合类型判断。虽然涉及概念理解，但不需要复杂的辨析或深度分析，属于基础概念的应用层面。" + }, + { + "idx": 3903, + "question": "Which of the following microstructures is expected to be most similar to a single crystal in terms of structure and properties? Assume all of the options offer the same volumes and only consider grain boundaries as a crystalline defect for this question. (a) Textured polycrystal with about 10,000 grains (b) Random polycrystal with about 1,000,000 grains (c) Random polycrystal with about 1,000,000,000 grains (d) Amorphous", + "answer": "(a) Textured polycrystal with about 10,000 grains", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从多个选项中选择最接近单晶结构和性能的微观结构，具有明确的选项和唯一正确答案 | 知识层次: 题目需要理解单晶和多晶的结构差异，并分析晶粒数量和取向对性能的影响，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目考察了单晶、多晶和非晶材料的结构与性能差异，以及晶粒取向和晶界数量的影响。虽然涉及多个概念的综合，但解题步骤相对直接，只需比较各选项与单晶的相似性即可。" + }, + { + "idx": 3904, + "question": "For a metal that has the simple cubic crystal structure, calculate the atomic radius if the metal has a density of 2.05g / {cm}^{3} and an atomic weight of 77.84g / mol.", + "answer": "the atomic radius is 0.122nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解金属的原子半径，答案是一个具体的数值结果（0.122nm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、晶体结构的理解以及原子半径的计算，涉及多个概念的关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶体结构知识（简单立方晶胞的原子数和边长与原子半径的关系）以及单位换算。解题步骤包括计算晶胞体积、确定晶胞边长、最后推导原子半径，涉及多步计算和概念关联，但不需要处理复杂多变量。" + }, + { + "idx": 3905, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Determine the crystal structure of the metal.", + "answer": "The metal has an FCC crystal structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过计算来确定金属的晶体结构，涉及使用给定的晶胞边长、密度和原子量等参数进行计算，最终得出晶体结构的结论。答案是基于计算结果得出的具体结构类型，而非从多个选项中选择或简单的对错判断。 | 知识层次: 题目需要多步计算（包括密度公式应用、单位换算、晶胞原子数计算等），并需要将计算结果与晶体结构特征进行关联分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、单位晶胞体积计算、原子数计算等多个步骤，并综合分析结果以确定晶体结构。虽然不涉及复杂多变量计算，但需要较强的概念关联和综合分析能力。" + }, + { + "idx": 3906, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Determine the atomic radius of the metal.", + "answer": "The metal has an atomic radius of 0.155 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定金属的原子半径，答案是一个具体的数值结果（0.155 nm），解答过程需要涉及密度、原子重量和晶格参数的计算。 | 知识层次: 题目需要进行多步计算，包括利用密度和原子质量计算晶胞中的原子数，然后根据立方晶胞的类型（如面心立方或体心立方）确定原子半径。这需要综合应用密度、晶胞参数和原子半径之间的关系，涉及多个概念的综合分析和计算。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、单位换算、晶体结构几何关系等多步骤计算，并综合分析立方晶胞参数与原子半径的关系。虽然计算过程明确，但涉及多个概念关联和单位转换，属于中等偏上的复杂度。" + }, + { + "idx": 3907, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Indicate the letter of the metal listed in the following table that has these characteristics.", + "answer": "The metal with these characteristics is metal C, which has an atomic radius of 0.155 nm and an FCC crystal structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的金属列表中选择符合特定特征的金属，答案明确指出了选择的是金属C，符合选择题的特征。 | 知识层次: 题目需要综合运用晶体结构知识（FCC）、密度计算公式、单位换算等多步骤计算，并需要将计算结果与给定选项进行匹配分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用密度计算、晶体结构分析、单位换算等多步计算，并结合原子半径和晶体结构特征进行判断。解题过程涉及多个概念的综合应用和复杂分析，超出了基础选择题的简单识别或单一概念应用。" + }, + { + "idx": 3908, + "question": "If the atomic radius of a metal that has the body-centered cubic crystal structure is 0.181nm, calculate the volume of its unit cell.", + "answer": "the volume of the unit cell is 0.0271 nm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案也是一个具体的数值结果。 | 知识层次: 题目需要应用体心立方晶体结构的公式计算单位晶胞体积，属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最简单难度，只需要直接套用体心立方晶胞体积公式V = (4r/√3)^3，代入给定的原子半径r=0.181nm即可完成计算，无需任何中间步骤或公式转换。" + }, + { + "idx": 3909, + "question": "If the atomic radius of a metal that has the face-centered cubic crystal structure is 0.123nm, calculate the volume of its unit cell.", + "answer": "\\[\nv_{c}=0.258nm^{3}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案是一个具体的数值结果。 | 知识层次: 题目要求应用面心立方晶体结构的基本公式进行简单计算，仅需直接套用公式并代入已知数值即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用面心立方晶体的单位晶胞体积公式（V = (4r/√2)^3），代入给定的原子半径即可得到结果。无需多个公式组合或复杂计算步骤，属于最基础的计算题类型。" + }, + { + "idx": 3910, + "question": "Rhodium has an atomic radius of 0.1345nm, a density of (12.41g / {cm}^{3}) and an atomic weight of 102.91 \\mathrm{g} / mol. What is rhodium's crystal structure?(a) Simple cubic(b) \\mathrm{BCC}(c) \\mathrm{FCC}", + "answer": "the crystal structure for rhodium is \\mathrm{fcc}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项(a) Simple cubic、(b) BCC、(c) FCC中选择正确答案，符合选择题的特征 | 知识层次: 题目需要根据给定的原子半径、密度和原子重量计算晶胞参数，并推断晶体的结构类型。这涉及到多步计算和概念关联，包括密度公式的应用、晶胞体积的计算以及不同晶体结构类型的比较分析。虽然不涉及复杂的推理或创新应用，但需要综合运用多个知识点进行判断。 | 难度: 在选择题中属于较高难度，需要综合运用原子半径、密度、原子重量等数据进行多步计算，并关联晶体结构的知识点进行综合分析判断。解题步骤较为复杂，涉及单位转换和公式推导，对学生的计算能力和概念理解深度要求较高。" + }, + { + "idx": 3911, + "question": "Niobium (Nb) has a BCC crystal structure, an atomic radius of 0.143nm and an atomic weight of 92.91g / mol. Calculate the theoretical density for nb.", + "answer": "the theoretical density for nb is 8.48g / {cm}^{3}. the experimental density for nb is 8.57g / {cm}^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铌的理论密度，答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目要求应用基本的晶体结构密度计算公式，涉及原子半径、晶格常数和原子量的简单换算，属于直接套用公式进行计算的应用层次，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用BCC晶体结构的密度计算公式，涉及原子半径、原子质量和晶格参数的基本转换，但不需要多个公式组合或复杂推导。" + }, + { + "idx": 3912, + "question": "Consider the ideal barium titanate \\left(\\mathrm{BaTiO}_{3}\\right) structure. What is the coordination number of the \\mathrm{Ti}^{4+} ion in terms of surrounding \\mathrm{O}^{2-} ions?\n[a] 1\n[b] 2\n[c] 3\n[d] 4\n[e] 5\n[f] 6\n[g] 7\n[h] 8", + "answer": "According to Fig. 3.10, the central \\mathrm{Ti}^{4+} ion is surrounded by six \\mathrm{O}^{2-} ions, one residing at each of the six cube faces.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项列表和正确答案 | 知识层次: 题目考查对理想钛酸钡结构中钛离子配位数的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆钛酸钡结构中Ti4+离子的配位数即可，无需复杂理解或分析。" + }, + { + "idx": 3913, + "question": "Consider the ideal barium titanate \\left(\\mathrm{BaTiO}_{3}\\right) structure. What is the coordination number of the \\mathrm{Ba}^{2+} ion in terms of surrounding \\mathrm{Ti}^{4+} ions?\n[a] 4\n[b] 6\n[c] 8\n[d] 10\n[e] 12", + "answer": "Careful consideration of Fig. 3.10, and consideration of the perovskite compound stoichiometry reveals that 12 \\mathrm{Ti}^{4+} ions surround each \\mathrm{Ba}^{2+} ion. A change in perspective is recommended to help visualize this, where the unit cell cube corners feature \\mathrm{O}^{2-} ions in the corners, \\mathrm{Ti}^{4+} ions centered along each cube edge, and \\mathrm{Ba}^{2+} ions centered in the middle of the cube.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择关于Ba²⁺离子配位数的正确答案，且提供了多个选项供选择。 | 知识层次: 题目考查对理想钛酸钡结构中离子配位数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于较高难度，需要深入理解钙钛矿结构的空间排布和离子配位关系。题目不仅要求记忆BaTiO3的晶体结构，还需要通过三维空间想象能力（如改变视角观察立方体边缘和中心离子的分布）来推导Ba²⁺离子的配位数。这种需要结合晶体学知识和空间思维能力的题目，在同题型内属于复杂概念区分层次。" + }, + { + "idx": 3914, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell edge lengths?\n\\[\na=b=c\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "For both cubic and rhombohedral crystal systems all the unit cell edge lengths are equal.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合给定条件的晶体系统，答案也明确指出了哪些选项是正确的。这符合选择题的特征。 | 知识层次: 题目考查对晶体系统基本特征（晶胞边长关系）的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题中属于中等偏下难度，需要理解晶体系统中单位晶胞边长关系的基本概念，并进行简单辨析。题目要求识别哪些晶系满足a=b=c的条件，涉及对立方和菱方晶系的记忆，但不需要复杂的比较分析。" + }, + { + "idx": 3915, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell edge lengths?\n\\[\na=b \\neq c\n\\](a) Cubic(b) Hexagonal(c) Tetragonal\n\\mathrm{d}) Rhombohedral(e) Orthorhombic(f) Monoclinic (g) Triclinic", + "answer": "For both hexagonal and tetragonal crystal systems two of the unit cell edge lengths are equal to one another, but unequal to the third length.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合给定条件的晶体系统，答案也是从选项中进行选择。 | 知识层次: 题目考查对晶体系统基本特征和分类的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体系统的基本定义和特征，并能简单辨析不同晶体系统的单元边长关系。题目要求识别出具有特定边长关系（a=b≠c）的晶体系统，这需要对六方晶系和四方晶系的基本特征有清晰记忆。虽然涉及两个正确选项，但选项本身较为明确，不需要复杂的推理或深度分析。" + }, + { + "idx": 3916, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell e edge lengths?a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "For orthorhombic, monoclinic and triclinic crystal systems, all three of the unit cell edge lengths are unequal to one another.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定条件的晶系，属于典型的选择题形式 | 知识层次: 题目考查对晶体系统基本分类和单元晶胞边长关系的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解不同晶系的基本定义和特征，并进行简单的辨析。题目要求识别哪些晶系的单位晶胞边长关系满足所有三个边长都不相等，这需要对晶系分类有基本的记忆和理解，但不需要复杂的分析或深度推理。" + }, + { + "idx": 3917, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?\n\\[\n\\alpha \\neq \\beta \\neq \\gamma \\neq 90^{\\circ}\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "Triclinic is the only crystal system for which none of the interaxial angles are equal to one another and also not equal to 90^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的正确答案 | 知识层次: 题目考查对晶体系统基本概念的记忆和理解，特别是对各晶系轴角关系的识别。只需记忆不同晶系的特征即可回答，无需复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体系统的基本定义和特征，并能区分不同晶体系统的角度关系。虽然涉及多个选项的比较，但题目明确给出了关键特征（α≠β≠γ≠90°），只需记忆并匹配到三斜晶系即可。不需要复杂的分析或推导。" + }, + { + "idx": 3918, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?(a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic\ng) Triclinic", + "answer": "Cubic, tetragonal and orthorhombic crystal systems all have the three interaxial angles equal to 90^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的答案 | 知识层次: 题目考查对晶体系统基本分类和特征的记忆，特别是各晶系轴角关系的定义性知识，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体系统中各晶系的晶轴角度关系，并进行简单辨析。虽然涉及多个晶系的记忆，但题目明确给出了角度关系（90°），只需从选项中筛选出符合条件的晶系，不需要复杂的分析或计算。" + }, + { + "idx": 3919, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?\n\\[\n\\alpha=\\beta=90^{\\circ}, \\gamma=120^{\\circ}\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "Only the hexagonal crystal system has two of the interaxial angles equal to 90^{\\circ}, while the third angle is equal to 120^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的正确答案 | 知识层次: 题目考查对晶体系统基本特征和分类的记忆，只需要识别不同晶体系统的角度关系即可回答，不涉及复杂计算或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体系统的定义和基本特征，并能简单辨析不同晶体系统的角度关系。虽然涉及多个选项，但核心知识点明确，只需记忆和基本理解即可选出正确答案。" + }, + { + "idx": 3922, + "question": "Polyethylene may be fluorinated by inducing the random substitution of fluorine atoms for hydrogen. For this polymer, determine the concentration of F (in wt %) that must be added if this substitution occurs for 18.6 % of all of the original hydrogen atoms. Atomic weights for several elements are included in the following table: Carbon 12.01 g/mol, Chlorine 35.45 g/mol, Fluorine 19.00 g/mol, Hydrogen 1.008 g/mol, Oxygen 16.00 g/mol.", + "answer": "the concentration of F that must be added is 18.0 wt %.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氟的浓度（wt%），需要利用给定的原子重量和百分比进行具体的计算。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及原子量的应用和百分比浓度的计算，需要将概念关联并进行综合分析。虽然不涉及复杂的推理分析或机理解释，但比简单的公式应用和直接套用更复杂。 | 难度: 在计算题中属于综合性计算问题，需要理解聚合物结构、原子替换的概念，并进行多步计算（包括分子量计算、替换比例计算和重量百分比转换）。虽然不涉及复杂变量，但需要将多个概念和计算步骤整合起来解决问题。" + }, + { + "idx": 3923, + "question": "Polyethylene may be fluorinated by inducing the random substitution of fluorine atoms for hydrogen. For this polymer, determine the concentration of F (in wt %) that must be added to completely fluorinate the material, i.e. to produce polytetrafluoroethylene (PTFE). Atomic weights for several elements are included in the following table: Carbon 12.01 g/mol, Chlorine 35.45 g/mol, Fluorine 19.00 g/mol, Hydrogen 1.008 g/mol, Oxygen 16.00 g/mol.", + "answer": "the concentration of F required to completely fluorinate the material is 76.0 wt %.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氟的浓度（wt%），答案是一个具体的数值结果（76.0 wt%），这符合计算题的特征。 | 知识层次: 题目要求进行基本的数值计算和公式应用，涉及原子量的简单计算和百分比浓度的确定，属于直接套用基本公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算氟的浓度，需要应用基本的化学计量学公式，涉及原子质量和简单的百分比计算。虽然需要理解聚乙烯和聚四氟乙烯的结构差异，但计算过程直接且步骤较少，属于该题型内中等偏下的难度。" + }, + { + "idx": 3924, + "question": "Which of the following may form linear polymers?(a) Rubber(b) Epoxy(c) Polyethylene(d) Phenol-formaldehyde(e) Polystyrene(f) Nylon", + "answer": "Polyethylene, polystyrene and nylon may form linear polymers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择可能形成线性聚合物的材料，属于选择题类型 | 知识层次: 题目考查对线性聚合物基本概念的记忆和理解，需要识别哪些材料可以形成线性聚合物，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏简单难度，需要理解线性聚合物的定义并能够区分不同类型的聚合物。虽然涉及多个选项，但主要考察基础概念的理解和简单辨析，不需要复杂的分析过程。" + }, + { + "idx": 3925, + "question": "Which of the following form network polymers?(a) Rubber(b) Epoxy(c) Polyethylene\nd) Phenol-formaldehyde(e) Polystyrene(f) Nylon\n\\", + "answer": "Epoxy and phenol-formaldehyde form network polymers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择形成网络聚合物的材料，答案给出了具体选项，符合选择题的特征 | 知识层次: 题目考查对网络聚合物分类的基本概念记忆，只需识别哪些选项属于网络聚合物结构类型，不涉及复杂分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解网络聚合物的定义并能够区分不同类型的聚合物。虽然涉及多个选项，但主要考察的是对基础概念的简单辨析能力，不需要复杂的分析过程。" + }, + { + "idx": 3926, + "question": "For most polymers, which configuration predominates?(a) Head-to-head(b) Head-to-tail", + "answer": "For most polymers, the head-to-tail configuration predominates.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择正确答案，符合选择题的特征 | 知识层次: 题目考查聚合物基本构型的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题中属于简单难度，只需要直接记忆聚合物最常见的构型即可，无需进行概念辨析或复杂理解。题目考察的是基础概念的记忆，属于最基本的知识点。" + }, + { + "idx": 3927, + "question": "Is it possible to produce a polymer that is 100% crystalline? (a) True (b) False", + "answer": "False. It is not possible to produce a polymer that is 100% crystalline. The maximum crystallinity that can be obtained is about 95%, with the remaining material being amorphous.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目以判断陈述对错的形式提问（True/False），并要求选择正确选项。答案明确给出了判断结果和解释，符合判断题的特征。 | 知识层次: 题目考查对聚合物结晶度的基本概念的理解和记忆，属于基础概念层次。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需要记忆聚合物结晶度的基本概念即可作答。题目直接询问\"能否生产100%结晶的聚合物\"这一事实性知识，不需要进行概念理解或复杂推理，属于该题型内最基础的难度等级。" + }, + { + "idx": 3928, + "question": "The number of vacancies in some hypothetical metal increases by a factor of 5 when the temperature is increased from 1040 K to 1150 K. Calculate the energy (in kj/mol ) for vacancy formation assuming that the density of the metal remains the same over this temperature range.", + "answer": "the energy for vacancy formation is 115 kj/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺形成的能量，答案是一个具体的数值结果（115 kj/mol），这符合计算题的特征。 | 知识层次: 题目需要应用空位形成能的计算公式，涉及多步计算和温度变化对空位数的影响分析，需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算空位形成能，涉及温度变化对空位数量的影响，需要理解并应用阿伦尼乌斯方程或相关公式。虽然计算步骤较多，但题目提供了明确的温度范围和变化因子，减少了复杂性。因此，在同类计算题中属于中等偏上的难度。" + }, + { + "idx": 3929, + "question": "The number of vacancies present in some metal at 864^{\\circ} C is 1.1 × 10^{24}{m}^{-3}. Calculate the number of vacancies at 463^{\\circ} C given that the energy for vacancy formation is 1.25 \\mathrm{eV} / atom; assume that the density at both temperatures is the same", + "answer": "the number of vacancies at 463^{\\circ} C is 5.45 × 10^{22}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定温度下的空位数量，答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用阿伦尼乌斯方程计算空位浓度，并理解温度对空位形成的影响。虽然计算过程较为直接，但需要综合运用多个知识点，包括单位转换和公式应用。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、能量单位转换和指数运算，但变量和计算步骤相对明确，属于中等偏上的难度。" + }, + { + "idx": 3930, + "question": "In metals, there are significantly more vacancies than self-interstitials.(a) True(b) False", + "answer": "True. In metals, there are significantly more vacancies than self-interstitials; the reason for this is that the atom is significantly larger than the interstitial position in which it is situated, and, consequently significant lattice strains result.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附有简要解释。 | 知识层次: 题目考查金属中空位和自间隙原子数量的基本概念记忆，属于基础知识的直接判断，无需复杂分析或计算。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆金属中空位和自间隙原子的相对数量关系这一基础知识点即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 3931, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for MgO.", + "answer": "For MgO, the ionic radii of the Mn2+ and Mg2+ are 0.067 nm and 0.072 nm, respectively. Therefore the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.072 nm - 0.067 nm) / 0.072 nm × 100 = 6.9%, which value is within the acceptable range for a high degree of solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么MgO能与MnO形成完全固溶体，需要基于离子半径差异进行文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解离子半径差异对固溶体溶解度的影响，并进行简单的百分比计算，属于中等应用层次。虽然涉及基础概念，但需要将概念与具体计算结合，属于多步计算和概念关联的范畴。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求进行离子半径计算和百分比差异分析，但解题步骤相对直接，主要涉及基础概念的应用和简单计算。题目没有要求多角度分析或深度关联性分析，因此不符合等级4或5的标准。该题目主要测试学生对离子半径差异和固溶体形成条件的理解，属于综合分析和说明的范畴。" + }, + { + "idx": 3932, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for CaO.", + "answer": "For CaO, the ionic radii of the Mn2+ and Ca2+ are 0.067 nm and 0.100 nm, respectively. Therefore, the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.100 nm - 0.067 nm) / 0.100 nm × 100 = 33%. This Δr% value is much larger than the ±15% range, and, therefore, CaO is not expected to experience any appreciable solubility in MnO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么CaO不会在MnO中形成完全固溶体，需要文字论述和解释，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用离子半径差异的计算公式，并结合Hume-Rothery规则进行综合分析，判断固溶体的溶解度。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解离子半径的概念，进行简单的计算，并解释计算结果的含义。虽然涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3933, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for BeO.", + "answer": "For BeO, the ionic radii of the Mn2+ and Be2+ are 0.067 nm and 0.035 nm, respectively. Therefore, the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.067 nm - 0.035 nm) / 0.067 nm × 100 = 48%. This Δr% value is much larger than the ±15% range, and, therefore, BeO is not expected to experience any appreciable solubility in MnO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释BeO在MnO中的固溶度问题，答案提供了详细的文字解释和计算过程，属于需要论述的简答题类型 | 知识层次: 题目要求学生应用离子半径差异的计算公式，并结合固溶体溶解度规则进行分析。这需要多步计算和概念关联，属于中等应用层次。虽然涉及基础概念（离子半径、固溶体），但重点在于应用这些概念进行综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求进行多步计算（离子半径差计算）和概念关联（固溶体溶解度规则），但整体解题思路较为直接，主要基于已知的离子半径数据和简单的百分比计算。题目没有要求多角度分析或深度关联其他材料科学概念，因此属于综合分析和说明的等级3难度。" + }, + { + "idx": 3934, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for NiO.", + "answer": "For NiO, the ionic radii of the Mn2+ and Ni2+ are 0.067 nm and 0.069 nm, respectively. Therefore, the percentage difference in ionic radii Δr% is determined as follows: Δr% = (0.069 nm - 0.067 nm) / 0.069 nm × 100 = 3%, which value is, of course, within the acceptable range for a high degree of solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释NiO与MnO形成完全固溶体的原因，需要文字论述和解释，而不是简单的选择、判断或计算。 | 知识层次: 题目需要计算离子半径差异百分比，并解释其与固溶体溶解度的关系，涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释NiO与MnO形成完全固溶体的原因，但解题过程相对直接，主要涉及离子半径的计算和比较。虽然需要一定的概念理解和计算能力，但不需要多角度分析或深度关联性分析。因此，在简答题题型中，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 3935, + "question": "Which of these elements would you expect to form a substitutional solid solution having complete solubility with copper? The elements are: Ni, O, H, Pt, Pd, Co, C, Zn, Ag, Al, Cr, Fe. The criteria for complete solubility are: 1) the difference in atomic radii between Cu and the other element must be less than ±15%, 2) the crystal structures must be the same, 3) the electronegativities must be similar, and 4) the valences should be the same, or nearly the same.", + "answer": "Ni, Pd, and Pt meet all of the criteria and thus form substitutional solid solutions having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素列表中选择符合特定条件的元素，属于从多个选项中选择正确答案的类型 | 知识层次: 题目要求考生根据多个标准（原子半径差异、晶体结构、电负性和价态）综合分析哪些元素能与铜形成完全固溶体。这需要考生不仅记住这些标准，还要能够应用这些标准进行多步判断和综合分析。虽然不涉及复杂计算，但需要较高的概念关联和综合分析能力。 | 难度: 在选择题中属于较高难度，需要综合应用多个材料科学概念（原子半径、晶体结构、电负性、价态）进行判断，并理解高温相变对溶解度的影响。解题步骤涉及多条件筛选和特殊情况分析，超出基础概念选择题的范畴。" + }, + { + "idx": 3936, + "question": "Which of these elements would you expect to form a substitutional solid solution of incomplete solubility with copper? The elements are: Pd, Al, Cr, Fe, H, Pt, Ni, Zn, C, Ag, O, Co. The criteria for incomplete solubility are: these metals have either BCC or HCP crystal structures, and/or the difference between their atomic radii and that for Cu are greater than ±15%, and/or have a valence different than 2+.", + "answer": "Ag, Al, Co, Cr, Fe, and Zn form substitutional solid solutions of incomplete solubility. All these metals have either BCC or HCP crystal structures, and/or the difference between their atomic radii and that for Cu are greater than ±15%, and/or have a valence different than 2+.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素列表中选择符合特定条件的元素，属于从多个选项中选择正确答案的类型 | 知识层次: 题目要求根据给定的元素和条件（晶体结构、原子半径差异、价态）判断哪些元素能与铜形成不完全固溶体。这需要理解固溶体的形成条件，并能够将这些条件应用到具体元素的分析中。虽然不涉及复杂的计算或深度推理，但需要对多个概念（晶体结构、原子半径、价态）进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合应用多个概念（晶体结构、原子半径差异、化合价）进行判断，并排除不符合条件的选项。解题过程涉及多步分析和比较，属于复杂分析过程的判断。" + }, + { + "idx": 3937, + "question": "Which of these elements would you expect to form an interstitial solid solution with copper? The elements are: C, Pd, Pt, H, Cr, O, Zn, Ag, Al, Co, Fe, Ni. The criteria for interstitial solid solutions are: these elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的元素列表中选择符合特定条件（原子半径显著小于铜）的元素，属于从多个选项中选择正确答案的类型。答案明确列出了符合条件的元素（C, H, O），符合选择题的特征。 | 知识层次: 题目考查对间隙固溶体形成条件的记忆和理解，仅需知道间隙固溶体形成元素需要比基体元素原子半径小得多这一基本原理即可回答。 | 难度: 在选择题题型中，该题目属于概念理解和简单辨析难度。虽然题目给出了明确的判断标准（原子半径显著小于铜），但需要考生记忆并理解哪些元素符合这个标准。相比等级1的直接记忆题目，这里需要考生对原子半径概念有一定理解，并能将其应用到具体元素的选择中。但不需要进行复杂的比较分析或深度推理，因此属于等级2难度。" + }, + { + "idx": 3938, + "question": "The concentration of carbon in an iron-carbon alloy is 0.57 wt%. What is the concentration in kilograms of carbon per cubic meter of alloy? The densities of iron and carbon are 7.87 and 2.25 \\mathrm{g} / {cm}^{3}, respectively.", + "answer": "the concentration of carbon is 11.8 kg / m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及浓度转换和密度计算，最终需要得出具体的数值结果（11.8 kg/m³）。答案形式为计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及质量分数转换、密度计算和单位换算，需要综合应用多个概念和公式，但不需要复杂的推理或深度分析。 | 难度: 在计算题中属于综合性计算问题，需要理解质量百分比与体积浓度的转换，涉及密度概念的应用和多步计算。虽然计算步骤明确，但需要综合运用多个知识点并进行单位转换，属于中等偏上的难度。" + }, + { + "idx": 3939, + "question": "13}\nSome hypothetical alloy is composed of 12.5 wt% of metal A and 87.5 wt% of metal B. If the densities of metals A and \\mathrm{B} are 4.27 and 6.35g / {cm}^{3}, respectively, whereas their respective atomic weights are 61.4 and 125.7g / mol, determine whether the crystal structure for this alloy is simple cubic, facercentered cubic, or body-centered cubic. Assume a unit cell edge length of 0.395nm.", + "answer": "the crystal structure is body-centered cubic.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过计算合金的密度和原子排列方式来确定晶体结构类型，涉及数值计算和公式应用。答案是基于计算结果得出的具体结论，而非从多个选项中选择或简单的对错判断。 | 知识层次: 题目需要进行多步计算，包括质量分数到原子分数的转换、单位晶胞中原子数的计算、密度计算等，涉及多个概念的综合应用和关联分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要掌握合金成分、密度、原子量、晶体结构等多方面知识，并进行多步计算和综合分析。虽然涉及多个变量和公式应用，但解题步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 3940, + "question": "17}\nIron and vanadium both have the BCC crystal structure andV forms a substitutional solid solution in \\mathrm{Fe} for concentrations up to approximately 20 wt%V at room temperature. Determine the concentration in weight percent ofV that must be added to iron to yield a unit cell edge length of 0.289nm.", + "answer": "the concentration of \\mathrm{v} that must be added to iron to yield a unit cell edge length of 0.289nm is 12.9 wt%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在铁中添加钒的重量百分比，从而得到特定的晶胞边长。答案是一个具体的数值（12.9 wt%），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及晶体结构参数与成分的关系，需要综合运用BCC晶体结构的知识和固溶体成分的计算方法，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用BCC晶体结构的相关知识，进行多步计算和概念关联。题目要求根据给定的晶胞边长计算合金成分，涉及原子量、晶胞体积和密度等概念的关联计算，但不需要处理复杂多变量或高级数学工具。" + }, + { + "idx": 3941, + "question": "Which of the following is a (are) linear defect(s)?(a) An edge dislocation(b) A Frenkel defect(c) A Schottky defect", + "answer": "Edge and screw dislocations are linear defects.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对线性缺陷这一基本概念的记忆和理解，只需要识别出边缘位错属于线性缺陷即可，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要理解线性缺陷的定义并区分不同类型的缺陷。虽然涉及多个概念，但只需简单辨析即可选出正确答案。" + }, + { + "idx": 3942, + "question": "A photomicrograph was taken of a specimen at a magnification of 100 ×, and it was determined that the average number of grains per square inch was 200 . What is this specimen's ASTM grain size number?", + "answer": "the specimen's astm grain size number is 4.9.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数值，答案是一个具体的数值结果（4.9），这表明解答过程涉及计算步骤。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，只需直接套用公式进行简单计算即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用ASTM grain size number的计算公式，虽然需要理解公式的含义和单位转换，但整体解题步骤较为直接，仅涉及单一公式的代入和简单计算，无需多个公式组合或复杂推导。" + }, + { + "idx": 3943, + "question": "Diffusion by which mechanism occurs more rapidly in metal alloys?(a) Vacancy diffusion(b) Interstitial diffusion", + "answer": "In metal alloys, interstitial diffusion takes place more rapidly than vacancy diffusion because the interstitial atoms are smaller and are more mobile. Also, there are more vacant adjacent interstitial sites than there are vacancies.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查扩散机制的基础概念记忆和理解，涉及金属合金中两种扩散方式的比较，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要对两种扩散机制有基本理解并进行简单比较。虽然需要区分两种扩散机制的特点，但题目提供了明确对比选项，且答案基于基础概念（原子大小和移动性差异），不需要复杂的推理过程。" + }, + { + "idx": 3944, + "question": "As temperature decreases, the fraction of total number of atoms that are capable of diffusive motion(a) increases.(b) decreases.", + "answer": "As temperature decreases, the fraction of the total number of atoms that are capable of diffusive motion decreases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的两个选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对温度与原子扩散能力关系这一基本概念的理解，属于基础概念记忆和简单理解的范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解温度与原子扩散能力之间的关系，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 3945, + "question": "If [m] atoms of helium pass through a [a] square meter plate area every [t] hours, and if this flux is constant with time, compute the flux of helium in units of atoms per square meter per second.", + "answer": "\\[\nj = \\frac{[m]}{[a] × [t] × 3600} \\text{ atoms per square meter per second}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定氦的通量，答案以数学公式形式给出，需要将给定的变量代入公式进行计算。 | 知识层次: 题目要求进行基本的单位转换和简单的公式应用，涉及的是直接套用公式进行计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（流量=数量/面积/时间）并进行单位换算（小时转秒），无需任何多步骤推理或复杂计算。" + }, + { + "idx": 3946, + "question": "If water molecules pass through a membrane with a steady state flux of [j] mole /\\left(m^{2}\\right. day ), how long will it take, in hours, for [m] kg of water to pass through a [\\mathrm{a}] square centimeter of the membrane?", + "answer": "\\[\nt = \\frac{[m] × 1000 × 24}{[a] × [j] × 18 × 10000} \\text{ hours}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解时间，答案是一个具体的计算公式，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的参数代入公式进行转换和计算，但不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用稳态通量公式并进行单位换算，但解题步骤相对直接，仅涉及单一公式的变形和单位转换，无需多个公式组合或复杂推导。" + }, + { + "idx": 3947, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the contact lens thickness likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "If the contact lens thickness is increased and all other factors are preserved, the concentration gradient decrease and the oxygen diffusion flux should decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述增加接触镜厚度对氧气稳态流量的影响，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解扩散通量的概念，并分析接触镜厚度变化对氧气扩散通量的影响。这涉及到浓度梯度的变化和扩散通量的计算，属于中等应用层次，需要多步推理和综合分析。 | 难度: 在简答题题型中，该题目要求考生进行多角度分析论述。首先需要理解扩散通量和稳态流量的关系，其次需要分析接触镜厚度变化对浓度梯度的影响，最后需要综合这些因素得出扩散通量变化的结论。这涉及到多个概念的关联和综合分析，属于较高难度的简答题。" + }, + { + "idx": 3948, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the diffusivity of oxygen gas by decreasing the contact lens porosity likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "If the lens features more voids, we expect the oxygen to permeate the membrane faster since oxygen should be able to transit voids faster than the bulk lens material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述为什么减少接触镜的孔隙率可能对增加氧气流量有用，答案提供了详细的文字解释，而不是简单的选择或判断。 | 知识层次: 题目要求分析氧气通过角膜接触镜的稳态流动速率与扩散系数及孔隙率之间的关系，需要综合运用扩散原理、材料孔隙率对扩散的影响等知识，并进行推理分析。解答过程涉及对扩散机理的理解和多因素的综合考虑，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对氧气扩散机理进行深度解释，需要综合运用扩散原理、材料孔隙率影响等知识，并推理分析接触镜孔隙率变化对氧气稳态流量的影响机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念应用的范畴，属于机理深度解释的难度层级。" + }, + { + "idx": 3949, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the ambient temperature likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "Increasing the temperature should increase the diffusivity and therefore increase the diffusion flux and flow rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述温度对氧气扩散速率的影响，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目需要理解扩散通量与温度的关系，并应用扩散定律进行简单分析，涉及多步概念关联和综合分析，但不需要复杂的推理或深度理解。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及扩散通量和稳态流量的概念关联，但解题步骤相对直接：只需理解温度对扩散系数的影响，并推导出其对流量增加的正面作用。不需要多角度分析或深度关联性分析，符合\"综合分析和说明\"的等级要求。" + }, + { + "idx": 3950, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the ambient partial pressure of oxygen gas likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "Increasing the concentration of oxygen in the ambient environment will increase the concentration gradient, thereby increasing the diffusion flux of oxygen.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么增加氧气分压会增加扩散通量，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对扩散通量基本公式的应用，即通过增加浓度梯度来提高扩散通量，属于直接套用基本原理的简单应用。 | 难度: 在简答题中属于较低难度，题目要求应用基本的扩散原理（浓度梯度与扩散通量的关系）来解释现象，解题步骤简单直接，仅需套用基本公式并给出简要说明，无需深入分析或多步骤推理。" + }, + { + "idx": 3951, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 16h duration at 757^{\\circ} C will raise the carbon concentration to 0.5 wt% at a point 2.3mm from the surface. Estimate the time necessary to achieve the same concentration at a 8mm position for an identical steel and at a carburizing temperature of 1130^{\\circ} C. Assume that D_{0} is 4.6 × 10^{-5}{m}^{2} / s and Q_{d} is 104kJ / mol.", + "answer": "the time necessary to achieve the same concentration at a 8mm position for an identical steel and at a carburizing temperature of 1130^{\\circ} C is 17.9h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和温度对扩散系数的影响，最终需要计算出一个具体的时间数值（17.9h）。 | 知识层次: 题目需要进行多步计算，包括扩散系数的计算、扩散方程的运用以及不同条件下的时间估算。虽然涉及公式的直接应用，但需要理解扩散机制和温度对扩散系数的影响，并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程和Arrhenius方程进行多步计算，涉及温度转换、距离与时间的关系计算，以及不同条件下的扩散系数调整。虽然计算步骤较多，但每一步都有明确的公式指导，属于中等应用层次的计算题。" + }, + { + "idx": 3952, + "question": "The diffusion coefficient for aluminum in silicon is D_{\\mathrm{Al}} in_{\\mathrm{Si}}=3 × 10^{-16} cm^{2} / s at 300 K (note that 300 K is about room temperature).\nWhat is a reasonable value for D_{\\mathrm{Al} \\text { in } \\mathrm{Si}} at 600 K ?\nNote: Rather than performing a specific calculation, you should be able to justify your answer from the options below based on the mathematical temperature dependence of the diffusion coefficient.\n(a) D<3 × 10^{16} cm^{2} / s\n(b) D=3 × 10^{16} cm^{2} / s\n(c) D=6 × 10^{16} cm^{2} / s\n(d) D=1.5 × 10^{16} cm^{2} /{s}\n(e) D>6 × 10^{16} cm^{2} /\n(f) D=6 × 10^{-17} cm^{2} / s", + "answer": "We expect the diffusion coefficient to increase if the temperature of this system is increased. Therefore, options (a), (b), (d), and (f) are eliminated.\nFurthermore, we expect that since the diffusion coefficient is exponentially dependent on temperature, the diffusivity should increase by more than a factor of two if the absolute temperature is doubled.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的多个选项中选择一个合理的扩散系数值，并基于扩散系数的温度依赖性进行判断。答案部分明确给出了选项的排除和选择过程，符合选择题的特征。 | 知识层次: 题目要求基于扩散系数的温度依赖性进行合理推断，需要理解扩散系数与温度的指数关系，并进行多步逻辑推理（排除不符合指数增长规律的选项）。这超出了简单记忆或直接套用公式的层次，但尚未达到需要复杂分析或创新应用的程度。 | 难度: 在选择题中属于较高难度，需要理解扩散系数的温度依赖性（阿伦尼乌斯方程），并能够进行概念性推理。题目要求在不进行具体计算的情况下，通过温度对扩散系数的影响趋势来排除错误选项并选择合理范围。这需要综合应用扩散理论和温度效应的知识，以及对指数关系的理解，属于复杂分析过程的判断。" + }, + { + "idx": 3953, + "question": "A specimen of some metal having a rectangular cross section 11.2mm × 12.4mm is pulled in tension with a force of 31200N, which produces only elastic deformation. Given that the elastic modulus of this metal is 63 \\mathrm{GPa}, calculate the resulting strain.", + "answer": "the resulting strain is 2.92 × 10^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（弹性模量公式）来求解应变，答案是一个具体的数值结果（2.92 × 10^{-3}），符合计算题的特征。 | 知识层次: 题目需要应用弹性模量的基本公式（应力=弹性模量×应变）进行简单计算，属于直接套用公式和基本单位换算的范畴，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用弹性模量的基本公式（应变=应力/弹性模量），并进行简单的数值计算即可得到结果。没有涉及多个公式的组合或复杂的解题步骤。" + }, + { + "idx": 3954, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 277 MPa and the modulus of elasticity is 117 GPa. What is the maximum load that may be applied to a specimen having a cross-sectional area of 327 mm^2 without plastic deformation?", + "answer": "the maximum load that may be applied without plastic deformation is 86,700 N.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应力、弹性模量和面积的关系）来求解最大载荷，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的应力计算和弹性模量的概念，需要应用简单的公式（应力=力/面积）进行计算，属于直接套用基本公式的简单应用。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用应力公式（应力=力/面积）进行简单数值计算，无需组合多个公式或进行复杂步骤。" + }, + { + "idx": 3955, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 277 MPa and the modulus of elasticity is 117 GPa. If the original specimen length is 148 mm, what is the maximum length to which it may be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen may be stretched without causing plastic deformation is 131.30 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最大拉伸长度，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的应力-应变关系和弹性模量的应用，仅需简单公式计算即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算，只需要使用弹性模量的基本公式（应变=应力/弹性模量）来计算最大弹性伸长量，然后加上原始长度。虽然涉及单位换算（MPa到GPa），但整体解题步骤直接且单一，不需要多个公式组合或复杂推导。" + }, + { + "idx": 3956, + "question": "A steel bar 100mm (4.0 in.) long and having a square cross section 20mm (0.8 in.) on an edge is pulled in tension with a load of 89,000N\\left(20,000 lb_{0}\\right), and experiences an elongation of 0.10mm (4.0 × 10^{-3} in.). Assuming that the deformation is entirely elastic, calculate the elastic modulus of the steel.", + "answer": "the elastic modulus of the steel is 223 \\text{ gpa} (31.3 × 10^6 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的材料参数（长度、截面积、载荷、伸长量）和弹性变形条件，应用胡克定律进行数值计算来求解钢的弹性模量。答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式（弹性模量计算公式）的直接应用和简单计算，不需要多步推导或综合分析，属于基础知识的简单应用层面。 | 难度: 在计算题-简单应用这一题型中，该题目仅需要单一公式的直接计算（弹性模量公式E=σ/ε），解题步骤简单明了，无需多个公式组合或复杂转换，属于该题型内最基础的难度等级。" + }, + { + "idx": 3957, + "question": "13: Typical relationship between E and G}\nFor most metals, the relationship between elastic and shear moduli is approximately which of the following?(a) G=0.1 E(b) G=0.2 E(c) G=0.3 E(d) G=0.4 E(e) G=0.5 E", + "answer": "the relationship between elastic and shear moduli for most metals is approximately g=0.4 e.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)到(e)中选择正确的弹性模量与剪切模量关系，符合选择题的特征 | 知识层次: 题目考查的是金属弹性模量（E）和剪切模量（G）之间关系的基本概念记忆，属于基础知识的直接应用，无需复杂分析或计算。 | 难度: 在选择题中属于简单难度，仅需直接记忆弹性模量（E）和剪切模量（G）之间的基本关系，无需复杂理解或分析。" + }, + { + "idx": 3958, + "question": "A cylindrical rod 380mm (15.0 in.) long and having a diameter of 10.0mm (0.40 in.), is to be subjected to a tensile load of 24,500 N (5500 lbf). Which of the four metals or alloys listed below will not experience plastic deformation under this load? The materials are: Aluminum alloy (Yield Strength: 255 MPa), Brass alloy (Yield Strength: 345 MPa), Copper (Yield Strength: 250 MPa), Steel alloy (Yield Strength: 450 MPa).", + "answer": "The materials that will not experience plastic deformation under the load of 24,500 N are the Brass alloy and Steel alloy, as their yield strengths (345 MPa and 450 MPa, respectively) are greater than the applied stress.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个金属或合金选项中选择不会发生塑性变形的材料，符合选择题的特征 | 知识层次: 题目主要考查对材料屈服强度的基本理解和简单应用，通过计算施加的应力并与各材料的屈服强度进行比较，从而判断哪些材料不会发生塑性变形。这个过程涉及基本的应力计算和直接比较，不需要多步计算或综合分析。 | 难度: 在选择题中属于简单难度，仅需应用基本应力公式（应力=力/面积）计算施加的应力，并与各材料的屈服强度直接比较。解题步骤简单直接，无需公式变形或多步骤选择。" + }, + { + "idx": 3959, + "question": "A cylindrical rod 380mm (15.0 in.) long and having a diameter of 10.0mm (0.40 in.), is to be subjected to a tensile load of 24,500 N (5500 lbf). Which of the four metals or alloys listed below will experience an elongation of no more than 0.9mm (0.035 in.) under this load? The materials are: Aluminum alloy (Modulus of Elasticity: 70 GPa), Brass alloy (Modulus of Elasticity: 100 GPa), Copper (Modulus of Elasticity: 110 GPa), Steel alloy (Modulus of Elasticity: 207 GPa).", + "answer": "The materials that will experience an elongation of no more than 0.9mm under the load of 24,500 N are the Brass alloy, Copper, and Steel alloy, as their calculated elongations (0.57 mm, 0.52 mm, and 0.57 mm, respectively) are less than or equal to 0.9 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算不同材料的伸长量来判断哪些材料满足伸长不超过0.9mm的条件。解答过程需要应用弹性模量公式进行数值计算，最终得出具体数值结果进行比较。 | 知识层次: 题目主要考查胡克定律的基本应用，需要计算不同材料的伸长量并与给定值比较。虽然涉及多个材料的计算，但每个计算步骤都是直接套用公式（应力=力/面积，应变=应力/弹性模量，伸长量=应变×原始长度），不需要复杂的分析或综合。属于基本公式的直接应用和简单计算范畴。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求应用胡克定律（Hooke's Law）进行单一公式的直接计算，涉及弹性模量、应力和应变的基本关系。虽然需要计算多个材料的伸长量，但每个计算都是独立的，且公式应用和计算步骤相对简单，没有复杂的推导或多步骤组合计算。" + }, + { + "idx": 3960, + "question": "Based on the previous two sub-questions, which of the four metals or alloys listed below are possible candidates for the cylindrical rod that will neither experience plastic deformation nor an elongation of more than 0.9mm under a tensile load of 24,500 N?", + "answer": "The only candidate material that satisfies both conditions is the Steel alloy, with an elongation of 0.57 mm.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从四个金属或合金选项中选择满足特定条件的候选材料，答案明确指出只有一个选项（Steel alloy）符合要求，符合选择题的特征。 | 知识层次: 题目要求基于前两个子问题的分析结果，综合考虑材料的塑性变形和伸长量限制，从多个选项中筛选出符合条件的金属或合金。这需要多步计算（如应力、应变计算）和概念关联（如材料性能与力学行为的联系），属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用多个材料科学概念（如塑性变形、弹性模量、应力应变关系）进行计算分析，并通过多步判断排除不符合条件的选项。题目要求考生在理解前两个子问题的基础上进行综合分析，涉及较复杂的计算过程和概念关联，属于需要复杂分析过程的判断题型。" + }, + { + "idx": 3961, + "question": "A tensile test is performed on a specimen of some metal alloy, and it is found that a true plastic strain of 0.12 is produced when a true stress of 280 MPa is applied. For this alloy, the value of the strain hardening exponent is 0.3 . On the basis of these data what true plastic strain would be expected for a total true plastic stress of 330 MPa ?", + "answer": "the true plastic strain expected for a total true plastic stress of 330 \\text{mpa} is 0.383.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的材料参数（应变硬化指数、真实塑性应变和真实应力）进行计算，以预测在另一个应力水平下的真实塑性应变。解答过程需要应用相关的材料科学公式（如幂律硬化模型），并进行数值计算。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用应变硬化公式进行多步计算，涉及对公式的理解和数值代入，但不需要复杂的推理或综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用应变硬化公式进行多步计算，并理解真应力和真应变之间的关系。虽然计算步骤明确，但需要正确关联概念和公式应用，属于中等偏上的难度。" + }, + { + "idx": 3962, + "question": "A cylindrical specimen of a metal alloy 48.8mm long and 9.09mm in diameter is stressed in tension. A true stress of 327 MPa causes the specimen to plastically elongate to a length of 55 mm. If it is known that the strain-hardening exponent for this alloy is 0.3 , calculate the true stress (in MPa )necessary to plastically elongate a specimen of this same material from a length of 48.8mm to a length of 57.6 mm.", + "answer": "390 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解真实应力，涉及应变硬化指数的使用和塑性伸长量的计算，最终要求得出具体的MPa数值。 | 知识层次: 题目需要进行多步计算，包括应变计算、应变硬化公式的应用以及数值求解。虽然不涉及复杂的机理分析或创新设计，但需要理解应变硬化行为并正确关联相关公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用应变硬化公式进行多步计算，涉及真实应力、应变和应变硬化指数的综合运用，但步骤和变量数量适中，未达到复杂多变量计算的程度。" + }, + { + "idx": 3963, + "question": "A three-point transverse bending test is conducted on a cylindrical specimen of aluminum oxide having a reported flexural strength of 390 MPa (56,600 psi). If the specimen radius is 2.5mm (0.10 in.) and the support point separation distance is 30mm (1.2 in.), predict whether or not you would expect the specimen to fracture when a load of 620 N (140 lbf) is applied.", + "answer": "Since the flexural strength for this test is 379 MPa (53,500 psi), which is less than the reported flexural strength of 390 MPa, fracture is not predicted. However, there is some chance of fracture due to variability in material strength.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来预测材料是否会断裂，涉及具体的数值计算和公式应用（如三点弯曲测试的强度计算）。答案中给出了具体的计算结果（379 MPa）并与报告值进行比较，这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用三点弯曲测试的公式来计算弯曲强度，并将计算结果与给定的弯曲强度进行比较。这涉及到公式的应用、数值计算和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用三点弯曲测试的公式进行多步计算，并综合分析材料强度与测试结果的关系。题目涉及多个变量的计算和比较，但未达到复杂多变量计算的程度。" + }, + { + "idx": 3964, + "question": "Calculate the value of flexural strength for this test given a cylindrical specimen of aluminum oxide with a radius of 2.5mm (0.10 in.) and a support point separation distance of 30mm (1.2 in.) when a load of 620 N (140 lbf) is applied.", + "answer": "The flexural strength for this test is 379 MPa (53,500 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（半径、支撑点距离、载荷）应用公式计算弯曲强度，答案是一个具体的数值结果（379 MPa），符合计算题的特征。 | 知识层次: 题目要求使用基本的弯曲强度公式进行计算，涉及简单的数值代入和单位转换，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的弯曲强度公式（σ = 3FL/2πr³），代入给定的数值进行计算即可。不需要多个公式组合或复杂的解题步骤，属于最基础的计算题类型。" + }, + { + "idx": 3965, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{cc} \\hline \\sigma_{\\mathrm{fs}} (MPa) & \\mathbf{P} \\ \\hline 100 & 0.05 \\ 50 & 0.20 \\ \\hline \\end{tabular} (a) Compute the flexural strength for a completely nonporous specimen of this material.", + "answer": "the flexural strength for a completely nonporous specimen of this material is 126 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据（弯曲强度和孔隙率）进行计算，以得出无孔隙材料的弯曲强度。答案是一个具体的数值计算结果（126 MPa），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用公式进行多步计算，涉及孔隙率与弯曲强度之间的关系，需要综合分析数据并推导出无孔隙情况下的强度值。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求根据给定的孔隙率和弯曲强度数据，通过公式推导计算出无孔隙材料的弯曲强度。虽然计算步骤不算极其复杂，但需要理解材料性能与孔隙率之间的关系，并正确应用相关公式进行综合分析。" + }, + { + "idx": 3966, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{cc} \\hline \\sigma_{\\mathrm{fs}} (MPa) & \\mathbf{P} \\ \\hline 100 & 0.05 \\ 50 & 0.20 \\ \\hline \\end{tabular} (b) Compute the flexural strength for a 0.10 volume fraction porosity.", + "answer": "the flexural strength for a 0.10 volume fraction porosity is 79.4 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的数据计算特定孔隙率下的弯曲强度，需要使用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求根据给定的数据应用公式进行计算，属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目提供了两个数据点，需要根据给定的体积分数孔隙率和抗弯强度之间的关系进行插值或简单公式推导。虽然需要理解材料性能与孔隙率的关系，但解题步骤相对直接，仅涉及基本公式应用和简单计算，不涉及多个公式组合或复杂推导过程。" + }, + { + "idx": 3967, + "question": "Mechanical twinning occurs in metals having which type(s) of crystal structure(s)?(a) \\mathrm{BCC}(b) \\mathrm{FCC}(c) \\mathrm{HCP}", + "answer": "Mechanical twinning occurs in metals having B C C and H C P crystal structures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对金属晶体结构中机械孪生现象发生条件的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏易难度，需要理解机械孪生的基本概念并辨析其在不同晶体结构中的发生条件。虽然涉及BCC、FCC、HCP三种晶体结构的记忆，但只需掌握\"机械孪生主要发生在BCC和HCP结构\"这一关键知识点即可作答，不需要复杂的分析过程。比单纯记忆定义稍难，但明显低于需要多概念交叉分析的题目难度。" + }, + { + "idx": 3968, + "question": "How does grain size influence strength of a polycrystalline material?(a) Strengthfine-grained < strength _{\\text {course-grained }}(b) Strength _{\\text {fine-grained }}= strength _{\\text {course-grained }}(c) Strengthfine-grained > strength _{\\text {course-grained }}", + "answer": "A fine-grained material is stronger than a coarse-grained material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了多个选项（a, b, c）并要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对晶粒尺寸与多晶材料强度关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于中等偏下难度，需要理解晶粒尺寸对多晶材料强度影响的基本原理（霍尔-佩奇关系），并进行简单辨析。虽然涉及概念理解，但选项设置较为直接，不涉及复杂概念区分或深度推理。" + }, + { + "idx": 3969, + "question": "Reducing the grain size of metal improves toughness.(a) True(b) False", + "answer": "True. Reducing the grain size of a metal improves its toughness.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断结果 | 知识层次: 题目考查对金属晶粒尺寸与韧性关系这一基本概念的记忆和理解 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆金属晶粒尺寸与韧性关系的基础知识即可作答，无需复杂理解或分析步骤，在同题型内属于最基础难度等级。" + }, + { + "idx": 3970, + "question": "As dislocation density increases, the resistance to dislocation movement(a) increases.(b) decreases.", + "answer": "As dislocation density increases, the resistance to dislocation movement increases. This phenomenon is responsible for cold working.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对位错密度与位错运动阻力之间关系的基本概念记忆和理解，属于材料科学中的基本原理知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆基础概念（位错密度增加导致位错运动阻力增加），无需理解或辨析复杂概念。" + }, + { + "idx": 3971, + "question": "On the average, dislocation-dislocation strain interactions are(a) repulsive.(b) attractive.", + "answer": "On the average, dislocation-dislocation strain interactions are repulsive.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案 | 知识层次: 题目考查位错-位错应变相互作用的基本概念，属于基础概念的记忆和理解范畴，不需要复杂的分析或应用。 | 难度: 在选择题中属于简单难度，仅需直接记忆位错-位错应变相互作用的基本性质（排斥性），无需进行概念辨析或复杂分析。" + }, + { + "idx": 3972, + "question": "As a metal is strain hardened, its ductility(a) increases(b) decreases", + "answer": "As a metal is strain hardened, its ductility decreases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查金属应变硬化后延展性变化的基本概念记忆，属于基础概念的记忆和理解层次 | 难度: 在选择题中属于简单难度，仅需直接记忆金属应变硬化与延展性的基本关系，无需复杂理解或分析。" + }, + { + "idx": 3973, + "question": "Most metals strain harden at room temperature.(a) True(b) False", + "answer": "True. Most metals strain harden at room temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案形式为True或False，符合判断题的特征 | 知识层次: 题目考查对金属应变硬化这一基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问\"大多数金属在室温下会应变硬化\"这一基础事实的正确性，不需要进行概念理解或复杂分析，仅需记忆金属材料的基本特性即可作答。这符合判断题中最基础的难度等级要求。" + }, + { + "idx": 3974, + "question": "During the recovery of a cold-worked material, is some of the internal strain energy relieved?", + "answer": "Some of the internal strain energy is relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即是否在冷加工材料的恢复过程中部分内应变能被释放）。答案直接给出了判断结果（部分内应变能被释放），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中内部应变能变化的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问冷加工材料恢复过程中是否释放部分内应变能，这是材料科学中关于冷加工和恢复过程的基础定义性知识。学生只需记忆相关基础概念即可正确判断，无需深入理解或分析复杂概念。" + }, + { + "idx": 3975, + "question": "During the recovery of a cold-worked material, is all of the internal strain energy relieved?", + "answer": "All of the internal strain energy is not relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is all of the internal strain energy relieved?\"），而答案直接给出了对错判断（\"All of the internal strain energy is not relieved.\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料回复过程中内应变能变化的基本概念记忆和理解，属于基础概念层次 | 难度: 在判断题中属于中等难度，需要理解冷加工恢复过程中内部应变能量的释放情况，而不仅仅是记忆基本概念。虽然题目涉及的是基础概念，但需要对概念有一定的理解才能正确判断陈述的对错。" + }, + { + "idx": 3976, + "question": "During the recovery of a cold-worked material, is there some reduction in the number of dislocations?", + "answer": "There is some reduction in the number of dislocations.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即\"During the recovery of a cold-worked material, is there some reduction in the number of dislocations?\"），而答案直接给出了对错判断（\"There is some reduction in the number of dislocations.\"）。这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中位错数量变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问冷加工材料恢复过程中位错数量是否减少，这是材料科学中关于位错行为的基础概念记忆题。学生只需回忆相关定义即可作答，无需进行概念理解或复杂分析，因此属于该题型内最基础的难度等级。" + }, + { + "idx": 3977, + "question": "During the recovery of a cold-worked material, is there a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state?", + "answer": "There is not a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了对陈述的判断（否定），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中位错数量变化的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基础难度，仅需记忆冷加工恢复过程中位错数量的基本概念即可判断正误，不涉及复杂理解或分析过程。" + }, + { + "idx": 3978, + "question": "During the recovery of a cold-worked material, is the electrical conductivity recovered to its precold-worked state?", + "answer": "The electrical conductivity is recovered to its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即是否恢复到冷加工前的状态），答案直接给出了对陈述的判断（恢复到了冷加工前的状态）。这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中电导率变化的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问冷加工材料恢复过程中电导率是否恢复到原始状态，答案只需记忆基础概念即可判断对错，无需深入理解或分析复杂概念。" + }, + { + "idx": 3979, + "question": "During the recovery of a cold-worked material, is the thermal conductivity recovered to its precold-worked state?", + "answer": "The thermal conductivity is recovered to its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"is the thermal conductivity recovered to its precold-worked state?\"），答案直接给出了对错判断（\"The thermal conductivity is recovered to its precold-worked state.\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中热导率变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问冷加工材料恢复过程中热导率是否恢复到冷加工前的状态，答案明确且直接基于基础概念记忆。不需要复杂的理解或分析步骤，只需记住相关基本原理即可正确回答。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 3980, + "question": "During the recovery of a cold-worked material, does the metal become more ductile, as in its precold-worked state?", + "answer": "The metal does not become more ductile, as in its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（金属是否恢复到冷加工前的延展性状态），答案直接给出了对错判断。这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中性能变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在判断题的基础概念记忆层次中，此题仅需判断冷加工恢复过程中金属延展性是否恢复到原始状态这一基本概念的正误，不涉及复杂概念或理解深度的要求，属于最基础的记忆性判断。" + }, + { + "idx": 3981, + "question": "During the recovery of a cold-worked material, are grains with high strains replaced with new, unstrained grains?", + "answer": "Grains with high strains are not replaced with new, unstrained grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"are grains with high strains replaced with new, unstrained grains?\"），答案直接给出了对错判断（\"Grains with high strains are not replaced with new, unstrained grains.\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料回复过程中晶粒变化的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆冷加工材料恢复过程中晶粒变化的基本原理即可作答，不涉及概念理解或复杂陈述的判断。" + }, + { + "idx": 3982, + "question": "During the recrystallization of a cold-worked material, is some of the internal strain energy relieved?", + "answer": "All of the internal strain energy is relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is some of the internal strain energy relieved?\"），而答案直接给出了判断结果（\"All of the internal strain energy is relieved.\"）。这符合判断题的特征，即对陈述的真伪进行判断。 | 知识层次: 题目考查对再结晶过程中内应变能变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆材料科学中关于再结晶过程的基本原理即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 3983, + "question": "During the recrystallization of a cold-worked material, is there some reduction in the number of dislocations?", + "answer": "There is significant reduction in the number of dislocations.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即冷加工材料再结晶过程中位错数量是否减少），答案直接给出了对错判断（位错数量显著减少）。这符合判断题的特征。 | 知识层次: 题目考查对再结晶过程中位错数量变化的基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆并确认\"再结晶过程中位错数量是否显著减少\"这一基础概念即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 3984, + "question": "During the recrystallization of a cold-worked material, does the metal become more ductile, as in its precold-worked state?", + "answer": "The metal becomes more ductile, as in its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（金属是否变得更延展），答案直接给出了对错判断（变得更延展），符合判断题的特征 | 知识层次: 题目考查对冷加工材料再结晶后性能变化的基础概念记忆和理解，属于材料科学中金属加工和性能变化的基本知识点。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆冷加工后金属在再结晶过程中会恢复延展性这一基础概念即可作答，无需深入理解或分析。" + }, + { + "idx": 3985, + "question": "During the recrystallization of a cold-worked material, are grains with high strains replaced with new, unstrained grains?", + "answer": "Grains with high strains are replaced with new, unstrained grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了判断结果（陈述为真）。这符合判断题的特征。 | 知识层次: 题目考查对再结晶过程中晶粒变化的基本概念的记忆和理解，属于基础概念层次。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆材料科学中关于再结晶过程的基本原理即可作答，无需深入理解或分析复杂概念。在判断题题型内属于最基础的难度等级。" + }, + { + "idx": 3986, + "question": "Grain growth requirements\n}\nGrain growth must always be preceded by recovery and recrystallization.(a) True(b) False", + "answer": "False. Grain growth does not always need to be preceded by recovery and recrystallization; it may occur in materials that have not been cold worked.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（True/False），并且答案明确给出了判断结果和解释。 | 知识层次: 题目考查对晶粒生长基本概念的记忆和理解，涉及晶粒生长与回复和再结晶之间的关系，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然题目涉及基础概念记忆，但需要理解晶粒生长的前提条件并非总是需要回复和再结晶过程，这比单纯记忆定义稍复杂，但不需要分析多个概念的交互关系。" + }, + { + "idx": 3987, + "question": "A hypothetical metal alloy has a grain diameter of 2.4 × 10^{-2} mm. After a heat treatment at 575^{\\circ} C for 500min, the grain diameter has increased to 7.3 × 10^{-2} mm. Compute the time required for a specimen of this same material (i.e., \\mathrm{d}_{0}=2.4 × 10^{-2}mm ) to achieve a grain diameter of 5.5 × 10^{-2}mm while being heated at 575^{\\circ} C. Assume the N grain diameter exponent has a value of 2.2.", + "answer": "the time required for the specimen to achieve a grain diameter of 5.5 × 10^{-2} mm is 246min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解时间，涉及金属合金晶粒直径的变化和热处理时间的计算，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式应用和数值计算，需要理解晶粒生长动力学的基本原理，并能够将给定的参数代入公式进行求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要应用晶粒生长动力学公式（如Beck方程），涉及多步计算和参数代入。题目要求从已知条件推导时间参数，需要理解晶粒直径与时间的关系，并正确应用指数参数N=2.2进行计算。虽然计算过程明确，但需要综合分析能力和对材料科学基础概念的掌握。" + }, + { + "idx": 3988, + "question": "Tensile strengths and number-average molecular weights for two polymers are as follows:\nTensile strength Number average molecular weight\n(MPa)\n(\\mathrm{g} / mol)\n37.7\n36800\n131\n62400\nEstimate the tensile strength (in MPa) for a number-average molecular weight of 51500g / mol.", + "answer": "the tensile strength for a number-average molecular weight of 51500g/mol is 95.2 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了两组数据（拉伸强度和数均分子量），要求根据这些数据估算另一个分子量下的拉伸强度。这需要通过数值计算和可能的插值或外推公式来完成。答案是一个具体的数值（95.2 MPa），表明这是一个计算题。 | 知识层次: 题目要求根据给定的数据点进行简单的线性插值计算，属于基本公式应用和直接套用的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要根据给定的数据点进行线性插值或外推计算，但不需要复杂的公式组合或多步骤推导。" + }, + { + "idx": 3989, + "question": "Tensile strengths and number-average molecular weights for two polymers are as follows\n\\[\n\\begin{array}{l}\n\\text { Tensile strength Number average molecular weight } \\\\\n(MPa) \\\\\n138 \\\\\n184 \\\\\n\\text { (g/mol) } \\\\\n12600 \\\\\n28100\n\\end{array}\n\\]\nEstimate number average molecular weight (in \\mathrm{g} / mol ) at a tensile strength of 141 MPa.", + "answer": "the estimated number average molecular weight at a tensile strength of 141 \\, MPa is 14600 \\, \\mathrm{g/mol}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了两组数据（拉伸强度和数均分子量），要求根据给定的拉伸强度估算数均分子量。这需要通过数值计算和可能的插值或外推方法来完成。答案是一个具体的数值（14600 g/mol），表明这是一个计算题。 | 知识层次: 题目要求根据给定的数据估算分子量，涉及基本的公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目提供了两组数据点（拉伸强度和数均分子量），要求根据给定的拉伸强度估算对应的数均分子量。这需要理解拉伸强度与分子量之间的关系，并可能涉及简单的线性插值或外推计算。虽然需要应用基本公式和进行数值计算，但解题步骤相对直接，不涉及多个公式的组合或复杂的推导过程。" + }, + { + "idx": 3990, + "question": "The bonding forces between adhesive and adherend surfaces are thought to be(a) Electrostatic(b) Covalent(c) Chemical", + "answer": "The bonding forces between adhesive and adherend surfaces are thought to be electrostatic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对粘合剂与被粘物表面结合力类型的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解静电力和化学键的区别，但不需要进行复杂的分析或比较多个概念。题目主要考察对粘附力类型的基本理解，属于概念理解和简单辨析的层次。" + }, + { + "idx": 3991, + "question": "Deformation of a semicrystalline polymer by drawing produces which of the following in the direction of drawing?", + "answer": "Increase in strength in the direction of drawing.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对半结晶聚合物变形行为的基础概念记忆，只需知道拉伸会导致强度增加这一基本原理即可回答，无需复杂分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要理解半结晶聚合物在拉伸过程中的行为变化，并能够将这一概念与材料性能变化联系起来。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，而非纯粹的直接记忆。" + }, + { + "idx": 3992, + "question": "Deformation of a semicrystalline polymer by drawing produces which of the following perpendicular to the direction of drawing?", + "answer": "Decrease in strength perpendicular to the direction of drawing.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，虽然题目中没有明确列出选项，但答案是以选项形式给出的单一结论，符合选择题的特征 | 知识层次: 题目考查半结晶聚合物在拉伸变形后性能变化的基本概念记忆，属于对基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解半结晶聚合物在拉伸变形时的基本行为特征，但不需要进行复杂的比较分析。题目考察的是对拉伸方向与强度变化关系的简单理解，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 3993, + "question": "How does deformation by drawing of a semicrystalline polymer affect its tensile strength?(a) Increases(b) Decreases", + "answer": "Deformation by drawing increases the tensile strength of a semicrystalline polymer. This effect is due to the highly oriented chain structure that is produced by drawing, which gives rise to higher interchain secondary bonding forces.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从给定的选项（a）和（b）中选择正确答案，符合选择题的特征。 | 知识层次: 题目不仅需要理解半晶态聚合物的基本特性，还需要分析拉伸变形对其微观结构（如分子链取向）的影响，并进一步关联到宏观力学性能（拉伸强度）的变化。这涉及多步概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解半结晶聚合物在拉伸变形过程中的微观结构变化（如分子链取向）及其对宏观力学性能（拉伸强度）的影响机制。虽然不涉及多步计算，但要求将材料结构特征与性能变化进行关联分析，属于多概念综合选择类型。" + }, + { + "idx": 3994, + "question": "How does increasing the degree of crystallinity of a semicrystalline polymer affect its tensile strength?(a) Increases\n\\mathrm{b}) Decreases", + "answer": "Increasing the degree of crystallinity of a semicrystalline polymer leads to an increase in its tensile strength. This is due to enhanced interchain bonding and forces in crystalline regions; in response to applied stresses, interchain motions become more restrained as degree of crystallinity increases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目不仅需要理解结晶度对聚合物拉伸强度影响的基本概念，还需要分析结晶区域分子链间相互作用增强的机理，属于中等应用层次的知识运用。 | 难度: 在选择题中属于中等难度，需要理解半结晶聚合物的结晶度与拉伸强度之间的关系，并综合分析结晶区域对分子链运动的限制作用。虽然涉及多个概念的关联，但不需要复杂的计算或高难度的综合应用判断。" + }, + { + "idx": 3995, + "question": "How does increasing the molecular weight of a semicrysatlline polymer affect its tensile strength?(a) Increases(b) Decreases\n\\", + "answer": "The tensile strength of a semicrystalline polymer increases with increasing molecular weight. This effect is explained by the increased chain entanglements at higher molecular weights.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对半结晶聚合物分子量与其拉伸强度关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于中等偏下难度，需要理解分子量增加对半结晶聚合物拉伸强度的影响机制，但选项较为直接，只需简单辨析即可得出正确答案。" + }, + { + "idx": 3996, + "question": "Which kind of fracture (ductile or brittle) is associated with intergranular crack propagation?", + "answer": "Intergranular fracture is brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要文字解释和论述来回答关于断裂类型的问题，而不是从选项中选择或判断对错 | 知识层次: 题目考查对断裂类型（韧性断裂和脆性断裂）的基本概念记忆，以及晶间裂纹扩展与脆性断裂的关联理解，属于基础概念的记忆和简单应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义和分类（脆性断裂与延性断裂的区别），属于最基础的概念记忆层面。题目明确指向\"intergranular crack propagation\"这一特定断裂类型，答案只需直接对应\"brittle\"这一核心特征，无需展开解释或论述其他相关概念体系。在简答题-基础概念记忆这一分类中，属于最简单的等级1难度。" + }, + { + "idx": 3997, + "question": "Which kind of fracture (ductile or brittle) is associated with transgranular crack propagation?", + "answer": "Transgranular fracture is brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种断裂类型与穿晶裂纹扩展相关，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对断裂类型（韧性断裂和脆性断裂）的基本概念记忆，特别是与穿晶裂纹扩展相关的断裂类型。这属于基础概念的记忆和理解层次，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答断裂类型与晶间裂纹扩展的关联性，属于基础定义简答。题目仅涉及单一概念（脆性断裂）的识别，无需展开解释或复杂论述，符合等级1对记忆性知识点的基本要求。" + }, + { + "idx": 3998, + "question": "The fracture strength of glass may be increased by etching away a thin surface layer. It is believed that the etching may alter the surface crack geometry (i.e. reduce crack length and increase tip radius). Calculate the ratio of the etched and original crack tip radii if the fracture strength is increased by a factor of 7 when 28% of the crack length is removed.", + "answer": "the ratio of the etched and original crack tip radii is: \\[\n\\frac{\\rho_{t}^{\\prime}}{\\rho_{t}} = 32\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解蚀刻前后裂纹尖端半径的比值，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及裂纹几何变化对断裂强度的影响，需要应用相关公式并综合分析裂纹长度和尖端半径的变化关系。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解断裂强度的相关概念，应用公式进行多步计算，并综合分析表面裂纹几何变化对强度的影响。虽然涉及多步骤计算，但题目提供了明确的计算路径和已知条件，不需要处理复杂多变量或高度抽象的数学推导。" + }, + { + "idx": 3999, + "question": "A structural component in the shape of a flat plate 27.3mm thick is to be fabricated from a metal alloy for which the yield strength and plane strain fracture toughness values are 535 MPa and 31.3 MPa·m^{-1 / 2}, respectively. For this particular geometry, the value of Y is 1.8 . Assuming a design stress of 0.5 times the yield strength, calculate the critical length of a surface flaw.", + "answer": "the critical length of a surface flaw is 2.0 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界表面缺陷长度，答案是一个具体的数值结果（2.0 mm），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括设计应力的计算、临界裂纹长度的公式应用（K_IC = Y * σ * sqrt(πa)），以及相关参数的代入和求解。虽然不涉及复杂的综合分析或机理解释，但需要理解断裂力学的基本概念和公式的正确应用。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及设计应力、几何因子和临界裂纹长度的综合求解，但变量关系相对明确，计算步骤虽多但逻辑清晰。" + }, + { + "idx": 4000, + "question": "How would the plane strain fracture toughness of a metal be expected to change with rising temperature?(a) Increase(b) Decrease(c) Remain constant", + "answer": "The magnitude of the plane strain fracture toughness, K_{i c}, diminishes with decreasing temperature; therefore as temperature increases, K_{i c}, should also increase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a、b、c）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对平面应变断裂韧性随温度变化的基本理解，属于基本概念的直接应用，不需要复杂的分析或多步推理。 | 难度: 在选择题中属于简单难度，仅需直接应用基本概念（温度对断裂韧性的影响）即可选择正确答案，无需复杂计算或多步骤推理。" + }, + { + "idx": 4001, + "question": "Does increasing temperature favor brittle fracture in polymers?", + "answer": "No, increasing temperature does not favor brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了\"是/否\"的判断。 | 知识层次: 题目考查对聚合物断裂行为与温度关系这一基本概念的记忆和理解，属于基础概念层次的知识点。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。只需要记忆聚合物温度与断裂行为的基本关系即可作答，不涉及概念理解或复杂陈述的判断。属于该题型内最基础的难度等级。" + }, + { + "idx": 4002, + "question": "Does increasing strain rate favor brittle fracture in polymers?", + "answer": "Yes, increasing strain rate favors brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"Does increasing strain rate favor brittle fracture in polymers?\"），而答案直接给出了\"是\"或\"否\"的判断（\"Yes\"）。这符合判断题的特征。 | 知识层次: 题目考查聚合物应变速率与脆性断裂关系的基本概念记忆和理解，属于基础理论知识范畴。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然问题涉及聚合物力学行为的基本概念，但需要理解应变速率与断裂模式之间的关系，而不仅仅是简单记忆定义。这比纯粹的正误判断（等级1）要求更高的概念理解，但尚未达到需要分析复杂概念陈述的等级3难度。" + }, + { + "idx": 4003, + "question": "Does the presence of a sharp notch favor brittle fracture in polymers?", + "answer": "Yes, the presence of a sharp notch favors brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"Does the presence...\"），而答案直接给出了\"yes\"的判断，符合判断题的特征。 | 知识层次: 题目考查对聚合物断裂行为的基本概念的理解，即尖锐缺口对聚合物脆性断裂的影响，属于基础概念的记忆和理解层面。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问尖锐缺口是否有利于聚合物的脆性断裂，这属于对基础概念的记忆性知识，不需要复杂的理解或分析。学生只需回忆相关定义或基本原理即可作答，因此属于该题型内最低难度等级。" + }, + { + "idx": 4004, + "question": "Does decreasing specimen thickness favor brittle fracture in polymers?", + "answer": "No, decreasing specimen thickness does not favor brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了\"是/否\"的判断。这符合判断题的特征，即判断某个陈述的真伪。 | 知识层次: 题目考查对聚合物断裂行为的基本概念的理解，属于基础概念记忆范畴，不需要复杂的分析或综合应用。 | 难度: 在判断题中属于中等难度，需要理解聚合物断裂行为与试样厚度之间的关系，而不仅仅是记忆基本定义。虽然不涉及复杂概念的判断，但需要对\"脆性断裂\"和\"厚度影响\"有基本理解才能正确作答。" + }, + { + "idx": 4005, + "question": "A plate of an alloy steel has a plane-strain fracture toughness of 50 MPa·{m}^{1 / 2}. If it is known that the largest surface crack is 0.5mm long, and that the value of Y is 1.1 , which of the following can be said about this plate when a tensile stress of 1200 MPa is applied?(a) The plate will definitely fracture.(b) The plate will definitely not fracture. c) It is not possible to determine whether or not the plate will fracture.", + "answer": "the plate will definitely fracture.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目提供了多个选项（a, b, c），要求从中选择关于合金钢板在给定条件下是否会断裂的正确陈述。答案形式为选择其中一个选项。 | 知识层次: 题目需要应用断裂力学的基本公式（K_IC = Yσ√(πa)）进行计算，并综合分析计算结果与给定条件的关系，判断材料是否会断裂。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用断裂力学知识进行多步计算和判断。题目要求考生理解平面应变断裂韧性、裂纹长度、几何因子和应力之间的关系，并通过计算临界应力与施加应力的比较来判断是否会发生断裂。这涉及多个概念的关联和综合分析，解题步骤较为复杂，属于复杂分析过程的判断题型。" + }, + { + "idx": 4006, + "question": "The effect of a stress raiser is more significant for which of the following types of materials?(a) Brittle materials(b) Ductile materials", + "answer": "The effect of a stress raiser is more significant for brittle materials. For a ductile material, plastic deformation ensues when the maximum stress exceeds the yield strength. This leads to a more uniform distribution of stress in the vicinity of the stress raiser and to the development of a maximum stress concentration factor less than the theoretical value. Such yielding and stress redistribution do not occur to any appreciable extent around flaws and discontinuities in brittle materials; therefore, essentially the theoretical stress concentration will result.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项（a）和（b）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对脆性材料和韧性材料在应力集中效应上的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于中等偏下难度，需要理解脆性材料和韧性材料的基本特性及其对应力集中的不同反应。虽然涉及概念辨析，但不需要复杂的分析步骤，属于基础概念理解和简单应用范畴。" + }, + { + "idx": 4007, + "question": "A structural component is fabricated from an alloy that has a plane strain fracture toughness of 45 MPa. It has been determined that this component fails at a stress of 300 MPa when the maximum length of a surface crack is 0.95 mm. What is the maximum allowable surface crack length (in mm ) without fracture for this same component exposed to a stress of 300 MPa and made from another alloy with a plane strain fracture toughness of 100.0 MPa ? The geometry factor Y is the same in both cases.", + "answer": "the maximum allowable surface crack length without fracture is 1.55 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最大允许的表面裂纹长度，答案是一个具体的数值结果（1.55 mm），解答过程涉及材料科学中的断裂力学公式应用。 | 知识层次: 题目需要进行多步计算，涉及平面应变断裂韧性和应力强度因子的概念关联，需要综合分析不同合金的性能差异并应用相关公式求解最大允许裂纹长度。虽然不涉及复杂的机理分析或创新设计，但比简单应用更深入。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及不同材料的参数替换和综合分析，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4008, + "question": "A cylindrical specimen 7.5mm in diameter of an S-590 alloy is to be exposed to a tensile load of 9000 N. At approximately what temperature will the steady-state creep be 10^{-2}h^{-1} ?", + "answer": "approximately 815^\\circ C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定条件下的温度值。答案是一个具体的数值（815°C），这表明需要通过计算或查表等方法得出结果。 | 知识层次: 题目需要进行多步计算，包括应用蠕变速率公式和材料性能数据，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求根据给定的材料参数和力学条件，通过公式应用和数值计算确定特定温度，涉及对材料科学和力学知识的综合分析。虽然计算步骤明确，但需要理解并正确应用相关公式，属于中等应用层次的计算题。" + }, + { + "idx": 4009, + "question": "The mineral olivine is a solid solution of the silicate compounds forsterite \\left(Mg_{2} \\mathrm{SiO}_{4}\\right) and fayalite \\left(\\mathrm{Fe}_{2} \\mathrm{SiO}_{4}\\right).\nHow many chemical components are there in a sample of olivine?\n(a) 1\n(b) 2\n(c) 3\n(d) 4", + "answer": "The components of a system are defined to be the smallest set of independently variable chemical constituents that are necessary to describe the composition of each phase that is present in a system. Components are chemically distinct. In this case, we only need to specify two things. It is convenient to simply use the compounds themselves as the components, but other options exist. For instance, specifying the amount of Mg and \\mathrm{Fe} in the system automatically fixes the \\mathrm{Si} and \\mathrm{O} content, assuming the compounds are present in their stoichiometric ratios (assuming they are defect free).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)、(d)中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对化学组分定义的基础概念记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题中属于中等难度，需要理解化学组分的基本定义，并能将其应用到具体矿物固溶体案例中。虽然题目涉及基础概念记忆，但需要一定的辨析能力来判断哪些化学物质可以被视为独立组分。解题过程需要理解\"最小独立变量\"的概念，但不需要复杂的推导或计算。" + }, + { + "idx": 4010, + "question": "Seawater, which covers the majority of the earth, is composed primarily of molecules of H_{2} \\mathrm{O} and equal numbers of \\mathrm{Na}^{+}ions and \\mathrm{Cl}^{-}ions. Suppose we have a thoroughly mixed solution (containing these species only) at 25^{\\circ} C. How many components and how many phases are in such a system?\n(a) 1 component, 1 phase\n(b) 1 component, 2 phase\n(c) 1 component, 3 phase\n(d) 1 component, 4 phase\n(e) 2 component, 1 phase\n(f) 2 component, 2 phase\n(g) 2 component, 3 phase\n(h) 2 component, 4 phase\n(i) 3 component, 1 phase\n(j) 3 component, 2 phase\n(k) 3 component, 3 phase(l) 3 component, 4 phase\n(m) 4 component, 1 phase\n(n) 4 component, 2 phase\n(o) 4 component, 3 phase\n(p) 4 component, 4 phase", + "answer": "(e) 2 component, 1 phase", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了多个选项供选择。 | 知识层次: 题目考查对组分和相这两个基本概念的理解和记忆，属于材料科学中的基础概念问题。 | 难度: 在选择题中属于中等偏下难度，需要理解组分和相的定义，并能简单辨析。题目明确给出了系统组成（H2O、Na+、Cl-），且说明是\"thoroughly mixed solution\"，因此只需识别出独立组分数为2（H2O和NaCl），相数为1（均匀溶液）。虽然涉及基本概念的理解，但不需要复杂的分析过程。" + }, + { + "idx": 4011, + "question": "Is solid ductile cast iron (ferrite solid solution + embedded graphite spheres) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is solid ductile cast iron... a two-phase material system?\"），答案直接给出了\"是/否\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及材料组成和相的定义，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目涉及对两相材料系统的定义理解，需要考生不仅记住基本概念，还要能够应用这些概念来判断具体材料是否属于两相系统。虽然不涉及复杂概念的判断，但比单纯记忆基本概念的正误判断要稍难一些。" + }, + { + "idx": 4012, + "question": "Is solid sodium chloride (salt, NaCl) a two-phase material system?", + "answer": "No, it is a single-phase compound, not a solution. The ratio of the two ions is in a fixed stoichiometry and they adopt an orderly arrangement in the crystal.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is solid sodium chloride a two-phase material system?\"），答案直接给出了对错判断（\"No\"）并进行了简要解释，符合判断题的特征。 | 知识层次: 题目考查对单相和多相材料系统的基本概念的理解，需要记忆和识别NaCl的晶体结构和化学计量比特性，属于基础概念记忆层次。 | 难度: 在判断题的基础概念记忆题型中，该题目仅需判断固体氯化钠是否为两相材料系统这一基本概念的正误。题目直接考察对单相化合物定义的理解，不涉及复杂概念或需要推理的步骤，属于最基础的概念正误判断层级。" + }, + { + "idx": 4013, + "question": "Is liquid bronze (Cu + Sn liquid solution) a two-phase material system?", + "answer": "No, it is a liquid solution, and solutions are single-phase by definition.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（判断液态青铜是否为两相材料系统），答案直接给出了对错的结论和简要解释。 | 知识层次: 题目考查对相和溶液定义的基本概念记忆和理解，属于基础概念层次 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对\"溶液是单相系统\"这一基础定义的记忆，无需复杂推理或概念间的关联分析，符合等级1的简单判断标准。" + }, + { + "idx": 4014, + "question": "Is solid gray cast iron (ferrite solid solution + embedded graphite flakes) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is solid gray cast iron...a two-phase material system?\"），答案直接给出了\"是/否\"的判断并附带解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及材料组成和相的定义，属于基础概念层次。 | 难度: 在判断题中属于中等难度，需要理解\"两相材料系统\"的定义，并能将其应用到具体的材料案例（灰口铸铁）中。虽然不涉及复杂的概念组合或分析，但需要超越简单的定义记忆，达到概念应用的理解层次。" + }, + { + "idx": 4015, + "question": "Is solid aluminum featuring dissolved silicon a two-phase material system?", + "answer": "No, it is a solid solution since silicon is implied to substitute for aluminum. Solutions are single-phase by definition.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断\"固体铝中溶解硅是否为两相材料系统\"这一陈述的对错，答案直接给出了\"否\"的判断并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对固溶体和两相系统基本定义的记忆和理解，属于基础概念层次。 | 难度: 在判断题中属于中等难度，需要理解\"固溶体\"和\"两相系统\"的定义区别，并能够根据题目描述判断硅在铝中的溶解行为属于固溶体而非两相系统。这超出了简单的定义记忆（等级1），但不需要处理复杂概念（等级3）。" + }, + { + "idx": 4016, + "question": "Is solid lead-tin solder (a mixture of Pb-rich and Sn-rich solid solutions) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断\"solid lead-tin solder是否为two-phase material system\"这一陈述的正确性，答案直接给出了\"Yes\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及材料相的定义和分类，属于基础概念层次。 | 难度: 在判断题中属于中等难度，需要理解两相材料系统的定义和特征，并能正确判断铅锡焊料是否符合这一标准。虽然题目涉及基础概念，但需要一定的概念理解和应用能力，而不仅仅是简单的记忆。" + }, + { + "idx": 4017, + "question": "Is partially melted aluminum a two-phase material system?", + "answer": "No, the physical boundary merely separates volumes that are structurally distinct (crystalline and liquid).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"部分熔化的铝是否是两相材料系统\"这一陈述的正确性。答案直接给出了\"否\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及晶体和液体的结构区别，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对\"两相材料系统\"这一基础概念的理解，需要判断部分熔化的铝是否属于两相系统。虽然涉及相变的基本概念，但不需要复杂的分析或推理，只需正确理解相的定义即可判断。相比纯粹的定义记忆题(等级1)稍难，但远未达到需要处理复杂概念陈述的等级3难度。" + }, + { + "idx": 4018, + "question": "Is frozen water with trapped air bubbles a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is frozen water with trapped air bubbles a two-phase material system?\"），答案直接给出了对错判断（\"Yes\"）并附带解释。 | 知识层次: 题目考查对两相材料系统基本概念的理解和判断，主要涉及定义和分类的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。虽然题目涉及两相系统的定义，但需要学生理解\"物理边界\"和\"化学结构差异\"这两个关键概念才能正确判断。这比单纯记忆定义的正误判断(等级1)要求更高，但尚未达到需要分析复杂概念陈述的等级3难度。" + }, + { + "idx": 4019, + "question": "Is epoxy embedded with carbon fibers a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断环氧树脂嵌入碳纤维是否属于两相材料系统，答案直接给出了对错的判断和简要解释。 | 知识层次: 题目考查对两相材料系统基本概念的记忆和理解，仅需判断是否存在物理边界和化学结构差异即可，不涉及复杂分析或综合应用。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问环氧树脂嵌入碳纤维是否属于两相材料系统，答案明确给出了定义层面的解释（存在物理边界区分化学和结构不同的体积）。这仅需学生对\"两相材料系统\"的基础定义有记忆性理解即可判断，无需深入分析或复杂推理，符合等级1的基本概念正误判断标准。" + }, + { + "idx": 4020, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must have a very [w] sizes. (w = similar, different)", + "answer": "The solute and host species must have a very similar sizes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求完成一个陈述句，需要填写一个单词来补全句子，属于简答题类型。虽然答案是一个单词，但题目没有提供选项，需要考生根据知识自行填写。 | 知识层次: 题目考查对固溶体溶解度条件的基本概念记忆，只需要回忆并填写\"similar\"这个关键词，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求填写一个关键词（similar）来完成关于固溶体溶解度条件的陈述，涉及的是最基础的概念记忆，无需解释或论述。这在该题型内属于最简单的知识再现类型。" + }, + { + "idx": 4021, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must attempt to pack with [x] crystal structure. (x = a similar (or the same), a different)", + "answer": "The solute and host species must attempt to pack with a similar (or the same) crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求完成一个陈述句，需要填写合适的词语来补全句子，而不是从给定的选项中选择或判断对错。答案是一个完整的句子，需要理解材料科学中固溶体溶解度条件的概念。 | 知识层次: 题目考查对固溶体形成条件中晶体结构相似性这一基本概念的记忆和理解，属于基础概念记忆范畴 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回忆并填写一个关键术语（\"a similar (or the same)\"），不需要进行概念解释或复杂阐述。这属于最基础的概念记忆性知识，符合等级1的标准。" + }, + { + "idx": 4022, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must feature [y] valence electron configuration. (y = a similar (or the same), a different)", + "answer": "The solute and host species must feature a similar (or the same) valence electron configuration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求完成一个陈述句，需要填写合适的词语来补全句子，而不是从给定的选项中选择或判断对错。答案是一个完整的句子，需要理解概念并用文字表达。 | 知识层次: 题目考查对固溶体溶解度条件中价电子配置要求的基本概念记忆，属于定义性知识的直接回忆，不涉及复杂推理或综合分析。 | 难度: 该题目属于基础概念记忆型的简答题，仅需回忆并复述固体溶液广泛溶解度的基本条件之一（价电子构型相似性），不涉及概念解释或复杂体系阐述。在简答题题型框架内，这是最基础的定义性问答，对应等级1的难度标准。" + }, + { + "idx": 4023, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must feature [z] ability to attract electrons (electronegativity). (z = a similar, a different)", + "answer": "The solute and host species must feature a similar ability to attract electrons (electronegativity).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（a similar, a different）中选择正确的填空内容 | 知识层次: 题目考查对固溶体溶解度条件的记忆，特别是关于溶质和溶剂电负性相似性的基本原理，属于基础概念的记忆和理解。 | 难度: 在选择题题型中，该题目属于基础概念记忆类型，仅需直接回忆固体溶解度条件中关于电负性的基本要求（相似性），无需进行概念辨析或复杂推理。题目结构简单，选项明确，属于该题型中最基础的难度层级。" + }, + { + "idx": 4024, + "question": "For a solution, which of the following is present in the higher concentration?(a) Solvent(b) Solute", + "answer": "Solvent. By definition, solvent is the element/compound that is present in a solution in the greatest amount.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项(a) Solvent和(b) Solute中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对溶剂和溶质基本定义的记忆和理解，属于基础概念层次 | 难度: 在选择题中属于简单概念识别，直接记忆的题目。题目仅考察对溶剂和溶质定义的基本记忆，无需进行任何辨析或深度理解。学生只需记住\"溶剂是溶液中含量最多的成分\"这一基本定义即可正确作答。" + }, + { + "idx": 4025, + "question": "A liquidus line separates which of the following combinations of phase fields?(a) Liquid and Liquid +\\alpha(b) \\alpha and Liquid +\\alpha(c) \\alpha and \\alpha+\\beta(d) Liquid +\\alpha and \\alpha+\\beta", + "answer": "A liquidus line separates Liquid and Liquid +\\alpha phase fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对相图中液相线（liquidus line）定义和功能的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解liquidus line的定义以及区分不同相区的组合，但不需要复杂的分析或深度理解多个概念。" + }, + { + "idx": 4026, + "question": "A solvus line separates which of the following pairs of phase fields?(a) Liquid and Liquid +\\alpha(b) \\alpha \\operatorname{and} Liquid +\\alpha(c) \\alpha and \\alpha+\\beta d) Liquid +\\alpha and \\alpha+\\beta", + "answer": "A solvus line separates \\alpha and \\alpha+\\beta phase fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对相图中solvus线的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解solvus线的定义并能区分不同相区的边界，但不需要复杂的分析或推导。" + }, + { + "idx": 4027, + "question": "Which of the following kinds of information may be determined with the aid of a phase diagram? The phase(s) present at a specified temperature and composition.", + "answer": "With the aid of a phase diagram the following may be determined: The phase(s) present at a specified temperature and composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释说明相图可以确定的信息，答案是以文字形式给出的解释性回答，符合简答题的特征。 | 知识层次: 题目考查对相图基本功能的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答相图可以确定的信息之一（特定温度和成分下的相态），属于最基础的概念记忆层面，无需解释或扩展说明，完全符合等级1对定义性知识直接复述的要求。" + }, + { + "idx": 4029, + "question": "Which of the following kinds of information may be determined with the aid of a phase diagram? The fraction(s) of phase(s) present at specified temperature and composition.", + "answer": "With the aid of a phase diagram the following may be determined: The fraction(s) of phase(s) present at a specified temperature and composition.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目陈述了一个关于相图功能的命题，要求判断该陈述是否正确。答案直接确认了该陈述的正确性，这是典型的判断题特征。 | 知识层次: 题目考查对相图基本功能的理解和记忆，属于基础概念层次 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目仅要求判断\"借助相图可以确定特定温度和成分下的相分数\"这一陈述的正确性，这直接对应相图的基础功能定义，无需复杂推理或概念交叉验证，属于最基础的概念记忆层级。" + }, + { + "idx": 4030, + "question": "At a eutectic point on a binary temperature-composition phase diagrams, how many phases are present when the system is at equilibrium?(a) 0(b) 1(c) 2(d) 3", + "answer": "At a eutectic point on a binary phase diagram, three phases (Liquid, \\alpha, and \\beta ) are present when the system is at equilibrium.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a、b、c、d）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对二元相图中共晶点处相平衡状态的基础概念记忆，只需理解共晶点处存在三相平衡（液相和两个固相）这一基本原理即可回答，无需复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解共晶点的定义和相平衡的基本概念，但不需要复杂的分析或比较。题目考察的是对共晶点处相数的记忆和理解，属于基础概念记忆的范畴。" + }, + { + "idx": 4031, + "question": "An intermetallic compound is found in the magnesium-gallium system that has a composition of 41.1 wt% Mg - 58.9 wt% Ga. Specify the formula for this compound.(a) MgGa (b) Mg_{2} \\mathrm{Ga} (c) \\mathrm{MgGa}_{2} (d) Mg_{3} \\mathrm{Ga}_{2}", + "answer": "(b) Mg_{2}Ga", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的化学式，属于选择题类型 | 知识层次: 题目要求根据给定的重量百分比计算化合物的化学式，这需要应用基本的化学计量学知识进行简单计算，属于直接套用公式的应用层次。 | 难度: 在选择题中属于简单难度，仅需应用基本的化学计量公式进行计算，无需复杂的变形或多步骤推理。题目直接给出了质量百分比，只需转换为摩尔比即可确定化学式，属于简单应用层次。" + }, + { + "idx": 4032, + "question": "A eutectoid reaction involves which of the following phases? (a) One liquid and one solid (b) One liquid and two solid (c) Two liquids and one solid (d) Three solid", + "answer": "(d) Three solid", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对共析反应中涉及相的基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题中属于简单难度，仅需直接记忆共晶反应涉及的相数即可作答，无需概念辨析或复杂分析" + }, + { + "idx": 4033, + "question": "A peritectic reaction involves which of the following combinations of phase fields? (a) One liquid and one solid (b) One liquid and two solid (c) two liquids and one solid (d) Three solid", + "answer": "(b) One liquid and two solid", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对包晶反应（peritectic reaction）基本概念的记忆和理解，涉及相图的基本分类和反应类型，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解包晶反应的定义并区分不同相的组合，但不需要复杂的分析或推导。" + }, + { + "idx": 4034, + "question": "For a congruent phase transformations there are (a) no composition alterations.(b) compositional alterations.", + "answer": "(a) no composition alterations", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择正确的陈述，符合选择题的特征 | 知识层次: 题目考查对“congruent phase transformations”这一基本概念的记忆和理解，特别是关于其组成变化特性的定义。 | 难度: 在选择题中属于最简单难度，仅需直接记忆\"共晶相变\"的基本定义特征（无成分改变），无需任何概念辨析或理解过程。这是最基础的定义性知识考察。" + }, + { + "idx": 4035, + "question": "Which of the following have a significant influence on a material's electrical resistivity?(a) impurity concentration(b) temperature(c) grain size(d) cold work(e) vacancy concentration", + "answer": "A material's electrical resistivity will depend on the following:\n- Impurity concentration\n- Vacancy concentration\n- Temperature\n- Cold work", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择对材料电阻率有显著影响的选项，符合选择题的特征 | 知识层次: 题目考查对材料电阻率影响因素的基础概念记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解材料电阻率的基本影响因素，并进行简单辨析。题目涉及多个选项，但每个选项都是基础概念，不需要复杂的比较分析。" + }, + { + "idx": 4036, + "question": "Conductivity in a metal is almost always reduced by the introduction of defects into the lattice.\nThe factor primarily affected by defects is:\n[a] free electron concentration\n[b] electron charge\n[c] electron mobility\n[d] electron spin", + "answer": "[c] electron mobility", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了四个选项和一个确定的答案 | 知识层次: 题目考查金属导电性与缺陷关系的基本概念，主要涉及电子迁移率这一基础概念的记忆和理解，无需复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解金属导电性的基本原理，并能够辨析缺陷对电子迁移率的影响。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，而非直接记忆。" + }, + { + "idx": 4037, + "question": "Compute the number of electrons that each aluminum atom donates, on average, to a bulk piece of aluminum metal. Room temperature data for aluminum:\nThe resistivity of aluminum is 2.63 × 10^{-8} \\Omega·m\nThe electron mobility of aluminum is 0.0012{m}^{2} /(V·s)\nThe mass density of aluminum is 2.7g / {cm}^{3}\nThe atomic weight of aluminum is 27g / mol", + "answer": "3.29 electron/atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解每个铝原子平均贡献的电子数，涉及多个物理量的计算和转换，答案是一个具体的数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括利用电阻率、电子迁移率、质量密度和原子重量等数据进行综合分析，最终计算出每个铝原子平均贡献的电子数。这超出了简单应用的范围，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要结合电阻率、电子迁移率、质量密度和原子重量等多个物理量进行多步计算，并理解电子捐赠的概念。虽然计算步骤较多，但每个步骤相对明确，不需要处理过于复杂的变量关系。" + }, + { + "idx": 4038, + "question": "Compute the number of electrons that each atom donates, on average, to a bulk piece of hypothetical metal. Room temperature data for the metal:\nThe resistivity of the metal is [\\mathrm{r}] \\Omega·{cm}\nThe electron mobility of the metal is [m] {cm}^{2} /(V·s)\nThe mass density of the metal is [\\mathrm{d}] \\mathrm{g} / {cm}^{3}\nThe atomic weight of the metal is [\\mathrm{w}] \\mathrm{g} / mol", + "answer": "the number of free electrons donated by each atom, on average, is: \\[\n\\frac{[w]}{\\left([r]\\left(1.6 × 10^{-19}\\right)[m]\\right)\\left([d]\\left(6.022 × 10^{23}\\right)\\right)}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数（电阻率、电子迁移率、质量密度、原子量）进行数值计算，应用特定公式来求解每个原子平均贡献的自由电子数。答案是一个具体的数学表达式，需要代入数值进行计算。 | 知识层次: 题目需要进行多步计算，涉及电阻率、电子迁移率、质量密度和原子重量等多个物理量的关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要理解和应用多个概念，并进行综合计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要结合多个物理概念（电阻率、电子迁移率、质量密度、原子量）进行多步计算，并正确应用单位转换和常数。虽然计算步骤明确，但涉及多个变量的综合运用和单位统一，对概念理解和计算能力要求较高。" + }, + { + "idx": 4039, + "question": "When an electric field is applied, in which direction are the free electrons accelerated?(a) Opposite to the direction of the electric field.(b) In the same direction as the electric field.", + "answer": "When an electric field is applied, the free electrons are accelerated in the direction opposite to that of the field.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对电场中自由电子运动方向这一基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于简单难度，仅需直接记忆基础概念（电子在电场中的运动方向与电场方向相反），无需理解或辨析复杂概念。" + }, + { + "idx": 4040, + "question": "The electrical conductivity of an intrinsic semiconductor is(a) characteristic of the high-purity metal.(b) due to the presence of impurities.", + "answer": "The electrical conductivity of an intrinsic semiconductor is characteristic of the high-purity material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对半导体基本概念的记忆和理解，特别是本征半导体的导电特性这一基础知识点。 | 难度: 在选择题中属于简单难度，仅需直接记忆并识别\"本征半导体导电性\"这一基础概念，无需进行概念辨析或复杂理解。题目选项设置简单明确，正确选项可直接对应教材定义。" + }, + { + "idx": 4041, + "question": "How do the electrical conductivities of metals compare with those of semiconductors?(a) \\sigma_{\\text {metals }}>\\sigma_{\\text {semiconductors }}(b) \\sigma_{\\text {metals }}=\\sigma_{\\text {semiconductors }}(c) \\sigma_{\\text {metals }}<\\sigma_{\\text {semiconductors }}", + "answer": "The electrical conductivities of metals are greater than those of semiconductors.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了多个选项（a, b, c）并要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对金属和半导体电导率的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于简单难度，仅需直接记忆金属和半导体电导率的基本概念即可作答，无需进行复杂辨析或深度理解。" + }, + { + "idx": 4042, + "question": "How does increasing temperature affect the concentration of both electrons and holes in an intrinsic semiconductor?(a) Increases the concentration.(b) Decreases the concentration.(c) May increase and/or decrease the concentration, depending on the temperature range.", + "answer": "Increasing temperature increases the concentration of both electrons and holes in an intrinsic semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了多个选项（a, b, c），要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对温度对半导体中电子和空穴浓度影响的基本概念的理解，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解温度对半导体载流子浓度的影响这一基本概念，并进行简单辨析。虽然不涉及复杂计算或多概念交叉，但需要掌握本征半导体的基本特性才能正确作答。" + }, + { + "idx": 4043, + "question": "Which type of charge carrier will be introduced into a semiconductor by the presence of an acceptor impurity?(a) Electron(b) Hole", + "answer": "The presence of an acceptor impurity introduces holes into a semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项(a)和(b)中选择正确的电荷载流子类型 | 知识层次: 题目考查半导体中受主杂质引入的载流子类型，属于基础概念的记忆和理解，不需要复杂的分析或计算。 | 难度: 在选择题中属于简单概念识别，直接记忆类型。题目仅考察对半导体中受主杂质引入载流子类型的基础概念记忆，无需复杂理解或辨析，属于最基础的知识点。" + }, + { + "idx": 4044, + "question": "Which type of charge carrier will be introduced into a semiconductor by the presence of a donor impurity?(a) Impurity(b) Hole", + "answer": "The presence of a donor impurity introduces electrons into a semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查半导体中掺杂引入载流子的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆半导体中施主杂质引入的载流子类型（电子），无需复杂辨析或深度理解。" + }, + { + "idx": 4045, + "question": "The electrical conductivity of an extrinsic semiconductor is(a) Characteristic of the high-purity material.(b) due to the presence of impurities.", + "answer": "The electrical conductivity of an extrinsic semiconductor is due to the presence of impurities.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择关于外禀半导体导电性的正确描述 | 知识层次: 题目考查对半导体导电性基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，题目直接考察对\"外征半导体\"基本定义的记忆，只需识别\"电导率来源于杂质\"这一单一知识点，无需概念辨析或复杂理解。" + }, + { + "idx": 4046, + "question": "For an n-type semiconductor, which type of charge carrier is present in the greater concentration?(a) Hole(b) Electron", + "answer": "For an n-type semiconductor, electrons (i.e., negative charge carriers) are present in a greater concentration than holes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项（a）Hole和（b）Electron中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对n型半导体中主要载流子类型的基础概念记忆，仅需知道n型半导体中电子浓度高于空穴这一基本原理即可作答，不涉及复杂分析或应用。 | 难度: 在选择题中属于简单难度，仅需直接记忆n型半导体的基本定义和主要载流子类型，无需进行概念辨析或复杂理解。" + }, + { + "idx": 4047, + "question": "For an n-type semiconductor(a) Concentration _{\\text {electrons }}< concentration _{\\text {holes }}(b) Concentration _{\\text {electrons }}= concentration _{\\text {holes }}(c) Concentration _{\\text {electrons }}< concentration _{\\text { holes }}", + "answer": "For an n-type semiconductor, the concentration of electrons is much greater than the concentration of holes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对n型半导体基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆n型半导体的基本特性（电子浓度远大于空穴浓度），无需进行概念辨析或复杂分析。" + }, + { + "idx": 4048, + "question": "For a p-type semiconductor, which type of charge carrier is present in the greater concentration?(a) Holes(b) Electrons", + "answer": "For a p-type semiconductor, holes, (i.e., positive charge carriers) are present in a greater concentration than electrons.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（a）Holes和（b）Electrons中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对p型半导体中主要载流子类型的基础概念记忆，仅需知道p型半导体中空穴浓度高于电子这一基本事实即可回答，无需复杂分析或计算。 | 难度: 在选择题中属于简单难度，仅需直接记忆p型半导体的基本特性（空穴为主要载流子），无需理解或辨析其他复杂概念。" + }, + { + "idx": 4049, + "question": "For a p-type semiconductor(a) Concentration _{\\text {electrons }}< concentration _{\\text {holes }}(b) Concentration _{\\text {electrons }}= concentration _{\\text {holes }}(c) Concentration _{\\text {electrons }}< concentration _{\\text { holes }}", + "answer": "For a p-type semiconductor, the concentration of electrons is much lower than the concentration of holes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对p型半导体基本概念的记忆和理解，即电子和空穴浓度的相对关系，属于基础概念记忆层次。 | 难度: 在选择题中属于简单难度，仅需直接记忆p型半导体的基本特性（空穴浓度远大于电子浓度），无需进行概念辨析或复杂分析。" + }, + { + "idx": 4050, + "question": "In order for a semiconductor to exhibit extrinsic electrical characteristics, relatively high impurity concentrations are required.(a) True(b) False", + "answer": "False. Even when minute impurity concentrations (e.g., 1 atom in 10^{12} ) are present in a semiconductor, its electrical characteristics will be extrinsic.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（True/False），并且答案直接给出了False的判断和解释，符合判断题的特征。 | 知识层次: 题目考查半导体掺杂的基本概念，只需要记忆和理解外征半导体特性的定义即可判断对错，不涉及复杂分析或计算。 | 难度: 在判断题中属于中等难度，题目涉及半导体外禀特性的基本概念，但需要理解\"即使微量杂质浓度也能导致外禀特性\"这一知识点，而非简单记忆定义。这要求对概念有更深层次的理解，但不需要复杂分析。" + }, + { + "idx": 4051, + "question": "The following electrical characteristics have been determined for both intrinsic and n-type extrinsic indium phosphide (InP) at room temperature:\n\\[\n\\begin{array}{llll}\n\\sigma(\\Omega·\\mathbf{m})^{-1} & \\boldsymbol{n}\\left(\\mathbf{m}^{-3}\\right) & \\boldsymbol{p}\\left(\\mathbf{m}^{-3}\\right) \\\\\n\\text { Intrinsic } & 2.5 × 10^{-6} & 3.0 × 10^{13} & 3.0 × 10^{13} \\\\\n\\text { Extrinsic } & 3.6 × 10^{-5} & 4.5 × 10^{14} & 2.0 × 10^{12}\n\\end{array}\n\\]\nCalculate electron and hole mobilities.\n\\mu_{\\mathrm{e}}=\n\\mu_{h}=", + "answer": "\\mu_{\\mathrm{e}} = 0.50 \\, m^{2} / \\mathrm{v}·s \\mu_{h} = 0.02 \\, m^{2} / \\mathrm{v}·s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解电子和空穴的迁移率，答案以具体数值形式给出，符合计算题的特征。 | 知识层次: 题目要求使用基本的电导率公式（σ = n·e·μ）进行直接计算，属于基本公式应用和简单计算范畴，无需多步推理或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用电导率与载流子浓度和迁移率的基本公式（σ = n·e·μ），但仅涉及单一公式的直接计算和简单代数运算。虽然需要分别计算电子和空穴的迁移率，但解题步骤较为直接，没有复杂的推导或多步骤组合计算。" + }, + { + "idx": 4052, + "question": "Which of the following are preferred for semiconducting devices?(a) Single crystals(b) Polycrystalline materials", + "answer": "Single crystals are preferred for semiconducting devices because grain boundaries are deleterious to the performance of electronic phenomena.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对半导体器件材料选择的基本概念记忆和理解，涉及单晶和多晶材料的性能差异这一基本原理。 | 难度: 在选择题中属于中等偏下难度，需要理解单晶和多晶材料的区别，并知道晶界对半导体器件性能的影响。虽然涉及概念理解，但知识点较为基础，不需要复杂的分析过程。" + }, + { + "idx": 4053, + "question": "As temperature increases, the electrical conductivities of polymers and ionic ceramics(a) Increase(b) Decrease", + "answer": "As temperature increases, the electrical conductivities of polymers and ionic ceramics increase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物和离子陶瓷电导率随温度变化的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题中属于中等难度，需要理解聚合物和离子陶瓷的电导率随温度变化的基本原理，并进行简单辨析。虽然不涉及复杂概念的区分，但需要超越单纯的记忆，对材料科学中的温度效应有一定理解。" + }, + { + "idx": 4054, + "question": "Most polymers and ionic ceramics have energy band gap structures that are most similar to those of(a) Insulators(b) Semiconductors(c) Metals", + "answer": "Most polymers and ionic ceramics have wide energy band gaps; thus, they are most like those of insulators.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对材料能带结构分类的基本概念记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题中属于中等偏下难度，需要理解能量带隙的基本概念，并能对不同材料的带隙特性进行简单辨析。虽然涉及多个选项的比较，但知识点较为基础，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 4055, + "question": "The charge carriers in ionic ceramics and polymers can be(a) Electrons(b) Holes(c) Anion(d) Cations", + "answer": "The charge carriers in ionic ceramics and polymers can be electrons, holes, anions, and/or cations.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)-(d)中选择正确的电荷载流子类型，符合选择题的特征。 | 知识层次: 题目考查对离子陶瓷和聚合物中电荷载流子的基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题中属于中等偏下难度，虽然涉及多个选项（电子、空穴、阴离子、阳离子），但主要考察对离子陶瓷和聚合物中电荷载流子的基本概念理解，不需要复杂的分析或深度推理。" + }, + { + "idx": 4056, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum alloys are generally not viable as lightweight structural materials in humid environments because they are highly susceptible to corrosion by water vapor.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案形式为F（False），符合判断题的特征。 | 知识层次: 题目考查对铝合金在潮湿环境中耐腐蚀性能这一基础概念的认知，属于材料科学中材料性能的基本知识范畴，仅需记忆和理解即可判断。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆铝及铝合金的基本特性（耐腐蚀性较好）即可判断陈述错误，无需复杂推理或概念交叉分析。" + }, + { + "idx": 4057, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum alloys are generally superior to pure aluminum, in terms of yield strength, because their microstructures often contain precipitate phases that strain the lattice, thereby hardening the alloy relative to pure aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案形式为T（正确），符合判断题的特征。 | 知识层次: 题目考查对铝及其合金基本性质的理解，特别是关于纯铝和铝合金在屈服强度方面的差异及其原因的基础知识。虽然涉及微观结构的简单解释，但整体上属于基础概念的记忆和理解范畴。 | 难度: 在判断题中属于中等难度，需要理解铝合金与纯铝在屈服强度上的差异及其微观结构原因，但不需要复杂的分析步骤。" + }, + { + "idx": 4058, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum is not very workable at high temperatures in air, in terms of extrusion and rolling, because a non-protective oxide grows and consumes the metal, converting it to a hard and brittle ceramic.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），并且答案以T/F形式给出 | 知识层次: 题目考查对铝及其合金在高温下加工性能的基本概念记忆，涉及氧化膜的形成及其对加工性能的影响，属于基础概念的记忆和理解。 | 难度: 在判断题中属于中等难度，需要理解铝在高温下的氧化行为及其对加工性能的影响，而不仅仅是记忆基本概念。题目涉及对非保护性氧化膜形成及其后果的判断，属于概念理解层面的对错判断。" + }, + { + "idx": 4059, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Compared to most other metals, like steel, pure aluminum is very resistant to creep deformation.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），并且答案是一个简单的“F”（False），符合判断题的特征。 | 知识层次: 题目考查对纯铝蠕变性能的基本概念记忆，属于基础概念的记忆性知识 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆纯铝的抗蠕变性能相对于其他金属（如钢）的特性即可作答，不涉及概念理解或复杂概念的判断。" + }, + { + "idx": 4060, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: The relatively low melting point of aluminum is often considered a significant limitation for structural applications.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），并且答案是一个简单的T（True）或F（False），符合判断题的特征。 | 知识层次: 题目考查对铝及其合金基本特性的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于判断题中最基础的难度等级，仅需识别\"铝的熔点较低是否被视为结构应用的重要限制\"这一基本概念的正误。题目直接考察对铝材料特性的记忆性知识，无需复杂推理或概念关联，完全符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 4061, + "question": "[a] Aluminum alloys are generally viable as lightweight structural materials in humid environments because they are not very susceptible to corrosion by water vapor.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Aluminum alloys are generally viable as lightweight structural materials in humid environments because they are not very susceptible to corrosion by water vapor.），并要求判断其正确性（答案：T）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对铝合金在潮湿环境中耐腐蚀性能的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在判断题的基础概念记忆类别中，此题仅需判断铝合金在潮湿环境中的基本腐蚀特性这一简单事实，属于最基础的定义性知识判断，无需深入理解或复杂推理。" + }, + { + "idx": 4062, + "question": "[b] Aluminum is not very workable at high temperatures in air, in terms of extrusion and rolling, because a non-protective oxide grows and consumes the metal, converting it to a hard and brittle ceramic.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案给出F表示错误），符合判断题的特征 | 知识层次: 题目考查对铝在高温下加工性能的基本概念记忆，涉及铝氧化物形成及其对加工性能影响的简单陈述，不需要复杂的分析或应用。 | 难度: 在判断题中属于中等难度，需要理解铝在高温下的氧化行为及其对加工性能的影响，而不仅仅是记忆基本定义。题目涉及对非保护性氧化物形成及其后果的判断，需要一定的概念理解而非单纯记忆。" + }, + { + "idx": 4063, + "question": "[c] Aluminum alloys are generally superior to pure aluminum, in terms of yield strength, because their microstructures often contain precipitate phases that strain the lattice, thereby hardening the alloy relative to pure aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Aluminum alloys are generally superior to pure aluminum...），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对铝合金强化机制的基础概念记忆和理解，涉及析出相和晶格应变对强度的影响，属于基本原理的记忆性知识。 | 难度: 在判断题中属于中等难度，需要理解铝合金与纯铝在屈服强度上的差异及其微观结构原因，而不仅仅是记忆基本定义。题目涉及对材料强化机制的理解，但不需要复杂的分析步骤。" + }, + { + "idx": 4064, + "question": "[d] Compared to other metals, like steel, pure aluminum is very resistant to failure via fatigue.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Compared to other metals, like steel, pure aluminum is very resistant to failure via fatigue），并要求判断其正确性（答案：F），符合判断题的特征。 | 知识层次: 题目考查对纯铝疲劳性能与其他金属（如钢）对比的基础概念记忆和理解，属于材料科学中金属性能的基本知识点。 | 难度: 在判断题中属于中等难度，需要理解纯铝与其他金属（如钢）在疲劳失效方面的相对特性，属于概念理解的对错判断。虽然不涉及复杂概念，但需要一定的材料科学基础知识来判断陈述的正确性。" + }, + { + "idx": 4065, + "question": "[e] Aluminum exhibits one of the highest melting points of all metals, which makes it difficult and expensive to cast.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案给出的是F，即False），符合判断题的特征 | 知识层次: 题目考查对铝的熔点这一基础概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在判断题题型中，此题属于基本概念正误判断。题目仅涉及铝的熔点这一单一事实的陈述判断，不需要理解复杂概念或进行多步骤推理。学生只需记住铝的实际熔点特性（相对较低）即可直接判断陈述错误，属于该题型中最基础的难度等级。" + }, + { + "idx": 4066, + "question": "[a] Copper has a higher elastic modulus than aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜的弹性模量比铝高），并要求判断其正确性（答案为T表示正确），这符合判断题的特征 | 知识层次: 题目考查对铜和铝弹性模量这一基本物理性质的记忆，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆铜和铝的弹性模量相对大小这一基础事实，无需深入理解或分析复杂概念。" + }, + { + "idx": 4067, + "question": "[b] The density of copper is closer to that of aluminum than it is to iron.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（F表示错误），符合判断题的特征 | 知识层次: 题目考查对铜、铝和铁密度这一基础物理性质的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆铜、铝和铁的密度关系即可作答，无需深入理解或复杂分析。在判断题题型内，这属于最基础的难度等级。" + }, + { + "idx": 4068, + "question": "[c] Bronze is an alloy of copper and zinc.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（F表示错误），符合判断题的特征 | 知识层次: 题目考查对青铜合金基本成分的记忆，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，此题属于最基本的概念正误判断。题目仅考察对青铜合金成分的基础定义记忆（铜和锡的合金，而非铜和锌），不需要任何理解或分析过程。在判断题的三个难度等级中，这属于最简单的等级1，即仅需识别基础概念的正误。" + }, + { + "idx": 4069, + "question": "[d] Copper and its alloys form a green tarnish over time, consisting of sulfides and carbonates.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜及其合金会形成绿色锈蚀），并要求判断其正确性（答案为T，即正确）。这是典型的判断题形式。 | 知识层次: 题目考查铜及其合金随时间形成绿色锈蚀物的基本概念记忆，涉及简单的化学反应产物（硫化物和碳酸盐）的识别，属于基础概念的记忆性知识。 | 难度: 该判断题属于基础概念记忆层次，仅需判断铜及其合金随时间形成绿色锈层（由硫化物和碳酸盐组成）这一基本事实的正确性。题目陈述的是材料科学中关于铜腐蚀现象的常识性知识，无需复杂推理或概念交叉分析，符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 4070, + "question": "[e] Copper is relatively resistant to corrosion by neutral and even mildly basic water, making it useful for freshwater plumbing applications.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜在中性和弱碱性水中相对耐腐蚀），并要求判断其正误（答案给出T表示正确），这符合判断题的特征。 | 知识层次: 题目考查对铜在特定环境下的耐腐蚀性能这一基础概念的记忆和理解，属于材料科学中金属腐蚀与防护的基本知识点。 | 难度: 在判断题中属于基本难度，仅需对铜的耐腐蚀性这一基础概念进行正误判断，不涉及复杂理解或分析步骤。题目直接陈述了铜在特定环境下的性质与应用，属于定义性知识的简单确认。" + }, + { + "idx": 4071, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is much more abundant in the earth's crust compared to iron or aluminum.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），并且答案是一个明确的判断（F），符合判断题的特征。 | 知识层次: 题目考查对铜、铁和铝在地壳中丰度的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆铜、铁、铝在地壳中的相对丰度这一基础事实即可判断对错，无需深入理解或分析复杂概念。" + }, + { + "idx": 4072, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is one of just a few metals that can be found in metallic form in nature.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为T（正确）或F（错误），符合判断题的特征 | 知识层次: 题目考查对铜及其合金基本性质的记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆铜在自然界中可以以金属形式存在这一基础事实，无需深入理解或分析复杂概念。在判断题的基础概念记忆层次中属于最简单级别。" + }, + { + "idx": 4073, + "question": "Select T / F for the following statement regarding copper & copper alloys: Pure and/or annealed copper is more difficult to machine compared to its work-hardened form or its alloys.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为T（正确）或F（错误），符合判断题的特征。 | 知识层次: 题目考查对铜及其合金加工性能的基础概念记忆，属于对材料基本特性的认知，无需复杂分析或计算。 | 难度: 在判断题中属于中等难度，需要理解铜及其合金的加工特性，并比较纯铜/退火铜与加工硬化铜/合金的可加工性差异。虽然不涉及复杂概念，但需要一定的概念理解和比较分析能力。" + }, + { + "idx": 4074, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is a minor component (by weight) of most brass & bronze alloys.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为F（False），符合判断题的特征 | 知识层次: 题目考查对铜合金（黄铜和青铜）基本成分的记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于判断题中的基础概念正误判断，仅需记忆铜在黄铜和青铜合金中的主要成分比例即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4075, + "question": "Select T / F for the following statement regarding copper & copper alloys: Amongst metals and alloys copper is one of the best conductors of heat.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为T（正确），符合判断题的特征 | 知识层次: 题目考查对铜及其合金导热性能这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在判断题题型中，该题目属于最基本的概念正误判断。题目直接考察铜及铜合金的热导率这一基础物理性质，属于材料科学中最基础的定义性知识，无需任何推理或复杂概念理解，只需记忆铜是优良热导体的基本事实即可作答。" + }, + { + "idx": 4076, + "question": "[a] Nickel is majority component (by mass) in certain superalloys such as Waspaloy TM.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（\"Nickel is majority component (by mass) in certain superalloys such as Waspaloy TM\"），并要求判断其正误（答案：T），这符合判断题的特征。 | 知识层次: 题目考查对镍在特定超合金中作为主要成分的基础知识记忆，属于定义和分类层面的记忆性知识。 | 难度: 在判断题的基础概念记忆层次中，该题目仅需识别镍是否为Waspaloy TM等超合金的主要成分（按质量计），属于直接的定义性知识验证，无需理解或分析过程，符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 4077, + "question": "[b] Tungsten is the lowest density metal that has structural use.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Tungsten is the lowest density metal that has structural use），并要求判断其正误（答案F），这是典型的判断题形式。 | 知识层次: 题目考查对钨金属基本性质（密度和结构用途）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于判断题中的基本概念正误判断，仅需记忆钨的密度特性及其在结构材料中的应用即可作答，无需深入理解或分析复杂概念。在同题型内属于最基础的难度等级。" + }, + { + "idx": 4078, + "question": "[c] Tantalum offers extremely good corrosion resistance, especially at low temperatures.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Tantalum offers extremely good corrosion resistance, especially at low temperatures），并要求判断其正确性（答案：T）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对钽（Tantalum）腐蚀抗性这一基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基础概念正误判断。题目陈述了钽（Tantalum）在低温下具有极好的耐腐蚀性这一基本事实，只需记忆相关材料科学的基础知识即可判断其正确性，无需深入理解或分析复杂概念。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 4079, + "question": "[d] Magnesium metal is very similar to aluminum, in terms of its physical and mechanical properties.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（镁金属在物理和机械性能上与铝非常相似），并要求判断其正确性（答案为T，即True）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对镁和铝物理和机械性能相似性的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。仅需记忆镁和铝在物理和机械性能上的相似性这一基础事实即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4080, + "question": "[e] Beryllium metal is commonly used as an alloying agent in copper metal.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Beryllium metal is commonly used as an alloying agent in copper metal），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对铍金属作为铜合金化剂这一基本事实的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目仅涉及铍金属作为铜合金剂的常见用途这一简单事实，不需要深入理解或分析多个概念，属于最基础的记忆性知识判断。" + }, + { + "idx": 4081, + "question": "Increasing the alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\right) content of fireclays results in(a) an increase in maximum service temperature.(b) a decrease in maximum service temperature.", + "answer": "Increasing the alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}\\right)_{3} content of fireclays results in an increase in maximum service temperature.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对氧化铝含量与耐火粘土最高使用温度关系的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解氧化铝含量与耐火粘土最高使用温度之间的关系，并进行简单辨析。虽然题目涉及基础概念记忆，但需要将材料成分与性能变化联系起来，比单纯的概念识别稍复杂。" + }, + { + "idx": 4082, + "question": "The high-temperature performance of silica refractories is compromised by the presence of even small concentrations of alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\end{array}(a) True(b) False", + "answer": "True. The presence of even small amounts of alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3)}\\right) in silica refractory ceramics compromises their high-temperature performance.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（True or False），并且答案直接给出了判断结果（True）。 | 知识层次: 题目考查对硅质耐火材料高温性能影响因素的基础概念记忆，仅需知道氧化铝的存在会降低其性能这一基本事实即可作答，不涉及复杂分析或应用。 | 难度: 在判断题中属于基本概念正误判断，仅需记忆硅质耐火材料中氧化铝的存在会损害其高温性能这一基础事实，无需深入理解或分析复杂概念。" + }, + { + "idx": 4083, + "question": "As the porosity of refractory ceramic bricks increases, what happens to the strength?", + "answer": "Strength decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释孔隙率增加对耐火陶瓷砖强度的影响，答案需要文字解释和论述，而非选择、判断或计算 | 知识层次: 题目考查耐火陶瓷砖孔隙率与强度关系的基本概念记忆和理解，属于基础知识的直接应用，无需复杂分析或推理。 | 难度: 在简答题题型中，该题目仅要求回答材料科学中最基础的概念关系（孔隙率与强度的反比关系），无需解释机制或论述影响因素，属于基本定义简答级别。同类题型中，这比需要描述晶界强化机制（等级2）或阐述断裂韧性测试方法（等级3）的题目简单得多。" + }, + { + "idx": 4084, + "question": "As the porosity of refractory ceramic bricks increases, what happens to the chemical resistance?", + "answer": "Chemical resistance decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释孔隙率增加对耐火陶瓷砖化学抵抗性的影响，答案需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查耐火陶瓷砖孔隙率与化学抗性之间关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义级别的知识（孔隙率增加导致化学抗性降低），无需展开解释或描述概念间的复杂关系。属于最基础的概念记忆层级，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4085, + "question": "As the porosity of refractory ceramic bricks increases, what happens to the thermal insulation?", + "answer": "Thermal insulation increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释孔隙率增加对耐火砖隔热性能的影响，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对多孔材料热绝缘性能的基本概念的理解，仅需记忆和简单解释孔隙率增加对热绝缘性能的影响，无需复杂分析或计算。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求考生记忆并复述\"孔隙率增加导致隔热性能提高\"这一基本原理，无需进行概念解释或复杂体系阐述。该知识点属于耐火材料最基础的热物理性质关系，在简答题框架内属于最基础的记忆性知识考查。" + }, + { + "idx": 4086, + "question": "The presence of silica \\left(\\mathrm{SiO}_{2}\\right) in basic refractory ceramics is beneficial to their high-temperature performance.(a) True(b) False", + "answer": "False. The presence of silica \\left(\\mathrm{SiO}_{2}\\right) in basic refractory ceramics is deleterious on their hightemperature performance.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（True/False），答案直接给出判断结果并简要解释原因，符合判断题的特征 | 知识层次: 题目考查对基础概念的记忆，即二氧化硅在碱性耐火陶瓷中的作用及其对高温性能的影响。这属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在判断题题型中，该题目属于基本概念正误判断，仅需记忆基础概念（二氧化硅在碱性耐火陶瓷中的作用）即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4087, + "question": "Basic refractory ceramics are often used for the containment of slags that are rich in(a) silica(b) \\mathrm{CaO}(c) MgO", + "answer": "Basic refractory ceramics are often used for the containment of slags that are rich in \\mathrm{CaO} and/or MgO.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查对基础耐火陶瓷材料应用场景的基本概念记忆，仅需知道其用于富含CaO和/或MgO的炉渣即可回答，不涉及复杂分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解基本耐火陶瓷的应用场景，并能简单区分不同成分的炉渣特性。虽然涉及两个正确选项（CaO和MgO），但知识点属于基础概念记忆范畴，无需复杂分析。" + }, + { + "idx": 4088, + "question": "Silica refractory ceramics are often used for the containment of slags that are rich in(a) silica(b) \\mathrm{CaO}(c) Mg \\mathrm{O}", + "answer": "Silica refractory ceramics are often used for the containment of slags that are rich in silica.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查对硅质耐火陶瓷材料基本用途的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题中属于简单难度，题目直接考察对硅质耐火陶瓷用途的基础记忆，只需识别\"silica\"这一关键词即可作答，无需概念辨析或深度理解。" + }, + { + "idx": 4089, + "question": "Such that the bond strength across the fiber-epoxy interface is [s] MPa, and the shear yield strength of the epoxy is [y] MPa, compute the minimum fiber length, in millimeters, to guarantee that the fibers are conveying an optimum fraction of force that is applied to the composite. The tensile strength of these carbon fibers is [f] MPa.", + "answer": "the minimum fiber length to guarantee that the fibers are conveying an optimum fraction of force that is applied to the composite is \\frac{[f][d]}{2[s] × 1000} millimeters.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数和公式计算最小纤维长度，答案是一个具体的计算公式和单位，需要数值计算和公式应用。 | 知识层次: 题目需要进行多步计算，涉及纤维-环氧树脂界面的结合强度、环氧树脂的剪切屈服强度以及碳纤维的拉伸强度等多个概念的关联和综合分析。虽然题目提供了公式，但需要理解公式中各参数的含义及其相互关系，并进行适当的单位转换（如MPa到Pa的转换），这要求一定的应用和分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解纤维-环氧树脂界面的粘结强度、环氧树脂的剪切屈服强度以及碳纤维的拉伸强度之间的关系，并应用公式进行多步计算。虽然涉及多个变量和概念，但计算步骤相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 4090, + "question": "For an aligned fibrous composite, when a stress is applied in a direction that is parallel to the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d) \\frac{3}{4}(e) 1", + "answer": "For an aligned fibrous composite when the stress is applied parallel to the fibers, the reinforcement efficiency is 1 .", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)-(e)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对齐纤维复合材料在应力平行于纤维方向时的增强效率这一基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，题目直接考察对纤维增强复合材料中增强效率的基础概念记忆。当应力方向与纤维平行时，增强效率为1是一个直接的定义性知识点，无需复杂理解或分析。" + }, + { + "idx": 4091, + "question": "For an aligned fibrous composite, when a stress is applied perpendicular to the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d)\n\\frac{3}{4}(e) 1", + "answer": "begin{tabular}{l|l|l|l|l|l|l|l|l|l|l|}\n\\hline\n\\end{tabular}\nFor an aligned fibrous composite when a stress is applied perpendicular to the fibers, the reinforcement efficiency is 0 .", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)-(e)中选择正确答案，且答案给出了具体选项(a)作为正确答案 | 知识层次: 题目考查对纤维增强复合材料中增强效率这一基本概念的记忆和理解，特别是当应力垂直于纤维方向时的特殊情况。不需要复杂的计算或分析，只需记住在这种情况下增强效率为零即可。 | 难度: 在选择题中属于简单难度，题目直接考察对纤维增强复合材料中增强效率的基础概念记忆，只需识别应力垂直于纤维方向时增强效率为零这一基本事实，无需复杂理解或分析。" + }, + { + "idx": 4092, + "question": "For a fibrous composite with fibers that are randomly and uniformly oriented within a specific plane, when a stress is applied in any direction within the plane of the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d) \\frac{3}{4}(e) 1", + "answer": "For a fibrous composite with fibers that are randomly and uniformly oriented within a specific plane,when a stress is applied in any direction within the plane of the fibers, the reinforcement efficiency is \\frac{3}{8}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目需要理解纤维增强复合材料中纤维随机均匀分布时的增强效率概念，并应用相关理论进行计算。虽然不涉及复杂的多步计算，但需要将概念与具体情境关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解复合材料中纤维随机排列的强化效率概念，并进行多步计算和综合分析。题目涉及特定平面内应力方向与纤维排列的关系，要求考生掌握较深的知识点并能够进行复杂分析过程的判断。" + }, + { + "idx": 4093, + "question": "For a fibrous composite with fibers that are uniformly distributed and randomly oriented in all directions, when a stress is applied in any direction, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{{ }_{5}}(c) \\frac{3}{8}(d) \\frac{3}{{ }_{4}}(e) 1", + "answer": "For a fibrous composite with fibersthat are uniformly distributed and randomly oriented in all directions, when a stress is applied in any direction, the reinforcement efficiency is 1 / 5.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对纤维增强复合材料中纤维随机分布时增强效率的基本理解和简单应用，需要知道随机分布纤维的增强效率为1/5这一基本结论，属于直接套用知识点。 | 难度: 在选择题中属于简单难度，只需要直接应用基本公式（纤维随机分布复合材料的增强效率公式）即可得出正确答案，无需复杂计算或变形步骤。" + }, + { + "idx": 4094, + "question": "A stress-strain test is performed on an aligned fibrous composite such that the force is applied in the longitudinal direction. During the initial stage of the test, which phase bears most of the load?(a) Fibers(b) Matrix", + "answer": "During a stress-strain test that is performed on an aligned fibrous composite, the fibers bear more of the applied load than the matrix in the initial stage of the test.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a) Fibers和(b) Matrix，要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查复合材料在应力-应变测试初期阶段的基本行为，即纤维和基体在受力时的基本作用，属于基础概念的记忆和理解。 | 难度: 在选择题中属于简单难度，仅需直接记忆复合材料在初始受力阶段纤维承担主要负载这一基础概念，无需进行复杂辨析或深度理解。" + }, + { + "idx": 4095, + "question": "Once the fibers fail in a fibrous composite, catastrophic failure of the piece takes place.(a) True(b) False", + "answer": "False. Once the fibers fail in a composite, catastrophic failure of the piece does not take place. Since the broken fibers are still embedded within the matrix, they are still capable of sustaining a diminished load.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附有简要解释。 | 知识层次: 题目考查对复合材料失效机制的基本概念理解，仅需记忆和简单理解纤维失效后复合材料的行为特征，无需复杂分析或计算。 | 难度: 在判断题中属于中等难度，需要理解复合材料中纤维失效后的行为，而不仅仅是记忆基本定义。题目考察的是对纤维失效后复合材料整体性能变化的理解，属于概念理解的对错判断。" + }, + { + "idx": 4096, + "question": "How are continuous fibers typically oriented in fibrous composites?(a) Aligned(b) Partially oriented(c) Randomly oriented", + "answer": "Continuous fibers are typically aligned in fibrous composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案，且答案明确指出了正确选项 | 知识层次: 题目考查对纤维复合材料中连续纤维排列方式的基础概念记忆，属于定义和分类层面的基本知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆连续纤维在复合材料中的典型排列方式（对齐排列），无需进行概念辨析或深度理解。" + }, + { + "idx": 4097, + "question": "How are discontinuous fibers typically oriented in fibrous composites?(a) Aligned(b) Partially oriented", + "answer": "Discontinuous fibers may be aligned, partially oriented, and randomly oriented in fibrous composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择正确的描述方式，符合选择题的特征 | 知识层次: 题目考查对纤维复合材料中不连续纤维取向方式的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题题型中，此题属于简单概念识别类型。题目直接询问不连续纤维在复合材料中的典型取向方式，答案选项(a)和(b)都是常见的取向类型，且题目明确给出了完整的正确答案。这只需要学生对基础概念有基本记忆即可作答，不需要进行复杂的概念辨析或深度理解。" + }, + { + "idx": 4098, + "question": "If the fiber orientation is random, which type of fibers is normally used?(a) Discontinuous(b) Continuous", + "answer": "Discontinuous fibers are normally used when the fiber orientation is random.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项（a）和（b），要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查纤维类型及其取向关系的基础概念记忆，仅需识别随机取向时通常使用的纤维类型，属于定义和分类层面的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆纤维类型与取向关系的基础概念，无需进行复杂辨析或深度理解。题目明确给出了随机取向时的标准答案，属于最基础的定义性知识。" + }, + { + "idx": 4099, + "question": "[a] Composites are single-phase materials by definition.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为F表示错误），符合判断题的特征 | 知识层次: 题目考查复合材料定义这一基础概念的记忆和理解，属于对单一知识点的直接判断 | 难度: 在判断题中属于基本概念正误判断，仅需记忆复合材料的定义即可判断陈述的对错，无需深入理解或分析复杂概念。" + }, + { + "idx": 4100, + "question": "[b] The term \"composite\" applies to materials that feature polymeric materials only.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（F表示错误），符合判断题的特征 | 知识层次: 题目考查对复合材料定义的基本概念记忆和理解，不涉及复杂分析或应用。 | 难度: 该判断题属于基础概念正误判断，仅需记忆复合材料的基本定义即可作答。复合材料并非仅由聚合物材料组成，这是材料科学中最基础的定义性知识，不需要任何复杂理解或推理过程。在同为判断题的基础概念记忆层次中，这属于最简单的等级1难度。" + }, + { + "idx": 4101, + "question": "[c] Structural composites are, in general, highly regarded for their specific strengths.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Structural composites are, in general, highly regarded for their specific strengths），并要求判断其正误（答案：T），这符合判断题的特征。 | 知识层次: 题目考查对结构复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 在判断题的基础概念记忆层次中，此题仅需识别\"结构复合材料因其比强度高而受到普遍认可\"这一基本定义的正确性，属于最基础的正误判断。题目直接陈述了材料科学中关于复合材料的一个基本特性，不需要任何推导或复杂概念理解，完全符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 4102, + "question": "[d] Composites featuring continuous and aligned fibers for reinforcement generally offer properties that are highly isotropic compared to most metals (random polycrystals).", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为F表示错误），符合判断题的特征 | 知识层次: 题目考查对复合材料各向异性特性的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题的基础概念记忆题型中，该题目属于中等难度。虽然考察的是复合材料的基本特性（纤维增强的方向性与各向异性关系），但需要学生准确理解\"isotropic\"（各向同性）与金属材料（通常为各向异性）的对比关系，并能识别出题干中\"highly isotropic\"表述的错误。这比简单判断定义正误（等级1）要求更高，但尚未达到需要分析复杂概念关系的等级3难度。" + }, + { + "idx": 4103, + "question": "Which of the following materials are typically used as fibers?(a) Graphite/carbon(b) Silicon carbide(c) Silicon nitride(d) Aluminum oxide(e) Glass(f) Boron(g) Steel\nh) Tungsten\ni) Molybdenum", + "answer": "Graphite, silicon carbide, glass, boron, and aluminum oxide are typically used as fibers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作纤维，答案是从给定选项中选择的特定材料组合 | 知识层次: 题目考查对常用纤维材料的基础概念记忆，只需识别哪些材料通常被用作纤维，不涉及复杂分析或应用。 | 难度: 在选择题中属于中等偏简单难度，需要对常见纤维材料有基本认知和记忆，但不需要深入理解材料性能或复杂区分。题目考察的是对典型纤维材料的识别能力，属于基础概念记忆范畴，但选项较多需要一定辨析能力。" + }, + { + "idx": 4104, + "question": "Match the fiber type 'Whiskers' with its description.", + "answer": "Whiskers are single crystals with extremely large length-to-diameter ratios.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求将纤维类型与其描述进行匹配，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对纤维类型'Whiskers'的基本定义和特征记忆，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求匹配纤维类型与其基本定义，属于最基础的定义简答级别。题目仅涉及单一概念的记忆，不需要解释或描述复杂关系，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4105, + "question": "Match the fiber type 'Fibers' with its description.", + "answer": "Fibers are polycrystalline or amorphous materials with small diameters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求将纤维类型与其描述进行匹配，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对纤维类型基本定义的记忆和理解，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求匹配纤维类型与其描述，且描述内容为纤维的基本定义（多晶或非晶材料、小直径）。这属于最基础的概念记忆层面，不需要额外的解释或复杂概念体系的阐述，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 4106, + "question": "Match the fiber type 'Wires' with its description.", + "answer": "Wires are large-diameter metals.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求将纤维类型与其描述进行匹配，属于从多个选项中选择正确答案的选择题类型 | 知识层次: 题目考查对纤维类型及其描述的基本概念记忆，仅需匹配\"Wires\"与其定义\"large-diameter metals\"，属于基础概念记忆层次。 | 难度: 在选择题中属于简单难度，仅需直接记忆并识别\"Wires\"的定义描述，无需进行概念辨析或深度理解。题目仅考察基础概念的记忆能力，符合等级1\"简单概念识别，直接记忆\"的标准。" + }, + { + "idx": 4107, + "question": "For a composite material, which phase normally has the higher elastic modulus?(a) Fiber phase(b) Matrix phase", + "answer": "The fiber phase normally has a higher elastic modulus than the matrix phase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（a）Fiber phase和（b）Matrix phase中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查复合材料中纤维相和基体相弹性模量的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆复合材料中纤维相和基体相的弹性模量高低关系，无需进行概念辨析或深度理解。" + }, + { + "idx": 4108, + "question": "For a composite material, how does the ductility of the matrix phase normally compare with the ductility of the dispersed phase?(a) more ductile(b) less ductile", + "answer": "A composite's matrix phase is normally more ductile than the dispersed phase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择正确的比较结果，符合选择题的特征 | 知识层次: 题目考查复合材料中基体相和分散相延展性的基本概念记忆，属于基础概念的理解和比较 | 难度: 在选择题中属于简单概念识别，直接记忆的题目。题目仅考察对复合材料中基体相和分散相延展性的基本记忆，无需复杂理解或分析。" + }, + { + "idx": 4109, + "question": "Aramid fiber-reinforced composites have very high tensile strengths and relatively low compressive strengths.(a) True(b) False", + "answer": "True. Aramid fiber-reinforced composites have very high tensile strengths and relatively low compressive strength.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断结果 | 知识层次: 题目考查对芳纶纤维增强复合材料基本性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，此题属于基本概念正误判断。题目直接考察对芳纶纤维增强复合材料力学性能的基本记忆，只需判断\"高拉伸强度、低压缩强度\"这一特性陈述是否正确，不需要进行复杂的概念理解或分析。属于判断题中最基础的知识点考察。" + }, + { + "idx": 4110, + "question": "Which of aramid and metal fibers have higher strength-to-weight ratios?(a) Aramid fibers(b) Metal fibers", + "answer": "Aramid fibers have higher strength-to-weight ratios than metal fibers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对芳纶纤维和金属纤维强度重量比这一基本概念的记忆和理解，无需复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解\"强度重量比\"这一基本概念，并对芳纶纤维和金属纤维的性能特点进行简单辨析。虽然涉及两种材料的比较，但属于材料科学中较为基础的知识点，不需要复杂的分析过程。" + }, + { + "idx": 4111, + "question": "Carbon fiber-reinforced composites have relatively high strengths?", + "answer": "Carbon fiber-reinforced composites have relatively high strengths.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），符合判断题的特征 | 知识层次: 题目考查对碳纤维增强复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断，仅需记忆碳纤维增强复合材料的基本特性即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4112, + "question": "Carbon fiber-reinforced composites have relatively high stiffnesses?", + "answer": "Carbon fiber-reinforced composites have relatively high stiffnesses.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了陈述句本身，符合判断题的特征 | 知识层次: 题目考查对碳纤维增强复合材料基本特性的记忆和理解，属于基础概念层次 | 难度: 在判断题题型中，此题属于基本概念正误判断。题目仅考察对碳纤维增强复合材料基本特性的记忆（高刚度），不需要深入理解或分析多个概念，属于该题型内最基础的难度等级。" + }, + { + "idx": 4113, + "question": "Carbon fiber-reinforced composites have high service temperatures (>200 degrees C)?", + "answer": "Carbon fiber-reinforced composites have high service temperatures (>200 degrees C).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对或错），答案直接给出了该陈述的判断结果，符合判断题的特征。 | 知识层次: 题目考查对碳纤维增强复合材料基本性能的记忆和理解，属于基础概念的记忆性知识 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对碳纤维增强复合材料高温性能这一基础概念的简单记忆，不需要深入理解或复杂推理，符合等级1的难度标准。" + }, + { + "idx": 4114, + "question": "Which of the following materials are typically used as whiskers?(a) graphite/carbon(b) silicon carbide(c) silicon nitride(d) aluminum oxide(e) glass(f) boron(g) steel\nh) tungsten\ni) molybdenum", + "answer": "Graphite, silicon carbide, silicon nitride, and aluminum oxide are typically used as whiskers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作晶须(whiskers)，答案给出了具体的选择项。 | 知识层次: 题目考查对常用晶须材料的基础概念记忆，只需从选项中识别出典型的晶须材料，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要考生对常见晶须材料有基本记忆和理解，但选项中的干扰项（如玻璃、钢铁等）与正确选项的区分度较高，只需简单辨析即可选出正确答案。不需要复杂的分析或深度理解。" + }, + { + "idx": 4115, + "question": "Which of the following materials are typically used as wires in composites?(a) graphite/carbon(b) silicon carbide(c) silicon nitride\n\\mathrm{d}) aluminum oxide(e) glass(f) boron(g) steel\nh) tungsten\ni) molybdenum", + "answer": "Steel, tungsten, and molybdenum are typically used as wires in composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作复合材料中的线材，答案给出了具体的选择结果，符合选择题的特征。 | 知识层次: 题目考查对复合材料中常用金属丝材料的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解复合材料中常用金属丝材料的基本概念，并进行简单辨析。题目给出了多个选项，但正确答案集中在金属材料（钢、钨、钼）这一特定类别，需要考生对复合材料增强相有基本了解，但不需要进行复杂的比较分析。" + }, + { + "idx": 4116, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better fracture toughnesses?", + "answer": "Ceramic-matrix composites have higher fracture toughnesses than other ceramic materials.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（陶瓷基复合材料是否比其他陶瓷材料具有更好的断裂韧性），答案直接给出了明确的判断结果（是或否）。 | 知识层次: 题目考查对陶瓷基复合材料基本性能（断裂韧性）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对陶瓷基复合材料与其他陶瓷材料断裂韧性比较的基本概念理解，需要学生掌握相关定义和分类知识，但不需要进行复杂的概念分析或推理。" + }, + { + "idx": 4117, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better oxidation resistance?", + "answer": "The answer is not provided in the given information.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（better oxidation resistance），符合判断题的特征。答案形式也是典型的判断题回答方式（未提供信息）。 | 知识层次: 题目考查对陶瓷基复合材料氧化抗性的基本概念记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目涉及陶瓷基复合材料与其他陶瓷材料在抗氧化性方面的比较，需要考生对陶瓷材料的性能特点有一定理解，但不需要进行复杂的分析或推理。属于基础概念的应用判断，但比单纯的定义正误判断（等级1）要求稍高。" + }, + { + "idx": 4118, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better stability at elevated temperatures?", + "answer": "The answer is not provided in the given information.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陶瓷基复合材料在高温下是否比其他陶瓷材料具有更好的稳定性，属于对陈述的判断 | 知识层次: 题目考查对陶瓷基复合材料在高温下稳定性的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目涉及陶瓷基复合材料在高温下的稳定性与其他陶瓷材料的比较，需要考生对陶瓷基复合材料的基本特性有一定理解，但不需要进行复杂的分析或比较多个概念。因此，在判断题的框架内，该题目属于中等难度。" + }, + { + "idx": 4119, + "question": "Which of the following materials are typically used as stabilizers in transformation-toughened ceramic-matrix composites?(a) \\mathrm{CaO}(b) MgO(c) \\mathrm{Y}_{2} \\mathrm{O}_{3}(d) \\mathrm{CeO}(e) \\mathrm{Al}_{2} \\mathrm{O}_{3}(f) \\mathrm{SiC}", + "answer": "(\\mathrm{CaO}, MgO, \\mathrm{Y}_{2} \\mathrm{O}_{3}, and \\mathrm{CeO} are typically used as stabilizers in transformation-toughened ceramicmatrix composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作相变增韧陶瓷基复合材料的稳定剂，符合选择题的特征 | 知识层次: 题目考查对特定材料在陶瓷基复合材料中作为稳定剂的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要记忆和理解哪些材料常用作稳定剂，但选项中的材料都是常见的稳定剂候选，只需基本的概念理解和简单辨析即可选出正确答案。不需要复杂的分析或深度理解多个概念的交互作用。" + }, + { + "idx": 4120, + "question": "Do carbon-carbon composites exhibit high tensile moduli at elevated temperatures?", + "answer": "Carbon-carbon composites have high tensile moduli at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了判断结果（陈述为真）。这符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料在高温下性能的基础概念记忆，仅需知道其基本特性即可判断陈述的对错，不涉及复杂分析或综合应用。 | 难度: 在判断题题型中，该题目仅涉及对碳碳复合材料高温下拉伸模量的基本特性判断，属于基础概念正误判断。题目陈述直接对应材料科学中的基本概念记忆，无需复杂推理或概念间的关联分析，符合等级1的简单正误判断标准。" + }, + { + "idx": 4121, + "question": "Do carbon-carbon composites exhibit high tensile strengths at elevated temperatures?", + "answer": "Carbon-carbon composites have high tensile strengths at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Do carbon-carbon composites exhibit high tensile strengths at elevated temperatures?），而答案直接给出了判断结果（Carbon-carbon composites have high tensile strengths at elevated temperatures.），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料在高温下性能的基础概念记忆，仅需了解其基本特性即可判断陈述的对错，无需复杂分析或综合应用。 | 难度: 在判断题的基础概念记忆题型中，该题目属于中等难度。虽然涉及的是碳碳复合材料的基本特性（高温下的拉伸强度），但需要学生对这一特定材料性能有明确的记忆和理解，而非简单的定义或分类判断。这比单纯判断\"碳碳复合材料是否属于复合材料\"（等级1）要难，但比判断涉及复杂机理或多种因素交互作用的陈述（等级3）要简单。" + }, + { + "idx": 4122, + "question": "Do carbon-carbon composites exhibit resistance to creep?", + "answer": "Carbon-carbon composites are highly resistant to creep.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（碳碳复合材料是否具有抗蠕变性），答案直接给出了对陈述的判断（是抗蠕变的），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料抗蠕变性能这一基础概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在判断题的基础概念记忆题型中，此题仅需判断碳碳复合材料是否具有抗蠕变性这一基本特性，属于直接记忆材料基本属性的简单判断，无需深入理解或分析复杂概念。" + }, + { + "idx": 4123, + "question": "Do carbon-carbon composites exhibit large fracture toughness values?", + "answer": "Carbon-carbon composites have large fracture toughness values.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其真假（对错），答案直接给出了判断结果（Carbon-carbon composites have large fracture toughness values），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本性能的记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问碳碳复合材料是否具有较大的断裂韧性值，答案也是直接陈述事实。这只需要学生对碳碳复合材料的基本特性有记忆性了解即可判断，不需要深入理解或分析复杂概念。因此在该题型内属于最简单的难度等级。" + }, + { + "idx": 4124, + "question": "Do carbon-carbon composites exhibit high thermal conductivities?", + "answer": "Carbon-carbon composites have high thermal conductivities.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个简单的陈述句提问，要求判断碳碳复合材料是否具有高热导率，答案是对该陈述的直接判断（肯定或否定），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本热导性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接询问碳碳复合材料是否具有高热导率这一基本属性，只需记忆相关材料特性即可作答，无需进行概念理解或复杂分析。属于该题型下最基础的难度等级。" + }, + { + "idx": 4125, + "question": "Do carbon-carbon composites exhibit low coefficients of thermal expansion?", + "answer": "Carbon-carbon composites have low coefficients of thermal expansion.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Do carbon-carbon composites exhibit low coefficients of thermal expansion?），而答案直接给出了判断结果（Carbon-carbon composites have low coefficients of thermal expansion.），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目仅涉及对碳碳复合材料基本特性的正误判断（低热膨胀系数），属于最基础的概念记忆层面，无需复杂推理或概念关联。同类题型中属于直接考察定义性知识的简单题目。" + }, + { + "idx": 4126, + "question": "Do carbon-carbon composites exhibit resistance to oxidation at elevated temperatures?", + "answer": "The answer does not specify resistance to oxidation at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断碳碳复合材料在高温下是否具有抗氧化性，答案是对该陈述的判断（未明确说明是否具有抗氧化性），符合判断题的特征。 | 知识层次: 题目考查对碳-碳复合材料在高温下抗氧化性能的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目仅询问碳碳复合材料在高温下是否具有抗氧化性，不涉及复杂概念或需要深入理解。学生只需回忆相关基础概念即可作答，无需分析或推理步骤。" + }, + { + "idx": 4127, + "question": "Are carbon-carbon composites low cost?", + "answer": "The answer does not specify low cost.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，询问碳碳复合材料是否低成本，答案直接给出了判断结果（未明确说明低成本），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料成本特性的基本概念记忆，属于定义和分类层面的基础知识点。 | 难度: 在判断题题型中，该题目仅涉及对碳碳复合材料是否低成本的简单正误判断，属于最基础的概念记忆层面。题目不需要理解复杂概念或进行多步骤分析，仅需回忆相关定义即可作答，因此属于等级1的基本概念正误判断难度。" + }, + { + "idx": 4128, + "question": "Laminar composites have high strengths in all directions (in three dimensions).(a) True(b) False", + "answer": "False. Laminar composites have high strengths in all directions only in their two-dimensional planes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附带简要解释。 | 知识层次: 题目考查对层状复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在判断题中属于基本难度，仅需记忆复合材料的基本特性即可判断正误，无需深入理解或分析复杂概念。题目直接考察对层状复合材料强度方向性的基础定义记忆。" + }, + { + "idx": 4129, + "question": "The strong outer sheets of sandwich panels are separated by a layer of material that is(a) less dense than the outer sheet material(b) more dense than the outer sheet material", + "answer": "The strong outer sheets of sandwich panels are separated by a layer of material that is less dense than the outer sheet material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对夹层板结构基本概念的记忆和理解，仅需知道夹层板中间层材料密度低于外层材料这一基本特性即可作答。 | 难度: 在选择题题型中，此题属于最基础的难度等级。题目仅考察对三明治板结构的基本记忆（外层材料与中间层材料的密度关系），不需要任何概念辨析或推理过程。学生只需记住\"三明治板的中间层材料密度较低\"这一简单事实即可作答，属于直接记忆型题目。" + }, + { + "idx": 4130, + "question": "To what temperature would 23.0kg of some material at 100^{\\circ} C be raised if 255kJ of heat is supplied? Assume a C_{p} value of 423 J/ kg-K for this material.\n(A) 26.2^{\\circ} C\n(B) 73.8^{\\circ} C\n(C) 126^{\\circ} C\n(D) 152^{\\circ} C", + "answer": "the final temperature is 126^{\\circ} C, which corresponds to answer C.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目涉及基本的热力学公式应用（Q = mC_pΔT），只需要直接套用公式进行简单计算即可得到答案，不需要多步计算或综合分析。 | 难度: 在选择题中属于简单难度，仅需直接应用热量计算公式Q=mcΔT，并进行一步代数运算即可得出答案。题目提供了所有必要参数，无需公式变形或多步骤推理，符合等级2\"简单公式选择和应用\"的标准。" + }, + { + "idx": 4131, + "question": "A rod of some material 0.50{m} long elongates 0.40mm on heating from 50^{\\circ} C to 151^{\\circ} C. What is the value of the linear coefficient of thermal expansion for this material?\n(A) 5.30 × 10^{-6}\\left({ }^{\\circ} C\\right)^{-1}\n(B) 7.92 × 10^{-6}\\left({ }^{\\circ} C C\\right)^{-1}\n(C) 1.60 × 10^{-5}\\left({ }^{\\circ} C\\right)^{-1}\n(D) 1.24 × 10^{-6}\\left({ }^{\\circ} C_{-}^{1}\\right.", + "answer": "the linear coefficient of thermal expansion for this material is 7.92 × 10^{-6} \\left(^{\\circ}c\\right)^{-1}, which is answer b.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的线性热膨胀系数值，并且提供了多个选项供选择。 | 知识层次: 题目主要考查线性热膨胀系数的基本公式应用和简单计算，只需套用公式α = ΔL / (L0 × ΔT)进行计算即可得到答案，不需要多步计算或综合分析。 | 难度: 在选择题中属于基础难度，仅需直接套用线性热膨胀系数公式（α = ΔL / (L0 × ΔT)）并进行简单计算即可得出答案，无需公式变形或多步骤推理。" + }, + { + "idx": 4132, + "question": "A 10 meter long square bar of 316 stainless steel (edge length of 5 cm, with a modulus of 193 \\mathrm{GPa} and a yield point of 290 MPa ) is bolted securely in place when its installation temperature was around [1]^{\\circ} C. What is the expected thermal stress in the bar when its service temperature reaches [F]^{o} C ? Enter a negative indicate compressive stress, if necessary. The thermal expansion coefficient of 316 stainless steel is 16.0 × 10^{-6} \\mathrm{I} /{ }^{\\circ} C.", + "answer": "sigma_{th} = (193,000)(16 × 10^{-6})([i] - [f]) MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解热应力，答案给出了具体的计算公式和单位，需要代入温度值进行计算。 | 知识层次: 题目主要考查热应力公式的直接应用和简单计算，涉及基本的热膨胀系数和弹性模量的概念，但不需要多步计算或综合分析。 | 难度: 该题目属于计算题中的单一公式直接计算类型。题目中只需要应用热应力公式 sigma_{th} = E * alpha * (T_i - T_f) 进行计算，无需额外的步骤或公式组合。所有需要的参数都已直接给出，计算过程简单直接，属于该题型内最基础的难度等级。" + }, + { + "idx": 4133, + "question": "Which of the following 1kg samples is expected to change temperature the least if 100kJ of heat is perfectly transferred to each of them at a constant pressure of 1 atmosphere. The initial temperature of each specimen is 25^{\\circ} C. (a) Aluminum (b) Copper (c) Gold (d) Borosilicate Glass (e) Polystyrene", + "answer": "polystyrene will experience the smallest temperature change.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个预期温度变化最小的材料，属于典型的选择题形式 | 知识层次: 题目考查比热容的基本概念和简单计算，需要应用比热容公式来比较不同材料在相同热量输入下的温度变化。虽然涉及多个材料的选择，但计算过程直接且无需复杂分析。 | 难度: 在选择题中属于简单难度，只需要直接应用比热容的概念和公式，比较不同材料在相同热量输入下的温度变化。题目提供了所有必要信息，无需复杂计算或公式变形，仅需选择比热容最大的材料（聚苯乙烯）即可得出答案。" + }, + { + "idx": 4134, + "question": "If you were to locally heat identical geometry plates of the materials listed below with the same heat source, which would increase in temperature the fastest? (a) Polystyrene (b) Aluminum (c) Copper (d) Gold (e) Borosilicate Glass", + "answer": "In this scenario, the material with the highest thermal conductivity will conduct heat the fastest. Therefore this material will absorb heat and increase in temperature the fastest. In this case, copper has the highest thermal conductivity.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案，符合选择题的特征。答案也是从给定的选项中选择最合适的材料，并给出了解释。 | 知识层次: 题目考查对材料热导率这一基本概念的简单记忆和理解，只需知道不同材料的热导率差异即可选择正确答案，无需复杂计算或综合分析。 | 难度: 在选择题题型中，该题目属于概念理解和简单辨析难度。虽然题目考察的是基础概念记忆（热导率），但需要考生对不同材料的热导率有一定了解，并能进行简单比较。不需要复杂的分析步骤，但比单纯记忆定义略高一个难度层级。" + }, + { + "idx": 4135, + "question": "This ceramic outlier has the highest room-temperature thermal conductivity of about 2,000 watts per meter per kelvin, a value that is five time higher than the best thermally conductive metals.\n(a) \\mathrm{Al}_{2} \\mathrm{O}_{3}\n(b) \\mathrm{CaF}_{2}\n(c) \\mathrm{TiO}_{2}\n(d) \\mathrm{SrTiO}_{3}\n(e) C (diamond)", + "answer": "Diamond has the highest thermal conductivity of these options.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择具有最高室温热导率的陶瓷材料，答案形式为选择其中一个选项。 | 知识层次: 题目考查对陶瓷材料热导率这一基础概念的记忆，要求识别出具有最高室温热导率的材料。 | 难度: 在选择题中属于中等难度，需要理解陶瓷材料的导热性能并进行简单辨析。虽然题目给出了具体的导热数值，但需要考生知道金刚石（diamond）是已知室温下导热性能最好的材料之一，并能与其他选项中的常见陶瓷材料进行区分。这超出了简单的概念识别，但不需要复杂的分析步骤。" + }, + { + "idx": 4136, + "question": "Which two of the following are ferromagnetic materials? \\\\(a) Aluminum oxide \\\\(b) Copper \\\\ c) Aluminum \\\\ d) Titanium \\\\ e) Iron ( \\alpha ferrite) \\\\ f) Nickel \\\\ g) MnO \\\\ h) \\mathrm{Fe}_{3} \\mathrm{O}_{4} \\\\ i) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}\n}", + "answer": "Iron ( \\alpha ferrite) and nickel are ferromagnetic materials.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择两个铁磁性材料，符合选择题的特征 | 知识层次: 题目考查对铁磁性材料基本概念的记忆和理解，只需识别出哪些材料属于铁磁性材料即可，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要考生识别并记忆常见的铁磁性材料，但选项中有多个干扰项需要简单辨析。虽然涉及基础概念记忆，但需要区分铁磁性与其他磁性材料（如反铁磁性的MnO、亚铁磁性的Fe3O4等），属于概念理解和简单辨析的范畴。" + }, + { + "idx": 4137, + "question": "Which of the following materials display(s) antiferromagnetic behavior?(a) Aluminum oxide(b) Copper(c) Aluminum(d) Titanium(e) Iron ( \\alpha ferrite)(f) Nickel(g) MnO\nh) \\mathrm{Fe}_{3} \\mathrm{O}_{4}\ni) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}", + "answer": "(\\mathrm{MnO} is an antiferromagnetic material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择显示反铁磁行为的材料，符合选择题的特征 | 知识层次: 题目考查对反铁磁性材料的基本概念和分类的记忆，只需识别哪些材料具有反铁磁性行为，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解并辨析不同材料的磁性行为。虽然题目给出了多个选项，但只需要识别出具有反铁磁性的材料（MnO），这需要对基础概念有一定的理解和记忆。不需要复杂的分析或深度理解，但比简单的概念识别稍难一些。" + }, + { + "idx": 4138, + "question": "Which of the following are ferrimagnetic materials?(a) Aluminum oxide(b) Copper(c) Aluminum(d) Titanium(e) Iron ( \\alpha ferrite)(f) Nickel(g) MnO\nh) \\mathrm{Fe}_{3} \\mathrm{O}_{4}\ni) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}", + "answer": "(\\mathrm{Fe}_{3} \\mathrm{O}_{4} and \\mathrm{NiFe}_{2} \\mathrm{O}_{4} are ferrimagnetic materials.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择出属于亚铁磁性材料的正确答案，符合选择题的特征 | 知识层次: 题目考查对铁磁性材料分类的基本概念记忆，只需识别哪些材料属于铁磁性材料，无需复杂分析或计算。 | 难度: 在选择题中属于中等偏易难度，需要理解并区分铁磁性、亚铁磁性等基本概念，但选项中的亚铁磁性材料（Fe3O4和NiFe2O4）具有明显特征，只需简单记忆和基本概念辨析即可作答。" + }, + { + "idx": 4139, + "question": "The formula for yttrium iron garnet \\left(\\mathrm{Y}_{3} \\mathrm{Fe}_{3} \\mathrm{O}_{12}\\right) may be written in the form \\mathrm{Y}_{3}^{*} \\mathrm{Fe}_{2}^{*} \\mathrm{Fe}_{3}^{d} \\mathrm{O}_{12}^{2}, where the superscripts a, c, and d represent different sites on which the \\mathrm{Y}^{3+} and \\mathrm{Fe}^{3+} ions are located. The spin magnetic moments for the \\mathrm{Y}^{3+} and \\mathrm{Fe}^{\\text {out }} ions positioned in the \\mathrm{a} and C sites are oriented parallel to one another and antiparallel to the \\mathrm{Fe}^{3+} ions in \\mathrm{d} sites. Compute the number of Bohr magnetons associated with each \\mathrm{Y}^{3+} ion, given the following information: (1) each unit cell consists of eight formula \\left(\\mathrm{Y}_{3} \\mathrm{Fe}_{5} \\mathrm{O}_{12}\\right) units; (2) the unit cell is cubic with an edge length of 1.2376nm; (3) the saturation magnetization for this material is 1.0 × 10^{4} \\mathrm{~A} / m; and (4) assume that there are 5 Bohr magnetons associated with each \\mathrm{Fe}^{3+} ion.", + "answer": "the number of bohr magnetons associated with each \\mathrm{y}^{3+} ion is 1.75 \\mathrm{bm}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定每个Y3+离子所关联的玻尔磁子数。解答过程涉及使用给定的物理参数和公式进行计算，最终得出一个具体的数值结果（1.75 BM）。 | 知识层次: 题目需要多步计算和概念关联，包括理解晶体结构、磁矩计算、单位转换等，涉及多个知识点的综合应用，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要结合多个概念（如磁矩、晶体结构、饱和磁化强度等）进行多步计算。题目提供了多个信息点，要求考生能够正确关联和应用这些信息，最终推导出每个Y³⁺离子的玻尔磁子数。虽然计算步骤较多，但每一步的计算相对明确，属于中等应用层次的计算题。" + }, + { + "idx": 4140, + "question": "At the Curie temperature, the saturation magnetization abruptly diminishes. Which of the following magnetic material types will have Curie temperatures?(a) Diamagnetics(b) Paramagnetics(c) Ferromagnetics(d) Antiferromagnetics(e) Ferrimagnetics", + "answer": "Ferromagnetic and ferrimagnetic materials will have Curie temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案形式为从给定选项中选择正确的选项组合。 | 知识层次: 题目考查对磁性材料基本分类及其特性的记忆和理解，特别是关于居里温度与不同类型磁性材料的关系。 | 难度: 在选择题中属于中等难度，需要理解磁性材料的基本分类及其特性，特别是关于Curie温度的概念。虽然题目涉及多个选项，但主要考察的是对铁磁性和亚铁磁性材料特性的记忆和简单辨析，不需要复杂的分析或深度理解。" + }, + { + "idx": 4141, + "question": "In a polycrystalline material, each grain will always consist of just a single domain.(a) True(b) False", + "answer": "False. In a polycrystalline material, each grain may consist of more than one domain.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"True\"或\"False\"），并且答案直接给出了判断结果（False）和简要解释。 | 知识层次: 题目考查对多晶材料中晶粒和畴的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在判断题题型中，此题属于基本概念正误判断。题目直接考察对多晶材料中晶粒与磁畴关系的定义记忆，只需知道\"一个晶粒可能包含多个磁畴\"这一基本事实即可判断。不需要进行概念理解或复杂分析，属于该题型中最基础的难度等级。" + }, + { + "idx": 4142, + "question": "With increasing temperature antiferromagnetic materials eventually become which of the following?(a) Diamagnetics(b) Paramagnetics(c) Ferromagnetics(d) Antiferromagnetics(e) Ferrimagnetics", + "answer": "With increasing temperature antiferromagnetic materials eventually become paramagnetic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的五个选项中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对反铁磁材料随温度变化行为的基本概念记忆，属于基础概念的记忆和理解范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解反铁磁材料在温度升高时的行为变化，并正确识别其最终转变为顺磁性。虽然涉及基本概念的记忆，但需要一定的概念理解和简单辨析能力，而非直接的概念识别。" + }, + { + "idx": 4143, + "question": "Which type(s) of magnetic materials may be classified as either soft or hard?(a) Diamagnetic(b) Paramagnetic(c) Ferromagnetic(d) Antiferromagnetic(e) Ferrimagnetic", + "answer": "Ferromagnetic and ferrimagnetic materials may be classified as either soft or hard.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案明确指出了正确的选项（Ferromagnetic and ferrimagnetic），符合选择题的特征。 | 知识层次: 题目考查对磁性材料分类的基础概念记忆，特别是软磁和硬磁材料的分类，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解磁性材料的基本分类并区分软磁和硬磁材料的特性，但不需要复杂的分析或深度推理。" + }, + { + "idx": 4144, + "question": "Which of the following characteristics are displayed by soft magnetic materials in terms of hysteresis loop size?", + "answer": "Soft materials have relatively small relative hysteresis loops.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断软磁材料在磁滞回线尺寸方面是否具有特定特征（相对较小的磁滞回线），这属于对陈述事实的判断。虽然题目以\"which of the following\"开头，但实际给出的答案是一个明确的判断性陈述，而非从多个选项中选择。 | 知识层次: 题目考查对软磁材料磁滞回线特性的基本概念记忆和理解，属于基础概念层次。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对软磁材料磁滞回线特性的记忆，无需深入理解或分析复杂概念，只需确认陈述是否符合基础定义。属于该题型内最基础的难度等级。" + }, + { + "idx": 4145, + "question": "Which of the following characteristics are displayed by soft magnetic materials in terms of magnetization and demagnetization fields?", + "answer": "Magnetization and demagnetization may be achieved using relatively low applied fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查软磁材料在磁化和退磁过程中的基本特性，属于对材料基本概念的记忆和理解。 | 难度: 在选择题中属于中等偏易难度，需要理解软磁材料的基本特性（如磁化和退磁所需场强较低），但不需要进行复杂的概念区分或深度分析。题目主要考察对基础概念的简单辨析能力。" + }, + { + "idx": 4146, + "question": "Which of the following characteristics are displayed by hard magnetic materials in terms of hysteresis loop size?", + "answer": "Hard materials have relatively large hysteresis loops.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目陈述了一个关于硬磁材料特性的论断（\"Hard materials have relatively large hysteresis loops\"），要求判断这个陈述的正确性。虽然题目以\"Which of the following\"开头，但实际给出的只是一个需要判断对错的陈述句，没有提供多个选项供选择。 | 知识层次: 题目考查对硬磁材料磁滞回线特性的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在判断题题型中，该题目属于基本概念正误判断。题目直接考察对硬磁材料磁滞回线特性的记忆，只需知道硬磁材料具有较大的磁滞回线这一基本事实即可判断正确，无需深入理解或分析复杂概念。" + }, + { + "idx": 4147, + "question": "Which of the following characteristics are displayed by hard magnetic materials in terms of magnetization and demagnetization field requirements?", + "answer": "Magnetization and demagnetization require relatively high applied fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对硬磁材料在磁化和退磁过程中所需场强的基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解硬磁材料的基本特性，即磁化和退磁需要较高的外加磁场。虽然涉及概念理解，但不需要复杂的比较分析或深度推理，属于对基础概念的简单辨析。" + }, + { + "idx": 4148, + "question": "What is the order of magnitude wavelength for visible light?(a) 0.5 Angstroms(b) 0.5 nanometers(c) 0.5 micrometers(d) 0.5 millimeters(e) 0.5 meters(f) 0.5 kilometers", + "answer": "The wavelength of visible light is on the order of 0.5 \\mathrm{micrometers}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案形式为单一选项的确认 | 知识层次: 题目考查对可见光波长数量级的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆可见光的波长范围即可选出正确答案，无需复杂的概念辨析或深度理解。" + }, + { + "idx": 4149, + "question": "In the visible spectrum, a thick metal specimen will be(a) Transparent(b) Translucent(c) Opaque", + "answer": "In the visible spectrum, a thick metal specimen is opaque.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择一个正确答案 | 知识层次: 题目考查对金属光学性质这一基本概念的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题中属于简单难度，仅需直接记忆金属在可见光谱中的基本光学性质（不透明性），无需概念辨析或复杂推理。" + }, + { + "idx": 4150, + "question": "In the visible spectrum, an electrical insulator that is a single crystal and without porosity is normally(a) Transparent(b) Opaque(c) Translucent", + "answer": "In the visible spectrum, an electrical insulator that is a single crystal and without porosity\nnormally transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a) Transparent、(b) Opaque、(c) Translucent中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对单晶无孔绝缘体在可见光谱中光学性质的基础概念记忆，仅需知道这类材料通常透明的特性即可作答，不涉及复杂分析或应用。 | 难度: 在选择题中属于简单难度，仅需直接记忆基础概念（单晶无孔隙绝缘体在可见光谱中的光学特性），无需进行概念辨析或复杂分析。" + }, + { + "idx": 4151, + "question": "Match the type of light transmission with its description: Transmits light with relative little absorption.", + "answer": "A transparent material transmits light with relatively little absorption.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求匹配光的传输类型与其描述，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对透明材料基本概念的记忆和理解，仅需识别并匹配描述与材料类型的关系，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答透明材料的基本定义和特性，属于最基础的概念记忆。题目没有涉及复杂的概念解释或体系阐述，仅需简单描述透明材料的光传输特性即可。因此，在同题型内属于最低难度等级。" + }, + { + "idx": 4152, + "question": "Match the type of light transmission with its description: Transmits light diffusely.", + "answer": "A translucent material transmits light diffusely.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求匹配光的传输类型与其描述，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对材料光学性质中基本概念（translucent material）的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求匹配光传输类型与其描述，且答案直接对应\"translucent material\"的定义特征（漫射透光）。这属于最基础的概念记忆层级，无需解释或延伸，完全符合等级1对定义性知识点的考查标准。" + }, + { + "idx": 4153, + "question": "Match the type of light transmission with its description: Is impervious to light transmission.", + "answer": "An opaque material is impervious to light transmission.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求匹配光的传输类型与其描述，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对材料光学性质基本概念的记忆和理解，即不透明材料的定义和特性。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（\"An opaque material is impervious to light transmission\"），属于最基础的概念记忆层次。题目直接对应教材中的明确定义，不需要额外的解释或论述步骤，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4154, + "question": "In the visible spectrum, a semiconductor that is a single crystal and nonporous may be(a) Transparent(b) Translucent(c) Opaque", + "answer": "In the visible spectrum, a semiconductor that is a single crystal and nonporous may be transparent or opaque.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a) Transparent、(b) Translucent、(c) Opaque中选择可能的正确答案，符合选择题的特征。 | 知识层次: 题目考查半导体材料在可见光谱中的光学特性（透明或不透明）这一基础概念的记忆和理解，属于材料科学中关于材料光学性质分类的基本知识。 | 难度: 在选择题中属于中等偏下难度，需要理解半导体在可见光谱中的光学特性（透明或不透明），并能够区分单晶非多孔材料的可能表现。虽然涉及概念理解，但不需要复杂的分析或比较多个概念。" + }, + { + "idx": 4155, + "question": "To which of the following electromagnetic radiation types are bulk metals opaque?(a) radio waves(b) microwaves(c) infrared radiation(d) ultraviolet radiation(e) X-rays", + "answer": "Bulk metals are opaque to the following radiation types: radio waves, microwaves, infrared radiation, and ultraviolet radiation.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)-(e)中选择正确的电磁辐射类型，符合选择题的特征 | 知识层次: 题目考查对金属对不同电磁波段的透明性的基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解金属对不同电磁辐射的透明度特性，并进行简单辨析。虽然涉及多个选项，但都属于基础概念的记忆和理解范畴，不需要复杂的分析或深度推理。" + }, + { + "idx": 4156, + "question": "Every nonmetallic material becomes opaque to electromagnetic radiation having some wavelength.(a) True(b) False", + "answer": "True. Every nonmetallic material becomes opaque to electromagnetic radiation having some wavelength. For all nonmetallic materials there is some maximum wavelength below which electronexcitations across the band gap will occur. This results in the adsorption of radiation, and, consequently, the material becomes opaque.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附有简要解释。 | 知识层次: 题目考查对非金属材料对电磁辐射不透明性的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在判断题中属于中等难度，需要理解非金属材料对电磁辐射的透射特性这一概念，并判断陈述的正确性。虽然题目涉及基础概念，但需要一定的理解深度来确认\"所有非金属材料都会在某个波长下变得不透明\"这一陈述的正确性。" + }, + { + "idx": 4157, + "question": "Match the following material types with their light transmission characteristics: Single crystal electrical insulators - Opaque, Translucent, Transparent", + "answer": "Single crystal electrical insulators are transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Opaque, Translucent, Transparent）中选择与材料类型（Single crystal electrical insulators）匹配的光传输特性。 | 知识层次: 题目考查对单晶电绝缘体光学特性的基本概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆单晶电绝缘体的透光特性（透明），无需概念辨析或复杂理解。" + }, + { + "idx": 4158, + "question": "Match the following material types with their light transmission characteristics: Polycrystalline and nonporous electrical insulators - Translucent, Transparent, Opaque", + "answer": "Polycrystalline and nonporous electrical insulators are translucent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Translucent, Transparent, Opaque）中选择与材料类型（Polycrystalline and nonporous electrical insulators）匹配的光传输特性。 | 知识层次: 题目考查对材料类型及其光传输特性的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆材料类型与光传输特性的基本对应关系，无需复杂辨析或深度理解。" + }, + { + "idx": 4159, + "question": "Match the following material types with their light transmission characteristics: Porous electrical insulators - Transparent, Opaque, Translucent", + "answer": "Porous electrical insulators are opaque to visible light.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求将材料类型与光传输特性进行匹配，并给出解释说明，需要文字描述而非简单选择或判断 | 知识层次: 题目考查对材料类型及其光传输特性的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目仅要求对基础概念进行简单匹配和记忆性回答，无需深入解释或复杂论述。属于最基本的概念记忆层次，符合等级1的标准。" + }, + { + "idx": 4160, + "question": "For noncubic crystals, the index of refraction is lowest in the crystallographic direction that has the(a) Highest atomic packing density(b) Lowest atomic packing density", + "answer": "For noncubic crystals, the index of refraction is lowest in the crystallographic direc�on having the lowest atomic packing density.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项中选择正确答案 | 知识层次: 题目考查对非立方晶体折射率与原子堆积密度关系的基本概念记忆，属于基础概念的记忆和理解范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解折射率与原子堆积密度之间的关系，并进行简单的概念辨析。虽然涉及非立方晶体的特性，但题目明确给出了两个对立选项，降低了判断复杂度。" + }, + { + "idx": 4161, + "question": "A completely amorphous and nonporous polymer will be(a) Transparent(b) Translucent(c) Opaque", + "answer": "A completely amorphous and nonporous polymer will be transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对非晶态聚合物光学性质这一基本概念的记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题中属于简单难度，仅需直接记忆非晶态无孔聚合物的光学特性即可选出正确答案，无需复杂辨析或深度理解。" + }, + { + "idx": 4162, + "question": "A beam of light is shined on a thin (sub-millimeter thick) single crystal wafer of material. The light source is special since it can be tuned to provide any wavelength of visible light on demand. The specimen is illuminated such that the frequency of light is decreased over time while the transmitted intensity of the light is measured. If the sample becomes transparent when the frequency is less than [F] THz, what is the band gap of the material, in eV? Assume that an intrinsic excitation of electrons is responsible for the absorption.", + "answer": "the band gap of the material is 4.135 × 10^{-3} [f] ev.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（将频率转换为电子伏特）来确定材料的带隙，答案是一个具体的数值计算结果（4.135 × 10^{-3} [f] ev），符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的频率计算材料的带隙能量。虽然需要理解带隙和光频率之间的关系，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在计算题中属于最低难度，只需要直接应用单一公式（E = hν）进行简单数值计算，无需组合多个公式或进行复杂推导。题目中已经明确给出频率与带隙的关系，解题步骤非常直接。" + }, + { + "idx": 4163, + "question": "Select the word combination that best completes this statement.\nWhen a semiconductor is exposed to a light source, its intrinsic carrier concentration will increase if the [a] of the light is [b] than band gap of the semiconductor.\n[a]: intensity, energy, wavelength, frequency, voltage, current, resistance\n[b]: greater, less", + "answer": "([a] energy\n[b] greater", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的单词组合来补全句子，符合选择题的特征。 | 知识层次: 题目考查半导体基本特性的记忆和理解，特别是关于光激发和带隙的基本概念。 | 难度: 在选择题题型内，这道题目属于中等难度。虽然考察的是基础概念记忆，但需要学生对半导体物理中的\"本征载流子浓度\"和\"带隙\"概念有基本理解，并能正确关联光子的能量与半导体带隙的关系。题目要求从多个选项中选出正确的物理量([a]部分)和比较关系([b]部分)，这比单纯记忆定义需要更深一层的概念辨析能力。不过题目没有涉及复杂计算或多步骤推理，因此不属于最高难度等级。" + }, + { + "idx": 4164, + "question": "Match the luminescence characteristics with their descriptions.\nReemission of photons occurs in much less than one second after excitation.\n- Phosphorescence\n- Fluorescence\nReemission of photons occurs in more than one second after excitation.\n- Fluorescence\n- Phosphorescence", + "answer": "Fluorescence involves reemission of photons in much less than one second after excitation; while phosphorescence involves reemission of photons in more than one second after excitation.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的匹配项，即将发光特性与描述进行配对。 | 知识层次: 题目考查荧光和磷光的基本定义和区别，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解荧光和磷光的基本定义，并能简单区分两者的主要特征（光子重发射时间）。虽然涉及两个概念的辨析，但区分标准明确单一（时间阈值），不需要复杂的推理过程。" + }, + { + "idx": 4165, + "question": "Only pure materials luminesce.(a) True(b) False", + "answer": "False. Luminescent materials contain impurities.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断结果 | 知识层次: 题目考查对发光材料基本概念的记忆和理解，即纯材料与掺杂材料在发光特性上的区别。 | 难度: 在判断题的基础概念记忆层次中，该题目仅涉及对\"纯材料发光\"这一基本概念的正误判断，无需深入理解或分析。只需记住\"发光材料通常含有杂质\"这一基础知识点即可作答，属于最基础的难度等级。" + }, + { + "idx": 4166, + "question": "Cite the difference between atomic mass and atomic weight.", + "answer": "Atomic mass is the mass of an individual atom, whereas atomic weight is the average (weighted) of the atomic masses of an atom's naturally occurring isotopes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述原子质量与原子重量的区别，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对原子质量和原子重量这两个基本概念的定义和区别的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。虽然需要区分两个相关但不同的概念（原子质量和原子量），但答案仅需简要说明两者的定义和区别，不需要深入分析或复杂的概念体系阐述。因此，在基础概念记忆的知识层次下，该题目属于中等难度。" + }, + { + "idx": 4167, + "question": "Chromium has four naturally-occurring isotopes: 4.34% of { }^{50} \\mathrm{Cr}, with an atomic weight of 49.9460 amu, 83.79% of { }^{52} \\mathrm{Cr}, with an atomic weight of 51.9405 amu, 9.50% of { }^{53} \\mathrm{Cr}, with an atomic weight of 52.9407 amu, and 2.37% of { }^{54} \\mathrm{Cr}, with an atomic weight of 53.9389 amu. On the basis of these data, confirm that the average atomic weight of \\mathrm{Cr} is 51.9963 amu.", + "answer": "the average atomic weight of \\mathrm{cr} is 51.9963 \\, amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的同位素丰度和原子质量数据，通过计算确认铬的平均原子质量。解答过程需要应用加权平均的公式进行计算，属于典型的数值计算题。 | 知识层次: 题目要求基于给定的同位素丰度和原子质量数据，通过简单的加权平均计算来确认铬的平均原子质量。这涉及基本的公式应用和直接计算，不需要多步推理或复杂分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目要求根据给定的同位素丰度和原子质量，直接套用平均原子质量的计算公式（加权平均）进行计算。解题步骤简单明确，无需多个公式组合或复杂推导，属于基本公式应用和简单计算的范畴。" + }, + { + "idx": 4168, + "question": "How many grams are there in one amu of a material?", + "answer": "1.66 x 10^-24 g/amu", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算1 amu对应的克数），答案是一个具体的数值结果（1.66 x 10^-24 g/amu），这符合计算题的特征。 | 知识层次: 题目涉及基本的单位换算和简单的数值计算，仅需直接应用已知的换算关系（1 amu = 1.66 x 10^-24 g）即可得出答案，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接应用原子质量单位(amu)与克(g)的换算公式(1 amu = 1.66 x 10^-24 g)进行单一数值转换，无需任何推导或多步骤计算。" + }, + { + "idx": 4169, + "question": "Mole, in the context of this book, is taken in units of gram-mole. On this basis, how many atoms are there in a pound-mole of a substance?", + "answer": "2.73 x 10^26 atoms/lb-mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（从克摩尔转换到磅摩尔并计算原子数量），答案以数值形式给出（2.73 x 10^26 atoms/lb-mol），需要使用阿伏伽德罗常数等公式进行计算。 | 知识层次: 题目涉及基本的单位转换和公式应用（阿伏伽德罗常数的使用），属于直接套用已知概念和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用阿伏伽德罗常数（6.022×10^23 atoms/mol）与磅摩尔（453.59237克/磅）的换算关系进行单一公式计算，无需公式组合或复杂推导。解题步骤仅为：1) 确认磅摩尔与克摩尔的换算关系；2) 直接乘以阿伏伽德罗常数。属于典型的\"单一公式直接计算\"类型。" + }, + { + "idx": 4170, + "question": "(a) Cite two important quantum-mechanical concepts associated with the Bohr model of the atom.", + "answer": "Two important quantum-mechanical concepts associated with the Bohr model of the atom are (1) that electrons are particles moving in discrete orbitals, and (2) electron energy is quantized into shells.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两个重要的量子力学概念，并简要解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对Bohr原子模型中两个重要量子力学概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求列举两个与玻尔原子模型相关的重要量子力学概念，不需要深入解释或论述概念之间的关系。回答仅需记忆性知识，属于该题型内最基础的要求。" + }, + { + "idx": 4171, + "question": "(b) Cite two important additional refinements that resulted from the wave-mechanical atomic model.", + "answer": "Two important refinements resulting from the wave-mechanical atomic model are (1) that electron position is described in terms of a probability distribution, and (2) electron energy is quantized into both shells and subshells--each electron is characterized by four quantum numbers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个重要的改进，并需要文字解释和论述，答案也是以文字形式呈现的详细解释，符合简答题的特征。 | 知识层次: 题目考查对波动力学原子模型两个重要改进的基本概念记忆，属于定义和基本原理的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释波动力学原子模型的两个重要改进，涉及对概率分布和量子化能量的描述。虽然需要记忆和理解相关概念，但不需要复杂的体系阐述或深入分析，属于概念解释和描述的难度等级。" + }, + { + "idx": 4172, + "question": "Relative to electrons and electron states, what does the n quantum number specify?", + "answer": "The n quantum number designates the electron shell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对量子数n的含义进行文字解释，答案是一个简短的文字描述而非选择或判断，符合简答题的特征。 | 知识层次: 题目考查对量子数n的基本定义和概念的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回答n量子数的基本定义（电子壳层），属于最基础的概念记忆层面，无需解释或延伸。同类题型中，这属于只需直接回忆定义即可作答的简单题目，解题步骤和知识深度要求最低。" + }, + { + "idx": 4173, + "question": "Relative to electrons and electron states, what does the l quantum number specify?", + "answer": "The l quantum number designates the electron subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释l量子数的含义，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对量子数l的基本定义和作用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需准确回忆并复述l量子数的定义（指定电子亚层），无需解释或延伸。题目仅考查基础概念的记忆能力，不涉及概念间关联或复杂体系阐述，符合等级1对知识点掌握深度和解题步骤的最低要求。" + }, + { + "idx": 4174, + "question": "Relative to electrons and electron states, what does the mj quantum number specify?", + "answer": "The mj quantum number designates the number of electron states in each electron subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对量子数mj进行文字解释和论述，答案提供了详细的描述而非选择、判断或计算。 | 知识层次: 题目考查对量子数mj的基本定义和作用的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释mj量子数的含义，这需要学生对量子数的基本概念有一定的理解，并能准确描述其作用。虽然不涉及复杂的推导或多概念整合，但需要比简单定义更深入的解释，因此属于等级2。" + }, + { + "idx": 4175, + "question": "Relative to electrons and electron states, what does the ms quantum number specify?", + "answer": "The ms quantum number designates the spin moment on each electron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对量子数ms进行文字解释和论述，答案提供了概念性的说明而非选择或判断 | 知识层次: 题目考查对量子数ms的基本定义和作用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需回忆并复述ms量子数的定义，不涉及概念解释或复杂体系阐述。题目直接询问量子数的指定含义，属于最基础的概念记忆层面。" + }, + { + "idx": 4176, + "question": "For the L shell (n=2), write the four quantum numbers for all of the electrons and note which correspond to the s and p subshells.", + "answer": "For the L state, n=2, and eight electron states are possible. Possible l values are 0 and 1, while possible ml values are 0 and ±1; and possible ms values are ±1/2. Therefore, for the s states, the quantum numbers are 200(1/2) and 200(-1/2). For the p states, the quantum numbers are 210(1/2), 210(-1/2), 211(1/2), 211(-1/2), 21(-1)(1/2), and 21(-1)(-1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出四个量子数并指出对应的s和p子壳层，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对量子数基本概念的记忆和理解，包括主量子数、角量子数、磁量子数和自旋量子数的定义及其在特定电子壳层（n=2）中的应用。虽然需要列举所有可能的量子数组合，但这是基于对基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求写出四个量子数并区分s和p亚层，但这些都是基于固定的量子数规则（n=2时的l、ml、ms取值范围）进行列举，不需要复杂的推导或体系阐述。主要考察的是对量子数基本概念的记忆和简单应用能力，属于基础概念记忆范畴内的中等难度题目。" + }, + { + "idx": 4177, + "question": "For the M shell (n=3), write the four quantum numbers for all of the electrons and note which correspond to the s, p, and d subshells.", + "answer": "For the M state, n=3, and 18 states are possible. Possible l values are 0, 1, and 2; possible ml values are 0, ±1, and ±2; and possible ms values are ±1/2. Therefore, for the s states, the quantum numbers are 300(1/2), 300(-1/2), for the p states they are 310(1/2), 310(-1/2), 311(1/2), 311(-1/2), 31(-1)(1/2), and 31(-1)(-1/2); for the d states they are 320(1/2), 320(-1/2), 321(1/2), 321(-1/2), 32(-1)(1/2), 32(-1)(-1/2), 322(1/2), 322(-1/2), 32(-2)(1/2), and 32(-2)(-1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出四个量子数并指出对应的s、p、d子壳层，需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目主要考查对量子数（n, l, ml, ms）的基本概念和电子在s、p、d亚层中分布的记忆和理解，不涉及复杂的计算或综合分析。 | 难度: 在简答题中属于复杂概念体系阐述，需要学生不仅记忆量子数的定义和分类，还要能够系统地列举所有可能的组合，并正确对应到s、p、d亚层。这涉及到对量子数之间关系的深入理解和应用，步骤较为复杂，对知识点的掌握深度要求较高。" + }, + { + "idx": 4178, + "question": "Give the electron configuration for the ion Fe2+.", + "answer": "The electron configuration for an Fe2+ ion is 1s2 2s2 2p6 3s2 3p6 3d6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Fe2+离子的电子排布，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对电子排布这一基础概念的记忆和理解，仅需直接回忆和写出Fe2+离子的电子排布即可，不涉及复杂计算或综合分析。 | 难度: 在简答题中属于中等难度，需要记忆铁原子的电子排布并理解离子化过程中电子的得失。虽然不涉及复杂的概念体系阐述，但需要准确应用电子排布规则并解释离子化后的电子构型变化。" + }, + { + "idx": 4179, + "question": "Give the electron configuration for the ion Al3+.", + "answer": "The electron configuration for an Al3+ ion is 1s2 2s2 2p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出特定离子的电子排布式，需要文字描述而非选择、判断或计算 | 知识层次: 题目考查对电子排布这一基础概念的记忆和理解，仅需根据原子序数写出Al3+离子的电子排布，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求记忆并写出Al3+离子的电子排布式，不涉及概念解释或复杂体系的阐述。解题步骤简单直接，只需应用基础的电子排布规则即可完成，属于该题型内最基础的难度等级。" + }, + { + "idx": 4180, + "question": "Give the electron configuration for the ion Cu+.", + "answer": "The electron configuration for a Cu+ ion is 1s2 2s2 2p6 3s2 3p6 3d10.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Cu+离子的电子排布，需要文字解释和论述，而不是从选项中选择或进行数值计算 | 知识层次: 题目考查对电子排布基本概念的记忆和理解，仅需根据原子序数和离子电荷直接写出电子排布式，不涉及复杂计算或综合分析。 | 难度: 在简答题中属于中等难度，需要记忆并正确书写铜离子的电子排布式，涉及对元素电子排布规律的理解和应用，但不需要复杂的推导或解释。" + }, + { + "idx": 4181, + "question": "Give the electron configuration for the ion Ba2+.", + "answer": "The electron configuration for a Ba2+ ion is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s2 5p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出Ba2+离子的电子排布，答案是一个详细的电子排布式，需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对电子排布的基本概念的记忆和理解，不需要复杂的计算或分析，只需直接回忆和写出Ba2+离子的电子排布。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求写出Ba2+离子的电子排布，不需要额外的解释或复杂的概念阐述。这属于基础概念记忆层次，只需回忆和写出特定的电子排布即可完成，解题步骤简单直接。" + }, + { + "idx": 4182, + "question": "Give the electron configuration for the ion Br-.", + "answer": "The electron configuration for a Br- ion is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出Br-离子的电子排布，答案是一个详细的电子排布序列，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对电子排布基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆并写出Br-离子的电子排布式，不涉及概念解释或复杂体系的阐述。解题步骤简单直接，只需回忆并正确书写电子排布即可，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 4183, + "question": "Give the electron configuration for the ion O2-.", + "answer": "The electron configuration for an O2- ion is 1s2 2s2 2p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出电子排布的具体描述，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对电子排布这一基础概念的记忆和理解，不需要复杂的计算或分析，只需直接回忆和应用基本的电子排布规则。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并写出氧离子(O2-)的电子排布式，不涉及复杂概念解释或体系阐述。" + }, + { + "idx": 4184, + "question": "The Na+ ion has an electron structure that is identical to which inert gas?", + "answer": "The Na+ ion has an electron configuration the same as neon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释说明Na+离子的电子结构与哪种惰性气体相同，答案需要论述和解释，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查对离子电子构型与惰性气体电子构型相同这一基本概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回忆并写出Na+离子的电子构型与哪种惰性气体相同，涉及的是基础概念的记忆性知识，无需进行概念解释或复杂体系阐述。解题步骤简单直接，仅需调用基础记忆内容即可完成作答。" + }, + { + "idx": 4185, + "question": "The Cl- ion has an electron structure that is identical to which inert gas?", + "answer": "The Cl- ion has an electron configuration the same as argon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释说明Cl-离子的电子结构与哪种惰性气体相同，答案需要论述和解释，而不是选择、判断或计算。 | 知识层次: 题目考查对离子电子构型与惰性气体电子构型相同这一基本概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求记忆并复述Cl-离子的电子构型与哪种惰性气体相同，属于最基础的定义性知识问答。不需要解释或推导过程，完全依赖对基础概念的机械记忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4186, + "question": "With regard to electron configuration, what do all the elements in Group VIIA of the periodic table have in common?", + "answer": "Each of the elements in Group VIIA has five p electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释元素在周期表中的共同特征，答案需要文字描述而非选择、判断或计算 | 知识层次: 题目考查对元素周期表中VIIA族元素电子排布的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并复述元素周期表VIIA族元素的电子排布共性（五个p电子），无需解释或深入分析概念。" + }, + { + "idx": 4187, + "question": "To what group in the periodic table would an element with atomic number 114 belong?", + "answer": "From the periodic table the element having atomic number 114 would belong to group IVA. Ds, having an atomic number of 110 lies below Pt in the periodic table and in the rightmost column of group VIII. Moving four columns to the right puts element 114 under \\mathrm{Pb} and in group IVA.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素114在周期表中的归属，并提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目主要考查对元素周期表中元素分组的基本概念的记忆和理解，需要根据原子数确定元素在周期表中的位置和所属族。虽然涉及一定的推理（从已知元素位置推断目标元素位置），但整体上属于基础概念的记忆和应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求根据原子序数确定元素在周期表中的族属位置，需要理解周期表的基本结构和元素分类原理，并能够进行简单的逻辑推理（从已知元素位置推导目标元素位置）。虽然涉及多个步骤的思考，但不需要复杂的体系阐述或深入的概念分析，符合等级2对概念解释和描述的要求。" + }, + { + "idx": 4188, + "question": "Determine whether the electron configuration (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{7} 4 s^{2}) is an inert gas, a halogen, an alkali metal, an alkaline earth metal, or a transition metal. Justify your choice.", + "answer": "The (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{7} 4 s^{2}) electron configuration is that of a transition metal because of an incomplete (d) subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据电子排布判断元素类别，并需要文字解释和论述来证明选择。答案提供了详细的理由说明，符合简答题的特征。 | 知识层次: 题目考查对电子构型与元素分类之间关系的基本概念记忆和理解，只需根据给定的电子构型判断元素类别，并简要说明理由，不涉及复杂的分析或计算。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求判断电子构型对应的元素类别，但只需基于电子排布的基本原理和过渡金属的定义进行简单解释即可。不需要复杂的推理或多步骤分析，属于概念解释和描述的范畴。" + }, + { + "idx": 4194, + "question": "What electron subshell is being filled for the rare earth series of elements on the periodic table?", + "answer": "The 4 f subshell is being filled for the rare earth series of elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述特定电子亚层（4f）在稀土元素周期表中的填充情况，答案需要文字说明而非选择、判断或计算。 | 知识层次: 题目考查对元素周期表中稀土元素电子填充亚层的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答稀土元素填充的电子亚层，即4f亚层，属于对基础概念的直接记忆和简单应用，不需要进行概念解释或复杂体系阐述。" + }, + { + "idx": 4195, + "question": "What electron subshell is being filled for the actinide series?", + "answer": "The 5 f subshell is being filled for the actinide series of elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个简短的文字描述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对元素周期表中锕系元素电子填充的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答actinide系列元素填充的电子亚层，属于基础概念记忆的范畴。题目直接考察对actinide系列电子排布的基本定义，无需额外的解释或复杂概念阐述，解题步骤简单明了，符合等级1的基本定义简答标准。" + }, + { + "idx": 4196, + "question": "Calculate the force of attraction between a K^{+}and an \\mathrm{O}^{2-} ion the centers of which are separated by a distance of 1.5nm.", + "answer": "the force of attraction between the k^{+} and \\mathrm{o}^{2-} ions is 2.05 × 10^{-10} N.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算两个离子之间的吸引力，需要使用库仑定律等公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目要求应用库仑定律进行简单的离子间吸引力计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用库仑定律公式F = k*q1*q2/r^2进行简单数值代入和计算，无需多步骤推导或公式组合。" + }, + { + "idx": 4197, + "question": "Briefly cite the main differences between ionic, covalent, and metallic bonding.", + "answer": "The main differences between the various forms of primary bonding are: Ionic--there is electrostatic attraction between oppositely charged ions. Covalent--there is electron sharing between two adjacent atoms such that each atom assumes a stable electron configuration. Metallic--the positively charged ion cores are shielded from one another, and also 'glued' together by the sea of valence electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要列举离子键、共价键和金属键之间的主要区别，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目考查对离子键、共价键和金属键这三种基本化学键类型的基本概念和区别的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要列举离子键、共价键和金属键的主要区别，这需要学生对这三种基本化学键的定义和特点有清晰的理解和记忆。虽然涉及多个概念，但每个概念的解释相对独立且基础，不需要复杂的推理或综合应用。因此，在简答题题型中属于中等难度（等级2）。" + }, + { + "idx": 4198, + "question": "State the Pauli exclusion principle.", + "answer": "The Pauli exclusion principle states that each electron state can hold no more than two electrons, which must have opposite spins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述Pauli exclusion principle的内容，答案是一个完整的句子解释该原理，符合简答题的特征。 | 知识层次: 题目考查对Pauli exclusion principle这一基本概念的记忆和理解，属于定义性知识的直接回忆。 | 难度: 在简答题题型中，该题目仅要求复述泡利不相容原理的基本定义，属于最基础的概念记忆层次。不需要解释、描述或阐述复杂概念体系，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于对知识点掌握深度要求最低、解题步骤最简单的一类问题。" + }, + { + "idx": 4199, + "question": "What type(s) of bonding would be expected for brass (a copper-zinc alloy)?", + "answer": "For brass, the bonding is metallic since it is a metal alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述brass的键合类型，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对金属合金键合类型的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答基本的金属键类型，属于基础概念的直接回忆和应用。题目不涉及复杂的概念解释或体系阐述，仅需简单说明合金的键合性质即可。因此在该题型和知识层次下属于最基本的难度等级。" + }, + { + "idx": 4200, + "question": "What type(s) of bonding would be expected for rubber?", + "answer": "For rubber, the bonding is covalent with some van der Waals. (Rubber is composed primarily of carbon and hydrogen atoms.)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释橡胶的键合类型，答案需要文字描述和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对橡胶中化学键类型的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在简答题题型中，该题目要求解释橡胶的键合类型，涉及基本概念（共价键和范德华力）的解释和描述，但不需要复杂的体系阐述或深入分析。属于概念解释和描述的难度级别。" + }, + { + "idx": 4201, + "question": "What type(s) of bonding would be expected for barium sulfide (BaS)?", + "answer": "For BaS, the bonding is predominantly ionic (but with some covalent character) on the basis of the relative positions of Ba and S in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释BaS的键合类型，需要文字论述和解释，而不是从选项中选择或简单判断对错 | 知识层次: 题目要求分析BaS的键合类型，需要理解元素周期表中Ba和S的位置关系，并综合判断其键合性质（主要是离子键但带有部分共价性）。这涉及多个概念的关联和综合分析，而不仅仅是基础概念的记忆。 | 难度: 在简答题题型中，该题目属于中等应用层次，要求考生不仅识别BaS的主要键合类型（离子键），还需要解释其部分共价特性。这需要考生理解元素周期表中元素位置与键合性质的关系，并进行综合分析。虽然涉及多步思考，但不需要进行深度关联性分析或多角度论述，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 4202, + "question": "What type(s) of bonding would be expected for solid xenon?", + "answer": "For solid xenon, the bonding is van der Waals since xenon is an inert gas.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释固体氙的键合类型，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对惰性气体固态时键合类型的基础概念记忆，仅需知道氙是惰性气体且固态时通过范德华力结合即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求回答固态氙的键合类型（范德华力），并给出简单解释（氙是惰性气体）。这属于最基础的概念记忆性知识，不需要复杂的解释或论述步骤，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4203, + "question": "What type(s) of bonding would be expected for bronze?", + "answer": "For bronze, the bonding is metallic since it is a metal alloy (composed of copper and tin).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释青铜中预期的键合类型，答案提供了详细的文字解释和论述，而不是从多个选项中选择或简单的对错判断，也不需要数值计算。 | 知识层次: 题目考查对金属合金（青铜）键合类型的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求回答青铜的键合类型，并简要说明原因（由铜和锡组成的金属合金）。这属于最基础的概念记忆和简单解释，无需深入分析或复杂论述，符合等级1的标准。" + }, + { + "idx": 4204, + "question": "What type(s) of bonding would be expected for nylon?", + "answer": "For nylon, the bonding is covalent with perhaps some van der Waals. (Nylon is composed primarily of carbon and hydrogen.)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释尼龙的键合类型，需要文字描述和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目考查对尼龙材料中化学键类型的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在简答题题型中，该题目要求解释尼龙的键合类型，涉及基础概念记忆中的分类和基本原理。虽然需要解释共价键和范德华力的存在，但不需要深入阐述复杂的概念体系或进行多步骤推理。因此，在简答题的基础概念记忆层次中属于中等难度（等级2）。" + }, + { + "idx": 4205, + "question": "What type(s) of bonding would be expected for aluminum phosphide (AlP)?", + "answer": "For AlP the bonding is predominantly covalent (but with some ionic character) on the basis of the relative positions of Al and P in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释铝磷化合物(AlP)的键合类型，需要文字解释和论述，而不是从选项中选择或简单判断对错。答案提供了详细的解释说明，符合简答题的特征。 | 知识层次: 题目要求根据元素在周期表中的位置分析化学键类型，涉及对元素电负性和键合性质的理解与应用，需要综合分析能力，但不需要复杂的推理或创新思维。 | 难度: 在简答题题型中，该题目要求对铝磷化合物的键合类型进行多角度分析论述。学生不仅需要理解共价键和离子键的基本概念，还需要根据元素在周期表中的位置（Al和P的电负性差异）分析键合性质，并进一步说明\"以共价为主但带有部分离子性\"的混合特征。这涉及到对化学键理论的综合应用和相对复杂的逻辑推导，属于需要多步骤分析和概念关联的中高难度简答题。" + }, + { + "idx": 4206, + "question": "What is the difference between atomic structure and crystal structure?", + "answer": "Atomic structure relates to the number of protons and neutrons in the nucleus of an atom, as well as the number and probability distributions of the constituent electrons. On the other hand, crystal structure pertains to the arrangement of atoms in the crystalline solid material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释原子结构和晶体结构之间的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对原子结构和晶体结构这两个基本概念的定义和区分，属于基础概念的记忆和理解层面，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分原子结构和晶体结构这两个基础概念，需要考生对两者的定义和基本特征有清晰的理解，并能用文字进行简要说明。虽然涉及两个概念的对比，但不需要深入分析或复杂推导，属于该题型中中等偏下的难度水平。" + }, + { + "idx": 4207, + "question": "If the atomic radius of aluminum is 0.143nm, calculate the volume of its unit cell in cubic meters.", + "answer": "the volume of the unit cell is 6.62 × 10^{-29} m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（计算铝的单位晶胞体积），答案是一个具体的数值结果（6.62 × 10^{-29} m^{3}），符合计算题的特征。 | 知识层次: 题目要求计算铝的单位晶胞体积，仅需应用基本的立方晶胞体积公式（V = a^3，其中a为晶格常数）和简单的单位转换。计算过程直接，无需多步推理或综合分析，属于基本公式的直接应用。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用立方晶胞体积公式V = a^3（其中a为晶格常数），而题目已给出原子半径，通过简单关系a = 4r/√2即可求得a值。整个过程仅涉及一个主要公式和基本代数运算，无需多步推导或复杂计算。" + }, + { + "idx": 4208, + "question": "Show that the atomic packing factor for BCC is 0.68 .", + "answer": "the atomic packing factor for bcc is 0.68.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算BCC结构的原子堆积因子，并给出具体数值结果0.68。解答过程需要应用几何关系和数学计算，属于典型的计算题类型。 | 知识层次: 题目要求计算BCC结构的原子堆积因子，涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用BCC结构的原子堆积因子公式（APF = (2 × (4/3)πr³) / a³）并进行简单数值计算。无需推导或组合多个公式，解题步骤单一且直接。" + }, + { + "idx": 4209, + "question": "Iron has a BCC crystal structure, an atomic radius of 0.124nm, and an atomic weight of 55.85g / mol. Compute and compare its theoretical density with the experimental value found inside the front cover.", + "answer": "the theoretical density of iron is 7.90g / {cm}^{3}. the experimental value given inside the front cover is 7.87g / {cm}^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铁的理論密度，并与实验值进行比较。答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目要求应用BCC晶体结构的基本公式进行密度计算，属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用BCC晶体结构的理论密度公式，并进行单位换算和简单计算，但不需要多个公式组合或复杂推导。" + }, + { + "idx": 4210, + "question": "Calculate the radius of an iridium atom, given that Ir has an FCC crystal structure, a density of 22.4g / {cm}^{3}, and an atomic weight of 192.2g / mol.", + "answer": "the radius of an iridium atom is 0.136nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（FCC晶体结构、密度、原子重量等）来求解铱原子的半径，答案是一个具体的数值结果（0.136nm），符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括FCC晶体结构的几何关系、密度与原子半径的转换、阿伏伽德罗常数的应用等综合分析。虽然不涉及复杂的推理或创新设计，但需要较深的理解和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用FCC晶体结构的相关公式，结合密度和原子重量进行多步计算，涉及单位转换和概念关联，但步骤相对明确，没有过于复杂的变量处理。" + }, + { + "idx": 4211, + "question": "Calculate the radius of a vanadium atom, given thatV has a BCC crystal structure, a density of 5.96 \\mathrm{g} / {cm}^{3}, and an atomic weight of 50.9g / mol.", + "answer": "the radius of a vanadium atom is 0.132 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如BCC晶体结构的密度公式）来求解钒原子的半径，答案是一个具体的数值结果（0.132 nm），符合计算题的特征。 | 知识层次: 题目需要应用BCC晶体结构的基本知识，结合密度和原子质量进行多步计算，涉及公式转换和单位换算，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用BCC晶体结构的相关知识、密度公式、原子量转换等多步骤计算，并涉及单位换算和综合分析。虽然步骤较多，但每一步的计算相对明确，属于中等偏上的难度。" + }, + { + "idx": 4212, + "question": "For alloy A with atomic weight 77.4 g/mol, density 8.22 g/cm³, and atomic radius 0.125 mm, determine whether its crystal structure is FCC, BCC, or simple cubic and then justify your determination.", + "answer": "for alloy a, its crystal structure is simple cubic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算和理论分析确定晶体结构类型，并给出合理的解释，需要文字论述和论证过程，而不仅仅是简单的选择或判断。 | 知识层次: 题目需要根据给定的原子重量、密度和原子半径，通过多步计算和综合分析来确定晶体结构类型。这涉及到对FCC、BCC和简单立方晶体结构的理解，以及相关公式的应用和计算过程，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合运用原子重量、密度和原子半径等概念进行计算和比较，以确定晶体结构类型。虽然涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4213, + "question": "For alloy B with atomic weight 107.6 g/mol, density 13.42 g/cm³, and atomic radius 0.133 mm, determine whether its crystal structure is FCC, BCC, or simple cubic and then justify your determination.", + "answer": "for alloy b, its crystal structure is fcc.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过计算合金的原子半径、密度和原子量来确定其晶体结构类型（FCC、BCC或简单立方），并给出合理的解释。解答过程涉及数值计算和公式应用，如计算原子堆积因子等。 | 知识层次: 题目需要应用晶体结构相关的公式进行多步计算（如原子堆积因子计算），并需要将计算结果与不同晶体结构（FCC、BCC、简单立方）的理论值进行对比分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶体结构几何关系等多步骤计算，并综合分析原子半径、密度和原子量之间的关系来确定晶体结构。虽然计算过程较为直接，但涉及多个概念的综合应用，属于中等偏上的难度。" + }, + { + "idx": 4214, + "question": "For alloy C with atomic weight 127.3 g/mol, density 9.23 g/cm³, and atomic radius 0.142 mm, determine whether its crystal structure is FCC, BCC, or simple cubic and then justify your determination.", + "answer": "for alloy c, its crystal structure is simple cubic.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过计算密度、原子半径等参数来确定晶体结构类型，涉及数值计算和公式应用。虽然最终需要判断晶体结构类型，但核心解答过程是基于计算推导的。 | 知识层次: 题目需要应用密度、原子半径和晶体结构之间的关系公式进行计算，涉及多步推导和综合分析，以确定晶体结构类型。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要应用密度公式、晶体结构几何关系等多步骤计算，并综合分析原子半径、密度和原子量等变量来确定晶体结构类型。虽然计算过程较为直接，但涉及多个概念的综合应用和判断，属于中等偏上的难度。" + }, + { + "idx": 4215, + "question": "The unit cell for tin has tetragonal symmetry, with a and b lattice parameters of 0.583 and 0.318nm, respectively. If its density, atomic weight, and atomic radius are 7.30g / {cm}^{3}, 118.69g / mol, and 0.151nm, respectively, compute the atomic packing factor.", + "answer": "the atomic packing factor (apf) for tin is 0.534.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如密度、原子量、原子半径等）来求解原子堆积因子（APF），答案是一个具体的数值结果（0.534），符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括晶胞参数、密度、原子量、原子半径的综合运用，以及原子堆积因子的计算公式应用，涉及中等难度的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要掌握晶格参数、密度、原子量、原子半径等多个概念，并进行多步计算和综合分析。虽然计算步骤较多，但每一步的计算相对直接，没有涉及过于复杂的变量或公式变换。" + }, + { + "idx": 4216, + "question": "List the point coordinates of the titanium, barium, and oxygen ions for a unit cell of the perovskite crystal structure.", + "answer": " the barium ions are situated at all corner positions. The point coordinates for these ions are as follows: 000,100,110,010,001,101,111, and 011 .\nThe oxygen ions are located at all face-centered positions; therefore, their coordinates are \\frac{1}{2} \\frac{1}{2} 0, \\frac{1}{2} \\frac{1}{2} 1, \\frac{1}{2} \\frac{1}{2}, \\frac{0}{2} \\frac{1}{2}, \\frac{1}{2} 0 \\frac{1}{2}, and \\frac{1}{2} 1 \\frac{1}{2}.\nAnd, finally, the titanium ion resides at the center of the cubic unit cell, with coordinates \\frac{1}{2} \\frac{1}{2} \\frac{1}{2}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出钛、钡和氧离子在钙钛矿晶体结构单胞中的点坐标，答案提供了详细的坐标描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对钙钛矿晶体结构中各离子位置坐标的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求列出钙钛矿晶体结构中钛、钡和氧离子的点坐标，并解释其位置。这需要学生对晶体结构的基本概念有一定的记忆和理解，包括单位晶胞中不同离子的位置及其坐标表示。虽然需要记忆多个坐标点，但题目并未涉及复杂的推导或深入的概念阐述，属于概念解释和描述的难度等级。" + }, + { + "idx": 4217, + "question": "List the point coordinates of all carbon atoms that occupy the corner positions of the diamond cubic unit cell.", + "answer": "The coordinates of these atoms are as follows: 000, 100, 110, 010, 001, 101, 111, and 011.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出金刚石立方晶胞中所有位于角位置的碳原子的点坐标，答案以列表形式给出具体的坐标值，属于需要具体回答的简答题类型。 | 知识层次: 题目考查对金刚石立方晶胞角位碳原子坐标的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需要记忆并列出金刚石立方晶胞角位碳原子的坐标，不涉及概念解释或复杂体系阐述。" + }, + { + "idx": 4218, + "question": "List the point coordinates of all carbon atoms that reside on the face-centered positions of the diamond cubic unit cell.", + "answer": "The coordinates of these atoms are as follows: 1/2 1/2 0, 1/2 1/2 1, 1/2 0 1/2, 0 1/2 1/2, and 1/2 1/2 1/2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出金刚石立方晶胞中面心位置的碳原子坐标，答案以文字形式给出具体坐标，不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查对金刚石立方晶胞中面心位置碳原子坐标的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求列出金刚石立方晶胞中面心位置的碳原子坐标。虽然需要记忆具体的坐标位置，但不需要深入的解释或复杂的推导过程。相对于等级1的基本定义简答，该题目需要更多的记忆和空间想象能力，但不需要等级3的复杂概念体系阐述。因此，在该题型内属于中等难度。" + }, + { + "idx": 4219, + "question": "List the point coordinates of all carbon atoms that are positioned within the interior of the diamond cubic unit cell.", + "answer": "The coordinates of these atoms are as follows: 3/4 1/4 1/4, 1/4 3/4 3/4, 1/4 1/4 3/4, and 3/4 3/4 1/4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出金刚石立方晶胞内部所有碳原子的点坐标，答案以文字形式给出具体坐标，属于需要具体回答的简答题类型。 | 知识层次: 题目考查对金刚石立方晶胞内部碳原子位置坐标的记忆和理解，属于晶体结构的基础概念范畴，不需要复杂的计算或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列出金刚石立方晶胞内部碳原子的坐标位置，属于对晶体结构基本概念的记忆性知识，不需要进行复杂的解释或论述。解题步骤简单直接，只需回忆并写出特定坐标即可，符合等级1的基本定义简答标准。" + }, + { + "idx": 4220, + "question": "Using the Molecule Definition Utility found in both \"Metallic Crystal Structures and Crystallography\" and \"Ceramic Crystal Structures\" modules of VMSE, located on the book's web site [www.wiley.com/college/Callister (Student Companion Site)], generate a three-dimensional unit cell for the intermetallic compound \\mathrm{AuCu}_{3} given the following: (1) the unit cell is cubic with an edge length of 0.374nm, (2) gold atoms are situated at all cube corners, and (3) copper atoms are positioned at the centers of all unit cell faces.", + "answer": "First of all, open the \"Molecular Definition Utility\"; it may be found in either of \"Metallic Crystal Structures and Crystallography\" or \"Ceramic Crystal Structures\" modules.\nIn the \"Step 1\" window, it is necessary to define the atom types, colors for the spheres (atoms), and specify atom sizes. Let us enter \"Au\" as the name for the gold atoms (since \"Au\" the symbol for gold), and \"Cu\" as the name for the copper atoms. Next it is necessary to choose a color for each atom type from the selections that appear in the pull-down menu-for example, \"Yellow\" for Au and \"Red\" for Cu. In the \"Atom Size\" window, it is necessary to enter an atom/ion size. In the instructions for this step, it is suggested that the atom/ion diameter in nanometers be used. From the table found inside the front cover of the textbook, the atomic radii for gold and copper are 0.144nm and 0.128nm, respectively, and, therefore, their ionic diameters are twice these values (i.e., 0.288nm and 0.256nm ); therefore, we enter the values \" 0.288 \" and \" 0.256 \" for the two atom types. Now click on the \"Register\" button, followed by clicking on the \"Go to Step 2\" button.\nIn the \"Step 2\" window we specify positions for all of the atoms within the unit cell; their point coordinates are specified in the problem statement. Let's begin with gold. Click on the yellow sphere that is located to the right of the \"Molecule Definition Utility\" box. Again, Au atoms are situated at all eight corners of the cubic unit cell. One Au will be positioned at the origin of the coordinate system-i.e., its point coordinates are 000, and, therefore, we enter a \"0\" (zero) in each of the \" \\mathrm{x} \", \" \\mathrm{y} \", and \" \\mathrm{z} \" atom position boxes. Next we click on the \"Register Atom Position\" button. Now we enter the coordinates of another gold atom; let us arbitrarily select the one that resides at the corner of the unit cell that is one unit-cell length along the x-axis (i.e., at the 100 point coordinate). Inasmuch as it is located a distance of a units along the x-axis the value of \" 0.374 \" is entered in the \" \\mathrm{x} \" atom position box (since this is the value of a given in the problem statement); zeros are entered in each of the \" \\mathrm{y} \" and \" z \" position boxes. We repeat this procedure for the remaining six Au atoms.\nAfter this step has been completed, it is necessary to specify positions for the copper atoms, which are located at all six face-centered sites. To begin, we click on the red sphere that is located next to the \"Molecule Definition Utility\" box. The point coordinates for some of the Cu atoms are fractional ones; in these instances, the a unit cell length (i.e., 0.374) is multiplied by the fraction. For example, one Cu atom is located 1 \\frac{1}{2} \\frac{1}{2} coordinate. Therefore, the \\mathrm{x}, \\mathrm{y}, and \\mathrm{z} atoms positions are (1)(0.374) =0.374, \\frac{1}{2}(0.374)=0.187, and \\frac{1}{2}(0.374)=0.187, respectively.\nFor the gold atoms, the \\mathrm{x}, \\mathrm{y}, and \\mathrm{z}^{\\prime} atom position entries for all 8 sets of point coordinates are as follows: \\[\n\\begin{array}{l}\n0,0, \\text { and } 0 \\\\\n0.374,0, \\text { and } 0 \\\\\n0,0.374, \\text { and } 0 \\\\\n0,0, \\text { and } 0.374 \\\\\n0,0.374,0.374 \\\\\n0.374,0.374 \\\\\n0.374,0 .374,0 \\\\\n0.374,0.374,0.374\n\\end{array}\n\\]\nNow, for the copper atoms, the \\mathrm{x}, \\mathrm{y}, and \\mathrm{z} atom position entries for all 6 sets of point coordinates are as follows:\n\\[\n\\begin{array}{l}\n0.187,0.187,0 \\\\\n0.187,0,0.187 \\\\\n0,0.187,0.187 \\\\\n0.374,0.187,0.187 \\\\\n0.187,0.374,0.187 \\\\\n0.187,0.187,0.374\n\\end{array}\n\\]\nIn Step 3, we may specify which atoms are to be represented as being bonded to one another, and which type of bond(s) to use (single solid, single dashed, double, and triple are possibilities), or we may elect to not represent any bonds at all (in which case we are finished). If it is decided to show bonds, probably the best thing to do is to represent unit cell edges as bonds. This image may be rotated by using mouse click-and-drag\nYour image should appear as the following screen shot. Here the gold atoms appear lighter than the copper atoms. [Note: Unfortunately, with this version of the Molecular Definition Utility, it is not possible to save either the data or the image that you have generated. You may use screen capture (or screen shot) software to record and store your image.]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用特定的软件工具生成三维晶胞结构，并详细描述操作步骤和参数设置。答案提供了详细的文字说明和操作流程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求学生使用分子定义工具生成三维晶胞，涉及多个步骤的操作和原子位置的精确计算。虽然题目提供了具体的参数和位置信息，但需要学生理解晶胞结构、原子坐标的计算方法，并能正确应用这些知识进行操作。这属于中等应用层次，因为它需要多步计算和概念关联，但不需要复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求使用特定的软件工具（Molecule Definition Utility）进行操作，这增加了技术性难度。其次，解题步骤较为复杂，包括定义原子类型、颜色、大小，以及精确输入多个原子的坐标位置。此外，题目还涉及对晶体结构的理解和计算，需要将理论知识与实际操作相结合。最后，题目还要求对生成的图像进行解释和说明，这需要综合分析和论述能力。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 4221, + "question": "Convert the (010) plane into the four-index Miller-Bravais scheme for hexagonal unit cells.", + "answer": "the (010) plane in the four-index miller-bravais scheme is (01 -1 0).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求将(010)平面转换为六方晶系的四指数Miller-Bravais方案，这需要进行坐标系的转换计算，答案是一个具体的计算结果。 | 知识层次: 题目要求将(010)平面转换为六方晶系的四指数Miller-Bravais方案，这需要应用基本的转换公式和简单的计算步骤，属于基本公式的直接应用，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。虽然需要将三指数Miller指数转换为四指数Miller-Bravais指数，但转换过程只需要应用一个简单的转换公式（h k i l）其中i=-(h+k）。解题步骤较为直接，不需要多个公式组合或复杂计算。" + }, + { + "idx": 4222, + "question": "Convert the (101) plane into the four-index Miller-Bravais scheme for hexagonal unit cells.", + "answer": "the (101) plane in the four-index miller-bravais scheme is (10 -1 1).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求将(101)平面转换为六方晶系的四指数Miller-Bravais方案，这需要进行坐标系的转换计算，涉及数值计算和公式应用。答案给出了具体的计算结果(10 -1 1)，表明这是一个需要计算步骤的题目。 | 知识层次: 题目要求将立方晶系的(101)平面转换为六方晶系的四指数Miller-Bravais表示法，这需要应用基本的晶体学知识和转换公式，属于基本公式的直接应用和简单计算。虽然涉及不同晶系之间的转换，但过程较为直接，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。虽然需要将三指数Miller指数转换为四指数Miller-Bravais指数，但转换过程仅涉及一个基本公式的应用（h=H-K, k=K-H, i=-(h+k), l=L），且计算步骤简单直接。不需要多个公式组合或复杂推导，属于该题型框架内的中等偏下难度。" + }, + { + "idx": 4223, + "question": "(a) Derive the planar density expression for the HCP (0001) plane in terms of the atomic radius R.", + "answer": "the planar density expression for the hcp (0001) plane in terms of the atomic radius r is: pd_{0001} = 1 / (2 r^{2} sqrt(3))", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导HCP (0001)面的平面密度表达式，涉及原子半径R的计算和公式应用，答案是一个具体的数学表达式，符合计算题的特征。 | 知识层次: 题目需要推导HCP (0001)晶面的面密度表达式，涉及晶体结构几何关系的理解和多步计算，需要将原子半径与晶面参数关联起来，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解HCP晶体结构、(0001)面的原子排列方式，并应用几何关系推导平面密度表达式。解题步骤涉及多步计算和概念关联，但不需要处理复杂多变量。" + }, + { + "idx": 4224, + "question": "(b) Compute the planar density value for this same plane for magnesium.", + "answer": "the planar density value for the (0001) plane for magnesium is: pd_{0001}(mg) = 1.128 × 10^{19} m^{-2}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算镁的(0001)面的平面密度值，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目要求计算镁的(0001)面的平面密度值，这需要应用基本的平面密度计算公式，并进行简单的数值计算。虽然需要理解平面密度的概念，但整体上属于直接套用公式和进行基本计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算镁的(0001)晶面的平面密度值，涉及的知识点是基本公式应用和简单计算，解题步骤仅需直接套用平面密度公式进行计算，无需多个公式组合或复杂推导。" + }, + { + "idx": 4225, + "question": "Explain why the properties of polycrystalline materials are most often isotropic.", + "answer": "Although each individual grain in a polycrystalline material may be anisotropic, if the grains have random orientations, then the solid aggregate of the many anisotropic grains will behave isotropically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释多晶材料性质通常为各向同性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解多晶材料的各向异性晶粒随机排列导致宏观各向同性的原理，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求解释多晶材料各向同性的原因，但只需理解晶粒随机取向导致宏观各向同性的基本概念即可回答，不需要进行多角度分析或深度关联性分析。解题步骤相对简单，主要涉及对晶体学基本概念的应用和简单论述。" + }, + { + "idx": 4226, + "question": "The metal iridium has an FCC crystal structure. If the angle of diffraction for the (220) set of planes occurs at 69.22 degrees (first-order reflection) when monochromatic x-radiation having a wavelength of 0.1542 nm is used, compute the interplanar spacing for this set of planes.", + "answer": "the interplanar spacing for the (220) set of planes for iridium is 0.1357 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（布拉格定律）来求解晶面间距，答案是一个具体的数值结果（0.1357 nm），符合计算题的特征。 | 知识层次: 题目需要应用布拉格定律（nλ=2d sinθ）进行一步计算，属于基本公式的直接套用和简单计算，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用布拉格定律（nλ = 2d sinθ）这一基本公式，进行简单的数值代入和计算即可得到结果。不需要多个公式组合或复杂的推导过程，属于最基础的计算题类型。" + }, + { + "idx": 4227, + "question": "The metal iridium has an FCC crystal structure. Given the interplanar spacing for the (220) set of planes is 0.1357 nm, compute the atomic radius for an iridium atom.", + "answer": "the atomic radius for an iridium atom is 0.1357 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶面间距计算铱原子的原子半径，涉及数值计算和公式应用（如晶格常数与原子半径的关系）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用FCC晶体结构的相关知识，通过给定的晶面间距计算原子半径。这涉及多步计算和概念关联，包括理解晶面间距与晶格常数的关系，以及FCC结构中原子半径与晶格常数的关系。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要理解FCC晶体结构、晶面间距与晶格常数的关系，并应用布拉格方程进行多步计算。虽然不涉及复杂多变量，但需要将多个概念关联并正确应用公式，属于中等偏上的难度。" + }, + { + "idx": 4228, + "question": "Which of these elements would you expect to form with copper a substitutional solid solution having complete solubility? Below, atomic radius, crystal structure, electronegativity, and the most common valence are tabulated, for several elements; for those that are nonmetals, only atomic radii are indicated.", + "answer": "Ni, Pd, and Pt meet all of the criteria and thus form substitutional solid solutions having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素中选择能够与铜形成完全固溶体的元素，答案明确指出了符合条件的元素（Ni, Pd, Pt）以及特定条件下的其他元素（Co, Fe），这符合选择题的特征，即从多个选项中选择正确答案。 | 知识层次: 题目要求考生综合运用原子半径、晶体结构、电负性和价态等多个因素来判断哪些元素能与铜形成完全固溶体，涉及多步分析和概念关联。虽然不涉及复杂计算，但需要对材料科学中的固溶体形成条件有较深入的理解和应用能力。 | 难度: 在选择题中属于较高难度，需要综合考虑原子半径、晶体结构、电负性和价态等多个因素，并进行复杂分析判断。题目要求考生不仅掌握Hume-Rothery规则的所有要素，还要能识别高温下的同素异形转变现象，这涉及多步骤推理和综合应用能力。" + }, + { + "idx": 4230, + "question": "Which of these elements would you expect to form with copper an interstitial solid solution? Below, atomic radius, crystal structure, electronegativity, and the most common valence are tabulated, for several elements; for those that are nonmetals, only atomic radii are indicated.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个元素中选择能够与铜形成间隙固溶体的元素，答案给出了具体的选择（C, H, and O），符合选择题的特征。 | 知识层次: 题目考查对间隙固溶体形成条件的记忆和理解，涉及原子半径比较这一基本概念，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解原子半径对形成间隙固溶体的影响，并进行简单比较分析。虽然涉及多个概念，但解题步骤较为直接，只需识别出原子半径显著小于铜的元素即可。" + }, + { + "idx": 4231, + "question": "What is the composition, in atom percent, of an alloy that consists of 30 wt% Zn and 70 wt% Cu ?", + "answer": "the composition of the alloy is 29.4 \\, \\text{at}% \\, \\mathrm{zn} and 70.6 \\, \\text{at}% \\, \\mathrm{cu}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如原子百分比的计算）来得出合金的组成，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的重量百分比到原子百分比的转换计算，需要应用简单的公式和基本的材料科学知识，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求将重量百分比转换为原子百分比，这需要应用基本的原子量计算公式，涉及两个步骤：1) 计算各元素的摩尔数；2) 转换为原子百分比。虽然需要应用公式并进行简单计算，但整个过程是直接的，不需要多个公式组合或复杂转换。" + }, + { + "idx": 4232, + "question": "What is the composition, in weight percent, of an alloy that consists of 6 at% \\mathrm{Pb} and 94 \\mathrm{at}% \\mathrm{Sn} ?", + "answer": "the composition of the alloy is: 1. 10.0 \\, \\text{wt% pb} 2. 90.0 \\, \\text{wt% sn}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出合金的重量百分比组成，需要应用原子百分比和重量百分比之间的转换公式，属于数值计算和公式应用的类型。答案给出了具体的计算结果，而不是选择或判断。 | 知识层次: 题目需要进行基本的原子百分比到重量百分比的转换计算，涉及简单的公式应用和直接套用，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算，需要将原子百分比转换为重量百分比，涉及原子质量和简单公式应用，但不需要多个公式组合或复杂计算步骤。" + }, + { + "idx": 4233, + "question": "What is the composition, in atom percent, of an alloy that contains 99.7 lb_{m} copper, 102 lb_{m} zinc, and 2.1 lb_{m} lead?\n", + "answer": "the composition of the alloy in atom percent is: \\[\nc_{\\mathrm{cu}} = 50.0 \\, \\text{at}%\n\\] \\[\nc_{\\mathrm{zn}} = 49.7 \\, \\text{at}%\n\\] \\[\nc_{\\mathrm{pb}} = 0.3 \\, \\text{at}%\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金的原子百分比组成，答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及原子百分比的转换，但计算过程相对直接，不涉及多步计算或复杂的概念关联。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算合金的原子百分比组成，需要应用质量转换为摩尔数的基本公式，并进行简单的百分比计算。虽然涉及三种元素，但计算步骤明确且直接，不需要复杂的公式组合或高级概念理解。" + }, + { + "idx": 4234, + "question": "What is the composition, in atom percent, of an alloy that consists of 97 wt% Fe and 3 wt% Si?", + "answer": "the composition of the alloy is 94.2 at% fe and 5.8 at% si.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行原子百分比的计算，需要应用材料科学中的成分转换公式，涉及数值计算过程。答案以具体数值形式呈现，符合计算题的特征。 | 知识层次: 题目涉及基本的重量百分比到原子百分比的转换计算，需要应用简单的公式和进行直接的计算，不涉及多步推理或复杂分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要掌握原子百分比和重量百分比之间的转换公式，并进行简单的代数运算。虽然涉及多个步骤，但每个步骤都是直接套用基本公式，不需要复杂的推导或组合多个公式。" + }, + { + "idx": 4235, + "question": "Calculate the number of atoms per cubic meter in aluminum.", + "answer": "6.05 × 10^{28} atoms/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铝中每立方米的原子数），并且答案是一个具体的数值（6.05 × 10^{28} atoms/m^3），这表明解答过程需要应用公式和计算步骤。 | 知识层次: 题目要求计算铝中每立方米的原子数，这需要应用基本的密度和摩尔质量公式进行计算。虽然涉及单位转换和基本概念的应用，但计算过程直接且无需多步推理或综合分析。 | 难度: 在计算题中属于最基础难度，仅需直接套用密度与摩尔质量关系公式（n = ρN_A/M），进行单一数值计算，无需公式组合或复杂推导。解题步骤仅涉及基本单位换算和代数运算，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 4236, + "question": "The concentration of carbon in an iron-carbon alloy is 0.15 wt%. What is the concentration in kilograms of carbon per cubic meter of alloy?", + "answer": "the concentration of carbon in the alloy is 11.8 \\mathrm{kg/m^{3}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（将重量百分比转换为每立方米的千克数），并应用相关公式（密度转换计算），最终给出具体数值结果。 | 知识层次: 题目需要进行基本的单位转换和公式应用（wt%到kg/m³的转换），属于直接套用密度和浓度关系的简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的浓度转换公式，将重量百分比转换为千克每立方米的单位，计算过程简单直接，无需多个公式组合或复杂推导。" + }, + { + "idx": 4237, + "question": "Cite the relative Burgers vector-dislocation line orientations for edge, screw, and mixed dislocations.", + "answer": "The Burgers vector and dislocation line are perpendicular for edge dislocations, parallel for screw dislocations, and neither perpendicular nor parallel for mixed dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述不同位错类型中Burgers矢量与位错线之间的相对取向关系，答案以文字描述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对位错类型（刃型、螺型和混合型）及其伯氏矢量与位错线相对取向的基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求记忆并复述三种位错的基本定义和相对取向关系，不涉及概念解释或复杂体系阐述，属于最基础的定义简答层次。" + }, + { + "idx": 4238, + "question": "For an FCC single crystal, would you expect the surface energy for a (100) plane to be greater or less than that for a (111) plane? Why? ", + "answer": "The surface energy for a crystallographic plane will depend on its packing density [i.e., the planar density (Section 3.11)] - that is, the higher the packing density, the greater the number of nearest-neighbor atoms, and the more atomic bonds in that plane that are satisfied, and, consequently, the lower the surface energy. From the solution to Problem 3.54, planar densities for FCC (100) and (111) planes are \\frac{1}{4 R^{2}} and \\frac{1}{2 R^{2} \\sqrt{3}}, respectively - that is \\frac{0.25}{R^{2}} and \\frac{0.29}{R^{2}} (where R is the atomic radius). Thus, since the planar density for (111) is greater, it will have the lower surface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述为什么FCC单晶的(100)面表面能会大于或小于(111)面，答案提供了详细的文字解释和理论依据，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解表面能与晶面密度的关系，并应用FCC晶体结构的平面密度计算结果进行比较分析。虽然涉及基础概念，但需要多步推理和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目不仅要求考生理解表面能与晶面密度的关系，还需要引用具体的平面密度计算数据（如FCC (100)和(111)面的平面密度），并进行比较分析。此外，题目还要求解释为什么平面密度较高的晶面具有较低的表面能量，这涉及到原子键合和能量状态的概念。因此，该题目在简答题中属于较高难度，需要综合运用多个概念和计算步骤来完整回答。" + }, + { + "idx": 4239, + "question": "For a BCC single crystal, would you expect the surface energy for a (100) plane to be greater or less than that for a (110) plane? Why? ", + "answer": "The surface energy for a crystallographic plane will depend on its packing density-that is, the higher the packing density, the greater the number of nearest-neighbor atoms, and the more atomic bonds in that plane that are satisfied, and, consequently, the lower the surface energy. From the solution to Problem 3.55, the planar densities for BCC (100) and (110) are \\frac{3}{16 R^{2}} and \\frac{3}{8 R^{2} \\sqrt{2}}, respectively-that is \\frac{0.19}{R^{2}} and \\frac{0.27}{R^{2}}. Thus, since the planar density for (110) is greater, it will have the lower surface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么BCC单晶的(100)面表面能会大于或小于(110)面，需要文字解释和论述，答案也提供了详细的解释和计算依据，属于简答题类型。 | 知识层次: 题目要求学生理解表面能与晶面密度的关系，并应用平面密度的计算结果进行比较分析。需要多步计算和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对BCC晶体的表面能进行多角度分析，包括平面堆积密度、最近邻原子数和原子键合状态的综合分析。解题步骤涉及查阅参考数据（Problem 3.55的平面密度计算结果）、进行数值比较（0.19/R² vs 0.27/R²），并最终关联到表面能的理论解释。这种需要多步骤计算和概念关联的论述题，在简答题中属于较高难度等级4。" + }, + { + "idx": 4240, + "question": "For a given material, would you expect the surface energy to be greater than, the same as, or less than the grain boundary energy? Why?", + "answer": "The surface energy will be greater than the grain boundary energy. For grain boundaries, some atoms on one side of a boundary will bond to atoms on the other side; such is not the case for surface atoms. Therefore, there will be fewer unsatisfied bonds along a grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么表面能会大于晶界能，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较表面能和晶界能的大小，并解释原因。这需要理解表面能和晶界能的定义，分析原子在不同界面处的键合情况，并进行比较。虽然不涉及复杂计算，但需要对概念进行关联和综合分析，思维过程有一定深度。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对表面能和晶界能进行比较，但只需要基于原子键合的基本概念进行解释，无需多角度或深度关联性分析。解题步骤相对直接，主要涉及对材料科学中表面和晶界原子排列差异的理解。" + }, + { + "idx": 4241, + "question": "The grain boundary energy of a small-angle grain boundary is less than for a high-angle one. Why is this so?", + "answer": "The small-angle grain boundary energy is lower than for a high-angle one because more atoms bond across the boundary for the small-angle, and, thus, there are fewer unsatisfied bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么小角度晶界能比大角度晶界能低，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释小角度晶界能量低于大角度晶界的原因，涉及晶界原子排列和键合状态的深入分析，需要综合运用晶界结构知识和能量形成机理进行推理解释。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于机理深度解释难度等级。题目要求解释小角度晶界能低于大角度晶界能的原因，需要综合运用晶界结构、原子键合等知识进行推理分析，并准确描述原子层面的机理解释。虽然不涉及多因素交互作用的复杂现象全面分析（等级5），但已超出基础概念复述层面，属于需要深入理解材料科学原理才能完整回答的问题类型。" + }, + { + "idx": 4242, + "question": "(a) Briefly describe a twin and a twin boundary.", + "answer": "A twin boundary is an interface such that atoms on one side are located at mirror image positions of those atoms situated on the other boundary side. The region on one side of this boundary is called a twin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述孪晶和孪晶边界，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对孪晶和孪晶界面的基本定义和概念的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求简要描述孪晶和孪晶界面的基本定义，属于最基础的概念记忆性知识。题目不需要深入解释或复杂的概念体系阐述，仅需简单回答定义即可，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 4243, + "question": "(b) Cite the difference between mechanical and annealing twins.", + "answer": "Mechanical twins are produced as a result of mechanical deformation and generally occur in BCC and HCP metals. Annealing twins form during annealing heat treatments, most often in FCC metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释机械孪晶和退火孪晶的区别，答案以文字解释和论述的形式给出，没有选项、判断对错或计算要求。 | 知识层次: 题目考查机械孪晶和退火孪晶的基本定义和形成条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求对两种不同类型的孪晶进行解释和区分，涉及基础概念的记忆和简单描述。虽然需要解释两种孪晶的形成条件和常见金属类型，但不需要复杂的分析或深入的论述，属于概念解释和描述的难度等级。" + }, + { + "idx": 4244, + "question": "Briefly explain the concept of steady state as it applies to diffusion.", + "answer": "Steady-state diffusion is the situation wherein the rate of diffusion into a given system is just equal to the rate of diffusion out, such that there is no net accumulation or depletion of diffusing species--i.e., the diffusion flux is independent of time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释稳态扩散的概念，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对稳态扩散这一基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要理解并解释\"steady state\"在扩散中的具体含义，但不需要涉及复杂的概念体系或多步骤的推理过程。题目主要考察对基础概念的记忆和简单应用，符合等级2对知识掌握深度和解题步骤的要求。" + }, + { + "idx": 4245, + "question": "(a) Briefly explain the concept of a driving force.", + "answer": "The driving force is that which compels a reaction to occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释一个概念，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对\"driving force\"这一基本概念的定义和简单理解，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求简要解释驱动力的概念，属于基础定义简答。题目仅涉及单一概念的定义，不需要深入的解释或复杂的论述，符合等级1的基本定义简答标准。" + }, + { + "idx": 4246, + "question": "(b) What is the driving force for steady-state diffusion?", + "answer": "The driving force for steady-state diffusion is the concentration gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案是一个简短的文字解释，没有涉及计算或选择选项。 | 知识层次: 题目考查对稳态扩散驱动力的基本概念记忆，即浓度梯度的定义，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（浓度梯度作为稳态扩散的驱动力），属于最基础的概念记忆层面，无需解释或复杂论述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这比需要描述扩散机制（等级2）或分析多因素耦合扩散（等级3）的题目简单得多。" + }, + { + "idx": 4247, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 10-h duration will raise the carbon concentration to 0.45 wt% at a point 2.5mm from the surface. Estimate the time necessary to achieve the same concentration at a 5.0-mm position for an identical steel and at the same carburizing temperature.", + "answer": "the time necessary to achieve a carbon concentration of 0.45 \\text{wt}% at a 5.0 \\text{mm} position is 40 \\text{h}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以估计达到特定碳浓度所需的时间。答案是一个具体的数值结果（40 h），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数调整，需要理解扩散距离与时间的关系，并进行综合分析。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（如Fick第二定律）进行多步计算，涉及距离与时间的平方关系推导（x²∝Dt），并要求学生理解相同温度条件下扩散系数D保持恒定的前提。虽然计算过程明确（t₂=(x₂²/x₁²)t₁），但需要学生正确关联概念并执行单位转换（mm²与h的关系），属于中等应用层次中复杂度较高的题目。" + }, + { + "idx": 4248, + "question": "The preexponential and activation energy for the diffusion of iron in cobalt are 1.1 × 10^{-5}{m}^{2} / s and 253,300 J/ mol, respectively. At what temperature will the diffusion coefficient have a value of 2.1 × 10^{-14}{m}^{2} / s ?", + "answer": "the temperature at which the diffusion coefficient has a value of 2.1 × 10^{-14} m^{2}/s is 1518 k (1245^{\\circ} C). alternatively, using the vmse software, the temperature is found to be 1519 k.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数公式（阿伦尼乌斯方程）进行数值计算，求出特定扩散系数对应的温度。答案提供了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，需要理解公式中各参数的含义及其相互关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，同时需要理解扩散系数与温度的关系。虽然计算步骤明确，但需要较强的数值处理能力和对物理概念的掌握。" + }, + { + "idx": 4249, + "question": "The activation energy for the diffusion of carbon in chromium is 111,000 J/ mol. Calculate the diffusion coefficient at 1100 K\\left(827^{\\circ} C\\right), given that D at 1400 K\\left(1127^{\\circ} C\\right) is 6.25 × 10^{-11}{m}^{2} / s.", + "answer": "the diffusion coefficient at 1100k is 4.6 × 10^{-12}{m}^{2} / s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散系数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及温度转换和指数运算，需要理解扩散激活能的概念并正确关联不同温度下的扩散系数。虽然计算过程较为直接，但需要一定的综合分析能力和对公式的深入理解。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、对数运算和指数运算。虽然计算过程较为直接，但需要正确理解和关联扩散系数与温度的关系，属于中等应用层次的计算题。" + }, + { + "idx": 4250, + "question": "The diffusion coefficients for iron in nickel are given at two temperatures: 1273 K with D = 9.4 x 10^-16 m^2/s and 1473 K with D = 2.4 x 10^-14 m^2/s. Determine the values of D0 and the activation energy Qd.", + "answer": "the values are d0 = 2.2 x 10^-5 m^2/s and the activation energy qd = 252,400 j/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，计算D0和激活能Qd的值。解答过程需要应用阿伦尼乌斯方程进行数值计算，最终给出具体的数值结果。这符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯方程进行多步计算，涉及对数运算和线性回归分析，需要理解温度与扩散系数的关系，并能够正确关联公式中的各个参数。虽然不涉及复杂的机理分析或创新设计，但计算过程需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和联立方程求解，同时需要理解扩散系数与温度的关系。虽然计算步骤明确，但需要较强的概念关联和综合分析能力。" + }, + { + "idx": 4251, + "question": "The diffusion coefficients for iron in nickel are given at two temperatures: 1273 K with D = 9.4 x 10^-16 m^2/s and 1473 K with D = 2.4 x 10^-14 m^2/s. What is the magnitude of D at 1100°C (1373 K)?", + "answer": "the magnitude of d at 1100°c (1373 k) is 5.4 x 10^-15 m^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用阿伦尼乌斯方程进行计算，最终得出在特定温度下的扩散系数数值。答案是一个具体的计算结果，而非选择、判断或文字解释。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯方程进行多步计算，涉及对数运算和温度单位的转换，需要理解扩散系数与温度的关系，并进行综合分析以求解未知温度下的扩散系数。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，包括温度转换、对数运算和指数运算。虽然计算过程较为直接，但涉及多个概念的综合应用和单位转换，属于中等偏上的难度水平。" + }, + { + "idx": 4252, + "question": "The diffusion coefficients for silver in copper are given at two temperatures: T(°C) = 650, D(m2/s) = 5.5 × 10^-16 and T(°C) = 900, D(m2/s) = 1.3 × 10^-13. Determine the values of D0 and Qd.", + "answer": "the values are d0 = 7.5 × 10^-5 m2/s and qd = 196,700 j/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用阿伦尼乌斯方程计算D0和Qd的值。解答过程涉及数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯方程进行多步计算，涉及对数运算和方程求解，需要理解温度与扩散系数的关系并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯方程进行多步计算，涉及对数运算和单位转换，但步骤相对明确，属于该题型内的中等难度。" + }, + { + "idx": 4253, + "question": "The diffusion coefficients for silver in copper are given at two temperatures: T(°C) = 650, D(m2/s) = 5.5 × 10^-16 and T(°C) = 900, D(m2/s) = 1.3 × 10^-13. What is the magnitude of D at 875°C?", + "answer": "the magnitude of d at 875°c is 8.3 × 10^-14 m2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的扩散系数数据，通过计算得出在875°C时的扩散系数值。解答过程需要应用阿伦尼乌斯方程或其他相关公式进行数值计算，最终给出一个具体的数值结果。 | 知识层次: 题目需要应用阿伦尼乌斯方程进行多步计算，涉及温度转换和自然对数运算，需要综合分析给定数据并正确应用公式求解扩散系数。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散系数的阿伦尼乌斯方程进行多步计算，包括温度转换、对数运算和指数运算。虽然计算过程较为复杂，但属于典型的材料科学扩散问题，在同类题型中属于中等偏上难度。" + }, + { + "idx": 4254, + "question": "Carbon is allowed to diffuse through a steel plate 15mm thick. The concentrations of carbon at the two faces are 0.65 and 0.30kg C / m^{2} Fe, which are maintained constant. If the preexponential and activation energy are 6.2 × 10^{-7}{m}^{2} / s and 80,000 J/ mol, respectively, compute the temperature at which the diffusion flux is 1.43 × 10^{-9}kg / m^{2}-s.", + "answer": "the temperature at which the diffusion flux is 1.43 × 10^{-9}kg / m^{2}-s is 1044k or 771^{\\circ} C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如扩散通量公式和Arrhenius方程）来求解温度，答案也是具体的数值结果。 | 知识层次: 题目需要应用扩散通量的计算公式，涉及多步计算和概念关联（如扩散系数与温度的关系），但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律（菲克第一定律）和扩散系数公式（阿伦尼乌斯方程），涉及多步计算和概念关联。虽然计算步骤较多，但变量关系明确，属于中等应用层次。" + }, + { + "idx": 4255, + "question": "The steady-state diffusion flux through a metal plate is 5.4 × 10^{-10}kg / m^{2}-s at a temperature of 727^{\\circ} C (1000 K) and when the concentration gradient is -350kg / m^{4}. Calculate the diffusion flux at 1027^{\\circ} C(1300 K) for the same concentration gradient and assuming an activation energy for diffusion of 125,000 J/ mol.", + "answer": "the diffusion flux at 1027^{\\circ} C (1300 k) is 1.74 × 10^{-8} \\mathrm{kg/m^{2}-s}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散通量的计算和温度变化的影响，答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散通量的公式并结合温度对扩散系数的影响进行计算。虽然不涉及复杂的推理分析或机理解释，但需要理解扩散通量与温度、浓度梯度之间的关系，并进行适当的数值计算。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散通量公式和温度对扩散系数的影响公式，涉及多步计算和概念关联。虽然计算步骤较多，但变量关系明确，属于中等应用层次。" + }, + { + "idx": 4256, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 275 MPa (40,000 psi), and the modulus of elasticity is 115 GPa (16.7 x 10^6 psi). What is the maximum load that may be applied to a specimen with a cross-sectional area of 325 mm^2 (0.5 in.^2) without plastic deformation?", + "answer": "the maximum load that may be applied without plastic deformation is 89,375 n (20,000 lb_f).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应力=力/面积）来确定最大载荷，答案也是具体的数值结果。 | 知识层次: 题目考查基本公式（应力=力/面积）的直接应用和简单计算，仅需一步转换即可得出结果，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用应力公式（应力=力/面积）进行简单的数值计算，无需多个公式组合或复杂步骤。直接套用基本公式即可得出答案，属于该题型内最基础的难度等级。" + }, + { + "idx": 4257, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 275 MPa (40,000 psi), and the modulus of elasticity is 115 GPa (16.7 x 10^6 psi). If the original specimen length is 115mm (4.5 in.), what is the maximum length to which it may be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen may be stretched without causing plastic deformation is 115.28mm (4.51 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最大拉伸长度，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即利用胡克定律计算弹性变形范围内的最大伸长量。虽然需要理解塑性变形和弹性模量的概念，但整体思维过程较为直接，属于基础知识的简单应用。 | 难度: 在计算题中属于最低难度，仅需直接应用胡克定律（应力=弹性模量×应变）这一单一公式进行计算，无需多步推导或组合公式。解题步骤仅为：1) 计算弹性应变；2) 用原始长度乘以应变增量。所有参数均为直接给定，无隐含条件或单位转换障碍（题目已提供国际单位和英制单位）。" + }, + { + "idx": 4258, + "question": "A cylindrical rod of copper (E=110g P a, 16 × 10^{6} psi) having a yield strength of 240 MPa(35,000 psi) is to be subjected to a load of 6660N\\left(1500 lb p\\right). If the length of the rod is 380 mm(15.0 in.), what must be the diameter to allow an elongation of 0.50 mm(0.020 in.) ?", + "answer": "the diameter must be 7.65mm (0.30 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定铜棒的直径，以满足特定的伸长量要求。答案是一个具体的数值（7.65mm），这表明需要通过计算来得出结果。 | 知识层次: 题目需要进行多步计算，包括应用胡克定律计算应变，然后通过几何关系计算直径，涉及概念关联和综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的计算步骤和公式应用能力。 | 难度: 在计算题中属于综合性计算问题，需要应用弹性模量、应力应变关系、几何变形公式等多步计算，并关联材料力学性能参数。虽然不涉及复杂多变量计算，但解题步骤较多且需要综合分析，符合等级3的标准。" + }, + { + "idx": 4259, + "question": "Compute the elastic modulus for titanium, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(a) the elastic modulus for titanium is 106.4 gpa, which is in very good agreement with the value of 107 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算钛的弹性模量，并将计算结果与表格中的参考值进行比较。虽然答案给出了具体数值，但解答过程需要基于应力-应变曲线进行数值计算，符合计算题的特征。 | 知识层次: 题目要求通过应力-应变行为计算钛的弹性模量，并与已知数据进行比较。这涉及基本的公式应用和简单计算，属于直接套用基本知识的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于最简单等级，仅需单一公式（弹性模量=应力/应变）直接计算，且题目已明确给出应力-应变曲线数据来源，无需额外推导或组合公式。计算过程仅涉及基本单位换算和简单除法，与参考值的比较也属于直接对比。" + }, + { + "idx": 4260, + "question": "Compute the elastic modulus for tempered steel, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(b) the elastic modulus for tempered steel is 204.7 gpa, which is in reasonably good agreement with the value of 207 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算回火钢的弹性模量，并将计算结果与表格中的数值进行比较。答案给出了具体的计算数值（204.7 GPa）和对比分析，符合计算题的特征。 | 知识层次: 题目要求计算弹性模量，并比较给定数值，主要涉及基本公式应用和简单计算，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算，仅需要从应力-应变曲线中读取弹性模量值并与给定表格值进行简单比较，无需复杂计算或多公式组合应用。" + }, + { + "idx": 4261, + "question": "Compute the elastic modulus for aluminum, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(c) the elastic modulus for aluminum is 69.1 gpa, which is in excellent agreement with the value of 69 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出铝的弹性模量，并与表格中的参考值进行比较。答案给出了具体的计算数值（69.1 GPa）和比较结果，这符合计算题的特征。 | 知识层次: 题目要求通过应力-应变曲线计算弹性模量，并与已知数据进行比较。这涉及基本的公式应用和简单计算，属于直接套用基础知识的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，仅需通过应力-应变曲线直接读取弹性模量数值，并与给定表格数据进行简单对比验证，不涉及复杂公式或多步骤计算。" + }, + { + "idx": 4262, + "question": "Compute the elastic modulus for carbon steel, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(d) the elastic modulus for carbon steel is 215 gpa, which is in reasonable agreement with the value of 207 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算碳钢的弹性模量，并将计算结果与表格中的参考值进行比较。虽然答案给出了具体数值，但解题过程需要通过应力-应变曲线进行计算，属于典型的计算题特征。 | 知识层次: 题目要求计算碳钢的弹性模量，并与参考值进行比较。这涉及基本的应力-应变关系理解和简单公式应用，属于直接套用基本知识的简单应用层次。 | 难度: 在计算题中属于最简单难度，仅需单一公式直接计算弹性模量，且题目已明确给出应力-应变曲线作为数据来源，只需读取数据并套用弹性模量定义公式E=σ/ε进行计算。与参考值的比较也是直接数值对比，无需复杂分析或推导。" + }, + { + "idx": 4263, + "question": "Consider a cylindrical specimen of some hypothetical metal alloy that has a diameter of 8.0 mm(0.31 in.). A tensile force of 1000N\\left(225 lb_{\\mathrm{f}}\\right) produces an elastic reduction in diameter of 2.8 × 10^{-4} mm\\left(1.10 × 10^{-5} in\\right..). Compute the modulus of elasticity for this alloy, given that Poisson's ratio is 0.30 .", + "answer": "the modulus of elasticity for this alloy is 1.705 × 10^{11} pa or 170.5 gpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解弹性模量，答案是一个具体的数值结果，解答过程需要运用材料力学中的相关公式和计算步骤。 | 知识层次: 题目需要进行多步计算，包括应力、应变的计算，并应用胡克定律和泊松比的概念来求解弹性模量。这需要理解相关概念并能够将它们关联起来进行综合分析，而不仅仅是简单的公式套用或基础概念的记忆。 | 难度: 在计算题中属于综合性计算问题，需要应用弹性模量、泊松比和应变关系的多个公式，并进行多步计算。虽然不涉及复杂多变量，但要求对材料力学基础概念的综合理解和应用能力。" + }, + { + "idx": 4264, + "question": "A cylindrical rod 100mm long and having a diameter of 10.0mm is to be deformed using a tensile load of 27,500 N. It must not experience plastic deformation. Of the materials listed as follows, which are possible candidates? Justify your choice(s).", + "answer": "Of the alloys listed, the steel alloy is a possible candidate because it meets the criterion of not experiencing plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个材料中选择符合条件的候选材料，并需要文字解释和论述来证明选择，这符合简答题的特征。 | 知识层次: 题目需要学生进行多步计算（计算应力并与材料屈服强度比较），同时需要综合分析不同材料的性能参数，并做出合理选择。这涉及概念关联和综合分析能力，超出了简单应用但尚未达到复杂分析或高级综合的层次。 | 难度: 在简答题题型中，该题目属于较高难度。题目要求考生进行多步计算（如应力计算、屈服强度比较等），并需要综合分析不同材料的性能参数。此外，考生还需结合塑性变形的概念进行论述，选择合适材料并给出合理依据。这些要求使得该题目在同类简答题中具有较高的复杂性和综合性，符合等级4的标准。" + }, + { + "idx": 4265, + "question": "A cylindrical rod 100mm long and having a diameter of 10.0mm is to be deformed using a tensile load of 27,500 N. It must not experience a diameter reduction of more than 7.5 x 10^-3 mm. Of the materials listed as follows, which are possible candidates? Justify your choice(s).", + "answer": "Of the alloys listed, the steel alloy is a possible candidate because it meets the criterion regarding diameter reduction. The titanium alloy is not a candidate as it fails this criterion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个材料中选择符合条件的候选材料，并需要文字解释和论述来证明选择的合理性。答案中提供了对选择的材料进行解释和论述，符合简答题的特征。 | 知识层次: 题目需要多步计算（包括应力、应变和泊松比的计算）和综合分析（比较不同材料的性能参数），涉及概念关联和判断选择，但不需要复杂的推理分析或创新设计。 | 难度: 在简答题题型中，该题目属于多角度分析论述的难度等级。题目要求考生不仅进行多步计算（如应力、应变、弹性模量等），还需要综合分析不同材料的性能参数，并关联直径变化限制这一具体工程要求进行判断。此外，题目还要求考生对材料选择进行合理性论证，这需要将计算结果与材料特性进行深度关联，并排除不符合条件的选项。因此，该题目在简答题题型中属于较高难度的综合分析类问题。" + }, + { + "idx": 4266, + "question": "A cylindrical metal specimen having an original diameter of 12.8mm (0.505 in.) and gauge length of 50.80mm (2.000 in.) is pulled in tension until fracture occurs. The diameter at the point of fracture is 6.60mm (0.260 in.), and the fractured gauge length is 72.14mm (2.840 in.). Calculate the ductility in terms of percent reduction in area.", + "answer": "the ductility in terms of percent reduction in area is 73.4%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算面积减少百分比），并给出了具体的数值和公式应用步骤，最终得出一个具体的数值答案。 | 知识层次: 题目要求进行基本的数值计算和公式应用，涉及简单的面积变化百分比计算，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于简单公式应用计算，仅需套用百分面积缩减率公式（(原始面积-断裂面积)/原始面积×100%），虽然涉及直径到面积的转换计算，但无需多步骤推导或复杂公式组合，属于该题型内中等偏下的难度水平。" + }, + { + "idx": 4267, + "question": "A cylindrical metal specimen having an original diameter of 12.8mm (0.505 in.) and gauge length of 50.80mm (2.000 in.) is pulled in tension until fracture occurs. The diameter at the point of fracture is 6.60mm (0.260 in.), and the fractured gauge length is 72.14mm (2.840 in.). Calculate the ductility in terms of percent elongation.", + "answer": "the ductility in terms of percent elongation is 42%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解延展性（percent elongation），答案是一个具体的数值结果（42%），解答过程需要基于给定的尺寸数据进行计算。 | 知识层次: 题目要求应用基本公式（百分伸长率计算公式）进行简单计算，不需要多步推导或综合分析，属于直接套用公式的简单应用类型。 | 难度: 在计算题-简单应用题型中，该题目仅需要单一公式（百分伸长率公式）的直接计算，解题步骤简单明确，属于该题型内最基础的难度等级。只需将给定的断裂后长度和原始长度代入公式即可得出结果，无需多步骤推导或复杂公式组合。" + }, + { + "idx": 4268, + "question": "For some metal alloy, a true stress of 415 MPa(60,175 psi) produces a plastic true strain of 0.475 . How much will a specimen of this material elongate when a true stress of 325 MPa(46,125 psi) is applied if the original length is 300mm (11.8 in.)? Assume a value of 0.25 for the strain-hardening exponent n.", + "answer": "the specimen will elongate by 58.8 mm (2.31 \\text{ in}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及应力、应变和伸长量的计算，答案也是具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括应用应变硬化公式和真实应力-应变关系，涉及概念关联和综合分析。虽然计算过程较为直接，但需要理解应变硬化指数n的含义及其在计算中的应用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用应变硬化公式进行多步计算，涉及真实应力-应变关系的转换和塑性变形量的推导。虽然计算步骤明确，但需要正确理解并关联多个材料科学概念（如应变硬化指数、真实应变与工程应变的转换），并对公式进行适当变形和代入。这比简单的单步计算题（等级2）更复杂，但尚未达到需要处理多变量或非线性关系的等级4难度。" + }, + { + "idx": 4269, + "question": "Cite five factors that lead to scatter in measured material properties.", + "answer": "The five factors that lead to scatter in measured material properties are the following: (1) test method; (2) variation in specimen fabrication procedure; (3) operator bias; (4) apparatus calibration; and (5) material inhomogeneities and/or compositional differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释导致材料性能测量分散的五个因素，答案以文字形式详细列出各个因素，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对导致材料性能测量分散的因素的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要列举五个导致材料性能测量分散的因素，但每个因素都是基础概念记忆层面的内容，不需要复杂的分析或深入的概念体系阐述。题目要求的是对基本原理的记忆和简单解释，符合等级2的标准。" + }, + { + "idx": 4270, + "question": "To provide some perspective on the dimensions of atomic defects, consider a metal specimen that has a dislocation density of 10^4 mm^-2. Suppose that all the dislocations in 1000 mm^3 (1 cm^3) were somehow removed and linked end to end. How far (in miles) would this chain extend?", + "answer": "for a dislocation density of 10^4 mm^-2, the chain would extend 6.2 miles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，具体包括计算位错密度和长度转换，最终得出以英里为单位的链长。答案是一个具体的数值结果，而不是选择、判断或文字解释。 | 知识层次: 题目涉及基本的数值计算和公式应用，需要将给定的位错密度转换为总长度，并进行单位换算。虽然需要一定的计算步骤，但整体上属于直接套用公式和简单计算的范畴，不需要复杂的分析或综合能力。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的密度和长度转换公式，将给定的数据直接代入计算即可得出结果，无需复杂的步骤或多公式组合。" + }, + { + "idx": 4271, + "question": "Now suppose that the density is increased to 10^10 mm^-2 by cold working. What would be the chain length of dislocations in 1000 mm^3 of material?", + "answer": "for a dislocation density of 10^10 mm^-2, the chain would extend 6.2 x 10^6 miles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（密度增加到10^10 mm^-2）来求解位错的链长度（6.2 x 10^6 miles），涉及公式应用和单位转换，属于典型的计算题。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的位错密度计算位错链的长度。虽然需要理解位错密度的概念，但计算过程相对直接，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的密度与体积关系公式进行计算，无需多个公式组合或复杂推导，解题步骤简单直接。" + }, + { + "idx": 4272, + "question": "For edge dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "edge dislocation--parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述edge dislocation中施加剪切应力方向与位错线运动方向之间的关系，答案形式为简短文字描述而非选择或计算。 | 知识层次: 题目考查对边缘位错基本概念的记忆和理解，即施加剪切应力方向与位错线运动方向之间的关系，属于基础概念的记忆性知识。 | 难度: 在简答题 - 需要文字解释和论述的题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆并简单陈述刃位错中施加剪应力方向与位错线运动方向之间的关系（平行），不涉及概念解释或复杂体系阐述，属于该题型下最基础的知识点考察。" + }, + { + "idx": 4273, + "question": "For screw dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "screw dislocation--perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述螺丝位错中施加剪切应力方向与位错线运动方向之间的关系，答案需要文字描述而非选择或判断。 | 知识层次: 题目考查对螺型位错基本概念的记忆和理解，即施加的剪切应力方向与位错线运动方向之间的关系，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述screw dislocation的应力方向与位错线运动方向的关系（垂直），不涉及概念解释或复杂体系阐述。" + }, + { + "idx": 4274, + "question": "For mixed dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "mixed dislocation--neither parallel nor perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释混合位错中施加剪切应力方向与位错线运动方向之间的关系，答案是一个描述性的陈述，而不是选择、判断或计算。 | 知识层次: 题目考查对混合位错基本概念的记忆和理解，即混合位错在施加剪切应力作用下的运动方向与应力方向的关系，属于基础概念的记忆性知识。 | 难度: 在简答题中属于基本定义简答，仅需记忆混合位错的定义特征（位错线运动方向与外加剪应力方向的关系），无需深入解释或复杂论述。" + }, + { + "idx": 4275, + "question": "Define a slip system.", + "answer": "A slip system is a crystallographic plane, and, within that plane, a direction along which dislocation motion (or slip) occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"slip system\"进行定义和解释，需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查基本概念的记忆和理解，要求对\"slip system\"这一基础术语进行定义，属于材料科学中晶体缺陷和变形机制的基础知识范畴。 | 难度: 在简答题题型中，该题目仅要求对\"slip system\"进行基本定义简答，属于最基础的概念记忆层次。题目不涉及概念的解释、描述或复杂体系的阐述，仅需直接回忆并写出定义即可，因此在该题型内属于最低难度等级。" + }, + { + "idx": 4276, + "question": "Do all metals have the same slip system? Why or why not?", + "answer": "All metals do not have the same slip system. The reason for this is that for most metals, the slip system will consist of the most densely packed crystallographic plane, and within that plane the most closely packed direction. This plane and direction will vary from crystal structure to crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么所有金属的滑移系统不同，答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对金属滑移系统的基本概念的理解，需要记忆不同晶体结构中滑移面的差异，并解释其原因。属于基础概念的记忆和理解层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释为什么不同金属的滑移系统不同，这需要理解滑移系统的基本原理（最密排面和最密排方向）以及不同晶体结构的影响。虽然涉及多个概念，但不需要深入分析复杂机制或进行多步骤推导，属于中等难度的概念解释题。" + }, + { + "idx": 4277, + "question": "Consider a metal single crystal oriented such that the normal to the slip plane and the slip direction are at angles of 43.1^{\\circ} and 47.9^{\\circ}, respectively, with the tensile axis. If the critical resolved shear stress is 20.7 MPa (3000 psi), will an applied stress of 45 MPa(6500 psi) cause the single crystal to yield? If not, what stress will be necessary?", + "answer": "the resolved shear stress is 22.0 MPa (3181 psi). since this is greater than the critical resolved shear stress of 20.7 MPa (3000 psi), the single crystal will yield.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算分解剪应力）并应用公式（Schmid定律），最终通过比较计算值与临界值来判断是否屈服。答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用（临界分切应力公式）和简单计算，不需要多步推理或综合分析，属于直接套用公式求解的范畴。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用临界分切应力公式进行计算，但仅涉及单一公式的直接套用和简单数值计算，无需多个公式组合或复杂推导。解题步骤清晰明确，属于该题型内中等偏下的难度水平。" + }, + { + "idx": 4278, + "question": "A single crystal of aluminum is oriented for a tensile test such that its slip plane normal makes an angle of 28.1 degrees with the tensile axis. Three possible slip directions make angles of 62.4 degrees, 72.0 degrees, and 81.1 degrees with the same tensile axis. Which of these three slip directions is most favored?", + "answer": "the most favored slip direction is at an angle of 62.4 degrees with the tensile axis.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述哪个滑移方向最有利，答案需要文字解释和论述，而不是简单的选择或计算。 | 知识层次: 题目需要应用施密特定律（Schmid's Law）计算临界分切应力，涉及多步计算和概念关联（滑移面法向与拉伸轴的夹角、滑移方向与拉伸轴的夹角）。虽然计算过程不复杂，但需要综合分析多个角度数据来确定最有利的滑移方向，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解临界分切应力概念并计算不同滑移方向的施密特因子，但无需多角度或深度关联性分析。" + }, + { + "idx": 4279, + "question": "A single crystal of aluminum is oriented for a tensile test such that its slip plane normal makes an angle of 28.1 degrees with the tensile axis. The most favored slip direction makes an angle of 62.4 degrees with the tensile axis. If plastic deformation begins at a tensile stress of 1.95 MPa (280 psi), determine the critical resolved shear stress for aluminum.", + "answer": "the critical resolved shear stress for aluminum is 0.80 mpa (114 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用（临界分切应力公式）来求解铝的临界分切应力，答案是一个具体的数值计算结果。 | 知识层次: 题目主要考查临界分解剪切应力的基本公式应用（Schmid定律），只需将给定的角度代入公式进行简单计算即可得到结果，不需要多步计算或复杂分析。 | 难度: 在计算题中属于简单应用难度，需要应用临界分切应力公式（Schmid定律）进行直接计算，但涉及角度转换和基本三角函数运算，属于简单公式应用计算。" + }, + { + "idx": 4280, + "question": "The critical resolved shear stress for iron is 27 MPa(4000 psi). Determine the maximum possible yield strength for a single crystal of \\mathrm{Fe} pulled in tension.", + "answer": "the maximum possible yield strength for a single crystal of \\mathrm{fe} pulled in tension is 54 MPa (8000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（临界分切应力与晶体取向的关系）来确定单晶铁的最大可能屈服强度，答案也是具体的数值结果。 | 知识层次: 题目需要应用临界分切应力的基本概念和公式进行简单计算，属于直接套用公式求解的范畴，不涉及多步计算或复杂分析。 | 难度: 在计算题-简单应用题型中，该题目仅需直接套用临界分切应力与屈服强度的基本关系公式（σ_y = 2τ_cr），无需多步骤推导或组合公式。计算过程仅涉及单位换算（MPa与psi）和简单乘法，属于单一公式直接计算的典型等级1难度。" + }, + { + "idx": 4281, + "question": "What is the difference between deformation by twinning and deformation by slip relative to mechanism?", + "answer": "With slip deformation there is no crystallographic reorientation, whereas with twinning there is a reorientation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种变形机制的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对变形机制中孪生和滑移的基本概念的理解和记忆，属于基础概念层次的认知能力要求。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要区分两种变形机制（滑移和孪生）的关键差异，但主要考察的是对基础概念的理解和对比能力，不需要涉及复杂的概念体系或深入的分析。题目要求明确指向机制差异这一核心点，属于中等难度的概念解释题。" + }, + { + "idx": 4282, + "question": "What is the difference between deformation by twinning and deformation by slip relative to conditions of occurrence?", + "answer": "For slip, the atomic displacements occur in atomic spacing multiples, whereas for twinning, these displacements may be other than by atomic spacing multiples. Slip occurs in metals having many slip systems, whereas twinning occurs in metals having relatively few slip systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释变形孪生和滑移变形在发生条件上的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较两种变形机制（孪生和滑移）的发生条件，涉及对两种机制的理解和对比分析，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于较高难度，需要综合分析和比较两种变形机制（孪生和滑移）的发生条件，涉及原子位移差异和金属晶体结构特性的多角度论述。" + }, + { + "idx": 4283, + "question": "What is the difference between deformation by twinning and deformation by slip relative to final result?", + "answer": "Normally slip results in relatively large deformations, whereas only small deformations result for twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种变形方式的区别，答案是以文字形式进行论述说明，没有选项或计算要求 | 知识层次: 题目考查对变形机制（孪生和滑移）的基本概念和区别的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较两种变形机制（孪生和滑移）的最终结果差异，需要学生对这两种机制的基本概念和特点有一定理解，并能进行简单的对比描述。虽然涉及两个概念的比较，但不需要深入分析复杂机制或建立概念体系，属于基础概念的应用层面。" + }, + { + "idx": 4284, + "question": "Briefly explain why small-angle grain boundaries are not as effective in interfering with the slip process as are high-angle grain boundaries.", + "answer": "Small-angle grain boundaries are not as effective in interfering with the slip process as are high-angle grain boundaries because there is not as much crystallographic misalignment in the grain boundary region for small-angle, and therefore not as much change in slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释小角度晶界在干扰滑移过程中不如大角度晶界有效的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释小角度晶界和大角度晶界对滑移过程干扰效果的差异，需要理解晶界结构对位错运动的影响机制，涉及晶体缺陷、位错理论等概念的关联和综合分析，属于对材料科学原理的深度理解和推理分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对晶界角度与滑移过程干扰效果之间的机理进行深度解释。需要综合运用晶体结构、位错理论和晶界特性等知识，通过推理分析说明小角度晶界与大角度晶界在阻碍滑移过程中的差异机制。虽然不涉及多因素交互作用的全面分析，但对材料变形机理的理解深度要求较高，属于机理深度解释层级。" + }, + { + "idx": 4285, + "question": "Briefly explain why HCP metals are typically more brittle than FCC and BCC metals.", + "answer": "Hexagonal close packed metals are typically more brittle than FCC and BCC metals because there are fewer slip systems in HCP.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释HCP金属比FCC和BCC金属更脆的原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释HCP金属比FCC和BCC金属更脆的原因，涉及对晶体结构、滑移系统等概念的理解和关联，需要综合分析不同晶体结构的特性及其对材料性能的影响。虽然不涉及复杂计算，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题中属于中等难度，需要理解HCP、FCC和BCC金属的晶体结构差异，并分析其对材料性能（如脆性）的影响。虽然题目要求解释原因，但答案相对直接，主要涉及对滑移系统数量的比较，不需要多角度或深度关联性分析。" + }, + { + "idx": 4286, + "question": "Two previously undeformed cylindrical specimens of an alloy are to be strain hardened by reducing their cross-sectional areas (while maintaining their circular cross sections). For one specimen, the initial and deformed radii are 16mm and 11 mm, respectively. The second specimen, with an initial radius of 12 mm, must have the same deformed hardness as the first specimen; compute the second specimen's radius after deformation.", + "answer": "the second specimen's radius after deformation is 8.25 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的初始半径和变形后的半径，计算第二个试样在变形后的半径以达到相同的硬度。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应变计算和硬度关联分析，涉及概念间的关联和综合分析。虽然不涉及复杂的推理或机理解释，但需要理解应变硬化原理并应用相关公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要理解应变硬化概念，应用面积变化公式进行多步计算，并综合分析两个试样的变形条件以达到相同的硬度。虽然不涉及复杂多变量，但需要关联多个概念和步骤。" + }, + { + "idx": 4287, + "question": "Two previously undeformed specimens of the same metal are to be plastically deformed by reducing their cross-sectional areas. One has a circular cross section, and the other is rectangular; during deformation the circular cross section is to remain circular, and the rectangular is to remain as such. Their original and deformed dimensions are as follows:\n\\begin{tabular}{ccc}\n\\hline & Circular (diameter, \\mathbf{m m} ) & Rectangular (\\mathbf{m m}) \\\\\n\\hline Original dimensions & 15.2 & 125 × 175 \\\\\nDeformed dimensions & 11.4 & 75 × 200 \\\\\n\\hline\n\\end{tabular}\nWhich of these specimens will be the hardest after plastic deformation, and why?", + "answer": "the hardest specimen will be the deformed circular one with a cold work percentage of 43.8%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来说明哪个试样在塑性变形后会最硬，并解释原因。答案提供了具体的解释和计算过程，而不是简单的选择或判断。 | 知识层次: 题目需要计算冷加工百分比，并比较不同形状试样的硬度变化。涉及多步计算（面积计算、冷加工百分比计算）和概念关联（冷加工与硬度的关系），但不需要复杂的机理分析或创新应用。 | 难度: 在简答题中属于较高难度，需要学生进行多步计算（如冷加工百分比的计算）、概念关联（如塑性变形与硬度关系）以及综合分析（比较不同形状的变形效果）。题目要求学生不仅掌握基础概念，还需要能够将不同知识点联系起来，并进行详细的解释和论述。" + }, + { + "idx": 4288, + "question": "A cylindrical specimen of cold-worked copper has a ductility (%EL) of 25%. If its cold-worked radius is 10mm (0.40 in.), what was its radius before deformation?", + "answer": "the radius before deformation was 10.6mm (0.424 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解变形前的半径，答案是一个具体的数值结果。 | 知识层次: 题目需要应用材料科学中的冷加工变形和延展性关系公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用材料科学中的塑性变形和延展性概念，进行多步计算和公式推导，涉及半径变化与延展性关系的综合分析。虽然计算过程不算极其复杂，但需要理解概念间的关联并正确应用公式，属于中等偏上的难度。" + }, + { + "idx": 4289, + "question": "Explain the differences in grain structure for a metal that has been cold worked and one that has been cold worked and then recrystallized.", + "answer": "During cold-working, the grain structure of the metal has been distorted to accommodate the deformation. Recrystallization produces grains that are equiaxed and smaller than the parent grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷加工和再结晶后金属晶粒结构的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷加工和再结晶后金属晶粒结构的差异，涉及对冷加工变形机制和再结晶过程的理解，需要将多个概念关联起来进行综合分析。虽然不涉及复杂计算，但需要对材料变形和热处理过程有较深入的理解，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解冷加工和再结晶对金属晶粒结构的影响，并进行综合分析和说明。题目要求解释两种不同处理方式下的晶粒结构差异，涉及多个概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4290, + "question": "What is the magnitude of the maximum stress that exists at the tip of an internal crack having a radius of curvature of 2.5 × 10^{-4} mm\\left(10^{-5} in.\\right) and a crack length of 2.5 × 10^{-2} mm\\left(10^{-3} in.\\right) when a tensile stress of 170 MPa(25,000 psi) is applied?", + "answer": "the magnitude of the maximum stress at the tip of the internal crack is 2404 \\text{ mpa} (354,000 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算内部裂纹尖端最大应力的数值，需要使用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用应力集中公式并结合给定的参数进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用应力集中公式并进行多步计算，涉及概念关联和综合分析，但未达到复杂多变量计算的难度。" + }, + { + "idx": 4291, + "question": "Estimate the theoretical fracture strength of a brittle material if it is known that fracture occurs by the propagation of an elliptically shaped surface crack of length 0.25 mm(0.01 in.) and having a tip radius of curvature of 1.2 × 10^{-3} mm\\left(4.7 × 10^{-5} in\\right..) when a stress of 1200 MPa(174,000 psi) is applied.", + "answer": "the theoretical fracture strength is 3.5 × 10^{4} MPa (5.1 × 10^{6} psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计脆性材料的理论断裂强度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用断裂力学中的理论强度公式，涉及多步计算和概念关联，如裂纹长度、应力集中系数和理论强度的关系。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及裂纹长度、应力集中系数等概念的综合分析，但计算过程相对直接，没有涉及复杂多变量或高阶数学处理。" + }, + { + "idx": 4292, + "question": "If the specific surface energy for soda-lime glass is 0.30 J/ m^{2}, using data contained in Table 12.5, compute the critical stress required for the propagation of a surface crack of length 0.05 mm.", + "answer": "the critical stress required for the propagation of a surface crack of length 0.05 mm is 16.2 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出一个具体的数值结果（16.2 MPa）。这符合计算题的特征，即需要应用公式和进行数值运算来解决问题。 | 知识层次: 题目需要应用临界应力公式进行计算，涉及多步推导和概念关联（如表面能、裂纹长度和临界应力的关系），但不需要复杂的综合分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用特定公式（临界应力公式）并结合给定的材料参数（比表面能）和裂纹长度进行多步计算。虽然计算过程涉及多个步骤，但变量相对明确，不需要处理复杂多变量或高度抽象的概念。" + }, + { + "idx": 4293, + "question": "A polystyrene component must not fail when a tensile stress of 1.25 MPa(180 psi) is applied. Determine the maximum allowable surface crack length if the surface energy of polystyrene is 0.50 J/ m^{2}\\left(2.86 × 10^{-3}\\right. in.-\\left.lb_{\\mathrm{f}} / in^{2}\\right). Assume a modulus of elasticity of 3.0 \\mathrm{GPa}\\left(0.435 × 10^{6} psi\\right).", + "answer": "the maximum allowable surface crack length is 6.1 × 10^{-4} \\, m (0.61mm or 0.024 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定最大允许表面裂纹长度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及表面能、弹性模量和应力等概念的关联，并应用断裂力学公式来求解最大允许表面裂纹长度。这需要一定的综合分析能力和对相关公式的理解与应用。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式（Griffith理论），涉及多步计算和单位转换，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4294, + "question": "A specimen of a 4340 steel alloy having a plane strain fracture toughness of 45 MPa \\sqrt{m}(41 ksi \\sqrt{in}.) is exposed to a stress of 1000 MPa(145,000 psi). Will this specimen experience fracture if it is known that the largest surface crack is 0.75 mm(0.03 in.) long? Why or why not? Assume that the parameter Y has a value of 1.0 .", + "answer": "the specimen will experience fracture because it can only tolerate a stress of 927 \\text{mpa} (133,500 \\text{psi}) before fracture, which is less than the applied stress of 1000 \\text{mpa} (145,000 \\text{psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定试样是否会断裂。解答过程涉及使用断裂韧性公式计算临界应力，并与实际应力进行比较。答案给出了具体的计算结果和结论，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用断裂力学公式计算临界应力，并与实际应力进行比较。虽然计算过程相对直接，但需要理解断裂韧性和裂纹长度的关系，以及如何应用这些概念来评估材料的断裂行为。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，并综合分析临界应力与施加应力的关系。题目涉及参数转换（MPa与psi）、临界裂纹尺寸计算以及安全评估，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4295, + "question": "Some aircraft component is fabricated from an aluminum alloy that has a plane strain fracture toughness of 35 MPa \\sqrt{m} (31.9 ksi \\sqrt{m}. It has been determined that fracture results at a stress of 250 MPa (36,250 psi) when the maximum (or critical) internal crack length is 2.0 mm(0.08 in.). For this same component and alloy, will fracture occur at a stress level of 325 MPa(47,125 psi) when the maximum internal crack length is 1.0 mm(0.04 in).? Why or why not?", + "answer": "fracture will not occur since the value 32.2 MPa \\sqrt{m} is less than the fracture toughness k_{ic} of the material, 35 MPa \\sqrt{m}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要应用断裂力学公式进行数值计算（计算临界应力强度因子），并将计算结果与材料的断裂韧性进行比较，最终得出是否发生断裂的结论。解答过程涉及具体数值运算和公式应用。 | 知识层次: 题目需要进行多步计算，包括应用断裂力学公式计算临界应力强度因子，并与材料的断裂韧性进行比较。虽然计算过程相对直接，但需要理解相关概念并进行综合分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，并综合分析应力、裂纹长度和材料断裂韧性之间的关系。虽然涉及多个变量，但计算步骤相对明确，属于中等应用层次。" + }, + { + "idx": 4296, + "question": "Suppose that a wing component on an aircraft is fabricated from an aluminum alloy that has a plane strain fracture toughness of 40 MPa \\sqrt{m} (36.4 k \\left.\\mathrm{si} \\sqrt{m}\\right). It has been determined that fracture results at a stress of 365 MPa(53,000 psi) when the maximum internal crack length is 2.5 mm(0.10 in.). For this same component and alloy, compute the stress level at which fracture will occur for a critical internal crack length of 4.0 mm(0.16 in.).", + "answer": "the stress level at which fracture will occur for a critical internal crack length of 4.0mm is 288 MPa (41,500 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解应力水平，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用断裂力学中的平面应变断裂韧性公式进行多步计算，涉及应力与裂纹长度的关系分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及应力强度因子和临界裂纹长度的关系，要求对概念有较好的理解并能正确关联和综合分析。虽然计算步骤不算极其复杂，但需要准确应用公式和单位转换，属于中等偏上的难度。" + }, + { + "idx": 4297, + "question": "A large plate is fabricated from a steel alloy that has a plane strain fracture toughness of 55 MPa \\sqrt{m}(50 ksi \\sqrt{in}.). If, during service use, the plate is exposed to a tensile stress of 200 MPa(29,000 psi), determine the minimum length of a surface crack that will lead to fracture. Assume a value of 1.0 for Y.", + "answer": "the minimum length of a surface crack that will lead to fracture is 0.024 \\, m (24 mm).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用平面应变断裂韧性公式）来确定表面裂纹的最小长度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用平面应变断裂韧性的公式进行多步计算，涉及应力、裂纹长度和几何因子的关联分析，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及平面应变断裂韧性和应力强度因子的概念关联，但计算过程相对直接，没有涉及复杂多变量或非线性关系。" + }, + { + "idx": 4298, + "question": "Calculate the maximum internal crack length allowable for a 7075-T651 aluminum alloy (Table 8.1) component that is loaded to a stress one half of its yield strength. Assume that the value of Y is 1.35 .", + "answer": "the maximum internal crack length allowable is 0.0033 \\, m (3.3 mm).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用公式来求解最大内部裂纹长度，答案是一个具体的数值结果（0.0033 m），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及材料性能参数查找（7075-T651铝合金的屈服强度）、应力强度因子公式的应用（Y值的使用），以及临界裂纹长度的计算。虽然不涉及复杂的综合分析或创新设计，但需要理解和关联多个概念，并进行适当的数值计算。 | 难度: 在计算题-需要数值计算和公式应用题型中，该题目属于综合性计算问题。题目要求考生掌握材料断裂韧性的概念，能够应用断裂力学公式（如K_IC = Yσ√(πa)）进行多步骤计算，并需要从材料表中查找相关参数（如7075-T651铝合金的K_IC值）。虽然计算过程本身不涉及复杂多变量，但需要将多个概念和步骤综合运用，因此在该题型内属于中等偏上难度。" + }, + { + "idx": 4299, + "question": "A structural component in the form of a wide plate is to be fabricated from a steel alloy that has a plane strain fracture toughness of 77.0 MPa \\sqrt{m}(70.1 ksi \\sqrt{m}.) and a yield strength of 1400 MPa(205,000 psi). The flaw size resolution limit of the flaw detection apparatus is 4.0 mm(0.16 in.) If the design stress is one half of the yield strength and the value of Y is 1.0 , determine whether or not a critical flaw for this plate is subject to detection.", + "answer": "the critical flaw size a_c is 3.9 mm. therefore, the critical flaw is not subject to detection since it is less than the 4.0 mm resolution limit.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定临界缺陷尺寸是否可被检测到。答案给出了具体的计算结果（3.9 mm），并基于此进行了判断。 | 知识层次: 题目需要进行多步计算，包括应用断裂韧性公式计算临界缺陷尺寸，并将结果与检测设备的极限分辨率进行比较。虽然涉及的概念和公式相对明确，但需要综合理解和应用多个参数（断裂韧性、屈服强度、设计应力、几何因子等），并进行适当的单位转换和逻辑判断。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及临界裂纹尺寸的确定和检测限度的比较。虽然计算步骤相对明确，但需要理解多个概念（如断裂韧性、设计应力、检测分辨率）并进行综合分析，属于中等应用层次的计算题。" + }, + { + "idx": 4300, + "question": "Cite five factors that may lead to scatter in fatigue life data.", + "answer": "Five factors that lead to scatter in fatigue life data are (1) specimen fabrication and surface preparation, (2) metallurgical variables, (3) specimen alignment in the test apparatus, (4) variation in mean stress, and (5) variation in test cycle frequency.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释五个可能导致疲劳寿命数据分散的因素，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目主要考查对疲劳寿命数据分散性影响因素的基本记忆和列举，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要列举五个导致疲劳寿命数据分散的因素，但每个因素都是基础概念记忆层面的内容，不需要深入分析或复杂推理。相比等级1的基本定义简答，该题目要求稍高的记忆广度和基础概念的组织能力，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 4301, + "question": "Briefly explain the difference between fatigue striations and beachmarks in terms of size.", + "answer": "With regard to size, beachmarks are normally of macroscopic dimensions and may be observed with the naked eye; fatigue striations are of microscopic size and it is necessary to observe them using electron microscopy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释两种现象在尺寸上的差异，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查疲劳条纹和海滩标记在尺寸上的基本区别，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要解释疲劳条纹和海滩标记在尺寸上的差异，这需要学生对这两个概念有基本的理解和记忆，并能进行简单的对比描述。虽然涉及两个概念的比较，但不需要复杂的分析或深入的阐述，因此属于中等难度。" + }, + { + "idx": 4302, + "question": "Briefly explain the difference between fatigue striations and beachmarks in terms of origin.", + "answer": "With regard to origin, beachmarks result from interruptions in the stress cycles; each fatigue striation corresponds to the advance of a fatigue crack during a single load cycle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释疲劳条纹和海滩标记在起源上的区别，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查疲劳条纹和海滩标记的基本概念及其起源的区别，属于对基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目要求解释两个相关概念的区别，并具体说明其起源。这需要考生不仅记忆疲劳条纹和海滩标记的定义，还要理解它们在疲劳断裂过程中的形成机制。虽然涉及两个概念的对比，但解释的深度和复杂性仍属于中等水平，没有要求阐述整个疲劳断裂理论体系。因此在该题型内属于等级2难度。" + }, + { + "idx": 4303, + "question": "List four measures that may be taken to increase the resistance to fatigue of a metal alloy.", + "answer": "Four measures that may be taken to increase the fatigue resistance of a metal alloy are:\n(1) Polish the surface to remove stress amplification sites.\n(2) Reduce the number of internal defects (pores, etc.) by means of altering processing and fabrication techniques.\n(3) Modify the design to eliminate notches and sudden contour changes.\n(4) Harden the outer surface of the structure by case hardening (carburizing, nitriding) or shot peening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出四种提高金属合金疲劳抗力的措施，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目要求列举提高金属合金疲劳抗力的措施，涉及多个方面的知识应用，包括表面处理、内部缺陷控制、设计修改和表面硬化等。虽然不需要复杂的计算或深度分析，但需要综合理解和应用多个相关概念，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求列举四项提高金属合金疲劳抗力的措施，但每项措施都需要一定的材料科学知识基础，并能够理解不同处理方法的原理和效果。题目涉及表面处理、内部缺陷控制、设计优化和表面硬化等多个方面，需要考生进行综合分析和说明，但不需要进行过于深入的多角度或关联性分析。" + }, + { + "idx": 4304, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for nickel.", + "answer": "for ni: 418 degrees c (785 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对镍材料蠕变变形温度这一基本概念的记忆，不需要复杂的分析或计算，仅需直接回忆或查找相关数据即可回答。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回忆镍材料发生蠕变变形的近似温度值，不需要进行概念解释或复杂体系阐述。该知识点属于基础概念记忆层次，只需掌握单一数据点即可作答，在同类简答题中属于最基础级别的难度。" + }, + { + "idx": 4305, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for copper.", + "answer": "for cu: 270 degrees c (518 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算或公式应用。答案是一个简短的数值回答，符合简答题的特征。 | 知识层次: 题目考查对铜材料蠕变温度这一特定数值的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析过程。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆铜的蠕变温度这一具体数值，无需解释概念或进行复杂论述。题目仅考察基础概念的记忆能力，属于该题型下最低难度层级。" + }, + { + "idx": 4306, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for iron.", + "answer": "for fe: 450 degrees c (845 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要从多个选项中选择，也不涉及判断对错或复杂的计算过程，属于简答题类型。 | 知识层次: 题目考查对铁材料蠕变温度这一基本概念的记忆，不需要复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求记忆并给出铁材料蠕变变形开始成为重要考虑因素的温度值，不需要额外的概念解释或复杂体系阐述。这符合基础概念记忆的知识层次要求，属于该题型内最简单的难度等级。" + }, + { + "idx": 4307, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for tungsten.", + "answer": "for w: 1200 degrees c (2190 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要从多个选项中选择，也不涉及判断对错或复杂的计算过程，属于简答题类型。 | 知识层次: 题目考查对钨材料蠕变变形温度这一特定数值的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用过程。 | 难度: 在简答题的基础概念记忆题型中，该题目仅要求回忆钨的蠕变温度这一具体数值，属于最基本的事实性知识问答。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单直接的记忆性题目。" + }, + { + "idx": 4308, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for lead.", + "answer": "for pb: -33 degrees c (-27 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对铅材料蠕变温度这一特定基础知识的记忆，不需要复杂的应用或分析过程，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求记忆并复述铅的蠕变温度这一具体数值，属于最基础的定义性知识问答。题目不涉及概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。在同类记忆性简答题中，这是最基础、最直接的考查方式。" + }, + { + "idx": 4309, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for aluminum.", + "answer": "for al: 100 degrees c (212 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要从多个选项中选择，也不涉及判断对错或复杂的计算过程，属于简答题类型。 | 知识层次: 题目考查对铝材料蠕变变形温度的基本概念记忆，属于基础知识的直接回忆，无需复杂分析或应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆层次，仅需要回忆铝的蠕变温度这一具体数值即可作答，无需进行概念解释或复杂体系阐述。题目要求的知识点掌握深度最浅，解题步骤最为简单，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4310, + "question": "Cite three variables that determine the microstructure of an alloy.", + "answer": "Three variables that determine the microstructure of an alloy are (1) the alloying elements present, (2) the concentrations of these alloying elements, and (3) the heat treatment of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并解释决定合金微观结构的三个变量，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对合金微观结构决定因素的基础概念记忆，仅需列举三个变量，无需深入分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求列举三个决定合金微观结构的变量，不需要进行概念解释或复杂阐述。答案直接对应基础概念记忆层面的知识点，属于该题型下最简单的难度等级。" + }, + { + "idx": 4311, + "question": "What thermodynamic condition must be met for a state of equilibrium to exist?", + "answer": "In order for a system to exist in a state of equilibrium the free energy must be a minimum for some specified combination of temperature, pressure, and composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述热力学条件，答案提供了详细的文字描述而非选择、判断或计算。 | 知识层次: 题目考查对热力学平衡状态基本条件的记忆和理解，属于基础概念层面的知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释热力学平衡状态的条件，涉及自由能最小化的基本原理，但不需要复杂的推导或多概念整合。属于对基础概念的理解和表述要求，符合等级2的标准。" + }, + { + "idx": 4312, + "question": "For alloys of two hypothetical metals A and B, there exist an α, A-rich phase and a β, B-rich phase. From the mass fractions of both phases for two different alloys provided in the table below, (which are at the same temperature), determine the composition of the phase boundary (or solubility limit) for the α phase at this temperature.", + "answer": "the composition of the phase boundary for the α phase is 90 wt% A-10 wt% B.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的质量分数数据计算相边界的组成，需要应用相图知识和数值计算，答案是一个具体的数值结果（90 wt% A-10 wt% B），属于典型的计算题特征。 | 知识层次: 题目需要多步计算和综合分析，涉及相图的理解和相边界成分的确定，需要将质量分数与相图知识关联起来进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、质量分数计算，并进行多步推导和综合分析。虽然不涉及复杂多变量计算，但需要将多个知识点关联应用，解题步骤较为复杂。" + }, + { + "idx": 4314, + "question": "A hypothetical A-B alloy of composition 55 wt% B-45 wt% A at some temperature is found to consist of mass fractions of 0.5 for both \\alpha and \\beta phases. If the composition of the \\beta phase is 90 wt% \\mathrm{~B}-10 wt% \\mathrm{~A}, what is the composition of the \\alpha phase?", + "answer": "the composition of the \\alpha phase is 20 \\text{ wt}% \\text{ b- } 80 \\text{ wt}% \\text{ a}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解α相的组成，答案是一个具体的数值结果，而不是选择、判断或文字解释。 | 知识层次: 题目需要进行多步计算，涉及杠杆定律的应用和相图的理解，需要将多个概念关联起来进行综合分析。虽然不涉及复杂的推理或创新应用，但比简单的直接套用公式要复杂一些。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆法则进行多步计算，涉及质量分数和相组成的综合分析。虽然计算步骤明确，但需要正确理解和关联多个概念，如相图、质量平衡和成分计算，属于中等应用层次。" + }, + { + "idx": 4315, + "question": "For 11.20 kg of a magnesium-lead alloy of composition 30 wt% Pb-70 wt% Mg, is it possible, at equilibrium, to have α and Mg2Pb phases having respective masses of 7.39 kg and 3.81 kg?", + "answer": "yes, it is possible to have a 30 wt% pb-70 wt% mg alloy with masses of 7.39 kg and 3.81 kg for the α and mg2pb phases, respectively.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断在特定条件下是否可能达到某种相的质量分配，答案直接给出了\"yes\"或\"no\"的判断，符合判断题的特征。 | 知识层次: 题目需要应用相图知识进行多步计算，包括质量平衡和相组成分析，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在判断题中属于较高难度，需要综合分析相图数据并进行多步计算验证。题目要求判断特定成分合金在平衡状态下能否存在指定质量的相，这涉及：" + }, + { + "idx": 4316, + "question": "What will be the approximate temperature of the alloy?", + "answer": "the approximate temperature of the alloy is 190 degrees c.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程，符合简答题的特征。 | 知识层次: 题目仅需要简单的温度数值回答，不涉及多步计算或综合分析，属于基本信息的直接应用。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目仅要求给出合金的近似温度，答案直接提供了具体数值（190摄氏度），没有涉及复杂的解释或论述过程。解题步骤简单，仅需基本温度概念的理解和简单数值应用，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 4317, + "question": "Briefly describe the phenomenon of coring and why it occurs.", + "answer": "Coring is the phenomenon whereby concentration gradients exist across grains in polycrystalline alloys, with higher concentrations of the component having the lower melting temperature at the grain boundaries. It occurs, during solidification, as a consequence of cooling rates that are too rapid to allow for the maintenance of the equilibrium composition of the solid phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述\"coring\"现象及其原因，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目不仅要求解释\"coring\"现象的定义（基础概念），还需要理解其形成原因（冷却速率与平衡组成的关系），这涉及到对凝固过程中非平衡条件的分析和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并解释\"coring\"现象及其产生原因。题目要求考生掌握合金凝固过程中的非平衡现象，并能将凝固速率与成分偏析联系起来进行综合分析。虽然涉及多个概念，但不需要进行多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 4318, + "question": "Cite one undesirable consequence of coring.", + "answer": "One undesirable consequence of a cored structure is that, upon heating, the grain boundary regions will melt first and at a temperature below the equilibrium phase boundary from the phase diagram; this melting results in a loss in mechanical integrity of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述一个具体现象（coring的不良后果），答案提供了详细的文字描述而非选择、判断或计算。 | 知识层次: 题目要求解释coring现象的一个不良后果，并涉及加热过程中晶界区域的熔化行为及其对合金机械性能的影响。这需要综合运用相图知识、材料微观结构变化的理解以及机械性能变化的机理分析，属于较为复杂的分析和解释过程。 | 难度: 在简答题题型中，该题目要求对coring现象的不良后果进行机理深度解释，需要综合运用相图知识和材料热力学原理，分析晶界区域先熔化的原因及其对机械性能的影响。虽然不涉及多因素交互作用的全面分析，但对单一机理的解释深度已达到等级4的要求。" + }, + { + "idx": 4319, + "question": "Briefly explain why, upon solidification, an alloy of eutectic composition forms a microstructure consisting of alternating layers of the two solid phases.", + "answer": "Upon solidification, an alloy of eutectic composition forms a microstructure consisting of alternating layers\nof the two solid phases because during the solidification atomic diffusion must occur, and with this layered configuration the diffusion path length for the atoms is a minimum.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释合金在凝固时形成交替层状微观结构的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释共晶合金凝固时形成交替层状微观结构的机理，涉及原子扩散路径最小化的原理分析，需要综合运用相变和扩散知识进行推理和机理解释，属于较高层次的综合分析能力。 | 难度: 在简答题的复杂分析题型中，该题目要求对共晶合金凝固过程中的原子扩散和微观结构形成机理进行深度解释。虽然不涉及多步骤的复杂现象全面分析（等级5），但需要综合运用扩散理论和相变知识，解释层状结构的形成原因，属于机理深度解释的范畴。" + }, + { + "idx": 4320, + "question": "What is the difference between a phase and a microconstituent?", + "answer": "A \"phase\" is a homogeneous portion of the system having uniform physical and chemical characteristics, whereas a \"microconstituent\" is an identifiable element of the microstructure (that may consist of more than one phase).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念的区别，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对\"phase\"和\"microconstituent\"这两个基本概念的定义和区别的记忆和理解，属于材料科学中最基础的概念性知识。 | 难度: 在简答题题型中，该题目要求对\"phase\"和\"microconstituent\"两个基础概念进行解释和区分，属于概念解释和描述的难度级别。虽然需要理解两个术语的定义并能进行对比，但不需要深入分析复杂的概念体系或进行多层次的论述，因此属于中等难度（等级2）。" + }, + { + "idx": 4321, + "question": "Two intermetallic compounds, A B and A B_{2}, exist for elements A and B. If the compositions for A B and A B_{2} are 34.3 wt% \\mathrm{~A}-65.7 wt% \\mathrm{~B} and 20.7 wt% \\mathrm{~A}-79.3 wt% \\mathrm{~B}, respectively, and element A is potassium, identify element B.", + "answer": "element b is arsenic (as), with an atomic weight of 74.92 \\, \\text{g/mol} . the two intermetallic compounds are \\text{kas} and \\text{kas}_2 .", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算和推理确定元素B的身份，并给出具体的答案（砷），这需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要将给定的重量百分比转换为原子百分比，并利用元素A（钾）的已知原子量来推断元素B的原子量。这涉及到多步计算和概念关联，包括理解重量百分比和原子百分比之间的关系，以及如何利用这些信息来识别未知元素。虽然不需要复杂的推理或机理解释，但需要一定的综合分析能力来解决问题。 | 难度: 在简答题中属于较高难度，需要综合运用多步计算、概念关联和综合分析能力。题目要求根据给定的重量百分比和已知元素A（钾）的信息，推导出元素B的化学式。这涉及到原子量的计算、化学计量关系的理解以及元素性质的关联分析。解题步骤较为复杂，需要学生具备扎实的化学基础和逻辑推理能力。" + }, + { + "idx": 4322, + "question": "What is the principal difference between congruent and incongruent phase transformations?", + "answer": "The principal difference between congruent and incongruent phase transformations is that for congruent no compositional changes occur with any of the phases that are involved in the transformation. For incongruent there will be compositional alterations of the phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对概念进行解释和论述，答案以文字形式详细说明了两者的区别，符合简答题的特征。 | 知识层次: 题目考查对相变类型的基本概念记忆和理解，仅需区分共格和非共格相变的定义特征，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要区分两种相变类型并说明其差异，但仅涉及基础概念的记忆和简单对比，不需要深入分析或构建复杂概念体系。解题步骤仅需明确两种相变的定义特征，属于该题型中中等偏基础的认知要求。" + }, + { + "idx": 4323, + "question": "Compute the mass fraction of α ferrite in pearlite.", + "answer": "the mass fraction of α ferrite in pearlite is 0.89.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算α铁素体在珠光体中的质量分数），并且答案是一个具体的数值结果（0.89），这表明解答过程需要应用相关的公式和计算步骤。 | 知识层次: 题目要求计算珠光体中α铁素体的质量分数，这需要应用基本的相图知识和简单的质量分数计算公式。虽然涉及相图的概念，但计算过程直接且无需多步推理或综合分析，属于基本公式的直接应用。 | 难度: 在计算题中属于最低难度，仅需直接应用单一公式（杠杆定律）计算α铁素体在珠光体中的质量分数，无需复杂推导或多步骤计算。" + }, + { + "idx": 4324, + "question": "Compute the mass fraction of cementite in pearlite.", + "answer": "the mass fraction of cementite in pearlite is 0.11.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算珠光体中渗碳体的质量分数，需要通过数值计算和公式应用来得出具体数值（0.11），属于典型的计算题。 | 知识层次: 题目需要应用基本公式进行简单计算，涉及铁碳相图中珠光体和渗碳体的质量分数计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（杠杆定律）计算珠光体中渗碳体的质量分数，无需多步骤推导或复杂公式组合。" + }, + { + "idx": 4325, + "question": "What is the distinction between hypoeutectoid and hypereutectoid steels?", + "answer": "A \"hypoeutectoid\" steel has a carbon concentration less than the eutectoid; on the other hand, a \"hypereutectoid\" steel has a carbon content greater than the eutectoid.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释hypoeutectoid和hypereutectoid steels的区别，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对hypoeutectoid和hypereutectoid steels的基本定义和分类的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答基本定义和分类，属于最基础的概念记忆层次。题目明确要求区分hypoeutectoid和hypereutectoid steels的定义，答案直接对应教材中的基础概念，不需要额外的解释或复杂推理。这符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4326, + "question": "In a hypoeutectoid steel, both eutectoid and proeutectoid ferrite exist. Explain the difference between them. What will be the carbon concentration in each?", + "answer": "For a hypoeutectoid steel, the proeutectoid ferrite is a microconstituent that formed above the eutectoid temperature. The eutectoid ferrite is one of the constituents of pearlite that formed at a temperature below the eutectoid. The carbon concentration for both ferrites is 0.022 wt% C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种铁素体的区别并说明各自的碳浓度，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释两种铁素体的区别及其碳浓度，涉及对相变过程的理解和相图知识的应用，需要将基础概念与实际材料行为关联起来进行分析。虽然不涉及复杂计算，但需要综合理解相变温度和成分的关系，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并区分两种铁素体的形成条件和碳浓度，并进行综合分析说明。虽然涉及多个概念，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 4327, + "question": "What is the carbon concentration of an iron-carbon alloy for which the fraction of total ferrite is 0.94 ?", + "answer": "the carbon concentration of the iron-carbon alloy is 0.42 \\text{ wt% c}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算铁碳合金的碳浓度，需要通过公式和数值计算得出具体数值（0.42 wt% c），属于典型的计算题类型。 | 知识层次: 题目需要应用铁碳合金相图的知识，通过给定的铁素体分数来计算碳浓度。这涉及多步计算和概念关联，需要理解相图中各相的比例关系，并进行相应的数值计算。虽然不涉及复杂的推理或综合分析，但比简单的公式应用要求更高。 | 难度: 在计算题中属于多步骤计算过程难度。题目需要应用铁碳相图的相关知识，通过已知的相分数反推碳浓度，涉及公式应用和数值计算，但步骤较为直接，不需要处理复杂多变量或进行高度综合分析。" + }, + { + "idx": 4328, + "question": "What is the proeutectoid phase for an iron-carbon alloy in which the mass fractions of total ferrite and total cementite are 0.92 and 0.08 , respectively? Why?", + "answer": "the proeutectoid phase is \\alpha ferrite because the alloy composition c_{0} is less than 0.76 wt% C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么铁碳合金中的先共析相是α铁素体，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的质量分数计算合金成分，并判断其先共析相。这涉及多步计算和概念关联，需要综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及多步计算和概念关联（如质量分数计算、相图分析、共析点判断等），但解题路径相对明确：首先通过质量分数计算合金成分，再根据铁碳相图判断先共析相。题目要求综合分析能力，但不需要多角度或深度关联性分析（如不需要讨论温度影响或与其他合金体系对比），符合等级3\"综合分析和说明\"的标准。" + }, + { + "idx": 4329, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). What is the proeutectoid phase?", + "answer": "the proeutectoid phase is fe3c.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定先共析相（proeutectoid phase），答案是一个具体的相名称（Fe3C），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目需要理解相图的基本概念，并能够根据给定的碳含量和温度条件，确定先共析相。这涉及到对铁碳相图的理解和应用，需要一定的综合分析能力，但不需要复杂的推理或创新思维。 | 难度: 在简答题中属于中等难度，需要理解相图、碳含量计算和相变过程，并进行综合分析。虽然涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4330, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). How many kilograms each of total ferrite and cementite form?", + "answer": "the total ferrite formed is 0.83 kg, and the total cementite formed is 0.17 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铁素体和渗碳体的质量），并应用相关的材料科学公式和相图知识。答案以具体的数值结果呈现，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用相图知识（如铁碳相图）和杠杆法则进行计算，同时需要理解奥氏体、铁素体和渗碳体的形成条件及其相互关系。虽然计算过程相对直接，但需要综合运用多个知识点，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用相图知识、质量守恒原理和多步计算。虽然计算步骤明确（如利用杠杆定律），但要求对铁碳相图和相变概念有清晰理解，并正确关联多个知识点才能得出结果。相比简单单步计算题（等级2）更复杂，但尚未达到涉及多变量或非线性关系的等级4难度。" + }, + { + "idx": 4331, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). How many kilograms each of pearlite and the proeutectoid phase form?", + "answer": "the pearlite formed is 0.93 kg, and the proeutectoid phase (cementite) formed is 0.07 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算珠光体和先共析相的重量），并应用材料科学中的相变和成分计算知识。答案以具体数值形式给出，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、杠杆定律的应用以及不同相的形成条件，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析碳含量与相变产物的关系。虽然计算步骤明确，但涉及多个概念关联和数值转换，属于中等应用层次中的典型问题。" + }, + { + "idx": 4332, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). What is the proeutectoid phase?", + "answer": "ferrite is the proeutectoid phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定先共析相（proeutectoid phase），而不是从多个选项中选择、判断对错或进行数值计算。答案“ferrite is the proeutectoid phase”是一个简短的文字回答，符合简答题的特征。 | 知识层次: 题目需要理解相图知识，分析碳含量与共析点关系，并判断先共析相，涉及多步概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解相图概念、计算碳含量并确定相变产物，涉及多步分析和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4333, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). How many kilograms each of total ferrite and cementite form?", + "answer": "the total ferrite formed is 2.27 kg, and the total cementite formed is 0.23 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用材料科学中的相变知识，通过公式和计算得出具体的千克数结果。答案也是具体的数值，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及铁碳相图的应用和成分转换，需要理解相图中不同相的比例计算，并运用杠杆定律进行计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用基础概念和公式进行中等难度的应用计算。 | 难度: 在计算题中属于综合性计算问题，需要应用相图知识、质量守恒原理和多步计算。虽然涉及多个步骤，但变量和条件相对明确，没有过于复杂的多变量交互，因此属于等级3的综合性计算问题。" + }, + { + "idx": 4334, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). How many kilograms each of pearlite and the proeutectoid phase form?", + "answer": "the pearlite formed is 2.12 kg, and the proeutectoid ferrite formed is 0.38 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定珠光体和先共析相的重量，需要应用材料科学中的相变和成分计算知识，最终答案以具体数值形式呈现。 | 知识层次: 题目需要进行多步计算，包括应用相图知识确定相组成比例，以及质量守恒计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用相图知识和基本公式进行数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆法则进行多步计算，涉及相图分析和成分转换，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4335, + "question": "Compute the mass fraction of proeutectoid ferrite that forms in an iron-carbon alloy containing 0.25 wt% C.", + "answer": "the mass fraction of proeutectoid ferrite is 0.69.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铁碳合金中先共析铁素体的质量分数，需要通过数值计算和公式应用来得出具体数值（0.69），属于典型的计算题类型。 | 知识层次: 题目涉及基本的铁碳合金相图知识，需要应用杠杆定律进行单步计算，属于基本公式的直接应用，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用铁碳相图中的杠杆法则来计算先共析铁素体的质量分数，无需多个公式组合或复杂步骤。" + }, + { + "idx": 4336, + "question": "Compute the mass fraction of pearlite that forms in an iron-carbon alloy containing 0.25 wt% C.", + "answer": "the mass fraction of pearlite is 0.31.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算珠光体的质量分数），答案是一个具体的数值结果（0.31），这符合计算题的特征。 | 知识层次: 题目涉及基本的铁碳合金相图知识，需要应用杠杆定律进行简单的质量分数计算，属于直接套用基本公式的范畴，不需要多步计算或复杂分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用杠杆法则（lever rule）这一基本公式，通过给定的碳含量（0.25 wt% C）直接计算出珠光体的质量分数。解题步骤简单，无需多个公式组合或复杂计算，属于该题型内最基础的难度水平。" + }, + { + "idx": 4337, + "question": "The microstructure of an iron-carbon alloy consists of proeutectoid ferrite and pearlite; the mass fractions of these two microconstituents are 0.286 and 0.714 , respectively. Determine the concentration of carbon in this alloy.\n\\[\n\\text {", + "answer": "0.55% \\text{c}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定碳的浓度，答案是一个具体的数值（0.55%），解答过程涉及质量分数和相图计算。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的质量分数计算碳的浓度。这涉及到多步计算和概念关联，包括理解先共析铁素体和珠光体的定义及其在相图中的位置，以及利用杠杆定律进行计算。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆法则和铁碳相图知识进行多步计算，涉及质量分数转换和相图定位，但计算过程相对直接，不涉及复杂变量或高级数学工具。" + }, + { + "idx": 4338, + "question": "The mass fractions of total ferrite and total cementite in an iron-carbon alloy are 0.88 and 0.12 , respectively. Is this a hypoeutectoid or hypereutectoid alloy? Why?", + "answer": "the alloy is hypereutectoid since c_0 is greater than 0.76 \\, \\text{wt% c}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么该合金是亚共析或过共析合金，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的质量分数计算碳含量，并与共析点进行比较，判断合金类型。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要计算和综合分析，但解题步骤相对直接，主要涉及铁碳合金相图的基本概念和简单计算。题目要求判断合金类型并解释原因，这需要理解共析点附近的组成关系，但不需要深入的多角度分析或复杂的关联性推理。因此，在简答题题型中属于等级3的综合分析和说明难度。" + }, + { + "idx": 4339, + "question": "The microstructure of an iron-carbon alloy consists of proeutectoid ferrite and pearlite; the mass fractions of these microconstituents are 0.20 and 0.80 , respectively. Determine the concentration of carbon in this alloy.", + "answer": "the concentration of carbon in this alloy is 0.61% \\text{c}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定铁碳合金中的碳浓度，需要应用相关的公式和数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用铁碳相图的知识，通过多步计算（利用杠杆定律计算共析点前后的碳含量）来确定合金的碳浓度。这涉及到概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解铁碳合金相图、计算质量分数、应用杠杆定律等多步骤计算过程，并综合分析微结构组成与碳浓度的关系。虽然涉及多个概念和计算步骤，但并未达到复杂多变量计算的难度。" + }, + { + "idx": 4340, + "question": "Consider 2.0 kg of a 99.6 wt % Fe-0.4 wt % C alloy that is cooled to a temperature just below the eutectoid. How many kilograms of proeutectoid ferrite form?", + "answer": "0.98 kg of proeutectoid ferrite forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定条件下形成的proeutectoid ferrite的质量。答案是一个具体的数值（0.98 kg），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要多步计算和概念关联，包括理解相图、计算相组成以及应用杠杆定律，涉及中等程度的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆法则进行多步计算，并综合分析合金成分与冷却过程对组织形成的影响。虽然计算步骤明确，但涉及多个概念关联和综合运用，属于中等偏上的难度。" + }, + { + "idx": 4342, + "question": "Consider 2.0 kg of a 99.6 wt % Fe-0.4 wt % C alloy that is cooled to a temperature just below the eutectoid. How many kilograms of cementite form?", + "answer": "0.114 kg of cementite forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及合金成分和相变过程的具体计算，最终答案是一个具体的数值结果（0.114 kg of cementite forms）。 | 知识层次: 题目涉及多步计算和概念关联，需要理解合金的组成、相图分析以及质量平衡计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析合金成分与相变过程的关系。虽然不涉及复杂变量，但步骤和概念关联性较强。" + }, + { + "idx": 4343, + "question": "Compute the maximum mass fraction of proeutectoid cementite possible for a hypereutectoid ironcarbon alloy.", + "answer": "the maximum mass fraction of proeutectoid cementite possible for a hypereutectoid iron-carbon alloy is 0.232.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算过共析铁碳合金中可能的最大先共析渗碳体质量分数，需要通过数值计算和公式应用来得出具体数值（0.232）。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算来确定先共晶渗碳体的最大质量分数。这涉及到对相图的理解、成分计算和公式应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析合金成分与相变关系。虽然计算步骤明确，但涉及多个概念关联和临界点判断，属于中等偏上的复杂度。" + }, + { + "idx": 4344, + "question": "Is it possible to have an iron-carbon alloy for which the mass fractions of total ferrite and proeutectoid cementite are 0.846 and 0.049 , respectively? Why or why not?", + "answer": "yes, it is possible to have an iron-carbon alloy with mass fractions of total ferrite w_{\\alpha}=0.846 and proeutectoid cementite w_{\\mathrm{fe}_{3} C^{\\prime}}=0.049. the alloy composition for both conditions is 1.05 wt% C. since the composition values are equal, such an alloy exists.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释是否可能拥有特定质量分数的铁碳合金，并需要文字论述原因。答案提供了详细的解释和论证，符合简答题的特征。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算和综合分析，以确定合金成分是否满足给定的质量分数条件。这涉及到对相图的理解、杠杆定律的应用以及成分的验证，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解铁碳合金相图的基本概念，进行多步计算以确定合金成分，并综合分析两种相的质量分数是否对应同一合金成分。虽然涉及多个步骤和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4345, + "question": "Is it possible to have an iron-carbon alloy for which the mass fractions of total cementite and pearlite are 0.039 and 0.417 , respectively? Why or why not?", + "answer": "no, such an iron-carbon alloy is not possible because the required carbon compositions for the given mass fractions of total cementite (0.28 wt% C) and pearlite (0.33 wt% C) are different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么不可能存在具有特定质量分数的铁碳合金，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用铁碳合金相图的知识，进行多步计算和概念关联，判断给定的质量分数是否可能。这涉及到对相图中不同相的质量分数计算和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目属于较高难度。首先需要理解铁碳合金相图中渗碳体和珠光体的定义及其质量分数关系；其次需要进行多步计算，包括根据给定质量分数反推碳含量；最后还需要综合分析计算结果并给出合理解释。这需要学生将相图知识、杠杆定律计算和逻辑推理能力有机结合，属于多角度分析论述的典型题目。" + }, + { + "idx": 4346, + "question": "Compute the mass fraction of eutectoid ferrite in an iron-carbon alloy that contains 0.43 wt% C.", + "answer": "the mass fraction of eutectoid ferrite in the iron-carbon alloy is 0.493.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算（使用铁碳相图和杠杆定律）来确定共析铁素体的质量分数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图的知识，理解共析反应的概念，并进行多步计算来求解共析铁素体的质量分数。这涉及到对相图的理解、成分与相组成关系的分析，以及具体的数值计算，属于中等应用层次。 | 难度: 在计算题中属于多步骤计算过程，需要应用杠杆定律和相图知识，但计算步骤相对明确，不涉及复杂多变量或高度综合的分析。" + }, + { + "idx": 4347, + "question": "Is it possible to determine the composition of an iron-carbon alloy if the mass fraction of eutectoid cementite is 0.104?", + "answer": "yes, it is possible to determine the alloy composition, and there are two possible answers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述如何通过给定的质量分数确定铁碳合金的组成，答案提供了文字解释和可能的两种情况，符合简答题的特征。 | 知识层次: 题目需要应用铁碳相图的基本原理，进行多步计算和概念关联，以确定合金的组成。虽然不涉及复杂的推理分析或机理解释，但需要综合运用相图知识和质量分数计算，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。首先需要理解并应用铁碳相图的相关知识，特别是关于共析反应和渗碳体的计算。其次，需要进行多步计算来确定合金的组成，并理解为什么会有两种可能的答案（亚共析和过共析钢）。此外，还需要综合分析相图中的不同区域和相变过程，将理论知识与具体问题相结合。这些要求使得该题目在同题型中属于需要多角度分析论述的难度等级。" + }, + { + "idx": 4348, + "question": "What is the composition of the alloy if eutectoid cementite exists in addition to proeutectoid cementite?", + "answer": "the alloy composition is 1.11 wt% c.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金的组成情况，并给出具体的成分数值，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解共析渗碳体和先共析渗碳体的概念，并进行多步计算和综合分析来确定合金成分。这涉及到对相图的理解和应用，以及相关概念之间的关联。 | 难度: 在简答题中属于较高难度，需要理解并区分eutectoid cementite和proeutectoid cementite的概念，掌握相图分析能力，进行多步计算（包括杠杆定律应用），并综合论述合金成分与显微组织的关系。这超出了基础概念复述的难度（等级3），但尚未达到需要深度关联多个知识体系的最高难度（等级5）。" + }, + { + "idx": 4349, + "question": "What is the composition of a hypoeutectoid alloy where all cementite is eutectoid cementite and the mass fraction of total cementite is 0.104?", + "answer": "the composition can be determined using the lever rule.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过杠杆定律计算亚共析合金的成分，需要数值计算和公式应用。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及共析渗碳体和总渗碳体质量分数的概念关联，需要综合分析合金成分的计算过程。 | 难度: 在计算题中属于综合性计算问题，需要应用杠杆法则进行多步计算，并理解共析渗碳体和总渗碳体的质量分数概念。虽然不涉及复杂多变量计算，但需要综合分析合金成分与相图的关系，属于中等应用层次的计算题。" + }, + { + "idx": 4350, + "question": "Is it possible to determine the composition of an iron-carbon alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "yes, it is possible to determine the alloy composition; and, in fact, there are two possible answers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释是否可能确定铁碳合金的成分，并需要文字解释和论述，答案也提供了详细的解释和可能的两种情况，符合简答题的特征。 | 知识层次: 题目需要理解共析铁素体的质量分数与合金成分之间的关系，并进行多步计算和综合分析。虽然不涉及复杂的机理或创新应用，但需要将概念关联并进行一定的推理分析。 | 难度: 在简答题题型中，该题目属于较高难度。首先，它要求考生理解铁碳合金相图的基本概念，特别是共析反应和共析铁素体的定义。其次，题目涉及质量分数的计算，需要考生能够将相图中的杠杆法则应用到具体问题中。此外，题目还暗示存在两个可能的合金成分，这要求考生能够从相图的两个不同区域（亚共析和过共析）来考虑问题，进行综合分析。这种多角度分析和多步计算的要求使得该题目在同题型中难度较高。" + }, + { + "idx": 4351, + "question": "What is the first possible composition of the alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "for the first case, the composition is c0 = 0.70 wt % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金的组成，涉及质量分数和成分的计算，答案给出了具体的数值结果（0.70 wt % c），表明需要通过计算得出答案。 | 知识层次: 题目涉及多步计算和概念关联，需要理解共析铁素体的质量分数与合金成分之间的关系，并进行相应的数值计算。这超出了简单公式应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要理解合金相图、质量分数计算以及多步公式推导。题目要求根据给定的质量分数反推合金成分，涉及多个概念关联和综合分析步骤，但尚未达到复杂多变量计算的程度。" + }, + { + "idx": 4352, + "question": "What is the second possible composition of the alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "for the second case, the composition is c0 = 1.22 wt % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金的第二种可能组成，答案给出了具体的数值结果（1.22 wt % c），这表明需要通过数值计算和公式应用来解答。 | 知识层次: 题目需要多步计算和概念关联，涉及合金成分的计算和相图的理解，需要综合分析质量分数和相图信息来确定合金的组成。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念、应用杠杆定律进行多步计算，并综合分析不同成分条件下的相组成关系。虽然不涉及复杂多变量计算，但解题过程需要将多个知识点关联运用，属于中等偏上的难度水平。" + }, + { + "idx": 4353, + "question": "What is the first stage involved in the formation of particles of a new phase? Briefly describe it.", + "answer": "The first stage is nucleation. The nucleation process involves the formation of normally very small particles of the new phase(s) which are stable and capable of continued growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述新相粒子形成的第一阶段，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即成核过程的定义和简要描述，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对\"成核\"这一基础概念进行解释和描述，不仅需要记忆定义，还需要简要说明其过程。这属于概念解释和描述的难度层级，比单纯回答基本定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。题目在简答题框架内属于中等难度，符合等级2的标准。" + }, + { + "idx": 4354, + "question": "What is the second stage involved in the formation of particles of a new phase? Briefly describe it.", + "answer": "The second stage is growth. The growth stage is simply the increase in size of the new phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述新相粒子形成的第二阶段，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查新相粒子形成过程中第二阶段的基本概念记忆和理解，即生长阶段的定义和简单描述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义和简单描述，属于最基础的记忆性知识。题目明确指向\"第二阶段\"的定义和简要说明，不需要深入解释或复杂概念体系的阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4355, + "question": "If copper (which has a melting point of 1085^{\\circ} C ) homogeneously nucleates at 849^{\\circ} C, calculate the critical radius given values of -1.77 × 10^{9} J/ m^{3} and 0.200 J/ m^{2}, respectively, for the latent heat of fusion and the surface free energy.", + "answer": "1.30 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数（熔点、潜热、表面自由能）和公式计算临界半径，最终需要得出一个具体的数值结果（1.30 nm）。这符合计算题的特征，即需要数值计算和公式应用。 | 知识层次: 题目需要应用临界半径计算公式，涉及多步计算和概念关联（如熔化潜热、表面自由能等），但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用临界半径公式（涉及表面自由能、过冷度、潜热等多变量关系），进行多步骤单位换算和数值计算，但变量关系明确且无复杂推导过程。相比简单代入计算（等级2）更综合，但未达到复杂多变量交互影响（等级4）的程度。" + }, + { + "idx": 4356, + "question": "The kinetics of the austenite-to-pearlite transformation obey the Avrami relationship. Using the fraction transformed-time data given here, determine the total time required for 95% of the austenite to transform to pearlite:\n\\begin{tabular}{cc}\n\\hline Fraction Transformed & Time (s) \\\\\n\\hline 0.2 & 12.6 \\\\\n0.8 & 28.2 \\\\\n\\hline\n\\end{tabular}", + "answer": "35.7(s)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据应用Avrami关系式进行数值计算，最终得出具体的时间数值（35.7秒），这符合计算题的特征。 | 知识层次: 题目需要应用Avrami关系进行多步计算，涉及数据分析和公式推导，要求将给定的分数转换-时间数据关联起来，并通过计算确定95%转换所需的总时间。这超出了简单应用的范围，需要中等程度的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用Avrami关系式进行多步计算，包括数据拟合、参数求解和最终时间预测。虽然计算步骤明确，但涉及概念关联和综合分析，属于中等应用层次的计算题。" + }, + { + "idx": 4357, + "question": "The fraction recrystallized-time data for the recrystallization at 600^{\\circ} C of a previously deformed steel are tabulated here. Assuming that the kinetics of this process obey the Avrami relationship, determine the fraction recrystallized after a total time of 22.8min.\n\\begin{tabular}{cc}\n\\hline \\begin{tabular}{c} \nFraction \\\\\nRecrystallized\n\\end{tabular} & Time (min) \\\\\n\\hline 0.20 & 13.1 \\\\\n0.70 & 29.1 \\\\\n\\hline\n\\end{tabular}", + "answer": "0.51", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和Avrami关系进行数值计算，最终得出一个具体的数值结果（0.51），这符合计算题的特征。 | 知识层次: 题目需要应用Avrami关系进行多步计算，涉及数据拟合和公式推导，属于中等应用层次。虽然不涉及复杂的机理分析或创新设计，但需要综合运用数学计算和材料科学知识来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要应用Avrami关系式进行多步计算，包括对数变换、线性拟合和参数求解等步骤。虽然题目提供了部分数据，但需要学生理解动力学模型并正确推导出时间与再结晶分数的关系，属于中等偏上的复杂度。" + }, + { + "idx": 4358, + "question": "In terms of heat treatment and the development of microstructure, what is one major limitation of the iron-iron carbide phase diagram related to nonequilibrium phases?", + "answer": "The nonequilibrium martensite does not appear on the diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铁-碳相图的一个主要局限性，并涉及非平衡相的形成，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求理解铁-碳相图的基本原理，并能够分析其在实际热处理过程中的局限性，特别是关于非平衡相（如马氏体）的缺失。这需要将相图知识与实际热处理过程联系起来，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解铁-铁碳相图的基本概念，并能够分析其局限性。题目要求解释非平衡相（如马氏体）在相图中的缺失，这需要对相图的平衡条件和非平衡相变有基本的理解。虽然涉及概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4359, + "question": "In terms of heat treatment and the development of microstructure, what is one major limitation of the iron-iron carbide phase diagram related to time-temperature relationships?", + "answer": "The diagram provides no indication as to the time-temperature relationships for the formation of pearlite, bainite, and spheroidite, all of which are composed of the equilibrium ferrite and cementite phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释铁-碳相图在热处理和微观结构发展中的一个主要局限性，答案需要文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目要求考生理解铁-碳相图的基本概念，并能够分析其在热处理和微观结构发展中的局限性，特别是关于时间-温度关系的缺失。这需要考生将相图知识与实际应用中的时间-温度关系联系起来，进行一定的综合分析，而不仅仅是记忆或简单应用。 | 难度: 在简答题题型中，该题目要求考生不仅理解铁-碳相图的基本概念，还需要综合分析其局限性，特别是关于时间-温度关系的缺失。这涉及到对相变动力学（如珠光体、贝氏体和球化体的形成）的理解，并需要将这些概念与相图的静态特性进行对比。虽然不需要进行多角度或深度关联性分析，但要求考生能够清晰地论述一个主要局限性，并解释其影响，这在该题型内属于较高难度的要求。" + }, + { + "idx": 4360, + "question": "Briefly describe the phenomena of superheating and supercooling.", + "answer": "Superheating and supercooling correspond, respectively, to heating or cooling above or below a phase transition temperature without the occurrence of the transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述过热和过冷现象，答案是通过文字解释和论述来回答的，没有涉及选择、判断或计算。 | 知识层次: 题目考查对超热和过冷现象的基本定义和概念的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求对超热和过冷现象进行基本定义简答，属于最基础的概念记忆层次。题目不涉及复杂解释或体系阐述，仅需直接回忆并复述定义即可完成作答，因此属于等级1难度。" + }, + { + "idx": 4361, + "question": "Why do these phenomena occur?", + "answer": "These phenomena occur because right at the phase transition temperature, the driving force is not sufficient to cause the transformation to occur. The driving force is enhanced during superheating or supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象发生的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释相变温度下驱动力的不足以及过热或过冷如何增强驱动力，这需要对相变机理有深入的理解和综合分析能力，涉及多个概念的关联和推理分析。 | 难度: 在简答题的复杂分析题型中，该题目要求对相变温度下的驱动力不足现象进行机理深度解释，涉及超加热和超冷却条件下驱动力增强的推理分析。虽然不需要全面分析复杂现象的所有方面，但需要对特定机理有较深入的理解和解释能力，属于该题型内较高难度的题目。" + }, + { + "idx": 4362, + "question": "Briefly cite the differences between pearlite, bainite, and spheroidite relative to microstructure.", + "answer": "The microstructures of pearlite, bainite, and spheroidite all consist of α-ferrite and cementite phases. For pearlite, the two phases exist as layers which alternate with one another. Bainite consists of very fine and parallel needle-shaped particles of cementite that are surrounded an α-ferrite matrix. For spheroidite, the matrix is ferrite, and the cementite phase is in the shape of sphere-shaped particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述珠光体、贝氏体和球化体在微观结构上的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对珠光体、贝氏体和球化体微观结构差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述珠光体、贝氏体和球化体在微观结构上的差异，涉及对三种组织的基本特征进行对比说明，但不需要深入分析形成机制或性能影响等复杂概念体系。回答时需要准确记忆并区分三种组织的相组成和形貌特征，属于基础概念记忆层次中的中等难度要求。" + }, + { + "idx": 4363, + "question": "Briefly cite the differences between pearlite, bainite, and spheroidite relative to mechanical properties.", + "answer": "Bainite is harder and stronger than pearlite, which, in turn, is harder and stronger than spheroidite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释pearlite、bainite和spheroidite在机械性能上的差异，答案以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目考查对珠光体、贝氏体和球化体机械性能差异的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要比较三种不同显微组织（珠光体、贝氏体和球化体）的机械性能差异，需要学生对这三种组织的基本特性有一定记忆和理解，并能进行简单的对比分析。虽然涉及多个概念，但不需要深入阐述复杂机制或相互关系，属于中等偏下的难度水平。" + }, + { + "idx": 4364, + "question": "What is the driving force for the formation of spheroidite?", + "answer": "The driving force for the formation of spheroidite is the net reduction in ferrite-cementite phase boundary area.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释spheroidite形成的驱动力，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对spheroidite形成驱动力的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释spheroidite形成的驱动力，涉及相边界面积减少的基本原理，但不需要复杂的体系阐述或多步骤推理。属于对基础概念的理解和表述要求。" + }, + { + "idx": 4365, + "question": "Name the microstructural products of eutectoid iron-carbon alloy (0.76 wt% C) specimens that are first completely transformed to austenite, then cooled to room temperature at a rate of 200°C/s.", + "answer": "At a rate of 200°C/s, only martensite forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述特定条件下（冷却速率200°C/s）的微观结构产物，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解铁碳合金相变的基本原理，并能够根据冷却速率判断微观结构的变化。这涉及到对连续冷却转变图（CCT图）的应用，以及对马氏体形成条件的理解。虽然不涉及复杂计算，但需要将多个概念关联起来进行综合分析。 | 难度: 在简答题中属于中等难度，需要理解铁碳合金相变的基本概念，并能将冷却速率与微观结构产物关联起来。题目要求分析特定冷却条件下的相变产物，涉及对CCT曲线的理解和应用，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4368, + "question": "What is one important difference between continuous cooling transformation diagrams for plain carbon and alloy steels regarding the presence of a bainite nose?", + "answer": "For an alloy steel, a bainite nose will be present, which nose will be absent for plain carbon alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释连续冷却转变图中普通碳钢和合金钢在贝氏体鼻部存在上的重要区别，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种钢的连续冷却转变图特征差异，涉及对相变曲线形态的理解和对比分析，需要将基础概念（CCT图、贝氏体鼻温）与实际材料特性（合金钢与碳钢的区别）进行关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解连续冷却转变图的基本概念，并能区分普通碳钢和合金钢在贝氏体鼻部存在性上的差异。虽然涉及多步概念关联，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 4369, + "question": "What is one important difference between continuous cooling transformation diagrams for plain carbon and alloy steels regarding the position of the pearlite-proeutectoid noses?", + "answer": "The pearlite-proeutectoid noses for plain carbon steel alloys are positioned at shorter times than for the alloy steels.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释连续冷却转变图中普通碳钢和合金钢珠光体-先共析鼻部位置的重要差异，答案需要文字描述和论述，而非选择、判断或计算。 | 知识层次: 题目要求比较两种不同钢种的连续冷却转变图中珠光体-先共析体鼻部位置的区别，需要理解并应用材料科学中关于相变和合金元素影响的知识，涉及多概念关联和综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及连续冷却转变图和珠光体-先共析体鼻点的位置差异，但只需要对普通碳钢和合金钢的特性进行综合分析和说明即可。不需要多角度分析或深度关联性分析，解题步骤相对直接，主要考察对材料科学基础概念的理解和应用能力。" + }, + { + "idx": 4370, + "question": "Briefly explain why there is no bainite transformation region on the continuous cooling transformation diagram for an iron-carbon alloy of eutectoid composition.", + "answer": "There is no bainite transformation region on the continuous cooling transformation diagram for an ironcarbon alloy of eutectoid composition because by the time a cooling curve has passed into the bainite region, the entirety of the alloy specimen will have transformed to pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释为什么在共析成分的铁碳合金的连续冷却转变图中没有贝氏体转变区，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释为什么在共析成分的铁碳合金连续冷却转变图中没有贝氏体转变区，这需要理解贝氏体转变的动力学和连续冷却过程中的相变竞争机制。涉及多个概念的关联和综合分析，包括贝氏体形成的温度范围、珠光体转变的动力学优势以及冷却速率对相变的影响。需要推理分析不同相变区域的相互作用，属于复杂分析层次。 | 难度: 在简答题中，该题目属于机理深度解释的难度等级。题目要求解释为什么在共析成分的铁碳合金连续冷却转变图中没有贝氏体转变区，这需要考生理解贝氏体转变的动力学条件以及连续冷却过程中珠光体转变的优先性。虽然题目涉及的知识点较为专业，但解释过程相对直接，不需要复杂的多步骤推理或跨领域知识整合，因此属于等级4而非等级5的复杂现象全面分析。" + }, + { + "idx": 4371, + "question": "Name the microstructural products of 4340 alloy steel specimens that are first completely transformed to austenite, then cooled to room temperature at a rate of 10°C/s.", + "answer": "only martensite forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述4340合金钢在特定冷却条件下的微观结构产物，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目要求将合金钢的冷却速率与微观结构产物相关联，需要理解4340合金钢的相变行为以及冷却速率对相变产物的影响。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求分析4340合金钢在特定冷却速率下的显微组织产物，需要理解连续冷却转变图（CCT图）和合金钢的相变行为。虽然题目给出了具体的冷却条件（10°C/s），但解答需要综合运用相变动力学知识，判断在该冷却速率下是否能够完全避免其他相（如贝氏体或珠光体）的形成。这要求学生对合金钢的相变有较好的理解，并能将理论知识与具体条件相结合，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4375, + "question": "On the basis of diffusion considerations, explain why fine pearlite forms for the moderate cooling of austenite through the eutectoid temperature, whereas coarse pearlite is the product for relatively slow cooling rates.", + "answer": "For moderately rapid cooling, the time allowed for carbon diffusion is not as great as for slower cooling rates. Therefore, the diffusion distance is shorter, and thinner layers of ferrite and cementite form (i.e., fine pearlite forms).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于扩散理论解释不同冷却速率下珠光体形成的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于扩散理论解释不同冷却速率下珠光体形貌差异的形成机理，需要综合运用扩散动力学、相变原理和显微组织形成机制等知识进行推理分析，思维过程涉及多因素关联和机理解释。 | 难度: 在简答题题型中，该题目要求对扩散机理进行深度解释，涉及碳扩散时间与冷却速率的关系，以及由此导致的珠光体组织粗细变化。虽然不需要全面分析复杂现象，但需要对扩散过程和组织形成机理有较深入的理解和论述，属于机理深度解释的难度等级。" + }, + { + "idx": 4376, + "question": "Briefly explain why fine pearlite is harder and stronger than coarse pearlite, which in turn is harder and stronger than spheroidite.", + "answer": "The hardness and strength of iron-carbon alloys that have microstructures consisting of \\alpha-ferrite and cementite phases depend on the boundary area between the two phases. The greater this area, the harder and stronger the alloy inasmuch as (1) these boundaries impede the motion of dislocations, and (2) the cementite phase restricts the deformation of the ferrite phase in regions adjacent to the phase boundaries. Fine pearlite is harder and stronger than coarse pearlite because the alternating ferrite-cementite layers are thinner for fine, and therefore, there is more phase boundary area. The phase boundary area between the sphere-like cementite particles and the ferrite matrix is less in spheroidite than for the alternating layered microstructure found in coarse pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释不同微观结构对硬度和强度的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释不同显微组织（细珠光体、粗珠光体和球化体）的硬度和强度差异，涉及相界面积对位错运动和变形限制的影响机制。这需要综合运用材料科学中的相变、位错理论和强化机制等知识，进行机理层面的分析和解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对铁碳合金中不同显微组织的硬度和强度差异进行机理深度解释。需要综合运用相界面积对位错运动的阻碍作用、渗碳体相限制铁素体相变形等知识，并比较珠光体、粗珠光体和球化体三种组织的层状结构差异。虽然不涉及多系统交互或动态过程分析，但需要清晰的因果链条和微观结构特征描述，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 4377, + "question": "Cite two reasons why martensite is so hard and brittle.", + "answer": "Two reasons why martensite is so hard and brittle are: (1) there are relatively few operable slip systems for the body-centered tetragonal crystal structure, and (2) virtually all of the carbon is in solid solution, which produces a solid-solution hardening effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举并解释马氏体硬而脆的两个原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释马氏体硬而脆的两个原因，涉及对体心四方晶体结构滑移系统和固溶强化效应的理解，需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解马氏体的晶体结构和固溶强化效应两个关键概念，并进行简要的关联分析。虽然不需要多角度或深度关联性分析，但要求对材料科学基础概念有一定掌握并能进行综合说明。" + }, + { + "idx": 4378, + "question": "Rank the following iron-carbon alloys and associated microstructures from the highest to the lowest tensile strength:\n(a) 0.25 wt% C with spheroidite,\n(b) 0.25 wt% C with coarse pearlite,\n(c) 0.60 wt% C with fine pearlite, and\n(d) 0.60 wt% C with coarse pearlit.", + "answer": "(c)(d)(b)(a)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项中选择正确的排序，答案是从多个选项中选择的特定顺序 | 知识层次: 题目要求对不同铁碳合金及其显微组织的抗拉强度进行排序，需要理解碳含量和显微组织（如珠光体和球化体）对材料性能的影响，并进行综合分析。这涉及多个知识点的关联和比较，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解铁碳合金的碳含量与微观结构对力学性能的影响，并比较不同组合的强度排序。解题过程涉及多个概念的关联分析（碳含量、珠光体粗细、球化体等）以及微观组织对性能影响的综合判断，属于复杂分析过程的判断题型。" + }, + { + "idx": 4379, + "question": "Briefly explain why the hardness of tempered martensite diminishes with tempering time at constant temperature.", + "answer": "The hardness of tempered martensite diminishes with tempering time at constant temperature because the microstructure consists of small sphere-like particles of cementite embedded within a ferrite matrix. As tempering time increases, the cementite particles grow, which reduces the ferrite-cementite phase boundary area. Since these phase boundaries act as barriers to dislocation motion, the reduction in phase boundary area leads to a decrease in hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释为什么回火马氏体的硬度会随着回火时间增加而降低，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释回火马氏体硬度随回火时间降低的微观机理，涉及相变、析出相生长、位错运动障碍等多重概念的综合分析和推理。需要深入理解微观结构演变与力学性能的关系，属于机理层面的复杂分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对回火马氏体硬度随回火时间变化的机理进行深度解释。需要综合运用相变理论、显微组织演变和位错运动机制等知识，分析渗碳体颗粒长大与相界面积减少对硬度的影响机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已经超出了基础概念解释的范畴，属于需要机理深度解释的等级4难度。" + }, + { + "idx": 4381, + "question": "Briefly describe the microstructural difference between spheroidite and tempered martensite.", + "answer": "Both tempered martensite and spheroidite have sphere-like cementite particles within a ferrite matrix; however, these particles are much larger for spheroidite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述两种微观结构的差异，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对spheroidite和tempered martensite两种微观结构的基本概念记忆和理解，属于基础概念层次的比较。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较两种微观结构的差异，但只需要简要描述其关键区别（球状渗碳体颗粒的大小差异），不需要深入分析形成机制或性能影响。这属于对基础概念的对比性描述，没有涉及复杂概念体系或多步骤推理过程。" + }, + { + "idx": 4382, + "question": "Explain why tempered martensite is much harder and stronger.", + "answer": "Tempered martensite is harder and stronger inasmuch as there is much more ferrite-cementite phase boundary area for the smaller particles; thus, there is greater reinforcement of the ferrite phase, and more phase boundary barriers to dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体更硬更强，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释回火马氏体硬度与强度的机理，涉及相界面对位错运动的阻碍作用等微观机制分析，需要综合运用材料科学中的相变、强化机制等知识进行推理和解释。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释回火马氏体为何更硬更强的机理，涉及相界面积、铁素体强化和位错运动障碍等复杂概念的综合运用。虽然不需要全面分析复杂现象，但需要对材料微观结构和性能关系有较深入的理解和解释能力，属于该题型中较高难度的题目。" + }, + { + "idx": 4383, + "question": "List the four classifications of steels.", + "answer": "Low Carbon Steels, Medium Carbon Steels, High Carbon Steels, High Alloy Steels (Stainless and Tool)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出钢材的四种分类，答案以文字形式给出，不需要选择或判断，也不需要计算。 | 知识层次: 题目考查对钢材分类的基本概念记忆，属于基础知识的直接回忆和列举 | 难度: 在简答题中属于基本难度，仅需记忆并列举钢材的四种分类，无需深入解释或复杂论述。题目要求的知识点掌握深度较浅，解题步骤简单，属于基础概念记忆的范畴。" + }, + { + "idx": 4384, + "question": "For Low Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: nonresponsive to heat treatments; relatively soft and weak; machinable and weldable. Typical applications: automobile bodies, structural shapes, pipelines, buildings, bridges, and tin cans.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述低碳钢的性质和典型应用，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对低碳钢的基本性质和典型应用的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述低碳钢的性质和典型应用，涉及对材料基本特性的记忆和典型应用场景的列举。虽然需要一定的知识掌握，但不需要深入分析或复杂的概念体系阐述，属于中等难度的简答题。" + }, + { + "idx": 4385, + "question": "For Medium Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: heat treatable, relatively large combinations of mechanical characteristics. Typical applications: railway wheels and tracks, gears, crankshafts, and machine parts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述中碳钢的性能和典型应用，答案以文字解释和论述的形式呈现，符合简答题的特征 | 知识层次: 题目考查对中碳钢的基本性质和典型应用的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述中碳钢的性能和典型应用，这需要学生对相关概念有一定的理解和记忆，但不需要深入分析或阐述复杂的理论体系。回答该题目需要掌握基础的材料科学知识，并能将这些知识组织成连贯的表述，属于中等难度的简答题。" + }, + { + "idx": 4386, + "question": "For High Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: hard, strong, and relatively brittle. Typical applications: chisels, hammers, knives, and hacksaw blades.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述高碳钢的性能和典型应用，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对高碳钢基本性质和典型应用的记忆和理解，属于基础概念层次的知识点。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述高碳钢的性能和典型应用，这需要学生对高碳钢的基本特性（如硬度、强度、脆性）和常见用途有一定的记忆和理解，但不需要进行复杂的体系阐述或多概念整合。属于基础概念记忆层次中的中等难度。" + }, + { + "idx": 4387, + "question": "For High Alloy Steels (Stainless and Tool), briefly describe the properties and typical applications.", + "answer": "Properties: hard and wear resistant; resistant to corrosion in a large variety of environments. Typical applications: cutting tools, drills, cutlery, food processing, and surgical tools.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述高合金钢（不锈钢和工具钢）的性能和典型应用，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求简要描述高合金钢（不锈钢和工具钢）的性质和典型应用，主要考查对基础概念的记忆和理解，不涉及复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求简要描述高合金钢（不锈钢和工具钢）的性能和典型应用，这需要考生不仅记忆相关的基本概念（如硬度、耐磨性、耐腐蚀性），还需要理解这些性能如何在实际应用中体现。虽然不需要复杂的论述或深入的分析，但要求考生能够将记忆的知识点进行适当的组织和解释，属于概念解释和描述的难度等级。" + }, + { + "idx": 4388, + "question": "Cite three reasons why ferrous alloys are used so extensively.", + "answer": "Ferrous alloys are used extensively because: (1) Iron ores exist in abundant quantities. (2) Economical extraction, refining, and fabrication techniques are available. (3) The alloys may be tailored to have a wide range of properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举三个原因，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对铁基合金广泛应用原因的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要列举三个原因，但每个原因都是基础概念的记忆性知识，不需要复杂的分析或推理。题目要求的知识点掌握深度适中，解题步骤相对简单，属于该题型内中等偏下的难度水平。" + }, + { + "idx": 4389, + "question": "Cite three characteristics of ferrous alloys that limit their utilization.", + "answer": "Disadvantages of ferrous alloys are: (1) They are susceptible to corrosion. (2) They have a relatively high density. (3) They have relatively low electrical conductivities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举铁基合金的三个限制其应用的特性，答案需要以文字形式进行解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举铁基合金的三个限制特性，属于对材料基本性质的理解和记忆，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举铁基合金的三个限制性特征，这需要学生对铁基合金的基本性质有一定了解，并能简要描述其缺点。虽然需要记忆多个知识点，但不需要深入分析或构建复杂的概念体系，因此属于中等难度。" + }, + { + "idx": 4390, + "question": "What is the function of alloying elements in tool steels?", + "answer": "The alloying elements in tool steels (e.g., \\mathrm{Cr}, V, \\mathrm{W}, and Mo) combine with the carbon to form very hard and wear-resistant carbide compounds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释合金元素在工具钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查合金元素在工具钢中的基本功能，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释合金元素在工具钢中的作用，需要考生理解并描述合金元素如何与碳结合形成硬质碳化物，但不需要深入阐述复杂的机理或多步骤的推理过程。这比基本定义简答（等级1）要求更高的理解深度，但尚未达到复杂概念体系阐述（等级3）的难度。" + }, + { + "idx": 4391, + "question": "On the basis of microstructure, briefly explain why gray iron is brittle and weak in tension.", + "answer": "Gray iron is weak and brittle in tension because the tips of the graphite flakes act as points of stress concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释灰口铸铁在拉伸条件下脆性和强度低的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于微观结构解释灰口铸铁的脆性和抗拉强度弱的原因，涉及对材料微观组织与力学性能之间关系的深入理解和分析，需要综合运用材料科学知识进行推理和解释。 | 难度: 在简答题题型中，该题目要求对灰口铸铁的微观结构与其力学性能之间的关系进行机理深度解释。虽然题目给出了石墨片尖端应力集中的关键点，但学生需要综合理解微观结构特征如何导致宏观性能表现，并进行合理的推理分析。这属于需要一定深度机理解释的题目，但尚未达到全面分析复杂现象的最高难度等级。" + }, + { + "idx": 4392, + "question": "Compare white and nodular cast irons with respect to composition and heat treatment.", + "answer": "White iron--2.5 to 4.0 wt% C and less than 1.0 wt% Si. No heat treatment; however, cooling is rapid during solidification. Nodular cast iron--2.5 to 4.0 wt% C, 1.0 to 3.0 wt% Si, and a small amount of Mg or Ce. A heat treatment at about 700°C may be necessary to produce a ferritic matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种铸铁的成分和热处理方式，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较两种铸铁的成分和热处理工艺，涉及多个知识点的关联和综合分析，需要理解不同成分对材料性能的影响以及热处理的作用，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解并比较两种铸铁的成分和热处理工艺，涉及多个概念的综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4393, + "question": "Compare white and nodular cast irons with respect to microstructure.", + "answer": "White iron--There are regions of cementite interspersed within pearlite. Nodular cast iron--Nodules of graphite are embedded in a ferrite or pearlite matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的微观结构，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对白口铸铁和球墨铸铁微观结构的基本概念记忆和理解，属于基础知识的直接对比和描述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较两种铸铁的微观结构，需要考生对白口铸铁和球墨铸铁的基本组织特征进行描述，但不需要深入分析或阐述复杂的概念体系。这属于对基础概念的记忆和简单应用，符合等级2的标准。" + }, + { + "idx": 4394, + "question": "Compare white and nodular cast irons with respect to mechanical characteristics.", + "answer": "White iron--Extremely hard and brittle. Nodular cast iron--Moderate strength and ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的机械特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对白口铸铁和球墨铸铁机械特性的基本概念记忆和理解，属于基础知识的直接对比和描述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较白口铸铁和球墨铸铁的机械特性，需要考生对两种材料的特性有基本的记忆和理解，并能进行简单的对比描述。虽然涉及两个概念，但不需要复杂的体系阐述或深入分析，因此属于中等难度。" + }, + { + "idx": 4395, + "question": "Is it possible to produce malleable cast iron in pieces having large cross-sectional dimensions? Why or why not?", + "answer": "It is not possible to produce malleable iron in pieces having large cross-sectional dimensions. White cast iron is the precursor of malleable iron, and a rapid cooling rate is necessary for the formation of white iron, which may not be accomplished at interior regions of thick cross-sections.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么不能生产大截面尺寸的可锻铸铁，答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目不仅需要理解可锻铸铁的基本概念（white cast iron作为前驱体），还需要分析冷却速率对材料微观结构的影响，并推理厚截面区域无法实现快速冷却的原因。这涉及多概念关联和机理解释，属于综合分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对可锻铸铁的生产限制进行机理深度解释。需要综合理解白口铸铁的形成条件、冷却速率对微观结构的影响，以及截面尺寸与冷却速率的相互关系。虽然不涉及多因素交互作用的全面分析，但对单一机理的阐述深度已达到等级4的要求。" + }, + { + "idx": 4396, + "question": "What is the principal difference between wrought and cast alloys?", + "answer": "The principal difference between wrought and cast alloys is as follows: wrought alloys are ductile enough so as to be hot or cold worked during fabrication, whereas cast alloys are brittle to the degree that shaping by deformation is not possible and they must be fabricated by casting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述锻造合金和铸造合金的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对锻造合金和铸造合金基本概念的记忆和理解，属于定义和分类的基础知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释锻造合金和铸造合金的主要区别，需要学生对两种合金的基本特性（如延展性和脆性）有明确的理解，并能对比描述其加工方式的差异。虽然涉及两个概念的对比，但不需要深入分析复杂机制或多种影响因素，属于中等难度的概念解释题。" + }, + { + "idx": 4397, + "question": "Why must rivets of a 2017 aluminum alloy be refrigerated before they are used?", + "answer": "Rivets of a 2017 aluminum alloy must be refrigerated before they are used because, after being solution heat treated, they precipitation harden at room temperature. Once precipitation hardened, they are too strong and brittle to be driven.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么2017铝合金铆钉在使用前必须冷藏，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解2017铝合金铆钉的热处理过程及其对材料性能的影响，涉及多步概念关联（固溶处理、时效硬化、材料性能变化）和综合分析（为什么需要冷藏以及不冷藏的后果）。虽然不涉及复杂计算，但需要对材料科学中的时效硬化机制有较深入的理解和应用。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释2017铝合金铆钉为何需要冷藏使用，涉及热处理和沉淀硬化等概念的综合分析。虽然需要理解多个材料科学概念并关联实际应用，但解题步骤相对直接，主要围绕一个核心原理展开论述，无需多角度或深度关联性分析。" + }, + { + "idx": 4398, + "question": "What is the chief difference between heat-treatable and non-heat-treatable alloys?", + "answer": "The chief difference between heat-treatable and nonheat-treatable alloys is that heat-treatable alloys may be strengthened by a heat treatment wherein a precipitate phase is formed (precipitation hardening) or a martensitic transformation occurs. Nonheat-treatable alloys are not amenable to strengthening by such treatments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两种合金的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对热处理合金和非热处理合金的基本定义和区别的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要区分两种合金的主要差异，但仅涉及基础概念的记忆和简单对比，不需要复杂的体系阐述或多步骤推理。属于该题型中中等偏下的难度水平。" + }, + { + "idx": 4399, + "question": "Cite advantages of cold working.", + "answer": "The advantages of cold working are: (1) A high quality surface finish. (2) The mechanical properties may be varied. (3) Close dimensional tolerances.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举冷加工的优点，答案以文字解释和论述的形式呈现，没有提供选项或要求判断对错，也不需要数值计算。 | 知识层次: 题目考查对冷加工优点的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要列举多个优点，但每个优点都是冷加工的基础特性，不需要深入分析或建立复杂的概念关联。题目要求的是对基础概念的记忆和简单阐述，没有涉及复杂的理论推导或综合应用，因此属于中等难度。" + }, + { + "idx": 4400, + "question": "Cite disadvantages of cold working.", + "answer": "The disadvantages of cold working are: (1) High deformation energy requirements. (2) Large deformations must be accomplished in steps, which may be expensive. (3) A loss of ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举冷加工的缺点，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目考查对冷加工缺点的基本概念记忆和理解，不需要复杂的分析或综合应用 | 难度: 在简答题题型中，该题目要求列举冷加工的缺点，属于概念解释和描述的难度级别。虽然需要记忆多个要点（高变形能量需求、分步变形导致的成本增加、延展性损失），但不需要深入分析或构建复杂的概念体系，属于中等难度的概念解释类简答题。" + }, + { + "idx": 4401, + "question": "Cite advantages of hot working.", + "answer": "The advantages of hot working are: (1) Large deformations are possible, which may be repeated. (2) Deformation energy requirements are relatively low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举热加工的优点，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对热加工优势的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释和描述热加工的优势，涉及多个要点但不需要复杂的体系阐述。" + }, + { + "idx": 4402, + "question": "Cite disadvantages of hot working.", + "answer": "The disadvantages of hot working are: (1) A poor surface finish. (2) A variety of mechanical properties is not possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举热加工的缺点，答案以文字解释和论述的形式给出，没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目考查对热加工缺点的基本记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目要求列举热加工的缺点，并简要解释每个缺点。这属于概念解释和描述的难度等级，需要学生对热加工的基本概念有一定理解，并能列举和简要说明其缺点，但不需要深入分析或构建复杂的论述体系。" + }, + { + "idx": 4403, + "question": "Cite advantages of forming metals by extrusion as opposed to rolling.", + "answer": "The advantages of extrusion as opposed to rolling are as follows: (1) Pieces having more complicated cross-sectional geometries may be formed. (2) Seamless tubing may be produced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举挤压成形相对于轧制的优势，答案以文字解释和论述的形式给出，没有选项、判断或计算的要求。 | 知识层次: 题目考查对金属成形工艺（挤压和轧制）基本概念的记忆和理解，主要涉及两种工艺的简单对比和优势列举，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举挤压成型相对于轧制的优势，需要考生理解两种加工方法的基本原理并比较其特点。虽然涉及多个知识点（挤压和轧制的特性），但答案只需列举2-3个关键区别点，不需要深入分析或建立复杂的概念体系。这符合等级2\"概念解释和描述\"的要求，比单纯的定义简答（等级1）要求更高，但尚未达到需要系统阐述的等级3难度。" + }, + { + "idx": 4404, + "question": "Cite some disadvantages of forming metals by extrusion as opposed to rolling.", + "answer": "The disadvantages of extrusion over rolling are as follows: (1) Nonuniform deformation over the cross-section. (2) A variation in properties may result over a cross-section of an extruded piece.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举挤压成形相对于轧制成形的缺点，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对金属挤压和轧制两种成形方法的基本概念和特点的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述挤压成型相对于轧制成型的缺点，涉及对两种加工方法的基本理解和比较。虽然需要记忆和解释相关概念，但不需要深入分析复杂的概念体系或进行多层次的论述。因此，在简答题的基础概念记忆层次中属于中等难度。" + }, + { + "idx": 4405, + "question": "List four situations in which casting is the preferred fabrication technique.", + "answer": "Four situations in which casting is the preferred fabrication technique are:\n(1) For large pieces and/or complicated shapes.\n(2) When mechanical strength is not an important consideration.\n(3) For alloys having low ductilities.\n(4) When it is the most economical fabrication technique.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举四种情况，需要文字解释和论述，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查对铸造工艺适用场景的基础概念记忆和理解，属于列举典型应用场景的简单记忆性知识，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举四种铸造技术优先使用的情况，这需要学生对铸造技术的应用场景有基本的理解和记忆，但不需要深入分析或构建复杂的逻辑关系。虽然需要列举多个点，但每个点都是相对独立的基础知识点，整体难度适中。" + }, + { + "idx": 4406, + "question": "Compare sand casting technique", + "answer": "For sand casting, sand is the mold material, a two-piece mold is used, ordinarily the surface finish is not an important consideration, the sand may be reused (but the mold may not), casting rates are low, and large pieces are usually cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对砂型铸造技术进行比较和描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对砂型铸造技术的基本概念和特点的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对砂型铸造技术进行多方面的比较和描述，包括模具材料、模具类型、表面处理、材料重复使用性、铸造速率和铸件尺寸等。虽然涉及多个知识点，但都属于基础概念的记忆和简单应用，不需要构建复杂的逻辑体系或进行深入分析。相比等级1的简单定义回答，需要更全面的描述；但相比等级3的复杂概念体系阐述，其知识深度和整合要求较低。" + }, + { + "idx": 4407, + "question": "Compare die casting technique", + "answer": "For die casting, a permanent mold is used, casting rates are high, the molten metal is forced into the mold under pressure, a two-piece mold is used, and small pieces are normally cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较压铸技术的特点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对压铸技术的基本概念和特点的记忆和理解，如模具类型、铸造速率、金属注入方式等，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对压铸技术进行简要比较，涉及永久模具使用、高铸造率、压力注入等基本概念描述，但不需要深入分析或构建复杂概念体系。虽然比单纯的定义简答(等级1)要求稍高，但仍属于基础概念记忆范畴，解题步骤相对简单，主要考察对压铸技术特点的记忆和表述能力。" + }, + { + "idx": 4408, + "question": "Compare investment casting technique", + "answer": "For investment casting, a single-piece mold is used, which is not reusable; it results in high dimensional accuracy, good reproduction of detail, and a fine surface finish; and casting rates are low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对投资铸造技术进行比较，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对投资铸造技术的基本概念和特点的记忆和理解，如模具类型、尺寸精度、表面光洁度等，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对投资铸造技术进行简要比较，涉及对技术特点的描述（如模具类型、精度、表面质量等），但不需要深入分析或阐述复杂概念体系。这属于基础概念记忆层次的知识点，解题步骤相对简单，主要考察学生对基本概念的理解和表达能力。" + }, + { + "idx": 4409, + "question": "Compare lost foam casting technique", + "answer": "For lost foam casting, the pattern is polystyrene foam, whereas the mold material is sand. Complex geometries and tight tolerances are possible. Casting rates are higher than for investment, and there are few environmental wastes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对消失模铸造技术进行比较和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目主要考查对消失模铸造技术的基本概念和特点的记忆和理解，包括材料选择、几何形状和公差、铸造速率以及环境影响等方面的基础知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对lost foam casting技术进行简要比较，涉及材料、工艺特点和优势等基本概念的解释，但不需要深入阐述复杂概念体系或进行多层次的论证分析。属于该题型中中等偏下的难度水平。" + }, + { + "idx": 4410, + "question": "Compare continuous casting technique", + "answer": "For continuous casting, at the conclusion of the extraction process, the molten metal is cast into a continuous strand having either a rectangular or circular cross-section; these shapes are desirable for subsequent secondary metal-forming operations. The chemical composition and mechanical properties are relatively uniform throughout the cross-section.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对连续铸造技术进行比较和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对连续铸造技术的基本概念和特点的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对连续铸造技术进行简要说明，包括其工艺特点和产品特性，但不需要深入分析或比较多个复杂概念体系。回答需要展示对基础概念的理解和描述能力，但不需要进行复杂的推理或综合论述。" + }, + { + "idx": 4411, + "question": "Describe one problem that might exist with a steel weld that was cooled very rapidly.", + "answer": "If a steel weld is cooled very rapidly, martensite may form, which is very brittle. In some situations, cracks may form in the weld region as it cools.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述一个可能存在的问题，并需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目要求解释快速冷却对钢焊缝的影响，涉及马氏体形成及其性能特点，需要将冷却速率与材料微观结构变化关联起来，并进行简单的因果分析。这超出了单纯记忆基础概念的层次，但尚未达到需要复杂分析或综合推理的程度。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求描述快速冷却钢焊缝可能出现的一个问题，并需要解释其原因（马氏体形成及其脆性特性）。这需要学生理解焊接冶金学的基本概念，并能将冷却速率与微观组织转变联系起来。虽然涉及多步概念关联，但不需要多角度分析或深度关联性分析（等级4-5的要求），因此符合等级3的综合分析和说明标准。" + }, + { + "idx": 4412, + "question": "Cite three sources of internal residual stresses in metal components.", + "answer": "Three sources of residual stresses in metal components are plastic deformation processes, nonuniform cooling of a piece that was cooled from an elevated temperature, and a phase transformation in which parent and product phases have different densities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举金属构件中内部残余应力的三个来源，需要用文字进行解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属构件内部残余应力来源的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举金属构件内部残余应力的三个来源，并需要简要解释每个来源的原理。这超出了单纯记忆基本定义的等级1要求，但尚未达到需要系统阐述复杂概念体系的等级3难度。回答需要理解塑性变形、不均匀冷却和相变等基础概念，并能够进行简要描述，符合等级2的特征。" + }, + { + "idx": 4413, + "question": "What are two possible adverse consequences of internal residual stresses in metal components?", + "answer": "Two adverse consequences of these stresses are distortion (or warpage) and fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举金属部件内部残余应力的两个不良后果，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属部件内部残余应力可能造成的不良后果的基本概念记忆，属于基础概念的记忆和理解层面，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举金属部件内部残余应力的两个可能不良后果，并给出了具体的例子（变形和断裂）。这需要学生对残余应力的影响有基本的理解和记忆，但不需要深入分析或复杂的论述。因此，在简答题题型中属于中等难度。" + }, + { + "idx": 4414, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.20 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 905°C (1660°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，这需要基于对铁碳相图和正常化热处理过程的理解，属于需要简要回答的简答题类型。答案是一个具体的数值而非选择或判断。 | 知识层次: 题目需要应用铁碳相图的基本知识来确定奥氏体化的最低温度，属于直接套用相图信息的简单应用，不需要多步计算或复杂分析。 | 难度: 在简答题题型中，该题目属于简单应用级别，仅需要直接套用铁碳相图的基本知识来确定奥氏体化温度。解题步骤简单明确，只需查找相图中对应碳含量的临界温度即可，不需要复杂的解释或推导过程。在同类简答题中属于基础难度，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 4415, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.76 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 782°C (1440°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行复杂的计算。虽然答案是一个数值，但解答过程需要理解材料科学中的相变知识，属于需要简要回答的问题。 | 知识层次: 题目需要理解铁碳合金相图，并能够根据给定的碳含量（0.76 wt%）确定奥氏体化温度。这涉及到相图中关键点（如共析点）的记忆和应用，以及将相图知识应用于具体的热处理条件（正火处理）。虽然不需要复杂的计算或多步骤推理，但需要将多个概念关联起来进行综合分析。 | 难度: 在简答题中属于中等难度，需要理解铁碳相图、奥氏体化温度的概念，并能根据合金成分（0.76 wt% C）在相图中定位共析点温度（727°C），同时考虑正常化处理需要超过该温度50-100°C的工程实践要求。虽然涉及多步概念关联，但不需要深入讨论相变动力学或微观组织演变等更复杂因素。" + }, + { + "idx": 4416, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.95 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 840°C (1545°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或进行复杂的计算。虽然答案是一个数值，但解答过程需要基于材料科学知识（如铁碳相图）进行解释和判断，属于需要简要回答的简答题类型。 | 知识层次: 题目要求根据铁碳相图确定奥氏体化温度，需要理解相变原理并应用相图知识进行综合分析，涉及多步推理和概念关联，但不需要复杂的机理解释或创新设计。 | 难度: 在简答题题型中，该题目属于中等应用难度。题目要求考生理解铁碳合金的相变温度，并能够根据给定的碳含量（0.95 wt% C）确定奥氏体化的最低温度。这需要考生掌握铁碳相图的基本知识，并能够将理论知识与实际应用（如正常化热处理）相结合。虽然题目涉及多步计算和概念关联，但解题步骤相对直接，不需要进行深度关联性分析或多角度论述。因此，在简答题题型内，该题目属于等级3的综合分析和说明难度。" + }, + { + "idx": 4417, + "question": "Give the approximate temperature at which it is desirable to heat a 0.25 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 880°C (1510°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错。虽然答案是一个具体的数值，但题目并未提供选项或要求进行计算，而是需要基于知识直接回答。 | 知识层次: 题目要求根据给定的铁碳合金成分（0.25 wt% C）直接应用标准热处理工艺参数（完全退火温度），属于对基础热处理知识的直接应用，不需要多步计算或复杂分析。 | 难度: 在简答题题型中，该题目属于简单应用过程描述。题目要求直接给出一个特定成分铁碳合金在全退火热处理中的加热温度，属于基本概念的直接应用，无需复杂计算或多步骤推理。答案可直接从铁碳相图或标准热处理规范中获取，属于该题型内较为基础的问题。" + }, + { + "idx": 4418, + "question": "Give the approximate temperature at which it is desirable to heat a 0.45 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 830°C (1525°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个具体的数值，但题目并未提供选项或要求进行计算，而是基于知识记忆和理解的简答形式。 | 知识层次: 题目考查对铁碳合金热处理温度的直接应用，属于基本公式应用和简单记忆性知识，无需复杂分析或多步计算。 | 难度: 在简答题中属于简单应用过程描述难度。题目要求直接应用铁碳相图的基本知识，给出特定碳含量合金的全退火温度。解题步骤简单，只需查找相图中对应碳含量的临界温度（A3线），无需复杂计算或深入解释。属于对基础知识的直接套用，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 4419, + "question": "Give the approximate temperature at which it is desirable to heat a 0.85 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 777°C (1430°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个具体的数值，但题目并未提供选项或要求进行计算，而是考察对热处理工艺中温度的记忆或理解，属于需要简短回答的问题。 | 知识层次: 题目考查对铁碳合金热处理温度的直接应用，属于基本概念的直接套用，无需复杂分析或多步计算。 | 难度: 在简答题中属于简单应用过程描述，题目要求直接套用铁碳相图的基本知识（共析温度）来回答，不需要复杂的计算或深入的解释。解题步骤简单，仅需记忆或查阅相图中的关键温度点即可得出答案。" + }, + { + "idx": 4420, + "question": "Give the approximate temperature at which it is desirable to heat a 1.10 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 777°C (1430°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或进行判断。虽然答案是一个数值，但题目并未要求进行计算或应用公式，而是基于知识记忆或理解给出近似温度，因此属于简答题。 | 知识层次: 题目考查对铁碳合金全退火处理温度这一基本概念的记忆，属于基础知识的直接应用，不需要复杂的分析或计算。 | 难度: 在简答题题型中，该题目属于基础概念记忆类问题，仅需回忆并给出特定温度值（1.10 wt% C铁碳合金的全退火加热温度），无需进行概念解释或复杂体系阐述。其解题步骤简单直接，仅涉及单一知识点的提取，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 4421, + "question": "What is the purpose of a spheroidizing heat treatment?", + "answer": "The purpose of a spheroidizing heat treatment is to produce a very soft and ductile steel alloy having a spheroiditic microstructure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释spheroidizing heat treatment的目的，答案以文字形式给出详细解释，符合简答题的特征。 | 知识层次: 题目考查热处理工艺的基本目的和微观结构变化的记忆性知识，属于基础概念的理解和记忆范畴 | 难度: 在简答题题型中，该题目仅要求回答基本定义和目的，属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，只需直接复述热处理的基本目的即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4422, + "question": "On what classes of alloys is a spheroidizing heat treatment normally used?", + "answer": "It is normally used on medium- and high-carbon steels, which, by virtue of carbon content, are relatively hard and strong.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释在哪些类型的合金上通常使用球化热处理，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对球化热处理应用合金类别的基本概念记忆和理解，属于定义和分类层面的基础知识点。 | 难度: 在简答题中属于中等难度，需要解释特定热处理工艺适用的合金类别，并简要说明原因。虽然不涉及复杂概念体系，但需要一定的知识理解和描述能力，比单纯的定义简答要求更高。" + }, + { + "idx": 4423, + "question": "Briefly explain the difference between hardness and hardenability.", + "answer": "Hardness is a measure of a material's resistance to localized surface deformation, whereas hardenability is a measure of the depth to which a ferrous alloy may be hardened by the formation of martensite. Hardenability is determined from hardness tests.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释两个概念的区别，需要用文字进行解释和论述，符合简答题的特征 | 知识层次: 题目考查对硬度和淬透性这两个基本概念的定义和区别的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度。虽然需要区分两个相关但不同的概念（hardness和hardenability），但答案仅需简要说明两者的定义和基本区别，不需要深入分析或阐述复杂的概念体系。属于基础概念记忆层次中较为典型的对比解释类题目。" + }, + { + "idx": 4424, + "question": "What influence does the presence of alloying elements (other than carbon) have on the shape of a herdenability curve? Briefly explain this effect.", + "answer": "The presence of alloying elements (other than carbon) causes a much more gradual decrease in hardness with position from the quenched end for a hardenability curve. The reason for this effect is that alloying elements retard the formation of pearlitic and bainitic structures which are not as hard as martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释合金元素对淬透性曲线形状的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素对淬透性曲线形状的影响机理，需要综合运用材料科学中的相变理论、合金元素作用机制等知识进行推理分析，属于对多概念关联和机理解释的复杂分析层次。 | 难度: 在简答题题型中，该题目要求对合金元素对淬透性曲线形状的影响进行机理深度解释。需要综合运用材料科学知识，理解合金元素如何延缓珠光体和贝氏体形成，从而影响硬度分布。虽然不涉及多因素交互作用的全面分析，但需要清晰的因果链条和微观组织转变机制的阐述，属于该题型中较高难度的机理解释类题目。" + }, + { + "idx": 4425, + "question": "Name two thermal properties of a liquid medium that will influence its quenching effectiveness.", + "answer": "The two thermal properties of a liquid medium that influence its quenching effectiveness are thermal conductivity and heat capacity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并解释液体介质的两个热性能，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对液体介质热性能的基本概念记忆，仅需列举影响淬火效果的两个热性能参数，无需深入分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求列举两个热学性质，属于基础概念记忆层面的简单回答，不需要深入解释或复杂论述。同类题型中，这属于最基础的难度等级。" + }, + { + "idx": 4426, + "question": "For a ceramic compound, what are the two characteristics of the component ions that determine the crystal structure?", + "answer": "The two characteristics of component ions that determine the crystal structure of a ceramic compound are: 1) the magnitude of the electrical charge on each ion, and 2) the relative sizes of the cations and anions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述陶瓷化合物中决定晶体结构的两个离子特征，答案以文字形式给出，没有选项或计算要求。 | 知识层次: 题目考查的是陶瓷化合物晶体结构决定因素的基本概念记忆和理解，涉及离子电荷和相对尺寸这两个基本原理，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求回答陶瓷化合物晶体结构决定因素的两个特征，涉及基础概念的记忆和简单解释，但不需要复杂的体系阐述或多步骤推理。相比等级1的基本定义简答，该题需要更深入的概念理解；相比等级3的复杂体系阐述，该题的解答相对直接和简单。" + }, + { + "idx": 4427, + "question": "The zinc blende crystal structure is one that may be generated from close-packed planes of anions. Will the stacking sequence for this structure be FCC or HCP? Why?", + "answer": "The stacking sequence of close-packed planes of anions for the zinc blende crystal structure will be the same as FCC (and not HCP) because the anion packing is FCC.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述，说明为什么锌矿晶体结构的堆积序列是FCC而不是HCP，答案也提供了详细的解释而非简单的选择或判断。 | 知识层次: 题目要求理解锌矿晶体结构的堆垛顺序，并解释为何选择FCC而非HCP。这需要将晶体结构的基本概念（FCC和HCP的堆垛方式）与具体材料（锌矿）的特性关联起来，进行综合分析。虽然不涉及复杂计算，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解锌矿晶体结构的基本概念，并能够将阴离子的密堆积方式与FCC和HCP的堆垛序列进行关联分析。虽然题目涉及多步概念关联，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 4428, + "question": "The zinc blende crystal structure is one that may be generated from close-packed planes of anions. Will cations fill tetrahedral or octahedral positions? Why?", + "answer": "The cations will fill tetrahedral positions since the coordination number for cations is four.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要解释为什么阳离子会填充四面体位置，而不是简单的选择或判断。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对闪锌矿晶体结构中阳离子填充位置的基础概念记忆和理解，涉及配位数的基本知识，不需要复杂的分析或推理。 | 难度: 在简答题中属于中等难度，需要理解锌闪锌矿晶体结构的基本原理，并解释为什么阳离子会填充四面体位置而非八面体位置。这涉及到对配位数和晶体结构的理解，但不需要复杂的推导或深入的分析。" + }, + { + "idx": 4429, + "question": "The zinc blende crystal structure is one that may be generated from close-packed planes of anions. What fraction of the positions will be occupied?", + "answer": "Only one-half of the tetrahedral positions will be occupied because there are two tetrahedral sites per anion, and yet only one cation per anion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释锌闪矿晶体结构中位置的占据情况，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目需要理解闪锌矿晶体结构的基本原理，并应用关于阴离子密堆积和四面体位置的知识进行综合分析。虽然涉及基础概念，但需要将多个知识点关联起来（密堆积平面、四面体位置、阳离子填充比例），并进行逻辑推理得出答案，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解锌闪锌矿晶体结构的基本概念，并能解释为什么只有一半的四面体位置被占据。虽然涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4430, + "question": "Cadmium sulfide (CdS) has a cubic unit cell, and from x-ray diffraction data it is known that the cell edge length is 0.582nm. If the measured density is 4.82g / {cm}^{3}, how many \\mathrm{Cd}^{2+} and \\mathrm{S}^{2-} ions are there per unit cell?", + "answer": "there are four \\mathrm{cd}^{2+} and four s^{2-} ions per unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用（如密度公式、单位晶胞体积计算等）来确定单位晶胞中的离子数量，答案是一个具体的计算结果而非选择或判断。 | 知识层次: 题目需要进行多步计算，包括利用晶胞边长计算体积、结合密度计算质量、再根据分子量计算离子数量，涉及多个概念的综合应用和关联分析。 | 难度: 在计算题中属于综合性计算问题，需要结合X射线衍射数据、密度计算和晶体结构知识进行多步计算。题目要求计算单位晶胞中的离子数量，涉及摩尔质量、阿伏伽德罗常数和晶胞体积的计算，需要综合分析多个概念并进行数值运算，但不需要处理复杂多变量或非常规计算方法。" + }, + { + "idx": 4431, + "question": "A hypothetical A X type of ceramic material is known to have a density of 2.65g / {cm}^{3} and a unit cell of cubic symmetry with a cell edge length of 0.43nm. The atomic weights of the A and X elements are 86.6 and 40.3g / mol, respectively. On the basis of this information, which of the following crystal structures is (are) possible for this material: rock salt, cesium chloride, or zinc blende? Justify your choice(s).", + "answer": "the only possible crystal structure for this material is cesium chloride, which has one formula unit per unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于给定的材料科学信息，分析并判断可能的晶体结构类型，并通过文字解释和论述来证明选择。虽然题目给出了几个选项（rock salt, cesium chloride, zinc blende），但解答过程需要详细的计算和理论分析，最终通过文字论述来证明唯一可能的晶体结构是cesium chloride。因此，这更符合简答题的特征，而非简单的选择题。 | 知识层次: 题目需要综合运用密度计算、晶体结构分析和单位晶胞公式应用等多步计算和概念关联，涉及对几种晶体结构的综合分析，但不需要深入的机理解释或创新应用。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求考生进行多步计算（如密度计算、单位晶胞内原子数的确定等），这需要扎实的计算能力和对晶体结构参数的理解。其次，题目要求考生综合分析多种可能的晶体结构（岩盐、铯氯、闪锌矿），并基于计算结果进行判断，这需要考生能够将理论知识与实际数据相结合。此外，题目还要求考生对每种晶体结构的特点有深入的理解，并能将计算结果与这些特点进行关联。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 4432, + "question": "In terms of bonding, explain why silicate materials have relatively low densities.", + "answer": "The silicate materials have relatively low densities because the atomic bonds are primarily covalent in nature, and, therefore, directional. This limits the packing efficiency of the atoms, and therefore, the magnitude of the density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来说明硅酸盐材料密度较低的原因，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释硅酸盐材料密度较低的原因，涉及对共价键方向性及其对原子堆积效率影响的理解和分析。这需要将键合类型与材料性质关联起来，属于中等应用层次的知识运用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要解释硅酸盐材料密度较低的原因，但主要涉及共价键的方向性及其对原子堆积效率的影响，属于单一概念的综合分析和说明。不需要多角度或深度关联性分析，解题步骤相对直接，符合等级3的标准。" + }, + { + "idx": 4433, + "question": "Would you expect Frenkel defects for anions to exist in ionic ceramics in relatively large concentrations? Why or why not?", + "answer": "Frenkel defects for anions would not exist in appreciable concentrations because the anion is quite large and is highly unlikely to exist as an interstitial.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么阴离子的Frenkel缺陷在离子陶瓷中不会大量存在，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对Frenkel缺陷在离子陶瓷中的存在情况进行解释，涉及对缺陷类型、离子大小和晶体结构的综合分析，需要深入理解缺陷形成的机理和影响因素，并进行推理分析。 | 难度: 在简答题的复杂分析类别中，该题目要求对Frenkel缺陷的形成机理进行深度解释，需要理解离子尺寸对缺陷形成的影响，并能够结合陶瓷材料特性进行推理分析。虽然不涉及多因素交互作用的全面分析（等级5），但已超出基础概念复述的层面，属于机理深度解释的范畴。" + }, + { + "idx": 4434, + "question": "Calculate the fraction of lattice sites that are Schottky defects for sodium chloride at its melting temperature \\left(801^{\\circ} C\\right). Assume an energy for defect formation of 2.3 \\mathrm{eV}.", + "answer": "the fraction of lattice sites that are schottky defects for sodium chloride at its melting temperature is 4.03 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Schottky缺陷的分数），并给出了具体的参数（熔融温度和缺陷形成能），答案是一个具体的数值结果（4.03 × 10^{-6}），这符合计算题的特征。 | 知识层次: 题目需要应用Schottky缺陷的形成能公式进行多步计算，涉及温度转换和指数运算，需要理解缺陷形成机制并正确应用相关公式，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用Schottky缺陷的公式，进行多步计算，并理解温度与缺陷形成能的关系。虽然计算过程较为直接，但涉及概念关联和综合分析，属于中等应用层次。" + }, + { + "idx": 4435, + "question": "(a) Suppose that Li2O is added as an impurity to CaO. If the Li+ substitutes for Ca2+, what kind of vacancies would you expect to form? How many of these vacancies are created for every Li+ added?", + "answer": "oxygen vacancies. Two Li+ ions added, a single oxygen vacancy is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释Li+取代Ca2+时形成的空位类型，并说明每添加一个Li+离子会形成多少空位。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解离子替代对晶体缺陷的影响，并分析Li+替代Ca2+时电荷平衡的机制，涉及多步推理和概念关联。虽然不涉及复杂计算，但需要综合分析离子价态变化与空位形成的关系。 | 难度: 在简答题题型中，该题目属于中等应用难度。虽然题目涉及多步计算和概念关联（如离子取代和空位形成机制），但解题思路相对直接，主要需要学生理解Li+取代Ca2+时的电荷补偿机制，并推导出氧空位的形成比例。相比需要多角度分析或深度关联性分析的题目（等级4-5），该题目的分析维度较为单一，属于典型的综合分析和说明类型题目。" + }, + { + "idx": 4436, + "question": "(b) Suppose that CaCl2 is added as an impurity to CaO. If the Cl substitutes for O2-, what kind of vacancies would you expect to form? How many of the vacancies are created for every Cl- added?", + "answer": "calcium vacancies. Two Cl- ions will lead to the formation of one calcium vacancy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释Cl-取代O2-时形成的空位类型，并说明每添加两个Cl-离子会形成一个钙空位。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解杂质替代对晶体缺陷的影响，并分析电荷平衡机制，涉及多步推理和概念关联，但不需要复杂的综合或创新思维。 | 难度: 在简答题中属于中等难度，需要理解缺陷化学的基本概念，并能将Cl-取代O2-的影响与CaO的晶体结构关联起来。题目要求分析杂质引入导致的空位类型和数量，涉及多步逻辑推理和简单计算，但不需要深入的多角度或跨领域分析。" + }, + { + "idx": 4437, + "question": "What point defects are possible for Al2O3 as an impurity in MgO?", + "answer": "For every Al3+ ion that substitutes for Mg2+ in MgO, a single positive charge is added. Thus, in order to maintain charge neutrality, either a positive charge must be removed or a negative charge must be added. Negative charges are added by forming O2- interstitials, which are not likely to form. Positive charges may be removed by forming Mg2+ vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al2O3作为杂质在MgO中可能形成的点缺陷类型，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求分析Al2O3作为杂质在MgO中可能产生的点缺陷，并解释电荷平衡机制。这需要综合运用点缺陷类型、电荷补偿原理等知识，进行推理分析，解释缺陷形成的机理。涉及多概念关联和深度理解，属于复杂分析层次。 | 难度: 在简答题的复杂分析层次中，该题目要求对点缺陷的形成机理进行深度解释，涉及电荷平衡的推理和离子置换的机理解释。虽然不需要全面分析复杂现象，但需要对材料科学中的缺陷化学有较深入的理解和综合运用能力，属于机理深度解释的难度等级。" + }, + { + "idx": 4438, + "question": "How many Al2+ ions must be added to form each of these defects?", + "answer": "One magnesium vacancy would be formed for every two Al3+ ions added.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Al2+离子添加与缺陷形成之间的关系，答案提供了文字解释而非计算或选择，符合简答题的特征。 | 知识层次: 题目需要理解缺陷形成的原理，并应用电荷平衡的概念进行计算，涉及多步推理和综合分析。 | 难度: 在简答题中属于中等难度，需要理解缺陷形成的概念并进行多步计算和综合分析。题目要求解释Al2+离子添加与缺陷形成的关系，涉及电荷平衡和离子替代的关联性分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4439, + "question": "When kaolinite clay [Al2(Si2O5)(OH)4] is heated to a sufficiently high temperature, chemical water is driven off. Under these circumstances, what is the composition of the remaining product (in weight percent Al2O3)?", + "answer": "the composition of the remaining product is 45.9% Al2O3 by weight.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定剩余产物的组成（以Al2O3的重量百分比表示），需要应用化学计量和分子量计算等数值计算方法。答案是一个具体的数值结果（45.9%），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，包括化学式的摩尔质量计算、水的质量损失计算以及最终产物中Al2O3的质量百分比计算。这需要理解化学反应的基本原理，并能够将多个概念关联起来进行综合分析。虽然不涉及复杂的推理或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解化学水脱除的概念，进行多步计算（包括分子量计算、质量分数转换等），并综合分析反应产物的组成。虽然不涉及复杂变量，但解题步骤较为复杂，需要较强的概念关联能力。" + }, + { + "idx": 4440, + "question": "When kaolinite clay [Al2(Si2O5)(OH)4] is heated to a sufficiently high temperature, chemical water is driven off. What are the liquidus and solidus temperatures of this material?", + "answer": "the liquidus and solidus temperatures of this material are 1825 degrees C and 1587 degrees C, respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答高岭石粘土在高温加热后的液相线和固相线温度，答案需要提供具体的温度数值，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对高岭石粘土加热过程中液线和固线温度的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆并准确复述材料的液线和固线温度数值，无需进行概念解释或复杂体系阐述。题目考查的是对特定材料相变温度的基础记忆能力，属于该题型内最基础的难度层级。" + }, + { + "idx": 4441, + "question": "Why may there be significant scatter in the fracture strength for some given ceramic material?", + "answer": "There may be significant scatter in the fracture strength for some given ceramic material because the fracture strength depends on the probability of the existence of a flaw that is capable of initiating a crack; this probability varies from specimen to specimen of the same material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对陶瓷材料断裂强度存在显著分散性的原因进行文字解释和论述，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷材料断裂强度存在显著分散性的原因，涉及对断裂机理的理解和分析，需要综合运用概率统计和材料缺陷的知识进行推理和解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解陶瓷材料断裂强度的基本概念，还需要解释其背后的概率性缺陷分布机理。这需要考生综合运用材料科学知识，分析断裂强度与微观缺陷之间的关系，并能够清晰阐述这种关系的随机性本质。虽然不涉及多因素交互作用的全面分析（等级5），但对单一机理的解释深度已达到较高水平。" + }, + { + "idx": 4442, + "question": "Why does fracture strength increase with decreasing specimen size?", + "answer": "The fracture strength increases with decreasing specimen size because as specimen size decreases, the probability of the existence of a flaw that is capable of initiating a crack diminishes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么断裂强度会随着试样尺寸的减小而增加，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释断裂强度与试样尺寸之间的关系，涉及缺陷概率和裂纹萌生机理的综合分析，需要深入理解材料断裂行为并运用相关理论进行推理解释。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释断裂强度随试样尺寸减小而增加的机理，涉及对材料缺陷概率与尺寸关系的理解，需要综合运用材料科学知识进行推理分析。虽然题目表述简洁，但回答需要准确描述尺寸效应与缺陷分布的关联性，属于该题型中较高层次的难度。" + }, + { + "idx": 4443, + "question": "The fracture strength of glass may be increased by etching away a thin surface layer. It is believed that the etching may alter surface crack geometry (i.e., reduce crack length and increase the tip radius). Compute the ratio of the original and etched crack tip radii for an eightfold increase in fracture strength if two-thirds of the crack length is removed.\n\\[\n\\text {", + "answer": "the ratio of the original and etched crack tip radii is 21.3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解裂纹尖端半径的比值，答案是一个具体的数值结果（21.3），解答过程涉及材料科学中的断裂力学公式和数学计算。 | 知识层次: 题目需要进行多步计算和概念关联，涉及断裂强度的计算和裂纹几何变化的综合分析。虽然题目提供了具体的计算步骤，但需要理解裂纹几何变化对断裂强度的影响，并进行相应的数值计算。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，并理解表面裂纹几何变化对断裂强度的影响。题目涉及概念关联和综合分析，但未达到复杂多变量计算的级别。" + }, + { + "idx": 4444, + "question": "A circular specimen of MgO is loaded using a three-point bending mode. Compute the minimum possible radius of the specimen without fracture, given that the applied load is 425N\\left(95.5 lb \\mathrm{b}_{1}\\right), the flexural strength is 105 MPa(15,000 psi), and the separation between load points is 50 mm(2.0 in).", + "answer": "the minimum possible radius of the specimen without fracture is 4.0mm (0.16 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小可能的半径，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及弯曲强度的概念和公式应用，需要将给定的参数代入公式并求解最小半径。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要应用三点弯曲公式进行多步计算，涉及载荷、弯曲强度和几何参数的关联分析。虽然计算步骤明确，但需要正确理解和应用材料力学中的弯曲强度概念，并合理转换单位，属于中等应用层次的计算题。" + }, + { + "idx": 4446, + "question": "Would you be 100% certain of the prediction in part (a)? Why or why not?", + "answer": "the certainty of this prediction is not 100% because there is always some variability in the flexural strength for ceramic materials. since the calculated stress 379 mpa is relatively close to the flexural strength 390 mpa, there is some chance that fracture will occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对预测的确定性进行解释和论述，答案提供了详细的文字解释，说明为什么预测不是100%确定，这符合简答题的特征。 | 知识层次: 题目要求学生理解并应用材料科学中的基本概念（如材料的变异性），并结合具体数值进行判断和分析。虽然不涉及复杂的计算或多步骤推理，但需要学生将理论知识与实际情况联系起来，进行一定程度的综合分析。 | 难度: 在简答题题型中，该题目要求考生不仅理解材料性能的基本概念（如flexural strength和variability），还需要进行多角度分析（如数值接近性对预测的影响）和论述（解释为什么不能100%确定）。这超出了单纯的概念复述（等级3），但尚未达到需要深度关联多个学科知识的程度（等级5）。题目要求考生综合运用材料科学知识和概率思维，属于该题型中较高但非最高的难度层级。" + }, + { + "idx": 4447, + "question": "Cite one reason why ceramic materials are, in general, harder yet more brittle than metals.", + "answer": "Crystalline ceramics are harder yet more brittle than metals because they (ceramics) have fewer slip systems, and, therefore, dislocation motion is highly restricted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述陶瓷材料比金属更硬但更脆的原因，答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷材料比金属更硬但更脆的原因，涉及对晶体结构、位错运动机制等深层次概念的理解和关联分析，需要综合运用材料科学知识进行机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对陶瓷材料与金属的硬度及脆性差异进行机理深度解释。需要综合运用材料科学知识，理解晶体结构、位错运动等概念，并能准确分析陶瓷材料因滑移系统较少导致位错运动受限的机理。虽然不涉及多因素交互作用的全面分析，但对材料微观结构与宏观性能关系的解释深度已达到等级4要求。" + }, + { + "idx": 4448, + "question": "The modulus of elasticity for beryllium oxide (BeO) having 5 vol% porosity is 310 GPa (45 x 10^6 psi). Compute the modulus of elasticity for the nonporous material.", + "answer": "the modulus of elasticity for the nonporous material is 342 gpa (49.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔材料的弹性模量，答案也是具体的数值结果。 | 知识层次: 题目需要应用基本公式（弹性模量与孔隙率的关系）进行简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用孔隙率与弹性模量的简单关系公式（如E = E0(1 - 1.9P + 0.9P^2)）进行一步反推计算即可得到无孔隙材料的弹性模量，无需多步推导或组合公式。" + }, + { + "idx": 4450, + "question": "The modulus of elasticity for boron carbide (B4C) having 5 vol% porosity is 290 GPa (42 x 10^6 psi). Compute the modulus of elasticity for the nonporous material.", + "answer": "320 GPa (46.3 x 10^6 psi)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔材料的弹性模量，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本公式的应用和简单计算，即通过已知的孔隙率和弹性模量计算非多孔材料的弹性模量，属于直接套用公式的简单应用。 | 难度: 在计算题中属于简单公式应用计算难度，需要理解孔隙率对弹性模量的影响并应用单一公式进行计算，解题步骤较为直接。" + }, + { + "idx": 4451, + "question": "The modulus of elasticity for boron carbide (B4C) having 5 vol% porosity is 290 GPa (42 x 10^6 psi). At what volume percent porosity will the modulus of elasticity be 235 GPa (34 x 10^6 psi)?", + "answer": "the modulus of elasticity will be 235 GPa (34 x 10^6 psi) at a porosity of 15.1 vol%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定孔隙率下的弹性模量，答案是一个具体的数值结果（15.1 vol%），这表明需要进行计算推导。 | 知识层次: 题目需要应用多步计算和公式推导，涉及孔隙率与弹性模量之间的关系，需要综合分析已知条件并求解未知参数。 | 难度: 在计算题-中等应用题型中，该题目属于综合性计算问题。需要应用孔隙率与弹性模量关系的公式（如Hasselman公式），进行多步计算和变量转换。虽然不涉及复杂多变量，但需要正确理解材料性能与孔隙率的非线性关系，并进行逆向求解，这比简单的正向计算更具挑战性。解题过程需要将给定的弹性模量值代入公式，解出未知孔隙率，体现了概念关联和综合分析的要求。" + }, + { + "idx": 4452, + "question": "Cite the two desirable characteristics of glasses.", + "answer": "Two desirable characteristics of glasses are optical transparency and ease of fabrication.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举玻璃的两个理想特性，答案需要文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对玻璃材料基本特性的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举玻璃的两个理想特性，不需要进行概念解释或复杂阐述，仅需回忆基础概念记忆性知识即可完成作答。" + }, + { + "idx": 4453, + "question": "What is crystallization?", + "answer": "Crystallization is the process whereby a glass material is caused to transform to a crystalline solid, usually as a result of a heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“crystallization”进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，仅要求对\"crystallization\"这一基础概念进行定义和简单描述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的概念记忆层次。不需要进行概念解释或复杂体系阐述，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4454, + "question": "Cite two properties that may be improved by crystallization.", + "answer": "Two properties that may be improved by crystallization are (1) a lower coefficient of thermal expansion, and (2) higher strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两个可能通过结晶改善的性能，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对结晶化改善材料性能这一基本概念的简单列举，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举两个通过结晶可能改善的性能，不需要进行概念解释或复杂体系阐述。回答仅需记忆基础材料科学知识中的结晶效应，属于最基础的概念记忆层面。" + }, + { + "idx": 4455, + "question": "For refractory ceramic materials, cite three characteristics that improve with increasing porosity.", + "answer": "For refractory ceramic materials, three characteristics that improve with increasing porosity are (1) decreased thermal expansion and contraction upon thermal cycling, (2) improved thermal insulation, and (3) improved resistance to thermal shock.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释多孔耐火陶瓷材料随孔隙率增加而改善的三个特性，答案以文字解释和论述的形式呈现，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查对耐火陶瓷材料孔隙率影响的基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举并简要说明耐火陶瓷材料随孔隙率增加而改善的三个特性，这需要学生对材料性能与孔隙率关系的基本概念有一定理解，但不需要进行复杂的体系阐述或深入分析。属于对基础概念记忆和简单应用的考查。" + }, + { + "idx": 4456, + "question": "For refractory ceramic materials, cite two characteristics that are adversely affected by increasing porosity.", + "answer": "For refractory ceramic materials, two characteristics that are adversely affected by increasing porosity are (1) load-bearing capacity and (2) resistance to attack by corrosive materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个特性，需要用文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对耐火陶瓷材料基本特性的记忆和理解，仅需列举两个受孔隙率增加负面影响的性质，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举两个受孔隙率增加不利影响的特性，这需要考生对耐火陶瓷材料的基本性能有一定了解，并能准确描述这些性能与孔隙率的关系。虽然涉及多个概念，但不需要深入分析或复杂推理，属于中等难度的简答题。" + }, + { + "idx": 4457, + "question": "How do the aggregate particles become bonded together in clay-based mixtures during firing?", + "answer": "For clay-based aggregates, a liquid phase forms during firing, which infiltrates the pores between the unmelted particles; upon cooling, this liquid becomes a glass, that serves as the bonding phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释粘土基混合物在烧制过程中颗粒如何结合，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释粘土基混合物在烧制过程中颗粒如何通过液相形成和冷却后的玻璃相粘结，涉及多步骤的物理化学变化和机理分析，需要综合运用材料科学知识进行推理和解释。 | 难度: 在简答题题型中，该题目要求对粘土基混合物在烧制过程中的粘结机理进行深度解释，涉及液相形成、孔隙渗透以及冷却后玻璃相的形成等复杂过程。虽然不需要全面分析所有相关现象（如不同温度阶段的具体变化），但仍需综合运用材料科学知识进行推理和机理解释，属于机理深度解释的难度等级。" + }, + { + "idx": 4458, + "question": "How do the aggregate particles become bonded together in cements during setting?", + "answer": "With cements, the bonding process is a chemical, hydration reaction between the water that has been added and the various cement constituents. The cement particles are bonded together by reactions that occur at the particle surfaces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释水泥在凝固过程中颗粒如何结合，答案需要文字解释和论述，没有提供选项或要求计算。 | 知识层次: 题目考查水泥凝固过程中颗粒结合的基本原理，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释水泥凝固过程中颗粒结合的具体化学反应过程，但主要考察的是对基础化学原理（水化反应）和水泥成分相互作用的理解，不需要涉及复杂的概念体系或多步骤分析。属于对单一化学过程的描述性回答，符合等级2的特征。" + }, + { + "idx": 4459, + "question": "What is the glass transition temperature for a noncrystalline ceramic?", + "answer": "The glass transition temperature is, for a noncrystalline ceramic, that temperature at which there is a change of slope for the specific volume versus temperature curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释玻璃化转变温度的定义，答案提供了详细的文字解释，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对玻璃转变温度这一基本概念的定义和理解，属于基础概念记忆范畴 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然需要学生准确记忆并表述非晶态陶瓷的玻璃化转变温度定义，但不需要进行复杂的概念体系阐述或深入分析。题目主要考察对基础概念的理解和表述能力，属于该题型中的中等难度。" + }, + { + "idx": 4460, + "question": "What is the melting temperature for a crystalline material?", + "answer": "The melting temperature is, for a crystalline material and upon cooling, that temperature at which there is a sudden and discontinuous decrease in the specific-volume-versus-temperature curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“结晶材料的熔点”进行解释，答案提供了详细的文字描述和定义，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对晶体材料熔化温度这一基本概念的定义和理解，属于基础概念记忆范畴。 | 难度: 在简答题题型中，该题目要求对结晶材料的熔点进行解释和描述，涉及对特定温度下物理性质变化的说明。虽然需要一定的概念理解，但并不需要复杂的体系阐述或多步骤推理，属于概念解释和描述的难度等级。" + }, + { + "idx": 4461, + "question": "Compare the softening points for 96% silica, borosilicate, and soda-lime glasses.", + "answer": "The softening point of a glass is that temperature at which the viscosity is 4 × 10^{6} \\mathrm{~Pa}·s; from Figure 13.7, these temperatures for the 96% silica, borosilicate, and soda-lime glasses are 1540^{\\circ} C\\left(2800^{\\circ} F\\right), 830^{\\circ} C\\left(1525^{\\circ} F\\right), and 700^{\\circ} C\\left(1290^{\\circ} F\\right), respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较不同玻璃的软化点，答案提供了具体的温度数值和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对不同类型玻璃软化点的记忆，属于基础概念的记忆性知识，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求比较三种玻璃的软化点，但本质上只需要记忆和复述特定数值及其对应关系，不需要进行复杂的逻辑推理或概念体系阐述。解题步骤仅涉及查找和列举数据，对知识点的掌握深度要求适中，属于该题型框架内中等偏下的难度水平。" + }, + { + "idx": 4462, + "question": "Explain why residual thermal stresses are introduced into a glass piece when it is cooled.", + "answer": "Residual thermal stresses are introduced into a glass piece when it is cooled because surface and interior regions cool at different rates, and, therefore, contract different amounts; since the material will experience very little, if any deformation, stresses are established.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释玻璃冷却时残余热应力的产生原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释残余热应力在玻璃冷却过程中的形成机制，涉及不同冷却速率导致的收缩差异和应力建立，需要综合运用热力学、材料变形行为等知识进行机理分析和推理。 | 难度: 在简答题-复杂分析题型中，该题目要求对玻璃冷却过程中残余热应力的产生机理进行深度解释。需要综合运用热膨胀系数、冷却速率差异和材料变形特性等知识，进行多因素推理分析。虽然不涉及最复杂的多变量交互作用（等级5特征），但已超出基础概念复述，属于需要机理深度解释的等级4难度。" + }, + { + "idx": 4463, + "question": "Are thermal stresses introduced upon heating? Why or why not?", + "answer": "Yes, thermal stresses will be introduced because of thermal expansion upon heating for the same reason as for thermal contraction upon cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要解释为什么加热时会产生热应力，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对热应力产生原因的基本理解，仅需记忆热膨胀导致热应力的基本原理即可回答，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释热应力在加热时是否产生及其原因，涉及对热膨胀基本原理的理解和简单应用，但不需要复杂的体系阐述或多步骤推理。这比单纯记忆定义（等级1）要求更高，但低于需要整合多个概念的复杂阐述（等级3）。" + }, + { + "idx": 4464, + "question": "Borosilicate glasses and fused silica are resistant to thermal shock. Why is this so?", + "answer": "Borosilicate glasses and fused silica are resistant to thermal shock because they have relatively low coefficients of thermal expansion; therefore, upon heating or cooling, the difference in the degree of expansion or contraction across a cross-section of a ware that is constructed from these materials will be relatively low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么硼硅酸盐玻璃和熔融石英具有抗热震性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释硼硅酸盐玻璃和熔融石英抗热震性的原因，涉及材料的热膨胀系数及其对热震性能的影响机制。这需要综合运用材料科学知识，理解热膨胀行为与热震性能之间的关系，并进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。虽然题目涉及的知识点（热膨胀系数与抗热震性的关系）较为明确，但要求考生不仅能够陈述基本事实，还需要解释其中的物理机制（即低热膨胀系数如何导致抗热震性）。这需要考生对材料科学中的热力学性质有较深入的理解，并能将多个概念联系起来进行逻辑推导。相较于只需简单列举事实的简答题（等级3），该题目对分析能力和机理解释的要求更高，但尚未达到需要综合多种复杂因素进行全面分析的等级5水平。" + }, + { + "idx": 4465, + "question": "Glass pieces may also be strengthened by chemical tempering. With this procedure, the glass surface is put in a state of compression by exchanging some of the cations near the surface with other cations having a larger diameter. Suggest one type of cation that, by replacing \\mathrm{Na}^{+}, will induce chemical tempering in a soda-lime glass.", + "answer": "Chemical tempering will be accomplished by substitution, for \\mathrm{Na}^{+}, another monovalent cation with a slightly larger diameter. Both K^{+}and \\mathrm{Cs}^{+}fill these criteria, having ionic radii of 0.138 and 0.170 nm, respectively, which are larger than the ionic radius of \\mathrm{Na}^{+}(0.102nm). In fact, soda-lime glasses are tempered by a K^{+}-\\mathrm{Na}^{+}ion exchange.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出一种可以替代Na+的阳离子，并解释其如何通过化学强化来增强玻璃。答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求考生理解化学强化玻璃的原理，并能够应用离子半径的知识选择合适的阳离子进行替换。虽然涉及基础概念（离子半径、化学强化），但需要考生进行一定的分析和综合，选择符合条件的阳离子（K+或Cs+），并解释其作用机制。这超出了单纯记忆的层次，属于中等应用水平。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释化学钢化的原理并给出具体的阳离子替换例子，但知识点相对明确，解题步骤较为直接。需要理解离子半径对玻璃表面压缩状态的影响，并关联到具体的阳离子选择（K+或Cs+）。相比更复杂的综合分析题，该题的深度和关联性要求适中，属于等级3的综合分析和说明难度。" + }, + { + "idx": 4466, + "question": "Cite the two desirable characteristics of clay minerals relative to fabrication processes.", + "answer": "Two desirable characteristics of clay minerals relative to fabrication processes are (1) they become hydroplastic (and therefore formable) when mixed with water; and (2) during firing, clays melt over a range of temperatures, which allows some fusion and bonding of the ware without complete melting and a loss of mechanical integrity and shape.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并简要说明粘土矿物在制造过程中的两个理想特性，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对粘土矿物在加工过程中两个理想特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释和描述两个具体的特性，但不需要复杂的体系阐述或深入分析。题目要求的是基础概念的记忆和简单应用，符合等级2的标准。" + }, + { + "idx": 4467, + "question": "From a molecular perspective, briefly explain the mechanism by which clay minerals become hydroplastic when water is added.", + "answer": "Clays become hydroplastic when water is added because the water molecules occupy regions between the layered molecular sheets; these water molecules essentially eliminate the secondary molecular bonds between adjacent sheets, and also form a thin film around the clay particles. The net result is that the clay particles are relatively free to move past one another, which is manifested as the hydroplasticity phenomenon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从分子角度简要解释黏土矿物加水后产生水塑性的机制，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求从分子层面解释黏土矿物加水后产生水塑性的机理，涉及分子间作用力、水分子在层状结构中的行为以及宏观性质变化的关联，需要综合运用材料科学和化学知识进行推理分析，思维过程较深。 | 难度: 在简答题中属于机理深度解释难度，需要理解粘土矿物的分子结构、水分子与粘土层间的相互作用机制，并能清晰阐述次级分子键的消除和粒子运动自由度的增加这一复杂过程。虽然不涉及多因素交叉分析，但对分子层面机理的解释深度要求较高。" + }, + { + "idx": 4468, + "question": "What are the three main components of a whiteware ceramic such as porcelain?", + "answer": "clay, quartz, and a flux.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举白瓷陶瓷的主要成分，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对白瓷陶瓷主要成分的基础概念记忆，属于定义和分类的基本原理记忆性知识。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目仅要求列举白瓷陶瓷（如瓷器）的三种主要成分，不需要进行概念解释或复杂体系阐述。回答仅需记忆性知识，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 4469, + "question": "What role does each component play in the forming and firing procedures?", + "answer": "Quartz acts as a filler material. Clay facilitates the forming operation since, when mixed with water, the mass may be made to become either hydroplastic or form a slip. Also, since clays melt over a range of temperatures, the shape of the piece being fired will be maintained. The flux facilitates the formation of a glass having a relatively low melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释每个组分在成型和烧制过程中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释各个组分在成型和烧制过程中的作用，需要将材料科学中的基础概念（如石英、粘土、助熔剂的性质）与实际工艺过程（成型和烧制）相关联，并进行综合分析。这超出了单纯记忆的范畴，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对多个组件的功能进行详细说明，并涉及它们在成型和烧制过程中的具体作用。需要考生不仅理解每个组件的特性，还要能够关联它们在工艺中的相互作用。这属于多角度分析论述的难度等级，因为需要综合多个知识点并进行较为详细的解释。" + }, + { + "idx": 4470, + "question": "Why is it so important to control the rate of drying of a ceramic body that has been hydroplastically formed or slip cast?", + "answer": "It is important to control the rate of drying inasmuch as if the rate of drying is too rapid, there will be nonuniform shrinkage between surface and interior regions, such that warping and/or cracking of the ceramic ware may result.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么控制陶瓷体的干燥速率很重要，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解陶瓷干燥过程中的基本原理（非均匀收缩），并分析其对产品性能（翘曲和开裂）的影响，涉及概念关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在简答题中属于中等难度，需要理解陶瓷干燥过程中的关键概念（如非均匀收缩、变形/开裂机制），并能将这些概念关联到成型工艺（水塑性成型/注浆成型）的具体情境中。虽然不涉及多角度或深度关联分析，但要求对材料行为进行综合说明，并解释因果关系。" + }, + { + "idx": 4471, + "question": "Cite three factors that influence the rate of drying, and explain how each affects the rate.", + "answer": "Three factors that affect the rate of drying are temperature, humidity, and rate of air flow. The rate of drying is enhanced by increasing both the temperature and rate of air flow, and by decreasing the humidity of the air.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释影响干燥速率的三个因素，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举并简要解释影响干燥速率的三个因素，主要考查对基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举并解释三个影响干燥速率的因素，这需要学生掌握相关基础概念，并能进行简单的因果关系说明。虽然涉及多个因素，但每个因素的解释都较为直接，不需要复杂的体系阐述或深入分析，因此属于等级2难度。" + }, + { + "idx": 4472, + "question": "Cite one reason why drying shrinkage is greater for slip cast or hydroplastic products that have smaller clay particles.", + "answer": "The reason that drying shrinkage is greater for products having smaller clay particles is because there is more particle surface area, and, consequently, more water will surround a given volume of particles. The drying shrinkage will thus be greater as this water is removed, and as the interparticle separation decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么干燥收缩在具有较小粘土颗粒的滑铸或水塑性产品中更大，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解粘土颗粒大小与干燥收缩之间的关系，并解释其机理。这涉及到多个概念的关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于中等难度，需要理解粘土颗粒大小与干燥收缩之间的关系，并进行简单的概念关联和综合分析。题目要求解释为什么较小的粘土颗粒会导致更大的干燥收缩，涉及表面面积和水分含量的概念，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4473, + "question": "Name three factors that influence the degree to which vitrification occurs in clay-based ceramic wares.", + "answer": "(1) composition (2) the temperature of firing(3) the time at the firing temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举影响粘土基陶瓷制品玻璃化程度的三个因素，答案需要以文字形式进行解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对影响陶瓷制品玻璃化程度的基本因素的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型内，该题目属于概念解释和描述难度等级。虽然需要列举三个影响陶瓷制品玻璃化程度的因素，但每个因素都是基础概念记忆层面的知识点，不需要进行复杂的概念体系阐述或深入分析。题目要求的是对基本原理的记忆和简单描述，符合等级2的特征。" + }, + { + "idx": 4474, + "question": "Explain how density, firing distortion, strength, corrosion resistance, and thermal conductivity are affected by the extent of vitrification.", + "answer": "Density will increase with degree of vitrification since the total remaining pore volume decreases. Strength will also increase with degree of vitrification inasmuch as more of the liquid phase forms, which fills in a greater fraction of pore volume. Upon cooling, the liquid forms a glass matrix of relatively high strength. Corrosion resistance normally increases also, especially at service temperatures below that at which the glass phase begins to soften. The rate of corrosion is dependent on the amount of surface area exposed to the corrosive medium; hence, decreasing the total surface area by filling in some of the surface pores, diminishes the corrosion rate. Thermal conductivity will increase with degree of vitrification. The glass phase has a higher conductivity than the pores that it has filled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个材料性质如何受到玻璃化程度的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多个材料性能（密度、强度、耐腐蚀性、热导率等）与玻璃化程度之间的复杂关系，涉及多因素综合分析、机理解释和概念关联，需要深入理解材料科学原理并进行推理分析。 | 难度: 在简答题（复杂分析类）中属于最高难度等级。题目要求综合解释五个不同材料性能（密度、烧成变形、强度、耐腐蚀性、导热性）与玻璃化程度的多维度关系，每个性能都需要从微观机理层面进行推理分析（如孔隙率变化、玻璃相形成、表面面积影响等）。答案需展示对陶瓷烧结过程中相变、孔隙演变、性能关联性的系统理解，并整合多个学科知识（材料热力学、腐蚀科学、传热学）进行交叉论证，完全符合\"复杂现象全面分析\"的判定标准。" + }, + { + "idx": 4475, + "question": "Some ceramic materials are fabricated by hot isostatic pressing. Cite some of the limitations and difficulties associated with this technique.", + "answer": "The principal disadvantage of hot-isostatic pressing is that it is expensive. The pressure is applied on a pre-formed green piece by a gas. Thus, the process is slow, and the equipment required to supply the gas and withstand the elevated temperature and pressure is costly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举和解释热等静压技术的局限性和困难，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举热等静压技术的局限性和困难，需要对热等静压工艺的原理和实际应用有较深入的理解，并能够综合分析其经济性和技术难点。这涉及到多方面的知识关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于中等难度，需要理解热等静压技术的基本原理，并能够列举其局限性和困难。虽然题目要求综合分析，但答案主要集中在成本和技术限制方面，没有涉及更深层次的材料科学原理或多角度分析。因此，在简答题题型内属于等级3的综合分析和说明难度。" + }, + { + "idx": 4476, + "question": "Compute repeat unit molecular weight for poly(vinyl chloride)", + "answer": "62.49g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚氯乙烯重复单元的分子量，需要通过数值计算和公式应用得出具体数值结果62.49g/mol | 知识层次: 题目要求计算聚氯乙烯重复单元的分子量，这需要应用基本的化学计算知识（原子量相加），属于单一公式的直接应用，不需要多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于最基本的单一公式直接计算。只需要知道聚氯乙烯的重复单元结构（-CH2-CHCl-）并计算其分子量即可，不需要任何公式组合或复杂计算步骤，完全符合等级1的定义标准。" + }, + { + "idx": 4477, + "question": "Compute repeat unit molecular weight for poly(ethylene terephthalate)", + "answer": "192.16g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚对苯二甲酸乙二醇酯的重复单元分子量，需要通过数值计算和化学公式应用来得出具体数值结果(192.16g/mol)，符合计算题的特征。 | 知识层次: 题目要求计算聚对苯二甲酸乙二醇酯的重复单元分子量，这需要应用基本的化学分子式计算知识，属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算聚对苯二甲酸乙二醇酯的重复单元分子量，这是一个直接套用已知分子式进行简单加和的计算过程，不需要多个公式组合或复杂的推导步骤。" + }, + { + "idx": 4478, + "question": "Compute repeat unit molecular weight for polycarbonate", + "answer": "254.27g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚碳酸酯的重复单元分子量，需要通过数值计算和公式应用来得出具体数值结果(254.27g/mol)，符合计算题的特征。 | 知识层次: 题目要求计算聚碳酸酯的重复单元分子量，这需要应用基本的分子量计算公式和原子量数据，属于直接套用基本公式的简单计算过程，不需要多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算聚碳酸酯的重复单元分子量，这是一个直接套用已知分子式进行简单加和的计算过程，不涉及多个公式组合或复杂推导步骤。" + }, + { + "idx": 4479, + "question": "Compute repeat unit molecular weight for polydimethylsiloxane", + "answer": "74.16g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚二甲基硅氧烷的重复单元分子量，需要通过数值计算和公式应用来得出具体数值（74.16g/mol），属于典型的计算题特征。 | 知识层次: 题目要求计算聚二甲基硅氧烷的重复单元分子量，这属于基本公式应用和简单计算，直接套用分子量计算公式即可完成，不需要多步计算或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。只需要应用聚二甲基硅氧烷重复单元的分子式进行简单加和计算，无需多个公式组合或复杂推导，符合等级1对基本公式应用和直接套用的要求。" + }, + { + "idx": 4480, + "question": "The number-average molecular weight of a polypropylene is 1,000,000g / mol. Compute the degree of polymerization.", + "answer": "23760", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（分子量除以单体分子量）来求解聚合度，答案是一个具体的数值结果，符合计算题的特征 | 知识层次: 题目要求计算聚合度，涉及基本公式应用（分子量除以单体分子量）和简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，只需要直接套用单一公式（聚合度=数均分子量/单体分子量）进行计算，无需额外步骤或复杂推导。题目中已给出所有必要参数，计算过程仅涉及基本除法运算。" + }, + { + "idx": 4481, + "question": "Compute the repeat unit molecular weight of polystyrene.", + "answer": "the repeat unit molecular weight of polystyrene is 104.14 g/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚苯乙烯重复单元的分子量，需要应用化学公式进行数值计算，答案是一个具体的数值结果(104.14 g/mol)。 | 知识层次: 题目要求计算聚苯乙烯重复单元的分子量，这需要应用基本的化学分子量计算公式，涉及简单的数值计算和直接套用公式，属于基本公式应用和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用单一公式（苯乙烯重复单元的分子量计算）即可得出结果，无需任何公式组合或复杂步骤。" + }, + { + "idx": 4482, + "question": "Compute the number-average molecular weight for a polystyrene for which the degree of polymerization is 25,000.", + "answer": "the number-average molecular weight for a polystyrene with a degree of polymerization of 25,000 is 2.60 x 10^6 g/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出聚合物的数均分子量，需要应用公式和数值计算，答案是一个具体的数值结果。 | 知识层次: 题目要求计算聚合物的数均分子量，仅需应用基本公式（分子量 = 聚合度 × 重复单元分子量）并进行简单计算，无需多步推理或综合分析。 | 难度: 在计算题-需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目仅要求套用已知的聚合度与分子量关系公式（Mn = DP × M0），其中聚苯乙烯的重复单元分子量（M0）为104 g/mol是已知常数。计算过程仅涉及一次乘法运算，无需多步推导或复杂公式组合，完全符合等级1的单一公式直接计算特征。" + }, + { + "idx": 4483, + "question": "High-density polyethylene may be chlorinated by inducing the random substitution of chlorine atoms for hydrogen. Determine the concentration of Cl (in wt%) that must be added if this substitution occurs for 5% of all the original hydrogen atoms.", + "answer": "the concentration of Cl that must be added is 20.3 wt%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氯的浓度（wt%），答案是一个具体的数值（20.3 wt%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括确定原始氢原子的数量、计算被氯取代的氢原子数量，以及最终计算氯的质量百分比。这涉及到对高密度聚乙烯分子结构的理解以及化学计量学的应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要理解高密度聚乙烯的氯化反应机理，进行多步计算（包括原子替换比例计算、分子量转换和浓度百分比计算），并综合应用化学计量学和材料科学知识。虽然不涉及复杂多变量，但解题步骤较多且需要概念关联，符合等级3的特征。" + }, + { + "idx": 4484, + "question": "In what ways does this chlorinated polyethylene differ from poly(vinyl chloride)?", + "answer": "chlorinated polyethylene differs from poly(vinyl chloride) in that, for pvc, (1) 25% of the side-bonding sites are substituted with Cl, and (2) the substitution is probably much less random.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种材料的不同之处，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较两种高分子材料的差异，涉及对材料结构和取代方式的理解，需要将多个知识点关联起来进行分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对两种高分子材料的结构差异进行多角度分析论述。不仅需要指出氯含量差异（25% vs 随机分布），还需要说明取代方式的本质区别（有序取代 vs 随机取代）。这涉及到对高分子化学合成方法和结构特性的深入理解，超越了简单的概念复述，属于需要综合应用知识的论述题。在同题型内，其难度高于只需单一知识点说明的题目（等级3），但尚未达到需要跨学科深度关联分析的等级5水平。" + }, + { + "idx": 4485, + "question": "Make comparisons of thermoplastic and thermosetting polymers on the basis of mechanical characteristics upon heating.", + "answer": "Thermoplastic polymers soften when heated and harden when cooled, whereas thermosetting polymers harden upon heating, while further heating will not lead to softening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对热塑性聚合物和热固性聚合物在加热时的机械特性进行比较，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物在加热时机械特性的基本概念记忆和理解，属于基础概念层次的认知能力。 | 难度: 在简答题中属于中等难度，需要对热塑性聚合物和热固性聚合物的机械特性进行比较和解释，但不需要深入阐述复杂的理论或机制。" + }, + { + "idx": 4486, + "question": "Make comparisons of thermoplastic and thermosetting polymers according to possible molecular structures.", + "answer": "Thermoplastic polymers have linear and branched structures, while for thermosetting polymers, the structures will normally be network or crosslinked.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对热塑性聚合物和热固性聚合物的分子结构进行比较，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物分子结构的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较热塑性聚合物和热固性聚合物的分子结构，这需要对两种聚合物的基本结构特征有清晰的理解和记忆。虽然需要一定的知识掌握，但不需要复杂的分析或深入的阐述，属于中等难度的概念解释题。" + }, + { + "idx": 4487, + "question": "Is it possible to grind up and reuse phenol-formaldehyde? Why or why not?", + "answer": "It is not possible to grind up and reuse phenol-formaldehyde because it is a network thermoset polymer and, therefore, is not amenable to remolding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要解释为什么不能磨碎和重复使用酚醛树脂，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对热固性聚合物基本特性的记忆和理解，涉及酚醛树脂的不可重复加工性这一基础概念，无需复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释为什么酚醛树脂不能研磨再利用，这需要学生理解热固性聚合物的基本特性（网络结构、不可逆固化等），并能够将这些概念联系起来进行解释。虽然涉及多个概念，但不需要构建复杂的理论体系或进行深入分析，因此属于中等难度。" + }, + { + "idx": 4488, + "question": "Is it possible to grind up and reuse polypropylene? Why or why not?", + "answer": "Yes, it is possible to grind up and reuse polypropylene since it is a thermoplastic polymer, will soften when reheated, and, thus, may be remolded.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述为什么可以或不可以磨碎和再利用聚丙烯，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对聚丙烯（polypropylene）基本特性的记忆和理解，即它是一种热塑性聚合物，可以通过加热软化并重新塑形。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释聚丙烯是否可以研磨和重复使用的原因，涉及对热塑性聚合物基本特性的理解和描述，但不需要复杂的体系阐述或多层次分析。回答需要记忆聚丙烯的基本性质并简要解释其可回收性，属于中等难度的概念解释题。" + }, + { + "idx": 4489, + "question": "The number-average molecular weight of a poly(styrene-butadiene) alternating copolymer is 1,350,000g / mol; determine the average number of styrene and butadiene repeat units per molecule.", + "answer": "the average number of styrene and butadiene repeat units per molecule is 8530.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定共聚物中苯乙烯和丁二烯重复单元的平均数量，答案是一个具体的数值结果，解答过程需要应用分子量计算公式。 | 知识层次: 题目需要应用分子量的计算公式，并进行多步计算以确定重复单元的数量。虽然涉及基本概念，但需要理解和关联多个知识点（如分子量计算、重复单元分子量等），并进行综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解聚合物的分子量计算原理，掌握重复单元分子量的计算方法，并进行多步骤的数值运算。虽然计算过程较为直接，但需要综合应用多个概念和公式，属于中等应用层次的计算题。" + }, + { + "idx": 4490, + "question": "Calculate the number-average molecular weight of a random nitrile rubber [poly(acrylonitrilebutadiene) copolymer] in which the fraction of butadiene repeat units is 0.30 ; assume that this concentration corresponds to a degree of polymerization of 2000 .", + "answer": "the number-average molecular weight of the nitrile rubber copolymer is \\bar{m}_{n} = 106740, \\text{g/mol}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算数均分子量），并给出了具体的计算条件和参数（重复单元分数和聚合度）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及分子量的计算和重复单元分数的应用，需要理解并关联多个概念，如聚合度、重复单元分子量等，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解共聚物的组成比例和聚合度的概念，并进行多步计算。题目涉及分子量的加权平均计算，需要将不同单体的分子量与其在共聚物中的比例结合，并考虑聚合度的影响。虽然计算步骤明确，但需要综合应用多个知识点，属于中等偏上的难度。" + }, + { + "idx": 4491, + "question": "An alternating copolymer is known to have a number-average molecular weight of 250,000g / mol and a degree of polymerization of 3420 . If one of the repeat units is styrene, which of ethylene, propylene, tetrafluoroethylene, and vinyl chloride is the other repeat unit? ", + "answer": "propylene", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（ethylene, propylene, tetrafluoroethylene, and vinyl chloride）中选择正确的重复单元，符合选择题的特征。 | 知识层次: 题目需要计算分子量并分析共聚物的重复单元，涉及多步计算和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要综合运用分子量计算、聚合度概念以及单体分子量的知识。解题步骤包括：1) 计算共聚物的平均重复单元分子量；2) 已知苯乙烯的分子量，求另一单体的分子量；3) 在给定选项中匹配计算结果。这需要多步计算和概念关联，比简单的概念选择题更复杂，但尚未达到最高难度的综合应用水平。" + }, + { + "idx": 4492, + "question": "(a) Determine the ratio of butadiene to styrene repeat units in a copolymer having a number-average molecular weight of 350,000 g/mol and degree of polymerization of 4425.", + "answer": "1.0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定共聚物中丁二烯与苯乙烯重复单元的比例，涉及分子量和聚合度的数值计算，答案以数值形式给出。 | 知识层次: 题目需要进行多步计算，涉及分子量、重复单元比例和聚合度的概念关联和综合分析，需要理解并应用相关公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用分子量计算、重复单元比例计算等多步骤公式，并理解共聚物结构概念。虽然计算过程明确，但需要将多个概念关联起来综合分析，属于中等偏上的难度。" + }, + { + "idx": 4493, + "question": "(b) Which type(s) of copolymer(s) will this copolymer be, considering the following possibilities: random, alternating, graft, and block?", + "answer": "random, alternating, graft, and block", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（random, alternating, graft, and block）中选择正确的类型，符合选择题的特征。 | 知识层次: 题目考查对共聚物类型（随机、交替、接枝、嵌段）的基本概念记忆和分类理解，属于基础概念层面的知识。 | 难度: 该题目属于基础概念记忆的选择题，仅要求识别和回忆不同类型的共聚物（random, alternating, graft, block），无需进行概念辨析或深度理解。在选择题题型中，这类直接记忆的题目属于最简单的难度等级。" + }, + { + "idx": 4494, + "question": "Crosslinked copolymers consisting of 60 wt% ethylene and 40 wt% propylene may have elastic properties similar to those for natural rubber. For a copolymer of this composition, determine the fraction of both repeat unit types.", + "answer": "the fraction of the ethylene repeat unit is f(\\text{ethylene}) = 0.69 . the fraction of the propylene repeat unit is f(\\text{propylene}) = 0.31 .", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算确定乙烯和丙烯重复单元的比例，答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及基本的重量百分比转换为摩尔分数的计算，需要应用简单的公式和单位转换，属于直接套用基本知识的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要根据给定的重量百分比，通过简单的分子量计算和比例转换，直接套用公式得出重复单元的比例。没有涉及多个公式的组合或复杂的解题步骤。" + }, + { + "idx": 4495, + "question": "Explain briefly why the tendency of a polymer to crystallize decreases with increasing molecular weight.", + "answer": "The tendency of a polymer to crystallize decreases with increasing molecular weight because as the chains become longer it is more difficult for all regions along adjacent chains to align so as to produce the ordered atomic array.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释聚合物结晶倾向随分子量增加而降低的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高分子材料结晶倾向与分子量之间的关系，涉及高分子链排列和有序结构的形成机理，需要综合运用高分子物理知识进行推理分析，属于对材料科学原理的深入理解和解释。 | 难度: 在简答题的复杂分析题型中，该题目要求对高分子结晶行为与分子量关系的机理进行深度解释。需要综合运用高分子物理知识，理解链段排列的动力学限制，并能够逻辑清晰地阐述长链分子对有序排列的影响机制。虽然不涉及多因素交互作用的全面分析（等级5特征），但已超出基础概念复述层面，属于需要机理深度解释的等级4难度。" + }, + { + "idx": 4496, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (a) Linear and syndiotactic poly(vinyl chloride); linear and isotactic polystyrene.", + "answer": "Yes, for these two polymers it is possible to decide. The linear and syndiotactic poly(vinyl chloride) is more likely to crystallize; the phenyl side-group for polystyrene is bulkier than the Cl side-group for poly(vinyl chloride). Syndiotactic and isotactic isomers are equally likely to crystallize.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同聚合物对进行判断，并解释原因或说明无法判断的理由。答案需要文字解释和论述，而不是简单的选择或计算。 | 知识层次: 题目要求对不同聚合物的结晶可能性进行比较和解释，涉及对聚合物结构（线性、间规立构、等规立构）和侧基效应的理解，需要综合分析多个因素（如侧基体积、立构规整度）对结晶能力的影响。虽然不涉及复杂计算，但需要对材料科学中的结晶原理有较深入的理解和应用能力。 | 难度: 在简答题题型中，该题目要求对两种聚合物的结晶可能性进行比较分析，涉及对聚合物结构（线性、间规立构、等规立构）和侧基体积效应的理解。需要综合运用高分子结晶原理、立体化学知识以及结构-性能关系进行多角度论述，且需明确指出判断依据（如苯基侧基比氯侧基体积大）。虽然不需要进行深度关联性分析（如结晶动力学或热力学计算），但已超出基础概念复述层面，属于需要中等应用能力的综合分析题。" + }, + { + "idx": 4497, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (b) Network phenol-formaldehyde; linear and heavily crosslinked cis-isoprene.", + "answer": "No, it is not possible to decide for these two polymers. Both heavily crosslinked and network polymers are not likely to crystallize.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行判断，并给出理由或解释为什么无法判断。这需要文字解释和论述，而不是简单的选择或判断对错。 | 知识层次: 题目要求学生能够理解并应用聚合物结晶性的基本原理，对不同类型聚合物（网络结构和高度交联结构）的结晶可能性进行比较和分析。这需要学生不仅记住基本概念，还要能够将多个知识点（如聚合物结构、结晶条件、交联影响等）进行关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要学生理解并分析两种不同类型聚合物的结晶可能性。题目要求对网络酚醛树脂和线性高度交联的顺式异戊二烯的结晶性进行比较和判断，涉及对聚合物结构（网络结构和交联程度）与结晶能力之间关系的理解。虽然题目提供了具体聚合物案例，但需要学生综合运用聚合物结晶的基本原理和结构特征知识进行判断。解题步骤包括：(1)识别聚合物类型和结构特征；(2)分析这些特征对结晶能力的影响；(3)得出结论并解释原因。这比简单回忆知识点更复杂，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 4498, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (c) Linear polyethylene; lightly branched isotactic polypropylene.", + "answer": "Yes, it is possible to decide for these two polymers. The linear polyethylene is more likely to crystallize. The repeat unit structure for polypropylene is chemically more complicated than is the repeat unit structure for polyethylene. Furthermore, branched structures are less likely to crystallize than are linear structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行比较，并给出理由或解释为什么无法决定。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求学生比较两种聚合物的结晶倾向，需要理解聚合物结构（线性与支化）对结晶能力的影响，并能够分析化学结构的复杂性对结晶的影响。这涉及到多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求进行多角度分析论述。首先需要判断是否可能比较两种聚合物的结晶倾向，然后需要基于化学结构和分支情况给出具体理由。这涉及到对聚合物结晶原理的深入理解，以及对不同结构影响的综合分析。题目不仅要求识别关键因素（线性vs支化结构、重复单元复杂性），还需要将这些因素关联起来进行系统论述，符合等级4\"多角度分析论述\"的标准。" + }, + { + "idx": 4499, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (d) Alternating poly(styrene-ethylene) copolymer; random poly(vinyl chloride-tetrafluoroethylene) copolymer.", + "answer": "Yes, it is possible to decide for these two copolymers. The alternating poly(styrene-ethylene) copolymer is more likely to crystallize. Alternating copolymers crystallize more easily than do random copolymers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释哪一种更容易结晶以及原因。这需要详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求学生能够理解并应用聚合物结晶性的基本原理，比较两种共聚物的结晶倾向。这需要学生不仅记住交替共聚物和随机共聚物的定义，还需要理解它们的结构差异如何影响结晶能力，并进行综合分析。虽然不涉及复杂的计算或深度机理分析，但需要一定的概念关联和推理能力。 | 难度: 在简答题中属于中等难度，需要理解并比较两种共聚物的结晶倾向性，涉及对交替共聚物和随机共聚物结晶能力的知识掌握，并进行简单的分析和说明。虽然需要一定的概念关联和综合分析，但解题步骤相对直接，不涉及多角度或深度关联性分析。" + }, + { + "idx": 4500, + "question": "Consider the diffusion of water vapor through a polypropylene (PP) sheet 2mm thick. The pressures of H_{2} \\mathrm{O} at the two faces are 1 kPa and 10 kPa, which are maintained constant. Assuming conditions of steady state, what is the diffusion flux [in \\left[{cm}^{3} STP\\right] / {cm}^{2}-s ] at 298 K ?", + "answer": "the diffusion flux is 1.71 × 10^{-7} \\ \\text{cm}^{3}\\text{stp}/\\text{cm}^{2}-\\text{s}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散通量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及稳态扩散条件下的扩散通量计算，需要直接套用菲克第一定律公式，并进行单位转换。虽然涉及单位转换，但整体思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目要求计算水蒸气通过聚丙烯片的扩散通量，只需要直接应用菲克第一定律（Fick's First Law）进行简单计算，无需多个公式组合或复杂步骤。题目中给出了所有必要的参数（厚度、压力差、温度），计算过程直接且明确。" + }, + { + "idx": 4501, + "question": "Argon diffuses through a high density polyethylene (HDPE) sheet 40mm thick at a rate of 4.0 × 10^{-7} \\left({cm}^{3} STP / {cm}^{2}-s\\right. at 325 K. The pressures of argon at the two faces are 5000 kPa and 1500 kPa, which are maintained constant. Assuming conditions of steady state, what is the permeability coefficient at 325 K ?", + "answer": "the permeability coefficient of ar through hdpe at 325k is 4.57 × 10^{-13} \\frac{{cm}^{3} \\mathrm{stp}·{cm}}{{cm}^{2}-s-\\mathrm{pa}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解渗透系数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和稳态条件，进行综合分析以求解渗透系数。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律和稳态条件进行多步计算，涉及单位转换和压力差处理，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4502, + "question": "The permeability coefficient of a type of small gas molecule in a polymer is dependent on absolute temperature according to the following equation:\n\\[\nP_{M}=P_{M_{0}} \\exp \\left(-\\frac{Q_{p}}{R T}\\right)\n\\]\nwhere P_{M_{0}} and Q_{p} are constants for a given gas-polymer pair. Consider the diffusion of hydrogen through a poly(dimethyl siloxane) (PDMSO) sheet 20mm thick. The hydrogen pressures at the two faces are 10 kPa and 1 kPa, which are maintained constant. Compute the diffusion flux [in \\left({cm}^{3} STP\\right) / {cm}^{2}-s ] at 350 K. For this diffusion system\n\\[\n\\begin{array}{l}\nP_{M_{0}}=1.45 × 10^{-8}\\left(cm^{3} STP\\right)\\left({cm}^{3} / {cm}^{2}-s-\\mathrm{Pa}\\right. \\\\\nQ_{p}=13.7kJ / mol\n\\end{array}\n\\]\nAlso, assume a condition of steady state diffusion", + "answer": "the diffusion flux is 5.90 × 10^{-7} \\frac{\\text{cm}^{3} \\text{stp}}{\\text{cm}^{2}·\\text{s}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（扩散通量）。解答过程涉及公式应用和单位转换，属于典型的计算题。 | 知识层次: 题目涉及多步计算和公式应用，需要理解渗透系数与温度的关系，并运用给定的参数进行数值计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要应用给定的公式进行多步计算，包括温度依赖的渗透系数计算、压力差导致的扩散通量计算等。虽然涉及多个步骤和概念关联，但题目提供了所有必要的参数和明确的指导，因此属于中等难度。" + }, + { + "idx": 4503, + "question": "For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to\n\\[\n\\sigma(t)=\\sigma(0) \\exp \\left(-\\frac{t}{\\tau}\\right)\n\\]\nwhere \\sigma(t) and \\sigma(t) represent the time-dependent and initial (i.e., time =0 ) stresses, respectively, and t and \\tau denote elapsed time and the relaxation time; \\tau is a time-independent constant characteristic of the material. A specimen of some viscoelastic polymer the stress relaxation of which obeys Equation 15.10 was suddenly pulled in tension to a measured strain of 0.6 ; the stress necessary to maintain this constant strain was measured as a function of time. Determine E_{\\tau}(10) for this material if the initial stress level was 2.76 MPa(400 psi), which dropped to 1.72 MPa (250 psi) after 60s.", + "answer": "e_{\\tau}(10) = 4.25 \\text{ mpa (616 psi)}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和初始条件进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和数值代入，符合计算题的特征。 | 知识层次: 题目需要应用给定的应力松弛公式进行多步计算，包括初始应力和时间变化后的应力关系，以及计算特定时间点的模量。虽然公式直接给出，但需要理解公式中各参数的含义并进行适当的代数运算和单位转换，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解应力松弛公式并应用初始条件和时间条件求解松弛时间常数，然后进一步计算特定时间点的松弛模量。解题步骤涉及多步计算和概念关联，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4504, + "question": "(a) Contrast the manner in which stress relaxation and viscoelastic creep tests are conducted.", + "answer": "Stress relaxation tests are conducted by rapidly straining the material elastically in tension, holding the strain level constant, and then measuring the stress as a function of time. For viscoelastic creep tests, a stress (usually tensile) is applied instantaneously and maintained constant while strain is measured as a function of time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对比两种测试方法的具体操作过程，需要文字解释和论述，没有提供选项或要求计算，属于简答题类型。 | 知识层次: 题目考查对两种测试方法的基本概念和操作步骤的记忆和理解，属于基础概念层次。 | 难度: 在简答题中属于中等难度，需要解释和描述两个不同的测试方法（应力松弛和粘弹性蠕变测试），并对比它们的实验过程。虽然不涉及复杂的概念体系阐述，但需要清晰表达两者的区别和各自的测试步骤。" + }, + { + "idx": 4505, + "question": "(b) For each of these tests, cite the experimental parameter of interest and how it is determined.", + "answer": "The experimental parameters of interest from the stress relaxation and viscoelastic creep tests are the relaxation modulus and creep modulus (or creep compliance), respectively. The relaxation modulus is the ratio of stress measured after 10 s and strain; creep modulus is the ratio of stress and strain taken at a specific time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释实验参数及其确定方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对松弛模量和蠕变模量这两个基本概念的记忆和理解，以及它们在实验中的确定方法。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求解释实验参数及其确定方法，但涉及的知识点（松弛模量和蠕变模量）是基础概念，且解题步骤较为直接，只需准确描述这两个参数的定义和测量方式即可。相较于等级1的基本定义简答，此题需要更多的解释性内容；但相较于等级3的复杂概念体系阐述，此题的知识点较为单一，不需要深入分析或综合多个概念。" + }, + { + "idx": 4506, + "question": "For thermoplastic polymers, cite five factors that favor brittle fracture.", + "answer": "For thermoplastic polymers, five factors that favor brittle fracture are as follows: (1) a reduction in temperature, (2) an increase in strain rate, (3) the presence of a sharp notch, (4) increased specimen thickness, and (5) modifications of the polymer structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举五个因素，答案以文字解释和论述的形式给出，没有选项或计算要求 | 知识层次: 题目主要考查对热塑性聚合物脆性断裂影响因素的基本记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要列举五个因素，但每个因素都是基础概念记忆性知识，不需要复杂的推理或深入分析。题目要求的是对已知基本原理的回忆和简单阐述，而非构建复杂的概念体系或进行多步骤的论证。" + }, + { + "idx": 4507, + "question": "For the pair of polymers: random acrylonitrile-butadiene copolymer with 10% of possible sites crosslinked; alternating acrylonitrile-butadiene copolymer with 5% of possible sites crosslinked, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why.", + "answer": "No, it is not possible. The random acrylonitrile-butadiene copolymer will tend to a lower degree of crystallinity than the alternating acrylonitrile-butadiene copolymer inasmuch as random copolymers don't normally crystallize. On this basis only, the alternating material would have a higher modulus inasmuch as tensile modulus increases with degree of crystallinity. On the other hand, the random copolymer has a higher degree of crosslinking (10% versus 5% for the alternating copolymer), and, on this basis only would have the higher tensile modulus-an increase in crosslinking leads to an increase in E. Thus, this determination is not possible; with regard to degree of crystallinity the alternating material has the higher E, whereas the random copolymer would have a higher E value on the basis of degree of crosslinking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，需要分析两种聚合物的不同特性（结晶度和交联度）对拉伸模量的影响，并给出详细的理由说明为何无法确定哪种聚合物具有更高的拉伸模量。答案不是简单的选择或判断，而是需要详细的论述。 | 知识层次: 题目要求综合分析两种不同结构（随机共聚物和交替共聚物）和不同交联度对拉伸模量的影响，需要理解并权衡结晶度和交联度对材料性能的相反作用机制。这涉及多个概念的关联和推理分析，超出了简单应用或中等应用的范畴，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用多个高分子材料科学的核心概念（如结晶度、交联度对拉伸模量的影响），并进行相互矛盾的机理分析（结晶度与交联度对模量的相反影响）。解题需要同时处理两种不同的结构特征（无规共聚与交替共聚）和两种改性参数（不同交联度），最终得出无法确定结论的辩证性判断。这完全符合等级5\"复杂现象全面分析\"的标准，需要最高层次的概念整合和矛盾分析能力。" + }, + { + "idx": 4508, + "question": "For the pair of polymers: branched and syndiotactic polypropylene with a degree of polymerization of 5000; linear and isotactic polypropylene with a degree of polymerization of 3000, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why.", + "answer": "Yes, it is possible. The linear and isotactic polypropylene will have a greater tensile modulus. Linear polymers are more likely to crystallize that branched ones. ", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断是否可能比较两种聚合物的拉伸模量、说明哪种聚合物具有更高的拉伸模量以及解释原因。答案也以文字形式给出，没有涉及计算或选择选项。 | 知识层次: 题目要求比较两种不同结构的聚丙烯的拉伸模量，需要理解聚合物结构（支化与线性、等规与间规）对结晶度和力学性能的影响，并进行综合分析。虽然不涉及复杂计算，但需要关联多个概念并给出合理的解释。 | 难度: 在简答题中属于中等难度，需要理解聚合物的结构（支化与线性、等规与间规）对力学性能的影响，并进行比较分析。虽然题目涉及多个概念，但解题步骤相对直接，主要考察对聚合物结构与性能关系的掌握程度。" + }, + { + "idx": 4509, + "question": "For the pair of polymers: branched polyethylene with a number-average molecular weight of 250000 g/mol; linear and isotactic poly(vinyl chloride) with a number-average molecular weight of 200000 g/mol, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why.", + "answer": "No, it is not possible. Linear polymers have higher degrees of crystallization (and higher tensile moduli) than branched polymers - on this basis, the PVC material should have the higher value of E. On the other hand, PVC has a more complex repeat unit structure than does polyethylene, which means that, on this basis, the PE would have a higher degree of crystallinity and also a greater tensile modulus. Also, tensile modulus is relatively independent of number-average molecular weight. Therefore, this determination is not possible since it is not possible to determine which of the two materials has the greater degree of crystallinity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，涉及对两种聚合物性能的比较和分析，需要详细的理由说明，而不是简单的选择或判断。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求综合运用聚合物结构（支化与线性）、分子量、结晶度与拉伸模量的关系进行推理分析，涉及多个概念的关联和比较，需要深入理解材料性能与结构之间的关系，并进行综合判断。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4510, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. Syndiotactic polystyrene having a number-average molecular weight of 600,000 g/mol; atactic polystyrene having a number-average molecular weight of 500,000 g/mol", + "answer": "Yes it is possible. The syndiotactic polystyrene has the higher tensile strength. Syndiotactic polymers are more likely to crystallize than atactic ones; the greater the crystallinity, the higher the tensile strength. Furthermore, the syndiotactic also has a higher molecular weight; increasing molecular weight also enhances the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较两种聚合物的拉伸强度并给出理由，或解释为何无法判断。答案需要详细的文字说明而非简单的选择或计算。 | 知识层次: 题目要求比较两种聚合物的拉伸强度，并解释原因。这需要理解分子量、立体规整性和结晶度对材料性能的影响，属于多个概念的关联和综合分析。虽然不涉及复杂计算，但需要对材料科学中的基本原理有较深入的理解和应用能力。 | 难度: 在简答题题型中，该题目要求进行多角度分析论述。学生需要综合运用关于聚合物结构（如立体规整性）、分子量对性能的影响以及结晶度与力学性能关系的知识。解题步骤包括：(1)判断是否可比较强度，(2)选择强度更高的聚合物，(3)提供两个独立的科学依据（立体规整性导致的结晶度差异和分子量差异）。这超出了简单概念复述（等级3），但尚未达到需要深度关联多个学科知识的程度（等级5）。" + }, + { + "idx": 4511, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. Random acrylonitrile-butadiene copolymer with 10% of possible sites crosslinked; block acrylonitrile-butadiene copolymer with 5% of possible sites crosslinked", + "answer": "No it is not possible. The random acrylonitrile-butadiene copolymer has more crosslinking; increased crosslinking leads to an increase in strength. However, the block copolymeric material will most likely have a higher degree of crystallinity; and increasing crystallinity improves the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因。答案需要详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对两种聚合物（随机共聚物和嵌段共聚物）的拉伸强度进行比较，涉及交联度和结晶度对材料性能的影响。需要综合运用材料科学中的多个概念（交联、结晶度、共聚物类型）进行推理分析，并解释机理。这属于复杂分析层次，因为不仅需要理解各个概念，还需要将它们关联起来进行综合判断和解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对两种不同结构的共聚物（随机共聚物和嵌段共聚物）的拉伸强度进行综合比较分析。需要考虑交联度和结晶度两个相互影响的因素，并解释它们对材料强度的相反作用机制。这种需要同时处理多个变量并分析其相互作用的题目，在该题型中属于最高难度的复杂现象全面分析层次。" + }, + { + "idx": 4512, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. Network polyester; lightly branched polypropylene", + "answer": "Yes it is possible. The network polyester will display a greater tensile strength. Relative chain motion is much more restricted than for the lightly branched polypropylene since there are many more of the strong covalent bonds for the network structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并给出理由，需要文字解释和论述，而不是简单的选择或判断。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因。这需要理解聚合物结构与性能之间的关系，以及网络结构和支化结构对力学性能的影响。虽然不涉及复杂的计算或深度机理分析，但需要综合应用多个概念进行判断和解释，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求对两种聚合物的拉伸强度进行比较，但解题过程主要涉及对网络结构和轻度支化结构的理解，以及它们对材料性能的影响。这需要学生掌握相关概念并能进行简单的综合分析，但不需要进行多角度或深度关联性分析。因此，在简答题的框架内，该题目属于中等难度。" + }, + { + "idx": 4513, + "question": "List the two molecular characteristics that are essential for elastomers.", + "answer": "Two molecular characteristics essential for elastomers are: (1) they must be amorphous, having chains that are extensively coiled and kinked in the unstressed state; and (2) there must be some crosslinking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出弹性体的两个分子特性，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对弹性体基本分子特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列出弹性体的两个基本分子特性，并简要解释每个特性的含义。这需要学生对弹性体的基本概念有一定理解，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，此题需要更多的解释性内容；相比等级3的复杂概念体系阐述，此题的要求又相对简单直接。" + }, + { + "idx": 4514, + "question": "Name the following polymer(s) that would be suitable for the fabrication of cups to contain hot coffee: polyethylene, polypropylene, poly(vinyl chloride), PET polyester, and polycarbonate. Why?", + "answer": "This question asks us to name which, of several polymers, would be suitable for the fabrication of cups to contain hot coffee. At its glass transition temperature, an amorphous polymer begins to soften. The maximum temperature of hot coffee is probably slightly below 100^{\\circ} C\\left(212^{\\circ} F\\right). Of the polymers listed, only polystyrene and polycarbonate have glass transition temperatures of 100^{\\circ} C or above, and would be suitable for this application.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个聚合物中选择适合制作热咖啡杯的材料，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求从多个聚合物中选择适合制作热咖啡杯的材料，并解释原因。这需要理解聚合物的玻璃化转变温度及其在实际应用中的意义，涉及多步分析和概念关联。虽然不涉及复杂计算，但需要对材料性能和应用条件进行综合分析。 | 难度: 在简答题中属于中等难度，需要理解多个聚合物的玻璃转变温度概念，并进行综合分析以确定适合的聚合物。虽然题目提供了多个选项，但解答过程相对直接，主要涉及温度比较和材料特性分析，不需要多角度或深度关联性分析。" + }, + { + "idx": 4515, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Isotactic polystyrene that has a density of 1.12 g/cm3 and a weight-average molecular weight of 150,000 g/mol; syndiotactic polystyrene that has a density of 1.10 g/cm3 and a weight-average molecular weight of 125,000 g/mol", + "answer": "Yes, it is possible to determine which of the two polystyrenes has the higher Tm. The isotactic polystyrene will have the higher melting temperature because it has a higher density (i.e., less branching) and also the greater weight-average molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来判断两种聚合物的熔点高低，并给出理由。答案需要详细说明判断依据，而不是简单的选择或计算。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这需要理解聚合物结构（等规和间规）对性能的影响，以及密度和分子量对熔点的作用。虽然不涉及复杂计算，但需要综合分析多个因素（结构、密度、分子量）来得出结论，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解聚合物的结构（等规和间规）与性能（熔点）之间的关系，并进行密度和分子量的综合分析。虽然涉及多个概念，但解题步骤相对直接，不需要过于复杂的推导或深度关联性分析。" + }, + { + "idx": 4516, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Linear polyethylene that has a degree of polymerization of 5,000; linear and isotactic polypropylene that has a degree of polymerization of 6,500", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. The polypropylene will have the higher Tm because it has a bulky phenyl side group in its repeat unit structure, which is absent in the polyethylene. Furthermore, the polypropylene has a higher degree of polymerization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并给出理由。这需要文字解释和论述，而不是简单的选择、判断或计算。答案也包含了详细的解释和原因说明，符合简答题的特征。 | 知识层次: 题目要求学生比较两种聚合物的熔点，并解释原因。这涉及到对聚合物结构（线性聚乙烯和线性等规聚丙烯）和聚合度对熔点影响的理解，以及如何将这些概念应用于具体案例的分析。虽然不需要复杂的计算或深度推理，但需要综合多个因素（如侧基效应和聚合度）来得出结论，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求进行多角度分析论述。首先需要判断是否可能比较两种聚合物的熔点，然后需要从分子结构（苯基侧基的存在）和聚合度两个维度进行综合分析，最后得出结论。这涉及到对高分子材料结构和性能关系的深入理解，以及将多个因素关联起来的能力，符合等级4的多角度分析论述要求。" + }, + { + "idx": 4517, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Branched and isotactic polystyrene that has a degree of polymerization of 4,000; linear and isotactic polypropylene that has a degree of polymerization of 7,500", + "answer": "No, it is not possible to determine which of the two polymers has the higher melting temperature. The polystyrene has a bulkier side group than the polypropylene; on the basis of this effect alone, the polystyrene should have the greater Tm. However, the polystyrene has more branching and a lower degree of polymerization; both of these factors lead to a lowering of the melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并详细解释原因或说明无法比较的理由。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的熔点，涉及对聚合物结构（支化、等规性）、分子量（聚合度）以及侧基体积效应的综合分析。需要理解这些因素如何影响熔点，并进行权衡判断。虽然不涉及复杂计算，但需要对多个概念进行关联和综合应用。 | 难度: 在简答题题型中，该题目要求对两种聚合物的多个特性（支化度、立构规整性、聚合度）进行综合分析，并解释这些因素如何相互影响熔点。需要考生不仅掌握单个概念，还要能够关联和权衡不同因素的影响，属于多角度分析论述的难度等级。" + }, + { + "idx": 4518, + "question": "Briefly explain the difference in molecular chemistry between silicone polymers and other polymeric materials.", + "answer": "The backbone chain of most polymers consists of carbon atoms that are linked together. For the silicone polymers, this backbone chain is composed of silicon and oxygen atoms that alternate positions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释两种聚合物在分子化学上的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对硅聚合物和其他聚合物分子化学差异的基本概念记忆和理解，仅需简单描述其分子链组成的区别，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释两种聚合物在分子化学上的差异，属于概念解释和描述的难度级别。虽然需要记忆硅氧主链和碳主链的基本区别，但不需要深入分析或比较复杂的化学性质或反应机理，因此不属于最高难度等级。" + }, + { + "idx": 4519, + "question": "List two important characteristics for polymers that are to be used in fiber applications.", + "answer": "Two important characteristics for polymers that are to be used in fiber applications are: (1) they must have high molecular weights, and (2) they must have chain configurations/structures that will allow for high degrees of crystallinity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个重要特性，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对聚合物纤维应用所需特性的基本概念记忆和理解，不涉及复杂分析或综合应用 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举聚合物用于纤维应用的两个重要特性，并简要解释这些特性的重要性。这需要学生对聚合物的基本特性及其在纤维应用中的具体要求有一定的理解和记忆，但不需要进行复杂的体系阐述或多层次的概念分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 4520, + "question": "Cite five important characteristics for polymers that are to be used in thin-film applications.", + "answer": "Five important characteristics for polymers that are to be used in thin-film applications are: (1) low density; (2) high flexibility; (3) high tensile and tear strengths; (4) resistance to moisture/chemical attack; and (5) low gas permeability.\n}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并简要说明聚合物在薄膜应用中需要具备的五个重要特性，答案以文字解释的形式呈现，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目主要考查对聚合物在薄膜应用中重要特性的记忆和列举，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求列举并简要说明聚合物在薄膜应用中的五个重要特性。虽然需要记忆多个特性，但不需要深入解释或复杂的概念体系阐述，属于概念解释和描述的难度等级。" + }, + { + "idx": 4521, + "question": "Cite the primary differences between addition and condensation polymerization techniques.", + "answer": "For addition polymerization, the reactant species have the same chemical composition as the monomer species in the molecular chain. This is not the case for condensation polymerization, wherein there is a chemical reaction between two or more monomer species, producing the repeating unit. There is often a low molecular weight by-product for condensation polymerization; such is not found for addition polymerization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种聚合技术的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对加成聚合和缩聚聚合两种技术的基本概念和主要差异的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求对两种聚合技术进行对比解释，涉及基本概念的定义和描述，但不需要深入阐述复杂的概念体系或进行多层次的推理分析。属于概念解释和描述的难度层级。" + }, + { + "idx": 4522, + "question": "Estimate the maximum thermal conductivity value for a cermet that contains 85 vol % titanium carbide (TiC) particles in a cobalt matrix. Assume thermal conductivities of 27 and 69 W/m-K for TiC and Co, respectively.", + "answer": "the maximum thermal conductivity k_max is 33.3 W/m-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计最大热导率值，答案是一个具体的数值结果（33.3 W/m-K），这表明需要进行计算步骤来得出答案。 | 知识层次: 题目需要应用热导率的混合规则进行多步计算，涉及不同材料的热导率数值和体积分数的综合计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料热导率的混合规则公式（如串联或并联模型），涉及多步计算和概念关联。虽然计算过程本身不复杂，但需要正确选择和应用理论模型，并对组分材料的热导率进行综合分析，属于中等应用层次的计算题。" + }, + { + "idx": 4523, + "question": "Estimate the minimum thermal conductivity value for a cermet that contains 85 vol % titanium carbide (TiC) particles in a cobalt matrix. Assume thermal conductivities of 27 and 69 W/m-K for TiC and Co, respectively.", + "answer": "the minimum thermal conductivity k_min is 29.7 W/m-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计cermet的最小热导率值，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及复合材料热导率的估算，需要理解并应用相关公式（如串联模型或并联模型），同时需要关联不同材料的热导率知识。虽然计算过程相对直接，但仍需要一定的综合分析能力来选择合适的模型进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料热导率的最小值计算公式，涉及多步计算和概念关联。虽然计算步骤明确，但需要对材料热导率的基本概念和复合材料的组成有清晰理解，属于中等应用层次的计算题。" + }, + { + "idx": 4524, + "question": "A large-particle composite consisting of tungsten particles within a copper matrix is to be prepared. If the volume fractions of tungsten and copper are 0.60 and 0.40 , respectively, estimate the upper limit for the specific stiffness of this composite given the data that follow.\n\\begin{tabular}{lcc}\n\\hline & Specific Gravity & \\begin{tabular}{c} \nModulus of Elasticity \\\\\n(GPa)\n\\end{tabular} \\\\\n\\hline Copper & 8.9 & 110 \\\\\nTungsten & 19.3 & 407 \\\\\n\\hline\n\\end{tabular}", + "answer": "the upper limit for the specific stiffness of this composite is 19.0 \\text{ gpa}. an alternate approach yields a specific stiffness of 17.6 \\text{ gpa}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式计算复合材料的比刚度上限，答案以数值形式给出，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用复合材料力学性能的计算公式，涉及多步计算和不同材料性能的综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料力学中的混合法则（Rule of Mixtures）进行多步计算，涉及体积分数、弹性模量和比重的综合运用。虽然计算步骤明确，但需要正确理解并关联多个概念（如比刚度定义、上限估计方法），且需注意单位转换（比重与密度的关系）。相比简单代入公式的题目（等级2），本题要求更高层次的概念整合能力，但尚未达到需要处理复杂边界条件或多变量优化的等级4难度。" + }, + { + "idx": 4525, + "question": "(a) What is the distinction between cement and concrete?", + "answer": "Concrete consists of an aggregate of particles that are bonded together by a cement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释水泥和混凝土之间的区别，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查基础概念的记忆和理解，要求区分水泥和混凝土的基本定义和组成，属于材料科学中最基础的概念性问题。 | 难度: 在简答题题型中，该题目仅要求回答水泥和混凝土的基本定义和区别，属于最基础的概念记忆性知识。题目不涉及复杂的概念解释或体系阐述，仅需简单陈述两者的组成关系即可。在同题型内属于最基础的难度等级。" + }, + { + "idx": 4526, + "question": "(b) Cite three important limitations that restrict the use of concrete as a structural material.", + "answer": "Three limitations of concrete are: (1) it is a relatively weak and brittle material; (2) it experiences relatively large thermal expansions (contractions) with changes in temperature; and (3) it may crack when exposed to freeze-thaw cycles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并简要说明混凝土作为结构材料的三个重要限制因素，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对混凝土作为结构材料局限性的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求列举并简要解释混凝土作为结构材料的三个重要限制因素。这属于概念解释和描述的难度等级，需要学生对混凝土的基本性能有一定了解，但不需要深入分析或构建复杂的概念体系。题目主要考察记忆和基础理解能力，属于中等偏基础的难度。" + }, + { + "idx": 4527, + "question": "(c) Briefly explain three techniques that are utilized to strengthen concrete by reinforcement.", + "answer": "Three reinforcement strengthening techniques are: (1) reinforcement with steel wires, rods, etc.; (2) reinforcement with fine fibers of a high modulus material; and (3) introduction of residual compressive stresses by prestressing or postensioning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释三种强化混凝土的技术，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目考查对混凝土增强技术的基本概念记忆和理解，仅需列举并简要解释三种增强技术，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释三种具体的混凝土增强技术，属于概念解释和描述的难度级别。虽然需要列举并简要说明三种技术，但不需要深入分析或构建复杂的概念体系，因此属于中等难度。" + }, + { + "idx": 4528, + "question": "Cite one similarity between precipitation hardening and dispersion strengthening.", + "answer": "The similarity between precipitation hardening and dispersion strengthening is the strengthening mechanism--i.e., the precipitates/particles effectively hinder dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述一个相似点，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对两种强化机制（沉淀硬化和弥散强化）的基本概念的理解和记忆，要求识别它们的共同点，属于基础概念的记忆和简单对比。 | 难度: 在简答题题型中，该题目要求解释两种强化机制的相似性，属于概念解释和描述层次。虽然需要理解两种强化机制的基本原理，但并不涉及复杂的概念体系阐述或深入的分析比较，因此属于中等难度。" + }, + { + "idx": 4529, + "question": "Cite two differences between precipitation hardening and dispersion strengthening.", + "answer": "The two differences are: (1) the hardening/strengthening effect is not retained at elevated temperatures for precipitation hardening--however, it is retained for dispersion strengthening; and (2) the strength is developed by a heat treatment for precipitation hardening--such is not the case for dispersion strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举两种区别，答案以文字解释和论述的形式给出，没有选项、判断或计算要求 | 知识层次: 题目要求比较两种强化机制的差异，涉及对两种机制的理解和关联分析，需要综合运用材料科学中的强化原理知识，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求列举两种强化方式的差异，但需要考生理解两种强化机制的基本原理（如温度影响和热处理过程），并能进行对比分析。这需要一定的概念关联能力，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4530, + "question": "A continuous and aligned fiber-reinforced composite is to be produced consisting of 30 vol% aramid fibers and 70 vol% of a polycarbonate matrix; mechanical characteristics of these two materials are as follows: Modulus of Elasticity for Aramid fiber is 131 GPa (19x10^6 psi) and Tensile Strength is 3600 MPa (520,000 psi); Modulus of Elasticity for Polycarbonate is 2.4 GPa (3.5x10^5 psi) and Tensile Strength is 65 MPa (9425 psi). Also, the stress on the polycarbonate matrix when the aramid fibers fail is 45 MPa (6500 psi). For this composite, compute the longitudinal tensile strength.", + "answer": "the longitudinal tensile strength is 1100 mpa (160,000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的纵向拉伸强度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括理解复合材料中各组分的作用、应用混合法则计算复合材料的纵向拉伸强度，以及考虑纤维和基体在失效时的应力状态。这需要将多个概念关联起来并进行综合分析，而不仅仅是简单的公式套用或基础概念的记忆。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料力学性能的基本概念，应用混合法则进行多步计算，并综合分析纤维和基体的力学特性对复合材料整体性能的影响。虽然计算步骤较多，但题目提供了所有必要的参数，且不需要处理复杂的多变量情况。" + }, + { + "idx": 4532, + "question": "For a continuous and oriented fiber-reinforced composite, the modulus of elasticity in the longitudinal direction is 19.7 GPa (2.8 x 10^5 psi). If the volume fraction of fibers is 0.25, determine the modulus of elasticity of the fiber phase.", + "answer": "the modulus of elasticity of the fiber phase e_f is 70.4 GPa (10.2 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如复合材料弹性模量的混合法则）来确定纤维相的弹性模量，答案是一个具体的数值结果。 | 知识层次: 题目需要应用复合材料弹性模量的混合法则公式进行多步计算，涉及不同相（纤维和基体）的弹性模量关联分析，需要理解复合材料的基本原理并进行综合计算。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料弹性模量的混合法则公式，进行多步计算和变量求解。题目要求将已知的整体模量和纤维体积分数代入公式，反推纤维相的模量，涉及概念关联和综合分析，但计算过程相对直接，没有复杂多变量或高阶数学要求。" + }, + { + "idx": 4533, + "question": "For a continuous and oriented fiber-reinforced composite, the modulus of elasticity in the transverse direction is 3.66 GPa (5.3 x 10^5 psi). If the volume fraction of fibers is 0.25, determine the modulus of elasticity of the matrix phase.", + "answer": "the modulus of elasticity of the matrix phase e_m is 2.79 GPa (4.04 x 10^5 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定基体相的弹性模量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用复合材料横向弹性模量的计算公式，涉及多步计算和概念关联，但不需要复杂的推理分析或深度理解。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料力学中的横向弹性模量公式，涉及多步计算和概念关联。题目要求根据已知的横向弹性模量和纤维体积分数，反推出基体相的弹性模量，这需要理解复合材料各相之间的相互作用关系，并进行适当的代数运算。虽然计算步骤不算极其复杂，但需要对相关公式和概念有较好的掌握，因此在该题型内属于中等偏上的难度。" + }, + { + "idx": 4534, + "question": "In an aligned and continuous glass fiber-reinforced nylon 6,6 composite, the fibers are to carry 94% of a load applied in the longitudinal direction. Using the data provided, determine the volume fraction of fibers that will be required.", + "answer": "the required volume fraction of fibers is 0.393.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定纤维的体积分数，答案是一个具体的数值（0.393），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及纤维增强复合材料中载荷分配的基本原理和公式应用，需要理解纤维和基体在载荷传递中的作用，并进行综合分析以确定纤维的体积分数。虽然不涉及复杂的机理分析或创新设计，但超出了简单直接套用公式的层次。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料中纤维和基体的载荷分配原理，应用相关公式进行多步计算，并综合分析给定的条件（纤维承载比例）来求解纤维体积分数。虽然不涉及复杂多变量计算，但需要概念关联和综合分析能力。" + }, + { + "idx": 4535, + "question": "In an aligned and continuous glass fiber-reinforced nylon 6,6 composite, the fibers are to carry 94% of a load applied in the longitudinal direction. What will be the tensile strength of this composite? Assume that the matrix stress at fiber failure is 30 MPa (4350 psi).", + "answer": "the tensile strength of this composite is 1354 mpa (196,400 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的拉伸强度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及复合材料中纤维和基体的应力分配，需要应用相关公式并综合分析纤维和基体的贡献。虽然计算过程较为直接，但需要理解复合材料的基本原理和应力分配的概念。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料力学的基本概念，应用载荷分配原理，并进行多步计算。虽然涉及多个步骤和概念关联，但变量相对明确，计算过程较为直接，因此属于中等偏上的难度等级。" + }, + { + "idx": 4536, + "question": "For a polymer-matrix fiber-reinforced composite, list three functions of the matrix phase.", + "answer": "For polymer-matrix fiber-reinforced composites, three functions of the polymer-matrix phase are: (1) to bind the fibers together so that the applied stress is distributed among the fibers; (2) to protect the surface of the fibers from being damaged; and (3) to separate the fibers and inhibit crack propagation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出聚合物基纤维增强复合材料中基体相的三个功能，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目考查对聚合物基纤维增强复合材料中基体相功能的基本概念记忆和理解，属于基础知识的直接回忆和列举。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列出聚合物基体相在纤维增强复合材料中的三个功能，这需要学生对基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。相比等级1的基本定义简答，该题目需要更多的解释和描述，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 4537, + "question": "For a polymer-matrix fiber-reinforced composite, compare the desired mechanical characteristics of matrix and fiber phases.", + "answer": "The matrix phase must be ductile and is usually relatively soft, whereas the fiber phase must be stiff and strong.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种相的机械特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对聚合物基纤维增强复合材料中基体和纤维相所需机械特性的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题中属于中等难度，需要解释和描述两种材料相（基质和纤维）的机械特性，并进行比较。虽然不涉及复杂的概念体系阐述，但需要理解并准确表达两者的关键差异，属于概念解释和描述的层次。" + }, + { + "idx": 4538, + "question": "For a polymer-matrix fiber-reinforced composite, cite two reasons why there must be a strong bond between fiber and matrix at their interface.", + "answer": "There must be a strong interfacial bond between fiber and matrix in order to: (1) maximize the stress transmittance between matrix and fiber phases; and (2) minimize fiber pull-out, and the probability of failure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个原因，并需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对纤维增强复合材料中纤维与基体界面结合重要性的基本概念记忆和理解，仅需列举两个基本原理层面的原因，无需深入分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然题目要求列举两个理由，但这两个理由都是复合材料界面结合的基本原理，属于基础概念记忆范畴。解题步骤相对简单，只需回忆并简要解释两个关键点，无需进行复杂的概念体系阐述或深入分析。因此，在简答题题型内属于中等难度（等级2）。" + }, + { + "idx": 4539, + "question": "What is the distinction between matrix and dispersed phases in a composite material?", + "answer": "The matrix phase is a continuous phase that surrounds the noncontinuous dispersed phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对复合材料中的基体和分散相进行解释和区分，答案需要文字描述和论述，而非选择、判断或计算。 | 知识层次: 题目考查复合材料中基体相和分散相的基本定义和区别，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目仅要求回答复合材料中基体相和分散相的基本定义和区别，属于最基础的概念记忆层面。不需要深入解释或复杂的概念体系阐述，解题步骤也非常简单直接。因此在该题型内属于最低难度等级。" + }, + { + "idx": 4540, + "question": "Contrast the mechanical characteristics of matrix and dispersed phases for fiber-reinforced composites.", + "answer": "In general, the matrix phase is relatively weak, has a low elastic modulus, but is quite ductile. On the other hand, the fiber phase is normally quite strong, stiff, and brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对比纤维增强复合材料中基体和分散相的机械特性，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对复合材料中基体相和纤维相机械特性的基本概念记忆和理解，属于基础知识的直接对比和描述，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求对比纤维增强复合材料中基体和分散相的机械特性，属于概念解释和描述的难度等级。虽然需要记忆和理解两个相的基本特性，但并不涉及复杂的概念体系阐述或深入的分析。因此，在简答题题型内属于中等难度。" + }, + { + "idx": 4541, + "question": "Briefly explain the difference between oxidation and reduction electrochemical reactions.", + "answer": "Oxidation is the process by which an atom gives up an electron (or electrons) to become a cation. Reduction is the process by which an atom acquires an extra electron (or electrons) and becomes an anion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释氧化和还原电化学反应的区别，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查氧化和还原反应的基本定义和电子转移过程的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对氧化和还原的基本定义进行简要解释，属于最基础的概念记忆性知识。题目不涉及复杂的概念体系阐述或深入的原理分析，仅需简单描述两个基本电化学反应过程即可。在同题型框架内，这属于最基础的难度等级。" + }, + { + "idx": 4542, + "question": "Which reaction occurs at the anode and which at the cathode?", + "answer": "Oxidation occurs at the anode; reduction at the cathode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释阳极和阴极发生的反应，答案需要文字描述和论述，而非选择、判断或计算。 | 知识层次: 题目考查的是电化学中阳极和阴极反应的基本概念记忆，即氧化反应发生在阳极，还原反应发生在阴极。这属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目仅要求回答基本的电化学定义（阳极发生氧化反应，阴极发生还原反应），属于最基础的概念记忆层面。不需要解释或描述概念，更不需要构建复杂的概念体系，完全符合等级1\"基本定义简答\"的标准。同类题型中，这属于最简单的直接复述型问题。" + }, + { + "idx": 4543, + "question": "(a) Write the possible oxidation and reduction half-reactions that occur when magnesium is immersed in each of the following solutions: (i) HCl", + "answer": "In HCl, possible reactions are Mg -> Mg2+ + 2 e- (oxidation) and 2 H+ + 2 e- -> H2 (reduction).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出可能的氧化和还原半反应，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求写出镁在HCl溶液中的氧化和还原半反应，这需要应用基本的电化学知识，即金属的氧化和氢离子的还原反应。虽然涉及多个概念（氧化、还原、半反应），但属于直接套用基本原理的简单应用，不需要多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述，只需要写出基本的氧化还原半反应式，不需要深入解释或复杂推导。题目直接给出了反应条件（HCl）和反应物（Mg），学生只需套用基本的电化学知识即可完成。" + }, + { + "idx": 4544, + "question": "(a) Write the possible oxidation and reduction half-reactions that occur when magnesium is immersed in each of the following solutions: (ii) an HCl solution containing dissolved oxygen", + "answer": "In an HCl solution containing dissolved oxygen, possible reactions are Mg -> Mg2+ + 2 e- (oxidation) and 4 H+ + O2 + 4 e- -> 2 H2O (reduction).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出可能的氧化和还原半反应，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求写出镁在含氧HCl溶液中的氧化和还原半反应，需要理解电化学腐蚀的基本原理，并能够将镁的氧化反应与氧的还原反应关联起来。虽然涉及的是基础概念，但需要综合分析不同反应物（镁、H+、O2）之间的相互作用，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解镁在含氧酸性溶液中的氧化还原反应，并写出相应的半反应。虽然涉及多个概念（氧化、还原、半反应），但解题步骤相对直接，不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 4546, + "question": "(b) In which of these solutions would you expect the magnesium to oxidize most rapidly? Why?", + "answer": "The magnesium would probably oxidize most rapidly in the HCl solution containing dissolved oxygen and Fe2+ ions because there are two reduction reactions that will consume electrons from the oxidation of magnesium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么镁在特定溶液中会最快氧化，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目要求分析镁在不同溶液中的氧化速率，并解释原因。这需要综合运用电化学知识（氧化还原反应）、理解不同离子对反应速率的影响，并进行推理分析。涉及多个概念的关联和机理解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对复杂现象进行全面分析，涉及多个化学反应的综合考量（HCl溶液、溶解氧和Fe2+离子的共同作用）。需要学生不仅理解镁的氧化过程，还要分析两种不同的还原反应如何协同加速氧化速率，这体现了最高层级的机理解释和综合推理能力。在同题型内属于最复杂的分析层次，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 4547, + "question": "Demonstrate that the value of F in Equation 17.19 is 96,500 C/mol.", + "answer": "The faraday constant F is 96,500 C/mol.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来证明法拉第常数的值，而不是进行数值计算或选择选项。答案提供了直接的陈述，但完整的解答需要进一步的解释和推导。 | 知识层次: 题目考查对法拉第常数这一基本概念的记忆，仅需直接回答其数值，不涉及应用或分析过程。 | 难度: 在简答题题型中，该题目仅要求直接回忆并陈述法拉第常数的数值，属于最基本的概念记忆性知识。不需要任何解释、推导或复杂概念的阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4548, + "question": "Demonstrate that at 25 C (298 K), (RT)/(nF) ln x = (0.0592)/(n) log x.", + "answer": "At 25 C (298 K), (RT)/(nF) ln x = (0.0592)/(n) log x. This gives units in volts since a volt is a J/C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来证明一个等式在特定条件下的成立，答案提供了详细的推导过程和单位说明，符合简答题的特征。 | 知识层次: 题目要求将给定的公式在特定温度下进行转换和验证，涉及基本公式的应用和简单计算，属于直接套用公式的范畴，不需要复杂的分析或综合。 | 难度: 在简答题中属于简单应用过程描述，题目要求直接套用已知公式并进行单位说明，解题步骤简单，仅需基本公式应用和简单计算，无需深入解释或复杂推导。" + }, + { + "idx": 4549, + "question": "Is a voltage generated between the two cell halves of a Zn/Zn2+ concentration cell where both electrodes are pure zinc, with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "Yes, a voltage is generated.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（是否产生电压），答案直接给出了“是”或“否”的判断，符合判断题的特征。 | 知识层次: 题目考查对浓度电池基本原理的理解和简单应用，需要知道浓度差会导致电势差，但不需要复杂的计算或多步推理。 | 难度: 在判断题题型中，该题目属于简单应用结果判断。题目直接考察对浓度电池基本原理的理解，只需判断在给定条件下是否会产生电压，不需要进行复杂的公式应用或计算过程。属于该题型框架内较为基础的问题。" + }, + { + "idx": 4550, + "question": "What is the magnitude of the voltage generated in the Zn/Zn2+ concentration cell with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "The magnitude of the voltage is 0.0592 v.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Zn/Zn2+浓度电池的电压大小，需要使用能斯特方程进行数值计算，答案是一个具体的数值结果（0.0592 v），符合计算题的特征。 | 知识层次: 题目需要应用能斯特方程进行简单的电压计算，属于基本公式的直接套用和简单计算，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用能斯特方程计算浓度电池的电压，虽然需要理解公式和代入数值，但仅涉及单一公式的直接应用和简单对数计算，没有复杂的步骤或多公式组合。" + }, + { + "idx": 4551, + "question": "Which electrode will be oxidized in the Zn/Zn2+ concentration cell with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "The electrode in the cell half with the Zn2+ concentration of 10^-2 M will be oxidized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释哪个电极会被氧化，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解浓度电池的工作原理，并应用能斯特方程的概念来判断电极的氧化情况。虽然不涉及复杂的计算，但需要将多个概念（如氧化还原反应、浓度梯度对电势的影响）关联起来进行综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及浓度电池的基本概念和氧化还原反应，但解题过程相对直接，只需要理解浓度对电极电势的影响以及氧化反应发生的条件。不需要进行复杂的多角度分析或深度关联性分析，但需要综合运用电化学知识进行说明。" + }, + { + "idx": 4552, + "question": "A piece of corroded steel plate was found in a submerged ocean vessel. It was estimated that the original area of the plate was 10 in^{2} and that approximately 2.6kg had corroded away during the submersion. Assuming a corrosion penetration rate of 200 \\mathrm{mpy} for this alloy in seawater, estimate the time of submersion in years. The density of steel is 7.9g / {cm}^{3}.", + "answer": "the time of submersion is 10 \\mathrm{yr}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及腐蚀速率、密度和面积等参数的转换和计算，最终得出时间估计。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位转换、密度计算、腐蚀速率公式应用等，涉及多个概念的关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及腐蚀速率、密度转换、面积计算等多个步骤，但并未涉及复杂多变量或高阶数学运算，因此属于等级3的综合性计算问题。" + }, + { + "idx": 4553, + "question": "A thick steel sheet of area 400 cm^{2} is exposed to air near the ocean. After a one-year period it was found to experience a weight loss of 375g due to corrosion. To what rate of corrosion, in both mpy and mm / \\mathrm{yr}, does this correspond?", + "answer": "the corrosion rate is 1.2mm / \\mathrm{yr}. the corrosion rate is 46.7 \\mathrm{mpy}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解腐蚀速率，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及腐蚀速率的计算，需要应用基本公式进行数值转换和单位换算，属于直接套用公式的简单计算题。虽然涉及单位转换，但思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用基本腐蚀速率公式并进行单位换算，但不需要多个公式组合计算。解题步骤包括：1) 计算腐蚀深度(mm/yr) 2) 换算为mpy单位。虽然涉及单位换算，但整体仍属于单一知识点的直接应用。" + }, + { + "idx": 4554, + "question": "Cite the major differences between activation and concentration polarizations.", + "answer": "Activation polarization is the condition wherein a reaction rate is controlled by one step in a series of steps that takes place at the slowest rate. For corrosion, activation polarization is possible for both oxidation and reduction reactions. Concentration polarization occurs when a reaction rate is limited by diffusion in a solution. For corrosion, concentration polarization is possible only for reduction reactions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述激活极化和浓度极化的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对激活极化和浓度极化这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题中属于中等难度，需要解释和描述两个相关但不同的概念（激活极化和浓度极化），并说明它们在腐蚀反应中的具体表现。题目要求对基础概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。" + }, + { + "idx": 4555, + "question": "Under what conditions is activation polarization rate controlling?", + "answer": "Activation polarization is rate controlling when the reaction rate is low and/or the concentration of active species in the liquid solution is high.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么条件下活化极化是速率控制步骤，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目需要理解活化极化控制速率的条件，涉及反应速率和活性物种浓度的综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释和论述，但答案相对直接，主要涉及对激活极化控制条件的理解。需要掌握相关概念并能进行简单关联分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4556, + "question": "Under what conditions is concentration polarization rate controlling?", + "answer": "Concentration polarization is rate controlling when the reaction rate is high and/or the concentration of active species in the liquid solution is low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么条件下浓度极化是速率控制步骤，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解浓度极化的控制条件，并能够分析反应速率和活性物种浓度之间的关系，属于中等应用层次的知识点。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要理解浓度极化和反应速率控制的概念，并能够关联两者之间的关系，但不需要进行多角度或深度关联性分析。解题步骤相对直接，主要涉及对基本概念的综合说明和应用。" + }, + { + "idx": 4557, + "question": "Assuming that activation polarization controls both oxidation and reduction reactions, determine the rate of corrosion of metal M (in mol/cm2-s) given the following corrosion data: For Metal M: V(M/M2+)=-0.47 V, i0=5x10-10 A/cm2, β=+0.15; For Hydrogen: V(H+/H2)=0 V, i0=2x10-9 A/cm2, β=-0.12.", + "answer": "the rate of corrosion of metal m is 2.64x10-13 mol/cm2-s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的腐蚀数据和公式计算金属M的腐蚀速率，答案是一个具体的数值结果，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用腐蚀电化学的基本原理，通过给定的电极电位、交换电流密度和塔菲尔斜率等参数，进行多步计算来确定腐蚀速率。这涉及到对活化极化控制下腐蚀速率公式的理解和应用，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用腐蚀电化学的基本原理（如活化极化控制下的腐蚀速率计算），涉及多个参数（平衡电位、交换电流密度、塔菲尔斜率）的综合运用，并需要进行多步对数计算和单位转换。虽然计算过程明确，但需要对电化学腐蚀机理有清晰理解才能正确建立计算模型。" + }, + { + "idx": 4558, + "question": "Compute the corrosion potential for this reaction given the following corrosion data: For Metal M: V(M/M2+)=-0.47 V, i0=5x10-10 A/cm2, β=+0.15; For Hydrogen: V(H+/H2)=0 V, i0=2x10-9 A/cm2, β=-0.12.", + "answer": "the corrosion potential for this reaction is -0.169 v.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的腐蚀数据和公式计算腐蚀电位，答案是一个具体的数值（-0.169 V），解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用腐蚀电化学的基本公式（如Butler-Volmer方程）进行多步计算，涉及腐蚀电位、交换电流密度和Tafel斜率等参数的关联分析。虽然不涉及复杂的机理推理或创新设计，但需要综合理解和应用多个概念来完成计算。 | 难度: 在计算题中属于综合性计算问题，需要应用腐蚀电化学的基本公式（如Butler-Volmer方程）进行多步计算，涉及交换电流密度、塔菲尔斜率等参数的关联分析，但尚未达到复杂多变量计算的程度。" + }, + { + "idx": 4559, + "question": "Briefly describe the phenomenon of passivity.", + "answer": "Passivity is the loss of chemical reactivity, under particular environmental conditions, of normally active metals and alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述钝化现象，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目考查对passivity这一基本概念的记忆和理解，属于定义性的知识，不涉及复杂分析或应用。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述\"passivity\"的定义，不涉及复杂概念体系或深入解释。题目要求的知识深度和解题步骤都非常基础，符合等级1的标准。" + }, + { + "idx": 4560, + "question": "Name two common types of alloy that passivate.", + "answer": "Stainless steels and aluminum alloys often passivate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两种常见的钝化合金类型，答案以文字形式给出，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查对合金类型及其钝化特性的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目仅要求列举两种常见的钝化合金类型，属于基础概念记忆层面的简单回答。题目不涉及概念解释或复杂体系阐述，仅需回忆并写出两种常见合金名称即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4561, + "question": "Why does chromium in stainless steels make them more corrosion resistant in many environments than plain carbon steels?", + "answer": "The chromium in stainless steels causes a very thin and highly adherent surface coating to form over the surface of the alloy, which protects it from further corrosion. For plain carbon steels, rust, instead of this adherent coating, forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释铬在不锈钢中提高耐腐蚀性的原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释铬在不锈钢中提高耐腐蚀性的机理，涉及表面涂层形成与普通碳钢腐蚀行为的对比，需要综合运用材料科学知识进行推理分析，属于对材料腐蚀保护机制的深入理解。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求解释铬在不锈钢中提高耐腐蚀性的具体机理，涉及表面涂层的形成及其保护作用，与普通碳钢的腐蚀行为进行对比。这需要学生对材料腐蚀原理有较深入的理解，并能综合运用相关知识进行分析和解释。虽然题目没有要求全面分析复杂现象，但对机理的解释深度要求较高，因此属于等级4。" + }, + { + "idx": 4562, + "question": "Briefly explain why cold-worked metals are more susceptible to corrosion than noncold-worked metals.", + "answer": "Cold-worked metals are more susceptible to corrosion than noncold-worked metals because of the increased dislocation density for the latter. The region in the vicinity of a dislocation that intersects the surface is at a higher energy state, and, therefore, is more readily attacked by a corrosive solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释冷加工金属比非冷加工金属更容易腐蚀的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷加工金属比非冷加工金属更易腐蚀的原因，涉及位错密度与腐蚀敏感性的关联机制，需要理解位错与表面能的关系以及腐蚀过程的机理，属于综合分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对冷加工金属的腐蚀敏感性进行机理深度解释。需要理解位错密度与表面能状态的关系，并能将材料微观结构与宏观腐蚀行为联系起来。虽然不涉及多因素交互作用的全面分析，但需要展示对材料科学原理的深入理解和应用能力，符合等级4的机理深度解释要求。" + }, + { + "idx": 4563, + "question": "Briefly explain why, for a small anode-to-cathode area ratio, the corrosion rate will be higher than for a large ratio.", + "answer": "For a small anode-to-cathode area ratio, the corrosion rate will be higher than for A large ratio. The reason for this is that for some given current flow associated with the corrosion reaction, for a small area ratio the current density at the anode will be greater than for a large ratio. The corrosion rate is proportional to the current density (i) according to Equation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释为什么小阳极-阴极面积比会导致更高的腐蚀速率，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解阳极-阴极面积比对腐蚀速率的影响机制，并运用电流密度与腐蚀速率的关系进行解释。这涉及多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解阳极-阴极面积比对腐蚀速率的影响机制，并能够解释电流密度与腐蚀速率的关系。虽然涉及多步概念关联，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 4564, + "question": "What are inhibitors?", + "answer": "Inhibitors are substances that, when added to a corrosive environment in relatively low concentrations, decrease the environment's corrosiveness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"inhibitors\"进行文字解释和论述，答案是一个完整的定义性陈述，不需要选择、判断或计算。 | 知识层次: 题目考查基本概念的记忆和理解，仅需要回答抑制剂的定义及其在腐蚀环境中的作用，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目仅要求回答基本定义，属于最基础的记忆性知识。题目不涉及概念解释的深度或复杂体系的阐述，仅需直接回忆并复述抑制剂的定义即可完成作答。在同题型框架内，这属于最基础难度等级。" + }, + { + "idx": 4565, + "question": "What possible mechanisms account for their effectiveness?", + "answer": "Possible mechanisms that account for the effectiveness of inhibitors are: (1) elimination of a chemically active species in the solution; (2) attachment of inhibitor molecules to the corroding surface so as to interfere with either the oxidation or reduction reaction; and (3) the formation of a very thin and protective coating on the corroding surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释可能的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释抑制剂有效性的可能机制，涉及多个机理的分析和综合理解，需要将腐蚀防护的基本原理与实际应用场景相结合，进行推理和解释。这超出了简单记忆或直接应用的层次，属于对知识的深度理解和综合分析。 | 难度: 在简答题题型中，该题目要求对抑制剂的可能机理进行深度解释，涉及多个复杂机制的综合分析。虽然不需要全面分析所有复杂现象（如等级5的要求），但仍需详细阐述三种不同的作用机理，并理解它们如何影响腐蚀过程。这需要较高的知识掌握深度和推理分析能力，符合等级4的标准。" + }, + { + "idx": 4566, + "question": "Briefly describe the sacrificial anode technique used for galvanic protection.", + "answer": "A sacrificial anode is electrically coupled to the metal piece to be protected, which anode is also situated in the corrosion environment. The sacrificial anode is a metal or alloy that is chemically more reactive in the particular environment. It (the anode) preferentially oxidizes, and, upon giving up electrons to the other metal, protects it from electrochemical corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述牺牲阳极技术用于电化学保护的原理，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对牺牲阳极技术的基本概念和原理的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述牺牲阳极技术用于电化学保护的原理，涉及基础概念的记忆和简单解释，但不需要复杂的体系阐述或多步骤推理。答案需要准确描述牺牲阳极的作用机制和基本原理，属于对单一概念的较深入解释，符合等级2的标准。" + }, + { + "idx": 4567, + "question": "Briefly describe the impressed current technique used for galvanic protection.", + "answer": "An impressed current from an external dc power source provides excess electrons to the metallic structure to be protected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述一种技术（impressed current technique），答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对阴极保护中外加电流技术的基本概念和原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要理解并描述一个技术方法（外加电流法），但仅涉及基本原理的简要说明，不需要深入分析或整合多个复杂概念。属于基础概念记忆层次中的中等难度要求。" + }, + { + "idx": 4568, + "question": "Compute the electrical conductivity of a 5.1-mm (0.2-in.) diameter cylindrical silicon specimen 51mm (2 in.) long in which a current of 0.1 A passes in an axial direction. A voltage of 12.5V is measured across two probes that are separated by 38mm (1.5 in.).", + "answer": "the electrical conductivity is σ = 14.9 (ω·m)^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解硅圆柱体的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求计算硅圆柱体的电导率，涉及基本公式的应用（欧姆定律和电导率公式），计算过程直接且步骤简单，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用电导率的基本公式σ = (I × L) / (V × A)，其中I是电流，L是长度，V是电压，A是横截面积。计算过程简单直接，不需要多个公式组合或复杂的推导步骤。" + }, + { + "idx": 4569, + "question": "Compute the resistance over the entire 51mm (2 in.) of the specimen.", + "answer": "the resistance is r = 168 ω.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（Compute the resistance），答案是一个具体的数值计算结果（r = 168 ω），符合计算题的特征 | 知识层次: 题目要求进行基本的电阻计算，仅涉及单一公式的直接应用和简单数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一电阻公式R=ρL/A（题目隐含给出电阻率ρ和尺寸参数），无需公式组合或单位换算，解题步骤仅涉及基础代数运算。" + }, + { + "idx": 4570, + "question": "Calculate the drift velocity of electrons in germanium at room temperature and when the magnitude of the electric field is 1000 V/m.", + "answer": "the drift velocity of electrons in germanium is 380 m/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算电子在锗中的漂移速度），并给出了具体的电场强度条件，答案也是一个具体的数值结果（380 m/s），符合计算题的特征。 | 知识层次: 题目要求计算电子在锗中的漂移速度，涉及基本公式应用（如漂移速度公式）和简单计算，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于最低难度等级，仅需直接应用单一公式（v_d = μE）进行简单数值计算，无需多步骤推导或复杂公式组合。题目明确给出了所有必要参数（电场强度1000V/m和迁移率0.38m²/V·s），解题过程仅涉及基本代数运算。" + }, + { + "idx": 4571, + "question": "Under these circumstances, how long does it take an electron to traverse a 25-mm (1-in.) length of crystal?", + "answer": "the time required for an electron to traverse a 25-mm length of crystal is 6.6 × 10^-5 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算电子通过25毫米晶体所需的时间，答案是一个具体的数值结果，需要通过公式和数值计算得出。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需直接套用公式计算电子通过晶体长度所需的时间，无需多步计算或复杂分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级，仅需应用基本公式进行简单数值计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 4572, + "question": "At room temperature the electrical conductivity and the electron mobility for copper are 6.0 x 10^7 (Ω·m)^-1 and 0.0030 m^2/V·s, respectively. Compute the number of free electrons per cubic meter for copper at room temperature.", + "answer": "the number of free electrons per cubic meter for copper at room temperature is 1.25 x 10^29 m^-3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率和电子迁移率数据，应用公式计算铜在室温下的自由电子数密度。答案是一个具体的数值结果，解答过程需要数值计算和公式应用。 | 知识层次: 题目主要涉及基本公式的直接应用（电导率与载流子浓度、迁移率的关系公式σ = n·e·μ），只需简单代入已知数值进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用电导率与载流子浓度、迁移率的基本关系公式σ = n e μ，进行简单的数值代入和计算即可得到结果，无需多个公式组合或复杂推导。" + }, + { + "idx": 4573, + "question": "At room temperature the electrical conductivity and the electron mobility for copper are 6.0 x 10^7 (Ω·m)^-1 and 0.0030 m^2/V·s, respectively. What is the number of free electrons per copper atom? Assume a density of 8.9 g/cm^3.", + "answer": "the number of free electrons per copper atom is 1.48.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜原子中自由电子的数量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括电导率公式的应用、电子浓度的计算以及铜原子密度的计算，需要将多个概念关联起来进行综合分析。虽然不涉及复杂的推理分析或机理解释，但计算过程较为复杂，超出了简单应用的范围。 | 难度: 在计算题中属于综合性计算问题，需要应用电导率、电子迁移率和密度的公式，进行多步计算和单位转换，并最终关联到铜原子的自由电子数量。虽然计算步骤较多，但每一步都有明确的物理意义和公式支持，不需要处理复杂多变量或高阶数学运算。" + }, + { + "idx": 4574, + "question": "At room temperature the electrical conductivity of \\mathrm{PbTe} is 500(\\Omega·m)^{-1}, whereas the electron and hole mobilities are 0.16 and 0.075{m}^{2} / V·s, respectively. Compute the intrinsic carrier concentration for \\mathrm{PbTe} at room temperature.", + "answer": "the intrinsic carrier concentration for \\mathrm{pbte} at room temperature is 1.33 × 10^{22}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解本征载流子浓度，答案是一个具体的数值结果，解答过程需要运用电导率、电子和空穴迁移率等参数进行计算。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即通过给定的电导率、电子和空穴迁移率来计算本征载流子浓度。虽然需要理解相关概念，但计算过程直接且步骤单一，属于简单应用层次。 | 难度: 在计算题中属于简单应用难度，需要应用电导率与载流子浓度及迁移率的基本公式进行计算，但仅涉及单一公式的直接应用和简单数值计算，无需多个公式组合或复杂推导。" + }, + { + "idx": 4575, + "question": "Define the term 'intrinsic' as it pertains to semiconducting materials and provide an example.", + "answer": "intrinsic--high purity (undoped) Si, GaAs, CdS, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述，符合简答题的特征 | 知识层次: 题目要求定义\"intrinsic\"术语并提供示例，属于半导体材料的基础概念记忆和理解范畴，不涉及复杂分析或应用。 | 难度: 在简答题题型中，该题目仅要求对\"intrinsic\"这一基础术语进行定义并列举相关示例，属于最基本的概念记忆和简单应用。题目不涉及概念间的关联分析或复杂原理阐述，完全符合等级1\"基本定义简答\"的标准。相比需要展开解释的等级2题目或需要系统阐述的等级3题目，该题的认知负荷和作答要求均为最低水平。" + }, + { + "idx": 4576, + "question": "Define the term 'extrinsic' as it pertains to semiconducting materials and provide an example.", + "answer": "extrinsic--P-doped Ge, B-doped Si, S-doped GaP, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述，答案形式为简短的文字描述和示例，符合简答题的特征。 | 知识层次: 题目考查对\"extrinsic\"这一基本术语的定义记忆，以及通过举例说明其应用，属于基础概念的记忆和理解层面。 | 难度: 在简答题题型中，该题目仅要求对\"extrinsic\"这一术语进行基本定义，并列举一个相关例子。这属于最基础的概念记忆和简单应用，不需要深入的解释或复杂的论述过程。同题型内相比，该题目仅测试学生对基础术语的记忆和简单举例能力，属于难度最低的等级1。" + }, + { + "idx": 4577, + "question": "Define the term 'compound' as it pertains to semiconducting materials and provide an example.", + "answer": "compound--GaAs, InP, CdS, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述，答案形式为开放式回答而非选择或判断 | 知识层次: 题目考查对半导体材料中\"化合物\"这一基本概念的定义记忆和简单举例，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求对基础术语进行定义并列举一个例子，属于最基本的概念记忆和简单应用。题目不涉及概念的解释、描述或复杂体系的阐述，仅需要学生回忆并复现基础定义和常见实例，因此在该题型内属于最低难度等级。" + }, + { + "idx": 4578, + "question": "Define the term 'elemental' as it pertains to semiconducting materials and provide an example.", + "answer": "elemental--Ge and Si.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对\"elemental\"这一基本术语的定义记忆和简单举例，属于半导体材料的基础概念范畴，仅需记忆性知识即可回答。 | 难度: 在简答题题型中，该题目仅要求对基础术语进行定义并列举一个例子，属于最基本的概念记忆和简单应用。不需要深入解释或复杂论述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4579, + "question": "Explain why no hole is generated by the electron excitation involving a donor impurity atom.", + "answer": "No hole is generated by an electron excitation involving a donor impurity atom because the excitation comes from a level within the band gap, and thus, no missing electron is created within the normally filled valence band.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在涉及施主杂质原子的电子激发过程中不会产生空穴，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释电子激发过程中不产生空穴的机理，涉及能带理论、杂质能级和电子跃迁等概念的关联和综合分析，需要深入理解半导体物理中的电子行为，并进行推理分析。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于机理深度解释难度。题目要求解释为什么施主杂质原子的电子激发不会产生空穴，这需要理解能带结构、施主能级位置以及电子激发过程的本质。虽然不涉及多步骤的复杂现象分析，但需要对半导体物理中的特定机理有深入理解，并能准确表述其原理。这比简单的事实陈述或基础概念解释（等级1-3）更复杂，但尚未达到需要综合分析多个相互关联现象的等级5难度。" + }, + { + "idx": 4580, + "question": "Explain why no free electron is generated by the electron excitation involving an acceptor impurity atom.", + "answer": "No free electron is generated by an electron excitation involving an acceptor impurity atom because the electron is excited from the valence band into the impurity level within the band gap; no free electron is introduced into the conduction band.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在涉及受主杂质原子的电子激发过程中不会产生自由电子，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释电子激发过程中自由电子未产生的原因，涉及价带、杂质能级和导带之间的电子跃迁机制分析，需要综合运用半导体物理知识进行推理和解释，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对半导体掺杂机理进行深度解释，需要理解价带、导带、杂质能级之间的电子跃迁关系，并能准确区分施主与受主杂质的差异。虽然不涉及多步骤推导，但对物理概念的掌握和机理描述的精确性要求较高，属于机理深度解释级别。" + }, + { + "idx": 4581, + "question": "Germanium to which 5 × 10^22 m^-3 Sb atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the Sb atoms may be thought of as being ionized (i.e., one charge carrier exists for each Sb atom). Is this material n-type or p-type?", + "answer": "this germanium material to which has been added 5 × 10^22 m^-3 sb atoms is n-type since sb is a donor in ge.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释为什么添加Sb原子的锗材料是n型半导体，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对半导体类型（n型或p型）的基本概念记忆和理解，以及掺杂元素在半导体中的作用。只需要识别Sb是施主杂质，就能判断材料是n型半导体，不需要复杂的分析或计算。 | 难度: 在简答题中属于基本定义简答难度，仅需识别掺杂元素类型（Sb作为施主杂质）并据此判断半导体类型（n型），无需复杂解释或概念体系阐述。" + }, + { + "idx": 4582, + "question": "Germanium to which 5 × 10^22 m^-3 Sb atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the Sb atoms may be thought of as being ionized (i.e., one charge carrier exists for each Sb atom). Calculate the electrical conductivity of this material, assuming electron and hole mobilities of 0.1 and 0.05 m^2/V-s, respectively.", + "answer": "the electrical conductivity of this material is 800 (ω·m)^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锗材料的电导率，涉及电子和空穴迁移率的计算，答案是一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的掺杂浓度和载流子迁移率直接计算电导率。虽然需要理解半导体掺杂和载流子迁移的概念，但计算过程较为直接，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用电导率的基本公式σ = n * e * μ，其中n是载流子浓度，e是电子电荷，μ是载流子迁移率。题目已经给出了所有必要的数值，计算过程简单直接，无需多个公式组合或复杂推导。" + }, + { + "idx": 4583, + "question": "The following electrical characteristics have been determined for both intrinsic and p-type extrinsic indium phosphide ( \\mathrm{InP} ) at room temperature:\n\\begin{tabular}{lccc}\n\\hline & \\boldsymbol{\\sigma}\\left(\\boldsymbol{\\Omega}·\\mathbf{m}\\right)^{-1} & \\mathbf{n}\\left(\\mathbf{m}^{-3}\\right) & \\mathbf{p}\\left(\\mathbf{m}^{-3}\\right) \\\\\n\\hline Intrinsic & 2.5 × 10^{-6} & 3.0 × 10^{13} & 3.0 × 10^{12} \\\\\nExtrinsic (n-type) & 3.6 × 10^{-5} & 4.5 × 10^{14} & 2.0 × 10^{12} \\\\\n\\hline\n\\end{tabular}\nCalculate electron and hole mobilities.", + "answer": "the electron and hole mobilities for \\mathrm{inp} are \\mu_{e} = 0.50 \\, m^{2}/\\mathrm{v}\\cdots and \\mu_{h} = 0.02 \\, m^{2}/\\mathrm{v}\\cdots.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的电导率、电子浓度和空穴浓度数据，应用相关公式计算电子和空穴的迁移率。答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用电导率与载流子浓度和迁移率的关系公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题。题目要求计算电子和空穴的迁移率，涉及多步计算和公式应用（如电导率与载流子浓度、迁移率的关系）。虽然计算过程相对直接，但需要理解并正确关联多个半导体物理概念（如本征和n型半导体的载流子行为），并进行综合分析。相比更简单的单步计算题（等级2），该题复杂度更高，但尚未达到需要处理复杂多变量或非常规公式的等级4难度。" + }, + { + "idx": 4584, + "question": "Some metal alloy is known to have electrical conductivity and electron mobility values of 1.5 × 10^{7} (\\Omega·m)^{-1} and 0.0020{m}^{2} / V·s, respectively. Through a specimen of this alloy that is 35mm thick is passed a current of 45 A. What magnetic field would need to be imposed to yield a Hall voltage of -1.0 × 10^{-7}V ?", + "answer": "the required magnetic field is 0.58 \\mathrm{tesla}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的磁场强度，答案是一个具体的数值结果（0.58 tesla），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用电导率、电子迁移率、电流、厚度和霍尔电压等概念，并通过公式推导和计算得出磁场强度。虽然不涉及复杂的机理解释或创新设计，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用霍尔效应公式进行多步计算，涉及电导率、电子迁移率、电流和厚度等多个变量的关联分析，但计算过程相对直接，没有过于复杂的变量处理或高级数学技巧要求。" + }, + { + "idx": 4585, + "question": "What is one function that a transistor may perform in an electronic circuit?", + "answer": "In an electronic circuit, a transistor may be used to amplify an electrical signal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释晶体管在电子电路中的功能，答案是一个简短的文字描述，不需要选择、判断或计算。 | 知识层次: 题目考查晶体管在电子电路中的基本功能，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答晶体管的一个基本功能（放大电信号），属于最基础的概念记忆范畴，不需要进行概念解释或复杂体系阐述。在同类简答题中，这是最基础的知识点考察形式，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4586, + "question": "What is another function that a transistor may perform in an electronic circuit?", + "answer": "In an electronic circuit, a transistor may act as a switching device in computers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述晶体管在电子电路中的另一种功能，答案提供了具体的解释而非选择或判断。 | 知识层次: 题目考查晶体管在电子电路中的基本功能记忆和理解，属于基础概念的记忆性知识 | 难度: 在简答题题型中，该题目要求考生不仅知道晶体管的基本功能（如放大作用），还需要列举并解释另一个功能（如开关作用）。这超出了单纯记忆基本定义的等级1难度，但尚未达到需要阐述复杂概念体系的等级3难度。题目要求对晶体管功能进行概念解释和描述，符合等级2的标准。" + }, + { + "idx": 4587, + "question": "At temperatures between 775^{\\circ} C\\left(1048 K\\right) and 1100^{\\circ} C\\left(1373 K\\right), the activation energy and preexponential for the diffusion coefficient of \\mathrm{Fe}^{2+} in \\mathrm{FeO} are 102,000 J/ mol and 7.3 × 10^{-8}{m}^{2} / s, respectively. Compute the mobility for an \\mathrm{Fe}^{2+} ion at 1000^{\\circ} C(1273 K).", + "answer": "the mobility for an \\mathrm{fe}^{2+} ion at 1000^{\\circ} C (1273 k) is 8.64 × 10^{-11}{m}^{2} / \\mathrm{v}·s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和前置指数计算Fe2+在FeO中的迁移率，需要使用扩散系数的阿伦尼乌斯公式进行计算，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用扩散系数的阿伦尼乌斯公式和迁移率的关系公式，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散系数公式和能斯特-爱因斯坦关系进行多步计算，涉及温度转换、参数代入和单位换算，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4588, + "question": "A parallel-plate capacitor using a dielectric material having an \\varepsilon_{r} of 2.5 has a plate spacing of 1 mm (0.04 in.). If another material having a dielectric constant of 4.0 is used and the capacitance is to be unchanged, what must be the new spacing between the plates?", + "answer": "the new spacing between the plates must be 1.6 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来解决问题，涉及电容器的参数变化和计算新的板间距。答案是一个具体的数值结果（1.6 mm），而不是选择、判断或文字解释。 | 知识层次: 题目涉及基本的电容公式应用和简单的数值计算，只需要理解电容与介电常数和板间距的关系，并进行一步计算即可得出答案。不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目仅涉及电容公式的直接应用（C = εA/d），需要根据给定的介电常数变化调整板间距以保持电容不变。解题步骤简单，仅需一次公式变换和数值代入，无需多个公式组合或复杂推导。" + }, + { + "idx": 4589, + "question": "(a) For each of the three types of polarization, briefly describe the mechanism by which dipoles are induced and/or oriented by the action of an applied electric field.", + "answer": "(a) For electronic polarization, the electric field causes a net displacement of the center of the negatively charged electron cloud relative to the positive nucleus. With ionic polarization, the cations and anions are displaced in opposite directions as a result of the application of an electric field. Orientation polarization is found in substances that possess permanent dipole moments; these dipole moments become aligned in the direction of the electric field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对三种极化机制进行简要描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对三种极化机制的基本概念记忆和理解，包括电子极化、离子极化和取向极化的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求对三种极化机制进行简要描述，涉及基础概念的记忆和解释，但不需要深入分析或复杂的概念体系阐述。解题步骤相对直接，主要考察对基本概念的理解和表达能力。" + }, + { + "idx": 4590, + "question": "(b) For solid lead titanate (PbTiO3), gaseous neon, diamond, solid KCl, and liquid NH3 what kind(s) of polarization is (are) possible? Why?", + "answer": "(b) Electronic, ionic, and orientation polarizations would be observed in lead titanate. The lead, titanium, and oxygen would undoubtedly be largely ionic in character. Furthermore, orientation polarization is also possible inasmuch as permanent dipole moments may be induced in the same manner as for BaTiO3. Only electronic polarization is to be found in gaseous neon; being an inert gas, its atoms will not be ionized nor possess permanent dipole moments. Only electronic polarization is to be found in solid diamond; this material does not have molecules with permanent dipole moments, nor is it an ionic material. Both electronic and ionic polarizations will be found in solid KCl, since it is strongly ionic. In all probability, no permanent dipole moments will be found in this material. Both electronic and orientation polarizations are found in liquid NH3. The NH3 molecules have permanent dipole moments that are easily oriented in the liquid state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同物质可能存在的极化类型进行解释和论述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同材料的极化类型进行分析和解释，需要理解电子极化、离子极化和取向极化的基本原理，并能将这些概念应用到具体的材料中。虽然不涉及复杂的计算或深度推理，但需要对多种材料的极化行为进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合运用多个概念（电子极化、离子极化、取向极化）并结合具体物质的性质进行分析。题目要求对不同物质（固态钛酸铅、气态氖、金刚石、固态KCl、液态NH3）的极化类型进行详细解释，涉及多步推理和概念关联，且需要对每种物质的微观结构和极化机制有深入理解。虽然不需要进行复杂计算，但需要较强的综合分析能力和论述能力。" + }, + { + "idx": 4591, + "question": "For aluminum, the heat capacity at constant volume Cv at 30 K is 0.81 J/mol-K, and the Debye temperature is 375 K. Estimate the specific heat at 50 K.", + "answer": "the specific heat at 50 K is 139 J/kg-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出一个具体的数值结果（139 J/kg-K），这符合计算题的特征。 | 知识层次: 题目需要应用德拜模型和热容公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用Debye模型和热容公式进行多步计算，涉及温度转换和单位换算，但计算过程相对直接，没有复杂变量或高级数学技巧要求。" + }, + { + "idx": 4592, + "question": "For aluminum, the heat capacity at constant volume Cv at 30 K is 0.81 J/mol-K, and the Debye temperature is 375 K. Estimate the specific heat at 425 K.", + "answer": "the specific heat at 425 K is 923 J/kg-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出一个具体的数值结果（923 J/kg-K）。解答过程需要应用材料科学中的热容和德拜温度相关知识，属于典型的计算题。 | 知识层次: 题目需要应用Debye模型计算高温下的比热，涉及多步计算和概念关联（Debye温度与热容的关系），但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用Debye模型和热容公式进行多步计算，涉及温度转换和单位换算，但计算过程相对直接，没有过于复杂的变量或条件。" + }, + { + "idx": 4593, + "question": "(a) Briefly explain why Cv rises with increasing temperature at temperatures near 0 K.", + "answer": "The reason that Cv rises with increasing temperature at temperatures near 0 K is because, in this temperature range, the allowed vibrational energy levels of the lattice waves are far apart relative to the available thermal energy, and only a portion of the lattice waves may be excited. As temperature increases, more of the lattice waves may be excited by the available thermal energy, and, hence, the ability of the solid to absorb energy (i.e., the magnitude of the heat capacity) increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释Cv在接近0 K时随温度升高的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释在接近0 K温度下Cv随温度升高的原因，涉及对晶格振动能级和热激发过程的深入理解，需要综合运用固体物理和热力学知识进行推理分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对低温下热容随温度变化的机理进行深度解释，涉及晶格振动能级和热激发的关系。虽然不需要全面分析复杂现象，但需要综合运用固体物理和热力学知识进行推理分析，解释较为深入，属于机理深度解释的难度等级。" + }, + { + "idx": 4594, + "question": "(b) Briefly explain why Cv becomes virtually independent of temperature at temperatures far removed from 0 K.", + "answer": "At temperatures far removed from 0 K, Cv becomes independent of temperature because all of the lattice waves have been excited and the energy required to produce an incremental temperature change is nearly constant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释Cv在远离0 K时几乎与温度无关的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Cv在远离0 K温度下几乎与温度无关的原因，这需要理解晶格波的激发和能量变化机制，涉及对固体物理中热容理论的深入理解和分析，属于复杂分析和机理解释的范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求对Cv与温度关系的物理机理进行深度解释，需要综合运用固体物理和热力学知识，理解晶格波激发与热容的关系。虽然不涉及多步骤推导或跨学科整合（这是等级5的特征），但需要对量子效应在高温极限下的表现有清晰认知，属于机理深度解释范畴。" + }, + { + "idx": 4595, + "question": "A 0.1{m}(3.9 in.) rod of a metal elongates 0.2 mm(0.0079 in.) on heating from 20 to 100^{\\circ} C(68 \\mathrm{to} 212^{\\circ} F ). Determine the value of the linear coefficient of thermal expansion for this material.", + "answer": "the linear coefficient of thermal expansion for this material is 25.0 × 10^{-6} \\, (\\degree c)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（线性热膨胀系数公式）来求解具体数值，答案是一个计算得出的具体数值（25.0 × 10^{-6} \\, (\\degree c)^{-1}），符合计算题的特征。 | 知识层次: 题目涉及基本的线性热膨胀系数公式应用和简单计算，仅需直接套用公式并代入已知数值即可得出结果，无需多步计算或复杂分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用线性热膨胀系数公式（ΔL = αL₀ΔT）进行简单代数运算即可得出结果，无需多步骤或复杂推导。" + }, + { + "idx": 4596, + "question": "Briefly explain why the thermal conductivities are higher for crystalline than noncrystalline ceramics.", + "answer": "Thermal conductivities are higher for crystalline than for noncrystalline ceramics because, for noncrystalline, phonon scattering, and thus the resistance to heat transport, is much more effective due to the highly disordered and irregular atomic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释晶体陶瓷比非晶体陶瓷具有更高热导率的原因，答案通过文字解释和论述来回答，符合简答题的特征。 | 知识层次: 题目要求解释晶体和非晶体陶瓷热导率差异的机理，涉及对声子散射和原子结构无序性影响热传输的深入理解，需要综合运用材料科学中的热传导理论和微观结构知识进行分析和推理。 | 难度: 在简答题中属于机理深度解释难度，需要理解晶体和非晶体陶瓷的热传导机制差异，并能够解释声子散射在非晶体材料中更为有效的原因。这要求对材料结构和热传导机理有较深入的理解和综合运用能力。" + }, + { + "idx": 4597, + "question": "Briefly explain why metals are typically better thermal conductors than ceramic materials.", + "answer": "Metals are typically better thermal conductors than are ceramic materials because, for metals, most of the heat is transported by free electrons (of which there are relatively large numbers). In ceramic materials, the primary mode of thermal conduction is via phonons, and phonons are more easily scattered than are free electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释金属为何比陶瓷材料具有更好的导热性，答案通过文字解释和论述来回答，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查金属和陶瓷材料热传导机制的基本概念记忆和理解，涉及自由电子和声子的作用，属于基本原理的记忆性知识。 | 难度: 在简答题中属于中等难度，需要解释金属和陶瓷材料在热传导方面的差异，涉及自由电子和声子的概念，但不需要深入阐述复杂机制或进行多层次的比较分析。" + }, + { + "idx": 4598, + "question": "Briefly explain why porosity decreases the thermal conductivity of ceramic and polymeric materials, rendering them more thermally insulative.", + "answer": "Porosity decreases the thermal conductivity of ceramic and polymeric materials because the thermal conductivity of a gas phase that occupies pore space is extremely small relative to that of the solid material. Furthermore, contributions from gaseous convection are generally insignificant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释孔隙率如何降低陶瓷和聚合物材料的热导率，使其更具隔热性。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释孔隙率如何降低陶瓷和高分子材料的热导率，涉及对材料微观结构和热传导机制的理解，需要将孔隙率与热导率的关系进行关联分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求解释孔隙率如何降低陶瓷和聚合物材料的热导率，使其更具隔热性。这需要理解热导率的基本概念，并能将孔隙率与热导率的变化联系起来。虽然涉及多个概念（如固体和气体的热导率差异、对流的影响），但不需要进行复杂的多角度分析或深度关联性分析。解题步骤相对直接，主要是解释现象背后的基本原理。" + }, + { + "idx": 4599, + "question": "Briefly explain how the degree of crystallinity affects the thermal conductivity of polymeric materials and why.", + "answer": "Increasing the degree of crystallinity of a semicrystalline polymer enhances its thermal conductivity; the vibrations, rotations, etc. of the molecular chains are more effective modes of thermal transport when a crystalline structure prevails.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释结晶度对聚合物材料热导率的影响及其原因，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释结晶度对聚合物热导率的影响及其原因，涉及概念关联和综合分析，需要理解结晶结构如何影响分子链的振动和旋转等热传输模式，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求解释结晶度对聚合物材料热导率的影响，但只需要进行单一概念（结晶度）与性能（热导率）之间的关联分析，不需要多角度或深度关联性分析。解题步骤相对直接，主要涉及对结晶结构如何影响分子振动和热传导的基本理解。" + }, + { + "idx": 4600, + "question": "For some ceramic materials, why does the thermal conductivity first decrease and then increase with rising temperature?", + "answer": "For some ceramic materials, the thermal conductivity first decreases with rising temperature because the scattering of lattice vibrations increases with temperature. At higher temperatures, the thermal conductivity will increase for some ceramics that are porous because radiant heat transfer across pores may become important, which process increases with rising temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷材料热导率随温度变化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷材料热导率随温度变化的复杂行为，涉及晶格振动散射和辐射传热两种机制的相互作用。需要深入理解热传导的微观机制，分析不同温度区间主导机制的转变，并进行综合推理。这超出了简单记忆或基本应用层面，属于需要综合分析多个物理过程的复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对陶瓷材料热导率随温度变化的复杂现象进行全面分析。需要综合运用晶格振动散射和辐射传热两种机理，解释先降低后升高的非单调变化趋势。这种双阶段机理解释需要深入理解材料微观结构对宏观性能的影响机制，属于该题型框架内最高难度的综合分析要求。" + }, + { + "idx": 4601, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Pure copper; aluminum bronze (95 wt% Cu-5 wt% Al).", + "answer": "Pure copper will have a larger conductivity than aluminum bronze because the impurity atoms in the latter will lead to a greater degree of free electron scattering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求学生理解热导率的基本概念，并能够分析合金中杂质原子对自由电子散射的影响，从而比较两种材料的热导率。这需要将基础概念与材料特性关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解热导率的影响因素（如杂质对自由电子散射的影响），并能对两种材料进行对比分析。虽然涉及概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4602, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Fused silica; quartz.", + "answer": "Quartz will have a larger conductivity than fused silica because fused silica is noncrystalline (whereas quartz is crystalline) and lattice vibrations are more effectively scattered in noncrystalline materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求学生比较两种材料的导热性能，并基于晶体结构对导热性能的影响进行解释。这需要理解晶体与非晶体材料在导热机制上的差异，并能够将这一概念应用到具体材料中进行分析。虽然不涉及复杂的计算或多步骤推理，但需要一定的概念关联和综合分析能力。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对两种材料的导热性进行比较并给出解释，但只需要基于晶体结构对导热性的影响这一核心概念进行论述，无需多角度或深度关联性分析。解题步骤相对直接，属于典型的综合分析说明类问题。" + }, + { + "idx": 4603, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Linear polyethylene; branched polyethylene.", + "answer": "The linear polyethylene will have the larger conductivity than the branched polyethylene because the former will have the higher degree of crystallinity. Linear polymers have higher degrees of crystallinity than branched polymers. Since heat transfer is accomplished by molecular chain vibrations, and the coordination of these vibrations increases with percent crystallinity, the higher the crystallinity, the greater the thermal conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性能并给出理由，需要文字解释和论述，而不是简单的选择或判断。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求比较两种聚乙烯的热导率，并解释原因。这涉及到对聚合物结构（线性与支化）与性能（热导率）之间关系的理解，以及结晶度对热导率的影响。虽然知识点较为基础，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对两种聚乙烯的热导率进行比较并给出解释，但解题过程主要依赖于对聚合物结晶度与热导率关系的理解，属于单一概念的应用和简单分析。不需要进行多角度或多步骤的深入论述，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 4604, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Random poly(styrene-butadiene) copolymer; alternating poly(styrene-butadiene) copolymer.", + "answer": "The alternating poly(styrene-butadiene) copolymer will have a higher crystallinity than the random copolymer; alternating copolymers crystallize more easily than random ones. The influence of crystallinity on conductivity is explained in part (c).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性，并给出选择的理由。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要理解共聚物结构（随机与交替）对结晶度的影响，并将结晶度与热导率关联起来进行分析。这涉及多个概念的关联和综合分析，但不需要深入机理或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求比较两种材料的导热性并给出理由，但答案中已经提供了明确的线索（交替共聚物比无规共聚物更容易结晶，而结晶度会影响导热性）。学生需要理解结晶度与导热性之间的关系，并将这一概念应用到具体的材料比较中。这需要一定的概念关联和综合分析能力，但不需要多角度或深度关联性分析。因此，在简答题题型中属于等级3的难度。" + }, + { + "idx": 4605, + "question": "Explain the two sources of magnetic moments for electrons.", + "answer": "The two sources of magnetic moments for electrons are the electron's orbital motion around the nucleus, and also, its spin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释电子磁矩的两个来源，需要文字解释和论述，答案也以文字形式呈现，符合简答题的特征 | 知识层次: 题目考查对电子磁矩两个来源的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在简答题题型中，该题目要求解释电子磁矩的两个来源（轨道运动和自旋），属于概念解释和描述的层次。虽然需要记忆基本原理，但不需要深入分析或复杂的概念体系阐述，因此属于中等难度。" + }, + { + "idx": 4606, + "question": "Do all electrons have a net magnetic moment? Why or why not?", + "answer": "Each electron will have a net magnetic moment from spin, and possibly, orbital contributions, which do not cancel for an isolated atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么所有电子都有净磁矩，需要文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目考查电子磁矩的基本概念，主要涉及电子自旋和轨道磁矩的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释电子是否具有净磁矩及其原因，涉及电子自旋和轨道贡献的基本概念，但不需要复杂的体系阐述或多层次分析。回答需要理解并简要描述这些概念，属于中等难度的概念解释类问题。" + }, + { + "idx": 4607, + "question": "Do all atoms have a net magnetic moment? Why or why not?", + "answer": "All atoms do not have a net magnetic moment. If an atom has completely filled electron shells or subshells, there will be a cancellation of both orbital and spin magnetic moments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么所有原子不一定具有净磁矩，需要文字解释和论述，而不是简单的选择或判断。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目考查原子磁矩的基本概念和电子排布对磁矩的影响，属于基本原理的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释原子是否具有净磁矩的原因，涉及对电子壳层填充状态与磁矩关系的理解。虽然需要一定的概念记忆和解释能力，但不需要复杂的体系阐述或多步骤推理，属于中等难度的概念解释题。" + }, + { + "idx": 4608, + "question": "Confirm that there are 2.2 Bohr magnetons associated with each iron atom, given that the saturation magnetization is 1.70 × 10^{6} \\mathrm{~A} / m, that iron has a BCC crystal structure, and that the unit cell edge length is 0.2866 nm.", + "answer": "2.16 bohr magnetons/atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（饱和磁化强度、晶体结构、晶胞边长）进行数值计算，最终得出每个铁原子对应的玻尔磁子数。解答过程需要应用相关公式和单位转换，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，包括利用BCC晶体结构信息计算单位体积内的铁原子数，应用饱和磁化强度公式，并将结果转换为玻尔磁子单位。这涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（饱和磁化强度、BCC晶体结构、单位晶胞边长）并进行多步计算（包括单位体积原子数计算、磁矩转换等），但尚未涉及复杂多变量或非常规公式推导。" + }, + { + "idx": 4609, + "question": "There is associated with each atom in paramagnetic and ferromagnetic materials a net magnetic moment. Explain why ferromagnetic materials can be permanently magnetized whereas paramagnetic ones cannot.", + "answer": "Ferromagnetic materials may be permanently magnetized (whereas paramagnetic ones may not) because of the ability of net spin magnetic moments of adjacent atoms to align with one another. This mutual magnetic moment alignment in the same direction exists within small volume regions--domains. When a magnetic field is applied, favorably oriented domains grow at the expense of unfavorably oriented ones, by the motion of domain walls. When the magnetic field is removed, there remains a net magnetization by virtue of the resistance to movement of domain walls; even after total removal of the magnetic field, the magnetization of some net domain volume will be aligned near the direction that the external field was oriented.\nFor paramagnetic materials, there is no magnetic dipole coupling, and, consequently, domains do not form. When a magnetic field is removed, the atomic dipoles assume random orientations, and no magnetic moment remains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么铁磁材料可以被永久磁化而顺磁材料不能，需要详细的文字解释和论述，答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释铁磁性和顺磁性材料在磁化行为上的差异，涉及磁矩排列、磁畴形成和运动等复杂机理。需要综合运用多个概念（如磁矩、磁畴、磁畴壁运动等）进行推理分析，解释永久磁化的原因。这超出了简单记忆或基本应用，属于对材料磁学行为的深入理解和综合分析。 | 难度: 在简答题题型中，该题目属于复杂现象全面分析的难度等级。题目要求解释铁磁性和顺磁性材料在磁化行为上的差异，涉及多个复杂概念的综合运用，包括磁矩排列、磁畴形成和运动、以及外加磁场移除后的行为机制。解答需要深入理解这些概念之间的相互作用，并进行逻辑严密的推理分析。此外，答案还需要对比两种材料的不同行为，进一步增加了分析的复杂性。因此，在简答题题型中，该题目属于最高难度等级。" + }, + { + "idx": 4611, + "question": "Why does the magnitude of the saturation magnetization decrease with increasing temperature for ferromagnetic materials?", + "answer": "The saturation magnetization decreases with increasing temperature because the atomic thermal vibrational motions counteract the coupling forces between the adjacent atomic dipole moments, causing some magnetic dipole misalignment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象的原因，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释铁磁材料饱和磁化强度随温度变化的机理，涉及原子热振动与磁偶极矩耦合作用的分析，需要综合运用热力学和磁学知识进行推理和解释，属于较深层次的理解和分析。 | 难度: 在简答题题型中，该题目要求对铁磁材料的饱和磁化强度随温度变化的机理进行深度解释。需要综合运用热振动与磁偶极耦合的知识，分析温度升高如何通过原子热运动影响磁矩排列。这属于机理深度解释的范畴，但尚未达到需要全面分析多个交互作用的复杂现象（如还需考虑居里温度、相变等），因此评定为等级4。" + }, + { + "idx": 4612, + "question": "Why does ferromagnetic behavior cease above the Curie temperature for ferromagnetic materials?", + "answer": "Ferromagnetic behavior ceases above the Curie temperature because the atomic thermal vibrations are sufficiently violent so as to completely destroy the mutual spin coupling forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行解释和论述，答案是一段文字解释，没有选项、判断对错或计算步骤。 | 知识层次: 题目要求解释铁磁材料在居里温度以上铁磁性消失的机理，涉及原子热振动与自旋耦合力的相互作用，需要深入理解材料微观行为与宏观性能的关系，属于机理解释层面的综合分析。 | 难度: 在简答题中属于机理深度解释难度，需要理解并解释铁磁材料在居里温度以上行为变化的微观机理，涉及原子热振动与自旋耦合力的相互作用，属于较深层次的理论分析。" + }, + { + "idx": 4613, + "question": "An iron bar magnet having a coercivity of 4000 \\mathrm{~A} / m is to be demagnetized. If the bar is inserted within a cylindrical wire coil 0.15{m} long and having 100 turns, what electric current is required to generate the necessary magnetic field?", + "answer": "the required electric current is 6 \\mathrm{a}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用（如计算电流大小），答案也是具体的数值结果（6 A）。 | 知识层次: 题目主要涉及基本公式的应用（H = nI/l）和简单计算，不需要多步推理或综合分析，属于直接套用公式求解电流的简单应用类型。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的磁场强度公式 H = nI/l，其中n是线圈匝数，I是电流，l是线圈长度。直接代入已知数值即可求解电流，无需多个公式组合或复杂计算步骤。" + }, + { + "idx": 4614, + "question": "Visible light having a wavelength of 6 x 10^-7 m appears orange. Compute the frequency of a photon of this light.", + "answer": "the frequency of the photon is 5 x 10^14 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（使用波长和频率的关系公式）得出具体数值结果，答案是一个具体的计算值（5 x 10^14 s^-1），符合计算题的特征。 | 知识层次: 题目要求使用基本公式（频率=光速/波长）进行简单计算，属于直接套用公式的应用层次，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目仅要求使用光速公式（c = λν）进行简单代数运算，无需多步骤推导或复杂概念理解，完全符合等级1\"单一公式直接计算\"的特征。同类题型中，这是最基础的频率计算问题，仅需掌握波长与频率的换算关系即可完成。" + }, + { + "idx": 4615, + "question": "Visible light having a wavelength of 6 x 10^-7 m appears orange. Compute the energy of a photon of this light.", + "answer": "the energy of the photon is 3.31 x 10^-19 j (2.07 ev).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如光子能量公式E=hc/λ）来求解光子的能量，答案以具体数值形式给出。 | 知识层次: 题目要求计算光子的能量，涉及基本公式E=hc/λ的直接应用，属于简单计算和基本公式套用，不需要多步计算或综合分析。 | 难度: 在计算题中属于最简单难度，只需要直接应用单一公式（E=hc/λ）进行计算，无需额外的步骤或复杂的公式组合。题目提供了所有必要的数据，计算过程简单直接。" + }, + { + "idx": 4616, + "question": "What are the characteristics of opaque materials in terms of their appearance and light transmittance?", + "answer": "Opaque materials are impervious to light transmission; it is not possible to see through them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释不透明材料的外观和光透射特性，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对不透明材料基本特性的记忆和理解，仅需回答其外观和光透射性的定义特征，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于基本定义简答，仅需记忆并复述不透明材料的基本特性（不透光性和不可透视性），无需深入解释或复杂论述。" + }, + { + "idx": 4617, + "question": "What are the characteristics of translucent materials in terms of their appearance and light transmittance?", + "answer": "Light is transmitted diffusely through translucent materials (there is some internal light scattering). Objects are not clearly distinguishable when viewed through a translucent material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和描述半透明材料的外观和光透射特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对半透明材料基本特性的记忆和理解，包括其外观和光透射特性的描述，属于基础概念的记忆性知识。 | 难度: 在简答题中，该题目属于概念解释和描述级别。虽然需要解释translucent materials的外观和光透射特性，但答案相对直接，主要涉及基础概念的记忆和简单描述，不需要复杂的分析或阐述多个相互关联的概念体系。" + }, + { + "idx": 4618, + "question": "What are the characteristics of transparent materials in terms of their appearance and light transmittance?", + "answer": "Virtually all of the incident light is transmitted through transparent materials, and one can see clearly through them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释透明材料的外观和透光特性，答案需要文字描述和论述，没有提供选项或要求计算 | 知识层次: 题目考查透明材料的基本特性，包括外观和光透射率的定义和描述，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目属于基本定义简答级别。题目仅要求回答透明材料的外观和透光特性，答案直接引用基础定义即可完成，不需要进行概念解释或复杂体系阐述。这符合等级1\"基本定义简答\"的标准，是同类题型中最基础的问题类型。" + }, + { + "idx": 4619, + "question": "In ionic materials, how does the size of the component ions affect the extent of electronic polarization?", + "answer": "In ionic materials, the larger the size of the component ions the greater the degree of electronic polarization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要解释离子尺寸如何影响电子极化程度，答案以文字论述形式给出，没有选项或计算要求。 | 知识层次: 题目考查离子材料中离子尺寸对电子极化影响的基本概念记忆和理解，属于基础原理的直接应用，不需要复杂的分析或综合过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释离子材料中离子尺寸对电子极化程度的影响，需要理解并描述基本原理，但不需要进行复杂的体系阐述或多概念整合。属于基础概念记忆层次中的中等难度。" + }, + { + "idx": 4620, + "question": "Can a material have an index of refraction less than unity? Why or why not?", + "answer": "In order for a material to have an index of refraction less than unity, the velocity of light in the material (v) would necessarily have to be greater than the velocity of light in a vacuum. This is not possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对材料折射率小于1的可能性进行解释和论述，答案提供了详细的文字解释而非选择、判断或计算。 | 知识层次: 题目考查对折射率基本概念的理解，即折射率与光速的关系，属于基础概念的记忆和理解层面。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释折射率小于1的可能性，并给出原因，这需要理解折射率的基本定义（光速比）以及相关物理限制。虽然涉及基础概念的记忆，但需要一定的逻辑推理来解释为什么这种情况不可能发生，因此属于中等难度的简答题。" + }, + { + "idx": 4621, + "question": "Briefly describe the phenomenon of dispersion in a transparent medium.", + "answer": "Dispersion in a transparent medium is the phenomenon wherein the index of refraction varies slightly with the wavelength of the electromagnetic radiation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述透明介质中的色散现象，答案是一个文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对色散现象的基本定义和原理的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目仅要求对\"dispersion\"现象进行基本定义简答，属于最基础的概念记忆层面。题目不涉及概念间的关联解释或复杂体系阐述，仅需复现单一概念的定义性描述，符合等级1\"基本定义简答\"的标准。在同类简答题中属于认知负荷最低的题型。" + }, + { + "idx": 4622, + "question": "Briefly explain how reflection losses of transparent materials are minimized by thin surface coatings.", + "answer": "The thickness and dielectric constant of a thin surface coating are selected such that there is destructive interference between the light beam that is reflected from the lens-coating interface and the light beam that is reflected from the coating-air interface; thus, the net intensity of the total reflected beam is very low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释透明材料如何通过薄表面涂层减少反射损失，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释如何通过表面涂层最小化透明材料的反射损失，涉及光的干涉原理和涂层材料的选择，需要综合运用光学和材料科学的知识进行推理分析，解释机理解释。 | 难度: 在简答题的复杂分析层次中，该题目要求对透明材料表面涂层的反射损失最小化机理进行深度解释。需要综合运用光学干涉原理、材料介电常数选择等知识，并能够清晰地阐述破坏性干涉如何导致反射光束强度降低。虽然不涉及多因素交互作用的全面分析，但对单一物理现象的机理解释已达到较高深度，符合等级4的标准。" + }, + { + "idx": 4623, + "question": "The index of refraction of corundum \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\right) is anisotropic. Suppose that visible light is passing from one grain to another of different crystallographic orientation and at normal incidence to the grain boundary. Calculate the reflectivity at the boundary if the indices of refraction for the two grains are 1.757 and 1.779 in the direction of light propagation.", + "answer": "the reflectivity at the boundary is 3.87 × 10^{-5}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解反射率，答案是一个具体的数值结果（3.87 × 10^{-5}），符合计算题的特征。 | 知识层次: 题目需要应用反射率公式进行计算，涉及多步计算和概念关联（折射率各向异性、晶界反射率计算），但不需要复杂的综合分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用反射率公式并进行多步计算。题目涉及各向异性折射率的概念理解，以及在不同晶粒间光传播方向上的折射率差异计算。虽然计算步骤明确，但需要对物理概念有较好的掌握才能正确应用公式。" + }, + { + "idx": 4624, + "question": "Briefly explain what determines the characteristic color of a metal.", + "answer": "The characteristic color of a metal is determined by the distribution of wavelengths of the nonabsorbed light radiation that is reflected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释金属特征颜色的决定因素，答案是通过文字解释和论述来回答的，符合简答题的特征。 | 知识层次: 题目考查金属特征颜色的基本原理，仅需记忆和理解光辐射反射与吸收的基本概念，不涉及复杂分析或综合应用。 | 难度: 在简答题中属于中等难度，需要解释金属特征颜色的决定因素，涉及对非吸收光波长分布的理解，但不需要复杂的体系阐述或深入分析。" + }, + { + "idx": 4625, + "question": "Briefly explain what determines the characteristic color of a transparent nonmetal.", + "answer": "The characteristic color of a transparent nonmetal is determined by the distribution of wavelengths of the nonabsorbed light radiation that is transmitted through the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释透明非金属特征颜色的决定因素，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对透明非金属材料颜色形成基本原理的记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释透明非金属特征颜色的决定因素，需要理解并描述光辐射波长分布与材料透射特性的关系，这超出了单纯记忆基本定义的层次，但尚未达到需要阐述复杂概念体系的程度。" + }, + { + "idx": 4626, + "question": "Briefly explain why some transparent materials appear colored while others are colorless.", + "answer": "For a transparent material that appears colorless, any absorption within its interior is the same for all visible wavelengths. On the other hand, if there is any selective absorption of visible light (usually by electron excitations), the material will appear colored, its color being dependent on the frequency distribution of the transmitted light beam.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释透明材料为何呈现颜色或无色的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对透明材料颜色现象的基本原理的理解和记忆，涉及光吸收和电子激发等基础概念，不需要复杂的分析或综合应用。 | 难度: 在简答题中属于概念解释和描述难度，需要解释透明材料显色和无色的基本原理，涉及选择性吸收和电子激发等概念，但不需要复杂的体系阐述或多步骤推理。" + }, + { + "idx": 4627, + "question": "Briefly explain why amorphous polymers are transparent, while predominantly crystalline polymers appear opaque or, at best, translucent.", + "answer": "Amorphous polymers are normally transparent because there is no scattering of a light beam within the material. However, for semicrystalline polymers, visible light will be scattered at boundaries between amorphous and crystalline regions since they have different indices of refraction. This leads to translucency or, for extensive scattering, opacity, except for semicrystalline polymers having very small crystallites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释非晶态聚合物透明而结晶态聚合物不透明的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非晶态聚合物透明而结晶态聚合物不透明的机理，涉及光散射、折射率差异等物理原理的综合分析，需要理解材料微观结构与光学性能的关联，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度等级。题目要求解释非晶态聚合物透明而结晶态聚合物不透明的机理，涉及光散射和折射率差异等复杂概念的综合运用。虽然不需要全面分析所有可能的影响因素，但需要对材料的光学性能与微观结构之间的关系有深入理解，并进行合理的推理分析。因此，在简答题题型中属于较高难度等级。" + }, + { + "idx": 4628, + "question": "Zinc has five naturally occurring isotopes: 48.63% of { }^{64} Zn with an atomic weight of 63.929 amu; 27.90% of { }^{66} Zn with an atomic weight of 65.926 amu^{\\text {; }} 4.10% of { }^{67} Zn with an atomic weight of 66.927 amu ; 18.75% of { }^{68} Zn with an atomic weight of 67.925 amu ; and 0.62% of { }^{70} Zn with an atomic weight of 69.925 amu. Calculate the average atomic weight of Zn.", + "answer": "the average atomic weight of \\mathrm{zn} is 65.400 amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（加权平均）来求解锌的平均原子量，答案是一个具体的数值结果。 | 知识层次: 题目要求计算锌的平均原子量，涉及基本公式应用（加权平均）和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目要求计算锌的平均原子量，只需要应用加权平均的公式，将各同位素的原子量乘以其自然丰度后相加即可。解题步骤简单，无需多个公式组合或复杂计算，属于直接套用基本公式的类型。" + }, + { + "idx": 4629, + "question": "Indium has two naturally occurring isotopes: { }^{113} In with an atomic weight of 112.904 amu, and { }^{115} \\mathrm{In} with an atomic weight of 114.904 amu. If the average atomic weight for In is 114.818 amu, calculate the fraction-of-occurrences of these two isotopes.", + "answer": "the fraction-of-occurrence of { }^{113}in is 0.043. the fraction-of-occurrence of { }^{115}in is 0.957.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种同位素的出现分数，答案也是具体的数值结果。 | 知识层次: 题目需要应用基本的同位素丰度计算公式，进行简单的数值计算。虽然涉及多步计算，但整体思路直接，无需复杂的综合分析或推理。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求使用加权平均公式计算同位素丰度，仅需设立一个简单方程并求解。虽然需要理解同位素概念和平均原子量计算原理，但解题步骤直接，不涉及多个公式组合或复杂推导，属于该题型内中等偏下的难度水平。" + }, + { + "idx": 4630, + "question": "Potassium iodide (KI) exhibits predominantly ionic bonding. The K+ ion has an electron structure that is identical to which inert gas?", + "answer": "The K+ ion is just a potassium atom that has lost one electron; therefore, it has an electron configuration the same as argon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释K+离子的电子结构与哪种惰性气体相同，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对离子电子构型与惰性气体电子构型相同这一基本概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于基本定义简答的难度等级。题目要求回答K+离子的电子结构与哪种惰性气体相同，这只需要记忆钾原子失去一个电子后的电子排布与氩原子相同即可。不需要进行复杂的解释或概念阐述，属于最基础的概念记忆性知识。" + }, + { + "idx": 4632, + "question": "With regard to electron configuration, what do all the elements in Group IIA of the periodic table have in common?", + "answer": "Each of the elements in Group IIA has two s electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释Group IIA元素的电子构型共同点，答案需要文字描述而非选择、判断或计算 | 知识层次: 题目考查对元素周期表中IIA族元素电子排布的共同特征的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求回答Group IIA元素的电子构型共同点，属于最基础的定义性知识。不需要解释或描述概念，更不需要构建复杂的概念体系。只需记忆并复述\"有两个s电子\"这一简单事实，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4633, + "question": "To what group in the periodic table would an element with atomic number 112 belong?", + "answer": "From the periodic table the element having atomic number 112 would belong to group IIB. According to the periodic table, Ds, having an atomic number of 110 lies below Pt in the periodic table and in the right-most column of group VIII. Moving two columns to the right puts element 112 under \\mathrm{Hg} and in group IIB.\nThis element has been artificially created and given the name Copernicium with the symbol Cn. It was named after Nicolaus Copernicus, the Polish scientist who proposed that the earth moves around the sun (and not vice versa).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素112在周期表中的归属，并提供了详细的文字解释和论述，而不是从选项中选择或进行简单的对错判断或数值计算。 | 知识层次: 题目主要考查对元素周期表分组的基本概念的记忆和理解，需要知道如何根据原子数确定元素在周期表中的位置和所属族。虽然涉及一些解释，但整体上属于基础知识的直接应用。 | 难度: 在简答题中属于中等难度，需要解释元素周期表中的分组依据，并涉及对特定元素位置的记忆和推理。虽然题目要求基础概念记忆，但需要结合周期表的结构进行一定的逻辑推理和解释，比单纯的定义简答更复杂。" + }, + { + "idx": 4634, + "question": "Without consulting Figure or Table, determine whether the electron configuration (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{5}) is an inert gas, a halogen, an alkali metal, an alkaline earth metal, or a transition metal. Justify your choice.", + "answer": "The (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{5}) electron configuration is that of a halogen because it is one electron deficient from having a filled (p) subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据电子构型判断元素类别，并需要文字解释和论述来证明选择的正确性，而不是从给定的选项中选择或进行简单的对错判断或数值计算。 | 知识层次: 题目考查对电子构型与元素分类之间关系的基本概念记忆和理解，仅需识别电子构型特征并对应到元素周期表中的分类，无需复杂分析或推理。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求根据给定的电子排布判断元素类别，并给出合理解释。这需要学生掌握电子排布与元素周期表族类的基本对应关系，并能进行简单的逻辑推理。虽然涉及基础概念的应用，但不需要复杂的体系阐述或多步骤分析，符合等级2的特征。" + }, + { + "idx": 4640, + "question": "Differentiate (E_{N}) with respect to (r), and then set the resulting expression equal to zero, because the curve of (E_{N}) versus (r) is a minimum at (E_{0}).", + "answer": "The derivative of (E_{N}) with respect to (r) is set to zero to find the minimum.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对数学操作进行解释和论述，而不是选择、判断或计算具体数值。答案需要文字描述微分和极值条件的应用过程。 | 知识层次: 题目要求对(E_{N})关于(r)的导数进行求解，并将其设为零以找到最小值，这涉及多步计算和概念关联，需要理解导数的物理意义以及其在能量曲线中的应用，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求对(E_{N})关于(r)的导数进行分析，并将结果设为零以找到最小值。这需要理解导数的概念及其在极值问题中的应用，属于多步计算和概念关联的综合分析。虽然涉及一定的数学操作，但步骤相对明确，不需要进行多角度或深度关联性分析，因此在该题型内属于等级3的难度。" + }, + { + "idx": 4641, + "question": "Solve for (r) in terms of (A, B), and (n), which yields (r_{0}), the equilibrium interionic spacing.", + "answer": "The equilibrium interionic spacing (r_{0}) is solved in terms of (A, B), and (n).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算求解平衡离子间距(r_{0})，涉及数值计算和公式应用 | 知识层次: 题目要求解平衡离子间距(r_{0})，涉及多个变量(A, B, n)的计算，需要应用相关公式并进行多步推导，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用多个概念（如平衡间距、离子间作用力等），涉及多步计算和变量处理，但尚未达到复杂多变量计算的程度。" + }, + { + "idx": 4642, + "question": "Determine the expression for (E_{0}) by substitution of (r_{0}) into Equation.", + "answer": "The bonding energy (e_{0}) is given by: (e_{0}=-\frac{a}{\\left(\frac{a}{nb}\right)^{1 /(1-n)}}+\frac{b}{\\left(\frac{a}{nb}\right)^{n /(1-n)}})", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过代入公式进行计算，并给出具体的表达式，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目要求通过将(r_{0})代入方程来确定(E_{0})的表达式，涉及多步计算和公式应用，需要理解相关概念并进行适当的数学操作。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式要复杂一些。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求通过代入(r_{0})到方程中推导出(E_{0})的表达式，涉及代数运算和指数处理，但步骤相对明确，没有过于复杂的变量或极端抽象的概念。" + }, + { + "idx": 4643, + "question": "Explain why hydrogen fluoride (HF) has a higher boiling temperature than hydrogen \\\\ chloride (\\mathrm{HCl})\\left(19.4 \\mathrm{vs} .-85^{\\circ} C\\right), even though \\mathrm{HF} has a lower molecular weight.", + "answer": "The intermolecular bonding for \\mathrm{HF} is hydrogen, whereas for \\mathrm{HCl}, the intermolecular bonding is van der Waals. Since the hydrogen bond is stronger than van der Waals, HF will have a higher melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释氢氟酸（HF）比氯化氢（HCl）沸点高的原因，答案需要文字解释和论述，涉及分子间作用力的比较，属于简答题类型。 | 知识层次: 题目要求解释HF和HCl沸点差异的原因，涉及氢键和范德华力的比较，需要理解分子间作用力的类型及其对物理性质的影响，属于概念关联和综合分析层次。 | 难度: 在简答题中属于中等难度，需要理解氢键和范德华力的概念，并能比较它们的强度差异对沸点的影响。虽然涉及多个概念的综合分析，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 4645, + "question": "What type(s) of bonding would be expected for calcium fluoride (CaF2)?", + "answer": "For CaF2, the bonding is predominantly ionic (but with some slight covalent character) on the basis of the relative positions of Ca and F in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释CaF2的键合类型，需要文字论述和解释，而不是选择、判断或计算 | 知识层次: 题目考查对化学键类型的基本概念记忆和理解，需要根据元素在周期表中的位置判断主要键型，属于基础知识的直接应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释CaF2的键合类型，需要理解离子键和共价键的基本概念，并能根据元素在周期表中的位置分析键合性质。虽然涉及一定的分析，但不需要复杂的体系阐述或多步骤推理，属于中等难度的概念解释题。" + }, + { + "idx": 4647, + "question": "What type(s) of bonding would be expected for cadmium telluride (CdTe)?", + "answer": "For CdTe, the bonding is predominantly covalent (with some slight ionic character) on the basis of the relative positions of Cd and Te in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释CdTe的键合类型，需要文字解释和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目要求考生根据元素在周期表中的位置分析CdTe的键合类型，涉及对元素电负性差异的理解和键合性质的判断，需要将基本概念（共价键和离子键）与具体元素特性相结合进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要理解Cd和Te在周期表中的位置关系，并分析其键合性质，但解题步骤相对直接，主要涉及单一概念的综合应用。不需要多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 4649, + "question": "What type(s) of bonding would be expected for tungsten?", + "answer": "For tungsten, the bonding is metallic since it is a metallic element from the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钨的键合类型，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对金属元素钨的键合类型的基本概念记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，该题目属于基本定义简答难度。题目仅要求识别钨的键合类型（金属键），并基于其在周期表中的位置进行简单解释。不需要深入的概念解释或复杂体系阐述，仅需基础概念记忆即可回答。" + }, + { + "idx": 4650, + "question": "Which of the following electron configurations is for an inert gas? \\\\ (A) 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} \\\\ (B) 1 s^{2} 2 s^{2} 2 p^{6} s 3 s^{2} \\\\ (C) 1 s^{2} 2 s^{2} 2 p^{6} .3 s^{2} 3 p^{6} 4 s^{1} \\\\ (D) 1 s^{2} 2 s^{2} 2 p^{6}·3 s^{2} 3 p^{6} 3 d^{2} 4 s^{2}", + "answer": "The correct answer is A. The 1 s^{2} 2 s^{2} 2 p^{6} 13 s^{2} 3 p^{6} electron configuration is that of an inert gas because of filled 3 s and 3 p subshells.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案明确指出了正确选项A。 | 知识层次: 题目考查对惰性气体电子排布的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解惰性气体的电子排布特征（全满电子层），并能识别选项中符合该特征的配置。虽然涉及基础概念记忆，但需要对电子排布模式进行简单辨析，比单纯记忆定义稍复杂。选项B/C/D的错误较为明显（未填满p轨道/有未配对电子/包含d轨道），干扰项区分度较高。" + }, + { + "idx": 4651, + "question": "What type(s) of bonding would be expected for bronze (a copper-tin alloy)?\n(A) Ionic bonding\n(B) Metallic bonding\n(C) Covalent bonding with some van der Waals bonding\n(D) van der Waals bonding", + "answer": "The correct answer is B. For bronze, the bonding is metallic because it is a metal alloy.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案。 | 知识层次: 题目考查对金属合金键合类型的基本概念记忆和理解，属于基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于简单难度，题目直接考察对金属合金键合类型的基本记忆，只需识别青铜（铜锡合金）的键合类型为金属键，无需复杂辨析或深度理解。" + }, + { + "idx": 4652, + "question": "What type(s) of bonding would be expected for rubber?\n(A) Ionic bonding\n(B) Metallic bonding\n(C) Covalent bonding with some van der Waals bonding\n(D) van der Waals bonding", + "answer": "FE}\nThe correct answer is C. For rubber, the bonding is covalent with some van der Waals bonding. (Rubber is composed primarily of carbon and hydrogen atoms.)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了多个选项（A-D）并给出了正确答案（C），符合选择题的特征。 | 知识层次: 题目考查对橡胶材料中化学键类型的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解橡胶的化学键类型（共价键和范德华力）并进行简单辨析，但不需要复杂的分析或深度理解多个概念。" + }, + { + "idx": 4653, + "question": "If the atomic radius of lead is 0.175nm, calculate the volume of its unit cell in cubic meters.", + "answer": "the volume of the unit cell is 1.213 × 10^{-28} m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的原子半径计算单位晶胞的体积，需要使用公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目要求计算单位晶胞的体积，涉及基本的公式应用（如立方晶系的体积计算）和简单的数值计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用立方体的体积公式（V = a^3），其中边长a可以通过原子半径和晶体结构关系直接计算得出（对于面心立方结构，a = 4r/√2）。计算过程简单直接，不需要多个公式组合或复杂推导。" + }, + { + "idx": 4654, + "question": "Calculate the radius of a palladium (P d) atom, given that P d has an FCC crystal structure, a density of 12.0g / {cm}^{3}, and an atomic weight of 106.4g / mol.", + "answer": "the radius of a palladium (pd) atom is 0.138nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钯原子的半径，涉及晶体结构、密度和原子重量等参数的计算，答案是一个具体的数值（0.138nm），符合计算题的特征。 | 知识层次: 题目需要应用FCC晶体结构的基本知识，结合密度和原子重量进行多步计算，涉及单位转换和公式推导，需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要掌握FCC晶体结构的基本参数（如晶胞原子数、配位数等）、密度与晶格常数的关系、原子半径与晶格常数的换算等多步骤计算。虽然不涉及复杂多变量，但需要将多个概念和公式关联起来进行综合分析，属于中等偏上的难度。" + }, + { + "idx": 4655, + "question": "Calculate the radius of a tantalum (Ta) atom, given that Ta has a BCC crystal structure, a density of 16.6g / {cm}^{3}, and an atomic weight of 180.9g / mol.", + "answer": "the radius of a tantalum (ta) atom is 0.143 \\, \\text{nm}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钽原子的半径，答案是一个具体的数值结果（0.143 nm），这符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括BCC晶体结构的理解、密度的计算、原子半径与晶格常数的关系等综合分析。虽然不涉及复杂的推理分析或创新应用，但需要一定的思维深度和知识点的综合运用。 | 难度: 在计算题中属于综合性计算问题，需要应用BCC晶体结构的相关公式，结合密度和原子质量进行多步计算，涉及单位转换和概念关联，但不需要处理复杂多变量。" + }, + { + "idx": 4656, + "question": "Titanium (Ti) has an HCP crystal structure and a density of 4.51 g/cm^3. What is the volume of its unit cell in cubic meters?", + "answer": "the volume of the ti unit cell is 1.058 x 10^-28 m^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钛的晶胞体积，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的密度和晶体结构公式进行计算，属于直接套用公式的简单应用，不涉及多步计算或复杂分析。 | 难度: 在计算题中属于简单应用难度，需要应用密度和晶体结构的基本公式进行计算，但不需要多个公式组合或复杂推导。解题步骤包括查找钛的原子质量、计算晶胞体积，属于直接套用公式的范畴。" + }, + { + "idx": 4657, + "question": "Titanium (Ti) has an HCP crystal structure and a density of 4.51 g/cm^3. If the c/a ratio is 1.58, compute the values of c and a.", + "answer": "the values of a and c are 0.296 nm and 0.468 nm, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Titanium的晶格常数a和c的值，答案也是具体的数值结果。 | 知识层次: 题目需要多步计算和概念关联，涉及HCP晶体结构的几何参数计算、密度公式应用以及c/a比值的综合分析，需要将多个知识点结合起来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要掌握HCP晶体结构的基本参数、密度计算公式以及c/a比的概念。解题过程涉及多步计算，包括晶胞体积的计算、原子数的确定以及密度的转换，需要综合分析多个概念并进行数值计算。虽然不涉及复杂多变量，但步骤较多且需要准确应用公式，因此在同类题型中属于中等偏上的难度。" + }, + { + "idx": 4658, + "question": "Magnesium (Mg) has an HCP crystal structure and a density of 1.74 g/cm3. What is the volume of its unit cell in cubic centimeters?", + "answer": "the volume of the unit cell is 1.39 × 10^-22 cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的晶胞体积，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用HCP晶体结构的基本公式和密度公式进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单应用级别，需要应用HCP晶体结构的密度公式进行计算，但步骤较为直接，仅涉及基本公式套用和单位转换，无需多个公式组合或复杂推导。" + }, + { + "idx": 4659, + "question": "Magnesium (Mg) has an HCP crystal structure and a density of 1.74 g/cm3. If the c/a ratio is 1.624, compute the values of c and a.", + "answer": "the values of a and c are 0.321 nm and 0.521 nm, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的晶格常数a和c的值，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及HCP晶体结构的参数计算和密度公式的应用，需要将多个概念关联起来进行综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用HCP晶体结构的相关公式，结合密度和c/a比进行多步计算，涉及单位转换和综合分析，但不需要处理复杂多变量。" + }, + { + "idx": 4660, + "question": "The unit cell for uranium (U) has orthorhombic symmetry, with a, b, and c lattice parameters of 0.286,0.587, and 0.495nm, respectively. If its density, atomic weight, and atomic radius are 19.05g / {cm}^{3}, 238.03g / mol, and 0.1385nm, respectively, compute the atomic packing factor.\n\\title{", + "answer": "the atomic packing factor (apf) for uranium is 0.536.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铀的原子堆积因子（APF），涉及密度、晶格参数、原子量等数据的计算，最终得出一个具体的数值结果（0.536）。 | 知识层次: 题目需要多步计算和概念关联，包括计算晶胞体积、原子体积、原子数等，并综合应用密度、原子量等参数，思维过程有一定深度要求。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算原子堆积因子（APF），涉及晶格参数、密度、原子量和原子半径等多个变量的综合运用。虽然计算步骤明确，但需要对晶体结构和APF概念有深入理解，并进行正确的单位转换和公式应用。相比更简单的单步计算题（等级2），此题需要更多的综合分析能力，但尚未达到复杂多变量计算（等级4）的难度。" + }, + { + "idx": 4661, + "question": "Indium (In) has a tetragonal unit cell for which the a and c lattice parameters are 0.459 and 0.495 nm, respectively. If the atomic packing factor and atomic radius are 0.693 and 0.1625 nm, respectively, determine the number of atoms in each unit cell.", + "answer": "4.0 atoms/unit cell", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定每个晶胞中的原子数，答案是一个具体的数值（4.0 atoms/unit cell），这符合计算题的特征。 | 知识层次: 题目需要应用晶格参数、原子堆积因子和原子半径等多重概念，并进行多步计算以确定每个晶胞中的原子数。这涉及到对晶体结构知识的理解和综合应用，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在计算题中属于综合性计算问题，需要结合晶格参数、原子堆积因子和原子半径等多个概念进行多步计算。虽然计算过程较为直接，但需要正确理解和应用相关公式，并进行综合分析。" + }, + { + "idx": 4662, + "question": "Indium (In) has a tetragonal unit cell for which the a and c lattice parameters are 0.459 and 0.495 nm, respectively. The atomic weight of indium is 114.82 g/mol; compute its theoretical density.", + "answer": "7.31 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如晶格参数、原子质量和密度公式）来求解理论密度，答案是一个具体的数值结果（7.31 g/cm3），符合计算题的特征。 | 知识层次: 题目要求计算铟的理论密度，涉及基本的晶格参数和原子量的应用，属于直接套用公式进行简单计算的范畴。虽然需要理解晶格参数和密度的关系，但不需要多步计算或综合分析，思维过程较为直接。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用密度公式（密度=质量/体积），通过给定的晶格参数和原子重量直接计算理论密度，无需多个公式组合或复杂步骤。" + }, + { + "idx": 4663, + "question": "Beryllium (Be) has an HCP unit cell for which the ratio of the lattice parameters c/a is 1.568. If the radius of the Be atom is 0.1143 nm, determine the unit cell volume.", + "answer": "4.87 × 10^{-23} cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及晶格参数和原子半径的计算，最终要求得出单位晶胞体积的数值结果。答案是一个具体的数值，符合计算题的特征。 | 知识层次: 题目需要应用HCP晶格参数与原子半径的关系公式，进行多步计算（包括晶格参数推导和体积计算），涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解HCP晶体结构的基本参数关系（c/a比和原子半径），并应用多步公式推导和计算（包括晶格参数求解和体积计算）。虽然不涉及复杂变量，但需要将多个概念关联并正确执行计算步骤。" + }, + { + "idx": 4664, + "question": "Beryllium (Be) has an HCP unit cell for which the ratio of the lattice parameters c/a is 1.568. If the radius of the Be atom is 0.1143nm, calculate the theoretical density of Be and compare it with the literature value.", + "answer": "the theoretical density of be is 1.84 g/cm3, and the literature value is 1.85 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如HCP晶胞参数、原子半径与密度的关系）来求解理论密度，并与文献值进行比较。答案呈现为具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用HCP晶格参数和原子半径的关系进行多步计算，包括晶格参数的计算、理论密度的推导，并与文献值进行比较。这涉及到对晶体结构、密度计算公式的理解和综合应用，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用HCP晶格参数与原子半径的关系公式，进行多步计算（包括晶胞体积计算、原子数确定、密度公式应用等），并最终与文献值进行对比分析。虽然计算步骤较多，但各步骤逻辑清晰，属于典型的中等应用层次计算题。" + }, + { + "idx": 4665, + "question": "Magnesium ( Mg ) has an HCP crystal structure, a c/a ratio of 1.624 , and a density of 1.74 \\mathrm{g} / {cm}^{3}. Compute the atomic radius for Mg.", + "answer": "the atomic radius for \\mathrm{mg} is 0.160\\;nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的原子半径，答案是一个具体的数值结果（0.160 nm），符合计算题的特征。 | 知识层次: 题目需要应用HCP晶体结构的相关知识，包括c/a比和密度的计算，涉及多步计算和概念关联。虽然不涉及复杂的推理分析，但需要综合运用晶体结构参数和密度公式进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要掌握HCP晶体结构的基本参数（如c/a比）、密度与原子半径的关系，并进行多步计算（包括体积计算、原子堆积因子应用等）。虽然不涉及复杂多变量，但需要综合分析多个概念和公式，属于中等偏上的难度。" + }, + { + "idx": 4666, + "question": "Cobalt (Co) has an HCP crystal structure, an atomic radius of 0.1253nm, and a c/a ratio of 1.623. Compute the volume of the unit cell for Co.", + "answer": "the volume of the unit cell for co is 6.64 × 10^{-23} {cm}^3 or 6.64 × 10^{-2} nm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钴的单位晶胞体积，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求计算HCP晶体结构的单位晶胞体积，涉及基本公式应用（HCP晶胞体积公式）和简单计算（代入已知原子半径和c/a比值进行计算），不需要多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算HCP晶胞体积，需要应用HCP晶胞体积公式（V = (3√3/2) * a^2 * c），并结合给定的原子半径和c/a比进行简单计算。虽然涉及单位转换，但整体步骤较为直接，属于基本公式应用和简单计算范畴。" + }, + { + "idx": 4667, + "question": "One crystalline form of silica \\left(\\mathrm{SiO}_{2}\\right) has a cubic unit cell, and from x-ray diffraction data it is known that the cell edge length is 0.700nm. If the measured density is 2.32g / {cm}^{3}, how many \\mathrm{Si}^{4+} and \\mathrm{O}^{2}-ions are there per unit cell?", + "answer": "there are 8 \\mathrm{si}^{4+} ions and 16 \\mathrm{o}^{2-} ions per \\mathrm{sio}_{2} unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解单位晶胞中的离子数量，答案也是具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括单位转换、密度公式应用以及离子数量的推导，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要结合晶体结构、密度计算和化学计量比等多方面知识。解题步骤包括计算单位晶胞体积、质量，再根据密度和分子量推算离子数量，涉及多步计算和概念关联，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4668, + "question": "A hypothetical AX type of ceramic material is known to have a density of 2.10g / {cm}^{3} and a unit cell of cubic symmetry with a cell edge length of 0.57nm. The atomic weights of the A and X elements are 28.5 and 30.0g / mol, respectively. On the basis of this information, which of the following crystal structures is (are) possible for this material: sodium chloride, cesium chloride, or zinc blende? Justify your choice(s).", + "answer": "of the three possible crystal structures, only sodium chloride and zinc blende have four formula units per unit cell, and therefore, are possibilities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于给定的材料特性和晶体结构知识，通过文字解释和论述来证明哪些晶体结构是可能的，而不是简单的选择或计算。答案需要详细说明为什么某些结构是可能的，这符合简答题的特征。 | 知识层次: 题目需要综合运用密度计算、晶体结构特征和原子量等知识，通过多步计算和概念关联来判断可能的晶体结构。虽然不涉及复杂的机理解释或创新设计，但需要一定的综合分析能力来排除不可能的选项并验证可能的选项。 | 难度: 在简答题题型中，该题目属于较高难度。首先，题目要求考生综合运用晶体结构、密度计算、单位晶胞等知识点进行多步计算和分析。其次，需要考生对三种不同的晶体结构（氯化钠、氯化铯、闪锌矿）有深入理解，并能根据计算结果进行排除和选择。最后，题目还要求考生给出合理的解释和论述，这需要较强的综合分析能力和表达能力。因此，该题目在简答题题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 4669, + "question": "Iron titanate, FeTiO3, forms in the ilmenite crystal structure that consists of an HCP arrangement of O2- ions. Which type of interstitial site will the Fe2+ ions occupy? Why?", + "answer": "From Table, the cation-anion radius ratio is 0.077 nm / 0.140 nm = 0.550. Since this ratio is between 0.414 and 0.732, the Fe2+ ions will occupy octahedral sites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Fe2+离子占据哪种间隙位点及其原因，答案提供了详细的解释和计算过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要应用半径比规则进行判断，涉及多步计算（半径比计算）和概念关联（半径比与间隙位置的关系），属于中等应用层次。虽然题目给出了具体数值，但需要学生理解并应用晶体结构中的间隙位置选择原则，这超出了简单记忆或直接套用的范畴。 | 难度: 在简答题中属于中等难度，需要理解晶体结构、离子半径比的概念，并进行简单的计算和综合分析。虽然涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4671, + "question": "Iron titanate, FeTiO3, forms in the ilmenite crystal structure that consists of an HCP arrangement of O2- ions. What fraction of the total tetrahedral sites will be occupied?", + "answer": "Since both Fe2+ and Ti4+ ions occupy octahedral sites, no tetrahedral sites will be occupied.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么没有四面体位点被占据，需要文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目需要理解ilmenite晶体结构中O2-离子的HCP排列方式，并分析Fe2+和Ti4+离子占据的八面体位点情况，进而推断四面体位点的占据情况。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在简答题中属于中等难度，需要理解HCP结构、离子占据规则以及空位计算等概念，并进行综合分析。虽然不需要多角度论述或深度关联性分析，但解题步骤涉及多个知识点的关联应用。" + }, + { + "idx": 4673, + "question": "To what equation does the expression for interplanar spacing (d_{\text {hkl }}) reduce for crystals having cubic symmetry, given that (a,(b), and c are the lattice parameters?", + "answer": "For the crystals having cubic symmetry, a=b=c. Making this substitution into the given equation leads to (\frac{1}{d_{h k l}^{2}}=\frac{h^{2}}{a^{2}}+\frac{k^{2}}{a^{2}}+\frac{l^{2}}{a^{2}} = \frac{h^{2}+k^{2}+l^{2}}{a^{2}}).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释在立方对称晶体中晶面间距的表达式如何简化，答案提供了详细的推导过程和最终表达式，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求将立方对称晶体的条件代入晶面间距公式进行简化，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在简答题中属于简单应用过程描述。题目要求将立方对称晶体的晶格参数代入晶面间距公式并进行简化，解题步骤直接且仅涉及基本公式的套用，无需深入分析或复杂计算。" + }, + { + "idx": 4674, + "question": "To what equation does the expression for interplanar spacing (d_{\text {hkl }}) reduce for crystals having tetragonal symmetry, given that a, b and c are the lattice parameters?", + "answer": "For crystals having tetragonal symmetry, a=b \neq c. Replacing b with a in the given equation leads to (\frac{1}{d_{h k l}^{2}}=\frac{h^{2}}{a^{2}}+\frac{k^{2}}{a^{2}}+\frac{l^{2}}{c^{2}} = \frac{h^{2}+k^{2}}{a^{2}}+\frac{l^{2}}{c^{2}}).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释并推导出特定晶体对称性下的晶面间距表达式，答案以文字和公式结合的形式呈现，需要论述和解释过程。 | 知识层次: 题目要求将四方晶系的对称性条件（a=b≠c）代入晶面间距公式，并进行简单的代数变换。这属于基本公式的直接应用，不需要多步计算或复杂的概念关联。 | 难度: 在简答题中属于简单应用过程描述，仅需直接套用基本公式并进行简单的代数替换（将b替换为a），无需深入解释或复杂推导。解题步骤清晰且直接，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 4675, + "question": "The number-average molecular weight of a polystyrene is 500,000g / mol. Compute the degree of polymerization.\n\\title{", + "answer": "the degree of polymerization is 4800.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（分子量除以单体分子量）来求解聚合度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求计算聚合度，只需应用基本的分子量计算公式（分子量除以重复单元分子量），属于直接套用公式的简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（聚合度=数均分子量/重复单元分子量）并进行简单除法运算，无需任何变形或组合计算步骤。" + }, + { + "idx": 4677, + "question": "High-density polyethylene may be chlorinated by inducing the random substitution of chlorine atoms for hydrogen. In what ways does this chlorinated polyethylene differ from poly(vinyl chloride)?", + "answer": "chlorinated polyethylene differs from poly(vinyl chloride) in that, for pvc, (1) 25% of the side-bonding sites are substituted with Cl, and (2) the substitution is probably much less random.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来比较两种材料的差异，答案提供了详细的文字说明而非选择、判断或计算。 | 知识层次: 题目要求比较两种聚合物在氯原子取代方面的差异，需要理解高密度聚乙烯氯化后的结构与聚氯乙烯的结构特点，并进行对比分析。这涉及到对聚合物化学结构的理解以及不同取代方式对材料性能的影响，属于中等应用层次的知识。 | 难度: 在简答题中属于较高难度，需要从多个角度（如氯原子取代比例和随机性）对两种聚合物进行比较分析，并解释其差异。这要求考生不仅掌握相关概念，还需要进行综合论述和关联性思考。" + }, + { + "idx": 4678, + "question": "Compare thermoplastic and thermosetting polymers on the basis of mechanical characteristics upon heating.", + "answer": "Thermoplastic polymers soften when heated and harden when cooled, whereas thermosetting polymers harden upon heating, while further heating will not lead to softening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种聚合物在加热时的机械特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物基本特性的记忆和理解，属于基础概念的记忆性知识，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较热塑性聚合物和热固性聚合物在加热时的机械特性，需要考生对两种聚合物的基本特性进行解释和对比。虽然涉及两个概念，但属于基础概念的记忆和简单应用，不需要复杂的分析或体系阐述。" + }, + { + "idx": 4679, + "question": "Compare thermoplastic and thermosetting polymers according to possible molecular structures.", + "answer": "Thermoplastic polymers have linear and branched structures, while for thermosetting polymers, the structures will normally be network or crosslinked.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种聚合物的分子结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物分子结构的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对热塑性聚合物和热固性聚合物的分子结构进行比较和解释，属于概念解释和描述的难度等级。虽然需要记忆和区分两种聚合物的结构特点，但不需要进行复杂的体系阐述或深入的分析推理。" + }, + { + "idx": 4680, + "question": "The number-average molecular weight of a poly(acrylonitrile-butadiene) alternating copolymer is 1,000,000g / mol; determine the average number of acrylonitrile and butadiene repeat units per molecule.", + "answer": "the average number of acrylonitrile and butadiene repeat units per molecule is 9333.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定高分子链中重复单元的平均数量，需要应用分子量和重复单元分子量的公式进行计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用分子量的计算公式，并理解交替共聚物的结构特点，进行多步计算以确定重复单元的平均数量。这涉及到概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题-需要数值计算和公式应用题型中，该题目属于综合性计算问题。需要理解交替共聚物的分子量计算方法，掌握重复单元分子量的概念，并进行多步计算（包括分子量换算和重复单元数量计算）。虽然计算过程明确，但需要将多个概念关联起来综合分析，符合等级3的综合性计算问题特征。" + }, + { + "idx": 4681, + "question": "Calculate the number-average molecular weight of a random poly(isobutylene-isoprene) copolymer in which the fraction of isobutylene repeat units is 0.25 ; assume that this concentration corresponds to a degree of polymerization of 1500 .", + "answer": "the number-average molecular weight of the poly(isobutylene-isoprene) copolymer is \\bar{m}_{n} = 97,700g/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算数均分子量），并给出了具体的条件和公式应用（分数和聚合度），答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及分子量的计算和重复单元分数的应用，需要理解并关联多个概念，如聚合度、重复单元分数和分子量计算等。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要理解共聚物的组成和分子量计算原理，进行多步计算（包括重复单元分子量的加权平均和与聚合度的乘积），并正确应用相关公式。虽然涉及多个概念和步骤，但变量和计算过程相对明确，没有过于复杂的推导或条件限制。" + }, + { + "idx": 4682, + "question": "An alternating copolymer is known to have a number-average molecular weight of 100,000g / mol and a degree of polymerization of 2210 . If one of the repeat units is ethylene, which of styrene, propylene, tetrafluoroethylene, and vinyl chloride is the other repeat unit? Why?", + "answer": "the other repeat unit is vinyl chloride, with a molecular weight of 62.49 \\mathrm{g/mol}. this matches the calculated value of 62.45 \\mathrm{g/mol} for the unknown repeat unit.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（styrene, propylene, tetrafluoroethylene, and vinyl chloride）中选择正确的另一个重复单元，并解释原因。虽然需要计算分子量来验证，但核心是选择正确答案。 | 知识层次: 题目需要计算未知重复单元的分子量，并与给定选项进行匹配。这涉及多步计算（计算平均分子量、推导未知单元分子量）和概念关联（理解共聚物的分子量与聚合度的关系）。虽然不涉及复杂的推理或机理解释，但需要一定的综合分析能力来解决问题。 | 难度: 在选择题中属于较高难度，需要综合运用分子量计算、聚合度概念以及重复单元识别等多个知识点。解题过程涉及多步计算（计算未知重复单元的分子量）和综合分析（将计算结果与给定选项进行匹配），且需要准确理解交替共聚物的结构特征。虽然题目提供了明确的计算路径，但步骤的复杂性和概念的综合运用使其在选择题中达到复杂分析过程的判断等级。" + }, + { + "idx": 4683, + "question": "(a) Determine the ratio of butadiene to acrylonitrile repeat units in a copolymer having a number-average molecular weight of 250,000 g/mol and a degree of polymerization of 4640.", + "answer": "the ratio of butadiene to acrylonitrile repeat units in the copolymer is fb/fa = 4.0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定共聚物中丁二烯和丙烯腈重复单元的比例，答案是一个具体的数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括分子量计算、重复单元比例确定等综合分析过程，涉及多个知识点的综合应用。 | 难度: 在计算题中属于综合性计算问题，需要理解共聚物组成与分子量之间的关系，应用分子量计算公式，并进行多步代数运算来求解重复单元比例。虽然计算步骤明确，但需要将多个概念（分子量、聚合度、重复单元比例）关联起来综合分析，属于中等偏上的难度。" + }, + { + "idx": 4685, + "question": "Crosslinked copolymers consisting of 35 wt% ethylene and 65 wt% propylene may have elastic properties similar to those for natural rubber. For a copolymer of this composition, determine the fraction of both repeat unit types.\n\\title{", + "answer": "the fraction of the ethylene repeat unit is 0.45. the fraction of the propylene repeat unit is 0.55.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定乙烯和丙烯重复单元的比例，需要应用相关的材料科学公式和数值计算。答案以数值形式给出，符合计算题的特征。 | 知识层次: 题目要求根据给定的重量百分比计算重复单元的摩尔分数，涉及基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要根据给定的重量百分比转换为摩尔分数，应用简单的组成计算即可得出结果，无需多个公式组合或复杂步骤。" + }, + { + "idx": 4686, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (a) Linear and atactic poly(vinyl chloride); linear and isotactic polypropylene", + "answer": "No, it is not possible to decide for these two polymers. On the basis of tacticity, the isotactic PP is more likely to crystallize than the atactic PVC. On the other hand, with regard to side-group bulkiness, the PVC is more likely to crystallize.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同聚合物结晶可能性进行比较，并给出理由或解释为什么无法决定，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对不同聚合物的结晶可能性进行比较和判断，需要理解聚合物结构（如线性、等规度）对结晶性能的影响，并进行综合分析。虽然涉及基础概念（如等规度），但需要将这些概念应用于具体案例并进行比较，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求进行多角度分析论述。首先需要判断是否可能比较两种聚合物的结晶倾向，然后根据不同的结构特征（如立构规整度和侧基体积）进行综合分析。题目不仅考察对聚合物结晶基本原理的理解，还需要考生能够权衡不同因素对结晶能力的影响，并给出合理的解释。这种多因素权衡和综合分析的要求使得该题目在同题型中属于较高难度等级。" + }, + { + "idx": 4687, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (b) Linear and syndiotactic polypropylene; crosslinked cis-polyisoprene", + "answer": "Yes, it is possible to decide for these two copolymers. The linear and syndiotactic polypropylene is more likely to crystallize than crosslinked cis-isoprene because linear polymers are more likely to crystallize than crosslinked ones.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行比较，并给出理由或解释为什么无法决定。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对不同聚合物的结晶能力进行比较和解释，需要理解聚合物结构（线性与交联、立体规整性）对结晶性能的影响，并进行综合分析。这涉及多个概念的关联和中等程度的推理分析。 | 难度: 在简答题中属于中等难度，需要理解聚合物结晶性的影响因素（如线性结构、交联结构、立体规整性等），并进行比较分析。题目要求对两种聚合物的结晶可能性进行判断并给出理由，涉及多个概念的关联和综合，但不需要过于深入的分析或复杂的推导。" + }, + { + "idx": 4688, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (c) Network phenol-formaldehyde; linear and isotactic polystyrene", + "answer": "Yes, it is possible to decide for these two polymers. The linear and isotactic polystyrene is more likely to crystallize than network phenol-formaldehyde; network polymers rarely crystallize, whereas isotactic ones crystallize relatively easily.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释哪一种更可能结晶以及原因。这需要详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对不同类型聚合物的结晶能力进行比较和分析，需要理解网络聚合物和线性等规聚合物的结构特点及其对结晶行为的影响。这涉及到多个概念的关联和综合分析，而不仅仅是基础概念的简单记忆或直接应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目要求对两种聚合物的结晶可能性进行比较，但涉及的知识点较为基础，主要是关于网络聚合物和线性等规聚合物的结晶特性。解题步骤包括判断可能性、比较结晶倾向并给出理由，相对直接。综合分析的要求不高，主要依赖对聚合物结构-性能关系的基本理解。" + }, + { + "idx": 4689, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (d) Block poly(acrylonitrile-isoprene) copolymer; graft poly(chloroprene-isobutylene) copolymer", + "answer": "Yes, it is possible to decide for these two copolymers. The block poly(acrylonitrileisoprene) copolymer is more likely to crystallize than the graft poly(chloroprene-isobutylene) copolymer. Block copolymers crystallize more easily than graft ones.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并详细说明哪一种更容易结晶以及原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对不同类型共聚物的结晶能力进行比较和判断，需要理解共聚物结构（嵌段与接枝）对结晶行为的影响，并进行综合分析。这涉及多个概念的关联和一定程度的推理分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度。题目要求对两种不同类型的共聚物（嵌段共聚物和接枝共聚物）的结晶能力进行比较分析，需要综合运用聚合物结晶原理、共聚物结构特性等知识。解题步骤包括：(1)判断是否可比较结晶能力；(2)选择更易结晶的聚合物；(3)给出结构决定性能的理由。这需要学生不仅掌握基本概念，还要能够关联不同知识点进行综合分析，因此属于该题型中较高难度的题目。" + }, + { + "idx": 4690, + "question": "For some hypothetical metal, the equilibrium number of vacancies at 900^{\\circ} C is 2.3 × 10^{25} m^{-3}. If the density and atomic weight of this metal are 7.40g / {cm}^{3} and 85.5g / mol, respectively, calculate the fraction of vacancies for this metal at 900^{\\circ} C.", + "answer": "the fraction of vacancies for this metal at 900^{\\circ} C is 4.41 × 10^{-4}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺位的分数，答案是一个具体的数值结果，需要运用密度、原子量和空缺位数量等参数进行计算。 | 知识层次: 题目需要进行多步计算，包括计算原子密度和空位分数，涉及公式应用和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于中等偏上难度，需要应用多个概念（如密度、原子量、阿伏伽德罗常数）进行多步计算，并综合分析得出空缺分数。虽然步骤较多，但每一步的计算相对直接，没有涉及复杂变量或高级数学技巧。" + }, + { + "idx": 4691, + "question": "(a) Calculate the fraction of atom sites that are vacant for copper (Cu) at its melting temperature of 1084°C (1357 K). Assume an energy for vacancy formation of 0.90 eV/atom.", + "answer": "the fraction of atom sites that are vacant for copper at 1357 k is 4.56 × 10^-4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜在熔点温度下的空位分数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求应用基本公式（空位分数公式）进行简单计算，仅涉及单一概念的直接应用，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式（空位浓度公式）进行简单数值计算，无需任何公式组合或复杂推导步骤。题目明确给出了所有必要参数（熔点和空位形成能），解题过程仅涉及基本代数运算。" + }, + { + "idx": 4692, + "question": "(b) Repeat this calculation at room temperature (298 K). Assume an energy for vacancy formation of 0.90 eV/atom.", + "answer": "the fraction of atom sites that are vacant for copper at 298 k is 6.08 × 10^-16.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算空位分数），并给出了具体的计算条件（温度、空位形成能）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，仅需将给定的能量值和温度代入公式进行计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目要求使用给定的能量值和温度直接套用空位浓度公式进行计算，无需额外的公式组合或复杂步骤。" + }, + { + "idx": 4693, + "question": "(c) What is ratio of N_V/N(1357 K) and N_V/N(298 K) ?", + "answer": "the ratio of n_v/n(1357 k) to n_v/n(298 k) is 7.5 × 10^11.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算两个温度下的N_V/N比值，并给出最终的比值结果。这涉及到数值计算和公式应用，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，涉及不同温度下的比值计算，需要理解相关公式并正确应用，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解并应用相关公式进行多步计算，涉及温度变化对N_V/N比值的影响，需要综合分析不同温度下的计算结果并进行比较。虽然计算步骤较多，但并未涉及复杂多变量或高级数学工具，因此在同类题型中属于中等偏上难度。" + }, + { + "idx": 4694, + "question": "Calculate the number of vacancies per cubic meter in gold (\\mathrm{Au}) at 900^{\\circ} C. The energy for vacancy formation is 0.98 \\mathrm{eV} / atom. Furthermore, the density and atomic weight for Au are 18.63 \\mathrm{g} / {cm}^{3} (at 900^{\\circ} C ) and 196.9g / mol, respectively.", + "answer": "the number of vacancies per cubic meter in gold at 900^{\\circ} C is 3.52 × 10^{24}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解金在900°C时的空位浓度，答案是一个具体的数值结果，解答过程需要运用材料科学中的空位形成能、密度和原子量等参数进行计算。 | 知识层次: 题目需要进行多步计算，包括使用阿伏伽德罗常数、密度和原子质量计算原子数，然后应用空位形成能公式计算空位浓度。这需要理解相关概念并能够综合运用多个知识点进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用多个概念（如密度、原子量、能量计算）并进行多步计算（包括单位转换、公式应用等）。虽然计算步骤较多，但每一步都有明确的指导方向，属于中等应用层次。" + }, + { + "idx": 4695, + "question": "Calculate the fraction of lattice sites that are Schottky defects for cesium chloride at its melting temperature \\left(645^{\\circ} C\\right). Assume an energy for defect formation of 1.86 \\mathrm{eV}.", + "answer": "the fraction of lattice sites that are schottky defects for cesium chloride at its melting temperature is 7.87 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Schottky缺陷的分数），并给出了具体的能量值和温度条件。答案是一个具体的数值结果，需要通过公式应用和计算得出。 | 知识层次: 题目需要进行多步计算，涉及Schottky缺陷的形成能计算和温度对缺陷浓度的影响，需要应用相关公式进行数值计算，并理解缺陷形成的基本原理。虽然不涉及复杂的综合分析或推理，但需要一定的概念关联和计算能力。 | 难度: 在计算题中属于综合性计算问题，需要应用Schottky缺陷的形成能公式，进行多步计算（包括温度转换、指数运算等），并理解缺陷浓度与温度的关系。虽然计算过程明确，但涉及物理概念的关联和综合运用，属于中等偏上的难度。" + }, + { + "idx": 4696, + "question": "In your own words, briefly define the term stoichiometric.", + "answer": "Stoichiometric means having exactly the ratio of anions to cations as specified by the chemical formula for the compound.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用自己的话简要解释术语\"stoichiometric\"，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"stoichiometric\"这一基本概念的定义记忆和理解，属于基础概念层次 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求用自己的话简要定义\"stoichiometric\"这一术语，不需要进行概念解释或复杂阐述。这属于最基础的概念记忆性知识，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4697, + "question": "Under conditions where cupric oxide (CuO) is exposed to reducing atmospheres at elevated temperatures, some of the Cu2+ ions will become Cu+. Name one crystalline defect that you would expect to form in order to maintain charge neutrality.", + "answer": "For a Cu2+ O2- compound in which a small fraction of the copper ions exist as Cu+, for each Cu+ formed there is one less positive charge introduced (or one more negative charge). In order to maintain charge neutrality, we must either add an additional positive charge or subtract a negative charge. This may be accomplished be either creating Cu2+ interstitials or O2- vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释一种晶体缺陷的形成以维持电荷中性，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析在特定条件下（还原气氛和高温）铜离子价态变化对晶体缺陷形成的影响，并解释如何维持电荷中性。这需要综合运用晶体缺陷、电荷平衡和氧化还原反应的知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在简答题的复杂分析题型中，该题目要求对晶体缺陷的形成机理进行深度解释，需要综合运用电荷平衡原理和缺陷化学知识。虽然不涉及多步骤的复杂现象全面分析，但对单一缺陷类型的形成原因和电荷补偿机制的解释已达到机理深度解释的要求，符合等级4的标准。" + }, + { + "idx": 4698, + "question": "Under conditions where cupric oxide (CuO) is exposed to reducing atmospheres at elevated temperatures, some of the Cu2+ ions will become Cu+. How many Cu+ ions are required for the creation of each defect?", + "answer": "There will be two Cu+ ions required for each of these defects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述在特定条件下CuO中Cu+离子的数量关系，答案需要文字说明而非选择、判断或计算。 | 知识层次: 题目需要理解CuO在还原气氛下的缺陷形成机制，并应用电荷平衡原理进行计算，涉及多步推理和概念关联。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及多步计算和概念关联，但解题步骤相对明确，主要考察学生对氧化还原反应和缺陷化学的理解。需要综合分析CuO在还原气氛下的行为，并解释Cu2+到Cu+的转变过程，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4699, + "question": "Under conditions where cupric oxide (CuO) is exposed to reducing atmospheres at elevated temperatures, some of the Cu2+ ions will become Cu+. How would you express the chemical formula for this nonstoichiometric material?", + "answer": "The chemical formula for this nonstoichiometric material is Cu1+ O or CuO1-x, where x is some small fraction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求用文字解释和论述的方式表达非化学计量材料的化学式，答案需要提供具体的化学式并解释其中的变量含义，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求理解非化学计量材料的化学式表达，需要将氧化还原反应的概念与材料化学式表达相结合，属于中等应用层次。虽然不涉及复杂计算，但需要综合分析CuO在还原气氛下的变化，并正确表达非化学计量比。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及非化学计量材料的化学式表达，但解题步骤相对直接，主要考察对氧化还原反应和化学式书写规则的理解。需要综合分析CuO在还原条件下的变化，并正确表达非化学计量比，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4700, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for FeO.", + "answer": "For FeO, the ionic radii of the Mg2+ and Fe2+ are 0.072 nm and 0.077 nm, respectively. The percentage difference in ionic radii is 6.5%, which is within the acceptable range for a high degree of solubility. Additionally, both MgO and FeO have rock salt crystal structures. Therefore, FeO and MgO are expected to form high degrees of solid solubility, and experimentally, they exhibit 100% solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释FeO与MgO形成完全固溶体的原因，需要文字论述和解释，而不是简单的选择或判断。答案中包含了离子半径比较、晶体结构分析等详细解释，符合简答题的特征。 | 知识层次: 题目要求解释FeO与MgO形成完全固溶体的原因，涉及离子半径比较（需要计算百分比差异）和晶体结构匹配性的分析。这需要理解固溶体形成条件的基本原理，并能将多个概念（离子半径、晶体结构）关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解离子半径差异和晶体结构的概念，并进行综合分析。虽然题目要求解释FeO的情况，但解题步骤相对直接，主要涉及离子半径计算和结构比较，不需要多角度或深度关联性分析。" + }, + { + "idx": 4701, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for BaO.", + "answer": "For BaO, the ionic radii of the Mg2+ and Ba2+ are 0.072 nm and 0.136 nm, respectively. The percentage difference in ionic radii is 47%, which is much larger than the acceptable range. Therefore, BaO is not expected to experience any appreciable solubility in MgO. Experimentally, the solubility of BaO in MgO is very small.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释BaO在MgO中的固溶度问题，需要文字论述和解释，而不是简单的选择或判断。答案中提供了详细的离子半径比较和百分比计算，并给出了实验观察结果，这些都是简答题的典型特征。 | 知识层次: 题目需要理解固溶体的形成条件，特别是离子半径差异对固溶度的影响，并进行具体的计算和解释。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解离子半径差异对固溶体溶解度的影响，并进行简单的计算和解释。虽然涉及多步计算和概念关联，但分析深度和论述角度较为单一，未达到多角度或深度关联性分析的要求。" + }, + { + "idx": 4702, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for PbO.", + "answer": "For PbO, the ionic radii of the Mg2+ and Pb2+ are 0.072 nm and 0.120 nm, respectively. The percentage difference in ionic radii is 40%, which is much larger than the acceptable range. Therefore, PbO is not expected to experience any appreciable solubility in MgO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释PbO在MgO中的固溶度问题，答案提供了详细的文字解释和论述，包括离子半径差异的计算和结论，符合简答题的特征。 | 知识层次: 题目需要应用离子半径差异的计算，并结合固溶体溶解度规则进行分析。虽然涉及基础概念（离子半径、固溶体），但需要多步推理和综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解离子半径差异对固溶体溶解度的影响，并进行简单的百分比计算和解释。虽然涉及多步计算和概念关联，但不需要深入的多角度分析或深度关联性分析。" + }, + { + "idx": 4703, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for CoO.", + "answer": "For CoO, the ionic radii of the Mg2+ and Co2+ are 0.072 nm and 0.072 nm, respectively. The percentage difference in ionic radii is 0%, which is within the acceptable range for a high degree of solubility. Therefore, CoO and MgO are expected to form high degrees of solid solubility, likely 100%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么CoO能与MgO形成完全固溶体，需要文字论述和解释，而不是简单的选择或判断。答案中提供了详细的离子半径比较和解释，符合简答题的特征。 | 知识层次: 题目要求解释CoO与MgO形成完全固溶体的原因，涉及离子半径比较和百分比差异计算，需要理解固溶体形成条件并应用相关概念进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解离子半径的概念并进行比较分析，同时需要解释为什么离子半径的差异会影响固溶体的溶解度。虽然涉及多步计算和概念关联，但不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 4704, + "question": "Suppose that CaO is added as an impurity to Li2O. If the Ca2+ substitutes for Li+, what kind of vacancies would you expect to form? How many of these vacancies are created for every Ca2+ added?", + "answer": "For Ca2+ substituting for Li+ in Li2O, lithium vacancies would be created. For each Ca2+ substituting for Li+, one positive charge is added; in order to maintain charge neutrality, a single positive charge may be removed. Positive charges are eliminated by creating lithium vacancies, and for every Ca2+ ion added, a single lithium vacancy is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述Ca2+替代Li+时形成的空位类型及其数量，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解杂质掺杂对晶体缺陷的影响，并分析电荷平衡机制。虽然涉及基础概念（如离子替代和电荷平衡），但需要将多个概念关联起来进行综合分析，解释缺陷形成的具体过程。这超出了简单记忆或直接套用的范畴，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解掺杂过程中的电荷平衡原理，并能正确分析缺陷类型和数量。虽然涉及多步推理，但概念相对明确，解题步骤较为直接。" + }, + { + "idx": 4705, + "question": "Suppose that CaO is added as an impurity to CaCl2. If the O2- substitutes for Cl-, what kind of vacancies would you expect to form? How many of these vacancies are created for every O2- added?", + "answer": "For O2- substituting for Cl- in CaCl2, chlorine vacancies would be created. For each O2- substituting for a Cl-, one negative charge is added; negative charges are eliminated by creating chlorine vacancies. In order to maintain charge neutrality, one O2- ion will lead to the formation of one chlorine vacancy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述O2-替代Cl-时形成的空位类型及其数量，答案提供了详细的文字解释，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解杂质替代的电荷平衡原理，并分析由此产生的空位类型和数量。虽然涉及基础概念，但需要将多个知识点（离子替代、电荷平衡、空位形成）关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解杂质取代的电荷平衡原理，并能正确推导空位形成机制。题目涉及离子取代和电荷补偿的概念关联，但解题步骤相对明确，不需要多角度或深度关联性分析。" + }, + { + "idx": 4706, + "question": "Which of these elements would you expect to form a substitutional solid solution having complete solubility with nickel? The four Hume-Rothery rules must be satisfied: (1) the difference in atomic radii between Ni and the other element (ΔR%) must be less than ±15%; (2) the crystal structures must be the same; (3) the electronegativities must be similar; and (4) the valences should be the same.", + "answer": "Pt is the only element that meets all of the criteria and thus forms a substitutional solid solution having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个元素中选择满足Hume-Rothery规则的正确答案，答案明确指出了符合条件的元素（Pt），并排除了其他选项（Co和Fe仅在高温下满足条件）。这符合选择题的特征，即从多个选项中选择最合适的答案。 | 知识层次: 题目要求应用Hume-Rothery规则进行综合分析，涉及多个条件的判断和关联，需要理解并应用这些规则来评估不同元素与镍的相容性。虽然不涉及复杂计算，但需要对多个因素进行综合考量，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合应用Hume-Rothery规则的四项标准进行判断。解题过程涉及多个步骤：首先需要了解镍的晶体结构（FCC）和原子半径，然后逐一比对候选元素是否符合四项规则（原子半径差<15%、相同晶体结构、相似电负性、相同价态）。此外，题目还隐含了温度对晶体结构转变的影响（Co和Fe在高温下的同素异构转变），增加了分析的复杂性。虽然选项明确，但需要深入理解和综合分析多个材料科学概念才能正确作答。" + }, + { + "idx": 4708, + "question": "Which of these elements would you expect to form an interstitial solid solution with nickel? The four Hume-Rothery rules must be satisfied: (1) the difference in atomic radii between Ni and the other element (ΔR%) must be less than ±15%; (2) the crystal structures must be the same; (3) the electronegativities must be similar; and (4) the valences should be the same.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Ni.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素中选择符合Hume-Rothery规则的元素形成间隙固溶体，答案给出了具体的选择（C, H, and O），符合选择题的特征。 | 知识层次: 题目要求应用Hume-Rothery规则进行综合分析，涉及原子半径、晶体结构、电负性和化合价等多个因素的关联判断，需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合应用Hume-Rothery规则进行多步判断。题目要求考生同时考虑原子半径差异、晶体结构、电负性和化合价四个因素，并识别出能够形成间隙固溶体的元素。这种综合分析过程比单纯记忆或单一概念应用更为复杂，符合等级4\"复杂分析过程的判断\"的标准。" + }, + { + "idx": 4709, + "question": "What is the composition, in atom percent, of an alloy that consists of 92.5 wt% \\mathrm{Ag} and 7.5 wt% Cu ?", + "answer": "the composition of the alloy is 87.9 \\text{ at}% \\text{ ag} and 12.1 \\text{ at}% \\text{ cu}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如原子百分比的计算）来得出合金的组成，答案也是具体的数值结果。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及原子百分比和重量百分比之间的转换，属于直接套用公式的简单应用。虽然需要一定的计算步骤，但不需要复杂的综合分析或推理。 | 难度: 在计算题中属于简单公式应用计算难度。题目需要应用原子百分比和重量百分比之间的转换公式，但仅涉及单一合金系统的两个组分，计算步骤直接且无需复杂推导。虽然需要理解并应用基本公式，但解题过程相对简单，属于该题型内的中等偏低难度。" + }, + { + "idx": 4710, + "question": "What is the composition, in atom percent, of an alloy that consists of 5.5 wt% \\mathrm{~Pb} and 94.5 wt% \\mathrm{Sn} ?", + "answer": "the composition of the alloy is 3.23 \\text{ at% pb} and 96.77 \\text{ at% sn}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如原子百分比的计算）来确定合金的组成，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的重量百分比到原子百分比的转换计算，需要应用简单的公式和基本的原子量知识，属于直接套用公式的简单应用。 | 难度: 在计算题中属于简单应用难度，需要应用基本的原子百分比计算公式，涉及简单的数值计算和单位转换，但不需要多个公式组合或复杂推导。" + }, + { + "idx": 4711, + "question": "What is the composition, in weight percent, of an alloy that consists of 5 at% Cu and 95 at% Pt?", + "answer": "the composition in weight percent is: 1.68 wt% cu \n98.32 wt% pt", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（原子百分比转换为重量百分比）来得出合金的组成，答案以具体的数值形式给出，符合计算题的特征。 | 知识层次: 题目涉及基本的原子百分比到重量百分比的转换计算，需要应用简单的公式（原子质量与原子百分比的乘积关系），属于直接套用基本公式的简单计算类型。 | 难度: 在计算题-简单应用题型中，该题目需要应用原子百分比与重量百分比转换的基本公式，涉及原子量的简单计算。虽然需要理解概念并进行单位转换，但解题步骤较为直接，仅需套用单一转换公式（无需多步骤推导或复杂公式组合），属于简单公式应用计算范畴。相比等级1的直接查表或单一数值计算稍复杂，但显著低于多公式组合的等级3难度。" + }, + { + "idx": 4712, + "question": "Calculate the composition, in weight percent, of an alloy that contains 105kg of iron, 0.2 kg of carbon, and 1.0kg of chromium.\n\\title{", + "answer": "the composition, in weight percent, of the alloy is: c_{\\mathrm{fe}} = 98.87 \\, \\text{wt}% c_{C} = 0.19 \\, \\text{wt}% c_{\\mathrm{cr}} = 0.94 \\, \\text{wt}%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算合金中各成分的重量百分比），答案是通过公式计算得出的具体数值结果，符合计算题的特征。 | 知识层次: 题目需要进行简单的重量百分比计算，涉及基本公式应用和直接套用，不需要多步计算或复杂分析。 | 难度: 在计算题中属于最低难度，仅需简单套用重量百分比公式（单一公式直接计算），无需复杂步骤或公式组合。题目给出各组分质量，只需计算总质量后分别求百分比，属于基础计算能力范畴。" + }, + { + "idx": 4713, + "question": "What is the composition, in atom percent, of an alloy that contains 44.5 lb m of \\mathrm{Ag}, 83.7 lb_{m} of \\mathrm{Au}, and 5.3 lb_{m} of Cu ?", + "answer": "the composition of the alloy in atom percent is: c_{\\mathrm{ag}} = 44.8 \\, \\text{at}% c_{\\mathrm{au}} = 46.2 \\, \\text{at}% c_{\\mathrm{cu}} = 9.0 \\, \\text{at}% ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算合金中各元素的原子百分比，需要通过数值计算和公式应用来得出具体数值的答案。答案也是以具体的数值形式呈现，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将质量转换为摩尔数，再计算原子百分比，属于中等应用层次。 | 难度: 在计算题-需要数值计算和公式应用这一题型中，该题目属于综合性计算问题。题目要求将质量百分比转换为原子百分比，涉及多个步骤的计算，包括质量到摩尔数的转换、各组分摩尔数的计算以及最终的原子百分比计算。虽然计算过程较为直接，但需要综合运用多个概念和公式，且需要处理多个变量（三种金属的质量和摩尔质量）。因此，在同类题型中属于中等偏上的难度。" + }, + { + "idx": 4714, + "question": "Calculate the number of atoms per cubic meter in \\mathrm{Pb}.", + "answer": "3.30 × 10^{28} atoms/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铅中每立方米的原子数），答案是一个具体的数值结果（3.30 × 10^{28} atoms/m^3），解答过程需要应用材料科学中的密度和原子量等公式进行计算。 | 知识层次: 题目要求计算铅中每立方米的原子数，这涉及基本的公式应用和简单计算，如使用密度和摩尔质量等已知数据。虽然需要理解相关概念，但计算过程直接，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用密度和摩尔质量的基本公式即可得出结果，无需复杂步骤或多公式组合。" + }, + { + "idx": 4715, + "question": "Calculate the number of atoms per cubic meter in chromium.", + "answer": "the number of atoms per cubic meter in chromium is 8.33 × 10^{28} \\ \\text{atoms/m}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铬中每立方米的原子数），答案是一个具体的数值结果（8.33 × 10^{28} atoms/m^3），解答过程需要应用材料科学中的密度和原子量等公式进行计算。 | 知识层次: 题目要求计算铬中每立方米的原子数，这需要应用基本的密度和摩尔质量公式进行简单计算，属于直接套用基本公式的应用层次。 | 难度: 在计算题中属于最低难度，仅需直接套用密度和摩尔质量的基本公式进行单一计算步骤，无需公式组合或复杂转换" + }, + { + "idx": 4716, + "question": "The concentration of \\mathrm{Si} in an \\mathrm{Fe}-\\mathrm{Si} alloy is 0.25 wt%. What is the concentration in kilograms of Si per cubic meter of alloy?", + "answer": "the concentration of \\mathrm{si} is 19.6kg / m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定硅在合金中的浓度，答案以具体数值形式给出。 | 知识层次: 题目涉及基本的单位转换和简单的公式应用，不需要多步计算或复杂的概念关联，主要考查学生对基本公式的直接套用能力。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用简单的浓度转换公式，将重量百分比转换为每立方米的千克数，无需多个公式组合或复杂计算步骤。" + }, + { + "idx": 4717, + "question": "Determine the approximate density of a Ti-6Al-4V titanium alloy that has a composition of 90 wt% \\mathrm{Ti}, 6 wt% \\mathrm{Al}, and 4 wt% V.", + "answer": "the approximate density of the ti-6al-4v titanium alloy is 4.38 \\mathrm{g/cm}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定钛合金的近似密度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用密度计算公式，通过已知成分的重量百分比和各元素的密度进行简单计算，属于基本公式的直接应用和简单计算。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用简单的密度计算公式，即通过各成分的质量分数和纯元素的密度来计算合金的近似密度。解题步骤简单，直接套用公式即可得出结果，无需多个公式组合或复杂的计算过程。" + }, + { + "idx": 4718, + "question": "Calculate the unit cell edge length for an 80 wt% \\mathrm{Ag}-20 wt% \\mathrm{Pd} alloy. All of the palladium is in solid solution, the crystal structure for this alloy is FCC, and the roomtemperature density of P d is 12.02g / {cm}^{3}.", + "answer": "the unit cell edge length for an 80 wt% \\mathrm{ag}-20 wt% \\mathrm{pd} alloy is 0.4050nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算一个80 wt% Ag-20 wt% Pd合金的单位晶胞边长，涉及数值计算和公式应用，答案是一个具体的数值结果（0.4050nm）。 | 知识层次: 题目需要进行多步计算，包括合金密度计算、原子质量计算和晶格常数计算，涉及多个概念的关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的计算能力和对相关公式的理解。 | 难度: 在计算题中属于综合性计算问题，需要掌握多步计算和概念关联。题目要求计算合金的晶胞边长，涉及重量百分比到原子百分比的转换、密度计算以及FCC晶体结构的相关知识。虽然计算步骤较多，但每一步都有明确的公式和逻辑关系，属于中等应用层次的计算题。" + }, + { + "idx": 4719, + "question": "Some hypothetical alloy is composed of 25 wt% of metal A and 75 wt% of metal B. If the densities of metals A and B are 6.17 and 8.00g / {cm}^{3}, respectively, and their respective atomic weights are 171.3 and 162.0g / mol, determine whether the crystal structure for this alloy is simple cubic, face-centered cubic, or body-centered cubic. Assume a unit cell edge length of 0.332nm.", + "answer": "the crystal structure is simple cubic with 1.00 atom per unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算密度、原子重量和单位晶胞边长来确定晶体结构类型，涉及数值计算和公式应用。答案给出了具体的计算结果和结论，属于计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量分数到原子分数的转换、密度计算、单位晶胞原子数的确定等，涉及多个概念的综合应用和关联分析。虽然不涉及复杂的推理或机理解释，但需要较为综合的计算和判断过程。 | 难度: 在计算题中属于综合性计算问题，需要结合重量百分比、密度、原子重量和晶体结构等多方面知识进行多步计算和综合分析。虽然不涉及复杂多变量计算，但解题步骤较为复杂，需要较高的概念关联能力。" + }, + { + "idx": 4720, + "question": "Molybdenum (Mo) forms a substitutional solid solution with tungsten (W). Compute the number of molybdenum atoms per cubic centimeter for a molybdenum-tungsten alloy that contains 16.4 wt% Mo and 83.6 wt% W. The densities of pure molybdenum and tungsten are 10.22 and 19.30g / {cm}^{3}, respectively.", + "answer": "1.73 × 10^{22} \\text{ atoms/cm}^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算钼原子数每立方厘米），需要应用密度和重量百分比等公式，最终答案为具体数值。 | 知识层次: 题目需要进行多步计算，包括质量分数转换为原子分数、计算合金密度、以及最终计算原子数密度。这需要理解并应用多个概念和公式，如质量分数、密度、摩尔质量等，并进行综合分析。虽然不涉及复杂的推理或机理解释，但计算过程较为复杂，超出了简单应用的范围。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目涉及重量百分比与原子数密度的转换，需要综合运用密度、原子量等概念，并进行单位换算和代数运算。虽然计算步骤较多，但每一步都是材料科学中的常规操作，没有涉及复杂多变量或非常规解法。" + }, + { + "idx": 4721, + "question": "Niobium forms a substitutional solid solution with vanadium. Compute the number of niobium atoms per cubic centimeter for a niobium-vanadium alloy that contains 24 wt% nb and 76 wt% V. The densities of pure niobium and vanadium are 8.57 and 6.10g / {cm}^{3}, respectively.", + "answer": "the number of niobium atoms per cubic centimeter is 1.02 × 10^{22} \\text{atoms/cm}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铌原子在钒铌合金中的数量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量分数转换为原子分数、计算合金密度、以及最终计算铌原子数密度。这涉及到多个概念的关联和综合运用，但不需要复杂的推理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要掌握多步计算和概念关联。题目涉及重量百分比转换、密度计算、原子量应用等多个步骤，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4722, + "question": "For a BCC iron-carbon alloy that contains 0.1 wt% C, calculate the fraction of unit cells that contain carbon atoms.\n\\title{", + "answer": "the fraction of unit cells that contain carbon atoms is 9.31 × 10^{-3} atoms/unit cell. there is one carbon atom per 107.5 unit cells.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算含碳原子的晶胞比例），答案给出了具体的计算结果（9.31 × 10^{-3} atoms/unit cell），且解答过程需要应用材料科学中的相关公式和单位换算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位晶胞中碳原子的数量计算和单位晶胞分数的确定，涉及材料科学中的晶体结构和合金成分的基本概念，并需要将这些概念关联起来进行综合分析。虽然计算过程不复杂，但需要理解并应用相关公式和概念，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求计算BCC铁碳合金中碳原子占据的晶胞比例，涉及质量分数到原子数的转换、晶胞体积计算以及单位晶胞内原子数的综合分析。虽然计算步骤明确，但需要综合运用材料科学和晶体学知识，属于中等偏上的难度等级。" + }, + { + "idx": 4723, + "question": "Gold (Au) forms a substitutional solid solution with silver (Ag). Compute the weight percent of gold that must be added to silver to yield an alloy that contains 5.5 × 10^{21} \\mathrm{Au} atoms per cubic centimeter. The densities of pure \\mathrm{Au} and \\mathrm{Ag} are 19.32 and 10.49g / {cm}^{3}, respectively.", + "answer": "15.9 wt%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算金的重量百分比），并给出了具体的密度数据和原子数量要求，需要应用相关公式进行计算才能得出答案15.9 wt%。 | 知识层次: 题目需要进行多步计算，包括原子浓度与质量分数的转换、密度与摩尔质量的应用，以及合金成分的计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行推导和计算。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算合金中金的重量百分比，涉及原子密度、质量转换和百分比计算等多个步骤。虽然计算过程较为复杂，但每一步都有明确的公式和方法可循，属于中等应用层次的计算题。" + }, + { + "idx": 4724, + "question": "Germanium (Ge) forms a substitutional solid solution with silicon (Si). Compute the weight percent of germanium that must be added to silicon to yield an alloy that contains 2.43 × 10^{21} Ge atoms per cubic centimeter. The densities of pure \\mathrm{Ge} and \\mathrm{Si} are 5.32 and 2.33g / {cm}^{3}, respectively.", + "answer": "11.7 wt%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锗的重量百分比，需要运用密度、原子数量等物理量进行计算，最终得出一个具体的数值结果（11.7 wt%）。 | 知识层次: 题目需要进行多步计算，包括原子密度、质量计算和百分比转换，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算合金中锗的重量百分比，涉及原子密度、质量转换和百分比计算等多个步骤。虽然计算过程较为复杂，但题目提供了必要的参数和明确的求解目标，因此属于等级3的综合性计算问题。" + }, + { + "idx": 4725, + "question": "For an ASTM grain size of 6, approximately how many grains would there be per square inch at a magnification of 100x?", + "answer": "32 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出具体的数值结果（32 grains/in.^2），涉及ASTM晶粒尺寸标准的公式应用和数值计算过程。 | 知识层次: 题目考查ASTM晶粒尺寸标准的基本公式应用，仅需直接套用公式计算每平方英寸的晶粒数量，属于简单计算和基本公式应用范畴。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用ASTM晶粒尺寸公式N=2^(n-1)，其中n为晶粒尺寸数，直接代入n=6即可得到答案。无需额外的公式组合或复杂计算步骤，属于最基础的公式应用题型。" + }, + { + "idx": 4726, + "question": "For an ASTM grain size of 6, approximately how many grains would there be per square inch without any magnification?", + "answer": "320000 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据ASTM晶粒度等级6计算每平方英寸的晶粒数量，需要应用相关公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目涉及ASTM晶粒尺寸标准的基本公式应用，只需直接套用公式计算每平方英寸的晶粒数量，无需多步计算或综合分析。 | 难度: 在计算题中属于最低难度等级，仅需直接套用ASTM晶粒度计算公式N=2^(n-1)（其中n为晶粒度数值），进行简单的指数运算即可得出结果，无需任何公式组合或复杂计算步骤。" + }, + { + "idx": 4727, + "question": "Determine the ASTM grain size number if 30 grains per square inch are measured at a magnification of 250 ×.", + "answer": "the astm grain size number is 8.6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数值，答案是一个具体的数值结果（8.6），这表明需要进行计算步骤来得出最终答案。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，仅需单步计算和直接套用公式，无需多步推理或综合分析。 | 难度: 在计算题中属于简单公式应用计算，需要掌握ASTM grain size number的计算公式，并进行简单的数值计算。虽然需要理解公式的含义和单位转换，但整体解题步骤较为直接，属于该题型内的中等难度。" + }, + { + "idx": 4728, + "question": "Determine the ASTM grain size number if 25 grains per square inch are measured at a magnification of 75 ×.", + "answer": "the astm grain size number is 4.8.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数值，答案是一个具体的数值结果（4.8），这表明解答过程涉及计算步骤。 | 知识层次: 题目要求应用ASTM晶粒度计算公式进行简单数值计算，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度，需要应用ASTM晶粒度计算公式，但仅涉及单一公式的直接套用和简单数值计算，无需多个公式组合或复杂推导步骤。" + }, + { + "idx": 4729, + "question": "Briefly explain the difference between self-diffusion and interdiffusion.", + "answer": "Self-diffusion is atomic migration in pure metals--i.e., when all atoms exchanging positions are of the same type. Interdiffusion is diffusion of atoms of one metal into another metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释两种扩散的区别，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即self-diffusion和interdiffusion的定义和区别，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目仅要求对两个基础概念进行简单的定义和区分，属于基本定义简答的范畴。不需要复杂的解释或深入的论述，只需记忆并复述相关定义即可完成作答。" + }, + { + "idx": 4730, + "question": "Self-diffusion involves the motion of atoms that are all of the same type; therefore, it is not subject to observation by compositional changes, as with interdiffusion. Suggest one way in which self-diffusion may be monitored.", + "answer": "Self-diffusion may be monitored by using radioactive isotopes of the metal being studied. The motion of these isotopic atoms may be detected by measurement of radioactivity level.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何监测自扩散现象，答案提供了具体的监测方法并解释了其原理，符合简答题的特征。 | 知识层次: 题目考查的是对自扩散监测方法的简单应用，需要理解自扩散的基本概念并能够提出一种具体的监测方法（使用放射性同位素），属于直接套用基本原理解决具体问题的层次。 | 难度: 在简答题中属于中等难度，需要理解自扩散的概念并说明一种监测方法。虽然不需要复杂的计算或深入的分析，但需要应用放射性同位素的知识来解释监测原理，属于应用方法说明的层次。" + }, + { + "idx": 4731, + "question": "Compare interstitial and vacancy atomic mechanisms for diffusion.", + "answer": "With vacancy diffusion, atomic motion is from one lattice site to an adjacent vacancy. Self-diffusion and the diffusion of substitutional impurities proceed via this mechanism. On the other hand, atomic motion is from interstitial site to adjacent interstitial site for the interstitial diffusion mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种扩散机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对间隙扩散和空位扩散两种原子扩散机制的基本概念和区别的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目要求对两种扩散机制进行解释和比较，属于概念解释和描述的难度等级。虽然需要记忆和区分两种机制的定义和特点，但不需要深入分析或构建复杂的理论体系，因此属于中等难度。" + }, + { + "idx": 4732, + "question": "Cite two reasons why interstitial diffusion is normally more rapid than vacancy diffusion.", + "answer": "Interstitial diffusion is normally more rapid than vacancy diffusion because: (1) interstitial atoms, being smaller, are more mobile; and (2) the probability of an empty adjacent interstitial site is greater than for a vacancy adjacent to a host (or substitutional impurity) atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个原因来解释间隙扩散比空位扩散更快，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对间隙扩散和空位扩散两种基本扩散机制的理解和记忆，属于材料科学中扩散现象的基础概念范畴，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举并简要解释间隙扩散比空位扩散更快的两个原因，涉及对两种扩散机制的基本理解和比较。虽然需要记忆基本原理，但不需要复杂的推导或深入分析，属于中等难度的概念解释类简答题。" + }, + { + "idx": 4733, + "question": "A sheet of steel 5.0-mm thick has nitrogen atmospheres on both sides at 900^{\\circ} C and is permitted to achieve a steady-state diffusion condition. The diffusion coefficient for nitrogen in steel at this temperature is 1.85 × 10^{-10}{m}^{2} / s, and the diffusion flux is found to be 1.0 × 10^{-7} kg / m^{2}·s. Also, it is known that the concentration of nitrogen in the steel at the high-pressure surface is 2kg / m^{3}. How far into the sheet from this high-pressure side will the concentration be 0.5kg / m^{3} ? Assume a linear concentration profile.", + "answer": "the concentration will be 0.5 \\mathrm{kg/m}^{3} at a distance of 2.78 mm from the high-pressure side.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散系数、扩散通量等参数的运算，最终要求计算出一个具体的距离值（2.78 mm）。答案是一个具体的计算结果，而非选择、判断或文字解释。 | 知识层次: 题目涉及稳态扩散条件下的扩散通量计算，需要应用菲克第一定律进行多步计算，包括浓度梯度的确定和距离的计算。虽然题目提供了线性浓度分布的假设简化了计算，但仍需要理解扩散通量与浓度梯度之间的关系，并进行适当的数值计算。这属于中等应用层次，需要概念关联和综合分析能力。 | 难度: 在计算题中属于多步骤计算过程难度。题目虽然涉及扩散系数、浓度梯度等概念，但解题步骤相对明确：首先根据菲克第一定律计算浓度梯度，然后利用线性浓度分布的假设求解距离。整个过程需要应用基本公式并进行代数运算，但不需要处理复杂变量或多重概念交叉分析，属于该题型内中等偏下的难度。" + }, + { + "idx": 4734, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 15h duration will raise the carbon concentration to 0.35 wt% at a point 2.0mm from the surface. Estimate the time necessary to achieve the same concentration at a 6.0-mm position for an identical steel and at the same carburizing temperature.", + "answer": "the time necessary to achieve the same concentration at a 6.0-mm position is 135 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计达到相同碳浓度所需的时间，答案是一个具体的数值结果（135 h），这表明需要进行计算和推导。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数调整，需要理解碳浓度与时间和位置的关系，并进行综合分析来估算时间。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程（如Fick第二定律）进行多步计算，涉及距离与时间的平方根关系推导（x²/Dt=常数），并要求学生理解并关联碳浓度、扩散距离和处理时间之间的相互作用。虽然计算步骤明确，但需要综合分析能力和对扩散原理的掌握，在同题型中属于中等偏上难度。" + }, + { + "idx": 4735, + "question": "The preexponential and activation energy for the diffusion of chromium in nickel are 1.1 × 10^{-4}{m}^{2} / s and 272,000 J/ mol, respectively. At what temperature will the diffusion coefficient have a value of 1.2 × 10^{-14}{m}^{2} / s ?", + "answer": "the temperature at which the diffusion coefficient has a value of 1.2 × 10^{-14} m^{2} / s is 1427 k or 1154^{\\circ} C. alternatively, using the vmse software, the temperature is found to be 1430 k.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数公式（Arrhenius方程）进行数值计算，以求出特定扩散系数对应的温度。答案提供了具体的数值计算结果，并涉及单位转换（开尔文到摄氏度），这些都是计算题的典型特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，需要理解公式中各参数的含义及其相互关系，属于中等难度的应用题目。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，但步骤明确且无复杂变量。" + }, + { + "idx": 4736, + "question": "The activation energy for the diffusion of copper in silver is 193,000 J/ mol. Calculate the diffusion coefficient at 1200 K\\left(927^{\\circ} C\\right), given that D at 1000 K\\left(727^{\\circ} C\\right) is 1.0 × 10^{-14}{m}^{2} / s.", + "answer": "the diffusion coefficient at 1200k is 4.8 × 10^{-13}{m}^{2} / s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和扩散系数数据，应用阿伦尼乌斯方程进行数值计算，最终得出扩散系数的具体数值。答案也是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用阿伦尼乌斯方程计算扩散系数，并理解温度对扩散系数的影响。虽然计算过程相对直接，但需要综合运用扩散理论和数学计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、对数运算和指数运算。虽然计算过程明确，但需要正确关联扩散系数与温度的关系，并准确执行数学运算。相比简单单步计算题（等级2）更复杂，但尚未达到需要处理多变量或非线性关系的等级4难度。" + }, + { + "idx": 4738, + "question": "The steady-state diffusion flux through a metal plate is 7.8 × 10^{-8}kg / m^{2}·s at a temperature of 1200^{\\circ} C(1473 K) and when the concentration gradient is -500kg / m^{4}. Calculate the diffusion flux at 1000^{\\circ} C(1273 K) for the same concentration gradient and assuming an activation energy for diffusion of 145,000 J/ mol.", + "answer": "the diffusion flux at 1000^{\\circ} C(1273k) is 1.21 × 10^{-8}kg / m^{2}·s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散通量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散通量公式并结合温度变化对扩散系数的影响进行计算，同时需要理解激活能的概念及其在扩散过程中的作用。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散通量公式和温度依赖的阿伦尼乌斯方程，涉及多步计算和概念关联（如浓度梯度、温度转换、活化能等），但未达到复杂多变量计算的程度。" + }, + { + "idx": 4739, + "question": "Consider the diffusion of some hypothetical metal Y into another hypothetical metal Z at 950^{\\circ} C; after 10h the concentration at the 0.5mm position (in metal Z) is 2.0 wt% Y. At what position will the concentration also be 2.0 wt% Y after a 17.5h heat treatment again at 950^{\\circ} C ? Assume preexponential and activation energy values of 4.3 × 10^{-4}{m}^{2} / s and 180,000 J/ mol, respectively, for this diffusion system.", + "answer": "the position will be 0.66 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和参数代入，最终需要计算出一个具体的位置数值（0.66 mm）。 | 知识层次: 题目需要进行多步计算，包括应用扩散方程和参数代入，涉及对扩散过程的理解和综合分析能力。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和计算步骤。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散方程（如Fick第二定律）进行多步计算，涉及时间与位置变量的关联分析，同时需要理解并正确代入给定的预指数因子和活化能参数。虽然计算过程明确，但需要综合运用多个概念和步骤，属于中等偏上的难度。" + }, + { + "idx": 4740, + "question": "Carbon dioxide diffuses through a high-density polyethylene (HDPE) sheet 50mm thick at a rate of 2.2 × 10^{-8}\\left(cm^{3} STP / {cm}^{2}\\right.-s at 325 K. The pressures of carbon dioxide at the two faces are 4000 kPa and 2500 kPa, which are maintained constant. Assuming conditions of steady state, what is the permeability coefficient at 325 K ?", + "answer": "the permeability coefficient at 325k is 0.73 × 10^{-13} \\frac{{cm}^{3} \\mathrm{stp}·{cm}}{{cm}^{2}·s·\\mathrm{pa}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解渗透系数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和稳态条件进行综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用扩散定律和稳态条件进行多步计算，涉及压力差、厚度和扩散率的综合分析，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4741, + "question": "A cylindrical specimen of a nickel alloy having an elastic modulus of 207 \\mathrm{GPa}\\left(30 × 10^{6} psi\\right) and an original diameter of 10.2 mm(0.40 in.) experiences only elastic deformation when a tensile load of 8900N\\left(2000 lb f_{\\mathrm{f}}\\right) is applied. Compute the maximum length of the specimen before deformation if the maximum allowable elongation is 0.25 mm(0.010 in.).", + "answer": "the maximum length of the specimen before deformation is 0.475{m} (475mm or 18.7 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最大长度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用胡克定律、应力应变关系以及几何变形公式，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用弹性模量、应力应变关系、几何变形等多步计算和概念关联。虽然不涉及复杂多变量，但解题步骤较为复杂，需要综合分析能力和公式应用技巧。" + }, + { + "idx": 4742, + "question": "An aluminum bar 125mm (5.0 in.) long and having a square cross section 16.5mm (0.65 in.) on an edge is pulled in tension with a load of 66,700N(15,000 lb) and experiences an elongation of 0.43 mm(1.7 × 10^{-2} in.). Assuming that the deformation is entirely elastic, calculate the modulus of elasticity of the aluminum.", + "answer": "the modulus of elasticity of the aluminum is 71.2 gpa (10.4 × 10^{6} psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性模量计算公式）来求解铝的弹性模量，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的弹性模量计算公式，涉及简单的数值计算和单位转换，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用胡克定律（Hooke's Law）的基本公式E = σ/ε，其中σ是应力（力除以横截面积），ε是应变（伸长量除以原始长度）。计算步骤简单直接，无需多个公式组合或复杂推导。" + }, + { + "idx": 4743, + "question": "Consider a cylindrical nickel wire 2.0 mm(0.08 in.) in diameter and 3 × 10^{4}mm (1200 in.) long. Calculate its elongation when a load of 300N\\left(67 lb^{2}\\right) is applied. Assume that the deformation is totally elastic.", + "answer": "the elongation of the nickel wire is 13.8mm (0.53 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镍丝的伸长量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的材料参数和载荷条件直接套用弹性变形公式进行计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于简单应用难度，需要应用胡克定律和圆柱体的几何关系进行简单计算，但不需要多个公式组合。" + }, + { + "idx": 4744, + "question": "For a brass alloy, the stress at which plastic deformation begins is 345 MPa (50,000 psi), and the modulus of elasticity is 103 GPa (15.0 x 10^6 psi). What is the maximum load that can be applied to a specimen with a cross-sectional area of 130 mm^2 (0.2 in.^2) without plastic deformation?", + "answer": "the maximum load that can be applied without plastic deformation is 44,850 n (10,000 lb_f).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应力=力/面积）来求解最大载荷，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的应力计算和弹性模量的概念，需要应用简单的公式（应力=力/面积）进行计算，属于直接套用基本公式的简单应用。虽然需要理解塑性变形的起始点，但整体思维过程较为直接，不涉及多步计算或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目只需要应用应力公式（应力=力/面积）进行简单的数值代入和计算，没有涉及多个公式的组合或复杂的解题步骤。因此，在该题型内属于最简单的难度等级。" + }, + { + "idx": 4745, + "question": "For a brass alloy, the stress at which plastic deformation begins is 345 MPa (50,000 psi), and the modulus of elasticity is 103 GPa (15.0 x 10^6 psi). If the original specimen length is 76mm (3.0 in.), what is the maximum length to which it can be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen can be stretched without causing plastic deformation is 76.25mm (3.01 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性模量和应力-应变关系）来求解最大拉伸长度，答案也是具体的数值结果。 | 知识层次: 题目需要应用胡克定律（Hooke's Law）进行简单的弹性变形计算，涉及基本的应力-应变关系和模量概念。计算过程直接，仅需一步公式应用和单位转换，属于基本公式的直接套用和简单计算范畴。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用胡克定律（Hooke's Law）来计算弹性变形范围内的最大长度，无需多个公式组合或复杂步骤。计算过程简单直接，属于该题型内最基础的难度水平。" + }, + { + "idx": 4746, + "question": "A cylindrical rod of steel (E=207 \\mathrm{GPa}, 30 × 10^{6} psi) having a yield strength of 310 MPa(45,000 psi) is to be subjected to a load of 11,100N(2500 lb). If the length of the rod is 500 mm(20.0 in.), what must be the diameter to allow an elongation of 0.38 mm(0.015 in.)?", + "answer": "the diameter must be 9.5 mm (0.376 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及弹性模量、载荷和几何尺寸的计算，最终需要得出具体的直径数值。答案也是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括应用胡克定律计算应力、应变关系，以及圆柱体的横截面积计算，涉及多个概念的综合应用和关联。虽然不涉及复杂的推理分析或创新设计，但需要一定的综合分析能力来解决问题。 | 难度: 在计算题中属于综合性计算问题，需要应用胡克定律、应力应变关系以及几何公式进行多步计算。题目涉及单位转换、公式推导和数值计算，但变量关系明确，步骤逻辑清晰，属于中等偏上的难度。" + }, + { + "idx": 4747, + "question": "A cylindrical specimen of a metal alloy 10 mm(0.4 in.) in diameter is stressed elastically in tension. A force of 15,000N(3,370 lb r) produces a reduction in specimen diameter of 7 × 10^{-3} mm(2.8 × 10^{-4} in.). Compute Poisson's ratio for this material if its elastic modulus is 100 \\mathrm{GPa} \\left(14.5 × 10^{6} psi\\right).", + "answer": "poisson's ratio for the material is v = 0.367 .", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括力的计算、直径变化的测量以及弹性模量的使用，最终得出泊松比的具体数值。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目需要应用弹性模量、泊松比和应力应变关系等多个概念，进行多步计算和综合分析，涉及公式推导和数值计算，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用弹性模量、泊松比和应变等多个概念，并进行多步计算。虽然不涉及复杂多变量计算，但需要综合分析力和变形的关系，属于中等偏上的难度。" + }, + { + "idx": 4748, + "question": "Consider a cylindrical specimen of some hypothetical metal alloy that has a diameter of 10.0 mm(0.39 in.). A tensile force of 1500N(340 lb) produces an elastic reduction in diameter of 6.7 × 10^{-4} mm(2.64 ×\n10^{-5} in.). Compute the elastic modulus of this alloy, given that Poisson's ratio is 0.35 .", + "answer": "100 gpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性模量的计算）来求解具体数值，答案是一个具体的数值结果（100 GPa），符合计算题的特征。 | 知识层次: 题目需要应用弹性模量和泊松比的概念，进行多步计算（包括应力、应变的计算和弹性模量的推导），涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用弹性模量、泊松比和应变之间的关系进行多步计算，涉及多个物理概念的关联和综合分析，但计算过程相对直接，没有过于复杂的变量或步骤。" + }, + { + "idx": 4749, + "question": "A cylindrical rod 500mm (20.0 in.) long and having a diameter of 12.7mm (0.50 in.) is to be subjected to a tensile load of 29,000 N (6500 lb). Which of the four metals or alloys listed in the table can experience neither plastic deformation nor an elongation of more than 1.3mm (0.05 in.)?", + "answer": "Of the four metal alloys listed, only brass and steel satisfy the stipulated criteria. Brass has an elongation of 1.15 mm, and steel has an elongation of 0.56 mm, both of which are less than the maximum allowed elongation of 1.3 mm.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从四个金属或合金列表中选择满足特定条件的材料，答案明确指出只有黄铜和钢满足标准，符合选择题的特征。 | 知识层次: 题目需要应用材料力学性能的基本概念（如塑性变形和伸长率）进行多步计算和综合分析，以确定哪种材料满足给定的力学性能要求。这涉及到理解材料的应力-应变行为、计算应力值、比较材料的屈服强度和伸长率等，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用材料力学性能知识（如弹性模量、屈服强度等）进行多步计算和判断。题目要求考生不仅需要计算各材料的应力和应变，还需要比较不同材料的性能参数，并综合考虑塑性变形和伸长量两个限制条件。这种综合分析过程在选择题中属于较为复杂的类型。" + }, + { + "idx": 4750, + "question": "Why is aluminum alloy not a candidate for the cylindrical rod subjected to a tensile load of 29,000 N (6500 lb) with a maximum allowed elongation of 1.3mm (0.05 in.)?", + "answer": "Aluminum alloy is not a candidate because its elongation of 1.64mm exceeds the limit.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么铝合金不适合作为圆柱形杆的材料，答案提供了文字解释和论述，说明铝合金的伸长量超过了允许的极限。这需要基于材料性能的理解和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用材料力学性能知识（如弹性模量、屈服强度等）进行多步计算，并综合分析铝合金的伸长量是否满足限制条件。这涉及概念关联和综合分析，超出了简单记忆或直接套用公式的层次，但尚未达到复杂分析或创新设计的深度。 | 难度: 在简答题中属于中等难度，需要理解材料性能、计算伸长量，并与限制条件进行比较分析。虽然涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4751, + "question": "Why is copper not considered for the cylindrical rod subjected to a tensile load of 29,000 N (6500 lb) with a maximum allowed elongation of 1.3mm (0.05 in.)?", + "answer": "Copper is not considered due to its lower yield strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么铜不被考虑用于特定应用场景，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解铜的力学性能（如屈服强度）与具体工程应用（圆柱杆的拉伸载荷和允许伸长量）之间的关系，并进行综合分析。虽然不涉及复杂计算，但需要将材料性能与实际应用条件关联起来，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要综合分析和说明。题目要求解释为什么铜不被考虑用于承受特定拉伸载荷的圆柱形杆，涉及对材料性能（如屈服强度）的理解和应用。虽然需要一定的概念关联和综合分析，但不需要多角度或深度关联性分析，因此属于等级3。" + }, + { + "idx": 4754, + "question": "The following true stresses produce the corresponding true plastic strains for a brass alloy:\n\\begin{tabular}{cc}\n\\hline True Stress (psi) & True Strain \\\\\n\\hline 60,000 & 0.15 \\\\\n70,000 & 0.25 \\\\\n\\hline\n\\end{tabular}\nWhat true stress is necessary to produce a true plastic strain of 0.21 ?", + "answer": "the true stress necessary to produce a true plastic strain of 0.21 is 66,400 \\, \\text{psi} (460 mpa).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了数据表格，要求通过计算得出特定应变下的应力值，答案是一个具体的数值结果，需要应用材料科学中的应力-应变关系进行计算。 | 知识层次: 题目需要应用基本的应力-应变关系公式进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求根据给定的真实应力和真实塑性应变数据，通过简单的线性插值或外推计算来求解特定应变下的应力值。虽然需要理解应力-应变关系的基本概念，但解题步骤相对直接，仅涉及单一公式的应用和简单计算。" + }, + { + "idx": 4756, + "question": "A three-point bending test was performed on an aluminum oxide specimen having a circular cross section of radius 5.0 mm(0.20 in.); the specimen fractured at a load of 3000N (675 lb f) when the distance between the support points was 40mm (1.6 in.). Another test is to be performed on a specimen of this same material, but one that has a square cross section of 15mm (0.6 in.) length on each edge. At what load would you expect this specimen to fracture if the support point separation is maintained at 40mm (1.6 in.)?", + "answer": "the specimen with a square cross section would be expected to fracture at a load of 17,200 n (3870 lb f).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过已知条件计算出另一个试样的断裂载荷，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括应用三点弯曲测试的公式，比较不同几何形状的试样，并进行相应的转换和计算。虽然不涉及复杂的机理分析或创新设计，但需要综合理解和应用材料力学的基本原理。 | 难度: 在计算题中属于综合性计算问题，需要应用三点弯曲测试的公式，并进行多步计算。题目涉及不同几何形状的转换（圆形截面到方形截面），需要理解弯曲应力与几何参数的关系，并正确代入公式求解。虽然计算步骤较多，但变量关系明确，属于该题型内的中等偏上难度。" + }, + { + "idx": 4758, + "question": "Would you be 100% certain of the answer in part (a)? Why or why not?", + "answer": "the certainty of this prediction is not 100% because there is always some variability in the flexural strength for ceramic materials, and the calculated stress is relatively close to the flexural strength, so there is some chance that fracture will occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对答案的确定性进行解释和论述，答案提供了详细的文字解释，说明为什么不能100%确定，这符合简答题的特征。 | 知识层次: 题目要求对陶瓷材料弯曲强度的预测确定性进行解释，涉及对材料性能变异性的理解、应力与强度关系的综合分析，以及概率性断裂的推理分析。这需要综合运用材料科学知识进行深度推理和解释，属于复杂分析层次。 | 难度: 在简答题题型中，该题目要求对材料性能的变异性进行机理层面的解释，并需要结合具体数值分析（计算应力与弯曲强度的接近程度）来论证不确定性。这属于需要运用专业知识进行深度推理和机理解释的题目，但尚未达到需要分析多个交互因素的复杂现象全面分析程度（等级5）。" + }, + { + "idx": 4759, + "question": "Compute the modulus of elasticity for the nonporous material given that the modulus of elasticity for spinel (MgAl2O4) having 5 vol% porosity is 240 GPa (35 x 10^6 psi).", + "answer": "the modulus of elasticity for the nonporous material is 265 gpa (38.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔材料的弹性模量，答案也是具体的数值结果。 | 知识层次: 题目需要应用孔隙率与弹性模量关系的公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用孔隙率对弹性模量的影响公式进行多步计算，并理解材料性能与孔隙率之间的关系。虽然计算步骤不算极其复杂，但需要综合分析概念和数值计算，属于中等偏上的难度。" + }, + { + "idx": 4760, + "question": "Compute the modulus of elasticity for 15 vol% porosity given that the modulus of elasticity for spinel (MgAl2O4) having 5 vol% porosity is 240 GPa (35 x 10^6 psi).", + "answer": "the modulus of elasticity for 15 vol% porosity is 195 gpa (28.4 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解给定孔隙率下的弹性模量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用多步计算和公式推导，涉及孔隙率对弹性模量的影响分析，需要理解材料性能与孔隙率的关系并进行数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用孔隙率与弹性模量的关系公式进行多步计算，并理解材料性能随孔隙率变化的规律。虽然计算过程明确，但需要对材料科学中的孔隙效应有基本认识，属于中等应用层次的计算题。" + }, + { + "idx": 4761, + "question": "Compute the modulus of elasticity for the nonporous titanium carbide (TiC) given that the modulus of elasticity for titanium carbide (TiC) having 5 vol% porosity is 310 GPa (45 x 10^6 psi).", + "answer": "the modulus of elasticity for the nonporous material is 342 gpa (49.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解无孔隙碳化钛的弹性模量，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及孔隙率对弹性模量的影响，需要应用相关公式（如孔隙率修正公式）进行计算，并理解材料性能与微观结构之间的关系。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求根据已知的含孔隙材料的弹性模量计算无孔隙材料的弹性模量，涉及孔隙率对材料性能的影响分析，需要理解并应用相关公式进行推导和计算。虽然计算步骤不算极其复杂，但需要对材料科学中的孔隙效应有较好的理解，并进行综合分析，因此在同类计算题中属于中等偏上难度。" + }, + { + "idx": 4762, + "question": "At what volume percent porosity will the modulus of elasticity for titanium carbide (TiC) be 240 GPa (35 x 10^6 psi)?", + "answer": "the volume percent porosity at which the modulus of elasticity is 240 gpa (35 x 10^6 psi) is 17.1 vol%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定特定孔隙率下的弹性模量值，需要使用公式进行数值计算，最终给出具体数值结果（17.1 vol%）。 | 知识层次: 题目需要应用材料科学中的孔隙率与弹性模量关系的公式进行计算，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和公式推导，涉及材料科学中的弹性模量与孔隙率关系概念。虽然计算过程明确，但需要综合分析能力和对材料性能的理解，属于中等偏上的难度。" + }, + { + "idx": 4763, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{ll} \\hline (\\sigma_{f_{S}}(\\mathbf{M P a})) & (\boldsymbol{P}) \\ \\hline 70 & 0.10 \\ 60 & 0.15 \\ \\hline \\end{tabular} (a) Compute the flexural strength for a completely nonporous specimen of this material.", + "answer": "the flexural strength for a completely nonporous specimen of this material is 95.3 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据计算无孔隙试样的弯曲强度，需要使用公式和数值计算，答案也是具体的数值结果。 | 知识层次: 题目需要应用公式进行多步计算，并理解孔隙率与弯曲强度之间的关系，属于中等应用层次。 | 难度: 在计算题中属于多步骤计算过程难度。题目提供了两个数据点，需要应用线性回归或插值公式来推导无孔隙情况下的强度值。虽然涉及公式应用和数值计算，但步骤相对明确，不需要处理复杂多变量或高级数学工具。" + }, + { + "idx": 4764, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{ll} \\hline (\\sigma_{f_{S}}(\\mathbf{M P a})) & (\boldsymbol{P}) \\ \\hline 70 & 0.10 \\ 60 & 0.15 \\ \\hline \\end{tabular} (b) Compute the flexural strength for a 0.20 volume fraction porosity.", + "answer": "the flexural strength for a 0.20 volume fraction porosity is 51.5 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的数据计算特定孔隙率下的弯曲强度，需要应用公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目要求根据给定的数据应用基本公式进行计算，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度。题目提供了两个已知数据点，要求根据给定的孔隙率与抗弯强度关系进行简单线性外推计算。虽然需要理解材料孔隙率对强度的影响规律，但解题过程仅涉及基本代数运算和单一公式的直接应用，不需要复杂的推导或多步骤计算。" + }, + { + "idx": 4765, + "question": "For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to\n\\[\n\\sigma(t)=\\sigma(0) \\exp \\left(-\\frac{t}{\\tau}\\right)\n\\]\nwhere \\sigma(t) and \\sigma(0) represent the time-dependent and initial (i.e., time =0 ) stresses, respectively, and t and \\tau denote elapsed time and the relaxation time, respectively; \\tau is a time-independent constant characteristic of the material. A specimen of a viscoelastic polymer whose stress relaxation obeys Equation was suddenly pulled in tension to a measured strain of 0.5 ; the stress necessary to maintain this constant strain was measured as a function of time. Determine E_{f}(10) for this material if the initial stress level was 3.5 MPa(500 psi), which dropped to 0.5 MPa(70 psi) after 30s.", + "answer": "e_{f}(10) = 3.66 \\text{mpa} (522 \\text{psi})", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定E_{f}(10)的值，答案是一个具体的数值结果，解答过程涉及公式代入和计算步骤。 | 知识层次: 题目需要进行多步计算，包括应用给定的应力松弛公式和计算弹性模量，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要理解应力松弛公式并应用初始条件求解松弛时间常数，然后进一步计算特定时间点的应力值。解题过程涉及多步计算和概念关联，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4766, + "question": "The following table gives a number of Rockwellg hardness values that were measured on a single steel specimen. Compute average and standard deviation hardness values.\n\\begin{tabular}{rrr}\n47.3 & 48.7 & 47.1 \\\\\n52.1 & 50.0 & 50.4 \\\\\n45.6 & 46.2 & 45.9 \\\\\n49.9 & 48.3 & 46.4 \\\\\n47.6 & 51.1 & 48.5 \\\\\n50.4 & 46.7 & 49.7\n\\end{tabular}", + "answer": "the average hardness value is 48.4 hrg. the standard deviation of the hardness values is 1.95 hrg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Rockwell硬度值的平均值和标准差，需要应用统计公式进行数值计算，答案以具体数值形式呈现。 | 知识层次: 题目主要涉及基本的数值计算和标准偏差公式的直接应用，不需要多步计算或复杂的概念关联，属于简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算平均值和标准差，这两个都是统计学中的基本公式，计算步骤明确且直接。虽然需要应用两个不同的公式，但都属于基础统计计算范畴，不需要复杂的推导或组合计算。数据量适中（18个数据点），但计算过程仍然保持线性且直接。因此在该题型内属于等级2难度。" + }, + { + "idx": 4767, + "question": "The following table gives a number of yield strength values (in MPa) that were measured on the same aluminum alloy. Compute average and standard deviation yield strength values.\n\\begin{tabular}{rrr}\n274.3 & 277.1 & 263.8 \\\\\n267.5 & 258.6 & 271.2 \\\\\n255.4 & 266.9 & 257.6 \\\\\n270.8 & 260.1 & 264.3 \\\\\n261.7 & 279.4 & 260.5\n\\end{tabular}", + "answer": "the average yield strength is 265.9 \\text{ mpa}. the standard deviation of the yield strength is 7.34 \\text{ mpa}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算屈服强度的平均值和标准差，需要应用统计公式进行数值计算，答案以具体数值形式呈现 | 知识层次: 题目要求计算平均屈服强度和标准偏差，这属于基本的统计计算，仅需要应用简单的数学公式（平均值和标准偏差公式），不需要多步计算或综合分析。题目主要考查基本公式的直接应用能力，属于简单应用层次。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算平均值和标准差，这两个都是统计学中的基本公式应用。虽然涉及多个数据点的处理，但计算步骤明确且直接，不需要复杂的推导或组合多个公式。属于简单应用层次中的典型题目。" + }, + { + "idx": 4768, + "question": "What is the first criterion upon which factors of safety are based?", + "answer": "The first criterion is consequences of failure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个简短的陈述，不需要选择或计算 | 知识层次: 题目考查对安全系数首要准则的基本概念记忆，属于定义性知识，不需要复杂的分析或应用。 | 难度: 在简答题题型中，此题属于基本定义简答级别。题目仅要求回忆并复述安全系数的首要判断标准（失效后果），不涉及概念解释或复杂体系阐述。回答仅需直接引用教材或课堂讲授的基础定义，无需展开分析或推理，符合等级1对记忆性知识点的基本要求。" + }, + { + "idx": 4769, + "question": "What is the second criterion upon which factors of safety are based?", + "answer": "The second criterion is previous experience.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个简短的陈述而非选择或计算 | 知识层次: 题目考查对安全系数第二准则的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目仅要求回忆并复述\"安全系数的第二个判断标准\"这一基础定义，属于最基础的概念记忆层面。题目不涉及概念解释或体系阐述，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这属于知识点掌握深度最浅、解题步骤最简单的一类。" + }, + { + "idx": 4770, + "question": "What is the third criterion upon which factors of safety are based?", + "answer": "The third criterion is accuracy of measurement of mechanical forces and/or material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个完整的句子而非选择或判断 | 知识层次: 题目考查安全系数基础标准的记忆和理解，属于基本原理的记忆性知识 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要回忆并准确表述第三个安全系数的判断标准，但不需要深入分析或构建复杂的概念体系。题目主要考察对基础概念的记忆和简单解释能力，属于中等偏下的难度水平。" + }, + { + "idx": 4771, + "question": "What is the fourth criterion upon which factors of safety are based?", + "answer": "The fourth criterion is economics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的知识点（第四准则是什么），答案需要以文字形式解释和论述，而不是从选项中选择或进行判断/计算。 | 知识层次: 题目考查对安全系数基础分类标准的记忆，属于基本概念的记忆性知识 | 难度: 在简答题题型中，该题目仅要求回忆并复述安全系数的第四个标准（经济学），属于基础概念记忆层面的直接提问。不需要解释或阐述概念之间的关系，也不涉及复杂推理或多步骤分析，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 4772, + "question": "Consider a metal single crystal oriented such that the normal to the slip plane and the slip direction are at angles of 60^{\\circ} and 35^{\\circ}, respectively, with the tensile axis. If the critical resolved shear stress is 6.2 MPa(900 psi), will an applied stress of 12 MPa (1750 psi) cause the single crystal to yield? If not, what stress will be necessary?", + "answer": "the applied stress of 12 MPa will not cause the single crystal to yield. the necessary stress for yielding to occur is 15.1 MPa (2200 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定施加的应力是否足以使单晶屈服，并计算必要的应力值。答案提供了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要应用临界分切应力的概念，进行多步计算（包括角度转换和应力分解），并综合分析结果来判断晶体是否会屈服。这涉及对概念的理解和公式的应用，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用临界分切应力公式进行多步计算，涉及角度转换和应力分量分析，但不需要处理复杂多变量情况。" + }, + { + "idx": 4773, + "question": "A single crystal of zinc is oriented for a tensile test such that its slip plane normal makes an angle of 65 degrees with the tensile axis. Three possible slip directions make angles of 30 degrees, 48 degrees, and 78 degrees with the same tensile axis. Which of these three slip directions is most favored?", + "answer": "the most favored slip direction is at an angle of 30 degrees with the tensile axis.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从三个可能的滑移方向中选择最有利的一个，答案明确给出了最佳选择，符合选择题的特征。 | 知识层次: 题目考查了晶体滑移方向与拉伸轴夹角的基本概念，并需要应用Schmid定律（临界分切应力定律）来选择最有利的滑移方向。虽然涉及角度计算，但只需比较角度大小即可得出答案，属于直接套用基本原理的简单应用。 | 难度: 在选择题中属于简单难度，只需要应用Schmid定律的基本公式（临界分切应力=cosφ*cosλ），比较三个角度对应的cosφ*cosλ值即可得出答案。题目直接给出了所有必要参数，无需公式变形或多步骤计算，属于基本公式的直接套用。" + }, + { + "idx": 4774, + "question": "A single crystal of zinc is oriented for a tensile test such that its slip plane normal makes an angle of 65 degrees with the tensile axis. The most favored slip direction makes an angle of 30 degrees with the same tensile axis. If plastic deformation begins at a tensile stress of 2.5 MPa (355 psi), determine the critical resolved shear stress for zinc.", + "answer": "the critical resolved shear stress for zinc is 0.91 mpa (130 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（临界分切应力公式）来求解锌的临界分切应力，答案是一个具体的数值结果。 | 知识层次: 题目需要应用临界分切应力的计算公式，涉及角度转换和多步计算，需要理解分切应力的概念并将其应用于具体情境，属于中等难度的应用题目。 | 难度: 在计算题中属于多步骤计算过程难度。题目需要应用临界分切应力公式（Schmid定律），涉及角度转换和三角函数计算，但步骤明确且变量较少，无需复杂综合分析或处理多变量关系。属于典型的中等应用层次计算题，但步骤复杂度低于综合性或复杂多变量问题。" + }, + { + "idx": 4775, + "question": "The critical resolved shear stress for copper (Cu) is 0.48 MPa(70 psi). Determine the maximum possible yield strength for a single crystal of Cu pulled in tension.", + "answer": "the maximum possible yield strength for a single crystal of Cu pulled in tension is \\sigma_{y} = 0.96 MPa (140 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（临界分切应力与屈服强度的关系）来确定单晶铜的最大可能屈服强度，答案给出了具体的数值计算结果。 | 知识层次: 题目需要应用临界分切应力的概念和公式进行简单的数值计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在计算题-简单应用题型中，该题目属于单一公式直接计算的难度等级。题目仅需应用临界分切应力与屈服强度的基本关系公式（σ_y = 2τ_cr），无需多步骤推导或复杂转换，且计算过程仅涉及单位换算和简单乘法，完全符合等级1\"直接套用单一公式\"的特征。" + }, + { + "idx": 4776, + "question": "The lower yield point for an iron that has an average grain diameter of 1 × 10^{-2}mm is 230 MPa(33,000 psi). At a grain diameter of 6 × 10^{-3} mm, the yield point increases to 275 MPa (40,000 psi). At what grain diameter will the lower yield point be 310 MPa(45,000 psi) ?\n\\underline{\\text {", + "answer": "the grain diameter at which the lower yield point is 310 MPa is 4.34 × 10^{-3} mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch关系）来求解特定晶粒尺寸下的屈服点，答案是一个具体的数值计算结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解Hall-Petch关系并正确代入数值进行计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch公式进行多步计算，涉及数值转换和代数求解。虽然计算步骤明确，但需要正确理解材料科学中的屈服强度与晶粒尺寸关系，并准确执行数学运算。相比单步计算题（等级2）更复杂，但尚未达到复杂多变量计算（等级4）的程度。" + }, + { + "idx": 4778, + "question": "Experimentally, it has been observed for single crystals of a number of metals that the critical resolved shear stress \\tau_{\\text {CrSS }} is a function of the dislocation density \\rho_{D} as\n\\[\n\\tau_{\\text {crss }}=\\tau_{0}+A \\sqrt{\\rho_{D}}\n\\]\nwhere \\tau_{0} and A are constants. For copper, the critical resolved shear stress is 0.69 MPa(100 psi) at a dislocation density of 10^{4} mm^{-2}. If it is known that the value of \\tau_{0} for copper is 0.069 MPa (10 psi), compute \\tau_{\\text {crss }} at a dislocation density of 10^{6} mm^{-2}.", + "answer": "the critical resolved shear stress \\tau_{\\text{crss}} at a dislocation density of 10^{6} mm^{-2} is 6.28 MPa (910 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和已知条件进行数值计算，最终得出一个具体的数值结果。解答过程需要应用公式和代入数值，符合计算题的特征。 | 知识层次: 题目要求应用给定的公式进行数值计算，虽然需要理解公式中各参数的含义，但计算过程相对直接，属于基本公式应用和简单计算的范畴。 | 难度: 在计算题中属于简单公式应用计算难度。题目给出了明确的公式和已知条件，只需要将已知数值代入公式并进行简单的平方根和乘法运算即可得到结果。虽然需要理解公式中各个参数的含义，但不需要进行复杂的推导或多步骤计算，属于直接套用公式的简单应用类型。" + }, + { + "idx": 4779, + "question": "Briefly cite the differences between the recovery and recrystallization processes.", + "answer": "For recovery, there is some relief of internal strain energy by dislocation motion; however, there are virtually no changes in either the grain structure or mechanical characteristics. During recrystallization, on the other hand, a new set of strain-free grains forms, and the material becomes softer and more ductile.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释恢复和再结晶过程之间的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对恢复和再结晶过程的基本概念的理解和记忆，涉及对两种过程的基本特征和差异的描述，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释和描述两个相关但不同的概念（恢复和再结晶），并比较它们的主要区别。这需要一定的概念理解和描述能力，但不需要复杂的体系阐述或深入的分析。属于概念解释和描述的难度等级。" + }, + { + "idx": 4780, + "question": "What is the driving force for recrystallization?", + "answer": "The driving force for recrystallization is the difference in internal energy between the strained and unstrained material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案提供了详细的解释而非选择或判断 | 知识层次: 题目考查对再结晶驱动力的基本概念的理解和记忆，属于材料科学中的基本原理知识。 | 难度: 在简答题题型中，该题目仅要求回答基本定义（recrystallization的驱动力），属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。同类简答题中，这属于最基础、最直接的问题类型。" + }, + { + "idx": 4781, + "question": "What is the driving force for grain growth?", + "answer": "The driving force for grain growth is the reduction in grain boundary energy as the total grain boundary area decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释grain growth的驱动力，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对晶粒生长驱动力这一基本概念的记忆和理解，属于材料科学中基础原理的范畴，不需要复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述的难度等级。题目要求解释晶粒生长的驱动力，涉及对晶界能量和晶界面积变化的基本理解，但不需要复杂的推导或多层次的概念体系阐述。学生只需准确描述驱动力来源即可，属于中等难度的概念解释题。" + }, + { + "idx": 4782, + "question": "The average grain diameter for a brass material was measured as a function of time at 650 degrees C, which is shown in the following table at two different times: Time (min) 40, Grain Diameter (mm) 5.6 x 10^-2; Time (min) 100, Grain Diameter (mm) 8.0 x 10^-2. What was the original grain diameter?", + "answer": "the original grain diameter was 0.031 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的时间和晶粒直径数据，应用相关公式计算出原始晶粒直径。解答过程涉及数值计算和公式应用，答案是一个具体的数值（0.031 mm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及时间与晶粒直径的关系分析，需要应用相关公式并理解晶粒生长的基本原理，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用多步计算和概念关联。题目要求根据给定的时间与晶粒直径数据，通过公式推导和计算得出原始晶粒直径。虽然计算步骤不算极其复杂，但需要综合分析数据并正确应用相关公式，属于中等应用层次的计算题。" + }, + { + "idx": 4784, + "question": "An undeformed specimen of some alloy has an average grain diameter of 0.050 mm. You are asked to reduce its average grain diameter to 0.020 mm. Is this possible? If so, explain the procedures you would use and name the processes involved. If it is not possible, explain why.", + "answer": "Yes, it is possible to reduce the average grain diameter of an undeformed alloy specimen from 0.050mm to 0.020 mm. In order to do this, plastically deform the material at room temperature (i.e., cold work it), and then anneal at an elevated temperature in order to allow recrystallization and some grain growth to occur until the average grain diameter is 0.020 mm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要详细的文字解释和论述，说明如何通过冷加工和退火来减小晶粒尺寸，并解释相关过程。答案也以文字形式详细描述了操作步骤和原理，符合简答题的特征。 | 知识层次: 题目要求学生理解并应用塑性变形和退火工艺来改变晶粒尺寸，涉及多步工艺的综合应用和概念关联，需要一定的分析和推理能力。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及多步操作（冷加工和退火）以及概念关联（塑性变形、再结晶和晶粒生长），但整体解题思路较为直接，主要考察对材料加工过程的基本理解和应用。不需要进行复杂的多角度分析或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 4785, + "question": "A non-cold-worked brass specimen of average grain size 0.01mm has a yield strength of 150 MPa(21,750 psi). Estimate the yield strength of this alloy after it has been heated to 500^{\\circ} C for 1000s, if it is known that the value of \\sigma_{0} is 25 MPa(3625 psi).", + "answer": "the yield strength of the brass alloy after heating to 500^{\\circ} C for 1000s is 124 MPa (18,000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过已知参数（初始晶粒尺寸、初始屈服强度、热处理条件等）进行计算，并最终给出一个具体的数值结果（124 MPa）。解答过程需要应用材料科学中的相关公式和原理进行数值计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及材料科学中的Hall-Petch关系（σy = σ0 + kd^(-1/2)）的应用，需要理解屈服强度与晶粒尺寸的关系，并能够根据给定的条件进行计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用基本概念和公式进行中等难度的应用计算。 | 难度: 在计算题中属于综合性计算问题，需要应用Hall-Petch关系式进行多步计算，并理解晶粒尺寸与屈服强度的关系。题目涉及初始条件设定、公式转换和参数代入，但未达到复杂多变量计算的程度。" + }, + { + "idx": 4786, + "question": "Normal butane and isobutane have boiling temperatures of -0.5^{\\circ} C and -12.3^{\\circ} C\\left(31.1^{\\circ} F\\right. and 9.9^{\\circ} F ), respectively. Briefly explain this behavior on the basis of their molecular structures.", + "answer": "Normal butane has a higher melting temperature as a result of its molecular structure . There is more of an opportunity for van der Waals bonds to form between two molecules in close proximity to one another than for isobutane because of the linear nature of each normal butane molecule.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释正丁烷和异丁烷沸点差异的原因，答案提供了基于分子结构的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于分子结构解释正丁烷和异丁烷沸点差异的行为，涉及分子间作用力（范德华力）与分子结构的关系，需要将概念关联并进行综合分析。虽然不涉及复杂计算，但需要理解分子结构对物理性质的影响，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求基于分子结构解释正丁烷和异丁烷沸点差异的行为。虽然需要理解分子结构和范德华力的概念，但解释相对直接，主要涉及线性分子与支链分子在分子间作用力上的差异。不需要多角度或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 4787, + "question": "The tensile strength and number-average molecular weight for two poly(methyl methacrylate) materials are as follows:\n\\begin{tabular}{cc}\n\\hline Tensile Strength (MPa) & Number-Average Molecular Weight (g/mol) \\\\\n\\hline 50 & 30,000 \\\\\n150 & 50,000 \\\\\n\\hline\n\\end{tabular}\nEstimate the tensile strength at a number-average molecular weight of 40,000 g/mol.", + "answer": "the estimated tensile strength at a number-average molecular weight of 40,000 g/mol is 112.5 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了具体的数据（拉伸强度和数均分子量），并要求通过计算估计在特定分子量下的拉伸强度。答案是一个具体的数值（112.5 MPa），这表明需要通过数值计算和可能的插值或外推方法来解决问题。 | 知识层次: 题目需要应用基本的线性插值公式进行数值计算，属于直接套用公式的简单应用，无需多步计算或综合分析。 | 难度: 在计算题中属于简单应用难度，需要根据给定的数据点进行线性插值计算。虽然涉及基本公式应用，但解题步骤较为直接，仅需进行一次简单的数学运算即可得出结果。相比等级1的直接套用单一公式，本题需要理解数据之间的关系并进行简单计算，因此属于等级2。" + }, + { + "idx": 4788, + "question": "The tensile strength and number-average molecular weight for two polyethylene materials are as follows:\n\\begin{tabular}{cc}\n\\hline Tensile Strength (MPa) & Number-Average Molecular Weight (g/mol) \\\\\n\\hline 90 & 20,000 \\\\\n180 & 40,000 \\\\\n\\hline\n\\end{tabular}\nEstimate the number-average molecular weight that is required to give a tensile strength of 140 MPa.", + "answer": "the required number-average molecular weight is 27700 g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据（拉伸强度和数均分子量）进行数值计算，估计达到特定拉伸强度所需的数均分子量。答案是一个具体的数值结果，需要通过公式或插值计算得出。 | 知识层次: 题目需要进行多步计算和概念关联，涉及对材料性能与分子量关系的理解和应用，需要综合分析给定的数据并推导出所需的分子量。 | 难度: 在计算题中属于多步骤计算过程难度。题目提供了两个数据点，需要通过线性插值或外推的方法估计第三个数据点。虽然需要应用公式和进行数值计算，但步骤相对直接，不涉及复杂多变量或高级综合分析。" + }, + { + "idx": 4789, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Branched and atactic poly(vinyl chloride) with a weight-average molecular weight of 100,000 g/mol; linear and isotactic poly(vinyl chloride) having a weight-average molecular weight of 75,000 g/mol", + "answer": "Yes, it is possible. The linear and isotactic poly(vinyl chloride) will display a greater tensile modulus. Linear polymers are more likely to crystallize that branched ones. In addition, polymers having isotactic structures will normally have a higher degree of crystallinity that those having atactic structures. Increasing a polymer's crystallinity leads to an increase in its tensile modulus. In addition, tensile modulus is independent of molecular weight - the atactic/branched material has the higher molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸模量进行比较，并详细解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对两种聚合物的拉伸模量进行比较，并解释原因。这涉及到对聚合物结构（线性和支化、等规和无规）与性能（拉伸模量）之间关系的理解，以及结晶度对性能的影响。虽然不需要复杂的计算，但需要综合分析多个因素（分子结构、结晶度、分子量）对性能的影响，属于中等应用层次。 | 难度: 在简答题中属于多角度分析论述难度，需要综合比较两种聚合物的结构特征（支化/线性、无规/等规）、分子量差异以及这些因素对结晶度和拉伸模量的影响。解题步骤涉及多个概念关联和综合分析，包括结晶度与拉伸模量的关系、分子量对拉伸模量的影响等，需要较深入的材料科学知识。" + }, + { + "idx": 4790, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Random styrene-butadiene copolymer with 5% of possible sites crosslinked; block styrene-butadiene copolymer with 10% of possible sites crosslinked", + "answer": "Yes, it is possible. The block styrene-butadiene copolymer with 10% of possible sites crosslinked will have the higher modulus. Block copolymers normally have higher degrees of crystallinity than random copolymers of the same material. A higher degree of crystallinity favors larger moduli. In addition, the block copolymer also has a higher degree of crosslinking; increasing the amount of crosslinking also enhances the tensile modulus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸模量进行比较，并详细解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的拉伸模量，并解释原因。这需要理解聚合物结构（随机共聚物与嵌段共聚物）、交联度对性能的影响，以及结晶度与模量的关系。虽然不涉及复杂计算，但需要综合分析多个因素，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要学生进行多角度分析论述。具体来说，题目要求比较两种聚合物的拉伸模量，不仅需要考虑交联度的影响，还需要考虑共聚物类型（随机与嵌段）对结晶度的影响。这要求学生能够综合运用材料科学中的多个概念（如结晶度、交联度、共聚物结构等）进行关联分析，并给出合理的解释。虽然不需要进行深度关联性分析（如涉及更复杂的材料性能或微观结构），但解题步骤和概念关联的复杂度已经超出了基础水平，属于该题型中较高难度的题目。" + }, + { + "idx": 4791, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Branched polyethylene with a number-average molecular weight of 100,000 g/mol; atactic polypropylene with a number-average molecular weight of 150,000 g/mol", + "answer": "No, it is not possible. Branched polyethylene will tend to have a low degree of crystallinity since branched polymers don't normally crystallize. The atactic polypropylene probably also has a relatively low degree of crystallinity; atactic structures also don't tend to crystallize, and polypropylene has a more complex repeat unit structure than does polyethylene.Tensile modulus increases with degree of crystallinity, and it is not possible to determine which polymer is more crystalline. Furthermore, tensile modulus is independent of molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸模量进行比较，并详细解释原因或说明无法比较的理由。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求考生综合运用聚合物结构（支化聚乙烯和无规聚丙烯）、分子量、结晶度对拉伸模量的影响等知识进行分析和比较。虽然不涉及复杂计算，但需要考生理解多个概念之间的关联，并进行合理的推理和解释。这超出了简单记忆或直接应用的层次，属于中等难度的应用和分析。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求考生不仅需要理解两种聚合物的结构特性（支化聚乙烯和无规聚丙烯），还需要分析结晶度对拉伸模量的影响，并进一步说明分子量在此情境下的无关性。这需要考生综合运用多个高分子材料科学的概念，并进行逻辑清晰的论述。虽然不涉及复杂的计算，但要求考生能够关联多个知识点并做出准确的判断和解释，因此在简答题中属于较高难度。" + }, + { + "idx": 4792, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Linear and isotactic poly(vinyl chloride) with a weight-average molecular weight of 100,000 g/mol; branched and atactic poly(vinyl chloride) having a weight-average molecular weight of 75,000 g/mol", + "answer": "Yes, it is possible. The linear and isotactic material will have the higher tensile strength. Both linearity and isotacticity favor a higher degree of crystallinity than do branching and atacticity; and tensile strength increases with increasing degree of crystallinity. Furthermore, the molecular weight of the linear/isotactic material is higher (100,000 g/mol versus 75,000 g/mol), and tensile strength increases with increasing molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求考生综合运用多个知识点（分子量、线性/支化结构、等规度/无规度对结晶度的影响，以及结晶度对拉伸强度的作用）进行比较和分析。虽然每个知识点本身属于基础概念，但需要将这些概念关联起来进行多步推理和综合分析，才能得出正确的结论。这超出了简单记忆或直接套用的范畴，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于多角度分析论述难度等级。题目要求考生不仅需要比较两种聚合物的分子结构（线性/支化、等规/无规）对结晶度的影响，还需要考虑分子量差异对拉伸强度的综合影响。解题过程涉及多个高分子物理概念的关联分析（结晶度与力学性能的关系、分子量效应等），并要求考生整合这些因素进行综合判断。虽然不需要进行复杂计算，但需要系统性的论述能力，符合等级4\"多角度分析论述\"的特征。" + }, + { + "idx": 4793, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Graft acrylonitrile-butadiene copolymer with 10% of possible sites crosslinked; alternating acrylonitrile-butadiene copolymer with 5% of possible sites crosslinked", + "answer": "No, it is not possible. Alternating copolymers tend to be more crystalline than graft copolymers, and tensile strength increases with degree of crystallinity. However, the graft material has a higher degree of crosslinking, and tensile strength increases with the percentage of crosslinks.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的拉伸强度，涉及结晶度和交联度对拉伸强度的影响，需要综合分析两种因素的作用。虽然不涉及复杂计算，但需要对聚合物结构和性能的关系有较深入的理解，并进行多因素的综合判断。 | 难度: 在简答题题型中，该题目要求对两种聚合物的拉伸强度进行多角度分析，涉及结晶度和交联度两个关键因素的权衡比较。需要同时理解并关联结晶度与交联度对拉伸强度的不同影响机制，且需要说明为何无法做出明确判断的原因。这超出了简单概念复述或单因素分析的要求，属于需要综合运用多个概念进行论述的中高难度题目。" + }, + { + "idx": 4795, + "question": "What is the magnitude of the maximum stress that exists at the tip of an internal crack having a radius of curvature of 1.9 × 10^{-4} mm\\left(7.5 × 10^{-6} in.\\right) and a crack length of 3.8 × 10^{-2} mm\\left(1.5 × 10^{-3}\\right. in.) when a tensile stress of 140 MPa(20,000 psi) is applied?", + "answer": "the magnitude of the maximum stress is 2800 \\text{ mpa} (400,000 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算在特定条件下裂纹尖端的最大应力值，需要使用相关公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（应力集中公式）进行简单计算，属于直接套用公式的范畴，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用最大应力公式（σ_m = 2σ_0√(a/ρ)）进行直接计算，无需多个公式组合或复杂推导。计算步骤简单，仅涉及基本代数运算和单位转换，属于该题型内最基础的难度水平。" + }, + { + "idx": 4796, + "question": "Estimate the theoretical fracture strength of a brittle material if it is known that fracture occurs by the propagation of an elliptically shaped surface crack of length 0.5 mm(0.02 in.) and a tip radius of curvature of 5 × 10^{-3} mm\\left(2 × 10^{-4} in\\right), when a stress of 1035 MPa(150,000 psi) is applied.", + "answer": "the theoretical fracture strength of the material is 20.7 gpa (3 × 10^{6} psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计材料的理论断裂强度，答案是一个具体的数值结果，解答过程需要应用相关公式进行计算。 | 知识层次: 题目需要应用断裂力学中的理论强度公式，涉及多步计算和概念关联，如裂纹长度、应力集中和材料强度的综合分析。虽然不涉及复杂的推理或创新设计，但需要理解和应用相关公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及应力集中系数和裂纹几何参数的关联分析，但不需要处理复杂多变量情况。" + }, + { + "idx": 4797, + "question": "A specimen of a 4340 steel alloy with a plane strain fracture toughness of 54.8 MPa \\sqrt{m} (50 ksi \\sqrt{m}.) is exposed to a stress of 1030 MPa(150,000 psi). Will this specimen experience fracture if the largest surface crack is 0.5mm ( 0.02 in.) long? Why or why not? Assume that the parameter Y has a value of 1.0 .", + "answer": "the specimen will not experience fracture because it can tolerate a critical stress of 1380 \\text{ mpa} before fracture, which is greater than the applied stress of 1030 \\text{ mpa}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（使用断裂韧性公式计算临界应力），并将计算结果与给定应力进行比较来判断是否会发生断裂。答案中包含了具体的计算过程和数值结果。 | 知识层次: 题目需要应用断裂力学中的临界应力公式进行计算，涉及多步推导和数值计算，同时需要理解平面应变断裂韧性和临界应力之间的关系，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算（临界应力计算、比较实际应力与临界应力），并理解材料断裂韧性与裂纹长度的关系。虽然计算过程明确，但涉及概念关联和综合分析，属于中等偏上难度。" + }, + { + "idx": 4798, + "question": "An aircraft component is fabricated from an aluminum alloy that has a plane strain fracture toughness of 40 MPa sqrt(m) (36.4 ksi sqrt(in)). It has been determined that fracture results at a stress of 300 MPa (43,500 psi) when the maximum (or critical) internal crack length is 4.0mm (0.16 in.). For this same component and alloy, will fracture occur at a stress level of 260 MPa (38,000 psi) when the maximum internal crack length is 6.0mm (0.24 in.)? Why or why not?", + "answer": "fracture will occur since the value 42.4 MPa sqrt(m) is greater than the fracture toughness K_IC of the material, 40 MPa sqrt(m).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在给定应力水平和裂纹长度下是否会发生断裂。答案基于计算结果，并解释了为什么断裂会发生。 | 知识层次: 题目需要应用断裂力学中的临界应力强度因子公式进行计算，涉及多步推导和综合分析。虽然计算本身不复杂，但需要理解公式中各参数的含义及其相互关系，并能够将计算结果与材料的断裂韧性进行比较来判断是否会发生断裂。这超出了简单套用公式的层次，属于中等应用范畴。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，并综合分析临界应力强度因子与材料断裂韧性的关系。题目涉及多个变量转换和单位统一，但计算过程相对直接，属于中等应用层次。" + }, + { + "idx": 4800, + "question": "A structural component is fabricated from an alloy that has a plane-strain fracture toughness of 62 MPa \\sqrt{m}. It has been determined that this component fails at a stress of 250 MPa when the maximum length of a surface crack is 1.6 mm. What is the maximum allowable surface crack length (in mm ) without fracture for this same component exposed to a stress of 250 MPa and made from another alloy that has a plane strain fracture toughness of 51 MPa \\sqrt{m} ?", + "answer": "the maximum allowable surface crack length without fracture is 1.08 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定最大允许的表面裂纹长度。答案是一个具体的数值结果（1.08 mm），这需要通过计算得出。 | 知识层次: 题目需要进行多步计算，涉及平面应变断裂韧性和应力强度因子的概念关联，需要综合分析不同合金的性能差异对允许裂纹长度的影响。虽然计算过程相对直接，但需要理解并应用断裂力学的基本公式，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式进行多步计算，涉及不同材料的断裂韧性参数转换和临界裂纹长度的求解。虽然计算过程相对直接，但需要对相关概念有清晰理解并正确应用公式，属于中等偏上的难度。" + }, + { + "idx": 4801, + "question": "A large plate is fabricated from a steel alloy that has a plane strain fracture toughness of 82.4 MPa \\sqrt{m}(75.0 ksi \\sqrt{m}.). If the plate is exposed to a tensile stress of 345 MPa(50,000 psi) during service use, determine the minimum length of a surface crack that will lead to fracture. Assume a value of 1.0 for Y.", + "answer": "the minimum length of a surface crack that will lead to fracture is 0.0182 \\text{ m} (18.2 mm).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用平面应变断裂韧性公式）来确定表面裂纹的最小长度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用平面应变断裂韧性公式进行多步计算，涉及参数转换和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要应用平面应变断裂韧性公式进行多步计算，涉及应力强度因子、临界裂纹长度等概念的关联分析，但计算过程相对直接，没有涉及复杂多变量或高阶数学运算。" + }, + { + "idx": 4806, + "question": "What is the maximum carbon content possible for a plain carbon steel that must have an impact energy of at least 200 Jat -50^{\\circ} C ?", + "answer": "the maximum carbon concentration is 0.11% C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定一个具体的数值（最大碳含量），并需要基于材料科学知识进行解释和论述，答案以文字形式给出具体数值（0.11% C），而非通过计算或选择得出。 | 知识层次: 题目需要理解碳钢的碳含量与冲击韧性之间的关系，并能够根据给定的冲击能量要求确定最大碳含量。这涉及多步计算和概念关联，需要综合分析材料性能与成分的关系，但不需要复杂的机理分析或创新设计。 | 难度: 在简答题中属于中等难度，需要理解碳钢的碳含量与冲击韧性的关系，并进行多步计算和综合分析。题目要求考生将材料性能与具体应用条件（低温冲击韧性）联系起来，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4807, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for tin.", + "answer": "for sn, -71°c or -96°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对特定材料（锡）的蠕变温度这一基础概念的记忆，不需要复杂的分析或计算，仅需直接回忆相关知识。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回忆特定材料（锡）的蠕变起始温度这一单一数据点，不需要进行概念解释或复杂体系阐述。符合等级1\"基本定义简答\"的特征，属于该题型内最基础的难度层级。" + }, + { + "idx": 4808, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for molybdenum.", + "answer": "for mo, 776°c or 1429°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答形式。 | 知识层次: 题目考查对钼材料蠕变变形温度这一特定数值的记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，此题属于基本定义简答难度。题目仅要求回忆并给出钼材料蠕变变形开始显著的温度数值（776°C或1429°F），不涉及概念解释或复杂体系阐述。该知识点属于基础概念记忆层次，无需推导或分析过程，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 4810, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for gold.", + "answer": "for au, 262°c or 504°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答形式。 | 知识层次: 题目考查对金属蠕变温度这一基本概念的记忆，属于单一知识点的直接回忆，不需要复杂的分析或应用过程。 | 难度: 在简答题中属于基本定义简答难度，仅需记忆特定材料的临界温度数值，无需解释概念或阐述复杂体系。题目仅考察对黄金蠕变温度这一单一数据点的记忆，属于最基础的知识点掌握要求。" + }, + { + "idx": 4811, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for zinc.", + "answer": "for zn, 4°c or 39°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对锌的蠕变变形温度这一基本概念的记忆，不需要复杂的分析或应用。 | 难度: 在简答题题型中，该题目属于基础概念记忆层次，仅需要回忆锌的蠕变温度这一具体数值，不需要进行概念解释或复杂体系阐述。题目要求的知识点非常具体且单一，属于该题型内最简单的等级。" + }, + { + "idx": 4812, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for chromium.", + "answer": "for cr, 586°c or 1087°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要从多个选项中选择，也不涉及判断对错或复杂的计算过程，属于需要简短回答的问题。 | 知识层次: 题目考查对铬材料蠕变变形温度的基本概念记忆，不需要复杂的分析或应用，只需记住特定材料的温度点即可。 | 难度: 在简答题中属于基础难度，仅需记忆特定材料的临界温度数值，无需解释概念或进行复杂论述。题目仅考察对铬的蠕变温度这一单一知识点的记忆，符合基础概念记忆层次的要求。" + }, + { + "idx": 4813, + "question": "A cylindrical specimen 13.2mm in diameter of an S-590 alloy is to be exposed to a tensile load of 27,000N. At approximately what temperature will the steady-state creep be 10^{-3} h^{-1} ?", + "answer": "the temperature would be approximately 775^\\circ c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定温度，答案是一个具体的数值结果（775°C），这表明需要进行计算和推导。 | 知识层次: 题目需要进行多步计算，包括应用蠕变速率公式和材料性能数据，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在计算题中属于综合性计算问题难度。题目需要应用材料科学中的蠕变公式，涉及多步计算和概念关联（如应力计算、蠕变速率与温度关系等），但尚未达到复杂多变量计算的程度。解题过程需要先计算工程应力，再结合合金的蠕变特性曲线或公式确定对应温度，属于典型的中等应用层次计算题。" + }, + { + "idx": 4814, + "question": "Steady-state creep rate data are given in the following table for a nickel alloy at 538^{\\circ} C \\\\ (811 K):\n\\begin{tabular}{lc}\n\\hline \\dot{\\varepsilon}_{s}\\left(h^{-1}\\right) & \\sigma(M P(a) \\\\\n\\hline 10^{-7} & 22.0 \\\\\n10^{-6} & 36.1 \\\\\n\\hline\n\\end{tabular}\nCompute the stress at which the steady-state creep is 10^{-5}h^{-1} (also at 538^{\\circ} C ).", + "answer": "the stress at which the steady-state creep is 10^{-5}h^{-1} is 59.4 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目提供了数据表格，要求通过计算得出特定条件下的应力值。解答过程需要应用公式和数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用稳态蠕变速率的公式，通过给定的数据点进行多步计算（如对数转换、线性回归等）来求解未知应力值，涉及概念关联和综合分析，但不需要复杂的机理分析或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解稳态蠕变速率与应力之间的关系，并应用相关公式进行多步计算。题目提供了基础数据，要求考生通过分析数据关系推导出未知应力值，涉及概念关联和综合分析能力，但计算步骤相对明确，没有涉及复杂多变量或高级数学工具。" + }, + { + "idx": 4815, + "question": "Steady-state creep rate data are given in the following table for some alloy taken at 200^{\\circ} C(473 K) :\n\\begin{tabular}{ll}\n\\hlines\\left(h^{-1}\\right) & \\sigma[MPa(psi)] \\\\\n\\hline 2.5 × 10^{-3} & 55(8000) \\\\\n2.4 × 10^{-2} & 69(10,000) \\\\\n\\hline\n\\end{tabular}\nIf it is known that the activation energy for creep is 140,000 J/ mol, compute the steady-state creep rate at a temperature of 250^{\\circ} C(523 K) and a stress level of 48 MPa(7000 psi).", + "answer": "the steady-state creep rate at 250^{\\circ} C and 48 MPa is 1.94 × 10^{-2} h^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（涉及激活能和温度变化）计算稳态蠕变速率，答案是一个具体的数值结果，解答过程需要数值计算和公式应用。 | 知识层次: 题目需要应用稳态蠕变速率的公式，涉及多步计算和温度、应力的综合分析，同时需要理解激活能的概念并将其应用于不同条件下的计算。虽然不涉及复杂的机理分析或创新设计，但超出了简单套用公式的范畴，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用稳态蠕变速率公式，涉及多步骤计算和概念关联。题目要求根据给定的数据计算不同温度和应力条件下的蠕变速率，需要理解蠕变速率与应力和温度的关系，并正确应用阿伦尼乌斯方程。虽然计算步骤较多，但题目提供了必要的参数和公式框架，属于中等应用层次的计算题。" + }, + { + "idx": 4816, + "question": "Steady-state creep data taken for an iron at a stress level of 140 MPa(20,000 psi) are given here:\n\\begin{tabular}{cc}\n\\hline\\dot{\\epsilon}_{s}\\left(h^{-1}\\right) & T(K) \\\\\n\\hline 6.6 × 10^{-4} & 1090 \\\\\n8.8 × 10^{-2} & 1200 \\\\\n\\hline\n\\end{tabular}\nIf it is known that the value of the stress exponent n for this alloy is 8.5 , compute the steady-state creep rate at 1300 K and a stress level of 83 MPa(12,000 psi).", + "answer": "the steady-state creep rate at 1300k and a stress level of 83 MPa is 4.31 × 10^{-2}h^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（应力指数n）计算稳态蠕变速率，答案是一个具体的数值结果，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用稳态蠕变速率公式，进行多步计算，包括温度转换和应力指数的应用，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要应用稳态蠕变公式，涉及多步计算和概念关联。题目提供了初始数据并要求在不同应力水平下计算蠕变速率，需要理解应力指数和温度对蠕变速率的影响，并进行相应的数值计算。虽然计算步骤较多，但题目提供了必要的参数和明确的求解路径，因此属于中等难度。" + }, + { + "idx": 4817, + "question": "If ice homogeneously nucleates at -40^{\\circ} C, calculate the critical radius given values of - 3.1 × 10^{8} J/ m^{3} and 25 × 10^{-3} J/ m^{2}, respectively, for the latent heat of fusion and the surface free energy.", + "answer": "the critical radius is 1.10 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数值（如潜热和表面自由能）应用公式计算临界半径，最终答案为数值结果（1.10 nm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及临界半径的计算公式应用，需要理解并关联表面自由能和潜热的概念，但不需要复杂的推理或综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用临界半径公式，涉及多步计算和概念关联，但变量和计算过程相对明确，没有过于复杂的多变量处理。" + }, + { + "idx": 4818, + "question": "It is known that the kinetics of recrystallization for some alloy obeys the Avrami equation, and that the value of n in the exponential is 5.0. If, at some temperature, the fraction recrystallized is 0.30 after 100 min, determine the rate of recrystallization at this temperature.", + "answer": "the rate of recrystallization at this temperature is 8.76 × 10^{-3}, \\text{min}^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Avrami方程）来确定再结晶速率，答案是一个具体的数值结果（8.76 × 10^{-3}, \\text{min}^{-1}），符合计算题的特征。 | 知识层次: 题目需要应用Avrami方程进行多步计算，涉及对公式的理解和数值计算，同时需要将给定的条件（如n值和分数再结晶）代入方程求解。这要求一定的综合分析能力和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用Avrami方程进行多步计算，涉及对数运算和指数函数的转换，同时要求对动力学概念有较好的理解。虽然计算步骤明确，但需要综合运用多个知识点，属于中等偏上的难度。" + }, + { + "idx": 4820, + "question": "The fraction recrystallized-time data for the recrystallization at 350^{\\circ} C of a previously deformed aluminum are tabulated here. Assuming that the kinetics of this process obey the Avrami relationship, determine the fraction recrystallized after a total time of 116.8min.\n\\begin{tabular}{cc}\n\\hline Fraction Recrystallized & Time (min) \\\\\n\\hline 0.30 & 95.2 \\\\\n0.80 & 126.6 \\\\\n\\hline\n\\end{tabular}", + "answer": "the fraction recrystallized after a total time of 116.8min is 0.65.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和Avrami关系进行数值计算，以确定在特定时间下的再结晶分数。解答过程涉及公式应用和数值计算，最终给出一个具体的数值结果。 | 知识层次: 题目需要应用Avrami关系进行多步计算，包括确定动力学参数和计算特定时间下的再结晶分数，涉及公式应用和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要应用Avrami关系式进行多步计算，包括数据拟合和插值求解。虽然计算步骤相对明确，但需要对动力学模型有较好的理解，并能正确关联给定的数据点进行综合分析。相比简单的单步计算题（等级2），此题涉及更复杂的公式应用和数据处理，但尚未达到多变量或高度复杂的计算（等级4）。" + }, + { + "idx": 4823, + "question": "What is the principal difference between natural and artificial aging processes?", + "answer": "For precipitation hardening, natural aging is allowing the precipitation process to occur at the ambient temperature; artificial aging is carried out at an elevated temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释自然时效和人工时效过程的主要区别，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查自然时效和人工时效的基本定义和区别，属于基础概念的记忆和理解。 | 难度: 在简答题题型中，该题目要求解释自然时效和人工时效的主要区别，属于概念解释和描述的难度等级。虽然需要记忆和理解两种时效过程的基本定义和操作条件，但并不涉及复杂的概念体系或深入的原理分析。题目主要考察对基础概念的掌握和简单对比能力，符合等级2的标准。" + }, + { + "idx": 4824, + "question": "Which of the following polymers would be suitable for the fabrication of cups to contain hot coffee: polyethylene, polypropylene, poly(vinyl chloride), PET polyester, and polycarbonate. Why?", + "answer": "This question asks us to name, which, of five polymers, would be suitable for the fabrication of cups to contain hot coffee. At its glass transition temperature, an amorphous polymer begins to soften. The maximum temperature of hot coffee is probably slightly below 100^{\\circ} C\\left(212^{\\circ} F\\right). Of the polymers listed, only polystyrene and polycarbonate have glass transition temperatures of 100^{\\circ} C or above, and would be suitable for this application.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个聚合物中选择合适的材料，并解释原因。答案提供了详细的解释和论述，说明为什么某些聚合物适合而其他不适合，这符合简答题的特征，需要文字解释和论述。 | 知识层次: 题目要求考生理解聚合物的玻璃化转变温度及其在实际应用中的意义，需要综合分析不同聚合物的性能参数（玻璃化转变温度）与具体应用场景（盛放热咖啡）的匹配性。虽然涉及基础概念，但更侧重于应用这些概念进行判断和选择，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要综合分析和多角度论述。题目要求评估五种聚合物在特定应用中的适用性，涉及玻璃化转变温度的概念理解、实际应用温度范围的判断，以及不同聚合物性能的比较分析。解题步骤包括：1) 理解题目要求；2) 回忆相关聚合物的玻璃化转变温度；3) 分析热咖啡的温度范围；4) 比较各聚合物的性能与需求匹配度；5) 综合论述选择理由。这种多步骤的概念关联和综合分析在简答题中属于较复杂的任务。" + }, + { + "idx": 4825, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Branched polyethylene having a number-average molecular weight of 850,000 g/mol; linear polyethylene having a number-average molecular weight of 850,000 g/mol", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. The linear polyethylene will most likely have a higher percent crystallinity, and, therefore, a higher melting temperature than the branched polyethylene. The molecular weights of both materials are the same and, thus, molecular weight is not a consideration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并给出详细的解释和理由，需要文字论述而非简单的选择或判断。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求比较两种聚乙烯的熔点，并解释原因。这需要理解分子结构（线性和支化）对结晶度和熔点的影响，以及分子量相同条件下的比较。虽然涉及基础概念，但需要综合分析结构-性能关系，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及多个概念（分子量、支化结构、结晶度和熔点）的综合分析，但解题步骤相对明确：首先判断可能性，然后比较结构差异对性能的影响。不需要进行多角度或深度关联性分析（等级4-5的要求），主要考察对聚乙烯结构与性能关系的理解和应用能力。" + }, + { + "idx": 4826, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Polytetrafluoroethylene having a density of 2.14 g/cm3 and a weight-average molecular weight of 600,000 g/mol; PTFE having a density of 2.20 g/cm3 and a weight-average molecular weight of 600,000 g/mol", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. Of these two polytetrafluoroethylene polymers, the PTFE with the higher density (2.20 g/cm3) will have the higher percent crystallinity, and, therefore, a higher melting temperature than the lower density PTFE. The molecular weights of both materials are the same and, thus, molecular weight is not a consideration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。题目没有提供选项，也没有要求计算，而是要求详细说明理由。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这需要理解密度与结晶度之间的关系，以及结晶度对熔点的影响。虽然涉及基础概念，但需要综合分析多个因素（密度、分子量、结晶度）来得出结论，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解聚合物密度与结晶度的关系，并能够综合分析分子量相同的情况下密度对熔点的影响。虽然涉及多个概念，但解题步骤相对直接，不需要过于复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 4827, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Linear and syndiotactic poly(vinyl chloride) having a number-average molecular weight of 500,000 g/mol; linear polyethylene having a number-average molecular weight of 225,000 g/mol", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. The linear polyethylene will have the greater melting temperature inasmuch as it will have a higher degree of crystallinity; polymers having a syndiotactic structure do not crystallize as easily as those polymers having identical single-atom side groups. With regard to molecular weight, or rather, degree of polymerization, it is about the same for both materials (8000), and therefore, is not a consideration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并给出详细的解释和理由。答案需要文字论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这涉及到对聚合物结构（线性聚乙烯与间规聚氯乙烯）、结晶度以及分子量影响的理解和应用。虽然不需要复杂的计算，但需要综合分析多个因素（如结晶度和分子量）来得出结论。因此属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对两种聚合物的熔点进行比较，涉及多个因素的综合分析，包括分子结构（线性与间规立构）、分子量、结晶度等。解题步骤较为复杂，需要理解并关联多个高分子物理概念，如结晶度对熔点的影响、分子结构对结晶能力的影响等。此外，还需要对分子量的影响进行判断，并最终综合这些因素得出结论。这种多角度分析和论述的要求使得该题目在同题型中属于较高难度。" + }, + { + "idx": 4828, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Linear and syndiotactic polypropylene having a weight-average molecular weight of 500,000 g/mol; linear and atactic polypropylene having a weight-average molecular weight of 750,000 g/mol", + "answer": "No, it is not possible to determine which of the two polymers has the higher melting temperature. The syndiotactic polypropylene will have a higher degree of crystallinity than the atactic material. On the basis of this effect alone, the syndiotactic PP should have the greater Tm, since melting temperature increases with degree of crystallinity. However, the molecular weight for the syndiotactic polypropylene (500,000 g/mol) is less than for the atactic material (750,000 g/mol); a lowering of molecular weight generally results in a reduction of melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，涉及对两种聚合物熔点的比较和原因分析，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同聚合物（线性间规聚丙烯和无规聚丙烯）的熔点进行比较，需要考虑多个因素（分子量、结晶度）的综合影响，并进行推理分析。这涉及到对聚合物结构与性能关系的深入理解，以及在不同影响因素之间进行权衡和判断，属于复杂分析的层次。 | 难度: 在简答题-复杂分析题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4829, + "question": "Compute the electrical conductivity of a cylindrical silicon specimen 7.0mm (0.28 in.) diameter and 57mm (2.25 in.) in length in which a current of 0.25 A passes in an axial direction. A voltage of 24V is measured across two probes that are separated by 45mm (1.75 in.).", + "answer": "12.2 (omega·m)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解硅圆柱体的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及电阻率与电导率的转换，以及欧姆定律的直接应用，不需要多步计算或复杂的概念关联。 | 难度: 在计算题中属于简单公式应用计算，需要应用电导率的基本公式（σ = (I * L) / (V * A)），并进行简单的单位转换和数值计算。虽然涉及多个步骤（计算截面积、应用公式等），但所有步骤都是直接且基础的，不需要复杂的推导或组合多个公式。因此，在同题型内属于等级2难度。" + }, + { + "idx": 4830, + "question": "Compute the resistance over the entire 57mm (2.25 in.) of the specimen.", + "answer": "the resistance over the entire specimen length is 121.4 omega.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算整个试样的电阻值，答案给出了具体的数值计算结果（121.4 omega），这表明需要通过数值计算和公式应用来解答问题。 | 知识层次: 题目要求进行基本的电阻计算，仅涉及单一公式的直接应用和简单数值计算，不需要多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算，仅需应用基本电阻公式进行简单计算，无需组合多个公式或进行复杂步骤。" + }, + { + "idx": 4831, + "question": "What is the distinction between electronic and ionic conduction? \\\\", + "answer": "When a current arises from a flow of electrons, the conduction is termed electronic; for \\\\ ionic conduction, the current results from the net motion of charged ions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释电子传导和离子传导的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查电子传导和离子传导的基本定义和区分，属于基础概念的记忆和理解范畴 | 难度: 在简答题题型中，该题目仅要求对电子传导和离子传导的基本定义进行区分和简答，属于最基础的概念记忆层面。题目不涉及复杂的概念体系阐述或深入的解释描述，仅需直接回忆并复述两种传导方式的本质区别即可。在同题型框架内，这属于最基础的难度等级。" + }, + { + "idx": 4832, + "question": "In terms of electron energy band structure, discuss reasons for the difference in electrical \\\\ conductivity among metals, semiconductors, and insulators.", + "answer": "For metallic materials, there are vacant electron energy states adjacent to the highest filled state; thus, very little energy is required to excite large numbers of electrons into conducting states. These electrons are those that participate in the conduction process, and, because there are so many of them, metals are good electrical conductors.\nThere are no empty electron states adjacent to and above filled states for semiconductors and insulators, but rather, an energy band gap across which electrons must be excited in order to participate in the conduction process. Thermal excitation of electrons occurs, and the number of electrons excited will be less than for metals, and will depend on the band gap energy. For semiconductors, the band gap is narrower than for insulators; consequently, at a specific temperature more electrons will be excited for semiconductors, giving rise to higher conductivities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论金属、半导体和绝缘体在电子能带结构方面的导电性差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从电子能带结构的角度分析金属、半导体和绝缘体导电性差异的原因，涉及对不同材料能带结构的深入理解、电子激发过程的解释以及导电性能的综合比较。这需要综合运用能带理论、电子激发机制等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对金属、半导体和绝缘体的电子能带结构进行深入比较，并解释导电性差异的机理。需要综合运用能带理论、热激发原理和导电机制等知识，进行多层次的推理分析。题目不仅要求掌握基础概念，还需要将这些概念有机整合，解释复杂现象背后的物理本质。这种全面分析和深度解释的要求，在同类题型中属于最高难度等级。" + }, + { + "idx": 4833, + "question": "How does the electron structure of an isolated atom differ from that of a solid material?", + "answer": "For an isolated atom, there exist discrete electron energy states (arranged into shells and subshells); each state may be occupied by, at most, two electrons, which must have opposite spins. On the other hand, an electron band structure is found for solid materials; within each band exist closely spaced yet discrete electron states, each of which may be occupied by, at most, two electrons, having opposite spins. The number of electron states in each band will equal the total number of corresponding states contributed by all of the atoms in the solid.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释孤立原子和固体材料中电子结构的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对比孤立原子和固体材料中的电子结构差异，涉及电子能级和能带结构的解释，需要深入理解量子力学原理和固体物理知识，并进行综合分析。这超出了简单记忆或基本应用的范围，属于对复杂概念的推理分析和机理解释。 | 难度: 在简答题-复杂分析题型中，该题目要求对孤立原子和固体材料的电子结构进行机理深度解释。需要综合运用量子力学和固体物理知识，比较两种状态下电子能级分布的差异，并解释能带形成原理。虽然不涉及多系统交互分析（等级5特征），但需要清晰的物理概念和逻辑推导能力，属于该题型内较高难度的机理解释类题目。" + }, + { + "idx": 4834, + "question": "Briefly state what is meant by the drift velocity of a free electron.", + "answer": "The drift velocity of a free electron is the average electron velocity in the direction of the force imposed by an electric field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释自由电子的漂移速度的含义，答案是一段文字解释，符合简答题的特征。 | 知识层次: 题目考查对自由电子漂移速度这一基本概念的定义和简单理解，属于基础概念记忆层次。 | 难度: 在简答题题型中，该题目仅要求对\"自由电子的漂移速度\"这一基本概念进行简单定义回答，属于最基础的定义简答级别。题目不涉及概念解释、描述或复杂体系阐述，仅需记忆性知识即可完成，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4835, + "question": "Briefly state what is meant by the mobility of a free electron.", + "answer": "The mobility is the proportionality constant between the drift velocity and the electric field. It is also a measure of the frequency of scattering events (and is inversely proportional to the frequency of scattering).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释自由电子迁移率的概念，答案以文字解释和论述的形式给出，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查自由电子迁移率的基本定义和物理意义，属于基础概念的记忆和理解层面，不涉及复杂计算或综合分析。 | 难度: 在简答题题型中，该题目要求对\"自由电子迁移率\"这一概念进行解释和描述，不仅需要给出定义（比例常数），还需要说明其物理意义（散射频率的度量）。这超出了单纯记忆定义的等级1要求，但尚未达到需要阐述复杂概念体系的等级3水平。题目在基础概念记忆层次中属于中等难度，符合等级2\"概念解释和描述\"的标准。" + }, + { + "idx": 4836, + "question": "(a) Calculate the drift velocity of electrons in silicon at room temperature and when the magnitude of the electric field is 500 V/m.", + "answer": "the drift velocity of electrons in silicon at room temperature and when the magnitude of the electric field is 500 V/m is 72.5 m/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算电子的漂移速度），并给出了具体的电场强度条件。答案是一个具体的数值结果（72.5 m/s），这表明需要通过公式应用和计算来解答。 | 知识层次: 题目要求计算硅中电子在室温下的漂移速度，涉及基本公式（漂移速度=迁移率×电场强度）的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用漂移速度公式v_d = μE（其中μ为电子迁移率，E为电场强度），并代入已知数值进行计算。题目明确给出了所有必要参数，无需额外推导或组合多个公式。" + }, + { + "idx": 4837, + "question": "(b) Under these circumstances, how long does it take an electron to traverse a 25-mm length of crystal?", + "answer": "under these circumstances, it takes an electron 3.45 x 10^-4 s to traverse a 25-mm length of crystal.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算电子通过25毫米晶体长度所需的时间，答案给出了具体的数值计算结果（3.45 x 10^-4 s），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需直接套用已知条件进行数值计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的速度或时间公式（如时间=距离/速度），且计算过程简单直接，无需多个公式组合或复杂步骤。" + }, + { + "idx": 4838, + "question": "At room temperature the electrical conductivity and the electron mobility for aluminum are 3.8 x 10^7 (Ω·m)^-1 and 0.0012 m^2/V·s, respectively. Compute the number of free electrons per cubic meter for aluminum at room temperature.", + "answer": "the number of free electrons per cubic meter for aluminum at room temperature is 1.98 x 10^29 m^-3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率和电子迁移率数据，应用相关公式计算铝在室温下的自由电子密度。答案是一个具体的数值结果，需要通过计算得出。 | 知识层次: 题目要求应用基本的电导率和电子迁移率公式进行计算，属于直接套用公式的简单应用。虽然需要理解相关概念，但计算过程较为直接，不涉及多步推理或综合分析。 | 难度: 在计算题中属于最低难度，只需要直接套用单一公式（电导率与载流子浓度和迁移率的关系公式σ = n·e·μ）进行简单数值计算，无需任何复杂步骤或公式组合。" + }, + { + "idx": 4839, + "question": "At room temperature the electrical conductivity and the electron mobility for aluminum are 3.8 x 10^7 (Ω·m)^-1 and 0.0012 m^2/V·s, respectively. What is the number of free electrons per aluminum atom? Assume a density of 2.7 g/cm^3.", + "answer": "the number of free electrons per aluminum atom is 3.28 electrons/al atom.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解每铝原子的自由电子数，答案是一个具体的数值结果，解答过程涉及电导率、电子迁移率和密度的计算。 | 知识层次: 题目需要进行多步计算，包括电导率公式的应用、电子浓度的计算、以及将结果转换为每铝原子的自由电子数。这需要理解电导率与电子迁移率的关系，以及将宏观性质与微观结构联系起来。虽然不涉及复杂的推理或创新，但需要综合运用多个概念和公式进行计算。 | 难度: 在计算题中属于综合性计算问题，需要应用电导率、电子迁移率和密度的公式进行多步计算，并理解自由电子与原子数的关系。虽然计算步骤较多，但每一步的计算相对直接，没有涉及复杂多变量的处理。" + }, + { + "idx": 4840, + "question": "At room temperature the electrical conductivity of P b S is 25\\left(\\Omega·m\\right)^{-1}, whereas the electron and hole mobilities are 0.06 and 0.02{m}^{2} / V·s, respectively. Compute the intrinsic carrier concentration for PbS at room temperature.", + "answer": "the intrinsic carrier concentration for pbs at room temperature is 1.95 × 10^{21}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率、电子和空穴迁移率等参数，应用相关公式计算本征载流子浓度。答案是一个具体的数值结果，解答过程涉及数值计算和公式应用。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即通过给定的电导率、电子和空穴迁移率来计算本征载流子浓度。虽然需要理解相关概念，但计算过程直接且步骤简单，属于基本公式的直接套用。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用电导率与载流子浓度及迁移率的基本关系公式σ = n|e|(μ_e + μ_h)，进行简单的代数运算即可得出结果，无需组合多个公式或进行复杂推导。" + }, + { + "idx": 4841, + "question": "An n-type semiconductor is known to have an electron concentration of 5 × 10^{17}{m}^{-3}. If the electron drift velocity is 350{m} / s in an electric field of 1000V / m, calculate the conductivity of this material.", + "answer": "the conductivity of the material is 0.028, (\\omega·m)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解材料的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的半导体电导率计算，仅需直接应用公式σ = n·e·μ（其中μ可通过漂移速度与电场关系求得），属于单一公式的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用电导率的基本公式σ = n·e·μ，其中μ可以通过已知的电子漂移速度和电场强度计算得出（μ = v_d / E）。整个过程仅涉及一个主要公式和简单的数值代入，没有复杂的推导或多步骤计算。" + }, + { + "idx": 4842, + "question": "Predict whether Nitrogen (N) will act as a donor or an acceptor when added to Silicon (Si). Assume that the impurity elements are substitutional.", + "answer": "Nitrogen will act as a donor in Si. Since it (N) is from group VA of the periodic table, and an N atom has one more valence electron than an Si atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，需要分析氮在硅中的行为并给出理由，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对半导体掺杂基本原理的记忆和理解，仅需知道氮和硅在周期表中的位置及其价电子数差异即可回答，无需复杂分析或计算。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要理解氮和硅的电子结构差异，但只需简单比较两者在周期表中的位置和价电子数即可得出结论，不需要复杂的推导或体系阐述。属于基础概念应用层次，解题步骤较为直接。" + }, + { + "idx": 4843, + "question": "Predict whether Boron (B) will act as a donor or an acceptor when added to Germanium (Ge). Assume that the impurity elements are substitutional.", + "answer": "Boron will act as an acceptor in Ge. Since it (B) is from group IIIA of the periodic table, a B atom has one less valence electron than a Ge atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求预测硼在锗中的行为，并解释原因。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对半导体掺杂基本原理的记忆和理解，涉及元素周期表中元素的价电子数及其在半导体中的作用，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并解释硼在锗中的掺杂行为，需要掌握基本的半导体掺杂原理和元素周期表族数的关系。虽然涉及基础概念的记忆，但需要一定的解释和逻辑推理，比单纯的定义简答（等级1）稍复杂，但尚未达到复杂概念体系阐述（等级3）的程度。" + }, + { + "idx": 4844, + "question": "Predict whether Sulfur (S) will act as a donor or an acceptor when added to Indium Antimonide (InSb). Assume that the impurity elements are substitutional.", + "answer": "Sulfur will act as a donor in InSb. Since S is from group VIA of the periodic table, it will substitute for Sb; an S atom has one more valence electron than an Sb atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测硫在锑化铟中的行为，并解释其作为施主或受主的原因。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解半导体掺杂的基本原理，分析硫在InSb中的替代位置及其对电子结构的影响，涉及多步概念关联和综合分析。虽然不涉及复杂计算，但需要对元素周期表分组和半导体掺杂行为有较深入的理解。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要学生理解并应用元素周期表中的位置关系、半导体掺杂原理以及价电子概念。解题步骤包括识别硫和锑的价电子差异、判断硫在InSb中的替代位置，并最终推导出硫的掺杂类型。虽然涉及多个概念的综合分析，但不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" + }, + { + "idx": 4845, + "question": "Predict whether Indium (In) will act as a donor or an acceptor when added to Cadmium Sulfide (CdS). Assume that the impurity elements are substitutional.", + "answer": "Indium will act as a donor in CdS. Since In is from group IIIA of the periodic table, it will substitute for Cd; an In atom has one more valence electron than a Cd atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测并解释铟在硫化镉中的行为，需要基于材料科学原理进行文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解掺杂元素在半导体中的行为，涉及元素周期表族数的比较和电子行为的分析，属于中等应用层次。需要将基础概念（如掺杂、价电子）与实际应用（预测掺杂类型）相结合，进行简单的推理和解释。 | 难度: 在简答题中属于中等难度，需要理解掺杂元素在半导体中的行为，并能够分析元素周期表中的位置与价电子数的关系。虽然题目涉及多步概念关联和综合分析，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 4846, + "question": "Predict whether Arsenic (As) will act as a donor or an acceptor when added to Zinc Telluride (ZnTe). Assume that the impurity elements are substitutional.", + "answer": "Arsenic will act as an acceptor in ZnTe. Since As is from group VA of the periodic table, it will substitute for Te; furthermore, an As atom has one less valence electron than a Te atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来预测砷在碲化锌中的行为，并给出详细的理由说明，符合简答题的特征。 | 知识层次: 题目需要理解掺杂元素在半导体中的行为，涉及元素周期表族群的比较和价电子数的分析，属于中等应用层次。需要将基本概念（如掺杂、价电子）与具体材料（ZnTe）相结合，进行多步推理和综合分析。 | 难度: 在简答题中属于中等难度，需要理解半导体掺杂的基本原理，并能正确分析元素在周期表中的位置及其价电子数差异对掺杂行为的影响。虽然题目涉及多步概念关联（如元素周期表位置、价电子比较、半导体掺杂类型判断），但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 4847, + "question": "Germanium to which 10^24 m^-3 As atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the As atoms may be thought of as being ionized (i.e., one charge carrier exists for each As atom). Is this material n-type or p-type?", + "answer": "this germanium material to which has been added 10^24 m^-3 as atoms is n-type since as is a donor in ge.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么这种掺杂锗材料是n型，需要文字解释和论述，而不是简单的选择或判断。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目考查对半导体类型（n型或p型）的基本概念记忆和理解，只需要识别掺杂元素As是施主杂质即可判断材料类型，无需复杂分析或计算。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求判断掺杂锗材料的类型，需要理解施主掺杂和n型半导体的基本概念，但不需要复杂的推导或多步骤分析。解题过程主要是应用基础概念进行简单判断，属于对单一知识点的解释性回答。" + }, + { + "idx": 4848, + "question": "Germanium to which 10^24 m^-3 As atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the As atoms may be thought of as being ionized (i.e., one charge carrier exists for each As atom). Calculate the electrical conductivity of this material, assuming electron and hole mobilities of 0.1 and 0.05 m^2/V-s, respectively.", + "answer": "the conductivity is equal to 1.60 × 10^4 (ω·m)^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及电导率的计算，需要运用给定的电子和空穴迁移率以及掺杂浓度等参数。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式应用和简单计算，即通过给定的掺杂浓度和载流子迁移率直接套用导电率公式进行计算。虽然涉及半导体物理的基本概念，但解题过程主要是数值代入和简单运算，不需要多步推导或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用电导率的基本公式σ = nqμ，其中n是载流子浓度，q是电子电荷，μ是载流子迁移率。题目已经给出了所有需要的数值，只需要直接代入公式计算即可，无需额外的推导或组合多个公式。" + }, + { + "idx": 4849, + "question": "A metal alloy is known to have electrical conductivity and electron mobility values of 1.2 × 10^{7}(\\Omega·m)^{-1} and 0.0050{m}^{2} / V·s, respectively. A current of 40 \\mathrm{~A} is passed through a specimen of this alloy that is 35mm thick. What magnetic field would need to be imposed to yield a Hall voltage of -3.5 × 10^{-7}V ?", + "answer": "the required magnetic field is 0.735, \\text{tesla}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的磁场强度，答案是一个具体的数值结果（0.735 tesla），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用电导率、电子迁移率、电流密度和霍尔效应等知识，进行公式推导和数值计算，思维过程有一定深度要求。 | 难度: 在计算题中属于综合性计算问题，需要应用霍尔效应的相关公式，进行多步计算，包括电流密度、载流子浓度等中间步骤的推导，最终求解磁场强度。虽然计算步骤较多，但每一步都有明确的物理意义和数学关系，属于中等应用层次的计算题。" + }, + { + "idx": 4850, + "question": "At temperatures between 540^{\\circ} C(813 K) and 727^{\\circ} C(1000 K), the activation energy and preexponential for the diffusion coefficient of \\mathrm{Na}^{+}in \\mathrm{NaCl} are 173,000 J/ mol and 4.0 × 10^{-4} m^{2} / s, respectively. Compute the mobility for an \\mathrm{Na}^{+}ion at 600^{\\circ} C(873 K).", + "answer": "the mobility for a \\mathrm{na}^{+} ion at 600^{\\circ} C (873 k) is 2.34 × 10^{-13} m^{2}/\\mathrm{v}-s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的激活能和前置指数计算钠离子在特定温度下的迁移率，需要使用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求应用扩散系数和活化能的公式进行简单计算，属于基本公式的直接应用，不需要多步计算或复杂分析。 | 难度: 在计算题中属于简单应用难度，需要应用扩散系数与迁移率之间的关系公式进行计算，但仅涉及单一公式的直接套用和简单数值计算，无需多个公式组合或复杂推导。" + }, + { + "idx": 4851, + "question": "A parallel-plate capacitor using a dielectric material having an \\varepsilon_{\\mathrm{r}} of 2.2 has a plate spacing of 2mm ( 0.08 in.). If another material having a dielectric constant of 3.7 is used and the capacitance is to be unchanged, what must be the new spacing between the plates?", + "answer": "the new spacing between the plates must be 3.36 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解新的板间距，答案是一个具体的数值结果（3.36 mm），而不是选择、判断或文字解释。 | 知识层次: 题目涉及基本公式（电容公式）的直接应用和简单计算，不需要多步推理或综合分析，只需根据给定的参数进行数值替换和计算。 | 难度: 在计算题中属于简单应用难度，仅需使用电容公式C=εA/d进行简单变形计算，无需多个公式组合或复杂推导。题目直接给出了新旧介电常数和初始间距，只需一步计算即可得出新间距。" + }, + { + "idx": 4852, + "question": "Consider a parallel-plate capacitor having an area of 3225 mm2 (5 in.2), a plate separation of 1mm (0.04 in.), and a material having a dielectric constant of 3.5 positioned between the plates. What is the capacitance of this capacitor?", + "answer": "the capacitance of this capacitor is 100 pf.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（电容公式）来求解电容值，答案是一个具体的数值结果（100 pf），属于典型的计算题特征。 | 知识层次: 题目考查基本公式（平行板电容器电容公式）的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在计算题中属于单一公式直接计算难度，仅需应用平行板电容公式C = ε₀εᵣA/d进行简单数值代入和计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 4853, + "question": "Consider a parallel-plate capacitor having an area of 3225 mm2 (5 in.2), a plate separation of 1mm (0.04 in.), and a material having a dielectric constant of 3.5 positioned between the plates. Compute the electric field that must be applied for 2 × 10−8 C to be stored on each plate.", + "answer": "the electric field that must be applied is 2.0 × 105 v/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解电场强度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（电容公式和电场公式）进行简单计算，涉及直接套用公式和单位转换，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用平行板电容器的基本公式（C = εA/d）和电场与电荷的关系（E = V/d），通过简单的数值代入和计算即可得到答案。无需多个公式组合或复杂的推导步骤，属于最基础的计算题类型。" + }, + { + "idx": 4854, + "question": "The polarization P of a dielectric material positioned within a parallel-plate capacitor is to be 4.0 × 10^-6 C/m^2. What must be the dielectric constant if an electric field of 10^5 V/m is applied?", + "answer": "the dielectric constant εr must be 5.52.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解介电常数，答案是一个具体的数值结果（5.52），这符合计算题的特征。 | 知识层次: 题目需要应用基本公式（P = ε0(εr - 1)E）进行简单计算，属于直接套用公式的简单应用层次，不需要多步计算或综合分析。 | 难度: 该题目属于计算题中的单一公式直接计算类型。题目明确给出了极化强度P和电场强度E，要求计算介电常数εr，可以直接使用公式P = ε0(εr - 1)E进行一步计算。不需要多个公式组合或复杂推导，属于该题型中最基础的难度等级。" + }, + { + "idx": 4855, + "question": "The polarization P of a dielectric material positioned within a parallel-plate capacitor is to be 4.0 × 10^-6 C/m^2. What will be the dielectric displacement D?", + "answer": "the dielectric displacement D will be 4.89 × 10^-6 c/m^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解电介质位移D，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求应用基本公式（如D = ε₀E + P）进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于等级1难度。题目仅需要直接应用单一公式（D = ε₀E + P）进行计算，且没有复杂的步骤或额外的公式组合。属于基本公式的直接套用和简单计算。" + }, + { + "idx": 4856, + "question": "For each of the three types of polarization, briefly describe the mechanism by which dipoles are induced and/or oriented by the action of an applied electric field.", + "answer": "For electronic polarization, the electric field causes a net displacement of the center of the negatively charged electron cloud relative to the positive nucleus. With ionic polarization, the cations and anions are displaced in opposite directions as a result of the application of an electric field. Orientation polarization is found in substances that possess permanent dipole moments; these dipole moments become aligned in the direction of the electric field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对三种极化机制进行简要描述，需要文字解释和论述，而不是选择、判断或计算。答案也是以文字形式详细解释了每种极化机制的工作原理。 | 知识层次: 题目考查对三种极化机制的基本概念记忆和理解，包括电子极化、离子极化和取向极化的定义和基本原理，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述三种极化机制，涉及电子极化、离子极化和取向极化的基本原理，但不需要深入分析或复杂的概念体系阐述。回答需要准确记忆和清晰表述各极化类型的核心机制，属于中等难度的概念解释类简答题。" + }, + { + "idx": 4857, + "question": "For gaseous argon, solid LiF, liquid H2O, and solid Si, what kind(s) of polarization is (are) possible? Why?", + "answer": "Only electronic polarization is found in gaseous argon; being an inert gas, its atoms will not be ionized nor possess permanent dipole moments. Both electronic and ionic polarizations are found in solid LiF, since it is strongly ionic. In all probability, no permanent dipole moments will be found in this material. Both electronic and orientation polarizations are found in liquid H2O. The H2O molecules have permanent dipole moments that are easily oriented in the liquid state. Only electronic polarization is to be found in solid Si; this material does not have molecules with permanent dipole moments, nor is it an ionic material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同物质中可能存在的极化类型进行解释和论述，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求对不同物质（气态氩、固态LiF、液态H2O、固态Si）的极化类型进行分析和解释，需要理解电子极化、离子极化和取向极化的概念，并能将这些概念应用到具体的物质状态和结构中。这涉及到多步的概念关联和综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在简答题题型中，该题目要求对四种不同状态的物质进行多角度分析，涉及电子极化、离子极化和取向极化等多种极化类型的判断和解释。需要考生综合运用材料科学和物理化学的知识，对不同物质的结构和性质有深入理解，并能准确关联到极化现象。虽然不需要进行复杂的数学计算，但需要对概念有清晰的把握和逻辑的论述能力，属于较高层次的综合分析题。" + }, + { + "idx": 4863, + "question": "Compare gray and malleable cast irons with respect to composition and heat treatment", + "answer": "Gray iron--2.5 to 4.0 wt% C and 1.0 to 3.0 wt% Si. For most gray irons there is no heat treatment after solidification. Malleable iron--2.5 to 4.0 wt% C and less than 1.0 wt% Si. White iron is heated in a nonoxidizing atmosphere and at a temperature between 800 and 900°C for an extended time period.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较灰铸铁和可锻铸铁在成分和热处理方面的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较灰铸铁和可锻铸铁的成分和热处理工艺，涉及两种材料的组成差异和热处理条件的对比。这需要理解材料的基本组成和热处理原理，并进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对灰铸铁和可锻铸铁的成分和热处理进行比较分析。虽然涉及多个知识点（成分范围、热处理工艺），但分析层次相对直接，主要基于记忆和基本概念的应用，不需要多角度或深度关联性分析。因此，在简答题的中等应用层次中属于综合分析和说明的难度等级。" + }, + { + "idx": 4864, + "question": "Compare gray and malleable cast irons with respect to microstructure", + "answer": "Gray iron--Graphite flakes are embedded in a ferrite or pearlite matrix. Malleable iron--Graphite clusters are embedded in a ferrite or pearlite matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的微观结构，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对灰铸铁和可锻铸铁微观结构的基本概念记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求比较灰铸铁和可锻铸铁的微观结构，需要考生对两种铸铁的微观组织特征进行描述和对比，但不需要深入阐述复杂的概念体系或进行多层次的推理分析。这属于基础概念记忆层次的知识点，但比单纯的定义简答（等级1）要求稍高，需要一定的理解和描述能力。" + }, + { + "idx": 4865, + "question": "Compare gray and malleable cast irons with respect to mechanical characteristics", + "answer": "Gray iron--Relatively weak and brittle in tension; good capacity for damping vibrations. Malleable iron--Moderate strength and ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的机械特性，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的描述性回答，符合简答题的特征。 | 知识层次: 题目考查对灰铸铁和可锻铸铁机械特性的基本概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在简答题题型内，该题目要求对两种铸铁的机械特性进行比较解释，属于概念解释和描述的难度等级。虽然需要记忆和对比两个材料的基本特性，但不需要深入分析复杂概念体系或进行多层次的论述。" + }, + { + "idx": 4866, + "question": "What are the distinctive features, limitations, and applications of titanium alloys?", + "answer": "Distinctive features: relatively low density, high melting temperatures, and high strengths are possible. Limitation: because of chemical reactivity with other materials at elevated temperatures, these alloys are expensive to refine. Applications: aircraft structures, space vehicles, and in chemical and petroleum industries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释钛合金的独特特征、局限性和应用，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求对钛合金的特性、局限性和应用进行综合分析和论述，涉及多个知识点的关联和综合分析，需要一定的理解和应用能力，但不需要进行复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目要求对钛合金的多个方面（特性、局限性和应用）进行多角度分析论述。需要考生不仅掌握钛合金的基本特性，还要理解其在实际应用中的限制和具体应用场景，涉及概念关联和综合分析。虽然不需要深度关联性分析，但多角度的论述要求使其在同题型中属于较高难度。" + }, + { + "idx": 4867, + "question": "What are the distinctive features, limitations, and applications of refractory metals?", + "answer": "Distinctive features: extremely high melting temperatures; large elastic moduli, hardnesses, and strengths. Limitation: some experience rapid oxidation at elevated temperatures. Applications: extrusion dies, structural parts in space vehicles, incandescent light filaments, x-ray tubes, and welding electrodes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述耐火金属的独特特征、局限性和应用，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求对耐火金属的独特特征、局限性和应用进行解释和论述，涉及多个知识点的关联和综合分析，需要理解并应用相关概念，但不需要复杂的推理或创新设计。 | 难度: 在简答题中属于较高难度，题目要求对耐火金属的多个方面（特性、局限性和应用）进行详细说明和分析。需要综合运用材料科学知识，进行多角度论述，并关联不同概念（如高温性能与氧化限制的关系）。虽然不涉及深度关联性分析（如跨学科知识），但已超出基础概念复述的范畴，属于典型的中等应用层次综合分析题。" + }, + { + "idx": 4868, + "question": "What are the distinctive features, limitations, and applications of superalloys?", + "answer": "Distinctive features: able to withstand high temperatures and oxidizing atmospheres for long time periods. Applications: aircraft turbines, nuclear reactors, and petrochemical equipment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述超合金的独特特征、局限性和应用，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释超合金的显著特征、局限性和应用，涉及多个知识点的关联和综合分析，需要理解超合金的基本特性并能够将其与具体应用场景联系起来，属于中等应用层次。 | 难度: 在简答题题型中，该题目要求对超合金的多个方面（特征、局限性和应用）进行多角度分析论述。虽然不需要进行深度关联性分析（如等级5所要求的），但需要综合不同领域的知识（材料科学、工程应用等）来全面回答问题，这超出了简单的概念解释或单一特征说明（等级3），属于中等偏上的难度水平。" + }, + { + "idx": 4869, + "question": "What are the distinctive features, limitations, and applications of noble metals?", + "answer": "Distinctive features: highly resistant to oxidation, especially at elevated temperatures; soft and ductile. Limitation: expensive. Applications: jewelry, dental restoration materials, coins, catalysts, and thermocouples.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述贵金属的独特特征、局限性和应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对贵金属的多个方面（特征、局限性和应用）进行综合论述，需要将不同知识点关联起来进行分析，但不需要进行复杂的推理或创新设计。 | 难度: 在简答题题型中，该题目要求对贵金属的多个方面（特征、局限性和应用）进行多角度分析论述。虽然不需要深度关联性分析（等级5），但需要综合多个知识点并进行较为详细的说明，超出了简单列举或单一概念解释的难度（等级3）。因此，在简答题题型内属于较高难度。" + }, + { + "idx": 4870, + "question": "For the MgO-Al2O3 system, what is the maximum temperature that is possible without the formation of a liquid phase?", + "answer": "This problem asks that we specify, for the MgO-Al2O3 system, the maximum temperature without the formation of a liquid phase; it is approximately 2800 degrees Celsius.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在MgO-Al2O3系统中不形成液相的最高温度，答案提供了具体的温度值并需要文字解释，符合简答题的特征。 | 知识层次: 题目需要理解MgO-Al2O3系统的相图，并从中提取关键信息（最高无液相温度），这涉及到多步分析和概念关联，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在简答题中属于中等难度，需要理解MgO-Al2O3系统的相图，并能够综合分析不同温度下的相变情况。虽然题目要求的是最大温度而不涉及复杂的计算，但需要对相图有较深的理解才能准确回答。" + }, + { + "idx": 4871, + "question": "For the MgO-Al2O3 system, at what composition or over what range of compositions will this maximum temperature be achieved?", + "answer": "This maximum temperature is possible for pure MgO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在MgO-Al2O3系统中，哪个组成或组成范围可以达到最高温度，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解MgO-Al2O3系统的相图特性，并能够分析特定组成范围内的温度变化趋势，涉及多步概念关联和综合分析，但不需要复杂的机理解释或创新应用。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目涉及MgO-Al2O3系统的综合分析，但答案明确指向纯MgO这一特定情况，不需要多角度或深度关联性分析。解题过程主要需要理解相图概念和最高温度点的判断，属于典型的中等应用层次要求。" + }, + { + "idx": 4872, + "question": "What are the characteristics of sand casting technique?", + "answer": "For sand casting, sand is the mold material, a two-piece mold is used, ordinarily the surface finish is not an important consideration, the sand may be reused (but the mold may not), casting rates are low, and large pieces are usually cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释砂型铸造技术的特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对砂型铸造技术特点的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。题目要求列举砂型铸造技术的特点，需要考生对砂型铸造的基本原理和操作过程有一定的理解和记忆，但不需要深入分析或阐述复杂的概念体系。回答该题目需要掌握砂型铸造的基本特征，如模具材料、模具类型、表面处理、模具重复使用性、铸造速率和铸件尺寸等，这些都属于基础概念记忆的范畴。因此，该题目在简答题题型中属于中等难度。" + }, + { + "idx": 4873, + "question": "What are the characteristics of die casting technique?", + "answer": "For die casting, a permanent mold is used, casting rates are high, the molten metal is forced into the mold under pressure, a two-piece mold is used, and small pieces are normally cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述压铸技术的特点，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对压铸技术特点的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述压铸技术的特点，涉及多个关键点（如永久模具、高铸造速率、压力注入等），但不需要深入分析或构建复杂概念体系。属于概念解释和描述级别，比单纯的定义简答（等级1）要求更高，但未达到复杂体系阐述（等级3）的程度。" + }, + { + "idx": 4874, + "question": "What are the characteristics of investment casting technique?", + "answer": "For investment casting, a single-piece mold is used, which is not reusable; it results in high dimensional accuracy, good reproduction of detail, and a fine surface finish; and casting rates are low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释投资铸造技术的特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查投资铸造技术的基本特征，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释投资铸造技术的特点，需要考生回忆并描述该技术的几个关键特征（如单件模具、高尺寸精度、细节再现性好等），但不需要进行复杂的体系阐述或深入分析。这属于对基础概念的记忆和简单应用，符合等级2的标准。" + }, + { + "idx": 4875, + "question": "What are the characteristics of lost-foam casting technique?", + "answer": "For lost foam casting, the pattern is polystyrene foam, whereas the mold material is sand. Complex geometries and tight tolerances are possible. Casting rates are higher than for investment, and there are few environmental wastes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释lost-foam casting technique的特性，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目主要考查对消失模铸造技术特点的基础概念记忆和理解，包括材料选择、工艺特点和优势等基本知识点，不涉及复杂分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释和描述lost-foam casting technique的特性，包括材料、几何复杂度、生产率和环境影响等方面。这属于概念解释和描述的难度等级，需要学生对相关概念有一定的理解和记忆，但不需要进行复杂的体系阐述或深入分析。" + }, + { + "idx": 4876, + "question": "What are the characteristics of continuous casting technique?", + "answer": "For continuous casting, at the conclusion of the extraction process, the molten metal is cast into a continuous strand having either a rectangular or circular cross-section; these shapes are desirable for subsequent secondary metal-forming operations. The chemical composition and mechanical properties are relatively uniform throughout the cross-section.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释连续铸造技术的特点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查连续铸造技术的基本特征和原理的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释连续铸造技术的特点，涉及对基本原理和工艺特点的描述，但不需要深入分析复杂概念体系或进行多层次的论述。答案提供了对连续铸造过程的基本描述和其优势的简要说明，符合等级2的要求。" + }, + { + "idx": 4877, + "question": "What is the distinction between dye and pigment colorants?", + "answer": "The distinction between dye and pigment colorants is that a dye dissolves within and becomes a part of the polymer structure, whereas a pigment does not dissolve, but remains as a separate phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释染料和颜料着色剂之间的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查染料和颜料色料的基本定义和区别，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求解释染料和颜料色剂之间的区别，涉及基本概念的定义和描述。虽然需要理解两者的溶解性差异，但不需要复杂的分析或阐述多个相关概念体系，属于概念解释和描述的难度等级。" + }, + { + "idx": 4878, + "question": "Cite four factors that determine what fabrication technique is used to form polymeric materials.", + "answer": "Four factors that determine what fabrication technique is used to form polymeric materials are: (1) whether the polymer is thermoplastic or thermosetting; (2) if thermoplastic, the softening temperature; (3) atmospheric stability; and (4) the geometry and size of the finished product.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释四个决定聚合物材料制造技术的因素，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目主要考查对聚合物材料加工技术选择因素的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要列举四个决定聚合物材料制造技术的因素，但每个因素都是基础概念记忆层面的知识点，不需要深入解释或复杂推理。相比等级1的基本定义简答，该题目要求对多个相关概念进行列举和简要说明，但尚未达到等级3的复杂概念体系阐述程度。" + }, + { + "idx": 4879, + "question": "What is the process of compression molding used to form plastic materials?", + "answer": "For compression molding, both heat and pressure are applied after the polymer and necessary additives are situated between the mold members.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释压缩成型的过程，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查压缩成型过程的基本概念和原理，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释压缩成型的过程，涉及对基本原理的记忆和简要描述，但不需要深入分析或阐述复杂的概念体系。回答需要包含关键步骤（加热、加压、模具放置等），但不需要扩展或与其他工艺对比，属于中等偏基础的难度。" + }, + { + "idx": 4880, + "question": "What is the process of transfer molding used to form plastic materials?", + "answer": "For transfer molding, the solid materials (normally thermosetting in nature) are first melted in the transfer chamber prior to being forced into the die.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释transfer molding的过程，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对转移模塑工艺的基本概念和步骤的记忆和理解，属于基础概念记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。题目要求解释transfer molding的过程，但不需要深入分析或比较多个概念体系。回答需要描述基本步骤和材料特性，属于对基础概念的记忆和简单应用，符合等级2的标准。" + }, + { + "idx": 4881, + "question": "What is the process of injection molding used to form plastic materials?", + "answer": "For injection molding (normally used for thermoplastic materials), the raw materials are impelled by a ram through a heating chamber, and finally into the die cavity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释注射成型的过程，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查注射成型过程的基本概念和步骤，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目要求对注射成型过程进行解释和描述，涉及基本原理的记忆和简单阐述。虽然需要一定的知识掌握，但不需要复杂的体系阐述或深入分析，属于概念解释和描述的难度等级。" + }, + { + "idx": 4882, + "question": "Why must fiber materials that are melt-spun be thermoplastic?", + "answer": "Fiber materials that are melt spun must be thermoplastic because they must be capable of forming a viscous liquid when heated, which is not possible for thermosets.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么熔纺纤维材料必须是热塑性的，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性材料基本特性的记忆和理解，即为什么熔纺纤维材料必须是热塑性的。这属于基础概念的记忆和简单解释，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释为什么熔纺纤维材料必须是热塑性的，这需要对热塑性和热固性材料的基本特性有一定理解，并能简要说明熔纺工艺对材料性质的要求。虽然涉及基本原理的记忆，但不需要复杂的体系阐述或多步骤推理，因此属于中等难度。" + }, + { + "idx": 4883, + "question": "Why must fiber materials that are drawn be thermoplastic?", + "answer": "Fiber materials that are drawn must be thermoplastic because during drawing, mechanical elongation must be possible; inasmuch as thermosetting materials are, in general, hard and relatively brittle, they are not easily elongated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么纤维材料在拉伸过程中必须是热塑性的，需要提供文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解纤维材料在拉伸过程中的行为，并解释为什么必须是热塑性材料。这涉及到对热塑性和热固性材料特性的理解，以及它们在拉伸过程中的行为差异。虽然不涉及复杂的计算或综合分析，但需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解热塑性材料的基本特性，并能将其与热固性材料进行对比分析。题目要求解释为什么纤维材料在拉伸过程中必须是热塑性的，这涉及到对材料机械性能和加工过程的理解，但不需要过于深入的多角度分析或复杂的关联性论述。" + }, + { + "idx": 4884, + "question": "Estimate the maximum thermal conductivity value for a cermet that contains 90 vol% titanium carbide (TiC) particles in a nickel matrix. Assume thermal conductivities of 27 and 67 W/m·K for TiC and Ni, respectively.", + "answer": "the maximum thermal conductivity k_max is 31.0 W/m·K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计最大热导率值，答案是一个具体的数值结果（31.0 W/m·K），这符合计算题的特征。 | 知识层次: 题目需要应用复合材料热导率的计算公式，涉及两种材料的热导率数值和体积分数的综合计算，属于多步计算和概念关联的中等应用层次。 | 难度: 在计算题中属于多步骤计算过程难度，需要应用复合材料热导率的混合规则公式进行计算，但步骤相对直接，不涉及复杂多变量或高度综合的分析。" + }, + { + "idx": 4885, + "question": "Estimate the minimum thermal conductivity value for a cermet that contains 90 vol% titanium carbide (TiC) particles in a nickel matrix. Assume thermal conductivities of 27 and 67 W/m·K for TiC and Ni, respectively.", + "answer": "the minimum thermal conductivity k_min is 28.7 W/m·K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计cermet的最小热导率值，答案是一个具体的数值结果（28.7 W/m·K），这表明解答过程涉及计算步骤和公式应用。 | 知识层次: 题目需要应用复合材料热导率的最小值计算公式，涉及多步计算和不同材料性能的综合分析，但不需要复杂的推理或深度理解。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料热导率的最小值公式，涉及多步计算和不同材料属性的综合考量，但不需要处理复杂多变量或高级数学技巧。" + }, + { + "idx": 4887, + "question": "For a continuous and oriented fiber-reinforced composite, the moduli of elasticity in the longitudinal and transverse directions are 33.1 and 3.66 \\mathrm{GPa}\\left(4.8 × 10^{6}\\right. and \\left.5.3 × 10^{5} psi\\right), respectively. If the volume fraction of fibers is 0.30 , determine the moduli of elasticity of fiber and matrix phases.", + "answer": "the moduli of elasticity of the matrix and fiber phases are: \\[\ne_{m} = 2.6 \\, \\text{gpa} (3.77 × 10^{5} \\, \\text{psi})\n\\] \\[\ne_{f} = 104 \\, \\text{gpa} (15 × 10^{6} \\, \\text{psi})\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定纤维和基体相的弹性模量，答案也是具体的数值结果。 | 知识层次: 题目需要应用复合材料弹性模量的计算公式，涉及纵向和横向弹性模量的多步计算，并需要理解纤维和基体相在复合材料中的相互作用。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料力学中的混合法则公式，进行多步计算和概念关联。题目要求根据给定的纵向和横向弹性模量以及纤维体积分数，反推出纤维和基体相的弹性模量，涉及多个变量的综合分析和计算步骤，但尚未达到复杂多变量计算的程度。" + }, + { + "idx": 4888, + "question": "In an aligned and continuous carbon fiber-reinforced nylon 6,6 composite, the fibers are to carry 97% of a load applied in the longitudinal direction. Using the data provided, determine the volume fraction of fibers required.", + "answer": "the volume fraction of fibers required is 0.258.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定纤维的体积分数，答案是一个具体的数值（0.258），这表明需要进行计算和推导。 | 知识层次: 题目需要进行多步计算，涉及复合材料中纤维承载比例的公式应用，需要理解纤维和基体的力学贡献，并进行综合分析以确定纤维的体积分数。虽然不涉及复杂的机理分析或创新设计，但超出了简单直接套用公式的范畴。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料力学的基本概念，应用载荷分配公式，并进行多步计算。虽然计算过程不涉及复杂多变量，但需要综合分析纤维和基体的力学性能数据，并正确应用公式求解体积分数。" + }, + { + "idx": 4889, + "question": "In an aligned and continuous carbon fiber-reinforced nylon 6,6 composite, the fibers are to carry 97% of a load applied in the longitudinal direction. What will be the tensile strength of this composite? Assume that the matrix stress at fiber failure is 50 MPa (7250 psi).", + "answer": "the tensile strength of this composite is 1070 mpa (155,000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的拉伸强度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及复合材料中纤维和基体的应力分配，需要理解纤维和基体的力学行为及其相互作用，并应用相关公式进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来正确应用公式和条件。 | 难度: 在计算题中属于综合性计算问题，需要理解复合材料力学的基本概念，应用载荷分配原理进行多步计算，并综合分析纤维和基体的应力贡献。虽然计算步骤明确，但需要将多个概念关联起来才能正确求解。" + }, + { + "idx": 4890, + "question": "Cite several reasons why fiberglass-reinforced composites are used extensively.", + "answer": "Reasons why fiberglass-reinforced composites are utilized extensively are: (1) glass fibers are very inexpensive to produce; (2) these composites have relatively high specific strengths; and (3) they are chemically inert in a wide variety of environments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释纤维增强复合材料广泛使用的原因，答案提供了多个理由的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对纤维增强复合材料基本特性的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举并简要解释玻璃纤维增强复合材料广泛使用的原因，涉及多个基本概念的记忆和简单阐述，但不需要深入分析或构建复杂的概念体系。" + }, + { + "idx": 4891, + "question": "Cite several limitations of fiberglass-reinforced composites.", + "answer": "Several limitations of these composites are: (1) care must be exercised in handling the fibers inasmuch as they are susceptible to surface damage; (2) they are lacking in stiffness in comparison to other fibrous composites; and (3) they are limited as to maximum temperature use.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举纤维增强复合材料的几个局限性，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目主要考查对纤维增强复合材料局限性的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求列举玻璃纤维增强复合材料的几个局限性，这需要学生对材料的基本特性有一定了解，并能简要描述其缺点。虽然涉及多个要点（表面易损性、刚度不足、温度限制），但每个要点都是基础概念的直接应用，不需要复杂的分析或体系阐述。相比等级1的基本定义简答，该题需要更深入的概念理解；相比等级3的复杂概念体系阐述，该题的解题步骤和知识深度要求较为基础。" + }, + { + "idx": 4892, + "question": "What is a hybrid composite?", + "answer": "A hybrid composite is a composite that is reinforced with two or more different fiber materials in a single matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"hybrid composite\"进行文字解释和论述，答案是一个定义性的简短描述，符合简答题的特征 | 知识层次: 题目考查对混合复合材料基本定义的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目仅要求回答混合复合材料的定义，属于最基本的概念记忆性知识。不需要进行额外的解释或描述，也不涉及复杂概念体系的阐述。因此在该题型内属于最简单的等级1难度。" + }, + { + "idx": 4893, + "question": "List two important advantages of hybrid composites over normal fiber composites.", + "answer": "Two advantages of hybrid composites are: (1) better overall property combinations, and (2) failure is not as catastrophic as with single-fiber composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举混合复合材料相对于普通纤维复合材料的两个重要优势，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对混合复合材料基本优势的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求列举两种混合复合材料的优势，并需要简要解释这些优势。这属于概念解释和描述的难度等级，因为不仅需要记忆基本概念，还需要对概念进行一定的理解和阐述。相比于等级1的基本定义简答，该题目要求更深入的理解和解释，但尚未达到等级3的复杂概念体系阐述的深度。" + }, + { + "idx": 4894, + "question": "(a) Write an expression for the modulus of elasticity for a hybrid composite in which all fibers of both types are oriented in the same direction.", + "answer": "the expression for the modulus of elasticity for a hybrid composite with all fibers aligned in the same direction is: e_cl = e_m v_m + e_f1 v_f1 + e_f2 v_f2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出混合复合材料弹性模量的表达式，需要文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求写出混合复合材料弹性模量的表达式，这属于基本公式的直接应用，不需要复杂的推理或多步计算，仅需理解各组分对整体模量的贡献并正确组合即可。 | 难度: 在简答题中属于简单应用过程描述，题目要求直接套用混合复合材料弹性模量的基本公式，无需深入解释或复杂推导。解题步骤简单，仅需将各组分模量和体积分数代入公式即可完成。" + }, + { + "idx": 4895, + "question": "(b) Using this expression, compute the longitudinal modulus of elasticity of a hybrid composite consisting of aramid and glass fibers in volume fractions of 0.25 and 0.35 , respectively, within a polyester resin matrix [E_m=4.0 GPa (6x10^5 psi)].", + "answer": "the longitudinal modulus of elasticity of the hybrid composite is: e_cl = 59.7 gpa (8.67x10^6 psi)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的表达式计算混合复合材料的纵向弹性模量，涉及数值计算和公式应用。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用复合材料弹性模量的计算公式，涉及多个材料的体积分数和弹性模量的综合计算，属于多步计算和概念关联的中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用复合材料弹性模量的混合法则公式，进行多步计算（包括不同纤维体积分数的加权计算和单位转换），并理解各组分材料性能对整体性能的影响。虽然涉及多个变量和步骤，但计算过程相对直接，没有过于复杂的推导或迭代过程。" + }, + { + "idx": 4896, + "question": "Briefly describe laminar composites.", + "answer": "Laminar composites are a series of sheets or panels, each of which has a preferred high-strength direction. These sheets are stacked and then cemented together such that the orientation of the high-strength direction varies from layer to layer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述层状复合材料，答案是一段文字解释，符合简答题的特征 | 知识层次: 题目考查对层状复合材料的基本定义和结构的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求简要描述层状复合材料的基本特征和结构组成，涉及对定义和基本原理的记忆性知识，但不需要进行复杂的概念体系阐述或深入分析。属于该题型中中等偏基础的难度水平。" + }, + { + "idx": 4897, + "question": "What is the prime reason for fabricating laminar composites?", + "answer": "These composites are constructed in order to have a relatively high strength in virtually all directions within the plane of the laminate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释层压复合材料制造的主要原因，答案提供了详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对层状复合材料基本原理的记忆和理解，属于基础概念层次。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释层压复合材料的主要制造原因，需要考生理解并描述复合材料在层压平面内各方向具有较高强度的基本原理。这比单纯记忆基本定义（等级1）要求更高，但不需要进行复杂概念体系的阐述（等级3），属于中等难度的概念解释题。" + }, + { + "idx": 4898, + "question": "Is a voltage generated between the two cell halves of an Fe/Fe2+ concentration cell where both electrodes are pure iron, with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "Yes, a voltage is generated.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（是否产生电压），答案直接给出\"Yes\"或\"No\"的判断形式，不需要计算或详细解释。 | 知识层次: 题目考查浓度电池的基本原理和简单应用，需要理解浓度差如何产生电压，并进行简单的计算或判断。虽然涉及基本概念，但更侧重于应用这些概念来回答问题。 | 难度: 在判断题中属于简单应用结果判断的难度等级。题目直接考察对浓度电池基本原理的理解，只需判断在给定浓度差条件下是否会产生电压，无需进行复杂计算或多步骤推理。属于该题型中较为基础的知识点应用。" + }, + { + "idx": 4899, + "question": "What is the magnitude of the voltage generated in an Fe/Fe2+ concentration cell with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "The magnitude of the voltage is 0.0414 V.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Fe/Fe2+浓度电池的电压大小，需要应用能斯特方程进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目涉及基本的浓度电池电压计算，需要应用能斯特方程进行简单计算，属于基本公式的直接套用，不需要多步推理或综合分析。 | 难度: 在计算题-简单应用题型中，该题目属于简单公式应用计算。虽然需要运用能斯特方程进行计算，但仅涉及单一公式的直接套用和简单对数运算，不需要多个公式组合或复杂推导。解题步骤清晰明确，属于该题型框架内的中等偏低难度。" + }, + { + "idx": 4900, + "question": "Which electrode will be oxidized in an Fe/Fe2+ concentration cell with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "Oxidation occurs in the cell half with the lower Fe2+ concentration (2 × 10^-2 M).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释哪个电极会被氧化，并需要基于浓度差异进行文字解释，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解浓度电池的工作原理，并能分析不同浓度对电极氧化还原反应的影响，涉及多步概念关联和综合分析。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要学生理解浓度电池的基本原理，并能将Fe/Fe2+浓度差与氧化还原反应方向关联起来。解题步骤包括：1)识别浓度差对电极电势的影响；2)应用能斯特方程定性分析；3)得出正确结论。虽然涉及多步推理，但不需要复杂计算，属于典型的综合分析类题目，符合等级3对\"综合分析和说明\"的要求。相比需要定量计算的浓度电池题目(等级4)或涉及多电极系统的复杂分析(等级5)，本题在简答题中属于中等偏上难度。" + }, + { + "idx": 4901, + "question": "For the aluminum and cast iron pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the aluminum-cast iron couple, corrosion is possible, and aluminum will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪种金属会腐蚀，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要学生理解电偶腐蚀的基本原理，并能够应用这些知识来分析特定金属对（铝和铸铁）在海水环境中的腐蚀行为。这涉及到对不同金属电化学性质的理解和比较，属于中等应用层次的知识。 | 难度: 在简答题中属于中等难度，需要理解电偶腐蚀的基本原理，并能正确识别铝和铸铁在海水中的电化学行为差异。虽然题目涉及多步概念关联（如电偶序、环境因素、材料选择），但不需要进行复杂的多角度分析或深度关联性分析。解题步骤主要包括识别电偶对、判断腐蚀倾向性以及确定被腐蚀金属，属于典型的综合分析说明题。" + }, + { + "idx": 4902, + "question": "For the Inconel and nickel pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the Inconel-nickel couple, corrosion is unlikely inasmuch as both alloys appear within the same set of brackets (in both active and passive states).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并解释哪种金属/合金会腐蚀，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解Inconel和镍在海水中的腐蚀行为，并基于它们在电化学序列中的位置进行综合分析。虽然不涉及复杂计算，但需要关联多个概念（如电化学序列、腐蚀可能性判断）并进行逻辑推理，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解金属腐蚀的基本原理，并能综合分析两种金属在特定环境下的电化学行为。题目要求预测腐蚀可能性并解释原因，涉及对金属活性/钝化状态的理解，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4903, + "question": "For the cadmium and zinc pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the cadmium-zinc couple, corrosion is possible, and zinc will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪种金属会腐蚀，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求预测腐蚀可能性并确定腐蚀金属，需要理解电偶腐蚀的基本原理（如电化学序列）并应用到具体金属对（镉-锌）中。这涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解电偶腐蚀的基本原理，并能综合分析不同金属在特定环境（海水）中的电化学行为。题目要求预测腐蚀可能性并指出具体腐蚀金属，涉及多步概念关联和综合分析，但不需要过于深入的多角度或深度关联性分析。" + }, + { + "idx": 4904, + "question": "For the brass and titanium pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the brass-titanium pair, corrosion is possible, and brass will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪个金属会腐蚀，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求预测特定金属对在特定环境中的腐蚀可能性，并确定哪种金属会腐蚀。这需要理解电化学腐蚀的基本原理（如电偶腐蚀），并能应用这些原理分析具体金属对的电化学行为。虽然不涉及复杂计算或多步推理，但需要对金属的电化学性质有较好的理解，并能进行简单的综合分析。 | 难度: 在简答题题型中，该题目属于中等难度。虽然题目涉及两种金属的腐蚀可能性判断，但解题步骤相对直接，主要需要理解电偶腐蚀的基本原理并应用在特定材料组合上。不需要多角度分析或深度关联性分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 4905, + "question": "For the low-carbon steel and copper pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the low-carbon steel-copper couple, corrosion is possible, and the low-carbon steel will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪种金属会腐蚀，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求预测特定金属对在海水中的腐蚀可能性，并判断哪个金属会腐蚀。这需要理解电偶腐蚀的基本原理（不同金属的电化学电位差异），并能将其应用于具体情境（低碳钢和铜在海水中的耦合）。虽然不涉及复杂计算或多步骤推理，但需要综合分析金属的电化学性质和腐蚀环境，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等应用层次，需要学生理解并应用电偶腐蚀的基本原理，分析不同金属在特定环境下的腐蚀行为。虽然题目涉及多步概念关联和综合分析，但解题步骤相对直接，主要考察学生对电偶序和腐蚀倾向的判断能力。相较于需要更深入关联性分析或多角度论述的题目，该题的难度适中，符合等级3的标准。" + }, + { + "idx": 4906, + "question": "A piece of corroded metal alloy plate was found in a submerged ocean vessel. It was estimated that the original area of the plate was 800 cm^2 and that approximately 7.6kg had corroded away during the submersion. Assuming a corrosion penetration rate of 4mm / yr for this alloy in seawater, estimate the time of submersion in years. The density of the alloy is 4.5g/cm^3.", + "answer": "the time of submersion is 5.27 yr.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及腐蚀面积、质量损失、腐蚀速率和密度等参数的运算，最终要求计算时间。答案是一个具体的数值结果（5.27年），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量损失与体积转换、腐蚀速率与时间的关系计算，涉及密度、面积、腐蚀速率等多个概念的关联和综合分析。虽然不需要复杂的推理分析或机理解释，但需要一定的计算步骤和概念关联，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目涉及腐蚀速率、密度、面积和质量等多个物理量的转换和计算，但步骤相对清晰，没有涉及复杂多变量或高阶数学运算。" + }, + { + "idx": 4908, + "question": "Compute the corrosion potential for this reaction. The following corrosion data are known about the metal and solution: For Metal M: V_(MM^2+) = -0.90 V, i_0 = 10^-12 A/cm^2, beta = +0.10. For Hydrogen: V_(H^-/H_2) = 0 V, i_0 = 10^-10 A/cm^2.", + "answer": "the corrosion potential for this reaction is -0.420 V.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的腐蚀数据和公式计算腐蚀电位，答案是一个具体的数值结果（-0.420 V），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用腐蚀电化学的基本公式（如Butler-Volmer方程）进行多步计算，涉及不同电极反应参数的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用腐蚀电化学的基本公式（如Butler-Volmer方程），同时处理金属和氢的两个电极反应体系。解题步骤包括：建立阴阳极极化曲线方程、求解腐蚀电位平衡条件、进行对数计算等。虽然不涉及多变量迭代等复杂计算，但需要正确关联多个电化学参数并执行准确的多步计算过程，符合等级3对综合性计算的要求。" + }, + { + "idx": 4910, + "question": "For a concentration cell, briefly explain why corrosion occurs at the region having the lower concentration.", + "answer": "Inasmuch as \\left[\\mathrm{M}_{\\mathrm{L}}^{2+}\\right] \\prec\\left[\\mathrm{M}_{H}^{2+}\\right] then the natural logarithm of the \\left[\\mathrm{M}^{2+}\\right] ratio is negative, which yields a positive value for \\Delta V. This means that the electrochemical reaction is spontaneous as written, or that oxidation occurs at the electrode having the lower \\mathrm{M}^{2+} concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释腐蚀发生在浓度较低区域的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释浓度电池中腐蚀发生的机理，涉及电化学反应的自发性判断、浓度对电势差的影响以及氧化还原反应的位置选择，需要综合运用电化学原理进行推理分析，属于复杂分析层次。 | 难度: 在简答题-复杂分析题型中，该题目要求对浓度电池的腐蚀机理进行深度解释，涉及电化学原理、自然对数计算以及自发反应判断等综合知识。虽然不需要全面分析复杂现象，但需要准确理解并阐述浓度差异如何导致特定区域的氧化反应，属于机理深度解释的范畴。" + }, + { + "idx": 4911, + "question": "For copper, the heat capacity at constant volume C_V at 20 K is 0.38 J/mol-K and the Debye temperature is 340 K. Estimate the specific heat at 40 K.", + "answer": "the specific heat for copper at 40 K is 47.8 J/kg-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（估算铜在40K时的比热），并给出了具体的计算答案（47.8 J/kg-K），符合计算题的特征。 | 知识层次: 题目需要应用德拜模型和热容公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要应用德拜模型和热容公式进行多步计算，涉及温度换算和单位转换，但不需要处理复杂多变量。" + }, + { + "idx": 4913, + "question": "A 0.4-m (15.7-in.) rod of a metal elongates 0.48mm (0.019 in.) on heating from 20^{\\circ} C to 100^{\\circ} C\\left(68^{\\circ} F\\right. to \\left.212^{\\circ} F\\right). Determine the value of the linear coefficient of thermal expansion for this material.", + "answer": "the linear coefficient of thermal expansion for this material is 15.0 × 10^{-6} \\, ({}^{\\circ} C)^{-1} [8.40 × 10^{-6} \\, ({}^{\\circ} \\mathrm{f})^{-1}].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定线性热膨胀系数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的线性热膨胀系数公式应用，仅需单步计算和单位转换，属于直接套用公式的简单应用层次。 | 难度: 该题目属于计算题中的简单应用层次，仅需直接套用线性热膨胀系数公式（ΔL = αL₀ΔT）进行单一计算步骤。题目已提供所有必要参数（原始长度、温度变化量、伸长量），无需单位换算或复杂推导，完全符合等级1\"单一公式直接计算\"的标准。在同题型内属于最基础的难度级别。" + }, + { + "idx": 4914, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Pure silver; sterling silver (92.5 wt% Ag-7.5 wt% Cu)", + "answer": "Pure silver will have a larger conductivity than sterling silver because the impurity atoms in the latter will lead to a greater degree of free electron scattering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性能并给出合理的解释，答案需要文字论述和解释，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种材料的导热性能，并解释原因。这需要理解热导率的基本概念，同时需要分析合金化对自由电子散射的影响，涉及多个概念的关联和综合分析。虽然不涉及复杂计算，但需要一定的推理和分析能力。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然需要解释和论述，但主要涉及单一概念（热导率）与杂质影响的基本原理，不需要多角度或深度关联性分析。解题步骤相对直接：比较两种材料的组成差异，并运用自由电子散射原理进行解释。这符合\"综合分析和说明\"的等级要求，但未达到更复杂的论述层次。" + }, + { + "idx": 4915, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Fused silica; polycrystalline silica", + "answer": "Polycrystalline silica will have a larger conductivity than fused silica because fused silica is noncrystalline and lattice vibrations are more effectively scattered in noncrystalline materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的导热性能，并解释原因。这需要理解晶体结构对热导率的影响，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在简答题中属于中等难度，需要理解非晶态和多晶态材料对热导率的影响，并能通过分析晶格振动散射效应来论证结论。虽然涉及概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4916, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Linear and syndiotactic poly(vinyl chloride) (DP =1000); linear and syndiotactic polystyrene (DP=1000)", + "answer": "The poly(vinyl chloride) will have the larger conductivity than the polystyrene because the former will have the higher degree of crystallinity. Both polymers are syndiotactic and have the same degree of polymerization. However, with regard to side-group bulkiness, the PVC is more likely to crystallize. Since heat transfer is by molecular chain vibrations, and the coordination of these vibrations increases with percent crystallinity, the higher the crystallinity, the greater the thermal conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，答案通过文字解释和论述来支持选择，没有涉及选择题的选项、判断题的对错判断或计算题的数值计算。 | 知识层次: 题目需要比较两种聚合物的热导率，并基于结晶度和侧基体积效应进行解释。这涉及对聚合物结构-性能关系的理解，以及热导率与结晶度之间关系的应用。虽然不需要复杂的计算或高级的综合分析，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。虽然题目要求比较两种聚合物的热导率并给出合理解释，但解题思路相对明确：主要基于结晶度的差异来分析。学生需要掌握聚合物结构与性能的基本关系（如侧基体积对结晶度的影响），并能将结晶度与热导率建立联系。这需要综合运用多个知识点，但不需要进行复杂的多角度论证或深度关联性分析（如等级4-5的要求）。" + }, + { + "idx": 4917, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Atactic polypropylene (Mw=10^6 g/mol); isotactic polypropylene (Mw=10^5 g/mol)", + "answer": "The isotactic polypropylene will have a larger thermal conductivity than the atactic polypropylene because isotactic polymers have higher degrees of crystallinity. The influence of crystallinity on conductivity is explained in part (c).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性并解释选择的原因，需要文字解释和论述，而不是简单的选择或判断。答案提供了详细的解释和理由，符合简答题的特征。 | 知识层次: 题目要求比较两种聚合物的热导率，并解释原因。这需要理解聚合物结构（等规和无规）与结晶度的关系，以及结晶度对热导率的影响。虽然涉及基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解聚合物结构（如等规和无规）对热导率的影响，并能够解释结晶度与热导率之间的关系。虽然涉及多个概念的综合分析，但解题步骤相对直接，不需要多角度或深度关联性分析。" + }, + { + "idx": 4918, + "question": "Briefly explain why thermal stresses may be introduced into a structure by rapid heating or cooling.", + "answer": "Thermal stresses may be introduced into a structure by rapid heating or cooling because temperature gradients are established across the cross section due to more rapid temperature changes at the surface than within the interior; thus, the surface will expand or contract at a different rate than the interior and since this surface expansion or contraction will be restrained by the interior, stresses will be introduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释热应力在快速加热或冷却时产生的原因，答案通过文字论述进行解释，符合简答题的特征。 | 知识层次: 题目要求解释热应力在快速加热或冷却过程中产生的原因，涉及温度梯度、表面与内部膨胀/收缩速率差异以及应力产生的机理。这需要理解热膨胀的基本原理，并能将多个概念（温度梯度、热膨胀、应力产生）关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解热应力产生的基本原理，并能解释温度梯度与材料内部约束之间的关系。虽然不需要多角度分析或深度关联性分析，但要求对概念进行综合说明和论述。" + }, + { + "idx": 4919, + "question": "For cooling, what is the nature of the surface stresses?", + "answer": "For cooling, the surface stresses will be tensile in nature since the interior contracts to a lesser degree than the cooler surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对冷却过程中表面应力的性质进行解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查冷却过程中表面应力的基本性质和原因，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释冷却过程中表面应力的性质，需要理解并描述基本原理（即内部收缩程度小于冷却表面导致表面产生拉应力），但不需要涉及复杂的概念体系或深入的分析。这比单纯记忆定义（等级1）要求更高，但低于需要阐述多个相关概念的复杂问题（等级3）。" + }, + { + "idx": 4920, + "question": "For heating, what is the nature of the surface stresses?", + "answer": "For heating, the surface stresses will be compressive in nature since the interior expands to a lesser degree than the hotter surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对加热时表面应力的性质进行解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目考查对加热过程中表面应力性质的基本理解和记忆，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释加热时表面应力的性质，需要理解热膨胀的基本原理和表面应力的产生机制，但不需要复杂的推导或多概念整合。属于基础概念记忆层次中的中等难度，比单纯的定义简答（等级1）稍复杂，但未达到复杂概念体系阐述（等级3）的程度。" + }, + { + "idx": 4921, + "question": "The magnetic flux density within a bar of some material is 0.630 tesla at an H field of 5 x 10^5 A/m. Compute the magnetic permeability for this material.", + "answer": "1.260 x 10^-6 h/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（磁通密度与磁场强度的关系）来求解磁导率，答案是一个具体的数值结果。 | 知识层次: 题目要求计算磁导率，仅需应用基本公式（B = μH）进行一步计算，属于直接套用公式的简单应用。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用基本的磁导率公式（μ = B/H），将给定的数值直接代入即可得到结果，无需额外的步骤或复杂的计算过程。" + }, + { + "idx": 4922, + "question": "The magnetic flux density within a bar of some material is 0.630 tesla at an H field of 5 x 10^5 A/m. Compute the magnetic susceptibility for this material.", + "answer": "2.387 x 10^-3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（磁通密度与磁场强度的关系）来求解磁化率，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（磁化率与磁感应强度、磁场强度的关系）进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用磁化率的基本公式χ = B/μ₀H - 1，并进行简单的数值代入和计算。没有涉及多个公式的组合或复杂的推导步骤，属于最基础的计算题类型。" + }, + { + "idx": 4923, + "question": "The magnetic flux density within a bar of some material is 0.630 tesla at an H field of 5 x 10^5 A/m. What type(s) of magnetism would you suggest is (are) being displayed by this material? Why?", + "answer": "This material would display both diamagnetic and paramagnetic behavior. All materials are diamagnetic, and since χm is positive and on the order of 10^-3, there would also be a paramagnetic contribution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料表现出的磁性类型及其原因，答案提供了详细的文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求根据给定的磁场强度和磁通密度判断材料的磁性类型，需要理解磁化率的概念，并能够将实验数据与理论概念关联起来。虽然不涉及复杂的计算，但需要对磁性的基本原理有较好的理解，并能综合分析材料的磁性行为。 | 难度: 在简答题题型中，该题目要求考生不仅能够识别材料表现出的磁性类型，还需要解释为什么这些磁性类型会被观察到。这涉及到对磁化率（χm）的理解，以及如何通过给定的磁场强度（H）和磁通密度（B）来推断材料的磁性行为。此外，题目还要求考生综合应用关于材料磁性的知识，包括所有材料都具有的固有抗磁性（diamagnetism）以及可能存在的顺磁性（paramagnetism）贡献。这种多角度分析和论述的要求使得该题目在同题型内属于较高难度等级。" + }, + { + "idx": 4924, + "question": "A net magnetic moment is associated with each atom in paramagnetic and ferromagnetic materials. Explain why ferromagnetic materials can be permanently magnetized whereas paramagnetic ones cannot.", + "answer": "Ferromagnetic materials may be permanently magnetized (whereas paramagnetic ones may not) because of the ability of net spin magnetic moments of adjacent atoms to align with one another. This mutual magnetic moment alignment in the same direction exists within small volume regions - domains. When a magnetic field is applied, favorably oriented domains grow at the expense of unfavorably oriented ones, by the motion of domain walls. When the magnetic field is removed, there remains a net magnetization by virtue of the resistance to movement of domain walls; even after total removal of the magnetic field, the magnetization of some net domain volume will be aligned near the direction that the external field was oriented.For paramagnetic materials, there is no magnetic dipole coupling, and, consequently, domains do not form. When a magnetic field is removed, the atomic dipoles assume random orientations, and no magnetic moment remains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么铁磁材料可以被永久磁化而顺磁材料不能，需要详细的文字解释和论述，答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释铁磁性和顺磁性材料在磁化行为上的差异，涉及磁矩排列、磁畴形成和运动等复杂机理。需要综合分析磁畴结构对磁化行为的影响，以及顺磁性材料缺乏磁畴结构的原因。这需要深入理解磁学原理和材料微观结构之间的关联，属于对复杂现象的机理分析和解释。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于复杂现象全面分析的难度等级。题目要求解释铁磁性和顺磁性材料在磁化行为上的根本差异，涉及多个复杂概念的整合：包括自旋磁矩排列、磁畴形成、畴壁运动机制，以及外场移除后的剩磁原理。需要考生综合运用磁学理论，建立多级因果关系，并对比两种材料的微观机制差异。这种对材料磁化机理的系统性解释要求，明显超出了简单概念复述或单一原理说明的范畴，符合该题型下最高难度等级的标准。" + }, + { + "idx": 4925, + "question": "The chemical formula for copper ferrite may be written as \\left(\\mathrm{CuFe}_{2} \\mathrm{O}_{4}\\right)_{8} because there are eight formula units per unit cell. If this material has a saturation magnetization of 1.35 × 10^{5} A/m and a density of 5.40g /cm^3, estimate the number of Bohr magnetons associated with each Cu^{2+} ion.", + "answer": "1.07 bohr magnetons/cu^{2+} ion", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以估计每个Cu^{2+}离子所关联的玻尔磁子数。答案是一个具体的数值结果（1.07 bohr magnetons/cu^{2+} ion），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及饱和磁化强度和密度的关系，以及玻尔磁子的计算。需要理解并应用相关公式，进行综合分析，但不需要复杂的推理或创新设计。 | 难度: 在计算题中属于综合性计算问题，需要理解饱和磁化强度和玻尔磁子的概念，进行多步计算和单位转换，涉及密度、分子量和磁矩的综合分析。虽然计算步骤明确，但需要较强的概念关联和数值处理能力。" + }, + { + "idx": 4926, + "question": "The formula for samarium iron garnet (Sm3Fe5O12) may be written in the form Sm3^aFe2^cFe3^dO12, where the superscripts a, c, and d represent different sites on which the Sm^3+ and Fe^3+ ions are located. The spin magnetic moments for the Sm^3+ and Fe^3+ ions positioned in a and c sites are oriented parallel to one another and antiparallel to the Fe^3+ ions in d sites. Compute the number of Bohr magnetons associated with each Sm^3+ ion, given the following information: (1) each unit cell consists of eight formula (Sm3Fe5O12) units; (2) the unit cell is cubic with an edge length of 1.2529 nm; (3) the saturation magnetization for this material is 1.35 × 10^5 A/m; and (4) there are 5 Bohr magnetons associated with each Fe^3+ ion.", + "answer": "2.86 bm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及磁矩的计算和单位转换，最终需要得出具体的数值结果（2.86 bm）。解答过程需要运用给定的物理参数和公式，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，涉及饱和磁化强度、单位晶胞体积、磁矩方向关系等多个概念的关联和综合分析。虽然不涉及复杂的机理分析或创新设计，但需要将多个已知条件有机结合并正确应用公式进行计算，属于中等难度的应用题型。 | 难度: 在计算题中属于综合性计算问题，需要结合多个概念（如磁矩、晶体结构、饱和磁化强度）进行多步计算。题目提供了多个信息点，要求考生能够正确关联和应用这些信息，包括单位晶胞参数、离子磁矩方向、以及饱和磁化强度的计算。虽然计算步骤明确，但需要较强的综合分析能力和对材料磁学性质的理解。" + }, + { + "idx": 4927, + "question": "An iron bar magnet having a coercivity of 7000 A/m is to be demagnetized. If the bar is inserted within a cylindrical wire coil 0.25m long and having 150 turns, what electric current is required to generate the necessary magnetic field?", + "answer": "11.7A", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的电流值，答案是一个具体的数值（11.7A），解答过程涉及磁学公式和单位转换。 | 知识层次: 题目涉及基本公式应用（H = nI/l）和简单计算，仅需直接套用公式即可求解所需电流，无需多步计算或综合分析。 | 难度: 在计算题中属于单一公式直接计算的难度等级，只需要应用基本公式H = nI/l进行简单计算，无需多个公式组合或复杂步骤。" + }, + { + "idx": 4928, + "question": "Cite the differences between type I and type II superconductors.", + "answer": "For type I superconductors, with increasing magnetic field the material is completely diamagnetic and superconductive below H_{C}, while at H_{C} conduction becomes normal and complete magnetic flux penetration takes place. On the other hand, for type II superconductors upon increasing the magnitude of the magnetic field, the transition from the superconducting to normal conducting states is gradual between lower-critical and upper-critical fields; so also is magnetic flux penetration gradual. Furthermore, type II superconductors generally have higher critical temperatures and critical magnetic fields.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答，需要详细描述I型和II型超导体的区别，而不是选择、判断或计算。答案也以论述形式呈现，符合简答题的特征。 | 知识层次: 题目考查对I型和II型超导体基本特性的记忆和理解，属于基础概念的分类和基本原理的对比。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求区分两种超导体的特性，包括临界磁场行为、磁通穿透方式以及临界温度等基本特征。虽然涉及多个概念点，但都属于基础概念记忆层次，不需要构建复杂的概念体系或进行深入分析。解题步骤主要是对两类超导体特性的对比描述，属于该题型中中等偏基础的难度水平。" + }, + { + "idx": 4929, + "question": "Briefly describe the Meissner effect.", + "answer": "The Meissner effect is a phenomenon found in superconductors wherein, in the superconducting state, the material is diamagnetic and completely excludes any external magnetic field from its interior. In the normal conducting state complete magnetic flux penetration of the material occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Meissner效应，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对Meissner效应的基本定义和现象的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在简答题题型中，该题目要求对Meissner效应进行概念解释和描述，不仅需要记忆基本定义，还需要理解并阐述超导体在超导态和正常态下的磁学行为差异。这属于概念解释和描述的难度层次，比单纯复述定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 4930, + "question": "Visible light having a wavelength of 5 x 10^-7 m appears green. Compute the frequency of a photon of this light.", + "answer": "the frequency of the photon is 6 x 10^14 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（使用波长和光速的关系公式）得出频率的数值结果，答案是一个具体的计算值（6 x 10^14 s^-1），符合计算题的特征。 | 知识层次: 题目需要应用基本公式（频率=光速/波长）进行简单计算，属于直接套用公式的简单应用层次。 | 难度: 在计算题中属于单一公式直接计算的难度等级。题目只需要应用光速公式c = λν，将已知波长代入即可直接求出频率，无需额外的公式组合或复杂计算步骤。这是该题型中最基础的计算类型。" + }, + { + "idx": 4931, + "question": "Visible light having a wavelength of 5 x 10^-7 m appears green. Compute the energy of a photon of this light.", + "answer": "the energy of the photon is 3.98 x 10^-19 j (2.48 ev).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如光子能量公式E=hc/λ）来求解光子的能量，答案以具体数值形式给出，符合计算题的特征。 | 知识层次: 题目要求应用基本公式（光子能量公式E=hc/λ）进行简单计算，无需多步推理或综合分析，属于直接套用公式的简单应用。 | 难度: 在计算题中属于最低难度，仅需直接套用单一公式E=hc/λ进行计算，无需多步推导或组合公式。题目提供了所有必要参数，计算过程简单直接。" + }, + { + "idx": 4935, + "question": "Can a material have a positive index of refraction less than unity? Why or why not?", + "answer": "In order for a material to have an index of refraction less than unity, the velocity of light in the material (v) would necessarily have to be greater than the velocity of light in a vacuum . This is not possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对材料折射率小于1的可能性进行解释和论述，答案提供了详细的文字解释而非简单选择或判断 | 知识层次: 题目要求解释折射率小于1的可能性，涉及光速在材料中的传播特性与真空光速的关系，需要深入理解折射率的物理本质和光速限制，属于需要综合运用物理原理进行推理分析的复杂问题。 | 难度: 在简答题（需要文字解释和论述）题型中，该题目属于机理深度解释难度。题目要求解释材料折射率小于1的可能性，这需要深入理解折射率的物理定义（光速比）及其物理限制。虽然解题步骤相对直接（只需说明光速不可能超过真空光速），但需要掌握电磁波在介质中传播的基本原理和相对论限制，属于对物理机理的深度解释层面。相比需要复杂推导或多因素分析的题目（等级5），该题更侧重于单一物理概念的深度阐述。" + }, + { + "idx": 4936, + "question": "The index of refraction of quartz is anisotropic. Suppose that visible light is passing from one grain to another of different crystallographic orientation and at normal incidence to the grain boundary. Calculate the reflectivity at the boundary if the indices of refraction for the two grains are 1.544 and 1.553 in the direction of light propagation.", + "answer": "the reflectivity at the boundary is 8.45 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解反射率，答案是一个具体的数值结果（8.45 × 10^{-6}），符合计算题的特征。 | 知识层次: 题目要求使用反射率公式进行直接计算，涉及基本的光学公式应用，无需多步推理或综合分析。 | 难度: 在计算题 - 需要数值计算和公式应用的题型中，该题目属于单一公式直接计算的难度等级。题目仅要求使用反射率的基本公式（如菲涅尔方程）进行计算，且给定的折射率数值直接代入即可得到结果，无需额外的推导或组合多个公式。解题步骤简单明了，符合等级1的标准。" + }, + { + "idx": 4937, + "question": "Zinc selenide has a band gap of 2.58 eV. Over what range of wavelengths of visible light is it transparent?", + "answer": "pure znse is transparent to visible light having wavelengths between 0.48 and 0.7 \\mu m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要根据给定的能带隙（2.58 eV）计算对应的波长范围，涉及公式应用和数值计算。答案给出了具体的数值结果（0.48到0.7 μm），表明这是一个计算题。 | 知识层次: 题目需要应用基本的能带隙与波长转换公式（E=hc/λ），并进行简单的数值计算，属于直接套用基本公式和简单计算的范畴。 | 难度: 在计算题中属于最简单难度，仅需直接应用单一公式（波长与能量的转换公式）进行计算，无需多步推导或组合公式。题目明确给出了能隙值，计算过程仅涉及基本单位换算和简单代数运算，属于该题型中最基础的计算类型。" + } +] \ No newline at end of file diff --git a/layer2/PGEE/code/step4_enhanced_classified_questions.json b/layer2/PGEE/code/step4_enhanced_classified_questions.json new file mode 100644 index 0000000..4079486 --- /dev/null +++ b/layer2/PGEE/code/step4_enhanced_classified_questions.json @@ -0,0 +1,54974 @@ +[ + { + "idx": 1, + "question": "What are the parameters used to quantitatively describe crystal structures?", + "answer": "Unit cell parameters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述晶体结构的定量描述参数，答案是一个概念性的简短回答而非计算或选择 | 知识层次: 题目考查对晶体结构定量描述参数的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对晶体结构基本参数的定义记忆，属于最基础的概念性知识。学生只需识别\"Unit cell parameters\"这一标准术语即可作答，无需任何解释或分析步骤，因此属于难度等级1。" + }, + { + "idx": 2, + "question": "What are the parameters used to qualitatively describe crystal structures?", + "answer": "Symmetry axes, symmetry center, crystal system, lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答，答案是一系列描述晶体结构的参数，而不是选择、判断或计算。 | 知识层次: 题目考查对晶体结构定性描述参数的基本概念记忆和理解，包括对称轴、对称中心、晶系和晶格等基础知识点，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶体结构的定性描述参数（对称轴、对称中心、晶系、晶格），属于基础概念的直接回忆，无需解释或复杂分析，符合等级1的基本定义简答标准。" + }, + { + "idx": 3, + "question": "According to the nature of bonding forces, what are the types of bonding interactions in crystals?", + "answer": "The bonding interactions in crystals can be classified into ionic bonds, covalent bonds, metallic bonds, van der Waals bonds, and hydrogen bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据键合力的性质分类晶体中的键合相互作用，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体中键合相互作用的基本分类，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需要识别晶体中键合作用的基本分类（离子键、共价键、金属键、范德华力和氢键）。题目不涉及概念解释或复杂体系阐述，仅考察对定义性知识的直接回忆，因此属于最低难度等级。" + }, + { + "idx": 4, + "question": "The intercepts of a crystal plane on the x, y, and z axes are a/3, b/2, and c, respectively. Determine the Miller indices of this crystal plane.", + "answer": "h:k:l=3:2:1, the Miller indices of this crystal plane are (321).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算晶体平面在x、y、z轴上的截距来确定Miller指数，需要应用公式和数值计算，最终得出具体数值结果(321)。 | 知识层次: 题目需要应用Miller指数的基本计算公式，通过给定的截距直接套用公式进行计算，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解Miller指数的基本概念和计算方法，但解题步骤相对直接，只需将截距倒数比转换为最小整数比即可得到答案。不需要复杂的推导或多步骤计算，因此难度等级为2。" + }, + { + "idx": 5, + "question": "What are the two types of voids in the closest packing of equal spheres?", + "answer": "The closest packing of equal spheres includes hexagonal close packing and face-centered cubic close packing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和描述两种类型的空隙，答案提供了文字解释和论述，没有选项或计算要求。 | 知识层次: 题目考查对等径球体最密堆积中空隙类型的基本概念记忆，属于定义和分类层面的基础知识点，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆两种最密堆积类型的名称（六方最密堆积和面心立方最密堆积），属于基础概念记忆层面的直接提问，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 6, + "question": "A crystal plane has intercepts of 2a, 3b, and 6c on the X, y, and z axes respectively. Find the Miller indices of this crystal plane.", + "answer": "h:k:1=2:3:6=3:2:1, the Miller indices of this crystal plane are (321).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Miller指数的计算步骤）来求解晶面的Miller指数，答案是一个具体的数值结果（321），属于典型的计算题特征。 | 知识层次: 题目需要应用Miller指数的基本计算公式，通过给定的截距进行简单计算即可得到结果，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解Miller指数的基本概念和计算方法，但解题步骤相对直接，只需根据给定的截距应用公式进行简单计算即可得出答案。不需要复杂的推理或多步骤的公式组合，因此在选择题型内属于等级2难度。" + }, + { + "idx": 7, + "question": "What are the characteristics of covalent bonds?", + "answer": "The characteristics of covalent bonds are directionality and saturation, and the bonding force is also very strong.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释共价键的特性，答案以文字论述的形式给出，没有选项、判断或计算要求 | 知识层次: 题目考查共价键的基本特性（方向性和饱和性）的记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目要求考生不仅记忆共价键的基本定义，还需要理解并描述其特性（方向性和饱和性）以及键的强度。这超出了简单的定义回忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。因此属于概念解释和描述的中等难度。" + }, + { + "idx": 8, + "question": "What are the characteristics of metallic bonds?", + "answer": "Metallic bonds are non-directional and non-saturated covalent bonds, where the binding force is the electrostatic Coulomb force between ions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属键的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查金属键的基本特性，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解并记忆金属键的基本特性（非方向性和非饱和性共价键），以及其作用力本质（离子间的静电库仑力）。虽然涉及多个概念，但都属于基础概念记忆层次，不需要复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 9, + "question": "Calculate the number of atoms in a face-centered cubic unit cell", + "answer": "Number of atoms 4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算面心立方晶胞中的原子数），答案是一个具体的数值（4），解答过程需要应用材料科学中的晶体结构知识进行计算。 | 知识层次: 题目要求计算面心立方晶胞中的原子数，这需要应用基本的晶体结构知识（面心立方晶胞的特点）和简单的数学计算（每个角原子和面心原子的贡献）。虽然需要理解晶胞结构的基本概念，但计算过程直接且不涉及多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用面心立方晶胞原子数的基本公式（4个原子），无需任何额外计算或概念组合。属于单一公式直接应用的等级1难度。" + }, + { + "idx": 10, + "question": "What are the characteristics of hydrogen bonds?", + "answer": "A hydrogen bond is a bond formed between two atoms with relatively high electronegativity, and it possesses saturation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释氢键的特性，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查氢键的基本定义和特性，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆氢键的基本定义和特性，属于基础概念记忆层次。正确选项直接描述了氢键的形成条件和饱和性，无需复杂推理或概念间的比较分析。因此，在选择题型内属于基本定义简答的难度等级。" + }, + { + "idx": 11, + "question": "What are the characteristics of van der Waals bonds?", + "answer": "Van der Waals bonds are formed through molecular forces, and the molecular forces are very weak.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释van der Waals bonds的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对范德华键基本特征的定义和记忆，属于基础概念的理解层面 | 难度: 在选择题型中，该题目仅要求记忆和识别范德华键的基本定义和特征，属于基础概念记忆层次。正确选项直接描述了范德华键的形成方式和强度，无需复杂推理或概念间的比较分析，因此属于最简单的难度等级。" + }, + { + "idx": 12, + "question": "How many tetrahedral voids and octahedral voids are there around a sphere?", + "answer": "There are 8 tetrahedral voids and 6 octahedral voids around a sphere.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述四面体空隙和八面体空隙的数量，答案以文字形式给出，没有涉及计算或选择。 | 知识层次: 题目考查对晶体结构中四面体空隙和八面体空隙数量的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求记忆晶体结构中四面体空隙和八面体空隙的数量，不需要解释或分析概念，属于最基础的概念记忆层次。" + }, + { + "idx": 13, + "question": "When n equal-sized spheres are closely packed, how many tetrahedral voids and octahedral voids can be formed?", + "answer": "When n equal-sized spheres are closely packed, 2n tetrahedral voids and n octahedral voids can be formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述在紧密堆积情况下形成的四面体空隙和八面体空隙的数量，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对紧密堆积中空隙类型和数量的基本概念记忆，属于定义和基本原理的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生掌握紧密堆积中四面体空隙和八面体空隙的数量关系，这比单纯记忆定义或分类要复杂一些。题目要求考生理解并应用基本原理，而不仅仅是简单的定义回忆。因此，在选择题型内，该题目属于等级2的难度。" + }, + { + "idx": 14, + "question": "What are the characteristics of ionic bonds?", + "answer": "The characteristics of ionic bonds are the absence of directionality and saturation, with very strong bonding forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释离子键的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对离子键基本特性的记忆和理解，属于基础概念层面的知识，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项要求考生不仅知道离子键的基本定义，还需要理解其特性（如无方向性和无饱和性）以及较强的键合力。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 15, + "question": "Calculate the coordination number in a face-centered cubic unit cell", + "answer": "Coordination number 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算面心立方晶胞中的配位数，需要通过数值计算和晶体学知识来得出具体数值（6），属于需要应用公式和计算的问题类型。 | 知识层次: 题目要求计算面心立方晶胞的配位数，这需要应用基本的晶体结构知识，属于基本公式应用和简单计算的范畴。虽然需要理解配位数的概念，但计算过程直接且单一，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算面心立方晶胞的配位数，这是一个基础概念，只需直接应用已知的配位数数值（对于面心立方结构为12）即可得出答案。虽然正确选项给出的是错误的配位数（应为12而非6），但题目本身的解题过程仅涉及记忆和直接应用单一知识点，无需复杂计算或多步骤推理。" + }, + { + "idx": 16, + "question": "How are unequal-sized spheres packed?", + "answer": "In the close packing of unequal-sized spheres, it can be considered that the larger spheres are first closely packed as equal-sized spheres, and then the smaller spheres are filled into the gaps according to their sizes. Slightly larger small spheres fill the octahedral voids, while slightly smaller small spheres fill the tetrahedral voids, forming the close packing of unequal-sized spheres.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对不等径球体的紧密堆积方式进行文字解释和论述，答案提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目考查的是对不等径球体紧密堆积的基本概念和原理的理解，属于基础概念的记忆和解释，不需要复杂的计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解并描述不等径球体的紧密堆积方式，包括大球体的紧密堆积和小球体填充空隙的具体情况（八面体空隙和四面体空隙）。这比单纯记忆定义或分类（等级1）要求更高的概念解释能力，但尚未达到复杂概念体系阐述（等级3）的深度。" + }, + { + "idx": 17, + "question": "Write the coordinates of all nodes on the unit parallelepiped of the face-centered cubic lattice.", + "answer": "All nodes on the unit parallelepiped of the face-centered cubic lattice are: (000), (001), (100), (101), (110), (010), (011), (111), (1/2 0 1/2), (0 1/2 1/2), (1/2 1/2 0), (1 1/2 1/2), (1/2 1 1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出面心立方晶格单位平行六面体上所有节点的坐标，答案需要列举具体的坐标点，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目考查对面心立方晶格单位平行六面体节点坐标的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求记忆面心立方晶格单位平行六面体上所有节点的坐标，但需要掌握面心立方晶格的基本结构和节点分布规律。解题步骤相对简单，只需根据面心立方晶格的定义和对称性列举出所有节点坐标即可。然而，由于涉及多个坐标点的记忆和分类，对基础概念的记忆和理解有一定要求，因此难度略高于基本定义简答。" + }, + { + "idx": 18, + "question": "Calculate the packing coefficient in a face-centered cubic unit cell", + "answer": "Atomic packing coefficient APC=(4×(4/3)πr^3)/(2√2r)^3=74.05%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算面心立方晶胞的堆积系数），答案给出了具体的计算公式和计算结果（74.05%），符合计算题的特征 | 知识层次: 题目要求应用基本公式（球体积公式和立方体体积公式）进行直接计算，并套用到面心立方晶胞的具体结构中。虽然需要理解晶胞结构和原子堆积的概念，但计算过程相对直接，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解面心立方晶胞的结构和原子堆积系数的概念，但解题步骤相对直接，只需套用给定的公式进行计算即可。不需要多个公式的组合或复杂的推导过程，因此难度等级为2。" + }, + { + "idx": 19, + "question": "Calculate the number of atoms in a hexagonal close-packed unit cell", + "answer": "Number of atoms 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算六方密堆积晶胞中的原子数），答案是一个具体的数值结果（6），需要通过公式应用和计算过程来得出答案 | 知识层次: 题目要求计算六方密堆积晶胞中的原子数，这需要应用基本的晶体学知识和简单的数学计算。虽然需要理解六方密堆积的结构特点，但计算过程直接且不涉及多步推理或复杂分析，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（六方密堆积晶胞原子数计算公式）进行简单计算，无需复杂步骤或多公式组合。属于单一公式直接计算的等级1难度。" + }, + { + "idx": 20, + "question": "Calculate the packing coefficient in a hexagonal close-packed unit cell", + "answer": "Atomic packing coefficient APC=(6×(4/3)πa^3)/((3√3a^2/2)√8)=74.05%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以得出原子堆积系数（packing coefficient）的具体数值。答案是通过一系列数学运算得出的百分比结果，符合计算题的特征。 | 知识层次: 题目需要应用几何公式和原子堆积原理进行多步计算，涉及对六方密堆积结构的理解以及相关参数的关联分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解六方密堆积结构的基本概念，掌握原子半径与晶格参数的关系，并能够正确应用几何公式进行多步骤计算。虽然题目给出了计算公式，但需要考生具备综合分析能力才能正确理解并应用这些公式。相比简单的概念选择题，此题涉及的计算步骤和概念关联更为复杂，但尚未达到需要处理多变量或极端复杂计算的等级4难度。" + }, + { + "idx": 21, + "question": "Calculate the coordination number in a hexagonal close-packed unit cell", + "answer": "Coordination number 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方密堆积晶胞中的配位数，需要通过数值计算和公式应用来得出答案（Coordination number 6）。 | 知识层次: 题目要求计算六方密堆积晶胞中的配位数，这需要应用基本的晶体学知识，但计算过程相对直接，仅涉及基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式（六方密堆积的配位数固定为12），无需任何计算或复杂步骤。题目给出的正确选项\"Coordination number 6\"实际上是错误的（六方密堆积的正确配位数应为12），但即使如此，这仍属于最简单的记忆性题目类型，只需记住单一知识点即可作答。" + }, + { + "idx": 22, + "question": "According to the radius ratio relationship, what is the coordination number when Si4+ coordinates with O2-? Given rO2-=0.132nm, rSi4+=0.039nm.", + "answer": "For Si4+, r+/r-=0.039/0.132=0.295; based on the relationship between cation coordination number and cation-anion radius ratio, the coordination number is 4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的离子半径计算半径比，并应用半径比与配位数的关系来确定配位数。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用半径比关系进行简单计算，直接套用公式即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用半径比关系来确定配位数，但解题步骤相对直接，仅涉及单一公式的简单计算和直接套用。不需要复杂的推理或多步骤分析，因此难度等级为2。" + }, + { + "idx": 23, + "question": "Based on the radius ratio relationship, determine the coordination number of K+ when coordinated with O2-. Given rO2-=0.132nm and rK+=0.131nm.", + "answer": "For K+, r+/r-=0.131/0.132=0.99; according to the relationship between cation coordination number and the radius ratio of positive to negative ions, the coordination number is 8.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于半径比关系进行计算，以确定K+的配位数。解答过程中需要进行数值计算（r+/r- = 0.131/0.132 = 0.99）并应用半径比与配位数的关系规则。答案是一个具体的数值结果（配位数为8），符合计算题的特征。 | 知识层次: 题目涉及基本的半径比计算和直接套用协调数与半径比的关系表，属于基本公式应用和简单计算范畴，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用半径比公式进行计算，解题步骤简单且单一，属于最基础的难度等级。学生只需掌握半径比与配位数之间的基本关系，并进行简单的除法运算即可得出正确答案，无需复杂的分析或多步骤推理。" + }, + { + "idx": 24, + "question": "The metal magnesium atoms form a hexagonal close packing, and its density is measured to be $1.74\\\\mathrm{g/cm}^{3}$. Find the volume of its unit cell.", + "answer": "Let the volume of the unit cell be V, and the relative atomic mass be M. Then the unit cell volume $$V={\\\\frac{n M}{M_{0}\\\\rho}}={\\\\frac{6\\\\times24}{6.023\\\\times10^{23}\\\\times1.74}}=1.37\\\\times10^{-22}\\\\quad\\\\mathrm{\\\\quad\\\\quad}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解六方密堆积结构中原子的排列方式以及密度的定义，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用密度公式和单位晶胞体积的计算公式，但解题步骤相对直接，仅需套用给定公式并进行简单的数值计算。不需要多个公式的组合或复杂的逻辑推理，因此属于等级2难度。" + }, + { + "idx": 25, + "question": "In CaO, the unit cell parameter a=0.480 nm, and the anions and cations are in contact with each other. Find the radius of O2-. The radius of Ca2+ is known to be 0.107 nm.", + "answer": "In CaO, a=0.480 nm, and the anions and cations are in contact with each other. a=2(r+ + r-), therefore rO2-=(0.480 nm / 2) - 0.107 nm = 0.097 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出O2-的半径。解答过程涉及单位换算和简单的代数运算，符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要直接套用已知的半径和晶格参数关系公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。题目直接给出了单位晶胞参数和离子半径的关系公式（a=2(r+ + r-)），只需简单代入已知数值进行计算即可得出答案。虽然需要理解离子半径的概念和晶胞参数的关系，但解题步骤直接且无需复杂的推理或组合多个公式，因此在选择题型内属于等级2难度。" + }, + { + "idx": 26, + "question": "According to the closest packing principle, the higher the space utilization, the more stable the structure. The space utilization of the diamond structure is very low (only 34.01%), why is it also very stable?", + "answer": "The closest packing principle is based on the spherical symmetry and non-directionality of the electron cloud distribution of particles, so it only applies to typical ionic crystals and metallic crystals, and cannot be used to measure the stability of atomic crystals. In addition, the number of single bonds in diamond is 4, meaning each atom is surrounded by 4 single bonds (or atoms), forming a three-dimensional structure through covalent bonding of tetrahedra sharing vertices. Therefore, although the space utilization of the diamond structure is very low (only 34.01%), it is still very stable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么金刚石结构在空间利用率低的情况下仍然非常稳定，答案提供了详细的文字解释和论述，涉及电子云分布、晶体类型和共价键结构等概念，符合简答题的特征。 | 知识层次: 题目不仅要求理解最密堆积原理和空间利用率的基本概念，还需要分析其适用范围和局限性。此外，需要深入解释金刚石结构的稳定性机制，涉及共价键的方向性和三维网络结构的形成，这需要综合运用多个概念并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 27, + "question": "According to the radius ratio rule, what is the coordination number when Mg2+ coordinates with O2-? Given rO2-=0.132nm, rMg2+=0.078nm.", + "answer": "For Mg2+, r+/r-=0.078/0.132=0.59; based on the relationship between cation coordination number and cation-anion radius ratio, the coordination number is 6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的离子半径计算半径比，并应用半径比规则确定配位数。解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用半径比规则进行简单的数值计算，并直接套用已知的半径比与配位数关系表得出结果。虽然涉及基本概念的理解，但主要考察的是基本公式的直接应用和简单计算能力，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用半径比规则进行计算，但仅涉及单一公式的直接套用和简单除法运算，无需多个步骤或复杂分析。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 28, + "question": "In MgS, the unit cell parameter a=0.5201 nm, and the anions are in contact with each other. Calculate the radius of S2-.", + "answer": "In MgS, a=0.5201 nm, and the anions are in contact with each other, a=2√2 r-, thus rS2-=0.5201 nm / (2√2) = 0.177 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及单位晶胞参数和离子半径的计算，答案也是通过数学运算得出的具体数值。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过给定的晶胞参数和几何关系（a=2√2 r-）来计算离子半径，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（a=2√2 r-）进行计算，解题步骤简单且直接，无需多个公式组合或复杂分析。属于最基础的难度等级。" + }, + { + "idx": 29, + "question": "Calculate whether the valence of I- in CdI2 crystal is saturated?", + "answer": "In CdI2 crystal, the coordination number (CN) of Cd2+ is 6. I is connected to three Cd2+ on the same side, and the coordination number (CN) of I is 3. Therefore, CN ∑i(z+/CN)=1=1z−1, meaning the valence of I− is saturated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来判断I-在CdI2晶体中的价态是否饱和，答案提供了详细的解释和计算过程，符合简答题的特征。 | 知识层次: 题目需要理解配位数和价态饱和的概念，并进行多步计算和综合分析，涉及概念关联和中等程度的思维过程。 | 难度: 在选择题中属于较高难度，题目要求考生不仅要理解晶体结构中的配位数概念，还需要进行多步计算和综合分析。具体来说，考生需要：" + }, + { + "idx": 30, + "question": "Why is the transformation temperature between different series of quartz variants much higher than that between variants of the same series?", + "answer": "The transformation within the same series of quartz is a displacive transformation, which does not involve the breaking and rebuilding of bonds in the crystal structure, but only the adjustment of bond lengths and angles, requiring lower energy and being rapidly reversible. In contrast, transformations between different series are reconstructive, involving the breaking of old bonds and the formation of new ones, thus requiring higher energy and proceeding at a slower rate. Therefore, the transformation temperature between different series of quartz is much higher than that between variants of the same series.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释石英变体之间转化温度差异的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释石英变体间相变温度的差异，涉及位移型相变和重建型相变的机理分析，需要综合运用晶体结构、相变类型和能量变化等知识进行推理和解释，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅要理解石英变体之间的转变类型（位移型转变和重建型转变），还需要深入掌握这两种转变在晶体结构、键合状态和能量需求方面的本质区别。正确选项涉及复杂的晶体学机理分析，需要综合运用材料科学、热力学和动力学知识进行推理判断。这种在选择题中要求对复杂现象进行全面机理解释的题目，在选择题型内属于最高认知难度的考查类型。" + }, + { + "idx": 31, + "question": "In CaS, the unit cell parameter a=0.567 nm, and the anions and cations are in contact with each other. Calculate the radius of Ca2+. The radius of S2- is known to be 0.177 nm.", + "answer": "In CaS, a=0.567 nm, and the anions and cations are in contact with each other, a=2(r+ + r-), therefore rCa2+=(0.567 nm / 2) - 0.177 nm = 0.107 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式（a=2(r+ + r-)）来求解Ca2+的半径，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要直接套用已知的半径公式进行计算即可，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（a=2(r+ + r-)）进行简单计算即可得出答案，无需额外的概念理解或步骤组合。属于最基础的直接计算类型。" + }, + { + "idx": 32, + "question": "Compare the unit cell parameter values obtained from density calculations with those calculated from ionic radii.", + "answer": "Calculated from ionic radii: a=2(r₊+r₋)=0.414 nm ∴ a₀ < a", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较通过密度计算和离子半径计算得到的晶胞参数值，答案中涉及数值计算和公式应用（a=2(r₊+r₋)），并给出了具体的计算结果（0.414 nm）和比较结论（a₀ < a）。 | 知识层次: 题目需要进行多步计算（密度计算和离子半径计算），并需要对计算结果进行比较分析，涉及概念关联和综合分析能力 | 难度: 在选择题中属于中等偏上难度，需要理解离子半径与晶胞参数的关系，并进行多步计算和比较分析。题目要求将密度计算得到的晶胞参数与离子半径计算得到的参数进行比较，涉及多个概念的综合应用和计算步骤。虽然不涉及复杂多变量计算，但需要较强的综合分析能力。" + }, + { + "idx": 33, + "question": "In MgO, the unit cell parameter a=0.420 nm, and the anions and cations are in contact with each other. Calculate the radius of Mg2+. The radius of O2- is known to be 0.097 nm.", + "answer": "In MgO, a=0.420 nm, and the anions and cations are in contact with each other. a=2(r+ + r-), therefore rMg2+=(0.420 nm / 2) - 0.097 nm = 0.113 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Mg2+的半径，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要直接套用已知的半径关系和单位晶胞参数进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（a=2(r+ + r-)）进行计算，解题步骤简单明了，无需复杂的推理或多步骤操作。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 34, + "question": "According to the rules of ionic compound formation, when all octahedral interstitial sites are filled, what valence cations should be inserted in the interstitial sites? Please provide examples.", + "answer": "The ratio of cation to anion valences should be 1:1, such as NaCl.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释离子化合物形成规则，并提供例子，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对离子化合物形成规则的基本应用，需要理解八面体间隙填充的价态规则，并给出具体例子。虽然涉及一定的概念理解，但主要是直接应用基本原理，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用难度。题目直接考察对离子化合物形成规则的基本理解，只需套用已知的1:1价态比例规则即可选出正确答案。解题步骤简单明确，不需要复杂分析或计算，符合选择题型中对基本知识点直接应用的考查要求。" + }, + { + "idx": 35, + "question": "Lithium fluoride (LiF) has a NaCl-type structure, and its measured density is 2.6 g/cm³. Based on this data, calculate the unit cell parameter.", + "answer": "Assuming the volume of the unit cell is V and the relative atomic mass is M, for the NaCl-type structure, n=4. Then the unit cell volume V = (n M)/(N0ρ) = (4×26)/(6.023×10²³×2.6) = 6.64×10⁻²³ cm³. Therefore, the unit cell parameter: a₀ = ³√V = 0.405 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的密度和晶体结构类型，通过数值计算和公式应用（如单位晶胞体积公式）来求解晶胞参数。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的密度和晶体结构类型计算晶胞参数。虽然需要理解NaCl型结构的基本特征和单位晶胞中的原子数，但整体上是一个直接套用公式的计算过程，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解NaCl型结构的基本概念和密度计算公式，但解题步骤相对直接，仅需套用单一公式（V = (n M)/(N0ρ)）并进行简单计算即可得出结果。不需要多个公式组合或复杂的概念分析，因此在选择题型内属于较低难度。" + }, + { + "idx": 36, + "question": "Calculate the ratio of octahedral void number to O2- number", + "answer": "The ratio of octahedral void number to O2- number is 1:1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算八面体空隙数与O2-离子数的比例），答案是一个具体的数值比例（1:1），这符合计算题的特征。 | 知识层次: 题目涉及基本的晶体结构概念（八面体空隙和氧离子数量）和简单的比例计算，属于直接套用基本公式和概念的应用层面，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行计算，属于单一公式直接计算的难度等级。题目明确给出了正确选项，且解题步骤简单，无需复杂的推理或多步骤计算。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 37, + "question": "Calculate the ratio of the number of tetrahedral voids to the number of O2- ions", + "answer": "The ratio of the number of tetrahedral voids to the number of O2- ions is 2:1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算四面体空隙与O2-离子的数量比），答案给出了具体的计算结果（2:1），这符合计算题的特征 | 知识层次: 题目要求计算四面体空隙与O2-离子数量的比值，这属于基本公式应用和简单计算，直接套用晶体结构中的空隙比例知识即可得出结果，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接应用基本公式（四面体空隙数与阴离子数的比例关系）进行简单计算，无需复杂推理或多步骤操作。属于单一公式直接计算的类型，因此难度等级为1。" + }, + { + "idx": 38, + "question": "MgO and CaO both belong to the NaCl-type structure, but when they react with water, CaO is more reactive than MgO. Please explain.", + "answer": "Because ${r_{i\\\\parallel_{g}}}^{2+}$ and ${r_{C a}}^{21}$ are different, $r_{\\\\tt C a2+}>r_{\\\\tt B_{\\\\tt B}2+}$, making the structure of CaO looser than that of $\\\\mathrm{Mg0}$, allowing $\\\\mathrm{H}_{2}\\\\mathrm{0}$ to enter more easily, hence more reactive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释MgO和CaO反应活性的差异，答案提供了详细的文字解释和论述，涉及离子半径差异和结构松紧度对反应性的影响，符合简答题的特征。 | 知识层次: 题目要求解释MgO和CaO在反应活性上的差异，涉及离子半径对晶体结构的影响以及与水反应机理的分析。需要综合运用晶体结构知识、离子半径效应和化学反应活性等多方面知识进行推理和解释，思维过程较为深入。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解MgO和CaO的晶体结构差异，还需要分析离子半径对结构紧密度的影响，并进一步推导出水分子进入晶格的难易程度与反应活性的关系。这需要综合运用晶体结构知识、离子半径效应以及化学反应机理的解释能力，属于复杂现象全面分析的层次。选择题型中，此类题目对知识深度和推理能力的要求较高，因此评为等级5。" + }, + { + "idx": 39, + "question": "Calculate whether the valence of O2- in CaTiO3 crystal is saturated?", + "answer": "In CaTiO3 crystal, the coordination number of Ca2+ CN=12, the coordination number of Ti4+ CN=6, and the coordination number of O2- CN=6, so CN ∑i(z+/CN)=2=|z−|, that is, the valence of O2- is saturated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来判断O2-在CaTiO3晶体中的价态是否饱和，答案提供了详细的解释和计算过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解晶体结构中离子的配位数和价态饱和的概念，并进行多步计算和综合分析，涉及多个知识点的关联和简单推理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求计算O2-在CaTiO3晶体中的价态是否饱和，涉及多个离子的配位数计算和价态平衡的综合分析。虽然解题步骤较为明确，但需要掌握晶体化学中的配位数概念和价态平衡原理，并进行多步计算和概念关联。在选择题型中，这种题目要求考生具备一定的综合分析能力，但不需要进行多角度或深度关联性分析，因此属于等级3难度。" + }, + { + "idx": 40, + "question": "According to the rules of ionic valence, when all tetrahedral interstitial sites are filled, what valence cations should be filled in the interstitial sites, and provide an example.", + "answer": "The ratio of cation to anion valences should be 1:2, such as CaF2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释离子价规则并举例说明，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求根据离子价规则推断间隙位填充的阳离子价态，并举例说明。这需要理解离子价规则并应用到具体晶体结构中，涉及多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握离子价态的基本规则，还需要理解四面体间隙填充的条件，并能进行多步计算和概念关联。此外，题目还要求考生能够举出具体的例子（如CaF2），这需要综合分析和应用知识的能力。这些要求超出了基础记忆和简单应用，属于中等应用层次的多角度分析论述。" + }, + { + "idx": 41, + "question": "According to the电价规则, when half of the tetrahedral interstitial sites are filled, what valency cations should be inserted into the interstitial sites, and provide an example to illustrate.", + "answer": "The ratio of cation to anion valency should be 1:1, such as ZnS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释电价规则并举例说明，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解电价规则并应用到具体情境中，涉及多步推理和概念关联，如确定填隙位置与离子价态的关系，并举例说明。 | 难度: 在选择题中属于中等难度，题目要求理解电价规则并能够应用该规则进行多步计算和概念关联。需要综合分析填充一半四面体间隙位时阳离子的价态选择，并给出具体实例（如ZnS）来说明。虽然涉及多个概念和步骤，但在选择题型中通过选项可以辅助判断，因此难度适中。" + }, + { + "idx": 42, + "question": "According to the电价规则, when half of the octahedral interstitial sites are filled, what valence cations should be inserted into the interstices, and provide examples to illustrate.", + "answer": "The valence ratio of anions to cations should be 1:2, such as TiO2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释电价规则并举例说明，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解电价规则并应用到具体情境中，涉及多步推理和概念关联，如计算价态比例并举例说明，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解电价规则、间隙位置填充比例以及阴阳离子价态比等多个概念，并进行综合分析。题目要求考生不仅掌握基本概念，还要能够应用这些概念进行多步计算和关联分析，如通过TiO2的例子来说明1:2的价态比。这比单纯记忆知识点或简单应用要复杂，但相比需要多角度分析或深度关联性分析的题目，其难度适中。" + }, + { + "idx": 43, + "question": "According to the radius ratio relationship, what is the coordination number when Al3+ coordinates with O2-? Given rO2-=0.132nm, rAl3+=0.057nm.", + "answer": "For Al3+, r+/r-=0.057/0.132=0.43; based on the relationship between cation coordination number and the radius ratio of positive to negative ions, the coordination number is 6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径进行数值计算（r+/r-比值），并根据半径比关系确定配位数。解答过程涉及具体计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及半径比的计算和基本配位数关系的直接应用，属于基本公式套用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需应用半径比公式（r+/r-）进行简单计算，并根据给定的半径比直接查表或记忆对应的配位数。无需多个公式组合或复杂推理，解题步骤简单直接，属于基础知识的简单应用。" + }, + { + "idx": 44, + "question": "Barium titanate is an important ferroelectric ceramic, and its crystal type is perovskite structure. What lattice does it belong to?", + "answer": "It belongs to the cubic crystal system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个简短的陈述，而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查对钛酸钡晶体结构类型的基础概念记忆，仅需回答其所属晶系，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即钡钛矿的晶体结构类型。题目直接给出了正确选项，无需进行复杂的分析或推理，属于最基本的知识点掌握要求。" + }, + { + "idx": 45, + "question": "Barium titanate is an important ferroelectric ceramic with a perovskite crystal structure. What are the coordination numbers of the ions in this structure?", + "answer": "The coordination numbers of Ba²⁺, Ti⁴⁺, and O²⁻ are 12, 6, and 6, respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释离子在晶体结构中的配位数，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对钙钛矿晶体结构中离子配位数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即Barium titanate晶体结构中各离子的配位数。不需要进行复杂的分析或推理，只需直接回忆相关知识即可选择正确答案。因此，属于基本定义简答的难度等级。" + }, + { + "idx": 46, + "question": "What is the basis for the classification of silicate crystals?", + "answer": "Silicate crystals are mainly classified based on the arrangement and bonding manner of [Si04] in the structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释硅酸盐晶体的分类基础，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对硅酸盐晶体分类基础概念的记忆和理解，主要涉及硅氧四面体[Si04]在结构中的排列和键合方式这一基本原理。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别硅酸盐晶体分类的基本依据，即[Si04]的排列和键合方式。这属于基础概念记忆层次，无需复杂推理或分析，解题步骤简单直接。" + }, + { + "idx": 47, + "question": "Into which categories can silicate crystals be classified?", + "answer": "Silicate crystals can be specifically classified into five categories: island, group, chain, layer, and framework.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对硅酸盐晶体进行分类，并需要文字解释和论述，答案提供了具体的分类名称，符合简答题的特征 | 知识层次: 题目考查对硅酸盐晶体分类的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆硅酸盐晶体的五种基本分类（岛状、群状、链状、层状和架状），属于基础概念的直接回忆。不需要解释或分析，只需识别正确选项，因此属于最简单的难度等级。" + }, + { + "idx": 48, + "question": "What are the structural characteristics of island silicates?", + "answer": "The structural characteristics of island silicates: [Si04] shares 0 O2-, the shape is tetrahedral, the complex anion group is [Si04], and the Si:O ratio is 1:4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释岛状硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对岛状硅酸盐结构特征的基本概念记忆和理解，包括[Si04]的共享氧离子数、形状、复杂阴离子团和Si:O比例等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求回答岛状硅酸盐的结构特征，正确选项直接给出了具体的结构特征描述，包括[Si04]的共享氧离子数量、形状、复杂阴离子基团以及Si:O比例。这些信息都是基础概念记忆层面的知识，不需要复杂的分析或推理，只需对定义和基本原理进行记忆即可回答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 49, + "question": "MnS has three polycrystalline forms, two with the NaCl-type structure and one with the cubic ZnS-type structure. When transforming from the cubic ZnS-type structure to the NaCl-type structure, what is the percentage change in volume? Given that for CN=6, ${r_{\\\\mathrm{{Mn}}}}^{2+}=0.08\\\\mathrm{{nm}}$, $\\\\ensuremath{r_{\\\\mathrm{s}}}^{2-}=0.184\\\\mathrm{nm}$; and for CN=4, ${r_{\\\\mathrm{Mn}}}^{2+}\\\\mathrm{=}0.073\\\\mathrm{nm}$, ${r_{\\\\mathrm{S}}}^{2-}{=}0.167\\\\mathrm{nm}$.", + "answer": "For the cubic ZnS-type structure: $a1={\\\\frac{4}{\\\\sqrt{2}}}r_{S}^{2-}={\\\\frac{4}{\\\\sqrt{2}}}\\\\times0.167=0.472\\\\mathrm{nm}$. For the NaCl-type structure: $a_{2}=2(r_{\\\\mathrm{Mn}}^{2+}+r_{\\\\mathrm{S}}^{2-})=2(0.08+0.184)=0.384\\\\mathrm{nm}$. Thus, the volume change is: $V={\\\\frac{a1^{3}-a2^{3}}{a1^{3}}}={\\\\frac{0.472^{3}-0.384^{3}}{0.472^{3}}}=46.15\\\\%$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的离子半径数据计算体积变化的百分比，涉及具体的数值计算和公式应用。答案展示了详细的计算步骤和最终结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶体结构参数的推导和体积变化的计算，涉及不同配位数下离子半径的应用，需要综合分析晶体结构转变对体积的影响。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构转变的概念，掌握配位数对离子半径的影响，并进行多步计算（包括晶格参数计算和体积变化百分比计算）。虽然题目提供了所有必要数据，但解题过程涉及多个关联步骤和公式应用，对学生的综合分析能力有一定要求。" + }, + { + "idx": 50, + "question": "Barium titanate is an important ferroelectric ceramic with a perovskite crystal structure. Does this structure obey Pauling's rules? Please discuss in detail.", + "answer": "This structure obeys Pauling's rules. Pauling's first rule—the coordination polyhedron rule: rO²⁻=0.132nm, rTi⁴⁺=0.064nm, rBa²⁺=0.143nm. For TiO₆, rTi⁴⁺/rO²⁻=0.064/0.132=0.485, coordination number is 6. For BaO₁₂, rBa²⁺/rO²⁻=0.143/0.132=1.083, coordination number is 12. This complies with Pauling's first rule. Pauling's second rule—the electrostatic valence rule: the anion charge Z=∑(zi⁺/CNi), thus the O²⁻ ion charge=(2/12)×4+(4/6)×2=2, which equals the O²⁻ ion charge, so it complies with Pauling's second rule. Furthermore, according to the perovskite-type structure, its coordination polyhedra do not share edges or faces, and the structural situation also complies with Pauling's fourth rule—the rule of different polyhedron connections and Pauling's fifth rule—the parsimony rule. Therefore, the perovskite structure obeys Pauling's rules.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细讨论钛酸钡的钙钛矿晶体结构是否遵循鲍林规则，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细讨论钛酸钡的钙钛矿晶体结构是否符合鲍林规则，涉及多个鲍林规则的应用和解释，需要综合运用晶体化学知识进行推理分析，思维过程较为深入。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅需要掌握Pauling规则的具体内容，还需要能够将这些规则应用到具体的晶体结构（钛酸钡的钙钛矿结构）中进行分析。解题步骤包括计算离子半径比、确定配位数、验证静电价规则，以及评估多面体连接方式等多个复杂步骤。此外，题目还要求考生能够综合运用这些规则进行全面的机理解释，这超出了单纯记忆或简单应用的层次，属于复杂现象全面分析的范畴。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 51, + "question": "The chemical handbook lists the density of NH4Cl as 1.5 g/cm3. X-ray data indicate that NH4Cl has two crystal structures: one is the NaCl-type structure with a=0.726 nm, and the other is the CsCl structure with a=0.387 nm. To which crystal type does the above density value belong? (The NH4+ ion occupies the crystal lattice as a single unit).", + "answer": "Solution: If NH4Cl has the NaCl structure, the density can be calculated using the formula: rho = n / (N_A * V) * M. Thus, the calculation yields: rho = 4 / (6.02 * 10^23) * 52.5 / (0.726 * 10^-7)^3 = 0.912 g/cm3. If NH4Cl has the CsCl structure, the density can be calculated using the formula: rho = n / (N_A * V) * M. Thus, the calculation yields: rho = 1 / (6.02 * 10^23) * 52.5 / (0.387 * 10^-7)^3 = 1.505 g/cm3. The calculation shows that the density of the NaCl-type NH4Cl is close to the value given in the chemical handbook, so the density corresponds to the NaCl crystal type.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定密度对应的晶体类型，解答过程中涉及到了密度的计算公式和具体数值的代入计算。 | 知识层次: 题目需要进行多步计算，涉及晶体结构、密度公式的应用，以及不同晶体结构的比较分析。虽然计算过程相对直接，但需要理解晶体结构类型和密度计算的关系，并进行综合分析以确定正确的晶体类型。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构的概念，掌握密度计算公式，并进行多步计算和比较分析。虽然题目提供了部分数据，但需要考生自行选择正确的计算路径并验证结果，涉及多个知识点的综合应用。" + }, + { + "idx": 52, + "question": "What are the structural characteristics of chain silicates?", + "answer": "The structural characteristics of chain silicates: [Si04] shares 2 or 3 O2-, shapes include single chains and double chains, the complex anion groups are [Si206]4 and [Si40], with Si:O ratios of 1:3 and 4:11 respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释链状硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对链状硅酸盐结构特征的基本概念记忆和理解，包括其组成单元、形状和比例等基础知识点，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个结构特征（如[Si04]共享氧离子、单链和双链形状、复杂阴离子基团及其Si:O比例），但这些都属于基础概念记忆范畴。选择题型允许通过选项提示来辅助回忆，降低了纯记忆的难度。但题目要求同时掌握多个相关特征，比单纯记忆单一定义（等级1）要复杂，因此属于等级2。" + }, + { + "idx": 54, + "question": "What are the structural characteristics of layered silicates?", + "answer": "The structural characteristics of layered silicates: [Si04] shares 3 O2-, the shape is a planar layer, the complex anion group is [Si4010], and the Si:O ratio is 4:10.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释层状硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对层状硅酸盐结构特征的基本概念记忆和理解，包括硅氧四面体的共享氧原子数量、平面层形状、复杂阴离子团组成以及硅氧比例等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确回忆并匹配多个结构特征（如[Si04]的共享氧数量、平面层形状、复杂阴离子组和Si:O比例）。这比单纯记忆单一定义（等级1）要求更高，但不需要进行复杂的概念体系阐述或分析（等级3）。" + }, + { + "idx": 55, + "question": "What are the structural characteristics of framework silicates?", + "answer": "The structural characteristics of framework silicates: [SiO4] shares 4 O2-, forming a skeleton [(AlxSi4)O], with the complex anion group being [SiO4]4, and the Si:O ratio is 1:4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释框架硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对硅酸盐结构基本特征的定义和记忆，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并记忆框架硅酸盐的结构特征，包括[SiO4]的共享氧原子数量、骨架结构[(AlxSi4)O]、复杂阴离子组[SiO4]4以及Si:O的比例。这些知识点需要一定的记忆和理解，但不需要复杂的分析或比较。因此，在选择题型中属于等级2的难度。" + }, + { + "idx": 56, + "question": "What are the characteristics of silicate crystal structures? How are their chemical formulas characterized?", + "answer": "Silicate crystal structures are very complex, but different structures share the following common characteristics: (1) The $\\\\mathrm{Si}^{4+}$ ions in the structure are located at the center of tetrahedra formed by $\\\\mathrm{O}^{2-}$ ions, constituting the basic structural unit of silicate crystals, the $[\\\\mathrm{SiO}_{4}]$ tetrahedron. The Si-O-Si bond forms a bent line with varying angles, generally around $145^{\\\\circ}$. (2) Each vertex of the $[\\\\mathrm{SiO}_{4}]$ tetrahedron, i.e., the $\\\\mathrm{O}^{2-}$ ion, can be shared by at most two $[\\\\mathrm{SiO}_{4}]$ tetrahedra. (3) Two adjacent $[\\\\mathrm{SiO}_{4}]$ tetrahedra can only share vertices and cannot share edges or faces. (4) The $\\\\mathrm{Si}^{4+}$ ion at the center of the $[\\\\mathrm{SiO}_{4}]$ tetrahedron can be partially replaced by $\\\\mathrm{Al}^{3+}$ ions. This substitution, known as isomorphous replacement, does not significantly alter the structure itself but greatly changes the properties of the crystal, offering possibilities for material modification. The chemical formulas of silicates are primarily characterized by the following two methods: (1) Oxide representation method All oxides constituting the silicate crystal are written out in a certain proportion and order, starting with monovalent alkali metal oxides, followed by divalent and trivalent metal oxides, and finally $\\\\mathrm{SiO}_{2}$. (2) Inorganic complex salt representation method All ions constituting the silicate crystal are written out in a certain proportion and order, with the relevant complex anions enclosed in brackets. The order starts with monovalent and divalent metal ions, followed by $\\\\mathrm{Al}^{3+}$ ions and $\\\\mathrm{Si}^{4+}$ ions, and finally $\\\\mathrm{O}^{2-}$ ions and $\\\\mathrm{OH}^{-}$ ions. The advantage of the oxide representation method is that it clearly reflects the chemical composition of the crystal, allowing for laboratory synthesis based on this formulation. The inorganic complex salt method, on the other hand, provides a more intuitive reflection of the structural type of the crystal, enabling predictions about its structure and properties. The two representation methods can be converted into each other.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释硅酸盐晶体结构的特征及其化学式的表征方法，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目不仅要求记忆和理解硅酸盐晶体结构的基本特征，还需要解释其化学式的表征方法，涉及多步概念关联和综合分析。虽然不涉及复杂的计算或创新设计，但需要对多个知识点进行整合和解释，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握硅酸盐晶体结构的基本特征，还需要理解其化学式的两种表征方法及其优缺点。题目涉及多个知识点的综合应用，包括硅氧四面体的结构特点、同晶替代现象以及化学式的表示方法转换。此外，考生需要能够将这些概念联系起来，进行多角度的分析和论述，这超出了简单的记忆或单一概念的应用，属于中等应用层次中的较高要求。" + }, + { + "idx": 57, + "question": "What type of silicate structure does Mg2[SiO4] belong to?", + "answer": "Island", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释Mg2[SiO4]属于哪种硅酸盐结构，答案需要文字描述（\"Island\"），而不是从选项中选择或简单判断对错，也不需要计算。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，只需识别Mg2[SiO4]属于孤岛状硅酸盐结构，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求识别Mg2[SiO4]所属的硅酸盐结构类型，属于基础概念记忆层次。正确选项\"Island\"是硅酸盐结构分类中最基本的一种，无需复杂推理或概念比较，只需直接回忆相关定义即可作答。" + }, + { + "idx": 58, + "question": "What type of silicate structure does K[AlSi3O8] belong to?", + "answer": "Framework", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别并描述硅酸盐结构类型，需要文字解释和论述，而不是从选项中选择或简单判断对错 | 知识层次: 题目考查对硅酸盐结构类型的基本分类记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求识别K[AlSi3O8]所属的硅酸盐结构类型（Framework），属于基础概念记忆层次。题目直接考察对硅酸盐结构分类的定义记忆，无需复杂推理或概念关联，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 59, + "question": "What type of silicate structure does CaMg[Si2O6] belong to?", + "answer": "Single chain", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答关于硅酸盐结构类型的问题，答案形式为简短的文字描述而非选择或计算。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆，只需识别CaMg[Si2O6]属于单链结构即可，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（硅酸盐结构分类），但需要考生准确记忆并区分不同类型的硅酸盐结构（如单链、双链、层状等）。解题步骤相对简单，只需识别化学式对应的结构类型，但要求对硅酸盐结构分类有清晰的记忆。相比纯粹的定义简答（等级1），此题需要更具体的分类知识，但不需要复杂的概念体系阐述（等级3）。" + }, + { + "idx": 60, + "question": "What type of silicate structure does Mg3[Si4O10](OH)2 belong to?", + "answer": "Layered (double-chain)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Mg3[Si4O10](OH)2所属的硅酸盐结构类型，需要文字描述和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（硅酸盐结构分类），但需要考生准确记忆并区分不同类型的硅酸盐结构（如层状、双链等）。相比等级1的直接定义简答，该题目要求考生对硅酸盐结构分类有更深入的理解和记忆，属于概念解释和描述层次的难度。" + }, + { + "idx": 61, + "question": "What type of silicate structure does Ca2Al[AlSiO7] belong to?", + "answer": "Group (double tetrahedron)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求识别并描述硅酸盐结构类型，需要文字解释和论述，答案形式为特定结构类型的名称而非选择或计算 | 知识层次: 题目考查对硅酸盐结构分类的基础概念记忆，只需识别Ca2Al[AlSiO7]属于双四面体结构类型，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（硅酸盐结构分类），但需要考生准确识别特定化学式对应的硅酸盐结构类型（双四面体结构）。这比单纯记忆定义（等级1）要求更高，需要将化学式与结构分类对应起来，属于概念解释和描述的层次。但不需要进行复杂的概念体系分析或推导（等级3），因此评为等级2。" + }, + { + "idx": 62, + "question": "Based on the projection diagram of Mg2[SiO4] on the (100) plane, answer: Is the valence of O2- saturated?", + "answer": "O2- is bonded to 3 [Mg] and 1 [SiO], N∑i(z+/CN)=2=1z-1, so O2- is saturated", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于投影图分析O2-的价态是否饱和，答案需要文字解释和论述，涉及化学键和配位数的分析，而非简单的选择、判断或计算。 | 知识层次: 题目需要理解晶体结构投影图，并应用配位数和电价规则进行多步计算和综合分析，涉及概念关联和中等复杂度的推理过程。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 63, + "question": "Based on the projection of Mg2[SiO4] on the (100) plane, answer: what is the number of molecules in the unit cell?", + "answer": "z=4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于投影计算晶胞中的分子数量，需要通过结构分析和数值计算得出具体数值（z=4），属于需要应用晶体学知识和计算方法的计算题。 | 知识层次: 题目需要基于晶体投影进行多步计算，涉及晶体结构分析和单位晶胞分子数的确定，需要概念关联和综合分析能力 | 难度: 在选择题中属于中等偏上难度，需要理解晶体投影、单位细胞分子数计算等概念，并进行多步骤的空间想象和综合分析。虽然题目提供了正确选项，但解题过程涉及对晶体结构的理解和投影分析，属于综合性计算问题。" + }, + { + "idx": 64, + "question": "Graphite, talc, and kaolinite have layered structures. Explain the differences in the structure of graphite and the resulting differences in properties.", + "answer": "Compared to talc and kaolinite, in graphite, the carbon atoms in the same layer undergo SP2 hybridization, forming large π bonds, and each layer has a hexagonal network structure. Due to the large interlayer gaps, electrons can move within the same layer, enabling electrical conductivity. The layers are held together by intermolecular forces, making graphite relatively soft.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释石墨的结构差异及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释石墨与滑石、高岭石在结构上的差异及其对性能的影响，涉及SP2杂化、π键形成、导电性机制等复杂概念的综合运用和推理分析。需要深入理解材料的结构-性能关系，并进行多层次的比较和解释。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解石墨、滑石和高岭石的层状结构，还需要深入分析石墨中碳原子的SP2杂化、大π键的形成以及由此导致的导电性和软性等特性。这需要考生具备扎实的材料科学基础，能够综合运用多个概念进行推理分析，并解释其中的机理。因此，在选择题型内，该题目属于机理深度解释的难度等级。" + }, + { + "idx": 65, + "question": "Based on the projection diagram of Mg2[SiO4] on the (100) plane, answer: What fraction of the tetrahedral and octahedral voids are occupied by Si4+ and Mg2+?", + "answer": "Si4+ occupies tetrahedral voids = 1/8, Mg2+ occupies octahedral voids = 1/2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于投影图分析并回答特定问题，答案需要具体描述占据空隙的比例，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求基于投影图分析晶体结构中四面体和八面体空隙的占据情况，涉及多步计算和概念关联，需要综合分析晶体结构知识和空间几何关系。 | 难度: 在选择题型中，该题目属于较高难度，需要综合理解晶体结构、投影图分析、空隙占有率计算等多个概念，并进行多步计算和综合分析。题目不仅要求掌握基本的晶体学知识，还需要能够将不同概念关联起来，进行较为复杂的推理和计算。" + }, + { + "idx": 66, + "question": "Describe the basic types of dislocations and their characteristics.", + "answer": "There are two main types of dislocations: edge dislocation and screw dislocation. Characteristics of edge dislocation: the slip direction is perpendicular to the dislocation line, denoted by the symbol ⊥, with an extra half-plane of atoms. Characteristics of screw dislocation: the slip direction is parallel to the dislocation line, the plane perpendicular to the dislocation line is not flat, presenting a spiral shape, hence called screw dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述位错的基本类型及其特征，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的文字描述，符合简答题的特点。 | 知识层次: 题目考查对位错基本类型（刃位错和螺位错）及其特征的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生描述两种基本位错类型及其特征，属于概念解释和描述的层次。虽然需要记忆和区分两种位错的定义和特点，但不需要进行复杂的分析或比较，因此属于中等难度。" + }, + { + "idx": 68, + "question": "In silicate crystals, why can Al3+ partially replace Si4+ in the silicon-oxygen framework?", + "answer": "Al3+ can form [AlO4]5- with O2-. Al3+ and Si4+ are in the second period and have similar properties, making it easy for Al3+ to enter the silicate crystal structure and undergo isomorphous substitution with Si4+. Due to compliance with Pauling's rules, only partial substitution is possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al3+可以部分替代Si4+的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释Al3+在硅酸盐晶体中部分替代Si4+的原因，涉及[AlO4]5-的形成、Al3+和Si4+的性质相似性、同晶替代以及Pauling规则的遵守。这需要综合运用晶体化学、离子替代机制和结构规则等多方面知识，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 69, + "question": "What is the effect of Al3+ replacing Si4+ on the composition of silicates?", + "answer": "The replacement of Si4+ by Al3+ is a partial substitution. When Al3+ replaces Si4+, the structural units [AlSiO4][AlSiO5] lose electrical neutrality, resulting in excess negative charge. To maintain electrical neutrality, some larger cations with lower charges such as K+, Ca2+, and Ba2+ will enter the structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al3+替换Si4+对硅酸盐组成的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及硅酸盐中Al3+替代Si4+的效应，需要理解离子替代对结构电中性的影响，并关联到补偿阳离子的引入。这需要多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生理解Al3+取代Si4+的基本概念，还需要综合分析这种取代对硅酸盐结构电中性的影响，以及后续引入补偿阳离子的机制。解题过程涉及多步逻辑推理和概念关联（如离子取代、电荷平衡、补偿阳离子选择等），超出了简单记忆或单一概念应用的范畴。在选择题型内，这种需要综合多个知识点并推导结论的题目属于较难水平。" + }, + { + "idx": 70, + "question": "Asbestos minerals such as tremolite $\\mathrm{Ca_{2}M g_{5}[S i_{4}O_{11}]}$ (OH)2 exhibit a fibrous crystal habit, while talc Mgs[Si4Oo](OH)2 displays a platy crystal habit. Please explain this phenomenon.", + "answer": "Tremolite has a double-chain structure, where the Si-O bonds within the chains are much stronger than the Ca-O and Mg-O bonds between the chains. Therefore, it easily cleaves along the weaker interchain bonding sites, resulting in a fibrous habit. Talc has a layered structure composed of two [SiO4] layers with a brucite-like layer in between. The layers are held together by weak van der Waals forces, and due to the weak intermolecular forces, talc readily cleaves along these weak bonding planes to form platy crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种矿物晶体习性的现象，答案提供了详细的文字解释和论述，涉及晶体结构和化学键的性质，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释矿物晶体习性的差异，涉及晶体结构（双链结构和层状结构）与化学键（Si-O键、Ca-O键、Mg-O键和范德华力）之间的关联分析，需要综合运用材料科学知识进行机理解释，思维过程具有较高的深度要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握硅酸盐矿物的晶体结构知识（如双链结构和层状结构），还需要深入理解不同化学键强度对晶体解理行为的影响机制。正确选项涉及多个知识点的综合运用：1) 透闪石的双链结构与滑石的层状结构对比；2) Si-O键与Ca-O/Mg-O键的强度差异分析；3) 范德华力在层状结构中的作用；4) 晶体解理面与化学键方向的关联性。解题需要完成从微观结构到宏观形态的完整推理链条，在选择题型中属于对复杂现象的全面分析要求。" + }, + { + "idx": 71, + "question": "What are the characteristics of non-stoichiometric compounds?", + "answer": "Characteristics of non-stoichiometric compounds: The formation and defect concentration of non-stoichiometric compounds are related to the nature and pressure of the atmosphere; they can be regarded as solid solutions of higher-valent and lower-valent compounds; the defect concentration is related to temperature, which can be seen from the equilibrium constant; non-stoichiometric compounds are all semiconductors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释非化学计量化合物的特性，涉及多个相关概念（如缺陷浓度、温度影响、半导体性质等）的综合分析，需要理解并关联这些概念，而不仅仅是记忆基础定义。虽然不涉及复杂计算，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。正确选项涵盖了非化学计量化合物的多个关键特征，包括与气氛性质和压力的关系、高低价态化合物的固溶体性质、缺陷浓度与温度的关系以及半导体特性。这些知识点需要考生不仅理解基本概念，还能进行多角度分析和概念关联。此外，题目要求考生能够综合这些信息并识别出正确选项，这在选择题型中属于较为复杂的综合分析任务。" + }, + { + "idx": 72, + "question": "Using the电价规则, explain that when Al3+ replaces Si4+ in the framework, it usually does not exceed half, otherwise the structure will become unstable.", + "answer": "Assuming Al3+ replaces half of the Si4+, then O2- is connected to one Si4+ and one Al3+. The electrostatic bond strength of the cation = 3/4×1 + 4/4×1 = 7/4. The charge number of O2- is -2, and the difference between the two is 1/4. If the replacement exceeds half, the difference will inevitably be >1/4, causing structural instability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用电价规则解释Al3+替换Si4+时不超过半数的原因，答案通过文字解释和论述来阐述这一现象，没有涉及选择、判断或计算。 | 知识层次: 题目要求学生运用电价规则解释Al3+替换Si4+的结构稳定性问题，涉及静电键强度的计算和结构稳定性的推理分析，需要综合运用多个概念并进行机理层面的解释。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅理解电价规则的基本概念，还需要进行复杂的静电键强度计算和结构稳定性推理。题目涉及多个知识点的综合运用（如离子替换、静电平衡、结构稳定性），解题步骤较为复杂，需要考生具备较强的分析推理能力和机理深度解释能力。在选择题型内，这类需要综合多个高阶认知技能进行复杂分析的题目属于最难的一类。" + }, + { + "idx": 73, + "question": "Why are non-stoichiometric compounds all n-type or p-type semiconductor materials?", + "answer": "Due to anion vacancies and interstitial cations leading to an excess of metal ions, metal-excess (n-type) semiconductors are formed; cation vacancies and interstitial anions leading to an excess of anions form anion-excess (p-type) semiconductors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物为何都是n型或p型半导体材料，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非化学计量化合物为何都是n型或p型半导体材料，涉及缺陷化学、半导体类型与缺陷类型之间的关联机制，需要综合运用多个概念并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 74, + "question": "Explain the meaning of the symbol V_{Na}", + "answer": "Sodium atom vacancy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号V_{Na}的含义，需要文字解释和论述，答案\"Sodium atom vacancy\"是一个简短的文字解释，符合简答题的特征 | 知识层次: 题目考查对材料科学中缺陷符号的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅要求识别和记忆基础符号的定义（钠原子空位），属于最基本的概念记忆层次。不需要解释或分析，只需直接回忆符号对应的含义，因此属于最低难度等级。" + }, + { + "idx": 75, + "question": "What is the effect on crystal stability after forming a solid solution?", + "answer": "Stabilizes the crystal lattice and prevents certain polymorphic transitions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固体溶液对晶体稳定性的影响，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目涉及固体溶液对晶体稳定性的影响，需要理解固体溶液的形成机制及其对晶体结构的影响，属于概念关联和综合分析层次。虽然不涉及复杂计算，但需要对晶体稳定性和多态性转变有较深入的理解。 | 难度: 在选择题中属于中等难度，需要理解固溶体形成对晶体稳定性的影响，并关联晶体结构和多晶型转变的概念。虽然题目涉及综合分析，但在选择题型中通过正确选项可以直接判断，不需要多步计算或深度关联性分析。" + }, + { + "idx": 76, + "question": "What is the effect on lattice activation after forming a solid solution?", + "answer": "Activating the lattice, after forming a solid solution, the lattice structure undergoes certain distortion and is in a high-energy activated state, which is conducive to chemical reactions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固体溶液形成后对晶格活化的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及固体溶液形成后晶格激活效应的解释，需要理解晶格畸变与高能激活状态之间的关系，并能够综合分析其对化学反应的影响。这属于中等应用层次，需要将多个概念关联起来进行解释，但不需要进行复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解固溶体形成后晶格结构的变化及其对化学反应的影响，涉及概念关联和综合分析。" + }, + { + "idx": 77, + "question": "What are the factors affecting the formation of substitutional solid solutions?", + "answer": "Factors influencing the formation of substitutional solid solutions include: (1) Ionic size: The 15% rule - 1. If (R1-R2)/R1 > 15%, discontinuous. 2. If ≤15%, continuous. 3. If >40%, solid solution cannot form. (2) Ionic valence: Same valence leads to continuous solid solution formation. (3) Crystal structure factors: Same structure of matrix and impurity results in continuous solid solution. (4) Field strength factor. (5) Electronegativity: Small difference favors solid solution formation, while large difference leads to compound formation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列举和解释影响置换固溶体形成的因素，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释影响置换固溶体形成的多个因素，涉及离子尺寸、离子价态、晶体结构等多个概念的综合应用和分析，需要理解这些因素之间的关联及其对固溶体形成的影响机制，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生掌握多个关键因素（离子尺寸、离子价态、晶体结构、场强因子、电负性）并理解它们之间的相互作用关系。正确选项不仅需要识别这些因素，还要理解15%规则等具体量化标准，以及不同条件下（连续/不连续固溶体、化合物形成）的判定逻辑。这超出了简单记忆的范畴，需要考生进行多角度分析和概念关联，符合等级4\"多角度分析论述\"的标准。" + }, + { + "idx": 78, + "question": "Based on the projection diagram of Mg2[SiO4] on the (100) plane, answer: How many types of coordination polyhedra are there in the structure, and what are the connection modes between the various coordination polyhedra?", + "answer": "There are two types of coordination polyhedra, [SiO4] and [MgO6]. [MgO6] octahedra in the same layer share edges, such as 59[MgO] and 49[MgO6] sharing edges 7502- and 2702-. [MgO6] octahedra in different layers share vertices, such as 1[MgO] and 51[MgO6] sharing vertex 2202-. [MgO] and [SiO4] in the same layer share vertices, such as T[MgO] and 7[SiO4] sharing vertex 2202-. [MgO6] and [SiO4] in different layers share edges, such as T[MgO] and 43[SiO4] sharing 2802- and 2802-.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述结构中的配位多面体类型及其连接方式，答案提供了详细的文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求分析晶体结构中的配位多面体类型及其连接方式，需要综合运用晶体学知识、空间想象能力和结构分析技巧。这涉及到对投影图的深入理解、配位多面体的识别以及它们之间连接方式的推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 79, + "question": "What is the effect of forming a solid solution on the mechanical properties of materials?", + "answer": "Solid solution strengthening; the dissolution of solute atoms increases the strength and hardness of the solid solution. The strength and hardness of the solid solution are often higher than those of the constituent elements, while the plasticity is lower.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释固溶体对材料机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对固溶体强化这一基本概念的记忆和理解，属于材料科学中的基本原理和现象解释，不涉及复杂的计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（固溶强化），但正确选项不仅需要识别\"固溶强化\"这一概念，还需要理解其对机械性能的具体影响（强度硬度增加、塑性降低）。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。题目要求考生能够将固溶强化的基本原理与材料性能变化联系起来，属于概念解释和描述的难度层次。" + }, + { + "idx": 80, + "question": "What is the effect on the physical properties of materials after forming a solid solution?", + "answer": "The electrical, thermal, magnetic, and other physical properties of solid solutions also change continuously with composition, but generally not in a linear relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固体溶液对材料物理性质的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶体形成对材料物理性能的影响，涉及多个物理性能（电、热、磁等）的变化及其与成分的非线性关系，需要综合分析不同性能的变化趋势和相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解固溶体的物理性质变化与成分之间的关系，并认识到这种变化通常是非线性的。题目要求考生综合分析和说明固溶体的电学、热学、磁学等物理性质随成分变化的规律，但不需要进行多角度分析或深度关联性分析。" + }, + { + "idx": 81, + "question": "Explain the meaning of the symbol V_{Cl}^*", + "answer": "Chlorine ion vacancy, with a single positive charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号V_{Cl}^*的含义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对缺陷化学符号的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求识别和记忆基础符号的定义（氯离子空位带一个正电荷），属于最基础的概念记忆层次。不需要解释或分析，只需直接回忆符号对应的定义即可，因此属于等级1的简单难度。" + }, + { + "idx": 82, + "question": "Explain the meaning of the symbol (V_{Na}'V_{Cl}^*)", + "answer": "An associated center formed by the nearest Na vacancy and Cl vacancy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释符号的含义，需要用文字进行解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对材料科学中缺陷符号的基本概念的记忆和理解，属于定义性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并解释一个特定的符号含义（V_{Na}'V_{Cl}^*），这比单纯记忆定义或分类稍复杂。正确选项要求考生能够将符号与具体的物理概念（即由最近的Na空位和Cl空位形成的关联中心）联系起来，这需要一定的概念理解和描述能力，而不仅仅是简单的记忆。因此，该题目在选择题型中属于等级2难度。" + }, + { + "idx": 83, + "question": "Explain the meaning of the symbol Ca_{i}^{* *}", + "answer": "Ca2+ is located at the interstitial site of the lattice", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，答案也是以文字形式给出解释说明 | 知识层次: 题目考查对材料科学中缺陷符号的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目要求考生解释符号Ca_{i}^{* *}的含义，并选择正确的选项。这属于概念解释和描述的层次，需要考生理解并记忆Ca2+位于晶格间隙位置的定义。虽然需要一定的知识掌握，但不需要复杂的分析或推理，因此属于中等难度。" + }, + { + "idx": 84, + "question": "Explain the meaning of the symbol Ca_{K}^*", + "answer": "Ca2+ occupies the K site, with a unit positive charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，答案也是以文字形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对材料科学中符号表示的基本概念的记忆和理解，涉及离子占据晶格位置及其电荷状态的简单描述，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生解释符号Ca_{K}^*的含义，属于概念解释和描述层次。虽然需要记忆基础概念，但不需要复杂的分析或比较多个概念。正确选项直接给出了定义，因此难度适中。" + }, + { + "idx": 85, + "question": "Explain the meaning of the symbol Ca_{Ca}", + "answer": "Ca atom located at the Ca atom site", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，答案也是以文字形式呈现的解释性内容 | 知识层次: 题目考查对晶体缺陷符号的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅要求识别并记忆基础符号的定义（Ca atom located at the Ca atom site），属于直接回忆型知识点，无需解释或推理步骤，符合等级1“基本定义简答”的标准。" + }, + { + "idx": 86, + "question": "Explain the meaning of the symbol V_{Na}'", + "answer": "Sodium ion vacancy, with a single negative charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对材料科学中缺陷化学符号的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅要求识别并记忆基础符号的定义（钠离子空位带一个负电荷），属于最基础的概念记忆层次，无需解释或分析过程。" + }, + { + "idx": 87, + "question": "Write the defect reaction equation for NaCl dissolving into CaCl2 to form a vacancy-type solid solution", + "answer": "NaCl > Naca + Cla + Va* NaC", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求写出缺陷反应方程，需要理解固溶体的形成机制和缺陷化学的基本原理，并能够将这些概念关联起来进行综合分析。虽然不涉及复杂的计算，但需要多步的思维过程来正确表达缺陷反应。 | 难度: 在选择题中属于中等难度，需要理解缺陷反应方程的基本概念，并能够正确关联NaCl溶解到CaCl2中形成空位型固溶体的具体反应。题目要求考生不仅掌握基本的缺陷化学知识，还需要进行多步思考和综合分析，以正确写出反应方程式。虽然题目提供了正确选项，但考生仍需具备一定的应用能力和概念关联能力才能准确作答。" + }, + { + "idx": 88, + "question": "Write the defect reaction equation for the formation of Schottky defects in NaCl", + "answer": "$Rsh$ $+V_{cl}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字解释和论述，答案形式为化学方程式，属于简答题类型 | 知识层次: 题目考查Schottky缺陷的基本概念和反应方程的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求写出NaCl中肖特基缺陷的形成反应方程，属于基础概念记忆的范畴。正确选项直接给出了缺陷反应方程，无需复杂的推理或分析，仅需对基本定义和反应方程的记忆。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 89, + "question": "Write the defect reaction equation for the formation of a vacancy-type solid solution when CaCl2 dissolves in NaCl", + "answer": "CaCl2 > CaNa' + 2Clci + Va'", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，而不是从选项中选择、判断对错或进行数值计算 | 知识层次: 题目要求写出缺陷反应方程，需要理解缺陷化学的基本原理，并能够将CaCl2溶解在NaCl中的具体情况进行应用。这涉及到多步思考和概念关联，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解缺陷化学的基本概念，包括点缺陷的形成和表示方法，并能正确应用Kröger-Vink符号表示缺陷反应。此外，题目要求将CaCl2溶解在NaCl中的过程转化为缺陷反应方程，涉及多步思考和概念关联，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 90, + "question": "What are the factors affecting the formation of interstitial solid solutions?", + "answer": "Factors influencing the formation of interstitial solid solutions include: (1) Size of impurity particles: The smaller the added atoms, the easier it is to form a solid solution, and vice versa. (2) Crystal (matrix) structure: The size of ions is closely related to the crystal structure, and to a certain extent, the size of the interstitial sites plays a decisive role. Generally, the larger the voids in the crystal, the looser the structure, and the easier it is to form a solid solution. (3) Valence factor: When foreign impurity atoms enter the interstitial sites, they inevitably cause an imbalance in the valence of the crystal structure. This can be compensated by generating vacancies, partial substitution, or changes in the valence state of ions to maintain valence balance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响间隙固溶体形成的因素，答案以文字论述形式给出，需要详细解释各个因素的作用，符合简答题的特征。 | 知识层次: 题目要求解释影响间隙固溶体形成的因素，涉及多个概念（如杂质粒子大小、晶体结构、价态因素）的关联和综合分析，需要理解这些因素如何相互作用并影响固溶体的形成，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生理解并综合分析多个影响间隙固溶体形成的因素，包括杂质粒子尺寸、晶体结构以及价态因素等。这些知识点不仅需要记忆，还需要进行多角度分析和概念关联。此外，题目中的正确选项涉及多个步骤的推理和综合判断，超出了简单的记忆或单一概念应用，因此属于等级4的难度。" + }, + { + "idx": 91, + "question": "Write the defect reaction equation for the formation of Frenkel defects (Ag entering interstitial sites) in AgI", + "answer": "AgAg $V_{Ag}$ $+Ag_{i}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，答案形式为化学方程式而非选择、判断或计算 | 知识层次: 题目考查对Frenkel缺陷形成的基本概念和反应方程的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求写出Frenkel缺陷的形成反应方程，属于基础概念记忆的范畴。题目直接给出了正确选项，不需要复杂的分析或推理，只需记住基本的缺陷反应方程即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 92, + "question": "If the partial pressure of surrounding oxygen is increased, how will the density of the non-stoichiometric compound Fe1-xO change? Increase or decrease? Why?", + "answer": "202(g) 0o+Vre’ +2h* k=[O][Vr’’][h']/PO21/2=4[00][Vr’′]3/PO1/2 [Vre′′]PO²1/6, PO[Vr]↓", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物Fe1-xO的密度如何随周围氧气分压的变化而变化，并需要提供原因。答案中包含了公式推导和文字解释，符合简答题的特征。 | 知识层次: 题目需要综合运用非化学计量化合物缺陷化学知识，通过缺陷反应方程和平衡常数推导氧分压与缺陷浓度的关系，并分析其对化合物密度的影响。涉及多步推理和机理解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 93, + "question": "Both MgO (NaCl-type structure) and Li2O (anti-fluorite-type structure) are based on the cubic close packing of oxygen, and the cations are in the gaps of this arrangement. Why are Frenkel-type point defects the main defects in Li2O?", + "answer": "Li occupies octahedral voids. The octahedral voids are larger, making it easier for Li ions to move from their normal lattice sites to interstitial positions, forming Frenkel defects (simultaneous presence of cation vacancies and interstitial cations).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Li2O中Frenkel型点缺陷是主要缺陷，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释Frenkel型点缺陷在Li2O中为主要缺陷的原因，涉及晶体结构、间隙位置、离子迁移等概念的关联和综合分析，需要深入理解晶体缺陷形成的机理和影响因素，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解MgO和Li2O的晶体结构差异，还需要深入掌握Frenkel缺陷的形成机理。正确选项涉及对八面体空隙大小的理解、离子迁移能力的分析，以及缺陷形成的综合解释。这需要考生具备将晶体结构知识、缺陷化学原理和离子迁移特性等多方面知识进行整合分析的能力，属于复杂现象的全面分析层次。在选择题型中，这种需要多维度知识综合运用和深度机理解释的题目最为困难。" + }, + { + "idx": 94, + "question": "The density of MgO is $3.58\\\\mathrm{g/cm^{3}}$, and its lattice parameter is $0.42\\\\mathrm{nm}$. Calculate the number of Schottky defects per unit cell of MgO.", + "answer": "Let the number of molecules per unit cell of defective $\\\\mathrm{MgO}$ be ${\\\\bf X}$, the unit cell volume $\\\\mathrm{V}{=}$ (4.20)°, $\\\\scriptstyle{\\\\mathbf{x}}={\\\\mathbf{p}}$ VNO/M=3.96. The number of Schottky defects per unit cell $:=4-\\\\tt X=0.04$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算单位晶胞体积、应用密度公式求解缺陷数量，涉及概念关联和综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题中属于中等偏上难度，需要理解密度、晶格参数与缺陷浓度之间的关系，并进行多步计算。虽然题目提供了部分计算步骤，但仍需综合应用材料科学中的基本概念和公式来推导正确答案。" + }, + { + "idx": 95, + "question": "The Schottky defect formation energy of Mg0 crystal is 84 kJ/mol. Calculate the defect concentration of this crystal at 1000K and 1500K.", + "answer": "$\\\\mathrm{n}/\\\\mathrm{N}{=}\\\\mathrm{exp}$ (-E/2RT), $\\\\mathrm{R}{=}8.314$, $\\\\mathrm{T}{=}1000\\\\mathrm{k}$ :n/N=6. $4\\\\times{10}^{-3}$ $\\\\mathrm{T}=1500\\\\mathrm{k}$ $\\\\mathrm{n}/\\\\mathrm{N}{=}3.5\\\\times{10}^{-2}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及Schottky缺陷形成能和浓度的直接计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用Schottky缺陷浓度公式，但题目已经提供了所有必要的参数和公式，仅需进行简单的代入和计算。解题步骤较为直接，无需复杂的推导或组合多个公式。因此，在选择题型内属于中等偏下的难度等级。" + }, + { + "idx": 96, + "question": "In the non-stoichiometric compound Fe_xO, Fe^{3+}/Fe^{2+}=0.1. Find the vacancy concentration in Fe_xO.", + "answer": "Fe2O3 →2FeFe +3O0+V_Fe. Let y be the concentration of Fe^{3+}, then 2y =0.1→2y=0.1-0.3y→y=0.1/2.3=0.0435. The vacancy concentration [V_Fe''] = y = 0.0435.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非化学计量化合物Fe_xO中的空位浓度，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及非化学计量化合物Fe_xO中Fe^{3+}/Fe^{2+}比值的计算，需要理解缺陷化学的基本原理，并应用相关公式进行多步计算。虽然不涉及复杂的机理分析或创新设计，但需要综合分析缺陷反应方程和浓度关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解非化学计量化合物的概念，掌握Fe^{3+}/Fe^{2+}比例与空位浓度的关系，并进行多步计算推导。题目涉及电荷平衡和缺陷化学的综合分析，虽然给出了正确选项的推导过程，但仍需要较强的概念关联和计算能力才能正确解答。" + }, + { + "idx": 97, + "question": "In the non-stoichiometric compound Fe_xO, Fe^{3+}/Fe^{2+}=0.1, find the value of x in Fe_xO.", + "answer": "Let y be the concentration of Fe^{3+}, y=0.0435. x=1-y=1-0.0435=0.9565, thus the chemical formula is Fe_0.9565O.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非化学计量化合物Fe_xO中的x值，答案是一个具体的数值结果，解答过程涉及化学计量和电荷平衡的计算。 | 知识层次: 题目涉及非化学计量化合物的计算，需要理解Fe^{3+}/Fe^{2+}比例的概念，并进行多步计算来确定x的值。虽然计算过程不算特别复杂，但需要将概念与计算结合起来，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解非化学计量比化合物的概念，掌握Fe^{3+}/Fe^{2+}比例的计算方法，并进行多步计算才能得出最终结果。虽然题目提供了部分计算过程，但仍需要考生具备综合分析能力和化学计量关系的理解。" + }, + { + "idx": 98, + "question": "For edge dislocations, what are the characteristics of the dislocation line direction, Burgers vector, and dislocation motion direction?", + "answer": "Edge dislocation: the dislocation line is perpendicular to the Burgers vector, and the dislocation line is perpendicular to the direction of dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释边缘位错的特性，包括位错线方向、Burgers矢量和位错运动方向之间的关系，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查边缘位错的基本特征，包括位错线方向、伯格斯矢量和位错运动方向之间的关系，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（位错线方向、伯格斯矢量、位错运动方向的关系），但需要考生准确记忆并区分边缘位错的三个关键特征之间的相互关系。这比单纯复述定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。正确选项明确给出了边缘位错的两个垂直关系，考生只需识别这些特征即可作答。" + }, + { + "idx": 99, + "question": "When two edge dislocations with the same sign meet on the same slip plane, will they repel or attract each other?", + "answer": "Repel, tensile stress overlaps, compressive stress overlaps.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释两个同号刃位错在同一滑移面上相遇时的相互作用机制，答案提供了文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目需要理解位错的基本概念，并能够分析两个同号刃位错在同一滑移面上相遇时的相互作用机制。这涉及到位错应力场的叠加和相互作用力的判断，属于中等应用层次，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解位错相互作用的基本原理，并能分析相同符号位错相遇时的应力场叠加效应。题目涉及中等应用层次的知识，要求考生将位错应力场概念与相互作用机制关联起来，但不需要进行复杂的多角度或深度关联性分析。" + }, + { + "idx": 100, + "question": "For screw dislocations, what are the characteristics of the dislocation line direction, Burgers vector, and dislocation motion direction?", + "answer": "Screw dislocation: the dislocation line is parallel to the Burgers vector, and the dislocation line is parallel to the direction of dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和描述螺位错的特征，包括位错线方向、Burgers矢量和位错运动方向之间的关系，答案以文字解释的形式给出，符合简答题的特点。 | 知识层次: 题目考查对螺位错基本特征（位错线方向、伯氏矢量、位错运动方向）的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求记忆和识别螺位错的基本特征（位错线方向、伯氏矢量方向、运动方向之间的关系），属于基础概念的直接回忆，无需解释或复杂分析。" + }, + { + "idx": 101, + "question": "Both MgO (NaCl-type structure) and Li2O (anti-fluorite-type structure) are based on the cubic close packing of oxygen, and the cations are located in the interstitial sites of this arrangement. Why are Schottky defects the predominant point defects in MgO?", + "answer": "Mg occupies the tetrahedral sites. The tetrahedral sites are relatively small, making it difficult for Mg ions to migrate within the lattice to form Frenkel defects. Therefore, they are more inclined to form Schottky defects (paired cation and anion vacancies).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么MgO中Schottky缺陷是主要的点缺陷，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要综合运用晶体结构、缺陷类型和离子迁移等知识，分析MgO中Schottky缺陷占主导的原因，涉及机理解释和推理分析。 | 难度: 在选择题型内属于最高难度等级，因为该题目要求考生：" + }, + { + "idx": 102, + "question": "If the partial pressure of surrounding oxygen is increased, how will the density of the non-stoichiometric compound Zn1+xO change? Increase or decrease? Why?", + "answer": "Zn (g) →Zni· +e Zn (g) +1/2O2=ZnO Zn:+e’+1/2O→ZnO [ZnO]=[e'] PO2↑,[Zni]↓", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物Zn1+xO的密度如何随周围氧气分压的变化而变化，并需要提供原因。答案中包含了化学反应方程式和文字解释，符合简答题的特征。 | 知识层次: 题目需要综合运用非化学计量化合物、缺陷化学、质量作用定律等知识，通过分析氧分压变化对缺陷浓度的影响机制来解释Zn1+xO密度的变化。这涉及多概念关联和机理解释，属于较高层次的综合分析能力。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 103, + "question": "What effect will grain boundaries have on the movement of dislocations? Can it be predicted?", + "answer": "Grain boundaries hinder the movement of dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶界对位错运动的影响，并讨论是否可以预测这种影响，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对晶界对位错运动影响的基本概念记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"晶界对位错运动的影响\"这一基本原理的直接复现。正确选项是教材或课堂中明确给出的结论，无需解释或推理过程，属于最基础的定义性知识考查。" + }, + { + "idx": 104, + "question": "Grain boundaries can be divided into small-angle grain boundaries and large-angle grain boundaries. Can large-angle grain boundaries be described by arrays of dislocations?", + "answer": "No, in large-angle grain boundaries, the atomic arrangement is close to a disordered state, and the distance between dislocations may only be 1 or 2 atoms in size, which is not applicable to large-angle grain boundaries.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（\"Can large-angle grain boundaries be described by arrays of dislocations?\"），答案明确给出了\"否\"的回答并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对晶界分类和位错描述的基本概念的理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解大角度晶界的原子排列状态以及位错阵列的适用性。题目不仅要求记忆定义，还需要对概念进行一定的理解和判断，因此难度高于简单的正误判断（等级1），但尚未达到复杂概念陈述的判断（等级3）。" + }, + { + "idx": 105, + "question": "Taking the dissolution of solute A0 in solvent B2O3 as an example, compare the chemical compositions of solid solutions, compounds, and mechanical mixtures.", + "answer": "
Comparison itemSolid solutionCompoundMechanical mixture
Chemical compositionB2xAxO X （x=0~2）AB2O4AO+B2O3
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较固体溶液、化合物和机械混合物的化学成分，并以表格形式展示答案，这需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求比较固体溶液、化合物和机械混合物的化学组成，涉及多个概念的关联和综合分析，需要理解不同物质状态下的化学组成变化，并进行对比分析。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在选择题型中，该题目要求考生不仅理解固体溶液、化合物和机械混合物的基本概念，还需要能够比较它们的化学组成。题目通过表格形式呈现了三种不同物质类型的化学组成，要求考生能够识别并区分这些组成。这涉及到多步的概念关联和综合分析，属于较高难度的选择题。此外，题目还涉及中等应用层次的知识，需要考生具备一定的化学组成分析和比较能力。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 106, + "question": "From the perspective of chemical composition and phase composition, compare the differences between solid solutions and mechanical mixtures.", + "answer": "
Solid solutionMechanical mixture
Formation reasonFormed by atomic-scale 'dissolution'Powder mixing
Number of phasesUniform single phaseMultiphase
Chemical compositionUncertainAs many chemical compositions as there are mixtures
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从化学组成和相组成的角度比较固溶体和机械混合物的差异，需要文字解释和论述，答案以表格形式呈现了详细的对比内容，符合简答题的特征。 | 知识层次: 题目考查对固体溶液和机械混合物在化学成分和相组成方面的基本概念的理解和记忆，属于基础概念的记忆和分类。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并比较固体溶液和机械混合物在化学成分和相组成方面的差异。正确选项通过表格形式清晰展示了两种材料的区别，包括形成原因、相数和化学成分。这要求考生不仅记住定义，还需要能够区分和对比这些概念。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 107, + "question": "Explain the similarities between solid solutions, lattice defects, and non-stoichiometric compounds", + "answer": "Solid solutions, lattice defects, and non-stoichiometric compounds are all point defects, which are crystal structure defects, and they are single-phase homogeneous solids with structures identical to the host crystal phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的相似性，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对固体溶液、晶格缺陷和非化学计量化合物这些基本概念的记忆和理解，以及它们之间的相似性。这些都属于晶体结构缺陷的基础知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生理解并描述三个相关概念（固溶体、晶格缺陷和非化学计量化合物）的相似性。虽然需要掌握多个概念，但题目仅要求识别和描述它们的共同特征（点缺陷、晶体结构缺陷、单相均质固体），而不需要进行复杂的比较分析或推导。这属于概念解释和描述的难度层次。" + }, + { + "idx": 108, + "question": "Explain the differences between solid solutions, lattice defects, and non-stoichiometric compounds", + "answer": "Thermal defects - intrinsic defects; solid solutions - extrinsic defects; non-stoichiometric compounds - caused by changes in environmental atmosphere properties and pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的差异，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的差异，这需要理解并关联多个概念，进行综合分析。虽然涉及基础概念，但需要将这些概念进行比较和关联，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅要理解固体溶液、晶格缺陷和非化学计量化合物的基本概念，还需要能够区分它们之间的差异，并正确匹配到热缺陷、外禀缺陷和环境因素导致的缺陷。这涉及到多步的概念关联和综合分析，属于较高难度的选择题。" + }, + { + "idx": 109, + "question": "Al2O3 forms a limited solid solution in MgO, with approximately 18wt% Al2O3 dissolved in MgO at the eutectic temperature of 1995℃, assuming the unit cell size change of MgO is negligible. Estimate the density change when Al3+ acts as a substitutional ion.", + "answer": "The defect reaction is: Al2O3→MgO 2Al•Mg + 3O×o + V''Mg. Taking 100g of sample as the basis: mAl2O3 = 18/102 = 0.176 mol, mMgO = 82/40.3 = 2.035 mol. The molecular formula after solid solution is Mg2.035Al0.352O2.563. The density change is ρ/ρMgO = (0.176×102 + 2.035×40.3)/(2.563×40.3) = 0.968. The density after solid solution is less than that before solid solution.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括摩尔质量计算、分子式推导和密度变化计算。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解缺陷反应、摩尔计算和密度变化分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解缺陷反应方程、摩尔质量计算、分子式推导以及密度变化计算等多个步骤。虽然题目提供了部分计算过程，但仍需要考生具备综合分析能力和对固溶体概念的理解。" + }, + { + "idx": 110, + "question": "In MgO-Al2O3 and PbTiO3-PbZrO3, which pair forms a limited solid solution, and why?", + "answer": "MgO-Al2O3 forms a limited solid solution because the ionic radii of Mg2+ and Al3+ differ significantly, and the crystal structure types of MgO (NaCl-type structure) and Al2O3 (corundum-type structure) are quite different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪一对形成有限固溶体并说明原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析两种材料体系中哪种形成有限固溶体，并解释原因。这需要综合运用离子半径差异和晶体结构类型差异的知识，进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 111, + "question": "For MgO, Al2O3, and Cr2O3, the cation-anion radius ratios are 0.47, 0.36, and 0.40 respectively. Is the solid solubility in the MgO-Cr2O3 system expected to be limited or unlimited? Why?", + "answer": "The solid solubility between MgO and Cr2O3 is limited. Reason: different structure types, MgO has a NaCl-type structure while Cr2O3 has a corundum structure. Although (0.47-0.40)/0.47=14.89%<15%, continuous solid solution still cannot be formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么MgO-Cr2O3系统的固溶度是有限的，需要文字解释和论述，而不是简单的选择、判断或计算。答案中提供了详细的解释和结构差异的分析。 | 知识层次: 题目需要理解并应用离子半径比与晶体结构类型的关系，分析不同氧化物之间的固溶度限制。虽然涉及基本概念（离子半径比、晶体结构类型），但需要综合分析两者之间的关联，并解释为什么即使离子半径比差异小于15%仍不能形成连续固溶体。这属于中等应用层次，需要多步分析和概念关联。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生掌握离子半径比与固溶体形成条件的基本概念，还需要考生能够综合分析不同晶体结构类型对固溶度的影响。解题步骤涉及多个知识点的关联应用（包括半径比计算、结构类型判断、固溶度限制条件等），并需要考生在选择题的有限选项中准确判断出关键限制因素（结构类型差异）。虽然题目给出了具体数值，但需要考生理解15%规则的适用条件及其例外情况（结构类型不同时不能形成连续固溶体），这超出了单纯记忆性知识的范畴，属于中等应用层次的多角度分析。" + }, + { + "idx": 113, + "question": "A certain NiO is non-stoichiometric. If the ratio of $\\\\mathrm{Ni^{3+}/Ni^{2+}}$ in NiO is $10^{-4}$, how many charge carriers are there per $\\\\mathrm{m}^{3}$?", + "answer": "Let the non-stoichiometric compound be $\\\\mathrm{Ni_{1}O}$. The reaction is: $Ni_{2}O_{3}\\\\xrightarrow{2\\\\sqrt{6}O}2^{1\\\\sqrt{1}i_{2}}Ni_{3}O_{0}+\\\\mathrm{V_{Ni}^{''}}$. The ratio $\\\\mathrm{Ni^{3+}/Ni^{2+}}=2y/(1-3y)=10^{-4}$. Solving gives $y=5\\\\times10^{-5}$, $x=1-y=0.99995$, leading to Ni$_{0.99995}$O. The number of charge carriers per $\\\\mathrm{m}^{3}$ is equal to the vacancy concentration: $[\\\\mathrm{V_{Ni}^{''}}]=y/\\\\Omega(1+x)=2.5\\\\times10^{-5}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定非化学计量NiO中的电荷载流子浓度。解答过程涉及化学反应方程、比例关系求解和浓度计算，这些都是计算题的典型特征。 | 知识层次: 题目涉及非化学计量比化合物的计算，需要理解缺陷反应方程、电荷平衡关系，并进行多步计算和概念关联。虽然不涉及复杂的机理解释或创新应用，但需要综合分析缺陷浓度与电荷载体浓度的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解非化学计量比化合物的概念，掌握Ni3+/Ni2+比例与空位浓度的关系，并进行多步计算。虽然题目提供了部分解题步骤，但仍需要综合分析能力和对材料缺陷化学的理解。" + }, + { + "idx": 114, + "question": "Explain why only substitutional solid solutions can achieve complete mutual solubility between the two components, while interstitial solid solutions cannot.", + "answer": "(1) The interstitial sites in a crystal are limited, with an impurity accommodation capacity of $\\zeta10\\%$; (2) The formation of interstitial solid solutions generally increases the lattice constant, and when this increase reaches a certain extent, the lattice becomes unstable and dissociates; substitutional solid solutions are formed by the exchange of positions between ions of the same type, which does not affect the bonding, thus allowing the formation of continuous solid solutions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么只有置换型固溶体可以实现两种组分的完全互溶，而间隙型固溶体不能。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释置换型固溶体和间隙型固溶体在完全互溶性方面的差异，涉及晶体结构、晶格稳定性、键合作用等多个概念的综合分析和关联。需要深入理解两种固溶体的形成机制及其对材料性能的影响，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解置换固溶体和间隙固溶体的基本概念，还需要深入掌握晶体结构、晶格稳定性、溶解度限制等复杂机理。正确选项涉及多个专业知识点（如间隙位置限制、晶格常数变化、键合影响等），并要求将这些知识点综合运用来解释溶解度差异现象。此外，选项表述包含专业术语和定量数据（ζ10%），需要考生具备较强的材料科学理论基础和分析推理能力。这种在选择题中要求对复杂现象进行全面机理分析的题目，在选择题型内属于最高难度级别。" + }, + { + "idx": 115, + "question": "For MgO, Al2O3, and Cr2O3, the radius ratios of cations to anions are 0.47, 0.36, and 0.40, respectively. Is it possible for Al2O3 and Cr2O3 to form continuous solid solutions? Why?", + "answer": "Al2O3 and Cr2O3 can form continuous solid solutions, because: 1) They have the same crystal structure type, both belonging to the corundum structure. 2) (0.40-0.36)/0.40=10%<15%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al2O3和Cr2O3能否形成连续固溶体，并给出原因。答案需要文字论述和解释，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解固溶体形成的条件，包括晶体结构类型和半径比的差异，并进行简单的计算和比较。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或深度理解。 | 难度: 在选择题中属于较高难度，需要综合运用多个知识点进行分析判断。具体包括：1) 需要掌握不同氧化物的晶体结构类型知识；2) 需要理解半径比对固溶体形成的影响；3) 需要进行具体的百分比计算；4) 需要将计算结果与15%的经验规则进行比较。这些步骤涉及概念关联和综合分析能力，超出了简单记忆或单一概念应用的难度水平。" + }, + { + "idx": 116, + "question": "List a concise table comparing solid solutions, lattice defects, and non-stoichiometric compounds", + "answer": "
ClassificationFormation reasonFormation conditionDefect reactionChemical formulaSolubility, defect concentration
Thermal defectSchottky FrenkelThermal fluctuationT>OkVM M+Vx 0MX MXOnly controlled by temperature
M>M+V
Solid solutionInfinite, finite, substitution, interstitialImpurity dissolutionSize, electronegativity, valence, structureNone: controlled by temperature With: impurity amount < solubility limit controlled by temperature impurity amount > solubility limit controlled by solubility limit
Non-stoichiometric compoundCation vacancy anion interstitial cation interstitial anion vacancyChanges in environmental atmosphere nature and pressureFe1x0 UO2x Zn1x0 TiO2-x[h'] pl16 8 20 [Zni]oPo P-1/6
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列出并比较固体溶液、晶格缺陷和非化学计量化合物的表格，需要以文字和表格形式进行解释和论述，属于简答题类型。 | 知识层次: 题目要求对固体溶液、晶格缺陷和非化学计量化合物进行比较，涉及多个概念的关联和综合分析。虽然包含一些基础概念的记忆，但更强调对不同类型缺陷的形成原因、条件和反应的理解和比较，需要中等程度的思维深度和知识点的关联。 | 难度: 在选择题型中，该题目要求考生对固体溶液、晶格缺陷和非化学计量化合物等多个概念有深入的理解，并能进行综合比较分析。题目提供了详细的表格，涉及分类、形成原因、形成条件、缺陷反应、化学式以及溶解度等多个方面，要求考生能够从多角度进行分析和论述。此外，题目还涉及中等应用层次的知识，需要进行多步计算和概念关联，进一步增加了题目的复杂程度。因此，在选择题型内，该题目属于较高难度等级。" + }, + { + "idx": 118, + "question": "Chemical analysis of pyrite yields two possible compositions based on the Fe/S ratio from the analytical data: Fe1-xS and FeS1-x. The former implies a defect structure with Fe vacancies, while the latter indicates Fe substitution. How can experimental methods determine whether the mineral belongs to Fe1-xS (Fe vacancy defect structure)?", + "answer": "Fe1-xS contains Fe vacancies and is a non-stoichiometric compound, exhibiting h'P-type semiconductor properties. By measuring its semiconductor characteristics, if the results show h'P-type semiconductor behavior, it can be confirmed that the mineral composition is Fe1-xS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过实验方法确定矿物属于Fe1-xS结构，需要文字解释和论述半导体特性的测量方法及其与矿物结构的关系。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求通过实验方法确定矿物属于Fe1-xS结构，涉及非化学计量化合物的缺陷结构分析、半导体特性测量以及结果解释。这需要综合运用材料科学中的缺陷化学、半导体物理等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解非化学计量化合物的概念（Fe1-xS和FeS1-x的区别），还需要掌握半导体特性与缺陷结构之间的机理关系。正确选项涉及通过实验现象（h'P型半导体行为）反推晶体缺陷类型，这需要考生具备：" + }, + { + "idx": 119, + "question": "In MgO-Al2O3 and PbTiO3-PbZrO3, which pair forms an infinite solid solution, and why?", + "answer": "PbTiO3-PbZrO3 forms an infinite solid solution. Although the ionic radii of Ti4+ and Zr4+ differ significantly (approximately 15.28%), they both possess the ABO3 perovskite-type structure, and both Ti4+ and Zr4+ occupy the octahedral voids. These voids are relatively large, allowing the radii of the inserted cations to vary within a certain range without causing structural changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪一对材料形成无限固溶体并说明原因，答案需要详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求分析两种材料体系中哪一种能形成无限固溶体，并解释原因。这需要综合运用晶体结构、离子半径、固溶体形成条件等多方面知识，进行推理分析。特别是需要理解离子半径差异对固溶体形成的影响，以及晶体结构中空隙大小对离子取代的容忍度，属于较深层次的分析和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 121, + "question": "Use experimental methods to identify SiO2 glass", + "answer": "Use X-ray detection. SiO2 glass - isotropic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用实验方法识别SiO2玻璃，答案提供了具体的实验方法（X-ray detection）和结果（isotropic），这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别SiO2玻璃，并解释其各向同性特性。这属于基本实验方法的直接应用，不需要复杂的分析或多步骤推理，主要涉及对实验原理和材料特性的简单理解和应用。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本知识（X-ray检测和SiO2玻璃的各向同性特性）即可选出正确选项，无需复杂分析或多步骤推理。" + }, + { + "idx": 122, + "question": "Use experimental methods to identify crystalline SiO2", + "answer": "Use X-ray detection. Crystalline SiO2—particles are arranged regularly in three-dimensional space, exhibiting anisotropy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求使用实验方法识别晶体SiO2，答案提供了具体的实验方法（X射线检测）和解释（晶体SiO2的三维规则排列和各向异性），属于需要文字解释和论述的简答题。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别晶体SiO2，并解释其结构特征。这涉及基本的实验技术应用和晶体学基本概念的理解，属于简单应用层次。 | 难度: 在选择题中属于中等难度，需要理解X射线检测的基本原理以及晶体结构（如各向异性）的特性，并能将两者联系起来进行判断。虽然题目给出了直接的应用方法说明，但需要考生具备一定的知识背景才能正确选择答案。" + }, + { + "idx": 123, + "question": "What are the characteristics of the polymer structure of silicate melts?", + "answer": "The characteristics of the polymer structure of silicate melts include: being composed of silicon-oxygen tetrahedra as the basic units forming polymers of varying sizes; undergoing three stages during formation: differentiation, polycondensation, and equilibrium; accompanying deformation during polycondensation, where chain polymers undergo rotation and bending, layered polymers experience wrinkling and warping, and framework polymers exhibit increased thermal defects with changes in the Si-O-Si bond angle; ultimately reaching an equilibrium state of polymerization and depolymerization under the influence of time and temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述聚合物结构的特点，答案提供了详细的文字描述和解释，符合简答题的特征。 | 知识层次: 题目要求对硅酸盐熔体聚合物结构的特性进行详细解释和论述，涉及硅氧四面体基本单元、聚合物形成过程的三个阶段（分化、缩聚和平衡）、聚合物变形机制（链状、层状和骨架聚合物的不同变形行为）以及最终平衡状态的描述。这些内容需要综合运用材料科学知识，进行推理分析和机理解释，思维过程深度较高，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。正确选项不仅要求掌握硅酸盐熔体聚合物结构的基本单元（硅氧四面体）和形成阶段（分化、缩聚、平衡），还需要深入理解不同聚合物类型（链状、层状、框架）在缩聚过程中的变形机理，以及时间和温度对聚合-解聚平衡状态的影响。这需要考生具备综合运用知识、进行复杂推理和机理解释的能力，远超选择题型中常见的简单概念识别或单一知识点考查。" + }, + { + "idx": 124, + "question": "Use experimental methods to identify SiO2 melt", + "answer": "Use X-ray detection. SiO2 melt—internal structure is framework-like, short-range ordered, long-range disordered.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求使用实验方法识别SiO2熔体，答案提供了具体的实验方法（X-ray detection）和解释（内部结构特征），属于需要文字解释和论述的简答题。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别SiO2熔体的结构特征，涉及对实验方法的理解和应用，以及将实验结果与材料结构特征（短程有序、长程无序）关联起来。这需要多步思维过程，包括选择合适的实验方法、理解其原理，并能解释实验结果，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解SiO2熔体的结构特征（短程有序、长程无序）以及X射线检测方法的原理和应用。虽然题目涉及实验方法和材料结构的综合分析，但在选择题型中，正确选项提供了明确的关键信息，降低了答题的复杂程度。" + }, + { + "idx": 125, + "question": "Use experimental methods to identify silica gel", + "answer": "Use X-ray detection. Silica gel—loose and porous.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用实验方法识别硅胶，答案需要文字解释和论述具体的实验方法（X射线检测）和硅胶的特征（松散多孔），属于需要文字解释的简答题类型。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别硅胶，并描述其特性（松散多孔）。这属于直接应用基本的实验技术和材料特性知识，不需要复杂的分析或综合过程。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需识别正确的实验方法（X-ray检测）并理解硅胶的基本特性（松散多孔）。题目直接给出了正确选项，无需复杂分析或多步骤推理，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 126, + "question": "Describe the structural and property characteristics of quartz melt", + "answer": "
StructureFramework structure, long-range disorder
PropertiesHigh viscosity, large surface tension
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述石英熔体的结构和性能特征，答案以文字解释和论述的形式呈现，符合简答题的特征 | 知识层次: 题目主要考查对石英熔体结构和性质特征的基础概念记忆和理解，不涉及复杂分析或综合应用 | 难度: 在选择题型中，该题目要求考生描述石英熔体的结构和性质特征，属于概念解释和描述的层次。虽然需要记忆和理解石英熔体的基本结构（框架结构、长程无序）和性质（高粘度、大表面张力），但不需要进行复杂的比较分析或阐述多个概念之间的关系。因此，在选择题型内属于中等难度。" + }, + { + "idx": 127, + "question": "What are the factors affecting the viscosity of the melt?", + "answer": "The main factors affecting the viscosity of the melt: temperature and the composition of the melt. The increase in the content of alkaline oxides drastically reduces the viscosity. As the temperature decreases, the viscosity of the melt increases exponentially.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响熔体粘度的因素，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对熔体粘度影响因素的基础概念记忆和理解，涉及温度和熔体组成等基本原理，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并记忆影响熔体粘度的两个主要因素（温度和成分）及其具体影响方式（碱性氧化物含量增加会显著降低粘度，温度降低则粘度呈指数增加）。这比单纯记忆定义（等级1）要求更高的理解深度，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 128, + "question": "What is the process of polymer structure formation in silicate melts?", + "answer": "The formation of polymers is based on the silicon-oxygen tetrahedron as the fundamental unit, forming aggregates of varying sizes. It can be divided into three stages: Initial stage: The breakdown of quartz, where the framework [Si0_{4}] fractures, forming polymers of varying degrees of polymerization in the melt. Middle stage: Polycondensation accompanied by deformation—linear polymers tend to rotate around the Si-O axis while bending, layered polymers cause the layers themselves to wrinkle and warp, framework polymers exhibit increased thermal defects, and the Si-O-Si bond angles change. [Si0_{4}]Na_{4} + [Si_{2}0_{7}]Na_{6} → [Si_{3}0_{10}]Na_{8} + Na_{2}O (short bond) 3[Si_{3}0_{10}]Na_{8} → [Si_{6}0_{18}]Na_{12} + 2Na_{2}O (six-membered ring). Final stage: Within a certain time and temperature range, polymerization and depolymerization reach equilibrium. The Na_{2}O released by polycondensation can further erode the quartz framework, breaking it down into oligomers, and this cycle continues until the system reaches a breakdown-polycondensation equilibrium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物在硅酸盐熔体中的结构形成过程，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求详细解释硅酸盐熔体中聚合物结构形成的三个阶段，涉及硅氧四面体的聚合、变形和平衡过程，需要综合运用多个概念并进行机理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解硅酸盐熔体中聚合物结构形成的复杂过程，包括三个阶段的具体机理和化学反应。正确选项不仅需要掌握硅氧四面体的基本单元概念，还需理解聚合、解聚平衡的动态过程，以及中间阶段的各种聚合物形态变化和化学反应方程式。这种题目在选择题型中极为少见，因为它要求考生具备高度的综合运用能力、推理分析能力和机理解释能力，远超一般选择题的知识点掌握深度和解题步骤复杂程度。" + }, + { + "idx": 129, + "question": "Analyze the reason why monovalent alkali metal oxides reduce the viscosity of silicate melts.", + "answer": "Generally, alkali metal oxides (Li2O, Na2O, K2O, Rb2O, Cs2O) can reduce melt viscosity. These cations, due to their small charge, large radius, and weak interaction with O2-, provide 'free oxygen' in the system, increasing the O/Si ratio. This causes the original silicon-oxygen anion groups to depolymerize into simpler structural units, thereby reducing the activation energy and decreasing viscosity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析碱金属氧化物降低硅酸盐熔体粘度的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析碱金属氧化物降低硅酸盐熔体粘度的原因，涉及离子特性（小电荷、大半径、弱相互作用）、氧硅比变化、硅氧阴离子基团的解聚以及活化能降低等多个方面的综合分析和机理解释。这需要深入理解材料科学中的结构-性能关系，并进行多因素的推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握碱金属氧化物的基本性质，还需要深入理解硅酸盐熔体粘度的变化机理。题目涉及多个复杂概念的综合运用，包括阳离子特性（电荷、半径）、氧硅比变化、硅氧阴离子基团的解聚过程以及活化能的影响机制。这种需要从微观结构角度解释宏观性质变化的题目，在选择题型中属于对知识深度和综合分析能力要求极高的类型。" + }, + { + "idx": 130, + "question": "Describe the structural and property characteristics of quartz crystals", + "answer": "
StructureRegular ordered arrangement, long-range order
Properties
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述石英晶体的结构和性质特征，需要文字解释和论述，答案以表格形式呈现了结构和性质的特点，符合简答题的特征。 | 知识层次: 题目主要考查对石英晶体结构和性质的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目要求考生描述石英晶体的结构和性质特征，属于概念解释和描述的难度等级。虽然题目涉及两个方面的内容（结构和性质），但每个方面都是基础概念的记忆和简单描述，不需要复杂的分析或比较。因此，在选择题型内属于中等难度。" + }, + { + "idx": 131, + "question": "The above data were obtained under constant pressure. If obtained under constant volume, do you think the activation energy would change? Why?", + "answer": "If obtained under constant volume, the activation energy would not change. Because activation energy is the energy required for liquid particles to undergo linear motion. It is related to the melt composition and the degree of [Si04] polymerization in the melt.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在恒容条件下活化能不会改变，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解活化能的概念，并分析其在恒压和恒容条件下的变化。虽然涉及基础概念，但需要将活化能与熔体组成和[Si04]聚合程度关联起来，进行一定的综合分析。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解活化能的定义及其与实验条件（恒压与恒容）的关系。其次，需要考生能够分析活化能的本质（液体粒子线性运动所需的能量）以及其与熔体组成和[Si04]聚合度的关联。这涉及多个概念的关联和综合分析，超出了简单的记忆或单一概念的应用。因此，在选择题型中，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 132, + "question": "What are the structural differences between crystalline SiO2, SiO2 glass, silica gel, and SiO2 melt?", + "answer": "Crystalline SiO2—particles are arranged regularly in three-dimensional space, exhibiting anisotropy; SiO2 glass—isotropic; silica gel—loose and porous; SiO2 melt—internal structure is framework-like, with short-range order and long-range disorder.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对不同形态的SiO2进行结构差异的描述，需要文字解释和论述，答案也是以文字形式呈现的详细解释，符合简答题的特征。 | 知识层次: 题目主要考查对四种不同形态SiO2结构特点的记忆和理解，属于基础概念的记忆性知识，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及四种不同形态的SiO2，但正确选项已经明确列出了它们各自的结构特点，考生只需记忆并区分这些基本概念即可。不需要进行复杂的分析或推理，属于概念解释和描述的层次。" + }, + { + "idx": 133, + "question": "Describe the structural and property characteristics of Na2O·2SiO2 melt", + "answer": "
StructureSix-membered or eight-membered rings, long-range disorder
PropertiesHigh electrical conductivity, high surface tension
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述Na2O·2SiO2熔体的结构和性能特征，需要文字解释和论述。答案以表格形式呈现了结构和性能的具体特点，符合简答题的特征。 | 知识层次: 题目要求描述Na2O·2SiO2熔体的结构和性能特征，涉及对材料结构（如六元环或八元环、长程无序）和性能（如高电导率、高表面张力）的综合分析，需要理解并关联多个概念，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅要掌握Na2O·2SiO2熔体的基本结构特征（如六元环或八元环、长程无序），还需要理解其相关性能特点（如高电导率、高表面张力）。这涉及到多步概念关联和综合分析，属于中等应用层次的知识。虽然题目提供了正确选项，但需要考生在选择题型内进行多角度分析，将结构和性能特征联系起来，因此难度较高，属于等级4。" + }, + { + "idx": 134, + "question": "Can glass be formed by rapid quenching at 1050°C?", + "answer": "At this temperature, rapid quenching can form glass.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（玻璃是否可以通过在1050°C快速淬火形成），答案直接给出了对错判断。 | 知识层次: 题目考查玻璃形成的基本原理和温度条件的记忆，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅涉及玻璃形成的基本原理和温度条件的记忆性知识，不需要深入理解或复杂分析。正确选项直接陈述了基础概念，属于最基础层次的难度。" + }, + { + "idx": 135, + "question": "CeO2 has a fluorite structure. When 15 mol% CaO is added to form a solid solution, the measured density of the solid solution is d = 7.01 g/cm³, and the unit cell parameter is a = 0.5417 nm. Determine through calculation which type of solid solution is formed. The atomic weights are Ce 140.12, Ca 40.08, O 16.00.", + "answer": "For the CaO-CeO2 solid solution, from the perspective of maintaining electrical neutrality, it can form either an oxygen vacancy solid solution or a solid solution with Ca²⁺ embedded in the anion interstitial sites. The solid solution equations are as follows: For substitutional solid solution, x = 0.15, 1 - x = 0.85, 2 - x = 1.85, so the chemical formula of the substitutional solid solution is Ca0.15Ce0.85O1.85. Since CeO2 has a fluorite structure, the number of unit cell molecules Z = 4, and the unit cell contains three types of ions: Ca²⁺, Ce⁴⁺, and O²⁻. The mass of the unit cell is: W = ΣWi = [4 × (0.15/1) × MCa²⁺ + 4 × (0.85/1) × MCe⁴⁺ + 8 × (1.85/2) × MO²⁻] / 6.022 × 10²² = 102.766 × 10⁻²² g. The calculated density dR = W/V = 0.6465 g/cm³. For interstitial solid solution, the chemical formula is Ca2Ce1-yO2. Compared with the given composition Ca0.15Ce0.85O1.85, the O²⁻ content differs: Ca0.15Ce0.85O1.85 → Ca0.15×2/1.85Ce0.85×2/1.85O2. y = 0.15 × 2 / 1.85, 1 - y = 0.85 × 2 / 1.85 ⇒ y = 0.15 / 1.85. The chemical formula of the interstitial solid solution is Ca0.15×2/1.85Ce1.7/1.85O2. Similarly, the calculated density dg = W/V = 7.033 g/cm³. The measured density is d = 7.01 g/cm³, which is close to d2. Therefore, an interstitial solid solution is formed, with interstitial Ca²⁺ ions present.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算确定形成的固溶体类型，涉及密度、晶胞参数和原子量的计算，答案中展示了详细的公式应用和数值计算过程。 | 知识层次: 题目需要进行多步计算，包括化学式的推导、单位晶胞质量的计算、密度的计算等，同时需要理解固溶体的形成机制和电中性原则，涉及多个概念的关联和综合分析。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和概念关联。需要考生掌握固体溶液的形成机制、密度计算、晶胞参数与化学组成的关联等知识点，并进行综合分析。计算过程涉及多个变量和步骤，包括化学式的推导、单位晶胞质量的计算、密度的比较等，对考生的综合能力和计算精度要求较高。" + }, + { + "idx": 136, + "question": "The viscosity of SiO2 melt is 10^14 Pa·s at 1000°C and 10^7 Pa·s at 1400°C. What is the activation energy for viscous flow of SiO2 glass?", + "answer": "According to the formula: η=η0exp(ΔE/RT)\\nAt 1000°C, η=10^14 Pa·s, T=1000+273=1273 K\\nAt 1400°C, η=10^7 Pa·s, T=1400+273=1673 K\\nSolving the two equations simultaneously yields: η0=5.27×10^-16 Pa·s\\nΔE=713.5 kJ/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解SiO2玻璃的粘流活化能，答案中包含了具体的计算步骤和结果。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及温度转换和联立方程求解，属于中等应用层次。虽然不涉及复杂的概念关联或综合分析，但需要一定的计算能力和公式应用技巧。 | 难度: 在选择题中属于中等难度，需要理解粘度与温度的关系公式，进行多步计算（包括温度转换和联立方程求解），并综合分析结果。虽然题目提供了公式和步骤，但计算过程较为复杂，涉及对数运算和单位转换，对学生的计算能力和概念理解有一定要求。" + }, + { + "idx": 137, + "question": "The melt viscosity is 10^7 Pa·s at 727°C and 10^3 Pa·s at 1156°C. At what temperature will it be 10^6 Pa·s?", + "answer": "According to logη=A+B/T, at 727°C, η=10^7 Pa·s, the equation gives: log10^7=A+B/(727+273) (1). At 1156°C, η=10^3 Pa·s, the equation gives: log10^3=A+B/(1156+273) (2). Solving equations (1) and (2) simultaneously yields A=-6.32 and B=13324. When η=10^6 Pa·s, log10^6=-6.32+13324/(t+273), solving gives t=808.5°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定温度下的熔体粘度，解答过程涉及对数运算和联立方程的求解，属于典型的计算题类型。 | 知识层次: 题目需要应用粘度与温度关系的公式，并进行多步计算和联立方程求解，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解粘度与温度的关系公式（logη=A+B/T），并能够建立两个方程联立求解未知参数A和B。随后还需代入新的粘度值求解温度，涉及多步计算和代数运算。虽然题目提供了明确的解题路径，但步骤较多且需要一定的数学技巧，因此在选择题型内属于综合性计算问题。" + }, + { + "idx": 138, + "question": "A melt has a viscosity of 310Pa·s at 1300℃ and 10^7Pa·s at 800℃. What is its viscosity at 1050℃?", + "answer": "According to logη=A+B/(T+273), at 1300℃, η=310Pa·s, the formula gives: log310=A+B/(1300+273)①; at 800℃, η=10^7Pa·s, the formula gives: log10^7=A+B/(800+273)②. Solving equations ① and ② simultaneously yields A=−7.2, B=15219.6. When t=1050℃, logη=−7.2+15219.6/(1050+273), solving gives η=20130.5Pa·s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定温度下的粘度值，解答过程涉及对数运算和方程求解，属于典型的计算题。 | 知识层次: 题目需要应用粘度与温度关系的公式，进行多步计算和联立方程求解，涉及中等难度的数学运算和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解粘度与温度的关系公式，并进行多步计算。题目要求解两个方程以确定常数A和B，然后代入新的温度值计算粘度。虽然计算步骤较多，但在选择题型中，正确选项提供了明确的解题路径，减少了推导的复杂性。" + }, + { + "idx": 139, + "question": "The viscosity of Pyrex glass is 10^9 Pa·s at 1400°C and 10^13 Pa·s at 840°C. To facilitate forming, approximately what temperature is required for the glass to reach a viscosity of 10^5 Pa·s?", + "answer": "According to the formula: η = η0 exp(ΔE / (R T)). Given η0 = 11.22 Pa·s and ΔE = 254.62 kJ/mol. When η = 10^5 Pa·s, 10^5 = 11.22 exp(254.62 × 1000 / ((273 + t) × 8.314)). Solving gives t = 3094.2°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，以求解特定温度值。答案展示了详细的公式应用和计算过程，符合计算题的特征。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及对数运算和温度转换，需要理解粘度与温度的关系并正确应用公式。虽然不涉及复杂的综合分析或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于高难度题目，需要理解粘度与温度的复杂关系，应用阿伦尼乌斯公式进行多步计算，涉及对数运算和温度转换，且需要处理较大的数值范围和单位换算。解题过程需要较强的综合分析能力和数学运算技巧，超出了选择题常见的简单计算或概念判断的范畴。" + }, + { + "idx": 140, + "question": "The viscosity of Pyrex glass is 10^9 Pa·s at 1400℃ and 10^13 Pa·s at 840℃. What is the activation energy for viscous flow?", + "answer": "According to the formula: η = η0 exp(ΔE / (R T)). At 1400℃, η = 10^9 Pa·s, T = 1400 + 273 = 1673 K, 10^9 = η0 exp(ΔE / (1673 × 8.314)). At 840℃, η = 10^13 Pa·s, T = 840 + 273 = 1113 K, 10^13 = η0 exp(ΔE / (1113 × 8.314)). Solving the two equations simultaneously yields: η0 = 11.22 Pa·s, ΔE = 254.62 kJ/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的粘度和温度数据，应用阿伦尼乌斯公式进行数值计算，求解粘性流动的活化能。答案涉及公式推导和数值计算过程，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、对数运算和联立方程求解，属于中等应用层次。虽然不涉及复杂的机理分析，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解粘度与温度的关系公式，并进行多步计算和方程联立求解。虽然题目提供了具体数值，但解题过程涉及对数运算和单位转换，对学生的计算能力和概念理解有一定要求。" + }, + { + "idx": 141, + "question": "From the following two glaze formulas, determine the difference in their melting temperatures? Explain the reason. Glaze formula 1: 0.2K2O 0.2Na2O 0.4CaO 0.2PbO 0.3Al2O3 2.1SiO2; Glaze formula 2: 0.2K2O 0.2MgO 0.6CaO 1.1Al2O3 10.0SiO2", + "answer": "(2) The melting temperature of glaze formula 1 > the melting temperature of glaze formula 2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种釉配方的熔化温度差异并解释原因，需要文字解释和论述，而不是简单的选择、判断或计算 | 知识层次: 题目要求比较两种釉料配方的熔化温度差异并解释原因，这涉及到对釉料成分及其对熔化温度影响的理解和应用。需要分析不同氧化物（如K2O、Na2O、CaO、PbO、MgO、Al2O3、SiO2）在釉料中的作用及其对熔化温度的影响，属于多步计算和概念关联的综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较两种釉料配方的熔融温度差异，并解释原因。这涉及到对釉料成分（如K2O、Na2O、CaO、PbO、Al2O3、SiO2等）及其对熔融温度影响的理解。虽然题目提供了具体的配方，但需要考生能够识别关键成分（如PbO的助熔作用、Al2O3和SiO2的提高熔融温度作用）并进行综合分析。此外，还需要进行多步计算和概念关联，但因为是选择题，正确选项已经给出，减少了部分难度。" + }, + { + "idx": 142, + "question": "A borosilicate glass used for sealing lamps has an annealing point of 544°C and a softening point of 780°C. Calculate the activation energy for viscous flow of this glass.", + "answer": "According to the formula: η=η0exp(ΔE/RT). At the annealing point of 544°C, η=1.0×10^12 Pa·s, T=544+273=817K; at the softening point of 780°C, η=4.5×10^6 Pa·s, T=780+273=1053K. Solving the simultaneous equations gives: η0=1.39×10^-12 Pa·s, ΔE=373.13 kJ/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的温度和粘度数据，应用公式计算玻璃的粘流活化能，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用粘性流动的Arrhenius方程进行多步计算，涉及两个温度点的数据联立求解，需要理解活化能的概念和公式转换，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解粘性流动的激活能计算公式，并能够正确转换温度单位（摄氏到开尔文）。解题过程涉及解联立方程，需要一定的数学能力和对公式的理解。虽然题目提供了关键数据点，但计算步骤较多，容易在单位转换或方程求解中出现错误。" + }, + { + "idx": 143, + "question": "From the following two glaze formulas, determine the difference in surface tension between them? Explain the reason. Glaze formula 1: 0.2K2O 0.2Na2O 0.4CaO 0.2PbO 0.3Al2O3 2.1SiO2; Glaze formula 2: 0.2K2O 0.2MgO 0.6CaO 1.1Al2O3 10.0SiO2", + "answer": "(3) Difference in surface tension: The surface tension of glaze formula 1 < the surface tension of glaze formula 2, because the O/Si ratio of glaze formula 1 is less than that of glaze formula 2, and glaze formula 1 contains PbO and B2O3, which can reduce surface tension.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种釉料配方的表面张力差异，并说明原因。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种釉配方的表面张力差异，并解释原因。这需要理解表面张力与釉组成（如O/Si比、PbO和B2O3的存在）之间的关系，涉及多步分析和概念关联。虽然不涉及复杂的计算，但需要对材料科学中的基本原理有较好的理解，并能综合应用这些知识来解答问题。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生计算两种釉料配方的O/Si比，并理解PbO和B2O3对表面张力的影响。虽然题目提供了具体配方，但需要考生具备一定的材料科学知识，能够进行多步计算和综合分析。" + }, + { + "idx": 144, + "question": "A borosilicate glass used for sealing lighting lamps has an annealing point of 544°C, a softening point of 780°C, and a viscous flow activation energy of 373.13 kJ/mol. Determine its working range.", + "answer": "The working temperature range viscosity is generally 10^3~10^7 Pa·s. According to the formula T=ΔE/(R·ln(η/η0)): when η=10^3 Pa·s, T=1033.6K=760.6°C; when η=10^7 Pa·s, T=1038.9°C. Therefore, the working temperature range is 760.6°C~1038.9°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（退火点、软化点、粘流活化能）和公式计算玻璃的工作温度范围，答案是通过数值计算得出的具体温度区间，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式的应用和温度单位的转换，需要理解粘度和温度之间的关系，并进行综合分析以确定工作温度范围。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃工作温度范围的概念，掌握粘度与温度的关系公式，并进行多步计算。虽然题目提供了必要的参数，但需要考生综合运用这些信息进行计算和分析，涉及中等应用层次的知识点。" + }, + { + "idx": 145, + "question": "The working range of a certain type of glass is from $870^{\\\\circ}\\\\mathrm{C}$ ($\\\\eta=10^{6}\\\\mathrm{{Pa}\\\\cdot{}}$) to $1300^{\\\\circ}\\\\mathrm{C}$ ($\\\\eta=10^{2.5}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$). Estimate its annealing point ($\\\\eta=10^{12}\\\\mathrm{{Pa}\\\\cdot\\\\Delta s}$)?", + "answer": "According to the formula: $\\\\mathfrak{H}=\\\\mathfrak{N}_{0}\\\\exp(\\\\frac{\\\\Delta\\\\mathcal{E}}{R T})$ \\n\\nAt $870^{\\\\circ}\\\\mathrm{C}$, $\\\\eta=10^{6}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$, T=870+273=1143K, $10^{6}=1.57\\\\times10^{-7}\\\\exp[\\\\frac{280.16\\\\times1000}{1143\\\\times8.314}]$ (1) \\nAt $1300^{\\\\circ}\\\\mathrm{C}$, $\\\\eta=10^{2.5}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$ (2) \\nBy solving equations (1) and (2) simultaneously, we get: $\\\\mathfrak{V}_{0}=1.57\\\\times\\\\ensuremath{10^{-7}}\\\\mathrm{Pa}\\\\cdot\\\\mathrm{s}$, $\\\\Delta E=280.16\\\\mathrm{kJ/mol}$ \\nWhen $\\\\eta=10^{12}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$, $10^{12}=1.57\\\\times10^{-7}\\\\exp[\\\\frac{280.16\\\\times1000}{(273+t)\\\\times8.314}]$ \\nSolving gives $t=505.15^{\\\\circ}\\\\mathrm{C}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计玻璃的退火点，解答过程中涉及多个步骤的数学计算和方程求解。 | 知识层次: 题目需要应用粘度-温度关系的公式进行多步计算，涉及对数运算和方程求解，同时需要理解粘度与温度之间的关系，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和多个变量的综合分析。需要理解并应用粘度与温度关系的公式，同时进行对数运算和方程求解。解题步骤包括：" + }, + { + "idx": 146, + "question": "What are the kinetic factors affecting the glass formation process?", + "answer": "The key factor affecting glass formation is the cooling rate of the melt. Whether the melt crystallizes or forms glass is related to the degree of supercooling, viscosity, nucleation rate, and crystal growth rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响玻璃形成过程的动力学因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响玻璃形成过程的动力学因素，涉及多个相关概念（冷却速率、过冷度、粘度、成核速率、晶体生长速率）的关联和综合分析，需要理解这些因素之间的相互作用及其对玻璃形成的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念（冷却速率、过冷度、粘度、成核速率和晶体生长速率）并进行综合分析。虽然题目涉及多个因素，但在选择题型中只需识别关键因素，不需要进行多步计算或深度关联性分析。" + }, + { + "idx": 147, + "question": "What are the crystallochemical factors affecting the glass formation process?", + "answer": "The crystallochemical factors affecting glass formation include: the size and arrangement of complex anion groups, bond strength, and bond type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述影响玻璃形成的结晶化学因素，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对玻璃形成过程中结晶化学因素的综合分析，需要理解并关联多个概念（如复杂阴离子基团的尺寸和排列、键强度和键类型），并进行一定程度的解释和论述。这超出了单纯记忆基础概念的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及玻璃形成过程中的结晶化学因素，包括复杂阴离子基团的大小和排列、键强度和键类型等概念。虽然不需要多步计算，但需要对多个概念进行关联和综合分析，才能正确理解并选择答案。" + }, + { + "idx": 148, + "question": "From the following two glaze formulas, determine the difference in viscosity between the two? Explain the reason. Glaze formula 1: 0.2K2O 0.2Na2O 0.4CaO 0.2PbO 0.3Al2O3 2.1SiO2; Glaze formula 2: 0.2K2O 0.2MgO 0.6CaO 1.1Al2O3 10.0SiO2", + "answer": "(1) Difference in viscosity\\nFor glaze formula 1:\\n∵(K2O+Na2O+CaO+PbO)/Al2O3=(0.2+0.2+0.4+0.2)/0.3=3.33>1, Al3+ acts as a network-forming ion,\\nR1=(0.2+0.2+0.4+0.2+0.3×3+2.1×2+0.5×3)/(0.3×2+2.1+0.5×2)=2.05\\nX1=2×2.05-4=0.1\\nY1=4-0.1=3.9\\nFor glaze formula 2:\\n∴(K2O+MgO+CaO)/Al2O3=(0.2+0.2+0.6)/1.1=0.910<1, Al3+ is considered a network-modifying ion\\nR2=(0.2+0.2+0.6+1.1×3+10×2)/10.0=2.43\\nX2=2×2.43-4=0.86\\nY2=4-0.86=3.14\\nThat is: Y of glaze formula 1 > Y of glaze formula 2, so at high temperatures, the viscosity of glaze formula 1 > the viscosity of glaze formula 2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算两个釉料配方的粘度差异，并解释原因。答案中包含了详细的数值计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括氧化物比例计算、R值计算、X和Y值计算，并需要理解Al3+在网络结构中的作用变化。虽然涉及公式应用，但需要综合分析不同氧化物的影响，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如网络形成离子和网络修饰离子的作用）并进行多步计算（包括摩尔比例计算、R值计算、X和Y值计算）。虽然题目提供了正确选项，但解题过程涉及综合分析不同釉料配方的粘度差异，需要较强的概念关联能力和计算能力。" + }, + { + "idx": 150, + "question": "Compare which of the two types of glass has higher viscosity at high temperature?", + "answer": "V1>V2, Glass No.1 has higher viscosity at high temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种玻璃在高温下的粘度，并给出具体结论，需要文字解释和论述，而不是简单的选择或判断。答案也以文字形式呈现，说明具体哪种玻璃的粘度更高。 | 知识层次: 题目要求比较两种玻璃在高温下的粘度高低，需要对玻璃粘度的基本概念有理解，并能够应用相关知识进行综合分析。虽然不涉及复杂的计算或推理，但需要对材料性质有一定的理解和比较能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解玻璃粘度与高温性能的关系，并进行比较分析。题目涉及多步计算和概念关联，但选项明确给出了比较结果，降低了部分分析难度。" + }, + { + "idx": 151, + "question": "Calculate the structural parameters of Glass No. 2, with the composition of Na2O 10 mol%, CaO 0 mol%, Al2O3 20 mol%, SiO2 60 mol%, B2O3 10 mol%", + "answer": "No. 2: Z=4, (Na2O+CaO)/Al2O3=(10+0)/20=0.5<1, Al3+ is considered as a network modifier ion. R1=(10+60+120+30)/(60+20)=2.75. X2=2R-Z=1.5. Y2=4-1.5=2.5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算玻璃的结构参数，涉及多个数值计算和公式应用（如Z值、R1值、X2值、Y2值的计算），答案也以数值结果和公式推导的形式呈现。 | 知识层次: 题目需要进行多步计算，包括结构参数的计算和网络修饰离子的判断，涉及多个公式的应用和概念关联，需要综合分析玻璃组成与结构参数之间的关系。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如网络修饰离子、结构参数计算）并进行多步骤计算（包括摩尔比例计算、结构参数R1/X2/Y2推导）。虽然题目提供了明确的计算公式，但需要综合应用玻璃化学组成分析和结构参数计算知识，涉及中等应用层次的知识点关联和综合分析能力。" + }, + { + "idx": 152, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass $\\mathrm{_{6}(1)N a_{2}O\\bullet S i0_{2}}$", + "answer": "Z=4, R=3/1=3, X=2R-Z=6-4=2, Y=8-2R=8-6=2. Non-bridging oxygen %=2/(1+2)=66.7%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含具体的计算步骤和结果（如Z=4, R=3/1=3等），符合计算题的特征。 | 知识层次: 题目涉及多步计算（结构参数和非桥氧分数计算），需要理解并应用玻璃结构参数的计算公式（如Z、R、X、Y的计算），以及非桥氧分数的概念和计算方法。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算步骤，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃结构参数计算的基本概念（如Z、R、X、Y的含义），掌握多步计算公式（包括非桥氧百分比的计算），并能正确应用这些公式进行综合计算。题目涉及多个变量的关联计算，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 153, + "question": "Which substances can form non-crystalline solids (NCS)?", + "answer": "Melts and glassy solids can form non-crystalline solids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪些物质可以形成非晶态固体，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对非晶态固体形成物质的基础概念记忆和理解，属于定义和分类的基本知识。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即非晶态固体（NCS）的形成物质类型。正确选项直接给出了明确的定义性答案（熔体和玻璃态固体），无需任何推理或分析过程。这属于最基础的定义识别类题目，完全符合等级1\"基本定义简答\"的特征。在选择题难度谱系中，此类只需机械记忆即可作答的题目属于最低难度层级。" + }, + { + "idx": 154, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass $\\mathrm{(3)Na_{2}0\\bullet_{}1/3A l_{2}O_{3}\\bullet S i O_{2}}$", + "answer": "Al2O3>1, Al3+ is considered as a network-forming ion. Z=4, R=(1+1+2)/(2*(2/3)+1)=2.4, X=2R-Z=4.8-4=0.8, Y=4-0.8=3.2. Non-bridging oxygen %=0.8/(1.6+0.8)=33.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，如结构参数和非桥氧分数的计算过程。 | 知识层次: 题目需要进行多步计算（结构参数计算、非桥氧分数计算），涉及网络形成离子概念的应用和公式推导（Z=4, R计算等），需要综合分析玻璃组成与结构参数的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如网络形成离子、结构参数计算、非桥氧分数等）并进行多步骤计算（包括Z、R、X、Y值的计算以及非桥氧百分比的推导）。虽然题目提供了明确的公式和步骤，但需要较强的综合分析能力和对玻璃结构化学的深入理解才能正确解答。" + }, + { + "idx": 156, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass with the composition $\\mathrm{(4)18Na_{2}0\\cdot10C a0\\cdot72S i0_{2}}$ (wt%)", + "answer": "Na2O: 18%, 0.290 mol, 17.4 mol%; CaO: 10%, 0.179 mol, 10.7 mol%; SiO2: 72%, 1.200 mol, 71.9 mol%. Z=4, R=(17.4+10.7+71.9*2)/71.9=2.39, X=2R-Z=0.78, Y=4-0.78=3.22. Non-bridging oxygen %=0.78/(1.61+0.78)=32.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括摩尔分数、结构参数Z、R、X、Y的计算以及非桥氧百分比的推导。答案中给出了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括摩尔分数计算、结构参数Z、R、X、Y的推导，以及非桥氧百分比的求解。这需要综合运用材料科学中的玻璃组成计算和结构参数分析知识，涉及多个概念和公式的关联应用，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如摩尔分数、结构参数Z/R/X/Y、非桥氧比例）并进行多步骤计算（包括摩尔转换、结构参数推导、比例计算等）。虽然题目提供了正确选项，但解题过程涉及综合应用玻璃化学知识，且计算步骤之间存在逻辑关联性，属于典型的综合性计算问题。" + }, + { + "idx": 157, + "question": "For glass No. 1 with the composition of Na2O 8 wt%, Al2O3 12 wt%, and SiO2 80 wt%, use the glass structural parameters to explain the magnitude of its viscosity at high temperatures?", + "answer": "For No. 1: Z=4 Na2O/Al2O3=8.16/7.47>1 Al2O3 is considered as a network-forming ion R=(8.16+7.47×3+84.37×2)/(7.47×2+84.37)=2.007 X1=2R−Z=0.014 Y1=4−X=3.986 Y1=3.986, therefore, the viscosity of No. 1 at high temperatures is high.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用玻璃结构参数来解释高温粘度的大小，答案提供了详细的参数计算和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求运用玻璃结构参数（如Z、R、X1、Y1等）进行多步计算和综合分析，解释高温粘度的变化机理。这需要深入理解玻璃结构参数之间的关系及其对粘度的影响，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求综合运用玻璃结构参数（如Z、R、X1、Y1等）进行复杂计算和推理分析，以解释高温粘度的变化机理。解题步骤涉及多个参数的转换和计算，需要深入理解网络形成离子、网络修饰离子等概念，并能将这些概念与粘度变化机理联系起来。这种综合运用和深度分析的要求在选择题型中属于最高难度等级。" + }, + { + "idx": 158, + "question": "A glass composition (wt%) is Na2O 14%, CaO 13%, SiO2 73%, with a density of 2.5 g/cm3. If soda ash, limestone, and quartz sand are used as raw materials to melt this glass with 1000 kg of quartz sand, how much of the other two raw materials are needed?", + "answer": "With 1000 kg of quartz sand, the required soda ash (Na2CO3) is: (14/73)×1000×(106/62)=327.88 kg. The required limestone (CaCO3) is: (13/73)×1000×(100/56)=318.00 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定所需的原材料数量。答案中给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量百分比的转换、分子量的计算以及原料用量的推导。虽然不涉及复杂的机理分析或创新设计，但需要综合运用化学计量和材料组成知识，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃成分的化学计量关系，进行多步计算（包括分子量转换和比例计算），并综合分析原料与最终成分之间的关联。虽然题目提供了明确的解题路径，但涉及多个计算步骤和概念转换，对学生的应用能力和计算准确性要求较高。" + }, + { + "idx": 160, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass (2) Na2O•CaO•Al2O3•SiO2", + "answer": "Na2O+CaO/(2*Al2O3)=2>1, Al is considered as a network-forming ion. Z=4, R=(1+1+3+2)/(2+1)=2.33, X=2R-Z=4.66-4=0.66, Y=4-0.66=3.34. Non-bridging oxygen %=0.66/(1.67+0.66)=28.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及结构参数和非桥氧分数的计算，答案以数值结果呈现。 | 知识层次: 题目需要进行多步计算，涉及结构参数和非桥氧分数的计算，需要理解网络形成离子的概念，并应用相关公式进行综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如网络形成离子、结构参数计算、非桥氧分数等）并进行多步骤计算（包括比值判断、Z值计算、R值计算、X/Y值推导等）。虽然题目提供了正确选项，但解题过程涉及多个关联概念和综合计算步骤，超出了基础选择题的单一知识点考察范围。" + }, + { + "idx": 161, + "question": "Does this composition have a tendency to form glass? Why?", + "answer": "This composition has a tendency to form glass because the structure maintains a three-dimensional framework at this point, and the viscosity of the glass is still relatively high, making it easy to form glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么该成分有形成玻璃的倾向，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释特定成分形成玻璃的倾向性，需要综合运用材料科学中的玻璃形成理论、结构分析和粘度特性等知识，进行推理分析和机理解释。这超出了简单记忆或基本应用，属于较复杂的分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 162, + "question": "Among the following three substances, which one is the least likely to form glass, and why? (1) Na2O·2SiO2; (2) Na2O·SiO2; (3) NaCl", + "answer": "(3) NaCl is the least likely to form glass. NaCl lacks a network structure and is a typical ionic crystal, making it difficult to form glass.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从三个选项中选择最不可能形成玻璃的物质，并解释原因，符合选择题的特征 | 知识层次: 题目要求考生理解玻璃形成的基本原理（网络结构），并能够分析不同物质的化学组成和结构特点（离子晶体vs硅酸盐），从而判断其形成玻璃的能力。这需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要综合应用多个概念进行分析判断。题目要求考生不仅了解玻璃形成的基本原理（网络结构的重要性），还需要比较三种不同物质的结构特性（硅酸盐网络结构 vs 离子晶体结构），并做出正确判断。解题过程涉及材料科学中玻璃形成能力的核心概念，需要将晶体结构知识与玻璃形成条件进行关联分析，属于复杂分析过程的判断题型。" + }, + { + "idx": 163, + "question": "Among the following three substances, which one is most likely to form glass, and why? (1) Na2O·2SiO2; (2) Na2O·SiO2; (3) NaCl", + "answer": "(1) Na2O·2SiO2 is most likely to form glass. Calculations show that R1=2.5, Y1=3. At high temperatures, (1) has high viscosity and is prone to form glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么某个物质最可能形成玻璃，需要文字解释和论述，而不是简单的选择或判断。答案中包含了理论依据（R1=2.5, Y1=3）和物理解释（高粘度易形成玻璃），符合简答题的特征。 | 知识层次: 题目要求考生不仅知道玻璃形成的条件，还需要通过计算R1和Y1值来比较不同物质的玻璃形成能力，涉及多步计算和概念关联。虽然不需要复杂的推理分析，但需要综合分析不同物质的组成和性质，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解玻璃形成的基本原理（如粘度、网络形成体与修饰体的比例关系），并能通过R1和Y1的计算结果进行综合分析。题目要求比较三种物质的玻璃形成倾向，涉及多步计算和概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 164, + "question": "Briefly describe the differences in structure and properties between tempered glass and annealed glass.", + "answer": "Glass that eliminates and balances internal stresses caused by temperature gradients is called annealed glass, which is less prone to breakage and easier to cut. Tempering involves heating the product to near its softening temperature to fully anneal the glass, followed by rapid cooling (quenching). This creates uniform internal stresses, resulting in pre-compressive stresses on the glass surface, thereby increasing resistance to bending, impact, and torsional deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述两种玻璃在结构和性能上的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对退火玻璃和钢化玻璃的基本定义、结构差异和性能特点的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求考生能够理解和描述两种玻璃的结构和性质差异。虽然涉及多个概念（如内部应力、热处理过程等），但主要是基于基础概念的记忆和简单解释，不需要复杂的分析或推理。因此属于中等难度。" + }, + { + "idx": 165, + "question": "What are the methods for forming non-crystalline solids (NCS)?", + "answer": "Non-crystalline solids can be obtained by supercooling melts and glasses.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释非晶态固体的形成方法，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查非晶态固体形成方法的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即非晶态固体的形成方法。正确选项直接给出了明确的答案，无需复杂的推理或分析。学生只需记住相关知识点即可正确作答，属于最基本的概念记忆题。" + }, + { + "idx": 166, + "question": "A glass composition (wt%) is Na2O 14%, CaO 13%, SiO2 73%, with a density of 2.5 g/cm3. Calculate the atomic packing factor (AFP) and structural parameter values of this glass?", + "answer": "The average molecular weight of the glass GW=0.14×62+0.13×56+0.73×60.02=59.77. The number of atoms in 1Å3 is n=2.5×10-24×6.02×1023/59.77=0.252 atoms/Å3. The volume occupied by atoms in 1Å3 V=0.0252×4/3π[0.14×2×0.983+0.13×1.063+0.73×0.393+(0.14+0.13+0.73+0.13+0.13)]×1.323=0.4685. AFP=0.46. Structural parameters: Na2O wt% 14, CaO wt% 13, SiO2 wt% 73; mol Na2O 0.23, CaO 0.23, SiO2 1.22; mol% Na2O 13.7, CaO 13.7, SiO2 72.6. R=(13.7+13.7+72.6×2)/72.6=2.38. Z=4. X=2R-Z=2.38×2-4=0.76. Y=Z-X=4-0.76=3.24.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算原子堆积因子（AFP）和结构参数值。答案中提供了详细的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括平均分子量计算、原子数密度计算、原子体积计算以及原子堆积因子计算，同时还需要理解和应用结构参数的概念和公式。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点并进行关联分析。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。需要完成以下高难度步骤：" + }, + { + "idx": 167, + "question": "How much CaO needs to be added to 100g of SiO2 to achieve an O:Si ratio of 2.5?", + "answer": "46.67", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算需要添加的CaO质量），答案是一个具体的数值（46.67），解答过程需要应用化学计量比和分子量计算等公式。 | 知识层次: 题目需要进行多步计算，涉及化学计量比的概念应用和公式推导，需要将O:Si比例要求转化为具体的物质添加量计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解化学计量比的概念，进行多步计算（包括摩尔质量转换和比例计算），并综合分析O:Si比与CaO添加量的关系。虽然题目给出了具体数值条件，但解题过程涉及多个化学概念的综合应用，比单纯记忆或简单计算题更复杂。" + }, + { + "idx": 168, + "question": "By adding $20\\%\\\\mathrm{B}_{2}0_{3}$ to $\\\\mathrm{Si0_{2}}$, calculate the $0:\\\\mathrm{Si}$ ratio of the melt.", + "answer": "S $\\\\frac{{\\\\cal O}}{\\\\bar{\\\\cal S}\\\\bar{\\\\imath}}=\\\\frac{1\\\\times2+0.2\\\\times3}{1+0.2\\\\times2}=1.86$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解O/Si的比例，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及简单的化学计量比计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求计算O/Si比例，涉及基本化学计量和百分比添加的计算。虽然需要应用两个简单的公式（B2O3和SiO2的化学计量关系），但步骤直接且无需复杂推导。在选择题型内，这属于中等偏下难度，因为解题过程清晰且计算简单。" + }, + { + "idx": 169, + "question": "If 50 mol% Na2O is added to SiO2, what is the O:Si ratio?", + "answer": "O/Si = (0.5 + 1 × 2)/1 = 2.5", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定O:Si的比例。答案是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目涉及基本的化学计量计算，只需要应用简单的摩尔比例公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型内，该题目仅需要直接应用基本公式进行简单计算，即通过给定的摩尔百分比直接套用公式计算O:Si比例。解题步骤简单直接，无需多个公式组合或复杂分析，符合等级1的单一公式直接计算要求。" + }, + { + "idx": 170, + "question": "If 10mol% Na2O is added to SiO2, what is the calculated O:Si ratio?", + "answer": "O:Si = (0.1 + 1 × 2)/1 = 2.1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，答案是一个具体的计算结果（O:Si = 2.1），而不是选择、判断或文字解释。 | 知识层次: 题目涉及基本的化学计量计算，只需要应用简单的公式和基本的化学计量知识即可得出答案，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行简单计算，属于单一公式直接计算的难度等级。解题步骤简单明了，无需复杂的分析或组合多个公式。" + }, + { + "idx": 171, + "question": "When Na2O is added to SiO2, making O/Si=2.5, is the crystallization ability enhanced or weakened?", + "answer": "Because O/Si increases, the viscosity decreases, and the crystallization ability is enhanced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Na2O添加到SiO2中导致O/Si=2.5时结晶能力的变化，答案提供了文字解释和论述，说明粘度降低和结晶能力增强的原因，符合简答题的特征。 | 知识层次: 题目需要理解Na2O和SiO2的相互作用对O/Si比的影响，以及O/Si比变化对粘度和结晶能力的影响。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及Na2O和SiO2的反应，以及O/Si比例变化对粘度和结晶能力的影响。虽然题目给出了正确选项，但学生需要掌握相关概念（如O/Si比例、粘度与结晶能力的关系）才能正确选择。这需要一定的综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 172, + "question": "Adding 50mol% Na2O to SiO2, can this ratio form a glass? Why?", + "answer": "Yes, it can form a glass. When 50mol% Na2O is added, although the continuous SiO network skeleton becomes relaxed, it still maintains a three-dimensional network structure, allowing the formation of a glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么50mol% Na2O添加到SiO2中可以形成玻璃，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解Na2O和SiO2在玻璃形成中的作用，并分析特定比例下网络结构的变化，涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解玻璃形成的条件以及Na2O对SiO2网络结构的影响，并进行综合分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了关键分析步骤和结论，降低了答题的复杂程度。" + }, + { + "idx": 173, + "question": "How much Na2O should be added to SiO2 to make the O/Si ratio of the glass equal to 2.5? Assume the amount of SiO2 is ymol.", + "answer": "Let xmol of Na2O be added, then O/Si=(x+2y)/y=2.5. Solving gives x=y/2, meaning when the molar ratio of the two is 1:2, O/Si=2.5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过设定变量和建立方程来求解所需的Na2O量。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的O/Si比例关系进行代数运算，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解O/Si比的概念并正确设置方程，但解题步骤相对直接，仅涉及单一公式的简单代数运算（解一元一次方程）。相比更复杂的多步骤计算或概念组合题，此题的难度较低，属于等级2。" + }, + { + "idx": 174, + "question": "What is surface tension?", + "answer": "Surface tension: the surface constriction force acting perpendicularly on a unit length line segment or the work required to increase an object's surface area by one unit; σ= force/total length (N/m)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"surface tension\"进行文字解释和定义，答案提供了概念描述和公式说明，属于需要文字论述的简答题类型 | 知识层次: 题目考查表面张力的基本定义和单位，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅考察对表面张力基本定义的记忆，属于最基础的概念性知识。正确选项直接给出了表面张力的定义和公式，不需要任何分析或推理过程，完全符合\"基本定义简答\"的难度等级特征。" + }, + { + "idx": 175, + "question": "What is surface energy?", + "answer": "Surface energy: Under constant temperature, pressure, and composition, the non-volume work required to reversibly increase the surface area of a substance is called surface energy; J/m2=N/m", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"surface energy\"进行定义和解释，答案提供了详细的文字描述和单位说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即表面能的定义和单位，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础定义的理解和记忆，即表面能的定义及其单位。题目要求考生识别并选择正确的定义描述，无需进行复杂的分析或推理。因此，在选择题型内属于基本定义简答的难度等级。" + }, + { + "idx": 176, + "question": "What is the difference between surface tension and surface energy in the liquid state?", + "answer": "Liquid: cannot withstand shear stress, the work done by external forces manifests as an expansion of surface area, because surface tension and surface energy are numerically the same", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释表面张力和表面能之间的区别，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查表面张力和表面能的基本概念及其在液态下的关系，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分表面张力和表面能量这两个相关但不同的概念。正确选项要求考生能够识别在液态状态下这两个物理量的数值关系，这超出了简单定义记忆的范畴，属于概念解释和描述的层次。不过题目没有涉及复杂的推导或多概念整合，因此不属于最高难度等级。" + }, + { + "idx": 177, + "question": "Explain based on the structure why the mixture of alkali and wollastonite with 0/Si=3 crystallizes instead of forming glass?", + "answer": "When 0/Si=3, Y=2. For silicate glasses, a three-dimensional network cannot be formed when Y=2 because the number of bridging oxygens shared between tetrahedra is less than 2, and the structure mostly consists of tetrahedral chains of varying lengths. Therefore, the mixture of alkali and wollastonite with 0/Si=3 crystallizes instead of forming glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于结构解释混合物结晶而非形成玻璃的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于结构解释混合物结晶而非形成玻璃的原因，涉及硅酸盐玻璃网络形成的机理分析、桥氧数计算（Y=2）与三维网络形成条件的关联，需要综合运用结构化学和玻璃形成理论进行推理分析，属于机理层面的复杂解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求基于结构解释混合物结晶而非形成玻璃的原因，涉及复杂的硅酸盐网络形成机理和Y值概念。正确选项需要综合理解三维网络形成条件、桥氧数量与Y值关系、以及链状结构对结晶倾向的影响。这种深度机理分析和多因素综合推理在选择题中极为罕见，要求考生具备高阶材料科学知识体系和逻辑推导能力。" + }, + { + "idx": 178, + "question": "Based on the structure, explain why a mixture of alkali and silica with 2<0/Si<2.5 can form glass?", + "answer": "When 2<0/Si<2.5, 390^{\\\\circ},B T\\\\cup\\\\gamma_{\\\\mathrm{SRE}}\\\\times1875^{\\\\circ}$$ So it cannot wet.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解接触角，并判断液体铁是否能润湿氧化铝。答案中包含了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及表面张力和接触角的基本公式应用，通过直接套用公式进行计算即可得出结果，不需要多步计算或综合分析。虽然需要理解表面张力和接触角的概念，但整体思维过程较为直接和简单。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解表面张力和接触角的概念，但解题步骤相对直接，只需套用给定的公式进行计算即可得出答案。不需要复杂的分析或多步骤推理，因此难度等级为2。" + }, + { + "idx": 198, + "question": "From an atomic scale perspective, explain the differences in the bonding effects of welding", + "answer": "Welding: A process where two or more materials (of the same or different types) are permanently joined by heating, applying pressure, or both, to achieve atomic bonding. The conditions during welding include: base material type, plate thickness, groove shape, joint form, restraint state, ambient temperature and humidity, cleanliness, as well as the type and diameter of the welding wire (or electrode), welding current, voltage, welding speed, welding sequence, deposition method, and gun (or electrode) manipulation method determined based on the above factors. If the weld groove or surface has impurities such as oil (paint), water, or rust, they can cause defects like pores, inclusions, slag, or cracks in the weld, posing hazards and potential risks to the welded joint.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释焊接的键合效应差异，需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求从原子尺度解释焊接的键合效应差异，涉及多因素综合分析（材料类型、工艺参数、环境条件等）及其对焊接质量的影响机制，需要深入理解原子键合原理并关联实际焊接条件，属于机理层面的复杂分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求从原子尺度解释焊接的键合效应，涉及复杂的机理分析和综合因素考量。正确选项不仅需要理解焊接的基本定义，还需要掌握多种影响因素（如材料类型、环境条件、工艺参数等）及其相互作用机制。此外，题目还要求分析杂质对焊接缺陷的影响机理，这需要深入的材料科学知识和工程实践经验。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最高难度级别。" + }, + { + "idx": 199, + "question": "Heat treat Si3N4 at the eutectic temperature and measure its thermal etching groove angle as 60°, calculate the grain boundary energy of Si3N4.", + "answer": "γss=2γsvcos(ψ/2)=2×900cos30°=1558.8mN/m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Si3N4的晶界能，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用公式进行计算，涉及多步推理和概念关联（如热蚀刻沟槽角与晶界能量的关系），但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解热处理的背景知识、热蚀刻沟角的概念，并正确应用公式γss=2γsvcos(ψ/2)进行多步计算。虽然题目给出了关键参数（ψ=60°和γsv=900），但需要考生能够正确关联这些概念并执行三角函数计算（cos30°），最终得出精确的晶界能量值。这超出了简单记忆或单步计算的要求，属于需要概念关联和综合分析的题目。" + }, + { + "idx": 200, + "question": "The eutectic of the MgO-Al2O3-SiO2 system is placed on a Si3N4 ceramic plate. At the eutectic temperature, the surface tension of the liquid phase is 900 mN/m, the interfacial energy between the liquid and solid is 600 mN/m, and the measured contact angle is 70.52°. Find the surface tension of Si3N4.", + "answer": "Yv = Ycosθ + Y = 900cos70.52° + 600 = 900 mN/m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Si3N4的表面张力，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用表面张力和接触角的公式进行直接计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目直接给出了所需的公式（Yv = Ycosθ + Y），并且只需要进行简单的代入和计算（代入θ=70.52°和给定的表面张力值）。虽然涉及到了接触角和表面张力的概念，但解题步骤非常直接，无需复杂的推导或分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 201, + "question": "From an atomic scale perspective, explain the differences in the bonding effects of sintering", + "answer": "Sintering: It is a high-temperature treatment process that imparts material properties. The diffusion of atoms to contact points causes bonding between particles, and further diffusion ultimately fills the remaining pores and increases the density of the material. It involves heating powder or powder compacts to a temperature below the melting point of their basic components, followed by cooling to room temperature using specific methods and rates. The result of sintering is the bonding between powder particles, increasing the strength of the sintered body, transforming the aggregate of powder particles into a coalescence of grains, thereby obtaining products or materials with desired physical and mechanical properties. Low-temperature pre-sintering stage: During this stage, metal recovery, volatilization of adsorbed gases and moisture, decomposition, and removal of forming agents in the compact mainly occur. Medium-temperature sintering stage: In this stage, recrystallization begins to appear. Within the particles, deformed grains are restored and reorganized into new grains, while surface oxides are reduced, and sintering necks form at particle interfaces. High-temperature sintering completion stage: In this stage, diffusion and flow proceed sufficiently and near completion, forming a large number of closed pores that continue to shrink, reducing pore size and total porosity, significantly increasing the density of the sintered body.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释烧结过程中的键合效应差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从原子尺度解释烧结过程中的键合效应，涉及多个烧结阶段的详细机理分析，包括原子扩散、颗粒间键合、孔隙填充和密度增加等复杂过程。这需要综合运用材料科学中的扩散理论、热力学和动力学知识，进行深入的推理和机理解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求从原子尺度解释烧结过程中的键合效应，涉及多个复杂阶段（低温预烧结、中温烧结、高温烧结完成阶段）的机理分析。正确选项不仅需要理解扩散、孔隙填充、晶粒重组等微观过程，还需要综合运用材料科学原理对不同温度阶段的物理化学变化进行推理和解释。这种深度机理解释和复杂现象全面分析的要求，远超选择题型的常规知识记忆或简单应用层次，属于选择题型内最高难度的综合推理分析题目。" + }, + { + "idx": 202, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the trend in potential changes of clay after adsorbing the following different cations (use arrows to show: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过箭头符号表示不同阳离子吸附后黏土电位变化的趋势，属于需要文字或符号解释的简答题类型。答案形式为一系列符号排列，而非选择、判断或计算。 | 知识层次: 题目要求对不同阳离子吸附后粘土电位变化的趋势进行排序，这需要理解阳离子电荷、离子半径等基本概念，并能够将这些概念综合应用到具体情境中。虽然不涉及复杂的计算或深度机理分析，但需要对多个因素进行综合考虑和比较，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要考生掌握黏土吸附阳离子的特性及其对电位变化的影响趋势。题目要求考生不仅理解不同阳离子的电荷和离子半径对吸附能力的影响，还需要将这些概念综合起来，进行多步比较和排序。正确选项涉及10种不同阳离子的排序，需要考生对离子特性有深入理解并能进行综合分析，这超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 203, + "question": "Silver plating is required on alumina ceramic parts. It is known that at 1000°C, γ_{Al2O3(s)} = 1.00 mN/m, γ_{Ag(L)} = 0.92 mN/m, and γ_{Ag(L)-Al2O3(s)} = 1.77 mN/m. Can liquid silver wet the surface of alumina ceramic parts? What methods can be used to improve the wettability between them?", + "answer": "cosθ = (γ_{sv} - γ_{sl}) / γ_{lv} = -0.837, θ = 146.8° > 90°, cannot wet. To silver plate ceramic components, the surface of the ceramic must first be ground and polished to improve the wettability between the ceramic and the silver layer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释液态银是否能润湿氧化铝陶瓷表面，并提出改善润湿性的方法。答案包含计算过程和文字解释，属于需要论述的简答题类型。 | 知识层次: 题目需要应用表面张力的基本公式计算接触角，并理解润湿性的判断标准（θ > 90°为不润湿）。此外，还需要提出改善润湿性的方法，涉及多步分析和概念关联。虽然计算部分相对简单，但整体需要综合分析表面处理和润湿性改善的关系。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及表面能的计算和润湿角的概念，要求考生能够正确应用公式计算润湿角，并根据结果判断润湿性。此外，还需要理解如何通过物理方法改善润湿性。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了明确的解题思路和答案，降低了部分难度。因此，该题目在选择题型内属于中等难度，对应等级3。" + }, + { + "idx": 204, + "question": "Analyze the scope of action of firmly bound water and loosely bound water in micelles", + "answer": "Firmly bound water surrounds the clay particles, forming an integral whole with them and moving together in the medium, with a thickness of approximately 3 to 10 water molecules. Loosely bound water is located on the periphery of firmly bound water, with poorer orientation. As they are farther from the clay particle surface, the binding force between them is smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析胶束中紧密结合水和松散结合水的作用范围，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析胶束中紧密结合水和松散结合水的作用范围，涉及对两种水分子在胶束中位置、厚度、取向和结合力的描述，需要理解并关联多个概念，进行综合分析。虽然不涉及复杂计算或深度推理，但需要一定的概念关联和解释能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生区分胶束中紧密结合水和松散结合水的不同作用范围，涉及对水分子排列、结合力以及距离颗粒表面远近等概念的综合理解。虽然不需要复杂的计算，但需要对相关概念有清晰的认识并能进行关联分析。" + }, + { + "idx": 205, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the ion exchange capacity of clay after adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "Li+ < Na+ < K+ < NH4+ < Mg2+ < Ca2+ < Sr2+ < Ba2+ < Al3+ < H+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示离子交换容量的变化模式，需要文字解释和排序，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求考生理解不同阳离子在黏土中的吸附能力及其对离子交换容量的影响，并能够根据离子电荷和半径等性质进行排序。这需要考生掌握相关概念并能进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解离子交换容量的概念，并掌握不同阳离子的特性及其对粘土性能的影响。解题步骤涉及多步比较和分析，需要将多个概念关联起来进行综合判断。此外，正确选项的排列顺序需要基于对离子半径、电荷数等参数的深入理解，这超出了基础记忆的范畴，属于中等应用层次的知识运用。" + }, + { + "idx": 206, + "question": "Explain the differences between structural water, bound water (tightly bound water, loosely bound water), and free water in clay.", + "answer": "Structural water in clay refers to the water within the clay structure. Since clay particles are generally negatively charged and water is a polar molecule, when clay particles are dispersed in water, under the influence of the negative electric field on the clay surface, water molecules align in a specific orientation around the clay particles, forming hydrogen bonds with the oxygen and hydroxyl groups on the surface, with their negative ends facing outward. A negatively charged surface forms around the first layer of water molecules, attracting a second layer of water molecules. The attractive force of the negative electric field on water molecules weakens with increasing distance from the clay surface, causing the arrangement of water molecules to transition gradually from ordered to disordered. The inner layer of water molecules arranged in an ordered manner is called tightly bound water, which surrounds the clay particles and moves together with them as a whole in the medium, with a thickness of approximately 3 to 10 water molecules. The outer layer of water molecules, which is less ordered, is called loosely bound water. Due to their greater distance from the clay particle surface, the binding force between them is weaker. The water beyond the loosely bound water is called free water.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释不同类型的水在粘土中的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对粘土中不同类型水的定义和分类的记忆和理解，属于基础概念的记忆性知识。虽然涉及了一些水分子排列和相互作用的描述，但整体上仍属于对基本概念的解释和论述，没有涉及复杂的应用或分析。 | 难度: 在选择题中属于高难度，题目要求考生理解并区分粘土中不同状态的水（结构水、结合水中的紧密结合水和松散结合水、自由水）的定义及其形成机制。这涉及多个复杂概念的阐述和比较，需要考生对粘土颗粒表面电场作用、水分子排列方式以及不同水层的特性有深入的理解。此外，题目还要求考生能够将这些概念联系起来，形成一个完整的知识体系，这在选择题型中属于较高难度的要求。" + }, + { + "idx": 207, + "question": "Analyze the influence of firmly bound water and loosely bound water on process performance", + "answer": "The density of bound water is high, the heat capacity is small, the dielectric constant is small, and the freezing point is low, which makes it different from free water in physical properties. The amount of clay-water combination can be judged by measuring the heat of wetting. The state and quantity of clay combined with these three types of water will affect the process performance of the clay-water system. When the water content of the clay is constant, if the bound water decreases, the free water increases, resulting in a reduced volume of clay particles that are easier to move, thus lowering the slurry viscosity and improving fluidity. When the amount of bound water is high, the water film is thick, facilitating the sliding between clay particles, which enhances plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析紧密结合水和松散结合水对工艺性能的影响，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析紧密结合水和松散结合水对工艺性能的影响，涉及多个物理性质的比较和相互作用，需要综合运用材料科学知识进行推理分析，解释机理，并关联实际工艺性能的变化。这超出了简单记忆或基本应用的范围，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生深入理解并综合分析粘土结合水的不同类型（紧密结合水和松散结合水）对工艺性能的影响机制。正确选项不仅涉及多个物理性质（密度、热容、介电常数、冰点）的对比分析，还需要理解这些性质如何影响粘土-水系统的工艺性能（如粘度、流动性和塑性）。此外，题目还要求考生能够推理出结合水量变化对自由水含量及系统性能的动态影响，这需要较高层次的机理解释和复杂现象分析能力。在选择题型中，此类需要综合运用多个知识点并进行深度推理的题目属于最难级别。" + }, + { + "idx": 208, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of combined water content in clay after adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附后黏土结合水含量的变化规律，需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求考生理解不同阳离子对黏土结合水含量的影响，并按照特定规律排列。这需要考生掌握阳离子与黏土相互作用的原理，并能综合分析不同阳离子的电荷、半径等因素对结合水含量的影响。虽然不涉及复杂计算，但需要多步概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解粘土吸附不同阳离子后结合水含量的变化规律，这涉及到多个概念的综合应用，包括离子半径、水合能力等。其次，题目给出的阳离子种类较多（H+、Al3+、Ba2+等），需要考生对这些离子的特性有较深入的理解，并能进行多步比较和排序。此外，正确选项的排列顺序（H+ < Al3+ < Ba2+等）需要考生能够综合分析离子电荷、半径等因素对结合水含量的影响，属于多角度分析论述的层次。因此，在选择题型内，该题目的难度等级为4。" + }, + { + "idx": 209, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation trend in slurry stability when clay adsorbs the following different cations (use arrows to show: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附时泥浆稳定性的变化趋势，需要根据材料科学知识进行排序和解释，属于简答题类型。答案形式为一系列符号排列，而非选择或判断。 | 知识层次: 题目要求考生理解不同阳离子对黏土浆体稳定性的影响，并能够根据阳离子的性质（如电荷、离子半径等）进行排序。这需要考生不仅记住阳离子的基本性质，还要能够将这些性质与黏土浆体稳定性的变化趋势关联起来，进行综合分析。虽然不涉及复杂的计算或机理解释，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题型中属于较高难度，需要考生掌握黏土吸附阳离子的相关知识，并能综合分析不同阳离子对黏土浆体稳定性的影响趋势。题目要求考生对多个阳离子的吸附能力进行排序，涉及多步计算和概念关联，需要较强的综合分析能力。" + }, + { + "idx": 210, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of slurry fluidity for clay adsorbed with the following different cations (use arrows to denote: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附下粘土浆体流动性的变化规律，答案是一个排序结果，需要解释和论述不同阳离子的影响，属于简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土浆体流动性的影响，并能够根据离子特性（如电荷、半径等）进行排序。这需要考生不仅记住阳离子的基本性质，还要能够应用这些知识来分析其对粘土性质的影响，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解粘土吸附阳离子的性质及其对浆体流动性的影响规律。题目要求考生掌握不同阳离子的吸附能力及其对粘土浆体流动性的影响趋势，涉及多个概念的综合分析和比较。正确选项的排列顺序需要基于对阳离子电荷、半径及其与粘土表面相互作用的理解，属于多角度分析论述的层次。" + }, + { + "idx": 211, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation trend of the thixotropy of clay slurry when adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Li+ < Na+ < K+ < NH4+ < Mg2+ < Ca2+ < Sr2+ < Ba2+ < Al3+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子对粘土浆触变性的影响趋势，答案是一个具体的排序结果，需要理解和解释不同阳离子的影响，属于简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土触变性的影响趋势，并能够根据离子电荷和半径等性质进行排序。这需要考生掌握粘土吸附阳离子的基本原理，并能将多个概念（离子性质、触变性）关联起来进行综合分析。虽然不涉及复杂计算，但需要对多个离子的影响进行比较和排序，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要掌握黏土吸附阳离子的规律及其对触变性的影响，涉及多个离子的比较和排序，要求考生具备较强的综合分析能力和对概念的理解深度。" + }, + { + "idx": 212, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of plasticity in clay lumps after adsorbing the following different cations (use arrows to denote: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "Li+ < Na+ < K+ < NH4+ < Mg2+ < Ca2+ < Sr2+ < Ba2+ < Al3+ < H+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附后黏土可塑性的变化规律，需要按照特定顺序排列离子，属于需要特定形式回答的简答题类型。答案是通过排列顺序而非选择或计算得出的。 | 知识层次: 题目要求考生理解不同阳离子对粘土塑性的影响，并能够根据离子特性（如电荷、半径等）进行排序。这需要考生不仅记住阳离子的基本性质，还要能够应用这些知识来分析其对粘土性能的影响，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解多个概念并进行多角度分析。题目要求考生掌握不同类型阳离子对粘土可塑性的影响，并能够正确排列这些阳离子的顺序。这涉及到对离子半径、电荷密度以及它们与粘土颗粒相互作用的理解。此外，题目中的阳离子种类较多，增加了比较和分析的复杂性。因此，该题目在选择题型内属于较高难度，需要考生具备较强的综合分析能力。" + }, + { + "idx": 213, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the filtrate loss of clay slurry adsorbed with the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答，具体表现为使用箭头符号表示不同阳离子对粘土浆滤失量的影响顺序，属于需要描述和排列的简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土滤失量的影响，并能够根据离子特性（如电荷、半径等）进行排序。这需要将多个概念（离子吸附、离子半径、电荷效应等）关联起来进行分析，属于中等应用层次。虽然不涉及复杂计算，但需要对离子特性及其对粘土性质的影响有较深入的理解。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生理解粘土吸附不同阳离子后滤失量的变化规律，并正确排列顺序。这需要考生掌握粘土吸附阳离子的基本原理（如离子价态、水化半径等对吸附性能的影响），并能将这些概念综合应用到具体例子中。此外，题目涉及的阳离子种类较多（10种），增加了比较和分析的复杂性。正确选项的排列顺序需要考生进行多步推理和概念关联，属于中等应用层次的知识要求。因此，在选择题型内属于等级4的难度。" + }, + { + "idx": 214, + "question": "According to Figure 5-13 and Table 5-2, the atomic densities on different crystallographic planes (110), (100), and (111) of a face-centered cubic lattice are different. Please answer, on which plane will the solid-gas surface energy be the lowest? Why?", + "answer": "According to the formula for surface energy $\\\\frac{\\\\underline{{L}}^{s}\\\\mathcal{E}_{\\\\underline{{\\\\bar{L}}}}}{N_{0}}[1-\\\\frac{n_{i}^{s}}{n_{i}^{\\\\delta}}]=(\\\\Delta\\\\zeta7)_{s,v}\\\\bullet\\\\underline{{\\\\zeta}}^{s}=\\\\gamma_{s o}^{0}$, where $\\\\gamma_{50}^{0}$ is the solid surface energy, $E_{L}$ is the lattice energy, $N_{0}$ is Avogadro's number, and $Z$ is the number of atoms per 1m² surface. $n_{i}^{\\\\delta}$ and $n_{i}^{s}$ represent the number of nearest neighbor atoms for the i-th atom in the bulk and on the surface, respectively. In a face-centered cubic crystal, $n_{i}^{\\\\delta}=12$; $n_{i}^{s}$ is 6 on the (111) plane, 4 on the (100) plane, and 2 on the (110) plane. Substituting these values into the formula gives $\\\\gamma_{s o(110)}^{0}=0.550\\\\frac{E_{z}}{N_{0}}(1-\\\\frac{2}{12})=0.46\\\\frac{E_{z}}{N_{0}}$,\\n$\\\\gamma_{s o(100)}^{0}=0.785\\\\frac{E_{L}}{N_{0}}(1-\\\\frac{4}{12})=0.53\\\\frac{E_{L}}{N_{0}}$,\\n$\\\\gamma_{s o(111)}^{0}=0.907\\\\frac{E_{z}}{N_{0}}(1-\\\\frac{6}{12})=0.45\\\\frac{E_{z}}{N_{0}}$.\\nThus: $\\\\gamma_{_{50(100)}}^{0}>\\\\gamma_{_{50(110)}}^{0}>\\\\gamma_{_{50(111)}}^{0}$.\\n\\nTherefore, the (111) close-packed plane has the lowest surface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么某个晶面的固气表面能最低，答案通过文字解释和公式推导进行了详细论述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解表面能公式并应用，涉及多步计算和不同晶面的比较，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解表面能的计算公式，并能够正确代入不同晶面的参数进行计算。其次，需要考生掌握面心立方晶体中不同晶面的原子排列和配位数，这需要对晶体结构有深入的理解。最后，题目还要求考生能够通过计算结果比较不同晶面的表面能大小，得出正确的结论。这些步骤涉及多步计算、概念关联和综合分析，超出了基础选择题的难度，属于多角度分析论述的层次。" + }, + { + "idx": 215, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the casting time of clay slurry when adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附时粘土浆料浇注时间的变化规律，需要根据材料科学知识进行排序和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土浆料浇注时间的影响，并能够根据离子特性（如离子半径、电荷数等）进行排序。这需要考生掌握粘土吸附阳离子的基本原理，并能将这些原理应用到具体情境中进行分析和判断。虽然不涉及复杂的计算或深度机理分析，但需要考生对多个概念进行关联和综合运用。 | 难度: 在选择题型中，该题目需要考生掌握粘土吸附不同阳离子时对浇铸时间的影响规律，涉及多个阳离子的比较和排序。考生需要理解阳离子的电荷、半径等性质对粘土性能的影响，并进行综合分析。虽然题目给出了正确选项，但需要考生具备较强的概念关联和综合分析能力，属于较高难度的选择题。" + }, + { + "idx": 216, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the green body formation rate when the clay adsorbs the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附时坯体形成速率的变化规律，需要根据材料科学知识进行解释和排序，而不是选择、判断或计算。答案的形式是一个有序的序列，属于简答题类型。 | 知识层次: 题目要求理解不同阳离子对黏土性能的影响，并按照特定规律（绿色体形成速率）进行排序。这需要综合运用对阳离子性质的理解（如离子半径、电荷等）及其与黏土相互作用的机制，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生掌握粘土吸附阳离子的特性及其对坯体形成速率的影响规律。题目要求考生综合分析不同阳离子的电荷数、离子半径等特性，并理解这些因素如何影响粘土颗粒间的相互作用力，从而推导出坯体形成速率的变化趋势。解题过程涉及多步概念关联和综合分析，需要考生具备较强的材料科学理论基础和逻辑推理能力。" + }, + { + "idx": 217, + "question": "What measures can be taken in production to increase or decrease the plasticity of clay to meet the needs of forming processes?", + "answer": "In production, the specific surface area of mineral components can be increased to enhance the capillary force, thereby increasing plasticity; the valence of adsorbed cations can also be increased or decreased to alter the plasticity of clay; or the particle size of minerals can be reduced to increase contact points, thereby enhancing the plasticity of clay;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述具体的生产措施来调节粘土的塑性，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求考生理解并应用材料科学中的塑性调节方法，涉及多个知识点（如矿物成分的比表面积、吸附阳离子的价态、矿物颗粒尺寸等）的综合应用，需要一定的分析和关联能力，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题型中，该题目要求考生不仅理解粘土塑性的基本概念，还需要掌握多种调控塑性的具体方法（如增加矿物组分比表面积、改变吸附阳离子价态、减小矿物粒径等）。这些知识点涉及材料科学中的多步计算和概念关联，需要考生进行综合分析才能正确作答。相比单纯记忆性选择题，该题需要更高层次的应用能力和多角度思考，因此在选择题型中属于较高难度等级。" + }, + { + "idx": 218, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite mineral), compare the differences in the casting rate of the two slurries when the same amount of electrolyte is added.", + "answer": "The addition of Na2CO3 basically has no effect on the casting rate of the clay, while the addition of Na2SiO3 increases the casting rate of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆料浇注速率的影响，并给出解释。答案需要文字论述两种电解质的不同效果，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对粘土浆料浇注速率的影响，涉及对电解质作用机理的理解和应用，需要综合分析不同电解质在粘土浆料中的行为差异，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解电解质对粘土浆料浇注速率的影响，并比较两种不同电解质（Na2CO3和Na2SiO3）的作用差异。题目要求考生综合分析两种电解质在相同条件下的不同效果，涉及多步概念关联和比较分析，但不需要进行复杂的多角度或深度关联性分析。" + }, + { + "idx": 219, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite mineral), compare the differences in thixotropy of the two slurries when the same amount of electrolyte is added.", + "answer": "Adding Na2CO3 basically has no effect on the thixotropy of the clay, while adding Na2SiO3 reduces the thixotropy of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆体触变性的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对黏土浆体触变性的影响，涉及对电解质作用机理的理解和应用，需要综合分析不同电解质与黏土矿物之间的相互作用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握Na2CO3和Na2SiO3对粘土浆体触变性的影响，并能够区分两者之间的差异。虽然题目提供了正确选项，但考生仍需具备一定的材料科学知识，特别是关于电解质对粘土浆体性质的影响，以及触变性的概念。此外，题目还要求考生能够综合分析不同电解质的作用效果，这增加了题目的复杂性。" + }, + { + "idx": 220, + "question": "What are the factors affecting the plasticity of clay?", + "answer": "The influencing factors include: 1. Mineral composition, different mineral compositions result in varying interparticle forces. 2. Types of adsorbed cations, higher valence cations improve plasticity. 3. Particle size and shape, finer particles with larger specific surface area and more contact points between particles increase plasticity. 4. Water content, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响粘土塑性的因素，答案以文字论述形式给出，列举了多个影响因素并进行简要说明，符合简答题的特征。 | 知识层次: 题目考查对影响粘土塑性因素的基本概念记忆和理解，包括矿物组成、吸附阳离子类型、颗粒大小和形状以及含水量等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个影响粘土塑性的因素，但每个因素的解释相对直接，主要基于基础概念的记忆和理解。正确选项提供了清晰的分类和简要解释，不需要复杂的分析或推理步骤。因此，它属于等级2，即概念解释和描述的难度水平。" + }, + { + "idx": 221, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite minerals), compare the differences in the body density of the two slurries when the same amount of electrolyte is added.", + "answer": "Adding Na2CO3 basically has no effect on the body density of the clay, while adding Na2SiO3 increases the body density of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆体密度的影响，并给出解释性的答案，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较两种电解质对黏土浆体密度的影响，涉及对电解质作用机理的理解和应用。需要分析Na2CO3和Na2SiO3在黏土浆体中的不同行为，并解释其对密度的影响差异。这属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握Na2CO3和Na2SiO3对粘土浆体密度的影响差异，并能够综合分析电解质的作用机制。虽然不需要复杂的计算，但需要对材料科学中的电解质行为有较深的理解，并能将概念关联起来进行判断。" + }, + { + "idx": 222, + "question": "What is the practical significance of Gibbs phase rule?", + "answer": "Applying the phase rule can conveniently determine the degrees of freedom of an equilibrium system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Gibbs相律的实际意义，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对Gibbs相规则的基本概念和实用意义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。题目要求考生理解Gibbs相律的实际意义，并能够识别其应用场景（确定平衡系统的自由度）。虽然涉及基础概念记忆，但需要一定的理解能力来将原理与实际应用联系起来，比单纯记忆定义（等级1）稍复杂，但不需要复杂概念体系阐述（等级3）。" + }, + { + "idx": 223, + "question": "In the phase diagram of the SiO2 system, find two examples of reversible polymorphic transformations", + "answer": "Reversible polymorphic transformations: β-quartz ↔ α-quartz, α-quartz ↔ tridymite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个可逆多晶型转变的例子，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对SiO2系统相图中可逆多晶转变的基本概念记忆，仅需列举两个例子，不涉及复杂分析或综合应用 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确回忆并识别SiO2系统中可逆的多晶型转变实例。这要求考生不仅记住定义，还要能区分不同相变类型的具体例子。相比单纯的定义复述（等级1），这种题目需要更深入的概念理解和记忆。" + }, + { + "idx": 224, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay (mainly composed of kaolinite mineral) slurry, respectively, compare the differences in fluidity of the two slurries when the same amount of electrolyte is added.", + "answer": "Adding Na2CO3 basically has no effect on the fluidity of the clay, while adding Na2SiO3 increases the fluidity of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆料流动性的影响，并解释其差异。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对黏土浆料流动性的影响，需要理解电解质与黏土颗粒之间的相互作用机制，并能够分析不同电解质（Na2CO3和Na2SiO3）在相同条件下的不同效果。这涉及多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解电解质对粘土浆液流动性的影响，并比较Na2CO3和Na2SiO3的不同作用。题目涉及多个概念的综合分析，但选项提供了明确的对比结果，降低了部分难度。" + }, + { + "idx": 225, + "question": "What is Gibbs phase rule?", + "answer": "The phase rule is a fundamental law of phase equilibrium derived by Gibbs based on thermodynamic principles, also known as Gibbs phase rule, used to describe the relationship between the number of degrees of freedom, the number of components, and the number of phases in a system at phase equilibrium. The general mathematical expression is F=C-P+2, where F is the number of degrees of freedom, C is the number of components, P is the number of phases, and 2 represents the two variables of temperature and pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Gibbs phase rule的定义和数学表达式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查Gibbs相律的基本定义和数学表达式，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（Gibbs相律的定义和数学表达式），但需要考生理解并描述相律中各变量的含义及其相互关系。相比单纯记忆定义（等级1），该题目要求对概念进行解释和描述（等级2），但不需要进行复杂的概念体系阐述或应用（等级3）。" + }, + { + "idx": 226, + "question": "In the SiO2 phase diagram, identify two examples of irreversible polymorphic transformations", + "answer": "Irreversible polymorphic transformations: β-cristobalite←→β-quartz, V-tridymite←→β-quartz", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求识别并列举SiO2相图中的不可逆多晶型转变例子，答案需要文字解释和具体例子，而不是选择、判断或计算。 | 知识层次: 题目考查对SiO2相图中不可逆多晶转变的具体实例的记忆，属于基础概念的记忆性知识，不需要复杂的分析或推理过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（SiO2相图中的不可逆多晶转变），但需要考生准确记忆并区分多种SiO2变体之间的转变关系。相比单纯的定义记忆（等级1），这需要考生掌握更具体的分类知识。不过题目仅要求识别两个例子，不需要进行复杂的概念体系阐述（等级3），因此属于概念解释和描述级别的难度。" + }, + { + "idx": 227, + "question": "In the Al2O3-SiO2 system, the liquidus line of SiO is very steep, so why is it necessary to strictly prevent the mixing of Al2O3 in silica bricks, otherwise the refractoriness of silica bricks will be greatly reduced?", + "answer": "Al2O3 in the SiO2 system can significantly increase the amount of liquid phase, leading to a substantial decrease in the eutectic point temperature, thereby greatly reducing the refractoriness of silica bricks. Therefore, it is essential to strictly prevent the mixing of Al2O3.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释为什么在SiO2系统中Al2O3的混入会显著降低硅砖的耐火度，答案通过文字论述了这一现象的原因，符合简答题的特征。 | 知识层次: 题目需要解释Al2O3在SiO2系统中如何显著增加液相量，并导致共晶点温度大幅下降，从而降低硅砖的耐火度。这涉及对相图的理解、液相形成的机理分析以及材料性能变化的综合推理，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解Al2O3-SiO2系统的相图特征，还需要深入分析杂质Al2O3对SiO2体系液相量和共晶点温度的影响机制。解题需要综合运用相平衡知识、液相形成原理以及耐火材料性能评估等多方面知识，并进行复杂的因果关系推理。这种需要全面分析复杂现象并解释深层机理的题目，在选择题型中属于最具挑战性的类型。" + }, + { + "idx": 228, + "question": "At this temperature, after prolonged holding to reach equilibrium, what is the phase composition of the system?", + "answer": "After prolonged holding at 1595°C, the system consists of liquid phase and A3S2, with L% = 21.8%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述系统在特定条件下的相组成，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求根据相图分析特定温度下的平衡相组成，需要理解相图的基本原理并应用相律进行计算，涉及多步分析和概念关联，但不需要复杂的机理推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解相平衡概念、温度对相组成的影响，并能将给定温度与相图关联起来进行综合分析。虽然题目提供了具体温度条件，但仍需考生掌握多步计算和概念关联能力才能正确解答。" + }, + { + "idx": 229, + "question": "In the CaO-SiO2 system, the liquidus line of SiO2 is very steep. Why can a small amount of CaO be added as a mineralizer in the production of silica bricks without reducing their refractoriness?", + "answer": "When a small amount of CaO is added to SiO2, at the eutectic point of 1436°C, the liquid phase content is 2/37=5.4%. The increase in liquid phase content is not significant and does not reduce the refractoriness of silica bricks, so a small amount of CaO can be added as a mineralizer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释为什么少量CaO可以作为矿化剂而不降低硅砖的耐火度，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解CaO-SiO2系统的相图特性，并能解释在特定温度下液相含量的计算及其对耐火材料性能的影响。这涉及到多步概念关联和综合分析，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解相图的基本概念（如液相线、共晶点），并能进行简单的百分比计算（2/37=5.4%）。此外，还需要将计算结果与耐火材料的性能关联起来，综合分析少量CaO作为矿化剂的作用机制。虽然涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了关键计算步骤和结论，降低了独立推导的难度。" + }, + { + "idx": 230, + "question": "When the clay mineral kaolinite (Al2O3•2SiO2•2H2O) is heated to 600°C, it decomposes into water vapor and Al2O3•2SiO2. What happens when it is further heated to 1595°C?", + "answer": "When heated to 1595°C, A3S2 is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释当高岭石加热到1595°C时会发生什么变化，答案需要文字描述反应产物，属于简答题类型。 | 知识层次: 题目需要理解高岭石在不同温度下的分解过程，并关联到具体的化学反应和产物形成。虽然涉及记忆性知识（如化学式），但更侧重于在不同温度条件下物质变化的分析和应用，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及粘土矿物高岭石在不同温度下的分解过程，要求考生掌握高岭石的热分解反应及其产物。虽然题目给出了部分反应信息，但需要考生综合理解并推断在更高温度下的反应产物。这需要一定的材料科学知识背景和逻辑推理能力，但题目提供了部分线索，降低了难度。" + }, + { + "idx": 231, + "question": "At what temperature does the clay completely melt?", + "answer": "Complete melting means the solid phase completely disappears, which should be at the temperature where the 33% line intersects with the liquidus line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么温度下粘土完全熔化，答案需要文字解释和论述，说明完全熔化的定义以及如何确定该温度，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解相图的基本原理，并能通过分析相图中的特定线（33%线和液相线）的交点来确定完全熔化的温度。这涉及到对相图的理解和应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解相图的基本概念（如液相线、固相线），并能将图表信息与百分比数据关联分析。虽然不涉及复杂计算，但要求考生综合运用相图知识和数据解读能力来确定完全熔化的温度点。" + }, + { + "idx": 232, + "question": "When the system generates 40% liquid phase, what temperature should be reached?", + "answer": "The temperature at which 40% liquid phase is generated needs to be determined by referring to the phase diagram, and the specific temperature is not provided in the answer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过参考相图来确定温度，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求通过相图确定特定液相比例对应的温度，需要理解相图的基本原理，并能进行多步分析和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解相图的概念并能进行综合分析。题目要求确定生成40%液相时的温度，这需要考生能够解读相图并关联相关概念，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 233, + "question": "Compare the characteristics of the eutectic point in ternary invariant points and write its equilibrium relationship", + "answer": "The eutectic point is a type of invariant point where several crystalline phases simultaneously precipitate from the melt upon cooling or melt together upon heating. The phase equilibrium relationship is L(E)⇄A+B+C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较三元不变点中共晶点的特性并写出其平衡关系，需要文字解释和论述，答案也以文字形式给出解释和公式。 | 知识层次: 题目考查对共晶点特性的基本概念记忆和简单理解，涉及相平衡关系的基本原理，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（定义、分类、基本原理等），但需要考生理解并描述三元共晶点的特征及其平衡关系，而不仅仅是简单的定义复述。题目要求考生能够将共晶点的概念扩展到三元体系，并写出具体的相平衡关系式，这比单纯记忆定义需要更深一层的理解和应用。因此，在选择题型中属于等级2的难度。" + }, + { + "idx": 234, + "question": "Cool a melt containing MgO and $\\\\mathrm{{Al}_{2}\\\\mathrm{{O}_{3}}}$ to a certain temperature, then filter out the precipitated crystals and analyze the remaining liquid phase. It is found that the liquid phase contains 65% MgO, and the amount of liquid phase is 70% of the total system. Determine the composition of the original melt.", + "answer": "$\\\\mathrm{MgO\\\\ 45.5\\\\%}$; $\\\\mathrm{Al_{2}O_{3}\\\\ 54.5\\\\%}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定原始熔体的组成，答案以具体数值形式给出，解答过程涉及物质平衡和相图分析等计算步骤。 | 知识层次: 题目需要进行多步计算和概念关联，包括相平衡和成分分析的综合应用，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目涉及质量平衡和组分分配的综合分析，解题步骤包括设定变量、建立方程和求解，但选项提供了明确的目标减少了部分复杂性。" + }, + { + "idx": 235, + "question": "Compare the characteristics of the singular peritectic point in ternary invariant points, and write its equilibrium relationship", + "answer": "If the invariant point is at the intersection position, it is a singular eutectic point; if it is at the conjugate position, it is a double peritectic point. The phase transformation relationship is L_{(g)}+A⇌D+C, L_{(g)}+A+B⇌S", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中单一包晶点的特性并写出其平衡关系，需要文字解释和论述，答案也是以文字形式呈现的详细解释，符合简答题的特征。 | 知识层次: 题目要求比较三元不变点中的单一包晶点特征并写出其平衡关系，涉及多个概念的关联和综合分析，需要理解相图的基本原理并应用相关知识进行解释。虽然不涉及复杂的计算或创新设计，但需要一定的思维深度和概念关联能力。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 236, + "question": "Compare the characteristics of transition points in ternary invariant points and write their equilibrium relationships", + "answer": "The transition point is where the properties change from peritectic to eutectic, with no corresponding triangle, and the compositions of the three crystalline phases in equilibrium lie on a straight line", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中过渡点的特性并写出它们的平衡关系，需要文字解释和论述，而不是选择、判断或计算。答案也以文字描述的形式给出，符合简答题的特征。 | 知识层次: 题目要求比较三元不变点中过渡点的特性并写出其平衡关系，这需要综合运用相图知识、理解相变机制，并进行推理分析。涉及多相平衡、相图解读和相变类型的关联，思维深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解三元不变点中的过渡点特性，还需要掌握其从包晶到共晶的性质变化，并能分析三个结晶相平衡时的成分直线排列关系。这需要考生具备复杂现象全面分析的能力，包括对相图机理的深度理解和综合运用知识进行推理分析。选择题型中，这种需要多维度知识整合和高级认知能力的题目属于最难级别。" + }, + { + "idx": 237, + "question": "Compare the characteristics of the double transition point in the ternary invariant point and write its equilibrium relationship", + "answer": "If the invariant point is at the intersection position, it is a single eutectic point; if it is at the conjugate position, it is a double transition point. The phase transformation relationship is L_{(g)}+A⇌D+C, L_{(g)}+A+B⇌S", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中双过渡点的特性并写出其平衡关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较三元不变点中双转变点的特性并写出其平衡关系，这需要理解相图的基本概念（如不变点、双转变点）并能够应用这些概念来分析具体的相变关系。虽然涉及一定的记忆性知识，但更强调对概念的理解和应用，以及将不同概念关联起来进行综合分析。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 238, + "question": "From an atomic scale perspective, explain the differences in the bonding mechanism of glass-to-metal sealing.", + "answer": "The sealing of glass and metal is governed by many factors. The most important factors affecting the seal are the following four aspects: (1) Oxidation of the metal: Before the hermetic sealing of glass and metal, the metal is usually moderately oxidized, placing the metal oxide between the glass and the metal. This step is essential for sealing and is also a microscopic control method for glass sealing. The oxidation treatment of the metal is the most critical factor affecting the sealing of glass and metal, and the oxidation mechanism is a key issue in sealing technology. (2) Thermal expansion coefficients of glass and metal: The consistency of the thermal expansion coefficients of glass and metal is a macroscopic control method for achieving good sealing. When the glass melt is sealed with the metal, the glass at high temperature has sufficient viscous fluidity. It deforms while simultaneously contracting along the thermal contraction curve of the metal. However, as the temperature decreases, the glass gradually loses its fluidity, causing it to separate from the metal's thermal contraction curve. This change is continuous and depends on the cooling rate, making it impossible to determine a specific temperature at which the glass separates from the metal's contraction curve. For convenience, a specific temperature TM is often used to represent the state when the glass is fixed to the metal. This means that when T > Tμ, the glass has complete fluidity and does not generate stress. When T < Ti1, the sealing glass contracts along its inherent thermal contraction curve. This specific temperature TM is called the solidification temperature, which is very close to the strain temperature of the glass. At any temperature T, a contraction difference ∠d is generated between the glass and metal, producing stress proportional to △d in the seal. When the stress exceeds the strength limit of the glass, the glass is damaged, affecting the hermeticity of the seal. Below the solidification temperature Ty, the relative relationship of the thermal contraction curves essentially reflects the matching degree of the expansion coefficients, i.e., the contraction difference between the glass and metal starting from Ty should be: △d = (ag - am)(T - T) (Equation 1-1). In Equation 1-1, ag and am represent the expansion coefficients of the glass and metal, respectively, from TM to the matching temperature T. To eliminate permanent stress in the glass, the seal must be annealed. Proper annealing is crucial for sealing quality. After annealing, the seal should not be cooled rapidly because the metal has better thermal conductivity than the glass, causing the metal to cool faster. When the expansion coefficients of the metal and glass are the same, this difference in cooling rates causes the metal to contract more than the glass. Once the glass loses fluidity, the metal must cool within a narrow range, and the length changes affect the adhesion between the glass and metal. If the rapid cooling starts at a temperature above the lower limit of the glass's annealing temperature, the glass will be in a stretched state. To prevent this tensile stress and to ensure the glass is slightly pressurized, the metal part is often heated separately with a gas flame after sealing. (3) Strength of the glass and interfacial diffusion: On the basis of matching the thermal expansion coefficients of the glass and metal, improving the mechanical strength of the glass, especially its tensile strength, is beneficial when the seal is subjected to thermal shock, thermal stress due to temperature gradients, or external forces during use. Generally, the compressive strength of glass can be very high, reaching 600~1500 MPa, while the tensile strength is extremely low, only about 10% of the compressive strength. In practice, only tensile strength poses problems. If possible, using crystallized glass for sealing is an effective way to improve the tensile strength of the glass, typically achieving 3~5 times or even more than 5 times the original tensile strength. It must be noted that the presence of a large number of bubbles (especially clustered bubbles) at the sealing interface is highly detrimental, as it can reduce mechanical strength and cause chronic leaks. Gas dissolved in the metal being released during sealing heating is one cause of bubbles, which is rare in metals like tungsten, molybdenum, and platinum but more common in nickel, iron, and their alloys. To eliminate this factor, metals produced by vacuum smelting are preferred, or the metal can be pre-degassed by heating in a vacuum or hydrogen atmosphere. Another cause of bubbles is carbon, especially in the surface layer of the metal, which oxidizes into carbon dioxide gas during sealing, forming bubbles. This is more severe in nickel, iron, and their alloys than in other metals. The solution is to anneal the metal in wet hydrogen or a vacuum to remove gas and carbon, thereby preventing bubble formation. The annealing temperature is generally 900~1100°C, and the duration depends on the thickness of the metal. Near the sealing interface, there are two scenarios: one involves direct mutual diffusion at the interface between two different materials, such as in glass-to-glass optical grinding seals or metal-to-metal welding. The other involves placing a different material at the interface to facilitate sealing, such as in glass-to-metal or ceramic-to-metal seals where direct mutual diffusion is difficult. In this case, melting diffusion occurs. However, whether mutual diffusion or melting diffusion occurs, the composition and properties near the interface differ from those in the bulk material, and this variation significantly affects the stability of the seal. (4) Shape, size, and surface roughness of the seal: The magnitude and distribution of stress within the seal are influenced by its shape and size. When the stress exceeds the strength limit of the sealing material, the seal is inevitably damaged. Generally, after sealing, if the seal is only a component of an electron tube or vacuum device and requires further processing or sealing with another similar device, it must undergo additional heat treatment or mechanical force. The temporary stress caused by external forces will combine with the thermal contraction stress between the materials. The combined effect of the permanent stress from thermal contraction differences and temporary stress from various causes is considerable. If the influence of shape and size on stress is overlooked, the stability of the seal may be compromised. For example, in production, the plasticity of thin metal edges can be utilized to reduce stress, or even the elasticity of the metal can be used for sealing. Additionally, adhesion tests have shown that if the substrate has uniform凹凸 (凹凸 refers to surface roughness or unevenness), the adhesion is good, which positively affects the sealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释玻璃与金属密封的键合机制差异，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求从原子尺度解释玻璃-金属密封的键合机制，涉及多个复杂因素的综合分析，包括金属氧化、热膨胀系数匹配、玻璃强度和界面扩散、密封形状和表面粗糙度等。需要深入理解材料科学原理，并进行多方面的推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从原子尺度解释玻璃-金属密封的键合机制，涉及多个复杂因素的综合分析，包括金属氧化、热膨胀系数匹配、玻璃强度和界面扩散、密封形状和表面粗糙度等。正确选项详细阐述了这些因素的相互作用和影响，需要考生具备深厚的材料科学知识，能够理解并整合多个高级概念。此外，解题过程需要综合运用物理、化学和材料力学等多学科知识，进行复杂的推理和机理分析，远超一般选择题的认知要求。" + }, + { + "idx": 239, + "question": "Concentration gradient causes diffusion, does diffusion always proceed from high concentration to low concentration? Why?", + "answer": "Diffusion is caused by gradient differences, and concentration gradient is only one type of gradient difference. When another gradient difference, such as stress gradient, has a greater influence than the concentration gradient, diffusion can proceed from low concentration to high concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散是否总是从高浓度向低浓度进行，并需要提供原因。答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目不仅考查扩散的基本概念（浓度梯度），还需要理解其他梯度（如应力梯度）对扩散方向的影响，涉及多因素的综合分析和机理解释，思维深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目不仅要求理解扩散的基本概念（浓度梯度驱动），还需要考生综合运用其他梯度差异（如应力梯度）的知识，进行复杂现象的全面分析。正确选项涉及机理深度解释和多个概念的比较推理，远超单一知识点的简单记忆或理解，符合选择题型内对复杂现象全面分析的最高要求。" + }, + { + "idx": 240, + "question": "A petrographic analysis of a certain Portland cement revealed that the flux mineral CA precipitated as a crystalline phase before CAF. Is this formulation a high-alumina formulation (P>1.38) or a high-iron formulation (P<1.38)?", + "answer": "It is a high-alumina formulation (P>1.38).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两个选项（high-alumina formulation或high-iron formulation）中选择正确答案 | 知识层次: 题目需要理解波特兰水泥的矿物组成及其在相变过程中的行为，并应用P值（铝铁比）的概念来判断水泥配方的类型。这涉及到多步分析和概念关联，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。题目要求考生不仅理解波特兰水泥的矿物组成和相变顺序，还需要掌握高铝配方（P>1.38）和高铁配方（P<1.38）的区分标准。解题过程中需要将矿物析出顺序与配方参数P值关联起来，进行综合分析判断。这超出了单一概念的记忆或简单应用，属于需要多步推理和概念关联的中等应用层次题目。" + }, + { + "idx": 241, + "question": "Compare the characteristics of polymorphic transition points in ternary invariant points and write their equilibrium relationships", + "answer": "Polymorphic transition points are the temperature points at which two or three crystal forms undergo crystal transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中的多晶型转变点特征并写出它们的平衡关系，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了概念性的文字解释，符合简答题的特征。 | 知识层次: 题目要求比较三元不变点中的多晶转变特性并写出平衡关系，涉及多个概念的关联和综合分析，需要理解多晶转变的基本原理并能够应用到具体体系中，思维过程需要一定的深度和逻辑性。 | 难度: 在选择题中属于较高难度，题目要求比较三元不变点中的多晶转变点特性并写出平衡关系，涉及多步计算、概念关联和综合分析。正确选项需要理解晶体转变的温度点以及两种或三种晶型之间的转变关系，这要求考生具备较深的知识掌握和多角度分析能力。" + }, + { + "idx": 242, + "question": "How should the cooling rate in the clinkering zone be controlled for high-alumina formulations (P>1.38)?", + "answer": "For formulations with an alumina modulus P>1.38, when the melt cools past the KT2 boundary, the liquid phase will reabsorb C3S and precipitate C2S and CsA. Therefore, if the clinker is cooled slowly in the clinkering zone, bringing the cooling process close to equilibrium, some C3S will be reabsorbed, which is detrimental to cement quality. Hence, for formulations with P>1.38, rapid cooling should be employed during the cooling process in the clinkering zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对高铝配方的冷却速率控制进行解释和论述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及对高铝配方在熟料带冷却速率的控制机制的理解，需要分析冷却速率对矿物相变（C3S重新吸收和C2S、CsA析出）的影响，并解释其对水泥质量的影响。这需要综合运用材料科学和工艺知识，进行机理层面的推理和分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 243, + "question": "The batching of high-alumina cement is usually selected within the range of the CA phase region, and it is often produced by firing to melting and then cooling. The main mineral of high-alumina cement is CA, and C2AS has no hydraulic properties, so it is desirable that the cement does not contain C2AS. Therefore, what range of batching should be chosen within the CA phase region, and why (note that complete equilibrium cannot be achieved during production, and independent crystallization processes may occur)?", + "answer": "High-alumina cement has the characteristic of rapid hardening and is widely used in the defense industry. The batching range is Al2O3 35%~55%, CaO 35%~45%, SiO2 5%~10%, Fe2O3 0~15%. This can prevent the formation of C2AS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么选择特定的配料范围，并需要文字论述来支持答案，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求分析高铝水泥配料范围的选择原因，涉及矿物相的形成条件、生产工艺的限制（无法达到完全平衡）以及独立结晶过程的影响。这需要综合运用材料科学知识，进行推理分析，解释为什么特定的配料范围可以防止C2AS的形成，属于复杂分析层次。 | 难度: 在选择题中属于最高难度，需要综合运用材料科学知识进行复杂分析。题目涉及高铝水泥的配料范围选择、矿物相平衡、生产工艺限制（非完全平衡状态）等多重因素，要求考生不仅掌握CA相区的理论基础，还要理解C2AS相的水硬性缺失机理，并能根据生产实际条件推导出最优配料比例。正确选项的确定需要完成从相图分析到工业应用的完整推理链条，远超单纯记忆性知识的考查范畴。" + }, + { + "idx": 244, + "question": "How should the cooling rate of high iron composition (P<1.38) in the burning zone be controlled?", + "answer": "For compositions with an alumina modulus P<1.38, the melt cooling and crystallization process passes through the WT2 boundary, where the liquid phase absorbs C2S back and precipitates CsS and C4AF. Therefore, the slower the clinker cooling rate, the closer it approaches equilibrium, and the more fully C2S is absorbed back. The content of CS in the clinker will increase, which is beneficial for cement quality. Thus, for clinker with P<1.38, the cooling rate in the burning zone should be appropriately slowed down.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对高铁成分（P<1.38）在燃烧区的冷却速率控制进行解释和论述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对高铁成分在燃烧区冷却速率的控制机制的理解，需要综合运用材料科学中的相变原理和水泥熟料形成过程的知识。解答过程中需要分析冷却速率对相变路径和最终产物组成的影响，并基于此提出控制策略，体现了较高的认知层次和综合分析能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解高铁成分（P<1.38）在燃烧区的冷却速率控制原理，还需要掌握熔体冷却和结晶过程中通过WT2边界时液相吸收C2S并析出CsS和C4AF的复杂机理。此外，题目还要求考生能够推理分析冷却速率对水泥质量的影响，并综合运用这些知识得出正确的控制策略。这种题目不仅考察了多个复杂概念的掌握，还需要考生进行深层次的机理解释和综合推理，因此在选择题型中属于最高难度。" + }, + { + "idx": 245, + "question": "The diffusion coefficient values of CaO at 1145°C and 1650°C", + "answer": "As shown in the figure, the diffusion coefficient values of CaO at 1145°C and 1650°C are D1 and D2, respectively (specific values need to be read from the figure).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表中的数据提供具体的扩散系数值，需要读取图表并给出具体数值，属于需要简短回答的问题。 | 知识层次: 题目要求从图中读取扩散系数的具体数值，属于基本数据的直接应用，不需要复杂的计算或深入的分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需要根据图表读取扩散系数值并进行简单比较。题目提供了明确的信息来源（图表）和具体温度点，不需要复杂的计算或深入的概念理解。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 246, + "question": "The diffusion coefficient values of Al2O3 at 1393°C and 1716°C", + "answer": "As shown in the figure, the diffusion coefficient values of Al2O3 at 1393°C and 1716°C are D3 and D4, respectively (specific values need to be read from the figure).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表读取并描述扩散系数值，答案需要文字解释和具体数值的引用，属于简答题类型。 | 知识层次: 题目要求从图中读取扩散系数值，属于基本数据的直接应用，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接应用和简单计算能力。题目提供了明确的温度点和对应的扩散系数值，只需要根据图表读取具体数值即可完成选择，无需复杂的分析或推理过程。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 247, + "question": "Provide a full explanation of the various property value estimates you made in the calculation. The Schottky defect formation energy of CaO is known to be 6eV.", + "answer": "The property values used in the calculation include: Schottky defect formation energy ΔHf = 6 eV, converted to joules as 6 × 1.6 × 10^-19 J; Avogadro's constant NA = 6.23 × 10^23 mol^-1; gas constant R = 8.314 J/(mol·K); melting point temperature T = 2600℃ = 2873 K. These values are used to calculate the Schottky defect concentration [V′′Ca] = exp(-ΔHf / 2RT).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提供详细的解释和论述，说明计算中使用的各种属性值估计，答案也以文字解释的形式呈现，没有涉及数值计算或公式应用的具体过程。 | 知识层次: 题目要求解释计算中使用的各种属性值，并涉及单位转换和基本公式的应用。虽然计算本身并不复杂，但需要理解Schottky缺陷形成能的概念，并将其与Avogadro常数、气体常数和温度等关联起来进行多步计算。这超出了简单记忆或直接套用公式的层次，属于中等应用水平。 | 难度: 在选择题中属于中等难度，题目要求考生理解并应用多个概念（如Schottky缺陷形成能、单位转换、阿伏伽德罗常数、气体常数等），并进行多步计算和综合分析。虽然涉及的知识点较多，但题目提供了明确的公式和数值，降低了部分难度。" + }, + { + "idx": 248, + "question": "Given the diffusion data of hydrogen in face-centered cubic iron as D_Ni = 0.0063 exp(-10300 × 4.18 / RT) cm²/s, calculate the diffusion coefficient at 1000°C.", + "answer": "Substituting T=1000°C into the equation yields D_H=3.6×10^-5 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散公式和温度条件进行数值计算，最终得出扩散系数的具体数值。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目要求直接套用给定的扩散系数公式进行数值计算，仅需简单的代数运算和单位转换，不涉及多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用给定的扩散系数公式，并进行简单的温度单位转换和数值计算。解题步骤非常直接，不涉及多个公式的组合或复杂的概念分析，因此属于单一公式直接计算的难度等级1。" + }, + { + "idx": 249, + "question": "What concentration of trivalent ions is required to ensure that the diffusion of Ca2+ in CaO remains non-intrinsic up to the melting point of CaO (2600°C)? The Schottky defect formation energy of CaO is known to be 6eV.", + "answer": "The defect reaction for doping M3+ is as follows: M2O3 → 2M′′Ca + V′′Ca + 3OO. When CaO is at its melting point, the concentration of Schottky defects is: [V′′Ca] = exp(-ΔHf / 2RT) = exp(-6 × 1.6 × 10^-19 × 6.23 × 10^23 / (2 × 8.314 × 2873)) = 3.6 × 10^-6. Therefore, to ensure that the diffusion of Ca2+ in CaO remains non-intrinsic up to the melting point of CaO (2600°C), the concentration of M3+ must be [M3+] = [M′′Ca] = 2[V′′Ca] > [V′′Ca], i.e., [M3+] > 2 × 3.6 × 10^-6 = 7.2 × 10^-6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算Schottky缺陷的浓度以及确定三价离子的浓度要求。答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解Schottky缺陷的形成能、扩散机制以及掺杂浓度对扩散行为的影响，并进行相应的数值计算。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷形成能的概念，掌握缺陷反应方程式的书写，并能进行多步计算（包括指数运算和单位转换）。此外，还需要综合分析掺杂浓度与缺陷浓度的关系，确保非本征扩散条件。虽然题目提供了正确选项，但解题过程涉及多个概念关联和计算步骤，对学生的知识掌握和计算能力要求较高。" + }, + { + "idx": 250, + "question": "Calculate the diffusion activation energy Q and D0 value of Ca2+ in CaO", + "answer": "According to D=D0exp(-Q/RT), the ratio of diffusion coefficients of CaO at 1145°C and 1650°C can be used to calculate Q and D0. The specific calculation process is: D1/D2 = exp[-Q/R(1/T1 - 1/T2)], where T1=1418K(1145°C), T2=1923K(1650°C). Solving this equation yields the Q value, and substituting the diffusion coefficient at either temperature gives D0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散激活能Q和D0值，解答过程涉及具体的温度转换、公式代入和方程求解，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括温度转换、公式应用和数值求解，涉及扩散激活能和扩散系数的综合分析，需要理解阿伦尼乌斯方程的应用和温度对扩散系数的影响。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散激活能的概念，掌握阿伦尼乌斯方程的应用，并能进行多步骤的温度转换和代数计算。虽然题目提供了计算框架，但仍需要综合运用多个知识点才能正确解答。" + }, + { + "idx": 251, + "question": "Given the diffusion data of nickel in face-centered cubic iron as D_Ni = 4.1 exp(-64000 × 4.18 / RT) cm²/s, calculate the diffusion coefficient at 1000°C.", + "answer": "Substituting T=1000°C into the equation yields D_Ni=4.35×10^-11 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散方程和温度条件进行数值计算，最终得出扩散系数的具体数值。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目要求直接套用给定的扩散系数公式进行数值计算，属于基本公式应用和简单计算范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的扩散系数公式，并进行简单的温度单位转换和数值计算。解题步骤非常直接，不涉及多个公式的组合或复杂的概念分析，因此属于单一公式直接计算的难度等级1。" + }, + { + "idx": 252, + "question": "Calculate the diffusion activation energy Q and D0 value of Al3+ in Al2O3", + "answer": "According to D=D0exp(-Q/RT), the ratio of diffusion coefficients of Al2O3 at 1393℃ and 1716℃ can be used to calculate Q and D0. The specific calculation process is: D3/D4 = exp[-Q/R(1/T3 - 1/T4)], where T3=1666K(1393℃), T4=1989K(1716℃). Solving this equation yields the Q value, and substituting it into the diffusion coefficient at any temperature gives D0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散激活能Q和D0值，答案中给出了具体的计算步骤和公式应用过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解扩散激活能的概念，并能够将不同温度下的扩散系数关联起来进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散激活能的概念，掌握阿伦尼乌斯方程的应用，并能进行多步计算和温度单位的转换。虽然题目提供了具体的计算步骤，但需要综合运用多个知识点，包括对数运算和代数求解，属于综合性计算问题。" + }, + { + "idx": 253, + "question": "Explain the difference in diffusion coefficients between hydrogen and nickel in face-centered cubic iron.", + "answer": "Compared to nickel atoms, hydrogen atoms are much smaller and can diffuse more easily through the gaps in face-centered cubic iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释氢和镍在面心立方铁中扩散系数的差异，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释氢和镍在面心立方铁中扩散系数的差异，涉及原子尺寸效应和晶体结构间隙扩散机理的综合分析，需要理解扩散机制和原子尺寸对扩散行为的影响，属于复杂分析和推理解释的范畴。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解扩散系数的概念，还需要掌握氢和镍原子在面心立方铁中的扩散机理差异。正确选项涉及对原子尺寸效应的深入理解以及晶体结构间隙扩散的机理分析，这需要考生具备综合运用材料科学知识的能力。虽然题目以选择题形式呈现，但考察的知识深度和推理复杂度明显高于基础概念题，属于需要机理深度解释的难度等级。" + }, + { + "idx": 254, + "question": "When Zn2+ diffuses in ZnS, the diffusion coefficient at 563°C is 3×10−4cm2/s, and at 450°C it is 1.0×10−4cm2/s. Calculate the activation energy for diffusion and D0.", + "answer": "Referring to 7-4, Q=48856J/mol, D0=3×10−15cm2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的温度与扩散系数数据，计算扩散激活能（activation energy）和D0值。解答过程涉及数值计算和公式应用（如阿伦尼乌斯方程），答案以具体数值形式给出。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及温度与扩散系数的关系，并求解活化能和D0值。这需要理解扩散机制的基本原理，并能正确关联和运用相关公式进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要应用阿伦尼乌斯公式进行两步计算（先求活化能Q，再求D0），涉及对数运算和单位转换。虽然题目提供了关键数据，但需要考生正确关联温度与扩散系数的关系，并执行连贯的数学推导步骤。相比单纯的概念选择题，此类计算题在选择题型中复杂度较高，但尚未达到多变量交互作用的最高难度等级。" + }, + { + "idx": 255, + "question": "Given that the activation energy Q for Zn2+ diffusion in ZnS is 48856 J/mol, and D0=3×10−15 cm2/s, calculate the diffusion coefficient at 750°C.", + "answer": "Substituting T=1023K into D=D0exp(−Q/RT) yields D1023=9.6×10−4 cm2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出一个数值结果。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目要求直接套用扩散系数公式进行计算，仅需简单代入已知数值和温度转换，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用给定的扩散系数公式D=D0exp(−Q/RT)，并进行简单的数值代入和计算。不需要额外的概念理解或复杂的解题步骤，属于单一公式直接计算的难度等级。" + }, + { + "idx": 256, + "question": "The diffusion coefficients of carbon in titanium measured at different temperatures are 2×10−9cm2/s (736℃), 5×10−9cm2/s (782℃), and 1.3×10−8cm2/s (838℃). Please calculate the activation energy for diffusion.", + "answer": "From the previous step, it is known that Q=2342787J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用公式计算扩散的活化能。答案是一个具体的数值结果，需要通过数值计算和公式应用得出。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和线性回归分析，属于中等应用层次。虽然计算过程较为直接，但需要理解扩散系数与温度的关系，并进行数据处理和公式转换。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与温度的关系（阿伦尼乌斯方程），进行多步对数计算和斜率求解，最后转换为激活能量。虽然选择题提供了正确选项，但仍需完成完整的计算流程才能验证答案的正确性，涉及中等应用层次的知识综合运用能力。" + }, + { + "idx": 257, + "question": "The diffusion coefficients of carbon in titanium at different temperatures were experimentally measured as 2×10−9cm2/s (736℃), 5×10−9cm2/s (782℃), and 1.3×10−8cm2/s (838℃). Given the activation energy for diffusion Q=2342787J/mol, determine the diffusion coefficient of carbon at 500℃.", + "answer": "Substituting T=773K into D=D0exp(−Q/RT), with Q=2342787J/mol known, D0 is derived from D̅1=2×10−9cm2/s and T1=1009K as D0=2×10−9exp(2342787/(8.31×1009)). The calculated D500℃=1.87×10−10cm2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的实验数据和公式（D=D0exp(−Q/RT)）进行数值计算，最终得出特定温度下的扩散系数。答案是一个具体的数值计算结果（D500℃=1.87×10−10cm2/s），符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，包括从已知数据推导前置因子D0，再计算新温度下的扩散系数。涉及公式变形、对数运算和单位转换，属于中等难度的应用题型。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与温度的关系（阿伦尼乌斯方程），并能够正确代入已知条件进行多步计算。题目要求从实验数据推导出前置因子D0，再计算新温度下的扩散系数，涉及多个概念的综合应用和较复杂的计算步骤。虽然题目提供了部分关键参数，但解题过程仍需较强的综合分析能力。" + }, + { + "idx": 258, + "question": "The diffusion coefficients of carbon in titanium were experimentally measured at different temperatures as 2×10−9cm2/s (736℃), 5×10−9cm2/s (782℃), and 1.3×10−8cm2/s (838℃). Please determine whether the experimental results conform to D̅=D̅0exp(−ΔG/RT).", + "answer": "Substituting D̅1=2×10−9cm2/s, D̅2=5×10−9cm2/s, D̅3=1.3×10−8cm2/s, T1=1009K, T2=1055K, T3=1111K into D=D0exp(−ΔG/RT) and following the method used in 7-4 yields Q1=2342787J/mol. Similarly, substituting D̅2, D̅3, T2, T3 gives Q2=2342132J/mol. It can be concluded that the experiment conforms to D=D0exp(−ΔG/RT).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来验证实验结果是否符合给定的扩散系数方程，答案中包含了具体的计算步骤和结果。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及不同温度下的数据代入和活化能的计算，属于中等难度的应用题目。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与温度关系的阿伦尼乌斯方程，并进行多步计算和比较分析。题目要求将实验数据代入公式并计算激活能，验证数据是否符合理论模型，涉及中等应用层次的知识和综合分析能力。虽然题目提供了正确选项，但仍需理解计算过程和概念关联才能做出正确判断。" + }, + { + "idx": 259, + "question": "Calculate the diffusion coefficient of carbon in α-Fe (body-centered cubic), given the diffusion coefficient formula as D=0.0079exp[-83600/RT] cm²/s, temperature T=800°C (1073K), and gas constant R=8.314 J/(mol·K).", + "answer": "Substitute T=1073K into the formula D=0.0079exp[-83600/(8.314×1073)] cm²/s, and calculate to obtain D_α=6.7×10^-7 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及直接套用给定的扩散系数公式进行数值计算，无需多步推理或综合分析，属于基本公式应用和简单计算范畴。 | 难度: 在选择题型中，该题目仅需要直接套用给定的扩散系数公式，并进行简单的数值计算。解题步骤非常直接，不涉及多个公式的组合或复杂的概念理解，因此属于单一公式直接计算的难度等级1。" + }, + { + "idx": 260, + "question": "In a certain material, the grain boundary diffusion coefficient and volume diffusion coefficient of a certain particle are $\\mathrm{D}_{\\mathrm{sb}}{=}2.00\\times{10}^{-10}\\mathrm{exp(-}$ 19100/RT) $\\mathrm{cm}^{2}/\\mathrm{s}$ and $\\mathrm{D}_{\\mathrm{v}}{=}1.00\\times\\mathrm{10}^{-4}\\mathrm{exp}$ (－38200/RT) cm²/s, respectively. Determine the temperature ranges in which the grain boundary diffusion coefficient and volume diffusion coefficient dominate.", + "answer": "When the grain boundary diffusion coefficient dominates, $\\mathrm{D}_{\\mathrm{gb}}>\\mathrm{D}_{\\mathrm{v}}$, i.e., $2.00\\times10^{-10}\\exp(-\\frac{19100}{R T})$ $1.00\\times10^{-4}\\exp(-\\frac{38200}{R T})$. Thus, T<1455.6K; when T>1455.6K, the volume diffusion coefficient dominates.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定温度范围，答案中涉及到了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和公式应用，包括比较两个扩散系数的大小关系，并通过解不等式确定温度范围。这需要理解扩散系数的物理意义和温度依赖关系，并进行适当的数学处理，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握扩散系数的概念，并能通过数学计算比较两种扩散系数在不同温度下的主导地位。解题步骤涉及指数函数的比较和对数运算，属于多步骤计算过程。虽然题目提供了公式，但需要考生具备一定的综合分析能力来确定温度范围。" + }, + { + "idx": 261, + "question": "In the fabrication of silicon semiconductor devices, boron is often diffused into silicon single crystals. If at a temperature of 1600K, the boron concentration on the surface of the silicon single crystal is kept constant (constant source semi-infinite diffusion), and the boron concentration at a depth of $10^{-3}\\\\mathrm{cm}$ from the surface is required to be half of the surface concentration (erfc =0.5 $\\\\frac{x}{2\\\\sqrt{D t}}$ 0.5), how long is needed (given $\\\\boldsymbol{D_{1600^{*}C}}=8\\\\times10^{-12}\\\\mathrm{{cm}^{2}/{s}}$ when 2√Dt, 2√D# )?", + "answer": "This model can be regarded as a one-dimensional diffusion problem of a semi-infinite rod, which can be solved using the Gaussian error function. $\\\\frac{C_{0}-C}{C_{0}-C_{1}}=\\\\mathrm{erf}(\\\\frac{x}{2\\\\sqrt{D t}})$ where $\\\\mathcal{C}_{1\\\\mathrm{~=~}0}$, $C=0.5C_{0}$, so there is $\\\\cot(\\\\frac{x}{2\\\\sqrt{D t}})$, 2=0.5. Substituting $x=10^{-3}\\\\mathrm{cm}$ and $D=8\\\\times10^{-12}\\\\mathrm{{cm}^{2}/\\\\mathrm{{s}}}$ yields $t=1.25\\\\times10^{5}\\\\mathrm{~s~}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和误差函数的计算，最终需要得出具体的时间数值。 | 知识层次: 题目涉及扩散方程的求解和误差函数的应用，需要多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解半导体扩散的基本概念（如恒定源半无限扩散模型），正确应用误差函数（erf）公式，并进行多步骤的代数运算和单位换算。题目涉及中等应用层次的知识，要求考生能够将扩散系数、浓度分布和时间计算等概念关联起来，综合分析求解。虽然题目提供了关键公式和参数，但解题过程仍需较强的逻辑推导和计算能力，属于综合性计算问题。" + }, + { + "idx": 262, + "question": "Explain the difference in diffusion coefficients of carbon in α-Fe and γ-Fe.", + "answer": "The structure of the diffusion medium has a significant impact on diffusion. α-Fe has a body-centered cubic structure, while γ-Fe has a face-centered cubic structure. The body-centered cubic structure is more open than the face-centered cubic structure. A more open structure results in lower diffusion resistance and a higher diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释碳在α-Fe和γ-Fe中扩散系数的差异，答案通过文字论述了晶体结构对扩散的影响，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释碳在α-Fe和γ-Fe中扩散系数的差异，需要理解晶体结构（体心立方和面心立方）对扩散的影响，并关联结构特征与扩散性能的关系。这涉及多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。虽然题目形式是选择题，但正确选项要求考生：" + }, + { + "idx": 263, + "question": "Calculate the diffusion coefficient of carbon in γ-Fe (face-centered cubic), given the diffusion coefficient formula as D=0.21exp[-141284/RT] cm²/s, temperature T=800°C (1073K), and gas constant R=8.314 J/(mol·K).", + "answer": "Substitute T=1073K into the formula D=0.21exp[-141284/(8.314×1073)] cm²/s, and calculate to obtain D_γ=2.1×10^-8 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目要求直接套用给定的扩散系数公式进行数值计算，属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的扩散系数公式，并进行简单的数值代入和计算。不需要理解多个概念或进行复杂的分析，属于单一公式直接计算的难度等级。" + }, + { + "idx": 264, + "question": "The diffusion activation energies of carbon, nitrogen, and hydrogen in body-centered cubic iron are 84 kJ/mol, 75 kJ/mol, and 13 kJ/mol, respectively. Analyze and explain this difference.", + "answer": "The atomic radii of carbon, nitrogen, and hydrogen decrease sequentially. The smaller the atomic radius, the easier it is for the atom to diffuse through the gaps in body-centered cubic iron, and the lower the corresponding diffusion activation energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析和解释扩散激活能的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析不同元素在体心立方铁中扩散激活能的差异，并解释其机理。这需要综合运用原子半径、晶体结构间隙和扩散机制等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅掌握扩散激活能的基本概念，还需要理解原子半径与晶体结构间隙之间的关系，并能将这些知识综合运用到体心立方铁的特定结构中。正确选项涉及机理层面的解释（原子半径越小越容易扩散），需要考生进行推理分析并解释现象背后的物理机制。这种在选择题中要求机理深度解释的题目，明显高于单纯记忆或简单应用的难度水平，但尚未达到需要全面分析复杂现象的最高难度（等级5）。" + }, + { + "idx": 265, + "question": "Analyze the reasons why the diffusion coefficient of anions is generally smaller than that of cations in ionic crystals.", + "answer": "In ionic crystals, anions generally form close packing, while cations fill the tetrahedral or octahedral voids. Therefore, cations diffuse more easily. If anions diffuse, the crystal packing arrangement must be altered, disrupting the structural framework of the ionic crystal, which results in greater resistance. Hence, in ionic crystals, the diffusion coefficient of anions is generally smaller than that of cations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析离子晶体中阴离子扩散系数通常小于阳离子的原因，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析离子晶体中阴离子扩散系数小于阳离子的原因，涉及对晶体结构、扩散机制和能量障碍的综合理解。需要解释阴离子紧密堆积和阳离子占据空隙的结构特点，以及扩散过程中结构框架改变带来的阻力增加。这种分析需要将多个概念关联起来，并进行推理和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解离子晶体中阴离子和阳离子的扩散机制，还需要深入分析晶体结构对扩散系数的影响。正确选项涉及对晶体堆积方式、空隙填充以及结构框架破坏的综合考量，需要考生具备复杂的推理分析能力和机理解释能力。这种题目在选择题中属于对知识深度和综合运用能力要求极高的类型。" + }, + { + "idx": 266, + "question": "What are the advantages, disadvantages, and applicable conditions of the Jander equation?", + "answer": "The Jander equation has good adaptability in the initial stage of the reaction, but the Jander model assumes that the cross-section of spherical particles remains unchanged. Therefore, it is only applicable to cases with low conversion rates in the initial stage of the reaction. Both equations are only applicable to stable diffusion conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Jander方程的优缺点和适用条件，答案提供了文字论述而非选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求分析Jander方程的优缺点和适用条件，涉及对模型假设的理解、适用范围的判断以及稳定扩散条件的综合分析。这需要将多个概念关联起来进行中等程度的分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目要求考生不仅要理解Jander方程的基本概念，还需要综合分析其优缺点和适用条件。题目涉及多个知识点的关联，包括方程在反应初期的适应性、球形颗粒横截面不变的假设限制，以及稳定扩散条件的适用范围。这些要求超出了简单的记忆或单一概念的应用，属于多角度分析论述的层次，因此难度等级为4。" + }, + { + "idx": 267, + "question": "What are the advantages, disadvantages, and applicable conditions of the Ginstling equation?", + "answer": "The Ginstling equation takes into account the fact that the reaction cross-sectional area changes during the reaction process, thus the Ginstling equation has a wider range of application and can be suitable for the initial and middle stages of the reaction. Both equations are only applicable to steady-state diffusion conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Ginstling方程的优缺点及适用条件，需要文字论述而非选择、判断或计算 | 知识层次: 题目要求分析Ginstling方程的优缺点和适用条件，需要理解该方程的特点及其与反应过程的关系，涉及多个概念的关联和综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在选择题型中，该题目要求考生不仅理解Ginstling方程的基本概念，还需要综合分析其优缺点及适用条件，并与稳态扩散条件进行关联。这涉及多角度分析论述，超出了简单记忆或单一概念应用的层次，属于较高难度的选择题。" + }, + { + "idx": 268, + "question": "Explain from the perspectives of structure and energy why $\\mathrm{D}_{\\rightleftarrows\\mathrm{m}}>\\mathrm{D}_{\\rightleftarrows\\mathrm{m}}>\\mathrm{D}$ within the crystal.", + "answer": "Under the influence of surface forces, the particles on the solid surface undergo polarization, deformation, rearrangement, and cause lattice distortion, making the surface structure different from the interior and placing the surface in a higher energy state. The internal particles of the crystal are arranged periodically, with each particle's force field being symmetrical. The activation energy required for particle migration on the surface is smaller than that within the crystal, resulting in a larger diffusion coefficient. Similarly, the arrangement of particles at grain boundaries differs from the interior, being disordered and containing defects such as vacancies and dislocations, placing them in a state of stress distortion with higher energy. The activation energy required for particle migration at grain boundaries is smaller than that within the crystal, leading to a larger diffusion coefficient. However, compared to the interior of the crystal, particles at grain boundaries are influenced by two grains to reach an equilibrium state, adopting a transitional arrangement with lower energy than surface particles. Thus, the resistance to particle migration is greater, resulting in $\\mathrm{D}_{\\mathrm{~\\rightmoon~}}\\mathrm{\\approx}{}$ the surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从结构和能量的角度解释晶体中扩散系数的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从结构和能量的角度解释晶体中不同区域的扩散系数差异，涉及表面、晶界和晶体内部的结构差异、能量状态以及粒子迁移的激活能等复杂概念的综合分析和推理。需要深入理解材料科学中的扩散机制、缺陷理论和能量状态，并进行多方面的关联和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从结构和能量的角度深入解释晶体中不同区域的扩散系数差异，涉及表面力、极化、晶格畸变、晶界缺陷等多个复杂概念的综合运用。解题需要全面分析表面、晶界和晶体内部的结构差异与能量状态，并推理其对扩散激活能和扩散系数的影响机制。这种深度机理解释和复杂现象分析在选择题中属于对知识掌握和逻辑推理能力的最高要求。" + }, + { + "idx": 269, + "question": "For spherical Al2O3 particles with a diameter of 1μm surrounded by excess MgO particles, the formation of spinel is observed. At a constant temperature, 20% of the Al2O3 reacts in the first hour. Calculate the time required for complete reaction using the Jander equation.", + "answer": "Calculation using the Jander equation: [1-(1-G)^(1/3)]^2 = kt ⇒ k = [1-(1-G)^(1/3)]^2 / t Substituting the reaction time of 1h and reaction progress of 20% given in the problem, we obtain k = [1-(1-0.2)^(1/3)]^2 / 1 = 5.138×10^-3 h^-1 Therefore, the time required for complete reaction (G=1) is t = 1/k = 1/(5.138×10^-3) = 194.62 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用Jander方程进行数值计算，并给出具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要应用Jander方程进行多步计算，涉及反应动力学和固体反应的基本原理。虽然计算过程相对直接，但需要对公式进行适当变形和数值代入，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解Jander方程的应用并进行多步骤计算。题目要求考生不仅掌握反应动力学的基本概念，还需要能够正确代入数值并解方程。虽然计算过程较为直接，但涉及多个步骤和公式转换，属于综合性计算问题。" + }, + { + "idx": 270, + "question": "When measuring the decomposition rate of alumina monohydrate, it was found that during the isothermal reaction, the mass loss increased linearly with time up to about 50%, and the rate of mass loss was less than the linear law when exceeding 50%. The rate increases exponentially with temperature. Is this a diffusion-controlled reaction or an interface first-order reaction-controlled reaction?", + "answer": "According to the analysis of the kinetic equations for some important solid-phase reactions in Table 8-2 and the G-t/t0.5 curves for various types of reactions in Figure 8-22, it is known from the problem statement that when G ≤ 50%, G-t shows a linear relationship, and when G > 50%, G-t is less than the linear law. This is a diffusion-controlled reaction, and G² = kt.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述反应类型（扩散控制反应或界面一级反应控制反应），答案提供了详细的分析和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析实验数据并判断反应类型，需要综合运用动力学方程和反应机理知识，涉及多步推理和综合分析。不仅需要理解扩散控制和界面一级反应控制的区别，还需要根据G-t关系曲线进行判断，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 271, + "question": "When the temperature increases from 451°C to 493°C, the rate increases by a factor of 10. Calculate the activation energy of this process. (Analyze using Table 8-2 and Figure 8-22)", + "answer": "k=c exp(-Q/RT), and since G²=kt, substituting T₁=451°C=724K, T₂=493°C=766K, G₁=G, G₂=10G, we get k₂/k₁=G₂²/G₁²=exp(-Q/RT₂)/exp(-Q/RT₁)=100. Solving for Q gives Q=RT₁T₂ln(k₂/k₁)/(T₂-T₁)=8.314×724×766×ln(100)/(766-724)=505.561×10³ J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解激活能，答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解阿伦尼乌斯方程并正确代入温度转换后的数值进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来关联不同概念并正确执行计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解阿伦尼乌斯方程的应用，进行多步计算和温度单位转换，并正确代入公式求解活化能。虽然题目提供了部分解题思路，但仍需较强的综合分析能力和计算技巧。" + }, + { + "idx": 272, + "question": "What is phase transition?", + "answer": "Phase transition is the mutual transformation between different phases of a material system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"phase transition\"进行文字解释和论述，答案提供了概念的定义和说明，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即相变的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对\"相变\"这一基础概念的定义记忆，属于最基础的知识点掌握要求。正确选项直接给出了相变的定义，不需要任何解释、比较或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 273, + "question": "The formation reaction of mullite from Al2O3 and SiO powders is diffusion-controlled and conforms to the Jander equation. What effective measures should be taken to accelerate the formation of mullite?", + "answer": "All factors favorable for diffusion can be employed to accelerate the formation of mullite: reducing particle size, using reactive reactants (such as Al2O3·3H2O), applying appropriate pressure, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出有效的措施来加速莫来石的形成，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求考生理解扩散控制反应的基本原理（Jander方程），并能综合运用扩散影响因素（如颗粒尺寸、反应物活性、压力等）来提出加速莫来石形成的具体措施。这需要多步概念关联和综合分析能力，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解扩散控制反应的基本原理，并能够综合分析多种促进扩散的因素（如粒径减小、反应物活性、压力等）对反应速率的影响。虽然不需要进行复杂的计算，但需要对Jander方程和相关概念有一定的掌握，并能将这些概念关联起来进行判断。" + }, + { + "idx": 274, + "question": "Spherical Al2O3 particles with a diameter of 1μm are surrounded by excess MgO particles, and the formation of spinel is observed. At a constant temperature, 20% of the Al2O3 reacts in the first hour. Use the Ginstling equation to calculate the time required for complete reaction.", + "answer": "Calculation using the Ginstling equation:\\n\\n1-(2/3)G-(1-G)^(2/3) = kt ⇒ k = [1-(2/3)G-(1-G)^(2/3)] / t\\n\\nSimilarly, substituting the reaction time of 1h and reaction progress of 20% from the problem, we get\\n\\nk = [1-(2/3)×0.2-(1-0.2)^(2/3)] / 1 = 4.893×10^-3 h^-1\\n\\nTherefore, for complete reaction (G=1),\\n\\n1-(2/3)G-(1-G)^2 = kt ⇒ kt = 1/3\\n\\nThus, the time required for complete reaction is t = 1/(3k) = 1/(3×4.893×10^-3) = 68.12 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用Ginstling方程进行数值计算，以确定完全反应所需的时间。答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用Ginstling方程进行多步计算，涉及反应进度与时间的关系推导，并需要将已知条件代入公式求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解Ginstling方程的应用并进行多步骤计算。题目要求将反应进度与时间关联，涉及方程变形、常数求解和最终时间计算，步骤较为复杂但逻辑清晰。" + }, + { + "idx": 275, + "question": "Analyze the influence of the chemical composition and structure of reactants on solid-phase reactions", + "answer": "The greater the interaction force between particles in the reactants, the lower the reaction capability; in the same reaction system, the solid-phase reaction rate is related to the proportion between the reactants; the special role of mineralizers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析化学组成和结构对固相反应的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析反应物化学组成和结构对固相反应的影响，涉及多个因素的相互作用和机理解释，需要综合运用知识进行推理分析，思维深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求分析反应物化学组成和结构对固相反应的影响，涉及多个复杂概念的综合运用和推理分析。正确选项包含三个关键点：粒子间作用力与反应能力的关系、反应物比例对反应速率的影响以及矿化剂的特殊作用。这要求考生不仅掌握相关理论知识，还需要具备将不同概念联系起来进行综合分析的能力。此外，题目涉及的知识层次为\"复杂分析\"，需要考生进行机理解释和复杂现象的全面分析，这在选择题型中属于最高难度的要求。" + }, + { + "idx": 276, + "question": "The reaction of forming mullite from Al2O3 and SiO powders is controlled by diffusion and conforms to the Jander equation. The experiment was conducted under constant temperature conditions. When the reaction proceeded for 1 hour, it was measured that 15% of the reactants had reacted. In how much time will all the reactants be converted into products?", + "answer": "According to the Jander equation, [1-(1-0.15)^(1/3)]^2=k×1 ⇒ k=0.00278. The time required for the reaction to complete (G=1) is t=1/k=1/(2.78×10^(-3))=359.63h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程涉及使用Jander方程进行数学推导和计算，最终得出具体的时间数值。 | 知识层次: 题目需要应用Jander方程进行多步计算，涉及反应进度与时间的关系推导，需要理解扩散控制的反应动力学模型，并进行数值计算和公式转换，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Jander方程的应用并进行多步计算。题目要求考生首先根据已知条件计算反应速率常数k，然后利用该常数计算完全反应所需时间。这涉及到对扩散控制反应动力学的理解以及代数运算能力，属于综合性计算问题。" + }, + { + "idx": 277, + "question": "Analyze the effect of reaction temperature on solid-phase reactions", + "answer": "The higher the temperature, the stronger the thermal motion of particles, and the enhanced reaction and diffusion capabilities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析反应温度对固相反应的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析反应温度对固相反应的影响，需要理解温度与粒子热运动、反应能力和扩散能力之间的关系，涉及多概念关联和综合分析，但不需要深入机理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解温度对粒子热运动的影响以及反应和扩散能力之间的关系，并进行综合分析。题目涉及多步概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 278, + "question": "Analyze the effect of mineralizers on solid-state reactions", + "answer": "The larger the lattice energy, the more complete and stable the structure, and the lower the reaction activity. Adding mineralizers can enhance solid-state reactions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析矿物化剂对固态反应的影响，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求分析矿化剂对固态反应的影响，涉及对反应机理的理解和解释，需要综合运用材料科学中的固态反应理论、晶体结构稳定性以及反应动力学等知识，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 279, + "question": "Analyze the influence of pressure and atmosphere on solid-phase reactions", + "answer": "For reactions between two solid phases, increasing pressure helps enlarge the contact area between particles, accelerates the mass transfer process, and increases the reaction rate; for solid-phase reactions involving liquid or gas phases, raising pressure does not show a positive effect and may even be counterproductive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析压力和气氛对固相反应的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析压力和气氛对固相反应的影响，涉及对不同反应条件下反应机理的理解和解释，需要综合运用材料科学中的反应动力学和热力学知识，进行推理和分析。这超出了简单记忆或基本应用的范围，属于复杂分析的层次。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解压力对固相反应的影响，还需要区分不同反应体系（纯固相与涉及液相/气相）中压力作用的差异。正确选项涉及机理层面的解释（接触面积、传质过程）和复杂现象分析（压力可能产生反效果），需要综合运用材料科学和反应工程知识进行推理判断。这种在选择题中要求多维度分析且答案具有条件依赖性的题目，对考生的知识深度和逻辑思维能力提出了较高要求，符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 280, + "question": "Analyze the influence of particle size and distribution on solid-phase reactions", + "answer": "The smaller the particle size, the faster the reaction rate; in the same reaction system, due to differences in material size, the reaction rate will be governed by different kinetic regimes; the presence of a small amount of larger-sized particles can significantly delay the completion of the reaction process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析颗粒尺寸和分布对固相反应的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析颗粒尺寸和分布对固相反应的影响，涉及多因素的综合作用（如反应速率、动力学机制等），需要深入理解材料科学中的反应动力学原理，并进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于复杂分析的层次。 | 难度: 在选择题型中，该题目要求考生不仅理解粒子尺寸和分布对固相反应的影响，还需要综合运用多个知识点进行推理分析，解释不同动力学机制对反应速率的影响，以及少量大尺寸粒子如何显著延迟反应完成。这种复杂现象全面分析和机理深度解释的要求，使得该题目在选择题型中属于最高难度等级。" + }, + { + "idx": 281, + "question": "Analyze the effect of strain energy on the kinetics of solid-state phase transformations", + "answer": "Strain energy can influence the kinetics of phase transformation processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对固态相变动力学的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析应变能对固态相变动力学的影响，这需要综合运用材料科学中的相变理论、热力学和动力学知识，进行机理层面的解释和推理分析。涉及多个概念的关联和深入理解，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解应变能的基本概念，还需要综合分析其对固态相变动力学的影响机制。正确选项涉及复杂现象的全面分析，需要考生具备将热力学、动力学和材料微观结构知识进行整合的能力。这种在选择题中考查机理深度解释和复杂现象分析的能力，远超过简单记忆或基础理解层面，属于选择题型中的顶级难度。" + }, + { + "idx": 282, + "question": "According to the phase transition mechanism, what types can it be divided into?", + "answer": "According to the phase transition mechanism, it can be divided into diffusion-type phase transition, non-diffusion-type phase transition, and semi-diffusion-type phase transition. Phase transitions that rely on long-distance diffusion of atoms or ions are called diffusion-type phase transitions. Non-diffusion-type phase transitions refer to the movement of atoms or ions, but the relative displacement does not exceed the atomic spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据相变机制进行分类，并需要文字解释和论述不同类型的相变机制。答案提供了详细的分类和定义，符合简答题的特征。 | 知识层次: 题目考查的是对相变机制分类的基本概念记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及相变机制的分类，但正确选项已经提供了明确的定义和分类，考生只需理解并记忆这些基本概念即可。不需要进行复杂的分析或推理，但需要掌握相关术语和分类标准。" + }, + { + "idx": 283, + "question": "If magnesium aluminate spinel is to be synthesized, the available raw materials are MgCO, Mg(OH)2, MgO, Al2O3·3H2O, γ-Al2O3, α-Al2O3. From the perspective of increasing the reaction rate, which raw materials should be selected? Please explain the reason.", + "answer": "It is better to use MgCO3, Mg(OH)2, and Al2O3·3H2O as raw materials. This is because MgCO3 and Mg(OH)2 can undergo thermal decomposition during the reaction, and Al2O3·3H2O undergoes dehydration and crystal transformation, resulting in nascent or amorphous substances with larger specific surface areas and lattice defects, thereby enhancing the reaction activity and accelerating the solid-state reaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个原料中选择合适的组合，并解释原因。答案需要详细的文字解释和论述，说明选择特定原料的原因及其对反应速率的影响，这符合简答题的特征。 | 知识层次: 题目要求从反应速率的角度选择原料，并解释原因。这需要综合运用材料科学中的热分解、晶体转变、反应活性等知识，分析不同原料在反应过程中的行为及其对反应速率的影响。涉及多步骤的推理和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 284, + "question": "Analyze the effect of component changes on the driving force of solid-state phase transformation", + "answer": "The driving force for phase transformation is the difference in volume free energy between the new and old phases at the phase transition temperature (ΔG̃τ), and ΔG<0 is a necessary condition for the formation of the new phase. When two components mix to form a solid solution, the free energy of the mixed system changes. The magnitude of the driving force for phase transformation can be determined through the free energy-composition curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析成分变化对固态相变驱动力的影响，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析组分变化对固态相变驱动力的影响，涉及自由能-成分曲线的理解和应用，需要综合运用热力学原理和相变理论进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解固态相变驱动力的基本概念（ΔG̃τ和ΔG<0的必要条件），还需要掌握自由能-成分曲线的分析方法，并能综合运用这些知识来判断组分变化对相变驱动力的影响。这涉及到复杂的热力学原理和相图分析能力，需要考生具备深度的机理理解和综合推理能力，属于选择题型中对知识掌握深度和综合分析能力要求最高的类型。" + }, + { + "idx": 285, + "question": "Analyze the effect of strain energy on the thermodynamics of solid-state phase transformations", + "answer": "Strain energy can influence the magnitude of the phase transformation driving force.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对固态相变热力学的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析应变能对固态相变热力学的影响，这需要综合运用应变能和相变热力学的知识，进行推理分析和机理解释。涉及多个概念的关联和综合分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 286, + "question": "What is the difference between martensitic transformation and nucleation-growth transformation?", + "answer": "In the nucleation-growth process, there is a diffusion transformation, the composition of the parent phase and the crystalline phase can be the same or different, the transformation speed is relatively slow, and there is no obvious start and end temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种转变过程的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种相变过程的区别，涉及对马氏体相变和形核-生长相变的基本概念的理解，以及它们之间的对比分析。虽然不涉及复杂的计算或深度推理，但需要对两种相变过程的特点有较为全面的掌握，并进行概念关联和综合分析。 | 难度: 在选择题中属于较高难度，题目要求考生不仅要理解马氏体相变和形核-生长相变的基本概念，还需要对两种相变过程的特点进行多角度比较分析（如扩散行为、成分变化、转变速度、温度特征等）。这需要考生具备将多个知识点关联起来进行综合分析的能力，而不仅仅是简单的概念记忆或单一知识点应用。" + }, + { + "idx": 287, + "question": "What are the characteristics of martensitic transformation?", + "answer": "Martensitic transformation is a first-order nucleation and growth phase transformation in which substitutional atoms undergo diffusionless shear displacement (uniform or non-uniform), resulting in shape change and surface relief, and possesses the characteristics of invariant plane strain. Features: it has shear uniformity and regularity, no atomic diffusion occurs, the transformation speed is fast, the transformation occurs within a certain range, and there is a large shear-type elastic strain energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查马氏体相变的基本特征和定义，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及马氏体相变的多个特征，如无扩散、剪切均匀性、快速转变等，但这些都属于基础概念的解释和描述，不需要进行复杂的比较分析或深入的概念体系阐述。选择题型中，学生只需识别和记忆这些特征即可正确作答，因此难度等级为2。" + }, + { + "idx": 288, + "question": "Analyze the effect of surface energy on the kinetics of solid-state phase transformations", + "answer": "Surface energy can influence the kinetics of phase transformation processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析表面能对固态相变动力学的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析表面能对固态相变动力学的影响，这需要综合运用表面能和相变动力学的知识，进行机理的解释和推理分析。涉及多个概念的关联和深层次的理解，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 289, + "question": "Analyze the influence of surface energy on the shape of new phases", + "answer": "Surface energy can influence the shape of new phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析表面能对新相形状的影响，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求分析表面能对新相形状的影响，这需要综合运用表面能的概念、新相形成的机理以及形状变化的驱动因素等多方面知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 290, + "question": "Analyze the effect of strain energy on the shape of the new phase", + "answer": "Strain energy can influence the shape of the new phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对新相形状的影响，需要文字解释和论述，答案形式为简短的文字说明而非计算或选择 | 知识层次: 题目要求分析应变能对新相形状的影响，这需要综合运用材料科学中的相变理论、弹性力学和热力学知识，进行推理分析和机理解释。涉及多个概念的关联和深层次理解，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求分析应变能对新相形状的影响，这涉及到对材料科学中相变机理的深入理解。正确选项虽然简洁，但背后需要考生掌握应变能与相变形状之间的复杂关系，并能进行机理层面的解释。这种题目不仅测试基础概念，还要求考生能够综合运用知识进行推理分析，因此在选择题型中属于机理深度解释的难度等级。" + }, + { + "idx": 291, + "question": "Analyze the influence of surface energy on the thermodynamics of solid-state phase transformations", + "answer": "The surface of a substance has surface tension α. To reversibly increase the surface area dA under constant temperature and pressure, work αdA is required. Since the work required equals the increase in the system's free energy, and this increase is due to the enlargement of the system's surface area, it is termed surface free energy or surface energy. Surface energy can influence the magnitude of the phase transformation driving force.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析表面能对固态相变热力学的影响，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析表面能对固态相变热力学的影响，涉及表面自由能的概念、热力学原理的应用，以及相变驱动力变化的解释。这需要综合运用多个概念，进行推理分析和机理解释，思维深度较高。 | 难度: 在选择题型中，该题目要求考生综合运用表面能、热力学自由能以及相变驱动机理等复杂概念，并进行深度推理分析。题目不仅涉及基本概念的定义（如表面能的计算），还需要理解这些概念如何影响固态相变的热力学过程。这种需要多知识点综合运用和机理深度解释的题目，在选择题型中属于最高难度等级。" + }, + { + "idx": 292, + "question": "Analyze the effect of undercooling variation on the driving force during solid-state phase transformation", + "answer": "Undercooling is the difference between the critical phase transformation temperature and the actual transformation temperature. The thermodynamic condition for phase transformation nucleation requires undercooling. The relationship between the driving force ΔG and undercooling ΔT is: ΔGg=-Lν(ΔT/T0)T, which further illustrates the thermodynamic condition for nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析过冷度变化对固态相变驱动力的影响，需要文字解释和论述，答案也提供了详细的文字说明和公式解释，符合简答题的特征。 | 知识层次: 题目要求分析过冷度变化对固态相变驱动力的影响，涉及热力学条件的理解和推导，需要综合运用相变理论、热力学公式和机理解释，思维过程深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求分析过冷度变化对固态相变驱动力的影响，涉及复杂的热力学条件和机理解释。正确选项不仅需要理解过冷度的定义（临界相变温度与实际相变温度的差值），还需要掌握驱动力的计算公式ΔGg=-Lν(ΔT/T0)T，并能解释其热力学意义。这要求考生具备综合运用知识、推理分析和机理解释的能力，属于复杂现象的全面分析层次。因此，在选择题型中属于最高难度等级。" + }, + { + "idx": 293, + "question": "What are the characteristics of the microstructure and properties obtained by spinodal decomposition?", + "answer": "The microstructure obtained by spinodal decomposition typically exhibits a quasi-periodic and interconnected composition modulation structure or a sponge-like organization, which is uniformly fine and can only be resolved under an electron microscope.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释spinodal分解获得的微观结构和性能特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目要求解释spinodal分解获得的微观结构和性能特征，涉及对分解机理的理解、微观结构的描述以及性能与结构关系的综合分析，需要较高的认知能力和深度理解。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解spinodal分解的基本概念，还需要掌握其微观结构特征（准周期、互连成分调制结构或海绵状组织）和性能特点（均匀细小、仅电子显微镜可分辨）。这需要综合运用材料科学原理进行复杂现象分析，并具备机理深度解释能力。选择题型中正确选项的识别需要考生对专业术语和微观组织特征有精确理解，远超简单记忆或基础概念识别的难度。" + }, + { + "idx": 294, + "question": "What is homogeneous nucleation?", + "answer": "Homogeneous nucleation occurs in a uniform medium, where the probability of nucleation is the same throughout the entire medium, independent of interfaces or defects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"homogeneous nucleation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即均匀成核的定义和基本特征，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求识别和记忆\"均质形核\"的基本定义，属于最基础的概念记忆层次。正确选项直接给出了定义性描述，无需进行概念比较或复杂推理，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 295, + "question": "Please analyze the influence of temperature on the thermodynamics and kinetics of phase transitions.", + "answer": "When the temperature decreases, the degree of undercooling increases, the nucleation barrier decreases, and the nucleation rate increases until reaching the maximum value; when the temperature continues to decrease, the liquid phase viscosity increases, and the diffusion rate of atoms or molecules decreases. Both excessively high and low temperatures are unfavorable for nucleation and growth rates, and only at a certain temperature can the maximum nucleation and growth rates be achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析温度对相变热力学和动力学的影响，需要详细的文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特点。 | 知识层次: 题目要求分析温度对相变热力学和动力学的影响，涉及多个概念（如过冷度、成核势垒、成核速率、液相粘度、原子扩散速率等）的综合运用和关联分析，需要深入理解温度变化如何影响相变过程的不同方面，并进行推理分析。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求综合运用热力学和动力学知识，分析温度对相变过程的多重影响机制，包括过冷度、成核势垒、成核速率、液相粘度、原子/分子扩散速率等多个变量的复杂交互作用。正确选项不仅需要理解每个独立概念，还需整合这些概念之间的动态关系（如温度变化如何通过不同路径影响成核和生长速率），并识别出非单调变化的临界点（最大成核/生长速率对应的温度）。这种深度机理解释和复杂现象全面分析的要求，在选择题型中属于最高认知层次，需要考生具备扎实的理论基础和综合推理能力。" + }, + { + "idx": 296, + "question": "What effect does a nucleating agent have on the critical nucleus radius r* during melt crystallization?", + "answer": "Using a nucleating agent can reduce ?s, thus r* decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释核化剂对临界核半径的影响，答案提供了简短的文字解释而非计算或选择 | 知识层次: 题目需要理解成核剂对临界核半径的影响机制，涉及表面能变化(Δσ)与临界半径(r*)的关联分析，属于概念关联和中等程度的应用分析。虽然不涉及多步计算，但需要理解Gibbs-Thomson方程的基本应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解成核剂对临界核半径的影响机制，并关联表面能（Δs）与临界核半径（r*）的关系。虽然不涉及多步计算，但需要对概念进行综合分析。" + }, + { + "idx": 297, + "question": "Given that iron has a body-centered cubic lattice with a lattice constant a=0.305 nm, determine how many unit cells the critical nucleus consists of at an undercooling of 100°C.", + "answer": "Nucleus volume = (4/3)×3.14×(1.775×10⁻⁹)³ = 2.34×10⁻²⁶ m³\\nUnit cell volume = (0.305×10⁻⁹)³ = 2.83×10⁻²⁹ m³\\nNumber of unit cells = 2.34×10⁻²⁶/2.83×10⁻²⁹ = 8.25×10⁸", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定临界核中的晶胞数量，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目需要进行多步计算，包括临界核体积和单位晶胞体积的计算，并将两者关联起来求解单位晶胞数量。这需要理解体心立方晶格结构、临界核形成概念以及相关公式的应用，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解临界核的概念、晶格常数与体积的关系，并进行多步计算（包括体积计算和除法运算）。虽然题目提供了具体数值，但解题步骤涉及单位转换和科学计数法运算，对计算能力和概念掌握有一定要求。" + }, + { + "idx": 298, + "question": "The atomic weight of iron is 55.84, its density is 7.3g/cm³, its melting point is 1593°C, its heat of fusion is 11495J/mol, and the solid-liquid interface energy is 2.04×10⁻⁵J/cm². Calculate the critical nucleus size at an undercooling of 10°C.", + "answer": "ΔGᵥ = - (7.3×10³)/(55.84×10⁻³) × (11495×283)/1876 = -2.267×10⁸ J/m³\\nr* = - (2×2.04×10⁻⁵)/(-2.267×10⁸) = 1.8×10⁻⁷ m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用热力学和材料科学知识进行计算，包括临界核尺寸的计算公式应用和单位转换等，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步计算和多个概念的关联应用，包括原子重量、密度、熔点、熔化热、界面能等参数的转换和综合运用。虽然题目提供了正确选项，但解题过程需要理解并正确应用热力学公式和临界核尺寸的计算方法，属于综合性计算问题。" + }, + { + "idx": 299, + "question": "Why is a certain degree of undercooling or overheating required for phase transformation in the nucleation-growth mechanism? Under what conditions is undercooling needed, and under what conditions is overheating needed?", + "answer": "From the thermodynamic formula ΔG=ΔH-TΔS, at equilibrium, ΔG_V=ΔH-T_mΔS=0, ΔS=ΔH/T_m. T: equilibrium phase transition temperature; ΔH: heat of phase transition. At temperature T, the system is in a non-equilibrium state, then ΔG=ΔH-TΔS≠0. ΔG=ΔH(T_m-T)/T_m=ΔHΔT/T_m. For the phase transition to occur spontaneously, ΔG<0 must be satisfied, i.e., ΔTΔH<0. Therefore, ΔT≠0 must be achieved for the phase transition to occur. For exothermic processes such as crystallization and condensation, ΔH<0, then ΔT>0, T>0, undercooling is required. For endothermic processes such as evaporation and melting, ΔH>0, then ΔT<0, T>0, overheating is required.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么需要过冷或过热来进行相变，以及在什么条件下需要过冷或过热。答案提供了详细的文字解释和论述，涉及热力学公式和相变条件，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求解释相变过程中过冷或过热的热力学原理，并分析不同条件下所需的过冷或过热条件。这需要综合运用热力学公式（ΔG=ΔH-TΔS）进行推理分析，理解非平衡状态下的相变条件，并解释不同相变过程（放热和吸热）对温度条件的要求。思维过程涉及多步推理和综合分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解热力学公式ΔG=ΔH-TΔS，并能够综合运用这一公式分析相变过程中的非平衡态条件。解题步骤复杂，需要推导出ΔG=ΔHΔT/T_m，并进一步分析不同相变过程（放热与吸热）对ΔT的要求。此外，题目还要求区分结晶/冷凝（需要过冷）与蒸发/熔化（需要过热）的具体条件，这需要考生具备机理深度解释和复杂现象全面分析的能力。在选择题型内，这类综合运用热力学原理进行多步骤推理的题目属于最高难度层级。" + }, + { + "idx": 300, + "question": "What are the differences and similarities between spinodal decomposition and precipitation decomposition?", + "answer": "Spinodal decomposition involves the segregation through diffusion, decomposing a single solid solution into two solid solutions with the same structure as the parent phase but different compositions. Precipitation decomposition is the process of precipitating a second phase from a supersaturated solid solution. Their main differences are as follows: (1) Spinodal decomposition belongs to continuous phase transformation. It is a solid-state phase transformation without a thermodynamic energy barrier or nucleation. Precipitation decomposition is a nucleation-growth type phase transformation, with a thermodynamic energy barrier and a nucleation process. (2) In the early stages of spinodal decomposition, compositional fluctuations within the parent phase are gradually established, and the compositions of the two phases change continuously over time following a sinusoidal distribution pattern, eventually reaching the equilibrium phase composition. Once the nucleus of precipitation decomposition forms in the parent phase, its composition is that of the equilibrium phase, with little subsequent change. (3) Spinodal decomposition occurs uniformly in the parent phase; precipitation nuclei generally form at crystal defects. (4) The amplification process in spinodal decomposition occurs through uphill diffusion. The formation of precipitate nuclei occurs through downhill diffusion. (5) The two segregated regions in spinodal decomposition have an indistinct coherent interface. The precipitate phase and the parent phase have a distinct interface. (6) The microstructure of spinodal decomposition is regular, while that of precipitation decomposition is less uniform. Similarity: Both proceed through solute diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种分解过程的区别和相似之处，需要详细的文字论述和比较，符合简答题的特征。答案提供了详细的解释和对比，没有涉及选择、判断或计算。 | 知识层次: 题目要求对两种分解过程进行详细的比较和相似性分析，涉及多个方面的差异和共同点，需要深入理解和综合分析材料科学中的相变机制和扩散过程。这不仅需要记忆基本概念，还需要对相关原理进行推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面理解和分析两种复杂的材料分解机制（spinodal decomposition和precipitation decomposition），包括它们的差异（6个方面）和相似性（1个方面）。这需要考生：" + }, + { + "idx": 301, + "question": "What is heterogeneous nucleation?", + "answer": "Heterogeneous nucleation occurs at heterogeneous interfaces, such as container walls, bubble interfaces, or on foreign substances (impurities or nucleating agents).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"heterogeneous nucleation\"进行文字解释和论述，答案提供了详细的定义和例子，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，仅需回答异质成核的定义及其发生的位置，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生识别并回忆\"heterogeneous nucleation\"的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了定义描述，不需要任何解释、比较或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 303, + "question": "During the melt cooling and crystallization process, given the solid-liquid interface energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=2090 J/cm^3 at 900°C, calculate the critical nucleus radius.", + "answer": "The critical nucleus radius r* = -2γ_sl/△Gv = -2×5×10^-6/2090 = 4.78×10^-10 m = 0.478 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体计算，最终得出一个数值结果（临界核半径），符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，直接套用临界核半径公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（临界核半径公式）进行简单计算，无需理解多个概念或进行复杂的分析。解题步骤非常直接，属于最基础的难度等级。" + }, + { + "idx": 304, + "question": "During the melt cooling and crystallization process, given the solid-liquid interface energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=418 J/cm^3 at 1000°C, calculate the critical nucleus radius.", + "answer": "The critical nucleus radius r* = -2γ_sl/△Gv = -2×5×10^-6/418 = 2.39×10^-9 m = 2.39 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行计算，最终得出一个具体的数值结果（临界核半径），属于典型的计算题类型。 | 知识层次: 题目要求直接套用临界核半径公式进行计算，属于基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（临界核半径公式）进行简单计算，无需理解多个概念或进行复杂分析。解题步骤非常直接，属于最基础的难度等级。" + }, + { + "idx": 305, + "question": "Given that iron has a body-centered cubic lattice with a lattice constant a=0.305nm, calculate the number of unit cells that make up the critical nucleus at an undercooling of 10°C.", + "answer": "Nucleus volume = (4/3)×3.14×(1.8×10⁻⁹)³ = 2.44×10⁻²⁶ m³\\nUnit cell volume = (0.305×10⁻⁹)³ = 2.83×10⁻²⁹ m³\\nNumber of unit cells = 2.44×10⁻²⁶/2.83×10⁻²⁹ = 8.61×10⁸", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶格常数、临界核体积和单元晶胞体积的计算，最终得出单元晶胞的数量。答案以数值结果呈现，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括临界核体积和单位晶胞体积的计算，并涉及概念关联（如临界核尺寸与过冷度的关系）。虽然计算过程较为直接，但需要综合运用材料科学中的晶体结构和形核理论知识。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算（临界核体积、晶胞体积、单位晶胞数量计算），需要综合理解晶体结构、成核理论和单位转换等概念。虽然选项提供了计算过程，但考生仍需具备扎实的材料科学基础和计算能力才能正确理解和验证这些步骤。" + }, + { + "idx": 306, + "question": "During the melt cooling and crystallization process, given the solid-liquid interfacial energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=2090 J/cm^3 at 900°C, calculate the energy required for the phase transition.", + "answer": "The energy required for the phase transition △G* = 16πγ_sl^3/3(△Gv)^2 = 16×3.14×(5×10^-6)^3/3×(2090)^2 = 3.24×10^-19 J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果。 | 知识层次: 题目主要涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析，属于对相变能量计算的基本应用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了所需的公式和所有必要的参数，只需要将这些数值代入公式进行简单的计算即可得到正确答案。不需要理解多个概念或进行复杂的分析，因此属于最低难度等级。" + }, + { + "idx": 307, + "question": "During the melt cooling and crystallization process, given the solid-liquid interface energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=418 J/cm^3 at 1000°C, calculate the energy required for the phase transition.", + "answer": "The energy required for the phase transition △G* = 16πγ_sl^3/3(△Gv)^2 = 16×3.14×(5×10^-6)^3/3×(418)^2 = 1.19×10^-17 J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及的能量计算步骤明确且直接套用给定公式即可完成，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的公式进行计算，无需额外的概念理解或步骤组合。题目提供了所有必要的参数和明确的公式，解题过程仅涉及基本的数学运算，属于单一公式直接计算的简单应用层次。" + }, + { + "idx": 308, + "question": "When forming a cubic nucleus with edge length a in the liquid phase, determine the critical free energy change ΔG*", + "answer": "ΔGa* = -64γzs³/ΔGv² · ΔGv + 6 × 16γzs²/ΔGv² = 32γzs³/ΔGv²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算临界自由能变化ΔG*，答案给出了具体的计算公式和结果，属于典型的计算题类型。 | 知识层次: 题目需要应用临界自由能变化的公式，并进行多步计算和概念关联，涉及立方核形成的临界条件分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如临界自由能变化、表面能、体积自由能变化等）并进行多步计算和综合分析。题目涉及公式推导和变量替换，但选项提供了部分计算步骤的提示，降低了纯计算的复杂度。" + }, + { + "idx": 309, + "question": "When forming a cubic nucleus with edge length a in the liquid phase, determine the critical nucleus edge length a*", + "answer": "From ΔGa = ΔGv + ΔGs = a³ΔGv + 6a²γzs, setting dΔGa/da = 0, we obtain 3a²ΔGv + 12aγzs = 0. Therefore, a* = -4γzs/ΔGv", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定临界核边长a*，解答过程中涉及了微分运算和代数求解，最终给出了具体的计算公式和结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界核形成的能量平衡条件，并应用微分求极值的方法来求解临界核边长。虽然计算过程相对直接，但需要综合运用热力学和相变的基本原理，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解临界核形成的基本概念（ΔGv和γzs的含义），掌握自由能变化的表达式（ΔGa = a³ΔGv + 6a²γzs），并能正确进行微分运算（dΔGa/da = 0）求解临界条件。解题过程涉及多步骤计算和概念关联，但相比等级4的复杂多变量问题，计算步骤和变量关系相对明确。" + }, + { + "idx": 310, + "question": "Why is the ΔG* of a cube greater than that of a sphere?", + "answer": "When forming nuclei of the same volume, a³ = (4/3)πr³ ⇒ a > r. The surface area of a cube 6a² > the surface area of a sphere 4πr², therefore ΔG*cube > ΔG*sphere", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么立方体的ΔG*大于球体的ΔG*，答案通过文字解释和公式应用进行了论述，没有涉及选项选择、对错判断或具体数值计算。 | 知识层次: 题目需要理解核化自由能（ΔG*）与几何形状的关系，涉及体积和表面积的计算比较，属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及ΔG*的计算和几何形状对表面能的影响，要求考生能够将体积与表面积的关系联系起来，并进行多步计算和综合分析。虽然题目提供了正确选项，但仍需要一定的知识掌握和逻辑推理能力来理解为什么立方体的ΔG*大于球体。" + }, + { + "idx": 311, + "question": "Are there differences in the atomic stacking modes and packing densities between face-centered cubic and hexagonal close-packed metals? Please explain.", + "answer": "FCC stacks in the ABCABC sequence, while HCP stacks in the ABABAB sequence; there is no difference in packing density, both are 0.74.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释面心立方和六方密堆积金属的原子堆垛方式和堆积密度差异，答案需要文字论述和解释，而非选择、判断或计算。 | 知识层次: 题目考查对FCC和HCP两种晶体结构的基本概念的记忆和理解，包括它们的原子堆垛顺序和堆积密度。不需要复杂的计算或综合分析，只需直接回答基本概念即可。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个晶体结构（FCC和HCP）的比较，但正确选项直接给出了明确的序列差异和相同的堆积密度，不需要复杂的推导或分析。主要考察的是对基础概念的记忆和简单对比，符合等级2的概念解释和描述要求。" + }, + { + "idx": 312, + "question": "What is a crystal face family?", + "answer": "A crystal face family refers to the combination of crystal faces with the same arrangement of atoms or molecules in a crystal. Due to symmetry relationships, there are often more than one type of such faces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"crystal face family\"进行文字解释和论述，答案提供了概念的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查晶体面族的基本定义和对称性关系的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅记住定义，还需要理解晶体面族的概念及其背后的对称性关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 313, + "question": "Which crystal planes are included in the cubic {111} plane family?", + "answer": "The cubic {111} plane family includes four planes: (111), (111), (111), (111).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举立方晶系{111}晶面族中包含的所有晶面，需要文字解释和具体回答，而不是选择、判断或计算。 | 知识层次: 题目考查对立方晶系中{111}晶面族包含的具体晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆立方{111}平面族包含的四个具体晶面，属于基础概念记忆的简单问题。不需要复杂的分析或推理，只需直接回忆定义即可作答。" + }, + { + "idx": 314, + "question": "What is the (100) interplanar spacing of a face-centered cubic metal? (a is the lattice constant)", + "answer": "The interplanar spacing d=a/2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算面心立方金属的(100)晶面间距，需要使用公式d=a/2进行计算，属于需要数值计算和公式应用的题目。 | 知识层次: 题目考查基本公式应用和简单计算，仅需套用面心立方晶体的晶面间距公式d=a/√(h²+k²+l²)，代入(100)面的hkl值即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（d=a/2）进行计算，无需额外的推导或组合多个公式。知识层次为简单应用，属于最基础的难度等级。" + }, + { + "idx": 315, + "question": "Compare interstitial solid solution and interstitial phase", + "answer": "Commonality: In both, the alloying elements are in interstitial positions and are themselves very small in size. Differences: Interstitial solid solution is a solid solution that retains the crystal structure of the solvent and has very low solubility, exhibiting tough and good plastic properties; interstitial phase is an intermediate phase (size-factor compound), with A and B atoms in proportional quantities, exhibiting hard properties and poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种不同的材料科学概念（间隙固溶体和间隙相），并详细解释它们的共同点和差异。答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对间隙固溶体和间隙相的基本概念的记忆和理解，包括它们的共同点和区别，属于基础概念的记忆性知识。 | 难度: 在选择题中属于较高难度，需要理解并比较两个复杂概念（间隙固溶体和间隙相）的共同点和差异点。题目不仅要求记忆定义，还需要分析两者的晶体结构、溶解度、力学性能等多方面特征，并进行综合对比。这种题目在选择题型中属于对知识掌握深度和综合分析能力要求较高的类型。" + }, + { + "idx": 316, + "question": "The melting point of copper T_m=1385K, at an undercooling of △T=0.2T_m, crystalline copper is obtained through homogeneous nucleation. Calculate the critical nucleus radius at this temperature. (ΔH=1628J/cm³, γ=1.77×10⁻⁵J/cm²)", + "answer": "From ΔG_v = - (ΔH × ΔT) / T_m = - (1628 × 0.2 × 1385) / 1385 = -325.6 J/cm³. The critical nucleus radius γ* = - (2 × γ) / ΔG_v = - (2 × 1.77 × 10⁻⁵) / (-325.6) = 1.087 × 10⁻⁷ cm ≈ 1.087 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出临界核半径的具体数值。答案展示了详细的推导和计算过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解过冷度的概念、应用临界核半径公式，并进行数值计算。虽然不涉及复杂的综合分析或创新应用，但需要将多个概念和公式关联起来进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如临界核半径、过冷度、自由能变化等）并进行多步骤计算。虽然题目提供了公式和数值，但需要正确应用公式并完成综合计算才能得出答案。" + }, + { + "idx": 317, + "question": "How do dislocations enter crystals?", + "answer": "The increase in dislocations mainly relies on deformation, where dislocations continuously generate within grains through nucleation and multiplication.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错如何进入晶体，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释位错进入晶体的机制，涉及位错的形核和增殖过程，需要综合运用材料科学中的位错理论，进行机理层面的解释和分析。这超出了简单记忆或基础应用的范畴，属于需要深入理解和推理的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解位错的基本概念，还需要掌握位错在晶体中产生的具体机制（形变过程中的成核和增殖）。这涉及到对复杂现象的全面分析，需要综合运用材料科学知识进行推理和解释。正确选项的表述也较为专业和深入，远超简单记忆或基础理解的层次，符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 318, + "question": "Explain the meaning of interstitial solid solution", + "answer": "An interstitial solid solution is a type of solid solution that retains the crystal structure of the solvent and has very low solubility. The alloying elements are located in the interstitial positions and are themselves very small in size. In terms of properties, it exhibits good toughness and ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙固溶体的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体这一基本概念的定义、特征和性质的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释间隙固溶体的定义和基本特性，但需要考生理解并记忆多个关键点（如晶体结构保留、低溶解度、间隙位置、尺寸要求以及力学性能）。这比单纯记忆基本定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 319, + "question": "Why is the strength of solid solutions often higher than that of pure metals?", + "answer": "Because the different sizes of the two types of atoms in the alloy cause lattice distortion, which hinders dislocation movement and results in solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么固溶体的强度通常高于纯金属，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及原子尺寸差异导致的晶格畸变以及位错运动的阻碍作用，需要综合运用材料科学中的晶体缺陷和强化机制知识进行推理分析。 | 难度: 在选择题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要掌握晶格畸变和位错运动之间的相互作用机制。这涉及到对材料科学中较为复杂的原理进行解释和分析，属于机理深度解释的层次。虽然题目提供了正确选项，但考生需要具备较高的知识整合能力和推理分析能力才能准确理解并选择正确答案。因此，在选择题型内属于较高难度等级。" + }, + { + "idx": 320, + "question": "What is the angle between the [100] and [111] crystallographic directions in face-centered cubic metals?", + "answer": "The angle between crystallographic planes cosφ=1/√3; φ=54.7°", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算面心立方金属中[100]和[111]晶向之间的夹角，需要通过公式计算得出具体数值（54.7°），属于典型的计算题类型。 | 知识层次: 题目涉及基本的晶体学方向计算，仅需套用已知的向量夹角公式（cosφ = (h1h2 + k1k2 + l1l2)/√(h1²+k1²+l1²)√(h2²+k2²+l2²)）进行一步计算，无需多步推导或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。解题仅需应用基本的向量点积公式cosφ = (h1h2 + k1k2 + l1l2)/√(h1²+k1²+l1²)√(h2²+k2²+l2²)，将[100]和[111]方向代入即可得到cosφ=1/√3。不需要额外的推导或复杂计算步骤，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 321, + "question": "What is the reason for the increase in strength caused by the proliferation of line defects and planar defects in crystals?", + "answer": "The reason is that the increase in both types of defects significantly hinders the movement of dislocations, thereby enhancing strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体中线缺陷和面缺陷增殖导致强度增加的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释线缺陷和面缺陷增殖导致强度增加的机理，涉及对晶体缺陷与位错运动之间相互作用的深入理解和综合分析，需要运用材料科学中的位错理论和强化机制进行推理分析。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅要理解线缺陷和面缺陷的基本概念，还需要深入掌握它们如何阻碍位错运动的机理。题目涉及晶体缺陷与力学性能之间的复杂关系，需要综合运用材料科学中的多个知识点进行推理分析，解释强度增加的深层原因。这种题目超出了简单记忆或基础理解的范畴，属于机理深度解释的层次。" + }, + { + "idx": 322, + "question": "If a crystal has a high density of line defects (dislocations) or planar defects (grain boundaries, twin boundaries, etc.), its strength will significantly increase. What are these phenomena called?", + "answer": "Called strain hardening and grain boundary strengthening (or fine-grain strengthening).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释现象并给出专业术语，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对材料科学中强化机制的基本概念的记忆和理解，如应变硬化和晶界强化，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分两种不同的强化机制（应变硬化和晶界强化/细晶强化），而不仅仅是简单的定义回忆。这要求考生对材料强化原理有一定的理解和应用能力，而不仅仅是机械记忆。因此，在选择题型内，该题目属于等级2难度。" + }, + { + "idx": 323, + "question": "How to increase the number of dislocations?", + "answer": "The number of dislocations can be increased by large deformation methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释如何增加位错数量，答案提供了简短的论述而非选择、判断或计算。 | 知识层次: 题目考查的是关于位错数量增加的基本方法，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"如何增加位错数量\"这一简单事实。正确选项直接给出了答案（大变形方法），不需要任何解释或推理过程。这属于最基本的概念记忆题，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 324, + "question": "Explain the meaning of interstitial phase", + "answer": "Interstitial phase is an intermediate phase (size-factor compound), and the number of A and B atoms is proportional. The alloy components are all in interstitial positions, with very small sizes themselves. In terms of properties, it exhibits high hardness and poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙相的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对间隙相（interstitial phase）这一基本概念的定义和特性的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生解释\"interstitial phase\"的定义和基本特性，属于概念解释和描述的难度级别。虽然涉及多个知识点（如定义、结构特点、性质），但不需要复杂的分析或比较，只需记忆和理解基本概念即可回答。因此属于中等难度（等级2）。" + }, + { + "idx": 325, + "question": "Calculate the number of atoms in the critical nucleus for copper with a face-centered cubic crystal structure. (a=0.3615nm)", + "answer": "The volume of the critical nucleus V = (4/3) × π × (γ*)³ = (4/3) × 3.14 × (1.087 × 10⁻⁷)³ = 5.39 × 10⁻²¹ cm³. The unit cell volume V_cell = a³ = (0.3615 × 10⁻⁷)³ = 4.72 × 10⁻²³ cm³. The number of unit cells N = V / V_cell = 5.39 × 10⁻²¹ / 4.72 × 10⁻²³ ≈ 114. The number of atoms in a face-centered cubic unit cell is 4, so the number of atoms in the critical nucleus = 114 × 4 = 456.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及原子数量、体积等具体计算步骤，答案也以数值结果呈现。 | 知识层次: 题目需要进行多步计算，包括临界核体积的计算、晶胞体积的计算以及单位晶胞内原子数的应用。虽然涉及的概念和公式较为基础，但需要将这些概念和公式综合运用，进行多步推导和计算，属于中等应用层次。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求进行多步骤的复杂计算，包括临界核体积、晶胞体积的计算，以及单位晶胞内原子数的转换。此外，还需要理解面心立方晶体结构的基本概念，并将这些概念综合应用到实际问题中。这种题目不仅考察了基础知识的掌握，还要求考生具备较强的计算能力和综合分析能力，因此在选择题型中属于复杂多变量计算的高难度题目。" + }, + { + "idx": 326, + "question": "How is grain refinement achieved?", + "answer": "Grain refinement can be achieved by adding heterogeneous nucleating agents or using high cooling rates during solidification, or through large deformation, recrystallization, or phase transformation methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何实现晶粒细化，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释晶粒细化的多种方法，涉及不同工艺和原理的综合应用，需要理解并关联多个知识点，如凝固过程、形变再结晶和相变等，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如异质形核、高冷却速率、大变形、再结晶和相变）并进行综合分析。虽然题目涉及多个知识点，但在选择题型中，正确选项已经整合了这些概念，考生只需识别和匹配相关知识即可，不需要进行多步计算或深度关联性分析。" + }, + { + "idx": 327, + "question": "How to improve the degree of grain refinement?", + "answer": "The degree of grain refinement can be improved by adding heterogeneous nucleation agents or using high cooling rates during solidification, or through large deformation, recrystallization, or phase transformation methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何提高晶粒细化程度，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释如何提高晶粒细化程度，涉及多种方法（如添加异质形核剂、高冷却速率、大变形、再结晶和相变等），需要综合理解和应用多个材料科学概念。虽然不涉及复杂计算或深度机理分析，但需要将不同知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多种提高晶粒细化程度的方法，包括添加异质形核剂、高冷却速率、大变形、再结晶和相变等。虽然选项提供了明确的答案，但需要考生具备一定的材料科学知识，能够理解并关联这些不同的方法。因此，在选择题型中属于中等难度。" + }, + { + "idx": 328, + "question": "What are the main mechanisms of metal plastic deformation at room temperature?", + "answer": "The main deformation mechanisms are slip and twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属在室温下的主要塑性变形机制，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查金属塑性变形的基本机制（滑移和孪生）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆金属塑性变形的基本机制（滑移和孪生），属于最基础的定义性知识。题目不涉及概念解释或复杂体系阐述，只需识别正确选项即可，因此属于最低难度等级。" + }, + { + "idx": 329, + "question": "Under the same degree of supercooling, compare the critical radius, critical nucleation work, and critical nucleus volume between homogeneous nucleation and heterogeneous nucleation. Which is larger?", + "answer": "The critical radius is the same; the critical nucleation work is higher for homogeneous nucleation; the critical nucleus volume is also larger for homogeneous nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较均相成核和非均相成核的临界半径、临界成核功和临界核体积，并说明哪个更大。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较均相成核和非均相成核的临界半径、临界成核功和临界核体积，需要理解成核理论的基本概念，并能够应用这些概念进行综合分析。虽然不涉及复杂的计算，但需要对不同成核方式的特点有较深的理解，并进行对比分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求比较均匀成核和非均匀成核在相同过冷度下的临界半径、临界成核功和临界核体积，并判断哪个更大。这需要深入理解成核理论，能够综合分析多个参数之间的关系，并进行多步比较和判断。虽然题目提供了正确选项，但解题过程涉及多个概念的关联和综合分析，属于多角度分析论述的难度等级。" + }, + { + "idx": 330, + "question": "Why is the liquid/solid interface front of an alloy more prone to undercooling during solidification compared to that of a pure metal?", + "answer": "The interface front of an alloy exhibits constitutional undercooling, where solute enrichment at the front raises the local melting point, making undercooling more likely to occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金在凝固过程中比纯金属更容易发生过冷的原因，答案需要文字解释和论述，涉及材料科学中的概念和原理，属于简答题类型。 | 知识层次: 题目需要解释合金凝固过程中液/固界面前沿更容易发生过冷的原因，涉及溶质富集和局部熔点升高的机理分析，属于综合运用和推理分析的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 331, + "question": "What is the main difference between slip and twinning?", + "answer": "The shear displacement produced by slip is an integer multiple of the atomic spacing, while that produced by twinning is a fraction of the atomic spacing; this leads to a series of other differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释slip和twinning的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对滑移和孪生这两种塑性变形机制的基本概念的理解和记忆，主要涉及定义和基本原理的对比，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分两种变形机制（滑移和孪生）的关键差异，即剪切位移与原子间距的关系。这超出了简单的定义记忆，要求考生能够解释和描述概念之间的区别。不过，题目并未涉及复杂的多概念体系分析或深入的应用，因此属于等级2难度。" + }, + { + "idx": 332, + "question": "What are the morphological differences between typical metals (such as iron) and typical non-metals (such as silicon, graphite) when grown individually in the liquid phase?", + "answer": "Because they are rough interface (iron) and smooth interface (silicon, etc.) respectively, the former forms uniform equiaxed crystals or dendrites, while the latter forms regular polygons with angular shapes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属和非金属在液相生长时的形态差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属和非金属在液相生长时的形态差异，涉及界面粗糙度与晶体形态的关联分析，需要理解并应用材料科学中的界面理论和晶体生长原理，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解金属（如铁）和非金属（如硅、石墨）在液相生长时的形态差异，这涉及多个材料科学的核心概念。其次，正确选项不仅需要考生识别粗糙界面和平滑界面的区别，还需要进一步关联这些界面特性与晶体形态（如等轴晶、枝晶、规则多边形）之间的关系。这种多步骤的概念关联和综合分析能力在选择题中属于较高要求。此外，题目还隐含了对材料生长机制的深入理解，进一步提升了难度。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 333, + "question": "Give the basic conditions (driving force) for metal recrystallization.", + "answer": "There must be a certain amount of deformation stored energy and a certain temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出金属再结晶的基本条件（驱动力），答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查金属再结晶的基本条件，属于基本原理的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆金属再结晶的基本条件（变形储存能量和一定温度），属于基础概念记忆层次，无需复杂分析或推理，因此属于最低难度等级。" + }, + { + "idx": 334, + "question": "What is the main difference between recrystallization and crystallization?", + "answer": "Recrystallization is only a microstructural change without structural transformation, driven by deformation stored energy; crystallization is the process of forming crystals from amorphous liquid, gas, or solid states.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的主要区别，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对recrystallization和crystallization这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题中属于中等难度，题目要求区分两个相关但不同的概念（再结晶和结晶），需要理解各自的基本定义和驱动机制。虽然不涉及复杂的概念体系阐述，但需要准确记忆和比较两个过程的本质区别，属于概念解释和描述的层次。" + }, + { + "idx": 335, + "question": "What are the upper and lower yield point effects (in pure iron or low-carbon steel)? What are the reasons?", + "answer": "Significant work hardening occurs during deformation at low temperatures (or high strain rates); a balance between hardening and softening (dynamic recovery) appears during deformation at medium temperatures (or medium strain rates); a distinct softening stage (dynamic recrystallization) occurs during deformation at high temperatures (or low strain rates).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释上下屈服点效应及其原因，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释上下屈服点效应的原因，涉及材料科学中的塑性变形机制、动态回复和动态再结晶等复杂概念，需要综合运用材料科学知识进行推理分析，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对纯铁或低碳钢的上下屈服点效应有深入理解，并能综合运用材料科学知识分析不同温度（或应变速率）条件下的变形机理（包括加工硬化、动态回复和动态再结晶）。这需要考生具备复杂现象全面分析的能力，能够整合多个知识点并进行机理深度解释。选择题型中仅给出正确选项的情况下，考生仍需通过推理分析来判断各选项描述的准确性，解题步骤和思维复杂度显著高于常规选择题。" + }, + { + "idx": 336, + "question": "What is the main difference between recrystallization and solid-state phase transformation?", + "answer": "Recrystallization is only a microstructural change without structural change, and the driving force is deformation stored energy; solid-state phase transformation is a structural change between solid/solid phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两个概念之间的主要区别，答案以文字形式详细说明了两者的不同点，没有涉及选择、判断或计算。 | 知识层次: 题目考查对再结晶和固态相变这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个基础概念（再结晶和固态相变），但正确选项要求考生能够区分两者的关键差异（微观结构变化vs结构变化，驱动力来源）。这需要考生不仅记住定义，还要理解概念之间的对比关系，属于概念解释和描述层次的认知要求。但题目并未涉及复杂机制或多步骤分析，因此不属于最高难度等级。" + }, + { + "idx": 337, + "question": "What are the main characteristics of allotriomorphic transformation?", + "answer": "Allotriomorphic transformation is primarily a phase change that occurs in pure components in the solid state, with no compositional changes, controlled by short-range diffusion processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释allotriomorphic transformation的主要特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对allotriomorphic transformation这一基本概念的定义和主要特征的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆（定义、分类、基本原理等），但需要学生对\"allotriomorphic transformation\"这一专业术语有准确的理解，并能区分其与其它相变类型的特征差异。题目正确选项包含了多个关键特征描述（纯组分、固态相变、无成分变化、短程扩散控制），要求学生对这些概念有较全面的掌握，而不仅仅是简单记忆定义。" + }, + { + "idx": 338, + "question": "What is the main difference between crystallization and solid-state phase transformation?", + "answer": "Crystallization is the process of forming crystals from amorphous liquid, gas, or solid non-crystalline states; solid-state phase transformation is the structural change between solid/solid phases. The driving forces for both processes are the chemical free energy difference.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对结晶和固态相变这两个基本概念的定义和区别的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等难度，题目要求考生理解并区分两个相关但不同的概念（结晶和固态相变），并正确识别它们的定义和驱动力的共同点。虽然涉及基础概念记忆，但需要一定的概念解释和描述能力，而不仅仅是简单的定义复述。" + }, + { + "idx": 339, + "question": "What are the main characteristics of martensitic transformation?", + "answer": "Martensitic transformation is a diffusionless, shear-type phase transformation that occurs in both pure metals and alloys, and is controlled by interface processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体转变的主要特征，答案提供了文字解释和论述，符合简答题的特点 | 知识层次: 题目考查马氏体相变的基本特征，属于定义和基本原理的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆，但需要考生理解并整合多个关键特征（扩散less、剪切型、界面过程控制等），比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 340, + "question": "What are the main characteristics of precipitation transformation?", + "answer": "Precipitation occurs in alloys, involves compositional changes, and is primarily controlled by long-range diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释沉淀转变的主要特征，答案提供了详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对沉淀相变主要特征的基础概念记忆和理解，涉及合金中的沉淀现象、成分变化和扩散控制等基本原理，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项需要考生理解并描述沉淀转变的三个主要特征（发生在合金中、涉及成分变化、主要受长程扩散控制），这比单纯记忆定义（等级1）要求更高。然而，题目并未要求考生阐述复杂概念体系或进行多概念比较分析（等级3），因此属于概念解释和描述层次的难度等级2。" + }, + { + "idx": 341, + "question": "Briefly describe the effect of deformation amount on metal properties under uniaxial compression?", + "answer": "As the deformation amount increases, strength and hardness improve, while plasticity decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述变形量对金属性能的影响，需要用文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目考查金属在单轴压缩下变形量对性能影响的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述变形量对金属性能的影响，包括强度、硬度和塑性的变化趋势。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 342, + "question": "Briefly describe the effect of deformation amount on the microstructure of metals under uniaxial compression (including changes in grain shape and dislocation substructure)?", + "answer": "From a lateral observation, as the deformation amount increases, the grains change from equiaxed to elongated, and the dislocations within the grains increase, forming dislocation tangles, subgrain boundaries, or new high-angle grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形量对金属微观结构的影响，需要文字解释和论述，答案也是以文字形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述变形量对金属微观结构的影响，涉及对晶粒形状和位错亚结构变化的综合分析。虽然不涉及复杂计算，但需要理解变形过程中的微观结构演变，并将多个概念（晶粒形状变化、位错密度增加、亚晶界形成等）关联起来进行解释。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在选择题中属于中等难度，需要理解金属在单轴压缩下微观结构的变化，包括晶粒形状和位错亚结构的变化。题目要求考生能够综合分析变形量增加对晶粒形态和位错结构的影响，涉及多个概念的关联和综合应用。虽然题目提供了正确选项，但考生仍需具备一定的知识深度和综合分析能力才能准确理解并选择正确答案。" + }, + { + "idx": 343, + "question": "Briefly describe the effect of deformation temperature on metal properties under uniaxial compression.", + "answer": "As the deformation temperature increases, the rates of both strength increase and plasticity decrease slow down.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形温度对金属性能的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释变形温度对金属性能的影响，需要理解温度与金属力学性能（强度和塑性）之间的关系，并进行一定的综合分析。这涉及到多个概念的关联和中等程度的分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解金属变形温度与强度、塑性之间的关系，并能综合分析温度变化对这两种性能变化速率的影响。题目要求考生将多个概念关联起来，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 344, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? How many atoms are there in an FCC unit cell?", + "answer": "The number of atoms in an FCC unit cell is 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体结构（晶胞）的常见参数，并需要文字论述FCC晶胞中的原子数量，答案形式为简短的文字解释而非计算或选择。 | 知识层次: 题目考查对晶体结构基本参数和面心立方晶胞原子数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对FCC晶胞中原子数目的基础记忆，属于最基本的概念性知识，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 345, + "question": "Briefly describe the effect of deformation temperature on metal microstructure (including changes in grain shape and dislocation substructure) under uniaxial compression.", + "answer": "As the deformation temperature increases, the rate at which grains elongate slows down due to enhanced thermal activation, subgrain boundaries form more rapidly, subgrain size tends to stabilize, and even dynamic recrystallization structures may appear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述变形温度对金属微观结构的影响，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求分析变形温度对金属微观结构的影响，涉及多个方面的变化（晶粒形状、位错亚结构等），需要综合运用材料科学知识进行机理解释和推理分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 346, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the close-packed plane of an FCC unit cell?", + "answer": "Close-packed plane {111}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述晶体结构的常见参数和FCC晶胞的密排面，需要文字解释和论述，答案也是以文字形式给出。 | 知识层次: 题目考查晶体结构的基本参数和密排面的记忆，属于基础概念的记忆和理解层面，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆并识别面心立方晶胞的密排面{111}，属于基础概念记忆层次，无需复杂分析或推理步骤。" + }, + { + "idx": 348, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the coordination number of an FCC unit cell?", + "answer": "Coordination number 12.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述晶体结构的常见参数，并给出FCC晶胞的配位数，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体结构的基本参数和面心立方晶胞的配位数，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅要求记忆并识别面心立方晶胞的配位数这一基础定义，无需解释或分析多个概念。正确选项直接给出了答案，解题步骤简单，属于最基础的概念记忆题。" + }, + { + "idx": 349, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What are the interstitial positions and their number in an FCC unit cell?", + "answer": "Interstitial positions (octahedral interstitial at the body center and equivalent positions) and number 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体结构（晶胞）的常见参数以及面心立方晶胞中的间隙位置和数量，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体结构的基本参数和间隙位置的定义及数量，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体结构的基本概念（如间隙位置和数量），但需要考生不仅记忆FCC晶胞的基本参数，还要理解并识别其中的间隙位置（如八面体间隙）及其数量。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。因此，该题目属于概念解释和描述的难度等级2。" + }, + { + "idx": 350, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the stacking sequence of an FCC unit cell?", + "answer": "The stacking sequence is ABCABC.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求文字解释和论述晶体结构（晶胞）的常见参数以及面心立方晶胞的堆垛顺序，答案以文字形式给出，没有涉及计算或选择。 | 知识层次: 题目考查晶体结构的基本参数和面心立方(FCC)晶体的堆垛顺序，这些都是材料科学中基础概念的记忆和理解，不涉及复杂的计算或分析。 | 难度: 在选择题型中，该题目仅要求记忆并选择FCC晶体的堆垛顺序（ABCABC），属于基础概念记忆层次。题目不涉及复杂的概念解释或分析，仅需直接回忆定义性知识，因此难度等级为1。" + }, + { + "idx": 351, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the packing density of an FCC unit cell?", + "answer": "Packing density 0.74.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述晶体结构的常见参数，并计算FCC晶胞的堆积密度，需要文字解释和数值计算相结合的回答方式。 | 知识层次: 题目要求描述晶体结构（晶胞）的常见参数，并计算FCC晶胞的堆积密度。虽然需要理解晶体结构的基本概念，但主要涉及基本公式的应用和简单计算，属于直接套用和简单应用层次。 | 难度: 在选择题中属于简单应用难度，题目直接考察对FCC晶胞堆积密度的记忆和基本公式应用，无需复杂计算或分析，仅需正确识别和选择给定的正确选项。" + }, + { + "idx": 352, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the atomic radius of an FCC unit cell?", + "answer": "The atomic radius is √2a/4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释常见的晶体结构参数，并给出FCC晶胞的原子半径，需要文字解释和论述，答案形式为简短的文字描述。 | 知识层次: 题目要求描述晶体结构（晶胞）的常见参数，并计算面心立方晶胞的原子半径。这需要应用基本的晶体学知识（如晶胞参数的定义）和简单的数学计算（如原子半径与晶格常数的关系公式）。虽然需要一定的理解，但主要是直接套用已知公式进行计算，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（FCC原子半径公式）进行计算。题目提供了明确的参数（a）和公式结构，解题步骤简单直接，无需复杂分析或概念比较。在选择题型内，此类直接应用公式的题目通常属于较低难度等级。" + }, + { + "idx": 353, + "question": "What is the main structural difference between (metal-based) solid solutions and intermediate phases?", + "answer": "Solid solutions retain the crystal structure of the pure metal, while the structure of intermediate phases is generally different from that of both constituent elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属基固溶体和中间相的主要结构差异，答案需要文字解释和论述，没有提供选项或要求判断对错或进行数值计算。 | 知识层次: 题目考查对固溶体和中间相的基本概念和结构差异的记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分两种不同的结构类型（固溶体和中间相），并记住它们的关键区别特征。这比单纯记忆单一概念的定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 354, + "question": "What are the main differences in properties between (metal-based) solid solutions and intermediate phases?", + "answer": "Solid solutions have good plasticity and toughness, while intermediate phases exhibit high strength but poorer toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属基固溶体和中间相在性能上的主要差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对金属基固溶体和中间相性质差异的基本概念记忆和理解，属于基础知识的直接对比和描述，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生理解并区分两种材料（固溶体和中间相）的基本性能差异。虽然涉及两个概念，但只需记忆和比较它们的关键特性（塑性与强度），不需要复杂的分析或推导过程。这属于概念解释和描述的难度层级。" + }, + { + "idx": 355, + "question": "What is the main difference in bonding nature between (metal-based) solid solutions and intermediate phases?", + "answer": "The atoms in solid solutions are primarily bonded by metallic bonds, while intermediate phases are mainly bonded by covalent and ionic bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述金属基固溶体和中间相在键合性质上的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对固体溶液和中间相之间键合性质差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（金属基固溶体和中间相的键合性质差异），但需要学生对金属键、共价键和离子键等基本键合类型有清晰的理解和区分能力。题目要求比较两种不同材料体系的键合特征，这比单纯记忆单个概念的定义（等级1）要复杂一些，但尚未达到需要阐述复杂概念体系（等级3）的程度。正确选项直接给出了明确的对比关系，减少了分析步骤的复杂性。" + }, + { + "idx": 356, + "question": "How does the dissolution of another element in a pure metal (assuming no new phase is formed) cause changes in properties due to microstructural changes?", + "answer": "The strength increases due to solid solution strengthening, while the plasticity decreases; the electrical resistance generally increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金元素溶解对纯金属性能的影响机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化对金属性能的影响，涉及多个概念（固溶强化、强度、塑性、电阻）的关联和综合分析，需要理解微观结构变化与宏观性能之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及固溶强化、塑性变化和电阻变化等多个概念的综合应用，要求考生能够关联不同知识点并分析其影响。虽然不需要复杂的计算，但需要对材料科学中的基本原理有较深的理解和应用能力。" + }, + { + "idx": 357, + "question": "After dissolving another element into a pure metal (assuming no new phase is formed), what microstructural changes will occur?", + "answer": "It causes lattice distortion, and the lattice constant will change; local segregation or ordering may occur, and even a superlattice can form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释溶解其他元素到纯金属中会引起的微观结构变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析溶解其他元素到纯金属中引起的微观结构变化，涉及晶格畸变、晶格常数变化、局部偏聚或有序化以及超晶格形成等复杂机理的解释和推理分析。这需要综合运用材料科学的知识，理解固溶体的形成机制和微观结构变化的原因，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 358, + "question": "What are the microscopic mechanisms of diffusion?", + "answer": "The main microscopic mechanisms of diffusion are the interstitial mechanism and the substitutional mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的微观机制，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查扩散的微观机制的基本概念记忆和理解，涉及两种主要机制的分类和基本原理，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别扩散的两种主要微观机制（间隙机制和置换机制），属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，解题步骤简单直接，只需选择正确的定义性描述即可。" + }, + { + "idx": 359, + "question": "How does the interaction between point defects and dislocations affect mechanical properties?", + "answer": "At this point, the dislocations are pinned and difficult to move, increasing strength and producing upper and lower yield point effects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释点缺陷与位错相互作用对力学性能的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及点缺陷与位错的相互作用对力学性能的影响，需要深入理解缺陷与位错的相互作用机制，并能够分析这种相互作用如何导致材料强度的变化和屈服点效应的产生。这需要综合运用材料科学中的缺陷理论和力学性能知识，进行机理层面的解释和推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解点缺陷与位错相互作用的复杂机理，并能将其对力学性能的影响（如强度增加和上下屈服点效应）进行准确关联。正确选项涉及多步推理：1) 理解位错被钉扎的物理过程 2) 分析位错运动受阻的后果 3) 解释宏观力学性能变化的表现形式。这种需要综合多个高阶概念并建立因果关系的题目，在选择题型中属于最复杂的考查类型，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 360, + "question": "Under normal circumstances, which mechanism diffuses faster?", + "answer": "Diffusion via the interstitial mechanism is faster, as interstitial atoms are smaller in size and do not require the presence of vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释哪种扩散机制更快，并需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查扩散机制的基础概念记忆和理解，仅需比较间隙扩散和空位扩散的基本原理和特点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（扩散机制），但需要考生理解并比较两种扩散机制（间隙扩散和空位扩散）的特点，并基于原子尺寸和空位需求进行判断。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 361, + "question": "Write a specific slip system for a face-centered cubic metal", + "answer": "Such as (111)[110]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出一个具体的滑移系统，需要提供具体的晶面和晶向组合（如(111)[110]），属于需要具体回答的简答题类型。 | 知识层次: 题目考查对面心立方金属滑移系统的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目要求写出一个具体的滑移系，这只需要记忆面心立方金属的典型滑移系组合（如(111)[110]）即可作答，不需要进行概念解释或复杂分析。" + }, + { + "idx": 362, + "question": "For an alloy that has solidified with microscopic non-equilibrium segregation, what measures can be taken to accelerate diffusion and homogenize the alloy?", + "answer": "Heating and annealing, deformation followed by annealing, or increasing vacancy concentration through high-energy particle irradiation to enhance diffusion (though this is uneconomical and impractical).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述具体的措施来加速扩散和均匀化合金，答案提供了多种可能的解决方案并进行了简要说明，符合简答题的特征。 | 知识层次: 题目要求考生理解非平衡偏析的概念，并应用扩散和均匀化的基本原理来提出解决方案。需要综合考虑加热退火、变形退火和高能粒子辐照等多种方法，并分析其优缺点。这涉及多步骤的思考和对不同处理方法的比较，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解非平衡偏析的基本概念，还需要综合掌握多种材料处理方法的原理（加热退火、变形后退火、高能粒子辐照）及其对扩散过程的影响机制。正确选项涉及多个步骤的工艺组合（如变形+退火）以及非常规方法（辐照）的经济性考量，需要考生进行多角度分析和概念关联。相比单纯记忆性选择题，本题需要更深入的材料科学知识储备和工艺原理的综合应用能力，因此属于选择题型中的较高难度等级。" + }, + { + "idx": 363, + "question": "Describe which solution of the second law of diffusion is applied in this process?", + "answer": "The sinusoidal solution can describe the concentration distribution during diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述哪种扩散第二定律的解适用于该过程，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述扩散第二定律的特定解在某一过程中的应用，需要理解扩散定律的基本原理，并能够将正弦解与具体的浓度分布情况关联起来。这涉及到多步的概念关联和综合分析，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题中属于中等难度，需要理解扩散第二定律的不同解及其应用场景，并能将正弦解与扩散过程中的浓度分布联系起来进行分析。虽然不涉及多步计算，但需要对概念进行关联和综合分析。" + }, + { + "idx": 364, + "question": "Why do point defects (such as interstitial atoms or substitutional atoms) and line defects (such as dislocations) interact?", + "answer": "Point defects cause distortion, increasing local energy and creating an elastic strain field nearby; dislocations also exhibit this behavior, but the stress field state around dislocations varies at different positions, with some being compressive stress and others tensile stress. Point defects will aggregate onto dislocations to reduce strain energy, thereby lowering the system's energy. Dislocations that adsorb solute atoms represent a stable configuration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释点缺陷和线缺陷之间的相互作用机制，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释点缺陷和线缺陷之间的相互作用机制，涉及弹性应变场、应力状态变化以及系统能量降低的原理。这需要综合运用多个概念（点缺陷、位错、应变场、能量状态）进行推理分析，并解释其背后的物理机制，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解点缺陷和线缺陷的相互作用机理，包括弹性应变场、应力状态变化以及系统能量降低的复杂过程。正确选项不仅需要综合运用多个核心概念（如点缺陷的畸变效应、位错的应力场特性），还需要进行机理层面的推理分析（如缺陷聚集降低应变能的原理）。这种深度解释和复杂现象分析的要求远超一般选择题的知识点记忆或简单应用，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 365, + "question": "What are the types of deformation textures?", + "answer": "Textures are divided into sheet textures and fiber textures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释变形织构的类型，答案提供了文字解释和分类，符合简答题的特征 | 知识层次: 题目考查对变形织构类型的基本分类记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别变形织构的基本分类（片状织构和纤维织构），属于最基础的定义简答类型。不需要进行概念解释或复杂体系阐述，解题步骤简单直接。" + }, + { + "idx": 366, + "question": "During the deformation of polycrystals, under a certain amount of deformation, why do some grains exhibit single slip while others exhibit multiple slips?", + "answer": "Hard-oriented stress axes induce multiple slips, such as <111>, <100>, <110> directions, while soft-oriented stress axes correspond to single slip, such as the <123> direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在变形过程中某些晶粒表现出单滑移而其他晶粒表现出多滑移，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释多晶变形过程中不同晶粒表现出单滑移和多滑移的原因，涉及晶体取向、应力轴方向与滑移系激活的复杂关系。需要综合运用晶体塑性变形理论、Schmid因子分析以及不同晶向的滑移系激活条件，属于机理分析和推理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 367, + "question": "What is deformation texture?", + "answer": "The deformation process causes the grains to rotate, and finally certain crystallographic directions within each grain tend to become parallel. This preferred orientation due to deformation is called deformation texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"deformation texture\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即变形织构的定义和形成原因，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"deformation texture\"的定义和形成机制，需要掌握材料科学中关于晶体取向的基本概念。虽然涉及多个知识点（晶粒旋转、晶体学方向、择优取向），但整体仍属于单一概念的解释范畴，不需要进行复杂的概念体系分析或比较。在选择题型中，这属于中等偏基础的难度，比简单定义记忆稍复杂，但不及需要综合分析的多概念题目难度。" + }, + { + "idx": 368, + "question": "During the deformation of polycrystals, under a certain amount of deformation, why do some grains exhibit large slip amounts while others show small slip amounts?", + "answer": "When the orientation factor of a slip system in a grain relative to the force axis is large, slip initiates first; when the orientation factor is small, slip initiates later, resulting in different deformation amounts among grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶体变形过程中不同晶粒滑移量差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及多晶变形过程中不同晶粒滑移量的差异，需要理解取向因子对滑移系统启动的影响机制，并进行综合分析。这需要综合运用晶体学、塑性变形原理等知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶体变形的基本概念，还需要综合运用取向因子、滑移系统等专业知识，进行复杂的推理分析。正确选项涉及多步骤的机理解释（取向因子大小与滑移启动顺序的关系），并需要将微观机制与宏观变形现象联系起来。这种深度分析和综合推理能力的要求明显高于普通选择题，属于复杂现象全面分析的范畴。" + }, + { + "idx": 369, + "question": "How to represent the fiber texture?", + "answer": "The fiber texture is represented as .", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何表示纤维织构，答案提供了具体的表示方法，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对纤维织构表示方法的基本概念记忆，仅需回答标准表示符号，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆纤维织构的基本表示方法（），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或分析步骤，因此属于最简单的难度等级。" + }, + { + "idx": 370, + "question": "Why is recrystallization annealing often required in actual production?", + "answer": "Continuous plastic deformation of the material causes severe work hardening, making further processing difficult; at the same time, the deformed structure is unstable, with poor toughness and plasticity, resulting in unsatisfactory service performance; moreover, the formation of strong deformation texture is also undesirable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在实际生产中经常需要再结晶退火，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释再结晶退火在实际生产中的必要性，涉及对塑性变形、加工硬化、组织不稳定性和变形织构等概念的综合理解，需要将多个知识点关联起来进行分析和论述，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解再结晶退火的基本概念，还需要综合分析材料塑性变形、加工硬化、组织结构稳定性、力学性能变化以及变形织构形成等多个相互关联的因素。正确选项整合了材料科学中多个重要知识点，需要考生具备将理论知识与实际生产问题相结合的能力，并进行多角度分析论述。这种综合分析能力在选择题型中属于较高层次的要求。" + }, + { + "idx": 371, + "question": "Which locations may be preferred nucleation sites?", + "answer": "Preferred nucleation sites include: original grain boundaries, newly formed high-angle grain boundaries during deformation or those gradually formed through subgrain growth, and the vicinity of second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释哪些位置可能是优选的成核位点，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对成核位点的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和描述多个具体的成核位置（如原始晶界、变形过程中新形成的高角度晶界、亚晶生长逐渐形成的晶界以及第二相粒子附近）。这些知识点虽然属于记忆性内容，但需要考生对成核位置有较为全面的理解和分类能力，而不仅仅是简单的定义记忆。因此，该题目在选择题型中属于等级2难度。" + }, + { + "idx": 372, + "question": "Schottky defect", + "answer": "A vacancy defect formed by displaced atoms migrating to the outer surface under thermal equilibrium conditions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对Schottky defect进行文字解释和论述，答案提供了详细的定义和形成条件，符合简答题的特征 | 知识层次: 题目考查Schottky缺陷的基本定义和形成条件，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对Schottky缺陷基本定义的记忆，属于最基础的概念性知识。正确选项直接描述了缺陷的形成机制，无需复杂分析或概念间的关联理解，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 373, + "question": "What are the characteristics or features of recrystallization nucleation sites?", + "answer": "Locally high dislocation density/deformation stored energy, or significant differences in dislocation density; near high-mobility high-angle grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释再结晶成核位点的特征，答案提供了详细的文字描述和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对再结晶成核位点特征的基础概念记忆和理解，属于定义和基本原理的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生理解并区分再结晶形核位点的具体特征（如局部高位错密度/变形储存能、位错密度显著差异、靠近高迁移率大角度晶界等），而不仅仅是简单的定义复述。这要求考生对相关概念有一定的理解和记忆深度，但不需要进行复杂的分析或推理。" + }, + { + "idx": 374, + "question": "Briefly describe the laws of changes in material microstructure and properties during recovery and recrystallization annealing", + "answer": "As the annealing temperature increases or the annealing time prolongs, dislocation tangles in the deformed structure evolve into subgrains, which merge and grow; recrystallization nucleation and growth occur in areas of uneven deformation, with equiaxed grains replacing elongated deformed grains; followed by normal grain growth; in terms of properties, strength and hardness decrease, electrical resistance decreases; plasticity and toughness improve, and density increases. These processes are more pronounced during the recrystallization stage than during the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述材料在回复和再结晶退火过程中微观结构和性能变化的规律，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求描述材料在回复和再结晶退火过程中微观结构和性能变化的规律，这需要综合运用多个概念（如位错、亚晶、再结晶形核与长大等）进行关联分析，并解释这些变化对材料性能的影响。这涉及到对材料科学中复杂机理的理解和解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用材料科学知识，深入理解回复和再结晶退火过程中微观结构和性能变化的复杂机理。正确选项不仅需要识别多个物理冶金现象（如位错重组、亚晶合并、再结晶形核与长大），还需准确关联微观结构演变与宏观性能变化（强度、电阻率、塑性等）。这种题目要求考生具备高阶分析能力和机理解释能力，远超简单记忆或基础理解层面，属于复杂现象全面分析的典型代表。" + }, + { + "idx": 375, + "question": "Up-hill diffusion", + "answer": "Driven by the chemical potential gradient, solute diffuses from areas of low concentration to areas of high concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"Up-hill diffusion\"现象进行文字解释和论述，答案是一个完整的句子解释该现象，符合简答题的特征。 | 知识层次: 题目涉及对化学势梯度驱动下溶质从低浓度向高浓度扩散的机理解释，需要综合运用扩散理论和热力学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 376, + "question": "Center of gravity rule", + "answer": "For an alloy in three-phase equilibrium, its composition point must lie at the centroid position of the conjugate triangle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目陈述了一个材料科学中的规则（重心规则），答案是对该规则的文字解释和描述，不需要计算或选择，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对\"重心规则\"这一基本概念的记忆和理解，属于相图分析中的基本原理，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（重心规则的定义），但需要考生理解并准确描述三相平衡合金的组成点必须位于共轭三角形的重心位置这一具体规则。这比单纯记忆基本定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 377, + "question": "同质异构体", + "answer": "Chemical compositions are the same but form different crystal structures due to different thermodynamic conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"同质异构体\"进行文字解释和论述，答案提供了概念的定义和形成原因，符合简答题的特征 | 知识层次: 题目考查同质异构体的基本定义和形成原因，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生理解并区分\"同质异构体\"的定义特征（相同化学成分但不同晶体结构）及其形成原因（不同热力学条件）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 378, + "question": "Habit plane", + "answer": "During solid-state phase transformation, the new phase often begins to form on certain crystallographic planes of the parent phase, which are called habit planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Habit plane\"进行文字解释和论述，答案提供了详细的定义和背景说明，符合简答题的特征。 | 知识层次: 题目考查对\"habit plane\"这一基本概念的定义和简单解释，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即“habit plane”的定义。正确选项直接给出了定义，没有涉及复杂的概念体系或需要解释和描述的内容。因此，属于基本定义简答的难度等级。" + }, + { + "idx": 379, + "question": "In the diamond structure, carbon is connected by (5) bonds, and the coordination number is (6).", + "answer": "(5) covalent; (6) 4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定术语（covalent和4）来补全句子，属于需要简短文字回答的简答题类型，而非选择、判断或计算题。 | 知识层次: 题目考查金刚石结构中碳原子之间的键合类型和配位数的基本概念记忆，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对金刚石结构中碳原子键合类型和配位数的记忆性知识，无需复杂的概念解释或分析。正确选项直接对应基础概念记忆，解题步骤简单明了。" + }, + { + "idx": 380, + "question": "There are two types of the most closely packed crystal structures: one is (1), with (2) atoms in each unit cell; the other is (3), with (4) atoms in each unit cell.", + "answer": "(1) ABC; (2) 4; (3) AB; (4) 2(or 6)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定的术语和数值，需要学生对晶体结构类型和单位晶胞中的原子数量有准确的理解和记忆，属于简答题类型。 | 知识层次: 题目考查对最紧密堆积晶体结构类型及其单位晶胞中原子数目的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求记忆两种最紧密堆积晶体结构的名称及其每个晶胞中的原子数量，这是材料科学中最基础的概念之一。正确选项直接对应记忆性知识，无需复杂分析或推理步骤。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 381, + "question": "The driving force for solid-state phase transformation is (10), while the resistances are (11) and (12).", + "answer": "(10) free energy difference between new and old phases; (11) interface energy; (12) strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的术语或概念，而不是从选项中选择或判断对错，也不需要计算。答案需要简要的文字解释，符合简答题的特征。 | 知识层次: 题目考查对固态相变驱动力和阻力的基本概念记忆，包括自由能差、界面能和应变能等基础概念的理解和识别 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察学生对固态相变驱动力和阻力的基础概念记忆，只需识别并匹配正确的术语（自由能差、界面能、应变能）即可，无需进行概念解释或复杂分析。" + }, + { + "idx": 382, + "question": "Coincidence site lattice", + "answer": "Consider two identical and coinciding lattices $L_{1}$ and $L_{2}$. After rotating or translating $L_{2}$ relative to $L_{1}$, the lattices formed by the coinciding positions of the two lattices constitute a new periodic superlattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Coincidence site lattice\"进行文字解释和论述，答案提供了概念性的描述和定义，属于简答题类型 | 知识层次: 题目考查对Coincidence site lattice（重合位置点阵）这一基本概念的定义和基本原理的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要理解并描述两个晶格重合后形成超晶格的过程，这比简单的定义记忆要复杂一些。题目要求考生能够解释和描述这一现象，而不仅仅是回忆定义，因此属于等级2。" + }, + { + "idx": 383, + "question": "The positional relationship between the screw dislocation line and the Burgers vector is (7), the positional relationship between the edge dislocation line and the Burgers vector is (8), and the dislocation whose dislocation line intersects obliquely with the Burgers vector is (9).", + "answer": "(7) parallel; (8) perpendicular; (9) mixed dislocation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定的术语来描述位错线与Burgers矢量之间的位置关系，答案需要文字解释而非选择或判断。虽然形式上类似于填空题，但更符合简答题的特征，因为需要理解概念并准确描述。 | 知识层次: 题目考查对位错类型与伯格斯矢量之间位置关系的基本概念记忆和理解，属于材料科学中晶体缺陷的基础知识范畴。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察对位错类型与伯格斯矢量位置关系的基础概念记忆，只需简单回忆平行、垂直和混合位错的定义即可作答，无需复杂分析或推理过程。正确选项明确对应基础概念，属于最基础的知识点考察。" + }, + { + "idx": 384, + "question": "The higher the diffusion temperature, the more conducive it is to diffusion.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查扩散温度与扩散速率之间关系的基本原理记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅涉及扩散温度与扩散速率关系的简单记忆性知识，无需理解复杂概念或进行多步骤分析。正确选项直接对应基础概念记忆层次，符合等级1的难度标准。" + }, + { + "idx": 385, + "question": "In the composition triangle of the A-B-C ternary system, for all alloys whose composition points lie on a line parallel to the AB side, the content of the (13) component is a fixed value.", + "answer": "(13) C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的成分名称（C），属于需要简短文字回答的题目类型，而不是从多个选项中选择或判断对错 | 知识层次: 题目考查三元相图的基本概念和组成三角形的理解，属于对基本原理的记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆题，仅需考生记住三元相图中平行于某边的直线代表第三组元含量固定这一基本原理。题目直接考查定义性知识，无需分析推理，属于最简单的记忆性题目。" + }, + { + "idx": 386, + "question": "From a diffusion perspective, the mobility of low-angle grain boundaries is lower compared to that of high-angle grain boundaries.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（低角度晶界的迁移率低于高角度晶界），并要求判断其正确性（√表示正确），这符合判断题的特征。 | 知识层次: 题目考查的是关于晶界扩散特性的基本概念记忆，即低角度晶界和高角度晶界在扩散过程中的迁移率差异。这属于对材料科学中晶界行为的基础知识的理解和记忆，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅涉及低角度晶界和高角度晶界迁移性的比较，属于基础概念记忆层次，无需复杂分析或推理。学生只需记住相关定义即可直接判断正误，因此难度最低。" + }, + { + "idx": 387, + "question": "The principle of zone refining is based on (16).", + "answer": "(16) Redistribution of solute during directional solidification of solid solution (fractional crystallization)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释区域精炼的原理，答案提供了详细的文字解释，符合简答题的特征 | 知识层次: 题目考查对区域精炼原理的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生准确理解\"区域精炼\"原理是基于\"固溶体定向凝固过程中溶质的再分配（分步结晶）\"这一特定概念。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。考生需要将原理名称与其具体机制正确对应，体现了对概念的理解深度。" + }, + { + "idx": 388, + "question": "When stretching a single crystal, the slip plane is most prone to slip when it turns to an angle of (14) with the external force axis.", + "answer": "(14) 45°", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的角度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。虽然答案是一个数值，但更侧重于对材料科学原理的理解和应用，属于简答题的范畴。 | 知识层次: 题目考查的是单晶拉伸时滑移面最容易滑动的角度这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的应用或分析。 | 难度: 在选择题型中，此题属于基础概念记忆题，仅需回忆单晶拉伸时滑移面最容易滑动的角度这一基本定义即可作答。题目直接给出了正确选项45°，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 389, + "question": "The decrease in volume free energy during the formation of a critical nucleus can only compensate for 1/3 of the newly added surface energy.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（The decrease in volume free energy during the formation of a critical nucleus can only compensate for 1/3 of the newly added surface energy），并要求判断其正确性（答案给出的是×，表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对临界核形成过程中体积自由能和表面能量关系的记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生理解临界晶核形成过程中体积自由能减少与表面能增加的关系。虽然涉及两个能量概念，但只需判断\"1/3补偿\"这一具体数值关系的正误，不需要进行复杂的概念比较或计算分析，属于选择题型中中等偏下的难度。" + }, + { + "idx": 390, + "question": "Both edge dislocations and screw dislocations have climb and glide motions.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Both edge dislocations and screw dislocations have climb and glide motions），要求判断其正误（答案给出×表示错误），符合判断题的特征 | 知识层次: 题目考查对位错类型及其运动方式的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对位错运动方式的基本理解，需要区分边缘位错和螺型位错的不同运动特性（边缘位错有攀移和滑移，而螺型位错只有滑移）。虽然涉及两个概念，但属于基础概念记忆层次，不需要复杂的分析步骤。" + }, + { + "idx": 391, + "question": "Both thermoplastic and thermosetting plastics can be reused.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Both thermoplastic and thermosetting plastics can be reused），并要求判断其正确性（答案给出×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对热塑性塑料和热固性塑料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆热塑性塑料和热固性塑料的基本特性即可作答。在选择题型中，这类直接考察定义记忆的题目属于最简单级别，无需复杂分析或推理过程。" + }, + { + "idx": 392, + "question": "In a binary system, the transformation that occurs at a certain temperature, L1 = L2 + α, is called (15) transformation.", + "answer": "(15) monotectic transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（monotectic transformation）来完成句子，而不是从多个选项中选择、判断对错或进行数值计算。这种形式更接近于简答题，需要学生对材料科学中的相变类型有准确的理解和记忆。 | 知识层次: 题目考查对二元系统中特定相变类型（monotectic transformation）的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆题，仅需考生回忆二元系统中特定温度下发生的相变类型名称（monotectic transformation）。题目直接给出定义式(L1 = L2 + α)，只需匹配术语，无需解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 393, + "question": "Common strengthening methods for metallic materials include (17), (18), (19), and (20).", + "answer": "(17) Solid solution strengthening; (18) Grain refinement strengthening; (19) Second phase strengthening; (20) Work hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的强化方法名称，需要文字回答而非选择或判断，也不涉及计算过程 | 知识层次: 题目考查对金属材料常见强化方法的基本概念记忆，属于基础概念和分类的范畴，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆类型，仅需要考生回忆并识别金属材料的常见强化方法。题目提供了明确的正确选项，考生只需匹配记忆中的知识点即可完成作答，无需进行复杂的概念解释或体系阐述。在选择题型中，这种直接考察定义和分类的记忆性题目属于最低难度等级。" + }, + { + "idx": 394, + "question": "The brittle phase is dispersed in granular form in the matrix of another phase, which is a microstructure state that is more beneficial to the strength and toughness of the material.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The brittle phase is dispersed...），并要求判断其正确性（答案：√），这是典型的判断题特征。 | 知识层次: 题目考查对材料微观结构状态及其对性能影响的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断给定的陈述是否正确。题目描述的是材料科学中关于微观结构对强度和韧性影响的基本概念，正确选项明确，无需复杂分析或推理。在选择题型中，此类题目属于最简单的难度等级，仅需对基本定义或分类有记忆即可正确作答。" + }, + { + "idx": 395, + "question": "Grain boundaries with a misorientation angle less than $2^{\\circ}$ between adjacent grains are called high-angle grain boundaries.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Grain boundaries with a misorientation angle less than $2^{\\circ}$ between adjacent grains are called high-angle grain boundaries），并要求判断其正误（答案给出的是×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对晶界分类的基本概念记忆，特别是低角度晶界和高角度晶界的定义区分，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于晶界分类的定义是否正确。题目陈述明确，只需识别\"小于2°的晶界称为小角度晶界\"这一基本概念即可判断正误，无需深入理解或分析。在选择题型中，这类直接考察定义记忆的题目属于最简单的难度等级。" + }, + { + "idx": 396, + "question": "If the arrangement of atoms in the parent phase of an alloy is ordered, then after martensitic transformation, the arrangement of atoms in the martensite becomes disordered.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（关于马氏体转变后原子排列有序性的描述），并要求判断该陈述的对错（答案用×表示错误）。这符合判断题的特征，即判断陈述的真伪。 | 知识层次: 题目考查对马氏体相变中原子排列有序性的基本概念记忆和理解，属于基础概念层面的判断题 | 难度: 该题目属于基础概念记忆层次，仅需判断马氏体相变后原子排列是否有序这一基本定义的正确性。在选择题型中属于最简单的正误判断题，不需要复杂分析或概念比较，完全基于对基础概念的准确记忆即可作答。" + }, + { + "idx": 397, + "question": "What is the driving force for grain boundary migration?", + "answer": "The driving forces for grain boundary migration are: the stored energy of deformation and the chemical potential difference across the grain boundary caused by grain boundary curvature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述晶界迁移的驱动力，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对晶界迁移驱动力的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求考生理解并记忆晶界迁移的驱动力，包括变形储存能和晶界曲率引起的化学势差。虽然涉及两个概念，但都属于基础概念记忆范畴，不需要复杂的分析或比较。因此，难度属于中等偏下，对应等级2。" + }, + { + "idx": 398, + "question": "What is spinodal decomposition?", + "answer": "Spinodal decomposition is a special form of solid solution, where a single solid solution decomposes into two solid solutions with the same structure as the parent phase but different compositions through a diffusion clustering mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"spinodal decomposition\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对spinodal decomposition这一基础概念的定义和基本特征的理解，属于材料科学中相变理论的基础知识记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生准确理解并描述spinodal decomposition的定义和机制，而不仅仅是简单的名词解释。正确选项包含了多个关键要素（如\"solid solution\"、\"same structure\"、\"different compositions\"、\"diffusion clustering mechanism\"），要求考生对这些概念有较全面的掌握。相比等级1的简单定义题，该题目需要更深入的概念理解和描述能力。" + }, + { + "idx": 399, + "question": "Are the geometric conditions for the following dislocation reaction satisfied? Among them: b1=a/2[110], b2=a/6[12¯1], b3=a/6[211]", + "answer": "Geometric conditions: after the reaction b2+b3=a/6[12¯1]+a/6[211]=a/6[330]=a/2[110] before the reaction b1=a/2[110] the geometric conditions are satisfied", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断给定的位错反应几何条件是否满足，答案直接给出了判断结果（满足或不满足），属于判断题的特征。 | 知识层次: 题目要求判断位错反应的几何条件是否满足，涉及基本的向量运算和位错反应的基本原理。虽然需要一定的理解，但主要是直接应用公式和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接套用和简单计算能力。题目要求判断位错反应的几何条件是否满足，解题步骤明确且直接，只需进行简单的矢量相加和比较即可得出正确结论。因此，在选择题型内属于较低难度，符合等级2的标准。" + }, + { + "idx": 400, + "question": "What are the characteristics of the modulated structure?", + "answer": "The modulated structure exhibits a periodic pattern, with high dispersion, uniform distribution, and high connectivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释调制结构的特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对调制结构基本特征的理解和记忆，属于基础概念层次，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（调制结构的特征），但正确选项包含了四个并列的特征描述（周期性图案、高分散性、均匀分布、高连通性），需要学生对调制结构有较全面的理解才能准确识别。这比单纯记忆单个特征（等级1）要求更高，但尚未达到需要分析复杂概念体系的等级3难度。" + }, + { + "idx": 401, + "question": "Explain the conditions for spinodal decomposition.", + "answer": "Conditions for spinodal decomposition: In a binary alloy phase diagram with a miscibility gap, the composition free energy curve has a range where ∂²G/∂x²<0, the temperature is sufficiently high for solute atoms to diffuse. (The decrease in free energy must be sufficient to overcome gradient energy and strain energy. This point is not required to be answered and will not be penalized.)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释spinodal decomposition的条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释spinodal分解的条件，涉及对二元合金相图和自由能曲线的理解，需要将多个概念（如miscibility gap、自由能二阶导数、扩散条件等）关联起来进行综合分析。虽然不涉及复杂计算，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解spinodal分解的基本概念，还需要掌握二元合金相图中混溶间隙的特征，以及自由能曲线二阶导数的物理意义。此外，题目还隐含了需要理解温度对扩散过程的影响。这些知识点需要考生进行多角度的分析和概念关联，超出了简单记忆的范畴，属于中等应用层次中较复杂的综合分析题。虽然题目给出了完整答案，但在选择题型中识别和判断这些条件的正确性仍需要较深入的理解。" + }, + { + "idx": 402, + "question": "What are the main factors affecting grain boundary migration?", + "answer": "The main factors affecting grain boundary migration rate: 1 solute atoms; 2 second-phase particles; 3 temperature; 4 orientation of grains on both sides of the grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响晶界迁移的主要因素，答案以文字解释和论述的形式呈现，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查对影响晶界迁移的主要因素的基本概念记忆和理解，不需要复杂的分析或综合运用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个因素（溶质原子、第二相粒子、温度、晶粒取向），但每个因素都是基础概念记忆层面的知识点，不需要复杂的分析或推理。学生只需识别并回忆这些影响晶界迁移的主要因素即可作答，属于概念解释和描述层级。" + }, + { + "idx": 403, + "question": "van der Waals bond", + "answer": "van der Waals bond: A physical bond formed by intermolecular attractive forces generated by instantaneous dipole moments and induced dipole moments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对van der Waals bond进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征。 | 知识层次: 题目考查van der Waals bond的基本定义和形成机制，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆van der Waals bond的基本定义，属于基础概念记忆层次。题目直接给出了正确选项的定义，没有涉及复杂的概念体系或需要解释和描述多个相关概念。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 404, + "question": "Grain boundary", + "answer": "Grain boundary: The region of atomic misalignment at the interface where two grains meet.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Grain boundary\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即晶界的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶界的基本定义，属于最基础的概念记忆层次。题目直接给出了正确选项的定义，无需进行复杂的概念比较或分析，因此难度等级为1。" + }, + { + "idx": 405, + "question": "Kirkendall effect", + "answer": "Kirkendall effect: A phenomenon in substitutional solid solutions where the relative diffusion of atoms of two components at different rates causes the migration of marker planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Kirkendall effect进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查Kirkendall效应的基本定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆Kirkendall效应的定义，即两种原子在置换固溶体中因扩散速率不同导致标记面迁移的现象。虽然需要掌握一定的专业术语和基本原理，但不需要进行复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 406, + "question": "Tie line", + "answer": "Tie line: the line connecting the composition points of two equilibrium phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Tie line\"进行文字解释和论述，答案是一个定义性的陈述，不需要计算或选择 | 知识层次: 题目考查对\"Tie line\"这一基本概念的定义记忆和理解，属于相图分析中的基础术语，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆并识别\"Tie line\"的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的简单描述，不需要解释或比较多个概念，解题步骤极为简单，符合选择题型中最基础的难度等级。" + }, + { + "idx": 407, + "question": "Solid solution", + "answer": "Solid solution: When foreign components enter the crystal structure, occupying part of the host crystal phase's lattice sites or interstitial positions, while still maintaining a single crystal phase, such a crystal is called a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Solid solution\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对固溶体这一基本概念的定义和特征的理解和记忆，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项对“solid solution”的定义进行了较为详细的解释，包括外来组分进入晶体结构的方式（占据晶格位点或间隙位置）以及保持单晶相的特性。这要求考生不仅记住定义，还需要理解其中的关键要素。因此，相较于仅需简单记忆基本定义的题目（等级1），该题目的难度稍高，属于等级2。" + }, + { + "idx": 408, + "question": "Is the energy condition for the following dislocation reaction satisfied? Where: b1=a/2[110], b2=a/6[12¯1], b3=a/6[211]", + "answer": "Energy condition: after the reaction |b2|^2+|b3|^2=(a^2/6^2)[1^2+2^2+(-1)^2]+(a^2/6^2)[2^2+1^2+1^2]=a^2/6+a^2/6=a^2/3 before the reaction |b1|^2=(a^2/2^2)(1^2+1^2)=a^2/2 the energy condition is satisfied and the dislocation reaction can proceed.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以验证能量条件是否满足。答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算位错反应的能条件，并综合分析结果判断反应是否可行。虽然计算本身不复杂，但需要理解位错反应的能量条件和相关公式的应用。 | 难度: 在选择题中属于中等偏上难度，需要理解位错反应的能量条件，进行多步矢量模平方计算，并比较反应前后的能量变化。虽然计算步骤明确，但涉及多个伯格斯矢量的运算和概念关联，对学生的综合分析能力有一定要求。" + }, + { + "idx": 409, + "question": "Dislocation climb", + "answer": "Dislocation climb: The movement of an edge dislocation perpendicular to the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation climb\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对位错攀移（dislocation climb）这一基本概念的定义和运动方向的记忆和理解，属于材料科学中基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别位错攀移的基本定义，属于最基础的概念记忆层面。题目仅涉及单个概念的简单描述，不需要任何分析或比较过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 410, + "question": "Eutectoid transformation", + "answer": "Eutectoid transformation: The process in which a single solid phase simultaneously precipitates two new solid phases with different compositions and crystal structures is called eutectoid transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Eutectoid transformation\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查对eutectoid transformation这一基本概念的定义和记忆，属于材料科学中相变的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"Eutectoid transformation\"基本定义的记忆，属于最基础的概念性知识。题目要求识别正确描述该术语定义的选项，不需要进行概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。选择题型中此类直接考察定义的题目属于最低难度级别。" + }, + { + "idx": 411, + "question": "Constitutional supercooling", + "answer": "Constitutional supercooling: During crystallization, the redistribution of solid and liquid phase compositions leads to the formation of a supercooled region in the liquid phase near the solid-liquid interface. This phenomenon is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Constitutional supercooling\"这一现象进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对\"Constitutional supercooling\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然涉及基础概念记忆，但需要理解并描述\"Constitutional supercooling\"这一现象的形成过程和基本原理，比单纯记忆定义要复杂一些，但不需要进行多个概念的比较分析或复杂体系阐述。" + }, + { + "idx": 413, + "question": "1. In the ionic crystal structure, the positive and negative ions form (1)", + "answer": "coordination polyhedron", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（coordination polyhedron）作为答案，而不是从多个选项中选择或判断对错，也不需要计算。这符合简答题的特征，即需要提供简短而具体的答案。 | 知识层次: 题目考查的是对离子晶体结构中正负离子排列方式的基本概念记忆，即配位多面体的定义，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需要考生回忆并识别\"coordination polyhedron\"这一专业术语的定义。题目直接考查对离子晶体结构中正负离子排列方式的基本概念，不需要进行任何解释或分析，属于最简单的记忆性知识考查。" + }, + { + "idx": 414, + "question": "For a carbon steel containing 0.1% carbon, carburized at 930‰, the carburized layer thickness is 0.4mm after 3 hours. Someone wants to obtain a 0.8mm carburized layer and plans to use 6 hours. Is this person's plan correct? Why?", + "answer": "$$ c{\\left(\\begin{array}{l l}{x,t}\\end{array}\\right)}=c_{1}+{\\left(\\begin{array}{l}{c_{8}-c_{1}}\\end{array}\\right)}{\\left(1-\\operatorname{erf}{\\frac{x}{2{\\sqrt{D t}}}}\\right)} $$ According to the problem, $c(\\textit{x}_{1},\\textit{t}_{1})=c(\\textit{x}_{2},\\textit{t}_{2})c_{s}$, and $c_{1}$ is a constant. Therefore, $$ \\operatorname{erf}{\\frac{x_{1}}{2{\\sqrt{D t_{1}}}}}=\\operatorname{erf}{\\frac{x_{2}}{2{\\sqrt{D t_{2}}}}} $$ Hence, $$ {\\frac{x_{1}}{2{\\sqrt{D t_{1}}}}}={\\frac{x_{2}}{2{\\sqrt{D t_{2}}}}}\\quad{\\frac{x_{1}}{\\sqrt{t_{1}}}}={\\frac{x_{2}}{\\sqrt{t_{2}}}},\\quad{\\frac{0.4}{\\sqrt{3}}}={\\frac{0.8}{\\sqrt{t_{2}}}} $$ $$ t_{2}={\\left({\\frac{0.8}{0.4}}\\times{\\sqrt{3}}\\right)}^{2}\\mathbf{h}=12\\mathbf{h} $$ Thus, the person's plan is incorrect.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来解决问题，答案中包含了具体的数学推导和计算过程，最终得出一个明确的数值结果。 | 知识层次: 题目需要应用扩散方程和误差函数进行多步计算，涉及碳浓度分布公式的理解和推导，需要将实际问题转化为数学模型并进行求解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的应用，并能够正确运用误差函数进行多步计算。题目要求考生将理论公式与实际问题相结合，通过数学推导得出正确结论。虽然题目提供了关键公式，但需要考生具备综合分析能力，能够正确建立变量关系并完成计算步骤。" + }, + { + "idx": 415, + "question": "1. In the ionic crystal structure, the distance between positive and negative ions depends on (2)", + "answer": "The sum of positive and negative ion radii", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释离子晶体结构中正负离子间距的决定因素，答案是一个简短的文字描述，不需要计算或选择选项 | 知识层次: 题目考查的是离子晶体结构中正负离子间距与离子半径关系的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中属于基础难度，仅需记忆离子晶体结构中正负离子间距的基本定义（正负离子半径之和），不需要进行概念解释或复杂分析。" + }, + { + "idx": 416, + "question": "Multiple slip", + "answer": "Multiple slip: When the resolved shear stress on several slip systems is equal and simultaneously reaches the critical resolved shear stress, the phenomenon of simultaneous slip occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Multiple slip\"这一现象进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"Multiple slip\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。虽然涉及多个概念（resolved shear stress、slip systems、critical resolved shear stress），但主要考察的是对\"Multiple slip\"这一现象的定义性理解，不需要进行复杂的比较分析或推导。在选择题型中，只需识别和匹配正确选项即可，属于中等偏下的难度水平。" + }, + { + "idx": 417, + "question": "3. The factors influencing the formation of substitutional solid solutions are _ (8)", + "answer": "Electronegativity", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写影响置换固溶体形成的因素，答案需要提供具体的文字解释（如电负性），而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对置换固溶体形成影响因素的基础概念记忆，属于基本原理的识记范畴 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的单一因素（电负性），不需要解释或比较多个概念，属于最基础的定义简答级别。" + }, + { + "idx": 418, + "question": "2. In polymer chains, the different spatial forms of molecules due to (4) are called conformations", + "answer": "Internal rotation of single bonds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物链中由于某种原因导致的不同空间形式，答案需要提供文字解释（Internal rotation of single bonds），而不是选择、判断或计算。 | 知识层次: 题目考查聚合物链中构象的基本概念，仅需记忆和理解由于单键内旋转导致分子不同空间形式的定义，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接考察对聚合物链构象形成原因的基础概念记忆，仅需识别\"Internal rotation of single bonds\"这一明确定义即可作答，无需进行概念解释或复杂分析。正确选项与题干关键词\"conformations\"存在直接对应关系，属于最基础的概念识别类选择题。" + }, + { + "idx": 419, + "question": "2.The property of polymers that allows them to change conformation is called (5)", + "answer": "Flexibility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用一个词（Flexibility）来回答问题，属于简答题的范畴，需要考生理解概念并给出准确的术语回答。 | 知识层次: 题目考查聚合物基本性质的定义记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，此题仅考查对聚合物基本性质\"Flexibility\"的定义记忆，属于最基础的概念性知识。题目直接给出专业术语的定义特征，不需要任何解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 420, + "question": "3. The factors influencing the formation of substitutional solid solutions include _ (6)", + "answer": "Ionic size", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写影响置换固溶体形成的因素，需要简要回答具体因素（如离子尺寸），属于简答题类型 | 知识层次: 题目考查对形成置换固溶体的影响因素的基本概念记忆，如离子尺寸等，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求识别影响置换固溶体形成的因素之一（离子尺寸），属于基础概念记忆层次。题目仅需回忆单一知识点，无需解释或比较多个概念，解题步骤简单直接，符合等级1的基本定义简答标准。" + }, + { + "idx": 421, + "question": "1.In the ionic crystal structure, the coordination number depends on the (3) of the positive and negative ions", + "answer": "radius ratio", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（radius ratio）作为答案，而不是从多个选项中选择或进行判断/计算。这符合简答题的特征，即需要提供简短但具体的答案。 | 知识层次: 题目考查离子晶体结构中配位数与正负离子半径比的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆类题目，仅需回忆离子晶体结构中配位数与正负离子半径比的关系这一基本定义即可作答，无需复杂分析或概念整合。" + }, + { + "idx": 422, + "question": "3. The factors influencing the formation of substitutional solid solutions include _ (7)", + "answer": "Crystal structure type", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举影响置换固溶体形成的因素，需要文字解释和论述，而不是从选项中选择或简单判断对错 | 知识层次: 题目考查的是对形成置换固溶体的影响因素之一（晶体结构类型）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"影响置换固溶体形成的因素包括晶体结构类型\"。题目仅要求识别正确选项，无需解释或分析，属于最基本的概念记忆层次。" + }, + { + "idx": 423, + "question": "3. The factors influencing the formation of substitutional solid solutions include _ (9)", + "answer": "Electron concentration factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写影响置换固溶体形成的因素，需要提供具体的文字答案（电子浓度因素），而不是从多个选项中选择或进行判断或计算。 | 知识层次: 题目考查对置换固溶体形成影响因素的基础概念记忆，属于基本原理的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的影响因素之一（电子浓度因素），属于直接回忆定义或分类的基本记忆性知识，无需解释或复杂分析，因此属于最低难度等级。" + }, + { + "idx": 424, + "question": "5. The two basic characteristics of martensitic transformation are (12)", + "answer": "Coherent shear", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释马氏体相变的基本特征，需要文字描述和论述，答案\"Coherent shear\"是一个简短的文字回答，符合简答题的特征。 | 知识层次: 题目考查马氏体相变的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对马氏体相变基本特征的记忆，属于基础概念的直接回忆。正确选项\"Coherent shear\"是马氏体相变的典型特征之一，无需复杂推理或概念比较，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 425, + "question": "6. Common methods for strengthening metal materials include: (15)", + "answer": "Dispersion strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属材料的强化方法，需要文字解释和论述，而不是从选项中选择或判断对错。答案\"Dispersion strengthening\"是一个简短的文字回答，符合简答题的特征。 | 知识层次: 题目考查金属材料强化方法的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对金属材料强化方法的基础概念记忆，属于最基础的定义性知识。学生只需识别\"弥散强化\"这一术语即可作答，无需进行概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 426, + "question": "5. The two basic characteristics of martensitic transformation are (11)", + "answer": "Diffusionless transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答马氏体相变的基本特征，需要简要的文字解释和论述，而不是从选项中选择或判断对错。答案\"Diffusionless transformation\"是一个简短的描述性回答。 | 知识层次: 题目考查马氏体相变的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆马氏体相变的基本特征之一（无扩散转变），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或复杂分析，符合等级1的基本定义简答标准。" + }, + { + "idx": 427, + "question": "6. Common methods for strengthening metal materials include: (13)", + "answer": "Grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属材料强化的常见方法，需要简要回答具体强化方式（晶粒细化强化），属于需要文字解释的简答题类型。 | 知识层次: 题目考查对金属材料强化方法的基础概念记忆，属于基本原理等记忆性知识 | 难度: 在选择题型中，该题目仅考察对金属材料强化方法中最基础概念的识别能力（晶粒细化强化），属于单一知识点的基础记忆层面，不需要解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 428, + "question": "6.Common methods for strengthening metal materials include: (14)", + "answer": "Solid solution strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属材料强化的常见方法，需要文字解释和论述，而不是从给定选项中选择或判断对错 | 知识层次: 题目考查金属材料强化方法的基本概念记忆，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对金属材料强化方法的基础概念记忆，属于最基本的定义简答级别。学生只需识别\"固溶强化\"这一基本术语即可作答，无需进行概念解释或复杂分析，符合等级1的简单记忆要求。" + }, + { + "idx": 429, + "question": "4.The expression for the relationship between the diffusion coefficient, diffusion activation energy, and diffusion temperature is (10)", + "answer": "D=D0exp(-Q/RT)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出扩散系数、扩散激活能和扩散温度之间关系的表达式，需要直接给出公式作为答案，属于简答题类型 | 知识层次: 题目考查扩散系数与活化能及温度关系的基本公式记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆扩散系数、扩散激活能和扩散温度之间的基本关系表达式，属于基础概念记忆的简单题目。无需解释或分析，只需识别正确选项即可。" + }, + { + "idx": 430, + "question": "7. The typical ingot structure usually consists of (17)", + "answer": "Surface fine grain zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的结构名称（Surface fine grain zone），属于需要简短文字回答的题目类型，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查典型铸锭结构的基本组成部分，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对典型铸锭结构的基本组成部分的记忆，属于基础概念记忆层次。正确选项直接对应教材或课堂讲授的定义，无需复杂推理或概念间的比较分析，符合等级1“基本定义简答”的标准。" + }, + { + "idx": 431, + "question": "7.The typical ingot structure usually consists of (18)", + "answer": "columnar crystal zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（columnar crystal zone）作为答案，属于需要简短文字回答的题目类型，而非选择、判断或计算。 | 知识层次: 题目考查对典型铸锭结构的基础概念记忆，仅需回答特定区域名称，属于定义性知识范畴 | 难度: 在选择题型中，该题目仅考察对典型铸锭结构组成的基础概念记忆，属于最基础的定义简答类型。学生只需回忆\"columnar crystal zone\"这一术语即可作答，无需进行概念解释或复杂分析，因此属于难度等级1。" + }, + { + "idx": 432, + "question": "Point defects are thermodynamically stable defects, and a certain number of equilibrium defects exist in crystals at a given temperature, also known as intrinsic defects.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确与否（√表示正确），符合判断题的特征。 | 知识层次: 题目考查点缺陷的基本概念和定义，属于基础概念的记忆和理解范畴 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆点缺陷的定义和特性即可做出正确选择，无需深入理解或分析复杂概念。" + }, + { + "idx": 434, + "question": "7.Typical ingot structure usually has (19)", + "answer": "Central equiaxed crystal zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Central equiaxed crystal zone）作为答案，这属于需要简短文字回答的问题类型，而不是从多个选项中选择或判断对错 | 知识层次: 题目考查典型铸锭结构的基本概念记忆，属于定义和分类等记忆性知识。 | 难度: 在选择题型中，该题目仅考察对典型铸锭结构的基本定义记忆，属于最基础的概念性知识。学生只需识别\"Central equiaxed crystal zone\"这一标准术语即可作答，无需进行概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 435, + "question": "Non-spontaneous nucleation still requires structural fluctuations, compositional fluctuations, and energy fluctuations.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述句，要求判断其正确性（用√表示正确），符合判断题的特征 | 知识层次: 题目考查对非自发成核所需条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断一个简单陈述的正确性，涉及的是基础概念记忆层次的知识点（非自发形核的基本要求），无需复杂分析或推理。学生只需回忆相关定义即可作答，属于选择题型中最简单的难度等级。" + }, + { + "idx": 436, + "question": "The eutectic transformation occurs in systems where the liquid phase is completely miscible and the solid phase is completely immiscible.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确与否（答案给出的是×表示错误），符合判断题的特征。 | 知识层次: 题目考查共晶转变的基本概念，属于定义和基本原理的记忆性知识 | 难度: 该题目属于基础概念正误判断，仅需记忆共晶转变的定义和条件即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 437, + "question": "Polymers with simple structure, high regularity, and good symmetry are not prone to crystallization.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案用×表示错误），符合判断题的特征 | 知识层次: 题目考查对聚合物结晶条件的基本概念记忆和理解，涉及结构简单性、规则性和对称性对结晶倾向的影响，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆聚合物结晶的基本原理即可作答，无需深入理解或分析多个概念。题目结构简单，直接考察基础定义，因此属于最低难度等级。" + }, + { + "idx": 438, + "question": "The reason why the carbon solubility of austenite is higher than that of ferrite is because the crystal interstices of austenite are larger.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√），符合判断题的特征 | 知识层次: 题目考查对奥氏体和铁素体晶体间隙大小及其对碳溶解度影响的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆奥氏体和铁素体的碳溶解度差异原因这一基本原理即可作答，无需复杂分析或推理过程。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 439, + "question": "8.The driving force for the coarsening of precipitates is (20)", + "answer": "The Gibbs free energy difference between different particles", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释沉淀物粗化的驱动力，需要文字解释和论述，答案形式为简短的文字描述而非选择或计算。 | 知识层次: 题目考查对沉淀相粗化驱动力的理解，需要将Gibbs自由能差与不同颗粒之间的能量差异联系起来，属于概念关联和综合分析的中等应用层次。虽然涉及基础概念，但需要一定的理解和分析能力来建立概念之间的联系。 | 难度: 在选择题中属于中等难度，需要理解Gibbs自由能的概念以及其在析出相粗化过程中的作用，并进行概念关联和综合分析。虽然题目涉及中等应用层次的知识，但在选择题型中，通过选项对比可以相对容易地识别正确答案，不需要进行多步计算或深度关联性分析。" + }, + { + "idx": 440, + "question": "In a ternary phase diagram, the degree of freedom at the eutectic temperature point is 0. At this time, it is a three-phase equilibrium.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（三元相图中共晶温度点的自由度为0，此时为三相平衡），并要求判断其正误（答案给出×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对三元相图中自由度概念和三相平衡条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆三元相图中共晶温度点的自由度概念即可作答。在选择题型中属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 441, + "question": "During diffusion, solute atoms always migrate from high concentration to low concentration.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其对错（答案给出的是×表示错误），符合判断题的特征 | 知识层次: 题目考查扩散过程中溶质原子迁移方向的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于非常基础的概念正误判断。只需要记忆扩散过程中溶质原子的迁移方向这一基本原理即可作答，无需深入理解或分析多个概念。题目直接考察对基础定义的记忆，属于选择题型中最简单的难度等级。" + }, + { + "idx": 442, + "question": "In the crystal structure of iodides, iodine occupies the corners of the cube and the body-centered position, so its structure type is body-centered lattice.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（碘在晶体结构中的位置和结构类型），并要求判断其正确性（答案给出×表示错误），符合判断题的特征。 | 知识层次: 题目考查晶体结构类型的基本概念记忆和理解，涉及简单的晶体结构分类知识，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体结构类型的基本定义即可判断。在选择题型中属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 443, + "question": "The yield strength σs of crystalline materials changes with the variation of the tensile axis relative to the crystal orientation.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The yield strength σs of crystalline materials changes with the variation of the tensile axis relative to the crystal orientation），并要求判断其正确性（答案给出√表示正确）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查的是晶体材料屈服强度与拉伸轴相对于晶体取向变化的基本概念，属于基础概念的记忆和理解范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体材料屈服强度与拉伸轴方向关系的基本原理即可作答，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 444, + "question": "Generally speaking, during solid-state phase transformations, crystal defects in the parent phase can promote the formation of the new phase.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对固态相变中晶体缺陷作用的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 该题目属于基础概念正误判断，仅需记忆晶体缺陷对固态相变的影响这一基本原理即可作答。在选择题型中属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 445, + "question": "What is the total cost for carburizing 500 gears at 900°C (1173K) for 10 hours, given the cost is 1000 yuan per hour?", + "answer": "Total cost = 1000 yuan/h * 10 h = 10000 yuan", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（1000 yuan/h * 10 h）并应用简单的乘法公式来求解总成本，答案是一个具体的数值结果。 | 知识层次: 题目仅涉及基本公式应用和简单计算，直接套用给定的成本和时间进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（总成本=每小时成本×时间）进行简单计算，无需任何额外的分析或组合多个公式。解题步骤非常直接，属于最基础的难度等级。" + }, + { + "idx": 446, + "question": "What is the total cost for carburizing 500 gears at 1000°C (1273K) for 3.299 hours, given the cost is 1500 yuan per hour?", + "answer": "Total cost = 1500 yuan/h * 3.299 h = 4948.5 yuan", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算总成本），并给出了具体的计算公式和步骤，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式应用和简单计算，无需多步推理或综合分析，仅需将给定数值直接套用乘法公式即可得出结果。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行简单计算（总成本=每小时成本×时间），无需额外的概念理解或复杂步骤，属于最基础的难度等级。" + }, + { + "idx": 447, + "question": "What is the equivalent time required to achieve the same carburization depth at 1000°C (1273K) as 10 hours at 900°C (1173K), given Q=32900 cal/mol and R=1.987 cal?", + "answer": "t_1273 = D_1173 * t_1173 / D_1273 = 10 * exp[-32900/(1.987*1173)] / exp[-32900/(1.987*1273)] = 10 * exp(-14.1156) / exp(-13.0068) h = 10 * exp(-1.5089) h = 10 * 0.3299 h = 3.299 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解等效时间，涉及指数函数和温度转换的计算过程。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式应用、指数运算和单位转换，涉及扩散方程的深入理解和温度对扩散系数的影响。虽然不涉及复杂的推理或创新设计，但需要综合运用多个知识点进行计算和分析。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程和温度对扩散系数的影响，并进行多步计算（包括指数运算和除法）。虽然题目提供了公式和参数，但解题过程涉及多个概念的综合应用和较复杂的计算步骤，属于综合性计算问题。" + }, + { + "idx": 448, + "question": "Explain the reason for cold deformation strengthening of pure metals using dislocation theory", + "answer": "Strengthening reason: Dislocation intersection produces kinks and jogs, dislocation reactions produce immobile dislocations, and dislocation multiplication increases dislocation density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用位错理论解释纯金属冷变形强化的原因，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求使用位错理论解释纯金属冷变形强化的原因，涉及位错相互作用、位错反应和位错增殖等复杂机理的分析和解释，需要综合运用多个概念并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 449, + "question": "At which temperature is the carburization cost lower for processing 500 gears to achieve the same depth?", + "answer": "The cost at 1000°C (4948.5 yuan) is lower than at 900°C (10000 yuan), so 1000°C is more cost-effective.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种温度下的成本，并选择更经济的选项，答案提供了具体的数值比较和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及多步计算（比较不同温度下的成本）和综合分析（选择更经济的温度），需要将温度与成本关联起来进行判断，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及温度对成本的影响，需要进行多步计算和综合分析，但选项已经提供了明确的比较结果，减少了部分思考负担。" + }, + { + "idx": 450, + "question": "What effect does a rough interface have on the crystal growth mode?", + "answer": "For a rough interface, continuous growth occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释粗糙界面对晶体生长模式的影响，答案提供了简短的文字解释，符合简答题的特征。 | 知识层次: 题目考查晶体生长模式的基本概念，特别是粗糙界面对生长模式的影响，属于基本原理的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅考察对粗糙界面与晶体生长模式关系的基础定义记忆，属于最基础的概念性知识，无需解释或分析步骤。" + }, + { + "idx": 451, + "question": "Changes occurring during recrystallization annealing", + "answer": "Changes occurring: During annealing, the dislocation density decreases, deformed grains transform into equiaxed grains, residual stresses are eliminated, and strength and hardness are reduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释再结晶退火过程中发生的变化，答案以文字形式详细描述了这一过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对再结晶退火过程中发生的变化的基本概念记忆和理解，包括位错密度降低、晶粒形状变化、残余应力消除以及力学性能变化等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述多个变化过程（如位错密度降低、晶粒形态转变、残余应力消除等），而不仅仅是简单的定义或分类。这要求考生对再结晶退火过程有较为全面的理解，并能将这些变化联系起来进行描述。" + }, + { + "idx": 452, + "question": "Approximate process parameters for recrystallization annealing", + "answer": "Process parameters: Heating temperature T=0.4Tm plus 100~200Ω, heating time depends on the specific furnace load and workpiece size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供近似的过程参数，答案以文字解释和论述的形式给出，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求提供再结晶退火的近似工艺参数，涉及基本公式（T=0.4Tm）和简单应用（加热温度的计算和加热时间的估计），属于直接套用基本知识的范畴，不需要复杂的分析或综合。 | 难度: 在选择题中属于较低难度，题目仅要求考生识别正确的再结晶退火工艺参数描述，涉及基本公式应用（0.4Tm）和简单参数范围记忆（100~200Ω），无需复杂计算或概念比较。" + }, + { + "idx": 453, + "question": "What is a rough interface?", + "answer": "Rough interface: It is a solid-liquid interface where the atomic arrangement on the solid-phase surface is uneven and rough, displaying no crystallographic plane characteristics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"rough interface\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对粗糙界面这一基本概念的定义和特征的理解，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别粗糙界面的基本定义，属于基础概念记忆层次。题目描述直接给出了定义，没有涉及复杂的概念体系或需要多步骤分析，因此在选择题型内属于最简单的难度等级。" + }, + { + "idx": 454, + "question": "What is a smooth interface?", + "answer": "Smooth interface: It is another type of solid-liquid interface where the atoms on the solid-phase interface are arranged into a flat atomic plane, specifically a certain crystallographic plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“smooth interface”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对平滑界面这一基本概念的定义和特征的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别“smooth interface”的基本定义，属于基础概念记忆层次。正确选项直接给出了定义，没有涉及复杂的概念体系或需要推理分析的内容，因此属于最简单的难度等级。" + }, + { + "idx": 455, + "question": "How to completely eliminate work hardening? Explain the heat treatment method used", + "answer": "Method to eliminate work hardening: recrystallization annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何完全消除加工硬化，并说明使用的热处理方法，需要文字解释和论述。答案提供了具体的处理方法（再结晶退火），但需要进一步解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解再结晶退火的基本概念（基础记忆），还需要解释其作为消除加工硬化的热处理方法的应用（概念关联和综合分析）。这涉及到将理论知识应用于具体问题，并解释其机理，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解工作硬化的概念以及消除方法，并关联到具体的再结晶退火热处理工艺。虽然不涉及多步计算，但需要对材料科学中的基本概念和工艺有较好的掌握，并进行综合分析。" + }, + { + "idx": 456, + "question": "Can the perfect dislocation $\\pmb{b}_{1}$ in a face-centered cubic crystal decompose into partial dislocations $b_{2}, b_{3}?$ Given ${\\pmb b}_{1}=\\frac{a}{2}[\\stackrel{-}{1}10], {\\pmb b}_{2}=\\frac{a}{6}[\\stackrel{-}{1}2\\stackrel{-}{1}], {\\pmb b}_{3}=\\frac{a}{6}[\\stackrel{-}{2}11],$ state the reasons.", + "answer": "Geometric condition: $\\begin{array}{l}{{\\vec{b}_{1}=a/2\\cdot\\left[\\stackrel{\\rightharpoonup}{1}10\\right]}}\\ {{}}\\ {{\\vec{b}_{2}+\\stackrel{\\rightharpoonup}{b}_{3}=a/6\\cdot\\left[\\stackrel{\\rightharpoonup}{3}30\\right]=a/2\\cdot\\left[\\stackrel{\\rightharpoonup}{1}10\\right]}}\\end{array}$ Energy condition: $\\mid\\vec{b}_{1}\\mid^{2}=(a/2\\sqrt{1+1+0})^{2}=a^{2}/2$ $|\\vec{b}_{2}|^{2}+|\\vec{b}_{3}|^{2}=(a/6\\sqrt{1+4+1})^{2}+\\bigl(a/6\\sqrt{4+1+1}^{2}=a^{2}/3
Plate martensiteLenticular shape
Lath martensiteLong columnar shape with elliptical cross-section
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述两种马氏体的三维形态差异，需要文字解释和论述，答案以表格形式呈现了对比说明，符合简答题的特征 | 知识层次: 题目考查对板条马氏体和片状马氏体三维形态差异的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生记忆并区分两种马氏体的三维形态特征（板条状马氏体的透镜状形态和板条马氏体的长柱状形态）。虽然涉及两个概念的对比，但属于基础概念记忆层面，无需复杂推理或体系化阐述。相较于单纯的定义复述（等级1），该题需要考生对形态特征进行准确对应，属于概念解释和描述级别（等级2）。" + }, + { + "idx": 462, + "question": "Screw dislocation", + "answer": "A dislocation where the dislocation line is parallel to the Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Screw dislocation\"进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征。 | 知识层次: 题目考查对screw dislocation这一基本概念的定义记忆和理解，属于材料科学中位错理论的基础知识，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别螺型位错的基本定义（位错线与伯氏矢量平行），属于最基础的概念记忆层次，无需复杂分析或推理步骤。" + }, + { + "idx": 463, + "question": "Explain the differences in metallographic structure between plate martensite and lath martensite", + "answer": "
Plate martensiteThe initially formed martensite needles traverse the austenite grains, while subsequently formed ones gradually become smaller. The plates are not parallel to each other. Those with C%>1.4% have a midrib
Lath martensiteThe original austenite grains are divided into several blocks, each consisting of several lath bundles, and each lath bundle is composed of many parallel lath martensites
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释板条马氏体和片状马氏体在金相组织上的差异，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求解释板条马氏体和片状马氏体在金相组织上的差异，这需要对马氏体转变机制、晶体结构以及显微组织特征有深入的理解和分析能力。答案中不仅描述了两种马氏体的形态特征，还涉及了它们的形成过程和相互关系，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 464, + "question": "Explain the difference in substructure between plate martensite and lath martensite", + "answer": "
Plate martensiteThere are a large number of twins in the middle of the martensite, and dislocations at the edges. The midrib is fine twins
Lath martensiteThere are high-density dislocations inside the martensite, forming dislocation cells
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释板条马氏体和片状马氏体的亚结构差异，答案以文字描述和表格形式呈现，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释板条马氏体和片状马氏体的亚结构差异，涉及对马氏体内部微观结构的深入理解和分析，需要综合运用材料科学中的相变理论和显微组织知识，并进行推理分析。这超出了基础概念记忆和简单应用的范畴，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生深入理解并区分两种马氏体的亚结构差异，涉及复杂的微观结构特征（如孪晶、位错、位错胞等）。正确选项需要综合运用材料科学知识进行机理解释和对比分析，属于复杂现象的全面分析层次。选择题型中此类题目对知识深度和综合分析能力要求极高，远超简单记忆或基础理解层面。" + }, + { + "idx": 466, + "question": "Sorbite", + "answer": "A product of medium-temperature pearlite transformation, composed of lamellar ferrite and cementite, with smaller interlamellar spacing and thinner layers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Sorbite\"进行文字解释和论述，答案提供了详细的描述，符合简答题的特征 | 知识层次: 题目考查对Sorbite这一基本概念的记忆和理解，包括其组成和结构特征，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生能够准确回忆并描述Sorbite的定义和组成。虽然需要记忆具体的材料科学术语（如lamellar ferrite和cementite）以及其结构特征（smaller interlamellar spacing and thinner layers），但不需要进行复杂的分析或比较。在选择题型中，这属于中等偏下的难度，主要考察对基本概念的掌握程度。" + }, + { + "idx": 467, + "question": "Cross-slip", + "answer": "The slip process transitions from one slip plane to another along the same slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Cross-slip\"这一概念进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征 | 知识层次: 题目考查对Cross-slip这一基本概念的定义和简单解释，属于基础概念的记忆和理解层面，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"Cross-slip\"的基本定义，属于最基础的概念记忆层面。题目正确选项直接给出了该术语的标准定义描述，不需要进行任何概念比较或复杂推理，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 468, + "question": "Frenkel defect", + "answer": "The displacement of an atom to an interstitial site in the crystal lattice is called a Frenkel defect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对Frenkel defect进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查Frenkel defect的基本定义，属于基础概念的记忆和理解范畴，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即Frenkel defect的定义。正确选项直接给出了定义，无需进行复杂的分析或推理。因此，该题目属于基本定义简答的难度等级。" + }, + { + "idx": 469, + "question": "Pseudoeutectoid transformation", + "answer": "Pseudoeutectoid transformation: During non-equilibrium transformation, hypoeutectoid or hypereutectoid alloys near the eutectoid composition point exhibit a fully eutectoid microstructure upon completion of the transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"Pseudoeutectoid transformation\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对非平衡转变过程中伪共析转变现象的解释，需要综合运用相变原理、非平衡条件影响等知识进行机理分析，涉及较深层次的概念关联和推理分析能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目涉及非平衡转变条件下的伪共析转变现象，要求考生不仅掌握共析转变的基本概念，还需要理解亚共析/过共析合金在特定条件下的微观结构变化机理。这种题目需要考生具备：1) 深入的热力学和动力学知识；2) 对非平衡转变过程的理解；3) 综合分析合金成分与微观结构关系的能力。在选择题型中，这种需要多维度知识整合和机理分析的题目属于最复杂的类型。" + }, + { + "idx": 470, + "question": "Perfect dislocation", + "answer": "A dislocation whose Burgers vector equals a lattice vector is called a perfect dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Perfect dislocation\"进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对完美位错（perfect dislocation）这一基本概念的定义记忆和理解，属于材料科学中位错理论的基础知识点，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"perfect dislocation\"这一基础定义的记忆，无需解释或分析。正确选项直接给出了定义，属于最基础的概念记忆题，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 471, + "question": "Coordination polyhedron", + "answer": "The polyhedron formed by connecting the centers of atoms or ions directly bonded to a central atom or ion is called the coordination polyhedron of that atom or ion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Coordination polyhedron\"进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对\"coordination polyhedron\"这一基本概念的定义记忆和理解，不涉及应用或分析过程 | 难度: 在选择题型中，该题目仅考察对\"配位多面体\"这一基础概念的定义记忆，属于最基础的知识层次。题目仅要求识别正确描述定义的正确选项，无需解释或分析概念之间的关系，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 472, + "question": "4. According to the different atomic arrangement structures at the interface, what three types of interfaces can phase interfaces in solids be divided into?", + "answer": "Coherent, semi-coherent, incoherent", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据不同的原子排列结构将固体中的相界面分为三种类型，并需要文字解释和论述，答案形式为列举三种类型，符合简答题的特征。 | 知识层次: 题目考查对固体中相界面分类的基本概念记忆，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆和识别固体相界面的三种基本分类（共格、半共格、非共格），属于基础概念的直接回忆，无需解释或复杂分析。题目仅测试对定义性知识的掌握，符合等级1的基本定义简答标准。" + }, + { + "idx": 473, + "question": "1. How many independent slip systems must be activated for plastic deformation in polycrystalline materials?", + "answer": "5", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（5），但没有提供选项供选择，属于需要直接回答的简答题形式。 | 知识层次: 题目考查的是关于多晶材料塑性变形所需独立滑移系统数量的基本概念记忆，属于材料科学中关于塑性变形的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"多晶材料塑性变形需要激活多少个独立滑移系统\"这一具体数值的记忆。题目不涉及概念解释或复杂体系分析，属于最基础的定义简答类型，符合等级1的难度标准。" + }, + { + "idx": 474, + "question": "The number-average relative molecular mass of polymers ( $\\overline{{{\\cal M}_{n}}}$ )", + "answer": "The relative molecular mass of polymers weighted by number, $\\widetilde{M_{n}}=\\sum_{i}{N_{i}M_{i}}/{\\sum{N_{i}}}$, where $N_{i}$ is the molar fraction of molecules with molecular weight $M_{i}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对聚合物的数均相对分子质量进行解释和定义，答案提供了详细的文字解释和公式说明，符合简答题的特征。 | 知识层次: 题目考查聚合物数均相对分子质量的基本定义和计算公式的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要理解并正确应用聚合物数均相对分子质量的定义和计算公式。解题步骤相对直接，但需要掌握公式中各符号的含义及其相互关系。相较于仅记忆定义的等级1题目，该题目对概念的理解和应用要求稍高，因此属于等级2。" + }, + { + "idx": 475, + "question": "2. During solid-state phase transformation nucleation, when the nucleus morphology is disk-shaped, it has the minimum what energy and the maximum what?", + "answer": "strain energy, interface", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求用文字解释和论述，答案需要填写特定的术语（strain energy, interface），而不是从选项中选择或进行数值计算。 | 知识层次: 题目涉及固态相变中形核过程的能量分析，需要理解不同形核形态（盘状）对应的应变能和界面能的变化关系。这需要将基础概念（应变能、界面能）与形核形态特征进行关联分析，属于中等应用层次的知识运用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及固态相变成核过程中的能量最小化和界面最大化问题，要求考生掌握应变能和界面能的概念及其在特定形态（盘状）下的变化规律。虽然不需要多步计算，但需要对相关物理概念有较深的理解并能进行综合分析。" + }, + { + "idx": 476, + "question": "Explain the differences in mechanical properties between plate martensite and lath martensite", + "answer": "
Plate martensiteHard and brittle
Lath martensiteStrong and tough
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种马氏体在机械性能上的差异，需要文字解释和论述，答案以表格形式呈现了对比说明，符合简答题的特征。 | 知识层次: 题目要求比较两种马氏体的力学性能差异，需要理解马氏体的微观结构特征及其对力学性能的影响，属于概念关联和综合分析层次。虽然不涉及复杂计算，但需要对材料科学中的相变和力学性能有较深入的理解。 | 难度: 在选择题中属于中等难度，需要理解两种马氏体的机械性能差异并进行比较分析。题目要求考生掌握板条马氏体和片状马氏体的基本特性，并能准确区分它们的机械性能特点（硬脆vs强韧）。虽然不涉及多步计算，但需要对相关概念有清晰的认识和关联能力。" + }, + { + "idx": 477, + "question": "3. In solid-state crystals, diffusion can be classified into which two types based on whether new phase structures are formed during atomic diffusion?", + "answer": "Atomic diffusion and reactive diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述扩散的分类，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对固态晶体中扩散类型的基本分类记忆，属于基础概念的记忆和理解层面 | 难度: 在选择题型中，该题目仅考察对固态晶体扩散分类的基础概念记忆，属于最基础的定义简答类型。题目直接给出两种扩散类型的名称（原子扩散和反应扩散），不需要进行概念解释或复杂分析，只需识别正确分类即可。这种题目在选择题中属于最低难度级别。" + }, + { + "idx": 479, + "question": "7. What are the main structural types (subtypes) of silicate crystals?", + "answer": "Island, group (or ring), chain, layer, framework", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举硅酸盐晶体的主要结构类型，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对硅酸盐晶体主要结构类型的基本分类记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅要求考生回忆并选择硅酸盐晶体的主要结构类型（岛状、群状/环状、链状、层状、框架状）。在选择题型中，这类直接考察定义和分类的记忆性知识属于最简单的难度等级，不需要任何解释、分析或推理过程。" + }, + { + "idx": 480, + "question": "6. In polymers, the different spatial forms of molecules caused by what are called conformations, and the property of polymers to change conformations is called what?", + "answer": "Single bond internal rotation, flexibility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述聚合物分子构象变化的原因和性质，答案也是以文字形式给出，没有提供选项或需要计算。 | 知识层次: 题目考查聚合物分子构象变化的基本概念和定义，属于基础概念的记忆和理解范畴 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接询问聚合物分子构象变化的原因和性质名称，正确选项\"Single bond internal rotation, flexibility\"是聚合物科学中最基础的定义性知识。学生只需记忆相关术语即可作答，无需进行概念解释或复杂分析，符合选择题型中最简单的难度等级标准。" + }, + { + "idx": 481, + "question": "What is the ground-state electron configuration of Cr (atomic number 24)?", + "answer": "1s22s22p63s23p63d54s1", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求直接写出铬（Cr）的基态电子构型，不需要从多个选项中选择，也不涉及判断对错或数值计算，而是需要准确写出电子排布式，属于简答题类型。 | 知识层次: 题目考查对原子基态电子排布的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求记忆铬（Cr）的基态电子排布，属于基础概念记忆的范畴。虽然需要记住特定的电子排布顺序，但不需要进行复杂的分析或推理。相对于更简单的定义简答题（等级1），此题需要记忆的元素更多，但仍在概念解释和描述的难度范围内。" + }, + { + "idx": 482, + "question": "9.Linear polymers can be reused and are also called what kind of plastic; cross-linked polymers cannot be reused and are called what kind of plastic?", + "answer": "Thermoplastic, thermosetting", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述两种塑料的名称，而不是从选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查对线性聚合物和交联聚合物的基本分类和名称的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别线性聚合物和交联聚合物的基本分类名称（热塑性和热固性），属于基础概念记忆层次，解题步骤简单直接，无需深入理解或分析。" + }, + { + "idx": 483, + "question": "8. Intermetallic compounds typically include what controlled by electronegativity, close-packed phases primarily governed by atomic size, and what mainly controlled by electron concentration?", + "answer": "Normal valence compounds, topologically close-packed phases, electron compounds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答关于金属间化合物的不同类型及其控制因素的问题，答案形式为简短的文字描述而非选择或判断。 | 知识层次: 题目考查对金属间化合物分类的基本概念记忆，包括电负性控制的正价化合物、原子尺寸控制的密排相和电子浓度控制的电子化合物。这些都属于材料科学中基础的定义和分类知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（金属间化合物的分类及其控制因素），但正确选项直接对应题干中的三个空，属于概念解释和描述层面的知识。考生需要记忆并理解这些基本分类原则，但不需要进行复杂的分析或推导。" + }, + { + "idx": 484, + "question": "In the bainitic transformation, neither Fe nor C atoms undergo diffusion.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（In the bainitic transformation, neither Fe nor C atoms undergo diffusion），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查贝氏体转变过程中Fe和C原子扩散行为的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆贝氏体转变过程中Fe和C原子的扩散行为即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 485, + "question": "In the solid-state crystal diffusion process, the direction of diffusing atom migration is always from high concentration to low concentration.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查固体晶体扩散过程中原子迁移方向的基本概念，属于对基本原理的记忆和理解。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆扩散过程的基本原理即可作答，无需深入理解或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 486, + "question": "The finer the grain size, the higher the strength and hardness of the crystal, and the better the plasticity and toughness.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶粒尺寸与材料力学性能关系的基本概念记忆，属于材料科学中最基础的知识点之一，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆晶粒尺寸与材料性能的基本关系即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 487, + "question": "During solid-state phase transformation, crystal defects in the parent phase hinder the formation of nuclei of the new phase.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述句要求判断对错，答案以\"√\"形式给出，符合判断题的特征 | 知识层次: 题目考查对固态相变过程中晶体缺陷对成核影响的基本概念的理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需考生记忆并判断\"晶体缺陷阻碍新相形核\"这一基本原理的正确性。在选择题型中，这类直接考察定义和基本原理记忆的题目属于最简单的难度等级，不需要复杂的概念理解或分析过程。" + }, + { + "idx": 489, + "question": "Component crystal types differ, but under specific conditions, they can also form infinitely miscible solid solutions.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对晶体类型和固溶体形成条件的基本概念记忆，属于基础概念层面的判断题 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆晶体类型和固溶体的基本定义即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 490, + "question": "Polymers with simple structures, high regularity, and good symmetry are prone to crystallization.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物结晶基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅涉及聚合物结晶的基本原理，即结构简单、规则性高和对称性好的聚合物易于结晶这一基础概念的陈述。正确选项为√，表明这是一个直接的记忆性知识判断，无需复杂的分析或推理。因此，在选择题型内，该题目属于最低难度等级。" + }, + { + "idx": 491, + "question": "Two edge dislocations with opposite signs and parallel dislocation lines on the same slip plane will move away from each other due to their interaction.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征。 | 知识层次: 题目考查对位错相互作用这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆位错相互作用的基本原理即可判断正误。在选择题型中属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 492, + "question": "What is aging?", + "answer": "Aging: The precipitation process of a supersaturated solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语进行文字解释和论述，答案提供了定义而非选择或判断 | 知识层次: 题目考查基本概念的记忆和理解，即对\"aging\"这一术语的定义进行回忆和表述，不涉及复杂的应用或分析。 | 难度: 在选择题型中，此题仅要求记忆基础定义，属于最简单的难度等级。题目直接考察对\"aging\"这一专业术语的定义记忆，不需要任何解释、分析或推理过程。正确选项直接给出了标准定义，学生只需识别匹配即可，符合选择题型中最基础的定义简答要求。" + }, + { + "idx": 493, + "question": "In the cesium chloride structure, chlorine occupies the corner positions and the body center position of the cube, so its structure type is body-centered lattice.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（关于氯化铯结构的描述），并要求判断其正确性（答案用×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对晶体结构类型的基本概念记忆和理解，涉及简单的定义和分类知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆并识别氯化铯结构的正确描述即可。题目直接考察对体心晶格定义的理解，无需复杂分析或推理步骤，属于最基础难度等级。" + }, + { + "idx": 494, + "question": "What are the main morphological types of martensitic transformation products in steel?", + "answer": "(2) Morphology of transformation products: lath martensite (1 point); acicular martensite. (1 point)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和描述马氏体转变产物的主要形态类型，答案以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目考查马氏体转变产物的主要形态类型，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确区分和记忆两种不同的马氏体形态（板条马氏体和针状马氏体），而不是简单的单一概念定义。这要求考生对马氏体转变产物的分类有较清晰的理解和记忆，属于概念解释和描述的层次。" + }, + { + "idx": 495, + "question": "The reason why the carbon solubility of austenite is higher than that of ferrite is that the interstitial spaces in the austenite crystal structure are larger.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），这是典型的判断题特征 | 知识层次: 题目考查对奥氏体和铁素体晶体结构中碳溶解度的基本概念的理解，属于基础概念的记忆和简单理解范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆奥氏体和铁素体的晶体结构差异这一基本原理即可作答。在选择题型中，这类仅涉及单一概念记忆的判断题属于最低难度等级。" + }, + { + "idx": 496, + "question": "What processes does aging typically undergo?", + "answer": "Aging process: 1) Formation of GP zones. 2) Formation of a series of metastable intermediate phases that maintain coherency or semi-coherency with the parent phase. 3) Formation of stable precipitates. 4) Coarsening and growth of stable precipitates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释老化过程的不同阶段，答案以文字形式详细描述了老化过程的四个阶段，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对时效处理过程的基本概念记忆和理解，主要涉及时效过程中各个阶段的描述，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个步骤的记忆（GP zones的形成、亚稳中间相的形成、稳定析出相的形成以及其粗化和生长），但这些步骤都是老化过程的典型阶段，属于基础概念的记忆性知识。学生需要能够回忆并识别老化过程的不同阶段，但不需要进行复杂的分析或比较。因此，该题目在选择题型中属于等级2的难度。" + }, + { + "idx": 497, + "question": "What are the intracrystalline substructures of martensitic transformation products in steel?", + "answer": "(3) Intracrystalline substructure: Lath martensite mainly consists of high-density dislocations (1 point); acicular martensite has high-density twins with some dislocations at the edges. (1 point)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体转变产物的晶内亚结构，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查马氏体转变产物的晶内亚结构的基本概念和分类，主要涉及记忆和理解高密度位错和孪晶等基本特征，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确区分和描述两种不同类型的马氏体（板条马氏体和针状马氏体）的亚结构特征。这要求考生不仅记住定义，还需要理解并能够描述这些亚结构的具体组成（如高密度位错和孪晶）。因此，该题目在选择题型中属于概念解释和描述的难度等级。" + }, + { + "idx": 498, + "question": "What are the main characteristics of martensitic transformation in steel?", + "answer": "(1) Transformation characteristics: $\\textcircled{1}$ Diffusionless, neither Fe nor C atoms diffuse. (2 points) $\\textcircled{2}$ Coherent shear, with habit plane and orientation relationship between the new phase and parent phase. (2 points) $\\textcircled{3}$ Non-isothermal nature. (1 point) $\\textcircled{4}$ Incompleteness of martensitic transformation. (1 point)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变的主要特征，答案以文字形式详细列出了多个特征点，需要论述和解释，符合简答题的特点。 | 知识层次: 题目考查马氏体相变的主要特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念点（扩散性、共格剪切、非等温性、不完全性），但每个概念点都是基础定义和描述性的内容，不需要进行复杂的比较分析或推导。学生只需准确记忆并识别马氏体转变的主要特征即可作答。因此，该题目在选择题型内属于等级2（概念解释和描述）难度。" + }, + { + "idx": 499, + "question": "What are the Burgers vector and dislocation properties of the generated dislocation?", + "answer": "The Burgers vector of the generated dislocation $\\widehat{b}_{3}$ is $a/2~[110]$, which is a pure edge dislocation. The slip plane (001) is not the slip plane of the face-centered cubic structure, so it is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述Burgers矢量和位错性质，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释Burgers矢量和位错性质，涉及位错类型和滑移面的分析，需要将多个概念关联起来进行综合判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要掌握Burgers矢量和位错性质的基本概念，还需要理解面心立方结构中的滑移面特性，并能综合分析位错类型（纯刃型位错）与滑移面的匹配关系。解题过程涉及多步概念关联和结构分析，超出了简单记忆或单一概念应用的范畴，属于需要多角度分析论述的中等应用层次题目。" + }, + { + "idx": 500, + "question": "What effect will this dislocation reaction have on the plastic deformation of the metal?", + "answer": "The dislocation reaction generates a sessile dislocation $\\pmb{a}/2$ [110], which will hinder the movement of dislocations on the (111) and (111) planes, resulting in significant strain hardening macroscopically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应对金属塑性变形的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错反应对金属塑性变形的影响，涉及到位错运动的阻碍机制和宏观应变硬化现象的解释。这需要综合运用位错理论、晶体塑性变形机制等多方面知识，并进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解位错反应的基本概念，还需要能够分析位错反应对金属塑性变形的影响机制。正确选项涉及到位错运动的阻碍作用及其宏观表现（应变硬化），这需要考生具备综合运用知识、推理分析和机理解释的能力。此外，题目还要求考生能够将微观的位错行为与宏观的力学性能变化联系起来，这种跨尺度的综合分析在选择题型中属于最复杂的考查形式。" + }, + { + "idx": 501, + "question": "What is the reason for age hardening?", + "answer": "Reason for age hardening: Dispersion precipitation of metastable phases, maintaining coherent or semi-coherent interfaces with the matrix phase, hindering dislocation movement in the matrix phase. 1) For deformable second-phase particles, dislocations cut through the second-phase particles, destroying the coherent or semi-coherent relationship between the second-phase particles and increasing the phase boundary area, while the second-phase particles themselves possess high strength. 2) For non-deformable second-phase particles, dislocations bypass the second-phase particles, leaving dislocation loops around them, increasing the dislocation line length and enhancing the resistance of the second-phase particles to subsequent dislocation movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释age hardening的原因，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释时效硬化的机理，涉及亚稳相的析出、与基体相的界面关系、位错运动受阻等复杂概念，需要综合运用材料科学中的相变、位错理论等知识进行深入分析和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解年龄硬化的复杂机理，包括亚稳相的弥散析出、与基体相的共格/半共格界面关系、位错运动的阻碍机制等核心概念。正确选项不仅需要区分可变形与不可变形第二相粒子的不同作用机制（位错切割 vs 位错绕过），还涉及位错环形成、相界面积变化等微观细节的机理解释。这种综合运用材料科学原理进行复杂现象分析的能力，远超选择题型对基础概念识别的常规要求，属于机理深度解释与复杂现象全面分析的综合考查。" + }, + { + "idx": 502, + "question": "Configuration of polymer chains", + "answer": "Configuration of polymer chains: The spatial geometric arrangement of atoms in polymers fixed by chemical bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Configuration of polymer chains\"进行文字解释和论述，答案提供了概念的定义和说明，符合简答题的特征 | 知识层次: 题目考查聚合物链构型的定义，属于基础概念的记忆和理解，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别聚合物链构型的定义，属于基础概念的直接回忆。题目没有涉及复杂的概念体系或需要多步骤的分析过程，因此属于最低难度等级。" + }, + { + "idx": 503, + "question": "How to overcome constitutional supercooling in single crystal growth?", + "answer": "To overcome constitutional supercooling, increase the temperature gradient and reduce the growth rate R.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何克服单晶生长中的组成过冷现象，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解constitutional supercooling的概念，并应用温度梯度和生长速率的关系来解决问题，涉及多步分析和概念关联。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及单晶生长中的成分过冷问题，要求考生掌握温度梯度和生长速率对成分过冷的影响，并能综合分析这两个因素的相互作用。虽然不需要多步计算，但需要对概念有较深的理解和关联分析能力。" + }, + { + "idx": 504, + "question": "What is constitutional supercooling? Explain its cause.", + "answer": "Due to the addition of a second component, the solidification point of the melt decreases at the solid-liquid interface, while the melt away from the interface maintains a higher melting point. Due to the presence of impurities, there is a distribution coefficient ko= Cs/CL at the solid-liquid interface, where the impurity concentration is higher than the average concentration C0. The concentration changes with distance as: CL=C0(1+(1-k0)/k0 e^(-R X/D)), where D is the diffusion coefficient, resulting in TL=Tm-mLC0(1+(1-k0)/k0 e^(-R X/D)). When the cooling rate of the melt is high, the liquid temperature falls below the solidification temperature, causing droplets to be surrounded by crystals and forming scattered particles. This phenomenon is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释\"constitutional supercooling\"的概念和原因，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和公式说明，符合简答题的特征。 | 知识层次: 题目要求解释成分过冷的定义及其原因，涉及多步推理和机理解释，包括溶质分布、扩散系数、冷却速率等复杂概念的关联和综合分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解并解释\"constitutional supercooling\"这一复杂现象，涉及多个专业概念（如分布系数、扩散系数、凝固点降低等）和数学表达式。正确选项不仅需要识别现象，还要全面分析其形成机理和影响因素，包括浓度梯度、温度梯度和冷却速率的相互作用。这种对复杂材料科学现象进行全面分析的题目，在选择题型中属于最具挑战性的类型，要求考生具备深厚的专业知识和综合分析能力。" + }, + { + "idx": 505, + "question": "Explain the reason why the dislocation $b_{1}=a/2\\\\big[10\\\\Bar{1}\\\\big]$ in the (111) plane of a face-centered cubic lattice metal and the dislocation $b_{2}=a/2[011]$ in the (111) plane can undergo a dislocation reaction.", + "answer": "The dislocation reaction $a/2{\\\\left[10{\\\\stackrel{\\\\leftarrow}{1}}\\\\right]}+a/2{\\\\left[011\\\\right]}\\\\rightarrow a/2{\\\\left[110\\\\right]}$ can occur for the following reasons: $\\\\textcircled{1}$ It satisfies the structural condition $\\\\vec{b}_{1}+\\\\vec{b}_{2}=\\\\vec{b}_{3}$. $\\\\textcircled{2}$ It satisfies the energy condition: $a^{2}/2+a^{2}/2>a^{2}/2_{\\\\circ}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释位错反应的原因，涉及位错矢量的结构条件和能量条件的综合分析，需要理解位错反应的基本原理并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 506, + "question": "Magnesium oxide and aluminum oxide (solute) form a substitutional solid solution, write the defect equation.", + "answer": "Defect equation: Al2O3→MgO 2AlMg· + VMg'' + 3OOc", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷方程，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目要求写出缺陷方程，需要理解固溶体的类型和缺陷化学的基本原理，并能够将铝氧化物在镁氧化物中的溶解过程转化为缺陷方程。这涉及到多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求写出缺陷方程，涉及对固溶体、缺陷类型和电荷平衡的综合理解。虽然题目给出了正确选项，但需要考生掌握相关概念并能正确应用，属于中等应用层次的知识要求。" + }, + { + "idx": 507, + "question": "Dislocation slip", + "answer": "Dislocation slip: Under a certain stress, the movement of dislocations where the dislocation line moves along the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation slip\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征 | 知识层次: 题目考查对位错滑移这一基本概念的定义和简单描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆和识别\"dislocation slip\"的基本定义，属于基础概念记忆层次。题目描述直接给出了定义，没有涉及复杂的概念体系或需要推理分析的步骤，因此属于最简单的难度等级。" + }, + { + "idx": 508, + "question": "Can magnesium oxide and aluminum oxide (solute) form a continuous solid solution? Explain the reason.", + "answer": "They cannot form a continuous solid solution due to different crystal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释镁氧化物和铝氧化物是否能形成连续固溶体，并说明原因。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解固溶体的形成条件，并分析两种氧化物的晶体结构差异对固溶体形成的影响，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道镁氧化物和铝氧化物的晶体结构不同，还需要理解这一差异如何影响它们形成连续固溶体的能力。这涉及到对晶体结构和固溶体形成条件的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 509, + "question": "Active oxygen", + "answer": "Active oxygen: oxygen in silicate structures with partially unsaturated valence.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Active oxygen\"进行文字解释和论述，答案提供了概念的定义和特征描述，符合简答题的特点 | 知识层次: 题目考查对\"活性氧\"这一基本概念的定义记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目仅考察对\"活性氧\"这一基础概念的定义记忆，属于最基础的知识点掌握要求。正确选项直接给出了定义，无需任何解释或分析步骤，符合选择题型中最简单的难度等级。" + }, + { + "idx": 510, + "question": "Homogeneous nucleation", + "answer": "Homogeneous nucleation: The formation of nuclei in a homogeneous phase relying on conditions such as its own structural fluctuations and energy fluctuations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Homogeneous nucleation\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即均相成核的定义和基本原理，不涉及复杂应用或综合分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"均相成核\"的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了定义性描述，不需要任何解释或分析过程，符合选择题型中最简单的难度等级标准。" + }, + { + "idx": 511, + "question": "Equilibrium distribution coefficient", + "answer": "Equilibrium distribution coefficient: The ratio of the solute concentration in the solid phase to that in the liquid phase during equilibrium solidification.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“Equilibrium distribution coefficient”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查的是平衡分配系数的定义，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅要求记忆并识别平衡分配系数的基本定义，属于基础概念记忆层次。题目直接给出了定义，无需进行额外的解释或复杂分析，因此属于最简单的难度等级。" + }, + { + "idx": 512, + "question": "What are the main influencing factors of constitutional supercooling?", + "answer": "The main influencing factors of constitutional supercooling include: melt cooling rate, impurity concentration C0, partition coefficient k0, diffusion coefficient D, growth rate R, and temperature gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述影响成分过冷的主要因素，答案提供了详细的文字解释和列举了多个影响因素，符合简答题的特征。 | 知识层次: 题目要求列举并解释影响成分过冷的主要因素，涉及多个参数的关联和综合分析，需要理解各因素之间的相互作用及其对成分过冷的影响机制，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目要求考生理解并综合多个概念（如冷却速率、杂质浓度、分配系数等）来分析影响成分过冷的主要因素。虽然不需要进行复杂的计算，但需要对材料科学中的基本概念有较深的理解和关联能力。" + }, + { + "idx": 513, + "question": "Uphill diffusion", + "answer": "Uphill diffusion: Under the condition of chemical potential difference as the driving force, atoms diffuse from low concentration positions to high concentration positions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Uphill diffusion\"进行文字解释和论述，答案提供了概念的定义和特征描述，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对Uphill diffusion这一基础概念的定义和基本原理的记忆和理解，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆（上坡扩散的定义），但需要考生理解化学势差作为驱动力的特殊条件，以及扩散方向与浓度梯度的反常关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 514, + "question": "Stored energy", + "answer": "Stored energy: A small portion of the energy consumed during cold deformation exists within the deformed crystal in the form of elastic strain energy and structural defect energy, which is called stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Stored energy\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查的是对\"stored energy\"这一基本概念的定义和解释，属于材料科学中基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅要求记忆和识别\"stored energy\"的基本定义，属于最基础的概念记忆层次。题目直接给出了定义性描述，不需要进行概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 515, + "question": "In face-centered cubic metals, can the dislocation b3 generated by the dislocation reaction b1 + b2 = b3 move on the slip plane?", + "answer": "The slip plane of face-centered cubic metals is {111}, and b3 is perpendicular to this crystal plane, so it cannot slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述为什么位错b3不能在滑移面上移动，答案提供了详细的晶体学分析和文字解释，符合简答题的特征。 | 知识层次: 题目涉及面心立方金属中位错反应生成的位错b3在滑移面上的运动能力，需要综合运用位错理论、晶体学知识以及滑移机制进行推理分析。解答不仅需要理解位错反应的基本原理，还需要分析位错b3与滑移面{111}的几何关系，判断其是否能够滑移。这属于对多个概念的深度理解和综合应用，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 516, + "question": "Pseudo-eutectoid", + "answer": "Pseudo-eutectoid: During non-equilibrium transformation, hypoeutectoid or hypereutectoid alloys near the eutectoid composition point form a completely eutectoid microstructure by the end of the transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对\"Pseudo-eutectoid\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目要求解释非平衡转变过程中的伪共析现象，涉及对相变机理的理解和特定条件下微观组织形成的分析，需要将基础概念与实际转变过程关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目涉及非平衡转变条件下的伪共析现象，需要考生理解并关联多个概念（如亚共析/过共析合金、共析成分点、完全共析组织等），并能综合分析非平衡转变对显微组织的影响。虽然不需要多步计算，但需要对相变原理有较深入的理解才能正确判断选项。" + }, + { + "idx": 517, + "question": "How do crystal structure and solid solution type affect atomic diffusion in crystalline solids?", + "answer": "In crystal structures with smaller packing density, the activation energy for diffusion is lower, making diffusion easier to occur; in crystal structures with lower symmetry, the anisotropy of the diffusion coefficient is more pronounced; the activation energy for diffusion in interstitial solid solutions is much smaller than that in substitutional solid solutions, facilitating easier diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体结构和固溶体类型如何影响原子扩散，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析晶体结构和固溶体类型对原子扩散的影响，涉及多个概念的关联和综合分析，需要理解扩散机制、晶体结构特性以及固溶体类型对扩散的影响，并进行推理和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 518, + "question": "Recrystallization", + "answer": "Recrystallization: The process in which deformed materials, upon heating, undergo the replacement of deformed grains by strain-free grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Recrystallization\"进行文字解释和论述，答案是一个定义性的陈述，符合简答题的特征。 | 知识层次: 题目考查对再结晶这一基础概念的定义记忆和理解，属于材料科学中的基本概念，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆再结晶的定义和基本原理，但不需要进行复杂的分析或比较。正确选项提供了明确的定义，属于基础概念记忆层次，符合等级2的标准。" + }, + { + "idx": 519, + "question": "How does temperature affect atomic diffusion in crystalline solids?", + "answer": "The higher the temperature, the greater the diffusion coefficient and the faster the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释温度对晶体固体中原子扩散的影响，需要文字解释和论述，而不是选择、判断或计算。答案也是以论述形式给出。 | 知识层次: 题目需要理解温度对原子扩散的影响机制，并关联扩散系数与温度的关系，属于中等应用层次的知识点。 | 难度: 在选择题中属于中等难度，需要理解温度与扩散系数之间的关系，并能综合分析温度对扩散速率的影响。虽然不涉及多步计算，但需要对概念进行关联和综合分析。" + }, + { + "idx": 520, + "question": "In face-centered cubic metals, what types of dislocations are b1 = [101], b2 = (a/6)[1̄2̄1], b3 = (a/3)[1̄1̄1̄] respectively?", + "answer": "b1: unit dislocation; b2: Shockley partial dislocation; b3: Frank partial dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求识别不同类型的位错，并给出相应的分类，这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别不同类型的位错，需要理解位错的基本概念（如单位位错、Shockley部分位错、Frank部分位错）以及它们在面心立方金属中的具体表现。这涉及多步分析和概念关联，而不仅仅是简单的记忆或直接应用。 | 难度: 在选择题中属于较高难度，需要综合理解面心立方金属中的位错类型，包括单位位错、Shockley部分位错和Frank部分位错的概念，并能正确区分它们的特征和表示方法。此外，题目要求将给定的位错矢量与相应的位错类型进行匹配，涉及多步计算和概念关联，需要较强的综合分析能力。" + }, + { + "idx": 522, + "question": "How do crystal defects affect atomic diffusion in crystalline solids?", + "answer": "The diffusion coefficient along grain boundaries is much greater than that of bulk diffusion; diffusion activation energy is smaller when occurring along dislocation pipes, thus dislocations accelerate diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体缺陷如何影响原子扩散，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释晶体缺陷如何影响原子扩散，涉及晶体缺陷（如晶界、位错）与扩散系数、扩散激活能之间的关联机制，需要综合运用材料科学中的扩散理论和缺陷理论进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶体缺陷（如晶界和位错管）对原子扩散的影响机制，还需要综合比较不同扩散路径（晶界扩散与体扩散）的扩散系数和激活能差异。正确选项涉及多个复杂概念的联动分析（扩散系数、激活能、位错加速效应），且需要机理层面的深度解释。这种题目在选择题型中属于需要全面分析复杂现象的典型高阶题目，远超单纯记忆或简单应用层次。" + }, + { + "idx": 524, + "question": "What changes occur in the microstructure of metals after plastic deformation?", + "answer": "After plastic deformation of metals, in terms of microstructure morphology, the originally equiaxed grains are elongated along the deformation direction. Under large deformation, grain boundaries may even appear fibrous. If hard and brittle second-phase particles or inclusions are present, they often distribute in a banded pattern along the deformation direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属在塑性变形后微观结构的变化，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目要求解释塑性变形后金属微观结构的变化，涉及变形方向对晶粒形态的影响、大变形下的纤维状晶界以及第二相粒子的带状分布等复杂现象。这需要综合运用塑性变形机制、晶粒取向和微观结构演变等知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 525, + "question": "What changes occur in the properties of metal after plastic deformation?", + "answer": "In terms of properties, cold-deformed metal will undergo work hardening, manifested as a significant increase in strength and a noticeable decrease in plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属在塑性变形后性质的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查金属塑性变形后性能变化的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述金属塑性变形后的具体性能变化（如加工硬化、强度增加和塑性下降），而不仅仅是简单的定义或分类。这要求考生对相关概念有一定的理解和应用能力，但不需要进行复杂的体系阐述或比较分析。" + }, + { + "idx": 526, + "question": "In face-centered cubic metals, can the dislocation reaction b1 + b2 = b3 proceed, where b1 = [101], b2 = (a/6)[1̄2̄1], b3 = (a/3)[1̄1̄1̄]?", + "answer": "Geometric condition: b1 + b2 = (a/2)[101̄] + (a/6)[1̄2̄1] = (a/3)[1̄1̄1̄], b3 = (a/3)[1̄1̄1̄], satisfying the geometric condition; Energy condition: after the reaction |b3|² = (a²/9) × (√(1+1+1))² = a²/3, before the reaction Σ|bi|² = (a²/4) × (√(1+0+1))² + (a²/36) × (√(1+4+1))² = 2a²/3 > after the reaction |b3|²; satisfying the energy condition, the reaction b1 + b2 → b3 can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述位错反应的几何条件和能量条件是否满足，答案通过文字和计算展示了详细的推导过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要多步计算和概念关联，包括几何条件和能量条件的验证，涉及位错反应的基本原理和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及面心立方金属中的位错反应，需要掌握位错的几何条件和能量条件。其次，解题过程需要进行多步计算，包括矢量相加和能量比较。此外，题目要求综合分析几何条件和能量条件，判断反应是否可以进行。这些步骤在选择题型中属于较为复杂的操作，需要较强的概念关联和综合分析能力。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 527, + "question": "2. The symmetry elements of the internal structure of a crystal are (3), (4), and (5) in addition to c, Pλ, Ln, and Lin.", + "answer": "(3) Translation axis; (4) Glide plane; (5) Screw axis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体内部结构的对称元素，答案需要文字描述和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查晶体内部结构对称元素的基本概念记忆，包括平移轴、滑移面和螺旋轴等基础定义和分类，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确识别并匹配晶体内部结构的对称元素（如平移轴、滑移面和螺旋轴）的具体名称。这要求考生不仅记住这些定义，还需要理解它们的分类和基本原理，而不仅仅是简单的定义复述。因此，相较于仅需基本定义简答的等级1题目，该题的难度稍高，属于等级2。" + }, + { + "idx": 528, + "question": "After plastic deformation of metal, what changes occur in its structure?", + "answer": "Microstructurally, the density of defects (vacancies and dislocations) significantly increases. Due to the multiplication of dislocations during deformation and the intersection and interaction of dislocations during movement, dislocation tangles form, and the annihilation of dislocations with opposite signs results in a cellular structure. As the deformation increases, the number of dislocation cells increases, their size decreases, and the stored energy within the crystal rises.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对金属塑性变形后的结构变化进行详细的文字解释和论述，答案提供了详细的微观结构变化描述，符合简答题的特征。 | 知识层次: 题目要求解释金属塑性变形后微观结构的变化，涉及缺陷密度增加、位错运动和相互作用、位错缠结和胞状结构的形成等复杂机理。这需要综合运用材料科学中的位错理论、晶体缺陷和变形机制等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解金属塑性变形的基本概念（如位错、空位等缺陷），还需要掌握变形过程中微观结构变化的复杂机理（如位错增殖、交互作用、位错缠结和胞状结构的形成）。此外，题目还涉及变形量增加对位错胞尺寸和储存能的影响，这需要考生具备综合分析和推理能力。在选择题型中，这种深度和复杂度的知识点掌握要求，以及解题时需要进行的多步逻辑推理，使其成为最具挑战性的题目类型。" + }, + { + "idx": 529, + "question": "1. Kaolinite belongs to the layered silicate structure, with one layer being (1) and another layer being (2).", + "answer": "(1) silicon-oxygen tetrahedral layer; (2) aluminum-oxygen octahedral layer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定术语（硅氧四面体层和铝氧八面体层），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查高岭石（Kaolinite）的层状硅酸盐结构的基本组成，即硅氧四面体层和铝氧八面体层的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即高岭石的层状硅酸盐结构由硅氧四面体层和铝氧八面体层组成。无需复杂推理或概念间的联系分析，属于最基本的知识点复现。" + }, + { + "idx": 530, + "question": "How does the third component affect atomic diffusion in crystalline solids?", + "answer": "Depending on the nature of the added third component, some promote diffusion while others hinder it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第三组分如何影响晶体固体中的原子扩散，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及第三组分对晶体固体中原子扩散的影响，需要综合运用扩散机制、组分相互作用等知识进行推理分析，解释不同组分对扩散的促进或阻碍作用，思维过程较为深入。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 531, + "question": "5. When Ca0 is doped into ZrO2, where Ca2+ ions replace Zr4+ ions, due to the requirement of electrical neutrality, this substitution simultaneously creates a (9) defect, which can be represented by the (10) defect reaction equation.", + "answer": "(9) vacancy; (10) CaO→ZrO2CaZr′′+V0..+ O0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求填写空缺部分并写出缺陷反应方程，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求理解掺杂过程中的电荷平衡原理，并写出缺陷反应方程，涉及多步概念关联和综合分析，需要将基础概念应用到具体情境中。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及掺杂缺陷的形成和电荷平衡，需要考生掌握离子取代对晶体结构的影响以及缺陷反应方程的书写。虽然题目提供了正确选项，但考生仍需具备一定的材料科学基础，能够将Ca2+取代Zr4+的电荷补偿机制与氧空位的形成联系起来，并正确理解缺陷反应方程的含义。这需要中等层次的应用能力，包括多步计算、概念关联和综合分析。" + }, + { + "idx": 532, + "question": "Explain why the strength of polycrystalline materials increases with decreasing grain size.", + "answer": "During plastic deformation of polycrystalline materials, coarse grains have a higher number of dislocations piled up at grain boundaries, creating a larger stress field that can activate dislocation sources in adjacent grains, allowing deformation to continue. In contrast, fine grains have fewer dislocations piled up at grain boundaries, requiring a greater external force to activate dislocation sources in adjacent grains for deformation to proceed. Therefore, finer-grained materials need a larger external force to undergo plastic deformation, meaning the strength of the crystal increases with decreasing grain size. (5 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶材料强度随晶粒尺寸减小而增加的原因，答案是通过文字解释和论述来回答的，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释多晶材料强度随晶粒尺寸减小而增加的机理，涉及位错理论、晶界作用以及塑性变形的微观过程。需要综合运用多个概念进行推理分析，思维过程较深，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解晶粒尺寸与材料强度的关系，还需要深入掌握位错堆积、应力场激活相邻晶粒位错源等复杂机理。正确选项涉及多步骤推理：从宏观晶粒尺寸差异→微观位错行为差异→应力场激活机制差异→最终宏观强度表现，需要综合运用材料科学原理进行因果链条分析。这种在选择题中要求完整解释复杂现象并建立跨尺度关联的题目，对知识整合和逻辑推理能力要求极高，远超一般选择题的认知负荷。" + }, + { + "idx": 533, + "question": "4. The term 'segment' is used to describe the (8) property of polymers.", + "answer": "(8) flexibility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个描述聚合物性质的术语（flexibility），需要根据知识进行简短的文字回答，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查对聚合物基本性质（segment与flexibility的关系）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对聚合物基本术语\"segment\"的定义记忆，属于最基础的概念性知识。正确选项\"flexibility\"直接对应术语的定义，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 534, + "question": "8. Methods to strengthen metal materials include (16) strengthening, (17) strengthening, (18) strengthening, (19) strengthening.", + "answer": "(16) solid solution; (17) dislocation; (18) fine grain; (19) dispersion (or precipitate particles)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的强化方法名称，需要文字回答而非选择或判断，且答案形式为简短的术语填空，符合简答题的特征。 | 知识层次: 题目考查金属材料强化方法的基本概念记忆，包括固溶强化、位错强化、细晶强化和弥散强化等基本原理的分类和名称，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个金属强化方法的基本概念记忆，但每个空格的正确选项都是材料科学中的基础术语（固溶强化、位错强化、细晶强化、弥散强化）。这些知识点属于定义性记忆范畴，不需要复杂的分析或概念间关系的理解。但由于需要同时回忆并区分四种不同强化机制，对基础概念掌握的完整性要求较高，因此略高于单纯的定义简答（等级1）。" + }, + { + "idx": 535, + "question": "Syndiotactic", + "answer": "Syndiotactic: A polymer in which the substituents are alternately attached to opposite sides of the main chain plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语进行文字解释和论述，没有提供选项或要求判断对错，也不需要数值计算 | 知识层次: 题目考查对\"Syndiotactic\"这一聚合物结构的基本定义和概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆，但需要考生准确理解并描述\"Syndiotactic\"的定义和特征，而不仅仅是简单的定义复述。题目要求考生能够解释聚合物中取代基的排列方式，这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 536, + "question": "What is the reason for age strengthening?", + "answer": "The reasons for age strengthening are as follows: First, when disc-shaped metastable phases precipitate and have a certain orientation relationship with the parent phase, large elastic strains are generated within the matrix, which can significantly strengthen the alloy. Second, when the alloy undergoes deformation, the interaction between dispersed particles and dislocations strengthens the alloy. If the precipitate particles are deformable, as dislocations cut through them, work is required to increase the surface area of the particles, thereby increasing the resistance to dislocation motion and strengthening the alloy. If the precipitate particles are strong and incoherent with the matrix, dislocation lines find it difficult to cut through the particles and will bypass them under applied stress, leaving dislocation loops. For the alloy to continue deforming, the stress exerted by the particles as dislocation lines bypass them must be overcome, requiring further increase in the applied stress, thus resulting in age strengthening of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释age strengthening的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释年龄强化的原因，涉及多个机理的综合分析，包括亚稳相析出、位错与析出相的相互作用、位错切割和绕过机制等。这些内容需要深入理解材料强化机制，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面理解并分析年龄强化的复杂机理，包括亚稳相析出、弹性应变、位错与析出粒子的相互作用等多个方面的知识。正确选项详细解释了不同情况下（如析出粒子可变形或不可变形）的强化机制，需要考生具备深入的材料科学知识和综合分析能力。这种题目不仅测试知识点的记忆，更强调对复杂现象的全面理解和推理分析能力，因此在选择题型中属于最难的一类。" + }, + { + "idx": 537, + "question": "Non-uniform nucleation", + "answer": "Non-uniform nucleation: The nucleation process during the cooling of a molten liquid that occurs on a certain interface within the parent phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Non-uniform nucleation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查非均匀形核的基本定义和过程描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求识别或回忆\"Non-uniform nucleation\"的基本定义，属于基础概念记忆层次。题目直接给出了正确选项的定义，没有涉及复杂的概念体系或需要多步骤分析，因此属于最简单的难度等级1。" + }, + { + "idx": 538, + "question": "7. Small-angle grain boundaries are composed of dislocations, among which symmetric tilt boundaries are composed of (14) dislocations, and twist boundaries are composed of (15) dislocations.", + "answer": "(14) edge; (15) screw", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定类型的位错名称（刃型位错和螺型位错），属于需要准确回答特定术语的简答题形式。虽然形式上类似填空题，但根据提供的题型选项，最接近的是简答题类型。 | 知识层次: 题目考查对小角度晶界和位错类型的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接考察对对称倾斜晶界和扭转晶界组成位错类型的基础记忆，无需复杂推理或概念比较。正确选项直接对应基础概念记忆，属于最基础的选择题难度。" + }, + { + "idx": 539, + "question": "Polymorph", + "answer": "Polymorph: Crystals of the same chemical composition that form different structures under varying thermodynamic conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Polymorph\"进行文字解释和论述，答案是一个定义性的陈述，符合简答题的特征。 | 知识层次: 题目考查对多晶型（Polymorph）这一基础概念的定义和基本特征的理解，属于材料科学中晶体结构的基础知识，主要依赖记忆和简单理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆（多晶型的定义），但需要考生准确理解并区分\"相同化学成分但不同晶体结构\"这一关键特征。相比简单定义复述（等级1），该选项要求对概念进行一定程度的解释和描述，但不需要涉及复杂的概念体系或比较分析（等级3）。在选择题型内，这属于典型的\"概念解释\"难度层级。" + }, + { + "idx": 540, + "question": "9.Linear polymers can be reused, also known as (20); cross-linked polymers cannot be reused and are called thermosetting plastics.", + "answer": "(20) Thermoplastic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语（Thermoplastic）来补全句子，属于需要文字回答的简答题类型，而非从多个选项中选择或判断对错。 | 知识层次: 题目考查对线性聚合物和交联聚合物基本分类的记忆，以及热塑性和热固性塑料这两个基础概念的理解。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接考察对线性聚合物和交联聚合物的基本分类记忆，仅需识别\"Thermoplastic\"这一术语即可作答，无需进行概念解释或复杂分析。正确选项与题干中的关键提示词\"reused\"直接对应，属于最基础的概念记忆层次。" + }, + { + "idx": 541, + "question": "Deformation texture", + "answer": "Deformation texture: As the amount of plastic deformation increases, the phenomenon where a certain crystallographic orientation of the deformed polycrystal tends to become consistent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Deformation texture\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"Deformation texture\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及应用或分析层面的要求。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"Deformation texture\"的定义和基本原理，但不需要进行复杂的概念体系阐述或多概念比较分析。虽然需要掌握一定的专业术语和基本概念，但整体上仍属于中等偏下的难度水平。" + }, + { + "idx": 542, + "question": "Peritectic transformation", + "answer": "Peritectic transformation: At a certain temperature, a liquid phase with a specific composition interacts with a solid phase of a specific composition to form a new solid phase with another specific composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Peritectic transformation\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征 | 知识层次: 题目考查对包晶转变（Peritectic transformation）这一基本概念的定义和描述，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生准确理解并描述包晶转变的定义和过程，涉及液相与固相在特定条件下的相互作用以及新固相的形成。这比单纯记忆基本定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 543, + "question": "Pearlite", + "answer": "Pearlite: The product of eutectoid transformation in iron-carbon alloys, it is a lamellar mixture of eutectoid ferrite and eutectoid cementite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Pearlite\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对珠光体（Pearlite）这一基本概念的记忆和理解，要求回答其定义和组成，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（珠光体的定义），但正确选项提供了较为详细的描述（包括组成相和形成过程），这比单纯记忆基本定义（等级1）要求更高。学生需要理解并区分\"eutectoid ferrite\"和\"eutectoid cementite\"等术语，但不需要进行复杂的体系阐述或分析（等级3）。" + }, + { + "idx": 544, + "question": "3. In a ternary phase diagram, the eutectic point is (6) phase equilibrium, and the degree of freedom is (7).", + "answer": "(6) four; (7) 0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的答案（如“four”和“0”），而不是从多个选项中选择或进行判断。虽然答案简短，但属于填空题或简答题的范畴，需要根据知识直接回答。 | 知识层次: 题目考查对三元相图中共晶点的相平衡和自由度等基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即三元相图中共晶点的相平衡数量和自由度数值。题目直接给出了正确选项，无需复杂推理或概念间的联系分析，属于最基础的定义简答类型。" + }, + { + "idx": 545, + "question": "Li Sheng", + "answer": "Li Sheng: The uniform shear process in which one part of a crystal moves relative to another along specific crystallographic planes and directions under the action of shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Li Sheng\"进行解释和论述，答案提供了详细的文字描述，符合简答题的特征 | 知识层次: 题目考查对Li Sheng（李生）这一基本概念的定义记忆和理解，属于材料科学中晶体变形的基础知识，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆Li Sheng的定义，属于基础概念记忆层次。题目直接给出了正确选项的定义，无需进行复杂的分析或推理，仅需识别和匹配定义即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 546, + "question": "2. In face-centered cubic packing, the number of atoms in the unit cell is (5), it has (6) _ tetrahedral voids, (7) _ octahedral voids.", + "answer": "(5) 4; (6) 8; (7) 4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程，属于简答题类型。 | 知识层次: 题目考查面心立方堆积中原子数、四面体空隙和八面体空隙的基本概念记忆，属于晶体结构的基础知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察面心立方堆积中原子数、四面体空隙和八面体空隙的数量，这些都是晶体学中最基础的定义性知识，无需复杂推理或概念关联。学生只需记忆单位细胞内原子数（4）、四面体空隙数（8）和八面体空隙数（4）这三个固定数值即可作答，属于纯记忆性知识点。选择题型中此类仅需机械回忆的题目通常列为最低难度等级。" + }, + { + "idx": 547, + "question": "Spinodal decomposition", + "answer": "Spinodal decomposition: A transformation in which a solid solution decomposes into two solid solutions with the same structure as the parent phase but different compositions through uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Spinodal decomposition进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对Spinodal decomposition这一基本概念的定义和特征的理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆Spinodal decomposition的定义和基本原理，包括其特点（如固溶体分解为两个相同结构但不同成分的固溶体）和机制（上坡扩散）。虽然需要一定的记忆和理解，但不需要复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 549, + "question": "Aging", + "answer": "Aging: The subsequent process of solute atom precipitation from a supersaturated solid solution at room temperature or above.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Aging\"这一概念进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征 | 知识层次: 题目考查对\"Aging\"这一基础概念的定义记忆和理解，属于材料科学中的基本原理和定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"Aging\"的基本定义，属于最基础的概念记忆层次。题目直接给出了明确的定义描述，无需进行概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。选择题型中此类题目通常作为基础题出现，主要测试学生对专业术语的识记能力。" + }, + { + "idx": 550, + "question": "1. Crystals can be classified into (1) crystal families, (2) crystal systems according to symmetry, with a total of (3) point groups and (4) space groups.", + "answer": "(1) 3; (2) 7; (3) 32; (4) 230", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值答案，而不是从给定的选项中选择。虽然答案简短，但需要基于对晶体分类系统的理解来回答，属于简答题的范畴。 | 知识层次: 题目考查晶体分类、对称性和点群/空间群数量的基础概念记忆，属于材料科学中最基本的晶体学知识，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆晶体学中的基本分类数字（3个晶族、7个晶系、32个点群、230个空间群）。题目不涉及概念解释或复杂体系分析，仅测试对关键数字的记忆准确性，因此属于最低难度等级。" + }, + { + "idx": 551, + "question": "6. The driving force for nucleation in solid-state phase transformation is (11), and the main resistances are (12) and (13).", + "answer": "(11) The difference in free energy between the new phase and the parent phase; (12) Interface energy; (13) Strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分的内容，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查固态相变中成核的驱动力和主要阻力的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。虽然题目涉及多个概念（自由能差、界面能、应变能），但每个概念都是固态相变中的基础概念，且题目明确给出了正确选项，不需要进行复杂的比较分析。主要考察的是对基本概念的记忆和理解，属于中等偏下的难度水平。" + }, + { + "idx": 553, + "question": "3. The three crystal zones of an ingot refer to (8), (9), and (10).", + "answer": "(8) surface fine grain zone; (9) columnar crystal zone; (10) central equiaxed coarse grain zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的晶体区域名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对铸锭三个晶区的基本概念的记忆，属于定义和分类的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆和识别铸锭的三个晶区名称，属于基础概念记忆的简单题目。不需要解释或分析，只需直接回忆并匹配正确选项即可。" + }, + { + "idx": 554, + "question": "5.After recrystallization is completed, grain growth can be divided into (14) grain growth and (15) grain growth.", + "answer": "(14) normal; (15) abnormal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个特定的术语（normal和abnormal）来补充句子，属于需要简短文字回答的题目类型。虽然形式类似于填空题，但在给定的题型选项中最接近的是简答题（short_answer）。 | 知识层次: 题目考查的是对再结晶完成后晶粒生长类型的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求考生记忆并区分两种晶粒生长的类型（正常晶粒生长和异常晶粒生长），不需要进行概念解释或复杂分析。知识点掌握深度要求较低，解题步骤简单，属于最基础的概念记忆题。" + }, + { + "idx": 555, + "question": "7.During martensitic transformation, the new phase often begins to form on a specific crystallographic plane of the parent phase, which is called (20).", + "answer": "(20) habit plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（habit plane）作为答案，属于需要简短文字回答的题目类型 | 知识层次: 题目考查马氏体相变中基本概念\"惯习面\"的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即马氏体相变中特定晶面的名称（habit plane）。题目直接给出定义性知识，无需解释或复杂分析，属于最基本难度的选择题。" + }, + { + "idx": 556, + "question": "Given: When the grain size of annealed pure iron is 16 per $\\mathbf{\\chi}_{\\mathbf{m}\\mathbf{m}^{2}}$, the yield strength $\\sigma_{\\mathsf{s}}=100\\mathrm{N/\\Omega}$ $\\mathbf{m}\\mathbf{m}^{2}$; when the grain size is 4096 per $\\prime_{\\mathbf{m}\\mathbf{m}^{2}}$, $\\sigma_{\\mathrm{s}}=250\\mathrm{N}/\\mathrm{mm}^{2}$. Find the value of yield strength $\\pmb{\\sigma_{\\S}}$ when the grain size is 256 per $\\mathbf{m}\\mathbf{m}^{2}$.", + "answer": "According to the Hall-Petch formula: $\\sigma_{\\mathrm{s}}=\\sigma_{0}+K_{\\mathrm{y}}d^{-1/2}$, the yield strength $\\sigma_{\\mathbf{s}}$ of the material is calculated from the average grain size $^d$. Expressing the grain size in terms of the radius of an equal-area circle: $$d_{1}=(4A_{1}/\\pi)^{1/2}d_{2}=(4A_{2}/\\pi)^{1/2}$$$A_{1}$ and $A_{2}$ are the grain areas. Thus, $$\\sigma_{\\mathrm{s1}}=\\sigma_{0}+K_{\\mathrm{y}}d_{1}^{-1/2}\\sigma_{\\mathrm{s2}}=\\sigma_{0}+K_{\\mathrm{y}}d_{2}^{-1/2}$$Given that $A_{1}=1/16\\mathrm{mm}^{2}$, $A_{2}=1/4096\\mathrm{mm}^{2}$, $\\sigma_{\\mathrm{s}1}=100\\mathrm{N/mm}^{2}$, $\\sigma_{\\mathrm{s}2}=250\\mathrm{N}/\\mathrm{mm}^{2}$, substituting into the above equations yields $K_{\\mathrm{y}}=25{\\sqrt{2}}\\pi^{-1/4}\\mathrm{N}/\\mathrm{mm}^{3/2}$, $\\pmb{\\sigma_{0}}=50\\mathbf{N}/\\mathbf{m}\\mathbf{m}^{2}$. Then, with $A_{3}=1/256\\mathrm{mm}^{2}$, we find $\\sigma_{\\mathbf{s}3}=150\\mathbf{N}/\\mathbf{m}\\mathbf{m}^{2}$. (10 points)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（Hall-Petch公式）进行数值计算，最终得出一个具体的数值结果（yield strength的值）。解答过程涉及公式应用和代数运算，符合计算题的特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值代入和求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和单位转换。虽然题目提供了部分已知条件，但仍需进行综合分析才能得出最终答案。" + }, + { + "idx": 558, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of temperature.", + "answer": "Temperature. The higher the temperature, the greater the diffusion coefficient and the faster the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释影响原子扩散的因素并简要说明温度的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查原子扩散影响因素的基础概念记忆，特别是温度对扩散系数和扩散速率影响的基本原理理解，属于基础概念记忆和理解范畴。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆和识别影响原子扩散的因素（温度）及其基本影响（温度升高导致扩散系数增大和扩散速率加快）。不需要进行复杂的概念解释或体系阐述，解题步骤简单直接，仅需基础概念的记忆即可正确回答。" + }, + { + "idx": 559, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of the third component.", + "answer": "The third component. Depending on the nature of the added third component, some promote diffusion while others hinder it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响原子扩散的因素，并简要说明第三组分的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求列举影响原子扩散的因素（基础概念），还需要解释第三组元的具体影响（概念关联和综合分析），涉及多因素相互作用的理解和解释。 | 难度: 在选择题中属于中等难度，需要理解原子扩散的基本概念以及第三组分对扩散的影响，并进行综合分析。题目要求考生不仅知道第三组分的存在会影响扩散，还需要理解其可能促进或阻碍扩散的双重作用，这涉及对材料科学中扩散机制的较深入理解。" + }, + { + "idx": 560, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of crystal defects.", + "answer": "Crystal defects. The diffusion coefficient along grain boundaries is much larger than that of bulk diffusion; the activation energy for diffusion along dislocation pipes is smaller, thus dislocations accelerate diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响原子扩散的因素，并简要说明晶体缺陷的影响。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响原子扩散的因素，并具体分析晶体缺陷的影响。这需要理解扩散的基本原理，并将这些原理与晶体缺陷的特性关联起来，进行综合分析。虽然不涉及复杂计算，但需要多步概念关联和一定程度的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解晶体缺陷对原子扩散的影响，并能够比较不同缺陷类型（如晶界和位错）对扩散系数和活化能的具体影响。虽然题目涉及多个概念的综合分析，但在选择题型中，正确选项已经提供了明确的比较和结论，降低了答题的复杂性。" + }, + { + "idx": 561, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of crystal structure and solid solution type.", + "answer": "Crystal structure and solid solution type. In crystal structures with smaller packing density, the diffusion activation energy is lower, making diffusion easier to occur; in crystal structures with lower symmetry, the anisotropy of the diffusion coefficient is significant; the diffusion activation energy in interstitial solid solutions is much smaller than that in substitutional solid solutions, facilitating easier diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响原子扩散的因素，并简要说明晶体结构和固溶体类型的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响原子扩散的因素，并具体分析晶体结构和固溶体类型的影响。这需要理解扩散的基本原理，并将这些原理与具体的材料特性（如晶体结构对称性、固溶体类型）联系起来进行分析。虽然不涉及复杂的计算或创新设计，但需要多步的概念关联和综合分析，超出了简单记忆或直接套用的层次。 | 难度: 在选择题型中，该题目要求考生不仅理解原子扩散的基本概念，还需要综合分析晶体结构和固溶体类型对扩散的影响。题目涉及多个知识点的关联，包括晶体结构的对称性、堆积密度以及不同类型固溶体的扩散激活能差异。此外，解题过程需要考生进行多角度分析，比较不同条件下的扩散行为，这超出了简单的记忆或单一概念的应用，属于较高层次的综合分析能力要求。因此，在选择题型内属于较高难度等级。" + }, + { + "idx": 562, + "question": "Analyze the changes in vacancies and dislocations in deformed metals during the recrystallization stage and their effects on properties.", + "answer": "Recrystallization stage: With the rearrangement of atoms during recrystallization, the dislocation density significantly decreases, the complex dislocation interactions generated during deformation disappear, the work hardening phenomenon vanishes, and the various properties of the deformed metal return to their pre-deformation state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析变形金属在再结晶阶段的空位和位错变化及其对性能的影响，需要详细的文字解释和论述。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析变形金属在再结晶阶段空位和位错的变化及其对性能的影响，需要综合运用材料科学中的变形、再结晶、位错理论等知识，进行推理分析和机理解释。这涉及到多个知识点的关联和深入理解，思维过程要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解金属再结晶阶段的微观机制，包括空位和位错的变化及其对性能的影响。正确选项不仅涉及多个复杂概念（如位错密度、加工硬化现象），还需要综合推理分析这些变化如何导致性能恢复。这种题目要求考生具备机理深度解释和复杂现象全面分析的能力，远超简单记忆或基础理解层面。" + }, + { + "idx": 563, + "question": "Briefly explain the disadvantages brought by the work hardening phenomenon", + "answer": "Disadvantages brought by the work hardening phenomenon: causes difficulty in plastic deformation. (3 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释工作硬化现象带来的缺点，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对work hardening现象带来的劣势的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆工作硬化现象的一个基本缺点（导致塑性变形困难），属于基础概念记忆层次，无需解释或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 564, + "question": "Analyze the changes of vacancies and dislocations in deformed metals during the recovery stage and their effects on properties.", + "answer": "Recovery stage: The vacancy concentration decreases to approach the equilibrium concentration, leading to a reduction in resistivity and an increase in crystal density. The mutual annihilation of dislocations with opposite signs on the same slip plane causes a slight decrease in dislocation density. During high-temperature recovery, edge dislocations undergo polygonization through slip and climb movements, resulting in the retention of work hardening. The strength and hardness slightly decrease, while residual stresses are essentially eliminated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析变形金属在回复阶段空位和位错的变化及其对性能的影响，需要详细的文字解释和论述，答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求分析变形金属在回复阶段空位和位错的变化及其对性能的影响，涉及多个概念的关联和机理解释，需要综合运用材料科学知识进行推理分析，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 565, + "question": "How to eliminate work hardening phenomenon", + "answer": "Subsequent recrystallization treatment is adopted to eliminate work hardening phenomenon. (3 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何消除加工硬化现象，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对消除加工硬化现象的基本方法的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的简单记忆，只需识别\"recrystallization treatment\"是消除加工硬化现象的正确方法即可。题目不涉及概念解释或复杂体系阐述，属于最基本的知识点回忆型题目。" + }, + { + "idx": 566, + "question": "Briefly explain the benefits brought by the work hardening phenomenon", + "answer": "The benefits brought by the work hardening phenomenon: During the deformation process, the dislocation density increases, and interactions between dislocations occur (such as dislocation intersection, dislocation entanglement, etc.), leading to dislocation pile-up, thereby strengthening the metal material. It also makes the deformation of the metal material more uniform. (4 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释加工硬化现象带来的好处，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对加工硬化现象的基本原理和作用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求简要解释加工硬化现象带来的好处，正确选项涵盖了加工硬化过程中位错密度增加、位错相互作用以及金属材料强化和均匀变形等关键概念。虽然需要理解多个相关概念，但题目并未要求深入分析或比较不同概念，因此属于中等难度。" + }, + { + "idx": 567, + "question": "Given the diffusion constant of carbon in γ-Fe D0=2.0×10^-5m^2/s and the activation energy for diffusion Q=140×10^3J/mol, calculate the diffusion coefficient of carbon in γ-Fe at 927℃.", + "answer": "The diffusion coefficient of carbon in γ-Fe at 927℃: 15.99×10^-12m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散常数和活化能计算碳在γ-Fe中的扩散系数，需要使用公式进行数值计算，答案也是一个具体的数值结果。 | 知识层次: 题目考查基本公式（阿伦尼乌斯方程）的直接应用和简单计算，不需要多步推理或综合分析 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要套用阿伦尼乌斯公式进行扩散系数的计算，但题目已经提供了所有必要的参数（D0、Q、温度），且计算过程仅涉及单一公式的直接套用和简单数学运算。不需要多个公式组合或复杂推导，因此属于等级2难度。" + }, + { + "idx": 568, + "question": "Given the diffusion constant of carbon in γ-Fe D0=2.0×10^-5m^2/s and the diffusion activation energy Q=140×10^3J/mol, calculate the diffusion coefficient of carbon in γ-Fe at 870℃.", + "answer": "The diffusion coefficient of carbon in γ-Fe at 870℃: 7.94×10^-12m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散常数和扩散激活能，应用阿伦尼乌斯公式计算特定温度下的扩散系数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及基本公式的套用和单位转换，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用阿伦尼乌斯公式（D = D0 * exp(-Q/RT)），但计算步骤相对直接，仅涉及温度转换（℃转K）和简单的指数运算。不需要多个公式组合或复杂推导，符合等级2的标准。" + }, + { + "idx": 569, + "question": "In a face-centered cubic crystal, a dislocation with Burgers vector b1= [101] meets a dislocation with b2= [121]. Can a dislocation reaction occur to form b3? Write the equation.", + "answer": "Geometric condition: b3=b1+b2= a/2[101]+a/6[121]=a/6[222]=a/3[111]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释是否会发生位错反应并写出反应方程，需要文字解释和论述，答案也以文字和方程形式呈现。 | 知识层次: 题目涉及位错反应的计算和几何条件的应用，需要理解位错Burgers向量的概念，并能进行向量运算和简化。虽然计算步骤不多，但需要将多个概念关联起来，并进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解位错反应的基本概念，掌握Burgers矢量的计算方法，并能进行多步矢量运算和综合分析。虽然题目涉及的知识点较为专业，但在选择题型中，通过给定的正确选项可以辅助验证计算过程，降低了部分难度。" + }, + { + "idx": 570, + "question": "Given the diffusion constant of carbon in γ-Fe D0=2.0×10^-5m^2/s and the activation energy for diffusion Q=140×10^3J/mol, how long is required to achieve the same carburizing thickness at 870°C as that obtained by carburizing for 10 hours at 927°C? (Ignore the difference in solubility of carbon in γ-Fe at different temperatures)", + "answer": "20.12 hours are required.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（扩散方程）来求解达到相同渗碳厚度所需的时间，答案是一个具体的数值结果（20.12 hours）。 | 知识层次: 题目需要进行多步计算，包括应用扩散公式（Arrhenius方程）计算不同温度下的扩散系数，然后根据扩散厚度与时间的平方根关系进行时间换算。这需要理解扩散机制和温度对扩散系数的影响，并进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解扩散常数、活化能、温度对扩散速率的影响等多个概念，并进行多步计算和综合分析。虽然题目提供了必要的参数，但解题过程涉及Arrhenius方程的应用、温度转换、时间计算等多个步骤，要求考生具备较强的综合计算能力和概念关联能力。" + }, + { + "idx": 571, + "question": "When $\\\\mathrm{Yb}\\\\mathrm{F}_{3}$ and $\\\\mathbf{NaF}$ are doped into $\\\\mathbf{CaF}_{2}$ crystals, if both ytterbium ions and sodium ions replace the cation positions, please write the defect reaction equation.", + "answer": "$\\\\mathrm{YbF}_{3}+\\\\mathrm{NaF}\\\\xrightarrow{\\\\mathrm{CaF}_{2}}\\\\mathrm{Yb}_{\\\\mathrm{Ca}}^{*}+\\\\mathrm{Na}_{\\\\mathrm{Ca}}^{\\\\prime}+4\\\\mathrm{F}_{\\\\mathrm{Fc}}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字解释和论述，答案形式为化学方程式，属于简答题类型 | 知识层次: 题目要求写出缺陷反应方程，需要理解掺杂过程中离子的取代位置和电荷平衡，涉及多步概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握缺陷化学的基本概念，能够正确写出掺杂反应的缺陷反应方程。虽然题目给出了掺杂物质和基体，但需要考生理解Yb和Na在CaF2中的取代位置，并正确写出缺陷反应方程，包括缺陷符号和电荷平衡。这需要一定的综合分析能力和对缺陷化学知识的掌握。" + }, + { + "idx": 572, + "question": "In a face-centered cubic crystal, indicate which types of dislocations b1, b2, and b3 belong to respectively", + "answer": "b1 is a perfect dislocation, b2 is a Shockley partial dislocation, and b3 is a Frank partial dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型的位错进行分类和说明，需要文字解释和论述，而不是选择、判断或计算。答案也是以文字描述的形式给出，符合简答题的特征。 | 知识层次: 题目要求识别不同类型的位错（完美位错、Shockley部分位错、Frank部分位错），这需要理解位错的基本概念及其在面心立方晶体中的具体表现。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握面心立方晶体中不同类型位错的基本概念，还需要能够区分完美位错、肖克利部分位错和弗兰克部分位错的特征。此外，题目涉及多步分析和概念关联，需要考生具备较强的综合分析能力。在选择题型内，这种需要深度理解和多角度分析的题目相对较少，因此难度较高。" + }, + { + "idx": 573, + "question": "How do dislocations strengthen metallic materials?", + "answer": "Dislocations can strengthen metallic materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错如何强化金属材料，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释位错如何强化金属材料，这需要深入理解位错与材料强度之间的机理关系，涉及位错运动、相互作用及其对材料力学性能的影响等多方面的综合分析。这超出了简单记忆或基本应用的范围，属于需要推理分析和机理解释的复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解位错的基本概念，还需要综合运用材料强化机理的知识，进行复杂现象的全面分析。正确选项虽然简洁，但背后隐含了对位错强化机制（如加工硬化、固溶强化、沉淀强化等）的深入理解，以及这些机制如何共同影响金属材料的强度。这种题目在选择题型中属于需要高阶思维和综合分析的难度水平。" + }, + { + "idx": 574, + "question": "Give two applications of solidification theory in the crystallization of metallic materials, and briefly explain them", + "answer": "Single crystal preparation. Using directional solidification technology to control the heat flow direction, enabling the metal to grow along a single crystal orientation, resulting in single crystals without grain boundaries, which are used in critical components such as high-temperature alloy blades.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出两个应用并简要解释，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求给出两个应用实例并简要解释，涉及对凝固理论的理解和应用，需要将理论与实际应用场景关联起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道固结理论的应用，还需要具体解释单晶制备的过程及其在高性能合金中的应用。这涉及到对固结理论的理解、定向凝固技术的掌握以及实际应用场景的关联，属于中等应用层次的知识要求。" + }, + { + "idx": 575, + "question": "Give one application of solidification theory in the crystallization of metallic materials, and briefly explain it", + "answer": "Ingot structure control. By controlling the cooling rate and temperature gradient during solidification, the grain size and distribution of the ingot can be adjusted, thereby improving the mechanical properties of the metallic material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个应用实例并进行简要解释，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求给出一个凝固理论在金属材料结晶中的应用实例，并简要解释。这需要将凝固理论的基本原理应用到具体场景中，属于直接套用理论解释实际问题的简单应用层次。虽然涉及理论的应用，但不需要多步计算或综合分析，思维深度要求不高。 | 难度: 在选择题中属于中等难度，需要理解固体化理论的基本概念，并能将其应用于金属材料的结晶过程。题目要求选择一个具体的应用实例（铸锭结构控制），并简要解释其原理（通过控制冷却速率和温度梯度来调整晶粒尺寸和分布）。这需要考生不仅记住知识点，还能进行简单的应用分析，但不需要复杂的计算或深入的理论推导。" + }, + { + "idx": 576, + "question": "Give three applications of solidification theory in the crystallization of metallic materials, and provide a brief explanation for each", + "answer": "Amorphous material preparation. By extremely rapid cooling (on the order of 10^6 K/s), the metal melt skips the crystallization stage and directly forms an amorphous structure, obtaining high-strength, corrosion-resistant amorphous alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举三个应用并简要解释每个应用，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求列举并简要解释凝固理论在金属材料结晶中的三个应用，这需要理解凝固理论的基本原理，并将其与实际应用场景关联起来。虽然不涉及复杂的计算或深度分析，但需要综合运用知识进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道固态化理论的基本概念，还需要理解其在金属材料结晶中的具体应用，并能简要解释每个应用。这涉及到对固态化理论、结晶过程以及材料性能之间关系的综合分析。虽然题目提供了正确选项，但考生仍需具备一定的知识深度和综合分析能力才能准确回答。" + }, + { + "idx": 577, + "question": "In a face-centered cubic crystal, a dislocation with Burgers vector b1= [101] meets a dislocation with b2= [121]. Explain the reason whether the dislocation reaction can occur.", + "answer": "Energy condition: b1^2+b2^2= (a^2/4)(1+0+1)+(a^2/36)(1+4+1)=a^2/2+a^2/6=2a^2/3, b3^2= (a^2/9)(1+1+1)=a^2/3, b3^2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构的密排方向，答案是一个特定的晶体学方向<110>，不需要计算或选择，属于需要特定知识点的简短回答 | 知识层次: 题目考查对FCC结构密排方向的基本概念记忆，属于晶体学基础知识的直接回忆，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即FCC结构的密排方向。题目仅要求考生回忆并选择正确的密排方向<110>，无需解释或分析。这种类型的题目属于最基本的知识点考察，解题步骤简单，相对难度较低。" + }, + { + "idx": 592, + "question": "Explain the term: grain boundary segregation", + "answer": "Grain boundary segregation: The enrichment phenomenon of solute atoms or impurity atoms at grain boundaries due to the difference in distortion energy between the grain interior and the grain boundaries or the presence of vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"grain boundary segregation\"，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对晶界偏析这一基础概念的定义和基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释\"grain boundary segregation\"这一概念，但正确选项已经提供了较为完整的定义和基本原理说明。学生需要理解并记忆晶界偏析的定义、成因（晶内与晶界畸变能差异或空位存在）以及表现形式（溶质原子或杂质原子在晶界的富集现象），这超出了简单定义记忆的要求，但尚未达到需要阐述复杂概念体系的难度。" + }, + { + "idx": 593, + "question": "The packing density of FCC structure is", + "answer": "0.74", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算FCC结构的堆积密度，需要应用相关公式进行数值计算，最终答案为具体数值0.74。 | 知识层次: 题目考查对FCC结构堆积密度的基本公式应用和简单计算，属于直接套用公式就能得出结果的简单应用层次。 | 难度: 在选择题型中，该题目仅需直接应用FCC结构的堆积密度公式（0.74），无需任何额外计算或推导。属于单一公式直接应用的简单题目，符合等级1的定义。" + }, + { + "idx": 594, + "question": "The stacking sequence of the close-packed planes in an FCC structure is", + "answer": "ABCABC…", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述FCC结构中密排面的堆垛顺序，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对FCC结构密排面堆垛顺序的基础概念记忆，属于晶体结构中最基本的知识点之一，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察对FCC结构密排面堆垛顺序的基础记忆，属于最基础的定义性知识。题目仅要求识别正确选项\"ABCABC...\"，无需解释或分析，解题步骤极为简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 595, + "question": "In the FCC structure, when atoms are regarded as rigid spheres with radius r, the relationship between the atomic radius and the lattice constant a is", + "answer": "r=a", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释FCC结构中原子半径与晶格常数之间的关系，答案需要文字说明而非选择或计算 | 知识层次: 题目考查FCC结构中原子半径与晶格常数关系的基本概念记忆，属于晶体学基础知识的直接应用，无需复杂计算或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即FCC结构中原子半径与晶格常数的简单关系。正确选项直接给出了公式r=a，无需复杂推理或计算，属于基本定义简答的难度等级。" + }, + { + "idx": 596, + "question": "The number of atoms in the unit cell of an FCC structure is", + "answer": "4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构中单位晶胞的原子数，答案是一个具体的数值（4），不需要计算或选择，属于直接回答的简答题类型。 | 知识层次: 题目考查对FCC结构单元晶胞中原子数目的基本概念记忆，属于晶体结构的基础知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目仅考察对FCC结构基本定义的记忆，无需解释或分析，属于最基础的概念记忆题。" + }, + { + "idx": 597, + "question": "The necessary condition for forming an ordered solid solution is", + "answer": "Slow cooling rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释形成有序固溶体的必要条件，需要文字解释和论述，而不是从选项中选择或简单判断对错。答案\"Slow cooling rate\"是一个简短的文字解释，符合简答题的特征。 | 知识层次: 题目考查形成有序固溶体的基本条件，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，涉及有序固溶体形成的必要条件这一简单定义。学生只需回忆\"慢冷速率\"这一关键知识点即可作答，无需进行概念解释或复杂分析，属于最基本的选择题难度等级。" + }, + { + "idx": 598, + "question": "The close-packed plane of FCC structure is", + "answer": "{111}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构的密排面，答案是一个特定的晶面指数{111}，这属于需要特定知识点的简短回答，不需要计算或选择，也不涉及判断对错 | 知识层次: 题目考查对FCC结构密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，此题属于非常基础的难度等级。题目仅考察对FCC结构密排面的记忆性知识，不需要任何解释、分析或推导过程。学生只需记住FCC的密排面是{111}晶面这一基本事实即可作答，属于最基础的定义性知识考察。在选择题型内，这类仅需记忆单一知识点的题目是最简单的类型。" + }, + { + "idx": 601, + "question": "The coordination number of FCC structure is", + "answer": "12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构的配位数，答案是一个具体的数值（12），不需要从多个选项中选择，也不需要判断对错或进行复杂的计算。虽然答案简短，但属于直接回答问题的简答题类型。 | 知识层次: 题目考查面心立方(FCC)结构配位数的记忆，属于晶体结构中最基础的概念性知识，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目仅考察对FCC结构配位数的基础定义记忆，属于最基础的概念性知识。题目仅需选择正确数字选项，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 602, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the changes of alloy properties is that strength and hardness", + "answer": "increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释有序固溶体转变对合金性能的影响趋势，答案需要文字描述（increase），属于简答题类型。 | 知识层次: 题目考查对有序固溶体转变后合金性能变化的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需记住有序固溶体转变后强度和硬度的一般变化趋势即可作答。题目直接给出正确选项，无需复杂推理或概念比较，属于最基本的选择题难度。" + }, + { + "idx": 603, + "question": "In the Fe-Fe3C phase diagram, what is the carbon content below which the material is considered steel?", + "answer": "2.11%C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（2.11%C），不需要从多个选项中选择，也不涉及判断对错或复杂的计算过程，属于简答题类型。 | 知识层次: 题目考查对Fe-Fe3C相图中钢的定义这一基本概念的记忆和理解，无需复杂分析或计算。 | 难度: 在选择题型中，该题目仅考察对Fe-Fe3C相图中钢的定义这一基础概念的记忆，不需要任何解释或分析步骤。学生只需回忆\"钢的碳含量上限是2.11%\"这一简单事实即可作答，属于最基础的定义性知识考查。" + }, + { + "idx": 604, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the change of alloy properties is: electrical conductivity", + "answer": "decreases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释无序固溶体转变为有序固溶体时合金性能的一般变化趋势，答案需要文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目要求解释无序固溶体转变为有序固溶体时导电性变化的趋势，这需要理解固溶体结构变化与导电性之间的关系，涉及多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解有序固溶体和无序固溶体的概念，并关联其对导电性能的影响。虽然题目给出了正确选项，但需要考生掌握材料科学中固溶体有序化对电子散射机制的影响这一知识点，并进行综合分析判断。" + }, + { + "idx": 605, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the change of alloy properties is: plasticity", + "answer": "decreases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释无序固溶体转变为有序固溶体时合金塑性变化的趋势，需要文字解释和论述，答案\"decreases\"是对趋势的简要描述，符合简答题的特征。 | 知识层次: 题目考查对有序固溶体转变过程中塑性变化这一基本概念的记忆和理解，属于基础概念记忆范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，此题仅考察对基础概念的简单记忆（有序固溶体转变对塑性影响的基本规律），不需要解释或分析过程，属于最基础的定义性知识考查。" + }, + { + "idx": 606, + "question": "In the Fe-Fe3C phase diagram, what carbon content is greater than that of cast iron?", + "answer": "2.11%C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（2.11%C），而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。虽然答案简短，但属于直接回答问题的简答题形式。 | 知识层次: 题目考查对Fe-Fe3C相图中关键点（2.11%C）的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆Fe-Fe3C相图中铸铁的碳含量临界值（2.11%C）这一单一知识点即可作答。题目不涉及概念解释或复杂体系分析，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 607, + "question": "The carbon content of ledeburite is", + "answer": "4.3%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的数值答案（4.3%），而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。这符合简答题的特征，即需要直接回答一个具体的问题。 | 知识层次: 题目考查对ledeburite碳含量的基本概念记忆，属于定义性知识的直接回忆，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅考察对ledeburite碳含量的基础定义记忆，属于最基本的概念性知识。题目仅要求考生回忆一个具体数值（4.3%），无需任何解释、分析或推理过程，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 608, + "question": "The crystal structure of austenite is", + "answer": "FCC", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答奥氏体的晶体结构，答案是一个简短的术语（FCC），不需要从多个选项中选择，也不涉及判断对错或数值计算。 | 知识层次: 题目考查对奥氏体晶体结构这一基础概念的记忆，属于材料科学中最基本的相结构知识，不需要复杂的分析或应用过程。 | 难度: 在选择题型中，该题目仅考察对奥氏体晶体结构的基础定义记忆（FCC），属于最基础的概念性知识，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 609, + "question": "At room temperature, the equilibrium microstructure of hypoeutectoid steel is", + "answer": "ferrite and pearlite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述亚共析钢在室温下的平衡显微组织，答案需要给出具体的组织名称（铁素体和珠光体），属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对亚共析钢在室温下平衡显微组织的基础概念记忆，仅需回答铁素体和珠光体这一基本知识点，无需深入分析或综合应用。 | 难度: 该题目属于基础概念记忆类型，仅需回忆亚共析钢在室温下的平衡显微组织（铁素体和珠光体）这一基本定义即可作答，无需复杂分析或概念关联。在选择题型中属于最基础的难度等级。" + }, + { + "idx": 610, + "question": "During the equilibrium solidification of alloys, the maximum carbon content in austenite is", + "answer": "2.11%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（2.11%），而不是从多个选项中选择或判断对错，也不需要复杂的计算过程，属于简短的直接回答类型 | 知识层次: 题目考查的是合金平衡凝固过程中奥氏体中碳含量的最大值这一基本概念的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即奥氏体中碳含量的最大值。不需要解释或分析，只需直接回忆教材或课堂中给出的具体数值（2.11%）。属于最基础的定义性知识考查，解题步骤和认知要求极低。" + }, + { + "idx": 611, + "question": "What is the carbon content of pearlite", + "answer": "0.77%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求直接回答一个具体的数值（0.77%），不需要从多个选项中选择，也不需要判断对错或进行复杂的计算，属于简答题类型。 | 知识层次: 题目考查对珠光体碳含量的基本概念记忆，属于定义性知识的直接回忆，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即珠光体的碳含量这一具体数值。不需要解释或分析，只需直接回忆并选择正确选项0.77%。属于最基础的定义简答级别。" + }, + { + "idx": 612, + "question": "What are the two basic phases that make up the room-temperature equilibrium structure of iron-carbon alloys", + "answer": "Ferrite (α)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释铁碳合金在室温下的平衡结构的基本相，需要文字解释和论述，答案形式为简短的文字描述而非选择或判断。 | 知识层次: 题目考查铁碳合金室温平衡结构的基本相组成，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求识别铁碳合金室温平衡结构的基本相之一（铁素体α），属于最基础的定义性知识。不需要解释或比较多个概念，只需记忆单一知识点即可作答，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 613, + "question": "From what is Fe3CI precipitated", + "answer": "Liquid phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释Fe3CI的沉淀来源，答案是一个简短的文字描述而非选择、判断或计算 | 知识层次: 题目考查Fe3CI沉淀来源的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即Fe3CI的沉淀来源。正确选项\"Liquid phase\"是一个简单的定义性知识，不需要复杂的解释或分析。题目仅测试学生对这一基本事实的记忆，属于最基础的选择题难度等级。" + }, + { + "idx": 615, + "question": "What are the two basic phases that make up the room-temperature equilibrium microstructure of iron-carbon alloys?", + "answer": "Cementite (Fe3C)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述铁碳合金在室温下的平衡微观结构的基本相，答案需要文字描述而非选择或判断 | 知识层次: 题目考查铁碳合金室温平衡显微组织的基本组成相，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别铁碳合金室温平衡显微组织的基本相之一——渗碳体（Fe3C）。这属于最基础的定义性知识，无需解释或分析，只需直接回忆即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 616, + "question": "From what is Fe3CII precipitated", + "answer": "Austenite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目以提问形式要求回答Fe3CII的沉淀来源，答案\"Austenite\"是一个简短的专有名词回答，不需要计算或选择，符合简答题的特征 | 知识层次: 题目考查Fe3CII从何种相中析出的基础概念记忆，属于材料科学中相变的基本知识点，不需要复杂的推理或综合分析。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即Fe3CII从何种相中析出这一简单事实。正确选项\"Austenite\"是材料科学中最基本的相变知识点之一，无需复杂推理或概念比较，属于直接回忆型问题。" + }, + { + "idx": 617, + "question": "According to the effect of cooling rate on metal microstructure, how should the solidification be controlled to obtain an amorphous structure?", + "answer": "To obtain an amorphous structure, the molten metal should be cooled at an extremely rapid rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何通过控制凝固速率获得非晶结构，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目需要理解冷却速率对金属微观结构的影响，并应用这一知识来论述如何通过控制凝固过程获得非晶态结构。这涉及到概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解金属微观结构与冷却速率之间的关系，并能综合分析快速冷却对非晶态结构形成的影响。虽然题目涉及中等应用层次的知识，但在选择题型中，正确选项直接给出了关键信息，减少了推理步骤的复杂性。" + }, + { + "idx": 618, + "question": "Cold working and hot working", + "answer": "Cold working and hot working: Generally distinguished based on the recrystallization temperature of metal materials. Processing above the recrystallization temperature is called hot working, while processing below the recrystallization temperature and at room temperature is called cold working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对冷加工和热加工进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对冷加工和热加工的基本定义和分类的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求区分冷加工和热加工的定义，并基于再结晶温度进行区分。虽然涉及基础概念记忆，但需要理解并解释两个加工方式的区别，属于中等难度的选择题。不需要复杂的分析或比较多个概念体系，因此不属于最高难度等级。" + }, + { + "idx": 619, + "question": "Crystal zone and zone axis", + "answer": "Crystal zone and zone axis: The collective term for various sets of crystal planes parallel to the same crystal direction is called a crystal zone, and the crystal direction parallel to these sets of crystal planes is called the zone axis.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Crystal zone and zone axis”进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查晶体学中晶带和晶带轴的基本定义和概念记忆，属于基础概念的理解和表述 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解和记忆晶体带和带轴的定义，虽然涉及两个相关概念，但都属于基础概念记忆范畴，不需要复杂的分析或比较。选择题型中，考生只需识别正确选项，无需进行多步骤推理或复杂概念体系的阐述。" + }, + { + "idx": 620, + "question": "Jog and kink", + "answer": "Jog and kink: During the movement of dislocations, certain dislocation intersection lines are formed after intersecting with other dislocations. If the dislocation line after intersection lies on the original slip plane of the dislocation, this dislocation line is called a kink. If the dislocation line after intersection is perpendicular to the original slip plane of the dislocation, this dislocation line is called a jog.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Jog and kink\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对位错运动中形成的jog和kink的基本定义和分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并区分\"jog\"和\"kink\"这两个位错运动中的基本概念，需要掌握它们的定义和形成条件。虽然涉及两个相关概念，但每个概念的定义相对明确，不需要进行复杂的比较分析或推导。在选择题型中，这属于中等偏下的难度，主要考察对基础概念的记忆和理解能力。" + }, + { + "idx": 621, + "question": "Peritectoid reaction and eutectoid reaction", + "answer": "Peritectoid reaction and eutectoid reaction: The process in which two solid phases react to form one solid phase is called a peritectoid reaction, while the reaction in which one solid phase decomposes into two other solid phases is called a eutectoid reaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对两个专业术语进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对相变反应的基本概念（包析反应和共析反应）的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个不同的反应类型（Peritectoid reaction和eutectoid reaction），但正确选项提供了明确的定义和区分，属于概念解释和描述的层次。学生需要理解并记忆这两种反应的基本定义和区别，但不需要进行复杂的分析或比较多个概念体系。因此，难度等级为2。" + }, + { + "idx": 622, + "question": "From what is Fe3CIII precipitated", + "answer": "Ferrite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答Fe3CIII是从什么物质中沉淀出来的，答案\"Ferrite\"是一个简短的文字回答，不需要选择、判断或计算，符合简答题的特征。 | 知识层次: 题目考查Fe3CIII从何种相中析出的基础概念记忆，属于材料科学中相变的基本知识点，不需要复杂的推理或分析。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即Fe3CIII的析出来源这一简单定义性知识。题目仅需考生回忆并选择\"Ferrite\"这一正确答案，无需进行概念解释或复杂分析，属于最基本的选择题难度等级。" + }, + { + "idx": 623, + "question": "The carbon content of Fe3CI, Fe3CII, Fe3CIII is", + "answer": "6.69%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答Fe3C的碳含量，答案是一个具体的数值（6.69%），不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查对Fe3C（渗碳体）碳含量的记忆性知识，属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对Fe3C碳含量的基础记忆，属于最简单的定义性知识问答。不需要任何解释或分析步骤，只需直接回忆标准数值即可作答。" + }, + { + "idx": 624, + "question": "According to the influence of cooling rate on metal microstructure, how should the solidification be controlled to obtain metastable phases?", + "answer": "To obtain metastable phases, the cooling rate must far exceed the equilibrium cooling rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何通过控制凝固过程获得亚稳相，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目要求理解冷却速率对金属微观结构的影响，并应用这一知识来论述如何通过控制凝固过程获得亚稳相。这需要将多个概念（冷却速率、平衡冷却速率、亚稳相）关联起来，并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属微观结构受冷却速率影响的基本概念，并能将冷却速率与亚稳态相的形成关联起来。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项直接给出了关键结论，减少了分析步骤的复杂性。" + }, + { + "idx": 625, + "question": "Columnar crystals and equiaxed crystals", + "answer": "Columnar crystals and equiaxed crystals: During the crystallization process of metal crystals, the elongated grains that preferentially grow along the heat dissipation direction are called columnar crystals, while if the grains grow without a preferred direction and the growth rates in all directions are roughly equal, the resulting grains are called equiaxed crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Columnar crystals and equiaxed crystals\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查柱状晶和等轴晶的基本定义和形成过程，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分两种晶体生长方式（柱状晶和等轴晶）的定义及其形成条件。这比单纯记忆一个定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 626, + "question": "Explain the effect of grain boundaries on material deformation", + "answer": "Grain boundaries strengthen metal materials at room temperature but weaken them at high temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶界对材料变形的影响，需要文字解释和论述，答案也提供了详细的解释而非简单的选择或判断。 | 知识层次: 题目要求解释晶界对材料变形的影响，涉及不同温度条件下的行为差异，需要综合运用材料科学中的晶界理论、变形机制以及温度效应等多方面知识进行推理分析。这超出了简单记忆或直接应用的范围，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 627, + "question": "According to the solidification theory, analyze the characteristics of typical ingot structure", + "answer": "The typical ingot structure features fine equiaxed crystals in the outer layer, columnar crystals extending inward from the surface, and coarse equiaxed crystals in the center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据凝固理论分析典型铸锭结构的特征，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求根据凝固理论分析典型铸锭结构的特征，需要理解并应用凝固理论的基本原理，关联不同晶体结构的形成原因，并进行综合分析。这超出了单纯记忆基础概念的层次，但尚未达到复杂分析或高级综合的要求。 | 难度: 在选择题中属于中等难度，需要理解典型铸锭结构的三个主要特征（外层细等轴晶、中间柱状晶和中心粗等轴晶），并能将这些特征与凝固理论的基本原理联系起来。虽然不需要进行多步计算，但需要对凝固过程中的晶体生长机制有较好的理解，并能综合分析不同区域的晶体形态差异。" + }, + { + "idx": 628, + "question": "What final heat treatment process can be used for overhead copper conductors (requiring certain strength) after processing for outdoor use? Why?", + "answer": "Overhead copper conductors for outdoor use require high strength, and recovery annealing is generally used to eliminate stress while retaining certain strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么选择特定的热处理工艺，需要文字解释和论述，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目要求考生理解铜导体的热处理工艺选择，并解释为何选择恢复退火来满足特定强度要求。这涉及对材料性能、热处理工艺及其效果的综合分析，需要将多个概念关联起来进行中等程度的推理和应用。 | 难度: 在选择题中属于中等难度，需要理解铜导体的热处理工艺及其对强度的影响，并综合分析不同热处理工艺的适用性。虽然题目提供了正确选项，但仍需考生具备一定的材料科学知识，能够将热处理工艺与材料性能要求关联起来。" + }, + { + "idx": 629, + "question": "How to improve the strength of solid solution alloys?", + "answer": "Solid solution strengthening, work hardening, grain refinement strengthening, precipitation strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何提高固溶体合金的强度，答案提供了多种方法但没有具体选项或计算步骤。 | 知识层次: 题目要求列举并解释提高固溶体合金强度的几种方法，涉及多个强化机制（固溶强化、加工硬化、晶粒细化强化、沉淀强化）的综合应用。虽然不需要深入分析每种机制的微观机理，但需要理解这些机制的基本原理及其在材料强化中的作用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握固体溶液合金强度提升的多种方法，包括固溶强化、加工硬化、晶粒细化强化和沉淀强化等概念。虽然题目提供了正确选项，但考生需要对这些概念有一定的理解和区分能力，才能正确选择。这涉及到中等应用层次的知识，需要考生进行概念关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 630, + "question": "What final heat treatment process can be used for decorative wires for indoor electric lights after processing? Why?", + "answer": "Decorative wires for indoor electric lights need to be easily deformable and have high electrical conductivity. Recrystallization annealing can be used to soften them and achieve high electrical conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么特定的热处理工艺适用于装饰性电线，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解材料性能要求（易变形性和高导电性）与热处理工艺（再结晶退火）之间的关系，属于概念关联和综合分析层次。虽然不涉及复杂计算，但需要对材料性能和处理工艺有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，题目要求理解装饰性电线所需的性能（易变形性和高导电性）以及再结晶退火的作用（软化和提高导电性）。需要将材料性能与热处理工艺关联起来，进行综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 631, + "question": "Give two examples to illustrate the phenomenon of uphill diffusion in metals", + "answer": "Examples of uphill diffusion in metals include the formation of Cottrell atmospheres and the spinodal decomposition process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出两个例子来说明金属中的上坡扩散现象，答案提供了具体的例子并进行了简要解释，符合简答题的特征。 | 知识层次: 题目要求列举并解释金属中上坡扩散的现象实例，需要理解上坡扩散的概念，并能将其与具体的金属学现象（如Cottrell气团和调幅分解）联系起来。这涉及到对扩散机制和相变过程的中等程度理解和应用，而不仅仅是基础概念的记忆。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道\"uphill diffusion\"的定义，还要能联想到具体的金属学现象（Cottrell atmospheres和spinodal decomposition），这需要对扩散原理和金属材料行为有较深入的理解。虽然不涉及计算，但需要将抽象概念与具体实例关联起来，属于概念关联和综合分析层次的要求。" + }, + { + "idx": 632, + "question": "Briefly explain the effect of atomic diffusion on materials", + "answer": "The effects of atomic diffusion on materials include processes such as grain nucleation and growth in casting, grain boundary movement, oxidation, etc., all of which involve atomic diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释原子扩散对材料的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对原子扩散影响的基本概念的理解和记忆，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生不仅记忆原子扩散的基本定义，还需要理解并描述其对材料的具体影响（如晶粒成核与生长、晶界移动、氧化等）。这属于概念解释和描述的层次，比单纯的定义记忆（等级1）更复杂，但尚未达到需要阐述复杂概念体系（等级3）的程度。因此，该题目在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 633, + "question": "Explain why solid solution alloys can grow in a dendritic manner under a positive temperature gradient during solidification, while pure metals cannot form dendritic crystals.", + "answer": "Due to solute redistribution causing constitutional supercooling, solid solution alloys can grow dendritically even under a positive temperature gradient during solidification; whereas pure metals require a negative temperature gradient to form dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液合金在正温度梯度下为何会以枝晶方式生长，而纯金属则不能形成枝晶晶体，需要文字解释和论述。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶体合金在正温度梯度下形成枝晶的机理，并对比纯金属的凝固行为。这需要综合运用溶质再分配、成分过冷等概念进行机理分析，涉及多个知识点的关联和深入理解，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 634, + "question": "Explain the influence of grain boundaries on material properties", + "answer": "Grain boundaries affect various aspects of materials, possessing grain boundary energy, influencing the shape of second phases in polycrystalline materials. Grain boundaries can move, exhibit grain boundary segregation, undergo changes in grain boundary charge, bear load transfer effects, have low melting points and are prone to overheating. Grain boundaries serve as easy diffusion paths, facilitate nucleation, and are susceptible to corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶界对材料性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释晶界对材料性能的影响，涉及多个方面的知识（如晶界能、扩散路径、腐蚀敏感性等），需要将不同概念关联起来进行综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解晶界的基本概念，还需要掌握晶界对材料性能的多方面影响，包括能量、形貌、运动、偏析、电荷、载荷传递、熔点、扩散路径、形核和腐蚀等多个角度。这需要考生具备较强的综合分析能力和对材料科学中晶界相关知识的深入理解。" + }, + { + "idx": 635, + "question": "Metal glass", + "answer": "Metal glass: refers to a solid formed when metal solidifies from a liquid state, retaining the same structure as the liquid metal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Metal glass\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征 | 知识层次: 题目考查对金属玻璃这一基本概念的定义和记忆，属于基础概念的理解和复述，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别金属玻璃的基本定义，属于最基础的概念记忆层次。题目描述直接给出了定义性陈述，不需要任何解释或分析步骤，因此属于最简单的难度等级。" + }, + { + "idx": 636, + "question": "Grain boundary segregation", + "answer": "Grain boundary segregation: The enrichment phenomenon of solute atoms or impurity atoms at grain boundaries due to the difference in distortion energy between the grain interior and grain boundaries or the presence of vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Grain boundary segregation\"这一现象进行文字解释和论述，答案提供了详细的定义和原因说明，符合简答题的特征。 | 知识层次: 题目考查对晶界偏析这一基础概念的定义和基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆晶界偏析的定义及其基本原理，但不需要进行复杂的分析或比较。虽然涉及一些专业术语（如“solute atoms”、“distortion energy”），但整体上是对基础概念的描述，属于中等难度的选择题。" + }, + { + "idx": 637, + "question": "Intermetallic compounds", + "answer": "Intermetallic compounds: Compounds formed between metals and metals, or between metals and certain non-metals, whose structure and composition differ from those of the pure metals forming the intermetallic compounds. They generally exhibit characteristics such as high melting points, high hardness, and significant brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Intermetallic compounds\"进行解释和论述，答案提供了详细的文字描述和特性说明，符合简答题的特征。 | 知识层次: 题目考查对金属间化合物的基本定义和特性的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项对金属间化合物的定义、组成和特性进行了较为详细的解释，需要考生对相关概念有一定的理解和记忆。相比于仅要求简单定义的选择题（等级1），该题目要求考生掌握更多的细节信息，但尚未达到需要分析复杂概念体系的程度（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 638, + "question": "Cottrell atmosphere", + "answer": "Cottrell atmosphere: the phenomenon of solute atoms aggregating around an edge dislocation. This atmosphere can impede dislocation motion, resulting in effects such as solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Cottrell atmosphere\"进行文字解释和论述，答案提供了概念的定义和现象说明，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即Cottrell atmosphere的定义及其对位错运动的影响，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生不仅记住Cottrell atmosphere的定义，还需要理解其背后的物理现象（溶质原子聚集、阻碍位错运动）以及产生的效果（固溶强化）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 639, + "question": "Divorced eutectic", + "answer": "Divorced eutectic: In alloys with eutectic reactions, if the composition is far from the eutectic point, due to the large amount of primary crystals and the small amount of eutectic, the same phase in the eutectic as the primary crystals attaches to the primary crystals and grows, while the other phase in the eutectic appears separately distributed, causing the eutectic structure to lose its characteristic organizational features.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Divorced eutectic\"进行详细的文字解释和论述，而不是选择、判断或计算。答案提供了对该术语的详细描述，符合简答题的特征。 | 知识层次: 题目考查对\"Divorced eutectic\"这一专业术语的定义和基本特征的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然涉及了共晶反应和离异共晶的概念，但题目已经给出了明确的定义和解释，不需要考生进行复杂的分析或比较。考生只需理解并记忆相关概念即可正确作答。相对于基本定义简答的等级1，该题目需要更深入一点的概念理解，但不需要达到复杂概念体系阐述的等级3。" + }, + { + "idx": 640, + "question": "Twinning", + "answer": "Twinning: An important mode of plastic deformation in crystals. Under shear stress, one part of the crystal undergoes uniform shear relative to another part along specific crystallographic planes and directions, resulting in different orientations of adjacent crystal regions that are mirror-symmetrical across the twinning plane (twin boundary).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Twinning\"这一概念进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查的是孪晶变形的基本概念和原理，属于对晶体塑性变形模式的定义和基本机制的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述的难度等级。虽然题目涉及晶体塑性变形的基本原理和具体机制，但正确选项已经提供了较为详细的解释，包括孪生的定义、发生条件（剪切应力）、具体过程（沿特定晶面和方向的均匀剪切）以及结果（相邻晶体区域的镜像对称取向）。这些信息足以让具备基础材料科学知识的考生识别出正确答案，无需进行复杂的分析或比较多个概念。因此，该题目在选择题型中属于中等难度（等级2）。" + }, + { + "idx": 641, + "question": "Explain the main factors affecting the diffusion coefficient in the equation", + "answer": "The main factors affecting the diffusion coefficient in the equation include temperature, crystal structure, crystal defects, type of solid solution, properties of the diffusing element, and concentration of the diffusing component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响扩散系数的主要因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响扩散系数的主要因素，涉及多个概念（如温度、晶体结构、缺陷等）的关联和综合分析，需要理解这些因素如何相互作用并影响扩散系数，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求解释影响扩散系数的主要因素，涉及温度、晶体结构、晶体缺陷、固溶体类型、扩散元素性质以及扩散组分浓度等多个知识点。虽然不需要进行复杂的计算，但需要对材料科学中的扩散现象有较全面的理解，并能将这些因素关联起来综合分析。" + }, + { + "idx": 643, + "question": "Determine whether the dislocation reaction a/6[2\\overline{1}\\overline{1}] + a/6[\\overline{1}21] → a/6[110] can proceed in a face-centered cubic crystal?", + "answer": "With reference to the geometric and energy conditions, the dislocation reaction can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过几何和能量条件分析位错反应是否可行，需要文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求分析位错反应在面心立方晶体中的可行性，涉及几何条件和能量条件的综合评估。这需要深入理解位错的性质、反应机制以及晶体结构的知识，并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 644, + "question": "If the leading dislocations of two extended dislocations undergo the reaction a/6[2\\overline{1}\\overline{1}] + a/6[\\overline{1}21] → a/6[110], what effect will it have on the properties of face-centered cubic metals?", + "answer": "The dislocations become immobile after the reaction, affecting the work hardening mechanism and fracture properties of the crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应对金属性能的影响，答案需要文字解释和论述，没有提供选项或要求计算 | 知识层次: 题目涉及位错反应的具体机制及其对材料性能的影响，需要综合运用位错理论、晶体结构知识以及材料性能变化的机理分析。不仅要求理解位错反应的基本原理，还需要分析反应后位错的运动性变化及其对宏观性能的影响，属于较高层次的综合分析和推理。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 645, + "question": "Reaction diffusion", + "answer": "Reaction diffusion: The diffusion accompanied by chemical reactions that leads to the formation of new phases is called reaction diffusion. For example, when infiltrating elements diffuse from the metal surface into the interior and their concentration exceeds the solubility limit, new phases appear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Reaction diffusion\"进行文字解释和论述，答案提供了详细的定义和例子，符合简答题的特征。 | 知识层次: 题目考查对反应扩散这一基本概念的定义和简单例子的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及反应扩散的定义和基本原理，但正确选项提供了明确的解释和示例，使得学生可以通过记忆和理解基础概念来回答。不需要复杂的分析或比较多个概念，但需要一定的概念理解和描述能力。" + }, + { + "idx": 646, + "question": "Write the expression for the unsteady-state diffusion equation", + "answer": "The expression for the unsteady-state diffusion equation is: ∂C/∂t = ∂(D(∂c/∂x))/∂x. If the diffusion coefficient D does not vary with concentration, it can be simplified to ∂C/∂t = D(∂²c/∂x²).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出非稳态扩散方程的表达式，并给出了详细的解释和可能的简化形式，这属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对非稳态扩散方程表达式的基本记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目要求考生回忆并写出非稳态扩散方程的基本表达式，并理解在扩散系数D不随浓度变化时的简化形式。这属于概念解释和描述的难度级别，需要考生对扩散方程有基本的理解和记忆，但不需要进行复杂的推导或分析。" + }, + { + "idx": 647, + "question": "Point out the main factors affecting the recrystallization temperature of metals after cold deformation", + "answer": "The main factors affecting the recrystallization temperature of metals after cold deformation are: degree of deformation, trace impurities and alloying elements, metal grain size, heating time, heating rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响金属再结晶温度的主要因素，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目主要考查对金属再结晶温度影响因素的基础概念记忆和理解，属于基本原理的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个影响再结晶温度的因素（变形程度、微量杂质和合金元素、金属晶粒尺寸、加热时间、加热速率），但这些因素都是基础概念记忆层面的内容，不需要进行复杂的比较分析或概念体系阐述。考生只需回忆并识别这些关键因素即可正确作答，因此难度等级为2。" + }, + { + "idx": 648, + "question": "What are the main measures to obtain fine recrystallized grains, and why?", + "answer": "The main measures to obtain fine recrystallized grains are: increasing the degree of cold deformation, adding trace alloying elements, increasing the heating rate, and using fine-grained metals", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述获得细小再结晶晶粒的主要措施及其原因，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目不仅要求列举获得细晶再结晶的主要措施，还需要解释原因，涉及多步骤的概念关联和综合分析，需要理解冷变形程度、微量合金元素、加热速率和细晶金属对再结晶晶粒尺寸的影响机制。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握多个关键概念（如冷变形程度、微量合金元素、加热速率和细晶金属），还需要理解这些因素如何相互作用以获得细小的再结晶晶粒。此外，题目要求综合分析这些措施的原理，而不仅仅是记忆单一知识点。这种多角度分析和概念关联的要求使得该题目在选择题型中难度较高。" + }, + { + "idx": 649, + "question": "Describe the main strengthening mechanisms that can be employed to strengthen Al-5%Cu alloy", + "answer": "The strengthening mechanisms for Al-5%Cu alloy are solid solution strengthening, precipitation strengthening, work hardening, and grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述铝合金的主要强化机制，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求描述铝合金的主要强化机制，涉及多个强化方式的列举和简要解释，需要理解不同强化机制的基本原理及其在铝合金中的应用，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握Al-5%Cu合金的主要强化机制，包括固溶强化、沉淀强化、加工硬化和晶粒细化强化等概念。虽然不涉及复杂的计算，但需要对不同强化机制有清晰的认识，并能综合判断哪些机制适用于该合金体系。这需要一定的知识积累和概念关联能力，但尚未达到多角度分析或深度关联性分析的要求。" + }, + { + "idx": 650, + "question": "What is the relationship between the corrosion of engineering materials and bonding?", + "answer": "The essence of corrosion in engineering materials is the formation and destruction of bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释工程材料的腐蚀与键合之间的关系，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查腐蚀与键合关系的基本概念，属于定义和基本原理的记忆性知识 | 难度: 在选择题型中，该题目仅要求考生记忆并识别腐蚀现象与化学键形成/断裂之间的基本关系。题目考查的是基础概念的定义层面，不需要进行概念解释或复杂体系分析。正确选项直接给出了明确的定义性陈述，属于最基础的选择题难度等级。" + }, + { + "idx": 651, + "question": "Describe the main strengthening mechanisms that may be employed to strengthen the Al-5%Al2O3 composite material", + "answer": "The strengthening mechanisms for the Al-5%Al2O3 composite material are work hardening, fine grain strengthening, and dispersion strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述主要的强化机制，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求描述Al-5%Al2O3复合材料的强化机制，涉及多个强化机制（加工硬化、细晶强化、弥散强化）的综合分析，需要理解这些机制在复合材料中的具体应用和相互作用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如工作硬化、细晶强化和弥散强化）并进行综合分析。虽然题目涉及多个强化机制，但在选择题型中只需识别正确选项，无需深入论述各机制的具体原理或计算过程。" + }, + { + "idx": 652, + "question": "For industrial pure copper ingots with low stacking fault energy, after hot breakdown rolling at $T=0.5T_{\\\\xi\\\\sharp,\\\\xi}$ temperature, what methods can be adopted in the final process to obtain semi-hard products, and why?", + "answer": "To obtain semi-hard products, cold working followed by recovery annealing, or appropriate cold deformation after complete recrystallization annealing can be adopted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释采用何种方法获得半硬制品并说明原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析工业纯铜锭在特定热轧温度后的加工方法，并解释原因。这需要综合运用材料加工、热处理和力学性能的知识，涉及多步骤的工艺选择和机理解释，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 653, + "question": "Describe the main strengthening mechanisms that can be employed for industrial pure aluminum", + "answer": "The main strengthening mechanisms for industrial pure aluminum are work hardening and grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述工业纯铝的主要强化机制，需要文字解释和论述，答案也是以文字形式呈现的简要说明。 | 知识层次: 题目考查对工业纯铝主要强化机制的基础概念记忆和理解，涉及简单的分类和基本原理，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述强化机制，但在选择题的上下文中，正确选项已经提供了明确的答案（加工硬化和晶粒细化强化）。这需要考生对工业纯铝的基本强化机制有概念性的理解和记忆，但不需要进行复杂的分析或比较。题目考察的是对基础概念的掌握程度，属于\"概念解释和描述\"层次的知识。" + }, + { + "idx": 654, + "question": "For industrial pure copper ingots with low stacking fault energy, after hot breakdown rolling at $T=0.5T_{\\\\xi\\\\sharp,\\\\xi}$ temperature, what methods can be used in the final process to obtain soft-state products, and why?", + "answer": "To obtain soft-state products, cold working followed by recrystallization annealing can be used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述如何通过特定方法获得软态产品，并说明原因，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目需要理解低堆垛层错能工业纯铜的热轧工艺，并应用冷加工和再结晶退火的知识来解决问题。这涉及到多步工艺选择和基本原理的应用，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 655, + "question": "What is work hardening?", + "answer": "The phenomenon where the flow stress of a metal increases with increasing strain during cold working is called work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"work hardening\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即工作硬化的定义和基本原理。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"work hardening\"的基本定义，属于最基础的概念记忆层次。正确选项直接给出了现象的定义，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 657, + "question": "How do the types of material bonding bonds affect the physical properties of materials?", + "answer": "The stronger the bonding bond, the higher the melting point, the smaller the thermal expansion coefficient, and the greater the density. Metals have luster, high electrical and thermal conductivity, good mechanical strength and plasticity, and a positive temperature coefficient of resistance, which are related to the metallic bonds of metals. Ceramics and polymers are generally non-conductive in the solid state, which is related to their non-metallic bonding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料键合类型如何影响物理性质，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释不同类型的材料键合如何影响材料的物理性质，涉及多个概念（如金属键、离子键、共价键等）的关联和综合分析，需要理解键合类型与物理性质之间的关系，并进行一定的推理和解释。虽然不涉及复杂计算，但需要对多个知识点进行整合和应用。 | 难度: 在选择题型中，该题目需要考生对不同类型的材料键合（如金属键、离子键、共价键等）及其对物理性质的影响有深入的理解。题目不仅要求考生识别键合类型与物理性质之间的基本关系，还需要综合分析不同材料（金属、陶瓷、聚合物）的具体特性与其键合类型的关联。此外，题目涉及多个物理性质（熔点、热膨胀系数、密度、导电性等）的综合分析，属于多角度分析论述的难度层次。" + }, + { + "idx": 658, + "question": "What are the adverse effects of texture on metal materials?", + "answer": "Texture induces anisotropy in metals, and anisotropy often causes difficulties in the processing and use of metals. Deep-drawn metal cups may develop ears. Polycrystalline metal rods with texture can significantly elongate after repeated heating and cooling cycles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释纹理对金属材料的不良影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释纹理对金属材料的不良影响，涉及纹理引起的各向异性及其在加工和使用中的具体问题（如深冲杯的耳状突起、多晶金属棒的热循环伸长）。这需要理解纹理的基本概念，并将其与金属材料的实际应用问题联系起来，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解金属材料的织构效应及其对性能的影响，涉及多个概念（各向异性、加工难度、深冲杯耳现象、热循环变形）的综合分析，但选项已提供明确的关联性解释，无需额外推导。" + }, + { + "idx": 659, + "question": "How do the types of material bonding affect the mechanical properties of materials?", + "answer": "The hardness of crystalline materials is related to the bonding of the crystals. Generally, crystals bonded by covalent bonds, ionic bonds, and metallic bonds have higher hardness than those bonded by molecular bonds. The greater the bonding energy between the bonds, the higher the elastic modulus. The strength of engineering materials is also somewhat related to the bonding energy. Generally, higher bonding energy results in higher strength. The plasticity of materials is also related to the type of bonding. Materials bonded by metallic bonds exhibit good plasticity, while those bonded by ionic or covalent bonds have difficulty undergoing plastic deformation, hence ceramic materials exhibit very poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料键合类型如何影响机械性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释不同类型材料键合如何影响机械性能，涉及多个概念（键合类型、硬度、弹性模量、强度、塑性）的关联和综合分析，需要理解键合能量与性能之间的关系，并进行多方面的论述。 | 难度: 在选择题中属于较高难度，题目要求考生理解并综合分析不同类型材料键合对机械性能（硬度、弹性模量、强度和塑性）的影响。需要掌握多个概念（共价键、离子键、金属键和分子键）及其与材料性能的关联，并进行多角度比较分析。虽然题目提供了正确选项，但涉及的知识点深度和综合分析能力要求较高，超出了简单记忆或单一概念应用的层次。" + }, + { + "idx": 660, + "question": "List the various possible mechanisms of work hardening", + "answer": "The mechanisms of work hardening are mainly the interactions between dislocations, such as the formation of jogs, dislocation intersection and entanglement, the interaction between moving dislocations and forest dislocations, the formation of Lomer-Cottrell locks, and the formation of solute atom atmospheres due to the interaction between solute atoms and dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列出各种可能的加工硬化机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举并解释加工硬化的多种机制，涉及位错之间的复杂相互作用（如jog形成、位错交叉和纠缠、移动位错与森林位错的相互作用、Lomer-Cottrell锁的形成、溶质原子与位错的相互作用等）。这需要深入理解位错理论并能综合分析多种机制，属于对材料变形机理的复杂分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面掌握并分析多种位错相互作用机制，包括位错交截、缠结、林位错相互作用、Lomer-Cottrell锁形成以及溶质原子气团形成等复杂现象。这些知识点不仅需要深入理解材料变形机理，还需要综合运用多个概念进行推理分析。在选择题型中，能够准确识别和区分所有这些机制需要极高的知识掌握深度和分析能力，远超一般选择题的认知要求。" + }, + { + "idx": 661, + "question": "Choose any material and describe its possible uses and processing methods.", + "answer": "Aluminum alloy is used to manufacture packaging containers such as beverage cans and food cans. For example, beverage companies like Coca-Cola and Pepsi extensively use aluminum alloy cans, which offer excellent sealing, corrosion resistance, and recyclability, ensuring beverage quality protection and convenience for consumers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求选择一个材料并描述其用途和加工方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述材料的用途和加工方法，属于对基础知识的直接应用，不需要复杂的分析或综合。答案中提到的铝合金属性及其在包装容器中的应用是材料科学中的常见案例，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用过程描述。题目要求选择一个材料并描述其用途和加工方法，正确选项直接给出了铝合金属的具体应用实例（饮料罐和食品罐）及其优点（密封性、耐腐蚀性、可回收性），这些都是材料科学中的基本知识点。题目不需要复杂的计算或深入的分析，只需对材料的基本应用有了解即可作答。因此，在选择题型内属于较低难度。" + }, + { + "idx": 662, + "question": "How does temperature affect the diffusion coefficient?", + "answer": "As temperature increases, the diffusion coefficient increases sharply.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释温度如何影响扩散系数，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查温度对扩散系数影响的基本原理记忆和理解，属于基础概念范畴 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即温度对扩散系数影响的基本原理。正确选项直接陈述了温度与扩散系数的关系，无需复杂分析或多概念比较。属于最基础的定义简答级别。" + }, + { + "idx": 663, + "question": "What are the beneficial applications of texture in metallic materials?", + "answer": "In some cases, it is necessary to deliberately obtain certain textures to utilize their anisotropy, such as silicon steel sheets for transformers, high-voltage electronic aluminum foils for precision electronic capacitors, and interstitial-free steels used in automotive and mechanical sectors that require superior deep-drawing performance. For heat-treatable non-strengthening aluminum alloys, work hardening through cold deformation can be employed to strengthen the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纹理在金属材料中的有益应用，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释纹理在金属材料中的有益应用，并列举具体实例，涉及多个概念（如各向异性、冷变形强化）的关联和综合分析，需要一定的理解和应用能力，但不需要复杂的推理或创新设计。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解金属材料织构的基本概念，还需要掌握其在不同应用场景中的具体表现和原理（如硅钢片的各向异性、高压电子铝箔的应用等）。此外，正确选项涉及多个专业领域的知识关联（材料科学、电子工程、机械工程），需要考生进行跨领域的综合分析。解题时需要将抽象的材料特性与具体工业应用场景联系起来，这种多角度分析论述的要求超出了基础选择题的范畴。" + }, + { + "idx": 664, + "question": "Explain the industrial applications of work hardening", + "answer": "Industrial applications of work hardening: During processing, the resistance of metal to plastic deformation continuously increases, making the metal brittle and necessitating multiple intermediate annealing processes, which requires more power consumption for cold working of the metal; work hardening provides the metal matrix with a certain ability to resist accidental overload; appropriate combination of work hardening and plastic deformation enables uniform plastic deformation of the metal, and some processing methods require the metal to have a certain degree of work hardening; work hardening is also one of the important means to strengthen metals, and for some pure metals, work hardening is a key method to improve strength; some components continuously harden on the surface under working conditions, meeting requirements for impact and wear resistance on the surface; after work hardening, the plasticity of materials decreases, improving machinability of materials such as low-carbon steel; the final properties of products can be controlled through cold working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释工业应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释和论述工作硬化的工业应用，涉及多个应用场景和原理的综合分析，需要将工作硬化的基本原理与实际工业应用相结合，进行多方面的阐述和关联。虽然不涉及复杂的计算或深度机理分析，但需要对概念进行关联和综合应用，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解工作硬化的基本概念，还需要综合分析其在工业应用中的多个方面。题目涉及多个知识点，如金属的塑性变形、脆性变化、中间退火工艺、冷加工能耗、金属强化机制等，并要求考生能够将这些概念关联起来，进行多角度分析。此外，题目还要求考生理解工作硬化对材料性能的影响，如表面硬化、耐磨性、塑性变化等，这需要较深的知识掌握和综合分析能力。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 665, + "question": "What are the methods for controlling the texture of metal materials?", + "answer": "One method to control texture is by regulating the processing and heat treatment regimes to obtain a processed structure with only slight texture and a fine-grained recrystallized structure. Additionally, altering the production process of rolled plates, combining intermediate recrystallization annealing during cold working with final recovery annealing can control texture. The cross-rolling method can also be employed. Controlling the hot rolling process of aluminum alloy sheets, multi-directional cross cold rolling, and corresponding annealing can reduce the formation of ears.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释控制金属材料织构的方法，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及多种控制金属材料织构的方法，需要理解不同加工和热处理工艺对织构的影响，并进行综合分析。虽然不需要复杂的推理或创新设计，但需要将多个概念关联起来，如加工工艺、热处理和织构控制之间的关系，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握金属材料织构控制的基本方法，还需要理解多步骤的加工和热处理工艺的综合应用。题目涉及的知识点包括加工工艺调控、热处理制度、冷热轧制工艺以及退火处理等多个方面，需要考生能够将这些概念关联起来进行综合分析。此外，题目还提到了具体的工艺方法如交叉轧制和多向冷轧，这要求考生具备一定的实际应用知识。因此，该题目在选择题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 666, + "question": "How do crystal defects affect the diffusion coefficient?", + "answer": "The diffusion rate of atoms along line defects (dislocations) and planar defects (grain boundaries and free surfaces, etc.) is much greater than that of bulk diffusion within the crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶体缺陷如何影响扩散系数，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释晶体缺陷对扩散系数的影响，涉及晶体缺陷类型（线缺陷和面缺陷）与扩散速率的关系，需要将多个概念关联起来进行分析，并比较不同类型缺陷的扩散速率差异。这属于中等应用层次，需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解晶体缺陷（线缺陷和面缺陷）对扩散系数的影响，并比较不同缺陷类型下的扩散速率差异。题目要求考生将晶体缺陷的概念与扩散行为进行关联分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 667, + "question": "Briefly explain the role of the second phase during cold plastic deformation", + "answer": "The primary deformation modes of duplex alloys remain slip and twinning. Due to differences in the type, quantity, size, shape, distribution characteristics of the second phase in the alloy, as well as its interfacial bonding with the matrix, the influence of the second phase on plastic deformation is complex. If both phases in the duplex alloy are plastic, and the size and deformability of the second phase are similar to those of the matrix, the deformation of the alloy depends on the volume fraction of the two phases. If one phase is plastic and the other is hard and brittle, the plastic deformation of the alloy mainly depends on the presence of the hard and brittle phase. If the second phase is coarse or large-needle-shaped, deformation occurs only in the matrix, and the alloy's plasticity will not be high. If the second phase is continuously distributed along the grain boundaries of the solid solution, the alloy becomes very brittle and almost incapable of plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释第二相在冷塑性变形中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第二相在冷塑性变形中的作用，涉及多种因素（类型、数量、尺寸、形状、分布特征等）的综合影响，需要深入分析和理解不同情况下第二相对塑性变形的复杂影响机制。这需要综合运用相关知识，进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面分析第二相在冷塑性变形中的复杂作用机制，涉及多种变量（类型、数量、尺寸、形状、分布特征等）的综合影响，并需要区分不同条件下的变形主导因素（双相塑性/硬脆相/粗大相/晶界连续相等）。这种题目不仅要求掌握材料变形的基础理论，还需要具备将多因素相互作用进行系统推理的能力，属于典型的复杂现象全面分析层次。" + }, + { + "idx": 668, + "question": "How does the anisotropy of crystals affect the diffusion coefficient?", + "answer": "The anisotropy of crystals also affects the diffusion coefficient, but this anisotropy gradually decreases with increasing temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体各向异性如何影响扩散系数，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目涉及晶体各向异性对扩散系数的影响机制分析，需要综合运用晶体结构、扩散理论和温度效应的知识，并进行推理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶体各向异性对扩散系数的影响机制，还需要掌握温度变化对各向异性效应的调控规律。这需要综合运用晶体学、扩散动力学和热力学知识进行复杂现象分析，属于需要深度机理解释和全面分析的题目类型。正确选项涉及两个变量的耦合作用（各向异性+温度），在选择题型中属于认知要求最高的考查形式。" + }, + { + "idx": 669, + "question": "How does allotropic transformation affect the diffusion coefficient?", + "answer": "In metals with allotropic transformation, the diffusion coefficient changes significantly with the alteration of crystal structure, and the diffusion coefficient of solute atoms in BCC crystal structure is larger than that in FCC.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释同素异构转变如何影响扩散系数，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释同素异构转变对扩散系数的影响机制，涉及晶体结构变化与扩散行为的关联分析，需要综合运用材料科学中的相变理论和扩散理论进行机理层面的解释，属于需要推理分析和综合运用的复杂问题。 | 难度: 在选择题型内，该题目属于高难度等级。题目要求考生不仅理解同素异构转变的基本概念，还需要掌握其对扩散系数的具体影响机制。正确选项涉及BCC和FCC晶体结构中扩散系数的比较，这需要考生具备深入的材料科学知识，能够对不同晶体结构中的原子扩散行为进行机理层面的解释和综合分析。这种题目在选择题中属于需要复杂分析能力的类型，符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 670, + "question": "What is the difference in diffusion activation energy between interstitial atoms and substitutional atoms?", + "answer": "The diffusion activation energy of interstitial atoms is much smaller than that of substitutional atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述间隙原子和置换原子在扩散激活能上的差异，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对间隙原子和置换原子扩散激活能差异的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及扩散激活能的基本概念，但需要考生理解并比较两种不同原子（间隙原子和置换原子）的扩散激活能差异。这超出了简单的定义记忆，要求考生能够解释和描述相关概念的区别。然而，题目并未涉及复杂的推导或多步骤分析，因此难度等级为2。" + }, + { + "idx": 671, + "question": "How does solute concentration affect the diffusion coefficient?", + "answer": "In many solid solution alloys, the diffusion coefficient of the solute increases with increasing concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释溶质浓度如何影响扩散系数，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及扩散系数与溶质浓度关系的理解，需要将扩散理论的基本概念与实际合金体系中的现象关联起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解扩散系数与溶质浓度的关系，并能够综合分析固体溶液合金中的扩散行为。题目涉及中等应用层次的知识，要求考生将多个概念关联起来进行判断，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 672, + "question": "Explain the basic concept of dislocations", + "answer": "Dislocations are a type of arrangement defect in crystal structures, which can be divided into edge dislocations, screw dislocations, and mixed dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释位错的基本概念，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释位错的基本概念和分类，属于对晶体缺陷基础知识的记忆和理解，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别位错的基本定义和分类，属于最基础的概念性知识。题目正确选项直接给出了定义和分类，无需进行复杂的概念比较或分析，因此属于难度等级1。" + }, + { + "idx": 673, + "question": "How does the difference in properties between the diffusing element and the solvent metal affect the diffusion coefficient?", + "answer": "The greater the difference in properties between the diffusing element and the solvent metal, the larger the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释扩散元素与溶剂金属之间性质差异对扩散系数的影响，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目要求解释扩散元素与溶剂金属性质差异对扩散系数的影响，涉及多步概念关联和综合分析，需要理解扩散机制并应用相关原理进行解释。 | 难度: 在选择题中属于中等难度，需要理解扩散元素与溶剂金属性质差异对扩散系数的影响这一概念，并进行综合分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项直接给出了结论，减少了推导的复杂性。因此，难度等级为3，属于中等应用层次。" + }, + { + "idx": 674, + "question": "What is the effect of a third element on the diffusion of components in a binary alloy?", + "answer": "The third element that forms compounds with the components in the alloy hinders the diffusion of solute atoms, thereby reducing the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第三元素对二元合金中组分扩散的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及第三元素对二元合金中组分扩散的影响，需要理解扩散机制、第三元素与合金组分的相互作用，以及这些因素如何影响扩散系数。这需要对扩散过程进行机理层面的解释和综合分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解二元合金中扩散的基本概念，还需要分析第三元素对扩散系数的影响机制。正确选项涉及化合物形成对溶质原子扩散的阻碍作用，这需要考生具备综合运用材料科学原理、进行推理分析和机理解释的能力。这种复杂现象全面分析的题目在选择题中属于最高难度，因为它超越了简单记忆或单一概念应用，要求考生整合多个知识点并推导出结论。" + }, + { + "idx": 675, + "question": "Explain the effect of grain size on the mechanical properties of metal materials at room temperature", + "answer": "Room temperature strengthening. Fine grain strengthening can improve the strength and hardness of metal materials. The smaller the grain size, the more grain boundaries there are, and the greater the resistance to dislocation movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶粒尺寸对金属材料力学性能的影响，需要文字解释和论述，而不是选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释晶粒尺寸对金属材料力学性能的影响，涉及晶粒尺寸与晶界数量、位错运动阻力之间的关系，需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶粒尺寸对金属材料力学性能的影响，并能够关联晶界数量与位错运动阻力之间的关系。虽然题目涉及多个概念的关联，但在选择题型中，正确选项已经提供了明确的解释，降低了分析难度。" + }, + { + "idx": 676, + "question": "Explain the diffusion mechanism", + "answer": "The diffusion mechanisms mainly include: interstitial diffusion where solute atoms diffuse through interstices in interstitial solid solutions, and the vacancy mechanism where atoms exchange with vacancies to achieve diffusion in substitutional solid solutions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散机制，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目考查扩散机制的基本概念和分类，属于对基础知识的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释扩散机制，但正确选项已经提供了明确的定义和分类（间隙扩散和空位机制），属于概念解释和描述的范畴。不需要进行复杂的概念体系阐述或比较分析，只需理解并记忆这些基本概念即可作答。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 677, + "question": "Explain uphill diffusion", + "answer": "Uphill diffusion is a diffusion process where the diffusing element moves from a region of low concentration to a region of high concentration; examples include the formation of various solute atom atmospheres and the formation of eutectoid reaction products, both of which are uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释\"uphill diffusion\"的概念，并提供相关例子，这需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释uphill diffusion现象，涉及从低浓度向高浓度扩散的特殊过程，需要理解扩散的基本原理并关联实际例子（如溶质原子氛围和共析反应产物）。虽然包含基础概念，但需要将概念与实际应用结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解\"uphill diffusion\"这一非直观概念，并能将其与常规扩散区分。题目要求考生不仅掌握浓度梯度驱动的普通扩散机制，还需理解在特定条件下（如化学势梯度驱动）物质会逆向扩散的现象。同时需要关联实际材料科学案例（如溶质原子气团形成、共析反应产物形成），体现概念的综合应用能力。但作为选择题，正确选项已提供完整解释，降低了答题复杂度。" + }, + { + "idx": 678, + "question": "How does the effect of solute elements on the melting point of alloys influence the diffusion coefficient?", + "answer": "Solute elements that can lower the melting point of alloys (or cause a decrease in the liquidus line) will increase the diffusion coefficient; conversely, they will decrease the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释溶质元素对合金熔点的影响如何影响扩散系数，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析溶质元素对合金熔点的影响如何进一步影响扩散系数，涉及多个概念的关联和机理解释，需要综合运用材料科学中的热力学和动力学知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 679, + "question": "How to control the microstructure and properties of materials through deformation and heating?", + "answer": "Deformation can increase dislocation density, thereby enhancing material strength; heating can promote dislocation rearrangement and recrystallization, thereby refining grains and improving material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过变形和加热控制材料的微观结构和性能，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解变形和加热对材料微观结构和性能的影响机制，涉及多个概念的关联和综合分析，如位错密度、再结晶和晶粒细化等。虽然不需要复杂的计算或创新设计，但需要一定的推理和解释能力。 | 难度: 在选择题中属于中等难度，需要理解变形和加热对材料微观结构和性能的影响机制，并能够将多个概念（如位错密度、晶粒细化、再结晶等）进行关联分析。虽然题目涉及的知识点较为基础，但需要综合应用这些知识来解答问题，属于中等应用层次。" + }, + { + "idx": 681, + "question": "Explain the effect of grain size on the high-temperature mechanical properties of metallic materials", + "answer": "High-temperature weakening. Grain boundaries become weak points at high temperatures, excessively fine grains reduce high-temperature creep resistance, and appropriately coarsening grains is beneficial for high-temperature performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶粒尺寸对金属材料高温力学性能的影响，需要文字解释和论述，答案也提供了详细的文字说明而非选择或判断。 | 知识层次: 题目要求解释晶粒尺寸对金属材料高温力学性能的影响，涉及晶界在高温下的行为、晶粒尺寸与高温蠕变抗力的关系，以及晶粒适当粗化对高温性能的益处。这需要综合运用材料科学中的晶体缺陷、高温变形机制等知识，进行推理分析和机理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。它要求考生不仅理解晶粒尺寸对高温力学性能的影响机理，还需要综合运用多个知识点（如晶界弱化、蠕变抗力、晶粒粗化效应等）进行推理分析。正确选项涉及复杂现象的全面解释，包括微观机制与宏观性能的关联，这远超简单记忆或基础理解的范畴，符合选择题型内对\"复杂现象全面分析\"能力的最高要求。" + }, + { + "idx": 682, + "question": "How to control the grain size of materials in production", + "answer": "1. Use inoculation treatment or rapid cooling to refine grains during casting; 2. Control rolling process parameters to refine the microstructure during hot working; 3. Utilize alloy elements to pin grain boundaries and inhibit grain growth during recrystallization annealing; 4. Coordinate the relationship between cold deformation amount and heating temperature according to the recrystallization diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释如何控制材料生产中的晶粒尺寸，答案提供了多个步骤和方法的文字论述，符合简答题的特征。 | 知识层次: 题目要求对材料生产过程中晶粒尺寸控制的方法进行解释和论述，涉及多个工艺步骤（铸造、热加工、再结晶退火等）的综合应用，需要理解不同工艺参数对晶粒尺寸的影响，并进行概念关联和综合分析。虽然不涉及复杂计算，但需要多步骤的思维过程和工艺参数的协调控制。 | 难度: 在选择题型内，该题目属于较高难度，因为：" + }, + { + "idx": 683, + "question": "All symmetry elements present in macroscopic crystals must pass through the center of the crystal", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体对称元素基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念正误判断，仅需记忆晶体对称元素的基本定义即可作答，无需深入理解或分析。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 684, + "question": "The symmetry characteristic of the cubic crystal system is having four 3-fold axes", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（立方晶系的对称性特征是具有四个三重轴），并要求判断其正确性（√表示正确），这是典型的判断题形式 | 知识层次: 题目考查立方晶系对称性特征的基础概念记忆，仅需判断\"四个三次轴\"这一基本特征的正确性，属于定义性知识的直接应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断立方晶系的对称性特征是否正确，即是否具有四个三重轴。这属于基础概念的记忆性知识，不需要深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 685, + "question": "The core of microscopic symmetry elements is the translation axis", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述句要求判断对错（√表示正确），符合判断题的特征 | 知识层次: 题目考查对微观对称元素核心概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，这道题目属于非常基础的正误判断题，仅需要考生记忆微观对称元素的核心概念（平移轴）即可做出正确判断。题目不涉及概念理解或复杂陈述的分析，完全符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 686, + "question": "Amorphous silicon prepared by CVD method also possesses the four general characteristics of glass", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（\"Amorphous silicon prepared by CVD method also possesses the four general characteristics of glass\"），并要求判断其正误（答案给出\"×\"表示错误），这符合判断题的特征。 | 知识层次: 题目考查对非晶硅和玻璃基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需要考生记忆无定形硅的基本特性即可作答。在选择题型中，这类直接考察定义和分类的记忆性知识题目属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 687, + "question": "Summarize the applications of diffusion in materials science", + "answer": "The roles of atomic diffusion in materials include: nucleation and growth during crystal solidification; component undercooling in alloys; composition homogenization, retention of high-temperature microstructure characteristics during peritectic reaction non-equilibrium solidification, nucleation during solid-state phase transformation, grain boundary nucleation, grain boundary movement, grain boundary segregation, high-temperature creep, oxidation, welding, chemical heat treatment (such as carburization, nitriding, etc.), powder metallurgy, coating, and various other aspects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结扩散在材料科学中的应用，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目要求总结扩散在材料科学中的应用，涉及多个具体应用场景和概念关联，需要综合理解和分析扩散在不同材料过程中的作用，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生对扩散在材料科学中的多种应用有深入的理解和综合的分析能力。正确选项涵盖了扩散在多个不同过程中的作用，如晶体凝固、合金成分均匀化、固态相变等，这些知识点不仅需要记忆，还需要理解其背后的物理机制和相互关联。此外，题目要求考生能够将这些分散的概念整合起来，形成一个全面的认识，这属于多角度分析论述的层次。因此，在选择题型内，该题目的难度等级为4。" + }, + { + "idx": 688, + "question": "Order-disorder transformation refers to the transformation between crystals and non-crystals", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案给出的是×表示错误），符合判断题的特征 | 知识层次: 题目考查对有序-无序转变这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆\"有序-无序转变\"的定义即可判断对错，无需理解或分析复杂概念，解题步骤简单直接。" + }, + { + "idx": 689, + "question": "A solid solution is an amorphous solid that has dissolved impurity components", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（A solid solution is an amorphous solid that has dissolved impurity components），并要求判断其正确性（答案给出×表示错误），符合判断题的特征。 | 知识层次: 题目考查对固溶体（solid solution）基本概念的记忆和理解，需要判断陈述是否正确，属于基础概念记忆的范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆固体溶液的定义即可判断正误。在选择题型中，这类题目对知识点掌握深度要求最低，解题步骤最简单，属于最基础的难度等级。" + }, + { + "idx": 690, + "question": "Most solid-phase reactions are controlled by diffusion rates", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对固相反应控制机制这一基础概念的记忆和理解，属于基本原理的记忆性知识 | 难度: 该题目属于基础概念正误判断题，仅需记忆\"大多数固相反应由扩散速率控制\"这一基本原理即可作答。在选择题型中，这类直接考察定义和基本原理记忆的题目属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 691, + "question": "At low temperatures, the diffusion that generally occurs in crystals is intrinsic diffusion", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体中扩散类型的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆类，仅需判断\"低温下晶体中通常发生的扩散是内扩散\"这一陈述的正确性。在选择题型中，这属于最简单的正误判断题，无需复杂推理或概念比较，仅需对基本定义有记忆即可。因此符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 692, + "question": "In the wetting of solid-liquid interfaces, increasing the roughness of the solid surface necessarily improves wetting.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案以×表示错误，符合判断题的特征。 | 知识层次: 题目考查对固体-液体界面润湿现象中表面粗糙度影响的基本概念的理解，属于基础概念的记忆和简单应用。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅考察对固体-液体界面润湿基本原理的记忆，即表面粗糙度并不必然改善润湿性。不需要理解复杂概念或进行多步骤分析，只需识别陈述是否正确。属于最基础的概念判断题。" + }, + { + "idx": 693, + "question": "Summarize the role of dislocations in materials", + "answer": "Dislocations can greatly influence the performance of materials, and their roles in materials are diverse: (1) The plastic deformation of metallic materials is accomplished through dislocation motion. (2) Dislocations have a distorted stress field around them, which can strengthen materials through mechanisms such as cutting or bypassing second-phase particles. Increasing dislocation density during cold working can also strengthen materials, as can the formation of Cottrell atmospheres. Additionally, mutual intersections during dislocation motion or the formation of jogs and Lomer-Cottrell locks can strengthen materials, thereby affecting their strength. (3) Dislocations influence the precipitation of second phases and have an impact on solid-state phase transformations such as nucleation mechanisms during recrystallization. (4) The areas around dislocations serve as preferential diffusion pathways.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对位错在材料中的作用进行总结和论述，答案以文字解释和列举要点的方式呈现，符合简答题的特征。 | 知识层次: 题目要求对位错在材料中的多种作用进行综合分析和解释，涉及位错运动、应力场、强化机制、相变和扩散等多个方面的知识，需要深入理解和关联不同概念，并进行综合论述。 | 难度: 在选择题型中，该题目属于最高难度等级。正确选项不仅要求考生全面掌握位错在材料中的多种作用机制（包括塑性变形、强化机制、相变影响和扩散路径），还需要将这些复杂现象进行综合分析和机理解释。题目涉及多个高阶材料科学概念的交叉运用，且每个作用机制都需要深入理解其物理本质，这远超出简单记忆或单一概念应用的难度水平。在选择题型内，此类需要综合多个复杂机理进行推理判断的题目属于最难级别。" + }, + { + "idx": 694, + "question": "Sintering is a process that involves various physical and chemical changes", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（以×表示错误），符合判断题的特征 | 知识层次: 题目考查对烧结过程的基本概念的理解和记忆，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断题，仅需记忆烧结过程的基本定义即可判断正误，无需深入理解或分析多个概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 695, + "question": "The collection of all symmetry elements in a crystal structure is called", + "answer": "The crystal structure with space group $\\bf{F m}3m$ belongs to the (2) crystal family and (3) crystal system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对晶体结构中的对称元素集合进行命名，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对晶体结构和空间群的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆晶体结构的基本分类和空间群归属，属于基础概念记忆层次。题目直接给出了明确的关键词（crystal family和crystal system），且选项内容为定义性知识，无需复杂推理或概念整合。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 696, + "question": "In the cubic crystal system, the possible types of space lattices are (a) P, I, C (b) P, I, F (c) P, C, F (d) F, I, C", + "answer": "The unit cell is (1)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)-(d)中选择正确的空间点阵类型组合，符合选择题的特征 | 知识层次: 题目考查立方晶系中空间点阵类型的基本概念记忆，属于对晶体学基础知识的直接考察，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别立方晶系中可能的空间格子类型。正确选项直接对应记忆性知识，无需复杂分析或理解多个概念。因此，在选择题型内属于简单难度。" + }, + { + "idx": 697, + "question": "Ionic crystals typically reduce their surface energy through the polarization deformation and rearrangement of surface ions. Among the following ionic crystals, the one with the smallest surface energy is (a) CaF2 (b) PbF2 (c) PbI2 (d) BaSO4 (e) SrSO4", + "answer": "The main reasons for clay charging are: (11) _, (12) _, and (13) _", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择具有最小表面能的离子晶体，符合选择题的特征 | 知识层次: 题目要求考生理解离子晶体的表面能概念，并能够分析不同离子晶体的极化变形和离子重排对表面能的影响。这需要考生综合运用材料科学中的晶体结构和表面能相关知识，进行中等程度的分析和比较。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。题目要求考生理解离子晶体表面能的影响因素，包括极化变形和表面离子重排等概念，并能综合分析不同离子晶体的性质（如离子半径、极化能力、晶格结构等）来比较表面能大小。这需要考生具备较深的知识掌握和综合分析能力，超出了简单概念记忆或单一知识点的应用水平。" + }, + { + "idx": 698, + "question": "(a) Symmetry type (b) Point group (c) Collection of microscopic symmetry elements (d) Space group", + "answer": "When a small amount of $\\\\mathbf{CaO}$ is added to the $\\\\mathrm{Th}\\\\mathbf{O}_{2}$ lattice to form a solid solution, write the possible defect reaction equations and solid solution formulas: defect reaction equation (7) and corresponding solid solution formula (8). Defect reaction equation (9) and corresponding solid solution formula (10)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出可能的缺陷反应方程和固溶体公式，需要文字解释和论述，而不是选择、判断或数值计算。 | 知识层次: 题目要求写出缺陷反应方程和相应的固溶体公式，这需要理解缺陷化学的基本原理，并能够应用这些原理来分析具体的掺杂情况。虽然题目没有涉及复杂的计算或多步推理，但需要将多个概念（如缺陷类型、电荷平衡、化学计量等）关联起来，进行综合分析。这超出了简单记忆或直接套用的层次，属于中等应用。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅掌握缺陷反应方程和固溶体公式的基本概念，还需要进行多步计算和综合分析。具体来说，考生需要理解CaO掺杂ThO2的缺陷化学行为，写出可能的缺陷反应方程（7）和（9），并推导出相应的固溶体公式（8）和（10）。这涉及到对点缺陷类型、电荷平衡和化学计量关系的深入理解，以及在不同条件下的反应路径选择。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 699, + "question": "In the face-centered cubic crystal structure, the close-packed plane is (a) {001} plane (b) {011} plane (c) {111} plane", + "answer": "The main reasons for clay charging are: (11) (12) and (13)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查面心立方晶体结构中密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆面心立方晶体结构中最密排面的晶面指数即可。选项(c) {111} plane是晶体学中的基本常识，无需复杂分析或理解，属于简单概念识别层次。" + }, + { + "idx": 700, + "question": "The four structural parameters $z$, $R$, $X$, and $Y$ of the $\\mathrm{Na}{2}\\mathrm{{\\bfO}}\\cdot\\mathrm{Ca}\\mathrm{{\\bfO}}\\cdot\\mathrm{Al}{2}\\mathrm{{\\bfO}}{3}\\cdot2\\mathrm{SiO}{2}$ glass", + "answer": "$,1.{\\surd};2.{\\surd};3.{\\searrow};4.\\times;5.\\times;6.\\times;7.{\\surd};8.\\times;9.\\times;10.\\times_{\\mathrm{~o~}}$ II. 1. b; 2. d; 3. a; 4. a; 5. c; 6. c; 7. (A) c、(B) a; 8. a、c; 9.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目答案中包含多个选项的选择（如1. b; 2. d; 3. a等），符合选择题的特征 | 知识层次: 题目考查的是对材料科学中玻璃结构参数的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合能力。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生对玻璃结构参数的定义和分类有一定的理解和辨析能力。题目中的正确选项涉及多个参数的判断，需要考生能够区分不同参数的含义和应用，而不仅仅是简单的记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 701, + "question": "In the thermodynamic relation of diffusion coefficient, $\\\\left(1+\\\\frac{\\\\partial{\\\\ln{\\\\gamma_{i}}}}{\\\\partial{\\\\ln{N_{i}}}}\\\\right)$ is called the thermodynamic factor of diffusion coefficient. In non-ideal mixing systems: when the thermodynamic factor of diffusion coefficient $>0$, the diffusion result causes the solute to (A); when the thermodynamic factor of diffusion coefficient $<0$, the diffusion result causes the solute to (B). (a) segregation occurs (b) concentration remains unchanged (c) concentration tends to be uniform", + "answer": "On the curve of glass properties changing with temperature, there are two characteristic temperatures (18) and (19), and the viscosities corresponding to these two characteristic temperatures are (20) and (21) respectively.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（a）、（b）、（c）中选择正确的答案填入（A）和（B）的位置 | 知识层次: 题目涉及扩散系数的热力学因子及其在非理想混合系统中的影响，需要理解热力学因子的定义及其与扩散结果的关系。虽然题目给出了热力学因子的表达式，但需要考生理解其物理意义，并能够根据热力学因子的正负判断扩散结果。这需要一定的概念关联和综合分析能力，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解非理想混合系统中扩散系数的热力学因子概念，并能够分析其正负值对溶质扩散结果的影响。题目涉及多个概念的关联和综合分析，解题步骤较为复杂，需要较强的应用能力和判断力。" + }, + { + "idx": 702, + "question": "Network former", + "answer": "A substance with single bond energy $\\geq335\\mathrm{kJ/mol}$ that can form glass alone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Network former\"进行定义和解释，答案提供了详细的文字描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对\"Network former\"这一基本概念的定义和特性的记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对\"Network former\"基础定义的记忆，即能够单独形成玻璃且单键能量≥335kJ/mol的物质。题目不涉及概念解释或复杂体系分析，属于最基础的定义简答类型，符合等级1标准。" + }, + { + "idx": 703, + "question": "In the phase transformation of quartz, the one that belongs to reconstructive transformation is (a) $\\\\alpha\\\\cdot$ quartz $=====\\\\alpha\\\\cdot$ tridymite (b) $\\\\alpha\\\\cdot$ quartz $\\\\mathbf{\\\\mu}=====\\\\beta\\\\mathbf{\\\\sigma}$ quartz (c) $\\\\alpha\\\\cdot$ tridymite $=====\\\\alpha\\\\cdot$ quartz (d) $\\\\alpha\\\\cdot$-cristobalite $\\\\begin{array}{r}{======\\\\beta.}\\\\end{array}$ cristobalite", + "answer": "Intrinsic diffusion is the migration of particles caused by (22), and the activation energy of intrinsic diffusion consists of two parts: (23) and (24). The relationship between the diffusion coefficient and temperature is given by: (25).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案，属于选择题类型 | 知识层次: 题目考查石英相变类型的基本概念记忆，特别是重构型相变的识别，属于基础概念的记忆和理解范畴。 | 难度: 在选择题中属于较高难度，需要理解石英相变中的重构型转变（reconstructive transformation）和位移型转变（displacive transformation）的区别，并能正确识别具体相变类型。题目涉及多个石英变体的相变过程，需要考生对每种相变的特点有深入理解才能做出正确选择。" + }, + { + "idx": 704, + "question": "First-order phase transition", + "answer": "During the phase transition, the chemical potentials of the two phases are equal, but the first-order partial derivatives of the chemical potential are not equal. A first-order phase transition involves latent heat and changes in volume.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"First-order phase transition\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点 | 知识层次: 题目考查对一级相变基本概念的记忆和理解，包括化学势相等但一阶导数不等、潜热和体积变化等特征，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分化学势的一阶偏导数在相变中的不同表现，以及一级相变的特征（如潜热和体积变化）。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 705, + "question": "In the sintering process, the mass transfer method that only changes the pore shape without causing shrinkage of the green body is (a) surface diffusion (b) flow mass transfer (c) evaporation-condensation (d) grain boundary diffusion", + "answer": "Martensitic transformation has the following characteristics: (26), (27), (28), and (29)_, etc. IV. Term Explanation (15 points) (Choose five questions; if all are answered, only the first five will be graded) 1. Network former 2. First-order phase transition 3. Schottky defect 4. Polymorphism 5. Wetting 6. Homogeneous nucleation 7. Non-stoichiometric structural defects 8. Grain growth", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（a）表面扩散、（b）流动质量传递、（c）蒸发-凝聚、（d）晶界扩散中选择正确的烧结过程中仅改变孔隙形状而不引起坯体收缩的质量传递方法。 | 知识层次: 题目考查烧结过程中质量传递方式的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目需要理解烧结过程中不同质量传递方式的特点，并能够区分它们对坯体收缩的影响。虽然涉及多个概念，但选项之间的区分度较高，属于概念理解和简单辨析的难度层次。" + }, + { + "idx": 706, + "question": "Polymorphism", + "answer": "Substances with the same chemical composition can form crystals with different structures under different thermodynamic conditions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Polymorphism\"进行解释说明，答案是以文字形式给出的概念性描述，符合简答题的特征 | 知识层次: 题目考查对多晶型（Polymorphism）这一基础概念的记忆和理解，要求解释不同热力学条件下相同化学组成的物质可以形成不同晶体结构的现象。这属于材料科学中的基本原理和定义性知识，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。题目考察的是对\"多晶型\"这一基础概念的理解和描述，需要考生能够准确识别并解释不同热力学条件下相同化学成分物质可以形成不同晶体结构的现象。虽然涉及一定的概念理解，但不需要复杂的分析或比较，属于概念解释和描述层次的难度。" + }, + { + "idx": 707, + "question": "What are the characteristics of pore changes during secondary recrystallization", + "answer": "During secondary recrystallization, pores are encapsulated within the grains", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述二次再结晶过程中孔隙变化的特征，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目涉及对二次再结晶过程中孔隙变化的特征描述，需要理解再结晶的基本原理，并能够将孔隙行为与晶粒生长过程关联起来进行分析。这属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解二次再结晶过程中孔隙变化的基本概念，并能够将孔隙被晶粒包裹这一特征与二次再结晶过程关联起来。虽然不需要多步计算，但需要对材料科学中的再结晶过程有较好的理解，属于中等应用层次的知识点。" + }, + { + "idx": 708, + "question": "Characteristics of grain growth", + "answer": "Grain growth is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution. Within the green body, grain sizes grow uniformly; during grain growth, pores remain at grain boundaries or grain boundary junctions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Characteristics of grain growth\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征 | 知识层次: 题目考查晶粒生长的基本概念和特征，属于定义和基本原理的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解和记忆晶粒生长的基本定义和特征，包括晶粒尺寸的变化、热处理过程中的行为以及孔隙的位置等。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要进行复杂的比较分析或推理。因此，难度等级为2。" + }, + { + "idx": 709, + "question": "Grain growth", + "answer": "is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Grain growth\"进行文字解释和论述，答案是一个完整的定义性陈述，符合简答题的特征。 | 知识层次: 题目考查对晶粒生长这一基础概念的定义和基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对\"grain growth\"这一基础概念的定义记忆，属于最基本的知识点掌握要求。正确选项直接给出了定义性描述，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 711, + "question": "Wetting", + "answer": "When the Gibbs free energy of the system decreases after a solid comes into contact with a liquid, it is called wetting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“Wetting”进行文字解释和论述，答案提供了定义和条件说明，符合简答题的特征 | 知识层次: 题目考查对wetting这一基础概念的定义和基本原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接考查对\"wetting\"这一基础概念的定义记忆，只需识别Gibbs自由能降低这一关键特征即可作答。选择题型中此类直接考查定义的题目属于最低难度层级，不需要任何解释或分析过程。" + }, + { + "idx": 712, + "question": "What are the process characteristics of secondary recrystallization", + "answer": "It is an abnormal growth process where a few large grains grow at the expense of fine grains. It is the abnormal growth of individual grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释二次再结晶的过程特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查对二次再结晶过程特性的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对二次再结晶的过程特征有较为清晰的理解，能够区分正常晶粒生长和异常晶粒生长的差异。正确选项不仅描述了二次再结晶的基本特征（异常生长过程），还进一步解释了其具体表现（少数大晶粒消耗小晶粒）。这要求考生不仅记住定义，还要理解其背后的原理，属于概念解释和描述的层次。" + }, + { + "idx": 713, + "question": "Non-stoichiometric structural defects", + "answer": "The composition of certain compounds deviates from their stoichiometric ratio depending on the nature of the surrounding atmosphere and the magnitude of pressure. Such compounds are called non-stoichiometric compounds. The defects arising from the deviation in composition from the stoichiometric ratio are called non-stoichiometric structural defects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对非化学计量结构缺陷进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征 | 知识层次: 题目考查非化学计量结构缺陷的基本定义和概念，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述非化学计量结构缺陷的定义及其形成原因。这比简单的定义记忆（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。考生需要能够解释概念并理解其背后的基本原理，这在选择题型中属于中等难度的要求。" + }, + { + "idx": 714, + "question": "There are countless translational axes in the crystal structure", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体结构中平移轴的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆晶体结构中存在无数平移轴这一基本原理即可做出正确选择，无需复杂理解或分析步骤。" + }, + { + "idx": 715, + "question": "Pauling's rules apply to all crystal structures", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征 | 知识层次: 题目考查对Pauling规则适用范围的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念正误判断题，仅需记忆Pauling规则的基本适用范围即可作答。在选择题型中，这类题目仅测试学生对基本定义的记忆能力，无需理解或分析复杂概念，因此属于最低难度等级。" + }, + { + "idx": 716, + "question": "The ratio of the intercepts of a crystal plane on the three coordinate axes must be a simple integer ratio", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体学中晶面截距比的基本概念，属于基础知识的记忆和理解层面，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念正误判断，仅需记忆晶体平面截距比的基本定义即可作答，无需理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 717, + "question": "The two most closely packed arrangements of equal-sized spheres", + "answer": "There are mainly cubic closest packing and hexagonal closest packing; the cubic closest packing arrangement has the close-packed planes arranged in the sequence ABCABC..., while the hexagonal closest packing arrangement has the close-packed planes arranged in the sequence ABAB...", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种最紧密排列的等径球体排列方式，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对等径球最密堆积排列方式的基础概念记忆和理解，包括立方最密堆积和六方最密堆积的定义及其堆垛序列。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生区分两种紧密堆积方式（立方最密堆积和六方最密堆积）的排列序列（ABCABC...和ABAB...）。这要求考生不仅记住定义，还需要理解并描述两种堆积方式的差异，属于概念解释和描述的层次。" + }, + { + "idx": 718, + "question": "Types and quantitative relationship of voids", + "answer": "When equal-sized spheres are closely packed, the main types of voids are octahedral voids and tetrahedral voids. When $\\pmb{n}$ spheres are closely packed, there will be $\\textbf{\\em n}$ octahedral voids and $2n$ tetrahedral voids", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释紧密堆积中空隙的类型和数量关系，答案提供了详细的文字解释和定量关系，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，主要涉及空隙的类型和数量关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生掌握两种空隙类型（八面体空隙和四面体空隙）的定义及其数量关系。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。题目要求考生能够理解和描述空隙类型及其数量关系，符合等级2的难度标准。" + }, + { + "idx": 719, + "question": "The dislocation line of an edge dislocation is parallel to the slip direction.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对位错线方向与滑移方向关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆边缘位错的位错线与滑移方向的关系即可作答，无需深入理解或分析。" + }, + { + "idx": 720, + "question": "Generally speaking, grain boundaries are the main diffusion channels for pores to reach the exterior of the sintered body.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查对晶界作为烧结体中孔隙扩散主要通道这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶界是烧结体中孔隙扩散的主要通道这一基本原理即可作答，无需深入理解或分析多个概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 721, + "question": "What is the relationship between secondary recrystallization and the particle size of the raw material", + "answer": "Secondary recrystallization is also related to the particle size of the raw material", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释二次再结晶与原材料颗粒尺寸之间的关系，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及二次再结晶与原材料颗粒尺寸之间的关系，需要理解两者之间的关联并进行综合分析，属于中等应用层次的知识点。 | 难度: 在选择题中属于中等难度，需要理解二次再结晶与原料颗粒尺寸之间的关系，并进行概念关联和综合分析。虽然题目涉及的知识点较为专业，但在选择题型中，通过正确选项可以直接判断出答案，不需要进行多步计算或深度关联性分析。" + }, + { + "idx": 722, + "question": "Feldspar is a silicate crystal with a layered structure", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对长石（Feldspar）晶体结构这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆长石（Feldspar）的基本结构特征即可作答。题目直接给出陈述，要求判断其正确性，无需复杂推理或概念间的关联分析，符合等级1的难度标准。" + }, + { + "idx": 723, + "question": "For some materials, no matter how fast the cooling rate is, it is impossible to form a glass", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征 | 知识层次: 题目考查对材料科学中玻璃形成能力的基本概念的理解，涉及冷却速率与玻璃形成之间的关系，属于基础概念的记忆和简单判断。 | 难度: 该题目属于基础概念正误判断题，仅需记忆材料科学中关于玻璃形成的基本原理即可作答。在选择题型中，这类题目仅需识别正确选项，不涉及复杂概念理解或分析过程，属于最简单的难度等级。" + }, + { + "idx": 724, + "question": "The flow of clay slurry belongs to plastic flow", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The flow of clay slurry belongs to plastic flow），要求判断其正确性（√），这是典型的判断题形式。答案只需判断对错，不需要选择或解释。 | 知识层次: 题目考查对粘土浆流动性质的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆粘土浆的流动类型属于塑性流动这一基本定义即可作答。在选择题型中，这类仅需识别基础概念正误的题目属于最低难度等级。" + }, + { + "idx": 725, + "question": "The Jander equation has a wider applicable range than the Ginstling equation", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The Jander equation has a wider applicable range than the Ginstling equation），并要求判断其正误（答案：×），这符合判断题的特征。 | 知识层次: 题目考查对Jander方程和Ginstling方程适用范围的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆Jander方程和Ginstling方程的适用范围即可做出判断，无需深入理解或分析。" + }, + { + "idx": 726, + "question": "Non-stoichiometric structural defects are a type of impurity defect caused by doping", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案用×表示错误），符合判断题的特征 | 知识层次: 题目考查对非化学计量结构缺陷类型的基本概念记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念正误判断题，仅需记忆非化学计量缺陷的定义和分类即可作答。在选择题型中，这类题目仅考察最基本的概念记忆能力，无需理解或分析过程，因此属于最低难度等级。" + }, + { + "idx": 727, + "question": "At low temperatures, the diffusion that generally occurs in crystals is extrinsic diffusion", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体扩散类型的基础概念记忆，特别是低温下扩散类型的判断，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆低温下晶体扩散类型的基本定义即可作答，无需复杂理解或分析步骤。" + }, + { + "idx": 728, + "question": "Most solid-phase reactions are controlled by the diffusion rate.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对固相反应控制因素这一基本概念的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题型中属于基本概念正误判断，仅需记忆固体相反应通常由扩散速率控制这一基本原理即可判断正误，无需深入理解或分析复杂概念。" + }, + { + "idx": 729, + "question": "During the cooling process of the melt, the greater the degree of undercooling, the greater the overall crystallization rate", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对结晶速率与过冷度关系这一基本概念的记忆和理解，属于材料科学中的基础知识点。 | 难度: 在选择题型中，此题属于基本概念正误判断，仅需记忆并确认\"过冷度与结晶速率的关系\"这一基础概念的正确性，无需深入理解或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 730, + "question": "A space lattice is formed by arranging in space with a regular repetition. (a) atoms (b) ions (c) geometric points (d) molecules", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（a、b、c、d）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查空间点阵的基本概念，即由几何点在空间中规则排列形成，属于基础概念的记忆和理解。 | 难度: 该题目属于基础概念记忆类型，仅需识别\"space lattice\"的定义即可直接选择正确答案。在选择题型中属于最简单的直接记忆类题目，无需理解或辨析其他选项。正确选项(c) geometric points是空间点阵的标准定义，属于材料科学中最基础的概念记忆层次。" + }, + { + "idx": 731, + "question": "In a narrow sense, the phase transition process is a physical change process", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对相变过程基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆狭义相变过程的定义即可作答，无需深入理解或分析。" + }, + { + "idx": 733, + "question": "The crystal structure with point group $\\\\bf F m3m$ belongs to the crystal system. (a) cubic (b) hexagonal (c) tetragonal (d) orthorhombic", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)(b)(c)(d)中选择正确答案 | 知识层次: 题目考查对晶体结构和点群分类的基础概念记忆，只需识别$F m3m$属于立方晶系即可，无需复杂分析或计算。 | 难度: 该题目属于基础概念记忆类型，仅需识别点群符号$F m3m$对应的晶系即可。在选择题型中，这是最直接的记忆性知识应用，无需复杂理解或辨析步骤。" + }, + { + "idx": 734, + "question": "In the $\\\\mathbf{ABO}_{3}$ (perovskite) type structure, B ions occupy (a) tetrahedral voids (b) octahedral voids (c) cubic voids (d) trigonal prismatic voids", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)-(d)中选择B离子在钙钛矿结构中所占据的空隙类型，符合选择题的特征 | 知识层次: 题目考查对钙钛矿结构中离子占据位置的基础概念记忆，属于定义和分类层面的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆ABO3钙钛矿结构中B离子占据的间隙类型（八面体间隙），无需复杂分析或概念辨析。属于最简单的直接记忆类题目。" + }, + { + "idx": 735, + "question": "Montmorillonite belongs to which type of silicate structure. (a) Island silicate structure (b) Layered silicate structure (c) Chain silicate structure (d) Framework silicate structure", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确的硅酸盐结构类型，符合选择题的特征 | 知识层次: 题目考查对硅酸盐结构分类的基础概念记忆，只需识别蒙脱石属于层状硅酸盐结构即可，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别蒙脱石属于层状硅酸盐结构这一直接记忆性知识点，无需复杂辨析或深度理解。" + }, + { + "idx": 736, + "question": "What property must the medium exhibit for slurry peptization? (a) Acidic (b) Alkaline (c) Neutral", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（a）Acidic、（b）Alkaline、（c）Neutral中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对浆料胶溶作用所需介质性质的基础概念记忆，属于基本原理的记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆\"slurry peptization\"所需介质的性质即可作答。在选择题型中属于最简单的难度等级，无需理解或辨析，仅需识别正确选项。" + }, + { + "idx": 737, + "question": "In the non-stoichiometric compound $\\\\operatorname{Cd}_{1+x}0$, the lattice defect present is (a) anion vacancy (b) cation vacancy (c) anion interstitial (d) cation interstitial", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)到(d)中选择正确答案 | 知识层次: 题目考查对非化学计量化合物中晶格缺陷类型的基础概念记忆和理解，只需识别Cd1+xO中存在的缺陷类型即可，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及非化学计量化合物的晶格缺陷这一基础概念，但需要考生理解并区分不同类型的缺陷（如空位和间隙）。正确选项（d）要求考生能够识别出阳离子间隙的存在，这需要一定的概念理解和简单辨析能力，而不仅仅是直接记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 738, + "question": "Which valence state of cations must be present in the exchange of originally adsorbed cations in clay for mud peptization? (d) Monovalent (e) Divalent (f) Trivalent", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项（d、e、f）中选择一个正确答案（d），符合选择题的特征 | 知识层次: 题目考查粘土中阳离子交换的基本概念，即单价阳离子在泥浆胶溶中的作用，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别黏土中阳离子交换的基本原理（单价阳离子促进泥浆胶溶）。题目直接给出定义性知识，无需理解或辨析其他选项的化学意义，属于最简单的概念识别题。" + }, + { + "idx": 739, + "question": "The essence of crystals", + "answer": "is the periodic repetition of particles in three-dimensional space", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对晶体的本质进行文字解释和论述，答案是一个简短的文字描述，符合简答题的特征。 | 知识层次: 题目考查晶体本质的基本概念记忆和理解，仅需回答周期性重复排列的定义，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅考察对晶体本质的基础定义记忆，属于最基础的概念性知识。正确选项直接给出了晶体的周期性重复特征，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 740, + "question": "What are the two types of arrangements in the closest packing of equal-sized spheres?", + "answer": "(2) Cubic close packing; (3) Hexagonal close packing", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两种最密堆积方式，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对等径球最密堆积两种排列方式的基础概念记忆，属于材料科学中最基本的晶体结构知识，仅需回忆和识别两种类型（立方最密堆积和六方最密堆积），不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆两种最密堆积方式的名称（立方最密堆积和六方最密堆积），属于基础概念的直接回忆，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 741, + "question": "In the closest packing of equal-sized spheres, what is the packing arrangement of cubic close packing?", + "answer": "(4) ABCABC……", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项编号和内容的形式给出 | 知识层次: 题目考查的是立方密堆积（cubic close packing）的基本排列方式，即ABCABC……的堆叠顺序。这属于材料科学中晶体结构的基础概念记忆，不需要复杂的分析或应用，只需对基本概念的记忆和理解即可回答。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需直接回忆立方密堆积的排列方式（ABCABC……），无需理解或辨析其他概念。题目要求的知识掌握深度和解题步骤都非常简单，属于最基础的记忆性题目。" + }, + { + "idx": 742, + "question": "Ionic crystals usually reduce their surface energy through the polarization deformation and rearrangement of surface ions. Among the following ionic crystals, the one with the smallest surface energy is (a) $\\\\mathrm{CaF}{2}$ (b) $\\\\mathrm{Pb}\\\\mathrm{F}{2}$ c) $\\\\mathrm{Pb}\\\\mathbf{I}{2}$ (d) $\\\\mathbf{BaSO{4}}$ (e) SrsO4", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案 | 知识层次: 题目要求考生理解离子晶体表面能的概念，并能够分析不同离子晶体的极化变形和离子重排对表面能的影响。这需要考生将多个概念（如离子极化、离子半径、晶格能等）进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题型中属于较高难度，需要综合理解离子晶体表面能的影响因素（如离子极化率、晶格能等），并比较不同化合物的离子特性（如PbI2中I-的大离子半径和高极化率导致表面能显著降低）。解题过程涉及多个概念的综合分析（极化效应、离子半径、晶格类型）以及化合物性质的横向比较，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 743, + "question": "In the closest packing of equal large spheres, what is the packing arrangement of hexagonal close packing?", + "answer": "(5) ABAB……", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项编号形式给出 | 知识层次: 题目考查对六方最密堆积（hexagonal close packing）排列方式的基础概念记忆，只需要记住其层序排列为ABAB...即可回答，不涉及复杂计算或分析。 | 难度: 在选择题型中，该题目仅需要考生记忆并识别六方最密堆积（hexagonal close packing）的排列方式ABAB……，属于基础概念的直接记忆，无需理解或辨析其他复杂概念。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 744, + "question": "The basis for classifying silicate crystals is (6)", + "answer": "[ $\\mathrm{Si}0{4}$ connection method", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释硅酸盐晶体分类的基础，需要文字描述和论述，答案给出了具体的分类依据（[ $\\mathrm{Si}0{4}$ connection method），属于简答题类型 | 知识层次: 题目考查对硅酸盐晶体分类基础的记忆和理解，主要涉及硅氧四面体连接方式这一基本概念，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求考生记忆并识别硅酸盐晶体分类的基础依据（$\\mathrm{Si}0_{4}$连接方式），无需解释或分析概念关系，属于最基础的概念记忆性知识，且选项直接指向核心定义，解题步骤简单明确。" + }, + { + "idx": 745, + "question": "In the face-centered cubic crystal structure, the close-packed plane is (7)", + "answer": "{111} plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的知识点（面心立方晶体结构中的密排面），答案是一个特定的晶体学平面（{111} plane），不需要计算或选择，属于简答题类型 | 知识层次: 题目考查面心立方晶体结构中密排面的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需考生记住面心立方晶体结构中密排面的晶面指数{111}即可作答。题目不涉及任何概念解释或复杂分析过程，完全基于对基本定义的直接回忆，因此属于最简单的难度等级1。" + }, + { + "idx": 746, + "question": "After the interaction between water and clay, what can be formed around the clay colloidal particles as the distance increases: (8) what?", + "answer": "Firmly bound water", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个具体的术语而非从多个选项中选择或判断对错，也不涉及计算。 | 知识层次: 题目考查对粘土胶体颗粒周围水分子分布的基本概念记忆，特别是\"firmly bound water\"这一术语的定义和形成原理的理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即\"firmly bound water\"这一术语的定义。学生只需识别并回忆该特定概念即可作答，无需进行概念解释或复杂分析，属于最简单的记忆性知识考查。" + }, + { + "idx": 747, + "question": "What is one of the main factors that determines the concentration of component defects?", + "answer": "Doping amount", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释一个主要因素，答案需要文字解释而非选择或判断 | 知识层次: 题目考查的是对缺陷浓度决定因素的基本概念记忆和理解，属于材料科学中的基础知识点。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"掺杂量\"(Doping amount)这一基础概念作为影响组分缺陷浓度的主要因素。题目涉及的知识层次为基础概念记忆，不需要解释或分析，属于最简单的定义识别类选择题。" + }, + { + "idx": 748, + "question": "What are the two main factors that determine the concentration of component defects?", + "answer": "Solid solubility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释两个主要因素，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查的是对材料科学中缺陷浓度决定因素的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的定义性知识（固体溶解度），不需要进行概念解释或复杂体系阐述。题目直接考查对\"component defects浓度决定因素\"这一基本定义的记忆，属于最基础的知识点掌握要求。" + }, + { + "idx": 749, + "question": "On the curve of glass properties changing with temperature, what is the first characteristic temperature?", + "answer": "Tg", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的术语(Tg)，不需要计算或选择，也不需要判断对错，符合简答题的特征 | 知识层次: 题目考查对玻璃特性温度曲线中第一个特征温度（Tg）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对玻璃特性温度曲线中最基础的定义性知识（Tg温度）的记忆，无需解释或分析过程，属于最基础的概念记忆层次。" + }, + { + "idx": 750, + "question": "In the ${\\\\bf R O}\\\\mathrm{-SiO}{2}$ system, the order of the size of the immiscibility regions for: (1) $\\\\mathbf{Mg0-SiO}{2}$; (2) $\\\\mathbf{CaO}\\\\mathbf{-SiO}{2}$; (3) $\\\\mathbf{SrO}\\\\mathbf{-SiO}{2}$; (4) BaO$\\\\mathrm{SiO}_{2}$ is (a)$\\\\left(1\\\\right)>\\\\left(2\\\\right)>\\\\left(3\\\\right)>\\\\left(4\\\\right)$(b)(4)>(3)>(2)>(1)(c)$\\\\left(2\\\\right)>\\\\left(1\\\\right)>\\\\left(3\\\\right)>\\\\left(4\\\\right)$ (d $)(3)>(4)>(2)>(1)$", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择正确的顺序排列，属于选择题类型 | 知识层次: 题目要求对不同氧化物-SiO2系统中的不混溶区大小进行排序，这需要理解离子半径对相图不混溶区的影响，并能够综合分析不同氧化物的特性（如离子半径变化趋势）来推断不混溶区的大小顺序。这属于中等应用层次，涉及多步分析和概念关联。 | 难度: 在选择题中属于较高难度，需要综合理解RO-SiO2系统中不同氧化物的不混溶区域大小规律，并掌握碱土金属离子半径对相分离的影响。题目要求考生将多个概念（离子半径效应、相图特征）进行关联分析，并正确排序四种系统的相对大小关系，解题步骤涉及多步逻辑判断和比较。虽然题目提供了选项引导，但正确解答需要较深入的材料科学知识背景和综合分析能力。" + }, + { + "idx": 751, + "question": "On the curve of glass properties changing with temperature, what is the second characteristic temperature?", + "answer": "Tr", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的术语（Tr），这属于需要简短文字回答的问题类型，而不是从多个选项中选择或进行判断或计算。 | 知识层次: 题目考查玻璃特性温度曲线中的第二个特征温度的定义和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即玻璃特性温度曲线的第二个特征温度的定义（Tr）。题目不涉及任何解释、分析或比较步骤，属于最基础的定义简答类型。" + }, + { + "idx": 752, + "question": "As a result of what reason, 'compositional defects' are inevitably produced in the crystal structure?", + "answer": "Doping of non-equivalent ions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释“compositional defects”产生的原因，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查的是对\"compositional defects\"产生原因的基础概念记忆和理解，只需要回答掺杂非等价离子这一基本原理即可，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接询问晶体结构中\"compositional defects\"产生的原因，正确选项\"Doping of non-equivalent ions\"是该缺陷的标准定义性答案，无需复杂推理或概念比较。学生只需记住基础概念即可作答，符合选择题型中最基础的知识记忆要求。" + }, + { + "idx": 753, + "question": "Methods to prevent secondary recrystallization", + "answer": "Methods to prevent secondary recrystallization: control sintering temperature, sintering time, control the uniformity of raw material particle size, and introduce sintering additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举防止二次再结晶的方法，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目要求列举防止二次再结晶的方法，涉及对烧结温度、时间、原料颗粒均匀性和烧结添加剂等多个因素的综合考虑，需要将多个概念关联起来进行分析和应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及防止二次再结晶的方法，要求考生掌握烧结温度、烧结时间、原料颗粒均匀性和烧结添加剂等多个因素的综合影响。虽然不需要复杂的计算，但需要对材料科学中的相关概念有较深的理解和关联能力。" + }, + { + "idx": 754, + "question": "After the interaction between water and clay, what can be found around the clay colloidal particles as the distance increases: (10) what?", + "answer": "Free water", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用简短的文字回答具体问题，答案形式为自由文本而非选择或判断 | 知识层次: 题目考查的是对粘土胶体颗粒与水相互作用后周围水分分布的基本概念记忆，属于基础概念的理解和记忆层次，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即水与黏土相互作用后黏土胶体颗粒周围随着距离增加会出现什么（自由水）。题目仅要求识别定义性知识，无需解释或分析，属于最基础的定义简答级别。" + }, + { + "idx": 755, + "question": "After water interacts with clay, what can be found around the clay colloidal particles as the distance increases: (9) what?", + "answer": "Loosely bound water", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述\"what can be found around the clay colloidal particles as the distance increases\"，答案\"Loosely bound water\"是一个简短的文字描述，符合简答题的特征。 | 知识层次: 题目考查的是对粘土胶体颗粒周围水分子分布的基础概念记忆，属于材料科学中关于粘土-水相互作用的基本原理知识，仅需记忆和理解即可回答。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即黏土胶体颗粒周围随着距离增加会出现什么（松散结合水）。题目不涉及概念解释或复杂体系分析，仅需回忆基本定义即可作答，属于最基础的选择题难度等级。" + }, + { + "idx": 756, + "question": "Briefly describe the characteristics of grain growth", + "answer": "Characteristics of grain growth: Grain growth is a process during heat treatment of a strain-free material where the average grain size continuously increases without altering its distribution. Within the bulk, grain sizes grow uniformly; during grain growth, pores remain at grain boundaries or their junctions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述晶粒生长的特征，答案以文字解释和论述的形式呈现，符合简答题的特点 | 知识层次: 题目考查对晶粒生长特性的基本概念记忆和理解，不涉及复杂分析或综合应用 | 难度: 在选择题型中，该题目要求考生理解和描述晶粒生长的基本特征，涉及对定义和基本原理的记忆与解释。虽然需要一定的概念理解，但不需要复杂的分析或比较，属于中等偏下的难度等级。" + }, + { + "idx": 757, + "question": "Causes of secondary recrystallization", + "answer": "Causes of secondary recrystallization: uneven particle size of raw materials, excessively high sintering temperature, and too fast sintering rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释二次再结晶的原因，答案以文字解释和论述的形式给出，没有选项、判断或计算要求 | 知识层次: 题目考查对二次再结晶原因的基础概念记忆和理解，答案直接列举了三个常见原因，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和记忆次级再结晶的多个具体原因（原料颗粒大小不均、烧结温度过高、烧结速率过快），而不仅仅是简单的定义或单一因素。这要求考生对相关概念有一定的理解和整合能力，但不需要进行复杂的分析或比较。" + }, + { + "idx": 758, + "question": "Briefly describe the characteristics of secondary recrystallization", + "answer": "Characteristics of secondary recrystallization: it is an abnormal growth process where a few large grains grow at the expense of fine grains. It involves the abnormal growth of individual grains; during secondary recrystallization, pores are enclosed within the grains; secondary recrystallization is also related to the particle size of the raw material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述二次再结晶的特征，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对二次再结晶特性的基本概念记忆和理解，涉及定义和简单描述，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生对二次再结晶的特征进行描述，涉及多个关键点（异常生长过程、大晶粒消耗小晶粒、孔隙被包裹、与原料粒径的关系）。虽然需要记忆和理解多个概念，但不需要复杂的分析或比较，属于概念解释和描述的难度层次。" + }, + { + "idx": 759, + "question": "What is intrinsic diffusion?", + "answer": "Intrinsic diffusion: refers to the migration phenomenon caused by vacancies originating from the intrinsic thermal defects of the crystal. The activation energy of intrinsic diffusion consists of two parts: the vacancy formation energy and the particle migration energy. At high temperatures, intrinsic diffusion predominates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"intrinsic diffusion\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即intrinsic diffusion的定义和基本原理，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。题目要求考生理解并记忆\"intrinsic diffusion\"的定义及其关键组成部分（空位形成能和粒子迁移能），并知道其在高温条件下的主导性。虽然涉及两个能量概念，但整体仍属于单一概念的解释层面，不需要进行多个概念的比较或复杂分析。" + }, + { + "idx": 760, + "question": "In the orthorhombic crystal system, the (001) plane must be perpendicular to the (110) plane", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对正交晶系中晶面垂直关系的基本概念记忆和理解，属于晶体学基础知识的直接应用，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅考察对正交晶系中晶面垂直关系的基础定义记忆，不需要理解或分析多个概念，解题步骤非常简单直接。" + }, + { + "idx": 761, + "question": "What is extrinsic diffusion?", + "answer": "Extrinsic diffusion: It is a migration phenomenon caused by vacancies generated from the doping of inequivalent impurity ions. The activation energy of extrinsic diffusion only includes the migration energy of mass points, and extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"extrinsic diffusion\"进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对\"extrinsic diffusion\"这一基本概念的定义和特征的理解与记忆，属于基础概念层次。答案中主要涉及定义、产生原因和特点的描述，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然涉及了\"extrinsic diffusion\"的定义和基本原理，但不需要进行复杂的概念体系阐述或比较分析。正确选项提供了明确的定义和关键特征（如激活能组成、温度影响等），属于中等难度的概念性选择题。" + }, + { + "idx": 762, + "question": "What are the characteristics of extrinsic diffusion?", + "answer": "The activation energy of extrinsic diffusion only includes the energy of particle migration, and extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释外在扩散的特征，答案提供了文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查的是外扩散（extrinsic diffusion）的基本特征，包括激活能的组成和温度影响，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分\"extrinsic diffusion\"的特征，包括激活能量的组成和温度影响。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。正确选项包含了两个关键特征，考生需要同时掌握这两个知识点才能正确作答。" + }, + { + "idx": 763, + "question": "In macroscopic crystals, the symmetry elements present must all pass through the center of the crystal", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体对称性基础概念的简单记忆和理解，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆层次，仅需判断对称元素是否必须通过晶体中心这一基本定义的正确性。在选择题型中，这种直接的正误判断题属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 764, + "question": "What are the similarities between solid-phase sintering and liquid-phase sintering?", + "answer": "The driving force for sintering is surface energy in both cases, and the sintering process consists of stages such as particle rearrangement, pore filling, and grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种烧结过程的相似之处，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较两种烧结过程的相似性，涉及对烧结驱动力和烧结阶段的理解和应用，需要将多个概念关联起来进行综合分析，但不需要深入机理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解固相烧结和液相烧结的基本概念，并能够比较两者的相似之处。题目要求考生识别烧结驱动力和烧结过程的共同阶段，这涉及多个概念的关联和综合分析。虽然不需要多角度分析或深度关联性分析，但仍需要一定的知识掌握和思考步骤。" + }, + { + "idx": 765, + "question": "What are the characteristics of intrinsic diffusion?", + "answer": "The activation energy of intrinsic diffusion consists of two parts: vacancy formation energy and particle migration energy, and intrinsic diffusion dominates at high temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释intrinsic diffusion的特性，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对固有扩散（intrinsic diffusion）基本特征的理解和记忆，包括其激活能的组成部分以及在高温下的主导作用。这属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分本征扩散的两个关键组成部分（空位形成能和粒子迁移能），以及掌握本征扩散在高温条件下的主导作用。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 766, + "question": "Diamond, graphite, and carbon nanotubes are allotropes of carbon", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Diamond, graphite, and carbon nanotubes are allotropes of carbon），并要求判断其正误（答案：√），这符合判断题的特征 | 知识层次: 题目考查对碳的同素异形体的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念正误判断，仅需记忆碳的三种同素异形体名称即可作答，无需理解或分析复杂概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 767, + "question": "What are the differences between solid-phase sintering and liquid-phase sintering?", + "answer": "Due to the faster mass transfer rate by flow compared to diffusion, liquid-phase sintering has a higher densification rate and requires a lower sintering temperature. Additionally, the rate of the liquid-phase sintering process is also related to factors such as the amount of liquid phase, its properties (viscosity, surface tension, etc.), the wetting condition between the liquid and solid phases, and the solubility of the solid phase in the liquid phase. The factors influencing liquid-phase sintering are more complex than those in solid-phase sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述固相烧结和液相烧结之间的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较固相烧结和液相烧结的差异，并详细解释液相烧结的速率影响因素，涉及多个复杂因素的综合分析，如质量传输速率、液相性质、润湿条件和固相溶解度等。这需要深入理解烧结机理和综合运用相关知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 771, + "question": "As long as the temperature is above 0K, point defects always exist in crystals", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体中点缺陷存在的基本原理，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆点缺陷在晶体中存在的条件即可作答，无需深入理解或分析。题目直接考察对\"温度高于0K时晶体中总是存在点缺陷\"这一基础概念的识记能力，属于最基础的难度等级。" + }, + { + "idx": 772, + "question": "Fick's first law is applicable to solving unstable diffusion problems", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为×表示错误），符合判断题的特征 | 知识层次: 题目考查对Fick's first law适用范围这一基本概念的简单记忆和理解，不涉及复杂应用或分析 | 难度: 该题目属于基础概念正误判断题，仅需记忆Fick第一定律的适用范围即可作答，无需理解或分析复杂概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 773, + "question": "In the cubic crystal system, the possible types of space lattices are F, I, and C", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（立方晶系中可能的空间格子类型是F、I和C），并要求判断其正确性（答案给出×表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查立方晶系中空间点阵类型的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆立方晶系中可能的空间格子类型即可做出正确判断，无需深入理解或复杂分析。" + }, + { + "idx": 775, + "question": "The critical radius of the nucleus $r_{k}$ decreases with increasing $\\Delta T$, making the phase transition easier to proceed.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The critical radius of the nucleus $r_{k}$ decreases with increasing $\\Delta T$, making the phase transition easier to proceed），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查对临界核半径与过冷度关系这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅考察对\"临界核半径与过冷度关系\"这一基础概念的记忆，不需要理解或分析多个概念。正确选项直接对应教材中的基本原理表述，属于最基础的定义性知识考察，因此难度等级为1。" + }, + { + "idx": 777, + "question": "Briefly describe the conditions for forming continuous substitutional solid solutions", + "answer": "The conditions for forming continuous substitutional solid solutions are: ionic size factor, the radius difference between the two substituting ions (r1-r2)/r1<15%; the two components must have exactly the same crystal structure type; continuous substitutional solid solutions can only form when the ionic valences are the same or when the total valence of composite substituting ions is equal; similar electronegativity and polarization properties", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述形成连续置换固溶体的条件，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对形成连续置换固溶体条件的记忆和理解，属于基础概念和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述形成连续置换固溶体的条件，但正确选项已经提供了明确的要点（离子尺寸因素、晶体结构类型、离子价态、电负性和极化性质）。这些要点属于基础概念记忆层次，不需要复杂的分析或推理。然而，由于涉及多个条件的列举和记忆，相对于仅回答单一基本定义的题目（等级1），该题目需要更全面的概念解释和描述能力，因此属于等级2难度。" + }, + { + "idx": 778, + "question": "During the growth of crystals, there must be the presence of undercooling", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征 | 知识层次: 题目考查晶体生长过程中过冷现象的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆晶体生长过程中过冷度的基本定义即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 779, + "question": "For the same system, the nucleation barrier for heterogeneous nucleation ≤ the nucleation barrier for homogeneous nucleation.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（异质成核的成核势垒≤均质成核的成核势垒），要求判断其正确性（答案为√表示正确），这符合判断题的特征 | 知识层次: 题目考查对异质成核和均质成核能垒差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆并确认\"异质成核能垒≤均质成核能垒\"这一基本原理的正确性，无需深入理解或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 780, + "question": "Liquid phase sintering refers to a sintering process in which a liquid phase is present.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案用×表示错误），符合判断题的特征 | 知识层次: 题目考查对液相烧结这一基本概念的记忆和理解，属于定义性知识的判断，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念正误判断题，仅需记忆液相烧结的定义即可判断正误，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 781, + "question": "1. Network former", + "answer": "Network former: substances with single bond energy ≥335kJ/mol that can form glass independently.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Network former\"进行定义和解释，答案以文字形式给出详细说明，符合简答题的特征 | 知识层次: 题目考查对\"Network former\"这一基础概念的定义和分类的记忆和理解，属于材料科学中玻璃形成物质的基本原理知识。 | 难度: 在选择题型中，该题目仅考察对\"Network former\"这一基础概念的定义记忆，属于最基础的知识点掌握要求。题目直接给出了明确定义，无需解释或比较分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 782, + "question": "2. First-order phase transition", + "answer": "First-order phase transition: During the phase transition, the chemical potentials of the two phases are equal, but the first-order partial derivatives of the chemical potential are not equal. A first-order phase transition involves latent heat and volume changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"First-order phase transition\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对一级相变的基本定义和特征的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解并描述一级相变的基本特征，包括化学势的相等和其一阶偏导数的不相等，以及涉及潜热和体积变化。这需要考生不仅记住定义，还需要对概念进行一定的解释和描述，但不需要进行复杂的体系阐述或比较分析。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 783, + "question": "3. Schottky defect", + "answer": "Schottky defect: When the lattice undergoes thermal vibration, some atoms with sufficient energy leave their equilibrium positions, migrate to the surface of the crystal, and leave vacancies at the original normal lattice sites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Schottky defect进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查Schottky defect的基本定义和形成过程，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆Schottky defect的定义和形成过程，虽然涉及一定的物理机制（如热振动、原子迁移等），但整体上仍属于基础概念的记忆性知识，不需要进行复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 784, + "question": "6.Polymorphism", + "answer": "Polymorphism: Substances with the same chemical composition can form crystals with different structures under different thermodynamic conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Polymorphism\"进行解释和论述，答案提供了详细的文字说明，符合简答题的特征 | 知识层次: 题目考查对多晶型（Polymorphism）这一基本概念的定义和简单解释，属于基础概念的记忆和理解层面，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆多晶现象的定义，即相同化学成分的物质在不同热力学条件下可以形成不同晶体结构。虽然涉及基础概念记忆，但需要一定的理解能力来区分多晶现象与其他相关概念（如同分异构体）。相较于等级1的简单定义记忆，该题目对知识点的掌握深度要求略高，但尚未达到等级3的复杂概念体系阐述水平。" + }, + { + "idx": 785, + "question": "4.Secondary recrystallization", + "answer": "Secondary recrystallization: is an abnormal growth process where a few large grains grow at the expense of fine grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Secondary recrystallization\"进行文字解释和论述，答案是一个定义性的陈述，符合简答题的特征 | 知识层次: 题目考查的是对二次再结晶这一基本概念的定义和简单描述，属于基础概念的记忆和理解层面，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"二次再结晶\"的基本定义，属于基础概念记忆层次。正确选项直接给出了定义描述，无需复杂推理或概念间关联分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 786, + "question": "5. Inverse spinel structure", + "answer": "Inverse spinel structure: It belongs to the cubic crystal system, where oxygen ions can be considered as arranged in a cubic close packing. Divalent cation A fills the octahedral voids, while trivalent cation B fills half of the octahedral voids and half of the tetrahedral voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Inverse spinel structure\"进行文字解释和论述，答案提供了详细的晶体结构描述，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对反尖晶石结构的基本定义和晶体学特征的记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及反尖晶石结构的基本定义和离子填充方式，但需要考生理解和记忆多个关键点（如立方晶系、氧离子排列方式、二价和三价阳离子的填充位置等）。这些知识点属于基础概念记忆层次，但需要一定的描述和解释能力，而不仅仅是简单的定义复述。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 787, + "question": "7. Lattice points", + "answer": "Space lattice: A series of equivalent points identified in the crystal structure must be arranged in a periodic repetition in three-dimensional space. A series of geometric points arranged in a periodic repetition in three-dimensional space is called a space lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Lattice points\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查空间点阵的基本定义和概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别空间点阵的基本定义，属于基础概念记忆层次。题目直接给出了定义描述，无需进行复杂的概念解释或比较分析，因此属于最低难度等级。" + }, + { + "idx": 788, + "question": "8.Sintering", + "answer": "Sintering: A process in which one or more solid powders are formed and then heated to a certain temperature, causing them to shrink and become a dense, hard sintered body below the melting point temperature. Alternatively: Due to the mutual attraction of molecules (or atoms) in solids, heating causes the powder particles to bond, and through material migration and diffusion, the powder gains strength, leading to densification and recrystallization—this process is called sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Sintering\"这一概念进行详细的文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查烧结过程的基本定义和原理，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解和记忆烧结过程的基本定义和原理，包括粉末加热、收缩、致密化等关键步骤。虽然涉及多个概念，但都属于基础概念记忆层次，不需要复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 789, + "question": "4. Briefly describe the characteristics of diffusionless phase transformation.", + "answer": "Characteristics of diffusionless phase transformation: shape change caused by uniform shear (change in crystal morphology); the new phase has the same chemical composition as the parent phase; it can occur at low temperatures with a fast transformation rate; there is a certain orientation relationship between the new phase and the parent phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述扩散无相变的特征，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目考查扩散无相变的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求简要描述无扩散相变的特征，涉及多个关键点（如形状变化、化学成分一致性、低温快速转变、取向关系等），但不需要深入分析或比较多个复杂概念体系。属于对基础概念记忆和简单解释的考查，符合等级2的标准。" + }, + { + "idx": 790, + "question": "In a simple cubic crystal, if the direction of the dislocation line is [001] and $b=a$ [110], determine what type of dislocation this belongs to.", + "answer": "nan", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过分析晶体结构和位错性质来确定位错类型，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解位错线的方向和伯格斯矢量的关系，并进行综合分析以确定位错类型。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握晶体结构中的位错类型判断，涉及方向指数和伯格斯矢量的概念关联。解题步骤包括：1) 识别[001]方向为位错线方向；2) 分析伯格斯矢量$b=a$[110]与位错线的几何关系；3) 综合判断位错类型。虽然不涉及复杂计算，但需要将多个概念联系起来进行综合分析，在选择题型中属于中等偏上的认知要求。" + }, + { + "idx": 791, + "question": "2. The concentration of structural defects in non-stoichiometric compounds is related to the nature and pressure of the surrounding atmosphere. Analyze how the density of the non-stoichiometric compounds Fe1-xO and Zn1+xO will change if the partial pressure of the surrounding oxygen atmosphere is increased.", + "answer": "If the partial pressure of the surrounding oxygen atmosphere is increased, the value of x in the non-stoichiometric compound Fe1-xO increases, leading to an increase in the concentration of cation vacancies, which results in a decrease in the density of Fe1-xO. Similarly, if the partial pressure of the surrounding oxygen atmosphere is increased, the value of x in the non-stoichiometric compound Zn1+xO decreases, leading to a reduction in the concentration of interstitial cations, which also results in a decrease in the density of Zn1+xO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析非化学计量化合物中结构缺陷浓度与周围氧气分压的关系，并解释其对密度的影响。答案需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析非化学计量化合物中结构缺陷浓度与周围氧气分压的关系，并解释其对密度的影响。这需要综合运用缺陷化学、非化学计量化合物的性质以及环境条件对材料性能的影响等多方面知识，进行推理分析和机理解释。思维过程涉及多个概念的关联和综合分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅理解非化学计量化合物的基本概念，还需要深入掌握缺陷化学的机理，能够分析氧分压变化对两种不同类型非化学计量化合物（Fe1-xO和Zn1+xO）缺陷浓度和密度的不同影响。解题需要综合运用多个知识点，包括缺陷类型、缺陷反应方程、质量作用定律等，并进行复杂的推理分析。此外，题目涉及两种化合物的对比分析，增加了思维复杂度，完全符合选择题型中\"复杂现象全面分析\"的最高难度标准。" + }, + { + "idx": 792, + "question": "Explain what type of solid solution compound austenite in carbon steel belongs to", + "answer": "Austenite is an interstitial solid solution of carbon in γ-Fe", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释奥氏体在碳钢中属于哪种固溶体类型，需要文字解释和论述，答案也以文字形式给出具体解释 | 知识层次: 题目考查对奥氏体（austenite）这一基本概念的记忆和理解，要求回答其属于何种固溶体类型，属于材料科学基础知识的范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（定义和分类），但需要考生准确理解并区分不同类型的固溶体（间隙固溶体 vs. 置换固溶体），并正确识别奥氏体的具体组成。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 793, + "question": "Explain what type of solid solution compound Fe3C belongs to", + "answer": "Fe3C is an interstitial compound, belonging to the interstitial phase with a complex structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C属于哪种固溶体化合物，需要文字解释和论述，答案也是以文字形式给出解释说明 | 知识层次: 题目考查对Fe3C分类的基础概念记忆和理解，属于材料科学中固溶体类型的基本知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并区分不同类型的固溶体化合物（如间隙相和间隙化合物），并能够正确识别Fe3C的具体分类。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的体系阐述（等级3）。" + }, + { + "idx": 794, + "question": "1. Briefly describe the characteristics of grain growth and secondary recrystallization, as well as the causes of secondary recrystallization and methods to prevent it.", + "answer": "Characteristics of grain growth: Grain growth is a process in which the average grain size of a strain-free material continuously increases during heat treatment without changing its distribution. The grain size grows uniformly within the body; during grain growth, pores remain at grain boundaries or grain boundary intersections. Characteristics of secondary recrystallization: It is an abnormal growth process where a few large grains grow at the expense of fine grains. It involves the abnormal growth of individual grains; during secondary recrystallization, pores are trapped inside the grains; secondary recrystallization is also related to the particle size of the raw material. Causes of secondary recrystallization: Non-uniform particle size of the raw material, excessively high sintering temperature, and too fast sintering rate. Methods to prevent secondary recrystallization: Control sintering temperature and time, ensure uniformity of raw material particle size, and introduce sintering additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶粒生长和二次再结晶的特征、二次再结晶的原因及防止方法，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目要求描述晶粒生长和二次再结晶的特征，分析二次再结晶的原因及预防方法，涉及多个概念的关联和综合分析，需要理解并应用相关知识进行解释和论述，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解晶粒生长和二次再结晶的特征，还需要分析二次再结晶的原因及预防方法。这涉及多个概念的关联和综合分析，需要考生具备较深的知识掌握和逻辑推理能力。" + }, + { + "idx": 795, + "question": "Explain what type of solid solution compound ME2Si belongs to", + "answer": "ME2Si is an intermetallic compound", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释ME2Si属于哪种固溶体化合物，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对固体溶液类型的基本概念记忆和理解，特别是对金属间化合物的识别和分类。 | 难度: 在选择题型中，该题目仅要求识别ME2Si属于哪种类型的固溶体化合物，属于基础概念记忆层次。正确选项直接给出了明确的分类（金属间化合物），无需复杂的推理或分析过程，因此属于最简单的难度等级。" + }, + { + "idx": 796, + "question": "Explain what type of solid solution compound Cu3Sn belongs to", + "answer": "Cu3Sn is an electron compound, an intermetallic compound with a specific electron concentration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Cu3Sn属于哪种固溶体化合物，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对电子化合物这一基本概念的记忆和理解，属于材料科学中固溶体分类的基础知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生不仅记住Cu3Sn的分类，还要理解\"电子化合物\"和\"金属间化合物\"的定义及其电子浓度特性。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 797, + "question": "What factors influence the formation of amorphous metals? Why", + "answer": "Viscosity of liquid metal: the higher the viscosity, the more difficult the atomic diffusion, making it easier to retain the liquid metal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响非晶金属形成的因素，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求分析非晶金属形成的因素，并解释原因，涉及多因素的综合分析和机理解释，需要深入理解原子扩散、粘度等概念及其相互作用，属于复杂分析层次。 | 难度: 在选择题型中，该题目要求考生不仅理解基本概念（如粘度、原子扩散），还需要综合运用这些知识进行复杂现象的全面分析（粘度如何影响非晶态金属的形成）。正确选项涉及机理深度解释（粘度与原子扩散的关系及其对金属结构的影响），这超出了简单记忆或基础理解的范畴，属于选择题型中的高难度水平。" + }, + { + "idx": 798, + "question": "In a simple cubic crystal, if the direction of the dislocation line is [112] and the Burgers vector is $b=a$ [110], determine the type of this dislocation.", + "answer": "Since the direction of the dislocation line is perpendicular to the direction of the Burgers vector, this dislocation is an edge dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错的类型，答案是一个简短的文字解释，而非选择、判断或计算。 | 知识层次: 题目需要理解位错线方向与伯格斯矢量的关系，并判断位错类型，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握晶体中位错的基本概念，包括位错线的方向和Burgers向量的关系，并能判断位错的类型（刃位错或螺位错）。解题步骤涉及向量点积的计算和位错类型的判断，属于中等应用层次的知识要求。" + }, + { + "idx": 799, + "question": "3. Briefly describe the main types and characteristics of solid-phase sintering and liquid-phase sintering, as well as the similarities and differences between solid-phase sintering and liquid-phase sintering.", + "answer": "Main types and characteristics of solid-phase sintering: Evaporation-condensation mass transfer, caused by the vapor pressure difference in different parts, does not result in shrinkage of the green body during the sintering process. Diffusion mass transfer, caused by the vacancy concentration difference in different parts of the particles, is the main method of mass transfer for most solid materials during sintering. Main types and characteristics of liquid-phase sintering: Flow mass transfer, which is the main method of mass transfer for most silicate materials during sintering, can be divided into viscous flow and plastic flow. Dissolution-precipitation mass transfer, where both solid and liquid phases exist, and the solid phase is soluble in the liquid phase. Similarities between solid-phase sintering and liquid-phase sintering: The driving force for sintering is surface energy, and the sintering process consists of stages such as particle rearrangement, pore filling, and grain growth. Differences: Due to the faster rate of flow mass transfer compared to diffusion, liquid-phase sintering has a higher densification rate and lower sintering temperature. Additionally, the rate of the liquid-phase sintering process is also related to factors such as the amount and properties of the liquid phase (viscosity, surface tension, etc.), the wetting condition between the liquid and solid phases, and the solubility of the solid phase in the liquid phase. The factors influencing liquid-phase sintering are more complex than those for solid-phase sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固相烧结和液相烧结的主要类型和特点，以及它们之间的异同点。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述固相烧结和液相烧结的主要类型和特点，并比较它们的异同。这需要理解烧结的基本原理和过程，并能对不同烧结类型的特点进行关联和综合分析。虽然涉及一些基础概念，但更侧重于对知识点的关联和应用，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅掌握固相烧结和液相烧结的主要类型和特征，还需要理解两者之间的相似性和差异性。这涉及到多个概念的关联和综合分析，包括质量传递机制、烧结驱动力、烧结过程阶段以及影响烧结速率的因素等。此外，题目还要求考生能够比较两种烧结方式的复杂性和影响因素，这需要多角度的分析和论述。因此，在选择题型内，该题目属于较高难度等级。" + }, + { + "idx": 800, + "question": "Please briefly describe the similarities and differences between interstitial solid solutions, interstitial phases, and interstitial compounds?", + "answer": "Similarity: small atoms dissolve. Differences: interstitial solid solutions retain the solvent (large atoms) lattice; interstitial phases and interstitial compounds alter the large atoms lattice, forming a new lattice. Interstitial phases have simple structures; interstitial compounds have complex structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述间隙固溶体、间隙相和间隙化合物的异同点，需要文字解释和论述，答案也以文字形式呈现，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体、间隙相和间隙化合物等基本概念的记忆和理解，要求比较它们的相似性和差异性，属于基础概念的记忆和简单对比。 | 难度: 在选择题型中，该题目要求考生理解并区分三个相关但不同的概念（间隙固溶体、间隙相和间隙化合物）。虽然需要记忆基础定义，但更侧重于概念的解释和描述，而非简单的定义复述。考生需要掌握这些概念之间的相似点和差异点，并能准确对应到选项中的描述。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 801, + "question": "What are the characteristics of various alloy strengthening methods?", + "answer": "Grain refinement strengthening, solid solution strengthening, multiphase strengthening, dispersion strengthening (age hardening), and work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释各种合金强化方法的特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对合金强化方法的基本概念和分类的记忆，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个合金强化方法的概念，但正确选项已经明确列出了五种主要的强化方法（晶粒细化强化、固溶强化、多相强化、弥散强化（时效硬化）和加工硬化），考生只需识别和记忆这些基本分类即可。不需要进行复杂的比较分析或深入的概念阐述，因此难度等级为2。" + }, + { + "idx": 802, + "question": "What is the physical significance of the critical nucleus?", + "answer": "The physical significance of the critical nucleus: the smallest embryo that can grow spontaneously (or, a nucleus with a radius equal to rk).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释临界核的物理意义，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对临界晶核物理意义的基本概念记忆和理解，属于定义性知识 | 难度: 在选择题型中，该题目仅考察对\"critical nucleus\"基本定义的记忆，属于最基础的概念性知识。正确选项直接给出了定义表述，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 803, + "question": "What are the methods of alloy strengthening?", + "answer": "Grain refinement strengthening, solid solution strengthening, multiphase strengthening, dispersion strengthening (age hardening), and work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举合金强化的方法，答案是通过文字解释和论述的形式给出，没有提供选项或要求判断对错，也不需要数值计算。 | 知识层次: 题目考查合金强化方法的基本分类和记忆，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生掌握合金强化的多种方法（晶粒细化强化、固溶强化、多相强化、弥散强化/时效硬化、加工硬化），并能准确识别和区分这些方法。这比单纯记忆单个定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 804, + "question": "If it is an edge dislocation, determine the crystallographic plane indices of the half-atom plane and the crystallographic direction indices of the insertion direction.", + "answer": "The crystallographic plane indices of the half-atom plane are (110).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定刃位错的半原子面的晶面指数和插入方向的晶向指数，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对边缘位错基本概念的记忆和理解，包括半原子面的晶面指数和插入方向的晶向指数，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（边缘位错的半原子面晶面指数），但需要考生准确记忆和理解(110)晶面指数这一特定知识点。相比单纯的定义简答（等级1），该题目要求考生能够将理论知识与具体位错类型对应起来，属于概念解释和描述层面的难度。题目不需要复杂的推导或比较分析，但比纯粹的记忆定义要稍难一些。" + }, + { + "idx": 805, + "question": "What are the sufficient conditions for the formation of a critical nucleus?", + "answer": "The sufficient conditions for the formation of a critical nucleus: (1) Formation of an embryo with r≥rk; (2) Acquisition of nucleation work with A≥A* (critical nucleation work).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释形成临界核的充分条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对临界核形成条件的记忆和理解，属于基本原理的记忆性知识，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并回忆临界核形成的两个充分条件（胚胎半径达到临界值和获得临界成核功），这比单纯记忆单一概念的定义要复杂一些。题目要求考生掌握成核理论中的关键参数和条件，属于概念解释和描述的层次，但不需要进行复杂的体系阐述或比较分析。" + }, + { + "idx": 806, + "question": "Please briefly describe the main factors affecting diffusion", + "answer": "The main factors affecting diffusion: (1) temperature; (2) crystal structure and type; (3) crystal defects; (4) chemical composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述影响扩散的主要因素，答案以文字解释和列举的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对扩散影响因素的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生回忆并描述影响扩散的主要因素，涉及多个基本概念的记忆和简单列举。虽然需要掌握一定的基础知识，但不需要深入分析或复杂推理，属于概念解释和描述的难度水平。" + }, + { + "idx": 807, + "question": "Briefly describe the growth mechanism of pure metal crystals", + "answer": "The crystal growth mechanism refers to the microscopic growth mode of crystals, which is related to the liquid-solid interface structure. For substances with rough interfaces, since about $50\\\\%$ of the atomic positions on the interface are vacant, these vacancies can accept atoms. Therefore, liquid atoms can individually enter the vacancies and connect with the crystal, causing the interface to advance perpendicularly along its normal direction, resulting in continuous growth. For crystals with smooth interfaces, growth does not occur through the attachment of individual atoms but rather through homogeneous nucleation, forming a two-dimensional nucleus one atomic layer thick on the crystallographic facet interface, creating a step between the new nucleus and the original interface. Individual atoms can then fill in the step, allowing the two-dimensional nucleus to grow laterally. Once the layer is filled, a new two-dimensional nucleus forms on the new interface, and the process repeats. If the smooth interface of the crystal has an exposed screw dislocation, the interface becomes a spiral surface, forming a step that never disappears. Atoms attach to the step, enabling crystal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述纯金属晶体的生长机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述纯金属晶体的生长机制，涉及液体-固体界面结构、粗糙界面和光滑界面的生长模式、二维核形成、螺旋位错等复杂概念。需要综合运用材料科学中的晶体生长理论，进行机理的解释和分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解金属晶体生长的微观机制，涉及粗糙界面和光滑界面的不同生长方式，以及二维核形成和螺旋位错等复杂概念。解题需要综合运用材料科学知识，进行机理深度解释和复杂现象全面分析，对知识掌握深度和推理能力要求极高。" + }, + { + "idx": 808, + "question": "What are the limitations of strain hardening as a strengthening method?", + "answer": "Strain hardening does not fundamentally change the properties of the alloy. Under certain conditions, such as temperature increase, strain hardening may be lost due to the occurrence of recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应变硬化的局限性，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求解释应变硬化的局限性，涉及对材料性能变化的理解和特定条件下（如温度升高）材料行为的分析。这需要将应变硬化的基本原理与实际应用中的限制条件关联起来，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解应变硬化的基本原理及其局限性，并能关联温度变化对材料性能的影响。虽然题目涉及多个概念的综合分析，但在选择题型中，正确选项已经提供了明确的解释，减少了推理的复杂性。" + }, + { + "idx": 809, + "question": "According to the position of solute atoms in the lattice, into how many categories can solid solution phases be divided?", + "answer": "Based on the position of solute atoms in the lattice, solid solutions can be divided into substitutional solid solutions, such as the α phase in Al-Cu alloys; interstitial solid solutions, such as the α phase in Fe-C alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释固体溶液的分类，并需要文字论述和举例说明，符合简答题的特征。 | 知识层次: 题目考查对固溶体分类的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别固体溶液相的分类，属于基础概念记忆的范畴。题目直接给出了两种固体溶液的分类及其例子，考生只需根据记忆选择正确的分类方式，无需进行复杂的分析或推理。因此，该题目在选择题型内属于基本定义简答的难度等级。" + }, + { + "idx": 810, + "question": "What is the significance of strain hardening in production?", + "answer": "Strain hardening, also known as work hardening, can improve the strength and hardness of alloys. For example, cold-drawn steel wires are strengthened by utilizing the strain hardening effect. Especially for some alloys that cannot be strengthened by heat treatment, strain hardening is a very important strengthening method.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应变硬化的意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释应变硬化的定义（基础概念），还需要说明其在生产中的具体应用和重要性（概念关联和综合分析），涉及多步思维过程和对材料强化机制的理解。 | 难度: 在选择题中属于中等难度，题目要求理解应变硬化的概念及其在生产中的实际应用（如冷拔钢丝的强化），并需要将这一概念与合金强化方法（特别是无法通过热处理强化的合金）进行关联分析。虽然不涉及复杂计算，但需要综合理解和应用材料科学中的基本概念。" + }, + { + "idx": 811, + "question": "During non-equilibrium solidification of solid solution alloys, sometimes microsegregation forms, and sometimes macrosegregation forms. What is the reason for this?", + "answer": "Microsegregation occurs within the range of a single grain and is caused by the slow diffusion rate during crystallization. Macrosegregation occurs throughout the entire part or sample and is caused by the redistribution of solute atoms during crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释微偏析和宏观偏析形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非平衡凝固过程中微观偏析和宏观偏析的形成原因，涉及对扩散速率和溶质原子再分布的理解，需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求区分微偏析和宏观偏析的形成原因，涉及非平衡凝固过程中的扩散速率和溶质原子再分布等复杂概念。需要考生综合理解并关联多个知识点，进行多角度分析才能正确解答。" + }, + { + "idx": 812, + "question": "What are the necessary conditions for an alloy to undergo precipitation hardening?", + "answer": "The necessary condition for precipitation hardening to occur is the availability of a supersaturated solid solution to facilitate the precipitation of a second phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释合金发生沉淀硬化的必要条件，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对沉淀硬化基本条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述\"过饱和固溶体\"和\"第二相析出\"这两个关键概念之间的关系，而不仅仅是简单的定义复述。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 813, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], if the slip is caused by an edge dislocation, indicate the direction of the dislocation line.", + "answer": "Direction of the dislocation line: [112]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个具体的晶体学方向[112]，而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目要求学生在理解面心立方晶体滑移系统的基础上，结合位错理论，分析刃位错线的方向。这需要学生将晶体学方向与位错性质相关联，进行多步推理和综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解面心立方晶体的滑移系统、位错类型（刃位错）以及位错线方向的计算。解题步骤涉及晶体几何学知识、滑移系分析以及位错线方向的确定，需要多步计算和概念关联。虽然题目给出了正确选项，但推导过程需要较强的空间想象力和综合分析能力，超出了基础记忆或简单应用的范畴。" + }, + { + "idx": 814, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], please indicate the Burgers vector of the unit dislocation causing the slip.", + "answer": "Burgers vector; b=a/2 [110]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释并给出Burgers vector的具体表达式，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别面心立方晶体中特定滑移系(111)[110]的单位位错的Burgers矢量，这需要理解晶体结构、滑移系和位错的基本概念，并将这些概念关联起来进行分析。虽然不涉及多步计算，但需要对晶体学方向和Burgers矢量的关系有中等程度的理解，属于概念关联和综合分析层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握面心立方晶体的滑移系统以及伯格斯矢量的概念，并能正确识别单位位错的伯格斯矢量。虽然题目给出了滑移系统（111）[110]，但需要考生知道在面心立方晶体中，单位位错的伯格斯矢量通常是a/2<110>类型。这需要一定的晶体学知识和综合分析能力，但不需要多步计算或深度关联性分析。" + }, + { + "idx": 816, + "question": "Explain the meaning of the rolling texture {110}<112> in face-centered cubic alloy α-brass.", + "answer": "It is a sheet texture. The {110}<112> texture indicates that the {110} plane is parallel to the rolling plane, and the <112> direction is parallel to the rolling direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释面心立方合金α-黄铜中{110}<112>轧制织构的含义，需要文字解释和论述，答案也是以文字形式详细说明该织构的特征和意义。 | 知识层次: 题目考查对轧制织构{110}<112>的基本概念和定义的理解，属于基础概念的记忆和解释，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述{110}<112>滚动织构的具体含义，包括平面和方向的对应关系。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 817, + "question": "How many equivalent slip systems can be simultaneously activated when a face-centered cubic metal single crystal is stretched along [111]? And specifically write the indices of each slip system.", + "answer": "When an FCC-structured crystal is stretched along the [111] direction, there are 6 equivalent slip systems, which are: (111)[011], (111)[110], (111)[011], (111)[101], (111)[101], (111)[110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细写出等效滑移系统的数量及其具体指数，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求确定面心立方金属单晶在特定拉伸方向下的等效滑移系统数量及其具体指数，这需要理解滑移系统的基本概念、晶体学方向的计算以及等效滑移系统的判断。虽然涉及一定的记忆性知识，但更需要对概念的综合应用和分析能力，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 819, + "question": "What is the Kirkendall effect in the process of alloy diffusion?", + "answer": "Kirkendall effect: As shown in Figure 1-4, a very thin molybdenum wire is applied as a marker on an FCC-structured α-brass (Cu+30%Zn) rod, and then copper is plated on the brass, enclosing the molybdenum wire between the brass and copper. Diffusion is carried out at a certain temperature. The molybdenum wire serves only as a marker and does not participate in the diffusion throughout the experiment. The diffusing components are copper and zinc, which form a substitutional solid solution. In the diffusion process of the substitutional solid solution, the markers placed at the original interface move towards the direction of the low-melting-point element, and the displacement distance exhibits a parabolic relationship with time. The reason for this phenomenon is that the low-melting-point component diffuses faster, while the high-melting-point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对Kirkendall效应进行详细的文字解释和论述，答案提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要详细描述实验现象、扩散机制以及不同元素扩散速率的差异导致的标记移动。这涉及到对扩散过程的深入理解、机理分析和综合推理，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目不仅要求考生掌握Kirkendall效应的基本概念，还需要深入理解扩散过程中的原子交换机制、熔点与扩散速率的关系，以及标记物移动的动力学行为。此外，题目涉及复杂的实验设计和现象解释，要求考生能够综合运用材料科学知识进行推理分析。这种深度和广度的知识要求，在选择题型中属于最复杂的层次。" + }, + { + "idx": 820, + "question": "How many types of two-dimensional lattices are there? Indicate their types and illustrate with diagrams.", + "answer": "There are 5 types of two-dimensional lattices, namely oblique, hexagonal, rectangular, centered rectangular, and square, as shown in Table 1-1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和描述二维晶格的类型，并附上图示，这需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对二维晶格类型的基础概念记忆和分类理解，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目要求考生记忆并识别二维晶格的五种类型，属于基础概念记忆的范畴。虽然需要记忆五种类型的名称，但不需要深入理解其背后的原理或进行复杂的分析。相对于等级1的基本定义简答，该题目稍微复杂一些，因为它涉及多个分类的记忆，但仍属于概念解释和描述的难度水平。" + }, + { + "idx": 821, + "question": "What are the main characteristics of Shockley partial dislocations in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "Shockley partial dislocation; Burgers vector is 1 <112> 6; dislocation nature is screw-type, edge-type, mixed-type; formation method is can only be formed through local slip of the crystal; motion state is even edge-type partial dislocations can only slip and cannot climb. Even screw-type partial dislocations cannot cross-slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Shockley partial dislocations在FCC晶体中的主要特征，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对Shockley partial dislocations的多个特性进行详细描述，包括Burgers vector、位错性质、形成方法和运动状态等，需要综合理解和应用多个相关概念，并进行一定的分析和关联。虽然不涉及复杂的计算或深度推理，但需要将多个知识点整合起来进行回答，超出了单纯的基础概念记忆。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握Shockley不全位错的基本概念（如位错名称、柏氏矢量、位错性质），还需要理解其形成机制和运动状态的复杂性（如只能通过局部滑移形成、不同类型位错的运动限制）。这需要考生能够将多个知识点进行关联和综合分析，并准确区分不同位错类型的特性，属于多角度分析论述的层次。" + }, + { + "idx": 822, + "question": "What are the main characteristics of Frank partial dislocations in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "Frank partial dislocation; Burgers vector is 1/3 <111>; the nature of the dislocation is edge-type; the formation method involves inserting or removing a layer of {111} close-packed plane in a local region of the crystal; the motion state is that it can only climb, not glide.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释Frank partial dislocations在FCC晶体中的主要特征，包括多个方面的描述（如位错名称、Burgers矢量、位错性质、形成方法和运动状态），答案提供了全面的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对Frank partial dislocations在FCC晶体中的基本特性的记忆和理解，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态等基础概念。这些内容属于材料科学中位错理论的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生记忆并理解Frank partial dislocations的多个关键特征，包括名称、Burgers向量、位错性质、形成方法和运动状态。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或比较。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 823, + "question": "What are the main characteristics of the Shockley partial dislocation in the extended dislocation of an FCC crystal? Include the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "Shockley partial dislocation in the extended dislocation; Burgers vector is 1 [112] 6 [121] 6; dislocation nature is mixed-type; formation method is the decomposition of a perfect dislocation into two parallel Shockley partial dislocations of screw-type, edge-type, and mixed-type, with a stacking fault region in between; motion state is glide-only. Climb or cross-slip can only occur after constriction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Shockley部分位错的主要特征，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对Shockley部分位错的主要特征进行详细描述，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态。这需要学生不仅记忆相关概念，还需要理解位错的性质和形成机制，并能将这些知识点关联起来进行综合分析。虽然不涉及复杂的推理或创新应用，但需要多步思考和概念关联，因此属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生对Shockley部分位错在FCC晶体扩展位错中的主要特征有深入理解。题目要求考生掌握位错名称、Burgers矢量、位错性质、形成方法以及运动状态等多个知识点，并进行综合分析和关联。此外，题目还涉及到位错分解、堆垛层错区域等较为复杂的概念，需要考生具备较强的综合分析能力和概念关联能力。因此，在选择题型内，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 824, + "question": "What are the main characteristics of perfect dislocations in FCC crystals? Including dislocation name, Burgers vector, dislocation nature, dislocation formation mode, and motion state.", + "answer": "Perfect dislocations (relatively rare in actual crystals); Burgers vector is 1 <110> 2; dislocation nature is screw-type, edge-type, mixed-type; dislocation formation mode is local slip or local displacement; motion state is can slip or climb.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释完美位错在FCC晶体中的主要特征，包括位错名称、伯格斯矢量、位错性质、位错形成方式和运动状态。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查完美位错在FCC晶体中的基本特征，包括位错名称、伯格斯矢量、位错性质、形成方式和运动状态等基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生记忆并理解完美位错在FCC晶体中的主要特征，包括位错名称、Burgers矢量、位错性质、形成方式和运动状态。虽然涉及多个概念，但都属于基础概念记忆范畴，不需要复杂的分析或比较。因此，在选择题型内属于中等难度。" + }, + { + "idx": 825, + "question": "What are the main characteristics of the L-C sessile dislocation in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "L-C sessile dislocation (with multiple configurations); Burgers vector is for example—[110] 6; dislocation nature is screw-type, edge-type, mixed-type; formation method is obtained through Shockley partial dislocation synthesis (or dislocation reaction); motion state is immobile.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释L-C sessile dislocation的主要特征，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态。答案提供了详细的文字解释和论述，而不是从选项中选择或简单的对错判断，也不需要数值计算。 | 知识层次: 题目要求对L-C sessile dislocation的多个特征进行描述，包括Burgers vector、位错性质、形成方法和运动状态等，需要综合理解和应用多个相关概念，并进行一定的关联分析。虽然不涉及复杂的计算或深度推理，但需要将多个知识点整合起来回答，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅掌握L-C sessile dislocation的基本概念，还需要理解其多种配置、Burgers向量的具体例子、位错性质（包括螺型、刃型和混合型）、形成方法（如通过Shockley部分位错合成或位错反应）以及运动状态（不可移动）。这需要考生具备多角度分析的能力，能够将多个概念关联起来进行综合分析，属于较高难度的选择题。" + }, + { + "idx": 826, + "question": "Using the standard projection diagram of a cubic crystal, explain the formation reason of the rolling texture {110}<112> in face-centered cubic alloy α-brass.", + "answer": "α-brass has an FCC structure, and its slip system is {111}<10\\overline{1}>. Under the action of tensile force along the rolling direction, the crystal slips and rotates. In the crystallographic coordinate system, if the tensile axis T1 is located in the 001-101-111 orientation triangle, the initial slip system is (111)[011], and the tensile axis turns toward the [011] direction, reducing the angle λ between the tensile axis and the slip direction. When the force axis reaches the common edge of the two orientation triangles, i.e., T2, double slip begins, and the slip system (111)[101] is also activated. The tensile axis turns both toward the [011] direction and the [101] direction, resulting in rotation along the common edge. When it reaches the [112] direction, since [101], [112], and [011] lie on the same great circle, the two λ angles simultaneously decrease to the minimum value, making [112] the final stable position. Thus, the <112> direction tends to align with the rolling direction. On the rolling plane, under the action of compressive force, if the compressive axis P1 is located in the 001-011-111 orientation triangle, the initial slip system is (111)[101], and the compressive axis turns toward the (111) plane, reducing the angle φ between the compressive axis and the slip plane. When the force axis reaches the common edge of the two orientation triangles, i.e., P2, double slip begins, and the slip system (111)[101] is also activated. The compressive axis turns both toward the (111) plane and the (111) plane, resulting in rotation along the common edge. When it reaches the (011) plane, since (111), (011), and (111) lie on the same great circle, the two φ angles simultaneously decrease to the minimum value, making (011) the final stable position. Thus, the (011) plane tends to become parallel to the rolling plane. As a result, the {110} plane becomes parallel to the rolling plane, and the <112> direction becomes parallel to the rolling direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释面心立方合金α-黄铜中{110}<112>轧制织构的形成原因，答案通过详细的文字解释和论述来回答，涉及晶体滑移、旋转和稳定位置的分析，符合简答题的特征。 | 知识层次: 题目要求解释面心立方合金α-黄铜中{110}<112>轧制织构的形成原因，涉及晶体滑移系统的激活、晶体旋转机制、双滑移系统的相互作用以及最终稳定取向的确定。这需要综合运用晶体学知识、力学原理和织构形成机制，进行多步骤的推理和分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 827, + "question": "What insights do the Kirkendall experiment results provide?", + "answer": "The practical significance of the Kirkendall effect includes: ① Revealing the intrinsic connection between macroscopic diffusion laws and microscopic diffusion mechanisms, which is universal; ② Directly refuting the exchange mechanism of substitutional solid solution diffusion and supporting the vacancy mechanism; ③ Each component in the diffusion system has its own diffusion coefficient; ④ The Kirkendall phenomenon often produces side effects, such as incomplete shrinkage leading to Kirkendall pores, etc. These side effects often have adverse impacts in practice and should therefore be controlled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提供详细的文字解释和论述，而不是选择、判断或计算。答案包含了多个要点，需要深入阐述Kirkendall实验结果的见解和实际意义。 | 知识层次: 题目要求对Kirkendall实验结果的多个方面进行深入分析和解释，包括宏观与微观扩散机制的联系、对扩散机制的验证、扩散系数的独立性以及Kirkendall现象的副作用等。这需要综合运用扩散理论、微观机制分析和实际应用的知识，并进行推理和解释，属于复杂分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 828, + "question": "Indicate the second main mechanism of alloy strengthening and explain its strengthening reason", + "answer": "Precipitation strengthening and dispersion strengthening. The compounds of alloying elements and matrix elements obtained through phase transformation processes in alloys, as well as hard particles mechanically mixed into the matrix material, both cause alloy strengthening, referred to as precipitation strengthening and dispersion strengthening, respectively. The effects of precipitation strengthening and dispersion strengthening are much greater than solid solution strengthening. When dislocations encounter second phases during movement, they need to cut through (small-sized particles in precipitation strengthening and particles in dispersion strengthening) or bypass (large-sized particles in precipitation strengthening) the second phases. Therefore, the second phases (precipitates and dispersoids) hinder dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第二种主要机制及其强化原因，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求记忆合金强化的第二种主要机制（沉淀强化和弥散强化），还需要解释其强化原因，涉及位错运动与第二相粒子的相互作用机制。这需要理解概念之间的关联，并进行一定的综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求识别合金强化的第二种主要机制（沉淀强化和弥散强化），还需要理解其强化原理。正确选项涉及多个概念的综合分析，包括相变过程、第二相粒子对位错运动的阻碍机制（切割或绕过），以及与固溶强化的效果比较。这需要考生具备较深的知识掌握和多角度分析能力，超出了简单的记忆或单一概念的应用。" + }, + { + "idx": 829, + "question": "Given that the recrystallization activation energy of a Cu-30%Zn alloy is 250 kJ/mol, and it takes 1 hour for this alloy to complete recrystallization at a constant temperature of 400°C, calculate how many hours it will take for this alloy to complete recrystallization at a constant temperature of 390°C.", + "answer": "According to the formula, t2/t1 = exp[-Q/R(1/T1 - 1/T2)] = exp[-250×10^3/8.314×(1/(400+273) - 1/(390+273))] = 1.962. Therefore, t2 = t1×1.962 = 1.962 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及激活能和温度对再结晶时间的影响，需要应用Arrhenius方程进行数值计算，并理解温度与时间的关系。虽然计算过程较为直接，但需要将多个概念关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及激活能、温度与时间的关系，以及阿伦尼乌斯公式的应用。解题步骤包括温度单位的转换（摄氏温度到开尔文温度）、公式的正确代入和计算，以及对数运算。虽然题目提供了正确选项，但理解和应用这些概念需要一定的综合分析能力。" + }, + { + "idx": 830, + "question": "Indicate the first main mechanism of alloy strengthening and explain its strengthening reason", + "answer": "Solid solution strengthening. The alloy element atoms dissolved in the lattice interstices or nodes, due to their size differing from the matrix atoms, generate a certain stress field that hinders dislocation movement; Cottrell atmospheres and Suzuki atmospheres, the former being interstitial atoms preferentially distributed in the tensile stress region of edge dislocations in BCC metals, producing a pinning effect on dislocations, the latter being alloy elements preferentially distributed in the stacking fault region of extended dislocations in FCC metals, reducing stacking fault energy, expanding the stacking fault region, making the slip of extended dislocations more difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第一种主要机制及其强化原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金强化的主要机制及其强化原因，涉及固溶强化、位错运动阻碍、Cottrell气团和Suzuki气团等复杂概念，需要综合运用材料科学知识进行机理分析和解释。思维过程要求深入理解位错与溶质原子的相互作用，以及不同晶体结构中的强化机制，属于复杂分析和机理解释的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目不仅要求识别合金强化的主要机制（固溶强化），还需要深入解释其强化原理，包括应力场的产生、Cottrell气团和Suzuki气团的作用机制，以及它们对不同晶体结构（BCC和FCC）中位错运动的影响。这需要考生具备深厚的材料科学知识，能够综合运用多个复杂概念，并进行机理层面的深入分析。在选择题型中，这种要求全面理解并解释复杂现象的问题属于最高难度等级。" + }, + { + "idx": 831, + "question": "What is the practical significance of the Kirkendall effect?", + "answer": "The practical significance of the Kirkendall effect includes: ① It reveals the intrinsic connection between macroscopic diffusion laws and microscopic diffusion mechanisms, demonstrating universality; ② It directly refutes the exchange mechanism of substitutional solid solution diffusion and supports the vacancy mechanism; ③ Each component in a diffusion system has its own diffusion coefficient; ④ The Kirkendall phenomenon often produces side effects, such as incomplete shrinkage leading to Kirkendall voids, which can have adverse impacts in practice and should therefore be controlled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应的实际意义，答案提供了详细的文字论述和多个要点，符合简答题的特征。 | 知识层次: 题目要求对Kirkendall效应的实际意义进行详细解释和论述，涉及多个方面的综合分析，包括宏观与微观的联系、扩散机制的验证、扩散系数的特性以及实际应用中的副作用控制。这需要深入理解扩散机制，并能将理论知识与实际应用相结合，属于复杂分析和综合运用的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解Kirkendall效应的基本概念，还需要综合运用多个知识点（如扩散机制、宏观与微观联系、实际应用中的副作用等）进行全面分析。正确选项涵盖了机理深度解释（等级4）和复杂现象全面分析（等级5）两个最高层次的要求，且需要考生在选择题的有限选项中识别和整合这些复杂信息。这种题目在选择题中属于对知识掌握深度和综合分析能力要求极高的类型。" + }, + { + "idx": 832, + "question": "Indicate the third main mechanism of alloy strengthening and explain the reason for its strengthening", + "answer": "Grain boundary strengthening. According to the Hall-Petch formula, the relationship between the yield point σs and the grain diameter d is σs=σ0+K d^(-1/2). The essence is that additional stress is required for dislocations to cross grain boundaries. Therefore, low-temperature steels often adopt a fine-grained structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金强化的第三种主要机制及其强化原因，需要文字解释和论述，符合简答题的特征。答案提供了详细的解释和公式支持，进一步验证了这一点。 | 知识层次: 题目要求解释合金强化的第三种主要机制（晶界强化）及其强化原因，涉及Hall-Petch公式的应用和位错理论的解释。这需要将基本原理（Hall-Petch关系）与实际材料行为（位错运动）联系起来，进行多步分析和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解合金强化的主要机制之一，并能够解释其强化原理。题目要求考生不仅知道晶界强化这一概念，还需要理解Hall-Petch公式及其物理意义，以及细晶粒结构在低温钢中的应用。这涉及多个概念的关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 833, + "question": "Explain the processes and characteristics of recovery, recrystallization, and grain growth when cold-deformed metal is heated.", + "answer": "When cold-deformed metal is heated, three processes occur sequentially: recovery, recrystallization, and grain growth. Their respective characteristics are as follows:\\n\\n(1) Characteristics of the recovery process\\n\\n① The microstructure does not change during recovery, and the elongated grains of the deformed state are still retained.\\n\\n② The recovery process completely eliminates the macroscopic (Type I) stresses caused by deformation and largely eliminates the microscopic (Type II) stresses.\\n\\n③ During recovery, the mechanical properties generally change little, with hardness and strength only slightly decreasing, plasticity slightly increasing, and certain physical properties changing significantly, such as resistivity decreasing markedly and density increasing.\\n\\n④ The stored energy from deformation is partially released during the recovery stage.\\n\\n(2) Characteristics of the recrystallization process\\n\\n① The microstructure changes, transforming from the elongated grains of cold deformation into new equiaxed grains.\\n\\n② The mechanical properties change drastically, with strength and hardness sharply decreasing and plasticity increasing, returning to the state before deformation.\\n\\n③ The stored energy from deformation is fully released during recrystallization, lattice distortions (Type III stresses) are eliminated, and dislocation density decreases.\\n\\n(3) Characteristics of the grain growth process\\n\\n① The grains grow larger.\\n\\n② It causes changes in some properties, such as decreases in strength, plasticity, and toughness.\\n\\n③ Along with grain growth, other structural changes occur, such as recrystallization texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释冷变形金属加热时的三个过程（回复、再结晶和晶粒长大）及其特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目要求解释冷变形金属加热时的三个过程（回复、再结晶和晶粒长大）及其特征，涉及多个知识点的综合运用和机理解释。需要深入理解每个过程的微观结构变化、力学性能变化以及能量释放等复杂机制，并进行综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用多个复杂概念（恢复、再结晶和晶粒长大），深入理解这些过程的机理和特征，并进行全面的推理分析。正确选项详细描述了每个过程的微观结构变化、力学性能变化、应力消除和能量释放等关键特征，需要考生具备扎实的材料科学基础和综合分析能力。这种深度和广度的知识要求在选择题型中属于最复杂的层次。" + }, + { + "idx": 834, + "question": "Indicate the fourth main mechanism of alloy strengthening and explain the reason for its strengthening", + "answer": "Order strengthening. The dislocations in ordered alloys are superdislocations. To cause plastic deformation in the metal, both partial dislocations of the superdislocation need to move simultaneously, thus requiring greater external stress. The bonding force between dissimilar element atoms is stronger than that between similar element atoms, so the ordered arrangement of dissimilar atoms gives ordered alloys higher strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第四种主要机制及其强化原因，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金强化的第四种主要机制（有序强化）及其强化原因，涉及对超位错、塑性变形机制以及原子间结合力的深入理解和综合分析。需要将多个概念关联起来，并进行机理层面的解释，思维深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 835, + "question": "Explain the formation reasons of the surface fine grain zone in typical ingot structure", + "answer": "The surface fine grain zone has numerous nucleation sites, fast cooling rate, and large undercooling, growing dendritically in various directions, thus forming fine, equiaxed crystals. Due to the rapid crystallization of the fine grain zone, the released latent heat of crystallization cannot dissipate in time, causing the temperature at the liquid-solid interface to rise sharply. This quickly halts the development of the fine grain zone, resulting in a very thin shell of fine grain zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释典型铸锭结构中表面细晶区的形成原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释典型铸锭结构中表面细晶区的形成原因，涉及多个因素的相互作用（如形核位点、冷却速率、过冷度等）以及结晶潜热的影响，需要综合运用材料科学中的凝固原理和热力学知识进行推理分析。这种题目不仅要求对基础概念的理解，还需要将这些概念关联起来，解释复杂的物理现象，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解并综合运用多个复杂概念（如成核位点、冷却速率、过冷度、枝晶生长方向、结晶潜热等），并能够解释这些因素如何相互作用形成表面细晶区。此外，还需要理解温度变化对细晶区发展的影响机制。这种需要全面分析复杂现象并解释其机理的题目，在选择题型中属于最难的一类。" + }, + { + "idx": 836, + "question": "Explain the formation reason of the central equiaxed crystal zone in typical ingot structure", + "answer": "The central equiaxed crystal zone forms due to the non-directional growth of crystal nuclei in the uniformly cooled central liquid. The crystal nuclei originate from two pathways: one is exogenous nuclei, including detached surface grains and broken dendrites; the other is endogenous nuclei, including homogeneous and heterogeneous nucleation in the undercooled liquid of the central region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释典型铸锭结构中中心等轴晶区的形成原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释典型铸锭结构中中心等轴晶区的形成原因，涉及晶体生长的非定向性、外生晶核和内生晶核的形成途径，需要综合运用晶体生长理论、凝固原理和热力学知识进行机理分析和推理。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解铸锭结构中中心等轴晶区的形成原因，还需要掌握晶体核形成的两种途径（外生核和内生核）及其具体来源。这需要考生具备综合运用知识的能力，能够进行复杂的推理分析和机理解释。此外，题目涉及的知识点较为深入，包括均匀冷却、晶体生长方式、枝晶破碎以及均质/异质形核等概念，对考生的知识掌握深度和综合分析能力要求很高。" + }, + { + "idx": 837, + "question": "Write the close-packed plane, interplanar spacing of close-packed planes, close-packed direction, and minimum unit length of the close-packed direction for an FCC crystal.", + "answer": "
FCC111}√3 a 3<110>√2 2 a
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细描述FCC晶体的密排面、密排面间距、密排方向及其最小单位长度，需要文字解释和论述，答案以表格形式呈现，属于简答题类型。 | 知识层次: 题目主要考查对FCC晶体结构的基本概念的记忆，包括密排面、密排方向及其相关参数的计算，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确记忆FCC晶体的密排面、面间距、密排方向及其最小单位长度等具体数值和符号表达。这比单纯的定义记忆（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 838, + "question": "Write the close-packed plane, interplanar spacing of close-packed planes, close-packed direction, and minimum unit length of the close-packed direction for BCC crystals.", + "answer": "
BCC110}√2 D 2<111>√3 2 a
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细描述BCC晶体的密排面、密排面间距、密排方向及其最小单位长度，需要文字解释和论述，答案以表格形式呈现了具体参数，符合简答题的特征。 | 知识层次: 题目要求写出BCC晶体的密排面、密排面间距、密排方向和密排方向的最小单位长度，这些内容属于晶体结构的基本性质，需要记忆和理解基本概念，并进行简单的公式应用和计算。虽然涉及多个知识点，但每个知识点都是直接套用和简单计算，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求直接套用BCC晶体的基本公式和概念，如密排面、面间距、密排方向及其最小单位长度。虽然涉及多个知识点，但都是晶体学中的基础内容，且题目提供了正确选项，学生只需识别和匹配即可，无需复杂计算或深入分析。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 839, + "question": "Write the indices of the crystal plane family with an interplanar spacing of $0.1246\\\\mathrm{nm}$ in nickel (Ni) crystal. The lattice constant of nickel is $0.3524\\\\mathrm{nm}$.", + "answer": "The crystal structure and lattice of nickel (Ni) are face-centered cubic (FCC). The formula for the interplanar spacing in a cubic crystal is: $$d={\\\\frac{a}{\\\\sqrt{h^{2}+k^{2}+l^{2}}}}$$Thus, $$h^{2}+k^{2}+l^{2}=\\\\frac{a^{2}}{d^{2}}=\\\\frac{0.3524^{2}}{0.1246^{2}}\\\\approx8$$Since $\\\\smash{\\\\boldsymbol{h}_{3},\\\\boldsymbol{k}_{3},\\\\boldsymbol{l}}$ are all integers, the possible values for $\\\\smash{\\\\boldsymbol{h}_{3},\\\\boldsymbol{k}_{3},\\\\boldsymbol{l}}$ are: 0, 2, 2. Therefore, The indices of the crystal plane family that meet the requirement are {220}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶面指数，解答过程中涉及到了具体的数学计算和公式推导。 | 知识层次: 题目主要考查对立方晶体晶面间距公式的直接应用和简单计算，涉及基本的数学运算和晶面指数的确定，不需要复杂的分析或多步骤推理。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用晶体学中的基本公式计算晶面间距，但题目已经给出了所有必要的参数和公式，只需要进行简单的代数运算即可得出答案。不需要复杂的推导或多步骤的计算，因此难度等级为2。" + }, + { + "idx": 840, + "question": "Write the close-packed plane, interplanar spacing of close-packed planes, close-packed direction, and the minimum unit length of the close-packed direction for HCP (M(a)>√8/3) crystals.", + "answer": "
HCP{0001}1 C 2<1120>D
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细写出HCP晶体的密排面、密排面间距、密排方向及其最小单位长度，需要文字解释和论述，答案形式为表格展示具体参数，符合简答题的特征。 | 知识层次: 题目要求写出HCP晶体的密排面、密排面间距、密排方向以及密排方向的最小单位长度，这需要理解HCP晶体的结构特点，并能够应用相关公式和概念进行计算和推导。虽然不涉及复杂的综合分析或创新应用，但需要多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 841, + "question": "Indicate and explain the reverse transformation phenomenon in the characteristics of martensitic transformation", + "answer": "When martensite is heated at a sufficiently rapid rate, it can directly transform back to the high-temperature phase without decomposition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体转变中的逆转变现象，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释马氏体逆转变现象，这涉及到对马氏体相变机理的深入理解，需要综合运用相变动力学和热力学知识进行分析和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 842, + "question": "Explain the formation reason of columnar crystal zone in typical ingot structure", + "answer": "After the formation of the fine-grained zone, the mold wall temperature increases, heat dissipation slows down, the cooling rate of the liquid decreases, the undercooling reduces, and nucleation no longer occurs. The crystals with fast growth rates in the fine-grained zone can develop along the direction opposite to heat dissipation, which is perpendicular to the mold wall. Their lateral growth is hindered due to mutual interference, thus forming columnar crystals with well-developed primary axes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释典型铸锭结构中柱状晶区的形成原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释柱状晶区的形成原因，涉及凝固过程中的热力学和动力学因素，需要综合分析冷却速率、过冷度、晶体生长方向等多个因素的相互作用，并进行机理层面的解释。这超出了简单记忆或基本应用的范围，属于需要深入理解和推理分析的复杂问题。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 843, + "question": "Indicate and explain the surface relief and shear coherency in the characteristics of martensitic transformation", + "answer": "Martensitic transformation produces uniform shear or lattice shear, causing structural changes, resulting in surface relief phenomena on the specimen. The interface between martensite and the parent phase is a coherent interface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的表面浮雕和剪切共格性特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释马氏体相变的表面浮凸和剪切共格性特征，涉及对相变机理的深入理解和综合分析，需要将结构变化与表面现象关联起来，并进行推理分析。 | 难度: 在选择题型内，该题目属于高难度等级。题目要求考生不仅理解马氏体相变的基本概念，还需要掌握其表面浮凸现象和剪切共格性的机理。正确选项涉及对相变过程中均匀剪切或晶格剪切的结构变化、表面浮凸现象的成因以及马氏体与母相界面的共格性质的综合理解。这需要考生具备复杂分析能力，能够综合运用多个知识点进行推理和解释，符合选择题型中最高难度等级的要求。" + }, + { + "idx": 844, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of perfect dislocations in FCC crystals?", + "answer": "Perfect dislocation (relatively rare in actual crystals); 1 <110> 2; screw type, edge type, mixed type; local slip or local displacement; can slip or climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释和描述FCC晶体中完美位错的多个特征（名称、伯氏矢量、位错性质、形成方法和运动状态），答案提供了详细的文字解释而非单一选项或简单判断，符合简答题的特征。 | 知识层次: 题目考查的是FCC晶体中完美位错的基本概念，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态等记忆性知识，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生记忆并理解FCC晶体中完美位错的基本概念，包括位错名称、伯氏矢量、位错性质、形成方式和运动状态。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或比较。题目主要考察对定义和分类的记忆，属于选择题型中的中等难度（等级2）。" + }, + { + "idx": 845, + "question": "Point out and explain the strict orientation relationship between the new phase and the parent phase in the characteristics of martensitic transformation", + "answer": "The main orientation relationships between martensite and the parent phase are: 1 K·S relationship; 2 G-T relationship; 3 Nishiyama relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出并解释马氏体相变中新相与母相之间的严格取向关系，答案提供了具体的取向关系名称，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查马氏体相变中新生相与母相之间严格取向关系的基本概念记忆，包括K·S关系、G-T关系和Nishiyama关系等基础知识的列举和简单解释，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及马氏体相变的基本概念，但需要考生记忆并区分三种不同的取向关系（K·S关系、G-T关系和Nishiyama关系）。这比单纯记忆一个定义或概念（等级1）要复杂，但不需要进行复杂的分析或比较（等级3）。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 846, + "question": "Indicate and explain the internal substructure in the characteristics of martensitic transformation", + "answer": "In addition to lattice shear, martensitic transformation also involves lattice-invariant shear, accomplished through slip or twinning, resulting in the formation of dislocation or twin substructures within the martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的内部亚结构特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释马氏体相变的内部亚结构特征，涉及晶格剪切和晶格不变剪切的机制，以及位错或孪晶亚结构的形成。这需要综合运用相变理论、晶体缺陷知识，并进行机理层面的解释和分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解马氏体相变的内部亚结构特征，包括晶格剪切和晶格不变剪切机制（滑移或孪生），并能解释由此产生的位错或孪晶亚结构。这需要综合运用相变机理知识，进行复杂的推理分析，属于\"复杂现象全面分析\"的知识层次。选择题型中仅凭正确选项就能看出其考查的知识深度和综合能力要求明显高于常规选择题。" + }, + { + "idx": 847, + "question": "Write the reaction equation for the decomposition of a perfect dislocation into an extended dislocation in a face-centered cubic (FCC) crystal, and analyze the possibility of the reaction.", + "answer": "Taking the (111) plane as an example, there are three reaction equations for the decomposition of a perfect dislocation into an extended dislocation on this plane: \\n(1) ${\\\\frac{1}{2}}[110]{-}{\\\\frac{1}{6}}[121]+{\\\\frac{1}{6}}[21\\\\overline{{1}}]$ Geometric condition: ${\\\\frac{1}{2}}[110]={\\\\frac{1}{6}}[121]+{\\\\frac{1}{2}}[21\\\\bar{1}]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\biggl[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\biggr]={\\\\frac{1}{3}}$ Therefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed. \\n(2) $\\\\frac{1}{2}[011]{\\\\rightarrow}\\\\frac{1}{6}[121]+\\\\frac{1}{6}[\\\\overline{{{1}}}12]$ Geometric condition: ${\\\\frac{1}{2}}[011]={\\\\frac{1}{6}}[121]+{\\\\frac{1}{2}}[\\\\overline{{{1}}}12]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\Big[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\Big]={\\\\frac{1}{3}}$ Therefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed. \\n(3) $\\\\frac{1}{2}[\\\\overline{{1}}01]{\\\\rightarrow}\\\\frac{1}{6}[\\\\overline{{1}}12]+\\\\frac{1}{6}[\\\\overline{{2}}\\\\overline{{1}}1]$ Geometric condition: $\\\\frac{1}{2}[\\\\overline{{1}}01]=\\\\frac{1}{6}[\\\\overline{{1}}12]+\\\\frac{1}{6}[\\\\overline{{2}}\\\\overline{{1}}1]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\Big[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\Big]={\\\\frac{1}{3}}$ \\nTherefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出反应方程式并分析反应的可能性，答案提供了详细的反应方程式和几何条件、能量条件的分析，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求写出面心立方晶体中完美位错分解为扩展位错的反应方程，并分析反应的可能性。这需要深入理解位错反应的条件（几何条件和能量条件），并进行综合分析和计算。涉及多个步骤的推理和复杂的机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握面心立方晶体中位错分解的基本概念，还需要能够写出具体的反应方程式，并进行几何条件和能量条件的分析。这需要考生具备以下能力：" + }, + { + "idx": 848, + "question": "Point out and explain the diffusionless characteristic of martensitic transformation", + "answer": "The transformation process involves no compositional change, with all participating atoms moving in a coordinated manner, maintaining unchanged relative positions between neighboring atoms, and the relative displacement being less than one atomic spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的无扩散特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体相变的无扩散特性，涉及原子协同运动、相对位置不变等机理层面的深入分析，需要综合运用相变理论和原子运动知识进行推理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解马氏体相变的无扩散特性，涉及原子运动的协调性、相对位置不变性以及位移限制等复杂机理。正确选项综合了多个高阶概念（成分不变性、协同运动、原子间距限制），需要考生具备将抽象相变机理转化为具体描述的能力。这种题目不仅测试记忆，更考察对材料科学核心原理的深度整合和应用能力，远超选择题常见的识别或简单推理层次。" + }, + { + "idx": 849, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of the L-C sessile dislocation in FCC crystals?", + "answer": "L-C sessile dislocation (with multiple configurations); for example—[110] 6; screw-type, edge-type, mixed-type; formed by the synthesis of Shockley partial dislocations (or dislocation reactions); cannot move", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释L-C sessile dislocation的多个属性（名称、Burgers矢量、位错性质、形成方法和运动状态），答案提供了详细的文字描述而非选择或判断，符合简答题的特征。 | 知识层次: 题目要求对L-C sessile dislocation的多个方面（名称、Burgers矢量、位错性质、形成方法和运动状态）进行综合描述，涉及多个概念的关联和综合分析。虽然部分内容需要记忆（如Burgers矢量），但整体上需要对位错的形成机制和性质进行理解和关联，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生综合掌握L-C sessile位错的多个特征（名称、Burgers矢量、位错性质、形成方式、运动状态），并需要将这些概念关联起来进行分析。此外，题目涉及FCC晶体中位错反应和Shockley不全位错等较深入的概念，要求考生能够进行多角度分析和论述。虽然题目给出了正确选项，但理解这些选项背后的原理和关联性需要较强的综合分析能力。" + }, + { + "idx": 850, + "question": "Indicate and explain the habit plane and its invariance in the characteristics of martensitic transformation", + "answer": "Martensite forms on certain crystallographic planes of the parent phase, and these planes are called habit planes. The habit plane is an undistorted and non-rotating plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变中惯习面的概念及其不变性特征，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查马氏体相变中习惯面的定义和基本特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生不仅记住habit plane的定义，还要理解其在马氏体相变中的不变性特征（undistorted and non-rotating plane）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。选择题型中，该题目要求考生能够解释和描述概念特征，符合等级2的标准。" + }, + { + "idx": 851, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of the Shockley partial dislocation in FCC crystals?", + "answer": "Shockley partial dislocation; 1 <112> 6; screw-type, edge-type, mixed-type; can only be formed through local slip of the crystal; even edge-type partial dislocations can only slip, not climb. Even screw-type partial dislocations cannot cross-slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Shockley partial dislocation的多个属性（名称、Burgers矢量、位错性质、形成方法和运动状态），答案提供了全面的文字解释而非选择或计算，符合简答题的特征。 | 知识层次: 题目要求对Shockley partial dislocation的多个属性（如Burgers vector、dislocation nature、formation method、motion state）进行综合描述，需要理解并关联多个概念，但不需要进行复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握Shockley部分位错的基本概念，还需要理解其Burgers矢量、位错性质、形成方式以及运动状态等多个方面的知识。此外，题目还涉及到位错的具体类型（螺型、刃型、混合型）及其运动限制（滑移、攀移、交叉滑移），这需要考生具备较强的综合分析能力和概念关联能力。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 852, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of the Frank partial dislocation in FCC crystals?", + "answer": "Frank partial dislocation; 1 <111> 3; edge type; formed by inserting or removing a layer of {111} close-packed plane in a local region of the crystal; can only climb, cannot glide", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Frank partial dislocation在FCC晶体中的多个属性（名称、Burgers矢量、位错性质、形成方法和运动状态），答案以文字形式给出详细说明，符合简答题的特征。 | 知识层次: 题目要求回答Frank部分位错的多个属性（名称、Burgers矢量、位错性质、形成方法和运动状态），涉及多个概念的关联和综合分析，需要理解位错的基本性质及其在FCC晶体中的具体表现，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，要求考生掌握Frank部分位错的多个关键属性（名称、Burgers矢量、位错性质、形成方法和运动状态），并能够将这些概念综合关联起来。题目不仅考察单一知识点的记忆，还需要对FCC晶体中位错行为的深入理解，涉及多步分析和概念整合。此外，正确选项中的信息较为复杂，需要考生具备较强的综合分析能力。" + }, + { + "idx": 854, + "question": "When the vacancy equilibrium concentration in germanium crystals decreases by six orders of magnitude from $600\\\\%$ to $300\\\\mathrm{\\\\textperthousand}$, calculate the vacancy formation energy in germanium crystals (Boltzmann constant $k=8.617\\\\times10^{-5}\\\\mathrm{eV}/\\\\mathrm{K})$.", + "answer": "The equilibrium concentration formula for Schottky defects is: $$\\\\begin{array}{r l}&{\\\\mathrm{atsing~sefiell}\\\\eta+\\\\mathrm{fight}\\\\mathcal{R}\\\\Sigma\\\\Delta t:}\\\\ &{\\\\qquad\\\\overline{{C}}_{\\\\mathrm{s}}\\\\leq e\\\\Bigg\\\\{-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg\\\\}=\\\\mathrm{evel}\\\\Bigg(-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg)=\\\\mathrm{evel}\\\\Bigg(-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg)}\\\\ &{\\\\mathrm{atsin}}\\\\ &{\\\\frac{\\\\Delta C_{s}}{H\\\\mathcal{N}_{x}\\\\Gamma}=-\\\\mathrm{in}\\\\overline{{C}}_{s},}\\\\ &{\\\\frac{\\\\Delta C_{s}}{\\\\Delta W_{x}}\\\\Bigg(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\Bigg)=\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}-\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}}\\\\ &{\\\\Delta G_{s}=\\\\frac{\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}-\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}}{\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}}(k\\\\chi_{x})}\\\\ &{\\\\qquad-\\\\frac{1}{\\\\frac{\\\\mathrm{fim}}{2}-\\\\frac{1}{T_{2}}}\\\\frac{\\\\kappa_{\\\\mathrm{B}}\\\\lambda_{1}\\\\Gamma\\\\kappa_{\\\\mathrm{m}}t^{-1}}{-\\\\frac{1}{\\\\omega_{0}+2/3}}}\\\\ &{\\\\qquad\\\\frac{1}{3(\\\\omega+2/3)}-\\\\frac{1}{6(\\\\omega+2/3)}}\\\\ &{\\\\qquad\\\\nu\\\\neq\\\\ell\\\\geq\\\\frac{1}{\\\\mathrm{in}\\\\mathcal{L}_{x}\\\\Bigg\\\\{1,2,3\\\\}\\\\Gamma\\\\kappa_{\\\\mathrm{m}}\\\\mathcal{R}_{x}\\\\Bigg\\\\}.}\\\\end{array}$$ That is, $10^{5}\\\\mathrm{J}^{\\\\cdot}\\\\mathrm{mol}^{-1}$ in germanium crystals.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空位形成能，答案中包含了具体的计算公式和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用Schottky缺陷的平衡浓度公式，进行多步计算和温度与浓度关系的综合分析。虽然涉及基本的公式应用，但需要理解温度变化对空位浓度的影响，并进行对数运算和能量计算，属于中等应用层次。 | 难度: 在选择题型中，这道题目属于高难度等级。题目涉及复杂的多步计算和概念关联，需要考生深入理解Schottky缺陷的平衡浓度公式，并能正确应用Boltzmann常数进行能量计算。题目中的公式推导和变量处理较为复杂，且需要考生具备综合分析能力，能够将多个物理概念和数学步骤结合起来解决问题。此外，题目中的符号和表达式较为复杂，增加了理解和解题的难度。因此，在选择题型内，这道题目属于复杂多变量计算的高难度等级。" + }, + { + "idx": 855, + "question": "Explain one of the main mechanisms of alloy strengthening from a microstructural perspective: solid solution strengthening, and provide examples", + "answer": "Solid solution strengthening occurs when alloying atoms dissolved in the lattice interstices or lattice points, due to their different sizes compared to the matrix atoms, create stress fields that hinder dislocation movement. Examples include Cottrell atmospheres and Suzuki atmospheres. The former refers to interstitial atoms preferentially distributing in the tensile stress region of edge dislocations in BCC metals, pinning the dislocations. The latter involves alloying elements preferentially distributing in the stacking fault regions of extended dislocations in FCC metals, reducing stacking fault energy, expanding the stacking fault region, and making the slip of extended dislocations more difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的主要机制之一（固溶强化），并从微观结构角度进行说明，同时提供例子。答案需要详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释固溶强化的主要机制，并提供具体例子（如Cottrell和Suzuki气团）。这需要深入理解位错与溶质原子的相互作用、应力场分布以及不同晶体结构（BCC/FCC）中的强化机理，涉及多概念关联和机理解释，属于综合分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握合金强化的基本概念，还需要深入理解固溶强化的微观机制，包括位错与溶质原子的相互作用（如Cottrell气团和Suzuki气团的形成原理）。此外，题目还要求考生能够区分BCC和FCC金属中不同的强化机制，并解释其对位错运动的影响。这种题目需要考生具备扎实的材料科学基础和综合分析能力，能够将多个复杂概念联系起来进行推理分析，因此在选择题型中属于最高难度等级。" + }, + { + "idx": 856, + "question": "Explain the second main mechanism of alloy strengthening from the microstructure perspective: precipitation strengthening and dispersion strengthening, and provide examples", + "answer": "Alloy strengthening is caused by compounds of alloying elements and matrix elements obtained through phase transformation processes and hard particles mechanically mixed into the matrix material, which are referred to as precipitation strengthening and dispersion strengthening, respectively. The effects of precipitation strengthening and dispersion strengthening are far greater than those of solid solution strengthening. When dislocations encounter second phases during movement, they need to cut through (small-sized particles in precipitation strengthening and particles in dispersion strengthening) or bypass (large-sized particles in precipitation strengthening) the second phases. Therefore, the second phases (precipitates and dispersoids) hinder dislocation movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第二种主要机制，并从微观结构角度详细说明沉淀强化和弥散强化，同时提供例子。答案需要详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释合金强化的第二种主要机制（沉淀强化和弥散强化），并提供实例。这需要综合运用材料科学中的相变过程、位错理论、第二相粒子与位错相互作用等知识，进行机理层面的深入分析和解释。同时，还需要结合实际例子进行说明，体现了较高的综合分析能力和深度理解要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从微观结构角度解释合金强化的第二种主要机制（沉淀强化和弥散强化），并举例说明。正确选项不仅需要理解沉淀强化和弥散强化的定义，还需要掌握它们与固溶强化的效果比较，以及位错运动与第二相颗粒相互作用的机理。这涉及到多个复杂概念的整合和深度理解，属于复杂现象全面分析的层次。在选择题型中，这种题目需要考生具备较高的知识掌握深度和综合分析能力，因此属于最高难度等级。" + }, + { + "idx": 857, + "question": "When an aluminum (Al) single crystal is stretched along the [123] direction to induce plastic deformation, determine the rotation law and rotation axis of the crystal during double slip.", + "answer": "During double slip, the specimen axis rotates toward [101], with the rotation axis being n1=[11¯2]×[10¯1]=[¯1¯1¯1], and also rotates toward [011], with the rotation axis being n2=[11¯2]×[01¯1]=[111]. Therefore, the resultant rotation axis is n=n1+ n2=[000], meaning the crystal orientation no longer changes and is only elongated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体在双滑移过程中的旋转规律和旋转轴，答案提供了详细的文字解释和论述，没有涉及选择、判断或数值计算。 | 知识层次: 题目要求分析铝单晶在双滑移过程中的旋转规律和旋转轴，涉及晶体塑性变形机制的综合理解和推理分析。需要综合运用晶体学、滑移系选择、旋转轴计算等知识，并进行多步推理和解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用晶体塑性变形、双滑移机制、晶体旋转定律等复杂概念，并进行矢量运算和空间几何分析。解题步骤涉及多个高阶知识点的整合，包括确定滑移方向、计算旋转轴、理解双滑移条件下的合成效应等。正确选项的推导需要深入理解晶体力学行为并具备较强的空间推理能力，远超一般选择题的认知要求。" + }, + { + "idx": 858, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Please determine the double slip systems.", + "answer": "When point F1 moves to point F2, double slip occurs. The double slip systems are:", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定双滑移系统，而不是从选项中选择、判断对错或进行数值计算。答案也以文字形式呈现，解释了双滑移系统的发生条件和具体系统。 | 知识层次: 题目要求确定铝单晶在[123]方向拉伸变形时的双滑移系统，这需要综合运用晶体学知识、滑移系统分析以及变形机制的理解。解题过程涉及多个步骤的分析和推理，包括确定可能的滑移系统、计算施密特因子、分析滑移系统的激活条件等，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 859, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Determine the rotation rule and rotation axis.", + "answer": "During single slip, the specimen axis should rotate towards [101], and the rotation axis is [12¯3]×[10¯1]=[¯1¯1¯1].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述塑性变形过程中的旋转规则和旋转轴，答案提供了详细的文字解释和向量计算，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求确定单晶铝在拉伸变形过程中的旋转规则和旋转轴，这需要综合运用晶体塑性变形的基本原理、滑移系统的选择、晶体取向变化等知识。解答过程涉及多个概念的关联和综合分析，包括滑移方向的确定、旋转轴的计算以及旋转方向的判断，思维过程较为复杂，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 860, + "question": "Explain one of the main mechanisms of alloy strengthening from the microstructure perspective: order strengthening, and provide an example", + "answer": "In ordered alloys, dislocations are superdislocations. To induce plastic deformation in the metal, both partial dislocations of the superdislocation must move simultaneously, requiring greater external stress. The bonding force between atoms of different elements is stronger than that between atoms of the same element, so the ordered arrangement of dissimilar atoms imparts higher strength to ordered alloys. For example, high-strength nickel-based superalloys contain ordered precipitate phases Ni(Ti, Al), whose strengthening mechanisms include general precipitation strengthening and order strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的主要机制之一（有序强化），并从微观结构角度进行论述，同时提供一个例子。答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释合金强化的主要机制之一——有序强化，并提供一个实例。这需要深入理解有序合金中位错的行为、原子间相互作用以及强化机制的综合分析。此外，还需要将理论知识与实际材料（如镍基高温合金）的应用相结合，体现了对概念的深度理解和综合运用能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求从微观结构角度解释合金强化的主要机制之一——有序强化，并提供一个具体例子。正确选项不仅需要理解有序合金中位错（超位错）的运动机制，还需要掌握不同元素原子间结合力与同种元素原子间结合力的差异，以及这些差异如何影响合金强度。此外，选项还要求联系实际材料（镍基高温合金）的具体强化机制，涉及沉淀强化和有序强化的综合知识。这种题目需要考生具备深入的材料科学机理知识、综合分析和应用能力，以及将理论知识与实际材料案例相结合的能力，因此在选择题型中属于最复杂的分析层次。" + }, + { + "idx": 861, + "question": "Stretch the aluminum (Al) single crystal along the [123] direction to induce plastic deformation, determine the final orientation of the crystal.", + "answer": "The final orientation of the crystal is F2, namely [112].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过分析和解释来确定铝单晶在拉伸后的最终取向，答案需要文字描述和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解晶体塑性变形的机制，并应用晶体学知识确定变形后的取向。这涉及到多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。该题目要求考生掌握晶体塑性变形的基本原理，并能将[123]方向的拉伸与最终的晶体取向[112]联系起来。解题过程中需要应用晶体学知识，进行多步计算和综合分析，但题目提供了正确选项，降低了部分难度。" + }, + { + "idx": 862, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Determine the crystal orientation and shear strain at the onset of double slip.", + "answer": "It can be calculated as follows: L=l+γ(l⋅n)b Substituting into the above equation: [m] =[123] + [[123][][10] √3 1√2 Thus, v=1+γ4/√6=2, W=−3−γ4/√6 Solving gives v=2, w=−4, γ=√6/4 That is, the orientation at the onset of double slip is [112], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体取向和剪切应变，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目涉及晶体塑性变形中的双滑移起始条件计算，需要多步计算和概念关联（如晶体取向、剪切应变计算），并需要综合分析滑移系激活条件。虽然不涉及复杂机理分析或创新设计，但已超出简单套用公式的范畴。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和概念关联，需要综合分析晶体取向和剪切应变的关系。解题过程包括向量运算、方程求解和物理概念应用，对学生的计算能力和理解深度要求较高。" + }, + { + "idx": 863, + "question": "Explain one of the three main mechanisms of alloy strengthening from a microstructural perspective: grain boundary strengthening, and provide an example", + "answer": "According to the Hall-Petch formula, the relationship between the yield point σs and the grain diameter d is σs=σ0+k d^(-1/2). The essence is that additional stress is required for dislocations to cross grain boundaries. Therefore, steels for low-temperature applications often adopt a fine-grained structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金强化的机制之一（晶界强化），并提供例子，需要文字解释和论述。答案中包含了理论解释（Hall-Petch公式）和实际应用例子（低温用钢的细晶结构），符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释合金强化的机制之一（晶界强化），并给出实例。这需要理解Hall-Petch公式及其物理意义，同时能够将理论知识与实际应用（如低温用钢的细晶结构）联系起来。虽然涉及基础概念，但需要一定的概念关联和综合分析能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hall-Petch公式的基本概念及其物理意义，并能将其与具体的应用实例（低温用钢的细晶结构）联系起来。题目要求考生不仅掌握公式本身，还要能够解释其微观机制，并给出实际应用的例子，这涉及多步的概念关联和综合分析。" + }, + { + "idx": 864, + "question": "There are two edge dislocations 1 and 2 separated by a distance d, with Burgers vectors b₁ and b₂ respectively. Given the stress field of the edge dislocation as σ_x, σ_y, σ_z, τ_xy, determine the climb force on dislocation 2 due to dislocation 1.", + "answer": "The climb force f_{y,12} = σ_x b₂ = - (G b₁ b₂) / (2π(1-ν)) * (d(3x² + d²)) / (x² + d²)²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的应力场和Burgers向量计算攀移力，涉及数值计算和公式应用，答案以具体公式形式给出。 | 知识层次: 题目需要理解位错应力场的概念，并应用给定的应力场公式进行多步计算，涉及位错间相互作用力的推导，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解位错应力场和攀移力的概念，并进行多步计算和综合分析。题目涉及多个变量和公式推导，要求考生具备较强的应用能力和综合分析能力。" + }, + { + "idx": 865, + "question": "There are two edge dislocations 1 and 2 separated by a distance d, with Burgers vectors b₁ and b₂, respectively. Given the stress field of an edge dislocation as σ_x, σ_y, σ_z, τ_xy, determine the glide force on dislocation 2 caused by dislocation 1.", + "answer": "The glide force f_{x,12} = -τ_{xy}b₂ = - (G b₁ b₂) / (2π(1-ν)) * (x(x² - d²)) / (x² + d²)²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的应力场和公式计算位错2的滑移力，答案涉及具体的数学表达式和数值计算过程。 | 知识层次: 题目涉及两个位错之间的相互作用力计算，需要理解位错的应力场公式，并应用给定的公式进行多步计算。虽然题目提供了具体的应力场表达式，但仍需要理解位错间相互作用的物理机制，并进行适当的数学推导和计算。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目涉及两个位错之间的相互作用力计算，需要掌握位错应力场的基本公式，并能正确应用应力场公式计算相互作用力。解题步骤包括理解位错应力场、正确识别应力分量对滑移力的贡献、以及进行代数运算。虽然题目给出了正确选项，但需要较强的概念理解和计算能力才能正确选择答案。" + }, + { + "idx": 866, + "question": "Write the expression for the equilibrium concentration of point defects and indicate the physical meaning of each parameter.", + "answer": "The Schottky defect concentration Cs = exp(-ΔGs/RT), where Cs is the equilibrium concentration of Schottky point defects; ΔGs is the molar Gibbs free energy of formation for Schottky point defects; T is the thermodynamic temperature (K) of the system; R is the molar gas constant. The Frenkel defect concentration CF = exp(-ΔGF/RT), where CF is the equilibrium concentration of Frenkel point defects; ΔGF is the molar Gibbs free energy of formation for Frenkel point defects; T is the thermodynamic temperature (K) of the system; R is the molar gas constant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出点缺陷平衡浓度的表达式并解释每个参数的物理意义，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对Schottky和Frenkel点缺陷平衡浓度表达式的记忆，以及各参数物理意义的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念的记忆，但需要考生准确理解并区分Schottky缺陷和Frenkel缺陷的表达式及其参数含义。这要求考生不仅记住公式，还要理解每个参数的物理意义，属于概念解释和描述的层次。相比于仅要求记忆基本定义的题目（等级1），该题目对知识点的掌握深度要求更高，但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 867, + "question": "There are two single-crystal Zn rods (Zn has an HCP structure with c/a=1.86), with the axial direction [0001]. Now, under room temperature conditions, they are stretched along the axial direction. Analyze the possible deformation modes and write the corresponding slip systems or twinning systems (if activated).", + "answer": "When the Zn rod with the axial direction [0001] is stretched along the axial direction, the axial elongation occurs, which is opposite to the length change trend during twinning, so twinning is not possible. During stretching, the external force is along the axial direction [0001], perpendicular to the slip plane (0001), so the Schmid factor is 0, and slip cannot occur. Therefore, when the Zn rod with the axial direction [0001] is stretched along the axial direction, the Zn rod will fracture in a brittle manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析可能的变形模式并写出相应的滑移系统或孪生系统（如果激活），这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析HCP结构Zn单晶在特定轴向拉伸条件下的变形模式，涉及对滑移系和孪生系激活条件的深入理解，需要综合运用晶体学、力学和材料变形机制的知识进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握HCP晶体结构的基本知识，还需要深入理解滑移系和孪生系的激活条件，并能综合运用Schmid因子分析外力方向与滑移系的关系。此外，题目还涉及脆性断裂的机理，需要考生具备复杂现象全面分析的能力。这些要求都超出了基础知识的范畴，属于复杂分析层次。" + }, + { + "idx": 868, + "question": "Write the expression for the relationship between the diffusion coefficient and temperature, and indicate the physical meaning of each parameter.", + "answer": "D=D0exp(-Q/RT), where D0 is the diffusion constant or frequency factor; Q is the diffusion activation energy (J/mol); T is the thermodynamic temperature of the system (K); R is the molar gas constant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出扩散系数与温度关系的表达式，并解释各参数的物理意义。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对扩散系数与温度关系的基本公式的记忆，以及各参数物理意义的理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求写出扩散系数与温度关系的表达式并解释各参数物理意义，但正确选项已经提供了完整的公式和参数解释。这需要考生对基础概念有一定的记忆和理解，但不需要进行复杂的分析或推导。题目主要考察对基本公式和参数定义的记忆，属于概念解释和描述的层次。" + }, + { + "idx": 870, + "question": "What are the three typical zones of a metal ingot structure?", + "answer": "Chill zone, columnar crystal zone, and equiaxed crystal zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属铸锭结构的三个典型区域，答案是以文字形式简要列出具体区域名称，不需要计算或选择，符合简答题的特征 | 知识层次: 题目考查金属铸锭结构的三个典型区域的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求识别金属铸锭结构的三个典型区域名称，属于基础概念记忆层面。题目仅需回忆定义性知识，无需解释或分析，解题步骤简单直接，在选择题型内属于最低难度等级。" + }, + { + "idx": 872, + "question": "Many precipitate phases have specific orientation relationships with the parent matrix. Analyze the reasons for the formation of such orientation relationships.", + "answer": "To achieve low interfacial energy, the atoms on the primary interface between the parent phase and the new phase must have a good matching relationship, which can only be realized under certain orientation conditions. Therefore, specific orientation relationships exist between the precipitate phase and the parent phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析特定取向关系形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析析出相与母相特定取向关系形成的机理，涉及界面能、原子匹配等概念的关联和综合分析，需要深入理解材料科学中的相变和界面理论，并进行推理分析。 | 难度: 在选择题型内属于最高难度等级，因为题目要求考生不仅理解沉淀相与母相之间的取向关系，还需要深入分析其形成机理（低界面能原理和原子匹配关系）。这涉及复杂现象的综合分析（晶体学匹配条件）和机理解释能力（能量最小化原理），远超单纯的概念记忆或简单应用。正确选项需要将材料科学基础理论与相变动力学知识相结合进行推理，符合选择题型中对\"复杂现象全面分析\"能力的最高要求。" + }, + { + "idx": 873, + "question": "What is the Kirkendall effect", + "answer": "On an FCC-structured α-brass (Cu+30%Zn) rod, very fine molybdenum wires are applied as markers, and then copper is plated on the brass, enclosing the molybdenum wires between the brass and copper. Diffusion is carried out at a certain temperature. The molybdenum wires serve only as markers and do not participate in the diffusion throughout the experiment. The diffusing components are copper and zinc, which form a substitutional solid solution. During the diffusion process in a substitutional solid solution, the markers placed at the original interface move toward the direction of the lower melting point element, with the displacement distance following a parabolic relationship with time. The reason for this phenomenon is that the lower melting point component diffuses faster, while the higher melting point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应的现象和原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要详细描述实验过程、扩散机制以及不同元素扩散速率的差异如何导致标记物的移动。这涉及到对扩散现象的深入理解、不同元素扩散行为的比较分析以及实验现象的机理解释，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目不仅要求考生掌握Kirkendall效应的基本概念，还需要深入理解扩散机制、固溶体结构、标记物的作用以及不同元素扩散速率的差异。此外，题目涉及复杂的实验设计和现象解释，要求考生能够综合运用材料科学知识进行推理分析。这种深度和广度的知识要求，以及解题过程中的综合分析能力，使得该题目在选择题型中属于最高难度水平。" + }, + { + "idx": 874, + "question": "Propose three technical approaches to achieve the aforementioned zone enlargement, and briefly explain the theoretical basis.", + "answer": "1. Add refiners to promote heterogeneous nucleation; 2. Apply mechanical vibration to reduce dendrites and provide new nuclei; 3. Perform ultrasonic treatment or electromagnetic field treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提出三种技术方法并简要解释理论基础，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求提出三种技术方法并解释理论依据，涉及多步骤的思考和对不同技术方法的理解与应用，需要将理论知识与实际技术手段相结合，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅掌握基础概念，还需要综合运用多种技术方法并理解其理论依据。题目涉及三种不同的技术途径（添加细化剂、机械振动、超声波或电磁场处理），每种方法都需要考生理解其背后的科学原理（如异质形核、枝晶破碎、外场作用等）。这种多角度分析和概念关联的要求，超出了简单记忆或单一概念应用的层次，属于选择题型中较高难度的题目。" + }, + { + "idx": 875, + "question": "What is the Kirkendall effect? Please explain it using diffusion theory.", + "answer": "Kirkendall effect: In the diffusion process of substitutional solid solutions, markers placed at the original interface move towards the direction of the low-melting-point element, with the movement rate following a parabolic relationship with time. The Kirkendall effect negates the exchange mechanism of diffusion in substitutional solid solutions and confirms the vacancy mechanism; different components in the system have different partial diffusion coefficients. Relatively speaking, the low-melting-point component diffuses faster, while the high-melting-point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应并用扩散理论进行说明，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要运用扩散理论进行深入分析，涉及不同组分的扩散系数差异、空位机制等复杂概念，并需要将这些概念关联起来进行综合解释。这需要较高的分析能力和对扩散机理的深入理解。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解Kirkendall效应的基本概念，还需要运用扩散理论进行机理深度解释，涉及多个复杂概念的综合运用（如置换固溶体、扩散机制、部分扩散系数等）。正确选项包含了对现象全面分析的要素（如标记移动方向与时间的关系、不同组元扩散速率的差异等），这远超选择题型通常考查的记忆或简单理解层面，需要考生具备高阶推理和分析能力。" + }, + { + "idx": 876, + "question": "To obtain a casting with uniform composition and performance, which zone should be expanded?", + "answer": "To obtain a casting with uniform composition, the equiaxed crystal zone should be expanded.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个简短的陈述，解释了如何通过扩大等轴晶区来获得成分和性能均匀的铸件。 | 知识层次: 题目要求理解铸件均匀成分和性能的实现方法，需要将凝固组织的分区（等轴晶区）与性能关联起来，属于概念关联和中等应用层次。虽然不涉及复杂计算，但需要理解凝固过程和组织控制的基本原理。 | 难度: 在选择题中属于中等难度，需要理解铸件均匀成分与等轴晶区的关系，并进行综合分析。题目要求考生将材料科学中的晶体生长理论与实际铸造工艺联系起来，属于中等应用层次的知识点掌握和概念关联。" + }, + { + "idx": 877, + "question": "Determine whether the following dislocation reaction can occur in FCC and confirm the reaction direction in the absence of external force: 1/6[112]+1/6[110]⇔1/3[111]", + "answer": "It can occur, to the left.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否可以在FCC中发生，并确认反应方向，答案给出了明确的判断（可以发生）和方向（向左），属于判断陈述的对错类型。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应的方向和可能性。这涉及到多步分析和概念关联，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题型中，该题目需要综合分析位错反应的能量条件和方向判断，涉及多步计算和概念关联，属于中等应用层次。需要考生不仅理解位错反应的基本原理，还要能够应用这些原理进行具体分析，判断反应的方向和可能性。这种综合分析能力的要求使得该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 878, + "question": "During the aging treatment of alloy A, metastable phases often precipitate first. Discuss the reasons why the equilibrium phase does not precipitate based on thermodynamic and kinetic theories.", + "answer": "The initial precipitation of metastable phases occurs because the interfacial energy between the equilibrium phase and the parent phase is high, whereas that between the metastable phase and the parent phase is low. Interfacial energy is the primary energy barrier for nucleation during solid-state phase transformation. Overcoming this nucleation barrier for the equilibrium phase often requires significant undercooling before noticeable nucleation can occur in the system. From a kinetic perspective, at a certain degree of undercooling, if the metastable phase forms much faster than the equilibrium phase, which forms much more slowly, the alloy will preferentially form metastable phases during aging treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于热力学和动力学理论讨论合金时效处理中平衡相不析出的原因，需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求基于热力学和动力学理论解释合金时效处理中亚稳相优先析出的原因，涉及多个概念的关联和综合分析，需要深入理解界面能、形核势垒和过冷度等复杂机理，并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用热力学和动力学理论，深入理解亚稳相和平衡相析出的机理差异。正确选项不仅涉及界面能这一关键概念，还需要分析形核能垒和过冷度的关系，以及动力学速率差异对相变路径的影响。这种需要同时掌握多个高级概念并进行机理深度解释的题目，在选择题中属于最复杂的分析层次。" + }, + { + "idx": 879, + "question": "Two batches of industrial pure aluminum samples were rolled with the same deformation amount on June 5 and June 9, respectively, and then subjected to recrystallization annealing simultaneously on the 9th. The experiment found that for the same annealing time, the temperatures required to complete recrystallization were different for the two batches of samples. Which batch do you think has a higher recrystallization temperature, and why?", + "answer": "The sample deformed on June 5 may have undergone partial recovery during storage, as the stored deformation energy decreases. To initiate recrystallization, it requires higher activation energy compared to the sample that was not stored. Therefore, the sample from June 5 has a higher recrystallization temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么两批样品的再结晶温度不同，并需要论述原因，答案以文字解释和论述的形式给出，没有提供选项或要求计算。 | 知识层次: 题目需要综合运用材料科学中的变形、储存能量、回复和再结晶等概念，分析不同储存时间对再结晶温度的影响机制。解答过程涉及能量状态变化、激活能需求等深层次原理的推理和解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 880, + "question": "Briefly describe Pauling's rules", + "answer": "Pauling's rules: $\\textcircled{1}$ The coordination polyhedron rule: A coordination polyhedron of anions is formed around a cation. The distance between the cation and anion depends on the sum of their ionic radii, while the coordination number depends on the ratio of their ionic radii. $\\textcircled{2}$ The electrostatic valence rule: In forming an ionic bond, the number of valence electrons given by the cation equals the number received by the anion. $\\textcircled{3}$ The rule of polyhedron linkage: Coordination polyhedra tend to share vertices, followed by edges and faces. The higher the cation's valence and the lower its coordination number, the more pronounced this effect. $\\textcircled{4}$ In crystals containing more than one type of cation, the coordination polyhedra of anions around cations with higher valence and smaller coordination numbers tend to share vertices. $\\textcircled{5}$ The types of coordination polyhedra in a crystal tend to be minimal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Pauling's rules，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目主要考查对Pauling规则的基本概念的记忆和理解，包括其五个主要规则的描述。这些内容属于材料科学中晶体结构的基础知识，不需要复杂的应用或分析，只需对规则进行简要解释即可。 | 难度: 在选择题型中，该题目属于高难度等级。虽然题目要求的是基础概念记忆，但Pauling's rules包含五个具体规则，每个规则都需要准确理解和记忆。选择题型中，正确选项需要涵盖所有规则，考生必须能够区分和识别每个规则的具体内容。此外，这些规则涉及多个相关概念（如配位多面体、离子半径、电价等），需要考生具备较高的知识整合能力。因此，在选择题型内，该题目属于复杂概念体系阐述的难度等级。" + }, + { + "idx": 881, + "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, determine the lattice constant a of diamond.", + "answer": "The nearest neighbor atomic spacing is 0.1544nm, i.e., the bond length d = 0.1544nm. In the diamond structure, the relationship between the bond length and the lattice constant is d = (a√3)/4, thus a = (4d)/√3 = (4 × 0.1544nm)/1.732 ≈ 0.3566nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（d = (a√3)/4）来确定晶格常数a，解答过程涉及具体的数学运算和单位转换，属于典型的计算题。 | 知识层次: 题目涉及基本的公式应用和简单计算，即通过已知的原子间距和钻石结构的几何关系直接套用公式求解晶格常数。虽然需要理解钻石结构的基本几何关系，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解钻石结构中原子间距与晶格常数的关系，但解题步骤直接，仅需套用一个基本公式（d = (a√3)/4）并进行简单代数运算即可得出答案。无需多个公式组合或复杂分析，因此属于等级2难度。" + }, + { + "idx": 882, + "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, determine the coordination number C.N. of diamond.", + "answer": "In the diamond structure, each carbon atom forms covalent bonds with 4 nearest neighbor carbon atoms, so the coordination number C.N. = 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来确定金刚石结构中的配位数，答案提供了详细的解释和结论，没有涉及计算、选择或判断对错的过程。 | 知识层次: 题目考查对金刚石结构中配位数的基本概念记忆和理解，仅需直接回答金刚石结构中每个碳原子与4个最近邻碳原子形成共价键这一基本事实，无需进行计算或深入分析。 | 难度: 在选择题型中，该题目仅考察对钻石结构配位数的基础定义记忆，属于最基础的概念简答。题目直接给出结构特征并询问配位数，无需任何复杂推理或计算步骤，完全基于对基本概念的掌握。" + }, + { + "idx": 883, + "question": "A compression test is conducted along the axial direction of an FCC metal single crystal specimen with a cross-sectional area of 10cm². The critical resolved shear stress is known to be 0.1kgf/mm², and the initial orientation of the rod axis is [215]. Please determine the double slip systems.", + "answer": "Double slip systems: (111)[011] + (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定双滑移系统，需要基于晶体学知识和方向分析进行文字解释和论述，答案以系统组合的形式给出，而非数值计算或选择判断。 | 知识层次: 题目需要理解FCC金属的滑移系统，并应用临界分切应力和晶体取向的知识来确定双滑移系统。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用晶体学知识、临界分切应力概念以及滑移系分析能力。解题过程涉及多个步骤：1) 确定FCC晶体的滑移系 2) 计算施密特因子 3) 分析初始取向[215]下的潜在滑移系 4) 判断双滑移条件。虽然题目给出了正确选项，但要在选择题中准确判断需要深入理解晶体塑性变形机制和滑移系激活条件，涉及中等应用层次的多步计算和概念关联。" + }, + { + "idx": 884, + "question": "Determine whether the following dislocation reaction can occur in FCC and confirm the reaction direction in the absence of external forces: 1/2[10−1]⇔1/6[2−1−1]+1/6[11−1]", + "answer": "It can occur, to the right.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否可以在FCC中发生，并确认反应方向，答案给出了明确的判断（可以发生）和方向（向右），符合判断题的特征。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应是否可行以及反应方向。这涉及到多步分析和概念关联，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题型中，该题目属于较高难度。需要综合运用以下能力：" + }, + { + "idx": 885, + "question": "A single crystal specimen of an FCC metal with a cross-sectional area of 10cm² is subjected to a compression test along its axial direction. Given that the critical resolved shear stress is 0.1kgf/mm² and the initial orientation of the rod axis is [215], determine the crystal orientation (i.e., the direction of the rod axis) when double slip begins.", + "answer": "The crystal orientation when double slip begins is: [102].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定晶体取向，需要文字解释和论述，答案是一个具体的晶体方向而非数值计算结果或选项选择。 | 知识层次: 题目需要理解临界分切应力的概念，并应用晶体取向和滑移系统的知识进行计算和分析。虽然涉及多步计算和概念关联，但不需要复杂的推理或深度理解。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及FCC金属的晶体取向和临界分切应力等专业概念，要求考生具备扎实的材料科学基础。其次，解题过程需要多步计算和综合分析，包括确定滑移系统、计算施密特因子、判断双滑移起始条件等。此外，题目还要求考生能够将理论知识与实际应用相结合，对晶体取向变化进行准确判断。虽然题目提供了正确选项，但解题过程的复杂性和对概念理解的深度要求使得该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 886, + "question": "A single crystal test bar of an FCC metal with a cross-sectional area of 10 cm² is subjected to a compression test along the axial direction. The critical resolved shear stress is known to be 0.1 kgf/mm², and the initial orientation of the bar axis is [215]. Please determine the initial slip system (specific indices are required).", + "answer": "Initial slip system: (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定初始滑移系统（需要具体的指数），这需要文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求确定初始滑移系统，需要理解FCC金属的滑移系概念，并应用临界分切应力定律进行计算。这涉及到多步计算和概念关联，包括确定可能的滑移面和滑移方向，计算施密特因子，并选择具有最大分切应力的滑移系统。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算和综合分析。具体来说，考生需要：" + }, + { + "idx": 887, + "question": "Term explanation: Lattice distortion", + "answer": "In local regions, atoms deviate from their normal lattice equilibrium positions, causing lattice distortion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Lattice distortion\"进行解释，需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查基本概念的记忆和理解，仅需要解释晶格畸变的定义，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求对\"Lattice distortion\"这一基础概念进行简单的定义记忆和识别。正确选项直接给出了该术语的标准定义，没有涉及概念间的比较或复杂分析，属于最基本的概念记忆层次。" + }, + { + "idx": 888, + "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, calculate the packing density ξ of diamond.", + "answer": "The diamond unit cell contains 8 atoms (each of the 8 corner atoms contributes 1/8, each of the 6 face-centered atoms contributes 1/2, and each of the 4 internal atoms contributes 1). The atomic radius r = d/2 = 0.0772nm. The packing density ξ = (total volume of atoms)/(volume of unit cell) = [(8 × (4/3)πr³)]/a³ = [8 × (4/3) × 3.1416 × (0.0772nm)³]/(0.3566nm)³ ≈ 0.34.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解金刚石的堆积密度，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算，包括原子半径的计算、单位晶胞体积的计算以及堆积密度的计算。此外，还需要理解金刚石晶胞中原子的分布和贡献比例，涉及多个概念的关联和综合分析。虽然不涉及复杂的推理或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解钻石晶胞的原子分布、计算原子半径、计算原子总体积和晶胞体积，并进行多步计算和综合分析。虽然题目提供了部分关键数据，但解题过程涉及多个概念和计算步骤，对学生的知识掌握和计算能力要求较高。" + }, + { + "idx": 889, + "question": "Determine whether the following dislocation reaction can proceed in FCC and confirm the reaction direction in the absence of external forces: 1/3[112]+1/2[111]⇔1/6[11−1]", + "answer": "The reaction cannot proceed.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能进行，并给出明确结论（\"The reaction cannot proceed\"），这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应是否可行。虽然不涉及复杂的计算，但需要对FCC晶体结构中的位错类型和反应方向有较深入的理解，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。需要综合运用位错反应的能量条件（Frank判据）和晶体学知识进行多步计算和判断。解题过程涉及矢量运算、能量比较和反应方向分析，属于需要综合分析结果判断的类型。虽然题目提供了反应式，但需要考生自行验证反应前后的能量变化和晶体学可行性，比单纯的概念识别或简单计算题更复杂。" + }, + { + "idx": 890, + "question": "If diffusion occurs in a Cu-Al diffusion couple, in which direction will the interface marker move?", + "answer": "When diffusion occurs in a Cu-Al diffusion couple, the interface marker will move toward the Al side.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释扩散偶中界面标记移动的方向，答案以文字解释的形式给出，没有提供选项或要求计算，属于简答题类型。 | 知识层次: 题目需要理解扩散偶中界面标记移动的机制，涉及不同金属的扩散速率差异和Kirkendall效应的概念。虽然不涉及复杂计算，但需要综合分析扩散方向和速率差异对界面标记位置的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解扩散偶中界面标记移动的原理，并综合分析Cu-Al扩散偶的特性。虽然不需要复杂的计算，但要求考生掌握扩散方向与浓度梯度的关系，并能将这一概念应用到具体材料体系中。" + }, + { + "idx": 891, + "question": "A single crystal test bar of FCC metal with a cross-sectional area of 10cm² is subjected to a compression test along the axial direction. The critical resolved shear stress is known to be 0.1kgf/mm², and the initial orientation of the bar axis is [215]. Please determine the final stable orientation of the crystal (assuming the test bar does not fracture before reaching the stable orientation).", + "answer": "The final stable orientation of the crystal: [101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定晶体的最终稳定取向，答案是一个具体的取向[101]，而不是通过计算或选择选项得出的结果。 | 知识层次: 题目需要理解FCC金属的晶体取向、临界分切应力的概念，并进行多步计算和综合分析，以确定晶体的最终稳定取向。这涉及到晶体滑移系统的选择和取向变化的分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用晶体学、力学和材料科学的知识。解题过程涉及多个步骤：理解FCC金属的滑移系统、计算施密特因子、确定临界分切应力条件，并推导晶体在压缩过程中的稳定取向。这需要考生不仅掌握基本概念，还要具备将多个知识点关联起来进行综合分析的能力。虽然题目给出了正确选项，但推导过程复杂，涉及矢量计算和晶体取向变化的判断，远超过简单记忆或单一概念应用的难度水平。" + }, + { + "idx": 892, + "question": "Term explanation: Burgers vector", + "answer": "An important vector describing the characteristics of a dislocation, which comprehensively reflects the magnitude and direction of the total distortion within the dislocation region; it also represents the amount of relative sliding of the crystal after the dislocation has swept through.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语\"Burgers vector\"进行解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对Burgers vector这一基本概念的定义和特性的记忆和理解，属于材料科学中位错理论的基础知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释Burgers vector的定义和特性，虽然涉及一定的专业术语和概念，但整体上属于对基础概念的记忆和理解，不需要复杂的分析或比较。正确选项提供了较为全面的解释，但并未涉及多个概念的交叉或复杂体系阐述。" + }, + { + "idx": 893, + "question": "A single crystal test bar of an FCC metal with a cross-sectional area of 10cm² is subjected to a compression test along the axial direction. Given that the critical resolved shear stress is 0.1kgf/mm² and the initial orientation of the bar axis is [215], determine the axial pressure P at the onset of double slip (without considering physical hardening).", + "answer": "P = (0.1×1000)/((√10/5)×(√10/5))×9.8N = 2450N.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定轴向压力P的值，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界分切应力、晶体取向、双滑移条件等概念，并进行综合分析和计算。 | 难度: 在选择题中属于中等偏上难度，需要理解临界分切应力、晶体取向与滑移系的关系，并进行多步骤的单位换算和向量计算。虽然题目提供了关键公式，但需要综合应用材料力学和晶体学知识才能正确求解。" + }, + { + "idx": 894, + "question": "Term explanation: phase diagram", + "answer": "A graphical representation describing the conditions for phase equilibrium or the coexistence relationships of phases; it can also be referred to as the geometric trajectory of thermodynamic parameters at equilibrium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语进行解释，答案是一段文字描述，属于简答题类型 | 知识层次: 题目考查对相图这一基础概念的定义和基本理解，属于记忆性知识范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释\"phase diagram\"这一基础概念，但正确选项提供了较为详细的描述，包括图形表示、相平衡条件以及热力学参数轨迹等。这需要学生对相图有基本的理解和记忆，而不仅仅是简单的定义复述。因此，该题目在选择题型中属于概念解释和描述级别(等级2)。" + }, + { + "idx": 895, + "question": "A single crystal test bar of FCC metal with a cross-sectional area of 10 cm² is subjected to a compression test along the axial direction. The critical resolved shear stress is known to be 0.1 kgf/mm², and the initial orientation of the bar axis is [215]. Please answer the rotation law and rotation axis when slip begins.", + "answer": "Since it is compression, the rotation law is: F→[111], and the rotation axis is [215]×[111]=[633]=[211].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释旋转定律和旋转轴，需要文字解释和论述，答案也以文字形式给出，没有涉及计算或选择。 | 知识层次: 题目需要理解FCC金属的滑移系统、临界分切应力概念，并应用施密特定律计算滑移方向。同时需要掌握晶体旋转规律和向量叉乘计算，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及FCC金属的压缩测试、临界分切应力、晶体取向以及旋转定律和旋转轴的计算。解题步骤包括理解压缩条件下的旋转定律（F→[111]），以及计算旋转轴（[215]×[111]）。虽然需要多步计算和概念关联，但在选择题型中，正确选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 896, + "question": "Term explanation: deformation texture", + "answer": "The phenomenon of crystallographic orientation preference occurring during polycrystalline deformation is called deformation texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语进行解释，答案是一段文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"deformation texture\"这一基本概念的定义和记忆，属于材料科学中基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"deformation texture\"的基本定义，属于最基础的概念记忆层次。题目直接给出了术语的明确定义，不需要进行任何解释、比较或分析，完全符合等级1\"基本定义简答\"的标准。这种题目在选择题中属于最简单的一类，只需考生对专业术语有最基本的记忆即可作答。" + }, + { + "idx": 897, + "question": "Term explanation: Degree of supercooling", + "answer": "In the phase transformation process, after cooling to a certain temperature below the phase transition point, the transformation occurs. The difference between the equilibrium phase transition temperature and this actual transformation temperature is called the degree of supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Degree of supercooling\"这一术语进行解释，答案提供了详细的文字说明和定义，符合简答题的特征。 | 知识层次: 题目考查对\"Degree of supercooling\"这一基本概念的定义和解释，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Degree of supercooling\"这一概念的定义，需要考生理解并准确描述相变过程中平衡相变温度与实际转变温度之间的差异。虽然涉及专业术语，但只需记忆和复述基本定义，不需要进行复杂的概念体系阐述或多概念比较分析。在选择题型内，这属于中等偏基础的概念性题目。" + }, + { + "idx": 898, + "question": "Term explanation: Slip system", + "answer": "In a crystal, the combination of a slip plane and a slip direction on that plane is called a slip system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Slip system\"进行解释，需要文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对\"Slip system\"这一基本概念的定义记忆和理解，属于材料科学中晶体变形的基础知识，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"slip system\"的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的定义，不需要进行比较分析或复杂推理，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 899, + "question": "Write the mathematical expression of Fick's first law and explain its significance.", + "answer": "In one dimension, J=-D(dc/dx). J: diffusion flux, the amount of substance diffusing per unit time through a unit area, g/s·m²; D: diffusion coefficient, m²/s; dc/dx: concentration gradient, g/m³. Its significance is that the amount of substance diffused is proportional to the concentration gradient of the substance and in the opposite direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出Fick第一定律的数学表达式并解释其意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Fick第一定律的基本数学表达式及其物理意义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅记忆Fick's第一定律的数学表达式，还需要解释其物理意义和各符号的含义。这超出了单纯的定义记忆（等级1），但并未涉及复杂的概念体系或深入的分析（等级3）。因此，属于概念解释和描述的难度等级2。" + }, + { + "idx": 900, + "question": "Term explanation: Twinning", + "answer": "Twinning refers to the shear process in which a crystal undergoes deformation by forming twins under stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Twinning\"进行解释，需要提供文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"Twinning\"这一晶体变形过程的基本定义和概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题仅要求对\"Twinning\"这一基础概念进行简单的定义记忆和识别。正确选项直接给出了明确的定义描述，不需要进行概念间的比较或复杂推理，属于最基本的概念记忆层次。" + }, + { + "idx": 901, + "question": "What are the general structural zones of an ingot? List their names.", + "answer": "It is divided into three crystal zones: chill zone, columnar crystal zone, and central equiaxed crystal zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出铸锭的一般结构区域名称，答案以文字解释的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对铸锭结构区域的基本分类和名称的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和复述铸锭的三个基本结构区域名称（激冷区、柱状晶区和中心等轴晶区），属于基础概念记忆层次。题目不涉及解释或复杂概念体系阐述，解题步骤简单直接，只需识别正确选项即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 902, + "question": "Briefly describe the changes in mechanical properties of deformed metals during annealing", + "answer": "Hardness and strength decrease, elongation increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述变形金属在退火过程中机械性能的变化，答案以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目考查对退火过程中金属机械性能变化的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目仅要求考生记忆并选择描述退火过程中金属机械性能变化的基本定义。题目涉及的知识点非常基础，属于金属材料科学中最基本的记忆性内容，不需要任何解释或分析步骤。正确选项直接给出了硬度、强度和延伸率变化的简单描述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 903, + "question": "Term explanation: secondary recrystallization", + "answer": "The phenomenon of abnormal growth of a few grains occurring when normal growth is inhibited after the completion of recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语进行解释，需要文字解释和论述，答案形式为一段文字描述，符合简答题的特征 | 知识层次: 题目考查对\"二次再结晶\"这一基本概念的定义记忆和理解，属于材料科学中基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求解释\"secondary recrystallization\"这一专业术语，但正确选项提供了明确的定义描述，不需要进行复杂的概念体系阐述或比较分析。学生只需理解并记忆该现象的基本定义即可作答，不需要深入理解其机理或与其他概念的关联。因此，在选择题型内属于中等偏下的难度水平。" + }, + { + "idx": 904, + "question": "Briefly describe the changes in stored energy during the annealing process of deformed metals", + "answer": "The stored energy is gradually released.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述变形金属退火过程中储存能的变化，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对退火过程中变形金属储存能变化的基本概念的理解和记忆，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目仅要求考生记忆并复述变形金属退火过程中储存能量的基本变化规律（\"逐渐释放\"），属于最基础的定义性知识回忆，无需解释或分析过程，符合等级1的简答要求。" + }, + { + "idx": 905, + "question": "Briefly describe the changes in physical properties of deformed metal during annealing", + "answer": "Electrical resistance decreases, density increases. The changes in various properties during recrystallization are much more pronounced than during recovery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形金属在退火过程中物理性质的变化，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述变形金属在退火过程中物理性质的变化，涉及多个物理性质（电阻、密度）的变化及其与再结晶和回复过程的关联。这需要理解退火过程中的微观结构变化及其对宏观性能的影响，属于概念关联和综合分析层次。 | 难度: 在选择题中属于中等难度，需要理解金属退火过程中物理性质的变化，并能够区分再结晶和回复阶段的不同影响。题目要求综合分析多个物理性质（电阻率和密度）的变化趋势，并比较不同退火阶段的显著程度。虽然不涉及多步计算，但需要对相关概念有较深的理解和关联能力。" + }, + { + "idx": 906, + "question": "Briefly describe the factors affecting the crystalline structure of ingots.", + "answer": "Factors affecting the crystalline structure of ingots: 1 Liquid superheat, the smaller the better; 2 Solidification temperature range, the larger the better, which is beneficial for dendrite fragmentation; 3 Temperature gradient, the smaller the more conducive to equiaxed crystals; 4 Alloy with low melting point, small temperature gradient; 5 Stirring or adding inoculants.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述影响铸锭晶体结构的因素，答案以文字解释和列举要点的方式呈现，符合简答题的特征。 | 知识层次: 题目要求简要描述影响铸锭晶体结构的因素，涉及多个因素的关联和综合分析，需要理解各因素对晶体结构的影响机制，并进行适当的解释和论述。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解多个概念（如液态过热、凝固温度范围、温度梯度等），还需要综合分析这些因素如何共同影响铸锭的晶体结构。此外，题目涉及的知识点较为深入，需要考生具备一定的材料科学基础，能够进行多角度分析论述。" + }, + { + "idx": 907, + "question": "Briefly describe the changes in the microstructure of deformed metal during the annealing process", + "answer": "As the annealing temperature increases or the time prolongs, subgrain coalescence and growth occur, followed by recrystallization nucleation and growth. The deformed grains with high dislocation density and elongated shape are replaced by equiaxed recrystallized grains free of dislocations, and then normal grain growth takes place.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述变形金属在退火过程中微观结构的变化，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求解释变形金属在退火过程中微观结构的变化，涉及多个阶段的转变（亚晶合并与长大、再结晶形核与长大、晶粒正常长大），需要综合运用材料科学中的变形、回复、再结晶和晶粒长大等知识，并进行机理分析和关联。这超出了简单记忆或基本应用，属于需要深入理解和综合分析的内容。 | 难度: 在选择题型中，该题目要求考生全面理解并分析金属在退火过程中微观结构的复杂变化，包括亚晶粒的合并与生长、再结晶形核与生长、变形晶粒的替代以及正常晶粒生长等多个阶段。这需要考生具备深厚的材料科学知识，能够综合运用多个概念并进行机理层面的解释，属于选择题型中的最高难度等级。" + }, + { + "idx": 908, + "question": "Briefly describe the similarities between solid-state phase transformation and liquid-state phase transformation", + "answer": "Both are phase transformations, consisting of nucleation and growth. The critical radius and critical nucleation work have the same forms. The transformation kinetics are also the same.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述两种相变的相似之处，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较固态相变和液态相变的相似性，涉及多个概念（成核、生长、临界半径、临界成核功、转变动力学）的关联和综合分析，需要理解并应用这些概念进行对比分析，思维过程有一定深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握固态相变和液态相变的相似之处，涉及成核和生长、临界半径和临界成核功的形式以及相变动力学等概念。虽然题目没有要求多步计算，但需要对不同相变过程的概念进行关联和综合分析，因此难度属于等级3。" + }, + { + "idx": 909, + "question": "Briefly describe the differences between solid-state phase transformation and liquid-state phase transformation", + "answer": "The nucleation resistance includes an additional strain energy term, leading to an increase in the critical radius and nucleation work for solid-state phase transformation; the new phase can appear in a metastable manner, with coherent, semi-coherent interfaces, specific orientation relationships, and heterogeneous nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固态相变和液态相变之间的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固态相变和液态相变的差异，涉及成核阻力、临界半径、成核功、界面类型、取向关系等复杂概念的综合分析和对比，需要深入理解相变机理并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解固态相变和液态相变的基本概念，还需要深入掌握成核阻力、临界半径、成核功等复杂机理。正确选项涉及多个专业术语（如相干/半相干界面、取向关系等）和综合知识点的运用（应变能项对成核过程的影响）。这需要考生具备将多个高级概念整合分析的能力，并能够解释相变过程中的复杂现象。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最难的一类。" + }, + { + "idx": 910, + "question": "Briefly describe the factors affecting diffusion.", + "answer": "1. Temperature. It follows the relationship D=D0e^(-Q/RT), where an increase in T leads to an increase in D; 2. Interfaces, surfaces, and dislocations. These serve as fast diffusion paths; 3. Third elements. They can have varying effects on binary diffusion, such as Mo and W reducing the diffusion coefficient of C in γ-Fe, Co and Si accelerating the diffusion of C, and Mn having little effect; 4. Crystal structure. In low-symmetry crystal structures, diffusion anisotropy exists, such as in hexagonal crystals where the diffusion coefficients parallel and perpendicular to the basal plane (0001) differ; 5. Melting point. Within the same alloy system, diffusion is slower in alloys with higher melting points and faster in those with lower melting points at the same temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述影响扩散的因素，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述影响扩散的多个因素，涉及温度、界面、第三元素、晶体结构和熔点等多个方面，需要理解和应用扩散的基本原理（如阿伦尼乌斯方程），并能够关联不同因素对扩散的影响。虽然不需要复杂的计算或深度推理，但需要对多个概念进行综合分析和解释。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解扩散的基本概念，还需要掌握多个影响扩散的因素及其具体作用机制。题目涉及温度、界面、第三元素、晶体结构和熔点等多个方面，每个方面都需要深入理解和综合分析。此外，题目还要求考生能够将这些因素与具体的物理和化学现象联系起来，如扩散系数的变化、不同元素对扩散的影响等。这种多角度的分析和论述在选择题型中属于较高难度的要求。" + }, + { + "idx": 911, + "question": "What is the difference in the driving force for nucleation during recrystallization and solidification?", + "answer": "The driving force for nucleation during solidification is the chemical potential difference between the new and old phases, while the driving force for recrystallization is only the stored energy of deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种不同过程中成核驱动力的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种不同相变过程（再结晶和凝固）的成核驱动力，涉及对材料科学中相变和变形储存能等概念的理解和应用。虽然不需要复杂的计算，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求区分两种不同相变过程（再结晶和凝固）的成核驱动力来源，涉及对化学势差和变形储存能等概念的理解和对比。虽然不需要多步计算，但需要综合分析不同相变机制的特点，属于中等应用层次的知识要求。" + }, + { + "idx": 912, + "question": "What is the difference in orientation relationship between growth during recrystallization and growth during solidification?", + "answer": "During solidification growth, there is no orientation relationship with the parent phase, whereas during recrystallization growth, a specific orientation relationship may exist.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种生长过程中的取向关系差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较两种不同生长过程中的取向关系，涉及对再结晶和凝固过程的理解，需要将多个概念关联起来进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及再结晶和凝固过程中的取向关系差异，要求考生掌握两种不同相变过程的基本原理，并能区分它们之间的关键区别。虽然不需要复杂的计算，但需要对材料科学中的相变和晶体生长有较深入的理解。" + }, + { + "idx": 913, + "question": "What is the difference in nucleation sites between recrystallization and solidification processes?", + "answer": "Solidification is often homogeneous nucleation; recrystallization nucleation occurs in existing deformation inhomogeneous regions, such as near grain boundaries, shear bands, deformation bands, and around second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述再结晶和凝固过程中成核位点的差异，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求比较两种不同过程（再结晶和凝固）的形核位点差异，涉及对形核机制的理解和概念关联，需要综合分析不同条件下的形核行为，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解再结晶和凝固两种过程的成核机制，还需要能够比较和分析它们之间的差异。正确选项涉及多个专业概念（如均匀成核、非均匀成核、晶界、剪切带等）的综合运用，并需要将这些概念与具体的材料加工过程联系起来。这种多角度分析和概念关联的要求使得该题目在选择题型中具有较高的难度。" + }, + { + "idx": 914, + "question": "5. Secondary recrystallization", + "answer": "A phenomenon where the normal growth process is inhibited after recrystallization, leading to abnormal growth of a few grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Secondary recrystallization\"这一现象进行文字解释和论述，答案是一个描述性的定义，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶这一基本现象的定义和描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生准确理解\"二次再结晶\"的定义特征（正常晶粒生长被抑制、少数晶粒异常长大），这比单纯记忆术语名称（等级1）要求更高。题目正确选项完整描述了现象的本质特征，属于概念解释和描述层面的考查，符合等级2的难度标准。" + }, + { + "idx": 915, + "question": "Briefly describe the inverse segregation in the macrosegregation of ingots", + "answer": "Inverse segregation: It still follows the distribution coefficient relationship, but after the formation of a large number of dendrites, the solute-enriched liquid phase will flow backward along the interdendritic channels to the vicinity of the initially solidified ingot surface, resulting in an abnormal composition distribution from the surface to the center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述逆偏析现象，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对逆偏析这一基本概念的记忆和理解，涉及定义和基本原理的解释，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求简要描述逆偏析现象，虽然涉及多个概念（如分配系数、枝晶形成、溶质富集液相流动等），但整体上仍属于对单一概念的描述性解释，不需要进行复杂的概念体系阐述或比较分析。因此属于中等难度。" + }, + { + "idx": 916, + "question": "Briefly describe the gravity segregation in the macrosegregation of ingots", + "answer": "Gravity segregation: During solidification, the solid phase and the liquid phase have different densities, causing deposition or floating, which results in uneven composition between the lower and upper ends of the ingot, also on a macroscopic scale.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述重力偏析在铸锭宏观偏析中的表现，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对重力偏析这一基本概念的记忆和理解，涉及定义和基本原理的解释，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但需要考生对重力偏析的定义、形成原因及其在宏观偏析中的表现有一定的理解和描述能力。题目不仅要求记忆，还需要能够简要解释现象背后的原理，因此难度略高于纯粹的定义记忆题。" + }, + { + "idx": 917, + "question": "Briefly describe normal segregation in the macro-segregation of ingots", + "answer": "Normal segregation: refers to the phenomenon where the initially solidified portion has lower solute content and the later solidified portion has higher solute content, according to the alloy's distribution coefficient (assuming k0<1). Due to the large size of the ingot, the composition varies from the surface to the center, resulting in non-uniformity, and the segregation occurs on a macroscopic scale, known as macro-segregation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述正常偏析现象，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对宏观偏析中正常偏析现象的基本定义和原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但需要考生理解并描述\"正常偏析\"的定义、形成原因及其在宏观尺度上的表现。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。考生需要掌握合金分配系数与凝固顺序的关系，并能解释宏观偏析的形成机制，这属于概念解释和描述的难度层次。" + }, + { + "idx": 918, + "question": "4.Deformation texture", + "answer": "The phenomenon of crystallographic orientation preference occurring during polycrystalline deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Deformation texture\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"Deformation texture\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对\"变形织构\"这一基础概念的定义记忆，属于最基础的定义简答级别。正确选项直接给出了该术语的准确定义，不需要任何解释、分析或推理过程，完全符合选择题型中最简单的难度标准。" + }, + { + "idx": 919, + "question": "3. Congruent solidification and incongruent solidification", + "answer": "Solidification without compositional change is called congruent solidification; conversely, solidification accompanied by compositional change is called incongruent solidification.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对两个专业术语进行解释和区分，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查的是对\"congruent solidification\"和\"incongruent solidification\"这两个基本概念的定义记忆和理解，属于材料科学中相变基础知识的范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念的定义记忆，无需复杂分析或比较。正确选项直接给出了\"congruent solidification\"和\"incongruent solidification\"的明确定义，属于最基础的定义简答类型。学生只需识别并匹配这两个术语与其定义即可，不需要进行任何推理或应用。" + }, + { + "idx": 920, + "question": "2.Grain boundaries and interfacial energy", + "answer": "A grain boundary is the interface between grains of the same composition and structure. Atoms at the interface are in a broken-bond state and possess excess energy. The average excess energy per unit area of the interface is called interfacial energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对晶界和界面能进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对晶界和界面能的基本定义和原理的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆晶界和界面能的基本定义及其相关原理，但不需要进行复杂的分析或比较。虽然涉及一些专业术语（如broken-bond state和excess energy），但整体上属于基础概念的记忆和简单解释范畴。" + }, + { + "idx": 921, + "question": "Analyze the crystallization process of an iron-carbon alloy with a carbon content of 0.12%", + "answer": "For steel with 0.12% carbon, when cooled from the liquid phase, δ-ferrite forms first. The compositions of the solid and liquid phases change according to the solidus and liquidus lines on the phase diagram. At the peritectic temperature of 1495°C, partial peritectic reaction occurs; the new phase γ-austenite nucleates on the pre-existing δ-ferrite and grows into both the δ-ferrite and liquid phase. After the reaction, the microstructure consists of two phases: δ-ferrite + γ-austenite. The relative amount of δ-ferrite is: (0.17-0.12)/(0.17-0.09)=62.5%. Upon further cooling, single-phase austenite is obtained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析铁碳合金的结晶过程，答案提供了详细的文字解释和论述，包括相变过程、温度变化和相组成计算，符合简答题的特征。 | 知识层次: 题目要求分析铁碳合金的结晶过程，涉及相图的理解、相变反应的描述、相对量的计算以及微观结构的演变。这需要综合运用相图知识、相变机理和定量计算，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对铁碳合金的结晶过程进行复杂现象全面分析，涉及多个相变过程（δ-铁素体形成、包晶反应、γ-奥氏体形成）、相图解读（固相线和液相线变化）、以及定量计算（相对含量62.5%）。解题需要综合运用相图知识、热力学原理和显微组织演变机理，并能够解释各阶段的相变行为和最终组织组成。这种深度和广度的知识整合在选择题型中属于最具挑战性的类型。" + }, + { + "idx": 922, + "question": "What are the characteristics of the space lattice in the tetragonal crystal system?", + "answer": "The lattice parameters of the tetragonal crystal system are a≠b≠c, α=β=γ=90°.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释四方晶系的空间点阵特征，答案提供了文字描述而非选择、判断或计算。 | 知识层次: 题目考查对四方晶系空间点阵特征的基本概念记忆，仅需回答晶格参数的关系（a≠b≠c, α=β=γ=90°），不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅考察对四方晶系空间点阵基本参数的定义记忆（a≠b≠c, α=β=γ=90°），属于最基础的概念性知识，无需解释或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 923, + "question": "Briefly describe the types of defects in metal crystals", + "answer": "According to size, they can be divided into: point defects, such as solute, impurity atoms, vacancies; line defects, such as dislocations; planar defects, such as various grain boundaries, phase boundaries, surfaces, etc.; volume defects, such as pores, bubbles, etc. Volume defects are absolutely harmful to material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述金属晶体中的缺陷类型，答案提供了详细的文字解释和分类论述，符合简答题的特征。 | 知识层次: 题目考查金属晶体缺陷的基本分类和定义，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生对金属晶体缺陷的分类进行描述，涉及点缺陷、线缺陷、面缺陷和体缺陷的基本概念。虽然需要记忆多个分类和例子，但题目仅要求简要描述，不涉及复杂的概念体系或深入分析，属于概念解释和描述的难度水平。" + }, + { + "idx": 924, + "question": "1. Edge dislocation and screw dislocation models", + "answer": "Cut the upper half of the crystal, insert half a crystal plane, and then bond it together; in this way, within a certain range near the centerline corresponding to the edge end, the atoms undergo regular misalignment. Its characteristic is that the upper half is under compression, and the lower half is under tension. This is the same as the scenario caused by edge dislocations in real crystals, known as the edge dislocation model. Similarly, cut the front half of the crystal, use the edge end as the boundary to make the left and right parts undergo a relative shear of one atomic spacing up and down, and then bond them together. At this time, near the boundary line between the sheared and unsheared regions, the atomic misalignment is similar to that of a real screw dislocation, known as the screw dislocation model.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对刃型位错和螺型位错模型进行详细的文字解释和论述，答案形式为描述性文字而非选择、判断或计算。 | 知识层次: 题目主要考查对边缘位错和螺位错模型的基本概念和特征的理解与记忆，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于高难度。题目要求考生不仅要记忆边缘位错和螺旋位错的定义，还需要理解它们的形成过程和特征。具体来说，考生需要掌握切割晶体、插入半晶面、原子错位等复杂概念，并能区分压缩和拉伸的不同效果。此外，题目还涉及相对剪切和原子间距的变化，这些都是较为复杂的知识点。因此，该题目在选择题型内属于高难度等级。" + }, + { + "idx": 925, + "question": "Briefly describe the characteristics of the eutectic reaction in a binary system and calculate the degrees of freedom when its phases are in equilibrium.", + "answer": "The eutectic reaction is: the liquid phase simultaneously solidifies into two solid phases of different compositions, which grow cooperatively and generally form a lamellar structure. When the eutectic reaction occurs, the degrees of freedom are 0, meaning the compositions of the three phases are fixed, and the temperature is also fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述共晶反应的特征并计算自由度，答案包含文字解释和论述，没有涉及选项选择、判断对错或复杂计算。 | 知识层次: 题目不仅要求描述共晶反应的基本特征（基础概念记忆），还需要计算自由度（简单应用），并将两者结合起来进行综合分析。这涉及到多步思维过程和对相平衡概念的理解，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握共晶反应的基本特征，并能计算自由度，涉及多步计算和概念关联。虽然题目提供了正确选项，但考生仍需具备综合分析能力才能准确理解并选择正确答案。" + }, + { + "idx": 926, + "question": "Briefly describe the characteristics of the peritectic reaction in a binary system and calculate the degrees of freedom at equilibrium for each phase.", + "answer": "The peritectic reaction is: a liquid phase reacts with a solid phase to form another solid phase, where the newly formed solid phase envelops the original solid phase. The reaction requires diffusion within the solid phase and proceeds relatively slowly. When a peritectic reaction occurs, the degrees of freedom are 0, meaning the compositions of the three phases are fixed, and the temperature is also fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述包晶反应的特点并计算平衡时的自由度，需要文字解释和论述，没有涉及选择题、判断题或纯计算题的特征。 | 知识层次: 题目不仅要求描述包晶反应的基本特征（基础概念），还需要计算平衡时各相的自由度（简单应用），并解释其物理意义（概念关联）。这涉及多步思维过程和概念的综合运用，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解包晶反应的基本概念，还需要掌握自由度计算的方法，并将两者结合起来进行综合分析。题目涉及多步计算和概念关联，属于中等应用层次的知识点。此外，题目要求考生在选择题型中展示对复杂概念的理解和应用能力，这比单纯记忆或简单分析更具挑战性。因此，该题目在选择题型内属于较高难度等级。" + }, + { + "idx": 927, + "question": "Briefly describe the characteristics of the eutectoid reaction in a binary system and calculate the degrees of freedom when its phases are in equilibrium.", + "answer": "The eutectoid is similar to the eutectic, except that the parent phase is a solid phase, i.e., one solid phase simultaneously transforms into two other solid phases of different compositions. When the eutectoid reaction occurs, the degrees of freedom are 0, meaning the compositions of the three phases are fixed, and the temperature is also fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述共析反应的特征并计算自由度，答案以文字解释为主，包含论述和计算部分，符合简答题的特征。 | 知识层次: 题目不仅要求描述共析反应的基本特征（基础概念记忆），还需要计算自由度（简单应用），并将两者结合起来进行综合分析（中等应用）。这涉及到多步思维过程和对相平衡概念的理解。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握共析反应的基本特征，并能计算自由度，涉及多个知识点的综合应用。虽然题目提供了正确选项，但需要考生对共析反应和自由度计算有较深的理解才能准确选择。" + }, + { + "idx": 928, + "question": "What are the characteristics of the space lattice in the cubic crystal system?", + "answer": "The lattice parameters of the cubic crystal system are a=b=c, α=β=γ=90°.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释立方晶系的空间点阵特征，答案提供了文字描述而非选择、判断或计算。 | 知识层次: 题目考查立方晶系空间点阵的基本特征记忆，属于晶体学中最基础的概念性知识，仅需记忆晶格参数关系即可回答，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆立方晶系的基本定义（a=b=c，α=β=γ=90°），属于最基础的概念性知识，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 929, + "question": "Briefly describe the meaning of Fick's first law, write its expression, and indicate the physical meanings of the letters.", + "answer": "Fick's first law J=-D(dc/dx) J: diffusion flux, which is the amount of substance passing through a unit area per unit time, g/m²·s; D: diffusion coefficient, m²/s; dc/dx: concentration gradient, g/m⁴.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述Fick第一定律的含义，写出其表达式，并指出字母的物理意义。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查Fick第一定律的基本定义、表达式及各符号的物理意义，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅要求简要描述Fick's第一定律的含义、写出其表达式并指出字母的物理意义。这属于基础概念记忆的范畴，只需直接回忆和复述定义和基本原理，无需深入分析或复杂推理。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 930, + "question": "Briefly explain the meaning of Fick's second law, write its expression, and indicate the physical meanings of the letters.", + "answer": "Fick's second law ∂c/∂t=∂/∂x(D∂c/∂x) ∂c/∂t: rate of concentration change over time, g/m³·s; ∂J/∂x: gradient of flux, g/m³·s.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释Fick's第二定律的含义，写出其表达式，并说明字母的物理意义。答案以文字解释和论述为主，没有涉及选择、判断或计算。 | 知识层次: 题目考查Fick第二定律的基本定义、表达式及其物理含义的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求解释Fick's第二定律的含义、写出其表达式并说明字母的物理意义。这属于概念解释和描述的层次，需要学生对基础概念有一定的理解和记忆，但不需要复杂的分析或推导。相比于等级1的基本定义简答，该题目对知识点的掌握深度要求稍高，但仍属于中等难度范围。" + }, + { + "idx": 931, + "question": "What is the method of nucleation during the recrystallization process?", + "answer": "Recrystallization nucleation often occurs in existing regions of deformation inhomogeneity, such as near grain boundaries, shear bands, deformation bands, and around second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释再结晶过程中成核的方法，答案提供了详细的文字解释和论述，没有选项或计算要求。 | 知识层次: 题目涉及再结晶过程中成核的具体位置和机制，需要理解变形不均匀区域的概念，并将成核现象与材料微观结构特征（如晶界、剪切带、第二相粒子等）关联起来。这需要一定的综合分析能力和对材料变形与再结晶过程的理解，超出了单纯的基础概念记忆。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及再结晶过程中的成核方法，正确选项提到了变形不均匀区域的多个具体位置（晶界、剪切带、变形带、第二相粒子周围），这要求考生不仅知道再结晶成核的基本概念，还需要掌握成核发生的具体位置及其与变形不均匀性的关联。这种题目需要考生综合应用材料科学中的变形和再结晶知识，属于中等应用层次。" + }, + { + "idx": 932, + "question": "What is a lattice parameter?", + "answer": "Lattice parameters are the fundamental parameters that describe the geometric shape of a unit cell, consisting of six parameters: the three edge lengths a, b, c and the three angles α, β, γ between them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"lattice parameter\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即晶格参数的定义和组成，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶格参数的基本定义，属于基础概念记忆层次。题目直接给出了晶格参数的定义和组成要素，不需要进行复杂的分析或推理，因此属于最简单的难度等级。" + }, + { + "idx": 933, + "question": "6.Hardenability and hardening capacity", + "answer": "Hardenability refers to the ability of an alloy to be quenched into martensite, mainly related to the critical cooling rate, with its magnitude represented by the depth of the hardened layer. Hardening capacity refers to the maximum hardness that can be achieved after quenching, primarily related to the carbon content of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对两个专业术语进行文字解释和论述，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查对\"Hardenability\"和\"Hardening capacity\"这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个相关但不同的概念（Hardenability和Hardening capacity），但正确选项已经清晰地给出了两者的定义和主要区别。学生需要理解并区分这两个概念，但不需要进行复杂的分析或推导。这属于概念解释和描述的层次，比基本定义简答稍难，但比复杂概念体系阐述简单。" + }, + { + "idx": 934, + "question": "Briefly describe the role and influence of grain boundaries on the plastic deformation of polycrystals", + "answer": "The slip planes on both sides of the grain boundary are not parallel. On one hand, grain boundaries act as obstacles to dislocation motion, causing pile-ups and strengthening; meanwhile, they necessitate the occurrence of multiple slip systems near the grain boundaries to accommodate the deformation on both sides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶界对多晶体塑性变形的作用和影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶界在多晶塑性变形中的作用和影响，涉及位错运动、滑移系统协调等机理分析，需要综合运用材料科学中的多个概念并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 935, + "question": "Briefly describe the characteristics of phase transformation resistance in solid-state phase transformations", + "answer": "The phase transformation resistance includes an additional term for strain energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述固态相变中的相变阻力特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对相变阻力的基本概念的理解，需要记忆和解释相变阻力的特性，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述相变阻力的特征，但正确选项仅涉及应变能的额外项这一具体知识点。这需要考生不仅记住基础定义，还要理解相变阻力的组成部分，属于概念解释和描述的层次。但不需要进行复杂的概念体系阐述或比较分析，因此难度等级为2。" + }, + { + "idx": 936, + "question": "What is the main difference between nucleation and growth during solidification and nucleation and growth during recrystallization?", + "answer": "The driving force for nucleation and growth during solidification is the chemical potential difference between the new and old phases, while the driving force for nucleation and growth during recrystallization is solely the stored deformation energy. Nucleation during solidification is often homogeneous; nucleation during recrystallization typically occurs in existing regions of deformation inhomogeneity, such as near grain boundaries, shear bands, deformation bands, or around second-phase particles. During solidification growth, there is no orientation relationship with the parent phase, whereas during recrystallization growth, there may be a certain orientation relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两种过程中成核和生长的主要区别，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种不同过程中成核和生长的差异，涉及多个概念的综合运用和机理的解释，需要深入理解固化和再结晶的驱动机制、成核位置以及生长过程中的取向关系等复杂因素。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解固化和再结晶过程中的成核与生长机制，还需要深入比较两者的驱动力差异、成核位置差异以及生长过程中的取向关系差异。这需要综合运用材料科学中的相变理论、变形储能概念以及微观结构演化知识，进行复杂的推理分析和机理解释。选择题型中此类综合比较题目对知识深度和逻辑分析能力要求极高，因此属于最高难度等级。" + }, + { + "idx": 937, + "question": "What is primary banded structure?", + "answer": "Primary banded structure is formed by dendrites during solidification and becomes banded after hot rolling; under CuCl2 etching, the dark bands are dendrite trunks (with less solute), while the light bands are often interdendritic regions enriched with impurities, also known as original bands.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"primary banded structure\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对primary banded structure的定义和形成过程的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项不仅需要考生记住\"primary banded structure\"的定义，还需要理解其形成过程（凝固过程中枝晶形成，经热轧后呈带状）和微观特征（在CuCl2腐蚀下不同区域的显色差异）。这超出了简单的定义记忆，需要对概念进行一定程度的解释和描述。但题目不涉及多个概念的比较或复杂体系的分析，因此不属于最高难度等级。" + }, + { + "idx": 938, + "question": "What is secondary banded structure?", + "answer": "Secondary banding is a product of solid-state transformation. Under nitric acid alcohol etching, the white bands are proeutectoid ferrite, and the black bands are pearlite, also known as micro banded structure. Secondary banding only occurs on the basis of primary banding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"secondary banded structure\"的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对二次带状结构这一基本概念的定义和特征的理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生不仅记住\"secondary banded structure\"的定义，还要理解其形成机制（固态转变产物）、在特定条件下的表现（硝酸酒精腐蚀后的白黑带）以及与primary banding的关系。这些内容超出了简单的定义记忆，需要对概念进行一定程度的解释和描述，但尚未达到需要阐述复杂概念体系的难度。" + }, + { + "idx": 939, + "question": "Analyze the causes of primary banded structure formation.", + "answer": "The formation of primary banded structure is related to dendrite formation during solidification and the hot rolling process, where the dark bands are dendrite trunks (with fewer solutes) and the white bands are interdendritic regions enriched with impurities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析带状结构形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析初级带状结构形成的原因，涉及凝固过程中的枝晶形成和热轧工艺的综合分析，需要理解枝晶主干和枝晶间区域的成分差异及其对结构形成的影响。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 940, + "question": "Analyze the causes of secondary banded structure formation.", + "answer": "The formation of secondary banded structure is the result of solid-state transformation. The white bands are proeutectoid ferrite, and the black bands are pearlite, which must form on the basis of primary bands. These bands are all related to element segregation and the special distribution of inclusions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析二次带状结构形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析二次带状结构的形成原因，涉及固态相变、先共析铁素体和珠光体的形成机制，以及元素偏析和夹杂物分布的影响。这需要综合运用材料科学中的相变理论、显微组织分析等知识，进行机理的解释和推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解二次带状结构的形成机理，包括固态相变、先共析铁素体和珠光体的形成过程，以及元素偏析和夹杂物特殊分布的综合影响。正确选项不仅需要识别现象，还需要解释多层次的复杂因果关系，涉及材料科学中较深层次的理论知识。这种题目在选择题中属于需要全面分析复杂现象的典型代表，远超出基础概念识别的难度水平。" + }, + { + "idx": 941, + "question": "Briefly describe the characteristics of nucleation in solid-state phase transformations", + "answer": "Non-uniform nucleation, with specific orientation relationships, often forming coherent or semi-coherent interfaces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述固态相变中成核的特征，答案以文字解释的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目要求描述固态相变中成核的特征，涉及非均匀成核、特定取向关系以及相干/半相干界面的形成。这需要将多个概念（成核理论、界面结构、取向关系）进行关联和综合分析，而不仅仅是基础概念的简单记忆。回答需要理解这些概念之间的关系，并能够进行中等程度的整合应用。 | 难度: 在选择题中属于中等难度，需要理解固态相变中形核的基本特征，包括非均匀形核、特定取向关系以及相干/半相干界面的形成等概念，并能将这些概念关联起来进行综合分析。虽然不涉及多步计算，但需要对多个相关概念有较好的掌握和理解。" + }, + { + "idx": 942, + "question": "Briefly describe the characteristics of growth in solid-state phase transformations", + "answer": "The occurrence of habit phenomena, i.e., there is a precipitation sequence; special/regular microstructural morphologies, such as lamellar, acicular.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述固态相变中生长的特征，答案以文字解释和论述的形式给出，符合简答题的特点。 | 知识层次: 题目考查对固态相变生长特性的基本概念记忆和理解，涉及常见的现象和微观结构形态，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生描述固态相变中生长的特征，涉及基础概念的记忆和理解。虽然需要掌握一定的专业术语和基本原理，但题目仅要求简要描述，不需要复杂的分析或比较。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 943, + "question": "Briefly describe the characteristics of metastable phases in solid-state phase transformations", + "answer": "The appearance of metastable phases serves to reduce the resistance to phase transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述亚稳态相的特征，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对亚稳相在固态相变中特性的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆层次的知识点（亚稳相的定义和特性），但正确选项要求考生不仅要记住亚稳相的定义，还需要理解其在固态相变中的作用机制（降低相变阻力）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 944, + "question": "Describe the mechanism of crystal growth during solidification", + "answer": "There are three growth mechanisms: continuous growth, two-dimensional nucleation and lateral growth via steps, and growth via screw dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体生长的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述晶体生长的机制，涉及多个生长方式的解释和机理分析，需要综合运用材料科学中的晶体生长理论，理解不同生长机制的特点和适用条件，属于对知识的深度理解和综合分析。 | 难度: 在选择题型中，该题目要求考生不仅掌握晶体生长的基本概念，还需要深入理解三种不同的生长机制（连续生长、二维成核与台阶侧向生长、螺位错生长）。这涉及到复杂现象的综合分析，需要考生具备较高的机理解释能力和知识整合能力。在选择题型内，这种要求深度理解和综合运用多个知识点的题目属于最高难度等级。" + }, + { + "idx": 945, + "question": "Briefly describe the macroscopic characteristics of the solidification process", + "answer": "The macroscopic characteristics during solidification are: a certain degree of undercooling is required, and significant latent heat of crystallization is released.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述凝固过程的宏观特征，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目考查对凝固过程宏观特征的基本概念记忆和理解，涉及基础原理（过冷度和结晶潜热）的直接描述，不需要复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生描述凝固过程的宏观特征，涉及基础概念的记忆和理解，如过冷度和结晶潜热。虽然需要一定的概念解释和描述能力，但不需要复杂的分析或比较，属于中等难度。" + }, + { + "idx": 946, + "question": "Briefly describe the role and influence of grain size on the plastic deformation of polycrystals", + "answer": "When grains are fine, the entire grain can deform more uniformly with fewer combinations of slip systems; when grains are coarse, different regions within the grain cannot coordinate with each other during deformation, requiring the activation of different combinations of slip systems, often leading to grain 'fragmentation,' where a large grain is 'fragmented' into several parts with different slip systems activated in each part. The effect on performance follows the Hall-Petch relationship σs=σ0+Kd−1/2, meaning the finer the grains, the more grain boundaries there are, and the more significant the hindrance of grain boundaries to moving dislocations, resulting in a greater increase in strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶粒尺寸对多晶体塑性变形的作用和影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶粒尺寸对多晶体塑性变形的影响，涉及晶粒变形机制、滑移系统的激活以及Hall-Petch关系的应用。这需要综合运用材料科学中的塑性变形理论、晶界作用和强化机制等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解晶粒尺寸对塑性变形的影响机制，还需要掌握Hall-Petch关系的数学表达式及其物理意义。正确选项涉及多个复杂概念的整合：晶粒尺寸与变形均匀性的关系、滑移系统的协同作用、晶粒\"破碎\"现象以及强度提升的位错阻碍机制。这需要考生具备将微观变形机理与宏观性能表现相联系的综合分析能力，完全符合\"复杂现象全面分析\"的知识层次要求。在选择题型中，此类需要深度机理解释和多因素推理的题目属于最难级别。" + }, + { + "idx": 947, + "question": "What is a solid solution?", + "answer": "A single homogeneous solid formed by solute atoms dissolving into the solvent lattice in atomic form; the lattice type of the solvent is retained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"solid solution\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对固溶体这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅要求识别和记忆固体溶液的基本定义，属于基础概念记忆层次。正确选项直接给出了定义，无需复杂的理解或分析步骤，因此属于最简单的难度等级。" + }, + { + "idx": 948, + "question": "List one method to increase the number of nuclei during the solidification process, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Increase the cooling rate to enhance the degree of undercooling. The phase transformation driving force is increased, thereby improving the nucleation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出一种方法并简要分析原因，需要文字解释和论述，符合简答题的特征 | 知识层次: 题目要求列举一种增加凝固过程中晶核数量的方法，并简要分析其原因。这需要理解凝固过程中的成核机制，并将冷却速率与过冷度、相变驱动力和成核速率之间的关系联系起来。虽然不涉及复杂的计算或多步骤分析，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道增加冷却速率可以提高形核率，还需要理解其背后的原理（过冷度增加导致相变驱动力增大）。这涉及对凝固过程中形核机制的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 949, + "question": "What changes occur in the structure, mechanical properties, and physical properties of a solid solution compared to its pure solvent component?", + "answer": "Structural changes in solid solutions: lattice distortion, changes in lattice constants, segregation and short-range ordering, and even the formation of ordered solid solutions. Changes in mechanical properties: increased hardness and strength, decreased plasticity. Changes in physical properties: increased electrical resistance, decreased conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液与纯溶剂相比在结构、机械性能和物理性能方面的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对固溶体与纯溶剂在结构、力学性能和物理性能方面的变化进行比较和分析，涉及多个知识点的关联和综合分析，需要理解固溶体的基本原理并能够应用这些知识解释具体现象。虽然不涉及复杂的计算或深度推理，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于较高难度，题目要求考生综合理解并比较固体溶液与纯溶剂在结构、机械性能和物理性能方面的多重变化。需要掌握多个相关概念（如晶格畸变、硬度变化、电导率变化等），并能进行多角度分析。虽然题目提供了正确选项，但选项内容涉及多个知识点的关联和综合分析，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 950, + "question": "List another method to increase the number of nuclei during solidification, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Add inoculants. They provide a large number of heterogeneous nucleation sites, increase the nucleation rate, and reduce the nucleation barrier.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出另一种增加凝固过程中晶核数量的方法，并简要分析晶核数量增加的原因。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求列举另一种增加凝固过程中晶核数量的方法，并简要分析原因。这需要理解凝固过程中的成核机制，并能够将异质成核的概念与实际应用（如添加孕育剂）联系起来。虽然涉及基础概念，但需要一定的综合分析能力来理解和解释成核率增加的原因。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道增加晶核数量的方法（添加孕育剂），还需要理解其背后的原理（提供异质形核位点、提高形核率、降低形核能垒）。这涉及对凝固过程中形核机制的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 951, + "question": "List the third method to increase the number of nuclei during solidification, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Mechanical or electromagnetic stirring. Breaking dendrites to increase the number of nuclei or enhancing thermal activation energy drop, which improves the nucleation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出第三种增加凝固过程中晶核数量的方法，并简要分析晶核数量增加的原因。这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目不仅要求列出增加晶核数量的第三种方法（基础记忆），还需要简要分析晶核数量增加的原因（概念关联和综合分析）。这涉及到对凝固过程中机械或电磁搅拌作用的理解，以及其对枝晶断裂和热激活能下降的影响，需要中等程度的认知能力和知识点的关联分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行综合分析。题目要求考生不仅知道增加晶核数量的第三种方法（机械或电磁搅拌），还需要简要分析其原理（通过破碎枝晶增加晶核数量或通过增强热激活能下降提高形核率）。这涉及到对凝固过程中形核机制的理解和具体应用方法的掌握，属于中等应用层次的知识要求。" + }, + { + "idx": 952, + "question": "Briefly describe the crystallization process of steel with a carbon content of 0.25%", + "answer": "The liquid phase first solidifies into ferrite, and a peritectic reaction occurs at 1495°C to form γ-austenite; upon further cooling, the remaining liquid phase precipitates γ-austenite again, which then transforms into single-phase austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述钢的结晶过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述钢的结晶过程，涉及相变反应和温度变化，需要理解并关联多个概念（如铁素体、奥氏体、包晶反应等），并进行综合分析。虽然不涉及复杂计算，但需要对相图和相关转变有较深的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解钢的结晶过程、相变反应（如包晶反应）以及不同温度下的相组成变化。虽然题目提供了具体的碳含量和温度信息，但解题者仍需综合运用相图知识和相变原理来分析结晶过程，涉及多步概念关联和综合分析。" + }, + { + "idx": 953, + "question": "Briefly describe the meaning of continuous precipitation", + "answer": "Continuous precipitation: as the new phase forms, the composition of the parent phase continuously changes from a supersaturated state to a saturated state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述连续沉淀的含义，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对连续沉淀这一基本概念的定义和特征的理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但正确选项需要对连续沉淀的定义进行较为详细的解释，包括新相形成和母相成分变化的过程。这比简单的定义记忆（等级1）要求更高的理解深度，但尚未达到复杂概念体系阐述（等级3）的程度。" + }, + { + "idx": 954, + "question": "What are the factors affecting solid solubility?", + "answer": "The factors affecting solid solubility include: 1. Atomic size factor. When the relative difference in atomic diameters between the solvent and solute is less than ±15%, there is a large substitutional solubility. 2. Electronegativity factor. The smaller the electronegativity difference between the solvent and solute, the greater the solubility; generally, a difference less than 0.4∼0.5 results in higher solubility. 3. Electron concentration factor. This has two aspects: one is the atomic valence effect, meaning for the same solvent metal, the higher the valence of the solute, the lower the solubility; the other is the relative valence effect, meaning the solubility of a high-valence solute in a low-valence solvent is higher than the opposite scenario.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响固溶度的因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对影响固溶度的因素的基本概念的记忆和理解，包括原子尺寸因素、电负性因素和电子浓度因素等基本原理，不需要复杂的应用或分析。 | 难度: 在选择题中属于高难度，题目要求考生掌握并理解多个影响固溶度的因素（原子尺寸因素、电负性因素、电子浓度因素），每个因素又包含具体的判断标准和原理。考生需要整合这些复杂概念体系，并能在选项中准确识别或匹配这些知识点。这超出了简单定义记忆的范畴，属于对复杂概念体系的阐述和应用。" + }, + { + "idx": 955, + "question": "Briefly describe the meaning of discontinuous precipitation", + "answer": "Discontinuous precipitation: also known as cellular precipitation, where an interface exists between the parent phase and the newly formed α phase. Across this interface, the parent phase discontinuously changes from supersaturated to saturated state, and the lattice parameter also changes discontinuously.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述不连续沉淀的含义，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对discontinuous precipitation这一基本概念的定义和特征的理解，属于基础概念记忆范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但要求考生不仅知道\"discontinuous precipitation\"这个术语，还需要理解其作为\"cellular precipitation\"的别称，以及能够描述相界面的特征和变化过程。这超出了简单的定义复述（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。题目要求考生对相变过程有一定理解，但选项本身提供了完整的解释框架。" + }, + { + "idx": 956, + "question": "Briefly describe the solid-state phase transformation process of steel with a carbon content of 0.25%", + "answer": "When cooled to about 800°C, proeutectoid α-ferrite precipitates from γ-austenite; at 727°C, the eutectoid reaction occurs, forming pearlite, and finally a ferrite plus pearlite structure is obtained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述钢的固态相变过程，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述钢的固态相变过程，涉及多个相变阶段（γ-austenite到α-ferrite的析出、共析反应形成珠光体等），需要将多个概念关联起来进行综合分析，并理解相变温度与组织变化的关系。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在选择题中属于中等难度，需要理解钢的固态相变过程，包括先共析铁素体的析出、共析反应以及最终组织的形成。虽然题目提供了具体碳含量和温度信息，但需要考生综合运用相图知识和相变原理进行分析和判断，涉及多个步骤和概念的关联。" + }, + { + "idx": 957, + "question": "Briefly describe metallic bond", + "answer": "The bonding force generated by the electrostatic interaction between free electrons and atomic nuclei.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述金属键，答案是一段文字解释，属于需要文字论述的简答题类型 | 知识层次: 题目考查金属键的基本定义和原理，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅要求对金属键的基本定义进行简答，属于基础概念的记忆性知识。题目直接给出了正确选项，无需复杂的分析或推理过程，符合等级1的基本定义简答标准。" + }, + { + "idx": 958, + "question": "Briefly describe the critical resolved shear stress for slip", + "answer": "The minimum resolved shear stress required to initiate slip system movement; it is a constant value, related to the intrinsic properties of the material and independent of the orientation of external forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述临界分切应力的概念，答案是一段文字解释，符合简答题的特征 | 知识层次: 题目考查对临界分切应力这一基本概念的记忆和理解，不涉及复杂计算或综合分析 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并描述临界分切应力的定义及其特性，涉及对材料科学基础概念的掌握。虽然需要一定的记忆和理解，但不需要复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 959, + "question": "Briefly describe intermediate phases", + "answer": "Phases formed between components in an alloy, which have structures different from those of the pure components. Located in the intermediate region of the phase diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述中间相，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对中间相（intermediate phases）这一基本概念的定义和特征的理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目仅要求对\"intermediate phases\"的基本定义进行简答，属于最基础的概念记忆层次。正确选项直接给出了定义和位置描述，无需复杂分析或推理，符合等级1的基本定义简答标准。" + }, + { + "idx": 960, + "question": "Briefly describe martensitic transformation", + "answer": "The process follows a diffusionless, shear-type phase transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述马氏体相变过程，需要用文字解释和论述，答案也是以文字形式给出解释说明 | 知识层次: 题目考查对马氏体相变这一基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别马氏体相变的基本定义特征（扩散型、剪切型相变），属于最基础的概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需从选项中识别出标准定义即可，符合等级1\"基本定义简答\"的难度标准。" + }, + { + "idx": 961, + "question": "Briefly describe the Bravais lattice", + "answer": "A lattice that considers not only the shape of the unit cell but also the positions of the lattice points (or: considers not only rotational symmetry but also translational symmetry, forming all lattice points after centering).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述Bravais lattice的概念，答案是一段文字解释，符合简答题的特征 | 知识层次: 题目考查对Bravais晶格这一基本概念的定义和特征的理解，属于基础概念记忆范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求对Bravais晶格的基本定义进行简单记忆和复述，属于最基础的概念性知识。正确选项直接给出了定义性描述，不需要进行任何概念比较或复杂推理，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 962, + "question": "Briefly describe the slip system", + "answer": "A slip system in a crystal refers to a combination of a slip plane and a slip direction on that plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述滑移系统的定义，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对滑移系统这一基本概念的定义记忆和理解，属于材料科学中的基础知识点，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"滑移系统\"的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的定义复述，无需解释或比较多个概念，解题步骤极为简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 963, + "question": "According to the size of defects relative to the crystal dimensions and their range of influence, into which categories can defects be classified? Briefly describe the characteristics of these categories.", + "answer": "There are four categories: Point defects: Very small in all three dimensions, such as solute atoms, interstitial atoms, and vacancies. Line defects: Very small in two dimensions, but large in the third dimension, potentially extending through the entire crystal, referring to dislocations. Planar defects: Very small in one dimension but large in the other two dimensions, such as grain boundaries and phase boundaries. Volume defects: Relatively large in all three dimensions but not excessively so, such as second-phase particles and microscopic voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对缺陷进行分类并简要描述各类别的特征，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目考查对晶体缺陷分类的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目要求考生理解和描述四种缺陷分类及其特征，属于概念解释和描述的层次。虽然需要记忆和掌握多个概念，但题目提供了明确的分类和特征描述，解题步骤相对直接，不需要复杂的分析或比较。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 964, + "question": "Briefly describe segregation", + "answer": "The non-uniformity of chemical composition in alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述一个概念（segregation），答案以文字解释的形式给出，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查基本概念的记忆和理解，仅要求对\"segregation\"这一术语进行简单定义，不涉及复杂分析或应用。 | 难度: 在选择题型中，此题仅要求识别和回忆\"segregation\"的基本定义，属于最基础的概念记忆。正确选项直接给出了该术语的标准定义，不需要任何解释或推理过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 965, + "question": "Briefly describe dislocations", + "answer": "It is a type of linear defect in crystals, characterized by a regular misalignment of atoms along a line; this defect is described by both a line direction and a Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述位错的定义和特征，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对位错这一基本概念的定义和特征的理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但正确选项不仅需要记忆位错的定义，还需要理解其作为线性缺陷的特征（原子沿线的规则错排）以及描述参数（线方向和伯格斯矢量）。这超出了简单的定义复述，需要对概念有一定程度的理解和描述能力。" + }, + { + "idx": 966, + "question": "Briefly describe secondary recrystallization", + "answer": "The phenomenon of abnormal growth of a few grains that occurs when the normal growth process is inhibited after recrystallization is completed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述二次再结晶现象，需要用文字进行解释和论述，符合简答题的特征 | 知识层次: 题目考查对二次再结晶这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求描述二次再结晶现象，但正确选项已经提供了明确的定义和关键特征（异常晶粒生长、正常生长过程被抑制等），不需要考生进行复杂的分析或比较。这属于对基础概念的理解和记忆，但比简单定义类题目（等级1）需要稍多的知识掌握深度。" + }, + { + "idx": 967, + "question": "Briefly describe the recrystallization temperature", + "answer": "The minimum temperature at which a deformed metal just completes recrystallization within a certain time (generally 1h).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述再结晶温度的定义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对再结晶温度这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并复述\"再结晶温度\"的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了标准定义，不需要任何解释、分析或推理过程，完全符合选择题型中最简单的\"基本定义简答\"难度等级。" + }, + { + "idx": 968, + "question": "What is the structural model that constitutes a small-angle grain boundary?", + "answer": "The structural model of a small-angle grain boundary is the dislocation model, for example, a symmetric tilt grain boundary is described by a set of parallel edge dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释小角度晶界的结构模型，答案提供了详细的文字描述和例子，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对小角度晶界结构模型的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 该题目在选择题型中属于中等难度。虽然考察的是基础概念记忆（小角度晶界的结构模型），但需要考生不仅记住\"位错模型\"这一关键词，还要理解对称倾侧晶界与平行刃位错之间的关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。选择题型中，正确选项提供了具体示例，降低了纯粹记忆的难度，但仍需一定概念理解能力。" + }, + { + "idx": 970, + "question": "Discuss the relationship between crystal structure and space lattice.", + "answer": "The relationship between the two can be described as 'space lattice $^+$ basis $\\asymp$ crystal structure.' There are only 14 types of space lattices, while the basis can be infinitely varied, thus resulting in an infinite variety of specific crystal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求讨论晶体结构与空间点阵之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查晶体结构和空间点阵的基本概念及其关系，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解并描述晶体结构与空间点阵之间的关系，包括空间点阵和基元如何组合形成晶体结构。这需要一定的概念解释和描述能力，而不仅仅是简单的定义记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 971, + "question": "The interface between grains in single-phase metals or alloys is generally called grain boundaries, which are usually divided into two categories: low-angle grain boundaries and high-angle grain boundaries. What is the basis for this classification?", + "answer": "The classification is based on the misorientation between the grains on either side of the boundary. Boundaries with a misorientation <15° are called low-angle grain boundaries, while those >15° are called high-angle grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶界分类的基础，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对晶界分类的基本概念记忆和理解，仅需要回答分类依据的具体角度数值，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接询问了晶界分类的基础，正确选项明确给出了基于晶粒间取向差的角度划分标准（<15°为低角度晶界，>15°为高角度晶界）。这属于材料科学中最基础的概念记忆，无需复杂推理或跨概念整合，仅需识别并匹配定义即可作答。" + }, + { + "idx": 972, + "question": "How does temperature affect atomic diffusion in metals or alloys?", + "answer": "Temperature follows the relationship D=Doe-Q/RT, where an increase in temperature accelerates diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释温度如何影响金属或合金中的原子扩散，需要文字解释和论述，而不是选择、判断或计算。答案提供了扩散系数与温度的关系，并解释了温度升高对扩散的影响，符合简答题的特征。 | 知识层次: 题目涉及扩散系数与温度关系的公式应用，需要理解阿伦尼乌斯方程中各参数的含义及其物理意义，并能够解释温度变化对扩散速率的影响机制。这属于中等应用层次，需要将基本概念与公式关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解扩散系数与温度的关系公式D=Doe-Q/RT，并能够综合分析温度变化对扩散速率的影响。题目涉及中等应用层次的知识，要求考生进行概念关联和多步计算，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 973, + "question": "What effects do interfaces, surfaces, and dislocations have on atomic diffusion in metals or alloys?", + "answer": "Interfaces, surfaces, and dislocations act as fast diffusion paths.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述界面、表面和位错对原子扩散的影响，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目要求分析界面、表面和位错对金属或合金中原子扩散的影响，并解释其作为快速扩散路径的机理。这需要综合运用多个概念（如扩散机制、晶体缺陷等），进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解界面、表面和位错的基本概念，还需要综合运用这些知识来分析它们对金属或合金中原子扩散的影响机制。正确选项涉及复杂现象的全面分析，需要考生具备机理深度解释的能力，能够将多个知识点联系起来进行推理和综合判断。这种题目在选择题型中属于对知识掌握深度和综合分析能力要求极高的类型。" + }, + { + "idx": 974, + "question": "How does the third component affect binary diffusion?", + "answer": "The third component can have different effects on binary diffusion, such as Mo and W reducing the diffusion coefficient of C in γ-Fe; Co and Si accelerating the diffusion of C; Mn and Ni having little effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第三组分对二元扩散的影响，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释第三组分对二元扩散的影响，并列举了不同元素的具体作用。这需要综合运用扩散理论、理解不同元素在材料中的行为，并进行机理上的解释。涉及多个概念的关联和综合分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 975, + "question": "What are the characteristics of nucleation in the solid-state phase transformation of metals?", + "answer": "Predominantly heterogeneous nucleation; exhibits specific orientation relationships; phase interfaces are often coherent or semi-coherent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固态相变中成核的特征，答案提供了详细的文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及固态相变中形核特性的分析，需要综合运用形核理论、界面结构和取向关系等知识进行解释和论述，思维过程要求较高的推理分析和机理解释能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生对固态相变中的形核特性有深入的理解，包括异质形核的主导性、特定取向关系以及相界面的共格或半共格特性。这些知识点不仅需要记忆，还需要综合运用和推理分析，属于复杂现象的全面分析层次。选择题型中，这类题目通常要求考生具备较高的知识掌握深度和解题能力，能够从多个选项中准确识别出正确描述复杂机理的选项。" + }, + { + "idx": 976, + "question": "How does melting point affect atomic diffusion within the same alloy system?", + "answer": "Within the same alloy system, at the same temperature, diffusion is slower in alloys with higher melting points and faster in those with lower melting points.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释熔化点如何影响原子扩散，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求理解熔点与原子扩散之间的关系，并能在同一合金系统中进行比较分析。这需要将熔点与扩散速率的概念关联起来，进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及熔点和原子扩散之间的关系，要求考生在同一合金系统中对不同熔点的合金进行比较，并理解温度相同时扩散速率的变化。虽然不需要复杂的计算，但需要对材料科学中的基本概念有较好的掌握，并能进行综合分析。" + }, + { + "idx": 977, + "question": "Analyze and discuss the characteristics of microstructural and property changes during the recovery and recrystallization process of cold-worked metals or alloys after plastic deformation.", + "answer": "As the annealing temperature increases or time prolongs, subgrains merge and grow, recrystallization nucleation and growth occur, and equiaxed recrystallized grains with no (or low-density) dislocations replace elongated deformed grains with high dislocation density, followed by normal grain growth. The stored energy is gradually released, most notably during the recrystallization stage; hardness and strength decrease, while elongation increases; electrical resistance decreases and density improves. The changes in various properties during recrystallization are much more pronounced than during recovery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析和讨论冷加工金属或合金在塑性变形后的回复和再结晶过程中的微观结构和性能变化特征，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷加工金属或合金在回复和再结晶过程中的微观结构和性能变化特征，涉及多个阶段的转变（如亚晶合并、再结晶形核与长大、晶粒生长等），需要综合运用材料科学中的位错理论、热力学和动力学知识，解释存储能量释放、硬度强度变化、延伸率提高等复杂现象，并进行机理层面的讨论。这属于需要深度理解和综合分析的高层次认知活动。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求对冷加工金属或合金在回复和再结晶过程中的微观结构和性能变化进行全面分析，涉及多个复杂概念的综合运用和机理解释。正确选项不仅需要理解回复和再结晶的基本过程，还需要掌握亚晶合并与生长、再结晶形核与长大、等轴晶形成、位错密度变化、储存能释放、力学性能和物理性能变化等多个方面的知识。此外，题目还要求比较回复和再结晶阶段性能变化的显著程度，这需要深入的理解和推理分析能力。因此，在选择题型内，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 978, + "question": "What are the main factors affecting the solubility of solid solutions?", + "answer": "The factors affecting the solubility of solid solutions include:\\n1. Atomic size factor. When the relative difference in atomic diameters between the solvent and solute is less than ±15%, it favors higher solubility in substitutional solid solutions; when the relative difference in diameters between the two elements exceeds 41%, it favors higher solubility in interstitial solid solutions.\\n2. Electronegativity factor. The smaller the electronegativity difference between the solvent and solute, the greater the solubility, generally less than 0.4–0.5 for higher solubility.\\n3. Electron concentration factor. This has two aspects: one is the atomic valence effect, where in the same solvent metal, the higher the valence of the solute, the lower the solubility; the other is the relative valence effect, where the solubility is higher when a high-valence solute dissolves into a low-valence solvent compared to the opposite scenario.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响固溶体溶解度的主要因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响固溶体溶解度的主要因素，涉及多个概念（原子尺寸因素、电负性因素、电子浓度因素）的关联和综合分析，需要理解这些因素如何相互作用并影响溶解度，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生理解并综合分析多个关键因素（原子尺寸因素、电负性因素、电子浓度因素）对固溶体溶解度的影响。每个因素都涉及具体的数值范围和条件判断（如±15%、41%、0.4-0.5等），要求考生不仅掌握概念，还能在多角度分析的基础上进行关联性思考。虽然题目提供了正确选项，但选项内容的深度和复杂性明显高于简单的记忆或单一概念应用，属于选择题型中较高难度的题目。" + }, + { + "idx": 979, + "question": "What is the difference in phase transformation resistance between the solid-state phase transformation of metals and the crystallization process of metals?", + "answer": "There is an additional term of strain energy in the phase transformation resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属的固态相变和结晶过程在相变阻力上的差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较金属固态相变和结晶过程的相变阻力差异，并解释其中应变能的作用。这需要深入理解相变机制、能量变化和微观结构演变，涉及多个概念的关联和综合分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 980, + "question": "Discuss the effect of aging temperature on the precipitation sequence of Al 4.5%Cu alloy", + "answer": "Increasing the aging temperature accelerates precipitation but reduces supersaturation and the driving force for phase transformation, potentially leading to direct precipitation of the equilibrium θ phase and weakening age-hardening capability; conversely, too low aging temperature prolongs the time required to achieve optimal performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论时效温度对Al 4.5%Cu合金析出序列的影响，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析时效温度对Al-Cu合金析出序列的影响，涉及相变驱动力、过饱和度、时效硬化能力等多个概念的关联和综合分析，需要深入理解析出序列的机理及其与温度的关系，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 981, + "question": "How does crystal structure affect atomic diffusion in metals or alloys?", + "answer": "In crystal structures with low symmetry, there is anisotropy in diffusion coefficients, such as in hexagonal crystals where the diffusion coefficients parallel and perpendicular to the basal plane (0001) differ.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体结构如何影响金属或合金中的原子扩散，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求分析晶体结构对原子扩散的影响，涉及晶体对称性与扩散系数的各向异性关系，需要综合运用晶体学和扩散理论的知识，进行机理层面的解释和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解晶体结构的基本概念，还需要掌握原子扩散的机理，并能综合运用这些知识分析低对称性晶体结构（如六方晶体）中扩散系数的各向异性现象。正确选项涉及复杂的机理解释和现象分析，需要考生具备深入的材料科学知识和推理能力，远超选择题型中对基础概念的记忆或简单应用要求。" + }, + { + "idx": 982, + "question": "What are the characteristics of the phase transformation products in the solid-state phase transformation of metals?", + "answer": "There are metastable phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属固态相变产物的特征，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对金属固态相变产物特征的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即金属固态相变产物的特征之一（亚稳相的存在）。题目不要求解释或比较多个概念，只需识别正确选项，属于最基础的定义简答难度。" + }, + { + "idx": 983, + "question": "Taking the Al-4.5%Cu alloy as an example, analyze the decomposition process of supersaturated solid solution (precipitation sequence).", + "answer": "After solution treatment of the Al-4.5%Cu alloy, aging at the optimal temperature of ~150°C will result in the precipitation sequence: GP zones are regions enriched with copper atoms; θ' is a metastable phase with a tetragonal structure, disk-shaped, precipitating along the {100} planes of the matrix, possessing coherent/semi-coherent interfaces with specific orientation relationships to the matrix; θ is a stable phase with a tetragonal structure, irregular in shape.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析Al-4.5%Cu合金过饱和固溶体的分解过程（析出序列），需要文字解释和论述，答案提供了详细的析出序列描述，符合简答题的特征。 | 知识层次: 题目要求分析Al-4.5%Cu合金过饱和固溶体的分解过程（析出序列），涉及多个析出相（GP区、θ'相、θ相）的结构特征、形貌特征以及与基体的界面关系，需要综合运用相变理论、晶体学知识和析出强化机理进行解释，思维过程要求较高的推理分析和机理解释能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握Al-4.5%Cu合金的析出序列，还需要理解各析出相（GP区、θ'相、θ相）的晶体结构、形貌特征、析出取向以及与基体的界面关系等复杂机理。这些知识点涉及材料科学中的相变理论、晶体学和界面科学等多个领域的综合运用，需要考生具备深入的材料科学知识和较强的分析推理能力。在选择题型中，能够正确回答此类题目需要对相关概念有全面而深入的理解，并能将这些知识整合起来进行复杂现象的分析。" + }, + { + "idx": 984, + "question": "What is the driving force for solid-state phase transformation?", + "answer": "The driving force for solid-state phase transformation is the free energy difference between the new and old phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对固态相变的驱动力进行文字解释和论述，答案以简短的文字形式给出，不需要选择、判断或计算。 | 知识层次: 题目考查对固态相变驱动力的基本概念的记忆和理解，属于定义和基本原理的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆和识别基础概念的定义，即固态相变的驱动力是自由能差。不需要解释或分析多个概念，属于最基础的知识点掌握要求。" + }, + { + "idx": 985, + "question": "Both allotropic transformation and recrystallization transformation occur through nucleation and growth mechanisms. What are the differences between them?", + "answer": "Allotropic transformation is a phase transition process, where the derivative of a certain thermodynamic quantity becomes discontinuous; recrystallization transformation is merely the reformation of grains and not a phase transition process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述两种转变过程的区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求比较两种不同的相变机制（同素异构转变和再结晶转变），需要理解它们的本质区别，并能够关联相关概念进行综合分析。虽然涉及基础概念，但需要更深入的理解和应用能力来区分这两种机制。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求区分同素异构转变和再结晶转变这两种不同的相变过程，涉及对相变和再结晶的基本概念的理解，以及它们之间的差异。虽然题目没有涉及复杂的计算，但需要对材料科学中的相变和再结晶有清晰的认识，并能进行概念上的比较。因此，在选择题型内属于等级3的难度。" + }, + { + "idx": 986, + "question": "What are the characteristics of solid-state phase transformation in metals in terms of growth?", + "answer": "Exhibits habit plane phenomena, with specific microstructural morphologies such as plate-like or needle-like.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属中固态相变的生长特性，答案提供了文字描述和论述，符合简答题的特征 | 知识层次: 题目要求解释金属固态相变在生长方面的特征，涉及习惯面现象和特定显微组织形态（如片状或针状），这需要对相变机理、晶体学关系和显微组织形成有深入的理解和分析能力。这超出了简单记忆或基本应用，需要综合运用知识进行推理和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解固态相变的基本概念，还需要掌握生长过程中的特定现象（如习惯面现象）和微观结构形态（如板状或针状）。这需要综合运用材料科学知识，进行复杂现象的分析和机理解释，远超简单的记忆或基础理解层次。" + }, + { + "idx": 987, + "question": "How to eliminate or improve macrostructure defects in steel ingots?", + "answer": "Macro defects (chemical inhomogeneity, physical inhomogeneity, and structural inhomogeneity) are often interrelated. Generally, it is desirable to have as many and fine central equiaxed crystals as possible. Methods such as adding inoculants, increasing cooling rate, and enhancing liquid movement (e.g., electromagnetic stirring, mechanical stirring) can be used to refine grains and eliminate columnar crystals. In this way, macro segregation, shrinkage cavities, and gas bubbles associated with columnar/dendritic crystal zones are significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对如何消除或改善钢锭中的宏观结构缺陷进行解释和论述，答案提供了详细的文字解释和方法描述，符合简答题的特征。 | 知识层次: 题目要求对钢锭宏观缺陷的消除或改善方法进行解释和论述，涉及多种方法的综合运用和机理解释，需要综合分析不同因素（如化学不均匀性、物理不均匀性、结构不均匀性）之间的关联，并提出具体的解决方案（如添加孕育剂、增加冷却速率、增强液体运动等）。这需要较高的认知能力层次（分析、综合）和深度理解相关知识点的复杂性和关联度。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解钢锭宏观缺陷的类型（化学不均匀性、物理不均匀性、结构不均匀性），还需要掌握多种改善方法（添加孕育剂、提高冷却速率、增强液体流动等）及其背后的机理（细化晶粒、消除柱状晶）。此外，题目还要求考生能够将这些方法与其对宏观偏析、缩孔和气孔等缺陷的影响联系起来，进行综合分析和推理。这种复杂现象全面分析和机理深度解释的要求，使得该题目在选择题型中属于最高难度等级。" + }, + { + "idx": 988, + "question": "What are the common macrostructural defects in steel ingots?", + "answer": "Macro defects include: macrosegregation (such as normal segregation, inverse segregation, gravity segregation), banded structure, as well as shrinkage cavities, porosity, and blowholes. Strictly speaking, it also includes the structural inhomogeneity of the three-crystal zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释钢锭中常见的宏观结构缺陷，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对钢锭宏观缺陷的基本分类和记忆，属于基础概念的记忆和理解层次，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个宏观缺陷类型，但主要是要求记忆和识别常见的宏观缺陷分类，不需要深入分析或比较。正确选项提供了明确的分类和例子，属于概念解释和描述的层次，但不需要复杂的推理或应用。" + }, + { + "idx": 989, + "question": "What is the driving force of recovery recrystallization?", + "answer": "The driving force of recovery recrystallization is deformation stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案是一个简短的文字描述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对恢复再结晶驱动力的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆基础概念的定义，即恢复再结晶的驱动力是变形储存能。题目不涉及复杂的概念解释或体系阐述，仅需直接回忆知识点即可作答，属于最基础的难度等级。" + }, + { + "idx": 990, + "question": "Please briefly describe the basic conditions for the crystallization of binary alloys.", + "answer": "Thermodynamic condition: $\\\\Delta G<0$; structural condition: $r>r^{*}$; energy condition: $A>\\\\Delta G_{\\\\mathrm{max}}$; composition condition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述二元合金结晶的基本条件，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查二元合金结晶的基本条件，属于基本原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目要求考生描述二元合金结晶的基本条件，涉及多个概念（热力学条件、结构条件、能量条件和成分条件）的解释和描述。虽然需要记忆多个知识点，但不需要进行复杂的比较分析或深入的概念体系阐述，属于中等难度的概念解释和描述题目。" + }, + { + "idx": 991, + "question": "Describe the common internal and external interfaces in metal crystals.", + "answer": "They include grain boundaries, phase boundaries, surfaces, twin boundaries, and stacking faults. Grain boundaries are the interfaces between grains of the same type; phase boundaries are the interfaces between phases with different structures and compositions; surfaces are the interfaces between crystals and the atmosphere or external environment; twin boundaries are new interfaces formed after twinning, which are special high-angle grain boundaries and can be coherent or semi-coherent; low-energy stacking faults are new interfaces formed within a single-phase crystal due to anomalous changes in stacking sequence, which are also low-energy interfaces with energy levels similar to twin boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述金属晶体中常见的内部和外部界面，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对金属晶体中常见内部和外部界面的定义和分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述金属晶体中常见的内部和外部界面，但正确选项已经提供了明确的分类和定义，包括晶界、相界、表面、孪晶界和堆垛层错等。这些概念属于基础概念记忆层次，但需要考生对每种界面的定义和特点有一定的理解和记忆。题目不需要复杂的分析或比较，但要求考生能够准确识别和描述这些界面类型。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 992, + "question": "Please briefly describe the microscopic mechanisms of diffusion.", + "answer": "Substitutional mechanism: including vacancy mechanism and direct exchange or ring exchange mechanisms, among which the vacancy mechanism is the primary one, while direct exchange and ring exchange mechanisms require high activation energy and generally only occur at high temperatures. Interstitial mechanism: including interstitial mechanism and interstitialcy mechanism, among which the interstitial mechanism is the primary one.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述扩散的微观机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查扩散的微观机制的基本概念记忆和理解，包括替代机制和间隙机制的分类及其主要类型，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求简要描述扩散的微观机制，包括替代机制和间隙机制的分类及其主要机制。虽然涉及多个概念，但主要是记忆性知识，不需要复杂的分析或比较。因此，在选择题型内属于中等难度。" + }, + { + "idx": 993, + "question": "What are the factors that affect diffusion?", + "answer": "The main factors affecting diffusion include: temperature (the higher the temperature, the faster the diffusion rate); crystal structure and type (including packing density, solid solubility, anisotropy, etc.); crystal defects; chemical composition (including concentration, third element, etc.).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响扩散的因素，答案以文字解释和论述的形式呈现，没有提供选项或需要计算。 | 知识层次: 题目考查扩散影响因素的基本概念记忆和理解，属于材料科学中基础知识的范畴，不需要复杂的分析或综合应用。 | 难度: 该题目要求考生列举并简要解释影响扩散的主要因素，涉及多个相关概念（温度、晶体结构、缺陷、化学成分等），但不需要深入分析各因素之间的相互作用机制。在选择题型中，这属于需要对概念进行解释和描述的难度级别，比单纯记忆基本定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 994, + "question": "Please briefly describe the mechanism of low-temperature recovery and its driving force", + "answer": "Low-temperature mechanism: corresponds to the disappearance of vacancies. Driving force: release of stored energy (mainly lattice distortion energy) generated during cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述低温回复的机制及其驱动力，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对低温度恢复机制及其驱动力的基本概念记忆和理解，涉及基础原理和定义，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述低温回复的机制及其驱动力，但正确选项已经提供了明确的定义和基本原理（空位消失和储存能释放）。这需要考生对材料科学中的基本概念有一定的理解和记忆，但不需要进行复杂的分析或推理。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 995, + "question": "What is the difference between kinks and jogs produced when two dislocations intersect?", + "answer": "The intersection of dislocations belongs to the interaction between dislocations, resulting in a bend on each other's dislocation line with a magnitude and direction equal to its Burgers vector. This bend is called a kink or a jog. A kink is the bend produced after intersection that lies on the original slip plane and does not affect the movement of the dislocation, making it easy to disappear. A jog is the bend that does not lie on the original slip plane and affects the slip of the dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释kinks和jogs的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对位错相互作用中kinks和jogs的基本定义和区别的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分kinks和jogs的定义、产生条件以及对位错运动的影响。这要求考生不仅记住定义，还需要能够解释和描述这两个概念的区别。题目没有涉及复杂的推理或多步骤的分析，因此不属于最高难度等级。" + }, + { + "idx": 996, + "question": "Please briefly describe the mechanism of medium-temperature recovery and its driving force", + "answer": "Medium-temperature mechanism: corresponds to the slip (rearrangement, annihilation) of dislocations. Driving force: the release of stored energy (mainly lattice distortion energy) generated during cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述中温回复的机制及其驱动力，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对中温回复机制及其驱动力这一基础概念的记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅能够回忆基础概念（中温回复机制的定义），还需要理解并描述其驱动力的具体来源（冷变形储存能的释放）。这属于概念解释和描述的层次，比单纯记忆定义稍复杂，但不需要进行多概念比较或体系化阐述。" + }, + { + "idx": 997, + "question": "Please briefly describe the mechanism of high-temperature recovery and its driving force", + "answer": "High-temperature mechanism: corresponds to polygonization (dislocation slip + climb). Driving force: release of stored energy (mainly lattice distortion energy) generated during cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述高温回复的机制及其驱动力，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求解释高温回复的机制及其驱动力，涉及位错滑移和攀移等多重概念的综合运用，需要深入理解材料变形和能量释放的机理，属于对知识点的复杂分析和推理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解高温回复的机制（多边形化过程，涉及位错滑移和攀移），还需要准确识别其驱动力（冷变形储存能的释放，主要是晶格畸变能）。这需要考生具备将多个复杂概念（位错理论、能量释放原理、变形机制）综合运用的能力，并进行机理层面的深度解释。选择题型中能够完整回答这种综合机理分析题的选项非常少见，对知识整合和推理能力要求极高。" + }, + { + "idx": 998, + "question": "Please analyze the characteristics and mechanisms of work hardening.", + "answer": "Work hardening: is the strengthening caused by the multiplication of dislocations due to plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析work hardening的特性和机制，需要文字解释和论述，答案也提供了简要的解释，符合简答题的特征。 | 知识层次: 题目要求分析加工硬化的特征和机制，涉及对位错增殖和塑性变形等复杂机理的解释和综合分析，需要深入理解和推理分析能力。 | 难度: 在选择题型中，该题目属于较高难度。题目要求分析加工硬化的特性和机理，正确选项涉及位错增殖和塑性变形的综合理解。这需要考生不仅掌握位错理论的基本概念，还要能够将这些概念与材料强化机制联系起来进行机理层面的解释。在选择题型内，这种需要综合运用知识并理解深层机理的题目属于等级4难度。" + }, + { + "idx": 999, + "question": "Please analyze the characteristics and mechanisms of grain refinement strengthening.", + "answer": "Grain refinement strengthening: It is caused by the increase in the number of grains and the decrease in their size, which increases the resistance to continuous dislocation slip, leading to strengthening. At the same time, the dispersion of slip also enhances plasticity. This strengthening mechanism is the only one that can simultaneously increase both strength and plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶粒细化强化的特点和机制，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析晶粒细化强化的特性和机制，涉及对材料科学中强化机理的深入理解和解释，需要综合运用相关知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求分析晶粒细化强化的特性和机理，涉及多个复杂概念的整合，包括晶粒数量增加、尺寸减小对位错滑移阻力的影响，以及滑移分散对塑性的增强作用。此外，题目还强调这是唯一能同时提高强度和塑性的强化机制，需要考生具备深入的材料科学知识，能够进行综合分析和机理解释。这种题目不仅测试知识点的记忆，更考察对复杂现象的理解和推理能力，因此在选择题型中属于最高难度。" + }, + { + "idx": 1000, + "question": "Assuming that the slip system that can be activated in a face-centered cubic crystal is (111)[011], if the slip dislocation is a pure edge dislocation, please indicate the direction of its dislocation line.", + "answer": "The direction of the dislocation line for a pure edge dislocation is perpendicular to $\\vec{b}$ and lies on the slip plane, which is [211].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案需要详细说明位错线的方向及其与滑移面和滑移方向的关系，而不是简单的选择或判断。 | 知识层次: 题目要求理解面心立方晶体中的滑移系统、纯刃位错的性质，并能够确定位错线的方向。这需要将多个概念（滑移系统、位错类型、位错线方向）关联起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解多个概念并进行多步计算和综合分析。题目要求考生掌握面心立方晶体中的滑移系统、纯刃位错的性质以及位错线与滑移面和柏氏矢量的关系。解题步骤包括确定滑移面(111)、滑移方向[011]，然后根据纯刃位错的定义（位错线垂直于柏氏矢量且位于滑移面上）推导位错线方向[211]。这需要将多个晶体学概念关联起来并进行空间几何分析，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 1001, + "question": "Assuming that the active slip system in a face-centered cubic crystal is (111)[011], if the slip dislocation is a pure screw dislocation, what is the direction of the dislocation line?", + "answer": "The dislocation line of a pure screw dislocation is parallel to $\\\\vec{b}$, which is [011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错线的方向，答案提供了详细的解释和方向说明，符合简答题的特征。 | 知识层次: 题目考查对纯螺型位错线方向与伯氏矢量关系的基本概念记忆和理解，属于材料科学中位错理论的基础知识点，不需要复杂的计算或综合分析。 | 难度: 在选择题型中，该题目仅需记忆纯螺型位错线的方向与伯氏矢量平行的基本原理，属于基础概念记忆的简单题目。无需复杂分析或推理步骤，仅需直接回忆定义即可选择正确答案。" + }, + { + "idx": 1002, + "question": "Please analyze the characteristics and mechanisms of solid solution strengthening.", + "answer": "Solid solution strengthening: Due to solute atoms impeding dislocation motion. Includes elastic interaction (Cottrell atmosphere), electrical interaction (Suzuki atmosphere), and chemical interaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析固溶强化的特性和机制，需要文字解释和论述，答案也提供了详细的解释说明，符合简答题的特征。 | 知识层次: 题目要求分析固溶强化的特性和机制，涉及多种相互作用（弹性、电性、化学）的详细解释，需要综合运用材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目要求考生全面分析固溶强化的特性和机制，包括弹性相互作用（Cottrell atmosphere）、电相互作用（Suzuki atmosphere）和化学相互作用。这需要考生具备深入的材料科学知识，能够综合运用多个概念并进行机理解释。此外，题目还要求考生理解位错运动受阻的具体原因，这属于复杂现象全面分析的范畴。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 1003, + "question": "Assuming that the active slip system in a face-centered cubic crystal is (111)[011], please provide the Burgers vector of the unit dislocation for the slip.", + "answer": "The Burgers vector of the unit dislocation is ${\\vec{b}}={\\frac{a}{2}}$ [011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提供Burgers vector的具体表达式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解面心立方晶体中的滑移系统概念，并应用Burgers向量的计算方法。虽然涉及基础概念，但需要将多个知识点（滑移系统、Burgers向量计算）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行综合分析。题目要求考生掌握面心立方晶体中的滑移系统（111）[011]，并正确识别单位位错的伯格斯矢量。这需要考生具备晶体结构、滑移系统和位错的基本知识，并能将这些概念关联起来进行多步计算。虽然题目给出了正确选项，但考生仍需理解伯格斯矢量的计算方法和单位位错的概念，才能确认选项的正确性。因此，在选择题型内，该题目属于中等应用难度，对应等级3。" + }, + { + "idx": 1004, + "question": "Please analyze the characteristics and mechanisms of dispersion strengthening (age strengthening).", + "answer": "Dispersion strengthening (age strengthening): It is the strengthening caused by fine dispersed second phases hindering dislocation motion. This includes the shearing mechanism and the bypassing mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析分散强化（时效强化）的特性和机制，需要文字解释和论述，答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求分析弥散强化（时效强化）的特性和机制，涉及对位错运动的阻碍机制（剪切机制和绕过机制）的解释，需要综合运用材料科学中的强化机制知识，进行机理层面的分析和解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解分散强化（时效强化）的基本概念，还需要掌握其背后的两种具体机制（剪切机制和绕过机制），并能准确区分和描述这些机制如何阻碍位错运动。这需要考生具备深入的材料科学知识，能够进行复杂现象的综合分析，并准确解释机理。这种题目在选择题型中属于对知识掌握深度和综合分析能力要求极高的类型。" + }, + { + "idx": 1005, + "question": "Please analyze the characteristics and mechanisms of multiphase strengthening.", + "answer": "Multiphase strengthening: When the relative content of the second phase is on the same order of magnitude as the matrix, strengthening occurs. The degree of strengthening depends on the quantity, size, distribution, and morphology of the second phase, and if the strength of the second phase is lower than that of the matrix, it may not contribute to strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析多相强化的特性和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析多相强化的特性和机制，涉及对多相材料中第二相的数量、尺寸、分布和形态等因素的综合分析，以及对强化机制的深入理解和解释。这需要较高的认知能力层次，包括分析、综合和推理，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目要求考生不仅理解多相强化的基本概念，还需要综合分析第二相的数量、尺寸、分布和形态对强化效果的影响，以及第二相强度与基体强度的相对关系。这涉及到多个因素的相互作用和机理的深度解释，属于复杂现象的全面分析，因此难度等级为5。" + }, + { + "idx": 1006, + "question": "If a piece of iron is heated from room temperature 20°C to 850°C, then cooled very quickly to 20°C, calculate the change in the number of vacancies before and after the treatment (assuming the energy required to form 1 mole of vacancies in iron is 104600J).", + "answer": "$$ \\\\cdot\\\\frac{c_{850\\\\mathrm{PC}}}{c_{20\\\\mathrm{PC}}}=\\\\frac{A\\\\mathrm{e}^{-\\\\frac{\\\\Delta E}{k\\\\cdot(850+273)}}}{A\\\\mathrm{e}^{-\\\\frac{\\\\Delta E}{k\\\\cdot(20+273)}}}=\\\\mathrm{e}^{-\\\\frac{104675}{1123\\\\times8.31}\\\\frac{104675}{293\\\\times8.31}}=6.3\\\\times10^{13}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和参数来计算空位数的变化，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括温度转换（摄氏到开尔文）、应用阿伦尼乌斯公式计算空位浓度比，以及对数运算。虽然不涉及多个概念的复杂关联或深度机理分析，但需要正确理解和应用热力学公式进行计算，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解空位形成能的概念，掌握阿伦尼乌斯公式的应用，并进行多步温度单位转换和指数计算。虽然题目提供了关键参数，但需要综合运用热力学和材料科学知识完成从摄氏温度到开尔文温度的转换、玻尔兹曼常数应用以及复杂的指数运算。相比简单记忆或单步计算的选择题，该题目对计算能力和概念关联性要求较高，但尚未达到多变量交互作用的复杂程度。" + }, + { + "idx": 1007, + "question": "From the perspective of bonding, analyze the characteristics of metallic materials", + "answer": "Metallic materials: Primarily bonded by metallic bonds, most metals exhibit high strength and hardness, along with good plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合角度分析金属材料的特性，需要文字解释和论述，答案也是以文字形式给出分析结果 | 知识层次: 题目要求从键合的角度分析金属材料的特性，这需要综合运用金属键的基本原理，理解键合与材料性能之间的关系，并进行推理分析。这超出了简单记忆或基本应用的范围，属于对知识的深度理解和综合分析。 | 难度: 在选择题型内，该题目要求从键合角度分析金属材料的特性，涉及金属键的本质及其对材料性能的影响。这需要考生不仅掌握金属键的基本概念，还要能够综合运用这些知识解释材料的强度、硬度和塑性等复杂现象。题目要求的知识层次属于\"复杂分析\"，需要考生进行推理分析和机理解释，这在选择题型中属于最高难度等级。" + }, + { + "idx": 1008, + "question": "From the perspective of bonding, analyze the characteristics of polymer materials", + "answer": "Polymer materials: primarily covalent bonds within molecules, with intermolecular forces mainly consisting of molecular bonds and hydrogen bonds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合角度分析高分子材料的特性，需要文字解释和论述，答案也以文字形式呈现，符合简答题的特征。 | 知识层次: 题目要求从键合的角度分析高分子材料的特性，涉及对共价键、分子间作用力和氢键的综合理解和分析，需要综合运用材料科学和化学键合的知识进行推理和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1009, + "question": "What are the common characteristics of the two major types of ceramic crystalline phases?", + "answer": "(1) The bonding is primarily ionic, with a certain proportion of covalent bonding; (2) They have a definite composition that can be expressed by an exact chemical formula; (3) They exhibit typical non-metallic properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述陶瓷晶相的常见特征，答案以文字形式列出多个要点，符合简答题的特点。 | 知识层次: 题目考查陶瓷晶体相的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及陶瓷晶体相的基本特性，但正确选项涵盖了多个关键点（离子键与共价键比例、确定化学式、非金属性质），需要考生对基础概念有一定的理解和记忆。不过，这些知识点属于材料科学中的基础内容，且选项之间没有复杂的逻辑关系或需要深入分析，因此难度等级为2。" + }, + { + "idx": 1010, + "question": "From the perspective of bonding types, analyze the characteristics of composite materials", + "answer": "Composite materials: artificial combinations of the above three basic materials, with a wide variety of bonding types and significant performance differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合类型的角度分析复合材料的特点，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求从键合类型的角度分析复合材料的特性，这需要综合运用材料科学中的键合理论、复合材料的结构与性能关系等知识，进行推理分析和机理解释。涉及的知识点较为复杂，且需要深入理解不同键合类型对材料性能的影响，思维过程的深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求从键合类型的角度分析复合材料的特性，这需要考生具备对多种基本材料键合类型的深入理解，并能综合运用这些知识进行复杂现象的全面分析。正确选项涉及人工组合三种基本材料、多种键合类型以及性能差异的显著特点，这要求考生不仅掌握基础概念，还需要能够进行机理深度解释和复杂现象的推理分析。在选择题型中，这种综合运用和深度分析的题目属于最难的一类。" + }, + { + "idx": 1011, + "question": "What are the two major categories of ceramic crystal phases?", + "answer": "Oxide ceramics and silicate ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答陶瓷晶体相的两大主要类别，答案以文字解释的形式给出，没有提供选项或需要计算。 | 知识层次: 题目考查陶瓷晶体相的两大主要分类，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，此题属于基础概念记忆类题目，仅需识别陶瓷晶体相的两个主要类别（氧化物陶瓷和硅酸盐陶瓷）。题目不涉及复杂的概念解释或比较分析，只需简单的分类记忆即可作答，因此属于最低难度等级。" + }, + { + "idx": 1012, + "question": "What are the characterization methods for dislocation density?", + "answer": "There are two methods: volume density, which is the length of dislocation lines per unit volume; and surface density, which is the number of dislocation lines perpendicularly passing through a unit area.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述位错密度的表征方法，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对位错密度表征方法的基本概念记忆和理解，仅需回答两种方法的定义，不涉及应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生记忆并理解位错密度的两种表征方法（体积密度和表面密度）的定义，但不需要进行复杂的比较分析或推导。虽然涉及两个概念，但都属于基础概念记忆层次，解题步骤相对简单，只需正确识别和匹配定义即可。" + }, + { + "idx": 1013, + "question": "From the perspective of bonding, analyze the characteristics of ceramic materials", + "answer": "Ceramic materials: primarily covalent and ionic bonds, hard, brittle, difficult to deform, high melting point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合的角度分析陶瓷材料的特性，需要文字解释和论述，答案也是以文字形式呈现的简要论述。 | 知识层次: 题目要求从化学键的角度分析陶瓷材料的特性，需要综合运用化学键理论（共价键和离子键）与材料性能（硬度、脆性、变形能力、熔点）之间的关联，进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于复杂分析的层次。 | 难度: 在选择题型中，该题目要求考生从化学键合的角度深入分析陶瓷材料的特性，涉及共价键和离子键的综合理解，以及这些键合类型如何影响材料的硬度、脆性、变形能力和熔点。这需要考生不仅掌握基础概念，还能进行机理层面的解释和推理，属于较高难度的选择题。" + }, + { + "idx": 1014, + "question": "Compare the activation energies of substitutional diffusion and interstitial diffusion.", + "answer": "In comparison, the activation energy of interstitial diffusion is smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种扩散方式的激活能，并给出解释性的答案，这属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对两种扩散方式（置换扩散和间隙扩散）激活能的基本概念记忆和理解，属于基础概念层面的比较。 | 难度: 在选择题中属于中等难度，需要理解并比较两种扩散机制（置换扩散和间隙扩散）的激活能概念，但不需要深入分析复杂的影响因素或推导过程。" + }, + { + "idx": 1015, + "question": "For cold-rolled pure copper sheets, if high strength is required, what heat treatment should be performed?", + "answer": "To maintain high strength, low-temperature annealing should be performed to allow only recovery and eliminate residual stresses.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应该进行何种热处理以获得高强度，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求考生理解冷轧纯铜板材的性能需求，并选择适当的热处理工艺。这需要将材料加工（冷轧）与热处理知识关联起来，分析不同热处理工艺（如低温退火）对材料性能（强度）的影响。虽然不涉及复杂计算，但需要多步概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解冷轧纯铜板材的强化机制（加工硬化）与热处理的关系，并能综合分析低温退火（仅发生回复过程）对残余应力和强度的具体影响。题目要求将材料加工工艺与微观结构变化相关联，但选项本身提供了明确的方向指引，降低了纯粹记忆性知识的难度。" + }, + { + "idx": 1016, + "question": "For cold-rolled pure copper sheets, what heat treatment should be performed if further cold rolling to reduce thickness is required?", + "answer": "To continue cold deformation, high-temperature annealing should be conducted to induce recrystallization and soften the microstructure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取的热处理措施，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对冷轧纯铜板材的热处理工艺选择，需要理解冷变形后的材料状态以及再结晶退火的作用，属于将基本原理应用于具体工艺场景的中等应用层次。虽然不涉及复杂计算，但需要综合分析材料状态与热处理目的之间的关系。 | 难度: 在选择题中属于中等难度，需要理解冷轧纯铜板材的加工硬化现象、再结晶退火的作用以及后续冷轧工艺要求之间的关联。题目要求考生综合应用材料加工和热处理知识，判断在特定工艺条件下应采取的热处理措施，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1017, + "question": "What is the physical meaning of diffusion activation energy?", + "answer": "The physical meaning of diffusion activation energy is the energy barrier that must be overcome during atomic jumps, which is the obstruction posed by surrounding atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散激活能的物理意义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查扩散激活能的基本概念和物理意义的记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于概念解释和描述难度。题目要求理解扩散激活能的物理意义，即原子跳跃过程中必须克服的能量障碍，这需要一定的概念理解而非简单记忆定义。虽然不涉及复杂概念体系，但比基本定义简答要求更高的理解深度。" + }, + { + "idx": 1018, + "question": "Analyze the effect of cold plastic deformation on the microstructure of alloys", + "answer": "1) Microstructure: 1 Formation of fibrous structure, grains are elongated along the deformation direction; 2 Formation of dislocation cells; 3 Grain rotation forms deformation texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金微观结构的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金微观结构的影响，涉及多个微观结构变化的解释（纤维结构形成、位错胞形成、变形织构形成），需要综合运用材料科学原理进行机理分析和推理，思维过程深度较高。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求分析冷塑性变形对合金微观结构的影响，涉及多个复杂的知识点，包括纤维结构的形成、位错胞的形成以及变形织构的形成。这些知识点不仅需要深入理解，还需要综合运用和推理分析。此外，题目要求对复杂现象进行全面分析，这在选择题型中属于较高层次的能力要求。因此，该题目在选择题型内属于最高难度等级。" + }, + { + "idx": 1019, + "question": "Given a certain low-carbon steel with $\\sigma_{0}=64\\mathrm{kPa}$, $K=393.7\\mathbf{k}\\mathbf{Pa}\\cdot\\mu\\mathbf{m}^{\\frac{1}{2}}$, and a grain diameter of $50\\mu\\mathrm{m}$, what is the yield strength of this low-carbon steel?", + "answer": "According to the Hall-Petch formula: $$\\sigma_{\\mathrm{s}}=\\sigma_{0}+K d^{-{\\frac{1}{2}}}=(64+393.7\\times50^{-{\\frac{1}{2}}})\\mathbf{kPa}=(64+55.68)\\mathbf{kPa}=119.7\\mathbf{kPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的参数和公式（Hall-Petch公式）进行数值计算，最终得出一个具体的数值结果（yield strength）。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查Hall-Petch公式的直接应用和简单计算，不需要多步计算或综合分析，属于基本公式的直接套用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了Hall-Petch公式，并提供了所有必要的参数（σ₀、K、d），只需将这些数值代入公式进行简单的数学运算即可得到答案。不需要额外的概念理解或复杂的分析步骤，属于最基础的难度级别。" + }, + { + "idx": 1020, + "question": "Given that for carbon diffusion in γ-Fe, D0=2.0×10^(-5)m²/s, Q=1.4×10^5J/mol, gas constant R=8.314J/(mol·K), calculate the diffusion coefficient D927°C at 927°C.", + "answer": "D927°C = D0 * exp(-Q / (R * T)) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * (927 + 273))) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * 1200)) = 2.0×10^(-5) * exp(-14.033) ≈ 2.0×10^(-5) * 8.315×10^(-7) ≈ 1.663×10^(-11) m²/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数D的具体数值，属于典型的计算题类型。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及基本公式的套用和数值计算，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单应用难度，题目要求直接套用扩散系数公式进行计算，涉及基本公式应用和简单计算，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 1021, + "question": "Calculate the packing density of the most densely packed plane in a BCC crystal.", + "answer": "The most densely packed plane in BCC is the {110} plane, and its area is: $A=a\\\\times{\\\\sqrt{2}}a={\\\\sqrt{2}}a^{2}$ \\n\\nThe area occupied by atoms on the {110} plane (two atoms) is: $$A^{\\\\prime}=2\\\\times\\\\pi R^{2}=2\\\\pi{\\\\left(\\\\frac{\\\\sqrt{3}}{4}a\\\\right)}^{2}=\\\\frac{3}{8}\\\\pi a^{2}$$ The packing density: $d=\\\\frac{A^{\\\\prime}}{A}=\\\\frac{3}{8\\\\sqrt{2}}\\\\pi=0.8332$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了面积计算、原子半径与晶格常数的关系以及密度的计算，这些都是典型的计算题特征。答案给出了具体的计算步骤和最终数值结果，符合计算题的特点。 | 知识层次: 题目需要多步计算（包括面积计算、原子面积计算和密度计算），并涉及BCC晶体结构的基本概念（如{110}平面和原子半径与晶格常数的关系）。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构中最密排面的概念，掌握{110}平面的几何计算，并进行多步数学运算（包括面积计算、原子半径与晶格常数的关系、以及最终的密度计算）。虽然题目提供了正确选项，但解题过程涉及多个知识点的综合应用和较为复杂的计算步骤，超出了基础选择题的难度水平。" + }, + { + "idx": 1022, + "question": "Given that for carbon diffusion in γ-Fe, D0=2.0×10^(-5)m²/s, Q=1.4×10^5J/mol, gas constant R=8.314J/(mol·K), calculate the diffusion coefficient D1027°C at 1027°C.", + "answer": "D1027°C = D0 * exp(-Q / (R * T)) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * (1027 + 273))) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * 1300)) = 2.0×10^(-5) * exp(-12.953) ≈ 2.0×10^(-5) * 2.394×10^(-6) ≈ 4.788×10^(-11) m²/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值，属于典型的计算题。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及温度单位的转换和指数运算，但不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目仅涉及单一公式的直接应用和简单计算，无需多个公式组合或复杂分析。学生只需正确代入给定数值到阿伦尼乌斯方程中并进行指数运算即可得出结果。" + }, + { + "idx": 1023, + "question": "Analyze the effect of cold plastic deformation on the energy of the alloy system", + "answer": "(4) The system energy includes two parts: 1 The lattice distortion caused by a large number of defects generated during cold deformation increases the distortion energy; 2 The microscopic and macroscopic internal stresses caused by uneven deformation between grains and different parts of the workpiece. These two parts are collectively referred to as stored energy, with the former being the primary. The changes in microstructure and properties caused by cold deformation prepare the alloy for subsequent recovery and recrystallization in terms of both structure and energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金系统能量的影响，答案提供了详细的文字解释和论述，包括两部分能量的变化及其对后续恢复和再结晶的影响，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金系统能量的影响，涉及多个方面的综合理解和分析，包括缺陷导致的晶格畸变、微观和宏观内应力等复杂概念，并需要将这些因素关联起来解释存储能量的形成及其对后续回复和再结晶的影响。这需要较高的认知能力和深度思维过程。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解冷塑性变形对合金系统能量的影响，还需要综合运用多个知识点进行推理分析。具体来说，考生需要掌握以下内容：" + }, + { + "idx": 1024, + "question": "Analyze the effect of cold plastic deformation on the mechanical properties of alloys", + "answer": "(2) Mechanical properties: The dislocation density increases, dislocations become entangled with each other, and the resistance to movement increases, resulting in work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金力学性能的影响，涉及位错密度增加、位错纠缠和加工硬化等机理的解释，需要综合运用材料科学中的变形机制和力学性能变化的知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解冷塑性变形对合金机械性能的影响，还需要掌握位错密度增加、位错纠缠以及由此导致的加工硬化等机理。这些知识点涉及较深的材料科学原理，需要考生具备综合运用和推理分析的能力。此外，题目要求考生在多个选项中识别出正确描述这些复杂现象的选项，这增加了题目的难度。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 1025, + "question": "Calculate the multiple of change in the diffusion coefficient when the temperature increases from 927°C to 1027°C.", + "answer": "Multiple of change = D1027°C / D927°C = (4.788×10^(-11)) / (1.663×10^(-11)) ≈ 2.88 times", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算扩散系数的变化倍数），并给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需套用扩散系数与温度的关系公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用扩散系数随温度变化的公式并进行简单的除法计算。题目提供了具体的数值，无需额外的推导或复杂的步骤，属于单一公式直接计算的难度等级。" + }, + { + "idx": 1026, + "question": "Analyze the effect of cold plastic deformation on the physical and chemical properties of alloys", + "answer": "(3) Physical and chemical properties: The changes are complex, mainly affecting electrical conductivity, thermal conductivity, chemical activity, chemical potential, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金物理和化学性质的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金物理和化学性质的影响，涉及多个性质（电导率、热导率、化学活性、化学势等）的综合分析，需要理解变形与性质变化之间的机理，并进行推理和解释。这超出了简单记忆或应用，属于复杂分析和综合运用的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1027, + "question": "Analyze the characteristics of grain boundaries from the structural features of grain boundaries", + "answer": "Structural features of grain boundaries: The atomic arrangement is relatively disordered and contains a large number of defects. Characteristics of grain boundaries: (3) Numerous defects such as dislocations and vacancies—high grain boundary diffusion rate. (6) Enrichment of trace elements and impurities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶界的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析晶界的结构特征及其特性，涉及对晶界原子排列无序性、缺陷类型（如位错和空位）以及微量元素富集等概念的综合理解和应用。虽然不涉及复杂计算，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生不仅理解晶界的基本结构特征（如原子排列无序和缺陷），还需要综合分析这些结构特征如何导致晶界的特性（如高扩散率和杂质富集）。这涉及多步骤的概念关联和综合分析，超出了简单的记忆或单一概念的应用，属于较高难度的选择题。" + }, + { + "idx": 1028, + "question": "Analyze the characteristics of grain boundaries from the perspective of their energy features", + "answer": "Energy features of grain boundaries: Atoms have higher energy and stronger activity compared to the grain interior. Characteristics of grain boundaries: (1) Grain boundary—distortion—grain boundary energy—transformation to a lower energy state—grain growth, grain boundary straightening—reduction in grain boundary area. (2) Hindering dislocation movement—increase in σb—grain refinement strengthening. (4) High grain boundary energy and complex structure—easily meeting the conditions for solid-state phase transformation—primary site for solid-state phase transformation. (5) Poor chemical stability—grain boundaries are prone to corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶界的能量特征及其相关特性，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求从能量特征的角度分析晶界的特性，涉及多个复杂概念的关联和综合分析，如晶界能、位错运动、固态相变条件等，需要深入理解和推理分析晶界的能量状态及其对材料性能的影响。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从能量特征的角度综合分析晶界的特性，涉及多个复杂概念和机理的深度解释（如晶界能量、位错运动阻碍、固态相变条件等）。正确选项包含5个不同维度的晶界特性分析，每个维度都需要对材料科学中的核心机理有深刻理解。考生需要同时掌握晶界结构、能量状态、力学性能影响、相变行为等多方面知识，并能将这些知识点相互关联形成系统认知。这种在选择题型内要求全面分析复杂现象并解释深层机理的题目，对学生的知识整合能力和高阶思维能力提出了极高要求。" + }, + { + "idx": 1029, + "question": "Dislocation", + "answer": "Dislocation: A one-dimensional or linear defect in a crystal, known as a dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征 | 知识层次: 题目考查对位错（dislocation）这一基本概念的定义和简单描述，属于基础概念的记忆和理解层面，不涉及应用、分析或综合等高阶认知能力。 | 难度: 在选择题型中，该题目仅要求识别或回忆\"dislocation\"的基本定义，属于最基础的概念记忆层次。正确选项直接给出了明确的定义，无需任何解释、分析或比较步骤，完全符合等级1\"基本定义简答\"的标准。这种题目在选择题中属于最低难度级别，只需对术语有最表层的记忆即可作答。" + }, + { + "idx": 1030, + "question": "Coordination number", + "answer": "Coordination number: In a crystal structure, the number of atoms that are adjacent to and equidistant from any given atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Coordination number\"进行定义和解释，需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对配位数这一基本概念的定义和记忆，属于基础概念的理解层面，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别配位数的基本定义，属于最基础的概念记忆层次。题目没有涉及复杂概念体系或需要分析推理的步骤，仅需直接回忆定义即可作答，因此属于难度等级1。" + }, + { + "idx": 1031, + "question": "Crystal face family", + "answer": "Crystal face family: Groups of equivalent crystal faces with the same symmetrical relationship (atomic arrangement and distribution, interplanar spacing) are called a crystal face family, denoted by hll.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Crystal face family\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查晶体学中晶面族的基本定义和符号表示，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆基础概念的定义和分类，属于最基础的知识层次。正确选项直接给出了\"crystal face family\"的定义和表示方法，不需要进行任何解释或复杂的概念分析。这种题目只需要考生记住基本定义即可作答，属于选择题中最简单的类型。" + }, + { + "idx": 1033, + "question": "Heterogeneous nucleation", + "answer": "Heterogeneous nucleation: The formation of crystal nuclei in liquid metal preferentially occurs on the surfaces of foreign substances (mold walls or impurities) or at locations with temperature inhomogeneity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Heterogeneous nucleation”进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即异质成核的定义和基本原理，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生准确记忆并理解\"异质形核\"的基本定义和发生条件，涉及对专业术语（如foreign substances, temperature inhomogeneity）的掌握。虽然不需要复杂的分析过程，但需要考生能够区分异质形核与其他形核方式的本质区别，属于概念解释和描述层面的考查。相比简单定义复述题（等级1）更具专业性，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1034, + "question": "Compositional supercooling", + "answer": "Compositional supercooling: During the solidification of an alloy solution, the theoretical solidification temperature remains unchanged, and the degree of supercooling is entirely determined by the distribution of solute components. This type of supercooling is called compositional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Compositional supercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即compositional supercooling的定义和基本原理，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述\"compositional supercooling\"的定义和基本原理。题目要求考生不仅知道这个术语，还要能够解释其背后的物理机制（如固溶体凝固过程中溶质分布对过冷度的影响）。这比简单的定义识别（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1035, + "question": "Pseudoeutectic", + "answer": "Pseudoeutectic: The eutectic structure obtained from an alloy of non-eutectic composition is called pseudoeutectic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Pseudoeutectic\"这一术语进行文字解释和论述，答案提供了该术语的定义，符合简答题的特征。 | 知识层次: 题目考查对\"Pseudoeutectic\"这一专业术语的定义记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目仅考察对\"Pseudoeutectic\"这一基础概念的定义记忆，属于最基础的定义简答类型。题目仅要求识别正确选项中的定义描述，不需要进行概念解释或复杂体系阐述，解题步骤简单直接，符合等级1的基本特征。" + }, + { + "idx": 1037, + "question": "Please indicate the method and principle of vibration refinement for grain refinement in metallic materials.", + "answer": "Vibration refinement. By solidifying the molten metal under vibration, the nucleation rate of the liquid phase is increased on one hand, and the growing crystals are fragmented on the other hand, thereby providing more crystallization nuclei, thus achieving the purpose of grain refinement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动细化晶粒的方法和原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释振动细化晶粒的方法和原理，涉及熔融金属在振动条件下的凝固过程、形核率的增加以及晶体破碎等复杂机理。这需要综合运用材料科学中的凝固理论、晶体生长和振动效应等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解振动细化的基本原理，还需要综合运用金属凝固、形核率、晶体生长等复杂概念，并解释其相互作用机理。正确选项涉及多步骤推理（提高形核率+晶体破碎→提供更多晶核→实现晶粒细化），需要考生具备将理论知识与实际工艺相结合的分析能力，属于复杂现象全面分析层次。" + }, + { + "idx": 1038, + "question": "Law of the center of gravity", + "answer": "Law of the center of gravity: In a ternary alloy phase diagram, if $R$ decomposes into three phases $\\alpha,~\\beta,$ $\\gamma$, then the concentration point of $R$ phase must be located at the center of gravity of $\\Delta\\alpha\\beta\\gamma$ (which is the weight center of gravity of the three phases, not the geometric center of the triangle). Moreover, the weight of $R$ phase has the following relationship with the weights of $\\alpha$, $\\beta$, and $\\gamma$ phases: $$ \\begin{array}{r l}&{w_{R}\\times R d=w_{\\alpha}\\times\\alpha d}\\ &{w_{R}\\times R e=w_{\\beta}\\times\\beta e}\\ &{w_{R}\\times R f=w_{\\gamma}\\times\\gamma f}\\end{array}$$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对“Law of the center of gravity”进行解释和论述，答案提供了详细的文字描述和公式说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及三元合金相图中重心定律的应用，需要理解并应用重心定律进行多步计算和概念关联。虽然题目给出了具体的公式，但需要理解这些公式的物理意义以及如何在实际问题中应用，这超出了简单记忆或直接套用的范畴，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及三元合金相图中的重心定律，需要考生对相图的基本概念和重心定律有深入理解。其次，题目不仅要求识别重心定律的应用，还需要理解浓度点与三相重心之间的关系，以及重量关系的数学表达。此外，题目中的数学表达式和几何概念结合，增加了理解的复杂性。因此，该题目在选择题型中属于需要多角度分析和综合应用知识的难度等级。" + }, + { + "idx": 1040, + "question": "Please indicate the method of adding nucleating agents to refine the grain size of metal materials and its principle.", + "answer": "Adding nucleating agents. Before the melt solidifies, some fine nucleating agents are added and dispersed in the melt to serve as ready-made substrates required for heterogeneous nucleation, thereby significantly increasing the number of nuclei and markedly refining the grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释添加成核剂的方法及其原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是关于晶粒细化方法的基本概念和原理，主要涉及记忆和理解添加成核剂的作用及其原理，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生不仅记住添加成核剂的方法，还要理解其原理（即通过提供异质成核的基底来增加晶核数量从而细化晶粒）。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。因此，该题目在选择题型中属于等级2难度。" + }, + { + "idx": 1041, + "question": "Analyze the reason why the solubility of carbon in austenite is greater than that in ferrite.", + "answer": "Austenite is a face-centered cubic crystal, while ferrite is a body-centered cubic crystal. In both face-centered cubic and body-centered cubic structures, carbon atoms are located in their octahedral interstitial sites. The size of the octahedral interstitial site in face-centered cubic is: $0.535\\\\mathring{\\\\mathbf{A}}^{\\\\odot}$, while in body-centered cubic, it is: 0.129A. Therefore, it can be seen that the solubility of carbon in austenite is much greater than that in ferrite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析碳在奥氏体和铁素体中溶解度差异的原因，答案通过文字解释和论述给出了晶体结构差异和间隙位置大小的比较，符合简答题的特征。 | 知识层次: 题目要求分析碳在奥氏体和铁素体中溶解度差异的原因，涉及晶体结构、间隙位置尺寸的对比和机理解释，需要综合运用材料科学知识进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解奥氏体和铁素体的晶体结构差异（面心立方与体心立方），还需要掌握碳原子在两种晶体结构中的间隙位置（八面体间隙）及其尺寸差异。此外，考生需要将这些结构特征与碳的溶解度差异进行机理层面的解释，涉及复杂的晶体学知识和溶解度影响因素的综合分析。这种题目在选择题型中属于需要深度理解和复杂推理的类型，远超简单的概念记忆或单一知识点应用。" + }, + { + "idx": 1042, + "question": "Please list more than three methods to improve the strength of metal materials and explain their principles.", + "answer": "(1) Grain refinement strengthening. The principle is: increasing the number of grains to enhance the hindering effect of grain boundaries on moving dislocations, thereby achieving strengthening. (2) Solid solution strengthening. This involves dissolving solute atoms into the base metal, causing lattice distortion in the base metal, which inhibits the activity of dislocation sources and improves the strength of the base metal. (3) Work hardening. When a crystal undergoes deformation, dislocations inside the crystal pile up or become entangled, making them difficult to move, thereby strengthening the crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列出并解释多种提高金属材料强度的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举并解释三种提高金属材料强度的方法及其原理，涉及多个概念（晶粒细化强化、固溶强化、加工硬化）的理解和应用，需要将基本原理与实际强化机制关联起来进行分析和解释，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅能够列举多种强化金属材料的方法，还需要理解并解释每种方法的原理。这涉及到多个知识点的综合运用和概念之间的关联分析。具体来说：" + }, + { + "idx": 1043, + "question": "Write all the crystallographic directions included in the <110> direction family in the cubic crystal system.", + "answer": "[110], [101], [011], [110], [101], [011], totaling 6 crystallographic directions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中<110>方向族包含的所有晶向，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查立方晶系中<110>方向族包含的所有晶向的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求记忆立方晶系中<110>方向族的所有结晶学方向，但需要理解方向族的概念以及立方晶系的对称性。解题步骤相对简单，主要是列举所有等效方向，但需要对结晶学方向的基本概念有一定的掌握。因此，在选择题型中属于等级2的难度。" + }, + { + "idx": 1044, + "question": "Write all the crystallographic directions included in the <123> direction family in the cubic crystal system.", + "answer": "[123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], totaling 24 crystallographic directions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中<123>方向族包含的所有晶向，需要文字描述和具体列举，不涉及选择、判断或数值计算。 | 知识层次: 题目要求列出立方晶系中<123>方向族的所有晶向，这需要应用立方晶系晶向指数的基本规则和对称性知识，属于直接套用基本概念进行简单列举的应用层次。虽然涉及多个方向的计算，但思维过程较为直接，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对立方晶系中晶向族的基本理解和直接套用。虽然需要列举多个晶向，但所有选项都是通过简单的排列组合得出，无需复杂计算或深入分析。因此，在选择题型内属于较低难度。" + }, + { + "idx": 1045, + "question": "Analyze the reasons for the formation of the iron-carbon dual phase diagram from a thermodynamic perspective", + "answer": "Thermodynamic analysis reveals that the total free energy of graphite is lower than that of Fe3C. Therefore, graphite is the more stable phase, while Fe3C is a metastable phase. Hence, the Fe-Fe3C system is commonly referred to as the metastable system, and the Fe-C system is called the stable system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从热力学角度分析铁碳双相图形成的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从热力学角度分析铁碳双相图形成的原因，涉及对自由能、稳定相和亚稳相等复杂概念的综合运用和推理分析，需要深入理解热力学原理及其在材料科学中的应用，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求从热力学角度分析铁碳双相图形成的根本原因，涉及对自由能、稳定相和亚稳相等复杂热力学概念的综合理解。正确选项不仅需要识别石墨和Fe3C的热力学稳定性差异，还需要理解这些差异如何导致两个不同系统（亚稳系统和稳定系统）的形成。这种题目要求考生具备将抽象热力学原理与具体材料系统相关联的高级分析能力，远超简单记忆或基础理解层面。在选择题型中，这种需要多步骤推理和机理深度解释的题目属于最复杂的类型。" + }, + { + "idx": 1046, + "question": "Analyze the equilibrium crystallization process of the Fe-0.4%C alloy and indicate the phase composition at room temperature", + "answer": "When C%=0.4%, the Fe-C alloy cools to room temperature, and the phase constituents are α+Fe3C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的相组成，需要文字解释和论述，答案也是以文字形式给出相组成的具体结果 | 知识层次: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的相组成，这需要理解相图的基本原理，并能将相图知识应用于具体合金成分的分析。虽然不涉及复杂计算，但需要将多个概念（如相图、相组成）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，掌握不同碳含量下的相变过程，并能正确识别室温下的相组成。虽然题目涉及多步计算和概念关联，但在选择题型中通过选项提示可以降低部分分析难度。" + }, + { + "idx": 1047, + "question": "Please indicate the methods and principles of refining metal grain size by increasing undercooling.", + "answer": "Increase undercooling. Since the number of grains is directly proportional to the nucleation rate N and inversely proportional to the grain growth rate Vg, increasing N/Vg can refine the grains. Moreover, when undercooling is increased, although both N and Vg increase, the rate of increase in N is faster than that in Vg. Therefore, N/Vg increases with the increase in undercooling, meaning the grains become finer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释增加过冷度细化金属晶粒的方法和原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释通过增加过冷度细化金属晶粒的方法和原理，涉及成核速率和晶粒生长速率的比较分析，需要综合运用材料科学中的相变理论，进行推理分析和机理解释。这超出了简单记忆或基本应用，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1048, + "question": "Analyze the cause of the iron-carbon dual phase diagram from a kinetic perspective", + "answer": "From a kinetic analysis, since Fe3C contains 6.69% carbon, while graphite contains 100% carbon, and the carbon content of commonly used steel materials is less than 5%. Thus, the compositional fluctuation required to form the graphite phase is much larger than that for Fe3C, meaning that forming graphite nuclei is much more difficult than forming Fe3C nuclei.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从动力学角度分析铁碳双相图的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从动力学角度分析铁碳双相图的成因，涉及对Fe3C和石墨相形成的动力学过程的理解和比较，需要综合运用材料科学中的相变动力学知识，进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1049, + "question": "Analyze the equilibrium crystallization process of the Fe-0.4%C alloy and indicate the microstructure constituents at room temperature", + "answer": "When C%=0.4%, the microstructure constituents of the Fe-C alloy upon cooling to room temperature are P+α", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的微观结构组成，需要文字解释和论述，答案也是以文字形式给出微观结构组成。 | 知识层次: 题目要求分析Fe-0.4%C合金的平衡结晶过程并指出室温下的微观组织成分，这需要理解相图、结晶过程以及组织转变的基本原理，并进行一定的综合分析。虽然涉及的知识点较为基础，但需要将多个概念关联起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铁碳合金相图的基本概念，掌握平衡冷却过程中相变规律，并能正确关联0.4%C成分对应的最终室温组织（P+α）。虽然不涉及多步计算，但需要综合分析相图信息并做出正确判断。" + }, + { + "idx": 1050, + "question": "Calculate the content of pearlite in the microstructure of an Fe-0.4%C alloy", + "answer": "The content of pearlite in the microstructure: P%=[(0.4-0.0218)/(0.77-0.0218)]×100%=50.55%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解珠光体含量，答案给出了具体的计算过程和数值结果 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，属于对杠杆定律的直接套用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅要求应用一个基本公式（杠杆定律）进行简单计算，无需多个公式组合或复杂分析。学生只需正确代入给定数值即可得出答案，解题步骤直接且明确。" + }, + { + "idx": 1051, + "question": "Calculate the graphite content in Fe-3.6%C alloy", + "answer": "The graphite content is: wG = (3.6 - 0.68) / (100 - 0.68) × 100% ≈ 2.94%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过计算得出的具体数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需直接套用给定的公式进行计算即可，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用特定公式进行百分比计算，但解题步骤明确且直接，仅涉及单一公式的简单应用和基础代数运算，无需多步骤推导或复杂概念整合。相比等级1的直接计算题稍复杂，但远低于等级3的多公式组合难度。" + }, + { + "idx": 1052, + "question": "Analyze the crystallization process of Fe-3.6%C alloy to obtain a pearlite matrix gray iron structure", + "answer": "For the Fe-3.6%C alloy, to obtain a pearlite matrix gray cast iron structure, according to the Fe-graphite phase diagram, the crystallization process is as follows: L↔γA, L↔(γ+G)3, γ↔G, γ↔(α+Fe3C)JE.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析Fe-3.6%C合金的结晶过程以获得珠光体基体灰口铸铁结构，答案提供了详细的文字解释和相变过程描述，符合简答题的特征。 | 知识层次: 题目要求分析Fe-3.6%C合金的结晶过程以获得珠光体基体的灰铸铁结构，涉及Fe-石墨相图的理解和应用，需要综合运用相变知识、相图分析以及结晶过程的推理分析。这需要较高的认知能力层次，包括理解、应用、分析和综合，且涉及多个知识点的关联和复杂思维过程。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1053, + "question": "If the aforementioned alloy undergoes directional solidification in a 100cm long horizontal round mold, assuming no diffusion in the solid phase during solidification and complete mixing of the liquid composition, and the lines in the phase diagram can be simplified as straight lines, calculate the length of the ledeburite structure at the end of solidification. It is known that the length of the δ phase is 28.75cm, the length of the γ phase is 70.08cm, and the total length is 100cm.", + "answer": "The length of the ledeburite structure is: (100-28.75-70.08)cm=1.17cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，并给出了具体的计算步骤和最终数值结果。解答过程涉及公式应用和逻辑推理，符合计算题的特征。 | 知识层次: 题目主要涉及基本的数值计算和简单的公式应用，无需多步计算或复杂的概念关联。解题过程直接套用已知数据，进行简单的减法运算即可得出结果。 | 难度: 在选择题型中，该题目仅需要简单的减法计算，直接套用已知数据即可得出答案。无需复杂的公式应用或多步骤推理，属于单一公式直接计算的难度等级。" + }, + { + "idx": 1055, + "question": "If the above alloy undergoes directional solidification in a horizontal round mold with a length of 100 cm, assuming no diffusion in the solid phase during solidification and complete mixing of the liquid composition, and the lines in the phase diagram can be simplified as straight lines, calculate the length of the δ phase at the end of solidification. Given C0=0.4, K0=0.09/0.53=0.1698.", + "answer": "Using the formula: Cs=K0C0(1-Z/L)^(K0-1). Substituting the known conditions into the formula gives: 0.09=0.1698×0.4×(1-Z1/100)^(0.1698-1). Calculation yields: 0.09/0.06792=(1-Z1/100)^(-0.8302). Further calculation: 1.325=(1-Z1/100)^(-0.8302). (1-Z1/100)^0.8302=1/1.325=0.7547. 1-Z1/100=0.7125. Z1=28.75 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，答案是通过具体的数学运算得出的数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式的代入和变换，同时需要理解相图和凝固过程中的成分变化规律。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解相图简化、定向凝固条件、成分分布公式等多个概念，并进行多步骤的代数运算和指数计算。虽然题目提供了关键公式，但解题过程中涉及多次变量代换和数学变换，对学生的综合计算能力和概念关联能力要求较高。" + }, + { + "idx": 1056, + "question": "If the aforementioned alloy undergoes directional solidification in a horizontal cylindrical mold with a length of 100 cm, assuming no diffusion in the solid phase during solidification and complete mixing of the liquid composition, and the lines in the phase diagram can be simplified as straight lines, calculate the length of the γ phase at the end of solidification. Given L2=(100-28.75)cm=71.25cm, C0'=0.53, K0'=2.11/4.3=0.4907.", + "answer": "Using the formula: Cs=K0C0(1-Z/L)^(K0-1). Substituting the known conditions into the formula gives: 2.11=0.4907×0.53×(1-Z2/71.25)^(0.4907-1). Calculation yields: 2.11/0.26007=(1-Z2/71.25)^(-0.5093)=8.1132. (1-Z2/71.25)^0.5093=1/8.1132=0.12326. 1-Z2/71.25=0.0164. Z2=70.08 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及代入已知条件和公式推导，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式的代入和变换，同时需要理解相图中的直线简化假设和固相无扩散的条件。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和数值计算技巧。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算和概念关联，需要综合运用相图知识、凝固原理和数学公式推导。虽然提供了正确选项的计算过程，但理解每一步的逻辑和正确代入变量仍需要较强的综合分析能力。相比简单直接的选择题，此题需要更深入的知识应用和计算能力。" + }, + { + "idx": 1058, + "question": "Interstitial phase", + "answer": "Interstitial phase: A compound formed between non-metal atoms (X) and transition metal atoms, when the ratio of atomic radii of the metal element (M) to the non-metal element (X) $R_{\\\\mathrm{X}}/R_{\\\\mathrm{M}}<0.59$, the non-metal atoms are located in the interstices of the metal atoms and exhibit a relatively simple crystal structure, it is called an interstitial phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Interstitial phase”进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对间隙相（Interstitial phase）这一基本概念的定义和特征的理解，主要涉及原子半径比和晶体结构的简单描述，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅要记住\"间隙相\"的定义，还需要理解原子半径比的条件（RX/RM<0.59）以及晶体结构特征。这超出了简单的定义记忆（等级1），需要对概念进行一定程度的解释和描述（等级2），但尚未达到需要阐述复杂概念体系的难度（等级3）。在选择题型中，这种题目需要考生能够识别和匹配概念定义中的关键要素。" + }, + { + "idx": 1059, + "question": "Critical nucleus", + "answer": "Critical nucleus: In a metal liquid, an embryo with a radius larger than the critical radius rk can stably grow and is called a critical nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Critical nucleus\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"Critical nucleus\"这一基本概念的定义和解释，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然涉及基础概念记忆，但需要理解并描述\"critical nucleus\"的定义及其在金属液体中的行为，比单纯记忆定义稍复杂，但不需要进行多概念比较或复杂体系阐述。" + }, + { + "idx": 1060, + "question": "Phase boundary contact rule", + "answer": "Phase boundary contact rule: In a phase diagram, the difference in the number of phases between adjacent phase regions is 1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Phase boundary contact rule\"进行文字解释和论述，答案以简短的文字形式给出，符合简答题的特征。 | 知识层次: 题目考查相图基础概念的记忆和理解，仅需直接陈述相边界接触规则的定义，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"相边界接触规则\"这一基础定义的记忆，无需解释或分析。正确选项直接给出了该规则的定义，属于最基础的概念记忆层次，符合等级1的简答定义要求。" + }, + { + "idx": 1061, + "question": "Write all the crystal planes included in the {110} crystal plane family in the cubic crystal system", + "answer": "(110)(101)(011)(110)(101)(011), totaling 6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中{110}晶面族包含的所有晶面，答案需要具体列出所有符合条件的晶面，属于需要具体回答的简答题类型。 | 知识层次: 题目考查立方晶系中{110}晶面族包含的所有晶面，属于基础概念的记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（{110}晶面族的组成），但需要学生准确回忆立方晶系中所有等效晶面的指数表示，并正确识别正负指数的不同组合。这比单纯记忆单个定义（等级1）要求更高，但不需要复杂的概念体系阐述（等级3）。解题步骤主要是回忆和应用对称性规则，属于概念解释和描述层面的要求。" + }, + { + "idx": 1063, + "question": "Write all the crystal planes included in the {112} crystal plane family of the cubic crystal system", + "answer": "(112)(112)(1 12)(11 2) + (121)(121)(1 21)(12 1) + (211)(211)(2 11)(21 1), totaling 12.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出立方晶系中{112}晶面族包含的所有晶面，答案需要列出具体的晶面指数，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目考查对立方晶系中晶面族{112}的理解和记忆，需要列出所有包含在该晶面族中的晶面。这属于基础概念的记忆和分类，不涉及复杂的计算或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并记忆立方晶系中{112}晶面族的所有可能组合，包括正负指数的排列。这需要一定的记忆能力和对晶面指数的理解，但不需要复杂的分析或推导。因此，难度等级为2。" + }, + { + "idx": 1064, + "question": "If the slip plane of a body-centered cubic crystal is {110} and the slip direction is [111], write out the specific slip systems.", + "answer": "(110)[1 11], (10 1)[1 11], (011)[1 11]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出具体的滑移系统，需要列举出具体的滑移面和滑移方向组合，属于需要文字描述和列举的简答题类型。 | 知识层次: 题目要求根据给定的滑移面和滑移方向写出具体的滑移系统，这需要理解体心立方晶体的滑移系统特性，并能够将给定的滑移面和方向进行组合。虽然不涉及复杂的计算或综合分析，但需要一定的概念关联和多步思考，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶体滑移系统的基本概念，并能够正确识别体心立方晶体的滑移面和滑移方向。此外，题目要求写出具体的滑移系统，这需要一定的综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1065, + "question": "Write all the crystal planes included in the {123} crystal plane family in the cubic crystal system", + "answer": "(123)(123)(123)(123) + (132)(132)(132)(132) + (213)(213)(213)(213) + (231)(231)(231)(231) + (312)(312)(312)(312) + (321)(321)(321)(321), totaling 24.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出立方晶系中{123}晶面族包含的所有晶面，答案需要列举具体的晶面指数，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求学生在立方晶系中确定{123}晶面族的所有晶面，这需要理解晶面指数的定义和立方晶系的对称性，并能够应用这些知识进行多步推导和综合分析。虽然不涉及复杂的计算或创新设计，但需要将多个概念关联起来，并进行系统性思考。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解并应用立方晶系中晶面族的定义和计算方法，这需要中等应用层次的知识掌握。其次，解题步骤较为复杂，需要考生列举所有可能的排列组合，并确保不遗漏任何可能的晶面。此外，题目还要求考生能够正确识别和区分不同的晶面指数排列，这需要较强的综合分析能力。虽然题目提供了正确选项，但在选择题型中，考生仍需具备较高的概念关联和多步计算能力才能准确作答。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 1067, + "question": "Given that copper has an FCC structure with an atomic radius of $0.1278\\\\mathrm{nm}$, calculate its density. (The atomic weight of copper is 63.5, and the Avogadro constant is $0.602\\\\times10^{24}$)", + "answer": "Given that the Cu lattice has an FCC structure, meaning the unit cell contains 4 atoms, to find its density ρ, we only need to calculate the ratio of the mass of the atoms in the unit cell to the volume of the unit cell: $$\\\\rho={\\\\frac{n M}{N_{A}(2{\\\\sqrt{2}}r)^{3}}}={\\\\frac{4\\\\times63.5\\\\times10^{-3}}{0.602\\\\times10^{24}\\\\times(2{\\\\sqrt{2}}\\\\times0.1278\\\\times10^{-9})^{3}}}\\\\mathrm{kg/m^{3}}\\\\approx8933\\\\mathrm{kg/m^{3}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜的密度，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据FCC结构的原子半径计算密度，属于直接套用公式和数值计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解FCC结构的基本概念和密度计算公式，但解题步骤相对直接，仅需套用给定的公式和数据进行简单计算。不需要复杂的推导或多步骤分析，因此在选择题型内属于中等偏下的难度等级。" + }, + { + "idx": 1068, + "question": "Describe the phase transformation process, products, and reaction conditions along the HJB horizontal line in the phase diagram", + "answer": "The HJB horizontal line undergoes a peritectic reaction: L_B + δ_H ⇌ γ_J; product: austenite (A)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述相变过程、产物和反应条件，需要文字解释和论述，答案也是以文字形式给出详细解释 | 知识层次: 题目要求描述相变过程、产物和反应条件，涉及多个概念的综合应用和关联分析，需要理解相图的基本原理并能够解释具体的相变反应，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握相图中的水平线HJB所代表的包晶反应过程、产物及反应条件，涉及液相L_B、δ_H和γ_J之间的转化关系，以及最终产物奥氏体（A）的形成。这需要考生具备对相图的基本理解、反应类型的识别能力以及产物性质的掌握，属于中等应用层次的知识要求。" + }, + { + "idx": 1069, + "question": "If the slip plane of a body-centered cubic crystal is {123} and the slip direction is [111], write out the specific slip systems.", + "answer": "(123)[1 11], (213)[1 11], (231)[1 11], (31 2)[1 11], (132)[1 11], (32 1)[1 11]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出具体的滑移系统，需要根据晶体结构和滑移要素进行列举和解释，答案形式为列举具体的滑移系统，属于简答题类型。 | 知识层次: 题目要求写出具体的滑移系统，需要理解体心立方晶体的滑移面和滑移方向的概念，并能够应用这些知识来确定所有可能的滑移系统。这涉及到多步思考和概念关联，但不需要复杂的推理或深度分析。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生不仅要理解体心立方晶体的滑移面和滑移方向的概念，还需要能够具体写出滑移系统。其次，题目涉及多个滑移系统的列举，需要考生具备较强的空间想象能力和综合分析能力。此外，题目中的滑移面{123}和滑移方向[111]的组合需要考生进行多步计算和概念关联，才能正确写出所有可能的滑移系统。因此，在选择题型内，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 1070, + "question": "Assuming carbon atoms are all located in the octahedral interstices of γ-Fe, calculate the maximum proportion of octahedral interstices occupied by carbon atoms in γ-Fe. (The atomic weight of iron is 55.85, and the Avogadro constant is 0.602×10^24)", + "answer": "In the γ-Fe phase, the maximum carbon concentration C_max = 2.11%. Given that γ-Fe has an FCC structure with n = 4, there are 400 Fe atoms per 100 unit cells. The mass fraction of Fe is: w_Fe = 1 - 2.11% = 97.89%. The total mass is: M = (400 × 55.85) / 0.9789 = 22821.5. The number of carbon atoms is: n_c = (M × C_max) / M_c = (22821.5 × 0.0211) / 12 = 40. Thus, there are 40 carbon atoms per 100 unit cells.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定γ-Fe中碳原子占据八面体间隙的最大比例。答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量分数的转换、总质量的计算以及碳原子数量的确定。虽然涉及的是基本的公式应用，但需要综合运用多个概念和步骤来解决问题，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解γ-Fe的FCC结构、碳原子占据八面体间隙的概念，并进行多步计算（包括质量分数计算、总质量计算和碳原子数量计算）。虽然题目提供了部分数据，但仍需要综合应用材料科学和化学知识来解决问题。" + }, + { + "idx": 1071, + "question": "Describe the phase transformation process, products, and reaction conditions along the ECF line in the phase diagram", + "answer": "The ECF line undergoes a eutectic reaction: L_C ⇌ γ_E + Fe3C; the product is: ledeburite (Ld)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述相变过程、产物和反应条件，需要文字解释和论述，答案也是以文字形式给出具体反应和产物，符合简答题的特征。 | 知识层次: 题目要求描述相变过程、产物及反应条件，涉及相图中ECF线的共晶反应，需要理解相图的基本原理并能够关联不同概念（如相变过程、产物组成等），属于中等应用层次。虽然涉及基础概念，但需要一定的综合分析能力来阐述反应条件和产物。 | 难度: 在选择题中属于中等难度，需要理解相图中的ECF线、共晶反应、产物莱氏体等多个概念，并进行综合分析。虽然题目给出了正确选项，但需要考生具备将相图知识与反应条件、产物关联起来的能力，属于中等应用层次的知识要求。" + }, + { + "idx": 1072, + "question": "Describe the phase transformation process, products, and reaction conditions along the PSK line in the phase diagram", + "answer": "The PSK line undergoes a eutectoid reaction: γ_S ⇌ α_P + Fe3C; product: pearlite (P)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述相变过程、产物和反应条件，需要文字解释和论述，答案也是以文字形式给出详细解释，符合简答题的特征。 | 知识层次: 题目要求描述相变过程、产物及反应条件，涉及相图中PSK线的共析反应，需要理解相图的基本原理并能够关联不同概念（γ相、α相、Fe3C、珠光体）进行综合分析。虽然不涉及复杂计算，但需要对相变过程有较深入的理解和中等程度的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解相图中的PSK线、共析反应、产物珠光体等多个概念，并能将这些概念关联起来进行综合分析。虽然题目给出了正确选项，但学生仍需掌握相图的基本知识和反应过程才能正确选择。" + }, + { + "idx": 1073, + "question": "Density", + "answer": "Density: The ratio of the volume occupied by atoms in a unit cell to the volume of the unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对术语\"Density\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查密度的基本定义和概念记忆，属于基础概念的理解和表述，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆密度的基本定义，属于基础概念记忆层次。题目直接给出定义，不需要解释或分析复杂概念，解题步骤简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 1074, + "question": "Non-steady state diffusion", + "answer": "Non-steady state diffusion: diffusion where both the concentration gradient and the diffusion flux vary with time and distance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Non-steady state diffusion\"进行文字解释和论述，答案是一个定义性的描述，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查非稳态扩散的基本定义，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆，但要求考生不仅记住定义，还需要理解非稳态扩散中浓度梯度和扩散通量随时间距离变化的关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1076, + "question": "Critical nucleation work", + "answer": "Critical nucleation work: the increment of free energy when forming a critical nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Critical nucleation work\"进行文字解释和定义，答案以论述形式给出，符合简答题的特征 | 知识层次: 题目考查对\"Critical nucleation work\"这一基础概念的定义记忆和理解，属于材料科学中相变理论的基础知识点，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"临界成核功\"的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了定义，无需任何解释、分析或复杂推理过程，符合选择题型中最简单的难度等级标准。" + }, + { + "idx": 1077, + "question": "Calculate the relative content of each phase when an alloy containing 0.40% C is cooled to room temperature under equilibrium conditions.", + "answer": "Relative content of each phase: w_α=(6.69-0.40)/(6.69-0.0008)×100%=94%; w_Fe3C=1-w_α=1-94%=6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（杠杆定律）来确定各相的相对含量，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要考查杠杆定律在铁碳相图中的应用，属于基本公式的直接套用和简单计算，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用杠杆定律公式计算各相相对含量，但题目已经给出了具体的计算步骤和公式，学生只需正确代入数值进行简单计算即可得出答案。不需要多个公式组合或复杂分析，因此难度等级为2。" + }, + { + "idx": 1078, + "question": "Calculate the relative content of each microstructural constituent in an alloy containing 0.40% C when it is cooled to room temperature under equilibrium conditions.", + "answer": "The relative content of each microstructural constituent: w_P=(0.40-0.0218)/(0.77-0.0218)×100%=50.5%; w_a=1-w_P=1-50.5%=49.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金中各微观结构组成的相对含量，答案给出了具体的计算过程和结果。 | 知识层次: 题目要求应用杠杆定律进行简单的二元合金相组成计算，属于基本公式的直接套用和单步计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用杠杆定律公式进行相对含量的计算，但解题步骤明确且直接，仅涉及单一公式的套用和简单代数运算。不需要复杂的推导或多步骤分析，符合选择题型中等级2的难度标准。" + }, + { + "idx": 1079, + "question": "Extended dislocation", + "answer": "Extended dislocation: In FCC crystals, a perfect dislocation is difficult to exist due to its high energy and will automatically decompose into two partial dislocations and a stacking fault in between, forming the so-called extended dislocation configuration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Extended dislocation进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对扩展位错这一基本概念的记忆和理解，包括其在FCC晶体中的形成原因和组成结构，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及FCC晶体中位错分解的概念，但主要考察的是对\"extended dislocation\"这一基础概念的记忆和理解，不需要进行复杂的分析或推导。正确选项给出了明确的定义和形成机制描述，属于概念解释和描述层面的知识，符合等级2的标准。" + }, + { + "idx": 1080, + "question": "Write all the crystal planes included in the {110} plane family of the cubic crystal system.", + "answer": "(110), (101), (011), (110), (101), (011).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举立方晶系中{110}晶面族包含的所有晶面，需要文字描述和具体列举，不涉及选择、判断或计算。 | 知识层次: 题目考查对立方晶系中{110}晶面族包含的所有晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目要求列出立方晶系{110}晶面族中包含的所有晶面，这只需要记忆立方晶系晶面族的对称性规则即可直接得出答案。不需要进行复杂的概念解释或分析，属于最基础的概念记忆性知识。" + }, + { + "idx": 1081, + "question": "Write all the crystal planes included in the {111} crystal plane family in the cubic crystal system.", + "answer": "(111), (1̄11), (11̄1), (111̄).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出立方晶系中{111}晶面族包含的所有晶面，答案需要列举具体的晶面指数，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目考查对立方晶系中{111}晶面族包含的所有晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需要回忆立方晶系中{111}晶面族包含的具体晶面。正确选项直接给出了所有可能的晶面组合，无需额外计算或推理步骤。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1083, + "question": "Write all the crystal planes included in the {123} crystal plane family of the cubic crystal system.", + "answer": "(123), (123), (123), (123), (132), (132), (132), (132), (213), (213), (213), (213), (231), (231), (231), (231), (312), (312), (312), (312), (321), (321), (321), (321).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中{123}晶面族包含的所有晶面，答案需要列出具体的晶面指数，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目考查对立方晶系中晶面族{123}包含的所有晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求记忆并列举立方晶系中{123}晶面族的所有晶面。虽然涉及多个晶面变体，但本质上仍属于基础概念记忆范畴，无需复杂分析或推导。相比等级1的简单定义问答，该题目需要更系统的记忆和分类能力，但未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 1084, + "question": "Are the shapes of the room-temperature tensile curves of low-carbon steel and aluminum alloy the same?", + "answer": "The shapes of the room-temperature tensile curves of low-carbon steel and aluminum alloy are not the same.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（低碳钢和铝合金的室温拉伸曲线形状是否相同），答案直接给出了明确的判断结果（不相同），符合判断题的特征。 | 知识层次: 题目考查对低合金钢和铝合金室温拉伸曲线形状差异的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目要求考生比较低碳钢和铝合金的室温拉伸曲线形状是否相同，这需要考生掌握两种材料的基本拉伸行为特征，属于对基础概念的对比理解。虽然需要记忆两种材料的特性，但不需要复杂的分析或推理过程，因此属于中等偏下的难度等级。" + }, + { + "idx": 1086, + "question": "For annealed low-carbon steel with a grain size of NA=16 grains/mm², its yield strength σs=100MPa; when NA=4096 grains/mm², σs=250MPa. Calculate the yield strength when NA=250 grains/mm².", + "answer": "According to the Hall-Petch formula: $\\sigma_{\\mathrm{s}}=\\sigma_{0}+K d^{-1/2}$. Since $N_{A}$ is inversely proportional to the square of the grain diameter $\\pmb{d}$, we have: Furthermore, it can be solved that $$\\begin{array}{c}{{\\displaystyle{\\sigma_{\\mathrm{s}}=100}{\\mathrm{MPa}}=\\sigma_{0}+K{d_{1}}^{-1/2}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=250}{\\mathrm{MPa}}=\\sigma_{0}+K{d_{2}}^{-1/2}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=\\sigma_{0}+K{d_{3}}^{-1/2}}}}\\ {{\\displaystyle{d_{2}}/d_{1}=1/16\\qquadd_{3}/d_{1}=4/5~\\sqrt{10}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=149}{\\mathrm{MPa}}}}\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和公式进行数值计算，最终得出一个具体的数值结果（149MPa），这符合计算题的特征。解答过程中需要应用Hall-Petch公式并进行多步计算推导。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸条件下的屈服强度计算，需要理解公式中各参数的关系并进行数值求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和数学计算技巧。 | 难度: 在选择题中属于中等难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和概念关联。虽然题目提供了部分计算步骤，但仍需要考生理解公式中各变量的关系，并能正确代入数值进行计算。此外，题目还涉及对晶粒尺寸与屈服强度关系的综合分析，增加了题目的复杂性。" + }, + { + "idx": 1087, + "question": "What are the characteristics of the room temperature tensile curve of low-carbon steel?", + "answer": "Low-carbon steel exhibits distinct upper and lower yield points due to the presence of Cottrell atmospheres.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释低碳钢室温拉伸曲线的特征，答案提供了文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释低碳钢室温拉伸曲线的特征，特别是上下屈服点的存在原因，这涉及到位错与间隙原子（Cottrell气团）相互作用的机理分析。需要综合运用材料力学性能、位错理论等知识进行推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1088, + "question": "Assuming carbon atoms are all located in the octahedral interstices of γ-Fe, at 1000°C, 1.7 weight percent of carbon atoms are dissolved in γ-Fe. Calculate how many carbon atoms are present in 100 unit cells and determine the proportion of octahedral interstices occupied by carbon atoms (the atomic weight of iron is 55.85, and the atomic weight of carbon is 12.01).", + "answer": "γ-Fe has a face-centered cubic structure, with 4 Fe atoms and 4 octahedral interstices per unit cell. Let the number of carbon atoms in one unit cell be $A$, then: Solving gives $A=0.32$ $$\\frac{100A\\times12.01}{100\\times4\\times55.85+100A\\times12.01}=1.7\\%$$ Thus, the number of carbon atoms in 100 unit cells is: $0.32\\times100=32$ The proportion of octahedral interstices occupied by C atoms: $$A/4=0.32/4=0.08=8\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程涉及单位换算、比例计算和百分比求解，最终需要得出具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解γ-Fe的面心立方结构、八面体间隙的位置和数量，以及碳原子在其中的溶解比例。同时，需要进行质量百分比和原子数量的转换计算，综合分析碳原子占据间隙的比例。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方结构、间隙位置、原子百分比与重量百分比转换等多个概念，并进行多步骤的综合计算。虽然题目提供了正确选项作为参考，但仍需要考生具备较强的概念关联能力和计算能力才能正确解答。" + }, + { + "idx": 1090, + "question": "Critical resolved shear stress", + "answer": "Critical resolved shear stress: When $\\sigma_{0}=\\sigma_{\\mathfrak{s}}$, the crystal begins to slip, and the resolved shear stress in the slip direction at this point is called the critical resolved shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Critical resolved shear stress\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查的是临界分切应力的定义和基本原理，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解和记忆临界分切应力的定义，即当$\\sigma_{0}=\\sigma_{\\mathfrak{s}}$时晶体开始滑移，此时滑移方向上的分切应力称为临界分切应力。虽然涉及一定的专业术语和公式符号，但整体上属于基础概念的记忆和理解范畴，不需要复杂的分析或比较步骤。因此，难度等级为2。" + }, + { + "idx": 1091, + "question": "What are the characteristics of the room temperature tensile curve of aluminum alloy?", + "answer": "Aluminum alloy does not exhibit a distinct yield point phenomenon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述铝合金室温拉伸曲线的特征，答案提供了文字解释而非选择或判断 | 知识层次: 题目考查对铝合金室温拉伸曲线特性的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对铝合金室温拉伸曲线特性的基础记忆性知识，正确选项直接给出了明确的特征描述（不表现明显屈服点现象），不需要进行概念解释或复杂分析。这属于最基本的概念记忆层次，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1095, + "question": "Cross-slip can enable multiple slip systems in crystals", + "answer": "Cross-slip is the process where a dislocation line transfers from one slip plane to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对交叉滑移现象进行解释，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对交叉滑移这一基本概念的定义和简单理解，属于基础概念记忆范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别交叉滑移的基本定义，属于基础概念记忆层次。题目直接给出了正确选项的定义，无需进行复杂的解释或分析，因此属于最简单的难度等级1。" + }, + { + "idx": 1096, + "question": "Interstitial solid solutions and interstitial compounds both belong to interstitial phases.", + "answer": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vector of the dislocation line, respectively. For a curved dislocation line, its Burgers vector remains constant, but the properties vary along different sections depending on the geometric relationship between the direction vector of the dislocation line and the Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对间隙固溶体和间隙化合物的概念进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体和间隙化合物的基本概念记忆，以及它们是否属于间隙相的分类理解。这属于基础概念的记忆和简单分类问题，不需要复杂的应用或分析。 | 难度: 在选择题中属于较高难度，题目涉及多个复杂概念（如Burgers向量、刃型位错、螺型位错、位错线方向向量等）的相互关系，并要求理解这些概念在不同几何条件下的变化规律。需要考生具备扎实的晶体缺陷理论基础和空间几何分析能力，属于需要综合运用多个知识点进行判断的题目类型。" + }, + { + "idx": 1097, + "question": "For metals or alloys without phase transformation in the solid state, their grain size cannot be changed unless remelted.", + "answer": "For metals or alloys without phase transformation in the solid state, their grain size can also be changed through plastic deformation and recrystallization treatment without remelting.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目陈述了一个观点，答案是对该观点的判断和修正，符合判断题的特征 | 知识层次: 题目涉及金属或合金的晶粒尺寸变化机制，需要理解塑性变形和再结晶处理对晶粒尺寸的影响，属于多概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。题目涉及金属或合金的晶粒尺寸变化机制，需要考生理解无固态相变材料的晶粒尺寸改变途径（塑性变形和再结晶处理），并能综合分析题目陈述的错误之处。这要求考生不仅掌握基础概念，还能进行多步骤的逻辑推理和判断，属于综合分析结果判断的难度等级。" + }, + { + "idx": 1098, + "question": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vectors of the dislocation lines, respectively, so a curved dislocation line has different properties.", + "answer": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vectors of the dislocation lines, respectively. For a curved dislocation line, its Burgers vector remains constant, but the properties vary along the line as the geometric relationship between the direction vector of the dislocation line and the Burgers vector changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对位错的性质进行文字解释和论述，答案提供了详细的描述和分析，符合简答题的特征。 | 知识层次: 题目涉及位错的基本概念（刃位错和螺位错的柏氏矢量方向）以及它们在曲线位错线上的变化，需要理解并应用这些概念来分析位错性质的变化。虽然知识点本身属于基础概念，但题目要求对不同位错类型在曲线位错线上的性质变化进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解位错的基本概念（刃位错和螺位错的柏氏矢量方向与位错线方向的关系），并能综合分析弯曲位错线上不同位置的性质变化。题目涉及多个概念的关联和比较，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 1099, + "question": "Calculate the planar density of the (100) plane in a face-centered cubic crystal, given the atomic radius r=(√2/4)a", + "answer": "For the (100) plane of a face-centered cubic crystal, there are 2 atoms. The planar density is calculated as: 2×π(√2/4 a)^2 / a^2 = 2π×1/8 = π/4 = 0.785", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了平面密度的计算和原子半径的代入，最终给出了具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即计算面心立方晶体(100)面的平面密度。虽然需要理解晶体结构和原子半径的关系，但整体上是一个直接套用公式的计算过程，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用平面密度的计算公式，但题目已经给出了原子半径与晶格常数的关系，且计算步骤较为直接，仅需套用公式并进行简单代数运算即可得出结果。相较于需要多个公式组合或复杂分析的题目，此题的解题步骤较为简单，属于选择题型中的中等偏低难度。" + }, + { + "idx": 1100, + "question": "Calculate the planar density of the (110) plane in a face-centered cubic crystal, given the atomic radius r=(√2/4)a", + "answer": "For the (110) plane of a face-centered cubic crystal, there are 2 atoms. The planar density is calculated as: 2×π(√2/4 a)^2 / (√2 a×a) = 2π×1/8 / √2 = √2/8 π = 0.56", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和公式推导，最终给出一个数值结果。 | 知识层次: 题目需要理解面心立方晶体结构、(110)平面的原子排列，并应用平面密度的计算公式。计算过程涉及多步推导和数值计算，需要将原子半径与晶格参数的关系（r=(√2/4)a）代入公式，并进行合理的数学运算。这超出了简单套用公式的范畴，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方晶体结构、(110)平面的原子排列、平面密度的计算公式，并进行多步数学运算。虽然题目提供了原子半径与晶格常数的关系，但解题过程涉及几何关系推导、面积计算和分数化简，步骤较为复杂，需要较强的综合分析能力。" + }, + { + "idx": 1101, + "question": "A metal test bar with a length of 20cm and a cross-sectional area of 4cm² is fixed at the upper end and subjected to a tensile force of 980N at the lower end. Find the angle θ at which the shear stress is maximum.", + "answer": "The angle θ at which the shear stress is maximum is 45°.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用来求解最大剪应力对应的角度θ，答案是一个具体的数值结果（45°），这符合计算题的特征。 | 知识层次: 题目涉及基本的应力计算和公式应用，需要理解剪切应力的概念并应用相关公式进行计算，但不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，需要应用基本的剪切应力公式，并进行简单的角度计算。虽然涉及公式应用，但步骤直接且不涉及多个公式的组合。" + }, + { + "idx": 1102, + "question": "Calculate the planar density of the (111) plane in a face-centered cubic crystal, given the atomic radius r=(√2/4)a", + "answer": "For the (111) plane of a face-centered cubic crystal, there are 2 atoms. The planar density is calculated as: 2π(√2/4 a)^2 / (1/2 √2 a×√2 a×sin60°) = 2π×1/8 / (√3/2) = π/(2√3) = 0.90", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出一个数值结果。 | 知识层次: 题目需要应用面心立方晶体的几何关系和平面密度的计算公式，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方晶体结构、(111)晶面的原子排布、平面密度计算公式等多个概念，并进行多步计算和综合分析。虽然题目提供了部分计算步骤，但仍需要较强的空间想象能力和数学计算能力才能正确解答。" + }, + { + "idx": 1103, + "question": "A metal test bar with a length of 20cm and a cross-sectional area of 4cm² is fixed at the upper end, and a tensile force of 980N is applied at the lower end. Calculate the normal stress and shear stress on a plane that forms a 0° angle with the central axis of the metal test bar.", + "answer": "When θ=0°: normal stress σθ=0; shear stress τθ=0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及计算法向应力和剪切应力。答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目要求进行基本的应力计算，直接应用公式即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算特定角度下的正应力和剪应力，直接套用基本公式即可得出结果，无需复杂推导或多步骤计算。正确选项直接给出了计算结果，考察的是对基本概念和公式的简单应用能力。" + }, + { + "idx": 1106, + "question": "A metal test bar with a length of 20cm and a cross-sectional area of 4cm² is fixed at the upper end and subjected to a tensile force of 980N at the lower end. Determine the general expressions for the normal stress and shear stress on a plane that forms an angle θ° with the central axis of the metal test bar.", + "answer": "Normal stress σθ=σsin²θ; shear stress τθ=(σ/2)sin2θ, where σ=P/A=980N/4cm²=2450000Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定金属测试棒在特定角度下的正应力和剪应力，答案给出了具体的计算公式和数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及应力公式的直接套用和数值计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解并应用两个公式（正应力和剪应力的表达式），但题目已经给出了明确的公式和计算步骤，且计算过程较为直接。因此，相对于仅需单一公式直接计算的题目，该题目难度稍高，但仍属于简单应用范畴。" + }, + { + "idx": 1107, + "question": "Indicate which plane among (100), (110), and (111) in a face-centered cubic crystal is the close-packed plane", + "answer": "The (111) plane has the highest packing density (0.90), so the close-packed plane in a face-centered cubic crystal is the (111) plane", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的平面选项（100）、（110）和（111）中选择一个密排面，属于从多个选项中选择正确答案的类型 | 知识层次: 题目考查对立方晶系中密排面的基本概念记忆，仅需识别(111)面为面心立方结构中的密排面，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆和理解面心立方晶体中不同晶面的堆垛密度，但题目直接给出了正确选项，且只需比较(100)、(110)、(111)三个晶面的堆垛密度即可得出答案。不需要复杂的分析或计算，属于基础概念理解和简单辨析的范畴。" + }, + { + "idx": 1108, + "question": "Interstitial compound", + "answer": "Interstitial compound: When small solute atoms such as C, H, O, N, etc. are distributed in the interstices of the solvent atomic structure, altering the crystal structure of the solvent atoms, and the composition can generally be represented by a chemical formula, such a phase is called an interstitial compound.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Interstitial compound\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对间隙化合物（interstitial compound）这一基本概念的定义和特征的理解和记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然题目涉及基础概念记忆，但正确选项提供了较为详细的定义和例子，需要考生对间隙化合物的定义和特征有一定的理解和记忆。相比于仅要求基本定义简答的等级1题目，该题目对知识点的掌握深度要求更高，但不需要进行复杂的概念体系阐述或比较分析。" + }, + { + "idx": 1109, + "question": "Number of atoms per unit cell", + "answer": "Number of atoms per unit cell: In the spatial structure of a crystal, a unit cell is adjacent to 26 other unit cells. Therefore, the atoms at the 8 corners, 12 edges, and 6 faces of the unit cell are shared with other unit cells, and only the atoms inside the unit cell entirely belong to this unit cell. The sum of the fractional contributions of the shared atoms and the actual number of atoms belonging to this unit cell is called the number of atoms per unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Number of atoms per unit cell”进行文字解释和论述，答案提供了详细的描述和解释，而不是选择、判断或计算。 | 知识层次: 题目考查晶体学中晶胞原子数的基本概念，主要涉及原子共享原理的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆晶体结构中单位晶胞内原子数的计算方法，包括共享原子的分数贡献和实际属于该晶胞的原子数。虽然涉及多个概念（如角、边、面共享原子的计算），但整体上属于基础概念的记忆和简单应用，不需要复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 1110, + "question": "Degree of supercooling", + "answer": "Degree of supercooling: Under rapid cooling conditions, when a metallic material cools to its melting point temperature, it does not solidify immediately but begins to solidify at a lower temperature. The difference between the actual solidification temperature and the melting point temperature is referred to as the degree of supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Degree of supercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对\"过冷度\"这一基本概念的定义和解释，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"degree of supercooling\"的定义，即实际凝固温度与熔点温度之间的差值。虽然需要理解基本概念，但并不涉及复杂的概念体系或需要进行比较分析。该题目主要考察对基础概念的记忆和理解，属于选择题型中的中等难度。" + }, + { + "idx": 1112, + "question": "The Burgers vector of edge dislocations and screw dislocations changes with the direction vector of the dislocation line.", + "answer": "Wrong! The Burgers vector of an edge dislocation is perpendicular to the direction vector of the dislocation line; the Burgers vector of a screw dislocation is parallel to the direction vector of the dislocation line.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个观点（The Burgers vector of edge dislocations and screw dislocations changes with the direction vector of the dislocation line），并要求判断其正确性。答案明确指出了该陈述是错误的，并给出了正确的解释。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对位错类型及其Burgers向量方向的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（位错的Burgers矢量方向），但需要考生理解并区分两种不同类型位错（刃型位错和螺型位错）的Burgers矢量与位错线方向的关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念陈述（等级3）的程度。" + }, + { + "idx": 1113, + "question": "Both austenite and pearlite are solid solutions of carbon in $\\alpha-\\mathrm{\\bfFe}$ with a body-centered cubic structure.", + "answer": "Wrong! Austenite is a solid solution of carbon in $\\gamma.$ -Fe with a face-centered cubic structure, while pearlite is a two-phase structure composed of ferrite and cementite.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Both austenite and pearlite are solid solutions of carbon in α-Fe with a body-centered cubic structure），要求判断其正确性。答案明确指出该陈述是错误的，并给出了正确的解释。这符合判断题的特征，即判断陈述的对错并给出解释。 | 知识层次: 题目考查对奥氏体和珠光体这两种材料的基本概念的记忆和理解，包括它们的晶体结构和组成。这属于基础概念记忆的范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解并区分奥氏体和珠光体的晶体结构及组成，但不需要复杂的分析或推理。" + }, + { + "idx": 1114, + "question": "Strain aging", + "answer": "Strain aging: After the first stretching, if a second stretching is performed immediately, the yield stage does not appear on the stress-strain curve. However, if the low-carbon steel specimen after the first stretching is left at room temperature for a period of time before the second stretching, the yield stage reappears on the stress-strain curve. Nevertheless, the yield strength upon re-yielding is higher than that during the initial yielding. This experimental phenomenon is called strain aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对\"Strain aging\"这一现象进行文字解释和论述，答案提供了详细的描述和定义，符合简答题的特征。 | 知识层次: 题目要求解释应变时效现象，涉及对材料力学行为变化的理解和实验现象的分析。需要将应变时效与低碳钢的应力-应变曲线特征联系起来，并解释不同条件下的行为差异。这属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解应变时效的概念及其对低碳钢应力-应变曲线的影响。题目涉及多个步骤的实验现象分析，包括初始拉伸、立即二次拉伸和室温放置后的二次拉伸，要求考生能够将这些现象与应变时效的概念关联起来。虽然不需要进行复杂的计算，但需要对材料科学中的基本概念有较好的掌握，并能综合分析不同条件下的实验结果。" + }, + { + "idx": 1115, + "question": "The diffusion of solute atoms always proceeds from regions of high concentration to regions of low concentration.", + "answer": "Wrong! The accurate statement is that the diffusion of solute atoms always proceeds from regions of high chemical potential to regions of low chemical potential. Only in this way can the driving force of reactive diffusion be satisfactorily explained.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性，答案明确指出该陈述是错误的并给出正确表述，符合判断题的特征。 | 知识层次: 题目不仅需要理解扩散的基本概念（从高浓度到低浓度），还需要理解化学势在扩散过程中的作用，这涉及到概念的关联和综合分析。虽然题目形式是判断题，但需要更深入的理解才能正确判断陈述的对错。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生掌握扩散的基本概念（从高浓度到低浓度），还需要理解更深入的化学势概念。正确选项涉及对扩散驱动力的本质理解（化学势梯度而非浓度梯度），并能解释反应扩散的驱动力机制。这需要考生将扩散理论与热力学概念进行综合关联分析，属于中等应用层次的多步概念判断。相比单纯记忆浓度梯度扩散的题目（难度2-3），本题需要更高层次的概念整合能力。" + }, + { + "idx": 1116, + "question": "Both martensitic transformation and bainitic transformation are diffusionless solid-state phase transformations.", + "answer": "Wrong! Martensitic transformation is a diffusionless solid-state phase transformation, while bainitic transformation involves both a diffusionless shear process and a diffusive atomic transport process, they are not the same.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Both martensitic transformation and bainitic transformation are diffusionless solid-state phase transformations），并要求判断其正确性（答案指出该陈述是错误的）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对马氏体相变和贝氏体相变这两种固态相变基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型内，该题目属于概念理解的对错判断难度等级。题目考察学生对马氏体相变和贝氏体相变的基本概念的理解，需要区分两种相变过程的差异。虽然涉及两个概念，但都属于基础概念记忆层次，解题步骤相对简单，只需判断陈述是否正确即可。因此属于等级2难度。" + }, + { + "idx": 1117, + "question": "In the iron-carbon phase diagram, the horizontal line where the eutectoid reaction occurs has two-phase regions both above and below it, which does not conform to the phase region contact rule.", + "answer": "Wrong! The horizontal line where the eutectoid reaction occurs in the iron-carbon phase diagram represents a three-phase equilibrium reaction, which is actually a three-phase region. Thus, the difference in the number of phases between the two-phase regions above and below the horizontal line is still 1, still conforming to the phase region contact rule.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个关于铁碳相图的观点，并要求判断其正确性。答案明确指出了该陈述是错误的，并给出了解释。这符合判断题的特征，即判断陈述的对错并给出理由。 | 知识层次: 题目考查对铁碳相图中共析反应水平线的基本概念的理解，涉及相区接触规则的应用，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察了对铁碳相图中共析反应水平线的理解，需要考生掌握相区接触规则的基本原理，并能够正确判断题目陈述的错误之处。虽然涉及多个概念，但主要考察的是对基础概念的理解和应用，解题步骤相对直接，不需要复杂的分析过程。" + }, + { + "idx": 1118, + "question": "In terms of the lattice constant, what is the atomic diameter in an FCC crystal structure?", + "answer": "The close-packed direction in an FCC structure is [110]. In the unit cell, there are two atoms along the [110] direction, so the atomic diameter is (√2/2)a.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释FCC晶体结构中原子直径的计算方法，答案需要文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目需要应用FCC晶体结构的基本知识，通过简单的几何关系计算原子直径。虽然涉及对晶体结构的理解，但计算过程直接且步骤简单，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于简单应用难度。题目直接考察对FCC晶体结构中原子直径的计算，只需掌握基本公式和简单计算步骤即可得出答案。解题过程仅需识别密排方向[110]并应用公式(√2/2)a，无需复杂分析或多步骤推理，符合选择题型中简单应用的标准。" + }, + { + "idx": 1119, + "question": "Why cannot the lever rule be used to analyze the relative amounts of phases in a vertical section of a ternary equilibrium phase diagram?", + "answer": "The vertical section of a ternary equilibrium phase diagram is a pseudo-binary phase diagram, and the composition points of the equilibrium phases cannot be determined on this vertical section. Therefore, the lever rule cannot be used to calculate the relative amounts of phases on the vertical section of a ternary equilibrium phase diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么杠杆定律不能用于分析三元平衡相图垂直截面中的相比例，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解三元平衡相图的垂直截面与伪二元相图的关系，并分析杠杆规则在此情境下的适用性限制。这涉及多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 1120, + "question": "Describe the characteristics of grain growth at temperatures of 760‰ and 870‰ and their engineering applications.", + "answer": "At 760‰ held for 1 hour, the grain size only grows to 0.0516mm. Comparing 0.0516mm with 0.05mm indicates that there is little change in this case, and the grains have basically not grown. However, at 870‰ held for 1 hour, the grain size grows to 0.069mm. Comparing 0.069mm with 0.05mm shows a 37% increase in grain size, indicating significant growth in this case. Therefore, when heating at relatively high temperatures, special attention must be paid to grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶粒生长的特性及其工程应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述晶粒生长在不同温度下的特性及其工程应用，涉及多步分析和概念关联。需要理解晶粒生长的基本原理，并能将实验结果与工程实践相结合，进行综合分析。虽然不涉及复杂的机理解释或创新设计，但需要一定的推理和分析能力。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解晶粒生长的基本概念，还需要对不同温度下的晶粒生长情况进行定量比较（0.0516mm vs 0.05mm和0.069mm vs 0.05mm），并分析其工程应用意义。这涉及多步计算、概念关联和综合分析能力，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 1121, + "question": "Phase", + "answer": "Phase: In alloys, a homogeneous component with the same state of aggregation, the same crystal structure, essentially the same composition, and clearly defined interfaces separating it from other parts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Phase\"这一概念进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"Phase\"这一基本概念的定义和特征的理解与记忆，属于材料科学中最基础的概念性知识，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆和识别\"Phase\"的基础定义，属于最基础的概念记忆层次。题目直接给出了明确的定义描述，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1122, + "question": "If the carbon content is 0.8% in high-carbon steel with an initial grain size of 0.05mm, calculate the grain size and its growth value after holding at 870‰ for 1 hour. The formula D^(1/n) - D0^(1/n) = c t can be used for calculation, where at 870‰, the constant c is 2×10^(-8), n is 0.2, D and D0 are grain sizes in mm, and t is time in min.", + "answer": "At 870‰ for 1h: D^(1/0.2) - D0^(1/0.2) = 2×10^(-8)×60; D^5 - D0^5 = 1.2×10^(-6); D^5 = 0.05^5 + 1.2×10^(-6) = 3.125×10^(-7) + 12×10^(-7) = 15.13×10^(-7); D = (15.13×10^(-7))^(1/5) mm = 0.069mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，以求解晶粒尺寸及其生长值。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解晶粒生长公式并正确代入数值进行计算，同时需要处理单位转换（小时到分钟）和指数运算。虽然计算过程较为直接，但涉及多个步骤和概念的综合应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算和公式应用，需要考生理解晶粒生长公式并正确代入数值进行计算。虽然题目提供了公式和常数，但计算过程较为复杂，包括指数运算和单位转换，对考生的计算能力和细节处理能力有一定要求。" + }, + { + "idx": 1123, + "question": "If the carbon content is 0.8% in high-carbon steel with an original grain size of 0.05mm, calculate the grain size and its growth value after holding at 760‰ for 1 hour. The formula D^(1/n) - D0^(1/n) = c t can be used for calculation, where at 760‰, the constant c is 6×10^(-16), n is 0.1, D and D0 are grain sizes in mm, and t is time in minutes.", + "answer": "Holding at 760‰ for 1h: D^(1/0.1) - D0^(1/0.1) = 6×10^(-16)×60; D^10 - D0^10 = 3.6×10^(-14); D^10 = 3.6×10^(-14) + D0^10 = 0.05^10 + 3.6×10^(-14) = 9.77×10^(-14) + 3.6×10^(-14) = 13.4×10^(-14); D = (13.4×10^(-14))^(1/10) = 5.16×10^(-2) mm = 0.0516mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，最终得出具体的数值结果（0.0516mm），这符合计算题的特征。解答过程涉及公式应用和数值运算，不需要选择或判断，也不需要文字论述。 | 知识层次: 题目需要进行多步计算，包括公式的代入和求解，涉及对晶粒生长公式的理解和应用。虽然计算过程较为直接，但需要一定的综合分析能力和对公式中各参数的理解。 | 难度: 在选择题中属于中等偏上难度，需要理解晶粒生长公式并正确代入数值进行多步计算。题目涉及指数运算和单位转换，要求考生具备综合应用公式和计算的能力。虽然提供了公式和常数，但计算步骤较多且需要精确处理小数值，属于综合性计算问题。" + }, + { + "idx": 1124, + "question": "Use the phase rule to explain why a ternary alloy can exhibit four-phase equilibrium", + "answer": "The phase rule formula is f=c-p+1, where f, c, p represent degrees of freedom, number of components, and number of phases, respectively. For a ternary alloy, when f reaches its minimum value of 0, the number of phases p is 4, indicating that four-phase equilibrium can occur. However, at this point, the degrees of freedom f is 0, meaning the compositions of all phases and the temperature are fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用相律解释三元合金可以呈现四相平衡的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求应用相律公式解释三元合金的四相平衡现象，涉及多步计算和概念关联，需要理解相律的基本原理并能够将其应用于具体情境。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力来理解自由度、组分和相数之间的关系。 | 难度: 在选择题中属于较高难度，需要理解相律公式并正确代入数值进行计算，同时需要解释自由度为零时的物理意义。题目涉及多步计算和概念关联，要求考生能够综合分析相律在多元合金中的应用。虽然题目提供了正确选项，但理解其背后的原理需要较深的知识掌握和逻辑推理能力。" + }, + { + "idx": 1125, + "question": "Why can the lever rule be used to analyze the relative content of each phase in the horizontal section of a ternary equilibrium phase diagram", + "answer": "On the horizontal section (i.e., the four-phase equilibrium plane) of a ternary equilibrium phase diagram, the composition of each phase and the temperature are all determined, so the lever rule can be used to analyze the relative content of each phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么杠杆定律可以用于分析三元平衡相图中水平截面上各相的相对含量，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解三元平衡相图中水平截面的特性，并应用杠杆规则来分析各相的相对含量。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解杠杆规则在三元平衡相图中的具体应用，并能够将多个概念（如四相平衡平面、相组成确定等）进行关联分析。虽然题目提供了正确选项，但考生仍需具备一定的综合分析能力才能准确理解并选择正确答案。" + }, + { + "idx": 1127, + "question": "Packing density", + "answer": "Packing density: It represents the ratio of the volume occupied by atoms in a unit cell to the volume of the unit cell, and is a parameter to measure the tightness of atomic arrangement. The higher the packing density, the tighter the atomic arrangement in the crystal, and the denser the crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Packing density\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对\"packing density\"的定义及其在晶体结构中的意义的解释。这属于基础概念记忆的范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对\"packing density\"的定义、计算方式及其在晶体结构中的意义有清晰的理解。题目不仅要求记忆定义，还需要理解这一参数如何反映原子排列的紧密程度，属于概念解释和描述的层次。相比简单定义简答（等级1），该题目需要更深入的概念掌握，但尚未达到复杂概念体系阐述（等级3）的程度。" + }, + { + "idx": 1128, + "question": "In terms of the lattice constant, what is the atomic diameter in the HCP crystal structure?", + "answer": "The close-packed direction in the HCP structure is [11 20], along which one atom is arranged, so the atomic diameter is a.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释HCP晶体结构中原子直径与晶格常数的关系，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查HCP晶体结构中原子直径的基本概念，仅需记忆和理解HCP结构中密排方向的定义和原子排列方式，无需复杂计算或综合分析。 | 难度: 该题目属于基础概念记忆类型，仅需记住HCP晶体结构中原子直径与晶格常数的关系即可作答。在选择题型中，这种直接考查定义和基本原理的题目属于最简单的等级1难度。" + }, + { + "idx": 1130, + "question": "In terms of lattice constant, what is the atomic diameter in a BCC crystal structure?", + "answer": "The close-packed direction in BCC structure is [111]. In the unit cell, there are two atoms along the [111] direction, so the atomic diameter is (√3/2)a.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定BCC晶体结构中的原子直径，涉及晶格常数和几何关系的数值计算，答案给出了具体的计算公式和结果。 | 知识层次: 题目需要理解BCC晶体结构的特点，识别密排方向[111]，并应用几何关系（√3/2）a进行多步计算，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构的基本概念，掌握[111]方向的原子排列方式，并进行多步计算（包括对角线长度计算和原子直径推导）。虽然不涉及复杂变量，但需要将晶体几何知识与数学计算相结合，属于综合性计算问题。" + }, + { + "idx": 1132, + "question": "The typical crystal structure types of metals are (1), (2), and (3). What are their names?", + "answer": "(1) fcc; (2) bcc; (3) hcp;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写金属的典型晶体结构类型名称，答案需要提供具体的结构名称（fcc, bcc, hcp），属于简答形式而非选择、判断或计算。 | 知识层次: 题目考查金属典型晶体结构类型的基本概念记忆，只需回忆并列举出常见的三种结构名称（fcc、bcc、hcp），不涉及应用、分析或综合等高阶认知能力。 | 难度: 在选择题型中，该题目仅要求记忆金属的三种典型晶体结构类型（fcc、bcc、hcp），属于基础概念记忆，无需解释或分析。解题步骤简单，只需直接回忆知识点即可选择正确答案，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 1134, + "question": "What is the movement of dislocations perpendicular to the slip plane called?", + "answer": "Climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字回答一个特定的概念（dislocation movement perpendicular to slip plane），答案是一个术语（Climb），不需要选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即位错运动中的\"攀移\"（climb）这一术语的定义。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即对\"dislocation movement perpendicular to the slip plane\"这一特定术语的定义记忆。题目直接询问专业术语名称，不涉及概念解释或复杂分析，属于最基本的知识点考察。" + }, + { + "idx": 1135, + "question": "According to the phase rule, what is the maximum number of equilibrium phases in a ternary system?", + "answer": "4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律回答三元系统中最大平衡相数，需要理解并应用相律知识进行简要回答，答案是一个具体的数值而非选择或判断。 | 知识层次: 题目考查对相律这一基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对相律基础定义的记忆，无需解释或分析，属于最基础的定义简答类型。" + }, + { + "idx": 1136, + "question": "Solid solution strengthening", + "answer": "Solid solution strengthening: When a solid solution is formed, the solvent lattice becomes distorted due to the dissolution of solute atoms. The stress field of the solute atoms interacts with dislocations, hindering their movement and increasing the resistance to dislocation motion. This results in a critical resolved shear stress much higher than that of pure metals, making the activation of slip systems more difficult compared to pure metals. Consequently, the material's resistance to plastic deformation increases, leading to higher hardness and strength, while plasticity and toughness decrease. This phenomenon is known as solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对“固溶强化”这一现象进行详细的文字解释和论述，答案提供了完整的定义、机制和影响，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及溶质原子与位错的相互作用、临界分切应力的变化以及对材料性能的影响等多个方面的综合分析。这需要深入理解材料科学中的位错理论和强化机制，并进行推理分析，属于复杂分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解固溶强化的基本概念，还需要深入掌握其微观机理（如晶格畸变、位错运动阻碍等），并能综合分析其对材料力学性能的影响（强度提高、塑性韧性下降）。这种需要同时运用材料科学原理和力学性能知识的综合分析题，在选择题型中属于最复杂的类型，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 1137, + "question": "According to the phase rule, what is the degree of freedom when the ternary system has the maximum number of equilibrium phases?", + "answer": "Zero", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律解释三元系统在最大平衡相数时的自由度，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对相律（phase rule）这一基本原理的记忆和理解，特别是关于自由度（degree of freedom）在特定条件下的直接应用。虽然涉及三元系统和最大平衡相数，但答案直接来源于相律的基本定义，不需要复杂的计算或综合分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接考察对相律基础概念的简单记忆，只需知道三元系统在最大平衡相数时的自由度为零即可选出正确选项，无需复杂推理或概念间的联系分析。" + }, + { + "idx": 1138, + "question": "What is the movement of dislocations on the slip plane called?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用简短的文字回答特定概念的定义或名称，不需要选择或判断，也不需要计算 | 知识层次: 题目考查的是对位错运动的基本概念的记忆和理解，即滑移的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题仅考察对\"滑移\"这一基础定义的单点记忆，不需要解释或比较其他概念。属于最基础的定义简答级别，符合等级1的简单记忆要求。" + }, + { + "idx": 1139, + "question": "According to the phase rule, what does the maximum number of equilibrium phases in a ternary system appear as on the phase diagram?", + "answer": "Plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释相律在三元系统中的表现，答案需要文字描述相图中的平面特征，而非选择、判断或计算。 | 知识层次: 题目考查对相律在多元系统中应用的基础概念记忆，仅需回忆三元系统相图中最大平衡相数对应的几何形状（平面），无需复杂推理或综合分析。 | 难度: 在选择题型中，该题目仅考察对相律基础定义的记忆，属于最基本的概念记忆题。学生只需知道三元系统中最大平衡相数在相图中的表现形式（平面）即可作答，无需任何解释或分析步骤。" + }, + { + "idx": 1140, + "question": "What kind of motion cannot be performed by a screw dislocation?", + "answer": "Climb", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案\"Climb\"是其中一个选项 | 知识层次: 题目考查对位错运动类型的基础概念记忆，特别是关于螺型位错不能进行的运动类型（攀移）这一基本知识点。 | 难度: 在选择题型中，该题目需要考生理解螺型位错的基本运动方式（滑移和攀移），并能够区分这两种运动的特点。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，因此属于等级2难度。" + }, + { + "idx": 1141, + "question": "The typical crystal structure types of metals are (1), (2), and (3), and what are their corresponding coordination numbers?", + "answer": "(4) 12; (5) 8; (6) 12;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的晶体结构类型和对应的配位数，需要文字解释和论述，而不是从选项中选择或判断对错。答案的形式也是填空式的简答形式。 | 知识层次: 题目考查金属典型晶体结构类型及其配位数的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求记忆金属的典型晶体结构类型及其对应的配位数，无需进行概念解释或复杂分析。正确选项直接对应记忆性知识点，解题步骤简单，属于基础概念记忆层次中最简单的类型。" + }, + { + "idx": 1142, + "question": "What is the slip plane of face-centered cubic metals?", + "answer": "{111}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的晶面指数{111}，属于需要特定知识点的简短回答，不需要计算或选择过程 | 知识层次: 题目考查面心立方金属滑移面的基本概念记忆，属于材料科学晶体结构的基础知识点，仅需直接回忆或理解{111}晶面族是FCC金属的滑移面这一事实即可回答。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别面心立方金属的滑移面{111}，属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接回忆定义性知识，因此属于最简单的难度等级1。" + }, + { + "idx": 1143, + "question": "What is the slip direction of face-centered cubic metals?", + "answer": "<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的晶体学方向（<110>），虽然答案简短，但需要理解面心立方金属的滑移方向知识，属于需要专业知识回答的简答题类型 | 知识层次: 题目考查面心立方金属滑移方向的基本概念记忆，属于材料科学晶体结构的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆面心立方金属的滑移方向这一基础定义，属于最基础的概念记忆层次。题目仅需识别正确选项<110>，无需解释或分析，解题步骤极其简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1144, + "question": "How many slip systems can be formed in face-centered cubic metals?", + "answer": "12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答面心立方金属中可以形成的滑移系统数量，答案是一个具体的数字（12），但需要基于对滑移系统的理解和计算得出，属于需要简要回答的问题。 | 知识层次: 题目考查面心立方金属滑移系统数量的记忆性知识，属于基础概念的记忆和理解层面，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目仅需记忆面心立方金属的滑移系统数量（12个），属于基础概念记忆，无需复杂推理或分析。题目直接考察定义性知识，解题步骤简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 1145, + "question": "The unit of diffusion flux is (24)", + "answer": "(24)1/cm2·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写扩散通量的单位，需要提供具体的单位名称，属于简答题类型 | 知识层次: 题目考查扩散通量的单位这一基础概念的记忆，属于定义性知识的直接回忆，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即扩散通量的单位。题目直接给出正确选项，无需任何解释或复杂推理，属于最简单的记忆性知识考查。" + }, + { + "idx": 1146, + "question": "The symbol for diffusion flux is (25), indicating that diffusion proceeds from high concentration to low concentration.", + "answer": "(25) negative sign", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个符号（negative sign）来解释扩散通量的符号意义，这需要学生对概念的理解并用简短的文字回答，而不是从选项中选择或进行判断/计算。 | 知识层次: 题目考查对扩散通量符号及其物理意义的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，此题仅要求记忆扩散通量的符号及其物理意义，属于最基础的定义性知识。题目直接给出概念定义，无需解释或分析过程，解题步骤非常简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1147, + "question": "The first law of diffusion applies to steady-state diffusion, and its mathematical expression can be written as (23).", + "answer": "(23) J=-Ddc/dx", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个数学表达式作为答案，属于需要简短回答的问题，而不是从选项中选择或进行复杂的计算或判断。 | 知识层次: 题目考查菲克第一定律的基本表达式，属于扩散理论中的基础概念记忆性知识，仅需记忆和理解即可回答。 | 难度: 在选择题型中，该题目仅要求记忆菲克第一定律的基本数学表达式，属于基础概念记忆层次。题目直接给出正确选项，无需进行复杂的概念解释或分析，因此难度等级为1。" + }, + { + "idx": 1148, + "question": "What is the conceptual difference in recrystallization?", + "answer": "Recrystallization refers to the transformation of a substance from one structure to another in the solid state, which is a solid-state phase transition process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对概念进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对再结晶这一基本概念的定义和简单解释，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于中等难度，题目要求考生理解并描述再结晶的概念差异，涉及对固态相变过程的基本原理的记忆和解释，但不需要复杂的分析或比较多个概念体系。" + }, + { + "idx": 1149, + "question": "What is the conceptual difference in crystallization?", + "answer": "Crystallization—The process by which a metal transitions from a liquid to a solid state is called solidification, and since the solid metal is a crystal, solidification is also referred to as crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释结晶的概念差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即结晶化的定义和基本原理，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目仅要求记忆基础概念的定义，即结晶与凝固的关系。题目直接给出了明确的定义描述，不需要进行额外的解释或复杂的概念分析。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1150, + "question": "What is constitutional supercooling?", + "answer": "During the solidification of a solid solution alloy, the distribution of solute in the liquid phase changes, which alters the alloy's melting point. Even if the actual temperature distribution remains unchanged, the degree of supercooling at the solid-liquid interface front will vary. Therefore, the supercooling of a solid solution alloy is determined by both the changing alloy melting point and the actual temperature distribution. This type of supercooling caused by changes in liquid phase composition is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"constitutional supercooling\"进行文字解释和论述，答案提供了详细的定义和形成机制说明，符合简答题的特征。 | 知识层次: 题目要求解释constitutional supercooling的机理，涉及固溶体合金凝固过程中溶质分布变化对熔点的影响，以及实际温度分布与合金熔点变化之间的相互作用。这需要综合运用材料科学中的凝固理论、相变原理和热力学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1151, + "question": "What effect does constitutional supercooling have on crystal growth morphology?", + "answer": "During the crystallization of solid solutions, constitutional supercooling significantly influences the morphology of crystal growth, leading to the formation of cellular structures or even dendritic crystals even under a positive temperature gradient. Specifically, without constitutional supercooling, the interface advances in a planar manner; with slight constitutional supercooling, the interface becomes cellular; and with substantial constitutional supercooling, the interface turns dendritic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释 constitutional supercooling 对晶体生长形态的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对constitutional supercooling对晶体生长形态影响的深入分析和解释，需要综合运用相关概念和机理，理解不同条件下的界面形态变化，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目涉及复杂的材料科学机理（成分过冷对晶体生长形貌的影响），要求考生不仅理解成分过冷的概念，还需要掌握其对晶体生长界面形貌（平面状→胞状→枝晶状）的渐进影响机制。正确选项包含三个层次的分析（无成分过冷、轻微成分过冷、显著成分过冷），需要综合运用相变动力学和扩散理论进行推理判断，完全符合\"复杂现象全面分析\"的知识层次要求。在选择题型中，这种需要多维度机理解释和现象分析的题目属于最难的类别。" + }, + { + "idx": 1152, + "question": "What are the differences and connections among crystallization, recrystallization, and grain growth?", + "answer": "The differences and connections among the three: Crystallization and recrystallization involve phase transformation processes, while grain growth does not; crystallization, recrystallization, and grain growth are all processes of nucleation and growth. The driving force for crystallization and recrystallization is the free energy difference between the reactant phase and the product phase, whereas for grain growth, it is the stored energy. After grain growth, strength and hardness decrease while ductility and toughness improve, whereas recrystallization involves allotropic transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述三个概念之间的区别和联系，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释和论述结晶、再结晶和晶粒生长之间的区别和联系，涉及多个概念的综合分析和关联，需要理解这些过程的驱动机制和结果，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度，因为它要求考生不仅理解结晶、再结晶和晶粒长大这三个独立概念，还需要进行多角度分析论述。具体来说，题目要求考生：" + }, + { + "idx": 1153, + "question": "Briefly describe the differences between solid solution alloys and pure metals during the crystallization process.", + "answer": "During crystallization, the interface of pure metals is rough and grows under a positive temperature gradient. Since heat is dissipated through the solid mold wall as the crystal grows, the solid-liquid interface is isothermal. If dynamic undercooling is achieved, the interface moves forward. If a small protrusion locally extends into the overheated liquid phase, it will be melted, and the interface remains straight, resulting in planar crystal growth. During solid solution crystallization, compositional undercooling occurs, creating a compositionally undercooled zone ahead of the solid-liquid interface. If any small protrusion extends into this undercooled zone, it will continue to grow due to the undercooling. The interface cannot remain straight and stable, leading to the formation of dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固溶体合金和纯金属在结晶过程中的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶体合金和纯金属在结晶过程中的差异，涉及动态过冷、成分过冷、界面稳定性等复杂概念，需要综合运用结晶学原理和材料科学知识进行机理分析和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生深入理解并比较纯金属和固溶体合金在结晶过程中的复杂现象，包括界面生长机制、温度梯度、成分过冷、枝晶形成等高级概念。正确选项不仅需要综合运用多个知识点，还需要进行机理层面的深度解释和推理分析。这种题目在选择题中属于对知识掌握深度和综合分析能力要求极高的类型，远超一般选择题的难度水平。" + }, + { + "idx": 1155, + "question": "Analyze the changes of vacancies and dislocations during the low-temperature recovery stage and their effects on properties", + "answer": "During the low-temperature recovery stage, the primary phenomenon is the disappearance of vacancies. The large number of vacancies generated after cold deformation are drastically reduced through various mechanisms, including vacancy migration to surfaces or grain boundaries, recombination of vacancies with interstitial atoms, interaction between vacancies and dislocations, and aggregation of vacancies into vacancy clusters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析低温回复阶段空位和位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析低温回复阶段空位和位错的变化及其对性能的影响，涉及多个机制的相互作用（空位迁移、复合、聚集等），需要综合运用材料科学知识进行推理分析和机理解释，思维过程深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1156, + "question": "Explain the reason why the strength is higher and the plasticity is better when the grain size is smaller during plastic deformation of polycrystalline metals.", + "answer": "The reason why the strength is higher and the plasticity is better when the grain size is smaller during plastic deformation of polycrystalline metals is as follows: Due to the fine grains, the slip planes available for dislocation pile-up in each grain are shorter, and the number of piled-up dislocations $_{n}$ is also smaller. The stress concentration caused by dislocation pile-up is small and dispersed, making it more difficult to activate dislocation sources in adjacent grains, thus resulting in higher yield strength. With fine and numerous grains, under the same external force, the number of grains in favorable slip orientations increases, allowing more grains to participate in slip. The slip amount is dispersed among various grains, and the stress concentration is small. This reduces the likelihood of cracking during metal deformation, enabling a larger plastic deformation before fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶金属塑性变形时晶粒尺寸较小导致强度和塑性提高的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多晶金属塑性变形中晶粒尺寸对强度和塑性的影响机制，涉及位错堆积、应力集中、滑移面等多个概念的关联和综合分析，需要深入理解材料变形机理并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对多晶金属塑性变形过程中晶粒尺寸对强度和塑性的影响进行全面的机理解释，涉及位错堆积、应力集中、滑移面等多个复杂概念的深入理解和综合运用。解题需要系统分析晶粒细化对位错运动、应力分布和变形均匀性的多重影响机制，并整合这些机制解释宏观力学性能的变化。这种深度机理分析和多因素耦合推理的要求，在选择题型中代表最高阶的认知复杂度。" + }, + { + "idx": 1157, + "question": "Analyze the changes of vacancies and dislocations during the medium-temperature recovery stage and their effects on properties", + "answer": "During the medium-temperature recovery stage, the increase in temperature facilitates the glide of dislocations. Dislocations with opposite signs on the same slip plane attract and annihilate each other, not only reducing the number of dislocations within subgrains but also significantly decreasing the tangled dislocations in cell walls. The rearrangement becomes more ordered, and the cell walls become clearer, forming recovered subgrains. This stage is primarily characterized by the glide of dislocations, leading to dislocation recombination, the annihilation of dislocations with opposite signs, and the growth of subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析中温回复阶段空位和位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析中温回复阶段空位和位错的变化及其对性能的影响，涉及位错的滑移、重组、湮灭以及亚晶的形成等复杂机理的解释和综合分析。需要深入理解材料科学中的位错理论和回复机制，并进行推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解中等温度回复阶段中空位和位错的变化及其对性能的影响机制。正确选项涉及多个复杂概念的综合运用，包括位错的滑移、相反符号位错的吸引与湮灭、亚晶粒的形成等。考生需要具备扎实的材料科学基础，能够将这些概念联系起来进行推理分析，并解释微观结构变化对宏观性能的影响。这种深度机理解释和复杂现象全面分析的要求，使得该题目在选择题型中属于最高难度等级。" + }, + { + "idx": 1158, + "question": "Analyze the changes of vacancies and dislocations during the high-temperature recovery stage and their effects on properties", + "answer": "During the high-temperature recovery stage, the kinetic conditions for dislocation motion are more sufficient, and slip is accompanied by climb, causing the dislocation densities on multiple slip planes to tend to equalize. The interactions between dislocations lead to a uniform distribution of dislocations on the same slip plane with roughly equal spacing, forming regularly arranged dislocation walls perpendicular to the slip plane, a process known as polygonization. The dislocation walls formed by polygonization constitute small-angle grain boundaries, which divide the original grains into several subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高温回复阶段空位和位错的变化及其对性能的影响，需要详细的文字解释和论述，答案也提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目要求分析高温回复阶段空位和位错的变化及其对性能的影响，涉及多个概念的关联和机理解释，需要综合运用材料科学知识进行推理分析，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用材料科学中的多个核心概念（如位错运动、攀移、多边形化、小角度晶界等），并深入理解高温回复阶段的微观机制及其对材料性能的影响。正确选项不仅涉及复杂现象的全面分析（位错密度均衡化、位错墙形成过程），还需要机理深度解释（多边形化如何形成亚晶结构）。这种题目在选择题型中需要考生具备高阶推理能力和对材料变形机制的透彻理解，远超简单记忆或基础概念应用的难度水平。" + }, + { + "idx": 1159, + "question": "Annealing", + "answer": "Annealing: A heat treatment process in which a metal or its alloy is heated above the phase transition temperature, held for a period of time, and then cooled at a relatively slow rate to obtain a nearly equilibrium microstructure is called annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Annealing\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对退火这一基本热处理工艺的定义和基本原理的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"Annealing\"的基本定义，属于最基础的概念记忆层次。题目描述直接给出了完整的定义，没有涉及复杂的概念体系或需要分析比较的内容，因此属于选择题型中最简单的难度等级。" + }, + { + "idx": 1161, + "question": "A cylindrical face-centered cubic single crystal with a diameter of 1mm has its tensile axis aligned with the [001] direction of the crystal. Determine its equivalent slip systems.", + "answer": "When the crystal is FCC and the force axis is in the [001] direction, among the 12 slip systems, the [110] crystal direction is perpendicular to the force axis, while the others have equal angles with the force axis, and 4 slip systems are also equivalent. Therefore, the equivalent slip systems are 8 in total. Specifically, they are (111)[101], (111)[011], (111)[101], (111)[011], (111)[10 1], (111)[011], (11 1)[011], and (11 1)[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定等效滑移系统，答案提供了详细的解释和具体的滑移系统列表，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求确定FCC单晶在特定拉伸轴方向下的等效滑移系统，需要理解FCC晶体的滑移系统特性，分析不同滑移方向与拉伸轴的几何关系，并进行分类和计数。这涉及多步概念关联和综合分析，但不需要复杂的机理推理或创新应用。 | 难度: 在选择题中属于较高难度，需要深入理解FCC晶体的滑移系统概念，并能正确分析[001]方向受力时的等效滑移系统。解题过程涉及多个步骤的综合分析，包括判断滑移方向与受力轴的几何关系、计算等效滑移系统数量等。此外，还需要准确识别并列举所有符合条件的滑移系统，对晶体学知识的掌握要求较高。" + }, + { + "idx": 1165, + "question": "Hardenability", + "answer": "Hardenability: refers to the tendency of steel to obtain martensite structure during quenching (i.e., the ability of steel to be hardened).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Hardenability\"进行定义和解释，需要文字论述，而不是选择、判断或计算。 | 知识层次: 题目考查对\"Hardenability\"这一基本概念的定义和记忆，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即对\"hardenability\"定义的直接回忆。题目仅要求识别正确选项中的定义描述，无需解释或分析复杂概念体系，属于最基本的概念识别题。选择题型中此类直接考察定义的题目通常属于最低难度等级。" + }, + { + "idx": 1167, + "question": "The typical crystal structure types of metals are (1), (2), and (3)", + "answer": "(1) FCC; (2) BCC; (3) HCP", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写典型的金属晶体结构类型，答案需要列举具体的结构名称（FCC, BCC, HCP），属于简答题的填空形式，不需要选择或判断，也不需要计算。 | 知识层次: 题目考查金属典型晶体结构类型的基础概念记忆，属于分类性知识，不需要复杂的应用或分析过程 | 难度: 在选择题型中，该题目仅要求记忆金属的典型晶体结构类型（FCC、BCC、HCP），属于基础概念记忆，无需解释或分析，解题步骤简单直接，符合等级1的基本定义简答标准。" + }, + { + "idx": 1168, + "question": "A cylindrical face-centered cubic single crystal with a diameter of 1mm has its tensile axis aligned with the [001] direction of the crystal. If the tensile force at yield is 0.5N, what is the resolved shear stress on the slip system?", + "answer": "Ω=cosλcosφ=√2/2×1/√3=√6/6 τ=P/AΩ=0.5/π(1/2)^2×√6/6MPa=0.26MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解剪切应力，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括晶体取向、滑移系统的确定、分切应力的计算等，涉及多个知识点的综合应用，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体学方向、剪切应力计算、多步骤数学运算等概念，并进行综合分析。虽然题目提供了正确选项，但解题过程涉及多个计算步骤和概念关联，对学生的知识掌握和计算能力要求较高。" + }, + { + "idx": 1169, + "question": "What type of solid solution is ferrite?", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述铁素体的固溶体类型，答案\"Interstitial\"是一个术语性的简短回答，属于需要专业知识解释的简答题类型 | 知识层次: 题目考查对铁素体类型的基本概念记忆，属于基础分类知识的直接回忆 | 难度: 该题目属于基础概念记忆类型，仅需识别铁素体（ferrite）属于间隙式固溶体（Interstitial）这一基本定义。选择题型中无需复杂推理或概念比较，属于最基础的定义简答级别。" + }, + { + "idx": 1170, + "question": "The typical coordination numbers for metal crystal structures should be (4), (5), and (6)", + "answer": "(4) 12; (5) 8; (6) 12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写典型的配位数，答案需要具体的数值而非选择或判断，且解答方式为直接填写数值，符合简答题的特征。 | 知识层次: 题目考查金属晶体结构中典型配位数的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆金属晶体结构的典型配位数即可作答。题目直接给出了正确选项，无需进行复杂的概念解释或比较分析，解题步骤简单明了，符合等级1的基本定义简答标准。" + }, + { + "idx": 1171, + "question": "Martensite is a supersaturated solid solution of carbon in what?", + "answer": "α-Fe", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的知识点（马氏体的组成），答案是一个简短的专业术语（α-Fe），不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查马氏体的基本定义和组成，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅需识别马氏体的基本定义（碳在α-Fe中的过饱和固溶体）。选择题型中仅需从选项中选出正确术语，无需解释或推理，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1172, + "question": "What type of solid solution is formed when the radius of solute atoms differs significantly from that of solvent atoms?", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述不同类型的固溶体形成条件，答案需要文字说明而非选择或判断 | 知识层次: 题目考查的是对固溶体类型的基本概念的记忆和理解，特别是当溶质原子半径与溶剂原子半径差异显著时形成的固溶体类型。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即固溶体的分类定义。学生只需记住当溶质原子半径与溶剂原子半径差异显著时形成间隙固溶体（Interstitial）这一基本事实即可作答，无需进行概念解释或复杂分析。" + }, + { + "idx": 1173, + "question": "What type of solid solution can be formed when the atomic radius of the solute is similar to that of the solvent?", + "answer": "Substitutional", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个具体的术语而非选择或判断 | 知识层次: 题目考查的是对固溶体类型的基础概念记忆和理解，特别是当溶质和溶剂原子半径相似时形成的置换型固溶体。这属于材料科学中的基本分类知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即对固溶体类型的定义和分类的记忆。题目直接询问当溶质和溶剂的原子半径相似时形成的固溶体类型，正确答案\"Substitutional\"是基础定义的一部分，无需复杂推理或概念间的比较分析。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1177, + "question": "What are the two metallographic morphologies of martensite in quenched steel?", + "answer": "Lath martensite and acicular martensite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举淬火钢中马氏体的两种金相形态，答案需要提供具体的文字描述而非选择或判断 | 知识层次: 题目考查马氏体在淬火钢中的两种金相形态的记忆，属于基础概念的分类和记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆马氏体的两种基本金相形态（板条马氏体和针状马氏体），属于最基础的定义性知识。题目不涉及概念解释或复杂体系阐述，仅需简单回忆即可作答，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1178, + "question": "The solid-liquid interface of crystals is divided into smooth interface and rough interface. According to the growth speed from slow to fast, the growth methods are (13), (14), and (15) in order.", + "answer": "(13) Two-dimensional nucleation growth; (14) Crystal defect growth; (15) Vertical growth", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的生长方法名称，需要文字解释和论述，而不是从选项中选择或进行数值计算 | 知识层次: 题目考查晶体生长方法的基本分类和顺序的记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生掌握晶体生长方式的分类和顺序。虽然需要记忆三种生长方式及其顺序，但不需要深入理解其背后的复杂机制或进行多概念比较分析。在选择题型中，这属于中等难度，介于简单定义回忆和复杂概念阐述之间。" + }, + { + "idx": 1179, + "question": "The two basic types of dislocations are (22) and (23)", + "answer": "(22) edge dislocation; (23) screw dislocation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个基本类型的位错名称，需要提供具体的术语作为答案，属于简答题类型。 | 知识层次: 题目考查对位错基本类型的记忆和理解，属于材料科学中最基础的概念性知识 | 难度: 在选择题型中，该题目仅要求考生记忆并区分两种基本的位错类型（刃型位错和螺型位错），属于最基础的定义简答。题目仅涉及单一知识点的直接回忆，无需解释或复杂推理步骤，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 1180, + "question": "During austenite nucleation, not only (10) fluctuations and (11) fluctuations are required, but also (12) fluctuations are needed", + "answer": "(10) structure; (11) energy; (12) composition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定的术语（structure, energy, composition）来完成句子，这需要学生对相关概念有准确的理解和记忆，属于简答题的范畴。虽然形式上类似于填空题，但更侧重于对知识点的简短回答而非选择或判断。 | 知识层次: 题目考查对奥氏体形核过程中所需波动类型的基础概念记忆，包括结构、能量和成分波动，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆奥氏体形核过程中所需的结构、能量和成分波动这三个基本定义。题目直接给出了正确选项，没有复杂的推理或分析步骤，因此属于最简单的难度等级。" + }, + { + "idx": 1181, + "question": "The relationship between the direction of the dislocation line of an edge dislocation and the Burgers vector is (24)", + "answer": "(24) perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答刃位错的位错线方向与伯格斯矢量之间的关系，答案需要简洁的文字描述（\"perpendicular\"），属于简答题类型。 | 知识层次: 题目考查刃型位错的位错线与伯格斯矢量方向关系的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即刃位错的位错线方向与伯格斯矢量之间的关系。题目直接给出正确选项\"perpendicular\"，无需复杂推理或概念比较，属于最基本的知识点回忆型题目。" + }, + { + "idx": 1182, + "question": "Ferritic stainless steel is (27)", + "answer": "(27) 1Cr17", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的材料牌号（1Cr17），属于需要简短文字回答的形式，没有提供选项或需要判断对错，也不涉及计算过程。 | 知识层次: 题目考查对铁素体不锈钢基本分类的记忆，仅需回答特定牌号1Cr17，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别Ferritic stainless steel的正确选项1Cr17，无需复杂推理或概念比较。在选择题型中，此类直接考察定义和分类的记忆性知识属于最低难度等级。" + }, + { + "idx": 1183, + "question": "The typical steel grade of martensitic stainless steel is (25）", + "answer": "（25）1Cr13", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的钢号（1Cr13），属于需要特定简短答案的题目，而非从多个选项中选择或判断对错，也不涉及计算过程。 | 知识层次: 题目考查对马氏体不锈钢典型钢号的记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆特定钢种的典型牌号（1Cr13），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或分析，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1184, + "question": "The typical steel grade of austenitic stainless steel is (26)", + "answer": "(26) 1Cr18Ni9Ti", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的钢号作为答案，而不是从多个选项中选择或判断对错，也不需要计算。答案形式是简短的文字回答。 | 知识层次: 题目考查对奥氏体不锈钢典型钢号的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆典型的奥氏体不锈钢牌号1Cr18Ni9Ti，属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或复杂分析，因此难度最低。" + }, + { + "idx": 1185, + "question": "Uphill diffusion refers to the diffusion of atoms from (28) to (29). The reason for uphill diffusion is the existence of (30) in the alloy system.", + "answer": "(28) low concentration; (29) high concentration; (30) chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的术语或概念（低浓度、高浓度、化学势梯度），而不是从选项中选择或判断对错，也不需要计算。答案形式为简短的文字填空，符合简答题的特征。 | 知识层次: 题目考查对\"uphill diffusion\"这一基础概念的记忆和理解，包括其定义（从低浓度向高浓度扩散）和原因（化学势梯度的存在）。不涉及复杂分析或综合应用，仅需基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解“uphill diffusion”的定义及其背后的原因（化学势梯度）。解题步骤相对简单，只需根据记忆选择正确的选项，但需要对相关概念有一定的理解和记忆。相较于等级1的纯定义简答，该题目需要更深入的概念解释和描述。" + }, + { + "idx": 1187, + "question": "Discuss the characteristics exhibited by pure metals during the solidification process and explain the reasons?", + "answer": "During crystallization, the interface of a pure metal is rough and grows under a positive temperature gradient. Since heat is dissipated through the solid mold wall as the crystal grows, the solid-liquid interface remains isothermal. If a dynamic undercooling is achieved, the interface advances forward. If a small protrusion locally extends into the overheated liquid phase, it will be melted, keeping the interface straight, and the crystal grows in a planar manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论纯金属在凝固过程中表现出的特性并解释原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论纯金属在凝固过程中的特性并解释原因，涉及对结晶过程中界面形态、温度梯度、动态过冷等复杂现象的综合分析和机理解释，需要较高的认知能力和深度理解。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对纯金属凝固过程中的界面特性、温度梯度、动态过冷等复杂现象进行全面分析，并解释晶体生长的平面方式。这需要综合运用材料科学中的多个高级概念，进行深入的机理推理和解释。选择题型中通常不涉及如此复杂的分析过程，因此该题目在选择题型内属于极难级别。" + }, + { + "idx": 1188, + "question": "Discuss the characteristics exhibited by solid solution alloys during the solidification process and explain the reasons?", + "answer": "During the crystallization of a solid solution, constitutional supercooling occurs, leading to the formation of a constitutionally supercooled zone ahead of the solid-liquid interface. If any small protrusion appears on the interface, it will extend into the constitutionally supercooled zone and continue to grow by obtaining supercooling. As a result, the interface cannot remain flat and stable, leading to the formation of dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论固溶体合金在凝固过程中的特性并解释原因，需要详细的文字解释和论述，符合简答题的特征。答案也提供了详细的解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求讨论固溶体合金在凝固过程中的特性并解释原因，涉及对凝固过程中成分过冷、固液界面稳定性以及枝晶形成机理的深入理解和分析。这需要综合运用材料科学中的相变理论、热力学和动力学知识，进行推理和解释，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解固溶体合金凝固过程中的复杂现象（如成分过冷、枝晶形成机理），并需要综合运用材料科学原理进行机理解释。正确选项涉及多步骤推理分析（从界面不稳定到枝晶形成的完整因果链），且需要掌握\"成分过冷区\"等专业概念之间的相互作用机制。这种在选择题中要求对复杂凝固现象进行全面机理分析的题目，远超过基础识记或简单应用层面，属于选择题型中最具挑战性的类型。" + }, + { + "idx": 1189, + "question": "What is the main difference between the first type and the second type of temper brittleness?", + "answer": "The first type of temper brittleness is irreversible, while the second type is reversible. The first type of temper brittleness is caused by the precipitation of discontinuous thin-shell carbides along the interfaces of martensite laths or plates during martensite decomposition. The second type of temper brittleness is caused by the segregation of impurity elements such as Sb, Sn, P, and As to the original austenite grain boundaries during tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种回火脆性的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种回火脆性的主要区别，涉及不可逆与可逆性的对比、微观机理分析（碳化物析出和杂质元素偏聚）、以及材料相变过程的综合理解。这需要深入掌握材料科学中的相变理论和缺陷机制，属于对复杂现象的机理分析和综合运用。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1190, + "question": "What is the first type of temper brittleness?", + "answer": "The brittleness that occurs during tempering between 250~400°C is called low-temperature temper brittleness, also known as the first type of temper brittleness. The first type of temper brittleness is irreversible temper brittleness, which is caused by the discontinuous thin-shell-like carbides precipitated along the interface of martensite laths or plates during martensite decomposition, reducing the fracture strength of grain boundaries and making them the path for crack propagation, thus leading to brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是第一种回火脆性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对第一类回火脆性的定义和基本机理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项不仅需要考生知道第一类回火脆性的温度范围（250~400°C），还需要理解其不可逆性以及微观机制（碳化物析出导致晶界强度降低）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1191, + "question": "How to solve the difficulties caused by work hardening in subsequent processing?", + "answer": "Recrystallization annealing can be used to eliminate the difficulties caused by work hardening in subsequent processing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何解决加工硬化带来的困难，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目涉及工作硬化的后续处理问题，需要理解工作硬化的概念及其影响，并应用再结晶退火这一解决方案。这需要多步思维过程，包括识别问题、理解再结晶退火的作用机制，并将其应用于具体情境中。虽然不涉及复杂的计算或深度机理分析，但需要对相关概念进行关联和综合应用。 | 难度: 在选择题中属于中等难度，题目涉及工作硬化和再结晶退火的概念关联，需要考生理解材料加工过程中的微观结构变化及其对后续加工的影响。虽然题目给出了正确选项，但考生仍需掌握工作硬化的基本原理和再结晶退火的作用机制，才能准确选择答案。这要求一定的综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1192, + "question": "What is the second type of temper brittleness?", + "answer": "The brittleness that occurs during tempering between 450~650℃ is called high-temperature temper brittleness, also known as the second type of temper brittleness. The second type of temper brittleness is reversible. The main reason for its occurrence is that impurity elements such as Sb, Sn, P, and As segregate to the original austenite grain boundaries during tempering, weakening the atomic bonding force at the austenite grain boundaries and reducing the grain boundary fracture strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释第二类回火脆性的定义和原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对第二类回火脆性的定义、发生温度范围、可逆性以及主要原因等基本概念的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解第二类回火脆性的定义、温度范围、可逆性以及产生原因等多个知识点。正确选项提供了较为详细的解释，考生需要将这些信息整合并选择正确的描述。相比于仅需记忆简单定义的等级1题目，该题目对概念的理解和描述要求更高，但尚未达到需要阐述复杂概念体系的等级3难度。" + }, + { + "idx": 1193, + "question": "Analyze the changes of vacancies during the low-temperature recovery stage and their impact on properties", + "answer": "During the low-temperature recovery stage, the main manifestation is the disappearance of vacancies. The large number of vacancies generated after cold deformation are drastically reduced through mechanisms such as vacancies migrating to surfaces or grain boundaries, recombination of vacancies with interstitial atoms, interaction of vacancies with dislocations, and aggregation of vacancies into vacancy clusters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析低温回复阶段空位的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析低温回复阶段空位的变化及其对性能的影响，涉及空位迁移、重组、与位错相互作用以及聚集等复杂机制的解释和综合分析，需要深入理解材料科学中的缺陷行为及其对材料性能的影响，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1194, + "question": "The typical crystal structures of metals are (1), (2), and (3)", + "answer": "(1) body-centered cubic; (2) face-centered cubic; (3) close-packed hexagonal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写金属的典型晶体结构名称，答案需要以文字形式提供具体结构名称，属于简答题类型 | 知识层次: 题目考查金属典型晶体结构的基础概念记忆，仅需回忆和列举三种常见结构类型，不涉及应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅需回忆金属的三种典型晶体结构名称（体心立方、面心立方和密排六方）。在选择题型中，这种直接考察定义或分类的记忆性知识属于最低难度等级，无需解释或分析步骤。" + }, + { + "idx": 1195, + "question": "Analyze the changes in dislocations during the high-temperature recovery stage and their impact on properties", + "answer": "During the high-temperature recovery stage, the kinetic conditions for dislocation motion are more sufficient, involving both slip and climb, which leads to a tendency for the dislocation densities on multiple slip planes to become equal. The interactions between dislocations cause the dislocations on the same slip plane to distribute uniformly with roughly equal spacing, forming regularly arranged dislocation walls perpendicular to the slip plane, a process known as polygonization. The dislocation walls formed by polygonization are small-angle grain boundaries, which divide the original grain into several subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高温回复阶段位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高温回复阶段位错的变化及其对性能的影响，涉及位错运动、多边形化过程、小角度晶界形成等多个复杂概念的综合运用和机理解释，需要深入理解和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解高温回复阶段位错运动的动力学条件（滑移和攀移），并分析其对多滑移面位错密度均衡化的影响。需要掌握位错相互作用导致的均匀分布机制，以及多边形化形成小角度晶界的完整过程。这些内容涉及复杂现象的综合分析和机理深度解释，远超一般选择题的概念识别层面，需要考生具备将多个高阶概念整合推理的能力。" + }, + { + "idx": 1196, + "question": "In homogeneous nucleation, assuming the nucleus shape is a cube with side length a, given σ and ΔGv, find the critical nucleus side length", + "answer": "The critical nucleus side length is (-4σ)/ΔGv", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（σ和ΔGv）进行计算，以找到临界核边长，答案是一个具体的数值表达式（(-4σ)/ΔGv），这符合计算题的特征。 | 知识层次: 题目要求应用基本公式（临界核尺寸与界面能和体积自由能变化的关系）进行直接计算，属于基本公式应用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，无需多个步骤或复杂理解。正确选项直接给出了公式应用的结果，属于最基础的难度等级。" + }, + { + "idx": 1197, + "question": "Analyze the changes in dislocations during the medium-temperature recovery stage and their impact on properties", + "answer": "During the medium-temperature recovery stage, the increase in temperature facilitates the glide of dislocations. Dislocations of opposite signs on the same slip plane attract and annihilate each other, not only reducing the number of dislocations within the subgrains but also significantly decreasing the tangled dislocations in the cell walls. This leads to a rearrangement into a more regular configuration, resulting in clearer cell walls and the formation of recovery subgrains. In this stage, the primary phenomena are the glide of dislocations, leading to their recombination, the annihilation of dislocations of opposite signs, and the growth of subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错在中温回复阶段的变化及其对性能的影响，需要详细的文字解释和论述，答案也呈现了详细的解释过程，符合简答题的特征。 | 知识层次: 题目要求分析位错在中温回复阶段的变化及其对性能的影响，涉及位错的运动、重组、湮灭以及亚晶的形成等复杂机理的解释和综合分析。这需要深入理解位错理论，并能将多个概念关联起来进行推理分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解位错在中等温度回复阶段的变化机制，包括位错的滑移、重组、相反符号位错的湮灭以及亚晶粒的形成等复杂现象。此外，还需要综合运用材料科学知识，分析这些变化对材料性能的影响。这种题目不仅考察了考生对基础概念的掌握，还要求他们能够进行机理深度解释和复杂现象全面分析，因此在选择题型中属于最高难度等级。" + }, + { + "idx": 1198, + "question": "What kind of motion can an edge dislocation undergo?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释边缘位错可以进行的运动类型，答案需要文字描述（\"Slip\"），属于需要简要文字解释的简答题类型。 | 知识层次: 题目考查位错运动类型的基础概念记忆，仅需回答\"滑移\"这一基本定义，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基本定义（edge dislocation的运动方式）的记忆，属于最基础的概念性知识，无需复杂分析或推理步骤。正确选项\"Slip\"是位错运动的标准术语，直接对应教材中的基础定义，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1199, + "question": "What other motion can an edge dislocation undergo?", + "answer": "Climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的概念或现象（edge dislocation的运动方式），答案是一个简短的术语（Climb），不需要计算或从多个选项中选择，属于简答题类型。 | 知识层次: 题目考查对位错运动类型的基础概念记忆，特别是边缘位错的攀移运动，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别边缘位错（edge dislocation）的另一种运动方式——攀移（climb）。这属于基础概念记忆层次，无需解释或分析，只需从选项中选出正确术语。因此，在选择题型内属于最低难度等级（等级1）。" + }, + { + "idx": 1200, + "question": "When a copper single crystal is stretched, if the force axis is in the [001] direction and the critical resolved shear stress is 0.64 MPa, what tensile stress is required to initiate slip in the crystal?", + "answer": "Since copper is face-centered cubic, the slip plane is {111} and the slip direction is <110>. Given that the force axis is [001], the four slip directions [110] and [1-10] are excluded, leaving eight equivalent slip systems. γ = 45°. cosλ = cos45° = √2/2. cosφ = |1×0 + 1×0 + 1×0| / (√(1² + 1² + 1²) × √(0² + 0² + 1²)) = √3/3. The formula is σ = τ / Ω = 0.64 / (cosλ cosφ) = 1.57 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的拉伸应力，解答过程中涉及到了临界分切应力、滑移面和滑移方向的计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括确定滑移系统、计算取向因子（cosλ和cosφ），并应用临界分切应力公式。虽然涉及的概念和公式是基础的，但需要综合运用多个知识点并进行适当的数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、滑移系统和临界分切应力等概念，并进行多步骤计算和综合分析。虽然题目提供了部分关键信息，但解题过程涉及多个计算步骤和概念关联，对学生的知识掌握和计算能力要求较高。" + }, + { + "idx": 1201, + "question": "What kind of motion can a screw dislocation undergo?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺丝位错可以进行的运动类型，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对位错运动类型的基础概念记忆，仅需回答\"滑移\"这一基本定义，无需深入分析或综合应用。 | 难度: 该题目属于基础概念记忆类型，仅需考生回忆并识别\"螺旋位错\"的基本运动方式。在选择题型中，这种直接考查定义或分类的题目属于最简单的等级1难度，不需要解释或分析过程。" + }, + { + "idx": 1202, + "question": "Why can screw dislocations only undergo glide motion?", + "answer": "Because it does not have a fixed half-atom plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么螺型位错只能进行滑移运动，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要解释螺位错只能进行滑移运动的机理，涉及位错的基本性质、运动方式及其与晶体结构的关系。这要求对位错理论有较深入的理解，并能进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生理解并解释螺型位错只能进行滑移运动的机理，这需要深入掌握位错的基本概念和运动机制。正确选项涉及对位错结构中半原子面的理解，这属于复杂分析层次的知识点。此外，题目要求考生能够将抽象的理论知识与具体现象联系起来，进行推理分析，这在选择题型中属于较高层次的认知要求。因此，该题目在选择题型内应评为等级4难度。" + }, + { + "idx": 1203, + "question": "The corresponding number of atoms per unit cell is (4), (5), and (6)", + "answer": "(4) 2; (5) 4; (6) 6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写对应的数值答案，而不是从选项中选择或进行判断，也不需要复杂的计算过程。答案形式为简短的数值回答，符合简答题的特征。 | 知识层次: 题目考查的是对单位晶胞中原子数量的记忆，属于基础概念的记忆性知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于基础概念记忆的范畴，仅需直接回忆单位晶胞中原子的对应数量。题目提供了明确的选项和正确答案，无需复杂推理或概念间的关联分析，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1204, + "question": "During the crystallization of a solid solution, nucleation requires both (13) fluctuations and (14) fluctuations, as well as (15) fluctuations.", + "answer": "(13) structure; (14) energy; (15) composition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定的关键词（structure, energy, composition）来完成句子，而不是从给定的选项中选择或进行判断、计算。这种形式更接近于简答题，需要考生回忆或理解相关概念来填写空白。 | 知识层次: 题目考查对结晶过程中成核所需波动类型的基本概念记忆，包括结构、能量和成分波动，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生同时掌握结构、能量和成分三个方面的波动在结晶成核过程中的作用。这比单纯记忆一个定义或概念（等级1）要复杂一些，但不需要进行复杂的分析或推理（等级3）。考生需要理解这三个波动的基本概念及其在结晶过程中的重要性，但不需要深入阐述或应用这些概念。" + }, + { + "idx": 1205, + "question": "In homogeneous nucleation, assuming the nucleus shape is a cube with side length a, given σ and ΔGv, find the critical nucleation work", + "answer": "The critical nucleation work is 32σ³/ΔGv²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（σ和ΔGv）和公式计算临界成核功，答案是一个具体的数值表达式（32σ³/ΔGv²），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解均相成核的基本原理，应用临界成核功的公式，并进行适当的代数运算。虽然计算过程不算复杂，但需要将几何形状（立方体）与表面能和体积自由能变化关联起来，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解均匀成核理论中的临界成核功概念，并能正确应用立方体几何关系（表面积与体积计算）。题目要求将界面能σ和体积自由能变化ΔGv进行关联，并完成多步推导计算（包括求导求极值等步骤）。虽然选择题提供了正确选项，但考生仍需具备综合分析能力才能确认答案的正确性，这超过了简单概念识别的层次。" + }, + { + "idx": 1206, + "question": "The characteristics of polycrystalline plastic deformation are (18)ity, (19)ity, and (20)ity.", + "answer": "(18) non-simultaneous; (19) coordinated; (20) non-uniform", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定的单词或短语来完成句子，而不是从给定的选项中选择或进行判断。答案需要根据知识储备来填写，属于简答题的范畴。 | 知识层次: 题目考查对多晶塑性变形特性的基础概念记忆，仅需回忆并填写三个特征词汇，无需深入分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆，但需要考生准确回忆并匹配三个不同的特性（非同时性、协调性和非均匀性），这比单纯记忆一个定义或概念要复杂一些。此外，题目采用了填空题的形式，增加了对记忆准确性的要求。不过，由于选项已经给出，考生不需要进行复杂的推理或分析，因此难度仍属于中等水平。" + }, + { + "idx": 1207, + "question": "When a crystal undergoes tensile slip, the slip plane is driven to rotate, attempting to align parallel to the (16), while the slip direction also rotates to coincide with the (17) direction.", + "answer": "(16) direction of the force axis; (17) maximum resolved shear stress", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求填写特定术语或概念来完成句子，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目涉及晶体滑移过程中滑移面和滑移方向的旋转行为，需要理解滑移机制与外力方向及最大分切应力方向的关系。这需要将基础概念（滑移面、滑移方向、分切应力）进行关联分析，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解晶体滑移过程中的力学行为，并关联滑移面和滑移方向的旋转机制。题目涉及对力轴方向和最大分解剪应力方向的概念理解，要求考生能够综合分析滑移系统的响应。虽然不涉及复杂计算，但需要对材料力学行为有较深的理解。" + }, + { + "idx": 1208, + "question": "Burgers vector", + "answer": "Burgers vector: A physical quantity used to describe the lattice distortion caused by dislocations. The magnitude of this vector represents the strength of the dislocation, indicating the total extent of lattice distortion, while its direction represents the direction of lattice point distortion. Generally, the larger this vector is, the greater the degree of crystal distortion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Burgers vector进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查Burgers vector的基本定义、物理意义和基本特性，属于基础概念的记忆和理解范畴，不涉及复杂应用或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆Burgers vector的定义、物理意义及其在描述位错引起的晶格畸变中的作用。虽然涉及多个概念（如晶格畸变、位错强度等），但整体上仍属于基础概念的记忆和解释范畴，不需要复杂的分析或比较步骤。因此，难度等级为2。" + }, + { + "idx": 1210, + "question": "What is the equilibrium distribution coefficient?", + "answer": "Equilibrium distribution coefficient: During the crystallization of solid solution alloys, selective crystallization occurs. Therefore, under equilibrium conditions at a certain temperature, the ratio of the solid phase composition to the liquid phase composition is called the equilibrium distribution coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"equilibrium distribution coefficient\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即平衡分布系数的定义和基本原理，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"平衡分配系数\"的定义，即在一定温度下固相组成与液相组成的比值。虽然涉及专业术语，但只需直接回忆定义内容，无需进行复杂的概念体系阐述或比较分析。在选择题型内，这属于中等偏下的难度，主要考察基础概念的记忆能力。" + }, + { + "idx": 1211, + "question": "What is the physical meaning of the equilibrium partition coefficient?", + "answer": "This parameter reflects the partition coefficient of solute between solid and liquid phases and the degree of influence of solute on the alloy's melting point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释平衡分配系数的物理意义，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查平衡分配系数的物理意义这一基本概念的理解和记忆，属于定义和基本原理的范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项不仅要求考生知道平衡分配系数的定义，还需要理解其在材料科学中的具体物理意义，即溶质在固相和液相之间的分配情况以及对合金熔点的影响。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1215, + "question": "Why is carburization chosen in γ-Fe around 930‰, where the diffusion coefficient increases with carbon content?", + "answer": "In γ-Fe, the diffusion coefficient increases with carbon content", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在γ-Fe中930‰温度下选择渗碳处理，并说明扩散系数随碳含量增加的原因。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求解释为什么在γ-Fe中碳含量增加时扩散系数增加，并选择930‰作为渗碳温度。这需要深入理解扩散机制、碳在γ-Fe中的行为以及温度对扩散的影响，涉及多个概念的关联和综合分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1216, + "question": "Why can a larger concentration gradient be formed in γ-Fe near 930‰ during carburization?", + "answer": "A larger concentration gradient can be formed", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在特定条件下可以形成更大的浓度梯度，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要解释在特定温度下γ-Fe中碳浓度梯度形成的机理，涉及扩散理论、相变和温度对扩散系数的影响等多方面知识的综合运用和推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解γ-Fe在特定温度下的晶体结构特性，还需要综合运用扩散动力学、相变原理和浓度梯度形成机制等知识进行复杂分析。正确选项涉及对碳原子扩散行为的机理深度解释，需要考生能够将多个高级概念联系起来进行推理，这远超出简单记忆或基础理解的范畴。在选择题型内，这种需要全面分析复杂现象并作出机理解释的题目属于最难的一类。" + }, + { + "idx": 1217, + "question": "Why does metal slip occur on the closest-packed planes and directions?", + "answer": "The slip in metal crystals occurs on the closest-packed planes and directions under external force because the atomic spacing is the smallest and the bonding force is the strongest on these planes, while the distance between two adjacent closest-packed planes is the largest and the bonding force is the weakest. It can be inferred that the resistance to slip is the smallest between the closest-packed atomic planes, requiring the least external force. Therefore, the closest-packed atomic planes and directions become the slip planes and slip directions for crystal slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属滑移发生在最密排面和方向的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属滑移发生在最密排面和方向的原因，涉及原子间距、键合力以及滑移阻力的综合分析。这需要深入理解晶体结构和滑移机制，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解金属晶体滑移的微观机制，包括原子间距、键合力与滑移阻力之间的关系，并能综合运用这些知识进行推理分析。正确选项不仅需要识别最密排面和方向的特征，还要解释为什么这些特定平面和方向成为滑移的首选路径，涉及复杂现象的全面分析。这种题目超越了简单记忆或单一概念应用，要求考生具备机理深度解释和综合推理能力。" + }, + { + "idx": 1218, + "question": "Why is carburization performed in γ-Fe around 930‰, where the diffusion coefficient increases with temperature at high temperatures?", + "answer": "At high temperatures, the diffusion coefficient increases with temperature, so high temperatures are chosen. However, excessively high temperatures can cause significant grain growth in austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在特定温度下进行渗碳处理，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及扩散系数与温度关系的机理解释，以及晶粒生长的综合分析，需要结合多个知识点进行推理和分析，思维深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1219, + "question": "Dislocations belong to crystal defects and also to line defects.", + "answer": "~\\\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案使用了判断题常见的符号（√）表示正确。 | 知识层次: 题目考查对晶体缺陷分类的基本概念记忆，属于定义和分类的基础知识层次。 | 难度: 在选择题型中，该题目属于非常基础的概念正误判断。题目仅要求考生记忆并识别位错（dislocations）属于晶体缺陷和线缺陷这一基本分类知识，不需要进行任何概念理解或复杂分析。这种类型的题目只需要考生对基础定义和分类有简单的记忆即可正确回答，因此属于难度等级1。" + }, + { + "idx": 1220, + "question": "Peritectic transformation refers to the transformation in which a liquid phase interacts with a solid phase, enveloping the original solid phase to form another new solid phase.", + "answer": "~\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（包晶转变的定义），并要求判断其正确性（答案标记为正确符号~\\surd~），这符合判断题的特征 | 知识层次: 题目考查对包晶转变（Peritectic transformation）这一基本概念的记忆和理解，属于定义性知识的判断，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接给出了包晶转变的定义，要求判断其正确性。这种题目只需要学生对基础概念有记忆即可作答，不需要深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1221, + "question": "Materials with different crystal lattices have different slip systems, thus their tendency to deform also varies.", + "answer": "~\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案以对错符号（~\\surd~）给出，符合判断题的特征 | 知识层次: 题目考查晶体结构和滑移系统的基本概念，属于基础概念的记忆和理解层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求识别晶体结构与变形倾向之间的基本关系，属于基础概念记忆层次，无需深入理解或分析多个概念。解题步骤简单，只需判断陈述的正确性。" + }, + { + "idx": 1222, + "question": "The higher the dislocation density, the larger the Burgers vector of the corresponding dislocation.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案以\"~\\\\times~\"形式给出，表示错误判断，这是典型的判断题特征 | 知识层次: 题目考查对位错密度和伯格斯矢量之间关系的基本概念的理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆并判断位错密度与伯格斯矢量之间的基本关系是否正确。题目陈述简单直接，不需要复杂的理解或分析过程，在选择题型中属于最基本的难度等级。" + }, + { + "idx": 1223, + "question": "Generally, the higher the activation energy for atomic diffusion in a crystal, the larger the diffusion coefficient and the faster the diffusion rate.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（\"Generally, the higher the activation energy for atomic diffusion in a crystal, the larger the diffusion coefficient and the faster the diffusion rate.\"），并要求判断其正确性（答案标记为~\\\\times~表示错误）。这是典型的判断题形式，不需要计算或解释，只需判断陈述的对错。 | 知识层次: 题目考查对原子扩散基本概念的理解，即激活能与扩散系数之间的关系，属于基础概念的记忆和理解层面。 | 难度: 该题目属于基础概念正误判断，仅需记忆激活能与扩散系数之间的关系即可作答，无需复杂推理或概念比较。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1224, + "question": "Stacking faults result from the local presence of an extra half atomic plane in the crystal lattice.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案形式为判断符号（~\\\\times~表示错误），符合判断题的特征 | 知识层次: 题目考查堆垛层错的基本概念，属于晶体缺陷的基础知识，主要依赖记忆和理解。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于堆垛缺陷的定义是否正确。在选择题型中，这类题目仅涉及单一概念的正误判断，无需深入理解或分析，因此属于最低难度等级。" + }, + { + "idx": 1225, + "question": "Metal solidification occurs through two processes: nucleation of the solid phase and grain growth. During the grain growth process, the liquid-solid interface of pure metals (such as Fe, Ni, Cu, Au, etc.) generally remains smooth.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（金属凝固过程中纯金属的液固界面通常保持平滑），并要求判断其正确性（答案给出的是×，表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查金属凝固过程中晶粒生长和液固界面形态的基础概念记忆，属于对基本原理的记忆性知识 | 难度: 该题目属于基础概念记忆层次，仅需判断关于金属凝固过程中液固界面形态的基本陈述是否正确。题目涉及的知识点较为简单，属于纯记忆性内容，无需深入理解或分析多个概念。在选择题型中，此类正误判断题通常属于最低难度等级。" + }, + { + "idx": 1226, + "question": "Non-equilibrium crystallization refers to the crystallization of an alloy under actual cooling conditions where the cooling rate is relatively high, deviating from equilibrium conditions. Under non-equilibrium conditions, the composition of the newly formed solid solution after a homogeneous transformation is inhomogeneous.", + "answer": "~\\\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（答案用对勾符号表示正确） | 知识层次: 题目考查非平衡结晶的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 该题目属于基础概念正误判断题，仅需识别非平衡结晶的定义特征即可作答。题目直接给出定义性描述，无需推理或分析，属于选择题型中最简单的难度等级。" + }, + { + "idx": 1227, + "question": "What is the essential difference between recrystallization and secondary recrystallization?", + "answer": "Recrystallization refers to the process in which a cold-worked metal is heated to a certain temperature, and new distortion-free equiaxed grains are regenerated within the deformed structure, restoring the properties to the softened state before cold working. Secondary recrystallization refers to the phenomenon where, after recrystallization annealing, the metal is held at a higher temperature or for a longer time, causing a very few grains to rapidly consume other grains and grow, resulting in the entire metal being composed of a few exceptionally large grains that are tens to hundreds of times larger than those after recrystallization. The essential difference between the two: Recrystallization is a process of nucleation and growth, while secondary recrystallization is only a growth process. The driving force for recrystallization is stored energy, whereas for secondary recrystallization, it is interfacial energy. After recrystallization, strength and hardness decrease while plasticity and toughness increase, whereas after secondary recrystallization, the material's strength, plasticity, and toughness all decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述recrystallization和secondary recrystallization之间的本质区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释和论述再结晶和二次再结晶的本质区别，涉及多个概念的理解和关联，包括过程描述、驱动力分析以及性能变化等。虽然不涉及复杂的计算或深度推理，但需要对相关概念进行综合分析和比较，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解再结晶和二次再结晶的基本概念，还需要掌握两者在本质上的区别，包括过程、驱动力以及材料性能的变化。这需要考生具备较强的概念关联能力和综合分析能力，能够从多个角度进行比较和论述。此外，题目中的正确选项包含了多个关键点，考生需要准确理解并区分这些细节，这增加了题目的复杂性和难度。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 1228, + "question": "Due to the varying degrees of tightness in the regular arrangement of atoms in different directions, the spacing between atoms and the bonding forces between them differ, resulting in different properties in different directions. Therefore, most metals and alloys also exhibit anisotropic characteristics.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个关于金属和合金各向异性特征的事实，答案以对错符号(~\\\\times~)的形式给出，符合判断题的特征。 | 知识层次: 题目考查对金属和各向异性特性的基本概念的理解和记忆，不涉及复杂的应用或分析。 | 难度: 该题目属于基础概念记忆层次，考察学生对金属和合金各向异性特性的理解。虽然涉及多个概念（原子排列紧密度、原子间距、键合力），但只需判断\"大多数金属和合金也表现出各向异性特性\"这一陈述的正确性，不需要进行复杂的概念比较或分析。在选择题型中，这属于需要理解概念但对错判断相对直接的中等难度题目。" + }, + { + "idx": 1229, + "question": "Iron-carbon alloy equilibrium phase diagram: (1) Contains peritectic transformation. (2) Contains eutectic transformation. (3) Contains congruent transformation. (4) Contains monotectic transformation. (5) Contains precipitation transformation of solid solution.", + "answer": "(1)(2)(3)(5)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的陈述组合，符合选择题的特征 | 知识层次: 题目考查对铁碳合金平衡相图中不同类型转变的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题中属于较高难度，需要深入理解铁碳合金相图中的多种相变类型（包晶、共晶、同成分、析出等），并能准确区分和识别这些概念。题目要求考生不仅记忆相变类型，还需辨析不同相变的特征及其在相图中的表现，涉及多个知识点的综合应用。" + }, + { + "idx": 1230, + "question": "Solid-state diffusion: (1) The diffusion of iron atoms in steel belongs to self-diffusion and is unrelated to the concentration gradient. (2) The diffusion of alloying elements in steel belongs to hetero-diffusion; in the absence of a chemical gradient, it is related to the concentration gradient. (3) The first law of diffusion is only applicable to steady-state diffusion conditions, hence it cannot be used to accurately determine the diffusion coefficient of carbon during the carburization process of steel. (4) Up-hill diffusion is solely related to the chemical gradient of the diffusing element and is unrelated to the concentration gradient. (5) The multiplication of dislocations is achieved through the diffusion movement of atoms.", + "answer": "(1)(4)(5)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出多个陈述，要求判断哪些陈述是正确的（即(1)(4)(5)），这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目主要考查对固体扩散基本概念的记忆和理解，如自扩散、异扩散、扩散定律的适用条件等，不涉及复杂的计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。题目涉及多个扩散相关的基础概念（如自扩散、异扩散、上坡扩散等），需要考生不仅记忆这些定义，还要理解它们在不同条件下的应用和相互关系。虽然题目提供了明确的判断点（1）（4）（5），但需要考生对扩散机制有较好的理解才能准确判断每个陈述的正确性。题目不涉及复杂的计算或推导，但需要对基础概念有清晰的认识和区分能力。" + }, + { + "idx": 1231, + "question": "Steel with a carbon content below the composition of point $S$ in the Fe-C phase diagram cannot obtain a completely pearlitic structure under any composition or condition.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目给出一个陈述（Steel with a carbon content below the composition of point $S$ in the Fe-C phase diagram cannot obtain a completely pearlitic structure under any composition or condition），并要求判断其正确性（答案用~\\\\times~表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目需要理解Fe-C相图中点S的含义，并能够分析不同碳含量下钢的组织转变能力，涉及相图知识的应用和综合分析能力。 | 难度: 在选择题中属于较高难度，需要综合分析Fe-C相图中关键点S的含义，理解珠光体形成的条件限制，并判断不同碳含量下的相变可能性。题目涉及多步概念关联和相图分析能力，要求考生在选择题框架内进行复杂的结果判断。" + }, + { + "idx": 1232, + "question": "Austenite in steel: \\n\\n(1) Can be represented as a $\\upgamma$-solid solution with dissolved carbon atoms. \\n\\n(2) Can be represented as an $\\alpha$-solid solution with dissolved carbon atoms. \\n(3) Exhibits good plasticity both at room temperature and high temperatures. \\n(4) Has ferromagnetism. \\n(5) Has paramagnetism.", + "answer": "(1) (3)(5)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的陈述，答案形式为选择特定编号的选项，符合选择题的特征 | 知识层次: 题目考查对奥氏体（Austenite）基本特性的记忆和理解，包括其晶体结构（γ-固溶体）、磁性（顺磁性）和塑性等基础概念，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目需要考生理解奥氏体的基本定义和特性，包括其晶体结构（γ-固溶体）、塑性行为以及磁性特征。虽然涉及多个概念，但这些都属于基础概念记忆层次，且选项之间有明显的区分度，不需要复杂的推理或深度分析。因此，难度属于等级2，即概念理解和简单辨析。" + }, + { + "idx": 1234, + "question": "Fracture characteristics of metals: (1) One form of brittle fracture is transgranular cleavage. (2) Cleavage fractures mainly exhibit river patterns. (3) The propagation direction of micro-cracks can be determined by the flow direction of the rivers, i.e., the convergence direction of the rivers indicates the crack propagation direction. (4) Some materials exhibit tongue patterns in their ductile fracture surfaces. (5) Ductile fractures mainly manifest as intergranular dimple fracture forms.", + "answer": "(2) (3) (5)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出了一系列陈述，要求判断哪些陈述是正确的（即选择正确的陈述作为答案）。这种形式符合判断题的特征，即从多个陈述中识别出正确的部分。 | 知识层次: 题目考查金属断裂特征的基础概念记忆，包括脆性断裂和韧性断裂的形貌特征及其判断依据，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个关于金属断裂特性的陈述，但主要考察的是对基础概念的理解和判断。正确选项(2)、(3)、(5)需要考生能够区分脆性断裂和韧性断裂的特征，并理解河流花样和舌状花样等微观形貌的含义。虽然涉及多个概念，但都属于基础概念记忆层次，不需要复杂的分析或推理。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 1235, + "question": "The typical coordination numbers for metal crystal structure types are (4), (5), and (6)", + "answer": "(4) 12; (5) 8; (6) 12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值答案，而不是从给定的选项中选择或判断对错，也不需要复杂的计算过程，属于需要直接回答的简答题类型。 | 知识层次: 题目考查金属晶体结构中配位数的基本概念记忆，属于基础知识的直接回忆和简单理解，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆金属晶体结构的典型配位数，无需进行概念解释或复杂分析。正确选项直接对应基础概念记忆，解题步骤简单明了，属于最基础的选择题难度。" + }, + { + "idx": 1236, + "question": "In polycrystals, grain boundaries are classified into large-angle and small-angle grain boundaries. What is the meaning of the angle?", + "answer": "The misorientation between adjacent grains", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“angle”的含义进行文字解释和论述，答案是一个简短的文字描述，而非选择、判断或计算。 | 知识层次: 题目考查对晶界角度定义的基本概念记忆和理解，属于材料科学中的基础知识点。 | 难度: 在选择题型中，该题目仅考察对基本定义的记忆，即\"晶界角度\"的含义。正确选项直接给出了定义（相邻晶粒之间的取向差），无需任何解释或推理步骤。这属于最基础的概念记忆题，符合等级1的简单定义要求。" + }, + { + "idx": 1237, + "question": "What are the types of small-angle grain boundaries classified according to their characteristics?", + "answer": "Twist, tilt, and coincidence", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举小角度晶界的类型，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对小角度晶界分类的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆小角度晶界的分类类型（Twist, tilt, and coincidence），属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接回忆定义性知识即可作答，因此属于最低难度等级。" + }, + { + "idx": 1238, + "question": "In polycrystals, grain boundaries are divided into large-angle and small-angle grain boundaries. What is the typical identification angle for distinguishing between large-angle and small-angle grain boundaries?", + "answer": "10°", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的角度值（10°），属于简短的直接回答，不需要选择、判断或计算过程。 | 知识层次: 题目考查对晶界分类的基本概念的记忆，即大角度晶界和小角度晶界的区分标准，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即区分大角度和小角度晶界的典型识别角度。题目直接给出定义性知识，无需复杂推理或概念间的关联分析，属于最基础的定义简答类型。" + }, + { + "idx": 1239, + "question": "When an embryo appears in an undercooled liquid, what can the total free energy change ΔG be written as?", + "answer": "ΔG=VΔGV+σS", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出总自由能变化的表达式，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查的是对过冷液体中胚胎出现时总自由能变化公式的记忆和理解，属于基础概念的记忆性知识，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即自由能变化的基本表达式。正确选项直接给出了公式形式，无需解释或推导，属于最基础的定义简答级别。题目仅要求考生识别并选择正确的公式表达，不涉及任何分析或复杂推理过程。" + }, + { + "idx": 1240, + "question": "What does the size of the critical nucleus radius depend on?", + "answer": "ΔGV and σ", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释临界核半径大小取决于哪些因素，答案需要提供文字说明（ΔGV and σ），而不是选择、判断或计算。 | 知识层次: 题目考查临界核半径大小的基本概念，仅需记忆和理解ΔGV（体积自由能变化）和σ（表面能）这两个基本参数对临界核半径的影响，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅考察对临界核半径尺寸依赖因素的基础定义记忆（ΔGV和σ），属于最基本的概念性知识，不需要解释或分析过程，符合等级1的简单记忆要求。" + }, + { + "idx": 1241, + "question": "When dΔG/dr=0, what is the obtained 'r' value called?", + "answer": "Critical nucleus radius", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述特定概念（临界核半径），不需要计算或选择选项 | 知识层次: 题目考查对临界核半径这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"Critical nucleus radius\"这一基础定义的记忆，不需要解释或复杂分析，属于最基本的概念记忆题。" + }, + { + "idx": 1242, + "question": "What does a decrease in 'r' imply about the nucleation rate?", + "answer": "Increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"r\"减小对形核速率的影响，需要文字说明其关系，答案\"increase\"是对问题的简要回答而非选择或判断 | 知识层次: 题目考查对成核速率与参数'r'关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即对'nucleation rate'与'r'关系的定义性知识。正确选项直接对应基本定义，无需复杂推理或概念整合，属于最简单的记忆性题目类型。" + }, + { + "idx": 1243, + "question": "According to the phase rule, what is the maximum number of equilibrium phases in a binary system?", + "answer": "17", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相规则回答二元系统中平衡相的最大数量，需要理论知识的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对相律这一基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对相律基础定义的记忆，无需解释或分析。学生只需回忆\"二元系统中最大平衡相数\"这一基本概念即可直接选择正确答案，属于最基础的定义简答类型。" + }, + { + "idx": 1244, + "question": "According to the phase rule, what is the degree of freedom when the number of equilibrium phases in a binary system is at its maximum?", + "answer": "18", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律计算二元系统中平衡相数最大时的自由度，需要应用公式进行数值计算，答案是一个具体的数值(18)，符合计算题的特征。 | 知识层次: 题目考查相律公式的直接应用，仅需将二元系统的最大平衡相数代入公式进行简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于最简单难度等级。题目直接考察对相律公式（F = C - P + 2）的简单套用，在二元系统中最大平衡相数时（P=3），只需将数值代入公式即可得出自由度F=1。不需要任何额外的推导或复杂计算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 1245, + "question": "What is the movement of an edge dislocation on the slip plane called?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用简短的文字回答特定概念（edge dislocation的运动名称），不需要选择、判断或计算 | 知识层次: 题目考查的是对位错运动基本概念的记忆和理解，即边缘位错在滑移面上的运动称为滑移。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"edge dislocation运动\"这一基础概念的定义记忆，属于最基础的知识点。题目直接询问专业术语\"slip\"，不需要任何解释或分析步骤，完全符合等级1\"基本定义简答\"的标准。在选择题难度谱系中，这是最简单的题型，只需识别标准术语即可作答。" + }, + { + "idx": 1246, + "question": "According to the phase rule, what is the maximum number of equilibrium phases in a binary system represented on the phase diagram?", + "answer": "19", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目涉及相律的应用和数值计算，需要根据相律公式（F = C - P + 2）进行计算得出最大平衡相数，答案是一个具体数值（19），属于计算题特征。 | 知识层次: 题目考查对相律公式的直接应用，需要简单的数值计算，属于基本公式应用和简单计算范畴。虽然涉及相律这一基础概念，但主要考察的是对公式的理解和直接套用能力，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目直接考察对相律公式（F = C - P + 2）的简单应用，只需将二元系统条件（C=2）代入公式并计算最大相数（F=0时）。解题过程仅需一步公式代入和基本算术运算，完全符合等级1\"单一公式直接计算\"的标准。选择题型中这种直接套用基础公式的题目属于最基础难度。" + }, + { + "idx": 1247, + "question": "What is the movement of an edge dislocation perpendicular to the slip plane called?", + "answer": "Climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用一个特定的术语（\"Climb\"）来回答问题，而不是从多个选项中选择或判断对错，也不需要计算或公式应用。这符合简答题的特征，即需要简洁准确的回答。 | 知识层次: 题目考查对位错运动基本概念的记忆和理解，特别是边缘位错在垂直于滑移面方向上的运动名称。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即边缘位错垂直于滑移面运动的名称。正确选项\"Climb\"是材料科学中的基本术语，属于直接的定义性知识，无需复杂推理或概念关联。选择题型中此类直接考查定义的题目属于最低难度等级。" + }, + { + "idx": 1249, + "question": "What are the usual slip planes for face-centered cubic metals?", + "answer": "{111}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答面心立方金属的常见滑移面，答案形式为简短的文本（{111}），不需要选择、判断或计算 | 知识层次: 题目考查面心立方金属常见滑移面的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆面心立方金属的常见滑移面{111}，属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接回忆单一知识点即可作答，因此属于最简单的难度等级1。" + }, + { + "idx": 1252, + "question": "Under what conditions is the first law of diffusion only applicable?", + "answer": "Steady state", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释在什么条件下第一扩散定律适用，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对扩散第一定律适用条件的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察对扩散第一定律适用条件的基础定义记忆，属于最基础的概念性知识。正确选项\"Steady state\"是直接来自定义的关键词，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1253, + "question": "What is the relationship between diffusion flux and concentration gradient?", + "answer": "Proportional", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散通量与浓度梯度之间的关系，答案需要文字表述而非选择或判断 | 知识层次: 题目考查扩散通量与浓度梯度之间关系的基本概念记忆，属于材料科学中扩散现象的基础知识，仅需记忆和理解即可回答。 | 难度: 在选择题型中，该题目仅要求记忆基础概念（扩散通量与浓度梯度的关系），属于最简单的定义性知识。正确选项\"Proportional\"直接对应菲克第一定律的基本表述，无需任何推导或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1254, + "question": "What is the basic condition expressed by the first law of diffusion?", + "answer": "dc/dt=0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散第一定律的基本条件，需要用文字表述答案，而给出的答案\"dc/dt=0\"是对该条件的数学表达，属于简答形式。 | 知识层次: 题目考查扩散第一定律的基本条件，属于基本原理的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对扩散第一定律基本条件的记忆，属于最基础的定义性知识。正确选项\"dc/dt=0\"直接对应定律表述，无需任何解释或推理步骤，完全符合等级1\"基本定义简答\"的标准。这是选择题中最简单的类型，仅需识别标准定义即可作答。" + }, + { + "idx": 1255, + "question": "What is the direction of diffusion flow from what concentration to what concentration?", + "answer": "From high concentration to low concentration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释扩散流动的方向，答案是一个简短的文字描述而非选择、判断或计算 | 知识层次: 题目考查扩散方向的基本概念记忆，仅需理解从高浓度到低浓度的基本原理，无需复杂分析或应用。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即扩散流动的方向是从高浓度到低浓度。这属于最基本的知识点掌握，无需复杂的理解或分析步骤，仅需简单回忆定义即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1257, + "question": "What is annealing twin? Explain its formation mechanism.", + "answer": "Annealing twin is a type of twin, which refers to the formation of lamellar twins with straight interfaces inside grains after cold deformation and recrystallization annealing in certain face-centered cubic metals, such as Cu, Ni, nickel alloys, and austenitic steels. These twin interfaces are on the {111} planes. Since they appear only after annealing, they are called annealing twins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"annealing twin\"的定义和形成机制，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的描述性回答，符合简答题的特征。 | 知识层次: 题目考查对\"退火孪晶\"这一基本概念的定义及其形成机制的记忆和理解，属于材料科学中的基础概念性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生不仅知道\"annealing twin\"的基本定义，还需要理解其形成机制和典型材料。这属于概念解释和描述的层次，比单纯记忆定义（等级1）要求更高，但不需要复杂的概念体系阐述（等级3）。题目给出了完整的正确选项，考生需要识别和匹配这些关键信息点。" + }, + { + "idx": 1258, + "question": "What is the kinking mechanism in the analysis of the mechanisms and manifestations of plastic deformation in materials?", + "answer": "When a crystal can neither slip nor undergo twinning, it can undergo plastic deformation through kinking. Its characteristic is that the orientation of the kinked crystal undergoes asymmetric changes. The dislocation mechanism refers to the process where, during plastic deformation, edge dislocations of the same sign accumulate in other regions due to dislocation motion. The convergence of dislocations generates bending stress, causing the crystal lattice to bend and kink, thereby forming a kinked region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释kinking机制在材料塑性变形中的作用和表现，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释塑性变形中的kinking机制，涉及位错运动、应力分布和晶体取向变化等多个复杂概念的综合分析，需要深入理解并关联多个知识点进行推理和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解晶体塑性变形的复杂机制，包括滑移、孪生和扭折等变形方式的区别，以及位错运动、积累和应力产生的详细过程。正确选项不仅需要识别扭折变形的特征，还需要解释位错机制如何导致晶格弯曲和扭折区域的形成。这要求考生具备综合运用材料科学知识、进行推理分析和机理解释的能力，属于复杂现象的全面分析层次。" + }, + { + "idx": 1260, + "question": "What is the slip mechanism in the analysis of the mechanisms and manifestations of plastic deformation in materials?", + "answer": "Slip is the relative movement of a crystal along the slip direction on the slip plane under the action of shear stress. Its dislocation mechanism is as follows: Due to the periodicity of the crystal lattice structure, when a dislocation moves along the slip plane, the energy at the dislocation center also undergoes periodic changes, causing the dislocation movement to encounter lattice resistance. However, in actual crystals, at a certain temperature, when the dislocation line moves from an energy valley position to an adjacent energy valley position, it does not simultaneously overcome the energy peak along its entire length. With the assistance of thermal activation energy, part of it can overcome the peak first, while the dislocation line forms a dislocation kink. Subsequently, the movement of the dislocation, aided by the kinked dislocation line, can easily shift sideways, resulting in a significant reduction in the stress required for the entire dislocation line to slip. During the slip process, in addition to lattice resistance, the resistance generated by the interaction between dislocations, the kinks and jogs formed after dislocation intersections, and the resistance caused by interactions between dislocations and other crystal defects all contribute to resistance, leading to crystal strengthening during slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对滑移机制进行详细的文字解释和论述，答案提供了详细的描述和分析，符合简答题的特征。 | 知识层次: 题目要求解释滑移机制及其在塑性变形中的作用，涉及晶体结构、位错运动、能量变化、热激活能等多个复杂概念的关联和综合分析。需要深入理解位错运动的机理，并能解释滑移过程中的各种阻力来源及其对晶体强化的影响，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解晶体滑移的微观机制，包括位错运动、能量变化、热激活能的作用以及多种阻力来源的综合分析。正确选项不仅需要掌握复杂的概念，还需要将这些概念串联起来进行机理解释和现象分析，体现了对材料塑性变形机制的全面理解和综合运用能力。这种深度和广度的知识要求在选择题型中属于最复杂的层次。" + }, + { + "idx": 1261, + "question": "What is the twinning mechanism in the analysis of the mechanisms and manifestations of plastic deformation in materials?", + "answer": "Twinning is a mode of plastic deformation that occurs when a crystal cannot undergo slip. It also involves the relative motion of the crystal along the twinning direction and twinning plane under shear stress. The difference from slip is that twinning is a uniform shear deformation, and the two parts of the twin crystal form a mirror-symmetric relationship. The dislocation mechanism lies in the fact that after the sliding of a partial dislocation in the crystal, parallel and adjacent crystal planes undergo stacking faults, resulting in the formation of a twin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对孪生机制进行解释和论述，答案提供了详细的文字描述和解释，符合简答题的特征。 | 知识层次: 题目要求解释孪生机制在材料塑性变形中的作用和表现，涉及晶体变形机制、剪切应力下的相对运动、与滑移的区别、位错机制等多方面的综合分析。需要深入理解并解释复杂的物理过程，属于对机理的详细解释和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解孪生机制在塑性变形中的作用，并能够区分孪生与滑移的不同之处。正确选项不仅涉及孪生的基本定义，还包括了孪生的晶体学特征、剪切变形机制以及位错机理等复杂概念的综合运用。此外，题目还要求考生能够理解并解释孪晶的镜像对称关系以及堆垛层错的形成过程，这些都是材料科学中较为复杂和深入的知识点。因此，该题目在选择题型内属于复杂现象全面分析的难度等级。" + }, + { + "idx": 1264, + "question": "What is a twin crystal? Explain its formation mechanism.", + "answer": "A twin crystal refers to two crystals (or two parts of one crystal) forming a mirror-symmetric orientation relationship along a common crystal plane, and these two parts are called twin crystals. The formation of twin crystals is due to uniform shear occurring throughout the twin region during twinning deformation, where the relative displacement of each crystal layer is caused by the movement of a partial dislocation. Taking face-centered cubic crystals as an example, the formation of twin crystals requires the generation of stacking faults. For instance, face-centered cubic crystals are stacked in the order of ABCABC··· on the 111 plane, which can be represented as △△△△△⋯. If the stacking sequence is reversed starting from a certain layer, becoming ABCACBACBA·.……., i.e., △△△∇∇∇∇⋯, the upper and lower parts of the crystal form a mirror-symmetric twin relationship. It can be observed that the ···CAC part corresponds to a stacking fault, followed by stacking in the reversed order, which still belongs to the normal FCC stacking sequence but is exactly opposite to the sequence of the crystal part before the fault, thus forming a symmetric relationship. This process is caused by the movement of a partial dislocation (Shockley partial dislocation).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释双晶的定义及其形成机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释孪晶的定义（基础概念），还需要详细阐述其形成机制，包括剪切变形、部分位错运动以及堆垛顺序变化等复杂过程。这需要深入理解晶体结构、位错理论和变形机制，并进行综合分析，属于对知识的深度理解和复杂应用。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解并解释双晶的形成机制，涉及复杂的晶体学概念（如堆垛顺序、部分位错运动）和对称性关系。正确选项不仅需要识别双晶的定义，还需详细描述面心立方晶体中通过堆垛层错和部分位错运动形成镜像对称的完整机理过程。这种综合运用晶体缺陷理论和空间想象力的题目，在选择题中属于对知识深度和推理能力要求极高的类型。" + }, + { + "idx": 1265, + "question": "From the perspective of bonding, discuss why metals generally exhibit higher plasticity or ductility compared to inorganic non-metals.", + "answer": "The bonding in metallic materials is primarily metallic bonding, while transition metals exhibit a mix of metallic and covalent bonding. Inorganic non-metallic materials are mainly bonded through ionic and covalent bonds. Metallic bonding is characterized by electron delocalization, where free electrons can move throughout the crystal, giving the bond no saturation or directionality. Due to the absence of saturation and directionality, each atom can potentially bond with more atoms and tends to form low-energy close-packed structures. When metals undergo deformation under force, the relative positions of atoms change without breaking the metallic bonds, which grants metals excellent ductility. Ionic bonding involves ions as the bonding units, where the bond is maintained by electrostatic attraction between positive and negative ions. This bond is strong, making it difficult for free electrons to move. Covalent bonds are formed between two or more atoms with similar electronegativity through shared electron pairs. Each bond has a fixed orientation, coordination numbers are relatively small, and the bonds are strong. Shared electron pairs between adjacent atoms cannot move freely, giving covalent bonds directionality and saturation, which generally results in poor plasticity and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合角度讨论金属与无机非金属的塑性差异，需要详细的文字解释和论述，答案也呈现为一段完整的论述性文字，符合简答题的特征。 | 知识层次: 题目要求从化学键的角度深入分析和比较金属与无机非金属材料的塑性差异，涉及多种键合类型（金属键、离子键、共价键）的特性及其对材料性能的影响机制。需要综合运用材料科学和化学键理论的知识，进行推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从键合角度深入分析金属与无机非金属的塑性差异，涉及多种键合类型（金属键、离子键、共价键）的特性比较，以及这些特性如何影响材料的宏观性能。解题需要综合运用材料科学中的键合理论，理解电子行为（如离域电子与局域电子的区别）、键的方向性与饱和性等抽象概念，并能将这些微观机制与宏观塑性表现建立逻辑关联。这种在选择题中要求进行多层次的机理解释和复杂现象分析，远超一般选择题的概念识别或简单应用要求。" + }, + { + "idx": 1269, + "question": "When a spherical embryo with radius r appears in an undercooled liquid, what is the critical nucleus radius?", + "answer": "-2σ/ΔGv", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算临界核半径，需要应用公式(-2σ/ΔGv)进行数值计算，答案是一个具体的计算结果表达式 | 知识层次: 题目要求直接应用临界核半径公式（-2σ/ΔGv），属于基本公式的直接套用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（临界核半径公式）进行计算，无需额外的步骤或组合多个公式。属于最基础的难度等级，适合考察学生对基本公式的记忆和简单应用能力。" + }, + { + "idx": 1270, + "question": "When a spherical crystal embryo with radius r appears in an undercooled liquid, what happens to the number of nucleation events as r* decreases?", + "answer": "Increases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释当球形晶胚半径r*减小时成核事件数量的变化情况，答案需要文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目涉及晶体成核的基本原理和临界半径的概念，需要理解成核事件与临界半径之间的关系，并进行一定的综合分析。虽然不涉及复杂的计算或深度推理，但需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶体成核理论中的临界半径概念(r*)及其与过冷液体的关系，并能综合分析半径减小对成核事件数量的影响。题目涉及多步概念关联，但作为选择题只需选择正确趋势（增加），不需要展开论述。" + }, + { + "idx": 1271, + "question": "The solubility of substitutional solid solutions is related to atomic size factor, (4), electron concentration factor, and (5).", + "answer": "4) electronegativity factor; (5) crystal structure factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分的内容，需要根据知识进行文字解释和补充，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对固溶体溶解度影响因素的基本概念记忆，包括原子尺寸因素、电负性因素、电子浓度因素和晶体结构因素等基础知识点，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然涉及基础概念记忆，但需要考生同时掌握原子尺寸因素、电子浓度因素、电负性因素和晶体结构因素四个相关概念，并正确匹配括号编号。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。题目主要测试对固溶体溶解度影响因素的分类记忆能力，属于选择题中典型的\"多概念匹配\"类型。" + }, + { + "idx": 1273, + "question": "The typical crystal structure types of metals are fcc, bcc, and hcp, with coordination numbers of (1), (2), and (3) respectively.", + "answer": "(1) 12; (2) 8; (3) 12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的数值作为答案，而不是从给定的选项中选择或判断对错。虽然答案简短，但需要基于对晶体结构类型的理解来回答，属于简答题的范畴。 | 知识层次: 题目考查金属典型晶体结构类型及其配位数的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆金属晶体结构的配位数即可作答。题目提供了明确的结构类型（fcc、bcc、hcp）与对应配位数的匹配关系，无需额外推理或分析步骤，符合等级1\"基本定义简答\"的难度标准。" + }, + { + "idx": 1274, + "question": "When a spherical embryo with radius r appears in an undercooled liquid, what is the critical nucleation work?", + "answer": "-1/3σS = 16πσ³/3ΔGv²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算临界成核功，答案给出了具体的计算公式和结果，需要通过数值计算和公式应用来解答。 | 知识层次: 题目涉及临界成核功的计算，需要应用公式并进行多步计算，同时需要理解表面能和体积自由能变化的概念及其关联。这属于中等应用层次，需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解临界成核功的概念，并能够关联表面能σ和体积自由能变化ΔGv的关系。题目涉及多步计算和概念的综合应用，但作为选择题，正确选项已经给出，减少了推导的复杂性。因此，在选择题型内属于需要一定综合分析能力的题目，但尚未达到最复杂的多变量计算水平。" + }, + { + "idx": 1275, + "question": "Intermediate phase", + "answer": "Intermediate phase: Refers to a new phase formed by the interaction between alloy components when the solid solubility limit of the solid solution is exceeded. This phase has a lattice structure and properties completely different from any of the components and exhibits metallic characteristics. Since it is often located in the middle of the phase diagram, it is also called an intermediate phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Intermediate phase\"进行文字解释和论述，答案提供了详细的定义和特性描述，符合简答题的特征。 | 知识层次: 题目考查对“Intermediate phase”这一基本概念的定义和特性的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项对中间相的定义进行了较为详细的解释，包括其形成条件、结构特点和位置特征等。这要求考生不仅要记住中间相的基本定义，还需要理解其相关特性，比简单的定义记忆题（等级1）要求更高。但题目并未涉及复杂的概念体系或需要比较分析多个概念，因此不属于高难度（等级3）题目。" + }, + { + "idx": 1276, + "question": "During the crystallization process of solid solution alloys, the laws of nucleation and grain growth are followed, but unlike pure metals, what additional fluctuation is required during nucleation?", + "answer": "composition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在固溶体合金结晶过程中除了遵循形核和晶粒生长规律外，还需要什么额外的波动，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对固溶体合金结晶过程中成核和晶粒生长规律的理解，需要将纯金属的结晶过程与固溶体合金进行比较，并识别出额外的成分波动要求。这涉及多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解固溶体合金结晶过程中的成核规律，并区分其与纯金属成核的差异。题目要求考生掌握成分波动这一关键概念，并进行综合分析判断。" + }, + { + "idx": 1277, + "question": "During the crystallization process of solid solution alloys, in what process does the composition fluctuation during nucleation occur?", + "answer": "Variable temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述结晶过程中成分波动的发生过程，答案形式为文字解释而非选择、判断或计算。 | 知识层次: 题目涉及固溶体合金结晶过程中的成分波动现象，需要理解成核过程中的热力学和动力学机制，并能够分析温度变化对成分波动的影响。这需要综合运用材料科学中的相变理论、热力学和动力学知识，进行推理和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1278, + "question": "What is the growth mode of crystals related to?", + "answer": "Interface structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体生长模式与什么相关，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查晶体生长模式与界面结构的关系，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，涉及晶体生长模式与界面结构关系的简单定义。题目仅要求识别正确选项\"Interface structure\"，无需复杂推理或多概念整合，属于最基本的知识点掌握要求。" + }, + { + "idx": 1279, + "question": "During the crystallization process of a solid solution alloy, what kind of diffusion is always accompanied?", + "answer": "Heterogeneous atoms (solute atoms)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释在固溶体合金结晶过程中伴随的扩散类型，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查的是对固体溶液合金结晶过程中扩散类型的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，此题属于基础概念记忆类题目，仅需回忆\"固溶体合金结晶过程中伴随何种扩散\"这一基本定义即可作答。正确选项直接对应教材中的基础知识点，不需要任何解释或分析过程，属于最简单的记忆性题目。" + }, + { + "idx": 1280, + "question": "What is the crystal growth morphology related to?", + "answer": "Interface structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述晶体生长形态与什么相关，答案是一个简短的文字描述而非选择、判断或计算。 | 知识层次: 题目考查晶体生长形态与界面结构关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，要求考生识别晶体生长形态与界面结构的关系。题目仅测试对单一概念的定义记忆，无需解释或分析，属于最基本的知识点掌握要求。" + }, + { + "idx": 1281, + "question": "The growth morphology of crystals is related to what distribution at the interface front?", + "answer": "Temperature gradient", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体生长形态与界面前沿分布的关系，答案需要文字解释而非选择、判断或计算 | 知识层次: 题目考查晶体生长形态与界面前沿温度梯度分布的关系，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即晶体生长形态与界面前沿温度梯度的关系。题目直接考察学生对基本定义的掌握，无需复杂推理或概念间的比较分析，属于最基础的知识点考察。" + }, + { + "idx": 1283, + "question": "According to the phase rule, the maximum number of equilibrium phases when the degrees of freedom in a ternary system are zero is", + "answer": "4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目涉及相律的应用，需要根据给定的自由度条件（三元系统中自由度为0）进行计算，得出最大平衡相数。答案是一个具体的数值（4），需要通过公式推导或计算得出。 | 知识层次: 题目考查对相律公式的直接应用，仅需简单计算即可得出答案，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接考察对相律公式的应用，只需记住并套用相律公式（F = C - P + 2），其中F为自由度，C为组分数，P为相数。题目中给出自由度F=0，组分数C=3（三元系统），直接代入公式即可得出P=5-2=3，但题目问的是最大平衡相数，因此需要考虑相律的限制条件，最终答案为4。虽然需要理解相律的基本概念，但解题步骤非常直接，属于最基础的公式应用。" + }, + { + "idx": 1284, + "question": "According to the phase rule, when the degrees of freedom in a ternary system are zero, it is represented on the phase diagram as", + "answer": "plane", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，虽然题目中没有明确给出选项，但答案\"plane\"暗示这是一个选择题的答案选项之一 | 知识层次: 题目考查对相律基础概念的记忆和理解，涉及自由度为零时在三元相图中的表示方式，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆相律在多元系统中的自由度与相图表示的关系。题目明确给出了正确选项，无需复杂辨析或深度理解，属于最简单的概念识别类型。" + }, + { + "idx": 1285, + "question": "When a single crystal undergoes plastic deformation, the common methods are (15), (16), and (17).", + "answer": "(15) Slip; (16) Twinning; (17) Kinking", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的变形方法名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对单晶塑性变形常见方法的基础概念记忆，仅需列举出三种方法名称，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求考生记忆并识别单晶塑性变形的三种常见方法（滑移、孪生和扭折），这些是材料科学中的基础概念，无需深入解释或分析。考生只需回忆相关定义即可正确作答，解题步骤简单，知识掌握深度要求较低。" + }, + { + "idx": 1286, + "question": "The negative sign of the diffusion flux indicates that diffusion proceeds from high concentration to low concentration, and the driving force for diffusion in this process is (20)", + "answer": "Chemical potential gradient (chemical force)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述扩散过程的驱动力，答案是一个概念性的解释（化学势梯度），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查扩散通量的负号含义以及扩散驱动力的基本概念，属于对基本原理的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生记住扩散过程的驱动力是化学势梯度（化学力）这一基本定义。题目直接给出明确选项，无需复杂推理或概念比较，属于最简单的记忆性知识考查。" + }, + { + "idx": 1287, + "question": "After cold deformation, the control of grain size after recrystallization is related to the degree of cold deformation, original grain size, recrystallization temperature, and impurities, among others. Among these, what is (21)?", + "answer": "Degree of cold deformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释或论述影响再结晶晶粒尺寸的因素，并具体指出其中一个因素（冷变形程度）。虽然答案是一个具体的因素，但题目本身更倾向于简答形式，需要理解并解释多个因素之间的关系。 | 知识层次: 题目考查对冷变形后晶粒尺寸控制因素的基础概念记忆，仅需识别关键影响因素之一（冷变形程度），无需深入分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别冷变形程度这一单一因素即可作答。题目直接给出了明确的关键词\"degree of cold deformation\"，不需要进行概念比较或复杂推理，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1288, + "question": "The first law of diffusion applies to steady-state diffusion, and its mathematical expression can be written as (19)", + "answer": "J=-Ddc/dx", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出扩散第一定律的数学表达式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查菲克第一定律的基本概念和数学表达式的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆菲克第一定律的基本数学表达式，属于基础概念记忆的范畴。题目直接给出了正确选项，无需进行复杂的分析或推理，因此难度等级为1。" + }, + { + "idx": 1289, + "question": "Dynamic recovery and dynamic recrystallization refer to deformation at high temperatures, where (18) occurs simultaneously during the deformation process.", + "answer": "(18) work hardening and softening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个短语或短句来补全句子，而不是从多个选项中选择或进行判断。答案需要简要解释或描述概念，符合简答题的特征。 | 知识层次: 题目考查动态回复和动态再结晶的基本概念，需要记忆和理解这些术语的定义及其在高温度变形过程中的作用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即动态恢复和动态再结晶的定义。正确选项直接给出了\"work hardening and softening\"这一基本概念，无需进行复杂的分析或推理。题目属于基础概念记忆层次，符合等级1的难度标准。" + }, + { + "idx": 1290, + "question": "After cold deformation, the control of grain size after recrystallization is related to the degree of cold deformation, original grain size, (22), and impurities, etc. What is (22)?", + "answer": "Recrystallization temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Recrystallization temperature），而不是从多个选项中选择或判断对错，也不需要计算。这符合简答题的特征，即需要提供具体的、简短的答案。 | 知识层次: 题目考查对再结晶过程中影响晶粒尺寸因素的基础概念记忆，特别是再结晶温度这一关键参数的理解和识别。 | 难度: 在选择题型中，该题目仅考察对\"再结晶温度\"这一基础概念的记忆，属于直接回忆型题目。无需解释或分析，只需识别正确术语填空，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1291, + "question": "When a crystal is subjected to external forces, the moving dislocations inside it will intersect, resulting in the formation of jogs and kinks. What is the length of these jogs and kinks the same as that of the intersecting dislocations?", + "answer": "The magnitude of the Burgers vector", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述jogs和kinks的长度与Burgers矢量的关系，答案需要文字解释而非选择或判断 | 知识层次: 题目考查的是对位错运动中形成的jogs和kinks的基本概念的理解，特别是它们与Burgers矢量的关系。这属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念（Burgers vector）的记忆，无需解释或分析。正确选项直接对应定义性知识，属于最简单的记忆性题目类型。" + }, + { + "idx": 1292, + "question": "If the slip of the jog is inconsistent with the slip of the main dislocation line, the main dislocation line will drag the jog to produce climb motion, resulting in what phenomenon?", + "answer": "Jog hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释一个现象（resulting in what phenomenon），答案需要文字解释和论述（Jog hardening），而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目涉及位错运动中的复杂机制分析，需要理解位错与割阶的相互作用以及攀移运动导致的硬化现象，属于对材料变形机制的深度解释和推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解位错和攀移运动的基本概念，还需要综合运用这些知识来分析复杂现象（jog hardening）。解题需要深入理解位错相互作用机理，并能推理出不一致滑移导致的后果。这种题目超出了简单记忆或单一概念应用的范畴，属于复杂现象全面分析的层次。" + }, + { + "idx": 1293, + "question": "What does secondary recrystallization conceptually refer to?", + "answer": "Secondary recrystallization refers to the phenomenon where, after recrystallization annealing, a metal subjected to higher temperatures or prolonged holding times experiences a few grains rapidly consuming other grains and growing, resulting in the entire metal being composed of a small number of exceptionally large grains that are tens to hundreds of times larger than the post-recrystallization grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary recrystallization\"这一概念进行解释和论述，答案是一段详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶这一基础概念的定义和现象描述，属于记忆和理解层次的知识点，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对二次再结晶的定义和现象有较为深入的理解，能够描述其过程和结果。相比于简单的定义简答（等级1），该题目要求考生能够解释和描述一个具体的材料科学现象，属于概念解释和描述的层次（等级2）。" + }, + { + "idx": 1294, + "question": "What does recrystallization conceptually refer to as a process?", + "answer": "Recrystallization refers to the process in which a substance transforms from one structure to another in the solid state, i.e., an allotropic transformation reaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对recrystallization的概念进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对再结晶这一基本概念的定义和简单解释，属于基础概念记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求对\"recrystallization\"这一基础概念的定义进行记忆性回答，属于最基本的概念简答。题目仅涉及单一概念的定义，不需要进行解释或比较分析，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1295, + "question": "Why does pure metal grow in a planar manner during solidification under a positive temperature gradient?", + "answer": "During crystallization, the interface of pure metal is rough and grows under a positive temperature gradient. As the crystal grows, heat is dissipated through the solid mold wall, making the solid-liquid interface isothermal. If dynamic undercooling is achieved, the interface moves forward. If there is a small protrusion locally on the interface extending into the superheated liquid phase, the protrusion will be melted, so the interface remains straight; the crystal grows in a planar manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纯金属在正温度梯度下凝固时为何以平面方式生长，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释纯金属在正温度梯度下凝固时平面生长的机理，涉及动态过冷、界面粗糙性、热量传递等多个概念的关联和综合分析，需要深入理解并推理分析其背后的物理机制。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1297, + "question": "What are the differences in the nucleation and growth processes among recrystallization, primary recrystallization, and secondary recrystallization?", + "answer": "Recrystallization and primary recrystallization involve nucleation and growth processes; secondary recrystallization only involves a growth process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述不同再结晶过程中的成核和生长过程的差异，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目要求对不同再结晶过程（再结晶、初次再结晶和二次再结晶）的形核和生长过程进行比较和分析，涉及多个概念的关联和机理的解释，需要综合运用知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合理解并区分三种再结晶过程（再结晶、初次再结晶和二次再结晶）的成核与生长机制差异。这需要考生不仅掌握每个过程的定义，还需要深入理解其背后的材料科学机理，并能进行复杂的推理分析。正确选项涉及对二次再结晶特殊性的精确把握（仅生长过程），这体现了对复杂现象的全面分析能力。在选择题型中，这种需要多概念综合比较和机理深度解释的题目属于最难类型。" + }, + { + "idx": 1298, + "question": "Why do solid solution alloys usually grow in a dendritic manner during solidification under a positive temperature gradient?", + "answer": "During the crystallization of solid solutions, constitutional supercooling occurs, leading to a constitutionally supercooled zone ahead of the solid-liquid interface. If any small protrusion exists on the interface, it will extend into the constitutionally supercooled zone and continue to grow as it gains supercooling. Therefore, the interface cannot remain flat and stable, resulting in dendritic growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么固溶体合金在正温度梯度下凝固时通常以枝晶方式生长，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释固溶体合金在正温度梯度下凝固时形成枝晶的原因，涉及成分过冷、固液界面稳定性等概念的关联和综合分析，需要深入理解凝固过程中的热力学和动力学机制，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1299, + "question": "Discuss the theory of grain refinement strengthening from the mechanism of plastic deformation in materials.", + "answer": "In the strengthening theories of materials, grain refinement strengthening is the only method that can simultaneously improve both the strength and toughness of materials. The specific explanation is as follows: Due to the fine grains, the slip planes available for dislocation pile-up are shorter, and the number of piled-up dislocations is smaller. The stress concentration caused by dislocation pile-up is dispersed among various grains, thereby increasing the yield strength. On the other hand, because the grains are fine, under the same external force, there are more grains in favorable slip directions, and the stress is distributed among the grains. Even under large plastic deformation, the material maintains its good performance without cracking, thus improving the toughness. In summary, grain refinement strengthening can enhance the comprehensive mechanical properties of materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对晶粒细化强化的理论进行讨论，需要详细的文字解释和论述，而不是选择、判断或计算。答案提供了详细的机制解释和结论，符合简答题的特点。 | 知识层次: 题目要求从塑性变形机制的角度讨论晶粒细化强化的理论，涉及对位错堆积、应力集中、屈服强度和韧性等多因素的关联分析，需要综合运用材料科学中的强化机制和塑性变形理论进行深入解释和推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解晶粒细化强化的机理，包括位错堆积、应力分散等复杂概念，并能综合运用这些知识解释强度和韧性的同步提升。解题步骤涉及多个知识点的串联和推理分析，远超简单记忆或基础理解的层次。" + }, + { + "idx": 1300, + "question": "What are the differences in the driving forces among recrystallization, primary recrystallization, and secondary recrystallization?", + "answer": "The driving force for recrystallization is the free energy difference between the new and old phases, for primary recrystallization it is the stored energy, and for secondary recrystallization it is the interfacial energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述不同再结晶过程的驱动力差异，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求区分三种再结晶过程的驱动力，涉及多个概念的关联和综合分析，需要理解不同再结晶阶段的能量来源及其差异，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求区分三种再结晶过程的驱动力，涉及对材料科学中相变和能量概念的综合理解。虽然题目提供了明确的选项，但需要考生掌握不同再结晶过程的本质差异，并能准确关联到相应的驱动力来源。这需要一定的概念关联和综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1301, + "question": "Why do metal crystals always slide along the slip plane and slip direction during the slip process?", + "answer": "The slip of metal crystals is the result of dislocation movement, and the dislocation movement is mainly subjected to the resistance of the crystal lattice. In the crystal, the greater the interplanar spacing between the densest atomic planes, and the smaller the atomic spacing in the most closely packed direction, the smaller the sliding resistance when dislocations slide along the slip plane and slip direction. Therefore, metal crystals always slide along the slip plane and slip direction during the slip process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属晶体在滑移过程中为何总是沿滑移面和滑移方向滑动，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属晶体滑移过程中的机理，涉及位错运动、晶格阻力、原子面间距和方向等复杂概念的综合分析和推理。需要深入理解晶体结构和位错理论，并能够将这些概念关联起来进行解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解金属晶体滑移的微观机制，包括位错运动、晶格阻力、密排面和密排方向等复杂概念的综合运用。正确选项不仅需要解释滑移现象，还需要分析晶面间距和原子间距对滑移阻力的影响机理。这种题目要求考生具备将多个高阶材料科学原理进行系统性整合和推理分析的能力，远超单纯记忆或简单应用层面，属于选择题型中最复杂的机理深度解释类题目。" + }, + { + "idx": 1302, + "question": "What are the differences in the effects of recrystallization and secondary recrystallization on material properties?", + "answer": "After recrystallization, strength and hardness decrease while plasticity and toughness improve; after secondary recrystallization, the material's strength, plasticity, and toughness all decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述再结晶和二次再结晶对材料性能的不同影响，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求比较两种再结晶过程对材料性能的影响，涉及多个性能指标的变化分析，需要理解并关联不同再结晶过程的基本原理及其对材料微观结构和宏观性能的影响。虽然不涉及复杂计算，但需要对概念进行综合分析和比较。 | 难度: 在选择题型中，该题目要求考生不仅理解recrystallization和secondary recrystallization的基本概念，还需要综合分析两者对材料性能（强度、硬度、塑性、韧性）的不同影响。这涉及多角度比较和概念关联，超出了简单记忆或单一概念应用的范畴，属于较高层次的分析能力要求。" + }, + { + "idx": 1303, + "question": "What is the structure of austenite?", + "answer": "Austenite: An interstitial solid solution of carbon in γ-Fe, with a face-centered cubic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释奥氏体的结构，答案提供了详细的文字描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对奥氏体结构的基本定义和晶体结构的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别奥氏体的基本定义和晶体结构（面心立方结构）。这属于最基础的概念记忆层次，不需要解释或分析多个概念，解题步骤非常简单直接。" + }, + { + "idx": 1304, + "question": "What are the differences in the phase transformation processes among recrystallization, primary recrystallization, and secondary recrystallization?", + "answer": "Recrystallization involves a phase transformation process, while primary recrystallization and secondary recrystallization do not involve a phase transformation process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述不同再结晶过程之间的相变过程差异，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目要求比较三种再结晶过程的相变差异，涉及多个概念的关联和综合分析，需要理解再结晶、初次再结晶和二次再结晶的定义及其相变过程的特点，并进行对比分析。这超出了基础概念的记忆，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及三个不同的再结晶过程，要求考生能够区分它们是否涉及相变过程。虽然不需要复杂的计算，但需要对材料科学中的相变和再结晶概念有清晰的理解，并能进行综合分析和比较。" + }, + { + "idx": 1305, + "question": "What type of structure is cementite?", + "answer": "Cementite: an interstitial compound formed by iron and carbon, belonging to the orthorhombic system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释cementite的结构类型，答案提供了详细的文字描述和分类信息，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对渗碳体（cementite）这一基本概念的定义和晶体结构的记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别水泥体的基本定义和分类（铁和碳形成的间隙化合物，属于正交晶系）。这属于最基础的概念记忆层次，无需复杂推理或概念间的关联分析，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 1306, + "question": "At room temperature, bending a lead plate makes it increasingly harder, but after some time, bending it again makes the lead plate as soft as it was initially. Why? Please explain this phenomenon.", + "answer": "At room temperature, bending a lead plate makes it increasingly harder due to work hardening, which increases the strength and hardness of the lead plate. After some time, because the melting point of lead is relatively low, recrystallization softening occurs at room temperature, causing its hardness to decrease again.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释一个现象，答案需要文字解释和论述，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目要求解释材料在变形后的硬度变化现象，涉及工作硬化和再结晶软化两个关键概念，需要理解这些现象的机理及其相互关系。此外，还需要结合铅的低熔点特性来解释室温下的再结晶行为，这需要较高的综合分析能力和对材料科学原理的深入理解。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解工作硬化和再结晶软化的基本概念，还需要综合运用这些知识来解释复杂现象。正确选项涉及多个步骤的推理分析，包括识别初始硬度增加的原因（工作硬化）和后续硬度恢复的原因（再结晶软化），并需要理解铅的低熔点特性如何影响室温下的再结晶过程。这种综合运用和深度机理解释的要求在选择题中属于最复杂的类型。" + }, + { + "idx": 1307, + "question": "What kind of structure is ferrite?", + "answer": "Ferrite: an interstitial solid solution of carbon in α-Fe, with a body-centered cubic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对ferrite的结构进行文字解释和论述，答案提供了详细的描述，符合简答题的特征 | 知识层次: 题目考查铁素体的基本定义和晶体结构，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别铁素体的基本定义和晶体结构特征。题目直接给出了明确的定义描述（间隙固溶体、α-Fe、体心立方结构），不需要进行概念间的比较或复杂推理，属于最基础的定义识别类题目。" + }, + { + "idx": 1308, + "question": "The solubility of substitutional solid solutions is related to atomic size factor, (1), electron concentration factor, and (2).", + "answer": "(1) electronegativity factor; (2) crystal structure factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分的内容，需要根据知识进行文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对固溶体溶解度影响因素的基本概念记忆，包括原子尺寸因素、电负性因素、电子浓度因素和晶体结构因素等基础知识点，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生同时掌握原子尺寸因素、电子浓度因素、电负性因素和晶体结构因素等多个相关概念，并理解它们之间的关联。题目要求考生在给定的选项中正确匹配两个空缺部分，这比单纯记忆单个定义要复杂一些，但不需要进行复杂的分析或推理。" + }, + { + "idx": 1309, + "question": "A decrease in $r^{}$ means the number of nucleation sites (4).", + "answer": "increases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（increases）来回答问题，属于简短的文字回答形式，不需要计算或选择选项 | 知识层次: 题目考查的是对成核位点与半径关系的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，此题仅涉及基础概念记忆，即对\"$r^{}$\"与成核位点数量关系的定义性知识。题目仅要求识别正确选项\"increases\"，无需解释或分析过程，属于最基础的定义简答层级。" + }, + { + "idx": 1310, + "question": "When a spherical embryo with radius $r$ appears in an undercooled liquid, the resulting critical nucleus radius is (3).", + "answer": "$\\\\frac{-2\\\\sigma}{\\\\Delta G_{V}}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式计算临界核半径，答案是一个具体的数学表达式，需要应用材料科学中的相关公式进行计算。 | 知识层次: 题目考查基本公式的直接应用，仅需将给定的临界核半径公式套用即可，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求直接应用临界核半径公式 $r^* = \\frac{-2\\sigma}{\\Delta G_V}$，无需进行额外的推导或组合多个公式。学生只需识别并正确套用该基本公式即可得出答案，解题步骤简单直接。" + }, + { + "idx": 1311, + "question": "Homogeneous nucleation of crystal nuclei relies on (5) providing atomic clusters with $r>r^{*}$ to act as nuclei.", + "answer": "Structural fluctuations", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体核均匀成核的机制，答案需要文字描述结构波动的作用，属于简答题类型 | 知识层次: 题目考查均相成核的基本概念，特别是结构波动在成核过程中的作用，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解\"结构波动\"（Structural fluctuations）在晶体成核过程中的作用，并能够将其与题目描述的情境联系起来。这超出了简单的定义记忆，需要对概念有一定的理解和应用能力。" + }, + { + "idx": 1312, + "question": "Homogeneous nucleation of crystal nuclei relies on (6) to provide nucleation work equivalent to the interfacial energy (7).", + "answer": "energy fluctuation; 1/3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要填写两个空白处的内容，分别是\"energy fluctuation\"和\"1/3\"，这属于简答题的填空形式，需要根据知识理解来填写正确答案，而不是从选项中选择或进行判断。 | 知识层次: 题目考查对均相成核过程中能量波动和界面能比例的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆并填写两个关键术语（能量波动和1/3），无需进行概念解释或复杂推导。题目直接考查均质形核的核心定义参数，属于对单一知识点的机械性记忆，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1313, + "question": "Dynamic recovery and dynamic recrystallization refer to the simultaneous occurrence of (15) during deformation.", + "answer": "(15) softening and strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写一个特定的术语或短语来完成句子，而不是从多个选项中选择或进行判断。答案需要简要的文字描述，符合简答题的特征。 | 知识层次: 题目考查动态回复和动态再结晶的基本概念，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生同时理解动态恢复和动态再结晶的定义，并能够将这两个概念与软化及应变硬化联系起来。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1314, + "question": "What kind of diffusion always accompanies the crystallization process of solid solution alloys?", + "answer": "Dissimilar atoms", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释在固溶体合金结晶过程中伴随的扩散类型，答案需要文字解释而非选择或判断 | 知识层次: 题目考查对扩散类型在合金结晶过程中伴随现象的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，此题仅考察对基础定义的记忆，属于最简单的难度等级。题目直接询问\"固溶体合金结晶过程中伴随的扩散类型\"，正确选项\"不同原子\"是教材中明确给出的基本概念，不需要任何解释或推理过程。学生只需记住相关定义即可作答，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1315, + "question": "What mainly occurs during the high-temperature recovery of cold-worked metals?", + "answer": "Polygonization", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释冷加工金属在高温恢复过程中主要发生的现象，答案需要提供文字解释而非选择或判断 | 知识层次: 题目考查的是冷加工金属高温回复过程中主要发生的现象（多边形化），属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆，但\"polygonization\"是金属高温回复过程中的一个特定术语，需要学生不仅记住定义，还要理解其在冷加工金属恢复过程中的具体应用场景。这比单纯记忆基本定义(等级1)要求更高，但不需要进行复杂概念体系的分析比较(等级3)。" + }, + { + "idx": 1316, + "question": "What is the main phenomenon during the low-temperature recovery of cold-worked metals?", + "answer": "The disappearance of point defects", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释低温恢复冷加工金属的主要现象，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对冷加工金属低温回复过程中主要现象的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需回忆低温恢复过程中点缺陷消失这一基本现象。选择题型中仅需识别正确选项，无需解释或分析，属于最简单的定义识别类题目。" + }, + { + "idx": 1320, + "question": "During the plastic deformation of metals, after twinning occurs, the crystal orientations on both sides of the twin plane exhibit (11), and the crystal undergoes (12) shear.", + "answer": "(11) symmetric relationship; (12) uniform", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定的术语或概念（对称关系和均匀剪切），需要学生对金属塑性变形中的孪晶现象有准确的理解和记忆，属于简答题类型。 | 知识层次: 题目考查金属塑性变形中孪晶现象的基本概念，包括孪晶面两侧晶体取向的对称关系和均匀剪切的基本原理，属于基础概念的记忆和理解范畴。 | 难度: 该题目属于基础概念记忆类型，仅需考生记住金属塑性变形中孪晶现象的基本定义和特征。题目直接考察对称关系和均匀剪切这两个明确的概念，无需解释或分析过程，在选择题型中属于最简单的记忆性知识考查。" + }, + { + "idx": 1321, + "question": "Briefly describe the growth mechanism of pure metal crystals and its relationship with the microstructure of the solid/liquid interface.", + "answer": "The solid/liquid interface of pure metal crystals is generally a rough interface. Therefore, for pure metal crystals, during the growth process, they usually grow according to the vertical growth mode of the rough interface. Since nearly $50\\\\%$ of the positions on the interface are vacant, the addition of liquid-phase atoms is not restricted by position, which facilitates continuous filling of atoms, thereby enabling the solid/liquid interface to grow rapidly along the normal direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述纯金属晶体的生长机制及其与固/液界面微观结构的关系，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求解释纯金属晶体的生长机制及其与固/液界面微观结构的关系，涉及对晶体生长机理的深入理解和综合分析，需要将界面结构与生长模式关联起来进行推理分析，思维过程较为深入。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求对纯金属晶体的生长机制及其与固/液界面微观结构的关系进行深入理解和分析。正确选项不仅涉及粗糙界面的概念，还需要理解垂直生长模式的具体机制，以及原子填充的动力学过程。这需要考生具备扎实的材料科学基础，能够综合运用多个知识点进行推理分析，并解释复杂的物理现象。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 1324, + "question": "Dendritic segregation", + "answer": "Dendritic segregation: It is a type of microsegregation in materials, where under non-equilibrium cooling conditions, the newly formed solid solution grains after a homogeneous transformation exhibit non-uniform composition within. The initially crystallized core contains more high-melting-point component atoms, while the later crystallized outer regions contain more low-melting-point component atoms. Typically, solid solution crystals grow in a dendritic manner, resulting in the dendrite arms containing more high-melting-point components and the interdendritic regions containing more low-melting-point component atoms. This leads to compositional inhomogeneity within the same grain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Dendritic segregation\"进行详细的文字解释和论述，答案提供了概念定义、形成机制和具体表现等详细说明，符合简答题的特征。 | 知识层次: 题目考查的是对\"Dendritic segregation\"这一基本概念的定义和描述，属于材料科学中关于微观偏析的基础知识。答案主要涉及对现象的定义、形成原因和特征的记忆性解释，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对\"枝晶偏析\"的定义、形成原因及其在材料中的具体表现有较为全面的理解。题目不仅要求记忆定义，还需要理解非平衡冷却条件下固溶体晶粒的成分不均匀性及其与枝晶生长方式的关系。这种程度的描述性解释在选择题中属于概念解释和描述级别，比单纯的定义简答（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1326, + "question": "Explain the source and morphological characteristics of Fe3CI", + "answer": "Fe3CI: originates from the liquid phase, appearing as white elongated strips.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3CI的来源和形态特征，需要文字解释和论述，答案也以文字形式呈现，符合简答题的特征。 | 知识层次: 题目考查对Fe3CI的来源和形态特征的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅记忆Fe3CI的来源（液相），还需要描述其形态特征（白色细长条状）。这属于概念解释和描述的层次，比单纯的定义记忆（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 1327, + "question": "Explain the origin and morphological characteristics of Fe3CII", + "answer": "Fe3CII: Originates from the austenite precipitation reaction, generally distributed in a network-like pattern along grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Fe3CII的起源和形态特征，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Fe3CII的起源和形态特征，涉及奥氏体析出反应和晶界分布模式的理解，需要将多个概念关联起来进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解Fe3CII的起源（奥氏体析出反应）和形态特征（沿晶界呈网状分布），并能够将这两个概念关联起来进行综合分析。虽然不涉及多步计算，但需要对材料科学中的相变和显微组织有较深的理解。" + }, + { + "idx": 1328, + "question": "According to the reaction temperature from high to low, sequentially write the reaction formulas of the three-phase equilibrium reactions in the Fe-Fe3C alloy system", + "answer": "L0.53 + δ0.09 → γ0.17 (1495°C)\\nL4.3 → γ2.11 + Fe3C (1148°C)\\nγ0.77 → α0.0218 + Fe3C (727°C)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求按照反应温度从高到低的顺序写出Fe-Fe3C合金系统中的三相平衡反应式，答案是以文字形式列出具体的反应式和对应的温度，不需要计算或选择，属于简答题类型。 | 知识层次: 题目要求按照温度顺序写出Fe-Fe3C合金系统中的三相平衡反应公式，这需要理解合金相图的基本原理，并能够将不同温度下的反应进行关联和综合分析。虽然涉及记忆性知识，但更强调对相图的理解和应用，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。首先，题目要求考生掌握Fe-Fe3C合金系统中三相平衡反应的具体反应式及其对应的温度顺序，这需要深入理解相图和相关反应。其次，题目涉及多个反应式的记忆和排序，要求考生能够准确关联反应式与温度，并进行综合分析。此外，正确选项中的反应式和温度数据较为复杂，增加了记忆和理解的难度。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 1329, + "question": "Explain the origin and morphological characteristics of Fe3CIII", + "answer": "Fe3CIII: Originates from the precipitation reaction of ferrite, generally distributed in a network pattern along grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3CIII的起源和形态特征，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目考查Fe3CIII的起源和形态特征的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅记住Fe3CIII的定义，还需要理解其起源和形态特征（如网络状分布）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1330, + "question": "Explain the origin and morphological characteristics of Fe3C eutectoid", + "answer": "Fe3C eutectoid: The cementite in the eutectoid product pearlite, generally distributed in a lamellar form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C共析体的起源和形态特征，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Fe3C共析体的基本概念和形态特征，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生解释Fe3C eutectoid的起源和形态特征，属于概念解释和描述的层次。虽然需要记忆和理解相关概念，但并不涉及复杂的体系阐述或多概念比较分析，因此属于中等难度。" + }, + { + "idx": 1331, + "question": "Explain the origin and morphological characteristics of Fe3C eutectic", + "answer": "Fe3C eutectic: The cementite in the eutectic product ledeburite, which generally exists as the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C共晶的起源和形态特征，需要文字解释和论述，答案也以文字形式给出，符合简答题的特征。 | 知识层次: 题目考查对Fe3C eutectic的基本概念和形态特征的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释Fe3C共晶的起源和形态特征，但正确选项已经提供了关键信息（Fe3C共晶是莱氏体中的渗碳体，通常作为基体存在）。这需要考生具备基础概念记忆能力，能够识别和描述材料科学中的基本相组成和形态特征，但不需要进行复杂的分析或多概念整合。" + }, + { + "idx": 1332, + "question": "Explain the temperature range and alias of the first type of temper brittleness", + "answer": "The brittleness that occurs when tempering between 250~400Ω is called low-temperature temper brittleness, also known as the first type of temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第一类回火脆性的温度范围和别名，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对第一类回火脆性的温度范围和别名的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别关于第一类回火脆性的基本定义和温度范围。题目涉及的知识点非常基础，属于简单的定义性记忆内容，不需要复杂的理解或分析过程。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1333, + "question": "Explain the reversibility of the second type of temper embrittlement", + "answer": "The second type of temper embrittlement is reversible.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"The second type of temper embrittlement is reversible\"），答案直接给出了对错判断（\"is reversible\"），符合判断题的特征。 | 知识层次: 题目考查对第二类回火脆性可逆性的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求对基础概念（第二类回火脆性的可逆性）进行正误判断，属于最基本的概念记忆层次，无需复杂理解或分析步骤。" + }, + { + "idx": 1334, + "question": "Explain the reversibility of the first type of temper embrittlement", + "answer": "The first type of temper embrittlement is irreversible temper embrittlement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第一类回火脆性的可逆性，需要文字解释和论述，答案提供了简要的论述而非选择或判断 | 知识层次: 题目考查对第一类回火脆性可逆性的基本概念记忆和理解，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别基本定义（第一类回火脆性的不可逆性），属于最基础的概念记忆层次，无需复杂分析或推理步骤。" + }, + { + "idx": 1335, + "question": "Briefly describe one of the essential reasons for the high hardness of martensite: the characteristics of its crystal structure", + "answer": "The crystal structure of martensite is body-centered tetragonal, lacking closely packed slip planes that facilitate dislocation movement, thus making dislocation slip difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的关键原因之一，即其晶体结构特征，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对马氏体晶体结构特征的基本记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及马氏体晶体结构的基本概念，但需要考生不仅记住马氏体是体心四方结构，还要理解这种结构缺乏密排滑移面从而阻碍位错运动的原理。这超出了单纯记忆定义的层次，需要对概念进行一定程度的解释和描述。但题目并未要求比较不同结构或分析复杂体系，因此不属于最高难度等级。" + }, + { + "idx": 1336, + "question": "Explain the cause of the first type of temper brittleness", + "answer": "The first type of temper brittleness occurs due to the precipitation of discontinuous thin-shell-like carbides along the interfaces of martensite laths or plates during martensite decomposition, which reduces the fracture strength of grain boundaries, making them the path for crack propagation and thus leading to brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第一类回火脆性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第一类回火脆性的原因，涉及马氏体分解过程中碳化物的析出行为及其对晶界断裂强度的影响，需要综合运用材料科学中的相变、断裂机理等知识进行推理分析，思维深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解马氏体分解过程中不连续薄壳状碳化物的析出机制，以及其对晶界断裂强度和裂纹扩展路径的影响。这需要综合运用材料科学知识，进行复杂的机理分析和推理，属于复杂现象的全面分析层次。在选择题型中，此类题目对知识点的掌握深度和解题能力要求极高。" + }, + { + "idx": 1337, + "question": "Explain the temperature range and alias of the second type of temper brittleness", + "answer": "The brittleness that occurs when tempering between 450~650°C is called high-temperature temper brittleness, also known as the second type of temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第二类回火脆性的温度范围和别名，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对第二类回火脆性的温度范围和别名的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆并识别\"第二类回火脆性\"的温度范围和别名，属于基础概念的直接回忆，无需复杂分析或推理步骤。正确选项直接提供了定义性信息，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1338, + "question": "Explain the cause of the second type of temper brittleness", + "answer": "The cause of the second type of temper brittleness is the segregation of impurity elements such as Sb, Sn, P, and As to the original austenite grain boundaries during tempering, which weakens the atomic bonding force at the austenite grain boundaries and reduces the grain boundary fracture strength. This is the main reason for the occurrence of the second type of temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第二类回火脆性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第二类回火脆性的原因，涉及杂质元素在晶界的偏聚及其对原子键合力和晶界断裂强度的影响。这需要综合运用材料科学中的相变、晶界偏聚和力学性能等知识，进行机理层面的分析和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1339, + "question": "Briefly describe the third essential reason for the high hardness of martensite: grain boundary strengthening mechanism", + "answer": "Whether it is the laths of lath martensite or the plates of plate martensite, they are all very fine, and the grain boundary strengthening mechanism also plays a significant role.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第三个主要原因，即晶界强化机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体高硬度的第三个重要原因——晶界强化机制，这需要对马氏体微观结构（板条马氏体和片状马氏体）有深入理解，并能分析晶界强化对硬度的影响机制。这属于综合运用材料科学知识进行推理分析的层次。 | 难度: 在选择题型中，该题目属于机理深度解释难度。正确选项不仅需要考生理解马氏体的基本结构（板条马氏体和片状马氏体），还需要掌握晶界强化机制的具体作用原理。这要求考生能够将微观结构与宏观性能联系起来，并进行机理层面的解释。虽然题目提供了正确选项，但理解其背后的科学原理需要较高的知识掌握深度和分析能力。" + }, + { + "idx": 1340, + "question": "Briefly describe the second essential reason for the high hardness of martensite: the solid solution strengthening mechanism", + "answer": "Ferrite typically contains only 0.03% carbon atoms, while the carbon content in martensite is the same as that of the material itself. Therefore, martensite contains a large number of supersaturated carbon atoms, making solid solution strengthening one of the primary mechanisms for the high hardness of martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第二个主要原因，即固溶强化机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体高硬度的第二个主要原因——固溶强化机制，涉及对马氏体中碳原子过饱和状态的理解及其对硬度的影响。这需要将基础概念（如固溶强化）与具体材料（马氏体）的特性相结合，进行多步分析和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生理解马氏体高硬度的第二个主要原因——固溶强化机制，并能够比较铁素体和马氏体中碳含量的差异及其对硬度的影响。虽然题目涉及的知识点较为具体，但解题步骤相对直接，只需进行概念关联和综合分析即可得出正确答案。" + }, + { + "idx": 1343, + "question": "How does the concentration of a solid solution affect the diffusion coefficient?", + "answer": "The higher the concentration, the easier the diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释固体溶液浓度对扩散系数的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释固体溶液浓度对扩散系数的影响，需要理解扩散机制和浓度效应的关联，进行概念关联和综合分析，而不仅仅是记忆基础概念或简单应用。 | 难度: 在选择题中属于中等难度，需要理解固体溶液的浓度与扩散系数之间的关系，并能综合分析浓度变化对扩散过程的影响。虽然题目涉及的概念较为基础，但需要将多个知识点关联起来进行分析，因此难度适中。" + }, + { + "idx": 1344, + "question": "How does the type of solid solution affect the diffusion coefficient?", + "answer": "Different solid solutions have different atomic diffusion and mechanisms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同类型的固溶体如何影响扩散系数，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析不同类型固溶体对扩散系数的影响机制，需要综合运用扩散理论、固溶体特性以及原子扩散机制的知识，并进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目要求考生理解不同类型固溶体对扩散系数的影响机制，涉及原子扩散和机理的解释。这需要考生具备较深的知识掌握和综合分析能力，属于机理深度解释的难度等级。" + }, + { + "idx": 1345, + "question": "How does crystal structure affect the diffusion coefficient?", + "answer": "Different structures result in different diffusion coefficients.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶体结构如何影响扩散系数，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求分析晶体结构对扩散系数的影响，需要理解不同晶体结构的特点及其与扩散系数的关联，涉及多概念的综合分析和中等深度的推理，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶体结构和扩散系数之间的关联性，并进行综合分析。题目要求考生不仅知道晶体结构会影响扩散系数，还需要理解不同结构如何具体导致不同的扩散系数，这涉及多步概念关联和综合分析能力。" + }, + { + "idx": 1346, + "question": "How does chemical composition affect the diffusion coefficient?", + "answer": "The addition of chemical elements hinders diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释化学组成如何影响扩散系数，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释化学组成如何影响扩散系数，涉及多个概念的关联和综合分析，需要理解扩散机制与化学元素添加之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解化学组成对扩散系数的影响这一概念，并能综合分析添加化学元素如何阻碍扩散过程。题目涉及中等应用层次的知识，要求考生将多个概念关联起来，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1347, + "question": "Briefly describe the fourth essential reason for the high hardness of martensite: the transformation strengthening mechanism", + "answer": "During martensitic transformation, substructures with high lattice defect density are created within the crystal. The high-density dislocation networks in lath martensite and the fine twins in plate martensite both hinder dislocation motion, thereby causing strengthening through transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第四个重要原因，即转变强化机制，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释马氏体高硬度的第四个重要原因——相变强化机制，涉及对马氏体相变过程中亚结构形成及其对位错运动阻碍作用的深入理解。需要综合运用晶体缺陷、相变机制和强化机理等多方面知识进行机理分析和解释，思维过程具有较高的深度要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解马氏体高硬度的基本概念，还需要深入掌握马氏体转变过程中产生的亚结构（高位错密度的板条马氏体和含细密孪晶的片状马氏体）及其对位错运动的阻碍机制。这涉及到晶体缺陷、位错理论、相变强化等多个复杂概念的整合运用，需要考生具备将微观结构与宏观性能关联起来的综合分析能力。在选择题型中，这种需要多维度知识整合和机理深度解释的题目属于最复杂的考查类型。" + }, + { + "idx": 1348, + "question": "Briefly describe the fifth essential reason for the high hardness of martensite: the aging strengthening mechanism", + "answer": "After the formation of martensite, carbon and alloy element atoms diffuse and segregate or precipitate to dislocations or other crystal defects, pinning the dislocations and making them difficult to move, thereby increasing the hardness and strength of martensite through aging strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第五个原因，答案是一段文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体高硬度的第五个重要原因——时效强化机制，涉及碳和合金元素原子的扩散、偏聚或析出，以及位错钉扎等复杂机理。这需要综合运用材料科学中的相变、扩散、位错理论等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解马氏体高硬度的基本原因，还需要掌握时效强化机制的详细机理，包括碳和合金元素原子的扩散、偏聚或析出过程，以及这些过程如何钉扎位错并阻碍其运动。这需要考生具备综合运用材料科学知识的能力，能够进行复杂的推理分析和机理解释。此外，题目涉及的知识点较为深入，解题步骤复杂，对考生的理解深度和分析能力要求较高，因此在选择题型内属于复杂现象全面分析的难度等级。" + }, + { + "idx": 1349, + "question": "A stress of 70MPa is applied in the [001] direction of an FCC crystal. Which slip system in the crystal will activate first?", + "answer": "The resolved shear stress on the (111)[10-1] slip system is 28.58MPa, while the (1-11)[110] slip system does not slip. Therefore, the (111)[10-1] slip system activates first.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要计算不同滑移系上的分切应力，通过数值比较确定哪个滑移系先启动。答案中给出了具体的计算数值和比较过程，符合计算题的特征。 | 知识层次: 题目需要应用Schmid定律计算分解剪切应力，涉及多步计算和概念关联，但不需要复杂的综合分析或推理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生计算不同滑移系的分切应力，并比较计算结果以确定哪个滑移系会首先激活。这涉及到晶体学方向、滑移系的选择、分切应力公式的应用等多个步骤的计算和概念理解。虽然题目提供了正确选项，但考生仍需具备综合分析能力才能正确解答。" + }, + { + "idx": 1350, + "question": "Analyze the essential similarities between work hardening, fine grain strengthening, solid solution strengthening, and second-phase strengthening", + "answer": "Similarities: All involve hindering dislocation movement, increasing the resistance to dislocation glide, thereby strengthening the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析四种强化机制的相似性，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求分析四种强化机制的相似性，涉及对位错运动阻碍机理的综合理解和比较分析，需要深入理解材料强化机制的本质，并进行概念间的关联和推理分析。这超出了简单记忆或基本应用层次，属于需要综合运用知识进行复杂分析的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求分析四种强化机制的相似性，涉及多个复杂概念的综合运用和机理解释。正确选项需要深入理解位错运动受阻的共同本质，并能够将不同强化机制的微观机理联系起来。这种题目不仅考察知识点的记忆，更要求考生具备高阶的分析推理能力，能够从不同现象中抽象出共同规律，属于复杂现象全面分析的层次。" + }, + { + "idx": 1351, + "question": "Analyze the fundamental differences of grain refinement strengthening", + "answer": "Grain refinement strengthening: increases grain boundaries, enlarges the range of dislocation pile-up.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶粒细化强化的基本原理差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析晶粒细化强化的基本原理和机制，涉及对晶界和位错堆积范围变化的深入理解，需要综合运用材料科学中的强化机制知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求分析晶粒细化强化的基本原理，正确选项涉及对晶界增加和位错堆积范围扩大这两个关键机理的理解。这需要考生不仅掌握基本概念，还要能够将不同知识点联系起来进行机理层面的解释。虽然题目以选择题形式呈现，但考察的是对复杂材料强化机制的深度理解，属于\"机理深度解释\"的知识层次。在选择题型内，这类需要综合运用知识进行推理分析的题目难度明显高于单纯记忆或简单理解的题目。" + }, + { + "idx": 1352, + "question": "A stress of 70 MPa is applied in the [001] direction of an FCC crystal. Determine the resolved shear stress on the (1-11)[110] slip system.", + "answer": "Substitute into the formula: τ=σcosφcosλ, where cosλ=|a u+b v+c w|/(√(a²+b²+c²)√(u²+v²+w²)), cosφ=|a h+b k+c l|/(√(a²+b²+c²)√(h²+k²+l²)). For the (1-11)[110] slip system, since cosλ=0, this slip system does not slip under the applied stress.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（τ=σcosφcosλ）来确定特定滑移系上的分切应力，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要应用公式计算分解应力，涉及多步计算和方向指数的理解，但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体学方向指数和滑移系统的概念，并正确应用解析剪切应力公式进行计算。题目涉及多步骤计算过程（包括方向余弦计算和公式代入），同时需要综合分析滑移系统与应力方向的几何关系。虽然题目给出了关键公式，但需要考生正确识别滑移面和滑移方向的关系（cosλ=0的特殊情况判断），这体现了对概念的综合应用能力。" + }, + { + "idx": 1353, + "question": "According to solidification theory, what is the fundamental principle of grain refinement by vibration and stirring?", + "answer": "Vibration and stirring. Vibration and stirring can input additional energy into the liquid to provide nucleation work, promoting nucleation. On the other hand, they can cause crystallized crystals to fragment under the impact of liquid flow, increasing the number of nuclei.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动和搅拌细化晶粒的基本原理，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释振动和搅拌对晶粒细化的基本原理，涉及凝固理论中的成核和晶体破碎机制，需要综合运用多个概念并进行机理分析，思维深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解凝固理论的基本概念，还需要综合运用知识分析振动和搅拌对晶粒细化的影响机理。正确选项涉及能量输入、形核功、晶体破碎等多个复杂过程的解释，需要考生具备深入的理论知识和综合分析能力。这种在选择题中要求全面分析复杂现象并解释深层机理的题目，属于选择题型中的最高难度层级。" + }, + { + "idx": 1354, + "question": "According to solidification theory, what is the fundamental principle of refining grain size by increasing undercooling?", + "answer": "Increasing undercooling. Grain size depends on the relative relationship between nucleation rate and grain growth velocity. When undercooling is significantly high, the increase rate of nucleation surpasses that of grain growth, thus enhancing undercooling ensures N > G and widens the gap between them, leading to grain refinement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释凝固理论中通过增加过冷度细化晶粒的基本原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释通过增加过冷度细化晶粒的基本原理，涉及成核速率与晶粒生长速度的相对关系，需要综合运用凝固理论中的概念进行推理分析，解释N>G的机理及其对晶粒细化的影响，思维过程较为深入。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1355, + "question": "According to solidification theory, what is the fundamental principle of grain refinement through modification treatment?", + "answer": "Modification treatment. That is, adding a modifier to the molten metal before pouring to promote heterogeneous nucleation and increase the number of nuclei, thereby refining the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述改性处理的基本原理，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对凝固理论中晶粒细化机理的理解和应用，需要将改性处理与异质形核、晶粒细化等概念关联起来，并进行综合分析。虽然涉及基本原理，但需要一定的概念关联和解释能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及固溶理论的基本原理，要求考生掌握晶粒细化的改性处理方法，并能够理解异质形核和晶核数量增加的概念。虽然题目没有涉及复杂的计算，但需要对相关概念进行综合分析和关联，因此在选择题型中属于中等难度。" + }, + { + "idx": 1356, + "question": "Describe the behavior and manifestations of crystal defects in metals during the recovery stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects in this stage.", + "answer": "Recovery: Line defects remain largely unchanged, point defects significantly decrease, mechanical properties remain unchanged, while corresponding physicochemical properties alter; the driving force is stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体缺陷在金属恢复阶段的行为和表现，以及相应的材料特性，并解释驱动这些晶体缺陷运动的驱动力。答案需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求描述晶体缺陷在金属回复阶段的行为和表现，并解释驱动这些缺陷运动的驱动力。这需要理解晶体缺陷的基本概念（记忆/理解），并将其应用于特定阶段（回复阶段）的行为分析（应用）。此外，还需要解释驱动力（综合分析），涉及多个概念的关联和一定程度的推理分析。虽然不涉及复杂的计算或创新应用，但需要中等程度的综合分析和理解。 | 难度: 在选择题型中，该题目要求考生不仅理解晶体缺陷的基本概念，还需要综合分析恢复阶段的具体行为表现（如线缺陷和点缺陷的变化）、材料性能的变化（机械性能和物理化学性能），以及驱动力的本质（储存能）。这涉及多角度分析论述，需要将多个知识点关联起来进行深度思考，超出了简单的记忆或单一概念应用，属于较高难度的选择题。" + }, + { + "idx": 1357, + "question": "Analyze the fundamental differences in solid solution strengthening", + "answer": "Solid solution strengthening: solute atoms gather along dislocations and pin them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析固溶强化的基本原理，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求分析固溶强化的基本原理，涉及溶质原子与位错的相互作用机制，需要综合运用材料科学中的位错理论和强化机制知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要掌握溶质原子在位错周围的聚集行为及其对位错运动的钉扎机制。这涉及到对材料科学中位错理论和强化机理的深度理解，属于机理深度解释的层次。虽然题目提供了正确选项，但考生需要具备较高的知识整合能力和机理分析能力才能准确判断。因此，在选择题型内属于较高难度等级。" + }, + { + "idx": 1358, + "question": "Analyze the essential differences in second-phase strengthening", + "answer": "Second-phase strengthening: The dispersed strengthening phase particles force dislocations to cut through or bypass the strengthening phase particles, and the additional work required constitutes the dislocation mechanism of dispersed phase strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析第二相强化的本质差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析第二相强化的本质差异，涉及位错机制的解释和强化相颗粒对位错运动的影响，需要综合运用材料科学中的位错理论和强化机制知识，进行推理分析和机理解释。 | 难度: 在选择题型内，该题目要求考生深入理解第二相强化的微观机制，包括位错切割和绕过强化相颗粒的具体过程，以及由此产生的额外功的物理意义。这需要综合运用材料科学中的位错理论和强化机制知识，进行机理层面的深度解释和复杂现象分析。因此，该题目在选择题型内属于最高难度等级。" + }, + { + "idx": 1359, + "question": "Analyze the effect of cold deformation degree on recrystallized grain size.", + "answer": "When the cold deformation degree is less than the critical deformation degree, the grains after recrystallization basically remain in the state before cold deformation. Due to the minimal stored energy, recrystallization does not actually occur, so the cold deformation degree has no relation to the size of recrystallized grains. When the cold deformation degree increases to the critical deformation degree, the stored energy from cold deformation is sufficient to drive recrystallization. However, because the overall deformation degree is small and uneven, only a few areas with higher deformation degrees can form nuclei and grow. At this point, since $G>>N$, only a few nuclei form and rapidly grow, resulting in the largest grain size after recrystallization. Beyond the critical deformation degree, the cold deformation degree is inversely proportional to the recrystallized grain size. When the deformation degree reaches a certain level, the grain size remains essentially unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷变形程度对再结晶晶粒尺寸的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析冷变形程度对再结晶晶粒尺寸的影响，涉及多个阶段的变形程度与再结晶行为的关系，需要综合运用材料科学中的变形、储存能、再结晶形核与长大等机理进行推理分析。解答过程中不仅需要理解基本概念，还需要对不同变形程度下的再结晶行为进行详细解释和综合分析，思维深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面分析冷变形程度对再结晶晶粒尺寸的影响机理，涉及多个关键概念（临界变形度、储存能、形核率与生长速率关系等）的综合运用。正确选项不仅需要理解不同变形程度区间（低于临界、等于临界、高于临界）的物理机制差异，还需要解释G>>N条件下的晶粒生长动力学原理。这种在选择题中要求对复杂现象进行多阶段机理解释和定量关系分析的情况，属于选择题型中最具挑战性的考核形式。" + }, + { + "idx": 1361, + "question": "At what temperature or temperature range is eutectic cementite formed through what reaction? And write the reaction equation.", + "answer": "Eutectic cementite: 1148°C, eutectic reaction, L→(γ+Fe3C) eutectic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释在什么温度或温度范围内通过什么反应形成共晶渗碳体，并写出反应方程式。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对共晶反应温度范围和反应方程的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求考生记忆并准确回答共晶渗碳体的形成温度、反应类型及反应方程式，这些都是基础概念记忆性知识，无需复杂推理或分析。正确选项直接提供了所有必要信息，考生只需识别并选择匹配的选项即可。" + }, + { + "idx": 1362, + "question": "Describe the behavior and manifestations of crystal defects in metals during the cold deformation stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects at this stage.", + "answer": "Cold deformation: Crystal defects including point defects, line defects, and planar defects all increase significantly, leading to work hardening and corresponding changes in physical and chemical properties; the driving force is the externally applied resolved shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体缺陷在冷变形阶段的行为和表现，并解释驱动力的来源，需要详细的文字解释和论述。答案也是以文字形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述冷变形阶段金属中晶体缺陷的行为和表现，并解释驱动这些缺陷运动的驱动力。这需要综合运用晶体缺陷的知识，分析其在冷变形过程中的变化及其对材料性能的影响，同时还需要理解驱动力的来源。涉及多个概念的关联和深层次的机理解释，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1363, + "question": "Describe the behavior and manifestations of crystal defects in metals during the recrystallization stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects at this stage.", + "answer": "Recrystallization: Line defects significantly decrease, and the material exhibits softening; the driving force is stored energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体缺陷在金属再结晶阶段的行为和表现，并解释驱动这些缺陷运动的驱动力，需要详细的文字解释和论述。答案也提供了简要的文字解释，符合简答题的特征。 | 知识层次: 题目要求描述晶体缺陷在再结晶阶段的行为和表现，并解释驱动力的来源，这需要综合运用材料科学中的晶体缺陷理论、再结晶机制以及能量学原理，进行推理分析和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用多个复杂概念（晶体缺陷行为、再结晶阶段、材料性能变化、驱动力机制），并进行机理层面的深度解释。正确选项不仅需要识别现象（线缺陷减少、材料软化），还需准确指出背后的驱动力（储存能），这要求考生具备将微观结构演变与宏观性能关联的高级分析能力。相比单纯记忆型或单一概念应用型选择题，此类题目对知识整合和推理能力的要求显著更高，完全符合\"复杂现象全面分析\"的等级5特征。" + }, + { + "idx": 1364, + "question": "Describe the behavior and manifestations of crystal defects in metals during the grain growth stage and the corresponding material properties, and explain the driving force that promotes the movement of these crystal defects at this stage.", + "answer": "Grain growth: planar defects significantly decrease; the driving force is the total interfacial free energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体缺陷在金属晶粒生长阶段的行为和表现，以及相应的材料特性，并解释促进这些晶体缺陷移动的驱动力。这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了简短的论述性回答，符合简答题的特征。 | 知识层次: 题目要求描述晶界缺陷在晶粒生长阶段的行为和表现，并解释驱动这些缺陷运动的驱动力，这需要综合运用晶体缺陷、晶粒生长机制和热力学驱动力等多方面知识，进行推理分析和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1365, + "question": "At what temperature or temperature range is tertiary cementite formed, and through what reaction? Also, write the reaction equation.", + "answer": "Tertiary cementite: <727°C, secondary precipitation reaction, α→Fe3CIII.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释温度范围、反应类型并写出反应方程式，需要文字解释和论述，答案也是以文字形式给出具体信息。 | 知识层次: 题目考查对三级渗碳体形成温度范围及反应类型的基础概念记忆，以及反应方程式的书写，属于材料科学中相变基础知识的记忆性内容。 | 难度: 在选择题型中，该题目要求考生记忆并理解三级渗碳体的形成温度范围（<727°C）以及反应类型（二次沉淀反应），同时需要写出反应方程式（α→Fe3CIII）。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或推理过程。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 1366, + "question": "At what temperature or temperature range is primary cementite formed, and through what reaction? Also, write the reaction equation.", + "answer": "Primary cementite: >1148°C, eutectic reaction, L→Fe3C1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释温度范围、反应类型并写出反应方程式，需要文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对初级渗碳体形成温度范围、反应类型及反应方程的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生准确掌握初级渗碳体的形成温度范围（>1148°C）和共晶反应（L→Fe3C1）这两个关键知识点。这比单纯记忆定义（等级1）要求更高，但又不涉及复杂概念体系的阐述（等级3）。" + }, + { + "idx": 1367, + "question": "Analyze the fundamental differences in work hardening", + "answer": "Work hardening: Possible mechanisms include dislocation pile-up, forest dislocation resistance, and the consumption of external force work through the formation of jogs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析工作硬化的基本差异，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算 | 知识层次: 题目要求分析加工硬化的基本差异，涉及位错堆积、森林位错阻力等机制的解释，需要综合运用材料科学知识进行推理分析和机理解释，思维深度较高。 | 难度: 在选择题型中，该题目要求考生对工作硬化的多种机制（如位错堆积、森林位错阻力、外力功消耗等）有深入的理解，并能综合运用这些知识进行复杂现象的分析。这需要考生具备较高的机理解释能力和综合分析能力，属于选择题型中的高难度题目。" + }, + { + "idx": 1368, + "question": "What types of cementite may exist in iron-carbon alloys?", + "answer": "Primary cementite, eutectic cementite, secondary cementite, eutectoid cementite, tertiary cementite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举铁碳合金中可能存在的渗碳体类型，答案以文字形式给出具体分类，不需要计算或选择，属于需要文字解释的简答题类型。 | 知识层次: 题目考查铁碳合金中不同类型渗碳体的分类记忆，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 该题目属于选择题型，要求考生识别并记忆铁碳合金中可能存在的不同类型渗碳体（Primary cementite, eutectic cementite, secondary cementite, eutectoid cementite, tertiary cementite）。虽然涉及多个分类，但都属于基础概念记忆范畴，不需要复杂的分析或比较。在选择题型中，这属于中等难度，因为需要考生对材料科学中的基本分类有清晰记忆，但不需要深入理解或应用这些概念。" + }, + { + "idx": 1369, + "question": "What are the differences in morphology, size, and distribution of primary cementite?", + "answer": "Regular strip shape, coarse, distributed on the ledeburite matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和描述初级渗碳体的形态、尺寸和分布特征，答案提供了具体的文字描述而非选择或计算，符合简答题的特征。 | 知识层次: 题目考查对初级渗碳体的形态、尺寸和分布等基本特征的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确回忆并区分初级渗碳体的形态、尺寸和分布特征。正确选项提供了具体的描述（规则条状、粗大、分布在莱氏体基体上），这要求考生对相关概念有清晰的理解和记忆，而不仅仅是简单的定义复述。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1371, + "question": "At what temperature or temperature range is secondary cementite formed, and through what reaction? Also, write the reaction equation.", + "answer": "Secondary cementite: 1148~727°C, secondary precipitation reaction, γ→Fe3CII.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释二次渗碳体的形成温度范围、反应类型并写出反应方程式，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对二次渗碳体形成温度范围及反应类型的记忆，以及反应方程式的书写，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确记忆并理解二次渗碳体的形成温度范围、反应类型以及反应方程式。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1372, + "question": "What are the differences in morphology, size, and distribution of eutectic cementite?", + "answer": "Acts as the continuous matrix of ledeburite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述共晶渗碳体的形态、尺寸和分布差异，需要详细的文字描述，而不是选择、判断或计算。 | 知识层次: 题目要求对共晶渗碳体的形态、尺寸和分布差异进行描述，这需要理解共晶渗碳体的基本概念，并将其与莱氏体的连续基体相关联。这涉及到多个概念的关联和综合分析，超出了单纯的基础概念记忆，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及对共晶渗碳体的形态、尺寸和分布差异的综合理解，并需要将这一概念与莱氏体的连续基体作用联系起来。虽然不需要多步计算，但要求考生能够将多个材料科学概念进行关联分析，这超出了简单记忆的范畴，属于中等应用层次的知识要求。" + }, + { + "idx": 1374, + "question": "What are the differences in morphology, size, and distribution of tertiary cementite?", + "answer": "Discontinuous granular, small amount, distributed at ferrite grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释三级渗碳体的形态、尺寸和分布差异，答案以文字描述的形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对三级渗碳体的形态、尺寸和分布等基本概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生对三级渗碳体的形态、尺寸和分布有基本的理解和记忆。虽然涉及多个特征（形态、尺寸、分布），但都属于基础概念记忆范畴，且正确选项提供了明确的描述，不需要复杂的分析或比较。因此属于中等难度。" + }, + { + "idx": 1375, + "question": "What effect does eutectic cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness but reduces toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释共晶渗碳体对铁碳合金机械性能的影响，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目需要理解共晶渗碳体对铁碳合金机械性能的影响，涉及多个概念的关联（硬度与韧性的关系）和综合分析（共晶渗碳体的作用机制），但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解共晶渗碳体对铁碳合金机械性能的影响，并能够关联硬度和韧性的变化关系。虽然不涉及多步计算，但需要对材料科学中的基本概念有较好的掌握，并能进行简单的综合分析。" + }, + { + "idx": 1376, + "question": "What are the differences in morphology, size, and distribution of secondary cementite?", + "answer": "It is distributed at the original austenite grain boundaries that have transformed into pearlite. When the amount is small, it appears as discontinuous granular; when the amount is large, it forms a continuous network.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述二次渗碳体的形态、尺寸和分布差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对二次渗碳体的形态、尺寸和分布进行描述和分析，涉及多个概念的关联和综合分析，需要理解材料微观结构的变化及其影响因素，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解二次渗碳体的形态、尺寸和分布特征，还需要将这些特征与原始奥氏体晶界转变为珠光体的过程关联起来。此外，题目还要求考生能够根据渗碳体数量的不同（少量或大量）分析其呈现的不同形态（不连续颗粒状或连续网状）。这种多角度分析和概念关联的要求使得该题目在选择题型中具有较高的难度。" + }, + { + "idx": 1377, + "question": "What effect will primary cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness but reduces toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释初级渗碳体对铁碳合金机械性能的影响，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求理解初生渗碳体对铁碳合金机械性能的影响，涉及硬度与韧性的变化关系，需要综合分析材料微观组织与宏观性能的关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解初级渗碳体对铁碳合金机械性能的影响，并能够关联硬度和韧性的变化。虽然题目涉及多步概念关联和综合分析，但在选择题型中，正确选项直接给出了明确的结论，减少了推理的复杂性。因此，相对于更复杂的多角度分析或深度关联性分析题目，此题难度适中。" + }, + { + "idx": 1379, + "question": "What effect will tertiary cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness and strength but reduces toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述第三渗碳体对铁碳合金机械性能的影响，答案提供了文字解释而非选择或判断 | 知识层次: 题目需要理解三次渗碳体对铁碳合金机械性能的影响，涉及多个概念（硬度、强度、韧性）的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及铁碳合金中三次渗碳体对机械性能的影响，要求考生掌握渗碳体的基本特性及其对硬度、强度和韧性的不同作用机制。虽然不需要多步计算，但需要综合分析不同性能指标的变化趋势，属于概念关联和综合分析层次。" + }, + { + "idx": 1380, + "question": "What effect does secondary cementite have on the mechanical properties of iron-carbon alloys?", + "answer": "Increases hardness but reduces toughness; discontinuous granular form enhances strength, while continuous network form reduces strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释二次渗碳体对铁碳合金机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解二次渗碳体对铁碳合金力学性能的影响，涉及多个概念的关联和综合分析，如硬度、韧性、强度等，并需要解释不同形态（不连续粒状和连续网状）对性能的具体影响。这超出了基础概念的记忆，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解二次渗碳体对铁碳合金机械性能的影响，还需要区分不同形态（不连续颗粒状和连续网状）对强度的具体影响。这涉及多步概念关联和综合分析，超出了单纯记忆或简单应用的水平。" + }, + { + "idx": 1381, + "question": "Using dislocation theory, explain one of the reasons for work hardening in pure metal single crystals.", + "answer": "Dislocation intersections occur, and the resulting jogs impede dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释纯金属单晶加工硬化的原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求运用位错理论解释纯金属单晶加工硬化的原因，涉及位错相互作用和运动阻碍的机理分析，需要综合理解和推理能力，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生运用位错理论解释纯金属单晶体的加工硬化现象，涉及复杂的机理分析和推理过程。正确选项需要理解位错交叉和位错运动受阻的微观机制，这要求考生具备深入的材料科学知识和综合分析能力。在选择题型中，这种需要综合运用多个高级概念并解释复杂现象的题目属于最高难度级别。" + }, + { + "idx": 1382, + "question": "What is the phenomenon of work hardening in metals?", + "answer": "The phenomenon where the applied flow stress continuously increases with the increase of strain during the plastic deformation of metallic materials is called work hardening. Alternatively, the phenomenon where the strength and hardness of metallic materials increase, while the plasticity and toughness decrease after cold plastic deformation, is called work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"work hardening\"现象进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即工作硬化现象的定义和基本特征，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"work hardening\"的基本定义和现象描述，但不需要进行复杂的比较分析或推导。正确选项提供了清晰的概念解释，属于基础概念记忆层次，符合选择题型中等级2的难度标准。" + }, + { + "idx": 1383, + "question": "Using dislocation theory, what is the second reason for the work hardening of pure metal single crystals?", + "answer": "Dislocation reactions occur, forming immobile dislocations that hinder dislocation motion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过位错理论解释纯金属单晶加工硬化的第二个原因，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求运用位错理论解释纯金属单晶加工硬化的第二个原因，涉及位错反应形成不可动位错并阻碍位错运动的机理。这需要深入理解位错理论，并能将理论知识与实际现象关联起来进行分析和解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生运用位错理论深入分析纯金属单晶加工硬化的第二个原因，涉及位错反应形成不可动位错并阻碍位错运动的复杂机理。这需要考生不仅掌握位错理论的基本概念，还要能够综合运用知识进行机理层面的解释和分析。在选择题型中，这种需要深度理解和复杂推理的题目属于最难的一类。" + }, + { + "idx": 1385, + "question": "Critical deformation degree", + "answer": "Critical deformation degree is the minimum pre-cold deformation required for metal to undergo recrystallization at a given temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Critical deformation degree\"这一概念进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查对\"临界变形度\"这一基础概念的定义记忆和理解，属于材料科学中金属再结晶的基本原理范畴，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并描述“Critical deformation degree”的定义及其在金属再结晶中的作用。这比简单的定义记忆（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1386, + "question": "What are the beneficial aspects of the work hardening characteristics of metals for the use of metal materials?", + "answer": "As a means to improve the strength of metal materials; facilitating the plastic forming of metal materials; enabling metal parts to resist accidental overload.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属材料加工硬化特性的有益方面，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属加工硬化特性的有益方面，涉及对金属材料强度提升、塑性成形和抗过载能力的综合分析。虽然不需要复杂的计算或深度机理分析，但需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属加工硬化的多个有益方面，包括提高强度、促进塑性成形和抵抗意外过载，并进行综合分析。虽然题目涉及多个概念，但在选择题型中，正确选项已经提供了明确的答案方向，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1387, + "question": "Unit cell", + "answer": "The unit cell is the most basic unit that constitutes a crystal lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"unit cell\"进行文字解释和论述，答案是一个定义性的陈述，符合简答题的特征 | 知识层次: 题目考查的是晶体学中最基本的单元——晶胞的定义，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"unit cell\"这一基础概念的定义记忆，属于最基础的知识点掌握要求。正确选项直接给出了晶体点阵最基本组成单元的定义，无需任何解释、分析或比较步骤，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1388, + "question": "Calculate the coordination number of the cation in the compound MgO, given r(Mg2+)=0.078nm, r(O2-)=0.132nm", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数值进行计算，以确定MgO中阳离子的配位数。解答过程需要应用半径比规则进行数值计算，最终得出具体的数值答案（6）。 | 知识层次: 题目要求根据给定的离子半径计算配位数，属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算MgO中阳离子的配位数，仅需根据给定的离子半径比值（r+/r-）直接套用配位数与半径比的关系表即可得出答案。无需多个公式组合或复杂计算步骤，属于基础知识的简单应用。" + }, + { + "idx": 1389, + "question": "Using dislocation theory, what is the third reason for the work hardening of pure metal single crystals?", + "answer": "Dislocation multiplication occurs, and the increase in dislocation density further enhances the resistance to dislocation motion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释纯金属单晶加工硬化的第三个原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求运用位错理论解释纯金属单晶加工硬化的第三个原因，涉及位错增殖和位错密度增加对位错运动阻力的影响。这需要深入理解位错理论，并能将理论知识与实际现象（加工硬化）进行关联和解释，属于机理层面的分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握位错理论的基本概念，还需要深入理解金属单晶加工硬化的复杂机理。正确选项涉及位错增殖和密度增加对位错运动阻力的影响，这需要考生具备综合运用知识、进行推理分析和机理解释的能力。这种题目在选择题中属于对知识深度和综合分析能力要求极高的类型，因此评为等级5。" + }, + { + "idx": 1391, + "question": "Unit dislocation", + "answer": "A unit dislocation is a dislocation whose Burgers vector equals a lattice vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Unit dislocation\"进行文字解释和论述，答案是一个定义性的陈述，符合简答题的特征 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是单位位错的定义及其Burgers矢量的特征。这属于材料科学中晶体缺陷的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察对\"unit dislocation\"这一基础概念的记忆，即其Burgers vector等于晶格矢量的定义。题目不涉及任何解释、比较或分析过程，属于最基础的定义简答类型，因此难度等级为1。" + }, + { + "idx": 1392, + "question": "What are the adverse effects of the work hardening characteristics of metals on the use of metal materials?", + "answer": "It makes the metal difficult to undergo further cold plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属加工硬化特性的不利影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属加工硬化特性对金属材料使用的不利影响，涉及对加工硬化概念的理解及其在实际应用中的影响分析。虽然需要一定的概念记忆，但更侧重于将概念与实际应用场景关联起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属加工硬化的特性及其对材料使用的影响，并进行综合分析。题目要求考生将金属的加工硬化特性与冷塑性变形的难度联系起来，这涉及多个概念的关联和一定程度的综合分析能力。" + }, + { + "idx": 1393, + "question": "Calculate the coordination number of the cation in the compound Cr2O3, given r(Cr3+)=0.064nm, r(O2-)=0.132nm", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（离子半径比）来确定配位数，答案是一个具体的数值结果（6），符合计算题的特征。 | 知识层次: 题目要求计算Cr2O3中阳离子的配位数，涉及离子半径比的计算和配位数判断，属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单公式应用计算难度。题目要求计算Cr2O3中阳离子的配位数，给出了Cr3+和O2-的离子半径，可以直接应用配位数与离子半径比的关系公式进行计算。虽然需要记忆和理解配位数与半径比的关系，但计算过程简单直接，属于基本公式应用和简单计算的范畴。" + }, + { + "idx": 1394, + "question": "Calculate the coordination number of the cation in the compound CaF2, given r(Ca2+)=0.106nm and r(F-)=0.133nm", + "answer": "8", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数值计算CaF2中阳离子的配位数，涉及数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目要求应用离子半径比公式计算配位数，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了离子半径数据，并直接要求计算配位数，只需应用简单的半径比公式即可得出答案。无需多个公式组合或复杂分析，属于最基础的计算类型。" + }, + { + "idx": 1395, + "question": "Calculate the coordination number of the cation in the compound K2O, given r(K+)=0.132nm, r(O2-)=0.132nm", + "answer": "12", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数据进行数值计算，应用相关公式来确定配位数，最终答案为具体的数值结果。 | 知识层次: 题目涉及基本的离子半径比计算和配位数的确定，属于直接套用公式和简单计算的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用半径比公式计算配位数，属于单一公式直接计算的简单题目。题目中已经给出了离子半径，只需套用半径比规则即可得出答案，无需复杂分析或组合多个公式。" + }, + { + "idx": 1396, + "question": "Determine whether the following statement is correct: After recovery annealing of cold-deformed metal, its mechanical properties can return to the state before deformation.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征 | 知识层次: 题目考查对冷变形金属在恢复退火后机械性能变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆金属材料冷变形和再结晶退火后的性能变化这一基本原理即可作答。在选择题型中，这类仅需识别定义或基本原理正确与否的题目属于最低难度等级。" + }, + { + "idx": 1397, + "question": "What basic conditions must be met for atomic diffusion in solids?", + "answer": "Atomic diffusion in solids requires the presence of a chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释原子扩散在固体中的基本条件，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查原子扩散的基本条件，属于基本原理的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅考察对原子扩散基本条件的记忆，属于基础概念的直接复现。正确选项明确给出了定义性答案，无需复杂推理或概念比较，符合等级1\"基本定义简答\"的特征。选择题型中此类题目只需识别关键词\"chemical potential gradient\"即可作答，属于难度最低的认知层次。" + }, + { + "idx": 1398, + "question": "According to the concentration distribution of the diffusing component, what are the basic types of diffusion?", + "answer": "Self-diffusion and interdiffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的基本类型，答案需要文字描述（Self-diffusion and interdiffusion），属于简答题的特征 | 知识层次: 题目考查扩散基本类型的记忆和理解，属于基础概念的分类范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求识别扩散的基本类型（自扩散和互扩散），属于基础概念记忆的简单题目。学生只需记住这两个分类即可正确作答，无需进行概念解释或复杂分析。" + }, + { + "idx": 1399, + "question": "Determine whether the following statement is correct: Edge dislocations can undergo cross-slip.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个陈述的正确性（\"Edge dislocations can undergo cross-slip\"），并且给出了明确的判断结果（\"Incorrect\"）。这符合判断题的特征，即只需要判断陈述的对错，而不需要选择、计算或详细解释。 | 知识层次: 题目考查对位错基本行为（边缘位错的交滑移能力）这一基础概念的记忆和理解，属于材料科学中晶体缺陷的基础知识范畴。 | 难度: 该题目属于基础概念正误判断，仅需记忆边缘位错的基本特性即可作答。在选择题型中属于最简单的难度等级，不需要复杂分析或概念间的比较。" + }, + { + "idx": 1400, + "question": "According to the path of atomic diffusion, what are the basic types of diffusion?", + "answer": "Bulk diffusion, grain boundary diffusion, dislocation diffusion, surface diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举原子扩散的基本类型，答案以文字形式给出，需要简要解释和论述不同扩散类型的特点。 | 知识层次: 题目考查原子扩散路径的基本类型，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆和识别基本的扩散类型，属于基础概念记忆层次。题目直接给出正确选项，无需复杂推理或比较分析，解题步骤简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 1401, + "question": "Determine whether the following statement is correct: The distinction between hot (deformation) working and cold (deformation) working of metals is based on the temperature of the deformation process.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了正确或错误的结论，符合判断题的特征。 | 知识层次: 题目考查对金属热加工和冷加工区分标准的基本概念记忆，属于定义性知识的判断。 | 难度: 该题目属于基础概念正误判断，仅需记忆热加工和冷加工的定义区别即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1402, + "question": "Determine whether the following statement is correct: Recrystallization is a process of nucleation and core growth, therefore it is a phase transformation process.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征 | 知识层次: 题目考查对再结晶过程是否属于相变过程这一基本概念的理解和判断，属于基础概念的记忆和辨析范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆并识别\"再结晶\"的基本定义和特性即可作答。在选择题型中，这类直接考察定义记忆的题目属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 1403, + "question": "Determine whether the following statement is correct: The growth of recrystallization nuclei is accompanied by the movement of grain boundaries, so the driving force is grain boundary energy.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征。 | 知识层次: 题目涉及再结晶核生长和晶界移动的驱动力的判断，需要理解再结晶过程中的能量变化和晶界行为，属于概念关联和综合分析的中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析再结晶核生长过程中的驱动力来源，并正确判断晶界能并非主要驱动力。题目涉及中等应用层次的知识点关联和多步概念判断，要求考生区分表面能、应变能和晶界能等不同驱动力的作用机制。" + }, + { + "idx": 1404, + "question": "According to the microscopic mechanism of diffusion, what are the basic types of diffusion?", + "answer": "Interstitial diffusion and vacancy diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的基本类型，答案需要文字描述和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查扩散机制的基本类型，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆类型，仅需要学生回忆扩散机制的基本分类（间隙扩散和空位扩散）。在选择题型中，这类直接考察定义或分类的题目属于最简单级别，不需要解释或分析过程，只需识别正确选项即可。" + }, + { + "idx": 1405, + "question": "Determine whether the following statement is correct: Point defects in crystals are a type of thermodynamic equilibrium defect, while dislocations are not thermodynamic equilibrium defects.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Correct\"，符合判断题的特征 | 知识层次: 题目考查对晶体缺陷类型及其热力学平衡性质的基本概念记忆和理解，属于基础概念层次 | 难度: 该题目属于基本概念正误判断，仅需记忆点缺陷和位错的热力学平衡特性即可作答。在选择题型中属于最简单的直接概念判断，无需复杂分析或推理过程。" + }, + { + "idx": 1406, + "question": "According to the relationship between the diffusion direction of components and their concentration gradient direction, what are the basic types of diffusion?", + "answer": "Downhill diffusion and uphill diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的基本类型，需要文字解释和论述，答案形式为简短的文字描述而非选择或计算。 | 知识层次: 题目考查扩散基本类型的记忆和理解，属于基础概念的分类问题，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并区分扩散的基本类型（下坡扩散和上坡扩散），属于基础概念的直接回忆。题目不涉及概念解释或复杂分析，仅需识别正确分类即可，因此属于最简单的难度等级1。" + }, + { + "idx": 1407, + "question": "According to whether new phases are formed during diffusion, what are the basic types of diffusion?", + "answer": "Single-phase diffusion and reactive diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的基本类型，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查扩散基本类型的记忆和理解，属于基础概念分类范畴 | 难度: 在选择题型中，该题目仅考察对扩散基本类型的记忆，属于最基础的定义简答级别。学生只需识别并选择\"单相扩散\"和\"反应扩散\"这两个分类术语，无需进行概念解释或复杂分析，符合等级1对基础概念记忆的要求。" + }, + { + "idx": 1408, + "question": "In interstitial solid solutions, by what mechanism do solute atoms diffuse?", + "answer": "In interstitial solid solutions, solute atoms diffuse by the interstitial mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述扩散机制，答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体中溶质原子扩散机制的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"间隙固溶体中溶质原子的扩散机制\"。正确选项直接给出了定义性的答案，不需要任何解释或分析步骤。这属于最基本的概念记忆题，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1409, + "question": "In substitutional solid solutions, by what mechanism do solute atoms diffuse?", + "answer": "In substitutional solid solutions, solute atoms diffuse by the vacancy mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述溶质原子在置换固溶体中的扩散机制，答案提供了详细的文字说明而非选择、判断或计算。 | 知识层次: 题目考查对置换固溶体中溶质原子扩散机制的基本概念记忆，即空位机制的理解和表述，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的定义和基本原理，即溶质原子在置换固溶体中的扩散机制。题目直接给出了正确选项，无需进行复杂的分析或比较，属于最基础的定义简答类型。" + }, + { + "idx": 1410, + "question": "What type of diffusion is the growth of uniform austenite grains?", + "answer": "The growth of uniform austenite grains belongs to self-diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述扩散类型，答案是一个简短的文字解释，不需要计算或选择选项 | 知识层次: 题目考查对扩散类型的基本分类和定义的理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即对自扩散定义的直接识别。无需解释或比较其他扩散类型，解题步骤简单，属于最基础的知识点掌握要求。" + }, + { + "idx": 1411, + "question": "What type of diffusion does the homogenization of intracrystalline segregation during diffusion annealing belong to?", + "answer": "The homogenization of intracrystalline segregation during diffusion annealing belongs to interdiffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对扩散退火过程中晶内偏析的均匀化类型进行解释，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查扩散类型的基本概念记忆和理解，属于对基础分类知识的直接问答 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即对\"interdiffusion\"这一术语的定义和分类的直接回忆。题目不需要解释或描述概念，更不需要分析复杂概念体系，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1412, + "question": "By what mechanism do metal materials conduct heat?", + "answer": "Metal materials mainly conduct heat through free electrons", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属材料导热的具体机制，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查金属材料导热的基本机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆层次，仅需识别金属导热的主要机制是自由电子这一基本定义。在选择题型中，这是最基础的知识点考察，不需要解释或分析，只需从选项中识别正确的基本原理表述。" + }, + { + "idx": 1413, + "question": "Will thermoplastic with a lower glass transition temperature (Tg) exhibit 'work hardening' after deformation? Please briefly explain.", + "answer": "Thermoplastics with a lower glass transition temperature will exhibit 'work hardening' after deformation. This is because as the degree of deformation increases, the molecular chains gradually align along the direction of the external force, leading to strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对现象进行解释和论述，答案提供了详细的文字说明来解释为什么具有较低玻璃化转变温度的热塑性塑料在变形后会表现出“加工硬化”现象。这符合简答题的特征，即需要文字解释和论述。 | 知识层次: 题目要求解释热塑性塑料在变形后表现出的\"加工硬化\"现象，需要理解玻璃化转变温度与分子链排列之间的关系，并能够将这两个概念关联起来进行分析。虽然不涉及复杂计算，但需要对材料行为进行一定程度的机理解释和综合分析。 | 难度: 在选择题中属于中等难度，需要理解玻璃化转变温度（Tg）与热塑性塑料变形行为之间的关系，并能够将分子链排列与应变硬化现象进行关联分析。题目要求考生不仅掌握基础概念，还需要进行一定程度的综合推理。" + }, + { + "idx": 1414, + "question": "What is the electron magnetic moment?", + "answer": "The electron magnetic moment refers to the orbital magnetic moment generated by the electron's motion around the nucleus and the spin magnetic moment produced by the electron's spin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"electron magnetic moment\"进行文字解释和论述，答案提供了概念的定义和组成要素，属于需要文字说明的简答题类型。 | 知识层次: 题目考查电子磁矩的基本定义和组成，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然涉及电子磁矩的两个组成部分（轨道磁矩和自旋磁矩），但仅要求考生记忆并识别定义层面的内容，不需要进行复杂的概念体系阐述或比较分析。题目正确选项直接给出了完整定义，符合选择题型中对基础概念记忆的要求。" + }, + { + "idx": 1415, + "question": "Will ceramic materials exhibit 'work hardening' after deformation? Please briefly explain.", + "answer": "Ceramic materials will not exhibit 'work hardening' after deformation, because ceramic materials cannot undergo plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对陶瓷材料是否表现出“加工硬化”进行简要解释，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对陶瓷材料变形行为的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求考生记忆并识别陶瓷材料的基本特性（无法塑性变形），不需要进行概念解释或复杂分析。正确选项直接给出了定义性结论，属于最基础的概念记忆层次。" + }, + { + "idx": 1416, + "question": "By what mechanism do polymer materials conduct heat?", + "answer": "Polymer materials mainly conduct heat through molecular conduction", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料导热的具体机制，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查聚合物材料导热机制的基本概念，属于基本原理的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对聚合物导热机制的基础概念记忆，属于最基础的定义简答级别。正确选项直接给出了明确的定义性答案，不需要进行概念解释或复杂分析，符合等级1的简单记忆性知识要求。" + }, + { + "idx": 1417, + "question": "What conditions must be satisfied for spontaneous dislocation reactions?", + "answer": "Geometric conditions and energy conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释自发位错反应必须满足的条件，答案以文字形式给出，需要简要论述几何条件和能量条件。 | 知识层次: 题目考查对位错反应自发条件的基本概念记忆，仅需回答几何条件和能量条件这两个分类要点，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆基本的定义和分类（几何条件和能量条件），属于最基础的概念记忆层面。不需要进行概念解释或复杂体系阐述，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1418, + "question": "What is atomic magnetic moment?", + "answer": "Atomic magnetic moment refers to the total magnetic moment composed of the orbital magnetic moment and the spin magnetic moment of electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"atomic magnetic moment\"进行文字解释和论述，答案提供了概念的定义和组成要素，符合简答题的特征 | 知识层次: 题目考查原子磁矩的基本定义和组成，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆，但需要考生理解并区分\"轨道磁矩\"和\"自旋磁矩\"这两个概念，并能正确组合它们的定义。这比单纯记忆一个简单定义(等级1)要求更高，但又不涉及复杂的概念体系阐述(等级3)。题目正确选项提供了完整的概念解释，符合选择题型中对概念解释和描述的要求。" + }, + { + "idx": 1419, + "question": "The bonding type of a material determines the level of its elastic modulus. What type of bond predominates in oxide ceramic materials, how strong is the bonding, and thus how is their elastic modulus?", + "answer": "Oxide ceramic materials are predominantly ionic bonded, with strong bonding, hence their elastic modulus is relatively high.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要解释和论述氧化物陶瓷材料的主要键合类型、键合强度及其对弹性模量的影响，答案以文字形式给出，没有选项或计算要求。 | 知识层次: 题目考查对氧化物陶瓷材料中主要键合类型及其对弹性模量影响的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（材料键合类型和弹性模量的关系），但需要考生理解并关联多个知识点：氧化物陶瓷的主要键合类型、键合强度与弹性模量的关系。这超出了单纯的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 1420, + "question": "What is the difference in the conduction mechanisms between intrinsic semiconductors and doped semiconductors?", + "answer": "In intrinsic semiconductors, the charge carriers participating in conduction are electrons in the conduction band and an equal number of holes in the valence band, with the Fermi level located at the center of the band gap. In doped semiconductors, the charge carriers participating in conduction are electrons in the conduction band and an unequal number of holes in the valence band, with the Fermi level not located at the center of the band gap—either shifting upward (as in $\\mathbf{n}$-type semiconductors) or downward (as in p-type semiconductors).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述本征半导体和掺杂半导体的导电机制差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查半导体导电机制的基本概念，包括本征半导体和掺杂半导体的区别，以及费米能级的位置变化。这些内容属于材料科学中的基础概念记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解并记忆本征半导体和掺杂半导体的基本定义，还需要掌握它们的导电机理差异，包括载流子类型、数量关系以及费米能级位置的变化。这涉及到多个概念的比较和综合分析，超出了简单的定义记忆或单一概念解释的范畴。" + }, + { + "idx": 1421, + "question": "The type of bonding in a material determines the level of its elastic modulus. What type of bond is present along the molecular chains of polymer materials, and what type of bond exists between the molecular chains, hence how is their elastic modulus?", + "answer": "The bonds along the molecular chains of polymer materials are covalent bonds, and the bonds between the molecular chains are molecular bonds, hence their elastic modulus is the lowest.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物材料中分子链内和分子链间的键类型及其对弹性模量的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对聚合物材料中键合类型及其对弹性模量影响的基础概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（聚合物材料的键类型和弹性模量），但需要考生同时掌握两种不同的键类型（分子链内的共价键和分子链间的分子键）及其对材料性能的影响。这比单纯记忆单一概念的定义（等级1）要求更高，但不需要进行复杂的概念体系阐述或比较分析（等级3）。" + }, + { + "idx": 1422, + "question": "What is the relationship between the magnetic properties of a substance and the filling of electrons outside the atomic nucleus?", + "answer": "Substances with completely filled electron shells in atoms are diamagnetic; substances with unfilled electron shells in atoms are paramagnetic or ferromagnetic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释电子填充与物质磁性的关系，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对物质磁性与电子填充状态之间关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。题目要求考生理解并记忆物质磁性与电子填充状态之间的关系，涉及基础概念的记忆和分类。虽然需要掌握一定的基本原理，但不需要复杂的分析或推理步骤，属于中等偏下的难度水平。" + }, + { + "idx": 1423, + "question": "Write the names and reaction formulas of all possible three-phase equilibrium reactions in a binary phase diagram.", + "answer": "Eutectic reaction: $\\\\operatorname{L}{\\\\overrightarrow{\\\\longrightarrow}}\\\\alpha+\\\\beta$ Eutectoid reaction: $\\\\gamma\\\\mathrm{=}\\\\mathrm{=}\\\\alpha+\\\\beta$ Monotectic reaction: $\\\\mathrm{L}_{1}\\\\longrightarrow\\\\mathrm{L}_{2}+\\\\updelta$ Syntectic reaction: $\\\\updelta\\\\rightleftharpoons\\\\mathbf{L}+\\\\upgamma$ Peritectic reaction: $\\\\mathbf{L}+\\\\alpha{\\\\stackrel{\\\\rightharpoonup}{\\\\longrightarrow}}\\\\beta$ Peritectoid reaction: $\\\\gamma+\\\\alpha{\\\\stackrel{\\\\textstyle}{\\\\longrightarrow}}\\\\beta$ Syntectic reaction: $\\\\mathrm{L}_{1}+\\\\mathrm{L}_{2}\\\\stackrel{\\\\rightharpoonup}{\\\\longrightarrow}\\\\delta$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出所有可能的三相平衡反应名称和反应式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对二元相图中三相平衡反应类型及其反应式的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生记忆并区分多种三相平衡反应的类型及其对应的反应公式。虽然涉及多个概念，但主要是基础概念的记忆和分类，不需要复杂的分析或推理。题目难度属于中等，因为需要考生掌握不同类型反应的定义和公式，但不需要深入理解或应用这些概念。" + }, + { + "idx": 1424, + "question": "By what mechanism do ceramic materials conduct heat?", + "answer": "Ceramic materials primarily conduct heat through phonons", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释陶瓷材料传导热量的机制，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查陶瓷材料导热机制的基本概念，仅需记忆和理解\"phonons\"这一基本原理即可回答，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，此题仅需记忆陶瓷材料导热的基本机制（声子传导），属于最基础的定义性知识。题目不涉及概念解释或复杂体系分析，只需识别正确选项即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1425, + "question": "What is an extended dislocation? Please give an example.", + "answer": "A dislocation configuration consisting of two partial dislocations and a stacking fault sandwiched between them. For example, in face-centered cubic crystals, $\\\\frac{a}{6}$ [121] $^+$ stacking fault $+{\\\\frac{a}{6}}$ [211].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是扩展位错并给出一个例子，答案提供了详细的文字解释和具体实例，符合简答题的特征。 | 知识层次: 题目考查对扩展位错这一基本概念的定义记忆和简单理解，仅需描述其构成并举例说明，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生不仅记忆扩展位错的基本定义，还需要理解其具体构成（两个部分位错和中间的堆垛层错）并能举例说明（如面心立方晶体中的具体例子）。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的深度（等级3），因此属于概念解释和描述的中等难度（等级2）。" + }, + { + "idx": 1426, + "question": "What is the intrinsic magnetic moment of a substance?", + "answer": "The intrinsic magnetic moment of a substance refers to the sum of all atomic magnetic moments in the absence of an external magnetic field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"intrinsic magnetic moment\"进行文字解释和论述，答案是一个定义性的陈述，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查对\"本征磁矩\"这一基本概念的定义和记忆，属于基础概念的理解层面，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅要求记忆和识别“内在磁矩”的基本定义，属于最基础的概念记忆层次。正确选项直接给出了定义，无需进行任何解释或分析，解题步骤极为简单，符合等级1“基本定义简答”的标准。" + }, + { + "idx": 1427, + "question": "Which is the most closely packed plane in a face-centered cubic crystal?", + "answer": "111", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个可能的晶体平面中选择最紧密堆积的平面，虽然题目中没有明确列出选项，但这类问题通常是在给定的选项中进行选择，答案\"111\"是一个特定的选项。 | 知识层次: 题目考查对晶体结构中最密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆类型。学生只需记住面心立方晶体中最密排面是(111)面这一基本事实即可作答，无需进行复杂的概念辨析或深度理解。" + }, + { + "idx": 1428, + "question": "What is the most close-packed direction in a face-centered cubic crystal?", + "answer": "<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的晶体学方向，答案是一个具体的晶体学指数<110>，不需要计算或选择，属于需要直接回答的简答题类型。 | 知识层次: 题目考查对晶体结构中密排方向的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察对最密排方向的基础概念记忆，属于最基础的定义简答级别。学生只需记住面心立方晶体中最密排方向是<110>即可作答，不需要进行任何解释或复杂分析。" + }, + { + "idx": 1429, + "question": "The type of bonding in a material determines the level of its elastic modulus. What type of bond predominates in metallic materials, how strong is the bonding, and consequently, what is their elastic modulus like?", + "answer": "Metallic materials are primarily bonded by metallic bonds, which are relatively weak, resulting in a lower elastic modulus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要解释金属材料中的主要键合类型、键合强度及其对弹性模量的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查金属材料中主要键合类型及其对弹性模量的影响，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接询问金属材料的主要键合类型、键合强度及其对弹性模量的影响，正确选项仅需记忆金属键的基本特性（相对较弱，导致较低的弹性模量），无需额外推理或跨概念整合。知识点明确且单一，符合等级1对「基础概念记忆」的要求。" + }, + { + "idx": 1430, + "question": "Which is the most closely packed plane of a body-centered cubic crystal?", + "answer": "110", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个可能的晶体平面中选择最紧密排列的平面，答案\"110\"是其中一个特定选项 | 知识层次: 题目考查对体心立方晶体最密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆体心立方晶体最密排面的定义即可选出正确答案110。不需要进行概念辨析或复杂分析，符合等级1的简单概念识别标准。" + }, + { + "idx": 1431, + "question": "The commonly used method to refine grains in casting processes is (19)", + "answer": "(19) Increasing the cooling rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个简短的具体答案（\"Increasing the cooling rate\"），而不是从多个选项中选择或判断对错，也不需要计算或详细论述。 | 知识层次: 题目考查的是铸造过程中细化晶粒的常用方法，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆并识别铸造过程中细化晶粒的常用方法。题目仅涉及单一知识点（冷却速率与晶粒尺寸的关系），无需复杂分析或概念比较，属于最基础的难度等级。" + }, + { + "idx": 1432, + "question": "What is the most densely packed direction in a body-centered cubic crystal?", + "answer": "<111>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答最密排方向的具体指数，需要专业知识解释和论述，答案形式为晶体学方向指数而非简单选择或判断 | 知识层次: 题目考查对体心立方晶体中最密排方向的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接考查对体心立方晶体最密排方向的记忆，正确选项<111>是晶体学中的基础知识点，不需要任何解释或分析步骤。学生只需记住这个基本概念即可作答，符合选择题型中最简单的难度等级。" + }, + { + "idx": 1433, + "question": "What is the most closely packed direction in a hexagonal close-packed crystal?", + "answer": "<1120>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的晶体学方向，需要专业知识来识别和表述，答案是一个具体的晶体学方向指标（<1120>），而不是从多个选项中选择或简单的对错判断，也不需要复杂的计算过程。 | 知识层次: 题目考查对六方密堆积晶体中最密排方向的基本概念记忆，属于晶体学基础知识的直接回忆 | 难度: 在选择题型中，该题目仅要求记忆六方密堆积晶体中最密排方向的基本定义，属于基础概念记忆层次。题目仅需直接回忆特定知识点（<1120>方向），无需解释或复杂分析，因此属于最简单的难度等级。" + }, + { + "idx": 1434, + "question": "A metal with finer grains has (16)_ strength and hardness compared to the same metal with coarser grains", + "answer": "(16) higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（higher）来补全句子，属于需要简短文字回答的类型，没有提供选项供选择，也不涉及计算或判断对错 | 知识层次: 题目考查对晶粒尺寸与金属强度、硬度关系的基本概念记忆和理解，属于材料科学中的基础知识点。 | 难度: 该题目属于基础概念记忆类型，仅需记住\"晶粒尺寸越小，金属强度和硬度越高\"这一基本原理即可作答。在选择题型中属于最简单的直接知识回忆类题目，无需任何分析或推理步骤。" + }, + { + "idx": 1435, + "question": "Ferrite is a solid solution of carbon in what type of iron?", + "answer": "α", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的术语（α铁），不需要从多个选项中选择，也不需要计算或判断对错，属于简答题类型。 | 知识层次: 题目考查对铁素体（Ferrite）基本定义的记忆，即碳在α铁中的固溶体。这属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别铁素体是碳在α铁中的固溶体这一基本定义。选择题型中只需选择正确选项\"α\"，无需复杂推理或多概念比较，属于最基础的定义简答难度。" + }, + { + "idx": 1436, + "question": "Metals with finer grains have _ (17) plasticity and toughness than the same metals with coarser grains", + "answer": "(17) better", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（better）来补全句子，属于简答题类型，需要根据材料科学知识进行简短回答 | 知识层次: 题目考查金属晶粒尺寸与塑性、韧性关系的基本概念记忆，属于材料科学中最基础的知识点，仅需记忆和理解即可作答。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即金属晶粒尺寸与塑性、韧性关系的简单事实。无需解释或分析，只需识别正确选项\"better\"即可。属于最基础的定义简答级别。" + }, + { + "idx": 1437, + "question": "Which is the most closely packed plane in a hexagonal close-packed crystal?", + "answer": "(0001)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别并写出最密排面的晶面指数，答案是一个具体的晶面指数(0001)，不需要计算或选择，属于需要特定知识回答的简答题 | 知识层次: 题目考查对六方密堆积晶体中最密排面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需要考生记住六方最密堆积晶体中最密排面的晶面指数(0001)这一基本事实。题目不涉及概念解释或复杂分析，属于最简单的记忆性知识考查。" + }, + { + "idx": 1438, + "question": "The commonly used method for refining grains in casting processes is (20)", + "answer": "(20) Adding nucleating agents", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个简短的答案（Adding nucleating agents），而不是从多个选项中选择或进行判断或计算。 | 知识层次: 题目考查的是铸造过程中细化晶粒的常用方法，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答级别。题目直接考察对铸造工艺中晶粒细化常用方法的记忆，仅需识别\"添加形核剂\"这一基础概念即可作答，无需解释或分析过程。正确选项明确且单一，属于最基础的概念记忆型题目。" + }, + { + "idx": 1439, + "question": "The commonly used method for refining grains in casting processes is (21)", + "answer": "(21) stirring or vibration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的方法名称（stirring or vibration），属于需要简短文字回答的简答题类型 | 知识层次: 题目考查的是铸造过程中细化晶粒的常用方法，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对铸造工艺中细化晶粒常用方法的基础概念记忆，属于最基础的定义简答级别。正确选项直接对应教材中的标准答案，无需复杂推理或概念比较。" + }, + { + "idx": 1440, + "question": "What is the solid solution method of carbon in ferrite?", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释碳在铁素体中的固溶方式，答案需要文字描述（\"Interstitial\"），属于简答题类型。 | 知识层次: 题目考查的是碳在铁素体中的固溶方式这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即碳在铁素体中的固溶方式（间隙固溶）。题目仅要求识别正确术语\"Interstitial\"，无需解释或分析，属于最基本的知识点回忆，因此属于等级1难度。" + }, + { + "idx": 1441, + "question": "A metal with finer grains exhibits this phenomenon compared to the same metal with coarser grains, which is called (18) strengthening", + "answer": "(18) fine grain", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（fine grain）来回答问题，属于需要简短文字回答的类型，而不是从多个选项中选择或进行判断、计算。 | 知识层次: 题目考查的是对金属材料中晶粒细化强化现象的基本概念记忆，即\"fine grain strengthening\"这一术语的识别和填写，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即\"细晶强化\"这一术语的定义。学生只需识别并选择\"fine grain\"这个正确选项即可，无需进行概念解释或复杂分析。这属于最基本的知识点回忆型题目，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1442, + "question": "For an edge dislocation line, what is the relationship between its climb direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释刃位错线的攀移方向与伯格斯矢量之间的关系，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对位错基本性质的理解，特别是刃位错的攀移方向与伯格斯矢量之间的关系，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即刃位错线的攀移方向与其柏氏矢量的关系。题目直接给出了正确选项\"Perpendicular\"，无需任何解释或分析步骤，属于最基础的定义简答级别。" + }, + { + "idx": 1443, + "question": "For a screw dislocation line, what is the relationship between its Burgers vector and the dislocation line?", + "answer": "Parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺位错线的Burgers矢量与位错线之间的关系，需要文字描述而非选择或判断 | 知识层次: 题目考查对螺位错基本概念的记忆和理解，即螺位错的Burgers矢量与位错线的关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆基本的定义性知识，即螺型位错线的柏氏矢量与位错线的关系是平行的。不需要进行概念解释或复杂分析，属于最基础的概念记忆层次。" + }, + { + "idx": 1444, + "question": "What strengthening mechanism results in the change of ferrite properties?", + "answer": "Solid solution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种强化机制导致铁素体性能变化，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对强化机制的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即\"固溶强化\"这一基本原理的定义。学生只需识别并选择正确术语，无需解释或分析复杂概念体系，属于最基础的定义简答级别。" + }, + { + "idx": 1445, + "question": "There are five possible types of cementite in iron-carbon alloys, listed in order of formation temperature from high to low: (22) cementite, (23) cementite, (24) cementite, (25) cementite, and (26) cementite.", + "answer": "(22) primary; (23) eutectic; (24) secondary; (25) eutectoid; (26) tertiary;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定术语（五种渗碳体类型），答案以文字形式给出，属于需要补充完整信息的简答题类型。 | 知识层次: 题目考查对铁碳合金中不同类型渗碳体的分类和形成温度顺序的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个类型的cementite，但主要是要求考生记忆并正确排序不同cementite的形成温度顺序。这需要考生掌握基础概念和分类，但不需要进行复杂的分析或推理。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 1446, + "question": "For a screw dislocation line, what is the relationship between its cross-slip motion direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺丝位错线的交叉滑移运动方向与伯格斯矢量之间的关系，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对螺位错基本性质的理解，即其交叉滑移运动方向与Burgers向量的关系，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别螺位错线的交叉滑移运动方向与伯格斯矢量之间的基本关系（垂直）。这属于基础概念记忆层次，无需解释或分析，只需直接回忆定义即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1447, + "question": "For an edge dislocation line, what is the relationship between the direction of its slip motion and the Burgers vector?", + "answer": "Parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释边缘位错线的滑移方向与Burgers矢量之间的关系，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对位错滑移方向与伯格斯矢量关系这一基本概念的记忆和理解，属于材料科学中位错理论的基础知识点。 | 难度: 该题目属于基础概念记忆类型，仅需掌握边缘位错线的滑移方向与其伯格斯矢量之间的关系这一基本定义。在选择题型中，只需识别正确选项\"Parallel\"，无需进行复杂的概念解释或分析，因此属于最低难度等级。" + }, + { + "idx": 1448, + "question": "Compared to pure iron, how do the plasticity and toughness of ferrite change?", + "answer": "Lower", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释ferrite的塑性和韧性相对于纯铁的变化情况，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对纯铁和铁素体塑性及韧性差异的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，此题仅涉及基础概念记忆，要求考生回忆纯铁与铁素体在塑性和韧性方面的差异。题目仅提供正确选项\"Lower\"，无需复杂分析或推理，属于最基本的概念性知识考察。" + }, + { + "idx": 1449, + "question": "Compared to pure iron, how do the strength and hardness of ferrite change?", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的强度和硬度变化，答案需要文字说明而非选择、判断或计算 | 知识层次: 题目考查对纯铁和铁素体强度与硬度差异的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆基础概念（纯铁与铁素体的强度硬度比较），属于直接回忆定义和分类的基础知识。题目仅提供正确选项\"Higher\"，不需要任何解释或分析步骤，因此属于最简单的难度等级。" + }, + { + "idx": 1450, + "question": "For a screw dislocation line, what is the relationship between its slip direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺位错线的滑移方向与伯格斯矢量之间的关系，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对螺位错基本性质的理解，即其滑移方向与伯氏矢量之间的关系，属于基础概念的记忆和理解范畴。 | 难度: 该题目属于基础概念记忆类型，仅需记住螺位错的滑移方向与伯格斯矢量之间的基本关系（垂直关系）。在选择题型中，这种直接考察定义或基本关系的题目属于最简单的等级1难度，不需要复杂的推理或分析过程。" + }, + { + "idx": 1451, + "question": "For an edge dislocation line, what is the relationship between its Burgers vector and the dislocation line?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释刃位错线的Burgers矢量与位错线之间的关系，答案需要文字描述（\"Perpendicular\"），属于简答题类型。 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是刃位错的Burgers矢量与位错线方向的关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即刃位错的柏氏矢量与位错线的关系。不需要解释或分析，只需直接回忆定义即可选出正确答案\"Perpendicular\"。属于最基本的概念记忆题。" + }, + { + "idx": 1452, + "question": "For a mixed dislocation line, what is the relationship between its Burgers vector and the dislocation line?", + "answer": "Neither perpendicular nor parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释混合位错线的Burgers矢量与位错线之间的关系，答案需要文字描述而非选择或判断。 | 知识层次: 题目考查对混合位错线的基本概念的理解，即其Burgers矢量与位错线方向的关系，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生记住混合位错线的柏氏矢量与位错线之间的关系是\"既不垂直也不平行\"这一基本定义即可作答。题目不涉及概念解释或复杂体系分析，属于最简单的记忆性知识考查。" + }, + { + "idx": 1453, + "question": "After cold plastic deformation, the strength and hardness of metal (40)", + "answer": "increase", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（冷塑性变形后金属的强度和硬度增加），并要求判断其正确性。答案\"increase\"是对该陈述的肯定判断，符合判断题的特征。 | 知识层次: 题目考查冷塑性变形对金属强度和硬度影响的基本概念记忆，属于材料科学中最基础的知识点之一，无需复杂分析或计算。 | 难度: 该题目属于基础概念记忆层次，仅需判断冷塑性变形后金属强度和硬度的变化趋势。正确选项\"increase\"是材料科学中最基础的概念之一，无需复杂分析或推理，属于选择题型中最简单的正误判断类型。" + }, + { + "idx": 1454, + "question": "After cold plastic deformation of metal, its plasticity and toughness (41)", + "answer": "decrease", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答金属冷塑性变形后其塑性和韧性的变化，答案是一个简短的描述性词语\"decrease\"，属于需要文字解释的简答题类型 | 知识层次: 题目考查金属冷塑性变形后塑性和韧性的变化这一基础概念的记忆和理解，属于材料科学中的基本原理知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对金属冷塑性变形后性能变化的基础概念记忆，属于最基础的定义性知识。学生只需记住\"冷变形会导致塑性和韧性下降\"这一简单事实即可作答，无需任何解释或分析步骤。" + }, + { + "idx": 1455, + "question": "For a mixed dislocation line, what is the relationship between the direction of its slip motion and the dislocation line?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释混合位错线的滑移方向与位错线之间的关系，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查对混合位错线滑移方向与位错线方向关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察对混合位错线滑移方向与位错线关系的基本定义记忆，属于最基础的概念性知识，无需解释或复杂分析。" + }, + { + "idx": 1456, + "question": "After metal undergoes cold plastic deformation, this phenomenon is called (42) strengthening or (43)", + "answer": "deformation; work hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个专业术语（deformation; work hardening），属于需要文字回答的简答题类型，而非选择题、判断题或计算题。 | 知识层次: 题目考查金属冷塑性变形后的强化现象的基本概念记忆，即变形强化和加工硬化的术语填空，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求考生记忆并填写金属冷塑性变形后的两个专业术语（变形强化和加工硬化），属于基础概念记忆层次，无需复杂推理或概念体系阐述。选择题型中此类直接考查定义和术语的题目通常是最简单的类型。" + }, + { + "idx": 1457, + "question": "For metals that have undergone pre-cold plastic deformation, (44) annealing should be performed before further cold plastic deformation to improve their (45)", + "answer": "recrystallization; plasticity and toughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空白处（44和45），需要根据材料科学知识提供具体的术语（recrystallization; plasticity and toughness），属于简答题类型，需要文字解释和论述。 | 知识层次: 题目考查对金属冷塑性变形后热处理的基本概念记忆，即再结晶退火的作用（改善塑性和韧性），属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对金属热处理过程中\"再结晶退火\"这一基础概念的简单记忆，以及对其作用（提高塑性和韧性）的基本认知。不需要进行概念解释或复杂分析，属于最基础的知识点考察。" + }, + { + "idx": 1458, + "question": "For metals that have undergone pre-cold plastic deformation, recrystallization annealing should be performed before further cold plastic deformation, and the annealing temperature is (46)", + "answer": "0.4Tm", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的数值（0.4Tm）作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。这符合简答题的特征，即需要提供简短而具体的答案。 | 知识层次: 题目考查对金属再结晶退火温度的基本概念记忆，即0.4Tm这一特定数值的掌握，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需记住\"再结晶退火温度应为0.4Tm\"这一简单定义即可作答。在选择题型中，这种直接考查单一知识点的题目属于最低难度等级，不需要任何解释或分析过程，完全基于记忆性知识。" + }, + { + "idx": 1459, + "question": "For cold-formed components, (47) annealing should be performed promptly after forming to remove (48) and prevent the components from (49) or (50) during use.", + "answer": "stress relief; residual internal stress; deformation; cracking", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定术语来完成句子，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目主要考查对冷成型组件后处理工艺（应力退火）及其目的（消除残余内应力、防止变形和开裂）的基础概念记忆，属于材料科学中热处理工艺的基本知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解冷成型组件的后处理工艺及其目的，包括应力消除、残余内应力、变形和开裂等概念。题目要求考生在给定的选项中选出正确的术语填空，这需要一定的概念理解和记忆能力，但不需要复杂的分析或推理过程。因此，难度等级为2。" + }, + { + "idx": 1460, + "question": "What effect do second-phase particles have on the plastic deformation of alloys? Use dislocation theory to explain the mechanism.", + "answer": "Key points: They increase the strength of the alloy and the flow resistance during plastic deformation. This is because the resistance increases when dislocations cut through deformable second-phase particles or bypass non-deformable second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释第二相粒子对合金塑性变形的影响，答案需要文字解释和论述，属于简答题类型。 | 知识层次: 题目要求使用位错理论解释第二相粒子对合金塑性变形的影响机制，涉及位错与第二相粒子的相互作用（切割或绕过），需要综合运用位错理论、塑性变形原理和材料强化机制等知识，进行机理层面的分析和解释。这属于需要深度理解和推理分析的复杂问题。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅掌握位错理论的基本概念，还需要综合运用该理论解释第二相粒子对合金塑性变形的影响机制。正确选项涉及两种不同的强化机制（切割可变形粒子与绕过不可变形粒子），需要考生具备深度机理理解和复杂现象分析能力。这种题目在选择题中属于对知识掌握深度和综合应用能力要求极高的类型，远超简单记忆或基础理解的难度水平。" + }, + { + "idx": 1461, + "question": "What is intrinsic semiconductor?", + "answer": "A semiconductor with high purity and no doped impurities is called an intrinsic semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"intrinsic semiconductor\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征。 | 知识层次: 题目考查对\"本征半导体\"这一基础概念的定义记忆和理解，属于材料科学中最基本的概念性知识，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅考察对\"本征半导体\"基本定义的记忆，属于最基础的概念性知识。正确选项直接给出了定义，不需要任何解释、比较或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1463, + "question": "The direction of crystal slip is the direction of dislocation line movement within the slip plane.", + "answer": "False", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案形式为True或False | 知识层次: 题目考查晶体滑移方向与位错线运动方向的基本概念记忆和理解，属于材料科学中位错理论的基础知识点。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体滑移方向与位错线运动方向的关系这一基本定义即可作答。在选择题型中，这类仅需识别概念正误的题目属于最低难度等级。" + }, + { + "idx": 1464, + "question": "What is a doped semiconductor?", + "answer": "A semiconductor formed by intentionally adding a small amount of impurity elements to an intrinsic semiconductor is called a doped semiconductor. If the doping element is from Group VA in the periodic table, it forms an n-type semiconductor; if the doping element is from Group IIIA, it forms a p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对掺杂半导体进行定义和解释，答案提供了详细的文字描述和分类说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，包括掺杂半导体的定义和分类，以及n型和p型半导体的形成原理。这些内容属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于中等难度，题目要求考生理解并记忆掺杂半导体的基本定义和分类，包括n型和p型半导体的形成原理。虽然涉及多个概念，但都属于基础概念记忆范畴，不需要复杂的分析或比较。" + }, + { + "idx": 1465, + "question": "What is the difference in Fermi levels between intrinsic semiconductors and doped semiconductors?", + "answer": "The Fermi level of an intrinsic semiconductor is located at the center of the band gap, while the Fermi level of a doped semiconductor is not at the center of the band gap. The Fermi level of an n-type semiconductor shifts upward relative to the center of the band gap, and the Fermi level of a p-type semiconductor shifts downward relative to the center of the band gap.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Fermi能级在本质半导体和掺杂半导体中的差异，答案提供了详细的文字解释和论述，没有涉及计算或选择选项。 | 知识层次: 题目要求解释本征半导体和掺杂半导体的费米能级差异，涉及多个概念的关联和综合分析，需要理解费米能级的位置变化及其与半导体类型的关系，思维过程具有一定深度。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解本征半导体和掺杂半导体的费米能级位置的基本概念，还需要能够比较和分析n型和p型半导体中费米能级的移动方向。这涉及到多步的概念关联和综合分析，超出了简单的记忆或单一概念的应用。此外，题目要求考生能够从多个角度（本征、n型、p型）进行论述，进一步增加了难度。" + }, + { + "idx": 1466, + "question": "A pure edge dislocation loop can form in a crystal.", + "answer": "True", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（True/False），符合判断题的特征 | 知识层次: 题目考查对位错类型（边缘位错环）这一基本概念的认知和理解，属于材料科学中晶体缺陷的基础知识范畴，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆边缘位错环的定义即可判断正确选项，无需深入理解或分析复杂概念。" + }, + { + "idx": 1467, + "question": "What is the difference between the carriers in intrinsic semiconductors and doped semiconductors?", + "answer": "The carriers in intrinsic semiconductors are electrons in the conduction band and holes in the valence band, with an equal number of electrons and holes. In doped semiconductors, the carriers are also electrons in the conduction band and holes in the valence band, but the number of electrons and holes is not equal. In n-type semiconductors, the number of electrons is greater than the number of holes, while in p-type semiconductors, the number of holes is greater than the number of electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述本征半导体和掺杂半导体中载流子的区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对半导体中载流子类型和数量的基本概念的理解和记忆，涉及本征半导体和掺杂半导体的区别，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分本征半导体和掺杂半导体中载流子的差异，包括电子和空穴的数量关系。这要求考生不仅记住定义，还需要对概念进行一定的解释和描述。然而，题目并未涉及复杂的推导或综合分析，因此难度等级为2。" + }, + { + "idx": 1468, + "question": "A screw dislocation line can only undergo glide motion, not climb motion.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（A screw dislocation line can only undergo glide motion, not climb motion），要求判断其正确性（Correct），这是典型的判断题特征。 | 知识层次: 题目考查对位错运动方式（滑移和攀移）的基本概念记忆和理解，属于材料科学中位错理论的基础知识点。 | 难度: 该题目属于基础概念正误判断题，仅需记忆螺丝位错线的基本运动特性（滑移与攀移的区别），无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1469, + "question": "In a binary alloy phase diagram, the greater the distance between the liquidus and solidus lines, the worse the fluidity of the alloy.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对二元合金相图中液相线和固相线距离与合金流动性关系的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆二元合金相图中液相线和固相线距离与合金流动性的关系这一基础概念即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 1470, + "question": "The presence of vacancies always increases the free energy of a crystal.", + "answer": "False", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（True/False），答案直接给出了False的判断，符合判断题的特征。 | 知识层次: 题目考查对晶体缺陷中空位概念的基本理解，属于基础概念的记忆和判断，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体缺陷中空位对自由能影响的基本原理即可作答。在选择题型中属于最简单的直接判断类题目，无需复杂推理或概念比较。" + }, + { + "idx": 1471, + "question": "The presence of dislocations always increases the free energy of a crystal.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct/Incorrect），属于典型的判断题形式。答案只需给出对错判断，无需解释或计算。 | 知识层次: 题目考查对位错基本性质的理解，属于晶体缺陷的基础概念记忆范畴 | 难度: 该题目属于基础概念记忆层次，仅需判断关于位错增加晶体自由能量的陈述是否正确。在选择题型中，这类直接考察定义或基本原理记忆的题目属于最低难度等级，无需复杂分析或推理过程。" + }, + { + "idx": 1472, + "question": "The driving force for the growth of recrystallization nuclei is the reduction of deformation stored energy, while the driving force for the growth of recrystallized grains is the reduction of total grain boundary energy.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（Correct），属于典型的判断题形式 | 知识层次: 题目考查对再结晶过程中驱动力这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念正误判断题，仅需记忆再结晶核生长和再结晶晶粒生长的驱动力这两个基本概念即可作答，无需理解或分析复杂关系，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1473, + "question": "In essence, a twin is also a stacking fault", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对孪晶和堆垛层错这两个基础概念的理解和记忆，属于材料科学中的基本概念辨析 | 难度: 该题目属于基础概念记忆层次，仅需判断\"孪晶也是一种堆垛层错\"这一陈述的正误。在选择题型中，这种直接考察定义或分类记忆的题目属于最基本的难度等级（等级1），不需要复杂的理解或分析过程。" + }, + { + "idx": 1474, + "question": "Under the condition of no solid-phase diffusion and complete liquid-phase mixing, constitutional supercooling cannot occur during the solidification of solid solutions.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对固溶体凝固过程中成分过冷条件的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对\"成分过冷\"这一基础概念的理解，需要考生掌握在特定条件下（无固相扩散和完全液相混合）成分过冷是否会发生的基本原理。虽然涉及多个条件限制，但核心概念较为明确，不需要复杂的分析推理过程，属于中等偏下的难度水平。" + }, + { + "idx": 1475, + "question": "In the vertical section of a ternary phase diagram, the lever rule cannot be used to determine the mass fractions of the three equilibrium phases.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征。题目没有提供多个选项，也不需要计算或文字解释，只需判断陈述的对错。 | 知识层次: 题目考查对三元相图中杠杆规则应用范围的基础概念记忆，仅需判断陈述是否正确，不涉及复杂分析或计算。 | 难度: 该题目属于基础概念正误判断，仅需记忆三元相图中杠杆规则的应用限制即可作答，无需深入理解或分析多个概念。在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1476, + "question": "At 727°C, the maximum carbon content in the equilibrium state of iron-carbon alloy is w_C=0.0218% for ferrite and w_C=0.77% for austenite. Where are the carbon atoms located in the ferrite and austenite crystals?", + "answer": "The carbon atoms are located at the centers of the flattened octahedral interstitial sites in ferrite crystals and at the centers of the regular octahedral interstitial sites in austenite crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释碳原子在铁素体和奥氏体晶体中的位置，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查铁碳合金中碳原子在铁素体和奥氏体晶体中的位置，属于晶体结构的基础概念记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（铁碳合金中碳原子的位置），但需要考生准确区分铁素体和奥氏体晶体结构中碳原子的不同位置（扁平八面体间隙中心与规则八面体间隙中心）。这要求考生不仅要记住定义，还要理解两种晶体结构的差异。相比单纯的定义复述（等级1），该题目需要更深入的概念解释和描述能力（等级2），但不需要进行复杂的体系阐述（等级3）。" + }, + { + "idx": 1477, + "question": "Explain the characteristics of grain growth process during heating of cold-deformed metals", + "answer": "Grain growth. It causes some property changes, such as decreases in strength, plasticity, and toughness. Along with grain growth, other structural changes also occur, such as recrystallization texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷变形金属加热过程中晶粒生长的特性，需要文字解释和论述，答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求解释冷变形金属加热过程中的晶粒生长特性，涉及晶粒生长对性能的影响以及其他结构变化（如再结晶织构）。这需要将多个概念（晶粒生长、性能变化、结构变化）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解冷变形金属加热过程中的晶粒生长特性及其对性能的影响，并关联其他结构变化如再结晶织构。虽然不涉及多步计算，但需要对多个概念进行综合分析和说明。" + }, + { + "idx": 1478, + "question": "Using the constitutional undercooling theory, explain the relationship between the casting properties (fluidity, distribution characteristics of shrinkage porosity) of an alloy and the vertical distance between the liquidus and solidus lines in its phase diagram.", + "answer": "The casting properties (fluidity, distribution characteristics of shrinkage porosity) of an alloy are related to the vertical distance between the liquidus and solidus lines in its phase diagram. The larger the vertical distance, the poorer the fluidity of the alloy, and the more likely shrinkage porosity is to be distributed dispersedly. The condition for constitutional undercooling is given by: $\\\\frac{-m C_{0}(1-k_{0})}{D k_{0}}$, where G is the actual temperature gradient in the liquid ahead of the liquid/solid interface, R is the velocity of the liquid/solid interface movement, $\\\\pmb{D}$ is the diffusion coefficient of solute atoms in the liquid phase, $\\\\mathbf{\\abla}m$ is the slope of the liquidus line in the alloy phase diagram, $C_{0}$ is the composition of the alloy, and $k_{0}$ is the equilibrium partition coefficient of the alloy. It can be proven that $\\\\frac{\\\\mathrm{-}m C_{0}~\\\\left(1-k_{0}\\\\right)}{k_{0}}$ in the above equation is the vertical distance between the liquidus and solidus lines for the $C_{0}$ alloy in its phase diagram. Clearly, the larger the vertical distance between the liquidus and solidus lines, the greater the tendency for constitutional undercooling in the alloy, and the more the liquid/solid interface tends to grow dendritically. This hinders the fluidity of the alloy melt and also causes dispersed shrinkage porosity to form in the interdendritic regions due to insufficient feeding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用成分过冷理论解释合金铸造性能与相图中液相线和固相线垂直距离之间的关系，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求运用成分过冷理论解释合金铸造性能与相图中液相线和固相线垂直距离的关系，涉及多个概念的关联和综合分析，需要深入理解成分过冷的条件及其对合金凝固行为的影响，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1479, + "question": "For the equilibrium state of T12 steel (w_C=1.2%), write its phase constituents at room temperature and calculate the mass fraction of each phase constituent.", + "answer": "Phase constituents: α+Fe3C. w_α=(6.69-1.2)/(6.69-0.0008)×100%≈82.07%. w_Fe3C=(1.2-0.0008)/(6.69-0.0008)×100%≈17.93%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算T12钢在室温下的相组成及其质量分数，解答过程涉及数值计算和公式应用（杠杆定律），答案以具体数值形式呈现。 | 知识层次: 题目主要考查对铁碳相图的基本理解和杠杆定律的简单应用，涉及单一公式的直接套用和基本计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解相图的基本概念和运用杠杆定律进行质量分数的计算，但解题步骤较为直接，仅涉及单一知识点的应用和简单计算，无需多个公式的组合或复杂分析。因此，在选择题型内属于中等偏下的难度。" + }, + { + "idx": 1480, + "question": "Explain the characteristics of the recovery process when cold-deformed metal is heated", + "answer": "During the recovery process, the microstructure does not change, and the elongated grains in the deformed state are still maintained. The recovery process completely eliminates the macroscopic first-class stresses caused by deformation and removes most of the microscopic second-class stresses. Generally, mechanical properties change little during recovery, with hardness and strength slightly decreasing, plasticity slightly improving, and some physical properties undergoing significant changes—resistivity notably decreases, while density increases. The deformation-stored energy is partially released during the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释冷变形金属加热时回复过程的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷变形金属加热时的回复过程特性，涉及微观结构、应力消除、机械性能和物理性能变化等多方面的综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和综合分析，思维过程有一定深度。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅理解冷变形金属加热过程中的回复过程，还需要掌握微观结构变化、应力消除、机械性能变化以及物理性能变化等多个方面的知识。此外，题目涉及的知识点需要考生进行多角度分析，包括宏观和微观层面的变化，以及不同性能指标的变化趋势。这种综合分析能力在选择题型中属于较高要求，因此难度等级为4。" + }, + { + "idx": 1481, + "question": "Qualitatively compare the elastic modulus of ceramic materials, metal materials, and polymer materials", + "answer": "Among the three types of materials, ceramic materials have the highest elastic modulus, metal materials have the next highest elastic modulus, and polymer materials have the lowest elastic modulus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对三种材料的弹性模量进行定性比较，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对不同材料弹性模量的基本概念记忆和简单比较，属于基础概念的记忆和理解层次，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆的范畴，仅需回忆和比较三种材料的基本弹性模量顺序，无需深入分析或复杂推理。正确选项直接给出了明确的比较结果，符合等级1的基本定义简答要求。" + }, + { + "idx": 1482, + "question": "At 727°C, the maximum carbon content in the equilibrium iron-carbon alloy is w_C=0.0218% for ferrite, while the carbon content in austenite is w_C=0.77%. Explain why the carbon content differs so greatly between the two.", + "answer": "Because the radius of the flat octahedral interstitial sites in the ferrite crystal is much smaller than that of the regular octahedral interstitial sites in the austenite crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种晶体结构中碳含量差异的原因，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的晶体结构差异解释，符合简答题的特征。 | 知识层次: 题目要求解释铁素体和奥氏体中碳含量差异的原因，涉及晶体结构中间隙位置的差异及其对碳溶解度的影响。这需要深入理解晶体结构、间隙固溶体以及相变等概念，并进行综合分析。思维过程需要从微观结构特征推导宏观性质差异，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生理解并比较铁素体和奥氏体晶体结构中碳溶解度的差异，并解释其根本原因。正确选项涉及晶体结构中间隙位置的几何特征（平面八面体间隙与规则八面体间隙的半径差异），这需要考生具备：" + }, + { + "idx": 1483, + "question": "Explain the role of Cottrell atmosphere in strengthening metals", + "answer": "Cottrell atmosphere: In BCC crystals (such as carbon steel), small-sized atoms like C and N preferentially distribute in the tensile stress region of edge dislocations, pinning the dislocations. To move the dislocations, they must be torn away from the pinning effect, requiring additional stress, thereby increasing the material's strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Cottrell atmosphere在金属强化中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Cottrell atmosphere在金属强化中的作用机制，涉及位错理论、原子扩散和应力场相互作用等复杂概念的综合运用和推理分析。需要深入理解位错与溶质原子的交互作用，以及这种交互如何导致材料强化的机理。 | 难度: 在选择题型中，该题目要求考生深入理解Cottrell atmosphere的机理及其对金属强化的影响，涉及BCC晶体结构、位错理论、溶质原子与位错的相互作用等复杂概念的综合运用。考生需要能够解释溶质原子在位错应力场中的分布及其对位错运动的阻碍作用，并理解这一现象如何导致材料强度的提高。这种深度机理解释和复杂现象全面分析的要求，使得该题目在选择题型中属于最高难度等级。" + }, + { + "idx": 1484, + "question": "There is a face-centered cubic single crystal with a right-handed screw dislocation on the (11) plane, whose Burgers vector is a/2 [101], and another right-handed screw dislocation on the (111) plane, whose Burgers vector is a/2 [011]. These two dislocations meet at the intersection line of the two slip planes and form a new perfect dislocation. Explain what type of dislocation the newly formed perfect dislocation is, whether this dislocation can glide, and why?", + "answer": "Since the dislocation line is the intersection line of the two slip planes, the dislocation line is [1 0 -1]. It can be seen that the dislocation line is neither parallel nor perpendicular to the Burgers vector, so the newly formed dislocation is a mixed-type dislocation. Given the dislocation line and Burgers vector of the newly formed dislocation, their cross product yields the normal vector of the slip plane for the new dislocation, which is [1 -1 1]. The slip plane of this dislocation is (1 -1 1). Because this slip plane is a close-packed plane in the face-centered cubic structure, the dislocation can glide.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释新形成的位错类型、是否可以滑移及其原因，需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析两个位错相遇后形成的新位错类型及其滑移能力，涉及位错线方向、伯氏矢量、滑移面等多方面知识的综合运用和推理分析，需要深入理解位错的性质和面心立方结构中的滑移机制。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1485, + "question": "From the perspective of bonding in materials, analyze the reasons for the differences in elastic modulus among ceramic materials, metal materials, and polymer materials", + "answer": "The magnitude of a material's elastic modulus depends on the strength of the bonding within the material. Ceramic materials are bonded by strong ionic or covalent bonds, hence their elastic modulus is very large; metal materials are bonded by weaker metallic bonds, hence their elastic modulus is smaller; in polymer materials, the molecular chains are bonded by strong covalent bonds, but the chains themselves are bonded by very weak secondary bonds, hence their elastic modulus is very small.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从材料键合的角度分析陶瓷、金属和聚合物材料弹性模量差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从材料键合的角度分析陶瓷、金属和聚合物材料弹性模量差异的原因，涉及对不同材料键合类型的深入理解、键合强度与弹性模量关系的综合分析，以及不同材料类别之间的对比分析。这需要综合运用材料科学中的键合理论、弹性模量的影响因素等知识，进行推理和解释，属于复杂分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握陶瓷、金属和聚合物材料的基本键合类型，还需要深入理解不同键合类型对弹性模量的影响机制。题目涉及复杂现象的综合分析，需要考生将键合强度与宏观力学性能（弹性模量）直接关联，并进行跨材料类别的比较推理。这种在选择题中要求机理深度解释和复杂现象全面分析的题目，对知识整合能力和材料科学原理的应用能力提出了极高要求，因此属于选择题型中的最高难度等级。" + }, + { + "idx": 1487, + "question": "Explain the role of Suzuki atmosphere in strengthening metals", + "answer": "Suzuki atmosphere: In FCC crystals (such as stainless steel), alloying elements like Ni and α preferentially distribute in stacking fault regions, reducing the stacking fault energy and expanding the extended dislocation zone. To move these extended dislocations, additional stress is required, thereby increasing the material's strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Suzuki atmosphere在强化金属中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Suzuki atmosphere在金属强化中的作用机制，涉及FCC晶体结构、合金元素分布、堆垛层错能变化以及位错运动等概念的关联和综合分析，需要深入理解材料微观结构与性能之间的关系，并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解Suzuki atmosphere的复杂机理，包括FCC晶体结构、合金元素分布、堆垛层错能变化以及位错运动等专业概念的综合运用。正确选项不仅需要识别这些概念，还要能够解释它们之间的相互作用如何导致材料强化。这种题目在选择题中属于需要全面分析复杂现象的题型，对学生的知识深度和综合分析能力要求极高。" + }, + { + "idx": 1488, + "question": "For the equilibrium state of T12 steel (w_C=1.2%), write its room temperature microstructure constituents and calculate the mass fraction of each constituent.", + "answer": "Microstructure constituents: P+Fe3CⅡ. w_P=(6.69-1.2)/(6.69-0.77)×100%≈92.74%. w_Fe3CⅡ=(1.2-0.77)/(6.69-0.77)×100%≈7.26%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算质量分数（w_P和w_Fe3CⅡ），需要使用给定的公式进行数值计算，答案呈现为具体的计算结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的碳含量和铁碳相图进行直接套用公式计算各相的质量分数。虽然需要理解铁碳相图的基本概念，但整体思维过程较为直接，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用杠杆定律计算质量分数，但解题步骤明确且直接，只需套用单一公式即可完成计算。相较于需要多个公式组合或复杂分析的题目，该题的解题过程较为简单直接。" + }, + { + "idx": 1489, + "question": "Which hazardous substances are prohibited by the EU RoHS Directive (now enacted as a regulation) that came into effect on July 1, 2006? What are their maximum allowable concentrations?", + "answer": "Prohibited substances include lead (Pb, 0.1%), mercury (Hg, 0.1%), cadmium (Cd, 0.01%), hexavalent chromium (Cr+6, 0.1%), polybrominated biphenyls (PPB, 0.1%), and polybrominated diphenyl ethers (PBDE, 0.1%).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出欧盟RoHS指令禁止的有害物质及其最大允许浓度，需要文字解释和论述，而不是从选项中选择或判断对错。答案提供了详细的物质名称和浓度限制，符合简答题的特征。 | 知识层次: 题目考查对欧盟RoHS指令中禁止的有害物质及其最大允许浓度的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求记忆欧盟RoHS指令中禁止的有害物质及其最大允许浓度，这属于基础概念记忆的范畴。正确选项直接列出了具体的物质和对应的浓度限制，没有涉及复杂的概念解释或体系阐述。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1490, + "question": "There is a face-centered cubic single crystal with a right-handed screw dislocation on the (11) plane, whose Burgers vector is a/2 [101], and another right-handed screw dislocation on the (111) plane, whose Burgers vector is a/2 [011]. These two dislocations meet at the intersection line of the two slip planes and form a new perfect dislocation. If a tensile stress of 17.2MPa is applied along the [010] crystal direction, calculate the force per unit length acting on the newly formed perfect dislocation and indicate its direction (given the lattice constant a=0.2nm).", + "answer": "cosφ=1/√3, cosλ=1/√2. According to Schmid's law, the resolved shear stress acting on the slip direction of the newly formed dislocation's slip plane is τ0=17.2×1/√3×1/√2 MPa=7.0MPa. Therefore, the force per unit length acting on the dislocation line is f=τb=(0.2×10^-9×7×10^6)/√2 N/m=10^-3 N/m. Its direction is perpendicular to the dislocation line direction [101], pointing towards the unslipped region.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（如计算力的大小和方向），并应用了材料科学中的特定公式（Schmid's law），最终给出了具体的数值结果和方向描述。这符合计算题的特征。 | 知识层次: 题目涉及多步计算（Schmid's law应用、应力分解、力的计算）、概念关联（位错性质、滑移面与方向关系）和综合分析（新形成位错的受力方向判断），需要中等程度的认知能力和知识点的关联运用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念（如Burgers向量、Schmid定律、位错线受力计算）并进行多步骤计算。题目涉及晶体学方向计算、应力分解和位错力学分析，虽然提供了正确选项的解题路径，但仍需要较强的概念关联和综合分析能力才能正确理解和执行计算步骤。" + }, + { + "idx": 1492, + "question": "What are the main solder systems that can replace lead-containing solders?", + "answer": "The main alternatives to lead-containing solders are: Sn-Ag-Cu, Sn-Zn, Sn-Bi, and Sn-In systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并简要说明可以替代含铅焊料的主要焊料系统，答案提供了具体的合金系统名称，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对无铅焊料系统的基本分类和记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆和识别主要的无铅焊料系统（Sn-Ag-Cu, Sn-Zn, Sn-Bi, Sn-In），属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，只需直接回忆知识点即可作答，因此属于最低难度等级。" + }, + { + "idx": 1493, + "question": "Explain the characteristics of the recrystallization process during heating of cold-deformed metals", + "answer": "The microstructure undergoes changes, transforming from elongated grains due to cold deformation into new equiaxed grains. Mechanical properties change drastically, with strength and hardness sharply decreasing and plasticity increasing, returning to the state before deformation. The stored energy from deformation is fully released during recrystallization, eliminating the three types of stresses (lattice distortion) and reducing dislocation density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释冷变形金属加热过程中再结晶过程的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释冷变形金属加热过程中再结晶过程的特性，涉及微观结构变化、机械性能变化、储存能量释放等多个方面的综合分析。需要理解再结晶的机理，并能关联不同现象（如晶粒形状变化、位错密度变化、应力消除等）之间的内在联系。这属于对材料科学中相变和变形机理的深入理解和综合分析，超出了基础概念记忆和简单应用的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生全面理解冷变形金属再结晶过程的微观结构变化、力学性能转变以及能量释放机制。正确选项不仅需要掌握多个复杂概念（如晶粒形态转变、位错密度变化、变形储能释放），还需要将这些概念整合成一个连贯的机理解释。这种题目在选择题中属于需要深度分析和综合判断的类型，远超简单记忆或单一概念应用的难度水平。" + }, + { + "idx": 1494, + "question": "A single crystal (BCC) with a rod axis [213] is stretched along the direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the initial slip system.", + "answer": "The single crystal has a BCC structure, and [213] lies within the orientation triangle [001]~[1¯11]~[101]. Therefore, the initial slip system is (011)[111].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定初始滑移系统，答案提供了详细的解释和结论，而不是简单的选择或计算。 | 知识层次: 题目需要理解BCC晶体结构、滑移面和滑移方向的概念，并能将给定的晶向[213]定位在标准三角形中，进而确定初始滑移系统。这涉及到多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要综合运用晶体结构、滑移系统、取向三角形等多方面知识，并进行多步计算和概念关联分析。题目要求考生不仅要掌握BCC结构的滑移系统特性，还需要能够确定特定晶向在取向三角形中的位置，并据此推导初始滑移系统。这种综合分析能力在选择题型中属于较高要求。" + }, + { + "idx": 1495, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the double slip system.", + "answer": "The double slip system is (011)[111]－(011)[111].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定双滑移系统，答案是一个具体的滑移系统组合，而不是简单的选择、判断或计算。 | 知识层次: 题目要求确定双滑移系统，需要理解BCC晶体结构、滑移面和滑移方向的关系，并进行综合分析。虽然不涉及复杂的计算，但需要将多个概念关联起来，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解BCC晶体结构、滑移面和滑移方向的概念，并能够将这些概念关联起来。其次，题目涉及多步计算，包括确定滑移系统以及判断双滑移系统，这需要考生具备较强的综合分析能力。此外，题目还要求考生能够将理论知识与实际应用相结合，进一步增加了难度。因此，在选择题型内，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 1496, + "question": "What is the closest packed direction in a body-centered cubic crystal?", + "answer": "<111>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的晶体学方向（<111>），需要专业知识解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对体心立方晶体中最密堆积方向的基本概念记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，此题仅需记忆最基本的晶体学方向知识，属于基础概念的直接回忆。题目仅要求识别体心立方晶体中最密排方向，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1499, + "question": "What is the reason for age hardening in Al-4.5%Cu alloy?", + "answer": "The reasons for age hardening are: first, when the precipitated metastable disk-shaped phase has a certain orientation relationship with the parent phase, it generates significant elastic strain in the matrix, which can markedly strengthen the alloy; second, when the alloy undergoes deformation, the interaction between dispersed particles and dislocations strengthens the alloy. If the precipitate particles are deformable, the work required to increase the surface energy of the particles when dislocations cut through them raises the resistance to dislocation motion, thereby strengthening the alloy. If the precipitate particles are strong and coherent with the matrix, the dislocation lines find it difficult to cut through the particles and will bypass them under applied stress, leaving dislocation loops. For the alloy to continue deforming, the stress exerted by the particles as the dislocation lines bypass them must be overcome, requiring further increase in the applied stress, meaning the alloy achieves age hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金时效硬化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金时效硬化的原因，涉及多个机理的综合分析，包括亚稳相与母相的取向关系、弹性应变、位错与析出粒子的相互作用等。需要深入理解材料科学中的相变、位错理论和强化机制，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解Al-4.5%Cu合金的时效硬化机理，包括亚稳相析出、弹性应变强化、位错与析出颗粒的相互作用等复杂概念。正确选项不仅需要掌握多个专业知识点，还需要将这些知识点综合运用来解释时效硬化的多重机制。此外，题目涉及位错切割颗粒和位错绕过颗粒两种不同情况下的强化机制，要求考生具备较强的推理分析和机理解释能力。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最难的一类。" + }, + { + "idx": 1502, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the shear strain γₒ at the onset of double slip.", + "answer": "Using L = l + γ(l⋅n)b, let L = [u0w], then L = [2¯13] + 4γ[111]/√6. From this, it can be determined that u = 3, w = 4, γ = √6/4. Therefore, the crystal orientation is [304], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定剪切应变γₒ，答案给出了具体的计算过程和数值结果（γ = √6/4），符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括晶体取向的确定、剪切应变的计算以及双滑移起始条件的分析。虽然不涉及复杂的机理或创新应用，但需要综合运用晶体学知识和数学计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体塑性变形的基本概念（如滑移面、剪切应变等），并进行多步骤的向量计算和综合分析。题目要求确定双滑移开始时的剪切应变，涉及向量运算和几何关系的推导，虽然提供了正确选项的解题思路，但仍需要较强的空间想象能力和数学计算能力。" + }, + { + "idx": 1503, + "question": "How do the strength and hardness of a metal with finer grains compare to the same metal with coarser grains", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属晶粒尺寸对强度和硬度的影响，需要文字论述而非简单选择或判断 | 知识层次: 题目需要理解晶粒尺寸对金属强度和硬度的影响机制，并能够将Hall-Petch关系等概念与实际材料性能关联起来进行分析。虽然不涉及复杂计算，但需要多步概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解金属晶粒尺寸对强度和硬度的影响这一概念，并进行比较分析。虽然题目没有涉及多步计算，但要求考生能够关联晶粒细化与力学性能之间的关系，属于中等应用层次的知识点。" + }, + { + "idx": 1505, + "question": "How do the plasticity and toughness of a metal with finer grains compare to the same metal with coarser grains", + "answer": "Better", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释金属晶粒尺寸对塑性和韧性的影响，需要文字论述，而非选择、判断或计算。答案\"Better\"过于简略，通常简答题需要更详细的解释。 | 知识层次: 题目要求比较金属晶粒细化对塑性和韧性的影响，需要理解晶粒尺寸与力学性能之间的关系，并进行综合分析。这涉及多个概念的关联和中等程度的推理分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解金属晶粒尺寸对塑性和韧性的影响这一概念，并进行比较分析。虽然题目给出了正确选项，但学生需要掌握晶粒细化对金属力学性能的影响机制，并能将这一知识应用到具体比较情境中。这涉及到材料科学中微观结构与宏观性能关系的理解，属于中等应用层次的知识要求。" + }, + { + "idx": 1506, + "question": "Compared with pure iron, how do the plasticity and toughness of ferrite change", + "answer": "Lower", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的塑性和韧性变化，需要文字论述而非简单选择或判断 | 知识层次: 题目考查的是对纯铁和铁素体塑性及韧性差异的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即纯铁与铁素体的塑性和韧性比较。题目仅要求选择正确选项\"Lower\"，无需解释或分析，属于最基本的知识点掌握深度要求。解题步骤极其简单，只需回忆相关定义即可作答，因此属于等级1难度。" + }, + { + "idx": 1507, + "question": "What is the reason for the change in properties of ferrite compared to pure iron", + "answer": "Solid solution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铁素体与纯铁性能变化的原因，需要文字论述而非选择或判断。答案\"Solid solution\"是一个简短的解释性回答，符合简答题的特征。 | 知识层次: 题目要求解释铁素体与纯铁性能差异的原因，涉及固溶体概念的应用和性能变化的综合分析，需要理解固溶体对材料性能的影响机制，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解固溶体的概念及其对铁素体性能的影响，并进行综合分析。题目要求考生将纯铁与铁素体的性能变化原因联系起来，涉及中等应用层次的知识，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1508, + "question": "What is the phenomenon called when a metal with finer grains exhibits higher strength and hardness but lower plasticity and toughness compared to the same metal with coarser grains?", + "answer": "Grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释一个现象的名称，需要文字回答而非选择、判断或计算 | 知识层次: 题目考查对晶粒细化强化现象的基本概念记忆和理解，属于材料科学中的基础知识点。 | 难度: 在选择题中属于中等难度，需要理解晶粒细化强化的基本概念，并能够将其与金属的力学性能变化联系起来。虽然不涉及复杂的分析或比较，但需要一定的概念解释和描述能力。" + }, + { + "idx": 1509, + "question": "Ferrite is a solid solution of carbon in what－Fe", + "answer": "α", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的术语（α-Fe）作为答案，而不是从多个选项中选择或判断对错，也不需要计算或解释。 | 知识层次: 题目考查对铁素体（Ferrite）基本定义的记忆，即碳在α-Fe中的固溶体，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对铁素体基本定义的记忆，即碳在α-Fe中的固溶体。题目直接给出正确选项，无需复杂推理或概念比较，属于最基础的定义简答类型。" + }, + { + "idx": 1510, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the final orientation of the test rod (assuming the rod does not fracture before reaching a stable orientation).", + "answer": "Let the stable orientation be [u′0w′]. To satisfy n = [000], it is required that [u′0w′] × ([111] ± [1¯11]) = [000], which implies u′ = w′. Therefore, the final stable orientation is [101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定单晶棒的最终取向，答案给出了详细的推导过程和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要综合运用晶体学知识（BCC结构、滑移面、晶向指数）、塑性变形原理（稳定取向条件）和向量运算（叉积为零条件）进行多步骤推理分析。解题过程涉及对晶体取向变化机理的深入理解，并要求建立数学条件（[u′0w′] × ([111] ± [1¯11]) = [000]）来推导最终稳定取向，属于需要深度分析和综合运用的复杂问题。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1511, + "question": "Compared with pure iron, how do the strength and hardness of ferrite change", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的强度和硬度变化，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对纯铁和铁素体强度与硬度变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即对纯铁和铁素体的强度与硬度进行比较。题目仅要求选择正确选项\"Higher\"，无需复杂的分析或推理步骤。属于最基本的概念记忆类题目，符合等级1的标准。" + }, + { + "idx": 1512, + "question": "A single crystal (BCC) rod is stretched along the rod axis [213] direction to undergo plastic deformation. Given that the slip plane of the single crystal is {110}, determine the rotation law and rotation axis during the slip process.", + "answer": "During double slip, the specimen axis on one hand rotates towards [111], with the rotation axis n₁ = [304] × [111] = [413], and on the other hand also rotates towards [1¯11]; the rotation axis n₂ = [304] × [1¯11] = [41¯3]; the resultant rotation axis is [020] i.e., [010], so after double slip, point F moves along the edge [001]－[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定旋转定律和旋转轴，答案提供了详细的推导过程和解释，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求确定单晶拉伸过程中的旋转规律和旋转轴，涉及双滑移系统的分析、旋转轴的计算以及最终结果的综合解释。这需要深入理解晶体滑移机制、向量运算、以及多滑移系统的相互作用，属于综合运用和推理分析的复杂问题。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用晶体学、塑性变形和旋转定律等复杂知识，进行多步骤推理分析。解题过程涉及双滑移系统的矢量运算（叉乘确定旋转轴）、结果合成（[020]等效于[010]）以及滑移路径的机理解释（点F沿晶向边移动）。这些都需要对BCC晶体结构、滑移系选择和晶体旋转机制有深刻理解，远超选择题型中常规的概念判断或简单计算要求。" + }, + { + "idx": 1513, + "question": "For an edge dislocation line, the direction of its slip motion is (18) to the Burgers vector", + "answer": "(18) parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（parallel）来回答问题，属于简答题的填空形式，需要根据知识理解来提供简短答案。 | 知识层次: 题目考查对位错滑移方向与伯格斯矢量关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目仅考察对位错滑移方向与伯格斯矢量关系的基础概念记忆，无需解释或分析，只需选择\"parallel\"这一简单定义性答案。这是材料科学中最基础的概念之一，在选择题中属于最基础难度层级。" + }, + { + "idx": 1514, + "question": "What are the common methods for refining grains in casting processes (the second method)", + "answer": "Adding nucleating agents, stirring or vibration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释铸造过程中细化晶粒的常见方法，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对铸造过程中晶粒细化常见方法的基础概念记忆，属于基本原理和分类的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆，但需要考生掌握铸造过程中细化晶粒的常见方法，并能正确识别第二类方法（添加形核剂、搅拌或振动）。这比单纯记忆基本定义（等级1）要求更高，但不需要进行复杂概念体系的阐述（等级3）。" + }, + { + "idx": 1515, + "question": "What is the common method to refine grains in casting process (the first method)", + "answer": "Increase the cooling rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的工艺方法，需要简要的文字解释，而不是从选项中选择或判断对错 | 知识层次: 题目考查的是铸造过程中细化晶粒的基本方法，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需回忆铸造过程中细化晶粒的常见方法（增加冷却速率），无需复杂分析或比较多个概念。题目直接考察单一知识点的定义性内容，符合等级1的基本定义简答标准。" + }, + { + "idx": 1516, + "question": "For an edge dislocation line, its Burgers vector is __(17)__ to the dislocation line", + "answer": "(17) perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Burgers vector的方向），答案是一个单词（perpendicular），属于简答题的填空形式，需要学生对相关概念有准确理解。 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是伯格斯矢量与位错线方向的关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对位错线柏氏矢量方向这一基础概念的记忆，属于最基本的知识点复现。题目仅要求选择\"perpendicular\"这个固定搭配，不需要任何解释或推导过程，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1517, + "question": "For an edge dislocation line, its climb direction is _（19）_ to the Burgers vector", + "answer": "（19）perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（perpendicular）来补全句子，属于需要简短文字回答的题目类型 | 知识层次: 题目考查对刃位错线攀移方向与伯格斯矢量关系的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即刃位错线的攀移方向与伯格斯矢量的关系。题目直接给出定义性知识，无需复杂推理或概念间的联系分析，属于最基本的概念记忆层次。" + }, + { + "idx": 1518, + "question": "What type of solid solution is ferrite formed by carbon in α-Fe", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述碳在α-Fe中形成的固溶体类型，答案\"Interstitial\"是一个术语，需要简要解释其含义和特点，属于简答题类型。 | 知识层次: 题目考查铁素体(ferrite)中碳在α-Fe中形成的固溶体类型这一基本概念的记忆和理解，属于材料科学中固溶体分类的基础知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即碳在α-Fe中形成的固溶体类型是间隙式（Interstitial）。题目不涉及复杂的概念解释或体系阐述，只需考生记住这一基本分类即可作答，属于最基础的难度等级。" + }, + { + "idx": 1519, + "question": "For a screw dislocation line, its Burgers vector is _（20） to the dislocation line", + "answer": "（20） parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（parallel）来补全句子，而不是从多个选项中选择或进行判断/计算。虽然形式上类似填空题，但更符合简答题中需要特定知识回答的特征。 | 知识层次: 题目考查对螺位错基本概念的记忆和理解，即螺位错的柏氏矢量与位错线的关系，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需考生记住螺位错的柏氏矢量与位错线的关系这一基本定义即可作答。在选择题型中，这种直接考查定义的题目属于最简单级别，不需要任何分析或推理过程。" + }, + { + "idx": 1520, + "question": "For a screw dislocation line, the direction of its slip motion is _（21）_ to the Burgers vector", + "answer": "（21）perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（perpendicular）来回答问题，属于简答题类型，需要根据知识进行简短回答而非选择或判断。 | 知识层次: 题目考查对螺位错滑移方向与伯格斯矢量关系的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即螺型位错滑移方向与伯氏矢量的关系。题目直接给出了正确选项\"perpendicular\"，无需进行复杂的概念解释或分析，属于最基础的定义简答级别。" + }, + { + "idx": 1521, + "question": "After cold plastic deformation, the strength and hardness of metal (23)—", + "answer": "(23) increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词\"increase\"作为答案，属于简短的文字回答形式，不需要选择或判断，也不需要计算 | 知识层次: 题目考查冷塑性变形后金属强度和硬度变化的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题型中属于基础难度，仅需记忆金属冷塑性变形后强度和硬度增加的基本原理，无需复杂分析或概念比较。" + }, + { + "idx": 1522, + "question": "After cold plastic deformation, the plasticity and toughness of metal (24)", + "answer": "(24) decrease", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属在冷塑性变形后的性能变化，需要文字解释和论述，答案形式为简短的文字描述而非选择或判断。 | 知识层次: 题目考查金属冷塑性变形后性能变化的基本概念记忆，属于基础概念记忆性知识，不需要复杂分析或推理。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需记忆金属在冷塑性变形后塑性和韧性的变化趋势（降低）。题目不涉及复杂概念体系或需要解释描述，解题步骤简单直接，属于最基本难度的选择题。" + }, + { + "idx": 1523, + "question": "For cold-formed components, (29)__ annealing should be performed promptly after forming to remove (30)__ and prevent deformation or cracking during use.", + "answer": "(29) stress relief; (30) residual internal stress", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定术语（stress relief和residual internal stress）来完成句子，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对冷成型后热处理的基本概念记忆，即应力退火和残余内应力的消除，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察对冷成型组件后处理工艺的基本概念记忆，即\"应力消除退火\"和\"残余内应力\"这两个术语的定义和应用场景。学生只需记住这两个专业术语的对应关系即可正确作答，无需进行概念解释或复杂分析。在选择题型内，这属于最基础的知识点考查。" + }, + { + "idx": 1524, + "question": "After metal undergoes cold plastic deformation, this phenomenon is called (25) strengthening or (26) __", + "answer": "(25) deformation; (26) work hardening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空白处的正确答案，需要根据材料科学知识进行文字回答，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查金属冷塑性变形后的强化现象的基本概念记忆，即变形强化和加工硬化的术语填空，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即金属冷塑性变形后的强化现象名称。题目直接给出两个空格的固定搭配（deformation strengthening和work hardening），属于最基础的定义性知识填空，无需解释或分析步骤。在选择题难度谱系中，这属于只需机械记忆就能完成的等级1难度。" + }, + { + "idx": 1525, + "question": "For a screw dislocation line, the direction of its cross-slip motion is __(22)__ to the Burgers vector", + "answer": "(22) perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（perpendicular）来描述螺位错线的交叉滑移方向与Burgers矢量的关系，属于需要简短文字回答的题目类型。 | 知识层次: 题目考查对螺位错运动方向与伯格斯矢量关系的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即螺位错线滑移方向与伯格斯矢量之间的关系。题目直接给出了正确选项，无需复杂的推理或分析，属于最基本的概念记忆题。" + }, + { + "idx": 1527, + "question": "Give examples of the basic strengthening forms of materials", + "answer": "The basic strengthening forms of materials include: solid solution strengthening, strain hardening, precipitation strengthening and dispersion strengthening, grain refinement strengthening, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举材料的基本强化形式，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对材料强化基本形式的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举材料强化的基本形式，但正确选项已经提供了完整的分类体系（固溶强化、应变硬化、沉淀强化、弥散强化和晶粒细化强化等）。这需要考生对材料强化机制有较全面的概念性理解，而不仅仅是记忆单个定义。题目考察的是对\"基本强化形式\"这一分类体系的掌握程度，属于概念解释和描述的层次，但不需要进行复杂的比较分析或体系阐述。" + }, + { + "idx": 1528, + "question": "Provide the Hall-Petch formula and explain the meaning and units of each physical quantity in the formula.", + "answer": "The Hall-Petch formula describes the relationship between yield strength and grain size. The formula is σ_s=σ_0+K·d^(-1/2). In the formula, σ_0 (MPa) and K (MPa·m^(1/2)) are constants; d is the grain diameter (m); σ_s is the yield strength (MPa).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供Hall-Petch公式并解释其中各物理量的含义和单位，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对Hall-Petch公式的记忆以及公式中各物理量含义和单位的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅记忆Hall-Petch公式，还需要理解并解释公式中各个物理量的含义和单位。这超出了单纯的定义记忆（等级1），但尚未达到需要阐述复杂概念体系（等级3）的程度。题目涉及的概念解释和描述属于中等难度。" + }, + { + "idx": 1529, + "question": "Provide the grain boundary segregation formula and explain the meaning and units of each physical quantity in the formula", + "answer": "The grain boundary segregation formula is C_gb=C_0·exp(-ΔE/kT)=C_0exp(-Q/RT). In the formula, C_gb and C_0 represent the grain boundary concentration and grain center concentration, respectively (both can use the same units, such as mass percentage concentration or volume concentration); ΔE is the interaction energy (eV); Q is the molar interaction energy (J), which reflects the change in grain boundary energy caused by segregation; R is the gas constant (J/K); k is the Boltzmann constant (eV/K); T is the absolute temperature (K).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提供公式并解释每个物理量的含义和单位，这需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求提供晶界偏析公式并解释各物理量的含义和单位，这涉及对公式的理解和应用，需要将多个概念（如浓度、能量、温度等）关联起来，并进行综合分析。虽然不涉及复杂的计算或推理，但需要一定的概念关联和解释能力，超出了简单记忆或直接套用的层次。 | 难度: 在选择题型中，该题目要求考生不仅要掌握晶界偏析公式的具体形式，还需要理解公式中每个物理量的具体含义和单位。这涉及到多个概念的关联和综合分析，包括浓度单位、能量单位、常数单位以及温度单位的理解。此外，题目还要求考生能够解释这些物理量在公式中的作用，这需要较深的知识掌握和多角度分析能力。因此，在选择题型中，该题目属于较高难度等级。" + }, + { + "idx": 1530, + "question": "Explain the strengthening mechanism of solid solution strengthening", + "answer": "Solid solution strengthening: For both substitutional atoms and interstitial atoms, under suitable conditions, atomic segregation may occur to form atmospheres. For substitutional lattices, when solute atoms are larger than solvent atoms, solute atoms tend to accumulate in the expanded region of edge dislocations; conversely, they accumulate in the compressed region. Interstitial atoms always tend to accumulate in the expanded region. This phenomenon of diffusion-driven accumulation near dislocations is called Cottrell atmosphere. The Cottrell atmosphere has a pinning effect on dislocations, thereby increasing strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固溶强化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及位错与溶质原子的相互作用、Cottrell气团的形成及其对位错的钉扎效应等复杂概念。需要综合运用材料科学中的晶体缺陷、扩散和强化机制等知识，进行推理分析和机理解释，思维过程深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解固溶强化的机理，包括置换原子和间隙原子的不同行为、柯垂尔气团的形成及其对位错的钉扎效应。这些知识点不仅需要记忆，还需要综合运用和推理分析，属于复杂现象的全面分析层次。选择题型中，这类题目通常要求考生具备较高的材料科学理论基础和机理解释能力，解题步骤复杂，相对难度较高。" + }, + { + "idx": 1531, + "question": "Explain the strengthening mechanism of work hardening", + "answer": "Work hardening: During the plastic deformation of cold-worked metals, a large number of dislocations are formed. Some of these dislocations become immobile dislocations, thereby increasing their resistance to mobile dislocations. This makes further deformation of the material difficult, resulting in work hardening or strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释加工硬化的强化机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释加工硬化的强化机制，涉及位错的形成、运动及其相互作用等复杂概念，需要综合运用材料科学中的位错理论和塑性变形知识进行机理层面的分析和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解位错理论、塑性变形机制以及加工硬化的微观机理，并能够将这些复杂概念整合起来进行综合解释。这需要考生具备扎实的材料科学基础，能够将抽象的理论知识与实际现象联系起来，属于复杂现象的全面分析层次。在选择题型中，这类需要深度机理解释和综合分析的题目通常是最具挑战性的。" + }, + { + "idx": 1532, + "question": "Explain the strengthening mechanisms of precipitation strengthening and dispersion strengthening", + "answer": "Precipitation strengthening and dispersion strengthening: A supersaturated solid solution undergoes decomposition upon temperature decrease or during prolonged holding (aging). The aging process is often complex; for example, in aluminum alloys, GP zones form first during aging, followed by the precipitation of transition phases (θ′′ and θ′), and finally the formation of thermodynamically stable equilibrium phases (θ). Fine precipitates dispersed in the matrix hinder dislocation motion, thereby producing a strengthening effect. This is known as 'precipitation strengthening' or 'age hardening'.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释沉淀强化和弥散强化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释沉淀强化和弥散强化的机制，涉及材料科学中的相变过程、位错运动等复杂概念，需要综合运用多个知识点进行推理分析，并深入理解材料微观结构与性能之间的关系。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解并解释两种强化机制的复杂机理，包括过饱和固溶体的分解过程、时效过程中的相变序列（如铝合金中的GP区、过渡相θ′′和θ′、平衡相θ的形成），以及这些析出相如何阻碍位错运动产生强化效应。这需要考生具备综合运用材料科学知识、进行推理分析和机理解释的能力，远超选择题型中常见的简单概念识别或记忆性内容。" + }, + { + "idx": 1533, + "question": "What is the thermodynamic condition for uphill diffusion to occur?", + "answer": "The thermodynamic condition for uphill diffusion to occur is ∂²G/∂x²<0.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释热力学条件，答案需要文字论述和解释，而不是选择、判断或计算 | 知识层次: 题目要求解释热力学条件，涉及对吉布斯自由能二阶导数的理解，需要将扩散现象与热力学概念关联起来，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解热力学条件与扩散现象之间的关联，并能够综合分析二阶导数与扩散方向的关系。题目涉及多步概念关联和综合分析，超出了基础记忆和简单应用的层次。" + }, + { + "idx": 1534, + "question": "What is uphill diffusion?", + "answer": "Uphill diffusion refers to the process where substances diffuse from regions of low concentration to regions of high concentration, resulting in an increased concentration gradient. Examples include the copper-rich clusters formed in the early stages of aging in aluminum-copper alloys and the solute-enriched regions formed during spinodal decomposition in certain alloy solid solutions. The true driving force for uphill diffusion is the chemical potential gradient, not the concentration gradient. Although diffusion leads to an increase in the concentration gradient, the chemical potential gradient actually decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"uphill diffusion\"进行文字解释和论述，答案提供了详细的定义、示例和原理说明，符合简答题的特征。 | 知识层次: 题目不仅要求解释uphill diffusion的定义，还需要论述其驱动机制（化学势梯度而非浓度梯度）和实际例子（铝铜合金时效早期和调幅分解），涉及多个概念的关联和综合分析，思维深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1535, + "question": "Recrystallization annealing", + "answer": "Recrystallization annealing: For plastically deformed metals, during the reheating process, when the temperature exceeds the recrystallization temperature, new grains with low defect density are formed, restoring properties such as strength to their pre-deformation levels, while the phase structure remains unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Recrystallization annealing\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对再结晶退火这一基本概念的记忆和理解，包括其定义、发生条件和效果，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（recrystallization annealing的定义和基本原理），但正确选项需要考生理解并描述一个相对完整的过程（包括温度条件、晶粒变化和性能恢复等），而不仅仅是简单的定义复述。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 1536, + "question": "Crystal", + "answer": "Crystal: A solid composed of atoms, molecules, or ions arranged in a regular periodic pattern", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Crystal\"进行定义和解释，需要文字描述和论述，属于简答题类型 | 知识层次: 题目考查对晶体这一基本概念的定义和记忆，属于基础概念的记忆性知识，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶体的基本定义，属于最基础的概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或分析，解题步骤极为简单，符合等级1“基本定义简答”的标准。" + }, + { + "idx": 1537, + "question": "Taking Al-4.5% Cu alloy as an example, explain the aging process and the changes in its properties (hardness).", + "answer": "After quenching, the aluminum alloy forms a supersaturated solid solution. Subsequent heating and holding cause the sequential precipitation of GP zones, θ'', θ', and θ phases within the solid solution. The formation of GP zones increases the material's hardness (the first aging peak). Prolonged aging leads to the dissolution of GP zones and a decrease in hardness. The formation of θ'' further increases the hardness (the second aging peak). When θ'' completely dissolves and transforms into θ' and θ' transforms into θ, the hardness begins to decline.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释时效处理过程及其性能变化，答案以文字论述形式详细描述了时效过程中各相的形成及其对硬度的影响，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5% Cu合金的时效过程及其硬度变化，涉及多个相变阶段（GP区、θ''、θ'和θ相）的形成和溶解，以及这些微观结构变化对宏观性能（硬度）的影响。这需要综合运用材料科学中的相变理论、强化机制等知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握铝合金时效处理的基本概念，还需要深入理解不同析出相（GP区、θ''、θ'和θ相）的形成顺序及其对硬度的影响机制。解题过程涉及多个步骤的推理分析，包括析出相的形成、溶解和转变过程，以及这些变化如何导致硬度曲线的双峰现象。此外，题目还要求考生能够将理论知识与具体合金体系（Al-4.5% Cu）相结合，进行综合分析和机理解释，这在选择题型中属于最复杂的考查形式。" + }, + { + "idx": 1538, + "question": "Taking the tensile curve of low-carbon steel as an example, use dislocation theory to explain the yield phenomenon", + "answer": "The yield of low-carbon steel is due to the fact that carbon in low-carbon steel is an interstitial atom, which interacts with dislocations in ferrite to form solute atom atmospheres, known as Cottrell atmospheres. These atmospheres have a pinning effect on dislocations, and only under higher stress can dislocations break away from the pinning of solute atoms, manifesting as the upper yield point on the stress-strain curve. Once dislocations are unpinned and continue to glide, less stress is required, which appears as the lower yield point and the horizontal plateau on the stress-strain curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释低碳钢的屈服现象，答案是一段详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢的屈服现象，涉及位错与间隙原子的相互作用、柯氏气团的形成及其对位错的钉扎效应，需要综合运用多个概念进行机理分析和解释，思维过程较为深入和复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解低碳钢的拉伸曲线特征，还需要运用位错理论深入解释屈服现象，包括柯氏气团的形成及其对位错的钉扎效应。这需要考生具备综合运用材料科学知识的能力，能够将多个复杂概念（如间隙原子、位错运动、应力-应变关系）有机结合，并进行机理层面的深度解释。这种题目在选择题中属于对知识掌握深度和综合分析能力要求极高的类型。" + }, + { + "idx": 1539, + "question": "Please explain the effect of stacking fault energy level on the cross-slip of screw dislocations", + "answer": "For metals with high stacking fault energy, during deformation, perfect dislocations are less likely to dissociate. When encountering obstacles, they can continue moving through cross-slip until they meet other dislocations and form tangles. In contrast, for metals with low stacking fault energy, their perfect dislocations easily dissociate into configurations consisting of two partial dislocations and a stacking fault, making cross-slip difficult and resulting in poor mobility of dislocation configurations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释堆垛层错能水平对螺位错交叉滑移的影响，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求解释堆垛层错能对螺位错交滑移的影响机制，涉及位错理论、晶体缺陷行为等复杂概念的综合运用和机理分析，需要深入理解材料变形过程中位错运动的微观机制及其与材料性能的关联。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解堆垛层错能的基本概念，还需要综合运用位错理论、晶体变形机制等知识，对复杂现象进行全面分析。正确选项涉及多个关键知识点（如位错解离、交滑移机制、位错缠结等），并要求考生能够对不同堆垛层错能金属的位错行为进行对比推理和机理解释。这种深度分析和综合推理能力在选择题型中属于最高层次的要求。" + }, + { + "idx": 1540, + "question": "Give the Hall-Petch formula and explain the meaning and units of each physical quantity in the formula", + "answer": "The Hall-Petch formula describes the relationship between yield strength and grain size. The formula is: σ_s = σ_0 + K·d^(-1/2). In the formula, σ_0 (MPa) is a constant; K (MPa·m^(1/2)) is a constant; d (m) is the grain diameter; σ_s (MPa) is the yield strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Hall-Petch公式并解释其中各物理量的含义和单位，这需要文字解释和论述，属于简答题类型。 | 知识层次: 题目主要考查对Hall-Petch公式的记忆以及公式中各物理量含义和单位的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅记忆Hall-Petch公式，还需要解释公式中各个物理量的含义和单位。这超出了单纯的定义记忆（等级1），但不需要复杂的推导或概念体系阐述（等级3）。题目涉及概念解释和描述，符合等级2的难度标准。" + }, + { + "idx": 1542, + "question": "Give the one-dimensional form of Fick's second law and explain the meaning and units of each physical quantity in the formula", + "answer": "The one-dimensional form of Fick's second law is: ∂C/∂t = D·∂²C/∂x². In the formula, C (g/cm³) is the concentration; D (cm²/s) is the diffusion coefficient; t (s) is the time; x (cm) is the distance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Fick's第二定律的一维形式，并解释公式中每个物理量的含义和单位。这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对Fick's第二定律一维形式的基本概念记忆，包括公式中各物理量的含义和单位，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目要求考生不仅记忆Fick's第二定律的一维形式，还需要解释公式中各个物理量的含义和单位。这属于概念解释和描述的层次，比单纯的定义简答（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。因此，该题目在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 1544, + "question": "Taking the tensile curve of low-carbon steel as an example, use dislocation theory to explain the phenomenon of work hardening", + "answer": "When deformation continues, the stress increases again due to a significant rise in the number of dislocations, a phenomenon known as work hardening. This occurs because cold-deformed metals generate a large number of dislocations during plastic deformation, some of which become immobile dislocations. These immobile dislocations increase resistance to mobile dislocations, making further deformation of the material more difficult, resulting in work hardening or strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用位错理论解释低碳钢拉伸曲线中的加工硬化现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢拉伸曲线中的加工硬化现象，涉及位错运动的机理、位错间的相互作用以及材料变形行为的综合分析。这需要深入理解位错理论，并能将其与材料的宏观力学行为联系起来，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生运用位错理论解释低碳钢拉伸曲线中的加工硬化现象，涉及复杂的机理分析和综合推理。正确选项不仅需要理解位错运动的基本概念，还需要掌握位错增殖、不动位错形成及其对材料变形抗力的影响机制。这种题目在选择题中属于对知识深度和应用能力要求极高的类型，需要考生将多个高阶概念整合并建立因果关系，完全符合\"复杂现象全面分析\"的等级5标准。" + }, + { + "idx": 1545, + "question": "5．Extended dislocation", + "answer": "A complete dislocation dissociates into two partial dislocations and the stacking fault between them, and this dislocation configuration is called an extended dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Extended dislocation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对扩展位错（extended dislocation）这一基本概念的定义和构成的理解，属于材料科学中位错理论的基础知识记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（定义、分类、基本原理等），但需要考生准确理解并区分\"complete dislocation\"、\"partial dislocations\"和\"stacking fault\"这几个专业术语及其相互关系。这比单纯记忆一个简单定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1546, + "question": "Please explain the effect of stacking fault energy on the work hardening rate of metals", + "answer": "For screw dislocations, cross-slip allows two screw dislocations of opposite signs (left and right) on the same slip plane to meet and annihilate each other, thereby reducing the dislocation multiplication rate. For metals with low stacking fault energy, cross-slip of dislocations is difficult, resulting in a high dislocation multiplication rate during deformation and an increased work hardening rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释堆垛层错能对金属加工硬化率的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释堆垛层错能对金属加工硬化率的影响机制，涉及位错运动、交叉滑移等复杂概念的综合分析和推理。需要深入理解位错行为与材料性能之间的关系，并进行机理层面的解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1547, + "question": "Using Al-4.5%Cu alloy as an example, explain the microstructural transformation during 130% aging", + "answer": "After quenching, the aluminum alloy forms a supersaturated solid solution. Subsequent heating and holding will cause the sequential precipitation of GP zones, θ′′, θ′, and θ phases within the solid solution. Among these, α and θ are equilibrium phases; GP zones, θ′′, and θ′ are metastable phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金在130%时效过程中的微观结构转变，需要详细的文字描述和论述，而不是选择、判断或计算。答案提供了详细的相变过程描述，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金在130%时效过程中的微观结构转变，涉及多个相变阶段（GP区、θ′′、θ′和θ相）的形成和演变，需要综合运用材料科学中的相变理论、热力学和动力学知识，进行机理分析和推理。这超出了简单记忆或基本应用的范围，属于对复杂过程的深入理解和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1548, + "question": "Taking the Al-4.5%Cu alloy as an example, explain the hardness changes during the 130% aging process", + "answer": "The formation of GP zones will increase the hardness of the material (the first aging peak). After prolonged aging, the GP zones dissolve, and the hardness decreases. The formation of θ′′ causes the hardness to continue increasing (the second aging peak). When θ′′ completely dissolves and transforms into θ′ and θ′ transforms into θ, the hardness begins to decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金在130%时效过程中硬度变化的原因，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金在130%时效过程中硬度的变化，涉及多个时效阶段的相变过程（GP区、θ′′、θ′和θ的形成与溶解）及其对硬度的影响。这需要综合运用材料科学中的相变理论、时效硬化机理等知识，进行多步骤的推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题中属于最高难度，需要全面理解Al-4.5%Cu合金时效过程中的多个相变阶段及其对硬度的影响机制。题目要求考生不仅掌握GP区、θ′′、θ′和θ相的形成顺序，还要理解这些相变对材料硬度变化的复杂影响（包括两次硬度峰值和中间下降过程）。这需要综合运用材料科学知识进行推理分析，属于复杂现象全面分析的层次。" + }, + { + "idx": 1549, + "question": "1. Pearlitic transformation", + "answer": "The phase transformation in which the austenite of Fe-C alloy simultaneously transforms into the eutectoid structure of ferrite and cementite below the eutectoid transformation temperature during cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对珠光体相变进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对珠光体转变这一基本概念的定义和描述，属于基础概念的记忆和理解层面 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。题目要求考生准确记忆并理解珠光体转变的定义，即奥氏体在共析转变温度以下同时转变为铁素体和渗碳体的共析结构。虽然涉及专业术语，但属于材料科学基础概念，不需要复杂的分析或比较，只需准确回忆定义即可作答。在选择题型中，这属于中等偏下的难度水平。" + }, + { + "idx": 1550, + "question": "2. Intermediate phase", + "answer": "A compound formed by two pure components with a structure different from theirs, whose composition lies between the two pure components.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Intermediate phase\"进行文字解释和论述，答案是一个详细的定义描述，而不是选择、判断或计算。 | 知识层次: 题目考查对中间相（Intermediate phase）这一基本概念的定义和特征的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但要求考生不仅记住中间相的定义，还需要理解其结构特点和成分范围。这比单纯记忆基本定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1551, + "question": "4.Coordination number", + "answer": "The number of nearest neighbor atoms around any lattice node atom in the crystal lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Coordination number\"进行文字解释和论述，答案是一个定义性的陈述，而不是选择、判断或计算。 | 知识层次: 题目考查基本概念的记忆和理解，即晶体结构中配位数的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题仅考查对\"配位数\"这一基础概念的定义记忆，属于最基础的知识点掌握要求。正确选项直接给出了晶体结构中配位数的明确定义，不需要任何解释、比较或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1552, + "question": "3.Solid solution strengthening", + "answer": "The presence of solute atoms in the solid solution causes lattice distortion of the solvent, thereby hindering dislocation motion and increasing its strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Solid solution strengthening\"进行解释说明，答案是通过文字论述来解释固溶强化的机制，符合简答题的特征。 | 知识层次: 题目考查固溶强化的基本概念和原理，属于对基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要理解固溶强化机制中溶质原子如何引起晶格畸变并阻碍位错运动。这比简单的定义记忆（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1553, + "question": "7. Up-hill diffusion", + "answer": "The diffusion of atoms from a low concentration to a high concentration region, driven by the chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Up-hill diffusion\"进行文字解释和论述，答案是一个定义性的描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即\"Up-hill diffusion\"的定义和驱动机制，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"Up-hill diffusion\"的定义及其驱动机制（化学势梯度），但不需要进行多个概念的比较分析或复杂推理。虽然涉及专业术语\"chemical potential gradient\"，但整体仍属于基础概念的记忆和理解范畴，比简单定义题稍难但未达到复杂概念体系阐述的难度。" + }, + { + "idx": 1554, + "question": "6. Eutectic transformation", + "answer": "The transformation in a binary alloy where a single liquid phase simultaneously transforms into two different solid phases at a constant temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语进行文字解释和论述，答案形式为一段描述性文字，没有选项或计算要求 | 知识层次: 题目考查对共晶转变这一基本概念的记忆和理解，属于定义性知识 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然涉及基础概念记忆，但需要考生准确理解并描述共晶转变的定义和特征，包括从单一液相同时转变为两种不同固相的过程以及恒温条件。这比简单记忆定义（等级1）要求更高，但不需要复杂的概念体系阐述（等级3）。" + }, + { + "idx": 1555, + "question": "8. Aging of aluminum alloys", + "answer": "After high-temperature solution treatment, aluminum alloys are rapidly cooled to form a supersaturated solid solution, followed by the precipitation of metastable phases during subsequent heating and holding processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对铝合金时效过程进行文字解释和论述，答案提供了详细的描述性回答，符合简答题的特征 | 知识层次: 题目涉及铝合金时效处理的多步过程（高温固溶处理、快速冷却、亚稳相析出），需要理解并关联多个概念（如过饱和固溶体、亚稳相形成等），属于中等应用层次。虽然不涉及复杂计算，但需要对时效机理有一定深度的理解。 | 难度: 在选择题中属于中等难度，题目涉及铝合金时效处理的多步过程（高温固溶处理、快速冷却、过饱和固溶体形成、亚稳相析出），需要考生理解并关联多个材料科学概念。虽然不需要多角度分析或深度关联性分析，但要求对铝合金热处理原理有较好的掌握，并能综合分析各步骤之间的逻辑关系。" + }, + { + "idx": 1556, + "question": "Based on the relationship between dislocation motion and crystal slip, analyze the relationship between the Burgers vector of a pure screw dislocation and the direction of the dislocation line", + "answer": "The Burgers vector is parallel to the direction of the dislocation line", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错运动与晶体滑移之间的关系，并解释纯螺型位错的Burgers矢量与位错线方向的关系。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析纯螺型位错的Burgers矢量与位错线方向之间的关系，这需要深入理解位错运动与晶体滑移的机理，并进行推理分析。这超出了基础概念记忆和简单应用的范畴，属于需要综合运用知识进行复杂分析的层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生深入理解位错运动与晶体滑移的关系，并能够综合运用这些知识来分析纯螺型位错的Burgers矢量与位错线方向的关系。这需要考生具备机理深度解释的能力，而不仅仅是简单的记忆或识别。此外，题目涉及的知识点较为复杂，解题步骤需要一定的推理和分析，因此在选择题型内属于等级4的难度。" + }, + { + "idx": 1557, + "question": "10. First-order phase transition", + "answer": "A phase transition where the free energies of the old and new phases are equal before and after the transition, but their first-order partial derivatives are unequal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"First-order phase transition\"进行文字解释和论述，答案是一个详细的定义描述，符合简答题的特征。 | 知识层次: 题目考查一级相变的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆一级相变的定义，即自由能在相变前后相等但一阶偏导数不等。虽然需要掌握一定的概念知识，但不需要复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 1559, + "question": "9. Recrystallization", + "answer": "For plastically deformed metals, during the reheating process, when the temperature exceeds the recrystallization temperature, new grains with low defect density are formed, restoring their properties such as strength to the pre-deformation level, while the phase structure remains unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对再结晶过程进行文字解释和论述，答案提供了详细的描述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对再结晶过程的基本概念和原理的记忆和理解，涉及变形金属在加热过程中新晶粒的形成和性能恢复，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然涉及的是基础概念记忆，但需要考生对再结晶过程有较为全面的理解，包括温度条件、晶粒变化、性能恢复等多方面内容。题目要求考生能够将多个知识点整合成一个连贯的描述，比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1560, + "question": "State Fick's second law (one-dimensional) and explain the meaning and units of each physical quantity in the formula", + "answer": "Fick's second law (one-dimensional): ∂C/∂t=D(∂²C/∂x²). In the formula, C is the concentration (g/cm³); D is the diffusion coefficient (cm²/s); t is the time (s); x is the distance (cm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求陈述Fick第二定律并解释公式中每个物理量的含义和单位，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对Fick第二定律的基本记忆和理解，包括公式中各物理量的含义和单位，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅记忆菲克第二定律的数学表达式，还需要解释公式中各个物理量的含义和单位。这超出了单纯的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。题目考察的是对基础概念的理解和描述能力，属于概念解释和描述层次，因此评定为等级2难度。" + }, + { + "idx": 1564, + "question": "Based on the relationship between dislocation motion and crystal slip, analyze the relationship between the Burgers vector of a pure edge dislocation and the direction of dislocation line motion", + "answer": "The Burgers vector is parallel to the direction of dislocation line motion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析位错运动与晶体滑移之间的关系，并解释纯刃位错的Burgers矢量与位错线运动方向的关系。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析刃位错的Burgers矢量与位错线运动方向之间的关系，这需要理解位错运动的基本原理和晶体滑移的机制，涉及多个概念的关联和综合分析。虽然不涉及复杂的计算或深度推理，但需要一定的概念理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握位错运动与晶体滑移的关系，并能够分析纯刃位错的伯氏矢量与位错线运动方向之间的关系。这需要考生具备一定的概念关联和综合分析能力，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1567, + "question": "Describe the main characteristics of martensitic transformation.", + "answer": "The fundamental characteristics of martensitic transformation are as follows (primarily the first two points): (1) Diffusionless nature. During martensitic transformation, atomic diffusion is not required, and there is no process of atomic mixing or remixing. The new phase M has exactly the same chemical composition as the parent phase A. (2) Shear nature. Specifically manifested as: $\\textcircled{1}$ Coordinated consistency of transformation: $\\mathbf{A}{\\longrightarrow}\\mathbf{M}$ $\\mathbf{FCC}{\\rightarrow}\\mathbf{BCC}$ ). Through the coordinated movement of atoms (shear), the crystal structure changes from FCC to BCC. The displacement distance of atoms is less than the interatomic spacing. $\\textcircled{2}$ Surface relief effect. On a polished surface, if martensitic transformation occurs, a surface relief effect will be produced during shear. This is due to the lattice deformation causing shape changes in the transformation region. $\\textcircled{3}$ Habit plane. M always precipitates on specific crystallographic planes of the parent phase, accompanied by the shear of the M phase transformation, generally parallel to this plane. This plane is shared by the matrix and the M phase and is called the habit plane. $\\textcircled{4}$ A definite crystallographic orientation relationship exists between the new phase and the parent phase. Two well-known orientation relationships (for steel M transformation) are the K-S relationship and the Nishiyama relationship. In practical materials, martensitic transformation usually deviates from these relationships by a few degrees. (3) Lattice distortion accompanies martensitic transformation. (4) Martensitic transformation has a start temperature $M_{\\mathrm{s}}$ and a finish temperature $M_{\\mathrm{f}}$ (or $M_{z}$ ).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述马氏体转变的主要特征，答案以详细的文字解释和论述形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求详细描述马氏体相变的主要特征，涉及多个方面的深入解释，包括扩散性、剪切性、表面浮雕效应、惯习面、晶体学取向关系以及相变温度等。这些内容不仅需要记忆和理解，还需要对相关概念进行关联和综合分析，解释其机理和相互关系。因此，属于复杂分析层次。 | 难度: 在选择题型内，该题目要求考生全面理解马氏体相变的核心特征，包括无扩散性、剪切特性、晶格畸变以及相变温度等复杂概念。题目不仅要求记忆多个关键点，还需要综合运用这些知识进行推理分析，解释相变机理。这种深度和广度的知识要求，以及解题步骤的复杂性，使得该题目在选择题型中属于最高难度等级。" + }, + { + "idx": 1568, + "question": "1. Precipitation (secondary crystallization)", + "answer": "The separation of another solid phase from a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Precipitation (secondary crystallization)\"进行解释，答案是一个文字描述的定义，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查的是对\"precipitation (secondary crystallization)\"这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"precipitation (secondary crystallization)\"这一基础概念的定义记忆，属于最基础的知识点。正确选项直接给出了该术语的标准定义，无需任何解释、分析或推理过程，完全符合等级1\"基本定义简答\"的特征。这类题目只需考生记住教材中的基础概念即可作答，是选择题中最简单的类型。" + }, + { + "idx": 1569, + "question": "Briefly describe the recovery process of deformed metal during heating and the changes in its microstructure and properties", + "answer": "When the temperature is below the recrystallization temperature, the main processes include the reduction in the concentration of point defects, the elimination of internal stresses, and the change in dislocation configuration, with no alteration in the optical microstructure; at this stage, mechanical properties such as strength, hardness, and plasticity remain largely unchanged, but electrical resistance decreases significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述变形金属在加热过程中的回复过程及其微观结构和性能的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述金属在加热过程中的回复过程及其微观结构和性能的变化，涉及多个概念的关联和综合分析。虽然不需要复杂的推理或创新应用，但需要对回复过程、微观结构变化和性能变化有较深入的理解和关联分析，属于中等应用层次。 | 难度: 在选择题型内，该题目需要考生对金属变形后的回复过程有较深入的理解，包括回复阶段和再结晶阶段的区别，以及微观结构和性能的变化。题目要求考生综合分析多个概念（如点缺陷浓度、内应力消除、位错构型变化）及其对性能的影响（强度、硬度、塑性、电阻率的变化）。此外，题目还涉及光学显微组织的不变性和机械性能的保持，这需要考生具备多角度分析的能力。因此，在选择题型内，该题目属于较高难度，需要考生进行多角度分析论述。" + }, + { + "idx": 1570, + "question": "Briefly describe the recrystallization process of deformed metal during heating and the changes in its microstructure and properties", + "answer": "After reaching or exceeding the recrystallization temperature, new grains with low defect density will form within the original deformed grains, and the grains are basically equiaxed. At this time, mechanical properties such as strength and physical properties quickly recover to the levels before deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述变形金属在加热过程中的再结晶过程及其微观结构和性能的变化，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对金属再结晶过程的基本概念和原理的记忆和理解，包括再结晶温度、新晶粒的形成、微观结构和性能的变化等基础知识点。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及金属再结晶过程的基本概念和微观结构变化，但正确选项已经提供了较为详细的描述，包括再结晶温度、新晶粒的形成、缺陷密度降低以及力学性能恢复等关键点。这要求考生不仅记住基本定义，还需要理解并描述这些概念之间的关系和变化过程。然而，由于选项已经概括了主要知识点，不需要考生进行复杂的分析或比较，因此难度等级为2。" + }, + { + "idx": 1571, + "question": "2. Space group", + "answer": "A symmetry group formed by the combination of all symmetry elements (including microscopic symmetry elements) in a crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Space group\"进行文字解释和论述，答案是一个详细的定义，不需要选择、判断或计算 | 知识层次: 题目考查对空间群这一基本概念的定义记忆和理解，属于晶体学中的基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目涉及空间群的定义，但只需要记忆和理解对称元素组合形成空间群的基本概念，不需要进行复杂的分析或比较多个概念。因此，难度属于中等偏下。" + }, + { + "idx": 1572, + "question": "8. Dynamic recrystallization", + "answer": "The phenomenon where deformation and recrystallization occur simultaneously above the recrystallization temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dynamic recrystallization\"这一现象进行文字解释和论述，答案是一个定义性的文字描述，符合简答题的特征。 | 知识层次: 题目考查动态再结晶这一基本概念的定义，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别动态再结晶的基本定义，属于最基础的概念记忆层次。题目直接给出了定义描述作为正确选项，无需进行复杂的概念比较或分析，因此属于难度等级1。" + }, + { + "idx": 1573, + "question": "Give examples of the basic strengthening mechanisms of materials", + "answer": "The basic strengthening mechanisms of materials include: solid solution strengthening, work hardening, grain refinement strengthening, and dispersion strengthening. Specific examples: carbon forms a solid solution in ferrite, causing solid solution strengthening; the hardness of pure aluminum sheets increases after repeated processing, and the strength of cold-drawn steel wires significantly improves; modification treatment can refine the strength of cast aluminum alloys, mainly due to grain refinement; the carbides in granular pearlite play the role of dispersion strengthening, and additionally, the finely dispersed carbides in tempered martensite have a good strengthening effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释材料的基本强化机制，答案提供了详细的文字解释和具体例子，符合简答题的特征。 | 知识层次: 题目考查对材料强化机制的基本概念的记忆和理解，包括各种强化机制的定义和简单例子，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举材料的基本强化机制及其具体例子，但主要考察的是对基础概念的记忆和理解。正确选项提供了清晰的分类和具体实例，考生需要掌握这些基本概念并能正确对应实例。相比于等级1的简单定义记忆，该题目需要更深入的概念解释和描述，但不需要进行复杂的体系阐述或分析，因此属于等级2难度。" + }, + { + "idx": 1574, + "question": "5. Austenite", + "answer": "An interstitial solid solution of carbon dissolved in γ-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Austenite\"进行解释，答案是一个文字描述的定义，符合简答题的特征 | 知识层次: 题目考查对奥氏体（Austenite）这一基本概念的定义记忆，属于材料科学中基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，此题仅考察对奥氏体基本定义的记忆，属于最基础的概念性知识。正确选项直接给出了标准定义，不需要任何解释或分析步骤，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1575, + "question": "4. Constitutional supercooling", + "answer": "During crystallization, the phenomenon where a supercooled zone forms in the liquid phase near the solid-liquid interface due to the redistribution of components between the solid and liquid phases is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Constitutional supercooling\"这一现象进行文字解释和论述，答案提供了详细的定义和解释，符合简答题的特征。 | 知识层次: 题目考查对\"Constitutional supercooling\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并描述\"constitutional supercooling\"这一现象的定义和形成原因。这比简单识别定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1576, + "question": "In NaCl-type crystals, what type of voids are entirely filled by Na+ ions?", + "answer": "Octahedral", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释回答特定问题，答案是一个专业术语而非从多个选项中选择或判断对错，也不需要计算过程 | 知识层次: 题目考查对NaCl晶体结构中空隙类型的基础概念记忆，仅需识别Na+离子占据的八面体空隙类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对NaCl晶体结构中空隙类型的基础记忆，属于最基础的定义简答级别。学生只需记住Na+离子占据的是八面体空隙即可作答，无需任何解释或复杂推理过程。" + }, + { + "idx": 1577, + "question": "6．Critical deformation", + "answer": "The minimum pre-deformation required to cause recrystallization in a metal material when heated above the recrystallization temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Critical deformation\"进行定义和解释，需要文字描述和论述，而不是选择、判断或计算。答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查的是\"Critical deformation\"这一专业术语的基本定义，属于金属材料再结晶过程中的基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但要求考生不仅知道\"Critical deformation\"这个术语，还需要理解其具体定义和应用场景（即金属材料在再结晶温度以上加热时引发再结晶所需的最小预变形量）。这比单纯识别术语名称（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1578, + "question": "Explain in detail one of the strengthening mechanisms (using solid solution strengthening as an example)", + "answer": "Dislocation theory explanation of solid solution strengthening: It is necessary to elaborate on the hindering effect of various strengthening factors on dislocation motion to improve material strength. For example, whether substitutional atoms or interstitial atoms, under suitable conditions, may undergo atomic segregation to form atmospheres. For substitutional lattices, when solute atoms are larger in diameter than solvent atoms, solute atoms tend to accumulate in the expanded region of edge dislocations; conversely, they accumulate in the compressed region. Interstitial atoms always tend to accumulate in the expanded region. This phenomenon of diffusion-induced enrichment near dislocations is called the Cottrell atmosphere. The Cottrell atmosphere has a pinning effect on dislocations, increasing the resistance to dislocation motion, thereby enhancing strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释一种强化机制（以固溶强化为例），答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细解释固溶强化的位错理论机制，涉及位错运动受阻的机理解释、柯垂尔气团的形成原理及其对位错的钉扎效应。这需要综合运用材料科学中的位错理论、原子扩散和强化机制等知识，进行深入的推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要深入掌握位错理论、Cottrell气团的形成机制及其对位错运动的阻碍作用。这涉及到复杂的材料科学原理和微观机制分析，属于选择题型中的最高难度等级。考生需要综合运用多个知识点，进行推理和解释，才能正确回答。" + }, + { + "idx": 1579, + "question": "What type of void does the Cs+ ion occupy in CsCl crystal?", + "answer": "Cubic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字回答Cs+离子在CsCl晶体中占据的空隙类型，答案\"Cubic\"是一个简短的描述性回答，不需要选择或判断，也不需要计算。 | 知识层次: 题目考查对CsCl晶体结构中Cs+离子占据的空隙类型的基本概念记忆，属于晶体结构分类的基础知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅考察对CsCl晶体中Cs+离子占据空隙类型的基础记忆，属于基本定义简答级别。学生只需记住CsCl晶体结构中阳离子占据立方空隙这一基本事实即可作答，无需进行概念解释或复杂分析。" + }, + { + "idx": 1580, + "question": "9. Spinodal decomposition", + "answer": "A transformation in which a solid solution decomposes into two solid solutions with the same structure as the parent phase but different compositions through uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Spinodal decomposition进行文字解释和论述，答案是一个详细的定义描述，符合简答题的特征 | 知识层次: 题目考查对Spinodal decomposition这一基础概念的定义和基本原理的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项需要对spinodal decomposition的定义和过程有较为清晰的理解，包括\"uphill diffusion\"这一关键概念。这超出了简单的定义记忆（等级1），需要一定的概念解释和描述能力（等级2），但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 1581, + "question": "10. Habit plane", + "answer": "During solid-state phase transformation, the new phase often forms along specific atomic planes of the parent phase. The parent phase crystal plane that is parallel to the main plane of the new phase is called the habit plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Habit plane\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对“habit plane”这一基本概念的定义和解释，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解并记忆\"habit plane\"的定义，即在新相形成过程中与母相特定原子平面对齐的晶体平面。虽然涉及固态相变的基本概念，但不需要复杂的分析或比较多个概念，只需准确描述定义即可。这符合等级2\"概念解释和描述\"的要求。" + }, + { + "idx": 1582, + "question": "7. Deformation texture", + "answer": "As the amount of plastic deformation increases, the phenomenon where a certain crystallographic orientation of different grains in a polycrystal tends to become consistent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Deformation texture\"这一概念进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查对\"变形织构\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及应用或分析层面的要求。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然题目涉及变形织构的定义，但正确选项已经提供了较为详细的解释，考生只需理解并匹配这一描述即可。不需要进行复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 1583, + "question": "3. Dislocation intersection", + "answer": "The phenomenon where dislocations moving on different slip planes meet and cut through each other during motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dislocation intersection\"现象进行文字解释和论述，答案以描述性文字呈现，符合简答题的特征 | 知识层次: 题目考查的是位错相交这一基本概念的定义和现象描述，属于材料科学中基础概念的记忆和理解范畴，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，此题仅要求考生记忆并识别位错相交的基本定义，属于最基础的概念记忆层次。题目直接给出了现象的定义描述，不需要进行任何概念比较或复杂分析，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1584, + "question": "1. The macroscopic symmetry elements of crystals include (1), (2), (3), (4), and (5)", + "answer": "(1) center of symmetry; (2) axis of symmetry; (3) plane of symmetry; (4) rotoinversion axis; (5) rotoreflection axis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举晶体的宏观对称元素，答案需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对晶体宏观对称元素的基本概念的记忆和理解，不需要复杂的应用或分析，只需列举出对称元素的名称即可。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆晶体宏观对称元素的基本分类，无需进行概念解释或复杂体系阐述。正确选项直接对应基础概念记忆的知识层次，解题步骤简单，仅需识别和匹配对称元素的名称即可。" + }, + { + "idx": 1585, + "question": "In fluorite, what type of voids are entirely occupied by F- ions?", + "answer": "Tetrahedral", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用简短的文字回答特定类型的问题，答案是一个专业术语而非选择或判断 | 知识层次: 题目考查对氟化钙晶体结构中空隙类型的基础概念记忆，仅需识别F-离子占据的空隙类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即氟化钙（萤石）结构中F-离子占据的空隙类型。题目直接给出正确选项\"Tetrahedral\"，无需任何解释或推理过程，属于最简单的定义性知识考查。" + }, + { + "idx": 1586, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (11)", + "answer": "(11) interstitial mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的微观机制名称作为答案，属于需要简短文字回答的类型，而不是从多个选项中选择或判断对错 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶体固体中扩散的微观机制之一——间隙机制（interstitial mechanism）。这属于基础概念记忆层次，无需解释或分析，只需直接回忆定义或分类即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1587, + "question": "In the heterogeneous nucleation model, what value of the contact angle θ between the nucleus and the substrate plane cannot promote nucleation?", + "answer": "π", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在异质成核模型中接触角θ的哪个值不能促进成核，需要文字解释和论述，而不是从选项中选择或简单的判断对错。答案π是一个具体的数值，但题目本身更侧重于理解和解释概念。 | 知识层次: 题目涉及异质成核模型中的接触角θ对成核的促进作用，需要理解接触角与成核能垒之间的关系，并分析特定角度（π）为何不能促进成核。这需要多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解异质成核模型中的接触角概念，并知道接触角θ为π时无法促进成核。虽然题目涉及中等应用层次的知识，但在选择题型中，通过排除法或记忆关键概念即可解答，不需要进行复杂的多步计算或深度关联性分析。" + }, + { + "idx": 1588, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (12)", + "answer": "(12) interstitial mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体固体中扩散的微观机制，答案以文字形式给出，需要简要描述扩散机制的类型。 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶体固体中扩散的微观机制之一（间隙机制），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释、比较或分析多个概念，因此属于选择题型中最简单的难度等级。" + }, + { + "idx": 1589, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (13)", + "answer": "(13) vacancy mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体固体中扩散的微观机制，答案需要提供具体的机制名称（空位机制），属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查晶体固体中扩散的微观机制，特别是空位机制的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题仅要求识别扩散机制的基本定义（空位机制），属于最基础的概念记忆层次。无需解释或比较其他机制，解题步骤简单直接，符合等级1的基本定义简答标准。" + }, + { + "idx": 1590, + "question": "In the heterogeneous nucleation model, when the contact angle θ between the nucleus and the substrate plane is π/2, what fraction of the homogeneous nucleation energy is the nucleation energy?", + "answer": "Half", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定条件下（接触角θ=π/2）异质形核能与均质形核能的比例关系，并给出了具体的答案（Half），这需要理解形核理论并应用相关概念进行解释，属于需要文字解释的简答题类型。 | 知识层次: 题目涉及异质成核模型中的接触角概念，需要理解接触角与成核能之间的关系，并进行简单的数学推导（当θ=π/2时，成核能是均质成核能的一半）。这属于中等应用层次，需要将概念与计算相结合，但不需要复杂的综合分析或推理。 | 难度: 在选择题中属于中等难度，需要理解异质成核模型中的接触角概念，并能将其与均质成核能量进行关联计算。虽然题目给出了具体角度（π/2），但仍需掌握能量分数计算的基本原理，属于需要多步概念关联和综合分析的中等应用层次。" + }, + { + "idx": 1591, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (14)", + "answer": "(14) exchange mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散的微观机制，需要文字描述而非选择或判断，答案形式为简短的文字回答而非计算 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对扩散微观机制中最基础的定义性知识（交换机制）的记忆，属于最基础的概念记忆层次。题目仅要求识别正确选项，无需解释或分析，解题步骤极为简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1592, + "question": "Small-angle grain boundaries are composed of dislocations, among which symmetric tilt grain boundaries are composed of what type of dislocations?", + "answer": "Edge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答特定类型的位错（edge dislocations），需要简要的文字解释而非选择或判断。答案形式为简短的术语，符合简答题的特征。 | 知识层次: 题目考查对称倾斜晶界由何种位错组成的基本概念记忆，属于材料科学中位错与晶界关系的基础知识点，仅需直接回忆教材定义即可作答。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即对称倾斜晶界由何种位错组成。题目直接给出正确选项\"Edge\"，无需复杂推理或概念比较，属于最基本的知识点记忆题。" + }, + { + "idx": 1593, + "question": "Small-angle grain boundaries are composed of dislocations, among which twist boundaries are composed of what type of dislocations?", + "answer": "Screw", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求回答特定类型的位错名称，需要简洁的文字回答，而不是从多个选项中选择或判断对错，也不需要复杂的计算。 | 知识层次: 题目考查对晶界和位错类型的基本概念记忆，特别是扭转晶界的组成位错类型，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并区分不同类型位错（如刃位错和螺位错）在晶界中的具体应用。题目要求考生不仅记住小角度晶界的组成，还要明确扭转晶界由螺位错构成这一特定知识点。这比单纯记忆定义（等级1）要求更高，但尚未达到需要复杂概念体系阐述（等级3）的程度。" + }, + { + "idx": 1594, + "question": "1. What is aging treatment?", + "answer": "The process of treating the precipitation of a supersaturated solid solution is called aging treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"aging treatment\"进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征 | 知识层次: 题目考查对\"aging treatment\"这一基本概念的定义记忆和理解，属于材料科学中的基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对\"aging treatment\"基础定义的记忆，属于最简单的定义简答类型。正确选项直接给出了术语的标准定义，不需要任何解释、分析或推理过程，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1595, + "question": "6．Adsorption occurring on solid surfaces can be divided into two types: (17) and (18).", + "answer": "(17) Physical adsorption; (18) Chemical adsorption", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空白处的具体术语，需要准确的知识点记忆和术语应用，属于简答题类型 | 知识层次: 题目考查固体表面吸附现象的基本分类记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆固体表面吸附的两种基本类型（物理吸附和化学吸附），属于最基础的定义性知识。题目不涉及概念解释或复杂体系分析，仅需简单回忆即可作答，因此属于等级1难度。" + }, + { + "idx": 1599, + "question": "What is the difference in deformation mode between slip and twinning, the two mechanisms of metal plastic deformation?", + "answer": "The slip process involves the relative sliding of one part of the crystal relative to another, while the twinning process involves the uniform shear of one part of the crystal relative to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制的区别，答案需要文字解释和论述，没有提供选项或要求进行判断或计算。 | 知识层次: 题目考查金属塑性变形中滑移和孪生两种机制的基本概念和区别，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（滑移和孪生的定义），但需要考生理解并区分两种塑性变形机制的具体差异（相对滑动 vs 均匀剪切）。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。正确选项通过对比方式清晰解释了两种机制的关键区别，符合选择题型中对概念解释和描述的要求。" + }, + { + "idx": 1600, + "question": "Explain the reason for the shape memory effect produced by martensitic transformation", + "answer": "The fundamental reasons are the diffusionless nature, coherent shear characteristics, and reversible transformation of martensitic transformation. During the cooling process of the parent phase, external stress induces martensitic transformation, utilizing the pseudoelasticity of martensitic transformation to produce macroscopic deformation. During the heating process, when the temperature exceeds the reverse transformation temperature of martensitic transformation, shape recovery occurs along with the reverse transformation of thermoelastic martensite, completing the shape memory process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变产生形状记忆效应的原因，需要文字解释和论述，答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释马氏体相变产生形状记忆效应的原因，涉及扩散特性、相干剪切特性和可逆相变等复杂机理的综合分析。需要深入理解马氏体相变的特性及其与形状记忆效应的关系，并进行推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解马氏体相变的扩散性、相干剪切特性和可逆转变等复杂机理，并能将这些概念综合运用到形状记忆效应的解释中。正确选项不仅涉及多个高级材料科学概念的整合，还需要对相变过程中的热力学和动力学有深刻理解。这种题目在选择题中属于需要全面分析复杂现象的难度水平，远超简单记忆或基础理解的题目要求。" + }, + { + "idx": 1601, + "question": "3. In practical applications, what treatment methods can be used to eliminate age hardening? Why?", + "answer": "Age hardening can be eliminated through reversion treatment or re-solution treatment. This is because the second phase precipitated during aging will dissolve back into the solid solution during reversion treatment or re-solution treatment. When the precipitated phase has already become a stable phase, only solution treatment can be used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释消除时效硬化的处理方法及其原因，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目不仅要求记忆消除时效硬化的方法（reversion treatment或re-solution treatment），还需要理解这些处理方法背后的原理（第二相溶解回固溶体），并能够根据时效阶段（亚稳态或稳定相）选择适当的处理方法。这涉及到多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 1603, + "question": "What is the difference in continuity between the two metal plastic deformation mechanisms of slip and twinning?", + "answer": "The slip process can proceed continuously while the twinning process cannot proceed continuously.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制（滑移和孪生）在连续性方面的差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属塑性变形机制中滑移和孪生两种基本过程的理解和记忆，属于基础概念的记忆和简单对比。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。虽然题目涉及两种金属塑性变形机制（滑移和孪生）的比较，但正确选项仅要求考生区分两者的连续性差异这一特定概念特征，不需要进行复杂的体系阐述或多概念交叉分析。在选择题型中，这属于对基础概念的理解和简单应用，符合等级2\"概念解释和描述\"的难度特征。" + }, + { + "idx": 1604, + "question": "What is the difference in critical shear stress between the two metal plastic deformation mechanisms of slip and twinning?", + "answer": "The critical shear stress required for twinning is much greater than that for slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制（滑移和孪生）在临界剪切应力上的差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属塑性变形两种机制（滑移和孪生）的基本概念记忆和理解，特别是临界剪切应力的差异这一基本原理。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（金属塑性变形的两种机制），但需要考生不仅记住滑移和孪生的定义，还要比较两者的临界剪切应力差异。这比单纯记忆单个概念（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。正确选项直接给出了比较结论，降低了分析难度，但仍属于概念解释和描述层面的考查。" + }, + { + "idx": 1605, + "question": "2. Explain the reasons for strengthening through aging treatment.", + "answer": "During the precipitation process of a supersaturated solid solution, the initially formed metastable precipitates maintain coherent or semi-coherent interfaces with the matrix phase. If the precipitate particles possess high strength, they will cause the gliding dislocations to bend and bypass the second-phase particles, leaving dislocation loops behind. This increases the dislocation line length, and both the second-phase particles and the dislocation loops enhance the resistance to subsequent dislocation motion, resulting in second-phase strengthening. If the precipitate particles can undergo deformation, new phase interfaces will form, disrupting the coherent (or semi-coherent) interfaces between the precipitates and the matrix phase. The slip planes will experience misfit, potentially destroying the ordered arrangement. In summary, macroscopic strengthening is achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释时效处理强化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释时效强化的机理，涉及析出相与基体相的界面关系、位错运动与第二相粒子的相互作用、以及宏观强化效果的成因。这需要综合运用材料科学中的相变理论、位错理论和强化机制等多方面知识，进行深入的推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解时效强化处理的机理，包括亚稳析出相与基体相的共格/半共格界面关系、位错绕过第二相粒子的过程、位错环的形成及其对后续位错运动的阻碍作用等复杂概念。此外，还需要综合理解析出相变形对界面关系和有序排列的影响。这些知识点涉及材料科学中较为深入的理论，需要考生具备较强的综合分析能力和机理解释能力。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最高难度级别。" + }, + { + "idx": 1606, + "question": "What is the difference between the effects of slip and twinning, these two metal plastic deformation mechanisms, on the crystal orientation relationship?", + "answer": "The twinning process alters the crystal orientation relationship. The slip process does not change the crystal orientation relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种金属塑性变形机制（滑移和孪生）对晶体取向关系的影响差异，答案以文字形式进行论述和比较，符合简答题的特征。 | 知识层次: 题目考查对金属塑性变形机制（滑移和孪生）对晶体取向关系影响的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（滑移和孪生两种金属塑性变形机制），但需要考生理解并区分这两种机制对晶体取向关系的具体影响。正确选项明确指出了孪生过程会改变晶体取向关系而滑移过程不会，这要求考生不仅要记住定义，还要能够比较和区分两种机制的效果。因此，该题目在选择题型内属于概念解释和描述的难度等级。" + }, + { + "idx": 1607, + "question": "What are the causes and movement characteristics of Shockley partial dislocations in face-centered cubic crystals?", + "answer": "In face-centered cubic crystals, Shockley partial dislocations are generated by non-uniform slip. They can be edge dislocations, screw dislocations, or mixed dislocations, and are capable of slipping.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Shockley partial dislocations的成因和运动特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Shockley不全位错的成因和运动特性，涉及面心立方晶体中的位错理论、位错类型（刃型、螺型、混合型）及其滑移能力。这需要综合运用材料科学中的位错理论，进行机理分析和推理，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1608, + "question": "7．The main resistances to solid-state phase transformation are (19) and (20)", + "answer": "(19) interfacial energy; (20) elastic strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个主要的固态相变阻力，答案需要提供具体的术语（界面能和弹性应变能），属于简答题类型，需要文字解释和论述。 | 知识层次: 题目考查对固态相变主要阻力的基本概念记忆，即界面能和弹性应变能，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求填写固态相变的主要阻力，正确选项直接给出了两个基础概念（界面能和弹性应变能），无需复杂推理或概念间的比较分析。这属于对基础概念记忆的直接考察，符合等级1的标准。" + }, + { + "idx": 1609, + "question": "What is a perfect dislocation?", + "answer": "A dislocation whose Burgers vector equals a lattice vector is called a perfect dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"perfect dislocation\"进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查基本概念的记忆和理解，即完美位错的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类，仅需识别和回忆\"perfect dislocation\"的定义即可作答。题目直接给出了定义性描述，不需要任何解释或推理过程，符合等级1\"基本定义简答\"的标准。在选择题难度谱系中，这是最基础级别的题目类型。" + }, + { + "idx": 1610, + "question": "What are the differences in the roles of slip and twinning as two mechanisms of metal plastic deformation during plastic deformation?", + "answer": "Slip is the primary mechanism of plastic deformation. When the slip system is unfavorable for slip deformation to occur, twinning can alter the orientation of the slip system relative to the external force, enabling further slip deformation to proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两种金属塑性变形机制（滑移和孪生）在塑性变形过程中的作用差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释滑移和孪生两种塑性变形机制在金属塑性变形中的作用差异，需要对两种机制的机理、相互关系及其在变形过程中的作用进行深入分析和综合理解。这涉及多个概念的关联和推理分析，超出了简单记忆或基本应用的范围。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解滑移和孪生两种塑性变形机制的基本概念，还需要深入分析它们在金属塑性变形过程中的相互作用和协同效应。正确选项涉及对变形机理的深度解释（滑移作为主要机制）以及复杂现象的综合分析（当滑移系统不利时，孪生如何通过改变晶格取向来促进后续滑移）。这需要考生具备将多个知识点进行整合、推理和应用的能力，远超简单的概念识别或记忆性题目。在选择题型中，此类需要机理深度解释和复杂现象全面分析的题目属于最难的一类。" + }, + { + "idx": 1611, + "question": "What is the shape memory effect?", + "answer": "When certain metal materials are deformed and then heated above a specific temperature, the deformed metal materials return to their pre-deformation shape. This phenomenon is called the shape memory effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"shape memory effect\"进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查形状记忆效应的基本定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对形状记忆效应基本定义的记忆，无需解释或分析复杂概念体系。正确选项直接给出了定义，属于基础概念记忆层次，符合等级1的难度标准。" + }, + { + "idx": 1612, + "question": "What are the formation and movement characteristics of Frank partial dislocations in face-centered cubic crystals?", + "answer": "Frank partial dislocations are caused by the removal or insertion of a close-packed plane, and their Burgers vector is perpendicular to the slip plane. Therefore, Frank partial dislocations cannot glide but can only climb.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Frank partial dislocations的形成和运动特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Frank不全位错的形成和运动特性，涉及位错的形成机制、Burgers向量的方向性以及位错滑移和攀移的区别。这需要综合运用位错理论、晶体结构知识以及位错运动的机理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1613, + "question": "Metallic bond", + "answer": "The bonding force between metal atoms formed by the interaction between metal cations and free electrons is called metallic bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Metallic bond\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查金属键的基本定义和形成原理，属于基础概念的记忆和理解，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆金属键的基本定义，属于最基础的概念记忆层次。题目直接给出了金属键的明确定义，无需任何解释或分析步骤，符合选择题型中最简单的难度标准。" + }, + { + "idx": 1614, + "question": "Interstitial solid solution", + "answer": "When the solute atoms are relatively small, they can enter the interstitial sites of the solvent lattice, and the solid solution formed in this way is called an interstitial solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Interstitial solid solution\"进行文字解释和论述，答案提供了详细的定义和形成机制，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体这一基本概念的定义和形成条件的记忆和理解，属于材料科学中最基础的概念性知识。 | 难度: 在选择题型中，该题目仅考察对\"interstitial solid solution\"基本定义的记忆，不需要解释或分析多个概念。正确选项直接给出了定义，属于最基础的概念记忆层次，因此难度等级为1。" + }, + { + "idx": 1615, + "question": "Schottky vacancy", + "answer": "A vacancy formed by the migration of a displaced atom to the outer surface or internal interface (such as grain boundaries, etc.) is called a Schottky vacancy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对Schottky vacancy进行文字解释和论述，答案以定义的形式给出，符合简答题的特征 | 知识层次: 题目考查Schottky vacancy的基本定义和形成过程，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别Schottky vacancy的基本定义，属于基础概念记忆层次。题目描述直接给出了定义，没有涉及复杂的概念体系或需要推理分析的内容，因此属于最简单的难度等级。" + }, + { + "idx": 1616, + "question": "The _（3）__ of an atom or ion refers to the number of atoms directly adjacent to it in the crystal structure or the number of all hetero-ions combined with it.", + "answer": "（3）coordination number", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（coordination number），属于需要简短文字回答的类型，而不是从选项中选择或判断对错。 | 知识层次: 题目考查的是\"配位数\"这一基本概念的定义和记忆，属于材料科学中最基础的概念之一，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即\"coordination number\"的定义。学生只需识别并选择正确的术语填空，无需进行概念解释或复杂分析。这属于最基本的选择题难度等级。" + }, + { + "idx": 1617, + "question": "The equilibrium concentration of point defects increases with the rise of __ (4).", + "answer": "(4) temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（temperature）来补全句子，属于需要简短文字回答的类型，没有提供选项或要求判断对错，也不需要计算。 | 知识层次: 题目考查点缺陷平衡浓度与温度关系的基本概念记忆，属于材料科学基础理论中的基本原理记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆题，仅需考生记住\"温度升高会增加点缺陷平衡浓度\"这一基本原理即可作答。题目直接考查定义性知识，不需要解释或分析过程，解题步骤极为简单，属于选择题中最基础的难度等级。" + }, + { + "idx": 1618, + "question": "When titanium oxide is oxygen-deficient, the following reaction can occur: $\\\\mathrm{TiO}_{2}-\\\\frac{1}{2}0_{2}{\\\\rightarrow}\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}+\\\\mathrm{V}_{0}^{\\\\ast}$. Please correctly write the defect equation and explain the meaning of each term.", + "answer": "The defect equation is $2\\\\mathrm{TiO}_{2}-\\\\frac{1}{2}0_{{2}}{\\\\rightarrow}2\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}+\\\\mathrm{V}_{0}^{\\\\ast}+30_{0}$. $\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}$: Titanium dioxide loses oxygen, generating $\\\\mathbb{T}^{3+}$ occupying the $\\\\mathbf{Ti}^{4+}$ lattice site, with an effective charge of -1. $\\\\mathbf{V}_{0}^{*}$: Oxygen vacancy, with an effective charge of $^{+2}$. $0_{\\\\mathfrak{o}}$: Oxygen still occupies the oxygen lattice site.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求正确写出缺陷方程并解释每个术语的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求正确书写缺陷方程并解释各项含义，涉及多步计算（平衡方程）和概念关联（缺陷化学符号的理解）。虽然包含基础概念，但需要综合分析能力来正确表达和解释缺陷反应。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求正确书写缺陷方程并解释每个术语的含义，这需要考生对缺陷化学有较深的理解。其次，题目涉及多步计算和概念关联，如有效电荷的计算和缺陷类型的识别。此外，题目还要求综合分析不同缺陷之间的关系，这在选择题型中属于较为复杂的任务。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 1621, + "question": "The process in which a single solid phase simultaneously precipitates two new solid phases with different compositions and crystal structures is called (8)__ transformation", + "answer": "(8) eutectoid", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（eutectoid transformation）来完成句子，属于需要准确回忆和填写特定知识点的简答题类型。 | 知识层次: 题目考查对\"eutectoid transformation\"这一基本概念的记忆和理解，属于材料科学中相变的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"eutectoid transformation\"的定义。题目直接给出了定义描述，只需选择正确的术语填空，无需解释或分析。这属于最基本的概念记忆题，在选择题型中属于最低难度等级。" + }, + { + "idx": 1622, + "question": "If different atomic planes in a crystal are represented by letters such as A, B, C, D, etc., the stacking sequence of atoms in a face-centered cubic crystal is _(1)_, and the stacking sequence of atoms in a hexagonal close-packed crystal is _(2)_.", + "answer": "(1) ABCABCABC...; (2) ABABAB.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的堆叠序列，需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对晶体结构中面心立方和六方密堆积原子堆垛序列的基础概念记忆，属于基本原理的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆两种晶体结构（面心立方和六方密堆积）的原子堆垛序列。题目直接给出了正确选项，无需进行复杂的分析或推理。属于基础概念记忆的简单题目，符合等级1的基本定义简答难度。" + }, + { + "idx": 1624, + "question": "The formation of nuclei in a homogeneous liquid phase through conditions such as structural fluctuations and energy fluctuations is called (10) nucleation", + "answer": "(10) homogeneous", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（homogeneous nucleation）来完成句子，属于需要简短文字回答的题目类型，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查基本概念的记忆和理解，即均相成核的定义和分类，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察对\"homogeneous nucleation\"这一基础概念的记忆，无需解释或复杂推理。正确选项是术语本身，只需识别并匹配定义即可完成选择，属于最基础的知识点掌握要求。" + }, + { + "idx": 1625, + "question": "What is the driving force for nucleation in solid-state phase transformations?", + "answer": "The difference in free energy between the new phase and the parent phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释固态相变中成核的驱动力，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对固态相变中成核驱动力的基本概念的理解和记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即驱动力的定义。不需要复杂的分析或比较，只需识别正确选项即可。属于最基本的知识点掌握要求。" + }, + { + "idx": 1626, + "question": "The imperfect dislocation caused by inserting or removing a close-packed plane is called _ (7) _ imperfect dislocation", + "answer": "(7) Frank", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Frank imperfect dislocation），属于需要准确回忆并填写特定知识点的简答题类型。虽然形式上类似填空题，但本质上属于简答题范畴，因为不需要选择或判断，而是直接回忆并写出答案。 | 知识层次: 题目考查对Frank不完全位错这一基本概念的记忆和理解，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，此题仅考察对Frank不全位错这一基础定义的单点记忆，无需解释或分析。属于最基本的概念记忆题，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1627, + "question": "Given that the yield strength of industrial pure copper is $\\\\sigma{\\\\mathrm{s}}=70\\\\mathrm{MPa}$, with a grain size of $N{\\\\mathbf{A}}=18$ per $\\\\nearrow\\\\mathbf{mm}^{2}$; when $N{\\\\mathbf{A}}=4025$ per $/\\\\mathbf{m}\\\\mathbf{m}^{2}$, $\\\\pmb{\\\\sigma{\\\\mathrm{s}}=95\\\\mathrm{MPa}}$; calculate the yield strength ${\\\\pmb{\\\\sigma}}{\\\\mathfrak{s}}$ when $N{\\\\mathrm{A}}=260$ per $\\\\scriptstyle\\\\left/\\\\mathbf{mm}^{2}\\\\right.$.", + "answer": "The relationship between grain size and yield strength satisfies the Hall-Petch formula, i.e., $$ \\\\sigma_{\\\\mathrm{s}}=\\\\sigma_{0}+K d^{-1/2} $$ Representing grain size by the diameter of an equal-area circle, thus $$ \\\\begin{array}{c}{{d=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{N_{\\\\mathrm{a}}}\\\\right)^{1/2}}}\\\\\\\\ {{d_{1}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{18}\\\\right)^{1/2}=0.22\\\\mathrm{mm}}}\\\\\\\\ {{d_{2}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{4025}\\\\right)^{1/2}=1.45\\\\times10^{-2}\\\\mathrm{mm}}}\\\\\\\\ {{d_{3}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{260}\\\\right)^{1/2}=5.71\\\\times10^{-2}\\\\mathrm{mm}}}\\\\\\\\ {{\\\\sigma_{\\\\mathrm{s}1}=\\\\sigma_{0}+K d_{1}^{\\\\mathrm{\\\\Gamma}-1/2},\\\\sigma_{\\\\mathrm{s}2}=\\\\sigma_{0}+K d_{2}^{\\\\mathrm{\\\\Gamma}-1/2}}}\\\\end{array} $$ Substituting ${\\\\pmb\\\\sigma}_{\\\\mathrm{s}1}=70\\\\mathrm{MPa},{\\\\pmb\\\\sigma}_{\\\\mathrm{s}2}=95\\\\mathrm{MPa}$ to solve for $K=0.13\\\\mathrm{MPa\\\\cdot m^{1/2}},\\\\sigma_{0}=61.3\\\\mathrm{MPa}$, hence $\\\\sigma_{\\\\mathrm{s}}=78.3\\\\mathrm{MPa}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解屈服强度，解答过程中涉及到了Hall-Petch公式的应用和具体的数值计算步骤。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值代入和求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和计算技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和变量求解。虽然题目提供了部分中间步骤，但仍需要考生具备综合分析能力和对材料科学基础概念的掌握。" + }, + { + "idx": 1628, + "question": "Negative temperature gradient", + "answer": "In the liquid phase at the crystallization front, the distribution where the temperature gradually decreases from the solid-liquid interface toward the interior of the liquid phase is called a negative temperature gradient", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Negative temperature gradient”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对负温度梯度这一基本概念的定义和记忆，属于基础概念的理解层面，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述\"负温度梯度\"的具体定义和分布情况，而不仅仅是简单的定义复述。这要求考生对概念有一定的理解和应用能力，但不需要复杂的分析或比较。" + }, + { + "idx": 1629, + "question": "A dislocation whose Burgers vector equals a lattice vector is called __ (5)_", + "answer": "(5) perfect dislocation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（perfect dislocation）来补全句子，属于需要简短文字回答的题目类型 | 知识层次: 题目考查的是位错的基本概念和分类，特别是完美位错的定义，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接考察对\"perfect dislocation\"这一基础概念的定义记忆，只需识别Burgers vector等于晶格矢量这一关键特征即可作答，无需概念解释或复杂推理。选择题型中此类直接考查术语定义的题目属于最基础难度层级。" + }, + { + "idx": 1630, + "question": "In the equilibrium phase diagram of an alloy, to determine the proportions of the various phases present in the alloy at a certain temperature and composition, the __(9)__ rule can be applied using an isothermal tie line for calculation.", + "answer": "(9) lever", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写一个特定的术语（lever rule）来完成句子，属于需要简短文字回答的题目类型。虽然答案只有一个词，但题目没有提供选项，需要通过知识回忆来回答，符合简答题的特征。 | 知识层次: 题目考查杠杆定律（lever rule）在相图中的应用，属于基本公式的直接套用，不需要复杂的计算或多概念关联。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用杠杆规则这一基本公式进行计算。题目明确给出了应用场景（平衡相图）和具体方法（使用等温连接线），学生只需识别并选择正确的术语（lever）即可，无需复杂的分析或推导过程。" + }, + { + "idx": 1631, + "question": "What are the main resistances to nucleation in solid-state phase transformations?", + "answer": "Interfacial energy and elastic strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举固态相变中成核的主要阻力，答案以文字形式给出，需要简要说明和论述 | 知识层次: 题目考查固态相变中成核的主要阻力，即界面能和弹性应变能，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生同时掌握\"界面能\"和\"弹性应变能\"这两个关键概念，并理解它们对固态相变中形核阻力的影响。这比单纯记忆单一概念的定义（等级1）要求更高，但又不涉及复杂的概念体系分析（等级3）。" + }, + { + "idx": 1632, + "question": "In face-centered cubic crystals, the partial dislocation caused by (6)__ is called the Shockley partial dislocation", + "answer": "(6) non-uniform slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（non-uniform slip）来完整句子，这属于需要提供简短文字答案的简答题类型，而不是从多个选项中选择或进行判断。 | 知识层次: 题目考查的是面心立方晶体中部分位错的基本概念和分类，需要记忆和理解Shockley部分位错的定义及其形成原因，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即Shockley partial dislocation的定义和成因。正确选项\"non-uniform slip\"是直接对应教材中的定义性知识，无需复杂推理或概念关联。属于最基础的定义简答层级，符合等级1标准。" + }, + { + "idx": 1633, + "question": "The dislocation that can produce cross-slip must be a _ (20) dislocation", + "answer": "screw-type", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（screw-type）作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。这种形式符合简答题的特征。 | 知识层次: 题目考查位错类型的基本概念记忆，特别是关于螺型位错（screw-type dislocation）能够产生交叉滑移的特性。这属于对材料科学基础知识的直接回忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆位错类型的基本定义和特性（如螺型位错可以发生交滑移）。题目不涉及复杂概念体系或分析过程，属于最基础的定义简答级别。" + }, + { + "idx": 1634, + "question": "The adsorption occurring on the surface of solids can be divided into two types: (15) and (16).", + "answer": "(15) Physical adsorption; (16) Chemical adsorption", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空缺处的答案，需要根据知识进行文字回答，而不是选择、判断或计算 | 知识层次: 题目考查对固体表面吸附类型的基本分类记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆固体表面吸附的两种基本类型（物理吸附和化学吸附），属于基础概念记忆，无需解释或复杂分析。题目直接给出正确选项，考察的是对基础定义的简单回忆，因此属于等级1难度。" + }, + { + "idx": 1635, + "question": "According to the different atomic arrangement structures at the interface, the phase interfaces in solids can be divided into _(17), (18), and (19) interfaces.", + "answer": "(17) coherent; (18) incoherent; (19) semi-coherent", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写空缺部分，需要根据知识进行文字回答，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对固体中相界面分类的基本概念记忆，属于定义和分类的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求考生记忆并区分固体中相界面的三种基本类型（共格、非共格和半共格界面），这属于基础概念的记忆性知识，无需复杂的理解或分析过程。选择题型中仅需识别正确选项，无需进一步解释或推导，因此难度较低。" + }, + { + "idx": 1636, + "question": "If 6kg of austenite with a carbon content of w_c=0.45% is slowly cooled below 727%, what is the proeutectoid phase?", + "answer": "If 6kg of austenite with a carbon content of w_c=0.45% is slowly cooled below 727%, the proeutectoid phase is proeutectoid ferrite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释在特定条件下（缓慢冷却至727℃以下）的相变产物，答案需要文字描述（proeutectoid ferrite），属于概念性简答而非计算/选择/判断。 | 知识层次: 题目考查对铁碳相图中奥氏体冷却过程中析出相的基础概念记忆，仅需知道0.45%碳含量低于共析点(0.77%)时会析出先共析铁素体这一基本原理，无需复杂分析或计算。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即碳含量为0.45%的奥氏体在缓慢冷却至727℃以下时形成的先共析相是什么。不需要复杂的分析或推理，只需记住基本的铁碳相图知识即可作答。" + }, + { + "idx": 1637, + "question": "Plastic deformation of metal polycrystals requires at least (14) independent slip systems to be activated", + "answer": "(14) five", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的数值（14）并补充说明（five），这需要简要的文字解释和论述，而不是从多个选项中选择或简单的对错判断。 | 知识层次: 题目考查对金属多晶体塑性变形所需独立滑移系统数量的基本概念记忆，属于定义性知识的直接回忆。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆金属多晶体塑性变形所需的独立滑移系统数量。题目直接给出正确选项(14)，无需复杂推理或概念比较，属于最基本的知识点考察。" + }, + { + "idx": 1638, + "question": "What changes occur in the microstructure of plastically deformed metals?", + "answer": "The strengthening factors of martensite include the interstitial solid solution strengthening effect of carbon atoms; the pinning effect of C atom clusters on dislocations; C atoms entering the flattened octahedral centers of the martensite crystal structure, causing asymmetric lattice expansion (forming a distorted dipole stress field), resulting in strong interstitial solid solution strengthening; and the strengthening effects of grain boundaries, dislocations, and twins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释塑性变形金属微观结构的变化，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求解释塑性变形金属微观结构的变化，涉及多种强化机制的综合分析，包括固溶强化、位错钉扎效应、晶格畸变应力场等复杂概念，需要深入理解材料变形机理并进行多因素关联分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对金属塑性变形后的微观结构变化有深入理解，并能够综合运用多个复杂概念（如间隙固溶强化、位错钉扎效应、晶格畸变等）进行机理分析。正确选项涉及马氏体强化因素的全面解释，需要考生具备将多个强化机制整合分析的能力，这远超单纯记忆或简单理解的层次，符合选择题型内\"复杂现象全面分析\"的最高标准。" + }, + { + "idx": 1639, + "question": "What is the total amount of ferrite and cementite in kilograms in the final room-temperature equilibrium microstructure?", + "answer": "According to the lever rule, the amounts of ferrite and cementite in the final room-temperature equilibrium microstructure are m_α=(6.70-0.45)/(6.70-0.022)×100%×6kg=5.64kg, m_Fe3C=(0.45-0.022)/(6.70-0.022)×100%×6kg=0.36kg, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算铁素体和渗碳体的总量，答案中给出了具体的计算过程和数值结果，涉及杠杆法则的应用和数值运算。 | 知识层次: 题目需要应用杠杆规则进行多步计算，涉及铁素体和渗碳体的质量分数计算，需要理解相图和相关概念，并进行数值计算和公式应用。虽然计算过程较为直接，但需要综合运用相图知识和杠杆规则，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要掌握杠杆定律的应用，并进行多步计算。题目涉及铁碳相图的基本概念，要求考生能够正确识别相组成并应用公式计算各相的质量分数。虽然计算过程较为直接，但需要综合运用多个知识点，包括相图解读和杠杆定律的应用，因此属于等级3的综合性计算问题。" + }, + { + "idx": 1640, + "question": "What changes occur in the properties of plastically deformed metals?", + "answer": "The strength and toughness of martensite are closely related to its carbon content, microstructure morphology, and substructure. In iron-carbon alloys, when the carbon content wc<0.3%, lath martensite forms with a dislocation substructure, exhibiting lower strength but good plasticity and toughness; when wc>1.0%, plate martensite forms with a twin substructure, showing high strength but poor plasticity and toughness; for 0.3%2)$ in the crystal structure, crystals are divided into lower (no higher-order axis), intermediate (one higher-order axis), and higher (more than one higher-order axis) crystal families.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对晶体家族进行分类并解释分类依据，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查晶体家族的基本分类标准，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体分类的基础概念记忆，但需要理解\"higher-order axes\"的定义以及如何根据其数量进行分类。这比单纯记忆基本定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。题目要求考生能够解释和描述晶体分类的标准，属于概念解释和描述的难度层次。" + }, + { + "idx": 1654, + "question": "Phase equilibrium", + "answer": "The chemical potentials of each phase in the system are equal, and the chemical potentials of each component in each phase are equal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Phase equilibrium\"进行解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目考查相平衡的基本概念，即化学势在相平衡中的条件，属于基本原理的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然涉及相平衡的基本概念，但正确选项需要理解化学势在相平衡中的具体表现（各相及各组分化学势相等），这超出了简单定义记忆的范畴。不过题目没有涉及复杂的概念体系或需要多步推理，因此属于概念解释和描述级别。" + }, + { + "idx": 1655, + "question": "Electronic compound", + "answer": "Belongs to intermetallic compounds, where the electron concentration, defined as the ratio of the total number of valence electrons to the total number of atoms, is approximately 1.4 when the alloy reaches its maximum solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Electronic compound\"进行解释和论述，答案提供了详细的文字说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对电子化合物（Electronic compound）的基本定义和特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并记忆电子化合物的定义、分类以及电子浓度的具体数值（1.4）。这比单纯记忆一个简单的定义（等级1）要复杂一些，但不需要进行复杂的分析或比较（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1658, + "question": "Steady-state diffusion", + "answer": "A diffusion process in which the concentration at any point in the diffusion system does not change with time", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Steady-state diffusion\"进行文字解释和论述，答案是一个定义性的描述，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查的是稳态扩散的基本定义，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"Steady-state diffusion\"这一基础概念的定义记忆，不需要进行概念间的比较或复杂推理。正确选项直接给出了该术语的标准定义，属于最基础的定义简答类型，符合难度等级1的特征。" + }, + { + "idx": 1659, + "question": "Dynamic recrystallization", + "answer": "The phenomenon where deformation and recrystallization occur simultaneously above the recrystallization temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Dynamic recrystallization\"这一概念进行文字解释和论述，答案形式为定义性的文字描述，符合简答题的特征。 | 知识层次: 题目考查对动态再结晶这一基本现象的定义和记忆，属于基础概念的理解和表述，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别动态再结晶的基本定义，属于最基础的概念记忆层次。题目直接给出了定义性描述，无需进行概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1662, + "question": "A slip plane and a (7) on it form a slip system", + "answer": "(7) slip direction", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（slip direction）来补全句子，这属于需要提供特定关键词的简答题形式，而不是从多个选项中选择或判断对错 | 知识层次: 题目考查对滑移系统基本组成要素的记忆，即滑移面和滑移方向的组合，属于材料科学中晶体塑性变形的基础概念。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目仅考察对\"slip system\"基本组成的记忆（slip plane和slip direction），不需要任何解释或分析步骤。正确选项直接对应基础术语填空，属于最基础的概念记忆层次。" + }, + { + "idx": 1663, + "question": "In a solid solution, when solute atoms and solvent atoms occupy fixed positions respectively, and the ratio of solute atoms to solvent atoms in each unit cell is constant, this ordered structure is called _ (6)—", + "answer": "(6) superlattice", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（superlattice）来补全句子，属于需要简短文字回答的题目类型。 | 知识层次: 题目考查对有序结构（超晶格）这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即\"超晶格\"（superlattice）的定义。题目直接描述了有序结构的特征，并提供了明确的正确选项，无需复杂分析或推理。属于最基础的定义简答类型。" + }, + { + "idx": 1664, + "question": "The three crystal zones of an ingot refer to the fine crystal zone near the inner wall of the mold, _ (10) __, and the equiaxed coarse crystal zone at the center of the ingot", + "answer": "(10) columnar crystal zone growing perpendicular to the mold wall", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（columnar crystal zone growing perpendicular to the mold wall）来补全句子，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对铸锭三个晶区的基本概念的记忆和理解，特别是柱状晶区的定义和位置 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目要求考生记忆并识别铸锭的三个晶区名称，正确选项直接给出了其中一个晶区的定义描述，无需进行复杂的概念分析或比较。考生只需掌握基础概念记忆即可正确作答，符合等级1的难度标准。" + }, + { + "idx": 1665, + "question": "Given carburization for 10 hours at 927°C, calculate the time t2 required to achieve the same carburization thickness at 870°C. Known values: D1=15.99×10^-12 m²/s, D2=7.94×10^-12 m²/s.", + "answer": "According to D1/D2 = t2/t1, t2 = (D1/D2) t1 = (15.99×10^-12 / 7.94×10^-12) × 10 h = 2.014 × 10 h = 20.14 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及使用已知的扩散系数和时间来计算新的时间，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即利用扩散系数与时间的关系公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解扩散系数与时间的关系公式（D1/D2 = t2/t1），但解题步骤直接且明确，仅需套用给定公式并进行简单数值计算即可得出答案。不需要多个公式组合或复杂分析，因此在选择题型内属于较低难度。" + }, + { + "idx": 1666, + "question": "Crystals can be classified into seven crystal systems based on the order and number of rotation axes and rotoinversion axes: cubic crystal system, trigonal crystal system, tetragonal crystal system, —(1), —(2)—, —(3), and _(4).", + "answer": "(1) Hexagonal crystal system; (2) Orthorhombic crystal system; (3) Monoclinic crystal system; (4) Triclinic crystal system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写缺失的晶体系统名称，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对晶体系统分类的基本概念记忆，只需回忆并填写七种晶体系统的名称，不涉及应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求填写晶体系统的分类，只需要记忆七个晶体系统的名称即可完成。不需要进行概念解释或复杂的概念体系阐述，解题步骤简单，仅需回忆基础知识。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1667, + "question": "The manner in which the crystal interface advances into the liquid phase during crystallization is called __（8）—, which is related to the microscopic structure of the liquid-solid interface", + "answer": "（8）crystal growth mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语（crystal growth mechanism）来完整描述结晶过程中晶体界面向液相推进的方式，属于需要简短文字回答的题目类型。 | 知识层次: 题目考查晶体生长机制这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接询问晶体生长过程中的特定术语（crystal growth mechanism），属于基础概念记忆的范畴，仅需考生回忆并识别正确的定义性术语即可，无需进行复杂的解释或分析。" + }, + { + "idx": 1670, + "question": "At phase equilibrium, the number of phases in the system can be calculated using the relationship between the degrees of freedom of the system, －（9）__, and the number of external factors that can influence the equilibrium state of the system", + "answer": "（9）number of components", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（number of components）来补全句子，而不是从多个选项中选择或进行判断、计算。这符合简答题的特征，即需要提供具体的文字答案。 | 知识层次: 题目考查对相平衡中自由度、组分数和相数之间关系的基本概念记忆，属于Gibbs相律的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察对相平衡中组分数（number of components）这一基础概念的记忆，无需复杂推理或概念间的关联分析。正确选项明确对应教材中的定义性内容，属于最基础的知识点考察。" + }, + { + "idx": 1671, + "question": "The _ (5) of an atom or ion refers to the number of atoms directly adjacent to it in the crystal structure or the number of all hetero-ions combined with it.", + "answer": "(5) Coordination number", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（coordination number）来完成句子，而不是从多个选项中选择、判断对错或进行数值计算。这符合简答题的特征，即需要提供具体的文字答案。 | 知识层次: 题目考查的是\"配位数\"这一基本概念的定义，属于晶体结构中最基础的概念记忆和理解范畴，不需要进行计算或综合分析。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆并识别\"配位数\"的定义即可。题目直接给出了概念的关键描述，正确选项与题干描述高度匹配，无需复杂推理或跨概念分析。属于选择题中最简单的难度等级，主要测试学生对基础术语的记忆能力。" + }, + { + "idx": 1672, + "question": "Linear polymers can be reused and are called (19)__ plastics", + "answer": "(19) thermoplastic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（thermoplastic）来完成句子，属于需要提供简短文字答案的题型 | 知识层次: 题目考查对线性聚合物分类的基本概念记忆，仅需回答\"thermoplastic\"这一术语，属于基础概念的记忆性知识。 | 难度: 在选择题型中属于基础难度，仅需要记忆线性聚合物的基本分类术语\"thermoplastic\"这一单一知识点，无需解释或分析其他概念。题目直接考查基础定义记忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1673, + "question": "Cross-linked polymers cannot be reused and are called (20)__ plastics", + "answer": "(20) thermosetting", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（thermosetting）来完成句子，这属于需要简短文字回答的类型，而不是从多个选项中选择或进行判断/计算 | 知识层次: 题目考查对交联聚合物分类的基础概念记忆，特别是热固性塑料的定义和特性，属于基础概念记忆性知识。 | 难度: 在选择题型中属于基础难度，仅需要记忆和识别\"thermosetting plastics\"这一基本定义即可作答，不涉及概念解释或复杂分析。题目直接考查学生对塑料分类的基础概念记忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1674, + "question": "After recrystallization is completed, grain growth can be divided into (17) _ grain growth and _ (18) grain growth.", + "answer": "(17) normal; (18) abnormal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空白处的答案，需要根据知识进行简短的文字回答，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查的是再结晶完成后晶粒生长的两种基本类型（正常晶粒生长和异常晶粒生长）的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即晶粒生长的两种类型（正常和异常）。题目直接给出定义性知识，无需解释或复杂分析，属于最基本的知识点掌握要求。" + }, + { + "idx": 1675, + "question": "Given the ionic radius of O2- is 0.14nm and that of Fe3+ is 0.069nm, calculate their radius ratio and predict what type of crystal structure can be formed.", + "answer": "Fe2O3, R+/R-=0.069/0.140=0.492, which also falls within the range of 0.414～0.732, has 6-coordination, A2X3 structure, trigonal crystal system.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算半径比）并应用晶体结构预测的知识（根据半径比范围判断配位数和晶体结构类型），答案给出了具体的计算过程和结构预测结果。 | 知识层次: 题目需要进行多步计算（半径比计算、配位数判断），并关联晶体结构类型的综合分析，涉及离子半径比与晶体结构的关系这一中等复杂度的知识点。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求计算离子半径比，并根据计算结果预测晶体结构类型。这涉及到多步骤的计算过程（半径比计算）和概念关联（半径比与配位数、晶体结构的关系）。虽然题目提供了具体数值，但仍需要综合分析才能得出正确结论。" + }, + { + "idx": 1676, + "question": "Compare the number of valence electrons in CaO and MgO, and determine whether CaO-MgO meets the electron concentration condition for forming a solid solution.", + "answer": "CaO and MgO have the same number of valence electrons, meeting the electron concentration condition for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较CaO和MgO的价电子数，并判断是否满足形成固溶体的电子浓度条件，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要比较CaO和MgO的价电子数，并判断是否符合形成固溶体的电子浓度条件。这涉及基本概念的应用（价电子数和固溶体形成条件），但不需要复杂的计算或深入的分析，属于直接套用基本原理的简单应用。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需要基本公式应用和简单计算。题目直接比较CaO和MgO的价电子数，并套用固溶体形成的电子浓度条件，解题步骤简单明了，无需复杂分析或深入理解多个概念。" + }, + { + "idx": 1677, + "question": "The methods for strengthening metal materials include (13) _ strengthening, (14) strengthening, (15) strengthening, _ (16) strengthening", + "answer": "(13) solid solution; (14) dislocation; (15) fine grain; (16) dispersion (or precipitate particles)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的强化方法名称，需要根据知识进行文字回答，而不是选择、判断或计算 | 知识层次: 题目主要考查对金属材料强化方法的基本概念的记忆和理解，包括固溶强化、位错强化、细晶强化和弥散强化等基础知识点，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确回忆并区分四种不同的金属强化方法（固溶强化、位错强化、细晶强化、弥散强化或沉淀强化）。这要求考生不仅记住定义，还要能正确分类和匹配每种强化方法的名称。相比等级1的简单定义回忆，该题目需要更深入的概念理解和分类能力，但尚未达到等级3的复杂概念体系阐述水平。" + }, + { + "idx": 1678, + "question": "Analyze the crystal structures of CaO and MgO, and determine whether CaO-MgO meets the crystal structural conditions for forming a solid solution.", + "answer": "Both CaO and MgO have FCC NaCl-type crystal structures, which meet the crystal structural conditions for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析CaO和MgO的晶体结构，并判断它们是否满足形成固溶体的晶体结构条件。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析两种氧化物的晶体结构并判断它们是否满足形成固溶体的晶体结构条件，这涉及对晶体结构类型的理解和应用，以及综合分析能力。虽然知识点相对明确，但需要将多个概念关联起来进行判断，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求分析CaO和MgO的晶体结构，并判断它们是否满足形成固溶体的晶体结构条件。这需要掌握FCC NaCl型晶体结构的知识，并能将这一概念应用到具体材料中。虽然不需要进行复杂的计算，但需要对晶体结构有深入的理解，并能进行综合分析。因此，在选择题型中属于等级3的难度。" + }, + { + "idx": 1679, + "question": "What is the difference between slip and twinning in terms of deformation continuity?", + "answer": "The slip process can proceed continuously while the twinning process cannot proceed continuously.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述滑移和孪生在变形连续性方面的区别，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对滑移和孪生这两种变形机制的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分两种变形机制（滑移和孪生）的连续性特征，而不仅仅是简单记忆定义。正确选项要求考生能够比较两种机制的变形过程特点，这比单纯记忆定义（等级1）要复杂一些，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1680, + "question": "Compare the electronegativity of Ca and Mg, and determine whether CaO-MgO meets the electronegativity condition for forming a solid solution. (The electronegativity of Ca is 1.0, and that of Mg is 1.2)", + "answer": "The electronegativity of Ca is 1.0, and that of Mg is 1.2. Their electronegativity values are close and within the same period, meeting the electronegativity condition for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较Ca和Mg的电负性，并判断CaO-MgO是否符合形成固溶体的电负性条件。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种元素的电负性并判断是否符合形成固溶体的条件，涉及基本概念的应用和简单判断，不需要复杂的分析或多步计算。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对电负性基本概念的理解和简单比较。题目提供了明确的电负性数值，只需进行直接比较和判断是否符合固溶体形成的电负性条件，无需复杂计算或多步骤推理。属于选择题中较为基础的难度水平。" + }, + { + "idx": 1681, + "question": "Based on the above conditions, determine what type of solid solution CaO-MgO can form.", + "answer": "Due to the excessive size difference (28%), CaO-MgO cannot form a continuous solid solution but instead forms a limited-type solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于给定条件解释CaO-MgO能形成何种固溶体类型，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目需要理解固溶体的形成条件，特别是尺寸差异对固溶体类型的影响，并进行综合分析判断。这涉及多个概念的关联和中等程度的推理分析。 | 难度: 在选择题中属于中等难度，需要理解固溶体的形成条件（如尺寸差异限制），并能将28%的尺寸差异与固溶体类型（连续型或有限型）进行关联分析。虽然不涉及多步计算，但需要综合应用材料科学基础概念进行判断。" + }, + { + "idx": 1682, + "question": "Based on the radius difference between Ca2+ and Mg2+ ions, calculate and determine whether CaO-MgO meets the size condition for forming a continuous solid solution. (The radii of Ca2+ and Mg2+ ions are known to be 0.1nm and 0.072nm, respectively)", + "answer": "Size difference calculation: (0.1 - 0.072) / 0.1 = 28%. The size difference exceeds 15%, thus it does not meet the size condition for forming a continuous solid solution.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行具体的数值计算（半径差百分比计算），并根据计算结果得出结论（是否满足形成连续固溶体的尺寸条件）。答案展示了完整的计算过程和基于计算结果的判断，符合计算题的特征。 | 知识层次: 题目要求进行简单的数值计算和公式应用，即通过给定的离子半径计算尺寸差异百分比，并根据已知条件判断是否符合形成连续固溶体的尺寸条件。这一过程涉及基本的公式应用和直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用半径差公式进行计算，但步骤较为直接，仅涉及单一公式和简单百分比计算，无需多个概念或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 1683, + "question": "What is the difference between slip and twinning in terms of deformation modes?", + "answer": "The slip process involves the relative sliding of one part of the crystal relative to another, while the twinning process involves the uniform shear of one part of the crystal relative to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种变形模式的区别，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对滑移和孪生这两种变形模式的基本定义和区别的理解，属于基础概念的记忆和简单对比。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个基本概念（slip和twinning）的比较，但正确选项已经清晰地给出了两者的定义和区别，不需要复杂的推理或分析。学生只需理解并记忆这两个概念的基本特征即可作答。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 1684, + "question": "What is the difference in critical shear stress between slip and twinning?", + "answer": "The critical shear stress required for twinning is much greater than that for slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种现象之间的差异，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对滑移和孪生临界剪切应力的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（临界剪切应力的定义），但需要考生区分两种不同变形机制（滑移和孪生）的临界条件差异。这比单纯记忆单一概念（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。正确选项直接比较了两种机制的临界剪切应力大小关系，属于概念解释和描述层面的认知要求。" + }, + { + "idx": 1685, + "question": "How does the influence of slip and twinning on crystal orientation relationships differ?", + "answer": "The twinning process alters the crystal orientation relationship. The slip process does not change the crystal orientation relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述滑移和孪生对晶体取向关系的不同影响，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目要求比较滑移和孪生对晶体取向关系的影响，涉及对两种变形机制的理解和对比分析，需要将概念关联并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶体取向关系的基本概念，并能够区分滑移和孪生两种变形机制对晶体取向的不同影响。题目要求考生综合分析两种机制的差异，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1687, + "question": "What are the differences in the roles of slip and twinning in the mechanisms of plastic deformation?", + "answer": "Slip is the primary mechanism of plastic deformation. When the slip system is unfavorable for slip deformation to occur, twinning can alter the orientation of the slip system relative to the external force, enabling further slip processes to take place.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述滑移和孪生在塑性变形机制中的不同作用，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释滑移和孪生在塑性变形机制中的不同作用，需要综合运用材料科学中的变形机制知识，进行推理分析和机理解释。这涉及到对两种变形机制的深入理解及其在特定条件下的相互作用，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 1689, + "question": "How does the type of bonding affect the physical properties of materials?", + "answer": "The type of bonding has a significant impact on the physical properties of materials. Metallic bonds impart metallic luster, high electrical and thermal conductivity, and a positive temperature coefficient of resistance; ceramics and polymers bonded by non-metallic bonds generally do not conduct electricity in the solid state. The stronger the bond, the higher the melting point of the material, the smaller the coefficient of thermal expansion, and the greater the density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述不同类型的键合如何影响材料的物理性质，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查材料中不同类型键合对物理性质影响的基本概念记忆和理解，属于基础知识的直接应用和解释。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（如金属键、非金属键、物理性质等），但正确选项已经将这些概念进行了明确的解释和描述，不需要考生自行推导或比较分析。考生只需理解并记忆这些基本原理即可作答，因此属于概念解释和描述的难度等级。" + }, + { + "idx": 1690, + "question": "How does the type of bonding affect the mechanical properties of materials?", + "answer": "The type of bonding significantly affects the mechanical properties of materials. Crystals bonded by covalent, ionic, and metallic bonds are generally harder than those bonded by molecular forces. The greater the bond energy, the higher the elastic modulus. Materials with metallic bonds usually exhibit good plasticity, while those with ionic and covalent bonds (such as ceramics) are difficult to undergo plastic deformation and have poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述不同类型的键合如何影响材料的机械性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释不同类型化学键对材料力学性能的影响，涉及多个概念（共价键、离子键、金属键、分子间力）的关联和综合分析，需要理解键能与弹性模量的关系以及不同键合类型对塑性变形能力的影响。虽然不涉及复杂计算，但需要对材料科学基本原理进行中等程度的综合应用和分析。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解不同类型化学键的基本概念，还需要综合分析它们对材料机械性能的具体影响。正确选项涉及多个知识点（共价键、离子键、金属键和分子间作用力）的比较，以及这些键能如何影响弹性模量和塑性变形能力。这需要考生能够进行多角度分析，将抽象的理论知识与具体的材料性能联系起来，属于中等应用层次中较复杂的综合分析题。" + }, + { + "idx": 1691, + "question": "How does the magnitude of bond energy affect the properties of materials?", + "answer": "The magnitude of bond energy directly influences material properties. The higher the bond energy, the greater the material's strength typically is. Additionally, high bond energy usually leads to a high melting point, low thermal expansion coefficient, and high density. The corrosion of engineering materials is essentially a process of bond formation and destruction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述键能大小如何影响材料性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释键能大小对材料性能的影响，涉及多个性能指标（强度、熔点、热膨胀系数、密度）的综合分析，需要理解键能与这些性能之间的关联，并进行一定的推理分析。虽然不涉及复杂计算，但需要对多个概念进行关联和综合，思维过程有一定深度。 | 难度: 在选择题中属于较高难度，题目要求考生理解并关联多个材料科学概念（如键能、强度、熔点、热膨胀系数、密度和腐蚀机制）。正确选项不仅需要识别键能对单一性质的影响，还需综合分析其对多种材料特性的共同作用机制。此外，题目涉及工程材料腐蚀的微观过程（键的形成与破坏），属于跨知识点整合，对概念掌握深度和逻辑推导能力要求较高。" + }, + { + "idx": 1692, + "question": "Explain your understanding of the relationship between the composition and properties of materials.", + "answer": "The properties of materials are closely related to their chemical composition. The mechanical properties of materials are often highly sensitive to their structure, and any minor changes in the structure can lead to significant variations in performance. For example, the presence of carbon atoms in steel plays a crucial role in its properties, and even trace amounts of alloying elements in many metallic materials can significantly affect their performance. However, different materials composed of the same element, such as graphite and diamond made from carbon, exhibit different properties. Some polymers with identical chemical compositions can have vastly different properties due to their distinct internal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料组成与性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料组成与性能之间的关系，涉及多个概念的综合分析，如化学组成、结构变化对性能的影响，以及不同材料（如石墨和金刚石）的性能差异。这需要理解并应用材料科学的基本原理，进行多方面的关联分析，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解材料组成与性能的基本关系，还需要综合分析不同材料（如钢、石墨与金刚石、聚合物）的具体案例，并解释结构变化对性能的影响。这涉及多角度分析和概念关联，超出了简单记忆或单一概念应用的层次。" + }, + { + "idx": 1693, + "question": "Using the dislocation theory of plastic deformation, explain why the strength of metallic materials increases with finer grain size.", + "answer": "During plastic deformation of metallic polycrystalline materials, coarse grains accumulate a larger number of dislocations at grain boundaries, creating a significant stress field that can activate dislocation sources in adjacent grains, allowing deformation to continue. In contrast, fine grains accumulate fewer dislocations at grain boundaries, requiring a greater external force to activate dislocation sources in adjacent grains for deformation to proceed. Therefore, finer-grained materials require a larger external force to undergo plastic deformation, meaning that the strength of the material increases with finer grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释金属材料强度随晶粒尺寸减小而增加的现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释晶粒尺寸对金属材料强度的影响机制，涉及塑性变形的微观过程、位错在晶界处的积累及其对相邻晶粒变形的影响等复杂概念。需要综合分析晶粒尺寸、位错行为和应力场之间的相互作用，并进行机理层面的解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生基于位错理论对多晶金属材料的塑性变形机制进行深入解释，涉及复杂的材料科学原理和微观结构分析。正确选项不仅需要理解位错在晶界处的积累行为，还需要分析不同晶粒尺寸下应力场的变化及其对位错源激活的影响。这种题目要求考生具备将多个高级概念（位错理论、晶界效应、塑性变形机制）综合运用的能力，并进行复杂的因果推理，完全符合选择题型中\"复杂现象全面分析\"的最高难度标准。" + }, + { + "idx": 1695, + "question": "How do different types of bonding affect the hardness of crystalline materials?", + "answer": "The hardness of crystalline materials is closely related to the type of bonding. Crystals bonded by covalent, ionic, and metallic bonds generally exhibit higher hardness than those bonded by molecular bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释不同键合类型对晶体材料硬度的影响，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求分析不同类型键合对晶体材料硬度的影响，需要理解不同键合类型的基本特性，并将这些特性与硬度这一宏观性能关联起来。这涉及到多概念的综合应用和中等程度的分析，但不需要复杂的机理推导或创新性设计。 | 难度: 在选择题中属于中等难度，需要理解不同化学键类型（共价键、离子键、金属键和分子键）对晶体硬度的影响，并进行概念关联和比较分析。题目要求考生综合运用材料科学基础知识，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1697, + "question": "Given: When the grain size of annealed pure iron is 16 per mm², the yield strength σₛ = 100 MPa. When the grain size is 4096 per mm², σₛ = 250 MPa. Find the value of yield strength σₛ when the grain size is 256 per mm².", + "answer": "According to the Hall-Petch formula, σₛ = σ₀ + Kd⁻¹ᐟ², the yield strength σₛ of the material is calculated from the average grain size d. The grain size is represented by the radius of an equal-area circle, i.e., d₁ = (4A₁/π)¹ᐟ², d₂ = (4A₂/π)¹ᐟ², where A₁ and A₂ are the grain areas. Thus, σₛ₁ = σ₀ + Kd₁⁻¹ᐟ², σₛ₂ = σ₀ + Kd₂⁻¹ᐟ². Given A₁ = 1/16 mm², A₂ = 1/4096 mm², σₛ₁ = 100 MPa, σₛ₂ = 250 MPa, we find K = 25√2 π⁻¹ᐟ⁴ MPa·mm¹ᐟ², σ₀ = 50 MPa. Then, with A₃ = 1/256 mm², we find σₛ₃ = 150 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和公式（Hall-Petch公式）进行计算，最终得出一个具体的数值结果（150 MPa）。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值求解。虽然计算过程较为直接，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和单位转换。虽然题目提供了关键公式和部分参数，但需要考生自行推导K值和σ₀值，并最终计算出新的屈服强度。这要求对材料科学中的晶粒尺寸与力学性能关系有较好的理解，并能进行综合计算分析。" + }, + { + "idx": 1698, + "question": "Explain your understanding of the relationship between the structure and properties of materials.", + "answer": "The internal structure of materials can be divided into different levels, including atomic structure, the arrangement of atoms, as well as microstructure and structural defects. If the same crystalline material has its grain or 'phase' morphology and distribution altered, its properties can be significantly improved. Whether it is metals, ceramics, semiconductors, polymers, or composite materials, their development is closely related to structure. Only by understanding and controlling the structure of materials can we achieve the desired material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料结构与性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料结构与性能之间的关系，涉及多个结构层次（原子结构、原子排列、微观结构、结构缺陷）及其对性能的影响，需要综合运用材料科学知识进行推理分析和机理解释，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对材料结构与性能的关系有深入的理解，并能综合运用多个层次的知识（如原子结构、微观结构、缺陷等）进行复杂分析。正确选项不仅需要识别不同结构层次的影响，还要理解结构变化如何导致性能改善，这涉及机理深度解释和复杂现象的全面分析。在选择题中，这种综合性和深度要求显著高于简单的概念识别或单一知识点回忆。" + }, + { + "idx": 1699, + "question": "Explain your overall understanding of the relationship between a material's composition, microstructure, processing, and properties.", + "answer": "The relationship between a material's composition, microstructure, processing, and properties is very close and mutually influential. The ultimate goal of materials scientists is to design reasonable compositions and formulate optimal production processes based on final requirements, thereby producing materials that meet the specifications. Only by understanding and controlling the structure of materials can the desired material properties be achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对材料组成、微观结构、加工和性能之间的关系进行解释和论述，答案以文字形式展开说明，符合简答题的特征。 | 知识层次: 题目要求解释材料组成、微观结构、加工和性能之间的复杂关系，需要综合运用多个概念并进行推理分析，涉及深层次的理解和关联，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用材料科学的核心概念（成分、微观结构、加工工艺和性能）之间的复杂关系，并进行机理层面的深度解释。正确选项不仅需要理解这些概念之间的相互影响，还需要掌握如何通过设计和控制这些因素来实现特定性能的材料。这种综合分析能力在选择题型中属于最高要求，需要考生具备扎实的理论基础和综合推理能力。" + }, + { + "idx": 1700, + "question": "Choose any material and explain its possible uses and processing methods.", + "answer": "For example, Al-Mg alloy. As a machinable, non-heat-treatable structural material, it is widely used in aircraft, lightweight marine structural materials, load-bearing components in the transportation industry, and welded containers for chemical engineering due to its good weldability, excellent corrosion resistance, and plasticity. Based on the intended use of the material, the alloy composition is designed, and ingredients are prepared considering factors such as burning loss. For instance, Al5Mg alloy sheets can be melted in a resistance crucible furnace at around 750°C under laboratory conditions. After refining, degassing, and slag removal, the alloy is cast in a metal mold at 720°C, homogenized at 430-470°C for 10-20 hours, hot-rolled at 380-450°C, and then cold-rolled to the required thickness. Stabilization treatment is performed in a resistance furnace, followed by shearing to the desired dimensions or machining into standard specimens for various microstructure and performance tests.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求选择一个材料并解释其可能的用途和加工方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求选择一个材料并解释其用途和加工方法，这需要对材料的基本性质、应用领域以及加工工艺有一定的理解和综合分析能力。虽然不涉及复杂的计算或深度机理分析，但需要将多个知识点关联起来，进行多步骤的思考和解释。 | 难度: 在选择题型中，该题目要求考生不仅需要掌握材料的基本性质（如Al-Mg合金的可加工性、耐腐蚀性等），还需要理解其在不同工业领域的具体应用（如航空、化工容器等）。此外，题目还涉及材料从设计到成品的多步加工工艺（如熔炼、铸造、轧制等），要求考生能够综合分析材料性能与加工方法之间的关联性。这种需要多角度分析论述的题目在选择题型中属于较高难度。" + }, + { + "idx": 1701, + "question": "Explain your understanding of the relationship between material processing and properties.", + "answer": "The preparation/synthesis and processing of materials are not only essential means to control their composition and structure but also endow materials with specific dimensions and shapes. For example, steel can undergo heat treatments such as annealing, quenching, and tempering to alter its internal structure and achieve desired properties. Cold-rolled silicon steel sheets, through complex processing steps, can align grains in a specific orientation, significantly reducing iron loss. The blades of aircraft engines can be cast with controlled solidification to form single-crystal blades, eliminating grain boundaries and greatly enhancing their operating temperature and performance. Optical fibers must not only be drawn into micron-level thin strands but also have their refractive index distribution controlled from the inside out. Sometimes it can be said that without a breakthrough in synthesis and processing, there would be no new material. For instance, the development of rapid cooling processing methods led to the creation of amorphous metal alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料加工与性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料加工与性能之间的关系，涉及多个加工方法（如热处理、冷轧、单晶铸造、光纤拉制等）及其对材料微观结构和性能的影响。需要综合运用材料科学知识，进行概念关联和机理解释，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对材料加工与性能之间的关系进行复杂现象全面分析，涉及多个高级概念（如热处理、晶粒取向、单晶铸造、折射率控制等）的综合运用。正确选项不仅需要理解各加工工艺的机理，还要能解释其对材料性能的具体影响（如降低铁损、提高工作温度等），并最终推导出\"合成加工突破决定新材料发展\"的深层结论。这种在选择题中要求多维度知识整合和因果链推导的题目，远超单纯记忆或简单应用层面，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 1702, + "question": "What are traditional materials and advanced materials (new materials)?", + "answer": "There is a wide variety of materials. Those that are mature, mass-produced in industry, and widely used are called traditional materials or basic materials, such as steel, cement, and plastics. On the other hand, those that are under development and possess excellent properties and application prospects are referred to as advanced materials or new materials. Traditional materials can become new materials by adopting new technologies and improving performance, while new materials eventually become traditional materials after long-term production and application.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对传统材料和先进材料进行定义和解释，需要文字论述和解释，属于简答题类型。 | 知识层次: 题目考查对传统材料和先进材料的基本定义和分类的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解和区分传统材料和先进材料（新材料）的定义及其特点，并能够识别两者之间的转化关系。虽然题目涉及两个概念的定义和分类，但内容相对直接，不需要复杂的分析或推理。考生只需记忆并理解这些基础概念即可正确回答。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1703, + "question": "For two types of diffusion with activation energies of E1= 83.7 kJ/mol and E2=251 kJ/mol, how does the diffusion rate change when the temperature increases from 25°C to 600°C?", + "answer": "From D=D0exp(-Q/RT): when the temperature increases from 298K to 873K, the diffusion rate D increases by 4.6×10^9 and 9.5×10^28 times, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过公式计算扩散速率的变化，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散速率公式进行多步计算，涉及不同温度下的比较和指数运算，需要理解公式中各参数的意义并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于高难度题目，需要综合运用扩散速率公式进行多步复杂计算。题目要求计算两种不同激活能情况下温度变化对扩散速率的影响，涉及指数函数的复杂运算（从298K到873K的9.5×10^28倍变化计算），需要准确理解并应用Arrhenius方程，同时处理两个不同激活能系统的对比分析。这种需要处理多变量、进行指数级计算并比较不同系统行为的题目，在选择题型中属于最复杂的类型之一。" + }, + { + "idx": 1704, + "question": "What are the new technologies for aluminum alloy preparation?", + "answer": "The new technologies for aluminum alloy preparation include: hot top casting, air gap casting and electromagnetic casting technology, aluminum alloy electromagnetic casting and rolling technology, large aluminum alloy profile extrusion technology, extra-wide aluminum alloy medium-thick plate rolling technology, semi-solid metal forming technology, and aluminum alloy microstructure prediction and performance control technology.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举和描述铝合金制备的新技术，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求列举和解释铝合金制备的新技术，涉及多个技术点的记忆和理解，并需要将这些技术点进行关联和综合分析。虽然不需要深入的分析或创新应用，但已经超出了单纯的基础概念记忆，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目要求考生掌握铝合金制备的新技术，并能够识别和理解多个相关概念。虽然题目提供了具体的技术名称，但考生需要对这些技术有一定的了解才能正确选择。这涉及到概念关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1705, + "question": "Explain the commonly used diffusion mechanisms.", + "answer": "The commonly used diffusion mechanisms are the vacancy mechanism and the interstitial mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释常见的扩散机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查扩散机制的基本分类和定义，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目仅要求考生记忆并识别常见的扩散机制名称（空位机制和间隙机制），属于最基础的定义简答层次。题目不涉及概念解释或复杂体系阐述，仅需简单回忆即可作答，因此属于等级1难度。" + }, + { + "idx": 1706, + "question": "What effect does activation energy have on the sensitivity of diffusion rate to temperature changes?", + "answer": "The higher the activation energy, the greater the sensitivity of the diffusion rate to temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对激活能对扩散速率敏感性的影响进行文字解释和论述，答案是一个简短的论述性回答，而非选择、判断或计算。 | 知识层次: 题目要求理解活化能对扩散速率温度敏感性的影响，需要将活化能的概念与扩散速率的变化关联起来，并进行综合分析。虽然不涉及复杂计算，但需要一定的概念关联和推理分析能力。 | 难度: 在选择题中属于中等难度，需要理解激活能的概念及其对扩散速率的影响，同时需要综合分析温度变化对扩散速率敏感性的作用。虽然题目涉及多步计算和概念关联，但在选择题型中，通过选项的提示可以降低一定的分析难度。" + }, + { + "idx": 1707, + "question": "What effect does an edge dislocation have on the diffusion process?", + "answer": "An edge dislocation can be regarded as a pipe, which can accelerate the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释边缘位错对扩散过程的影响，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解位错对扩散过程的影响机制，涉及位错作为扩散通道的概念，需要将位错结构与扩散速率关联起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解位错的概念及其对扩散过程的影响，并能将边缘位错类比为管道来理解其对扩散速率的促进作用。这涉及多个概念的关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1708, + "question": "Please analyze with examples the influence of material processing on the service performance of materials.", + "answer": "The material processing process has a significant and complex impact on the service performance of materials. Materials must also undergo reasonable technological processes to be prepared into materials with practical value. Through rational and economical synthesis and processing methods, many new materials can be continuously created, or the composition and structure of many traditional materials can be altered and precisely controlled, further exploring and enhancing material properties. The preparation/synthesis and processing of materials not only impart certain dimensions and shapes to materials but are also essential means to control their composition and structure. For example, steel can undergo heat treatments such as annealing, quenching, and tempering to alter its internal structure and achieve desired properties. Cold-rolled silicon steel sheets can significantly reduce iron loss through complex processing steps that align grains in a specific orientation. The blades of aircraft engines can be made into single-crystal blades through solidification control during casting, eliminating grain boundaries and greatly improving their service temperature and performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过例子分析材料加工对材料服役性能的影响，答案提供了详细的文字解释和论述，包括具体的例子和过程描述，符合简答题的特征。 | 知识层次: 题目要求分析材料加工对材料服役性能的影响，并提供实例进行说明。这需要综合运用材料科学的知识，理解加工工艺与材料性能之间的关系，进行推理分析和机理解释。题目不仅涉及多个加工工艺（如热处理、冷轧、铸造控制等），还需要将这些工艺与材料的结构和性能变化联系起来，思维过程的深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解材料加工对材料性能的影响，还需要能够综合运用多个知识点（如热处理、晶粒取向控制、单晶制备等）进行复杂现象的全面分析。正确选项涉及机理深度解释和复杂现象的全面分析，需要考生具备较高的知识整合能力和推理分析能力。此外，题目中的例子（如钢的热处理、冷轧硅钢片、单晶叶片）要求考生能够将理论知识与实际应用相结合，进一步增加了题目的难度。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 1709, + "question": "What is the connection between new materials and new processes?", + "answer": "Currently, new materials are often associated with new processing technologies. For example, amorphous metal alloys can be prepared through processing methods such as rapid cooling or mechanical alloying, whereas previously it was unknown that metals could be made amorphous. Other examples include spray deposition technology, semi-solid processing technology, and net-shape thin-strip continuous casting technology, all of which are new processing techniques. For certain polymer materials, the use of extrusion filament processes has significantly increased the specific strength and specific stiffness of organic fibers. Additionally, new optical fiber materials are prepared using CVD + melting or ion exchange methods, among others.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释新材料与新工艺之间的联系，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释新材料与新工艺之间的联系，并举例说明，涉及多个知识点的关联和综合分析，需要一定的理解和应用能力，但不需要深度推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解新材料与新工艺之间的关联，并能够通过具体例子进行综合分析。题目要求考生不仅掌握基本概念，还需要能够将不同工艺技术与材料特性联系起来，进行多步的思考和判断。" + }, + { + "idx": 1710, + "question": "How to control and improve the microstructure in metal materials through heat treatment?", + "answer": "The microstructure of metal materials can be altered through heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过热处理控制和改善金属材料的微观结构，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求通过热处理控制和改善金属材料的微观结构，这需要对热处理工艺（如退火、淬火、回火等）的机理有深入理解，并能综合分析不同工艺参数（如温度、时间、冷却速率）对微观结构的影响。此外，还需要推理分析不同金属材料的相变行为及其与性能的关系，属于复杂分析和综合运用的范畴。 | 难度: 在选择题型内，该题目属于较高难度等级。题目涉及金属材料微观结构的控制和改善，需要通过热处理的机理深度解释来理解。正确选项要求考生不仅掌握热处理的基本概念，还需要理解微观结构变化的机理，并能综合运用这些知识进行分析。这超出了简单记忆或基础理解的范畴，属于复杂分析层次，因此在选择题型内属于等级4的难度。" + }, + { + "idx": 1711, + "question": "How do dislocations affect the plastic deformation ability of metal materials?", + "answer": "The plastic deformation of metals is achieved through the movement of dislocations, therefore the strengthening methods for metal materials can be realized by altering the number of dislocations in the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释位错如何影响金属材料的塑性变形能力，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及位错对金属材料塑性变形能力的影响，需要理解位错运动与塑性变形的关系，并能够分析强化方法如何通过改变位错数量来实现。这需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解位错对金属塑性变形的影响机制，并关联强化方法如何通过改变位错数量实现。题目涉及多步概念关联和综合分析，但未达到多角度或深度关联性分析的要求。" + }, + { + "idx": 1712, + "question": "How to control and improve the microstructure in metallic materials through processing methods?", + "answer": "The microstructure of metallic materials can be altered through various processing methods, such as cooling rate and method during casting, temperature gradient, and the magnitude and method of pressure processing after casting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过加工方法控制和改善金属材料的微观结构，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求通过加工方法控制和改善金属材料的微观结构，涉及多种加工方法的综合应用和概念关联，需要理解不同加工参数（如冷却速率、温度梯度、压力加工等）对微观结构的影响，并进行综合分析。这超出了简单记忆或直接套用的层次，但尚未达到需要复杂推理或创新设计的程度。 | 难度: 在选择题中属于中等难度，需要理解金属材料微观结构控制的基本概念，并能够关联不同加工方法（如冷却速率、温度梯度、压力加工等）对微观结构的影响。虽然题目涉及多个概念的综合分析，但在选择题型中，正确选项已经提供了明确的关联性说明，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1713, + "question": "How to control and improve the grain size in metal materials through additives?", + "answer": "The grain size of metal can be altered by additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过添加剂控制和改善金属材料的晶粒尺寸，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目要求通过添加剂控制和改善金属材料的晶粒尺寸，涉及多步概念关联和综合分析，需要理解添加剂对晶粒生长的影响机制，并能够综合运用相关知识进行解释和论述。 | 难度: 在选择题中属于中等难度，需要理解金属材料中晶粒尺寸控制的基本原理，并能够将添加剂的作用与晶粒尺寸变化关联起来。题目涉及中等应用层次的知识，要求考生能够综合分析添加剂对金属晶粒尺寸的影响机制，而不仅仅是记忆单一知识点。" + }, + { + "idx": 1714, + "question": "Describe the deformation behavior and characteristics of a certain type of material you are familiar with.", + "answer": "Metallic materials typically undergo elastic deformation and plastic deformation stages during tensile deformation, and may eventually fracture. In each single crystal of metallic materials, the primary deformation mode is slip, while some metals may also exhibit twinning deformation during deformation. The microscopic mechanisms of both slip and twinning deformation can be explained using the concept of dislocations. Polycrystalline materials, due to the blocking effect of grain boundaries and the differences in orientation between adjacent grains, generally hinder dislocation motion, making deformation more difficult compared to single-crystal materials. Single-phase solid solution alloys exhibit solid solution strengthening due to the presence of solute atoms. Body-centered cubic metals show yield phenomena and strain aging during tensile deformation. The plastic deformation characteristics of multiphase alloys are related to the quantity, size, and distribution of the second phase. Generally, fine, dispersed, and uniformly distributed second phases enhance alloy strength, making deformation more difficult. Metallic materials often exhibit work hardening during deformation, accompanied by changes in microstructure and other physical and chemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述某种材料的变形行为和特征，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述特定材料的变形行为和特征，涉及多个变形阶段（弹性变形、塑性变形、断裂）、微观机制（滑移、孪生、位错）、多晶材料与单晶材料的比较、固溶强化、屈服现象、应变时效、多相合金的塑性变形特征以及加工硬化等多个复杂概念的综合分析和解释。需要深入理解材料变形的基本原理，并能将这些原理关联起来进行综合分析，解释不同条件下的变形行为。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求对金属材料的变形行为及其微观机理进行全面的分析和解释，涉及多个复杂概念的综合运用，如弹性变形、塑性变形、滑移、孪生、位错理论、晶界效应、固溶强化、屈服现象、应变时效、多相合金的变形特性以及加工硬化等。解题需要深入理解这些概念之间的相互关系，并能够进行机理层面的深度解释和复杂现象的综合分析。这种题目在选择题型中属于对知识掌握深度和综合分析能力要求极高的类型。" + }, + { + "idx": 1715, + "question": "How to control and improve the microstructure in metal materials by selecting compositions?", + "answer": "By selecting compositions to determine the appropriate microstructure, different compositions of metals can yield pure metals, single-phase solid solution alloys, and multi-phase alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过选择成分来控制和改善金属材料的微观结构，答案提供了详细的解释和分类，符合简答题的特征。 | 知识层次: 题目要求通过选择成分来控制并改善金属材料的微观结构，这涉及到对不同成分金属（纯金属、单相固溶体合金和多相合金）的理解和应用。虽然题目没有要求复杂的计算或深入的分析，但需要将成分选择与微观结构关联起来，进行一定的综合分析和概念关联，超出了单纯记忆或简单应用的层次。 | 难度: 在选择题中属于中等难度，需要理解金属材料中成分选择对微观结构的影响，并能够关联不同成分与纯金属、单相固溶体合金和多相合金之间的关系。题目要求综合分析成分选择对微观结构的控制作用，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1716, + "question": "Talk about your understanding of high-strength materials.", + "answer": "For structural materials, one of the most important performance indicators is strength. Strength refers to a material's ability to resist deformation and fracture. Improving the strength of a material can save materials and reduce costs. When utilizing the mechanical properties of materials, people always hope that the materials used have sufficient strength. They aim to reasonably apply and develop material strengthening methods to tap into the potential of material performance. Theoretically, there are two approaches to increasing the strength of metal materials: one is to completely eliminate internal dislocations and other defects, bringing its strength close to the theoretical strength. Although it is currently possible to produce high-strength metal whiskers without dislocations, practical applications remain challenging because the high strength obtained this way is unstable, highly sensitive to operational effects and surface conditions, and the strength drops significantly once dislocations occur. Therefore, in production practice, the primary approach to strengthening metals is to introduce a large number of defects to hinder dislocation movement. For example, common strengthening methods for metal materials include solid solution strengthening, grain refinement strengthening, second-phase particle strengthening, and deformation strengthening. By comprehensively applying these strengthening methods, it is possible to approach the theoretical strength from another perspective. For instance, in iron and titanium, up to 38% of the theoretical strength can be achieved. Some new high-strength aluminum alloys, such as Al-Li alloys, Al-Cu-Mg series alloys, Al-Zn-Mg series alloys, high-Zn-content Al-Zn-Mg alloys, Al-Mg-Sc series alloys, Al-Zn-Mg-Sc series alloys, and aluminum matrix composites, have achieved high strength and other comprehensive properties through various strengthening methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对高强材料进行理解和论述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求对高强材料进行深入理解和论述，涉及多种强化方法的综合运用、理论强度与实际应用的对比分析，以及具体合金体系的性能优化。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对高强材料的理解进行全面分析，涉及多种强化方法的综合运用、理论强度的概念、实际应用中的限制条件等复杂知识点。正确选项不仅需要掌握材料强度的基本定义，还需要理解金属材料强化的多种机理（如固溶强化、晶粒细化强化等），并能分析不同强化方法的实际应用效果和理论限制。这种深度和广度的知识要求在选择题型中属于最复杂的分析层次，需要考生具备综合运用和推理分析的能力。" + }, + { + "idx": 1717, + "question": "What is the effect of the interaction between dislocations and solute atoms on the properties of metallic materials?", + "answer": "The interaction between dislocations and solute atoms in alloys forms Cottrell atmospheres, leading to yield phenomena and strain aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述位错与溶质原子相互作用对金属材料性能的影响，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释位错与溶质原子相互作用对金属材料性能的影响机制，涉及位错理论、溶质原子扩散、Cottrell气团形成等复杂概念的综合运用和机理解释，需要深入分析和推理。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1718, + "question": "What is the effect of dislocations on the nucleation of the second phase?", + "answer": "Dislocations are preferential sites for the nucleation of the second phase, and typically the second phase can nucleate and grow preferentially at dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错对第二相形核的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及位错对第二相形核的影响机制，需要理解位错作为形核位点的原理，并能够解释第二相在位错处优先形核和生长的原因。这需要对位错和第二相形核的相互作用进行综合分析，属于机理层面的解释，思维深度较高。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解位错的基本概念，还需要掌握位错对第二相形核的影响机制。正确选项涉及位错作为第二相形核的择优位置，并解释了第二相在位错处优先形核和生长的机理。这需要考生具备综合运用知识、推理分析和机理解释的能力，属于复杂分析层次。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 1719, + "question": "How to control and improve the microstructure in metallic materials through rapid solidification and powder metallurgy?", + "answer": "Non-equilibrium microstructures can be obtained through rapid solidification and powder metallurgy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过快速凝固和粉末冶金控制和改善金属材料的微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释如何通过快速凝固和粉末冶金控制和改善金属材料的微观结构，这需要综合运用材料科学中的相变、凝固理论和加工工艺知识，进行推理分析和机理解释。涉及的知识点复杂且关联度高，思维过程需要深入分析和综合运用。 | 难度: 在选择题型中，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 1720, + "question": "Describe the solidification process of a certain type of material you are familiar with.", + "answer": "After the solidification process, metallic materials usually form crystals, so the solidification process of metallic materials is also called the crystallization process. The crystallization of metals generally consists of two stages: nucleation and subsequent growth. Nucleation in metals typically occurs on the basis of small-sized ordered atomic clusters (embryos) in the metal melt, where atomic diffusion leads to the formation of stable nuclei capable of growth. Thus, the nucleation process of pure metals generally requires meeting energy and structural conditions, while alloy nucleation also requires certain compositional conditions. The subsequent growth of metal nuclei usually requires a small degree of undercooling, with atoms diffusing toward the nuclei to facilitate growth. During the growth process, the crystallization interface is rough, so the growth rate of metals is generally rapid. The structure of the crystallization interface, temperature gradient, and crystallization speed influence the shape and size of the resulting grains. For alloys, this process can also lead to issues such as compositional segregation after crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述某种材料的凝固过程，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求描述特定材料的凝固过程，涉及金属材料的结晶过程，包括成核和生长两个阶段，以及能量、结构和成分条件等。需要理解并关联多个概念，如原子扩散、过冷度、结晶界面等，并进行综合分析。虽然不涉及复杂计算或创新设计，但需要较深的理解和应用能力。 | 难度: 在选择题型中，该题目属于较高难度。题目要求对金属材料的凝固过程进行详细描述，涉及多个关键概念（如成核、生长、能量和结构条件、成分条件等）的综合分析。此外，题目还要求理解凝固过程中的界面结构、温度梯度和结晶速度对晶粒形状和尺寸的影响，以及合金中可能出现的成分偏析问题。这些知识点不仅需要深入理解，还需要能够关联和综合分析，因此在选择题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 1721, + "question": "What effect does constitutional supercooling have on the solidification structure of alloys?", + "answer": "The occurrence of constitutional supercooling phenomenon will cause multicomponent alloys to develop cellular or dendritic structures even under a positive temperature gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释constitutional supercooling对合金凝固结构的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及合金凝固过程中成分过冷现象对凝固组织的影响，需要理解成分过冷的形成机制及其与凝固组织形貌的关系，属于对材料科学中凝固理论的深入分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目涉及复杂的合金凝固现象，要求考生不仅理解\"成分过冷\"的概念，还需要掌握其对凝固组织的影响机制。正确选项需要综合温度梯度、多组分合金特性以及凝固组织形态学等多方面知识进行推理分析。这种题目在选择题中属于对机理深度解释和复杂现象全面分析要求最高的类型，需要考生具备扎实的理论基础和综合分析能力。" + }, + { + "idx": 1722, + "question": "Why does constitutional supercooling occur during the solidification of multicomponent alloys?", + "answer": "During the solidification of multicomponent alloys, elements with higher melting points solidify first. If the alloy is not sufficiently stirred, elements with lower melting points will become enriched at the solidification interface front, lowering the actual solidification temperature of the liquid phase there. Even under a positive temperature gradient, the degree of supercooling at the solidification interface front may increase with distance from the interface. This phenomenon is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释\"constitutional supercooling\"现象的原因，需要文字论述和解释，而不是选择、判断或计算。答案提供了详细的文字说明来解释这一现象。 | 知识层次: 题目要求解释多组分合金凝固过程中的成分过冷现象，涉及多元素凝固顺序、界面富集、实际凝固温度变化等复杂机理的综合分析，需要深入理解热力学和动力学原理并进行推理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解多组分合金凝固过程中的成分过冷现象，涉及多个复杂概念的整合（如熔点差异、界面富集、温度梯度等）。正确选项不仅需要解释机理，还需要综合推理实际凝固温度变化与界面距离的关系。这种复杂现象全面分析的题目在选择题中属于对专业知识和分析能力要求极高的类型，远超基础概念题和简单应用题的难度。" + }, + { + "idx": 1723, + "question": "Summarize the grain boundary strengthening mechanism in the application of dislocation theory in materials science, considering the factors affecting the strength of metal materials", + "answer": "Grain boundary strengthening, according to the Hall-Petch formula, essentially means that additional stress is required for dislocations to cross grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对晶界强化机制进行总结，并考虑影响金属材料强度的因素，需要文字解释和论述，而不是选择、判断或计算。答案也提供了简要的解释，符合简答题的特征。 | 知识层次: 题目要求总结晶界强化机制，并应用位错理论进行解释，同时考虑影响金属材料强度的因素。这需要综合运用多个概念（晶界、位错、Hall-Petch关系等），进行机理层面的分析和解释，涉及较高层次的认知能力和思维深度。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1724, + "question": "Combining the factors affecting the strength of metal materials, summarize the solid solution strengthening mechanism in the application of dislocation theory in materials science", + "answer": "The possible dislocation mechanisms of solid solution strengthening mainly include the pinning of dislocations by solute atom atmospheres, which increases the resistance to dislocation slip. Examples include the Cottrell atmosphere and Snoek atmosphere resulting from the elastic interaction between solute atoms and dislocations, as well as the Suzuki atmosphere arising from the interaction between solute atoms and extended dislocations, which increases the stacking fault width, making dislocation constriction and cross-slip more difficult. The segregation and short-range order formed by solute atoms raise the energy when dislocations pass through and disrupt these configurations, thereby increasing the resistance to dislocation motion. Additionally, the electrostatic interaction between solute atoms and dislocations generates resistance to dislocation slip, enhancing the material's strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求结合金属材料强度的影响因素，总结固溶强化机制在材料科学位错理论中的应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求结合金属材料强度的多种影响因素，运用位错理论来总结固溶强化机制。这需要深入理解位错与溶质原子之间的相互作用机制（如Cottrell atmosphere、Snoek atmosphere、Suzuki atmosphere等），并能够综合分析这些机制如何影响材料的强度。题目涉及多个复杂概念的关联和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用材料科学中的多个高级概念（如固溶强化机制、位错理论、Cottrell/Snoek/Suzuki atmosphere等），并需要深入理解这些机理之间的相互作用。正确选项不仅涉及多个专业术语的准确解释，还需要将这些概念串联起来形成完整的机理解释链。这种题目要求考生具备将理论知识应用于复杂现象分析的能力，远超简单记忆或基础理解的层次，属于选择题型中最具挑战性的综合推理分析类型。" + }, + { + "idx": 1725, + "question": "What is the basic principle of grain refinement by adding a modifier?", + "answer": "The basic principle of grain refinement by a modifier is that the modifier itself or the reaction between the modifier and elements in the alloy can form dispersed phases that serve as nucleation sites for alloy precipitation. These dispersed phases can form coherent interfaces with very low interfacial energy with the solidifying phase of the alloy, enabling heterogeneous nucleation of the alloy on these dispersed phases, thereby achieving the purpose of grain refinement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶粒细化的基本原理，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对晶粒细化基本原理的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项需要对晶粒细化的基本原理进行解释和描述，包括分散相的形成、异质成核等概念。这比简单的定义记忆（等级1）要求更高，但不需要复杂的体系阐述（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1726, + "question": "Given the vacancy formation energy of aluminum is 0.76 eV/vacancy, and the lattice constant of aluminum at 25°C is 0.405 nm, calculate the vacancy concentration in aluminum at 25°C (vacancies/cm3).", + "answer": "Let the lattice constant of aluminum be a=0.405 nm. From the problem, the number of unit cells per unit crystal volume is 1/a3. Since aluminum has an FCC structure, the number of atoms per unit cell is 4, so the number of lattice sites per unit volume is N=4/a3. The vacancy concentration is Cv=Ae^(-Qv/RT), where A is a material constant, usually taken as A=1; the vacancy formation energy Qv=0.76 eV, and 1 eV=1.602×10-19 J; R=8.31 J/mol·K is the gas constant; and T is the thermodynamic temperature. At 25°C, T=(273+25) K=298 K. Substituting into the formula, the vacancy concentration in aluminum at this temperature is n=8.34×10^9 vacancies/cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝在25°C时的空位浓度，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括理解FCC结构、单位晶胞体积计算、阿伦尼乌斯公式应用以及单位换算等综合分析过程，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如晶格常数、空位形成能、FCC结构等）并进行多步计算（包括单位转换、公式代入和指数运算）。虽然题目提供了所有必要参数，但解题过程涉及多个物理概念的关联应用和综合计算能力，比单纯的概念选择题更复杂。" + }, + { + "idx": 1727, + "question": "Based on the factors affecting the strength of metal materials, summarize the dispersion strengthening mechanism in the application of dislocation theory in materials science", + "answer": "Dispersion strengthening also strengthens materials by hindering dislocation movement, such as the Orowan mechanism where dislocations bypass harder, incoherent second-phase particles with the matrix, and the cutting mechanism where dislocations cut through softer, coherent second-phase particles with the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于金属材料强度的因素，总结分散强化机制在材料科学中位错理论的应用，需要文字解释和论述。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求基于金属材料强度的影响因素，总结弥散强化机制在材料科学中位错理论的应用。这需要综合运用位错理论、弥散强化机制（如Orowan机制和切割机制）以及它们与材料性能的关系，涉及多个概念的关联和深入分析，思维过程要求较高。 | 难度: 在选择题中属于最高难度，题目要求综合运用材料科学中的多个高级概念（如位错理论、Orowan机制、切割机制等），并需要理解不同强化机制之间的区别和联系。正确选项涉及复杂的机理解释和现象分析，需要考生具备深入的材料科学知识和高阶思维能力。这种题目在选择题型中属于对知识掌握深度和综合分析能力要求最高的类型。" + }, + { + "idx": 1730, + "question": "Summarize the work hardening mechanism in the application of dislocation theory in materials science based on the factors affecting the strength of metallic materials", + "answer": "Various possible mechanisms for work hardening include the theory of parallel dislocation hardening due to interactions between parallel dislocations on the slip plane, and the theory of forest dislocation strengthening caused by the cutting of forest dislocations on other slip planes by dislocations on the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对工作硬化机制进行总结和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求基于位错理论总结加工硬化机制，并涉及影响金属材料强度的因素。这需要综合运用位错理论、理解不同位错相互作用机制（如平行位错和森林位错强化），并进行机理层面的解释和分析。这种题目不仅需要深入理解位错理论，还需要将多个概念关联起来进行综合分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求基于位错理论综合解释金属材料加工硬化的多种机制，涉及平行位错强化和林位错强化等复杂概念的机理分析。正确选项不仅需要掌握位错相互作用的核心原理，还需理解不同强化机制之间的区别与联系。这种深度机理解释和复杂现象分析在选择题中属于对专业知识和推理能力的最高要求，远超单纯记忆或简单应用层面。" + }, + { + "idx": 1732, + "question": "Explain which locations are likely to be the preferred nucleation sites for recrystallization", + "answer": "The preferred nucleation sites are: original grain boundaries, newly formed high-angle grain boundaries during deformation or gradually formed high-angle grain boundaries through subgrain growth, and the vicinity of second-phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释再结晶的优先形核位置，答案需要文字解释和论述，没有提供选项或要求计算 | 知识层次: 题目要求解释再结晶过程中优先形核的位置，涉及对变形过程中晶界演变、亚晶生长和第二相粒子影响的理解。需要将多个概念关联起来进行综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。正确选项涉及多个关键概念的综合分析，包括原始晶界、变形过程中新形成的高角度晶界、亚晶生长逐渐形成的高角度晶界以及第二相粒子附近的成核位置。考生需要理解这些不同位置的成核机制及其相互关系，并能将这些概念关联起来进行多角度分析。此外，题目要求的知识层次为中等应用，涉及多步计算和概念关联，进一步增加了题目的复杂程度。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 1733, + "question": "What is a modifier?", + "answer": "A substance that can change the phase composition, phase morphology, or grain size of an alloy's as-cast structure by adding a small amount, thereby altering the properties of the cast alloy, is called a modifier.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“modifier”进行定义和解释，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对\"modifier\"这一基本概念的定义和作用的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求识别和记忆“modifier”的基本定义，属于最基础的概念记忆层次。正确选项直接给出了定义，无需进行复杂的概念比较或分析，符合等级1“基本定义简答”的标准。" + }, + { + "idx": 1734, + "question": "Given the vacancy formation energy of aluminum is 0.76 eV/vacancy, and the lattice constant of aluminum at 25°C is 0.405 nm, at what temperature will the vacancy concentration in aluminum be 1000 times that at 25°C?", + "answer": "Let the vacancy concentration at 25°C be n1=8.34×10^9 vacancies/cm3, and the vacancy concentration after 1000 times be n2=8.34×10^12 vacancies/cm3. According to the vacancy concentration formula Cv=Ae^(-Qv/RT), we have n2/n1=e^(Qv/R(1/T1-1/T2)). Substituting n2=1000n1, Qv=0.76eV=0.76×1.602×10-19J, R=8.31J/mol·K, T1=298K, we solve for T2≈434K. Therefore, the vacancy concentration in aluminum at approximately 434K is 1000 times that at 25°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定温度下的空位浓度变化，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用空位浓度公式进行多步计算，涉及能量单位转换和温度关系的推导，需要综合分析能力和概念关联。虽然计算过程明确，但需要理解公式中各参数的意义及其相互关系，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解空位浓度公式并进行多步计算。题目涉及能量单位转换（eV到J）、温度转换（℃到K）、对数运算以及综合公式推导。虽然提供了关键参数，但解题过程需要较强的概念关联和综合分析能力，属于典型的综合性计算问题。" + }, + { + "idx": 1735, + "question": "Briefly describe the laws of changes in material structure and properties during recovery and recrystallization annealing of metals after cold deformation", + "answer": "As the annealing temperature increases or the annealing time prolongs, dislocation tangles in the deformed structure evolve into subgrains, which then merge and grow; recrystallization nucleation and growth occur in areas of uneven deformation, with equiaxed grains replacing elongated deformed grains; followed by normal grain growth. In terms of properties, strength and hardness decrease, electrical resistance decreases; plasticity and toughness improve. These processes are more pronounced during the recrystallization stage than the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述金属冷变形后回复和再结晶退火过程中结构和性能变化的规律，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求描述金属冷变形后回复和再结晶退火过程中组织与性能变化的规律，涉及多个概念（位错、亚晶、再结晶等）的关联和综合分析，需要理解并应用材料科学中的基本原理来解释现象，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求描述金属冷变形后回复和再结晶退火过程中组织与性能变化的规律，涉及多个步骤和概念关联，如位错缠结演变为亚晶、再结晶形核与长大、晶粒生长等。此外，还需要综合分析性能变化趋势（强度、硬度、塑性等）。虽然题目提供了正确选项，但理解和掌握这些内容需要一定的综合分析能力，因此在选择题型内属于等级3难度。" + }, + { + "idx": 1739, + "question": "Summarize the order strengthening mechanism in the application of dislocation theory in materials science based on the factors affecting the strength of metallic materials", + "answer": "Order strengthening: In ordered alloys, dislocations are superdislocations. To induce plastic deformation in the metal, both partial dislocations of the superdislocation must move simultaneously, requiring greater external stress. The bonding force between dissimilar element atoms is stronger than that between similar element atoms, so the ordered arrangement of dissimilar atoms imparts higher strength to ordered alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对有序强化机制进行总结和解释，答案提供了详细的文字论述，符合简答题的特征 | 知识层次: 题目要求基于位错理论解释有序强化的机理，涉及对位错运动、原子间作用力等复杂概念的综合理解和分析，需要将多个知识点关联起来进行深入解释，属于复杂分析层次。 | 难度: 在选择题型中属于最高难度等级，因为该题目要求考生：" + }, + { + "idx": 1740, + "question": "The space lattice is an abstraction derived from the ____ in the crystal structure. a. atoms b. ions c. geometric points d. equivalent points", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体结构中空间点阵这一基础概念的记忆和理解，属于定义性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解空间点阵是从晶体结构中的等效点抽象出来的概念，并进行简单的概念辨析。虽然涉及基础概念记忆，但需要区分几何点和等效点的差异，比单纯记忆定义稍复杂。" + }, + { + "idx": 1741, + "question": "According to the law of rational indices, the coordinate axes in a crystal structure should be selected in the direction of . a．mutually perpendicular b．close-packed planes c．rows in the crystal", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c中选择正确答案，符合选择题的特征 | 知识层次: 题目考查晶体结构中坐标轴选择方向的基本概念记忆，属于对\"有理指数定律\"基础知识的直接考察。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然考察的是基础概念记忆，但需要学生对\"law of rational indices\"有基本理解，并能区分\"rows in the crystal\"与其他选项的区别。相比直接记忆定义（等级1），此题需要一定的概念辨析能力（等级2），但不需要复杂的分析推理（等级3）。" + }, + { + "idx": 1742, + "question": "Point out the main differences between recrystallization, crystallization, and solid-state phase transformation", + "answer": "Recrystallization is only a microstructural change without structural change, and its driving force is deformation stored energy; crystallization is the process of forming crystals from amorphous liquid, gas, or solid states; solid-state phase transformation is a structural change between solid/solid phases. The driving forces for the latter two are both chemical free energy differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述三个概念之间的主要区别，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目考查对再结晶、结晶和固态相变这三个基本概念的定义和区别的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求考生能够区分三个相关但不同的概念（再结晶、结晶和固态相变），并理解它们各自的驱动力和变化类型。虽然题目涉及多个概念，但每个概念的定义和区别相对明确，不需要复杂的推导或综合分析。因此，该题目属于中等难度，主要考察考生对基础概念的理解和记忆能力。" + }, + { + "idx": 1743, + "question": "A crystal structure with space group Fm3m belongs to the _ crystal family and crystal system. a. high b. intermediate c. low d. cubic e. hexagonal f. tetragonal g. orthorhombic", + "answer": "a d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项字母组合 | 知识层次: 题目考查对晶体结构和空间群分类的基础概念记忆，属于对晶体家族和晶系的基本分类知识的直接回忆。 | 难度: 在选择题中属于中等难度，需要理解空间群Fm3m属于高对称性（high）和立方（cubic）晶系，并进行简单辨析。虽然涉及基础概念记忆，但需要将空间群与晶族和晶系对应起来，有一定的理解要求。" + }, + { + "idx": 1744, + "question": "In the non-stoichiometric compound ZrO2-x, the lattice defect present is a. anion vacancy b. cation vacancy c. anion interstitial d. cation interstitial", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查非化学计量化合物中晶格缺陷类型的基本概念记忆，仅需识别ZrO2-x中存在的缺陷类型（阴离子空位），无需复杂分析或计算。 | 难度: 在选择题型中，该题目需要理解非化学计量化合物ZrO2-x中的晶格缺陷类型，并能够区分阴离子空位、阳离子空位、阴离子间隙和阳离子间隙等概念。虽然题目涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，因此属于等级2难度。" + }, + { + "idx": 1745, + "question": "a≠b≠c,α≠β≠γ crystals belong to the crystal system. a. cubic b. hexagonal c. tetragonal d. orthorhombic", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项（a. cubic b. hexagonal c. tetragonal d. orthorhombic）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查晶体系统分类的基本概念记忆，只需记住不同晶体系统的晶格参数特征即可选择正确答案。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体系统的基本分类和特征，并能根据题目描述的条件（a≠b≠c,α≠β≠γ）进行简单辨析，但不需要复杂的分析或深度理解多个概念。" + }, + { + "idx": 1746, + "question": "The melt is a mixture of . a. polymers with the same degree of polymerization and free alkali b. various polymers with different degrees of polymerization c. various oligomers d. various high polymers", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案 | 知识层次: 题目考查对熔体混合物组成的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生理解\"melt\"的组成成分。虽然需要区分不同聚合度的聚合物概念，但选项间的区分度较为明显，正确选项b直接对应教材定义，无需复杂分析。在选择题型中属于需要简单概念辨析的难度等级。" + }, + { + "idx": 1747, + "question": "In UO2 crystals, the diffusion of O2- proceeds via the mechanism. a. vacancy b. interstitial c. dopant point defect", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a. vacancy b. interstitial c. dopant point defect）中选择一个正确答案（b），符合选择题的特征。 | 知识层次: 题目考查对UO2晶体中O2-扩散机制的基础概念记忆，属于对基本原理和分类的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生了解UO2晶体中O2-的扩散机制。虽然需要记忆具体机制类型（间隙扩散），但不需要复杂的分析或比较过程。在选择题型中属于概念理解和简单辨析难度，比纯粹的概念识别（等级1）稍高，但低于需要深度理解的复杂概念区分（等级3）。" + }, + { + "idx": 1748, + "question": "During liquid-solid phase transformation, the heterogeneous nucleation barrier is related to the contact angle θ. When , the heterogeneous nucleation barrier is reduced by half compared to the homogeneous nucleation barrier. a.θ=0° b.θ=45° c.θ=90° d.θ=180°", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对异质成核能垒与接触角关系的理解，需要应用基本公式和概念进行简单计算和判断，属于直接套用知识点的范畴。 | 难度: 在选择题型中，该题目属于简单难度。题目直接考察对异质形核能垒与接触角关系的理解，只需应用基本公式即可得出答案。解题步骤简单，无需复杂计算或公式变形，属于直接套用知识点的类型。" + }, + { + "idx": 1749, + "question": "In a ternary system phase diagram, if there are n boundary lines, then the number of connecting lines that can be drawn in this phase diagram is . a. 3 b. n - 1 c. n d. n+1", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a. 3 b. n - 1 c. n d. n+1）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对三元相图中边界线和连接线数量关系的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（三元系统相图的边界线和连接线数量关系），但需要考生理解相图的基本构造原理和边界线与连接线之间的对应关系，而不仅仅是简单的定义记忆。正确选项需要考生通过基本概念的理解进行简单辨析，因此属于等级2难度。" + }, + { + "idx": 1750, + "question": "Most solid-phase reactions are in a. chemical reaction kinetics range b. diffusion kinetics range c. transition range", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的三个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对固相反应动力学范围的基础概念记忆，属于基本原理的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆\"大多数固相反应属于扩散动力学范围\"这一知识点即可作答，无需复杂辨析或深度理解。题目选项设计简单明确，正确选项与其他选项区分度高，属于最简单的概念识别类型。" + }, + { + "idx": 1751, + "question": "In the sintering process, the mass transfer method that only gradually increases the strength of the green body without causing shrinkage of the green body is a. lattice diffusion b. flow mass transfer c. evaporation-condensation d. dissolution-precipitation", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案，符合选择题的特征 | 知识层次: 题目考查烧结过程中物质传递方式的基本概念记忆和理解，特别是蒸发-凝聚这一特定机制的特征，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解烧结过程中不同传质方式的基本概念及其对生坯的影响，并进行简单辨析。虽然涉及多个概念，但题目明确给出了关键特征（不引起收缩），降低了分析复杂度。" + }, + { + "idx": 1752, + "question": "There are types of spatial lattice forms that may correspond to the seven crystal systems.", + "answer": "14", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的数字答案（14），这属于需要直接回答的简答题形式，而不是从选项中选择或判断对错 | 知识层次: 题目考查对晶体系统与空间格子类型对应关系的基础概念记忆，属于分类和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆晶体系统对应的空间格子类型数量这一简单事实。题目不涉及复杂概念体系或解题步骤，仅需直接选择正确数字选项，因此属于最低难度等级。" + }, + { + "idx": 1754, + "question": "In the closest packing of equal-sized spheres, which crystal plane should the close-packed planes of cubic close packing be parallel to?", + "answer": "(111)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求识别立方密堆积中的密排面，并给出具体的晶面指数（111），这需要理解晶体结构和密堆积的知识，属于简答题类型。答案是一个具体的晶面指数，而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查对立方紧密堆积（cubic close packing）中密排面（close-packed planes）的基本概念记忆，即密排面平行于(111)晶面。这属于对晶体结构基本原理的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察对立方密堆积中最密排晶面（111）的基础概念记忆，属于最基础的定义简答级别。无需解释或复杂分析，只需直接回忆晶体学基本知识即可作答。" + }, + { + "idx": 1755, + "question": "The unit cell is (2), whose _(3)_ and (4)_ are consistent with the corresponding unit parallelepiped.", + "answer": "(2) the smallest unit that can fully reflect the characteristics of the crystal structure; (3) shape; (4) size", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对晶体结构中最基本单元的定义和特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生同时理解并正确匹配三个关键概念（晶胞的定义、形状和大小），而不仅仅是单一的定义记忆。这要求考生对晶体结构的基本原理有较清晰的理解，并能将这些概念联系起来。" + }, + { + "idx": 1756, + "question": "When a cubic close packing is formed by n spheres, what is the number of tetrahedral voids?", + "answer": "2n", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算立方紧密堆积中四面体空隙的数量，需要应用材料科学中的相关公式和概念，最终答案是一个具体的数值（2n），属于计算题的特征。 | 知识层次: 题目考查对立方紧密堆积中四面体空隙数量的基本公式应用，只需直接套用\"四面体空隙数量=2n\"的结论进行计算，属于简单应用层次。 | 难度: 在选择题中属于简单公式应用计算难度，题目直接考察立方密堆积中四面体空隙数量的基本公式应用（2n），无需复杂推导或多步骤计算，属于单一知识点直接套用类型。" + }, + { + "idx": 1757, + "question": "In the thermodynamic relation of diffusion coefficient, $\\\\left(1+\\\\frac{\\\\partial\\\\mathrm{ln}\\\\gamma_{i}}{\\\\partial\\\\mathrm{ln}N_{\\\\mathrm{i}}}\\\\right)$ is called the thermodynamic factor of diffusion coefficient. In a non-ideal mixing system: when the thermodynamic factor of diffusion coefficient > 0, the diffusion result causes the solute to ____; when the thermodynamic factor of diffusion coefficient < 0, the diffusion result causes the solute to ____. a. segregate b. concentration remains unchanged c. concentration tends to be uniform", + "answer": "c a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（a. segregate b. concentration remains unchanged c. concentration tends to be uniform）中选择正确的填空答案，符合选择题的特征。 | 知识层次: 题目涉及非理想混合系统中扩散系数的热力学因子及其对溶质扩散结果的影响，需要理解热力学因子的概念及其与扩散行为的关系，属于中等应用层次。需要将热力学因子与扩散结果联系起来进行分析，但不需要复杂的推理或综合运用。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度等级。题目要求考生不仅要理解扩散系数的热力学因子概念，还需要掌握非理想混合系统中热力学因子与扩散结果之间的关联。解题步骤涉及对热力学因子正负值的含义进行判断，并将其与溶质的扩散行为（偏聚或均匀化）联系起来。这种综合分析过程超出了简单概念记忆或单一知识点应用的范围，属于需要多步推理和概念关联的中等应用层次题目。" + }, + { + "idx": 1758, + "question": "When n spheres form a cubic close packing, what is the number of octahedral voids?", + "answer": "n", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算立方密堆积中八面体空隙的数量，需要应用材料科学中的晶体结构知识进行数值计算，答案是一个具体的数值(n)。 | 知识层次: 题目需要应用立方密堆积中八面体空隙数量的基本公式，属于直接套用已知知识进行简单计算的情况，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目直接考察立方密堆积中八面体空隙数量的基本公式应用（n个球体对应n个八面体空隙），无需任何计算或推导过程，仅需记忆或识别这一基本知识点即可作答。" + }, + { + "idx": 1759, + "question": "What is the viscosity corresponding to the characteristic temperature Tf?", + "answer": "(19)108dPa·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（108dPa·s），这属于需要直接给出答案的简答题形式，不需要选择、判断或计算过程 | 知识层次: 题目考查的是特征温度Tf对应的粘度值这一基本概念的记忆，属于定义性知识的直接回忆，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的具体数值（108dPa·s），属于直接回忆型问题，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1760, + "question": "The crystal structure is related to its (10) (11) and (12).", + "answer": "(10) chemical composition; (11) relative size of particles; (12) polarization properties", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的术语或概念，而不是从选项中选择或进行判断、计算。答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查晶体结构与其化学组成、粒子相对大小和极化性质之间关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体结构的基础概念记忆，但需要考生同时掌握化学组成、颗粒相对大小和极化特性三个相关知识点，并理解它们与晶体结构的关系。这比单纯记忆单一概念（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 1761, + "question": "The reason why a base-centered lattice cannot exist in the cubic system is _(9)", + "answer": "If a base-centered lattice existed in the cubic system, the characteristic 4L3 symmetry of the cubic system would no longer exist, which does not conform to the symmetry characteristics of the cubic system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在立方晶系中不能存在底心点阵，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释为什么底心立方晶系不存在，需要理解立方晶系的对称性特征（4L3对称性）以及底心晶格对对称性的影响。这涉及到对晶体学对称性和晶格类型的综合分析，需要推理和解释机理，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解立方晶系的基本对称性特征（4L3对称性），还需要进行复杂的推理分析，解释为什么底心点阵在立方晶系中无法存在。这涉及到对晶体学对称性原理的深度理解和综合运用，远超简单的记忆或概念辨析。正确选项的推导需要考生将对称性原理与点阵类型的具体限制相结合，属于复杂现象全面分析的范畴。" + }, + { + "idx": 1762, + "question": "When 6 mol% of MgO is added to the UO2 lattice to form a substitutional solid solution, write its solid solution formula", + "answer": "U0.94Mg0.06O1.94", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出固溶体的化学式，需要根据给定的摩尔百分比进行计算和表达，答案是一个具体的化学式而非选择或判断。虽然涉及计算，但更侧重于化学式的表达和书写，属于简答题范畴。 | 知识层次: 题目考查的是基本公式应用和简单计算，需要根据给定的摩尔百分比计算固溶体的化学式，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求考生根据给定的摩尔百分比（6 mol% MgO）直接套用固溶体公式，并进行简单的计算（如U的摩尔分数为0.94，O的摩尔分数为1.94）。解题步骤较为直接，无需复杂的分析或推导，仅需基本公式应用和简单计算即可得出正确选项。因此，在选择题型内属于较低难度（等级2）。" + }, + { + "idx": 1763, + "question": "In the wetting of solid-liquid interfaces, what is the second method to improve wetting?", + "answer": "Increase the surface energy of the solid", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释第二种改善固体-液体界面润湿的方法，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查的是关于固体-液体界面润湿改进方法的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解固体-液体界面润湿的基本原理，并知道提高润湿的第二种方法。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 1764, + "question": "What is the viscosity corresponding to the characteristic temperature Tg?", + "answer": "(18)1013dPa·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（1013dPa·s），这个数值是材料科学中关于玻璃化转变温度（Tg）对应的粘度的标准值，不需要计算或选择，属于需要直接回答的简答题类型。 | 知识层次: 题目考查的是材料科学中玻璃化转变温度(Tg)对应的粘度值这一基本概念的记忆，属于定义性知识的直接回忆，不涉及复杂计算或分析。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即Tg温度对应的粘度值。不需要解释或分析，只需直接回忆正确答案1013dPa·s。属于最简单的记忆性题目类型。" + }, + { + "idx": 1765, + "question": "In the wetting of solid-liquid interfaces, what is the third method to improve wetting?", + "answer": "Altering the surface roughness of the solid", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释第三种改善固体-液体界面润湿的方法，答案需要提供文字解释而非选择、判断或计算。 | 知识层次: 题目涉及固体-液体界面润湿性的改善方法，需要理解润湿性的基本原理，并能够关联表面粗糙度对润湿性的影响。这需要多步的概念关联和综合分析，而不仅仅是简单的记忆或直接应用。 | 难度: 在选择题中属于中等难度，需要理解固体-液体界面润湿的基本概念，并能够综合分析不同改善润湿方法的特点。题目要求考生在已知两种常见方法（如改变表面张力或温度）的基础上，识别第三种方法（改变固体表面粗糙度），这需要一定的概念关联和综合分析能力。虽然不涉及多步计算，但需要对润湿机制有较深入的理解才能正确选择。" + }, + { + "idx": 1766, + "question": "7. The reason why glass is isotropic is (15)", + "answer": "The long-range disorder of the glass structure exhibits statistical homogeneity macroscopically", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释玻璃各向同性的原因，答案是一个简短的论述性回答，符合简答题的特征 | 知识层次: 题目考查玻璃各向同性的基本原因，属于对材料结构特性的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆层次，要求考生理解玻璃各向同性的原因。虽然需要掌握\"长程无序\"和\"统计均匀性\"等专业术语，但属于单一概念的解释性题目，不需要进行多概念比较或复杂推理。在选择题型中属于中等难度，高于简单定义识记但低于需要综合分析的多概念题目。" + }, + { + "idx": 1767, + "question": "In the wetting of solid-liquid interfaces, one of the methods to improve wetting is?", + "answer": "Reduce the solid-liquid interfacial energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释一种改善润湿的方法，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查的是关于固体-液体界面润湿改进方法的基本概念记忆，即通过降低固液界面能来改善润湿性。这属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即\"降低固液界面能\"这一改善润湿性的方法。题目不涉及概念解释或复杂体系分析，属于最基础的定义简答级别。" + }, + { + "idx": 1768, + "question": "When 6 mol% of MgO is added to the UO2 lattice to form a substitutional solid solution, write the defect reaction equation.", + "answer": "MgO→UO2Mg0′′+O0+V0∗", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求写出缺陷反应方程，需要理解固溶体形成的基本原理和缺陷化学的知识，并能够将这些概念关联起来进行综合分析。虽然不涉及复杂的计算，但需要多步的逻辑推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解缺陷化学的基本概念，掌握离子替代和空位形成的原理，并能正确书写缺陷反应方程式。虽然题目涉及多步计算和概念关联，但在选择题型中，通过选项提示可以降低部分难度。" + }, + { + "idx": 1769, + "question": "What are the two characteristic temperatures on the curve of glass properties changing with temperature?", + "answer": "(16) Tg; (17) Tf", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答两个特征温度的名称，答案以简短的词语形式给出，不需要计算或选择，属于简答题类型 | 知识层次: 题目考查玻璃性质随温度变化的两个特征温度（Tg和Tf）的基本概念记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆玻璃性质变化曲线上的两个特征温度（Tg和Tf），属于基础概念记忆的简单问题。无需解释或分析，只需直接回忆定义即可选择正确答案。" + }, + { + "idx": 1770, + "question": "10. What type of solid solution can albite Na(AlSi3O8) and anorthite Ca(Al2Si2O8) form?", + "answer": "Continuous substitutional solid solution", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释albite和anorthite能形成哪种类型的固溶体，答案需要文字描述（Continuous substitutional solid solution），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目需要理解固溶体的类型及其形成条件，并能够将这一概念应用到具体的矿物体系中（钠长石和钙长石）。这涉及到对固溶体分类的理解以及矿物化学组成的分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解固溶体的基本概念，并能区分不同类型固溶体的特征。题目涉及两种矿物（钠长石和钙长石）的固溶体形成，要求考生掌握连续置换型固溶体的特点，并能将这一概念应用到具体矿物体系中。虽然不需要复杂的计算，但需要对相关概念有清晰的理解和正确的应用。" + }, + { + "idx": 1771, + "question": "11．The crystallographic characteristics of martensitic transformation are manifested as: _（26）_, etc.", + "answer": "（26）the presence of habit plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（habit plane）来描述马氏体转变的晶体学特征，这属于需要文字解释和论述的简答题类型。答案不是从多个选项中选择，也不是判断对错或进行数值计算。 | 知识层次: 题目考查马氏体相变的基本晶体学特征，属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对马氏体相变基本特征的记忆，属于基础概念的直接回忆。题目仅要求识别\"habit plane\"这一特定术语，无需解释或分析，符合等级1的基本定义简答要求。" + }, + { + "idx": 1772, + "question": "11. The crystallographic characteristics of martensitic transformation are manifested as: _（27）_, etc.", + "answer": "（27）strict orientation relationship", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（\"strict orientation relationship\"）来补充句子，这属于需要简短文字回答的简答题类型。 | 知识层次: 题目考查马氏体相变的晶体学特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆马氏体相变的晶体学特征之一（严格的取向关系），属于基础概念记忆层次，无需解释或分析，解题步骤简单直接。" + }, + { + "idx": 1773, + "question": "11. The crystallographic characteristics of martensitic transformation are manifested as: _(28)_, etc.", + "answer": "(28) maintaining coherent relationship", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的术语或短语（\"maintaining coherent relationship\"）来补充句子，这属于需要简短文字回答的类型，而非选择、判断或计算。 | 知识层次: 题目考查马氏体相变的晶体学特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆马氏体相变的晶体学特征之一，即保持共格关系。这属于基础概念记忆层次，无需复杂分析或推理，仅需对定义性知识进行简单回忆。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1774, + "question": "10. What ions in plagioclase Na(AlSi3O8) and what ions in anorthite Ca(Al2Si2O8) can substitute for each other?", + "answer": "Na+ and Si4+ in plagioclase can substitute for Ca2+ and Al3+ in anorthite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种矿物中哪些离子可以相互替代，需要文字解释和论述，答案也是以文字形式给出，而非选择、判断或计算。 | 知识层次: 题目要求理解并应用离子替代的概念，涉及不同矿物中离子的替换关系，需要综合分析Na+和Si4+与Ca2+和Al3+之间的替代机制，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解并分析两种矿物中离子的替代关系，涉及多步计算和概念关联，综合分析能力要求较高。" + }, + { + "idx": 1776, + "question": "A green body with an initial particle size of 5μm is sintered for 2h to reach x/r=0.1. If sintering continues until x/r=0.2 (without considering grain growth), what is the required sintering time when material transport occurs via dissolution-precipitation?", + "answer": "128h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算，涉及公式应用（如烧结时间与x/r的关系），答案是一个具体的数值（128h），属于典型的计算题特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解溶解-沉淀机制下的烧结动力学关系，并通过初始条件推导出新的烧结时间。虽然不涉及复杂的机理分析或创新设计，但需要将概念关联并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解溶解-沉淀机制下的烧结动力学关系，并能正确应用x/r与时间的关系公式（通常为立方关系）。解题需要两个关键步骤：1) 根据初始条件建立时间与x/r的关系；2) 利用立方关系计算新x/r对应的时间（0.2/0.1的立方倍）。虽然计算本身不复杂，但需要准确识别材料传输机制对应的动力学模型，并正确关联题目条件与理论公式。" + }, + { + "idx": 1777, + "question": "There is a green body with an initial particle size of 5μm. After sintering for 2h, x/r=0.1. If sintering proceeds until x/r=0.2 (without considering grain growth), what is the required sintering time when material transport is dominated by viscous flow?", + "answer": "8h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要基于给定的初始条件和物理关系（x/r与时间的关系）进行数值计算，最终得出一个具体的数值答案（8h）。解答过程涉及公式应用和数学推导，属于典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解烧结动力学中的基本公式（如x/r与时间的关系），并能够进行数值计算。虽然不需要复杂的机理分析或创新应用，但需要综合分析题目条件并应用正确的公式进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解烧结动力学中的关键概念（如x/r比值与时间的关系），并应用viscous flow主导的烧结模型进行两步计算（从初始状态到x/r=0.1，再推算到x/r=0.2的时间）。虽然不涉及多变量，但需要正确关联理论公式与实际问题，并进行指数关系的推导计算。" + }, + { + "idx": 1778, + "question": "There is a green body with an initial particle size of 5μm. After sintering for 2h, x/r=0.1. If sintering continues until x/r=0.2 (without considering grain growth), what is the required sintering time when the material transport is dominated by evaporation-condensation?", + "answer": "16h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要基于给定的初始条件和公式（x/r与时间的关系）进行数值计算，最终得出一个具体的数值答案（16h）。解答过程涉及材料科学中的烧结动力学和蒸发-凝聚机制的应用，属于典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解蒸发-凝聚机制下的烧结动力学方程，并应用x/r与时间的关系进行推导和计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的公式应用和数值计算能力。 | 难度: 在选择题中属于中等难度，需要理解烧结动力学中的蒸发-凝聚机制，并应用相关公式进行多步计算。题目要求从初始条件推导出新的烧结时间，涉及对x/r比例与时间关系的理解（通常为立方关系），需要进行两次计算步骤（先求比例系数再求新时间）。虽然计算本身不复杂，但需要正确关联材料科学原理和数学关系，属于典型的综合性计算问题。" + }, + { + "idx": 1779, + "question": "A green body has an initial particle size of 5μm. After sintering for 2h, x/r=0.1. If sintering proceeds until x/r=0.2 (without considering grain growth), what is the required sintering time when the process is driven by diffusion mass transfer?", + "answer": "64h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散传质驱动的烧结时间计算，答案是一个具体的数值（64h），符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解烧结过程中扩散质量传递的动力学关系，并能够将初始条件与目标条件关联起来进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解烧结动力学中的扩散质量传输模型（x/r与时间的关系），并应用平方关系（x/r∝t^(1/2)）进行两步计算：首先根据已知条件建立比例关系，然后推导新的时间值。虽然计算步骤明确，但需要正确关联概念和数学关系，且涉及指数运算（0.2/0.1的平方倍时间延长）。相比单纯的概念题或单步计算题，此题的综合性和计算要求更高，但未达到复杂多变量分析的等级4难度。" + }, + { + "idx": 1781, + "question": "Component defect", + "answer": "3. Component defect: In solid solutions with non-equivalent substitution, in order to maintain the electrical neutrality of the crystal, vacancies or interstitial ions are inevitably generated in the crystal. This type of crystal defect is called a component defect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"component defect\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对\"component defect\"这一基础概念的定义和基本原理的记忆和理解，属于材料科学中晶体缺陷的基础知识范畴，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆“component defect”的定义及其产生原因，涉及非等价替代、电中性维持、空位或间隙离子等基本概念。虽然需要一定的知识掌握深度，但不需要复杂的分析或比较，属于中等偏下的难度水平。" + }, + { + "idx": 1782, + "question": "Degrees of freedom in phase diagrams", + "answer": "Degrees of freedom in phase diagrams: In a phase equilibrium system, the independent variables that can be arbitrarily changed within a certain range without causing the disappearance of old phases or the formation of new phases are called degrees of freedom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“相图中的自由度”进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查相图中自由度这一基本概念的定义和解释，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"相图中的自由度\"这一基础概念的定义，但不需要进行复杂的分析或比较。正确选项直接给出了定义，属于中等难度的记忆性知识题目。" + }, + { + "idx": 1783, + "question": "Inverse spinel structure", + "answer": "Inverse spinel structure: It belongs to the cubic crystal system, where oxygen ions can be considered to be arranged in a cubic close-packed structure. Divalent cations A occupy octahedral sites, while trivalent cations B are half-filled in octahedral sites and half-filled in tetrahedral sites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Inverse spinel structure\"进行文字解释和论述，答案提供了详细的晶体结构描述，属于简答题类型。 | 知识层次: 题目考查对反尖晶石结构的基本定义和离子分布的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆反尖晶石结构的基本定义和组成，包括晶体系统、氧离子的排列方式以及不同价态阳离子的占位情况。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或比较，因此难度适中。" + }, + { + "idx": 1784, + "question": "Electrokinetic potential of clay colloids", + "answer": "Electrokinetic potential of clay colloids: When charged clay colloids are dispersed in water, a diffuse double layer forms at the interface between the colloidal particles and the liquid phase. The adsorption layer and the diffuse layer carry opposite charges, and the potential difference between them during relative movement is called the electrokinetic potential.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Electrokinetic potential of clay colloids\"进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对粘土胶体电动电势这一基本概念的定义和形成机理的理解，属于基础概念记忆和简单解释的范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述\"电动力学电位\"的形成机制及其相关概念（如扩散双电层、吸附层等）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。题目主要考察对概念的解释和描述能力，符合等级2的标准。" + }, + { + "idx": 1785, + "question": "Pb has a face-centered cubic structure with an atomic radius of 0.1750 nm. Calculate the volume of its unit cell.", + "answer": "V = a³ = (2√2r)³ = 0.1212 nm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用原子半径计算面心立方结构的晶胞体积）来得出具体数值结果，答案也是一个具体的计算结果。 | 知识层次: 题目考查基本公式应用和简单计算，直接套用面心立方结构的边长与原子半径关系公式（a = 2√2r）并进行立方计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（V = a³ = (2√2r)³）进行计算，无需额外的公式组合或复杂步骤。属于最基础的难度等级，适合考察学生对基本公式的理解和简单应用能力。" + }, + { + "idx": 1786, + "question": "The chemical composition of a glass is: 24mol% Na2O, 12mol% Al2O3, 64mol% SiO2. Calculate the four structural parameters Z, R, X, and Y of this glass.", + "answer": "Converted to 6Na2O·3Al2O3·16SiO2; Z=4; R=2.17; Y=3.66; X=0.34.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解四个结构参数（Z, R, X, Y），答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括将摩尔百分比转换为具体化学式，并应用结构参数公式进行计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃结构参数的计算方法，进行多步摩尔比转换和公式计算，并正确关联Z、R、X、Y四个参数的概念。虽然题目提供了正确选项，但需要考生具备将化学组成转换为标准形式（6Na2O·3Al2O3·16SiO2）的能力，并应用结构参数计算公式进行综合计算。" + }, + { + "idx": 1787, + "question": "The defect concentration of the non-stoichiometric compound TiO2-x is related to the nature and partial pressure of the surrounding atmosphere. When the oxygen partial pressure is increased, explain through calculation what changes will occur in the density of TiO2-x.", + "answer": "As the value of x in TiO2-x increases, its density decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算解释TiO2-x密度的变化，答案提供了文字解释和论述，而非数值计算或选择判断。 | 知识层次: 题目要求通过计算解释非化学计量化合物TiO2-x的缺陷浓度与周围气氛氧分压的关系，并分析密度变化。这涉及多步计算和概念关联，需要理解缺陷化学的基本原理，并能够将氧分压变化与缺陷浓度及材料密度变化联系起来。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于较高难度，需要理解非化学计量化合物TiO2-x的缺陷浓度与氧分压的关系，并通过计算分析密度变化。题目涉及多步计算、概念关联和综合分析，要求考生具备较强的应用能力和逻辑推理能力。" + }, + { + "idx": 1788, + "question": "In the manufacturing of Al2O3 ceramics, the particle size of the raw material is 2μm. After holding at the sintering temperature for 30min, the measured grain size is 10μm. What will be the grain size in μm after holding at the same sintering temperature for 2h?", + "answer": "d1=20μm(D2=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（D2=kt）来求解晶粒尺寸，答案是一个具体的数值结果（20μm），属于典型的计算题特征。 | 知识层次: 题目主要考查对晶粒生长公式（D²=kt）的直接应用和简单计算，仅需一步代入已知条件求解未知量，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了晶粒生长公式D²=kt，并且只需要简单代入已知条件进行计算即可得出答案。解题步骤非常直接，无需复杂的推理或多步骤计算，符合等级1的标准。" + }, + { + "idx": 1789, + "question": "The defect concentration of the non-stoichiometric compound Zn1+xO is related to the nature and partial pressure of the surrounding atmosphere. When the oxygen partial pressure is increased, explain through calculation what changes will occur in the density of Zn1+xO.", + "answer": "ZnO↔Zni+2e'+1/2O2; Zn1+xO; the concentration of zinc interstitial ions is inversely proportional to the oxygen partial pressure. When the oxygen partial pressure increases, the x value in Zn1+xO decreases, resulting in a reduction of its density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算解释Zn1+xO密度的变化，答案提供了详细的文字解释和化学反应方程式，但没有涉及具体的数值计算步骤，更侧重于概念和原理的论述。 | 知识层次: 题目需要理解非化学计量化合物Zn1+xO的缺陷浓度与周围气氛的关系，并通过化学反应方程式和浓度关系进行计算分析。这涉及到多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解非化学计量化合物Zn1+xO的缺陷浓度与周围气氛的关系，还需要通过计算分析氧分压变化对密度的影响。正确选项涉及多个概念（缺陷反应、浓度关系、密度变化）的综合分析，并需要将理论知识与实际计算相结合。这种多步骤、多角度的分析在选择题型中较为复杂，对考生的知识掌握深度和综合分析能力要求较高。" + }, + { + "idx": 1790, + "question": "To inhibit grain growth, 0.2% MgO was added to the raw powder, and the temperature was held for 2 hours at the same sintering temperature. What is the grain size in μm?", + "answer": "d2=16μm (D³=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式（D³=kt）和参数（d2=16μm）进行数值计算，以确定晶粒尺寸，属于典型的计算题。 | 知识层次: 题目涉及基本公式（D³=kt）的直接应用和简单计算，不需要多步推理或综合分析，属于对基本知识的直接运用。 | 难度: 在选择题型中，该题目仅需要直接套用给定的公式D³=kt进行计算，无需额外的公式组合或复杂推导。解题步骤简单，仅涉及基本公式的直接应用和简单计算，符合等级1的单一公式直接计算要求。" + }, + { + "idx": 1791, + "question": "Conditions necessary for mud peptization", + "answer": "① The medium must be alkaline, ② Monovalent alkali metal cations must exchange with the higher-valent ions originally adsorbed on the clay, ③ Polymerization of anions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出泥浆胶溶的必要条件，答案以文字解释和论述的形式给出，没有提供选项或需要计算，符合简答题的特征。 | 知识层次: 题目考查的是泥浆胶溶作用所需条件的基本概念记忆，包括碱性介质、单价碱金属阳离子交换和高价阴离子聚合等基本原理，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个条件（碱性介质、单价阳离子交换、阴离子聚合），但每个条件都是基础概念的直接应用，不需要复杂的推理或跨概念整合。学生只需准确记忆泥浆胶溶作用的三个必要条件即可作答，属于\"概念解释和描述\"层级。" + }, + { + "idx": 1792, + "question": "Structurally compare the arrangement of silicon-oxygen frameworks in silicate crystals and silicate glasses", + "answer": "In silicate crystals, the silicon-oxygen frameworks are arranged in an orderly manner according to certain symmetrical rules; in silicate glasses, the arrangement of silicon-oxygen frameworks is disordered.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对硅酸盐晶体和硅酸盐玻璃中硅氧骨架的排列进行结构比较，答案需要文字解释和论述，没有提供选项或要求判断对错，也不涉及数值计算。 | 知识层次: 题目主要考查对硅酸盐晶体和玻璃中硅氧骨架排列方式的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目要求考生理解和比较硅酸盐晶体和硅酸盐玻璃中硅氧骨架的排列方式。虽然涉及两个概念的比较，但知识点较为基础，属于定义和基本原理的记忆性知识。解题步骤相对简单，只需识别和区分两种材料的结构特征，无需复杂的分析或推理过程。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 1793, + "question": "Briefly describe the mechanism of slurry peptization", + "answer": "Due to the difference in electrical charges on the edge and face surfaces of plate-like clay particles, face-face, edge-face, or edge-edge associations occur, forming a certain structure in the slurry that increases flow resistance. The peptization process of the slurry involves breaking down this internal structure, transforming edge-face and edge-edge associations into face-face arrangements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述泥浆胶溶的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释浆体胶溶的机理，涉及对粘土颗粒表面电荷差异的理解，以及不同排列方式对浆体结构的影响。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解粘土颗粒表面电荷差异导致的微观结构变化，并能够解释浆体胶溶过程中结构转变的复杂机理。这需要考生具备综合运用材料科学、胶体化学知识的能力，以及对复杂现象进行全面分析的能力。正确选项涉及多个专业概念（如face-face/edge-face排列）和机理解释，远超选择题常见的简单识别或记忆层面，属于需要深度推理和综合分析的高阶题型。" + }, + { + "idx": 1794, + "question": "Structurally compare the distribution characteristics of extra-framework metal ions in silicate crystals and silicate glasses", + "answer": "In silicate crystals, the extra-framework metal ions occupy certain positions in the lattice; whereas in silicate glasses, the network-modifying ions are statistically distributed within the voids of the framework, balancing the negative charge of oxygen.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对硅酸盐晶体和硅酸盐玻璃中额外金属离子的分布特性进行结构性比较，需要文字解释和论述，答案也以文字形式呈现，符合简答题的特征。 | 知识层次: 题目要求对硅酸盐晶体和玻璃中金属离子的分布特性进行结构比较，涉及对两种材料结构的理解、概念关联和综合分析。虽然不涉及复杂计算，但需要对晶体和玻璃的结构特点有较深入的理解，并能进行对比分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较硅酸盐晶体和硅酸盐玻璃中金属离子的分布特征，涉及晶体结构和非晶态结构的知识，需要对两种材料的结构特点有清晰的认识，并能进行对比分析。虽然题目提供了正确选项，但需要考生具备一定的综合分析能力才能准确理解并选择正确答案。" + }, + { + "idx": 1795, + "question": "Compare the conditions for the substitution of extra-framework cations in silicate crystals and silicate glasses from a structural perspective", + "answer": "In silicate crystals, isomorphous substitution can only occur when the radius of the foreign cation is similar to that of the cation in the crystal; in silicate glasses, extra-framework cations can undergo substitution regardless of their radius, as long as electrical neutrality is maintained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从结构角度比较硅酸盐晶体和硅酸盐玻璃中额外骨架阳离子的取代条件，需要文字解释和论述，答案也以论述形式给出，符合简答题的特征。 | 知识层次: 题目要求从结构角度比较硅酸盐晶体和玻璃中额外骨架阳离子的取代条件，涉及对晶体和玻璃结构的深入理解，以及不同结构对阳离子取代的影响机制的分析。这需要综合运用材料科学中的结构知识，进行推理和解释，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1796, + "question": "Structurally compare the characteristics of oxide composition ratios in silicate crystals and silicate glasses", + "answer": "In crystals, the original components (oxides) have simple fixed quantitative ratios between each other; whereas in glasses, oxides are mixed in almost any proportion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对硅酸盐晶体和硅酸盐玻璃中氧化物组成比例的结构特征进行比较，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较硅酸盐晶体和玻璃中氧化物组成比例的结构特征，需要理解晶体和玻璃的结构差异，并能够关联不同材料状态下的组成特点。这涉及多步概念关联和综合分析，超出了单纯记忆基础概念的层次，但尚未达到需要复杂分析或创新应用的程度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较硅酸盐晶体和玻璃中氧化物组成比例的结构特征，涉及对晶体和玻璃结构的基本理解，以及它们在组成比例上的差异。虽然不需要复杂的计算，但需要对两种材料的结构特性有清晰的认识，并能进行综合分析。" + }, + { + "idx": 1798, + "question": "What are the diffusion coefficient, activation energy, and characteristics of intrinsic diffusion?", + "answer": "The activation energy of intrinsic diffusion consists of two parts: vacancy formation energy and particle migration energy, with intrinsic diffusion dominating at high temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释扩散系数、活化能和本征扩散的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释扩散系数、活化能和本征扩散的特性，涉及多个概念的关联和综合分析，需要理解本征扩散的机理及其与温度的关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及扩散系数、活化能以及本征扩散的特性，要求考生能够综合理解这些概念，并能够分析本征扩散在高温条件下的主导作用。虽然题目没有要求多步计算，但需要对概念进行关联和综合分析，因此在选择题型内属于中等难度。" + }, + { + "idx": 1799, + "question": "Briefly describe the difference between grain growth and secondary recrystallization", + "answer": "Grain growth is the continuous increase in average grain size, with uniform grain size growth, and pores remaining at grain boundaries or grain boundary intersections; secondary recrystallization is the abnormal growth of individual grains, with pores being trapped inside the grains. Secondary recrystallization is also related to the particle size of the raw material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述两种现象的区别，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目考查对晶粒生长和二次再结晶这两个基本概念的记忆和理解，主要涉及定义和基本特征的描述，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个概念的定义和比较，但正确选项已经提供了清晰的对比描述，不需要复杂的推理或分析。主要考察的是对基础概念的理解和记忆，属于概念解释和描述的层次。" + }, + { + "idx": 1800, + "question": "What are the diffusion coefficient, activation energy, and characteristics of extrinsic diffusion?", + "answer": "The activation energy of extrinsic diffusion only includes the migration energy of particles, and extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散系数、激活能和外在扩散的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对外在扩散（extrinsic diffusion）的基本概念和特性的记忆和理解，包括扩散系数、激活能及其在低温下的主导作用。这些内容属于材料科学中扩散现象的基础知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及扩散系数、激活能和外在扩散特性等基础概念，但正确选项需要考生理解外在扩散的激活能仅包括粒子迁移能，并且外在扩散在低温下占主导地位。这要求考生不仅记住定义，还需要理解概念之间的关系和应用场景。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 1802, + "question": "Discuss the grain growth process based on the limiting grain size", + "answer": "The grain growth process is briefly described.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论晶粒生长过程，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求基于限制晶粒尺寸讨论晶粒生长过程，这需要综合运用材料科学中的晶粒生长理论、热力学和动力学知识，进行推理分析和机理解释。涉及的知识点较为复杂，且需要将多个概念关联起来进行综合分析。 | 难度: 在选择题型中，该题目要求考生对晶粒生长过程有深入的理解，并能够基于限制晶粒尺寸进行综合分析和推理。这需要考生掌握复杂的材料科学知识，并能将这些知识应用于具体现象的解释。此外，题目要求考生进行机理深度解释和复杂现象的全面分析，这在选择题型中属于最高难度等级。" + }, + { + "idx": 1805, + "question": "What are grain growth and secondary recrystallization?", + "answer": "Grain growth is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution. Within the body, grain sizes grow uniformly, and during grain growth, pores remain at grain boundaries or their intersections. Secondary recrystallization is an abnormal growth process where a few large grains grow at the expense of fine grains, representing the abnormal growth of individual grains. During secondary recrystallization, pores become trapped inside the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"grain growth\"和\"secondary recrystallization\"这两个概念进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对晶粒生长和二次再结晶这两个基本概念的定义和特征的理解和记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述的难度等级。题目要求考生理解和记忆晶粒生长和二次再结晶的定义及其基本特征，虽然涉及两个概念，但都是基础性的定义描述，不需要复杂的分析或比较。正确选项提供了清晰的定义和关键特征，符合选择题型中对概念解释和描述的要求。" + }, + { + "idx": 1806, + "question": "In the orthorhombic system, the possible types of space lattices are a.P, I, C b.P, 1, F c.P, C, F d.P, F, 1, C", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案 | 知识层次: 题目考查对正交晶系可能的空间格子类型的基本概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生记住正交晶系中可能的空间格子类型。虽然需要记忆多个选项，但只需识别正确组合，无需复杂分析或深度理解。相对于等级1的直接记忆题目，该题需要简单辨析不同选项的差异，因此属于等级2难度。" + }, + { + "idx": 1807, + "question": "In the spinel (MgAl2O4) structure, O2- forms a cubic close packing, and Mg2+ ions fill a. 1/2 of the tetrahedral voids b. 1/2 of the octahedral voids c. 1/8 of the tetrahedral voids d. 1/8 of the octahedral voids", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案 | 知识层次: 题目考查对尖晶石结构中离子填充位置的基础概念记忆，属于对晶体结构基本知识的直接应用，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（spinel结构中离子的填充情况），但需要考生对立方紧密堆积中的四面体和八面体空隙有清晰的理解，并能区分不同离子填充的具体比例。这比单纯记忆定义（等级1）要求更高，但尚未达到需要复杂概念区分或深度理解的程度（等级3）。" + }, + { + "idx": 1808, + "question": "Kaolinite belongs to the layered silicate structure, and its structural feature is a. two-layer type trioctahedral structure b. three-layer type trioctahedral structure c. two-layer type dioctahedral structure d. three-layer type dioctahedral structure", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择关于高岭石结构特征的正确答案 | 知识层次: 题目考查对高岭石（Kaolinite）结构特征的基础概念记忆，属于对层状硅酸盐结构分类的基本知识点的直接考察。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生对高岭石的结构特征有清晰的理解，并能够区分两层型和三层型、三八面体和二八面体等专业术语。题目要求考生不仅记住高岭石属于二八面体结构，还要在四个相似选项中准确识别出正确描述。这比单纯的概念识别（等级1）要求更高，但尚未达到需要深度理解和复杂概念区分的等级3难度。" + }, + { + "idx": 1809, + "question": "In the non-stoichiometric compound Cd1+xO, the type of non-stoichiometric structural defect present is a. anion vacancy b. cation vacancy c. anion interstitial d. cation interstitial", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查非化学计量化合物中缺陷类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生识别非化学计量化合物Cd1+xO中的缺陷类型。虽然涉及特定缺陷类型的记忆（阳离子间隙），但不需要复杂的分析或概念间的比较，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 1810, + "question": "Among various layered silicate structures, the unit cell parameters that are similar are a.a0 and b0 b.a0 and c0 c.c0 and b0 d.c0", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案 | 知识层次: 题目考查对层状硅酸盐结构单元晶胞参数的基本概念记忆，只需识别相似参数即可，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别和回忆层状硅酸盐结构中单元晶胞参数的相似性。题目直接给出了正确选项，无需复杂辨析或深度理解，属于选择题型中最简单的难度等级。" + }, + { + "idx": 1812, + "question": "The viscosity corresponding to the glass transition temperature Tg is a.108dPa·s b.1010dPa·s c.1011dPa·s d.1013dPa·s", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对玻璃转变温度Tg对应粘度值的记忆，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆玻璃转变温度Tg对应的粘度数值即可选出正确答案。在选择题型中，这种仅需简单记忆的知识点属于最低难度等级。" + }, + { + "idx": 1814, + "question": "In the sintering process, the mass transfer method that only changes the pore shape without causing shrinkage of the green body is a. diffusion mass transfer b. flow mass transfer c. evaporation-condensation mass transfer d. grain boundary diffusion", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查烧结过程中质量传递方式的基本概念记忆，特别是蒸发-凝聚质量传递的特点，属于基础概念的记忆和理解。 | 难度: 该题目属于基础概念记忆层次，要求考生识别烧结过程中不同传质方式的特点。虽然需要理解蒸发-凝聚传质与其他传质方式的区别，但题目直接给出了关键特征（不引起收缩），属于概念理解和简单辨析的难度级别。在选择题型中，不需要复杂的分析过程，只需将特征与选项对应即可。" + }, + { + "idx": 1815, + "question": "Pauling's rules apply to (1)__ crystal structures.", + "answer": "(1) ionic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（ionic）来补全句子，属于需要简短文字回答的题目类型 | 知识层次: 题目考查对Pauling规则适用对象的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，此题仅考察对Pauling规则适用对象的基础记忆，属于最基础的定义简答级别。题目直接给出正确选项\"ionic\"，无需任何解释或分析步骤，完全依赖学生对基本概念的识记能力。" + }, + { + "idx": 1816, + "question": "In the phase diagram of a ternary condensed system, if there are n boundary lines, the number of connection lines in this phase diagram must be a. (n+1) lines b. (n-1) lines c. n lines d. none", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目涉及三元相图中边界线和连接线数量的关系，需要理解相图的基本原理并应用相关规则进行推理判断，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解三元相图中边界线与连接线的关系，并进行综合分析判断。题目涉及多步计算和概念关联，要求考生具备较强的相图分析能力和空间想象能力。虽然给出了具体选项，但需要考生对相图结构有深入理解才能正确选择。" + }, + { + "idx": 1817, + "question": "In the calculation of solid-state reactions, the Ginstling equation has a wider range of applicability than the Jander equation, and the biggest difference between the two is a. Different calculation methods b. The former is solved by the unstable diffusion equation c. Different geometric models", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案 | 知识层次: 题目考查对Ginstling方程和Jander方程区别的基础概念记忆，主要涉及两种方程的不同几何模型这一基本知识点，不需要复杂的应用或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解Ginstling方程和Jander方程的基本区别，并能够辨析两者在几何模型上的差异。虽然涉及两个方程的比较，但题目明确指出了\"最大的区别\"，降低了分析复杂度。" + }, + { + "idx": 1819, + "question": "The essence of a crystal is (2)", + "answer": "(2) Particles are arranged in a periodic repetition in three-dimensional space", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案明确对应选项(2) | 知识层次: 题目考查晶体本质的基本概念记忆，仅需理解晶体中粒子在三维空间周期性排列的定义，不涉及复杂分析或应用。 | 难度: 在选择题型中，此题属于基础概念记忆，仅需识别晶体本质的定义即可作答，无需复杂理解或分析。正确选项直接对应晶体结构的基本特征，属于简单概念识别层级。" + }, + { + "idx": 1820, + "question": "When selecting the unit parallelepiped of a space lattice, the primary principle is _ (3)", + "answer": "(3) The symmetry of the unit parallelepiped should conform to the symmetry of the entire space lattice", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个空格，答案是一个完整的句子解释，需要文字解释和论述，而不是从多个选项中选择或简单的对错判断或数值计算。 | 知识层次: 题目考查对空间晶格单位平行六面体选择原则的基本概念记忆和理解，属于晶体学基础原理的范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆并选择关于空间晶格单位平行六面体选择的基本原则。正确选项直接给出了定义性的陈述，无需进行复杂的分析或推理，符合等级1的基本定义简答难度标准。" + }, + { + "idx": 1821, + "question": "One of the conditions for clay slurry peptization is (6)", + "answer": "The medium is alkaline", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字简要回答粘土浆料胶溶的条件之一，答案是一个简短的陈述句，不需要选择、判断或计算 | 知识层次: 题目考查对粘土浆体胶溶条件的基本概念记忆，仅需回答介质为碱性这一基本条件，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆粘土浆料胶溶作用的条件之一（介质呈碱性）即可作答。题目不涉及概念解释或复杂体系分析，属于最简单的定义性知识考查。" + }, + { + "idx": 1822, + "question": "同质多晶现象是指 (4)", + "answer": "（4）chemical substances with the same composition form crystals with different structures under different thermodynamic conditions", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案是一个明确的选项（4），符合选择题的特征 | 知识层次: 题目考查对同质多晶现象这一基本概念的定义记忆和理解，属于材料科学中的基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然考察的是基础概念记忆，但\"同质多晶现象\"这一术语需要学生理解其定义并能够与选项中的描述进行匹配。题目要求学生对化学物质组成和晶体结构变化的关系有基本理解，而不仅仅是简单的术语识别。选项表述较为直接，但需要一定的概念辨析能力。" + }, + { + "idx": 1823, + "question": "A crystal with space group Fm3m has a (5)_ structure.", + "answer": "(5) face-centered cubic structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的晶体结构名称，需要根据空间群Fm3m的知识进行文字回答，而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查对晶体结构空间群Fm3m对应的具体结构类型的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目仅要求识别空间群Fm3m对应的晶体结构类型（面心立方），属于晶体学中最基础的空间群与结构对应关系记忆，无需解释或推导过程。选择题的正确选项直接提供了答案，考察的是对单一知识点的机械记忆能力，在选择题难度谱系中属于最低层级。" + }, + { + "idx": 1824, + "question": "Glass has the following general properties: (12)", + "answer": "Isotropic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求提供一个简短的文字答案（\"Isotropic\"）来描述玻璃的一般性质，而不是从多个选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查玻璃的一般性质，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对玻璃基本属性的记忆性知识（各向同性），属于最基础的定义简答层次，无需复杂推理或概念比较。" + }, + { + "idx": 1825, + "question": "One of the conditions for the peptization of clay slurry is (8)", + "answer": "Polymerization of anions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释粘土浆料胶溶的条件之一，答案需要提供文字解释而非选择或判断 | 知识层次: 题目考查对粘土浆体胶溶条件的基本概念记忆，只需要回忆和陈述\"阴离子聚合\"这一条件即可，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆粘土浆体胶溶作用的条件之一即可。题目直接给出正确选项，无需复杂推理或概念比较，符合等级1的基本定义简答要求。" + }, + { + "idx": 1826, + "question": "What type of diffusion problem does Fick's first law apply to?", + "answer": "Steady-state diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述Fick's第一定律适用的扩散问题类型，答案\"Steady-state diffusion\"是一个简短的文字回答，不需要计算或选择选项。 | 知识层次: 题目考查Fick第一定律适用的扩散类型，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对Fick第一定律适用条件的基础定义记忆，属于最基础的概念性知识。学生只需识别\"稳态扩散\"这一关键词即可作答，无需任何解释或分析步骤，因此属于难度等级1。" + }, + { + "idx": 1827, + "question": "What type of diffusion problems is Fick's second law applicable to solve?", + "answer": "Non-steady-state diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释Fick's second law适用的扩散问题类型，答案是一个简短的文字描述而非选择、判断或计算 | 知识层次: 题目考查对Fick第二定律适用范围的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求考生记忆并识别Fick's第二定律适用的扩散类型（非稳态扩散），属于基础概念的直接回忆。题目不涉及概念解释或复杂体系分析，仅需从选项中选出正确的基本定义，因此属于最简单的难度等级。" + }, + { + "idx": 1828, + "question": "One of the conditions for the peptization of clay slurry is (7)", + "answer": "Exchange of original cations with monovalent alkali metal cations", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释粘土浆体胶溶的条件之一，答案是一个具体的解释性陈述，而不是从多个选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查粘土浆料胶溶作用的基本条件，属于基本原理的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生理解粘土浆体胶溶的条件之一，即原始阳离子与单价碱金属阳离子的交换。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 1829, + "question": "The vacancy mechanism of diffusion refers to (11)", + "answer": "(11) When vacancies exist in the lattice, the diffusion mode of mass points mediated by vacancy migration", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对空缺扩散机制进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即空位扩散机制的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对\"空位扩散机制\"这一基础概念的定义记忆，属于最基础的知识点复现。题目直接给出定义描述作为正确选项，不需要任何解释、比较或分析过程，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1830, + "question": "Glass has the following general properties: (13)", + "answer": "Metastability", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对玻璃的一般性质进行描述，答案\"Metastability\"是一个需要解释和论述的概念，而不是简单的选择或判断。 | 知识层次: 题目考查对玻璃基本性质（亚稳态）的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅考察对玻璃基本性质\"Metastability\"这一基础概念的简单记忆和识别，属于最基础的定义简答类型。题目无需解释或分析，只需选择正确术语，符合等级1的基本定义简答标准。" + }, + { + "idx": 1831, + "question": "Glass has the following general properties: (14)", + "answer": "The transformation process is reversible and gradual", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对玻璃的一般性质进行描述，答案是一个陈述句，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查玻璃的一般性质，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对玻璃一般特性的基础概念记忆，正确选项直接对应教材中的基本定义（玻璃转变过程的可逆性和渐进性特征）。选择题型中无需复杂推理或概念关联，只需识别并选择与记忆内容匹配的选项即可，属于最基础层级的认知要求。" + }, + { + "idx": 1832, + "question": "What is the migration of particles caused by intrinsic diffusion?", + "answer": "Vacancies generated by intrinsic thermal defects", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释粒子迁移的原因，答案是以文字形式给出的解释性回答，不需要计算或选择，符合简答题的特征 | 知识层次: 题目考查对\"本征扩散\"这一基础概念的理解，需要记忆本征扩散是由本征热缺陷产生的空位迁移这一基本原理，属于材料科学中扩散机制的基础知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"本征扩散引起的粒子迁移\"的定义。正确选项直接对应基础概念，不需要解释或分析过程，属于最简单的定义性记忆题目。" + }, + { + "idx": 1833, + "question": "Glass has the following general properties: (15)", + "answer": "Continuous change in properties during transformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述玻璃的一般性质，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查玻璃的一般性质，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题型中，此题仅考察对玻璃基本特性的记忆，属于最基础的定义性知识。题目直接给出正确选项\"Continuous change in properties during transformation\"，不需要任何概念解释或复杂分析，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1834, + "question": "What are the two components of the activation energy for intrinsic diffusion?", + "answer": "Vacancy formation energy and particle migration energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举激活能的两个组成部分，答案以文字形式给出，不需要计算或选择 | 知识层次: 题目考查对激活能组成部分的基础概念记忆，仅需回答两个关键术语，无需深入分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即激活能的两个组成部分。学生只需回忆并识别\"空位形成能\"和\"粒子迁移能\"这两个术语即可作答，无需进行概念解释或复杂分析。这属于最基本的概念记忆题，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1835, + "question": "What factors primarily determine the concentration of component defects?", + "answer": "Doping amount", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释决定组分缺陷浓度的主要因素，需要文字解释和论述，而不是从选项中选择或简单判断对错 | 知识层次: 题目考查的是对组分缺陷浓度决定因素的基本概念记忆，属于基础概念的理解和记忆范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对\"component defects浓度主要决定因素\"这一基础概念的记忆，属于最基础的定义简答级别。正确选项\"Doping amount\"是材料科学中的基本知识点，不需要任何解释或分析步骤，只需直接回忆相关定义即可作答。" + }, + { + "idx": 1837, + "question": "What is the relationship between the diffusion coefficient of intrinsic diffusion and temperature?", + "answer": "D=D0exp(-(ΔHf/2 + ΔHm)/RT)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散系数与温度之间的关系，答案给出了具体的数学表达式，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求解释扩散系数与温度的关系，并给出具体的公式。这需要理解扩散机制（ΔHf和ΔHm的含义）以及阿伦尼乌斯方程的应用，属于多步概念关联和综合分析。虽然不涉及复杂的推理或创新，但超出了简单记忆或直接套用公式的层次。 | 难度: 在选择题中属于较高难度，需要理解扩散系数与温度的关系，并掌握阿伦尼乌斯方程的应用。题目涉及多个概念（ΔHf、ΔHm、R、T）的综合分析，以及多步计算（指数运算和参数组合）。此外，需要将扩散机制与热力学参数关联起来，这在选择题型中属于较复杂的综合分析要求。" + }, + { + "idx": 1838, + "question": "What factors does the concentration of component defects mainly depend on?", + "answer": "Solid solubility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释影响组分缺陷浓度的主要因素，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查的是对组分缺陷浓度主要依赖因素的基本概念记忆，即固溶度（solid solubility），属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，要求考生回忆\"组分缺陷浓度主要取决于什么\"这一简单定义。正确选项\"固溶度\"是材料科学中的基本术语，无需复杂推理或概念比较，属于最基础的定义简答级别。" + }, + { + "idx": 1839, + "question": "What are the four main mass transfer mechanisms in sintering?", + "answer": "(23) Evaporation-condensation mass transfer; (24) Diffusion mass transfer; (25) Flow mass transfer; (26) Dissolution-precipitation mass transfer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举烧结过程中的四种主要传质机制，答案以简短的文字形式给出，不需要选择或判断，属于简答题类型。 | 知识层次: 题目考查烧结过程中四种主要传质机制的记忆和理解，属于基础概念的分类和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求识别和记忆烧结过程中的四种主要传质机制，不需要解释或比较这些机制。正确选项直接对应基础概念记忆层次的知识点，解题步骤简单，只需回忆和匹配选项即可完成。" + }, + { + "idx": 1840, + "question": "What is the relationship between △L/L and sintering time in the mass transfer process?", + "answer": "(29) △L/L∝t", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释△L/L与烧结时间之间的关系，答案需要文字描述和论述，而非简单的选择、判断或计算。 | 知识层次: 题目涉及烧结过程中质量传递的基本关系，需要理解△L/L与时间t的关系，并应用相应的公式或原理进行解释。这属于中等应用层次，因为它需要将概念与公式关联起来，并进行一定的综合分析。 | 难度: 在选择题中属于中等难度，需要理解烧结过程中的质量传递概念，并能将△L/L与时间t的关系进行综合分析。题目要求考生掌握中等应用层次的知识，包括多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1841, + "question": "What is the relationship between △L/L and sintering time in the evaporation-condensation mass transfer process?", + "answer": "(27) △L/L=0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目询问的是烧结过程中△L/L与时间的关系，需要解释蒸发-凝聚传质过程中的变化规律。答案虽然给出了一个具体值，但实际需要论述整个关系变化过程，属于需要文字解释的简答题类型。 | 知识层次: 题目涉及蒸发-凝聚传质过程中烧结时间与尺寸变化的关系，需要理解该过程的机理并应用相关概念进行分析，属于中等应用层次。虽然答案简单，但需要一定的背景知识来理解为什么△L/L=0。 | 难度: 在选择题中属于中等难度，需要理解蒸发-凝聚传质过程的基本原理，并能够将烧结时间与尺寸变化率(△L/L)的关系进行综合分析。题目涉及中等应用层次的知识，要求考生将多个概念关联起来，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 1842, + "question": "What is the relationship between △L/L and sintering time in the dissolution-precipitation mass transfer process?", + "answer": "(30) △L/L∝t^(1/3)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释烧结时间与△L/L之间的关系，答案是一个数学表达式，需要简要说明其物理意义，属于需要文字解释的简答题类型。 | 知识层次: 题目涉及溶解-沉淀传质过程中烧结时间与长度变化的关系，需要理解并应用相关公式（△L/L∝t^(1/3)），属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解溶解-沉淀传质过程的基本原理，并能将烧结时间与尺寸变化关系进行综合分析。题目要求考生掌握△L/L与时间t的1/3次方关系这一特定知识点，并能在选项中进行正确识别。虽然不涉及多步计算，但需要对烧结动力学有较好的概念理解。" + }, + { + "idx": 1847, + "question": "Connection rule", + "answer": "Connection rule: In a ternary system, if the boundary (or its extension) between two adjacent phase regions (primary crystallization regions) intersects with the corresponding connecting line (or its extension), then this intersection point is the temperature maximum on that boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释\"Connection rule\"的定义和条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求理解和应用三元系统中的连接规则，涉及相区边界和连接线的交点判断，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解三元系统中的相边界规则、连接线概念以及温度极值点的判定条件。题目要求将多个概念关联起来进行分析，但不需要进行复杂的多角度论述或深度关联性分析。" + }, + { + "idx": 1849, + "question": "Sintering", + "answer": "Sintering: A process in which one or more solid powders are formed and then heated to a certain temperature, causing them to shrink and become a dense, hard sintered body below the melting point temperature. Alternatively: Due to the mutual attraction of molecules (or atoms) in solids, heating causes the powder particles to bond, and through material migration and diffusion, the powder gains strength, leading to densification and recrystallization—this process is called sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Sintering\"这一概念进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查烧结过程的基本定义和原理，属于基础概念的记忆和理解，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解和记忆烧结的基本定义和过程，虽然涉及一定的细节描述（如粉末颗粒的粘结、材料迁移和扩散等），但整体上仍属于对单一概念的明确解释，不需要进行复杂的概念体系阐述或多概念比较分析。" + }, + { + "idx": 1850, + "question": "To inhibit grain growth, 0.1% grain growth inhibitor is added. If the holding time is also 2h, what is the grain size?", + "answer": "d2=16μm(D3=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式（d2=16μm(D3=kt)）和条件（0.1% grain growth inhibitor, 2h holding time）进行数值计算，得出具体的晶粒尺寸（grain size）。解答过程涉及公式应用和数值计算，属于典型的计算题。 | 知识层次: 题目主要考查基本公式的直接应用（D3=kt）和简单计算，不需要多步推导或综合分析，属于对基本知识的直接运用。 | 难度: 在选择题型中，该题目仅需要直接套用给定的公式（d2=16μm(D3=kt)）进行计算，无需额外的步骤或复杂的思考过程。属于单一公式直接计算的简单应用层次，因此难度等级为1。" + }, + { + "idx": 1851, + "question": "Calculate the four structural parameters Z, R, X, and Y of the glass Na2O·CaO·Al2O3·2SiO2", + "answer": "1.Z=4; R=9/4=2.25; X=0.5; Y=3.5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算四个结构参数Z、R、X和Y的具体数值，答案也是以数值形式给出，符合计算题的特征。 | 知识层次: 题目要求计算玻璃的四个结构参数（Z, R, X, Y），这需要理解玻璃结构参数的定义和计算方法，并应用相关公式进行多步计算。虽然计算本身不复杂，但需要对玻璃结构化学有较好的理解，并能正确关联和综合应用这些概念。这超出了简单应用的范围，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃结构参数的计算方法，掌握Z、R、X、Y的定义和相互关系，并能正确应用公式进行多步计算。题目涉及多个概念的综合运用和计算步骤的衔接，但选项提供了计算结果，降低了部分难度。" + }, + { + "idx": 1852, + "question": "Write the solid solution formula corresponding to 20mol% YF3 doped into CaF2", + "answer": "Ca0.8Y0.2F2.2, Ca0.7Y0.2F2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出固溶体的化学式，需要根据掺杂比例进行推导和书写，属于需要文字解释和论述的简答题类型。答案给出了具体的化学式，而不是选择或判断。 | 知识层次: 题目需要理解固溶体的概念，并能够进行多步计算来确定掺杂后的化学式。这涉及到对掺杂比例的理解和化学式的调整，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解固溶体的化学式书写规则，进行摩尔百分比的计算，并正确应用电荷平衡原理。解题步骤涉及多步计算和概念关联，但选项数量有限降低了部分难度。" + }, + { + "idx": 1853, + "question": "From the perspective of crystal chemistry, discuss the rationality of the defect reaction equation for doping 20mol% YF3 into CaF2", + "answer": "From the viewpoint of crystal chemistry, the substitution of Y3+ for Ca2+ will generate cation vacancies or interstitial fluoride ions to maintain electrical neutrality, both of these defect reactions are reasonable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从晶体化学角度讨论掺杂缺陷反应方程的合理性，需要文字解释和论述，答案也提供了详细的文字解释而非计算或选择。 | 知识层次: 题目要求从晶体化学的角度讨论掺杂YF3到CaF2中的缺陷反应方程的合理性，涉及离子取代、电荷平衡和缺陷类型的综合分析，需要深入理解晶体化学原理并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 1854, + "question": "Try to write the defect reaction equation for 20mol% YF3 doped into CaF2", + "answer": "2.YF3→CaF2YCa*+Fi'+2FF, 2YF3→CaF22YCa*+VCa''+6FF", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字解释和论述，答案形式为化学反应方程式，属于简答题类型。 | 知识层次: 题目要求写出掺杂缺陷反应方程，需要理解缺陷化学的基本原理，并能够将YF3掺杂到CaF2中的具体情况进行应用。这涉及到多步思考和概念关联，如电荷平衡、缺陷符号表示等，但不需要过于复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解缺陷反应方程的基本概念，并能够正确应用掺杂和缺陷形成的原理。题目要求写出20mol% YF3掺杂到CaF2中的缺陷反应方程，这涉及到对掺杂剂引入的缺陷类型（如间隙离子、空位等）的综合分析，以及电荷平衡的考虑。虽然题目提供了正确选项，但学生需要具备一定的材料科学基础，能够理解并正确写出多步缺陷反应方程，这属于中等应用层次的知识要求。" + }, + { + "idx": 1855, + "question": "A certain powder compact has an average particle size of 2μm. After sintering to the highest temperature and holding for 0.5h, the measured grain size is 10μm. If the holding time is extended to 2h, what will the grain size be?", + "answer": "d1=20μm(D2=kt)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过公式计算得出最终结果，涉及数值计算和公式应用（D2=kt），答案以具体数值形式给出。 | 知识层次: 题目需要进行多步计算，涉及晶粒生长动力学公式的应用（D²=kt），需要理解时间与晶粒尺寸的关系，并进行数值计算。虽然公式直接给出，但需要正确理解和应用公式来解决问题，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解晶粒生长动力学方程（D2=kt）的概念，并进行两步计算（首先根据已知条件计算k值，然后应用该值计算新的晶粒尺寸）。虽然计算步骤明确，但需要将理论知识与实际数据关联，并正确应用公式。" + }, + { + "idx": 1856, + "question": "Give two examples of forming continuous substitutional solid solutions", + "answer": "PbTiO3-PbZrO3, albite-orthoclase, MgO-NiO, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出两个连续置换固溶体的例子，答案需要列举具体的材料组合，属于需要文字回答的简答题类型。 | 知识层次: 题目考查对连续置换固溶体基本概念的记忆和理解，只需列举典型例子，不需要深入分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目要求列举两个形成连续置换固溶体的例子，这只需要学生对相关基础概念的记忆，无需深入解释或分析。正确选项直接提供了几个常见的例子，学生只需识别或回忆这些例子即可作答，解题步骤简单，对知识点掌握深度的要求较低。" + }, + { + "idx": 1857, + "question": "For an AB-type compound crystal with a face-centered cubic structure, the molecular weight of the AB compound is 26, and its measured density is 2.6g/cm3. Based on this, calculate the unit cell parameter of the AB crystal.", + "answer": "The number of formula units per unit cell Z=4, the number of AB molecules in 1mol is 2.6/26×N0=6.02×1022; the number of unit cells=6.02/4×1022=1.5×1022; 1.5×1022V=1.5×1022a3=1021nm3, thus a=0.41nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶胞参数，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括分子量、密度、单位晶胞参数的计算，并需要理解面心立方结构的基本概念和公式应用。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行计算。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及面心立方结构、分子量、密度和晶胞参数的计算，需要综合运用这些概念进行多步计算。虽然题目提供了正确选项，但解题过程需要理解并关联多个知识点，如公式单位数、摩尔质量、阿伏伽德罗常数等，并进行适当的单位转换和数学运算。这种复杂性在选择题中属于中等偏上的难度。" + }, + { + "idx": 1859, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, how many octahedral voids are there?", + "answer": "There are a total of 4 octahedral voids in the NaCl unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求回答一个具体的问题，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对晶体结构中八面体空隙数量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（NaCl晶胞中的八面体空隙数量），但需要学生对面心立方紧密堆积结构有清晰的理解，并能准确计算空隙数量。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 1860, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, how many tetrahedral voids are there?", + "answer": "There are a total of 8 tetrahedral voids in the NaCl unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述在NaCl单位晶胞中的四面体空隙数量，答案提供了具体的文字解释和数量，没有涉及计算或选择。 | 知识层次: 题目考查对NaCl晶胞中四面体空隙数量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要学生对面心立方紧密堆积结构中的空隙类型和数量有清晰的理解。学生需要知道NaCl晶胞的结构特点，并能够准确记忆或推导出四面体空隙的数量。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 1861, + "question": "What is martensitic transformation?", + "answer": "Martensitic transformation refers to a phase transformation that occurs at an extremely rapid speed through the shear of a discrete volume of a crystal under the action of external stress. Martensitic transformation is one of the basic forms of solid-state phase transformations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“马氏体转变”进行定义和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即马氏体相变的定义和基本特征，属于基础概念记忆层次。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。题目要求考生理解并记忆马氏体相变的基本定义和特征，虽然涉及专业术语和基本原理，但不需要进行复杂的比较分析或多概念整合。在选择题型中，这属于中等偏下的难度，主要考察基础概念的记忆和理解能力。" + }, + { + "idx": 1862, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, where are the tetrahedral void positions located?", + "answer": "In the NaCl unit cell, the tetrahedral voids are located along the body diagonal direction of the unit cell. They are formed by the corner Cl- ions and the point Cl- ions in the three adjacent edges, constituting the tetrahedral voids, which are also the centers of the 8 small cubes. There are a total of 8 tetrahedral voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释NaCl晶胞中四面体空隙的位置，答案提供了详细的文字描述和位置说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对NaCl晶胞中四面体空隙位置的基本概念记忆和理解，属于晶体结构的基础知识范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体结构中的四面体空隙位置这一基础概念，但需要考生对NaCl晶胞结构有清晰的空间想象能力，并能准确描述四面体空隙的位置和形成方式。题目不仅考察了基础定义记忆，还要求考生能够将抽象的空间几何概念与具体的晶体结构对应起来，属于概念解释和描述的难度层次。" + }, + { + "idx": 1863, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, where are the octahedral void positions located?", + "answer": "In the NaCl structure, Cl- forms a face-centered cubic close packing, and Na+ occupies all the octahedral voids. The positions of the octahedral voids include one at the center of the unit cell, and the midpoint of each edge is also an octahedral void position, totaling 12. The number of such voids belonging to this unit cell is 12 × 1/4 = 3. Therefore, there are a total of 4 octahedral voids in the NaCl unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述NaCl单位晶胞中八面体空隙的位置，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要理解面心立方紧密堆积结构和八面体空隙的基本概念，还需要分析NaCl晶胞中八面体空隙的具体位置和数量计算，涉及多步推理和概念关联。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生理解面心立方密堆积结构的基本概念，还需要掌握八面体空隙的位置分布和计算方法。解题步骤涉及多个概念的综合运用（如单位晶胞、配位数、空隙计算等），并需要进行多步逻辑推理和计算（12个边中点空隙的归属计算）。这种题目在选择题中属于需要多角度分析论述的类型，超出了单纯记忆或简单应用层面。" + }, + { + "idx": 1864, + "question": "Briefly describe the crystallographic characteristics of martensitic transformation.", + "answer": "The crystallographic characteristics of martensitic transformation include: a strict orientation relationship between the new phase and the parent phase during the transformation, maintenance of a coherent relationship through shear, the presence of a habit plane that remains undistorted and unrotated before and after the transformation, and macroscopic continuity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体相变的晶体学特征，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求描述马氏体相变的晶体学特征，涉及多个复杂概念的关联和综合分析，包括新相与母相的取向关系、剪切保持的相干关系、习惯面的不变性以及宏观连续性等。这需要深入理解相变机理和晶体学原理，并进行推理分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用多个复杂概念（如取向关系、共格关系、惯习面等），并理解马氏体相变的晶体学机理。正确选项涉及对相变过程中微观结构和宏观现象的全面分析，需要考生具备深度推理和机理解释能力。这种综合性的知识运用和复杂现象分析在选择题中属于最高难度水平。" + }, + { + "idx": 1865, + "question": "What is grain growth?", + "answer": "Grain growth is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution. Within the bulk, grain sizes grow uniformly, and pores remain at grain boundaries or grain boundary junctions during grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"grain growth\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对晶粒生长这一基本概念的定义和简单描述，主要依赖记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度。虽然题目要求记忆和理解\"grain growth\"的定义和特征，但不需要进行复杂的概念比较或体系阐述。正确选项提供了完整的定义和过程描述，属于中等难度的概念性选择题。" + }, + { + "idx": 1866, + "question": "What causes secondary recrystallization?", + "answer": "The causes of secondary recrystallization: uneven particle size of the raw material, excessively high sintering temperature, and too fast sintering rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释二次再结晶的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解二次再结晶的机理，并分析其影响因素，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及的知识点包括二次再结晶的原因，需要考生掌握材料科学中关于烧结过程的基本概念，并能将不均匀的原料颗粒尺寸、过高的烧结温度和过快的烧结速率这些因素与二次再结晶现象联系起来。虽然不需要进行复杂的计算，但需要对概念有一定的综合理解能力。" + }, + { + "idx": 1867, + "question": "What are the methods to prevent secondary recrystallization?", + "answer": "Methods to prevent secondary recrystallization: control sintering temperature, sintering time, control the uniformity of raw material particle size, introduce sintering additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举防止二次再结晶的方法，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目要求列举防止二次再结晶的方法，涉及对烧结温度、时间、原料粒径均匀性和烧结添加剂等多个因素的综合考虑，需要将多个概念关联起来进行分析和应用，但不需要深入机理解释或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求掌握防止二次再结晶的方法，涉及控制烧结温度、烧结时间、原料颗粒均匀性以及引入烧结添加剂等多个知识点。虽然不需要复杂的计算，但需要对材料科学中的再结晶现象有较深的理解，并能综合分析不同因素对二次再结晶的影响。" + }, + { + "idx": 1868, + "question": "What is secondary recrystallization?", + "answer": "Secondary recrystallization is an abnormal growth process where a few large grains grow at the expense of fine grains, representing the abnormal growth of individual grains. During secondary recrystallization, pores are enclosed within the grains, and it is also related to the particle size of the raw material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary recrystallization\"进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对二次再结晶这一基础概念的定义和基本特征的理解，属于记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆二次再结晶的定义及其特征，包括异常晶粒生长过程、孔隙被包裹在晶粒内以及与原料颗粒尺寸的关系。虽然涉及多个知识点，但都属于基础概念的记忆和理解范畴，不需要复杂的分析或比较。因此，难度适中，属于等级2。" + }, + { + "idx": 1869, + "question": "Among the seven crystal systems, the number of crystal systems belonging to the highest crystal category is A.1 B.2 C.3 D.4", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案 | 知识层次: 题目考查对晶体系统分类的基础概念记忆，属于对晶体学基本分类体系的直接考察，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆七种晶系中最高晶系的分类数量，无需复杂辨析或深度理解。题目直接给出明确选项，解题步骤简单，属于最基础的难度等级。" + }, + { + "idx": 1870, + "question": "The crystal structure with point group L6L27PC belongs to the crystal system. A. Cubic B. Hexagonal C. Tetragonal D. Orthorhombic", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体结构点群和晶系分类的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对晶体结构和点群分类有一定的理解和辨析能力。具体来说，考生需要知道L6L27PC对应的晶体系统是Hexagonal，这不仅仅是对定义的简单记忆，还需要对点群符号和晶体系统之间的关系有一定的理解。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1871, + "question": "Kaolinite belongs to the silicate of . A. Chain structure B. Layered structure C. Framework structure D. Island structure", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对高岭石（Kaolinite）所属硅酸盐结构类型的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，此题属于简单概念识别，直接记忆类型。题目直接考察高岭石属于哪种硅酸盐结构，只需记住高岭石属于层状结构即可作答，无需进行概念辨析或复杂分析。" + }, + { + "idx": 1872, + "question": "The crystal structure of diamond is , and the coordination number of carbon atoms is A. face-centered cubic lattice B. simple cubic lattice C. body-centered cubic lattice D. 3 E. 4 F. 6 G. 8", + "answer": "A, E", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案由多个选项组成（A, E），符合选择题的特征。 | 知识层次: 题目考查对金刚石晶体结构和碳原子配位数的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆钻石的晶体结构（面心立方格子）和碳原子的配位数（4）。在选择题型中，这种直接记忆的知识点属于最简单的难度等级，不需要进行概念辨析或深度理解。" + }, + { + "idx": 1873, + "question": "Most solid-phase reactions fall into A. Chemical reaction kinetics range B. Diffusion kinetics range C. Transition range", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查对固相反应动力学范围的基本分类记忆，属于基础概念的记忆和理解层面，不需要复杂的分析或应用过程。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需识别\"Most solid-phase reactions\"的分类归属。题目直接考察对固相反应动力学范围的基本定义记忆，无需复杂辨析或深度理解。正确选项B（Diffusion kinetics range）是教材中明确指出的标准答案，属于简单概念识别层级。" + }, + { + "idx": 1874, + "question": "When water-based substances melt into a liquid state, their volume undergoes the phenomenon of . A. expansion B. contraction C. no change", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查水基物质熔化时体积变化的基本现象记忆，属于基础概念的记忆和理解范畴 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即水基物质在融化时体积变化的现象。学生只需记住\"水基物质融化时体积收缩\"这一基本事实即可正确作答，无需进行概念辨析或深度理解。题目选项简单明确，属于直接记忆性知识，因此难度等级为1。" + }, + { + "idx": 1875, + "question": "At low temperatures, the diffusion that generally occurs in solid materials is A. Intrinsic diffusion B. Extrinsic diffusion C. Random diffusion", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查对固体材料中扩散类型的基本概念记忆和理解，特别是低温条件下扩散类型的分类知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生区分不同扩散类型的定义。虽然需要理解\"低温下固体材料中通常发生的扩散类型\"这一知识点，但选项之间的区分度较为明显（本征扩散、非本征扩散、随机扩散），属于概念理解和简单辨析的难度层级。不需要复杂的分析过程，只需掌握基础定义即可正确作答。" + }, + { + "idx": 1876, + "question": "Among the following types of crystals, the order of forming interstitial solid solutions is A. zeolite > CaF2 > TiO2 > MgO B. MgO > TiO2 > CaF2 > zeolite C. CaF2 > TiO2 > MgO > zeolite D. TiO2 > MgO > CaF2 > zeolite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的顺序，属于选择题类型 | 知识层次: 题目考查对晶体间隙固溶体形成顺序的基础概念记忆，属于对基本原理和分类的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，主要考察对晶体形成间隙固溶体顺序的记忆。虽然需要记住四种晶体的具体顺序，但不需要复杂的分析或推理过程。在选择题型中，这属于需要简单概念理解和记忆的题目，难度适中。" + }, + { + "idx": 1877, + "question": "Substances that easily form glass often have bond types such as . A. Ionic bond B. Metallic bond C. Polar covalent bond D. Covalent bond", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对玻璃形成物质键型的基础概念记忆和理解，属于基本原理的记忆性知识 | 难度: 该题目属于基础概念记忆层次，但需要考生理解不同化学键类型的特点及其与玻璃形成能力的关系。虽然选项都是常见的化学键类型，但需要考生能够区分极性共价键与其他键型的区别，并理解其在玻璃形成中的特殊作用。这比单纯记忆定义(等级1)要求更高，但尚未达到需要复杂概念区分(等级3)的程度。" + }, + { + "idx": 1878, + "question": "The viscosity corresponding to the glass transition temperature Tf is A.105dPa·s B.109dPa·s C.1011dPa·s D.1013dPa·s", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择与玻璃转变温度Tf对应的粘度值，属于典型的选择题形式 | 知识层次: 题目考查对玻璃转变温度对应粘度值的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅需记忆玻璃转变温度对应的粘度值即可选出正确答案，属于基础概念的直接记忆，无需复杂理解或分析。" + }, + { + "idx": 1879, + "question": "When a small amount of CaO is doped into ThO2, write the possible defect reaction equation (7)", + "answer": "7) CaO → CaTh'' + O0 + V0''", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出可能的缺陷反应方程，需要文字解释和论述，而不是从选项中选择或判断对错或进行数值计算。 | 知识层次: 题目要求写出掺杂CaO到ThO2中的缺陷反应方程，这需要理解缺陷化学的基本原理，并能够应用这些原理来分析具体的掺杂情况。虽然不涉及复杂的计算或多步推理，但需要对缺陷类型和符号表示有一定的理解，并能够正确应用这些知识来写出反应方程。这属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解掺杂反应的基本原理，掌握缺陷化学符号的表示方法，并能正确写出缺陷反应方程式。虽然题目涉及的知识点较为专业，但在选择题型中，通过选项的提示可以辅助判断，降低了部分难度。" + }, + { + "idx": 1880, + "question": "Under the same system and the same degree of supercooling, the heterogeneous nucleation rate is always the homogeneous nucleation rate. A. Greater than or equal to B. Less than or equal to C. Equal to D. Not necessarily", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查的是对均相成核和非均相成核速率比较的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察的是对异质成核和均质成核速率关系的直接记忆。虽然需要理解\"相同系统和相同过冷度\"条件下的比较关系，但选项提供了明确的对比方向（A选项直接给出了正确关系），不需要复杂的分析或推导。因此属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 1881, + "question": "How many space groups can appear in crystal structures?", + "answer": "230", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目询问晶体结构中可能出现的空间群数量，答案是一个具体的数字（230），不需要计算过程或选择选项，属于需要直接回答的简答题类型。 | 知识层次: 题目考查对晶体结构中空间群数量的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即晶体结构中可能出现的空间群数量。不需要任何解释、分析或复杂推理，只需直接回忆并选择正确数字230。这符合等级1\"基本定义简答\"的标准，是最简单的选择题难度类型。" + }, + { + "idx": 1882, + "question": "When a small amount of CaO is doped into ThO2, write the corresponding solid solution formula (9)", + "answer": "9) Th1-xCaxO2-x", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出相应的固溶体化学式，需要根据掺杂规则进行推导和书写，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解掺杂过程中的电荷平衡原理，并能够正确应用缺陷化学的知识来推导固溶体化学式。这涉及到多步的思考和概念关联，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题中属于中等难度，需要理解掺杂固溶体的基本概念，掌握电荷平衡原理，并能正确推导出固溶体化学式。题目涉及多步计算和概念关联，但选项提供了明确的结构指引，降低了纯推导的难度。" + }, + { + "idx": 1883, + "question": "What is a space group?", + "answer": "The collection of all symmetry elements in a crystal structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"space group\"进行定义和解释，答案是一个简短的文字描述，符合简答题的特征 | 知识层次: 题目考查对空间群这一基本概念的定义记忆和理解，属于晶体学中的基础概念，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"space group\"这一基础概念的定义记忆，属于最基础的知识点。正确选项直接给出了术语的标准定义，不需要任何解释、比较或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1884, + "question": "Fick's first law can be directly applied to solve the problem of . A．steady-state diffusion B．non-steady-state diffusion C．any diffusion", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对Fick's第一定律适用条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念记忆题，直接考察Fick第一定律的应用范围。只需识别\"稳态扩散\"这一基本定义，无需进行概念辨析或复杂分析。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 1885, + "question": "When a small amount of CaO is doped into ThO2, write the possible defect reaction equation (8)", + "answer": "8) 2CaO → CaTh'' + Cai'' + 2O0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出可能的缺陷反应方程，需要文字解释和论述，答案是一个具体的反应方程式，属于简答题类型。 | 知识层次: 题目要求写出掺杂CaO到ThO2中的缺陷反应方程，这需要理解缺陷化学的基本原理，并能够应用这些原理来推导具体的缺陷反应。虽然不涉及复杂的计算或多步推理，但需要对缺陷类型和电荷平衡有较好的理解，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。首先，题目要求考生理解掺杂过程中的缺陷反应方程，这需要掌握晶体缺陷的基本概念和符号表示。其次，正确选项涉及多步计算和概念关联，考生需要正确识别掺杂离子（Ca²⁺）在ThO₂基质中的取代位置和电荷补偿机制。此外，题目还要求综合分析掺杂过程中可能产生的缺陷类型（如CaTh''和Cai''），这超出了简单的记忆或单一概念的应用，需要考生具备较强的逻辑推理和综合分析能力。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 1886, + "question": "When a small amount of CaO is doped into ThO2, write the corresponding solid solution formula (10)", + "answer": "10) Th1-xCa2xO2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出相应的固溶体化学式，需要根据掺杂规则进行推导并给出具体的化学式，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据掺杂情况写出固溶体化学式，需要理解掺杂原理和电荷平衡的概念，并进行多步推理和计算（如确定掺杂比例和电荷补偿方式），属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解掺杂固溶体的基本概念，掌握电荷平衡的计算方法，并能正确写出固溶体的化学式。虽然题目涉及多步计算和概念关联，但在选择题型中，通过选项可以辅助判断，降低了部分难度。" + }, + { + "idx": 1887, + "question": "4. Melt is a high-energy state of matter existing above the liquidus temperature, and during the cooling process of the melt, three different phase transition processes can occur: (11), (12), and (13).", + "answer": "(11) Crystallization; (12) Vitrification; (13) Phase separation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写三个不同的相变过程，需要考生根据知识进行简短的文字回答，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查对熔体冷却过程中三种相变过程的基本概念记忆，属于基础概念的记忆性知识，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确区分并记忆三种不同的相变过程（结晶、玻璃化和相分离）。这比单纯记忆单一概念的定义（等级1）要求更高，但不需要进行复杂的概念体系阐述或比较分析（等级3）。" + }, + { + "idx": 1888, + "question": "Crystals have basic properties such as (1) (2) (3) and (4).", + "answer": "1) Symmetry; (2) Crystallographic homogeneity; (3) Anisotropy; (4) Self-confinement (or minimal internal energy property)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写晶体的基本性质，需要文字解释和列举具体性质，而不是从选项中选择或判断对错，也不涉及计算。 | 知识层次: 题目考查晶体基本性质的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆晶体的基本性质即可完成作答。题目直接列出了四个基本性质，没有涉及概念解释或复杂概念体系的阐述，解题步骤简单，对知识点的掌握深度要求较低。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1889, + "question": "5．According to the thermodynamic theory of diffusion, the driving force of the diffusion process is", + "answer": "chemical potential gradient", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释扩散过程的驱动力，需要文字回答，而不是选择、判断或计算 | 知识层次: 题目考查扩散过程驱动力的基本概念记忆，即化学势梯度，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对扩散过程驱动力的基础定义记忆，属于最基础的概念性知识。学生只需识别\"chemical potential gradient\"这一标准术语即可作答，无需进行概念解释或复杂分析，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1890, + "question": "Wetting is an important behavior at the solid-liquid interface, and one of the methods to improve wetting is (16)", + "answer": "Reduce the solid-liquid interfacial energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求提供一个简短的解释或论述来回答问题，而不是从多个选项中选择或进行数值计算。答案“Reduce the solid-liquid interfacial energy”是一个简短的文字解释，符合简答题的特征。 | 知识层次: 题目考查对润湿行为及其改善方法的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"降低固液界面能\"这一改善润湿性的方法。题目不涉及概念解释或复杂体系分析，属于最基础的定义性知识考查，符合等级1的简答要求。" + }, + { + "idx": 1891, + "question": "5. According to the thermodynamic theory of diffusion, the condition for reverse diffusion to occur is", + "answer": "<0 or the thermodynamic factor of the diffusion coefficient is less than 0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释热力学扩散理论中反向扩散发生的条件，需要文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目涉及热力学扩散理论中的反向扩散条件，需要理解扩散系数的热力学因子概念，并能够分析其与扩散方向的关系。这属于中等应用层次，需要将理论知识与具体条件相结合进行分析，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题中属于中等难度，需要理解扩散的热力学理论中的关键概念（如反向扩散的条件和扩散系数的热力学因子），并能将这些概念关联起来进行综合分析。题目要求考生不仅知道基本定义，还要能够应用这些知识来判断特定条件下的扩散行为。" + }, + { + "idx": 1892, + "question": "7. Martensitic transformation has the following characteristics: (19) etc.", + "answer": "(19) Presence of habit plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求补充马氏体相变的特征，需要填写具体的文字描述（如\"Presence of habit plane\"），属于需要文字解释的简答题形式。 | 知识层次: 题目考查马氏体相变的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆马氏体相变的基本特征之一（存在惯习面），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或分析，因此属于最低难度等级。" + }, + { + "idx": 1893, + "question": "Wetting is an important behavior at the solid-liquid interface, one of the methods to improve wetting is (18)", + "answer": "Changing surface roughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求提供一个简短但具体的答案（\"Changing surface roughness\"），而不是从多个选项中选择或进行判断或计算。这种形式更符合简答题的特征。 | 知识层次: 题目考查对润湿行为及其改善方法的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生记住改善润湿性的一种方法即可作答，无需进行复杂的概念解释或分析。题目直接给出了正确选项，且知识点较为单一，属于选择题中最简单的难度等级。" + }, + { + "idx": 1894, + "question": "7．Martensitic transformation has the following characteristics: (20) etc.", + "answer": "(20) Orientation relationship", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述马氏体相变的特征，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查马氏体相变的基本特征，如取向关系等，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅要求识别马氏体相变的一个基本特征（取向关系），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1895, + "question": "Wetting is an important behavior at the solid-liquid interface, one of the methods to improve wetting is (17)", + "answer": "Increase the surface energy of the solid (remove the adsorbed film on the solid surface)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释改善润湿行为的方法，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对润湿行为及其改善方法的基本概念记忆和理解，属于基础知识的直接应用，不涉及复杂分析或综合推理。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生记住改善润湿的一种方法即可。题目直接给出了正确选项，没有涉及复杂的概念体系或需要解释和描述的内容。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1897, + "question": "8.The characteristic of reversible polymorphic transformation is: (23)", + "answer": "(23) The polymorphic transformation temperature is lower than the melting points of both crystal forms", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项编号(23)给出，符合选择题的特征 | 知识层次: 题目考查可逆多晶型转变的基本特征，属于对基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆层次，要求考生掌握可逆多晶型转变的特征。虽然需要记忆具体定义，但选项直接给出了明确的特征描述（转变温度低于两种晶型的熔点），不需要复杂的分析或比较。在选择题型中属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 1901, + "question": "What are the main mass transfer mechanisms in solid-state sintering?", + "answer": "(28) Evaporation-condensation mass transfer; (29) Diffusion mass transfer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举主要的固态烧结中的质量传递机制，答案以文字形式给出，没有选项或计算要求 | 知识层次: 题目考查固体烧结过程中主要传质机制的基础概念记忆和理解，属于定义和分类层面的知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求识别和记忆固体烧结过程中的主要传质机制，属于基础概念记忆层次。题目提供了明确的正确选项，无需进行复杂的分析或比较，因此难度较低。" + }, + { + "idx": 1902, + "question": "What are the main mass transfer mechanisms in liquid phase sintering?", + "answer": "(30) Flow mass transfer; (31) Dissolution-precipitation mass transfer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释液相烧结中的主要传质机制，答案提供了两种机制的简要描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查液相烧结中主要传质机制的基本概念记忆和理解，属于定义和分类等记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生准确区分和识别液相烧结中的两种主要传质机制（流动传质和溶解-沉淀传质）。这比单纯记忆单一概念的定义（等级1）要求更高，但不需要进行复杂的概念体系阐述或比较分析（等级3）。" + }, + { + "idx": 1905, + "question": "Glass phase separation", + "answer": "3. Glass phase separation: A homogeneous glass phase may, within certain temperature and composition ranges, separate into two mutually insoluble or partially soluble glass phases that coexist. This phenomenon is called glass phase separation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Glass phase separation\"这一现象进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对玻璃相分离现象的基本定义和描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要考生理解\"玻璃相分离\"的定义和基本原理，但题目本身提供了完整的解释，考生只需识别和匹配正确选项即可。不需要进行复杂的概念比较或推导，属于概念解释和描述层面的考查。" + }, + { + "idx": 1906, + "question": "Unit parallelepiped", + "answer": "Unit parallelepiped: In a space lattice, the parallelepiped selected according to the selection principle is called the unit parallelepiped.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Unit parallelepiped\"进行文字解释和论述，答案提供了概念的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对\"Unit parallelepiped\"这一基本概念的定义记忆，属于空间点阵中的基础概念，不涉及应用或分析过程 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"unit parallelepiped\"的基本定义，属于最基础的概念记忆层次。题目直接给出了定义描述，不需要进行任何解释、比较或分析，完全符合等级1\"基本定义简答\"的标准。在选择题型内，这是最简单的难度级别，只需对专业术语的定义有基本记忆即可正确作答。" + }, + { + "idx": 1907, + "question": "Tangent rule", + "answer": "4. Tangent rule: Draw a tangent at a certain point on the boundary line and intersect it with the corresponding connecting line. If the intersection point lies on the connecting line, it indicates that the boundary at that point has a eutectic property; if the intersection point lies on the extension of the connecting line, it indicates that the boundary at that point has a peritectic property, and the crystalline phase farther from the intersection point is peritectically consumed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对Tangent rule进行文字解释和论述，答案提供了详细的描述和解释，符合简答题的特征。 | 知识层次: 题目要求解释Tangent rule的应用，涉及边界线切线交点位置的判断，需要理解并应用相图的基本原理，进行概念关联和综合分析。虽然不涉及复杂计算，但需要多步思维过程来区分共晶和包晶性质，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及的知识点\"Tangent rule\"需要深入理解相图边界线的切线规则及其在共晶和包晶反应中的应用。其次，解题步骤较为复杂，需要考生能够正确绘制切线、判断交点位置，并关联到共晶或包晶性质的分析。此外，题目要求考生能够综合分析边界线性质与结晶相变化的关系，这需要将多个概念进行关联和比较。在选择题型内，这种需要多角度分析和概念关联的题目相对较少，因此难度等级较高。" + }, + { + "idx": 1912, + "question": "Normal spinel structure", + "answer": "5. Normal spinel structure: It belongs to the cubic crystal system, in which oxygen ions can be regarded as arranged in cubic close packing, divalent cations A fill one-eighth of the tetrahedral voids, and trivalent cations B fill half of the octahedral voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Normal spinel structure进行文字解释和论述，答案提供了详细的晶体结构描述，属于简答题的特征。 | 知识层次: 题目考查对Normal spinel结构的基本概念记忆，包括晶体系统、离子排列方式以及阳离子占据空隙的类型和比例，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体结构的基本概念，但需要考生理解和记忆多个关键点，如立方晶系、氧离子的立方密堆积排列、二价和三价阳离子占据的间隙位置等。这些知识点虽然基础，但需要一定的概念整合能力，属于概念解释和描述的层次。" + }, + { + "idx": 1914, + "question": "Write the defect reaction equation for the formation of a solid solution of YF3 in CaF2 (atomic weights are Y88.9, Ca40.0, F19.0)", + "answer": "2.YF3→CaF2YCa·+Fi′+2FF Ca0,8Y0,2F2,2 2YF3→CaF22YCa∗+V Ca′′+6FF Ca0,7Y0,2F2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，而不是简单的选择、判断或计算。答案的形式也是以文字和化学方程式为主，符合简答题的特征。 | 知识层次: 题目要求写出YF3在CaF2中形成固溶体的缺陷反应方程，这需要理解缺陷化学的基本原理，并能够应用这些原理来推导具体的反应方程。这涉及到多步的思考和概念关联，如电荷平衡、缺陷类型（如间隙离子、空位等）的识别和表示。虽然不涉及复杂的计算，但需要对材料缺陷化学有较深的理解和应用能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求写出YF3在CaF2中形成固溶体的缺陷反应方程，这需要深入理解缺陷化学和固溶体形成的原理。其次，题目涉及多步计算和概念关联，如电荷平衡、缺陷符号的正确使用以及固溶体化学式的推导。此外，题目还要求综合分析不同缺陷类型（如间隙离子、空位等）对固溶体形成的影响。这些因素使得该题目在选择题型中需要较高的知识掌握深度和解题步骤的复杂程度，属于多角度分析论述的难度等级。" + }, + { + "idx": 1915, + "question": "When 20 mol% YF3 is added to CaF2 to form a solid solution, the experimentally measured density of the solid solution is 3.64 g/cm3, and the lattice parameter at this time is a=0.55 nm. Calculate and determine the type of this solid solution. (The atomic weights are Y 88.9, Ca 40.0, F 19.0).", + "answer": "The unit cell of the fluorite-type crystal structure contains 4 CaF2, ρ_vacancy=3.34 g/cm3; ρ_interstitial=3.65 g/cm3; ρ_interstitial is close to the measured ρ=3.65 g/cm3, so under these conditions, an interstitial solid solution is formed.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（如密度、晶格参数等）并应用相关公式来确定固溶体的类型。答案中包含了具体的计算过程和结果比较，符合计算题的特征。 | 知识层次: 题目涉及多步计算（密度计算、晶格参数分析）、概念关联（固溶体类型判断）和综合分析（比较计算值与实验值）。虽然不涉及复杂的机理分析或创新设计，但需要将多个知识点和计算步骤结合起来解决问题，超出了简单应用的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目涉及固体溶液类型的判断，需要计算理论密度并与实验值比较。解题步骤包括：" + }, + { + "idx": 1916, + "question": "Explain the formation conditions and characteristics of structural defects in anion interstitial non-stoichiometric compounds", + "answer": "Under oxidizing atmosphere, low valence state changes to high valence state, p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结构缺陷的形成条件和特征，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求解释非化学计量化合物中结构缺陷的形成条件和特征，涉及氧化气氛下的价态变化和半导体类型，需要综合运用材料科学和化学原理进行机理分析和推理。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解非化学计量化合物的基本概念，还需要掌握结构缺陷的形成条件（氧化气氛）及其对材料性能的影响（p型半导体特性）。这需要综合运用晶体化学、缺陷化学和半导体物理等多学科知识，并进行机理层面的深度解释。在选择题型中，这种需要多维度分析和机理推理的题目属于最复杂的类型。" + }, + { + "idx": 1917, + "question": "In the non-stoichiometric compound FexO, Fe3+/Fe2+=0.1. Determine the value of x in the non-stoichiometric compound FexO.", + "answer": "According to the reaction formula Fe_xO → Fe2O3 → Fe0 → 2Fe_Fe^· + V_Fe^′′ + 3O_∘; Fe_1-3y^2+ Fe_2y^3+ O, let y be the mole fraction of Fe3+, then 2y/(1-3y) = 0.1. Solving gives y = 1/23 ≈ 0.043. The value of x is 1 - y = 1 - 0.043 ≈ 0.957.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定非化学计量化合物FexO中的x值，解答过程中涉及化学反应方程式的建立和代数方程的求解，属于典型的计算题。 | 知识层次: 题目需要进行多步计算和概念关联，涉及非化学计量化合物的组成计算和离子价态平衡，需要综合分析反应公式和数学求解过程。 | 难度: 在选择题中属于中等偏上难度，需要理解非化学计量化合物的概念，掌握Fe3+/Fe2+比例的计算方法，并进行多步推导和代数求解。虽然题目提供了反应公式和解题思路，但仍需要较强的综合分析能力和计算技巧才能正确解答。" + }, + { + "idx": 1918, + "question": "In the non-stoichiometric compound FexO, Fe3+/Fe2+=0.1. Find the vacancy concentration in the non-stoichiometric compound FexO.", + "answer": "According to the reaction formula Fe_xO → Fe2O3 → Fe0 → 2Fe_Fe^· + V_Fe^′′ + 3O_∘; Fe_1-3y^2+ Fe_2y^3+ O, let y be the mole fraction of Fe3+, then 2y/(1-3y) = 0.1. Solving gives y = 1/23 ≈ 0.043. The vacancy concentration is y/(1 + x), where x = 1 - y = 0.957, thus the vacancy concentration is 0.043 / (1 + 0.957) ≈ 2.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非化学计量化合物FexO中的空位浓度，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及非化学计量化合物FexO中Fe3+/Fe2+比值的计算，需要通过反应公式建立方程并求解，涉及多步计算和概念关联。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和对非化学计量化合物缺陷化学的理解。 | 难度: 在选择题中属于中等偏上难度，需要理解非化学计量化合物的概念，建立反应方程式，并进行多步计算。虽然题目提供了部分解题步骤，但仍需要综合分析Fe3+/Fe2+比例与空位浓度之间的关系，并进行代数求解。这比简单的概念选择题或单步计算题更复杂，但尚未达到涉及多变量或高度抽象思维的复杂计算问题水平。" + }, + { + "idx": 1919, + "question": "Briefly describe the reasons for the formation of structural defects in non-stoichiometric compounds", + "answer": "Reasons for formation: presence of variable valence elements, changes in the nature of the surrounding atmosphere.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述非化学计量化合物中结构缺陷形成的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查非化学计量化合物中结构缺陷形成的基本原因，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求简要描述非化学计量化合物中结构缺陷的形成原因，但正确选项中涉及了可变价元素和周围气氛性质变化两个关键点，这需要考生对相关基础概念有一定的理解和记忆。题目不涉及复杂的分析或比较，但超出了简单定义回忆的范畴，属于概念解释和描述的层次。" + }, + { + "idx": 1920, + "question": "Explain the formation conditions and characteristics of structural defects in anion vacancy-type non-stoichiometric compounds", + "answer": "Under reducing atmosphere, high valence state changes to low valence state, n-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结构缺陷的形成条件和特征，需要文字解释和论述，而不是选择、判断或计算。答案提供了简要的解释，符合简答题的特点。 | 知识层次: 题目要求解释阴离子空位型非化学计量化合物的结构缺陷形成条件和特征，涉及还原气氛下的价态变化和半导体类型判断，需要综合运用材料科学、固体化学和半导体物理等多学科知识，进行机理分析和推理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解非化学计量化合物中阴离子空位型结构缺陷的形成条件和特征，还需要掌握还原气氛下高价态向低价态转变的机理，以及n型半导体的相关特性。这些知识点涉及复杂的材料科学原理和深入的机理分析，需要考生具备综合运用知识、推理分析和解释机理的能力。在选择题型中，这类题目通常要求考生在多个复杂概念之间建立联系，并准确识别正确选项，因此难度最高。" + }, + { + "idx": 1921, + "question": "Explain the formation conditions and characteristics of structural defects in cation interstitial non-stoichiometric compounds", + "answer": "Under reducing atmosphere, high valence state changes to low valence state, n-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结构缺陷的形成条件和特征，需要详细的文字论述和解释，而不是简单的选择、判断或计算。答案也提供了具体的解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释阳离子间隙非化学计量化合物的结构缺陷形成条件和特征，涉及还原气氛下的价态变化和半导体类型判断，需要综合运用材料科学中的缺陷化学、半导体物理等知识，进行机理分析和推理。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1922, + "question": "Explain the formation conditions and characteristics of structural defects in cation vacancy-type non-stoichiometric compounds", + "answer": "Under oxidizing atmosphere, low valence state changes to high valence state, p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释阳离子空位型非化学计量化合物的结构缺陷形成条件和特征，需要详细的文字解释和论述。答案提供了氧化气氛下价态变化和半导体类型的描述，符合简答题的特点。 | 知识层次: 题目要求解释阳离子空位型非化学计量化合物的结构缺陷形成条件和特征，涉及氧化气氛下的价态变化和半导体类型转变，需要综合运用材料科学中的缺陷化学、半导体物理等知识，进行机理分析和推理。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解非化学计量化合物的基本概念，还需要深入掌握结构缺陷的形成条件（氧化气氛）及其对材料性能的影响（p型半导体特性）。这需要综合运用晶体化学、缺陷化学和半导体物理等多学科知识进行机理层面的深度解释，并能够将氧化还原反应与半导体类型变化联系起来。选择题型中仅给出正确选项的情况下，考生仍需具备从复杂现象中提取关键特征的能力，这远超简单记忆或基础理解的层次。" + }, + { + "idx": 1923, + "question": "Given a powder compact with an average particle size of 5μm, after sintering for 2 hours, the neck growth rate x/r=0.1. If grain growth is not considered, how much time is needed to sinter the compact to a neck growth rate x/r=0.2 via material transport by flow?", + "answer": "The formula for material transport by flow: x/r = k r^(-1/2) t^(1/2). Substituting x/r=0.1, r=5μm, t=2h to solve for k: 0.1 = k (5)^(-1/2) (2)^(1/2), yielding k. Then substituting x/r=0.2, r=5μm, and k to solve for t: 0.2 = k (5)^(-1/2) t^(1/2), yielding t=8h. Material transport by flow requires 8h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需时间，答案给出了具体的计算步骤和结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，需要将已知条件代入公式求解常数k，然后再用同样的公式求解新的时间t。整个过程不需要多步计算或复杂的概念关联，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要代入公式并解方程，但整个过程仅涉及单一公式的直接套用和简单代数运算，不需要多个公式的组合或复杂推导。解题步骤清晰且直接，属于选择题型中较为基础的难度水平。" + }, + { + "idx": 1924, + "question": "Please explain what a perfect dislocation is", + "answer": "Perfect dislocation: The Burgers vector is an integer multiple of the lattice vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"perfect dislocation\"的概念，需要文字解释和论述，答案也是以文字形式给出的定义说明 | 知识层次: 题目考查对完美位错这一基本概念的定义记忆，属于材料科学中晶体缺陷的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别完美位错的基本定义（柏氏矢量是晶格矢量的整数倍）。这属于最基础的概念记忆题，不需要解释或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1926, + "question": "Why do primitive, face-centered, and body-centered lattices exist in the cubic system, but not base-centered lattices?", + "answer": "The characteristic of the cubic system is the presence of 4L3 axes, which exist in the primitive, face-centered, and body-centered lattices of the cubic system. If a base-centered lattice were to exist in the cubic system, the 4L3 axes would not be possible in such a lattice. Therefore, the base-centered lattice does not conform to the symmetry characteristics of the cubic system and cannot exist in it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在立方晶系中存在原始、面心和体心点阵，但不存在底心点阵。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要深入理解立方晶系的对称性特征（4L3轴），并分析不同点阵类型（原始、面心、体心）如何满足这些对称性要求。同时，需要推理为什么底心点阵不符合立方晶系的对称性特征，涉及对称性原理和点阵类型的综合分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1927, + "question": "Please write the Burgers vector of the shortest unit dislocation in BCC crystals", + "answer": "BCC: a/2<111>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出BCC晶体中最短单位位错的Burgers矢量，答案需要特定的文字表述（a/2<111>），属于需要特定知识回答的简答题类型 | 知识层次: 题目考查BCC晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆BCC晶体中最短单位位错的Burgers矢量表达式a/2<111>，属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接回忆定义即可作答，因此属于最简单的难度等级1。" + }, + { + "idx": 1928, + "question": "Given a powder compact with an average particle size of 5μm, after sintering for 2 hours, the neck growth ratio x/r=0.1. If grain growth is not considered, how much time is required to sinter the compact to a neck growth ratio x/r=0.2 through diffusion mass transport?", + "answer": "Diffusion mass transport formula: x/r = k r^(-3/5) t^(1/5). Substituting x/r=0.1, r=5μm, t=2h to solve for k: 0.1 = k (5)^(-3/5) (2)^(1/5), yielding k. Then substituting x/r=0.2, r=5μm and k to solve for t: 0.2 = k (5)^(-3/5) t^(1/5), yielding t=64h. Diffusion mass transport requires 64h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的公式和条件求解所需时间，答案也是具体的数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解扩散质量传输公式并正确代入数值求解常数k，然后再次应用公式求解新的时间t。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散质量传输公式并进行多步计算。题目要求考生首先根据已知条件求解常数k，然后利用k值计算新的时间t。虽然计算步骤明确，但涉及指数运算和代数求解，对考生的计算能力和公式应用能力有一定要求。" + }, + { + "idx": 1929, + "question": "Please write the Burgers vector of the shortest unit dislocation in HCP crystals", + "answer": "HCP: a/3<11\\\\bar{2}0>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出HCP晶体中最短单位位错的Burgers矢量，答案需要具体的矢量表示（a/3<11\\\\bar{2}0>），属于需要具体回答的简答题类型，而非选择、判断或计算。 | 知识层次: 题目考查HCP晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆HCP晶体中最短单位位错的Burgers向量，属于基础概念记忆性知识，无需解释或分析，解题步骤简单直接。" + }, + { + "idx": 1930, + "question": "What is the difference between intrinsic diffusion and extrinsic diffusion?", + "answer": "The activation energy of intrinsic diffusion consists of both vacancy formation energy and particle migration energy, while the activation energy of extrinsic diffusion only includes particle migration energy; intrinsic diffusion dominates at high temperatures, whereas extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释内在扩散和外在扩散的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对扩散类型的基本概念记忆和理解，包括内在扩散和外在扩散的定义及其激活能量的组成差异，以及温度对扩散类型的影响。这些都属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个概念（本征扩散和外征扩散）的比较，但正确选项已经明确列出了两者的关键区别（激活能组成和温度依赖性）。这要求考生不仅要记忆两个扩散机制的定义，还需要理解它们之间的对比关系。不过由于选择题型提供了明确的选项提示，相比开放式简答降低了难度，因此属于等级2（概念解释和描述）而非更复杂的等级3。" + }, + { + "idx": 1931, + "question": "Compare the similarities between solid-phase sintering and liquid-phase sintering", + "answer": "The similarities between solid-phase sintering and liquid-phase sintering: the driving force for sintering is surface energy in both cases, and the sintering process consists of stages such as particle rearrangement, pore filling, and grain growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较固相烧结和液相烧结的相似之处，需要文字解释和论述，答案也是以文字形式详细描述了两者的相似点，符合简答题的特征。 | 知识层次: 题目要求比较固相烧结和液相烧结的相似性，涉及对两种烧结过程的理解和概念关联，需要综合分析烧结驱动力和烧结阶段的共同点，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较固相烧结和液相烧结的相似性，涉及表面能驱动力的理解以及烧结过程的多个阶段（颗粒重排、孔隙填充和晶粒生长）的综合分析。虽然不需要多角度或深度关联性分析，但仍需对相关概念有较好的掌握和应用能力。" + }, + { + "idx": 1932, + "question": "Please explain what is a partial dislocation", + "answer": "Partial dislocation: The Burgers vector is not an integer multiple of the lattice vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释部分位错的概念，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对部分位错（partial dislocation）这一基本概念的定义记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求对\"partial dislocation\"的基本定义进行记忆性回答，属于最基础的概念识别层面。正确选项直接给出了教科书式的定义，无需任何解释或推理步骤，完全符合\"基础概念记忆\"的知识层次要求。" + }, + { + "idx": 1933, + "question": "How does the thermal motion of atoms affect diffusion?", + "answer": "The enhancement of thermal motion will increase the jump distance, jump probability, and jump frequency of atoms, thereby increasing the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释热运动如何影响扩散，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目需要理解热运动与扩散系数之间的关系，涉及原子跳跃距离、概率和频率等概念的关联，并进行综合分析解释扩散系数的变化。这超出了基础概念的记忆，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解热运动与扩散系数之间的多因素关联（跳跃距离、概率、频率），并能综合分析这些因素如何共同影响扩散行为。虽然不涉及计算，但要求对物理机制有较深的概念掌握和逻辑推导能力。" + }, + { + "idx": 1935, + "question": "How to distinguish between hot deformation and cold deformation of metals?", + "answer": "It is distinguished based on the relationship between the deformation temperature and the recrystallization temperature. Deformation above the recrystallization temperature is hot deformation, and vice versa is cold deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何区分金属的热变形和冷变形，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对金属热变形和冷变形的基本定义和分类的记忆和理解，涉及基本原理的简单应用，但不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即区分热变形和冷变形的标准。正确选项直接给出了定义和分类，无需复杂的分析或推理步骤，属于最基础的难度等级。" + }, + { + "idx": 1936, + "question": "Please write the Burgers vector of the shortest unit dislocation in an FCC crystal", + "answer": "FCC: a/2<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出FCC晶体中最短单位位错的Burgers矢量，答案需要特定的文字表述（a/2<110>），而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查FCC晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆FCC晶体中最短单位位错的Burgers向量这一基础定义，无需解释或分析，属于最简单的记忆性知识考察。" + }, + { + "idx": 1937, + "question": "It is known that atomic radius is related to crystal structure. When the coordination number decreases, how does the atomic radius change? Why?", + "answer": "The radius contracts. If the radius remains unchanged, a decrease in coordination number would cause an increase in crystal volume. To minimize volume change, the atomic radius will contract.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述原子半径如何变化及其原因，答案提供了详细的解释而非简单的选择或判断。 | 知识层次: 题目需要理解原子半径与配位数之间的关系，并解释其变化原因，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解原子半径与配位数之间的关系，并能够解释为什么半径会收缩。题目要求考生不仅知道现象，还要理解背后的原理（最小化体积变化），这涉及中等应用层次的知识点掌握和综合分析能力。" + }, + { + "idx": 1938, + "question": "Discuss the conditions and characteristics of dissolution-precipitation mass transfer", + "answer": "The conditions for dissolution-precipitation mass transfer are: a considerable amount of liquid phase, high solubility of the solid phase in the liquid phase, and the liquid phase can wet the solid phase; the characteristics are: dissolution at particle contact points and deposition on flat surfaces, dissolution of small grains and deposition on large grains, and the mass transfer process is also a grain growth process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论溶解-沉淀传质的条件和特征，需要文字解释和论述，答案也提供了详细的描述和解释，符合简答题的特点。 | 知识层次: 题目要求讨论溶解-沉淀传质的条件和特征，涉及多个知识点的关联和综合分析，需要理解基本原理并能够解释其在实际过程中的表现，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生理解并综合多个概念（溶解-沉淀传质的条件和特征），并能够将这些概念关联起来进行分析。题目不仅要求识别基本条件（液相量、溶解度、润湿性），还需要掌握具体的传质特征（接触点溶解、平坦面沉积、小颗粒溶解大颗粒沉积、晶粒生长过程）。这种多角度分析和概念关联的要求使得题目在选择题型中属于较高难度等级。" + }, + { + "idx": 1939, + "question": "Homogeneous nucleation and heterogeneous nucleation have the same critical nucleus radius, and the critical nucleation work for heterogeneous nucleation is also equal to one-third of the surface energy. Why is heterogeneous nucleation easier than homogeneous nucleation?", + "answer": "Because in heterogeneous nucleation, impurities or mold cavities act as part of the nucleus. That is to say, fewer atoms need to be mobilized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述，说明为什么异质成核比均质成核更容易，答案提供了详细的解释而非简单的选择或判断。 | 知识层次: 题目涉及对均相成核和非均相成核的理解，需要比较两者的临界核半径和成核功，并解释非均相成核更容易的原因。这需要将多个概念关联起来进行分析，并理解杂质或模具空腔在成核过程中的作用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及均匀成核和非均匀成核的临界核半径和临界成核功的概念，并需要理解为什么非均匀成核更容易。虽然题目给出了正确选项，但需要考生掌握相关概念并能够进行综合分析。" + }, + { + "idx": 1940, + "question": "For metals without phase transformation in the solid state, how to refine grain size through hot working without remelting?", + "answer": "Perform hot working to induce dynamic recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个简短的文字说明，而不是选择、判断或计算。 | 知识层次: 题目考查对动态再结晶概念的理解及其在热加工中的应用，需要将材料加工工艺与微观结构演变机制相关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解动态再结晶的概念及其与热加工的关系，并进行综合分析。题目要求考生将金属热加工与晶粒细化机制联系起来，属于中等应用层次的知识运用。" + }, + { + "idx": 1941, + "question": "For metals without phase transformation in the solid state, can the grain size be refined without remelting?", + "answer": "Yes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Yes/No），符合判断题的特征。答案直接给出\"是\"或\"否\"的判断结果，不需要选择、计算或解释。 | 知识层次: 题目考查对金属晶粒细化方法的基础概念记忆，特别是关于无固态相变金属的晶粒细化可能性，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆金属晶粒细化方法的基本原理即可作答，无需复杂分析或概念比较。题目直接询问是否可以通过非重熔方式细化晶粒，属于最基础的定义性知识考查。" + }, + { + "idx": 1942, + "question": "In an FCC crystal, does the dislocation reaction a/2[10-1] + a/6[-121] → a/3[11-1] satisfy the energy condition?", + "answer": "Energy condition: |a/2√2|^2 + |a/6√6|^2 = (a²/2 + a²/6) = 2a²/3 > a²/3, the energy condition is satisfied.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目涉及具体的数值计算和公式应用，需要验证能量条件是否满足，答案中给出了具体的计算过程和结果。 | 知识层次: 题目涉及晶体缺陷中的位错反应能量条件计算，需要理解位错反应的能量守恒原理，并应用矢量运算和能量公式进行多步计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解位错反应的能量条件，并进行多步计算和综合分析。题目涉及FCC晶体结构、位错反应的能量计算，以及比较初始和最终位错的总能量。虽然计算步骤较多，但在选择题型中属于中等难度的综合性计算问题。" + }, + { + "idx": 1943, + "question": "In an FCC crystal, does the dislocation reaction a/2[10-1] + a/6[-121] → a/3[11-1] satisfy the geometric conditions?", + "answer": "Geometric conditions: b1 + b2 = (1/2 - 1/6)a + (0 + 2/6)b + (-1/2 + 1/6)c = 1/3a + 1/3b - 1/3c = a/3[11-1], satisfying the geometric conditions.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个具体的陈述（位错反应是否满足几何条件）的对错，答案给出了明确的判断依据和计算过程，符合判断题的特征 | 知识层次: 题目涉及位错反应几何条件的验证，需要进行多步计算和概念关联，包括矢量相加和验证是否符合几何条件。虽然不涉及复杂的推理分析或机理解释，但需要一定的综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解FCC晶体中的位错反应，并能够进行矢量计算。其次，解题过程涉及多步计算（矢量相加和分量计算），需要考生具备较强的空间想象能力和数学运算能力。最后，题目要求考生综合判断几何条件是否满足，这需要对位错反应的基本原理有深入理解。因此，该题目在选择题型中属于综合分析结果判断的难度等级。" + }, + { + "idx": 1944, + "question": "For metals without phase transformation in the solid state, if not remelted, how to refine grains through cold deformation and recrystallization?", + "answer": "By performing significant cold deformation followed by recrystallization at an appropriate temperature to obtain fine grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的步骤和方法，而不是简单的选择或判断。 | 知识层次: 题目需要理解冷变形和再结晶的基本原理，并能够将这两个概念关联起来，综合分析如何通过这两个步骤细化晶粒。这涉及到多步的知识应用和概念关联，而不仅仅是简单的记忆或直接套用。 | 难度: 在选择题中属于中等难度，需要理解金属冷变形和再结晶的基本概念，并能将这两个过程关联起来综合分析其对晶粒细化的影响。题目要求考生不仅知道冷变形和再结晶的单独作用，还要理解它们结合使用的效果，属于中等应用层次的知识要求。" + }, + { + "idx": 1945, + "question": "What is texture?", + "answer": "Texture is the phenomenon where crystal planes and orientations in a crystal tend to align uniformly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"texture\"这一概念进行文字解释和论述，答案提供了详细的定义说明，符合简答题的特征 | 知识层次: 题目考查基本概念的记忆和理解，即texture的定义和基本现象描述，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅考察对\"texture\"这一基础概念的定义记忆，属于最基础的知识层次。正确选项直接给出了术语的标准定义，无需任何解释、分析或推理步骤，符合等级1\"基本定义简答\"的难度特征。" + }, + { + "idx": 1946, + "question": "Compare the differences between solid-phase sintering and liquid-phase sintering", + "answer": "Differences: Due to the faster mass transfer rate by flow compared to diffusion, liquid-phase sintering has a higher densification rate and lower sintering temperature. Additionally, the rate of the liquid-phase sintering process is also related to factors such as the amount of liquid phase, its properties (viscosity, surface tension, etc.), the wetting condition between the liquid and solid phases, and the solubility of the solid phase in the liquid phase. The factors affecting liquid-phase sintering are more complex than those for solid-phase sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较两种烧结过程的差异，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求比较固相烧结和液相烧结的差异，涉及对两种烧结过程中物质传输机制、影响因素（如液相量、性质、润湿条件等）的综合分析，需要深入理解烧结机理并能够进行对比推理。这超出了简单记忆或基本应用的范畴，属于需要综合运用知识和进行机理分析的复杂层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解固相烧结和液相烧结的基本概念，还需要深入掌握两者在物质传输速率、致密化速率、烧结温度等方面的差异。此外，题目还涉及液相烧结过程中多种复杂因素（液相量、性质、润湿条件、固相溶解度等）的综合分析，这要求考生具备较高的综合运用和推理分析能力。在选择题型中，这种需要多维度比较和机理深度解释的题目属于最复杂的一类。" + }, + { + "idx": 1947, + "question": "What is equilibrium crystallization?", + "answer": "Equilibrium crystallization refers to crystallization that occurs at a very slow rate, with sufficient diffusion in both the liquid and solid phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"equilibrium crystallization\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即equilibrium crystallization的定义和基本原理，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆，但需要考生理解并描述\"equilibrium crystallization\"的定义和特点，而不仅仅是简单的名词解释。正确选项提供了较为详细的解释，涉及结晶速率和扩散过程，这比单纯记忆定义要复杂一些，属于概念解释和描述的层次。" + }, + { + "idx": 1948, + "question": "What is non-equilibrium crystallization?", + "answer": "Non-equilibrium crystallization refers to crystallization that occurs under conditions of relatively fast crystallization rates and insufficient diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对非平衡结晶进行文字解释和论述，答案提供了概念的定义和特征描述，符合简答题的特点 | 知识层次: 题目考查非平衡结晶的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求对非平衡结晶的基本定义进行识别和记忆，属于最基础的概念性知识。正确选项直接给出了定义，不需要进行任何分析或推理，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1949, + "question": "It is known that for a certain crystal at 500°C, 1 vacancy can form for every 10^10 atoms. What is the vacancy formation energy of this crystal? (Given: the constant A=0.0539 for this crystal, Boltzmann constant k=1.381×10^-23 J/K)", + "answer": "$$ x\\\\begin{array}{c}{{c=A\\\\exp\\\\enspace\\\\big(\\\\enspace-\\\\frac{\\\\Delta E_{V}}{k T}\\\\big)}}\\\\ {{\\\\Delta E_{V}=-k T\\\\mathrm{ln}\\\\frac{c}{A}=\\\\mathrm{-\\\\enspace\\\\left[1.381\\\\times10^{-23}\\\\times\\\\enspace\\\\left(500+273\\\\right)\\\\right]\\\\enspace\\\\mathrm{ln}\\\\frac{10^{-10}}{0.0539}\\\\mathrm{\\\\scriptsize\\\\mathrm{~J}}}}}\\\\\\\\ {{=1.068\\\\times10^{-20}\\\\times17.8=1.9\\\\times10^{-19}\\\\mathrm{\\\\scriptsize{\\\\times10^{-19}}}}}\\\\\\\\ \\n $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出空缺形成能的具体数值。答案展示了详细的推导过程和计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解空位形成能的概念，并能够正确应用玻尔兹曼方程进行计算。虽然计算过程较为直接，但需要将多个概念（如浓度、温度、能量）关联起来，并进行对数运算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解空位形成能的概念，掌握相关公式，并进行多步计算。题目涉及对数运算、单位转换和常数代入，要求考生具备较强的综合计算能力和概念关联能力。虽然题目提供了公式和常数，但计算过程较为复杂，需要仔细推导和验证。" + }, + { + "idx": 1950, + "question": "What are the application conditions of the first law of diffusion?", + "answer": "The application condition of the first law of diffusion is steady-state diffusion, that is, diffusion independent of time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第一扩散定律的应用条件，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对扩散第一定律应用条件的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别第一扩散定律的基本应用条件（稳态扩散），属于最基础的定义性知识，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1951, + "question": "What types of textures are included?", + "answer": "Textures include recrystallization texture and deformation texture. Among them, deformation texture further includes fiber texture and sheet texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举不同类型的纹理，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对纹理类型的基本分类记忆，属于基础概念的记忆性知识，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解和区分不同纹理类型（再结晶纹理和变形纹理）及其子分类（纤维纹理和片状纹理）。这比单纯记忆定义（等级1）要求更高，但尚未达到复杂概念体系阐述（等级3）的深度。" + }, + { + "idx": 1952, + "question": "What are the common phase structures in solids?", + "answer": "The common phase structures in solids include: solid solution (element), compound, ceramic crystalline phase, amorphous phase, and molecular phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释常见的固相结构类型，答案以文字解释和论述的形式呈现，没有提供选项或要求进行判断或计算。 | 知识层次: 题目考查对固体中常见相结构的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生掌握并区分多种不同的固体相结构（如固溶体、化合物、陶瓷晶相等），这比单纯记忆单个定义要复杂。题目不涉及复杂的概念体系阐述或深入分析，但要求对多个相关概念有清晰的理解和分类能力，因此属于等级2难度。" + }, + { + "idx": 1953, + "question": "2. Please calculate the angle between (111) and (111) in a simple cubic crystal.", + "answer": "$${{\\\\cos\\\\alpha=\\\\frac{h_{1}h_{2}+k_{1}k_{2}+l_{1}l_{2}}{\\\\sqrt{h_{1}^{2}+k_{1}^{2}+l_{1}^{2}\\\\sqrt{h_{2}^{2}+k_{2}^{2}+l_{2}^{2}}}}\\\\mathrm{\\\\textstyle=\\\\frac{1-1+1}{\\\\sqrt{3}\\\\times\\\\sqrt{3}}=\\\\frac{1}{3}}}}\\\\ {{\\\\alpha=70^{\\\\circ}32^{\\\\prime}\\\\quad\\\\qquad\\\\quad}}\\\\end{array} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算简单立方晶体中(111)和(111)晶面之间的夹角，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用基本的晶体学公式计算晶面夹角，属于直接套用公式的简单计算类型，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要套用晶面夹角公式并进行简单计算，但步骤明确且直接，无需多个公式组合或复杂推导。正确选项已提供完整计算过程，学生只需理解基本公式的应用即可完成。" + }, + { + "idx": 1955, + "question": "What is a substitutional solid solution?", + "answer": "An alloy phase where solute atoms replace solvent atoms while maintaining the solvent structure is called a substitutional solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"substitutional solid solution\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对置换固溶体这一基本概念的定义记忆和理解，属于材料科学中的基础概念。 | 难度: 在选择题型中，该题目仅考察对\"置换固溶体\"这一基础定义的记忆，无需解释或分析多个概念。正确选项直接给出了定义，属于最基础的概念记忆层次，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1956, + "question": "For cases where the concentration gradient changes over time, can the first law of diffusion be applied?", + "answer": "The first law of diffusion can also be applied to non-steady-state diffusion, but it must be modified.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对非稳态扩散情况下第一扩散定律的应用进行解释和论述，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目涉及非稳态扩散情况下第一扩散定律的应用，需要对扩散定律的基本原理有理解，并能进行概念关联和综合分析，以判断其适用性和必要的修改。这超出了简单记忆或直接套用的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等难度，需要理解非稳态扩散的概念，并能将其与第一扩散定律的应用条件联系起来进行分析。题目要求考生不仅知道第一扩散定律的基本应用，还要理解其在变化条件下的适用性及必要的修正，涉及概念关联和综合分析能力。" + }, + { + "idx": 1957, + "question": "What are the factors affecting the solubility of substitutional solid solutions?", + "answer": "The influencing factors include: ①Atomic size; ②Crystal structure; ③Electronegativity; ④Electron concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响置换固溶体溶解度的因素，答案以文字形式给出多个影响因素，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查的是对置换固溶体溶解度影响因素的基本概念记忆和理解，涉及原子尺寸、晶体结构、电负性和电子浓度等基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个影响因素（原子尺寸、晶体结构、电负性、电子浓度），但每个因素都是基础概念记忆层面的知识点，不需要复杂的分析或推理。学生只需回忆并识别这些基本影响因素即可作答，不需要进行概念间的关联或深入解释。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1958, + "question": "How does constitutional supercooling affect the growth morphology of solid solutions?", + "answer": "In the absence of constitutional supercooling, the solid solution grows in a planar manner, forming equiaxed crystals; with a small degree of supercooling, cellular structures form; with a large degree of constitutional supercooling, dendritic crystals form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释constitutional supercooling对固溶体生长形态的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对constitutional supercooling如何影响固溶体生长形态的深入解释，需要理解并分析不同冷却条件下晶体生长的变化机制，属于对概念的深度理解和综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解\"成分过冷\"这一复杂概念，还需要掌握其对固溶体生长形貌的多层次影响机制（平面生长→胞状结构→枝晶形成）。正确选项涉及三个不同条件下的晶体生长形态变化，需要考生具备将热力学原理与晶体生长动力学相结合的分析能力。这种需要综合多个高阶概念并解释复杂现象的选择题，在材料科学选择题中属于最具挑战性的类型。" + }, + { + "idx": 1959, + "question": "What are the conditions for forming an infinite solid solution?", + "answer": "The same crystal structure of the two components is a necessary condition for forming an infinite solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释形成无限固溶体的条件，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对无限固溶体形成条件的基本概念记忆和理解，主要涉及晶体结构相同这一必要条件的知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对无限固溶体形成条件的必要条件的记忆，即两种组分具有相同的晶体结构。不需要解释或分析其他因素，属于最基础的概念记忆层次。" + }, + { + "idx": 1960, + "question": "What is the difference in diffusion coefficients between substitutional diffusion and interstitial diffusion?", + "answer": "The interstitial diffusion coefficient is independent of vacancy concentration, whereas the substitutional diffusion coefficient is related to vacancy concentration (can be expressed by a formula). Generally, the interstitial diffusion coefficient is greater than the substitutional diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种扩散系数之间的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种扩散机制的扩散系数差异，涉及对扩散机制的理解和关联分析，需要将扩散系数与空位浓度等概念联系起来，并进行综合分析。虽然不涉及复杂计算，但需要对相关概念有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生区分两种扩散机制（置换扩散和间隙扩散）的扩散系数差异，并理解它们与空位浓度的关系。虽然不需要进行多步计算，但需要对概念有较深的理解和关联能力。" + }, + { + "idx": 1961, + "question": "An FCC crystal yields under a normal stress of 2MPa in the [123] direction. The activated slip system has been measured as (111)[101]. Determine the resolved shear stress τ that activates this slip system.", + "answer": "$$ \\\\begin{array}{l}\\\\cos\\\\phi=\\\\frac{[\\\\overline{1}23]}{|[\\\\overline{1}23]|}\\\\cdot\\\\frac{[111]}{|[111]|}=\\\\frac{-1+2+3}{\\\\sqrt{14}\\\\sqrt{3}}=0.617\\\\\\\\ \\\\cos\\\\lambda=\\\\frac{[\\\\overline{1}23]}{|[\\\\overline{1}23]|}\\\\cdot\\\\frac{[\\\\overline{1}01]}{|[\\\\overline{1}01]|}=\\\\frac{1+0+3}{\\\\sqrt{14}\\\\sqrt{2}}=0.756\\\\end{array}$$ $$\\\\tau=2\\\\times0.617\\\\times0.756\\\\mathrm{MPa}=0.933\\\\mathrm{MPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定解析剪切应力τ，答案中包含了具体的数学计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括向量点积计算、方向余弦求解以及Schmid因子应用，涉及晶体学方向指数和滑移系统的综合分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体学方向指数、滑移系统、分解剪应力等概念，并进行多步向量点积计算。虽然题目提供了正确选项的计算过程，但需要考生具备综合分析能力和准确执行数学运算的技能。" + }, + { + "idx": 1962, + "question": "In a diffusion couple, if it is interstitial diffusion, will the Kirkendall effect occur? Why?", + "answer": "It will not occur. Because interstitial diffusion considers the directional flow of interstitial atoms and does not account for substitutional diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述，答案提供了详细的解释说明为什么间隙扩散不会发生柯肯达尔效应，而不是简单的选择或判断。 | 知识层次: 题目不仅需要理解间隙扩散和置换扩散的基本概念，还需要分析Kirkendall效应的发生条件，并将两者关联起来进行综合分析。这涉及到多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解间隙扩散和置换扩散的基本概念，并能够分析Kirkendall效应的产生条件。题目要求考生将这两个概念进行关联，并判断在间隙扩散情况下Kirkendall效应是否会发生。虽然不需要复杂的计算，但需要对扩散机制有较深入的理解和综合分析能力。" + }, + { + "idx": 1963, + "question": "At room temperature, a sheet of iron (with a melting point of 1538°C) is bent back and forth. What phenomenon will occur as the bending continues? Why?", + "answer": "According to T_recrystallization = (0.35–0.45)T_melting, the processing of Fe at room temperature is cold working. Therefore, as bending proceeds, the sheet undergoes work hardening, and continued deformation leads to fracture of the iron sheet.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释现象并论述原因，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要理解冷加工和再结晶温度的概念，并应用公式T_recrystallization = (0.35–0.45)T_melting进行计算和判断。同时，需要解释铁片在室温下弯曲时发生的加工硬化和最终断裂的现象，涉及多个概念的关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及冷加工、再结晶温度计算、加工硬化等概念的综合应用，要求考生能够将理论知识与实际现象关联起来，并进行多步推理。虽然题目提供了计算公式，但仍需考生具备一定的材料科学基础才能正确理解和应用这些概念。" + }, + { + "idx": 1964, + "question": "Please compare the similarities between binary eutectic transformation and peritectic transformation", + "answer": "Similarities: isothermal and constant composition transformation; both appear as horizontal lines on the phase diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较二元共晶转变和包晶转变的相似之处，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对二元共晶转变和包晶转变的基本概念记忆和理解，涉及相图中的基本特征和等温转变等基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求比较二元共晶转变和包晶转变的相似性，但正确选项已经明确给出了两个关键相似点（等温和恒定组成转变，以及在相图中表现为水平线）。这要求考生不仅要记忆两种转变的基本定义，还需要理解它们在相图中的表现特征。因此，题目涉及的概念解释和描述，属于等级2的难度。" + }, + { + "idx": 1965, + "question": "When bending a tin plate (with a melting point of 232°C) back and forth at room temperature, what phenomenon will occur as the bending proceeds? Why?", + "answer": "According to T_recrystallization=(0.35～0.45)Tm, the processing of Sn at room temperature is considered hot working. Therefore, as bending proceeds, dynamic recrystallization occurs in the Sn plate, allowing it to be bent for an extended period.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象并论述原因，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要综合运用动态再结晶理论（T_recrystallization=(0.35～0.45)Tm）和热加工概念，分析室温下锡板弯曲过程中的现象。这涉及材料科学中的相变机理、温度对材料行为的影响等复杂概念，并要求进行推理分析来解释现象。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1966, + "question": "What is solid solution strengthening? Please briefly describe its strengthening mechanism.", + "answer": "Solid solution strengthening is the phenomenon where solute atoms impede dislocation motion, thereby enhancing the strength of the alloy. The main mechanisms include: ① Cottrell atmosphere, where the elastic stress field of solute atoms hinders dislocation motion; ② Suzuki atmosphere, where solute atoms reduce the stacking fault energy of the matrix, causing dislocations to decompose into extended dislocations and impeding dislocation cross-slip or climb; ③ Electrical interaction, where charged solute atoms form electrostatic interactions with dislocations, hindering dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固溶强化的定义及其强化机制，答案以文字解释和论述的形式呈现，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目不仅要求解释固溶强化的定义，还需要详细描述其强化机制，包括Cottrell atmosphere、Suzuki atmosphere和Electrical interaction等复杂机理。这需要深入理解位错与溶质原子的相互作用，并进行综合分析，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解固溶强化的基本概念，还需要掌握并解释三种不同的强化机制（Cottrell atmosphere、Suzuki atmosphere和Electrical interaction）。这需要考生具备深入的材料科学知识，能够综合运用多个概念并进行机理层面的分析。此外，题目要求考生在选择题的有限选项中准确识别和区分这些复杂的机理，这在选择题型中属于最高难度的考查要求。" + }, + { + "idx": 1967, + "question": "Please compare the differences between binary eutectic transformation and peritectic transformation", + "answer": "Differences: eutectic is a decomposition-type reaction, peritectic is a synthesis-type reaction; the eutectic line is entirely a solidus line, while only part of the peritectic line is a solidus line; the eutectic triangle is above the horizontal line, the peritectic triangle is below the horizontal line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较二元共晶转变和包晶转变的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对二元共晶转变和包晶转变的基本概念和差异的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解并比较二元共晶转变和包晶转变的基本概念和特征，但不需要深入分析复杂的体系或机制。" + }, + { + "idx": 1968, + "question": "Please write out the crystal planes included in the {110} and {100} crystal plane families in the cubic crystal system, respectively.", + "answer": "{110}: (110) (101) (011) (110) (101) (011) {100}: (100) (010) (001) (001) (010) (100)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出立方晶系中{110}和{100}晶面族包含的所有晶面，需要列举具体的晶面指数，属于需要文字回答的简答题类型。答案形式为列举具体晶面而非计算或选择。 | 知识层次: 题目考查立方晶系中{110}和{100}晶面族包含的具体晶面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确回忆并区分立方晶系中{110}和{100}晶面族包含的具体晶面。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。考生需要理解晶面族的对称性并正确列举所有等效晶面，这属于概念解释和描述的范畴。" + }, + { + "idx": 1969, + "question": "Please compare the distortion energy of the two dislocations b1= a/2[111] and b2=a[100] in FCC crystals, which one is greater.", + "answer": "∣b₁∣=a/2√(1+1+1)=√3/2a ∣b₂∣=a√(1+0+0)=a Therefore, the distortion energy of b1 is smaller.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算两个位错的畸变能并进行比较，解答过程中涉及数值计算和公式应用（如计算位错矢量的模），最终通过计算结果得出比较结论。 | 知识层次: 题目涉及基本的矢量长度计算和公式应用，属于简单计算和直接套用类型，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算两个位错的畸变能并进行比较，但仅涉及基本的矢量模长公式和简单比较，无需复杂推导或多步骤计算。正确选项直接给出了计算过程和结论，符合等级2的标准。" + }, + { + "idx": 1970, + "question": "When CN=6, the ionic radius of Na+ is 0.097nm, what is its radius when CN=4?", + "answer": "0.088nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据已知条件(CN=6时的离子半径)通过计算得出CN=4时的离子半径，需要应用离子半径与配位数关系的计算公式，最终给出具体数值答案(0.088nm)。 | 知识层次: 题目涉及离子半径随配位数变化的简单计算，只需要直接应用已知的半径转换关系或经验公式即可得出结果，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用已知的离子半径与配位数关系公式，属于单一公式直接计算的简单应用。题目提供了明确的配位数变化和对应的半径值，解题步骤简单直接，无需复杂推理或多步骤计算。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1971, + "question": "Nickel has a face-centered cubic structure with an atomic radius of r_Ni=0.1246 nm. Determine how many atoms are present in 1 mm^2 on the (100) plane of nickel.", + "answer": "6.1×10^13 atoms/mm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及原子半径、晶面密度等材料科学参数的计算，最终要求得出具体的数值结果（6.1×10^13 atoms/mm^2）。 | 知识层次: 题目需要理解面心立方结构在(100)面上的原子排列方式，计算单位面积上的原子数，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方结构、(100)晶面的原子排布、原子半径与晶格参数的关系等概念，并进行多步计算（包括晶格参数计算、面密度计算、单位换算等）。虽然题目给出了正确选项，但解题过程涉及多个知识点的综合应用和计算步骤，比单纯的概念识别或单步计算题目更复杂。" + }, + { + "idx": 1973, + "question": "In the <100> direction of copper (fcc, a=0.361nm), what is the linear density of atoms?", + "answer": "The linear density of Cu atoms is 2.77×10^6 atoms/mm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铜在<100>方向上的线性原子密度，需要应用晶体结构参数和公式进行数值计算，答案给出了具体的计算结果。 | 知识层次: 题目需要应用基本的线性密度计算公式，并代入给定的晶格常数进行计算，属于直接套用公式的简单应用层次。虽然需要理解晶向和晶格结构的基本概念，但整体思维过程较为直接，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算铜在<100>方向的线性原子密度，仅需应用线性密度的基本公式（1/a）并进行单位转换（从nm到mm），无需复杂的推导或多步骤计算。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1974, + "question": "Write the equivalent crystal planes included in the crystal plane families {100}, {110}, {111}, {112} in cubic crystals.", + "answer": "{100}=(100)+(010)+(001), totaling 3 equivalent planes. {110}=(110)+(1̅10)+(101)+(1̅01)+(011)+(01̅1), totaling 6 equivalent planes. {111}=(111)+(1̅11)+(11̅1)+(111̅), totaling 4 equivalent planes. {112}=(112)+(1̅12)+(11̅2)+(112̅)+(121)+(121)+(121)+(121)+(211)+(211)+(211)+(211), totaling 12 equivalent planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出立方晶体中特定晶面族的等效晶面，答案需要列举具体的晶面指数并进行解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对立方晶体中晶面族等效晶面的记忆和理解，属于基础概念的记忆性知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要学生准确回忆并匹配立方晶体中不同晶面族的等效晶面。解题步骤相对直接，但需要掌握晶面指数的基本规则和对称性知识。相较于只需简单定义的等级1题目，此题要求更高的记忆准确性和对晶体对称性的理解。" + }, + { + "idx": 1975, + "question": "In the <100> direction of iron (bcc, a=0.286nm), what is the linear density of atoms?", + "answer": "The linear density of Fe atoms is 3.50×10^6 atoms/mm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铁在<100>方向上的线性原子密度，需要应用晶体结构和晶格常数的知识进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的线性密度计算公式，并代入已知的晶格常数进行简单计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型内，该题目属于单一公式直接计算的难度等级。题目要求计算铁在<100>方向的线性原子密度，仅需应用基本的线性密度公式（1/a）并进行单位转换即可得出答案。无需复杂的推导或多步骤计算，属于最基础的应用题类型。" + }, + { + "idx": 1977, + "question": "Determine whether the following dislocation reaction can proceed: $a[100]\\\\rightarrow\\\\frac{a}{2}[101]+\\\\frac{a}{2}[10{\\\\overline{{1}}}]$", + "answer": "No. Energy condition: $\\\\sum b_{\\\\mathbb{M}}^{2}=\\\\sum b_{E}^{2}=a^{2}$, the energy on both sides is equal.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能进行，答案直接给出\"是\"或\"否\"的判断结果，并附带简要解释。这符合判断题的特征，即对某个陈述或命题进行真伪判断。虽然答案中包含能量计算说明，但核心要求仍是判断反应能否进行。 | 知识层次: 题目需要应用位错反应的能量条件进行计算和判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。需要考生掌握位错反应的能量条件计算，能够正确应用矢量运算进行能量比较（∑b²的计算）。题目涉及多步概念关联（位错反应规则、能量条件判断）和综合分析（两边能量相等时的反应可能性判断），超出了简单的概念记忆或单步计算。虽然题目提供了正确选项，但解题过程需要较强的材料科学理论基础和计算能力，属于中等应用层次中较复杂的题目。" + }, + { + "idx": 1978, + "question": "The atomic packing density of magnesium, like all hcp metals, is 0.74. Calculate the volume of the unit cell of magnesium. Given the density of Mg ρMg=1.74 Mg/m³, relative atomic mass of 24.31, and atomic radius r=0.161 nm.", + "answer": "The volume of the unit cell is Vuc=0.14 nm³ (or 1.4×10⁻²⁸ m³).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（密度、相对原子质量、原子半径）和公式（原子堆积密度与晶胞体积的关系）进行数值计算，最终得出晶胞体积的具体数值。答案是一个具体的计算结果，而非选择、判断或文字解释。 | 知识层次: 题目需要多步计算和概念关联，包括原子堆积密度、单位晶胞体积计算、密度和相对原子质量的应用，以及单位转换等综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解hcp结构原子堆积密度概念，掌握单位晶胞体积计算公式，并能正确代入密度、相对原子质量和原子半径等数据进行多步计算。虽然题目提供了关键参数，但仍需综合应用材料科学和晶体学知识才能得出正确答案。" + }, + { + "idx": 1979, + "question": "Nickel has a face-centered cubic structure with an atomic radius of r_Ni=0.1246 nm. Determine the number of atoms per 1 mm^2 on the (110) plane of nickel.", + "answer": "1.14×10^13 atoms/mm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定镍在(110)平面上每平方毫米的原子数，答案是一个具体的数值结果，解答过程需要涉及晶体结构参数的计算。 | 知识层次: 题目需要多步计算和概念关联，包括晶体结构、晶面原子密度计算等综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方结构、(110)晶面的原子排列、原子半径与晶格参数的关系，并进行多步计算（晶格参数计算、面密度计算、单位换算）。虽然选项已给出，但解题过程涉及多个概念的综合应用和单位转换，属于综合性计算问题。" + }, + { + "idx": 1980, + "question": "Determine whether the following dislocation reaction can occur: $\\\\frac{a}{3}[112]+\\\\frac{a}{2}[111]\\\\rightarrow\\\\frac{a}{6}[11\\\\overline{{{1}}}]$", + "answer": "No. Geometric condition: $\\\\sum b_{\\\\mathbb{H}}=\\\\frac{a}{b}[557],\\\\sum b_{\\\\mathbb{H}}=\\\\frac{a}{b}[11\\\\overline{{1}}]$, cannot be satisfied.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能够发生，答案直接给出了\"否\"的判断结果，并提供了几何条件的验证依据。这符合判断题的特征，即对陈述或命题进行真伪判断。 | 知识层次: 题目需要应用位错反应的基本原理进行几何条件的判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求判断位错反应是否能够发生，这需要理解位错反应的几何条件和能量条件。其次，解题过程涉及多步计算和概念关联，包括位错矢量的计算和比较。最后，题目要求综合分析计算结果来判断反应是否满足条件，这超出了简单的概念记忆或单一计算步骤，属于中等应用层次的知识要求。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 1981, + "question": "The density of quartz (SiO2) is 2.65 Mg/m3. How many silicon atoms (and oxygen atoms) are there in 1 m3?", + "answer": "5.29×10^28 silicon atoms /m3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算硅和氧原子的数量），并给出了具体的答案（5.29×10^28 silicon atoms /m3），这需要应用密度和摩尔质量等公式进行计算。 | 知识层次: 题目需要进行基本的密度和摩尔质量计算，涉及简单的公式应用和单位转换，属于直接套用基本概念和公式的范畴。虽然需要计算硅和氧原子的数量，但整个过程是线性的，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要知道石英的分子式和密度，以及阿伏伽德罗常数的概念，但解题步骤相对直接：先计算石英的摩尔质量，然后利用密度和摩尔质量求出摩尔数，最后乘以阿伏伽德罗常数得到硅原子数量。这些步骤都是基础公式的简单应用，不需要复杂的推导或多步骤组合计算，因此在选择题型内属于等级2难度。" + }, + { + "idx": 1982, + "question": "At $800^{\\circ}\\mathrm{C}$, one atom in $10^{10}$ atoms has sufficient energy to move within the solid, while at $900^{\\circ}\\mathrm{C}$, only one atom in $10^{9}$ atoms does. Calculate the activation energy (J/atom).", + "answer": "$0.4\\times10^{-18}~\\mathrm{J}/$ atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解激活能（J/atom），答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度与激活能的关系，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解阿伦尼乌斯方程的概念，并进行多步计算和综合分析。题目涉及温度变化与活化能的关系，需要考生将给定的数据转换为合适的数学表达式，并进行对数运算来求解活化能。虽然计算步骤较多，但在选择题型中，正确选项的提示可以降低部分难度。" + }, + { + "idx": 1983, + "question": "If a face-centered cubic crystal has a unit dislocation with b=a/2[1̄01] and a partial dislocation with b=a/6[121̄], these two dislocations meet and undergo a dislocation reaction. Can this reaction proceed? Why?", + "answer": "It can proceed. Because it satisfies both the geometric condition: ∑bH=∑bE=a/3[1̄11], and the energy condition: ∑bM²=2/3a²>∑bE²=1/3a².", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两个位错相遇时是否会发生位错反应，并给出原因。答案不仅提供了结论（可以发生反应），还详细解释了满足的几何条件和能量条件，这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目涉及位错反应的条件判断，需要综合运用几何条件和能量条件进行分析，并进行推理解释。这要求对位错理论有深入的理解和综合应用能力，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1984, + "question": "When the radii of silicon and oxygen in quartz (SiO2) are 0.038 nm and 0.114 nm respectively, what is the packing density (assuming the atoms are spherical)?", + "answer": "0.33", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解石英的堆积密度，答案是一个具体的数值（0.33），解答过程需要运用材料科学中的相关公式和计算步骤。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及原子半径和堆积密度的简单计算，属于直接套用公式的范畴，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算石英（SiO2）的堆积密度，只需要应用堆积密度的基本公式（原子体积总和除以晶胞体积），并代入给定的硅和氧的半径值进行简单计算即可。无需组合多个公式或进行复杂的推导分析，因此属于最基础的难度等级。" + }, + { + "idx": 1985, + "question": "Determine whether the following dislocation reaction can proceed: $\\\\frac{a}{2}[10\\\\overline{{{1}}}]+\\\\frac{a}{6}[\\\\overline{{{1}}}21]\\\\rightarrow\\\\frac{a}{3}[11\\\\overline{{{1}}}]$", + "answer": "Yes. Geometric condition: $\\\\sum b_{\\\\tt H}=\\\\sum b_{\\\\tt G}=\\\\frac{\\\\alpha}{3}[11\\\\overline{{1}}]$; energy condition: $\\\\sum b_{\\\\mathbb{H}}^{2}={\\\\frac{2}{3}}a^{2}>$ $\\\\sum b_{E}^{2}={\\\\frac{1}{3}}a^{2}.$", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能够进行，答案给出了明确的\"yes\"判断，并提供了几何条件和能量条件的验证，符合判断题的特征。 | 知识层次: 题目需要应用位错反应的能量条件和几何条件进行判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求判断位错反应是否可以进行，这需要理解位错反应的几何条件和能量条件。其次，解题过程涉及多个步骤的计算和概念的综合应用，包括矢量运算和能量比较。虽然题目提供了正确选项，但学生仍需具备扎实的基础知识和综合分析能力才能正确判断。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 1986, + "question": "Given the Burgers vector b=0.25 nm, if the misorientation angle θ of a symmetric tilt grain boundary is 10°, calculate the distance between dislocations at the grain boundary.", + "answer": "When θ=10°, D=1.4 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的Burgers向量和错向角计算晶界位错间距，需要应用公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（Burgers vector与位错间距的关系公式）进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型内，该题目仅需要直接应用单一公式（D = b/θ）进行计算，无需多个步骤或复杂推理。题目提供了所有必要参数，且计算过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 1987, + "question": "Determine whether the following dislocation reaction can proceed: $a[100]\\\\rightarrow\\\\frac{a}{2}[111]+\\\\frac{a}{2}[1\\\\overline{{{11}}}]_{\\\\circ}$.", + "answer": "No. Energy condition: $\\\\sum b_{\\\\mathbb{H}}^{2}=a^{2}<\\\\sum b_{\\\\mathbb{H}}^{2}={\\\\frac{3}{2}}a^{2}$, meaning the energy increases after the reaction.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能进行，答案直接给出了\"是\"或\"否\"的判断，并提供了能量条件的解释。这符合判断题的特征，即对某个陈述或现象进行真伪判断。 | 知识层次: 题目需要应用位错反应的能量条件进行判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于较高难度，需要综合运用位错能量计算和反应条件判断的知识。题目要求考生不仅理解位错反应的能量条件（∑b²），还需要进行多步计算和比较（计算反应前后总伯氏矢量的平方和），最后综合分析得出反应不能进行的结论。这超出了单纯概念记忆或简单计算的范畴，属于需要综合分析判断的题目类型。" + }, + { + "idx": 1988, + "question": "What conclusion can be drawn from the calculation results?", + "answer": "When θ=10°, the distance between dislocations is only 5∼6 atomic spacings, indicating that the dislocation density is too high at this point. This suggests that the model is no longer applicable when the θ angle is large.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据计算结果得出结论，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求根据计算结果进行分析和结论推导，涉及多步计算和概念关联，需要综合分析能力来判断模型适用性。 | 难度: 在选择题中属于中等难度，需要理解位错密度与角度θ的关系，并能从计算结果中综合分析出模型适用性的结论。题目涉及多步计算和概念关联，但选项本身提供了明确的结论线索，不需要进行更深层次的分析或论述。" + }, + { + "idx": 1989, + "question": "Calculate the shear stress required for slip to occur in a nickel crystal with this F-R dislocation source. Given that for Ni, G=7.9×10^10 Pa, a=0.350 nm.", + "answer": "τ_Ni=1.95×10^7 Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算镍晶体中滑移所需的剪切应力），并给出了具体的材料参数（G=7.9×10^10 Pa, a=0.350 nm）和最终数值答案（τ_Ni=1.95×10^7 Pa），这符合计算题的特征。 | 知识层次: 题目要求直接应用弗兰克-瑞德位错源公式进行单步计算，仅需代入给定参数（G和a）即可求解剪切应力，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目要求直接应用F-R位错源的基本公式计算剪切应力，仅需简单代入给定参数（G和a）并进行一步计算即可得出结果，无需组合多个公式或进行复杂分析。" + }, + { + "idx": 1990, + "question": "If the dislocation density in a certain crystal is known to be ρ=10^6~10^7 cm/cm^3, and the average length of F-R dislocation sources measured experimentally is 10^-4 cm, determine the number of F-R dislocation sources in the dislocation network.", + "answer": "Assuming that the dislocation lines in the crystal are entangled and mutually pinned, the possible number of dislocation sources is n= ρ/L=10^10~10^11 per cm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的数值和公式进行计算，以确定F-R位错源的数量。答案是通过数值计算得出的具体数值范围，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的位错密度和平均长度直接套用公式n=ρ/L进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（n= ρ/L）进行计算，无需多个公式组合或复杂分析。属于单一公式直接计算的难度等级。" + }, + { + "idx": 1991, + "question": "Given the Burgers vector b=0.25 nm, if the misorientation angle θ of the symmetric tilt grain boundary is 1°, calculate the distance between dislocations at the grain boundary.", + "answer": "When θ=1°, D=14 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的Burgers向量和错向角计算晶界位错间距，需要应用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求应用基本公式（Burgers vector与位错间距的关系公式）进行简单计算，无需多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了Burgers向量和晶界错向角，只需要应用基本公式D = b/θ（需注意角度转换为弧度）即可直接计算出位错间距。解题步骤简单，无需复杂推导或多公式组合，属于最基础的应用题类型。" + }, + { + "idx": 1992, + "question": "If a piece of iron is heated to $850^{\\\\circ}\\\\mathrm{C}$ and then rapidly cooled to $20^{\\\\circ}\\\\mathrm{C}$, calculate how many times the number of vacancies should increase before and after the treatment (assuming the energy required to form one mole of vacancies in iron is 104600J)", + "answer": "$0.616\\\\times10^{14}$ times", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算空位数量增加的倍数），需要使用公式（空位浓度公式）并给出具体数值结果 | 知识层次: 题目需要应用空位浓度公式进行多步计算，涉及温度变化对空位数量的影响，需要理解并关联热力学参数与材料微观结构变化的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解空缺形成能的概念，掌握阿伦尼乌斯方程的应用，并进行多步计算（包括温度转换、指数运算等）。虽然题目提供了关键参数，但解题过程涉及综合分析和精确计算，属于典型的综合性计算问题。" + }, + { + "idx": 1993, + "question": "Among the three common crystal structures of metals, which structure cannot serve as a space lattice?", + "answer": "Hexagonal close-packed structure", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从三种常见的金属晶体结构中选择一个不能作为空间点阵的结构，属于从多个选项中选择正确答案的类型 | 知识层次: 题目考查对金属常见晶体结构及其空间点阵特性的基础概念记忆，属于定义和分类层面的记忆性知识 | 难度: 在选择题型中，此题需要考生理解三种常见金属晶体结构（体心立方、面心立方和六方密堆）的基本概念，并能够区分空间点阵（Bravais点阵）与晶体结构的区别。虽然题目考察的是基础概念记忆，但需要一定的概念辨析能力，因为六方密堆结构本身不是空间点阵（它需要两个点来描述完整结构）。这比单纯记忆定义（等级1）要求稍高，但不需要复杂的分析过程（等级3）。" + }, + { + "idx": 1994, + "question": "In the expression for calculating the force on dislocation motion, $f=\\tau b$, what does $\\tau$ refer to?", + "answer": "The resolved shear stress of the external force in the slip direction on the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号$\\tau$的含义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对位错运动中基本概念的记忆和理解，即τ的定义和物理意义，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆类型，仅需回忆并识别$\\tau$的定义。在选择题型中，这种直接考查定义的问题属于最简单的难度等级，不需要复杂的分析或推理步骤。" + }, + { + "idx": 1995, + "question": "If a face-centered cubic crystal has a unit dislocation with b=α/2[1̄01] and a partial dislocation with b=a/6[121̄], these two dislocations meet and undergo a dislocation reaction. Write the Burgers vector of the resulting dislocation and specify the type of the resulting dislocation.", + "answer": "bŝ=a/3[1̄11]; this dislocation is a Frank partial dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出反应后的位错的Burgers向量并指定其类型，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目涉及位错反应的计算和结果类型的判断，需要理解位错矢量的合成规则和Frank不全位错的定义，属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。需要掌握位错反应的基本原理，能够正确计算Burgers矢量的合成，并识别Frank不全位错的特性。解题步骤涉及矢量运算、位错类型判断等综合分析过程，超出了简单记忆或单一概念应用的范畴。同时，题目要求将计算结果与位错类型相关联，体现了多角度分析的要求。在选择题型内，这种需要多步计算和概念关联的题目属于较难水平。" + }, + { + "idx": 1996, + "question": "What is the difference between a space lattice and a crystal lattice?", + "answer": "A crystal lattice, also known as a crystal structure, refers to the specific arrangement of atoms; whereas a space lattice abstracts atoms as pure geometric points by ignoring their volume.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的区别，答案需要文字论述和解释，没有提供选项或要求判断对错或进行数值计算。 | 知识层次: 题目考查对空间点阵和晶体点阵这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个相关概念（空间点阵和晶体点阵）的比较，但正确选项提供了清晰的定义和区分，不需要复杂的推理或深入的概念体系理解。主要考察的是对基础概念的记忆和简单解释能力，符合等级2“概念解释和描述”的要求。" + }, + { + "idx": 1997, + "question": "How are jogs generally formed on dislocation lines?", + "answer": "Intersection of dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释位错线上jog的形成方式，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查位错线上jog形成的基本概念，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"jogs\"在位错线上的形成方式。正确选项直接给出了定义性的答案（Intersection of dislocations），不需要任何解释或推理过程。这属于最基本的知识点回忆型题目，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1998, + "question": "Can a dislocation loop be formed by inserting a columnar half-atom plane in a crystal?", + "answer": "No. Because a dislocation loop can only be formed when the crystal inside the loop undergoes slip while the crystal outside does not.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（\"Can a dislocation loop be formed...\"），答案直接给出对错判断（\"No\"）并简要解释原因，符合判断题的特征。 | 知识层次: 题目考查对位错环形成条件的基本概念的理解和记忆，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解位错环的形成机制，并能够区分插入半原子平面与位错环形成的不同条件。正确选项的解释需要考生对位错环的形成原理有一定的理解，而不仅仅是简单的定义记忆。因此，该题目在选择题型中属于概念理解的对错判断难度等级。" + }, + { + "idx": 1999, + "question": "When a dislocation is subjected to force, its motion direction is everywhere perpendicular to the dislocation line and can vary during movement. What should be the direction of the relative sliding of the crystal?", + "answer": "It is always the direction of the Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶体相对滑动的方向，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目需要理解位错运动的基本原理，并能够将位错线的运动方向与晶体的相对滑动方向联系起来。这涉及到对位错和Burgers向量的概念的综合应用，而不仅仅是简单的记忆或直接套用。虽然不需要复杂的推理或创新应用，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解位错运动的基本概念、Burgers矢量的定义以及它们之间的关系。题目要求考生能够将位错线的运动方向与晶体的相对滑动方向联系起来，并进行综合分析。虽然不涉及复杂的计算，但需要对相关概念有较深的理解和关联能力。" + }, + { + "idx": 2000, + "question": "The atomic radius is related to the crystal structure. How does the atomic radius change when the coordination number of the crystal structure decreases?", + "answer": "The atomic radius contracts. This is because the atom tries to maintain the volume it occupies as unchanged or with minimal change [the volume occupied by the atom $V_{A}=$ the volume of the atom () + the interstitial volume]. When the coordination number of the crystal structure decreases, the interstitial volume increases. To maintain the balance of the above equation, the atomic radius must contract.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释原子半径如何随配位数变化，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要理解原子半径和配位数之间的关系，还需要解释原子半径收缩的机理，涉及体积守恒的概念和平衡方程的维持，需要综合运用多个概念进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解原子半径与晶体结构的关系，还需要深入掌握配位数变化对原子半径影响的机理。正确选项涉及复杂的体积守恒原理和间隙体积概念，需要考生进行多步推理分析（从配位数变化→间隙体积变化→原子半径补偿性收缩）。这种在选择题中要求综合运用多个高阶概念并解释深层机理的题目，远超出基础记忆或简单应用层面，属于复杂现象全面分析的难度范畴。" + }, + { + "idx": 2001, + "question": "What is the interface with the lowest interfacial energy?", + "answer": "Coherent interface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种界面具有最低的界面能，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断 | 知识层次: 题目考查对界面能基本概念的记忆和理解，特别是不同类型界面（如共格界面、半共格界面、非共格界面）的界面能高低比较。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"Coherent interface\"作为界面能最低的界面类型，属于基础概念的直接回忆。题目不涉及概念解释或复杂分析，仅需简单识别正确选项，因此属于最低难度等级。" + }, + { + "idx": 2002, + "question": "Is the statement 'Small-angle grain boundaries are all formed by edge dislocations arranged into walls' correct?", + "answer": "No. Twist boundaries are formed by crossed screw dislocations of the same sign.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的正确性（'Small-angle grain boundaries are all formed by edge dislocations arranged into walls'），答案直接给出了该陈述是错误的（No）并提供了正确的解释。这符合判断题的特征，即判断陈述的对错并简要说明原因。 | 知识层次: 题目考查对晶界类型和位错排列的基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。题目考察学生对小角度晶界形成机制的理解，需要区分边缘位错和螺旋位错在晶界形成中的作用。虽然涉及基础概念记忆，但需要将定义和分类知识应用到具体情境中进行判断，比单纯的正误判断稍复杂，但不需要多概念比较分析。" + }, + { + "idx": 2003, + "question": "A subgrain boundary is composed of $n$ edge dislocations with a misorientation of $0.057^{\\\\circ}$. Assuming there is no interaction between the dislocations before forming the subgrain boundary, by what factor does the distortion energy change after forming the subgrain boundary (given $R{=}10^{-4}$, $r_{0}=b=10^{-8}$; after forming the subgrain boundary, $$ R=D\\\\approx{\\\\frac{b}{\\\\theta}})?", + "answer": "The distortion energy is 0.75 times the original value (indicating that the dislocation energy decreases after forming the subgrain boundary).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及能量变化的计算和给定的参数条件。答案提供了具体的计算结果，表明这是一个需要计算步骤的问题。 | 知识层次: 题目涉及多步计算和概念关联，需要应用位错能量公式和亚晶界形成后的能量变化计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及位错、亚晶界、畸变能等多个材料科学概念，需要进行多步计算和综合分析。虽然题目提供了部分参数和公式，但仍需要考生具备一定的计算能力和概念关联能力，才能正确评估畸变能的变化。这比简单的概念选择题要复杂，但比需要复杂多变量计算的题目要简单一些。" + }, + { + "idx": 2004, + "question": "What are the characteristics of atomic arrangement in ordered alloys?", + "answer": "An ordered solid solution, where atoms of each component occupy their respective Bravais sublattices, known as sublattices. The entire solid solution forms a complex lattice composed of the sublattices of each component, also referred to as a superlattice or superstructure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释有序合金中原子排列的特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查有序合金中原子排列的基本特征，属于对基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及有序合金的原子排列特征，但正确选项已经提供了明确的定义和描述，包括Bravais亚晶格、复杂晶格等关键概念。考生需要理解并记忆这些基本概念，但不需要进行复杂的分析或比较。因此，该题目在选择题型内属于概念解释和描述的难度等级。" + }, + { + "idx": 2005, + "question": "What is the relationship between the atomic arrangement and bonding in ordered alloys?", + "answer": "This arrangement is related to the bonding energy (bond) between atoms. The greater the bonding energy, the less likely the atoms are to combine. If the bonding energy between dissimilar atoms is less than that between similar atoms, i.e., E_{A B}<(E_{A A}+E_{B B})/2, then the solute atoms will exhibit partially ordered or completely ordered arrangements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释原子排列与键合之间的关系，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及原子排列与键能关系的分析，需要理解键能对原子排列顺序的影响，并进行简单的比较和判断（E_{A B}<(E_{A A}+E_{B B})/2）。这属于中等应用层次，需要将基本概念与实际情况关联，并进行一定的综合分析。 | 难度: 在选择题型中，该题目需要考生理解原子排列与键能之间的复杂关系，并进行多步计算和概念关联。题目不仅要求掌握键能的基本概念，还需要综合分析不同原子间键能的比较（E_{AB}与(E_{AA}+E_{BB})/2的关系），从而推导出溶质原子的排列方式（部分有序或完全有序）。这种需要多角度分析和论述的题目，在选择题型中属于较高难度。" + }, + { + "idx": 2006, + "question": "Why do many ordered alloys become disordered at high temperatures?", + "answer": "The driving force for ordering is the mixing energy parameter (=AB一 (ε^{m}=ε_{A B}-1/2(E_{A A}+E_{B B}))ε^{m}<0, while the resistance to ordering is the configurational entropy; increasing temperature enhances the contribution of the latter to the free energy (-T S), and beyond a certain critical temperature, the disordered solid solution becomes more stable, causing the ordered solid solution to disappear and transform into a disordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么有序合金在高温下会变得无序，答案提供了详细的文字解释和论述，涉及热力学参数和熵的概念，没有涉及计算或选择判断。 | 知识层次: 题目需要综合运用热力学和材料科学的知识，解释有序合金在高温下无序化的机理。涉及混合能参数、构型熵、自由能等概念的关联分析，以及温度对系统稳定性的影响，属于复杂的推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解有序合金的基本概念，还需要深入掌握混合能参数和构型熵的相互作用机制。解题过程涉及多个复杂步骤：1) 理解ε^m的定义及其与有序化的关系 2) 认识温度对自由能中熵项的影响 3) 综合分析这些因素如何共同决定相稳定性 4) 推导临界温度的存在及其物理意义。这些要求都超出了选择题型的常规考查范围，需要考生具备将热力学原理与材料科学知识进行复杂整合的能力，属于\"复杂现象全面分析\"的最高认知层次。" + }, + { + "idx": 2007, + "question": "Analyze the type of solid solution formed by H in α-Fe and γ-Fe, their locations, and the solubility (mole fraction). The atomic radii of the elements are as follows: H: 0.046 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "H forms an interstitial solid solution in α-Fe. Due to the significant difference in size factors, the solubility (mole fraction) is very small. The location of H in α-Fe is mostly at the octahedral interstitial centers. The solubility decreases rapidly with decreasing temperature. In γ-Fe, H also forms an interstitial solid solution, located at the octahedral interstitial centers, with slightly higher solubility than in α-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析H在α-Fe和γ-Fe中形成的固溶体类型、位置和溶解度，需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析氢在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，涉及多个概念的关联和综合分析。需要理解间隙固溶体的形成条件、原子半径的影响、间隙位置的选择以及温度对溶解度的影响等。虽然不涉及复杂的计算或机理的深入解释，但需要对多个知识点进行综合应用和分析。 | 难度: 在选择题型中，该题目属于较高难度，要求考生不仅理解间隙固溶体的基本概念，还需要掌握不同晶体结构（α-Fe和γ-Fe）中间隙位置的特点，并能分析原子半径差异对溶解度的影响。此外，题目还涉及温度对溶解度的复杂影响，需要多角度分析和综合判断。正确选项的表述也较为复杂，包含多个关键知识点和逻辑关系，对考生的综合分析能力要求较高。" + }, + { + "idx": 2008, + "question": "The known solid solubility limits (mole fractions) of elements such as Cd, Zn, Sn, and Sb in Ag are x_Cd=42.5×10^-2, x_Zn=20×10^-2, x_Sn=12×10^-2, x_Sb=7×10^-2, respectively, and their atomic diameters are 0.3042 nm, 0.314 nm, 0.316 nm, 0.3228 nm, while Ag is 0.2883 nm. Analyze the reasons for the differences in their solid solubility limits (mole fractions).", + "answer": "When the atomic size factors are similar, the solid solubility limits (mole fractions) of the above elements in Ag are influenced by the atomic valence factor, i.e., the valence electron concentration e/a is an important factor determining the solid solubility limit (mole fraction). Their valences are 2, 3, 4, and 5, respectively, while Ag is 1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析不同元素在银中的固溶度差异的原因，答案提供了详细的文字解释和论述，涉及原子尺寸因素和价电子浓度的影响，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析不同元素在银中的固溶度差异的原因，涉及原子尺寸因素和价电子浓度（e/a）的综合影响。这需要理解固溶度的决定因素，并能将原子尺寸和价电子浓度这两个关键因素关联起来进行综合分析。此外，还需要对不同元素的价态进行比较和推理，属于对材料科学中固溶度理论的深入应用和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握固溶度极限的基本概念，还需要理解原子尺寸因素和原子价因素对固溶度的影响。解题过程中需要综合运用多个知识点（原子直径、价电子浓度等），并进行复杂的推理分析。此外，题目涉及多个元素的比较分析，要求考生能够解释不同元素在银中固溶度差异的机理，这需要较高层次的理解和分析能力。因此，在选择题型内，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 2009, + "question": "Calculate the electron concentration at the solid solubility limit (mole fraction) for Cd, Zn, Sn, and Sb, given their valences are 2, 3, 4, and 5 respectively, Ag is 1, and the solid solubility limits (mole fractions) are x_Cd=42.5×10^-2, x_Zn=20×10^-2, x_Sn=12×10^-2, x_Sb=7×10^-2", + "answer": "The electron concentration at the solid solubility limit can be calculated using the formula c=Z_A(1-x_B)+Z_Bx_B. Here, Z_A and Z_B are the numbers of valence electrons for components A and B respectively; x_B is the mole fraction of component B. The electron concentration for Cd=1×(1-0.425)+2×0.425=1.43; for Zn=1×(1-0.20)+3×0.20=1.42; for Sn=1×(1-0.12)+4×0.12=1.39; for Sb=1×(1-0.07)+5×0.07=1.31.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出具体的电子浓度数值。解答过程涉及公式应用和数值代入，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，需要理解电子浓度的计算公式并代入给定的数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求直接套用给定的公式c=Z_A(1-x_B)+Z_Bx_B进行计算，无需额外的概念理解或复杂的解题步骤。每个元素的电子浓度计算都是独立且重复的简单算术操作，属于基础的应用题。" + }, + { + "idx": 2010, + "question": "Analyze the type of solid solution formed by N in α-Fe and γ-Fe, their locations, and the solubility (mole fraction). The atomic radii of the elements are as follows: N: 0.071 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "N forms an interstitial solid solution in α-Fe, with a maximum solubility (mole fraction) of about 0.1×10^-2 at 590°C, decreasing to 0.001×10^-2 at room temperature. In α-Fe, N is mostly located at the octahedral interstitial sites. In γ-Fe, N forms an interstitial solid solution, located at the octahedral interstitial sites, with a maximum solubility (mass fraction) of about 2.8×10^-2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析N在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析N在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，涉及多个概念的综合应用，包括固溶体类型、原子半径比较、溶解度变化等。需要理解并关联多个知识点，进行一定的分析和解释，但不需要复杂的推理或创新设计。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解间隙固溶体的基本概念，还需要掌握N在α-Fe和γ-Fe中的具体位置（八面体间隙）以及在不同温度下的溶解度变化。此外，题目还涉及原子半径的比较和不同晶体结构（α-Fe和γ-Fe）对固溶度的影响，需要考生进行多角度分析和综合判断。这些要求超出了简单的概念记忆，需要较深的理解和应用能力。" + }, + { + "idx": 2011, + "question": "The intermetallic compound AlNi has a CsCl-type structure with a lattice constant of $a=0.288\\\\mathrm{~nm}$. Calculate its density (the relative atomic mass of Ni is 58.71, and the relative atomic mass of Al is 26.98).", + "answer": "Density $\\\\rho=5.97~\\\\mathrm{g}/\\\\mathrm{cm}^{3}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解密度，答案是一个具体的数值结果。 | 知识层次: 题目要求计算密度，涉及基本公式应用（密度计算公式）和简单计算（代入已知数值进行计算），不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用密度计算公式，即$\\rho = \\frac{Z \\times M}{a^3 \\times N_A}$，其中$Z$为晶胞中的原子数（CsCl结构$Z=1$），$M$为摩尔质量，$a$为晶格常数，$N_A$为阿伏伽德罗常数。题目已提供所有必要参数，计算过程仅涉及单位换算和简单代数运算，无需多步骤推导或复杂概念理解，属于单一公式直接计算的等级1难度。" + }, + { + "idx": 2012, + "question": "Analyze the type of solid solution formed by C in α-Fe and γ-Fe, their locations, and the solubility (mole fraction). The atomic radii of the elements are as follows: C: 0.077 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "In α-Fe, C forms an interstitial solid solution, with the maximum solubility (mole fraction) reaching 0.0218×10^-2 at 727°C and decreasing to 0.006×10^-2 at room temperature. The location of C in α-Fe is mostly at the octahedral interstitial centers. In γ-Fe, C forms an interstitial solid solution located at the octahedral interstitial centers, with the maximum solubility (mass fraction) being 2.11×10^-2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析碳在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度（摩尔分数），需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目需要分析碳在α-Fe和γ-Fe中的固溶体类型、位置以及溶解度，涉及多步概念关联和综合分析。虽然题目给出了原子半径等基础数据，但需要理解间隙固溶体的形成条件、不同温度下的溶解度变化以及间隙位置的选择等中等复杂度的知识点。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅理解间隙固溶体的基本概念，还需要掌握碳在α-Fe和γ-Fe中的具体位置（八面体间隙中心）以及不同温度下的溶解度变化。此外，题目还涉及原子半径数据的隐含应用，需要考生进行多步计算和综合分析。这些要求超出了简单记忆或单一概念的应用，属于多角度分析论述的范畴。" + }, + { + "idx": 2013, + "question": "Why can only the two components of substitutional solid solutions mutually dissolve infinitely, while interstitial solid solutions cannot?", + "answer": "This is because when a solid solution forms, the dissolution of solute atoms causes lattice distortion in the solvent structure, thereby increasing the system's energy. The greater the difference in atomic size between the solute and solvent, the more severe the lattice distortion, leading to higher distortion energy, lower structural stability, and smaller solubility. Generally, the lattice distortion caused by solute atoms in interstitial solid solutions is more significant, so they cannot mutually dissolve infinitely but only have limited solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么置换固溶体可以无限互溶而间隙固溶体不能，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释置换固溶体和间隙固溶体在无限互溶方面的差异，涉及晶格畸变、系统能量变化、原子尺寸差异对溶解度的影响等复杂机理分析，需要综合运用多个概念并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2014, + "question": "The density of ZnS is $4.1~\\\\mathrm{Mg}/\\\\mathrm{m}^{3}$, calculate the distance between the centers of the two ions based on this", + "answer": "The distance between the centers of the two ions is $0.234\\\\mathrm{~n}\\\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的密度数据进行计算，得出两个离子中心之间的距离。答案是一个具体的数值结果（0.234 nm），这表明需要通过公式和数值计算来解决问题，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度与晶格参数的关系推导，以及离子间距的计算，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但比简单的公式应用要求更高。 | 难度: 在选择题中属于中等偏上难度，需要综合运用密度计算、晶体结构知识和单位换算等多步骤计算过程。题目要求考生根据密度数据反推离子间距，涉及对ZnS晶体结构的理解（如闪锌矿结构）、阿伏伽德罗常数的应用以及立方晶系几何关系的推导。虽然选择题提供了正确选项可以部分降低难度，但仍需要考生具备较强的综合分析能力和计算技巧，属于需要多概念关联的综合性计算问题。" + }, + { + "idx": 2015, + "question": "The maximum solid solubility (mole fraction) of carbon in γ-Fe is x_C=8.9×10^-2. Given that C atoms occupy octahedral interstitial sites, calculate the percentage of octahedral interstitial sites occupied by C atoms.", + "answer": "The percentage of octahedral interstitial sites occupied by C atoms is 10.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳原子占据八面体间隙的百分比），并给出了具体的数值答案（10.2%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及固溶体最大固溶度的概念、晶格间隙位置的计算以及百分比转换，需要综合运用材料科学中的相关知识和公式。虽然不涉及复杂的机理分析或创新设计，但思维过程要求一定的深度和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体、间隙位置和浓度计算等多个概念，并进行多步计算和综合分析。虽然题目提供了关键数据，但需要正确应用晶体学知识和数学转换才能得出正确答案。" + }, + { + "idx": 2016, + "question": "Calculate the distance between the center of a sodium ion and its nearest neighboring positive ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.393nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子与其最近邻正离子之间的距离），并给出了具体的离子半径数据。答案是一个具体的数值（0.393nm），需要通过公式应用和计算得出。 | 知识层次: 题目要求应用给定的离子半径数据进行简单计算，直接套用离子间距公式（半径相加），无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用给定的离子半径数据进行简单加法计算（Na+半径 + Cl−半径 = 0.097nm + 0.181nm = 0.278nm），然后乘以√2（因为NaCl晶体结构中最近邻正离子位于面心立方位置）得到最终距离0.393nm。整个过程仅涉及单一晶体学距离公式的直接套用，无需多步骤推导或复杂概念整合，属于最基础的计算类选择题。" + }, + { + "idx": 2017, + "question": "The maximum solid solubility (mole fraction) of nitrogen in γ-Fe is x_N=10.3×10^-2. Given that N atoms occupy octahedral interstitial sites, calculate the percentage of octahedral interstitial sites occupied by N atoms.", + "answer": "The percentage of octahedral interstitial sites occupied by N atoms is 12.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算氮原子占据八面体间隙的百分比），并给出了具体的数值和公式应用（最大固溶度和间隙位置信息）。答案也是一个具体的数值结果。 | 知识层次: 题目需要应用给定的最大固溶度数据，结合晶体结构中八面体间隙位置的基本知识，进行简单的百分比计算。虽然涉及晶体结构的概念，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需应用给定的最大固溶度（mole fraction）数据，并直接计算占据八面体间隙位置的氮原子百分比。解题步骤简单直接，无需多个公式组合或复杂分析，符合等级1的标准。" + }, + { + "idx": 2019, + "question": "Calculate the distance between the center of a sodium ion and the next nearest Cl− ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.482nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子和氯离子之间的距离），并给出了具体的半径数据，解答过程需要应用公式和计算步骤，最终答案是一个具体的数值（0.482nm）。 | 知识层次: 题目要求应用基本公式（离子半径相加）进行简单计算，属于直接套用已知数据进行一步运算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算NaCl晶体中钠离子与下一个最近氯离子之间的距离，只需应用简单的晶体几何关系（如面心立方结构中离子间距的计算公式）和给定的离子半径进行直接相加即可得出答案。解题步骤简单，无需复杂的推导或多步计算，符合等级1的定义。" + }, + { + "idx": 2020, + "question": "Analyze the type of solid solution formed by B in α-Fe and γ-Fe, its location, and the solubility (mole fraction). The atomic radii of the elements are as follows: B: 0.091 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "In α-Fe, due to the larger atomic size of B, it is more difficult to dissolve interstitially, sometimes partially dissolving substitutionally, forming interstitial or substitutional solid solutions, with relatively low solubility. In γ-Fe, B forms an interstitial solid solution, located at the center of octahedral interstitial sites, with slightly higher solubility than in α-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析B在α-Fe和γ-Fe中形成的固溶体类型、位置和溶解度，需要文字解释和论述，答案也是以文字形式详细解释，符合简答题的特征。 | 知识层次: 题目要求分析B在α-Fe和γ-Fe中形成的固溶体类型、位置和溶解度，涉及原子半径比较、固溶体类型判断以及溶解度差异的解释。这需要理解固溶体的基本概念，并能将原子半径与固溶体类型关联起来，同时进行综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和解释，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生综合理解原子半径差异对固溶体类型的影响，同时分析不同晶体结构（α-Fe和γ-Fe）中溶质原子的溶解方式和位置选择。题目涉及多个概念的关联（间隙固溶体、置换固溶体、八面体间隙位置）和比较分析（两种铁的同素异构体中的溶解度差异），解题步骤较为复杂，需要考生具备较强的综合分析能力。在选择题型内，这类需要多角度分析论述的题目属于较高难度等级。" + }, + { + "idx": 2021, + "question": "Calculate the distance between the center of a sodium ion and the third nearest Cl− ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.622nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子与第三近邻氯离子之间的距离），并给出了具体的离子半径数据，需要使用公式和计算步骤来得出最终答案0.622nm。 | 知识层次: 题目需要理解NaCl晶体结构，应用离子半径和晶体几何关系进行多步计算，涉及空间几何概念和数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构的基本概念（如离子半径、晶格排列），并能够进行多步计算（确定晶格常数、计算第三近邻距离）。虽然题目给出了离子半径，但需要考生综合运用这些信息来推导正确答案，涉及概念关联和综合分析能力。" + }, + { + "idx": 2022, + "question": "A common polymer has C2H2Cl2 as its monomer, with an average molecular weight of 60000u (using the relative atomic masses of the elements as Ar(C)=12, Ar(H)=1, Ar(Cl)=35.5). What is its degree of polymerization?", + "answer": "The degree of polymerization is n = 60000 / 97 = 620", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（分子量计算和聚合度计算），并应用相关公式（聚合度 = 聚合物分子量 / 单体分子量）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目考查基本的公式应用和简单计算，只需要将聚合物的平均分子量除以单体的分子量即可得到聚合度，属于直接套用公式的计算题。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（分子量除以单体分子量）进行简单计算，无需额外的概念理解或复杂步骤。属于单一公式直接计算的难度等级。" + }, + { + "idx": 2023, + "question": "A solid solution contains xMgO=30/10−2 and xLiF=70/10−2. What are the mass fractions of Li+, Mg2+, F−, and O2−?", + "answer": "wLi+=16/10−2, wMg2+=24/10−2, wF−=44/10−2, wO2−=16/10−2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算得出各离子的质量分数，需要应用化学计量和质量分数的计算公式，答案以具体数值形式给出。 | 知识层次: 题目涉及基本公式应用和简单计算，需要将摩尔分数转换为质量分数，属于直接套用公式的计算题，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用质量分数的基本公式，但计算步骤直接且无需复杂转换。题目提供了摩尔分数，只需简单转换为质量分数，属于选择题中较为基础的题型。" + }, + { + "idx": 2024, + "question": "A ceramic insulator contains $1\\\\%$ (by volume) of pores after sintering, with the pores being cubes of side length $13.7\\\\mathrm{mm}$. If during the manufacturing process, the powder can be pressed to contain $24\\\\%$ pores, what should the size of the mold be?", + "answer": "The size of the mold should be $l=15.0\\\\mathrm{~mm}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定模具的尺寸。答案给出了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及孔隙率和尺寸变化的概念关联，需要综合分析初始和最终状态的关系，并应用相关公式进行计算。虽然不涉及复杂的机理分析或创新设计，但思维过程要求高于简单的公式套用。 | 难度: 在选择题中属于中等偏上难度，需要理解孔隙率与尺寸变化的关系，进行多步计算（包括体积百分比转换和立方体尺寸计算），并综合分析制造工艺参数对最终尺寸的影响。虽然题目提供了关键参数，但解题过程涉及多个概念关联和计算步骤，比单纯的概念选择题更复杂。" + }, + { + "idx": 2025, + "question": "The theoretical strength of amorphous materials is calculated to be $G/6\\\\sim G/4$, where $G$ is the shear modulus. Given $\\\\nu=0.25$, estimate the theoretical strength of glass (an amorphous material) based on its elastic properties (given $E=70~000~\\\\mathrm{MPa}$).", + "answer": "Therefore, the theoretical strength ranges between 0.4E and 0.4E, that is, $$4~900\\\\sim7~000~\\\\mathrm{MPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的弹性模量（E=70 000 MPa）和泊松比（ν=0.25）计算玻璃的理论强度范围。解答过程涉及数值计算和公式应用（G=E/2(1+ν)），最终给出数值结果（4 900~7 000 MPa）。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的弹性模量和泊松比计算理论强度范围，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求基于给定的弹性模量E和泊松比ν，通过基本公式（G=E/[2(1+ν)]）计算剪切模量G，然后直接套用理论强度范围公式（G/6~G/4）进行计算。虽然涉及两个步骤，但都是直接套用基础公式，无需复杂推导或概念整合，因此在选择题型中属于等级2难度。" + }, + { + "idx": 2026, + "question": "Calculate the distance between the centers of sodium ions at the nearest identical positions in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.393nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子之间的距离），并给出了具体的数值答案（0.393nm），这符合计算题的特征。 | 知识层次: 题目主要考查基本公式应用和简单计算，仅需知道离子半径和晶体结构的基本概念，通过简单加法即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算NaCl晶体中最近邻钠离子中心之间的距离，只需应用简单的晶体学距离公式（即离子半径之和的两倍），无需多个步骤或复杂推理。给定离子半径后，计算过程直接且明确，属于基础级别的应用。" + }, + { + "idx": 2027, + "question": "An organic compound has the composition ${w_{\\mathrm{C}}=62.1/10^{-2}}$, ${w_{\\mathrm{H}}}=10.3/1\\\\time10^{-2}$, $\\\\varpi_{0}=27.6/10^{-2}$. Try to write the possible name of the compound.", + "answer": "\\\\mathrm{{C}:\\\\mathrm{{H}:\\\\mathrm{{O}=\\\\frac{62.\\\\mathrm{{1}}}{12.\\\\mathrm{{,011}}}:\\\\frac{10.\\\\mathrm{{3}}}{1.\\\\mathrm{{007}\\\\mathrm{{97}}}}:\\\\frac{27.6}{15.\\\\mathrm{{9994}}}=5.2:10.2:1.7\\\\approx3:6:10.4:1.7\\\\approx3:6:1.74:\\\\mathrm{{8}.\\\\mathrm{{1}:\\\\mathrm{{7}}}}}}} Therefore, the possible compound is $\\\\mathrm{CH}_{3}\\\\mathrm{COCH}_{3}$ (acetone).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的元素组成比例推导出可能的有机化合物名称，并给出详细的推导过程。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求根据给定的元素组成比例计算并推断可能的有机化合物名称，主要涉及基本的化学计量计算和简单的分子式推导，属于基本公式应用和直接套用的范畴。虽然需要一定的计算步骤，但整体思维过程较为直接，不涉及复杂的概念关联或综合分析。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求根据给定的元素组成比例计算并推断可能的有机化合物名称。解题步骤包括基本的化学计量计算和简单的比例转换，最终直接套用常见有机化合物的分子式（丙酮）。选择题型中，这种题目仅需基本公式应用和简单计算，无需复杂的分析或推理过程，因此难度较低。" + }, + { + "idx": 2028, + "question": "Assuming the density of MgO is 3.6 g/cm3 and the density of LiF is 2.6 g/cm3, what is the density of the solid solution?", + "answer": "The density of the solid solution ρ=2.9 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目给出了具体材料的密度数据，要求通过计算得出固溶体的密度。解答过程需要应用密度计算公式，最终给出数值结果。这符合计算题的特征。 | 知识层次: 题目需要应用密度计算公式进行简单计算，属于基本公式的直接套用，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用密度计算公式，属于单一公式直接计算的简单应用。题目提供了所有必要的数据，解题步骤简单明了，无需复杂的推理或多步骤计算，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 2029, + "question": "A common polymer has C2H2Cl2 as its monomer, with an average molecular weight of 60000u (using the relative atomic masses of the elements as Ar(C)=12, Ar(H)=1, Ar(Cl)=35.5). Calculate the mass of the monomer.", + "answer": "The mass of the monomer is 12×2 + 1×2 + 35.5×2 = 97u/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算单体的质量），并给出了具体的原子质量和计算公式，答案也是通过计算得出的具体数值。 | 知识层次: 题目仅需应用基本化学公式进行简单的分子量计算，无需多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行简单的原子质量相加计算，无需复杂的推理或多步骤操作。属于单一公式直接计算的难度等级。" + }, + { + "idx": 2030, + "question": "What are the types of silicate structures", + "answer": "Silicates are divided into the following categories: (1) silicates containing finite silicon-oxygen groups; (2) chain silicates; (3) layer silicates; (4) framework silicates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举硅酸盐结构的类型，答案以文字形式详细描述了不同类型的硅酸盐结构，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确记忆并区分四种不同的硅酸盐结构类型。这比单纯记忆一个定义（等级1）要求更高，但不需要进行复杂的分析或阐述（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 2031, + "question": "Why can rapid changes in external temperature cause many ceramic devices to crack or break?", + "answer": "Because most ceramics are mainly composed of crystalline and glass phases, and the thermal expansion coefficients of these two phases differ significantly. When rapidly cooled from high temperatures, the different contractions of each phase generate internal stresses sufficient to cause the ceramic devices to crack or break.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷器件在外部温度快速变化时开裂或断裂的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释陶瓷材料在温度快速变化时开裂或断裂的机理，涉及不同相的热膨胀系数差异及其导致的内部应力，这需要对材料的多相结构、热力学行为及其相互作用有较深入的理解和分析能力。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2032, + "question": "A polymeric material contains polyvinyl chloride, with 900 monomers in one molecule. If each molecule can be stretched into a linear molecule, calculate the theoretically maximum strain that can be achieved for this polymer (assuming the bond length of each C-C bond is $0.154\\\\mathrm{nm}$).", + "answer": "The theoretically maximum strain is $3380\\\\%$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算最大应变），并给出了具体的输入参数（单体数量、键长）和输出结果（应变百分比）。解答过程需要应用公式和数学计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括单体数量、键长计算和应变公式应用），并需要理解聚合物链的线性拉伸概念，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解聚合物分子链的拉伸概念、单体数量与总长度的关系，并进行多步计算（包括单位转换和百分比计算）。虽然题目提供了明确的参数和公式，但解题过程涉及多个步骤的综合分析，对学生的应用能力和计算准确性要求较高。" + }, + { + "idx": 2033, + "question": "Describe the thermodynamic conditions of crystallization phase transition", + "answer": "Analysis of the change in system free energy during crystallization phase transition shows that the thermodynamic condition for crystallization is ΔG<0. From the change in free energy per unit volume ΔGB=-LmΔT/Tm, it can be seen that only when ΔT>0 can ΔGg<0 be achieved. That is, only undercooling can make ΔG<0.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述结晶相变的热力学条件，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析结晶相变的热力学条件，涉及系统自由能变化和单位体积自由能变化的计算，需要理解并应用相关公式（ΔG<0和ΔGB=-LmΔT/Tm），同时需要关联概念（过冷度ΔT>0）来综合解释热力学条件。这属于中等应用层次，需要多步推理和概念关联。 | 难度: 在选择题中属于较高难度，题目要求分析结晶相变的热力学条件，涉及系统自由能变化、单位体积自由能变化以及过冷度等概念的综合理解和计算。需要考生能够将多个热力学概念关联起来，并进行多步推导和分析，才能得出正确的结论。这种题目不仅考察基本概念的理解，还要求考生能够进行综合分析和应用，因此在选择题型中属于较高难度。" + }, + { + "idx": 2034, + "question": "Describe the structural conditions of crystalline phase transformation", + "answer": "The structural fluctuations present in the liquid serve as the foundation for nucleation during crystallization. Therefore, structural fluctuations are the essential structural condition required for the crystallization process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体相变的结构条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述晶体相变的结构条件，涉及对液态结构波动与成核过程之间关系的深入理解，需要综合运用材料科学中的相变理论和结构分析知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解结晶过程中的结构波动及其在成核中的作用，这需要对复杂现象进行全面分析。正确选项不仅涉及机理深度解释，还需要综合运用多个概念进行推理分析。选择题型中，这种题目对知识点的掌握深度和解题能力要求极高，属于复杂现象全面分析的范畴。" + }, + { + "idx": 2035, + "question": "Polyvinyl chloride eccC2H3Cl∂n is dissolved in an organic solvent, with its C-C bond length set at 0.154nm, and the number of bonds in the chain x=2n. For a molecule with a molecular mass of 28500g, what is its root mean square length?", + "answer": "Root mean square length 4.65nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解根均方长度，答案是一个具体的数值结果（4.65nm），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括分子量的计算、键数的确定以及均方根长度的公式应用，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或创新应用，但需要一定的计算步骤和概念理解。 | 难度: 在选择题中属于中等偏上难度，需要理解聚合物链的构象统计概念（如均方根长度公式），进行分子量到聚合度的转换计算（n=M/M0），并正确应用键长和键数关系（x=2n）。虽然题目提供了关键参数（键长0.154nm），但需要综合运用高分子物理和数学计算知识，涉及多步骤推导（包括开方运算），比单纯的概念选择题更复杂，但选项的存在降低了完全推导错误的可能性。" + }, + { + "idx": 2036, + "question": "For a copolymer ABS with equal mass fractions of each component, what is the ratio of the monomers (A—acrylonitrile; B—butadiene; S—styrene)?", + "answer": "The mole fractions of the monomers are \\n\\n$$\\nx_{\\\\#Z\\\\#}=20/10^{-2},\\\\quad x_{\\\\sf T\\\\lceil-w\\\\rceil}=40/10^{-2},\\\\quad x_{\\\\#\\\\mathbb{W}\\\\#\\\\mathbb{W}}=40/10^{-2}\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算共聚物ABS中单体的摩尔分数比，需要通过数值计算和公式应用来得出答案。答案中给出了具体的计算结果和数学表达式，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将质量分数转换为摩尔分数，并考虑不同单体的分子量差异，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解共聚物的组成概念，并进行多步计算。题目涉及质量分数与摩尔分数的转换，需要掌握各单体的分子量并进行综合计算。虽然题目给出了正确选项，但解题过程需要较强的化学计算能力和概念关联能力，属于综合性计算问题。" + }, + { + "idx": 2037, + "question": "Polyvinyl chloride C2H3Cln is dissolved in an organic solvent, with its C-C bond length set at 0.154nm, and the number of bonds in the chain x=2n. If the root mean square length is only half of that in (1), what is the molecular mass?", + "answer": "The molecular mass M=7125g.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及分子质量的计算，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括理解聚氯乙烯的分子结构、键长与链长的关系，以及均方根长度的概念。此外，还需要将分子质量的计算与给定的条件关联起来，进行综合分析。虽然不涉及复杂的机理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解聚合物链的构象统计概念（如均方根长度与键数的关系），进行多步计算（包括键数推导、分子量计算），并正确关联题目给出的条件（如键长和键数关系）。虽然题目提供了部分参数，但需要综合运用高分子物理和化学计量知识才能得出正确选项。" + }, + { + "idx": 2038, + "question": "Given that the relative atomic mass of Cu is 63.5 and its density is 8.9 g/cm^3, find the number of atoms in the critical nucleus.", + "answer": "n≈261", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界核中的原子数量，答案是一个具体的数值结果(n≈261)，这符合计算题的特征。 | 知识层次: 题目需要应用相对原子质量和密度等基本概念，通过多步计算（如计算临界核的体积、质量等）来求解原子数目，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解相对原子质量、密度与原子数量之间的关系，并进行多步计算。虽然题目提供了关键参数，但解题过程涉及单位换算和公式应用，属于综合性计算问题。" + }, + { + "idx": 2039, + "question": "If the maximum undercooling during the solidification of pure nickel is 0.18 times its melting point $(t_{\\\\mathrm{m}}=1453^{\\\\circ}\\\\mathrm{C})$, calculate the driving force for solidification. $(\\\\Delta H=-18075.\\\\mathrm{J/mol})$", + "answer": "The driving force for solidification $\\\\Delta G=-3~253.5~\\\\mathrm{J/mol},$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以求解凝固驱动力，答案给出了具体的计算结果。 | 知识层次: 题目要求应用基本公式进行简单计算，涉及驱动力的计算和基本热力学概念的直接应用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解最大过冷度和凝固驱动力之间的关系，但解题步骤相对直接，仅需套用给定的公式进行简单计算即可得出答案。不需要复杂的推导或多步骤计算，因此难度等级为2。" + }, + { + "idx": 2040, + "question": "What are the main bonding types in ceramic materials?", + "answer": "The main bonding types in ceramic materials are ionic bonds and covalent bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释陶瓷材料中的主要键合类型，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查陶瓷材料中主要键合类型的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅要求记忆陶瓷材料的主要键合类型（离子键和共价键），属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接回忆定义性知识，因此在选择题型内属于最简单的难度等级。" + }, + { + "idx": 2041, + "question": "Discuss the energy conditions of crystalline phase transformation", + "answer": "From the critical nucleus formation work oS, it can be seen that when a critical nucleus is formed, 1/3 of the surface energy must still be provided by energy fluctuations in the liquid.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论晶体相变的能量条件，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求讨论晶体相变的能量条件，涉及临界核形成功和表面能等概念的综合运用，需要理解能量波动在相变中的作用，并进行机理层面的解释。这超出了简单记忆或基本应用，属于需要综合分析能力和深度理解的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解晶体相变的能量条件，特别是临界核形成功的概念，并能够分析表面能与液体中能量波动之间的关系。这需要综合运用多个复杂概念，进行机理深度解释和复杂现象全面分析。选择题型中，正确选项涉及的知识点掌握深度要求高，解题步骤复杂，需要考生具备较高的推理分析能力和机理解释能力。因此，在选择题型内属于最高难度水平。" + }, + { + "idx": 2042, + "question": "Describe the kinetic conditions of crystalline phase transformation", + "answer": "The kinetic condition is that the temperature of the liquid at the liquid-solid interface front Tir_k have the potential to nucleate; while embryos with r=r_k may either disappear or grow stably. Therefore, an embryo with radius r_k is called a critical nucleus. Its physical meaning is that the short-range ordered atomic clusters emerging in the undercooled liquid can become nuclei and grow when their size r≥r_k.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"critical nucleus\"进行文字解释和论述，答案提供了详细的定义和物理意义的描述，符合简答题的特征。 | 知识层次: 题目考查对临界核（critical nucleus）这一基本概念的定义和物理意义的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并解释\"critical nucleus\"的定义及其物理意义，而不仅仅是简单的定义复述。题目要求考生能够描述胚胎半径与自由能之间的关系，并解释临界核的物理含义，这比单纯记忆定义要复杂一些。然而，题目并未涉及多个概念的比较分析或复杂概念体系的阐述，因此不属于最高难度等级。" + }, + { + "idx": 2049, + "question": "What is the quantitative relationship between the critical nucleus radius r_k and the undercooling ΔT?", + "answer": "The critical nucleus radius r_k, whose size is related to the undercooling, is given by r_k=(2σT_m)/(L_m)×1/ΔT", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定量描述临界核半径r_k与过冷度ΔT之间的关系，并给出了具体的计算公式，需要应用公式进行计算和推导 | 知识层次: 题目要求应用给定的公式进行定量计算，涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用，即临界核半径与过冷度之间的定量关系。学生只需识别并正确套用给定公式即可作答，无需进行额外的计算或概念分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2050, + "question": "What is dynamic undercooling?", + "answer": "During crystal growth, a certain degree of undercooling in the liquid ahead of the liquid-solid interface is required to satisfy (dN/dt)F>(dN/dt)M. This undercooling is called dynamic undercooling (ΔTl=Tm−Ti), which is a necessary condition for crystal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"dynamic undercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征 | 知识层次: 题目考查动态过冷（dynamic undercooling）的基本定义和原理，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在选择题中属于中等难度，需要理解动态过冷度的定义及其在晶体生长中的作用，但不需要进行复杂的比较分析或多概念整合。" + }, + { + "idx": 2051, + "question": "What are the characteristics of ingot structure?", + "answer": "In the ingot structure, there are generally 3 crystal zones. (1) The outermost layer is the fine-grained zone. Its formation is due to the lower temperature of the mold wall and the larger undercooling of the liquid, resulting in a higher nucleation rate. (2) The middle layer is the columnar crystal zone. Its formation is mainly due to the increase in the temperature of the mold wall, where the growth rate of crystal nuclei is greater than the nucleation rate, and heat dissipation is more favorable in the direction perpendicular to the mold wall. In the fine-grained zone, grains with favorable orientations preferentially grow into columnar crystals. (3) The center is the equiaxed crystal zone. Its formation is due to the further increase in mold wall temperature and the further decrease in liquid undercooling, where the directional heat dissipation of the remaining liquid is no longer obvious, and it is in a state of uniform cooling. At the same time, unmelted impurities, broken dendrites, etc., tend to concentrate in the remaining liquid, all of which promote the formation of equiaxed crystals. It should be noted that not all ingot structures have 3 crystal zones. Due to different solidification conditions, an ingot may only have one type of crystal zone or only two types of crystal zones.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释和描述铸锭结构的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目主要考查对铸锭结构的三个晶区及其形成原因的记忆和理解，属于基础概念的记忆性知识，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及了三个晶体区的特征和形成原因，但正确选项已经提供了完整的解释，学生只需要理解并记忆这些基本概念即可。不需要进行复杂的分析或比较多个概念。因此，该题目在选择题型内属于等级2，即概念解释和描述的难度水平。" + }, + { + "idx": 2052, + "question": "Point out the errors in the following concepts and correct them: (1) The so-called degree of undercooling refers to the difference between the temperature at which a plateau appears on the cooling curve during crystallization and the melting point; while the dynamic degree of undercooling refers to the difference between the actual temperature of the liquid phase during crystallization and the melting point.", + "answer": "The difference between the actual crystallization temperature on the cooling curve and the melting point; the difference between the temperature of the liquid at the liquid-solid interface front and the melting point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行改正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对\"过冷度\"和\"动态过冷度\"这两个基本概念的定义和区别的记忆与理解，属于材料科学中相变基础知识的记忆性内容。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念的记忆，但需要考生准确区分“过冷度”和“动态过冷度”的定义，并理解两者之间的差异。这要求考生不仅记住定义，还需要对概念有一定的理解和应用能力。然而，题目并未涉及复杂的分析或多概念的综合运用，因此难度等级为2。" + }, + { + "idx": 2054, + "question": "What is undercooling?", + "answer": "The temperature difference between the actual crystallization temperature and the theoretical crystallization temperature is called undercooling (ΔT=Tm−Tn). It is required by the thermodynamic conditions of phase transformation. Only when ΔT>0 can the condition that the free energy of the solid phase is lower than that of the liquid phase be achieved. The free energy difference between the liquid and solid phases is the driving force for crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"undercooling\"进行文字解释和论述，答案提供了详细的定义和原理说明，符合简答题的特征。 | 知识层次: 题目考查对undercooling这一基础概念的定义和基本原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但正确选项不仅给出了undercooling的定义，还解释了其热力学条件和结晶驱动力，需要考生理解并描述概念背后的原理。相比仅记忆定义的等级1题目，该题要求更高层次的概念解释能力，但尚未达到需要分析复杂概念体系的等级3难度。" + }, + { + "idx": 2055, + "question": "What is critical undercooling?", + "answer": "In an undercooled liquid, the degree of undercooling at which an embryo can form with a radius equal to the critical nucleus radius is called the critical undercooling (ΔT∗). Clearly, when the actual undercooling ΔT<ΔT∗, even the largest embryo in the undercooled liquid is smaller than the critical nucleus radius, making nucleation difficult. Only when ΔT>ΔT∗ can homogeneous nucleation occur. Therefore, critical undercooling is required for nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"critical undercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对临界过冷度（critical undercooling）这一基本概念的定义和解释，属于基础概念的记忆和理解范畴。虽然涉及一些简单的逻辑关系（如ΔT与ΔT∗的比较），但整体上仍属于对基本原理的阐述，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要理解临界过冷度的定义及其在成核过程中的作用。正确选项不仅给出了定义，还解释了临界过冷度与成核条件的关系，要求考生能够理解并应用这一概念。因此，相较于仅记忆定义的简单题目（等级1），该题目需要更深入的概念解释和描述（等级2）。" + }, + { + "idx": 2056, + "question": "Analyze the basic conditions for the formation of single crystals", + "answer": "The basic condition for forming a single crystal is to ensure that only one nucleus is generated (or only one nucleus can grow) during the crystallization of liquid metal, which then grows into a single crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求分析单晶形成的基本条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查单晶形成的基本条件，属于对基本原理的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆单晶形成的基本条件，即确保在液态金属结晶过程中只产生一个晶核（或只有一个晶核能够生长），从而形成单晶。这需要考生掌握相关的基础概念，但不需要进行复杂的分析或比较多个概念。因此，该题目在选择题型内属于中等难度。" + }, + { + "idx": 2057, + "question": "Given the melting point of Cu tm=1083°C, latent heat of fusion Lm=1.88×10^3 J/cm^3, and specific surface energy σ=1.44×10^5 J/cm^2. Calculate the critical nucleus radius for homogeneous nucleation of Cu at 853°C.", + "answer": "rk=9.03×10^-10 m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数（熔点、潜热、比表面能）和公式计算临界核半径，答案是一个具体的数值结果，解答过程需要数值计算和公式应用。 | 知识层次: 题目需要应用均质形核的临界半径公式，涉及多步计算（包括温度转换、单位统一等），并需要理解表面能、潜热等概念之间的关联。虽然不涉及复杂的机理分析或创新设计，但已超出简单套用公式的范畴，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念（临界核半径、熔化潜热、比表面能等）并进行多步计算（包括温度转换、公式代入等）。虽然题目提供了所有必要参数，但解题过程涉及多个物理概念的关联和综合应用，属于综合性计算问题。" + }, + { + "idx": 2058, + "question": "Point out the errors in the following concepts and correct them: (2) During metal crystallization, atoms transition from a disordered arrangement in the liquid phase to an ordered arrangement in the solid phase, which reduces the entropy of the system, making it a spontaneous process.", + "answer": "Reduces the free energy of the system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对金属结晶过程中热力学基本概念的理解和记忆，主要涉及熵和自由能的变化关系，属于基础概念的记忆和简单应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（金属结晶过程中的熵变和自由能变化），但需要考生不仅记住定义，还要理解熵变和自由能变化之间的关系。题目要求识别错误概念并选择正确表述，这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。因此，该题目属于概念解释和描述层次的难度（等级2）。" + }, + { + "idx": 2059, + "question": "Point out the errors in the following concept and correct them: (8) During the crystallization of certain castings, due to the faster cooling rate, the homogeneous nucleation rate N1 increases, and the heterogeneous nucleation rate N2 also increases. Therefore, the total nucleation rate is N=N1+N2.", + "answer": "Then the total nucleation rate is N=N2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求指出并纠正关于结晶过程中成核速率的错误概念，涉及对均质成核和非均质成核的理解，以及它们在实际结晶过程中的相互作用。这需要学生不仅记住基本概念，还要能够应用这些概念来分析具体情境，并进行适当的修正。思维过程涉及多步分析和概念关联，但不需要复杂的机理推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 2060, + "question": "Point out the errors in the following concepts and correct them: (4) The maximum structural fluctuations appearing in the liquid phase at any temperature are nuclei.", + "answer": "Under a certain degree of undercooling (>ΔT*).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案提供了修正后的概念，符合简答题的特征。 | 知识层次: 题目要求指出并纠正关于液相中最大结构波动的错误概念，这需要深入理解相变理论、成核机理以及过冷度对成核过程的影响。解答不仅需要识别错误，还需要提供正确的科学解释，涉及多个概念的关联和综合分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解\"最大结构波动\"和\"晶核\"的概念，还需要掌握过冷度(ΔT*)的临界条件，并能进行机理层面的深度解释。正确选项涉及复杂的热力学相变条件判断，需要综合运用凝固理论、临界晶核形成条件等多方面知识，属于典型的复杂现象全面分析题型。" + }, + { + "idx": 2061, + "question": "To obtain metallic glass, why is it generally necessary to choose binary systems with a steep liquidus line and thus a low eutectic temperature?", + "answer": "Metallic glass is obtained by ultra-rapid cooling methods, which suppress the liquid-solid crystallization process, resulting in an amorphous structure with exceptional properties. Glass is an undercooled liquid. This type of liquid has high viscosity and low atomic mobility, making crystallization difficult. For example, polymer materials (silicates, plastics, etc.) can achieve a glassy state under normal cooling conditions. Metals, however, are different. Due to the low viscosity of liquid metals, they rapidly crystallize when cooled below the liquidus line, thus requiring extremely high cooling rates (estimated >10^10 °C/s) to achieve a glassy state. To obtain metallic glass at lower cooling rates, the stability of the liquid must be increased, allowing it to exist over a wider temperature range. Experiments have shown that when the liquidus line is steep, resulting in a low eutectic temperature, the stability of the liquid is enhanced. Therefore, such binary systems (e.g., Fe-B, Fe-C, Fe-P, Fe-Si, etc.) are selected. To improve performance, other elements (e.g., Ni, Mo, Cr, Co, etc.) can be added. This type of metallic glass can be obtained at cooling rates of 10^5–10^6 °C/s.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在获得金属玻璃时通常需要选择具有陡峭液相线和低共晶温度的二元系统，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目需要综合运用材料科学中的多个概念（如金属玻璃的形成条件、液体稳定性、冷却速率的影响等），并进行推理分析（解释为什么选择具有陡峭液相线和低共晶温度的二元体系）。此外，还需要理解实验现象和机理，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用多个复杂概念（如金属玻璃的形成机制、液体稳定性、冷却速率的影响等），并进行深入的机理解释和推理分析。正确选项不仅需要理解金属玻璃的基本定义，还需要掌握二元系统的相图特征（如陡峭的液相线和低共晶温度）对液体稳定性的影响，以及如何通过合金设计优化性能。此外，题目还涉及实际应用中的冷却速率要求和其他元素的添加策略，这些都是高度专业化的知识点，需要考生具备扎实的材料科学基础和综合分析能力。" + }, + { + "idx": 2062, + "question": "Point out the errors in the following concept and correct them: (5) The so-called critical nucleus is the size of the embryo when the decrease in the system's free energy fully compensates for the increase in surface free energy.", + "answer": "The decrease in the system's free energy should compensate for 2/3 of the surface free energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对临界核概念的基本理解和记忆，需要指出并纠正一个常见的概念错误，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生不仅知道临界核的定义，还需要理解自由能变化与表面自由能之间的具体补偿关系（2/3而非完全补偿）。这超出了简单的定义复述，要求对概念有更深入的理解和应用。" + }, + { + "idx": 2063, + "question": "Derive the K.A. Jackson equation formula", + "answer": "The so-called equilibrium structure of an interface refers to the most stable state of the interface under the condition of minimum interfacial energy. The essence of the problem is to analyze the relative change in interfacial free energy when the interface becomes rough. For this purpose, the following assumptions are made: (1) The equilibrium between the liquid and solid phases is under isothermal conditions; (2) The structures of the liquid and solid phases are identical near the interface; (3) Only configurational entropy is considered, while vibrational entropy is neglected. Let $N$ be the total number of atomic positions on the liquid-solid interface, with $n$ being the number of solid-phase atomic positions, and the occupation fraction $x=\\\\frac{n}{N}$; the vacancy fraction on the interface is $1-x$, and the number of vacancies is $N(1-x)$. The formation of vacancies causes changes in internal energy and structural entropy, leading to a corresponding change in surface Gibbs free energy: $$\\\\Delta G_{\\\\mathrm{s}}=\\\\Delta H-T\\\\Delta S=(\\\\Delta u+P\\\\Delta S)-T\\\\Delta S\\\\approx\\\\Delta u-T\\\\Delta S$$ The increase in internal energy due to the formation of $N(1-x)$ vacancies is determined by the product of the number of broken solid bonds and the bond energy of a pair of atoms. The change in internal energy is: $$\\\\Delta u=N\\\\xi L_{\\\\mathrm{~m~}}x(1-x)$$ Here, $\\\\boldsymbol{\\\\xi}$ is related to the crystal structure and is called the crystallographic factor. Next, the entropy change is calculated. From the definition of entropy change, we have: $$\\\\Delta S=k\\\\ln w=k\\\\ln\\\\frac{N!}{(N x)![N-(N x)]!}=k\\\\ln\\\\frac{N!}{(N x)![N(1-x)]!}$$ Using Stirling's approximation, when $N$ is large, we obtain: $$\\\\Delta S=-k N[x\\\\mathrm{ln}x+(1-x)\\\\mathrm{ln}(1-x)]$$ Finally, the total change in free energy on the liquid-solid interface is calculated as: $$\\\\Delta G_{\\\\mathrm{s}}=\\\\Delta u-T_{\\\\mathrm{m}}\\\\Delta S=N\\\\hat{\\\\xi}L_{\\\\mathrm{m}}x(1-x)+k T_{\\\\mathrm{m}}N[x\\\\mathrm{ln}x+(1-x)\\\\mathrm{ln}(1-x)]$$ Thus: $$\\\\frac{\\\\Delta G_{\\\\mathrm{S}}}{N k T_{\\\\mathrm{m}}}=\\\\frac{\\\\xi L_{\\\\mathrm{m}}}{k T_{\\\\mathrm{m}}}x(1-x)+x\\\\mathrm{ln}x+(1-x)\\\\mathrm{ln}(1-x)$$ $$\\\\alpha=\\\\frac{\\\\xi L_{\\\\mathrm{~m~}}}{k T_{\\\\mathrm{~m~}}}$$ Therefore: $$\\\\frac{\\\\Delta G_{\\\\mathrm{S}}}{N k T_{\\\\mathrm{m}}}=\\\\alpha x\\\\left(1-x\\\\right)+x{\\\\ln x+(1-x)\\\\ln(1-x)}$$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求推导K.A. Jackson方程公式，答案通过文字解释和数学推导详细论述了方程的推导过程，包括假设、熵变计算和自由能变化等步骤，属于需要详细解释和论述的简答题类型。 | 知识层次: 题目要求推导K.A. Jackson方程，涉及多个假设、概念关联和复杂的数学推导。需要理解界面自由能、熵变、内能变化等概念，并能够综合运用这些知识进行推理分析。此外，还需要使用Stirling近似等数学工具，思维过程的深度要求较高。 | 难度: 在选择题型内，该题目要求对K.A. Jackson方程的推导过程有深入的理解和掌握。题目涉及复杂的物理概念（如界面能、熵变、自由能变化）、数学推导（如Stirling近似）以及多个假设条件。学生需要综合运用热力学、统计力学和材料科学的知识，进行多步骤的推理和分析。这种深度和广度的知识要求，以及解题的复杂性，使得该题目在选择题型中属于最高难度等级。" + }, + { + "idx": 2064, + "question": "Point out the errors in the following concepts and correct them: (6) In liquid metal, any embryo that emerges with a radius smaller than the critical nucleus radius cannot nucleate, but as long as there is sufficient energy fluctuation to provide the nucleation work, nucleation is still possible.", + "answer": "Nucleation cannot occur, even if there is sufficient energy fluctuation to provide it, nucleation still cannot occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出概念中的错误并纠正，类似于判断陈述的对错并给出正确解释 | 知识层次: 题目考查对成核基本概念的记忆和理解，特别是临界核半径和能量波动在成核过程中的作用。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。题目要求考生理解临界核半径的概念以及成核的基本原理，并能够判断在能量波动足够的情况下，半径小于临界核半径的胚团是否能够成核。虽然涉及基础概念的记忆，但需要一定的理解深度来判断陈述的正确性，因此属于中等难度。" + }, + { + "idx": 2065, + "question": "Point out the errors in the following concept and correct them: (7) Measuring the maximum undercooling during the crystallization of a pure metal casting, where the measured value is basically consistent with the calculated value using the formula ΔT=0.2Tm.", + "answer": "Measure the effective undercooling during homogeneous nucleation of a pure metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算 | 知识层次: 题目要求识别并纠正概念错误，涉及对均相形核和有效过冷度的理解，需要将理论公式与实际测量值进行对比分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求识别并纠正关于纯金属铸造结晶过程中最大过冷度的测量错误，并正确指出应在均质形核时测量有效过冷度。这涉及对结晶过程、过冷度概念及其测量方法的理解，以及公式ΔT=0.2Tm的应用背景。虽然不需要复杂的计算，但需要对相关概念有清晰的认识并能进行综合分析。" + }, + { + "idx": 2066, + "question": "Point out the errors in the following concepts and correct them: (3) At any temperature, the maximum structural fluctuations appearing in liquid metals are all embryos.", + "answer": "In undercooled liquids, the maximum structural fluctuations appearing in liquid metals are all embryos.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对液体金属中结构波动和胚胎形成的基本概念的理解和记忆，需要识别并纠正错误表述，属于基础概念层面的认知要求。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生不仅记住定义，还要能够识别并纠正错误概念。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 2067, + "question": "Point out the errors in the following concepts and correct them: (14) During the growth of pure metals, regardless of whether the liquid-solid interface is rough or smooth, the liquid-phase atoms are connected one by one along the vertical direction of the solid-phase surface.", + "answer": "If the liquid-solid interface is rough, its liquid-phase atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对纯金属生长过程中液固界面原子连接方式的基本概念的理解和记忆，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分粗糙界面和光滑界面的生长机制差异。正确选项要求考生能够识别并纠正错误概念，这比单纯记忆定义（等级1）更具挑战性，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2068, + "question": "Point out the errors in the following concepts and correct them: (10) From the calculation formula of heterogeneous nucleation work A_hetero = A_g(2-3cosθ+cos³θ), it can be seen that when the wetting angle θ=0°, the nucleation work for heterogeneous nucleation is the largest.", + "answer": "The nucleation work for heterogeneous nucleation is the smallest.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断给定的概念陈述是否正确，并指出错误和纠正，这符合判断题的特征。答案是对原陈述的判断和修正，而不是选择、计算或详细解释。 | 知识层次: 题目考查对异质形核功公式的理解和记忆，属于基础概念的判断和纠正，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。题目要求考生理解异质成核功的计算公式及其物理意义，特别是润湿角θ=0°时的特殊情况。虽然涉及公式记忆，但主要考察的是对公式物理意义的理解，而非复杂的推导或分析。因此属于中等难度，需要考生具备一定的概念理解能力。" + }, + { + "idx": 2069, + "question": "Point out the errors in the following concept and correct them: (12) Heterogeneous nucleation is always easier than homogeneous nucleation because the former uses foreign particles as the crystallization core, unlike the latter which forms an interface and causes an increase in free energy.", + "answer": "Because the former uses foreign particles as the substrate, the nucleation work is smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字解释的形式呈现，符合简答题的特征。 | 知识层次: 题目要求指出并纠正关于异质成核和均质成核的错误概念，需要理解两种成核方式的区别及其自由能变化的原理。这涉及到概念之间的关联和综合分析，而不仅仅是基础概念的记忆。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生识别并纠正关于异质成核和均质成核的错误概念，这涉及到对成核过程中自由能变化和界面形成的基本理解。虽然题目提供了正确选项，但考生仍需具备一定的综合分析能力来辨别错误并理解为什么异质成核的成核功较小。这需要将多个概念关联起来，但不需要进行复杂的多步计算或深度关联性分析。" + }, + { + "idx": 2070, + "question": "Point out the errors in the following concept and correct them: (11) In order to produce a batch of sand castings with significant thickness variations and require uniform grain size, it can be satisfied by merely adding nucleating agents in the process.", + "answer": "It can be satisfied by merely accelerating the cooling of thicker sections (such as adding chills) in the process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式给出，解释了如何通过加速较厚部分的冷却来满足要求。 | 知识层次: 题目要求识别并纠正关于铸造过程中晶粒尺寸控制的错误概念，需要理解晶粒尺寸控制的基本原理（如冷却速率的影响）以及如何在实际操作中应用这些原理（如使用冷却装置）。这涉及到多步思考和概念关联，但不需要复杂的综合分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解砂型铸造中晶粒尺寸均匀性的控制原理，并综合分析冷却速度与成核剂的作用机制。题目要求识别原概念的误区（仅靠成核剂无法解决厚度差异问题），并选择正确的工艺措施（加速厚壁部分冷却）。这涉及中等应用层次的知识关联和工艺综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2071, + "question": "Point out the errors in the following concepts and correct them: (13) When studying the process of refining grains in a certain metal, the main focus is to find nucleating agents with low melting points and lattice constants similar to those of the metal, as their nucleation catalytic efficiency is the highest.", + "answer": "The main focus is to find those with high melting points, and.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出并纠正错误概念，这类似于判断题中判断陈述的对错并给出正确解释。答案部分直接指出了原陈述中的错误并提供了正确的表述，符合判断题的特征。 | 知识层次: 题目考查对晶粒细化过程中形核剂选择的基本概念的理解和记忆，属于基础概念范畴。 | 难度: 在选择题型中，这道题目属于中等难度。虽然考察的是基础概念记忆（晶粒细化过程中的形核剂选择标准），但需要考生不仅记住正确概念（高熔点），还要能够识别并纠正题目中给出的错误概念（低熔点）。这比单纯的正误判断（等级1）要求更高，但不需要进行复杂概念分析（等级3）。" + }, + { + "idx": 2072, + "question": "Point out the errors in the following concept and correct them: (9) If 10,000 nucleation agents are added to an undercooled liquid, then 10,000 grains will form after crystallization.", + "answer": "then tens of thousands of grains will form after crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择或判断。答案也是通过文字描述来修正错误概念。 | 知识层次: 题目要求识别并纠正关于成核剂与晶粒形成关系的错误概念，需要理解成核剂的作用机制和晶粒形成的多因素影响，涉及概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解成核剂的作用机制以及晶粒形成的原理，并进行综合分析。题目要求识别概念错误并给出正确表述，涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2073, + "question": "Point out the errors in the following concepts and correct them: (18) When a nucleation agent is added to liquid pure metal, its growth morphology always appears dendritic.", + "answer": "Its growth morphology will not change.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念错误并进行修正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对成核剂添加后金属生长形态变化的基本概念的理解和记忆，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解成核剂对纯金属生长形态的影响，并能够识别和纠正错误概念。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 2074, + "question": "Point out the errors in the following concepts and correct them: (15) Regardless of the temperature distribution, common pure metals always grow with a dendritic interface.", + "answer": "Only under negative temperature gradient conditions, common pure metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案形式也是通过文字说明来纠正错误概念。 | 知识层次: 题目要求指出并纠正关于纯金属生长形态的错误概念，需要理解温度梯度对金属生长形态的影响，并能够将这一概念与具体条件（负温度梯度）联系起来。这涉及到对金属凝固过程的基本原理的应用和综合分析，而不仅仅是简单的记忆或直接套用。 | 难度: 在选择题中属于中等难度，需要理解金属凝固过程中的温度梯度概念，并能区分不同条件下的界面生长形态。题目要求识别错误概念并选择正确表述，涉及对纯金属凝固行为的综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2075, + "question": "Point out the errors in the following concept and correct them: (17) It is impossible to observe the dendritic growth process of extremely pure metals, so the dendritic growth morphology is merely a speculation.", + "answer": "The growth process can be observed through experimental methods, such as pouring off the remaining liquid of the crystallizing metal or performing overall quenching, so the dendritic growth morphology is not a speculation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求指出并纠正错误概念，涉及对枝晶生长过程的实验观察方法的理解和应用，需要将理论知识与实验技术相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属结晶过程中的枝晶生长现象，并掌握相关实验观察方法（如倾倒剩余液体或整体淬火）。题目要求考生不仅识别原陈述的错误，还要选择正确的科学解释，涉及概念关联和综合分析能力。" + }, + { + "idx": 2076, + "question": "Point out the errors in the following concepts and correct them: (16) The microstructure morphology of a saturated aqueous solution of ammonium chloride and pure metal at the end of crystallization is the same, with the former exhibiting dendritic crystals and the latter also exhibiting dendritic crystals.", + "answer": "The microstructure morphology at the end of crystallization is different; the former exhibits dendritic crystals (with water between the branches), while the latter exhibits individual (blocky) grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出并纠正概念中的错误，类似于判断陈述的对错并给出正确解释。答案形式是对原陈述的否定和修正，符合判断题的特征。 | 知识层次: 题目考查对结晶过程中微观结构形态的基础概念记忆和理解，涉及对饱和溶液和纯金属结晶形态差异的基本认识。 | 难度: 在选择题型中，该题目属于中等偏下难度。题目要求考生区分两种不同结晶过程的微观结构形态，需要理解饱和氯化铵水溶液和纯金属在结晶结束时的不同表现。虽然涉及基础概念记忆，但需要考生对结晶形态有清晰的理解，并能正确识别和纠正错误陈述。解题步骤相对简单，但需要准确的概念掌握。" + }, + { + "idx": 2077, + "question": "In the Al-Mg alloy, $x_{\\\\mathrm{Mg}}=0.05$, calculate the mass fraction of Mg ($w_{\\\\mathrm{Mg}}$) in the alloy (given that the relative atomic mass of Mg is 24.31 and Al is 26.98).", + "answer": "$w_{\\\\mathrm{Mg}}=0.0453$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的相对原子质量和摩尔分数来计算镁的质量分数，答案是一个具体的数值结果。 | 知识层次: 题目考查基本的质量分数计算，仅需套用简单公式（质量分数=组分质量/总质量），涉及单一概念的直接应用和基本数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（质量分数计算公式）进行简单计算，无需复杂的推理或多步骤操作。题目提供了所有必要的数据，且计算过程直接明了，属于最基础的难度等级。" + }, + { + "idx": 2078, + "question": "Point out the errors in the following concepts and correct them: (21) Pure metal crystallization grows in a dendritic morphology or a planar morphology, which is unrelated to the melting entropy of the metal.", + "answer": "Because it is also related to the structure of the liquid-solid interface (α=ξΔSm/k), i.e., it is related to the melting entropy of the metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解纯金属结晶的基本形态（基础概念），还需要分析界面结构与熔化熵的关系（概念关联），并指出原陈述的错误（综合分析）。这涉及到多步思维过程和概念间的联系，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解金属结晶的形态与熔化熵之间的关系，并能够分析液体-固体界面结构的影响。题目要求不仅识别错误概念，还需提供正确的关联性解释，涉及多步计算和概念关联的综合分析。" + }, + { + "idx": 2079, + "question": "Point out the errors in the following concepts and correct them: (20) From a macroscopic perspective, if the liquid-solid interface is straight, it is called a smooth interface structure; if it is zigzag like metal, it is called a rough interface structure.", + "answer": "The straight one is called a rough interface structure; the zigzag one is called a smooth interface structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念错误并进行修正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查的是对液体-固体界面结构的基本概念的记忆和理解，即区分平滑界面结构和粗糙界面结构的定义。虽然需要纠正错误概念，但整体上仍属于基础概念的记忆和简单应用范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对\"平滑界面结构\"和\"粗糙界面结构\"的定义有准确的理解，并能识别出题目中给出的错误描述。这比单纯记忆定义（等级1）要求更高，需要考生能够辨别概念的正误并进行修正，但不需要进行复杂的体系阐述（等级3）。" + }, + { + "idx": 2080, + "question": "Point out the errors in the following concepts and correct them: (23) During metal crystallization, the dynamic undercooling required for crystal growth is sometimes greater than the critical undercooling required for nucleation.", + "answer": "The dynamic undercooling is smaller than the critical undercooling required for nucleation.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出并纠正错误概念，答案直接给出了正确的陈述，类似于判断陈述的对错并给出正确版本 | 知识层次: 题目考查金属结晶过程中动态过冷度和临界过冷度的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目要求考生理解金属结晶过程中动态过冷和临界过冷的相对大小关系，并判断原陈述的错误之处。这需要考生掌握基础概念并能进行简单的比较分析，但不需要复杂的推理或多概念整合，因此属于中等难度。" + }, + { + "idx": 2081, + "question": "Point out the errors in the following concepts and correct them: (22) During the crystallization of actual metals, the nucleation rate increases with the increase of undercooling, and after exceeding a certain maximum value, the opposite change occurs.", + "answer": "increases, but due to the limited undercooling capacity of metals, it does not exceed a certain maximum value.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式呈现，解释了概念的正确理解。 | 知识层次: 题目要求指出并纠正关于金属结晶过程中形核速率与过冷度关系的错误概念，需要理解形核速率与过冷度的关系，并能够分析实际金属结晶过程中的限制因素。这涉及多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，题目要求考生理解金属结晶过程中的成核速率与过冷度之间的关系，并能够识别和纠正错误概念。这需要考生具备一定的知识掌握深度，能够将理论知识与实际现象联系起来进行分析。虽然题目涉及的概念较为基础，但需要考生进行综合思考和判断，因此属于中等难度。" + }, + { + "idx": 2082, + "question": "Should high carbon steel or low carbon steel be used to manufacture automobile fenders?", + "answer": "High carbon steel. Because high carbon steel has high strength and can withstand greater impact force without deformation. In contrast, low carbon steel is softer and more prone to deformation under force.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述为什么选择高碳钢而不是低碳钢来制造汽车挡泥板，答案提供了详细的文字解释和比较，符合简答题的特征。 | 知识层次: 题目要求学生理解高碳钢和低碳钢的性能差异，并应用这些知识来选择适合制造汽车挡泥板的材料。这涉及到对材料性能的综合分析和实际应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解高碳钢和低碳钢的基本特性（如强度和抗变形能力），并能将这些概念与汽车挡泥板的应用场景进行关联分析。题目要求考生在给定选项中综合比较两种材料的性能差异，并选择最适合应用场景的选项，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2083, + "question": "At 800°C, which phases exist in Fe-0.002C steel?", + "answer": "α phase, γ phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答在特定温度下存在的相，答案需要列举具体的相（α phase, γ phase），属于简答形式，不需要计算或选择。 | 知识层次: 题目考查对铁碳相图的基本记忆和理解，需要知道在800°C时Fe-0.002C钢中存在哪些相，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别Fe-0.002C钢在800°C时存在的相（α相和γ相），属于基础概念记忆层次。题目不涉及复杂的概念解释或比较分析，仅需直接回忆教材或课程中的基本知识点即可作答，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 2084, + "question": "Calculate the relative amounts of secondary cementite, eutectic cementite, and eutectoid cementite in ledeburite", + "answer": "In ledeburite, the relative amount of Fe_3C_I is 10.15%, the relative amount of Fe_3C_3tan is 41.21%, and the relative amount of eutectoid Fe:C is 3.9%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算特定成分的相对含量，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要计算不同形态的渗碳体在莱氏体中的相对含量，涉及多步计算和概念关联（如区分二次渗碳体、共晶渗碳体和共析渗碳体），但不需要复杂的机理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如二次渗碳体、共晶渗碳体、共析渗碳体）并进行多步计算和综合分析。题目要求计算不同相的含量比例，涉及中等应用层次的知识，需要将概念关联起来并执行精确计算。" + }, + { + "idx": 2085, + "question": "Calculate the relative amounts of cementite and ferrite in the pearlite microstructure", + "answer": "In pearlite, the relative amount of F is 9.38%, and the relative amount of Fe_3C_## is 1.22%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算珠光体微观结构中渗碳体和铁素体的相对含量，需要通过数值计算和公式应用来得出结果。答案给出了具体的百分比数值，符合计算题的特征。 | 知识层次: 题目需要应用杠杆法则计算珠光体中渗碳体和铁素体的相对含量，属于基本公式的直接套用和简单计算，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式进行简单计算，属于单一公式直接计算的难度等级。题目明确给出了计算所需的相对比例，无需额外的分析或组合公式，因此难度最低。" + }, + { + "idx": 2086, + "question": "In the Al-Cu phase diagram, given $K=0.16$, $m=3.2$. If the solidification rate of the casting is $R=3\\\\times10^{-4}~\\\\mathrm{cm/s}$, the temperature gradient is $G=30^{\\\\circ}\\\\mathrm{C}/\\\\mathrm{cm}$, and the diffusion coefficient is $D=3\\\\times10^{-5}~\\\\mathrm{cm}^{2}/\\\\mathrm{s}$, find the extreme value of $\\\\scriptstyle{\\\\mathcal{W}}_{\\\\mathrm{Cu}}$ in the alloy that maintains planar interface growth.", + "answer": "$w_{\\\\mathrm{Cu}}^{\\\\mathrm{C}_{0}}=\\\\frac{G D}{R m}\\\\frac{K}{1-K}=0.1744$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出一个具体的数值答案。解答过程涉及公式应用和数值代入，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，涉及相图参数的理解和公式应用，需要将给定的参数代入公式进行计算，并理解平面界面生长的条件。虽然计算过程较为直接，但需要对相图和扩散系数等概念有一定的理解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图、扩散系数、凝固速率等多个概念，并进行多步计算和综合分析。题目涉及多个变量的代入和公式推导，但作为选择题，正确选项已经给出，减少了部分计算复杂度。" + }, + { + "idx": 2087, + "question": "Point out the errors in the following concept and correct them: (19) When a pure metal crystallizes and grows vertically, its interface is sometimes smooth and sometimes rough, growing alternately.", + "answer": "The interface is of the rough type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对金属结晶界面类型的基础概念记忆和理解，仅需识别并纠正错误描述，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解金属结晶过程中界面类型的分类（光滑界面与粗糙界面），并能准确识别题目中描述的错误概念。正确选项直接给出了界面的正确类型，但考生需要基于对结晶过程的基本原理的理解来判断。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 2088, + "question": "Based on microstructural analysis, the volume of graphite in a gray cast iron accounts for 12%, and the volume of ferrite accounts for 88%. Determine the value of ωC (given that the density of graphite ρG=2.2 g/cm³, and the density of ferrite ρα=7.8 g/cm³).", + "answer": "ωC=0.037.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ωC的值，答案是一个具体的数值结果，解答过程需要运用给定的密度数据和体积百分比进行计算。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及体积分数和密度的转换，属于直接套用公式的计算题，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用密度和体积分数的基本公式，但解题步骤较为直接，仅需套用公式进行简单计算即可得出结果。不需要复杂的推理或多步骤的公式组合，因此在选择题型内属于等级2难度。" + }, + { + "idx": 2089, + "question": "Calculate the relative amounts of pearlite, secondary cementite, and ledeburite in the microstructure of an iron-carbon alloy with a carbon content of w_c=0.04 after metastable cooling to room temperature.", + "answer": "In the microstructure, the relative amount of P is 10.6%, the relative amount of Fe_3C_∥ is 3.10%, and the relative amount of L_d′ is 86.3%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算相对含量），答案给出了具体的百分比数值，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及铁碳合金相图中不同相的相对含量计算，需要理解相图的基本原理并应用杠杆定律进行计算。虽然计算过程较为直接，但需要综合运用多个知识点，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，掌握珠光体、二次渗碳体和莱氏体的形成条件，并能进行多步计算来求解相对含量。虽然题目给出了正确选项，但考生仍需具备综合分析能力才能正确选择。" + }, + { + "idx": 2090, + "question": "At 800°C, what are the compositions of the α phase and γ phase in Fe-0.002C steel?", + "answer": "α: wC=0.0001, wFe=0.9999; γ: wC=0.0046, wFe=0.9954.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算在特定温度下α相和γ相的成分，需要参考相图或相关公式进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图的基本知识，通过查图和简单计算确定α相和γ相的成分。虽然涉及相图的理解，但计算过程直接，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于简单应用层次，需要考生根据给定的温度（800°C）和钢的成分（Fe-0.002C），直接套用铁碳相图的基本知识来确定α相和γ相的成分。虽然涉及相图的应用，但题目已经提供了具体的温度点，且选项直接给出了计算结果，减少了复杂推导的需求。因此，该题目在选择题型内属于等级2难度，即简单公式应用计算。" + }, + { + "idx": 2091, + "question": "How to obtain the mass and Cu content of solid α3 by heating solid α2 to melting and slowly cooling it to 920°C, then pouring off the liquid?", + "answer": "Reheat α2 to melting, slowly cool to 920°C, pour off the liquid, leaving only α3, with a mass of 260g and w_Cu≈0.02.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字描述步骤和结果来解答，答案提供了具体的操作步骤和最终结果，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及多步操作（加热、冷却、倒出液体）和综合分析（确定固体α3的质量和铜含量），需要理解相变过程和成分变化，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解相图概念、掌握多步计算过程，并能将加热冷却操作与物质组成变化关联起来。题目要求考生综合运用相变知识和成分计算能力，但选项已提供关键数值，降低了纯计算难度。" + }, + { + "idx": 2092, + "question": "How to obtain the mass and Cu content of solid α4 by heating solid α3 to melting and slowly cooling it to 935°C before pouring off the liquid?", + "answer": "Heat α3 to melting again, slowly cool it to 935°C, pour off the liquid, leaving only α4, with a mass of 180g and a Cu content of w_Cu≈0.013.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字描述如何通过加热和冷却过程获得特定固体的质量和铜含量，答案提供了具体的操作步骤和结果，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及多步操作（加热、冷却、倒出液体）和综合分析（计算质量和铜含量），需要理解相图概念并应用相关原理进行计算，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及多步操作（加热、冷却、倾倒液体）和多个概念（相变、成分分析）的综合应用。其次，解题需要准确理解相图原理和成分计算，并能将实验操作步骤与理论计算结果关联起来。最后，题目要求考生在选择题的有限选项中识别出同时满足质量（180g）和成分（w_Cu≈0.013）两个条件的正确答案，这需要较强的综合分析能力。这些因素使得该题在选择题型中属于需要多角度分析论述的难度等级。" + }, + { + "idx": 2093, + "question": "Assuming the Cu content in α phase at 100°C can be considered zero, calculate how many copper atoms are present in each θ particle, given that the atomic radius of Al is 0.143 nm.", + "answer": "Approximately 150 Cu atoms per θ particle.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铜原子数量），并给出了具体的条件和参数（如温度、原子半径等），答案也是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括原子半径的应用、相组成的分析以及粒子中原子数量的估算，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要综合运用材料科学中的相图知识、原子半径概念以及单位晶胞计算。题目要求考生：" + }, + { + "idx": 2094, + "question": "How to obtain the mass and Cu content of solid α2 by heating solid α1 to melting, slowly cooling to 900°C, and pouring off the liquid?", + "answer": "Heat the solid (α1) in (1) to melting, slowly cool to 900°C, pour off the liquid, and the remaining solid α2 has a weight of 390g with w_Cu≈0.03.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来描述如何通过加热、冷却和倒出液体来获得固体α2的质量和铜含量，答案也以文字形式给出了具体的操作步骤和结果。 | 知识层次: 题目涉及多步操作（加热、冷却、分离）和结果分析（质量测定和成分计算），需要综合运用相图知识和实验操作步骤的理解，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及加热、冷却和分离液体的多步操作，同时要求计算剩余固体的质量和铜含量。虽然题目提供了具体的数值，但需要考生具备一定的材料科学知识，能够理解相变和成分变化的基本原理。此外，题目还要求考生能够将实验步骤与结果联系起来，进行综合分析。因此，在选择题型中，这道题目属于中等难度，对应等级3。" + }, + { + "idx": 2095, + "question": "At 800°C, what are the fractions of α phase and γ phase in Fe-0.002C steel?", + "answer": "nα=0.58, nγ=0.42.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算在特定温度下Fe-0.002C钢中α相和γ相的比例，需要通过相图或相关公式进行数值计算，最终给出具体的数值结果。答案以数值形式呈现，符合计算题的特征。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相平衡的概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，能够正确识别800°C时Fe-0.002C钢所处的相区，并应用杠杆定律进行两相含量的计算。虽然题目给出了具体温度（800°C）和成分（0.002C），简化了相区判断的步骤，但仍需要进行多步计算和概念关联，包括：" + }, + { + "idx": 2096, + "question": "A eutectic reaction in the Mg-Ni system is given by $$ \\\\operatorname{L}_{w_{\\\\mathrm{Ni}}=0.235}\\\\frac{570^{\\\\circ}\\\\mathrm{C}}{\\\\Longleftarrow}\\\\alpha_{(\\\\#\\\\mathbb{M}_{\\\\operatorname{g}})}+\\\\mathrm{Mg}_{2}\\\\mathrm{Ni}_{w_{\\\\mathrm{Ni}}=0.546} $$ Let $\\\\omega_{\\\\mathrm{Ni}}^{1}=C_{1}$ be a hypoeutectic alloy and $\\\\boldsymbol{w_{\\\\mathrm{Ni}}^{2}}=C_{2}$ be a hypereutectic alloy. The mass fraction of the proeutectic phase in these two alloys is equal, but the total amount of $\\\\upalpha$ in alloy $\\\\mathrm{C}_{1}$ is 2.5 times that in alloy $\\\\mathrm{C}_{2}$. Calculate the compositions of $\\\\mathrm{C}_{1}$ and $\\\\mathrm{C}_{2}$.", + "answer": "The composition of alloy $C_{1}$ is $w_{\\\\mathrm{Mg}}=0.873$, $w_{\\\\mathrm{Ni}}=0.127$. The composition of alloy $\\\\mathrm{C}_{2}$ is $w_{\\\\mathrm{Mg}}=0.66,w_{\\\\mathrm{Ni}}=0.368$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定两种合金的组成，答案给出了具体的数值结果，解答过程需要运用相图分析和质量分数计算等材料科学中的计算方法。 | 知识层次: 题目涉及多步计算和概念关联，需要理解共晶反应的基本原理，并应用杠杆定律进行质量分数的计算。虽然不涉及复杂的推理分析或机理解释，但需要综合分析合金的成分与相组成之间的关系，并进行数值计算。 | 难度: 在选择题中属于高难度题目，需要深入理解共晶反应、相图分析、质量分数计算等多个材料科学核心概念。题目涉及多变量计算（C1和C2合金的成分计算）、多步骤推理（通过质量分数相等和α相总量关系建立方程组），以及综合分析能力（将相图信息与数学计算相结合）。这些要求明显超出了选择题型的常规难度水平，需要考生具备较强的应用能力和计算技巧。" + }, + { + "idx": 2097, + "question": "If there is a certain Cu-Ag alloy (w_Cu=0.075, w_Ag=0.925) weighing 1000g, how can the mass of solid α1 and its Cu content be obtained by heating it above 900°C to melt, then slowly cooling to 850°C and pouring off the liquid part?", + "answer": "When 1000g of this alloy is heated above 900°C to melt, then slowly cooled to 850°C and the liquid part is poured off, the remaining solid α1 weighs 780g with a w_Cu≈0.055.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算固体α1的质量和铜含量），并应用相图相关知识来解答，答案给出了具体的计算结果。 | 知识层次: 题目涉及多步计算（相图应用、杠杆定律计算、成分分析）和概念关联（相变过程、合金成分与相组成的关系），需要综合分析相图信息并进行定量计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆法则应用以及多步计算过程。题目要求考生能够将Cu-Ag相图知识应用于具体合金成分分析，通过温度变化判断相组成，并运用质量守恒原理进行定量计算。虽然给出了正确选项减少了部分思考量，但仍需综合运用材料科学基础知识和计算能力才能正确解答。" + }, + { + "idx": 2098, + "question": "Under equilibrium cooling conditions, a carbon steel obtains a microstructure containing 50% pearlite and 50% ferrite. What is the mass fraction of carbon in this alloy?", + "answer": "x=wC=0.385", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解碳的质量分数，答案是一个具体的数值结果（x=wC=0.385），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用杠杆定律（lever rule）进行多步计算，涉及相图中相组成与碳含量的关系，需要理解并关联多个概念（如珠光体、铁素体的形成条件及其碳含量），并进行综合分析得出结果。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、杠杆定律的应用，并进行多步计算。题目要求考生能够将50%珠光体和50%铁素体的微观组织比例转化为碳含量计算，这需要综合运用相图知识和计算能力，属于典型的综合性计算问题。虽然题目给出了正确选项，但解题过程涉及多个概念关联和计算步骤，在选择题型中属于较复杂的题目。" + }, + { + "idx": 2099, + "question": "14. At 550°C, an aluminum-copper alloy solid solution with composition x_Cu=0.02 is quenched and then reheated to 100°C to precipitate θ phase (CuAl2). The θ phase forms many small particles dispersed in the alloy with an average particle spacing of 5.0 nm. Approximately how many particles are formed in 1 mm³ of the alloy?", + "answer": "Approximately 8×10^24 particles/m³ (equivalent to 8×10^15 particles/mm³).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在1 mm³合金中形成的θ相颗粒数量。答案给出了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算和概念关联，包括理解固溶体、相变、粒子间距等概念，并应用这些概念进行数值计算。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力来解决问题。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，包括固溶体、相变、粒子间距计算等。虽然题目提供了正确选项，但需要考生综合运用材料科学知识进行计算和推理，属于综合性计算问题。" + }, + { + "idx": 2100, + "question": "A carbon steel, under equilibrium cooling conditions, obtains a microstructure consisting of 50% pearlite and 50% ferrite. Question: If this alloy is heated to 730°C, what microstructure will be obtained under equilibrium conditions?", + "answer": "The microstructure will be F+A", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定温度下材料的微观结构变化，答案需要文字描述（F+A表示铁素体和奥氏体的混合结构），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解铁碳相图并应用相变知识，分析在特定温度下的平衡相组成，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，能够分析不同温度下的相变过程，并进行多步计算和概念关联。虽然题目给出了明确的温度点，但需要考生综合运用相图知识和平衡冷却条件来推断最终的微观结构。" + }, + { + "idx": 2101, + "question": "Under equilibrium cooling conditions, a carbon steel obtains a microstructure consisting of 50% pearlite and 50% ferrite. If it is heated to 850°C, what microstructure will be obtained?", + "answer": "Entirely austenite (A) microstructure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定温度下材料的微观结构变化，答案需要文字描述和论述，而非选择、判断或计算。 | 知识层次: 题目需要理解铁碳相图的基本原理，并能够根据给定的条件（50%珠光体和50%铁素体）推断出钢的碳含量，然后进一步分析在850°C加热时的相变过程。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及碳钢在平衡冷却条件下的微观结构（珠光体和铁素体比例），以及加热到850°C后的相变过程。解答需要综合运用铁碳相图知识，判断在给定温度下钢的相组成，并理解奥氏体形成的条件。虽然不涉及复杂计算，但需要对相变概念有清晰的理解和关联分析能力。" + }, + { + "idx": 2102, + "question": "Point out the errors in the following concept and correct them: Repeatedly 'melting and solidifying' a solid solution alloy rod and using directional rapid solidification can effectively purify the metal.", + "answer": "Repeatedly perform zone melting and use directional slow solidification.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也是以文字形式给出修正后的正确概念。 | 知识层次: 题目要求识别并纠正错误概念，涉及对金属纯化方法的理解和应用，需要综合分析熔化、凝固过程对金属纯度的影响，并正确选择工艺参数（如快速或慢速凝固）。这超出了简单记忆的范畴，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求识别并纠正错误概念，涉及对\"melting and solidifying\"与\"zone melting\"、\"rapid solidification\"与\"slow solidification\"等专业术语的区分和理解。虽然不需要复杂的计算，但需要对材料科学中的提纯原理有较深入的理解，并能将不同概念关联起来进行综合分析。" + }, + { + "idx": 2103, + "question": "Point out the errors in the following concept and correct them: Although the crystallization rate of solid solution alloys is very fast, at a certain moment during solidification, the chemical potentials of components A and B in the liquid and solid phases are equal.", + "answer": "At the phase interface, the chemical potentials of components A and B in the liquid and solid phases are equal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别并纠正关于固溶体合金结晶速率和化学势的错误概念，涉及对相变过程中化学势平衡条件的理解和应用，需要将基础概念与实际相变过程关联起来进行分析和判断。 | 难度: 在选择题中属于中等难度，需要理解化学势平衡的概念，并能识别出题目中关于结晶速率与化学势平衡关系的错误表述。虽然不需要复杂的计算，但需要对相平衡和固溶体合金凝固过程有较深的理解，并能将多个概念关联起来进行分析。" + }, + { + "idx": 2104, + "question": "Point out the errors in the following concepts and correct them: In the solid solution alloy, whether during equilibrium or non-equilibrium crystallization, the liquid phase composition at the liquid-solid interface changes along the average liquid composition line; the solid phase composition changes along the average solid composition line.", + "answer": "The liquid phase composition at the liquid-solid interface changes along the liquidus line; the solid phase composition changes along the solidus line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对固溶体合金结晶过程中液相和固相成分变化路径的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解并区分平衡结晶和非平衡结晶过程中液相和固相成分的变化规律。虽然题目涉及的是基础概念记忆，但需要考生准确掌握液相线和固相线的定义及其在相图中的应用，并能识别和纠正错误描述。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 2105, + "question": "Point out the errors in the following concepts and correct them: On the eutectic line, the lever rule can be used to calculate the relative amount of the eutectic. Since the eutectic line belongs to the three-phase region, the lever rule is not only applicable to the two-phase region but also to the three-phase region.", + "answer": "However, the lever rule is only applicable to the two-phase region, so the relative amount of the eutectic is actually calculated in the two-phase region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目考查对杠杆规则适用范围的记忆和理解，属于相图分析中的基本原理知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分杠杆规则在两相区和三相区的适用性。正确选项直接指出了概念错误并提供了正确的解释，考生需要具备一定的概念辨析能力才能准确作答。相比等级1的简单定义记忆，该题目要求更高层次的理解和判断。" + }, + { + "idx": 2106, + "question": "Point out the error in the following concept and correct it: In the directional solidification process of a solid solution alloy rod, the faster the liquid-solid interface advances, the more severe the macrosegregation in the rod.", + "answer": "the less severe the macrosegregation in the rod.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出并纠正一个概念错误，类似于判断陈述的对错并给出正确表述。答案形式是直接纠正错误陈述，不需要计算或详细论述。 | 知识层次: 题目涉及对定向凝固过程中宏观偏析现象的理解和应用，需要将凝固速率与偏析程度的关系进行综合分析，属于中等应用层次的知识点。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解定向凝固过程的基本原理，还需要掌握宏观偏析的形成机制及其与凝固速率的关系。这需要考生能够综合分析多个概念（如溶质分配、扩散速率、界面稳定性等），并正确判断因果关系。虽然题目给出了正确选项，但判断过程涉及中等应用层次的知识关联和综合分析能力，比单纯的概念识别或单步计算更为复杂。" + }, + { + "idx": 2107, + "question": "Given the solid solubility equation of carbon in α-Fe in equilibrium with cementite as $$ w_{\\mathrm{C}}^{\\alpha}=2.55\\exp{\\frac{-11.3\\times10^{3}}{R T}} $$, assuming the solid solubility equation of carbon in austenite is similar to this equation, write this equation based on the Fe-Fe3C phase diagram.", + "answer": "Let the solid solubility equation of C in γ be $$ w_{\\mathrm{c}}^{\\gamma}=A\\exp\\bigl(-\\frac{Q}{R T}\\bigr) $$ Taking the logarithm of both sides, we get $$ \\ln w_{\\mathrm{c}}^{\\gamma}=\\ln A-\\frac{Q}{R T} $$ From the Fe-Fe3C phase diagram, we have $\\ln0.77=\\ln A-{\\frac{Q}{R\\times1000}}$ $$ \\ln2.11=\\ln A-{\\frac{Q}{R\\times1~421}}\\quad. $$ Combining these two equations, we obtain $Q=28\\mathrm{kJ}$, $A=22,3$, thus $$ w_{\\mathrm{c}}^{\\mathrm{r}}=22.3\\exp\\Bigl(-\\frac{2.8\\times10^{3}}{R T}\\Bigr) $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的固溶度方程和Fe-Fe3C相图，推导出奥氏体中碳的固溶度方程。解答过程涉及对数运算、方程联立求解和参数确定，属于典型的计算题。答案展示了具体的计算步骤和最终结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要从给定的固溶度方程出发，结合Fe-Fe3C相图的数据进行推导和计算。虽然题目给出了部分指导，但仍需要理解相图信息并正确应用对数变换和联立方程求解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶度方程的形式，掌握对数变换方法，并能从Fe-Fe3C相图中提取关键数据点（0.77%和2.11%碳含量）建立联立方程。解题过程涉及多步推导（取对数、建立方程、解方程组）和温度单位换算（1000K和1421K），最后还需将求得的参数代回原方程。虽然题目给出了正确推导过程，但在选择题环境下需要考生具备综合分析能力和计算技巧来判断选项的正确性。" + }, + { + "idx": 2108, + "question": "Point out the incorrect concept and correct it: In solid solution grains, dendritic segregation exists, the composition of the main axis differs from that of the interdendritic regions, so the entire grain is not a single phase.", + "answer": "Therefore, the entire grain is a single phase.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求指出错误概念并纠正，类似于判断陈述的对错并给出正确陈述。答案形式是直接给出正确陈述，符合判断题的特征。 | 知识层次: 题目考查对固溶体晶粒中枝晶偏析和单相概念的基本理解，属于基础概念的记忆和判断。 | 难度: 该题目属于基础概念正误判断，仅需识别并纠正一个明确的错误概念（\"整个晶粒不是单相\"），正确选项直接给出了标准定义（\"整个晶粒是单相\"）。题目不涉及概念关系的分析或复杂推理，完全依赖对\"固溶体晶粒\"和\"枝晶偏析\"这两个基础定义的记忆性判断，符合等级1对知识点掌握深度和解题步骤简单性的要求。" + }, + { + "idx": 2109, + "question": "Point out the incorrect concept and correct it: In Ni-Cu alloy castings with uneven thickness, thin sections tend to form dendritic structures after crystallization, while thick sections tend to form cellular structures.", + "answer": "After crystallization, thin sections tend to form cellular structures, while thick sections tend to form dendritic structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出错误概念并进行纠正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目要求识别并纠正关于Ni-Cu合金铸造中结晶结构的错误概念，这需要理解结晶过程中冷却速率对微观结构形成的影响，涉及多个概念的关联和综合分析。虽然不涉及复杂计算，但需要对结晶机制有一定深度的理解，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属凝固过程中的枝晶和胞状结构形成机制，并能分析不同厚度截面对凝固组织的影响。题目要求考生不仅掌握基本概念，还需要将凝固速率与微观组织形态进行关联分析，属于中等应用层次的知识运用。" + }, + { + "idx": 2110, + "question": "Point out the incorrect concept and correct it: Using circulating water to cool the metal mold is beneficial for obtaining a columnar crystal zone to improve the compactness of the casting.", + "answer": "It is not beneficial for obtaining a columnar crystal zone.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个概念的正确性（指出错误概念并纠正），答案直接给出了判断结果（不正确），这符合判断题的特征。 | 知识层次: 题目考查对金属铸造过程中冷却方式对晶体结构影响的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中属于基本概念正误判断，仅需识别并纠正一个简单的错误概念，不需要深入理解或分析多个概念。" + }, + { + "idx": 2111, + "question": "Point out the error in the following concept and correct it: In the Fe-Fe3C system alloys, only hypereutectoid steels have secondary cementite in their equilibrium crystallization structure.", + "answer": "Only when the iron-carbon alloy with a carbon mass fraction of 0.0077 < w_c < 0.043 undergoes equilibrium crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目要求识别并纠正Fe-Fe3C系统中关于二次渗碳体形成的错误概念，需要理解不同碳含量范围内合金的平衡结晶结构，并能够将这一概念应用到具体情境中。这涉及到多步分析和概念关联，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解Fe-Fe3C相图的基本概念，还需要能够区分不同碳含量范围内的合金特性，并准确识别原陈述中的错误。解题过程涉及：" + }, + { + "idx": 2112, + "question": "Point out the errors in the following concept and correct them: From the condition for constitutional supercooling <0, c=0. The left eutectoid steel rod is divided into volume elements with thickness d, so the carbon content per unit area is c0 d. Considering only the effect of this volume element, it is equivalent to an instantaneous plane source diffusion problem. After diffusion time t, the concentration at point P(x) at a distance ξ from this volume element is cξ=(c0 dξ)/(2√(πDt))exp(-ξ²/(4Dt)). Using the superposition principle, the total concentration at point P at time t should be the sum of contributions from all volume elements, i.e., c(x,t)=(c0)/(2√(πDt))∫_x^∞exp(-ξ²/(4Dt))dξ=(c0)/√π∫_(x/√π)^∞exp(-η²)dη. Here, η=ξ/2√Dt; erf(β)=2/√π∫_0^βe^(-η²)dη. erf(β) is the error function, and its values are given in Table 5-1. Note that erf(β)=∫_β^∞e^(-η²)dη=∫_0^∞e^(-η²)dη-∫_0^βe^(-η²)dη=√π/2[1-erf(β)]. Thus, c(x,t)=c0/2 erf(x²/(2√Dt)), as shown in Figure 5-7. When x<0, the concentration increases with |x|; when x>0, the concentration decreases with x; at x=0, when t>0, c=c0/2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析浓度分布曲线随时间的变化，解答过程中涉及复杂的数学推导和公式应用，包括积分、误差函数等计算步骤，属于典型的计算题类型。 | 知识层次: 题目涉及扩散偶的浓度分布随时间变化的分析，需要综合运用扩散理论、误差函数、叠加原理等知识，进行多步推理和计算，属于复杂分析和综合运用层次。 | 难度: 在选择题型内，该题目属于高难度综合计算问题。题目涉及复杂的扩散偶分析，需要综合运用扩散理论、误差函数（erf）以及叠加原理等多个高级概念。解题步骤包括初始条件的设定、体积元素的划分、瞬时平面源扩散问题的等效处理、积分运算以及误差函数的应用，这些都要求考生具备深厚的材料科学基础和数学分析能力。此外，题目还要求考生能够理解和解释浓度分布曲线的变化机理，这在选择题型中属于最高层次的难度要求。" + }, + { + "idx": 2141, + "question": "In a ternary system during diffusion, can a three-phase coexistence region appear within the diffusion layer? Why?", + "answer": "A three-phase coexistence region cannot exist within the diffusion layer of a ternary system. The reasons are as follows: If three-phase equilibrium coexistence occurs in a ternary system, the compositions of the three phases are fixed, and the chemical potentials of the same component in different phases are equal, resulting in a zero chemical potential gradient, making diffusion impossible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对三元系统中扩散层内三相共存区域的存在性进行解释和论述，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目涉及三元系统中扩散层的多相平衡问题，需要理解相平衡条件、化学势梯度与扩散的关系，并进行逻辑推理和综合分析。这超出了简单记忆或基本应用的范围，属于对复杂现象的解释和分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2142, + "question": "For NaCl crystals doped with a small amount of $\\\\mathrm{Cd}^{2+}$, the number of $\\\\mathrm{Na^{+}}$ vacancies related to Schottky defects at high temperatures is much higher than that related to $\\\\mathrm{Cd}^{2+}$, so intrinsic diffusion dominates. At low temperatures, the vacancies caused by the presence of $\\\\mathrm{Cd}^{2+}$ ions can accelerate the diffusion of $\\\\mathrm{Na^{+}}$ ions. Analyze how the transition point temperature in Figure 5-5 would shift if the concentration of $\\\\mathrm{Cd}^{2+}$ is reduced.", + "answer": "The transition point shifts toward lower temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析掺杂浓度变化对转变温度的影响，并给出解释性答案，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析掺杂浓度变化对过渡温度的影响，涉及Schottky缺陷和掺杂缺陷的竞争机制，需要综合运用扩散机制、缺陷化学和温度效应的知识进行推理分析，思维过程较为复杂。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用材料科学中的缺陷化学和扩散机理知识，分析掺杂浓度变化对过渡温度的影响。考生需要理解Schottky缺陷与掺杂缺陷的竞争关系，并推理内在扩散与外在扩散主导的温度区间变化。这种复杂现象的分析不仅需要深入掌握相关机理，还需要在选择题的有限选项中准确判断因果关系，体现了最高层次的综合分析和推理能力。" + }, + { + "idx": 2143, + "question": "Point out the errors in the following concept: (1) If there is no diffusion flow in a solid, it means that atoms are not diffusing.", + "answer": "Even if there is no macroscopic diffusion flow in a solid, diffusion still occurs due to the migration jumps of atomic thermal vibrations. Self-diffusion in pure substances is a typical example.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行解释，答案通过文字论述说明了即使没有宏观扩散流，扩散仍然发生的原因，符合简答题的特征。 | 知识层次: 题目要求分析并指出概念中的错误，需要理解扩散现象的微观机制（原子热振动迁移）与宏观表现（扩散流）之间的关系，并进行推理分析。这涉及对扩散原理的深度理解和综合运用，超出了简单记忆或应用的范畴。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求理解扩散的基本概念，还需要深入掌握扩散的微观机理（如原子热振动迁移跳跃）和宏观表现（无净扩散流）之间的关系。正确选项涉及对自扩散现象的机理解释，这需要学生具备将微观原子行为与宏观现象联系起来的能力，属于复杂分析层次的知识运用。" + }, + { + "idx": 2144, + "question": "In a ternary system during diffusion, can a two-phase coexistence region appear within the diffusion layer? Why?", + "answer": "A two-phase coexistence region can exist within the diffusion layer of a ternary system. The reasons are as follows: In a ternary system, when two phases coexist, due to the degree of freedom being 2, at a constant temperature, the composition of the coexisting phases can change. This disrupts the chemical potential balance of the same component atoms in the two phases, leading to diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在三元系统中扩散层内会出现两相共存区域，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及三元系统中扩散层的两相共存现象，需要理解相平衡的自由度概念、化学势平衡的破坏机制以及扩散过程的驱动因素。这需要综合运用相图知识、热力学原理和扩散理论进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对三元系统中的扩散现象进行复杂分析，涉及两相共存区域的机理解释和化学势平衡的推理。需要综合运用热力学、相平衡和扩散理论的知识，进行深度解释和全面分析。这种题目不仅考察知识点的掌握深度，还要求考生能够将多个复杂概念联系起来进行推理，因此在选择题型中属于最难的一类。" + }, + { + "idx": 2145, + "question": "Point out the error in the following concept: (2) Because the direction of each jump of solid atoms is random, the diffusion flux is zero under any circumstances.", + "answer": "The direction of each jump of atoms is random. Only when the system is in thermal equilibrium, the probability of atoms jumping in any direction is equal. At this time, although there is atomic migration (i.e., diffusion), there is no macroscopic diffusion flow. If the system is in a non-equilibrium state, there must be a gradient of thermodynamic potential in the system (specifically expressed as concentration gradient, chemical potential gradient, strain energy gradient, etc.). The probability of atoms jumping in the direction of decreasing thermodynamic potential will be greater than that in the direction of increasing thermodynamic potential. As a result, macroscopic diffusion flow occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行详细的文字解释和论述，答案形式为一段完整的论述性文字，而非选择、判断或计算。 | 知识层次: 题目要求对扩散现象进行深入分析，涉及非平衡态热力学、概率统计和宏观扩散流的关系，需要综合运用多个概念并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2146, + "question": "Point out the error in the following concept: (3) The atomic arrangement at grain boundaries is disordered, and there are no vacancies, so atoms diffusing by the vacancy mechanism cannot diffuse at grain boundaries.", + "answer": "The atomic arrangement at grain boundaries is disordered, similar to that in amorphous phases, and the atomic packing density is much lower than inside the grains, resulting in weaker constraints on atoms. The energy and vibration frequency ν of grain boundary atoms are significantly higher than those of intragranular atoms. Therefore, atoms at grain boundaries have higher mobility. The grain boundary diffusion coefficient is also significantly higher than the intragranular diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行解释，答案通过文字论述详细说明了晶界扩散的机制和特点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求对晶界扩散机制进行深入分析和解释，涉及晶界原子排列、原子振动频率、扩散系数等多个概念的关联和综合分析，需要较高的推理分析能力和机理解释能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶界原子排列的无序性、原子堆积密度低等基本概念，还需要综合运用扩散机制、原子振动频率、扩散系数等知识进行复杂现象的全面分析。正确选项涉及多个深层次机理的解释和推理，需要考生具备将不同知识点串联起来进行综合判断的能力，这远超出简单记忆或单一概念应用的难度水平。" + }, + { + "idx": 2147, + "question": "Point out the error in the following concept: (4) In an interstitial solid solution, the higher the solute concentration, the more interstitial sites are occupied by the solute, leaving fewer vacant interstitial sites for diffusion, i.e., the value of $_z$ decreases, leading to a reduction in the diffusion coefficient.", + "answer": "In fact, this scenario is impossible. The solubility of solute atoms in an interstitial solid solution is very limited. Even in a supersaturated state, the number of solute atoms is several orders of magnitude smaller than the total number of interstitial sites in the crystal. Therefore, the interstitial sites around the solute atoms can be considered entirely vacant. That is, for a given crystal structure, 𝓏 is a constant.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个概念陈述是否正确，并指出其中的错误。答案通过解释说明了原陈述的错误之处，符合判断题的特征。 | 知识层次: 题目需要理解间隙固溶体的基本概念，并能够分析间隙位置占据与扩散系数之间的关系。虽然涉及基础概念，但需要综合分析间隙固溶体的溶解度限制和扩散机制，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析多个概念并进行推理判断。题目要求考生不仅理解间隙固溶体的基本概念，还需要掌握溶质原子在间隙固溶体中的溶解度限制，以及扩散系数的相关影响因素。此外，还需要判断题目中描述的情景是否可能，并给出正确的解释。这涉及到多步的概念关联和综合分析，因此难度较高。" + }, + { + "idx": 2148, + "question": "For a pre-annealed metal polycrystal, the relationship between true stress σ_T and true strain ε_T in the uniform plastic deformation stage of the true stress-strain curve is given by σ_T=Kε_T^n, where K is the strength coefficient and n is the strain hardening exponent. If there are two metals A and B with roughly equal K values, but n_A=0.5 and n_B=0.2, which metal has higher hardening capability and why?", + "answer": "Since σ_T=Kε_T^n, then dσ_T=n Kε_T^(n-1)dε_T, and θ=dσ_T/dε_T=n Kε_T^(n-1). From this equation, it can be seen that when ε_T<1 and 0n_B, metal B has a higher dislocation density at the same plastic strain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的推导过程和结论，而不是简单的选择或判断。 | 知识层次: 题目需要理解应变硬化指数与位错密度的关系，并应用给定的公式进行综合分析。虽然涉及基本公式的应用，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用多个概念（应变硬化指数、位错密度与应力的关系）并进行多步逻辑推理。题目要求考生不仅理解σ_T=Kε_T^n公式的含义，还要掌握σ_T与位错密度ρ的关联性（σ_T∝√ρ），并能在给定条件下（K值相近、ε_T<1）比较不同n值对位错密度的影响。这种需要将不同知识点串联分析，并在特定条件下推导结论的题目，在选择题型中属于多角度分析论述的难度层次。" + }, + { + "idx": 2152, + "question": "For a face-centered cubic crystal, the movable slip system is (111)[110]. If the slip is caused by a pure edge dislocation, indicate the direction of the dislocation line.", + "answer": "The dislocation line lies on the slip plane (111). Let the direction of the dislocation line be [uow], then u+v-w=0; the dislocation line is perpendicular to b, i.e., perpendicular to [110], so -u+v=0. From the above two equations, u:v:w=1:1:2, thus the direction of the dislocation line is [112].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错线的方向，答案给出了详细的推导过程和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解面心立方晶体的滑移系统，并应用几何关系推导位错线方向。涉及多步计算和概念关联，需要综合分析滑移面、位错线和柏氏矢量的几何关系。 | 难度: 在选择题型中，该题目属于较高难度。原因如下：" + }, + { + "idx": 2153, + "question": "If the surface of a single crystal copper is exactly the {100} crystal plane, assuming the crystal can slip on various slip systems, discuss the possible morphology of slip lines (the orientation of slip lines and the angles between them) that may be observed on the surface.", + "answer": "Copper crystal has a face-centered cubic lattice, and its slip systems are {111}<110>. If the surface of the single crystal copper is the {100} crystal plane, when plastic deformation occurs, the slip lines appearing on the crystal surface should be the intersection lines of {111} and {100}, which are <110>. That is, the slip lines observed on the crystal surface are either parallel to each other or intersect at a 90° angle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论单晶铜表面滑移线的可能形态，包括滑移线的取向和它们之间的角度，这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析单晶铜在特定晶面（{100}）上的滑移线形态，需要理解面心立方晶体的滑移系统（{111}<110>），并能够将滑移面与观察面的几何关系进行综合分析。这涉及到多步概念关联和几何分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，需要理解面心立方晶体的滑移系统{111}<110>，并能够将其与给定的{100}晶面关联。其次，需要计算{111}和{100}晶面的交线方向<110>，并理解滑移线的形态（平行或90°相交）。这涉及多步计算和概念关联，要求考生具备综合分析能力。虽然题目给出了正确选项，但推导过程较为复杂，超出了基础选择题的难度范围。" + }, + { + "idx": 2154, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], indicate the direction of dislocation line movement during slip in the cases of pure edge dislocation and pure screw dislocation.", + "answer": "In the case of pure edge dislocation, the direction of dislocation line movement is parallel to b; in the case of pure screw dislocation, the direction of dislocation line movement is perpendicular to b.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述纯刃型位错和纯螺型位错在位错线移动时的方向，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析面心立方晶体中特定滑移系统下纯刃型位错和纯螺型位错的运动方向，需要理解位错类型与运动方向的关系，并能够将这一知识应用到具体晶体结构中。这涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 2155, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], if the slip is caused by pure screw dislocations, indicate the direction of the dislocation line.", + "answer": "The dislocation line lies on the slip plane and is parallel to b, so the direction of the dislocation line is [110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案需要详细说明位错线的方向及其原因，而不是简单的选择或判断。 | 知识层次: 题目需要理解面心立方晶体滑移系统的基本概念，并能够将纯螺位错的性质与滑移方向关联起来。虽然涉及基础概念，但需要一定的综合分析能力来确定位错线的方向。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解面心立方晶体结构、滑移系统（111）[110]以及纯螺型位错的概念。其次，需要将位错线的方向与滑移方向（b矢量）联系起来，进行多步分析和概念关联。此外，题目还隐含了位错线必须位于滑移面上的条件，这需要考生具备综合分析能力。虽然题目给出了正确选项，但推导过程涉及多个晶体学概念的深度理解和应用，超出了简单记忆或单一概念应用的范畴，因此在选择题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 2156, + "question": "When a tensile force is applied along the [0001] direction of a hexagonal close-packed single crystal, what are the possible deformations and the primary mode of deformation?", + "answer": "The slip plane of hexagonal close-packed metals is (0001), and the resolved shear stress on the slip plane in the [0001] direction is zero, so the single crystal cannot slip. During tension, the possible deformations of the single crystal are elastic deformation or subsequent brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释可能的变形和主要变形模式，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解六方密堆积单晶的滑移面和方向，并分析在特定方向施加拉力时的变形机制。这涉及到对晶体结构、滑移系统和应力分解的综合理解，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 2157, + "question": "A 20m long aluminum rod with a diameter of 14.0mm is drawn through a die with an aperture of 12.7mm. Calculate the cold working rate that this aluminum rod will undergo.", + "answer": "The cold working rate (CW) can be expressed as the percentage reduction in cross-sectional area caused by plastic deformation, i.e., CW=[π×(14.0/2)^2-π×(12.7/2)^2]/[π×(14.0/2)^2]=18%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解冷加工率，答案是一个具体的百分比数值，需要通过计算得出。 | 知识层次: 题目涉及基本的公式应用和简单计算，仅需套用冷加工率的定义公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（冷加工率计算公式）并进行简单的数值代入和计算。题目没有涉及多个公式的组合或复杂的逻辑推理，属于最基础的直接计算类型。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2158, + "question": "The critical resolved shear stress of an aluminum single crystal at room temperature is $7.9\\\\times10^{5}~\\\\mathrm{Pa}$. If a tensile test is performed on an aluminum single crystal specimen at room temperature with the tensile axis in the [123] direction, and the possible activated slip system is (111)[101], determine the stress required to cause the specimen to yield.", + "answer": "The aluminum crystal has a face-centered cubic lattice, and its slip system is $\\\\{111\\\\}<110>$. When performing a tensile test on an aluminum single crystal: $$ \\\\sigma_{s}=\\\\frac{\\\\tau_{\\\\mathrm{c}}}{\\\\cos\\\\varphi\\\\cos\\\\lambda} $$ Given $\\\\tau_{\\\\mathrm{c}}=7.9\\\\times10^{5}~\\\\mathrm{Pa}$, when the external force axis direction is [123], the possible activated slip system is (111)[101]. Thus, $\\\\varphi$ is the angle between [123] and the normal [111] of the (111) crystal plane, and $\\\\lambda$ is the angle between [123] and [101]. $$ \\\\mathrm{cos}\\\\varphi={\\\\frac{{\\\\overline{{1}}}+2+3}{\\\\sqrt{14}\\\\times\\\\sqrt{3}}}={\\\\frac{4}{\\\\sqrt{42}}} $$ $$ \\\\cos\\\\lambda={\\\\frac{1+0+3}{\\\\sqrt{14}\\\\times{\\\\sqrt{2}}}}={\\\\frac{2}{\\\\sqrt{7}}} $$ Therefore, $$ \\\\sigma_{\\\\mathrm{s}}=\\\\frac{7.9\\\\times10^{5}}{\\\\frac{4}{\\\\sqrt{42}}\\\\times\\\\frac{2}{\\\\sqrt{7}}}=1.69\\\\times10^{6}~\\\\mathrm{Pa} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定应力值，解答过程中涉及角度计算和临界分切应力的应用，最终得出具体的数值结果。 | 知识层次: 题目涉及多步计算，需要理解临界分切应力的概念，并应用施密特定律进行计算。同时需要计算晶体学方向之间的角度，涉及多个步骤和概念的综合应用。 | 难度: 在选择题中属于中等偏上难度，需要理解临界分切应力的概念，掌握晶体学方向指数的计算，并能正确应用施密特定律进行多步骤计算。题目涉及向量点积、角度计算和应力转换等综合分析步骤，对学生的空间想象力和数学计算能力有一定要求。虽然题目提供了具体方向和滑移系统，但计算过程较为复杂，属于综合性计算问题。" + }, + { + "idx": 2159, + "question": "For a pre-annealed metal polycrystal, the relationship between true stress σ_T and true strain ε_T in the uniform plastic deformation stage of the true stress-strain curve is given by σ_T=Kε_T^n, where K is the strength coefficient and n is the strain hardening exponent. Derive the mathematical relationship between the strain hardening exponent n and the strain hardening rate θ=dσ_T/dε_T.", + "answer": "The definition of the strain hardening rate θ is θ=dσ_T/dε_T. From σ_T=Kε_T^n, we obtain dσ_T/dε_T=n Kε_T^(n-1), that is, θ=n Kε_T^(n-1). Further derivation yields θ=n(σ_T/ε_T^n)ε_T^(n-1)=n(σ_T/ε_T).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数学推导来建立应变硬化指数n与应变硬化率θ之间的关系，涉及公式应用和推导过程，属于计算题。 | 知识层次: 题目需要理解应变硬化指数和应变硬化速率之间的关系，并能够进行多步推导和公式应用。虽然涉及的概念和公式较为基础，但需要一定的综合分析能力和数学推导技巧，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解应变硬化指数和应变硬化率的概念，并进行多步推导计算。题目要求从给定的真实应力-应变关系出发，通过微分和代数运算推导出两者之间的关系，涉及中等应用层次的知识和综合分析能力。" + }, + { + "idx": 2160, + "question": "If the surface of a single crystal copper is the {111} crystal plane, assuming that the crystal can slip on various slip systems. Discuss the possible morphology of slip lines on the surface (the orientation of slip lines and the angles between them).", + "answer": "When the outer surface of a copper single crystal is the {111} family of crystal planes, the slip lines appearing on the surface are <110>, which are either parallel to each other or intersect at an angle of 60°.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论单晶铜表面滑移线的可能形态（滑移线的取向和它们之间的角度），需要文字解释和论述，而不是选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求分析单晶铜在特定晶面（{111}）上的滑移线形态，涉及晶体滑移系统的选择和滑移线方向的确定。这需要理解晶体结构、滑移系统的基本原理，并能将这些概念应用于具体情境中。虽然不涉及复杂的计算或深度推理，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生掌握晶体滑移系统的基本概念，理解{111}晶面和<110>滑移方向的关系，并能综合分析滑移线在表面形成的可能形态（平行或60°夹角）。这需要将晶体学知识与实际观察现象进行多角度关联，并正确推导出结论，超出了简单记忆或单一概念应用的层次。" + }, + { + "idx": 2161, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], indicate the Burgers vector of the unit dislocation causing the slip (taking the lattice constant a=0.2nm).", + "answer": "The Burgers vector of the unit dislocation causing the slip is b=a/2[110], which is the vector represented by the line connecting two adjacent atoms along the slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释并给出Burgers vector的具体表达式，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求应用基本的晶体学知识（面心立方晶体的滑移系和伯格斯矢量）进行计算和解释，涉及直接套用已知公式和概念，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接套用和简单计算。题目明确给出了晶体结构和滑移系统，只需根据已知条件直接应用Burgers向量的计算公式即可得出答案，无需复杂的分析或推理过程。因此，在选择题型内属于较低难度。" + }, + { + "idx": 2162, + "question": "When a compressive force is applied along the [0001] direction of a hexagonal close-packed single crystal, what are the possibilities of deformation and the primary mode of deformation?", + "answer": "The slip plane of hexagonal close-packed metals is (0001), and the resolved shear stress on the slip plane in the [0001] direction is zero, so the single crystal cannot slip. During compression, after elastic deformation, twinning may occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下材料的变形可能性及主要变形模式，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析六方密堆积单晶在特定方向受压时的变形可能性及主要变形模式，涉及对滑移面和孪生变形的理解，需要将晶体结构、滑移系和应力分析等概念关联起来进行综合分析。虽然不涉及复杂计算，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 2163, + "question": "Calculate the volume fraction of the Fe3C phase in 40 steel, given the mass fraction of carbon ωC=0.004", + "answer": "φFe3C=0.004/0.069=0.06", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Fe3C相的体积分数），并给出了具体的计算公式和数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的质量分数到体积分数的转换计算，仅需直接套用公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用单一公式（体积分数=质量分数/相成分比例）进行简单计算，无需多步骤推理或复杂概念理解，属于最基础的难度等级。" + }, + { + "idx": 2164, + "question": "The movable slip system of a certain face-centered cubic crystal is (111)[110]. Assuming a shear stress of magnitude 0.7MPa acts on this slip system, calculate the magnitude and direction of the force per unit length on a unit edge dislocation and a unit screw dislocation (take the lattice constant a=0.2nm).", + "answer": "Under the applied shear stress τ, the magnitude of the force per unit length on the dislocation line is F=τb, and the direction is perpendicular to the dislocation line. Here, |b|=√((a/2)^2+(a/2)^2)=√2/2a, so F=τb=0.7×√2/2a=0.7×√2×0.2×10^-9/2=9.899×10^-11MN/m. The direction of F is perpendicular to the dislocation line; the direction of F is also perpendicular to the dislocation line.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算力的大小和方向）并应用相关公式（F=τb），答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错的基本性质、滑移系统的定义，并应用剪切应力与位错力的关系公式进行计算。虽然计算过程较为直接，但需要对位错方向和力的方向有清晰的理解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解位错的基本概念、滑移系统的几何关系，并进行多步计算。题目要求计算单位长度上的力，并确定方向，涉及矢量分析和材料科学的基本原理。虽然题目提供了部分计算步骤，但仍需要综合应用多个知识点才能正确解答。" + }, + { + "idx": 2165, + "question": "Calculate the interparticle spacing λ, given the number of Fe3C particles per unit volume NV=1.43×1013", + "answer": "λ=NV-1/3=(1.43×1013)-1/3=0.24×10-5m=2.4μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算interparticle spacing λ），并给出了具体的计算公式和步骤，最终需要得出一个具体的数值结果。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析，属于简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（NV-1/3）进行计算，无需额外的概念理解或步骤组合。属于最基础的难度等级，仅需基本公式应用和简单计算能力。" + }, + { + "idx": 2166, + "question": "Calculate the number of Fe3C particles per unit volume NV, given the volume fraction of Fe3C phase φFe3C=0.06 and the spherical particle radius r=10×10-6m", + "answer": "NV=φFe3C/(4/3πr3)=0.06/(4/3π×(10×10-6)3)≈1.43×1013", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即通过给定的体积分数和粒子半径直接套用公式计算粒子数密度，不需要多步计算或综合分析。 | 难度: 在选择题中属于最低难度，仅需直接套用单一公式进行计算，无需理解复杂概念或多步骤推理。题目提供了所有必要参数，只需将数值代入公式即可得出答案，属于基本公式应用和简单计算的范畴。" + }, + { + "idx": 2167, + "question": "Calculate the Burgers vector b of α-Fe, given the lattice constant of α-Fe a=0.28nm", + "answer": "b=√3/2a=√3/2×0.28=0.25nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers vector b），并给出了具体的公式应用（b=√3/2a），最终答案是一个具体的数值结果（0.25nm）。这符合计算题的特征。 | 知识层次: 题目仅需应用已知公式（Burgers vector计算公式）进行一步数值计算，无需多步推理或综合分析，属于基本公式的直接套用。 | 难度: 在选择题型中，该题目仅需要直接套用已知公式（Burgers vector计算公式）并进行简单数值计算。题目没有涉及多个公式的组合或复杂推导，属于单一公式直接计算的类型，因此难度等级为1。" + }, + { + "idx": 2168, + "question": "Calculate the shear strength τ of 40 steel, given the shear modulus of iron GFe=7.9×1010Pa, Burgers vector b=0.25nm, and particle spacing λ=2.4μm", + "answer": "τ=Gb/λ=7.9×1010×2.5×10-10/2.4×10-5=8.23×105Pa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出具体的数值结果。答案的形式是一个具体的计算结果，解答过程涉及公式应用和数值运算。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及到的知识点较为基础，思维过程较为直接，无需多步计算或综合分析。 | 难度: 在选择题型内，该题目属于单一公式直接计算的难度等级。题目明确给出了所有必要的参数（G, b, λ），并直接要求套用公式τ=Gb/λ进行计算。解题步骤简单直接，无需额外的概念理解或公式组合，仅需进行基本的单位换算和数值代入。在选择题的背景下，这种类型的题目属于最基础的难度级别。" + }, + { + "idx": 2169, + "question": "Give the relationship between the lattice resistance to dislocation motion and the crystal structure.", + "answer": "τ_p≈(2G/(1-ν))exp[-(2πa)/((1-ν)b)]≈(2G/(1-ν))exp(-2πw/b) where w is the dislocation width (w=a/(1-ν)), a is the interplanar spacing of the slip plane, b is the atomic spacing in the slip direction, and ν is the Poisson's ratio.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求给出晶格对位错运动的阻力与晶体结构之间的关系，答案是一个公式解释，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求解释晶格对位错运动的阻力与晶体结构之间的关系，并给出了具体的数学表达式。这需要综合运用材料科学中的位错理论、晶体结构知识以及相关的物理参数（如剪切模量G、泊松比ν等）进行推理分析。此外，理解并解释公式中各参数的含义及其相互关系，需要较高的认知能力和深度理解，属于复杂分析的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2170, + "question": "What is single slip? What are the characteristics of its slip lines?", + "answer": "Single slip refers to the slip occurring on only one slip system. The slip lines appear as a series of parallel straight lines. This is because in single slip, only one set of slip systems is active, where all slip planes are parallel to each other and the slip directions are identical.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"single slip\"及其滑移线特征进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对单滑移及其滑移线特征的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生不仅知道单滑移的定义，还要理解其滑移线的特征。正确选项中对单滑移的解释和滑移线特征的描述较为详细，要求考生具备一定的概念理解和描述能力，而不仅仅是简单的定义记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2171, + "question": "For annealed pure iron with a grain size of $N_{\\\\mathrm{A}}=16$ grains/mm², its yield strength $\\\\sigma_{\\\\textrm{s}}=100$ MPa; when $N_{\\\\mathrm{A}}=4~096$ grains/mm², $\\\\sigma_{\\\\mathrm{s}}=250\\\\mathrm{MPa}$. Calculate $\\\\sigma_{s}$ when $N_{\\\\mathrm{A}}=250$ grains/mm².", + "answer": "Let the average grain diameter be $d$, and the number of grains per square millimeter be $N_{\\\\mathrm{A}}$. It can be proven that $$ d=\\\\sqrt{\\\\frac{8}{3\\\\pi N_{\\\\mathrm{A}}}} $$ Therefore, $$ d_{1}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times16}}=0.053\\\\mathrm{~mm} $$ $$ d_{2}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times4~096}}=2.072\\\\times10^{-4}~\\\\mathrm{mm} $$ $$ d_{3}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times250}}=3.395\\\\times10^{-3}\\\\mathrm{mm} $$ Substituting into the Hall-Petch formula, $$ \\\\begin{array}{l}{\\\\left\\\\{100=\\\\sigma_{0}+K(0.053)^{-1/2}\\\\right.} \\\\\\\\ {\\\\left.250=\\\\sigma_{0}+K(2.072\\\\times10^{-4})^{-1/2}\\\\right.}\\\\end{array} $$ Solving gives $$ \\\\sigma_{0}=90\\\\mathrm{MPa} $$ Therefore, when $N_{\\\\mathrm{A}}=250$ grains/mm² and $d=3.395\\\\times10^{-3}\\\\mathrm{mm}$, $$ \\\\sigma_{\\\\mathrm{s}}=90+2.303\\\\times(3.395\\\\times10^{-3})^{-1/2}=129.5~\\\\mathrm{MPa} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch公式）来求解特定条件下的屈服强度，答案包含详细的数学推导和计算结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值求解。虽然不涉及复杂的机理分析或创新应用，但需要一定的综合分析能力和计算技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和变量求解。虽然题目提供了部分计算过程，但需要考生掌握晶粒尺寸与屈服强度的关系，并能正确代入公式求解。此外，还需要解二元一次方程组来求得材料常数，最后再进行一次公式应用计算目标值。这些步骤在选择题型中属于较为复杂的计算过程。" + }, + { + "idx": 2172, + "question": "Given that the critical resolved shear stress τc for the {111}[110] slip system in pure copper is 1MPa, what stress should be applied in the [001] direction to produce slip in the [101] direction on the (111) plane?", + "answer": "For cubic crystals, the angle between two crystallographic directions [u1v1w1] and [u2v2w2] is given by cosφ=(u1u2+v1v2+w1w2)/(√(u1²+v1²+w1²)*√(u2²+v2²+w2²)). Therefore, the angle between the normal direction [111] of the slip plane (111) and the tensile axis [001] is cosφ=(1×0+1×0+1×1)/(√(1²+1²+1²)*√(0²+0²+1²))=1/√3=0.577. The angle between the slip direction [101] and the tensile axis [001] is cosλ=(1×0+0×0+1×1)/(√(1²+0²+1²)*√(0²+0²+1²))=1/√2=0.707. The applied stress σ=τc/(cosφcosλ)=1/(0.577×0.707)=2.45MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解应力值，解答过程中涉及角度计算和应力公式的应用，最终给出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括角度计算和应力计算，并需要理解临界分切应力的概念及其与施加应力的关系。虽然涉及公式的直接应用，但需要综合运用晶体学知识和力学概念来解决问题。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体学方向计算、临界分切应力概念，并进行多步骤的向量点积和反余弦计算。虽然题目提供了公式，但需要正确应用并综合计算才能得出最终应力值，涉及中等应用层次的知识关联和综合分析能力。" + }, + { + "idx": 2173, + "question": "When stretching a copper single crystal, if the direction of the tensile axis is [001], $\\\\sigma=10^{6}$ Pa. Calculate the force on the screw dislocation line with Burgers vector $b=$ $\\\\frac{a}{2}$ [101] on the (111) plane $(a_{\\\\mathrm{Cu}}=0.36\\\\mathrm{nm})$.", + "answer": "Let the resolved shear stress of the applied tensile stress along the [101] direction on the (111) slip plane be $\\\\tau$, then $$ x \\\\tau=\\\\sigma{\\\\cos}\\\\varphi{\\\\cos}\\\\lambda\\n $$\\n where, $\\\\varphi$ is the angle between [001] and the normal [111] of the (111) plane, $\\\\lambda$ is the angle between [001] and the [101] direction. \\n\\nSo $$ \\\\tau=10^{6}\\\\times{\\\\frac{1}{{\\\\sqrt{1}}\\\\times{\\\\sqrt{3}}}}\\\\times{\\\\frac{1}{\\\\sqrt{2}}}=4.0825\\\\times10^{5}{\\\\mathrm{~Pa}}\\n $$\\n If the force on the screw dislocation line is $F_{\\\\mathrm{d}}$, then $$ F_{\\\\mathrm{d}}=\\\\tau b=4.0825\\\\times10^{5}\\\\times{\\\\frac{\\\\sqrt{2}}{2}}\\\\times0.36\\\\times10^{-9}=1.039\\\\times10^{-4}~{\\\\mathrm{N/m}}\\n $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了应力分解、角度计算和力的计算，最终给出了具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括计算分解剪应力、角度计算以及最终的力计算，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的理解和应用能力。 | 难度: 在选择题型中，这道题目属于高难度等级。原因如下：" + }, + { + "idx": 2174, + "question": "What is cross-slip? What are the characteristics of its slip lines?", + "answer": "Cross-slip refers to the simultaneous or alternating slip of two or more slip planes along a common slip direction. Their slip lines are usually zigzag or wavy. This is the result of screw dislocations repeatedly 'expanding' on different slip planes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"cross-slip\"进行定义并描述其滑移线特征，需要文字解释和论述，属于简答题类型。 | 知识层次: 题目考查对交叉滑移（cross-slip）这一基本概念的定义及其滑移线特征的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生不仅知道\"cross-slip\"的基本定义，还需要理解其特征（如zigzag或wavy slip lines）以及形成机制（screw dislocations在不同滑移面上的运动）。这超出了简单的定义记忆，需要对概念进行一定程度的解释和描述，但尚未达到需要阐述复杂概念体系的难度。" + }, + { + "idx": 2175, + "question": "Give examples of the impact of Lüders bands on industrial production and methods to prevent them.", + "answer": "Lüders bands can cause the surface of workpieces made from low-carbon thin steel sheets to become rough and uneven during stamping and forming. The solution, based on the strain aging principle, involves subjecting the steel sheet to a slight cold rolling process (e.g., 1%∼2% reduction) before stamping to eliminate the yield point, followed by stamping and forming. Alternatively, adding small amounts of Ti, Al, C, and N to the steel to form compounds can also eliminate the yield point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求给出具体例子和解决方法，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Lüders bands对工业生产的影响以及预防方法，涉及对材料科学中应变时效原理的理解和应用，需要多步分析和概念关联。虽然不涉及复杂计算，但需要对材料行为及其工业应用有较深入的理解和综合分析能力。 | 难度: 在选择题中属于较高难度，题目要求考生不仅要理解Lüders bands的概念及其对工业生产的影响，还需要掌握具体的预防方法（如冷轧工艺和合金添加）。这涉及到多步骤的分析和综合应用知识的能力，包括对材料科学原理（应变时效）的理解和实际工业应用的关联。此外，题目还要求考生能够区分不同解决方案的适用性和原理，这增加了题目的复杂性和难度。" + }, + { + "idx": 2176, + "question": "How is texture formed?", + "answer": "After cold working, the orientations of metal grains exhibit certain relationships. For instance, certain crystal planes or directions become parallel to each other and also parallel to an external reference direction of the component. Such an orientation distribution is called preferred orientation or simply texture. The formation of texture is not limited to cold working, but here it mainly refers to deformation texture. In terms of both orientation and properties, polycrystalline materials with texture lie between single crystals and completely randomly oriented polycrystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"How is texture formed?\"进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目不仅要求解释纹理的定义，还需要论述其形成机制和影响因素，涉及多步骤的推理分析和机理解释，思维深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解金属晶粒取向的基本概念，还需要掌握冷加工后晶粒取向变化的复杂机理，并能解释变形织构的形成过程。这涉及到对多晶体材料、单晶体和随机取向多晶体之间性质差异的综合分析，需要考生具备深厚的材料科学基础和机理推理能力。在选择题中，这种要求全面分析复杂现象并解释深层机理的题目属于最高难度。" + }, + { + "idx": 2177, + "question": "What is multiple slip? What are the characteristics of its slip lines?", + "answer": "Multiple slip refers to the simultaneous or alternating slip of two or more different slip systems. Their slip lines are either parallel or intersect at a certain angle. This is because certain crystal structures have specific slip systems, and there are certain angles between the slip planes and slip directions of these slip systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"multiple slip\"及其滑移线特征进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对\"multiple slip\"这一基础概念的定义及其特征的理解和记忆，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（multiple slip的定义和特征），但正确选项已经整合了这些概念，并提供了清晰的解释。考生需要理解并记忆multiple slip的基本定义及其滑移线的特征，但不需要进行复杂的分析或比较。题目主要考察基础概念的记忆和理解，符合等级2的要求。" + }, + { + "idx": 2178, + "question": "For face-centered cubic crystals, it is generally required to have five independent slip systems for slip to occur. Is this conclusion correct? Please explain the reason and the conditions under which this conclusion applies.", + "answer": "This conclusion is correct. Because generally, representing a deformation requires nine strain components, i.e., $$ \\\\mathfrak{\\\\varepsilon}_{i j}=\\\\left|\\\\begin{array}{l l l}{\\\\varepsilon_{x x}}&{\\\\mathfrak{\\\\varepsilon}_{x y}}&{\\\\mathfrak{\\\\varepsilon}_{x z}}\\\\\\\\{\\\\mathfrak{\\\\varepsilon}_{y y}}&{\\\\mathfrak{\\\\varepsilon}_{y x}}&{\\\\mathfrak{\\\\varepsilon}_{y z}}\\\\\\\\{\\\\mathfrak{\\\\varepsilon}_{z z}}&{\\\\mathfrak{\\\\varepsilon}_{z x}}&{\\\\mathfrak{\\\\varepsilon}_{z y}}\\\\end{array}\\\\right| $$ but $\\\\varepsilon_{x y}=\\\\varepsilon_{y x}, \\\\varepsilon_{y z}=\\\\varepsilon_{z y}, \\\\varepsilon_{z x}=\\\\varepsilon_{x z}$; thus, there are only six components left. Since the deformation is required to be uniform and continuous, the volume remains unchanged before and after deformation, i.e., $\\\\Delta V{=}_{\\\\epsilon_{x x}}+\\\\epsilon_{y y}+\\\\epsilon_{z z}{=}0$. With this constraint, there are only five independent strain components. Each independent strain component is generated by an independent slip system; therefore, five independent slip systems are needed to produce five independent strain components. When applying this conclusion, attention must be paid to the size of the crystal. The volume cannot be too small; it must be larger than the spacing between slip bands so that the plastic deformation can be considered uniform. However, the volume cannot be too large either; it must remain within the range of linear plastic deformation, such as not exceeding the size of a single grain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结论的正确性及其适用条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释面心立方晶体需要五个独立滑移系统的原因，还需要分析该结论适用的条件。这涉及到对晶体塑性变形机制的深入理解，包括应变张量的分析、体积不变条件的应用，以及晶体尺寸对变形均匀性的影响。需要综合运用多个概念进行推理分析，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2180, + "question": "How is fibrous structure formed?", + "answer": "After cold working of materials, in addition to transforming the disordered orientation of polycrystalline materials into materials with preferred orientation, it also causes deformation of insoluble impurities, second phases, and various defects in the material. Since grains, impurities, second phases, and defects are all elongated into fibrous shapes along the main deformation direction of the metal, it is called fibrous structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维状结构的形成过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释纤维结构的形成过程，还需要理解冷加工对材料微观结构的影响，包括晶粒、杂质、第二相和缺陷的变形机制。这需要综合运用材料科学的知识，进行推理分析和机理解释，思维过程的深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解冷加工对材料微观结构的影响，还需要综合运用多方面的知识（包括晶粒取向、杂质、第二相和缺陷的变形机制）来解释纤维状结构的形成机理。这种复杂现象的分析和机理解释在选择题中属于最高认知层次的要求，需要考生具备深入的材料科学知识和综合推理能力。" + }, + { + "idx": 2181, + "question": "What is the difference between fibrous structure and texture?", + "answer": "Fibrous structure is formed by grains, impurities, second phases, defects, etc., being elongated into fibrous shapes along the main deformation direction of the metal; whereas texture refers to the certain orientation relationship among grains after cold working, where certain crystal planes or directions are parallel to each other and all parallel to an external reference direction of the component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两个概念之间的区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对纤维结构和织构这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题中属于较高难度，题目要求考生不仅要理解\"纤维结构\"和\"织构\"这两个专业术语的定义，还需要能够区分和比较这两个概念的具体特征和形成机制。正确选项包含了多个专业知识点（如晶粒变形、杂质分布、晶体取向关系等），需要考生对这些概念有较深入的理解才能准确作答。此外，题目涉及金属材料科学中较为复杂的微观结构概念体系，在选择题型内属于需要综合分析能力的高难度题目。" + }, + { + "idx": 2182, + "question": "Explain why crystal slip usually occurs on the most closely packed atomic planes and directions.", + "answer": "As can be seen from the relation, the larger the value of a, the smaller the τ_p, so the slip plane should be the one with the largest interplanar spacing, i.e., the most closely packed atomic plane; the smaller the value of b, the smaller the τ_p, so the slip direction should be the most closely packed atomic direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体滑移通常发生在最密排原子面和方向的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶体滑移通常发生在最密排原子面和方向的原因，涉及对晶体结构、滑移机制和临界分切应力等概念的深入理解和综合分析。需要运用相关理论进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解晶体滑移的基本概念，还需要综合运用材料科学中的多个原理（如晶面间距与临界分切应力的关系、原子密排方向与滑移难易度的关系）进行深度推理分析。正确选项涉及对复杂材料现象的全面解释，需要考生具备将理论公式（τ_p与a、b的关系）与晶体结构实际特征（密排面/方向）联系起来的能力，这远超选择题常见的简单记忆或基础应用层次。" + }, + { + "idx": 2183, + "question": "Use dislocation theory to explain the yield phenomenon of low-carbon steel.", + "answer": "The yield phenomenon of low-carbon steel can be explained by dislocation theory. Since low-carbon steel is an alloy based on ferrite, carbon (nitrogen) atoms in ferrite interact with dislocations and tend to aggregate in the tensile stress regions of dislocation lines to reduce the distortion energy of the system, forming Cottrell atmospheres that 'pin' the dislocations, thereby increasing σs. Once dislocations break free from the pinning of these atmospheres, they can continue to move under lower stress, leading to the appearance of the lower yield point on the stress-strain curve. For a specimen that has already yielded, if it is unloaded and immediately reloaded in tension, the yield point does not reappear because the dislocations have already escaped the pinning of the atmospheres. However, if the unloaded specimen is left for a long time or slightly heated before retesting, the solute atoms will diffuse back and re-aggregate around the dislocation lines to form atmospheres, causing the yield phenomenon to reappear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释低碳钢的屈服现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢的屈服现象，涉及位错与溶质原子的相互作用、柯氏气团的形成及其对位错的钉扎作用、应力-应变曲线的特征以及卸载和重新加载对屈服现象的影响。这需要深入理解位错理论，综合分析多个概念和机制，并进行推理分析，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅掌握位错理论的基本概念，还需要深入理解低碳钢屈服现象的微观机理，包括柯氏气团的形成、位错钉扎效应、应力-应变曲线特征以及时效现象等复杂内容。正确选项涉及多个知识点的综合运用和机理深度解释，需要考生具备将理论知识与实际材料行为联系起来的能力。这种题目在选择题型中属于需要复杂现象全面分析的类型，对考生的理解深度和综合分析能力要求极高。" + }, + { + "idx": 2184, + "question": "What effect does fibrous structure have on the properties of metals?", + "answer": "Generally speaking, fibrous structure makes the longitudinal (fiber direction) strength of metals higher than the transverse strength. This is because on the cross-section, the cross-sectional area of brittle, low-strength 'components' such as impurities, second phases, and defects is small, while on the longitudinal section, the cross-sectional area is large. When parts bear large loads or are subjected to impact and alternating loads, this anisotropy may pose significant risks.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维结构对金属性能的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要理解纤维结构的基本概念，还需要分析其对金属性能的影响机制，涉及多相材料、缺陷和载荷方向的综合分析，属于较深层次的机理解释和推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2185, + "question": "Briefly analyze the essential similarities and differences in work hardening", + "answer": "Work hardening is caused by dislocation pile-up, entanglement, and their interactions, which hinder further dislocation movement, with the flow stress σd=αGb√ρ", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析加工硬化的本质相似性和差异，需要文字解释和论述，而不是选择、判断或计算。答案也提供了文字解释和公式说明，符合简答题的特征。 | 知识层次: 题目要求分析加工硬化的本质相似性和差异性，涉及位错堆积、缠结及其相互作用的机理解释，需要综合运用材料科学中的位错理论和塑性变形知识，进行推理分析和机理解释。这超出了简单记忆或基本应用，属于对复杂现象的深入理解和分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求分析加工硬化的本质相似性和差异性，涉及位错堆积、纠缠及其相互作用等复杂机理，并需要理解流动应力公式σd=αGb√ρ的物理意义。这要求考生具备深入的材料科学知识，能够综合运用多个概念进行推理分析，并解释复杂现象。在选择题型中，此类题目对知识掌握深度和解题能力的要求极高，属于复杂现象全面分析的范畴。" + }, + { + "idx": 2186, + "question": "Briefly analyze the essential similarities and differences of solid solution strengthening", + "answer": "Solid solution strengthening results from the interaction between dislocations and solute atoms, namely the Cottrell atmosphere hindering dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析固溶强化的本质异同点，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析固溶强化的本质相似性和差异性，涉及位错与溶质原子的相互作用机制（Cottrell气团阻碍位错运动），需要综合运用材料科学中的位错理论和强化机制知识进行机理层面的解释和分析。这超出了简单记忆或基础应用的范畴，属于需要深入理解和推理分析的复杂问题。 | 难度: 在选择题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要掌握位错与溶质原子相互作用的机理（如Cottrell气团对位错运动的阻碍作用）。这属于对材料强化机理的深度解释，需要考生具备将微观机制与宏观性能联系起来的分析能力，符合等级4\"机理深度解释\"的标准。选择题型中仅提供正确选项时，判断该选项的准确性需要较高的专业知识储备。" + }, + { + "idx": 2187, + "question": "What effect does texture have on the properties of metals?", + "answer": "Due to texture-induced anisotropy in metals, it often causes inconvenience in metal processing. For example, cold-rolled magnesium sheets develop a (0001)<11\\overline{2}0> texture, making them prone to cracking during further processing; earing in deep-drawn metal cups; thermal cycling growth of metals, etc. However, in some cases, it also has beneficial aspects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纹理对金属性能的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释织构对金属性能的影响，并举例说明其不利和有利方面。这需要综合运用材料科学中的织构概念、金属加工行为以及性能变化的机理分析，涉及多个知识点的关联和深入理解，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解金属织构的基本概念，还需要掌握织构诱导各向异性对金属加工性能的具体影响机制（如冷轧镁板的开裂倾向、深冲杯的制耳现象等）。正确选项涉及多个复杂现象的全面分析，需要考生具备将理论知识综合运用于实际工程问题的能力，并能辩证分析织构的利弊影响。这种深度机理解释和复杂现象分析的结合，在选择题型中属于最高认知层次的要求。" + }, + { + "idx": 2188, + "question": "Briefly analyze the essential similarities and differences of grain refinement strengthening", + "answer": "Grain refinement strengthening occurs because the atoms at grain boundaries are irregularly arranged, with many impurities and defects, resulting in higher energy that hinders dislocation movement, σs=σ0+Kd−1/2; moreover, when grains are fine, deformation is uniform, stress concentration is low, and cracks are less likely to initiate and propagate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析晶粒细化强化的本质相似性和差异，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析晶粒细化强化的本质相似性和差异，涉及对晶界原子排列、位错运动阻碍机制以及变形均匀性等概念的综合理解和应用。虽然题目没有涉及复杂的计算，但需要对多个材料科学原理进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解晶粒细化强化的基本原理（如晶界原子排列不规则、杂质和缺陷导致能量升高阻碍位错运动），还需要掌握霍尔-佩奇关系（σs=σ0+Kd−1/2）以及晶粒尺寸对变形均匀性、应力集中和裂纹扩展的影响。这需要考生能够综合多个概念并进行多角度分析，属于中等应用层次中的复杂综合分析题。" + }, + { + "idx": 2189, + "question": "Briefly analyze the essential similarities and differences of dispersion strengthening", + "answer": "Dispersion strengthening occurs because dislocations bypass or cut through second-phase particles, requiring additional energy (such as surface energy or misfit energy); meanwhile, the elastic stress field around the particles interacts with dislocations, hindering their movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析分散强化的本质相似性和差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析弥散强化的本质相似性和差异性，涉及位错与第二相颗粒的相互作用机制（如绕过或切割颗粒所需的额外能量、弹性应力场与位错的相互作用等），需要综合运用材料科学中的位错理论和强化机制知识，进行机理层面的解释和推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解分散强化的基本概念，还需要掌握位错与第二相颗粒相互作用的复杂机理（包括位错绕过或切割颗粒的能量要求、表面能和错配能等概念），以及弹性应力场对位错运动的阻碍作用。这需要考生具备将多个高级概念综合运用的能力，并进行机理层面的深度解释。在选择题型中，这种需要同时处理多个复杂概念并理解其相互作用的题目是最具挑战性的。" + }, + { + "idx": 2190, + "question": "When the bubble density in tungsten wire increases from 100/cm² to 400/cm², the tensile strength can approximately double, because bubbles can hinder dislocation motion. Analyze the mechanism by which bubbles impede dislocation motion.", + "answer": "The mechanism by which bubbles hinder dislocation motion is that when dislocations pass through bubbles, they cut the bubbles, increasing the area of the bubble-metal interface. This requires additional external shear stress to perform work, thereby enhancing the strength of tungsten metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析气泡阻碍位错运动的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析气泡阻碍位错运动的机制，涉及位错与气泡相互作用的微观过程，需要综合运用材料科学中的位错理论和强化机制知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解气泡密度增加对钨丝抗拉强度的影响，还需要深入分析气泡阻碍位错运动的机理。正确选项涉及位错切割气泡、增加界面面积以及需要额外剪切应力等复杂概念的综合运用和推理分析。这要求考生具备扎实的材料科学基础，能够将多个知识点联系起来进行机理解释，属于复杂现象全面分析的层次。" + }, + { + "idx": 2191, + "question": "Given the Burgers vector of a dislocation as b, the bubble radius as r, and the specific interfacial energy between the bubble and metal as σ, determine the increment of shear stress Δτ.", + "answer": "The increased interfacial area between the bubble and metal after the dislocation cuts the bubble is A=2rb. The increment of interfacial energy is 2rbσ. If the increment of shear stress for a dislocation cutting one bubble is Δτ', then the work done by the stress is Δτ'b. Therefore, 2rbσ=Δτ'b, Δτ'=2rσ. When the bubble density is n, the total increment of shear stress Δτ=nΔτ'=2nrσ. It can be seen that the increment of shear stress is proportional to the bubble density.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（Burgers vector、bubble radius、specific interfacial energy）进行计算，并得出增量剪切应力的数值结果。解答过程涉及公式应用和数值推导，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括理解位错切割气泡导致的界面能增加、应力增量与气泡密度的关系等综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（Burgers向量、位错切割气泡的界面能增量、剪切应力增量等）并进行多步计算和综合分析。题目涉及中等应用层次的知识点，要求考生能够将不同概念关联起来，并通过逻辑推导得出最终结论。虽然题目提供了正确选项的详细推导过程，但在选择题型内仍需要考生具备较强的概念理解和计算能力才能正确解答。" + }, + { + "idx": 2192, + "question": "Why is the actual tensile strength of ceramics lower than the theoretical yield strength?", + "answer": "This is due to the unavoidable microscopic voids present during the sintering of ceramic powders. During cooling or thermal cycling, thermal stresses generate microcracks, and surface cracks caused by corrosion result in ceramics, unlike metals, having inherent microcracks. At the crack tip, severe stress concentration occurs. According to elastic mechanics estimates, the maximum stress at the crack tip has already reached the theoretical fracture strength or theoretical yield strength (because ceramic crystals have very few mobile dislocations, and dislocation motion is extremely difficult, so once the yield strength is reached, fracture occurs). Conversely, one can calculate the nominal stress at which the crystal fractures when the maximum stress at the crack tip equals the theoretical yield strength, and this value is extremely close to the actual measured tensile strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的实际拉伸强度低于理论屈服强度，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要综合运用弹性力学、陶瓷材料微观结构和断裂机理等多方面知识进行深入分析和解释，涉及复杂的应力集中和理论强度与实际强度差异的机理探讨。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解陶瓷材料的基本性能，还需要深入掌握微观结构缺陷（如微孔、微裂纹）对材料强度的影响机制。正确选项涉及复杂的应力集中分析、理论强度与实际强度的差异解释，以及陶瓷晶体中位错运动的特殊性。此外，解题过程需要综合运用弹性力学和材料科学知识进行推理分析，属于复杂现象的全面分析层次，远超一般选择题的概念记忆或简单应用要求。" + }, + { + "idx": 2193, + "question": "This shows, what effect does recovery have on recrystallization?", + "answer": "After polygonization, the dislocation energy decreases, reducing the stored energy and thereby diminishing the driving force for subsequent recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释恢复对再结晶的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及恢复过程对再结晶的影响机制，需要理解位错能量变化、储存能量减少以及再结晶驱动力减小的因果关系。这需要对材料科学中的位错理论、恢复和再结晶过程有深入的理解，并进行推理分析，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解回复（recovery）和再结晶（recrystallization）的基本概念，还需要深入掌握位错多边形化（polygonization）过程中位错能降低的机理，以及这对后续再结晶驱动力（driving force）的影响。这涉及到多个材料科学核心概念的串联和机理层面的解释，需要考生具备复杂现象全面分析的能力。在选择题型中，这种需要综合运用多个高阶概念并进行机理推理的题目属于最难的一类。" + }, + { + "idx": 2194, + "question": "Given that the elastic modulus of sintered alumina is $370\\\\mathrm{GPa}$ when its porosity is $5\\\\%$, if the elastic modulus of another sintered alumina is $270~\\\\mathrm{GPa}$, calculate its porosity.", + "answer": "The relationship between the elastic modulus $E$ of ceramic materials and their pore volume fraction $\\\\varphi$ can be expressed as $$ E=E_{\\\\circ}(1-1.9\\\\varphi+0.9\\\\varphi^{2}) $$ where $E_{0}$ is the elastic modulus of the material without pores. Given that when $\\\\varphi=0.05$, $E=370~\\\\mathrm{GPa}$, thus $$ E_{\\\\circ}={\\\\frac{E}{1-1.9{\\\\varphi}+0.9{\\\\varphi}^{2}}}={\\\\frac{370}{1-1.9\\\\times0.05+0.9\\\\times(0.05)^{2}}}=407.8{\\\\mathrm{~GPa}} $$ When $E=270$ GPa, $$ 270=407.8(1-1.9\\\\varphi+0.9\\\\varphi^{2}) $$ which simplifies to $$ 0.9\\\\varphi^{2}-1.9\\\\varphi+0.338=0 $$ Therefore, $$ \\\\varphi=0.196=19.6\\\\% $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数值计算另一个烧结氧化铝的孔隙率，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要进行多步计算，包括公式的推导和数值求解，涉及弹性模量与孔隙率之间的非线性关系，需要一定的综合分析能力。虽然不涉及复杂的机理分析或创新设计，但超出了简单直接套用公式的范围。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性模量与孔隙率的关系公式，并进行多步计算。首先需要根据已知条件求解无孔隙时的弹性模量E0，然后代入新的弹性模量值建立方程，最后解二次方程得到孔隙率。整个过程涉及公式推导、数值计算和方程求解，但题目提供了完整的解题思路，降低了部分难度。" + }, + { + "idx": 2195, + "question": "Why is the compressive strength of ceramics always higher than the tensile strength?", + "answer": "The compressive strength of ceramics is generally about 15 times the tensile strength. This is because under tension, when a crack reaches the critical size, it becomes unstable and propagates rapidly, leading to fracture; whereas under compression, cracks either close or propagate steadily and slowly, turning parallel to the compression axis. In other words, under tension, the tensile strength of ceramics is determined by the maximum crack size in the crystal, while the compressive strength is determined by the average size of the cracks.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的抗压强度总是高于抗拉强度，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释陶瓷压缩强度高于拉伸强度的机理，涉及裂纹在不同应力状态下的行为差异和传播机制的分析，需要综合运用材料科学中的断裂力学知识，进行推理和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解陶瓷材料的基本力学性能差异，还需要深入掌握裂纹扩展的微观机理及其在不同应力状态下的行为差异。正确选项涉及复杂的材料断裂力学原理，包括临界裂纹尺寸、裂纹不稳定传播条件以及压缩与拉伸状态下裂纹行为的对比分析。这需要考生具备综合运用材料科学和力学知识的能力，能够进行高阶推理和机理解释，远超选择题型中常见的简单概念识别或记忆性内容。" + }, + { + "idx": 2196, + "question": "A subgrain boundary is composed of several edge dislocations with a misorientation of 0.057 degrees. Assuming there is no interaction between the dislocations before polygonization, by what factor does the distortion energy change after the formation of the subgrain?", + "answer": "The energy per unit length of a dislocation line is W_I = (G b^2) / (4π(1-ν)) * ln(R/r_0), where r_0 is the radius of the dislocation core region and R is the radius of the maximum range of the dislocation stress field. If we take r_0 ≈ b = 10^-8 cm and R ≈ 10^-4 cm, then before polygonization, W_D = (G b^2) / (4π(1-ν)) * ln(10^4). After polygonization, R = D = b / θ = 10^-8 / 10^-3 = 10^-5 cm, and W_31* = (G b^2) / (4π(1-ν)) * ln(10^3). Thus, W_I* / W_I1 = ln(10^3) / ln(10^4) = 0.75.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解亚晶界形成后畸变能的变化因子，答案中包含了具体的公式推导和数值计算过程。 | 知识层次: 题目需要进行多步计算，涉及位错能量公式的应用和变形前后的能量比较，需要理解位错的基本概念和能量计算原理，并进行综合分析。虽然不涉及复杂的机理分析或创新应用，但计算过程需要一定的思维深度和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解位错能量公式、多边形化过程以及角度与距离的转换关系。题目涉及多步骤计算（如计算前后能量比）和概念关联（如位错核心半径与应力场范围的关系），但未达到复杂多变量计算的程度。" + }, + { + "idx": 2197, + "question": "Given that the recovery activation energy of a zinc single crystal is $20000\\\\mathrm{J/mol}$, removing $2\\\\%$ of the work hardening at $50^{\\\\circ}\\\\mathrm{C}$ requires $13\\\\textup{d}$; how much should the temperature be increased to remove the same amount of work hardening in $5\\\\textrm{min}$?", + "answer": "When cold-plastically deformed metal undergoes recovery, if the recovery amount $R$ (in this case, the removed portion of work hardening) is constant, the relationship between the required recovery time $t$ and the recovery temperature $T$ can be expressed as $$ \\\\ln t=a+{\\\\frac{Q}{R}}{\\\\frac{1}{T}}$$ where $a$ is a constant; $\\\\boldsymbol{Q}$ is the recovery activation energy. Accordingly, we have $$ \\\\frac{t_{1}}{t_{2}}=\\\\exp\\\\biggl[-\\\\frac{Q}{R}\\\\Bigl(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\Bigr)\\\\biggr]$$ From the problem statement, $$ T_{2}=-50^{\\\\circ}C=223\\\\mathrm{~K~}$$ $$ t_{2}=13~\\\\mathrm{d}=18~500~\\\\mathrm{min},\\\\quad Q=20~000~\\\\mathrm{J/mol}$$ When $t_{1}=5\\\\mathrm{min}$ is required, then $$ {\\\\frac{5}{18500}}{=}\\\\exp\\\\Bigl[-{\\\\frac{20000}{2}}\\\\Bigl({\\\\frac{1}{223}}-{\\\\frac{1}{T_{1}}}\\\\Bigr)\\\\Bigr]$$ $$ {\\\\frac{1}{T_{1}}}={\\\\frac{1}{223}}-{\\\\frac{\\\\ln3700}{10000}}$$ Therefore, the recovery temperature $$ T_{1}=273\\\\mathrm{~K~}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及激活能、温度和时间的关系，最终要求计算出一个具体的温度值。解答过程中使用了数学公式和代数运算，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解恢复激活能的概念，并能够将时间、温度与激活能之间的关系进行综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的计算能力和概念关联能力。 | 难度: 在选择题型中，这道题目属于高难度等级。题目涉及多个复杂步骤和概念的综合运用，包括：" + }, + { + "idx": 2198, + "question": "The strength of OFHC copper (oxygen-free high-conductivity copper) can be increased by more than 2 times after cold drawing deformation. If the safety factor for allowable stress is taken as 2, calculate the service life of an OFHC copper component working at $130^{\\\\circ}\\\\mathrm{C}$. (Given: $A=10^{12}1/\\\\operatorname*{min}, \\\\frac{Q}{R}=$ $1.5\\\\times10^{4}~\\\\mathrm{K}, t_{0.5}$ is the time required for 50% recrystallization)", + "answer": "Since OFHC copper operates at $130^{\\\\circ}C$, with a strength design safety factor of 2, for cold-worked and strengthened materials, only 50% recrystallization is allowed, i.e., $$ \\\\begin{array}{r}{\\\\frac{1}{t_{0.5}}=A\\\\mathrm{exp}\\\\left(-\\\\frac{Q}{R T}\\\\right)} \\\\ {\\\\mathrm{lg}(A t_{0.5})=\\\\frac{Q}{R T}\\\\mathrm{lg}\\\\mathrm{~e~}}\\\\end{array}$$ $A=10^{12}~1/\\\\operatorname*{min}{},\\\\frac{Q}{R}=1.5\\\\times10^{4}~\\\\mathrm{K}{},T=130^{\\\\circ}\\\\mathrm{C}=403~\\\\mathrm{K}$. Therefore, $$ t_{0.5}=14497\\\\mathrm{min}=242\\\\mathrm{h}$$ Thus, the service life of OFHC copper under these working conditions is $242\\\\mathrm{~h~}$ \\\\lg(10^{12}t_{0.5})={\\\\frac{1.5\\\\times10^{4}}{403}}\\\\times0.4342$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的数学运算和物理公式的使用，最终得出一个具体的数值结果（242小时）。 | 知识层次: 题目需要进行多步计算，包括温度单位转换、公式应用（Arrhenius方程）、对数运算和单位转换，涉及材料科学中的再结晶动力学概念。虽然计算过程较为直接，但需要理解和应用多个知识点，并进行综合分析以得出最终的服务寿命。 | 难度: 在选择题中属于中等偏上难度，需要理解材料科学中的再结晶动力学概念，掌握Arrhenius方程的应用，并进行多步骤计算。题目涉及温度转换、对数运算和单位换算，综合性强，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 2199, + "question": "What is the difference between crazing and cracking?", + "answer": "Crazing is different from cracking. The two open surfaces of a crack are completely empty, whereas the surfaces of a craze consist of highly oriented fiber bundles and voids, which still retain some strength. The formation of crazes is due to localized yielding and cold drawing of the material under tensile stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对材料科学中基本概念（crazing和cracking）的记忆和理解，主要涉及定义和基本特征的区分，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生理解并区分两个相关概念（crazing和cracking），并能够识别它们的关键差异。虽然涉及多个知识点，但主要考察的是对基础概念的解释和描述，而非复杂的分析或综合应用。因此属于中等难度（等级2）。" + }, + { + "idx": 2200, + "question": "The melting point of iron is known to be 1,538℃, estimate the minimum recrystallization temperature of iron", + "answer": "The minimum recrystallization temperature of iron is T_r=0.4×(1,538+273)=723 K", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计铁的再结晶温度，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需将已知的熔点转换为绝对温度后乘以经验系数0.4即可得到再结晶温度，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（T_r=0.4×(T_m+273)）并进行简单计算，无需额外的概念理解或步骤组合。属于最基础的公式应用和计算难度。" + }, + { + "idx": 2201, + "question": "Based on the minimum recrystallization temperature of iron, 723 K, select the recrystallization annealing temperature for iron", + "answer": "The recrystallization annealing temperature for iron T=823∼923 K", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的最低再结晶温度选择一个合适的再结晶退火温度范围，答案给出了具体的温度范围，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求基于已知的最低再结晶温度（723 K）选择铁的再结晶退火温度，这属于直接应用基本公式或经验规则（通常在最低再结晶温度以上100-200 K）来确定具体参数。虽然需要理解再结晶温度的概念，但主要考察的是简单应用能力，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用已知的最低再结晶温度（723 K）并选择适当的再结晶退火温度范围（823∼923 K）。题目不涉及复杂计算或多步骤推理，仅需基本知识点的记忆和应用，因此难度较低。" + }, + { + "idx": 2202, + "question": "Given that the melting point of copper is 1,083℃, estimate the minimum recrystallization temperature of copper", + "answer": "The minimum recrystallization temperature of copper is T_r=0.4×(1,083+273)=542 K", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用0.4乘以铜的熔点加上273来转换单位并计算最低再结晶温度）来得出具体数值结果，答案是一个计算得出的数值而非文字解释或选择判断。 | 知识层次: 题目涉及基本公式应用（0.4×Tm）和简单计算（温度转换和乘法），不需要多步计算或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需直接套用单一公式（T_r=0.4×(T_m+273)）进行简单计算，无需理解多个概念或进行复杂分析。题目明确给出了铜的熔点数据，解题步骤仅涉及基本代数运算，属于最基础的应用层级。" + }, + { + "idx": 2203, + "question": "Based on the minimum recrystallization temperature of copper being 542 K, determine the recrystallization annealing temperature for copper", + "answer": "The recrystallization annealing temperature for copper T=643∼743 K", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的最低再结晶温度（542 K）来确定铜的再结晶退火温度，并给出了具体的温度范围（643∼743 K）。这需要根据材料科学中的相关公式或经验法则进行计算或推导，属于需要数值计算和公式应用的题型。 | 知识层次: 题目需要应用已知的铜最低再结晶温度（542 K）来计算再结晶退火温度范围（643∼743 K），属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用已知的铜再结晶温度（542 K）来确定再结晶退火温度范围（643~743 K）。题目属于单一公式直接计算类型，无需复杂推导或多步骤分析，符合等级1的难度标准。" + }, + { + "idx": 2204, + "question": "Pure zirconium requires 40 h and 1 h of isothermal annealing at $553^{\\\\circ}\\\\mathrm{C}$ and $627^{\\\\circ}\\\\mathrm{C}$ respectively to complete recrystallization. Calculate the recrystallization activation energy of this material.", + "answer": "From Equation (7-6) in Section 7.3: $$Therefore$$ Q=R\\\\ln\\\\frac{t_{1}}{t_{2}}\\\\bigg/\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}\\\\Big)$$ Substituting the known values, we get $$ Q={\\\\frac{8.31\\\\ln{\\\\frac{40}{1}}}{{\\\\frac{1}{553+273}}-{\\\\frac{1}{627+273}}}}=3.08\\\\times10^{5}~\\\\mathrm{J/mol}$$ \\\\ln{\\\\frac{t_{1}}{t_{2}}}=\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}\\\\Big)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解再结晶活化能，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式的变形和数值代入，同时需要理解再结晶激活能的概念及其与温度和时间的关系。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解再结晶激活能的概念，掌握Arrhenius方程的应用，并进行多步骤的计算。题目涉及温度转换（摄氏到开尔文）、对数运算和单位换算，虽然计算过程明确，但步骤较多且需要准确执行。" + }, + { + "idx": 2205, + "question": "For metals and alloys that do not undergo phase transformations in the solid state, can their grain size be changed without remelting? What methods can be used to alter it?", + "answer": "Yes. It can be achieved through cold deformation followed by recrystallization annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述如何在不重新熔化的条件下改变金属和合金的晶粒尺寸，答案提供了文字解释和具体方法，符合简答题的特征。 | 知识层次: 题目需要理解金属和合金的晶粒尺寸变化机制，并应用冷变形和再结晶退火的概念来解决问题。这涉及多步思考（冷变形和再结晶退火两个步骤）和概念关联（将塑性变形与热处理工艺联系起来），但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解金属和合金的晶粒尺寸变化原理，并关联冷变形和再结晶退火两个工艺步骤的作用。虽然不涉及多步计算，但需要综合分析材料加工工艺对微观结构的影响，属于概念关联和综合分析层次。" + }, + { + "idx": 2206, + "question": "A cold-drawn steel wire rope was used to hoist a large workpiece into a furnace and was heated together with the workpiece to $1,000^{\\circ}\\mathrm{C}$. Upon completion of heating, when the workpiece was lifted out, the steel wire rope broke. Analyze the reason for this.", + "answer": "The processing of the cold-drawn steel wire rope is a cold-working process. Due to work hardening, the strength and hardness of the steel wire increase, thereby enhancing its load-bearing capacity. When heated, if the temperature exceeds its recrystallization temperature, the steel wire rope undergoes recrystallization, leading to a reduction in strength and hardness. Once the external load exceeds its load-bearing capacity, it will break.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢丝绳断裂的原因，答案提供了详细的文字解释和论述，涉及冷加工、加工硬化、再结晶等材料科学概念，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析冷拔钢丝绳在高温下断裂的原因，涉及冷加工、加工硬化、再结晶温度等多个概念的综合运用和机理解释。需要理解材料在不同温度下的行为变化，并分析其与断裂现象的因果关系，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2207, + "question": "There are three types of ingots: pure Ti, Al, and Pb. It is known that the melting point of Ti is 1672°C, with a hexagonal close-packed structure below 883°C and a face-centered cubic structure above 883°C; the melting point of Al is 660°C, with a face-centered cubic structure; the melting point of Pb is 328°C, with a face-centered cubic structure. Determine the order of their rolling difficulty at room temperature (20°C).", + "answer": "At room temperature, Pb is the easiest to roll, followed by Al, and Ti is the most difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据材料的结构和性质进行解释和论述，最终得出一个排序结论，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要综合运用金属的晶体结构、相变温度和室温下的力学性能等知识，通过分析不同金属在室温下的晶体结构（如Ti的HCP结构在室温下更难变形，而Al和Pb的FCC结构相对容易变形）来推断其轧制难度。这涉及多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握不同金属的晶体结构、熔点以及这些性质对室温下轧制难度的影响。解题步骤包括识别各金属的晶体结构、分析其室温下的塑性变形能力，并进行综合比较。虽然不涉及复杂计算，但需要将多个材料科学概念关联起来，属于中等应用层次的知识要求。" + }, + { + "idx": 2208, + "question": "What measures should be taken for A1 and Ti to enable them to be rolled into thin sheets?", + "answer": "For A1 and Ti, intermediate annealing (i.e., recrystallization annealing) should be employed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取的措施，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求对A1和Ti的轧制工艺进行具体措施的选择，需要理解材料加工过程中的再结晶退火原理及其应用，属于多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解金属材料的加工工艺（如轧制）和热处理（如再结晶退火）之间的关系，并能将特定材料（A1和Ti）的特性与加工要求进行关联分析。虽然不涉及多步计算，但需要对材料科学中的多个概念进行综合应用。" + }, + { + "idx": 2209, + "question": "Given that brass containing ${w_{\\\\mathrm{Zn}}}=0.30$ requires $^{1\\\\textrm{h}}$ to complete recrystallization at a constant temperature of $400^{\\\\circ}\\\\mathrm{C}$, and $2\\\\textrm{h}$ at $390^{\\\\circ}\\\\mathrm{C}$, calculate the time required to complete recrystallization at a constant temperature of $420^{\\\\circ}\\\\mathrm{C}$.", + "answer": "The rate of recrystallization is given by $Q$ is the activation energy for recrystallization) Let $t$ be the time required to complete recrystallization, then$$ $$ \\\\begin{array}{r}{\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}=\\\\ln\\\\frac{t_{2}}{t_{1}}}\\\\\\\\ {\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{3}}=\\\\ln\\\\frac{t_{3}}{t_{1}}}\\\\end{array}$$ Substituting $T_{1}=673~\\\\mathrm{K},t_{1}=1~\\\\mathrm{h};T_{2}=663~\\\\mathrm{K},t_{2}=2~\\\\mathrm{h};T_{3}=693~\\\\mathrm{K}$ into the above equations, we obtain$$ t_{3}\\\\approx0.26~\\\\mathrm{h}$$ That is, completing recrystallization at a constant temperature of $420^{\\\\circ}\\\\mathrm{C}$ requires approximately $0,26\\\\mathrm{~h~}$ \\\\begin{array}{c}{{V_{\\\\parallel\\\\parallel}t=1}}\\\\\\\\ {{A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{1}}}t_{1}=A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{2}}}t_{2}=A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{3}}}t_{3}}}\\\\\\\\ {{-\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}\\\\Big)=\\\\ln\\\\frac{t_{2}}{t_{1}}}}\\\\\\\\ {{-\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{3}}\\\\Big)=\\\\ln\\\\frac{t_{3}}{t_{1}}}}\\\\end{array}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在特定温度下完成再结晶所需的时间，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用阿伦尼乌斯方程进行温度和时间关系的推导，并进行对数运算和数值计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解再结晶动力学的基本概念（如阿伦尼乌斯方程的应用），并进行多步温度和时间转换的计算。题目涉及温度单位转换（摄氏到开尔文）、对数运算和方程联立求解，虽然计算过程明确但步骤较多，对学生的综合计算能力和概念理解有一定要求。在选择题型中属于需要综合分析能力的题目，但尚未达到最复杂的多变量计算水平。" + }, + { + "idx": 2210, + "question": "Design an experimental method to determine the variation of recrystallization nucleation rate $\\dot{N}$ with time at a certain temperature (T).", + "answer": "The recrystallization nucleation rate $\\dot{N}$ can be determined using the metallographic method. Specific steps: Heat a batch of specimens deformed with a large strain to a certain temperature (T) and hold, then quench one specimen at regular time intervals t. Observe the prepared metallographic samples under a microscope and count the number of recrystallization nuclei N. After obtaining a set of data (several points), plot an N-t graph. The slope at each point on the N-t curve represents the recrystallization nucleation rate $\\dot{N}$ of the material at temperature T for different holding times.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计实验方法并详细描述步骤，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求设计一个实验方法来测定再结晶形核速率随时间的变化，这需要综合运用材料科学中的再结晶理论、实验设计和数据分析等多方面知识。实验步骤涉及热处理、金相观察、数据收集和曲线绘制等多个环节，需要深入理解再结晶过程的机理，并能将理论知识转化为具体的实验方案。此外，还需要对实验结果进行分析和解释，以确定形核速率的变化规律。整个过程体现了创新应用、深度理解和设计优化的能力。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2211, + "question": "Design an experimental method to determine the variation of growth linear velocity G with time at a certain temperature (T).", + "answer": "The growth linear velocity G can be determined using the metallographic method. Specific steps: Perform metallographic observation on a set of quenched samples from the nucleation rate experiment, measure the linear dimension D of the largest nucleus in each sample (representing different holding times), plot a D-t graph, and the slope at each point on the D-t curve represents the growth linear velocity G at temperature T for different holding times.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计一个实验方法，并详细描述实验步骤和数据处理过程，这需要文字解释和论述，属于简答题类型。 | 知识层次: 题目要求设计实验方法来确定生长线性速度G随时间的变化，这需要综合运用材料科学知识、实验设计和数据分析能力。涉及多步骤的实验操作、数据收集和解释，以及对生长动力学的深入理解。这属于高级综合层次，需要创新应用和设计优化。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握材料科学中的基本概念（如生长线性速度、金相观察方法），还需要具备创新应用能力来设计实验步骤（如淬火样品处理、最大晶核尺寸测量、D-t曲线绘制与斜率分析）。解题过程涉及多步骤综合操作和深度理解温度T对生长速度G的动态影响机制，远超常规选择题对知识点简单识记或单一概念应用的要求。" + }, + { + "idx": 2212, + "question": "When cold-drawn copper wires are used as overhead conductors (requiring certain strength), what final heat treatment process should be adopted?", + "answer": "Stress relief annealing (low-temperature annealing) should be adopted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取何种最终热处理工艺，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求根据具体应用场景（冷拉铜线作为架空导线）选择适当的热处理工艺，需要理解材料性能与工艺之间的关系，并进行综合分析。虽然答案较为直接，但需要将材料科学原理与实际应用相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铜线作为架空导体的应用场景及其强度要求，并关联到适当的热处理工艺。虽然题目涉及多步概念关联和综合分析，但在选择题型中，通过排除法可以缩小选项范围，降低解题难度。" + }, + { + "idx": 2213, + "question": "Can metal castings refine grain size through recrystallization annealing?", + "answer": "Recrystallization annealing must be applied to materials that have undergone cold plastic deformation processing, with the purpose of improving the microstructure and properties of the material after cold deformation. The temperature of recrystallization annealing is relatively low, generally below the critical point. If recrystallization annealing is applied to castings, their microstructure will not undergo phase transformation, nor will there be a driving force for the formation of new nuclei (such as stored energy from cold deformation, etc.), so new grains will not form, and grain refinement cannot be achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对金属铸件是否可以通过再结晶退火细化晶粒进行解释和论述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及对金属铸造和再结晶退火过程的深入理解，需要分析冷塑性变形与再结晶退火之间的关系，以及解释为什么铸造组织无法通过再结晶退火细化晶粒。这需要综合运用材料科学中的相变、形变储存能、再结晶驱动力等概念，并进行推理分析。 | 难度: 在选择题型中属于最高难度等级，因为题目要求考生不仅掌握再结晶退火的基本概念，还需要深入理解其适用条件（冷塑性变形材料）和微观机理（储存能驱动形核）。正确选项涉及多个专业概念的串联分析：1) 必须区分铸造与冷变形材料的微观结构差异 2) 需要理解再结晶热力学驱动力来源 3) 要综合判断相变临界温度与退火温度的关联。这种需要同时运用材料热力学、加工工艺学和显微组织演变原理进行机理推演的题目，在选择题型中属于最复杂的分析层次。" + }, + { + "idx": 2215, + "question": "Point out the unreasonable aspects of the above process and formulate a reasonable grain refinement process", + "answer": "Under the condition of 80% deformation, annealing at 150°C for 1h can refine its grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出不合理之处并提出合理的晶粒细化工艺，需要文字解释和论述，答案也给出了具体的工艺条件说明，符合简答题的特征。 | 知识层次: 题目要求指出不合理之处并设计合理的晶粒细化工艺，需要综合运用材料科学知识进行深度分析和优化设计，涉及对工艺参数的理解、材料行为的预测以及创新性的工艺方案制定。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握材料科学中关于晶粒细化的基本原理，还需要具备创新应用和设计优化的能力。正确选项涉及具体的工艺参数（80%变形量、150°C退火1小时），这需要考生对材料加工工艺有深入理解，并能将这些知识应用于实际问题的解决。此外，题目要求指出不合理之处并制定合理的晶粒细化工艺，这需要综合运用多个知识点并进行创造性思考，远超一般选择题的认知要求。" + }, + { + "idx": 2216, + "question": "To refine the grain of a pure aluminum part, it was cold deformed by 5% and then annealed at 650°C for 1 hour, but the structure coarsened instead. Analyze the reason for this.", + "answer": "Since the deformation of the aluminum part was under the critical deformation degree, only a few recrystallization nuclei could form during annealing, resulting in extremely coarse grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析原因并进行文字解释和论述，答案也是以文字形式给出解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析纯铝零件在冷变形和退火后晶粒粗化的原因，涉及临界变形度、再结晶成核和晶粒长大等复杂机理的综合推理和解释。需要深入理解材料加工过程中的微观结构演变，并能够将多个概念关联起来进行综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2217, + "question": "Explain the meanings of N0, G0, Qg, Qn and their influencing factors.", + "answer": "N0 and G0 are constants in the Arrhenius equation; Qn is the activation energy for recrystallization nucleation; Qg is the activation energy for recrystallized grain growth. Qn and Qg are mainly influenced by deformation amount, metal composition, metal purity, and original grain size. When the deformation amount exceeds 5%, Qn and Qg are approximately equal. For high-purity metals, the value of Qg is roughly equivalent to the activation energy for grain boundary self-diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个术语的含义及其影响因素，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释多个专业术语的含义及其影响因素，涉及对Arrhenius方程中常数的理解、再结晶成核和晶粒生长的活化能概念，以及这些参数如何受变形量、金属成分、纯度和原始晶粒尺寸的影响。这需要将多个概念关联起来进行综合分析，而不仅仅是简单的记忆或理解。 | 难度: 在选择题中属于较高难度，题目要求理解多个专业术语（N0, G0, Qg, Qn）及其相互关系，并分析它们的影响因素。需要综合运用材料科学知识，包括Arrhenius方程、再结晶成核和晶粒生长的激活能等概念。此外，还需考虑变形量、金属成分、纯度和原始晶粒尺寸等多个影响因素，并进行比较分析。这种多角度分析和概念关联的要求使得题目在选择题型中难度较高。" + }, + { + "idx": 2218, + "question": "When cold-drawn copper wire is used as lamp filament wire (requiring good toughness), what final heat treatment process should be adopted?", + "answer": "Recrystallization annealing (high-temperature annealing) should be adopted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取何种热处理工艺，并给出具体答案，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据具体应用场景（冷拉铜丝作为灯丝材料）选择合适的最终热处理工艺，需要理解冷加工对材料性能的影响以及不同热处理工艺的作用。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解冷拉铜丝作为灯丝材料的特性要求（良好的韧性），并关联热处理工艺（再结晶退火）对材料性能的影响。题目涉及材料加工工艺与性能关系的综合分析，但选项明确指向正确工艺，降低了纯粹记忆的难度。" + }, + { + "idx": 2219, + "question": "To refine the grain size of a pure aluminum part, the cold deformation was increased to 80%, followed by annealing at 650°C for 1 hour, but coarse grains were still obtained. Analyze the reason.", + "answer": "The reason is the inappropriate selection of recrystallization annealing temperature (the temperature was too high). According to the estimation of T_rec ≈ 0.4T_melt, where T_melt = 100°C, the recrystallization temperature should not exceed 200°C. Since annealing was performed at 650°C for 1 hour, the grains remained coarse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析原因并进行文字解释和论述，答案提供了详细的解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的再结晶理论、温度计算和晶粒生长机制，进行推理分析。涉及多步思维过程，包括理解冷变形对晶粒尺寸的影响、计算再结晶温度、分析高温退火对晶粒生长的作用机制等。 | 难度: 在选择题型中属于高难度，题目要求综合运用材料科学知识（如再结晶温度计算、晶粒细化机理）并进行复杂推理分析。需要理解并应用T_rec ≈ 0.4T_melt公式，正确判断温度选择不当的影响，同时解释高温退火导致晶粒粗化的深层机理。这种需要多步骤计算和机理解释的题目在选择题中属于最高难度层级。" + }, + { + "idx": 2220, + "question": "Compare the differences in dislocation motion between stress relief annealing and dynamic recovery processes.", + "answer": "In the stress relief annealing process, dislocations rearrange through climb and glide, transitioning from a high-energy state to a low-energy state; in the dynamic recovery process, it is through cross-slip of screw dislocations and climb of edge dislocations that opposite-sign dislocations cancel each other out, maintaining a dynamic balance between dislocation multiplication rate and dislocation annihilation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较两种不同过程中位错运动的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较两种不同热处理过程中位错运动的差异，涉及位错攀移、滑移、交叉滑移等复杂机制的解释，需要综合运用材料科学中的位错理论和热处理知识，进行机理层面的分析和对比。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2221, + "question": "A low-carbon steel part has developed banded structure, how to eliminate or improve the banded structure through heat treatment methods?", + "answer": "For materials that have developed banded structure, heating in the single-phase region and normalizing treatment can eliminate or improve it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过热处理方法消除或改善带状组织，答案提供了具体的处理方法和解释，符合简答题的特征。 | 知识层次: 题目要求对带状组织的消除或改善提出热处理方案，需要理解带状组织的形成原因以及不同热处理工艺（如单相区加热和正火处理）对其影响。这涉及多个概念的关联和综合分析，但不需要复杂的机理解释或创新设计。 | 难度: 在选择题中属于中等难度，需要理解低碳钢带状组织的形成机制以及热处理工艺（如单相区加热和正火处理）对其影响。题目要求考生将材料科学基础知识和热处理工艺相结合，进行综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2222, + "question": "How to distinguish dynamic and static recovery, and dynamic and static recrystallization from the microstructure", + "answer": "During static recovery, clear subgrain boundaries can be observed, while static recrystallization forms equiaxed grains. In contrast, dynamic recovery forms cellular substructures, and dynamic recrystallization produces dislocation-tangled cells within equiaxed grains, which are finer than those formed by static recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来区分动态和静态恢复以及动态和静态再结晶的微观结构特征，答案提供了详细的描述和对比，符合简答题的特点。 | 知识层次: 题目要求区分动态和静态回复以及动态和静态再结晶的微观结构特征，这需要对不同过程形成的微观结构有深入的理解和分析能力。不仅需要记忆各种结构的特征，还需要综合比较和解释不同过程之间的差异，涉及多个概念的关联和综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解动态和静态恢复、动态和静态再结晶的基本概念，还需要能够从微观结构特征上准确区分这四种现象。正确选项涉及多个复杂微观结构的对比分析（如亚晶界、等轴晶、胞状亚结构、位错缠结等），并需要综合运用材料科学原理进行机理层面的解释。这种题目在选择题中属于对知识深度和综合分析能力要求极高的类型，完全符合\"复杂现象全面分析\"的等级5标准。" + }, + { + "idx": 2223, + "question": "A low-carbon steel part requires isotropy, but a relatively obvious banded structure forms after hot working. How can the formation of banded structure be mitigated or eliminated by controlling the hot working process?", + "answer": "First, avoid deformation in the two-phase region; second, reduce the content of impurity elements; third, use high-temperature diffusion annealing to eliminate element segregation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过控制热加工过程来减轻或消除带状结构的形成，答案提供了具体的步骤和措施，属于简答题类型。 | 知识层次: 题目要求分析带状结构的形成原因，并提出通过控制热加工过程来减轻或消除带状结构的具体方法。这需要综合运用材料科学中的相变、元素偏析、热加工工艺等多方面知识，并进行推理分析。思维过程涉及对热加工工艺参数的选择和优化，以及对材料微观组织演变机理的深入理解。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2224, + "question": "Assuming the recrystallization temperature is defined as the temperature at which 95% recrystallization is completed within 1h, according to the Arrhenius equations Ṅ=N0exp(−Qn/RT) and G=G0exp(−Qg/RT), it can be inferred that the recrystallization temperature will be a function of G and Ṅ. Determine the functional relationship between the recrystallization temperature and G0, N0, Qg, Qn.", + "answer": "According to the J-M equation, if the temperature at which 95% recrystallization is completed within 1h is defined as TF, then 0.95=1−exp(−π/3 ṄG3t0^4). Therefore, t0=(2.86/ṄG3)^1/4. Substituting the Arrhenius equations, we obtain N0G0^3exp(−(Qn+3Qg)/RTF)=k. Rearranging gives TF=(Qn+3Qg)/(R ln(N0G0^3/k))=k′(Qn+3Qg). This equation represents the functional relationship between TF and N0, G0, Qn, Qg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据给定的Arrhenius方程推导出再结晶温度与G0、N0、Qg、Qn之间的函数关系，答案中涉及了公式推导和数学运算，属于需要数值计算和公式应用的题型。 | 知识层次: 题目需要综合运用Arrhenius方程和J-M方程，进行多步推导和公式变换，涉及多个变量的关联分析，思维过程较为复杂，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于高难度综合计算。题目要求综合运用Arrhenius方程和J-M方程，进行多步骤的数学推导和变量替换，最终得出复杂的函数关系。这不仅需要深入理解材料科学中的再结晶机理，还需要较强的数学推导能力和综合运用知识的能力。在选择题型内，这种需要多学科知识综合和复杂推导的题目属于最高难度等级。" + }, + { + "idx": 2225, + "question": "Determine whether the following statement is correct. (1) Appropriate recrystallization annealing can refine the grain size of metal castings.", + "answer": "Incorrect. Only for metals that have undergone cold deformation (with significant deformation) can the grain size be refined through appropriate recrystallization annealing.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案直接给出了对错判断并解释了原因，符合判断题的特征 | 知识层次: 题目不仅需要理解再结晶退火的基本概念，还需要分析其在特定条件下的应用（冷变形金属），涉及概念关联和综合分析。 | 难度: 在选择题中属于较高难度，需要综合分析金属铸造和冷变形两个不同条件下的再结晶退火效果。题目不仅要求判断陈述的正确性，还需要理解再结晶退火对晶粒细化的适用条件（仅适用于经过显著冷变形的金属），这涉及多个概念的关联和综合判断。" + }, + { + "idx": 2226, + "question": "Why do metallic materials exhibit better mechanical properties after hot working compared to the as-cast state?", + "answer": "During hot working, metallic materials undergo dynamic deformation, dynamic recovery, and recrystallization processes. The columnar crystal zones and coarse equiaxed crystal zones disappear and are replaced by finer equiaxed grains. Many dispersed shrinkage pores and microcracks in the original ingot vanish due to mechanical welding effects, and microsegregation is also reduced to some extent through compression and diffusion. Consequently, the material's density and mechanical properties (especially plasticity and toughness) are improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么金属材料在热加工后比铸态具有更好的机械性能，答案提供了详细的文字解释和论述过程，符合简答题的特征。 | 知识层次: 题目要求解释金属材料在热加工后机械性能改善的机理，涉及动态变形、动态回复和再结晶等多个过程，需要综合分析材料微观结构变化与宏观性能之间的关系，属于复杂分析和机理解释的范畴。 | 难度: 在选择题中属于最高难度等级，需要深入理解金属材料热加工过程中的动态变形、动态回复和再结晶等复杂现象，并能综合解释这些过程如何改善材料的机械性能。题目要求考生不仅掌握基本概念，还需要进行机理深度解释和复杂现象全面分析，属于选择题型中对知识掌握深度和综合分析能力要求最高的类型。" + }, + { + "idx": 2227, + "question": "Determine whether the following view is correct. (7) Recovery, recrystallization, and grain growth are all processes of nucleation and growth, and their driving force is the stored energy.", + "answer": "Incorrect. Only the recrystallization process is a nucleation and growth process, and its driving force is the stored energy.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断给定的观点是否正确，答案直接给出了对错判断并简要解释了原因，符合判断题的特征。 | 知识层次: 题目涉及恢复、再结晶和晶粒长大三个过程的区分，需要理解它们的驱动机制和是否为形核长大过程。这需要将多个概念关联起来进行分析，而不仅仅是记忆单个概念的定义。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生综合分析恢复、再结晶和晶粒长大三个过程的本质及其驱动力，并判断给定观点的正确性。需要考生掌握这些过程的区别（如哪些属于形核长大机制）以及各自驱动力的来源（如储存能的作用范围）。这涉及多概念关联和综合分析能力，超出了简单记忆或单一概念应用的层次，符合等级4中\"综合分析结果判断\"的标准。" + }, + { + "idx": 2228, + "question": "Determine whether the following statement is correct. (3) Polygonization causes the scattered dislocations to gather together to form dislocation walls, and the superposition of dislocation stress fields increases the lattice distortion.", + "answer": "Incorrect. During the polygonization process, the vacancy concentration decreases and dislocations recombine, causing dislocations of opposite signs to cancel each other out, reducing dislocation density and thereby alleviating lattice distortion.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案明确指出了陈述的错误并解释了原因，符合判断题的特征。 | 知识层次: 题目涉及对多边形化过程中位错行为的理解，需要将位错重组、应力场叠加和晶格畸变等概念进行关联分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析多边形化过程中位错重组和应力场变化的复杂关系。题目不仅要求理解位错运动的基本概念，还需要掌握位错相互作用对晶格畸变的影响机制。正确选项涉及多步推理过程（位错重组→符号相反位错抵消→位错密度降低→晶格畸变减轻），且需要将多个材料科学概念（多边形化、位错应力场、晶格畸变）关联起来进行判断。这超出了简单记忆或单一概念应用的层次，属于需要综合分析能力的中等应用题型。" + }, + { + "idx": 2229, + "question": "Determine whether the following statement is correct. (4) For any metal that undergoes cold deformation followed by recrystallization annealing, the grain size can be refined.", + "answer": "Incorrect. If the metal is deformed at the critical deformation degree, the grain size will coarsen after recrystallization annealing.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个陈述的正确性（\"Determine whether the following statement is correct\"），答案直接给出了该陈述是错误的（\"Incorrect\"）并解释了原因。这符合判断题的特征，即判断给定陈述的对错。 | 知识层次: 题目不仅需要理解冷变形和再结晶退火的基本概念，还需要分析临界变形度对晶粒尺寸的影响，涉及多步概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解冷变形和再结晶退火的基本概念，还需要掌握临界变形程度对晶粒尺寸的影响这一特定知识点。解题时需要综合分析变形程度与再结晶后晶粒尺寸的关系，并判断题目陈述的正确性。这种综合分析结果判断的能力要求高于简单的概念记忆或单一知识点应用，因此属于等级4难度。" + }, + { + "idx": 2230, + "question": "The tungsten filament in a light bulb operates at very high temperatures, leading to significant grain growth. When large grains spanning the filament form, the filament becomes brittle under certain conditions and may fracture due to stresses caused by thermal expansion during heating and cooling. Find a method to extend the lifespan of the tungsten filament.", + "answer": "Dispersed, particulate second phases (such as $\\\\mathrm{ThO}_{2}$) can be introduced into the tungsten filament to restrict grain growth. If the volume fraction of $\\\\mathrm{ThO}_{2}$ is $\\\\varphi$ and the radius is $r$, the limiting grain size $R = \\\\frac{4r}{3\\\\varphi(1+\\\\cos\\\\alpha)}$ (where $\\\\alpha$ is the contact angle). By selecting appropriate values of $\\\\varphi$ and $r$ to minimize $R$, grain growth can be effectively halted. Since grain refinement significantly reduces the brittleness of the filament, it becomes less prone to fracture, thereby effectively extending its lifespan.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提出一个方法来延长钨丝寿命，并给出了详细的解释和公式应用，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求综合运用材料科学知识（如晶粒生长限制机制、第二相颗粒的作用）进行推理分析，解释如何通过控制第二相颗粒的参数（体积分数和半径）来优化钨丝性能，涉及多概念关联和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2231, + "question": "Determine whether the following view is correct. (5) The recrystallization temperature of a certain aluminum alloy is 320°C, indicating that this alloy can only undergo recovery below 320°C, while recrystallization must occur above 320°C.", + "answer": "Incorrect. Recrystallization is not a phase transformation. Therefore, it can occur over a wide temperature range.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断给定的观点是否正确，答案直接给出了对错判断并简要解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶温度及其相关基础概念的记忆和理解，属于材料科学中的基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（如recrystallization的定义和温度范围），但需要考生不仅记住定义，还要理解recrystallization不是一个相变过程，并且能够在不同温度下发生。这要求考生对概念有一定的理解深度，而不仅仅是简单的记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 2232, + "question": "Determine whether the following statement is correct. (2) Dynamic recrystallization only occurs under hot deformation conditions, therefore, metals deformed at room temperature will not undergo dynamic recrystallization.", + "answer": "Incorrect. The recrystallization temperature of some metals is below room temperature, so deformation at room temperature is also considered hot deformation, and dynamic recrystallization can occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案明确指出了原陈述的错误并给出了解释，符合判断题的特征。 | 知识层次: 题目不仅需要理解动态再结晶的基本概念，还需要结合不同金属的再结晶温度进行综合分析，判断在室温条件下是否可能发生动态再结晶。这涉及到对概念的应用和一定程度的推理分析。 | 难度: 在选择题中属于较高难度，需要综合分析动态再结晶的条件和金属的再结晶温度概念，并理解室温变形对某些金属而言可能属于热变形范畴。题目要求考生不仅掌握基础概念，还需要进行多步逻辑推理和特殊情况判断。" + }, + { + "idx": 2233, + "question": "Determine whether the following statement is correct. (6) The melting point of 20# steel is lower than that of pure iron, so its recrystallization temperature is also lower than that of pure iron.", + "answer": "Incorrect. The presence of trace solute atoms (wC=0.002 in 20# steel) hinders the recrystallization of the metal, thereby increasing its recrystallization temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案明确指出\"Incorrect\"并给出解释，符合判断题的特征 | 知识层次: 题目需要理解合金元素对金属性能的影响，并能够将溶质原子对再结晶温度的阻碍作用与熔点变化的影响进行综合分析。这涉及到多个概念的关联和一定程度的推理分析，超出了简单记忆或直接套用的层次。 | 难度: 在选择题中属于较高难度，需要综合分析多个概念（熔点、再结晶温度、溶质原子影响）并进行逻辑推理判断正误。题目不仅考察基础概念理解，还要求考生掌握溶质原子对金属再结晶行为的复杂影响机制，属于中等应用层次的多步骤综合分析题。" + }, + { + "idx": 2234, + "question": "Determine whether the following view is correct. (8) The greater the deformation of the metal, the more likely the recrystallization mechanism of grain boundary bulging nucleation will occur.", + "answer": "Incorrect. When the cold deformation degree of the metal is small, uneven deformation is more likely to occur in adjacent grains, that is, the dislocation density differs, making the recrystallization mechanism of grain boundary bulging nucleation more likely to occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个陈述是否正确（Determine whether the following view is correct），并且答案直接给出了该陈述是错误的（Incorrect）以及解释原因。这符合判断题的特征，即对给定的陈述进行对错判断。 | 知识层次: 题目涉及金属变形与再结晶机制的关联分析，需要理解变形程度对晶界凸起形核机制的影响，并进行综合判断，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析金属变形程度与再结晶机制之间的关系。题目不仅要求理解晶界凸起成核机制的概念，还需要掌握变形程度对位错密度分布的影响，并能将这两个概念关联起来进行判断。正确选项的解释涉及多步推理过程，包括理解小变形时的不均匀变形特性及其对位错密度差异的影响，这超出了简单概念记忆的范畴，需要进行较深入的综合分析。" + }, + { + "idx": 2235, + "question": "Determine whether the following view is correct. (9) Normal grain growth is the consumption of small grains by large grains, while abnormal growth is the consumption of large grains by small grains.", + "answer": "Incorrect. Normal grain growth is uniform growth driven by interface curvature, whereas abnormal growth is non-uniform growth where large grains consume small grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个陈述是否正确，答案明确指出了陈述的错误并给出了正确解释，符合判断题的特征。 | 知识层次: 题目考查对正常晶粒生长和异常晶粒生长这两个基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断，仅需记忆并区分正常晶粒生长和异常晶粒生长的基本定义即可作答。在选择题型中属于最简单的难度等级，不涉及复杂概念分析或比较。" + }, + { + "idx": 2236, + "question": "Determine whether the following statement is correct. (10) The second-phase particles in an alloy generally can hinder recrystallization but promote grain growth.", + "answer": "Incorrect. The second-phase particles in an alloy generally can hinder recrystallization and also impede grain growth.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了正确与否的判断并解释了原因 | 知识层次: 题目考查对第二相粒子在合金中作用的理解，需要将多个概念（再结晶、晶粒长大）关联起来进行分析，并判断其对错。这超出了单纯记忆基础概念的层次，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析第二相粒子对再结晶和晶粒长大的影响，并理解两者之间的相互作用关系。题目要求判断陈述的正确性，并选择正确的解释，涉及多步概念关联和综合分析能力。" + }, + { + "idx": 2237, + "question": "Determine whether the following statement is correct. (13) Recrystallization is a nucleation-growth process, so it is also a phase transformation process.", + "answer": "Incorrect. Although recrystallization is a nucleation-growth process, the crystal lattice type does not change, so it is not a phase transformation process.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的正确性，答案明确指出了陈述的错误并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶过程和相变过程这两个基础概念的理解和区分，属于基础概念的记忆和辨析范畴 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（再结晶和相变），但需要考生理解两个关键概念之间的关系（再结晶是形核-生长过程但不改变晶格类型）。这超出了简单的定义记忆（等级1），但尚未达到需要分析复杂概念陈述的程度（等级3）。考生需要正确区分形核-生长过程和相变过程的本质区别，这属于概念理解层面的对错判断。" + }, + { + "idx": 2238, + "question": "Determine whether the following statement is correct. (11) Recrystallization texture is the deformation texture retained during the recrystallization process.", + "answer": "Incorrect. Recrystallization texture is the texture formed during the recrystallization (primary, secondary) process of cold-deformed metals. It is formed on the basis of deformation texture, with two scenarios: one is retaining the original deformation texture, and the other is the disappearance of the original deformation texture, replaced by a new recrystallization texture.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目明确要求判断陈述的正确性（Determine whether the following statement is correct），且答案直接给出了该陈述是错误的（Incorrect）并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶织构这一基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目要求判断关于再结晶织构的陈述是否正确，需要考生理解再结晶织构的定义及其与变形织构的关系。虽然涉及基础概念记忆，但需要一定的概念理解和应用能力，属于中等偏下的难度。" + }, + { + "idx": 2239, + "question": "In Fe-Si steel (with $\\\\mathrm{{\\\\tau}}\\\\mathrm{{{w}}}_{\\\\mathrm{{Si}}}$ being 0.03), the measured diameter of $\\\\mathrm{MnS}$ particles is $0.4\\\\mu\\\\mathrm{m}$, and the number of particles per $1~\\\\mathrm{m}\\\\mathrm{m}^{2}$ is $2\\\\times10^{5}$. Calculate the effect of $\\\\mathrm{MnS}$ on the austenite grain growth during normal heat treatment of this steel (i.e., calculate the austenite grain size).", + "answer": "Let the number of $\\\\mathrm{MnS}$ particles per unit volume be $N_{\\\\mathrm{V}}(1/\\\\mathrm{m}\\\\mathrm{m}^{3})$. Given the number of MnS particles per unit area $N_{\\\\mathrm{A}}=$ $2\\\\times10^{5}~1/\\\\mathrm{m}\\\\mathrm{m}^{2}$ and the particle diameter $d=0.4~\\\\mu\\\\mathrm{m}$. According to the principles of quantitative metallography, $$ N_{\\\\mathrm{A}}=d N_{\\\\mathrm{v}} $$ The volume fraction of MnS is $$ \\\\varphi={\\\\frac{1}{6}}\\\\pi d^{3}N_{\\\\mathrm{v}}={\\\\frac{1}{6}}\\\\pi d^{2}N_{\\\\mathrm{A}}= $$ $$ \\\\frac{1}{6}\\\\pi\\\\times(0.4\\\\times10^{-3})^{2}\\\\times2\\\\times10^{5}=0.0167 $$ Therefore, during the heating of this steel, due to the effect of $\\\\mathrm{MnS}$ particles, the limiting size for austenite grain growth is $$ \\\\overline{{\\\\cal D}}_{\\\\mathrm{lim}}=\\\\frac{4r}{3\\\\varphi}=\\\\frac{4\\\\times0.2}{3\\\\times0.016~7}=16~\\\\mu\\\\mathrm{m} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及多个计算步骤和公式推导，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括定量金相学原理的应用、体积分数的计算以及奥氏体晶粒生长限制尺寸的推导。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算和概念关联。需要考生掌握定量金相学原理、体积分数计算以及奥氏体晶粒生长限制尺寸的计算方法。虽然题目提供了计算公式，但需要正确理解并应用这些公式，涉及单位换算和综合分析能力。相比简单记忆或单步计算的选择题，这类题目对考生的知识掌握深度和计算能力要求较高。" + }, + { + "idx": 2240, + "question": "If σ_α/β=200×10^-3 J/m^2, what is the total interfacial energy per cubic meter of the alloy? What is the total interfacial energy per mole of the alloy (V_m=10^-5 m^3/mol)?", + "answer": "The total interfacial energy per cubic meter of the alloy is 1.2×10^8×200×10^-3=240×10^5 J/m^3. The interfacial energy per mole of the alloy is γ=1.2×10^8×200×10^-3×10^-5=240 J/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案也是具体的计算结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的界面能数值代入公式进行直接计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及单位转换和基本公式套用，但解题步骤较为直接，仅需简单计算即可得出答案。不需要复杂的逻辑推理或多步骤分析，因此属于等级2难度。" + }, + { + "idx": 2241, + "question": "If the interfacial energy is the same as (3), how much driving force for phase transformation remains in the alloy?", + "answer": "420.8-240=180.8 J/mol. That is, after overcoming the interfacial energy during the phase transformation, there remains a driving force of 180.8 J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（420.8-240=180.8 J/mol）并应用公式来求解剩余的相变驱动力，答案以具体数值形式呈现。 | 知识层次: 题目涉及基本的数值计算和公式应用，仅需简单的减法运算和单位转换，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解界面能的概念并进行简单的减法运算，但解题步骤直接且仅涉及单一公式的套用和基本计算，没有复杂的分析或多个公式的组合应用。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2242, + "question": "Determine whether the following view is correct. (12) When the deformation is large and relatively uniform, the grains after recrystallization tend to undergo normal growth, otherwise, abnormal growth is more likely to occur.", + "answer": "Incorrect. Normal grain growth is the process of uniform grain growth that occurs during continued heating or holding after recrystallization is completed; whereas abnormal grain growth is the process of non-uniform grain growth that occurs under certain conditions (i.e., stable grains after recrystallization, the presence of a few grains favorable for growth, and high-temperature heating) following normal grain growth.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断给定的观点是否正确（\"Determine whether the following view is correct\"），答案明确给出了\"incorrect\"的判断并解释了原因，符合判断题的特征。 | 知识层次: 题目涉及对再结晶后晶粒生长行为的判断，需要理解正常晶粒生长和异常晶粒生长的条件及其区别，属于对多个概念的综合应用和分析。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生理解再结晶后晶粒生长的基本概念（正常生长和异常生长），还需要综合分析变形条件与生长类型之间的关系。正确选项需要考生能够区分两种生长模式的发生条件和时序关系（正常生长在先，异常生长在后），并识别题目中关于变形条件描述的误导性。这需要将多个材料科学概念（再结晶、晶粒生长、变形条件）关联起来进行综合判断，属于中等应用层次的知识运用。" + }, + { + "idx": 2243, + "question": "The carbon in iron, c0=wC=0.0001, E=-0.5 eV, calculate the critical temperature for solute segregation.", + "answer": "c=c0exp(-E/kT), when complete solute segregation occurs, c=wx=1, T=T∥s, 1=c0exp(-E/kT), then T∥⊥=-E/kln(1/c0). Substituting c0=wC=0.0001, E=-0.5 eV=-1.602×10^-19×0.5 J, T∥∥=(1.602×10^-19×0.5)/(1.381×10^-23×ln(1/0.0001))=629 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及代入数值、使用公式和最终得出计算结果。 | 知识层次: 题目需要进行多步计算，包括公式的变形和数值代入，同时需要理解溶质偏析的临界温度概念，并正确应用相关公式进行计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如溶质偏聚、临界温度计算）并进行多步计算（包括指数运算、单位转换和代数求解）。虽然题目提供了正确选项的推导过程，但仍要求考生能够综合运用物理化学知识，正确代入数值并执行计算步骤。" + }, + { + "idx": 2244, + "question": "In the regular melt α, the total driving force ΔG for the precipitation of β can be approximately expressed as ΔG=RT[x_o ln(x_o/x_e)+(1-x_o)ln((1-x_o)/(1-x_e))]-2Ω(x_o-x_e)^2. Given T=600K, x_o=0.1, x_e=0.02, Ω=0, use this expression to estimate the total driving force for α→α′+β.", + "answer": "Given T=600K, x_o=0.1, x_e=0.02, R=8.31 J/(mol·K). ΔG=RT[x_o ln(x_o/x_e)+(1-x_o)ln((1-x_o)/(1-x_e))]=8.31×600×[0.1 ln(0.1/0.02)+(1-0.1)ln((1-0.1)/(1-0.02))]=420.8 J/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式和参数进行数值计算，最终得出一个具体的数值结果。答案展示了具体的计算步骤和最终结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需将给定数值代入公式进行计算即可。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了所有必要的参数和公式，只需要将给定的数值代入公式中进行简单的计算即可得到答案。不需要理解多个概念或进行复杂的分析，解题步骤非常直接和简单。" + }, + { + "idx": 2245, + "question": "Using classical nucleation theory, calculate the shape factor η of a new phase when a cubic nucleus is formed by $n$ atoms during a solid-state phase transformation.", + "answer": "According to classical nucleation theory, during a solid-state phase transformation, the change in the system's free energy is given by $$ \\\\Delta G=n\\\\Delta G_{V}+S\\\\gamma+n E_{s}$$ where $\\\\Delta G_{V}$ is the free energy difference per atom between the old and new phases; S is the surface area of the nucleus; $\\\\gamma$ is the average surface energy; $E_{s}$ is the strain energy per atom in the nucleus; $n$ is the number of atoms in the nucleus. Assuming the density of the new phase is $\\\\rho$ and the relative atomic mass is $M,$ the volume occupied per gram-atom of the new phase material is $M/\\\\rho;$ the volume occupied per atom of the new phase is $M/(\\\\rho N_{0});$ the volume of a nucleus with $n$ atoms is $n M/(\\\\rho N_{0})$. If a cubic nucleus is formed, its edge length is $(n M/(\\\\rho N_{\\\\circ}))^{1/3}$, and the surface area of the nucleus is $6(n M/(\\\\rho N_{\\\\circ}))^{2/3}$. Thus, the shape factor $$\\\\eta=(M/(\\\\rho N_{\\\\circ}))^{2/3}$$ and the free energy change is $$ \\\\Delta G=n\\\\Delta G_{V}+6(M/(\\\\rho N_{\\\\L_{0}}))^{2/3}n^{2/3}\\\\gamma+n E_{s}$$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求使用经典成核理论计算立方核的形状因子η，涉及多个公式推导和数值计算步骤，答案呈现了详细的计算过程和最终公式结果。 | 知识层次: 题目需要应用经典成核理论进行多步计算，涉及自由能变化、表面能、应变能等多个概念的关联和综合分析。虽然不需要复杂的推理分析或创新应用，但需要理解和应用多个公式，并进行适当的数学推导和计算。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和多个概念的关联应用。需要理解经典成核理论、自由能变化公式、立方核的形成、体积和表面积的计算，以及形状因子的推导。此外，还需要对原子体积、密度、相对原子质量等概念有深入理解，并能将这些概念综合运用到具体计算中。这种题目不仅要求考生掌握相关理论知识，还需要具备较强的数学推导和综合分析能力。" + }, + { + "idx": 2246, + "question": "If an alloy has β-phase precipitates with a spacing of 50 nm after heat treatment, calculate the total area of α/β interfaces per cubic meter (assuming the precipitates are cubes).", + "answer": "The number of β precipitates is n_β=1/(50×10^-9)^3=8×10^21. The surface area of each β is S_β=6×(50×10^-9)^2=1.5×10^-14 m^2. The total interface area in 1 m^3 is S_A=8×10^21×1.5×10^-14=1.2×10^8 m^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解α/β界面的总面积，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算，包括计算β相析出物的数量、每个β相的表面积以及总的界面面积。虽然计算过程相对直接，但需要理解析出物间距与数量的关系，以及立方体表面积的计算方法，涉及一定的概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解合金相变、沉淀相间距计算、几何形状假设（立方体）、表面积计算等多个概念，并进行多步骤的综合计算。虽然题目提供了明确的解题路径，但涉及的知识点较多且需要准确串联各步骤，属于综合性计算问题。" + }, + { + "idx": 2247, + "question": "During solid-state phase transformation, assuming the new phase nucleus is spherical and the volume free energy change per atom ΔGv=200ΔT/Tc (J/cm³), the critical transformation temperature Tc=1000K, the strain energy Es=4 J/cm³, the coherent interface energy γ_coherent=40×10⁻⁷ J/cm², and the incoherent interface energy γ_incoherent=400×10⁻⁷ J/cm², calculate ΔT when ΔG_coherent* = ΔG_incoherent*.", + "answer": "Let ΔG_coherent* = ΔG_incoherent*, then (40×10⁻⁷)³ / (200×ΔT/1000 - 4)² = (400×10⁻⁷)³ / (200×ΔT/1000)². Solving gives ΔT ≈ 21K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解ΔT的值，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相变过程中的能量变化，并应用临界形核功的公式进行推导和计算。虽然不涉及复杂的机理分析或创新设计，但需要综合分析多个参数之间的关系，并进行适当的数学处理。 | 难度: 在选择题型内，该题目属于复杂多变量计算问题。题目要求考生理解固态相变中的多个关键概念（如体积自由能变化、应变能、共格与非共格界面能），并建立它们之间的数学关系。解题过程涉及多个步骤的代数运算和方程求解，包括设定方程、代入数值、解方程等。此外，题目还要求考生能够综合应用这些概念来比较共格和非共格形核的临界条件。这种综合性和复杂性在选择题型中属于较高难度，因此评估为等级4。" + }, + { + "idx": 2248, + "question": "For zinc in copper, c0=wZn=0.0001, E=-0.12 eV, calculate the critical temperature for solute segregation.", + "answer": "c=c0exp(-E/kT). When complete solute segregation occurs, c=wx=1, T=T∥s, 1=c0exp(-E/kT), then T∥⊥=-E/kln(1/c0). Substituting c0=wZn=0.0001, E=-0.12 eV=-1.602×10^-19×0.12 J, T∥∥=(1.602×10^-19×0.12)/(1.381×10^-23×ln(1/0.0001))=151 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及多个步骤的数学运算和物理常数的代入，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括公式变换、单位转换和数值代入，涉及对溶质偏析临界温度概念的理解和公式应用。虽然计算过程较为直接，但需要综合运用多个知识点，如能量单位转换、对数运算等，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解溶质偏析的概念，掌握指数公式的变形应用，并进行多步单位换算和数值计算。题目涉及能量单位转换(eV→J)、对数运算和临界温度推导，虽然计算过程明确但步骤较多，对学生的公式应用和计算能力要求较高。" + }, + { + "idx": 2249, + "question": "Analyze the main reasons for dislocations promoting nucleation, focusing on the case where the new phase nucleates on the dislocation line", + "answer": "When the new phase nucleates on the dislocation line, the dislocation disappears at the nucleation site, and the released elastic strain energy reduces the nucleation work, thereby promoting nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错促进形核的主要原因，并聚焦于新相在位错线上形核的情况。答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求分析位错促进形核的主要原因，并聚焦于新相在位错线上形核的情况。这需要综合运用位错理论、形核理论以及弹性应变能等知识，进行推理分析和机理解释。思维过程涉及多个概念的关联和深入理解，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 2251, + "question": "During the solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the time required to achieve a $50\\\\%$ transformation.", + "answer": "$$ \\\\varphi=1-\\\\exp\\\\Bigl(-\\\\textstyle{\\\\frac{\\\\pi}{3}}\\\\dot{N}G^{3}t^{4}\\\\Bigr)$$ $$ 50\\\\%=1-\\\\exp\\\\Bigl(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\Bigr)$$ $$ 0.6931={\\\\frac{\\\\pi}{3}}\\\\times1000\\\\times(3\\\\times10^{-5})^{3}t^{4}$$ $$ t^{4}=2.45\\\\times10^{10}$$ $$ t=395\\\\mathrm{~s~}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出具体的时间数值。解答过程涉及公式变换和数值运算，符合计算题的特征。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，涉及对数运算和指数函数的转换，需要理解相变动力学的基本原理并正确代入数值进行计算，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解Johnson-Mehl方程的概念，并进行多步骤的计算和转换。题目涉及对数运算、指数函数处理以及单位换算，虽然计算过程明确但步骤较多，对学生的综合计算能力和概念理解有一定要求。" + }, + { + "idx": 2252, + "question": "Analyze the resistance to solid-state phase transformation.", + "answer": "The resistance to nucleation during solid-state phase transformation arises from the interfacial energy $E_{\\\\gamma}$ introduced by the formation of an interface between the new-phase nucleus and the matrix, as well as the volumetric strain energy (i.e., elastic energy) $E_{\\\\mathrm{e}}$. The interfacial energy $E_{\\\\gamma}$ consists of two parts: one is the chemical energy caused by changes in the strength and quantity of like and unlike bonds when forming the new-phase interface in the parent phase, referred to as the chemical term of the interfacial energy; the other is the interfacial strain energy caused by the mismatch of interfacial atoms and the resulting strain in atomic spacing, referred to as the geometric term of the interfacial energy. The strain energy $E_{\\\\mathrm{e}}$ arises because the formation of the new phase in the parent phase, due to their differing specific volumes, induces volumetric strain. This volumetric strain is typically accommodated by elastic strain between the new phase and the parent phase, resulting in volumetric strain energy. Overall, as the size of the new-phase nucleus increases and the new phase grows, $(E_{\\\\gamma}+E_{e})$ will increase. Of course, $E_{\\\\gamma}$ and $E_{\\\\mathrm{e}}$ can also adjust to each other through factors such as the precipitation location, particle shape, and interface state of the new phase to minimize $(E_{\\\\gamma}+E_{e})$. When the parent phase is liquid, there is no issue of volumetric strain energy, and the interfacial energy of a solid phase is much higher than that of a liquid-solid interface. In comparison, the resistance to solid-state phase transformation is greater.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析固态相变的阻力，答案提供了详细的文字解释和论述，涉及界面能和应变能的概念及其影响因素，属于需要深入解释和论述的简答题类型。 | 知识层次: 题目要求分析固态相变过程中的阻力来源，涉及界面能和应变能的概念及其相互作用，需要综合运用多个知识点进行机理解释和推理分析。答案详细讨论了界面能的化学和几何部分、应变能的来源，以及它们如何相互调整以最小化总能量，体现了较高的认知层次和思维深度。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解固态相变过程中的成核阻力机制，包括界面能和应变能的详细组成及其相互作用。需要综合运用材料科学中的热力学、晶体学和弹性理论知识，分析不同能量项的来源和影响，并能比较固态与液态相变的差异。这种复杂现象全面分析的题目在选择题中属于对知识掌握深度和综合分析能力要求最高的类型。" + }, + { + "idx": 2253, + "question": "Analyze the driving force for particle coarsening when spherical second-phase particles precipitate from the solid solution.", + "answer": "Assume spherical β particles with radius r precipitate in the α parent phase, with volume V and β/α interfacial area S. The free energy can be expressed as $$ where G_V and E_s are the chemical free energy and elastic strain energy per unit volume of the new phase, respectively, and γ is the specific interfacial energy. The chemical potential of a certain component, such as the solute component, can be expressed as G = V(G_V + E_s) + Sγ $$ where Ω is the molar volume, i.e., the volume of the new phase corresponding to one mole of solute atoms. From the above two equations, we obtain $$ μ = Ω(G_V + E_s) + Ω(∂S/∂V)γ $$ where ∂S/∂V is the increase in surface area per unit volume increase. For spherical particles, we have Thus, $$ ∂S/∂V = d(4πr²)/d(4/3πr³) = 2/r $$ $$ μ = Ω(G_V + E_s) + 2Ωγ/r $$ Clearly, the chemical potential of solute atoms in spherical particles depends on the particle radius r. The smaller r is, the higher μ becomes, making such particles less stable. Assume two spherical β particles with radii r₁ and r₂ (r₁ > r₂) precipitate in the parent phase and are adjacent to each other. The difference in their chemical potentials is $$ Δμ = μ₂ - μ₁ = 2Ωγ(1/r₂ - 1/r₁) $$ This is the driving force for solute atoms to diffuse from smaller particles to larger ones, leading to particle coarsening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析球形第二相颗粒从固溶体中析出时的粗化驱动力，答案通过文字解释和公式推导详细论述了化学势与颗粒半径的关系以及粗化驱动力，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析球形第二相粒子从固溶体中析出时的粗化驱动力，涉及化学自由能、弹性应变能和界面能的概念，以及化学势与粒子半径的关系。需要综合运用热力学原理、扩散理论和材料科学知识进行推理分析，解释粒子粗化的机理。思维过程要求较高，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目涉及复杂的材料科学原理，包括化学自由能、弹性应变能、界面能等多个概念的整合运用。解题需要深入理解粒子粗化的驱动机理，并能进行数学推导（如化学势与粒子半径的关系）。此外，题目要求考生能够分析不同尺寸粒子间的化学势差，并解释扩散驱动的粗化过程，这需要综合运用热力学、动力学和材料科学知识进行推理分析。在选择题型中，这种需要多步骤推导和机理深度解释的题目属于最复杂的类型。" + }, + { + "idx": 2254, + "question": "Analyze the main reasons why dislocations promote nucleation, focusing on the scenario where dislocations do not disappear and adhere to the new phase interface", + "answer": "The dislocations do not disappear and instead adhere to the new phase interface, becoming part of the dislocations in the semi-coherent interface, compensating for the mismatch. This reduces the energy, thereby decreasing the energy required for nucleus formation and promoting nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错促进形核的主要原因，并针对特定情境进行论述。答案以文字解释和论述的形式呈现，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析位错促进形核的主要原因，并聚焦于位错不消失且附着在新相界面的特定情景。这需要深入理解位错理论、界面能量以及形核机制之间的复杂关系，并进行推理分析。涉及的知识点较为复杂，需要综合运用多个概念来解释现象，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2255, + "question": "Analyze the main reasons for dislocations promoting nucleation in the case where the composition of the new phase differs from that of the parent phase", + "answer": "When the composition of the new phase differs from that of the parent phase, the segregation of solute atoms along dislocation lines (forming Cottrell atmospheres) facilitates the precipitation of the new phase and also promotes nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析并解释位错促进新相成核的主要原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错促进新相形核的主要原因，涉及溶质原子在位错线上的偏聚（Cottrell气团）及其对新相析出的影响。这需要综合运用位错理论、相变原理和扩散知识，进行机理层面的解释和推理分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2256, + "question": "During the solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ of the new phase are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the maximum transformation rate during the phase transformation.", + "answer": "$$ \\\\frac{\\\\mathrm{d}\\\\varphi}{\\\\mathrm{d}t}=\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ Substitute $t_{\\\\mathrm{max}}=403$ into the above equation to calculate the maximum transformation rate.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，通过给定的参数和公式计算出最大转变速率，答案也给出了具体的计算步骤和结果。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，包括求导和数值代入，涉及对相变动力学的基本理解和公式的综合应用，但不需要复杂的推理或深度分析。 | 难度: 在选择题中属于中等难度，需要理解Johnson-Mehl方程并正确求导得到转化速率表达式，然后代入给定参数进行多步计算。题目涉及中等应用层次的知识点，要求综合分析和多步计算能力。" + }, + { + "idx": 2257, + "question": "What is the main difference between precipitation decomposition and spinodal decomposition in the formation of precipitated phases?", + "answer": "The main difference between the two in the formation of precipitated phases lies in the nucleation driving force and the compositional change of the new phase. During precipitation transformation, the formation of the new phase requires significant concentration fluctuations, and the composition of the new phase changes abruptly compared to the parent phase, resulting in interfacial energy. This necessitates a larger nucleation driving force to overcome the interfacial energy, meaning a greater degree of undercooling is required. In contrast, spinodal decomposition does not involve a nucleation process or abrupt compositional changes; any small concentration fluctuation can lead to the formation and growth of the new phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种分解过程的主要区别，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求对两种分解机制在析出相形成过程中的差异进行深入分析和比较，涉及成核驱动力、成分变化、界面能等机理层面的解释，需要综合运用相关概念并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解两种分解机制（沉淀分解和旋节分解）在形成析出相时的核心差异，包括成核驱动力和新相成分变化的机理。正确选项涉及复杂的热力学和动力学概念，需要综合运用材料科学原理进行推理分析。考生必须掌握浓度波动、界面能、过冷度等专业概念，并能区分成核生长与连续分解的本质区别。这种机理深度解释和复杂现象全面分析的要求，远超一般选择题的知识点记忆层面，属于选择题型中的顶尖认知负荷题目。" + }, + { + "idx": 2258, + "question": "The following equation represents the change in the system's free energy caused by the formation of a crystal embryo containing $n$ atoms. $$ \\\\Delta G=-\\\\:b n\\\\left(\\\\Delta G_{V}-E_{\\\\mathrm{s}}\\\\right)+a n^{2/3}\\\\gamma_{\\\\upalpha/\\\\upbeta} $$ where $\\\\Delta G_{V}$ is the free energy change per unit volume of the crystal embryo; $\\\\gamma_{\\\\mathfrak{a}/\\\\mathfrak{g}}$ is the interfacial energy; $E_{\\\\mathrm{s}}$ is the strain energy; $a, b$ are coefficients whose values are determined by the shape of the crystal embryo. \\n\\nFind the values of $a$ and $b$ when the crystal embryo is spherical. If $\\\\Delta G_{V}, \\\\gamma_{\\\\scriptscriptstyle\\\\alpha/\\\\beta}, E_{s}$ are all constants, derive the nucleation energy $\\\\Delta G^{*}$ for a spherical nucleus.", + "answer": "If precipitation occurs simultaneously throughout the parent phase, and the composition of the parent phase changes continuously with the formation of the new phase, but the grain morphology and orientation remain unchanged, it is called continuous precipitation. \\n\\nIn contrast to continuous precipitation, when precipitation occurs, the solid solution within a certain surrounding range immediately changes from a supersaturated state to a saturated state, forming a distinct interface with the original composition of the parent phase. After nucleation at grain boundaries, it grows into the grain interior in an alternating lamellar distribution. Not only does the composition change abruptly at the interface, but the orientation also changes. This is discontinuous precipitation. The main difference lies in the length of the diffusion path. In the former, the diffusion field extends over a considerable distance, while in the latter, the diffusion distance is on the order of the lamellar spacing (generally less than $1~\\\\mu\\\\mathrm{m}$). \\n\\nDiscontinuous precipitation has the following characteristics: \\n\\n(1) At the interface between the precipitate and the matrix, the composition is discontinuous; the interfaces between the precipitate and the matrix are all high-angle incoherent interfaces, indicating that the crystal orientation is also discontinuous. (2) Cellular precipitates usually nucleate at the grain boundaries of the matrix $({\\\\alpha^{\\\\prime}})$ and always grow into one of the adjacent grains of the $\\\\alpha^{'}$ phase. (3) During the growth of cellular precipitates, the redistribution of solute atoms is achieved through interfacial diffusion between the precipitate and the parent phase, with the diffusion distance typically less than $1~\\\\mu\\\\mathrm{m}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过公式推导和计算来求解特定条件下的系数（a和b）以及成核能（ΔG*），这属于典型的计算题。答案部分虽然包含了一些概念解释，但核心要求是进行数学推导和计算。 | 知识层次: 题目要求推导球形晶核的成核能ΔG*，涉及多步计算和公式应用，需要理解自由能变化方程中各参数的含义及其相互关系，并进行适当的数学推导。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多变量计算和概念关联。需要理解自由能变化方程中的各项含义，并推导球形晶核的成核能。此外，还需要掌握连续和不连续析出的区别及其特征，综合分析多个概念和计算步骤。" + }, + { + "idx": 2259, + "question": "In the process of solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the time at which the phase transformation rate is the fastest.", + "answer": "$$ \\\\varphi=1-\\\\exp\\\\Bigl(-\\\\textstyle{\\\\frac{\\\\pi}{3}}\\\\dot{N}G^{3}t^{4}\\\\Bigr)$$ $$ \\\\frac{\\\\mathrm{d}\\\\varphi}{\\\\mathrm{d}t}=\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ $$ \\\\frac{\\\\mathrm{d}^{2}\\\\varphi}{\\\\mathrm{d}t^{2}}=-\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)^{2}\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)+\\\\left(\\\\frac{12}{3}\\\\pi\\\\dot{N}G^{3}t^{2}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ ${\\\\frac{\\\\mathrm{d}^{2}\\\\varphi}{\\\\mathrm{d}t^{2}}}=0$ , i.e.,$$ -\\\\left({\\\\frac{4}{3}}\\\\pi{\\\\dot{N}}G^{3}t^{3}\\\\right)^{2}+\\\\left({\\\\frac{12}{3}}\\\\pi{\\\\dot{N}}G^{3}t^{2}\\\\right)=0$$ $$ t_{\\\\mathrm{max}}=\\\\left(\\\\frac{9}{4\\\\pi\\\\dot{N}G^{3}}\\\\right)^{1/4}=\\\\left[\\\\frac{9}{4\\\\times3.14\\\\times1000\\\\times(3\\\\times10^{-5})^{3}}\\\\right]^{\\\\frac{1}{4}}=403$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出具体的时间值。解答过程涉及导数和极值计算，属于典型的计算题特征。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，包括求导和求解方程，涉及对相变动力学的基本理解和公式的综合应用，但不需要复杂的推理或创新性思维。 | 难度: 在选择题中属于高难度，需要深入理解Johnson-Mehl方程及其微分运算，进行多步骤的数学推导和计算，包括二阶导数的求解和极值点的确定，涉及复杂的多变量计算和综合分析能力。" + }, + { + "idx": 2260, + "question": "What is the difference between continuous and discontinuous precipitation?", + "answer": "If precipitation occurs simultaneously throughout the parent phase, and the composition of the parent phase changes continuously with the formation of the new phase, but the grain morphology and orientation remain unchanged, it is called continuous precipitation. In contrast to continuous precipitation, when precipitation occurs, the solid solution within a certain range around it immediately changes from a supersaturated state to a saturated state, forming a distinct interface with the original composition of the parent phase. After nucleation at grain boundaries, it grows into the grain interior with an alternating lamellar distribution. Not only does the composition change abruptly at the interface, but the orientation also changes, which is called discontinuous precipitation. The main difference lies in the length of the diffusion path. In the former, the diffusion field extends over a considerable distance, while in the latter, the diffusion distance is only on the order of the lamellar spacing (generally less than 1 μm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释连续和不连续沉淀的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释连续和不连续析出的区别，涉及对析出过程的理解、扩散路径的分析以及微观结构的描述。虽然包含基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解连续和不连续析出的基本概念，还需要掌握两者在析出过程中的微观结构变化、成分变化、取向变化等多方面的差异。解题时需要综合分析多个知识点，包括扩散路径长度、界面特性、析出形态等，并进行多角度的比较分析。这种深度和广度的知识要求，使得该题目在选择题型中属于较难的水平。" + }, + { + "idx": 2261, + "question": "Describe the precipitation sequence of Al-Cu alloy", + "answer": "The precipitation sequence of Al-Cu alloy is: GP zones → θ′′ metastable phase → θ′ metastable phase → θ phase (equilibrium phase)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述Al-Cu合金的析出序列，需要文字解释和论述，答案给出了详细的析出过程，符合简答题的特征。 | 知识层次: 题目考查Al-Cu合金的析出序列，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述Al-Cu合金的析出序列，但正确选项已经提供了完整的序列，学生只需记忆和理解这一序列即可。这涉及到基础概念的记忆和简单描述，不需要复杂的分析或比较。因此，在选择题型内，这属于等级2的难度。" + }, + { + "idx": 2262, + "question": "What are the main characteristics of discontinuous precipitation?", + "answer": "Discontinuous precipitation has the following characteristics: (1) At the interface between the precipitate and the matrix, the composition is discontinuous; the interfaces between the precipitate and the matrix are all high-angle non-coherent interfaces, indicating that the crystal orientation is also discontinuous. (2) Cellular precipitates usually nucleate at the grain boundaries of the matrix (α') and always grow into one of the adjacent grains of the α' phase. (3) When cellular precipitates grow, the partitioning of solute atoms is achieved through their interfacial diffusion between the precipitate phase and the parent phase, with the diffusion distance typically less than 1 μm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述不连续沉淀的主要特征，答案以文字形式详细描述了多个特点，符合简答题的特征。 | 知识层次: 题目考查对不连续析出主要特征的基本概念记忆和理解，涉及定义和基本原理的描述，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个特征点的描述，但每个特征点都是对不连续沉淀现象的直接解释和描述，不需要进行复杂的比较分析或推导。考生只需准确记忆和理解这些基本特征即可正确作答。题目要求的知识点掌握深度属于基础概念记忆层次，解题步骤相对简单，主要考察对定义和基本原理的记忆能力。" + }, + { + "idx": 2263, + "question": "What is the essence of aging?", + "answer": "The essence of aging is the process of separating a new phase from a supersaturated solid solution, usually caused by temperature changes. The microstructure after aging consists of a matrix and precipitates. The matrix has the same crystal structure as the parent phase but differs in composition and lattice constants, while the precipitates can have different crystal structures and compositions from the parent phase. Due to variations in the properties, size, shape, and distribution of the precipitates in the microstructure, the performance of the alloy can change significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"aging\"的本质进行解释和论述，答案提供了详细的文字描述和概念分析，符合简答题的特征。 | 知识层次: 题目要求解释时效的本质及其对合金性能的影响，涉及相变过程、微观结构变化以及性能变化的综合分析，需要深入理解时效的机理和多因素的相互作用。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解时效处理的基本概念，还需要掌握复杂的微观结构变化机理，包括基体和析出相的晶体结构差异、成分变化及其对合金性能的影响。这需要考生具备综合运用材料科学知识的能力，能够分析复杂现象并进行机理解释，远超简单的概念记忆或单一知识点应用。" + }, + { + "idx": 2264, + "question": "For a φ5mm carbon steel sample with a carbon mass fraction of w_c=0.003, after heating and quenching at 860°C, the sample is tempered. How will the microstructure change during the tempering process?", + "answer": "For carbon steel with w_c=0.003, when tempered below 200°C, the changes in microstructure morphology are minor, and the hardness change is also small. However, the tendency for carbon atoms to segregate near dislocation lines increases. When the tempering temperature exceeds 250°C, cementite precipitates between laths or along dislocation lines, leading to a decrease in strength and plasticity. When the tempering temperature reaches 300~400°C, lamellar or rod-shaped cementite precipitates, causing a significant reduction in hardness and strength, while plasticity begins to increase. During tempering at 400~700°C, the carbides undergo aggregation, growth, and spheroidization, and the α phase undergoes recovery and recrystallization. At this stage, hardness and strength gradually decrease, while plasticity gradually increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述碳钢样品在回火过程中微观结构的变化，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析碳钢在回火过程中微观结构的变化，涉及多个温度阶段的不同相变行为和性能变化，需要综合运用材料科学中的相变理论、碳钢的回火行为以及微观结构与性能之间的关系等知识进行推理分析。这超出了简单记忆或基本应用的范畴，属于对复杂机理的解释和综合分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2265, + "question": "If a new phase in a solid-state phase transformation precipitates from the parent phase as spherical particles, and the change in free energy per unit volume is $10^{8}\\\\mathrm{~J~}\\\\cdot\\\\mathrm{~m~}^{-3}$, the specific surface energy is $1~\\\\mathrm{J}\\\\cdot\\\\mathrm{m}^{-2}$, and the strain energy is negligible, calculate the diameter of the new phase particles when the surface energy is $1\\\\%$ of the volume free energy.", + "answer": "Diameter $2r=6\\\\times10^{-6}\\\\mathrm{~m~}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解新相粒子的直径，答案是一个具体的数值结果（Diameter $2r=6\\times10^{-6}\\mathrm{~m~}$），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解自由能变化、表面能的概念，并应用相关公式进行计算。虽然计算过程不复杂，但需要综合分析自由能和表面能的关系，并正确应用公式求解粒子直径。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及固体相变中的自由能变化、表面能和应变能的概念，并要求计算新相粒子的直径。虽然题目提供了具体数值，但需要学生理解表面能与体积自由能之间的关系，并正确应用公式进行计算。解题步骤包括理解题意、建立数学模型、代入数值计算，属于多步骤计算过程，但相对于更复杂的多变量计算问题，难度适中。" + }, + { + "idx": 2266, + "question": "Describe the characteristics of diffusionless phase transformation.", + "answer": "Diffusionless phase transformation has the following characteristics: (1) There is a shape change caused by uniform shear, resulting in a change in the crystal's external form. (2) Since the phase transformation process is diffusionless, the new phase and the parent phase have the same chemical composition. (3) There is a certain crystallographic orientation relationship between the parent phase and the new phase. (4) The phase boundary moves extremely fast, approaching the speed of sound.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述扩散less相变的特征，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目要求描述扩散相变的特征，涉及对相变过程中晶体结构变化、化学成分保持、取向关系以及相界移动速度的理解和综合分析。虽然不涉及复杂计算，但需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅理解扩散型相变的基本概念，还需要掌握扩散型相变与无扩散型相变的区别，并能综合分析无扩散型相变的多个特征（如形状变化、化学成分不变、晶体学取向关系、相界移动速度等）。这些知识点需要考生进行多角度分析和关联性思考，而不仅仅是简单的记忆或单一概念的应用。因此，该题目在选择题型中属于等级4的难度。" + }, + { + "idx": 2267, + "question": "Describe the basic characteristics of the possible precipitates in Al-Cu alloys", + "answer": "GP zones are disc-shaped, with a thickness of 0.3~0.6nm and a diameter of about 8nm, formed on the {100} planes of the parent phase. Their lattice is the same as that of the matrix α (fcc) and is fully coherent with the α phase. The θ′′ transition phase is disc-shaped, with a thickness of 2nm and a diameter of 30~40nm, formed on the {100} planes of the parent phase. It has a tetragonal lattice with lattice constants a=b=0.404nm, c≈0.78nm, and is fully coherent with the matrix. However, due to the difference in lattice constants along the Z-axis, there is about 4% mismatch, creating an elastic coherency strain field around θ′′. The θ′ transition phase also forms on the {100} planes of the matrix, with a tetragonal structure and lattice constants a=b=0.404nm, c=0.58nm, and its nominal composition is CuAl2. Due to the large mismatch along the Z-axis, it can only maintain partial coherence with the matrix. The θ phase has a tetragonal structure with lattice constants a=b=0.607nm, c=0.487nm. This equilibrium precipitate phase is completely incoherent with the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述Al-Cu合金中可能析出相的基本特征，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述Al-Cu合金中可能析出相的基本特征，涉及多个析出相（GP zones、θ′′、θ′、θ）的形态、晶体结构、晶格常数以及与基体的共格关系等。虽然这些信息需要记忆，但题目要求将这些知识点进行关联和综合分析，理解不同析出相之间的差异及其对材料性能的影响。因此，这属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅要记忆Al-Cu合金中不同析出相的基本特征，还需要理解并比较它们的晶体结构、晶格常数、共格性以及与母相的关系。题目涉及多个析出相（GP区、θ′′相、θ′相和θ相）的详细描述，需要考生能够综合分析这些信息，并在选择题的选项中准确识别正确描述。此外，题目还要求考生理解共格应变场和部分共格等概念，这增加了题目的复杂性和难度。因此，该题目在选择题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 2268, + "question": "Why do transition phases appear during the precipitation process?", + "answer": "Transition phases appear during the precipitation process because the system requires a series of intermediate transition phases to gradually reduce free energy during the transformation from a supersaturated solid solution to the equilibrium phase. These transition phases, with their crystal structures and compositions intermediate between GP zones and the equilibrium phase, can reduce nucleation work and strain energy, making the phase transformation process easier to proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释过渡相在析出过程中出现的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释过渡相在析出过程中出现的原因，涉及自由能降低、中间过渡相的作用、晶体结构和成分的中间性、形核功和应变能的减少等多个方面的综合分析。需要深入理解相变机理，并能将这些概念关联起来进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解相变过程中的自由能变化、过渡相的作用机理等复杂概念，并能综合运用这些知识解释现象。正确选项涉及多个专业概念（如GP区、应变能、形核功等）的关联分析，需要考生具备将理论知识转化为机理解释的能力，这远超出简单记忆或基础理解的范畴。在选择题型中，此类需要综合推理和机理深度分析的题目属于最复杂的类型。" + }, + { + "idx": 2269, + "question": "For carbon steel samples with carbon mass fractions of w_c=0.003 and w_C=0.012 and a diameter of φ5mm, both heated at 860°C and then quenched, explain the microstructure morphology, fine structure, and composition obtained after quenching.", + "answer": "Heated at 860°C, both steels are in the single-phase region (refer to the Fe-Fe3C phase diagram), and after quenching, both form martensite. The carbon steel with w_C=0.012 contains a certain amount of retained austenite. For the carbon steel with w_c=0.003, the martensite composition is w_c=0.003, with a lath-like morphology and a fine structure of dislocations. For the carbon steel with w_c=0.012, the martensite composition is w_c=0.012, with an acicular morphology and a fine structure of twins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释淬火后获得的微观结构形态、精细结构和成分，需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释不同碳含量钢在淬火后的显微组织形态、精细结构和成分，需要综合运用Fe-Fe3C相图知识、马氏体转变机理以及不同碳含量对马氏体形态和精细结构的影响。这涉及到多个概念的关联和深入分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2270, + "question": "Referring to the composite material in the previous question. Given that the yield strength of steel is 280 MPa and the yield strength of copper is 140 MPa. What is the maximum tensile load the composite material can withstand without undergoing plastic deformation?", + "answer": "The maximum tensile force is F⊥=Fcu+Fst=(140×10^6 N/m^2)×(2.4×10^−6 m^2)+(260×10^6 N/m^2)×(0.8×10^−6 m^2)=540 N", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的材料参数和公式来求解最大拉伸载荷，答案也是具体的数值计算结果。 | 知识层次: 题目涉及基本公式应用和简单计算，直接套用给定的材料参数和面积数据进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及两种材料的强度计算，但解题步骤较为直接，只需分别计算铜和钢的承受力并相加。不需要复杂的分析或多步骤推理，属于基础应用层次。" + }, + { + "idx": 2271, + "question": "For a φ5mm carbon steel sample with a carbon mass fraction of w_c=0.012, after quenching at 860°C and then tempering, how will the microstructure change during the tempering process?", + "answer": "For carbon steel with w_c=0.012, when tempered below 100°C, carbon atoms form carbon-rich regions; during tempering at 100~200°C, a large number of fine carbides precipitate, resulting in a slight increase in hardness; during tempering at 200~300°C, retained austenite transforms into tempered martensite (or bainite), causing an increase in hardness, but at the same time, the hardness of martensite decreases, so overall, the hardness change is minimal; when tempered above 300°C, carbides continue to precipitate, followed by carbide growth and spheroidization, while the α phase undergoes recovery and recrystallization, leading to a decrease in hardness and an increase in toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述碳钢样品在回火过程中微观结构的变化过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析碳钢在回火过程中微观结构的变化，涉及多个温度阶段的相变和性能变化，需要综合运用材料科学中的相变理论、热处理原理和显微组织分析知识。解答过程需要对不同温度下的回火机制进行推理和解释，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对碳钢在回火过程中的微观组织变化有深入的理解，包括不同温度区间内的碳原子行为、碳化物析出、残余奥氏体转变以及α相的回复再结晶等复杂现象。解题需要综合运用材料科学中的相变理论、热处理原理和显微组织分析知识，进行多步骤的推理和机理解释。这种题目不仅考察知识点的记忆，更强调对复杂现象全面分析的能力，因此在选择题型中属于最高难度。" + }, + { + "idx": 2272, + "question": "Referring to the composite material in the previous question. Given that the yield strength of steel is 280 MPa and the yield strength of copper is 140 MPa. If the composite material is subjected to tension, which metal will yield first?", + "answer": "Since the stress ratio is 1.86, when the stress on steel is 140 MPa, the stress on copper is also 140 MPa. Therefore, copper will yield first.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要解释和论述两种金属在复合材料中的屈服行为，答案提供了详细的文字解释和逻辑推理，而不是简单的选择或计算。 | 知识层次: 题目涉及简单的应力计算和材料屈服强度的比较，属于基本公式应用和直接套用范畴，不需要复杂的分析或多步计算。 | 难度: 在选择题中属于较低难度，题目仅需简单应用基本公式和直接比较两种金属的屈服强度，无需复杂计算或多步骤推理。正确选项直接给出了结论和简单解释，符合简单应用的知识层次要求。" + }, + { + "idx": 2273, + "question": "A steel wire with a diameter of 0.89 mm has σ_ss=980 MPa and σ_sb=1,130 MPa. There is also an aluminum alloy with σ_as=255 MPa and σ_ab=400 MPa. Their densities are known to be ρ_s=7.85 g/cm³ and ρ_a=2.7 g/cm³, respectively. If the aluminum wire is to bear the same maximum load without deformation, how much heavier or lighter is it compared to the steel wire (expressed as a percentage)?", + "answer": "σ_ss=φ_max/A_s=980, σ_as=φ_max/A_a=255. From these two equations, we know A_s/A_a=255/980. A_a=3.84A_s. m_a/m_s=(3.84×2.7)/(1×7.85)=1.32. 1.32-1=0.32=32%. This aluminum wire is 32% heavier than the steel wire.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来比较两种材料的重量差异，答案涉及具体的数值计算过程和百分比结果。 | 知识层次: 题目需要进行多步计算，包括应力与面积的关系推导、不同材料的性能比较以及密度和质量的综合计算。虽然不涉及复杂的机理分析或创新设计，但需要将多个概念（应力、面积、密度）关联起来进行综合分析，并最终得出比较结果。这超出了简单应用的范畴，属于中等难度的应用题目。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如应力、面积、密度）并进行比较分析。题目涉及多步骤计算过程，包括应力与面积的关系推导、面积比的转换以及质量比的计算。虽然计算步骤较多，但每一步都是基于基本物理概念，且在选择题型中可以通过选项验证思路的正确性，因此不属于最复杂的多变量计算问题。" + }, + { + "idx": 2274, + "question": "A steel wire with a diameter of 0.89 mm has σ_ss=980 MPa and σ_sb=1,130 MPa. Another aluminum alloy has σ_as=255 MPa and σ_ab=400 MPa. Their densities are known to be ρ_s=7.85 g/cm³ and ρ_a=2.7 g/cm³, respectively. What if they do not break?", + "answer": "σ_sb=φ_max/A_s=1,130, σ_ab=φ_max/A_a=400. From the above two equations, A_s/A_a=400/1,130. A_a=2.825A_s. m_a/m_s=(2.825×2.7)/(1×7.85)=0.97. 0.97-1=-0.03=-3%. That is, the aluminum wire is 3% lighter than the steel wire.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目提供了具体的材料参数和密度，要求通过公式计算比较两种材料的重量差异，解答过程涉及数值计算和公式应用。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用材料的力学性能和密度数据进行计算，并进行比较分析。虽然不涉及复杂的推理或机理解释，但需要理解和应用多个参数之间的关系。 | 难度: 在选择题中属于中等偏上难度，需要理解材料的强度、密度等基本概念，并进行多步计算和比较分析。题目涉及两个不同材料的性能参数，要求考生能够正确应用公式计算面积比和质量比，最后得出百分比差异。虽然题目提供了正确选项，但解题过程需要综合运用多个知识点和计算步骤，属于综合性计算问题。" + }, + { + "idx": 2275, + "question": "Referring to the composite material in the previous question. Given that the elastic modulus of steel is 205 GPa and the elastic modulus of copper is 110 GPa. What is the elastic modulus of this composite material?", + "answer": "E=(φE)st+(φE)cu=0.25×(205000 MPa)+0.75×(110000 MPa)=130000 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的弹性模量和体积分数进行数值计算，并应用混合法则公式来求解复合材料的弹性模量。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，只需要将给定的弹性模量和体积分数代入公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的复合弹性模量公式（E=(φE)st+(φE)cu），并进行简单的数值代入和计算。无需理解多个概念或进行复杂的分析，属于单一公式直接计算的难度等级。" + }, + { + "idx": 2276, + "question": "Please derive the rule of mixtures for the longitudinal elastic modulus of a fiberglass composite fishing rod (composed of longitudinally aligned glass fibers and polyester resin as the bonding fiber).", + "answer": "The derivation assumes that the two constituent materials have the same Poisson's ratio, and the transverse strain is negligible. Under longitudinal loading, the strains of the two components must be equal, i.e., $$ {\\\\varepsilon}_{\\\\mathfrak{g}1}={\\\\varepsilon}_{\\\\mathfrak{m}}={\\\\varepsilon}_{\\\\mathfrak{p}\\\\mathfrak{r}}$$ $$ {\\\\frac{F/f_{\\\\mathrm{^{gl}}}}{E_{\\\\mathrm{gl}}}}={\\\\frac{F/A}{E_{\\\\mathrm{m}}}}={\\\\frac{F/f_{\\\\mathrm{pr}}}{E_{\\\\mathrm{pr}}}}$$ where $E_{\\\\mathrm{m}}$ is the elastic modulus of the mixture; $_{\\\\mathrm{g1}}$ represents glass fiber; pr represents resin fiber; $A$ is the total cross-sectional area (can be considered as 1), and $f$ is the cross-sectional area (or volume) fraction of different materials. Then, $$ \\\\begin{array}{c}{F_{\\\\mathrm{g1}}=\\\\frac{f_{\\\\mathrm{g1}}E_{\\\\mathrm{g1}}F}{E_{\\\\mathrm{m}}}}\\\\\\\\ {F_{\\\\mathrm{pr}}=\\\\frac{f_{\\\\mathrm{pr}}E_{\\\\mathrm{pr}}F}{E_{\\\\mathrm{m}}}}\\\\end{array}$$ Since $F=F_{\\\\mathrm{gl}}+F_{\\\\mathrm{pr}}$, it follows that $$ F=\\\\frac{(f_{\\\\mathrm{gl}}E_{\\\\mathrm{gl}}+f_{\\\\mathrm{pr}}+E_{\\\\mathrm{pr}})F}{E_{\\\\mathrm{m}}}$$ $$ E_{\\\\mathrm{m}}=f_{\\\\mathrm{g1}}E_{\\\\mathrm{g1}}+f_{\\\\mathrm{pr}}E_{\\\\mathrm{pr}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导纤维增强复合材料纵向弹性模量的混合规则，涉及公式推导和数学运算，答案展示了详细的推导过程和最终公式，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目需要多步计算和概念关联，涉及复合材料弹性模量的混合规则推导，需要理解应变相等假设和体积分数的应用，并进行公式推导和综合。虽然不涉及复杂的机理分析或创新设计，但超出了简单套用公式的范畴。 | 难度: 在选择题型中，该题目属于高难度级别。题目要求推导纤维增强复合材料纵向弹性模量的混合规则，涉及多个概念的综合运用和复杂的多步计算。具体来说，题目需要考生理解并应用以下内容：" + }, + { + "idx": 2277, + "question": "From the perspective of wettability, should β-SiC whiskers or Al2O3 short fibers be selected as the reinforcement for aluminum matrix composites? It is known that the wettability of molten aluminum on β-SiC is higher than that on Al2O3.", + "answer": "The wettability of molten aluminum on β-SiC is higher than that on Al2O3. From the perspective of wettability, β-SiC whiskers should be selected as the reinforcement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从润湿性角度分析并选择增强材料，答案需要文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目要求从润湿性角度分析并选择增强材料，涉及对润湿性概念的理解和应用，需要综合分析已知条件（熔融铝在β-SiC上的润湿性高于Al2O3）并做出合理选择。虽然不涉及复杂计算，但需要关联概念和进行简单推理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生从润湿性的角度选择增强材料，需要掌握润湿性的概念及其对复合材料性能的影响，并比较两种材料（β-SiC晶须和Al2O3短纤维）在润湿性上的差异。虽然题目提供了关键信息（熔融铝在β-SiC上的润湿性高于Al2O3），但仍需要考生进行综合分析才能得出正确结论。" + }, + { + "idx": 2278, + "question": "Calculate the critical length Lc of β-SiC whiskers, given a diameter of 0.5μm, tensile strength of 70000MPa, and interfacial shear strength τy approximated by the matrix yield strength of 76MPa.", + "answer": "For β-SiC whiskers, the critical length Lc = (0.5×10^-6 × 70000) / (2 × 38) = 460.5×10^-6 m = 460.5μm. Since the actual length of 70μm is less than Lc, the fibers do not achieve the maximum strengthening effect.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（直径、拉伸强度、界面剪切强度）进行数值计算，应用公式求解临界长度Lc，答案也是具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解临界长度的概念并将其与材料参数（直径、拉伸强度、界面剪切强度）关联起来进行计算。虽然计算过程相对直接，但需要对材料性能参数的综合理解和应用。 | 难度: 在选择题中属于中等偏上难度，需要理解临界长度的计算公式，并进行多步单位换算和数值计算。题目涉及材料力学性能参数的综合运用，要求考生能够正确代入公式并处理单位转换（MPa到Pa、μm到m），最后还需要对计算结果进行实际意义分析（比较实际长度与临界长度）。虽然题目提供了公式框架，但计算步骤和概念关联性较强，在选择题型中属于需要一定综合分析能力的题目。" + }, + { + "idx": 2279, + "question": "Calculate the critical length Lc of Al2O3 short fibers, given a diameter of 10μm, tensile strength of 2275MPa, and interfacial shear strength τy approximated by the matrix yield strength of 76MPa.", + "answer": "For Al2O3 short fibers, the critical length Lc = (10×10^-6 × 2275) / (2 × 38) = 299.3×10^-6 m = 299.3μm. Since the actual length of 4mm is greater than Lc, the fibers can achieve maximum strengthening effect.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（直径、拉伸强度、界面剪切强度）进行数值计算，应用公式求出临界长度Lc，答案也是具体的计算结果。整个过程符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的参数和公式计算临界长度Lc。虽然需要理解临界长度的概念，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用和简单计算，即使用临界长度公式 Lc = (d × σ) / (2 × τ) 进行计算。解题步骤简单，无需多个公式组合或复杂分析，属于最基础的难度等级。" + }, + { + "idx": 2281, + "question": "Predict the strength σLu of an Al2O3 short fiber reinforced composite at a volume fraction φf=0.1, given the fiber stress σf=2190MPa and the matrix yield strength σy=76MPa.", + "answer": "For Al2O3 short fiber composites, the strength σLu = σf × φf + σy × (1 - φf) = 2190 × 0.1 + 76 × 0.9 = 386MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出一个数值结果。答案展示了完整的计算过程和最终结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及复合材料强度的基本公式套用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需直接套用单一公式进行计算（σLu = σf × φf + σy × (1 - φf)），无需理解多个概念或进行复杂步骤。题目提供所有必要参数，仅需简单代入和基础算术运算即可得出答案，属于最基础的计算题类型。" + }, + { + "idx": 2282, + "question": "Calculate the critical volume fraction φtr of β-SiC whisker reinforced composite, given the matrix tensile strength σm=186MPa, yield strength σy=76MPa, and average fiber stress σf=5320MPa.", + "answer": "For β-SiC whiskers, the critical volume fraction φtr = (σm - σy) / (σf - σy) = (186 - 76) / (5320 - 76) = 0.021.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出一个具体的数值结果（临界体积分数φtr），这符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，无需多步推理或综合分析，仅需理解公式中各参数的含义并进行数值代入计算。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了所需的公式和所有必要的参数，只需要进行简单的代入和计算即可得出答案。不需要理解多个概念或进行复杂的分析，因此属于最低难度等级。" + }, + { + "idx": 2283, + "question": "Calculate the fiber stress σf of Al2O3 short fibers when the length exceeds the critical length, given the fiber tensile strength σfa=2275MPa, critical length Lc=299.3μm, and actual length L=4mm.", + "answer": "For Al2O3 short fibers, the fiber stress σf = (1 - Lc/(2L)) × σfa = (1 - 299.3×10^-6/(2 × 4000×10^-6)) × 2275 = 2190MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和单位转换，最终给出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，虽然需要理解临界长度的概念，但整体思维过程较为直接，属于基本公式套用和数值计算的范畴。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解临界长度和实际长度的概念，但解题步骤仅涉及直接套用一个明确的公式（σf = (1 - Lc/(2L)) × σfa），并进行简单的单位换算和代数运算。不需要多个公式组合或复杂的推导过程，因此难度等级为2。" + }, + { + "idx": 2284, + "question": "Predict the strength σLu of a β-SiC whisker-reinforced composite with a volume fraction φf=0.1, given the average fiber stress σf=5320MPa and the matrix yield strength σy=76MPa.", + "answer": "For the β-SiC whisker composite, the strength σLu = σf × φf + σy × (1 - φf) = 5320 × 0.1 + 76 × 0.9 = 700MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体计算，最终得出一个数值结果。解答过程涉及公式应用和数值运算，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的公式和数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即σLu = σf × φf + σy × (1 - φf)。解题步骤简单，无需复杂的分析或组合多个公式，属于最基础的难度等级。" + }, + { + "idx": 2285, + "question": "Calculate the critical volume fraction φtr of Al2O3 short fiber reinforced composite, given the matrix tensile strength σm=186MPa, yield strength σy=76MPa, and fiber stress σf=2190MPa.", + "answer": "For Al2O3 short fibers, the critical volume fraction φtr = (σm - σy) / (σf - σy) = (186 - 76) / (2190 - 76) = 0.052.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目涉及基本公式的直接应用和简单计算，无需多步推理或综合分析，仅需理解公式中各参数的含义并进行数值代入即可求解。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了所有必要的参数，并且只需要套用一个简单的公式（φtr = (σm - σy) / (σf - σy)）即可得出答案。计算过程简单，无需复杂的推理或多步骤的推导，因此属于最低难度等级。" + }, + { + "idx": 2286, + "question": "A steel wire (with a diameter of $1~\\\\mathrm{mm}$) is coated with a layer of copper (total diameter of $2~\\\\mathrm{mm}$). What is the thermal expansion coefficient of this composite material? The elastic modulus of steel is $E_{\\\\mathrm{st}}{=}205~\\\\mathrm{GPa}$, and that of copper is $E_{\\\\mathrm{cu}}{=}110~\\\\mathrm{GPa}$; their expansion coefficients are $\\\\alpha_{\\\\mathrm{st}}=1.1\\\\times10^{-6}/\\\\mathsf{\\\\Pi}^{\\\\circ}\\\\mathsf{C}, \\\\alpha_{\\\\mathrm{Cu}}=17\\\\times10^{-6}/\\\\mathsf{\\\\Pi}^{\\\\circ}\\\\mathsf{C}$ respectively.", + "answer": "Under no-load conditions, the composite material satisfies $(\\\\Delta l/L)_{\\\\mathrm{st}}=(\\\\Delta l/L)_{\\\\mathrm{cu}}$, and the forces $F_{\\\\mathrm{Cu}}=-F_{\\\\mathrm{st}}$. If $\\\\Delta t= 1^{\\\\circ}\\\\mathrm{C}$, then $$ A_{\\\\mathrm{Cu}}=\\\\pi(\\\\frac{d}{2})^{2}=(\\\\pi/4)(0.002\\\\mathrm{m})^{2}-0.8\\\\times10^{-6}\\\\mathrm{m}^{2}=2.4\\\\times10^{-6}\\\\mathrm{m}^{2}$$ $$ (\\\\Delta l/L)_{\\\\mathrm{st}}=(\\\\Delta l/L)_{\\\\mathrm{cu}}$$ $$ \\\\begin{array}{r}{\\\\left[\\\\alpha\\\\Delta t+(F/A)/E\\\\right]_{\\\\ast}=\\\\left[\\\\alpha\\\\Delta t+(F/A)/E\\\\right]_{\\\\mathrm{cu}}}\\\\end{array}$$ $$ 1\\\\times10^{-6})\\\\times1+{\\\\frac{F_{\\\\mathrm{st}}/(0.8\\\\times10^{-6}{\\\\mathrm{m}}^{2})}{205\\\\times10^{9}{\\\\mathrm{N/m}}^{2}}}=(17\\\\times10^{-6})\\\\times1+{\\\\frac{-F_{\\\\mathrm{st}}/(2.4\\\\times10^{-6}{\\\\mathrm{m}}^{2})}{110\\\\times10^{9}{\\\\mathrm{N/m}}^{2}}}$$ When $\\\\Delta t=1~^{\\\\circ}C$, then $$ (\\\\Delta l/L)_{\\\\mathrm{cu}}=(17\\\\times10^{-6}/^{9}\\\\mathbb{C}\\\\times1^{9}\\\\mathbb{C})+\\\\frac{=0.61~\\\\mathrm{N}/(2.4\\\\times10^{-6}~\\\\mathrm{m}^{2})}{110\\\\times10^{9}~\\\\mathrm{N/m}^{2}}=15\\\\times10^{-6}$$ Thus, the thermal expansion coefficient of the composite material is $$ \\\\overline{{\\\\alpha}}=15\\\\times10^{-6}/^{\\\\circ}\\\\mathrm{C}$$ $A_{\\\\mathrm{st}}=\\\\pi(\\\\frac{d}{2})^{2}=(\\\\pi/4)(0.001~\\\\mathrm{m})^{2}=0.8\\\\times10^{-6}~\\\\mathrm{m}^{2}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及热膨胀系数的复合计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用热膨胀系数、弹性模量等知识，并进行综合分析。虽然不涉及复杂的推理分析或机理解释，但需要理解和应用多个物理概念和公式，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及多步复杂计算和多个物理概念的关联应用。需要正确理解复合材料的膨胀行为，建立力学平衡方程，并进行精确的数值计算。解题步骤包括面积计算、应变平衡方程建立、力平衡条件应用以及最终的热膨胀系数求解，涉及多个变量和单位转换，对综合分析和计算能力要求较高。" + }, + { + "idx": 2287, + "question": "Calculate the average stress σf of β-SiC whiskers when the critical length is not reached, given the matrix yield strength σy=76MPa, fiber length L=70μm, and diameter df=0.5μm.", + "answer": "For β-SiC whiskers, the average stress σf = (τy × L) / df = (σy × L) / (2 × df) = (76 × 70×10^-6) / (2 × 0.5×10^-6) = 5320MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，给出了具体的参数和计算公式，最终需要得出一个具体的数值结果。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及纤维增强复合材料的应力传递机制，但计算过程较为直接，仅需套用给定公式进行数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解基本概念（如临界长度未达到时的平均应力计算公式），但解题步骤相对直接，仅需套用单一公式并进行简单单位换算和代数运算。不需要组合多个公式或进行复杂分析，因此属于等级2难度。" + }, + { + "idx": 2288, + "question": "A contact device is made of silver-tungsten composite material. Its production process involves first creating a porous tungsten powder metallurgy blank, and then infiltrating pure silver into the pores. Before silver infiltration, the density of the tungsten compact is 14.5 g/cm³. Calculate the mass fraction of silver in the blank after infiltration. The densities of pure tungsten and pure silver are 19.3 g/cm³ and 10.49 g/cm³, respectively. Assume the tungsten blank is very thin and entirely composed of open pores.", + "answer": "The mass fraction of silver after infiltration is wAg = (0.25 × 10.49) / (0.25 × 10.49 + 0.75 × 19.3) = 15.4%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及密度、质量分数等物理量的计算，答案也是通过具体计算得出的数值结果。 | 知识层次: 题目需要进行多步计算，涉及密度、质量分数等概念的综合应用，需要理解孔隙率和材料复合的原理，并进行适当的公式推导和数值计算。虽然不涉及复杂的推理分析或创新设计，但比简单的直接套用公式要复杂一些。 | 难度: 在选择题中属于中等偏上难度，需要理解多孔材料的密度计算、质量分数的概念，并进行多步骤的综合计算。题目涉及多个物理概念的关联应用，且计算过程需要一定的综合分析能力。" + }, + { + "idx": 2289, + "question": "A contact device is made of silver-tungsten composite material. Its production process involves first creating a porous tungsten powder metallurgy blank, then infiltrating pure silver into the pores. Before silver infiltration, the density of the tungsten compact is 14.5 g/cm³. Calculate the volume fraction of the pores. The density of pure tungsten is known to be 19.3 g/cm³. Assume the tungsten blank is very thin and all pores are open.", + "answer": "The pore density ρ_pore is obviously zero. Therefore, φ_pore = 1 - φ_tungsten = 1 - (ρc / ρ_tungsten) = 1 - (14.5 / 19.3) = 0.25", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解孔隙的体积分数，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的钨块密度和纯钨密度来计算孔隙的体积分数。虽然需要理解孔隙和材料密度的关系，但计算过程直接且步骤单一，属于简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。解题仅需应用一个基本公式（体积分数计算公式），且计算步骤简单直接（只需代入已知数值进行除法运算）。题目中所有必要参数均已明确给出，无需进行任何概念转换或额外推导，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 2290, + "question": "In randomly oriented short fiber composites, what is the relationship between the value of $\\\\frac{L_{\\\\mathrm{c}}}{L}$ and the number of pulled-out fibers and fractured fibers on the composite fracture surface? Please explain.", + "answer": "If the fiber strength variability is not significant, for a single ideal straight short fiber, the probability of fracture occurring at any location is equal. In the composite, for a segment of the composite with the same fiber length, the probability of fracture occurring at any location is also equal. The probability that the fracture occurs at a distance less than $L_{\\\\mathrm{c}}/2$ from the fiber end should be $L_{\\\\mathrm{c}}/L$ (where $L$ is the fiber length). When the fracture occurs at a distance less than $L_{\\\\mathrm{c}}/2$ from the fiber end, the fiber will not fracture but will instead be pulled out from the matrix. This probability is the same for any fiber. Therefore, $L_{\\\\mathrm{c}}/L$ represents the probability of fiber pull-out on the fracture surface of the short fiber composite, and $1-L_{\\\\mathrm{c}}/L$ represents the probability of fiber fracture on the fracture surface, meaning the number of fractured fibers is the total number of fibers on the fracture surface multiplied by $(1-L_{\\\\mathrm{c}}/L)$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释短纤维复合材料中$L_{\\mathrm{c}}/L$与拔出纤维和断裂纤维数量之间的关系，答案提供了详细的文字解释和论述，没有涉及计算、选择或判断对错。 | 知识层次: 题目要求解释短纤维复合材料中纤维拔出和断裂的关系，涉及概率分析、临界长度概念的理解以及复合材料断裂表面的分析。这需要综合运用多个概念，进行推理和机理解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解短纤维复合材料的断裂机理，包括纤维拔出和断裂的概率计算，以及临界长度（Lc）与纤维长度（L）比值的物理意义。解题需要综合运用材料力学、概率统计和复合材料原理，进行多步骤的推理分析。正确选项不仅解释了现象背后的机理，还涉及复杂的数学关系推导，对学生的知识深度和逻辑思维能力要求极高。在选择题型中，这类题目通常用于区分顶尖学生，因此难度等级为5。" + }, + { + "idx": 2291, + "question": "What is the role and mechanism of particle (granular) reinforcement?", + "answer": "Particle reinforcement: Hard particles with a diameter of 1~50 μm are added to the matrix. The particles can bear part of the load, but the matrix bears the main load. The particles restrict the deformation of the matrix through mechanical constraint. Properly sized and uniformly distributed particles can effectively strengthen the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释颗粒增强的作用和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释颗粒增强的作用和机制，涉及对颗粒与基体之间相互作用的深入理解，需要分析颗粒如何分担载荷、限制基体变形等机理，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解颗粒增强的基本概念，还需要掌握其作用机理（如机械约束、载荷分担等）。题目涉及对颗粒尺寸、分布和基体相互作用等复杂因素的综合分析，属于机理深度解释层次。虽然题目提供了正确选项，但需要考生具备较强的材料科学背景知识才能准确理解和判断。" + }, + { + "idx": 2292, + "question": "What role does the matrix play in composite materials?", + "answer": "The matrix primarily serves to fix and adhere the reinforcement, transferring the applied load to the reinforcement through the interface while also bearing a small portion of the load itself. The matrix acts like a separator, keeping the reinforcements apart. When some reinforcements are damaged or fractured, cracks are prevented from propagating from one reinforcement to another. During the processing and use of composite materials, the matrix also protects the reinforcements from chemical interactions with the environment and physical damage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对复合材料中基体的作用进行详细的文字解释和论述，而不是选择、判断或计算。答案提供了全面的描述，符合简答题的特征。 | 知识层次: 题目考查对复合材料中基体作用的基本概念的理解和记忆，属于基础知识的范畴，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项对复合材料中基体作用的描述较为详细，需要考生理解并记忆多个功能点（如固定增强材料、传递载荷、防止裂纹扩展、保护增强材料等）。这比简单的定义记忆（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2293, + "question": "Briefly describe the classification of different reinforcement particle sizes in composite materials and their strengthening mechanisms.", + "answer": "From the perspective of structural units and scales in composite materials, reinforcement particles with sizes of 1~50 μm are called particle-reinforced composites, those with sizes of 0.01~0.1 μm are called dispersion-strengthened composites, and those at submicron to nanometer scales are called fine composites, each with distinct strengthening mechanisms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述复合材料中不同增强颗粒尺寸的分类及其强化机制，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查复合材料中不同尺寸增强颗粒的分类及其强化机制的基本概念记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（粒子增强复合材料、弥散强化复合材料、精细复合材料）及其尺寸范围和强化机制，但正确选项已经将这些信息整合并清晰地呈现出来。考生需要理解并记忆这些分类和定义，但不需要进行复杂的分析或推理。因此，该题目在选择题型中属于概念解释和描述的难度等级。" + }, + { + "idx": 2294, + "question": "What role does the interface play in composite materials?", + "answer": "The interface serves to coordinate the deformation of the matrix and the reinforcement. Through the interface, the stress from the matrix can be transferred to the reinforcement. The matrix and reinforcement are bonded via the interface, but the bonding strength must be appropriate—neither too strong nor too weak. Excessive bonding strength can reduce the toughness of the composite material, while insufficient bonding strength fails to transfer stress effectively, making the interface prone to cracking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对复合材料中界面的作用进行文字解释和论述，答案提供了详细的描述和分析，符合简答题的特征。 | 知识层次: 题目考查对复合材料界面作用的综合理解，需要解释界面的功能、应力传递机制以及结合强度的影响，涉及多个概念的关联和综合分析。 | 难度: 在选择题型中，该题目要求考生不仅理解复合材料中界面的基本功能，还需要综合分析界面在应力传递、变形协调以及结合强度对材料性能的影响。题目涉及多个概念的关联（如应力传递、结合强度与韧性的关系），并要求考生在选项中进行多角度分析（如界面结合强度对材料性能的双重影响）。这种深度和广度的知识应用在选择题中属于较高难度，符合等级4的多角度分析论述标准。" + }, + { + "idx": 2295, + "question": "In a glass fiber reinforced nylon composite, the volume fraction of E-glass fiber is 0.3. The elastic moduli of E-glass and nylon are 72.4 GPa and 2.76 GPa, respectively. Calculate the fraction of the load borne by the fibers in the composite.", + "answer": "If the interface bonding is good, the strain of the composite under force should be equal to that of the matrix and the fibers, i.e., $$ \\\\varepsilon_{\\\\mathrm{c}}={\\\\frac{\\\\sigma_{\\\\mathrm{c}}}{E_{\\\\mathrm{c}}}}=\\\\varepsilon_{\\\\mathrm{m}}={\\\\frac{\\\\sigma_{\\\\mathrm{m}}}{E_{\\\\mathrm{m}}}}=\\\\varepsilon_{\\\\mathrm{f}}={\\\\frac{\\\\sigma_{\\\\mathrm{f}}}{E_{\\\\mathrm{f}}}} $$ Thus, $$ \\\\frac{\\\\sigma_{\\\\mathrm{f}}}{\\\\sigma_{\\\\mathrm{m}}}=\\\\frac{E_{\\\\mathrm{f}}}{E_{\\\\mathrm{m}}}=\\\\varepsilon_{\\\\mathrm{f}}=\\\\frac{72.4~\\\\mathrm{GPa}}{2.76~\\\\mathrm{GPa}}=26.25 $$ The fraction of the load borne by the fibers is $$ \\\\varphi=\\\\frac{\\\\sigma_{\\\\mathrm{f}}}{\\\\sigma_{\\\\mathrm{f}}+\\\\sigma_{\\\\mathrm{m}}}=\\\\frac{1}{1+\\\\frac{\\\\sigma_{\\\\mathrm{m}}}{\\\\sigma_{\\\\mathrm{f}}}}=\\\\frac{1}{1+\\\\frac{1}{26.25}}=0.96 $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及弹性模量和载荷分配的计算，答案也展示了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及复合材料中纤维和基体的弹性模量比较，以及载荷分配的计算。虽然公式相对直接，但需要理解应变相等的条件，并进行适当的代数变换来求解载荷分数。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料力学中的等应变假设，进行多步计算和概念关联。题目要求考生掌握弹性模量的定义、应力-应变关系以及复合材料载荷分配原理，并通过综合分析得出纤维承载比例。虽然题目提供了关键公式，但需要正确应用和转换多个变量关系才能得出最终答案。" + }, + { + "idx": 2296, + "question": "What is the role and mechanism of dispersion strengthening?", + "answer": "Dispersion strengthening: mainly applied to metal matrices, by adding hard particles such as Al2O3, TiC, SiC, etc., with particle sizes around 0.01~0.1μm. These particles dispersed in the metal or alloy can effectively hinder the movement of dislocations, providing significant strengthening effects, but the matrix remains the primary load-bearing component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释分散强化的作用和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释分散强化的定义和基本原理，还需要详细说明其作用机制（如阻碍位错运动）和实际应用（如添加特定颗粒），涉及多个概念的关联和综合分析，思维深度较高。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解分散强化的基本概念，还需要掌握其具体机制（如硬质颗粒如何阻碍位错运动）和应用条件（金属基体、颗粒尺寸范围等）。这需要考生具备材料强化机理的深入知识，并能将多个专业概念（位错理论、第二相强化、载荷传递机制）进行整合分析。虽然题目提供了正确选项，但选项内容本身涉及专业术语和机理描述，需要考生在选择题型内进行较高层次的认知加工。" + }, + { + "idx": 2297, + "question": "Given a hard alloy containing WC, TiC, TaC, and Co with mass fractions of 0.25, 0.15, 0.05, and 0.05, respectively. Their densities are $15.77\\\\mathrm{g/cm^{3}}, 4.94\\\\mathrm{g/cm^{3}}, 14.5\\\\mathrm{g/cm^{3}}, 8.9\\\\mathrm{g/cm^{3}}$. Calculate the density of this composite material.", + "answer": "The density can be calculated using $\\\\rho_{\\\\mathrm{c}}=\\\\rho_{\\\\mathrm{wc}}\\\\varphi_{\\\\mathrm{wc}}+\\\\rho_{\\\\mathrm{Tic}}\\\\varphi_{\\\\mathrm{Tic}}+\\\\rho_{\\\\mathrm{Tac}}\\\\varphi_{\\\\mathrm{TaC}}+\\\\rho_{\\\\mathrm{co}}\\\\varphi_{\\\\mathrm{co}}$. Convert the mass fractions to volume fractions, i.e., $$ $$ \\\\begin{array}{l}{\\\\displaystyle{\\\\varphi_{\\\\mathrm{\\\\tiny~\\\\mathrm{{TC}}}}=\\\\frac{\\\\frac{15}{4.94}}{8.70}=0.349}}\\\\ {~}\\\\ {\\\\displaystyle{\\\\varphi_{\\\\mathrm{\\\\tiny~\\\\mathrm{{Tac}}}}=\\\\frac{\\\\frac{5}{14.5}}{8.70}=0.040}}\\\\ {~}\\\\ {\\\\displaystyle{\\\\varphi_{\\\\mathrm{\\\\tiny~{co}}}=\\\\frac{\\\\frac{5}{8.90}}{8.70}=0.064}}\\\\end{array}$$ $$ \\\\rho\\\\mathrm{c}=\\\\sum\\\\rho_{i}\\\\varphi_{i}=11.5~\\\\mathrm{g/cm}^{3}$$ \\\\varphi\\\\mathrm{wc}={\\\\frac{\\\\frac{25}{15.77}}{{\\\\frac{25}{15.77}}+{\\\\frac{15}{4.94}}+{\\\\frac{5}{14.5}}+{\\\\frac{5}{8.9}}}}={\\\\frac{4.76}{8.70}}=0.547$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的质量分数和密度数据，应用公式计算复合材料的密度。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量分数到体积分数的转换，以及最终密度的综合计算。虽然不涉及复杂的推理分析或机理解释，但需要综合应用多个公式和概念，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料密度的计算原理，掌握质量分数与体积分数的转换方法，并进行多步骤的综合计算。题目涉及多个组分的密度和含量，计算过程较为复杂，但选项提供了明确的公式和步骤指引，降低了部分难度。" + }, + { + "idx": 2298, + "question": "What role does the reinforcement play in composite materials?", + "answer": "From the perspective that the reinforcement in structural composites mainly bears the load, it is generally required that the reinforcement has high strength and high modulus. The volume fraction of the reinforcement and its bonding performance with the matrix greatly influence the properties of the composite material. The combined action of the reinforcement, matrix, and interface can alter the toughness, fatigue resistance, creep resistance, impact resistance, and other properties of the composite material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释复合材料中增强体的作用，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对复合材料中增强体作用的基本概念的理解和记忆，涉及增强体的功能、要求及其对材料性能的影响，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解复合材料中增强体的作用及其对材料性能的影响，涉及多个基本概念（如强度、模量、体积分数、界面性能等）的综合描述。虽然不需要复杂的分析或推导，但需要对相关概念有清晰的理解和记忆，并能将这些概念联系起来解释增强体的作用。因此，该题目在选择题型中属于等级2（概念解释和描述）。" + }, + { + "idx": 2299, + "question": "Briefly describe the relationship between the size of composite material specimens and their strength.", + "answer": "The larger the composite material specimen, the higher the probability of defects, and the lower the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述复合材料试样尺寸与其强度之间的关系，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对复合材料尺寸与强度关系的基本概念的理解，属于基本原理的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解复合材料尺寸与强度之间的关系，并能够解释其中的基本原理（缺陷概率增加导致强度降低）。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 2300, + "question": "Briefly describe in which aspects the size effect of fiber-reinforced composites is manifested.", + "answer": "The fiber failure probability F(σ)=1-exp(-α lσ^β) and the average fiber strength σ̄=(αl)^(-1/β)𝒯(1+1/β) are both related to the fiber length l. The performance of fiber-reinforced composites is not only related to the fiber length but also to the fiber aspect ratio l/d, as well as the thickness of the composite plate. These are all manifestations of the size effect in composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述纤维增强复合材料尺寸效应的表现方面，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释纤维增强复合材料尺寸效应的表现方面，涉及纤维长度、长径比和复合材料板厚度等多个因素的关联分析。虽然不需要复杂的计算或深度推理，但需要综合理解和应用相关知识，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生理解纤维增强复合材料尺寸效应的多个方面，包括纤维失效概率、平均纤维强度与纤维长度的关系，以及纤维长径比和复合材料板厚度的影响。这需要考生不仅掌握相关公式，还要能够综合分析这些因素如何共同体现尺寸效应。这种多角度分析和概念关联的要求使得题目在选择题型中属于较难级别。" + }, + { + "idx": 2301, + "question": "What is the role and mechanism of fiber reinforcement?", + "answer": "Fiber reinforcement: 1) Continuous fiber reinforcement can be explained by the rule of mixtures, where the load and modulus are primarily determined by the fibers. Since the strength and modulus of the fibers are much higher than those of the matrix and exceed the critical fiber volume fraction, they provide reinforcement, and the interfacial bonding should be moderate. 2) In short fiber and whisker reinforced composites, the fiber length should be greater than the critical length, or the aspect ratio should exceed the critical value. The fibers are the main contributors to strength and modulus, as their strength and modulus are much higher than those of the matrix, and the interfacial bonding should be moderate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维增强的作用和机制，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释纤维增强的作用和机理，涉及连续纤维和短纤维/晶须增强的不同机制，需要综合运用材料科学中的复合材料原理、界面结合理论以及临界纤维长度等概念进行深入分析和解释。这超出了简单记忆或基本应用的范围，属于对复杂机理的综合理解和推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解纤维增强的机理，包括连续纤维和短纤维/晶须增强的不同机制，涉及临界纤维体积分数、临界长度、长径比等专业概念的综合运用。正确选项包含复合材料的载荷传递原理、界面结合要求等复杂分析，需要考生具备将材料力学原理与微观结构特征相结合的推理能力。这种在选择题中要求对复杂现象进行全面机理分析的题目，远超单纯记忆或简单应用层面，属于选择题型中的顶尖难度。" + }, + { + "idx": 2302, + "question": "What are the requirements for forming a composite, and can any two materials form a composite material after combination? What are the requirements for interfacial bonding strength?", + "answer": "To form a composite material, the two materials must establish a certain bonding strength at the interface. The interfacial bonding strength can generally be divided into physical bonding strength and chemical bonding strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释复合材料形成的条件以及界面结合强度的要求，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对复合材料形成条件和界面结合强度的基本概念的理解和记忆，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解复合材料形成的基本要求以及界面结合强度的分类，涉及基础概念的记忆和简单解释。虽然需要掌握多个知识点，但题目并未要求复杂的分析或比较，主要考察对定义和分类的记忆与理解。" + }, + { + "idx": 2303, + "question": "Explain the significance of the critical volume fraction", + "answer": "The significance of the critical volume fraction: when the fiber volume fraction is greater than the critical volume fraction, the strength of the composite material is higher than that of the matrix. When the fiber volume fraction is less than the critical volume fraction, the strength of the composite material is lower than that of the matrix, and no reinforcement effect is achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释临界体积分数的意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对临界体积分数这一基本概念的理解和记忆，解释其意义和影响，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等难度，需要理解临界体积分数的概念及其对复合材料强度的影响，并进行简单的比较分析。题目要求解释临界体积分数的意义，涉及基础概念的记忆和简单应用，但不需要复杂的推理或多概念整合。" + }, + { + "idx": 2304, + "question": "Compare the critical volume fractions of continuous fiber and short fiber reinforced composites", + "answer": "Continuous fiber: φ_Cr=(σ_mu−σ_m∗)/(σ_fu−σ_m), where σ_mu and σ_fu are the tensile strengths of the matrix and fiber, respectively; σ_m∗ is the stress borne by the matrix when the fiber reaches its fracture strain. Short fiber: φ_cr=(σ_mu−σ_m∗)/(σ_f−σ_m∗), where σ_f is the average stress of the fiber. Since σ_f is less than σ_fu, the critical volume fraction of short fibers is greater than that of continuous fibers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较连续纤维和短纤维增强复合材料的临界体积分数，答案提供了详细的公式解释和文字论述，而非简单的选择、判断或数值计算。 | 知识层次: 题目需要比较连续纤维和短纤维增强复合材料的临界体积分数，涉及多个公式的应用和概念关联。虽然题目提供了具体的公式，但需要理解各个参数的含义以及它们之间的关系，并进行综合分析。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生理解连续纤维和短纤维增强复合材料的临界体积分数计算公式，并能够比较两者的差异。题目涉及多个概念（如基体和纤维的拉伸强度、纤维断裂应变时的基体应力等）和计算步骤，要求考生具备较强的综合分析能力和概念关联能力。虽然题目提供了正确选项，但理解和比较的过程较为复杂，因此在选择题型中属于较高难度。" + }, + { + "idx": 2305, + "question": "Explain why in short-fiber composites with $LL_c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导一个关系表达式，涉及公式应用和数值计算，答案给出了具体的数学表达式和条件说明，符合计算题的特征。 | 知识层次: 题目要求推导随机取向短纤维复合材料中φ_min的关系表达式，涉及多步计算和概念关联（如σ_Lu、σ_fu、L_c等参数的相互关系），需要综合分析不同条件下的力学行为，并应用相关公式进行推导。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料强度理论中的关键概念（如临界纤维长度L_c、基体和纤维的强度贡献等），并能够正确关联和代入多步推导公式。虽然题目给出了正确选项，但需要考生具备综合分析能力来验证公式的正确性，涉及中等应用层次的知识点整合和计算步骤。" + }, + { + "idx": 2312, + "question": "What are the requirements for compounding? Can any two materials form a composite material after compounding? What are the requirements for dissolution and wetting bonding?", + "answer": "For dissolution and wetting bonding, the matrix must wet the reinforcement, and mutual diffusion and dissolution should occur to form a bond. For reaction bonding, the matrix and reinforcement should react to form favorable interfacial products, whose thickness must be controlled below a critical value.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对复合材料的复合要求、溶解和润湿结合的要求进行文字解释和论述，答案也是以文字形式详细解释相关概念和条件，符合简答题的特征。 | 知识层次: 题目要求解释复合材料的复合要求以及溶解和润湿结合的条件，涉及多个概念的关联和综合分析，需要理解材料之间的相互作用和界面行为，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目涉及复合材料制备中的多个关键概念（溶解润湿结合与反应结合），要求考生不仅理解界面润湿和扩散溶解的基本原理，还需要掌握界面产物厚度控制这一特定条件。正确选项整合了两种不同结合机制的要求，需要进行多角度对比分析才能准确判断。虽然不涉及计算，但需要对复合材料界面科学有较深入的理解才能正确作答。" + }, + { + "idx": 2313, + "question": "If unidirectional continuous fibers are unevenly distributed but all well-aligned in parallel, will it affect the elastic modulus? Please explain.", + "answer": "No effect. The modulus of the composite material $\\\\boldsymbol{E}_{\\\\mathrm{{L}}}=\\\\varphi_{\\\\mathrm{{f}}}\\\\boldsymbol{E}_{\\\\mathrm{{f}}}+\\\\varphi_{\\\\mathrm{{m}}}\\\\boldsymbol{E}_{\\\\mathrm{{m}}}$ varies linearly with the fiber volume percentage. Areas with dense fiber arrangement have a higher elastic modulus, while areas with sparse fiber arrangement have a lower elastic modulus. However, the linear relationship is additive, and the overall average modulus still equals the elastic modulus of a composite material with uniformly arranged fibers of the same volume fraction, meaning there is no effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释不均匀分布但平行排列的单向连续纤维是否会影响弹性模量，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目涉及复合材料弹性模量的计算和分布不均匀性的影响分析，需要理解弹性模量与纤维体积分数的线性关系，并能综合分析不同分布情况下的平均模量。虽然公式直接给出，但需要解释不均匀分布对整体模量的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解复合材料弹性模量的计算公式，并能够分析纤维分布不均匀但对整体模量的影响。题目涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2314, + "question": "In what aspects should matrix modification be considered to improve interface bonding?", + "answer": "Matrix modification", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在哪些方面应考虑基体改性以改善界面结合，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求从多个方面考虑基体改性以改善界面结合，这需要对材料科学中的界面相互作用、改性方法及其影响机理有深入的理解和综合分析能力。回答需要结合不同改性策略的优缺点、适用条件及其对界面性能的影响进行推理和解释，属于复杂分析和综合运用的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解\"matrix modification\"这一概念，还需要综合运用材料科学知识，分析界面结合的多个改进方面。这涉及到复杂现象的全面分析能力，包括材料改性机理、界面相互作用原理等深层次知识。选择题型中，此类题目需要考生在多个潜在正确选项中进行高阶推理和判断，远超出简单记忆或基础理解的范畴，属于材料科学选择题中最具挑战性的类型。" + }, + { + "idx": 2315, + "question": "When unidirectional continuous composites are subjected to longitudinal stress and the fibers fracture, what length will the fibers break into, and analyze why this type of fracture occurs.", + "answer": "The fibers will break into short segments with lengths of $L_{\\\\mathrm{c}}$ or $2L_{\\\\mathrm{c}}$. According to the shear-lag theory analysis, when the short fiber length is $L_{\\\\mathrm{c}}$, the maximum normal stress in the fiber can reach the fiber fracture stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维断裂的长度和原因，答案提供了理论分析和文字解释，没有涉及计算或选择选项。 | 知识层次: 题目不仅要求解释纤维断裂后的长度，还需要分析断裂机理（剪切滞后理论），涉及多概念关联和机理解释，思维深度达到分析推理层面。 | 难度: 在选择题型中，该题目属于最高难度等级。题目不仅要求考生掌握剪切滞后理论（shear-lag theory）的核心概念，还需要理解纤维断裂的临界长度（Lc）这一专业参数。正确选项涉及对复合材料断裂机理的深度解释（为什么断裂成特定长度）和复杂现象分析（应力传递与断裂的关联性）。考生需要综合运用材料力学、复合材料原理等多学科知识进行推理，这远超简单记忆或基础概念选择题的要求。在选择题型中，此类需要机理深度解释和复杂现象全面分析的题目属于最难类型。" + }, + { + "idx": 2316, + "question": "How to select reasonable composite processes and conditions for improving interface bonding?", + "answer": "Select reasonable composite processes and conditions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何选择合理的复合工艺和条件来改善界面结合，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求选择合理的复合工艺和条件以改善界面结合，这需要对不同复合工艺的原理、影响因素和界面结合机制有深入理解，并能进行综合分析、推理和优化选择。这超出了简单记忆或应用层次，需要综合运用多方面的知识进行复杂分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅需要掌握复合材料界面结合的基本原理，还需要综合运用材料科学、工艺学和界面工程等多学科知识，对复合工艺和条件的选择进行深度分析和推理。正确选项涉及复杂现象全面分析，需要考生具备机理深度解释能力和综合判断能力，这远超选择题型中常规的记忆或简单应用类题目。" + }, + { + "idx": 2317, + "question": "Derive the relational expression for φ_min in continuous fiber reinforced composites", + "answer": "For continuous fiber reinforcement, from σ_Lu=σ_fuφ_f+σ_m*(1-φ_f)=σ_mu(1-φ_f), we can obtain φ_min=φ_f=(σ_mu-σ_m*)/(σ_fu+σ_mu-σ_m*)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导连续纤维增强复合材料中φ_min的关系表达式，答案涉及公式推导和数值计算，符合计算题的特征。 | 知识层次: 题目要求推导连续纤维增强复合材料中φ_min的关系表达式，涉及多个变量的综合运用和公式推导，需要理解复合材料的基本原理并进行多步计算和概念关联。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和对材料性能的理解。 | 难度: 在选择题中属于中等偏上难度，需要理解连续纤维增强复合材料的强度理论，并能够将多个概念（纤维强度、基体强度、体积分数）关联起来进行综合分析。题目要求从给定的强度平衡方程推导最小纤维体积分数的表达式，涉及多步骤代数运算和变量替换，但选项已经提供了完整的推导结果，降低了计算过程的复杂度。" + }, + { + "idx": 2318, + "question": "What aspects should be considered for fiber surface modification to improve interfacial bonding?", + "answer": "Fiber surface modification", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述纤维表面改性应考虑的方面，答案需要文字描述而非选择、判断或计算 | 知识层次: 题目要求分析纤维表面改性的多个方面以改善界面结合，涉及综合运用不同知识（如表面化学、力学性能等）、推理分析改性方法的效果，以及解释其机理。这需要深入理解和关联多个概念，并进行综合分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握纤维表面改性的基本概念，还需要综合运用材料科学、界面化学和力学等多学科知识，深入理解改善界面结合的机理。正确选项涉及复杂现象全面分析，需要考生具备高阶推理能力和机理解释能力，远超简单记忆或基础理解的层次。在选择题型内，这类综合性强、分析深度高的题目属于最难的类别。" + }, + { + "idx": 2319, + "question": "In a Kevlar fiber-epoxy resin composite, the fiber volume fraction is 0.3, the density of epoxy resin is 1.25 g/cm³, and the density of Kevlar fiber is 1.44 g/cm³. Calculate the density of this composite material.", + "answer": "The density is ρ=1.31 g/cm³. Calculation process: ρ_L=1.25×0.7+1.44×0.3=1.3078 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算复合材料的密度），并给出了具体的计算过程和公式应用（ρ_L=1.25×0.7+1.44×0.3=1.3078 g/cm³）。答案也是一个具体的数值结果（1.31 g/cm³），符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需直接套用复合材料密度计算公式，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅要求应用简单的混合密度公式（ρ_L=ρ_1×V_1+ρ_2×V_2）进行计算，无需额外的概念理解或复杂步骤。学生只需正确代入给定的数值（纤维体积分数、树脂密度和纤维密度）即可得出答案。这种类型的题目在选择题中属于最基础的难度级别。" + }, + { + "idx": 2320, + "question": "Nickel is alloyed with Th having ${\\\\boldsymbol{w}}_{\\\\mathrm{Th}}$ of 0.01 to form an alloy, which is then made into powder, pressed into the desired shape, and sintered into the final product, during which Th is completely oxidized. Calculate the volume fraction of $\\\\mathrm{ThO}_{2}$ produced in this Th-Ni material. Given the density of $\\\\mathrm{ThO}_{2}$ is $9.86~\\\\mathrm{g/cm^{3}}$, Ni is $8.98~\\\\mathrm{g/cm}^{3}$, and Th is $11.72~\\\\mathrm{g/cm}^{3}$.", + "answer": "The volume fraction of $\\\\mathrm{ThO}_{2}$ is $0.0084 (0.84\\\\%)$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定体积分数，且答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括质量分数到质量的计算、氧化反应的质量转换、体积计算以及体积分数的综合计算。同时需要关联密度、质量守恒等概念，并进行综合分析。虽然不涉及复杂的机理或创新设计，但思维过程要求一定的深度和步骤间的逻辑关联。 | 难度: 在选择题中属于中等偏上难度，需要理解合金成分计算、氧化反应、密度转换等多个概念，并进行多步骤的综合计算。题目涉及质量分数转换为体积分数的过程，需要考生具备较强的综合分析能力和计算技巧。" + }, + { + "idx": 2321, + "question": "In a Kevlar fiber-epoxy resin composite, the fiber volume fraction is 0.3, the elastic modulus of the epoxy resin is 31 GPa, and the elastic modulus of the Kevlar fiber is 124 GPa. Calculate the modulus parallel to the fiber direction.", + "answer": "The modulus in the fiber direction is 58.9 GPa. Calculation process: E_T=0.3×124+0.7×31=58.9 GPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料在纤维方向的模量，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目考查基本公式的直接应用和简单计算，仅需套用复合材料模量的混合法则公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（混合法则）进行计算，无需复杂的分析或组合多个公式。解题步骤简单明了，属于最基础的难度等级。" + }, + { + "idx": 2323, + "question": "If manufacturing a continuous aluminum fiber cable with epoxy resin as the matrix and a volume fraction of 0.30, predict the electrical conductivity of the cable. The electrical conductivity of aluminum is $3.8\\\\times10^{7}~\\\\mathrm{S/m}$, and the electrical conductivity of epoxy resin is $10^{-11}~\\\\mathrm{S/m}$.", + "answer": "$1.14\\\\times10^{5}~\\\\mathrm{{S/m}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来预测电缆的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用（混合材料的电导率计算），只需要简单的数值代入和计算，无需多步推理或综合分析。 | 难度: 在选择题型内，该题目属于简单应用层次，需要基本公式应用和简单计算。题目直接给出了两种材料的电导率和体积分数，只需套用混合材料的电导率公式进行计算即可得出答案。虽然涉及公式应用，但步骤较为直接，不需要复杂的推导或多步骤计算，因此在选择题型中属于等级2难度。" + }, + { + "idx": 2324, + "question": "Why are most covalent solids low-density materials?", + "answer": "Most covalent solids have low packing density because the interatomic bonds are constrained by bond saturation and directionality.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么大多数共价固体是低密度材料，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释共价固体低密度的原因，涉及共价键的方向性和饱和性等复杂概念，需要综合运用材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解共价固体的基本性质，还需要深入分析键饱和性和方向性对堆积密度的影响机制。正确选项涉及对共价键特性的机理解释，需要综合运用材料科学知识进行推理分析，这超出了简单记忆或基础理解的范畴。在选择题型内，这类需要机理深度解释的题目通常属于难度等级4。" + }, + { + "idx": 2325, + "question": "According to solidification theory, how does adding a nucleating agent refine the grains of a casting?", + "answer": "After adding a nucleating agent, it can promote heterogeneous nucleation in the undercooled liquid. This not only increases the substrates required for heterogeneous nucleation but also reduces the critical nucleus radius, both of which will increase the number of nuclei, thereby refining the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释添加成核剂如何细化铸件晶粒，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释添加成核剂如何细化铸件晶粒的机理，涉及凝固理论中的异质成核、临界晶核半径等概念的综合运用和推理分析，需要深入理解并关联多个知识点进行解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解凝固理论的基本概念（如异质形核、临界晶核半径等），还需要综合运用这些知识分析成核剂对晶粒细化的影响机制。正确选项涉及多个关键步骤的推理（增加形核基底→降低临界晶核半径→增加形核数量→细化晶粒），且需要将热力学（临界半径）与动力学（形核率）因素结合分析。这种对复杂机理的深度解释和综合推理能力要求，远超选择题常见的概念识别或简单应用层次。" + }, + { + "idx": 2326, + "question": "In an aluminum specimen, the dislocation density within the grains was measured to be 2×10^12 m^−2. Assuming all dislocations are edge dislocations and are entirely concentrated at subgrain boundaries (i.e., low-angle grain boundaries), with their Burgers vector b=a/2⟨110⟩. If the cross-sections of the subgrain boundaries are all regular hexagons, and the tilt angle between subgrains is 2°, calculate the dislocation spacing at the subgrain boundary (given the lattice constant of aluminum a=0.404 nm).", + "answer": "The dislocation spacing D is calculated by the formula D = b / θ, where b is the Burgers vector and θ is the tilt angle. The Burgers vector b = (√2/2) × 0.404 nm = 0.286 nm. The tilt angle θ = 2° = 2 × (3.14/180) rad = 0.0349 rad. Therefore, D = 0.286 nm / 0.0349 = 8.188 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及具体的物理量（如Burgers向量、倾斜角度）和数学运算（如角度转换、除法运算），最终需要得出一个具体的数值结果（位错间距）。解答过程完全基于计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括Burgers向量的计算、角度转换以及最终应用公式计算位错间距。虽然涉及的概念和公式较为基础，但需要将这些知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解位错密度、柏氏矢量、小角度晶界等概念，并进行多步计算和单位转换。虽然题目提供了计算公式，但需要正确应用和综合多个知识点才能得出答案。" + }, + { + "idx": 2329, + "question": "Why are metals high-density materials?", + "answer": "The bonding in metal crystals has neither directionality nor saturation requirements, so atoms are packed as closely as possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属为何是高密度材料，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查金属晶体结构的基本概念和键合特性的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及金属晶体结构的基本概念，但需要考生理解金属键的无方向性和无饱和性特点，并能够将这些概念与材料密度联系起来。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。正确选项的解释性表述也增加了题目的难度层次。" + }, + { + "idx": 2330, + "question": "Both silver and aluminum have face-centered cubic lattices, and their atomic radii are very close, $r_{\\\\text{Ag}}=0.288\\\\mathrm{~nm}$ $r_{\\\\text{Al}}=0.286\\\\mathrm{nm}$, but they cannot form infinite solid solutions in the solid state. Explain the reason. (Northwestern Polytechnical University postgraduate entrance exam question)", + "answer": "For substitutional solid solutions, the solute and solvent having the same crystal structure type and similar atomic radii are necessary conditions for forming infinite solid solutions. However, the $15\\\\%$ rule indicates that when $|\\\\delta|>15\\\\%$, the solid solubility (mole fraction) becomes very small, showing that when the size factor is within a favorable range for forming infinite solid solutions, its importance becomes secondary, meaning the extent of solid solubility depends on other factors. Here, the valence factor is crucial. Because the valence of $\\\\text{Ag}$ is 1, while that of Al is 3, i.e., the solid solubility of a high-valence element as a solute in a low-valence element is greater than that of a low-valence element in a high-valence element. Therefore, silver and aluminum cannot form infinite solid solutions in the solid state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释银和铝不能形成无限固溶体的原因，需要文字解释和论述，答案也提供了详细的论述和理论依据，符合简答题的特征。 | 知识层次: 题目不仅需要理解面心立方晶格和原子半径对固溶体形成的影响，还需要分析价态因素对固溶度的作用机制。解答过程涉及多个概念的关联和综合分析，包括15%规则、价态效应等，需要较深入的推理和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2331, + "question": "According to solidification theory, how does increasing the undercooling ΔT refine the grain size of castings?", + "answer": "Increase the undercooling ΔT. As ΔT increases, both N and Vs increase, but the growth rate of N is greater than that of Vs. Therefore, the value of N/Vs increases, meaning z increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释增加过冷度ΔT如何细化铸件晶粒尺寸，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释过冷度ΔT如何细化铸件晶粒尺寸，涉及凝固理论中的成核速率N和生长速率Vs的变化关系，需要综合运用凝固理论的基本原理，进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2332, + "question": "According to solidification theory, how does vibration crystallization refine the grain size of castings?", + "answer": "Vibration crystallization, on one hand, provides the energy required for nucleation, and on the other hand, can break the growing crystals to form more crystallization nuclei, thereby refining the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动结晶如何细化铸件晶粒，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释振动结晶如何细化铸件晶粒的机理，涉及固体理论中的成核和晶体生长过程，需要综合运用多个概念进行推理分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解振动结晶的基本概念，还需要综合运用凝固理论中的成核和晶体生长机理，分析振动能量对晶粒细化的双重作用机制（提供成核能量和破碎晶体）。这需要考生具备将复杂现象分解为多个相互作用因素的能力，并能够解释其内在物理机制，属于典型的复杂现象全面分析层次。在选择题型中，这种需要多步骤推理和机理深度解释的题目对考生的知识整合能力和分析能力要求极高。" + }, + { + "idx": 2333, + "question": "Why are ionic solids medium-density materials?", + "answer": "The structural unit of an ionic crystal is an electrically neutral molecule composed of a set of positive and negative ions. The stacking of ions in ionic crystals must consider the role of electrical charge. In actual ionic crystals, the radii of positive and negative ions differ significantly. Generally, the negative ions are stacked in a cubic or hexagonal close-packed arrangement, while the smaller positive ions fill the gaps in this close-packed structure. This filling method of positive ions can uniformly separate the negative ions, increasing the distance between them so they no longer contact each other. Such a stacking structure can achieve higher packing density than covalently bonded crystals while satisfying the requirement of alternating arrangement of oppositely charged ions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么离子固体是中等密度材料，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释离子固体中等密度的原因，涉及离子晶体的结构单元、电荷作用、离子半径差异、堆积方式以及填充方式等多个概念的综合分析。需要深入理解离子晶体的结构特点，并能将这些概念关联起来进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解离子晶体的基本结构特征，还需要综合运用晶体堆积理论、离子半径差异的影响、电荷平衡原理等多重概念进行机理层面的深度解释。正确选项涉及复杂的空间堆积分析（立方/六方密堆积）、离子填充机制（间隙填充）以及静电作用对晶体密度的综合影响，这远远超出了选择题通常考查的单一知识点记忆或简单应用层面。考生必须能够将多个高阶概念整合推理，才能准确理解离子晶体中等密度的形成机制，这完全符合\"复杂现象全面分析\"的知识层次要求。" + }, + { + "idx": 2334, + "question": "What type of solid solution is formed when hydrogen atoms dissolve in aluminum?", + "answer": "The crystal structure of aluminum is fcc. From the appendix, the radius of the hydrogen atom is found to be rH=0.046nm, and the radius of the aluminum atom is rAl=0.143nm. The radius ratio rH/rAl=0.046/0.143=0.32.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释氢原子溶解在铝中形成的固溶体类型，答案提供了晶体结构、原子半径比等文字解释和论述，没有涉及选项选择、对错判断或具体数值计算。 | 知识层次: 题目需要应用基本的半径比计算来判断固溶体类型，属于直接套用基本公式和简单计算的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题中属于较低难度，题目仅要求简单应用基本公式进行计算（半径比计算），并直接套用已知数据（原子半径）。解题步骤简单直接，无需复杂分析或概念整合。" + }, + { + "idx": 2335, + "question": "Given that the recrystallization activation energy of a Cu-Zn alloy (w_Zn=0.30) is 250 kJ/mol, and this alloy takes 1 hour to complete recrystallization at a constant temperature of 400°C, how many hours does it take for this alloy to complete recrystallization at a constant temperature of 390°C? (Shanghai Jiao Tong University postgraduate entrance exam question)", + "answer": "Given T_1=400°C=673 K, t_1=1 h, T_2=390°C=663 K, Q=2.5×10^5 J/mol. Let the time required to complete recrystallization at 390°C be t_2, then from A e^(-Q/(R T_1 )) t_1=A e^(-Q/(R T_2 )) t_2, we get t_1/t_2=e^[-Q/R (1/T_2 -1/T_1 )]=e^[-2.5×10^5/8.31×(1/663-1/673)]=0.509. Therefore, t_2=1.96 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在390°C下完成再结晶所需的时间，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解再结晶激活能的概念，并能够正确应用阿伦尼乌斯公式进行计算。虽然计算过程较为直接，但需要将温度转换为开尔文温标，并进行指数运算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解并应用阿伦尼乌斯方程进行多步计算，涉及温度转换、指数运算和综合分析。虽然题目提供了所有必要参数，但解题过程需要较强的概念关联能力和计算技巧，属于综合性计算问题。" + }, + { + "idx": 2336, + "question": "Assuming the lattice constant of the alloy solid solution changes linearly with the increase of Zn atoms, and given the atomic radii of Cu and Zn are r_Cu=0.128nm and r_Zn=0.133nm respectively, find the average atomic radius r of the alloy with x_Zn=3%.", + "answer": "The average atomic radius r is r = r_Cu + (r_Zn - r_Cu) × 3% = 0.128 + (0.133 - 0.128) × 0.03 nm = 0.1282 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和参数（原子半径和百分比）来求解合金的平均原子半径。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，仅需将给定的原子半径和百分比代入线性关系公式即可得出结果，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的线性变化公式进行计算，属于单一公式直接计算的类型。解题步骤简单，无需复杂的推理或多步骤计算，符合等级1的难度标准。" + }, + { + "idx": 2337, + "question": "Given the diffusion constant of carbon in γ-Fe, D₀ = 2.0 × 10⁻⁵ m²·s⁻¹, and the activation energy for diffusion, Q = 1.4 × 10⁵ J/mol (R = 8.31 J/(mol·K)). Under the condition of a carbon potential Cₚ = 1.1% C, carburization of 20# steel is performed at 880°C. To achieve the same effect as carburizing at 927°C for 5 hours, how long should the carburization time be? (Huazhong University of Science and Technology postgraduate entrance exam question)", + "answer": "T₁ = 927°C = 1200 K. From D = D₀ exp(−Q/RT), we have D₁ = D₁₂₀₀ = 2.0 × 10⁻⁵ exp(−1.4 × 10⁵ / (8.31 × 1200)) = 1.6 × 10⁻¹¹ m²·s⁻¹. T₂ = 880°C = 1153 K. D₂ = D₁₁₅₃ = 2.0 × 10⁻⁵ exp(−1.4 × 10⁵ / (8.31 × 1153)) = 0.902 × 10⁻¹¹ m²·s⁻¹. Therefore, tₓ = (1.6 × 10⁻¹¹ × 5) / (0.902 × 10⁻¹¹) = 9 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散常数的计算和时间的转换，最终需要得出具体的时间数值。答案也是通过一系列计算步骤得出的具体数值，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散公式进行温度转换和扩散系数计算，并通过综合分析确定等效的渗碳时间。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解扩散常数、活化能、温度对扩散系数的影响等多个概念，并进行多步计算和综合分析。虽然题目提供了公式和参数，但需要正确应用阿伦尼乌斯方程计算不同温度下的扩散系数，并通过比例关系求解时间，涉及较为复杂的计算过程。" + }, + { + "idx": 2338, + "question": "Calculate the packing density of a crystal structure with a coordination number of 6 for a monoatomic substance", + "answer": "When the coordination number of a monoatomic substance is 6, it forms a simple cubic structure, where the atomic radius r1=a1×7. The packing density η=(1×(4/3)πr3)/a3=(4πa3)/(3×8×a3)=0.523", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算晶体的堆积密度，涉及数值计算和公式应用，答案也给出了具体的计算过程和结果。 | 知识层次: 题目涉及基本的晶体结构知识（简单立方结构）和简单的数学计算（原子半径与晶格参数的关系、堆积密度的公式应用），属于直接套用公式和进行一步计算的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解协调数为6对应的简单立方结构，并应用原子半径与晶格常数的关系，但整体解题步骤较为直接，仅涉及基本公式的套用和简单计算，无需多个公式的组合或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2339, + "question": "Where should hydrogen atoms be located in the aluminum lattice? Why?", + "answer": "The octahedral interstice is larger than the tetrahedral interstice, so hydrogen atoms reside in the octahedral interstice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释氢原子在铝晶格中的位置及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解铝晶格中氢原子的位置选择，涉及八面体间隙和四面体间隙的比较，需要将晶体结构知识与原子尺寸效应进行关联分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铝晶格中八面体间隙和四面体间隙的概念，并比较它们的尺寸大小。此外，还需要知道氢原子的尺寸与这些间隙的关系，综合分析得出氢原子应位于较大的八面体间隙。这涉及多步概念关联和综合分析，但不需要更深入的多角度分析或深度关联性分析。" + }, + { + "idx": 2340, + "question": "Calculate the ratio of the atomic radius when the coordination number of the elemental atom is 6 to that when the coordination number is 12.", + "answer": "Since the molar volumes are equal for coordination numbers 6 and 12, according to the packing density relation: η12Vmol=(4NAπr123)/3, η6Vmol=(4NAπr63)/3. Dividing the two equations gives: r6/r12=(η6/η12)1/3=(0.52/0.74)1/3=0.89", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及协调数与原子半径的关系，并需要理解摩尔体积相等的条件。虽然计算过程相对直接，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解原子半径与配位数的关系、摩尔体积的概念，并应用堆积密度公式进行多步计算。虽然题目提供了关键公式，但需要正确推导比例关系并代入数值计算，涉及多个概念的综合运用和数学处理能力。" + }, + { + "idx": 2341, + "question": "The measured lattice constant a=0.3795nm and density of 14.213g/cm^3 for the Cu-40%Au solid solution. Calculate and explain what type of solid solution this alloy is. The relative atomic mass of Au is found to be 196.97 from the appendix.", + "answer": "The average weight per atom A in the Cu-40%Au solid solution is (63.55×0.6+196.97×0.4)/(6.0238×10^23)g=1.941×10^-22g. The number of atoms per unit cell n is calculated as a^3×ρ/A=(0.3795×10^-7)^3×14.213/1.941×10^-22=4.002. Both Cu and Au have a face-centered cubic structure, with 4 atoms per unit cell. The calculation yields 4.002 atoms per unit cell, where the decimal is due to calculation and measurement errors, thus this is a substitutional solid solution.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（如计算平均原子重量、单位晶胞中的原子数等）并应用公式，最终通过计算结果解释合金类型。答案中包含详细的数学运算过程和结果分析，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括原子质量计算、晶胞原子数计算等），并需要将计算结果与晶体结构知识关联起来进行综合分析，以判断固溶体类型。这涉及对基础概念的理解和中等难度的应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求计算平均原子重量、单位晶胞中的原子数，并结合晶体结构知识判断固溶体类型。涉及多步计算和概念关联，但选项提供了明确的解题路径，减少了开放性思考的难度。" + }, + { + "idx": 2342, + "question": "The density of copper is 8.96g/cm^3, calculate the lattice constant and atomic radius of copper. The relative atomic mass of copper is found to be 63.55 from the appendix, and the Avogadro constant is 6.0238×10^23.", + "answer": "The mass of each Cu atom is A_Cu=63.55/(6.0238×10^23)g=10.55×10^-23g. Cu has an fcc structure, with each unit cell containing 4 atoms. Let the lattice constant of the unit cell be a, the mass of one unit cell is the mass of 4 Cu atoms, so a^3×ρ=4×A_Cu, i.e., a=(4×A_Cu/ρ)^1/3=(4×10.55×10^-23/8.96)^1/3cm=0.3611×10^-7cm=0.3611nm. The relationship between the atomic radius r and the lattice constant a in an fcc structure is r=a×√2/4, so the atomic radius of Cu is r_Cu=0.3611×√2/4nm=0.1277nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜的晶格常数和原子半径，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算（从密度计算晶格常数，再计算原子半径），需要理解面心立方结构的基本原理和公式应用，并能够正确关联不同概念（密度、晶格常数、原子半径）。虽然不涉及复杂的推理或创新，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方结构（fcc）的基本概念，掌握密度、晶格常数和原子半径之间的关系，并进行多步计算。虽然题目提供了所有必要的数据，但解题过程涉及单位换算、立方根计算以及几何关系的应用，对学生的综合计算能力和概念理解有一定要求。" + }, + { + "idx": 2343, + "question": "Given that the alloy is a face-centered cubic solid solution with an average atomic radius r=0.1282nm, find the average lattice constant a", + "answer": "The average lattice constant a is a = 4r / √2 = 4 × 0.1282 / √2 nm = 0.3625 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（a = 4r / √2）来求解平均晶格常数a，答案是一个具体的数值计算结果（0.3625 nm），符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接应用（面心立方晶格常数与原子半径的关系公式），计算过程简单，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（a = 4r / √2）进行计算，无需额外的概念理解或步骤组合。属于最基础的公式应用层级，符合等级1\"单一公式直接计算\"的定义。" + }, + { + "idx": 2344, + "question": "Given the relative atomic masses of Cu and Zn are 63.55 and 65.38 respectively, the Avogadro constant is 6.0238×10^23, and x_Zn=3%, find the average mass of component atoms A in the alloy solid solution.", + "answer": "The average mass of component atoms A is A = (63.55 × 0.97 + 65.38 × 0.03) / (6.0238 × 10^23) g = 10.56 × 10^-23 g", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及相对原子质量和阿伏伽德罗常数的计算，最终需要得出一个具体的数值结果。答案也是通过计算得出的具体数值。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的原子质量和百分比计算平均质量，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及相对原子质量和阿伏伽德罗常数的概念，但解题步骤较为直接，只需套用给定的公式进行简单计算即可得出答案。不需要复杂的推理或多步骤的公式组合，因此属于等级2难度。" + }, + { + "idx": 2345, + "question": "Given the lattice constant a=0.3625nm of a face-centered cubic solid solution and the average atomic mass A=10.56×10^-23g of the component atoms, calculate the theoretical density ρ of the alloy.", + "answer": "The theoretical density ρ is ρ = 4A / a^3 = 4 × 10.56 × 10^-23 / (0.3625 × 10^-7)^3 g·cm^-3 = 8.87 g·cm^-3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解理论密度ρ，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，只需套用密度计算公式即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（ρ = 4A / a^3）并进行简单的数值计算。不需要理解多个概念或进行复杂的分析，属于单一公式直接计算的难度等级。" + }, + { + "idx": 2346, + "question": "Based on the above calculation results, explain the relationship between the atomic radius and volume change when pure iron transforms from bcc to fcc structure at 17°C.", + "answer": "From the calculated results above, it can be seen that if the atomic radius remains unchanged before and after the transformation, the volume change after the transformation would be very large, which is inconsistent with the actual measured results and also contradicts the nature of metallic bonds. Therefore, for the same metal, the atomic radius of different structures should change to minimize the volume change as much as possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于计算结果解释原子半径与体积变化之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释原子半径与体积变化之间的关系，涉及晶体结构转变的机理分析，需要综合运用金属键性质、晶体结构知识以及实际测量结果的对比，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生基于计算结果，解释纯铁在17°C从bcc转变为fcc结构时原子半径与体积变化的关系。这需要考生：" + }, + { + "idx": 2347, + "question": "Pure iron transforms from bcc structure to fcc structure at 17°C, with a volume reduction of 1.06%. Calculate the relative change in atomic radius.", + "answer": "The relative change in atomic radius is (r_f - r_b)/r_b = 1 - 1/0.9758 = -2.47%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解原子半径的相对变化，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要理解bcc和fcc晶体结构的特点，应用体积变化与原子半径的关系进行多步计算，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构转变的概念，掌握体积变化与原子半径的关系，并进行多步计算。虽然题目提供了体积变化数据，但需要考生自行推导原子半径变化的计算公式，并正确执行计算步骤。这比单纯记忆概念或执行单步计算的选择题更为复杂，但尚未达到需要处理多变量或极端复杂计算的最高难度水平。" + }, + { + "idx": 2348, + "question": "Assuming the atomic radius remains unchanged before and after the transformation, calculate the volume change of pure iron when it transforms from bcc to fcc structure at 17°C.", + "answer": "Assuming the atomic radius remains unchanged before and after the transformation, the volume change after the transformation is (a_f^3 - 2a_b^3)/(2a_b^3) = ((4r_f/√2)^3 - 2(4r_b/√3)^3)/(2(4r_b/√3)^3) = ((4/√2)^3 - 2(4/√3)^3)/(2(4/√3)^3) = -8.196%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及原子半径、晶体结构转变和体积变化的计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及晶体结构参数（bcc和fcc的晶格常数与原子半径的关系）的转换和体积变化的计算，需要综合应用相关公式和概念，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构转变的概念，掌握bcc和fcc晶格常数与原子半径的关系，并进行多步计算和综合分析。虽然题目给出了计算步骤，但需要考生具备较强的空间想象能力和数学计算能力，才能正确理解并应用公式。" + }, + { + "idx": 2349, + "question": "Calculate the theoretical density of CsCl", + "answer": "The experimentally measured density is 3.99 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算CsCl的理论密度，需要应用相关公式和数值计算，答案给出了具体的数值结果。 | 知识层次: 题目要求计算CsCl的理论密度，这涉及基本公式的应用和简单计算，属于直接套用公式的范畴。虽然需要理解晶体结构和密度计算的基本原理，但不需要多步计算或综合分析，因此属于简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用密度计算公式，属于单一公式直接计算的简单应用。题目明确给出了实验测量值，无需额外推导或组合多个公式，解题步骤简单直接，符合等级1的难度标准。" + }, + { + "idx": 2350, + "question": "Pure iron transforms from bcc structure to fcc structure at 17°C, with a volume reduction of 1.06%. Calculate the atomic radius of the bcc structure based on the atomic radius of the fcc structure.", + "answer": "Let the lattice constant of the bcc structure be a_b, and the lattice constant of the fcc structure be a_f. When transforming from bcc to fcc, the volume reduces by 1.06%: since each bcc unit cell contains 2 atoms, and the fcc unit cell contains 4 atoms, 2 bcc unit cells transform into 1 fcc unit cell. Therefore, (a_f^3 - 2a_b^3)/(2a_b^3) = -1.06/100, solving for a_f = (2×(100 - 1.06)/100)^(1/3)×a_b = 1.255a_b. The atomic radius of the bcc structure r_b = √3a_b/4, and the atomic radius of the fcc structure r_f = √2a_f/4. Substituting a_f = 1.255a_b, we get r_b = (√3a_b)/4 = (√3a_f)/(4×1.255) = (√3×4r_f)/(4×1.255×√2) = 0.9758r_f.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的条件和公式进行数值计算，最终得出原子半径的具体数值。解答过程涉及多个步骤的数学运算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及bcc和fcc结构的转换关系、体积变化计算以及原子半径的推导，需要综合运用晶体结构知识和数学计算能力，但不需要进行复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构转变的概念，进行多步计算，并正确关联不同晶体结构的原子半径关系。题目涉及体积变化百分比的计算、晶格常数转换以及原子半径的推导，步骤较为复杂，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 2351, + "question": "Iron carbide Fe3C is an orthorhombic intermetallic compound with lattice constants of a=0.4514nm, b=0.5080nm, c=0.6734nm, and a density of 7.65g/cm³. Determine the number of iron and carbon atoms in the unit cell.", + "answer": "From the appendix, the atomic masses of Fe and C are found to be 55.85g/mol and 12g/mol, respectively. The mass of each Fe and C atom is A_Fe = [55.85/(6.023×10^23)]g = 9.273×10^-23g, A_C = [12/(6.023×10^23)]g = 1.992×10^-23g. The atomic ratio of Fe to C is 3:1. Assuming there are n C atoms in the unit cell, there should be 3n Fe atoms. The density of Fe3C is ρ_Fe3C = (n × A_Fe + 3n × A_C) / V_unit cell. Therefore, 7.65 = [(9.273 × 3n + 1.992n) × 10^-23] / [0.4514 × 10^-7 × 0.5080 × 10^-7 × 0.6734 × 10^-7] = [29.811 × 10^-23 × n] / [1.544 × 10^-22]. Solving for n gives n = [7.65 × 1.544 × 10^-22] / [29.811 × 10^-23] = 3.97. Thus, there are 4 C atoms and 3 × 4 = 12 Fe atoms in the unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞中的铁和碳原子数量，解答过程中涉及到了密度、晶格常数、原子质量等参数的计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括原子质量的计算、密度公式的应用、单位换算以及解方程求解原子数量。虽然涉及的概念和公式较为基础，但需要将这些知识点综合运用，并进行适当的数值计算和逻辑推理，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。需要掌握晶体结构、密度计算、原子质量换算等多个知识点，并进行多步骤的综合计算。解题过程涉及单位换算、代数方程求解等复杂操作，且需要准确关联多个概念。相比其他选择题，该题的解题步骤和思维复杂度显著更高，因此属于最高难度等级。" + }, + { + "idx": 2352, + "question": "Predict the crystal structure of CsCl", + "answer": "From the appendix, the electronegativities of Cs and Cl are found to be 0.82 and 3.16, respectively: the ionic radii are r(Cs+)=0.165 nm, r(Cl-)=0.181 nm. The electronegativity difference ΔEN=3.16-0.82=2.34, the ionic bond character is 75%, the covalent character is 25%, primarily ionic bonding. The ratio of anion radius to cation radius r(Cs+)/r(Cl-)=0.165/0.181=0.912. From the data given in Table 3-5 in the text, the cation should occupy the interstitial site at the center of a cube formed by the anions, corresponding to CN(Cl-)=8; the ratio of the number of anions to cations is 1:1, so CN(Cs+)=8. This crystal structure should be a simple cubic structure, with Cl- at the cube corners and Cs+ at the cube center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来预测CsCl的晶体结构，答案中包含了详细的推理过程和依据，没有涉及选择、判断或数值计算。 | 知识层次: 题目需要综合运用电负性、离子半径比、配位数等概念，通过多步计算和查表分析，最终确定晶体结构。虽然涉及多个知识点，但主要是基于已有规则和数据的直接应用，不需要复杂的推理或创新。 | 难度: 在选择题型内，该题目属于较高难度，需要考生进行多步计算（如电负性差、离子半径比）、概念关联（离子键与共价键比例、配位数判断）以及综合分析（晶体结构预测）。虽然题目提供了部分数据，但要求考生能够整合多个知识点并应用表格数据进行推理，这超出了基础记忆或简单计算的范畴，属于多角度分析论述的层次。" + }, + { + "idx": 2353, + "question": "Brass $(77,77)$ has a B2 structure, with a $z_{17}$ to $C11$ atomic ratio of 46:54. At $450-20=20$, if $900\\\\div\\\\cdots$ of the ($112$ 1/2, 1/2) positions are occupied by copper atoms, what percentage of the $(0,0,0)$ positions are occupied by copper atoms?", + "answer": "The stoichiometric composition of $C112.77$ is $5(\\\\angle17)=500^{\\\\circ}$. In the stoichiometric alloy, the ($112$, $117$, $112$) positions are entirely occupied by copper atoms, and the $(0,0,0)$ positions are entirely occupied by zinc atoms. Currently, the ratio of $217$ to $Cu$ atoms is $46:54$, and at $450-40$, $90\\\\%$ of the ($112$, 1/2, 1/2) positions are occupied by copper atoms. Thus, in the alloy, $\\\\sum11$ atoms have $0.5\\\\times0.0=4500$ located at the (1/2, 1/2, 1/2) positions. The remaining $0.54-0.45=0.00$ are located at the (0, 0, 0) positions, meaning $0.09/0.5=180\\\\dot{0}$ of the (0, 0, 0) positions are occupied by $c_{11}$ atoms. This can also be verified in the opposite direction. From the calculation results above, it shows that in the alloy, $z u$ atoms have $0.5-0.45=500$ located at the ($112$ 1/2, 1/2) positions and $0.5\\\\times(1-1).18)=410.0$ located at the (0, 0, 0) positions. Therefore, the content of $z_{1}$ in the alloy should be $0.41+0.05=4600$, which matches the given alloy composition.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目涉及复杂的数值计算和公式应用，需要根据给定的原子比例和位置占有率进行一系列数学运算来求解最终百分比。答案中展示了详细的计算步骤和验证过程，符合计算题的特征。 | 知识层次: 题目涉及复杂的晶体结构分析、原子位置占据率的计算、以及合金成分的推理验证。需要综合运用材料科学中的晶体学知识、化学计量学计算以及多步骤的逻辑推理。题目中的计算和验证过程较为复杂，涉及多个概念的综合应用和深度分析，超出了简单或中等应用的范围。 | 难度: 在选择题型内，该题目属于高难度综合计算题。题目涉及复杂的材料科学概念（如B2结构、原子位置占有率）、多步骤的化学计量计算（包括比例转换、百分比计算）以及需要综合运用多个知识点进行推理分析（如验证计算结果与给定合金成分的匹配性）。解题过程需要深入理解晶体结构和原子分布，并进行非直观的数学运算，远超选择题型的常规难度要求。正确选项的推导过程涉及多个逻辑层次和计算步骤，属于选择题型中最复杂的分析类型。" + }, + { + "idx": 2354, + "question": "(2) Calculate the theoretical density of CsCl.", + "answer": "First, calculate the lattice constant from the ionic radii. Since the crystal structure is simple cubic, the diagonal length of the cube should be the sum of the diameters of the negative and positive ions, i.e., equal to $2(0.181+0.165)\\\\mathrm{nm}=0.692$ nm. The diagonal length equals $\\\\sqrt{3}a$, so $a=0.692/\\\\sqrt{3}=0.3995$ nm. From the appendix, the relative atomic masses of Cl and Cs are $35.45$ and $132.91$, respectively. The mass of each Cl and Cs atom is $35.45/6.023\\\\times10^{23}=5.885\\\\times10^{-23}$ g and $132.91/6.023\\\\times10^{23}=2.207\\\\times10^{-22}$ g. A unit cell contains one Cl ion and one Cs ion, so the theoretical density of CsCl is $\\\\rho_{\\\\text{(CsCl)}}=\\\\frac{5.885\\\\times10^{-23}+2.207\\\\times10^{-22}}{(0.3995\\\\times10^{-7})^{3}}\\\\text{g/cm}^{3}=4.38\\\\text{g/cm}^{3}$. The calculated theoretical density is slightly higher than the experimentally measured density, possibly because the estimated lattice constant is smaller than the actual value.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解CsCl的理论密度，解答过程中涉及多个计算步骤和公式推导，最终得出具体数值结果。 | 知识层次: 题目需要进行多步计算，包括从离子半径计算晶格常数、利用相对原子质量计算单个原子的质量、结合单位晶胞中的原子数计算理论密度，并涉及简单的误差分析。虽然不涉及复杂的综合分析或创新应用，但需要多个概念和公式的关联应用，超出了简单直接套用的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、离子半径、晶格常数计算、相对原子质量转换、密度公式应用等多个概念，并进行多步骤的综合计算。虽然题目提供了完整的解题步骤，但在选择题型中需要考生快速识别关键计算点并验证结果，对知识掌握和计算能力要求较高。" + }, + { + "idx": 2355, + "question": "Calculate the packing density of the CsCl crystal structure (assuming ions are in contact along the body diagonal).", + "answer": "The CsCl crystal has a simple cubic structure. The radii of the Cs⁺ and Cl⁻ ions are r_Cs⁺ = 0.165 nm and r_Cl⁻ = 0.181 nm, respectively. Assuming the ions are in contact along the body diagonal, the diagonal length d = 2(r_Cs⁺ + r_Cl⁻) = 2(0.165 + 0.181) nm = 0.692 nm. The lattice constant a = d/√3 = 0.692 nm/√3 = 0.3995 nm. A unit cell contains one Cs⁺ ion and one Cl⁻ ion, so the packing density η_CsCl of the CsCl crystal structure is η_CsCl = [4π(r_Cs⁺³ + r_Cl⁻³)/3] / a³ = [4π(0.165³ + 0.181³)] / (3 × 0.3995³) = 0.685.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算离子半径、晶格常数和堆积密度等步骤，最终得出一个具体的数值结果。 | 知识层次: 题目涉及多步计算（离子半径求和、体对角线计算、晶格常数推导、堆积密度公式应用），需要理解CsCl晶体结构特征并正确关联各参数，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构的基本概念（如简单立方结构、离子半径、体对角线接触条件），并能够正确应用几何关系（体对角线与晶格常数的关系）进行多步计算。题目还要求综合运用体积公式和密度公式，涉及多个变量的代入和计算步骤，但整体思路清晰，属于典型的综合性计算问题。" + }, + { + "idx": 2356, + "question": "Why do commercial oxides such as windows and beverage glass require the addition of CaO to SiO2?", + "answer": "CaO cannot form a network in glass. Calcium ions have only one functionality, and Ca2+ has only two functionalities. When they are added to the SiO2 network and connected with oxygen ions, they inevitably break a primary bond of the network, reducing the density of primary bonds in the network and thereby lowering the glass transition temperature. For general wide-mouth bottles and window glass, which are used at low temperatures, they do not require an excessively high glass transition temperature Tg. A low Tg makes the product easier to handle and reduces costs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么商业氧化物如窗户和饮料玻璃需要添加CaO到SiO2中，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求解释CaO在商业氧化物玻璃中的作用机制，涉及网络形成体与非网络形成体的概念、玻璃结构的变化、玻璃转变温度的影响因素等多方面的知识。需要综合运用材料科学中的玻璃结构理论，进行推理分析，解释添加CaO如何降低玻璃的Tg，并联系实际应用需求。这超出了简单记忆或基本应用的层次，属于对知识的深度理解和综合分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解CaO和SiO2在玻璃网络结构中的基本作用，还需要深入分析钙离子的功能性和对玻璃网络结构的影响机制。正确选项涉及复杂的网络结构破坏机理、玻璃转变温度的影响因素以及实际应用中的工程考量。这种题目需要考生具备综合运用材料科学知识、进行推理分析和机理解释的能力，远超简单的概念记忆或单一知识点应用。在选择题型内，此类需要多维度分析和深度理解的题目属于最复杂的类型。" + }, + { + "idx": 2357, + "question": "Is the glass transition temperature of ordinary window glass above or below room temperature?", + "answer": "The glass transition temperature of ordinary window glass should be above room temperature. If it were below room temperature, the glass would remain in a liquid state at room temperature, albeit with high viscosity and some fluidity, meaning the atoms would still be delocalized. Consequently, it could not maintain a fixed shape at room temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断\"普通窗玻璃的玻璃化转变温度是否高于室温\"这一陈述的对错，答案给出了明确的判断和解释，符合判断题的特征。 | 知识层次: 题目考查对玻璃转变温度这一基本概念的记忆和理解，以及其在室温下的状态判断，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断普通窗玻璃的玻璃化转变温度是否高于室温，属于对基础概念的记忆性知识。正确选项直接给出了结论，不需要复杂的分析或推理过程，因此难度等级为1。" + }, + { + "idx": 2358, + "question": "What is the role of SiO2 in commercial oxide glasses?", + "answer": "SiO2 oxide satisfies Zachariasen's rules and can form a large-scale three-dimensional glass network, acting as the network former in glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释SiO2在商业氧化物玻璃中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对SiO2在商业氧化物玻璃中作用的基本概念记忆和理解，涉及Zachariasen规则和网络形成体的基本知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（SiO2在玻璃中的角色），但正确选项要求考生不仅知道SiO2是网络形成体，还需要理解Zachariasen规则和三维网络结构的概念。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 2359, + "question": "What is the relationship between functionality and the structural morphology of polymers?", + "answer": "If the functionality of a polymer monomer equals 2, the monomer can only form long molecular chains without branches, resulting in a linear structure. If the functionality equals 3 or is greater than 3, during polymerization, one functionality of a trifunctional monomer provides covalent cross-linking with another molecular chain, forming a network, which is a three-dimensional structure. Such a polymer is essentially a single molecule with an extremely large molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物功能性与结构形态之间的关系，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释聚合物功能性与结构形态之间的关系，涉及对功能性的理解、聚合反应机制的分析以及不同功能性导致的结构差异的综合论述。这需要将多个概念关联起来并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解聚合物功能性与结构形态的基本概念，还需要综合分析不同功能度（2 vs ≥3）对聚合物分子链形成的具体影响。正确选项涉及多步逻辑推理（从功能度推导链结构类型）和跨概念关联（共价交联与三维网络形成机制），这超出了单纯记忆或简单应用的范畴。此外，题目隐含了对\"功能度决定聚合物拓扑结构\"这一核心原理的深度理解，需在选项层面辨析线性结构与网络结构的形成条件，符合选择题型中\"多角度分析论述\"的等级4标准。" + }, + { + "idx": 2360, + "question": "Why are the atomic masses of Si and Al very close (28.09 and 26.98, respectively), while the densities of SiO2 and Al2O3 differ significantly (2.55 g/cm³ and 3.95 g/cm³, respectively)? Explain this difference using crystal structure and Pauling's rules.", + "answer": "The ionic radii of silicon, aluminum, and oxygen are r_Si4+=0.039 nm, r_Al3+=0.057 nm, and r_O2-=0.132 nm, respectively. The radius ratio of silicon to oxygen is 0.295, and that of aluminum to oxygen is 0.431. Therefore, silicon ions occupy the tetrahedral interstices of oxygen ions, while aluminum ions occupy the octahedral interstices of oxygen ions. Si is located at the center of an oxygen-coordinated tetrahedron with a coordination number (CN) of 4. Si is tetravalent, so the electrostatic bond strength S=4/4=1. O2- is divalent, i.e., Z-=2. According to Pauling's second rule, since Z-=∑S_i=2, the summation index i is 2, meaning each O2- at the tetrahedron vertex is shared by two tetrahedra. Thus, silicon-oxygen tetrahedra share all vertices, forming a three-dimensional framework structure of silicates. Because one oxygen ion is connected to only two silicon ions, such a low coordination number prevents SiO2 from achieving close packing, resulting in a generally open silicate structure. Al is located at the center of an oxygen-coordinated octahedron with a coordination number (CN) of 6. Al is trivalent, so the electrostatic bond strength S=3/6=0.5. O2- is divalent, i.e., Z-=2. According to Pauling's second rule, since Z-=∑S_i=2, the summation index i is 4, meaning each O2- at the octahedron vertex is shared by four octahedra. Because one oxygen ion is connected to four aluminum ions, close packing is possible. Oxygen ions are arranged in a hexagonal close-packed structure, with aluminum ions occupying the octahedral interstices. Since the number of atoms and octahedral interstices in a hexagonal close-packed structure are equal, 1/3 of the octahedral interstices remain unfilled. Because SiO2 has a relatively open structure and Al2O3 has a relatively close-packed structure, despite the very similar atomic masses of Si and Al, the densities of SiO2 and Al2O3 differ significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Si和Al的原子质量相近但SiO2和Al2O3密度差异显著的原因，答案提供了详细的文字解释和论述，涉及晶体结构和Pauling规则的应用，符合简答题的特征。 | 知识层次: 题目要求解释Si和Al原子质量相近但SiO2和Al2O3密度差异显著的原因，涉及晶体结构和Pauling规则的综合运用。需要分析离子半径比、配位数、静电键强度等概念，并关联到晶体结构的紧密程度，思维过程深度要求高，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用晶体结构、离子半径比、配位数、静电键强度以及Pauling规则等多个复杂概念，进行深入的机理分析和推理。正确选项不仅需要理解单个概念，还需要将这些概念有机结合起来，解释密度差异的根本原因。这种需要多步骤复杂推理和综合知识应用的题目，在选择题中属于最具挑战性的类型。" + }, + { + "idx": 2361, + "question": "How to compare the density difference between SiO2 and Al2O3 by calculating the packing density?", + "answer": "The relative atomic mass of SiO2 is 16. For SiO2, the mass of each SiO2 molecule is A_SiO2=(28.09+2×16)/(6.023×10^23) g=9.977×10^-23 g. The number of SiO2 molecules per cm³ is n_SiO2=ρ_SiO2/A_SiO2=2.55/9.977×10^-23=2.556×10^22 per cm³. The number of Si4+ and O2- ions per cm³ are n_Si4+=2.556×10^22 per cm³ and n_O2-=5.112×10^22 per cm³, respectively. The packing density of SiO2 is η_SiO2=(n_Si4+×4πr_Si4+^3/3 + n_O2-×4πr_O2-^3/3)/1=(4π/3)(2.556×0.039^3 + 5.112×0.132^3)×10^22×10^-21=0.577. For Al2O3, the mass of each Al2O3 molecule is A_Al2O3=(2×26.98+3×16)/(6.023×10^23) g=1.693×10^-22 g. The number of Al2O3 molecules per cm³ is n_Al2O3=ρ_Al2O3/A_Al2O3=3.95/1.693×10^-22=2.330×10^22 per cm³. The number of Al3+ and O2- ions per cm³ are n_Al3+=4.660×10^22 per cm³ and n_O2-=6.990×10^22 per cm³, respectively. The packing density of Al2O3 is η_Al2O3=(n_Al3+×4πr_Al3+^3/3 + n_O2-×4πr_O2-^3/3)/1=(4π/3)(4.660×0.057^3 + 6.990×0.132^3)×10^22×10^-21=0.714. Since η_Al2O3=0.714 is greater than η_SiO2=0.577, the density of Al2O3 is greater than that of SiO2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算SiO2和Al2O3的堆积密度来比较它们的密度差异，答案中包含了详细的数值计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算分子质量、分子数、离子数以及堆积密度，并进行综合分析比较。虽然不涉及复杂的推理分析或创新应用，但需要一定的理解和应用能力来正确执行这些步骤。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求通过计算堆积密度来比较SiO2和Al2O3的密度差异，涉及多个复杂的计算步骤和概念关联。具体包括：" + }, + { + "idx": 2362, + "question": "Is the glass transition temperature of rubber band polymers above or below room temperature?", + "answer": "The glass transition temperature of rubber band polymers is below room temperature. This is because rubber band polymers exhibit significant elasticity at room temperature; if they were in a glassy state at room temperature, they would not display elasticity but rather brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释橡胶带聚合物的玻璃化转变温度与室温的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对玻璃转变温度这一基本概念的记忆和理解，以及其在橡胶带聚合物中的具体表现。虽然需要一定的解释，但主要依赖于对基础概念的掌握，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察对玻璃化转变温度这一基础概念的记忆和理解，只需判断橡胶带聚合物在室温下的状态即可得出正确答案。不需要复杂的分析或概念间的联系，属于最基础的选择题难度等级。" + }, + { + "idx": 2363, + "question": "Why do commercial oxides such as windows and beverage glass require the addition of Na2O to SiO2?", + "answer": "Na2O cannot form a network in glass. Sodium ions have only one functionality, Na+ has only one functionality. When they are added to the SiO2 network and connected with oxygen ions, they inevitably break a primary bond of the network, reducing the density of primary bonds in the network and thereby lowering the glass transition temperature. For general wide-mouth bottles and window glass, which are used at low temperatures, they do not require an excessively high glass transition temperature Tg. A low Tg makes the products easier to handle and reduces costs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么商业氧化物如窗户和饮料玻璃需要添加Na2O到SiO2中，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释Na2O在商业氧化物玻璃中的作用机制，涉及网络形成体与非网络形成体的概念、玻璃结构的变化、玻璃转变温度的影响因素等多方面的知识。需要综合运用材料科学中的玻璃结构理论，分析Na2O的加入如何破坏SiO2网络结构，并解释其对玻璃性能的影响。这种题目不仅需要理解基本概念，还需要进行机理层面的推理和分析，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2364, + "question": "The copolymer contains PVC (polyvinyl chloride — $T_{2}H_{2}C-1-$) and PVA (polyvinyl alcohol —CHO—). The mass fraction of PVC is $1\\\\Psi_{\\\\mathrm{W}_{\\\\mathrm{E}}}=\\\\mathrm{B},5\\\\Psi_{\\\\mathrm{W}}$, and the mass fraction of PVA is $14^{\\\\circ}=15^{\\\\circ}$. Determine the mole fractions of PVC and PVA.", + "answer": "First, calculate the molar masses of PVC and PVA. The relative atomic mass of C is 12.0I, $\\\\mathsf{H}$ is 1.008, Cl is 35.45, and O is $16.00$. The molar mass of PVC is $(2\\\\times12+3\\\\times1+35.45)\\\\underline{{{\\\\mathrm{g}}}}/110|=62.45\\\\underline{{{\\\\mathrm{g}}}}/1101$. The molar mass of PVA is $(4\\\\times12+6\\\\times1+2\\\\times16)\\\\mathrm{g/mol}=86\\\\mathrm{g/mol}$. In $100\\\\underline{{\\\\underline{{\\\\mathbf{I}}}}}$ of the polymer, there are $85/62,45=1,36\\\\mathrm{PVC}$ moles and $15:80=0.174$ PVA moles. Therefore, the mole fraction of PVC in the polymer, Ac, and the mole fraction of PVC, $f^{\\\\prime}(x)$, are: $$ f_{\\\\mathrm{vc}}={\\\\frac{1.36}{1.36+0.174}}=0.887\\\\qquadf_{\\\\mathrm{vA}}={\\\\frac{0.174}{1.36+0.174}}=0.113$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算确定PVC和PVA的摩尔分数，涉及摩尔质量的计算和摩尔分数的推导，答案展示了具体的计算步骤和结果。 | 知识层次: 题目涉及多步计算，包括摩尔质量的计算、质量分数到摩尔分数的转换，以及最终的摩尔分数计算。虽然不涉及复杂的推理或综合分析，但需要理解和应用多个概念，并进行关联计算。 | 难度: 在选择题型中，该题目属于高难度等级。题目涉及多步计算过程，包括摩尔质量的计算、质量分数与摩尔分数的转换，以及最终的分数计算。此外，题目还要求对高分子化学中的基本概念有深入理解，如共聚物的组成和摩尔分数的定义。这些步骤和概念的综合运用使得该题目在选择题型中显得较为复杂和具有挑战性。" + }, + { + "idx": 2365, + "question": "A lightly cross-linked rubber band is stretched several times its original length and returns to its original length after the force is removed. If the stretched rubber band is placed below its glass transition temperature, what will happen to its length after the force is removed? Why?", + "answer": "When the stretched rubber band is placed below its glass transition temperature, it transitions into a glassy state. The glass transition causes the atoms to change from delocalized to localized (solidification), so it cannot return to its original length after the external force is removed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象并论述原因，答案需要文字解释和论述，没有提供选项或要求计算 | 知识层次: 题目要求分析橡胶带在玻璃化转变温度以下的行为变化，并解释其背后的机理。这需要综合运用材料科学中的高分子物理知识，理解玻璃化转变对材料性能的影响，以及橡胶弹性的基本原理。思维过程涉及多个概念的关联和深层次的理解，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2366, + "question": "In the copolymer of PVC vinyl chloride $(C_{2}H_{3}C)$ and PVA vinyl alcohol $(C_{4}H_{5}C)_{2}$, the ratio of vinyl chloride to vinyl alcohol is 10:1. If the average molar mass of the copolymer molecular chain is $\\lvert5000\\rvert\\lvert\\bar{\\mathbf{g}}/17\\rvert\\lvert\\bar{\\mathbf{U}}\\rvert$, find its degree of polymerization (DP).", + "answer": "First, calculate the molar mass of the repeating unit. In question 49, the molar masses of PVC and PVA were determined to be $\\bar{6}\\bar{2}.45\\bar{5}\\bar{5}^{\\prime}\\bar{1}710\\bar{1}$ and $86\\\\mathrm{g/mol}$, respectively. In this copolymer, the ratio of PVC to PVA is 10:1, so the molar mass of the repeating unit is $111$ $$\\\\begin{array}{l l}{{}}&{{M=\\\\displaystyle\\\\frac{10}{11}\\\\mathrm{PVC}\\\\mathrm{\\\\Ddot{H}^{\\\\sharp}J}\\\\frac{\\\\mathrm{s}\\\\mathrm{s}}{\\\\mathrm{1}}\\\\mathrm{s}^{\\\\prime}\\\\mathrm{H}\\\\overline{{{\\\\mathcal{T}}}}^{\\\\sharp}\\\\mathrm{IW}\\\\mathrm{E}\\\\mathrm{H}+\\\\displaystyle\\\\frac{1}{11}\\\\mathrm{PVA}\\\\mathrm{\\\\Ddot{H}^{\\\\sharp}}}}\\\\ {{}}&{{=\\\\displaystyle[\\\\frac{10}{11}\\\\mathrm{6}2.45+\\\\frac{1}{11}86]\\\\mathrm{g}/\\\\mathrm{mol}=\\\\mathrm{64.6}\\\\mathrm{g}/\\\\mathrm{mol}}}\\\\end{array}$$ The degree of polymerization (DP) of the copolymer is: DP = molar mass of the copolymer / molar mass of the repeating unit = 16000g/mol / 64.6g/mol = 248", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算摩尔质量和聚合度，最终得出一个具体的数值结果。答案中展示了详细的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算重复单元的摩尔质量（涉及PVC和PVA的摩尔质量及其比例），然后计算聚合度（DP）。这需要理解共聚物的组成和聚合度的概念，并进行综合计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及计算共聚物的平均摩尔质量和聚合度，需要掌握PVC和PVA的摩尔质量计算，以及根据比例计算重复单元的摩尔质量。解题步骤包括多个计算环节，但题目提供了部分中间结果，降低了部分计算难度。" + }, + { + "idx": 2367, + "question": "After washing and drying clothes containing artificial fibers, the clothes shrink. Please explain.", + "answer": "The fiber polymers in clothes made of artificial fibers are stretched and have a certain crystalline state. When the clothes are washed, the stretched state is removed, causing the polymer chains to return to a curled state. This is because the value of the curled state is greater than that of the stretched state, resulting in the clothes shrinking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释人工纤维衣物洗涤后缩水的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释人工纤维衣物洗涤后收缩的机理，涉及聚合物链的拉伸状态、结晶态变化以及能量状态比较等复杂概念。需要综合运用高分子材料学知识进行推理分析，解释现象背后的物理化学原理，属于机理层面的解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2369, + "question": "Calculate the equilibrium vacancy concentration in a Cu crystal at |000|.", + "answer": "The equilibrium vacancy concentration in metals is x_s = exp(ΔS_f / k_B) * exp(-ΔH_f / (k_B * T)).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铜晶体中的平衡空位浓度，答案给出了具体的计算公式，需要通过数值计算来得到结果。 | 知识层次: 题目要求应用给定的公式进行数值计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的平衡空位浓度公式进行计算，无需额外的公式组合或复杂推导。属于单一公式直接应用的简单题目，符合等级1的难度标准。" + }, + { + "idx": 2370, + "question": "A transparent PET film remains generally transparent when stretched slowly at room temperature. However, if stretched at $130^{\\circ}$, it becomes opaque. Why?", + "answer": "The glass transition temperature of PET (polyethylene terephthalate) is $10-C$. Stretching at $130^{\\circ}$, which is above the glass transition temperature, allows molecular chains to flow more easily. External stretching can promote polymer crystallization, and crystallization reduces transparency, with opacity increasing as crystallinity rises. However, slow stretching at room temperature (below the glass transition temperature) makes crystallization difficult for the polymer, so it retains its transparency.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么PET薄膜在不同温度下拉伸时透明度会发生变化，答案提供了详细的文字解释和论述，涉及材料科学中的玻璃化转变温度和结晶行为，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要解释PET薄膜在不同温度下拉伸时的透明度变化，涉及玻璃化转变温度、分子链流动、结晶行为等多个概念的关联和综合分析。解答过程需要理解材料在不同温度下的行为差异，并分析结晶对透明度的影响机制，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2371, + "question": "According to the $F E=F e=C$ phase diagram, calculate the relative amounts of phases in an iron-carbon alloy at room temperature under equilibrium conditions, where the mass fraction of carbon is $0.14$.", + "answer": "At room temperature, the equilibrium phases of the iron-carbon alloy are $\\alpha$-Fe (the mass fraction of carbon is $0.008$) and $Fe_3C$ (the mass fraction of carbon is $6.67$). Therefore, for an alloy with a mass fraction of carbon of $0.14$ at room temperature under equilibrium conditions, the relative amounts (mass fractions) of the $\\alpha$-Fe phase and the $Fe_3C$ phase are: $$ A^{\\alpha}=\\frac{6.67-0.14}{6.67-0.008}=98.62\\% \\qquad A^{Fe_3C}=1-98.62\\%=1.38\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的铁碳相图计算特定成分合金在室温下的相组成比例，解答过程涉及数值计算和杠杆定律的应用，答案以具体数值形式呈现。 | 知识层次: 题目主要考查对铁碳相图的基本理解和杠杆定律的简单应用，涉及单一条件下的质量分数计算，属于基本公式的直接套用和简单计算。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解铁碳相图的基本概念和杠杆定律的应用，但解题步骤相对直接，仅需套用一个公式进行计算。相比单一公式直接计算的题目（等级1），该题需要稍多的理解，但相比需要多个公式组合的题目（等级3）仍较为简单。" + }, + { + "idx": 2372, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the relative amount of eutectoid (pearlite) in an iron-carbon alloy with a carbon mass fraction of $0.14$ at room temperature under equilibrium conditions.", + "answer": "The microstructure of an alloy with a carbon mass fraction of $0.14$ at room temperature under equilibrium conditions consists of $\\\\alpha$-Fe and eutectoid (pearlite). The microstructure can be approximately considered the same as after the eutectoid transformation. At the eutectoid temperature, the carbon composition of $\\\\alpha$-Fe is $0.022$, and the carbon composition of the eutectoid structure is $0.76$. Therefore, the relative amount of eutectoid in the microstructure of an alloy with a carbon mass fraction of $0.14$ at room temperature is: $$ A^{P}=\\\\frac{0.14-0.022}{0.76-0.022}=10.58\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据铁碳相图计算特定碳质量分数合金中珠光体的相对含量，解答过程涉及数值计算和杠杆定律的应用，最终给出具体百分比结果。 | 知识层次: 题目需要进行多步计算，包括理解相图、应用杠杆定律计算相对量，并关联不同温度下的相组成。虽然不涉及复杂的机理分析或创新设计，但需要综合运用相图知识和计算技巧。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，掌握共析转变的相关知识，并进行多步骤的计算。虽然题目提供了关键数据（如碳含量），但考生仍需正确应用杠杆定律进行计算，并理解微观组织的组成。这要求考生具备一定的综合分析能力和计算能力，但相对于更复杂的多变量计算问题，此题的计算步骤较为直接。" + }, + { + "idx": 2373, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the percentage of cementite precipitated from all primary phases relative to the total system (the entire system) for an iron-carbon alloy with a carbon mass fraction of $3.6$ at the eutectoid temperature.", + "answer": "For an alloy with a carbon mass fraction of $3.6$ just after solidification, the relative amount of all phases (including primary phases and phases in the eutectic) is: $$ A^{\\\\Psi}=\\\\frac{6.67-3.6}{6.67-2.14}=67.77\\\\%$$ During the cooling process, the relative amount of $Fe_3C$ precipitated from the primary phases relative to the total system is: $$ A^{tFe_3C}=67.77\\\\% \\\\times 23.35\\\\%=15.82\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用相图和相关公式来求解渗碳体的百分比，答案也给出了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和相图分析，需要理解铁碳相图的基本原理，并应用杠杆定律进行两次计算（先计算初生相比例，再计算其中渗碳体析出比例），属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，掌握杠杆定律的应用，并能进行多步计算。题目要求计算从所有初生相中析出的渗碳体相对于整个系统的百分比，涉及多个步骤和概念的综合运用，但相比复杂多变量计算问题，其难度略低。" + }, + { + "idx": 2374, + "question": "Assuming an ionic crystal has monovalent cations and anions, with a cation vacancy formation energy of 2000, an anion vacancy formation energy of 101-1'tra01, and a cation interstitial formation energy of 30k=1,17701, calculate the relative concentration of Schottky defects.", + "answer": "The formation energy of a Schottky defect is the sum of the cation vacancy formation energy and the anion vacancy formation energy, which is (20+40) kJ/mol = 60 kJ/mol. The relative concentration of Schottky defects is exp(-60×10^3/RT). For example, at room temperature (300K), the above ratio equals 0.018.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Schottky缺陷的相对浓度），并给出了具体的能量值和计算公式（exp(-60×10^3/RT)），最终需要得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括理解Schottky缺陷的形成能计算和相对浓度的公式应用，涉及能量求和和指数计算，需要一定的综合分析能力。虽然公式直接给出，但需要正确理解和应用这些公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷的形成能计算概念，并正确应用公式进行多步计算（包括能量求和和指数运算）。虽然题目提供了部分计算示例，但仍需要考生掌握相关物理化学知识才能正确推导和验证选项。" + }, + { + "idx": 2375, + "question": "According to the $F E=F e=C$ phase diagram, calculate the relative amounts of phases in an iron-carbon alloy with a carbon mass fraction of $3.6$ under equilibrium conditions at room temperature.", + "answer": "At room temperature, the equilibrium phases of the iron-carbon alloy are $\\alpha$-Fe (carbon mass fraction is $0.008$) and $Fe_3C$ (carbon mass fraction is $6.67$). Therefore, for an alloy with a carbon mass fraction of $3.6$ under equilibrium conditions at room temperature, the relative amount (mass fraction) of the $\\alpha$-Fe phase and the relative amount of the $Fe_3C$ phase are: $$ A^{\\alpha}=\\frac{6.67-3.6}{6.67-0.008}=46.08\\% \\qquad A^{Fe_3C}=1-46.08\\%=53.92\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的铁碳相图计算特定成分合金在室温下的相比例，答案涉及具体的数值计算和公式应用（杠杆定律），属于典型的计算题类型。 | 知识层次: 题目需要理解铁碳相图的基本原理，应用杠杆定律进行多步计算，涉及相图分析和质量分数的综合计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，掌握杠杆定律的应用，并进行多步骤计算。虽然题目给出了具体数值和公式，但考生仍需正确识别相图中的相关相区，并准确应用杠杆定律进行计算。这比单纯记忆概念或进行单步计算的选择题要复杂，但比涉及多变量或动态分析的题目要简单。" + }, + { + "idx": 2376, + "question": "Assuming an ionic crystal has monovalent cations and anions, with a cation vacancy formation energy of 2000, anion vacancy formation energy of 101-1'tra01, and cation interstitial formation energy of 30k=1,17701, calculate the relative concentration of Frenkel defects.", + "answer": "The formation energy of Frenkel defects is the sum of the cation vacancy formation energy and the cation interstitial formation energy, which is (20+30) kJ/mol = 50 kJ/mol. The relative concentration of Frenkel defects is exp(-50×10^3/RT).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及能量计算和浓度计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要理解Frenkel缺陷的形成机制，并应用相关公式进行多步计算（包括能量求和和指数计算），涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及离子晶体中的缺陷形成能计算，需要综合运用Frenkel缺陷的概念，正确理解并计算形成能的总和，然后应用阿伦尼乌斯公式计算相对浓度。虽然计算步骤相对明确，但需要考生具备扎实的基础知识和对公式的正确理解。" + }, + { + "idx": 2377, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the percentage of the final transformed eutectoid in the eutectic structure relative to the total system for an iron-carbon alloy with a carbon mass fraction of $3.6$.", + "answer": "The percentage of phases in the eutectic structure is: $$ A_{6}^{7}=\\\\frac{6.67-4.3}{6.67-2.14}=52.3\\\\%$$ Therefore, the percentage of the final transformed eutectoid in the eutectic structure is: $$ A_{G}^{P}=67.6\\\\% \\\\times 52.3\\\\% \\\\times (1-23.35\\\\%)=27.1\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及相图分析和公式应用，需要理解相图的基本原理和计算方法，但不需要进行复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，进行多步计算，并综合分析不同相的比例关系。虽然题目提供了正确选项，但解题过程涉及多个步骤和概念关联，对学生的知识掌握和计算能力有一定要求。" + }, + { + "idx": 2379, + "question": "Can all parts of a dislocation loop be screw dislocations? Why?", + "answer": "The Burgers vector of a screw dislocation is parallel to the dislocation line. A single dislocation has only one Burgers vector, and a dislocation loop cannot be parallel to one direction everywhere. Therefore, a dislocation loop cannot have all its parts as screw dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么位错环的所有部分不能都是螺型位错，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对位错环的性质进行深入分析，涉及位错线的方向与Burgers矢量的关系，需要综合运用位错理论的基本概念进行推理和解释。这超出了简单记忆或直接应用的范畴，属于对材料科学中位错行为的复杂分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2380, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the relative amounts of the primary phase (austenite) and eutectic in an iron-carbon alloy with a carbon mass fraction of $3.6$ just after solidification is completed.", + "answer": "Just after solidification is completed, the carbon compositions of the primary phase and eutectic structure are $2.14$ and $4.3$ respectively. Therefore, the relative amounts of the primary phase and eutectic just after solidification are: $$ A^{\\\\gamma}=\\\\frac{4.3-3.6}{4.3-2.14}=32.4\\\\% \\\\qquad A^{0}=1-32.4\\\\%=67.6\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据相图进行数值计算，应用杠杆定律来求解各相的相对含量，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解相图、应用杠杆定律计算相对量，并涉及概念关联（如初生相和共晶组织的组成）。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来正确应用相图知识进行计算。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，掌握杠杆定律的应用，并进行多步计算。虽然题目提供了关键数值，但考生仍需正确识别相图中的关键点（如共晶点和初生相成分），并准确应用公式计算相对含量。这比单纯记忆或简单计算更复杂，但相比涉及多变量或更复杂相变的题目，其难度适中。" + }, + { + "idx": 2381, + "question": "MgO dissolves into Al2O3 to form a solid solution. Assuming Mg2+ replaces Al3+, write the reaction equation using Kroger-Vink notation.", + "answer": "2MgO forms 2MgAl' + V..O + 2OOX through Al2O3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Kroger-Vink符号写出反应方程式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求使用Kroger-Vink符号表示固溶体形成反应，这需要理解缺陷化学的基本原理和符号规则，并能够将其应用于具体反应中。虽然不涉及复杂的计算或综合分析，但需要将多个概念（如离子取代、缺陷形成）关联起来，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求使用Kroger-Vink符号表示反应方程，这需要学生对缺陷化学符号系统有深入理解。其次，题目涉及离子替代反应，需要学生掌握电荷平衡和缺陷补偿的概念。此外，解题过程需要多步推理：1) 识别Mg2+替代Al3+产生的缺陷类型；2) 确定电荷补偿机制；3) 正确应用Kroger-Vink符号表示所有缺陷和晶格位置。这种综合分析能力和多概念关联的要求，使该题在选择题型中属于较难水平。" + }, + { + "idx": 2382, + "question": "MgO dissolves into Al2O3 to form a solid solution, assuming the formation of cation interstitials. Write the reaction equation using Kroger-Vink notation.", + "answer": "3MgO forms 3Mg••i + 2V•Al + 3OO× through Al2O3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Kroger-Vink符号写出反应方程式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求使用Kroger-Vink符号表示固溶体形成反应，涉及缺陷化学的复杂概念和符号系统，需要深入理解缺陷反应机理和符号表示方法，并进行综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2383, + "question": "Assuming a monovalent cation and anion in an ionic crystal, the cation vacancy formation energy is 2000, the anion vacancy formation energy is 101-1'tra01, the cation interstitial formation energy is 30k=1,17701, calculate the concentration ratio of Schottky defects to Frenkel defects.", + "answer": "The concentration ratio of Schottky defects to Frenkel defects is exp(-60×10^3/RT)/exp(-50×10^3/RT)=exp(-10×10^3/RT). For example, at room temperature (300K), the above ratio equals 0.018.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Schottky缺陷与Frenkel缺陷的浓度比，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合应用Schottky缺陷和Frenkel缺陷的形成能公式，并进行浓度比的计算。虽然不涉及复杂的推理分析或机理解释，但需要理解和应用相关公式，并进行适当的数值计算。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及离子晶体中的缺陷形成能计算，需要掌握Schottky缺陷和Frenkel缺陷的概念，并能正确应用相关公式进行多步计算。虽然题目提供了部分数值，但需要考生能够正确理解并应用这些数值进行综合分析，最终得出正确的浓度比。此外，题目还要求考生能够理解温度对缺陷浓度的影响，并在特定温度下进行计算，这增加了题目的综合性和难度。" + }, + { + "idx": 2384, + "question": "At which temperature is the equilibrium vacancy concentration 10 times that at 1000K?", + "answer": "The ratio of vacancy concentrations at two different temperatures T1 and T2 is x_r(T2)/x_r(T1) = exp[-ΔH_f / k_B * (1/T2 - 1/T1)]. Let T1 = 1000K, and the vacancy concentration at T2 be 10 times that at T1, then ln10 = -ΔH_f / k_B * (1/T2 - 1/1000). 1/T2 = (1/1000 - k_B * ln10 / ΔH_f) K^-1. From textbook Table 6-1, ΔH_f for Cu is 1.22 eV, and k_B = 8.61×10^-5 eV·K^-1. Substituting these values into the equation gives 1/T2 = (1/1000 - 8.61×10^-5 * ln10 / 1.22) K^-1 = 8.375×10^-4 K^-1. Therefore, T2 = 1144 K. That is, the vacancy concentration at 1144 K is 10 times that at 1000 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及温度、空位浓度比、焓变等物理量的计算，最终得出具体的温度值。解答过程展示了详细的数学推导和代入计算步骤，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用公式进行数值计算，并结合具体材料参数（如铜的ΔH_f）进行综合分析。虽然不涉及复杂的推理分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如平衡空位浓度、温度关系、玻尔兹曼常数等）并进行多步骤计算。题目涉及从教材表格中查找数据、代入公式、对数运算和倒数计算等步骤，虽然计算过程明确但步骤较多且需要一定的综合分析能力。在选择题型内相比简单概念题或单步计算题更为复杂，但尚未达到复杂多变量计算的最高难度。" + }, + { + "idx": 2385, + "question": "Can all parts of a dislocation loop be edge dislocations? Why?", + "answer": "The Burgers vector of an edge dislocation is perpendicular to the dislocation line. If the Burgers vector is perpendicular to the plane of the dislocation loop, then every part of the dislocation loop is an edge dislocation. The slip plane of such a dislocation is the prismatic plane formed by the dislocation loop and the direction of the Burgers vector. This type of dislocation is also called a prismatic dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么位错环的所有部分都可以是刃位错，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对位错环的性质进行深入分析，涉及位错类型与伯格斯矢量的关系，以及位错滑移面的确定。需要综合运用位错理论的知识，进行推理和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解位错环和刃位错的基本概念，还需要综合运用Burgers矢量的方向性、位错线与滑移面的几何关系等知识进行推理分析。正确选项涉及复杂的机理解释（棱柱位错的形成）和空间几何关系的全面分析，这远超出选择题通常考查的记忆或简单应用层面，需要考生具备将多个高阶概念整合分析的能力。" + }, + { + "idx": 2386, + "question": "Explain how to use the method of measuring density to determine which reaction is correct when MgO dissolves into Al2O3 to form a solid solution", + "answer": "By experimentally measuring the crystal lattice constants, calculate the theoretical densities under two defect scenarios and compare them with the measured density. First, calculate the number of ions in the unit cell for each type of defect based on the solid solution concentration, then use the lattice constants obtained from X-ray experiments to calculate the densities for both cases. The defect mode corresponding to the theoretical density closest to the measured density is the correct one.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何使用密度测量方法来确定正确的反应，答案提供了详细的步骤和论述，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求通过实验测量和理论计算相结合的方法，分析两种缺陷情景下的密度差异，并与实测数据对比，从而确定正确的反应机制。这涉及多步计算、概念关联和综合分析，需要较高的推理分析和机理解释能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解密度测量方法的基本原理，还需要综合运用晶体结构、缺陷化学、X射线衍射数据分析等多个领域的知识。解题步骤复杂，涉及理论密度计算、缺陷场景分析、实验数据对比等高级技能。此外，题目要求考生在选择题型内进行机理深度解释和复杂现象全面分析，这远超过一般选择题的知识点掌握深度要求。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 2387, + "question": "In a simple cubic crystal, the Burgers vector of dislocation (2) is $b^{(2)}=a[0,10]$, and the tangent direction of the dislocation line is $l^{(2)}=[001]$. Identify the type of this dislocation and the slip plane of the dislocation. If the slip plane is not unique, explain the constraints on the slip plane.", + "answer": "For dislocation (2), since the Burgers vector is perpendicular to the dislocation line, it is an edge dislocation. The slip plane is the plane that contains both the Burgers vector and the dislocation line, so the slip plane of dislocation (2) should be the (100) plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来识别位错类型和滑移面，并解释滑移面的约束条件，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求识别位错类型并确定滑移面，需要理解位错的基本概念（如Burgers向量和位错线的关系），并应用这些概念来分析具体的晶体几何关系。虽然不涉及复杂的计算或多步骤推理，但需要对概念进行关联和综合分析，因此属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求识别位错类型和滑移面，涉及到位错线与柏氏矢量的关系、滑移面的确定等概念。虽然解题步骤相对明确，但需要综合应用晶体学和位错理论的知识，进行一定的推理和判断。" + }, + { + "idx": 2388, + "question": "The vacancy formation energy is 75 kJ/mol, and the crystal is quenched from 1000K to room temperature (approximately 300K). The Burgers vector h of the edge dislocation is about 0.25 nm. What is the osmotic force experienced by the dislocation?", + "answer": "When there is an unbalanced vacancy concentration, the chemical force per unit length on an edge dislocation is Fs=(kBT/h²)ln(x/x̄), where kB is the Boltzmann constant, T is the temperature, h is the Burgers vector, x is the actual vacancy concentration, and x̄ is the equilibrium vacancy concentration. The equilibrium vacancy concentration at different temperatures is x=exp(-Gf/kBT). Therefore, the vacancy concentrations at 1000K and 300K are exp(-Gf/1000kB) and exp(-Gf/300kB), respectively. The normal stress σs on the edge dislocation when the crystal is quenched from 1000K to 300K is σs=(kB300/h³)(Gf/R)(1/300-1/1000)=(300/(0.25×10⁻⁹)³)×(75000/6.02×10²³)(1/300-1/1000)Pa=5.43×10⁹Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括使用给定的参数（如空位形成能、温度、Burgers矢量）和物理公式（如化学力公式、平衡空位浓度公式）来求解位错所受的渗透力。答案中展示了详细的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解空位形成能、平衡空位浓度、位错的化学力等概念，并应用相关公式进行数值计算。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点进行计算。 | 难度: 在选择题中属于高难度，需要综合运用多个概念（空位形成能、平衡空位浓度、位错化学力等）并进行多步复杂计算。题目涉及温度变化对空位浓度的影响、不同温度下的平衡浓度计算、以及最终应力值的推导，计算过程中需要处理指数函数、单位换算和多个物理常数的整合。这种综合性问题在选择题型中属于复杂多变量计算类型，对学生的概念理解和计算能力要求较高。" + }, + { + "idx": 2389, + "question": "The vacancy formation energy is 75 kJ/mol, the crystal is quenched from 1000 K to room temperature (approximately 300 K), and the Burgers vector h of the edge dislocation is about 0.25 nm. Estimate whether the dislocation can climb.", + "answer": "The climb stress σs acting on the dislocation is 5.43×10⁹ Pa, which is close to the theoretical shear strength of general metals, so the dislocation will climb.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（估算位错能否攀移），并给出了具体的物理参数（空位形成能、温度变化、伯氏矢量等），最终答案是一个具体的计算结果（攀移应力值）。这符合计算题的特征，即需要应用公式和数值计算来解决问题。 | 知识层次: 题目需要应用多个概念（空位形成能、温度变化、Burgers矢量）并进行多步计算来评估位错攀移的可能性，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（空位形成能、位错攀移、应力计算等）并进行多步骤计算（包括温度转换、应力公式应用等）。虽然题目提供了部分参数，但仍需要综合运用材料科学知识来推导和判断位错攀移的可能性，接近理论剪切强度的比较也增加了分析复杂度。" + }, + { + "idx": 2390, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the relative amounts of phases in an iron-carbon alloy at room temperature under equilibrium conditions, where the mass fraction of carbon is $1.20$.", + "answer": "At room temperature, the equilibrium phases of the iron-carbon alloy are $\\alpha$-Fe (with a mass fraction of carbon of $0.008$) and $Fe_3C$ (with a mass fraction of carbon of $6.67$). Therefore, for an alloy with a mass fraction of carbon of $1.20$, the relative amounts (mass fractions) of the $\\alpha$-Fe phase and the $Fe_3C$ phase at room temperature under equilibrium conditions are: $$ A^{\\alpha}=\\frac{6.67-1.2}{6.67-0.008}=82.11\\% \\qquad A^{Fe_3C}=1-82.11\\%=17.89\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的铁碳相图计算特定成分合金中各相的相对含量，解答过程涉及数值计算和公式应用，最终给出具体的百分比结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图的理解和相成分的关联分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，掌握杠杆定律的应用，并进行多步骤计算。虽然题目提供了关键数据点（α-Fe和Fe3C的碳含量），但解题过程涉及多个计算步骤和概念关联，对学生的综合分析能力有一定要求。" + }, + { + "idx": 2392, + "question": "A face-centered cubic single crystal undergoes tensile deformation with the tensile axis along [001]. Determine the force on a dislocation with Burgers vector $b{=}a[\\overline{{\\textbf{\\vert}}}0\\mathbf{\\vert}]/2$ and line direction $t$ parallel to [121] in the slip direction. The lattice constant is given as $=0.35\\\\pi m$.", + "answer": "The force $F$ per unit length of the dislocation line in the slip plane is the product of the resolved shear stress $=5$ in the slip direction of the applied stress field and the Burgers vector $h$: $F_{n}=n+$. Under uniaxial tension (stress $(\\overline{o})$), $\\\\tau=\\\\sigma\\\\mathrm{cos}\\\\lambda\\\\cos\\\\varphi$, where $\\\\lambda$ is the angle between the tensile axis and the Burgers vector, and $11\\\\pi$ is the angle between the tensile axis and the normal to the slip plane. Since $b{=}a[\\overline{{\\textbf{l}}}()]\\\\backslash2$ and $t$ is parallel to [121], the slip plane is the plane containing both the Burgers vector and the dislocation line, hence the slip plane is (111). Therefore, 2 is the angle between [001]-[101], and $42$ is the angle between [001]-[111]. Using the crystallographic angle formula for cubic systems, $$\\\\cos\\\\lambda={\\\\frac{1}{\\\\sqrt{1}\\\\sqrt{1+1}}}={\\\\frac{1}{\\\\sqrt{2}}}\\\\qquad\\\\cos\\\\varphi={\\\\frac{1}{\\\\sqrt{1}\\\\sqrt{1+1+1}}}={\\\\frac{1}{\\\\sqrt{3}}}$$ Thus, $=\\\\sigma/\\\\sqrt{6}=0.408\\\\sigma$, and the magnitude of $11$ is $\\\\alpha\\\\sqrt{2}/2=0.36\\\\times10^{-9}\\\\times\\\\sqrt{2}/2=2.55\\\\times10^{-10}\\\\mathrm{m}$. Finally, $$ F_{\\\\mathrm{g}}=\\\\tau b=0.408\\\\times2.55\\\\times10^{-10}\\\\sigma\\\\mathrm{N}/\\\\mathrm{m}=1.04\\\\times10^{-10}\\\\sigma\\\\mathrm{N}/\\\\mathrm{m}$$ where the unit of $\\\\frac{1}{a^{2}}$ is $\\\\mathsf{P}_{\\\\perp}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定位错上的力，解答过程中涉及到了晶体学角度公式、应力分解和单位转换等计算步骤，最终给出了具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括确定滑移面、计算角度、应用晶体学公式、计算分解剪应力以及最终的力计算。虽然不需要复杂的推理分析或机理解释，但需要综合运用多个知识点进行中等难度的计算和分析。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。需要综合运用晶体学、位错理论、应力分析等多个知识点，并进行多步骤的计算推导。具体包括：" + }, + { + "idx": 2394, + "question": "In a crystal, there is a pair of parallel edge dislocations on the slip plane. How large should their spacing be to prevent movement due to their interaction? Assume the slip resistance (shear stress) of the dislocation is $\\\\square A^{\\\\prime\\\\prime}\\\\approx10^{5}Pa$, $1=0.3$, $G=5\\\\times10^{10}Pa$ (express the answer in terms of b).", + "answer": "Two parallel edge dislocations (denoted as A and B), with dislocation A located on the $\\\\underline{{\\\\underline{{\\\\pi}}}}$ axis of the coordinate frame. The force per unit length exerted by dislocation A on parallel dislocation B at position $(x,y)$ in the slip direction is F. Since both dislocations are on the same slip plane, the force is $F_{s}^{\\\\mathrm{A\\\\toB}}=\\\\frac{G b^{2}}{2\\\\pi(1-\\\\nu)}\\\\frac{1}{x}$ G²1, where x is the distance between the two dislocations. When this force equals or exceeds the resistance $\\\\cdot E_{1}b$ that the dislocation must overcome to slip, the two dislocations can slide. Therefore, when $$\\\\leq\\\\frac{\\\\vec{\\\\left(r\\\\right)}^{h}}{\\\\underline{{\\\\vec{2}\\\\pi(1-\\\\nu^{\\\\prime})}}}\\\\frac{1}{\\\\tau_{\\\\perp}}$$, the two dislocations will slide. That is, $$ \\\\displaystyle{x\\\\leq\\\\frac{G b}{2\\\\pi(1-\\\\nu)}\\\\frac{1}{\\\\tau_{\\\\mathrm{pe}}}}{=\\\\frac{5\\\\times10^{10}b}{2\\\\pi(1-0.3)}\\\\frac{1}{9.8\\\\times10^{5}}}{=1.16\\\\times10^{4}b}$$. If the two dislocations have the same sign, they will move toward each other until the distance between them is less than the calculated $^\\\\texttt{I}$ and then remain stationary. If the two dislocations have opposite signs, they will attract and annihilate each other when the distance between them is less than the calculated $x$. The two dislocations will remain stationary only if the distance between them is greater than $\\\\gamma^{-}$. The force in the climb direction is 0, so no climb will occur regardless of the distance between the two dislocations.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定两个平行刃位错之间的临界间距，以防止它们因相互作用而移动。解答过程中涉及到了具体的公式推导和数值代入计算，最终给出了一个具体的数值结果（1.16×10^4b），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错相互作用力的公式应用，并进行数值计算。虽然不需要复杂的推理分析或创新应用，但需要综合运用材料科学中的位错理论和力学知识来解决问题。 | 难度: 在选择题中属于中等偏上难度，需要理解位错相互作用的基本概念，掌握剪切应力与位错间距的关系，并进行多步计算。题目涉及平行刃位错在滑移面上的相互作用力计算，需要将理论公式与给定数值结合，最终推导出临界间距。虽然题目提供了部分公式，但仍需要考生综合运用材料力学和位错理论的知识来完成解答。" + }, + { + "idx": 2395, + "question": "If the resistance (shear stress) that dislocation slip needs to overcome is 9.8×10^5 Pa for copper, the shear modulus G of copper is 4×10^10 Pa, and the lattice constant is 0.55 nm. How thick is the low-dislocation-density layer on the surface of copper? It is known that copper has a face-centered cubic structure, and the Burgers vector length is 0.36/√2 nm = 0.255 nm.", + "answer": "Due to the effect of the surface image force, dislocations near the surface are subjected to the image force F_im. When the image force is greater than or equal to the dislocation slip resistance, the dislocation slips out of the surface, reducing the dislocation density on the surface. Taking a screw dislocation as an example, the image force F_im per unit length parallel to the surface is F_im = τ_in b = G b^2 / (4π d), where d is the distance of the dislocation from the surface. When F_im equals the dislocation slip resistance, the corresponding d is the thickness of the low-dislocation-density layer on the surface. Therefore, d ≤ G b / (4π τ_⊥). The thickness of the low-dislocation-density layer for copper is d = (4×10^10 × 0.255×10^-9) / (4π × 9.8×10^5) m = 8.28×10^-7 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解低位错密度层的厚度，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如表面镜像力、位错滑移阻力、剪切模量等），需要综合分析不同参数之间的关系，但不需要进行复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解表面镜像力、位错滑移阻力等概念，并进行多步计算（包括单位转换和公式代入）。虽然题目提供了关键公式，但需要考生正确关联概念并执行综合计算，属于典型的综合性计算问题。" + }, + { + "idx": 2396, + "question": "Assuming the resistance (shear stress) that dislocation slip needs to overcome is 1.5×10^8 Pa for 30-51=Fe alloy, the shear modulus G for 3% Si-Fe alloy is 3.5×10^11 Pa, and the lattice constant is 0.28 nm. How thick is the low-dislocation-density layer near the surface of the 3% Si-Fe alloy? It is known that iron-silicon alloy has a body-centered cubic structure, and the Burgers vector length is 0.28√3/2 nm = 0.242 nm.", + "answer": "Due to the effect of surface image force, dislocations near the surface are subjected to the image force F_im. When the image force is greater than or equal to the resistance to dislocation slip, the dislocation slips out of the surface, reducing the dislocation density near the surface. Taking a screw dislocation as an example, the image force F_im per unit length parallel to the surface is F_im = τ_in b = G b^2 / (4π d), where d is the distance of the dislocation from the surface. When F_im equals the resistance to dislocation slip, d represents the thickness of the low-dislocation-density layer near the surface. Therefore, d ≤ G b / (4π τ_⊥). The thickness of the low-dislocation-density layer for the iron-silicon alloy is d = (3.5×10^11 × 0.242×10^-9) / (4π × 1.5×10^8) m = 4.88×10^-8 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解低位错密度层的厚度，解答过程中涉及多个物理量的代入和计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如表面镜像力、位错滑移阻力等），但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于高难度，需要综合运用多个材料科学概念（如位错理论、表面镜像力、剪切模量等），进行多步骤计算（包括单位转换、公式推导和数值计算），并理解复杂物理现象（位错在近表面的行为）。题目涉及的知识点深度和计算复杂度明显高于普通选择题要求。" + }, + { + "idx": 2397, + "question": "A simple cubic crystal has a screw dislocation with $b=[001]$ on the (100) plane. An edge dislocation with $b=[010]$ on the (001) plane intersects with it. After the intersection, do kinks or jogs form on the two dislocations?", + "answer": "After the intersection of the two dislocations, a small segment of dislocation with the same magnitude and direction as the Burgers vector of the other dislocation is left on each dislocation. If this small segment lies on the slip plane of the original dislocation, it is a kink; otherwise, it is a jog. Let dislocation A be the screw dislocation with $b=[001]$ on the (100) plane, and dislocation B be the edge dislocation with $b=[010]$ on the (001) plane. After the intersection of dislocation A and dislocation B, dislocation A produces a small segment of dislocation in the [010] direction. The slip plane of dislocation A is (100), and [010]·[100]=0, meaning the small segment lies on the slip plane of dislocation A, so it is a kink. On dislocation B, a small segment of dislocation in the [001] direction is produced. The slip plane of dislocation B is (001), and [001]·[001]=1, meaning the small segment does not lie on the slip plane of dislocation B, so it is a jog.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来分析位错相交后形成的结构类型（kink或jog），需要详细说明判断依据和过程，属于需要文字解释的简答题类型。 | 知识层次: 题目涉及位错交互作用的复杂分析，需要理解位错的性质（如螺位错和刃位错）、柏氏矢量的方向、滑移面的确定，以及kink和jog的形成机制。解答过程需要综合运用这些概念进行推理和分析，判断位错交互后形成的缺陷类型，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目涉及复杂的位错相互作用分析，要求考生不仅掌握位错的基本概念（如螺位错、刃位错、伯格斯矢量、滑移面等），还需要深入理解位错相交后形成的kink和jog的机理。解题过程中需要综合运用向量点积判断位错段是否在滑移面上，并进行多步逻辑推理。这种题目在选择题型中属于对知识深度和综合分析能力要求极高的类型，需要考生具备扎实的理论基础和较强的空间想象能力。" + }, + { + "idx": 2398, + "question": "In a face-centered cubic crystal, there are two dislocations with their Burgers vectors $b$ and the planes on which they are gliding as follows: Dislocation A has $b^{[i]}=a[0]1]12$ and glides on the (111) plane; Dislocation B has $b^{(h)}=a[10\\overline{{1}}]/2$ and glides on the (111) plane. If the two dislocations are parallel, what are the tangent vectors of these two dislocations?", + "answer": "Since the (111) and (111) planes intersect, when the dislocations on these two planes are parallel to each other, the direction of the dislocation line can only be the line of intersection of the two planes. Using the zone law, it is easy to determine that the line of intersection of the (111) and (111) planes is [110], so the tangent vectors of the two dislocation lines are [110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定两个位错的切线向量，解答过程涉及晶体几何和位错理论的应用，需要详细的文字说明而非简单的选择或计算。 | 知识层次: 题目需要理解面心立方晶体中的位错性质，应用晶面相交的几何关系（区定律）来确定位错线的方向。这涉及多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 2400, + "question": "In a Ni single crystal, there is a dislocation with Burgers vector b=a[0]12 on the (11T) plane. The lattice constant a=0.35 nm. What is the length of the dislocation's Burgers vector?", + "answer": "Solution: The Ni crystal has an fcc structure, and the Burgers vector b is of the [110]/2 type. Therefore, the length of the Burgers vector is b=a√2/2=0.35√2/2=0.254 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算位错的Burgers矢量的长度，需要通过给定的晶格常数和Burgers矢量的类型进行数值计算，最终得出具体的数值结果。答案中展示了具体的计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式应用和简单计算，即通过已知的晶格常数和Burgers向量的类型直接套用公式计算其长度。虽然需要理解Burgers向量的类型和fcc结构的基本知识，但整体思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要知道fcc结构中Burgers vector的类型和计算公式，但解题步骤相对直接，仅需套用公式b=a√2/2并进行简单计算即可得出答案。不需要多个公式组合或复杂的概念分析，因此在选择题型内属于等级2难度。" + }, + { + "idx": 2401, + "question": "In a face-centered cubic crystal, there are two dislocations with their Burgers vectors $b$ and the planes they are gliding on as follows: Dislocation A has $b^{[i]}=a[0]1]12$ and glides on the (111) plane; Dislocation B has $b^{(h)}=a[10\\\\overline{{1}}]/2$ and glides on the (111) plane. Can they react when they meet during gliding? What is the Burgers vector of the resulting dislocation after the reaction? What is the glide plane?", + "answer": "If the two dislocations meet and react, the reaction equation is $${\\\\frac{a}{2}}[011]+{\\\\frac{a}{2}}[10{\\\\overline{{1}}}]\\\\rightarrow{\\\\frac{a}{2}}[110]$$. The sum of the squares of the Burgers vectors of the two dislocations before the reaction is $a^{2}/2+a^{2}/2=a^{2}$, and the square of the Burgers vector of the resulting dislocation after the reaction is $=2-17$. According to the Frank criterion, this reaction reduces energy, so the reaction can proceed. Since the direction of the resulting dislocation line is [110] and the Burgers vector direction is [110], its glide plane is (001).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两个位错相遇时是否会发生反应，并描述反应后位错的Burgers矢量和滑移面。答案提供了详细的文字解释和论述，包括反应方程、能量变化分析以及最终结论，符合简答题的特征。 | 知识层次: 题目涉及位错反应的能量判据（Frank准则）、位错线的方向与滑移面的关系等复杂概念的综合运用，需要深入理解位错反应机制并进行能量计算和几何分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2402, + "question": "In a face-centered cubic crystal, there are two dislocations with their Burgers vectors $b$ and the planes on which they are gliding as follows: Dislocation A has $b^{[i]}=a[0]1]12$ and glides on the (111) plane; Dislocation B has $b^{(h)}=a[10\\overline{{1}}]/2$ and glides on the (111) plane. Does the generation of such dislocations make them easier or more difficult to glide, and why?", + "answer": "The glide plane of the generated dislocation is not the original glide planes of the two dislocations, the (111) plane and the (111) plane, and its glide plane (001) is not the easiest glide plane for the fcc structure, so this dislocation is difficult to glide.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么生成的位错更容易或更难滑移，答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求分析面心立方晶体中位错的滑移行为，涉及位错的Burgers向量、滑移面以及位错反应后的滑移难易程度。需要综合运用位错理论、晶体结构知识以及滑移系选择原理进行推理分析，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2403, + "question": "The density of a crystal with NaCl-type structure is 3.55g/cm³, what should its Burgers vector be?", + "answer": "In NaCl-type structures, the common dislocation Burgers vector is of the <110>/2 type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释NaCl型晶体结构中常见的位错Burgers向量类型，答案提供了文字解释而非计算或选择。 | 知识层次: 题目需要理解NaCl型晶体结构的基本特征，并应用Burgers矢量的相关知识进行判断。虽然不涉及复杂的计算，但需要对晶体结构和位错理论有一定的理解和关联分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握NaCl型晶体结构的基本知识，并能够将密度与Burgers矢量的概念关联起来。虽然题目给出了密度值，但正确选项直接指向了Burgers矢量的类型，减少了计算步骤的复杂性。因此，在选择题型中，这属于需要中等应用能力的题目，涉及概念关联和综合分析，但不需要进行复杂的多步计算或深度关联性分析。" + }, + { + "idx": 2404, + "question": "The shear modulus of Ni is G=75 GPa, and the intrinsic stacking fault energy is γ=150 mJ/m². Calculate the equilibrium width of dislocation extension.", + "answer": "Since the perfect dislocation before decomposition is an edge dislocation, the equilibrium width d₀ of the extended dislocation is d₀=Gb²/(8πγ)×(2+ν)/(1−ν)=75×10⁹×(0.147×10⁻⁹)²/(8π×150×10⁻³)×(2+1/3)/(1−1/3) m=1.505×10⁻⁹ m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（equilibrium width of dislocation extension）。答案中展示了详细的公式应用和计算过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解剪切模量、堆垛层错能以及位错扩展平衡宽度的概念，并能够正确代入公式进行计算。虽然计算过程较为直接，但需要对相关物理概念和公式有一定的理解和应用能力。 | 难度: 在选择题中属于高难度，题目涉及多步骤计算和多个物理概念的关联应用（如剪切模量、堆垛层错能、位错扩展宽度公式），需要综合运用材料科学和力学知识进行复杂计算。此外，题目还要求对泊松比等参数有深入理解，并正确代入公式进行推导，这在选择题型中属于较高要求。" + }, + { + "idx": 2405, + "question": "Calculate the length of the Burgers vector for a NaCl-type structure crystal, given the lattice constant a=0.4151 nm.", + "answer": "The Burgers vector b=a√2/2=0.4151×√2/2 nm=0.2935 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers vector的长度），并给出了具体的计算公式和步骤，最终得出数值结果。 | 知识层次: 题目要求应用基本公式（Burgers vector的计算公式）进行简单计算，无需多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需直接套用单一公式（Burgers vector的计算公式）进行简单计算，无需多步骤推理或公式组合。题目明确给出了所有必要参数（晶格常数a），且计算过程仅涉及基本数学运算（乘法和开平方）。这种直接应用型题目在选择题中属于最低难度等级。" + }, + { + "idx": 2406, + "question": "If the dislocation is an edge dislocation, can it decompose into an extended dislocation? Write the decomposition reaction equation.", + "answer": "As long as the stacking fault energy is sufficiently low, any type of perfect dislocation on the {111} plane can decompose into an extended dislocation. If the given perfect dislocation decomposes into an extended dislocation, the reaction equation is a/2[101]→a/6[112]+a/6[21̅1]. This is because the decomposition into an extended dislocation involves the perfect dislocation splitting into two Shockley partial dislocations, whose Burgers vectors are of the a/6<112> type, with a Burgers vector length of b=a√6/6=0.35√6/6 nm=0.147 nm. Additionally, the slip planes of the dislocations before and after decomposition remain the original slip plane. Therefore, when writing the reaction equation, two points must be ensured: (1) the Burgers vectors of the two Shockley partial dislocations must lie on the (111) plane; (2) the Burgers vector must be conserved in the decomposition equation, meaning the Burgers vector of the dislocation before decomposition equals the sum of the Burgers vectors of the two dislocations after decomposition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释边缘位错是否可以分解为扩展位错，并写出分解反应方程。答案提供了详细的文字解释和论述，包括分解的条件、反应方程的具体形式以及相关的物理原理，符合简答题的特征。 | 知识层次: 题目不仅要求理解位错分解的基本原理，还需要应用Burgers矢量的守恒原则，进行具体的分解反应方程推导。这涉及到对位错类型、滑移面、堆垛层错能等概念的深入理解，以及综合分析能力，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2407, + "question": "Verify the correctness of the calculation: The radius of Mg²⁺ ion is 0.078 nm, the radius of O²⁻ ion is 0.132 nm, and the lattice constant of NaCl-type structure is the sum of the diameters of one cation and one anion.", + "answer": "The lattice constant a=2(0.078+0.132) nm=0.420 nm, which is basically consistent with the result of 0.4151 nm calculated based on density.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求验证计算的正确性，涉及数值计算和公式应用（离子半径和晶格常数的计算），答案也给出了具体的计算结果。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，仅需将给定的离子半径相加并乘以2得到晶格常数，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用给定的公式进行计算，无需理解多个概念或进行复杂的分析。题目明确给出了离子半径和计算公式，只需简单地将数值代入公式即可得出结果。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 2408, + "question": "After polishing and etching lithium fluoride polycrystals, etch pits arranged in straight lines with a spacing of 10μm were observed. After applying shear stress, grain boundary dislocations moved perpendicular to the grain boundary plane. Explain the structure of the grain boundary.", + "answer": "The crystal structure of lithium fluoride is a √3-1<1 type structure, and its slip plane is {0}11}. The etch pits reveal the outcrops of dislocations, and the straight-line arrangement of the etch pits indicates that this line is a set of parallel dislocation outcrops, which is a small-angle grain boundary with a dislocation spacing of 10μm. Since the grain boundary dislocations all move perpendicular to the boundary, it indicates that only a set of like-signed dislocations form the grain boundary, which can only be edge dislocations, and the slip plane of the dislocations is perpendicular to the grain boundary. Assuming the dislocation slip plane is (110), then the grain boundary plane is (110), and the Burgers vector of the dislocations can only be [1¯1¯1]¯1¯2. Therefore, this is a symmetric tilt grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶界的结构，答案提供了详细的文字解释和论述，涉及晶体结构、位错排列和晶界类型等内容，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释晶界的结构，涉及对位错、滑移面、晶界类型等概念的深入理解和综合分析。需要根据实验观察到的蚀刻坑排列和位错运动方向，推导出晶界的类型和结构，并进行合理的假设和推理。这需要综合运用材料科学中的位错理论和晶体学知识，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用晶体结构、位错理论、晶界类型等多个复杂概念，并进行深入的推理分析。解题步骤涉及多个层次的逻辑推导，包括从实验现象（蚀刻坑排列）推断位错结构，再结合应力响应行为确定晶界类型和位错性质。这需要考生不仅掌握相关知识点，还要具备将这些知识整合运用的能力，属于复杂现象的全面分析。" + }, + { + "idx": 2409, + "question": "Using the etch pit method, the distance between small-angle grain boundary etch pits was measured to be $[5,8][11]$. X-ray diffraction measured the misorientation between the two grains as 30 ($1\\\\because=0.000280$). What is the magnitude of the Burgers vector of the dislocations in the grain boundary?", + "answer": "Assuming the relationship between the dislocation spacing $n$, the Burgers vector $b$, and the misorientation in the grain boundary can be approximately estimated by the following formula: $$ D={\\\\frac{\\\\tilde{b}}{\\\\theta}} $$. Based on the given data, the Burgers vector $b$ is calculated as $$b=D\\\\pmb{\\\\theta}=6.87\\\\times10^{3}\\\\times30\\\\times0.0002\\\\&(\\\\pi/180)\\\\mathrm{nm}=1.00\\\\mathrm{nm}$$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出Burgers vector的具体数值。答案中包含了详细的公式应用和计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如Burgers向量、小角度晶界位错间距和取向差的关系），但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解小角度晶界、位错柏氏矢量、蚀刻坑间距与取向差的关系等多个概念，并正确应用公式进行多步计算。虽然题目提供了关键公式，但需要将给定的数据正确代入并进行单位转换（如弧度与度的转换），计算过程涉及多个步骤和概念的综合运用，对学生的知识掌握和计算能力要求较高。" + }, + { + "idx": 2410, + "question": "Given the density of a crystal with NaCl-type structure is 3.55 g/cm³, calculate its unit cell lattice constant. A unit cell contains 4 cations and 4 anions, the relative atomic mass of Mg is 24.31, and that of O is 16.", + "answer": "According to the density formula ρ=4(24.31+16)/(a³×6.022×10²³), solving for the lattice constant a=[4(24.31+16)/(3.55×6.022×10²³)]^(1/3) cm=4.151×10⁻⁸ cm=0.4151 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶格常数，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位换算和立方根求解，涉及晶体结构、原子质量和阿伏伽德罗常数等多个概念的关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度公式、单位换算等多个概念，并进行多步骤计算。虽然题目提供了公式和计算步骤，但需要考生具备综合分析能力和单位转换技巧，才能正确求解晶格常数。" + }, + { + "idx": 2411, + "question": "Based on the calculation results at 700°C and 550°C, find the average bonding energy between sulfur atoms and 12 iron atoms (express the answer in kJ/mol and eV).", + "answer": "Averaging over these two temperatures yields -ΔG=69 kJ/mol=0.71 eV. If it is approximately assumed that the distortion energy of sulfur atoms at grain boundaries is negligible, then this value can be considered as the bonding energy between sulfur atoms and Fe atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于计算结果找到硫原子与12个铁原子之间的平均键能，并需要以kJ/mol和eV为单位表达答案。解答过程涉及数值计算和单位转换，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（平均值的计算和单位转换），并涉及概念关联（将自由能变化与键能联系起来）。虽然计算过程不复杂，但需要理解热力学参数之间的关系，并做出合理假设（忽略晶界畸变能）。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解热力学计算（ΔG转换）、单位换算（kJ/mol与eV）以及材料键能概念的综合应用。题目要求考生能够将两个温度下的计算结果进行平均处理，并理解键能概念的物理意义，同时涉及能量单位的转换（1 eV ≈ 96.485 kJ/mol）。虽然题目提供了计算结果的直接选项，但需要考生具备将热力学数据与材料键能关联的能力，并判断假设条件（晶界畸变能忽略）对结果的影响，属于典型的多步骤综合分析问题。" + }, + { + "idx": 2412, + "question": "At 700°C (973K), the enrichment rate of sulfur at the grain boundaries of iron is 7170. Estimate the bonding energy between sulfur atoms and iron (answer in kJ/mol and eV).", + "answer": "Since the concentrations at the grain boundaries and within the grains are both much smaller than 1, the simplified formula for concentration segregation is used: -ΔG=8.314×973×ln7170=71.8 kJ/mol =71.8×10^3/(6.022×10^23×1.603×10^-19) eV=0.74 eV", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解硫原子与铁之间的键合能，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要进行多步计算（包括对数运算和单位转换），并需要理解浓度偏析的简化公式应用。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解浓度偏析的简化公式，并进行多步计算（包括单位转换和对数运算）。虽然题目提供了关键公式，但需要正确应用热力学常数和单位换算，涉及中等应用层次的知识点。" + }, + { + "idx": 2413, + "question": "At 550°C (823K), the enrichment rate of sulfur at the grain boundaries of γ-Fe is 15700. Estimate the bonding energy between sulfur atoms and iron (provide the answer in kJ/mol and eV).", + "answer": "Since the concentrations at both the grain boundaries and within the grains are much smaller than 1, the simplified formula for concentration segregation is used: -ΔG=8.314×823×ln15700=66.1 kJ/mol =66.1×10^3/(6.022×10^23×1.603×10^-19) eV=0.68 eV", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计硫原子与铁之间的键合能，并提供具体的数值答案（kJ/mol和eV）。解答过程中使用了物理常数和数学运算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括使用简化公式进行浓度偏析计算，并将结果从kJ/mol转换为eV。这需要理解相关概念并正确应用公式，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解浓度偏析的简化公式，并进行多步计算（包括单位转换和常数代入）。虽然题目提供了关键公式，但需要正确应用热力学常数和对数运算，同时涉及从kJ/mol到eV的能量单位转换，综合了概念理解和计算能力。" + }, + { + "idx": 2414, + "question": "A Cu (a=0.3615nm) thin film is deposited on an Au (a=0.4079nm) substrate, and their mismatch is relaxed by misfit dislocations at the interface. If the interface is the (100) plane, determine the magnitude of the Burgers vector of the misfit dislocations and the dislocation spacing.", + "answer": "If the (100) plane is taken as the interface, the two phases remain parallel to each other along the [110] direction at the interface, and their mismatch δ is still 0.121, so the spacing of the misfit dislocations is also 2.256nm. Since the grain boundary dislocations relax the mismatch along the [110] direction, the Burgers vector of the dislocations is [110]/2, and thus the dislocation line is along the [110] direction. There are two [110] directions on the (100) plane, so there are two sets of misfit dislocations on the interface, perpendicular to the [110] directions and mutually forming a 90° angle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定Burgers矢量和位错间距，答案提供了详细的解释和计算过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解晶格错配的概念，应用Burgers矢量的计算方法，并进行多步计算和综合分析，包括确定错配度、计算位错间距以及分析位错线的方向。这涉及到多个知识点的关联和综合运用，但不需要进行复杂的机理推理或创新设计。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 2415, + "question": "If the Burgers vector magnitude of a grain boundary dislocation is 0.253nm, what is the misorientation between the two sides of the grain boundary?", + "answer": "The misorientation between the two grains at the grain boundary is θ = b/D = (0.253 × 10^-9)/(10 × 10^-6) × (180/π) = 1.45 × 10^-3 degrees.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶界两侧的取向差，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的Burgers向量大小和晶界间距计算晶界两侧的取向差。虽然需要理解Burgers向量和晶界取向差的概念，但计算过程相对直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（θ = b/D）并进行简单计算，无需理解多个概念或进行复杂分析。属于最基础的难度等级。" + }, + { + "idx": 2417, + "question": "Consider a two-dimensional rectangular crystal with side lengths $L_{1}$ and $L_{\\\\pm}$ $L_{1}$ and $L_{\\\\perp}$. The interfacial energies for the two sides are $71$ and p, respectively. If the interfacial area remains constant ($L_{1}L_{1}=$ constant), prove that the equilibrium shape satisfies the relation $L_{1}/L_{2}=m g/y_{2}$.", + "answer": "The total surface energy of this crystal is $E=2(L_{1}y+L_{2}y_{2})$. At equilibrium shape, the following relation holds: $$ \\\\mathrm{d}E=2(L_{1}\\\\mathrm{d}\\\\gamma_{1}+\\\\gamma_{1}\\\\mathrm{d}L_{1}+L_{2}\\\\mathrm{d}\\\\gamma_{2}+\\\\gamma_{2}\\\\mathrm{d}L_{2})=0 $$ Since $72$ and $79$ are independent of length, the equation simplifies to $$ \\\\gamma_{1}\\\\mathrm{d}L_{1}+\\\\gamma_{1}\\\\mathrm{d}L_{2}=0 $$ Given that the area $[1L]=$ constant, i.e., $\\\\angle1\\\\mathrm{d}L_{2}+L_{2}\\\\mathrm{d}L_{1}=0$, substituting this relation into the above equation yields $L_{1}:L_{2}=m:21$. Q.E.D.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数学推导和公式应用来证明一个关系式，解答过程涉及微分和代数运算，属于典型的计算题类型。 | 知识层次: 题目涉及多步计算和概念关联，需要应用表面能的概念和平衡条件，并通过微分和代数运算推导出平衡形状的关系。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在选择题中属于高难度，题目涉及多变量计算和综合分析。需要理解晶体平衡形状的概念，掌握表面能的计算方法，并能正确应用微分和约束条件进行推导。解题步骤包括建立能量表达式、微分处理、代入约束条件等多个复杂步骤，对学生的综合能力要求较高。" + }, + { + "idx": 2418, + "question": "Two parallel low-angle tilt boundaries have misorientation angles of 6 and degrees, respectively. Is it possible for these two boundaries to merge into a single boundary with a misorientation angle of $\\\\theta_{1}+\\\\theta_{2}$?", + "answer": "The energy of a low-angle grain boundary is $$ \\\\gamma_{_\\\\mathrm{\\\\scriptsize{ab}}}=\\\\gamma_{_0}\\\\theta(\\\\mathcal{A}^{\\\\mathrm{\\\\scriptsize{r}}}-\\\\ln\\\\theta) $$ where $M^{\\\\prime}$ is a constant. The energy before the merging of the two boundaries is $$ \\\\gamma_{\\\\bar{0}}\\\\theta_{\\\\bar{1}}(A^{\\\\prime}-\\\\ln\\\\theta_{1})+\\\\gamma_{\\\\bar{0}}\\\\theta_{\\\\bar{z}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\bar{z}}) $$ The energy after merging is: $$ \\\\gamma_{\\\\mathrm{o}}(\\\\theta_{\\\\mathrm{i}}+\\\\theta_{\\\\mathrm{z}})[A^{\\\\prime}-\\\\mathrm{ln}(\\\\theta_{\\\\mathrm{i}}+\\\\theta_{\\\\mathrm{z}})] $$ The energy difference $\\\\bar{A}E$ before and after merging is: $$ \\\\begin{array}{r l}&{\\\\Delta E=\\\\gamma_{\\\\mathrm{0}}(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})[A^{\\\\prime}-\\\\ln(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})]-\\\\gamma_{\\\\mathrm{0}}\\\\theta_{\\\\mathrm{1}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\mathrm{1}})-\\\\gamma_{\\\\mathrm{0}}\\\\theta_{\\\\mathrm{2}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\mathrm{2}})} &{\\\\qquad=\\\\gamma_{\\\\mathrm{0}}A^{\\\\prime}(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}-\\\\theta_{\\\\mathrm{1}}-\\\\theta_{\\\\mathrm{2}})-\\\\gamma_{\\\\mathrm{0}}[(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})\\\\ln(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})-\\\\theta_{\\\\mathrm{1}}\\\\ln\\\\theta_{\\\\mathrm{1}}-\\\\theta_{\\\\mathrm{2}}\\\\ln\\\\theta_{\\\\mathrm{2}}]} &{\\\\qquad=\\\\gamma_{\\\\mathrm{0}}[\\\\theta_{\\\\mathrm{1}}\\\\ln\\\\frac{\\\\theta_{\\\\mathrm{1}}}{\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}}+\\\\theta_{\\\\mathrm{2}}\\\\ln\\\\frac{\\\\theta_{\\\\mathrm{2}}}{\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}}]}\\\\end{array} $$ Because $y=\\\\frac{1}{2}$ $C A$ and $C H_{2}$ are both positive, $\\\\left|\\\\Pi\\\\right|\\\\left|\\\\hat{H}_{l}\\\\right|\\\\left|\\\\hat{H}_{1}+\\\\hat{H}_{2}\\\\right|\\\\right|$ and $\\\\|\\\\bar{\\\\boldsymbol{\\\\Pi}}\\\\|\\\\hat{\\\\cal{Q}}^{\\\\prime}(\\\\hat{\\\\cal{Q}}_{1}+\\\\hat{\\\\cal{Q}}_{2})\\\\|$ are both less than 0. This process reduces energy, so it can proceed. In fact, during the recovery process of deformed materials, a large number of such processes occur, namely the coarsening of subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案中包含了详细的公式推导和能量变化的分析，属于需要论述和解释的简答题类型。 | 知识层次: 题目涉及低角度晶界的能量计算和合并过程的能量变化分析，需要综合运用晶界能量公式、对数运算和能量差计算，并进行机理解释。思维过程要求较高的分析能力和对材料恢复过程的理解。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2419, + "question": "Which side does the marker wire in the diffusion couple move towards?", + "answer": "Because D_Zn > D_Cu, the marker plane moves towards the Cu side.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释扩散偶中标记线的移动方向，答案提供了文字解释和论述，说明移动方向的原因（D_Zn > D_Cu），符合简答题的特征。 | 知识层次: 题目需要理解扩散偶中标记线的移动原理，并应用扩散系数差异（D_Zn > D_Cu）进行分析，属于多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解扩散偶中标记线的移动原理，并能够比较不同元素的扩散系数（D_Zn和D_Cu）以得出结论。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了明确的结论，减少了部分分析负担。" + }, + { + "idx": 2420, + "question": "A diffusion couple is formed by pure copper and a Zn=10° alloy with w(Zn)=3000. A marker wire is inserted at the bonding interface. After annealing at 7851 for 56 days, the marker wire is found to have moved 0.0105πm, with x(Zn)=200 at the marker plane, a concentration gradient (∂x_Zn/∂x)=-0.089 mm^-1, and ∫_{0}^{0.27} x dN_Zn=0.016 mm. Calculate the interdiffusion coefficient D̃ for the alloy with concentration x(Zn)=22.74°.", + "answer": "The diffusion duration is 56 days, i.e., t=56d=56×24×3600s=4838400s. Based on the given data, the interdiffusion coefficient D̃ is: D̃ = (-1)/(2t (dC/dx)) ∫_0^∞ x dC = (-0.016 mm)/(-2×4838400s×0.089 mm^-1) = 1.869×10^-8 mm^2 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及时间单位转换、浓度梯度计算和积分运算，最终需要得出具体的扩散系数数值。这完全符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括时间单位的转换、浓度梯度的应用以及积分计算，涉及多个概念的综合应用和关联分析。虽然不需要进行复杂的推理分析或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。需要综合运用扩散偶、浓度梯度、积分计算等多个概念，并进行多步骤的数学运算。题目涉及的单位转换、积分计算以及多个变量的综合分析都增加了难度，属于选择题型中较高难度的题目。" + }, + { + "idx": 2421, + "question": "To remove hydrogen from the system through palladium membrane diffusion, it is known that the diffusion coefficient of hydrogen in palladium at $500^{\\\\circ}C$ is $1.0\\\\times10^{-8}177^{-15}$. The hydrogen concentrations on both surfaces of a palladium plate are maintained at $2.4 kg/m^{3}$ and $0.61-2^{7}m^{3}$. Under steady-state diffusion, calculate the amount of hydrogen passing through a palladium plate with an area of $0.277^{2}$ and a thickness of $5\\\\pi\\\\pi\\\\pi$ per hour (expressed in $k=1$).", + "answer": "Since this is a steady-state thin-film diffusion problem, and the diffusion coefficient does not vary with concentration, the concentration distribution within the film is linear. According to the problem statement, substituting the corresponding values, the concentration gradient within the film is calculated as: $$\\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}=\\\\frac{0.6-2.4}{5\\\\times10^{-3}}kg/m^{4}=-360\\\\mathrm{kg/m^{-4}}$$ The one-dimensional steady-state problem can be solved using the first law of diffusion: $$J=-D{\\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}}$$ The amount of hydrogen passing through the palladium plate with an area of $0.2171^{3}$ per hour is: $$Q=J\\\\times A\\\\times t=-D{\\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}}.A t=1.0\\\\times10^{-8}\\\\times360\\\\times0.2\\\\times3600\\\\mathrm{kg}=2.592\\\\times10^{-3}\\\\mathrm{kg}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决一个稳态扩散问题，涉及扩散系数、浓度梯度和扩散通量的计算，最终需要得出具体的数值结果。答案中展示了详细的公式推导和数值代入过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律进行稳态扩散问题的求解，包括浓度梯度的计算、扩散通量的确定以及最终通过面积的氢量计算。虽然题目提供了必要的参数和公式，但需要综合运用这些知识进行正确的数值计算和单位转换。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及稳态扩散问题，需要应用菲克第一定律进行多步计算，包括浓度梯度的计算、扩散通量的求解以及最终通过面积和时间计算总扩散量。虽然题目提供了所有必要的数据，但需要考生能够正确理解和应用这些概念，并进行准确的数学运算。" + }, + { + "idx": 2422, + "question": "Assuming that at 1000°C, atoms diffuse through an Al2O3 crystal a distance x in 3h, estimate the time required for Al atoms to diffuse through the same Al2O3 crystal a distance of 9x.", + "answer": "Since the diffusion distance is proportional to the square root of time, when the diffusion distance is 9x, the required time is t2 = (9x)^2 / x^2 * 3h = 243h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过扩散距离与时间的关系公式来估算所需时间。答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查对扩散距离与时间平方根关系的理解，并直接套用公式进行计算。虽然需要理解扩散的基本原理，但计算过程相对简单，属于基本公式的直接应用。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解扩散距离与时间的关系（平方根关系），但解题步骤相对直接，仅需套用公式并进行简单计算即可得出答案。不需要复杂的分析或多步骤推理，因此在选择题型内属于等级2难度。" + }, + { + "idx": 2423, + "question": "A $C_{5}^{5}$ Fe plate with a thickness of $1.2\\\\pi m m$. One side is carburizing and the other side is decarburizing atmosphere, with surface concentrations of $\\\\mathrm{Pr}(C)=0.01200$ and $1+1(1-)=0.007500$, respectively. At $750-10$, when steady-state diffusion is achieved in the plate, the measured diffusion flux is $1.4\\\\times10^{-8}k g/m^{2}\\\\cdot5$. Find the diffusion coefficient of carbon at this temperature. $\\\\mathrm{{.}_{W}(C)=0.8\\\\%\\\\equiv60k g/m^{3})}$", + "answer": "First, convert the mass concentration to volume concentration. Since $\\\\begin{array}{r}{w(\\\\mathbf{C})=0,8\\\\%=60\\\\mathrm{kg/m^{3}}}\\\\end{array}$, the volume concentrations of $\\\\mathbb{C}_{1}{=}\\\\mathrm{w}(\\\\mathbb{C})=0,012\\\\%$ and $\\\\mathrm{C_{2}}{=}{}_{\\\\mathrm{W}}(\\\\mathrm{C}){=}0.00750/\\\\$ are: $$ C_{1}=\\\\frac{0.012}{0.8}\\\\times60=0.9\\\\mathrm{kg\\\\cdotm^{-3}}\\\\quad C_{2}=\\\\frac{0.0075}{0.8}\\\\times60=0.5625\\\\mathrm{kg\\\\cdotm^{-3}}$$ This is a one-dimensional steady-state diffusion problem, and the diffusion coefficient does not vary with concentration, so the concentration distribution in the plate is linear. Based on the given data, the concentration gradient in the plate can be calculated: $$ \\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}=\\\\frac{0.5625-0.9}{1.2\\\\times10^{-3}}\\\\mathrm{kg/m^{4}}=-281.25\\\\mathrm{kg/m^{4}}$$ According to the one-dimensional steady-state diffusion equation, the diffusion coefficient is $$ {\\\\cal D}=-J{\\\\frac{\\\\mathrm{d}\\\\mathrm{r}}{\\\\mathrm{d}C}}=1.4\\\\times10^{\\\\mathrm{~8}}\\\\times{\\\\frac{1}{281.25}}\\\\mathrm{m}^{2}/\\\\mathrm{s}=4.98\\\\times10^{-11}\\\\mathrm{m}^{2}/\\\\mathrm{s}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散系数，解答过程中涉及浓度转换、浓度梯度计算以及扩散系数的推导，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将质量浓度转换为体积浓度，并应用一维稳态扩散方程进行计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行中等难度的应用。 | 难度: 在选择题中属于高难度题目，需要综合运用多个概念（如浓度转换、稳态扩散、浓度梯度计算等），并进行多步骤的复杂计算。题目涉及的单位转换和公式推导也增加了难度，属于需要深入理解和综合分析的类型。" + }, + { + "idx": 2424, + "question": "A diffusion couple is composed of pure copper and a Zn=10° alloy with w(Zn)=3000. A marker wire is inserted at the bonding interface. After annealing at 7851 for 56 days, the marker wire is found to have moved 0.0105πm. The marker plane has x(Zn)=200, the concentration gradient (∂x_Zn/∂x)=-0.089 mm^-1, and ∫_{0}^{0.27} x dN_Zn=0.016 mm. Determine the intrinsic diffusion coefficients of Zn and Cu in the alloy with x(Zn)=22.74°.", + "answer": "The velocity of the marker plane movement v = marker displacement / (2×time) = 0.0105 mm / (2×4838400s) = 1.085×10^-9 mm/s. According to the relations v = (D_Cu - D_Zn) (dx_Zn/dy) and D̃ = (x_Zn D_Cu + x_Cu D_Zn), at the marker plane where x_Zn=0.22, the simultaneous equations are: (D_Cu - D_Zn)×(-0.089 mm^-1) = 1.085×10^-9 mm/s and (0.22 D_Cu + 0.78 D_Zn) = 1.869×10^-8 mm^2 s^-1. Solving the simultaneous equations yields: D_Zn = 2.137×10^-8 mm^2 s^-1, D_Cu = 0.918×10^-8 mm^2 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散系数，解答过程中涉及多个步骤的数学运算和方程求解，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散理论中的多个公式，并进行综合分析。虽然不需要深度推理或创新应用，但需要理解和运用多个相关概念（如标记平面移动速度、浓度梯度、扩散系数关系等）来解决问题。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步骤计算和多个概念的关联应用。需要理解扩散偶、标记线移动速度、浓度梯度、内在扩散系数等多个材料科学概念，并进行综合分析。解题过程需要解联立方程，计算步骤复杂且容易出错，对学生的计算能力和概念掌握深度要求较高。" + }, + { + "idx": 2425, + "question": "Calculate the diffusion rate of AI through Al2O3 at a temperature 10 times that at 1000°C (i.e., find D(T)=10D(1000°C)). The activation energy Q for AI diffusion in Al2O3 crystal is known to be 477 kJ/mol.", + "answer": "According to the relationship between diffusion coefficient and temperature D = D0 exp(-Q/RT), let T1=1000°C=1273K, and find the temperature T2 where D(T2)=10D(T1). From 10 = exp(-Q/R (1/T2 - 1/T1)), we get 1/T2 = 1/T1 - (R ln10)/Q = 1/1273K - (8.314*ln10)/477000 = 7.454×10^-4 K^-1. Therefore, T2=1341.6K, and the temperature increases by 68.6K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散速率，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解扩散系数与温度的关系，并运用对数运算求解温度变化。虽然不涉及复杂的综合分析或创新应用，但超出了简单直接套用公式的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与温度的关系公式，并进行多步骤的计算和转换。题目要求考生能够正确应用阿伦尼乌斯方程，进行对数运算和温度单位的转换，同时需要处理较大的数值计算（如477 kJ/mol的激活能）。虽然题目提供了明确的公式指引，但计算步骤较为复杂，涉及多个关键概念的综合运用，属于综合性计算问题。" + }, + { + "idx": 2426, + "question": "The turbine blade is oxidized as metal atoms reach the metal surface through oxide diffusion and react with oxygen to form oxides. This material forms a $B H//H T$ thick oxide layer after $50\\\\textcircled{<}107$. What is the thickness of the oxide layer after 100h at the same temperature?", + "answer": "This process involves two sub-processes: diffusion of metal atoms in the oxide layer and the reaction of metal atoms with oxygen. Because diffusion is slow, the entire process is controlled by diffusion. The diffusion distance $l$ and diffusion time $^ Ḋ t Ḍ$ follow a square root relationship, i.e., $l=11$ after $5-50=50$ holding time $\\\\lfloor0\\\\rfloor_{\\\\lfloor1\\\\rfloor}$, forming $3[1171(l)$. Then, the oxide layer thickness $l-$ after $\\\\lvert[\\\\rvert]\\\\rvert\\\\lvert\\\\chi\\\\rvert/\\\\lvert\\\\chi\\\\rvert)$ is $$ I_{\\\\mathrm{{z}}}=I_{\\\\mathrm{{|\\\\sqrt{\\\\frac{t_{\\\\mathrm{z}}}{t_{\\\\mathrm{l}}}}=8\\\\sqrt{\\\\frac{100}{10}}\\\\mu\\\\mathrm{{m}=25.3\\\\upmu5}}}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氧化层的厚度，答案中包含了具体的数学运算和公式推导过程。 | 知识层次: 题目涉及扩散控制氧化过程的计算，需要理解扩散距离与时间的平方根关系，并进行多步计算。虽然计算过程相对直接，但需要将扩散理论与具体数值计算相结合，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散控制过程的概念，掌握扩散距离与时间的平方根关系，并进行多步计算。题目涉及中等应用层次的知识点，要求综合分析扩散与反应的关系，并通过数学计算得出最终结果。虽然题目提供了部分计算过程，但仍需要考生具备一定的概念关联和计算能力才能正确解答。" + }, + { + "idx": 2427, + "question": "At what temperature can the contribution of grain boundary diffusion be neglected?", + "answer": "From the data, it can be seen that at 1200K, the difference between Dapp and D1 is already very small, and the special contribution of grain boundary diffusion can be neglected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么温度下晶界扩散的贡献可以忽略，答案提供了具体的温度（1200K）并解释了原因，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解晶界扩散的贡献及其与温度的关系，并基于数据进行综合分析判断。这涉及多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及对晶界扩散贡献的理解，需要考生掌握扩散系数（Dapp和D1）的概念，并能从数据中分析出温度对晶界扩散贡献的影响。虽然题目提供了具体数据（1200K），但考生仍需具备综合分析能力，判断在何种条件下晶界扩散的贡献可以忽略。这要求考生不仅理解基本概念，还能进行简单的数据分析和逻辑推理。" + }, + { + "idx": 2428, + "question": "If the diameter of polyester (PET) carpet fibers is doubled to 100 microns, how much time is required for water, dye, and dye bags to penetrate to the center of the fiber, respectively?", + "answer": "The penetration depth is 50 microns. The time required for water to penetrate to the center of the fiber is t=(50×10^-6)^2/(2×1.0×10^-12)=1250 s; the time required for dye to penetrate to the center of the fiber is t=(50×10^-6)^2/(2×1.0×10^-13)=12500 s; the time required for dye bags to penetrate to the center of the fiber is t=(50×10^-6)^2/(2×1.0×10^-14)=125000 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用扩散方程计算渗透时间。虽然需要理解扩散系数的概念，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及三个不同的物质（水、染料、染料袋）的渗透时间计算，但每个计算都是基于相同的公式（t = (penetration depth)^2 / (2 × diffusion coefficient)），仅需替换不同的扩散系数值。解题步骤重复且直接，无需复杂的逻辑推理或多公式组合。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2429, + "question": "In polycrystalline ceramics, does diffusion predominantly occur along grain boundaries or through the lattice?", + "answer": "Grain boundaries are fast paths for diffusion, so in polycrystals, if the temperature is not too high, grain boundary diffusion predominates. However, at very high temperatures, the difference between grain boundary diffusion and lattice diffusion diminishes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对扩散机制进行解释和论述，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要理解晶界扩散和晶格扩散的基本概念，还需要分析温度对扩散机制的影响，涉及多因素的综合考虑和概念关联。虽然不涉及复杂计算，但需要对不同条件下的扩散行为进行比较和解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目涉及多晶陶瓷中扩散路径的理解，需要掌握晶界扩散和晶格扩散的基本概念，并能根据温度条件分析主导扩散机制。虽然不需要复杂的计算，但需要对材料科学中的扩散机制有较深的理解，并能综合分析温度对扩散路径选择的影响。" + }, + { + "idx": 2430, + "question": "Both Ge and Cu exhibit self-diffusion via a vacancy mechanism. When diffusion occurs at comparable temperatures, which one has a larger self-diffusion coefficient? Why?", + "answer": "Referring to Appendix B of the materials, the melting points of Ge and $[\\\\frac{\\\\pi}{2}]$ are $\\\\textcircled{1}17.57.757$ and $108.1.575\\\\times$, respectively. At first glance, it might seem that Cu's self-diffusion coefficient is lower than Ge's at comparable temperatures. However, $111$ crystal is metallically bonded, while Ge crystal is covalently bonded. Covalent bonds are much stronger than metallic bonds. Therefore, in reality, $\\\\sum11$'s self-diffusion coefficient is higher than Ge's.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来比较Ge和Cu的自扩散系数，并说明原因。答案中包含了详细的解释和理论依据，而不是简单的选择或判断。 | 知识层次: 题目要求学生比较两种不同材料（Ge和Cu）的自扩散系数，并解释其原因。这需要学生理解自扩散机制、晶体结构、键合类型（金属键与共价键）对扩散行为的影响，以及温度与扩散系数的关系。此外，学生还需综合这些知识进行推理分析，解释为什么在相似温度下Cu的自扩散系数高于Ge。这涉及多个概念的关联和深层次的机理解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握自扩散系数的基本概念，还需要深入理解不同晶体结构（金属键与共价键）对扩散行为的影响机制。正确选项涉及多个复杂分析步骤：1) 比较两种材料的熔点；2) 分析键合类型差异；3) 综合判断键合强度对空位迁移能垒的影响。此外，题目要求考生能够将附录中的参考数据与理论知识相结合进行推理，这种需要多维度知识整合和机理深度解释的要求，在选择题型中属于最复杂的考查形式。" + }, + { + "idx": 2431, + "question": "Is the diffusion in oxide ceramics a vacancy exchange mechanism or a rotary exchange mechanism?", + "answer": "The bonding in oxide ceramics is ionic bonding, and the diffusion mechanism in ionic crystals is primarily the vacancy exchange mechanism. The activation energy for the rotary exchange mechanism is too high and often disrupts the ionic bonding, so it cannot be the diffusion mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散机制的类型，并提供详细的论述和理由，而不是从多个选项中选择或判断对错。答案也以文字解释的形式呈现，符合简答题的特征。 | 知识层次: 题目要求解释氧化物陶瓷中的扩散机制，涉及离子键合、空位交换机制和旋转交换机制的比较，需要综合运用材料科学中的扩散理论和晶体缺陷知识，进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于复杂分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解氧化物陶瓷中的扩散机制，还需要深入分析离子键合的特性，并比较空位交换机制和旋转交换机制的活化能差异。这需要综合运用材料科学中的键合理论、扩散机理和能量分析等多方面知识，进行复杂的推理和判断。正确选项的解释涉及机理深度解释和复杂现象全面分析，远超一般选择题的知识点掌握要求。" + }, + { + "idx": 2433, + "question": "The diameter of polyester (PET) carpet fiber is 50 micrometers, immersed in a dye bath containing water, dye, and dye bags at boiling temperature. The diffusion coefficients of water, dye, and dye bags are 1.0×10^-12 m²/s, 1.0×10^-13 m²/s, and 1.0×10^-14 m²/s, respectively. Estimate the time required for water, dye, and dye bags to penetrate into the center of the fiber.", + "answer": "Using the simple one-dimensional diffusion distance-time relationship l=√(2Dt) for approximate estimation, the penetration depth is 25 micrometers. The time required for water to penetrate into the fiber center is t=(25×10^-6)^2/(2×1.0×10^-12)=312.5 s; the time required for dye to penetrate into the fiber center is t=(25×10^-6)^2/(2×1.0×10^-13)=3125 s; the time required for dye bags to penetrate into the fiber center is t=(25×10^-6)^2/(2×1.0×10^-14)=31250 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计水、染料和染料袋渗透到纤维中心所需的时间，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式（一维扩散距离-时间关系）的直接应用和简单计算，无需多步推理或综合分析，属于基础知识的直接运用。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（l=√(2Dt)）进行计算，解题步骤简单明确，无需组合多个公式或进行复杂分析。题目提供了所有必要参数，计算过程属于单一公式直接应用，符合等级1的难度标准。" + }, + { + "idx": 2434, + "question": "Given the volume diffusion coefficient of silver D1=7.2×10^-5 exp(-190 kJ/mol / (R T)) m²·s^-1 and the grain boundary diffusion coefficient Db=1.4×10^-5 exp(-90 kJ/mol / (R T)) m²·s^-1, with a grain size of 7×10^-5 m and a grain boundary thickness of 5×10^-10 m, calculate the effective diffusion coefficient Dapp at temperatures 577°C, 727°C, and 0.776 Tm.", + "answer": "The apparent diffusion coefficient of a polycrystal containing grain boundaries is expressed as Dapp=f Db + (1-f) D1, where f is the fraction of defects (grain boundaries). Assuming the grains are cubes with side length a equivalent to the grain diameter, each face of the cube is shared by adjacent cubes, so there are only 3 grain boundaries per cube, hence f≈3δ/d=7.5×10^-5. The calculation results are as follows: Temperature K: 800, 1000, 1200; D (m²·s^-1): 2.82×10^-17, 8.5×10^-15, 3.86×10^-13; Db (m²·s^-1): 1.86×10^-11, 2.78×10^-10, 1.69×10^-9; Dapp (m²·s^-1): 1.42×10^-15, 2.94×10^-14, 5.13×10^-13; Dapp/D: 50.47, 3.44, 1.33.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出不同温度下的有效扩散系数Dapp，答案也展示了具体的计算过程和结果。这符合计算题的特征，即需要应用公式和进行数值计算来解决问题。 | 知识层次: 题目需要应用扩散系数的计算公式，理解晶界扩散和体积扩散的贡献比例，进行多步计算，并综合分析不同温度下的扩散行为。虽然涉及多个概念和计算步骤，但不需要深入机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数的概念、掌握有效扩散系数的计算公式，并能正确代入数据进行多步计算。题目涉及温度转换、指数运算和比例计算，虽然提供了公式和部分中间步骤，但仍需要较强的综合计算能力和对材料科学中扩散机制的理解。" + }, + { + "idx": 2435, + "question": "How is texture formed in crystals?", + "answer": "A crystal is a three-dimensionally periodic ordered arrangement, which has a certain orientation relative to a reference coordinate. The orientations of the grains in a polycrystal have an orientation distribution relative to the reference coordinate. If the orientation distribution of the polycrystal deviates from a random distribution, texture is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体中织构的形成过程，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查晶体织构形成的基本概念和定义，主要涉及记忆和理解晶体取向分布与织构形成的关系，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体结构的基本概念，但正确选项不仅需要记忆晶体的定义，还需要理解多晶体中晶粒取向分布与随机分布偏离时形成织构的概念。这超出了简单的定义记忆，属于概念解释和描述的层次。" + }, + { + "idx": 2436, + "question": "The critical resolved shear stress of aluminum is $2.40\\\\approx10^{5}$ Pa. When the tensile axis is [001], what is the tensile stress required to cause yielding?", + "answer": "The relationship between tensile stress $\\\\sqrt{h}$ and the resolved shear stress on the slip system is =coscos, where and are the angles between the tensile direction and the slip direction and the normal to the slip plane, respectively. The crystal structure of aluminum is fcc, and the slip system is $11117=110.3$. When the tensile axis is [001], since it is perpendicular to [110] and [110], the resolved shear stress on the slip systems composed of them is 0, and they will not activate. The geometric relationship between the [001] axis and its slip systems is equivalent, and their resolved shear stresses are equal. Taking the (111)[011] slip system as an example, the tensile stress required to cause yielding is calculated. The cosine of the angle $\\\\varphi$ between [001] and the slip plane normal [111], cos$\\\\varphi$, and the cosine of the angle $\\\\lambda$ between [001] and the slip direction [011], cos$\\\\lambda$, are respectively $$ \\\\cos\\\\varphi={\\\\frac{1}{\\\\sqrt{1}{\\\\sqrt{3}}}}={\\\\frac{1}{\\\\sqrt{3}}}\\\\cos\\\\lambda={\\\\frac{1}{\\\\sqrt{1}{\\\\sqrt{2}}}}={\\\\frac{1}{\\\\sqrt{2}}}$$ When the critical resolved shear stress $\\\\frac{\\\\sqrt{1}}{2}=\\\\frac{1}{2}$ is $2.40\\\\times0^{-}10^{5}Pa$, the corresponding stress $\\\\alpha$ is the yield stress: $$ \\\\sigma_{\\\\circ}={\\\\frac{\\\\tau_{\\\\circ}}{\\\\cos\\\\varphi\\\\cos\\\\lambda}}=2.4\\\\times10^{5}\\\\times{\\\\sqrt{3}}\\\\times{\\\\sqrt{2}}\\\\mathbf{Pa}=5.89\\\\times10^{5}\\\\mathbf{Pa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的拉伸应力，解答过程中涉及到了角度计算、余弦值求解以及临界剪切应力的转换，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界分切应力与拉伸应力之间的关系，并应用几何关系进行计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在选择题中属于高难度，需要深入理解晶体结构和滑移系统的概念，进行多步计算和综合分析。题目涉及复杂的几何关系和三角函数计算，要求考生能够将理论知识与实际计算相结合，解决复杂多变量问题。" + }, + { + "idx": 2437, + "question": "For a face-centered cubic crystal stretched along the [131] axis, determine the resolved shear stress of the slip system (111)[10-1]. The tensile stress is 6.9×10^5 Pa", + "answer": "For the slip system (111)[10-1], the cosine of the angle between [131] and the slip plane normal [111] is cosφ=5/(√3×√11)=0.870; the cosine of the angle between [131] and the slip direction [10-1] is cosλ=(1×1 + 3×0 + 1×(-1))/(√11×√(1+0+1))=0/(√11×√2)=0. The resolved shear stress τ=6.9×10^5×0.870×0 Pa=0 Pa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定剪切应力，解答过程中涉及角度计算和应力分解，最终给出具体的数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括计算角度余弦和应用分解剪应力公式，涉及晶体学方向和应力分解的综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体学方向指数、滑移系统、分解剪应力等概念，并进行多步向量计算（包括点积和模的计算）。虽然题目提供了具体数值，但考生仍需正确应用公式并执行准确的计算步骤，包括角度余弦值的确定和最终应力计算。这种综合性计算问题在选择题型中属于较高要求。" + }, + { + "idx": 2438, + "question": "Mg2+ diffuses in MgO. What concentration of trivalent cation impurities needs to be added near the melting point of 2800°C to ensure that Mg2+ mainly diffuses via the non-intrinsic vacancy mechanism?", + "answer": "When the concentration of non-intrinsic vacancies exceeds that of intrinsic vacancies, the non-intrinsic vacancy mechanism becomes the dominant diffusion mechanism. In MgO crystals, the formation enthalpy of Schottky defects is ΔH = 6 eV (as shown in Table 6-2 of the textbook). Thus, the equilibrium concentration of Schottky vacancies at 2800°C is: xv ≈ exp(-ΔHc / 2kBT) = exp(-6 / (2 × 8.62 × 10^-5 × 3073)) = 1.206 × 10^-5. If the non-intrinsic vacancy concentration exceeds this equilibrium intrinsic vacancy concentration, diffusion will primarily occur via the non-intrinsic vacancy mechanism. Now, by adding trivalent cations, every two trivalent cations replacing two Mg2+ ions will generate one cation vacancy. To achieve a non-intrinsic cation vacancy concentration of 1.206 × 10^-5, the required trivalent cation concentration x is: x = 2 × 1.206 × 10^-5 = 2.412 × 10^-5. Therefore, at 2800°C, for Mg2+ in MgO to mainly diffuse via the non-intrinsic vacancy mechanism, the trivalent cation impurity concentration must exceed 2.412 × 10^-5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算平衡浓度和杂质浓度，解答过程涉及多个计算步骤和公式推导。 | 知识层次: 题目涉及多步计算和概念关联，需要计算非本征空位浓度并与本征空位浓度比较，同时理解掺杂三价阳离子对空位浓度的影响机制。虽然不涉及复杂的推理分析或创新设计，但需要综合运用热力学公式和缺陷化学知识进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解非本征空位扩散机制与本征空位浓度的关系，进行多步骤计算（包括平衡浓度计算和杂质浓度换算），并综合分析杂质添加对扩散机制的影响。题目涉及多个材料科学核心概念的综合应用，但计算过程相对明确，属于典型的综合性计算问题。" + }, + { + "idx": 2439, + "question": "For a face-centered cubic crystal stretched along the [131] axis, determine the resolved shear stress on the slip system (111)[0-11]. The tensile stress is 6.9×10^5 Pa.", + "answer": "According to the relationship between tensile stress and resolved shear stress on the slip system, τ=σcosλcosφ. For the slip system (111)[0-11], the cosine of the angle between [131] and the slip plane normal [111], cosφ, and the cosine of the angle between [131] and the slip direction [0-11], cosλ, are: cosφ=(1×1 + 3×1 + 1×1)/(√(1+1+1)×√(1+9+1))=5/(√3×√11)=0.870; cosλ=(1×0 + 3×(-1) + 1×1)/(√(1+9+1)×√(0+1+1))=-2/(√11×√2)=-0.426. The resolved shear stress τ=6.9×10^5×0.870×(-0.426) Pa=-2.56×10^5 Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如τ=σcosλcosφ）来确定分解剪应力，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要多步计算（包括角度余弦计算和应力分解），涉及晶体几何和力学概念的关联应用，需要综合分析拉伸方向、滑移面和滑移方向之间的关系。虽然不涉及创新或深度机理分析，但计算过程较为复杂，超出了简单套用公式的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如晶体学方向指数、滑移系统、分切应力公式）并进行多步计算（包括方向余弦计算和应力转换）。虽然题目提供了具体步骤，但要求考生具备较强的空间几何想象力和综合计算能力，属于需要综合分析的应用题。" + }, + { + "idx": 2441, + "question": "What are the similarities between crystal texture and polymer texture in a broad sense?", + "answer": "In a broad sense, the textures of the two are similar.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对晶体织构和聚合物织构的相似性进行文字解释和论述，答案也是以文字形式给出的简要回答 | 知识层次: 题目考查对晶体织构和聚合物织构相似性的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目仅要求识别和记忆晶体纹理和聚合物纹理在广义上的相似性这一基本定义。题目属于基础概念记忆层次，不需要复杂的解释或分析，只需选择正确的陈述即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2442, + "question": "How is texture formed in polymers?", + "answer": "Under the action of tensile force on polymers, the molecular chains in the amorphous regions of the polymer become ordered in one-dimensional or two-dimensional directions. In the crystalline regions (folded lamellae), the layers rotate to orient along the tensile axis, meaning the direction of the molecular chains and the orientation of the crystalline blocks are not randomly distributed, thus forming the polymer texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物中纹理的形成过程，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释聚合物中织构的形成机制，涉及分子链在非晶区和晶区的有序排列和取向变化，需要综合运用材料科学中的高分子物理知识，理解拉伸力对聚合物微观结构的影响，并进行机理分析。这超出了简单记忆或基本应用的层次，属于对复杂现象的深入解释和分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解聚合物在拉伸力作用下的微观结构变化机制，包括非晶区和晶区的分子链排列方式、层状结构的旋转取向等复杂现象。正确选项涉及多维度的机理解释和综合推理，需要考生具备扎实的高分子物理知识体系和分析能力，远超选择题常见的记忆性知识点考查范畴。" + }, + { + "idx": 2443, + "question": "For a ceramic oxide, in which temperature ranges does the vacancy diffusion mechanism occur as intrinsic or extrinsic?", + "answer": "If the ceramic oxide is a solid solution, the incorporation of solutes with different valences will generate extrinsic point defects. The concentration of intrinsic point defects changes drastically with temperature, while the concentration of extrinsic point defects does not vary with temperature. Therefore, at low temperatures, the concentration of extrinsic vacancies is higher than that of intrinsic vacancies, and this difference becomes more pronounced as the temperature decreases. Thus, in the low-temperature range, the extrinsic vacancy diffusion mechanism dominates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷氧化物中空位扩散机制在何种温度范围内表现为本征或外征，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要综合运用点缺陷理论、温度对缺陷浓度的影响以及扩散机制的知识，进行推理分析和机理解释。涉及多个概念的关联和综合分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用陶瓷氧化物中本征与非本征点缺陷的知识，理解不同温度范围内扩散机制的主导因素，并能够分析掺杂价态对缺陷浓度的影响。解题需要：" + }, + { + "idx": 2444, + "question": "What changes occur in polymer texture when heated?", + "answer": "Heating can cause oriented polymers to disorient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物在加热时发生的纹理变化，需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查聚合物在加热过程中纹理变化的基本概念，属于对基本原理的记忆和理解。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及聚合物加热时的变化这一基础概念，但正确选项\"加热会导致取向聚合物解取向\"需要学生对聚合物结构变化有一定理解，而不仅仅是记忆定义。这属于概念解释和描述层次，比单纯记忆定义(等级1)稍难，但不需要复杂的分析推理(等级3)。" + }, + { + "idx": 2445, + "question": "What are the differences in the formation mechanisms between crystal texture and polymer texture?", + "answer": "Polycrystalline texture is formed by the deformation and rotation of grains under force, while polymer texture is formed by the ordered arrangement and distribution of molecular chains under force, along with the rotational orientation of crystalline blocks in the amorphous region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体织构和聚合物织构的形成机制差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较晶体织构和聚合物织构的形成机制，涉及不同材料体系（金属/聚合物）的微观结构演变机理，需要综合运用晶体学、高分子物理等知识进行机理层面的对比分析，属于需要深度理解和推理分析的复杂问题。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2446, + "question": "The possible slip planes for a body-centered cubic crystal are {110}, {112}, and {123}. If the slip direction is [1-11], what are the specific slip systems?", + "answer": "The slip direction of a slip system must lie on its slip plane. According to the crystallographic zone law, when the slip direction is [1-1 1], for the {110} slip plane, the possible slip planes are (110), (011), and (10-1). For the {112} slip plane, the possible slip planes are (121), (21-1), and (-112). For the {123} slip plane, the possible slip planes are (132), (231), (32-1), (-123), (-213), and (31-2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和列举具体的滑移系统，答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用晶体学中的滑移面和滑移方向的概念，并通过晶带定律进行多步分析和判断，涉及多个滑移面的具体计算和关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生掌握体心立方晶体滑移系的基本概念，包括滑移面和滑移方向的确定。其次，需要应用晶带定律（crystallographic zone law）来判断哪些滑移面包含给定的滑移方向[1-11]，这需要一定的空间想象力和计算能力。此外，题目涉及多个滑移面族（{110}、{112}、{123}）的分析，每个面族又有多个可能的滑移面需要验证，步骤较为复杂。最后，题目要求考生综合所有信息，正确识别所有符合条件的滑移系，这需要较强的综合分析能力。因此，在选择题型内，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 2447, + "question": "When using X-ray detection, how does the diffraction of polycrystalline texture appear?", + "answer": "The diffraction of polycrystalline texture appears as the diffraction rings of polycrystals becoming discontinuous rings, and in extreme cases, turning into diffraction spots like those of single crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释X射线检测中多晶织构的衍射表现，答案以文字形式详细描述了衍射环的变化情况，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解多晶织构在X射线衍射中的表现，并解释衍射环不连续甚至变成单晶衍射点的现象。这涉及对多晶和单晶衍射原理的综合理解，以及织构对衍射图案影响的分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解X射线衍射的基本原理以及多晶和单晶衍射的区别，并能综合分析多晶织构衍射的特殊表现。虽然题目提供了正确选项，但需要考生具备一定的知识背景才能准确理解并选择正确答案。" + }, + { + "idx": 2448, + "question": "What is the critical curvature radius of particles that substantially affects the solubility of Fe3C in α-Fe? Given the interfacial energy of Fe3C is 0.71 J/m², and the molar volume of Fe is 23.4×10^-6 m³/mol.", + "answer": "When the particle curvature radius is large (e.g., 1000nm), the solubility already approaches the equilibrium concentration. When the curvature radius exceeds this size, it no longer has a substantial effect on solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释临界曲率半径对Fe3C在α-Fe中溶解度的影响，并提供相关参数，答案以文字解释的形式给出，而非计算或选择。 | 知识层次: 题目涉及临界曲率半径对溶解度的影响，需要理解Gibbs-Thomson效应，并应用给定的界面能和摩尔体积数据进行计算。虽然不涉及多步计算，但需要概念关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及界面能、摩尔体积和溶解度之间的关系，要求考生能够综合运用这些概念来评估粒子曲率半径对溶解度的影响。虽然题目提供了必要的参数，但需要考生具备一定的材料科学基础知识和计算能力来理解并应用这些参数。此外，题目要求考生能够识别临界曲率半径的概念，并理解其对溶解度的实质性影响，这需要一定的综合分析能力。" + }, + { + "idx": 2449, + "question": "The equilibrium solubility of Fe3C in α-Fe measured by internal friction method is given by C=0.736exp(-4850/T), where T is the temperature. Determine the equilibrium solubility of Fe3C in α-Fe at 627°C (i.e., 900K).", + "answer": "C∞=0.736exp(-4850/T)=0.736exp(-4850/900)=3.36×10^-3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式进行数值计算，最终得出一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，只需将给定的温度代入公式即可得到结果，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的公式进行计算，无需额外的概念理解或步骤组合。属于单一公式直接计算的简单应用，符合等级1的标准。" + }, + { + "idx": 2450, + "question": "When using X-ray detection, how does the diffraction of polymer texture appear?", + "answer": "The diffuse rings of polymer texture consist of diffuse peaks (rather than the discrete reflections observed in crystals).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物纹理在X射线检测中的衍射表现，答案提供了详细的文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对聚合物X射线衍射图案的基本特征的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及X射线衍射和聚合物结构的基础概念，但正确选项要求考生能够区分晶体和非晶体（聚合物）的衍射模式差异。这需要考生不仅记住定义，还要理解衍射图案的特征（如漫射环与离散反射的区别），属于概念解释和描述的层次。不过题目不需要复杂的推导或多概念整合，因此不属于最高难度等级。" + }, + { + "idx": 2451, + "question": "At 627°C (i.e., 900K), what is the solubility of Fe3C particles with a radius of 100nm in α-Fe? The interfacial energy of Fe3C is known to be 0.71 J/m², and the molar volume of Fe is 23.4×10^-6 m³/mol.", + "answer": "Cr=C∞(1+(2×23.4×10^-6×0.71)/(8.314×900×100×10^-9))=3.36×10^-3(1+4.440×10^-9/100×10^-9)=3.509×10^-3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（温度、半径、界面能、摩尔体积）和公式进行数值计算，最终得出一个具体的溶解度数值。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及溶解度公式的应用、单位转换和数值计算，需要理解界面能、摩尔体积等概念的综合运用，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解溶解度公式、界面能概念、摩尔体积应用，并进行多步计算和单位转换。虽然题目提供了关键参数，但解题过程涉及多个物理量的综合运用和代数运算，对学生的概念理解和计算能力要求较高。" + }, + { + "idx": 2453, + "question": "For the allotropic transformation of a pure metal $(x\\\\rightarrow\\\\beta)$, at a certain degree of undercooling, the volume Gibbs free energy difference between the two phases is $7\\\\times10^{8} kJ/m^{3}$, and the interfacial energy is $0.5 J/m^{2}$. If the strain energy of nucleation is neglected, calculate the critical nucleus size and the critical nucleation work for forming a cubic nucleus.", + "answer": "For a cubic nucleus, the critical edge length $a^{*}=-\\\\frac{4\\\\gamma}{\\\\Delta G_{V}}=\\\\frac{4\\\\times0.6}{7\\\\times10^{8}}m=3.428\\\\times10^{-9}m$. The critical nucleation work is $\\\\Delta G^{*}=\\\\frac{1}{3}\\\\gamma A^{*}=\\\\frac{1}{3}\\\\times6\\\\times(3.428\\\\times10^{-9})^{2}\\\\times0.6J=1.44\\\\times10^{-17}J$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界核尺寸和临界形核功的计算方法，并应用相关公式进行综合分析。虽然题目提供了具体数值，但仍需理解公式背后的物理意义和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（吉布斯自由能差、界面能、临界核尺寸、临界成核功）并进行多步计算。题目要求考生能够将理论公式应用于具体几何形状（立方体核），并正确执行单位转换和代数运算。虽然题目提供了关键参数，但需要考生综合运用材料科学和热力学知识来推导和计算最终结果。" + }, + { + "idx": 2456, + "question": "For the allotropic transformation of pure metal $(x\\\\rightarrow\\\\beta)$, at a certain degree of undercooling, the volume Gibbs free energy difference between the two phases is $7\\\\times10^{8} kJ/m^{3}$, and the interfacial energy is $0.5 J/m^{2}$. If the strain energy of nucleation is neglected, calculate the critical nucleus size and the critical nucleation energy for the formation of a disk-shaped nucleus with a diameter $(D)$ to thickness $(1)$ ratio $(D//)$ of 20.", + "answer": "For the disk-shaped nucleus, the critical nucleus diameter $D^{*}=-\\\\frac{88}{3}\\\\frac{\\\\gamma}{\\\\Delta G_{V}}=\\\\frac{88\\\\times0.6}{3\\\\times7\\\\times10^{8}}m=2.514\\\\times10^{-8}m$. The critical nucleation energy is $\\\\Delta G^{*}=[-\\\\frac{\\\\pi}{80}\\\\times(2.514\\\\times10^{-8})^{3}\\\\times7\\\\times10^{8}+\\\\frac{11\\\\pi}{20}\\\\times(2.514\\\\times10^{-8})^{2}\\\\times0.6]J=2.184\\\\times10^{-16}J$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及临界核尺寸和临界成核能量的具体计算过程，答案也以数值结果呈现。 | 知识层次: 题目涉及多步计算和公式应用，需要理解临界核尺寸和临界成核能量的概念，并能够正确应用相关公式进行计算。虽然题目提供了具体的数值和公式，但需要综合运用这些信息进行求解，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及多步复杂计算和多个概念的关联应用。需要计算临界核尺寸和临界成核能，涉及体积吉布斯自由能差、界面能等参数的代入和转换，且计算步骤繁琐，容易出错。此外，题目还要求对盘状核的形状比进行考虑，增加了复杂性。" + }, + { + "idx": 2457, + "question": "Assuming the shear moduli G of the parent phase and the precipitate phase are the same, and the parent phase is an isotropic continuous medium. If a coherent nucleus forms, derive the expression for the size at which the spherical nucleus loses coherency during growth.", + "answer": "For a spherical nucleus, the sum of the misfit strain energy and interfacial energy before the loss of coherency is (4/3)πr^3×4Gδ^2+4πr^2γ_ci0. After losing coherency, there is no misfit strain energy, and the interfacial energy becomes 4πr^2γ_m. Let the critical size for losing coherency be r*. At this size, the energies of the coherent and incoherent states should be equal, hence (4/3)π(r*)^3×4Gδ^2+4π(r*)^2γ_ci0=4π(r*)^2γ_m. Solving this gives r*=3(γ_m−γ_ci0)/(4Gδ^2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导球形核在生长过程中失去共格性时的尺寸表达式，需要通过公式应用和数值计算来解决问题。答案中给出了具体的推导过程和最终的计算结果，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括应变能、界面能的计算，以及临界条件的推导。虽然不涉及复杂的机理分析或创新应用，但需要综合运用材料科学中的基本理论和公式进行中等难度的推导和计算。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如剪切模量、共格与非共格界面能、应变能等）并进行综合计算分析。题目要求推导临界尺寸，涉及多步计算和能量平衡的概念关联，但相比等级4的复杂多变量计算，步骤和变量相对简化。" + }, + { + "idx": 2458, + "question": "The equilibrium melting point of nickel is 172515, the solid phase ρ̄=0.6cm³/1770l, the liquid/solid interface energy y=2.25×10⁻⁵·50⁻⁷. If the radius of the spherical particle is 1cm, how much is the melting point reduced? Assume the molar melting ΔHₘ=[Γ̄Γ̄ḠḠJ†m0]", + "answer": "The melting point Tᵣ of a crystal with a curvature radius of 1cm is Tᵣ = Tₘ - (2γVₛTₘ)/(rΔHₘ). Substituting the data gives Tᵣ = 1728K - (2×6.6×2.25×10⁻⁵×1728)/(1×18066)K ≈ 1727.99K, ΔT = 0.01K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解熔点降低的具体数值，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括公式的代入和数值计算，同时需要理解熔化点降低的物理机制和相关的材料科学概念。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式要复杂一些。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如熔点降低公式、界面能、摩尔体积等）并进行多步骤计算。虽然题目提供了所有必要数据，但需要正确代入公式并处理单位换算，涉及中等应用层次的知识综合能力。相比简单概念题或单步计算题，该题目对计算准确性和概念关联性要求更高，但尚未达到复杂多变量计算的难度。" + }, + { + "idx": 2460, + "question": "Estimate the number of atomic clusters containing 60 atoms in 1cm³ of copper at its melting point temperature. The atomic volume of liquid copper is 1.6×10⁻²⁹m³, the surface energy is 0.177J/m², and the melting point is 1356K.", + "answer": "According to nᵢ = n exp(-ΔG / k_B T), first calculate the energy ΔG₆₀ of a 60-atom cluster. The radius of the cluster r = (3×60×1.6×10⁻²⁹ / 4π)^(1/3), and the surface area A₆₀ = 4πr² = 4π(3×60×1.6×10⁻²⁹ / 4π)^(2/3). ΔG₆₀ = A₆₀γ = 4π(3×60×1.6×10⁻²⁹ / 4π)^(2/3)×0.177 = 8.33×10⁻¹⁹J. The number of atoms per cm³ n = 1 / (1.6×10⁻²³) = 6.25×10²² cm⁻³. n₆₀ = 6.25×10²² exp(-8.33×10⁻¹⁹ / (1.38×10⁻²³×1356)) = 2.91×10³ cm⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计铜中60原子团簇的数量，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算，包括原子团簇半径、表面积、能量变化等，并应用了热力学公式和指数函数。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行计算，属于中等应用层次。 | 难度: 在选择题中属于高难度，需要综合运用多个物理概念（原子体积、表面能、热力学等）进行多步骤计算，涉及复杂公式推导和变量转换，且计算精度要求较高。" + }, + { + "idx": 2461, + "question": "What is the ratio of nucleation rates between intragranular coherent disc-shaped nucleation and grain boundary incoherent double spherical cap-shaped nucleation? Given the grain diameter Π=10^-3 m, temperature T=1000 K, and Boltzmann constant k=1.38×10^-23 J/K.", + "answer": "The calculation process for the nucleation rate ratio I2/I1 is as follows: I2/I1 = (d/L)exp[-(ΔGb* - ΔG*)/kT] = (10^-9/10^-3)exp[-(2.615×10^-18 - 1.26×10^-18)/(1.38×10^-23×1000)] = 2.27×10^-49. The result shows that the nucleation rate for intragranular coherent nucleation is higher than that for grain boundary incoherent nucleation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种形核速率之比，答案中包含了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用公式进行数值计算，并理解不同形核机制的能量差异。虽然计算过程较为直接，但需要综合运用多个知识点，包括形核能垒、Boltzmann分布等，属于中等应用层次。 | 难度: 在选择题型内，该题目属于高难度等级。题目涉及复杂的多步骤计算过程，包括不同形核机制的激活能差计算、玻尔兹曼因子应用以及尺寸参数比值的综合运算。需要考生同时掌握形核理论、热力学公式转换和指数运算技巧，并能正确关联多个物理概念（如相干/非相干界面、晶界形核几何因子等）。这种在选择题中要求进行多变量复杂计算和概念深度整合的题目，显著高于常规选择题的认知负荷要求。" + }, + { + "idx": 2462, + "question": "AI-Mg substitutional solid solution, estimate the misfit strain energy generated by solute atoms $1\\\\cdot11$, expressed in $\\\\|\\\\cdot\\\\|\\\\Pi\\\\mathbb{O}\\\\|^{-1}$ and $E V_{1}$ per atom. State the assumptions used in your estimation. The atomic radius of AI is $0.14317171$, shear modulus $G=2.5\\\\times10^{10}P a$, and Mg's $\\\\therefore\\\\frac{1}{2}$ axis length is $0.32\\\\mathrm{nm}$.", + "answer": "Assumption $\\\\boxed{1}$ the matrix is an isotropic continuous medium, $121$ solute atoms are far apart, and the stress field of each solute atom does not overlap. The misfit strain energy generated by solute atoms $N/E$ can be estimated using the following formula: \\n\\n$$ \\n\\\\Delta G_{x}=4G\\\\delta^{2}F^{\\\\prime} \\n$$ \\n\\nwhere $0.51$ lattice misfit is \\n\\n$$ \\n\\\\delta=\\\\frac{r_{\\\\mathrm{{Mg}}}-r_{\\\\mathrm{{Al}}}}{r_{\\\\mathrm{{Al}}}}=\\\\frac{0.16-0.143}{0.143}=0.1189 \\n$$ \\n\\n$\\\\int\\\\limits_{a}^{b}$ is the atomic volume of AI: \\n\\n$$ \\n\\\\begin{array}{l}{{{\\\\displaystyle{\\\\cal V}=\\\\frac{4}{3}\\\\pi v_{\\\\mathrm{Al}}^{3}=\\\\frac{4}{3}\\\\pi(0.143\\\\times10^{-9})^{3}=1.225\\\\times10^{-29}m^{3}}}}\\\\ {{{\\\\mathrm{}}}}\\\\ {{{\\\\Delta G_{\\\\mathrm{sl}}}=4G\\\\delta^{2}V=4\\\\times2.5\\\\times10^{10}\\\\times(0.1189)^{2}\\\\times1.225\\\\times10^{-29}J/a t=1.73\\\\times10^{-20}J/a t}}\\\\end{array} \\n$$ \\n\\nTherefore, \\n\\nsince $\\\\mathsf{I e V}{=}1.602\\\\times10^{-19}J$, \\n\\n$$ \\n\\\\Delta G_{*}=1.73\\\\times10^{-20}/1.602\\\\times10^{-19}{\\\\mathrm{~eV/at}}=0.108{\\\\mathrm{~eV/at}} \\n$$ \\n\\nMultiply the value expressed in $\\\\int\\\\limits_{0}^{1}\\\\frac{2}{c}d t$ by Avogadro's number $N_{10}$ to obtain the value in $\\\\vert11770-5\\\\vert$ units: \\n\\n$$ \\n\\\\Delta G_{_{x t}}=1.73\\\\times10^{-20}\\\\times6.025\\\\times10^{23}\\\\mathrm{J/mol}=10.4\\\\times10^{3}\\\\mathrm{J/mol} \\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括估计错配应变能、使用给定的公式和参数进行计算，并最终得出结果。答案中包含了详细的数学推导和单位转换，这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算，包括计算晶格失配度、应变能以及单位转换，同时需要理解并应用相关公式和假设。虽然不涉及复杂的综合分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步计算和概念关联。需要理解固溶体中的错配应变能计算，掌握原子半径、剪切模量等基本概念，并能正确应用公式进行单位转换和数值计算。虽然题目提供了计算公式和关键参数，但需要综合运用多个知识点才能得出正确答案。" + }, + { + "idx": 2463, + "question": "Estimate the number of clusters containing 10 atoms in 1cm³ of copper at its melting point temperature. The atomic volume of liquid copper is 1.6×10⁻²⁹m³, the surface energy is 0.177J/m², and the melting point is 1356K.", + "answer": "According to nᵢ = n exp(-ΔG / k_B T), first calculate the energy ΔG₁₀ of a 10-atom cluster. The radius of the cluster r = (3×10×1.6×10⁻²⁹ / 4π)^(1/3), and the surface area A₁₀ = 4πr² = 4π(3×10×1.6×10⁻²⁹ / 4π)^(2/3). ΔG₁₀ = A₁₀γ = 4π(3×10×1.6×10⁻²⁹ / 4π)^(2/3)×0.177 = 2.52×10⁻¹⁹J. The number of atoms per cm³ n = 1 / (1.6×10⁻²³) = 6.25×10²² cm⁻³. n₁₀ = 6.25×10²² exp(-2.52×10⁻¹⁹ / (1.38×10⁻²³×1356)) = 8.85×10¹⁰ cm⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算能量、半径、表面积等，并最终得出具体的数值结果。答案中展示了详细的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子团簇半径和表面积的计算、能量计算以及最终的数量估算。虽然涉及公式的直接应用，但需要理解各个参数之间的关系，并进行综合分析。题目还要求对材料科学中的表面能和原子体积等概念有一定的理解，但不需要进行复杂的机理分析或创新设计。 | 难度: 在选择题中属于高难度，题目涉及多步骤的复杂计算和多个物理概念的关联应用。解题过程需要计算原子团簇的半径和表面积，进而求解能量变化，最后应用玻尔兹曼分布公式计算团簇数量。每一步都需要精确的数学运算和对物理概念的深入理解，综合性强，计算复杂度高。" + }, + { + "idx": 2464, + "question": "Given that the shear moduli G of the parent phase and the precipitate phase are the same, and the parent phase is an isotropic continuous medium. If a coherent nucleus forms, derive the expression for the size at which the disc-shaped nucleus loses coherence during growth.", + "answer": "For a disc-shaped nucleus, let the radius be r and the thickness be t. Before coherence is lost, the sum of the misfit strain energy and the interfacial energy is πr^2t×4Gδ^2+2πr^2γ_ci0+2πrtγ_in. After coherence is lost, there is no misfit strain energy, and the disc interface changes from coherent to incoherent, so the energy becomes 2πr^2γ_in+2πrtγ_in. At the critical size, the energies of coherent and incoherent states should be equal, i.e., πr^2t*×4Gδ^2+2πr^2γ_ci0+2πrt*γ_in=2πr^2γ_in+2πrt*γ_in. Solving gives t*=(γ_in−γ_ci0)/(2Gδ^2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导一个表达式，涉及公式应用和数值计算，最终给出一个具体的解。答案展示了详细的推导过程和最终的数学表达式，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相干与非相干界面的能量变化，并推导临界尺寸的表达式。虽然不涉及复杂的综合分析或创新应用，但需要一定的推理和计算能力。 | 难度: 在选择题中属于高难度，需要理解多个复杂概念（如剪切模量、相干性、应变能等），进行多步骤计算（能量平衡方程的建立与求解），并综合分析临界尺寸的物理意义。题目涉及多变量计算和概念关联，对材料科学基础知识的掌握深度要求较高。" + }, + { + "idx": 2465, + "question": "For heterogeneous nucleation at grain boundaries (double spherical cap shape, with all interfaces being incoherent), what is the critical nucleus formation energy ΔGb*? Given the contact angle θ=50°, nucleation driving force ΔG1=5×10^8 J/m^3, and incoherent interface energy γin=0.5 J/m^2.", + "answer": "The calculation process for the critical nucleus formation energy ΔGb* is as follows: First, calculate the shape factor f(θ) = 0.5×(2-3cos50°+cos^3 50°) = 0.3125. The critical nucleus radius for homogeneous nucleation (spherical shape) rin* = 2γin/ΔG1 = 2×0.5/(5×10^8) m = 2×10^-9 m. The critical nucleus formation energy for homogeneous nucleation ΔGin* = (16π/3)(γin^3)/(ΔG1^2) = (16π/3)(0.5^3)/(5×10^8)^2 J = 8.37×10^-18 J. The critical nucleus formation energy for heterogeneous nucleation ΔGb* = f(θ)ΔGin* = 8.37×10^-18×0.3125 J = 2.615×10^-18 J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界核形成能量ΔGb*，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解异质成核的形状因子、临界核形成能的计算方法，并综合应用相关公式进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如异质形核、临界核形成能、接触角等）并进行多步骤计算（包括形状因子计算、临界核半径计算、均质形核能计算等）。虽然题目提供了具体数值和公式，但解题过程涉及多个变量和步骤的综合运用，对学生的计算能力和概念关联能力要求较高。" + }, + { + "idx": 2466, + "question": "What is the critical nucleation energy ΔG* when nucleation occurs as coherent disc-shaped particles within grains? Given the ratio of disc diameter to thickness D/N=10, the nucleation driving force ΔG1=5×10^8 J/m^3, the coherent interfacial energy γco=0.05×(1/17)^2, and the incoherent interfacial energy γin=0.5 J/m^2.", + "answer": "The calculation process for the critical nucleation energy ΔG* is as follows: The relationship between the disc radius r and thickness t is t = r/5. The disc volume equals πr^2t = πr^3/5. The disc top surface area equals πr^2, and the disc side surface area equals 2πrt = 2πr^2/5. The energy required for nucleation ΔG is ΔG = (πr^3/5)ΔG1 + 2πr^2γco + (2πr^2/5)γin. Differentiating with respect to r and setting it to zero, the critical size r* = (4×5γco + 4γin)/(3ΔG1) = (4×5×0.05 + 4×0.5)/(3×5×10^8) m = 2×10^-9 m. Substituting r* back into the ΔG equation, we obtain ΔG* = [-(π(2×10^-9)^3)/5 ×5×10^8 + 2π×(2×10^-9)^2×0.05 + (2π(2×10^-9)^2)/5×0.5] J = 1.26×10^-18 J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界成核能ΔG*，答案中包含了详细的数学推导和数值代入过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界成核能量的计算过程，并综合应用给定的参数和公式进行推导和计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题型中，该题目属于高难度等级。题目涉及多步骤的复杂计算过程，包括几何关系转换、能量方程建立、微分求极值以及多参数代入计算。解题者需要同时掌握形核理论、界面能概念和数学建模能力，并能够将这些知识综合应用于具体问题。计算过程中涉及多个变量的处理和单位转换，容易出现计算错误。这种复杂度和综合能力要求明显高于选择题型的平均水平，因此评定为等级4。" + }, + { + "idx": 2467, + "question": "What is the interdiffusion coefficient D for the A-B binary system at 550K with molar fractions x_A=0.6 and x_B=0.4, given D_B^AB=9×10^-12 cm²/s, D_A^AB=2×10^-12 cm²/s, and d²G/dx_B²=-95.325?", + "answer": "The interdiffusion coefficient D is calculated as D = (x_A * D_B^AB + x_B * D_A^AB) * (x_A * x_B / (R * T)) * (d²G/dx_B²) = (0.6 * 2×10^-16 + 0.4 * 9×10^-16) * (0.6 * 0.4 / (8.314 * 550)) * (-95.325) m²/s = -2.4×10^-18 m²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果。答案中包含了详细的公式应用和计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用给定的公式和参数，涉及不同变量的综合运用和单位转换。虽然不涉及复杂的推理分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于综合性计算问题，需要理解多个概念（如互扩散系数、摩尔分数、热力学参数等）并进行多步骤计算。虽然题目提供了所有必要参数，但计算过程涉及多个变量的组合和单位转换（如cm²/s到m²/s），要求考生具备较强的综合计算能力和概念关联能力。相比简单记忆或单步计算的选择题，这类题目在选择题型中属于较高难度。" + }, + { + "idx": 2468, + "question": "What are the similarities between polymer crystallization and metal crystallization in terms of the crystallization process?", + "answer": "Polymer crystallization and metal crystallization follow the general phase transition rules: 1 The crystallization process consists of nucleation and growth processes: (1) 1/2 Heterogeneous nucleation is dominant: (1-1) The kinetic equation has the same form as the Avrami equation: 4 Large undercooling results in small grain size. 5 The melting point of small particles is lower than that of large particles, exhibiting a Gibbs-Thomson-like effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物结晶和金属结晶在结晶过程中的相似之处，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较聚合物结晶和金属结晶过程的相似性，涉及多个概念（成核、生长、动力学方程、过冷度影响等）的关联和综合分析，需要理解并应用这些概念进行论述，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题中属于较高难度，题目要求考生对聚合物结晶和金属结晶的过程进行多角度分析，包括成核与生长过程、动力学方程形式、过冷度对晶粒尺寸的影响以及吉布斯-汤姆逊效应等多个方面的综合理解。需要考生具备较强的概念关联能力和综合分析能力，能够将不同知识点联系起来进行论述。" + }, + { + "idx": 2469, + "question": "For a silicon-containing low-alloy steel ingot with dendritic segregation and a dendrite arm spacing of 500μm, diffusion annealing is performed at 1200°C. To reduce the segregation amplitude to 10% of its original value, how long should the holding time be for carbon? Given that the diffusion coefficient of carbon in austenite at 1200°C is 2.23×10^(-6)cm^2/s.", + "answer": "When dendritic segregation exists, the solute composition is distributed with the dendrite arm spacing as the period, where the period l is 500μm=0.05cm. According to the trigonometric series solution of the diffusion equation, the concentration amplitude decays with a decay factor, i.e., C=C¯+C0sin(πx/l)exp(-π^2Dt/l^2). If the amplitude decays to 1/10 of its original value, then exp(-π^2Dt/l^2)=0.1. Therefore, the required time for carbon is: t=l^2/(π^2D)ln0.1=-(0.025)^2/(π^2×2.23×10^(-6))ln0.1s=65.3s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的保温时间，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，包括理解扩散方程的三角级数解、应用衰减因子公式、以及对数运算。虽然涉及的知识点较为明确，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的解法和浓度振幅衰减的概念，并进行多步计算。题目涉及三角函数解、指数衰减和时间计算，需要综合分析多个知识点才能得出正确答案。虽然计算步骤明确，但概念关联和公式应用要求较高，属于综合性计算问题。" + }, + { + "idx": 2470, + "question": "What cooling rate v is required to avoid spinodal decomposition at 550K when cooling from 850K to 550K, given the required time t=173.6 s?", + "answer": "The cooling rate v must be greater than (850K - 550K) / 173.6 s = 1.44 K/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算确定冷却速率，涉及具体数值运算和公式应用（(850K - 550K) / 173.6 s），答案也是具体的计算结果（1.44 K/s），符合计算题的特征。 | 知识层次: 题目涉及基本的冷却速率计算，仅需直接套用公式进行简单数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用和简单计算，即冷却速率的计算公式。学生只需将给定的温度差和时间代入公式即可得出答案，无需复杂的推理或多步骤计算。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2471, + "question": "What are the main differences in crystallization ability between polymer crystallization and metal crystallization?", + "answer": "Only thermoplastic polymers can crystallize. These polymers have a linear structure, and the crystallization process involves the arrangement of molecular chains from disorder to order, with no fixed melting temperature. Due to factors such as the long molecular chains, complex structure, and high melt viscosity of polymers, most polymer crystallizations are much slower than metal crystallizations and cannot fully crystallize, typically achieving a crystallinity of around 50%. The degree of crystallinity is closely related to the molecular structure of the polymer, and the more complex the structure, the more difficult it is to crystallize, often leading to the formation of a glassy state. Therefore, the ability of a polymer to form a crystalline state has an inverse relationship with its ability to form a glassy state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物结晶与金属结晶的主要区别，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求对聚合物和金属的结晶能力进行详细比较，涉及分子结构、结晶过程、熔融温度、结晶速度等多个方面的综合分析。需要深入理解聚合物和金属的结晶机理，并能解释不同材料结晶行为的差异。这属于复杂分析层次，需要综合运用多个知识点并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解聚合物和金属结晶的基本概念，还需要深入掌握两者在结晶能力上的具体差异及其背后的机理。正确选项涉及多个复杂因素的综合分析，包括分子结构、结晶速度、结晶度、玻璃态形成能力等，需要考生具备高度的综合运用和推理分析能力。此外，题目还要求考生理解这些因素之间的相互关系（如结晶能力与玻璃态形成能力的反比关系），这进一步增加了题目的复杂性和难度。因此，在选择题型内，该题目属于需要全面分析复杂现象的最高难度等级。" + }, + { + "idx": 2472, + "question": "What is the time t required for spinodal decomposition to occur over a diffusion distance of λ_m/2=50 nm (with λ_m=100 nm) at 550K, given the interdiffusion coefficient D=-2.4×10^-18 m²/s?", + "answer": "The time t required is calculated as t = (λ_m/2)² / (6D) = (50×10^-9)² / (6 * 2.4×10^-18) s = 173.6 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体计算，最终得出一个数值结果。解答过程涉及公式应用和数值代入，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及将已知数值代入公式求解时间，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式进行计算，即t = (λ_m/2)² / (6D)。解题步骤简单，无需多个公式组合或复杂的概念理解，属于单一公式直接计算的难度等级。" + }, + { + "idx": 2473, + "question": "A low-alloy steel ingot containing silicon exhibits dendritic segregation with a dendrite arm spacing of 500μm. After diffusion annealing at 1200°C, the segregation amplitude is reduced to 10% of its original value. How long should the holding time be for the silicon element? Assume the diffusion coefficient of silicon in austenite at 1200°C is 7.03×10^(-11)cm^2/s.", + "answer": "When dendritic segregation exists, the solute composition is distributed with the dendrite arm spacing as the period, where the period l is 500μm=0.05cm. According to the trigonometric series solution of the diffusion equation, the concentration amplitude decays with a decay factor, i.e., C=C¯+C0sin(πx/l)exp(-π^2Dt/l^2). If the amplitude decays to 1/10 of its original value, then exp(-π^2Dt/l^2)=0.1. Therefore, the required time for the Si element is: t=l^2/(π^2D)ln0.1=-(0.025)^2/(π^2×7.03×10^(-11))ln0.1s=2.07×10^6s. Since Si in Fe is a substitutional solute atom while C is an interstitial solute atom, the diffusion rate of Si atoms is much slower than that of C, so the homogenization time for Si is several orders of magnitude slower than that for C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解硅元素的保温时间，答案中包含了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解扩散方程的三角级数解、计算衰减因子、求解时间等。同时需要理解枝晶偏析的概念和扩散系数的影响，涉及概念关联和综合分析。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的解、三角函数级数解、衰减因子等概念，并进行多步计算（包括对数运算和单位转换）。虽然题目提供了关键参数，但需要综合运用材料科学和数学知识才能正确求解。相比单纯的概念选择题，这类计算题在选择题型中属于较复杂的类型。" + }, + { + "idx": 2475, + "question": "If two such subgrain boundaries merge to form one new subgrain boundary, by how much does the misorientation increase?", + "answer": "If two such subgrain boundaries merge to form one new subgrain boundary, the dislocation density at the grain boundary doubles. Since the misorientation is proportional to the dislocation density, the misorientation becomes 2 × 10^-3 radians.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两个亚晶界合并后取向差的变化，并给出具体的数值结果。答案不仅包含计算部分（2 × 10^-3 radians），还涉及对物理概念（位错密度与取向差的关系）的文字解释，符合简答题的特征。 | 知识层次: 题目需要理解亚晶界合并的机制，并应用位错密度与取向差的关系进行计算。虽然涉及基本概念，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及子晶界合并形成新晶界时的取向差变化，需要掌握位错密度与取向差之间的正比关系，并进行简单的乘法计算。虽然计算步骤不复杂，但需要将两个材料科学概念（晶界合并效应和位错-取向差关系）关联起来才能得出正确结论，这体现了中等应用层次的知识要求。" + }, + { + "idx": 2476, + "question": "If the stored energy is mainly contributed by dislocations, establish the relationship between dislocation density and critical nucleus size.", + "answer": "The energy of a dislocation per unit length is approximately Gb^2. Let the dislocation density be ρ, then the dislocation energy per unit volume is ρGb^2. If the stored energy E is mainly contributed by dislocations, the relationship between the critical nucleus radius and dislocation density is r* = 4γ/(ρGb^2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求建立关系并解释，答案提供了详细的文字解释和公式推导，符合简答题的特征 | 知识层次: 题目需要建立位错密度与临界核尺寸之间的关系，涉及位错能量计算和临界核半径公式的应用。虽然涉及基本概念（位错能量、临界核尺寸），但需要多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求建立位错密度与临界核尺寸之间的关系，这涉及到多个材料科学的核心概念，如位错能量、临界核半径等。其次，解题步骤较为复杂，需要理解位错能量与位错密度的关系，并将其与临界核尺寸的计算公式相结合。此外，题目要求综合分析多个概念并进行多步计算，这在选择题型中属于较为复杂的任务。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 2477, + "question": "How much energy is released before and after the merging?", + "answer": "The grain boundary energy per unit area after merging is 2θ E0(A - ln2θ), the energy of the two grain boundaries before merging is 2θ E0(A - lnθ), and the relative value of released energy after merging ΔE is ΔE = (2θ E0(A - lnθ) - 2θ E0(A - ln2θ))/(2θ E0(A - lnθ)) = (ln2θ - lnθ)/(0.5 - lnθ) = (ln(2 × 10^-3) - ln10^-3)/(0.5 - ln10^-3) = 9.35%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及公式的应用和推导，需要理解晶界能量变化的概念，并进行综合分析以得出最终的能量释放值。虽然不涉及复杂的机理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，要求考生能够理解并应用能量释放的计算公式，同时进行对数运算和百分比计算。虽然计算步骤较多，但在选择题型中，选项提供了明确的公式和计算路径，降低了部分难度。" + }, + { + "idx": 2478, + "question": "A copper block subjected to large cold deformation has a stored energy of 2×10^5 J·m^-3, and the typical value of high-angle boundary energy is 0.5 J·m^-2. According to the classical homogeneous nucleation theory, what is the critical nucleus size for recrystallization?", + "answer": "According to classical nucleation theory, the critical nucleus radius r* = 2γ/ΔG, where γ is the boundary energy and ΔG is the stored energy per unit volume. Substituting the boundary energy and stored energy, we obtain r* = (2×0.5)/(2×10^5) m = 5×10^-7 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和数据进行数值计算，最终得出一个具体的数值结果（临界核尺寸）。解答过程涉及公式应用和单位换算，符合计算题的特征。 | 知识层次: 题目主要涉及经典均质形核理论的基本公式应用，即通过给定的边界能和储存能直接套用公式计算临界核尺寸。虽然需要理解相关概念，但计算过程简单直接，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（r* = 2γ/ΔG）并进行简单的数值代入计算。解题步骤非常直接，无需多个公式组合或复杂的概念理解，属于最基础的难度等级。" + }, + { + "idx": 2479, + "question": "What are the basic characteristics of the Bravais lattice?", + "answer": "It has periodicity and symmetry, and each node is an equivalent point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释Bravais lattice的基本特征，答案以文字论述形式给出，不需要计算或选择选项 | 知识层次: 题目考查对Bravais晶格基本特征的定义和记忆，属于基础概念的理解和复述，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆并识别Bravais晶格的基本特征（周期性和对称性），属于最基础的定义简答层次。不需要复杂的解释或比较分析，只需直接回忆相关定义即可选择正确答案。" + }, + { + "idx": 2480, + "question": "If a nucleus with a radius of 2×10^-9 m is to be formed, what should the dislocation density at the nucleation site be? (G=4×10^10 Pa, b=0.25×10^-9 m)", + "answer": "If a nucleus with a radius of 2×10^-9 m is to be formed, the required dislocation density ρ is: ρ = 4γ/(r*Gb^2) = (4×0.5)/(2×10^-9×4×10^10×(0.25×10^-9)^2) m^-2 = 4×10^17 m^-2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的位错密度，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如位错密度、核形成半径、剪切模量等），但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如位错密度、核形成半径、材料常数等）并进行多步计算和综合分析。题目涉及公式推导和单位换算，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 2481, + "question": "Demonstrate why there are no fewer than 14 Bravais lattices", + "answer": "For any one of the 14 lattices, it is impossible to find a method of connecting nodes to form a new unit cell while preserving the symmetry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来证明为什么存在不少于14种布拉维格子，答案提供了详细的解释而非选择、判断或计算。 | 知识层次: 题目要求解释14种Bravais晶格存在的必然性，这需要深入理解晶体对称性和空间群的概念，并能够进行逻辑推理和分析。这不仅仅是记忆或简单应用，而是需要对晶体学原理有较深的理解和综合分析能力。 | 难度: 在选择题型内，该题目属于最高难度等级。正确选项要求考生不仅掌握14种布拉维晶格的基本概念，还需要深入理解晶格对称性和单元晶胞构建的复杂机理。题目涉及对晶体学对称操作（如旋转、反射、平移）的综合运用，以及通过推理分析证明\"无法通过节点连接形成新单元晶胞\"这一抽象结论。这种在选择题中要求对复杂现象进行全面分析的能力，远超单纯记忆或简单应用层面，属于材料科学晶体学领域的顶级认知要求。" + }, + { + "idx": 2482, + "question": "Comment on the possibility of classical nucleation. It is known that the dislocation density of heavily worked metallic materials is approximately 10^15 m^-2.", + "answer": "The dislocation density of heavily worked metallic materials is approximately 10^15 m^-2, making the formation of a critical nucleus of such size essentially impossible. The critical nucleus radius for classical nucleation discussed above is 5×10^-7 m, clearly indicating that nucleation cannot occur via the classical nucleation mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对经典成核的可能性进行评论，答案提供了详细的文字解释和论述，没有涉及计算、选择或判断对错。 | 知识层次: 题目要求对经典成核理论的可能性进行评论，需要结合位错密度和临界核半径的概念进行综合分析，涉及多知识点的关联和推理分析，思维过程深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要掌握经典成核理论的基本概念，还需要理解位错密度对成核过程的影响机制。正确选项涉及复杂的定量比较（10^15 m^-2位错密度与5×10^-7 m临界核半径的对比），需要考生进行跨尺度的物理概念整合和机理推理。此外，题目要求将材料加工状态（剧烈变形金属）与成核理论相结合，体现了对复杂现象的综合分析能力，这完全符合等级5\"复杂现象全面分析\"的标准。在选择题型中，这种需要多维度知识整合和定量分析的题目属于最具挑战性的类型。" + }, + { + "idx": 2483, + "question": "The subgrain boundaries formed after polygonization contain π edge dislocations, and the misorientation between subgrains is 10^-3 radians. Assuming there is no interaction between dislocations before polygonization, how much energy is released after polygonization (expressed as a percentage)? (The grain boundary energy E⊥-E0θ(A-1)=β, where A is set to 0.5)", + "answer": "Before polygonization, the dislocations have no interaction, meaning their energy is the same as when they exist independently. Assuming the dislocations are edge dislocations, the total energy E1 of these π dislocations when they exist separately is πEe, where Ee is the energy per unit length of an edge dislocation: Ee = (μb^2)/(4π(1-ν)) ln(R/r0) ≈ 10θ E0, where E0 = μb^2/(4π(1-ν)), and the approximation ln(R/r0) = 10 is used. After polygonization, the energy Eb of the grain boundary formed by these π dislocations per unit area is Eb = E0θ(0.5 - lnθ). The relative energy released per unit area of the grain boundary before and after polygonization compared to E1 is ΔE/E1 = (E1 - Eb)/E1 = (10θ E0 - E0θ(0.5 - lnθ))/(10θ E0) = (10 - 0.5 + ln10^-3)/10 = 25.99%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及能量释放的百分比计算，解答过程包含多个公式推导和数值代入。 | 知识层次: 题目涉及多步计算和概念关联，需要应用多个公式（如位错能量公式、晶界能量公式）并进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，题目涉及多个概念的理解和关联（如位错能量、亚晶界形成、能量释放计算等），并需要进行多步骤的计算（包括对数运算和百分比计算）。虽然题目提供了关键公式，但需要考生综合运用这些公式并正确代入数值（如θ=10^-3）才能得出最终答案。这种需要概念关联和综合计算的题目在选择题型中属于较复杂的类型。" + }, + { + "idx": 2484, + "question": "What is the lattice constant?", + "answer": "The lengths a, b, c of the three adjacent edges in a unit cell and the angles α, β, γ between these edges determine the size and shape of the unit cell. These six parameters are called the lattice constants.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“lattice constant”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即晶格常数的定义和描述，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别晶格常数的基本定义，属于基础概念记忆层次。正确选项直接给出了晶格常数的定义，没有涉及复杂的概念体系或需要深入理解的内容，因此属于最简单的难度等级。" + }, + { + "idx": 2485, + "question": "Demonstrate why there are no more than 14 Bravais lattices", + "answer": "If each crystal system includes four types of lattices: simple, face-centered, body-centered, and base-centered, the seven crystal systems would yield 28 Bravais lattices. However, some of these 28 can be connected to form one of the 14 lattices without changing the symmetry. For example, a body-centered monoclinic lattice can be connected to form a base-centered monoclinic lattice, so it is not a new lattice type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来证明为什么只有14种布拉维点阵，而不是简单的选择、判断或计算。答案提供了详细的解释和例子，符合简答题的特征。 | 知识层次: 题目要求解释为什么布拉维晶格不超过14种，这需要综合运用晶体学知识，包括晶体系统的对称性、晶格类型的转换以及对称性不变的条件。解答过程涉及对多种晶格类型的分析和比较，需要深入理解晶体结构的对称性和空间群的概念，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解Bravais晶格的基本概念，还需要综合运用晶体学对称性知识进行推理分析。正确选项涉及对7大晶系与4种点阵类型组合的全面分析（28种可能性），并能识别其中因对称性等效而简化的案例（如单斜晶系体心与底心的转换）。这种需要多维度知识整合和机理深度解释的题目，远超选择题型对简单知识再现或单一概念应用的要求，属于复杂现象全面分析的范畴。" + }, + { + "idx": 2486, + "question": "Write the specific indices of all equivalent crystal planes in the {123} plane family of the cubic crystal system", + "answer": "{123}=(123)+(123̄)+(1̄23)+(12̄3)+(132)+(13̄2)+(1̄32)+(132̄)+(213)+(21̄3)+(2̄13)+(213̄)+(231)+(231̄)+(2̄31)+(23̄1)+(312)+(31̄2)+(3̄12)+(312̄)+(321)+(321̄)+(3̄21)+(32̄1)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列举所有等效晶面指数，需要详细列出所有可能的组合，属于需要具体回答的简答题类型 | 知识层次: 题目要求识别立方晶系中{123}晶面族的所有等效晶面，这需要理解晶面指数的定义和立方晶系的对称性，并应用对称操作来推导所有等效晶面。虽然不涉及复杂的计算或综合分析，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生掌握立方晶系中晶面指数的基本概念和计算方法。其次，需要理解晶面族{123}的定义，即所有等效晶面的集合。解题过程中需要系统地列举所有可能的等效晶面，包括正负指数的组合和排列。这需要考生具备较强的空间想象能力和对晶体对称性的深入理解。虽然题目给出了正确选项，但考生仍需通过多步计算和综合分析才能确认所有等效晶面，这在选择题型中属于较为复杂的题目。" + }, + { + "idx": 2487, + "question": "Using BCC, FCC, and hexagonal lattices as examples, explain the similarities and differences between unit cells and primitive cells.", + "answer": "Both unit cells and primitive cells can reflect the periodicity of the lattice, meaning that infinite stacking of unit cells or primitive cells can reconstruct the entire lattice. However, unit cells are required to reflect the symmetry of the lattice, and the smallest volume unit under this premise is the unit cell; whereas primitive cells only require the smallest volume, and the primitive cells of Bravais lattices contain only one lattice point. For example: in a BCC unit cell, the number of lattice points is 2, while in a primitive cell it is 1; in an FCC unit cell, the number of lattice points is 4, while in a primitive cell it is 1; in a hexagonal lattice unit cell, the number of lattice points is 3, while in a primitive cell it is 1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来比较和说明单元晶胞和原始晶胞的相似性和差异性，答案也是以文字形式详细阐述了两者的特点和区别，符合简答题的特征。 | 知识层次: 题目要求解释和比较单元晶胞和原胞的相似性和差异性，涉及多个晶格类型（BCC、FCC和六方晶格）的具体分析。这需要学生不仅理解基本概念，还能将这些概念应用到不同的晶格结构中，并进行综合比较。虽然不涉及复杂的计算或深度推理，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅理解单元晶胞和原胞的基本定义，还需要能够具体分析BCC、FCC和六方晶系中这两种晶胞的异同点。解题步骤涉及多个概念的关联和对比，包括晶体的周期性、对称性要求以及不同晶系中晶格点的数量计算。此外，题目还要求考生能够将理论知识应用到具体晶体结构中，进行综合分析和说明。这些要求使得该题目在选择题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 2488, + "question": "Calculate the length of the [10 0] crystal direction in a hexagonal crystal (in units of lattice constants a and c)", + "answer": "The formula for the length of the [10 0] crystal direction in a hexagonal crystal: L = a", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方晶体中[10 0]晶向的长度，需要使用公式进行数值计算，答案给出了具体的计算公式和结果。 | 知识层次: 题目仅涉及基本公式的直接应用和简单计算，无需多步推理或综合分析 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（L = a）进行计算，无需任何额外的步骤或复杂的公式组合。属于单一公式直接计算的简单应用层次，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 2489, + "question": "Write all the equivalent crystallographic direction indices in the <123> direction family of the cubic crystal system", + "answer": "<123>=[123]+[1̄23]+[12̄3]+[123̄]+[132]+[1̄32]+[13̄2]+[132̄]+[213]+[2̄13]+[21̄3]+[213̄]+[231]+[2̄31]+[23̄1]+[231̄]+[312]+[3̄12]+[31̄2]+[312̄]+[321]+[3̄21]+[32̄1]+[321̄]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出立方晶系中<123>方向族的所有等效结晶学方向指数，需要列举所有可能的组合，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目要求写出立方晶系中<123>方向族的所有等效晶向指数，这需要理解晶向指数的定义和立方晶系的对称性，并能够应用对称操作生成所有等效方向。虽然不涉及复杂的计算或综合分析，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求掌握立方晶系中等效晶向指数的概念，这需要深入理解晶体学中的对称性操作。其次，解题过程涉及多步计算和排列组合，需要系统性地考虑所有可能的符号变化和指数排列。此外，题目还要求综合分析不同晶向之间的等效关系，这超出了简单记忆或单一概念应用的范畴。虽然题目提供了正确选项，但在选择题型中理解和验证这些选项的正确性仍然需要较高的认知能力和计算技巧。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 2490, + "question": "Calculate the length of the [11 0] crystal direction in a hexagonal crystal (in units of lattice constants a and c)", + "answer": "The formula for the length of the [11 0] crystal direction in a hexagonal crystal: L = a√3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方晶体中[11 0]晶向的长度，需要使用特定的公式进行数值计算，答案给出了具体的计算公式和结果形式。 | 知识层次: 题目要求应用基本公式计算六方晶体中[11 0]方向的长度，属于直接套用公式的简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用单一公式（L = a√3）进行计算，无需额外的公式组合或复杂推导。属于最基础的公式应用级别，符合等级1的单一公式直接计算标准。" + }, + { + "idx": 2491, + "question": "Calculate the length of the [0001] direction in a hexagonal crystal (in units of lattice constants a and c)", + "answer": "Formula for the length of the [0001] direction in a hexagonal crystal: L = c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方晶体中[0001]方向的长度，需要使用公式进行数值计算，答案是一个具体的计算结果（L = c），符合计算题的特征。 | 知识层次: 题目仅需要直接应用已知的公式（L = c）来计算[0001]方向的长度，无需多步计算或综合分析，属于基本公式的直接套用。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（L = c）进行计算，无需任何额外的步骤或组合公式。属于单一公式直接计算的简单应用层次，因此难度等级为1。" + }, + { + "idx": 2492, + "question": "Calculate the lengths L (in units of the unit cell edge a) of low-index crystallographic directions with indices not exceeding 3 in cubic crystals.", + "answer": "The length of a crystallographic direction is given by L=a·sqrt(u²+v²+w²), yielding:\\n<100>: 1\\n<110>: √2\\n<111>: √3\\n<200>: 2\\n<210>: √5\\n<211>: √6\\n<220>: 2√2\\n<221>: 3\\n<300>: 3\\n<310>: √10\\n<311>: √11\\n<222>: 2√3\\n<320>: √13\\n<321>: √14\\n<322>: √17\\n<330>: 3√2\\n<331>: √19\\n<332>: √22\\n<333>: 3√3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算立方晶体中低指数晶向的长度，需要使用给定的公式进行数值计算，答案也是具体的计算结果。 | 知识层次: 题目要求应用基本公式（L=a·sqrt(u²+v²+w²)）进行简单计算，涉及低指数晶向长度的直接计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用立方晶体中晶向长度的基本公式L=a·sqrt(u²+v²+w²)，但计算过程直接且无需组合多个公式。题目要求计算多个低指数晶向的长度，但每个计算都是独立的，步骤简单，属于选择题型中的中等偏低难度。" + }, + { + "idx": 2493, + "question": "How many lattice constants are there in each crystal system?", + "answer": "
Crystal SystemRelationships among a, b, c, α, β, γNumber of Lattice Constants
Triclinica≠b≠c, α≠β≠γ≠90°6 (a, b, c, α, β, γ)
Monoclinica≠b≠c, α=γ=90°≠β or α=β=90°≠γ4 (a, b, c, γ or a, b, c, β)
Orthorhombica≠b≠c, α=β=γ=90°3 (a, b, c)
Tetragonala=b≠c, α=β=γ=90°2 (a, c)
Cubica=b=c, α=β=γ=90°1 (a)
Hexagonala=b≠c, α=β=90°, γ=120°2 (a, c)
Rhombohedrala=b=c, α=β=γ≠90°2 (a, α)
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释每种晶系中的晶格常数数量，并以表格形式详细列出各晶系的关系和晶格常数数量，属于需要详细说明和论述的简答题类型。 | 知识层次: 题目考查对晶体系统中晶格常数数量的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个晶体系统的分类和对应的晶格常数数量，但题目已经以表格形式清晰列出了所有相关信息，考生只需根据记忆或理解进行匹配即可。不需要进行复杂的推导或分析，主要考察的是对基础概念的记忆和分类能力。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2494, + "question": "Calculate the interplanar spacings (in units of the unit cell edge length a) for low-index planes with indices not exceeding 3 in a cubic crystal.", + "answer": "The interplanar spacing is given by d=a/sqrt(h²+k²+l²), yielding:\\n{100}: 1\\n{110}: √2/2\\n{111}: √3/3\\n{200}: 1/2\\n{210}: √5/5\\n{211}: √6/6\\n{220}: √2/4\\n{221}: 1/3\\n{300}: 1/3\\n{310}: √10/10\\n{311}: √11/11\\n{222}: √3/6\\n{320}: √13/13\\n{321}: √14/14\\n{322}: √17/17\\n{330}: √2/6\\n{331}: √19/19\\n{332}: √22/22\\n{333}: √3/9", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算立方晶体中低指数晶面的晶面间距，需要使用给定的公式进行数值计算，并给出具体结果。答案形式为一系列计算得出的数值，符合计算题的特征。 | 知识层次: 题目要求应用基本的晶体学公式（d=a/sqrt(h²+k²+l²)）进行计算，属于直接套用公式的简单计算类型。虽然涉及多个晶面指数的计算，但每个计算步骤都是独立的，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要计算多个低指数晶面的面间距，但所有计算都是直接套用单一公式d=a/sqrt(h²+k²+l²)，没有复杂的推导或组合计算。题目要求的知识层次是简单应用，即基本公式的直接套用和简单计算，符合等级2的标准。" + }, + { + "idx": 2495, + "question": "Based on the stacking characteristics of FCC and HCP crystals, demonstrate that the sizes of octahedral and tetrahedral interstices in these two types of crystals must be the same.", + "answer": "Examining the (111) close-packed planes of FCC crystals and the (0001) close-packed planes of HCP crystals, it is found that the atomic arrangements of the two are identical. Further studying the adjacent two layers of close-packed planes reveals no difference in the way the layers fit together. In fact, only when examining three adjacent layers can the distinction between FCC and HCP be observed. However, both octahedral and tetrahedral interstices are only related to two layers of close-packed atoms. Therefore, for these two types of interstices, the microscopic environments provided by FCC and HCP are exactly the same, and their sizes must also be identical.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来证明FCC和HCP晶体中八面体和四面体间隙的大小必须相同，答案提供了详细的文字解释和逻辑推理，符合简答题的特征。 | 知识层次: 题目要求通过分析FCC和HCP晶体的堆垛特性，证明两种晶体中八面体和四面体间隙的大小必须相同。这需要深入理解晶体结构、堆垛顺序以及间隙形成的微观环境，并进行推理分析。涉及多个概念的关联和综合运用，思维过程较为复杂。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握FCC和HCP晶体结构的基本知识，还需要深入理解它们的堆垛特征和间隙类型。题目涉及对(111)和(0001)密排面的原子排列分析，以及多层堆垛的微观环境比较。解题需要综合运用晶体学知识，进行多层次的推理分析，并最终得出关于间隙尺寸的机理解释。这种深度和广度的知识运用在选择题型中属于最复杂的类型。" + }, + { + "idx": 2497, + "question": "Calculate the angles between low-index crystallographic directions with indices not exceeding 3 in cubic crystals (presented in a list)", + "answer": "Use the crystallographic direction angle formula cosθ=(u1u2+v1v2+w1w2)/sqrt((u1²+v1²+w1²)*(u2²+v2²+w2²)) to calculate. The angle between two crystallographic direction families may have multiple values depending on the selected directions. The specific calculation results need to list all crystallographic direction combinations with indices not exceeding 3 and their corresponding angles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用特定的公式计算立方晶体中低指数晶向之间的角度，并列出所有不超过3的晶向组合及其对应角度。这需要数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目要求应用立方晶体中低指数晶向间夹角的计算公式，涉及多步计算和不同晶向组合的综合分析。虽然公式本身是直接的，但需要列举所有指数不超过3的晶向组合并计算对应角度，这增加了复杂性和关联度，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要掌握立方晶体中晶向角度的计算公式，并能够正确应用该公式进行多步计算。题目要求列出所有指数不超过3的晶向组合及其对应角度，涉及多个变量的组合和计算，具有一定的综合性。虽然题目提供了明确的公式，但计算过程较为繁琐，需要较高的注意力和准确性。" + }, + { + "idx": 2498, + "question": "Compare the obtained results with the previous question", + "answer": "The obtained results are exactly the same as the previous question, only the crystal plane indices {hkl} are replaced with [uvw]. Superficially, this is because the formula for the angle between crystal directions is identical to that for the angle between crystal planes. Upon deeper analysis, it is found that the crystal direction [uvw] is the normal direction of the crystal plane (hkl), forming a perpendicular relationship. Therefore, the angle between two crystal planes is always equal to the angle between crystal directions with the same indices.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较和分析结果，答案提供了详细的文字解释和论述，涉及晶体学概念和关系的深入分析，符合简答题的特征。 | 知识层次: 题目不仅要求比较结果，还需要解释晶体学中晶面指数{hkl}与晶向指数[uvw]之间的关系，涉及公式的深层分析和垂直关系的理解，属于综合运用和推理分析的复杂层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2499, + "question": "Derive the four-index zone equation from the three-index zone equation of the hexagonal crystal system.", + "answer": "The three-index zone equation for the hexagonal crystal system is $H\\\\sqcup+K V+L W=0$; the plane (H K L) is converted to four-index $(\\\\textsf{h k i}\\\\textsf{l})$, with $\\\\forall=h,\\\\quad\\\\forall=k,\\\\quad\\\\mathsf{L}=1$; the direction [U $\\\\pmb{\\\\upnu}$ W] is converted to four-index $[u\\\\textbf{v t}\\\\pmb{w}]$, with $\\\\Psi=2{\\\\mathsf{u}}+{\\\\mathsf{v}},\\\\quad\\\\forall{\\\\mathsf{{\\\\mathbf{\\\\bar{\\\\alpha}}}}}2{\\\\mathsf{v}}+{\\\\mathsf{u}},\\\\quad\\\\forall{\\\\mathsf{I}}={\\\\mathsf{w}};$; substituting into the zone equation, we get ${\\\\sf h}\\\\left(2{\\\\sf u}+{\\\\sf v}\\\\right)+{\\\\sf k}\\\\left(2{\\\\sf v}+{\\\\sf u}\\\\right)+{\\\\sf I}{\\\\sf w}=0;$; substituting $\\\\dag=-(h+k)$, $\\\\mathtt{t=-\\\\tau(u+v)}$ into the above equation, we obtain ${\\\\mathsf{h}}{\\\\mathsf{u}}+{\\\\mathsf{k}}{\\\\mathsf{v}}+{\\\\mathsf{i}}{\\\\mathsf{t}}+{\\\\mathsf{I}}{\\\\mathsf{w}}=0{\\\\mathsf{c}}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过推导和解释，将三指数晶带方程转换为四指数晶带方程，答案包含详细的推导步骤和文字说明，属于需要论述和解释的简答题类型。 | 知识层次: 题目要求从三指数晶带方程推导出四指数晶带方程，涉及多步计算和概念关联，需要理解六方晶系的指数转换规则并进行适当的代数运算，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。题目要求从六方晶系的三指数晶带方程推导出四指数晶带方程，涉及多个步骤的转换和计算，包括平面指数和方向指数的转换，以及代数运算。此外，题目还要求理解六方晶系中不同指数表示方法之间的关系，并进行综合分析。这些步骤和概念关联使得题目在选择题型内相对复杂，需要较深的知识掌握和较高的解题能力。" + }, + { + "idx": 2500, + "question": "What is the bonding type of graphite?", + "answer": "Within the same layer of graphite, the bonding is covalent, while between adjacent layers, the bonding is van der Waals forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释石墨的键合类型，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对石墨键合类型的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及石墨的两种不同键合类型（层内共价键和层间范德华力），但正确选项已经明确给出了这两种键合类型的描述，不需要考生自行推导或分析。考生只需记忆并识别这两种键合类型即可作答。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 2501, + "question": "What is the crystal structure of diamond?", + "answer": "The crystal structure of diamond is FCC with tetrahedral interstices, where carbon atoms are located at the bonding points of the FCC lattice and four non-adjacent tetrahedral interstice positions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钻石的晶体结构，答案需要详细的文字描述和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对金刚石晶体结构这一基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并描述金刚石的晶体结构（FCC晶格和四面体间隙位置）。这比简单的定义记忆（等级1）要求更高，但尚未达到复杂概念体系阐述（等级3）的程度。考生需要掌握FCC晶格和四面体间隙的基本知识，并能正确描述碳原子的位置分布。" + }, + { + "idx": 2502, + "question": "What is the bonding type in diamond?", + "answer": "In diamond, carbon atoms are bonded by covalent bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钻石中的键合类型，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金刚石中碳原子键合类型的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题仅需记忆金刚石中碳原子的键合类型（共价键）这一基础定义，无需解释或比较其他键合类型，属于最基本的概念记忆题。" + }, + { + "idx": 2503, + "question": "What are the performance characteristics of diamond?", + "answer": "Diamond has high hardness and a dense structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钻石的性能特征，答案需要文字描述和论述，没有提供选项或要求计算 | 知识层次: 题目考查对钻石性能特征的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需要考生回忆钻石的基本性能特征（高硬度和致密结构）。在选择题型中，这属于最简单的直接回忆类题目，不需要任何解释、分析或推理过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2504, + "question": "What is the reason for the difference in property changes between short-period elements and long-period elements?", + "answer": "This is because the number of subshell electrons in the long-period transition elements also affects the properties of the elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释元素性质变化的原因，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释短周期元素和长周期元素性质差异的原因，涉及对元素周期表中不同周期元素电子排布和性质变化的深入理解，需要综合运用原子结构和周期律的知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2505, + "question": "What are the performance characteristics of graphite?", + "answer": "Graphite has a loose structure and certain electrical conductivity, and is commonly used as a lubricant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释石墨的性能特点，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查石墨的基本性能特征，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对石墨基本性能特征的记忆，属于基础概念的直接回忆。正确选项明确描述了石墨的结构特点和常见用途，无需复杂推理或概念间的关联分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2506, + "question": "Derive the conversion formula between the lattice constant $a_{R}$ in rhombohedral axes and the lattice constant $\\pmb{a}_{\\sf H}$ in hexagonal axes for a rhombohedral crystal.", + "answer": "Under $\\pmb{a}_{\\sf H}$, bH, $\\pmb{\\mathbb{G H}}$, $a_{R}=1/s$ [1 1], so the lattice constant $a_{R}=\\mathsf{L}$ $\\begin{array}{r l}&{=\\mathsf{a_{H}}\\bullet\\mathsf{s q r t}(\\mathsf{U}^{2}+\\mathsf{V}^{2}+\\mathsf{W}^{2}\\mathsf{c_{H}}^{2}/\\mathsf{a_{H}}^{2}-\\mathsf{U V})}\\ &{=\\V_{3}\\vee(3\\mathsf{a_{H}}^{2}+\\mathsf{c_{H}}^{2}),}\\end{array}$ Since ${\\pmb{\\upalpha}}_{\\aleph}$ is the angle between the crystallographic directions $\\%$ [1 1] and $\\%$ [121], the lattice constant $\\texttt{a}_{\\texttt{R}}$ $\\begin{array}{r l}{=\\mathsf{a r c o s}(c_{\\mathsf{G}_{\\mathsf{H}}}{}^{2}/\\mathsf{a}_{\\mathsf{H}}{}^{2}{}-3/2)/(3+\\mathsf{c}_{\\mathsf{H}}{}^{2}/\\mathsf{a}_{\\mathsf{H}}{}^{2})}\\ {=\\mathsf{a r c o s}(}&{(2\\mathsf{c}_{\\mathsf{H}}{}^{2}{}-3\\mathsf{a}_{\\mathsf{H}}{}^{2})/(6\\mathsf{a}_{\\mathsf{H}}{}^{2}+2\\mathsf{c}_{\\mathsf{H}}{}^{2}))\\circ}\\end{array}$ ) gives a H = aR·sqrt (2(1-cosα)); $c_{H}=a_{R}\\cdot\\mathsf{s q r t}(3(1+2\\cos\\theta)\\circ$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导晶格常数之间的转换公式，涉及数值计算和公式应用，答案中包含了具体的数学推导过程和公式转换，属于典型的计算题类型。 | 知识层次: 题目需要多步计算和概念关联，涉及不同晶系之间的转换公式推导，需要综合分析能力和对晶体学基础知识的理解。虽然不涉及复杂的机理解释或创新应用，但已经超出了简单应用的范围。 | 难度: 在选择题型内，该题目属于高难度等级。题目涉及复杂的多步计算和概念关联，需要深入理解晶格常数转换公式的推导过程。正确选项包含了多个数学运算和物理概念的结合，如向量运算、三角函数和晶格几何关系的综合分析。此外，题目还要求对六方晶系和菱方晶系之间的转换有清晰的认识，这在实际应用中属于较高层次的知识要求。因此，在选择题型中，该题目的难度属于复杂多变量计算的最高等级。" + }, + { + "idx": 2507, + "question": "Why do the properties of elements change periodically with atomic number?", + "answer": "Because the properties of elements are mainly determined by the number of outer valence electrons, and the number of valence electrons changes periodically with atomic number, thus reflecting the periodic changes in the properties of elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素性质随原子序数周期性变化的原因，答案需要文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对元素性质周期性变化的基本原理的理解和记忆，主要涉及外层价电子数与原子序数的关系这一基础概念，不需要复杂的推理或综合分析。 | 难度: 该题目在选择题型中属于中等难度。虽然题目涉及基础概念记忆，但需要理解元素性质周期性变化的原因，并能够将原子序数与价电子数的周期性变化联系起来。正确选项不仅要求记忆基本原理，还需要进行简单的概念解释和描述，因此难度高于基本定义简答的等级1，但尚未达到复杂概念体系阐述的等级3。" + }, + { + "idx": 2508, + "question": "What are the differences in the property changes between short-period elements and long-period elements?", + "answer": "The properties of long-period elements change more continuously and gradually, while the properties of short-period elements differ more significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释短周期元素和长周期元素在性质变化上的差异，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对元素周期表中短周期和长周期元素性质变化差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分短周期元素和长周期元素在性质变化上的差异。正确选项要求考生能够描述两种周期元素性质变化的特征，并进行简单比较。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2509, + "question": "Given the lattice constants of $\\mathsf{\\Omega}\\mathsf{a}-\\mathsf{A l}\\mathsf{\\Omega}_{2}\\mathsf{0}_{3}$ (rhombohedral crystal) as $\\mathtt{a}_{\\mathsf{R}}={\\mathsf{5}}.$ .12$\\mathring{\\mathbf{A}}$ 、 $a_{\\scriptscriptstyle\\textsf{R}}=55^{\\circ}17^{\\circ}$ ’, find its lattice constants $\\pmb{a}_{\\sf H}$ and $\\mathbf{GHo}$ in the hexagonal axes.", + "answer": "Using the formula from the previous question and substituting the values of aR and $\\texttt{a}_{\\texttt{R}}$, we obtain $a_{\\scriptscriptstyle\\ H}={\\bf\\nabla}4.75\\mathrm{~\\AA~}$ 、 $\\pmb{\\upalpha}_{\\mathsf{H}}=12.97\\mathrm{~\\AA~}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶格常数和角度，应用公式计算出六方晶系的晶格常数，答案也给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将菱方晶系的晶格常数转换为六方晶系的晶格常数，需要理解晶格常数之间的关系并应用相应的公式进行计算。虽然不涉及复杂的综合分析或机理解释，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构转换的基本概念，掌握多步计算公式，并能正确代入数值进行计算。题目涉及从菱方晶系到六方晶系的晶格常数转换，需要综合运用几何知识和数学计算能力，但选项提供了明确的公式指引，降低了部分难度。" + }, + { + "idx": 2510, + "question": "What is the crystal structure of graphite?", + "answer": "The crystal structure of graphite is a simple hexagonal lattice, with carbon atoms located at the lattice points.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释石墨的晶体结构，答案提供了详细的描述而非选择或判断 | 知识层次: 题目考查对石墨晶体结构这一基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆石墨的基本晶体结构（简单六方晶格），属于基础概念记忆层次。题目仅涉及单一知识点，无需复杂分析或比较，符合等级1的基本定义简答标准。" + }, + { + "idx": 2511, + "question": "Derive the conversion formula between the lattice constant $\\\\mathfrak{a}_{R}$ in rhombohedral axes and the lattice constant $\\\\pmb{\\\\complement H}$ in hexagonal axes for a rhombohedral crystal.", + "answer": "In $\\\\pmb{a}_{\\\\sf H}$, $b_H$, $\\\\pmb{\\\\mathbb{G H}}$, $a_{R}=1/s$ [1 1], so the lattice constant $a_{R}=\\\\mathsf{L}$ $\\\\begin{array}{r l}&{=\\\\mathsf{a_{H}}\\\\bullet\\\\mathsf{s q r t}(\\\\mathsf{U}^{2}+\\\\mathsf{V}^{2}+\\\\mathsf{W}^{2}\\\\mathsf{c_{H}}^{2}/\\\\mathsf{a_{H}}^{2}-\\\\mathsf{U V})}\\\\ &{=\\\\V_{3}\\\\vee(3\\\\mathsf{a_{H}}^{2}+\\\\mathsf{c_{H}}^{2}),}\\\\end{array}$ Also, since ${\\\\pmb{\\\\upalpha}}_{\\\\aleph}$ is the angle between the crystallographic directions $\\\\%$ [1 1] and $\\\\%$ [121], the lattice constant $\\\\texttt{a}_{\\\\texttt{R}}$ $\\\\begin{array}{r l}{=\\\\mathsf{a r c o s}(c_{\\\\mathsf{G}_{\\\\mathsf{H}}}{}^{2}/\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2}{}-3/2)/(3+\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}/\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2})}\\\\ {=\\\\mathsf{a r c o s}(}&{(2\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}{}-3\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2})/(6\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2}+2\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}))\\\\circ}\\\\end{array}$ ) gives $a_H = a_R\\\\cdot\\\\sqrt{2(1-\\\\cos\\\\alpha)}$; $c_{H}=a_{R}\\\\cdot\\\\mathsf{s q r t}(3(1+2\\\\cos\\\\theta)\\\\circ$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导晶格常数之间的转换公式，涉及数学推导和公式应用，答案中包含了具体的数学表达式和计算步骤，符合计算题的特征。 | 知识层次: 题目要求推导晶格常数在菱方和六方坐标系之间的转换公式，涉及多步计算和概念关联，需要综合分析不同坐标系之间的关系，并应用相关数学和晶体学知识。虽然不涉及复杂的机理或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题型内，该题目属于高难度等级。题目涉及复杂的多步计算和概念关联，需要深入理解晶格常数在菱方和六方坐标系之间的转换关系。解题过程不仅需要掌握基本的晶体学知识，还需要进行多变量计算和综合分析，包括向量运算、三角函数转换等高级数学操作。这些要求超出了选择题型中常见的简单概念识别或单步计算，属于复杂多变量计算范畴。" + }, + { + "idx": 2512, + "question": "Calculate the angles between low-index crystal planes with indices not exceeding 3 in cubic crystals (presented in a list). Why are the angles independent of the lattice constant?", + "answer": "Using the crystal plane angle formula $\\\\cos\\\\phi=(h_{1}h_{2}+k_{1}k_{2}+1,1,2)/\\\\{(h_{1}^{2}+k_{1}^{2}+1,^{2})\\\\ast(h_{2}^{2}+k_{2}^{2}+1,^{2}))$ to calculate. There may be multiple angles between two crystal plane families depending on the selected planes, only one is listed below, others are not discussed here.
cos in[100}[110}[111}[210}[211}[221}{310}
[100}1√2/2√3/32√5/5√ 6/32/33√10/10
[110}1√6/33√10/10√3/22√2/32√5/5
[111}1√15/52√2/35 √3/92√30/15
[210}1√30/62√5/57 √2/10
[211}17 √6/187 √15/30
[221}14√10/15
[310}1
The remaining results are omitted.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用特定的晶体平面角度公式进行计算，并给出了具体的计算步骤和结果表格，属于典型的计算题类型。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，虽然需要计算多个角度，但每个角度的计算都是直接套用给定的公式，没有涉及多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目要求计算多个低指数晶面之间的角度，但所有计算都基于同一个晶体平面角度公式，且题目已经提供了完整的计算表格，学生只需要理解并应用给定的公式即可完成。此外，题目还解释了角度与晶格常数无关的原因，这进一步降低了理解难度。因此，在选择题型内，该题目属于等级2难度，即简单公式应用计算。" + }, + { + "idx": 2513, + "question": "Discuss the significance of atomic radius in covalent crystals and its influencing factors, with examples", + "answer": "For covalent crystals, the atomic radius is defined as half the distance between the nearest neighboring atomic nuclei of the same element in the crystal. The type of bonding between atoms in covalent crystals—whether single, double, or triple bonds—will affect the atomic radius, so the largest single-bond atomic radius r(1) is generally used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论共价晶体中原子半径的意义及其影响因素，并提供例子，这需要详细的文字解释和论述，符合简答题的特征。答案也以论述形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求讨论共价晶体中原子半径的意义及其影响因素，并举例说明。这需要理解原子半径的定义，分析不同类型键合对原子半径的影响，并能将概念与实际例子关联起来。虽然涉及基础概念，但需要一定的综合分析能力和知识点的关联应用，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅要理解原子半径的基本定义，还需要掌握共价晶体中不同类型化学键对原子半径的影响，并能进行多角度分析（如单键、双键、三键的比较）。此外，题目要求考生能够将理论概念与实际例子关联起来，这需要较深入的综合分析能力，超出了简单记忆或单一概念应用的范畴。因此，在选择题型内属于较高难度等级。" + }, + { + "idx": 2514, + "question": "Discuss the significance of atomic radius in metal crystals and its influencing factors, and provide examples for illustration", + "answer": "For metal crystals, the atomic radius is defined as half the distance between the nuclei of nearest-neighbor atoms in the crystal of the same element. In metal crystals, the coordination number affects the atomic radius. For example, α-Fe (CN=8) has an atomic radius 3% smaller than that of γ-Fe (CN=12). Generally, the atomic radius for CN=12 is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论金属晶体中原子半径的重要性及其影响因素，并提供示例进行说明。答案以文字解释和论述的形式呈现，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求讨论原子半径在金属晶体中的重要性及其影响因素，并提供实例说明。这需要理解原子半径的定义、协调数对原子半径的影响，以及不同晶体结构（如α-Fe和γ-Fe）之间的比较。虽然涉及基础概念，但需要将这些概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型内，该题目要求考生不仅理解原子半径的基本定义，还需要掌握配位数对原子半径的影响，并能通过具体例子（α-Fe和γ-Fe）进行多角度分析。此外，题目还涉及不同配位数下原子半径的通用标准，需要考生进行综合论述和比较分析，因此属于较高难度等级。" + }, + { + "idx": 2515, + "question": "Discuss the significance of atomic radius in molecular crystals of nonmetals and its influencing factors, with examples provided.", + "answer": "For molecular crystals of nonmetals, there exist two atomic radii: one is the covalent radius, and the other is the van der Waals atomic radius (half the distance between adjacent molecules). For example, in the chlorine molecular crystal, the two radii are 0.099nm and 0.180nm, respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论非金属分子晶体中原子半径的重要性及其影响因素，并提供例子。答案提供了详细的文字解释和具体例子，符合简答题的特征。 | 知识层次: 题目要求讨论非金属分子晶体中原子半径的意义及其影响因素，并提供例子。这需要理解原子半径的概念（包括共价半径和范德华半径），并能将其应用于具体实例（如氯分子晶体）。虽然涉及基础概念，但需要将这些概念关联起来进行综合分析，并举例说明，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解非金属分子晶体中原子半径的概念（共价半径和范德华半径），还需要能够区分两者并举例说明具体数值。这涉及多角度分析（共价键与分子间作用力的差异）和具体实例的应用（氯分子晶体的数据），属于较高层次的综合分析能力要求。虽然题目提供了正确选项，但需要考生具备扎实的概念基础和实例关联能力才能准确选择。" + }, + { + "idx": 2516, + "question": "Explain the term: component", + "answer": "Each element (metal, non-metal) that constitutes an alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"component\"，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对“component”这一术语的定义进行解释，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求识别\"component\"的基本定义（合金的构成元素），属于最基础的概念记忆层面。正确选项直接给出了术语的明确定义，不需要任何解释、比较或推理过程，完全符合等级1\"基本定义简答\"的标准。这类题目只需考生记住最基础的专业术语定义即可作答。" + }, + { + "idx": 2517, + "question": "Explain the term: alloy", + "answer": "A material formed by the chemical bonding of a metal with one or more other elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"alloy\"，答案是一个文字解释和论述，没有选项、判断或计算的要求 | 知识层次: 题目考查基本概念的记忆和理解，即合金的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别合金的基本定义，属于最基础的概念记忆层次。题目不涉及任何解释、分析或比较过程，只需直接回忆并选择正确的定义描述。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2518, + "question": "Explain the term: sublattice", + "answer": "The respective Bravais lattices occupied by the constituent atoms in an ordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"sublattice\"，需要文字解释和论述，答案也是以文字形式给出的定义说明 | 知识层次: 题目考查对\"sublattice\"这一基本概念的定义和记忆，属于材料科学中晶体结构的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生对\"sublattice\"这一术语进行概念解释和描述，属于基础概念记忆层次。虽然需要理解并准确描述该术语的定义，但并不涉及复杂的概念体系阐述或多概念比较分析，因此在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 2519, + "question": "Explain the term: intermetallic compound", + "answer": "A compound formed between metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"intermetallic compound\"，需要文字解释和论述，答案形式为简短的定义性陈述。 | 知识层次: 题目考查基本概念的记忆和理解，仅需要解释intermetallic compound的定义，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求识别和记忆\"intermetallic compound\"的基本定义，属于最基础的概念记忆层次。正确选项直接给出了术语的简单定义，不需要任何解释、分析或推理过程。这种题目在选择题中属于最简单的类型，只需基础概念记忆即可作答。" + }, + { + "idx": 2520, + "question": "Explain the term: microstructure", + "answer": "Under certain external conditions, the collective of several different phases that constitute an alloy of a certain composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"microstructure\"，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对\"microstructure\"这一基本概念的定义和记忆，属于材料科学中最基础的概念之一，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求对\"microstructure\"这一基础概念进行定义记忆，属于最基础的定义简答层次。正确选项直接给出了标准定义，不需要进行概念比较或复杂分析，符合等级1的基本特征。" + }, + { + "idx": 2521, + "question": "Discuss the significance of atomic radius in ionic crystals and its influencing factors, with examples provided.", + "answer": "For ionic crystals, the sizes of cations and anions are represented by ionic radii r+ and r-, respectively. Assuming that the same ion has the same radius in different ionic crystals, the ionic radius can be roughly determined. However, the ionic radius is only an approximate concept, as electrons cannot completely detach from the cation. Therefore, many ionic bonds have more or less covalent character. When this feature is particularly prominent, the significance of the ionic radius becomes less precise.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论离子晶体中原子半径的重要性及其影响因素，并提供例子。答案是一段详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求讨论离子晶体中原子半径的意义及其影响因素，并提供例子。这需要理解离子半径的概念，分析其在离子晶体中的重要性，以及影响离子半径的因素，如电子构型、配位数等。此外，还需要能够举例说明，这涉及到概念之间的关联和综合分析。虽然不涉及复杂的计算或创新设计，但需要一定的理解和应用能力，超出了单纯的基础概念记忆。 | 难度: 在选择题型内，该题目需要考生理解并分析离子晶体中原子半径的重要性及其影响因素，同时要求能够关联多个概念（如离子半径、共价特性等）进行综合论述。题目不仅涉及基础概念的记忆，还需要进行多角度分析，属于较高难度的选择题。" + }, + { + "idx": 2523, + "question": "Explain the term: solid solution", + "answer": "The atoms of the solute and the solvent occupy a common Bravais lattice, and this lattice type is the same as that of the solvent; the content of the components can vary within a certain range without causing a change in the lattice type. Metal or non-metal compounds possessing these two properties are called solid solutions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"solid solution\"，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对“solid solution”这一基本概念的定义和特性的记忆和理解，不涉及应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释\"solid solution\"这一概念，但正确选项提供了较为详细的定义和关键特征描述，包括溶质和溶剂原子占据共同的Bravais晶格、晶格类型与溶剂相同、组分含量可在一定范围内变化等。这超出了简单定义记忆（等级1），但尚未达到需要阐述复杂概念体系（等级3）的程度。学生需要理解并记忆这些关键特征，但不需要进行复杂的分析或比较。" + }, + { + "idx": 2524, + "question": "Explain the term: phase", + "answer": "A portion or region within an alloy that has the same (or continuously varying) composition, structure, and properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"phase\"，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"phase\"这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"phase\"的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了术语的标准定义，不需要任何解释、分析或比较过程，完全符合等级1\"基本定义简答\"的难度标准。" + }, + { + "idx": 2525, + "question": "Explain the term: electronegativity", + "answer": "A parameter indicating the ability of an element to attract electrons when forming compounds or solid solutions with other elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"electronegativity\"，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对电负性这一基本概念的定义和记忆，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"电负性\"的基本定义，属于最基础的概念记忆层次。正确选项直接给出了标准定义，不需要进行任何解释、比较或分析，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 2526, + "question": "Explain the term: electron concentration", + "answer": "The average number of valence electrons per atom in an alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"electron concentration\"，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，仅需解释电子浓度的定义，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆并选择电子浓度的基本定义，属于基础概念的直接回忆，无需复杂分析或推理步骤。" + }, + { + "idx": 2527, + "question": "Explain the term: superstructure (superlattice)", + "answer": "A complex lattice composed of the sublattices of each component in an ordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"superstructure (superlattice)\"，答案是一个文字解释和论述，没有选项、判断或计算要求。 | 知识层次: 题目考查对\"superstructure (superlattice)\"这一术语的基本定义和概念的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅知道\"超结构\"的基本定义，还需要理解其组成原理（由有序固溶体中各组分的亚晶格构成）。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的等级3。属于需要概念解释和描述的中间难度等级。" + }, + { + "idx": 2530, + "question": "How to theoretically determine the order-disorder transition temperature (Curie temperature)?", + "answer": "Theoretically, the transition temperature of ordered alloys can be determined by the relationship between the strength of metallic bonds and the magnitude of the average molecular free energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过理论方法解释如何确定有序-无序转变温度（居里温度），答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求理论推导有序-无序转变温度（居里温度），涉及金属键强度与分子自由能关系的综合分析，需要深入理解相变机理和热力学原理，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用金属键强度和分子自由能等复杂概念，通过理论分析推导有序合金的相变温度（居里温度）。这需要深入理解材料科学中的热力学和键合理论，并能将多个高阶概念联系起来进行推理判断。选择题型中仅凭正确选项评估，此类涉及机理深度解释和复杂现象分析的题目对考生的知识掌握深度和逻辑推理能力要求极高，属于选择题型中最具挑战性的类型。" + }, + { + "idx": 2531, + "question": "Briefly describe the influence of electronegativity difference on solid solubility according to the Hume-Rothery rules", + "answer": "If the electronegativity difference between alloy components is large, the solid solubility is extremely small.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述电负性差异对固溶度的影响，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则中电负性差对固溶度影响的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（Hume-Rothery规则），但需要考生理解并描述电负性差异对固溶度的影响机制，而不仅仅是简单的定义复述。正确选项要求考生能够将电负性差异与固溶度之间的因果关系联系起来，这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 2532, + "question": "Briefly describe the practical significance of the Hume-Rothery rules", + "answer": "Although the Hume-Rothery rules are only negative rules, qualitative or semi-quantitative rules, and the latter three are limited to specific situations, they summarize some patterns of alloy solid solubility, helping to predict the extent of solid solubility. Thus, they are highly useful for determining the properties and heat treatment behavior of alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Hume-Rothery规则的实际意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则的基本理解和记忆，包括其性质（定性或半定量规则）和实际意义（预测固溶度范围、确定合金性能和热处理行为）。虽然涉及一些应用层面的解释，但整体上属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目要求考生对Hume-Rothery规则的实际意义进行解释和描述，而不仅仅是记忆基本定义。虽然题目涉及的知识点属于基础概念记忆层次，但需要考生理解并简要总结这些规则的局限性和实用价值，这比单纯记忆定义要复杂一些。因此，该题目在选择题型中属于中等难度（等级2）。" + }, + { + "idx": 2533, + "question": "Briefly describe the law of solid solubility of specific group elements in the Hume-Rothery rules", + "answer": "The solid solubility of solute elements from groups 11B to VB in solvent elements of group IB is the same (θ/a=1.36), regardless of the specific element types.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Hume-Rothery规则中特定族元素的固溶度定律，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则中特定组元素固溶度定律的基本概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生描述Hume-Rothery规则中特定族元素固溶度的定律，属于概念解释和描述的层次。虽然涉及一定的记忆性知识，但不需要复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 2534, + "question": "Briefly describe the influence of atomic valence on solid solubility according to the Hume-Rothery rules", + "answer": "The solid solubility of two elements is related to their atomic valence. The solubility of a high-valence element in a low-valence element is greater than that of a low-valence element in a high-valence element.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述原子价对固溶度的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则中原子价对固溶度影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及Hume-Rothery规则的基础概念记忆，但需要考生理解并描述原子价对固溶度的影响关系，而不仅仅是简单的定义记忆。正确选项要求考生能够解释两种不同价态元素之间的固溶度差异，这需要一定的概念理解和描述能力，但不需要复杂的分析或比较多个概念体系。" + }, + { + "idx": 2535, + "question": "Briefly describe the influence of atomic radius difference on solid solubility according to the Hume-Rothery rules", + "answer": "If the difference in atomic radii of the elements forming the alloy exceeds 14%~15%, the solid solubility is extremely limited.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述原子半径差异对固溶度的影响，需要文字解释和论述，而不是选择、判断或计算。答案也是以文字形式给出的解释性陈述。 | 知识层次: 题目考查Hume-Rothery规则中原子半径差异对固溶度影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（Hume-Rothery规则），但需要考生不仅记住原子半径差异的百分比限制（14%~15%），还要理解这一数值对固溶度的具体影响（\"extremely limited\"）。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述或比较分析（等级3）。题目正确选项完整呈现了概念解释和描述层面的知识，符合等级2的难度特征。" + }, + { + "idx": 2536, + "question": "Using the Darken-Gurry diagram to analyze elements that may have relatively high solid solubility in Mg", + "answer": "Possible elements include Cd, Nb, Ti, Ce, Hf, Zr, Am, P, Sc, and lanthanides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析并列举可能具有较高固溶度的元素，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求使用Darken-Gurry图来分析元素在Mg中的固溶度，这需要理解Darken-Gurry图的基本原理，并能够将其应用于具体元素的分析。虽然不涉及复杂的计算或深度推理，但需要对多个元素的性质进行综合比较和判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求使用Darken-Gurry图来分析元素在Mg中的固溶度，这需要学生掌握该图的基本原理和应用方法。其次，正确选项中列出了多个可能的元素，学生需要理解这些元素的原子半径和电负性与Mg的匹配程度，才能做出正确选择。此外，题目涉及的元素种类较多，包括镧系元素和过渡金属等，增加了分析的复杂性。因此，该题目在选择题型中属于需要多角度分析和综合判断的较高难度题目。" + }, + { + "idx": 2537, + "question": "What is the relationship between the mechanical properties of a solid solution and those of its pure components? Please provide a qualitative explanation.", + "answer": "The strength and hardness of a solid solution are often higher than those of its components, while the plasticity is lower. This is because: (1) For interstitial solid solutions, solute atoms tend to preferentially distribute along dislocation lines, forming interstitial atom 'atmospheres' that firmly pin the dislocations, thereby strengthening the material; (2) For substitutional solid solutions, solute atoms are usually uniformly distributed within the lattice, causing lattice distortion, which increases the resistance to dislocation motion, though this strengthening effect is relatively smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对固溶体与其纯组分机械性能之间的关系进行定性解释，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求对固溶体机械性能与其纯组分之间的关系进行定性解释，涉及对位错钉扎、晶格畸变等机理的分析和推理，需要综合运用材料科学中的多个概念并进行关联分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2538, + "question": "What is Vegard's law?", + "answer": "Experiments have found that when two isomorphous salts form a continuous solid solution, the lattice constant of the solid solution has a linear relationship with the composition, meaning the lattice constant is proportional to the concentration of any component. This is Vegard's law.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Vegard's law的定义和内容，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Vegard's law的基本定义和原理，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目涉及Vegard's law的定义，但正确选项提供了较为详细的解释，包括实验发现、线性关系和比例关系等关键要素，超出了简单定义的范围。然而，题目并未要求考生进行复杂的概念体系阐述或比较分析，因此属于中等难度。" + }, + { + "idx": 2539, + "question": "Briefly describe the influence of crystal structure on solubility according to the Hume-Rothery rules", + "answer": "Only when the two components have the same crystal structure can they form an infinite (or continuous) solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述晶体结构对溶解度的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对Hume-Rothery规则中晶体结构对溶解度影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是Hume-Rothery规则的基础概念记忆，但需要考生理解并描述晶体结构对溶解度的具体影响，而不仅仅是简单的定义复述。题目要求考生能够将基本原理与具体现象联系起来，属于\"概念解释和描述\"层次的知识运用。" + }, + { + "idx": 2540, + "question": "Why do real solid solutions often not conform to Vegard's law?", + "answer": "Because Vegard's law reflects the influence of composition on the structure of alloy phases, but the structure of alloy phases is affected not only by composition but also by other factors (such as electron concentration, electronegativity, etc.), which cause real solid solutions to deviate from Vegard's law.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么实际固溶体常常不符合Vegard定律，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释为什么实际固溶体不符合Vegard定律，这需要理解Vegard定律的基本原理，并分析影响合金相结构的多种因素（如电子浓度、电负性等），涉及多因素的综合分析和机理解释，思维深度较高。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解Vegard's law的基本概念，还需要综合运用多个影响因素（如电子浓度、电负性等）来解释实际固溶体偏离该定律的原因。这需要考生具备深入的材料科学机理知识，能够进行复杂现象的全面分析和推理，属于选择题型中要求较高的综合分析和机理解释能力。" + }, + { + "idx": 2541, + "question": "What is the relationship between the physical properties of a solid solution and those of the pure components? Please provide a qualitative explanation.", + "answer": "The electrical, thermal, magnetic, and other physical properties of a solid solution also change continuously with composition, but generally not in a linear relationship. This is because solute atoms usually disrupt the original physical properties of the solvent. However, when the alloy is in an ordered state, the physical properties undergo abrupt changes, exhibiting superior physical performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对固溶体的物理性质与纯组分之间的关系进行定性解释，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求对固溶体的物理性质与纯组分之间的关系进行定性解释，涉及多个物理性质（电学、热学、磁学等）的综合分析，并需要理解固溶体有序状态对物理性质的突变影响。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解固溶体的物理性质变化规律，还需要掌握非线性变化的原因（溶质原子对溶剂性质的干扰）以及有序状态下的突变现象。这需要综合运用材料科学、固体物理和热力学知识进行复杂分析，远远超出了简单记忆或单一概念应用的范畴。正确选项涉及多个层次的机理解释和现象分析，在选择题型中属于对知识深度和综合能力要求极高的题目。" + }, + { + "idx": 2542, + "question": "Discuss the general rules of oxide structures.", + "answer": "An important characteristic of oxide structures is the close packing of oxygen ions. In most simple oxide structures, oxygen ions are arranged in face-centered cubic, hexagonal close-packed, or approximately close-packed simple cubic configurations, while the cations occupy octahedral interstitial sites, tetrahedral interstitial sites, or the body center of the simple cubic lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求讨论氧化物结构的一般规则，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对氧化物结构基本规则的理解和记忆，涉及氧离子的紧密堆积方式及阳离子占据的间隙位置等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及氧化物结构的基本规则，但正确选项需要考生理解并记忆氧离子的紧密堆积方式（如面心立方、六方紧密堆积等）以及阳离子占据的间隙位置（如八面体间隙、四面体间隙等）。这超出了简单的定义记忆，需要对相关概念有一定的理解和描述能力。然而，题目并未要求考生进行复杂的比较分析或推导，因此难度等级为2。" + }, + { + "idx": 2543, + "question": "Analyze the crystal structure of rutile using Pauling's rules", + "answer": "For rutile: (1) The cation-anion radius ratio is 0.48. According to Table 2-8 on page 104 of the textbook, it can be seen that the anion polyhedron is an octahedron, and the cation coordination number is 6; (2) Z+=4, Z-=2, so CN-=CN+•Z-/Z+=6/2=3.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析金红石的晶体结构，并应用Pauling规则进行解释。答案提供了详细的文字解释和计算过程，符合简答题的特征。 | 知识层次: 题目要求应用Pauling's规则分析金红石的晶体结构，涉及多步计算（如阳离子-阴离子半径比、配位数计算）和概念关联（如半径比与配位数的关系、电荷平衡计算）。虽然不涉及复杂的推理或机理解释，但需要综合分析多个知识点并正确应用规则。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 2544, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of the main factors determining their structures and theoretical foundations.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Electronegativity, electron shell theoryElectron concentration, electron theoryComponent atomic radius ratio, topologyComponent atomic radius ratio, spatial geometry
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同金属间化合物进行总结和比较，需要文字解释和论述，答案以表格形式呈现了不同化合物的理论基础和决定因素，符合简答题的特征。 | 知识层次: 题目要求对不同类型金属间化合物的结构决定因素和理论基础进行总结和比较，这需要综合运用多个知识点，进行概念关联和综合分析。涉及电子理论、拓扑学、空间几何等多方面知识的整合，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2545, + "question": "Describe Pauling's rules regarding the structure of ionic compounds", + "answer": "(1) A coordination polyhedron of anions is formed around the cation, with the distance between the cation and anion determined by the sum of their ionic radii, and the coordination number determined by the ratio of the cation to anion radii; (2) The number of valence electrons provided by the cation equals the number of valence electrons received by the anion, hence Z+/CN+=Z-/CN-; (3) In a coordination structure, when coordination polyhedra share edges, especially faces, their stability decreases, and this effect is more pronounced for cations with higher valence and lower coordination numbers; (4) In crystals containing more than one type of cation, the coordination polyhedra of anions around cations with higher valence and smaller coordination numbers tend to connect by sharing vertices; (5) The types of coordination polyhedra in a crystal tend to be minimized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述Pauling关于离子化合物结构的规则，需要文字解释和论述，答案以列举要点形式呈现，符合简答题的特征 | 知识层次: 题目要求描述Pauling规则，属于对基本原理的记忆性知识，主要考查学生对基础概念的理解和记忆能力，不涉及复杂的应用或分析过程。 | 难度: 在选择题中属于高难度，题目要求描述Pauling规则，涉及多个复杂概念和原理的综合阐述，包括离子半径比、配位数、配位多面体的稳定性、高电荷阳离子的配位多面体连接方式以及晶体中配位多面体类型的最小化等。这些内容不仅需要记忆，还需要深入理解和整合多个相关概念，因此在选择题型中属于较高难度。" + }, + { + "idx": 2546, + "question": "Summarize and compare the performance characteristics of various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds)", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Non-metallic or semiconducting propertiesDistinct metallic characteristicsHard and brittle phases, Cr3Si-type structure alloys mostly exhibit superconducting propertiesWide mutual solid solubility range, distinct metallic properties, very high melting points, extremely high hardness and brittleness
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型的金属间化合物的性能特征进行总结和比较，需要文字解释和论述，答案以表格形式呈现了详细的比较信息，符合简答题的特征。 | 知识层次: 题目要求对不同类型金属间化合物的性能特征进行总结和比较，这需要综合运用多个知识点，包括各类化合物的结构特点、物理和化学性质等，并进行对比分析。这种题目不仅考查记忆和理解，还需要较高层次的分析和综合能力。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2547, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of their constituent elements.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Metal and metal, metal and metalloidElements, Group VII (ironSmall metal elementsGroup metal elements and atomic radii
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，需要文字解释和论述，答案以表格形式呈现了各类化合物的构成元素，符合简答题的特征 | 知识层次: 题目要求对不同金属间化合物进行总结和比较，涉及多个概念的综合分析和关联，需要理解各类化合物的组成元素特点并进行对比，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对多种金属间化合物（如价化合物、电子化合物、TCP相、间隙相等）的组成元素进行总结和比较。这需要考生不仅掌握各个化合物的基本概念，还需要能够综合分析不同化合物的组成特点，并进行横向对比。题目涉及的知识点较为深入，且需要多步思维过程来关联和区分不同化合物的特性，因此在选择题型中属于较高难度。" + }, + { + "idx": 2548, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of their structural characteristics", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Transfer or sharing to form stable 8-electronStructure mainly determined by electron concentrationStacked in a certain order by close-packed tetrahedronsFCC or CPH structure, metalloid atoms located in tetrahedral
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，需要文字解释和论述，答案以表格形式呈现了各种化合物的结构特征，符合简答题的特点 | 知识层次: 题目要求对不同类型的金属间化合物进行总结和比较，涉及多个概念（价化合物、电子化合物、TCP相、间隙相等）的结构特征分析，需要综合理解和关联这些概念，并进行比较分析。这超出了单纯记忆的范畴，属于中等应用层次的知识要求。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握多种金属间化合物的基本概念，还需要能够比较和分析它们在结构特征上的差异。题目涉及的知识点较为复杂，包括电子化合物、TCP相、间隙相等多个概念的综合运用。此外，正确选项以表格形式呈现，要求考生能够准确匹配每种化合物的结构特征，这增加了题目的复杂度和难度。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 2549, + "question": "What are the main types of silicate structures?", + "answer": "The main types of silicate structures can be classified according to the spatial arrangement of silicon-oxygen tetrahedra into: island, chain, sheet, and framework.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举硅酸盐结构的主要类型，答案以文字叙述形式给出，不需要计算或选择选项 | 知识层次: 题目考查对硅酸盐结构基本分类的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然涉及的是基础概念记忆（硅酸盐结构的分类），但需要考生准确回忆并区分四种不同的空间排列方式（岛状、链状、片状和架状）。这比单纯记忆单一定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。选择题型中，这类题目通常表现为让考生从选项中识别正确的分类描述，属于概念解释和描述的难度层级。" + }, + { + "idx": 2550, + "question": "Given that the outer surface of a copper single crystal sample is (111), analyze the possible angles between slip lines that may appear on this outer surface when the crystal undergoes slip at room temperature.", + "answer": "The possible slip planes are the {111} family of crystal planes, and their intersections with the (111) plane may be [ 10], [0 1], [10 ], so the slip lines are either parallel or at a 60-degree angle to each other.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析铜单晶样品在特定条件下可能出现的滑移线角度，需要基于晶体学知识进行解释和论述，答案也以文字解释形式给出，没有涉及计算或选择判断。 | 知识层次: 题目要求分析铜单晶样品在特定表面(111)上可能出现的滑移线角度，需要理解晶体滑移的基本原理（{111}滑移面族），并能将滑移面与特定表面相交的情况进行综合分析。这涉及多步概念关联和几何分析，但不需要复杂的机理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，需要理解晶体滑移的基本概念，包括滑移面和滑移方向。其次，需要掌握立方晶系中{111}晶面族的几何特性及其与给定(111)表面的交线计算。最后，还需要综合分析滑移线在表面上的可能角度关系。这些步骤涉及多步计算和概念关联，超出了简单的记忆或单一概念应用，属于中等应用层次中的复杂综合分析。" + }, + { + "idx": 2551, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of bonding types.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Ionic or covalent bondsPrimarily metallic bondsMetallic bondsMixed type: metallic bonds between metal atoms, and covalent bonds between metal and metalloid atoms
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，需要文字解释和论述，答案以表格形式呈现了详细的比较信息，符合简答题的特征。 | 知识层次: 题目要求对不同类型的金属间化合物（如价化合物、电子化合物、TCP相、间隙相等）的键合类型进行总结和比较，这需要综合运用多个知识点，进行推理分析和机理解释。不仅需要理解每种化合物的键合特性，还需要进行比较和综合分析，思维过程的深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2552, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the initial slip system.", + "answer": "The aluminum single crystal has an FCC structure, and [2 3] lies within the orientation triangle [001]―[1 1]―[101]. Therefore, the initial slip system is (111)[0 1].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定初始滑移系统，答案提供了详细的解释和结论，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目需要理解FCC结构的滑移系统，并能够将给定的方向[2 3]定位在标准三角形中，从而确定初始滑移系统。这涉及到多步分析和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，需要掌握FCC晶体结构的基本知识；其次，需要理解取向三角形概念并能正确应用；最后，需要综合判断[2 3]方向在取向三角形中的位置，并据此确定初始滑移系。这些步骤涉及多个概念的关联和综合分析，超出了简单记忆或单一概念应用的范畴，属于需要多角度分析论述的难度水平。" + }, + { + "idx": 2553, + "question": "Write all possible slip systems for an FCC crystal at room temperature (specific crystallographic plane and direction indices are required).", + "answer": "There are a total of 12 possible slip systems: (111)[10 ], (111)[01 ], (111)[1 0], ( 11)[110], ( 11)[0 1], ( 11)[101], (1 1)[110], (1 1)[10 ], (1 1)[011], (11 )[011], (11 )[101], (11 )[1 0].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举所有可能的滑移系统，需要详细说明具体的晶面和晶向指数，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对FCC晶体滑移系统的基本概念的记忆和理解，需要列举所有可能的滑移面和滑移方向，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求记忆FCC晶体的12个可能的滑移系统，包括具体的晶面和晶向指数。虽然需要记忆的内容较多，但属于基础概念记忆的范畴，不需要复杂的分析或推理。相较于等级1的基本定义简答，该题目需要更详细的知识点记忆，但不需要深入的概念解释或复杂体系的阐述，因此属于等级2的难度。" + }, + { + "idx": 2554, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) from typical examples.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
MgSe, Pt2P, Mg2Si, MnS, MgS, MnAsCuZn, CusZn8, CuZn3MgCu2, MgZn2, MgNi2 (Laves phases), Fe-Cr alloys (phases), Cr3SiFe4N, Fe2N, NaH, TiH2 (simple); Fe3C, Cr23C6, Fe4W2C (complex)
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，并提供典型例子。答案以表格形式呈现，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求对不同类型金属间化合物进行总结和比较，需要理解各类化合物的特点、典型例子以及它们之间的区别和联系。这涉及多个知识点的关联和综合分析，但不需要进行复杂的机理分析或创新应用。 | 难度: 在选择题型内，该题目要求考生不仅掌握各类金属间化合物的基本概念，还需要能够从典型例子中识别和比较不同类别的化合物（如价化合物、电子化合物、TCP相、间隙相等）。这涉及多步的知识点关联和综合分析，需要考生具备较高的知识整合能力和比较分析能力。虽然题目提供了正确选项，但理解和区分这些化合物的类别及其典型例子需要较深的知识掌握和应用能力，因此在选择题型中属于较高难度。" + }, + { + "idx": 2555, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the rotation rule and the rotation axis.", + "answer": "The specimen axis turns toward [0 1], and the rotation axis is [2 1 3]×[0 1 1]=[2 1 2], i.e., [1 ].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述旋转规则和旋转轴，答案提供了详细的文字解释和推导过程，而不是简单的选择、判断或数值计算。 | 知识层次: 题目需要理解晶体取向和旋转规则，并应用向量叉积计算旋转轴，涉及多步计算和概念关联，但不需要深度推理或创新应用。 | 难度: 在选择题中属于较高难度，需要理解晶体学方向、旋转规则和向量叉积计算等多个概念，并进行多步综合分析和计算。题目要求确定旋转方向和旋转轴，涉及多个知识点的关联和综合应用，解题步骤较为复杂，对学生的综合分析能力要求较高。" + }, + { + "idx": 2556, + "question": "If tension is applied along the [110] direction of an FCC crystal, please write down the possible activated slip systems.", + "answer": "There are four possible activated slip systems, which are (111)[101], (111)[011], (111)[110], (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出可能的激活滑移系统，需要文字解释和论述，而不是从选项中选择或判断对错。答案给出了具体的滑移系统，属于简答形式。 | 知识层次: 题目要求确定FCC晶体在特定方向受力时的滑移系统，需要理解晶体结构、滑移系统的基本概念，并能够将[110]方向与可能的滑移面进行关联分析。这涉及多步思考和概念的综合应用，但不需要复杂的推理或创新设计。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握FCC晶体结构的基本知识，还需要理解滑移系统的概念，并能综合分析[110]方向施加张力时可能激活的滑移系统。解题步骤涉及多个概念的综合运用和计算，需要考生具备较强的综合分析能力和空间想象能力。" + }, + { + "idx": 2557, + "question": "Using computer verification, it is determined that the image rule for slip systems applies to both FCC crystals and BCC crystals with {110}<111> slip systems. (Hint: For any given external force direction, use a computer to calculate the orientation factors for all equivalent slip systems.)", + "answer": "μ=cosλcosφ, calculate μ for all equivalent slip systems, and it can be found that μ_max must correspond to the slip system selected by the image rule.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用公式μ=cosλcosφ进行计算，并针对所有等效滑移系统计算μ值，最终验证图像规则的应用。这涉及到具体的数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目要求使用计算机验证滑移系统的取向因子计算，涉及多步计算和概念关联（如取向因子公式的应用、滑移系统的等效性分析），需要综合分析不同滑移系统的计算结果来确定最大取向因子对应的滑移系统。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等偏上难度，需要理解图像规则在FCC和BCC晶体中的应用，掌握取向因子μ的计算方法，并能综合分析多个等效滑移系统的计算结果。题目涉及多步计算和概念关联，但相比复杂多变量计算问题，步骤和变量相对较少。" + }, + { + "idx": 2558, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the double slip system.", + "answer": "The double slip system is (111)[0 1]－( 1)[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定双滑移系统，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求确定双滑移系统，需要理解晶体滑移的基本原理，并能够将施加的张力方向与滑移系统关联起来。这涉及到多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求确定双滑移系统，这需要理解晶体学方向、滑移面和滑移方向的概念。其次，题目中给出了特定的张力方向[2 3]，这需要考生能够正确计算和确定可能的滑移系统。最后，正确选项涉及两个滑移系统的组合，这需要考生能够综合分析并选择正确的组合。因此，该题目在选择题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 2560, + "question": "If a single crystal aluminum rod with a diameter of $5mm$ starts to slip when a tensile force of 40N is applied along the rod axis [123], find the critical resolved shear stress of aluminum during slipping.", + "answer": "Single crystal aluminum has an FCC structure, and the slip system is {111}<110>. Using the imaging rule, the slip plane and slip direction are determined to be (11)[101]. The angles between them and the axis are respectively: $$ \\begin{array}{r l}&{\\mathtt{cos}\\Phi=\\left[123\\right]\\bullet[\\overline{{1}}11]/(\\left|\\left[123\\right]\\right|\\left[\\overline{{1}}11\\right]|)=4/\\surd42;}\\ &{\\mathtt{cos}\\mathtt{\\lambda}=\\left[123\\right]\\bullet[101]/(\\left|\\left[123\\right]\\right|\\left[101\\right]|)=2/\\surd7;}\\end{array} $$ Therefore, the critical resolved shear stress τc = $\\mathsf{\\bar{cos}\\lambda cos\\Phi/A_{0}=\\lambda\\cdots=0.95MPa}.$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界分切应力，解答过程中涉及角度计算、应力公式应用和具体数值代入，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，包括确定滑移面和滑移方向、计算角度、应用临界分切应力公式等。同时需要理解FCC结构的滑移系统概念和成像规则，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、滑移系统、成像规则等概念，并进行多步计算（包括向量点积、角度计算、应力公式应用等）。虽然题目提供了部分计算步骤，但仍要求考生具备较强的综合分析能力和计算准确性。" + }, + { + "idx": 2561, + "question": "What are the basic characteristics of silicate structures?", + "answer": "The basic characteristics of silicate structures include: (1) The fundamental structural unit of silicates is the [SiO4] tetrahedron, with silicon atoms located in the interstices of the oxygen tetrahedron; (2) Each oxygen can be shared by at most two [SiO4] tetrahedra; (3) [SiO4] tetrahedra can exist isolated in the structure or be interconnected by sharing vertices; (4) The Si-O-Si bond forms a bent line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述硅酸盐结构的基本特征，答案提供了详细的文字描述和解释，符合简答题的特点。 | 知识层次: 题目考查对硅酸盐结构基本特征的记忆和理解，属于基础概念的记忆性知识，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生记忆并理解硅酸盐结构的基本特征，包括[SiO4]四面体的基本结构单元、氧原子的共享方式、四面体的连接方式以及Si-O-Si键的形状。虽然涉及多个知识点，但都属于基础概念的记忆和理解范畴，不需要复杂的分析或比较。因此，在选择题型内属于中等难度。" + }, + { + "idx": 2562, + "question": "If a single crystal of aluminum is stretched along the [2 3] direction, determine the final orientation (stable orientation) of the crystal.", + "answer": "From (5), it can be seen that the final orientation of the crystal is [1 2].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定晶体在拉伸后的最终取向，需要基于材料科学原理进行分析和解释，答案给出了具体的取向结果，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解晶体拉伸过程中的取向变化，并应用相关原理进行多步分析和计算，涉及概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。题目要求确定铝单晶在特定方向拉伸后的最终取向，这需要深入理解晶体学中的取向概念和拉伸过程中的晶体行为。解题步骤涉及多步计算和概念关联，包括对晶体取向变化的综合分析。此外，题目要求将理论知识与实际应用相结合，进行多角度分析，这在选择题型中属于较为复杂的要求。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 2563, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the crystal orientation and shear strain at the onset of double slip.", + "answer": "Using L=ds/+dt dt∨(/⋅↗)db, let L=[u u w], then L=[2 1 3]+4Y[0 1 1]/√6, from which it can be determined that u=2, v=4, γ=√6/4. Therefore, the crystal orientation is [2 4], i.e., [1 2], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体取向和剪切应变，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要确定晶体取向和剪切应变，并应用公式进行计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用材料科学中的基本概念和计算方法。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体取向和剪切应变的概念，并进行多步计算和综合分析。题目涉及向量运算和数学推导，虽然给出了正确选项，但解题过程需要较强的材料科学基础和计算能力。" + }, + { + "idx": 2564, + "question": "Niobium single crystal has a BCC structure, with [2 3] located in the orientation triangle [001]―[1 1]―[101]. What is the initial slip system?", + "answer": "The initial slip system is (0 1)[111].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定初始滑移系统，答案是一个具体的滑移系统描述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解BCC结构的滑移系统，并能够根据给定的晶体取向三角形确定初始滑移系统。这涉及到多步分析和概念关联，需要一定的综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解BCC晶体结构、滑移系统、取向三角形等概念，并进行多步计算和综合分析来确定初始滑移系统。虽然题目给出了正确选项，但解题过程涉及多个知识点的关联和应用，属于中等应用层次的要求。" + }, + { + "idx": 2565, + "question": "Change the tension in the previous question to compression, determine the initial slip system", + "answer": "[2 3] is located in the orientation triangle [001]―[1 1]―[101], so the initial slip system is (111)[0 1]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据给定的条件（改变张力为压缩）和晶体学信息（取向三角形）确定初始滑移系统，需要文字解释和论述，答案形式为具体的滑移系统描述，而非选择、判断或计算。 | 知识层次: 题目要求将张力改为压缩并确定初始滑移系统，涉及多步计算和概念关联，需要综合分析晶体取向和滑移系统的关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求将张力改为压缩并确定初始滑移系统，涉及对晶体取向三角形和滑移系统的理解。虽然题目给出了正确选项，但需要考生具备将概念应用于新情境的能力，并进行综合分析。这比单纯记忆概念要难，但比需要多角度分析论述或深度关联性分析的题目要简单。" + }, + { + "idx": 2566, + "question": "Change the tension in the previous question to compression, determine the double slip system", + "answer": "The double slip system is (111)[0 1]－(1 1)[011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定双滑移系统，答案是一个具体的滑移系统组合，需要基于材料科学知识进行解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求将张力条件改为压缩条件，并确定双滑移系统，这需要理解滑移系统的基本原理，并能根据不同的应力条件（张力或压缩）进行综合分析。虽然不涉及复杂的推理或创新设计，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求将张力改为压缩并确定双滑移系统，涉及对晶体滑移系统的理解和应用，需要综合分析不同滑移系统的可能性。虽然题目给出了正确选项，但需要考生具备一定的材料科学基础知识和计算能力，能够将概念与实际应用相结合。" + }, + { + "idx": 2567, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the rotation law and rotation axis of the crystal during double slip.", + "answer": "During double slip, the specimen axis rotates towards [0 1], with the rotation axis n1=[1 1 2]×[0 1 1]=[1 1 1], and simultaneously rotates towards [101], with the rotation axis n2=[1 1 2]×[101]=[1 1 1]. The resultant rotation axis is [000], so the crystal no longer rotates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述双滑移过程中晶体的旋转规律和旋转轴，答案提供了详细的文字解释和推导过程，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求确定双滑移过程中晶体的旋转规律和旋转轴，涉及晶体学方向、滑移系统、旋转轴计算等复杂概念的综合运用和推理分析。需要理解双滑移机制，进行向量叉积计算，并解释最终的旋转行为，思维过程深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用晶体学、滑移系和旋转定律等复杂知识，进行多步骤推理分析。需要正确理解双滑移条件下的晶体旋转机制，计算两个滑移系的旋转轴，并推导最终合成旋转轴。这种深度机理解释和复杂现象分析在选择题中非常罕见，对学生的材料科学理论基础和空间思维能力要求极高。" + }, + { + "idx": 2568, + "question": "The sample axis is rotated to [111], what is the rotation axis?", + "answer": "The rotation axis is [2 1 3]×[111]=[4 1 3].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行向量叉乘计算来求解旋转轴，答案是通过数学运算得出的具体数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（向量叉乘），并需要理解晶体学中旋转轴的概念及其计算方法，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解向量叉积的概念，并能正确应用公式进行计算。题目要求将样本轴旋转到[111]方向，并计算旋转轴，涉及多步计算和概念关联。虽然题目给出了正确选项的计算过程，但在选择题型中，学生仍需具备一定的综合分析能力才能正确理解和解答。" + }, + { + "idx": 2569, + "question": "Change the tension in the previous question to compression, determine the specimen axis rotation direction and rotation axis", + "answer": "The specimen axis rotation direction is [111], and the rotation axis is $[2\\bar{1}3]\\times[111]=[\\bar{4}13]$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定试样轴的旋转方向和旋转轴，答案给出了具体的旋转方向和旋转轴的计算结果，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求从张力条件转变为压缩条件，并确定试样轴的旋转方向和旋转轴。这需要深入理解晶体学中的方向指数和旋转机制，涉及多个概念的关联和综合分析。解答过程中需要运用向量叉积等数学工具，进行推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2570, + "question": "Change the tension in the previous question to compression, and calculate the crystal orientation and shear strain", + "answer": "Using $A=a-\\textsf{v}(a\\cdot b)n,$, let $\\textsf{A}=\\textsf{[u0w]}$, we get $\\mathsf{A}=[2\\bar{1}3]-4\\lor[111]/\\surd6$. From this, it can be seen that $\\scriptstyle{\\boldsymbol{\\mathsf{u}}}=3$, $v=4$, $\\gamma=-\\sqrt{6/4}$, so the crystal orientation is [304], and the shear strain is - $\\surd6/4$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行晶体取向和剪切应变的计算，答案中包含了具体的数学运算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及晶体取向和剪切应变的计算，需要应用公式并进行综合分析。虽然题目给出了具体的计算步骤，但仍需要理解晶体学中的向量运算和应变计算，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及多步计算和复杂的概念关联。正确选项需要理解晶体取向和剪切应变的计算，并应用特定的公式进行推导。解题步骤包括变量替换、向量运算和数学推导，涉及多个知识点的综合应用。此外，题目还要求对计算结果进行解释，进一步增加了难度。在选择题型内，这种复杂多变量计算和综合分析的要求使得题目难度较高。" + }, + { + "idx": 2571, + "question": "Change the tension in the previous question to compression, analyze the rotation of the specimen axis and the resultant rotation axis during double slip.", + "answer": "During double slip, the specimen axis rotates towards [111], with the rotation axis $\\mathsf{n}_{1}=[304]\\times[111]=[\\bar{4}13]$, and simultaneously rotates towards [1 1], with the rotation axis $n_{2}=[304]\\times[1\\overline{{{1}}}1]=[41\\overline{{{3}}}]$. The resultant rotation axis is [020], i.e., [010], so after double slip, point F moves along the edge [001]－[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析双滑移过程中试样轴的旋转和合成旋转轴的变化，答案提供了详细的文字解释和论述，包括旋转方向和旋转轴的计算结果，符合简答题的特征。 | 知识层次: 题目要求分析双滑移过程中试样轴和旋转轴的变化，涉及多个晶体学方向的旋转计算和综合推理，需要深入理解滑移机制和晶体旋转原理，并进行复杂的向量运算和综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生在双滑移条件下分析试样轴的旋转和合成旋转轴，涉及复杂的向量运算和晶体学知识。解题步骤包括：" + }, + { + "idx": 2572, + "question": "What is a double slip system?", + "answer": "The double slip system is (0 1)[111]－(011)[1 1].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"double slip system\"进行解释，答案提供了具体的晶体学表示，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对双滑移系统这一基本概念的记忆和理解，属于定义性知识，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别双滑移系统的具体表示方式，属于基础概念记忆层次。题目直接给出了正确选项，无需进行复杂的分析或推理，仅需对定义性知识有基本掌握即可正确作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2573, + "question": "Change the tension in the previous question to compression, and determine the stable orientation", + "answer": "Let the stable orientation be $[\\\\boldsymbol{\\\\mathbf{u}}^{},~\\\\boldsymbol{\\\\mathbf{0}}\\\\boldsymbol{\\\\mathbf{w}}^{}~]$. To make $\\\\boldsymbol{\\\\mathsf{n}}=[000]$, it is required that $\\\\begin{array}{r l}{[\\\\mathbf{u}^{\\\\prime}}&{{}0\\\\mathbf{w}^{\\\\prime}]\\\\times([111]+[1\\\\bar{1}1])}\\\\end{array}$ $=[000]$, i.e., $\\\\begin{array}{r l}{\\\\upmu^{\\\\prime}}&{{}=\\\\upmu^{\\\\prime}}\\\\end{array}$. Therefore, the stable orientation is [101]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过分析和推导确定稳定的取向，答案给出了具体的取向结果并附有推导过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要多步计算和概念关联，涉及稳定取向的确定和数学推导，但不需要复杂的综合分析或创新应用。 | 难度: 在选择题型中，该题目需要考生不仅理解材料科学中的晶体取向和应力状态的基本概念，还需要进行多步计算和综合分析。题目要求考生将张力改为压缩，并确定稳定取向，这涉及到对晶体结构的深入理解和数学计算能力。此外，正确选项的推导过程较为复杂，需要考生具备较强的逻辑推理能力和综合分析能力。因此，在选择题型内，该题目属于较高难度，需要多角度分析和论述。" + }, + { + "idx": 2574, + "question": "Using L=ds/+ds†(′⋅η)b, let L=[u 0 w], find the crystal orientation and shear strain.", + "answer": "L=[2 1 3]+4∨[111]/√6, from which it can be seen that u=3, v=4, γ=√6/4, so the crystal orientation is [304], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和条件进行数值计算，最终得出晶体取向和剪切应变的数值结果。解答过程涉及数学运算和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解晶体取向和剪切应变的概念，并进行数值计算和综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多变量计算和综合分析。需要理解晶体取向和剪切应变的概念，并进行多步骤的计算推导。正确选项的解析过程需要将多个变量（u, v, γ）与晶体取向和剪切应变关联起来，计算过程较为复杂。此外，题目还要求对给定的数学表达式进行解析，进一步增加了难度。" + }, + { + "idx": 2575, + "question": "Assuming the stable orientation is [u′, 0 w′], what should the stable orientation be to make n=[000]?", + "answer": "To make n=[000], it is required that [u′ 0 w′]×([111]+[1 1 1])=[000], i.e., u′=u′’, thus the stable orientation is [101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定稳定取向的条件，答案给出了具体的推导过程和结论，属于需要解释和论述的简答题类型。 | 知识层次: 题目需要理解晶体取向的概念，并应用向量叉乘的数学知识来推导稳定取向。虽然涉及一定的计算和概念关联，但整体思维过程较为直接，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解晶体取向的概念，进行向量叉乘运算，并综合分析稳定取向的条件。解题步骤涉及多步计算和概念关联，要求考生具备较强的综合分析能力。" + }, + { + "idx": 2576, + "question": "During double slip, the specimen axis turns towards [111] and [1 1]. What is the resultant rotation axis? Along which direction does point F move after double slip?", + "answer": "During double slip, the specimen axis turns towards [111] with a rotation axis n1=[304]×[111]=[4 1 3], and simultaneously turns towards [1 1] with a rotation axis n2=[304]×[1 1 1]=[4 1 3]. The resultant rotation axis is [020], i.e., [010]. Therefore, after double slip, point F moves along the edge [001]－[101].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释双滑移过程中试样轴的旋转方向和点F的移动方向，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解双滑移过程中旋转轴的计算方法，以及点F的运动方向推导。虽然不涉及复杂的机理分析，但需要综合运用向量叉乘和方向判断的知识。 | 难度: 在选择题中属于较高难度，需要综合运用多个概念（双滑移、旋转轴计算、晶体学方向分析）并进行多步计算。题目要求考生不仅要理解双滑移过程中试样轴的转向机制，还要能够正确计算两个旋转轴的矢量积，最终推导出合成旋转轴和点F的运动方向。这种需要多角度分析和综合计算的问题在选择题型中属于较复杂的类型。" + }, + { + "idx": 2577, + "question": "Practice has shown that highly cold-rolled magnesium sheets tend to crack during deep drawing. Analyze the reasons for this.", + "answer": "After cold rolling, magnesium sheets develop a (0001)<11 0> texture. When stress is applied parallel or perpendicular to the sheet surface, the orientation factor is zero, resulting in almost no plasticity, making further processing prone to cracking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷轧镁板在深冲时易开裂的原因，需要文字解释和论述，答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷轧镁板在深冲过程中易开裂的原因，涉及材料微观结构（(0001)<11 0>织构）与宏观性能（塑性）的关联机制，需要综合运用晶体学、塑性变形理论和材料加工知识进行机理层面的解释，属于需要推理分析和综合运用的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 2578, + "question": "It is known that the critical resolved shear stress required for twinning in magnesium single crystals is several times larger than that for slip. When a magnesium single crystal is stretched along the [0001] direction, what is the deformation mode of the crystal?", + "answer": "The slip systems of magnesium single crystals are (0001)<11-20> and {10-10}<11-20>, and the possible slip directions are all perpendicular to [0001], so slip does not occur in this case; c/a=1.62<√3, so [0001] is in the obtuse angle region of K1 and K2, and twinning will increase during deformation. Therefore, twinning occurs when stretched along the [0001] direction, and twinning changes the crystal orientation, which may further lead to slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁单晶在[0001]方向拉伸时的变形模式，答案提供了详细的文字解释和论述，包括滑移系统和孪生的条件分析，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析镁单晶在特定拉伸方向下的变形模式，涉及滑移和孪生机制的对比、晶体学方向的分析以及变形过程中晶体取向变化的推理。这需要综合运用材料科学中的晶体塑性理论、滑移系统分析以及孪生条件判断，属于对多个概念的深度理解和复杂推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用镁单晶的滑移和孪生机制知识，分析特定拉伸方向[0001]下的变形模式。解题需要深入理解晶体学方向、临界分切应力比较、滑移系几何限制（方向垂直性）以及c/a比值对孪生倾向的影响等多重因素，最后还需推理变形过程中晶体取向变化的二次效应。这种需要多维度机理交叉分析且包含因果链推理的题目，在选择题中属于最复杂的考查类型。" + }, + { + "idx": 2579, + "question": "Can inserting an additional columnar half-atom plane in a crystal form a dislocation loop? Why?", + "answer": "A dislocation loop cannot be formed. Assuming a dislocation loop could form, it would consist entirely of edge dislocations. According to l⊥b, the Burgers vector $\\pmb{b}$ at each point of the loop should be along the radial direction, meaning the $\\pmb{b}$ at different points on the loop would vary. This contradicts the fact that a single dislocation line has only one $\\pmb{b}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么插入额外的柱状半原子平面不能形成位错环，需要文字论述和理论依据，而不是简单的选择、判断或计算。 | 知识层次: 题目涉及位错环的形成机制和伯格斯矢量的方向性分析，需要综合运用位错理论和晶体学知识进行推理和解释，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用晶体缺陷理论（特别是位错环的形成机制）、Burgers向量的性质以及几何分析能力。解题时需要：" + }, + { + "idx": 2580, + "question": "Highly cold-rolled aluminum sheets will form a well-developed {001}<100> texture (cube texture) after high-temperature annealing. If such an aluminum sheet is deep-drawn into a cup, how many ears will be produced?", + "answer": "Eight ears will be produced during deep drawing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在深冲过程中会产生八个耳朵，需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解冷轧铝板在高温退火后形成的立方织构（{001}<100>）及其在深冲过程中的行为。虽然涉及基础概念（织构和深冲），但需要将织构与深冲过程中产生的耳数关联起来，进行一定的分析和应用。这需要多步思考和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 2581, + "question": "What is the fundamental reason for the formation of deformation texture (or processing texture)?", + "answer": "The fundamental reason for the formation of deformation texture is that during processing, each grain slips along certain slip planes and rotates according to specific rules, causing the slip direction to align with the principal strain direction or the slip plane to align with the compression plane. Therefore, when the deformation is sufficiently large, the slip directions or slip planes of a large number of grains will become parallel to the tensile direction or compression plane, thus forming the texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释变形织构形成的基本原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释变形织构形成的根本原因，涉及晶体滑移、旋转规则以及应变方向的关联，需要综合运用材料科学中的晶体塑性变形机理进行推理分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解变形织构形成的根本原因，涉及复杂的晶体滑移机制和旋转规则的综合分析。正确选项不仅需要掌握多个专业概念（如滑移面、主应变方向、压缩平面等），还需要将这些概念串联起来进行机理层面的深度解释。此外，题目要求考生能够推理出大变形条件下大量晶粒的取向排列规律，这属于复杂现象的全面分析能力，远超选择题型中常规的知识点识别或简单应用层次。" + }, + { + "idx": 2582, + "question": "What is texture (or preferred orientation)?", + "answer": "After cold working, the orientations of metal grains exhibit a certain relationship, and such a distribution of orientations is called preferred orientation, i.e., texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"texture (or preferred orientation)\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对\"texture (or preferred orientation)\"的定义进行解释，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目仅考察对\"texture (or preferred orientation)\"这一基础概念的定义记忆。正确选项直接给出了定义，无需进行复杂的概念解释或比较分析，属于最基础的定义简答类型。" + }, + { + "idx": 2584, + "question": "In a simple cubic crystal, pure bending of the (010) plane around the [001] axis will form what type of dislocation (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[010]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求详细解释和论述晶体中位错类型、位错线方向和Burgers向量的关系，答案需要文字描述而非简单选择或判断 | 知识层次: 题目需要理解晶体结构、位错类型及其几何关系，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解晶体结构、位错类型、伯格斯矢量等概念，并进行综合分析。题目要求将纯弯曲变形与位错类型关联，并正确识别位错线方向和伯格斯矢量方向，涉及多步概念关联和空间想象能力。虽然题目给出了具体晶面和旋转轴，但仍需要较强的晶体学基础才能正确解答。" + }, + { + "idx": 2585, + "question": "For a simple cubic crystal, pure bending of the (110) plane around the [001] axis will form what type of dislocations (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[100] or a[010]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释和论述晶体弯曲形成的位错类型、位错线方向和伯格斯矢量，答案需要文字描述而非简单选择或判断。 | 知识层次: 题目需要理解晶体结构、位错类型和伯格斯矢量的概念，并能够将这些概念关联起来进行分析。虽然不涉及复杂的计算，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解晶体结构、位错类型、伯格斯矢量等概念，并进行多步分析和关联。题目要求确定位错类型、位错线方向和伯格斯矢量，涉及多个知识点的综合应用和计算，超出了简单记忆或单一概念的应用。" + }, + { + "idx": 2586, + "question": "FCC crystal, pure bending occurs on the (110) plane around the [001] axis, what kind of dislocations will form (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[110]/2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释和指定位错的方向和Burgers向量，答案需要文字描述和具体参数，而非选择或判断。 | 知识层次: 题目需要理解FCC晶体结构、纯弯曲变形机制、位错类型及其伯格斯矢量的确定，涉及多个概念的关联和综合分析。虽然不涉及复杂的计算，但需要对晶体学方向和位错性质有较深入的理解和应用能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及FCC晶体结构、纯弯曲变形、滑移面和滑移方向等概念的综合理解。其次，需要正确识别(110)平面和[001]轴的关系，并推导出在此变形条件下会形成的位错类型。此外，题目要求具体说明位错线方向和Burgers矢量，这需要深入理解位错几何和晶体学方向的计算。虽然题目给出了正确选项，但解题过程需要多步概念关联和综合分析，包括：1)理解纯弯曲变形产生的位错类型；2)确定滑移面和滑移方向；3)计算Burgers矢量；4)判断位错线方向。这些步骤都超出了基础知识的简单回忆，需要进行较深入的分析和计算。" + }, + { + "idx": 2587, + "question": "When a simple cubic crystal is twisted by an angle θ around the [001] axis, what kind of dislocation will form (specify the direction of the dislocation line and the Burgers vector)?", + "answer": "Screw type, dislocation line direction=[001], Burgers vector=a[001]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述在特定条件下形成的位错类型，包括位错线的方向和Burgers向量的具体描述。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要理解晶体扭转后形成的位错类型，并确定位错线和Burgers矢量的方向。这涉及到对位错基本概念的理解以及在不同晶体学方向上的应用，属于中等应用层次。虽然不涉及复杂的计算或多步骤分析，但需要对概念进行关联和综合判断。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 2589, + "question": "When the crystal around an edge dislocation contains excess interstitial atoms, how will the dislocation climb?", + "answer": "Negative climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释边缘位错在含有过量间隙原子时的攀移行为，答案\"Negative climb\"是一个专业术语的解释，属于需要文字说明的简答题类型 | 知识层次: 题目涉及位错攀移的机理分析，需要理解间隙原子对位错运动的影响机制，并综合运用位错理论和扩散知识进行推理判断。这属于需要深入理解材料微观结构演变和缺陷行为的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅要理解位错攀移的基本概念，还需要综合运用关于间隙原子对位错行为影响的知识，进行机理层面的推理分析。正确选项\"Negative climb\"需要考生能够将晶体缺陷理论与实际材料行为联系起来，这涉及到复杂现象的全面分析和机理解释能力。在选择题型中，这类需要多步骤推理和深度理解的题目属于最难的一类。" + }, + { + "idx": 2590, + "question": "When the crystal around an edge dislocation contains an excess of vacancies, how will the dislocation climb?", + "answer": "Positive climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错攀移的行为，需要文字解释和论述，答案\"Positive climb\"是一个简短的文字回答，而不是从多个选项中选择或判断对错 | 知识层次: 题目涉及位错攀移机制的分析，需要理解空位对位错运动的影响，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2591, + "question": "When the crystal around an edge dislocation contains vacancies below the equilibrium concentration, how will the dislocation climb?", + "answer": "Negative climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错攀移的行为，需要文字论述而非选择或判断，答案\"Negative climb\"是一个简短的术语解释而非计算结果 | 知识层次: 题目要求理解空位浓度与位错攀移之间的关系，并分析在特定条件下（空位浓度低于平衡浓度）位错攀移的方向。这需要综合运用位错理论、扩散机制和热力学知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 2592, + "question": "A screw dislocation with $b=a/2$ [10] moves on the (111) plane. If it encounters an obstacle during motion and undergoes cross-slip, please identify the cross-slip system.", + "answer": "∵ All planes containing the direction of the screw dislocation are slip planes, ∴ For the FCC crystal slip plane (111), only (111) and (11 ) contain $I=b={\\\\sf a}/2$ [10]. ∴ If cross-slip occurs, it must be from the (111) plane to the (11 ) plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来识别交叉滑移系统，答案提供了详细的推导过程和结论，属于需要文字解释的简答题类型。 | 知识层次: 题目需要理解螺位错的基本性质及其在FCC晶体中的滑移系统，并能够分析在不同滑移面之间的交叉滑移过程。这涉及到多个概念的关联和综合分析，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 2593, + "question": "A closed dislocation loop lies on the slip plane of a prism with a square cross-section. The two sides of the square are along the x and y axes, and the Burgers vector is along the z-axis. If the dislocation loop can only glide, determine the equilibrium shape of the dislocation loop and the critical stress for initiation under the stress distribution condition τxz = τyz = τ = const. (Assume the line tension is approximately constant.)", + "answer": "f = (σ ⋅ b) × υ = (u - v)τbk; the initiation stress τp = 2G exp(-2πw/b)/(1-υ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定位错环的平衡形状和临界应力，需要通过公式计算得出具体数值结果。答案给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目涉及复杂的力学分析，需要综合运用位错理论、应力分析和能量平衡原理，推导位错环的平衡形状和临界应力。这需要深入理解位错行为、应力场与位错的相互作用，以及线张力的概念，并进行多步推理和计算。 | 难度: 在选择题型内，该题目属于高难度综合计算问题。题目涉及复杂的位错理论、应力分析和临界应力计算，需要综合运用多个高级概念（如Burgers矢量、滑移面、线张力等）并进行机理推导。解题步骤要求：1)理解位错环在应力场中的平衡条件；2)推导临界应力公式；3)处理各向异性应力条件。这远超选择题的一般概念辨析或简单计算要求，需要深入的理论知识和较强的数学推导能力。" + }, + { + "idx": 2594, + "question": "If the applied stress is uniformly distributed, find the net force acting on any dislocation loop.", + "answer": "In general, the formula for the force on a dislocation is ${\\mathsf{d}}F=({\\textsf{\\sigma}}\\cdot{\\textsf{\\em b}})\\times{\\mathsf{d}}/,$. Since the applied stress is uniformly distributed, $\\pmb{\\upsigma}$ and $\\pmb{b}$ are both constants. Therefore, the net force on any dislocation loop is $\\oint\\mathbf{d}F=\\oint{\\bigl(}\\upsigma\\bullet b{\\bigr)}\\times\\mathbf{d}/={\\bigl(}\\upsigma\\bullet b{\\bigr)}\\oint\\mathbf{d}/={\\bigl(}\\upsigma$ • $b)\\times0=0.$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算均匀应力下的净力，答案展示了具体的数学推导和积分过程，符合计算题的特征。 | 知识层次: 题目涉及对均匀应力分布下位错环受力情况的综合分析，需要应用位错力的基本公式并进行积分运算。虽然公式本身是基础的，但需要理解应力、位错矢量和积分路径之间的关系，并进行多步推导和计算。这超出了简单应用的范畴，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如均匀应力分布、位错力公式、环路积分等）并进行多步计算和综合分析。虽然题目提供了正确选项的推导过程，但考生仍需掌握相关物理概念和数学运算才能正确理解和验证该选项。" + }, + { + "idx": 2595, + "question": "When the crystal around an edge dislocation contains interstitial atoms below the equilibrium concentration, how will the dislocation climb?", + "answer": "Positive climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下位错如何攀移，需要文字描述和论述，答案\"Positive climb\"是一个简短的定性描述，而非从多个选项中选择或简单判断对错。 | 知识层次: 题目涉及位错攀移机制与间隙原子浓度关系的深入分析，需要综合运用位错理论和扩散知识进行推理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2596, + "question": "Derive the elastic energy formula for a mixed dislocation.", + "answer": "$\\\\begin{array}{r l}&{\\\\mathsf{E}=\\\\mathsf{E}_{\\\\mathsf{o}1}\\\\left(\\\\mathcal{V}\\\\right)+\\\\mathsf{E}_{\\\\mathsf{e}1}\\\\left(\\\\frac{\\\\mathsf{i}\\\\mathcal{R}}{\\\\mathsf{s}\\\\mathsf{t}_{\\\\mathrm{A}}}\\\\right)=\\\\mathsf{G b}^{2}|\\\\mathsf{s}\\\\mathsf{i n}^{2}\\\\mathsf{a}\\\\star|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)/\\\\left[4\\\\pi\\\\left(1-\\\\upsilon\\\\right)\\\\right]+\\\\mathsf{G b}^{2}|\\\\mathsf{c o s}^{2}\\\\mathsf{a}\\\\star|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)}\\\\ &{\\\\mathrm{~\\\\ensuremath~{\\\\left/~\\\\left(4\\\\pi\\\\right)~\\\\tau~=~\\\\mathsf{Gb}^2|\\\\tau~\\\\left(1-\\\\upsilon\\\\cos^2\\\\theta\\\\right)~\\\\cdot~|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)~\\\\middle/~\\\\left[4\\\\pi\\\\left(1-\\\\upsilon\\\\right)\\\\right]~\\\\right.~}}\\\\end{array}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导混合位错的弹性能量公式，涉及复杂的数学推导和公式应用，答案呈现为详细的数学表达式和推导过程，符合计算题的特征。 | 知识层次: 题目要求推导混合位错的弹性能量公式，涉及多步计算和概念关联，需要理解位错的基本性质、弹性理论的应用以及数学推导能力。虽然不涉及复杂的综合分析或创新应用，但比简单应用更复杂，需要中等程度的认知能力和知识点的关联。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。正确选项涉及弹性力学中的混合位错能量公式推导，需要掌握剪切模量(G)、伯格斯矢量(b)、泊松比(ν)等多个变量的相互作用关系。题目要求考生能够理解并应用位错能量分解为刃型分量和螺型分量的概念，进行三角函数转换和综合计算。在选择题型中，这种需要同时处理多个物理概念和数学变换的题目属于最高难度等级。" + }, + { + "idx": 2598, + "question": "What kind of a pair of dislocations is equivalent to a row of vacancies (or a row of interstitial atoms)?", + "answer": "When the half-atomic planes of a positive edge dislocation and a negative edge dislocation lie on the same plane, leaving out one atomic site in between will form a row of vacancies, while overlapping one atomic site will form a row of interstitial atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释何种位错对等价于空位行或间隙原子行，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释位错对与空位或间隙原子行的等效关系，涉及位错类型（正负刃位错）的相互作用及其对晶体缺陷形成的影响。这需要理解位错的基本概念，并能将不同概念（位错、空位、间隙原子）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解正负刃位错的基本概念，还需要能够综合分析和关联这些概念来推导出空位或间隙原子行的形成机制。解题步骤涉及多步逻辑推理和概念的综合应用，超出了简单的记忆或单一概念的应用。此外，题目要求考生在选择题的有限选项中识别出正确的理论解释，这需要较高的分析能力和对材料科学原理的深入理解。" + }, + { + "idx": 2599, + "question": "On the (111) plane of a copper single crystal, there is a right-handed screw dislocation with $b=a/2$ [10 ], where $a=0.36\\\\mathsf{n m}$. Now, a tensile stress of $10^{6}\\\\mathsf{P a}$ is applied along the [001] direction. Find the force acting on the screw dislocation.", + "answer": "Using the Peach-Koehler formula, we obtain \\n\\n$$\\n{f}=(\\\\sigma\\\\cdot b)\\\\times\\\\upsilon\\n$$\\n\\n$$\\n\\\\begin{array}{r l}&{\\\\langle\\\\left[\\\\begin{array}{l}{\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}}\\\\ {\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}}\\\\end{array}\\\\right]\\\\bullet\\\\frac{\\\\bar{\\\\mathbb{a}}}{2}\\\\left[\\\\begin{array}{l}{1}\\\\ {\\\\bar{\\\\mathbb{O}}}\\\\ {-1}\\\\end{array}\\\\right]\\\\rangle\\\\times\\\\frac{\\\\sqrt{2}}{2}\\\\left[\\\\begin{array}{l}{1}\\\\ {\\\\bar{\\\\mathbb{O}}}\\\\ {-1}\\\\end{array}\\\\right]=\\\\frac{\\\\rho}{(-\\\\sqrt{2/4})\\\\mathsf{a}\\\\upsigma_{z}j},}\\\\end{array}\\n$$\\n\\nThus, $\\\\pounds=1.27\\\\times10^{-4}$ N/m, and the direction is along the negative $\\\\pmb{\\\\ y}$-axis.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过应用Peach-Koehler公式进行数值计算，最终得出一个具体的力值（1.27×10^-4 N/m），并确定其方向。答案涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目需要应用Peach-Koehler公式进行多步计算，涉及应力、柏氏矢量和位错线方向的向量运算，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于高难度，需要深入理解Peach-Koehler公式的应用，进行多步骤的向量和矩阵运算，并正确识别晶体学方向和应力张量的关系。题目涉及复杂的多变量计算和综合分析能力，远超一般选择题的简单概念判断或单步计算要求。" + }, + { + "idx": 2600, + "question": "Estimate the equilibrium width of an extended dislocation in Al. Given the lattice constant of Al a = 0.404 nm, shear modulus G = 3×10^6 N/cm^2, and stacking fault energy γ_I = 166×10^-6 J/m^2.", + "answer": "Al has a face-centered cubic structure, and the equilibrium width of an extended dislocation d_0 = G a^2 / (24πγ_I). Substituting the data: d_0 = (3×10^6 N/cm^2) × (0.404×10^-9 m)^2 / (24π × 166×10^-6 J/m^2) = 3.91×10^-7 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的物理参数和公式进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，无需多步推理或综合分析，仅需将给定数据代入公式进行计算即可。 | 难度: 在选择题中属于简单难度，仅需直接套用给定公式并进行简单计算，无需多个公式组合或复杂分析。" + }, + { + "idx": 2601, + "question": "Which four quantum numbers can determine the spatial position and energy of an electron in an atom?", + "answer": "Principal quantum number n, orbital angular momentum quantum number li, magnetic quantum number mi, and spin angular momentum quantum number si", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举四个量子数，答案是以文字形式给出的解释和论述，没有提供选项或需要计算。 | 知识层次: 题目考查对量子数这一基础概念的记忆和理解，不需要复杂的应用或分析，仅需回答四个量子数的名称即可。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要学生准确掌握四个量子数的名称及其作用（确定电子空间位置和能量）。这比单纯记忆单个定义（等级1）要求更高，但不需要进行复杂的概念体系阐述或比较分析（等级3）。学生只需正确识别四个量子数的组合即可作答。" + }, + { + "idx": 2602, + "question": "Estimate the equilibrium width of an extended dislocation in Cu. Given: lattice constant of Cu a = 0.361 nm, shear modulus G = 5×10^6 N/cm^2, stacking fault energy γ_I = 45×10^-6 J/m^2.", + "answer": "Cu has a face-centered cubic structure, and the equilibrium width of an extended dislocation d_0 = G a^2 / (24πγ_I). Substituting the data: d_0 = (5×10^6 N/cm^2) × (0.361×10^-9 m)^2 / (24π × 45×10^-6 J/m^2) = 1.92×10^-6 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（1.92×10^-6 m）。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及到的知识点较为基础，思维过程较为直接，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解扩展位错的概念和基本公式，但解题步骤相对直接，只需将给定数据代入单一公式进行计算即可。不需要多个公式组合或复杂推导，符合等级2的标准。" + }, + { + "idx": 2603, + "question": "In multi-electron atoms, what principles should the arrangement of extranuclear electrons follow?", + "answer": "The principle of lowest energy, Pauli exclusion principle, Hund's rule.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释多电子原子中核外电子排布遵循的原则，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对多电子原子核外电子排布遵循的基本原则的记忆和理解，包括能量最低原理、泡利不相容原理和洪特规则，这些都是材料科学中的基础概念，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生记忆并理解多电子原子中核外电子排布的三个基本原理（最低能量原理、泡利不相容原理和洪德规则）。虽然涉及多个概念，但都属于基础概念的记忆和简单应用，不需要复杂的分析或推理。因此属于中等难度（等级2）。" + }, + { + "idx": 2604, + "question": "In the periodic table, what are the differences in atomic structure of elements in the same period from left to right?", + "answer": "From left to right, the nuclear charge increases sequentially, and the atomic radius gradually decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素在同一周期中从左到右的原子结构差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查元素周期表中同一周期元素原子结构变化的基本概念，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并比较同一周期内元素原子结构的变化趋势（核电荷增加和原子半径减小），而不仅仅是记忆单一的定义。这要求考生对周期表的基本规律有一定的理解和应用能力，但不需要复杂的分析或推理步骤。" + }, + { + "idx": 2605, + "question": "In the periodic table, how do the properties of elements in the same main group change from top to bottom?", + "answer": "From top to bottom, the ionization energy decreases, the ability to lose electrons increases, the ability to gain electrons decreases, the metallic character increases, and the non-metallic character decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对元素周期表中同一主族元素性质的变化进行文字解释和论述，答案提供了详细的描述而非选择或判断。 | 知识层次: 题目考查元素周期表中主族元素性质变化的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个元素性质的变化规律（如电离能、得失电子能力、金属性等），但这些都属于同一主族元素性质的基础概念记忆和简单描述。不需要进行复杂的比较分析或推导，只需理解并记忆主族元素从上到下的性质变化趋势即可。因此，在选择题型内属于概念解释和描述的难度等级。" + }, + { + "idx": 2606, + "question": "In the periodic table, what are the common characteristics of atomic structures for elements in the same main group?", + "answer": "Elements in the same main group have the same number of outer electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释元素在同一主族中的共同特征，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目考查对元素周期表中主族元素原子结构共同特征的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察对元素周期表主族元素外层电子数相同这一基础定义的记忆，无需解释或分析，属于最基本的概念记忆题。" + }, + { + "idx": 2607, + "question": "Why is the relative atomic mass of an element not always a whole number?", + "answer": "Because different isotopes contain varying numbers of neutrons (while having the same number of protons), elements with multiple isotopes in different abundances have a relative atomic mass that is not a whole number.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么元素的相对原子质量不总是整数，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对同位素和相对原子质量的基本概念的理解，属于基础概念记忆和简单解释的范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解同位素的概念以及它们如何影响相对原子质量的计算。正确选项解释了不同同位素的中子数差异及其丰度对相对原子质量的影响，这超出了简单的定义记忆，需要对概念进行一定的解释和描述。因此，该题目在选择题型中属于等级2难度。" + }, + { + "idx": 2608, + "question": "Estimate the equilibrium width of extended dislocations in stainless steel. Given the lattice constant of stainless steel a = 0.356 nm, shear modulus G = 10×10^6 N/cm^2, and stacking fault energy γ_I = 15×10^-6 J/m^2.", + "answer": "Stainless steel has a face-centered cubic structure, and the equilibrium width of extended dislocations d_0 = G a^2 / (24πγ_I). Substituting the data: d_0 = (10×10^6 N/cm^2) × (0.356×10^-9 m)^2 / (24π × 15×10^-6 J/m^2) = 1.12×10^-5 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目需要应用公式进行多步计算，涉及材料科学中的基本概念（如剪切模量、堆垛层错能）和公式推导，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如晶格常数、剪切模量、堆垛层错能）并进行多步骤计算。题目要求将给定的公式代入数值并进行单位换算，涉及中等应用层次的知识综合运用。虽然计算过程明确，但需要较强的概念关联能力和计算准确性。" + }, + { + "idx": 2609, + "question": "In the periodic table, what are the differences in atomic structure from top to bottom for elements in the same main group?", + "answer": "From top to bottom, the number of electron shells increases, and the atomic radius becomes larger.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释同一主族元素从上到下原子结构的变化，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对元素周期表中同主族元素原子结构变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（元素周期表中同主族元素的原子结构变化），但需要考生理解并描述两个关键变化（电子层数增加和原子半径增大），而不仅仅是简单的定义回忆。这要求考生对周期表趋势有一定的理解和描述能力，但不需要复杂的分析或比较。" + }, + { + "idx": 2610, + "question": "In the periodic table, what common characteristics do the atomic structures of elements in the same period have?", + "answer": "Elements in the same period have the same number of electron shells outside the atomic nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释元素周期表中同一周期元素的共同特征，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对元素周期表中同周期元素原子结构共同特征的基本概念记忆，仅需要回答电子层数相同这一基本原理，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求记忆元素周期表中同一周期元素的共同特征（电子层数相同），不需要进行概念解释或复杂分析。正确选项直接对应基础概念记忆层次，解题步骤简单明了，属于选择题型中最基础的难度等级。" + }, + { + "idx": 2611, + "question": "What are isotopes?", + "answer": "Substances that occupy the same position in the periodic table, although their masses are different, yet their chemical properties are the same, are called isotopes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述同位素的定义，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查同位素的基本定义和特性，属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别同位素的基本定义，属于最基础的概念记忆层次。正确选项直接给出了同位素的明确定义，无需进行任何解释、比较或分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2612, + "question": "In the periodic table, how do the properties of elements change from left to right within the same period?", + "answer": "From left to right, ionization energy increases, the ability to lose electrons decreases, the ability to gain electrons increases, metallic character weakens, and non-metallic character strengthens.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素周期表中同一周期内元素性质的变化趋势，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查元素周期表中同一周期内元素性质变化的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个元素性质的变化趋势（电离能、得失电子能力、金属性/非金属性），但这些都属于基础概念记忆范畴，且变化规律在周期表中呈现系统性。考生需要理解并记忆这些规律，但不需要进行复杂的推导或分析。相比等级1的简单定义题，该题需要整合多个相关概念；但相比等级3的复杂概念体系阐述题，其知识点的关联性和深度要求较低。" + }, + { + "idx": 2613, + "question": "The atomic number of chromium is 24, and it has a total of 4 isotopes: 4.31% of Cr atoms contain 26 neutrons, 83.76% contain 28 neutrons, 9.55% contain 29 neutrons, and 2.38% contain 30 neutrons. Calculate the relative atomic mass of chromium.", + "answer": "$A{\\tau}=0.0431\\times(24+26)+0.8376\\times(24+28)+0.0955\\times(24+29)$ $+0.0238\\times(24+30)=52.057$ 1-6 $A", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铬的相对原子质量，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要考查基本公式应用和简单计算，涉及同位素丰度和相对原子质量的计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题中属于简单难度，题目要求应用基本公式（相对原子质量计算）并进行简单计算。虽然涉及多个同位素的比例和计算步骤，但每一步都是直接套用公式，没有复杂的推理或分析过程。" + }, + { + "idx": 2614, + "question": "The atomic number of tin is 50, and except for the 4f subshell, all other inner electron subshells are filled. Determine the number of valence electrons in tin from the perspective of atomic structure.", + "answer": "1s²2s²2p63s²3p63d104s²4p64d105s²5p²; the number of valence electrons in tin is 4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从原子结构的角度确定锡的价电子数，并给出了详细的电子排布和价电子数的答案。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对原子结构和电子排布的基本概念的记忆和理解，需要根据给定的原子序数和电子排布规则写出电子构型并确定价电子数，属于基础概念记忆的范畴。 | 难度: 在选择题型中，该题目需要考生理解原子结构的基本概念，包括电子排布和价电子的定义。虽然题目提供了部分电子排布信息，但考生仍需根据原子序数和给定的条件推断出完整的电子排布，并从中识别价电子。这比简单的定义记忆（等级1）更复杂，但不需要复杂的分析或概念体系阐述（等级3）。因此，该题目属于概念解释和描述的难度等级2。" + }, + { + "idx": 2615, + "question": "Given that the atomic number of an element is 32, based on the knowledge of atomic electronic structure, write its electron configuration.", + "answer": "1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于原子电子结构知识写出电子排布式，需要文字解释和论述，答案是一个具体的电子排布式而非数值计算或选择判断 | 知识层次: 题目考查对原子电子结构基础知识的记忆和理解，需要根据原子数直接写出电子排布式，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求根据给定的原子数直接写出电子排布，属于基础概念记忆的范畴。解题步骤简单，只需按照电子填充顺序（1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p）进行填写，无需复杂的分析或比较。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2616, + "question": "The atomic number of copper is 29, its relative atomic mass is 63.54, and it has two isotopes, Cu63 and Cu65. Calculate the percentage content of the two copper isotopes.", + "answer": "$A{\\\\mathrm{r}}=63.54=63x+65\\\\times(1-x);\\\\quad x={\\\\frac{65-63.54}{2}}=0.73\\\\rightarrow73\\\\mathcal{V}_{0}\\\\left(\\\\mathrm{Cu}^{\\\\mathrm{63}}\\\\right);$ $1-x=0.27\\\\substack{\\\\rightarrow27\\\\%(\\\\mathrm{Cu}^{65})}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种铜同位素的百分比含量，答案展示了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式应用和简单计算，通过给定的原子质量和同位素信息直接套用公式求解百分比含量，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及同位素百分比的计算，但解题步骤明确且直接，只需套用给定的相对原子质量公式并进行简单的代数运算即可得出答案。不需要复杂的推理或多步骤的公式组合，因此难度等级为2。" + }, + { + "idx": 2618, + "question": "What are the characteristics of physical bonds (van der Waals forces)?", + "answer": "Physical bonds: secondary bonds, also known as van der Waals forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释物理键（范德华力）的特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查物理键（范德华力）的基本特征和定义，属于基础概念的记忆和理解范畴 | 难度: 在选择题型中，该题目仅要求识别物理键（范德华力）的基本定义和分类，属于基础概念记忆层次。题目仅需选择正确选项，无需复杂分析或概念比较，解题步骤简单直接。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2619, + "question": "Given that the atomic number of an element is 32, based on its electron configuration, indicate which period it belongs to.", + "answer": "The fourth period", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于电子构型指出元素所属的周期，需要文字解释和论述，答案形式为简短的文字回答而非选择、判断或计算。 | 知识层次: 题目考查对元素周期表周期划分的基本概念记忆和理解，仅需根据原子序数确定电子排布并对应到周期表的位置，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅需要记忆原子序数与周期表周期的对应关系，属于基础概念记忆的简单应用。解题步骤简单，只需根据原子序数32直接对应到第四周期，无需复杂推理或概念整合。" + }, + { + "idx": 2620, + "question": "The atomic number of platinum is 78, it has only 9 electrons in the 5d subshell and no electrons in the 5f subshell. How many electrons are there in the 6s subshell of Pt?", + "answer": "$\\\\mathrm{ls^{2}2s^{2}2p^{6}3s^{2}3p^{6}3d^{10}4s^{2}4p^{6}4d^{10}4f^{14}5s^{2}5p^{6}5d^{9}6s^{1}};$ $2+8+18+32+17=77;\\\\quad78-77=1$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定铂原子6s子壳层中的电子数，答案涉及电子排布和数值计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括电子排布的规则理解和应用，以及简单的减法运算。虽然不涉及复杂的推理分析，但需要综合运用电子排布的知识和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要掌握电子排布规则并进行多步计算。题目要求考生理解铂原子（原子序数78）的电子排布，特别是5d和6s轨道的填充情况。解题过程涉及核对电子总数（78个电子）与已给出电子排布的总和（77个电子）之间的差异，从而得出6s轨道有1个电子的结论。虽然题目提供了部分电子排布信息，但仍需要考生具备综合分析能力和计算技巧，属于综合性计算问题。" + }, + { + "idx": 2621, + "question": "How many types of bonds exist between atoms?", + "answer": "There are 5 types of bonds between atoms: metallic bond, ionic bond, covalent bond, physical bond (van der Waals force), hydrogen bond.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并解释原子间存在的键类型，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查基本概念的记忆和理解，仅需列举原子间键合的类型，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆和识别五种基本化学键的类型，属于基础概念记忆层次。题目不涉及概念解释、比较或复杂分析，仅需简单回忆知识点即可作答，因此属于最低难度等级。" + }, + { + "idx": 2622, + "question": "Given that the atomic number of an element is 32, based on its electron configuration, identify which group it belongs to.", + "answer": "Group IVA", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于电子构型识别元素所属的族，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对元素周期表中元素分组的基本概念的记忆和理解，仅需根据原子序数确定电子排布并对应到相应的族，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要记忆原子序数与电子排布的关系，并能根据电子排布判断元素所属的族。虽然涉及基础概念记忆，但需要一定的知识应用能力，比单纯的定义记忆稍复杂。" + }, + { + "idx": 2624, + "question": "Given that the atomic number of an element is 32, determine the strength of its metallic character based on its electron configuration.", + "answer": "Metalloid Ge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据给定的原子序数确定元素的金属特性，并基于电子构型进行解释。答案需要文字描述（\"Metalloid Ge\"）而非选择、判断或计算。 | 知识层次: 题目需要根据原子序数确定元素（锗），并分析其电子构型以判断金属性强度。这涉及多步推理和概念关联，包括元素周期表位置、电子构型与金属性之间的关系等综合分析。虽然不涉及复杂计算，但需要一定的概念理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求根据原子序数32确定元素的金属性强度，涉及电子排布和元素周期表位置的综合分析。虽然解题步骤较为直接（确定元素为Ge并识别其类金属性质），但需要学生掌握电子构型与周期性趋势的关联知识，属于中等应用层次的多步计算和概念关联题型。" + }, + { + "idx": 2626, + "question": "Given that the relative atomic mass of Si is 28.09, if there are 5×10^10 electrons capable of free movement in 100g of Si, calculate the proportion of freely moving electrons to the total number of valence electrons.", + "answer": "Number of atoms = (100 / 28.09) × 6.023 × 10^23 = 2.144 × 10^24; Number of valence electrons = 4 × number of atoms = 4 × 2.144 × 10^24 = 8.576 × 10^24; Proportion = (5 × 10^10) / (8.576 × 10^24) = 5.830 × 10^-15", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算原子数量、价电子数量以及自由电子比例。答案以数值形式呈现，展示了具体的计算步骤和结果。 | 知识层次: 题目需要进行多步计算，包括原子数量的计算、价电子总数的计算以及最终比例的计算。虽然涉及的概念（相对原子质量、价电子）是基础的，但需要将这些概念关联起来进行综合分析。思维过程要求一定的深度，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解相对原子质量、摩尔计算、价电子概念，并进行多步骤计算和综合分析。虽然题目提供了具体数值和计算步骤，但涉及的知识点较多且需要准确串联，对学生的概念掌握和计算能力要求较高。" + }, + { + "idx": 2627, + "question": "What does the short-range structure (primary structure) of polymer chain include?", + "answer": "Chemical structure, atomic arrangement in the molecular chain, bonding sequence of structural units, branching, cross-linking, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物链的短程结构（一级结构）包括哪些内容，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对聚合物短程结构（一级结构）基本组成要素的记忆和理解，属于基础概念范畴 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项包含了多个具体知识点（化学结构、分子链中的原子排列、结构单元的键合序列、支化、交联等），需要考生对聚合物短程结构的多个方面有较为全面的理解和记忆。相较于仅考察单一基本定义的题目（等级1），该题目要求考生能够综合掌握并区分多个相关概念，因此难度稍高。" + }, + { + "idx": 2628, + "question": "The density of Al2O3 is 3.8g/cm3, calculate how many atoms are present in 1 mm3?", + "answer": "The relative molecular mass of Al2O3 M=26.98×2+16×3=101.96, the number of atoms in 1mm3 is 1×3.8×10-3/101.96×6.023×1023×5=1.12×1020", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及密度、分子量和阿伏伽德罗常数的计算，最终得出具体数值答案。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解密度的概念和摩尔质量的计算，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用密度、摩尔质量和阿伏伽德罗常数等多个概念，但解题步骤相对直接，只需套用基本公式并进行简单计算即可得出答案。不需要复杂的逻辑推理或多步骤的组合计算，因此在选择题型内属于等级2难度。" + }, + { + "idx": 2629, + "question": "Although the relative molecular mass of HF is relatively low, please explain why the boiling temperature of HF (19.4 ℃) is higher than that of HCl (-85 ℃)?", + "answer": "This is because the intermolecular force in HF is hydrogen bonding, while that in HCl is van der Waals force. The bond energy of hydrogen bonding is higher than that of van der Waals force, so the boiling point of HF is higher than that of HCl.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释HF沸点高于HCl的原因，需要文字解释和论述，答案形式为简短的文字说明，而非选择、判断或计算。 | 知识层次: 题目要求解释HF和HCl沸点差异的原因，涉及氢键和范德华力的比较，需要理解分子间作用力的概念并进行分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解氢键和范德华力的概念，并能比较它们的键能差异对沸点的影响。虽然题目涉及多个概念的综合分析，但在选择题型中，正确选项直接给出了关键概念和结论，减少了推理步骤的复杂性。" + }, + { + "idx": 2631, + "question": "Given that the relative atomic mass of Si is 28.09, if there are 5×10^10 electrons capable of free movement in 100g of Si, calculate the proportion of covalent bonds that must be broken.", + "answer": "Number of covalent bonds = number of atoms = 2.144 × 10^24; Number of covalent bonds to be broken = (5 × 10^10) / 2 = 2.5 × 10^10; Proportion = (2.5 × 10^10) / (2.144 × 10^24) = 1.166 × 10^-14", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算共价键的数量、需要断裂的共价键数量以及比例。答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目需要进行多步计算，包括计算硅的原子数、自由电子数与共价键断裂数的关系，以及最终的比例计算。这需要理解硅的原子结构、共价键的性质以及自由电子的来源，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相对原子质量、自由电子与共价键的关系，并进行多步计算（包括摩尔计算、比例计算等）。虽然题目提供了具体数值，但解题步骤涉及概念关联和综合分析，对学生的应用能力要求较高。" + }, + { + "idx": 2632, + "question": "What does the long-range structure (secondary structure) of polymer chain structures include?", + "answer": "Relative molecular mass and its distribution, chain flexibility and conformation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释聚合物链结构的远程结构（二级结构）包括哪些内容，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查聚合物长程结构（二级结构）的基本概念，包括相对分子质量及其分布、链柔性和构象等基础知识的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生同时掌握聚合物长程结构的两个关键方面（相对分子质量及其分布、链柔性和构象），并理解它们之间的关联性。这比单纯记忆单一概念（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2633, + "question": "The density of Al2O3 is 3.8g/cm3, calculate how many atoms are contained in 1g?", + "answer": "The relative molecular mass of Al2O3 M=26.98×2+16×3=101.96, the number of atoms contained in 1g is 1/101.96×6.023×1023×5=2.95×1022", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算1g Al2O3中的原子数量），答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的分子量计算和摩尔概念的应用，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用相对分子质量和阿伏伽德罗常数的概念，但解题步骤较为直接，仅需套用基本公式并进行简单计算即可得出答案。不需要复杂的逻辑推理或多步骤转换，因此在选择题型内属于中等偏下难度。" + }, + { + "idx": 2634, + "question": "The percentage of ionic character in the bonding between elements A and B can be approximately expressed by the following formula: IC(%)=[1-e^(-0.25(x_A-x_B)^2)]×100, where x_A and x_B are the electronegativity values of elements A and B, respectively. Given that the electronegativities of In and Sb are 1.7 and 1.9, respectively, calculate the IC(%) for InSb.", + "answer": "For InSb: IC(%)=[1-e^(-0.25)(1.9-1.7)^2]×100=1.0%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，最终得出一个具体的百分比数值。解答过程涉及代入已知的电子亲和力值并进行数学运算，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，只需将给定的电负性值代入公式进行计算即可，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的公式进行简单计算，无需额外的概念理解或复杂的解题步骤。题目提供了所有必要的信息（电负性值和公式），学生只需将数值代入公式并完成基本的数学运算即可得出答案。因此，该题目在选择题型内属于最低难度等级。" + }, + { + "idx": 2635, + "question": "Explain the characteristics of thermoplastic polymer materials from the perspective of polymer chain structure", + "answer": "Thermoplastic polymers have linear and branched polymer chain structures, which soften upon heating and can be repeatedly processed and reshaped", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释热塑性聚合物材料的特性，需要从聚合物链结构的角度进行文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对热塑性聚合物链结构特征的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生从聚合物链结构的角度解释热塑性聚合物材料的特性，正确选项提供了线性与支化链结构、加热软化以及可重复加工等关键特征。虽然需要一定的记忆和理解，但不需要复杂的分析或比较多个概念，属于中等偏下的难度水平。" + }, + { + "idx": 2636, + "question": "The percentage of ionic character in the bonding between elements A and B can be approximately calculated using the following formula: IC(%)=[1-e^(-0.25(x_A-x_B)^2)]×100, where x_A and x_B are the electronegativity values of elements A and B, respectively. Given that the electronegativities of Ti and O are 1.5 and 3.5, respectively, calculate the IC(%) for TiO2.", + "answer": "For TiO2: IC(%)=[1-e^(-0.25)(3.5-1.5)^2]×100=63.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，最终得出一个具体的百分比数值（63.2%），这符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即根据给定的电负性值套用公式计算离子键百分比，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于最低难度等级。题目直接给出了计算公式和所需的电负性数值，仅需进行简单的代入和计算即可得出答案。解题步骤非常直接，无需理解多个概念或进行复杂的分析，完全符合等级1“单一公式直接计算”的标准。" + }, + { + "idx": 2637, + "question": "The chemical behavior of S sometimes resembles that of a hexavalent element, while other times it resembles a tetravalent element. Please explain the reason for this behavior of S.", + "answer": "The outermost electrons of S are 3s²3p⁴. When S combines with H to form H₂S, it accepts 2 electrons, and since S has 6 valence electrons in its outer shell, it behaves as a hexavalent element. When S combines with O to form SO₂, it provides 4 electrons, thus behaving as a tetravalent element.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释硫元素化学行为的原因，需要文字解释和论述，答案也是以文字形式详细说明了硫元素在不同化合物中的价态表现，符合简答题的特征。 | 知识层次: 题目要求解释硫元素在不同化合物中表现出不同化合价的原因，涉及对硫原子电子排布的理解以及在不同化学反应中电子行为的分析。这需要将基础概念（如电子排布、化合价）与实际化学反应相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解硫元素的外层电子构型（3s²3p⁴）及其在不同化合物中的行为变化。题目要求考生能够分析硫在形成H₂S和SO₂时的电子行为差异，并解释其表现为六价和四价元素的原因。这涉及对价电子概念的掌握以及在不同化学环境中的应用，属于中等应用层次的知识要求。" + }, + { + "idx": 2638, + "question": "Explain the characteristics of thermosetting polymer materials from the perspective of polymer chain structure", + "answer": "Thermosetting polymers have a three-dimensional (cross-linked network) polymer chain structure, are insoluble in any solvent, and cannot be melted. Once set, their shape cannot be altered and they cannot be recycled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从聚合物链结构的角度解释热固性聚合物材料的特性，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对热固性聚合物材料特性的基本概念记忆和理解，主要涉及聚合物链结构的描述和基本特性的解释，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生从聚合物链结构的角度解释热固性聚合物材料的特性，正确选项提供了关于热固性聚合物三维（交联网络）链结构、不溶性、不可熔性以及形状固定和不可回收性的详细描述。虽然需要记忆和理解这些特性，但不需要进行复杂的比较分析或阐述多个概念之间的关系，因此属于中等难度。" + }, + { + "idx": 2639, + "question": "Determine whether [-110] lies on the (111) plane", + "answer": "Using the zone law: h u + k v + l w = 0, here 1×(-1) + 1×1 + 1×0 = 0, thus [-110] lies on the (111) plane.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述（[-110]是否在(111)平面上）的对错，答案通过应用特定规则（zone law）进行验证，最终给出明确的判断结果。 | 知识层次: 题目需要应用基本的晶体学公式（zone law）进行简单计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（zone law）并进行简单计算即可得出正确结论。解题步骤明确且不复杂，无需深入分析或多步骤推理，符合等级2的简单应用结果判断标准。" + }, + { + "idx": 2640, + "question": "Calculate the number-average relative molecular mass $\\overline{M}_{n}$ of this polymer material, given the molecular weight range, average molecular weight M, and molecular number fraction.", + "answer": "The number-average relative molecular mass $\\overline{M}_{n} = \\sum x_{i}M_{i} = 375 + 2000 + 3850 + 6075 + 5500 + 2600 + 750 = 21150$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的分子量范围和分子数分数进行数值计算，应用公式求出数均相对分子质量，答案是一个具体的计算结果。 | 知识层次: 题目要求应用基本公式（数均分子量公式）进行直接计算，涉及简单的数值运算和公式套用，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（数均相对分子质量的计算公式）并进行简单的加法运算。题目提供了所有必要的数据，无需额外的分析或推导步骤，属于最基础的直接计算类型。" + }, + { + "idx": 2641, + "question": "Calculate the linear density in the [-110] direction", + "answer": "The formula for linear density is K = (4 × r) / l, where r = (√2 × a) / 4, l = √2 × a. Substituting gives K = (4 × (√2 × a / 4)) / (√2 × a) = 1. Therefore, the linear density in the [-110] direction is 1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和公式代入，最终得出一个数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解线性密度的定义并正确代入数值进行计算，但不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的线性密度公式，并进行简单的数值代入和计算。解题步骤非常直接，没有涉及多个公式的组合或复杂的概念分析，因此属于单一公式直接计算的难度等级1。" + }, + { + "idx": 2642, + "question": "Label the coordinates of all points on the (111) plane in a face-centered cubic unit cell", + "answer": "The coordinates of all points on the (111) plane in a face-centered cubic unit cell include: (0,0,0), (1,0,0), (0,1,0), (0,0,1), (1,1,0), (1,0,1), (0,1,1), (1,1,1).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出面心立方晶胞中(111)面上所有点的坐标，答案以文字形式给出具体坐标点，不需要计算或选择，属于简答题类型。 | 知识层次: 题目要求学生在理解面心立方晶胞结构的基础上，应用晶体学知识确定特定晶面（111）上的所有点坐标。这需要学生不仅记忆晶胞的基本结构，还需要理解晶面的定义和坐标的确定方法，并进行多步分析和综合。虽然不涉及复杂的计算或推理，但需要对概念进行关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求识别面心立方晶胞中(111)平面上的所有点坐标，涉及对晶体结构、晶面指数和坐标系统的综合理解。虽然题目给出了正确选项，但学生仍需掌握面心立方晶胞的基本结构、晶面指数的含义以及如何确定特定晶面上的点坐标。这需要中等层次的应用能力，包括多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2643, + "question": "Calculate the weight-average relative molecular mass $\\overline{M}_{w}$ of this polymer material, given the average molecular weight M and mass fraction.", + "answer": "The weight-average relative molecular mass $\\overline{M}_{w} = \\sum w_{i}M_{i} = 150 + 1250 + 3150 + 6525 + 7150 + 4225 + 750 = 23200.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的平均分子量和质量分数计算聚合物的重量平均相对分子质量，答案是通过数值计算得出的具体数值，符合计算题的特征。 | 知识层次: 题目要求应用基本的重量平均分子量公式进行计算，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用和简单计算，无需多个公式组合或复杂分析，属于最基础的难度等级。" + }, + { + "idx": 2644, + "question": "There is a copolymer ABS (A—acrylonitrile, B—butadiene, S—styrene), with the same mass fraction for each monomer. Calculate the mole fraction of each monomer.", + "answer": "Acrylonitrile (—C2H3CN—) monomer has a relative molecular mass of 53; butadiene (—C2H3C2H3—) monomer has a relative molecular mass of 54; styrene (—C2H3C6H5—) monomer has a relative molecular mass of 104. Assuming each weighs 1 g, then acrylonitrile has 1/53 mol, butadiene has 1/54 mol, and styrene has 1/104 mol. Therefore, the mole fractions of the monomers are: x_acrylonitrile = (1/53) / (1/53 + 1/54 + 1/104) = 40.1%; x_butadiene = (1/54) / (1/53 + 1/54 + 1/104) = 39.4%; x_styrene = (1/104) / (1/53 + 1/54 + 1/104) = 20.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算每个单体的摩尔分数，涉及数值计算和公式应用，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及基本的摩尔分数计算，需要应用相对分子质量和简单的数学运算，属于直接套用公式和基本计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算三个单体的摩尔分数，但每个步骤都是直接套用基本公式（摩尔分数定义），且计算过程较为直接。题目提供了所有必要的相对分子质量数据，避免了额外的查找或推导步骤。因此，在选择题型内属于等级2难度，比单一公式直接计算稍复杂，但不需要多个公式的组合或深入的概念分析。" + }, + { + "idx": 2645, + "question": "An organic compound consists of $\\\\mathbf{\\\\pi}\\\\mathbf{\\\\pi}(\\\\mathbf{C})$ at $62.1\\\\%$, $w(\\\\mathrm{H})$ at $\\\\mathtt{10.3\\\\%}$, and $\\\\boldsymbol{\\\\mathbf{\\\\hat{\\\\rho}}}\\\\mathbf{\\\\hat{\\\\rho}}\\\\mathbf{\\\\hat{\\\\rho}}$ at $27.6\\\\%$. Try to deduce the name of the compound.", + "answer": "The mole fractions of each component are $$ x_{\\\\mathrm{C}}=\\\\frac{62.1}{12.011}=5.2$$ $$ x_{{\\\\scriptscriptstyle\\\\mathrm{H}}}=\\\\frac{10,3}{1.008}{=}10,2$$ $$ x_{0}=\\\\frac{27\\\\cdot6}{16}=1.7$$ $$ \\\\begin{array}{r l}{\\\\mathrm{~C~}^{:}\\\\mathrm{~H~}^{:}\\\\mathrm{~O}=5.2:10.2:1.7\\\\approx3:6:1\\\\quad}&{{}\\\\mathrm{~H~}\\\\stackrel{\\\\mathrm{~O~}\\\\mathrm{~H~}}{\\\\longrightarrow}\\\\mathrm{C}-\\\\mathrm{C}-\\\\mathrm{H}}\\\\\\\\ {\\\\mathrm{~H~}^{:}\\\\mathrm{~H~}\\\\stackrel{\\\\mathrm{~O~}\\\\mathrm{~H~}}{\\\\longrightarrow}\\\\mathrm{~H~}}&{{}\\\\mathrm{~H~}\\\\stackrel{\\\\mathrm{~H~}}{\\\\longrightarrow}\\\\mathrm{~H~}}\\\\end{array}$$ Therefore, the possible compound is $\\\\mathrm{CH}_{3}\\\\mathrm{COCH}_{3}$ (acetone).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算和推理推导出化合物的名称，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要多步计算（摩尔分数计算、比例简化）和概念关联（元素比例与分子结构的对应关系），但不需要复杂的推理分析或机理解释。 | 难度: 在选择题型内，该题目属于较高难度。首先，题目要求考生通过百分比计算推导出有机化合物的分子式，这需要熟练掌握元素摩尔质量的计算和比例转换。其次，题目涉及多步计算和概念关联，包括将质量百分比转换为摩尔比，并进一步推导出可能的分子结构。最后，题目要求考生具备综合分析能力，能够将计算结果与已知的有机化合物结构进行匹配。这些步骤在选择题型中较为复杂，需要考生具备较高的知识应用能力和逻辑推理能力。" + }, + { + "idx": 2646, + "question": "Calculate the number-average degree of polymerization $n_{\\\\eta}$ of this polymer material, given the number-average relative molecular mass $\\\\overline{M}_{n}$ and the mass of each repeating unit.", + "answer": "The mass of each repeating unit $\\\\overline{m} = 2 \\\\times 12.01 + 3 \\\\times 1.008 + 35.45 = 62.50$. The number-average degree of polymerization $n_{\\\\eta} = \\\\frac{\\\\overline{M}_{n}}{\\\\overline{m}} = \\\\frac{21150}{62.50} = 338$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的数值（数均相对分子质量和每个重复单元的质量）进行计算，最终得出数均聚合度的数值结果。解答过程涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，仅需将给定的数值代入公式进行计算即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（$n_{\\\\eta} = \\\\frac{\\\\overline{M}_{n}}{\\\\overline{m}}$）并进行简单的数值计算。题目提供了所有必要的数据，解题步骤单一且直接，无需组合多个公式或进行复杂的概念分析，因此属于最低难度等级。" + }, + { + "idx": 2647, + "question": "High-density polyethylene can be chlorinated by replacing hydrogen atoms in the structural units with chlorine atoms. If 8% of the hydrogen atoms in polyethylene are replaced by chlorine, calculate the mass fraction of chlorine that needs to be added.", + "answer": "From the previous question, it is known that the structural unit of polyethylene contains 2 C atoms and 4 H atoms. If 8% of the H atoms are replaced by Cl atoms, the mass fraction of Cl that needs to be added is $$ \\\\begin{array}{r}{\\\\overbrace{2\\\\times A_{c}+4\\\\times(0.08\\\\times A_{\\\\mathrm{G}}+0.92\\\\times A_{\\\\mathrm{H}})}^{4\\\\times0.08\\\\times A_{\\\\mathrm{G}}}=\\\\overbrace{2\\\\times12.01+4\\\\times(0.08\\\\times35.45+0.921\\\\times1.001\\\\times1.001\\\\times1.001\\\\times1.001\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01\\\\times1.01}^{4\\\\times0.08\\\\times35.45}}\\\\\\\\ {=0,290=29.0\\\\%\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定需要添加的氯的质量分数。答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子质量的计算、替换比例的应用以及质量分数的求解。虽然不涉及复杂的推理分析或创新应用，但需要综合运用化学计量和百分比替换的概念，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解聚乙烯结构单元的概念，掌握氢原子被氯原子取代的比例计算，并进行多步质量分数计算。题目涉及原子质量、百分比替换和综合公式推导，虽然提供了正确选项的详细计算过程，但在选择题型内仍需要较强的概念关联和计算能力。" + }, + { + "idx": 2648, + "question": "It is known that pure titanium at 20°C is α-Ti (hcp structure), with lattice constants a=0.2951nm and c=0.4679nm. Calculate the interplanar spacing of the (112) plane.", + "answer": "For the hcp structure, when h+2k=3n (n=0,1,2,3...), and l is an odd number, there is an additional plane. d_(112)=1/√[(4/3)((h²+hk+k²)/a²)+(l/c)²]=1/√[(4/3)((1²+1×1+1²)/0.2951²)+(2/0.4679)²]=0.1248nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解(112)晶面的面间距，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用hcp结构的晶面间距计算公式，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要掌握hcp结构晶面间距的计算公式，理解晶面指数的含义，并能正确代入数值进行多步骤计算。题目涉及的概念和计算步骤较为复杂，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 2650, + "question": "It is known that pure titanium at 900°C is β-Ti (bcc structure) with a lattice constant a=0.3307nm. Calculate the interplanar spacing of the (112) plane.", + "answer": "For the bcc structure, there is an additional plane when h+k+l=odd number. d_(112)=a/√(h²+k²+l²)=0.3307/√(1²+1²+2²)=0.135nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及计算(112)晶面的晶面间距，解答过程需要使用给定的晶格常数和公式进行计算。 | 知识层次: 题目要求直接应用已知的bcc结构晶面间距公式进行计算，涉及基本的公式套用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解bcc结构的额外平面条件（h+k+l=奇数），但主要解题步骤是直接套用已知的晶面间距公式d=a/√(h²+k²+l²)进行简单计算。不需要多个公式组合或复杂推导，符合等级2\"简单公式应用计算\"的标准。" + }, + { + "idx": 2651, + "question": "Given that pure titanium at 900°C is β-Ti (bcc structure) with a lattice constant a=0.3307nm, calculate the (001) interplanar spacing.", + "answer": "For the (001) plane of bcc structure, d_(001)=1/2×a/√1²=1/2×0.3307/1=0.1653nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算(001)晶面间距），并应用了晶体学公式（d_(001)=a/√(h²+k²+l²)），答案是一个具体的计算结果（0.1653nm）。这符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及晶体学中晶面间距的计算，属于基础知识的直接运用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即d_(001)=1/2×a/√1²，无需额外的概念理解或步骤组合。属于最基础的难度等级。" + }, + { + "idx": 2652, + "question": "Indicate the crystal plane with the largest interplanar spacing in a face-centered cubic crystal", + "answer": "From the above calculation results, it is known that the (111) crystal plane, which has the densest atomic arrangement, has the largest interplanar spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出具有最大晶面间距的晶面，并给出了解释性的答案，需要文字解释和论述 | 知识层次: 题目考查对晶体学中晶面间距这一基本概念的记忆和理解，特别是面心立方晶体中不同晶面的原子排列密度与晶面间距的关系。虽然需要一定的计算，但主要是基于对基本概念的直接应用和记忆。 | 难度: 在选择题型中，该题目要求考生记忆并理解面心立方晶体中晶面间距的基本概念，特别是(111)晶面具有最大间距这一特定知识点。虽然涉及基础概念记忆，但需要考生对晶体结构有一定理解，而不仅仅是简单的定义回忆。因此属于中等难度。" + }, + { + "idx": 2653, + "question": "Calculate the interplanar spacing and planar density of the (100) plane in a face-centered cubic crystal", + "answer": "In a face-centered cubic crystal, when (h k l) are not all odd or all even, there are additional planes. d_(100)=1/2*a/sqrt(1^2+0+0)=0.5a; K_100=((1/4×4+1)πr^2)/a^2=(2πr^2)/((4/sqrt(2))r)^2=0.785", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的数学运算和晶体学公式的使用，最终给出了具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括晶面间距的计算和平面密度的计算，涉及面心立方晶体结构的基本原理和公式应用。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方晶体的结构特点、晶面间距计算公式以及平面密度的概念，并进行多步计算和综合分析。虽然题目提供了正确选项，但考生仍需掌握相关公式和计算步骤才能正确理解和选择答案。" + }, + { + "idx": 2654, + "question": "Using the method of analytic geometry, how to determine the crystallographic direction indices of the intersection line between two crystal planes in a cubic crystal system", + "answer": "Let there be two non-parallel crystal planes (h1,k1,l1) and (h2,k2,l2) in a cubic crystal system, and their intersection line is [u v w]. According to geometric relations, this crystallographic direction should lie on both crystal planes simultaneously, hence the following system of equations can be obtained: h1u+k1v+l1w=0, h2u+k2v+l2w=0. Solving the above system of equations yields u:v:w=(k1l2-l1k2):(l1h2-h1l2):(h1k2-h1h2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过解析几何方法确定立方晶系中两个晶面交线的晶向指数，解答过程涉及建立方程组并求解，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目需要应用几何关系和方程组求解，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体几何学中的方向指数和平面指数的关系，并能够进行多步计算和综合分析。题目要求掌握立方晶系中两个非平行晶面交线的方向指数的确定方法，涉及解线性方程组和向量叉积的概念，属于中等应用层次的知识。虽然题目给出了明确的解题步骤，但在选择题型中仍需要较高的理解能力和计算能力来正确解答。" + }, + { + "idx": 2655, + "question": "Using the method of analytic geometry, how to determine the crystallographic plane indices defined by two crystallographic directions in a cubic crystal system", + "answer": "Assume there are two non-parallel crystallographic directions [u1,v1,w1] and [u2,v2,w2] in the crystal. The crystallographic plane indices defined by them are (hkl). According to the zone law, we have the equation system: u1h+v1k+w1l=0, u2h+v2k+w2l=0. Solving the above equations yields h:k:l=(v1w2-w1v2):(w1u2-u1w2):(u1v2-v1u2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过解析几何方法确定立方晶系中由两个晶向定义的晶面指数，解答过程涉及方程组的建立和求解，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目需要应用解析几何方法解决晶体学问题，涉及多个步骤的计算（建立方程组、求解比例关系），并且需要理解晶带定律的概念及其在立方晶系中的应用。虽然不涉及复杂的机理分析或创新设计，但需要将几何知识与晶体学知识进行关联和综合运用。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体学方向与晶面指数的关系，掌握带轴定律（zone law），并能够解二元一次方程组来确定晶面指数。虽然题目给出了明确的解题步骤，但需要综合应用多个概念并进行多步计算，属于综合性计算问题。" + }, + { + "idx": 2656, + "question": "Using the method of analytic geometry, how to determine the angle θ between two crystallographic directions in a cubic crystal system", + "answer": "Let the two crystallographic directions in the cubic crystal system be [u1,v1,w1] and [u2,v2,w2]. From the scalar product of vectors, we know: [u1,v1,w1]·[u2,v2,w2]=|[u1,v1,w1]|·|[u2,v2,w2]|·cosθ. Therefore, the angle θ between the two crystallographic directions can be obtained from its cosine value: cosθ=(u1u2+v1v2+w1w2)/(√(u1²+v1²+w1²)·√(u2²+v2²+w2²)), θ=arccos(cosθ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶系中两个晶向之间的夹角，答案涉及向量点积和模的计算，并最终通过反余弦函数求得角度值，属于典型的计算题。 | 知识层次: 题目主要涉及基本的向量点积公式应用和简单的反余弦计算，属于直接套用公式进行求解的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解向量点积和反余弦的概念，但解题步骤直接且明确，仅需套用给定的公式进行计算。相较于需要多个公式组合或复杂分析的题目，此题的难度较低，属于等级2。" + }, + { + "idx": 2657, + "question": "Calculate the interplanar spacing and planar density of the (110) plane in a face-centered cubic crystal.", + "answer": "In a face-centered cubic crystal, when (h k l) are not all odd or all even, there is an additional plane. d_(110)=1/2*a/sqrt(1^2+1^2+0)=0.354a; K_110=((1/4×4+1/2×2)πr^2)/(sqrt(2)*a^2)=(2πr^2)/(sqrt(2)(4/sqrt(2))r)^2=0.555", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算晶面间距和面密度），并应用了具体的公式（d_(110)和K_110的计算过程），答案也以数值结果呈现。 | 知识层次: 题目需要应用晶体学中的面间距计算公式和面密度计算方法，涉及多步计算和概念关联，如理解面心立方晶体的特点、计算面间距d_(110)和面密度K_110，需要综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方晶体的结构特点、晶面间距计算公式以及平面密度的计算方法。题目涉及多步计算和概念关联，包括判断晶面是否存在附加平面、计算晶面间距以及平面密度，综合性强。虽然题目提供了正确选项，但理解和推导过程较为复杂，需要一定的综合分析能力。" + }, + { + "idx": 2658, + "question": "Using the method of analytic geometry, how to determine the angle θ between two crystal planes in a cubic crystal system", + "answer": "Let there be two crystal planes (h1,k1,l1) and (h2,k2,l2) in the cubic crystal system. The angle θ between them is the angle between their respective normals [h1,k1,l1] and [h2,k2,l2]. Therefore, cosθ=(h1h2+k1k2+l1l2)/(√(h1²+k1²+l1²)·√(h2²+k2²+l2²)), and the angle θ between the two crystal planes is θ=arccos(cosθ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶系中两个晶面之间的夹角θ，答案中给出了具体的计算公式和步骤，涉及数值计算和公式应用。 | 知识层次: 题目需要应用解析几何方法计算立方晶系中两个晶面之间的夹角，涉及多步计算（包括向量点积和模的计算）和概念关联（晶面指数与法向量的关系），但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握立方晶系中晶面夹角的计算方法，涉及向量点积和反余弦函数的应用。虽然计算步骤较多，但在选择题型中，考生只需识别正确的公式和步骤，无需实际进行复杂计算，因此难度适中。" + }, + { + "idx": 2659, + "question": "Calculate the interplanar spacing and planar density of the (111) plane in a face-centered cubic crystal.", + "answer": "In a face-centered cubic crystal, when (h k l) are not all odd or all even, there are additional planes. d_(111)=a/sqrt(1^2+1^2+1^2)=0.577a; K_111=((1/6×3+1/2×3)πr^2)/(sqrt(3)/4*(sqrt(2)a)^2)=(2πr^2)/(sqrt(3)/4(sqrt(2)*4/sqrt(2))r)^2=0.907", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算面心立方晶体中(111)晶面的晶面间距和面密度，答案涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶面间距的计算和平面密度的计算，涉及公式应用和概念关联，需要综合分析晶体结构和几何关系。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方晶体的结构特点、晶面间距计算公式以及面密度的计算方法。题目涉及多步计算和概念关联，包括晶格常数与原子半径的关系转换，以及分数原子的计算。虽然选项提供了完整解答路径，但需要考生具备扎实的晶体学基础和计算能力才能正确理解和选择。" + }, + { + "idx": 2660, + "question": "Using Cu's ka (λ=0.1542 nm), the first line of Cr's X-ray diffraction spectrum was measured at 2θ=64.6°. If the lattice constant a of (bcc) Cr is 0.2885 nm, find the Miller indices corresponding to these spectral lines.", + "answer": "According to the formula d_hkl=a/sqrt(h^2+k^2+l^2)=λ/(2sinθ), if 2θ=64.6°, then h^2+k^2+l^2={(2sin(64.6°/2)×0.2885)/0.1542}^2=3.9976≈4. Therefore, this plane is (200), or (020) or (002).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的波长、角度和晶格常数，利用布拉格方程计算晶面指数。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括布拉格定律的应用和晶面间距公式的计算），并需要将计算结果与晶面指数关联起来。虽然计算过程相对直接，但需要理解X射线衍射的基本原理和立方晶系的晶面间距公式，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解X射线衍射的基本原理，掌握晶面间距的计算公式，并能正确应用布拉格方程。题目涉及多步计算和概念关联，包括角度转换、晶面间距计算和米勒指数的确定。虽然题目提供了必要的公式和数据，但解题过程需要一定的综合分析能力。" + }, + { + "idx": 2661, + "question": "The crystal structure of Ni is face-centered cubic, and its atomic radius is r=0.1243nm. Calculate the lattice constant of Ni.", + "answer": "a=4r/sqrt(2)=4×0.1243/sqrt(2)=0.3516(nm)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用原子半径和面心立方晶格常数公式）来求解镍的晶格常数，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要套用已知的原子半径和面心立方晶格常数的关系公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了面心立方晶体的晶格常数计算公式a=4r/sqrt(2)，只需要将给定的原子半径r=0.1243nm代入公式进行简单计算即可得到正确答案。不需要额外的概念理解或复杂的解题步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2664, + "question": "The crystal structure of Ni is face-centered cubic, with an atomic radius of r=0.1243nm and a lattice constant of a=0.3516nm. Calculate the density of Ni.", + "answer": "ρ=4Ar/(a³×NA)=4×58.69/((3.516×10^-8)^3×6.023×10^23)=8.967(g/cm³)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的晶体结构参数（原子半径和晶格常数）进行计算，以得出镍的密度。答案涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目要求应用基本的密度计算公式，涉及简单的数值计算和单位转换，属于直接套用公式的简单应用层次。虽然需要理解晶体结构和相关参数的含义，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要掌握面心立方晶体的密度计算公式，但题目已经提供了所有必要的参数（原子半径、晶格常数、原子量和阿伏伽德罗常数），并且正确选项直接展示了计算过程。学生只需正确代入数值并进行简单计算即可得出答案，无需进行复杂的推导或多步骤分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2665, + "question": "One of the allotropes of Mn has a cubic structure with a lattice constant a of 0.632 nm, an atomic radius r of 0.122 nm, and 20 atoms in the unit cell. What is its packing density?", + "answer": "The packing density K = (20 * (4/3) * π * r³) / a³. Substituting the data: K = (20 * (4/3) * π * (0.122)^3) / (0.632)^3 = 0.466.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Mn的堆积密度，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过给定的原子半径和晶格常数计算堆积密度，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，无需复杂的推理或多步骤操作。题目提供了所有必要的数据，学生只需将数值代入给定的公式即可得出答案。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 2666, + "question": "The lattice constant of Cr is $\\mathbf{a=0.2884nm}$, and the density is $\\rho{=}7.19\\mathrm{g}/\\mathrm{cm}^{3}$. Determine the crystal structure of $\\mathrm{Cr}$ at this time.", + "answer": "p= $\\rho{=}\\frac{n A_{\\tau}}{a\\times N_{\\mathrm{A}}}\\Rightarrow n=\\frac{\\rho a^{3}N_{\\mathrm{A}}}{A_{\\tau}}{=}\\frac{7.19\\times(2.884\\times10^{-8})^{3}\\times6.023\\times10^{23}}{52.0}{=}1.9977\\approx2$, hence it is a bcc structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体的结构，解答过程中涉及到了密度、晶格常数、阿伏伽德罗常数等物理量的计算，最终通过计算结果得出晶体结构类型。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换和数值计算，同时需要将计算结果与晶体结构理论关联起来进行综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算、单位换算等多个概念，并进行多步骤计算和综合分析。虽然题目提供了公式和计算过程，但考生仍需掌握相关知识点才能正确理解和应用。" + }, + { + "idx": 2667, + "question": "In indium with a tetragonal structure, the relative atomic mass A_r=114.82, atomic radius r=0.1625 nm, lattice constants a=0.3252 nm, c=0.4946 nm, and density ρ=7.286 g/cm³. What is the packing fraction of In?", + "answer": "K=(2×(4/3)πr³)/(a²c)=(2×(4/3)π(0.1625)^3)/((0.3252)^2×0.4946)=0.6873.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铟的堆积分数，答案是一个具体的数值计算结果，解答过程涉及使用给定的参数和公式进行运算。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的原子半径和晶格常数计算堆积分数。虽然需要理解堆积分数的概念，但整体过程是直接套用公式进行计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用体积分数公式，但解题步骤明确且直接，仅需代入给定数据进行计算，无需复杂的推理或多步骤组合。属于基础知识的直接应用层次。" + }, + { + "idx": 2668, + "question": "In indium with a tetragonal structure, the relative atomic mass A_r=114.82, atomic radius r=0.1625 nm, lattice constants a=0.3252 nm, c=0.4946 nm, and density ρ=7.286 g/cm³. How many atoms are there in the unit cell of In?", + "answer": "n=(ρa²c×N_A)/A_r=(7.286×(3.252×10^-8)^2×(4.946×10^-8)×6.023×10^23)/114.82=1.9991≈2. Therefore, there are 2 atoms in the unit cell of In.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞中的原子数量，答案涉及具体的数学运算和单位转换。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的密度、晶格常数和相对原子质量等参数，直接套用公式计算单位晶胞中的原子数。虽然需要理解相关概念和公式，但思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及密度、晶格常数和原子质量等多个参数，但解题步骤明确且直接，只需套用单一公式（单位晶胞原子数计算公式）并进行简单代数运算即可得出答案。不需要复杂的逻辑推理或多步骤推导，符合选择题型中等级2的难度标准。" + }, + { + "idx": 2669, + "question": "One of the allotropes of Mn has a cubic structure with a lattice constant a of 0.632nm, ρ of 7.26g/cm³, and Ar of 54.94. How many atoms are there in the Mn unit cell?", + "answer": "According to the formula ρ = (n * Ar) / (a³ * NA), it can be derived that n = (ρ * a³ * NA) / Ar. Substituting the data: n = (7.26 * (6.32 * 10^-8)^3 * 6.023 * 10^23) / 54.94 = 20.091 ≈ 20. Therefore, there are 20 atoms in each unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞中的原子数量，答案涉及具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换和数值计算，同时需要理解晶格常数、密度和原子量之间的关系。虽然不涉及复杂的推理分析，但需要综合运用多个概念进行计算。 | 难度: 在选择题中属于中等偏上难度，需要掌握晶体结构、密度计算和单位换算等多个概念，并进行多步骤的综合计算。虽然题目提供了公式和数据，但需要正确代入和运算，涉及单位转换和科学计数法的处理，对学生的计算能力和概念理解有一定要求。" + }, + { + "idx": 2670, + "question": "The crystal structure of Mo is body-centered cubic, with a lattice constant $a{=}0.3147{\\mathrm{~nm}}$. Determine the atomic radius $\\\\scriptstyle{\\\\mathcal{r}}_{\\\\circ}$ of Mo.", + "answer": "$$ \\\\alpha{=}\\\\frac{4r}{\\\\sqrt{3}}\\\\Rightarrow r{=}\\\\frac{\\\\sqrt{3}}{4}\\\\alpha{=}\\\\frac{\\\\sqrt{3}}{4}\\\\times0.3147{=}0.1363(\\\\mathrm{nm})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（体心立方晶格常数与原子半径的关系公式）来求解Mo的原子半径，答案是一个具体的数值计算结果。 | 知识层次: 题目考查基本的公式应用和简单计算，仅需将已知的晶格常数代入体心立方结构的原子半径公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目仅涉及单一公式的直接应用（体心立方晶格常数与原子半径的关系公式），解题步骤简单明确，只需将已知数值代入公式并进行简单计算即可得出答案。无需多个公式组合或复杂分析，符合等级2的标准。" + }, + { + "idx": 2671, + "question": "Compared with question 1, explain the reasons for the difference.", + "answer": "Reasons for the difference: different crystal structures and different atomic radii; when the coordination number of atoms in the crystal structure decreases, the atomic radius contracts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释晶体结构和原子半径差异的原因，涉及对晶体结构变化与原子半径关系的深入理解和分析，需要综合运用材料科学知识进行推理和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2672, + "question": "If the atomic fraction of Zn dissolved in a Cu crystal is 10%, what is the maximum additional atomic fraction of Sn that can be dissolved?", + "answer": "1.36=(1(100-10-x3)+2×10+4x3)/100, solving gives x3=8.67, meaning a maximum of 8.67% Sn can be additionally dissolved.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的原子分数和公式求解最大可溶解的Sn原子分数。答案是通过具体计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和公式应用，涉及原子分数的计算和溶解度的理解，需要综合分析不同元素在晶体中的溶解行为，并运用数学方法求解。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体原子分数计算的概念，并能够正确设置和求解方程。题目涉及多步计算和概念关联，需要综合分析能力来正确解答。虽然题目给出了正确选项的计算过程，但理解并应用这些步骤仍然需要一定的专业知识。" + }, + { + "idx": 2673, + "question": "What is the maximum atomic fraction of Zn or Sn that can be dissolved in Cu-Zn and Cu-Sn solid solutions?", + "answer": "The limiting electron concentration for Cu-based solid solutions is 1.36. For the Cu-Zn solid solution, 1.36=(1(100-x1)+2x1)/100→x1=36, so the maximum solubility is 36% Zn; for the Cu-Sn solid solution, 1.36=(1(100-x2)+4x2)/100→x2=12, so the maximum solubility is 12% Sn.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定Cu-Zn和Cu-Sn固溶体中Zn和Sn的最大原子分数。解答过程中涉及电子浓度的计算和代数方程的求解，这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算，涉及电子浓度的概念应用和公式推导，需要理解电子浓度与溶解度之间的关系，并进行相应的数值计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解电子浓度概念并进行多步计算。题目涉及两个独立的计算过程（Cu-Zn和Cu-Sn），每个都需要正确应用公式并解方程。虽然计算本身不复杂，但需要将理论概念与数学计算相结合，且要求考生能同时处理两个相似但不同的案例。这比单纯的概念记忆题或单一计算题更具挑战性，但尚未达到需要处理多变量或非常规计算的最高难度水平。" + }, + { + "idx": 2674, + "question": "According to X-ray diffraction measurements, at 912°C, the lattice parameter a of α-Fe is 0.2892 nm, and that of γ-Fe is 0.3633 nm. Calculate the volume expansion when γ-Fe transforms into α-Fe.", + "answer": "fcc: r = sqrt(2)/4 * a = sqrt(2)/4 * 0.3633 = 0.1284 nm; bcc: r = sqrt(3)/4 * a = sqrt(3)/4 * 0.2892 = 0.1251 nm; ΔV = (1/2 * (0.2892)^3 - 1/4 * (0.3633)^3) / (1/4 * (0.3633)^3) = 0.87%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶格参数和体积变化的计算，答案以数值结果呈现。 | 知识层次: 题目需要进行多步计算，包括晶格参数转换、体积计算和体积变化率的计算，涉及fcc和bcc晶体结构的几何关系，需要综合应用材料科学中的晶体学知识。虽然不涉及复杂的机理分析或创新设计，但计算过程需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构（fcc和bcc）的几何关系，掌握晶格参数与原子半径的换算公式，并进行多步计算（包括立方运算和百分比变化）。虽然题目提供了关键参数，但解题过程涉及多个概念的关联和综合计算，属于典型的综合性计算问题。" + }, + { + "idx": 2675, + "question": "Cementite (Fe3C) is an interstitial compound with an orthorhombic crystal structure. Its lattice constants are a=0.4514nm, b=0.508nm, c=0.6734nm, and its density ρ=7.66g/cm³. Determine the number of Fe and C atoms per unit cell of Fe3C.", + "answer": "Assume the number of C atoms in the Fe3C unit cell is x, then the number of Fe atoms is 3x. ρ = (x Ar(C) + 3 × Ar(Fe)) / (a b c × NA), 7.66 = (x × 12.011 + 3x × 55.85) / (4.514 × 5.08 × 6.743 × 10^-24 × 6.023 × 10^23). x = (7.66 × 4.514 × 5.08 × 6.734 × 0.602) / (12.011 + 3 × 55.85) = 3.968 ≈ 4. 3x = 12. Therefore, in the Fe3C compound, each unit cell contains 4 C atoms and 12 Fe atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定Fe3C晶胞中的Fe和C原子数量，解答过程涉及密度、晶格常数和原子量的计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及晶体结构、密度公式的应用以及原子量的计算，需要将多个概念关联起来进行综合分析。虽然不涉及复杂的推理分析或创新应用，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算、化学计量比等多个概念，并进行多步骤的综合计算。虽然题目提供了正确选项，但解题过程涉及单位换算、公式应用和数值计算，对学生的综合分析能力有一定要求。" + }, + { + "idx": 2676, + "question": "According to the hard sphere model of crystals, if the diameter of the spheres remains unchanged, calculate the volume expansion when Fe transforms from fcc to bcc.", + "answer": "a_fcc = 4 / sqrt(2) * r ⇒ V_fcc = a_fcc^3 = 64 / (2 * sqrt(2)) * r^3；a_bcc = 4 / sqrt(3) * r ⇒ V_bcc = a_bcc^3 = 64 / (3 * sqrt(3)) * r^3；ΔV = (1/2 * 64 / (3 * sqrt(3)) * r^3 - 1/4 * 64 / (2 * sqrt(2)) * r^3) / (1/4 * 64 / (2 * sqrt(2)) * r^3) = 9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及晶体结构参数的计算和体积变化的推导，最终得出具体的百分比结果。 | 知识层次: 题目需要应用硬球模型和晶体结构的知识，进行多步计算（包括晶格常数计算、体积计算和体积变化百分比计算），并理解fcc和bcc结构的几何关系。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解fcc和bcc的晶体结构模型，掌握晶格常数与原子半径的关系，并进行多步计算和综合分析。虽然题目提供了正确选项的计算过程，但考生仍需具备较强的空间想象能力和数学计算能力才能正确理解和应用这些公式。" + }, + { + "idx": 2677, + "question": "What is an interstitial phase? Explain its characteristics from the perspective of crystal structure.", + "answer": "Interstitial phases are intermediate phases dominated by atomic size factors. They are formed when nonmetal elements with smaller atomic radii occupy the interstitial sites of the lattice, yet the lattice of the interstitial phase differs from that of any of their constituent elements. Their composition can fluctuate within a certain range. However, the constituent elements generally have a specific atomic ratio, which can be represented by a chemical formula. When rB/rA < 0.59, interstitial phases usually form, characterized by a simple crystal structure, extremely high melting points, and hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙相的概念及其晶体结构特征，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对interstitial phase这一基础概念的定义和特性的记忆与理解，包括其形成条件、晶体结构特点以及物理性质等基本知识，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅要记住间隙相的定义，还需要理解其晶体结构特征、形成条件以及物理特性。这些知识点需要考生对材料科学中的晶体结构有较为深入的理解，而不仅仅是简单的定义记忆。因此，该题目在选择题型中属于概念解释和描述的难度等级。" + }, + { + "idx": 2678, + "question": "Given that the ionic radii of K⁺ and Cl⁻ are 0.133nm and 0.181nm respectively, and KCl has a CsCl-type structure, calculate its density ρ.", + "answer": "ρ = (Aₜ(K) + Aₜ(Cl)) / [(2(rₖ⁺ + rCl⁻) / √3)³ × Nₐ] = (39.102 + 35.453) / [(2 × (0.133 + 0.181) / √3)³ × 6.023 × 10²³ × 10⁻²⁴] = 2.597 g/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的离子半径和晶体结构类型，应用公式计算KCl的密度，答案是通过数值计算得出的具体数值结果 | 知识层次: 题目需要进行多步计算，包括离子半径的加和、晶格参数的计算、密度的公式应用等，涉及多个概念的综合运用和数值计算，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解离子半径、晶体结构类型（CsCl型）、密度计算公式等多个概念，并进行多步骤的综合计算。虽然题目提供了所有必要数据，但解题过程涉及单位换算（nm到cm）、立方根计算以及阿伏伽德罗常数的应用，对学生的综合计算能力和概念关联能力要求较高。" + }, + { + "idx": 2679, + "question": "MgO has a NaCl-type structure. The ionic radius of Mg2+ is 0.078nm, and the ionic radius of O2- is 0.132nm. Calculate the density (ρ) of MgO.", + "answer": "ρ = 4[Ar(Mg) + Ar(O)] / (2rMg + 2rO)^3 × NA = 4 × 24.31 + 4 × 16.00 / 8 × (0.78 + 1.32)^3 × 10^-24 × 6.023 × 10^23 = 3.613 g/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的离子半径和晶体结构信息，应用公式进行密度计算，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括晶体结构类型的识别、离子半径的应用、密度计算公式的正确运用以及单位换算等综合分析过程。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、离子半径、密度计算等多个概念，并进行多步计算和单位换算。虽然题目提供了公式和部分计算过程，但仍需要考生具备综合分析能力和对相关物理化学知识的掌握。" + }, + { + "idx": 2680, + "question": "A solid solution contains x(MgO) at 30% and x(LiF) at 70%. Calculate the mass fractions of Li1+, Mg2+, F1-, and O2-. The relative atomic masses of Mg, O, Li, and F are 24.31, 16.00, 6.94, and 19.00, respectively.", + "answer": "w(Li+) = (0.7 × 6.94) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 16%\\nw(Mg2+) = (0.3 × 24.31) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 24%\\nw(F-) = (0.7 × 19) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 44%\\nw(O2-) = (0.3 × 16) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 16%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，涉及质量分数的计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的摩尔分数转换为质量分数，并进行相应的数值计算。虽然涉及多个步骤，但每个步骤都是直接套用公式，没有复杂的综合分析或推理过程。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然涉及多个离子的质量分数计算，但每个计算步骤都是直接套用相同的质量分数公式，且各步骤之间相互独立，没有复杂的逻辑转换或组合。题目主要考察对基本质量分数公式的理解和简单应用能力，符合等级2的简单公式应用计算标准。" + }, + { + "idx": 2681, + "question": "MgO has a NaCl-type structure. The ionic radius of Mg2+ is 0.078nm, and the ionic radius of O2- is 0.132nm. Calculate the packing fraction (K) of MgO.", + "answer": "K = [4 × (4/3)πrMg^3 + 4 × (4/3)πrO^3] / (2rMg + 2rO)^3 = [16/3π × (0.78^3 + 1.32^3)] / [8 × (0.78 + 1.32)^3] = 0.627", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解离子半径和堆积分数的概念，并进行直接的数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用离子半径和堆积分数的基本公式，但解题步骤相对直接，仅需套用给定的公式并进行简单的数值计算。不需要复杂的推导或多步骤的公式组合，因此在选择题型内属于等级2难度。" + }, + { + "idx": 2682, + "question": "What is an interstitial solid solution? Explain its characteristics from the perspective of crystal structure.", + "answer": "An interstitial solid solution is formed when solute atoms are distributed in the interstitial sites of the solvent lattice. The solute atoms that form interstitial solid solutions are usually non-metallic elements with atomic radii smaller than 0.1nm, such as H, B, C, N, O, etc. The interstitial solid solution retains the crystal structure of the parent phase (solvent), and its composition can fluctuate within a certain solubility limit, but cannot be expressed by a molecular formula.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙固溶体的定义及其晶体结构特征，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对间隙固溶体这一基本概念的定义和特征的理解，属于基础概念记忆范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。题目要求解释间隙固溶体的定义及其晶体结构特征，涉及基础概念的记忆和理解。虽然需要掌握多个知识点（如间隙位置、溶质原子尺寸限制、晶体结构保留等），但都属于材料科学基础概念范畴，不需要复杂的分析或比较。在选择题型内，这属于需要概念解释和描述的难度等级，比简单定义题（等级1）稍复杂，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2683, + "question": "A solid solution contains x(MgO) at 30% and x(LiF) at 70%. If the density of MgO is 3.6 g/cm3 and the density of LiF is 2.6 g/cm3, what is the density of this solid solution?", + "answer": "The density of the solid solution ρ = 0.3 × 3.6 + 0.7 × 2.6 = 2.9 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解固溶体的密度，答案是一个具体的数值计算结果。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，仅需将给定的摩尔分数和密度数据进行加权平均即可得出结果，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（密度加权平均公式）进行计算，无需额外的概念理解或步骤组合。解题过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 2684, + "question": "What are interstitial compounds? Explain their characteristics from the perspective of crystal structure.", + "answer": "Interstitial compounds belong to intermediate phases dominated by atomic size factors. They are formed when non-metal elements with smaller atomic radii occupy the interstitial sites of the crystal lattice, yet the lattice of interstitial compounds differs from that of any of their constituent elements. Their composition can vary within a certain range. However, the constituent elements generally maintain a specific atomic ratio, which can be represented by a chemical formula. When rB/rA≥0.59, interstitial compounds form, exhibiting a complex crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙化合物的定义及其晶体结构特征，需要详细的文字解释和论述，而不是选择、判断或计算。答案提供了详细的描述和解释，符合简答题的特点。 | 知识层次: 题目主要考查间隙化合物的定义和基本特征，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但要求考生不仅知道间隙化合物的定义，还需要理解其晶体结构特点和形成条件。正确选项包含了多个关键知识点（如原子半径比、晶格变化、成分可变性等），需要考生对这些概念有一定的理解和整合能力，而不仅仅是简单的定义记忆。因此，在选择题型内属于概念解释和描述的难度等级。" + }, + { + "idx": 2685, + "question": "Given the ionic radii of K⁺ and Cl⁻ are 0.133nm and 0.181nm respectively, and KCl has a CsCl-type structure, calculate its packing fraction κ.", + "answer": "κ = [(4/3)πrₖ⁺³ + (4/3)πrCl⁻³] / [2(rₖ⁺ + rCl⁻) / √3]³ = [(4/3)π(0.133³ + 0.181³)] / [2(0.133 + 0.181) / √3]³ = 0.728", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的离子半径和晶体结构类型，应用公式进行计算，最终得出堆积分数κ的数值结果。答案展示了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括离子半径的立方和、配位数的考虑、晶格参数的计算等），并需要理解CsCl型结构的特点和堆积因子的概念。虽然不涉及复杂的推理分析或创新设计，但需要综合应用多个知识点进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解离子半径、晶体结构类型（CsCl型）、堆积分数计算等多个概念，并进行多步骤的综合计算。虽然题目提供了具体数值，但计算过程涉及立方根和分数运算，对学生的计算能力和概念关联能力有一定要求。" + }, + { + "idx": 2686, + "question": "In a ZrO2 solid solution, for every 6 Zr4+ ions, 1 Ce3+ ion is added to form a cubic lattice of ZrO2. If these cations form an fcc structure and the O2- ions occupy the tetrahedral interstitial sites, calculate how many O2- ions are needed for 100 cations.", + "answer": "The total charge of 100 cations = (100/7) × (6×4 + 1×2) = 371.4, so 371.4/2 = 185.7 O2- ions are required to balance this charge.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算O2-离子的数量），并应用了电荷平衡的公式，最终给出了具体的计算结果。 | 知识层次: 题目需要进行多步计算，包括电荷平衡的计算和比例关系的应用，涉及对固溶体结构和离子电荷的理解，需要综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如固溶体、电荷平衡、晶格结构）并进行多步计算。题目要求考生能够综合应用化学计量和晶体结构知识，通过比例关系和电荷平衡原理推导出正确答案。虽然计算过程相对直接，但涉及的概念关联和综合分析能力使其高于基础选择题难度。" + }, + { + "idx": 2687, + "question": "What is glass?", + "answer": "The so-called glass refers to an amorphous solid that has a glass transition temperature. The difference between glass and other amorphous states lies in the presence or absence of a glass transition temperature. The glassy state also refers to amorphous metals and alloys (amorphous metal), which are essentially supercooled liquid metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"glass\"进行定义和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对玻璃这一基本概念的定义和特性的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项对玻璃的定义进行了较为详细的解释，包括玻璃过渡温度的概念以及与其他非晶态的区别。这要求考生不仅记住基本定义，还需要理解相关概念的描述和区分，属于\"概念解释和描述\"层次。相比简单定义记忆题(等级1)需要更深一层的理解，但尚未达到需要分析复杂概念体系的难度(等级3)。" + }, + { + "idx": 2688, + "question": "In the ZrO2 solid solution, cations form an fcc structure, and O2- ions are located at tetrahedral interstitial sites. Given that 100 cations form 25 unit cells, and each unit cell has a total of 8 tetrahedral interstitial sites, calculate the percentage of tetrahedral interstitial sites occupied by O2- ions.", + "answer": "Since the fcc structure contains 4 atoms per unit cell, 100 cations form 25 unit cells. Each unit cell has a total of 8 tetrahedral interstitial sites, so the percentage of tetrahedral interstitial sites occupied by O2- ions is 185.7/(25×8)=92.9%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算单位细胞数量、间隙位置数量以及最终的百分比计算。答案也是通过具体的数值计算得出的。 | 知识层次: 题目涉及多步计算和概念关联，需要理解fcc结构、单位细胞数量与间隙位点的关系，并进行综合分析计算。虽然不涉及复杂的推理分析或机理解释，但需要一定的思维深度和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解fcc结构、单位细胞计算、间隙位置等概念，并进行多步计算和综合分析。题目涉及多个知识点的关联应用，解题步骤较为复杂，但选项提供了部分计算过程，降低了部分难度。" + }, + { + "idx": 2689, + "question": "Given that the number-average relative molecular weight of linear polytetrafluoroethylene is 5×10^5, its C-C bond length is 0.154 nm, and the bond angle θ is 109°, calculate its root-mean-square length.", + "answer": "The root-mean-square length r=d√N=0.154×√(1.0×10^4)=15.4 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（分子量、键长、键角）应用公式计算均方根长度，答案呈现为具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解根均方长度的概念、应用相关公式（r=d√N）以及进行数值计算。虽然不涉及复杂的综合分析或推理，但需要将多个概念（如键长、键角和分子量）关联起来进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解高分子链的均方根末端距计算公式（r=d√N），并正确关联题目给出的参数（键长d=0.154 nm、聚合度N=5×10^5/100=5×10^3）。虽然计算步骤明确（先求聚合度再开方计算），但需要综合应用高分子物理知识和三角函数计算（109°键角隐含的投影关系），且涉及数量级转换（将5×10^5分子量转换为聚合度）。相比简单概念选择题（等级1）或单步计算题（等级2），该题需要更系统的知识整合能力。" + }, + { + "idx": 2690, + "question": "Polypropylene is polymerized from propylene, with the chemical formula C3H6. Crystalline polypropylene belongs to the monoclinic crystal system, with lattice constants α = 0.665 nm, b = 2.096 nm, c = 0.65 nm, α = γ = 90°, β = 99.3°, and a density ρ = 0.91 g/cm³. Calculate the number of C and H atoms in the unit cell of crystalline polypropylene.", + "answer": "Assuming there are x C atoms in the polypropylene unit cell, then there are 2x H atoms. The volume of the unit cell is $$ V = a b c \\\\sin \\\\beta $$ $$ \\\\rho = \\\\frac{x \\\\cdot 12.011 + 2x \\\\cdot 1.008}{(6.65 \\\\times 10^{-8})(20.96 \\\\times 10^{-8})(6.5 \\\\times 10^{-8}) \\\\sin 99.3 \\\\times 6.023 \\\\times 10^{23}} = 0.91 $$ $$ x = \\\\frac{0.91 \\\\times 6.65 \\\\times 2.096 \\\\times 6.5 \\\\times \\\\sin 99.3 \\\\times 6.023}{12.011 + 2 \\\\times 1.008} = 34.936 \\\\approx 35 $$ $$ 2x = 2 \\\\times 35 = 70 $$ Therefore, the C3H6 unit cell contains 35 C atoms and 70 H atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞中的碳和氢原子数量，答案展示了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括单位晶胞体积的计算、密度的计算以及原子数量的推导，涉及晶体学参数和化学计量关系的综合分析。虽然不涉及复杂的机理分析或创新设计，但需要较高的计算能力和对晶体结构参数的理解。 | 难度: 在选择题中属于高难度，需要综合运用晶体学、化学计量学和密度计算等多个概念，进行多步骤的复杂计算，包括单位晶胞体积计算、原子质量求和、阿伏伽德罗常数应用等，最终还需要正确解方程并四舍五入得到整数解。这种综合性计算问题在选择题型中属于最复杂的类型之一。" + }, + { + "idx": 2691, + "question": "The ionic radii of $\\\\mathrm{Al}^{3+}$ and $\\\\mathrm{O}^{2-}$ are $0.051\\\\mathrm{nm}$ and $0.132\\\\mathrm{nm}$ respectively. Determine the coordination number of $\\\\mathbf{Al}_{2}\\\\mathbf{O}_{3}$.", + "answer": "The ratio of the two ionic radii is $\\\\frac{0.051}{0.132}{=}0.386$. The coordination number (CN) of an ionic crystal depends on the ratio of the cation to anion radii. Referring to the table, when $\\\\frac{r_{+}}{r_{-}}$ is between $0.225\\\\sim0.414$, the CN is 4. The shape of the anion polyhedron is tetrahedral.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算离子半径比并参考表格数据来确定配位数，答案需要文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目主要涉及离子半径比的计算和查表确定配位数，属于基本公式应用和直接套用已有知识，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用层次。题目要求考生根据给定的离子半径比值直接查表确定配位数，涉及的知识点较为基础，解题步骤简单直接，仅需进行简单的计算和查表操作。不需要复杂的推理或多步骤分析，因此难度较低。" + }, + { + "idx": 2692, + "question": "Diamond is a crystalline form of carbon with a lattice constant α = 0.357 nm. When it transforms into the graphite (ρ = 2.25 g/cm³) structure, calculate the change in volume.", + "answer": "The crystal structure of diamond is a complex face-centered cubic structure, with each unit cell containing a total of 8 carbon atoms. The density of diamond is $$ ρ = (8 × 12) / ((0.357 × 10⁻⁷)³ × 6.023 × 10²³) = 3.503 (g/cm³) $$. For 1 g of carbon, when it is in the diamond structure, its volume is $$ V₁ = 1 / 3.503 = 0.285 (cm³) $$. When it is in the graphite structure, its volume is $$ V₂ = 1 / 2.25 = 0.444 (cm³) $$. Therefore, the volume expansion when transforming from diamond to graphite is = (V₂ - V₁) / V₁ = (0.444 - 0.285) / 0.285 ≈ 55.8%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解体积变化，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶体结构分析、密度计算、体积转换和百分比变化计算。虽然不涉及复杂的推理或综合分析，但需要理解和应用多个概念，并进行关联计算。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算和体积变化的概念，并进行多步计算和综合分析。虽然题目提供了具体数值和公式，但解题过程涉及多个步骤和概念关联，对学生的计算能力和理解深度有一定要求。" + }, + { + "idx": 2693, + "question": "Given that the number-average relative molecular weight of linear polytetrafluoroethylene is 5×10^5, the C-C bond length is 0.154 nm, and the bond angle θ is 109°, calculate its total chain length L.", + "answer": "For a linear polymer, the total chain length L depends on the bond length d between atoms, the number of bonds N, and the angle θ between adjacent bonds, i.e., L=Ndsin(θ/2). For polytetrafluoroethylene, each chain unit has 2 C atoms and 4 F atoms. First, calculate its degree of polymerization πn=M/m=5×10^5/(2×12.01+4×19.00)=5×10^3. Each chain unit has 2 C atoms, so each chain unit has two C-C main bonds. Therefore, the total number of bonds in this polymer is N=2πn=2×5×10^3=1.0×10^4. If each C-C bond length d=0.154 nm and bond angle θ=109°, then L=Ndsin(θ/2)=1.0×10^4×0.154×sin(109°/2)=1253.738 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚合物的总链长，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，包括计算聚合度、键的数量，并应用公式计算链的总长度。虽然涉及的概念和公式相对明确，但需要综合运用多个知识点并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如聚合度、键长、键角等）并进行多步计算（包括聚合度计算、键数计算和最终链长计算）。虽然题目提供了公式和具体数值，但解题过程涉及多个步骤和概念的综合应用，对学生的计算能力和概念理解有一定要求。" + }, + { + "idx": 2694, + "question": "What are the main differences between amorphous and crystalline substances in terms of internal atomic arrangement and properties?", + "answer": "From the perspective of internal atomic arrangement, the fundamental characteristic of a crystalline structure is that atoms are arranged periodically in three-dimensional space, exhibiting long-range order, whereas the atomic arrangement in amorphous materials lacks long-range order. In terms of properties, crystals have fixed melting points and anisotropy, while amorphous materials do not have fixed melting points and are isotropic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释非晶态和晶态物质在内部原子排列和性质上的主要差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对非晶态和晶态物质内部原子排列和性质差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目要求考生理解和比较两种材料（非晶态和晶态）的内部原子排列和性质差异。虽然涉及多个概念（长程有序、各向异性等），但题目提供了明确的对比框架，且正确选项直接总结了这些差异，不需要复杂的推理或分析步骤。因此，在选择题型内属于中等难度（等级2），主要考察概念解释和描述能力。" + }, + { + "idx": 2695, + "question": "Calculate the theoretical density of α-Fe (given a=0.286nm for α-Fe, Ar(Fe)=55.85, NA=6.023×10²³)", + "answer": "ρtheoretical=2×Ar(Fe)/(a³×NA)=2×55.85/((2.86×10⁻⁸)³×6.023×10²³)=7.9276(g/cm³)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（晶格常数a、原子量Ar、阿伏伽德罗常数NA）和公式（理论密度计算公式）进行数值计算，最终得出具体的密度值7.9276g/cm³，符合计算题的特征。 | 知识层次: 题目要求应用基本公式进行简单计算，涉及晶体结构参数和密度的直接套用，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用密度计算公式，但步骤较为直接，仅涉及单一公式的代入和简单数值计算，无需复杂的推导或多步骤分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2696, + "question": "Calculate the packing density of the diamond structure.", + "answer": "Diamond is the most typical covalent crystal, entirely bonded by covalent bonds. Its crystal structure belongs to a complex fcc structure, where each C atom (d=0.1544 nm) has 4 equidistant nearest neighbors, conforming to the 8-N rule. The distance between the nearest neighbors is equivalent to the bond length. Based on the crystal structure of diamond, it can be determined that: Therefore, $$ a={\\frac{4\\times0.1544}{\\sqrt{3}}}=0.3566({\\mathrm{nm}})$$ $$ {\\cal K}=\\frac{8\\times\\frac43\\pi r^{3}}{a^{3}}=\\frac{8\\times\\frac43\\pi\\left(\\frac{0.1544}{2}\\right)^{3}}{(0.3566)^{3}}=0.34$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要理解金刚石结构的晶体学特征，应用几何关系进行多步计算，包括晶格常数推导和堆积密度公式应用，涉及概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解金刚石晶体结构的基本概念（如fcc结构、8-N规则、共价键特性），并能够进行多步骤计算（包括键长与晶格常数的转换、堆积密度公式的应用）。虽然题目提供了部分计算过程，但考生仍需掌握相关晶体学知识和数学推导能力才能正确理解和验证计算结果。" + }, + { + "idx": 2697, + "question": "Calculate the theoretical packing density of α-Fe (given rFe=0.1241nm, a=0.286nm)", + "answer": "Ktheoretical=8/3×π×rFe³/a³=8/3×π×(0.1241)³/(0.286)³=0.6844", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目要求应用基本公式进行数值计算，属于直接套用公式的简单应用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算α-Fe的理论堆积密度，只需套用给定的公式和参数进行简单计算即可得出结果。不需要理解多个概念或进行复杂的分析，解题步骤直接且明确。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2698, + "question": "If in fcc Cu, 1 out of every 500 atoms is missing, and its lattice constant is 0.3615 nm, calculate the density of Cu.", + "answer": "$$ \\\\rho{=}\\\\frac{4\\\\times\\\\left(1-\\\\frac{1}{500}\\\\right)63.54}{(3.615\\\\times10^{-8})^{3}\\\\times6.023\\\\times10^{23}}{=}8.915({\\\\mathrm{g/cm}}^{3})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜的密度，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括考虑缺陷浓度对原子数量的影响、晶格常数的转换、以及密度的计算公式应用。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和计算步骤，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方结构、缺陷浓度、密度计算等多个概念，并进行多步计算和综合分析。虽然题目提供了公式，但需要正确代入数值并处理单位转换，涉及一定的计算复杂度。" + }, + { + "idx": 2699, + "question": "There is a glass containing soda, with a mass fraction of SiO2 at 80% and Na2O at 20%. Calculate the fraction of non-bridging O atoms.", + "answer": "According to the problem, assume there is 100g of glass, containing 80g of SiO2 and 20g of Na2O. First, calculate their molar fractions: The amount of SiO2 is 80/(28.09+2×16.00)=1.331(mol) ⇒ x_SiO2=80.47%. The amount of Na2O is 20/(2×22.99+16.00)=0.323(mol) ⇒ x_Na2O=19.53%. Now, using 100mol as the basis, then: 80.47SiO2 = 80.47Si + 160.94O 19.53Na2O = 39.06Na + 19.53O Since each Na+ produces one non-bridging oxygen ion, there are 39.06 non-bridging oxygen atoms, while the bridging oxygen atoms are: (160.94 + 19.53) - 39.06 = 141.41 The fraction of non-bridging oxygen atoms is then: 39.06/180.47 = 0.216", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非桥氧原子的比例，解答过程中涉及摩尔分数计算和化学计量关系，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括摩尔分数的计算、非桥氧和桥氧原子的数量计算，以及最终的比例计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用化学计量和玻璃结构的基本知识，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃结构中的非桥氧和桥氧概念，并进行多步计算。题目涉及摩尔分数计算、原子平衡以及非桥氧比例的推导，步骤较为复杂，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 2700, + "question": "Given the vibration frequency of atoms around a vacancy in Cu as 1×10¹³ s⁻¹, ΔEv as 0.15×10⁻¹⁸ J, and exp(ΔSm/k) approximately 1, calculate the migration frequency of vacancies at room temperature 27°C (300K).", + "answer": "ν=ν₀zexp(−ΔEv/kT)exp(ΔSm/k), ν₃₀₀=1×10¹³×12×exp(−0.15×10⁻¹⁸/(1.38×10⁻²³×300))×1=2.207×10⁻² s⁻¹", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，给出了具体的物理参数和计算公式，最终需要计算出迁移频率的数值结果。答案也是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用公式进行多步计算，涉及振动频率、迁移能、熵变等多个概念的关联，并需要正确代入数值进行计算，思维过程有一定深度要求。 | 难度: 在选择题中属于中等偏上难度，需要理解振动频率、迁移能、熵变等多个概念，并正确应用Arrhenius方程进行多步骤计算。题目涉及单位换算（温度转换）、指数运算和常数代入，计算过程较为复杂，但选项提供了完整的解题路径，降低了部分难度。" + }, + { + "idx": 2701, + "question": "Given that the vibration frequency of atoms around a vacancy in Cu is 1×10¹³ s⁻¹, ΔEv is 0.15×10⁻¹⁸ J, and exp(ΔSm/k) is approximately 1, calculate the migration frequency of vacancies at 700K.", + "answer": "ν=ν₀zexp(−ΔEv/kT)exp(ΔSm/k), ν₇₀₀=1×10¹³×12×exp(−0.15×10⁻¹⁸/(1.38×10⁻²³×700))×1=2.165×10⁷ s⁻¹", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算并应用给定的公式来求解迁移频率，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目直接给出了所需的公式和参数，仅需进行简单的代入和计算即可得出答案。虽然涉及指数运算，但整体步骤清晰且直接，无需复杂的推导或多步骤分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2702, + "question": "Calculate the actual packing density of α-Fe (given that for every 200 iron atoms there is 1 H atom, rFe=0.1241nm, rH=0.036nm, a=0.286nm)", + "answer": "K actual=8/3×π×(rFe³+rH³/200)/a³=8/3×π×((0.1241)³+(0.036)³/200)/(0.286)³=0.6845", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目需要进行多步计算，包括原子半径的立方计算、比例换算以及最终的体积分数计算，涉及多个概念的综合应用和公式的灵活运用，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、原子半径、堆积密度等多个概念，并进行多步计算。题目要求考生不仅掌握基本公式，还需要正确代入多个变量（铁原子半径、氢原子半径、晶格常数等），并进行综合运算。虽然题目提供了所有必要参数，但计算步骤较多且需要精确处理小量（氢原子占比1/200），在选择题型中属于需要较高计算精度和概念整合能力的题目。" + }, + { + "idx": 2703, + "question": "Calculate the actual density of α-Fe (given that for every 200 iron atoms there is 1 H atom, Ar(H)=1.008, a=0.286nm, NA=6.023×10²³)", + "answer": "ρ_actual=2×(Ar(Fe)+1/200×Ar(H))/(a³×NA)=2×(55.85+1.008/200)/((2.86×10⁻⁸)³×6.023×10²³)=7.9283(g/cm³)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及原子量、晶格常数和密度计算，答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解晶体结构、原子质量、单位换算等知识，并进行综合分析。虽然计算过程较为直接，但需要将多个知识点结合起来，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体密度计算的基本概念（如晶格常数、原子量、阿伏伽德罗常数等），并能够正确应用公式进行多步骤计算。题目中涉及掺杂原子的修正计算（1/200氢原子），增加了问题的综合性。虽然计算过程较为复杂，但在选择题型中通过选项可以验证计算结果，降低了部分难度。" + }, + { + "idx": 2704, + "question": "To dissolve MgF2 into LiF, what type of vacancies (anion or cation) need to be introduced into LiF?", + "answer": "To dissolve MgF2 into LiF by replacing Mg2+ with Li+, anion vacancies must be introduced to balance the charge and maintain the original MgF2 structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么需要引入特定的空位来溶解MgF2到LiF中，答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要理解溶解过程中的电荷平衡原理，并分析引入何种空位来维持结构稳定性，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及溶解过程中的电荷平衡和空位引入的概念，需要考生综合理解MgF2和LiF的结构差异以及电荷补偿机制。虽然不需要复杂的计算，但需要对材料科学中的缺陷化学有较好的理解，并能将不同概念关联起来进行分析。" + }, + { + "idx": 2705, + "question": "In a diffusion experiment of a certain crystal, it was found that at 500°C, 1 in 10^10 atoms had sufficient activation energy to jump out of their equilibrium positions and enter interstitial positions; at 600°C, this ratio increased to 10^9. Calculate the activation energy required for this jump.", + "answer": "The thermal activation process can generally be described by the famous Arrhenius equation. Let E be the energy required to form an interstitial atom, so the ratio of the number of atoms n with energy exceeding the average energy to the total number of atoms N is C = n/N = A e^(-E/kT), where A is the proportionality constant, k is the Boltzmann constant, and T is the absolute temperature. Taking the logarithm of both sides, we have ln C = ln A - E/kT. Solving the simultaneous equations gives ln 10^(-10) = ln A - E/(1.38×10^(-23)×773) and ln 10^(-9) = ln A - E/(1.38×10^(-23)×873). Thus, ln A = -2.92, E = 2.14×10^(-19) (J).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来求解激活能，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及对数运算和联立方程的求解，同时需要理解热激活过程的基本原理。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解阿伦尼乌斯方程的概念，进行对数运算，并解联立方程。虽然计算步骤较多，但在选择题型中可以通过选项验证简化部分过程。" + }, + { + "idx": 2706, + "question": "The density of $\\\\mathbf{M}_{\\\\mathbf{g}}\\\\mathbf{O}$ is $3.58\\\\:\\\\mathbf{g}/\\\\mathrm{cm}^{3}$, and its lattice constant is $0.42\\\\mathfrak{n m}$. Determine the number of Schottky defects per unit cell of $\\\\mathbf{M}_{\\\\mathbf{g}}\\\\mathrm{O}$.", + "answer": "Let the number of Schottky defects per unit cell be x. $$ \\\\rho{=}\\\\frac{(4-x)\\\\times\\\\left[A_{\\\\mathrm{r}}(\\\\mathrm{M}g)+A_{\\\\mathrm{r}}(\\\\mathrm{O})\\\\right]}{a^{3}N_{\\\\mathrm{A}}}$$ $$ x=4-{\\\\frac{\\\\rho\\\\alpha^{3}N_{\\\\mathrm{{A}}}}{A_{\\\\mathrm{{r}}}(\\\\mathrm{Mg})+A_{\\\\mathrm{{r}}}(\\\\mathrm{O})}}=4-{\\\\frac{3.58\\\\times(4.2\\\\times10^{-8})^{3}\\\\times6.023\\\\times10^{23}}{24.31+16.00}}=0.0369$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞中的肖特基缺陷数量，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换、原子量的使用以及最终求解缺陷数量。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和计算步骤，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷的概念，掌握密度计算公式，并能正确代入数据进行多步计算。题目涉及单位转换、摩尔质量应用和综合公式推导，但选项提供了明确的解题路径，减少了部分思考难度。" + }, + { + "idx": 2707, + "question": "If LiF is dissolved in MgF2, what type of vacancies (anion or cation) must be introduced into MgF2?", + "answer": "To dissolve LiF into MgF2, where Mg2+ replaces Li+, cation vacancies must be introduced because the valence charges of the replaced ion and the newly added ion must be equal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么在溶解LiF到MgF2时需要引入特定类型的空位，答案提供了详细的文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解溶解过程中的离子替换机制，并分析价态平衡对空位形成的影响。这涉及多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解离子替换的概念，并分析价态平衡的要求。虽然不需要复杂的计算，但需要综合理解晶体缺陷和电荷平衡的概念。" + }, + { + "idx": 2708, + "question": "At 700°C, what is the proportion of atoms with sufficient energy?", + "answer": "According to the Arrhenius equation, ln C = ln A - E/kT. Given ln A = -2.92, E = 2.14×10^(-19) J, k = 1.38×10^(-23) J/K, and T = 973 K. Substituting these values yields ln C = -2.92 - (2.14×10^(-19))/(1.38×10^(-23)×973). The calculation gives C = n/N = 6×10^(-9).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来求解特定温度下具有足够能量的原子比例，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及对数运算和指数转换，需要理解方程中各参数的含义及其相互关系，并进行综合计算。虽然不涉及复杂的推理分析或创新应用，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解阿伦尼乌斯方程并正确代入多个变量进行计算。题目涉及多步骤计算过程，包括对数运算和指数转换，同时需要综合理解能量、温度和比例之间的关系。虽然题目提供了所有必要参数，但计算过程较为复杂，需要较高的注意力以避免错误。" + }, + { + "idx": 2709, + "question": "Given that Al has an fcc crystal structure with a lattice constant α=0.405 nm, and the vacancy concentration at 550°C is 2×10-6, calculate the average spacing between these vacancies if they are uniformly distributed in the crystal.", + "answer": "The number of lattice points in $1~\\\\mu\\\\mathrm m^{3}$ volume of Al is $$ N={\\\\frac{1}{a^{3}}}\\\\times4\\\\Rightarrow{\\\\frac{1}{(0.405\\\\times10^{-6})^{3}}}=6.021\\\\times10^{10}$$ Therefore, the number of vacancies in $1~\\\\mu\\\\mathrm m^{3}$ volume is $$ n_{V}=\\\\mathrm{CN}=6.021\\\\times10^{10}\\\\times2\\\\times10^{-6}=1.204\\\\times10^{5}$$ Assuming the vacancies are uniformly distributed in the crystal, the average spacing between them is $$ L=\\\\sqrt[3]{\\\\frac{1}{n_{v}}}=\\\\sqrt[3]{\\\\frac{1}{1.204\\\\times10^{5}}}=0.02025(\\\\mu\\\\mathrm{m})=20.25\\\\mathrm{nm}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺的平均间距，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算晶格点的数量、空位浓度，并进一步推导空位之间的平均间距。虽然不涉及复杂的机理分析或创新应用，但需要综合运用晶体结构和缺陷的知识进行中等难度的计算。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、空位浓度、均匀分布等概念，并进行多步计算（包括晶格点计算、空位数量计算和平均间距计算）。虽然题目提供了正确选项，但解题过程涉及多个物理概念的关联和综合应用，对学生的计算能力和概念理解要求较高。" + }, + { + "idx": 2710, + "question": "Given that W at 20℃ has one vacancy per 10^23 unit cells, and each unit cell contains 2 W atoms, calculate the vacancy concentration C at 20℃.", + "answer": "C_20 = 1 / (2 × 10^23) = 5 × 10^-24.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和单位转换，最终给出一个数值结果。 | 知识层次: 题目仅涉及基本公式应用和简单计算，直接套用给定的数值进行计算即可，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（空缺浓度计算）并进行简单的数值计算。解题步骤非常直接，没有涉及多个公式的组合或复杂的概念分析，因此属于单一公式直接计算的难度等级1。" + }, + { + "idx": 2711, + "question": "The activation energy required to form a vacancy in a certain crystal is 0.32×10^-18 J. At 800°C, there is one vacancy per 1×10^4 atoms. At what temperature will there be one vacancy per 10^3 atoms?", + "answer": "According to the Arrhenius equation: $$ \\\\ln{\\\\frac{n}{N}}=\\\\ln A-{\\\\frac{E}{{k}\\\\ T}}$$ Substituting the known conditions into the equation: $$ \\\\ln10^{-4}=\\\\ln A-\\\\frac{0.32\\\\times10^{-18}}{1.38\\\\times10^{-23}\\\\times1073}$$ We obtain: $$ \\\\ln A=12.4$$ And: $$ {\\\\bf{In}}10^{-3}=12.4-\\\\frac{0.32\\\\times10^{-18}}{1.38\\\\times10^{-23}\\\\times\\\\mathit{T}}.$$ Therefore: $$ \\\\operatorname{T}=1201\\\\operatorname{K}=928^{\\\\circ}{\\\\mathbb{C}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来求解温度，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解并运用阿伦尼乌斯方程进行温度与空位浓度的关系计算，同时需要将不同条件下的数据进行关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解并应用阿伦尼乌斯方程进行多步计算，涉及对数运算和温度转换，同时需要综合分析不同条件下的变量关系。虽然题目提供了正确选项，但解题过程需要较强的概念关联和计算能力。" + }, + { + "idx": 2712, + "question": "When the temperature increases from 20℃ to 1020℃, the lattice constant expands by (4 × 10^-4)%, and the density decreases by 0.012%. Assuming the total mass remains unchanged, calculate the total volume change rate ΔV/V.", + "answer": "(1 + ΔV/V) × (1 - 0.00012) = 1 → ΔV/V ≈ 0.012%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的条件计算体积变化率，答案也是通过计算得出的具体数值。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解密度和体积之间的关系，并进行直接套用公式计算体积变化率。虽然涉及温度变化和晶格常数，但计算过程相对直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目涉及了热膨胀和密度变化的概念，但解题过程仅需要直接套用给定的百分比变化关系（密度减少0.012%对应体积增加0.012%），并通过简单的代数运算得出结果。不需要复杂的推导或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 2713, + "question": "For a cubic crystal with side length L, derive the volume change rate ΔV0/V0 due to thermal expansion when the temperature increases from T1 to T2.", + "answer": "ΔV0/V0 = (L + ΔL)^3 - L^3 / L^3 = 3 × (ΔL/L).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式推导和数值计算来求解体积变化率，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目要求应用基本的体积变化公式和热膨胀概念进行简单计算，涉及直接套用公式和一步推导，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解热膨胀的基本概念和立方体体积公式，但解题步骤仅涉及直接套用体积变化率公式（ΔV0/V0 = 3 × (ΔL/L)），无需多步推导或复杂计算。相比单一公式直接计算的等级1题目，该题需要稍高的理解能力，但仍属于选择题中的基础难度范畴。" + }, + { + "idx": 2714, + "question": "The vacancy formation energy (E_v) and interstitial atom formation energy (E_i) of Al are 0.76 eV and 3.0 eV, respectively. Calculate the ratio of the equilibrium concentration of vacancies to the equilibrium concentration of interstitial atoms in Al at 500°C.", + "answer": "At 500°C: C_V/C_i = e^((1/(8.617×10^-5×773))(3.0-0.76)) = e^33.63 = 4.026×10^14", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及能量和浓度的计算，答案也是通过具体计算得出的数值结果。 | 知识层次: 题目需要应用缺陷形成能的基本概念，进行多步计算（包括温度转换、玻尔兹曼因子计算和指数运算），并理解平衡浓度与形成能之间的关系。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行计算和结果解释。 | 难度: 在选择题中属于中等偏上难度，需要理解空位形成能和间隙原子形成能的概念，掌握平衡浓度计算公式，并能正确进行多步指数运算。题目涉及温度单位转换（°C转K）、玻尔兹曼常数应用以及综合计算能力，但选项提供了明确的解题路径，减少了部分分析难度。" + }, + { + "idx": 2715, + "question": "Solve the equations to find the vacancy formation energy Ev and entropy Sv.", + "answer": "Ev = 1.45 eV, Sv = 3.3 × 10^-4 eV.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过解方程来计算空位形成能Ev和熵Sv，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解空缺形成能和熵的概念，并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解空缺形成能和熵的概念，并进行多步骤计算和综合分析。虽然题目提供了正确选项，但解题过程涉及多个物理概念的关联和计算步骤的整合，对学生的知识掌握和计算能力有一定要求。" + }, + { + "idx": 2716, + "question": "Assuming the vacancy concentration at T1 is negligible compared to T2, calculate the equilibrium vacancy concentration Cv at 1020℃.", + "answer": "Cv = ΔV0/V0 - ΔVa/Va = 3 × (ΔL/L - Δa/a) = (0.012% - 3 × 4 × 10^-4%) = 1 × 10^-4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如空位浓度与温度的关系），需要综合分析题目给出的条件（T1和T2的温度差异）并正确应用公式进行计算。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步计算和概念关联，需要综合理解空位浓度与温度的关系，并正确应用公式进行计算。虽然题目提供了正确选项，但解题过程需要理解多个物理量的含义及其相互关系，并进行精确的计算步骤。" + }, + { + "idx": 2717, + "question": "Using the vacancy concentrations at 20℃ and 1020℃, set up the equations to solve for the vacancy formation energy Ev and entropy Sv.", + "answer": "5 × 10^-24 = exp(Sv/k) × exp[-Ev/(293k)], 1 × 10^-4 = exp(Sv/k) × exp[-Ev/(1293k)].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的方程和条件进行数值计算和公式应用，以求解空缺形成能Ev和熵Sv。答案给出了具体的方程形式，需要进一步的数学运算来解出未知数。 | 知识层次: 题目需要建立并求解两个方程来计算空位形成能和熵，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解空缺浓度与温度的关系，掌握指数方程的对数变换技巧，并能建立联立方程求解两个未知数（Ev和Sv）。虽然题目给出了正确选项，但需要考生具备将物理概念转化为数学表达的能力，并理解熵和能量的温度依赖性。这超出了简单的概念回忆或单步计算，属于需要多步推导和概念关联的综合问题。" + }, + { + "idx": 2718, + "question": "When the temperature decreases from 600°C to 300°C, the equilibrium vacancy concentration in $\\mathtt{Ge}$ crystal decreases by 6 orders of magnitude. Calculate the vacancy formation energy in the Ge crystal.", + "answer": "$$ \\\\begin{array}{r l}&{\\\\frac{C_{\\\\tau_{1}}}{C_{\\\\tau_{2}}}=\\\\frac{1}{10^{6}}=\\\\frac{A\\\\exp\\\\left(-\\\\frac{E_{\\\\mathrm{v}}}{k T_{1}}\\\\right)}{A\\\\exp\\\\left(-\\\\frac{E_{\\\\mathrm{v}}}{k T_{2}}\\\\right)}=\\\\mathrm{e}^{\\\\frac{\\\\varepsilon_{\\\\mathrm{v}}}{k}\\\\left(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\right)}-\\\\ln10^{6}}\\\\ &{\\\\qquad=\\\\frac{E_{\\\\mathrm{v}}}{\\\\frac{1}{k}\\\\left(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\right)}}\\\\ &{E_{\\\\mathrm{v}}=\\\\frac{-\\\\ln10^{6}}{\\\\frac{1}{873}-\\\\frac{1}{573}}=\\\\frac{-13,8\\\\times8,617\\\\times10^{-5}}{1.145\\\\times10^{-3}-1.745\\\\times10^{-3}}=1.98\\\\mathrm{(eV)}}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺形成能，答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解平衡空位浓度与温度的关系，并能够正确应用自然对数和指数函数进行推导。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，包括平衡空位浓度与温度的关系、能量计算等。虽然题目提供了正确的计算步骤，但在选择题型中，学生需要理解并验证这些步骤的正确性，这需要一定的综合分析能力。" + }, + { + "idx": 2719, + "question": "Derive the volume change rate ΔVa/Va due to lattice constant expansion when the temperature increases from T1 to T2.", + "answer": "ΔVa/Va = (a + Δa)^3 - a^3 / a^3 = 3 × (Δa/a).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式推导和数值计算来求解体积变化率，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目要求应用基本公式进行简单的体积变化率计算，涉及基本的代数运算和热膨胀概念的直接应用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解体积变化率的概念，但解题步骤相对直接，仅需应用基本的体积变化公式并进行简单的代数运算。不需要多个公式的组合或复杂的分析过程，因此属于等级2难度。" + }, + { + "idx": 2720, + "question": "If the positive direction of a dislocation line is defined as the original opposite direction, will the Burgers vector of this dislocation change?", + "answer": "According to the method of determining the Burgers vector of a dislocation by the Burgers circuit, the Burgers vector of this dislocation will reverse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的解释和依据，而不是简单的选择或判断。 | 知识层次: 题目考查对位错Burgers矢量定义和Burgers回路方法的基本理解，属于基础概念的记忆和应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（Burgers vector的定义和确定方法），但需要考生理解并应用Burgers circuit的原理来判断Burgers vector是否会反转。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较多个概念（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 2721, + "question": "If the positive direction of a dislocation line is defined as the original opposite direction, does the type and nature of the dislocation change?", + "answer": "The type and nature of this dislocation do not change.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（dislocation的类型和性质是否改变），答案直接给出了对错判断（不改变） | 知识层次: 题目考查对位错线方向和位错类型及性质的基本概念的理解，属于基础概念记忆范畴。 | 难度: 该题目属于基本概念正误判断，仅需记忆和理解位错线方向定义对位错类型和性质的影响即可作答，无需复杂分析或推理过程。在选择题型中属于最基础的难度等级。" + }, + { + "idx": 2722, + "question": "The vacancy formation energy (E_v) and interstitial atom formation energy (E_i) of Al are 0.76 eV and 3.0 eV, respectively. Calculate the ratio of the equilibrium concentration of vacancies to the equilibrium concentration of interstitial atoms in Al at room temperature (20℃).", + "answer": "At 20℃: C_V/C_i = e^((1/(8.617×10^-5×293))(3.0-0.76)) = e^88.72 = 3.395×10^38", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及能量和温度的计算，最终需要得出一个具体的数值结果。答案的形式也是通过计算得出的数值，符合计算题的特征。 | 知识层次: 题目需要应用缺陷形成能的基本概念，进行多步计算（包括温度转换、玻尔兹曼因子计算和指数运算），并理解平衡浓度与形成能之间的关系。虽然不涉及复杂的综合分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及空位形成能和间隙原子形成能的概念，以及平衡浓度比的计算。解题步骤包括温度转换、玻尔兹曼因子计算和指数运算，属于多步骤计算过程。虽然计算本身不复杂，但需要综合应用多个知识点，因此在选择题型内属于等级3的难度。" + }, + { + "idx": 2723, + "question": "Assume there is an edge dislocation with Burgers vector b in the [0-10] direction gliding along the (100) plane. If another edge dislocation with Burgers vector in the [010] direction moves through the (001) plane, will this dislocation form a kink or a jog when passing through the aforementioned dislocation?", + "answer": "Kink", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两个选项（kink或jog）中选择正确答案 | 知识层次: 题目需要理解位错的基本概念（如Burgers向量和滑移面），并能够分析两种不同位错相互作用时的行为。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，这道题目属于较高难度，需要考生综合运用位错理论中的多个概念（Burgers矢量、滑移面、割阶与扭折的形成机制）并进行空间几何关系的判断。具体来说：" + }, + { + "idx": 2724, + "question": "Assume there is an edge dislocation with a b in the [0-10] direction gliding along the (100) crystal plane. If a screw dislocation with a b direction of [100] gliding on the (001) crystal plane passes through the aforementioned dislocation, will it form a kink or a jog?", + "answer": "Jog", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两个选项（kink或jog）中选择正确答案 | 知识层次: 题目需要理解位错的基本概念（如刃位错和螺位错的性质），并能够应用这些概念来分析两种位错相互作用的结果。虽然不涉及复杂的计算或多步推理，但需要对位错运动和相互作用有一定的综合分析能力。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。首先，题目涉及两种不同类型的位错（刃型位错和螺型位错）的相互作用，需要考生对位错的基本性质（如柏氏矢量和滑移面）有清晰的理解。其次，题目要求考生分析两种位错相互穿过时形成的缺陷类型（kink或jog），这需要综合应用位错理论中的相关知识，并进行空间想象和逻辑推理。此外，题目中的晶体学方向和平面描述增加了复杂性，要求考生能够准确地将抽象概念转化为具体情境。因此，该题目在选择题型内属于较高难度，需要考生具备较强的综合分析能力和概念应用能力。" + }, + { + "idx": 2725, + "question": "There are two left-handed screw dislocation lines, each with an energy of $E_{1}$. When they approach infinitely close, what is the total energy?", + "answer": "Since the strain energy of a dislocation is proportional to $b^{2}$, and the energies of like-signed screw dislocations are the same, their Burgers vectors must be identical. If they approach infinitely close and merge into a new dislocation with a Burgers vector of 2b, the total energy should be $4E_{1}$. However, in reality, this dislocation reaction cannot proceed because the energy increases after merging. Moreover, like dislocations repel each other, and the repulsive force between two like-signed dislocations will prevent them from approaching infinitely close.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两个左旋螺位错线接近时的总能量变化，并论述位错反应不能进行的原因。答案包含详细的文字解释和理论分析，而非简单的计算或选择。 | 知识层次: 题目涉及位错能量计算、位错反应的能量变化分析以及位错间相互作用力的理解，需要综合运用位错理论、能量守恒原理和力学分析，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2726, + "question": "Are the types of dislocations the same at each point on a dislocation loop?", + "answer": "Judging by the angle between the dislocation line and the Burgers vector, if the Burgers vector of a dislocation loop is perpendicular to the dislocation line at each point on the loop, then the nature of the dislocations is the same at each point on the loop, all being edge dislocations; however, if the Burgers vector of the dislocation loop is parallel to the plane where the dislocation line lies, then some are pure edge dislocations, some are pure screw dislocations, and others are mixed dislocations; when the Burgers vector intersects the dislocation loop line at a certain angle, although each point on this dislocation loop is a mixed dislocation, the edge and screw components at each point are different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对位错环上各点位错类型是否相同进行解释和论述，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析位错环上各点位错类型的异同，需要理解位错线与伯格斯矢量的角度关系，并综合运用边缘位错、螺型位错和混合位错的概念进行推理分析。这涉及多个概念的关联和综合运用，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用位错理论中的多个核心概念（如位错线、伯格斯矢量、刃型位错、螺型位错、混合位错等），并能够根据伯格斯矢量与位错线之间的角度关系进行复杂的推理分析。解题时需要理解并应用位错环上不同位置位错性质的动态变化，涉及三维空间想象和矢量分析能力。这种需要全面分析复杂现象并作出机理深度解释的题目，在选择题型中属于最具挑战性的类型。" + }, + { + "idx": 2727, + "question": "Indicate the nature types of the three dislocations in the dislocation reaction $$ \\frac{a}{2}[10\\overline{{{1}}}] + \\frac{a}{6}[\\overline{{{1}}}21] \\rightarrow \\frac{a}{3}[11\\overline{{{1}}}] $$?", + "answer": "Referring to the Thompson tetrahedron, this dislocation reaction corresponds to $\\begin{array}{r l r l r l r l r l}{{\\bf C}{\\bf A}}&{{}}&{+}&{{}{\\bf a}{\\bf C}}&{}&{{}\\searrow}&{}&{{\\bf a}{\\bf A}}\\end{array}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应的性质类型，并参考Thompson四面体进行说明。答案提供了详细的文字解释和图示说明，属于需要文字论述的简答题类型。 | 知识层次: 题目涉及位错反应的分析，需要理解Thompson四面体的应用，以及位错类型的识别和反应过程的解释。这需要综合运用材料科学中的位错理论，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握Thompson四面体的复杂符号系统，还需要理解位错反应的能量和几何条件，并能将抽象的位错反应符号与具体的晶体学概念对应起来。这需要考生具备：" + }, + { + "idx": 2728, + "question": "Calculate the dislocation density ρ when the shear strength is $42\\mathrm{MPa}$.", + "answer": "The dislocation density ρ can be calculated using the formula ρ = (τ̄/αGb)^2, where α is a constant (typically taken as 0.5). Substituting τ̄ = 42×10^6 Pa, G = 50×10^9 Pa, and b = 3.12×10^-10 m, we obtain ρ = (42×10^6 / (0.5×50×10^9×3.12×10^-10))^2 ≈ 7.3×10^12 m^-2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（dislocation density ρ），这符合计算题的特征。 | 知识层次: 题目要求直接套用公式进行数值计算，涉及基本的材料科学参数和简单的代数运算，无需多步推导或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要代入多个已知参数并进行计算，但整个过程仅涉及单一公式的直接套用，没有复杂的推导或多步骤组合。学生只需正确识别公式并准确代入数值即可得出答案，符合等级2的简单应用要求。" + }, + { + "idx": 2729, + "question": "Given that the lattice constant of a $\\\\mathrm{\\\\hat{Cu}}$ crystal is $a=0.35\\\\mathrm{nm}$, the shear modulus $G=4\\\\times10^{4}MPa$, and there is a dislocation with Burgers vector $\\\\pmb{\\\\mathscr{b}}==\\\\frac{a}{2}[\\\\overline{{1}}01]$, where the dislocation line direction is [-101], calculate the strain energy of this dislocation.", + "answer": "Based on the relationship between the Burgers vector and the dislocation line, it is known that this dislocation is a screw dislocation, and its strain energy is $$ \\\\begin{array}{r}{E=\\\\frac{G b^{2}}{4\\\\pi}\\\\mathrm{ln}\\\\frac{{R}}{r_{\\\\mathrm{0}}}}\\\\end{array}$$ $r_{0}\\\\approx b-{\\\\frac{\\\\sqrt{2}}{2}}a=0.707\\\\times0.35\\\\times10^{-6}=2.475\\\\times10^{-10}({\\\\mathrm{m}})$ $R{\\\\approx}1\\\\times10~^{\\\\circ}\\\\mathrm{m}$ $E={\\\\frac{4\\\\times10^{10}\\\\times(2.475\\\\times10^{-16})^{2}}{4\\\\pi}}\\\\ln{\\\\frac{10^{-2}}{2.475\\\\times10^{-10}}}=3.415\\\\times10^{-9}(\\\\mathrm{N}\\\\cdot\\\\mathrm{m}/\\\\mathrm{m})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解位错的应变能，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括确定位错类型、计算应变能公式中的各项参数，并进行数值计算。虽然涉及的知识点较为基础，但需要综合运用位错理论和弹性力学的基本原理，属于中等应用层次。 | 难度: 在选择题中属于高难度，需要深入理解位错理论、Burgers向量与位错线的关系，并进行多步复杂计算，包括对数运算和单位转换。题目要求综合应用材料力学和晶体学知识，涉及多个变量和公式推导，对学生的分析能力和计算精度要求较高。" + }, + { + "idx": 2730, + "question": "In fcc, can the dislocation reaction $$ \\\\frac{a}{2}[10\\\\overline{{{1}}}] + \\\\frac{a}{6}[\\\\overline{{{1}}}21] \\\\rightarrow \\\\frac{a}{3}[11\\\\overline{{{1}}}] $$ proceed?", + "answer": "Dislocation reaction geometric condition: $b_{1}+b_{2}=\\\\Big(\\\\frac{1}{2}-\\\\frac{1}{6}\\\\Big)a+\\\\frac{2}{6}b+\\\\Big(-\\\\frac{1}{2}+\\\\frac{1}{6}\\\\Big)c=\\\\frac{1}{3}a+\\\\frac{1}{3}b-\\\\frac{1}{3}c=\\\\frac{a}{3}[11\\\\bar{1}]$ Energy condition: $\\\\left|{\\\\frac{a}{2}}{\\\\surd2}\\\\right|^{2}+\\\\left|{\\\\frac{a}{6}}{\\\\surd6}\\\\right|^{2}=\\\\Bigl({\\\\frac{a^{2}}{2}}+{\\\\frac{a^{2}}{6}}\\\\Bigr)>\\\\frac{a^{2}}{3}$ Therefore $\\\\frac{a}{2}[10\\\\overline{{{1}}}]+\\\\frac{a}{6}[\\\\overline{{{1}}}21]{\\\\rightarrow}\\\\frac{a}{3}[11\\\\overline{{{1}}}]$ The dislocation reaction can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应是否可以进行，答案中包含了详细的几何条件和能量条件的计算和解释，需要文字论述和解释，而不是简单的选择、判断或纯数值计算。 | 知识层次: 题目涉及位错反应的几何条件和能量条件的综合分析，需要理解位错反应的基本原理，进行多步计算和推理分析，判断反应是否能够进行。这需要较高的认知能力和对位错理论的深入理解。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2731, + "question": "Given the stacking fault energy Y=0.01 J/m², shear modulus G=7 × 10^10 Pa, lattice constant α=0.3 nm, Poisson's ratio v=0.3 for an fcc crystal, determine the equilibrium separation distance between the two partial dislocations $\\frac{a}{6}[11\\vec{2}]$ and $\\frac{a}{6}[2\\overline{{{1}}}\\overline{{{1}}}]$.", + "answer": "$d_{\\mathrm{s}}\\approx\\frac{G b^{\\mathrm{2}}}{24\\pi\\gamma}$ $b{=}{\\frac{a}{n}}{\\sqrt{1^{2}+1^{2}+2^{2}}}{=}{\\frac{\\sqrt{6}}{6}}a,$ $$ d_{*}\\approx\\frac{7\\times10^{10}\\times\\frac{1}{6}\\times(0.3\\times10^{-9})^{2}}{24\\times3.1416\\times0.01}=1.3926\\times10^{-9}(\\mathrm{m})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的材料参数和公式进行数值计算，最终得出一个具体的数值结果。答案中包含了详细的公式推导和计算步骤，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错理论、堆垛层错能、剪切模量等概念，并应用相关公式进行综合分析。虽然不涉及复杂的推理分析或创新应用，但需要一定的思维深度和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如堆垛层错能、剪切模量、晶格常数、泊松比等）并进行多步骤计算。题目要求考生能够正确应用公式并代入数值进行计算，同时需要理解位错分离距离的物理意义。虽然题目提供了公式，但计算过程涉及多个变量和单位转换，对考生的综合计算能力和概念掌握有一定要求。" + }, + { + "idx": 2732, + "question": "The dislocation spacing of a Ni crystal is ${\\\\bf2000n m}$. Assuming each dislocation is caused by an additional (110) atomic plane, calculate the $\\\\pmb\\\\theta$ angle of the small-angle grain boundary.", + "answer": "The interplanar spacing of (110) is $d_{110}=\\\\frac{1}{2}\\\\times\\\\frac{\\\\alpha}{\\\\sqrt{1^{2}+1^{2}+0}}=\\\\stackrel{0.35238}{2\\\\sqrt{2}}=0.1246(\\\\mathrm{nm})$. $$ \\\\sin\\\\frac{\\\\theta}{2}=\\\\frac{d_{110}}{\\\\cal{I}}=\\\\frac{0.1246}{2000}=6.23\\\\times10^{-5},$$ $$ \\\\theta{=0.003569527^{\\\\circ}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解小角度晶界的定义和计算步骤，但不需要复杂的综合分析或推理过程。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算小角度晶界的θ角，解题步骤仅涉及直接套用已知的晶面间距公式和简单的三角函数关系，无需多个公式组合或复杂的分析过程。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2733, + "question": "Can the new dislocation generated by the dislocation reaction $$ \\\\frac{a}{2}[10\\\\overline{{{1}}}] + \\\\frac{a}{6}[\\\\overline{{{1}}}21] \\\\rightarrow \\\\frac{a}{3}[11\\\\overline{{{1}}}] $$ move on the slip plane?", + "answer": "The dislocation line of the new dislocation $\\\\frac{a}{3}[11\\\\overline{{{1}}}]$ is located at the intersection of (111) and (111) planes on the (001) plane, and it is a pure edge dislocation. Since the (001) plane is a non-close-packed plane in fcc, it cannot move and is a fixed dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释新生成的位错是否能在滑移面上移动，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及位错反应和位错运动的综合分析，需要理解位错的性质、滑移面的选择以及非密排面的影响，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2734, + "question": "In an aluminum specimen, the dislocation density within the grains was measured to be 5×10^9/cm². Assuming all dislocations are concentrated on the subgrain boundaries; each subgrain has a regular hexagonal cross-section. The misorientation angle between subgrains is 5°, and if all dislocations are edge dislocations with b = a/2 [101], the magnitude of the Burgers vector is equal to 2×10^-10 m. Calculate the dislocation spacing on the subgrain boundary.", + "answer": "D = b / (2 sin(θ/2)) ≈ b / θ = (2×10^-10) / 0.087 = 23×10^-10 m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式推导，最终给出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括应用Burgers矢量和位错间距的公式，同时需要理解位错密度、亚晶界和位错类型之间的关系。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解位错密度、亚晶界取向差、伯格斯矢量等多个材料科学概念，并应用公式进行多步骤计算（包括角度转换和单位统一）。虽然题目提供了关键公式，但考生仍需正确识别和应用这些概念才能得出答案。" + }, + { + "idx": 2735, + "question": "If this stress determines the shear strength of the material, to achieve a strength value of $\\\\frac{G}{100}$, and given that $G=50\\\\mathrm{GPa}$, $a=0.36\\\\mathrm{nm}$, what should the value of $D$ be?", + "answer": "According to $\\\\overline{\\\\tau} = \\\\frac{G}{100}$, substituting $\\\\overline{\\\\tau} = \\\\frac{Gb}{D}$ yields $D = 100b$. The Burgers vector $b = \\\\frac{a\\\\sqrt{3}}{2} = \\\\frac{0.36\\\\times10^{-9}\\\\times\\\\sqrt{3}}{2} \\\\approx 3.12\\\\times10^{-10}\\\\mathrm{m}$, therefore $D = 100\\\\times3.12\\\\times10^{-10} = 3.12\\\\times10^{-8}\\\\mathrm{m}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解D的值，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式应用和数值计算，涉及Burgers向量的计算和材料强度的关联分析，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解剪切强度与位错间距的关系，进行多步计算（包括Burgers矢量计算和单位换算），并正确应用材料科学中的基本公式。虽然不涉及复杂变量，但需要综合应用多个概念才能得出正确答案。" + }, + { + "idx": 2736, + "question": "The lattice constant of a copper single crystal is $a=0.36\\\\mathfrak{n m}$. When the copper single crystal sample is subjected to tensile deformation at a constant strain rate, the true strain of the sample is $6\\\\%$ after $\\\\mathtt{3s}$. If the average velocity of dislocation motion is $4\\\\times10^{-3}~\\\\mathrm{cm/s}$, calculate the average dislocation density in the crystal.", + "answer": "① The two nodes in the dislocation network and the dislocation segments between them can act as F-R sources, and the shear stress required for dislocation multiplication is the minimum shear stress required to activate the F-R source; $$ D=\\\\frac{G b}{\\\\tau}$$ ② $$ D=\\\\frac{G b}{\\\\tau}=\\\\frac{G b}{\\\\frac{G}{100}}=100b=100~\\\\frac{\\\\sqrt{2}}{2}a=25.5\\\\left(\\\\mathrm{nm}\\\\right)$$ ③ For a three-dimensional dislocation network $$ \\\\rho={\\\\frac{2}{D^{2}}}=2\\\\left({\\\\frac{\\\\tau}{G b}}\\\\right)^{2}=2\\\\left({\\\\frac{42\\\\times10^{6}}{50\\\\times10^{8}\\\\times2.55\\\\times10^{-8}}}\\\\right)^{2}=2.17\\\\times10^{9}{\\\\mathrm{cm}}^{-2}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解平均位错密度，答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括使用Frank-Read源公式、剪切应力计算、位错密度公式等，涉及多个概念的综合应用和数值计算，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于高难度，题目涉及多步计算和多个概念的关联应用。需要理解晶格常数、应变率、位错运动速度等概念，并进行复杂的数学推导和计算。此外，题目还要求综合分析位错密度与剪切应力、弹性模量等参数的关系，涉及多变量计算和物理概念的深入理解。" + }, + { + "idx": 2737, + "question": "The average distance between nodes of the entangled three-dimensional dislocation network in a copper single crystal is $D$. Calculate the stress $\\overline{\\tau}$ required for dislocation multiplication.", + "answer": "The stress $\\overline{\\tau}$ required for dislocation multiplication can be calculated by the formula $\\overline{\\tau} = \\frac{Gb}{D}$, where $G$ is the shear modulus and $b$ is the Burgers vector of the dislocation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式进行数值计算，解答过程涉及具体的物理量计算和公式应用。 | 知识层次: 题目要求直接应用公式$\\overline{\\tau} = \\frac{Gb}{D}$进行计算，属于基本公式的直接套用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需直接套用单一公式 $\\overline{\\tau} = \\frac{Gb}{D}$ 进行计算，无需额外的概念理解或步骤组合。属于最基础的公式应用层级，符合等级1的定义（单一公式直接计算）。" + }, + { + "idx": 2738, + "question": "In an aluminum sample, the dislocation density inside the grains is measured to be 5×10^9/cm². Assuming all dislocations are concentrated on the subgrain boundaries; each subgrain has a regular hexagonal cross-section. The misorientation angle between subgrains is 5°, and if all dislocations are edge dislocations, with b = a/2 [101], where the magnitude of the Burgers vector equals 2×10^-10 m, calculate the average size of the subgrains.", + "answer": "The area of a regular hexagon S = (3/2)√3 a², and the total perimeter is 6a. The number of subgrains per unit area n = 1/S. The dislocation density ρ = 5×10^13 = (1/S) × 6a × (1/D) × (1/2). Solving gives a = 1×10^-5 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解亚晶的平均尺寸，涉及到了具体的数学运算和物理公式的应用。答案也展示了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和概念关联，包括位错密度、亚晶界、位错类型和Burgers矢量的综合应用。需要理解几何关系并进行公式推导和数值计算，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解位错密度、亚晶界、位错类型和伯格斯矢量等多个概念，并进行多步骤计算。虽然题目提供了正确选项的解题思路，但仍需要综合运用材料科学和几何知识来推导亚晶尺寸，涉及单位换算和公式变形等操作。" + }, + { + "idx": 2739, + "question": "If an extra (111) plane is embedded, causing a small-angle grain boundary tilted by 1° in α-Fe, calculate the average distance between the dislocations.", + "answer": "The lattice constant of α-Fe crystal $$ \\\\alpha=\\\\frac{4r_{\\\\mathrm{Fe}}}{\\\\sqrt{3}}=\\\\frac{4\\\\times0.1241}{\\\\sqrt{3}}=0.2866(\\\\mathrm{nm})$$ $$x d_{111}={\\\\frac{a}{\\\\sqrt{{{1}}^{2}+{{1}}^{2}+{{1}}^{2}}}}={\\\\frac{0.2866}{\\\\sqrt{3}}}=0.16547({\\\\mathrm{nm}})$$ $$ \\\\sin{\\\\frac{\\\\theta}{2}}={\\\\frac{d_{\\\\mathrm{{111}}}}{\\\\it{l}}}$$ $$ \\\\begin{array}{r}{\\\\lambda=\\\\frac{d_{\\\\mathrm{{n1}}}}{\\\\sin\\\\frac{\\\\theta}{2}}=\\\\frac{0.16547}{\\\\sin\\\\left(\\\\frac{1}{2}\\\\right)^{\\\\circ}}=18.9615(\\\\mathrm{nm})}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解晶格常数、晶面间距以及小角度晶界的几何关系，并应用三角函数进行计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的综合分析能力和对材料科学基础知识的理解。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、晶面间距计算、小角度晶界与位错的关系等多个概念，并进行多步骤的计算和综合分析。虽然题目提供了计算公式和步骤，但需要考生具备扎实的基础知识和一定的计算能力才能正确解答。" + }, + { + "idx": 2740, + "question": "To achieve homogeneous nucleation at 2045K, by how much must the atmospheric pressure be increased? Given the volume change during solidification ΔV= -0.26 cm^3/mol (1J=9.87×10^6 cm^3·Pa)", + "answer": "For homogeneous nucleation to occur at 1726K, an undercooling of 319°C is required. To achieve this, the pressure must be increased to raise the solidification temperature of pure nickel from 1726K to 2045K: dP/dT=ΔH/TΔV. Integrating this equation: ∫1.013×10^5^P dP=∫1726^2045 ΔH/TΔV dT P-1.013×10^5=ΔH/ΔV ln2045/1726=18075/0.26×9.87×10^5×ln2045/1726=116366×10^5(Pa). Thus, when P=116366×10^5-1.013×10^5=116365×10^5(Pa), homogeneous nucleation can occur at 2045K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如dP/dT=ΔH/TΔV的积分计算）来确定需要增加的大气压力值，最终给出具体的数值结果。这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式应用和积分运算，同时需要理解相变热力学中的Clausius-Clapeyron方程及其在凝固过程中的应用。虽然涉及一定的综合分析，但整体上仍属于中等难度的应用题目。 | 难度: 在选择题中属于高难度，题目涉及多步骤的复杂计算和概念的综合应用。需要理解并应用热力学公式（dP/dT=ΔH/TΔV），进行积分计算，同时处理单位转换（1J=9.87×10^6 cm^3·Pa）。此外，还需要综合分析温度变化对压力需求的影响，并进行精确的对数运算。这些步骤在选择题型中属于较高层次的认知要求，需要较强的计算能力和概念关联能力。" + }, + { + "idx": 2741, + "question": "It is known that liquid pure nickel undergoes homogeneous nucleation at an undercooling of 319°C under 1.013×10^5 Pa (1 atm). Given the critical nucleus radius as 1 nm, the melting point of pure nickel as 1726 K, the heat of fusion Lm = 18075 J/mol, and the molar volume V = 6.6 cm^3/mol, calculate the liquid-solid interfacial energy and the critical nucleation work for pure nickel.", + "answer": "Since r* = 2σ/ΔGv = 2σTm/LmΔT = 2σTm V/ΔHmΔT, and for solidification, ΔGv = LmΔT/Tm, thus σ = r*ΔGv/2V = r*ΔHmΔT/2VTm = 1×10^-7 × 18075 × 319 / 2 × 1726 × 6.6 = 2.53×10^-5 (J/cm^2) = 0.253 (J/m^2). ΔG* = 16πσ^3Tm^2Vs^2 / 3ΔHm^2ΔT^2 = 16 × 3.14 × (2.53×10^-5)^3 × 1726^2 × 6.6^2 / 3 × 18075^2 × 319^2 = 1.06×10^-18 (J).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及多个物理量的计算和推导，最终需要得出具体的数值结果。答案中展示了详细的公式应用和计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个公式的应用和概念关联，如临界核半径、熔化热、摩尔体积等，需要综合分析并正确代入数值进行计算。虽然不涉及复杂的推理分析或机理解释，但计算过程较为复杂，超出了简单应用的范围。 | 难度: 在选择题中属于高难度题目，需要综合运用多个热力学和材料科学概念（如均相成核、临界核半径、界面能等），并进行多步骤的复杂计算。题目涉及多个变量的转换和单位统一（如J/cm²到J/m²的转换），且需要正确应用公式推导过程。这种题目在选择题型中属于需要深度理解和较强计算能力的类型，远超基础概念题和简单计算题的难度水平。" + }, + { + "idx": 2742, + "question": "Explain why polymers crystallized at lower temperatures have a wider melting range, and vice versa.", + "answer": "When polymers crystallize at lower temperatures, the mobility of molecular chains is poor, resulting in less perfect crystals with a greater variation in perfection. Crystals with more defects will melt at lower temperatures, while those with fewer defects will melt at higher temperatures, leading to a wider melting range. Conversely, when polymers crystallize at higher temperatures, the mobility of molecular chains is stronger, resulting in more perfect crystals with less variation in perfection. Therefore, the melting range is narrower.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物在不同温度下结晶时熔融范围的变化原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释聚合物在不同温度下结晶时熔融范围变化的机理，涉及分子链运动性、晶体完美度变化及其对熔融行为的影响。这需要综合运用聚合物结晶和熔融的基本原理，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2743, + "question": "Calculate the axial ratio c/a of an ideal close-packed hexagonal crystal structure", + "answer": "c/a=√(8/3)=1.633", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算轴向比c/a），并给出了具体的计算公式和结果（c/a=√(8/3)=1.633），符合计算题的特征。 | 知识层次: 题目要求计算理想密排六方晶体结构的轴比c/a，涉及基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（c/a=√(8/3)）进行简单计算，无需额外的公式组合或复杂步骤，属于单一公式直接计算的难度等级。" + }, + { + "idx": 2744, + "question": "Indicate the close-packed plane of an ideal hexagonal close-packed crystal structure", + "answer": "The close-packed plane is {0001}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出密排面，答案需要文字说明具体的晶面指数，属于需要简短文字回答的问题 | 知识层次: 题目考查对六方密堆积晶体结构中密排面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对六方密堆积晶体结构密排面的基本定义记忆，属于最基础的概念性知识。正确选项直接给出了标准答案{0001}晶面，无需任何解释或推理过程，完全符合\"基础概念记忆\"层次的要求。在选择题难度谱系中，这属于最简单的等级1问题。" + }, + { + "idx": 2745, + "question": "Calculate the change in the melting point of tin when the pressure increases to $500\\\\times10^{5}\\\\mathbf{Pa}$. It is known that at $\\\\mathfrak{10}^{5}\\\\mathbf{Pa}$, the melting point of tin is $505~\\\\mathrm{K}$, the heat of fusion is $7196\\\\mathrm{J/mol}$, the molar mass is $118.8\\\\times10^{-3}~\\\\mathrm{kg/mol}$, the density of solid tin is $\\\\small7.30\\\\times10^{3}~\\\\mathrm{kg/m^{3}}$, and the volume change during melting is $+2.7\\\\%$.", + "answer": "The molar volume of tin $$ V_{\\\\mathrm{m}}={\\\\mathrm{molar mass}}/\\\\mathrm{density}={\\\\frac{118.7\\\\times10^{-3}}{7.30\\\\times10^{3}}}=1.626\\\\times10^{-5}(\\\\mathrm{m}^{3}/\\\\mathrm{mol})$$ $$ \\\\begin{array}{r}{\\\\Delta V_{\\\\mathrm{m}}=0.027\\\\times1.626\\\\times10^{-5}}\\\\\\\\ {=4.39\\\\times10^{-7}\\\\left(\\\\mathrm{m}^{3}/\\\\mathrm{mol}\\\\right)}\\\\end{array}$$ Assuming $\\\\Delta V_{\\\\mathfrak{m}}$ and $\\\\Delta H_{\\\\pmb{\\\\upmu}}$ remain constant within the considered temperature range, and $\\\\Delta T{\\\\ll}T$ $$ \\\\begin{array}{c}{{\\\\frac{\\\\Delta\\\\phi}{\\\\Delta T}=\\\\frac{\\\\Delta H_{\\\\mathrm{m}}}{T\\\\cdot\\\\Delta V_{\\\\mathrm{m}}}=\\\\frac{7196}{505\\\\times4.39\\\\times10^{-7}}}}\\\\\\\\ {{=3.25\\\\times10^{7}(\\\\mathrm{N}\\\\cdot\\\\mathrm{m}^{-2}\\\\cdot\\\\mathrm{K}^{\\\\mathrm{\\\\Delta_{\\\\parallel}}})}}\\\\end{array}$$ Then $$ \\\\Delta T={\\\\frac{(500-1)\\\\times10^{5}}{3.25\\\\times10^{7}}}=1.54(\\\\mathrm{K})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锡的熔点变化，答案中包含了详细的数学推导和计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用克劳修斯-克拉珀龙方程进行压力对熔点影响的计算，并理解相关物理量的含义和相互关系。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点进行中等难度的计算。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如摩尔体积、热力学关系）并进行多步骤计算（包括单位转换、比例计算和公式应用）。虽然题目提供了所有必要数据，但解题过程涉及多个物理量的综合运用和近似假设，对学生的综合分析能力有一定要求。" + }, + { + "idx": 2746, + "question": "Determine the solidification velocity $R$ required to maintain a planar liquid-solid interface during directional solidification of an 8% B binary alloy. Given the temperature gradient $G=225^{\\\\circ}C$/cm, the diffusion coefficient of component B $D=2\\\\times10^{-4}$ cm²/s, the equilibrium partition coefficient $\\\\pmb{k}_{0}=0.3$, and the slope of the binary alloy liquidus line $m=0.142^{\\\\circ}C$/%, which means the temperature decreases by $0.142^{\\\\circ}C$ for every 1% increase in B solute concentration.", + "answer": "nan", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数和公式计算固相速度R，需要应用材料科学中的相关理论和数值计算方法，属于典型的计算题。 | 知识层次: 题目需要应用多个给定的参数（温度梯度、扩散系数、分配系数、液相线斜率）进行多步计算，涉及公式应用和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如温度梯度、扩散系数、平衡分配系数、液相线斜率等）并进行多步计算和综合分析。题目要求计算维持平面液-固界面所需的凝固速度，涉及多个变量的关联和计算步骤，但不需要处理过于复杂的多变量交互作用。" + }, + { + "idx": 2747, + "question": "What is the experimental method for determining the critical resolved shear stress of a crystal?", + "answer": "Experimental method: 1) Select an appropriate orientation in the single crystal to ensure that the initial slip of the crystal is single slip. 2) Determine the orientation of the crystal's tensile direction to obtain the orientation factor. 3) Use τc=σscosφcosλ and the σs from the tensile curve, along with the orientation factor, to calculate the τs, the type of crystal, purity, test temperature, strain rate, and other factors affecting the resolved shear stress τc value.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释实验方法，答案提供了详细的步骤和论述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释实验方法并涉及多步计算和概念关联，如确定取向因子、使用公式计算临界分切应力等，需要综合分析能力和对实验条件的理解。 | 难度: 在选择题型中属于较高难度，因为题目要求考生不仅要理解晶体临界分切应力的基本概念，还需要掌握实验方法的具体步骤（包括晶体取向选择、取向因子确定等），并能将这些概念与计算公式（τc=σscosφcosλ）关联起来进行综合分析。此外，题目还涉及多种影响因素（晶体类型、纯度、温度等）的考虑，这要求考生具备较强的多角度分析能力。在选择题型中，这种需要多步骤计算和概念关联的题目相对较少，因此难度等级较高。" + }, + { + "idx": 2748, + "question": "In a copper crystal, when the a/2[101] dislocation on the (111) plane reacts with the a/2[011] dislocation on the (11-1) plane, write the dislocation reaction equation and determine the direction of the reaction.", + "answer": "[101]+[011]a2/2+a2/2>a2/2 , the reaction proceeds to the right", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出位错反应方程并确定反应方向，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求写出位错反应方程并确定反应方向，涉及多步计算和概念关联，需要理解位错反应的基本原理并能够进行综合分析。 | 难度: 在选择题型内，该题目属于较高难度。首先，题目要求考生掌握位错反应的基本概念和计算方法，需要理解并正确写出位错反应方程。其次，题目涉及多个位错矢量的计算和方向判断，要求考生具备较强的空间想象能力和综合分析能力。此外，题目还要求考生判断反应方向，这需要深入理解位错反应的驱动力和能量变化。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 2749, + "question": "The $c/a$ ratio for an ideal hexagonal close-packed metal is ", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项字母形式给出 | 知识层次: 题目考查对理想六方密堆积金属的c/a比值的记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆理想六方密堆积金属的$c/a$比值这一具体数值即可作答。在选择题型中，此类直接考察定义或基本数值的记忆性题目属于最简单的难度等级，无需理解或分析过程。" + }, + { + "idx": 2750, + "question": "Indicate the close-packed directions of an ideal hexagonal close-packed crystal structure", + "answer": "The close-packed directions are (11-20)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释指出密排方向，答案是一个具体的晶体学方向（11-20），属于需要简短文字回答的简答题类型 | 知识层次: 题目考查对理想六方密堆积晶体结构中密排方向的基本概念的记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目仅要求记忆六方密堆积晶体结构的密排方向（11-20），属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需识别正确选项，因此属于最低难度等级。" + }, + { + "idx": 2751, + "question": "In a copper crystal, when the a/2[101] dislocation on the (111) plane reacts with the a/2[011] dislocation on the (11-1) plane, describe the nature of the new dislocation.", + "answer": "The new dislocation b=a/2[110] is a unit dislocation in the face-centered cubic structure; the direction of the dislocation line is along the intersection line [110] of the two crystal planes (111) and (111), so the dislocation is of edge type; the slip plane is (001), which is not a close-packed plane, hence it is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述新位错的性质，答案提供了详细的文字解释和论述，包括位错类型、方向和滑移面等特征，符合简答题的特点。 | 知识层次: 题目要求分析位错反应后新位错的性质，涉及位错线方向、滑移面判断以及位错类型（刃型位错）的确定。这需要综合运用晶体结构、位错理论和滑移系统知识，进行多步推理和机理解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握位错反应的基本概念，还需要综合运用晶体学知识（如面心立方结构中的位错类型、滑移面判断）和矢量运算能力（如位错反应后的新柏氏矢量计算）。此外，题目涉及多个复杂分析步骤：1) 判断新位错的柏氏矢量性质 2) 确定位错线方向 3) 分析位错类型（刃型）4) 评估滑移面特性（非密排面）5) 最终得出固定位错的结论。这种需要多维度知识整合和机理深度解释的题目，在选择题中属于最复杂的类型。" + }, + { + "idx": 2752, + "question": "Cesium chloride (CsCl) has an ordered body-centered cubic structure, which belongs to (A) body-centered cubic lattice (B) face-centered cubic lattice (C) simple cubic lattice", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对晶体结构分类的基本概念记忆，只需识别CsCl的晶体结构类型即可，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（CsCl的晶体结构类型），但需要考生理解并区分不同的立方晶格类型（体心立方、面心立方和简单立方）。正确选项（C）需要考生能够辨析CsCl的有序体心立方结构实际上属于简单立方格子，而不是直接选择体心立方格子（A）。这种辨析需要一定的概念理解和简单分析能力，因此难度等级为2。" + }, + { + "idx": 2753, + "question": "The [001] direction in a cubic crystal is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，且答案以选项字母形式给出 | 知识层次: 题目考查对立方晶体中[001]方向的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆立方晶体中[001]方向的定义即可作答，无需复杂理解或辨析步骤。" + }, + { + "idx": 2754, + "question": "In the hexagonal crystal system, the interplanar spacing of (11-20) plane is (1010) plane spacing.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查六方晶系中晶面间距的计算，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单难度。题目直接考察六方晶系中晶面间距的基本公式应用，只需正确选择并套用公式即可得出答案，无需复杂计算或变形步骤。知识层次为简单应用，符合等级2的标准。" + }, + { + "idx": 2755, + "question": "In a crystal, the defect formed by creating a vacancy while simultaneously generating an interstitial atom is called", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查晶体缺陷的基本概念和分类，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆，仅需识别并回忆晶体缺陷的定义和分类。题目直接考察对\"Frenkel defect\"这一术语的记忆，无需复杂理解或分析，属于最简单的难度等级。" + }, + { + "idx": 2756, + "question": "Fick's first law describes the characteristics of steady-state diffusion, where the concentration does not vary with . \\n\\n(A) distance (B) time (C) temperature", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)中选择正确答案 | 知识层次: 题目考查Fick's first law的基本概念记忆，即稳态扩散中浓度不随时间变化这一特性，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆Fick第一定律的定义即可选出正确答案。题目中明确提到“steady-state diffusion”和“concentration does not vary with”，这些都是Fick第一定律的基本特征，学生只需记住这些关键点就能轻松作答。在选择题型中，此类题目属于最简单的直接记忆类问题。" + }, + { + "idx": 2757, + "question": "The ordered structure formation temperature of any alloy is _____ the disordered structure formation temperature. (A) Lower than (B) Higher than (C) May be lower or higher than", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对合金有序结构和无序结构形成温度关系的基本概念记忆，属于基础概念的理解和记忆层次。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆合金有序结构和无序结构的形成温度关系。选项明确且无需复杂分析，属于最简单的概念识别层次。" + }, + { + "idx": 2758, + "question": "The twinning plane of a face-centered cubic crystal is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（C） | 知识层次: 题目考查面心立方晶体孪晶面的基本概念记忆，属于晶体学中的基础定义性知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆（面心立方晶体的孪晶面），但需要学生对晶体结构有一定理解才能准确选择正确选项。相比纯粹的定义记忆题（等级1），此题需要学生对晶面类型进行简单辨析，但不需要复杂的分析过程（等级3）。" + }, + { + "idx": 2759, + "question": "There is a dislocation loop on the crystal slip plane, and a shear stress $\\\\boldsymbol{\\\\tau}$ is applied in the direction of its Burgers vector. What is the minimum radius required for the dislocation loop to remain stable in the crystal?", + "answer": "The force acting on the ds arc segment of the dislocation line: $\\\\pmb{\\\\tau}\\\\cdot\\\\pmb{b}\\\\cdot\\\\mathbf{d}\\\\mathscr{s}.$ At the same time, the line tension on the dislocation line: $T{\\\\approx}\\\\alpha\\\\cdot G\\\\cdot b^{2}$ , where the horizontal component: $2(\\\\alpha G b^{2})\\\\sin\\\\frac{\\\\mathrm{d}\\\\theta}{2}$ Thus, $$ \\\\mathrm{d}s=r\\\\mathrm{d}{\\\\theta},\\\\sin\\\\frac{\\\\mathrm{d}\\\\theta}{2}\\\\approx\\\\frac{\\\\mathrm{d}\\\\theta}{2}$$ When the two forces reach equilibrium, they are equal, i.e., Therefore, $$ \\\\begin{array}{c}{{\\\\tau\\\\bullet b\\\\bullet\\\\mathrm{d}s=2(a G b^{2}){\\\\frac{\\\\mathrm{d}\\\\theta}{2}}}}\\\\\\\\ {{\\\\tau\\\\bullet b\\\\bullet r_{c}\\\\bullet\\\\mathrm{d}\\\\theta=a G b^{2}\\\\mathrm{d}\\\\theta}}\\\\\\\\ {{r_{\\\\bullet}={\\\\frac{a G b}{\\\\tau}}}}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算最小半径以使位错环在晶体中保持稳定，答案通过公式推导和数值计算得出，涉及力的平衡和数学运算。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错环的受力平衡条件，并应用线张力和剪切应力的公式进行推导。虽然不涉及复杂的综合分析或创新应用，但需要一定的物理理解和数学推导能力。 | 难度: 在选择题中属于中等偏上难度，需要理解位错环的受力平衡条件、线张力概念，并进行多步数学推导和变量替换。虽然题目给出了关键公式，但需要综合应用材料力学和晶体缺陷知识才能正确推导出临界半径表达式。" + }, + { + "idx": 2760, + "question": "In a body-centered cubic structure, can a dislocation with Burgers vector $a[100]$ decompose into $\\frac{a}{2}[111]+\\frac{a}{2}[1\\overline{1}\\overline{1}]$? (A) No (B) Yes (C) Possible", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确答案，符合选择题的特征。 | 知识层次: 题目涉及位错分解的矢量分析，需要理解Burgers矢量的几何关系、位错分解的能量条件以及晶体结构对位错行为的限制。这需要综合运用晶体学、位错理论和能量分析等多方面知识，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握体心立方结构中的位错分解原理，还需要深入理解Burgers矢量的计算和能量守恒条件。解题步骤涉及复杂的矢量运算和能量分析，需要综合运用多个知识点进行推理判断。此外，题目中的选项设计也增加了判断的复杂性，要求考生具备深度推理和机理分析能力。" + }, + { + "idx": 2761, + "question": "In substitutional solid solutions, the general mode of atomic diffusion is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（C） | 知识层次: 题目考查的是置换固溶体中原子扩散的基本模式，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即替换固溶体中原子扩散的一般模式。学生只需直接回忆相关定义即可选择正确答案，无需进行复杂的概念辨析或深度理解。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 2762, + "question": "The condition for an alloy to develop constitutional supercooling during solidification is . (where $T_{\\\\ L}$ is the solidification start temperature of the alloy with composition $C_{\\\\mathrm{L}}$)", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查合金凝固过程中成分过冷的条件判断，需要理解凝固温度与成分的关系，并综合分析相关参数的影响，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解合金凝固过程中的多个概念（如固相线温度、成分过冷条件等），并能够将这些概念关联起来进行综合分析判断。题目要求考生不仅掌握基础概念，还需要进行多步计算和逻辑推理才能得出正确结论，这超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 2763, + "question": "The driving force for atomic diffusion is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查原子扩散驱动力的基本概念记忆，属于材料科学中最基础的定义性知识，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别\"原子扩散驱动力\"这一简单概念的定义即可作答。在选择题型中属于直接记忆类题目，无需理解或辨析过程，符合等级1的简单概念识别标准。" + }, + { + "idx": 2764, + "question": "When a critical nucleus forms, the reduction in volume free energy can only compensate for the surface energy by ", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（B） | 知识层次: 题目考查的是关于临界核形成时体积自由能和表面能之间关系的基本概念记忆，属于对基本原理的理解和记忆性知识。 | 难度: 该题目属于基础概念记忆类型，主要考察对临界核形成时体积自由能与表面能关系的理解。虽然需要一定的概念理解，但选项直接指向基本原理，不需要复杂的分析或比较，因此在选择题型中属于中等偏下难度。" + }, + { + "idx": 2765, + "question": "In the Kirkendall effect, the main reason for marker drift is the diffusion couple's ", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（C） | 知识层次: 题目考查Kirkendall效应的基本概念和原因，属于对基本原理的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解Kirkendall效应的基本原理和标记漂移的原因，但不需要进行复杂的比较分析或深度推理。" + }, + { + "idx": 2766, + "question": "What is the critical resolved shear stress for crystal slip?", + "answer": "The minimum resolved shear stress required for alternate slip in the slip systems of a crystal is called the critical resolved shear stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"critical resolved shear stress\"的定义，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即临界分切应力的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对\"临界分切应力\"这一基础概念的定义记忆，属于直接复述教材定义的最简单类型。题目仅要求识别正确描述定义的选项，无需解释或应用概念，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2767, + "question": "The difference between cast iron and carbon steel lies in the presence of", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案形式为选项字母（A） | 知识层次: 题目考查对铸铁和碳钢之间差异的基础概念记忆，仅需识别铸铁中特有的元素存在即可回答，属于定义性知识范畴 | 难度: 在选择题型中，该题目仅需识别和记忆基础概念（铸铁与碳钢的区别在于某种成分的存在），属于直接记忆性知识，无需复杂理解或分析步骤。" + }, + { + "idx": 2768, + "question": "The effective distribution coefficient $K_{i}$ represents the degree of mixing in the liquid phase, and its value range is . (where $K_{\\circ}$ is the equilibrium distribution coefficient)", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查对有效分布系数$K_{i}$的定义及其取值范围的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生记住有效分配系数的定义及其取值范围。虽然需要理解概念，但不需要进行复杂的分析或比较，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 2769, + "question": "In a binary alloy phase diagram, the lever rule for calculating the relative amounts of two phases can only be applied in", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，并且提供了选项（B）作为答案 | 知识层次: 题目考查对杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解杠杆法则的应用条件，但题目仅要求识别该法则适用的特定区域（两相区），属于基础概念的直接应用。不需要复杂的分析或计算，只需记住杠杆法则的基本适用条件即可正确作答。" + }, + { + "idx": 2770, + "question": "According to the vertical section of a ternary phase diagram, one can", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项字母形式给出（B） | 知识层次: 题目考查对三元相图垂直截面图的基本理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对三元相图垂直截面基本功能的记忆性知识，属于最基础的概念识别层级。学生只需直接回忆教材定义即可作答，无需任何理解或分析过程。" + }, + { + "idx": 2771, + "question": "In a ternary phase diagram, the isothermal section of a three-phase region is always a connected triangle, with its vertices touching", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对三元相图中三相区等温截面形状的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需识别和回忆三元相图中三相区的等温截面特征。题目直接考察定义性知识，无需理解或辨析，属于最简单的难度等级。" + }, + { + "idx": 2772, + "question": "In the ternary composition triangle, alloys whose compositions lie on the have equal contents of the two components represented by the other two vertices. (A) The perpendicular bisector passing through the vertex of the triangle (B) Any straight line passing through the vertex of the triangle (C) A straight line passing through the vertex of the triangle and forming a $45^{\\circ}$ angle with the opposite side", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对三元相图中特定组成线的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，但需要考生理解三元相图中通过顶点的垂直平分线的定义及其含义。虽然题目直接考察定义，但需要一定的概念理解和简单辨析能力，因此属于等级2难度。" + }, + { + "idx": 2773, + "question": "How many equivalent slip systems are there when a face-centered cubic metal single crystal is stretched along [001]? And specifically write out the indices of each slip system.", + "answer": "When an fcc-structured crystal is stretched along the [001] axis, there are a total of 8 equivalent slip systems, which are: (111)[011], (111)[101], (111)[011], (111)[101], (1 11)[011], (1 11)[101], (111)[101], (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求具体写出每个滑移系的指数，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别面心立方金属单晶在特定拉伸方向下的等效滑移系统，并具体写出每个滑移系统的指数。这需要理解滑移系统的基本概念，并能够应用晶体学知识进行多步分析和计算，涉及概念关联和综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的晶体学知识和空间想象能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握面心立方金属的基本滑移系统概念，还需要能够具体分析在特定拉伸方向[001]下的等效滑移系统数量及其指数。这涉及到多步计算和概念关联，包括对晶体学方向的理解、滑移面的确定以及等效滑移系统的识别。此外，题目还要求考生具体写出每个滑移系统的指数，这增加了题目的复杂性和对细节的要求。因此，在选择题型内，该题目需要考生进行多角度分析和论述，属于等级4难度。" + }, + { + "idx": 2775, + "question": "Carburizing steel in a carbon-rich environment can harden the surface of the steel. It is known that during this carburizing heat treatment at 1000°C, the carbon content decreases from x=5% to x=4% at a distance of 1∼2mm from the surface of the steel. First, the content of solute carbon atoms should be converted from atomic fraction to volume fraction, so the number of atoms per unit volume of the solvent iron must be determined. The density of γ-Fe at 1000°C is known to be =7.63g/cm³.", + "answer": "ρ=7.63×(6.023×10^23)/55.85=8.23×10^22 at/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及将碳含量从原子分数转换为体积分数，并计算单位体积溶剂铁的原子数。答案也是一个具体的计算结果。 | 知识层次: 题目需要进行多步计算，包括单位转换和公式应用，涉及原子分数到体积分数的转换，并需要理解碳在钢中的扩散行为。虽然计算本身不复杂，但需要综合运用密度、原子量等概念进行关联分析。 | 难度: 在选择题中属于中等偏上难度，需要理解碳原子浓度转换的概念，掌握密度与原子数密度的转换计算，并正确应用阿伏伽德罗常数和铁的摩尔质量进行多步计算。虽然题目提供了关键参数，但解题过程涉及单位转换和公式应用，对学生的综合计算能力有一定要求。" + }, + { + "idx": 2776, + "question": "Given that the recrystallization activation energy of a $\\mathtt{C u}{\\sim}30\\%\\mathtt{Z n}$ alloy is $250\\mathrm{kJ/mol}$, and it takes 1 hour for this alloy to complete recrystallization at a constant temperature of $400^{\\circ}C$, calculate how many hours it will take for this alloy to complete recrystallization at a constant temperature of $390\\mathrm{\\textperthousand}$.", + "answer": "Solution: Using the formula $$ \\frac{t_{2}}{t_{1}}{=}\\ e^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{2}}\\right)},$$ thus $$ \\begin{array}{r l}&{\\frac{t_{2}}{t_{1}}{=}\\exp\\Big({-}\\frac{Q}{R}\\Big(\\frac{1}{T_{1}}{-}\\frac{1}{T_{2}}\\Big)\\Big)}\\ &{\\quad\\quad{=}\\exp\\Big({-}\\frac{250\\times10^{3}}{8.314}\\Big(\\frac{1}{400+273}{-}\\frac{1}{390+273}\\Big)\\Big)}\\ &{\\quad{=}1.962}\\end{array}$$ Therefore, it will take 1.962 hours.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解并运用阿伦尼乌斯公式进行温度对再结晶时间影响的定量计算，同时需要单位转换和数值计算能力。虽然不涉及复杂的机理分析或创新设计，但比简单应用更复杂，需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解再结晶激活能的概念，掌握阿伦尼乌斯公式的应用，并进行多步温度转换和指数计算。虽然题目提供了公式，但需要正确代入数值并处理单位转换（如温度从摄氏度转换为开尔文），最后还需进行指数运算得出结果。这种综合性计算问题在选择题中属于较复杂的类型。" + }, + { + "idx": 2777, + "question": "Based on the diffusion coefficients at 1223K and 1136K, calculate the activation energy Q for interstitial atom diffusion in face-centered cubic metals. The diffusion coefficient at 1223K is 4.34×10⁻⁸m²/s, and at 1136K it is 1.78×10⁻⁸m²/s.", + "answer": "According to Arrhenius' law, D = D₀exp(-Q/RT). For two temperatures, we have: D₁/D₂ = exp[(-Q/R)(1/T₁ - 1/T₂)]. Substituting the data: 4.34×10⁻⁸ / 1.78×10⁻⁸ = exp[(-Q/8.314)(1/1223 - 1/1136)]. Solving gives: Q ≈ 1.2×10⁵J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的扩散系数和温度数据，通过Arrhenius方程计算激活能Q，需要应用公式进行数值计算，最终得出具体数值结果。 | 知识层次: 题目需要应用Arrhenius定律进行多步计算，涉及对数运算和温度转换，需要理解扩散系数与温度的关系，并进行综合分析来求解激活能。虽然不涉及复杂的机理分析或创新设计，但比简单的公式应用要求更高的计算能力和概念关联能力。 | 难度: 在选择题中属于中等偏上难度，需要理解Arrhenius定律并进行多步计算，包括对数运算和温度倒数处理。虽然提供了正确选项，但解题过程涉及多个概念的综合应用和较复杂的数学运算，超出了基础选择题的难度。" + }, + { + "idx": 2778, + "question": "At a temperature of 1223K, calculate the diffusion coefficient of interstitial atoms in a face-centered cubic metal. The thickness of the metal film is 0.25mm, the end face area is 1000mm², the rate of interstitial atoms passing through the film is 0.0025g/s, and the solubility of interstitial atoms in the film is 14.4kg/m³.", + "answer": "According to Fick's first law, the formula for calculating the diffusion coefficient D is: D = -J * Δx / Δρ. Here, J = v / A = 0.0025g/s / 1000mm² = 0.0025×10⁻³kg/s / 10⁻³m² = 0.0025kg/(m²·s). Δx = 0.25mm = 0.25×10⁻³m. Δρ = 0 - 14.4kg/m³ = -14.4kg/m³. Therefore, D = -0.0025kg/(m²·s) * 0.25×10⁻³m / (-14.4kg/m³) ≈ 4.34×10⁻⁸m²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散系数，答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及Fick第一定律的直接应用和简单计算，不需要多步推理或综合分析，属于基本公式的直接套用和数值计算。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用Fick第一定律公式，但解题步骤相对直接，仅需进行单位转换和简单代数运算。题目提供了所有必要参数，且计算过程不涉及复杂推导或多步骤分析，符合选择题型中\"简单公式应用计算\"的特征。" + }, + { + "idx": 2779, + "question": "According to Fick's first law, calculate the influx J (atoms/m²s) of carbon atoms entering the steel in the near-surface region.", + "answer": "J=−D(Δρ/Δx)=−(2.98×10⁻¹¹)×(−8.23×10^29)=2.45×10^19 at/(m²s)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据Fick's first law进行数值计算，并给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查菲克第一定律的直接应用，仅需套用公式进行简单计算，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式（Fick's first law）的直接套用和简单计算，无需多个公式组合或复杂分析，属于最基础的难度等级。" + }, + { + "idx": 2780, + "question": "The homogeneous nucleation rate of pure metals can be expressed by the following equation: $$ \\\\dot{N}=A\\\\exp\\\\Bigl(-\\\\frac{\\\\Delta G^{*}}{k T}\\\\Bigr)\\\\exp\\\\Bigl(-\\\\frac{Q}{k T}\\\\Bigr)$$ where $A\\\\approx10^{35}\\\\mathfrak{s e x p}\\\\left\\\\{-\\\\frac{Q}{k T}\\\\right\\\\}\\\\approx10^{-2}\\\\mathfrak{s}$, $\\\\Delta G^{*}$ is the critical nucleation work; $\\\\pmb{k}$ is the Boltzmann constant, with a value of $1.38\\\\times10^{-23}\\\\mathrm{J}/\\\\mathrm{K}$. \\n\\n$\\\\textcircled{1}$ Assuming undercooling $\\\\Delta T$ is $20\\\\mathrm{\\\\mathcal{C}}$ and ${\\\\bf 200}\\\\%$, interfacial energy $\\\\sigma{=}2\\\\times10^{-5}~\\\\mathrm{J/cm^{2}}$, heat of fusion $\\\\Delta H_{\\\\mathrm{m}}=$ $\\\\mathrm{12600J/mol}$, melting point $\\\\mathcal{T}_{\\\\mathbf{m}}{=}1000\\\\:\\\\mathrm{K}$, molar volume $V{=}6~\\\\mathrm{cm}^{3}/\\\\mathrm{mol}$, calculate the homogeneous nucleation rate $\\\\dot{N}$. \\n\\n$\\\\textcircled{2}$ If it is heterogeneous nucleation, with the contact angle between the nucleus and impurity $\\\\pmb{\\\\theta}\\\\mathrm{=}60^{\\\\circ}$, how does $\\\\dot{N}$ change? What is $\\\\Delta T$? \\n\\n$\\\\textcircled{3}$ Derive the relationship between $\\\\neq^{*}$ and $\\\\mathbf{\\\\Delta}\\\\pmb{\\\\Delta}^{T}$, and calculate $\\\\begin{array}{l}{\\\\underbrace{\\\\Delta\\\\mathcal{T}}_{\\\\mathcal{T}_{\\\\infty}}}\\\\end{array}$ when $r^{*}=1{\\\\mathrm{~nm}}$.", + "answer": "$$ \\\\begin{array}{l}{{\\\\dot{N}=A\\\\exp\\\\Bigl(-\\\\frac{\\\\Delta G^{*}}{{\\\\dot{k}}T}\\\\Bigr)\\\\exp\\\\Bigl\\\\{-\\\\frac{Q}{k t}\\\\Bigr\\\\}}}\\\\ {{{}}}\\\\ {{=10^{35}\\\\times10^{-2}\\\\times\\\\exp\\\\Bigl(-\\\\frac{16\\\\pi\\\\sigma^{3}}{3\\\\Delta G_{v}^{2}k T}\\\\Bigr)}}\\\\ {{{}}}\\\\ {{=10^{33}\\\\times\\\\exp\\\\Bigl(-\\\\frac{16\\\\pi\\\\sigma^{3}T_{\\\\mathrm{a}}^{2}V^{2}}{3k T\\\\Delta{\\\\dot{H}}^{2}\\\\Delta{\\\\dot{T}}^{2}}\\\\Bigr)}}\\\\end{array}$$ $\\\\textcircled{1}$ \\n\\nWhen $\\\\Delta T=20\\\\mathrm{~C~}$: $$ {\\\\dot{N}}{=}10^{33}\\\\exp\\\\Bigl[{-\\\\frac{16\\\\times3.14\\\\times(2\\\\times10^{-5})^{3}\\\\times1000^{2}\\\\times6^{2}}{3\\\\times1.38\\\\times10^{-23}\\\\times800\\\\times12600^{2}\\\\times200^{2}}}\\\\Bigr]$$ $\\\\textcircled{2}$ When $\\\\theta=60^{\\\\circ}$: The heterogeneous nucleation free energy $$ \\\\Delta G_{\\\\mathrm{in}}^{*}=\\\\Delta G^{*}\\\\ \\\\Bigl(\\\\frac{2-3\\\\mathrm{cos}60^{\\\\circ}+\\\\mathrm{cos}^{3}60^{\\\\circ}}{4}\\\\Bigr)=0.156\\\\Delta G^{*}.$$ When $\\\\Delta T{=}20\\\\mathrm{~C~}$, $\\\\dot{N}=10^{33}\\\\exp(-0.156\\\\times5615,8)=0$. When $\\\\Delta{\\\\cal T}{=}200\\\\Upsilon$, $\\\\dot{N}{=}10^{33}\\\\exp(-0.156\\\\times68.79){=}2.2\\\\times10^{28}\\\\left({\\\\mathrm{cm}}^{-3}{\\\\mathrm{s}}^{-1}\\\\right)$. Assuming undercooling is $\\\\Delta T,T{=}T_{\\\\infty}{-}\\\\Delta T$, according to the given conditions: $$ 1=10^{33}\\\\exp\\\\Bigl(-\\\\frac{16\\\\times3.14\\\\times200^{3}\\\\times1000^{2}\\\\times6^{2}}{3\\\\times1.38\\\\times10^{-16}\\\\times(12600\\\\times10^{7})^{2}(1000-\\\\Delta T)\\\\Delta T^{2}}\\\\times0.156\\\\Bigr)$$ or $$ 10^{-33}=\\\\exp\\\\Bigl(-\\\\frac{3.43\\\\times10^{8}}{(1000-\\\\Delta T)\\\\Delta T^{2}}\\\\Bigr)$$ Taking the logarithm of both sides: $$ 75.98={\\\\frac{3.43\\\\times10^{8}}{(1000-\\\\Delta T)\\\\Delta T^{2}}}$$ $$ (1000-\\\\Delta T)\\\\Delta T^{\\\\circ}=4.51\\\\times10^{6}$$ Thus: $$ \\\\Delta T\\\\approx70^{\\\\circ}C$$ $\\\\textcircled{3}$ $$ r^{\\\\bullet}=\\\\frac{2\\\\sigma}{\\\\Delta G}=\\\\frac{2\\\\sigma T_{\\\\mathrm{m}}V}{\\\\Delta H\\\\Delta T}$$ $$ {\\\\frac{\\\\Delta\\\\mathrm{T}}{\\\\mathrm{T}_{\\\\mathrm{m}}}}={\\\\frac{2\\\\sigma V}{\\\\Delta H r^{\\\\ast}}}$$ When $r^{*}=1\\\\mathrm{nm}$: $$ \\\\frac{\\\\Delta T}{T_{\\\\mathrm{m}}}=\\\\frac{2\\\\times200\\\\times6}{12600\\\\times10^{7}\\\\times1\\\\times10^{-7}}=0.19$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算均匀成核速率、非均匀成核速率的变化以及推导临界半径与过冷度之间的关系，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用公式进行计算和分析，包括均质形核率、异质形核率的变化以及临界半径与过冷度的关系推导。虽然不涉及复杂的机理解释或创新设计，但需要较高的综合分析能力。 | 难度: 在选择题中属于高难度题目，需要处理复杂的多变量计算和综合分析。题目涉及多个步骤的计算，包括临界成核功、界面能、熔化热等参数的运用，以及在不同条件下的比较分析（如均质成核与非均质成核的对比）。此外，还需要推导关系式并进行数值计算，对学生的综合应用能力和数学处理能力要求较高。" + }, + { + "idx": 2781, + "question": "Calculate the diffusion coefficient D of carbon in γ-Fe. Given the diffusion coefficient of carbon in γ-Fe D₀=2.0×10⁻⁵ m²/s, activation energy Q=142 kJ/mol, and temperature T=1000℃.", + "answer": "D=D₀e^(−Q/RT)=2.0×10⁻⁵×exp(−142000/(8.314×1273))=2.98×10⁻¹¹ m²/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数D的具体数值。答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目要求直接应用扩散系数的计算公式，涉及基本的数值计算和公式套用，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用扩散系数的阿伦尼乌斯公式，但题目已经提供了所有必要的参数（D₀、Q、T），且计算过程仅涉及基本代数运算和指数函数的应用。不需要额外的推导或复杂转换，属于直接套用公式即可解决的题目。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2782, + "question": "Approximately consider (number of carbon atoms + number of iron atoms) ≈ number of iron atoms, calculate the rate of change of carbon atom number Δρ/Δx at a distance of 1∼2mm from the steel surface.", + "answer": "Δρ/Δx=(5%−4%)×(8.23×10^22)/(1−2)×10^6×10^3=−8.23×10^29 at/m⁴", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算结果和单位，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（碳原子浓度变化率计算），涉及浓度梯度的理解和公式应用，需要将材料科学中的扩散理论与具体数值计算相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，要求考生能够综合运用材料科学中的扩散理论和浓度梯度知识。虽然题目提供了近似条件简化计算，但仍需正确理解和应用这些条件，并进行适当的单位转换和数学运算。这种题目在选择题型中属于需要一定综合分析能力的类型，但相比更复杂的多变量计算问题，其难度适中。" + }, + { + "idx": 2783, + "question": "Given a diffusion couple composed of pure chromium and pure iron, after 1 hour of diffusion, the Matano plane moved by 1.52×10^(-3) cm. It is known that the ratio of the square of the distance moved by the Matano plane to the diffusion time is a constant. Determine the moving speed of the Matano plane.", + "answer": "According to the given conditions: x²/t = k, the moving speed of the Matano plane vₐ = dx/dt = k/(2x) = x/(2t) = (1.52×10^(-3))/(2×3600) cm/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程涉及数学运算和物理公式的使用，最终给出具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的条件和公式直接计算Matano平面的移动速度，不需要多步计算或复杂的概念关联。 | 难度: 在选择题中属于简单公式应用计算难度，题目要求直接套用给定的公式x²/t = k，并通过简单的代数变换和数值代入计算出Matano平面的移动速度。解题步骤清晰且直接，不需要复杂的推理或多步骤计算，符合等级2的标准。" + }, + { + "idx": 2785, + "question": "There is a silicon single crystal wafer with a thickness of 0.5 mm. On one end face, every 10^7 silicon atoms contain two atoms, while the other end face has an increased concentration of gallium after treatment. Determine how many gallium atoms per 10^7 silicon atoms are required on this face to achieve a concentration gradient of 2×10^26 atoms/m³·m. The lattice constant of silicon is 0.5407 nm.", + "answer": "Silicon has a diamond structure, with 8 atoms per unit cell. Therefore, the volume corresponding to 10^7 atoms is: V = (10^7 / 8) × a₀³ = (10^7 / 8) × (0.5407 × 10^-9)^3 = 1.976 × 10^-22 m³. Let x be the number of gallium atoms per 10^7 silicon atoms on this end face. Then: Δρ/Δx = [(x / V) - (2 / V)] / (0.5 × 10^-3) = 2 × 10^26. x = 2 + 0.5 × 10^-3 × 2 × 10^26 × 1.976 × 10^-22 = 21.76 ≈ 22. Thus, this end face must contain 22 gallium atoms per 10^7 silicon atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算体积、浓度梯度等，最终得出具体的数值答案。解答过程涉及多个步骤的数学运算和物理概念的应用。 | 知识层次: 题目需要进行多步计算，包括单位晶胞体积的计算、浓度梯度的计算以及最终求解所需的镓原子数量。虽然涉及基础概念如晶体结构和浓度梯度，但需要将这些概念关联起来进行综合分析，并应用公式进行数值计算。思维过程要求一定的深度和逻辑性，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解硅的晶体结构、浓度梯度概念，并进行多步计算。虽然题目提供了部分计算步骤，但仍需要综合应用多个知识点（如单位晶胞计算、浓度梯度公式转换）才能得出正确答案。相比简单概念题或单步计算题，该题的复杂度和综合分析要求更高，但尚未达到复杂多变量计算的难度。" + }, + { + "idx": 2786, + "question": "A carbon steel with w(C)=0.1% is carburized at 930°C, reaching a carbon concentration of 0.45% at a depth of 0.05cm. For all times t>0, the carburizing atmosphere maintains a surface composition of 1%. Assuming D=0.2×10^(-5) exp(-140000/RT)(m²/s), calculate the carburizing time.", + "answer": "From Fick's second law, the solution is w=w_s-(w_s-w_0)erf(x/(2√(Dt))). Substituting the data gives (1%-0.45%)/(1%-0.1%)=erf(0.05/(2√(Dt))), i.e., 0.61=erf(0.05/(2√(Dt))). Looking up the table yields 0.05/(2√(Dt))=0.61, and D=0.2×exp(-140000/(8.314×1203))=1.67×10^(-7)(cm²/s). Therefore, the carburizing time t≈1.0×10^3(s).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及Fick第二定律的解析解和误差函数的使用，最终需要计算出具体的渗碳时间。答案中包含了详细的数学推导和数值代入过程，符合计算题的特征。 | 知识层次: 题目需要应用Fick第二定律进行多步计算，包括查表、数值代入和单位转换等操作，涉及扩散系数的计算和误差函数的应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要综合运用菲克第二定律、误差函数查表、温度换算和扩散系数计算等多个步骤。虽然题目提供了关键公式和数据，但解题过程涉及多个概念关联和计算环节，包括查表换算和单位转换，对学生的综合分析能力有一定要求。" + }, + { + "idx": 2787, + "question": "If w(C)=0.3% is specified as the measure of carburization layer thickness, how many times is the carburization layer thickness after 10h at 930°C compared to that after 10h at 870°C?", + "answer": "x₉₃₀/x₈₇₀=√(D₉₃₀t₉₃₀)/√(D₈₇₀t₈₇₀). Since t₉₃₀=t₈₇₀, D₉₃₀=1.67×10^(-7)(cm²/s), D₈₇₀=0.2×exp(-140000/(8.314×1143))=8.0×10^(-8)(cm²/s). Therefore, x₉₃₀/x₈₇₀=√(D₉₃₀)/√(D₈₇₀)=√(1.6×10^(-7)/7.9×10^(-8))=1.45.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散系数和时间的平方根关系，最终得出一个具体的数值结果。答案中展示了详细的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括扩散系数的计算和比较，以及应用扩散定律公式。虽然不涉及复杂的综合分析或创新应用，但需要理解扩散过程的基本原理并进行数值计算，属于中等难度的应用题目。 | 难度: 在选择题中属于中等难度，需要理解扩散系数与温度的关系，并进行多步计算和综合分析。题目涉及多个概念（如扩散系数、时间、温度）的关联，且需要正确应用公式进行计算。虽然题目提供了部分数据，但仍需考生具备一定的综合分析能力来推导最终答案。" + }, + { + "idx": 2788, + "question": "Given the initial carbon concentration of plain carbon steel w0=0.85%, after heating to 900°C and holding in air for 1h, the outer carbon concentration drops to zero. If the required carbon concentration in the outer layer of the part is 0.8%, how much depth should be turned off the surface? (D=1.1×10−7cm2/s)", + "answer": "From w=w0erf(β), we get 0.80=0.85erf(x/(2√Dt)) → erf(x/(2√Dt))=0.94. Checking the error function table gives x/(2√Dt)=1.33. Calculating √Dt=√(1.1×10−7×3600)=0.0199 cm. Solving for x gives x=1.33×2×0.0199=0.053 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及碳浓度的变化和误差函数的查表计算，最终需要求解深度x的值。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算（误差函数表查询、扩散方程应用、数值计算）和概念关联（扩散系数与时间的关系），需要综合分析能力，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程和误差函数的概念，进行多步骤计算，并查阅误差函数表获取关键参数。虽然题目提供了公式和计算步骤，但需要综合应用多个知识点才能正确解答。" + }, + { + "idx": 2789, + "question": "Derive the solution to the decarburization diffusion equation, assuming that at t>0, ρ=0 at x=0. The initial conditions are known as t=0, x≥0, ρ=ρ0; boundary conditions are t>0, x=0, ρ=0; x=∞, ρ=ρ0.", + "answer": "From Fick's second law, the general solution is obtained (assuming D is independent of ρ): ρ=A1∫0βexp(−β2)dβ+A2. Initial condition t=0, x≥0, ρ=ρ0, β=x/(2√Dt). Boundary condition t>0, x=0, ρ=0 → 0=A1∫0βexp(−β2)dβ+A2 → A2=0. Combined equation: ρ0=A1√π/2+A2 → A1=2ρ0/√π. Substituting into the general solution: ρ=2ρ0/√π∫0βexp(−β2)dβ=ρ0erf(β). Dividing by the alloy density gives w=w0erf(β).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导脱碳扩散方程的解，涉及数学推导和公式应用，需要根据初始条件和边界条件进行计算和推导，最终得出解析解。答案展示了详细的数学推导过程，符合计算题的特征。 | 知识层次: 题目需要应用Fick第二定律进行多步推导，涉及边界条件和初始条件的处理，以及误差函数的应用。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和公式推导技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Fick第二定律的解法和边界条件的应用，并进行多步推导和综合分析。虽然题目给出了正确选项，但解题过程涉及多个步骤和概念关联，包括积分、边界条件处理和误差函数的应用，对学生的理解和计算能力要求较高。" + }, + { + "idx": 2790, + "question": "If the depth of the diffusion layer is doubled, how much time is required?", + "answer": "From the relation x=A√(Dt), we have x₁=A√(Dt₁) and x₂=A√(Dt₂). Dividing the two equations gives (x₂²)/(x₁²)=(Dt₂)/(Dt₁). When the temperature is the same, D₁=D₂, thus t₂=(x₂²)/(x₁²)×t₁=(0.1²)/(0.05²)×1.0×10^4=4.0×10^4 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案中包含了具体的计算步骤和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的扩散方程进行数值计算，无需多步推理或综合分析。 | 难度: 在选择题中属于简单公式应用计算难度。题目直接给出了相关公式x=A√(Dt)，并明确要求计算时间变化。解题步骤仅需简单套用公式并进行一次平方运算和除法计算，无需复杂的推导或多步骤分析。虽然涉及单位换算(10^4s)，但计算过程直接明了，属于基础层面的公式应用。" + }, + { + "idx": 2791, + "question": "Calculate the root mean square displacement of the total migration of carbon atoms $\\\\sqrt{\\\\overline{R_{n}^{2}}}$, given the jump frequency of carbon atoms as $\\\\Gamma=1.7\\\\times10^{9}/\\\\mathrm{s}$, the jump distance as $2.53\\\\times10^{-10}\\\\mathrm{m}$, and the time as $4\\\\mathrm{h}$.", + "answer": "$\\\\sqrt{\\\\overline{R_{n}^{2}}}=\\\\sqrt{n}\\\\cdot r=\\\\sqrt{1.7\\\\times10^{9}\\\\times4\\\\times3600}\\\\times2.53\\\\times10^{-10}=1.25\\\\times10^{-3}\\\\mathrm{m}\\\\approx1.3\\\\mathrm{mm}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和参数来求解碳原子的均方根位移。答案是通过具体的数学计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括时间单位转换、根均方位移公式的应用以及数值计算，涉及对扩散理论的理解和公式的综合运用，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散理论中的均方位移概念，并正确应用公式进行多步计算。题目涉及单位换算（小时转秒）、平方根运算以及科学计数法的处理，虽然计算步骤明确但容易在细节上出错。相比单纯的概念题或单步计算题更具挑战性，但尚未达到需要处理复杂变量或高级数学工具的等级4难度。" + }, + { + "idx": 2792, + "question": "Given a diffusion couple composed of pure chromium and pure iron, it is known that when the mole fraction x_Cr=0.478, ∂x/∂z=126/cm, and the interdiffusion coefficient D=1.43×10^(-8) m²/s, find the intrinsic diffusion coefficients D_Cr and D_Fe of chromium and iron.", + "answer": "According to the Kirkendall effect, the marker velocity vₐ = (D_Cr - D_Fe)×126. The interdiffusion coefficient D = x_Fe D_Cr + x_Cr D_Fe → 0.478 D_Fe + (1-0.478) D_Cr = 1.43×10^(-8) m²/s. By solving these two equations together with the marker velocity vₐ at the Matano plane, we obtain D_Cr = 2.23×10^(-9) cm²/s and D_Fe = 0.56×10^(-9) cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铬和铁的本征扩散系数D_Cr和D_Fe，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用Kirkendall效应和扩散系数的相关公式，进行多步计算和概念关联，包括解方程组和数值计算，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于高难度，需要理解Kirkendall效应、Matano平面、扩散系数等多个概念，并进行多步计算和综合分析。题目涉及多个变量和方程联立求解，计算过程复杂，对知识点的掌握深度和解题能力要求较高。" + }, + { + "idx": 2793, + "question": "For pure iron carburized at $950\\\\mathrm{\\\\textperthousand}$, it is desired to achieve a carbon content of $\\\\mathfrak{w}{1}\\\\left(\\\\mathbb{C}\\\\right)=0,9\\\\%$ at a depth of $0.1\\\\mathrm{mm}$. Assuming the surface carbon content remains at $w{2}\\\\left(\\\\mathsf{C}\\\\right)=1.20\\\\%$, and the diffusion coefficient $D_{\\\\mathtt{Y F e}}{=}10^{{-}10}\\\\ensuremath{\\\\mathbf{m}}^{2}/\\\\mathbf{s},$, calculate the minimum carburization time required to meet this requirement.", + "answer": "$$\\\\begin{array}{c}{\\\\frac x{2\\\\sqrt{D t}}=0,8163}}\\\\ {{{\\\\mathrm x}=2\\\\times0.8163\\\\times\\\\sqrt{1.1\\\\times10^{-1}\\\\times3600}}}\\\\ {{{\\\\mathrm x}=0.032\\\\mathrm{(cm)}}}\\\\ {{{\\\\mathrm w}_{2}-{\\\\mathrm w}_{1}=\\\\mathrm{erf}\\\\left({\\\\frac{x}{2\\\\sqrt{D t}}}\\\\right)}}\\\\ {{{\\\\mathrm x}_{2}-{\\\\mathrm w}_{0}=\\\\mathrm{erf}\\\\left({\\\\frac{0.1\\\\times10^{-3}}{2\\\\sqrt{10^{-10}\\\\times t}}}\\\\right)}}\\\\end{array}$$ $$\\\\operatorname{erf}{\\\\Big(}{\\\\frac{5}{\\\\sqrt{t}}}{\\\\Big)}=0.25$$ Look up the table to find $$\\\\frac{5}{\\\\sqrt{t}}\\\\approx0.2763,$$ hence $$t\\\\approx327(\\\\mathrm{s})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小渗碳时间，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和误差函数表进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程和误差函数的概念，并进行多步骤计算。题目涉及查找表格数据和解方程，但整体计算过程在选择题型内相对可控，属于综合性计算问题。" + }, + { + "idx": 2794, + "question": "There are two diffusion reactions with activation energies of Q_1=83.7 kJ/mol and Q_2=251 kJ/mol, respectively. Observe the effect of increasing the temperature from 25°C to 600°C on the diffusion with an activation energy of Q_2=251 kJ/mol, and comment on the results.", + "answer": "From D=D_0 exp(-Q/RT), we get D_873/D_298=exp[-251000/(8.314)×(298-873)/(873×298)]=9.5×10^28. For the temperature increase from 298K to 873K, the diffusion rate D increases by 9.5×10^28 times, showing that the higher the activation energy, the more sensitive the diffusion rate is to temperature.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算扩散速率的变化，并给出具体的数值结果。答案中使用了扩散公式D=D_0 exp(-Q/RT)进行计算，并得出了具体的倍数变化（9.5×10^28 times），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算（温度转换、扩散系数公式应用、指数运算），并理解激活能与温度敏感性的关系，属于中等应用层次。虽然计算过程明确，但需要将概念与计算结果关联分析。 | 难度: 在选择题中属于中等难度，需要理解扩散速率与温度的关系，并应用阿伦尼乌斯公式进行多步骤计算。题目要求分析高活化能下温度变化对扩散速率的影响，涉及指数计算和单位转换，但不需要处理复杂多变量或高级数学工具。" + }, + { + "idx": 2795, + "question": "Determine whether the formula D=D0exp(-Q/RT) is applicable to the diffusion coefficient data of carbon in α-Ti; if applicable, calculate the diffusion constant D0 and activation energy Q", + "answer": "By plotting D against temperature (converted to absolute temperature), it was found that lgD has a linear relationship with 1/T, thus satisfying the formula D=D0exp(-Q/RT). The slope is Q/(2.3R), and the calculated Q=2.3×R×0.92×10^4=175.9 kJ/mol. For T=1009 K (736℃), D736=2×10^-13 m^2/s. Substituting into the formula gives lgD0=lgD+Q/(2.3R)×1/T=lg(2×10^-13)+175900/(2.3×8.314×1009)≈-3.58, therefore D0=2.62×10^-4 m^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求应用公式D=D0exp(-Q/RT)进行数值计算，包括确定扩散常数D0和激活能Q，并通过绘制数据和数学推导得出结果。答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的公式进行多步计算，包括线性回归分析、斜率计算、激活能求解以及对数转换等步骤。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点和计算技巧，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数的温度依赖性公式（D=D0exp(-Q/RT)），掌握对数转换和线性关系分析（lgD与1/T的关系），能够正确提取斜率信息计算活化能Q（涉及单位换算和常数处理），并通过特定温度点的数据反推扩散常数D0（需要熟练运用对数运算和科学计数法）。整个过程涉及多步计算和概念关联，但题目提供了明确的计算路径，降低了部分难度。" + }, + { + "idx": 2796, + "question": "Calculate the diffusion activation energy Q1 of polycrystalline silver at 700°C (based on the given data).", + "answer": "From the equation -10.72-(-12) = -Q_1/R (1.10×10^-3 -1.30×10^-3) lge, the solution gives Q_1 = 122.4 kJ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出扩散激活能Q1的具体数值。答案展示了计算过程和最终结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散激活能的计算公式，并进行多步计算和单位转换，涉及对Arrhenius方程的理解和运用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散激活能的概念，掌握阿伦尼乌斯方程的应用，并能正确进行多步数学运算（包括对数运算和单位转换）。题目涉及温度转换（700°C需转为绝对温度）、方程变形和综合计算能力，但作为选择题，正确答案已经给出了关键计算步骤，降低了部分难度。" + }, + { + "idx": 2797, + "question": "Calculate the diffusion coefficient of carbon in α-Ti at 500℃", + "answer": "Using the formula lgD500=lgD0-Q/(2.3×R)×1/T=lg(2.62×10^-4)-175.9×10^3/(2.3×8.314×773)=-3.58-11.90=-15.48, thus D500≈3.31×10^-16 m^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算碳在α-Ti中的扩散系数，答案涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的计算公式，涉及多步计算（包括对数运算和单位转换），并且需要理解温度对扩散系数的影响以及相关参数的物理意义。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数的计算公式，掌握对数运算和单位转换，并能正确代入温度、活化能等参数进行多步计算。虽然题目提供了公式和部分参数，但仍需要较强的综合分析能力和计算准确性才能得出正确结果。" + }, + { + "idx": 2798, + "question": "Calculate the total migration distance $S$ of carbon atoms, given the carbon atom jump frequency as $\\Gamma=1.7\\times10^{9}/\\mathrm{s}$, jump distance as $2.53\\times10^{-10}\\mathrm{m}$, and time as $4\\mathrm{h}$.", + "answer": "$4\\mathrm{h}=4\\times3600\\mathrm{s}$, $S=\\Gamma \\cdot t \\cdot r=1.7\\times10^{9}\\times4\\times3600\\times2.53\\times10^{-10}=6193\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及单位转换和乘法运算，最终给出具体的计算结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即利用给定的参数（跳频、跳跃距离和时间）通过公式计算迁移距离。虽然需要单位转换，但整体思维过程较为直接，不涉及多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，解题步骤简单，仅涉及基本公式应用和简单计算，无需多个公式组合或复杂分析，因此属于最低难度等级。" + }, + { + "idx": 2799, + "question": "Calculate the total migration distance S of carbon atoms at 20%, given the transition frequency r=2.1×10^-9/s, transition step length of 2.53×10^-10m, and time of 4h.", + "answer": "S=Γ·t·r=2.1×10^-9×4×3600×2.53×10^-10=7.65×10^-15m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和参数来求解碳原子的总迁移距离。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需将给定的数值代入公式进行计算即可。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算（S=Γ·t·r），无需理解多个概念或进行复杂步骤。题目明确给出了所有必要参数，且计算过程简单，属于最基础的公式应用层级。" + }, + { + "idx": 2800, + "question": "Indicate approximately in which temperature range grain boundary diffusion dominates.", + "answer": "In the low-temperature region (when 1/T is large), the lnD value of grain boundary diffusion is higher than that of bulk diffusion, and grain boundary diffusion dominates at this time. As the temperature increases (1/T decreases), the two curves will intersect, and in the high-temperature region above the intersection point, bulk diffusion will dominate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在哪个温度范围内晶界扩散占主导地位，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释晶界扩散在特定温度范围内占主导的原因，涉及对扩散机制的理解和温度对扩散行为的影响分析。需要将晶界扩散和体扩散的概念关联起来，并通过温度变化对扩散系数的影响进行综合分析。虽然不涉及复杂计算，但需要一定的概念关联和推理分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握晶界扩散和体扩散的基本概念，并能分析温度变化对两种扩散机制的影响。虽然不需要复杂的计算，但需要对扩散机制在不同温度区间的相对优势进行综合判断，涉及概念关联和综合分析能力。" + }, + { + "idx": 2801, + "question": "Calculate the root mean square displacement $\\sqrt{\\overline{R_{n}^{2}}}$ of carbon atoms at $20\\%$, given the transition frequency is $r=2.1\\times10^{-9}/\\mathrm{s}$, the transition step length is $2.53\\times10^{-10}\\mathrm{m}$, and the time is $4\\mathrm{h}$.", + "answer": "$\\sqrt{\\overline{R_{n}^{2}}}=\\sqrt{n}\\cdot r=\\sqrt{2.1\\times10^{-9}\\times4\\times3600}\\times2.53\\times10^{-10}=1.39\\times10^{-12}\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和参数来求解碳原子的均方根位移，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括时间单位的转换、频率与步长的综合应用，以及根均方位移公式的运用。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散理论中的根均方位移概念，并正确应用公式进行多步骤计算。题目涉及时间单位转换、频率与步长的综合运用，以及平方根运算，但选项提供了明确的解题路径，减少了分析复杂度。" + }, + { + "idx": 2802, + "question": "Calculate the diffusion activation energy Q2 for single-crystal silver (based on the given data).", + "answer": "From equation 8-14 = -Q_2/R lge (0.8×10^-3 -1.39×10^-3), we obtain Q_2 = 194.5 kJ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出扩散激活能Q2的具体数值，符合计算题的特征。 | 知识层次: 题目要求基于给定数据进行扩散激活能的计算，涉及公式应用和多步计算，需要理解扩散激活能的概念并正确运用相关公式进行推导和计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散激活能的概念，掌握对数运算和单位转换，并能正确应用给定的公式进行多步骤计算。虽然题目提供了具体公式和数据，但解题过程涉及多个计算步骤和概念关联，对学生的综合分析能力有一定要求。" + }, + { + "idx": 2803, + "question": "For grain boundary diffusion and bulk diffusion, assuming the diffusion activation energy Q_AF≈1/2 Q_AF, plot the curve of InD versus the reciprocal of temperature 1/T.", + "answer": "According to the Arrhenius equation D = D_0 exp(-Q/RT), taking the logarithm gives lnD = lnD_0 - Q/(RT). For grain boundary diffusion (Q_gb) and bulk diffusion (Q_bulk), when Q_gb ≈ 1/2 Q_bulk, both lnD vs 1/T curves are straight lines, with the grain boundary diffusion line having a smaller slope.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，涉及对扩散激活能和温度关系的描述，并需要绘制曲线图，属于需要详细解释和论述的简答题类型。 | 知识层次: 题目需要应用Arrhenius方程进行对数变换，并理解晶界扩散和体扩散激活能的关系，通过斜率差异绘制曲线。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解阿伦尼乌斯方程及其对数形式，同时能够比较晶界扩散和体扩散的活化能关系，并分析其对lnD与1/T曲线斜率的影响。虽然涉及多步计算和概念关联，但在选择题型中通过选项可以辅助判断，不需要进行深度论述。" + }, + { + "idx": 2804, + "question": "Introducing high-valence W6+ into NiO will generate vacancies of which ions?", + "answer": "Vacancies of cations (Ni) will be generated. (Principle of electroneutrality)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释引入高价位W6+对NiO中离子空位的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解电中性原理并应用到具体材料体系中，涉及多价态离子掺杂对缺陷类型的影响分析，属于概念关联和中等复杂度的应用分析。 | 难度: 在选择题中属于中等难度，需要理解电中性原则和离子价态变化对缺陷形成的影响，并进行综合分析。题目要求考生将高价位W6+引入NiO的概念与阳离子空位生成联系起来，这需要多步概念关联和中等程度的综合分析能力。" + }, + { + "idx": 2806, + "question": "In NiO, introducing high-valence W6+, how many vacancies will each W6+ generate?", + "answer": "Each W6+ introduction generates 2 Ni2+ vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释高价位W6+引入NiO中会产生多少个空位，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解高价位掺杂对NiO中空位形成的影响，涉及电荷平衡和缺陷化学的基本原理，需要进行多步推理和计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解NiO中掺杂高价态W6+的电荷补偿机制，并能够正确计算生成的Ni2+空位数量。题目涉及多步计算和概念关联，但选项已经给出了明确的计算结果，降低了部分难度。" + }, + { + "idx": 2807, + "question": "Explain why the diffusion activation energy of polycrystals is lower than that of single crystals.", + "answer": "Polycrystals have grain boundaries, and the 'short-circuit' diffusion effect of grain boundaries increases the diffusion rate, thus resulting in a lower diffusion activation energy. The diffusion in single crystals is purely bulk diffusion, which has a higher activation energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶体的扩散激活能低于单晶体的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释多晶和单晶扩散激活能差异的机理，涉及对晶界扩散效应的理解和综合分析，属于对材料科学中扩散机制的深入分析和解释。 | 难度: 在选择题型内，该题目属于机理深度解释难度。题目要求考生不仅理解扩散激活能的基本概念，还需要掌握多晶体和单晶体在扩散机制上的差异，特别是晶界“短路”扩散效应的原理。这需要考生具备较高的知识综合运用能力和机理解释能力，能够将多个知识点联系起来进行推理分析。虽然题目提供了正确选项，但选项本身包含了较为复杂的机理描述，对考生的理解深度有较高要求。" + }, + { + "idx": 2808, + "question": "Compare the oxidation resistance of NiO and W-doped NiO (i.e., NiO-WO3), which one is better?", + "answer": "Due to the introduction of W, the vacancy concentration increases, making it easier for oxygen in the air and Ni2+ ions in the oxide to migrate in and out of the surface, thereby increasing the oxidation rate. As a result, the oxidation resistance is reduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较NiO和W-doped NiO的氧化抗性，并解释哪一种更好。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较NiO和W掺杂NiO的氧化抗性，并解释其机理。这需要理解掺杂对材料性能的影响，分析空位浓度变化对氧化速率的作用机制，涉及多个概念的关联和综合运用。思维过程需要推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解NiO和W-doped NiO的基本性质，还需要掌握掺杂对材料氧化抗性的影响机制。正确选项涉及复杂的材料科学原理，包括空位浓度变化、离子迁移性以及氧化速率的关系。考生需要综合运用材料化学和缺陷化学知识进行推理分析，并解释掺杂引入的W如何通过改变材料微观结构来影响宏观性能。这种需要多维度知识整合和机理深度解释的题目，在选择题型中属于最高难度级别。" + }, + { + "idx": 2809, + "question": "The yield strength of the Mg alloy is 180MPa, and E is 45GPa. Under the maximum load, what is the elongation per mm of this magnesium plate?", + "answer": "ε=σ/E=180×10^6/45×10^9=0.004", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（σ=Eε）来求解伸长率，答案是一个具体的计算结果。 | 知识层次: 题目仅涉及基本公式（胡克定律）的直接应用和简单数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（ε=σ/E）进行计算，无需额外的步骤或复杂的分析。题目要求的知识点掌握深度较浅，解题步骤简单明了，属于最基础的难度等级。" + }, + { + "idx": 2810, + "question": "Explain the reason for the difference in diffusion coefficients between Al and O in Al2O3.", + "answer": "Because in Al2O3, the ionic radius of the cation Al is smaller than that of the anion O, the activation energy for Al diffusion in Al2O3 is lower than that for O diffusion in Al2O3. Therefore, the diffusion coefficient of the former is greater than that of the latter.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al和O在Al2O3中扩散系数差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Al和O在Al2O3中扩散系数差异的原因，涉及离子半径、活化能等概念的关联和综合分析，需要深入理解扩散机制并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2811, + "question": "Given the diffusion coefficient of O in Al2O3, D0(O) = 0.19 m^2/s, and the activation energy Q = 636 kJ/mol, calculate its diffusion coefficient D at a temperature of 2000 K.", + "answer": "D = D0 * exp(-Q / (R * T)) = 0.19 * exp(-636000 / (8.314 * 2000)) = 4.7×10^-18 m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的扩散系数和激活能计算特定温度下的扩散系数，需要使用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及基本公式的套用和数值计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一扩散系数公式D = D0 * exp(-Q / (R * T))，并进行简单的数值计算。无需组合多个公式或进行复杂推导，属于最基础的公式应用层级，因此属于等级1难度。" + }, + { + "idx": 2812, + "question": "Given the diffusion coefficient of Al in Al2O3, D0(Al) = 2.8×10^-3 m^2/s, and the activation energy Q = 477 kJ/mol, calculate its diffusion coefficient D at a temperature of 2000 K.", + "answer": "D = D0 * exp(-Q / (R * T)) = 2.8×10^-3 * exp(-477000 / (8.314 * 2000)) = 9.7×10^-16 m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式（D = D0 * exp(-Q / (R * T))）来求解扩散系数D，答案是一个具体的计算结果（9.7×10^-16 m^2/s）。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及扩散系数的计算，需要直接套用给定的公式和参数进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的扩散系数公式进行计算，无需额外的概念理解或复杂的解题步骤。题目提供了所有必要的参数（D0, Q, R, T），只需将这些数值代入公式即可得出答案。因此，该题目属于单一公式直接计算的难度等级。" + }, + { + "idx": 2813, + "question": "The yield strength of Mg alloy is 180MPa, E is 45GPa, find the maximum load that will not cause plastic deformation of a 10mm×2mm Mg plate.", + "answer": "F=σA=180×10^6×10×2×10^-6=3600(N)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算最大负载），并应用了公式（F=σA），答案是一个具体的数值结果（3600N），符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用（F=σA）和简单计算，不需要多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（F=σA）进行计算，无需理解多个概念或进行复杂分析。解题步骤简单，仅涉及基本单位换算和乘法运算，属于最基础的难度等级。" + }, + { + "idx": 2814, + "question": "A nickel-based alloy sample with a cross-section of 10mm×10mm and a length of 40mm was subjected to a tensile test, and the results are shown in the table below. Calculate its yield strength σ0.2.", + "answer": "σ0.2 can be obtained from the stress-strain curve of the tensile test, which is 1000 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出镍基合金的屈服强度σ0.2，需要应用材料力学中的应力-应变关系和相关公式进行计算。答案给出了具体的数值结果（1000 MPa），这表明解答过程涉及数值计算而非简单的选择或判断。 | 知识层次: 题目要求根据拉伸试验结果计算屈服强度σ0.2，这属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（σ0.2的定义）并读取给定数据（1000 MPa），无需额外计算或复杂步骤。属于单一公式直接应用的简单题型。" + }, + { + "idx": 2815, + "question": "A Gu–30%Zn brass plate is cold rolled by 25%, reducing its thickness to 1 cm. Subsequently, the plate is further reduced to a thickness of 0.6 cm. Calculate the total cold deformation degree.", + "answer": "Cold deformation degree = (A0 - AF) / A0 × 100%, 25% = (h w - 1 w) / (h w) × 100%, h = 4/3 cm. Total deformation degree = (4/3 w - 0.6 w) / (4/3 w) × 100% = 55%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解总冷变形程度，答案涉及具体的数学运算和百分比计算。 | 知识层次: 题目需要进行多步计算，包括初始厚度的推导和总变形程度的计算，涉及公式的应用和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解冷变形度的计算公式，并进行多步计算。题目涉及初始厚度计算、两次变形后的总变形度计算，需要综合应用材料科学中的变形概念和数学计算能力。虽然题目提供了部分计算步骤，但考生仍需正确理解并应用公式才能得出最终答案。" + }, + { + "idx": 2816, + "question": "Analyze the effect of polymer molecular weight on the viscous flow temperature", + "answer": "When the molecular weight is smaller, the internal frictional resistance between molecular chains is reduced, making the relative movement of molecular chains easier, thus lowering the viscous flow temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求分析聚合物分子量对粘流温度的影响，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目要求分析聚合物分子量对粘流温度的影响，涉及分子链间摩擦阻力和相对运动的机理解释，需要理解分子量与粘流温度之间的关系，并进行综合分析。虽然不涉及复杂计算，但需要对概念进行关联和推理分析。 | 难度: 在选择题中属于中等难度，需要理解聚合物分子量对粘流温度的影响机制，涉及分子链间内摩擦阻力和相对运动的概念关联，但不需要多角度或深度关联性分析。" + }, + { + "idx": 2817, + "question": "What are the changes in properties of a Gu–30%Zn brass sheet after cold rolling?", + "answer": "After cold rolling, the strength and hardness of the brass sheet increase, while plasticity and toughness decrease, which is the phenomenon of work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷轧后黄铜板材性能的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷轧后黄铜板材性能的变化，涉及多个性能指标（强度、硬度、塑性、韧性）的综合分析，需要理解冷加工对材料性能的影响机制（加工硬化现象），属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解冷轧对黄铜板材性能的影响，包括强度、硬度、塑性和韧性的变化，并关联到加工硬化现象。虽然不需要多步计算，但需要对材料科学中的基本概念有较好的掌握，并能综合分析不同性能指标的变化趋势。" + }, + { + "idx": 2818, + "question": "There is an aluminum wire with a length of 5 m and a diameter of 3 mm. Given that the elastic modulus of aluminum is 70 GPa, find the total length of the wire under a tensile force of 200 N.", + "answer": "Within the elastic range, stress and strain obey Hooke's law ${\\pmb\\sigma}{=}{\\pmb E}{\\pmb\\varepsilon}$, and $\\mathsf{e}=\\frac{\\boldsymbol{\\ell}-\\boldsymbol{l}_{0}}{\\boldsymbol{l}_{0}}{=}\\frac{\\frac{\\boldsymbol{F}}{A}}{E}$. Therefore, $$l=l_{0}+\\frac{F}{E A}l_{\\circ}=l_{0}\\left(1+\\frac{F}{E A}\\right)=5\\left[1+\\frac{200}{70\\times10^{3}\\times\\frac{\\pi}{4}(3\\times10^{-3})^{2}}\\right]$$$$=5.00202(\\mathrm{m})=5002.02(\\mathrm{mm})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝线在拉伸力作用下的总长度，答案中包含了具体的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目主要考查Hooke's law的基本公式应用和简单计算，涉及弹性模量、应力和应变的基本概念，计算过程直接套用公式，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目涉及弹性模量、应力应变关系等概念，但解题过程仅需直接套用Hooke's定律公式，进行简单的代数运算即可得出结果。不需要复杂的推导或多步骤计算，属于选择题中较为基础的题型。" + }, + { + "idx": 2819, + "question": "There is a nickel-based alloy specimen with a cross-section of 10mm×10mm and a length of 40mm. The tensile test results are shown in the table below. Calculate its tensile strength σb.", + "answer": "σb = 127600 / (10 × 10 × 10^-6) = 1.276 GPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镍基合金试样的拉伸强度σb，答案也是一个具体的数值计算结果。 | 知识层次: 题目仅涉及基本的拉伸强度公式应用和简单计算，无需多步推理或综合分析 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（σb = F/A）并进行简单的单位换算和计算，无需复杂的分析或多步骤推理。属于单一公式直接计算的难度等级。" + }, + { + "idx": 2820, + "question": "It is known that the porosity of sintered $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ is $5\\\\%$, and its $E=370\\\\mathrm{GPa}$. If another sintered $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ has $E=270\\\\mathrm{GPa}$, find its porosity.", + "answer": "The relationship between the $\\\\pmb{E}$ of ceramic materials and their pore volume fraction $\\\\varphi$ can be expressed by the following equation: $$E=E_{\\\\circ}(1-1.9\\\\varphi+0.9\\\\varphi^{2})$$where $E_{0}$ is the elastic modulus of the material without pores. Substituting the known conditions into the above equation, we obtain $$E_{\\\\circ}={\\\\frac{E}{1-1.9{\\\\varphi}+0.9{\\\\varphi}^{2}}}={\\\\frac{370\\\\times10^{\\\\vartheta}}{1-1.9\\\\times0.05+0.9\\\\times(0.05)^{2}}}=407.8({\\\\mathrm{GPa}})$$$$270\\\\times10^{9}=407.8\\\\times10^{9}(1-1.9\\\\varphi_{1}+0.9\\\\varphi_{1})$$Thus, $\\\\varphi_{1}=19.61\\\\%$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解孔隙率，答案展示了具体的计算过程和公式推导，符合计算题的特征。 | 知识层次: 题目需要应用给定的公式进行多步计算，涉及数值代入和求解过程，需要理解孔隙率与弹性模量之间的关系，并进行适当的数学运算。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性模量与孔隙率的关系公式，并进行多步计算。题目要求考生首先根据已知条件求解无孔隙材料的弹性模量，然后再利用该值计算新的孔隙率。虽然计算步骤较多，但公式明确且无需复杂推导，因此在选择题型内属于综合性计算问题。" + }, + { + "idx": 2821, + "question": "A nickel-based alloy specimen with a cross-section of 10mm×10mm and a length of 40mm was subjected to a tensile test, and the results are shown in the table below. Calculate its elastic modulus E.", + "answer": "E = (86200 / (10 × 10 × 10^-6)) / ((40.2 - 40) / 40) = 172.4 GPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解弹性模量E，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目要求应用基本公式（弹性模量计算公式）进行直接计算，涉及简单的数值代入和单位转换，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用弹性模量的基本公式E = (F/A) / (ΔL/L)，但解题步骤相对直接，仅涉及简单的单位转换和代数运算。不需要多个公式组合或复杂的概念分析，符合等级2的标准。" + }, + { + "idx": 2822, + "question": "A nickel-based alloy specimen with a cross-section of 10mm×10mm and a length of 40mm was subjected to a tensile test, and the results are shown in the table below. Calculate its elongation δ.", + "answer": "δ = (50.2 - 40) / 40 = 25.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算伸长率δ），需要应用公式并得出具体数值结果，符合计算题的特征。 | 知识层次: 题目要求进行基本的数值计算和公式应用，涉及简单的伸长率计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用伸长率的基本公式进行计算，无需额外的概念理解或复杂步骤。题目提供了所有必要的数据，且计算过程简单直接，属于单一公式直接计算的难度等级。" + }, + { + "idx": 2823, + "question": "Analyze the influence of molecular chain flexibility on the viscous flow temperature of polymers", + "answer": "From the relationship between chain segments and the energy barrier difference (potential barrier) Lp=l exp{Δε/kT}, it can be seen that the better the molecular chain flexibility, the lower the potential barrier (Δε) for internal rotation, and the shorter the flow unit segments. According to the segmental motion mechanism of polymer flow, flexible molecules require smaller free volume space for flow, thus viscous flow can occur at relatively lower temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析分子链柔顺性对聚合物粘流温度的影响，答案提供了详细的文字解释和论述，涉及分子链段运动机制和自由体积空间等概念，属于需要展开说明的简答题类型。 | 知识层次: 题目要求分析分子链柔顺性对聚合物粘流温度的影响，涉及分子链段运动机制、自由体积理论等复杂概念的关联和综合分析，需要深入理解聚合物流动的机理并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解聚合物分子链柔性与粘流温度之间的复杂关系，涉及分子链段运动机理、能垒差（势垒）计算以及自由体积理论等高级概念。正确选项不仅需要综合运用多个知识点（如Lp=l exp{Δε/kT}公式的物理意义、链段运动机制等），还需要进行机理层面的深度解释和推理分析。这种题目在选择题中属于对知识掌握深度和综合分析能力要求极高的类型，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 2824, + "question": "Given that the glass transition temperature of polyethylene is $T_{\\\\mathrm{g}}=-68~\\\\mathrm{^\\\\circ C}$, that of polyoxymethylene is $\\\\mathcal{T}_{\\\\varepsilon}=-83^{\\\\circ}\\\\mathrm{C}$, and that of polydimethylsiloxane is $T_{\\\\mathrm{{s}}}=-128^{\\\\circ}\\\\mathrm{{C}}$, analyze the general relationship between the flexibility of polymer chains and their $T_{\\\\mathfrak{s}}$.", + "answer": "The repeating unit structure of polyethylene is: —CH2—CH2—; the repeating unit structure of polyoxymethylene is: —$\\\\mathbf{CH_{3}}$—O—, and the repeating unit structure of polydimethylsiloxane is: —Si$\\\\mathbf{CH_{3}}$$\\\\mathbf{CH_{3}}$—O—. Since the internal rotation of the Si—O bond is easier than that of the C—O bond, and the internal rotation of the C—O bond is easier than that of the C—C bond, the easier the internal rotation, the better the flexibility of the molecular chain. It can thus be concluded that as flexibility increases, the temperature $T_{g}$ decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析聚合物链的柔韧性与玻璃化转变温度之间的关系，并提供文字解释和论述。答案中包含了详细的分子结构分析和逻辑推理，符合简答题的特征。 | 知识层次: 题目要求分析聚合物链柔性与玻璃化转变温度之间的关系，涉及多个聚合物结构的比较和内部旋转能力的分析。需要理解聚合物链柔性的影响因素，并将这些因素与玻璃化转变温度的变化联系起来。虽然不需要复杂的计算或深度推理，但需要综合多个概念进行解释，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解多个概念并进行比较分析。题目要求分析聚合物链的柔韧性与玻璃化转变温度（Tg）之间的关系，涉及对不同聚合物重复单元结构的理解、内部旋转难易程度的比较，以及这些因素如何影响分子链的柔韧性和Tg。此外，还需要综合这些信息得出结论，属于多角度分析论述的层次。" + }, + { + "idx": 2825, + "question": "An aluminum rod with a length of 20m and a diameter of 14mm is drawn through a die with an aperture of 12.7mm. Calculate the length of the aluminum rod after drawing.", + "answer": "During the deformation process, the total volume remains unchanged. Let the length after drawing be L, then π(14.0/2)^2×20×10^3 = π(12.7/2)^2×L×10^3, L=24.3m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝棒在拉伸后的长度，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及体积不变原理的直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用体积不变原理这一基本公式进行计算，解题步骤简单，无需组合多个公式或进行复杂分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2826, + "question": "A 14mm diameter aluminum rod is drawn through a die with an aperture of 12.7mm. Calculate the cold working rate that this aluminum rod will undergo.", + "answer": "The cold working rate is the reduction in cross-sectional area: φ=[π(14.0/2)^2-π(12.7/2)^2]/π(14.0/2)^2=18%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解冷加工率，答案是一个具体的百分比数值，解答过程涉及数学运算和公式推导。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即通过给定的直径计算横截面积的变化率，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（冷加工率的计算公式）并进行简单的数值代入和计算。题目没有涉及多个公式的组合或复杂的逻辑推理，属于最基础的直接计算类型。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2827, + "question": "Determine the engineering strain εe and true strain εT when the length increases from L to 1.1L, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (1.1 - 1)L / L = 10%; εT = ln(1.1L / L) = 9.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（工程应变和真实应变）并应用相关公式，答案以计算结果形式呈现 | 知识层次: 题目主要涉及工程应变和真实应变的基本公式应用和简单计算，不需要多步计算或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算工程应变和真实应变，但两者都是直接套用基本公式（工程应变εe = ΔL/L，真实应变εT = ln(Lf/L0)），且计算过程简单。题目仅要求对两种应变进行基本计算和简单比较，不涉及复杂推导或多步骤分析，因此在选择题型内属于等级2难度。" + }, + { + "idx": 2828, + "question": "Determine the engineering strain εe and true strain εT when compressed from h to 0.9h, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (0.9 - 1)h / h = -10%; εT = ln(0.9h / h) = -10.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算工程应变和真实应变）并应用相关公式，答案也以数值形式给出，符合计算题的特征。 | 知识层次: 题目要求进行基本的工程应变和真实应变计算，涉及直接套用公式（εe = ΔL/L0 和 εT = ln(L/L0)），属于简单应用层次。虽然需要理解两种应变的定义，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题中属于简单应用难度，需要应用工程应变和真实应变两个基本公式进行计算，但不需要复杂的推导或分析。题目直接给出了变形前后的高度比，只需套用公式即可得出结果。虽然涉及两个公式，但计算过程简单直接，属于选择题型中的基础难度水平。" + }, + { + "idx": 2829, + "question": "Determine the engineering strain εe and true strain εT when elongating from L to 2L, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (2 - 1)L / L = 100%; εT = ln(2L / L) = 69.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（工程应变和真实应变）并应用相关公式，答案也以数值形式呈现。虽然题目还要求解释哪种应变更好反映真实变形特性，但主要任务仍是计算。 | 知识层次: 题目要求应用工程应变和真实应变的公式进行计算，属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，仅需应用基本公式（工程应变和真实应变）进行简单计算，无需组合多个公式或进行复杂分析。题目直接给出了变形前后的长度关系，计算步骤明确且直接。" + }, + { + "idx": 2830, + "question": "Determine the engineering strain εe and true strain εT when compressed from h to 0.5h, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (0.5 - 1)h / h = -50%; εT = ln(0.5h / h) = -69.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（工程应变和真实应变的计算）并应用相关公式（应变计算公式），答案也以具体数值形式呈现。虽然最后需要解释哪种应变更好反映变形特性，但主要考察点仍是计算能力。 | 知识层次: 题目主要涉及工程应变和真实应变的简单计算，需要直接套用基本公式进行计算，属于基本公式应用和简单计算的范畴。虽然题目要求解释哪种应变更能反映真实变形特性，但这一部分也属于对基本概念的直接应用，思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算工程应变和真实应变两个值，但都是直接套用基本公式（工程应变公式和自然对数公式），无需复杂推导或多步骤组合计算。题目主要考察对两种应变定义的理解和基本计算能力，属于选择题型中中等偏下的难度水平。" + }, + { + "idx": 2831, + "question": "Compare the differences between engineering strain and true strain under tension and compression, and explain which one better reflects the true deformation characteristics", + "answer": "εT ≠ εe, the larger the deformation, the greater the difference between εT and εe. Comparing the cases of elongation to 2L and compression to 0.5h, the absolute values of true strain are equal, while the absolute values of engineering strain are not equal. Therefore, true strain better reflects the true deformation characteristics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较工程应变和真实应变的差异，并解释哪一种更能反映真实的变形特性。答案通过文字解释和论述来回答问题，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求比较工程应变和真实应变在拉伸和压缩下的差异，并解释哪一种更能反映真实的变形特性。这需要理解两种应变的概念，进行多步比较和分析，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，该题目要求考生不仅理解工程应变和真实应变的定义，还需要在拉伸和压缩两种情况下进行比较分析。题目涉及多步计算（如计算不同变形条件下的应变值）和概念关联（如理解两种应变在不同变形条件下的差异）。此外，题目要求综合分析哪种应变更能反映真实的变形特性，这需要考生从多个角度进行论述。因此，该题目在选择题型中属于较高难度，对应知识层次为中等应用，符合等级4的标准。" + }, + { + "idx": 2832, + "question": "For a pre-annealed metallic polycrystal, the true stress-strain curve in the plastic region can be approximately expressed as ∇σ_T= kε_T^n, where k and n are empirical constants; known as the strength coefficient and strain hardening exponent, respectively. Derive the mathematical relationship between the strain hardening exponent n and the strain hardening rate (θ=dσ_T/dε_T).", + "answer": "θ=dσ_T/dε_T=n kε_T^(n-1). Substituting σ_T=kε_T^n, we obtain θ=nσ_T/ε_T.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导应变硬化指数n与应变硬化率θ之间的数学关系，需要应用公式和进行数学推导，最终给出具体的数学表达式。答案的形式是具体的数学公式，符合计算题的特征。 | 知识层次: 题目需要理解应变硬化指数和应变硬化速率之间的关系，并进行多步数学推导和公式应用，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解应变硬化指数和应变硬化率的概念，并进行多步推导和综合分析。题目要求将给定的应力-应变关系进行微分，并正确代入表达式，涉及中等应用层次的知识点掌握和计算能力。" + }, + { + "idx": 2833, + "question": "For a pre-annealed metal polycrystal, the true stress-strain curve in the plastic region can be approximately expressed as ∇σ_T= kε_T^n, where k and n are empirical constants, referred to as the strength coefficient and strain hardening exponent, respectively. If there are two materials, A and B, with roughly equal k values, but n_A=0.5 and n_B=0.2, which material has higher hardening capability and why?", + "answer": "For σ_T=kε_T^n, dσ_T=n kε_T^(n-1)dε_T, so dσ_T/dε_T=n kε_T^(n-1). When ε_T<1, if 0. Along which direction of tension (or compression) will slip not occur?", + "answer": "Based on the characteristics of the slip systems in the magnesium oxide structure, slip will not occur only when tension (or compression) is applied along a direction perpendicular to all (110) planes. From the standard projection diagram of the cubic crystal system (001), it can be seen that there is no pole that is $90^\\mathfrak{o}$ away from all (110) poles. Therefore, for magnesium oxide, there is no direction of tension (or compression) that will not cause slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来分析在特定条件下滑移不会发生的方向，答案提供了详细的解释和论证过程，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析MgO晶体结构中的滑移系统特性，并基于立方晶系标准投影图进行空间几何关系的推理，判断在何种拉伸或压缩方向下滑移不会发生。这需要综合运用晶体学知识、滑移系统特性以及空间几何分析能力，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2838, + "question": "A cross-slip system consists of one slip direction and two crystallographic planes containing this slip direction, such as the (101) [111] (110) in bcc crystals. Write down three other cross-slip systems of the same type for bcc crystals.", + "answer": "From the standard projection diagram of the cubic crystal system (001), it can be found that the other three cross-slip systems of the same type for bcc crystals are: (101) [111] (110), (011) [111] (110), (110) [111] (101).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出三个其他交叉滑移系统，需要文字解释和论述，而不是选择、判断或计算。答案也是以文字形式给出具体的滑移系统，符合简答题的特征。 | 知识层次: 题目要求学生在理解bcc晶体滑移系统的基础上，通过标准投影图找出其他相同类型的交叉滑移系统。这需要学生不仅记忆bcc晶体的滑移方向和晶面，还需要理解交叉滑移系统的构成原理，并进行一定的分析和应用。虽然不涉及复杂的计算或深度推理，但需要多步的概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握bcc晶体的交叉滑移系统，并能从标准投影图中识别出其他相同类型的交叉滑移系统。这需要考生具备一定的晶体学知识，能够理解滑移方向和晶面之间的关系，并能进行多步的分析和综合。虽然题目提供了部分提示（如标准投影图），但考生仍需具备一定的空间想象能力和综合分析能力才能正确解答。" + }, + { + "idx": 2839, + "question": "For a bcc crystal with a critical resolved shear stress of 60MPa on the (110)[111] slip system, how much stress must be applied in the [001] direction to initiate slip?", + "answer": "Vector dot product:\\n[001] direction:\\na⋅b=|a|⋅|b|cosθ⇒cosθ=(a⋅b)/(|a|⋅|b|)=(a1b1+a2b2+a3b3)/(√(a1²+a2²+a3²)⋅√(b1²+b2²+b3²))\\ncosλ=1/(1×√3)=1/√3,\\ncosφ=0/(1×√2)=0\\nσ=τt/(cosλcosφ)=60/((1/√3)×0)=∞,\\nTherefore, slip cannot be initiated in this direction no matter how much stress is applied.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，涉及向量点积和临界分切应力的计算，最终得出一个具体的数值结果（∞）。答案展示了详细的数学推导过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括向量点积、方向余弦计算和临界分切应力公式的应用。虽然不涉及复杂的综合分析或机理解释，但需要理解晶体滑移系统的基本原理，并能正确应用相关公式进行计算。 | 难度: 在选择题中属于高难度，需要深入理解晶体滑移系统的概念，进行多步骤的向量点积计算，并综合分析临界分切应力的应用。题目涉及复杂的多变量计算和概念关联，对学生的知识掌握深度和计算能力要求较高。" + }, + { + "idx": 2841, + "question": "For a Cu single crystal, the stress σ corresponding to 1% plastic deformation is 40 MPa. From the standard projection diagram of the cubic crystal system (001), it is found that when the tensile axis is [111], the activated slip systems are (111)[011] and another 5 equivalent slip systems. The orientation factor for activating any one of these slip systems can be calculated as cosφcosλ=1/3×2/√6=2/3√6. Determine the dislocation density after 1% plastic deformation. Given τ0=700 kPa, G=42×10^3 MPa, b=0.256 nm, α=0.4.", + "answer": "τ=σcosφcosλ=40×2/3√6=10.80 MPa. From τ=τ0+αGb√ρ, the dislocation density can be calculated as ρ=((τ−τ0)/αGb)^2=((10.89×10^3−700)/(0.4×42×10^6×0.256×10^−9))^2=5.61×10^8 cm−2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定位错密度，解答过程中涉及多个计算步骤和公式代入，最终得出具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括应力与取向因子的计算、位错密度的推导以及材料常数的应用。虽然不涉及复杂的推理分析或创新设计，但需要综合运用多个知识点进行中等难度的计算和分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及晶体塑性变形、位错密度计算等多个知识点，解题步骤包括应力计算、位错密度公式应用等，属于综合性计算问题。虽然题目提供了部分计算步骤，但仍需考生具备一定的材料科学基础和计算能力。" + }, + { + "idx": 2842, + "question": "The critical resolved shear stress of a single crystal at room temperature is $\\\\tau_{\\\\mathfrak{c}}=7.9\\\\times10^{5}~\\\\mathrm{Pa}$. If a tensile test is performed on an aluminum single crystal sample at room temperature with the tensile axis in the [123] direction, calculate the stress required to cause the sample to yield.", + "answer": "Al has an fcc crystal structure, and its slip system is $\\\\{111\\\\}\\\\langle110\\\\rangle$. When the external force axis is [123], according to the standard projection diagram of the cubic crystal system, the first activated slip system is (111)[101]. Therefore, $\\\\phi$ is the angle between [123] and the normal [111] of the (111) crystal plane, and $\\\\lambda$ is the angle between [123] and [101]. Thus, $$\\\\cos\\\\phi{=}\\\\frac{-1+2+3}{\\\\sqrt{14}\\\\times\\\\sqrt{3}}=\\\\frac{4}{\\\\sqrt{42}}$$ $$\\\\cos\\\\lambda{=}\\\\frac{1+0+3}{\\\\sqrt{14}\\\\times\\\\sqrt{2}}=\\\\frac{2}{\\\\sqrt{7}}$$ $$\\\\sigma_{\\\\mathrm{{s}}}=\\\\frac{\\\\tau_{C}}{\\\\cos{\\\\phi}\\\\cos\\\\lambda}=\\\\frac{7.9\\\\times10^{5}}{\\\\frac{4}{\\\\sqrt{42}}\\\\times\\\\frac{2}{\\\\sqrt{7}}}=1.69({\\\\mathrm{MP}}a)$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及角度计算、应力计算等具体数值操作，最终给出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括确定滑移系统、计算角度、应用临界分切应力公式等，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、滑移系统、角度计算等多个概念，并进行多步骤的综合计算。虽然题目提供了正确选项，但解题过程涉及多个关键步骤和公式应用，对学生的综合分析能力有一定要求。" + }, + { + "idx": 2843, + "question": "For a bcc crystal with a critical resolved shear stress of ${60}\\\\mathbf{M}\\\\mathbf{Pa}$ on the (110)[111] slip system, how much stress must be applied in the [001] and [010] directions to initiate slip?", + "answer": "$A C$ and $A^{\\\\prime}C^{\\\\prime}$ are the distances between two adjacent slip planes in the crystal before and after stretching, respectively. Since the distance between slip planes remains unchanged before and after stretching, i.e., $A C{=}A^{\\\\prime}C^{\\\\prime}$, we have \\n$$\\n\\\\epsilon={\\\\frac{A^{\\\\prime}B^{\\\\prime}-A B}{A B}}={\\\\frac{{\\\\frac{A^{\\\\prime}C^{\\\\prime}}{\\\\sin30^{\\\\circ}}}-{\\\\frac{A C}{\\\\sin45^{\\\\circ}}}}{\\\\frac{A C}{\\\\sin45^{\\\\circ}}}}\\n$$\\n\\n$$\\n={\\\\frac{2-{\\\\sqrt{2}}}{\\\\sqrt{2}}}=41.4\\\\%\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算在特定方向上施加的应力以启动滑移，涉及数值计算和公式应用。答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界分切应力的概念，并应用施密特定律计算不同方向上的应力分量。虽然不涉及复杂的机理分析或创新设计，但需要综合分析晶体结构和应力方向的关系。 | 难度: 在选择题中属于中等偏上难度，需要理解临界分切应力的概念，并能够正确应用施密特定律进行计算。题目涉及多步计算过程，包括确定施密特因子和计算所需应力，同时需要综合分析晶体结构和滑移系统的几何关系。虽然题目提供了明确的方向和滑移系统，但解题步骤较为复杂，需要较强的概念关联和计算能力。" + }, + { + "idx": 2844, + "question": "When a single crystal sample of Mg is subjected to tensile testing, the three slip directions form angles of $38^{\\\\circ}, 45^{\\\\circ}, 85^{\\\\circ}$ with the tensile axis, respectively, while the normal to the basal plane forms an angle of $60^{\\\\circ}$ with the tensile axis. If plastic deformation is first observed at a tensile stress of $2.05\\\\,\\\\mathrm{MPa}$, what is the critical resolved shear stress of $\\\\mathrm{Mg}$?", + "answer": "The slip plane of $\\\\mathrm{Mg}$ is the (0001) plane (basal plane). According to the resolved shear stress formula $\\\\tau = \\\\sigma \\\\cos\\\\lambda \\\\cos\\\\phi$, when $\\\\phi$ is fixed at $60^{\\\\circ}$, the smaller $\\\\lambda$ is, the larger $\\\\tau$ becomes. Therefore, under tensile stress, the crystal slips along the slip direction that forms a $38^{\\\\circ}$ angle with the tensile axis, resulting in plastic deformation. Thus, the critical resolved shear stress of $\\\\mathrm{Mg}$ is $$\\\\tau_{\\\\mathrm{c}} = \\\\sigma_{\\\\mathrm{s}} \\\\cos\\\\lambda \\\\cos\\\\phi = 2.05 \\\\times \\\\cos60^{\\\\circ} \\\\times \\\\cos38^{\\\\circ}$$ $$= 2.05 \\\\times 0.5 \\\\times 0.788 = 0.8077\\\\,(\\\\mathrm{MPa})$$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（临界分切应力公式）来求解镁的临界分切应力，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即使用临界分切应力公式进行计算。虽然需要选择正确的滑移方向，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在选择题中属于简单应用难度，题目要求直接应用临界分切应力公式进行计算，仅需理解公式中的角度关系并代入数值。虽然涉及角度选择和简单计算，但步骤明确且无需复杂分析，属于基础公式应用层次。" + }, + { + "idx": 2845, + "question": "For FCC and BCC metals during plastic deformation, the relationship between flow stress and dislocation density ρ is given by τ=τ0+αGb√ρ, where τ0 is the stress required for dislocation motion without interference from other dislocations, i.e., the shear stress without work hardening, G is the shear modulus, b is the Burgers vector of the dislocation, and α is a material-dependent constant, α=0.3∼0.5. If a Cu single crystal has τ0=700 kPa, initial dislocation density ρ0=10^5 cm−2, G=42×10^3 MPa, b=0.256 nm, α=0.4, what is the critical resolved shear stress?", + "answer": "τ=τ0+αGb√ρ0=700+0.4×42×10^6×0.256×10^−9×√10^9=836 kPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（临界分解剪切应力）。解答过程涉及公式应用和单位换算，属于典型的计算题类型。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过给定的公式和参数计算临界分切应力。虽然需要理解公式中各参数的含义，但整体上属于直接套用公式进行计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目提供了多个参数和公式，但解题过程仅需直接套用给定的公式τ=τ0+αGb√ρ0，并进行简单的数值计算。不需要多个公式的组合或复杂的推导步骤，因此属于等级2难度。" + }, + { + "idx": 2846, + "question": "Indicate the easy slip plane and easy slip direction of Cu crystal, and calculate the slip plane spacing, atomic spacing in the slip direction, and lattice resistance. (Given G_Cu=48.3GPa, ν=0.3)", + "answer": "Cu has an fcc structure, with the easy slip plane being {111} and the easy slip direction being <110>. The slip plane spacing d_(111)=a/√3, and the atomic spacing in the slip direction b=√2/2a. The lattice resistance τ_PN=(2×48.3×10^9)/(1-0.3)×exp[-2π(a/√3)/((1-0.3)(√2/2)a)]=90.45MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算滑移面间距、滑移方向原子间距和晶格阻力，涉及数值计算和公式应用，答案也给出了具体的计算过程和结果。 | 知识层次: 题目需要理解Cu晶体的fcc结构，识别易滑移面和滑移方向，并应用公式计算滑移面间距、原子间距和晶格阻力。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握Cu晶体的fcc结构、滑移面和滑移方向的基本概念，同时需要进行多步计算（如滑移面间距、滑移方向原子间距和晶格阻力的计算）。虽然题目提供了公式和参数，但需要考生综合运用材料科学和数学知识来完成计算和分析。" + }, + { + "idx": 2847, + "question": "Calculate the volume fraction φ_Fe3C of the Fe3C phase in 40 steel, given the mass fraction of carbon w_c=0.004.", + "answer": "φ_Fe3C = 0.004 / 0.0667 = 0.06", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算Fe3C相的体积分数），并给出了具体的计算步骤和公式应用（φ_Fe3C = w_c / 0.0667），最终得出数值结果（0.06）。这符合计算题的特征。 | 知识层次: 题目考查基本公式应用和简单计算，仅需将给定的质量分数代入公式进行一步除法运算即可得到结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算（φ_Fe3C = w_c / 0.0667），无需额外的概念理解或步骤组合。题目提供所有必要参数，且计算过程简单直接，属于最基础的公式应用层级。" + }, + { + "idx": 2848, + "question": "Indicate the easy slip plane and easy slip direction of α-Fe crystal, and calculate the slip plane spacing, atomic spacing in the slip direction, and lattice resistance. (Given G_α-Fe=81.6GPa, ν=0.3)", + "answer": "α-Fe has a bcc structure, with the slip plane being {110} and the easy slip direction being <111>. The slip plane spacing d_(110)=a/√2, and the atomic spacing in the slip direction b=√3/2a. The lattice resistance τ_PN=(2×81.6×10^9)/(1-0.3)×exp[-2π(a/√2)/((1-0.3)(√3/2)a)]=152.8MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算滑移面间距、滑移方向的原子间距和晶格阻力，涉及数值计算和公式应用，答案也给出了具体的计算结果。 | 知识层次: 题目需要理解α-Fe晶体的滑移面和滑移方向的基本概念，并应用给定的参数进行多步计算，包括滑移面间距、原子间距和晶格阻力的计算。这涉及到对晶体结构、滑移机制的理解以及相关公式的应用，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解bcc晶体结构的基本概念（滑移面和滑移方向），掌握晶面间距和原子间距的计算方法，并能够应用弹性模量和泊松比进行晶格阻力的综合计算。题目涉及多步骤推导和公式应用，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 2849, + "question": "Calculate the shear strength τ of 40 steel, given that the shear modulus of Fe is G=7.9×10^4 MPa, the lattice constant of α-Fe is a=0.28 nm, and the average spacing of Fe3C particles is λ=41.2 μm.", + "answer": "τ = (G * b) / λ = (G * (√3/2) * a) / λ = (7.9×10^4 * (√3/2) * 0.28×10^-3) / 41.2 = 0.465 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及给定的参数和公式推导，最终得出一个具体的数值结果。答案展示了完整的计算过程和最终结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及剪切强度公式的应用、晶格常数和粒子间距的转换，以及数值计算。虽然公式直接给出，但需要理解各参数的含义并进行单位转换和计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解剪切强度、剪切模量、晶格常数和粒子间距等多个概念，并进行多步计算和综合分析。虽然题目提供了公式和具体数值，但计算过程涉及单位转换和数学运算，对学生的概念掌握和计算能力有一定要求。" + }, + { + "idx": 2850, + "question": "A single crystal of A1 is made into a tensile specimen (with a cross-sectional area of 9 mm²) for room-temperature tensile testing. The tensile axis forms an angle of $36.7^{\\\\circ}$ with [001], $19.1^{\\\\circ}$ with [011], and $22.2^{\\\\circ}$ with [111]. The load at the onset of yielding is 20.4 N. Determine the resolved shear stress on the primary slip system.", + "answer": "From the known tensile axis direction, the primary slip system can be determined as (111)[101] using the standard projection diagram of the cubic crystal system (001). Let the stress axis direction be $[u\\\\tau\\\\mathbf{w}]$. From the given conditions, we have $$\\\\cos36.7^{\\\\circ}=\\\\frac{w}{\\\\sqrt{u^{2}+v^{2}+w^{2}}}$$$$\\\\cos19.1^{\\\\circ}=\\\\frac{v+w}{\\\\sqrt{2}\\\\sqrt{u^{2}+v^{2}+w^{2}}}$$$$\\\\cos22.2^{\\\\circ}={\\\\frac{u+v+w}{{\\\\sqrt{3}}{\\\\sqrt{{u}^{2}+{v}^{2}+{w}^{2}}}}}$$Let $u^{2}+v^{2}+w^{2}=1$, then solving gives $\\\\scriptstyle\\\\pmb{u}=0.26$, $v{=}0.54$, ${\\\\mathfrak{w}}{=}0.80$. Thus, $\\\\cos\\\\lambda={\\\\frac{0.26+0.80}{\\\\sqrt{2}}}=0.75$ $$\\\\cos\\\\phi=\\\\frac{-0.26+0.54+0.80}{\\\\sqrt{3}}=0.62$$$$\\\\tau=\\\\sigma\\\\cos\\\\lambda\\\\cos\\\\phi=\\\\frac{20.4}{9\\\\times10^{-6}}\\\\times0.75\\\\times0.62=1.01(\\\\mathrm{MPa})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定解析剪切应力，解答过程中涉及多个步骤的数学运算和方向余弦的计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括确定主滑移系统、计算方向余弦、求解应力分量等，涉及多个概念的综合应用和关联分析，但不需要进行复杂的机理推理或创新设计。 | 难度: 在选择题型中，该题目属于高难度等级。题目涉及复杂的多变量计算，需要掌握晶体学方向指数的计算、解析剪切应力的概念，以及多步骤的数学推导和计算过程。解题过程中需要求解方向余弦、确定主滑移系统，并进行应力分解，这些步骤在选择题型中都属于较高难度的要求。此外，题目还要求考生能够综合运用多个知识点，进行复杂的数学运算，这在选择题型中属于较为复杂和综合性的问题。" + }, + { + "idx": 2851, + "question": "Calculate the average spacing λ of Fe3C particles, given the number of Fe3C particles per unit volume N_v=1.43×10^13 1/m^3.", + "answer": "λ = (1 / N_v)^(1/3) = (1 / 1.43×10^13)^(1/3) = 4.12×10^-5 m = 41.2 μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算并应用公式来求解Fe3C颗粒的平均间距λ，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接应用和简单计算，无需多步推导或综合分析，属于对Fe3C粒子间距公式的直接套用。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即λ = (1 / N_v)^(1/3)，无需额外的公式组合或复杂推导。解题步骤简单明了，属于最基础的直接计算类型，因此难度等级为1。" + }, + { + "idx": 2852, + "question": "Given that a straight dislocation line in an alloy is hindered by second-phase particles with a spacing of $\\\\pmb{\\\\lambda}$ during its motion, prove that the shear stress required for the dislocation to continue moving via the bypass mechanism is: 2T-Bln(2), where T is the line tension; b is the Burgers vector; $_{!G}$ is the shear modulus; $\\\\pmb{\\\\gamma}_{0}$ is the radius of the second-phase particle; and $B$ is a constant.", + "answer": "Strengthening effect of non-deformable particles: When a moving dislocation encounters non-deformable particles, it will be blocked, causing the dislocation line to bend around them. Since the dislocation has line tension $\\\\pmb{T}$, bending the dislocation line requires overcoming the effect of its line tension. The shear stress required for the dislocation line to bypass particles with spacing $\\\\lambda$ is The line tension of a dislocation is analogous to the surface tension of a liquid and can be represented by the energy per unit length of the dislocation. The energy per unit length of the dislocation $T=E=\\\\frac{G b^{2}}{4\\\\pi k}\\\\ln\\\\frac{\\\\bar{R}}{r_{0}}$ Gn. Substituting this into the above equation, then", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求证明一个具体的公式，并给出了详细的推导过程，涉及数值计算和公式应用。 | 知识层次: 题目要求证明一个关于位错绕过第二相粒子所需的剪切应力的公式，这涉及到位错理论、线张力概念、Burgers矢量、剪切模量等多个材料科学中的高级概念的综合运用。此外，题目还要求进行推理分析和机理解释，而不仅仅是简单的公式应用或记忆。因此，这属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于高难度综合计算等级。题目要求证明一个复杂的剪切应力公式，涉及多个材料科学中的高级概念（如位错线张力、Burgers矢量、剪切模量等），并需要综合运用这些概念进行推导。解题步骤复杂，需要深入理解位错与第二相粒子相互作用的机理，并进行数学推导。这种题目在选择题中属于最高难度级别，因为它不仅测试知识点的掌握深度，还要求考生具备综合分析和复杂计算能力。" + }, + { + "idx": 2853, + "question": "For an Al2O3 specimen with a circular cross-section in a three-point bending test, the cross-sectional radius r=3.5mm, the span between the two supports is 50mm, and it fractures under a load of 950N. Calculate the fracture strength σfs of the material.", + "answer": "σfs = (Ff * L) / (π * r^3) = (950 * 50 * 10^-3) / (π * (3.5 * 10^-3)^3) = 352.6 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体数值的代入和计算，最终得出一个具体的数值结果（352.6 MPa）。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及三点弯曲测试中的断裂强度计算，属于直接套用公式的范畴，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用三点弯曲测试的断裂强度公式，但计算步骤直接且明确，仅涉及单一公式的代入和简单数学运算。题目没有复杂的转换或额外概念要求，属于基础应用层次。" + }, + { + "idx": 2854, + "question": "For an Al2O3 specimen with a square cross-section of side length 12mm in a three-point bending test, the distance between the two supports is 40mm. Given the material's fracture strength σfs=352.6 MPa, find the load at fracture Ff.", + "answer": "Ff = (2 * σfs * b^3) / (3 * L) = (2 * 352.6 * 10^6 * (12 * 10^-3)^3) / (3 * 40 * 10^-3) = 10154.9 N", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解断裂载荷Ff，答案是一个具体的数值结果，解答过程涉及公式代入和单位转换，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及三点弯曲测试中的断裂强度公式直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解三点弯曲测试的基本原理和公式，但解题步骤相对直接，仅需套用给定的公式并进行简单的单位转换和计算。不需要多个公式的组合或复杂的分析，因此属于等级2难度。" + }, + { + "idx": 2855, + "question": "Calculate the number of Fe3C particles per unit volume N_v, given the volume fraction of Fe3C phase φ_Fe3C=0.06 and the radius of spherical cementite particles r=10×10^-6 m.", + "answer": "N_v = φ_Fe3C / (4/3 * π * r^3) = 0.06 / (4/3 * π * (10×10^-6)^3) ≈ 1.43×10^13 (1/m^3)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算并应用公式来求解Fe3C颗粒的单位体积数量，答案也是通过计算得出的具体数值。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，属于对体积分数和球形颗粒体积公式的直接套用。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，无需复杂的推理或多步骤操作。题目提供了所有必要的参数，只需将数值代入公式即可得到答案。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 2856, + "question": "For many polymer materials, their tensile strength σi is a function of the number-average relative molecular mass Mn̅: the formula is given by σi = σ0 - A / Mn̅, where σ0 is the tensile strength at infinite molecular weight, and A is a constant. Given two types of poly(methyl methacrylate) with number-average relative molecular masses of 4×10^4 and 6×10^4, the corresponding tensile strengths are 107 MPa and 170 MPa, respectively. Determine the tensile strength σb when the number-average relative molecular mass is 3×10^4.", + "answer": "The equations are: 107 = σ0 - A / (4×10^4), 170 = σ0 - A / (6×10^4). Solving these gives σ0 = 296 MPa and A = 7.56×10^6. Therefore, σb = σ0 - A / Mn̅ = 296 - 7.56×10^6 / (3×10^4) = 44 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（44 MPa）。解答过程涉及解方程组和应用公式，符合计算题的特征。 | 知识层次: 题目需要应用给定的公式进行多步计算，包括解方程组和代入求解，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解聚合物拉伸强度与分子量之间的关系公式，并能够建立方程组求解常数σ0和A。解题步骤涉及多步计算，包括解线性方程组和代入求解，要求考生具备一定的数学运算能力和综合分析能力。虽然题目提供了公式和具体数值，但需要考生正确关联概念并准确执行计算步骤，属于综合性计算问题。" + }, + { + "idx": 2857, + "question": "The recovery activation energy of iron is $88.9\\\\mathrm{kJ/mol}$. If cold-deformed iron is subjected to recovery treatment at $400^{\\\\circ}\\\\mathrm{C}$ to retain 60% of its work hardening, it takes $160\\\\mathfrak{min}$. How much time is needed to achieve the same effect with recovery treatment at $450\\\\mathrm{~C~}$?", + "answer": "$$\\\\frac{t_{1}}{t_{2}}=\\\\mathrm{e}^{-{\\\\frac{Q}{R}(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}})}} , t_{2}={\\\\frac{t_{1}}{\\\\mathrm{e}^{-{\\\\frac{\\\\mathrm{{Q}}}{\\\\scriptscriptstyle{R}}}\\\\big({\\\\frac{1}{T_{2}}}-{\\\\frac{1}{T_{1}}}\\\\big)}}}}={\\\\frac{160}{\\\\mathrm{e}^{-{\\\\frac{80.5}{831}}\\\\big({\\\\frac{1}{723}}-{\\\\frac{1}{673}}\\\\big)}}}=59(\\\\operatorname*{min})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案给出了具体的计算过程和最终的时间结果。 | 知识层次: 题目需要进行多步计算，包括公式应用和数值计算，涉及温度转换和激活能的概念关联，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及恢复激活能的概念，需要应用阿伦尼乌斯公式进行多步计算，包括温度转换和指数运算。虽然题目提供了公式，但需要正确代入数值并进行复杂的数学运算才能得出正确答案。这要求考生具备中等应用层次的知识，能够将理论知识与实际计算相结合。" + }, + { + "idx": 2858, + "question": "Briefly describe the characteristics of plastic deformation in ceramic materials (crystalline).", + "answer": "In general, compared to metallic materials and high molecular materials, ceramic materials appear hard and brittle, which is determined by the type of bonding between their atoms. The atoms in ceramic materials are usually bonded by ionic or covalent bonds. In covalently bonded ceramics, atoms are bonded through shared electron pairs, exhibiting directionality and saturation, with relatively high bond energy. During plastic deformation, the movement of dislocations inevitably disrupts the covalent bonds between atoms, resulting in significant lattice resistance (Peierls-Nabarro force). Therefore, covalently bonded ceramics exhibit hard and brittle characteristics. For ionically bonded ceramic materials, there are two scenarios: single crystals (such as NaCl, FeO, etc.) can undergo considerable plastic deformation under compressive stress at room temperature. However, polycrystalline ionically bonded ceramics are often brittle and prone to crack formation at grain boundaries. This is because ionic crystals require alternating positive and negative ion arrangements. Under external forces, when a dislocation moves by one atomic spacing, the strong Coulombic repulsion between like-charged ions makes dislocation movement along directions perpendicular or parallel to the ionic bonds extremely difficult. However, if the dislocation moves along a $45^{\\circ}$ direction rather than horizontally, adjacent crystal planes remain mutually attracted by Coulombic forces during the slip process, resulting in relatively good plasticity. Nevertheless, during the deformation of polycrystalline ceramics, adjacent grains must deform in a coordinated and mutually constrained manner. Due to the limited number of slip systems in ceramics, this is difficult to achieve, leading to cracking at grain boundaries and ultimately brittle fracture. On the other hand, during the heating and cooling processes of sintered ceramic materials, the presence of thermal stresses often leads to the formation of microcracks. Additionally, factors such as corrosion can cause surface cracks. Therefore, inherent cracks are always present to some extent in ceramic materials. Under external forces, severe stress concentration occurs at crack tips. According to elastic mechanics estimates, the maximum stress at a crack tip can reach the theoretical fracture strength. Moreover, since ceramic crystals have few mobile dislocations and dislocation movement is difficult, brittle fracture often occurs once the yield strength is reached. Of course, under tensile or compressive conditions, the mechanical properties of ceramic materials also differ significantly, with compressive strength typically being higher than tensile strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述陶瓷材料塑性变形的特点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对陶瓷材料的塑性变形特性进行详细描述，涉及离子键和共价键陶瓷的不同行为、位错运动、晶界影响、热应力等多方面因素的综合分析。需要深入理解材料科学中的键合理论、位错理论、断裂力学等高级概念，并进行复杂的推理和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对陶瓷材料的塑性变形特性进行全面分析，涉及多种键合类型（离子键和共价键）的对比分析，以及单晶和多晶陶瓷的不同行为机制。解题需要综合运用材料科学、晶体学和力学知识，理解位错运动、晶界效应、应力集中等多个复杂概念，并进行机理层面的深入解释。这种在选择题中要求全面分析复杂现象并解释深层机理的题目，对学生的知识掌握深度和综合分析能力提出了极高要求。" + }, + { + "idx": 2859, + "question": "The tensile strength of brittle materials can be expressed by the following formula: \\n\\n$$\\n\\\\sigma_{\\\\mathrm{m}}=2\\\\sigma_{\\\\mathrm{0}}\\\\bigg(\\\\frac{\\\\ell}{r}\\\\bigg)^{\\\\frac{1}{2}}\\n$$\\n\\nWhere, $\\\\sigma_{0}$ is the nominal applied tensile stress; $l$ is the length of the surface crack or half the length of an internal crack; $r$ is the radius of curvature at the crack tip; and $\\\\sigma_{\\\\infty}$ is actually the maximum stress caused by stress concentration at the crack tip. Now assume that the critical length of the surface crack in $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ ceramic is $l = 2\\\\times10^{-3}\\\\mathrm{mm}$, its theoretical fracture strength is $\\\\frac{E}{10}$, where $E$ is the elastic modulus of the material and is $393\\\\mathrm{GPa}$. Calculate: When a tensile stress of $275\\\\mathrm{MPa}$ is applied to the $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ ceramic specimen, what is the critical radius of curvature $r_{\\\\mathfrak{c}}$ at the crack tip that causes fracture?", + "answer": "When the tensile stress reaches the fracture strength of the material ($\\\\frac{E}{10}$), $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ fractures, therefore:\\n\\n$$\\n\\\\frac{E}{10}=2\\\\sigma_{\\\\circ}\\\\left(\\\\frac{\\\\lambda}{r}\\\\right)^{\\\\frac{1}{2}}\\\\Rightarrow r=\\\\frac{400\\\\ l\\\\sigma_{0}^{2}}{E^{2}}\\n$$\\n\\n$$\\nr_{\\\\mathrm{c}}={\\\\frac{400l\\\\sigma_{0}^{2}}{E^{2}}}={\\\\frac{400\\\\times2\\\\times10^{-3}\\\\times(275)^{2}}{(393\\\\times10^{3})^{2}}}=3.9\\\\times10^{-7}(\\\\mathrm{mm})=0.39(\\\\mathrm{nm})\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（临界半径）。解答过程涉及公式推导和数值代入计算，符合计算题的特征。 | 知识层次: 题目需要应用给定的公式进行多步计算，涉及材料断裂强度的理论计算和实际应用，需要理解公式中各参数的含义及其相互关系，并进行数值计算。虽然不涉及复杂的综合分析或创新应用，但超出了简单直接套用公式的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解断裂力学公式的含义，并正确代入多个变量进行计算。题目涉及弹性模量、临界裂纹长度和临界半径等概念的综合运用，解题步骤包括公式变形和单位换算，计算过程较为复杂但步骤明确。虽然题目提供了关键公式，但需要考生具备较强的综合分析能力和计算技巧。" + }, + { + "idx": 2860, + "question": "Given that the yield strengths of pure iron with average grain diameters of $\\\\boldsymbol{1}\\\\mathfrak{mm}$ and $0.0625\\\\mathbf{mm}$ are 112.7MPa and 196$\\\\mathbf{MPa}$ respectively, what is the yield strength of pure iron with an average grain diameter of $0.0196\\\\mathrm{mm}$?", + "answer": "$$\\\\tau={\\\\frac{G b}{\\\\lambda}}={\\\\frac{G{\\\\frac{\\\\sqrt{3}}{2}}a}{\\\\lambda}}={\\\\frac{7.9\\\\times10^{19}\\\\times{\\\\frac{\\\\sqrt{3}}{2}}\\\\times0.28\\\\times10^{-9}}{41.2\\\\times10^{-6}}}=0.465(\\\\mathrm{MPa})$$\\n\\n$$\\\\left\\\\{\\\\begin{array}{l}{{112,7=\\\\sigma_{\\\\circ}+k(1\\\\times10^{\\\\circ})^{-\\\\frac{1}{2}},}}\\\\ {{}}\\\\ {{196=\\\\sigma_{\\\\circ}+k(0.0625\\\\times10^{\\\\circ})^{-\\\\frac{1}{2}}}}\\\\end{array}\\\\right.,$$\\n\\nThe solution is\\n\\n$$\\\\begin{array}{l}{{\\\\pmb{\\\\mathscr{s}}}_{\\\\mathscr{0}}=84,935(\\\\mathrm{MPa})}\\\\ {\\\\backslash_{\\\\pmb{\\\\mathscr{k}}}=0.878}\\\\end{array}$$\\n\\nTherefore, $\\\\sigma_{\\\\ast}=84.935+0.878(0.0196\\\\times10^{-3})^{-\\\\frac{2}{2}}=283.255(\\\\mathrm{MPa})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出一个具体的数值结果。答案中包含了详细的公式推导和计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括解方程组和公式应用，涉及Hall-Petch关系的理解和运用，需要一定的综合分析能力。 | 难度: 在选择题中属于高难度题目，需要理解Hall-Petch关系并进行多步计算。题目要求考生首先建立方程组求解材料常数，然后应用这些常数计算新的晶粒尺寸下的屈服强度。涉及对数运算、单位换算和复杂公式推导，对计算精度和概念理解要求很高。" + }, + { + "idx": 2861, + "question": "Explain the phenomenon where the cross-sectional area of the neck remains essentially unchanged during uniaxial stretching of polymers.", + "answer": "Many polymers often exhibit instability in uniform deformation during plastic deformation. For example, when a polymer sample is subjected to a uniaxial tensile test, the stress initially increases linearly with strain, and the specimen is uniformly elongated. After the yield point, the strain at a certain part of the specimen suddenly increases faster than the overall strain, causing the originally uniform cross-section to become non-uniform, forming one or several necks. As deformation continues, the necking zone expands and extends along the length of the specimen until the entire specimen's cross-section becomes uniformly thinner. During this deformation process, the stress remains almost constant. This is because, after exceeding the yield strength, the specimen undergoes plastic deformation, and work hardening occurs at the necking region. XRD analysis proves that, whether in the amorphous or crystalline state, the macromolecules in the polymer gradually align along the direction of the external force as deformation increases. Due to the directionality of bonds (mainly covalent bonds), strain hardening occurs after alignment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物在单轴拉伸过程中颈缩现象的本质，答案提供了详细的文字解释和论述，包括现象描述、机理分析和实验证据，符合简答题的特征。 | 知识层次: 题目要求解释聚合物在单轴拉伸过程中颈缩现象的机理，涉及塑性变形、屈服点、应变硬化、分子取向等多个概念的关联和综合分析。需要深入理解聚合物变形过程中的微观结构变化（如XRD分析证明的分子排列）与宏观力学行为的关系，并进行推理分析。这超出了简单记忆或基本应用的范畴，属于需要综合运用知识进行机理解释的复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解聚合物在单轴拉伸过程中的复杂现象，包括屈服点后的颈缩形成、应变硬化机理以及分子排列变化等。需要综合运用材料科学、力学和结构分析等多方面知识，进行机理层面的深度解释和复杂现象全面分析。这种题目在选择题中属于对知识掌握深度和综合分析能力要求极高的类型。" + }, + { + "idx": 2862, + "question": "Explain how pre-deformation degree, original grain size, and metal purity affect the recrystallization temperature.", + "answer": "From the above analysis, it can be seen that increasing the pre-deformation degree and refining the original grain size will cause the $\\boldsymbol{T}_{\\mathtt{R}}$ to decrease. The influence of impurities on $T_{\\mathbf{R}}$ is dual. If the presence of impurities increases the distortion energy and this factor dominates, then metals with lower purity will have a lower $T_{\\tt R}$. Conversely, if the presence of impurities slows down interface migration and this factor dominates, then metals with higher purity will have a lower $T_{\\tt R}$. Different impurity atoms have different effects on $T_{\\mathbf{R}}$. Generally, the presence of a small amount of impurity atoms will hinder the recrystallization of the metal, thereby causing $T_{8}$ to rise, and the extent of the increase varies depending on the type of impurity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释预变形程度、原始晶粒尺寸和金属纯度对再结晶温度的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多个因素（预变形程度、原始晶粒尺寸、金属纯度）对再结晶温度的影响，涉及不同因素之间的相互作用和机理分析。需要综合运用材料科学中的再结晶理论，理解各因素如何影响变形储能和界面迁移，并进行推理分析。特别是金属纯度的影响具有双重性，需要更深入的理解和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用多个材料科学概念（预变形度、原始晶粒尺寸、金属纯度）对再结晶温度的影响进行深度分析，并理解杂质对再结晶温度的双重作用机制。解题需要：" + }, + { + "idx": 2863, + "question": "Given that the yield strength of industrial pure copper is ${\\\\pmb{\\\\sigma{s}}}=70~{\\\\bf M}{\\\\bf P}{\\\\bf a}$, its grain size is $N{\\\\mathrm{A}}=18$ per $'\\\\mathbf{m}\\\\mathbf{m}^{2}$, and when $N{\\\\mathbf{A}}=$ $\\\\bf{4025}$ per $\\\\scriptstyle{\\\\prime}{\\\\mathbf{m}\\\\mathbf{m}^{2}}$, ${\\\\pmb{\\\\sigma}}{\\\\mathsf{S}}={\\\\pmb{95}}\\\\mathbf{M}\\\\mathbf{P}{\\\\bf a}$. Calculate ${\\\\pmb\\\\sigma_{\\\\mathfrak{s}}}$ when $N{\\\\mathbf{A}}=260$ per $\\\\scriptstyle{\\\\left/{\\\\mathfrak{m m}}^{2}\\\\right.}$.", + "answer": "Let the average grain diameter be $^{d}$, and the number of grains per $\\\\scriptstyle\\\\mathtt{m m}^{2}$ be $N_{\\\\Lambda}$. It can be proven that: Thus $$d=\\\\sqrt{\\\\frac{8}{3\\\\pi N_{\\\\Lambda}}}$$$$d_{1}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times\\\\mathrm{i}8}}=0.217(\\\\mathrm{mm})$$$$d_{2}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times4025}}=1.452\\\\times10^{-2}(\\\\mathrm{mm})$$$$d_{3}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times260}}=5.714\\\\times10^{-2}(\\\\mathrm{mm})$$Substituting into the Hall-Petch formula: Solving $$\\\\left\\\\{\\\\begin{array}{l l}{{70=\\\\sigma_{0}+k(0,217\\\\times10^{-3})^{-\\\\frac{1}{2}}}}\\\\ {{95=\\\\sigma_{0}+k(1,452\\\\times10^{-5})^{-\\\\frac{1}{2}}}}\\\\end{array}\\\\right.$$$$\\\\begin{array}{r}{\\\\sigma_{0}=61,3\\\\mathrm{MPa},\\\\quad k=0,1285}\\\\end{array}$$$$\\\\sigma_{5}=61,3+0.1285\\\\times(5,714\\\\times10^{-5})^{-\\\\frac{1}{2}}=78.3(\\\\mathrm{MPa})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch公式）来求解特定条件下的屈服强度，答案给出了详细的计算过程和最终数值结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度求解，需要理解公式中各参数的含义并进行适当的代数运算。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算和概念关联。需要掌握Hall-Petch公式的应用，能够正确计算晶粒尺寸，并建立方程组求解材料常数。虽然题目提供了正确选项，但解题过程需要综合运用材料科学知识和数学计算能力，属于综合性计算问题。" + }, + { + "idx": 2864, + "question": "There is currently a $\\\\phi{\\\\ell\\\\mathrm{mm}}$ aluminum wire that needs to be finally processed into $\\\\phi{\\\\mathrm{0.5mm}}$ aluminum material. However, to ensure product quality, the cold working amount of this aluminum material cannot exceed $85\\\\%$. How to formulate a reasonable processing procedure?", + "answer": "Cold working amount $=\\\\frac{\\\\Delta A}{A}=\\\\frac{A_{0}-A_{1}}{A_{0}}=\\\\frac{\\\\frac{\\\\pi}{4}d_{0}^{2}-\\\\frac{\\\\pi}{4}\\\\times d_{1}^{2}}{\\\\frac{\\\\pi}{4}\\\\times d_{0}^{2}}=1-\\\\left(\\\\frac{d_{1}}{d_{0}}\\\\right)^{2}=85\\\\%$\\n$$\\nd_{1}=\\\\sqrt{1-0.85}\\\\times6=2.324(\\\\mathrm{mm}),\\\\quad d_{2}=\\\\sqrt{0.15}\\\\times2.324=0.9(\\\\mathrm{mm}),\\n$$\\n\\n$$\\nd_{3}=\\\\sqrt{0.15}\\\\times0.9=0.348(\\\\mathrm{mm})\\n$$\\n\\nTherefore, the $\\\\phi{\\\\mathrm{6mm}}$ aluminum wire can first be cold drawn to $\\\\phi{\\\\mathrm{2.324mm}}$, followed by recrystallization annealing to eliminate work hardening. Then, it is cold drawn to $\\\\phi_{\\\\mathrm{0.9mm}}$, followed by another recrystallization annealing, and finally cold drawn to $\\\\phi_{\\\\mathrm{0.5mm}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定合理的加工步骤。答案中包含了具体的计算过程和公式推导，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解冷加工量的概念及其计算方法，并通过多次计算和中间退火步骤来制定合理的加工流程。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行分步计算和流程规划。 | 难度: 在选择题中属于中等偏上难度，需要理解冷加工量的计算公式，并能够进行多步骤的计算和综合分析。题目涉及多个概念（如冷加工量、直径变化、再结晶退火）的关联，且解题步骤较为复杂，需要分阶段计算和验证。虽然题目提供了正确选项，但理解和应用这些步骤仍需要一定的材料科学基础和分析能力。" + }, + { + "idx": 2865, + "question": "After cold working, the dislocation density of $\\\\mathbf{A}\\\\mathbf{g}$ is $10^{12}/\\\\mathfrak{c m}^{2}$. Assuming that the recrystallization nucleus moves from a high-angle grain boundary into the deformed matrix, find the minimum radius of curvature for the bulging grain boundary $\\\\scriptstyle\\\\left(\\\\mathbf{A}\\\\mathbf{g}_{:}G=30\\\\mathrm{GPa},b=0.3\\\\mathrm{nm},\\\\gamma=0.4\\\\mathrm{J}/\\\\mathrm{m}^{2}\\\\right)$.", + "answer": "The driving force $F$ for the movement of the $\\\\mathbf{Ag}$ recrystallization nucleus from a high-angle grain boundary into the deformed matrix is the stored energy from cold working, $F= G b^{2}\\\\left(\\\\rho_{1}-\\\\rho_{0}\\\\right)$. Since $\\\\rho_{1}\\\\gg\\\\rho_{0}$, $\\\\scriptstyle{F\\\\approx G b^{2}\\\\rho_{1}}$. The bulged grain boundary is subjected to a force $f$ directed toward its center of curvature. When the radius of curvature of the bulge is $R$, $f= \\\\frac{2\\\\gamma}{R},f$ $\\\\scriptstyle{\\\\dot{F}}$ $R_{\\\\mathrm{min}}$ $f$ $F$ $$F{=}f,$$$$G\\\\delta^{2}\\\\rho_{\\\\mathrm{f}}=\\\\frac{2\\\\gamma}{R_{\\\\mathrm{rein}}}$$$$R_{\\\\mathrm{aia}}={\\\\frac{2\\\\gamma}{G b^{2}\\\\rho_{1}}}={\\\\frac{2\\\\times0.4}{30\\\\times10^{8}\\\\times(3\\\\times10^{-10})^{2}\\\\times10^{16}}}=2.9\\\\times10^{-8}({\\\\mathrm{m}})=29({\\\\mathrm{nm}})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小曲率半径，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解冷加工后的位错密度、再结晶核的形成以及晶界弯曲的力学平衡等概念，并应用相关公式进行计算。虽然题目提供了必要的参数和公式，但需要综合运用这些知识来解决问题，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如位错密度、再结晶驱动力、晶界曲率半径等）并进行多步计算。题目要求将理论公式与给定参数结合，推导出最小曲率半径，涉及综合性计算和概念关联。虽然题目提供了所有必要参数，但解题步骤较为复杂，需要较强的综合分析能力。" + }, + { + "idx": 2866, + "question": "A factory used a cold-drawn steel wire rope to lift a large steel component into a heat treatment furnace. Due to a momentary oversight, the wire rope was not removed but was heated together with the component to $860~\\\\mathrm{{^\\\\circC}}$. When the holding time was reached and the furnace door was opened to lift out the component, the wire rope broke. Analyze the cause.", + "answer": "The cold-drawn steel wire rope is made by twisting cold-drawn steel wires with large deformation. The cold work hardening during the processing significantly improves the strength and hardness of the steel wires, enabling them to bear heavy loads. However, when heated to ${\\\\tt860^{\\\\circ}C}$, the temperature far exceeds the recrystallization temperature of the wire rope, leading to recovery and recrystallization phenomena. The effect of work hardening completely disappears, and the strength and hardness are greatly reduced. When used for lifting again, once the load exceeds its bearing capacity, it inevitably leads to the fracture of the wire rope.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢丝绳断裂的原因，答案通过文字解释和论述的方式详细说明了冷拔钢丝绳在高温下发生的微观结构变化及其对力学性能的影响，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析冷拔钢丝绳在高温下断裂的原因，涉及冷加工硬化、回复与再结晶等复杂材料科学原理的综合运用和推理分析。需要理解冷加工硬化对材料性能的影响，以及高温下回复和再结晶过程如何消除加工硬化效应，导致材料性能下降。这需要较深层次的材料科学知识和对材料行为机理的理解，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2867, + "question": "When moving dislocations are pinned, their average spacing is $\\scriptstyle{\\ell=\\rho^{-{\\frac{1}{2}}}(\\rho}$ is the dislocation density). It is given that a $\\mathtt{Cu}$ single crystal has been strain-hardened to the extent that the resolved shear stress acting on the crystal is 14MPa. Given $G=40\\mathrm{GPa},b=0,256$ $\\scriptstyle{\\mathtt{n m}}$, calculate the dislocation density of the $\\mathtt{Cu}$ single crystal.", + "answer": "After moving dislocations are pinned, a dislocation segment of length $\\boldsymbol{\\ell}$ can act as a dislocation source, and the resolved shear stress required to activate this dislocation source is $$\\tau_{\\mathrm{c}}=\\frac{G b}{l},$$$$14\\times10^{6}=\\frac{40\\times10^{9}\\times0.256\\times10^{-9}}{\\rho^{-\\frac{1}{2}}},$$$$\\rho{=1.869\\times10^{12}(\\mathrm{m}^{-2})}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出一个数值结果（dislocation density）。答案中展示了详细的公式推导和计算过程，符合计算题的特征。 | 知识层次: 题目需要应用位错钉扎的基本原理和公式，进行多步计算和单位转换，涉及位错密度与剪切应力的关系，需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，包括理解位错钉扎、位错密度与应力之间的关系，以及应用相关公式进行综合计算。虽然题目提供了必要的公式和数据，但解题过程需要一定的综合分析能力和数学运算技巧。" + }, + { + "idx": 2868, + "question": "Based on the equation $t_{0.95}=\\\\left[\\\\frac{2.85}{\\\\dot{N}G^{3}}\\\\right]^{\\\\frac{1}{4}}$, derive the functional relationship between the recrystallization temperature $T_{R}$ and $G_{0},N_{0},Q_{g}$ and $Q_{n}$.", + "answer": "$t_{0.95}=\\\\Big[\\\\frac{2.85}{\\\\tilde{N}\\\\bar{G}^{3}}\\\\Big]^{\\\\frac{1}{4}}=\\\\Big[\\\\frac{2.85}{N_{0}G_{0}^{3}}\\\\Big]^{\\\\frac{1}{4}}\\\\:\\\\mathrm{exp}\\\\Big(\\\\frac{Q_{n}+3Q_{\\\\ell}}{4k T}\\\\Big)$. Substituting $T=T_{\\\\parallel}\\\\circ\\\\mathcal{t}_{0,85}=1$, we get $$\\\\exp\\\\Big(\\\\frac{Q_{n}+3Q_{s}}{4k T_{\\\\mathrm{R}}}\\\\Big)=\\\\Big[\\\\frac{2,85}{N_{0}G_{0}^{3}}\\\\Big]^{-\\\\frac{1}{4}},\\\\frac{Q_{n}+3Q_{\\\\mathrm{g}}}{4k T_{\\\\mathrm{R}}}=-\\\\frac{1}{4}\\\\ln\\\\frac{2.85}{N_{0}G_{0}^{3}},$$ Therefore, $T_{\\\\mathbb{R}}=-\\\\frac{Q_{n}+3Q_{g}}{k\\\\ln\\\\Bigl(\\\\frac{2.85}{N_{0}G_{0}^{3}}\\\\Bigr)}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于给定的方程推导出再结晶温度与其他变量之间的函数关系，解答过程涉及公式变换和数学推导，最终得出一个具体的表达式，符合计算题的特征。 | 知识层次: 题目需要多步计算和公式推导，涉及多个变量（G0, N0, Qg, Qn）的关联和综合分析，要求对再结晶温度与这些参数之间的函数关系有较深的理解和应用能力。虽然不涉及复杂的机理分析或创新设计，但已超出简单应用的范围。 | 难度: 在选择题中属于高难度，需要理解复杂的多变量关系并进行多步推导计算。题目涉及多个变量（G0, N0, Qg, Qn）的相互作用，要求考生能够综合运用材料科学中的再结晶理论、Arrhenius方程和对数运算等知识。解题步骤包括指数转换、对数运算和代数重组，且需要准确理解物理意义与数学表达式的对应关系。这种复杂度和深度在选择题型中属于最高难度级别。" + }, + { + "idx": 2869, + "question": "Given that the Tm of Fe is 1538°C, estimate the minimum recrystallization temperature of Fe.", + "answer": "According to the empirical formula, the recrystallization temperature Tr≈0.4Tm. Therefore, the minimum recrystallization temperature of Fe is Tr=0.4×(1538+273)=724.4(K)=451.4(°C). In production, to improve efficiency, the actual recrystallization annealing temperature in factories is usually selected as Tr+(100~200)(°C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（0.4×(1538+273)）并应用经验公式（Tr≈0.4Tm）来求解铁的再结晶温度，属于典型的计算题类型。答案中给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查对经验公式的直接应用和简单计算，涉及将熔点转换为绝对温度并进行基本乘法运算，属于基本公式的直接套用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的经验公式（Tr≈0.4Tm）进行简单计算，无需额外的概念理解或复杂的解题步骤。属于单一公式直接计算的类型，因此难度等级为1。" + }, + { + "idx": 2870, + "question": "Given that the Tm of Cu is 1083°C, estimate the minimum recrystallization temperature of Cu.", + "answer": "According to the empirical formula, the recrystallization temperature Tr≈0.4Tm. Therefore, the minimum recrystallization temperature of Cu is Tr=0.4×(1083+273)=542.4(K)=269.4(°C). In production, to improve efficiency, the actual recrystallization annealing temperature in factories is usually set at Tr+(100~200)(°C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（使用0.4Tm的公式）并给出具体温度结果，答案呈现了完整的计算过程和单位转换，符合计算题的特征。 | 知识层次: 题目主要考查对经验公式的直接应用和简单计算，涉及将熔点转换为绝对温度并进行基本乘法运算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用一个基本公式（Tr≈0.4Tm）并进行简单的温度单位转换，但解题步骤直接且明确，不需要复杂的推理或多步骤计算。因此，在选择题型内属于较低难度。" + }, + { + "idx": 2871, + "question": "Given a $1~\\\\mathrm{cm}^{3}$ brass sample annealed at $700\\\\textcircled{1}$ with an initial grain diameter of $2.16\\\\times10^{-3}~\\\\mathrm{cm}$, the grain boundary energy of brass is $0.5J/\\\\mathfrak{m}^{2}$. A calorimeter measured a total heat release of 0.035J after holding for $2\\\\mathtt{h}$. Determine the grain size after holding for $2\\\\mathtt{h}$.", + "answer": "Assuming the heat released after holding for $2\\\\textrm{h}$ is due to grain growth, where the reduction in total grain boundary area releases energy. From quantitative metallography, the relationship between the interfacial area per unit volume $S_{V}$ and the grain diameter $d$ on the cross-section is $S_{v}={\\\\frac{2}{d}}$. Therefore, $$\\\\scriptstyle Q={\\\\Big(}{\\\\frac{2}{d_{1}}}-{\\\\frac{2}{d_{2}}}{\\\\Big)}\\\\gamma,\\\\quad{\\\\frac{1}{d_{2}}}={\\\\frac{1}{d_{1}}}-{\\\\frac{Q}{2\\\\gamma}}$$Substituting the corresponding data, we obtain $$d_{z}=8.9\\\\times10^{3}(\\\\mathrm{cm)}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶粒尺寸，答案给出了具体的计算过程和最终数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括理解晶界能与晶粒尺寸的关系、应用定量金相学公式进行计算，以及综合分析热释放与晶粒生长的关系。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和数学运算技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如晶界能、晶粒生长热力学关系）并进行多步计算（包括代数转换和单位换算）。题目要求将理论公式与实验数据结合，综合分析得出最终晶粒尺寸，涉及中等应用层次的知识点。虽然选项提供了计算路径，但步骤和概念关联的复杂度仍使其高于基础计算题。" + }, + { + "idx": 2872, + "question": "Industrial pure aluminum was rolled into strips with large deformation at room temperature, and the measured room-temperature mechanical properties were those of the cold-worked state. It was found from the table that the recrystallization temperature of industrial pure aluminum is $T_{\\\\mathbb{F}}=150~\\\\mathrm{\\\\textdegree}$. However, when the aforementioned industrial pure aluminum strip was heated to $100^{\\\\circ}C$, held for 16 days, and then cooled to room temperature before measuring its strength again, a significant decrease in strength was observed. Please explain the reason.", + "answer": "The recrystallization temperature of industrial pure aluminum $T_{\\\\mathbb{R}}=150^{\\\\circ}C$ found in the table refers to the temperature at which recrystallization is completed after annealing for $^\\\\textrm{\\\\scriptsize1h}$. In reality, besides the annealing temperature, the holding time also affects the recrystallization process. For metal materials subjected to large cold deformation, even when annealed at $T{<}T_{\\\\mathbb{R}}$, recrystallization can still occur if the holding time is sufficient. Two methods can be used to determine this: $\\\\textcircled{1}$ metallographic examination; $\\\\textcircled{2}$ substituting the known $T_{1},t_{1},t_{2},Q$ into the formula $\\\\frac{t_{1}}{t_{2}}=\\\\mathrm{e}^{-\\\\frac{Q}{R}(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}})}$ to solve for $\\\\pmb{T_{2}}$, and comparing it with $100\\\\mathrm{\\\\mathcal{C}}$ to determine whether recrystallization has occurred.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释工业纯铝在低于再结晶温度加热后强度显著下降的原因，答案提供了详细的文字解释和论述，包括再结晶温度的定义、保温时间的影响以及两种确定再结晶是否发生的方法。这符合简答题的特征，即需要文字解释和论述。 | 知识层次: 题目需要综合运用材料科学中的多个知识点，包括冷加工、再结晶温度、退火时间和温度对再结晶过程的影响，以及通过公式计算和比较来判断再结晶是否发生。这涉及到对材料微观结构变化机理的深入理解和分析，需要较高的认知能力和思维深度。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2873, + "question": "Given that H70 brass [w(Zn)=30%] requires 1 hour to complete recrystallization at a constant temperature of 400°C, and 2 hours at 390°C, calculate the time required to complete recrystallization at a constant temperature of 420°C.", + "answer": "Recrystallization is a thermally activated process, so the recrystallization rate; v_R = A exp(-Q/RT), and the recrystallization rate is inversely proportional to the time t required to achieve a certain volume fraction, i.e., v_R ∝ 1/t. 1/t = A' exp(-Q/RT) When recrystallization of the same degree occurs at two different constant temperatures, t1/t2 = e^(-Q/R (1/T2 - 1/T1)) Taking the natural logarithm on both sides: ln(t1/t2) = -Q/R (1/T2 - 1/T1). Similarly, ln(t1/t3) = -Q/R (1/T3 - 1/T1). Thus, (ln(t1/t2)) / (ln(t1/t3)) = (1/T2 - 1/T1) / (1/T3 - 1/T1) Substituting the corresponding data, we obtain t3 = 0.26 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在420°C下完成再结晶所需的时间。解答过程中涉及到了热激活过程的公式推导、对数运算和数值代入计算，这些都是计算题的典型特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解再结晶过程的动力学关系，并运用对数变换和温度-时间关系进行综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及热激活过程的速率方程、比例关系的推导、对数运算以及温度与时间的综合计算。解题步骤包括建立方程、代入数据、解方程等多个步骤，需要较强的综合分析能力和数学运算能力。虽然题目提供了部分解题思路，但整体计算过程较为复杂，属于综合性计算问题。" + }, + { + "idx": 2874, + "question": "Explain how the following factors affect $G_{0},N_{0},Q_{8}$, and $Q_{n}$: degree of pre-deformation; original grain size; metal purity.", + "answer": "The driving force for primary recrystallization is the distortion energy of the crystal after deformation. The transition of the crystal from the high-energy state after distortion to the low-energy state of annealing is a spontaneous trend. However, this change in energy state requires atoms to overcome a potential barrier $\\\\Delta E$, the height of which depends on the lattice distortion energy after deformation. When the distortion energy is high, $\\\\Delta E$ decreases, and the nucleation and growth activation energies $\\\\mathbf{Q}_{\\\\mathfrak{n}}, \\\\mathbf{Q}_{\\\\mathfrak{g}}$ both decrease, thereby accelerating the recrystallization rate. Therefore, all factors affecting the distortion energy after deformation will influence $\\\\mathbf{Q}_{\\\\mathbf{n}}, \\\\mathbf{Q}_{\\\\mathbf{\\\\tilde{g}}}$, and $T_{\\\\mathsf{R}}$. From the above analysis, within a certain range of deformation, the higher the degree of pre-deformation and the finer the original grain size, the greater the distortion energy after deformation, and the lower $Q_{\\\\mathfrak{n}}, Q_{\\\\mathfrak{g}}$ will be. The effect of metal purity on $\\\\mathbf{Q}_{\\\\mathrm{n}}, \\\\mathbf{Q}_{\\\\mathrm{g}}$ can be considered from two aspects. On one hand, impurities increase the distortion energy, reducing $Q_{\\\\mathrm{n}}$ and $\\\\mathbf{Q}_{\\\\mathrm{g}}$. On the other hand, impurities also hinder interface migration, increasing $\\\\mathbf{\\\\hat{Q}}_{\\\\mathrm{n}}, \\\\mathbf{\\\\hat{Q}}_{\\\\mathrm{g}}$. These two opposing effects coexist, and the dominant one determines the outcome. $\\\\aleph_{\\\\mathfrak{g}}\\\\mathrm{G}_{\\\\mathfrak{o}}$ is only related to the intrinsic nature of the metal and is not significantly affected by the degree of pre-deformation, original grain size, or metal purity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个因素对材料科学中特定参数的影响，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求解释多个因素（预变形程度、原始晶粒尺寸、金属纯度）对再结晶过程中关键参数（G0、N0、Q8、Qn）的影响机制，涉及变形能、激活能等概念的关联分析，需要综合运用材料科学原理进行推理和解释，思维过程较为深入和复杂。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用多个材料科学概念（如变形能、再结晶驱动力、激活能等），并进行复杂的机理分析和推理。正确选项不仅需要理解各因素（预变形程度、原始晶粒尺寸、金属纯度）对变形能的影响，还需要分析这些因素如何通过改变激活能（Qn, Qg）来影响再结晶过程。此外，题目还涉及金属纯度对激活能的双重影响机制（降低变形能 vs 阻碍界面迁移），这需要考生具备深入的材料科学机理知识和综合分析能力。在选择题型中，这种需要多维度推理和复杂机理解释的题目属于最难的一类。" + }, + { + "idx": 2875, + "question": "In a metal with a dislocation density of $\\\\mathrm{10^{12}/cm^{2}}$ after cold deformation, there exist second-phase particles that do not aggregate or grow upon heating, with a volume fraction $\\\\varphi{=}1\\\\%$ and a radius of $1\\\\mu\\\\mathfrak{m}$. Can the presence of these second-phase particles completely prevent recrystallization of this metal upon heating? (Given $G{=}10^{5}\\\\mathrm{MPa}$, $\\\\pmb{b=0.3\\\\mathrm{nm}}$, and interfacial energy ${\\\\pmb\\\\sigma}{=}0,5\\\\mathrm{J}/\\\\uppi^{2}$.)", + "answer": "The driving force for recrystallization $$F=G b^{2}\\\\left(\\\\rho-\\\\rho_{\\\\circ}\\\\right)\\\\approx G b^{2}\\\\rho=10^{11}\\\\times(3\\\\times10^{-10})^{2}\\\\times10^{16}=9\\\\times10^{7}({\\\\mathrm{N/m}}^{2})$$The resistance to recrystallization $$f={\\\\frac{3\\\\varphi}{2r}}{\\\\sigma}={\\\\frac{3}{2}}\\\\times{\\\\frac{0.01}{{\\\\bar{1}}\\\\times}}{\\\\frac{0.01}{10^{-6}}}\\\\times0.5=7.5\\\\times10^{3}({\\\\mathrm{N/m^{2}}})$$$F{\\\\gg}f$, so the presence of these second-phase particles cannot completely prevent recrystallization.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解答问题，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用材料科学中的位错密度、驱动力和阻力等概念进行综合分析。虽然计算过程较为直接，但需要理解各个参数之间的关系并进行适当的近似处理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及金属的再结晶驱动力和阻力计算，需要掌握位错密度、第二相粒子体积分数、半径等概念，并进行多步计算和综合分析。虽然计算步骤较多，但在选择题型中属于中等应用层次，需要将多个知识点关联起来进行判断。" + }, + { + "idx": 2876, + "question": "For an Fe-3%Si alloy containing MnS particles with a radius of 0.05μm and a volume fraction of 0.01, during the annealing process below 850°C, when the average grain diameter of the matrix reaches 6μm, normal grain growth stops. Analyze the reason for this phenomenon.", + "answer": "For silicon steel sheets containing MnS particles with a radius of 0.05μm and a volume fraction of 0.01 during recrystallization, the limiting grain diameter is calculated as: D_lim = (4r)/(3φ) = (4/3) × (0.05/0.01) = 6.67μm. It is precisely due to the presence of these dispersed particles that when the silicon steel sheet is annealed below 850°C, normal grain growth stops once the average grain diameter of the matrix reaches 6μm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析现象的原因，答案提供了详细的文字解释和论述，涉及材料科学中的晶粒生长机制和分散颗粒的影响，属于需要深入分析和解释的简答题类型。 | 知识层次: 题目要求分析Fe-3%Si合金在退火过程中晶粒生长停止的现象，涉及分散相粒子对晶粒生长的抑制作用。需要理解Zener钉扎效应的原理，并运用公式计算极限晶粒尺寸，同时结合材料的具体参数进行综合分析。这需要较高的推理分析和机理解释能力，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2877, + "question": "Briefly describe the driving forces of primary recrystallization and secondary recrystallization", + "answer": "The driving force of primary recrystallization is the elastic distortion energy of the matrix, while the driving force of secondary recrystallization comes from the reduction of interfacial energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述两种再结晶的驱动力，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对初级再结晶和次级再结晶驱动力的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个不同的概念（初级再结晶和次级再结晶），但正确选项直接给出了两者的驱动力定义，不需要复杂的推理或比较分析。考生只需准确记忆并区分这两个概念的基本原理即可作答。因此，该题目属于\"概念解释和描述\"层次，对应难度等级2。" + }, + { + "idx": 2878, + "question": "W has a very high melting point (Tm=3410°C) and is often chosen as the heating element for incandescent light bulbs. However, when large grains spanning the filament exist, the filament becomes brittle and may fracture under the thermal shock of frequent switching. Please introduce a method to extend the filament's lifespan.", + "answer": "Factors affecting the normal growth of recrystallized grains, besides temperature, include the presence of finely dispersed second-phase particles, which play a significant role in grain boundary migration. For example, ThO2 second-phase particles can be formed in the tungsten filament to hinder grain growth during high-temperature operation. If the volume fraction of ThO2 particles is φ and the particle radius is r, the limiting grain size is given by: Dlim=4r/(3φ(1+cosα)), where α is the contact angle. Therefore, by selecting appropriate φ and r, Dlim can be minimized. Grain refinement can enhance strength while maintaining a high level of toughness, effectively extending the filament's service life.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求介绍一种方法来延长灯丝的寿命，答案提供了详细的文字解释和论述，包括第二相粒子的作用、计算公式的应用以及晶粒细化的效果，符合简答题的特征。 | 知识层次: 题目要求分析钨丝灯寿命问题，并提出解决方案。答案涉及多相颗粒对晶界迁移的阻碍作用、晶粒尺寸限制公式的应用，以及通过参数选择优化材料性能。这需要综合运用材料科学知识，进行推理分析和机理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解钨丝高温脆化的机理，还需要综合运用材料科学中关于晶粒生长、第二相粒子强化等复杂概念。正确选项涉及多个变量的数学关系式(Dlim=4r/(3φ(1+cosα)))，需要考生具备将理论公式与实际工程问题相结合的能力。此外，题目要求从微观机理推导宏观性能改善（强度与韧性的平衡），这种跨尺度分析在选择题中属于最复杂的认知要求。" + }, + { + "idx": 2879, + "question": "In engineering, it is often considered that the grain size of steel does not grow when heated to 760°C, but will significantly grow at 870°C. If the original grain diameter of the steel is 0.05 mm, the empirical formula for grain growth is D^(1/n)−D0^(1/n)=c t, where D is the grain diameter after growth; D0 is the original grain diameter; c is the proportionality constant; t is the holding time. Given that at 760°C, n=0.1, c=6×10^(−16), find the grain diameter of steel with a carbon content of 0.8% after holding at 760°C for 1 hour.", + "answer": "At 760°C: D^(1/n)=D0^(1/n)+c t=(0.05)^10+6×10^(−16)×60=13.37×10^(−14). D=0.0516(mm). Therefore, the grain has essentially not grown.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求应用给定的经验公式进行数值计算，以确定钢在特定条件下的晶粒直径。解答过程涉及代入数值、计算指数和求解最终结果，这些都是计算题的典型特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，无需多步推理或综合分析。虽然需要理解晶粒生长的经验公式，但计算过程相对直接，属于简单应用层次。 | 难度: 在选择题型内，该题目仅涉及单一公式的直接套用和简单计算。解题步骤非常直接，只需将给定数值代入经验公式并进行基本的幂运算即可得出答案。无需理解多个概念或进行复杂的分析，因此属于最低难度等级。" + }, + { + "idx": 2880, + "question": "How to distinguish between cold and hot working?", + "answer": "The recrystallization temperature is the dividing line between cold and hot working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何区分冷加工和热加工，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查冷加工和热加工的基本区分标准，即再结晶温度的概念，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅考察对基础定义的记忆，即区分冷热加工的分界线是再结晶温度。不需要解释或分析，只需识别正确选项。属于最基本的概念记忆题，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 2881, + "question": "In practice, it is often considered that the grain size of steel will significantly grow when heated to 870°C. If the original grain diameter of the steel is 0.05 mm, the empirical formula for grain growth is D^(1/n)−D0^(1/n)=c t, where D is the grown grain diameter; D0 is the original grain diameter; c is the proportional constant; t is the holding time. Given that at 870°C, n=0.2, c=2×10^(−8), find the grain diameter of steel with 0.8% carbon content after holding at 870°C for 1 hour.", + "answer": "At 870°C: D^5=(0.05)^5+2×10^(−8)×60=1.513×10^(−6) D=0.0686(mm). Compared to the original grain diameter, it has significantly grown (approximately 37%).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出具体的数值结果（0.0686 mm），属于典型的计算题。 | 知识层次: 题目需要进行多步计算，包括代入公式、单位转换和数值求解，同时需要理解晶粒生长的经验公式及其参数的含义。虽然不涉及复杂的综合分析或机理解释，但比简单的直接套用公式更具挑战性。 | 难度: 在选择题中属于中等偏上难度，需要理解并应用晶粒生长经验公式，进行多步骤计算（包括指数运算和单位转换），同时需要综合分析计算结果与原始数据的对比关系。题目涉及材料科学中的具体应用场景，要求考生具备将理论公式与实际问题相结合的能力。" + }, + { + "idx": 2882, + "question": "Assuming we add Na2O with w(Na2O)=10% to SiO2, please calculate the ratio of oxygen to silicon.", + "answer": "There are 90at% SiO2 and 10at% Na2O, so O:Si = (0.9×2 + 0.1) : 0.9 = 2.111. Since O:Si = 2.111 < 2.5, there is a good tendency for glass formation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算氧与硅的比例），并应用了化学计量公式。答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需将给定的百分比转换为原子百分比并进行简单的比例计算，无需多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目涉及基本公式应用和简单计算，仅需理解氧硅比的概念并进行直接套用计算，无需复杂步骤或多公式组合。" + }, + { + "idx": 2883, + "question": "In a eutectic reaction of the Mg-Ni system, let C1 be the hypoeutectic alloy and C2 be the hypereutectic alloy. The mass fractions of the proeutectic phases in these two alloys are equal. Find the relationship between C1 and C2.", + "answer": "According to the lever rule, the mass fractions of the proeutectic phases are: α_pro=(23.5-C1)/23.5 β_pro=(C2-23.5)/(54.6-23.5) Given that α_pro=β_pro, combining the above equations yields: C2=54.6-1.323C1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用（杠杆定律）来求解C1和C2之间的关系，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，并建立两个合金成分之间的关系。虽然计算过程不复杂，但需要理解共晶反应和杠杆定律的应用，并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解共晶反应、杠杆定律等概念，并进行多步计算和综合分析。题目要求建立两个合金成分之间的关系，涉及多个变量的计算和方程组合，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 2884, + "question": "What are the main differences in the microstructure between dynamic recrystallization and static recrystallization?", + "answer": "Although the microstructure after dynamic recrystallization also consists of equiaxed grains, the grain boundaries are serrated, and the grains contain subgrains divided by dislocation tangles. This differs from the grains produced by static recrystallization, which have a very low dislocation density. Therefore, the strength and hardness of dynamically recrystallized structures with the same grain size are higher than those of statically recrystallized ones. The grain size after dynamic recrystallization is proportional to the flow stress. Additionally, the lower the strain rate and the higher the deformation temperature, the larger and more complete the grains after dynamic recrystallization will be.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释动态再结晶和静态再结晶在微观结构上的主要差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较动态再结晶和静态再结晶的微观结构差异，涉及对两种再结晶过程的深入理解、微观结构的详细描述（如锯齿状晶界、亚晶粒等）、以及力学性能差异的解释。这需要综合运用材料科学中的再结晶理论、位错理论以及变形条件对微观结构的影响等多方面知识，并进行推理分析和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅掌握动态再结晶和静态再结晶的基本概念，还需要深入理解两者微观结构的差异及其对材料性能的影响机制。正确选项涉及多个复杂知识点（如锯齿状晶界、亚晶结构、位错密度与强度的关系、流变应力和晶粒尺寸的关系等），并要求考生能够综合运用这些知识进行推理分析。此外，题目还考察了应变速率和变形温度对动态再结晶晶粒尺寸的影响，这需要考生具备机理层面的深入理解和复杂现象的全面分析能力。在选择题型中，这种需要多维度知识整合和机理深度解释的题目属于最难的一类。" + }, + { + "idx": 2885, + "question": "What is a copolymer?", + "answer": "A polymer formed by the polymerization of two or more monomers is called a copolymer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“copolymer”进行定义和解释，答案以文字形式给出，属于简答题类型 | 知识层次: 题目考查基本概念的记忆和理解，仅需要回答共聚物的定义，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别“copolymer”的基本定义，属于基础概念记忆层次。题目直接给出定义，无需解释或分析，解题步骤简单，符合等级1的“基本定义简答”标准。" + }, + { + "idx": 2886, + "question": "In a eutectic reaction of the Mg-Ni system, let C1 be the hypoeutectic alloy and C2 be the hypereutectic alloy. The total amount of α in alloy C1 is 2.5 times that in alloy C2. Determine the compositions of C1 and C2.", + "answer": "Let the total amount of α in C1 be α1, then: α1=(54.6-C1)/54.6 Let the total amount of α in C2 be α2, then: α2=(54.6-C2)/54.6 According to the given condition, α1=2.5α2, that is: (54.6-C1)/54.6=2.5*(54.6-C2)/54.6 Substituting C2=54.6-1.323C1 into the above equation, we can solve for: C1=w(Ni)=12.7% C2=w(Ni)=37.8%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来解决问题，答案给出了具体的计算过程和最终数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要运用杠杆定律进行合金成分计算，并通过建立方程求解未知数。虽然不涉及复杂的机理分析或创新设计，但需要综合理解和应用相图知识。 | 难度: 在选择题中属于中等偏上难度，需要理解共晶反应、亚共晶和过共晶合金的概念，并运用杠杆定律进行多步计算。题目要求建立两个合金中α相含量的关系式，并通过代数运算求解成分，涉及综合分析和计算能力。虽然题目提供了正确选项，但推导过程需要较强的概念关联和计算能力，在选择题型中属于较复杂的计算问题。" + }, + { + "idx": 2887, + "question": "If O:Si ≈ 2.5 is the criterion for glass-forming tendency, what is the maximum amount of Na2O that can form a glass?", + "answer": "Let the maximum content of Na2O be x, and SiO2 = 1 - x. According to (x + 2(1 - x)) / (1 - x) ≤ 2.5, we get (2 - x) / (1 - x) ≤ 2.5. Further derivation yields 1 + 1 / (1 - x) ≤ 2.5; 1 / (1 - x) ≤ 1.5; 1 - x ≥ 1 / 1.5; x ≤ 1 / 3. Therefore, the maximum amount of Na2O that can form a glass is 1/3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最大Na2O含量，答案展示了具体的计算过程和推导步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和公式应用，涉及玻璃形成倾向的判定标准（O:Si ≈ 2.5）以及Na2O和SiO2的比例关系。虽然计算过程较为直接，但需要理解并应用相关概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃形成倾向的O:Si比例标准，并进行多步数学推导和不等式求解。虽然题目给出了明确的解题路径，但仍需要较强的概念关联和综合分析能力。" + }, + { + "idx": 2888, + "question": "Based on the shown CaO·ZrO2 phase diagram, write down all the isothermal three-phase transformations.", + "answer": "There are three isothermal three-phase transformations in the shown ZrO2-σ·CaO phase diagram: peritectic reaction: L+T-ZrO3→C-ZrO2; eutectic reaction: L→(C-ZrO2+ZrCaO3); eutectoid reaction: T-ZrO2→M-ZrO2+C-ZrO2; where L represents liquid phase, T represents tetragonal, C represents cubic, M represents monoclinic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据相图写出所有等温三相转变，答案需要文字解释和论述，没有选项或计算要求 | 知识层次: 题目要求基于相图识别等温三相转变，需要理解相图的基本原理和三相反应的类型（包晶、共晶、共析），并能将相图中的信息与这些概念关联起来。这需要一定的综合分析能力，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求基于相图识别所有等温三相转变，这需要深入理解相图的结构和符号含义。其次，正确选项涉及多个专业术语（如peritectic、eutectic、eutectoid反应）和相变类型（L, T-ZrO3, C-ZrO2等），需要考生具备较强的相图分析能力和材料科学专业知识。此外，解题过程需要综合分析和关联多个概念，而不仅仅是简单的记忆或单一概念的应用。因此，在选择题型中，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 2889, + "question": "What is a homopolymer?", + "answer": "A polymer formed by the polymerization of a single monomer is called a homopolymer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"homopolymer\"进行定义和解释，答案以文字形式给出，属于简答题类型。 | 知识层次: 题目考查对聚合物基本分类的记忆和理解，仅需回答单一概念的定义，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆并识别“homopolymer”的基本定义，属于基础概念记忆的简单题目。正确选项直接给出了定义，无需复杂推理或比较分析，符合等级1的基本定义简答标准。" + }, + { + "idx": 2890, + "question": "Using the data from the previous question, assuming the alloy composition is Al-0.5%Cu and there is no convection in the liquid, calculate the temperature gradient required to maintain a planar solid-liquid interface.", + "answer": "G≥(m w0 R(1-k0))/(D k0)=(320×0.005×3×10^-4×(1-0.16))/(3×10^-5×0.16)=84℃/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和参数代入，需要理解温度梯度与合金成分、扩散系数等参数之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解合金凝固理论中的多个关键概念（如成分过冷、溶质分配系数等），并正确应用公式进行多步骤计算。题目要求将理论知识与具体参数代入相结合，且计算过程涉及单位换算和负号处理，在选择题型中属于需要较强综合分析能力的题目。" + }, + { + "idx": 2891, + "question": "Using the data from the previous question, assuming the alloy composition is Al-2%Cu and there is no liquid convection, calculate the interface temperature at the beginning of solidification", + "answer": "T=T0-m(w0/k0)=660.37-320×(0.02/0.16)=620.37℃", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需理解公式中各参数的含义并进行数值代入计算。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算（T=T0-m(w0/k0)），无需额外的理解或组合多个公式。题目提供了所有必要的数据，解题步骤简单直接，属于最基础的难度等级。" + }, + { + "idx": 2893, + "question": "What is homoaddition polymerization?", + "answer": "A polymerization reaction involving a single monomer is called homoaddition polymerization, abbreviated as homoaddition; the resulting polymer has the same composition as its monomer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"homoaddition polymerization\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即homoaddition polymerization的定义和基本特征，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求对基础定义进行简答，正确选项直接给出了homoaddition polymerization的定义和缩写形式，属于最基础的概念记忆层次。不需要任何解释或分析步骤，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2894, + "question": "What is co-condensation?", + "answer": "The polycondensation reaction involving two or more monomers is called co-condensation polymerization, abbreviated as co-condensation, and the resulting polymer composition differs from the monomers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"co-condensation\"进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即对co-condensation的定义和基本原理的掌握。 | 难度: 在选择题型中，该题目仅考察对\"co-condensation\"这一基础概念的定义记忆，属于最基本的概念简答。题目直接给出了定义描述，不需要进行任何概念比较或复杂推理，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2895, + "question": "Briefly describe the advantages of polymer alloying", + "answer": "Through alloying, polymers can overcome certain performance weaknesses of single-component polymers (homopolymers). For example, polypropylene (PP) is prone to brittle fracture at low temperatures, but blending with butadiene rubber (BR) can significantly improve the toughness of polypropylene. It can also broaden the applications of polymers. For instance, blending polyethylene (PE) with different densities can produce foam plastics with various properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述聚合物合金化的优势，答案通过文字解释和举例进行了论述，符合简答题的特征。 | 知识层次: 题目要求简要描述聚合物合金化的优势，涉及对基本概念的理解和简单应用，如通过具体例子（PP与BR的混合）说明性能改进，属于直接套用基本原理进行解释的范畴。 | 难度: 在选择题中属于中等难度，题目要求考生理解聚合物合金化的基本概念，并能通过具体实例（如PP与BR的混合、PE不同密度的混合）来说明其优势。这需要考生不仅掌握基本概念，还能应用这些概念解释实际案例，但不需要进行复杂的分析或计算。" + }, + { + "idx": 2896, + "question": "Calculate the relative amounts (in mol%) of monoclinic ZrO2 solid solution (Monoclinic ZrO2 SS) and cubic ZrO2 solid solution (Cubic ZrO2 SS) at room temperature for a CaO–ZrO2 ceramic with w(CaO)=4%. Assume that the solubilities of monoclinic ZrO2 solid solution and cubic ZrO2 solid solution at room temperature are 2mol% CaO and 15mol% CaO, respectively.", + "answer": "Using the conversion formula between mole fraction and mass fraction, the mole fraction corresponding to w(Ca)=4% can be calculated: xA = (wA/ArA)/(wA/ArA + wB/ArB) = (4/(40+16))/(4/(40+16) + 96/(91+16×2)) ≈ 0.08; thus, 4wt% CaO = 8mol% CaO. Moreover, it can be observed from the figure that the solubility limit changes little below 900°C, yielding: monoclinic phase % = (xcub - x)/(xcub - xmono) × 100% = (15 - 8)/(15 - 2) × 100% = 53.8%; cubic phase % = (x - xmono)/(xcub - xmono) × 100% = (8 - 2)/(15 - 2) × 100% = 46.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及摩尔百分比的计算和相图分析，答案展示了具体的计算步骤和结果。 | 知识层次: 题目需要进行多步计算，包括摩尔分数转换和相组成计算，涉及对相图的理解和公式应用，需要综合分析不同相在特定条件下的溶解度限制。虽然不涉及复杂的机理分析或创新设计，但超出了简单应用的范围，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要完成多步骤计算（包括摩尔分数转换和相比例计算），同时需要理解溶解度限和相图概念。虽然题目提供了关键参数，但解题过程涉及多个公式的综合应用和逻辑推导，对考生的计算能力和概念关联能力有较高要求。" + }, + { + "idx": 2897, + "question": "Using the data from the previous question, assuming the alloy composition is Al-0.5%Cu and there is no liquid convection, calculate the interface temperature at the beginning of solidification", + "answer": "T=T0-m(w0/k0)=660.37-320×(0.005/0.16)=650.37℃", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需理解并套用给定的公式即可得出结果。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求直接套用给定的公式（T=T0-m(w0/k0)）进行计算，无需额外的步骤或复杂的分析。学生只需正确代入数值并执行简单的算术运算即可得出答案。因此，在选择题型内，该题目的难度较低，属于等级1。" + }, + { + "idx": 2898, + "question": "What is a quasicrystal?", + "answer": "Quasicrystals lack translational symmetry but are a type of solid atomic aggregation state that exhibits periodic order similar to crystalline materials. In three-dimensional space, they possess not only 5-fold symmetry axes but also 8, 10, or 12-fold symmetry axes, with diffraction patterns showing non-crystallographic symmetry. Most quasicrystalline phases are metastable and can only be obtained through rapid solidification methods. It is well known that periodic tiling of a plane can be achieved with equilateral triangles, squares, or regular hexagons, whereas regular pentagons cannot tile the plane without overlaps or gaps.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“quasicrystal”进行定义和解释，答案提供了详细的文字描述和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查准晶体的基本定义、对称性特征和形成条件等基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项对quasicrystal的定义和特性进行了较为详细的解释，包括其对称性、衍射图案特征以及形成条件等。这要求考生不仅记住基本定义，还需要理解并描述相关概念，而不仅仅是简单的定义复述。因此，在选择题型内，该题目属于等级2的难度。" + }, + { + "idx": 2899, + "question": "Briefly describe the characteristics of nanomaterials from the perspective of internal microstructure.", + "answer": "Nanomaterials refer to materials that have at least one dimension in the three-dimensional space at the nanoscale or are composed of them as basic units. According to dimensionality, the basic units of nanomaterials can be divided into three categories: (1) Zero-dimensional, meaning all three spatial dimensions are at the nanoscale, such as nanopowder materials; (2) One-dimensional, meaning two dimensions in space are at the nanoscale, such as nanowires, nanorods, nanotubes, etc.; (3) Two-dimensional, meaning one dimension in three-dimensional space is at the nanoscale, such as ultrathin films, multilayer films, and superlattices. Due to the ultrafine size of nanoparticles, they are on the same order of magnitude as the wavelength of light waves, neutron wavelength, mean free path, etc., resulting in quantum size effects, small size effects, surface effects, macroscopic quantum tunneling effects, and when the volume fraction exceeds $50\\%$, the influence of grain boundary structure causes nanomaterials to exhibit unique mechanical, physical, and chemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述纳米材料从内部微观结构角度的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目主要考查对纳米材料基本概念的记忆和理解，包括其定义、分类（零维、一维、二维）以及由于尺寸效应带来的特性（量子尺寸效应、小尺寸效应、表面效应等）。这些内容属于基础概念和基本原理的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及了纳米材料的基本定义和分类，但需要考生理解和记忆多个概念（如零维、一维、二维纳米材料的具体例子）以及纳米材料的基本特性（如量子尺寸效应、小尺寸效应等）。这些知识点虽然属于基础概念记忆层次，但需要考生对纳米材料的内部微观结构有较为全面的理解，而不仅仅是简单的定义记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2900, + "question": "A ternary alloy with mass fractions of 40% A, 30% B, and 30% C forms a three-phase equilibrium at the eutectic temperature. The compositions of the three phases are as follows: liquid phase (50% A, 40% B, 10% C), α phase (85% A, 10% B, 5% C), and β phase (10% A, 20% B, 70% C). Calculate the fractions of the liquid phase, α phase, and β phase.", + "answer": "First, draw a concentration triangle and mark the compositions of each phase. The alloy composition point is: L% = (57 - 30) / (57 - 10) × 100% = 57.4%; α% = (40 - 35) / (85 - 35) × 100% = 10%; β% = 100% - 57.4% - 10% = 32.6%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解各相的质量分数，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要运用杠杆定律和相图知识进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解三元合金相图的基本概念，掌握杠杆定律在多组分系统中的应用，并进行多步骤计算。题目要求考生能够正确绘制浓度三角形并标记各相组成点，然后通过杠杆定律计算各相的质量分数。虽然题目提供了各相的组成，但计算过程涉及多个变量和步骤，需要较强的综合分析能力。" + }, + { + "idx": 2901, + "question": "Briefly describe the methods of polymer alloying", + "answer": "The preparation methods of polymer alloys can be divided into physical methods and chemical methods. Physical blending methods include dry powder blending, melt blending, and latex blending, with melt blending being the most commonly used. Chemical blending methods mainly include copolymerization-blending and interpenetrating polymer network methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述聚合物合金化的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对聚合物合金制备方法的基本分类和简单描述，主要涉及记忆性知识，如物理方法和化学方法的具体类型及其特点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述聚合物合金化的方法，但正确选项已经提供了明确的分类和具体方法，包括物理方法和化学方法的具体类型。这需要考生不仅记住基本概念，还要理解并区分不同的制备方法。然而，由于选项已经结构化地呈现了信息，不需要考生自行组织复杂的概念体系，因此难度属于等级2。" + }, + { + "idx": 2902, + "question": "Why can stretching improve the crystallinity of crystalline polymers?", + "answer": "From $\\Delta G{=}\\Delta H{-}T\\Delta S$, it is known that the free energy $\\Delta G$ must be less than zero for the crystallization process to proceed spontaneously. When a substance transitions from an amorphous state to a crystalline state, the arrangement of molecules changes from disordered to ordered, which always results in a decrease, i.e., $\\Delta S{<}0$. In this case, $-T\\Delta S{>}0$, while $\\Delta H{<}0$ (exothermic). To ensure $\\Delta G{<}0$, it is necessary that $|\\Delta H|>T|\\Delta S|$. For some polymers transitioning from the amorphous phase to the crystalline phase, $\\vert\\Delta S\\vert$ is large, while the thermal effect of crystallization $\\Delta H$ is small. To satisfy $\\mid\\Delta H\\mid>T\\mid\\Delta S\\mid$, there are only two approaches: lowering $T$ or reducing $\\{\\Delta S\\}$. However, excessively lowering the temperature makes molecular movement difficult, potentially leading to a glassy state instead of crystallization. To reduce $\\mid\\Delta S\\mid$, stretching the polymer before crystallization can be employed, which imparts a certain degree of order to the polymer chains in the amorphous phase. This reduces the corresponding $|\\Delta S|$ during crystallization, enabling the process. Therefore, for crystalline polymers, stretching is beneficial for increasing crystallinity. For example: natural rubber takes decades to crystallize at room temperature, but when stretched, it crystallizes in just a few seconds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么拉伸可以提高结晶聚合物的结晶度，答案通过热力学原理和分子排列变化进行了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释拉伸如何提高结晶性聚合物的结晶度，涉及自由能变化、熵变、焓变等热力学概念的综合运用，以及分子排列有序化的机理分析。需要深入理解并关联多个概念，进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解热力学基本公式（ΔG=ΔH-TΔS），还需要综合运用多个高级概念：1) 理解聚合物从非晶态到晶态转变的熵变特性；2) 分析温度对结晶过程的双重影响；3) 掌握拉伸对分子链有序化的特殊作用机制。解题需要完成复杂的逻辑推理链条：从热力学自发条件推导→分析熵变障碍→提出两种解决方案→排除降温方法的局限性→最终论证拉伸方法的有效性。此外，题目还涉及实际案例（天然橡胶）的机理解释，要求考生能将抽象理论与具体现象结合。这种深度和广度的知识整合能力，以及多步骤的推理要求，使该题在选择题型中达到最高难度水平。" + }, + { + "idx": 2903, + "question": "The crystallization activation energy of amorphous alloys can be determined using the Ozawa plotting method, which utilizes the linear relationship between the crystallization temperature $\\scriptstyle{\\mathcal{T}}_{\\mathbf{z}}$ and the heating rate $^{a}$ measured under different continuous heating conditions. The $\\pmb{T_{x}}$ values for the pre-crystallization phase $\\alpha{\\boldsymbol{-}}\\mathbf{\\overline{{F}}}\\mathbf{e}$ of the amorphous FenBsSis alloy have been measured as shown in the table below. Calculate the activation energy.", + "answer": "Based on the data in the table, plot the graph (see Figure 42), which approximates a straight line. Using the least squares method, the equations of the straight lines are fitted as follows: \\n$$\\n\\\\ln{\\\\frac{T_{x}}{a}}={\\\\frac{46}{T_{x}}}-53\\n$$\\n$$\\n\\\\ln{\\\\frac{T_{x}}{a}}={\\\\frac{49}{T_{x}}}-57\\n$$\\nFrom the slope of the straight lines, the activation energy for the precipitation stage of the ${\\\\mathfrak{a}}{\\\\mathfrak{F}}{\\\\mathfrak{e}}$ pre-crystallization phase is determined to be $(382\\\\sim407)\\\\mathrm{kJ/mol}_{\\\\circ}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出激活能的数值。解答过程中涉及绘制图表、拟合直线方程和从斜率中确定激活能，这些都是典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括绘制图表、拟合直线方程，并通过斜率计算激活能量。这涉及到对Ozawa绘图法的理解和应用，以及对实验数据的综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于高难度，题目涉及多步骤计算和概念关联，需要综合分析表格数据、绘制图形、拟合直线方程，并通过斜率计算激活能量。解题过程复杂，涉及多个变量和计算步骤，对知识掌握深度和计算能力要求较高。" + }, + { + "idx": 2904, + "question": "Explain why crystal structures do not possess 5-fold or higher than 6-fold symmetry axes?", + "answer": "5-fold or higher than 6-fold symmetry axes cannot satisfy the condition of identical surroundings around lattice points, lack translational symmetry, and thus cannot achieve a regularly periodic arrangement of crystal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体结构为何不具备5重或高于6重的对称轴，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求解释晶体结构中不存在5重或高于6重对称轴的原因，这需要综合运用晶体学的基本原理（如平移对称性、点阵理论）进行推理分析，并解释其物理机制。这超出了简单记忆或直接应用的范畴，属于对晶体对称性深层次理解的复杂分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求解释晶体结构中不存在5重或高于6重对称轴的原因，涉及对晶体学基本原理的深入理解，包括点阵的平移对称性和周期性排列的限制条件。正确选项不仅需要识别对称性限制，还需综合运用晶体学知识进行机理解释，这要求考生具备较高的分析推理能力和对复杂现象的全面理解。在选择题型中，此类题目通常需要考生超越简单记忆，进行深层次的概念整合和逻辑推理，因此难度等级为5。" + }, + { + "idx": 2905, + "question": "How to describe the quasicrystalline structure?", + "answer": "The quasicrystalline structure cannot be represented by a unit cell like crystals, meaning it cannot achieve periodicity through translation operations. Currently, the more commonly used model is the tiling method to characterize quasicrystalline structures. For example, a 5-fold symmetric quasicrystalline structure can be constructed using two types of rhombuses with equal side lengths and angles of 36 and 144 degrees (narrow), and 72 and 108 degrees (wide), following specific matching rules.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对quasicrystalline结构进行描述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅要求对准晶结构的基本概念进行解释（如非周期性结构），还需要应用特定的模型（如tiling方法）来具体描述准晶结构，并举例说明如何构建5重对称的准晶结构。这涉及到多步的概念关联和综合分析，超出了单纯记忆基础概念的层次，但尚未达到需要复杂推理或创新设计的程度。 | 难度: 在选择题中属于较高难度，题目要求对准晶结构有深入的理解，包括其与普通晶体的区别、无法通过平移操作实现周期性、以及具体的拼图模型构建方法。此外，还需要掌握特定几何形状（如两种菱形）的角度和匹配规则，这涉及多步概念关联和综合分析。因此，在选择题型内，该题目需要多角度分析论述，属于等级4难度。" + }, + { + "idx": 2906, + "question": "Briefly describe the influencing factors of the glass transition temperature of polymers.", + "answer": "There are many factors affecting the glass transition temperature, usually including (1) chain flexibility; (2) the influence of intermolecular forces; (3) the effect of copolymerization; (4) the influence of plasticizers, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述聚合物玻璃化转变温度的影响因素，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对聚合物玻璃化转变温度影响因素的基本概念记忆和理解，涉及的知识点较为基础，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述影响聚合物玻璃化转变温度的因素，但正确选项已经列出了四个主要因素，考生只需识别和选择这些因素。这需要考生对相关概念有一定的理解和记忆，但不需要进行复杂的分析或比较。因此，该题目在选择题型中属于等级2的难度。" + }, + { + "idx": 2907, + "question": "Briefly describe the method of determining phase boundaries in polymer phase diagrams using scattered light intensity.", + "answer": "For multiphase polymer blends, when the size of the dispersed phase is comparable to the wavelength of visible light (i.e., several hundred nanometers), the scattered light intensity method can be used for measurement. When visible light passes through such materials, strong light scattering occurs, resulting in turbidity. In a single-phase system, there is no abrupt change in scattered light intensity. Therefore, for a binary polymer with composition w, if it is single-phase at low temperatures and undergoes a phase transition to two phases upon heating to a certain temperature ${\\\\bf\\\\cal I}_{1}$, the curve of scattered light intensity versus temperature will show an abrupt change. The temperature at this abrupt change point is often referred to as the 'cloud point,' which is the phase transition temperature. Similarly, the corresponding $T_{2}$ for ${\\\\mathfrak{w}}_{2}$ and $T_{3}$ for $w_{3}$ can be measured. By plotting the cloud points of blends with different compositions against their compositions, the phase boundaries can be obtained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述确定聚合物相图中相边界的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释通过散射光强度测定聚合物相图中相边界的方法，涉及多步概念关联和综合分析。需要理解散射光强度与相变的关系，以及如何通过测量不同组成下的浊点来绘制相边界。这超出了基础概念的记忆和简单应用，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握聚合物相图中相边界的确定方法，涉及散射光强度与相变温度的关系，以及\"云点\"的概念。虽然不需要复杂的计算，但需要对多个概念进行综合理解和关联，才能正确理解并选择答案。" + }, + { + "idx": 2908, + "question": "What is the glass transition temperature of a polymer?", + "answer": "Amorphous linear polymers can be divided into three states based on their mechanical properties at different temperatures: glassy state, high elastic state, and viscous flow state. At lower temperatures, the thermal motion of molecules is limited, preventing not only the movement of entire macromolecular chains but also the movement of chain segments or even individual chain units, causing the entire macromolecule to lose flexibility. In this state, the polymer resembles ordinary silicate glass in a supercooled liquid state, hence it is called the glassy state. The highest temperature (Tg) at which a polymer exhibits the glassy state is called the glass transition temperature, which is the temperature at which the polymer transitions from the high elastic state to the glassy state. During the glass transition, in addition to discontinuous and significant changes in mechanical properties such as the elastic modulus (E) of the polymer, other properties like the expansion coefficient, heat capacity, and dielectric constant also undergo notable changes. Therefore, the glass transition is not a thermodynamic phase transition but rather a state transition under non-equilibrium conditions, which can be regarded as a volume relaxation process. The glass transition temperature is an extremely important property of polymeric materials and serves as the dividing line between plastics and rubbers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释玻璃化转变温度的定义和相关概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对玻璃化转变温度这一基本概念的定义、分类和基本原理的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及了玻璃化转变温度的定义和相关概念，但正确选项提供了较为详细的解释和背景知识，帮助考生理解这一概念。题目要求考生掌握聚合物状态转变的基本原理和玻璃化转变温度的重要性，但不需要进行复杂的分析或比较多个概念。因此，在选择题型内，该题目属于等级2，即概念解释和描述的难度水平。" + }, + { + "idx": 2909, + "question": "Due to the incompleteness of crystallization, crystalline and amorphous regions always coexist in crystalline polymers. The volume fraction crystallinity and density of two crystalline polytetrafluoroethylene samples have been measured as φ₁=51.3%, φ₂=74.2% and ρ₁=2.144 g/cm³, ρ₂=2.215 g/cm³, respectively. Calculate the densities of completely crystalline and completely amorphous polytetrafluoroethylene.", + "answer": "The density of a crystalline polymer ρ = φρ_c + (1-φ)ρ_a, where ρ_c and ρ_a are the densities of the crystalline and amorphous parts of the polymer, respectively, and φ is the volume fraction of the crystalline part. Solving the simultaneous equations: 2.144 = 0.513ρ_c + (1-0.513)ρ_a, 2.215 = 0.742ρ_c + (1-0.742)ρ_a, we obtain ρ_c = 2.296 g/cm³ and ρ_a = 1.984 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解完全结晶和完全无定形聚四氟乙烯的密度，答案也展示了具体的计算过程和结果。 | 知识层次: 题目需要应用密度与结晶度的关系公式，并通过解联立方程来计算完全结晶和非结晶区域的密度。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解聚合物结晶度的概念，并能够建立和求解联立方程。虽然题目提供了明确的公式和步骤，但需要考生具备一定的数学计算能力和对材料科学基础知识的掌握。" + }, + { + "idx": 2910, + "question": "At the same temperature, when the α phase (85% A, 10% B, 5% C) and β phase (10% A, 20% B, 70% C) each account for 50%, estimate the composition of the alloy.", + "answer": "Let the alloy composition be x, which must lie on the line connecting the α-β phase composition points. According to the lever rule: (α/β) = (x - 10%) / (85% - x) = 1; solving gives x = 47.5% A; then, from the concentration triangle, B = 14.5% and C = 38% are obtained.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用（杠杆定律）来求解合金的成分，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要应用杠杆规则进行多步计算，同时需要理解相图中成分点的连接和浓度三角形的概念，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解杠杆规则的应用，进行多步计算，并正确运用浓度三角形概念来推导合金成分。虽然题目提供了明确的解题路径，但涉及多个计算步骤和概念的综合运用，对学生的理解和计算能力有一定要求。" + }, + { + "idx": 2911, + "question": "For an Al-Cu alloy with an atomic fraction of Cu at 4.6%, after solution treatment at 550°C, the α phase contains x(Cu)=2%. When reheated to 100°C and held for a period, the precipitated θ phase spreads throughout the entire alloy volume. The θ phase has an fcc structure with r=0.143nm, and the average spacing between θ particles is 5nm. If the Cu atoms in the α phase can be neglected after θ precipitation, how many Cu atoms does each θ particle contain?", + "answer": "The fcc structure has 4 atoms per unit cell, a=4r/√2=4×0.143/√2=0.404nm. Since x(Cu)=2%, the number of Cu atoms per cm³=0.02×4/(4.04×10⁻⁸)³=1.213×10²¹ atoms/cm³. Therefore, the number of Cu atoms per θ phase particle=1.213×10²¹/8×10¹⁸=151.6 atoms/particle", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算单位晶胞中的原子数、铜原子浓度、以及每个θ相粒子中的铜原子数。答案给出了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，包括固溶体成分计算、晶体结构参数计算、原子间距与体积关系等综合分析。虽然不需要复杂的推理分析或机理解释，但需要将多个知识点结合起来进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如fcc结构、原子分数、相变等）并进行多步计算（包括单位转换、体积计算、原子数量估算等）。虽然题目提供了部分计算步骤，但综合分析要求较高，涉及多个知识点的关联应用。" + }, + { + "idx": 2912, + "question": "The concentration fluctuation equation for spinodal decomposition is given by $C-C_{0}=\\\\mathtt{e}^{R(\\\\lambda)t}\\\\cos{\\\\frac{2\\\\pi}{\\\\lambda}{Z}}$. Find the critical wavelength, where $R(\\\\lambda)=-M\\\\frac{4\\\\pi^{2}}{\\\\lambda}\\\\biggl[\\\\vert G^{\\\\prime}+2\\\\eta Y+\\\\frac{8\\\\pi^{2}K}{\\\\lambda^{2}}\\\\biggr]$; M is the interdiffusion mobility; $\\\\eta$ is the mismatch due to concentration gradient; $Y=\\\\frac{E}{(1-\\\\nu)}$ ($E$ is the elastic modulus, $\\\\nu$ is the Poisson's ratio); $K$ is a constant; $\\\\lambda$ is the wavelength; $Z$ is the distance; $t$ is the time; $\\\\vert G^{\\\\prime}={\\\\frac{\\\\partial^{2}\\\\dot{G_{s}}}{\\\\partial x^{2}}}$ ($G_{s}$ is the free energy of the solid solution, $_x$ represents the composition of the solid solution).", + "answer": "When $R\\\\langle\\\\lambda\\\\rangle=0$, \\n\\n$$\\nC-C_{\\\\mathrm{0}}=\\\\cos\\\\frac{2\\\\pi}{\\\\lambda}Z\\n$$\\n\\nAt this point, the composition fluctuation does not change with time, meaning spinodal decomposition does not occur. Spinodal decomposition can only occur when $R\\\\langle\\\\lambda\\\\rangle>0$, i.e., the $\\\\lambda$ value when $R(\\\\lambda)=0$ is the critical wavelength $\\\\lambda_{c}$. Therefore, \\n\\n$$\\nG^{\\\\prime\\\\prime}+2\\\\eta Y+\\\\frac{8\\\\pi^{2}K}{\\\\lambda_{\\\\odot}^{2}}=0\\n$$\\n\\n$$\\n\\\\lambda_{\\\\mathrm{{c}}}=\\\\Bigl[\\\\frac{-8\\\\pi^{2}K}{\\\\vec{G}^{\\\\eta}+2\\\\eta Y}\\\\Bigr]^{\\\\frac{3}{2}}\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和条件，计算临界波长（critical wavelength）。解答过程涉及公式推导和数值计算，符合计算题的特征。 | 知识层次: 题目需要理解spinodal分解的浓度波动方程，并应用给定的公式进行多步计算以找到临界波长。虽然涉及多个变量和参数，但主要是基于给定的公式进行推导和计算，不需要进行复杂的机理分析或创新应用。 | 难度: 在选择题中属于高难度，需要深入理解多个复杂概念（如自旋分解、临界波长、自由能等），并进行多步计算和综合分析。题目涉及多个变量和参数（如M、η、Y、K等），要求考生能够正确应用公式并推导临界波长的表达式。解题步骤复杂，需要较高的数学和物理基础。" + }, + { + "idx": 2913, + "question": "After quenching 1.2% steel to obtain martensite and a small amount of retained austenite structure, what changes will occur when heated to 300°C and held for 2h?", + "answer": "The retained austenite decomposes and transforms into α plus fine carbides, and the martensite also decomposes into α plus fine carbides, with the original martensite morphology becoming less distinct.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释热处理过程中组织变化的具体情况，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目要求分析淬火钢在回火过程中的组织转变，涉及马氏体和残余奥氏体的分解机制，需要综合运用相变原理和热处理知识进行推理分析，思维深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2914, + "question": "An Al-Cu alloy with an atomic fraction of Cu at 4.6% undergoes solution treatment at 550°C, resulting in the α phase containing x(Cu)=2%. After reheating to 100°C and holding for a period, θ phase precipitates uniformly throughout the alloy volume. The θ phase has an fcc structure with r=0.143 nm, and the average spacing between θ particles is 5 nm. Calculate the number of θ phase particles per cm³ in the alloy.", + "answer": "Assuming each θ phase particle occupies a volume of 5 nm³, the number of θ particles is 1/(5×10⁻⁷)³=8×10¹⁸ particles/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，涉及公式应用和单位转换，最终需要得出具体的数值答案。答案的形式是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，包括固溶处理、相变、晶体结构参数的应用，以及通过平均间距计算粒子数密度。虽然计算本身不复杂，但需要综合理解材料科学中的相变和晶体结构知识，并正确应用相关公式进行计算。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算和概念关联。需要理解固溶处理、相变、晶体结构等概念，并进行单位换算和体积计算。虽然题目提供了部分参数简化了计算过程，但仍需综合分析多个知识点才能得出正确选项。" + }, + { + "idx": 2915, + "question": "An Al-Cu alloy with an atomic fraction of 2% Cu is rapidly cooled from 520°C to 27°C and held for 3 hours, forming G.P. zones with an average spacing of 1.5×10^-6 cm. Given that the diffusion coefficient of Cu in Al at 27°C is D=2.3×10^-25 cm²/s, and assuming the process is diffusion-controlled, estimate the quenched vacancy concentration of the alloy.", + "answer": "According to the vacancy concentration formula Cv=C0 exp(-Qv/RT), given the vacancy formation energy Qv=82.811 kJ/mol, temperature T=793 K, and R=8.314 J/(mol·K), the quenched vacancy concentration is Cv=2.3 exp(-82811/(8.314×793))=8.069×10^-6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（quenched vacancy concentration）。解答过程涉及公式应用和数值代入，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数和空位浓度公式进行多步计算，涉及对扩散控制和空位形成能的理解，需要综合分析实验条件和计算结果。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，包括扩散系数、空位浓度公式、温度转换等。虽然给出了正确选项，但解题过程需要综合运用材料科学和热力学知识，进行较为复杂的计算和单位转换。" + }, + { + "idx": 2916, + "question": "During solid-state phase transformation, assuming the volume free energy change per atom is ΔGB=200ΔT/Tc, in units of J/cm³, the critical transformation temperature Tc=1000K, strain energy ε=4J/cm³, coherent interface energy σ_coherent=4.0×10⁻⁶ J/cm², and incoherent interface energy σ_incoherent=4.0×10⁻⁵ J/cm², calculate the ratio of critical nucleation work ΔG_coherent* to ΔG_incoherent* when ΔT=50°C.", + "answer": "The nucleation work for a spherical nucleus is ΔG_coherent*=16πσ³/3(ΔGB−ε)², and if the interface is incoherent, the strain energy can be neglected, with the nucleation work being ΔG_incoherent*=16πσ³/3ΔGB². The ratio ΔG_coherent*/ΔG_incoherent*=ΔGB²σ_coherent³/(ΔGB−ε)²σ_incoherent³ =[(200×50/1000)²×(4.0×10⁻⁶)³]/[(200×50/1000−4)²×(4.0×10⁻⁵)³]=2.777×10⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及多个物理量的代入和运算，最终需要计算出一个具体的数值结果。答案中展示了详细的推导过程和最终计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相变过程中的能量变化、临界成核功的计算公式，并能够正确应用这些公式进行数值计算。虽然题目提供了具体的公式，但需要综合运用体积自由能变化、应变能和界面能等概念，并进行适当的代数运算来求解比例。这超出了简单应用的范畴，但尚未达到需要复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及固体相变中的临界形核功计算，需要掌握体积自由能变化、应变能、共格和非共格界面能等概念，并进行多步计算。虽然题目提供了公式和计算步骤，但仍需要综合应用这些知识来求解比例，属于中等应用层次。" + }, + { + "idx": 2917, + "question": "For a quenched alloy, precipitation begins to form from the supersaturated solid solution after aging at $15^{\\\\circ}\\\\mathrm{C}$ for 1h. If aging is performed at $100^{\\\\circ}\\\\mathrm{C}$, precipitation starts after $1\\\\mathfrak{min}$. To prevent precipitation within 1 day after quenching, at what temperature should the alloy be maintained? (Hint: Apply the Arrhenius rate equation)", + "answer": "Rate $=A\\\\exp\\\\Bigl\\\\{-\\\\frac{Q}{R T}\\\\Bigr\\\\}$, so $\\\\ln t=A+\\\\frac{Q}{R T}$. Substituting the data, we obtain $Q{=}4.24\\\\times10^{4}~\\\\mathrm{J/mol}$. Substituting again, we get $\\\\pmb{T=243K(-30^{\\\\circ}C)}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius速率方程）来求解合金应保持的温度，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要应用Arrhenius速率方程进行多步计算，涉及对数运算和温度转换，需要理解动力学过程并正确代入数据求解。虽然计算过程较为直接，但需要一定的综合分析能力和对公式的理解。 | 难度: 在选择题中属于中等偏上难度，需要理解Arrhenius速率方程的应用，并进行多步计算和变量替换。虽然题目提供了提示，但仍需要综合运用热力学和动力学知识来解决问题。" + }, + { + "idx": 2918, + "question": "After quenching 1.2% steel to obtain martensite and a small amount of retained austenite structure, what changes will occur when heated to 180°C and held for 2 hours?", + "answer": "Fine carbides begin to precipitate from the martensite laths, which are easily etched and appear dark.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定热处理条件下材料结构的变化，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目需要理解淬火后钢的组织转变（马氏体和残余奥氏体），并分析在特定温度和时间下加热时发生的组织变化（碳化物析出）。这涉及多个概念的关联和综合分析，但不需要复杂的机理推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解马氏体回火过程中的碳化物析出行为，并关联金相组织观察特征（易腐蚀变暗）。虽然不涉及多步计算，但需要综合分析淬火组织在回火温度下的相变行为，属于中等应用层次的概念关联题。" + }, + { + "idx": 2919, + "question": "Under the given conditions, prove the following relationship holds: ΔFπr²=(1/6)Gϕ̂²πh_max[8r−9h_max], where ΔF is the free energy difference between austenite and martensite.", + "answer": "The equation −ΔFπr²+(4/3)Gϕ̂²πrh_max−(3/2)Gϕ̂²πh_max²=0 is derived from the equilibrium condition dΔF_t/dh=0. Multiplying both sides by πr² and rearranging yields ΔFπr²=(1/6)Gϕ̂²πh_max[8r−9h_max].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求证明一个特定的关系式成立，并且答案中包含了详细的数学推导过程，涉及公式的应用和变形，这符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式推导，需要理解自由能差的概念以及平衡条件的应用，并进行代数运算和公式重组。虽然不涉及复杂的机理分析或创新应用，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解自由能差、平衡条件等概念，并进行多步推导和代数运算。虽然题目给出了正确选项，但需要考生具备综合分析能力和对公式变形的熟练度，属于综合性计算问题。" + }, + { + "idx": 2920, + "question": "In the face-centered cubic (fcc) structure of aluminum crystal, the coordination number of each aluminum atom on the (111) plane is (A)12 (B) 6 (C) 4 (D) 3", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A）12、（B）6、（C）4、（D）3中选择正确答案 | 知识层次: 题目考查面心立方结构中(111)晶面上原子的配位数这一基本概念的记忆和理解，属于晶体学基础知识的直接应用。 | 难度: 在选择题中属于中等难度，需要理解面心立方结构的基本概念和(111)平面的原子排列，并进行简单的空间想象和计数。虽然不涉及复杂的计算或深度推理，但需要一定的晶体学基础知识。" + }, + { + "idx": 2921, + "question": "Given the density of fully crystalline polytetrafluoroethylene ρ_c = 2.296 g/cm³ and the density of completely amorphous polytetrafluoroethylene ρ_a = 1.984 g/cm³, calculate the crystallinity of a polytetrafluoroethylene sample with a density of 2.26 g/cm³.", + "answer": "Crystallinity φ = (ρ - ρ_a)/(ρ_c - ρ_a) = (2.26 - 1.984)/(2.296 - 1.984) = 0.276/0.312 = 0.885, thus φ = 88.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的密度数据和公式进行数值计算，最终得出结晶度的百分比。解答过程涉及公式应用和具体数值运算，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即利用给定的密度值直接套用结晶度计算公式进行计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了所有必要的参数（ρ, ρ_c, ρ_a），并明确要求使用给定的结晶度公式进行计算。解题步骤仅涉及将数值代入公式并进行简单的算术运算，无需额外的概念理解或公式推导。这种类型的题目在选择题中属于最基础的计算题。" + }, + { + "idx": 2922, + "question": "In cubic crystals, the (110) and (211) planes belong to the same zone axis.", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（D） | 知识层次: 题目需要理解立方晶体中晶面与晶带轴的关系，并能够判断不同晶面是否属于同一晶带轴。这涉及到对晶体几何学基本原理的应用，以及综合分析不同晶面指数的关系，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。需要掌握立方晶体中晶面指数和晶带轴的概念，并能进行多步计算和综合分析。题目要求判断(110)和(211)晶面是否属于同一晶带轴，这需要运用晶带定律进行计算验证，涉及多个概念的综合应用和较复杂的分析过程。在选择题型内，这种需要多步计算和概念关联的题目相对难度较高。" + }, + { + "idx": 2924, + "question": "In polyethylene polymer materials, the C一H chemical bond belongs to (A) metallic bond (B) ionic bond (C) covalent bond (D) hydrogen bond", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项（A、B、C、D）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚乙烯材料中C一H化学键类型的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别C一H化学键的类型为共价键，无需复杂辨析或深度理解，属于简单概念识别。" + }, + { + "idx": 2925, + "question": "After quenching, 1.2% steel obtains a martensite and a small amount of retained austenite structure. What changes will occur when heated to 680°C and held for 2 hours?", + "answer": "Carbides are distributed in granular form within the ferrite matrix, resulting in a granular pearlite structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料在特定热处理条件下的结构变化，答案提供了详细的文字描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析淬火后钢在特定热处理条件下的组织转变，涉及多个概念（马氏体、残余奥氏体、回火过程）的关联和综合分析，需要理解热处理工艺对材料微观结构的影响机制，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解淬火后的组织转变、回火过程中的相变行为以及最终组织的形成机制。题目要求考生将多个热处理概念（马氏体、残余奥氏体、碳化物析出、粒状珠光体形成）进行关联分析，并预测特定工艺参数（680°C保温2小时）下的微观组织演变。这超出了简单记忆的范畴，需要进行多步骤的逻辑推理和综合判断。" + }, + { + "idx": 2926, + "question": "When a pure metal undergoes an allotropic transformation during cooling from high temperature to room temperature with volume expansion, the atomic coordination number of the low-temperature phase is ___ that of the high-temperature phase. (A) Lower (B) Higher (C) The same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对同素异构转变过程中原子配位数变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（同素异构转变和原子配位数），但需要考生理解体积膨胀与配位数变化之间的关系，并进行简单辨析。题目不涉及复杂概念的区分或深度理解，但比直接记忆性题目（等级1）要求稍高。" + }, + { + "idx": 2927, + "question": "The packing density of a simple cubic crystal is (A) $100\\\\%$ (B) $65\\\\%$ (C) $52\\\\%$ (D) $58\\\\%$", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)、(D)中选择正确答案 | 知识层次: 题目考查简单立方晶体堆积密度的基本概念记忆，属于晶体结构的基础知识，无需复杂计算或分析。 | 难度: 在选择题中属于简单难度，仅需记忆简单立方晶体的堆积密度数值即可作答，无需理解或分析复杂概念。" + }, + { + "idx": 2929, + "question": "In substitutional solid solution alloys, the diffusion of solute atoms is achieved through . (A) Atomic exchange mechanism (B) Interstitial diffusion mechanism (C) Vacancy mechanism", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于置换固溶体中溶质原子扩散机制的正确描述 | 知识层次: 题目考查的是对置换固溶体中溶质原子扩散机制的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要学生对固溶体扩散机制有一定的理解和辨析能力，能够区分原子交换机制、间隙扩散机制和空位机制。学生需要掌握这些机制的基本定义和特点，才能正确选择答案。因此，该题目属于等级2，需要概念理解和简单辨析。" + }, + { + "idx": 2930, + "question": "The flexibility of polymer materials mainly depends on the mobility of . (A) Main chain segments (B) Side groups (C) Functional groups or atoms within side groups", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查聚合物材料柔韧性的基本概念，即主链段的运动性，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别聚合物材料柔韧性的主要决定因素（主链段的活动性），无需复杂辨析或深度理解。选项直接对应基础知识点，属于简单概念识别。" + }, + { + "idx": 2931, + "question": "Two parallel screw dislocations, when their Burgers vectors are in the same direction, the interaction force between them is (A) zero (B) repulsive (C) attractive", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于两个平行螺位错相互作用力的正确答案 | 知识层次: 题目考查对平行螺型位错相互作用力的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解螺位错相互作用的基本原理，并能够区分不同Burgers向量方向下的相互作用力类型（排斥或吸引）。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 2932, + "question": "In ionic crystals, if Schottky defects are formed in a local region, the concentration of cation vacancies in this region is equal to . \\n\\n(A) Anion vacancy concentration (B) Interstitial anion concentration (C) Interstitial cation concentration", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查离子晶体中肖特基缺陷的基本概念，即阳离子空位浓度与阴离子空位浓度的关系，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆Schottky缺陷的定义即可得出正确答案。题目选项设计简单，没有涉及复杂的概念辨析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 2933, + "question": "Among the three crystal structures of fcc, bcc, and hcp materials, the one most prone to forming twins during plastic deformation is (A) fcc (B) bcc (C) hcp", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从三个选项（A、B、C）中选择最易形成孪晶的晶体结构，符合选择题的特征 | 知识层次: 题目考查对晶体结构（fcc、bcc、hcp）及其塑性变形行为的基础概念记忆，特别是关于孪生倾向性的基本知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生识别并记忆不同晶体结构在塑性变形中形成孪晶的倾向性。虽然需要区分fcc、bcc和hcp三种结构，但知识点较为明确，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 2934, + "question": "For a lenticular martensite plate with thickness h and radius r, the volume can be approximated as πr²h, and the volume of the surrounding strain field can be taken as (4/3)πr³−πr²h. The strain energy per unit volume in the strain field can be expressed as (Gϕ̂²h²)/(2r²) (where G is the shear modulus and ϕ̂ is the shear angle). Assuming the diameter of the plate remains unchanged during martensite growth, explain that when the plate thickens, the thickness cannot exceed a maximum value h_max due to the limitation imposed by strain energy.", + "answer": "If the semi-coherent interface energy is negligible, the change in the system's free energy during martensite plate growth is ΔF_t=−ΔFπr²h+Gϕ̂²h²((4/3)πr³−πr²h)/(2r²). Given that the diameter remains unchanged, setting dΔF_t/dh=0 yields −ΔFπr²+(4/3)Gϕ̂²πrh_0−(3/2)Gϕ̂²πh_0²=0. Simplifying this gives ΔFr²=(1/6)Gϕ̂²h_0[8r−9h_0], where h_0 is the h_max.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在板条马氏体增厚过程中，厚度不能超过最大值h_max，并给出了相关的自由能变化方程和推导过程。解答需要文字解释和论述，而不是简单的计算或选择。 | 知识层次: 题目要求解释马氏体片增厚过程中厚度不能超过最大值的限制，涉及应变能的计算和自由能变化的分析。需要综合运用材料科学中的应变能概念、自由能变化计算以及数学推导（求导和简化方程），属于复杂的机理分析和推理过程。 | 难度: 在选择题型内，该题目属于最高难度等级。题目涉及复杂的材料科学原理，包括应变能计算、自由能变化分析以及数学推导。解题步骤要求综合运用多个高级概念（如剪切模量、剪切角、半共格界面能等），并进行多步数学运算和逻辑推理。此外，题目还要求理解马氏体生长过程中的能量限制机制，这需要深入的材料相变知识。在选择题型中，这种综合性强、分析深度高的题目属于最复杂的类型。" + }, + { + "idx": 2935, + "question": "The dislocation that cannot undergo climb motion is (A) Shockley partial dislocation (B) Frank partial dislocation (C) edge perfect dislocation", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)中选择一个正确答案 | 知识层次: 题目考查对位错类型及其运动方式的基本概念记忆和理解，属于材料科学中晶体缺陷的基础知识范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解不同类型位错（Shockley partial dislocation、Frank partial dislocation、edge perfect dislocation）的基本特性，并能够区分它们之间的运动方式。特别是需要知道Shockley partial dislocation不能进行climb motion这一特定知识点。这比单纯记忆定义要复杂一些，但不需要进行深度分析或多概念比较。" + }, + { + "idx": 2936, + "question": "When a deformed material is reheated and undergoes recovery and recrystallization phenomena, the significant decrease in point defect concentration occurs during (A) recovery stage (B) recrystallization stage (C) grain growth stage", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对材料科学中恢复和再结晶过程中点缺陷浓度变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏易难度，需要理解恢复阶段和再结晶阶段的基本概念，并能区分点缺陷浓度显著下降发生的具体阶段。虽然涉及多个概念，但选项间的区分度较高，只需基础概念理解和简单辨析即可正确作答。" + }, + { + "idx": 2937, + "question": "A sample composed of three components is analyzed by X-ray diffraction (XRD) in air to study its phase transformation with temperature changes. The maximum number of coexisting phases that can be recorded is .", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（C） | 知识层次: 题目考查对相律（Gibbs Phase Rule）这一基础概念的记忆和理解，属于材料科学中最基本的相平衡原理知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆X射线衍射（XRD）分析中相变研究的基本原理，即吉布斯相律（Gibbs Phase Rule）在开放系统中的简单应用。题目无需复杂分析或概念辨析，仅需记住在空气环境下（开放系统）最大共存相数的定义即可选出正确答案。因此属于最简单的难度等级。" + }, + { + "idx": 2938, + "question": "After welding A and A-B alloy, the Kirkendall effect occurs, and the interface is measured to move towards the A sample. Then (A) The diffusion rate of component A is greater than that of component B (B) The opposite of (A) (C) The diffusion rates of components A and B are the same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（A）、（B）、（C）中选择正确答案 | 知识层次: 题目考查Kirkendall效应的应用，需要理解扩散速率差异对界面移动方向的影响，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要理解Kirkendall效应的基本原理，并能将界面移动方向与扩散速率差异进行关联分析。题目要求考生不仅掌握扩散概念，还需要进行逆向推理（从界面移动方向反推扩散速率关系），涉及多步逻辑推理和概念的综合应用。" + }, + { + "idx": 2939, + "question": "The Peierls-Nabarro force for dislocation slip is smaller.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（A） | 知识层次: 题目考查Peierls-Nabarro力的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆Peierls-Nabarro力的定义及其与位错滑移的关系，无需复杂理解或分析步骤。" + }, + { + "idx": 2940, + "question": "The fundamental reason for diffusion to occur in materials is (A) temperature change (B) concentration gradient (C) chemical potential gradient", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查扩散现象的基本原因，属于材料科学中的基础概念记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解扩散现象的根本原因，并区分温度变化、浓度梯度和化学势梯度这三个选项之间的差异。正确选项（化学势梯度）不是最直观的选项，需要一定的概念理解和简单辨析能力。" + }, + { + "idx": 2941, + "question": "The relationship between the probability of annealing twin formation and the stacking fault energy of the crystal is (A) unrelated, only dependent on the annealing temperature and time (B) crystals with low stacking fault energy have a higher probability of forming annealing twins (C) crystals with high stacking fault energy have a higher probability of forming annealing twins", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对堆垛层错能与退火孪晶形成概率关系这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解堆垛层错能与退火孪晶形成概率之间的关系这一基础概念，并进行简单辨析。虽然涉及基本原理的记忆，但选项之间的区分度较高，正确选项较为明显。" + }, + { + "idx": 2942, + "question": "During the nucleation stage of solidification, only when the radius of the nucleus equals or exceeds the critical size can it become a crystallization core. When the formed nucleus has a radius equal to the critical size, the free energy change of the system is", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对凝固过程中临界核尺寸和系统自由能变化的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解临界尺寸与自由能变化之间的关系，而不仅仅是简单的定义记忆。学生需要掌握成核阶段的基本原理，并能够将临界尺寸与系统自由能变化联系起来。这比单纯的概念识别（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 2943, + "question": "A factory used 9Mn2V steel to make plastic molds, requiring a hardness of 58~63 HRC. After oil quenching at 790°C and tempering at 200~220°C, brittle fractures often occurred during use. Later, the process was changed to heating at 790°C followed by isothermal treatment in a nitrite salt bath at 260~280°C for 4 hours and then air cooling. Although the hardness decreased to 50 HRC, the service life was significantly improved. Please analyze the reason.", + "answer": "After quenching and low-temperature tempering, the 9Mn2V steel mainly obtains a tempered structure of plate martensite. Since the substructure of plate martensite consists of twins and microcracks exist during its formation, the brittleness is relatively high. Isothermal quenching in nitrite salt produces lower bainite, whose matrix ferrite has a substructure of high-density dislocations and no microcracks, resulting in significantly reduced brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述分析工艺改变后性能提升的原因，答案提供了详细的材料科学原理和微观结构变化的解释，符合简答题的特征。 | 知识层次: 题目要求分析不同热处理工艺对9Mn2V钢组织和性能的影响，涉及马氏体和贝氏体组织的亚结构差异及其对脆性的影响，需要综合运用材料科学知识进行机理解释和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2944, + "question": "In a binary system composed of A and B, when α and β phases are in equilibrium, the relationship between composition (x) and free energy (G) for the two components is (A) $G^{\\\\alpha}=G^{\\\\beta}$ (B) $\\\\mathrm{d}G^{\\\\circ}/\\\\mathrm{d}x=\\\\mathrm{d}G^{\\\\beta}/\\\\mathrm{d}x$ (C) $G_{\\\\tt A}=G_{\\\\tt B}$", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项（A、B、C）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查二元系统中两相平衡时自由能与成分关系的理解，需要掌握自由能曲线的概念及其在相平衡中的应用，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及二元系统中α和β相平衡时的自由能关系，需要理解热力学平衡条件（化学势相等）及其数学表达形式。其次，正确选项B要求考生掌握自由能对成分的偏导数（即化学势的斜率）在相平衡时必须相等的原理，这需要将热力学概念与数学微分运算相结合。此外，题目中的干扰项A和C分别设置了常见错误选项（直接比较相自由能或组分自由能），增加了判断难度。综合来看，该题需要考生在多步概念关联和综合分析的基础上才能正确选择，符合等级4\"复杂分析过程的判断\"的标准。" + }, + { + "idx": 2945, + "question": "The relationship between the growth velocity (vg) of a certain crystal during solidification and the dynamic undercooling (ΔTx) at the liquid-solid interface front is vg proportional to ΔTx^2. This crystal belongs to which growth mechanism? (A) Continuous growth (B) Growth via screw dislocations (C) Two-dimensional nucleation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对晶体生长机制的理解和应用，需要将生长速度与动态过冷度的关系与不同的生长机制联系起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解晶体生长机制中的动态过冷与生长速度的关系，并能够将数学关系（vg ∝ ΔTx^2）与具体的生长机制（如螺位错生长）联系起来。此外，还需要对连续生长、二维成核等其他机制有一定的了解，才能正确选择。这需要多步的概念关联和综合分析，超出了基础记忆或简单理解的层次。" + }, + { + "idx": 2946, + "question": "When most of the latent heat of crystallization can be dissipated through the liquid phase during ingot solidification, the main solid microstructure is (A) dendritic crystal (B) columnar crystal (C) spherulite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个选项（A、B、C）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对凝固过程中微观结构形成的基本概念的理解和记忆，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，考察学生对凝固过程中微观组织形成的理解。虽然需要知道不同晶体结构（枝晶、柱状晶、球晶）的形成条件，但题目已经明确给出了关键条件（潜热通过液相散失），只需将这一条件与枝晶形成对应起来即可。相比纯粹的定义记忆题（等级1），此题需要一定的概念理解和简单辨析能力，但不需要复杂的分析或深度推理（等级3）。" + }, + { + "idx": 2947, + "question": "The dislocation that can undergo cross-slip must be (A) edge dislocation (B) screw dislocation (C) mixed dislocation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于位错类型的正确答案 | 知识层次: 题目考查对位错类型及其特性的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生理解并区分不同类型的位错（刃型位错、螺型位错、混合位错）的基本特性。虽然题目直接考察的是记忆性知识，但需要考生对位错类型及其行为（如交滑移）有明确的理解和简单辨析能力，因此属于中等难度。" + }, + { + "idx": 2948, + "question": "In ionic crystals, the diffusion rate of cations is (A) faster than that of anions (B) slower than that of anions (C) neither A nor B is correct", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查离子晶体中阳离子和阴离子扩散速率的基本概念记忆，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆离子晶体中阳离子和阴离子的扩散速率差异。题目选项明确，无需复杂分析或深度理解，属于简单概念识别。" + }, + { + "idx": 2949, + "question": "In an fcc crystal, there is a perfect dislocation with a Burgers vector of 1/2[011] on the (111) plane. When it decomposes into an extended dislocation, the leading dislocation is 1/6[121]. Determine the possible dislocation decomposition reaction and evaluate the possibility of decomposition using the structural condition and energy condition.", + "answer": "The possible dislocation reaction on the (111) plane is 1/2[011](b_{4})→1/6[\\\\overline{1}21](b_{5})+1/6[112](b_{6}). Energy condition: b_{4}^{2}=1/2, b_{5}^{2}+b_{6}^{2}=1/3. b_{4}^{2}>b_{5}^{2}+b_{6}^{2}, decomposition is feasible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释可能的位错分解反应，并评估分解的可能性，需要文字解释和论述，答案也以文字形式呈现了详细的分解过程和能量条件分析。 | 知识层次: 题目要求分析面心立方晶体中位错的分解反应，涉及位错分解的结构条件和能量条件评估，需要综合运用位错理论、晶体学知识以及能量计算，并进行推理分析。这超出了简单应用和中等应用的范围，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅掌握位错分解的基本概念，还需要深入理解Burgers矢量的计算、能量条件的评估以及结构条件的应用。解题步骤涉及复杂的矢量分解和能量计算，需要综合运用多个知识点进行推理分析。此外，题目还要求考生能够解释分解的可行性，这需要机理层面的深度理解和复杂现象的综合分析能力。因此，在选择题型中，该题目属于最高难度的复杂分析题目。" + }, + { + "idx": 2951, + "question": "When two leading dislocations 1/6[2\\overline{1}\\overline{1}] and 1/6[\\overline{1}21] move on their respective slip planes and meet, a new dislocation reaction occurs. Determine the possible dislocation reaction.", + "answer": "When b_{2} and b_{5} meet and react: b_{2}+b_{5}→1/6[110], forming a stair-rod dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错反应的可能结果，而不是从选项中选择、判断对错或进行数值计算。答案也以文字形式给出了具体的位错反应过程。 | 知识层次: 题目要求分析两个位错相遇时的反应，并确定新的位错形成。这需要理解位错的基本性质、伯格斯矢量的计算以及位错反应的规则，涉及多个概念的关联和综合分析。此外，还需要推理和解释位错反应的机理，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握位错反应的基本原理，还需要能够综合运用晶体学知识和位错理论，对复杂的位错相互作用进行推理分析。具体表现在：" + }, + { + "idx": 2952, + "question": "When the crystal growth mechanism of Ge (germanium) follows the two-dimensional nucleation model, if the nuclei formed at the liquid-solid interface are cylindrical with each nucleus height h = 0.25 nm, calculate the critical nucleus diameter d*. (Given: melting point Tm = 1231 K, heat of fusion = 750000 kJ/m³, surface energy per unit area = 5.5×10⁻² J/m², undercooling during solidification ΔT = 0.01 Tm)", + "answer": "ΔG = π(d/2)²hΔGv + πdhσ\\n\\n∂ΔG/∂d = 0 yields\\nπ(d/2)hΔGv + πhσ = 0\\nd* = -2σ/ΔGv\\nSince ΔGv = -LvΔT/Tm\\nThus, d* = 2σTm/(LvΔT)\\nSubstituting the values gives d* = 14.7 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及多个步骤的推导和具体数值的代入计算，最终得出一个具体的数值结果（d* = 14.7 nm）。 | 知识层次: 题目需要进行多步计算，涉及临界核直径的推导和公式应用，需要理解二维成核模型的基本原理，并能够将给定的参数代入公式进行计算。虽然计算过程较为直接，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解二维成核模型、临界核尺寸计算、热力学参数关联等多个概念，并正确应用公式进行多步推导和数值计算。虽然题目提供了所有必要参数，但解题过程涉及公式变形、参数代换和单位换算，对学生的综合分析能力要求较高。" + }, + { + "idx": 2953, + "question": "According to the relationship d²=kt and k=17.6μm²/min, find the grain diameter d after annealing for 90 minutes.", + "answer": "d = √(17.6μm²/min × 90min) = √1584μm² = 39.8μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和数学运算，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了公式d²=kt和k的值，只需要将时间t=90min代入公式并进行简单的平方根计算即可得到答案。解题步骤非常直接，无需复杂的推理或多步骤计算，符合等级1的定义。" + }, + { + "idx": 2956, + "question": "According to the relationship d²=kt and k=17.6μm²/min, find the grain diameter d after annealing for 60 minutes.", + "answer": "d = √(17.6μm²/min × 60min) = √1056μm² = 32.5μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和数学运算，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析，属于基础知识的简单应用。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式d²=kt，并进行简单的平方根计算即可得出答案。解题步骤非常直接，无需组合多个公式或进行复杂分析，属于最基础的难度等级。" + }, + { + "idx": 2957, + "question": "The main reason why it is difficult to form a single-phase structure in polymer alloys is that the alloy has (A) smaller mixing entropy (B) opposite to (A) (C) smaller mixing heat", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物合金形成单相结构困难原因的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（聚合物合金的单相结构形成困难的主要原因），但需要考生理解并区分\"混合熵\"和\"混合热\"这两个概念。正确选项A（较小的混合熵）需要考生对聚合物合金的基本原理有一定理解，而不仅仅是简单的概念识别。不过题目没有涉及更复杂的分析或多概念综合比较，因此难度属于等级2。" + }, + { + "idx": 2958, + "question": "Carbon atoms take 10 hours to diffuse into the surface of pure iron material at ${800}^{\\\\circ}\\\\mathrm{C}$ to a depth of $0.1\\\\mathfrak{c m}$. Calculate the time required to achieve the same carbon depth at $900^{\\\\circ}\\\\mathrm{C}$. (The diffusion activation energy of carbon atoms in fcc iron is $137520\\\\mathrm{J/mol}$.)", + "answer": "Since $D{=}D_{0}\\\\exp(-Q/R T)$, substituting the values gives $D_{800}/D_{500}{=}0.27$. The diffusion depth $x^{2}/(4D t)=$ constant. Substituting the values gives $t_{900}=2.7\\\\mathrm{hr}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，涉及扩散系数和时间的计算，答案也是具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和温度对扩散系数的影响，综合分析不同温度下的扩散时间。虽然不涉及复杂的机理分析或创新设计，但需要理解和应用多个相关概念和公式。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程、温度对扩散系数的影响以及扩散深度与时间的关系。题目涉及多步计算和概念关联，包括使用阿伦尼乌斯方程计算不同温度下的扩散系数比例，以及利用扩散深度公式求解时间。虽然题目提供了正确选项，但解题过程需要综合分析和计算能力。" + }, + { + "idx": 2959, + "question": "Explain the phenomenon of melting with increasing temperature in polymer crystals.", + "answer": "Crystalline polymer materials exhibit a relatively wide melting temperature range (melting range) during the melting process. The reasons are as follows: (1) The crystallization rate of polymers is slow, and the usual cooling rate cannot ensure sufficient diffusion of chain segments in the polymer to form well-developed crystals; (2) When the temperature increases, less perfect crystals melt first at lower temperatures due to their thin lamellae and high defect content, while more perfect crystals melt within a higher temperature range. This results in the phenomenon of melting with increasing temperature; (3) Slower cooling rates during crystallization can narrow the melting range.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物晶体随温度升高熔化的现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释聚合物晶体随温度升高的熔融现象，涉及多个因素的相互作用和机理分析，如结晶速率、晶体完美程度和冷却速率的影响。这需要综合运用材料科学知识，进行推理和综合分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对聚合物晶体熔融现象的复杂机理进行全面分析，涉及多个关键因素的综合解释（如结晶速率、晶体完美度、冷却速率等）。正确选项不仅需要理解基础概念，还需进行多步骤推理和机理深度解释，属于复杂现象全面分析层次。在选择题型中，此类题目对知识掌握深度和综合分析能力要求极高，远超一般选择题的认知负荷。" + }, + { + "idx": 2961, + "question": "In the hexagonal crystal system, the interplanar spacing of $(11\\\\overline{2}0)$ is $(10\\\\overline{1}0)$ interplanar spacing.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（A） | 知识层次: 题目考查六方晶系中间距的计算，需要应用基本的晶体学公式，属于简单应用层次。虽然需要理解晶面指数的含义，但计算过程直接，不涉及多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目直接要求应用六方晶系的面间距公式进行计算，无需复杂变形或多步骤选择，仅需基本公式选择和简单计算即可得出答案。" + }, + { + "idx": 2962, + "question": "In the seven polymorphic forms of $\\\\mathrm{{SiO}}_{2}$, there are two types of transformations: one is displacive transformation, and the other is reconstructive transformation. The activation energy required for displacive transformation is _____ that for reconstructive transformation. (A) greater than (B) less than (C) equal to", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对两种相变类型（位移型相变和重构型相变）的基本概念记忆，特别是它们所需活化能的相对大小，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目需要理解两种相变类型（位移型相变和重构型相变）的基本概念，并比较它们的活化能大小。虽然涉及两个概念，但题目直接给出了明确的比较关系，不需要复杂的分析或推理过程，属于概念理解和简单辨析的难度级别。" + }, + { + "idx": 2963, + "question": "According to the relationship between grain diameter and annealing time d²=kt, given that the grain diameter is 23μm after annealing for 30 minutes, find the value of the constant k.", + "answer": "k = (23μm)² / 30min = 529μm² / 30min = 17.6μm²/min", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和数据进行数值计算，最终得出一个具体的数值结果（k的值）。解答过程涉及公式应用和单位转换，属于典型的计算题。 | 知识层次: 题目考查基本公式的直接应用和简单计算，仅需将给定数值代入公式d²=kt并进行一步除法运算即可得到结果，无需多步计算或综合分析。 | 难度: 在选择题型中属于最低难度，仅需直接套用给定公式d²=kt进行简单计算，无需理解复杂概念或进行多步骤推导。题目明确给出了所有必要参数，解题过程仅涉及单一公式的直接应用和基本算术运算。" + }, + { + "idx": 2965, + "question": "According to the Hall-Petch equation σ=σ₀+kd⁻¹/², given that when annealed for 30 minutes σ=112MPa, d=23μm, and when annealed for 60 minutes σ=103MPa, d=32.5μm, find the values of the constants σ₀ and k.", + "answer": "Set up the system of equations: 112MPa = σ₀ + k×(23μm)⁻¹/² 103MPa = σ₀ + k×(32.5μm)⁻¹/² The solutions are: σ₀ = 55.3MPa, k = 272MPa·μm¹/²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，求解常数σ₀和k的值，答案也是通过计算得出的具体数值。 | 知识层次: 题目需要应用Hall-Petch方程进行多步计算，涉及建立方程组和求解未知数，需要一定的综合分析能力，但不需要复杂的推理或创新思维。 | 难度: 在选择题中属于中等偏上难度，需要建立并解二元一次方程组，涉及材料科学中的Hall-Petch方程应用。解题步骤包括：1)正确理解方程中各参数含义；2)将给定数据代入建立两个方程；3)进行包含分数指数的计算；4)解方程组求两个未知数。虽然选择题提供了正确选项，但仍需较强的计算能力和概念理解才能验证答案的正确性。" + }, + { + "idx": 2967, + "question": "In a body-centered cubic structure with a lattice constant of $\\pmb{\\alpha}$, can a dislocation with a Burgers vector of a[100] decompose into $\\frac{a}{2}[111]+\\frac{a}{2}[1\\overline{{{1}}}\\overline{{{1}}}]$? (A) No (B) Yes (C) Possibly", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目涉及位错分解的复杂分析，需要理解Burgers矢量的守恒条件以及不同位错之间的相互作用。这要求综合运用材料科学中的晶体结构和位错理论，进行推理分析以判断分解是否可行。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解体心立方结构中的位错分解机制，并能够综合运用晶体学知识和位错理论进行推理分析。解题步骤复杂，需要判断Burgers矢量的分解是否满足能量和几何条件，涉及多个概念的深度整合和机理分析。此外，题目还要求对晶体学方向指数的运算有精确掌握，这在选择题型中属于非常高的认知要求。" + }, + { + "idx": 2968, + "question": "In $\\\\mathrm{Ti}\\\\Omega_{2}$, when a portion of $\\\\mathrm{^{\\\\circ}Ti^{\\\\circ}}$ is reduced to $\\\\mathrm{Ti^{3+}}$, to balance the charge, there appears \\n\\n(A) oxygen ion vacancy (B) titanium ion vacancy (C) cation vacancy", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目涉及电荷平衡和缺陷化学的基本原理，需要理解Ti3+的形成如何影响晶格中的电荷平衡，并推断出氧空位的形成。这需要将多个概念关联起来进行综合分析，而不仅仅是记忆基础概念或进行简单应用。 | 难度: 在选择题型中，该题目属于较高难度。首先需要理解TiΩ2的晶体结构以及Ti3+的形成机制，其次要分析电荷平衡的原理，最后需要判断哪种缺陷类型能够补偿电荷变化。这个过程涉及晶体缺陷化学、氧化还原反应和电荷守恒等多个概念的关联分析，解题步骤较为复杂，属于需要综合分析判断的题目类型。" + }, + { + "idx": 2970, + "question": "From the symmetry of the repeating structural unit (mer) of polymers, the one that is most prone to crystallization is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择最易结晶的聚合物重复结构单元，答案以选项字母形式给出 | 知识层次: 题目考查对聚合物结构对称性与结晶倾向之间关系的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（聚合物结构单元的对称性与结晶倾向的关系），但需要考生理解对称性对结晶的影响这一基本原理，并进行简单辨析。相比直接记忆定义（等级1），该题目要求更高一层的概念理解。" + }, + { + "idx": 2971, + "question": "According to the Hall-Petch formula σ=σ₀+kd⁻¹/², given σ₀=55.3MPa, k=272MPa·μm¹/², d=39.8μm, find the yield strength σ after annealing for 90 minutes.", + "answer": "σ = 55.3MPa + 272MPa·μm¹/² × (39.8μm)⁻¹/² = 55.3MPa + 272MPa·μm¹/² × 0.1585μm⁻¹/² = 55.3MPa + 43.1MPa = 98.4MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果（yield strength σ），这符合计算题的特征。 | 知识层次: 题目主要考查对Hall-Petch公式的直接应用和简单计算，不需要多步推理或综合分析，属于基本公式套用和数值计算的范畴。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了Hall-Petch公式和所有需要的参数，解题步骤仅需将给定数值代入公式并进行简单的算术运算即可得到正确答案。不需要额外的概念理解或复杂的分析过程，符合等级1的简单直接计算要求。" + }, + { + "idx": 2972, + "question": "In the Kirkendall effect, the main reason for marker shift in a diffusion couple is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项标记（C）作为答案 | 知识层次: 题目考查Kirkendall效应的基本原理和原因，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解Kirkendall效应的基本原理和标记物移动的原因，但不需要进行复杂的概念区分或深度分析。" + }, + { + "idx": 2973, + "question": "When forming a critical nucleus, the decrease in volume free energy can only compensate for the surface energy by", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查对临界核形成过程中体积自由能和表面能补偿关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，考察的是对临界核形成过程中自由能与表面能关系的理解。虽然需要一定的概念理解，但选项直接指向基本原理，不需要复杂分析或概念区分，属于选择题型中中等偏下的难度。" + }, + { + "idx": 2975, + "question": "In substitutional solid solutions, the mode of atomic diffusion is generally", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项标记（C）作为答案 | 知识层次: 题目考查的是置换固溶体中原子扩散方式的基本概念记忆，属于材料科学中最基础的知识点之一，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别\"substitutional solid solutions\"中原子的扩散方式这一简单概念。题目直接考察定义性知识，无需理解或辨析过程，属于最基础的选择题难度等级。" + }, + { + "idx": 2976, + "question": "The difference between cast iron and carbon steel lies in the presence or absence of (A) ledeburite (B) pearlite (C) ferrite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对铸铁和碳钢的基本组成相的记忆，特别是莱氏体的存在与否这一基础概念，属于材料科学中基础知识的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解铸铁和碳钢的基本区别，并能够识别莱氏体（ledeburite）的存在与否是关键差异点。虽然涉及基础概念记忆，但需要一定的材料学知识来区分不同组织的特征，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 2977, + "question": "In binary phase diagrams, the lever rule for calculating the relative amounts of two phases can only be used in", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（B） | 知识层次: 题目考查对杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解杠杆法则的基本原理和应用条件，但题目仅要求识别该法则的使用范围（两相区），属于概念理解和简单辨析层面。不需要进行复杂计算或多概念交叉分析，因此难度低于需要深度理解的题目。" + }, + { + "idx": 2978, + "question": "Network polymers cannot exhibit", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（C） | 知识层次: 题目考查对网络聚合物基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别网络聚合物不能表现的性质，属于直接记忆性知识，无需复杂分析或概念辨析。" + }, + { + "idx": 2979, + "question": "In the ionic compound $\\\\mathbf{MgO}$, the cation most likely to replace $\\\\mathbf{Mg}^{2+}$ in the compound (given the radii (nm) of each cation: (${\\\\bf Mg}^{2+}$) 0.066, ($\\\\mathbb{C}a^{2+}$) 0.099, ($\\\\mathrm{Li^{+}}$) 0.066, ($\\\\mathbf{Fe}^{\\\\mathbf{2+}}$) 0.074) is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的多个选项中选择最可能替换Mg2+的阳离子，答案以选项形式给出（C），符合选择题的特征。 | 知识层次: 题目考查离子半径数据的直接应用，需要根据给定的离子半径数据选择最可能替换Mg²⁰的阳离子。虽然涉及离子半径的概念，但主要是简单的数据比较和选择，不需要复杂的分析或推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接比较给定离子半径数据并选择最接近Mg²⁰半径的选项（Ca²⁺）。无需复杂计算或公式变形，属于基础概念的直接应用。" + }, + { + "idx": 2980, + "question": "In the concentration equilateral triangle of a ternary phase diagram, for alloys whose composition lies on , the content of the two components represented by the other two vertices is equal. (A) The perpendicular bisector passing through the vertex of the triangle (B) Any straight line passing through the vertex of the triangle (C) A straight line passing through the vertex of the triangle and forming a $45^{\\\\circ}$ angle with the opposite side", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对三元相图等浓度三角形中成分线的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解三元相图中等边三角形的几何特性，并能够正确识别垂直于对边的中线与通过顶点的其他直线的区别。这要求考生不仅记住定义，还需要进行简单的几何概念辨析。" + }, + { + "idx": 2981, + "question": "According to the Clausius-Clapeyron equation, as pressure increases, the temperature at which Y-Fe transforms into $\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}$", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案（答案：B），符合选择题的特征 | 知识层次: 题目考查Clausius-Clapeyron方程的基本应用，需要理解方程的含义并直接套用公式来判断温度变化趋势，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用Clausius-Clapeyron方程的基本公式，无需进行公式变形或多步骤计算。题目要求考生根据压力增加对相变温度的影响做出简单判断，属于基础知识的直接应用，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 2982, + "question": "Given erf(0.71)=0.68, find the value of x/(2√(Dt)).", + "answer": "x/(2√(Dt)) = 0.71.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目给出了一个数学函数的值（erf(0.71)=0.68），并要求根据这个信息计算x/(2√(Dt))的值。解答过程需要应用数学公式和数值计算，最终得出一个具体的数值结果（0.71）。这符合计算题的特征。 | 知识层次: 题目仅需要直接应用给定的误差函数值(erf)和公式x/(2√(Dt))进行计算，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在选择题中属于最低难度，题目直接给出了erf函数的数值和对应的参数，只需要简单套用公式x/(2√(Dt)) = 0.71即可得出答案。无需任何额外的计算或公式组合，属于单一公式直接计算的类型。" + }, + { + "idx": 2983, + "question": "Calculate the diffusion coefficient D of carbon at 920°C, given the activation energy for diffusion is 133984 J/mol and D0=0.23 cm²/s.", + "answer": "D = D0 × exp(-Q/(RT)) = 0.23 × exp(-133984/(8.314 × (273 + 920))) = 3.12 × 10^-7 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数D的具体数值。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及扩散系数的计算，需要套用给定的公式和参数进行数值计算，思维过程较为直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（D = D0 × exp(-Q/(RT))）并进行简单的数值计算。题目没有涉及多个公式的组合或复杂的逻辑推理，属于单一公式直接计算的类型，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 2984, + "question": "In polymer materials, what is the bond between molecules (secondary bond)?", + "answer": "Molecular bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料中分子间的键（次级键）是什么，答案需要文字描述而非选择或判断 | 知识层次: 题目考查聚合物材料中分子间键（次级键）的基本概念记忆，属于定义性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，此题仅考察对高分子材料中分子间键（次级键）的基本定义记忆，属于最基础的概念性知识。题目直接给出正确选项\"Molecular bond\"，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2985, + "question": "Polymer materials are", + "answer": "Materials with polymer compounds as the main component", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述聚合物材料的定义，答案是一个简短的文字描述而非选择、判断或计算 | 知识层次: 题目考查对聚合物材料基本定义的记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅要求识别聚合物材料的基本定义，属于最基础的概念记忆层次。正确选项直接对应题干中的核心概念，无需复杂推理或比较分析，解题步骤极为简单。" + }, + { + "idx": 2986, + "question": "Calculate the carburizing time t, given x=0.2 cm, D=3.12 × 10^-7 cm²/s.", + "answer": "t = (x/(2 × 0.71))² / D = (0.2/(2 × 0.71))² / (3.12 × 10^-7) = 17.7 hours.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解碳化时间，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，无需多步推理或综合分析，属于对扩散方程的直接套用和数值计算。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，解题步骤简单明确，属于最基础的难度等级。学生只需掌握基本公式并正确代入数值即可得出答案，无需进行复杂的分析或多步骤推理。" + }, + { + "idx": 2987, + "question": "What are the two synthesis methods of polymer materials", + "answer": "Addition polymerization and condensation polymerization", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举聚合物材料的两种合成方法，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对聚合物材料合成方法的基本分类记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆聚合物材料的两种基本合成方法（加聚和缩聚），属于基础概念记忆层次。题目仅涉及简单的定义和分类，无需解释或比较分析，解题步骤非常直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2988, + "question": "Using the carburization equation to calculate the value of erf(x/(2√(Dt))), given the surface carbon content ρs=1.2%, initial carbon content ρ0=0.1%, and target carbon content ρ(x,t)=0.45%.", + "answer": "erf(x/(2√(Dt))) = (ρs - ρ(x,t))/(ρs - ρ0) = (1.2 - 0.45)/(1.2 - 0.1) = 0.682.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式和数值进行具体计算，最终得出一个数值结果。解答过程涉及数值代入和公式应用，符合计算题的特征。 | 知识层次: 题目主要考查对carburization方程的基本应用，涉及简单的数值计算和公式套用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解并应用carburization方程中的erf函数关系，但解题步骤较为直接，仅需代入给定的数值进行简单计算即可得出正确选项。不需要复杂的推导或多步骤分析，因此属于等级2难度。" + }, + { + "idx": 2989, + "question": "Into what categories can polymer materials be classified by application", + "answer": "Plastics, rubber, fibers, adhesives, coatings", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举聚合物材料按应用分类的类别，需要文字解释和论述，答案形式为列举多个项目而非选择或判断 | 知识层次: 题目考查聚合物材料按应用分类的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，此题属于基础概念记忆类题目，仅需回忆聚合物材料按应用分类的基本类别（塑料、橡胶、纤维、粘合剂、涂料）。题目不涉及概念解释或复杂体系分析，仅测试对简单分类的记忆能力，因此属于最低难度等级。" + }, + { + "idx": 2990, + "question": "In polymer materials, what is the atomic bonding between molecules (primary valence force)?", + "answer": "Covalent bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的概念（原子键合类型），答案是一个术语（Covalent bond），不需要选择、判断或计算，符合简答题的特征。 | 知识层次: 题目考查聚合物材料中分子间原子键合的基本概念记忆，属于基础概念层次 | 难度: 在选择题型中，该题目仅考察对聚合物材料中分子间原子键合类型（共价键）的基础定义记忆，属于最基本的概念性知识，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2991, + "question": "Thermosetting plastics mainly have (5) molecular chains.", + "answer": "(5) three-dimensional network", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（three-dimensional network）来描述热固性塑料的分子链结构，属于需要特定关键词回答的简答题形式 | 知识层次: 题目考查热固性塑料分子链结构的基本概念记忆，属于定义性知识，无需复杂分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆并识别热固性塑料的主要分子链结构（三维网络）。题目仅涉及单一知识点的直接回忆，无需解释或分析，属于选择题中最简单的难度等级。" + }, + { + "idx": 2992, + "question": "Due to the very long molecular chains, how is the relationship between secondary valence forces and primary valence forces often?", + "answer": "Greater than", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释分子链长度对次级价力和主价力关系的影响，需要文字论述而非选择或判断 | 知识层次: 题目考查对高分子链中次级价力与主价力关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需要考生记住高分子材料中次级价力与主价力的基本关系。在选择题型中，只需识别正确选项\"Greater than\"，无需复杂推理或概念比较，属于最简单的定义性知识考查。" + }, + { + "idx": 2993, + "question": "The geometric shapes of macromolecular chains are (1), (2), (3).", + "answer": "(1) Linear; (2) Branched; (3) Network", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举大分子链的几何形状，答案需要提供具体的文字描述（线性、支化、网状），属于简答题类型。 | 知识层次: 题目考查对高分子链几何形状的基本分类的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需回忆并选择高分子链的几何形状分类（线性、支化、网状）。题目仅考察对基本定义的直接记忆，无需解释或复杂分析，解题步骤简单，属于最基础的难度等级。" + }, + { + "idx": 2994, + "question": "Thermoplastics mainly have (4) molecular chains.", + "answer": "(4) linear", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的单词（linear）来描述热塑性塑料的分子链结构，属于简短的文字回答形式，而非从多个选项中选择或判断对错。 | 知识层次: 题目考查热塑性塑料分子链结构的基本概念记忆，属于定义和分类的基础知识范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对热塑性塑料分子链结构的基础定义记忆（线性结构），属于最基础的概念识别层级，无需解释或分析步骤。" + }, + { + "idx": 2995, + "question": "The basic motion units corresponding to the three mechanical states of linear amorphous polymers are (4), (5), (6)", + "answer": "(4) chain segments or side groups; (5) chain segments; (6) macromolecular chains", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写对应的基本运动单元，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对线性无定形聚合物三种力学状态对应基本运动单元的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确区分和记忆线性无定形聚合物三种机械状态对应的基本运动单元（链段或侧基、链段、大分子链）。这要求考生不仅记住定义，还需要理解不同运动单元在不同状态下的对应关系，属于概念解释和描述的层次。" + }, + { + "idx": 2996, + "question": "The three mechanical states of linear amorphous polymers are (1), (2), (3)", + "answer": "(1) Glassy state; (2) High elastic state; (3) Viscous flow state", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写三个机械状态的名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对线性无定形聚合物三种力学状态的基本概念记忆，属于定义和分类的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆线性无定形聚合物的三个力学状态的基本名称，属于基础概念的直接回忆。题目不涉及解释、比较或分析，解题步骤简单直接，符合等级1的基本定义简答标准。" + }, + { + "idx": 2997, + "question": "The aging of polymer materials involves structural changes such as (1) and (2).", + "answer": "(1) cross-linking; (2) scission", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的结构变化名称，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对聚合物材料老化过程中结构变化的基本概念记忆，仅需回答交联和断裂两个术语，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别聚合物材料老化的两种基本结构变化（交联和断裂），属于基础概念记忆层次。题目直接给出正确选项，无需解释或分析，解题步骤简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2998, + "question": "The three mechanical states corresponding to linear amorphous polymers are the usage states of (7), (8), and (9)", + "answer": "(7) plastic; (8) rubber; (9) flow resin", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写三个机械状态的名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对线性无定形聚合物三种力学状态的基本概念记忆，属于定义和分类的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆线性无定形聚合物的三种力学状态对应的具体名称（塑料、橡胶、流动树脂），属于基础概念的直接回忆。无需解释或分析，解题步骤简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2999, + "question": "What are the mechanical states of high polymers with larger molecular weight that are not completely crystalline?", + "answer": "(1) Glassy state; (2) High elastic state; (3) Leathery state; (4) Viscous flow state", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对高分子材料机械状态分类的基础概念记忆，属于定义和分类的记忆性知识，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆层次，考察高分子材料在不同机械状态下的分类。虽然需要记忆多个状态（玻璃态、高弹态、皮革态、粘流态），但选项均为直接对应的专业术语，不涉及复杂辨析或深度理解。在选择题型中属于概念理解和简单辨析难度，略高于简单识别但未达到复杂区分程度。" + }, + { + "idx": 3000, + "question": "What are the usage states corresponding to these mechanical states?", + "answer": "(5)Plastic; (6)Rubber; (7)Flow resin", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释机械状态对应的使用状态，答案需要文字描述而非选择或计算 | 知识层次: 题目考查对材料在不同机械状态下对应使用状态的基础概念记忆，如塑性、橡胶态和流动树脂态，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求考生记忆并匹配机械状态与对应的使用状态（塑料、橡胶、流动树脂），属于基础概念记忆层次，无需复杂推理或分析。正确选项直接对应定义，解题步骤简单明了。" + }, + { + "idx": 3001, + "question": "What usually breaks first when a polymer material fractures under force?", + "answer": "Covalent bonds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料在受力断裂时首先断裂的化学键类型，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查聚合物材料断裂时共价键断裂的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察对聚合物材料断裂时最先断裂的化学键类型的基础记忆，属于最基本的概念性知识，无需解释或分析步骤。正确选项\"共价键\"是高分子材料断裂机理中的基础定义，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3002, + "question": "The five major engineering plastics are (1), (2), (3), (4), (5).", + "answer": "(1)Polyoxymethylene; (2)Polyamide; (3)Polycarbonate; (4)ABS; (5)Polysulfone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写五个主要工程塑料的名称，需要学生回忆并列举具体材料名称，属于简答题类型。答案形式为文字列举，而非选择或判断。 | 知识层次: 题目考查对五大工程塑料名称的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆五大工程塑料的具体名称，无需解释或分析。题目要求的知识点掌握深度较浅，解题步骤简单直接，属于选择题型中最基础的难度等级。" + }, + { + "idx": 3003, + "question": "Rubber exhibits (1) physical state at -70℃.", + "answer": "(1)glass transition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（glass transition）来描述橡胶在特定温度下的物理状态，这属于需要特定知识点的简短回答，而非从多个选项中选择或判断对错。 | 知识层次: 题目考查橡胶在特定温度下的物理状态变化，属于基础概念的记忆和理解，涉及玻璃化转变温度的基本定义和分类。 | 难度: 在选择题型中，该题目仅考察对橡胶在低温下物理状态的基础概念记忆（玻璃化转变），属于最基础的定义简答级别。题目仅要求识别单一知识点，无需解释或复杂分析，符合等级1的简单记忆要求。" + }, + { + "idx": 3004, + "question": "When a factory used a nylon rope sling that had been in stock for two years, a fracture accident occurred even though the load-bearing capacity was far greater than the lifting stress. The reason for the fracture was (1).", + "answer": "(1)aging", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释断裂原因，需要文字解释和论述，答案形式为简短的文字描述而非选择或判断 | 知识层次: 题目考查对材料老化这一基本概念的记忆和理解，不需要复杂的分析或计算。 | 难度: 在选择题型中属于基础难度，仅需要记忆材料老化的基本概念即可作答，无需复杂分析或概念比较。题目直接考查对\"aging\"这一基础定义的识别能力。" + }, + { + "idx": 3005, + "question": "The mechanical properties of polymers are mainly determined by their degree of polymerization, crystallinity, and intermolecular forces.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物机械性能决定因素的基础概念记忆，仅需识别三个关键因素（聚合度、结晶度和分子间作用力）的正确性，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆聚合物机械性能的决定因素（聚合度、结晶度和分子间作用力）即可做出正确判断，无需深入理解或分析。" + }, + { + "idx": 3006, + "question": "Linear polymers with high molecular weight exhibit glassy (or crystalline) state, high elastic state, and viscous flow state. Three-dimensional polymers with high crosslinking density do not possess high elasticity or viscous flow state.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物状态和交联密度影响的基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆线性聚合物和三维聚合物的基本状态特性即可做出正确选择，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3007, + "question": "ABS plastic is an engineering material with excellent comprehensive properties.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（ABS plastic is an engineering material with excellent comprehensive properties），并要求判断其正确性（答案：√），符合判断题的特征。 | 知识层次: 题目考查对ABS塑料基本特性的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆ABS塑料的基本定义和特性即可做出正确选择，无需深入理解或分析复杂概念。" + }, + { + "idx": 3008, + "question": "Engineering polymers can be divided into five major types based on performance: (1), for example: (2) belongs to the (3) category, for example (4) belongs to the (5) category, for example (6) belongs to the (7) category, for example (8) belongs to the (9) category, for example (10) belongs to the (11) category.", + "answer": "(1)plastics, rubber, fibers, adhesives, coatings; (2)polyamide; (3)plastics; (4)styrene-butadiene rubber; (5)rubber; (6)polyester fiber; (7)fibers; (8)epoxy adhesive; (9)adhesives; (10)phenolic resin coating; (11)coatings", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的分类和例子，需要文字解释和论述，而不是从选项中选择或判断对错。答案的形式也是具体的文字描述，而非计算或选择。 | 知识层次: 题目主要考查对工程聚合物分类的记忆和理解，属于基础概念的记忆性知识，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个分类和具体例子，但每个空格的答案都是直接对应的基础概念记忆内容，不需要复杂的推理或分析。学生只需记住工程聚合物的五大分类及其代表性材料即可正确作答。题目结构清晰，解题步骤相对简单，属于概念解释和描述的难度层次。" + }, + { + "idx": 3009, + "question": "Silicate glass, mica, and asbestos belong to which category of compounds? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对无机聚合物分类的基本概念记忆，只需识别给定的材料属于哪一类化合物，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需识别无机聚合物的常见实例（硅酸盐玻璃、云母、石棉）。选项区分明显，无需复杂分析或概念辨析，符合等级1\"简单概念识别，直接记忆\"的标准。" + }, + { + "idx": 3010, + "question": "To which category of compounds do silicone resins and silicone rubbers belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Element-organic compounds D. Inorganic polymers", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对硅树脂和硅橡胶所属化合物类别的基本概念记忆，属于定义和分类的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要考生理解并区分不同类型化合物的分类标准。虽然题目涉及的是基础概念记忆，但需要对\"元素有机化合物\"的定义有明确理解，并能与其它选项(如碳链聚合物、杂链聚合物等)进行简单辨析。不需要复杂的分析过程，但比单纯记忆概念略高一个层次。" + }, + { + "idx": 3011, + "question": "To which category of compounds do nylon and polysulfone belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物分类的基本概念记忆，只需要知道尼龙和聚砜属于杂链有机聚合物即可回答，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（有机聚合物的分类），但需要学生理解并区分\"碳链有机聚合物\"和\"杂链有机聚合物\"这两个概念。学生需要知道尼龙和聚砜的分子结构特点（含有杂原子），才能正确选择\"杂链有机聚合物\"这个选项。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析过程（等级3）。" + }, + { + "idx": 3012, + "question": "To which category of compounds do Teflon (polytetrafluoroethylene) and Plexiglas (polymethyl methacrylate) belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物基本分类的记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆类型，仅需识别Teflon和Plexiglas属于碳链有机聚合物这一简单事实。选项直接对应记忆性知识，无需复杂理解或辨析过程，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3013, + "question": "The form of polymer with the lowest expansion coefficient is (1). A. Linear B. Branched C. Crosslinked", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，且答案形式为选项编号，符合选择题的特征 | 知识层次: 题目考查对聚合物结构类型（线性、支化、交联）及其基本性质（膨胀系数）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别聚合物形式与膨胀系数之间的基本关系。选项直接对应记忆性知识，无需复杂辨析或深度理解，属于选择题型中最简单的难度等级。" + }, + { + "idx": 3014, + "question": "The usage state of synthetic fibers is (). A. Crystalline state B. Glassy state C. High elastic state D. Viscous flow state", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C、D）中选择正确答案 | 知识层次: 题目考查对合成纤维使用状态这一基础概念的简单记忆和理解，属于材料科学中最基本的知识点，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然考察的是基础概念记忆（合成纤维的使用状态），但需要考生理解并区分\"玻璃态\"与其他状态（如晶态、高弹态、粘流态）的不同。这比单纯记忆定义（等级1）要求稍高，但不需要复杂的分析比较（等级3）。正确选项B需要考生掌握合成纤维在常温下的典型状态特征。" + }, + { + "idx": 3015, + "question": "The elasticity of a polymer is related to which temperature? A. $T_{\\\\mathrm{m}}$ B. $T_{_{8}}$ C. $T_{t}$ D.Ta", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对聚合物弹性相关温度的基本概念记忆，只需识别与弹性相关的温度符号即可，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即聚合物弹性与特定温度的关系。正确选项C（$T_{t}$）是直接记忆性知识点，无需复杂理解或辨析。因此，该题目属于简单概念识别，直接记忆的难度等级。" + }, + { + "idx": 3016, + "question": "The usage state of plastic is (). A. Crystalline state B. Glassy state C. High elastic state D. Viscous flow state", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择塑料使用状态的正确答案 | 知识层次: 题目考查塑料使用状态的基本概念记忆，属于对材料科学基础知识的直接考察，无需复杂推理或综合分析。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别塑料的使用状态为玻璃态（Glassy state），无需复杂辨析或深度理解。题目直接考察定义性知识，属于简单概念识别。" + }, + { + "idx": 3017, + "question": "The close-packed {111} planes of the face-centered cubic (fcc) structure are stacked in the sequence ABCABC..., while the close-packed {0001} planes of the hexagonal close-packed (hcp) structure are stacked in the sequence ABABAB.... Explain how and by introducing what type of dislocations the fcc structure can be entirely transformed into the hcp structure.", + "answer": "Accordingly, if the C-layer atoms are moved to the E position (or E2, E positions, all referring to projection positions), the arrangement of the C atomic layer can be changed to that of the A atomic layer. If the B atomic layer is correspondingly moved at this time, it will change to the arrangement of the C atomic layer, and the A-layer atoms will change to the arrangement of the B layer. Therefore, introducing a partial dislocation of $\\frac{a}{6}(11\\overline{2})$ (or $\\frac{a}{6}(1\\overline{2}1)$, or $\\frac{a}{6}(211)$) into the second layer of the ABCABC... stacking and allowing it to sweep through the third layer and subsequent layers can change the atomic arrangement to ABABCABC.... Then, introducing the same dislocation into the fourth layer and performing the same operation can change the atomic arrangement to ABABABCABC..., and so on, resulting in the ABABAB... stacking sequence. In summary, by introducing partial dislocations of $\\frac{a}{6}(11\\overline{2})$ (or $\\frac{a}{6}(1\\overline{2}1)$, or $\\frac{a}{6}(211)$) into every second layer (111) plane (where n = 1, 2, 3,...) of the fcc structure's ABCABC... stacking, i.e., introducing a partial dislocation every other layer in the (111) plane, the stacking sequence can be changed to ABABAB..., thereby transforming it into the hcp stacking structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释如何通过引入特定类型的位错将面心立方结构转变为六方密排结构，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释如何通过引入特定类型的位错将面心立方结构完全转变为六方密排结构，这需要深入理解晶体结构、位错理论以及它们之间的相互作用。解答过程涉及复杂的机理分析和推理，包括位错类型的识别、位错运动的描述以及堆垛顺序变化的详细解释，属于综合运用和推理分析的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解面心立方（fcc）和六方密排（hcp）结构的堆垛序列，并能够分析通过引入特定类型的位错（如$\\frac{a}{6}(11\\overline{2})$）来改变堆垛序列的机理。这需要综合运用晶体结构、位错理论和堆垛序列变换的知识，进行复杂的推理和机理解释。选择题型中，这种题目不仅考察知识点的深度掌握，还要求考生能够将多个复杂概念联系起来，进行全面的分析和解释，因此属于最高难度等级。" + }, + { + "idx": 3018, + "question": "When a polymer material is subjected to force, the elasticity achieved by the elongation of bond length is (1). A. Ordinary elasticity B. High elasticity C. Viscoelasticity D. Forced elasticity", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案 | 知识层次: 题目考查对聚合物材料弹性类型的基本概念记忆和理解，属于定义性知识，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物材料在受力时的弹性类型，并进行简单辨析。虽然涉及基础概念记忆，但需要区分不同弹性类型的定义，属于概念理解和简单辨析的层次。" + }, + { + "idx": 3019, + "question": "The one that is easier to obtain a crystalline structure is (1). B. Branched molecules A. Linear molecules C. Three-dimensional molecules", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查对分子结构与结晶性关系的基础概念记忆，只需区分线性分子和支化/三维分子在结晶难易度上的基本差异，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别线性分子更容易形成晶体结构这一简单事实。题目选项直接对应知识点，无需复杂分析或深度理解，属于最简单的概念识别类型。" + }, + { + "idx": 3020, + "question": "If crystalline regions exist in polymer materials, then their melting point is (1). A. Fixed B. A temperature softening range C. Above the glass transition temperature D. Above the flow temperature", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查聚合物材料中结晶区域熔点与玻璃化转变温度之间关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物材料中结晶区的熔点特性，并知道其与玻璃化转变温度的关系。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，而非纯粹的直接记忆。" + }, + { + "idx": 3021, + "question": "The plasticity of a polymer is related to which temperature? A. $T_{\\mathrm{m}}$ B. $T_{_{8}}$ C. $T_{t}$ D.Ta", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对聚合物塑性相关温度的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别与聚合物塑性相关的温度符号Ta，无需复杂理解或辨析其他选项。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 3022, + "question": "Comparison of mechanical properties, the (1) of polymers is better than that of metal materials. A. Stiffness B. Strength C. Impact strength (toughness) D. Specific strength", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物和金属材料机械性能基本概念的对比记忆，属于基础概念的记忆和理解。 | 难度: 该题目属于基础概念记忆层次，但需要考生理解\"specific strength\"的定义（强度与密度之比）并能与金属材料进行简单比较。虽然不涉及复杂分析，但比单纯记忆定义略高一个难度层次，属于概念理解和简单辨析级别。" + }, + { + "idx": 3023, + "question": "When a polymer material is subjected to force, the elasticity achieved by the movement of chain segments is (2). A. Ordinary elasticity B. High elasticity C. Viscoelasticity D. Forced elasticity", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对聚合物材料弹性类型的基本概念记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生理解聚合物材料在受力时的弹性类型，并能够区分普通弹性、高弹性、粘弹性和强制弹性等概念。这要求考生不仅记住定义，还要能够进行简单的概念辨析。" + }, + { + "idx": 3024, + "question": "To improve the strength of polymers, how many 'alloying' methods are there?", + "answer": "Physical modification: mainly involves adding fillers to alter the physical and mechanical properties of polymers. For example, after treatment, asbestos used as a filler for polypropylene can increase tensile strength by 60% and flexural strength by 100%. Chemical modification: through copolymerization, block, grafting, blending, and compounding methods, polymers can acquire new properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释聚合物增强的“合金化”方法，答案提供了详细的文字解释和论述，包括物理改性和化学改性两种方法的具体说明，符合简答题的特征。 | 知识层次: 题目要求解释聚合物增强的两种主要方法（物理改性和化学改性），并需要理解每种方法的具体应用和效果。这涉及多个概念的关联和综合分析，而不仅仅是基础概念的记忆。 | 难度: 在选择题中属于中等难度，题目要求考生理解并区分物理改性和化学改性两种聚合物强化方法，并能够识别具体的改性技术（如共聚、嵌段、接枝等）。虽然不需要复杂的计算，但需要对相关概念有较深的理解和综合分析能力。" + }, + { + "idx": 3025, + "question": "What is the aging of polymers?", + "answer": "The phenomenon where polymer materials gradually degrade in performance and eventually lose their use value due to external factors such as oxygen, light, heat, mechanical force, water vapor, and microorganisms during long-term storage and use is called aging. The fundamental cause of aging is the cross-linking and scission of polymer molecular chains under the influence of external factors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对聚合物老化的现象进行解释和论述，答案提供了详细的文字描述和原因分析，符合简答题的特征。 | 知识层次: 题目考查聚合物老化的基本定义和原因，属于基础概念的记忆和理解，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆聚合物老化的定义及其根本原因，涉及多个外部因素和分子链变化的基本原理。虽然需要掌握一定的基础知识，但不需要进行复杂的分析或比较，属于中等难度的选择题。" + }, + { + "idx": 3026, + "question": "Explain the role of crosslinking and how it alters the structure and properties of polymers.", + "answer": "The so-called crosslinking reaction refers to the process in which polymers, under external factors, transform from a linear structure to a three-dimensional network structure, leading to increased strength, brittleness, and improved chemical stability. The crosslinking reaction makes polymer materials harder, more brittle, and even prone to cracking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释交联的作用及其对聚合物结构和性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对聚合物交联反应的基本概念、定义及其对聚合物结构和性能影响的理解，属于基础概念记忆和简单解释的范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并解释交叉链接的定义及其对聚合物结构和性能的影响。这比简单的定义记忆（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 3027, + "question": "What are the steps involved in the production process of ceramic materials?", + "answer": "(4) Preparation of raw materials; (5) Forming of the green body; (6) Sintering of the product", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释陶瓷材料生产过程的步骤，答案以文字形式列出具体步骤，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查陶瓷材料生产流程的基本步骤记忆，属于基础概念和基本原理的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及陶瓷材料生产过程的多个步骤，但正确选项已经明确列出了三个关键步骤（原料准备、生坯成型和产品烧结），考生只需识别和匹配这些基本概念即可。这要求考生对陶瓷生产工艺有基本的记忆和理解，但不需要深入分析或复杂推理。因此，在选择题型中，该题目属于等级2的难度。" + }, + { + "idx": 3028, + "question": "How to prevent the aging of polymers?", + "answer": "Currently, there are three measures taken to prevent aging.\\n① Modify the structure of the polymer. For example, chlorinating polyvinyl chloride can improve its thermal stability.\\n② Add anti-aging agents. Incorporating organic compounds such as salicylate esters, benzophenones, and carbon black into polymers can prevent photo-oxidation.\\n③ Surface treatment. Coating the surface of polymer materials with metals (such as silver, copper, nickel) or spraying anti-aging coatings (such as paint, paraffin) as protective layers isolates the material from air, light, water, and other aging-inducing media to prevent aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何防止聚合物老化，答案提供了详细的文字解释和论述，包括三种具体措施及其原理，符合简答题的特征。 | 知识层次: 题目要求列举并解释防止聚合物老化的措施，涉及多个知识点的关联和综合分析，需要理解老化机理并应用不同的防护方法，思维过程有一定深度。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解聚合物老化的基本概念，还需要掌握三种具体的防老化措施及其原理。题目涉及的知识点包括聚合物结构改性、抗老化剂的作用机制以及表面处理技术，这些内容需要考生进行多角度分析和综合应用。此外，正确选项中的详细说明要求考生能够将这些措施与具体的化学物质和实际应用场景联系起来，进一步增加了题目的复杂性和难度。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 3029, + "question": "What are the advantages and disadvantages of parts made entirely of plastic?", + "answer": "Advantages: Good chemical stability, excellent corrosion resistance, high specific strength, good friction and wear properties, good insulation. Disadvantages: Low strength and elastic modulus, low hardness, cold flow phenomenon, poor heat resistance, large expansion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举塑料制品的优缺点，需要文字解释和论述，而不是选择、判断或计算。答案以列表形式呈现了多个优缺点，符合简答题的特征。 | 知识层次: 题目考查塑料零件优缺点的基本概念记忆和理解，属于基础知识的列举和分类，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生记忆并区分塑料制品的优缺点，涉及多个基础概念（如化学稳定性、腐蚀性、比强度等）的列举和对比。虽然知识点较多，但都属于基础概念记忆范畴，不需要复杂的分析或推理过程，因此属于中等难度（等级2）。" + }, + { + "idx": 3030, + "question": "To improve the toughness of polymers, how many 'alloying' methods are there?", + "answer": "Chemical modification; methods such as copolymerization, block, grafting, blending, and compounding are used to endow polymers with new properties. For example, ABS plastic is a type of plastic with excellent comprehensive performance obtained through ternary copolymerization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何通过“合金化”方法提高聚合物的韧性，答案提供了详细的文字解释和论述，包括具体的改性方法和例子，符合简答题的特征。 | 知识层次: 题目要求列举并解释聚合物增韧的多种合金化方法，涉及多种技术（如共聚、嵌段、接枝、共混等）的综合应用和性能关联分析，需要理解不同方法的作用机理和实际应用案例（如ABS塑料），属于中等应用层次的知识运用。 | 难度: 在选择题中属于中等难度，题目要求考生理解聚合物增韧的多种“合金化”方法，并能够识别和关联不同的化学改性技术（如共聚、嵌段、接枝、共混和复合）。虽然题目提供了具体的例子（ABS塑料），但考生仍需具备一定的综合分析能力来理解这些方法如何共同作用以改善聚合物的性能。这需要中等层次的知识掌握和概念关联能力，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3031, + "question": "What are the three categories of ceramic materials?", + "answer": "(1)Glass; (2)Ceramics; (3)Glass-ceramics", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举陶瓷材料的三个类别，答案以简短的文字形式给出，不需要选择或判断，也不需要计算。 | 知识层次: 题目考查陶瓷材料分类的基础概念记忆，属于定义和分类的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆陶瓷材料的三个基本分类，属于基础概念记忆层次。题目直接给出正确选项，无需进行复杂的概念解释或比较分析，解题步骤简单明了，符合等级1的基本定义简答难度标准。" + }, + { + "idx": 3032, + "question": "When designing plastic parts, compared to metals, list four limiting factors.", + "answer": "Low strength, low hardness, low elastic modulus, cold flow phenomenon, poor heat resistance, large expansion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举塑料零件设计中的限制因素，答案提供了多个文字解释的要点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对塑料材料限制因素的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目仅要求列举塑料相比金属的四个限制因素，属于基础概念的记忆性知识，不需要解释或分析。正确选项直接给出了多个可能的答案，考生只需识别或回忆这些基本特性即可，解题步骤非常简单。" + }, + { + "idx": 3033, + "question": "The Tg of the glass phase in ceramics is (5).", + "answer": "(5)Glass transition temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（玻璃转变温度），需要学生对相关概念有准确理解并用文字作答，属于简答题类型 | 知识层次: 题目考查对玻璃相变温度（Tg）这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求识别和记忆\"Tg\"的基本定义（Glass transition temperature），属于最基础的概念记忆层次。无需解释、分析或比较多个概念，解题步骤极为简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 3034, + "question": "The Tf of the glass phase in ceramics is (6).", + "answer": "(6) viscous flow temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语（viscous flow temperature）作为答案，属于需要简短文字回答的类型，而不是从多个选项中选择或进行判断/计算。 | 知识层次: 题目考查的是玻璃相在陶瓷中的Tf（viscous flow temperature）这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对\"Tf\"这一基础定义的记忆，属于最基础的概念记忆层次。题目直接给出术语定义选项，无需任何解释、分析或推理步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3035, + "question": "Rubber is an excellent damping material and friction material due to its outstanding (1). A. High elasticity B. Viscoelasticity C. Plastic D. Anti-friction", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查橡胶材料的基本特性记忆，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目仅需识别橡胶的基本特性（高弹性），属于直接记忆的基础概念，无需复杂辨析或深度理解。题目选项设置简单明确，正确选项A与其他选项区分明显，符合等级1的简单概念识别标准。" + }, + { + "idx": 3036, + "question": "The roles of the glass phase in ceramics are (1), (2), (3), and (4).", + "answer": "(1) bonding dispersed crystalline phases; (2) reducing sintering temperature; (3) inhibiting grain growth; (4) filling pores", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举玻璃相在陶瓷中的作用，答案需要以文字形式解释和论述多个要点，符合简答题的特征。 | 知识层次: 题目考查对陶瓷中玻璃相作用的基本概念记忆，属于定义和基本原理的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个玻璃相在陶瓷中的作用，但每个作用都是基础概念记忆层面的知识点，不需要复杂的分析或推理。学生只需回忆并识别出正确的功能描述即可。相较于等级1的简单定义题，该题目需要记忆多个相关知识点，但不需要深入理解或应用，因此属于等级2难度。" + }, + { + "idx": 3037, + "question": "The basic raw materials of traditional ceramics are (1), (2), and (3), and its structure is composed of (4), (5), and (6).", + "answer": "(1) clay; (2) quartz; (3) feldspar; (4) crystalline phase; (5) glass phase; (6) gas phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的材料名称和结构组成，需要文字回答而非选择或判断 | 知识层次: 题目考查传统陶瓷的基本原料和结构组成，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅需回忆传统陶瓷的基本原料和结构组成。在选择题型中，题目直接给出了正确选项，无需进行复杂的概念比较或分析。学生只需记住粘土、石英、长石这三种原料，以及晶相、玻璃相、气相这三种结构组成即可。这种题目在选择题中属于最简单的难度等级，主要考察学生对基础知识的记忆能力。" + }, + { + "idx": 3038, + "question": "The structure of glass is an irregular network formed by silicon-oxygen tetrahedra in space.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（玻璃的结构是由硅氧四面体在空间中形成的无规则网络），并要求判断其正确性（答案用√表示正确），这符合判断题的特征。 | 知识层次: 题目考查对玻璃结构这一基础概念的记忆和理解，涉及硅氧四面体在空间中的不规则网络结构这一基本原理。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断关于玻璃结构的描述是否正确，涉及的是基础概念的记忆，无需深入理解或分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3039, + "question": "What type of alloy is YT30?", + "answer": "Tungsten-cobalt-titanium alloy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求提供具体的合金类型名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对YT30合金类型的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆YT30合金的基本分类（钨钴钛合金），属于最基础的定义性知识。不需要任何解释或分析步骤，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3040, + "question": "Which compounds can be used to prepare high-temperature ceramics?", + "answer": "(1) Oxides; (2) Carbides; (3) Nitrides; (4) Borides; (5) Silicides", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择可以用于制备高温陶瓷的化合物，答案给出了多个具体选项供选择 | 知识层次: 题目考查对高温陶瓷制备材料的分类和基本概念的记忆，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别和记忆哪些化合物可用于制备高温陶瓷。正确选项直接列出了氧化物、碳化物、氮化物、硼化物和硅化物，这些都是高温陶瓷的常见原料，无需深入理解或辨析。因此，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3041, + "question": "What are the main components of YT30 alloy?", + "answer": "WC, TiC, and Co", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举YT30合金的主要成分，答案以文字形式给出具体成分，不需要计算或选择，属于简答题类型 | 知识层次: 题目考查对YT30合金主要成分的基础概念记忆，属于定义和分类层面的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接询问YT30合金的主要成分，正确选项明确列出了三种成分（WC, TiC, Co），属于基础概念记忆层次。学生只需回忆合金的基本组成即可作答，无需进行概念解释或复杂分析，符合等级1的简单记忆性知识要求。" + }, + { + "idx": 3042, + "question": "What can YT30 alloy be used to make?", + "answer": "Cutting tool edges", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释YT30合金的用途，答案是一个简短的文字描述而非选择或判断，符合简答题的特征 | 知识层次: 题目考查对YT30合金用途的基础概念记忆，仅需回忆该合金的典型应用场景，无需深入分析或综合推理。 | 难度: 该题目属于基础概念记忆类型，仅需识别YT30合金的常见用途（切削工具刃口），无需解释或分析复杂概念体系。在选择题型中，这种直接回忆单一事实的题目属于最低难度等级。" + }, + { + "idx": 3043, + "question": "Oxide ceramics have a close-packed structure and exhibit high melting points and chemical stability due to strong ionic bonds.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对氧化物陶瓷基本特性的记忆和理解，包括其紧密堆积结构、高熔点和化学稳定性等基础概念，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆氧化物陶瓷的基本特性（如紧密堆积结构、高熔点、化学稳定性及强离子键）即可做出正确判断，无需深入理解或分析多个概念。" + }, + { + "idx": 3044, + "question": "What are the main bonding types of these compounds?", + "answer": "(6) Covalent bond; (7) Ionic bond", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释化合物的主要键合类型，答案以文字形式给出，需要简要描述不同类型的键合方式，符合简答题的特征。 | 知识层次: 题目考查对化合物主要键合类型（共价键和离子键）的基本概念记忆和分类理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求识别和记忆化合物的主要键合类型（共价键和离子键），属于基础概念记忆层次。题目直接给出了正确选项，无需复杂的分析或推理步骤，因此属于最简单的难度等级。" + }, + { + "idx": 3045, + "question": "Ceramic materials can be used as high-temperature materials and also as wear-resistant materials.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对陶瓷材料基本应用领域的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念正误判断题，仅需记忆陶瓷材料的基本应用领域（高温材料和耐磨材料），无需深入理解或分析多个概念。在选择题型中，这是最简单的难度等级，仅需识别陈述是否符合基础定义。" + }, + { + "idx": 3046, + "question": "What type of chemical bond is primarily found in nitrides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对化学键类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆氮化物中主要的化学键类型（共价键），但选项中的其他键类型（金属键、分子键、离子键）与共价键有较明显的区别，只需基础的概念理解和简单辨析即可选出正确答案。不需要复杂的分析或深度理解多个概念之间的关系。" + }, + { + "idx": 3047, + "question": "Ceramic materials can be used as cutting tool materials, and can also be used as thermal insulation materials.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Ceramic materials can be used as cutting tool materials, and can also be used as thermal insulation materials），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查对陶瓷材料基本用途的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆陶瓷材料的常见用途即可作答，无需深入理解或分析多个概念。题目直接陈述了陶瓷材料的两种应用，正确选项明确，属于最基础难度的记忆性知识题目。" + }, + { + "idx": 3048, + "question": "What type of chemical bond is primarily found in oxides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择关于氧化物中主要化学键类型的正确答案 | 知识层次: 题目考查对氧化物中主要化学键类型的基础概念记忆，属于定义和分类层面的基本知识。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需识别氧化物中主要存在的化学键类型（离子键），无需进行概念辨析或复杂分析。题目选项直接对应基本知识点，属于最简单的难度等级。" + }, + { + "idx": 3049, + "question": "Ceramic materials have low tensile strength but high compressive strength.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（陶瓷材料具有低抗拉强度但高抗压强度），并要求判断其正确性（答案用√表示正确），这符合判断题的特征。 | 知识层次: 题目考查对陶瓷材料基本力学性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆陶瓷材料的基本力学特性（低抗拉强度、高抗压强度）即可作答。在选择题型中属于最简单的难度等级，不需要理解或分析复杂概念。" + }, + { + "idx": 3050, + "question": "The porosity of special ceramics is (4). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(4)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查特殊陶瓷孔隙率这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆特殊陶瓷的孔隙率范围即可作答，无需复杂理解或辨析步骤。" + }, + { + "idx": 3051, + "question": "The porosity of cermet is (1). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对cermet孔隙率这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆金属陶瓷（cermet）的孔隙率范围即可作答。题目选项设置简单明确，无需进行概念辨析或复杂推理，完全符合等级1\"简单概念识别，直接记忆\"的特征。在选择题型中属于最基础的难度层级。" + }, + { + "idx": 3052, + "question": "The porosity of ordinary ceramics is (2). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(2)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查普通陶瓷孔隙率的基本概念记忆，属于定义性知识的直接回忆，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆普通陶瓷的孔隙率范围即可选出正确答案，无需复杂理解或分析步骤。" + }, + { + "idx": 3053, + "question": "The porosity of thermal insulation material is (3). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(3)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对热绝缘材料孔隙率范围的基础概念记忆，属于定义性知识的直接回忆。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆热绝缘材料的孔隙率范围即可选择正确答案。选项之间的区分度明显，无需复杂分析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 3054, + "question": "What are the main types of special ceramics? Options: A. Cement B. Alumina C. Silicon carbide D. Boron nitride E. Refractory materials F. Household ceramics G. Silicon nitride H. Glass", + "answer": "B,C,D,E,G", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择特殊陶瓷的主要类型，答案给出了具体选项组合，符合选择题的特征 | 知识层次: 题目考查对特殊陶瓷主要类型的基础概念记忆，属于分类知识的直接回忆，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别特殊陶瓷的主要类型。正确选项（B, C, D, E, G）均为常见的特殊陶瓷材料，且题目明确给出了选项范围，无需复杂辨析或深度理解。学生只需记住这些基本分类即可正确作答，因此难度等级为1。" + }, + { + "idx": 3055, + "question": "What can alumina ceramic be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "C,E", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案形式为选项字母组合，符合选择题的特征 | 知识层次: 题目考查对氧化铝陶瓷常见用途的基础概念记忆，只需从给定选项中选择正确的应用场景，不涉及复杂分析或综合运用。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生了解氧化铝陶瓷的基本用途。虽然需要记忆多个应用场景，但选项之间的区分度较高，只需简单辨析即可选出正确答案。不需要复杂的分析或深度理解，因此属于等级2难度。" + }, + { + "idx": 3056, + "question": "What can SiC ceramics be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对SiC陶瓷用途的基本概念记忆，属于基础知识的直接回忆和识别，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆层次，仅需识别SiC陶瓷的基本用途。选项B（Blade）是直接记忆性知识点，无需复杂分析或概念辨析，符合等级1的简单概念识别标准。" + }, + { + "idx": 3057, + "question": "What can silicon nitride ceramics be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "A,D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项列表和答案组合 | 知识层次: 题目考查对氮化硅陶瓷用途的基础概念记忆，只需从选项中识别其典型应用场景，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别硅氮化物陶瓷的基本用途。选项直接对应材料的基本应用领域（研磨轮和磨料），无需复杂辨析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 3058, + "question": "What are included in traditional ceramics? Options: A. Cement B. Alumina C. Silicon carbide D. Boron nitride E. Refractory materials F. Household ceramics G. Silicon nitride H. Glass", + "answer": "A,F,H", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项列表和答案组合 | 知识层次: 题目考查对传统陶瓷分类的基础概念记忆，只需识别哪些选项属于传统陶瓷范畴，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别传统陶瓷的常见组成材料（水泥、家用陶瓷、玻璃）。选项明确区分传统陶瓷与先进陶瓷材料，无需复杂分析或深度理解，属于直接记忆性知识。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3059, + "question": "What material is suitable for a thermocouple sheath? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramics D.Manganese brass", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择适合用于热电偶护套的材料，且提供了四个具体选项和唯一正确答案 | 知识层次: 题目考查对热电偶套管材料选择的基本概念记忆，只需知道高温陶瓷具有耐高温特性这一基础知识即可作答，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆热电偶护套材料的合适选项。选项C（高温陶瓷）是热电偶护套的常见材料，属于直接记忆性知识，无需复杂辨析或深度理解。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3060, + "question": "What type of chemical bond is primarily found in carbides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对碳化物中主要化学键类型的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆碳化物的主要化学键类型，但选项中的概念区分较为明确（金属键、共价键、分子键、离子键），且共价键是碳化物最典型的键型这一知识点在基础化学中较为常见。不过仍需要一定的概念理解能力来排除其他干扰选项，因此属于等级2难度。" + }, + { + "idx": 3061, + "question": "What material is suitable for the handle of a test pen? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramic D.Manganese brass", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择最适合用于测试笔手柄的材料，答案形式为单一选项（A）。 | 知识层次: 题目考查对材料基本性质和适用场景的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆类型，仅需识别和记忆常见材料的应用场景。选项A（Polyvinyl chloride）是测试笔手柄的常见材料，属于直接记忆性知识，无需复杂理解或辨析。其他选项虽然涉及不同材料，但题目要求的是基础应用场景的识别，因此难度等级为1。" + }, + { + "idx": 3062, + "question": "What material is suitable for steam turbine blades? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramics D.Manganese brass", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择最适合蒸汽涡轮叶片的材料，答案形式为选项中的一个字母 | 知识层次: 题目考查对特定应用场景下材料选择的基本知识，需要理解不同材料的特性和适用环境，但不需要复杂的分析或综合推理。 | 难度: 在选择题中属于简单难度，题目直接考察对蒸汽轮机叶片材料的基本知识，只需识别2Cr13是适合的材料，无需复杂计算或多步骤推理。" + }, + { + "idx": 3063, + "question": "In which fields can ceramic materials be applied?", + "answer": "Applied in insulation, wear resistance, corrosion resistance, and high-temperature resistant parts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举陶瓷材料的应用领域，答案以文字解释和论述的形式给出，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查陶瓷材料在不同领域的应用，属于直接套用已知知识点的简单应用，不需要复杂的分析或综合。 | 难度: 在选择题中属于简单应用过程描述，题目直接考察陶瓷材料的应用领域，正确选项列举了具体的应用场景（绝缘、耐磨、耐腐蚀、耐高温部件），无需复杂分析或计算，仅需基本知识记忆即可作答。" + }, + { + "idx": 3064, + "question": "What is special ceramics?", + "answer": "To improve the performance of ordinary ceramics, it was found that the impurities brought by natural raw materials were quite unfavorable. Therefore, high-purity artificially synthesized raw materials were adopted, and the forming and sintering processes of ordinary ceramics were followed to produce new types of ceramics. These ceramics are called special ceramics, such as oxide ceramics and piezoelectric ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“特殊陶瓷”进行定义和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目考查特殊陶瓷的定义和基本原理，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项提供了较为详细的解释和描述，包括特殊陶瓷的定义、产生背景、制作方法以及具体例子。这要求考生不仅要记住基本定义，还需要理解相关背景知识和具体应用实例。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 3065, + "question": "What are the similarities and differences in composition between traditional ceramics and special ceramics?", + "answer": "Similarities and differences in composition: a) Traditional ceramics are made from clay, feldspar, and quartz as raw materials. b) Special ceramics: They are formed and sintered using traditional processes with artificially synthesized raw materials (various compounds with no or fewer impurities, such as oxides, nitrides, carbides). Their compositional characteristic is fewer impurities compared to traditional ceramics, and since artificially synthesized powders are used, the composition can be adjusted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对传统陶瓷和特种陶瓷的成分进行相似性和差异性的解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目主要考查对传统陶瓷和特种陶瓷组成的基本概念的记忆和理解，涉及它们的原材料和成分特点，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个概念（传统陶瓷和特种陶瓷）的比较，但正确选项已经提供了明确的相似点和差异点，考生只需识别和匹配这些信息即可。不需要进行复杂的分析或推理，主要考察的是对基础概念的记忆和理解。因此，难度等级为2。" + }, + { + "idx": 3066, + "question": "Why are ceramic materials brittle?", + "answer": "The brittleness of ceramic materials is influenced by both microstructural factors and macroscopic organization. From a microstructural perspective, the bonding in ceramic materials is ionic. If relative displacement occurs in ionic crystals, the electrical balance is lost, leading to the destruction of the ionic bonds, which is why materials bonded by ionic bonds are brittle. From a macroscopic organizational standpoint, ceramic materials contain a large number of pores (5%~10%), which reduce the load-bearing area when the ceramic is under stress, with pores being particularly prone to stress concentration. In summary, ceramic materials are brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷材料脆性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从微观结构和宏观组织两个角度综合分析陶瓷材料的脆性，涉及离子键的破坏机理和孔隙对力学性能的影响，需要深入理解和推理分析多个相关概念及其相互作用。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解陶瓷材料脆性的基本概念，还需要从微观结构（离子键特性）和宏观组织（孔隙影响）两个层面进行综合分析。正确选项涉及复杂的材料科学机理解释，需要考生具备将微观键合原理与宏观力学性能关联的能力，并能整合多个知识点进行推理分析。这种深度解释和全面分析的要求远超一般选择题的认知层次，属于需要高阶思维能力的复杂题目类型。" + }, + { + "idx": 3067, + "question": "What are the characteristics of ceramic materials?", + "answer": "Main performance characteristics: high hardness, high wear resistance, high elastic modulus, relatively high compressive strength, excellent high-temperature strength, good insulation, excellent high-temperature oxidation resistance, and good corrosion resistance. The disadvantages are high brittleness and low impact toughness. Solving the problem of ceramic toughening is the key to its application in the mechanical industry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释陶瓷材料的特性，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对陶瓷材料基本特性的记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求记忆陶瓷材料的主要性能特征和缺点，但涉及多个具体特性（如高硬度、高耐磨性、高弹性模量等）以及关键应用问题（陶瓷增韧）。这需要考生不仅记住基础概念，还要理解这些特性之间的关系及其在实际应用中的重要性。因此，它比简单的定义记忆题（等级1）要复杂，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 3068, + "question": "What is traditionally referred to as 'ceramics'?", + "answer": "Ordinary ceramics are inorganic polycrystalline solid materials obtained by processing natural silicate minerals (such as clay, feldspar, and quartz) through raw material processing—forming—sintering. Therefore, this type of ceramics is also called silicate ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“ceramics”进行定义和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对传统陶瓷材料的基本定义和组成成分的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项提供了较为详细的定义和分类信息，需要考生对\"ceramics\"的定义和组成材料有一定的理解和记忆。相比于仅要求简单定义的等级1题目，该题目要求考生掌握更具体的概念解释和描述，因此属于等级2难度。" + }, + { + "idx": 3069, + "question": "Why is the tensile strength of ceramics often much lower than the theoretical strength?", + "answer": "Due to the splitting effect of pores and stress concentration during tension, the tensile strength of ceramics is lower than the theoretical strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的抗拉强度通常远低于理论强度，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释陶瓷材料拉伸强度低于理论强度的原因，涉及孔隙效应和应力集中等复杂机理的分析，需要综合运用材料科学知识进行推理和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解陶瓷材料的基本性能特点，还需要掌握孔隙和应力集中对材料强度影响的机理。正确选项涉及对复杂现象（孔隙分裂效应和应力集中）的综合分析，需要考生具备将理论知识应用于具体材料性能解释的能力。这超出了简单记忆或基础理解的范畴，属于需要机理深度解释的题目类型。" + }, + { + "idx": 3070, + "question": "What is reaction sintering?", + "answer": "Reaction sintering is a process in which ceramic powders of various compounds (such as Si, Si-SiN4 powder, etc.) are pressed into shape and then subjected to special chemical treatment during sintering to obtain ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"reaction sintering\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对反应烧结（reaction sintering）这一基本概念的定义和简单描述，属于基础概念的记忆和理解层次，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求考生理解反应烧结的定义和基本原理，但不需要进行复杂的概念体系阐述或比较分析。正确选项提供了明确的定义和基本过程描述，属于中等难度的选择题。" + }, + { + "idx": 3071, + "question": "What is wood composed of?", + "answer": "(1) Cellulose; (2) Lignin", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答木材的组成成分，答案以列举形式给出，需要简要说明而非选择或判断 | 知识层次: 题目考查木材的基本组成成分，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆木材的基本组成成分（纤维素和木质素），属于基础概念记忆层次。题目仅涉及简单的定义和分类，无需解释或复杂分析，因此难度等级为1。" + }, + { + "idx": 3072, + "question": "What is hot pressing sintering?", + "answer": "Hot pressing sintering is a method that uses ceramic powders of various compounds as raw materials, adds a small amount of additives, loads them into graphite molds, and sinters and forms under high temperature and high pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“hot pressing sintering”进行解释和论述，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查热压烧结的基本定义和过程，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆热压烧结的基本定义和过程，包括原材料、添加剂、模具类型以及烧结条件等关键要素。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要进行复杂的概念体系阐述或比较分析。因此，在选择题型内属于中等难度。" + }, + { + "idx": 3073, + "question": "What is gray cast iron composed of?", + "answer": "(3) steel matrix; (4) graphite", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案中给出了编号选项(3)和(4)，表明这是一个从多个选项中选择正确组合的选择题。 | 知识层次: 题目考查对灰铸铁组成成分的基础概念记忆，只需回答其基本构成要素（钢基体和石墨），不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅需基础概念记忆，直接考察灰铸铁的组成成分（钢基体和石墨），无需复杂理解或辨析，属于简单概念识别层级。" + }, + { + "idx": 3074, + "question": "What are the advantages and disadvantages of reaction sintering?", + "answer": "The porosity of reaction-sintered ceramics is as high as 20%~30%, so their strength is not as good as that of hot-pressed sintered ceramics. However, reaction-sintered ceramics can often be machined during chemical processing, making them suitable for producing heat-resistant, wear-resistant, corrosion-resistant insulating products with complex shapes and high dimensional accuracy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释反应烧结的优缺点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析反应烧结的优缺点，涉及对材料性能的综合理解和应用，需要关联多个知识点（如孔隙率、强度、加工性能等）进行综合分析，但不需要深入机理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解反应烧结陶瓷的孔隙率、强度特点以及加工优势，并进行综合分析比较。题目涉及多个概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3075, + "question": "What are the advantages and disadvantages of hot pressing sintering?", + "answer": "Hot pressing sintered ceramics are limited by the mold shape and can only process simple-shaped wear-resistant and high-temperature-resistant products (e.g., cutting tools). However, hot pressing sintered ceramics have higher strength, are dense, and have extremely low porosity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释热压烧结的优点和缺点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析热压烧结的优缺点，需要理解热压烧结的基本原理，并能够关联其在实际应用中的限制和优势。这涉及到多方面的综合分析，包括材料性能、加工限制等，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解热压烧结陶瓷的优缺点，并进行综合分析。题目要求考生掌握热压烧结工艺的限制（如模具形状限制）和优势（如高强度、低孔隙率），并能够将这些概念关联起来进行比较。虽然不需要多步计算，但需要对相关概念有较深的理解和综合分析能力。" + }, + { + "idx": 3076, + "question": "In fiber composites, what should the length of carbon fiber be", + "answer": "Tall", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释碳纤维在复合材料中的合适长度，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查碳纤维在复合材料中的长度要求，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即碳纤维长度的基本定义。正确选项\"Tall\"直接对应记忆性知识点，无需复杂推理或概念比较，属于最基础的难度等级。" + }, + { + "idx": 3077, + "question": "In fiber-reinforced composites, the fibers with relatively good performance are mainly (1), (2), (3), (4).", + "answer": "(1)glass fiber; (2)carbon fiber; (3)boron fiber; (4)silicon carbide fiber", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举性能较好的纤维增强复合材料中的纤维类型，答案以列举的形式给出，不需要计算或判断对错，属于简答题类型。 | 知识层次: 题目主要考查对纤维增强复合材料中常用高性能纤维种类的记忆，属于基础概念和分类知识的范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆纤维增强复合材料中性能较好的纤维类型，属于基础概念记忆的简单题目。题目提供了明确的选项，无需进行复杂的概念解释或比较分析，仅需识别和回忆相关知识即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3078, + "question": "In fiber composite materials, how should the diameter of carbon fibers be", + "answer": "Small", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对碳纤维直径的选择进行解释，答案需要文字论述而非选择或判断 | 知识层次: 题目考查对碳纤维直径在纤维复合材料中作用的基本概念记忆和理解，属于基础性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即碳纤维直径的基本要求。题目直接询问\"how should the diameter of carbon fibers be\"，正确选项为\"Small\"，属于最基础的定义性知识，无需解释或分析。在选择题难度等级中，这属于最简单的等级1，即基本定义简答。" + }, + { + "idx": 3079, + "question": "In fiber composites, what should be the range of carbon fiber volume content", + "answer": "Higher", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对碳纤维体积含量的范围进行解释，答案\"Higher\"是一个简短的文字回答，需要进一步的论述和解释来说明为什么碳纤维体积含量应该较高。这符合简答题的特征，即需要文字解释而非选择、判断或计算。 | 知识层次: 题目涉及纤维复合材料中碳纤维体积含量的范围，需要理解复合材料的基本原理和性能影响因素，并结合实际应用场景进行综合分析。虽然不涉及复杂计算，但需要对材料性能和应用要求有一定的关联分析能力。 | 难度: 在选择题中属于中等难度，需要理解碳纤维体积含量的概念及其在复合材料中的作用，并能综合分析不同含量范围的影响。虽然题目给出了正确选项，但学生仍需具备一定的知识背景和应用能力才能准确判断。" + }, + { + "idx": 3080, + "question": "When designing fiber-reinforced composites, for a matrix with lower toughness, the coefficient of expansion of the fiber can be what? A. Slightly lower B. Very different C. Slightly higher D. The same", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案 | 知识层次: 题目涉及复合材料设计中纤维与基体热膨胀系数的匹配问题，需要理解材料性能之间的相互作用关系，并做出适当选择。这属于中等应用层次，需要将材料性能知识应用于具体设计情境中，但不需要复杂的计算或深度分析。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解纤维增强复合材料的基本概念，还需要掌握基体韧性与纤维膨胀系数之间的复杂关系。解题过程需要综合分析材料性能的匹配原则，并判断在特定条件下（基体韧性较低时）纤维膨胀系数的合理选择。这超出了简单记忆或单一概念应用的范畴，属于需要多步推理和综合分析的选择题。" + }, + { + "idx": 3081, + "question": "Tungsten-cobalt carbide is a composite material of (3) and (4)", + "answer": "(3)WC; (4)Co", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的材料名称（WC和Co），属于需要简短文字回答的形式，而非选择、判断或计算 | 知识层次: 题目考查对钨钴碳化物复合材料基本组成的记忆，属于基础概念的记忆性知识，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆钨钴碳化物（Tungsten-cobalt carbide）的基本组成成分WC和Co，属于基础概念记忆的简单题目。不需要解释或分析，只需直接回忆相关知识即可作答。" + }, + { + "idx": 3082, + "question": "In fiber-reinforced composites, the smaller the fiber diameter, the better the fiber reinforcement effect.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对纤维增强复合材料中纤维直径与增强效果关系的基本概念的理解和记忆，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆纤维增强复合材料中纤维直径与增强效果的基本关系即可作答，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3083, + "question": "What materials can be used to manufacture the vehicle body itself? Options: A. Carbon fiber resin composite material B. Thermosetting fiberglass C. Boron fiber resin composite material", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对车辆制造材料的基础概念记忆，只需从给定选项中选择正确的材料类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和直接回忆材料科学中的基本分类知识。选项明确且直接对应车辆制造中常用的材料，无需复杂辨析或深度理解。" + }, + { + "idx": 3084, + "question": "Fiberglass is a composite material of (1) and (2)", + "answer": "(1) Resin; (2) Glass fiber", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空缺部分的内容，答案以文字形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查对复合材料基本组成的记忆，仅需要回答树脂和玻璃纤维这两个基本成分，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对纤维玻璃复合材料基本组成的记忆，属于最基础的定义简答。学生只需回忆树脂和玻璃纤维这两个基本成分即可作答，无需任何解释或分析步骤，因此属于难度等级1。" + }, + { + "idx": 3085, + "question": "The reinforcing effect is best when the diameter of the fine particle phase in fine-grained composites is (1). A. $<0.01~\\\\mu\\\\mathrm{m}$ B.0.01\\\\~0.1-pm $\\\\mathrm{C.}>0.1\\\\mu m$", + "answer": "(1)B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对细粒复合材料中细颗粒相直径对增强效果影响的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目考察的是对细颗粒复合材料中细颗粒相直径范围的基础概念记忆，只需记住最佳增强效果的直径范围是0.01~0.1微米即可选择正确答案，无需复杂的理解或分析过程。" + }, + { + "idx": 3086, + "question": "In order to achieve high strength in composite materials, the elastic modulus of the fibers must be very high.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对复合材料中纤维弹性模量与强度关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅考察对复合材料强度与纤维弹性模量关系这一基础概念的简单记忆，无需深入理解或分析。正确选项直接对应教材中的基本原理陈述，属于最基础的选择题难度等级。" + }, + { + "idx": 3087, + "question": "When designing fiber composites, for a matrix with good plasticity, how can the coefficient of expansion of carbon fiber be? A. Slightly lower B. Very different C. Slightly higher D. The same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从选项（A. Slightly lower B. Very different C. Slightly higher D. The same）中选择正确答案 | 知识层次: 题目要求在设计纤维复合材料时，考虑基体塑性和碳纤维膨胀系数的匹配关系，需要理解材料性能之间的相互作用并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解复合材料设计中基体塑性与纤维膨胀系数的匹配关系，并进行概念关联分析。题目考察的是对材料性能协调性的综合判断能力，但不需要复杂的计算过程。" + }, + { + "idx": 3088, + "question": "What materials can be used to manufacture rocket supports? Options: A. Carbon fiber resin composite B. Thermosetting fiberglass C. Boron fiber resin composite", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对火箭支撑材料的基本概念记忆，只需要从给定的选项中选择正确的材料类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，此题需要考生理解不同复合材料的基本特性及其在火箭支撑结构中的应用。虽然选项都是复合材料，但需要考生对硼纤维树脂复合材料的特殊性能（如高强度、高刚度）有一定了解才能正确选择。这超出了简单的概念识别（等级1），但尚未达到需要复杂概念区分（等级3）的程度。" + }, + { + "idx": 3089, + "question": "What are the commonly used reinforcing fibers?", + "answer": "Glass fiber, carbon fiber, boron fiber, aramid fiber, silicon carbide fiber", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举常用的增强纤维类型，答案以列举形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查常见增强纤维的分类和记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆常见的增强纤维类型，属于基础概念记忆，无需解释或分析，解题步骤简单直接。" + }, + { + "idx": 3090, + "question": "What types can composites be divided into according to the category of matrix materials?", + "answer": "Non-metal matrix composites and metal matrix composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据基体材料的类别对复合材料进行分类，答案需要文字解释和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目考查复合材料根据基体材料分类的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆复合材料根据基体材料分类的基本定义（非金属基复合材料和金属基复合材料），属于最基础的概念记忆层次，无需解释或分析，因此属于等级1难度。" + }, + { + "idx": 3091, + "question": "What materials can be used to manufacture helicopter propeller blades? Options: A. Carbon fiber resin composite B. Thermosetting fiberglass C. Boron fiber resin composite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项中的一个字母。 | 知识层次: 题目考查对直升机螺旋桨叶片制造材料的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目仅要求考生识别直升机螺旋桨叶片制造材料的基本概念，选项中的碳纤维树脂复合材料是常见的应用材料，属于基础概念记忆范畴，无需复杂分析或深度理解。" + }, + { + "idx": 3092, + "question": "What is the reinforcement mechanism of fiber-reinforced composites?", + "answer": "Fiber-reinforced composites are formed by combining high-strength, high-modulus continuous (long) fibers or discontinuous (short) fibers with a matrix (resin, metal, ceramic, etc.). When the composite material is subjected to force, the high-strength, high-modulus reinforcing fibers bear most of the load, while the matrix primarily acts as a medium to transfer and disperse the load.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释纤维增强复合材料的增强机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查纤维增强复合材料的基本增强机制，属于基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述纤维增强复合材料的增强机制，包括纤维和基体的作用。这比简单的定义记忆（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 3093, + "question": "What types can composites be classified into based on the types of reinforcing materials?", + "answer": "Fiber-reinforced composites, particle-reinforced composites, and laminated composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释复合材料基于增强材料类型的分类，答案以文字形式给出具体分类，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查复合材料按增强材料类型分类的基本概念记忆和理解 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即复合材料根据增强材料类型的分类。正确选项直接给出了三种明确的分类（纤维增强、颗粒增强和层压复合材料），无需复杂推理或概念间的比较分析。属于最基本的选择题难度，只需识别和回忆定义性知识即可作答。" + }, + { + "idx": 3094, + "question": "What are the factors affecting the widespread application of composite materials?", + "answer": "Composite materials refer to multiphase materials artificially synthesized from two or more materials with different properties through various processing methods. Composites not only retain the optimal characteristics of their constituent materials but also exhibit new properties after combination. For example, the fracture energy of glass fibers is only 7.5×10^-2 J, while common resins have a fracture energy of about 2.26×10^-2 J. However, the composite material composed of glass fibers and thermosetting resins, known as thermosetting fiberglass, achieves a fracture energy as high as 17.6 J, with strength significantly higher than that of resins and brittleness much lower than that of glass fibers. It is evident that 'compositing' has become an important means to improve material performance. Therefore, composite materials are attracting increasing attention, and the development and application of new composite materials are becoming more widespread.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响复合材料广泛应用的因素，答案提供了详细的文字论述和例子，符合简答题的特征 | 知识层次: 题目要求分析影响复合材料广泛应用的因素，需要理解复合材料的基本概念和性能特点，并结合实际应用中的问题进行综合分析。虽然涉及基础概念，但更侧重于应用层面的分析和讨论，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解复合材料的基本定义和特性，还需要通过具体实例（如玻璃纤维和树脂的复合）分析复合材料的性能提升机制。此外，题目涉及断裂能量等具体数值的比较和综合分析，要求考生具备较强的概念关联能力和多角度分析能力。因此，在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 3095, + "question": "What are the performance characteristics of carbon fiber?", + "answer": "Low density, high strength and modulus. It has good high and low temperature performance, high chemical stability; small thermal expansion coefficient, high thermal conductivity, good electrical conductivity and self-lubrication. Its disadvantages are high brittleness and susceptibility to oxidation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释碳纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对碳纤维性能特征的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生不仅记忆碳纤维的基本性能特点（如低密度、高强度等），还需要理解并描述其优缺点（如高脆性、易氧化等）。这超出了简单的定义记忆（等级1），但尚未达到需要分析复杂概念体系的程度（等级3）。题目主要考察对材料性能的概念解释和描述能力，符合等级2的难度标准。" + }, + { + "idx": 3096, + "question": "What are the performance characteristics of fiberglass?", + "answer": "The density is 2.4~2.7g/cm³, similar to aluminum. The tensile strength is dozens of times higher than that of bulk glass and even higher than that of bulk high-strength alloy steel. The elastic modulus is 5~8 times higher than that of other artificial fibers, and the elongation is lower than that of other organic fibers. It has relatively high heat resistance, good corrosion resistance, and excellent chemical stability to other solvents. It is easy to produce and inexpensive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对纤维玻璃的性能特点进行详细的文字解释和论述，答案提供了多个方面的性能描述，符合简答题的特征。 | 知识层次: 题目主要考查对纤维玻璃性能特点的基础概念记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个性能特征的描述，但每个特征都是基础概念的记忆性知识，不需要复杂的分析或比较。正确选项提供了具体的数值和比较，但整体上仍属于概念解释和描述的范畴，没有达到复杂概念体系阐述的层次。" + }, + { + "idx": 3097, + "question": "Through what means can the performance of composite materials be further improved and their application scope expanded?", + "answer": "Composite materials refer to multiphase materials artificially synthesized from two or more materials with different properties through various process methods. Composite materials not only retain the optimal characteristics of their constituent materials but also possess new properties resulting from their combination. For example, the fracture energy of glass fiber is only 7.5×10^-2J, while that of commonly used resin is about 2.26×10^-2J. However, the composite material composed of glass fiber and thermosetting resin, known as thermosetting fiberglass, has a fracture energy as high as 17.6J, with its strength significantly higher than that of resin and its brittleness much lower than that of glass fiber. It is evident that 'compositing' has become an important means to improve material performance. Therefore, composite materials are attracting increasing attention, and the development and application of new composite materials are becoming more widespread.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何提高复合材料性能并扩大其应用范围，答案提供了详细的解释和例子，符合简答题的特征。 | 知识层次: 题目要求分析复合材料的性能提升方法和应用范围扩展，涉及多材料组合的综合性能分析、机理解释和实际应用的综合考量，需要深入理解和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解复合材料的基本概念，还需要通过具体数据（如断裂能数值）进行复杂现象的分析和推理。此外，题目涉及多材料性能的综合比较和新性能的机理解释，需要考生具备较高的综合分析能力和深度知识掌握。这种题目在选择题中属于要求最高、复杂度最大的类型。" + }, + { + "idx": 3098, + "question": "What are the performance characteristics of boron fibers?", + "answer": "Boron fibers have a high melting point, high strength, high elastic modulus, and good oxidation resistance and corrosion resistance. Their disadvantages include high density, large diameter, complex production process, high cost, and expensive price.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释硼纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查硼纤维性能特征的基础概念记忆和理解，属于对材料特性的直接描述和列举，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及硼纤维的性能特点，但正确选项已经明确列出了其主要特性和缺点，属于概念解释和描述的范畴。考生需要记忆和理解这些特性，但不需要进行复杂的分析或比较。因此，在选择题型内，这属于等级2的难度。" + }, + { + "idx": 3099, + "question": "What are the performance characteristics of silicon carbide fibers?", + "answer": "High melting point, high strength, high modulus ceramic fibers, mainly used to reinforce metals and ceramics. The outstanding feature is excellent high-temperature strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释硅碳纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对碳化硅纤维性能特征的基础概念记忆和理解，属于定义和分类层面的知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及硅碳纤维的性能特点，但正确选项提供了明确的性能描述和主要用途，属于概念解释和描述的层次。考生需要理解并记忆硅碳纤维的基本特性，但不需要进行复杂的分析或比较。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 3100, + "question": "What are the performance characteristics of aramid fiber?", + "answer": "Its most notable characteristics are high specific strength and specific modulus. It has low density, good toughness, better heat resistance than glass fiber, excellent fatigue resistance, corrosion resistance, insulation properties, and processability, and is inexpensive.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释芳纶纤维的性能特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对芳纶纤维性能特点的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个性能特征，但所有信息都是关于aramid fiber的基础特性描述，属于概念解释和描述层次。不需要复杂的比较分析或深入理解概念间的关系，只需记忆和识别关键性能特点即可。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3101, + "question": "What is the reinforcement mechanism of particle-reinforced composites?", + "answer": "The reinforcement mechanism of particle-reinforced composites is divided into two types: 1. Dispersion-strengthened composites are materials formed by dispersing and uniformly distributing particles (less than 0.1 micrometers) of one or several materials within the matrix material. The reinforcement mechanism of such composites is: under external forces, the matrix of the composite primarily bears the load, while the uniformly dispersed reinforcing particles hinder the movement of dislocations causing collective plastic deformation (e.g., the bypass mechanism in metal matrices) or molecular chain movement (in polymer matrices). The strengthening effect is related to particle diameter and volume fraction; the smaller the particle size and the higher the volume fraction, the better the strengthening effect. Typically, particle diameters range from 0.01 to 0.1 micrometers, and volume fractions range from 1% to 15%. 2. Particle-reinforced composites are materials formed by bonding metal oxides, carbides, or nitrides, which have good heat resistance and high hardness but poor impact resistance, using metals or polymer binders. These materials combine the advantages of high hardness and heat resistance of ceramics with the benefits of low brittleness and good impact resistance, demonstrating outstanding composite effects. Since the reinforcing particles are relatively large (greater than 1 micrometer), they do not significantly hinder dislocation slip (in metal matrices) or molecular chain movement (in polymer matrices), so the strengthening effect is not significant. Particle-reinforced composites are primarily used not to enhance strength but to improve wear resistance or overall mechanical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释粒子增强复合材料的增强机制，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求详细解释颗粒增强复合材料的增强机制，涉及两种不同类型的复合材料及其各自的增强原理。需要深入理解分散强化和颗粒增强的机理，包括粒子尺寸、体积分数对强化效果的影响，以及不同基体材料（金属或聚合物）中的位错运动或分子链运动的阻碍机制。此外，还需要综合分析这些因素如何共同作用以实现复合材料的性能优化。这种深度和广度的分析要求属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面理解并分析粒子增强复合材料的两种强化机制，包括分散强化复合材料和颗粒增强复合材料的具体机理、影响因素（如粒径和体积分数）以及应用特点。这不仅需要考生掌握材料科学中的多个核心概念，还需要能够进行综合推理和机理解释，属于复杂现象全面分析的层次。选择题型中，这种深度和广度的知识要求以及分析能力的需求，使得该题目难度显著高于一般的选择题。" + }, + { + "idx": 3102, + "question": "Elastic alloys can be divided into two major categories: (1) and (2).", + "answer": "(1) High elastic alloys; (2) Constant elastic alloys", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个类别的名称，需要文字回答而非选择或判断 | 知识层次: 题目考查弹性合金的基本分类记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆弹性合金的两个主要分类名称，属于基础概念记忆的简单题目。无需解释或分析，只需直接回忆分类名称即可作答，因此难度最低。" + }, + { + "idx": 3103, + "question": "What is the development direction of materials science?", + "answer": "In the 21st century, materials science will inevitably develop towards high functionality, ultra-high performance, complexity (compositing and complicating), refinement, ecological environmentalization, and intelligence, based on the rapid advancement of science and technology, thereby making greater contributions to the material civilization of human society.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对材料科学的发展方向进行文字解释和论述，答案是一段详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求对材料科学的发展方向进行综合分析和论述，涉及多个高级概念（如高功能性、超高性能、复杂性、生态环保化、智能化等）的关联和推理，需要深入理解材料科学的未来趋势及其对社会的影响，属于复杂分析和综合运用的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3104, + "question": "Commonly used expansion materials are divided into three categories: (1), (2), (3).", + "answer": "(1) Low expansion materials; (2) Controlled expansion materials; (3) High expansion materials", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写三类膨胀材料的名称，需要文字回答而非选择或判断 | 知识层次: 题目考查对膨胀材料分类的基本概念记忆，属于定义和分类的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别常见的膨胀材料分类，属于基础概念记忆的简单题目。题目直接给出了三个分类的正确选项，不需要进行复杂的分析或推理，仅需基本的记忆能力即可回答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3105, + "question": "High elastic alloys have (1). A. high elastic limit and high elastic modulus B. high elastic limit and low elastic modulus C. low elastic limit and high elastic modulus D. low elastic limit and low elastic modulus", + "answer": "(1)B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对高弹性合金基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然题目涉及高弹性合金的两个关键特性（弹性极限和弹性模量），但选项设计相对直接，只需理解高弹性合金的基本定义即可选出正确答案。不需要复杂的分析或多个概念的交叉比较，属于概念理解和简单辨析的层次。" + }, + { + "idx": 3106, + "question": "Below the critical temperature Tc, superconductors possess complete (1) what property?", + "answer": "Electrical conductivity", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字回答超导体在临界温度Tc以下具有的特定性质，答案是一个专业术语而非选项或判断，也不需要计算过程 | 知识层次: 题目考查超导体在临界温度以下的基本性质（完全导电性），属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对超导体基本特性的记忆，属于最基础的定义简答级别。题目直接询问超导体在临界温度以下具有的特定性质（完全导电性），无需任何解释或分析过程，只需识别并选择正确术语即可。" + }, + { + "idx": 3107, + "question": "Below the critical temperature Tc, superconductors exhibit complete (2) what property?", + "answer": "Diamagnetism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字回答超导体在临界温度以下表现出的特定性质，答案\"Diamagnetism\"是一个术语而非选项，需要学生对概念的理解和表述。 | 知识层次: 题目考查超导体在临界温度以下表现出的基本性质（完全抗磁性）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆超导体的基本特性之一——完全抗磁性（Diamagnetism）。题目直接考查定义性知识，无需解释或分析，解题步骤简单，属于最基础难度等级。" + }, + { + "idx": 3108, + "question": "Shape memory alloys utilize the characteristics of (1) and (2) of the material to achieve shape recovery.", + "answer": "(1) superelasticity; (2) shape memory effect", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个特定的术语来完成句子，需要考生回忆和写出具体的专业术语，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查形状记忆合金的基本特性（超弹性和形状记忆效应）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中属于基础难度，仅需记忆形状记忆合金的两个基本特性（超弹性和形状记忆效应）即可正确作答，无需进行概念解释或复杂分析。" + }, + { + "idx": 3109, + "question": "Resistance materials can be divided into (1), (2), and (3) according to their characteristics and applications.", + "answer": "(1) Precision resistance materials; (2) Film resistance materials; (3) Electric heating materials", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的分类名称，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对电阻材料分类的基本概念记忆，属于定义和分类的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求考生记忆并识别电阻材料的分类，属于基础概念的记忆性知识。正确选项直接对应题目中的空缺部分，无需复杂推理或分析，仅需对电阻材料的基本分类有清晰记忆即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3110, + "question": "Hydrogen storage alloys are alloys that form hydrogen-containing solid solutions by absorbing hydrogen, and under certain conditions, these alloys decompose to release hydrogen", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，并要求判断其正确性（答案以√表示正确），符合判断题的特征 | 知识层次: 题目考查对氢存储合金基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于储氢合金定义的陈述是否正确。在选择题型中，这种直接考察定义记忆的题目属于最简单的难度等级，不需要复杂的概念理解或分析过程。" + }, + { + "idx": 3111, + "question": "The temperature coefficient of resistance (1) of resistive materials. A. The larger the better B. The smaller the better C. No requirement on size", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查对电阻材料温度系数这一基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆电阻温度系数的基本定义即可作答。在选择题型中属于最简单的难度等级，不需要任何分析或推理过程，完全依赖对基础概念的识记能力。" + }, + { + "idx": 3112, + "question": "Shape memory alloy components undergo plastic deformation in the (1) state and recover their original shape after (2). A. Martensite Heating transforms into parent phase B. Parent phase Cooling transforms into martensite C. Martensite Staying for several days D. Parent phase Heating transforms into new parent phase", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查形状记忆合金的基本相变过程，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解形状记忆合金的基本原理和相变过程，但选项设计较为直接，只需识别正确的相变状态即可选出答案。" + }, + { + "idx": 3113, + "question": "The active layer and passive layer of a thermostatic bimetal strip are respectively (1). A. Constant expansion alloy and high expansion alloy B. High expansion alloy and constant expansion alloy C. Constant expansion alloy and low expansion alloy D. High expansion alloy and low expansion alloy", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了四个选项供选择，符合选择题的特征。 | 知识层次: 题目考查对热双金属片主动层和被动层材料分类的基础概念记忆，属于定义和分类的基本原理记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然考察的是基础概念记忆（热双金属片的主动层和被动层材料），但需要考生区分高膨胀合金和低膨胀合金的概念，并进行简单配对。相比纯粹的定义复述（等级1），此题需要一定的概念理解和材料特性辨析能力，但不需要复杂的分析过程（等级3）。正确选项D的区分度主要体现在对\"高/低膨胀\"这一组对立概念的掌握上。" + }, + { + "idx": 3114, + "question": "What characteristics do high-elastic alloys have?", + "answer": "These alloys require a high elastic limit σe and a low elastic modulus E, meaning a high σe/E ratio, which minimizes the elastic after-effect of components and ensures stable operation. Additionally, they must possess high fatigue strength and good workability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释高弹性合金的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查高弹性合金的基本特性，包括弹性极限、弹性模量、疲劳强度和加工性能等基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（弹性极限、弹性模量、疲劳强度、加工性等），但正确选项已经将这些概念整合成一条清晰的逻辑链，考生只需理解并匹配这些基本概念即可选出正确答案。不需要进行复杂的比较分析或推导，但需要掌握相关术语的定义和基本关系。" + }, + { + "idx": 3115, + "question": "What are the characteristics of future materials science research?", + "answer": "Currently, due to the increasing demand for new materials, there is a desire to enhance theoretical predictability and reduce blind experimentation in materials development as much as possible. Objectively, the in-depth development of modern fundamental sciences such as physics and chemistry has provided many new principles and concepts. More importantly, advancements in computer information processing technology, as well as various material preparation and characterization techniques, have led to some new features in materials development and design. 1) In terms of the microscopic structure design of materials, the focus will shift from the microstructural level (-1μm) to the molecular and atomic levels (1~10nm) and the electronic level (0.1~1nm) (developing micrometer and nanometer materials). 2) The conceptual idea of mixing organic, inorganic, and metallic materials at the atomic and molecular levels to form so-called 'hybrid' (Hybrid) materials, exploring new pathways for synthetic materials. 3) In the development of new materials, based on databases and knowledge repositories, computers are used to predict the properties of new materials and simulate the relationship between the microscopic structure and properties of new materials. 4) In-depth research into the production processes of materials under various conditions, employing new thinking and adopting new technologies to develop new materials, such as the design of semiconductor superlattice materials, exemplified by 'bandgap engineering' or 'atomic engineering.' This involves controlling the electronic structure of materials to create multilayer heterostructure periodic materials composed of alternating ultrathin layers of different semiconductors, thereby greatly advancing the development of semiconductor lasers. 5) Selecting key objectives and organizing multidisciplinary efforts to jointly design certain new materials, such as the concept and practice of 'functionally graded' materials (FGM) proposed according to the requirements of aerospace thermal protection materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对材料科学未来研究的特征进行详细的文字解释和论述，答案提供了多个方面的详细描述，符合简答题的特点。 | 知识层次: 题目要求对材料科学未来研究的特点进行详细论述，涉及多个复杂概念和跨学科知识的综合运用，如微观结构设计、混合材料概念、计算机模拟、生产工艺研究以及多学科协作设计新材料等。这需要深入理解材料科学的前沿发展，并能将这些概念关联起来进行综合分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目涉及未来材料科学研究的多个复杂特征，包括微观结构设计、混合材料概念、计算机预测与模拟、材料生产工艺研究以及多学科协作设计新材料等。这些内容不仅要求考生具备深厚的材料科学基础知识，还需要能够综合运用物理、化学、计算机等多学科知识进行推理分析。此外，题目中的概念如\"功能梯度材料\"和\"半导体超晶格材料\"的设计原理，需要对材料科学的前沿研究有深入理解。因此，该题目在选择题型内属于复杂现象全面分析的难度等级。" + }, + { + "idx": 3116, + "question": "What are the categories of high elastic alloys?", + "answer": "High elastic alloys can be divided into steel, copper alloys, nickel-based and cobalt-based alloys by composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对高弹性合金的分类进行文字解释和论述，答案提供了详细的分类说明，符合简答题的特征。 | 知识层次: 题目考查高弹性合金的分类，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆高弹性合金的基本分类，属于基础概念记忆层次。题目直接给出了明确的分类选项，不需要进行复杂的分析或推理，仅需识别正确分类即可。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3117, + "question": "What are the characteristics of constant expansion alloys?", + "answer": "Materials with a certain coefficient of expansion within a specific temperature range are called constant expansion materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释constant expansion alloys的特性，答案以文字形式进行解释和论述，符合简答题的特征。 | 知识层次: 题目考查对恒定膨胀合金特性的基本概念记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求识别和记忆基础定义，属于最简单的难度等级。正确选项直接给出了恒定膨胀合金的定义，不需要任何解释或分析步骤，仅需基础概念的记忆即可作答。" + }, + { + "idx": 3118, + "question": "What is resistive material?", + "answer": "Materials used in physical components that serve a resistive function in circuits are called resistive materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述\"resistive material\"的定义，答案是一个简短的文字说明，不需要选择、判断或计算。 | 知识层次: 题目考查对电阻材料这一基本概念的定义和功能的理解，属于基础概念记忆范畴 | 难度: 在选择题型中，此题仅考察对\"resistive material\"基本定义的记忆，属于最基础的概念性知识。题目直接给出了定义性描述，不需要任何解释或分析过程，符合等级1\"基本定义简答\"的标准。在选择题难度谱系中，这是最简单的题型，只需识别正确定义即可。" + }, + { + "idx": 3119, + "question": "What is the main use of controlled expansion alloys?", + "answer": "This type of material is used in the electric vacuum industry to seal with glass, ceramics, etc., requiring its expansion coefficient to match that of the sealed material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释controlled expansion alloys的主要用途，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对控制膨胀合金主要用途的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别控制膨胀合金的主要用途，属于基础概念记忆层次。题目直接给出了明确的定义和用途，无需进行复杂的分析或推理，因此难度等级为1。" + }, + { + "idx": 3120, + "question": "What are the characteristics of resistance materials?", + "answer": "The general requirements are high and stable resistance values, a small temperature coefficient of resistance, and sufficient mechanical strength, while also requiring a small thermoelectric potential with copper, good corrosion resistance, and ease of machining and welding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释电阻材料的特性，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对电阻材料特性的基本概念记忆和理解，不涉及复杂计算或综合分析，仅需列举和描述基本特性。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生记忆并理解电阻材料的基本特性，包括高且稳定的电阻值、小的温度系数、足够的机械强度等。虽然涉及多个特性，但都属于基础概念记忆范畴，不需要复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 3121, + "question": "What is the critical temperature Tc of a superconductor?", + "answer": "The temperature at which the resistance abruptly drops to zero is called the superconducting transition temperature or critical temperature Tc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对关键术语进行解释和论述，答案以文字形式给出，没有涉及计算或选择判断 | 知识层次: 题目考查超导体临界温度Tc的基本定义，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目仅要求记忆和识别超导体的临界温度Tc的基本定义，属于基础概念记忆层次。题目直接给出了正确选项，无需复杂的推理或分析步骤，因此难度等级为1。" + }, + { + "idx": 3122, + "question": "What is a superconductor?", + "answer": "Generally, the DC resistivity of metals decreases as temperature drops, and near absolute zero, the resistivity no longer continues to decline but approaches a finite value. However, the DC resistivity of certain conductors suddenly drops to zero at a specific low temperature, a phenomenon known as zero resistance or superconductivity. Objects exhibiting such superconducting properties are typically referred to as superconductors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对超导体进行定义和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对超导体这一基本概念的定义和现象的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但正确选项提供了较为详细的解释和描述，包括金属电阻率随温度变化的规律以及超导体的定义和特性。这要求考生不仅记住超导体的基本定义，还需要理解相关现象的描述。因此，该题目在选择题型内属于等级2的难度。" + }, + { + "idx": 3123, + "question": "What are the main uses of superconductors?", + "answer": "Superconductors can not only be used in superconducting generators, but also prove effective in applications such as superconducting motors, superconducting power transmission, superconducting energy storage, maglev trains, magnetohydrodynamic power generation, and nuclear fusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举超导体的主要用途，答案以文字解释和论述的形式给出，没有选项、对错判断或数值计算的要求。 | 知识层次: 题目考查对超导体主要用途的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求记忆超导体的主要用途，但正确选项列举了多个应用领域，需要考生对超导体的应用有较全面的了解。这超出了基本定义的简答（等级1），但尚未达到需要阐述复杂概念体系（等级3）的程度。因此，该题目属于概念解释和描述的难度等级（等级2）。" + }, + { + "idx": 3124, + "question": "Explain the basic concept and terminology: Superstructure", + "answer": "Superstructure: The lattice constant of an ordered solid solution differs from that of a disordered solid solution, resulting in additional diffraction lines on the X-ray diffraction pattern, known as superstructure lines. Therefore, an ordered solid solution is also referred to as a superstructure or superlattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"Superstructure\"这一基本概念的定义和术语的记忆和理解，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Superstructure\"的基本概念和术语，正确选项提供了明确的定义和相关的X射线衍射现象描述。虽然涉及一些专业术语（如\"lattice constant\"、\"ordered solid solution\"等），但整体上是对单一概念的阐述，不需要进行复杂的概念体系分析或比较。在选择题型内，这属于中等难度，比简单定义记忆（等级1）要求更高，但比需要处理多个相互关联概念的题目（等级3）要简单。" + }, + { + "idx": 3125, + "question": "Explain the basic concept and terminology: uphill diffusion", + "answer": "Uphill diffusion: The diffusion of atoms from a region of low concentration to a region of high concentration is called uphill diffusion, and the driving force for uphill diffusion is the chemical potential gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即uphill diffusion的定义和驱动力的记忆性知识。 | 难度: 在选择题型中，该题目要求考生理解并解释\"uphill diffusion\"这一概念，包括其定义和驱动力的基本原理。虽然不涉及多个概念的比较分析，但需要考生对化学势梯度等基础概念有一定理解，属于概念解释和描述层次的难度。" + }, + { + "idx": 3126, + "question": "What is the shape memory mechanism of shape memory alloys?", + "answer": "After heating and quenching, shape memory alloy materials obtain thermoelastic martensite. The interface between this martensite and the parent phase has good coherency, so the martensite phase continuously shrinks and grows during heating and cooling. When the temperature exceeds the As point, the martensite undergoes plastic transformation into the parent phase. If pressure is applied in the martensitic state, the martensite lattice orientation changes, resulting in deformation. This deformed martensite undergoes reversible phase transformation upon heating, reverting to the parent phase state, causing the entire lattice to restore its original form, thereby eliminating the deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释形状记忆合金的形状记忆机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释形状记忆合金的形状记忆机制，涉及热弹性马氏体、相变过程、晶格取向变化等多个复杂概念的综合运用和机理解释，需要深入理解和分析相变过程中的物理机制及其与材料性能的关系。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解形状记忆合金的复杂机理，包括热弹性马氏体的形成、相变过程、晶格取向变化以及可逆相变等多个复杂概念的综合运用。解题步骤涉及多个层次的推理分析，需要对材料科学中的相变机理有深刻的理解和掌握。此外，题目还要求将理论知识与实际现象（如加热、冷却、压力应用等）相结合，进行全面的分析。因此，在选择题型内，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 3127, + "question": "Explain the basic concept and terminology: symmetric tilt boundary", + "answer": "Symmetric tilt boundary: Formed by a series of edge dislocations with parallel Burgers vectors and the same sign arranged vertically. The two sides of the boundary are symmetric, and the misorientation between the two grains is very small. It is the simplest type of low-angle grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释对称倾斜晶界的基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对称倾斜晶界的基本概念和术语的定义，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生解释对称倾斜晶界的基本概念和术语，包括其形成机制、结构特征和分类。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或比较。题目要求对定义和基本原理进行描述，属于概念解释和描述层次，因此难度等级为2。" + }, + { + "idx": 3128, + "question": "What is the shape memory mechanism of shape memory polymers?", + "answer": "The shape memory mechanism of polymers is the radiation crosslinking reaction that occurs when polymers are exposed to high-energy radiation. When the temperature exceeds the melting point and enters the high elastic state region, the crystals melt, allowing the polymer's shape to be arbitrarily altered by applying external force. If the temperature is then cooled below the crystalline melting point, the polymer chains become 'frozen' due to recrystallization, fixing the shape. Once the temperature rises above the melting point again (or above the glass transition temperature for polymers like polyvinyl chloride), the polymer returns to its original shape, demonstrating the shape memory effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释形状记忆聚合物的形状记忆机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释形状记忆聚合物的形状记忆机制，涉及辐射交联反应、高弹态区域、结晶熔点和玻璃化转变温度等多个概念的综合运用和机理解释，需要深入理解和分析这些概念之间的关联和作用机制。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解形状记忆聚合物的复杂机理，包括辐射交联反应、高弹态转变、结晶熔融和再结晶过程等多个关键步骤。正确选项不仅需要掌握高分子物理的多个核心概念（如熔点、玻璃化转变温度、结晶行为），还需要将这些概念串联起来解释动态形状记忆效应。这种综合运用知识解释复杂现象的能力，远超选择题型中常见的简单概念识别或单一知识点考察，属于需要全面分析能力的最高难度题目类型。" + }, + { + "idx": 3129, + "question": "Explain the basic concept and terminology: dendritic segregation", + "answer": "Dendritic segregation: During non-equilibrium solidification, the initially solidified solid solution contains more high-melting-point components, while the later solidified solid solution contains more low-melting-point components. This results in non-uniform chemical composition within the grain, known as intracrystalline segregation. Since solid solutions often grow in a dendritic manner, it is also called dendritic segregation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即dendritic segregation的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求考生解释并描述\"dendritic segregation\"的基本概念和术语，涉及非平衡凝固过程中的成分不均匀现象。虽然需要理解多个相关概念（如非平衡凝固、固溶体、高/低熔点组分等），但主要考察的是对单一概念的定义和基本描述，不需要进行复杂的比较分析或推导。因此属于选择题型中的中等难度（等级2）。" + }, + { + "idx": 3130, + "question": "Explain the basic concept and terminology: Twinning", + "answer": "Twinning: One of the important forms of cold plastic deformation, occurring as a uniform shear within the crystal, always along certain crystallographic planes and directions. After deformation, the deformed part and the undeformed part exhibit a mirror-symmetric orientation relationship, hence this type of plastic deformation is called twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即孪生的定义、发生机制和特征，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求解释\"Twinning\"这一概念，但正确选项已经提供了明确的定义、发生机制和特征描述，不需要考生进行复杂的分析或比较多个概念。考生只需理解并记忆这些基本概念即可正确回答，因此属于中等难度。" + }, + { + "idx": 3131, + "question": "Explain the basic concept and terminology: Modification treatment", + "answer": "Modification treatment: Before casting metal or alloy, adding certain solid-phase substances that can promote heterogeneous nucleation or hinder the growth of crystal nuclei into the molten metal to refine the grains of the casting is called modification treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，要求解释\"Modification treatment\"的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Modification treatment\"的基本概念和术语，正确选项提供了明确的定义和基本原理，但不需要进行复杂的概念体系阐述或多概念比较分析。该题目主要考察对单一概念的记忆和理解，符合选择题型中中等难度的要求。" + }, + { + "idx": 3132, + "question": "Explain the basic concept and terminology: superplasticity", + "answer": "Superplasticity: Under specific conditions, metallic materials can achieve exceptionally large elongation rates when stretched, sometimes even reaching 1000%. This property is called superplasticity. During superplastic deformation, the strain rate sensitivity index m is very high, with m≈0.5, whereas for ordinary metallic materials it is only 0.01~0.04.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释超塑性的基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对超塑性这一基本概念的定义和特性的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释超塑性的基本概念和术语，但正确选项已经提供了较为详细的定义和关键参数（如应变速率敏感性指数m的数值范围）。考生需要理解并记忆这些关键点，但不需要进行复杂的分析或比较。因此，该题目在选择题型内属于等级2，即概念解释和描述的难度水平。" + }, + { + "idx": 3133, + "question": "Explain the basic concept and terminology: Dynamic recovery", + "answer": "Dynamic recovery: During hot deformation of high stacking fault energy metallic materials, due to the narrow width of extended dislocations, they are prone to constriction and cross-slip. Therefore, high-temperature recovery occurs simultaneously during hot deformation, hence it is called dynamic recovery. It is the primary or sole softening mechanism for high stacking fault energy metallic materials during hot deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释动态回复的基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查动态恢复的基本概念和术语的定义，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生不仅记忆动态恢复的基本定义，还需要理解其发生条件和作用机制。虽然不涉及复杂的概念体系阐述，但需要考生对相关术语和原理有一定的掌握和解释能力，属于概念解释和描述的难度层次。" + }, + { + "idx": 3135, + "question": "Compare the roles of twinning and slip in the plastic deformation process", + "answer": "The direct contribution of twinning to plastic deformation is not as significant as that of slip. However, since twinning alters the crystal orientation, it can enable slip systems originally in hard orientations to rotate into soft orientations and participate in slip. This is particularly important for hexagonal close-packed metals with fewer slip systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较孪生和滑移在塑性变形过程中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较孪生和滑移在塑性变形过程中的作用，不仅需要理解两者的基本概念，还需要分析它们之间的相互作用和影响，特别是孪生如何通过改变晶体取向来促进滑移。这涉及到对晶体塑性变形机制的深入理解和综合分析，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3136, + "question": "What is secondary recrystallization (abnormal growth)?", + "answer": "After recrystallization is completed, continued heating or holding may lead to discontinuous grain growth, where the growth of most grains is inhibited, while a few grains grow rapidly, which is called abnormal growth, also known as secondary recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary recrystallization (abnormal growth)\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶（异常生长）这一基本概念的定义和解释，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对二次再结晶（异常生长）的定义和过程有一定的理解和描述能力，而不仅仅是简单的定义记忆。题目要求考生能够理解并解释这一现象，属于概念解释和描述的层次。" + }, + { + "idx": 3137, + "question": "Briefly explain the differences between twinning and slip in the plastic deformation process", + "answer": "Twinning causes a uniform shear in a portion of the crystal, while slip is concentrated on the slip plane; twinning changes the orientation of a portion of the crystal, whereas slip does not alter the crystal orientation; the twinning elements are usually different from the slip systems; the critical shear stress for twinning is much higher than that for slip, the stress-strain curve for twinning is serrated, while that for slip is smooth; the deformation rate of twinning is far higher than that of slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释孪生和滑移在塑性变形过程中的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释孪生和滑移在塑性变形过程中的差异，涉及多个方面的比较（如剪切分布、晶体取向变化、临界剪切应力等），需要综合理解和分析不同变形机制的异同点，属于中等应用层次的知识。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅理解\"twinning\"和\"slip\"这两个塑性变形过程的基本概念，还需要从多个角度（包括变形机制、晶体取向变化、临界剪切应力、应力-应变曲线特征以及变形速率）进行对比分析。正确选项包含了5个不同的比较维度，每个维度都需要准确的概念理解和应用能力。这种多角度分析的要求超出了简单记忆或单一概念理解的层次，需要考生能够综合运用所学知识进行系统比较，因此在选择题型内属于等级4的难度。" + }, + { + "idx": 3138, + "question": "Determine whether the dislocation reaction $\\frac{1}{2}[111]\\rightarrow\\frac{1}{8}[110]+\\frac{1}{4}[112]+\\frac{1}{8}[110]=0.$ 110] can proceed, and why?", + "answer": "$$ \\Sigma b_{\\mathbb{H}}=\\Sigma b_{\\mathbb{E}}=\\frac{1}{2}[111]$$Thus, this dislocation reaction satisfies the geometric condition$$ x\\Sigma b_{j j}^{2}=\\frac{3}{4}>\\Sigma b_{j j}^{2}=\\frac{1+1}{64}+\\frac{1+1+4}{16}+\\frac{1+1}{64}=\\frac{7}{16} $$Therefore, it also satisfies the energy condition, so this dislocation reaction can proceed spontaneously.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算验证位错反应的能量条件是否满足，答案中包含了具体的矢量计算和能量比较，属于需要数值计算和公式应用的类型。 | 知识层次: 题目需要进行多步计算（矢量分解、能量条件验证），并需要理解位错反应的能量条件和几何条件之间的关系。虽然不涉及复杂的机理分析或创新应用，但需要综合运用位错理论和能量守恒原理进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解位错反应的基本概念，进行矢量运算验证几何条件，并通过能量计算判断反应可行性。题目涉及多步骤计算和综合分析，但选项提供了关键计算步骤，降低了部分难度。" + }, + { + "idx": 3139, + "question": "It is known that the stacking fault energy of a certain stainless steel is very low, γ=0.013 J/m². It is cold-pressed with a reduction of 8%, followed by recrystallization annealing. Briefly describe its recrystallization nucleation mechanism.", + "answer": "At a reduction of 8%, the nucleation mechanism is the bow-out nucleation mechanism. Due to the small deformation amount and non-uniform deformation, the dislocation density between adjacent grains varies significantly. A small segment of the remaining original grain boundary will suddenly bow out towards the side with higher dislocation density. The swept small region releases all stored energy, and this area can become the recrystallization nucleus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述再结晶成核机制，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释特定条件下（低层错能不锈钢经8%冷压后）的再结晶成核机制，涉及变形量、位错密度分布、晶界弓出等复杂概念的综合分析和机理解释，需要深入理解材料变形与再结晶的相互作用机制。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握材料科学中的基本概念（如堆垛层错能、冷压变形、再结晶退火等），还需要深入理解变形量与再结晶形核机制之间的复杂关系。正确选项涉及对非均匀变形条件下位错密度差异的机理分析，以及晶界弓出形核机制的具体描述。这需要考生具备将理论知识综合运用于具体情境的能力，并能进行机理层面的深度解释，符合选择题型中对复杂现象全面分析的最高要求。" + }, + { + "idx": 3140, + "question": "What are the conditions for the occurrence of secondary recrystallization (abnormal growth)?", + "answer": "The conditions for its occurrence are the presence of recrystallization texture, second-phase particles, or surface thermal grooves.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述二次再结晶（异常生长）发生的条件，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目考查对二次再结晶（异常生长）发生条件的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生掌握\"二次再结晶\"发生的三个具体条件（再结晶织构、第二相颗粒、表面热沟槽），属于对多个相关要素的联合记忆。相比单纯记忆定义（等级1），该题要求对概念条件进行完整描述；但尚未达到需要阐述复杂机理或比较分析的等级3水平。在选择题型中，这类题目需要考生对知识点有较全面的记忆而非简单识别。" + }, + { + "idx": 3142, + "question": "γ-Fe has a lattice constant α=0.3633nm slightly above 910 ℃, find the atomic radius of γ-Fe", + "answer": "The atomic radius of γ-Fe r=√2/4×a=√2/4×0.3633=0.1284nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用晶格常数计算原子半径）来得出具体数值结果，答案是一个具体的计算结果（0.1284nm），符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要套用已知的公式（r=√2/4×a）和给定的数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（r=√2/4×a）进行计算，无需额外的公式组合或复杂推导。题目要求的知识点掌握深度较浅，解题步骤简单直接，属于最基础的难度等级。" + }, + { + "idx": 3143, + "question": "For α-Fe slightly below 910°C, the lattice constant α=0.2892nm, find the atomic radius of α-Fe", + "answer": "The atomic radius of α-Fe r=√3/4×a=√3/4×0.2892=0.1252nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（√3/4×a）来求解α-Fe的原子半径，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要套用已知的公式（原子半径与晶格常数的关系）进行一步计算即可得出结果，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（原子半径与晶格常数的关系公式）进行简单计算，无需额外的概念理解或复杂的解题步骤。属于最基础的难度等级。" + }, + { + "idx": 3144, + "question": "It is known that the stacking fault energy of a certain stainless steel is very low, γ=0.013 J/m². After cold pressing deformation with reductions of 8% and 60%, recrystallization annealing is performed. Explain the difference in grain size after recrystallization annealing between the two cases. Why?", + "answer": "After recrystallization annealing, with a reduction of 8%, the deformation is near the critical deformation level. The small deformation amount results in low stored energy and a small driving force for recrystallization. Although recrystallization can occur, the nucleation rate is low, leading to very coarse grains. With a reduction of 60%, the stored energy is high, the driving force for recrystallization is large, and the nucleation rate is high, resulting in fine grains after recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种情况下再结晶退火后晶粒尺寸的差异及其原因，答案通过文字论述进行详细解释，没有涉及计算、选择或判断对错。 | 知识层次: 题目需要综合运用材料科学中的变形、储存能、再结晶驱动力和晶粒尺寸控制等知识，进行机理分析和推理。不仅要求理解低堆垛层错能不锈钢的特性，还需要分析不同变形量对储存能和再结晶行为的影响，进而解释晶粒尺寸差异的原因。这涉及多个概念的关联和深层次的机理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解堆垛层错能、冷压变形和再结晶退火等基础概念，还需要综合运用这些知识进行复杂现象的分析和机理解释。具体来说，考生需要：" + }, + { + "idx": 3145, + "question": "The volume change rate during the γ-Fe→α-Fe transformation (given the lattice constant of γ-Fe α=0.3633nm, and the lattice constant of α-Fe α=0.2892nm)", + "answer": "The volume change rate ΔV=(Vα-Vγ)/Vγ=(0.2892³×1/2-0.3633³×1/4)/(0.3633³×1/4)≈0.886", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶格常数计算γ-Fe→α-Fe相变过程中的体积变化率，涉及数值计算和公式应用，答案以数值结果呈现。 | 知识层次: 题目涉及多步计算和概念关联，需要理解晶体结构、相变过程中的体积变化计算，并正确应用公式进行数值计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解γ-Fe和α-Fe的晶体结构差异（面心立方和体心立方），掌握晶格常数与体积的关系，并能正确应用体积计算公式。题目涉及多步计算（包括立方运算和分数运算）和概念关联（晶体结构转变与体积变化），但计算过程相对明确，不需要处理复杂变量或高级数学工具。" + }, + { + "idx": 3146, + "question": "In has a tetragonal structure with lattice constants a=0.3252 nm, c=0.4946 nm, atomic radius r=0.1625 nm, and number of atoms per unit cell n=2. Calculate the packing density.", + "answer": "The packing density K=(n×v)/V=(2×(4/3)π(0.1625)³)/(0.3252²×0.4946)≈0.687.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出一个数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的晶格常数和原子半径计算堆积密度，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目直接给出了所有必要的参数（晶格常数、原子半径、单位晶胞原子数），并明确要求计算堆积密度。解题步骤仅需套用单一公式（堆积密度公式），进行简单的数值代入和计算，无需多个公式组合或复杂推导。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3148, + "question": "The lattice constant of a copper crystal is $a=0.362\\mathrm{nm},$ the density is $\\rho=8.98~\\mathrm{g/cm}^{3},$ and the relative atomic mass is 63.55. Determine the crystal structure of copper.", + "answer": "From the physical meaning of density $\\rho=\\frac{6.023\\times10^{23}}{(0.362\\times10^{-7})^{3}}=8.98(g/\\mathrm{cm}^{3})$ n. Solving gives $n=3.997{\\approx}4.$ A cubic unit cell with 4 atoms corresponds to a face-centered cubic structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定铜的晶体结构，答案中给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，通过已知的晶格常数、密度和相对原子质量，直接套用密度公式进行计算，得出晶胞中的原子数，从而判断晶体结构。整个过程不需要多步计算或综合分析，属于直接应用基本知识的范畴。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解密度的物理意义并进行简单的代数运算，但整体步骤较为直接，仅涉及单一公式的套用和简单计算。与选择题型内其他更复杂的题目相比，该题的解题步骤和知识点掌握深度要求较低，因此属于等级2难度。" + }, + { + "idx": 3149, + "question": "Given the density of amorphous polyethylene ρa=0.854 g/cm³, and the density of typical commercial low-density polyethylene ρ=0.920 g/cm³, calculate the volume fraction of the crystalline region φc", + "answer": "The volume fraction of the crystalline region φc = (ρ - ρa) / (ρc - ρa) = (0.92 - 0.854) / (1.01 - 0.854) ≈ 42.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的密度数据和公式进行数值计算，最终得出结晶区域的体积分数，属于典型的计算题。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及密度和体积分数的直接套用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了所有必要的参数（ρa, ρ, ρc），并直接要求套用给定的公式进行计算。学生只需要正确代入数值并执行简单的算术运算即可得出答案，无需额外的分析或推导步骤。因此，在选择题型内，该题目属于最低难度等级。" + }, + { + "idx": 3150, + "question": "Using analytical geometry to determine the angle between two crystal planes $h_{1}k_{1}l_{1}$ and $h_{2}k_{2}l_{2}$ in a cubic crystal", + "answer": "Let the two crystal planes in the cubic system be $h_{1}k_{1}l_{1}$ and $h_{2}k_{2}l_{2}$, and the angle between them be $\\phi$, then $$ \\cos\\phi={\\frac{h_{1}h_{2}+k_{1}k_{2}+l_{1}l_{2}}{\\sqrt{h_{1}^{2}+k_{1}^{2}+l_{1}^{2}}\\cdot\\sqrt{h_{2}^{2}+k_{2}^{2}+l_{2}^{2}}}} $$ Therefore, $$ \\phi=\\operatorname{arccos}(\\cos\\phi) $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用解析几何方法计算两个晶面之间的夹角，答案中给出了具体的计算公式和步骤，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的公式计算两个晶面之间的夹角。虽然需要理解立方晶体中晶面的表示方法，但整体上属于直接套用公式的简单应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及解析几何和晶体学的基本概念，但解题过程仅需直接套用给定的公式进行计算，无需复杂的推导或多步骤分析。因此，在选择题型内属于中等偏下的难度等级。" + }, + { + "idx": 3151, + "question": "In has a tetragonal structure, with a relative atomic mass Ar=114.82, lattice constants a=0.3252 nm, c=0.4946 nm, atomic radius r=0.1625 nm, density ρ=7.286 g/cm³. Determine the number of atoms per unit cell of In.", + "answer": "From the density expression ρ=(n×114.82)/((0.3252×10⁻⁷)²×0.4946×10⁻⁷×6.023×10²³)≈7.286, the number of atoms per unit cell is obtained as n≈1.999, n=2, which should be a body-centered tetragonal structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定每个晶胞中的原子数，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换和数值计算，同时需要理解晶体结构的基本概念和关联密度与晶胞参数的关系。虽然不涉及复杂的推理分析，但需要综合运用多个知识点进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算和单位晶胞原子数的关系，并进行多步计算和综合分析。虽然题目提供了所有必要的数据，但解题过程涉及单位换算、公式应用和逻辑推理，需要较强的应用能力和计算技巧。" + }, + { + "idx": 3152, + "question": "Using analytical geometry to determine the angle between two crystallographic directions [$u_{1}v_{1}w_{1}$] and [$u_{2}v_{2}w_{2}$] in a cubic crystal", + "answer": "Let the two crystallographic directions in the cubic system be [$u_{1}v_{1}w_{1}$] and [$u_{2}v_{2}w_{2}$], and the angle between them be θ, then $$ \\\\cos\\\\theta={\\\\frac{\\\\left[u_{1}v_{1}w_{1}\\\\right]\\\\cdot\\\\left[u_{2}v_{2}w_{2}\\\\right]}{|\\\\left[u_{1}v_{1}w_{1}\\\\right]|\\\\cdot|\\\\left[u_{2}v_{2}w_{2}\\\\right]|}}={\\\\frac{u_{1}u_{2}+v_{1}v_{2}+w_{1}w_{2}}{{\\\\sqrt{u_{1}^{2}+v_{1}^{2}+w_{1}^{2}}}\\\\cdot{\\\\sqrt{u_{2}^{2}+v_{2}^{2}+w_{2}^{2}}}}} $$ Therefore $$ \\\\theta=\\\\operatorname{arccos}(\\\\cos\\\\theta) $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶体中两个晶向之间的夹角，答案涉及具体的数学公式和计算步骤，属于典型的计算题。 | 知识层次: 题目主要涉及立方晶体中两个晶向之间夹角的计算，需要应用基本的向量点积公式和几何知识。虽然需要一定的计算步骤，但整体上属于直接套用公式的简单应用，不涉及复杂的综合分析或深度理解。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及解析几何和晶体学方向的概念，但解题过程仅需直接套用给定的向量点积公式计算夹角，无需多个公式组合或复杂推导。学生只需正确识别并应用立方晶系中的方向夹角公式即可完成计算，因此属于等级2难度。" + }, + { + "idx": 3153, + "question": "In stable ZrO2 material, cations form an fcc structure, and anions occupy tetrahedral interstitial sites. If 20 mol% CaO is added, calculate how many anions are needed for 100 cations?", + "answer": "Since the amount of CaO added to ZrO2 is 20 mol%, the total charge number for 100 cations is 20×2 + 80×4 = 360. To maintain electrical neutrality, the required number of O2− anions is 360 ÷ 2 = 180.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算需要的阴离子数量），并应用了电荷平衡的公式来解决问题。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及电荷平衡的概念应用和综合分析。虽然计算本身不复杂，但需要理解掺杂对晶体结构的影响以及电荷平衡的原理，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解电荷平衡的概念，进行多步计算（包括摩尔百分比换算、电荷数求和、电荷平衡计算），并综合应用材料化学和晶体结构知识。虽然题目提供了明确的解题路径，但涉及的步骤和概念关联使其高于基础选择题的难度水平。" + }, + { + "idx": 3154, + "question": "In stable ZrO2 material, cations form an fcc structure, and anions occupy tetrahedral interstitial sites. If 20 mol% CaO is added, calculate the percentage of occupied tetrahedral interstitial sites.", + "answer": "Zr4+ and Ca2+ cations occupy the face-centered cubic lattice sites. 100 cations can form 25 unit cells, with a total of 25×8=200 tetrahedral interstitial sites. Therefore, the percentage of occupied tetrahedral interstitial sites is 180÷200=90%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算占据的四面体间隙位置的百分比），并且答案给出了具体的计算步骤和结果。这符合计算题的特征，即需要应用公式和进行数值推导。 | 知识层次: 题目需要进行多步计算（包括单位晶胞的计算、间隙位置的计算和百分比计算），并需要理解阳离子和阴离子在ZrO2结构中的位置关系以及掺杂CaO对间隙位置的影响。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算。题目涉及晶体结构、间隙位置占据率的计算，以及掺杂对结构的影响。虽然正确选项提供了计算步骤，但需要考生具备扎实的晶体学基础和计算能力，能够正确理解并应用给定的信息。" + }, + { + "idx": 3155, + "question": "Determine the crystallographic direction in the diamond structure defined by the points (0,0,0) and $(\\\\frac{3}{4},\\\\frac{3}{4},\\\\frac{1}{4})$, and find the crystallographic plane perpendicular to this direction.", + "answer": "Subtract the coordinates of the two points, then reduce them to a set of coprime integers. The direction indices are [331]. Since it is a cubic system, the crystallographic plane with the same indices is perpendicular to the direction, i.e., (331) is perpendicular to [331].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定晶体学方向和垂直的晶面，解答过程涉及坐标计算和指数简化，需要详细的步骤说明而非简单的选择或判断。 | 知识层次: 题目需要多步计算（坐标相减、约简为互质整数）和概念关联（立方晶系中方向与垂直晶面的关系），属于中等应用层次。虽然不涉及复杂的综合分析或创新设计，但比简单应用要求更高。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求确定金刚石结构中的晶向，并找到与之垂直的晶面。解题步骤包括坐标减法、约简到互质整数，以及利用立方晶系的性质确定垂直晶面。虽然步骤较多，但在选择题型中，正确选项提供了明确的解题思路和答案，降低了部分难度。" + }, + { + "idx": 3156, + "question": "It is known that polyethylene belongs to the body-centered orthorhombic structure, with lattice constants a=0.740nm, b=0.493nm, c=0.253nm, and two molecular chains passing through a unit cell. Calculate the density ρc of fully crystalline polyethylene.", + "answer": "Polyethylene (C2H4) is produced through addition polymerization, with its repeating unit being CH2-CH2. Considering one repeating unit as a lattice point, it can be determined that each unit cell contains two repeating units. Therefore, the density ρc of fully crystalline polyethylene can be calculated as ρc = 2(12×2 + 1×4) / (6.023×10^23) / (0.740×0.493×0.253)×10^-21 ≈ 1.01 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚乙烯的密度，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括分子量的计算、单位晶胞体积的计算以及密度的计算，同时需要理解晶格常数和单位晶胞的概念，并能够将这些概念和公式结合起来进行综合分析。虽然不涉及复杂的推理分析或创新应用，但已经超出了简单应用的范围。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算、化学式推导等多个概念，并进行多步骤的综合计算。虽然题目提供了部分参数，但需要考生自行推导化学式、计算分子量、理解单位晶胞概念，并正确应用密度公式进行计算。这些步骤在选择题型中属于较为复杂的综合分析过程。" + }, + { + "idx": 3157, + "question": "The density of $\\\\mathrm{CaF}_{2}$ is $\\\\rho=3.18~\\\\mathrm{g/cm}^{3}$, the relative atomic mass of $\\\\mathrm{Ca}$ is $A_{\\\\mathrm{r}}=40.08$, and the relative atomic mass of $\\\\mathrm{F}$ is $A_{\\\\mathrm{r}}=19.00$. Find the lattice constant $a$.", + "answer": "From the structure of $\\\\mathrm{CaF}_{2}$, it is known that the unit cell contains 4 $\\\\mathrm{Ca}^{2+}$ ions and 8 $\\\\mathrm{F^{-}}$ ions. Therefore, the relationship between its density and the lattice constant is as follows: $$ x\\\\rho=\\\\frac{4\\\\times\\\\frac{40.08+19\\\\times2}{6.023\\\\times10^{23}}}{a^{3}}\\\\approx3.18 $$ Solving the above equation gives $a=0.546(\\\\mathrm{nm})$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶格常数a，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，包括单位晶胞中离子数量的确定、相对原子质量的计算、密度与晶格常数的关系公式应用，以及最终的数值求解。这需要综合运用材料科学中的晶体结构知识和数学计算能力，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算、单位换算等多个概念，并进行多步骤的综合计算。虽然题目提供了关键参数，但解题过程涉及单位转换和代数求解，对学生的综合能力要求较高。" + }, + { + "idx": 3158, + "question": "Given the density of amorphous polyethylene ρa=0.854 g/cm³, the density of typical commercial low-density polyethylene ρ=0.920 g/cm³, and the density of fully crystalline polyethylene ρc=1.01 g/cm³, calculate the mass fraction of the crystalline region wc", + "answer": "The mass fraction of the crystalline region wc = ρc(ρ - ρa) / ρ(ρc - ρa) = 1.01×(0.92 - 0.854) / 0.92×(1.01 - 0.854) ≈ 46.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，最终得出一个具体的百分比结果。解答过程涉及使用给定的密度值和公式进行计算，符合计算题的特征。 | 知识层次: 题目需要应用密度与结晶度关系的公式进行计算，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解密度与结晶度的关系，并进行多步计算。题目涉及多个密度值的应用和公式推导，但选项提供了明确的解题路径，减少了部分思考负担。" + }, + { + "idx": 3159, + "question": "What type of alloy phase does CuZn belong to, and what are its structural characteristics?", + "answer": "CuZn is an electron compound, c13=3.12, with a body-centered cubic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释CuZn合金相的类型及其结构特征，答案提供了详细的文字描述和结构特点，符合简答题的特征。 | 知识层次: 题目考查合金相的基本分类和结构特征的记忆，属于基础概念的记忆和理解层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及合金相的类型和结构特征，但正确选项直接提供了CuZn的电子化合物类型、c13值和体心立方结构，这些信息属于基础概念记忆范畴。考生需要掌握电子化合物的定义和体心立方结构的基本特征，但不需要进行复杂的分析或推理。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 3160, + "question": "What type does the alloy phase Fe3C belong to, and what are its structural characteristics?", + "answer": "Fe3C is a complex lattice interstitial compound with an orthorhombic crystal system. Its unit cell contains 12 iron atoms and 4 carbon atoms. The iron atoms are arranged in a close-packed manner, forming octahedrons, with carbon atoms located in the octahedral interstitial sites. The corner atoms of the octahedrons are shared by two adjacent octahedrons, and there is a certain orientation between the octahedrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C合金相的类型和结构特征，答案提供了详细的文字描述和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对Fe3C合金相的类型和结构特征的基本概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题中属于较高难度，需要掌握复杂概念体系。题目要求考生不仅知道Fe3C的分类（复杂间隙化合物），还需理解其正交晶系结构特征、晶胞组成（12Fe+4C）、铁原子密排方式形成的八面体间隙，以及碳原子在其中的位置分布。这些知识点涉及晶体结构、原子排列和间隙理论等多个相互关联的概念，需要考生具备较强的空间想象能力和对金属学基础理论的深入理解。" + }, + { + "idx": 3161, + "question": "What type of alloy phase is VC, and what are its structural characteristics?", + "answer": "VC is an interstitial phase, where V occupies the lattice points of a face-centered cubic lattice, and C occupies all the octahedral interstitial sites. It belongs to the face-centered cubic lattice and has a NaCl-type structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释VC合金相的类型和结构特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对合金相类型和结构特征的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（合金相类型和结构特征），但需要考生准确记忆并描述VC的具体结构特征（间隙相、面心立方晶格、NaCl型结构）。这比单纯识别合金相类型（等级1）要求更高的概念解释和描述能力，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 3162, + "question": "What type of alloy phase is ZrFe2, and what are its structural characteristics?", + "answer": "ZrFe2 is a Laves phase among the topologically close-packed phases, with a complex cubic structure. The smaller iron atoms form small tetrahedrons, and the vertices of these tetrahedrons are interconnected to form a network. The larger Zr atoms are located in the gaps between the small tetrahedrons formed by Fe atoms and themselves form a diamond structure. This structure only contains tetrahedral gaps, so its packing density is higher than that of the face-centered cubic structure formed by equal-sized steel balls.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对ZrFe2合金相的类型和结构特征进行详细的文字解释和论述，而不是从选项中选择、判断对错或进行数值计算。答案也提供了详细的描述性回答，符合简答题的特点。 | 知识层次: 题目不仅要求识别ZrFe2的合金相类型（Laves相），还需要描述其结构特征和原子排列方式，涉及多个概念的关联和综合分析。虽然不涉及复杂计算或深度推理，但需要理解并整合多个知识点来回答问题。 | 难度: 在选择题中属于较高难度，题目要求考生不仅识别ZrFe2的合金相类型（Laves相），还需要理解其结构特征（复杂立方结构、铁原子形成小四面体、锆原子位置及形成的金刚石结构）以及其与面心立方结构的比较。这需要考生具备较深的知识掌握和多角度分析能力，能够将多个概念关联起来进行综合分析。" + }, + { + "idx": 3163, + "question": "Calculate the number of atoms N in 1 cm³ of copper, given that the density of copper is 8.9 g/cm³, the relative atomic mass is 63.5, and Avogadro's number is 6.02×10²³.", + "answer": "N = (6.02×10²³ × 8.9) / 63.5 ≈ 0.84×10²³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及密度、相对原子质量和阿伏伽德罗常数的计算，最终得出具体的数值结果。 | 知识层次: 题目需要应用基本的公式（密度、摩尔质量、阿伏伽德罗常数）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（N = (Avogadro's number × density) / relative atomic mass）并进行简单计算，无需组合多个公式或进行复杂分析。题目提供的所有必要参数明确，计算步骤直接，属于最基础的单一公式应用层级。" + }, + { + "idx": 3164, + "question": "Calculate the number of vacancies n in 1 cm³ of copper at 1000°C, given the average vacancy concentration C≈6.27×10⁻⁵ and the number of atoms N≈0.84×10²³.", + "answer": "n = N × C = 0.84×10²³ × 6.27×10⁻⁵ ≈ 5.27×10¹⁸", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铜中空位数量），并给出了具体的公式和数值代入过程。答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析 | 难度: 在选择题型中，该题目仅需要直接套用单一公式n = N × C进行计算，无需理解多个概念或进行复杂分析。解题步骤简单直接，属于最基础的难度等级。" + }, + { + "idx": 3165, + "question": "The vacancy formation energy of copper is 1.7×10⁻¹⁹ J. Calculate the average vacancy concentration C at 1000°C, given the Boltzmann constant K=1.38×10⁻²³ J/K.", + "answer": "The average vacancy concentration C = e^(-Ev/KT) = exp{- (1.7×10⁻¹⁹) / (1.38×10⁻²³ × 1273)} ≈ 6.27×10⁻⁵", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用Boltzmann公式计算空位浓度，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解并应用Boltzmann公式计算空位浓度，但题目已经提供了所有必要的参数和公式，解题步骤相对直接，仅需代入数值并进行简单计算即可得出结果。相较于需要多个公式组合或复杂分析的题目，此题的难度较低。" + }, + { + "idx": 3166, + "question": "To dissolve MgF2 into LiF, what type of vacancies should be introduced into LiF?", + "answer": "Dissolving MgF2 into LiF, i.e., replacing Li+ with Mg2+, generates cation vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释和论述溶解MgF2到LiF中时应该引入的空位类型，答案以文字解释的形式给出，没有选项或计算要求。 | 知识层次: 题目需要理解溶解过程中离子替换的机制，并关联到空位的产生，涉及多步推理和概念关联，但不需要复杂的综合分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解离子替换的概念以及由此产生的空位类型。虽然题目涉及多个概念（离子替换、空位形成），但在选择题型中，正确选项直接给出了结论，减少了分析步骤的复杂性。考生需要具备将Mg2+替换Li+与阳离子空位形成关联起来的能力，这属于中等应用层次的知识要求。" + }, + { + "idx": 3168, + "question": "Given that Cr has a body-centered cubic structure, with a lattice constant a=0.2885 nm, density ρ=7.10 g/cm³, and relative atomic mass A=51.996, calculate the number of vacancies in Cr per 10⁶ lattice points.", + "answer": "The fraction of vacancies is x. From the definition of density, xρ=(2×(51.996)/(6.023×10²³)×(1−x))/(2.885³×10⁻²⁴)=7.10. Solving gives x=1−(2.885³×10⁻²⁴×7.10×6.023×10²³)/(2×51.996)≈0.0126. Therefore, the number of vacancies per 10⁶ lattice points is 10⁶×0.0126=12,600 (vacancies).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Cr中每10⁶个晶格点的空位数，答案涉及具体的计算过程和数值结果。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换、以及解方程求解空缺浓度，涉及多个概念的综合运用和关联分析。虽然不涉及复杂的机理或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，包括密度定义、晶格常数、相对原子质量等知识点的综合应用。虽然题目提供了正确选项，但解题过程需要较高的综合分析能力，属于综合性计算问题。" + }, + { + "idx": 3169, + "question": "The temperature increases from $T_{1}$ to $T_{2}$. The relative change in lattice parameter measured by X-ray diffraction method is $\\frac{\\Delta a}{a}=($4\\times10^{6}$）%. For a cube with side length L, the measured value is =0.004%. Find the vacancy concentration at temperature T2.", + "answer": "$$ xC_{v}=\\frac{\\Delta N}{N}=3\\Bigl[\\frac{\\Delta L}{L}-\\frac{\\Delta a}{a}\\Bigr]=3(0.004\\%-0.0004\\%)=1.08\\times10^{-4} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空位浓度，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解相对变化的概念、应用公式计算空位浓度，并综合分析X射线衍射测量结果与宏观尺寸变化之间的关系。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及温度变化对晶格参数的影响、相对变化的计算以及空位浓度的推导。解题步骤包括理解题意、应用公式、进行多步计算，并最终得出正确选项。虽然题目提供了部分计算过程，但仍需要考生具备一定的材料科学基础和计算能力来理解和验证选项的正确性。" + }, + { + "idx": 3170, + "question": "Two edge dislocations with opposite signs on the same slip plane have Burgers vectors of b. If they approach infinitely close, what is the total energy?", + "answer": "When two edge dislocations with opposite signs approach infinitely close, they annihilate each other, and the total energy becomes zero.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是对现象的解释而非计算或选择 | 知识层次: 题目考查对位错湮灭这一基本概念的记忆和理解，不需要复杂的计算或分析，只需知道当两个符号相反的刃位错无限接近时会相互湮灭，总能量变为零。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察对位错湮灭现象的基础概念记忆，只需知道相反符号的刃位错在无限接近时会相互湮灭，总能量变为零这一基本原理即可作答，无需复杂推理或多步骤分析。" + }, + { + "idx": 3171, + "question": "Two positive edge dislocations on the same slip plane, each with a Burgers vector b, when they approach infinitely close, what is the total energy?", + "answer": "When two positive edge dislocations approach infinitely close, it is equivalent to the energy of a single large dislocation with a Burgers vector 2b, W=α⋅G(2b)²=4αGb²", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算两个正刃位错无限接近时的总能量，答案涉及数值计算和公式应用（W=α⋅G(2b)²=4αGb²），属于典型的计算题。 | 知识层次: 题目需要理解位错的基本概念（如Burgers向量和能量关系），并应用公式进行多步计算（从单个位错能量推导出两个位错接近时的总能量）。虽然涉及基础概念，但需要一定的综合分析能力来理解位错相互作用的等效性。 | 难度: 在选择题中属于中等难度，需要理解位错能量公式（W=αGb²）的概念，并能将两个相同位错的接近等效为一个双倍伯格斯矢量的位错（2b），然后进行能量计算（4αGb²）。这涉及多步概念关联和公式应用，但不需要处理复杂变量或多种条件组合。" + }, + { + "idx": 3172, + "question": "Two positive edge dislocations on the same slip plane, with Burgers vector b and separated by a distance L, when L is much larger than the magnitude of the Burgers vector, what is the total energy?", + "answer": "When the two edge dislocations are far apart, the total energy equals the sum of their individual energies, regardless of whether they are like or unlike dislocations, given by W=W1+W2=2αGb2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个刃位错在特定条件下的总能量，答案提供了理论解释和公式应用，需要文字论述而非简单选择或判断。 | 知识层次: 题目考查对位错能量基本公式的直接应用，仅需简单计算和套用公式，无需多步推理或综合分析。 | 难度: 在选择题型内，该题目属于简单应用层次，仅需直接套用基本公式进行计算。题目明确给出了两个刃位错的总能量等于各自能量之和的条件，且不需要复杂的分析或比较。因此，在选择题型中属于较低难度，符合等级2的标准。" + }, + { + "idx": 3173, + "question": "The density of $\\\\mathrm{CaF}_{2}$ is $\\\\rho=3.18~\\\\mathrm{g/cm}^{3}$, the lattice constant is $a=0.5463\\\\mathrm{nm}$, and the relative atomic masses of Ca and F are 40.08 and 19.00, respectively. Calculate the number of Schottky vacancies in the unit cell of CaF2.", + "answer": "To maintain electrical neutrality, in the $\\\\mathrm{CaF}_{2}$ ionic crystal, for every Schottky defect formed, one $\\\\mathrm{Ca}^{2+}$ and two $\\\\mathbf{F}^{-}$ must be lost simultaneously. Let the number of Schottky defects in the unit cell be $x$, then $$ x\\\\rho=\\\\frac{\\\\left(4-x\\\\right)\\\\left(40.08+19\\\\times2\\\\right)/6.023\\\\times10^{23}}{5.463^{3}\\\\times10^{-24}}\\\\approx3.18\\\\left({\\\\mathrm{g}}/{\\\\mathrm{cm}^{3}}\\\\right) $$ Therefore, $$ x=4-\\\\frac{6.023\\\\times10^{23}\\\\times3.18\\\\times5.463^{3}\\\\times10^{-24}}{40.08+19.00\\\\times2}\\\\approx6.10\\\\times10^{-4}\\\\uparrow $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了密度、晶格常数、相对原子质量等数据的计算，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括密度、晶格常数和相对原子质量的综合应用，同时需要理解肖特基缺陷的形成机制和电中性条件。虽然不涉及复杂的推理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和概念关联。需要理解Schottky缺陷的概念，掌握密度和晶格常数的关系，进行单位换算和代数运算，并综合分析多个变量。解题步骤复杂，对知识点的掌握深度要求较高。" + }, + { + "idx": 3174, + "question": "Given that the dislocation line Φt of a newly formed Frank partial dislocation lies on the (111) plane, with b = a/3 [111] perpendicular to the (111) plane, explain why this dislocation is a sessile dislocation.", + "answer": "The plane determined by b and t is certainly not the close-packed plane of the face-centered cubic structure, hence this dislocation cannot glide and is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来说明为什么给定的Frank partial dislocation是一个sessile dislocation，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目要求解释为什么Frank部分位错是固定位错，需要理解位错的性质、滑移面与柏氏矢量的关系，以及面心立方结构中的密排面特性。这涉及多个概念的关联和综合分析，需要推理和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3175, + "question": "Estimate the strain energy of a 1cm long edge dislocation (r0=1nm, R=1cm, μ=5×10^10Pa, b=0.25nm, ν=1/3)", + "answer": "The strain energy per unit length of an edge dislocation is WE=(W/L)E=μb^2/[4π(1−ν)]ln(R/r0). The strain energy of a 1cm edge dislocation is WI={[5×10^10×(0.25×10^-9)^2]/[4×3.14×(1−1/3)]}×10^-2×ln[(1×10^-2)/(1×10^-9)]=6×10^-11J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解应变能，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式应用、单位转换和对数运算，同时需要理解应变能的概念和位错的基本性质。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解应变能公式并正确代入多个变量进行计算，包括对数运算和单位转换。虽然题目提供了公式，但涉及多个步骤的综合计算和对数函数的应用，对考生的计算能力和概念理解有一定要求。" + }, + { + "idx": 3176, + "question": "Indicate the radius of the region that accounts for half of the energy (r0=1nm, R=1cm)", + "answer": "Let the radius of the region accounting for half of the dislocation energy be r, Wr/W1=ln(r/r0)/ln[(1×10^-2)/r0]=ln[r/(1×10^-9)]/ln[(1×10^-2)/(1×10^-9)]=1/2. Solving gives r=10^-5.5=10^-6×10^0.5=3.16×10^-6m=3.16μm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定半径的值，答案展示了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解位错能量的分布概念并进行对数运算求解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解位错能量分布的概念，掌握对数运算和单位换算，并进行多步骤的综合计算。虽然题目提供了关键公式，但解题过程涉及多个数学操作和物理概念的关联应用，对学生的综合分析能力有一定要求。" + }, + { + "idx": 3177, + "question": "The lattice constant of α-Fe is $a=0.28664\\mathrm{nm}.$ When two adjacent grains form a symmetric tilt boundary with a tilt angle of 1°, calculate the spacing $D$ of the edge dislocations.", + "answer": "The Burgers vector of the unit dislocation in a body-centered cubic structure is $b=\\frac{a}{2}\\textcircled{111},$ so $b={\\frac{\\sqrt{3}}{2}}a.$ Using the formula $$ D={\\frac{b}{\\theta}}={\\frac{\\sqrt{3}}{2}}\\times0.28664/0.0175\\approx14.183{\\mathrm{~nm}} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及使用Burgers向量和倾斜角度来计算位错间距，答案是一个具体的数值结果。 | 知识层次: 题目需要理解体心立方结构中的位错概念，应用Burgers向量的计算，并运用公式进行多步计算以求解位错间距。虽然不涉及复杂的综合分析或创新应用，但需要将多个概念和计算步骤结合起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及晶格常数、对称倾斜晶界、位错间距等多个材料科学概念，并需要进行多步计算（包括矢量计算和角度转换）。虽然题目提供了关键公式，但需要考生正确识别和应用这些概念，属于综合性计算问题。" + }, + { + "idx": 3179, + "question": "Explain the concept of critical undercooling", + "answer": "In an undercooled liquid, the degree of undercooling at which an embryo can form with a radius equal to the critical nucleus radius is called the critical undercooling (ΔT*). Clearly, when the actual undercooling ΔT<ΔT*, the largest embryo size in the undercooled liquid is still smaller than the critical nucleus radius, making nucleation difficult; only when ΔT>ΔT* can homogeneous nucleation occur. Therefore, critical undercooling is required for nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释临界过冷度的概念，答案通过文字详细论述了临界过冷度的定义及其在形核过程中的作用，符合简答题的特征。 | 知识层次: 题目考查对临界过冷度这一基本概念的定义和原理的理解，属于基础概念记忆和理解的范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅要记住\"critical undercooling\"的定义，还需要理解其物理意义和在成核过程中的作用。题目解释了临界过冷度与临界核半径的关系，以及其对均相成核的影响，这超出了简单的定义记忆，需要进行概念解释和描述。但相比需要分析复杂概念体系的题目，该题的难度仍属于中等水平。" + }, + { + "idx": 3180, + "question": "Explain the concept of dynamic undercooling", + "answer": "During crystal growth, a certain degree of undercooling in the liquid ahead of the solid/liquid interface is required to satisfy (dN/dt)F > (dN/dt)M. This undercooling is called dynamic undercooling (ΔTc = Tm − Ti), which is a necessary condition for crystal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释动态过冷的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查动态过冷的基本定义和原理，属于基础概念的记忆和理解范畴 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅要记住动态过冷的定义，还需要理解其背后的物理意义（即晶体生长过程中液体/固体界面前沿所需的过冷度条件）。这超出了简单的定义复述，属于概念解释和描述的层次。不过题目并未要求考生分析复杂概念体系或进行多步骤推导，因此难度未达到等级3。" + }, + { + "idx": 3181, + "question": "Given that the unit dislocation a/2 [101] can combine with the Shockley partial dislocation [121] to form a Frank partial dislocation, determine the Burgers vector of the newly formed Frank partial dislocation.", + "answer": "The Burgers vector of the newly formed Frank partial dislocation is b, where b = a/2 [101] + a/6 [121] = a/3 [111].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过矢量加法计算新形成的Frank位错的Burgers矢量，涉及数值计算和公式应用。答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（Burgers向量的叠加运算），并需要理解位错组合的概念和Frank部分位错的形成机制。虽然不涉及复杂的综合分析或创新应用，但需要将不同概念关联起来进行中等难度的计算。 | 难度: 在选择题中属于中等偏上难度，需要理解位错的基本概念（如单位位错、Shockley部分位错、Frank部分位错），掌握Burgers矢量的叠加原理，并进行多步矢量计算。虽然题目提供了正确选项，但解题过程涉及多个概念的关联和综合计算，对学生的知识掌握深度和计算能力有一定要求。" + }, + { + "idx": 3182, + "question": "Analyze whether a screw dislocation with Burgers vector $b=\\frac{a}{2}$ [overline{{1}}10] moving on the (111) plane in a face-centered cubic crystal can cross-slip onto one of the (111), (11overline{1}), or (overline{1}11) planes when obstructed. Why?", + "answer": "For the screw dislocation with $b=\\frac{a}{2}[\\overline{{1}}10]$, the dislocation line $t=\\left[\\overline{{1}}10\\right]$. Since [\\overline{{1}}10] $[\\overline{{1}}10]=0$, the [\\overline{{1}}10] direction lies on the (11overline{1}) plane, meaning $t$ is also on the (11overline{1}) plane. Therefore, the intersection line of (111) and (11overline{1}) planes is [\\overline{{1}}10], so the screw dislocation with $b=\\frac{a}{2}$ [\\overline{{1}}10] can cross-slip onto the (11overline{1}) plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析一个具体的材料科学现象（螺位错的交叉滑移），并解释其原因。答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析螺位错在面心立方晶体中的交滑移行为，涉及位错线方向、滑移面几何关系以及交滑移条件的综合判断。需要深入理解位错几何学、晶体学方向计算以及交滑移机制，属于需要综合运用多个概念进行推理分析的复杂问题。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用晶体学、位错理论以及几何分析等多方面知识，深入理解螺位错的滑移机制和交叉滑移条件。解题步骤复杂，需要分析Burgers向量、位错线方向与滑移面的几何关系，并进行推理判断。此外，题目涉及复杂的空间想象和数学计算，对学生的综合分析和推理能力要求极高。" + }, + { + "idx": 3183, + "question": "Explain the concept of undercooling", + "answer": "The temperature difference between the actual crystallization temperature and the theoretical crystallization temperature is called the undercooling (ΔT=Tm−Tn). It is required by the thermodynamic conditions of phase transformation. Only when ΔT>0 can the condition that the free energy of the solid phase is lower than that of the liquid phase be achieved. The free energy difference between the liquid and solid phases is the driving force for crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"undercooling\"的概念，答案提供了详细的文字解释和论述，包括定义、公式和热力学条件的说明，符合简答题的特征。 | 知识层次: 题目主要考查对undercooling这一基础概念的定义和基本原理的记忆与理解，涉及温度差和自由能差等基本概念，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释过冷的概念，并涉及基本的温度差和热力学条件，但不需要复杂的分析或比较多个概念。正确选项提供了清晰的定义和基本原理，属于中等难度的选择题。" + }, + { + "idx": 3186, + "question": "Directly observing the aluminum sample, the dislocation density within the grains is ρ=5×10^13/m^2. If the angle between subgrains is 5°, estimate the dislocation spacing at the interface (the lattice constant of aluminum a=2.8×10^-10m).", + "answer": "Using the formula D≈b/θ, where b is the magnitude of the Burgers vector of the dislocation and D is the dislocation spacing, the Burgers vector b=[101], so b_Al=a/2×√2=2.8×10^-10×√2/2≈1.98×10^-10m. θ=5/57.3=0.087, substituting into the expression for D, we obtain D=2.28×10^-9m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及使用特定的公式（D≈b/θ）和给定的参数（如Burgers vector、角度等）来估算位错间距。答案提供了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（Burgers向量计算、角度转换、间距公式应用），涉及位错理论中多个概念的关联（位错密度、亚晶界角度、位错间距），需要综合分析能力，但不需要复杂的机理解释或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解位错密度、亚晶界角度、位错间距等多个概念，并进行多步计算（包括Burgers矢量计算、角度转换和最终间距计算）。虽然题目提供了计算公式，但需要正确应用材料常数和单位转换，对概念理解和计算能力要求较高。" + }, + { + "idx": 3187, + "question": "Describe the structural conditions of crystalline phase transition", + "answer": "The structural fluctuations present in the liquid are the basis for the formation of crystal nuclei during crystallization, therefore, structural fluctuations are the necessary structural conditions for the crystallization process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体相变的结构条件，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求描述晶体相变的结构条件，涉及对结构波动在结晶过程中作用的深入理解和分析，需要综合运用材料科学中的相变理论和结构知识，进行机理层面的解释和推理。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解结晶过程中的结构波动及其与晶体成核的关系，涉及复杂现象的综合分析和机理解释。正确选项不仅需要掌握结晶学的基本概念，还需要能够将这些概念联系起来，进行推理分析。这种深度和综合性的知识运用在选择题中较为罕见，因此属于最高难度等级。" + }, + { + "idx": 3188, + "question": "Direct observation of an aluminum specimen shows a dislocation density within the grains of ρ=5×10^13/m^2. If the angle between subgrains is 5°, estimate the average size of the subgrains (the lattice constant of aluminum is a=2.8×10^-10m).", + "answer": "Assuming all dislocations are concentrated on the subgrain boundaries and each subgrain is a regular hexagon with side length a and area S. S=1/2×a×√3/2×a×6=3√3/2×a^2. The number of subgrains per unit area is n=1/S. Substituting the values of D and S gives 1/2×6a×1/2.28×10^-9×1/(3/2×√3×a^2)=5×10^13. Finally, a=1.01×10^-5m is obtained, so the average subgrain size d=2a=2.02×10^-5m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计亚晶粒的平均尺寸，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算和概念关联，包括对位错密度、亚晶界角度和晶格常数的综合分析，以及几何形状的假设和计算。虽然不涉及复杂的机理解释或创新设计，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解位错密度、亚晶界角度和亚晶尺寸之间的关联，并进行多步计算。题目涉及几何关系推导（六边形面积计算）、单位转换和代数运算，虽然正确选项提供了计算步骤，但需要较强的综合分析能力和材料科学基础知识才能正确理解和应用。" + }, + { + "idx": 3189, + "question": "Under the same negative temperature gradient, why does Pb crystallize into dendritic crystals, while the crystallization interface of Si is flat?", + "answer": "Under the same negative temperature gradient, Pb is a metallic element with a rough interface. Therefore, it grows into dendritic crystals continuously in the direction perpendicular to the liquid-solid interface. In contrast, Si is a non-metallic element with a smooth interface, and it grows into crystals with flat interfaces through discontinuous lateral growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在相同的负温度梯度下，Pb和Si的结晶形态不同，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种不同元素（Pb和Si）在相同负温度梯度下结晶行为的差异，涉及金属和非金属元素的界面特性（粗糙和平滑界面）及其对晶体生长方式的影响。这需要综合运用材料科学中的晶体生长理论、界面动力学和热力学知识，进行机理层面的分析和解释。思维过程需要深入理解不同材料的生长机制，并进行对比分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3190, + "question": "In the symmetric tilt grain boundary of face-centered cubic metal $\\\\mathrm{Cu}$, the spacing between two positive edge dislocations is $D=1000\\\\mathrm{nm}$. Assuming the extra half-plane of the edge dislocation is the (110) plane and $d_{110}=0.1278\\\\mathrm{~nm}$, find the tilt angle $\\\\theta$ of the tilt grain boundary.", + "answer": "The unit dislocation of the face-centered cubic structure is $b=\\\\frac{a}{2}\\\\langle110\\\\rangle$. Since the {110} plane has an extra atomic plane, $b=2d_{110}=2\\\\times0.1278=0.2556\\\\mathrm{nm}$. The tilt angle $\\\\theta$ of the tilt grain boundary can be calculated using the following deformation formula: $$ \\\\theta\\\\approx\\\\frac{b}{D}=\\\\frac{0.2556}{1000}=2.556\\\\times10^{-4}\\\\times\\\\frac{180}{\\\\pi}\\\\approx0.0146^{\\\\circ} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解倾斜角θ，答案中给出了具体的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过已知的位错间距和晶面间距计算倾斜角度，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式进行计算，即通过已知的位错间距和位错矢量计算倾斜角度。解题步骤简单，无需复杂的推理或多步骤计算，属于最基础的难度等级。" + }, + { + "idx": 3191, + "question": "Given: the melting point of aluminum Tm=993K, the volumetric heat of fusion Lm=1.836×10^9 J/m^3, the solid-liquid interface specific surface energy σ=93 mJ/m^2, and the atomic volume V0=1.66×10^-29 m^3. Considering the solidification of liquid aluminum at 1 atm, when the undercooling ΔT=19℃, calculate the critical nucleus size r*.", + "answer": "The critical nucleus size r* = (2σ Tm) / (Lm ΔT) = (2 × 93 × 10^-3 × 993) / (1.836 × 10^9 × 19) = 9.45 × 10^-8 m = 94.5 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（临界核尺寸r*），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个参数的关联和综合分析，包括临界核尺寸的计算公式应用和单位转换，需要一定的理解和应用能力。 | 难度: 在选择题中属于中等偏上难度，需要理解临界核尺寸的概念，掌握相关公式，并进行多步计算。题目涉及多个物理量的代入和单位换算，要求考生具备一定的综合分析能力和计算准确性。虽然题目提供了所有必要参数，但计算过程较为复杂，需要仔细处理指数运算和单位转换。" + }, + { + "idx": 3192, + "question": "What are the characteristics of the outermost crystal zone in the ingot structure?", + "answer": "The outermost layer is a fine equiaxed grain zone. Its formation is due to the lower temperature of the mold wall, which results in a larger undercooling of the liquid and thus a higher nucleation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和描述铸锭结构中最外层晶区的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查的是铸锭结构中最外层晶区的特征及其形成原因，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生不仅记住最外层晶区的名称（细等轴晶区），还要理解其形成原因（模壁温度低导致较大过冷度和较高形核率）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 3193, + "question": "Given: The solid-liquid interface specific surface energy of aluminum σ=93 mJ/m^2, and the free energy change per unit volume ΔGV=-3.51×10^7 J/m^3. Calculate the free energy change ΔGr* (nucleation work) at the critical nucleus size r* during the transition from liquid to solid.", + "answer": "ΔGr* = (16π σ^3) / (3 ΔGV^2) = (16π × (93 × 10^-3)^3) / (3 × (-3.51 × 10^7)^2) = 3.47 × 10^-15 J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的公式和数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了所有必要的参数，并明确要求使用给定的公式进行计算。学生只需正确代入数值并进行简单的数学运算即可得出答案，无需额外的概念理解或复杂的步骤组合。因此，在选择题型内，该题目属于最低难度等级。" + }, + { + "idx": 3194, + "question": "Briefly describe the mechanism of crystal growth.", + "answer": "The mechanism of crystal growth refers to the microscopic growth mode of crystals, which is related to the structure of the liquid/solid interface. For substances with rough interfaces, approximately $50\\\\%$ of the atomic positions on the interface are vacant. These vacancies can accept atoms, allowing liquid atoms to individually occupy the vacancies and connect with the crystal. The interface moves perpendicularly along its normal direction, exhibiting continuous growth. For crystals with smooth interfaces, growth does not occur through the attachment of individual atoms. Instead, it proceeds via homogeneous nucleation, forming a two-dimensional nucleus one atomic layer thick on the crystallographic facet interface. This creates a step between the new nucleus and the original interface. Individual atoms can then fill in the step, enabling lateral growth of the two-dimensional nucleus. Once the layer is filled, a new two-dimensional nucleus forms on the new interface, and the process repeats. If the smooth interface of a crystal has an exposed screw dislocation, the interface becomes a spiral surface, forming a step that never disappears. Atoms attach to this step, allowing the crystal to grow.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶体生长的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细描述晶体生长的微观机制，涉及粗糙界面和平滑界面的不同生长模式，以及二维成核和螺旋位错等复杂概念。需要综合运用材料科学中的晶体生长理论，进行机理的解释和分析，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对晶体生长的微观机制进行深度解释，涉及粗糙界面和光滑界面的不同生长模式，以及二维成核和螺旋位错等复杂概念的综合运用。正确选项不仅需要理解多个专业术语和物理过程，还需要将这些概念有机串联起来解释完整的生长机理。这种需要同时掌握界面结构、原子附着方式、生长动力学等多维度知识的题目，在选择题中属于对专业知识和分析能力要求极高的类型，完全符合\"复杂现象全面分析\"的等级5标准。" + }, + { + "idx": 3195, + "question": "What are the characteristics of the central equiaxed grain zone in the ingot structure?", + "answer": "The center is the equiaxed grain zone. Its formation is due to the further increase in mold wall temperature and the further decrease in liquid undercooling, resulting in the heat dissipation directionality of the remaining liquid becoming less obvious and the liquid being in a state of uniform cooling. At the same time, unmelted impurities, broken dendrites, etc., tend to concentrate in the remaining liquid, all of which promote the formation of equiaxed grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述中心等轴晶区的特征，答案提供了详细的文字描述和解释，符合简答题的特点。 | 知识层次: 题目要求解释铸锭结构中中心等轴晶区的形成机理，涉及多个因素的相互作用（如温度变化、液体过冷度、散热方向性、杂质和枝晶碎片的影响等），需要综合运用材料科学中的凝固原理和晶体生长知识进行推理分析，思维过程较为深入。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解铸锭结构中中心等轴晶区的特征，还需要综合运用材料科学知识，分析其形成机理（如模具壁温升高、液体过冷度降低、散热方向性减弱等），并解释杂质和破碎枝晶对等轴晶形成的影响。这种复杂现象全面分析和机理深度解释的要求，在选择题型中属于最高难度级别，需要考生具备扎实的理论基础和综合分析能力。" + }, + { + "idx": 3196, + "question": "Analyze the basic conditions for the formation of single crystals.", + "answer": "The basic condition for forming a single crystal is to ensure that only one nucleus is produced (or only one nucleus can grow) when the liquid metal crystallizes, and it grows into a single crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求分析单晶形成的基本条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查单晶形成的基本条件，属于对基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述单晶形成的基本条件，而不仅仅是简单的定义记忆。正确选项要求考生能够解释为什么需要确保只有一个核生成或生长，这比单纯记忆定义需要更深一层的理解。因此，该题目在选择题型中属于概念解释和描述的难度等级。" + }, + { + "idx": 3197, + "question": "Given: The volumetric latent heat of fusion for aluminum Lm=1.836×10^9 J/m^3, melting point Tm=993K, undercooling ΔT=19℃. Calculate the change in volumetric free energy ΔGV during the transformation from liquid to solid.", + "answer": "ΔGV = (-Lm ΔT) / Tm = (-1.836 × 10^9 × 19) / 993 = -3.51 × 10^7 J/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果。 | 知识层次: 题目要求直接套用给定的公式进行数值计算，涉及基本的公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求直接套用给定的公式 ΔGV = (-Lm ΔT) / Tm，并进行简单的数值代入和计算。不需要理解多个概念或进行复杂的分析，仅需基本的代数运算能力即可得出正确答案。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3198, + "question": "Given the liquid-solid interfacial energy of pure liquid nickel σ=2.53×10^-5 J/cm^2, the critical nucleus radius r*=1 nm, the melting point of pure nickel Tm=1726 K, the heat of fusion ΔLm=18075 J/mol, the molar volume Vs=6.6 cm^3/mol, and the undercooling ΔT=319 K, calculate the critical nucleation work ΔG*.", + "answer": "ΔG*=(16πσ^3·Tm^2·Vs^2)/(3·Lm^2·ΔT^2)=(16×3.14×(2.53×10^-5)^3×1726^2×6.6^2)/(3×18075^2×319^2)=1.06×10^-18 (J)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是一个具体的数值结果，解答过程涉及多个参数的代入和计算步骤。 | 知识层次: 题目需要进行多步计算，涉及多个参数的代入和公式的综合应用，需要理解临界核形成功的概念及其与各参数之间的关系，但不需要进行复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如临界核半径、界面能、过冷度等）并进行多步骤的综合计算。虽然题目提供了所有必要参数，但计算过程涉及多个变量的组合和复杂公式的应用，要求考生具备较强的综合分析能力和计算准确性。" + }, + { + "idx": 3199, + "question": "How does vibration crystallization refine grain size?", + "answer": "Vibration, on one hand, provides the energy required for nucleation, and on the other hand, can fracture growing crystals, thereby increasing more crystallization nuclei and refining the grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释振动结晶如何细化晶粒尺寸，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释振动结晶细化晶粒的机理，涉及能量供给、形核和晶体生长的综合分析，需要深入理解振动对结晶过程的影响机制，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解振动结晶的基本原理，还需要综合运用多个知识点（如成核能、晶体生长断裂机制、晶粒细化原理）进行机理层面的深度解释。正确选项涉及复杂现象的全面分析，需要考生具备将振动能量传递、晶体断裂与晶粒尺寸控制等跨领域知识整合的能力，这远超单纯记忆或简单应用层面，属于材料科学中需要高阶思维能力的题目类型。" + }, + { + "idx": 3200, + "question": "Does the ingot structure necessarily have three crystal zones?", + "answer": "It should be pointed out that not all ingot structures have three crystal zones. Due to different solidification conditions, an ingot may only have one type of crystal zone or only two types of crystal zones.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，即“铸锭结构是否必然有三个晶区”，而答案明确指出了该陈述的错误性，并解释了原因。这符合判断题的特征。 | 知识层次: 题目考查对铸锭结构基本概念的记忆和理解，涉及铸锭晶体区的分类和形成条件，属于基础概念层次。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对铸锭结构晶体区基本概念的理解，需要判断\"是否所有铸锭结构都必然具有三个晶体区\"这一陈述的正确性。虽然涉及基础概念记忆，但需要考生理解铸锭结构形成原理和不同凝固条件的影响，属于对概念理解的简单应用判断，比单纯记忆性知识（等级1）略高，但尚未达到需要分析复杂概念陈述的等级3难度。" + }, + { + "idx": 3201, + "question": "What are the characteristics of the intermediate crystal zone in the ingot structure?", + "answer": "The intermediate zone consists of columnar crystals. Its formation is primarily due to the increase in mold wall temperature, where the growth rate of crystal nuclei exceeds the nucleation rate, and heat dissipation is more favorable in the direction perpendicular to the mold wall. In the fine crystal zone, preferentially oriented grains grow into columnar crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释中间晶区的特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目要求解释中间晶区的特征及其形成原因，涉及晶体生长速率与形核速率的关系、热传导方向的影响以及晶粒择优取向等概念的综合分析，需要将多个知识点关联起来进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及中间晶区的特征、形成原因以及与细晶区的关系，要求考生能够综合运用晶体生长和热传导的知识。虽然不需要复杂的计算，但需要对多个概念进行关联分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3203, + "question": "According to solidification theory, what are the basic approaches to refining grains?", + "answer": "From solidification theory, it is known that the number of grains per unit volume during crystallization, z, depends on two factors: the nucleation rate N and the crystal growth rate Vg, i.e., z∝N/Vg. The basic approaches include increasing undercooling, adding nucleating agents (modification treatment), and vibration crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述基本的晶粒细化方法，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目要求从凝固理论出发，解释细化晶粒的基本方法，涉及对成核速率和晶体生长速率的理解，以及如何通过增加过冷度、添加形核剂和振动结晶等方法实现晶粒细化。这需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及凝固理论中的晶粒细化基本方法，要求考生掌握成核速率和晶体生长速率的关系，并能综合分析增加过冷度、添加成核剂（变质处理）和振动结晶等不同方法的作用。虽然不需要多步计算，但需要将多个概念关联起来进行综合分析，因此在选择题型中属于等级3的难度。" + }, + { + "idx": 3204, + "question": "How does increasing undercooling refine grains?", + "answer": "Increasing the undercooling ΔT causes both N and Vg to increase, but the growth rate of N is greater than that of Vg. Therefore, the value of N/Vg increases, meaning z becomes larger.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释undercooling如何细化晶粒，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要解释增加过冷度如何细化晶粒，涉及成核率（N）和生长速率（Vg）的变化及其相对关系，要求综合运用成核与生长理论进行机理分析，思维过程较深入。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解过冷度（ΔT）对晶粒细化（N/Vg）的影响机制，还需要综合运用成核率（N）和生长速率（Vg）的动态关系进行推理分析。正确选项涉及多变量相互作用（N和Vg增速差异）的机理解释，且需要推导最终结论（z值变化），这显著超出了基础概念记忆或简单比较的认知层次，完全符合\"复杂现象全面分析\"的能力要求。" + }, + { + "idx": 3205, + "question": "How does adding a nucleating agent (modification treatment) refine the grain size?", + "answer": "After adding a nucleating agent, it can promote heterogeneous nucleation in the undercooled liquid. It not only increases the substrates required for heterogeneous nucleation but also reduces the critical nucleus volume, both of which will increase the number of nuclei, thereby refining the grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释添加成核剂如何细化晶粒尺寸，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释成核剂如何细化晶粒的机理，涉及异质成核、临界晶核体积等概念的关联和综合分析，需要深入理解并解释多个因素如何共同作用，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解成核剂的基本作用（促进异质成核），还需要综合分析其对临界晶核体积和成核基底数量的双重影响机制。正确选项涉及凝固学中较深层次的机理解释（降低临界晶核体积与增加成核基底协同作用），需要将\"过冷液体中的异质成核理论\"与\"晶粒细化实际效果\"建立逻辑关联。这种在选择题中要求对复杂现象进行多因素机理解释的题目，远超单纯记忆或简单应用层面，属于典型的复杂分析层次。" + }, + { + "idx": 3206, + "question": "A Cu-30%Zn brass cold-rolled sheet undergoes 25% cold deformation, resulting in a thickness of 1cm. Find the original thickness Lo.", + "answer": "From (Lo - 1)/Lo = 25%, solving gives Lo = 4/3 cm ≈ 1.333 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解原始厚度Lo，答案是通过数学计算得出的具体数值结果。 | 知识层次: 题目仅涉及基本的百分比变形计算和简单代数运算，属于直接套用公式和基本计算的应用层次，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即通过给定的变形百分比和最终厚度求解原始厚度。解题步骤简单，仅需一步代数运算即可得出答案，无需组合多个公式或进行复杂分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3207, + "question": "Compress the above-mentioned cold-rolled sheet from 1cm thickness to 0.6cm, and find the true linear strain e.", + "answer": "e = ln(0.6/(4/3)) ≈ -80%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算真实线性应变e），并给出了具体的计算步骤和结果（e = ln(0.6/(4/3)) ≈ -80%）。这符合计算题的特征，即需要应用公式和进行数值计算来得出答案。 | 知识层次: 题目要求应用真实线性应变的公式进行计算，属于基本公式的直接应用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（真实线性应变公式 e = ln(final thickness / initial thickness)）并进行简单计算。题目没有涉及多个公式的组合或复杂的概念分析，属于最基础的难度等级。" + }, + { + "idx": 3208, + "question": "A specimen with an original gauge length of L0 is stretched to L. Determine the engineering linear strain and true linear strain during the stretching process.", + "answer": "Engineering linear strain ε = (L - L0) / L0; true linear strain e = ln(L / L0)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式计算工程线性应变和真实线性应变，答案给出了具体的计算公式和结果形式，属于典型的计算题。 | 知识层次: 题目要求直接应用工程应变和真实应变的定义公式进行计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及两个不同的应变定义（工程应变和真实应变），但都是直接套用基本公式，不需要复杂的推导或组合计算。学生只需记住这两个公式并正确应用即可，解题步骤相对简单。" + }, + { + "idx": 3209, + "question": "Compress the above-mentioned cold-rolled sheet from 1cm thickness to 0.6cm, calculate the total engineering strain ε.", + "answer": "ε = (0.6 - 4/3)/(4/3) ≈ -55%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算工程应变ε），并给出了具体的计算公式和最终数值结果，符合计算题的特征。 | 知识层次: 题目仅需应用基本的工程应变公式进行计算，属于直接套用公式的简单计算题，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用工程应变的基本公式进行计算，属于单一公式直接计算的简单应用。题目明确给出了初始和最终厚度，只需套用公式即可得出答案，无需额外的分析或组合多个公式。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3210, + "question": "Can close-packed hexagonal metal magnesium produce cross-slip? What is the slip direction?", + "answer": "In addition to the (0001) $<11$ $\\overline{2}0>$ slip system, magnesium also has $|10\\overline{{1}}1\\}<11\\overline{{2}}0$ > slip systems, and the slip direction is always $<11\\overline{{2}}0:$, so cross-slip can occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁金属是否能够产生交叉滑移以及滑移方向，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要记忆镁的滑移系统，还需要理解滑移方向的概念，并分析交叉滑移的可能性。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，题目涉及密排六方金属镁的滑移系统和交叉滑移的概念，需要考生不仅掌握基本的滑移方向知识，还需要理解交叉滑移的条件和机制。此外，题目要求综合分析不同滑移系统之间的关系，并准确识别滑移方向，这需要较深的知识掌握和多角度分析能力。" + }, + { + "idx": 3211, + "question": "A 20m long aluminum rod with a diameter of 14.0mm is drawn through a die with an aperture of 12.7mm. Calculate the true strain experienced by this aluminum rod.", + "answer": "True strain e=ln(L/L0)=ln(24.3/20)=19.47%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用对数公式计算真实应变）来得出具体数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式（真实应变公式）的直接应用和简单计算，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（true strain公式）进行计算，无需额外的概念理解或步骤组合。解题过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 3212, + "question": "A 20m long aluminum rod with a diameter of 14.0mm is drawn through a die with an aperture of 12.7mm. Calculate the engineering linear strain experienced by this aluminum rod.", + "answer": "The engineering strain ε=(L-L0)/L0=21.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算工程线性应变），需要应用公式ε=(L-L0)/L0，并最终给出数值结果21.5%，符合计算题的特征。 | 知识层次: 题目考查基本公式（工程应变公式）的直接应用和简单计算，不需要多步推导或综合分析 | 难度: 在选择题型中，该题目仅需要直接应用工程应变的基本公式 ε=(L-L0)/L0 进行计算，无需额外的公式组合或复杂推导。题目提供了所有必要的参数（初始长度和直径变化），计算步骤简单直接，属于单一公式直接计算的难度等级。" + }, + { + "idx": 3214, + "question": "Compress the above stretched specimen from L to L0, and calculate the engineering linear strain and true linear strain during the compression process.", + "answer": "Engineering linear strain ε = (L0 - L) / L; true linear strain e = ln(L0 / L)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算公式和结果形式，符合计算题的特征。 | 知识层次: 题目要求应用基本的工程应变和真实应变公式进行计算，属于直接套用公式的简单应用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用两个不同的应变公式（工程线性应变和真实线性应变），但这两个公式都是直接套用，无需复杂的推导或组合计算。题目要求考生掌握基本公式的应用能力，但解题步骤相对简单，属于选择题型中的中等偏下难度。" + }, + { + "idx": 3216, + "question": "Given: The critical nucleus size of aluminum r*=94.5 nm, atomic volume V0=1.66×10^-29 m^3. Calculate the number of atoms Nr* in a nucleus with radius r*.", + "answer": "Nr* = (4/3 π r*^3) / V0 = (4/3 π × (94.5 × 10^-9)^3) / (1.66 × 10^-29) = 2.12 × 10^8", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的临界核尺寸和原子体积计算核中的原子数量，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即使用球形体积公式除以原子体积来得到原子数量。解题步骤简单，无需组合多个公式或进行复杂的概念分析，属于最基础的直接计算类型。" + }, + { + "idx": 3218, + "question": "Given that the critical resolved shear stress of pure aluminum is τ_c = 0.79 MPa, the question is: To produce slip in the [110] direction on the (1̅11) plane, what magnitude of force should be applied in the [001] direction?", + "answer": "The slip plane is (1̅11), the slip direction is [110], and the force axis is [001]. Then, cosφ = 1/√3; cosλ = 0/√2 = 0. Since λ = 90°, σ_S = τ_c / (cosλ · cosφ) = ∞. Therefore, when the force axis is in the [001] direction, the (111)[110] slip system will not be activated.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定施加在特定方向上的力的大小，解答过程中涉及到了三角函数计算和临界分切应力的应用，最终得出一个具体的数值结果。 | 知识层次: 题目需要多步计算和概念关联，包括确定滑移面和滑移方向、计算方向余弦、应用临界分切应力公式，并进行综合分析判断滑移系统是否激活。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合理解和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及临界分切应力、滑移面和滑移方向的概念，以及施密特定律的应用。解题步骤包括确定滑移面和滑移方向、计算施密特因子、判断滑移系统是否激活等。虽然题目给出了具体数值，但需要综合运用多个知识点进行计算和判断，属于综合性计算问题。" + }, + { + "idx": 3219, + "question": "The surface of a copper single crystal is parallel to {001}. If a tensile force is applied along the [001] direction, and the measured critical resolved shear stress is $\\overline{{\\tau_{c}}}=0.7$ MPa, determine the stress at which the material yields.", + "answer": "The force is applied along the [001] direction, which is in a soft orientation with 8 equivalent slip systems. Taking one of them, (111)[overline{1}01], we have: $$ \\cos\\lambda={\\frac{1}{\\sqrt{2}}};\\cos\\varphi={\\frac{1}{\\sqrt{3}}} $$ $$ \\sigma_{S}={\\frac{\\tau_{c}}{\\cos\\lambda\\cdot\\cos\\varphi}}={\\frac{0.7}{{\\frac{1}{\\sqrt{2}}}\\cdot{\\frac{1}{\\sqrt{3}}}}}=1.715~{\\mathrm{MPa}} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定材料屈服时的应力，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，包括确定滑移系统、计算方向余弦以及应用临界分切应力公式。虽然不涉及复杂的综合分析或机理解释，但需要将多个概念（如滑移系统、方向余弦、临界分切应力）关联起来进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解临界分切应力的概念，掌握晶体滑移系统的等效性，并能正确应用施密特定律进行多步骤计算。虽然题目提供了具体的滑移系统方向，但仍需要考生综合运用多个知识点才能得出正确答案。" + }, + { + "idx": 3220, + "question": "A face-centered cubic single crystal is stretched with [131] as the force axis. When the tensile stress is 1×10^7Pa, determine the resolved shear stress on the (111)[1\\\\overline{1}0] slip system.", + "answer": "For the (111)[1\\\\overline{1}0] slip system, cosφ=5√33/33; cosλ=-√22/11. Therefore, τ3=1×10^7×(5√33/33)×(-√22/11)=3.7×10^6Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定滑移系上的分切应力，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要计算面心立方单晶在特定拉伸方向下的分切应力，涉及晶体学方向指数的计算、施密特因子的求解以及分切应力公式的应用。虽然计算步骤明确，但需要理解晶体学方向与滑移系统的关系，并进行多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体滑移系统的概念，掌握分解剪应力的计算方法，并进行多步向量运算和三角函数计算。虽然题目提供了正确选项，但解题过程涉及方向余弦计算、向量点积和综合分析，比单纯的概念选择题更复杂。" + }, + { + "idx": 3223, + "question": "In the compression test of a magnesium single crystal at room temperature, the [0001] direction coincides with the compression axis. Assuming that the critical resolved shear stress for twinning on the (10\\\\overline{1}2) plane is 10 times that for slip on the (0001) plane, denoted as $\\\\tau_{\\\\mathrm{e}}$, determine whether the crystal will undergo twinning or slip when the compressive stress is sufficiently large, and explain why.", + "answer": "If the compression axis coincides with the [0001] direction, since the slip directions of different slip systems in magnesium are the same, all being <11\\\\overline{2}0> directions, and the slip directions are all perpendicular to the [0001] direction, $\\\\cos\\\\lambda=0$. Therefore, $\\\\sigma_{S}=\\\\frac{\\\\sigma_{C}}{\\\\cos\\\\lambda\\\\cos\\\\phi}=\\\\infty$. No matter how large the pressure is, slip cannot occur. However, the twinning plane is {10\\\\overline{1}2}, and the twinning direction is {10\\\\overline{1}2}. When compressed along the [0001] direction, there is a resolved shear stress. When the external force reaches a certain value, twinning will occur along {10\\\\overline{1}2}<\\\\overline{1}011>{10\\\\overline{1}2}. In this example, the resolved shear stress for twinning has already reached 10 times $\\\\tau_{C}$, so twinning deformation can occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下镁单晶会发生孪生还是滑移，并给出原因。答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析镁单晶在特定压缩轴方向下的变形机制选择（孪生或滑移），涉及晶体学方向、临界分切应力计算、变形机制比较等复杂概念的综合运用。需要理解滑移系和孪生系的几何关系，计算分切应力，并比较不同变形机制的临界条件，进行推理分析。这超出了简单应用或中等应用的范畴，属于需要综合运用知识进行复杂分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3224, + "question": "A copper single crystal is subjected to tension with the tensile axis along the [001] direction and σ=10^6 Pa. Calculate the force acting on a screw dislocation line with Burgers vector b=(a/2)[1̄01] on the (111) plane. Given a_Cu=0.36 nm.", + "answer": "The tensile stress is applied along the [001] direction. On the (111) slip plane, the resolved shear stress along the [1̄01] direction is τ=σcosφcosλ, where cosφ=1/√3, cosλ=1/√2, and σ=10^6 Pa. Thus, τ=10^6×(1/√3)×(1/√2)≈4.08×10^5 Pa. The force per unit length on the dislocation line is F_d=τb=4.08×10^5×(√2/2)×0.36×10^(-9)≈1.04×10^(-4) N/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及应力分解、剪切应力计算以及位错线受力计算等具体运算步骤，最终需要得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括计算分解剪切应力、应用施密特定律、计算位错受力等步骤。虽然涉及的概念和公式较为基础，但需要将这些概念和公式关联起来进行综合分析，思维过程有一定的深度要求。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如Burgers向量、滑移面、分解剪应力等）并进行多步计算（包括方向余弦计算、分解剪应力公式应用、单位转换等）。虽然题目提供了具体公式和步骤，但综合应用和计算过程仍具有一定复杂性，属于综合性计算问题。" + }, + { + "idx": 3225, + "question": "A copper single crystal is subjected to tensile stress with the tensile axis along the [001] direction and σ=10^6 Pa. Calculate the force on the edge dislocation line with Burgers vector b=(a/2)[1̄01] on the (111) plane. Given a_Cu=0.36 nm.", + "answer": "The tensile stress is applied along the [001] direction. On the (111) slip plane, the resolved shear stress along the [1̄01] direction is τ=σcosφcosλ, where cosφ=1/√3, cosλ=1/√2, and σ=10^6 Pa. Thus, τ=10^6×(1/√3)×(1/√2)≈4.08×10^5 Pa. The force per unit length on the dislocation line is F_d=τb=4.08×10^5×(√2/2)×0.36×10^(-9)≈1.04×10^(-4) N/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及应力分解、剪切应力计算和单位长度力的求解，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括应力分解、剪切应力计算以及力的大小计算，涉及多个概念的综合应用和关联分析。虽然不涉及复杂的推理或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及晶体学方向、应力分解、位错受力计算等多个步骤，要求考生能够综合运用材料科学中的基本概念和公式进行计算。虽然题目提供了部分计算步骤，但仍需要考生对相关概念有较深的理解才能正确解答。" + }, + { + "idx": 3226, + "question": "What are the practical applications of fracture toughness K_IC in mechanical design?", + "answer": "1. Given the working stress σ and the fracture toughness K_IC of the material, the maximum allowable crack size a_c in the workpiece can be estimated. 2. Given the crack size a and the working stress σ, the stress intensity factor K_I during operation can be determined to provide a theoretical basis for reasonable material selection. 3. Given K_IC and the existing crack size a, the maximum allowable stress σ can be determined. If the working stress is less than this stress, the crack will not propagate; otherwise, the crack will become unstable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释断裂韧性K_IC在机械设计中的实际应用，答案提供了详细的文字解释和论述，没有涉及计算、选择或判断对错。 | 知识层次: 题目要求应用断裂韧性K_IC的概念来解决实际工程问题，涉及多步计算和概念关联，如估算最大允许裂纹尺寸、确定应力强度因子和最大允许应力等。这需要理解断裂力学的基本原理，并能将其应用于具体的设计场景，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多个步骤的计算和概念关联，要求考生能够综合分析材料的工作应力、断裂韧性和裂纹尺寸之间的关系。虽然题目提供了具体的应用场景，但需要考生具备一定的材料力学知识基础，能够将理论知识与实际应用相结合。" + }, + { + "idx": 3227, + "question": "Describe the process of extended dislocation cross-slip from the (111) plane to the (111) plane in a face-centered cubic structure.", + "answer": "When the extended dislocation on the (111) plane encounters obstacles during slip, it can constrict to form a screw-type perfect dislocation. The dislocation reaction is $$\\\\frac{a}{6}[\\\\bar{1}2\\\\bar{1}]+\\\\frac{a}{6}[\\\\bar{2}11]-\\\\frac{a}{2}[\\\\bar{1}10]$$The formed screw dislocation has a Burgers vector $b=\\\\frac{a}{2}$ [\\\\overline{1}10], and the dislocation line $t=[\\\\overline{{1}}10]$. It can cross-slip onto the (11\\\\overline{1}) plane and spread out, forming an extended dislocation on the (11\\\\overline{1}) plane, i.e., $\\\\frac{a}{2}[\\\\overline{{{110}}}]\\\\rightarrow\\\\frac{a}{6}[\\\\overline{{{21}}}\\\\overline{{{1}}}]+\\\\frac{a}{6}[\\\\overline{{{1}}}21]$. This extended dislocation can continue to move on the (11\\\\overline{1}) plane or constrict again to cross-slip back onto the (111) plane and spread out once more.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述面心立方结构中扩展位错从(111)面到(111)面的交滑移过程，答案通过文字解释和论述给出了完整的位错反应和运动过程，符合简答题的特征。 | 知识层次: 题目涉及扩展位错的交滑移过程，需要理解位错反应、Burgers矢量的计算以及在不同晶面上的运动机制。这需要综合运用位错理论、晶体结构知识以及位错运动的动力学分析，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解面心立方结构中扩展位错的交滑移过程，包括位错反应、Burgers矢量的计算、位错线的方向以及在不同滑移面上的扩展和收缩机制。解题步骤复杂，需要综合运用位错理论、晶体学知识以及数学表达式进行推理分析。此外，题目还涉及复杂的机理解释和现象全面分析，对学生的知识掌握深度和综合应用能力要求极高。" + }, + { + "idx": 3229, + "question": "What is called fracture toughness K_IC?", + "answer": "K_IC is the critical value of the stress intensity factor for a Type I crack, representing the fracture toughness in terms of stress intensity factor under linear elastic conditions, with the unit MPa*m^0.5.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"fracture toughness K_IC\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查对断裂韧性K_IC这一基本概念的定义和单位记忆，属于基础概念的记忆和理解层面，不涉及复杂应用或分析。 | 难度: 该题目要求考生理解和记忆\"fracture toughness K_IC\"的定义及其关键特征（如临界应力强度因子、I型裂纹、线弹性条件等），属于概念解释和描述的层次。虽然涉及多个专业术语，但在选择题型中只需识别正确描述，不需要进行复杂的概念体系阐述或分析比较，因此属于中等难度。" + }, + { + "idx": 3230, + "question": "Describe the similarities between twinning and slip", + "answer": "The similarities between slip and twinning are that both are fundamental modes of crystal plastic deformation, both occur as shear under shear stress along certain crystallographic planes and directions, and the crystal structure type remains unchanged before and after deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述两种晶体塑性变形方式的相似之处，需要文字解释和论述，答案也以文字形式呈现，符合简答题的特征 | 知识层次: 题目考查对晶体塑性变形基本模式（滑移和孪生）的相似性的记忆和理解，属于基础概念的对比和描述，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于中等难度，需要理解并比较两个基本概念（滑移和孪生）的相似之处，涉及对晶体塑性变形基本原理的记忆和描述，但不需要复杂的分析或推理。" + }, + { + "idx": 3231, + "question": "In the actual crystallization process of metals, nucleation occurs in two ways: homogeneous nucleation and heterogeneous nucleation. Since homogeneous nucleation requires higher nucleation energy, heterogeneous nucleation is predominantly observed.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查金属结晶过程中均质形核和非均质形核的基本概念及其能量差异的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于金属结晶过程中均匀成核和非均匀成核的基本陈述是否正确。题目直接给出了明确的正误判断选项（√），无需进行复杂的概念分析或比较。在选择题型中，这类直接考察定义和分类记忆的题目属于最简单的难度等级。" + }, + { + "idx": 3232, + "question": "Some solid solutions with certain atomic ratios are disordered solid solutions at high temperatures, and may transform into ordered solid solutions when cooled below a certain critical temperature. Once the ordering transition occurs, it can lead to abrupt changes in certain properties.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，并要求判断其正确性（答案用√表示正确），符合判断题的特征。 | 知识层次: 题目考查对固溶体有序-无序转变这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或计算。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅要求考生识别关于固溶体有序-无序转变的基本定义和现象描述是否正确，不需要进行复杂的概念分析或比较。这种题型主要测试对基础概念的记忆能力，属于选择题型中最基础的难度等级。" + }, + { + "idx": 3233, + "question": "Describe the differences between twinning and slip", + "answer": "The differences are as follows: twinning causes a uniform shear in a portion of the crystal, while slip is concentrated only on certain slip planes. During slip, the slipped and unslipped parts of the crystal have the same phase, whereas the twinned part and the matrix have different phases, exhibiting a special mirror-symmetry relationship. In twinning deformation, the atomic displacement is less than the atomic spacing in the twinning direction, being a fractional multiple of the atomic spacing; during slip deformation, the distance atoms move is an integer multiple of the atomic spacing in the slip direction. Similar to slip, twinning elements are also related to the crystal structure, but the twinning plane and twinning direction in the same structure can differ from the slip plane and slip direction. The critical resolved shear stress for twinning is much higher than that for slip. The stress-strain curve for twinning deformation differs from that of slip, showing serrated fluctuations, mainly because the shear stress required for twinning 'nucleation' is greater than the stress needed for twinning boundary propagation. Generally, slip occurs first, and twinning deformation occurs only when slip becomes difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述孪生和滑移之间的差异，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求描述孪生和滑移的差异，涉及多个概念的综合比较和关联分析，需要理解两者的变形机制、晶体结构关系以及应力-应变行为等，属于中等应用层次的知识。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解并区分孪生和滑移这两个关键概念，还需要综合分析它们在晶体变形中的不同表现和机制。具体来说，题目涉及多个方面的比较，如剪切分布、相位关系、原子位移、临界分切应力以及应力-应变曲线的差异等。此外，题目还要求考生理解孪生和滑移的先后顺序及其在晶体结构中的具体应用。这种多角度的分析和论述在选择题型中较为复杂，需要考生具备较深的知识掌握和综合分析能力。" + }, + { + "idx": 3234, + "question": "Using the three-axis system to index the crystallographic plane indices and direction indices of a hexagonal close-packed structure, the resulting indices for the same family of planes or directions are different.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查对六方密堆积结构晶面指数和方向指数标定方法的基础概念记忆，属于对基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。虽然涉及六方密堆积结构的晶面指数和方向指数的概念，但题目仅要求判断关于不同坐标系下指数差异的基本陈述是否正确，不需要复杂的分析或比较多个概念。因此属于中等难度。" + }, + { + "idx": 3235, + "question": "During the crystallization of liquid metal, the degree of undercooling required to form an embryo equal to the critical nucleus radius in the undercooled liquid is called the critical undercooling.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案用√表示正确），这符合判断题的特征 | 知识层次: 题目考查对临界过冷度这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆题型，仅需判断\"临界过冷度\"的定义是否正确。题目直接给出定义陈述，不需要任何推导或分析，属于选择题型中最简单的正误判断题。在选择题型内，这类仅需记忆定义即可作答的题目属于最低难度等级。" + }, + { + "idx": 3236, + "question": "At room temperature, the plastic deformation modes of metal polycrystals are A. Slip, twinning, creep B. Slip, twinning, kinking C. Slip, climb, cross-slip D. Slip, twinning, grain boundary sliding", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C、D）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查金属多晶体在室温下的塑性变形模式的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解金属多晶体在室温下的塑性变形模式，并对选项中的概念进行简单辨析。虽然涉及多个变形模式（滑移、孪生、扭折），但这些都是基础概念，不需要复杂的分析或深度理解即可选出正确答案。" + }, + { + "idx": 3237, + "question": "The relationship between the yield strength and grain size of No. 10 steel was measured as follows: when the grain diameter was $400\\\\mu m$, $\\\\partial_{\\\\mathfrak{s}}=86$ MPa, and when the grain diameter was $5\\\\mu\\\\mathrm{m}$, $\\\\sigma_{\\\\mathrm{s}}=242$ MPa. Determine the yield strength when the average grain diameter is $50~\\\\mu\\\\mathrm{m}$.", + "answer": "Using the Hall-Petch formula $\\\\sigma_{S}=\\\\sigma_{0}+k d^{-\\\\frac{1}{2}}$, the system of equations is obtained as: $$186=\\\\sigma_{0}+k(400\\\\times10^{-6})^{-\\\\frac{1}{2}}$$ $$1242=\\\\sigma_{0}+k(5\\\\times10^{-6})^{-\\\\frac{1}{2}}$$ Solving gives: $$k=0.393;\\\\sigma_{0}=66.25\\\\mathrm{MPa}$$ Substituting $d=50\\\\times10^{-6}(\\\\mathrm{m})$ into the Hall-Petch formula: $$\\\\sigma_{S}=66.25+0.393(50\\\\times10^{-6})^{-\\\\frac{1}{2}}\\\\approx121.83~\\\\mathrm{MPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch公式）来确定特定晶粒尺寸下的屈服强度，答案展示了具体的计算过程和结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，包括建立方程组、求解常数、代入新值计算等步骤，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并建立方程组，进行多步计算求解常数项和系数，最后代入新数据进行计算。虽然题目提供了公式，但解题过程涉及多个计算步骤和单位换算，需要较强的综合分析能力。" + }, + { + "idx": 3238, + "question": "The main mechanism of high-temperature recovery is A. Dislocation slip and cross-slip B. Dislocation climb and polygonization C. Polygonization and subgrain coalescence D. Bulge nucleation and subgrain coalescence", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对高温回复机制的理解和应用，需要将多个概念（位错攀移和多边化）关联起来进行分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解高温回复的主要机制，还需要区分多个相似但不同的概念（如位错滑移、交叉滑移、位错攀移、多边形化等）。解题过程涉及综合分析多个材料科学原理，并准确关联到高温回复的具体机制。此外，选项中的术语和概念需要较深的理解才能正确判断，属于中等应用层次的多步分析和概念关联题目。" + }, + { + "idx": 3239, + "question": "Among the following alloy phase structures, the one with high melting point, high hardness, great brittleness, and simple crystal structure is A. Topologically close-packed phase B. Interstitial compound with complex lattice structure C. Electron compound D. Interstitial phase", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对合金相结构基本特性的记忆和理解，如熔点、硬度、脆性和晶体结构的简单性等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个合金相结构的特性比较，但正确选项D（间隙相）具有明确的特征描述（高熔点、高硬度、大脆性、简单晶体结构），这些特征在基础材料科学课程中通常会被强调和记忆。考生需要理解并辨析不同合金相结构的基本特性，但不需要进行复杂的分析或推导。因此，该题目在选择题型中属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3240, + "question": "Using the Peierls-Nabarro formula, explain why slip in crystals usually occurs on the closest-packed planes and in the closest-packed directions.", + "answer": "During room temperature deformation, since the grain boundary strength is higher than that within the grain, the finer the grains, the more grain boundaries are contained per unit volume, resulting in a better strengthening effect. According to the Hall-Petch formula, $\\sigma_{s}=\\sigma_{0}+k d^{-\\frac{1}{2}},$ the smaller the grain diameter $d$, the higher $\\sigma_{S}$ becomes, which is known as fine-grain strengthening. Each grain in a polycrystal is surrounded by other grains, so deformation is not isolated and requires neighboring grains to coordinate and adapt to the shape changes of plastically deformed grains. Plastic deformation must involve multiple slip systems from the outset. The finer the grains, the better the deformation coordination, and thus the better the plasticity. Additionally, finer grains reduce the severity of stress concentrations caused by dislocation pile-ups, which can delay crack initiation. The tortuous grain boundaries hinder crack propagation, contributing to improved strength and plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Peierls-Nabarro公式解释晶体滑移通常发生在最密排面和最密排方向的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求使用Peierls-Nabarro公式解释晶体滑移现象，涉及晶体结构、滑移系统选择的理论基础，以及公式的物理意义和应用。这需要综合运用材料科学中的晶体学知识、位错理论和力学性能分析，属于对多个概念的关联和深入理解，并进行推理分析的过程。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用Peierls-Nabarro公式、Hall-Petch关系、多晶变形协调机制等多个高级概念，进行复杂的机理分析和推理。需要深入理解晶界强化、位错堆积、应力集中等微观机制，并能将这些概念联系起来解释宏观力学性能。这种需要多知识点整合和机理深度解释的题目，在选择题中属于最复杂的类型，对考生的材料科学理论基础和分析能力要求极高。" + }, + { + "idx": 3241, + "question": "The driving force for atomic diffusion is A. Concentration gradient of components B. Temperature gradient C. Chemical potential gradient of components", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对原子扩散驱动力的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆，但需要学生对\"原子扩散驱动力\"这一概念有准确理解，并能区分浓度梯度、温度梯度和化学势梯度这三个相近概念。正确选项C不是最直观的选项(学生可能首先想到浓度梯度)，因此需要一定的概念辨析能力，但不需要复杂的分析过程。" + }, + { + "idx": 3242, + "question": "When polycrystalline metal is heated to a relatively high temperature and held, the grains will grow. The grain growth mode is A. Subgrain coalescence and growth B. Grain boundary bowing outward and growth C. Grain boundary moving toward the curvature center D. Movement of Y junctions", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对晶粒生长模式的理解，需要将晶界移动与曲率中心的关系进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，此题属于较高难度。题目涉及多晶金属在高温下的晶粒生长机制，需要考生理解晶界移动的物理机制（如曲率驱动迁移）并综合分析不同生长模式的区别。正确选项C要求考生掌握晶界向曲率中心移动这一非直观概念，并能排除其他看似合理的干扰选项（如亚晶合并或Y结移动）。这需要将材料科学基础理论与实际现象关联，属于中等应用层次的多步分析判断。" + }, + { + "idx": 3243, + "question": "In the cubic system, the relationship between the crystal plane (hkl) and the crystal direction [hkl] is A. [hkl]//(hkl) B. [hkl] is perpendicular to (hkl) C. No definite relationship", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查立方晶系中晶面(hkl)与晶向[hkl]关系的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生理解立方晶系中晶面与晶向的关系。虽然需要一定的晶体学基础知识，但题目仅涉及单一概念的直接应用（垂直关系），无需复杂分析或跨概念比较。相比等级1的直接记忆题稍难，但低于需要深度理解的等级3题目。" + }, + { + "idx": 3244, + "question": "Which of the following statements about dislocation loops is correct? A. A dislocation loop cannot be entirely edge dislocation everywhere. B. A dislocation loop can be entirely edge dislocation everywhere. C. A dislocation loop must simultaneously contain both edge dislocation and screw dislocation. D. A dislocation loop must simultaneously contain edge dislocation, screw dislocation, and mixed dislocation.", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择关于位错环的正确陈述，符合选择题的特征 | 知识层次: 题目考查对位错环基本概念的理解，属于对位错类型（刃型位错和螺型位错）及其在环状结构中分布情况的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解位错环的基本概念和类型，并能区分边缘位错和螺型位错的特征。虽然涉及概念辨析，但不需要复杂的分析步骤。" + }, + { + "idx": 3245, + "question": "The correct order of coordination numbers for the following alloy phases from small to large is A.SiC、NaCl、a-Fe、Cu B.a-Fe、SiC、Cu、NaClC.a-Fe、Cu、SiC、NaCl D.SiC、a=Fe、NaCl、Cu", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的配位数顺序，答案形式为选项A，符合选择题的特征。 | 知识层次: 题目考查对合金相配位数顺序的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目需要考生理解和辨析不同合金相的配位数概念，并进行排序比较。虽然涉及多个材料的配位数记忆，但属于基础概念的理解和简单应用，不需要复杂的分析或深度推理。因此属于中等难度（等级2）。" + }, + { + "idx": 3246, + "question": "Which of the following statements about zone melting is correct? A. For alloys with $K_{0}<1$, the solute is enriched at the end, and the beginning is purified; for alloys with $K_{0}>1$, the solute is enriched at the beginning, and the end is purified. B. For alloys with $K_{0}<1$, the solute is enriched at the beginning, and the end is purified; for alloys with $K_{0}>1$, the solute is enriched at the end, and the beginning is purified. C. Regardless of $K_{0}<1$ or $K_{0}>1$, the solute is enriched at the beginning. D. Regardless of $K_{0}<1$ or $K_{0}>1$, the solute is enriched at the end.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择关于区域熔炼的正确陈述，符合选择题的特征 | 知识层次: 题目考查对区域熔炼过程中溶质分布规律的理解和应用，需要掌握分配系数K0与溶质分布的关系，并进行综合分析。虽然涉及基础概念，但需要对不同K0值条件下的溶质分布进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解分区熔炼的基本原理，还需要掌握分配系数（K0）与溶质分布之间的关系。题目涉及两种不同情况（K0<1和K0>1）的综合分析，要求考生能够正确判断溶质在开始和结束位置的富集与纯化情况。这种多概念综合和复杂分析过程的判断使得该题目在选择题型中属于较难级别。" + }, + { + "idx": 3247, + "question": "Carburize industrial pure iron at 920°C. If the carbon concentration on the workpiece surface remains constant, i.e., w_C=1.2%, the diffusion coefficient D=1.5×10^-11 m^2/s, and carburize for 10h. If the carburized layer depth is defined as the distance from the surface to where the carbon mass fraction is 0.2%, find the carburized layer depth?", + "answer": "Substitute C_x=0.2 into the formula C_x=1.2[1-erf(6.8×10^2x)]. Referencing the error function table, Z≈6.8×10^2x=0.9784, the layer depth is x=0.00144m=1.44mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解渗碳层深度，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及扩散方程的数值计算和误差函数表的应用，需要多步计算和概念关联，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的应用、误差函数的使用以及多步骤计算过程。题目要求考生能够正确代入公式并查阅误差函数表，同时进行单位换算。虽然题目提供了明确的公式和参数，但解题过程涉及多个概念的综合运用和精确计算，属于综合性计算问题。" + }, + { + "idx": 3248, + "question": "Carburize industrial pure iron at 920°C. If the carbon concentration on the workpiece surface remains constant, i.e., w_C=1.2%, with a diffusion coefficient D=1.5×10^-11 m^2/s, and carburize for 10 hours. Determine the surface carbon concentration distribution?", + "answer": "Let the carburizing depth be x. Substituting C_0=0, C_s=1.2, D=1.5×10^-11 m^2/s, and t=36000s into the formula (C_s-C_x)/(C_s-C_0)=erf(x/(2√(Dt))), the surface carbon concentration distribution is obtained as C_x=1.2[1-erf(6.8×10^2x)].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如误差函数erf）来确定表面碳浓度分布，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及扩散方程的公式应用和数值计算，需要理解碳浓度分布的概念，并能够正确代入参数进行计算。虽然计算过程较为直接，但需要理解误差函数（erf）的应用和扩散系数的物理意义，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如扩散系数、碳浓度分布、误差函数等）并进行多步计算和综合分析。题目要求将给定的参数代入公式并正确理解误差函数的应用，涉及中等应用层次的知识点掌握和解题步骤。" + }, + { + "idx": 3249, + "question": "Please design an experimental plan to measure the recrystallization activation energy of a metal sheet cold-rolled by 75%.", + "answer": "Subject the cold-rolled specimen to isothermal recrystallization at different temperatures, and for each recrystallization temperature, determine the time t required to achieve a certain recrystallized volume fraction x_V. Since the recrystallization rate of cold-deformed metal V_rec ∝ 1/t = A′ e^(-Q_R/RT), take the logarithm of both sides: ln(1/t) = ln A′ - Q_R/RT The relationship between ln(1/t) and 1/T is linear. Plot this line using experimental data, and the slope of the line can be used to determine the recrystallization activation energy Q_R.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计一个实验计划来测量金属薄板的再结晶活化能，答案提供了详细的实验步骤和理论依据，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求设计实验方案来测量金属板材的再结晶激活能，涉及多步实验设计、数据分析和机理解释。需要综合运用材料科学中的再结晶理论、动力学分析以及实验技能，进行推理分析和综合运用。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅理解金属再结晶的基本概念，还需要掌握实验设计、数据处理和机理分析的综合能力。具体体现在：" + }, + { + "idx": 3250, + "question": "Describe the recovery mechanism at medium temperatures of 0.3~0.5Tm", + "answer": "At medium-temperature recovery of 0.3~0.5Tm, dislocations glide on slip planes, causing dislocations of opposite signs to meet and annihilate, reducing dislocation density, rearranging and recombining within dislocation tangles, and regularizing subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述中等温度下的恢复机制，答案是一段详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述中等温度下的回复机制，涉及位错的滑移、湮灭、重排和亚晶粒的规则化等复杂过程，需要综合运用位错理论、热激活过程和微观结构演变等知识进行机理分析和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解并综合运用材料科学中的位错理论、恢复机制以及温度对材料性能的影响等多个复杂概念。正确选项不仅描述了位错的滑移和湮灭过程，还涉及到位错密度的减少、位错缠结的重排和重组，以及亚晶粒的规则化等高级内容。这需要考生具备较强的推理分析能力和机理解释能力，能够将多个知识点有机结合起来进行综合判断。因此，在选择题型中，该题目的难度属于最高等级。" + }, + { + "idx": 3251, + "question": "Describe the recovery mechanisms at high temperatures above 0.5Tm", + "answer": "At high temperatures above 0.5Tm, in addition to dislocation slip, recovery can also occur through climb, with the primary mechanism being polygonization, forming low-angle grain boundaries. After polygonization, subgrain coalescence and growth still exist. Subgrain coalescence can be achieved through the movement of Y-nodes, which requires dislocation climb, slip, and cross-slip to accomplish.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述高温下的回复机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高温下（>0.5Tm）的回复机制，涉及位错攀移、多边形化、亚晶合并等多个复杂过程及其相互作用。需要综合运用位错理论、扩散机制和显微组织演变等知识进行机理层面的分析，属于需要深度理解和推理的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解高温恢复机制，包括位错攀移、多边形化、亚晶合并等复杂现象，并能够综合运用这些知识进行机理解释。这需要考生具备扎实的材料科学基础和高级分析能力，远超简单的概念记忆或单一知识点应用。" + }, + { + "idx": 3252, + "question": "Adding thorium oxide particles with a size of 10-50nm to nickel, after 40% rolling, the material exhibits high high-temperature strength. Explain the reason.", + "answer": "According to the recrystallization theory of two-phase alloys, if the second-phase particles are very fine (less than $0.3\\\\mu m$) and the spacing is small (less than $1\\\\:\\\\mu\\\\mathrm{m}$), the second-phase particles will inhibit the formation of recrystallization nuclei. In this case, the added second-phase particles are smaller than $0.3\\\\mu m$, so adding a certain volume fraction of thorium oxide can improve high-temperature performance. This is because before the formation of recrystallization nuclei, the growth of sub-nuclei encounters the obstruction of second-phase particles, inhibiting the formation of recrystallization nuclei and preventing recrystallization from occurring, so that recrystallization does not occur even before melting. Therefore, during high-temperature operation, the dislocation density remains high, resulting in high deformation resistance. Additionally, thorium oxide particles hinder the movement of dislocations, increasing the resistance to plastic deformation, thereby enhancing high-temperature performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释添加氧化钍颗粒后材料表现出高温强度的原因，答案通过理论分析和文字论述进行详细解释，符合简答题的特征。 | 知识层次: 题目要求解释纳米级氧化钍颗粒增强镍基合金高温强度的机理，涉及多相合金再结晶理论、位错运动阻碍、亚晶核形成抑制等复杂概念的综合运用和推理分析。需要深入理解第二相粒子尺寸和间距对再结晶过程的抑制作用，以及位错密度与高温强度的关系，属于对材料强化机制的深度解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解两相合金的再结晶理论，还需要综合运用纳米颗粒尺寸效应、位错运动机制以及高温性能提升的复杂机理。正确选项涉及多个深层次的材料科学概念（如再结晶核形成抑制、位错密度保持、塑性变形阻力增加等），并要求将这些概念串联起来进行推理分析。此外，题目还要求考生能够将理论知识与具体材料加工工艺（40%轧制）和性能表现（高温强度）联系起来，这需要非常全面和深入的理解能力。在选择题型中，这种需要多步骤复杂推理和机理深度解释的题目属于最高难度级别。" + }, + { + "idx": 3253, + "question": "For an Fe-3% (Si) alloy containing MnS particles, when the particle radius is $0.05\\\\mu m$ and the volume fraction is approximately 1%, annealing below 850℃ results in the cessation of normal grain growth when the average grain diameter of the matrix is $6\\\\mu m$. Analyze the reason for this phenomenon.", + "answer": "According to the formula for calculating the limiting average grain size: $$\\\\overline{{D}}_{\\\\mathrm{lim}}=\\\\frac{4r}{3\\\\varphi}=\\\\frac{4\\\\times0.05}{3\\\\times0.01}=6.7~\\\\mu\\\\mathrm{m}$$ The dispersed particles exert a pinning effect on grain boundary migration. When the driving force for grain boundary migration provided by grain boundary energy equals the resistance to grain boundary migration caused by the dispersed particles, the limiting grain size is reached. Further holding does not increase the grain size, as calculated by $\\\\overline{{D}}_{\\\\mathrm{lim}}=6.7~\\\\mu m$. During annealing, the average matrix diameter is 6 μm, which is already close to $\\\\overline{{D}}_{\\\\mathrm{lim}}$, so grain growth becomes extremely slow and nearly stops.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析现象的原因，答案提供了详细的文字解释和论述，包括公式应用和理论分析，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的晶粒生长理论、第二相粒子钉扎效应以及相关公式计算，进行推理分析和机理解释。涉及多步计算和概念关联，思维过程要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用材料科学中的晶粒生长理论、第二相粒子钉扎效应以及相关计算公式，进行复杂的推理分析和机理解释。具体来说，考生需要：" + }, + { + "idx": 3254, + "question": "What are the conditions for the occurrence of secondary recrystallization?", + "answer": "The conditions for abnormal grain growth are that normal grain growth is strongly hindered by dispersed phase particles, texture, surface energy grooves, etc., and the number of grains that can grow is small, resulting in a significant difference in grain size, which leads to abnormal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述二次再结晶发生的条件，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释二次再结晶发生的条件，涉及异常晶粒生长的机理和影响因素，需要综合分析分散相颗粒、织构、表面能沟槽等多因素对晶粒生长的阻碍作用，以及晶粒尺寸差异导致的异常生长过程。这需要深入理解材料科学中的再结晶理论，并进行机理层面的解释和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解二次再结晶的基本概念，还需要综合运用多个复杂条件（如分散相颗粒阻碍、织构、表面能沟槽等）来分析异常晶粒生长的机理。正确选项涉及对材料科学中复杂现象（异常晶粒生长）的全面分析，需要考生具备深入的知识掌握和推理能力，能够解释多种因素如何共同作用导致特定现象。这种题目在选择题型中属于对知识深度和综合分析能力要求极高的类型。" + }, + { + "idx": 3255, + "question": "What is called secondary recrystallization?", + "answer": "The growth of grains after recrystallization is further divided into normal growth and abnormal growth. The abnormal growth of grains is also called discontinuous growth or secondary recrystallization. Secondary recrystallization is a special mode of grain growth where the growth of most grains in the matrix is suppressed, while a few grains grow rapidly, significantly increasing the size difference between grains until these rapidly growing grains come into complete contact with each other.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary recrystallization\"进行定义和解释，需要文字论述，答案也是详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶这一基本概念的定义和解释，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解并记忆\"二次再结晶\"的定义及其在晶粒生长中的分类（异常生长或不连续生长）。虽然涉及多个概念（正常生长、异常生长、二次再结晶），但主要是对基础概念的定义和描述，不需要进行复杂的比较分析或推导。因此，在选择题型中属于概念解释和描述层次的难度。" + }, + { + "idx": 3256, + "question": "Describe the recovery mechanism at low temperatures of 0.1~0.3Tm", + "answer": "Recovery at 0.1~0.3Tm low temperatures primarily involves the movement of point defects, where vacancies and interstitial atoms migrate to grain boundaries or dislocations and annihilate, the recombination of vacancies and interstitial atoms, and the aggregation of vacancies to form vacancy pairs or vacancy clusters, leading to a significant reduction in point defect density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述低温下的恢复机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释低温下的回复机制，涉及点缺陷的迁移、湮灭和聚集等微观过程，需要综合运用材料科学中的缺陷理论和热力学知识，进行机理层面的分析和解释。这超出了简单记忆或基本应用的范畴，属于需要深入理解和综合分析的内容。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求对低温恢复机制进行全面的机理解释，涉及点缺陷（空位和间隙原子）的迁移、复合以及聚集形成空位对或空位团簇等复杂现象的综合分析。这不仅需要深入理解材料科学中的缺陷理论，还需要能够将这些概念综合运用来解释具体的恢复过程。此外，题目还要求对温度范围（0.1~0.3Tm）的影响有清晰的认识，进一步增加了题目的复杂性和难度。因此，在选择题型中，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 3257, + "question": "After high-temperature recovery, several edge dislocations form a subgrain boundary with a misorientation of $0.057^{\\\\circ}$. Assuming there is no interaction between these dislocations, what is the ratio of the distortion energy after forming the subgrain to the original energy? (Given the core radius of the dislocation $r_{0}\\\\approx$ $b\\\\approx10^{-8}\\\\mathrm{cm}$, and the effective radius of the dislocation stress field before forming the subgrain $R=10^{-4}\\\\mathrm{cm}$.)", + "answer": "Given the core radius of the dislocation $r_{0}=b\\\\approx10^{-8}~\\\\mathrm{cm}$ and the effective radius of the dislocation stress field $R=10^{-4}$ $\\\\mathrm{{cm}}$, since the total length of dislocations remains unchanged before and after forming the subgrain, the ratio of the energy per unit dislocation line before and after forming the subgrain is equal to the ratio of the energy before and after polygonization. The energy per unit dislocation line is $$ W_{E}=\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}\\\\ln\\\\frac{R}{r_{0}}=\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}\\\\ln10^{4} $$ After polygonization, the edge dislocations are arranged perpendicular to the slip plane with a spacing of $D$, so the effective radius of the dislocation $R$ becomes $D$. From the formula $R=D=\\\\frac{b}{\\\\theta}=\\\\frac{10^{-8}}{10^{-3}}=10^{-5}$, the energy per unit dislocation line after polygonization is $$ W_{E}^{\\\\prime}={\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}}\\\\cdot\\\\ln{\\\\frac{10^{-5}}{10^{-8}}}={\\\\frac{G b^{2}}{4\\\\pi(1-\\\\nu)}}\\\\cdot\\\\ln10^{3} $$ $$ \\\\frac{W_{E}^{\\\\prime}}{W_{E}}=\\\\frac{\\\\ln{10^{3}}}{\\\\ln{10^{4}}}=\\\\frac{3}{4} $$ This shows that after polygonization, the dislocation energy decreases, reducing the stored energy and also the driving force for recrystallization.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解变形能量比，解答过程中涉及到了具体的数学运算和公式推导，最终得出一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错能量公式的应用，并综合运用位错间距与取向差的关系进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来推导能量比。 | 难度: 在选择题中属于中等偏上难度，需要理解位错能量计算、多边形化过程以及能量比值的推导。题目涉及多步骤计算（包括对数运算和单位转换）和多个材料科学概念的关联（位错应力场、多边形化、存储能量变化）。虽然提供了关键公式和参数，但需要考生综合运用这些信息进行推导，属于典型的综合性计算问题。" + }, + { + "idx": 3258, + "question": "Given that brass with a zinc mass fraction of 30% takes 1 hour to complete recrystallization at a constant temperature of 400°C, and 2 hours at 390°C, calculate how much time is needed to complete recrystallization at a constant temperature of 420°C.", + "answer": "Recrystallization of cold-deformed metal is also a thermally activated process, and the recrystallization rate follows the Arrhenius equation $$ V_{\\overline{{\\{\\}}}}=A^{\\prime}\\cdot\\mathrm{e}^{-Q/R T} $$ Since $V_{\\overrightarrow{\\vert\\overrightarrow{\\vert\\cdot}\\vert}}$ is inversely proportional to the time $\\scriptstyle t$ required to achieve a certain volume fraction $x_{\\upsilon}$, i.e., $V_{\\mathrm{\\#}}\\propto1/t$, we have $$ \\frac{1}{t_{1}}=A\\mathrm{e}^{-\\frac{Q}{R T_{1}}};\\frac{1}{t_{2}}=A\\mathrm{e}^{-\\frac{Q}{R T_{2}}};\\frac{1}{t_{3}}=A\\mathrm{e}^{-\\frac{Q}{R T_{3}}} $$ From the above three equations, dividing them pairwise yields $$ \\frac{t_{2}}{t_{1}}=\\mathrm{e}^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{2}}\\right)};\\quad\\frac{t_{3}}{t_{1}}=\\mathrm{e}^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{3}}\\right)} $$ Taking the natural logarithm and then dividing gives $$ \\frac{\\ln(t_{2}/t_{1})}{\\ln(t_{3}/t_{1})}=\\frac{1/T_{1}-1/T_{2}}{1/T_{1}-1/T_{3}} $$ Substituting $T_{1}=673~\\mathrm{K},t_{1}=1~\\mathrm{h};~T_{2}=663~\\mathrm{K},t_{2}=2~\\mathrm{h};~T_{3}=693~\\mathrm{K}$ into the above equation, we obtain $t_{3}=0.27$ h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来解决具体问题，答案给出了详细的计算过程和最终的时间结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用Arrhenius方程进行推导和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解Arrhenius方程及其在再结晶过程中的应用，进行多步计算和温度转换（摄氏到开尔文），并正确运用对数运算来求解时间。虽然题目提供了必要的公式和数据，但解题步骤较为复杂，涉及多个概念的综合运用和计算。" + }, + { + "idx": 3259, + "question": "How to prolong the lifespan of tungsten filaments by adding second-phase particles?", + "answer": "Finely dispersed high-melting-point second-phase particles can be added to the tungsten filaments. The second phase can effectively hinder grain growth, with the limiting grain size Dlim=4r/3f. When the particle size r is smaller and the volume fraction f of the added particles is larger, the limiting grain size becomes smaller, preventing the formation of large grains that span the filament. This mitigates grain boundary weakening at high temperatures, thereby preventing brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过添加第二相颗粒来延长钨丝寿命，答案提供了详细的文字解释和论述，包括作用机制和影响因素，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释如何通过添加第二相颗粒来延长钨丝寿命，涉及多步推理和机理解释，包括第二相颗粒对晶粒生长的阻碍作用、限制晶粒尺寸的计算公式及其影响因素，以及高温下晶界弱化的防止机制。这需要综合运用材料科学知识进行深入分析和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解钨丝寿命延长的基本原理（第二相粒子的添加），还需要掌握复杂的机理分析（晶粒生长限制公式Dlim=4r/3f）及其对材料性能的影响。解题需要综合运用多个高阶概念（晶粒尺寸控制、高温晶界弱化、脆性断裂预防），并进行定量关系推理（粒子尺寸r和体积分数f的影响）。这种深度机理解释和复杂现象分析的要求，明显超出了选择题型的常规难度水平，属于需要全面理解和综合分析能力的最高难度题目。" + }, + { + "idx": 3260, + "question": "A factory was conducting solution treatment on the jaw plates of a crusher made of high manganese steel. After heating at 1100°C, the plates were suspended with cold-drawn steel wires and transported by a crane to the quenching water tank. During transportation, the steel wire suddenly broke. This wire was new and had no defects. Analyze the cause of the steel wire fracture.", + "answer": "Due to work hardening, the cold-drawn steel wire has high strength and strong load-bearing capacity. However, when heated by the red-hot jaw plate, once the temperature rises above $T_{\\overrightarrow{\\mathbb{H}}}$, recrystallization occurs, causing a decrease in strength. As a result, the wire can no longer bear the weight of the jaw plate, leading to fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢线断裂的原因，答案提供了详细的文字解释和论述，涉及材料科学中的工作硬化和再结晶现象，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要综合运用材料科学中的相变、热处理和力学性能等知识，分析冷拉钢丝在高温条件下的性能变化及其断裂原因。涉及多个概念的关联和推理分析，思维过程较为深入。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3261, + "question": "What is superplasticity?", + "answer": "When metallic materials are stretched under certain conditions, their elongation can reach over 200%, or even exceed 1000%. This property is called superplasticity. During superplastic deformation, the true stress-true strain conforms to the relation: σT(εT,T)=C·ε̇T^m, where m is called the strain rate sensitivity constant. When m=0.3-0.8, the material can exhibit superplasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"superplasticity\"这一概念进行文字解释和论述，答案提供了详细的定义和相关公式说明，符合简答题的特征。 | 知识层次: 题目主要考查对超塑性这一基本概念的定义和简单描述，涉及记忆和理解层面，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆超塑性的定义及其基本特征，包括伸长率范围和应变速率敏感性常数的关系。虽然涉及一些公式和参数，但整体上仍属于对基础概念的描述，不需要复杂的分析或比较。" + }, + { + "idx": 3262, + "question": "How to extend the life of tungsten wire by adding oxides of potassium, aluminum, silicon, etc.?", + "answer": "Adding oxides of potassium, aluminum, silicon, etc., which vaporize during sintering to form bubbles. During processing, these bubbles elongate along the direction of processing. These small bubbles distributed along the axial direction can also act as obstacles to grain boundary migration, allowing grains to grow only parallel to the axis of the tungsten wire. This results in elongated large grains along the axis, preventing the formation of large grains that span the cross-section of the tungsten wire, thereby improving high-temperature performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过添加氧化物来延长钨丝的寿命，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释通过添加氧化物延长钨丝寿命的机理，涉及多步过程（烧结气泡形成、晶界迁移阻碍、晶粒定向生长等）的综合分析和机理解释，需要深入理解材料微观结构与性能的关系，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解添加氧化物对钨丝寿命的影响，还需要掌握烧结过程中气泡形成、晶界迁移阻碍、晶粒生长方向控制等复杂机理。正确选项涉及多步骤推理和跨学科知识整合（材料科学、热力学、晶体学），需要考生具备将微观结构演变与宏观性能提升相关联的高级分析能力。这种在选择题中要求全面解释复杂现象并推导性能改善机制的题目，对知识深度和逻辑推理能力的要求远超常规选择题。" + }, + { + "idx": 3263, + "question": "How to achieve superplasticity?", + "answer": "Superplasticity can be divided into three categories: structural superplasticity, transformation superplasticity, and other types of superplasticity. Structural superplasticity should meet three conditions: (1) Ultra-fine, equiaxed, and stable grains, with grain size generally not exceeding 10μm. (2) Deformation temperature is typically in the range of (0.5∼0.7)Tm. (3) A certain strain rate, with the optimal superplastic deformation rate being 10^-4∼10^-2s^-1 or 10^-3∼10^-2min^-1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何实现超塑性，答案提供了详细的文字解释和论述，包括超塑性的分类和实现条件，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释超塑性的实现条件，涉及多个条件的综合分析和概念关联，需要理解超塑性的分类和具体实现条件，并进行一定的综合分析。 | 难度: 在选择题型中，该题目要求考生不仅掌握超塑性的基本分类（结构超塑性、相变超塑性等），还需要理解实现结构超塑性的三个具体条件（晶粒尺寸、变形温度、应变速率）。这涉及多步概念关联和综合分析，属于较高层次的应用题。虽然不涉及计算，但需要对材料科学中的专业术语和条件有较深的理解，因此在选择题中属于较难级别（等级4）。" + }, + { + "idx": 3264, + "question": "As an economic measure, using pure lead instead of lead-tin alloy to make solder for brazing iron, how is the wettability of pure lead on iron?", + "answer": "The wettability of pure lead on iron is poor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释纯铅在铁上的润湿性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对纯铅在铁上润湿性的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或推理。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对纯铅在铁上润湿性的基础概念记忆，不需要解释或分析过程，只需回忆\"纯铅润湿性差\"这一基本事实即可作答。正确选项直接给出了定义性结论，没有涉及概念比较或复杂推理过程。" + }, + { + "idx": 3265, + "question": "As an economic measure, using pure lead instead of lead-tin alloy to make solder for brazing iron, how does the melting point of pure lead compare to that of lead-tin alloy?", + "answer": "The melting point of pure lead is higher than that of Sn-Pb alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释纯铅和铅锡合金的熔点比较，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对纯铅和铅锡合金熔点差异的基本概念记忆，属于基础概念层次，无需复杂分析或推理。 | 难度: 该题目属于基础概念记忆类型，仅需回忆纯铅和铅锡合金的熔点比较这一基本事实。选择题型中正确选项直接给出了明确结论，无需复杂推理或概念间的关联分析，属于最基础的定义简答级别。" + }, + { + "idx": 3270, + "question": "What factors constitute the resistance to phase transformation?", + "answer": "The resistance to phase transformation consists of strain energy and interface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释影响相变阻力的因素，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对相变阻力构成因素的基本概念记忆和理解，涉及的是定义和基本原理等记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接询问相变阻力的构成因素，正确选项明确给出了两个基本概念（应变能和界面能），不需要进行额外的解释或复杂分析。这属于最基础的概念记忆题，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3272, + "question": "What are the main characteristics of diffusion-type phase transformations?", + "answer": "The fundamental characteristics of diffusion-type phase transformations are: $\\textcircled{1}$ Atomic diffusion occurs during the phase transformation, and the transformation rate is controlled by diffusion, i.e., determined by the diffusion speed. $\\textcircled{2}$ In alloy phase transformations, the compositions of the new phase and the parent phase are often different. $\\textcircled{3}$ There is only volume change caused by the difference in specific volume between the new phase and the parent phase, with no shape alteration. Phase transformations such as allotropic transformation in pure metals, polymorphic transformation in solid solutions, precipitation transformation, eutectoid transformation, spinodal decomposition, and ordering transformation all belong to diffusion-type phase transformations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散型相变的主要特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查扩散型相变的基本特征，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于较高难度，题目要求掌握扩散型相变的基本特征，并理解多个相关概念（如原子扩散、相变速率控制、新相与母相成分差异、体积变化等）。此外，还需要将这些概念整合成一个完整的体系进行阐述，涉及的知识点较多且需要深入理解。" + }, + { + "idx": 3273, + "question": "Explain the influence of crystal defects on the nucleation of solid-state phase transformations in metals.", + "answer": "During solid-state phase transformations, various crystal defects present in the parent phase, such as grain boundaries, dislocations, and vacancies, significantly promote the transformation. The new phase often preferentially nucleates at defect sites, and crystal defects have a substantial impact on processes such as nucleus growth and component diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体缺陷对固态相变成核的影响，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求解释晶体缺陷对固态相变形核的影响，涉及对晶体缺陷类型及其作用的深入理解，以及它们如何促进新相形核的机理分析。这需要综合运用材料科学中的相变理论和缺陷理论，进行推理和解释，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解晶体缺陷对固态相变成核的影响机制，涉及多个复杂概念的综合运用（如晶界、位错、空位等缺陷类型的作用），并需要推理分析这些缺陷如何促进新相成核及影响后续生长和扩散过程。这种深度机理解释和复杂现象全面分析的要求，远超选择题型的常规知识记忆或简单应用层次，属于需要高阶思维能力的题目类型。" + }, + { + "idx": 3274, + "question": "What is the actual grain size of austenite?", + "answer": "The size of austenite grains obtained under a specific heat treatment condition is generally referred to as the actual grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"actual grain size of austenite\"进行文字解释和论述，答案提供了概念性的说明而非选择、判断或计算。 | 知识层次: 题目考查对奥氏体实际晶粒尺寸这一基本概念的记忆和理解，属于材料科学中的基础概念知识，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅需识别和回忆\"实际晶粒尺寸\"的定义。选择题型中正确选项直接给出了明确答案，无需复杂推理或概念比较，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3275, + "question": "What is the reason for the formation of a 'precipitate-free zone' near grain boundaries in age-hardening alloys?", + "answer": "In the case of the decomposition of a supersaturated solid solution, when rapidly cooled from a high temperature, along with the solute atoms being supersaturatedly retained in the solid solution, a large number of supersaturated vacancies are also retained. These vacancies, on one hand, promote the diffusion of solute atoms and, on the other hand, act as nucleation sites for precipitates, facilitating heterogeneous nucleation and causing the precipitates to disperse throughout the matrix. When observing the distribution of precipitates in age-hardening alloys, a 'precipitate-free zone' is often seen near grain boundaries, where no precipitates are visible. This is because the supersaturated vacancies near the grain boundaries diffuse to the grain boundaries and disappear, so no heterogeneous nucleation or precipitation occurs in this region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释“precipitate-free zone”形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释\"precipitate-free zone\"的形成原因，涉及多个材料科学概念的关联和综合分析，包括固溶体的分解、过饱和空位的作用、异质成核机制以及晶界对空位扩散的影响。需要深入理解这些概念之间的相互作用，并进行推理分析来解释现象。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解基本的沉淀硬化机制，还需要综合运用多个复杂概念（如过饱和空位、异质形核、晶界扩散等）进行机理深度解释。正确选项涉及多步骤推理分析，包括：" + }, + { + "idx": 3276, + "question": "What is the reason for the appearance of transition phases during the solid-state phase transformation of metals?", + "answer": "During solid-state phase transformations, metastable phases often form first to reduce surface energy, thus frequently resulting in transition phases. For example, when the undercooling is significant, the critical size for the formation of the new phase is very small, and the new phase per unit volume has a large surface area, so the interfacial energy poses a substantial barrier to nucleation. In such cases, transition phases with low interfacial energy and coherent interfaces are more likely to form to reduce the nucleation work and facilitate nucleation. An example is the ε-carbide in lower bainite in steel, which forms a coherent interface with the matrix. During the tempering of martensite in steel, to reduce the interfacial energy generated by carbide formation, ε-carbide, which is coherent with the martensite, forms as a transition phase at lower tempering temperatures. As the tempering temperature increases, the value of ΔG_B rises, and cementite, which is incoherent with the matrix, gradually forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属固态相变过程中过渡相出现的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释固态相变过程中过渡相出现的机理，涉及多个概念的关联和综合分析，如表面能、临界尺寸、界面能、形核功等。需要深入理解相变过程中的能量变化和动力学因素，并结合具体实例（如钢中的ε-碳化物）进行解释。这属于对复杂现象的分析和机理解释，超出了简单记忆或基本应用的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解金属固态相变中的过渡相形成机理，包括表面能、形核功、界面能等复杂概念的综合运用。正确选项不仅需要掌握相变热力学和动力学知识，还需要能够将这些原理与具体实例（如钢中的ε-碳化物）联系起来进行推理分析。这种深度机理解释和复杂现象分析的要求，在选择题型中属于最具挑战性的类型。" + }, + { + "idx": 3277, + "question": "What is the initial grain size of austenite?", + "answer": "In the heating transformation, when the transformation from pearlite to austenite has just been completed, the size of the austenite grains is called the initial grain size of austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"initial grain size of austenite\"进行文字解释和定义，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对奥氏体初始晶粒尺寸这一基本概念的定义和记忆，属于材料科学中相变基础知识的范畴，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需考生回忆并识别\"初始奥氏体晶粒尺寸\"的定义。在选择题型中，正确选项直接给出了完整定义，无需任何推理或分析过程，属于最简单的定义简答级别。题目仅测试单一知识点的记忆能力，符合等级1的基本特征。" + }, + { + "idx": 3278, + "question": "Describe the formation process of austenite", + "answer": "Austenite formation process: a) Formation of austenite nuclei; b) Growth of austenite nuclei; c) Dissolution of residual cementite; d) Homogenization of austenite composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述奥氏体的形成过程，答案提供了详细的步骤解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求描述奥氏体的形成过程，涉及多个步骤（形核、生长、残余渗碳体溶解、成分均匀化），需要理解相变机理并关联不同阶段的变化，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求描述奥氏体的形成过程，涉及多个步骤（成核、生长、残余渗碳体溶解、成分均匀化），需要考生掌握这些概念并能正确排序和关联。虽然选项提供了明确的步骤，但仍需综合分析各步骤之间的关系和顺序，属于中等应用层次的知识要求。" + }, + { + "idx": 3280, + "question": "What is the inherent grain size of austenite?", + "answer": "According to the former national metallurgical industry standard, the grain size measured after heating the steel to 930°C ± 10°C, holding for 8 hours, and then cooling is called the inherent grain size. This grain size is used to indicate the tendency of austenite grain growth during heating.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"inherent grain size of austenite\"进行解释说明，答案提供了详细的定义和测量方法，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对固有晶粒尺寸这一基本概念的记忆和理解，涉及标准测试方法和定义，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然题目涉及具体的温度和时间参数（930°C ± 10°C，8小时），但核心是考察对\"固有晶粒度\"这一基础概念的定义记忆。正确选项直接给出了标准定义和测试方法，不需要进行比较分析或推导。属于概念解释和描述层级，但相比纯定义记忆题（等级1）需要掌握更多细节参数。" + }, + { + "idx": 3281, + "question": "Compare the differences in the microstructure transformation zones between the CCT diagram and TTT diagram of eutectoid carbon steel.", + "answer": "The CCT diagram of eutectoid carbon steel only has the high-temperature pearlite transformation zone and the low-temperature martensite transformation zone, without the intermediate-temperature bainite transformation zone. In the CCT diagram, the Ps curve (pearlite start transformation line) and Pf curve (pearlite finish transformation line) shift to the lower right.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较和分析两种相变图的微观结构转变区域差异，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求比较CCT图和TTT图中微观结构转变区的差异，涉及对两种相图的理解和应用，需要综合分析不同温度区域的转变特点以及曲线位置的变化。这需要一定的概念关联和多步分析能力，但不需要进行复杂的机理推理或创新设计。 | 难度: 在选择题型中，该题目要求考生不仅理解CCT和TTT图的基本概念，还需要对两者的微观结构转变区域进行多角度比较分析。题目涉及高温珠光体转变区、低温马氏体转变区以及中温贝氏体转变区的差异，同时需要掌握Ps和Pf曲线的移动规律。这种综合分析能力在选择题型中属于较高难度，需要考生具备较强的概念关联和综合分析能力。" + }, + { + "idx": 3282, + "question": "Why is the activation energy for atoms crossing an incoherent interface much smaller than that for crossing a semicoherent interface?", + "answer": "$u=\\delta V_{0}\\mathrm{exp}\\big(-\\Delta\\mathrm{G/kT}\\big)$. For an incoherent interface, the $\\Delta G$ value equals the activation energy for grain boundary diffusion; whereas for a semicoherent interface, it can be considered roughly equal to the activation energy of atoms in the $\\beta$ phase (actually slightly smaller). Therefore, the activation energy for atoms crossing an incoherent interface is much smaller than that for crossing a semicoherent interface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么非共格界面的原子跨越激活能比半共格界面小，需要文字论述和解释。答案提供了详细的解释和公式支持，符合简答题的特征。 | 知识层次: 题目需要解释原子跨越非共格界面和半共格界面的激活能差异，涉及扩散激活能、界面结构和能量状态等复杂概念的综合分析和推理。答案中引用了公式并对比了不同界面的ΔG值，体现了对机理的深入理解和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解界面能量和扩散机理，并能够综合运用热力学和动力学知识进行推理分析。正确选项涉及复杂的公式推导和概念比较（如非共格界面与半共格界面的激活能差异），需要考生具备将抽象理论转化为具体解释的能力。这种题目在选择题型中属于需要全面分析复杂现象的典型代表，远超基础概念题和简单计算题的难度水平。" + }, + { + "idx": 3283, + "question": "What is the significance of the TTT diagram for eutectoid carbon steel in practical heat treatment?", + "answer": "The isothermal transformation C-curve (TTT curve) can determine the process parameters during isothermal heat treatment of steel, namely the isothermal temperature, isothermal time, and the microstructure after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释TTT图的实际意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释TTT图在实际热处理中的意义，涉及对等温热处理过程参数（温度、时间）和最终组织的综合分析，需要将理论知识与实际应用相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解TTT图的基本概念及其在热处理中的应用，并能将多个概念（如等温温度、时间和显微组织）关联起来进行综合分析。虽然不涉及复杂的计算，但需要对材料科学中的基本原理有较好的掌握。" + }, + { + "idx": 3284, + "question": "Methods for controlling austenite grain size", + "answer": "Methods for controlling austenite grain size: a) Establish appropriate heating specifications, including controlling heating temperature and holding time, rapid short-term heating; b) Control carbon content within a certain range and add a certain amount of alloying elements that hinder austenite grain growth, such as: Al, V, Ti, Zr, Nb, etc.; c) Consider the influence of the original microstructure, such as lamellar pearlite being more prone to coarsening than spheroidized pearlite during heating.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释控制奥氏体晶粒尺寸的方法，答案提供了详细的文字解释和论述，没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目要求解释控制奥氏体晶粒尺寸的方法，涉及加热规范、合金元素添加和原始组织影响等多个方面的知识。需要综合理解和应用材料科学中的基本原理，并进行一定的分析和关联，但不需要过于复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及控制奥氏体晶粒尺寸的多种方法，包括加热规范、碳含量和合金元素的影响以及原始组织的影响。虽然不需要复杂的计算，但需要对材料科学中的相关概念有较深的理解，并能综合分析不同因素对奥氏体晶粒尺寸的影响。" + }, + { + "idx": 3285, + "question": "Under what conditions can austenite transform into lamellar pearlite?", + "answer": "When the austenitizing temperature is high, the holding time is long, the composition of austenite is uniform, and the cooling rate is fast, lamellar pearlite is prone to form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在什么条件下奥氏体可以转变为层状珠光体，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释奥氏体转变为层状珠光体的条件，涉及多个因素（温度、时间、成分均匀性、冷却速率）的综合分析，需要理解相变原理并关联实际工艺条件，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅掌握奥氏体向层状珠光体转变的基本条件，还需要综合分析多个因素（奥氏体化温度、保温时间、成分均匀性和冷却速率）之间的相互作用。这种多因素关联分析在选择题中属于较复杂的思维过程，需要考生具备较强的概念整合能力和综合分析能力，因此属于等级4难度。" + }, + { + "idx": 3286, + "question": "What is pearlite interlamellar spacing?", + "answer": "The distance between the centers of two adjacent cementite (or ferrite) plates in lamellar pearlite, or the total thickness of a pair of ferrite and cementite plates, is called pearlite interlamellar spacing, denoted as S0.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对专业术语进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即珠光体层间距的定义和表示方法，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆珍珠岩层间距的定义，即相邻两个渗碳体（或铁素体）板中心之间的距离或一对铁素体和渗碳体板的总厚度。虽然需要记忆具体定义，但不需要进行复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 3287, + "question": "What are the main characteristics of diffusionless phase transformations?", + "answer": "Characteristics of diffusionless phase transformations: $\\textcircled{1}$ There is a shape change caused by uniform shear, as the atoms undergo collective coordinated motion during the phase transformation, resulting in a change in the crystal's external shape. If a polished specimen surface is prepared in advance, a relief effect will appear on the polished surface after this transformation occurs. The presence of this relief can be observed under a metallographic microscope. $\\textcircled{2}$ The phase transformation does not require diffusion, and the chemical composition of the new phase is the same as that of the parent phase. $\\textcircled{3}$ There is a specific crystallographic orientation relationship between the new phase and the parent phase. $\\textcircled{4}$ The phase boundary moves extremely fast, approaching the speed of sound. The martensitic transformation in steel and some alloys (Fe-Ni, Cu-Al, Ni-Ti) is a diffusionless phase transformation. Some pure metals (such as zirconium, titanium, lithium, cobalt) also undergo diffusionless phase transformations during allotropic transformations at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释扩散无相变的主要特征，答案以文字论述的形式详细列出了多个特征点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释扩散型相变的主要特征，涉及多个特征点的描述和关联，需要理解相变过程中的原子运动、晶体结构变化、化学成分保持等概念，并进行综合分析。虽然不涉及复杂计算或深度推理，但需要将多个知识点关联起来进行解释，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 3288, + "question": "What is martensite?", + "answer": "The supersaturated solid solution formed by carbon in α-Fe is called martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"martensite\"进行定义解释，需要文字描述而非选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即马氏体的定义，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察对马氏体基本定义的记忆，属于最基础的概念性知识。正确选项直接给出了马氏体的定义，不需要进行任何概念解释或复杂分析，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3289, + "question": "What is the significance of the CCT diagram of eutectoid carbon steel in practical heat treatment?", + "answer": "The CCT curve can determine the heat treatment process parameters of steel during continuous cooling, such as the critical quenching cooling rate, quenching medium, and microstructure after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释CCT图在实际热处理中的意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释CCT图在实际热处理中的意义，涉及对CCT图的理解和应用，需要将理论知识与实际热处理工艺参数（如临界淬火冷却速率、淬火介质和热处理后的显微组织）联系起来，属于中等应用层次。这不仅仅是对基础概念的简单记忆，而是需要一定的分析和综合能力来理解和应用CCT图的信息。 | 难度: 在选择题中属于中等难度，需要理解CCT图的基本概念及其在热处理中的实际应用，并能将多个概念（如临界淬火冷却速率、淬火介质和热处理后的显微组织）进行关联分析。虽然题目涉及多步计算和综合分析，但在选择题型中，正确选项已经提供了明确的关联性分析，因此难度属于等级3。" + }, + { + "idx": 3290, + "question": "What is the effect of pearlite interlamellar spacing and pearlite colonies on mechanical properties?", + "answer": "The lower the formation temperature, the smaller the size of pearlite colonies and interlamellar spacing, the finer the pearlite structure, and the higher the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释珠光体层间距和珠光体团对机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解珠光体层间距和珠光体团对力学性能的影响，并能够分析温度变化对微观结构的影响及其与强度的关系。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解珠光体层间距和珠光体团对力学性能的影响，并综合分析温度、尺寸和强度之间的关系。虽然涉及多个概念，但在选择题型中通过选项可以辅助判断，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3291, + "question": "What are the main characteristics of various types of solid-state phase transformations in metals?", + "answer": "
Classification of solid-state phase transformationsCharacteristics of phase transformations
Allotropic transformation in pure metalsChanges from one crystal structure to another with temperature or pressure variation, involving nucleation and growth processes
Polymorphic transformation in solid solutionsSimilar to allotropic transformation, such as Y in Fe-Ni alloys
Precipitation transformationDecomposition of supersaturated solid solutions, precipitating metastable or stable secondary phases
Eutectoid transformationA single phase decomposes into two phases with different structures through eutectoid transformation, such as Y→α+FeC in Fe-C alloys
Peritectoid transformationTwo phases with different structures transform into another phase through peritectoid transformation, such as α+Y→β in Ag-Al alloys, often leaving residual α phase
Martensitic transformationNo change in composition between the new and old phases during transformation; atoms undergo coordinated rearrangement (shear) without diffusion, maintaining strict orientation relationships and coherency, with surface relief effects observable on polished surfaces
Massive transformationChanges in crystal structure of metals or alloys without composition change between new and old phases, characterized by nucleation and growth with minimal diffusion, rapid growth via incoherent interface migration, producing irregular massive products, as seen in pure iron, low-carbon steel, Cu-Al alloys, and Cu-Ga alloys
Bainitic transformationOccurs in steel and many non-ferrous alloys, combining features of martensitic and diffusional transformations, resulting in composition changes; in steel, bainitic transformation is considered to proceed via coherent shear of iron atoms and diffusion of carbon atoms
Spinodal decompositionA non-nucleation decomposition process where a solid solution decomposes into two phases with the same crystal structure but different compositions (continuously varying within a certain range)
Order-disorder transformationTransition of alloy elements from random to ordered arrangement without structural change
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释各种固态相变的主要特征，答案以表格形式详细列出了不同类型相变的分类和特征，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求对不同类型的固态相变进行分类并描述其主要特征，这需要理解各种相变的基本原理和特点，并进行一定的综合分析。虽然涉及记忆性知识，但更强调对概念的理解和关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握多种固态相变的基本概念，还需要理解每种相变的具体特征和区别。题目涉及的知识点较多，包括多种相变类型的分类和详细描述，需要考生具备较强的综合分析能力和概念关联能力。此外，题目中的正确选项以表格形式呈现，增加了信息的复杂性和理解难度，要求考生能够快速准确地提取和比较关键信息。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 3292, + "question": "Under what conditions can austenite transform into granular pearlite?", + "answer": "When the austenitizing temperature is low, the holding time is short, the heating transformation is incomplete, the composition of austenite is non-uniform, and subsequently during cooling, the pearlite transformation isothermal temperature is high, the isothermal time is sufficiently long, or the cooling rate is extremely slow, granular pearlite is prone to form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在什么条件下奥氏体会转变为粒状珠光体，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释奥氏体转变为粒状珠光体的具体条件，涉及多个因素的相互作用和机理分析，需要综合运用材料科学中的相变知识，进行推理和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用多个复杂条件（如奥氏体化温度、保温时间、加热转变完整性、成分均匀性、冷却参数等）进行推理分析，并理解这些条件如何共同作用导致粒状珠光体形成。这需要考生具备机理深度解释能力和对复杂现象的全面分析能力，远超选择题常见的单一知识点考查或简单比较分析要求。" + }, + { + "idx": 3293, + "question": "What is a pearlite colony?", + "answer": "In lamellar pearlite, the region where ferrite and cementite are alternately arranged in layers with roughly the same orientation is called a pearlite colony or pearlite nodule.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"pearlite colony\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对pearlite colony这一基本概念的定义和描述，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆，但需要考生准确理解并描述珠光体团（pearlite colony）的定义和结构特征。这比简单的定义记忆（等级1）要求更高，需要考生能够解释和描述概念（等级2），但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 3295, + "question": "What factors influence the interlamellar spacing of pearlite and the pearlite colony?", + "answer": "They are mainly influenced by the formation temperature of pearlite. The lower the temperature, the smaller the pearlite colony size and the smaller the interlamellar spacing of pearlite, such as S0=8.02/ΔGT×10^3(nm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响珠光体片层间距和珠光体团尺寸的因素，答案提供了详细的文字解释和论述，包括温度的影响和具体公式的应用，符合简答题的特征。 | 知识层次: 题目需要理解珠光体片层间距和珠光体团尺寸的影响因素，并涉及温度与片层间距的关系公式。这需要将多个概念关联起来，并进行一定的综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目涉及珍珠岩层间距和珍珠岩团尺寸的影响因素，需要理解温度与这些参数之间的关系，并能够应用给定的公式进行计算。虽然题目提供了具体的公式，但考生仍需具备一定的材料科学基础知识，能够将温度变化与微观结构特征联系起来进行综合分析。" + }, + { + "idx": 3296, + "question": "Compare the diffusivity during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, both iron and carbon atoms can diffuse; in bainitic transformation, carbon atoms diffuse while iron atoms do not; in martensitic transformation, neither iron nor carbon atoms diffuse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同相变过程中的扩散性进行比较和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目要求比较三种不同相变过程中的扩散行为，涉及对扩散机制的理解和不同相变过程特点的综合分析。虽然不需要复杂的计算或推理，但需要对多个概念进行关联和比较，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生同时理解并比较三种不同的相变过程（珠光体转变、贝氏体转变和马氏体转变）中原子扩散行为的差异。这涉及到多个概念的关联和综合分析，需要考生不仅掌握每种相变的基本特征，还要能够区分铁原子和碳原子在不同条件下的扩散行为。这种多角度的分析论述在选择题型中属于较复杂的题目类型。" + }, + { + "idx": 3297, + "question": "Is the statement that the strength and hardness of martensite mainly depend on the mass fraction of carbon correct? Why?", + "answer": "Incorrect. The hardness of martensite primarily depends on the carbon content (mass fraction), but the strength of martensite not only depends on its hardness but also on the morphology of martensite and the size of martensite laths (or plates).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个陈述的对错，并解释原因。答案明确指出了陈述的部分正确性和错误性，并提供了详细的解释。 | 知识层次: 题目不仅需要理解马氏体硬度和强度的基本概念，还需要分析碳含量、马氏体形态和板条尺寸对性能的影响，涉及多个概念的关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生掌握马氏体硬度和强度的基本概念，还需要理解碳含量对硬度的直接影响，以及马氏体形态和板条尺寸对强度的额外影响。这需要综合分析多个因素，并判断原始陈述的正确性。解题过程涉及多步概念关联和结果判断，超出了简单记忆或单一概念应用的范畴，符合等级4的综合分析要求。" + }, + { + "idx": 3298, + "question": "Compare the formation temperatures of bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "Pearlitic transformation occurs in the high-temperature region (below A), bainitic transformation occurs in the medium-temperature region (below B), and martensitic transformation occurs in the low-temperature region (below Ms).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较三种相变的形成温度，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对三种相变温度范围的基础概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个相变温度区域的比较，但正确选项已经明确给出了各个相变发生的温度区域（高温、中温、低温）及其对应的相变类型（珠光体、贝氏体、马氏体）。这属于基础概念记忆的范畴，只需要考生能够区分和记忆不同相变的温度范围即可，不需要进行复杂的分析或推导。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 3299, + "question": "Compare the transformation processes and leading phases of bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "The leading phase of pearlitic transformation is FeC, the leading phase of bainitic transformation is the a phase, and the leading phase of martensitic transformation is not clearly specified.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较贝氏体转变、珠光体转变和马氏体转变的转变过程和主导相，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求比较三种不同的相变过程及其主导相，需要理解并关联多个概念（bainitic、pearlitic、martensitic transformation），并进行综合分析。虽然不涉及复杂计算，但需要对相变机制有较深入的理解和比较能力，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对三种不同的相变过程（贝氏体相变、珠光体相变和马氏体相变）的领先相进行综合比较和分析。这需要考生不仅掌握各个相变的基本概念，还需要理解它们之间的差异和联系。题目涉及的知识点较为深入，且需要考生进行多角度的分析和论述，因此在选择题型中属于较高难度。" + }, + { + "idx": 3300, + "question": "Compare the coherency during the transformations of bainite, pearlite, and martensite", + "answer": "Pearlite transformation has no coherency, while bainite and martensite transformations have shear coherency and produce surface relief.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较贝氏体、珠光体和马氏体转变过程中的共格性，需要文字解释和论述，答案也以文字形式给出，没有选项或计算要求。 | 知识层次: 题目要求比较贝氏体、珠光体和马氏体相变过程中的共格性，涉及多个相变机制的深入理解和综合分析，需要解释不同相变的共格性差异及其产生的原因，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合比较三种不同相变（贝氏体、珠光体、马氏体）的相干性特征，并理解其背后的机理性差异。正确选项不仅需要掌握每种相变的基本特性，还需要理解剪切相干性和表面浮凸效应的产生机制。这种题目要求考生具备将多个复杂概念进行整合分析的能力，并能够区分不同相变过程的本质差异，属于选择题型中最具挑战性的综合分析和机理解释类题目。" + }, + { + "idx": 3301, + "question": "Compare the lattice shear during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "Pearlitic transformation involves no lattice shear, while bainitic transformation and martensitic transformation involve lattice shear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同相变过程中的晶格剪切进行比较和解释，答案以文字论述形式呈现，没有涉及计算或选择判断。 | 知识层次: 题目要求比较三种相变过程中的晶格剪切现象，涉及多个概念（bainitic、pearlitic、martensitic transformation）的关联和综合分析。虽然不涉及复杂计算，但需要对不同相变机制的理解和比较，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对三种不同的相变过程（贝氏体相变、珠光体相变和马氏体相变）的晶格剪切行为进行比较分析。这需要考生不仅掌握每种相变的基本概念，还需要理解晶格剪切在不同相变中的具体表现及其差异。此外，题目涉及的知识点较为深入，需要考生能够将多个概念关联起来进行综合分析，属于多角度分析论述的层次。因此，在选择题型内，该题目的难度等级为4。" + }, + { + "idx": 3302, + "question": "Is the statement that the plasticity and toughness of martensite mainly depend on its substructure correct? Why?", + "answer": "Yes. The plasticity and toughness of martensite mainly depend on its substructure.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求判断一个陈述是否正确（\"Is the statement...correct?\"），并且答案直接给出了对陈述的判断（\"Yes\"），这符合判断题的特征。虽然题目还要求解释原因（\"Why?\"），但主要考察的是对陈述真伪的判断能力。 | 知识层次: 题目不仅需要判断陈述的对错，还需要解释为什么，涉及对马氏体亚结构与其塑性和韧性关系的深入理解和分析。这需要综合运用材料科学知识，进行推理和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解马氏体的塑性和韧性与亚结构的关系，还需要进行深度分析和机理解释。正确选项涉及复杂的材料科学知识，需要综合运用多个概念并进行推理分析，才能得出正确结论。这种题目在选择题型中属于较高层次的认知要求，因此难度等级为5。" + }, + { + "idx": 3303, + "question": "What is the microstructural transformation of quenched steel during tempering at 20-100°C?", + "answer": "Carbon segregation in martensite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在20-100°C回火过程中的微观结构转变，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目涉及对淬火钢在回火过程中微观结构转变的理解，需要将马氏体中的碳偏析现象与回火温度范围联系起来，属于中等应用层次的知识。这需要一定的概念关联和综合分析能力，而不仅仅是基础概念的记忆。 | 难度: 在选择题中属于中等难度，需要理解淬火钢在回火过程中的微观结构转变，并能够将碳在马氏体中的偏析现象与特定温度范围（20-100°C）联系起来。这要求考生掌握马氏体回火的基本知识，并能将温度范围与具体的结构变化对应起来，属于中等应用层次的知识运用。" + }, + { + "idx": 3304, + "question": "Compare the distribution of alloying elements in bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, alloying elements are redistributed through diffusion, while in bainitic transformation and martensitic transformation, alloying elements do not diffuse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对不同相变过程中合金元素的分布进行比较和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目要求比较三种相变过程中合金元素的分布情况，涉及多个概念（扩散、相变类型）的关联和综合分析，需要理解不同相变过程的机制及其对合金元素分布的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较三种不同相变过程中合金元素的分布情况，涉及扩散和非扩散机制的理解。虽然不需要多步计算，但需要对珠光体相变、贝氏体相变和马氏体相变的基本原理有清晰认识，并能综合分析不同相变过程中合金元素的行为差异。这属于中等应用层次的知识要求，符合等级3的综合分析和说明标准。" + }, + { + "idx": 3305, + "question": "Compare the mechanical properties of upper bainite and lower bainite", + "answer": "Generally, the hardness and strength of lower bainite are higher than those of upper bainite, and the plasticity and toughness of lower bainite are also higher than those of upper bainite. Lower bainite has good comprehensive mechanical properties and better toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较上贝氏体和下贝氏体的力学性能，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求比较上贝氏体和下贝氏体的力学性能，需要理解两种组织的形成机制及其对性能的影响，涉及多个概念的关联和综合分析，但不需要深入机理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解并比较上下贝氏体的机械性能差异，包括硬度、强度、塑性和韧性等综合性能的分析。虽然不涉及复杂的计算，但需要对材料微观组织与性能的关系有较深入的理解。" + }, + { + "idx": 3306, + "question": "Compare the hardness of the transformation products of bainite transformation, pearlite transformation, and martensite transformation", + "answer": "The pearlite transformation product has low hardness, the bainite transformation product has medium hardness, and the martensite transformation product has high hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较不同转变产物的硬度，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对三种相变产物硬度的基本记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个相变产物（珠光体、贝氏体、马氏体）的硬度比较，但只需要记忆和区分它们的基本硬度特征即可作答，无需深入理解相变机制或进行复杂分析。这属于\"概念解释和描述\"层次的知识应用。" + }, + { + "idx": 3307, + "question": "What is the microstructural transformation of quenched steel during tempering at 250-400°C?", + "answer": "Transformation of carbides", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在250-400°C回火时的微观结构转变，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对淬火钢在回火过程中微观结构转变的理解，需要将温度范围与具体的碳化物转变相关联，属于中等应用层次的知识。虽然不涉及复杂计算，但需要对材料科学中的相变和碳化物形成有较深入的理解，并能够综合分析不同温度下的微观结构变化。 | 难度: 在选择题中属于中等难度，需要理解淬火钢在回火过程中的微观结构转变，并关联碳化物的转变这一具体知识点。题目涉及中等应用层次的知识，要求考生能够综合分析回火温度范围与微观结构变化的关系，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3308, + "question": "Compare the microstructures of the transformation products of bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "The product of pearlitic transformation is a+FeC (lamellar), the product of upper bainitic transformation is y→a+FeC (non-lamellar), the product of lower bainitic transformation is Ya+e-carbide (non-lamellar), and the two most typical products of martensitic transformation are lath-shaped and plate-shaped.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较不同转变产物的微观结构，需要详细的文字解释和论述，答案也以描述性文字呈现，符合简答题的特征。 | 知识层次: 题目要求比较不同相变产物的显微结构，涉及多个相变过程的概念关联和综合分析。虽然需要记忆各相变产物的基本特征，但更强调对不同相变过程的理解和比较，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生同时掌握并区分四种不同的相变产物（珠光体、上贝氏体、下贝氏体和马氏体）的显微组织特征。题目不仅涉及多个概念的记忆，还需要对这些概念进行横向比较和综合分析。正确选项包含了非层状/层状组织、碳化物形态差异等需要深入理解的微观结构特征，这超出了简单记忆的范畴，属于多角度分析论述的层次。" + }, + { + "idx": 3309, + "question": "Compare the completeness of isothermal transformation for bainite transformation, pearlite transformation, and martensite transformation", + "answer": "Pearlite transformation can be completely transformed, some bainite transformations can be completely transformed while others cannot, and martensite transformation cannot be completely transformed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同相变的完整性进行比较和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目要求比较三种相变（贝氏体、珠光体、马氏体）的等温转变完整性，涉及多个相变过程的概念关联和综合分析。虽然不需要复杂的计算或深度推理，但需要对不同相变的特点和条件有较深入的理解，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解三种相变（贝氏体、珠光体、马氏体）的等温转变特性，并进行多角度比较分析。题目要求考生不仅掌握每种相变的基本概念，还需要了解其转变动力学和完成度的差异，涉及多步概念关联和综合分析能力。正确选项的表述也包含了\"部分可以完全转变\"这种需要精确理解的中间状态描述，增加了判断难度。" + }, + { + "idx": 3310, + "question": "Explain the application of upper bainite and lower bainite in production", + "answer": "a) Isothermal quenching of bainite (lower bainite) is often used to replace quenching + low-temperature tempering; b) Ultra-high strength steel obtains a composite structure of bainite (lower) + martensite to achieve the best combination of strength and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释上贝氏体和下贝氏体在生产中的应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释上贝氏体和下贝氏体在生产中的应用，涉及对贝氏体形成条件、性能特点及其在热处理工艺中的具体应用的理解和综合分析。需要将贝氏体的分类（上贝氏体和下贝氏体）与其在实际生产中的具体应用场景联系起来，并进行一定的解释和论述。这属于中等应用层次，需要多步概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解上贝氏体和下贝氏体的基本概念，还需要掌握它们在工业生产中的具体应用场景。题目涉及等温淬火工艺替代传统淬火+低温回火的综合分析，以及超高强度钢中复合组织的性能优化策略，需要考生进行多角度分析和概念关联。正确选项包含两个需要综合判断的技术应用场景，在选择题型内属于需要较强应用分析能力的题目。" + }, + { + "idx": 3311, + "question": "What is the microstructure transformation of quenched steel during tempering at 100-250°C?", + "answer": "Decomposition of martensite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在100-250°C回火时的微观结构转变，答案需要文字描述（马氏体分解），属于简答题类型。 | 知识层次: 题目考查对淬火钢在回火过程中微观结构转变的理解，需要将马氏体分解的概念与特定温度范围（100-250°C）联系起来，属于中等应用层次。虽然不涉及复杂计算，但需要综合理解和应用相关知识。 | 难度: 在选择题中属于中等难度，需要理解马氏体分解的概念，并能够将其与回火温度范围（100-250°C）联系起来。这涉及对钢的热处理过程中微观结构变化的综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3312, + "question": "What is the microstructural transformation of quenched steel during tempering at 200-300°C?", + "answer": "Transformation of retained austenite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在200-300°C回火时的微观结构转变，需要文字解释和论述，而不是选择或判断。答案也是以简短描述的形式给出。 | 知识层次: 题目要求解释淬火钢在200-300°C回火时的微观结构转变，涉及对回火过程中残余奥氏体转变的理解。这需要将热处理工艺参数与相变知识关联起来，属于中等应用层次。虽然不涉及复杂计算，但需要综合分析温度范围与相变类型的关系，比单纯记忆概念要求更高。 | 难度: 在选择题中属于中等难度，需要理解淬火钢在回火过程中的微观结构转变，特别是200-300°C温度范围内残余奥氏体的转变。这要求考生掌握相关概念并能进行综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3313, + "question": "What is temper brittleness?", + "answer": "When some steels are tempered within a certain temperature range, their impact toughness significantly decreases compared to being tempered at lower temperatures. This embrittlement phenomenon is called temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"temper brittleness\"进行文字解释和论述，答案提供了详细的定义和现象描述，符合简答题的特征。 | 知识层次: 题目考查对\"temper brittleness\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（temper brittleness的定义），但正确选项需要理解并描述一个特定的材料现象（特定温度区间回火导致的韧性下降），而不仅仅是简单的名词定义。这比单纯记忆术语（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 3314, + "question": "What is the microstructure transformation of quenched steel during tempering at 400-600°C?", + "answer": "Cementite aggregation and growth, and recovery and recrystallization of α phase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释淬火钢在400-600°C回火过程中的微观结构转变，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释淬火钢在400-600°C回火过程中的微观结构转变，涉及多个相变过程（渗碳体聚集与长大、α相回复与再结晶）的机理分析，需要综合运用材料科学中的相变理论、热力学和动力学知识，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用多个知识点（淬火钢的回火过程、渗碳体聚集与长大、α相的回复与再结晶），并理解这些现象在400-600°C温度范围内的相互作用机理。解题需要深入掌握材料相变原理，能够分析复杂的热处理过程，并准确识别特定温度区间内的微观结构演变特征。这种题目不仅测试记忆能力，更考察对材料科学原理的系统性理解和综合应用能力。" + }, + { + "idx": 3315, + "question": "Describe the microstructure type, obtaining conditions, characteristics, and mechanical properties of medium-temperature tempered steel", + "answer": "Medium-temperature tempering Tempered troostite 350-500°C High elastic limit", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述中温回火钢的微观结构类型、获得条件、特征和机械性能，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求描述中温回火钢的微观结构类型、获得条件、特征和力学性能，涉及多个知识点的关联和综合分析，需要理解回火温度与微观结构的关系以及这些结构对性能的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握中温回火钢的微观结构类型、获得条件、特性以及机械性能，并能够将这些知识点关联起来。虽然题目提供了正确选项，但考生仍需具备一定的综合分析能力，才能准确理解并选择正确的答案。" + }, + { + "idx": 3316, + "question": "Describe the types of low-temperature tempered structures in steel, the conditions for obtaining them, their structural characteristics, and mechanical properties", + "answer": "Low-temperature tempering Tempered martensite 150-250°C High hardness, high wear resistance", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述低温回火钢结构的类型、获得条件、结构特征和机械性能，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案提供了简要的信息，但完整的回答需要更详细的描述。 | 知识层次: 题目要求描述低温回火组织的类型、获得条件、结构特征和力学性能，涉及多个知识点的关联和综合分析，需要理解不同条件对组织性能的影响，并进行一定程度的推理和解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握低溫回火钢的结构类型、获得条件、结构特征和机械性能，并能够将这些知识点关联起来。虽然题目提供了正确选项，但考生仍需具备一定的综合分析能力，才能准确匹配各个要素。" + }, + { + "idx": 3317, + "question": "Describe the microstructure type, obtaining conditions, characteristics, and mechanical properties of steel after high-temperature tempering", + "answer": "High-temperature tempering Tempered sorbite 500-650℃ Good combination of strength and toughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述高温回火后钢的微观结构类型、获得条件、特征和机械性能，需要文字解释和论述，答案也以简短的文字形式呈现。 | 知识层次: 题目要求描述高温回火后钢的微观结构类型、获得条件、特征和力学性能，涉及多个知识点的关联和综合分析，需要理解回火温度对钢性能的影响机制，并能够将微观结构与宏观性能联系起来。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生综合掌握高温回火后的钢的微观结构类型、获得条件、特性以及力学性能，并能够将这些知识点关联起来。虽然题目给出了正确选项，但考生仍需具备一定的综合分析能力才能准确选择。" + }, + { + "idx": 3318, + "question": "Compare the approximate diffusion distances/mm of carbon atoms during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, the diffusion distance of carbon atoms is greater than 10mm; in bainitic transformation, the diffusion distance of carbon atoms is 0~10mm; in martensitic transformation, the diffusion distance of carbon atoms is 0mm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对不同相变过程中碳原子的扩散距离进行比较和解释，答案以文字形式详细描述了不同相变过程中的扩散距离范围，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较不同相变过程中碳原子的扩散距离，涉及对珠光体、贝氏体和马氏体相变过程的理解，需要综合分析不同相变机制对碳原子扩散的影响。虽然不涉及复杂计算，但需要对多个概念进行关联和比较，思维过程有一定深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生比较碳原子在不同相变过程中的扩散距离，涉及对珠光体转变、贝氏体转变和马氏体转变的理解。虽然题目提供了正确选项，但考生仍需掌握这些相变的基本特征和扩散机制，才能正确判断和比较扩散距离。这需要中等层次的知识应用能力，包括概念关联和综合分析。" + }, + { + "idx": 3319, + "question": "Indicate the main purpose of normalizing 20 steel gears and the microstructure after normalizing", + "answer": "Normalizing of 20 steel: improve machinability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释正常化处理20钢齿轮的主要目的以及处理后的显微组织，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对正火处理目的和结果的基础概念记忆，属于基本原理的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆20钢正火的主要目的和微观结构，属于基础概念记忆性知识。题目直接给出了正确选项，无需复杂分析或推理，仅需识别和回忆相关定义即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3320, + "question": "Explain the factors affecting the depth of the hardened layer.", + "answer": "The depth of the hardened layer is related to factors such as the hardenability of the steel, the size of the workpiece, and the cooling capacity of the quenching medium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响硬化层深度的因素，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求解释影响硬化层深度的因素，需要理解并关联多个概念（钢的淬透性、工件尺寸、淬火介质冷却能力），属于中等应用层次的知识运用。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如钢的淬透性、工件尺寸和淬火介质的冷却能力）并进行综合分析。虽然题目涉及多个因素，但在选择题型中，正确选项已经整合了这些概念，不需要考生自行推导或深入关联不同领域的知识。" + }, + { + "idx": 3321, + "question": "Indicate the main purpose of normalizing T12 steel file and the structure after normalizing", + "answer": "T12 steel file: Normalizing eliminates the network carbide and prepares for spheroidizing annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释T12钢文件的主要正火目的及正火后的结构，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释T12钢正火的主要目的及正火后的组织，涉及对正火工艺的理解和应用，需要将材料科学中的热处理知识与具体材料（T12钢）的特性相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解T12钢正火的主要目的和后续球化退火的关系，涉及多个概念的综合分析。虽然题目给出了正确选项，但需要考生具备对正火工艺和球化退火的基本理解，以及对碳化物网络消除的认知。这种题目在选择题型中属于需要一定知识深度和概念关联的题目，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3322, + "question": "What is the hardenability of steel?", + "answer": "The hardenability of steel refers to the ability of steel to obtain martensite during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"hardenability of steel\"的定义，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对钢的淬透性这一基本概念的定义和记忆，属于基础概念的理解和表述。 | 难度: 在选择题型中，该题目仅考察对\"钢的淬透性\"这一基础定义的记忆，属于最基本的概念性知识。题目仅要求识别正确选项中的定义描述，不需要任何解释、分析或比较过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3323, + "question": "How to suppress temper brittleness?", + "answer": "Methods to suppress temper brittleness: For the first type of temper brittleness, due to its irreversibility, it can only be avoided by tempering outside the embrittlement temperature range; if tempering must be performed within this temperature range, isothermal quenching can be used; adding Si to shift the low-temperature temper embrittlement range to higher temperatures, etc. Methods to suppress high-temperature temper brittleness: a) Rapid cooling after high-temperature tempering; b) Reducing the content of impurity elements in the steel; c) Adding appropriate amounts of Mo or W to the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何抑制回火脆性，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释如何抑制回火脆性，涉及多种方法和原理的综合应用，需要理解不同方法的适用条件和作用机制，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解回火脆性的基本概念，还需要掌握两种不同类型的回火脆性（第一类回火脆性和高温回火脆性）的抑制方法。题目涉及多个知识点，包括温度范围控制、合金元素添加、热处理工艺选择等，要求考生能够综合分析和关联这些概念。此外，解题步骤较为复杂，需要考生在多个选项中识别出正确的抑制方法，并进行多角度分析。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 3325, + "question": "What are the types and characteristics of temper brittleness?", + "answer": "There are mainly two types of temper brittleness, namely low-temperature temper brittleness and high-temperature temper brittleness. Low-temperature temper brittleness, also known as the first type of temper brittleness, occurs to varying degrees in almost all industrial steels and is independent of the cooling rate after tempering. Therefore, it is also called irreversible temper brittleness (i.e., it occurs whether cooled rapidly or slowly). High-temperature temper brittleness, also known as the second type of temper brittleness, is characterized by its occurrence only in steels with specific compositions. Whether temper brittleness occurs depends on the cooling rate after tempering, i.e., it appears with slow cooling after tempering but not with rapid cooling, hence it is also called reversible temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述回火脆性的类型和特征，答案提供了详细的文字解释和分类说明，符合简答题的特点。 | 知识层次: 题目主要考查对回火脆性的类型和特点的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生理解和描述两种回火脆性的类型及其特点，涉及概念的解释和描述，但不需要复杂的比较分析或深入的概念体系阐述。因此，属于中等难度。" + }, + { + "idx": 3326, + "question": "Explain the factors affecting hardenability.", + "answer": "Hardenability mainly depends on the carbon content of martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响淬透性的因素，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求解释影响淬透性的因素，需要理解淬透性的基本原理，并能够关联多个影响因素（如碳含量、合金元素、冷却速率等）进行综合分析。虽然答案只提到马氏体的碳含量，但完整的回答需要更全面的分析和关联。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求解释影响淬透性的因素，而正确选项涉及马氏体碳含量这一关键概念，需要考生具备将材料性能与微观结构关联的能力。虽然不涉及多步计算，但需要对淬透性机制有综合理解，这超过了基础记忆层面，属于概念关联和中等应用层次。" + }, + { + "idx": 3327, + "question": "Describe the purpose of quenching", + "answer": "Quenching can significantly improve the strength and hardness of steel. Combined with tempering at different temperatures, it can achieve a balance of strength, hardness, and toughness to meet various requirements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述淬火的目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查淬火的基本目的及其对钢性能的影响，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生不仅记忆淬火的基本定义，还需要理解淬火对钢材性能的影响以及与其他工艺（如回火）的协同作用。这超出了简单的定义记忆，属于概念解释和描述的层次，但不需要复杂的体系阐述或比较分析。" + }, + { + "idx": 3328, + "question": "What are the types of quenching methods", + "answer": "The quenching methods include: 1. Single-liquid quenching; 2. Dual-liquid quenching; 3. Graded quenching; 4. Isothermal quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举淬火方法的类型，答案以文字解释和论述的形式给出，没有选项或计算要求 | 知识层次: 题目考查淬火方法的基本分类和记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆淬火方法的分类，属于基础概念记忆的简单题目。正确选项直接列出了四种淬火方法，无需进一步解释或分析，符合等级1的基本定义简答要求。" + }, + { + "idx": 3329, + "question": "There is a 20 steel workpiece with a diameter of φ12mm, which is carburized and then air-cooled, followed by normal quenching and tempering. Analyze the microstructure from the surface to the core of the workpiece after carburizing and air-cooling, and after quenching and tempering.", + "answer": "After air-cooling: P + Fe3CI, P, P + F; After quenching and tempering: M⊥+ FeC, tempered M, tempered M + F.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析工件从表面到核心的微观结构变化，需要详细的文字解释和论述，答案也是以描述性文字形式呈现，而非选择、判断或计算。 | 知识层次: 题目要求分析从表面到核心的微观结构变化，涉及多个热处理步骤（渗碳、空冷、淬火、回火）的综合影响，需要深入理解材料相变原理和热处理工艺对微观结构的影响，并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3330, + "question": "After quenching T8 steel wire to 275°C and holding for 1s, indicate its phase and composition.", + "answer": "Undercooled austenite (w_C=0.77%)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述材料的相和组成，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解T8钢的相变行为，并应用TTT图或CCT图的知识来确定在特定温度和时间下的相组成。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及T8钢的淬火工艺、相变温度以及相组成等知识点，要求考生能够综合运用这些知识来判断在特定条件下的相和成分。虽然题目给出了具体的温度和时间条件，但需要考生对钢的相变行为和成分有深入的理解才能正确选择答案。此外，题目还要求考生能够将理论知识与实际工艺条件相结合，进行综合分析。" + }, + { + "idx": 3331, + "question": "After quenching T8 steel wire to 20°C and holding, indicate its phases and composition.", + "answer": "M+A′ (w_C=0.77% in M, A′)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述淬火后T8钢的相组成和成分，需要文字解释和论述，答案给出了具体的相和成分，属于简答题类型。 | 知识层次: 题目要求分析T8钢在特定热处理条件下的相组成和成分，需要理解钢的相变原理和相图知识，并能够将理论应用于具体材料和处理条件。这涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解T8钢的相变过程、淬火后的组织组成以及碳含量的分配。题目要求考生综合运用相图知识和热处理原理，分析淬火后钢中的马氏体（M）和残余奥氏体（A′）的组成及其碳含量。虽然题目提供了正确选项，但考生仍需具备一定的知识深度和综合分析能力才能正确理解和选择答案。" + }, + { + "idx": 3333, + "question": "When complete austenitization of steel is required, is the original structure better with coarse granular pearlite or fine lamellar pearlite?", + "answer": "Fine lamellar pearlite is better.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么细片状珠光体比粗粒状珠光体更适合完全奥氏体化，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要理解奥氏体化过程中原始组织的影响，并比较粗粒状珠光体和细片层珠光体的差异。这涉及到材料科学中相变和显微组织的概念关联，需要综合分析不同组织对奥氏体化过程的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及钢的奥氏体化过程，要求考生掌握粗粒珠光体和细片层珠光体的区别及其对奥氏体化的影响。虽然不需要复杂的计算，但需要综合理解材料微观结构对热处理过程的影响，并进行概念关联和综合分析。" + }, + { + "idx": 3334, + "question": "Explain why the initial structure with fine lamellar pearlite is better using the austenite isothermal formation mechanism.", + "answer": "Increasing the dispersion of carbides can accelerate the transformation from pearlite to austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么初始结构具有细片状珠光体更好，需要使用奥氏体等温形成机制进行论述。答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释初始细片层珠光体结构更优的原因，并涉及奥氏体等温形成机制的分析。这需要综合运用材料科学中的相变原理、组织-性能关系等知识，进行机理层面的推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解珠光体到奥氏体的转变机制，还需要掌握碳化物分散度对相变动力学的影响。正确选项涉及微观结构-性能关系的深层机理分析，需要综合材料科学、相变动力学和扩散理论等多学科知识进行推理判断。这种在选择题中要求对复杂现象进行全面分析的题目，对考生的知识整合能力和高阶思维能力提出了极高要求。" + }, + { + "idx": 3335, + "question": "After quenching T8 steel wire to 550°C and holding for 1s, indicate its phase and composition.", + "answer": "B⊥[F(w_C=0.0218%)+Fe3C(w_C=6.69%)]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出材料的相和组成，需要文字解释和论述，答案形式为相组成的具体描述而非选择或计算 | 知识层次: 题目需要结合钢的相变知识和TTT曲线，通过中等复杂度的分析判断在特定温度和时间下的相组成和成分。这涉及多步概念关联和综合分析，但不需要复杂的机理推导或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握T8钢的相变知识，包括淬火后的相组成和成分计算。虽然题目给出了具体的温度和时间条件，但需要考生能够正确识别相组成（F+Fe3C）并计算其成分（w_C=0.0218%和w_C=6.69%）。这需要考生具备中等应用层次的知识，能够进行多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3336, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for normalizing φ25 hot-rolled eutectoid steel.", + "answer": "Normalizing: 780°C holding for 1h, air cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定热处理条件（温度、时间、冷却速率等），答案需要文字解释和论述，而不是从选项中选择或简单的对错判断或数值计算。 | 知识层次: 题目要求根据给定的材料（φ25热轧共析钢）直接应用标准的热处理工艺（正火），涉及温度、时间和冷却方式等具体参数的记忆和应用，属于直接套用标准工艺的简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用标准热处理工艺参数（780°C保温1小时空冷）即可作答。不需要进行计算或复杂分析，属于对基础知识的直接应用，符合等级2\"简单应用过程描述\"的特征。" + }, + { + "idx": 3337, + "question": "Indicate the main purpose of normalizing a small shaft made of 45 steel and the microstructure after normalizing", + "answer": "Small shaft made of 45 steel: Using normalizing instead of quenching and tempering as the final heat treatment can achieve good comprehensive mechanical properties similar to those obtained through quenching and tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释45钢小轴正火的主要目的及正火后的显微组织，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释正火处理的主要目的和微观结构，需要理解正火处理的基本原理及其对45钢性能的影响，并能够将热处理工艺与材料性能关联起来进行分析。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解45钢正火处理的主要目的及其后的显微组织，并与淬火回火处理的综合力学性能进行比较分析。题目要求考生将多个热处理概念进行关联，并做出正确判断，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3338, + "question": "After heating T8 steel wire to 870°C and holding for 1h, indicate its phase and composition.", + "answer": "Austenite, w_C=0.77%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述材料的相和成分，需要文字解释和论述，而不是从选项中选择或进行数值计算 | 知识层次: 题目考查对T8钢在特定热处理条件下的相和成分的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（T8钢的相变温度和成分），但需要考生准确记忆T8钢在特定温度（870°C）下的相变结果（奥氏体）和碳含量（0.77%）。这比单纯的定义记忆（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 3339, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for φ25 hot-rolled eutectoid steel during annealing.", + "answer": "Annealing: hold at 760°C for 1h, furnace cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定热处理条件（温度、时间、冷却速率等），需要文字解释和论述，答案给出了具体的处理条件和方式，属于简答题类型。 | 知识层次: 题目要求确定热轧共析钢的退火热处理条件，涉及温度、时间和冷却速率等参数的选择。这需要理解退火工艺的基本原理，并能根据具体材料（φ25热轧共析钢）进行参数选择和调整。虽然有一定的记忆成分，但更多是需要将理论知识应用到具体情境中，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。该题目要求考生掌握热轧共析钢的退火热处理条件，包括温度、时间和冷却速率等参数。虽然题目给出了正确选项，但考生需要理解退火工艺的基本原理，并能将理论知识与实际应用相结合。此外，还需要对共析钢的相变温度有所了解，才能正确判断760°C的保温温度是否合适。这些要求使得该题目在选择题型中处于中等难度水平。" + }, + { + "idx": 3340, + "question": "There is a batch of approximately 10,000 pieces of 45 steel gears, which are subjected to relatively low contact stress but require good wear resistance on the teeth and minimal heat treatment deformation. What surface treatment should be selected for these parts? Why?", + "answer": "High-frequency surface quenching. After high-frequency surface quenching, the surface hardness is 1-2 HRC higher than conventional quenching, providing good wear resistance. Additionally, since high-frequency surface quenching results in minimal heat treatment deformation, this process is selected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述选择某种表面处理的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求根据具体工况（低接触应力、耐磨性要求、热处理变形小）选择合适的表面处理方法，并解释原因。这需要综合理解高频表面淬火的工艺特点（硬度提升、变形小）与材料性能（45钢）的关联，属于多因素综合分析的应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生综合考量材料特性（45钢）、应用场景（低接触应力但高耐磨需求）以及热处理工艺特性（高频表面淬火变形小且硬度更高），才能正确选择表面处理方法。这涉及多步概念关联和综合分析能力，但无需进行多角度或深度关联性分析，因此符合等级3的标准。" + }, + { + "idx": 3341, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for spheroidizing annealing of φ25 hot-rolled eutectoid steel.", + "answer": "Spheroidizing annealing: hold at 780°C for 1h, air cool; hold at 680-700°C for 1h, air cool.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定球化退火的热处理条件（温度、时间、冷却速率等），答案需要提供具体的处理参数和文字说明，属于需要详细解释和论述的简答题类型。 | 知识层次: 题目要求确定球化退火的热处理条件，涉及温度、时间和冷却速率等多个参数的设定，需要综合理解球化退火的原理和具体工艺参数的选择。虽然答案给出了具体的数值，但需要理解这些参数背后的原理和相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求确定球化退火的热处理条件，涉及温度、时间和冷却速率等多个参数的综合考虑。虽然给出了正确选项，但需要考生具备对球化退火工艺的基本理解，并能将理论知识与实际应用相结合。此外，题目还要求考生能够关联不同温度阶段的作用，并进行综合分析，因此在选择题型中属于中等难度。" + }, + { + "idx": 3342, + "question": "If a $\\phi5\\$ hot-rolled steel specimen is heated to 650℃, held isothermally for 15s, and then quenched in water, can the isothermal transformation curve be used to analyze the final microstructure obtained?", + "answer": "No. The isothermal transformation curve describes the transformation of undercooled austenite. The hot-rolled eutectoid steel heated to 650℃ does not undergo austenitization.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（是否可以使用等温转变曲线分析最终获得的微观结构），答案直接给出了\"是/否\"的判断（No），并提供了简要解释。这符合判断题的特征。 | 知识层次: 题目考查对等温转变曲线基本概念的理解，即它仅适用于过冷奥氏体的转变，而不适用于未发生奥氏体化的情况。这属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等难度，需要理解等温转变曲线的基本概念及其应用条件，并判断题目描述的情况是否符合这些条件。虽然不涉及复杂的分析步骤，但需要对基础概念有一定的理解和应用能力。" + }, + { + "idx": 3343, + "question": "In eutectoid steel, both pearlite and tempered martensite (assuming tempered at 400°C) are composed of ferrite and carbides. Why do the morphology of ferrite and the number of internal defects in tempered martensite differ from those in pearlite?", + "answer": "The pearlite in eutectoid carbon steel is lamellar, consisting of F plates (with a low number of internal defects) + Fe3C plates. After tempering at 400°C, the martensite structure becomes tempered troostite, F45 + Fe3C45, which is acicular ferrite and fine granular cementite. The ferrite in pearlite is lamellar with a low number of crystal defects (dislocations, twins), whereas the tempered martensite contains acicular ferrite, where the number of crystal defects is much higher than in pearlite due to quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在共析钢中珠光体和回火马氏体的铁素体形态和内部缺陷数量不同，需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释珠光体和回火马氏体中铁素体形态和内部缺陷数量的差异，涉及相变过程、显微组织演变和晶体缺陷等复杂概念的综合分析。需要理解淬火和回火过程中的相变机制，以及这些机制如何影响最终的组织形态和缺陷密度。这超出了简单记忆或直接应用的范围，需要深入的分析和推理。 | 难度: 在选择题型内属于最高难度等级，需要考生具备以下能力：" + }, + { + "idx": 3344, + "question": "When hypereutectoid steel is slowly cooled from the austenite region, secondary cementite precipitates along the austenite grain boundaries in a network pattern. How can the network cementite be eliminated by heating above Ac cm followed by quenching and subsequent treatment?", + "answer": "Heating above Ac cm followed by quenching results in martensite and retained austenite, which is then tempered at high temperature to obtain spheroidized pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过热处理消除网状渗碳体，答案提供了详细的步骤和原理说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及对钢的热处理过程的理解，需要综合运用相变原理、热处理工艺知识，并分析不同处理步骤对微观组织的影响。解答过程需要推理分析加热、淬火和回火等步骤如何消除网状渗碳体，并解释最终获得的球化珠光体组织的形成机理。这超出了简单记忆或直接应用的层次，属于较复杂的分析和综合运用。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3345, + "question": "Among the various types of steel currently used in industry, cold-drawn high-carbon steel wire has the highest strength (up to 3000 MPa). This type of wire is generally obtained by first undergoing austenitization, followed by isothermal treatment in a lead bath at 500°C, and then cold drawing. Analyze the reasons for the high strength of this material.", + "answer": "When high-carbon steel undergoes isothermal treatment at 550°C after austenitization, the interlamellar spacing of pearlite can be made very small. Subsequent cold drawing not only increases the dislocation density in the ferrite of the pearlite, causing work hardening and subgrain refinement, but also further reduces the interlamellar spacing of the pearlite, thereby achieving high strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高碳钢冷拉钢丝高强度的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高碳钢丝高强度的原因，涉及多个热处理和加工步骤（奥氏体化、等温处理、冷拔）的综合作用机制，需要理解珠光体层间距、位错密度增加、亚晶粒细化等微观结构变化对宏观性能的影响，属于需要综合运用材料科学知识进行机理分析和解释的复杂问题。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解高碳钢的微观结构变化（如珠光体片层间距、位错密度增加等），还需要综合运用热处理和冷加工的知识，分析多个工艺步骤对材料性能的影响机制。正确选项涉及复杂的热力学和动力学过程解释，需要考生具备深入的材料科学原理知识和综合分析能力。这种题目在选择题型中属于对机理深度解释和复杂现象全面分析的最高要求。" + }, + { + "idx": 3346, + "question": "In eutectoid steel, both pearlite and tempered martensite (assuming tempered at 400°C) consist of ferrite and carbide. Why do the morphology and dispersion of carbides in tempered martensite differ from those in pearlite?", + "answer": "The carbides in pearlite exhibit a lamellar morphology with low dispersion, whereas the carbides in martensite are fine particles with high dispersion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体和珠光体中的碳化物形态和分散度不同，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释珠光体和回火马氏体中碳化物的形态和分散性差异的原因，这需要深入理解相变过程、显微组织形成机制以及热处理对组织的影响。涉及多个概念的关联和综合分析，需要推理和机理解释，属于较高层次的认知要求。 | 难度: 在选择题中属于最高难度，需要深入理解珠光体和回火马氏体的微观结构差异及其形成机理。题目要求综合运用相变动力学、晶体学知识和热处理原理，对碳化物的形态和分布进行机理层面的对比分析。这种复杂现象的全方位分析在选择题型中属于认知要求最高的类型。" + }, + { + "idx": 3347, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the iron-carbon phase diagram?", + "answer": "The iron-carbon phase diagram can only be used to determine the microstructure under equilibrium cooling conditions and is not applicable for predicting the normalizing effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对铁碳相图在预测正火效果中的适用性进行文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析铁碳相图在预测正火效果中的适用性，涉及对相图的理解和应用，需要将相图的基本原理与实际热处理工艺（正火）联系起来进行综合分析。虽然不涉及复杂计算，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念及其应用限制，并能将这一知识应用到具体的热处理工艺（正火）中。题目要求考生不仅知道铁碳相图的作用，还要明白其在非平衡冷却条件下的局限性，这需要一定的综合分析能力。" + }, + { + "idx": 3348, + "question": "Compare the advantages and disadvantages of various quenching methods", + "answer": "1. Single-liquid quenching: This method is widely used, simple to operate, and easy to mechanize. The drawback is that some steel parts are prone to deformation and cracking when water-quenched, while oil quenching may result in insufficient hardness. 2. Dual-liquid quenching: This method is difficult to control. 3. Graded quenching: During quenching, the internal temperature of the workpiece is uniform, and the structural transformation occurs almost simultaneously, thereby reducing internal stress and significantly lowering the tendency for deformation and cracking. However, it is only suitable for workpieces with strict deformation requirements and smaller dimensions. 4. Isothermal quenching: Workpieces treated by this method exhibit high strength and hardness, as well as good plasticity and toughness. Additionally, the quenching stress is low, and deformation is minimal. It is mostly used for workpieces with complex shapes, smaller dimensions, and higher precision requirements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较不同淬火方法的优缺点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较不同淬火方法的优缺点，需要对各种淬火方法的基本原理和应用场景有较深入的理解，并进行综合分析。虽然不涉及复杂的计算或创新设计，但需要对多个概念进行关联和比较，思维过程具有一定的深度和复杂性。 | 难度: 在选择题型中，该题目要求考生对多种淬火方法的优缺点进行多角度分析和比较，涉及多个概念的综合运用和关联。虽然题目提供了正确选项，但考生需要理解每种淬火方法的具体特点、适用条件及其对工件性能的影响，这需要较高的综合分析能力。此外，题目还要求考生能够对不同方法进行横向比较，评估其优缺点，这进一步增加了题目的难度。因此，该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 3349, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the isothermal transformation curve?", + "answer": "Using the isothermal transformation curve can only provide an approximate estimation of the normalizing effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对等温转变曲线在预测正火效果中的适用性进行解释和论述，答案提供了文字解释而非选择、判断或计算 | 知识层次: 题目涉及使用等温转变曲线来预测正火效果，需要理解等温转变曲线的含义及其在热处理中的应用，属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解等温转变曲线的应用范围及其局限性，并能综合分析其对正火效果的预测能力。题目要求考生将材料科学中的等温转变曲线与实际工艺效果联系起来，进行概念关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3350, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the continuous cooling transformation curve?", + "answer": "To predict the microstructure and hardness after cooling, the continuous cooling transformation curve should be used, as normalizing is a continuous cooling process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释连续冷却转变曲线在预测正火效果中的适用性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求将连续冷却转变曲线应用于预测正火效果，涉及概念关联和综合分析，需要理解正火过程与连续冷却转变曲线的关系，并应用该知识进行预测。 | 难度: 在选择题中属于中等难度，需要理解连续冷却转变曲线的应用场景，并能将其与正火工艺（连续冷却过程）关联起来。题目要求考生不仅知道连续冷却转变曲线的基本概念，还要能综合分析其在预测显微组织和硬度方面的适用性。这种题目涉及多步概念关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3351, + "question": "Suppose the microstructure of an alloy consists of multiple two-phase lamellar eutectic domains with different orientations and uniform distribution. The actual interlamellar spacing in each domain is equal. How should this interlamellar spacing be determined under a metallographic microscope?", + "answer": "Measure the minimum interlamellar spacing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述如何确定层间距，答案是一个简短的文字说明而非计算或选择 | 知识层次: 题目需要理解两相层状共晶组织的微观结构特征，并应用测量最小层间距的方法来确定实际层间距。这涉及到对显微组织观察的理解和实际测量技术的应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生在显微镜下测量层间距，并选择正确的测量方法。虽然题目给出了多个两相层状共晶域的不同取向和均匀分布的条件，但正确选项要求考生能够综合这些信息，理解在显微镜下测量最小层间距的重要性。这需要考生具备一定的材料科学知识，能够将微观结构与实际测量方法联系起来，并进行综合分析。" + }, + { + "idx": 3352, + "question": "In eutectoid steel, both pearlite and tempered martensite (assuming tempered at 400°C) are composed of ferrite and carbide. Why is the strength of tempered martensite higher than that of the strongest pearlite?", + "answer": "The morphology of ferrite and the number of internal defects differ between the two. In pearlite, the ferrite is lamellar with fewer crystal defects (dislocations, twins), whereas in tempered martensite, the ferrite is acicular, and the number of crystal defects is much higher due to quenching. The morphology and dispersion of carbides also differ. In pearlite, the carbides are lamellar with low dispersion, while in martensite, the carbides are fine particles with high dispersion. Thus, the strength of tempered martensite is higher than that of the strongest pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体的强度高于最强的珠光体，答案提供了详细的文字解释和论述，涉及两种组织的铁素体和碳化物的形态、缺陷数量等差异，符合简答题的特征。 | 知识层次: 题目要求解释两种不同微观组织（珠光体和回火马氏体）的强度差异，涉及晶体缺陷、碳化物形态和分散度等多个因素的对比分析。需要综合运用材料科学中的相变、强化机制等知识，进行深入的推理和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解珠光体和回火马氏体的基本组成（铁素体和碳化物），还需要深入分析两者在铁素体形态、晶体缺陷数量、碳化物形态和分散度等方面的差异。此外，题目涉及淬火和回火工艺对材料性能的影响，需要综合运用材料科学中的相变理论和强化机制知识进行推理分析。正确选项的解释涉及多个复杂概念的交叉对比，属于复杂现象全面分析的层次，因此在选择题型中属于最高难度。" + }, + { + "idx": 3353, + "question": "Suppose the microstructure of a certain alloy consists of spherical second-phase particles and a matrix. If the actual diameters of the second-phase particles are all equal, how should the particle size be determined under a metallographic microscope?", + "answer": "Measure the diameter of the largest particle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来说明如何确定粒子尺寸，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查对金相显微镜下测量第二相粒子尺寸的基本方法的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即测量第二相颗粒直径的基本方法。正确选项直接给出了明确的答案，无需复杂推理或概念比较，属于最基础的定义简答级别。" + }, + { + "idx": 3354, + "question": "Using the fact that pearlite, proeutectoid ferrite, and proeutectoid cementite preferentially precipitate at austenite grain boundaries, propose a method for determining the austenite grain size of steel with a carbon mass fraction of 0.8%.", + "answer": "After austenitization, isothermally hold near the knee of the C-curve until partial pearlite transformation occurs (e.g., around 10%), then quench. Since pearlite preferentially nucleates and grows at austenite grain boundaries, the grain boundaries will appear as dark pearlite, while the grain interiors will be less etchable martensite. This allows convenient measurement of austenite grain size under a microscope. Alternatively, this microstructure can be obtained by cooling at an appropriate rate after austenitization (e.g., oil quenching for specimens about 10mm thick). For better control, a rod-shaped specimen can be austenitized with one end immersed in water while the rest cools in air. This creates a range of cooling rates along the rod's length, ensuring there will always be a section where pearlite precipitates along austenite grain boundaries with martensite in the grain interiors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提出一个方法并详细解释其步骤和原理，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求学生综合运用材料科学中的相变原理、显微组织观察和实验设计等多方面知识，提出一种确定奥氏体晶粒尺寸的方法。这需要深入理解珠光体、先共析铁素体和先共析渗碳体的形成机制，以及它们与奥氏体晶界的关系。此外，还需要设计实验步骤（如等温保持、淬火等）并解释其原理，体现了较高的综合分析能力和推理能力。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3356, + "question": "A heat-treated part is made of 55 steel with an effective thickness of 10 mm, requiring a quenched and tempered hardness of HRC 32-37. Using oil quenching and tempering can also achieve the hardness specified in the drawing. Analyze whether this treatment method is reasonable.", + "answer": "Generally speaking, it is not reasonable. Because oil quenching will result in a large amount of lamellar pearlite transformation products. Although the hardness after tempering falls within the required range, the overall mechanical properties are inferior to those of tempered martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析热处理方法的合理性，答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要综合分析55钢的淬火回火工艺选择及其对机械性能的影响，涉及热处理工艺参数与材料性能的关联，需要中等程度的认知能力和知识点关联分析。 | 难度: 在选择题中属于较高难度，需要综合运用材料科学知识进行多角度分析。题目不仅考察对淬火介质选择的理解，还要求考生能够分析不同热处理工艺对最终机械性能的影响。正确选项涉及对珠光体和回火马氏体组织性能的对比分析，需要将热处理工艺、显微组织和机械性能三者关联起来进行综合判断。这种综合分析能力在选择题型中属于较高层次的要求。" + }, + { + "idx": 3357, + "question": "Classify according to the interaction between alloying elements and carbon, and indicate which elements are weak carbide-forming elements", + "answer": "Weak carbide-forming elements: manganese", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对合金元素与碳的相互作用进行分类，并指出哪些是弱碳化物形成元素，需要文字解释和论述，而不是简单的选择或判断。答案也以文字形式给出，符合简答题的特征。 | 知识层次: 题目考查对合金元素与碳相互作用分类的基础概念记忆，特别是弱碳化物形成元素的识别，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅要求记忆和识别弱碳化物形成元素（锰），属于基础概念记忆层次。题目直接给出正确选项，无需复杂推理或概念比较，符合等级1的基本定义简答标准。" + }, + { + "idx": 3359, + "question": "Classify according to the interaction between alloying elements and carbon, and indicate which elements do not form carbides", + "answer": "Non-carbide forming elements: nickel, silicon, cobalt, aluminum, copper, boron, nitrogen, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对合金元素与碳的相互作用进行分类，并列举不形成碳化物的元素，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对合金元素与碳相互作用分类的基础概念记忆，以及非碳化物形成元素的列举，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别并回忆非碳化物形成元素的列表。题目直接给出了正确选项，无需进行复杂的概念比较或推理分析，符合等级1“基本定义简答”的标准。" + }, + { + "idx": 3360, + "question": "When hypereutectoid steel is slowly cooled from the austenite region, secondary cementite will precipitate along the austenite grain boundaries in a network form. How can the network cementite be eliminated by heating above Ac cm followed by air cooling and subsequent treatment?", + "answer": "Heating above Ac cm followed by air cooling to obtain a pseudo-eutectoid structure, then performing high-temperature tempering or spheroidizing annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的处理步骤和后续处理方法，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解过共析钢的冷却过程及二次渗碳体的形成机制，并应用热处理工艺（加热至Ac cm以上、空冷、高温回火或球化退火）来消除网状渗碳体。这涉及多步操作和概念关联，但不需要复杂的推理或创新设计。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及多个热处理步骤的综合应用，包括加热、冷却和后续处理，需要考生对每个步骤的作用和相互关系有深入理解。其次，正确选项要求考生能够将伪共析组织形成原理与高温回火或球化退火工艺联系起来，这需要较强的概念关联能力。此外，题目考察的是对网络状渗碳体消除方法的综合分析能力，而非单一知识点的简单记忆，在选择题型中属于需要多角度分析论述的复杂题目。" + }, + { + "idx": 3361, + "question": "What are the ways to improve the strength of materials", + "answer": "The strengthening effects of alloying elements in steel mainly include the following four methods: solid solution strengthening, grain boundary strengthening, second-phase strengthening, and dislocation strengthening. By applying these four methods individually or in combination, the strength of steel can be effectively improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述提高材料强度的多种方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释和论述提高材料强度的四种方法，涉及多个概念的关联和综合分析，需要理解不同强化机制的相互作用和应用场景，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解材料强化的基本概念（如固溶强化、晶界强化等），还需要综合掌握这些方法在钢铁材料中的具体应用和相互作用。正确选项涉及多个知识点的关联分析，且需要考生能够区分不同强化机制的特点和效果。这种综合分析能力在选择题型中属于多角度分析论述的层次，因此难度等级为4。" + }, + { + "idx": 3362, + "question": "Discuss the factors affecting the plasticity of materials", + "answer": "The main factors affecting the plasticity of steel include: (1) the influence of solute atoms; (2) the influence of grain size; (3) the influence of the second phase; (4) the influence of dislocation strengthening, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论影响材料塑性的因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论影响材料塑性的因素，涉及多个概念（如溶质原子、晶粒尺寸、第二相、位错强化等）的关联和综合分析，需要理解这些因素如何相互作用并影响材料的塑性行为，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解影响材料塑性的基本概念，还需要综合多个因素进行分析。正确选项涵盖了四个主要影响因素（溶质原子、晶粒尺寸、第二相、位错强化），这要求考生能够将这些概念关联起来，并进行多角度分析。虽然题目提供了正确选项，但选项内容涉及的知识点较为深入，需要考生具备一定的综合分析能力，因此在选择题型中属于较高难度。" + }, + { + "idx": 3363, + "question": "Discuss the factors affecting the strength of materials", + "answer": "The mechanical properties of materials are related to their chemical composition, internal microstructure, inclusions and surface microstructure, as well as stress state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论影响材料强度的因素，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求讨论影响材料强度的因素，涉及多个知识点的关联和综合分析，如化学成分、内部微观结构、夹杂物和表面微观结构等，需要理解这些因素如何相互作用影响材料强度，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解材料强度的基本概念，还需要综合分析多个影响因素（化学组成、内部微观结构、夹杂物、表面微观结构、应力状态）之间的关联性。这超出了单一概念的记忆或简单应用，属于多角度分析论述的层次，符合等级4的标准。" + }, + { + "idx": 3364, + "question": "Classify according to the interaction between alloying elements and carbon, and indicate which elements are strong carbide-forming elements. What are the performance characteristics of strong carbides?", + "answer": "Strong carbide-forming elements: titanium, zirconium, vanadium, niobium. Strong carbides are relatively stable, with high melting points, high hardness, and relatively high brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求分类并指出强碳化物形成元素，并解释强碳化物的性能特征。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对合金元素与碳相互作用分类的记忆，以及强碳化物形成元素的列举和性能特征的描述，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（强碳化物形成元素及其性能特点），但正确选项已经明确列出了具体的元素和性能特征，不需要考生进行复杂的比较分析或推导。主要考察的是对基础概念的记忆和理解，属于\"概念解释和描述\"层次。" + }, + { + "idx": 3365, + "question": "What is alloy cementite, and how does its performance compare with cementite", + "answer": "Alloy cementite is formed when alloying elements dissolve into cementite. Alloy cementite has higher stability than ordinary cementite and exhibits a more significant strengthening effect on the steel matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是合金渗碳体，并比较其性能与普通渗碳体的差异，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对合金渗碳体的基本定义和性能比较的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅知道合金渗碳体的定义，还需要理解其与普通渗碳体的性能比较。这涉及到基础概念的记忆和简单比较分析，属于概念解释和描述的层次，但不需要复杂的推理或多概念整合。" + }, + { + "idx": 3366, + "question": "Why can shot peening and surface rolling significantly improve the fatigue limit of materials?", + "answer": "Shot peening and surface rolling can create a very thin work-hardened layer on the surface of the workpiece, which not only has a higher yield limit but also contains significant compressive stress (400-500 MPa). This weakens the effect of tensile stress on the surface and delays the formation of surface cracks, thereby significantly improving the fatigue limit of the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么喷丸和表面滚压能显著提高材料的疲劳极限，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要解释shot peening和surface rolling如何通过产生work-hardened层和压缩应力来改善材料的疲劳极限，这涉及到多个概念的关联和机理解释，需要综合运用材料科学的知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解表面处理工艺（喷丸和表面滚压）的基本作用，还需要深入掌握这些工艺如何通过形成加工硬化层和引入残余压应力来影响材料的疲劳极限。此外，题目还要求考生能够将这些机理与疲劳性能的改善联系起来，进行综合分析和推理。这种题目需要考生具备较高的知识整合能力和机理解释能力，属于复杂现象全面分析的层次。" + }, + { + "idx": 3367, + "question": "Describe the role of alloying elements in ordinary low-alloy steels", + "answer": "Adding alloying elements such as manganese is to improve the strength of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述合金元素在普通低合金钢中的作用，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对合金元素在普通低合金钢中作用的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求记忆合金元素（如锰）在普通低合金钢中的作用（提高强度），属于单一知识点的直接回忆，无需解释或分析多个概念。选择题的正确选项直接提供了明确答案，解题步骤简单，符合等级1对基础概念记忆的要求。" + }, + { + "idx": 3368, + "question": "What elements are commonly used to improve hardenability?", + "answer": "Cr, Ni, Mn, Si, B", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举常见的元素来改善淬透性，答案是一系列元素符号，属于需要列举或简要回答的简答题类型 | 知识层次: 题目考查对常见合金元素及其作用的记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，此题属于基础概念记忆的简单题目。只需记住常见的提高淬透性元素（Cr, Ni, Mn, Si, B）即可作答，不需要进行概念解释或复杂分析。题目仅考察对基本元素的记忆，属于最基础的选择题难度等级。" + }, + { + "idx": 3369, + "question": "Discuss the approaches to improve the plasticity of materials", + "answer": "Approaches to improve plasticity: (1) Adding small amounts of alloying elements such as titanium and vanadium to steel can fix carbon and nitrogen and form carbides or nitrides, thereby improving the plasticity of steel. (2) Refining grain size is beneficial for enhancing plasticity. (3) When strengthening with a second phase, the quantity, size, shape, and distribution of carbides can be controlled by combining alloying with tempering and spheroidization treatments; reducing the number of inclusions in steel and controlling their morphology. (4) When strengthening through cold deformation, adding trace elements such as titanium, vanadium, and zirconium to fix interstitial atoms and prevent their segregation to dislocations can improve the plasticity of steel to some extent.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论提高材料塑性的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论提高材料塑性的方法，涉及多种技术手段的综合应用，如合金元素添加、晶粒细化、第二相强化和冷变形强化等。需要理解这些方法的原理及其对材料性能的影响，并进行综合分析。虽然不涉及复杂的计算或深度机理分析，但需要将多个概念关联起来，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解材料塑性的基本概念，还需要掌握多种改善塑性的具体方法及其背后的原理。题目涉及的知识点包括合金元素的作用、晶粒细化、第二相强化以及冷变形强化等多个方面，需要考生进行多角度分析和综合论述。此外，解题步骤较为复杂，需要考生将不同概念关联起来，并理解它们之间的相互作用。因此，在选择题型内，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 3370, + "question": "Why are carburizing steels mostly used to manufacture gears for automobile and tractor gearboxes and rear axle gears?", + "answer": "Their working conditions are demanding, requiring high toughness in the core and high hardness on the surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么渗碳钢主要用于制造汽车和拖拉机变速箱齿轮和后桥齿轮，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解渗碳钢的特性及其在特定工作条件下的应用，涉及材料性能与工作要求的关联分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及对渗碳钢性能的理解，以及其在特定应用场景（汽车和拖拉机变速箱齿轮、后桥齿轮）中的优势。正确选项要求考生能够将材料性能（芯部高韧性和表面高硬度）与工作条件（苛刻的工作环境）联系起来，进行综合分析。虽然不需要复杂的计算，但需要对材料科学和应用场景有较深入的理解。" + }, + { + "idx": 3371, + "question": "What is the reason why alloying elements improve hardenability?", + "answer": "It shifts the C-curve to the right and reduces the critical cooling rate for quenching", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素提高淬透性的原因，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目不仅需要理解合金元素对淬透性的影响，还需要解释其背后的机理（C曲线右移和临界冷却速率降低），这涉及到对相变动力学和合金元素作用的综合分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3372, + "question": "What are the ways to improve the strength and toughness of mild steel?", + "answer": "The way to improve is solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述提高低碳钢强度和韧性的方法，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释和论述提高低碳钢强度和韧性的方法，涉及多个概念（如固溶强化）的关联和综合分析，需要多步思维过程来理解和应用这些概念。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及的知识点（固溶强化）属于中等应用层次，需要考生将材料强化机制与具体材料（低碳钢）的性能改善方法进行关联。虽然不涉及多步计算，但要求考生在选项分析时能综合判断不同强化方式的适用性，符合等级3的综合分析要求。" + }, + { + "idx": 3373, + "question": "What is the reason why alloying elements improve the tempering stability of steel?", + "answer": "Non-carbide forming elements have the effect of delaying the decomposition of martensite. This is because they can dissolve into ε-carbide and stabilize it, slowing down the aggregation rate of carbides. Compared to carbon steel, the final decomposition temperature of martensite may be delayed to 350-500℃, which is 100-150℃ higher than that of carbon steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素提高钢的回火稳定性的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释合金元素提高钢的回火稳定性的机理，涉及非碳化物形成元素对马氏体分解的延迟作用、ε-碳化物的稳定化以及碳化物聚集速率的减缓等复杂过程。这需要综合运用材料科学中的相变理论、合金化原理和热力学知识，进行深入的推理分析和机理解释。 | 难度: 在选择题中属于最高难度等级，题目要求考生深入理解合金元素对钢回火稳定性的影响机理，包括非碳化物形成元素如何延迟马氏体分解、稳定ε碳化物以及减缓碳化物聚集速率等复杂现象。需要综合运用材料科学知识进行推理分析，并解释背后的物理冶金原理，这远超出简单记忆或基础理解的范畴。" + }, + { + "idx": 3374, + "question": "What elements are commonly used to improve the tempering stability of steel?", + "answer": "Common elements: Si, Co.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举常见的用于提高钢的回火稳定性的元素，答案以简短的文字形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目考查对钢的回火稳定性改善常用元素的基本记忆，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆常见的用于提高钢的回火稳定性的元素（Si、Co），属于基础概念记忆的范畴。题目不涉及复杂的概念解释或体系阐述，解题步骤简单直接，只需回忆相关知识即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3375, + "question": "Compare the heat treatment process characteristics of hot work die steel and alloy quenched and tempered steel.", + "answer": "The heat treatment processes for both are quenching + high temperature tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种钢材的热处理工艺特点，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求比较两种钢材的热处理工艺特点，需要理解并关联不同材料的热处理工艺知识，进行综合分析。虽然答案给出了基本的热处理流程，但完整的回答需要解释两种钢材在热处理过程中的具体差异和原因，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解热作模具钢和合金调质钢的热处理工艺特点，并进行比较分析。虽然题目给出了正确选项，但学生仍需掌握两种材料的热处理工艺知识，并能识别其共同点（淬火+高温回火）。这涉及多步概念关联和综合分析能力，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3376, + "question": "What are the characteristics of the heat treatment process for high-speed steel?", + "answer": "The most prominent features of the process are the very high quenching heating temperature, high tempering temperature, multiple tempering cycles, and the use of preheating during quenching heating.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释高速钢热处理过程的特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目要求解释高速钢热处理工艺的特点，涉及多个工艺参数（淬火加热温度、回火温度、多次回火循环等）的综合分析，需要理解各参数之间的关系及其对材料性能的影响，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解高速钢热处理过程中的多个关键特征（如高淬火温度、高回火温度、多次回火循环和预热使用），并将这些概念关联起来进行综合分析。虽然题目不涉及计算，但需要对热处理工艺有较深入的理解才能正确选择答案。" + }, + { + "idx": 3377, + "question": "Why are 40CrNiMo and 37SiMnCrMoV steels (25mm in diameter) in the normalized state difficult to machine? Please consider the most economical method to improve machinability.", + "answer": "The high carbon content and the presence of alloying elements result in excessive hardness in the normalized state, making machining difficult. The most economical method to improve machinability is annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么特定钢材在正火状态下难以加工，并提出经济有效的改进方法。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解合金钢在正火状态下的硬度问题，并分析其对加工性能的影响。同时，需要综合考虑经济性和加工性能改进方法（退火），涉及多步分析和概念关联。虽然不涉及复杂计算，但需要对材料性能和热处理工艺有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及钢材的化学成分、热处理状态对加工性能的影响，以及改善加工性能的经济方法。虽然不需要复杂的计算，但需要综合理解材料科学中的几个关键概念，并能够将它们关联起来做出正确选择。" + }, + { + "idx": 3378, + "question": "How to select the microstructure state of steel for machine parts based on their service conditions?", + "answer": "For less critical parts where the comprehensive mechanical properties are not highly demanded, normalize to obtain ferrite + pearlite. For parts requiring good surface wear resistance and high contact fatigue resistance, while the entire part bears impact loads and the core demands higher toughness, carburizing, quenching, and low-temperature tempering can be applied, resulting in a surface of martensite with high hardness and wear resistance, and a core of ferrite + pearlite with higher toughness. For parts requiring higher comprehensive mechanical properties, apply quenching and tempering to obtain tempered sorbite. Carbon steels and alloy steels with relatively high carbon content can be used to manufacture springs, and the heat treatment process of quenching and medium-temperature tempering should be adopted to achieve tempered troostite. Bearings should be made of rolling bearing steel, treated with quenching and low-temperature tempering to obtain tempered martensite with high hardness and wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于服务条件选择钢的微观结构状态，答案提供了详细的文字解释和论述，涉及不同零件和热处理工艺的选择，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据不同的服役条件选择钢材的微观组织状态，涉及多个热处理工艺和对应的组织性能关系，需要综合分析不同工艺对材料性能的影响，并关联具体应用场景。虽然不涉及复杂计算，但需要多步概念关联和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生根据不同的服役条件选择钢材的微观组织状态，涉及多个知识点和复杂的综合分析。考生需要理解不同热处理工艺（如正火、渗碳淬火、调质等）对钢材微观组织和力学性能的影响，并能将这些知识与具体零件的服役条件（如耐磨性、疲劳抗力、冲击载荷等）关联起来。此外，题目还要求考生能够区分不同零件（如弹簧、轴承）的特殊要求，并选择相应的热处理工艺和组织状态。这种多角度分析和概念关联的要求使得该题目在选择题型中具有较高的难度。" + }, + { + "idx": 3379, + "question": "What is the role of carbon and alloying elements in high-speed steel?", + "answer": "The purpose of high carbon content is to form carbides with carbide-forming elements such as Cr, W, Mo, and V, and to ensure a strong martensitic matrix to enhance the hardness and wear resistance of the steel. W, Mo, and V primarily improve the red hardness of the steel, as the carbides formed by these elements have high hardness and produce a 'secondary hardening' effect, thereby significantly enhancing the steel's red hardness, hardness, and wear resistance. Cr mainly improves the hardenability of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释碳和合金元素在高速钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释碳和合金元素在高速钢中的作用，涉及多个元素的协同效应和机理解释，需要综合分析不同元素对钢性能的影响，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解高碳钢和合金元素的基本作用，还需要综合分析不同元素（如Cr、W、Mo、V）在高速钢中的具体功能及其相互作用。题目涉及多个概念（如碳化物形成、马氏体基体、红硬性、二次硬化效应等），并要求考生将这些概念关联起来，进行多角度分析。此外，解题步骤较为复杂，需要考生具备较强的材料科学知识背景和综合分析能力。" + }, + { + "idx": 3380, + "question": "Describe the role of carbon in low-alloy steel", + "answer": "Low carbon content is to ensure the plasticity, toughness and weldability of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述碳在低合金钢中的作用，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对碳在低合金钢中作用的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求记忆碳在低合金钢中的基本作用，属于基础概念记忆层次。正确选项直接给出了明确的定义性描述（低碳含量确保塑性、韧性和可焊性），无需分析或推理过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3381, + "question": "Why are medium carbon (alloy) steels mostly used to manufacture gearbox gears for machine tools?", + "answer": "Their working conditions are much better than those of automobiles, requiring certain toughness in the core and higher hardness on the surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么中碳（合金）钢主要用于制造机床齿轮箱齿轮，答案提供了文字解释和论述，说明其工作条件和性能要求，符合简答题的特征。 | 知识层次: 题目需要结合材料科学中的碳钢性能特点（如韧性、硬度）与具体应用场景（齿轮箱齿轮的工作条件）进行综合分析，涉及多概念关联和中等程度的推理分析。 | 难度: 在选择题中属于较高难度，题目涉及多个概念的综合分析，包括材料性能（韧性、硬度）、工作条件比较（机床齿轮箱与汽车齿轮的差异）以及材料选择依据。解题需要将材料科学知识与工程应用场景进行多角度关联，并理解表面处理与核心性能的不同要求。这种需要跨领域知识整合的题目在选择题型中属于较复杂类型。" + }, + { + "idx": 3382, + "question": "How to select the carbon content in steel for machine parts based on their service conditions?", + "answer": "For non-critical parts with low requirements for comprehensive mechanical properties, medium carbon steel can be selected. For parts requiring good surface wear resistance and high contact fatigue resistance, while the entire part withstands impact loads and the core requires high toughness, carburizing steel, i.e., low carbon steel or low carbon alloy steel, should be selected. For parts requiring high comprehensive mechanical properties, quenched and tempered steel, i.e., medium carbon steel or medium carbon alloy steel, should be selected. Carbon steel and alloy steel with higher carbon content can be used to manufacture springs. Bearings should be made of rolling bearing steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于服务条件选择钢材的碳含量，答案提供了详细的文字解释和论述，说明不同工况下应选择的钢材类型及其原因，符合简答题的特征。 | 知识层次: 题目要求根据不同的服役条件选择钢材的碳含量，涉及多个概念的综合应用和分析，如机械性能、磨损抵抗、疲劳抵抗等，需要将材料性能与使用条件关联起来进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解不同碳含量钢材的基本特性，还需要根据具体的服务条件（如非关键部件、表面耐磨性要求、冲击载荷承受能力、核心韧性需求等）进行多角度分析和综合判断。题目涉及多个概念关联和综合分析步骤，需要考生具备较强的知识应用能力和逻辑推理能力，因此在选择题型内属于等级4的难度。" + }, + { + "idx": 3383, + "question": "Compare the alloying characteristics of hot-work die steel and alloy quenched and tempered steel, and analyze the similarities and differences in the roles of alloying elements.", + "answer": "The main alloying elements (Si, Mn, Cr, Ni, B, etc.) in quenched and tempered steel primarily enhance the hardenability of the steel; the auxiliary elements (W, Mo, V, Ti) mainly refine the austenite grain size, thereby refining the ferrite grain size in tempered sorbite. Hot-work die steel often contains alloying elements such as Cr, Mn, Si, Mo, W, and V to improve the steel's hardenability, tempering stability, and wear resistance, while also suppressing secondary temper brittleness. Cr, Si, and W enhance fatigue resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较和分析两种钢材的合金化特性，并详细解释合金元素的作用，这需要详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较和分析两种钢材的合金化特性，涉及多种合金元素的作用机理及其对材料性能的影响，需要综合运用材料科学知识进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用材料科学知识，对两种不同类型钢的合金化特性进行深入比较和分析。需要考生掌握合金元素在钢中的作用机理（如提高淬透性、细化晶粒、提高回火稳定性等），并能区分主合金元素和辅助元素的不同功能。此外，题目还涉及复杂的材料性能关系（如疲劳抗力、二次回火脆性等），要求考生具备高阶的分析推理能力。在选择题型中，这种需要综合多个知识点并进行机理解释的题目最具挑战性。" + }, + { + "idx": 3384, + "question": "What is the approximate quenching process in the manufacturing route of round dies made from 9SiCr steel?", + "answer": "Quenching process: Heating temperature 850-870°C (oil quenching).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释具体的淬火工艺参数，答案以文字形式给出具体温度范围和淬火介质，属于需要文字解释的简答题类型 | 知识层次: 题目考查的是特定材料（9SiCr钢）在特定工艺（淬火）中的具体参数（加热温度850-870°C，油淬）的应用，属于直接套用工艺知识的简单应用层次，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用已知的淬火工艺参数（850-870°C油淬）即可作答，无需复杂计算或概念分析。题目考察的是对基础工艺参数的记忆能力，符合等级2“简单应用过程描述”的标准。" + }, + { + "idx": 3385, + "question": "The large screwdriver requires the shank to be fine pearlite and the tip to be tempered martensite, with only one external heat source. How should it be processed?", + "answer": "Overall normalizing, local quenching + low-temperature tempering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过热处理工艺实现螺丝刀不同部位的组织要求，答案提供了具体的处理步骤，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求综合运用热处理知识（正火、局部淬火+低温回火）来解决实际问题，需要理解不同热处理工艺对材料微观组织的影响，并进行推理分析以实现特定部位的不同性能要求。这涉及多步骤的工艺设计和综合分析能力，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3386, + "question": "What is the purpose of quenching and tempering in the process route of making round dies from 9SiCr steel?", + "answer": "Quenching and tempering are to obtain tempered martensite, ensuring high hardness and high wear resistance after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火和回火在9SiCr钢制圆模工艺路线中的目的，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及热处理工艺的具体应用，需要理解淬火和回火的目的及其对材料性能的影响，属于中等应用层次。虽然不涉及复杂计算，但需要将多个概念关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解淬火和回火的基本概念，并能够关联到具体的材料（9SiCr钢）和应用场景（圆形模具）。题目要求考生综合理解热处理工艺的目的和效果，即通过淬火和回火获得回火马氏体，从而确保高硬度和高耐磨性。这需要一定的概念关联和综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3387, + "question": "The bolts on the gear hobbing machine should have been made of 45 steel, but T12 steel was mistakenly used, and the annealing process for 45 steel was followed. What structure will be obtained in this case? What will be the performance?", + "answer": "Annealing: The structure will be lamellar pearlite and networked carbides. Steel with such a structure is prone to deformation and cracking during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下材料的结构和性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解不同钢材（45钢和T12钢）的性质差异，并分析在错误的热处理工艺（45钢的退火工艺应用于T12钢）下会产生的组织结构和性能变化。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于较高难度，需要综合理解材料科学中的多个概念（如钢种特性、热处理工艺、组织结构与性能关系），并能够将错误材料选择与错误工艺步骤的后果进行关联分析。题目要求考生不仅识别出T12钢与45钢的差异，还要预测在错误工艺下会形成的具体组织结构（层状珠光体+网状碳化物）及其对机械性能的影响（淬火时易变形开裂），这需要多步骤的逻辑推理和综合分析能力。" + }, + { + "idx": 3388, + "question": "The bolts on the gear hobbing machine should have been made of 45 steel, but T12 steel was mistakenly used. The high-temperature tempering process for 45 steel was still applied. What microstructure will be obtained in this case? What will be the performance?", + "answer": "High-temperature tempering: The microstructure consists of coarse tempered sorbite and retained austenite; Performance: Poor toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料在特定热处理条件下的微观结构和性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解不同钢材（45钢和T12钢）在高温回火后的显微组织和性能变化，涉及材料选择错误导致的显微组织差异及其对性能的影响。这需要多步分析和概念关联，包括对钢材成分、热处理工艺和显微组织之间关系的理解，以及对性能影响的综合分析。 | 难度: 在选择题中属于较高难度，需要综合理解材料科学中的多个概念（如钢种特性、热处理工艺、显微组织与性能关系），并分析错误材料选择与工艺应用导致的非预期结果。题目要求考生不仅掌握45钢和T12钢的本质区别（共析钢与过共析钢），还需预判错误热处理工艺（高温回火）对T12钢显微组织（粗大回火索氏体+残余奥氏体）和力学性能（韧性恶化）的影响，涉及多步骤逻辑推理和跨知识点关联分析。" + }, + { + "idx": 3389, + "question": "What is the general process of spheroidizing annealing in the manufacturing process of round dies made from 9SiCr steel?", + "answer": "Spheroidizing annealing process: heating temperature 790-810°C, isothermal temperature 700-720°C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释球化退火的一般过程，答案提供了具体的温度参数，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查的是球化退火工艺的具体参数设置，需要理解工艺原理并关联具体材料（9SiCr钢）的应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及具体的工艺参数（加热温度和等温温度），需要考生对9SiCr钢的球化退火工艺有基本了解，并能将理论知识与实际工艺参数对应起来。虽然不需要复杂的计算，但需要对材料热处理工艺有综合理解才能正确选择答案。" + }, + { + "idx": 3390, + "question": "What is the approximate tempering process in the process route of round dies made of 9SiCr steel?", + "answer": "Tempering process: 160-180°C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释9SiCr钢制圆模的回火工艺温度范围，答案给出了具体的温度区间（160-180°C），属于需要简要回答具体参数的简答题形式。 | 知识层次: 题目考查对9SiCr钢回火工艺温度范围的基础记忆，属于材料热处理工艺中的基本参数知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅要求记忆特定钢种（9SiCr）的特定热处理工艺参数（回火温度范围160-180°C），属于基础概念记忆层面的单一知识点考察。题目不涉及概念解释、工艺原理分析或复杂工艺路线比较，完全符合等级1\"基本定义简答\"的特征。选择题型中此类题目只需识别正确数值即可作答，对认知层次的要求最低。" + }, + { + "idx": 3391, + "question": "A batch of carbon tool steel workpieces were found to have insufficient hardness after quenching. It is estimated that either surface decarburization occurred or the cooling rate during quenching was too low. How to quickly determine the cause of the problem.", + "answer": "Metallographic examination.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来快速确定问题的原因，答案“Metallographic examination”是一个简短的解决方案描述，属于需要文字解释的简答题类型。 | 知识层次: 题目要求通过金相检验来快速确定硬度不足的原因，这需要将金相检验的基本原理与实际问题的分析相结合，属于中等应用层次。虽然金相检验本身是基础概念，但如何将其应用于具体问题的诊断需要一定的综合分析能力，涉及多步思考和概念关联。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及碳工具钢淬火后硬度不足的两个可能原因（表面脱碳或淬火冷却速率过低），要求考生通过金相检验快速确定原因。这需要考生具备材料科学基础知识，能够将金相检验方法与问题原因关联起来，并进行综合分析判断。虽然不需要多步计算，但需要概念关联和综合分析能力，因此在选择题型中属于等级3难度。" + }, + { + "idx": 3392, + "question": "What is the purpose of spheroidizing annealing in the process route of making round dies with 9SiCr steel?", + "answer": "Spheroidizing annealing is to eliminate forging stress, obtain spheroidized pearlite and carbides, reduce hardness to facilitate machining, prepare the microstructure for quenching, and minimize deformation and cracking during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释spheroidizing annealing的目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对球化退火工艺目的的理解和应用，需要将材料热处理的基本原理与实际工艺需求相结合，分析球化退火在特定钢种（9SiCr）和特定用途（圆形模具）中的作用。这涉及多步骤的工艺理解，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解球化退火的基本概念，还需要综合分析其在9SiCr钢制圆模加工工艺路线中的多重目的（消除锻造应力、获得球状珠光体和碳化物、降低硬度便于加工、为淬火准备组织、减少淬火变形和开裂）。这需要考生将材料热处理原理与具体工艺应用深度关联，属于多角度分析论述的层次。" + }, + { + "idx": 3393, + "question": "Briefly describe the alloying principle of stainless steel.", + "answer": "Alloying principle: Adding alloying elements to form a stable, dense, and strong protective film on the surface of the steel, obtaining a single-phase structure in the steel, and increasing the electrode potential of the solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述不锈钢的合金化原理，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查不锈钢合金化原理的基本概念记忆和理解，涉及合金元素的作用和形成保护膜的基本原理，属于基础概念层次。 | 难度: 在选择题型中，该题目要求考生理解并描述不锈钢的合金化原理，涉及基础概念的记忆和简单解释。虽然需要掌握一定的专业术语和基本原理，但不需要复杂的分析或比较，属于概念解释和描述的难度等级。" + }, + { + "idx": 3394, + "question": "The bolts on the gear hobbing machine should have been made of 45 steel, but T12 steel was mistakenly used instead, and the quenching process for 45 steel was still applied. What microstructure will be obtained in this case? What will the properties be like?", + "answer": "Quenching: The microstructure will consist of martensite, a significant amount of retained austenite, and a small amount of carbide. Properties: Martensite is hard and brittle, retained austenite has low hardness, resulting in non-uniform properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下（错误使用T12钢并应用45钢的淬火工艺）会得到何种微观结构及其性能特点，答案需要详细的文字描述和论述，而非选择、判断或计算。 | 知识层次: 题目要求分析不同钢材在错误热处理工艺下的显微组织和性能变化，涉及多个概念的综合应用和关联分析，需要理解材料成分、热处理工艺与显微组织之间的关系，并进行一定的推理和解释。 | 难度: 在选择题中属于较高难度，需要综合理解材料科学中的多个概念（如不同钢材的淬火特性、马氏体和残余奥氏体的形成条件及其对性能的影响），并进行多步分析和关联。题目要求考生不仅知道T12钢和45钢的区别，还要预测在错误工艺下得到的微观组织及其性能影响，这需要较深的知识掌握和综合分析能力。" + }, + { + "idx": 3395, + "question": "Why is Cr12MoV steel not stainless steel?", + "answer": "Because Cr is the main factor that makes steel corrosion-resistant. It can increase the electrode potential of steel. If its mass fraction is small (below 13 %), the electrode potential cannot be significantly increased, nor can a single-phase structure be formed, so the corrosion resistance of the steel cannot be significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Cr12MoV钢不是不锈钢，答案提供了详细的文字解释和论述，涉及Cr含量对钢的耐腐蚀性能的影响，符合简答题的特征。 | 知识层次: 题目需要理解Cr在钢中的作用机制，并分析其含量对钢的耐腐蚀性能的影响。这涉及到多个概念的关联和综合分析，如Cr的质量分数、电极电位、单相结构形成等，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要理解Cr对钢的耐腐蚀性的影响机制，包括电极电位提升和单相结构形成的条件，并进行多角度分析论述。题目要求考生不仅掌握基本概念，还需要综合分析Cr含量与耐腐蚀性之间的关系，涉及较深层次的材料科学知识。" + }, + { + "idx": 3396, + "question": "After the wire drawing die made of high-carbon high-chromium steel wears out, the inner hole has a slight oversize. What heat treatment can be used to reduce the inner hole diameter?", + "answer": "Water quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述使用何种热处理方法来减小内孔直径，答案需要文字解释和论述，而不是从多个选项中选择或简单的对错判断。 | 知识层次: 题目要求根据特定材料（高碳高铬钢）和特定情况（拉丝模内孔轻微超差）选择合适的淬火工艺（水淬），需要理解材料的热处理原理和工艺选择的基本知识，并能够将理论知识应用于具体问题中。这涉及到多步思考和概念关联，但不需要复杂的分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解高碳高铬钢的热处理特性以及拉丝模具磨损后的修复方法。题目要求考生综合分析材料的热处理工艺（如水淬）对尺寸变化的影响，并关联到实际应用场景中的问题解决。虽然不需要多步计算，但需要对材料科学和热处理工艺有较深的理解才能正确选择水淬作为解决方案。" + }, + { + "idx": 3397, + "question": "Why can't Cr12MoV steel be turned into stainless steel through heat treatment?", + "answer": "Because Cr is the main factor that makes steel corrosion-resistant. It can increase the electrode potential of the steel. If its mass fraction is small (below 13 %), the electrode potential cannot be significantly increased, nor can a single-phase structure be formed, so the corrosion resistance of the steel cannot be significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Cr12MoV钢不能通过热处理变成不锈钢，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释Cr12MoV钢不能通过热处理转变为不锈钢的原因，涉及Cr元素对钢的耐腐蚀性能的影响机制，包括电极电位的变化和单相结构的形成条件。这需要综合运用材料科学中的合金元素作用原理、热处理对组织性能的影响以及腐蚀机制等多方面知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3398, + "question": "Analyze the special effects of alloying elements (such as Cr, Mo, W, etc.) on improving the thermal strength of steel", + "answer": "Alloying elements (Cr, Mo, W, etc.) can increase the recrystallization temperature of steel, thereby improving its thermal strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析合金元素对钢热强度的特殊影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析合金元素（如Cr、Mo、W等）对提高钢热强度的特殊效应，这需要综合运用材料科学知识，理解合金元素对钢的再结晶温度的影响机制，并进行推理分析。这涉及到多个概念的关联和深层次的机理解释，超出了简单记忆或基本应用的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握合金元素（Cr、Mo、W等）的基本作用，还需要深入理解这些元素如何通过提高钢的再结晶温度来增强热强度的机理。这涉及到对材料科学中复杂现象的全面分析，包括合金元素与钢基体之间的相互作用、热力学和动力学过程的综合理解。此外，正确选项的表述需要考生能够将多个知识点整合并进行推理分析，这在选择题型中属于对知识深度和综合运用能力要求极高的题目。" + }, + { + "idx": 3399, + "question": "How is the range of high, medium, and low carbon steels usually divided?", + "answer": "High carbon steel: wC>0.60%, medium carbon steel: wC=0.25%~0.60%, low carbon steel: wC≤0.25%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释高、中、低碳钢的范围划分，答案提供了具体的文字说明和数值范围，属于需要文字解释的简答题类型。 | 知识层次: 题目考查对高、中、低碳钢分类标准的基本概念记忆，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆高、中、低碳钢的碳含量范围划分，属于基础定义简答。题目仅涉及单一知识点的直接回忆，无需解释或复杂分析，符合等级1的难度标准。" + }, + { + "idx": 3400, + "question": "Analyze the special role of alloying elements (such as Cr, Si, Al, etc.) in improving the thermal stability of steel", + "answer": "Alloying elements (Cr, Si, Al, etc.) form dense protective oxide films at high temperatures, preventing the oxidation of steel and thereby enhancing thermal stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析合金元素在提高钢的热稳定性中的特殊作用，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析合金元素在提高钢的热稳定性中的特殊作用，涉及多种合金元素（Cr、Si、Al等）的协同效应和机理解释，需要综合运用材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于机理深度解释难度。正确选项不仅要求考生识别合金元素（Cr、Si、Al等）的作用，还需要理解其形成致密氧化膜的具体机理及其对钢热稳定性的影响。这需要考生具备较深的知识储备和机理分析能力，能够将多个概念（如氧化膜形成、高温防护、热稳定性提升）综合联系起来进行推理解释。虽然题目以选择题形式呈现，但正确选项涉及的知识深度和综合推理要求使其达到等级4的难度水平。" + }, + { + "idx": 3401, + "question": "What elements is carbon steel composed of?", + "answer": "Carbon steel is mainly composed of Fe and C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释碳钢的组成元素，答案提供了简明的文字说明而非选择、判断或计算 | 知识层次: 题目考查碳钢的基本组成元素，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察对碳钢基本组成的记忆，属于最基础的定义简答。题目仅要求识别碳钢的主要成分（Fe和C），不需要任何解释或复杂概念的理解，符合等级1的基本定义简答标准。" + }, + { + "idx": 3402, + "question": "What are the characteristics of carbon steel and alloy steel in terms of performance?", + "answer": "Carbon steel is inferior to alloy steel in mechanical, physical, and chemical properties such as strength, wear resistance, toughness, and corrosion resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释碳钢和合金钢在性能上的特点，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目考查对碳钢和合金钢性能特点的基础概念记忆和理解，属于材料科学中钢材分类和基本性能的入门知识，不涉及复杂分析或综合应用。 | 难度: 该题目属于选择题型，要求考生比较碳钢和合金钢在性能上的特点。虽然涉及多个性能指标（强度、耐磨性、韧性、耐腐蚀性），但只需记忆和识别基本概念差异，无需深入分析或复杂推理。在选择题型中属于中等偏下的难度。" + }, + { + "idx": 3403, + "question": "Why do the dimensions of some measuring tools change during storage and use?", + "answer": "The reason for the dimensional changes of measuring tools during storage and use is: due to the excessive amount of retained austenite after quenching and tempering, stress relaxation occurs during storage and use, causing the retained austenite to transform, thereby leading to dimensional changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么测量工具的尺寸在储存和使用过程中会发生变化，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要解释测量工具尺寸变化的机理，涉及淬火回火后残余奥氏体的应力松弛和相变过程，需要综合运用材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解淬火回火后残余奥氏体的概念，还需要掌握应力松弛和相变机理对尺寸变化的影响机制。解题需要综合运用材料热处理、相变动力学和尺寸稳定性等多方面知识，进行复杂的机理分析和推理判断。这种深度机理解释和复杂现象分析的题目，在选择题型中属于对专业知识和分析能力要求最高的类型。" + }, + { + "idx": 3404, + "question": "What are the commonly used elements in alloy steel?", + "answer": "Alloy steel is mainly composed of elements such as Si, Mn, Cr, Ni, Mo, and V, in addition to Fe and C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举合金钢中常用的元素，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对合金钢常用元素的基本概念记忆，仅需列举常见元素名称，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆合金钢中常用的元素，正确选项直接列出了这些元素（Si, Mn, Cr, Ni, Mo, V, Fe, C），无需进行概念解释或复杂分析。这种类型的题目主要考察学生对基础概念的简单记忆能力，属于选择题型中最基础的难度层次。" + }, + { + "idx": 3405, + "question": "Explain the meaning of the steel grade 4Cr13", + "answer": "4Cr13 is a martensitic stainless steel, wc=0.4%, w=13%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢号4Cr13的含义，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对钢材牌号的基本概念记忆和理解，需要解释牌号中各元素的含义及其含量，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆基本的钢号命名规则和成分含义，属于基础概念记忆层次。正确选项直接给出了钢号4Cr13的碳含量和铬含量，无需复杂分析或推理，符合等级1的基本定义简答标准。" + }, + { + "idx": 3406, + "question": "How is the range of high, medium, and low alloy steels usually divided?", + "answer": "High alloy steel: wMe>10%, medium alloy steel: wMe=5%~10%, low alloy steel: wMe<5%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释高、中、低合金钢的范围划分，答案以文字形式给出具体的百分比范围，属于需要简要回答的简答题类型。 | 知识层次: 题目考查对高、中、低合金钢分类标准的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即高、中、低合金钢的分类标准。正确选项直接给出了具体的百分比范围，无需复杂的推理或分析。学生只需记住这些数值范围即可正确作答，属于最基本的知识点掌握要求。" + }, + { + "idx": 3407, + "question": "What measures can be taken to ensure the long-term dimensional stability of measuring tools?", + "answer": "The method of cold treatment after quenching can be adopted to reduce the amount of retained austenite and achieve long-term dimensional stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出措施来确保测量工具的长期尺寸稳定性，答案提供了具体的处理方法并进行了简要解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释如何通过冷处理来确保测量工具的长期尺寸稳定性，涉及热处理工艺的应用和材料微观组织的控制，需要理解奥氏体残留量对尺寸稳定性的影响，并进行综合分析。这属于中等应用层次，需要将多个概念关联起来并给出具体的工艺措施。 | 难度: 在选择题中属于中等难度，题目涉及热处理工艺中的冷处理概念及其对残余奥氏体的影响，需要考生理解材料科学中的相变原理和尺寸稳定性控制方法。虽然不涉及复杂计算，但要求将多个概念（淬火、冷处理、残余奥氏体、尺寸稳定性）进行关联分析才能正确作答。" + }, + { + "idx": 3408, + "question": "Explain the meaning of the steel grade 16Mn", + "answer": "16Mn is a low-alloy structural steel, wc=0.16%, 10Mn=1.4%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释16Mn钢的含义，答案提供了详细的文字解释和具体成分数据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对钢材牌号16Mn的基本概念记忆和理解，包括其分类（低合金结构钢）和成分（碳含量和锰含量）等基本信息，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别16Mn钢的基本定义和成分信息，属于基础概念记忆层次。题目仅涉及简单的定义和数值记忆，不需要复杂的解释或分析，因此属于最低难度等级。" + }, + { + "idx": 3409, + "question": "Explain the meaning of the steel grade 20CrMnTi", + "answer": "20CrMnTi is a carburizing steel with wc=0.20%, wMn=1%, wCr=0.3%, wC=1.1%, wTi=0.09%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释20CrMnTi钢的含义，答案提供了详细的成分说明和文字解释，符合简答题的特征。 | 知识层次: 题目考查对钢材牌号含义的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目要求考生解释20CrMnTi钢的含义，并给出具体的化学成分。这属于概念解释和描述的层次，需要考生记忆和理解钢号的命名规则及其对应的化学成分范围。虽然涉及多个元素含量的记忆，但整体上仍属于基础概念记忆的范畴，解题步骤相对直接，不需要复杂的分析或比较。因此，在选择题型内属于中等难度。" + }, + { + "idx": 3410, + "question": "Compare the alloying direction of high-temperature structural steel and room-temperature structural steel", + "answer": "The alloying direction of high-temperature structural steel focuses on adding elements that improve thermal strength and thermal stability (such as Cr, Mo, W, Si, Al, etc.), while the alloying direction of room-temperature structural steel pays more attention to improving strength, toughness, and other room-temperature properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种钢材的合金化方向，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种不同类型结构钢的合金化方向，涉及对高温结构钢和室温结构钢合金元素选择的理解和应用。虽然题目不涉及复杂计算，但需要对两种钢的性能要求和合金元素的作用有较深入的理解，并进行综合分析。这属于中等应用层次，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解高温结构钢和室温结构钢的合金化方向，并比较两者之间的差异。题目要求考生掌握相关元素的作用及其在不同温度条件下的应用，涉及多步概念关联和综合分析。" + }, + { + "idx": 3411, + "question": "Explain the meaning of the steel grade 08F", + "answer": "08F is a plain carbon structural steel, wc=0.08% rimmed steel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢号08F的含义，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对钢材牌号基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求考生记忆并识别08F钢的基本定义和成分（wc=0.08%的沸腾钢），属于最基础的概念记忆层次，无需解释或推理过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3412, + "question": "What is the meaning of the commonly referred terms 'ordinary steel', 'quality steel', and 'high-quality steel'?", + "answer": "It mainly refers to the difference in the mass fraction of phosphorus and sulfur. Ordinary steel: $w_{P}\\\\leqslant0.045\\\\%$ $w_{\\\\mathrm{S}}\\\\leqslant0.05\\\\%;$ quality steel: $\\\\scriptstyle w_{\\\\mathrm{P}}\\\\leq0.035\\\\%,w_{\\\\mathrm{S}}\\\\leq0.035\\\\%;$ high-quality steel: $w_{\\\\mathrm{P}}{\\\\le}0.025\\\\%$ $w_{\\\\mathrm{S}}{\\\\leq}0.025\\\\%$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语的含义，答案提供了详细的文字说明和具体数值标准，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对普通钢、优质钢和高级优质钢的定义和分类的记忆，涉及的是基本概念和分类标准，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个术语的定义和分类，但主要考察的是对\"ordinary steel\"、\"quality steel\"和\"high-quality steel\"这三个基本概念的记忆和理解，特别是对磷和硫含量限制的具体数值的记忆。题目没有要求复杂的分析或推理过程，只需正确识别和匹配给定的数值范围与相应的钢材分类即可。因此，在选择题型内属于概念解释和描述的难度等级。" + }, + { + "idx": 3413, + "question": "Explain the meaning of the steel grade T12A", + "answer": "T12A is a carbon tool steel, wc=1.2% high-grade quality steel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢号T12A的含义，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对钢材牌号T12A的基本定义和分类的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆并复述T12A钢的基本定义和成分（碳工具钢，含碳量1.2%的高质量钢），属于最基础的概念记忆层次。不需要进行概念解释或复杂体系阐述，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3414, + "question": "Explain the meaning of the steel grade 9SiCr", + "answer": "9SiCr is a low-alloy tool steel with wc=0.9%, ws=1%, Wc=1.1%, wMn=0.45%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号9SiCr的含义，答案提供了详细的文字解释和成分说明，符合简答题的特征。 | 知识层次: 题目考查对特定钢号9SiCr的基本成分和分类的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释钢号9SiCr的含义，但正确选项已经提供了具体的化学成分和分类信息，考生只需识别和匹配这些关键信息即可。这需要考生对钢号命名规则和基本合金元素有一定记忆，但不需要复杂的分析或推理过程。" + }, + { + "idx": 3415, + "question": "Explain the meaning of the steel grade 1Cr18Ni9Ti", + "answer": "1Cr18Ni9Ti is an austenitic stainless steel, wc=0.1%, wc=18%, WN=9%, wv=0.7%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释1Cr18Ni9Ti钢的含义，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对不锈钢牌号命名规则的基本概念记忆和理解，需要解释牌号中各元素的含义及其含量，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释钢号1Cr18Ni9Ti的含义，但正确选项已经提供了具体的成分和分类信息（奥氏体不锈钢），这属于概念解释和描述的范畴。学生需要记忆并理解钢号中各元素的含义及其对应的含量范围，但不需要进行复杂的分析或推导。因此，该题目在选择题型中属于等级2难度。" + }, + { + "idx": 3416, + "question": "Explain the meaning of the steel grade 3Cr2W8", + "answer": "3Cr2W8V is a hot extrusion die steel with wc=0.3%, wcr=2.5%, ww=8%, and wv=0.3%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢材牌号3Cr2W8的含义，答案提供了详细的成分说明和用途描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对钢材牌号命名规则的基本概念记忆和理解，需要解释各元素符号和数字的含义，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆并识别3Cr2W8V钢的基本成分和用途，属于基础概念记忆的简单题目。不需要复杂的分析或推理，只需直接回忆定义即可作答。" + }, + { + "idx": 3417, + "question": "Explain the meaning of the steel grade Cr12MoV", + "answer": "Cr12MoV is a cold work die steel with wc=1.55%, wc=12%, WM=0.5%, wy=0.25%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释Cr12MoV钢的含义，答案提供了详细的化学成分和用途说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对钢材牌号Cr12MoV的基本定义和成分的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求解释Cr12MoV钢的含义，正确选项直接给出了该钢种的化学成分和基本分类（冷作模具钢），属于基础概念记忆层次的知识点。选择题型中只需识别和匹配定义，无需复杂推理或概念比较，因此属于最低难度等级。" + }, + { + "idx": 3418, + "question": "Explain the meaning of the steel grade 00Cr18Ni10", + "answer": "00Cr18Ni10 is an austenitic stainless steel, with Wc≤0.03%, WCr=18%, WNi=10%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢材牌号00Cr18Ni10的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对不锈钢牌号命名规则的基本概念记忆和理解，需要解释牌号中各元素的含义及其含量范围，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求解释钢号00Cr18Ni10的含义，正确选项直接给出了该钢号的成分和分类（奥氏体不锈钢），属于基础概念记忆层次的知识点。选择题型中，学生只需识别并选择与记忆内容匹配的选项，无需进行复杂的概念分析或推理，因此难度较低。" + }, + { + "idx": 3419, + "question": "Explain the meaning of the steel grade W6Mo5Cr4V2", + "answer": "W6Mo5Cr4V2 is a high-speed steel, wc=0.85%, ww=6%, WMo=5%, wc=4%, wv=3%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号W6Mo5Cr4V2的含义，答案提供了详细的文字解释和成分说明，符合简答题的特征。 | 知识层次: 题目考查对高速钢牌号W6Mo5Cr4V2的基本成分记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生解释特定钢号的成分含义，属于概念解释和描述层次。虽然需要记忆具体的元素含量百分比，但不需要复杂的分析或比较，属于中等偏下的难度。" + }, + { + "idx": 3420, + "question": "Which commonly used alloying elements belong to the γ-phase field narrowing elements?", + "answer": "Niobium, boron, and zirconium narrow the γ-phase field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举常见的合金元素，并解释它们对γ相区的影响，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对γ相区缩小元素的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生掌握γ-phase field narrowing elements的具体分类，并能够正确识别出Niobium、boron和zirconium这三种元素。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 3421, + "question": "Explain the meaning of the steel grade 5CrMnMo", + "answer": "5CrMnMo is a hot forging die steel, wc=0.5%, 0.75Cr, 10Mm=1.4%, wMo=0.25%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钢号5CrMnMo的含义，答案提供了详细的文字解释和成分说明，符合简答题的特征。 | 知识层次: 题目考查对钢材牌号含义的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基本定义简答，仅需记忆钢号5CrMnMo的基本成分和用途，无需进行复杂的概念解释或分析。题目直接给出了钢号的化学成分和用途，属于最基础的概念记忆层次。" + }, + { + "idx": 3422, + "question": "Explain the meaning of the steel grade GCr15SiMn", + "answer": "GCr15SiMn is a rolling bearing steel, wc=1.5%, Wc=1%, wsi=0.5%, WM=1.05%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释GCr15SiMn钢的含义，答案提供了详细的成分说明和文字解释，符合简答题的特征。 | 知识层次: 题目考查对特定钢号（GCr15SiMn）的基本成分和分类的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释钢号GCr15SiMn的含义，但正确选项已经提供了具体的化学成分和用途（滚动轴承钢），这需要考生对钢号命名规则和基本合金元素的作用有一定的记忆和理解。题目涉及的知识点属于基础概念记忆，但需要考生能够将钢号中的字母和数字与具体的化学成分对应起来，并理解其用途，因此比单纯的定义记忆题稍复杂。" + }, + { + "idx": 3423, + "question": "Which commonly used alloying elements belong to the γ-phase expanding elements?", + "answer": "Nickel, manganese, cobalt, carbon, nitrogen, and copper expand the γ-phase region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举γ相扩展元素，答案以文字形式给出具体元素名称，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对γ-phase expanding elements的基本记忆和分类，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅需识别γ相扩展元素的基本分类。选择题型中只需从给定选项中识别正确元素组合，不涉及概念解释或复杂分析，属于最基础的定义识别难度等级。" + }, + { + "idx": 3424, + "question": "Which of these elements can form infinite solid solutions with Fe? What are the conditions?", + "answer": "Manganese, nickel, and cobalt can form infinite solid solutions with γ-Fe. Whether alloying elements expand or contract the γ region mainly depends on factors such as their lattice type, atomic size, electronic structure, and electrochemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪些元素可以与Fe形成无限固溶体，并说明条件，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目不仅需要记忆哪些元素能与γ-Fe形成无限固溶体，还需要理解并解释形成条件（如晶格类型、原子尺寸、电子结构等），涉及多个概念的关联和综合分析。 | 难度: 在选择题中属于较高难度，需要考生掌握γ-Fe的晶体结构特性，理解无限固溶体的形成条件，并能综合分析合金元素对γ相区的影响因素（晶格类型、原子尺寸、电子结构等）。题目不仅考察单一知识点，还要求将多个材料科学概念关联起来进行判断，属于多角度分析论述的层次。" + }, + { + "idx": 3425, + "question": "Which commonly used alloying elements belong to the elements that close the γ region?", + "answer": "Silicon, chromium, tungsten, molybdenum, phosphorus, vanadium, titanium, and aluminum close the γ region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举特定类别的合金元素，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对合金元素分类的基础概念记忆，只需回答哪些元素属于关闭γ区的元素，不涉及复杂分析或应用。 | 难度: 该题目属于选择题型，考察的是对合金元素分类的基础概念记忆。虽然需要记忆多个元素（硅、铬、钨、钼、磷、钒、钛和铝）属于关闭γ区域的元素，但不需要复杂的分析或推理过程。在选择题型中，这属于中等难度，因为需要记住并识别多个相关元素，但不需要深入理解或应用这些概念。" + }, + { + "idx": 3426, + "question": "Explain the meaning of the steel grade 55Si2Mn", + "answer": "55Si2Mn is a spring steel, wc=0.55%, ws=1.75%, WMn=0.75%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号55Si2Mn的含义，答案提供了详细的成分说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对钢号命名规则的基本概念记忆和理解，需要解释钢号中各元素的含义及其含量范围，属于基础知识的直接应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释钢号55Si2Mn的含义，但正确选项已经提供了具体的化学成分和钢种分类，考生只需记忆和理解这些基本信息即可作答。不需要进行复杂的分析或比较多个概念，但需要掌握一定的专业术语和基本概念。" + }, + { + "idx": 3427, + "question": "What is the practical significance of these elements' influence on the γ region?", + "answer": "Its engineering practical significance: For example, to ensure that the steel has good corrosion resistance (such as stainless steel), it is necessary to obtain a single-phase structure at room temperature. This is achieved by applying the above-mentioned principles, controlling the types and amounts of alloying elements to obtain single-phase austenite or ferrite and other single structures in the steel under room temperature conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释元素的γ区域影响的实践意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素对γ区影响的工程实际意义，并举例说明如何通过控制合金元素获得特定单相组织。这需要综合运用材料科学中的相变原理、合金元素作用机制等知识，进行推理分析和实际应用的解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解合金元素对γ区的影响，还需要综合运用材料科学原理进行推理分析，解释如何通过控制合金元素种类和含量来获得特定单相组织（如奥氏体或铁素体），并联系工程实际（如不锈钢的耐腐蚀性）。这种题目需要考生具备深度机理理解和复杂现象分析能力，远超简单记忆或基础概念选择题的难度水平。" + }, + { + "idx": 3428, + "question": "Explain the meaning of the steel grade ZGMn13", + "answer": "ZGMn13 is a high manganese wear-resistant steel, wc=1.15%, wMn=13%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释ZGMn13钢的含义，答案提供了详细的成分和特性描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对特定钢号ZGMn13的基本定义和成分的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆和复述ZGMn13钢的基本定义和成分，属于最基础的概念记忆层次。不需要解释或分析，只需直接回忆并选择正确选项即可。" + }, + { + "idx": 3429, + "question": "What are the differences in heat treatment processes between alloy steel and carbon steel?", + "answer": "Due to the influence of alloying elements on critical temperature, point E, and point S, the heat treatment temperature of alloy steel differs from that of carbon steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢和碳钢在热处理过程中的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较合金钢和碳钢的热处理工艺差异，涉及合金元素对临界温度、E点和S点的影响，需要综合运用材料科学知识进行推理分析，解释不同钢种热处理温度差异的机理。这超出了简单记忆或应用层面，属于需要深度理解和综合分析的内容。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解合金钢和碳钢的热处理差异，还需要掌握合金元素对临界温度、E点和S点的影响机制。这需要综合运用材料科学知识，进行复杂的推理分析，并解释热处理温度差异的深层机理。正确选项涉及多个专业概念的联动关系，远超简单记忆或基础理解的层次，属于复杂现象全面分析的范畴。" + }, + { + "idx": 3430, + "question": "What are the forms of alloying elements in steel?", + "answer": "The forms of alloying elements in steel are: (1) dissolved in ferrite, austenite, or martensite, existing as solute; (2) forming strengthening phases; (3) existing in a free state; (4) forming non-metallic inclusions with impurities such as oxygen, nitrogen, and sulfur in the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释合金元素在钢中的存在形式，答案提供了详细的文字描述和分类，符合简答题的特征。 | 知识层次: 题目考查合金元素在钢中存在形式的基本分类和记忆，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和记忆合金元素在钢中的四种存在形式，包括溶解在铁素体、奥氏体或马氏体中作为溶质、形成强化相、以自由状态存在以及与杂质形成非金属夹杂物。这要求考生不仅记住定义，还需要对合金元素的不同存在形式有一定的理解和分类能力。因此，相较于仅需记忆单一定义的题目（等级1），该题目需要更深入的概念解释和描述能力（等级2）。" + }, + { + "idx": 3431, + "question": "Explain the practical significance of commonly added alloying elements in steel by combining their effects on the heating transformation of steel.", + "answer": "Effect on heating transformation: Alloying elements (except nickel and cobalt) can slow down the austenitization process and inhibit austenite grain growth; Significance: Except for manganese steel, alloy steels are less prone to overheating during heating, which is beneficial for obtaining fine martensite after quenching, appropriately increasing heating temperature to enhance hardenability, and reducing the tendency of deformation and cracking during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素在钢中的实际意义，并结合其对钢加热转变的影响进行论述。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求结合合金元素对钢加热转变的影响来解释其实际意义，涉及多个合金元素的作用机制、对奥氏体化过程和晶粒长大的影响，以及这些影响如何在实际应用中体现（如减少过热倾向、获得细马氏体等）。这需要综合运用材料科学知识，进行机理分析和实际应用关联，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3432, + "question": "What is the influence law of alloying elements on the critical temperature, E point, and S point of the iron-carbon phase diagram?", + "answer": "After the addition of alloying elements, they affect the critical temperature, E point, and S point. Elements that expand the austenite region generally lower the A3 and A1 temperatures and shift the S point and E point to the lower left; elements that shrink the austenite region generally raise the A3 and A1 temperatures and shift the S point and E point to the upper left.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素对铁碳相图中临界温度、E点和S点的影响规律，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析合金元素对铁碳相图中临界温度、E点和S点的影响规律，涉及多个概念的综合应用和关联分析，需要理解合金元素对相图的具体影响机制，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握合金元素对铁碳相图中临界温度、E点和S点的影响规律，还需要理解不同合金元素（扩大或缩小奥氏体区）对相图特征点的具体影响方向（如A3/A1温度升降、S/E点移动方向）。这涉及多概念关联和综合分析能力，比单纯记忆单个知识点（等级1-2）或简单应用（等级3）更为复杂。正确选项中的内容需要考生在理解基础上进行多角度分析判断，符合等级4\"多角度分析论述\"的标准。" + }, + { + "idx": 3433, + "question": "Explain the meaning of the steel grade 38CrMoAlA", + "answer": "38CrMoAlA is a nitriding-specific steel (quenched and tempered steel), wc=0.38%, wc=1.00%, WM=0.2%, 0A=0.9%, wsi=0.3%, wM=0.45%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号38CrMoAlA的含义，答案提供了详细的文字解释和成分说明，属于需要文字论述的简答题类型。 | 知识层次: 题目考查对钢材牌号命名规则和成分的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求解释钢号38CrMoAlA的含义，但正确选项已经提供了具体的成分和特性描述，考生只需识别并匹配这些信息即可。不需要进行复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 3434, + "question": "Explain the practical significance of adding common alloying elements to steel based on their influence on the kinetic curves during the cooling transformation of steel.", + "answer": "Influence on cooling transformation: The addition of alloying elements (except cobalt and aluminum) shifts the position of the isothermal transformation C-curve of undercooled austenite to the right. Strong carbide-forming elements not only shift the C-curve to the right but also alter its shape, resulting in the separation of the pearlite and bainite transformation curves. Therefore, the effects of adding alloying elements are: (1) improving hardenability; (2) carbide-forming elements can also enhance the wear resistance, tempering stability, and red hardness of steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素对钢冷却转变动力学曲线的实际意义，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释合金元素对钢冷却转变动力学曲线的影响及其实际意义，涉及多个合金元素的作用机制、对C曲线形状和位置的影响，以及这些变化如何改善钢的性能（如淬透性、耐磨性、回火稳定性等）。这需要综合运用材料科学知识，进行机理分析和推理，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解合金元素对钢的冷却转变动力学曲线的影响，还需要综合运用这些知识来解释实际应用中的意义。具体来说，考生需要掌握合金元素（除钴和铝外）如何使过冷奥氏体的等温转变C曲线右移，以及强碳化物形成元素如何改变曲线形状并分离珠光体和贝氏体转变曲线。此外，题目还要求考生理解这些变化如何提高钢的淬透性、耐磨性、回火稳定性和红硬性。这种题目需要考生具备深入的材料科学知识，能够进行复杂的推理和分析，因此在选择题型中属于最高难度。" + }, + { + "idx": 3435, + "question": "What is the difference between the microstructure of alloy steel and carbon steel after heat treatment?", + "answer": "There are also differences in the microstructure after heat treatment, for example, 4Cr13, due to Cr shifting the E point to the left, its microstructure becomes that of a hypereutectoid steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢和碳钢在热处理后微观结构的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较合金钢和碳钢在热处理后的微观结构差异，并举例说明Cr对E点的影响导致微观结构变化。这需要理解合金元素对相图的影响以及热处理对微观结构的作用，涉及多步概念关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解合金钢和碳钢的基本概念，还需要掌握Cr元素对E点位置的影响以及由此导致的微观结构变化。这涉及到多步概念关联和综合分析，需要考生具备较深的知识掌握和应用能力。" + }, + { + "idx": 3436, + "question": "Combining ordinary low-alloy high-strength steels of different strength levels, explain the characteristics of their compositional changes?", + "answer": "While using Mn for solid solution strengthening, the carbon mass fraction was adjusted and the types of alloying elements were increased.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释不同强度级别普通低合金高强度钢的成分变化特点，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释不同强度级别低合金高强度钢的成分变化特点，需要理解合金元素的作用（如Mn的固溶强化）和成分调整的影响，涉及多概念关联和综合分析，但不需要复杂的机理推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解低合金高强度钢的成分变化特点，并分析Mn的固溶强化作用、碳质量分数的调整以及合金元素种类的增加等概念。虽然题目涉及多个概念的关联，但在选择题型中，正确选项已经提供了明确的答案方向，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3437, + "question": "Combining ordinary low-alloy high-strength steels of different strength grades, explain the role of each element in them?", + "answer": "The role of alloying elements in hot-rolled steel: solution strengthening; in normalized steel: in addition to solution strengthening, it also plays a role in dispersion strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同强度等级的低合金高强度钢中各元素的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释不同强度等级低合金高强度钢中各元素的作用，涉及多种元素的强化机制（固溶强化和弥散强化）在不同热处理状态（热轧和正火）下的表现。这需要将材料科学中的强化机制与具体工艺条件关联起来进行分析，属于中等应用层次的知识。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解合金元素在不同热处理状态下的作用（固溶强化和弥散强化），还需要对不同强度等级的钢材进行综合分析。这需要考生具备较强的概念关联能力和多角度分析能力，属于中等应用层次中的复杂题目。" + }, + { + "idx": 3438, + "question": "What are the carbon contents of engineering structural steel, carburizing steel, quenched and tempered steel, spring steel, and bearing steel?", + "answer": "The mass fraction of carbon in engineering structural steel is relatively low, mostly ranging from 0.1% to 0.2%. The mass fraction of carbon in carburizing steel is generally 0.1% to 0.25%. The mass fraction of carbon in most quenched and tempered steels ranges from 0.25% to 0.5%. The mass fraction of carbon in spring steel is generally 0.6% to 0.9%. The mass fraction of carbon in bearing steel ranges from 0.95% to 1.15%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举不同类型钢材的碳含量范围，答案以文字解释和论述的形式给出，没有涉及计算、选择或判断对错。 | 知识层次: 题目考查对不同类型钢的碳含量范围的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个钢材类型的碳含量范围，但每个范围都是基础概念的记忆性知识，不需要复杂的分析或推理。考生只需准确记忆不同钢材的碳含量范围即可正确作答。题目没有设置干扰项或需要深入理解的复杂概念，因此难度等级为2。" + }, + { + "idx": 3439, + "question": "What are the main reasons for the different carbon contents in engineering structural steel, carburizing steel, quenched and tempered steel, spring steel, and bearing steel?", + "answer": "Engineering structural steel is mainly used for engineering structures, where the strength requirement is not high, but the weldability requirement is high, so the mass fraction of carbon is low. The carbon content of carburizing steel cannot be high to ensure high toughness in the core. Quenched and tempered steel should have good comprehensive mechanical properties after quenching and tempering, meaning not only high strength but also good toughness, so medium carbon steel is used. Spring steel requires high elastic limit and fatigue strength, so the mass fraction of carbon cannot be too low, but if it is too high, brittleness increases. Bearing steel requires high hardness and high wear resistance, so a high mass fraction of carbon is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同钢材中碳含量差异的主要原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同类型钢材的碳含量差异进行解释，涉及多个概念的综合分析和关联，需要理解各类钢材的性能要求与碳含量之间的关系，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度，因为它要求考生不仅理解不同钢材的基本特性，还需要综合分析碳含量与钢材性能之间的多角度关系。题目涉及五种不同类型的钢材，每种钢材的碳含量选择都有其特定的工程应用背景和性能要求，考生需要将这些概念关联起来进行多角度分析论述。此外，解题步骤较为复杂，需要考生具备较强的材料科学知识背景和综合分析能力。" + }, + { + "idx": 3440, + "question": "If 20CrMnTi is used as carburizing steel, what are the differences in its mechanical properties, process performance, and process characteristics? Why?", + "answer": "20CrMnTi is a medium-hardenability carburizing steel used for manufacturing larger-sized parts that bear moderate loads. The carburizing temperature is 930~950°C, the quenching temperature is 870~890°C (oil quenching), and the tempering temperature is 190°C. The differences mainly result from the types and contents of alloying elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释20CrMnTi作为渗碳钢在机械性能、工艺性能和工艺特性方面的差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析20CrMnTi作为渗碳钢在机械性能、工艺性能和工艺特性上的差异，并解释原因。这需要理解合金元素的类型和含量如何影响材料的性能，涉及多步分析和概念关联，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，题目不仅要求理解20CrMnTi作为渗碳钢的基本性能和应用，还需要分析其机械性能、工艺性能和工艺特点的差异，并解释这些差异的原因。这涉及到对合金元素类型和含量的深入理解，以及它们如何影响材料的性能。此外，题目还要求综合多个知识点进行多角度分析，超出了简单的记忆或单一概念的应用。" + }, + { + "idx": 3441, + "question": "If 20Cr is used as carburizing steel, what are the differences in its mechanical properties, process performance, and process characteristics? Why?", + "answer": "20Cr is a low hardenability carburizing steel, suitable for manufacturing small wear-resistant parts with low stress. The carburizing temperature is 900~920°C, the quenching temperature is 860~890°C (water quenching or oil quenching), and the tempering temperature is 180°C. The differences are mainly due to the influence of the types and content of alloying elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释20Cr作为渗碳钢在机械性能、工艺性能和工艺特性上的差异，并说明原因。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析20Cr作为渗碳钢在机械性能、工艺性能和工艺特性上的差异，并解释原因。这需要理解合金元素类型和含量对材料性能的影响，涉及多步分析和概念关联，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅要掌握20Cr作为渗碳钢的基本性能和应用范围，还需要理解其热处理工艺参数（如渗碳温度、淬火温度、回火温度）的具体设定及其背后的原理。此外，题目还要求考生能够分析合金元素的种类和含量对材料性能的影响，这涉及到多个知识点的综合应用和关联分析。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 3442, + "question": "If Cr12MoV steel is selected to manufacture cold work molds, what heat treatment process should be formulated? Why?", + "answer": "For Cr12MoV steel used in cold work molds, the heat treatment process is the primary hardening method: quenching at 980～1030‰ and tempering at 200-270°C. Reason: The primary hardening method of Cr12MoV steel can provide the steel with high hardness and wear resistance, minimal heat treatment deformation, and most molds made of Cr12MoV steel without special requirements adopt this method.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Cr12MoV钢制造冷作模具时应采用的热处理工艺及其原因，答案提供了详细的工艺参数和理论依据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求制定Cr12MoV钢的热处理工艺并解释原因，涉及多步热处理过程（淬火和回火）的选择和参数设定，以及这些工艺对材料性能（硬度、耐磨性、变形）的影响。这需要综合理解材料的热处理原理和具体应用场景，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道Cr12MoV钢的热处理工艺，还需要理解为什么选择这种工艺（高硬度、耐磨性、热处理变形小等）。这涉及到对材料性能和应用的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3443, + "question": "What are the differences in heat treatment between engineering structural steel, carburizing steel, quenched and tempered steel, spring steel, and bearing steel? Why?", + "answer": "Engineering structural steel is used in the hot-rolled normalized state. Carburizing steel undergoes carburizing, quenching + low-temperature tempering. Quenched and tempered steel uses medium-carbon steel and is subjected to quenching and tempering. Spring steel undergoes quenching + medium-temperature tempering. Bearing steel undergoes quenching + low-temperature tempering. Engineering structural steel is mainly used for engineering structures where high strength is not required, but good weldability is essential, hence it is used in the hot-rolled normalized state. Carburized parts require certain toughness in the core, so carburizing, quenching + low-temperature tempering is applied. Quenched and tempered parts should possess good comprehensive mechanical properties after treatment, meaning not only high strength but also good toughness, hence quenching and tempering is used. Spring parts require high elastic limit and fatigue strength, so quenching + medium-temperature tempering is applied. Bearings require high hardness and wear resistance, hence quenching + low-temperature tempering is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同类型钢材的热处理差异进行解释和论述，答案提供了详细的文字说明和原因分析，符合简答题的特征。 | 知识层次: 题目要求对不同类型钢材的热处理工艺进行比较，并解释其背后的原因。这需要综合运用材料科学知识，理解不同钢材的性能要求与热处理工艺之间的关系，进行推理分析。涉及多个知识点的关联和综合分析，思维过程较为深入。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3444, + "question": "If Cr12MoV steel is selected to manufacture a stamping die with certain hot hardness requirements, what heat treatment process should be formulated? Why?", + "answer": "When Cr12MoV steel is used to make a stamping die with certain hot hardness requirements, the secondary hardening method can be adopted, i.e., quenching at 1050～1100℃ followed by multiple tempering at 500-520℃, which can increase the hardness to 60～62HRC. Reason: The secondary hardening method of Cr12MoV steel is suitable for applications with higher working temperatures (400～500℃) or requiring hot hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述Cr12MoV钢的热处理工艺及其原因，答案提供了详细的工艺步骤和理论依据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求针对特定材料（Cr12MoV钢）和特定应用场景（冲压模具的热硬度要求）制定热处理工艺，并解释原因。这需要综合运用材料科学知识，包括材料的热处理特性、二次硬化机理、温度选择对性能的影响等多方面知识，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目不仅要求考生掌握Cr12MoV钢的热处理工艺知识，还需要理解二次硬化法的机理及其在特定工况（热硬度要求）下的适用性。正确选项涉及高温淬火和多次回火的复杂工艺参数（1050～1100℃淬火+500-520℃回火），并需要解释该方法能提升热硬度的深层原因（碳化物析出强化）。这种综合工艺选择与机理解释的题目，远超简单记忆或单一概念判断，需要考生具备材料相变、合金元素作用和工程应用场景的综合分析能力，完全符合\"复杂现象全面分析\"的等级5标准。" + }, + { + "idx": 3445, + "question": "Explain the microstructural changes of high-speed steel during heat treatment", + "answer": "Annealing not only reduces hardness, facilitating machining, but also obtains a granular structure with uniformly distributed carbides, preparing the microstructure for subsequent quenching; quenching results in martensite + granular carbides + a considerable amount of retained austenite; triple tempering yields tempered martensite + granular carbides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释高速钢在热处理过程中的微观结构变化，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目要求解释高速钢在热处理过程中的微观结构变化，涉及多个热处理步骤（退火、淬火、三次回火）及其对应的微观结构转变（马氏体、碳化物、残余奥氏体等）。这需要综合运用材料科学知识，理解相变机理，并能分析不同热处理工艺对微观结构的影响。思维过程需要深度推理和综合分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生深入理解高速钢在热处理过程中的微观结构变化机理，包括退火、淬火和三次回火三个阶段的具体转变产物及其形成原因。这不仅需要掌握复杂的热处理原理，还需要综合运用材料科学知识进行推理分析，解释不同工艺条件下的相变行为。选择题型中正确选项的深度和复杂性明显高于一般题目，要求考生具备全面分析复杂现象的能力。" + }, + { + "idx": 3446, + "question": "Since high-speed steel already has good red hardness, why is high-speed steel generally not used for die-casting molds, and why was the steel grade 3Cr2W8V developed?", + "answer": "Although high-speed steel has high hardness, high wear resistance, and red hardness, its toughness and thermal fatigue properties are inferior to those of 3Cr2W8V, so high-speed steel is not used for die-casting molds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么高速钢不用于压铸模具以及3Cr2W8V钢种的开发原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解高速钢和3Cr2W8V钢的基本性能特点，还需要分析它们在特定应用场景（压铸模具）下的适用性差异，涉及材料性能的综合比较和实际应用中的权衡考量。这要求考生具备较高的综合分析能力和对材料性能与使用条件之间关系的深入理解。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解高速钢和3Cr2W8V钢的基本性能特点，还需要综合分析它们在韧性、热疲劳性能等方面的差异，并推理出材料选择背后的机理。这种题目需要考生具备深入的材料科学知识，能够对不同材料的性能进行对比分析，并理解材料选择背后的工程考量。在选择题型中，这种需要多维度综合分析和机理解释的题目属于最复杂的一类。" + }, + { + "idx": 3447, + "question": "Describe the basis for formulating the heat treatment process of high-speed steel", + "answer": "The basis is the chemical composition and the transformation curve of undercooled austenite in high-speed steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述高速钢热处理工艺的基础，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目要求描述高速钢热处理工艺制定的基础，涉及化学成分和过冷奥氏体转变曲线的综合分析，需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解高速钢的化学成分和过冷奥氏体转变曲线这两个关键概念，并将它们关联到热处理工艺制定的基础。虽然不需要多步计算，但要求对材料科学原理有较好的掌握和综合分析能力。" + }, + { + "idx": 3448, + "question": "List several types of ledeburitic steel you are familiar with?", + "answer": "High-speed steel, Cr12, Cr12MoV, etc. all belong to ledeburitic steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出几种熟悉的莱氏体钢类型，答案以文字形式列举具体例子，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对莱氏体钢（ledeburitic steel）分类的基本记忆，只需列举熟悉的类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求列举几种莱氏体钢的常见类型，属于基础概念记忆的范畴。正确选项直接提供了具体的钢种名称（如高速钢、Cr12、Cr12MoV等），无需复杂的分析或推理过程。题目仅测试学生对莱氏体钢分类的简单记忆能力，因此属于选择题型中最基础的难度等级。" + }, + { + "idx": 3449, + "question": "If 20Cr2Ni4W is used as carburizing steel, what are the differences in its mechanical properties, process performance, and process characteristics? Why?", + "answer": "20Cr2Ni4W is a high-hardenability carburizing steel used for manufacturing heavy-duty, large-section components requiring high wear resistance and good toughness. The carburizing temperature is 900~950°C, the quenching temperature is 880°C, and a secondary quenching is performed at 780°C, with a tempering temperature of 190°C. The differences are mainly due to the influence of the types and contents of alloying elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释20Cr2Ni4W作为渗碳钢在机械性能、工艺性能和工艺特性方面的差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析20Cr2Ni4W作为渗碳钢在机械性能、工艺性能和工艺特性上的差异，并解释原因。这需要综合运用材料科学知识，包括合金元素的影响、热处理工艺对性能的影响等，并进行推理分析。涉及的知识点复杂且关联度高，思维过程要求深入。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握20Cr2Ni4W钢的基本性能，还需要深入理解其作为渗碳钢时的热处理工艺参数（如渗碳温度、淬火温度、二次淬火温度和回火温度）及其对机械性能的影响。此外，题目还要求考生能够解释合金元素种类和含量对这些性能差异的影响机制。这种题目需要考生具备综合运用知识、进行推理分析和机理解释的能力，属于复杂现象全面分析的层次。在选择题型中，这种需要多维度知识整合和深度机理解释的题目是最具挑战性的。" + }, + { + "idx": 3450, + "question": "5CrNiMo, 3Cr2W8V, and H11 (or H13) all belong to hot-work die steels. Are there any differences in their usage? Why?", + "answer": "Yes, there are differences. Their total alloying element contents are low-alloy (5CrNiMo), medium-alloy (H11), and high-alloy (3Cr2W8V), respectively. 5CrNiMo is used for hot forging dies, H11 replaces 3Cr2W8V for small and medium-sized mechanical forging dies and hot extrusion dies with relatively low operating temperatures, while 3Cr2W8V is used for hot extrusion dies. The reason for their differences in usage lies in the varying types and amounts of alloying elements, which result in different levels of thermal strength, thermal fatigue resistance, and high-temperature oxidation resistance, hence their different applications.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同热作模具钢的使用差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同热作模具钢的使用差异进行比较和解释，涉及合金元素含量、热强度、热疲劳抗力等概念的综合分析，需要理解不同合金元素对性能的影响及其在实际应用中的选择依据。这属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在选择题型内，该题目属于较高难度，因为需要考生不仅掌握不同热作模具钢的基本分类（低合金、中合金、高合金），还要理解合金元素含量与性能（热强度、抗热疲劳性、高温抗氧化性）的关联性，并能综合分析不同钢种在实际应用中的选择依据（如锻造模、挤压模的工况差异）。题目要求将材料成分、性能、应用场景三个维度进行多角度关联分析，超越了单纯记忆或单一概念比较的层次。" + }, + { + "idx": 3451, + "question": "What is the most notable characteristic of ledeburitic steel?", + "answer": "Its most notable characteristic is the presence of eutectic ledeburite structure in the as-cast microstructure, with high hardness, high wear resistance, and red hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释ledeburitic steel的最显著特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对ledeburitic steel最显著特征的基础概念记忆，包括其微观结构和性能特点，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（ledeburitic steel的最显著特征），但正确选项涉及多个具体特性（eutectic ledeburite结构、高硬度、高耐磨性和红硬性），需要考生对材料科学中的特定钢种有较全面的记忆理解，而不仅仅是简单定义。这超出了最基本定义简答的难度（等级1），但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 3452, + "question": "What is the most prominent weakness of ledeburitic steel?", + "answer": "The weakness is the coarse carbides, uneven distribution, and high brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释莱氏体钢的主要弱点，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算 | 知识层次: 题目考查对莱氏体钢主要弱点的基本概念记忆，答案直接列举了其微观组织特征（粗大碳化物、分布不均）和宏观性能表现（高脆性），属于基础概念的记忆性知识，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆莱氏体钢的主要弱点（粗大碳化物、不均匀分布和高脆性），但这些都是该材料的基础特性，属于定义性知识范畴。题目不涉及多个概念的比较分析或复杂推理过程，只需准确回忆相关知识点即可作答。" + }, + { + "idx": 3453, + "question": "If Cr12MoV steel is selected to manufacture measuring tools, what heat treatment process should be formulated? Why?", + "answer": "When Cr12MoV steel is used to make measuring tools, it can be quenched at 1050～1100°C, tempered multiple times at 550～600°C, and then subjected to nitriding or carbonitriding to achieve high wear resistance, corrosion resistance, and dimensional stability. Reason: Cr12MoV steel, after quenching + high-temperature tempering (quenching and tempering) followed by nitriding or carbonitriding, is commonly used for making measuring tools due to its high wear resistance, corrosion resistance, and relatively high dimensional stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Cr12MoV钢制造测量工具时应采用的热处理工艺及其原因，答案提供了具体的工艺步骤和理论依据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据特定材料（Cr12MoV钢）的应用场景（测量工具）制定热处理工艺，并解释原因。这涉及到多步工艺的选择（淬火、多次回火、氮化或碳氮共渗）以及对这些工艺如何提高材料性能（耐磨性、耐腐蚀性、尺寸稳定性）的理解。虽然不需要复杂的机理分析或创新设计，但需要综合应用材料选择和热处理知识，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目不仅要求考生掌握Cr12MoV钢的热处理工艺，还需要理解其背后的原理（如高耐磨性、耐腐蚀性和尺寸稳定性的需求）。此外，题目涉及多步热处理工艺（淬火+高温回火+氮化或碳氮共渗）的综合应用，要求考生能够将多个概念关联起来，并进行综合分析。这种题目在选择题型中属于需要多角度分析论述的类型，超出了简单的记忆或单一概念应用。" + }, + { + "idx": 3454, + "question": "What are the types of heat-resistant steels?", + "answer": "Commonly used heat-resistant steels are roughly divided into three categories according to their microstructure in the normalized state: pearlitic steel, martensitic steel, and austenitic steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举热阻钢的类型，答案提供了详细的分类和说明，属于需要文字解释和论述的简答题。 | 知识层次: 题目考查对热阻钢分类的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆和识别热阻钢的基本分类，属于基础概念记忆层次。题目直接给出了正确选项，无需进行复杂的概念比较或分析，解题步骤简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 3455, + "question": "Based on the alloy composition of oxidation-resistant steel, analyze how the steel meets different thermal stability requirements.", + "answer": "Alloying elements such as chromium, silicon, and aluminum are added to oxidation-resistant steel. These elements have a high affinity for oxygen, so they are preferentially oxidized, forming a dense, high-melting-point oxide film that firmly covers the steel surface. This isolates the metal from external oxidizing gases, preventing further oxidation. The amount of alloying elements added varies, resulting in different levels of oxidation resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析合金成分如何满足不同的热稳定性要求，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析合金元素如何通过形成氧化膜来满足不同的热稳定性需求，涉及多元素的协同作用、氧化机理的解释以及不同氧化抵抗水平的综合分析。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生基于合金成分分析氧化抵抗钢如何满足不同热稳定性需求，涉及复杂分析层次的知识点。正确选项不仅需要识别关键合金元素（铬、硅、铝），还需理解这些元素优先氧化的机理，以及形成的致密高熔点氧化膜如何隔离金属与外部氧化气体。此外，选项还提到合金元素添加量的变化导致不同抗氧化等级，这要求考生具备综合运用和推理分析能力。选择题型中，这种深度机理解释和复杂现象全面分析的题目相对较少，因此属于最高难度等级。" + }, + { + "idx": 3456, + "question": "Why is it still necessary to develop ledeburitic steel?", + "answer": "Because it has high hardness, high wear resistance, and red hardness, this steel is developed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么需要开发莱氏体钢，答案需要提供文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释莱氏体钢的发展必要性，涉及对其性能特点（高硬度、高耐磨性、红硬性）的理解和应用，需要将材料性能与实际应用需求关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解ledeburitic steel的多个性能特点（高硬度、高耐磨性、红硬性）并进行综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3457, + "question": "Based on the role of alloying elements used in stainless steel, analyze the main characteristics of martensitic stainless steel? What are the main shortcomings? How to prevent or overcome them?", + "answer": "Martensitic stainless steel belongs to chromium stainless steel. As the carbon content increases, the strength, hardness, and wear resistance of the steel improve, but the corrosion resistance decreases, because carbon forms chromium carbides with chromium, preventing its potential from rising. To enhance corrosion resistance and mechanical properties, quenching and tempering are usually performed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析马氏体不锈钢的主要特性、主要缺点以及如何预防或克服这些缺点，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析马氏体不锈钢的主要特性及其主要缺点，并提出预防或克服这些缺点的方法。这需要综合运用材料科学知识，包括合金元素的作用、相变行为、腐蚀机制以及热处理工艺等多方面的知识。此外，还需要进行推理分析，理解碳含量对性能的影响机制，并提出相应的解决方案。因此，该题目属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3458, + "question": "Based on the role of alloying elements used in stainless steel, analyze the main characteristics of ferritic stainless steel? What are the main shortcomings? How to prevent or overcome them?", + "answer": "Ferritic stainless steel also belongs to chromium stainless steel. Its structure remains unchanged from room temperature to high temperature (960～1100‰), and it has strong resistance to atmospheric and acid corrosion. However, if the grain coarsens during heating, it cannot be refined by heat treatment methods and can only be improved through plastic deformation and recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析铁素体不锈钢的主要特性、主要缺点以及如何预防或克服这些缺点，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析铁素体不锈钢的主要特性和缺点，并探讨如何预防或克服这些缺点。这需要理解铁素体不锈钢的基本特性（如铬含量、耐腐蚀性等），分析其缺点（如晶粒粗化问题），并提出解决方案（如塑性变形和再结晶）。虽然涉及多个概念，但主要是对已有知识的应用和综合分析，不需要复杂的推理或创新设计。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握不锈钢中合金元素的作用，还需要综合分析铁素体不锈钢的主要特性及其缺点，并理解如何预防或克服这些缺点。题目涉及多个概念和步骤的关联分析，需要考生具备较强的综合能力和应用知识的能力。" + }, + { + "idx": 3459, + "question": "Based on the role of alloying elements used in stainless steel, analyze the main characteristics of austenitic stainless steel? What are the main shortcomings? How to prevent or overcome them?", + "answer": "Austenitic stainless steel belongs to nickel-chromium steel, which has excellent corrosion resistance and heat resistance. However, intergranular corrosion may occur at 450~850°C. It is usually prevented by reducing the mass fraction of carbon, adding elements that can form stable carbides (such as Ti), and applying appropriate heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析奥氏体不锈钢的主要特性、主要缺点以及如何预防或克服这些缺点，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求分析奥氏体不锈钢的主要特性、主要缺点以及预防或克服这些缺点的方法，涉及多个知识点的综合运用和推理分析。需要理解合金元素在不锈钢中的作用、奥氏体不锈钢的性能特点、晶间腐蚀的机理以及预防措施等，思维过程较为深入和复杂。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握不锈钢中合金元素的作用，还需要深入理解奥氏体不锈钢的主要特性、主要缺点及其预防措施。这涉及到多个复杂概念的整合，包括腐蚀机理、合金元素的影响以及热处理工艺的应用。此外，正确选项中的内容需要考生具备综合分析和推理能力，能够将理论知识应用于实际问题的解决。因此，在选择题型内，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 3460, + "question": "What are the different application scenarios for austenitic stainless steel, wear-resistant steel, and quenched tool steel?", + "answer": "Wear-resistant steel is used to make working parts that withstand strong impact and pressure, such as bulldozer blades and railway switches. Quenched tool steel is used in situations that do not require withstanding strong impact pressure but demand high wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对不同类型钢材的应用场景进行文字解释和论述，答案提供了详细的描述而非选择或判断。 | 知识层次: 题目要求对不同类型钢材的应用场景进行解释和论述，涉及的是基本概念的直接应用和简单关联，不需要复杂的分析或综合推理。 | 难度: 在选择题中属于简单应用难度，题目直接描述了不同钢材的应用场景，只需根据题目内容进行匹配选择，无需复杂分析或计算。" + }, + { + "idx": 3461, + "question": "How is tool steel further classified?", + "answer": "Tool steel is divided into: cutting tool steel, die steel, and measuring tool steel. Cutting tool steel is divided into: carbon tool steel, low-alloy tool steel, and high-speed steel. Die steel is divided into: cold work die steel and hot work die steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对工具钢的分类进行详细解释和论述，答案提供了详细的分类和子分类，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对工具钢分类的基本概念记忆和理解，不需要复杂的分析或应用，仅需回忆和列举工具钢的分类及其子类。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个分类层次（工具钢的三大类及其子类），但主要考察的是基础概念的记忆和分类体系的掌握。不需要复杂的分析或推理过程，只需准确回忆工具钢的分类体系即可。相比等级1的简单定义题，该题需要记忆更多分类细节；但相比等级3需要阐述复杂概念体系的题目，该题仍属于概念解释和描述层面的难度。" + }, + { + "idx": 3462, + "question": "How to overcome the weaknesses of ledeburitic steel?", + "answer": "By repeatedly forging to break down the coarse carbides and distribute them uniformly, which can also reduce brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对如何克服ledeburitic steel的弱点进行解释和论述，答案提供了具体的解决方法（反复锻造以分解粗大碳化物并均匀分布），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释如何克服莱氏体钢的弱点，涉及对材料性能的理解和具体工艺（反复锻造）的应用，需要将材料性能与加工工艺关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解莱氏体钢的弱点（粗大碳化物分布不均导致脆性）与锻造工艺之间的关联性，并能综合分析锻造工艺对材料性能改善的作用机制。虽然不涉及多步计算，但需要将材料科学原理与加工工艺知识进行关联分析。" + }, + { + "idx": 3463, + "question": "Discuss the microstructural characteristics and processing techniques of ZGMn13", + "answer": "ZGMn13 is a wear-resistant steel with an austenitic microstructure at room temperature. Whether in the as-cast, forged, or hot-rolled condition, carbides precipitate along the austenite grain boundaries, reducing the steel's toughness and wear resistance. Therefore, water toughening treatment must be performed. After water toughening, it exhibits good toughness. During subsequent use, under strong compressive stress, martensitic transformation occurs, thereby increasing its wear resistance. Hence, this type of steel is used in applications subject to strong compressive stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论ZGMn13的微观结构特征和加工技术，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论ZGMn13的显微组织特征和加工技术，涉及多个概念（如奥氏体组织、碳化物析出、水韧处理、马氏体转变等）的关联和综合分析。虽然不需要复杂的推理或创新设计，但需要理解不同加工条件对材料性能的影响，并进行多步分析。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握ZGMn13钢的基本微观结构特征（如奥氏体组织和碳化物析出），还需要理解不同加工状态（铸态、锻造、热轧）对材料性能的影响。此外，题目还涉及水韧处理的作用机制和后续使用中的马氏体相变过程，这要求考生能够将多个概念（如相变、加工工艺、力学性能）进行关联和综合分析。虽然题目提供了正确选项，但理解和分析这些复杂的概念和过程在选择题型中仍属于多角度分析论述的难度等级。" + }, + { + "idx": 3464, + "question": "Discuss the microstructural characteristics and processing techniques of Cr12-type cold-work die steel", + "answer": "Cr12 is a type of cold-work die steel, with Cr as the main alloying element, which significantly enhances hardenability and wear resistance. Due to the high content of alloying elements, the as-cast microstructure contains eutectic carbides. Therefore, repeated forging is required to break down the carbides and improve their distribution and brittleness. After forging, spheroidizing annealing is performed, followed by quenching + low-temperature tempering to obtain tempered martensite, which provides high hardness and wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论Cr12型冷作模具钢的显微组织特征和加工技术，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求讨论Cr12型冷作模具钢的显微组织特征和加工工艺，涉及合金元素的作用、铸态组织、锻造工艺、球化退火、淬火和低温回火等多个工艺步骤及其对组织性能的影响。需要综合运用材料科学知识，分析各工艺步骤的机理及其对最终性能的贡献，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用材料科学知识，深入理解Cr12型冷作模具钢的微观结构特征和加工工艺。需要掌握合金元素对性能的影响、共晶碳化物的形成机制、锻造和热处理工艺对微观结构的改变等复杂机理。解题过程涉及多个知识点的串联和推理分析，远超选择题型中常见的简单概念识别或记忆性内容。" + }, + { + "idx": 3465, + "question": "What is the difference between the purpose of quenching for austenitic stainless steel and wear-resistant steel compared to that of general steel?", + "answer": "The purpose of quenching for austenitic stainless steel and wear-resistant steel is to obtain a single-phase, uniform austenitic structure, preventing the formation of secondary phases that could cause intergranular corrosion. Therefore, the quenching of austenitic stainless steel is referred to as solution treatment, while for wear-resistant steel, the quenching process, which results in a single austenitic structure with high plasticity and toughness, is also known as water toughening treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释淬火对奥氏体不锈钢和耐磨钢与普通钢的不同目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解不同钢材淬火目的的区别，并解释其背后的原理和术语（如固溶处理和水韧处理），涉及多个概念的关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题型中，该题目需要考生理解并比较不同钢材（奥氏体不锈钢、耐磨钢和普通钢）淬火目的的区别，涉及多个专业概念（单相奥氏体组织、二次相、晶间腐蚀等）和热处理工艺（固溶处理、水韧处理）。解题时需要综合分析不同材料的热处理目的和机理，属于多角度分析论述的难度等级。" + }, + { + "idx": 3466, + "question": "How is structural steel further subdivided?", + "answer": "Structural steel is divided into: engineering structural steel and mechanical component steel. Engineering structural steel is further divided into: ordinary carbon structural steel and ordinary low-alloy steel. Mechanical component steel is divided into: carburizing steel, quenched and tempered steel, spring steel, and rolling bearing steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对结构钢的细分进行文字解释和论述，答案提供了详细的分类和说明，符合简答题的特征。 | 知识层次: 题目考查结构钢的基本分类和子分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个分类和细分概念，但所有信息都集中在结构钢的分类体系上，属于单一知识点的系统性记忆。考生需要准确回忆并匹配不同层级的分类关系，但不需要进行跨概念比较或复杂推理。这比单纯记忆基本定义（等级1）要求更高，但尚未达到需要整合多个复杂概念体系的难度（等级3）。" + }, + { + "idx": 3467, + "question": "Why does alloy steel have less heat treatment deformation than carbon steel?", + "answer": "The addition of alloying elements (except C) increases the hardenability of the steel, so when obtaining the same structure, alloy steel can choose a slower cooling medium, resulting in less heat treatment deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢比碳钢热处理变形小的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金钢与碳钢在热处理变形方面的差异，涉及合金元素对淬透性的影响、冷却介质选择与组织转变的关系等复杂机理分析，需要综合运用材料科学原理进行推理和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解合金钢和碳钢的基本区别，还需要掌握合金元素对钢的淬透性影响这一较深层次的机理知识。正确选项涉及多个关键概念的综合运用（合金元素、淬透性、冷却介质选择、热处理变形关系），需要考生进行机理层面的推理分析才能准确作答。这种需要将多个专业知识模块串联起来解释复杂现象的题目，在选择题中属于难度较高的类型。" + }, + { + "idx": 3468, + "question": "For a machine tool spindle made of 40Cr steel, the core requires good strength and toughness (200-300HB), while the journal needs to be hard and wear-resistant (HRC54-58). What preparatory heat treatment should be selected?", + "answer": "Preparatory heat treatment: Quenching + high-temperature tempering, tempered sorbite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述选择特定预备热处理的原因，答案提供了详细的文字解释而非选择或计算。 | 知识层次: 题目要求根据材料的不同部位性能需求选择合适的预备热处理工艺，涉及对材料热处理工艺的理解和应用，需要综合分析材料的性能要求和热处理工艺的效果，属于中等应用层次。 | 难度: 在选择题型内，这道题目属于较高难度，原因如下：" + }, + { + "idx": 3469, + "question": "Is it reasonable to use Q235 steel after quenching and tempering treatment? Why?", + "answer": "No, it is not reasonable. Because Q235 is an ordinary-quality carbon structural steel with high sulfur and phosphorus content, it is generally used in the hot-rolled state. Due to its low carbon content, high S and P content, poor quality, and low hardenability, even in the quenched and tempered state, its performance will not improve significantly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对是否合理使用Q235钢进行淬火和回火处理进行解释，答案提供了详细的文字论述和原因分析，符合简答题的特征。 | 知识层次: 题目需要理解Q235钢的基本特性（如碳含量、硫磷含量等）及其对热处理效果的影响，并综合分析淬火和回火处理对Q235钢性能提升的有限性。这涉及多个概念的关联和一定程度的综合分析，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解Q235钢的基本特性（如碳含量、硫磷含量、普通质量等），并关联热处理工艺（淬火回火）对材料性能的影响机制。题目要求考生综合分析材料属性和处理工艺的匹配性，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3470, + "question": "Why does alloy steel have better mechanical properties than carbon steel?", + "answer": "The addition of alloying elements and appropriate heat treatment can improve or enhance the mechanical properties of steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金钢比碳钢具有更好机械性能的原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释合金钢比碳钢具有更好机械性能的原因，涉及合金元素的作用和热处理的影响，需要将多个概念关联起来进行综合分析，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解合金钢和碳钢的基本概念，并综合分析合金元素添加和热处理对机械性能的影响。虽然题目涉及多步概念关联，但在选择题型中通过正确选项可以直接判断，不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 3471, + "question": "How is steel classified by use?", + "answer": "Steel is classified by use into structural steel, tool steel, and special performance steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个简短的文字描述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对钢材按用途分类的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆钢铁按用途分类的基本定义，属于最基础的概念记忆层次。题目仅涉及简单的分类列举，不需要解释或比较分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3472, + "question": "How are special property steels further classified?", + "answer": "Special property steels are divided into: stainless steel, heat-resistant steel, and wear-resistant steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对特殊性能钢的分类进行文字解释和论述，答案提供了具体的分类说明，符合简答题的特征。 | 知识层次: 题目考查特殊性能钢的分类，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆特殊性能钢的基本分类（不锈钢、耐热钢、耐磨钢），属于最基础的定义简答层面。题目不涉及概念解释或复杂体系阐述，仅需直接回忆教材中的分类标准即可作答，因此属于难度等级1。" + }, + { + "idx": 3473, + "question": "Why do alloy tool steels have higher wear resistance and hot hardness than carbon steels?", + "answer": "Alloy tool steels contain certain alloying elements that form alloy carbides with the carbon in the steel. These alloy carbides have high hardness and high melting points, which is why alloy tool steels exhibit higher wear resistance and hot hardness than carbon steels.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金工具钢比碳钢具有更高耐磨性和热硬度的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解合金工具钢和碳钢在耐磨性和热硬度上的差异，并解释合金元素如何通过形成合金碳化物来提高性能。这涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解合金工具钢和碳钢的基本概念，并能够分析合金元素如何形成合金碳化物及其对性能的影响。虽然不需要复杂的计算，但需要对材料科学中的基本概念有较好的掌握，并能进行简单的综合分析。" + }, + { + "idx": 3476, + "question": "There is a W18Cr4V steel disc milling cutter, please arrange its processing route.", + "answer": "Processing route: Blanking and forging → Spheroidizing annealing → Cutting → Quenching + High-temperature tempering (three times) → Finishing → Assembly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述一个具体的加工路线，答案以文字解释和论述的形式给出，没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目要求安排W18Cr4V钢制圆盘铣刀的加工路线，涉及多个加工步骤的选择和顺序安排，需要对材料的热处理工艺和机械加工流程有较好的理解和综合应用能力。虽然不涉及复杂的计算或深度机理分析，但需要综合考虑材料特性和加工要求，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握W18Cr4V钢的加工路线，涉及多个步骤和热处理工艺，需要综合分析和关联不同加工步骤的目的和顺序。虽然题目提供了正确选项，但考生仍需具备一定的材料加工知识才能正确理解和选择。" + }, + { + "idx": 3477, + "question": "For a machine tool spindle made of 40Cr steel, the core requires good strength and toughness (200-300HB), while the journal needs to be hard and wear-resistant (HRC54-58). Describe the microstructure after preparatory heat treatment.", + "answer": "Microstructure after preparatory heat treatment: tempered sorbite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述预备热处理后的微观结构，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对材料热处理后微观结构的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别40Cr钢经过预备热处理后的微观组织（回火索氏体），属于基础概念记忆层面的知识，无需解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3478, + "question": "Compare the compositional characteristics of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V.", + "answer": "
Steel gradeCompositional characteristics
9SiCrwc=0.9%, wsiWcr<1.5%
Cr12wc=2.15%, wc=12%
5CrMnMowc=0.5%, wc=0.75%, wM=0.9% WMo=0.21%
W18Cr4Vwc=0.75%, ww=18%, wc=4%, wv=1.2%
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较四种合金工具钢的成分特征，需要文字解释和论述，答案以表格形式呈现了详细的成分数据，属于需要详细说明的简答题类型。 | 知识层次: 题目主要考查对不同合金工具钢成分的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生记忆并比较四种合金工具钢的成分特征。虽然涉及多个钢种的成分数据，但每个选项的信息相对独立且明确，属于基础概念记忆的范畴。考生只需准确回忆各钢种的成分范围即可作答，无需进行复杂的分析或推理。因此，在选择题型内属于中等偏下的难度（等级2）。" + }, + { + "idx": 3479, + "question": "What is the difference between the wear resistance principle of wear-resistant steel and that of quenched tool steel?", + "answer": "The wear resistance principle of wear-resistant steel is that the single austenite structure is subjected to strong impact and pressure during work, resulting in stress-induced martensite and work hardening, which greatly increases the wear resistance of the steel. Quenched tool steel obtains high hardness and high wear resistance tempered martensite through quenching + low-temperature tempering, giving the steel high wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种钢材的耐磨原理差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种钢材的耐磨原理，涉及材料微观结构转变（如奥氏体向马氏体的应力诱导转变）和热处理工艺（淬火+低温回火）对性能的影响。这需要综合运用材料科学知识，理解不同机制如何导致耐磨性提升，并进行对比分析，属于机理层面的解释和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3480, + "question": "Compare the heat treatment processes of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V", + "answer": "
Steel gradeHeat treatment
9SiCrQuenching + low tempering
Cr12Quenching + low tempering
5CrMnMoQuenching + high tempering
W18Cr4VQuenching + high tempering
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较四种合金工具钢的热处理工艺，答案以表格形式呈现了每种钢的热处理过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较四种合金工具钢的热处理工艺，需要理解不同钢种的特性和对应的热处理工艺，并进行综合分析。虽然涉及记忆性知识，但更强调对不同钢种热处理工艺的理解和应用，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对四种合金工具钢的热处理工艺进行比较分析，涉及多个知识点（淬火+低温回火 vs 淬火+高温回火）的综合应用。解题时需要考生具备较强的概念关联能力和综合分析能力，能够区分不同钢材的热处理特点，并正确匹配工艺。虽然题目提供了正确选项，但需要考生在选择题框架内完成多角度对比分析，因此属于较高难度等级。" + }, + { + "idx": 3481, + "question": "Compare the properties of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V", + "answer": "
Steel gradeProperties
9SiCrHigh strength and high wear resistance
Cr12High strength and high wear resistance
5CrMnMoBest comprehensive mechanical properties
W18Cr4VHigh strength and high wear resistance
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较四种合金工具钢的性能，答案以表格形式呈现了每种钢的性能特点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较四种合金工具钢的性能，需要理解每种钢的基本特性并进行综合分析。虽然不涉及复杂的计算或机理分析，但需要对不同材料的性能有一定的理解和关联，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对四种合金工具钢（9SiCr、Cr12、5CrMnMo、W18Cr4V）的性能进行多角度比较和分析。虽然题目提供了正确选项，但考生需要具备较深的知识储备，能够理解并区分不同钢材的高强度、高耐磨性以及综合机械性能等特性。此外，题目涉及的知识层次为中等应用，要求考生进行多步计算、概念关联和综合分析，这在选择题型中属于较高难度的要求。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 3482, + "question": "Explain the purposes of each hot working process.", + "answer": "Spheroidizing annealing: Eliminate forging stress, spheroidize carbides to reduce hardness and improve machinability, preparing for quenching. Quenching: To obtain martensite, maintaining high hardness and wear resistance. Tempering: Adjust properties, eliminate quenching stress, and reduce retained austenite (A′).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释每个热加工过程的目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对热加工工艺目的的基本概念记忆和理解，如球化退火、淬火和回火的作用，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生解释每个热加工过程的目的，涉及多个概念的解释和描述。虽然不需要复杂的分析或比较，但需要考生对每个过程的基本原理和目的有清晰的理解和记忆。这属于概念解释和描述的难度水平。" + }, + { + "idx": 3483, + "question": "Compare the uses of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V.", + "answer": "
Steel gradeUse
9SiCrTaps, dies, drill bits
Cr12Large-sized cold work dies
5CrMnMoSmall hot forging dies
W18Cr4VHigh-speed cutting dies
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较四种合金工具钢的用途，答案以表格形式详细列出了每种钢材的具体应用，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对不同合金工具钢用途的记忆和分类，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及四种合金工具钢的用途比较，但正确选项以表格形式清晰列出了每种钢材的具体用途，减少了记忆负担。学生只需准确匹配钢材类型与其典型应用场景，无需进行复杂的分析或推理。题目主要考察基础概念记忆能力，属于\"概念解释和描述\"层次，但比单纯的定义简答（等级1）要求稍高。" + }, + { + "idx": 3484, + "question": "Is tempering high-speed steel at 560°C considered quenching and tempering treatment? Why?", + "answer": "No. Quenching and tempering treatment refers to high-temperature tempering (typically 500~650°C) after quenching to obtain tempered sorbite structure, which provides good comprehensive mechanical properties. However, tempering high-speed steel at 560°C aims to achieve dispersion hardening and secondary quenching phenomena, improving hardness and wear resistance, with the microstructure being tempered martensite + a small amount of retained austenite + carbides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在560°C回火高速钢不被认为是淬火和回火处理，答案需要详细的文字解释和论述，涉及材料科学中的热处理原理和微观结构变化。 | 知识层次: 题目要求分析高速钢在560°C回火与淬火回火处理的区别，涉及对热处理工艺目的、微观组织演变和性能影响的深入理解。需要综合运用材料科学知识，解释不同热处理工艺的机理和效果，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3486, + "question": "Can one prolonged tempering at 560°C replace three tempering processes at 560°C?", + "answer": "No. Because a single tempering is difficult to completely eliminate retained austenite, multiple tempering processes are required to reduce the retained austenite to the minimum amount. Moreover, each subsequent tempering can eliminate the internal stress generated by the transformation of austenite into martensite during the previous tempering.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目是一个是非判断问题，要求判断“一次长时间回火是否可以替代三次回火”这一陈述的正确性。答案明确给出了“No”并解释了原因，符合判断题的特征。 | 知识层次: 题目涉及回火工艺对残余奥氏体消除的影响，需要理解多次回火的作用机理和残余奥氏体转变的复杂过程。解答不仅需要知道多次回火的必要性，还需要分析每次回火对内部应力和组织转变的影响，属于综合运用和推理分析的层次。 | 难度: 在选择题型中属于高难度，需要深入理解回火工艺的机理，包括残余奥氏体的消除、内应力的产生与消除等复杂过程。题目要求综合运用材料科学知识进行推理分析，判断单一长时间回火是否能替代多次回火的效果，涉及多个知识点的综合应用和机理解释。" + }, + { + "idx": 3487, + "question": "What is the role of carbon in high-speed steel?", + "answer": "The role of carbon in high-speed steel: high carbon content, generally with a mass fraction of 0.7% to 1.5%, is to ensure the formation of alloy carbides with alloying elements, obtaining a martensite matrix plus carbides during quenching to improve the hardness and wear resistance of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释碳在高速钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释碳在高速钢中的作用，涉及碳含量范围、合金碳化物的形成、马氏体基体与碳化物的相互作用等概念关联和综合分析，需要理解并应用材料科学中的合金化原理和相变知识，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解碳在高速钢中的作用机制，包括碳含量范围、合金碳化物的形成、马氏体基体的获得以及硬度和耐磨性的提升等多个概念，并进行综合分析。虽然不需要多角度分析论述或深度关联性分析，但仍需一定的知识掌握和概念关联能力。" + }, + { + "idx": 3488, + "question": "Why is the quenching temperature of W18Cr4V steel as high as 1280°C?", + "answer": "The two elements that have the greatest impact on the hot hardness of high-speed steel are W and V. Their solubility in austenite only increases significantly above 1000°C. At 1270~1280°C, the austenite contains wW=7%~8%, wCr=4%, and wV=1%. If the temperature is higher, the austenite grains will rapidly grow and coarsen, and the retained austenite in the quenched state will also increase rapidly, thereby reducing the hardness of the high-speed steel and increasing brittleness. This is the main reason why the quenching temperature is generally set at 1270~1280°C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么W18Cr4V钢的淬火温度高达1280°C，答案提供了详细的文字解释和论述，涉及材料科学中的热硬性、溶解度、晶粒生长等概念，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释W18Cr4V钢的淬火温度高达1280°C的原因，涉及多个元素的溶解度与温度的关系、奥氏体晶粒生长和粗化、残余奥氏体含量对硬度的影响等复杂机理。需要综合运用材料科学中的相变、合金元素作用和热处理原理进行推理分析，思维过程深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3489, + "question": "Why does W18Cr4V steel need to undergo three tempering cycles at 560°C after quenching?", + "answer": "Because W18Cr4V steel contains about 20%~25% retained austenite in the quenched state, which is difficult to fully eliminate with a single tempering. Three tempering cycles can reduce the retained austenite to a minimum (about 15% remains after the first tempering, 3%~5% after the second, and 1%~2% after the third). Each subsequent tempering also relieves the internal stress generated by the transformation of austenite into martensite during the previous tempering. The tempered microstructure consists of tempered martensite + a small amount of retained austenite + carbides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么W18Cr4V钢需要在淬火后进行三次560°C的回火处理，答案提供了详细的文字解释和论述，说明每次回火的作用和效果，符合简答题的特征。 | 知识层次: 题目需要解释W18Cr4V钢在淬火后需要进行三次回火的原因，涉及残余奥氏体的转变、回火过程中内应力的消除以及显微组织的演变。这需要综合运用材料科学中的相变理论、热处理原理和组织分析知识，进行多步骤的推理和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3490, + "question": "What is the role of alloying elements in high-speed steel?", + "answer": "The role of alloying elements in high-speed steel: W improves the red hardness of the steel, Cr enhances hardenability, Mo reduces the second type of temper brittleness, Co delays the precipitation and aggregation of carbides during tempering, that is, improves tempering stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金元素在高速钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素在高速钢中的作用，涉及多个元素的特定功能及其对材料性能的影响。这需要理解合金元素的基本特性及其在材料中的相互作用，属于概念关联和综合分析的中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个合金元素（W、Cr、Mo、Co）在高速钢中的不同作用，并能将这些概念关联起来进行综合分析。题目要求考生不仅知道单个元素的作用，还要能区分不同元素对钢材性能的影响，属于中等应用层次的知识掌握。" + }, + { + "idx": 3491, + "question": "Can austenitic stainless steel be strengthened by heat treatment?", + "answer": "No. Because after quenching (solution treatment), austenitic stainless steel undergoes no phase transformation, and all second-phase particles dissolve into the austenite. As a result, its hardness and strength drop to the lowest level after quenching, so it cannot be strengthened by heat treatment.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Can austenitic stainless steel be strengthened by heat treatment?），而答案明确给出了判断结果（No）并提供了简要解释。这符合判断题的特征，即判断陈述的对错并提供简要说明。 | 知识层次: 题目考查对奥氏体不锈钢热处理强化原理的基础概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对奥氏体不锈钢热处理强化原理的理解，需要学生掌握奥氏体不锈钢在淬火后的相变行为和强化机制。虽然涉及专业概念，但只需判断一个基本原理的正确性，不需要进行复杂的概念比较或综合分析。" + }, + { + "idx": 3492, + "question": "How to improve the corrosion resistance of steel?", + "answer": "Methods to improve the corrosion resistance of steel: (a) Increase the electrode potential of the metal. (b) Make the metal easier to passivate. (c) Obtain a single-phase structure with uniform chemical composition, microstructure, and metal purity, aiming to avoid the formation of microcells.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何提高钢的耐腐蚀性，答案提供了详细的文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求对提高钢材耐腐蚀性的方法进行解释和论述，涉及多个概念（电极电位、钝化、单相结构等）的关联和综合分析，需要一定的理解和应用能力，但不需要复杂的创新或深度设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握提高钢材耐腐蚀性的多种方法，并能够区分不同方法的原理和效果。正确选项涉及电极电位、钝化现象以及微观结构等概念，需要考生具备一定的综合分析能力。虽然题目提供了具体选项，但需要对材料科学中的腐蚀防护有较深入的理解才能准确选择最佳答案。" + }, + { + "idx": 3493, + "question": "What are the characteristics of cast iron and carbon steel in terms of mechanical properties?", + "answer": "Cast iron has low tensile strength, compressive strength similar to steel with the same matrix, and poor plasticity and toughness; carbon steel has higher strength and better plasticity and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述铸铁和碳钢在机械性能方面的特点，答案提供了详细的文字描述而非选择、判断或计算。 | 知识层次: 题目考查对铸铁和碳钢机械性能基本特征的记忆和理解，属于基础概念层面的知识。 | 难度: 该题目在选择题型中属于中等偏下难度。虽然需要考生同时掌握铸铁和碳钢的机械性能特点（包括抗拉强度、抗压强度、塑性、韧性等），但题目仅要求对两种材料的基本特性进行对比描述，不涉及复杂的概念体系或深入的分析。正确选项直接给出了两种材料的特性对比，属于概念解释和描述层面的知识，符合等级2的标准。" + }, + { + "idx": 3494, + "question": "How to distinguish between 45 steel and HT150 metals through metallographic examination", + "answer": "Metallographic examination", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述如何通过金相检验区分45钢和HT150金属，答案形式为文字描述而非选择、判断或计算。 | 知识层次: 题目要求通过金相检验区分45钢和HT150金属，这需要理解两种材料的基本金相组织特征，并能进行对比分析。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属材料的基本特性（如45钢和HT150铸铁的组织结构差异），掌握金相检验的基本原理和方法，并能综合分析金相组织特征来区分两种材料。这涉及多个概念的关联应用，但不需要多角度或深度关联性分析。" + }, + { + "idx": 3495, + "question": "What measures should be taken to improve the strength of stainless steel?", + "answer": "Measures: Work hardening. Some martensitic stainless steels (such as 4Cr13) can be strengthened through heat treatment (quenching + low-temperature tempering).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何提高不锈钢的强度，答案提供了文字解释和论述，没有选项、对错判断或数值计算的需求。 | 知识层次: 题目要求回答提高不锈钢强度的措施，涉及工作硬化和热处理（淬火+低温回火）等具体工艺的应用。需要理解不同不锈钢类型（如马氏体不锈钢4Cr13）的特性及其强化机制，属于多概念关联和综合分析的应用层次。 | 难度: 在选择题中属于中等难度，题目要求理解不锈钢强化的具体措施（加工硬化和热处理），并需要关联不同种类不锈钢（如马氏体不锈钢4Cr13）的特定强化方法。虽然不涉及复杂计算，但需要对材料强化机制和热处理工艺有综合理解，属于概念关联和综合分析层次。" + }, + { + "idx": 3496, + "question": "What method is used to strengthen austenitic stainless steel in production?", + "answer": "Work hardening is commonly used to strengthen it in production.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种方法用于强化奥氏体不锈钢，答案提供了文字解释而非选择或判断，符合简答题的特征。 | 知识层次: 题目考查对奥氏体不锈钢强化方法的基础概念记忆，即冷加工硬化（work hardening）这一基本原理的应用。 | 难度: 在选择题型中，此题仅需记忆基础概念（奥氏体不锈钢的强化方法），属于最简单的定义性知识考察。题目直接给出正确选项\"work hardening\"，不需要任何解释或分析步骤，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3497, + "question": "How to distinguish between 45 steel and HT150 metals through macroscopic fracture analysis", + "answer": "Macroscopic fracture analysis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来区分两种金属材料，答案形式为文字描述而非选择、判断或计算。 | 知识层次: 题目要求通过宏观断口分析区分45钢和HT150金属，这需要理解两种材料的断口特征（如45钢的韧性断裂和HT150的脆性断裂），并能将这些特征与实际观察结果关联起来进行分析。虽然不涉及复杂计算，但需要综合运用材料科学知识进行判断，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属材料的宏观断裂特征（如45钢的韧性断裂和HT150的脆性断裂表现），并能通过断口形貌（纤维状/结晶状）进行区分。题目要求将材料性能知识与实际观察技能结合，但无需多角度或深度关联性分析。" + }, + { + "idx": 3498, + "question": "What are the compositional characteristics of stainless steel?", + "answer": "The compositional characteristics of stainless steel are: (a) Low carbon content: Most w_C = (0.1-0.2)%. C has a strong affinity with Cr, and C and Cr can form a series of complex compounds, reducing the corrosion resistance of the steel. (b) Stainless steel generally contains a high amount of chromium (the mass fraction of Cr in martensitic and ferritic stainless steels is greater than 13%, and the mass fraction of Cr in austenitic stainless steel is greater than 18%) and a high amount of nickel (the mass fraction of Ni in austenitic stainless steel is greater than 8%). (c) The carbon content is generally low, with the mass fraction of C in austenitic and ferritic stainless steels being relatively low (<0.1%).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释不锈钢的成分特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目主要考查不锈钢的成分特征这一基础概念的记忆和理解，涉及碳含量、铬和镍的含量等基本知识点，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及不锈钢的成分特性，但正确选项已经提供了明确的成分范围和解释，不需要考生进行复杂的推理或计算。主要考察的是对不锈钢基本成分的记忆和理解，属于概念解释和描述的层次。" + }, + { + "idx": 3499, + "question": "Why is it often easy to form white iron on the surface layer and thin-walled areas of the same casting?", + "answer": "Because the undercooling degree is large and the cooling rate is fast at the surface layer and thin-walled areas, it is easy to obtain white iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么在铸件的表层和薄壁区域容易形成白口铁，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解白口铁形成的条件（过冷度和冷却速率），并将其与铸件表面层和薄壁区域的特点联系起来进行分析。这涉及到多个概念的关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及铸铁凝固过程中的冷却速率和过冷度对组织形成的影响，要求考生能够将表面层和薄壁区域的冷却条件与白口铁的形成联系起来。虽然不需要复杂的计算，但需要对材料科学中的凝固原理有较好的理解，并能综合分析不同区域的冷却条件差异对组织的影响。" + }, + { + "idx": 3500, + "question": "Compare the composition of HT150 and annealed 20 steel", + "answer": "Composition: a) HT150: w_C=(2.5~4)%, w_Si=(1~2.5)%, w_Mn=(0.5~1.3)%, w_P≤0.3%, w_S≤0.15%. b) 20 steel: w_C=(0.17~0.24)%, w_Mn=(0.35~0.65)%, w_Si=(0.17~0.37)%, w_P≤0.035%, w_S≤0.035%. Composition difference: The mass fractions of C, Si, P, and S are higher in cast iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种材料的成分，答案提供了详细的成分对比和差异分析，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对HT150和20钢成分的记忆和基本理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目需要考生记忆并比较两种材料的成分范围，涉及基础概念记忆和简单的对比分析。虽然需要掌握多个元素的含量范围，但不需要复杂的推理或计算步骤，属于概念解释和描述的难度等级。" + }, + { + "idx": 3501, + "question": "What is the main difference between cast iron and carbon steel?", + "answer": "The main difference between carbon steel and cast iron lies in the carbon content and the form of carbon present. The carbon content in cast iron is greater than 2.11%, while that in carbon steel is greater than 0.0218% but less than 2.11%. In carbon steel, apart from a portion dissolved in ferrite, all other carbon exists in the form of Fe3C. In cast iron, a small amount of carbon is dissolved in ferrite, while most of the carbon exists in the form of graphite (gray cast iron) or Fe3C (white cast iron). The microstructure is not entirely the same, leading to differences in properties (both processing and service performance).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释cast iron和carbon steel的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对碳钢和铸铁的基本区别的记忆和理解，主要涉及碳含量和碳的存在形式等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分两种材料（铸铁和碳钢）在碳含量和碳存在形式上的差异。正确选项提供了较为详细的解释，包括碳含量的具体范围、碳的存在形式（Fe3C或石墨）以及由此导致的性能差异。这要求考生不仅记住定义，还要能够理解和比较这些概念。因此，在选择题型内，该题目属于等级2（概念解释和描述）难度。" + }, + { + "idx": 3502, + "question": "What are the process characteristics of high-speed steel?", + "answer": "Process characteristics of high-speed steel: a) Two-stage preheating: reduces thermal stress, minimizes deformation and cracking. b) High quenching temperature: ensures full dissolution of W and V into austenite, allowing alloy carbides to precipitate during tempering, thereby ensuring red hardness. c) Graded quenching: reduces deformation and cracking. d) 560‰ tempering: achieves maximum hardness with secondary hardening and secondary quenching phenomena. e) Triple tempering: reduces retained austenite from over 20% after quenching to approximately 1%–2%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释高速钢的工艺特性，答案提供了详细的文字描述和论述，符合简答题的特征 | 知识层次: 题目要求解释高速钢的工艺特性，涉及多个工艺步骤（如预热、淬火、回火等）及其原理，需要将不同工艺步骤与材料性能关联起来进行综合分析。虽然不涉及复杂计算，但需要对工艺参数和材料行为有较深入的理解和关联分析。 | 难度: 在选择题型内，该题目属于较高难度，因为它要求考生不仅理解高速钢的基本特性，还需要掌握其具体的工艺特点及其背后的原理。题目涉及多个工艺步骤（如两段预热、高淬火温度、分级淬火、560‰回火和三次回火），每个步骤都有其特定的目的和效果，考生需要综合分析这些步骤之间的关系及其对材料性能的影响。此外，题目还要求考生能够理解并关联诸如热应力、变形、裂纹、红硬性、二次硬化等专业概念，这需要较深的知识掌握和综合分析能力。因此，在选择题型内，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 3503, + "question": "Is Cr12MoV a stainless steel?", + "answer": "Cr12MoV is not a stainless steel, it is a cold work die steel. The w_Cr of stainless steel is ≥13%.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断\"Cr12MoV is a stainless steel\"这一陈述的对错，答案明确给出了判断结果和解释，符合判断题的特征。 | 知识层次: 题目考查对不锈钢定义和Cr12MoV钢种分类的基本概念记忆，仅需判断材料类型是否符合不锈钢的铬含量标准，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念正误判断，仅需记忆不锈钢的基本定义（铬含量≥13%）和Cr12MoV钢的分类即可作答。在选择题型中，这类直接考查定义记忆的题目属于最低难度等级。" + }, + { + "idx": 3504, + "question": "Compare the compressive strength of HT150 and annealed 20 steel", + "answer": "The tensile strength and hardness of the two are not much different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的压缩强度，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的压缩强度，涉及对材料性能的理解和对比分析，需要综合运用材料科学知识进行多步思考和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解HT150和退火20钢的压缩强度特性，并进行比较分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了关键比较点，降低了答题的复杂性。" + }, + { + "idx": 3505, + "question": "Why does cast iron with a chemical composition of 'three lows' (low carbon, silicon, and manganese content) and 'one high' (high sulfur content) tend to form white iron during production?", + "answer": "Because both carbon and silicon are graphitization-promoting elements, their low content facilitates the formation of white iron structure. Although manganese is a graphitization-inhibiting element, its low mass fraction cannot counteract the effect of sulfur, making the sulfur's role in inhibiting graphitization more pronounced and thus favoring the production of white cast iron. Since sulfur is a graphitization-inhibiting element, low carbon, silicon, and manganese combined with high sulfur content easily lead to the formation of white iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么特定化学成分的铸铁在生产过程中容易形成白口铁，需要详细的文字解释和论述，而不是选择、判断或计算。答案提供了详细的论述，解释了各种元素对石墨化的影响，符合简答题的特征。 | 知识层次: 题目需要解释铸铁中化学成分对组织形成的影响机制，涉及多个元素的相互作用（碳、硅、锰、硫）及其对石墨化的促进或抑制作用。这需要综合运用材料科学中的相变原理和合金元素效应，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3506, + "question": "Compare the microstructures of HT150 and annealed 20 steel", + "answer": "Microstructure: a) HT150: F+P+G (graphite); b) 20 steel: F+P.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种材料的微观结构，答案需要文字解释和论述，没有提供选项或要求计算，属于简答题类型。 | 知识层次: 题目主要考查对HT150和20钢两种材料微观结构的基础概念记忆，包括铁素体(F)、珠光体(P)和石墨(G)等基本组织的识别，属于材料科学中基础知识的记忆和理解层面。 | 难度: 在选择题型中，该题目要求考生记忆并区分两种不同材料的微观结构组成（HT150的F+P+G和20钢的F+P）。虽然涉及基础概念的记忆，但需要考生掌握两种材料的分类和基本组成，属于概念解释和描述的难度等级。题目不涉及复杂的概念体系或深入的分析，因此难度适中。" + }, + { + "idx": 3507, + "question": "Compare the welding performance of HT150 and annealed 20 steel", + "answer": "The welding performance of 20 steel is better than that of HT150.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的焊接性能，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的焊接性能，需要理解材料的基本性质（如HT150是铸铁，20钢是低碳钢）以及焊接性能的影响因素（如碳含量、热处理状态等），并进行综合分析。这涉及到多个概念的关联和中等程度的分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解HT150和20钢的焊接性能特点，并进行比较分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了明确的比较结论，降低了分析难度。" + }, + { + "idx": 3508, + "question": "Compare the hardness of HT150 and annealed 20 steel", + "answer": "The tensile strength and hardness are not significantly different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的硬度，答案需要文字解释和论述，而非选择、判断或计算 | 知识层次: 题目要求比较两种材料的硬度，涉及对材料性能（HT150和20钢）的理解和应用，需要综合分析不同热处理状态（退火）对材料性能的影响。虽然不涉及复杂计算，但需要对材料科学中的基本概念（如硬度、热处理）有较深的理解，并能进行概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解HT150和annealed 20 steel的基本性能特点，并能够比较它们的硬度和抗拉强度。虽然不涉及复杂的计算，但需要对材料性能有基本的了解，并能进行简单的综合分析。" + }, + { + "idx": 3509, + "question": "Compare the anti-friction properties of HT150 and annealed 20 steel", + "answer": "HT150 has better anti-friction properties than 20 steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的抗摩擦性能，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的抗摩擦性能，需要理解材料的基本性质（如HT150的铸铁特性和20钢的退火状态特性），并分析这些性质如何影响抗摩擦性能。这涉及多步分析和概念关联，但不需要复杂的机理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解HT150和20钢的材料特性，并进行抗摩擦性能的比较分析。题目要求考生综合运用材料科学知识，对两种材料的性能进行对比，涉及多步计算和概念关联。" + }, + { + "idx": 3510, + "question": "In the graphitization process of cast iron, if the first stage is completely graphitized and the second stage is partially graphitized, what kind of microstructure cast iron is obtained?", + "answer": "F+P+G (graphite)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述铸铁在特定石墨化条件下获得的微观结构，答案需要给出具体的组织组成（F+P+G），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解铸铁石墨化过程的不同阶段及其对最终显微组织的影响，涉及多阶段石墨化程度的判断和显微组织组成的综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铸铁石墨化过程的两个阶段及其对最终显微组织的影响，并能将部分石墨化与特定组织（F+P+G）关联起来。虽然不涉及复杂计算，但需要对概念有较深的理解和综合分析能力。" + }, + { + "idx": 3511, + "question": "In the graphitization process of cast iron, if the first stage is completely graphitized and the second stage is not graphitized, what type of cast iron structure is obtained?", + "answer": "P+G (graphite)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要解释在铸铁石墨化过程中特定条件下的结构类型，答案以文字形式给出（P+G (graphite)），属于简答题类型 | 知识层次: 题目考查对铸铁石墨化过程的基础概念记忆，只需识别石墨化不同阶段的结果对应的铸铁结构类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对铸铁石墨化过程基础概念的记忆，即知道第一阶段完全石墨化和第二阶段未石墨化会得到P+G（石墨）结构的铸铁。不需要解释或分析复杂概念体系，只需识别正确选项即可。" + }, + { + "idx": 3512, + "question": "Compare the machinability of HT150 and annealed 20 steel", + "answer": "The machinability of HT150 is better than that of 20 steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的机械加工性能，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的可加工性，需要理解材料性能（如硬度、强度等）与可加工性的关系，并进行综合分析。这涉及多个概念的关联和应用，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解HT150和20钢的机械加工性能概念，并进行比较分析。虽然题目涉及两种材料的比较，但在选择题型中，只需识别出正确选项，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3513, + "question": "Please indicate the type of cast iron and heat treatment method that should be used for the machine tool bed, and why?", + "answer": "Machine tool bed: gray cast iron, (as-cast) HT250, stress relief annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述选择特定铸铁类型和热处理方法的理由，答案提供了具体的材料选择和热处理工艺，并隐含需要解释\"why\"的部分，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求选择特定类型的铸铁和热处理工艺，并解释原因。这需要理解铸铁的分类、性能特点及其应用场景，以及热处理工艺对材料性能的影响。虽然不涉及复杂的计算或深度机理分析，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 3514, + "question": "Compare the casting properties of HT150 and annealed 20 steel", + "answer": "The casting properties of HT150 are better than those of 20 steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的铸造性能，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的铸造性能，涉及对HT150和20钢的铸造性能的理解和综合分析，需要关联不同材料的特性并进行对比分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解HT150和20钢的铸造性能概念，并进行比较分析。题目要求考生综合两种材料的特性，判断其铸造性能优劣，涉及多步概念关联和综合分析。" + }, + { + "idx": 3515, + "question": "Compare the tensile strength of HT150 and annealed 20 steel", + "answer": "The tensile strength of 20 steel is much higher than that of HT150.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的拉伸强度，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的拉伸强度，需要理解HT150和20钢的基本性能特点，并能够分析退火处理对20钢性能的影响。这涉及到材料性能的综合分析和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解HT150和20 steel的力学性能特点，并进行比较分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了明确的结论，减少了推理的复杂性。" + }, + { + "idx": 3516, + "question": "Compare the forgeability of HT150 and annealed 20 steel", + "answer": "The forgeability of 20 steel is better than that of HT150 (HT150 cannot be forged).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的可锻性，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的可锻性，需要理解材料的基本性质（如HT150是铸铁不可锻造，20钢经退火后可锻造性较好），并能够将这些概念关联起来进行综合分析。虽然不涉及复杂计算，但需要对材料性质有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解HT150和20钢的锻造性能差异，并综合分析材料状态（退火）对锻造性能的影响。虽然不需要多步计算，但需要关联材料特性和工艺知识进行判断。" + }, + { + "idx": 3517, + "question": "In the graphitization process of cast iron, if the first stage is completely graphitized and the second stage is completely graphitized, what type of cast iron structure is obtained?", + "answer": "F+G (graphite)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是一个简短的描述（F+G (graphite)），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查铸铁石墨化过程的基本概念和最终组织类型的记忆，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目仅考察对铸铁石墨化过程基础概念的记忆，属于直接回忆型问题。只需知道两个阶段完全石墨化后的产物是F+G（石墨）结构即可作答，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3518, + "question": "Please specify the type of cast iron and heat treatment method that should be used for diesel engine crankshafts, and why?", + "answer": "Crankshaft: ductile iron, QT800-2, quenching and tempering treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述特定材料选择和热处理方法的理由，答案提供了详细的文字说明而非简单的选择或判断。 | 知识层次: 题目要求选择特定类型的铸铁和热处理工艺，并解释原因。这需要将材料性能（如球墨铸铁QT800-2的特性）与工程应用（柴油机曲轴的工作条件）相关联，进行多因素综合分析。虽然不涉及复杂计算，但需要理解材料选择与热处理的关联性，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅需要识别正确的材料类型（球墨铸铁）和热处理方式（淬火+回火），还需要理解QT800-2牌号的含义以及这些选择背后的工程原理（如高强度、耐磨性要求）。这涉及多概念的综合应用和材料性能的深度关联分析，超出了简单记忆或单一概念应用的范畴，属于较高难度的选择题。" + }, + { + "idx": 3519, + "question": "Please indicate the type of cast iron and heat treatment method that should be used for plowshares, and why?", + "answer": "Plowshare: white cast iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述适合犁铧的铸铁类型和热处理方法及其原因，需要文字解释而非选择、判断或计算 | 知识层次: 题目要求选择铸铁类型和热处理方法，并解释原因。这需要理解不同铸铁的特性及其应用场景，以及热处理方法对性能的影响。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道不同类型的铸铁及其特性，还需要理解不同应用场景下材料的选择依据。此外，题目还涉及热处理方法的考虑，这需要考生将材料特性与实际应用需求进行关联分析。虽然题目给出了正确选项，但考生仍需具备一定的综合分析能力才能做出正确选择。" + }, + { + "idx": 3520, + "question": "Please indicate the type of cast iron and heat treatment method that should be used for the hydraulic pump housing, and why?", + "answer": "Hydraulic pump housing: malleable cast iron, KΠ2650-02, graphitizing annealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释选择特定铸铁类型和热处理方法的理由，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目要求选择适当的铸铁类型和热处理方法，并解释原因。这需要理解铸铁的分类、性能特点以及热处理方法的应用，属于多概念关联和综合分析的应用层次。虽然不涉及复杂的计算或深度机理分析，但需要对材料性能和应用场景有一定的理解和判断能力。 | 难度: 在选择题型内，该题目属于较高难度，因为它不仅要求考生识别正确的铸铁类型和热处理工艺（可锻铸铁KΠ2650-02和石墨化退火），还需要理解为什么这些选择适用于液压泵壳体。这涉及对材料性能（如强度、韧性、加工性）与部件功能要求的综合分析，以及热处理工艺对材料微观结构和性能的影响。考生需要将多个概念（铸铁类型、热处理工艺、部件应用场景）关联起来进行多角度分析，而不仅仅是记忆或简单识别。因此，在选择题型中，这属于需要较深入理解和综合分析的题目。" + }, + { + "idx": 3521, + "question": "Please specify the type of cast iron and heat treatment method that should be used for ball mill liners, and why?", + "answer": "Ball mill liners: alloy nodular cast iron (such as medium manganese cast iron).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述特定材料的选择原因，答案需要文字说明而非简单选择或判断 | 知识层次: 题目要求选择特定类型的铸铁和热处理方法来满足球磨机衬板的使用需求，这需要理解不同铸铁材料的性能特点及其热处理工艺的影响，属于多概念关联和综合分析的应用层次。虽然不涉及复杂的计算或深度机理分析，但需要综合考虑材料选择与工艺匹配的合理性。 | 难度: 在选择题型内，该题目要求考生不仅掌握球磨机衬板材料的基本选择标准，还需要理解合金球墨铸铁（如中锰铸铁）的具体特性和适用原因。这涉及到多步概念关联和综合分析，包括材料性能、应用场景和热处理方法的匹配。虽然题目提供了正确选项，但考生仍需具备较深的知识储备和实际应用能力才能准确判断，因此属于较高难度等级。" + }, + { + "idx": 3522, + "question": "Can aluminum alloys be strengthened through martensitic transformation like steel? Why?", + "answer": "No. Because aluminum alloys only undergo solubility changes during heating and cooling in the solid state, without allotropic transformation. Therefore, they can only be strengthened by quenching + aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么铝合金不能像钢一样通过马氏体转变强化，需要文字解释和论述，答案也提供了详细的解释说明。 | 知识层次: 题目需要理解铝合金和钢的强化机制差异，涉及溶解度变化、同素异构转变等概念的综合分析，并解释为什么铝合金不能通过马氏体转变强化。这需要将多个概念关联起来进行中等程度的综合分析。 | 难度: 在选择题中属于中等难度，需要理解铝合金和钢的强化机制差异，并综合分析铝合金的固溶和时效强化原理。虽然涉及多个概念，但选项提供了明确的解释路径，不需要多角度或深度关联性分析。" + }, + { + "idx": 3523, + "question": "Explain the alloying principles of aluminum alloys", + "answer": "Alloying principles of aluminum alloys: Commonly added elements: Cu, Mg, Zn, Si, Mn", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释铝合金的合金化原理，答案提供了常见的添加元素，但需要进一步的文字解释和论述来完整回答问题。 | 知识层次: 题目考查铝合金合金化原理的基本概念，包括常用添加元素，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型内，该题目仅要求记忆铝合金融合的基本原则和常见添加元素，属于基础概念记忆，无需深入理解或复杂分析。题目直接给出正确选项，考察的是对基本定义和分类的记忆，因此难度等级为1。" + }, + { + "idx": 3524, + "question": "Explain the role of Cu element in aluminum alloys", + "answer": "Copper in aluminum not only significantly enhances the room temperature strength of aluminum alloys through solid solution strengthening and precipitation strengthening, but also improves the heat resistance of aluminum alloys. Therefore, copper is a primary alloying element in high-strength aluminum alloys and heat-resistant aluminum alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铜元素在铝合金中的作用，需要文字解释和论述，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释铜元素在铝合金中的作用，涉及固溶强化和沉淀强化等概念的综合应用，需要理解铜元素如何通过这些机制提高铝合金的强度和耐热性。虽然不涉及复杂的计算或深度推理，但需要对多个概念进行关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解铜元素在铝合金中的多重作用（固溶强化、沉淀强化、耐热性提升），并能综合分析这些效应与合金性能的关联。题目涉及中等应用层次的知识点，要求考生将多个概念联系起来，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3525, + "question": "Explain the role of Mn element in aluminum alloys", + "answer": "Manganese has low solubility in aluminum, resulting in limited solid solution strengthening capability. The second phase MnAl6 in the Al-Mn system has electrochemical properties similar to aluminum, providing good corrosion resistance. Therefore, manganese is often added to rust-proof aluminum alloys, with its wMn generally not exceeding 2%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Mn元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Mn元素在铝合金中的作用，涉及Mn在Al中的固溶度、第二相MnAl6的电化学性质及其对合金性能的影响，需要理解多个概念并进行关联分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握Mn元素在铝合金中的作用，包括其溶解度限制、第二相MnAl6的电化学性质以及在实际应用中的添加量限制。这些知识点需要考生对铝合金的强化机制和腐蚀性能有一定的理解，并能将这些概念关联起来进行综合分析。虽然题目提供了具体的信息，但需要考生在选择题的选项中识别和匹配这些知识点，因此属于中等难度。" + }, + { + "idx": 3526, + "question": "Explain the role of Si element in aluminum alloys", + "answer": "Similar to manganese, silicon has low solubility in aluminum, resulting in limited solid solution strengthening and insignificant precipitation strengthening effects. Therefore, it primarily relies on excess phase strengthening. The binary Al-Si system alloy has a low eutectic point, making it suitable for casting, and serves as the foundational alloy series for cast aluminum alloys, with wSi typically ranging from 10% to 13%. Silicon and magnesium can form Mg2Si precipitates in aluminum, which exhibit excellent strengthening effects. Hence, silicon can also be added as a precipitation strengthening element to magnesium-aluminum alloys, with its addition amount usually not exceeding wSi (1.0~1.2)%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释硅元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释硅元素在铝合金中的作用，涉及多个知识点如固溶强化、沉淀强化和过剩相强化等，需要综合分析硅在不同铝合金体系中的具体作用和影响。虽然不涉及复杂计算，但需要对材料科学中的强化机制和相图有一定的理解和应用能力。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解硅元素在铝合金中的基本作用，还需要综合分析其在固溶强化、析出强化以及过剩相强化中的具体表现。此外，题目还涉及二元Al-Si合金的共晶点、铸造适用性以及硅与镁形成Mg2Si析出物的强化效果等复杂概念。这些知识点需要考生进行多角度分析和关联性思考，因此在选择题型中属于较难的水平。" + }, + { + "idx": 3527, + "question": "Explain the role of Mg element in aluminum alloys", + "answer": "Magnesium has a good solid solution strengthening effect in aluminum, which can increase the strength of aluminum while also reducing its density. The precipitation strengthening effect of magnesium-aluminum alloys is not significant, but they exhibit good corrosion resistance and can be used as corrosion-resistant alloys. Magnesium cannot serve as the main additive element for high-strength aluminum alloys alone; it must be combined with other elements to fully utilize its effects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释镁元素在铝合金中的作用，涉及固溶强化、沉淀强化、腐蚀抗力等多个概念的综合应用，需要理解镁元素与其他元素的协同效应，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解镁在铝合金中的基本固溶强化作用，还需要综合分析其与其他元素的协同效应、对密度的影响、腐蚀性能以及在高强度铝合金中的应用限制。这涉及多角度分析论述，超出了简单的概念记忆或单一知识点应用，属于较高难度的选择题。" + }, + { + "idx": 3528, + "question": "What is the difference between natural aging and artificial aging of aluminum alloys?", + "answer": "The process of spontaneous strengthening of the alloy at room temperature is called natural aging, while the aging process carried out at a certain heating temperature is called artificial aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释自然时效和人工时效的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对自然时效和人工时效的基本定义和区别的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生区分自然时效和人工时效的定义，属于概念解释和描述的层次。虽然需要记忆两个不同的定义，但不需要复杂的分析或比较多个概念体系，因此属于中等难度。" + }, + { + "idx": 3529, + "question": "Can aluminum alloys be surface strengthened by carburizing or nitriding? Why?", + "answer": "No. Because the solubility of C and N in aluminum is very low, especially since aluminum has a strong affinity for oxygen, forming a very dense oxide film on the surface. This prevents the active atoms from being absorbed by the surface during carburizing or nitriding. Even if the active atoms are absorbed by the surface, the dense oxide film hinders the diffusion of these absorbed atoms toward the core. Therefore, aluminum alloys cannot be surface strengthened by carburizing or nitriding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么铝合金不能通过渗碳或渗氮进行表面强化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解铝及其合金的基本性质（如氧化膜的形成），还需要分析碳和氮在铝中的溶解度及其对表面强化工艺的影响。此外，还需要解释为什么这些工艺在铝中不可行，涉及多个概念的关联和综合分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目不仅要求考生掌握铝及铝合金的基本性质（如氧化膜形成倾向、碳氮溶解度低等），还需要综合运用材料科学原理（扩散机制、表面反应动力学）进行深度推理分析。正确选项涉及多步骤逻辑链条：从热力学（溶解度限制）到动力学（氧化膜阻碍扩散）的完整机理解释，且需要理解这些因素如何共同导致表面强化工艺失效。这种在选择题中要求全面分析复杂现象并整合多个高阶知识点的题目，在选择题型内属于最难级别。" + }, + { + "idx": 3530, + "question": "Taking A1-4Cu alloy as an example, explain the changes in microstructure and properties during the aging process.", + "answer": "Aging refers to the phenomenon where the supersaturated solid solution of aluminum alloy obtained after quenching decomposes over time at a certain temperature, leading to an increase in the strength and hardness of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释A1-4Cu合金在时效过程中微观结构和性能的变化，需要详细的文字解释和论述，符合简答题的特征。答案也提供了详细的文字解释，而非选择、判断或计算。 | 知识层次: 题目要求解释A1-4Cu合金在时效过程中微观结构和性能的变化，这需要综合运用材料科学中的相变、强化机制等知识，进行推理分析和机理解释，涉及多个知识点的关联和深入理解。 | 难度: 在选择题型中，该题目要求考生不仅理解铝合金时效处理的基本概念，还需要掌握微观结构变化与性能提升之间的机理关系。正确选项涉及对过饱和固溶体分解过程的解释，以及时效过程中强度硬度变化的因果关系，属于需要机理深度解释的复杂分析题。相比单纯记忆性选择题，该题需要更高层次的综合推理能力，因此在选择题型中属于较高难度(等级4)。" + }, + { + "idx": 3531, + "question": "Explain the role of Zn element in aluminum alloys", + "answer": "Zinc has a high solubility in aluminum and exhibits strong solid solution strengthening capability. A small amount of zinc (wZn=(0.4~0.8)%) can enhance the strength and corrosion resistance of aluminum alloys. In multi-component aluminum alloys, zinc serves as an element that forms precipitation strengthening phases, significantly improving the precipitation strengthening effect of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释锌元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释锌元素在铝合金中的作用，涉及溶解度、固溶强化、沉淀强化等多个概念的综合应用，需要理解锌元素对铝合金性能的影响机制，并进行一定的关联分析。 | 难度: 在选择题中属于中等难度，题目要求理解锌在铝合金中的多种作用（固溶强化、耐腐蚀性提升、沉淀强化相形成），并综合分析这些效应如何共同提升合金性能。虽然不涉及多步计算，但需要关联多个概念并理解其相互作用，符合等级3的综合分析要求。" + }, + { + "idx": 3532, + "question": "What is the principle for selecting natural aging or artificial aging?", + "answer": "The principles for choosing between artificial aging and natural aging are: ① Determine the aging method (natural or artificial) based on the working temperature of the part; ② Consider the required aging strengthening effect for the part; ③ Take into account the type of aluminum alloy, batch size of the workpiece, production efficiency, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释选择自然时效或人工时效的原则，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求考生综合考虑多个因素（工作温度、强化效果、合金类型、批量大小等）来选择时效处理方法，涉及概念关联和综合分析能力，超出了单纯记忆或简单应用的范畴，但尚未达到复杂分析或创新设计的深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生综合考虑工作温度、强化效果、铝合金类型、批量大小和生产效率等多个因素来选择自然时效或人工时效的方法。这需要考生具备一定的综合分析能力，能够将多个相关概念联系起来，但不需要进行过于复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 3533, + "question": "How many types of titanium alloys are there?", + "answer": "Titanium alloys are classified into α titanium alloys, α+β titanium alloys, and β titanium alloys", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要回答钛合金的分类类型，答案以文字解释的形式给出，不需要选择、判断或计算 | 知识层次: 题目考查钛合金的基本分类记忆，属于基础概念的记忆和理解层面，不涉及复杂分析或应用。 | 难度: 在选择题型中，此题仅需要记忆钛合金的基本分类（α、α+β、β三种类型），属于最基础的定义性知识。题目不涉及概念解释或复杂体系阐述，只需简单回忆分类名称即可作答，因此属于难度等级1。" + }, + { + "idx": 3534, + "question": "Briefly describe the generation of solid solution strengthening and provide examples", + "answer": "Solid solution strengthening refers to the increase in strength by adding alloying elements to form solid solutions with aluminum. Commonly used alloying elements include Cu, Mg, Zn, Si, etc. These elements can form limited solid solutions with aluminum and have significant solubility, resulting in effective solid solution strengthening, thus serving as the primary alloying elements in aluminum alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述固溶强化的产生并提供例子，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对固溶强化这一基础概念的记忆和理解，包括其定义、作用机制以及常见合金元素的举例，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述固溶强化的生成机制并提供例子，但正确选项已经给出了明确的定义和具体的合金元素例子（Cu, Mg, Zn, Si等）。这要求考生不仅记住基本定义，还需要理解固溶强化的基本原理和常见应用。因此，该题目在选择题型中属于概念解释和描述的难度等级。" + }, + { + "idx": 3535, + "question": "Briefly describe the generation of dispersion strengthening and provide examples", + "answer": "Excess phase (second phase) strengthening: When the content of alloying elements in an alloy exceeds the solubility limit, there will be some undissolved second phases present in the matrix (solid solution), also known as excess phases. In aluminum alloys, excess phases are mostly hard and brittle intermetallic compounds, which also hinder dislocation movement, increasing the strength and hardness of the alloy while reducing its plasticity and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述弥散强化的产生并提供例子，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对分散强化生成的基本概念的理解和记忆，包括定义、基本原理和简单例子，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生不仅能够记忆分散强化的基本定义，还需要理解其背后的原理（如第二相的形成机制及其对材料性能的影响）。虽然题目提供了具体的例子（铝合金中的金属间化合物），但考生仍需具备一定的概念解释能力，能够将理论知识与实际应用联系起来。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的深度（等级3）。" + }, + { + "idx": 3536, + "question": "Briefly describe the differences between solution strengthening, dispersion strengthening, and age strengthening", + "answer": "Solution strengthening improves strength by forming solid solutions with alloying elements and the matrix; dispersion strengthening enhances strength by impeding dislocation movement through undissolved second phases (excess phases); age strengthening is achieved by heat treatment to form supersaturated solid solutions and precipitate transition phases or transition zones. Both solution strengthening and age strengthening involve solid solutions, but age strengthening requires subsequent heat treatment processes, while dispersion strengthening does not rely on heat treatment but rather on the formation of second phases due to alloying elements exceeding solubility limits.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述三种强化机制的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释三种强化机制的区别，涉及多个概念的理解和关联，需要综合分析不同强化方法的原理和特点，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解三种强化机制的基本概念，还需要能够区分它们的异同点。具体来说，题目涉及多个知识点（固溶强化、弥散强化和时效强化）的综合分析，需要考生能够关联这些概念并理解它们之间的相互作用和区别。此外，题目还要求考生能够识别不同强化机制所依赖的条件（如热处理、溶解度限制等），这增加了题目的复杂性和难度。因此，在选择题型内，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 3537, + "question": "Compare the microstructure, properties, and heat treatment characteristics of brass.", + "answer": "
MaterialMicrostructurePropertiesHeat Treatment
Brassα (Cu-Zn solid solution) or α+βExcellent corrosion resistance, thermal conductivity, good cold (or hot) working propertiesStress relief annealing
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较黄铜的微观结构、性能和热处理特性，答案以表格形式详细列出了这些方面的信息，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较黄铜的微观结构、性能和热处理特性，涉及多个知识点的关联和综合分析，需要理解不同成分黄铜的微观结构差异及其对性能和热处理的影响，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对黄铜的微观结构、性能特点以及热处理特性进行多角度的分析和比较。虽然题目提供了表格形式的正确选项，但考生需要具备对材料科学中相关概念的深入理解，能够关联不同知识点（如相图、材料性能、热处理工艺等），并进行综合分析。这种题目不仅考察记忆能力，更注重对知识点的应用和关联能力，因此在选择题型中属于较高难度。" + }, + { + "idx": 3538, + "question": "Compare the microstructure, properties, and heat treatment characteristics of bronze.", + "answer": "
MaterialMicrostructurePropertiesHeat treatment
Bronzea (Cu-Sn) or (a+0) eutectoidExcellent casting performance, corrosion resistance, hot and cold pressure processing performance, certain wear resistance and antifriction properties, can be used as bearing alloyQuenching + aging (beryllium bronze)
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较青铜的微观结构、性能和热处理特性，答案以表格形式详细列出了这些方面的具体内容，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较青铜的微观结构、性能和热处理特性，涉及多个知识点的关联和综合分析，需要理解不同特性之间的关系，并进行一定的归纳总结。 | 难度: 在选择题型中，该题目要求对青铜的微观结构、性能和热处理特性进行多角度分析论述。虽然题目提供了正确选项，但需要考生具备较深的知识点掌握深度，能够理解并关联多个概念（如Cu-Sn合金的微观结构、性能特点及热处理工艺）。此外，题目涉及的知识层次为中等应用，要求考生进行多步计算、概念关联和综合分析，因此在选择题型内属于较高难度。" + }, + { + "idx": 3539, + "question": "How to choose tin-based and lead-based babbitt alloys?", + "answer": "Tin-based bearing alloys are suitable for high-speed bearings. Lead-based bearing alloys are mostly used for small and low-speed ordinary machinery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释如何选择锡基和铅基巴氏合金，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查对锡基和铅基巴氏合金选择的基本概念记忆和理解，涉及它们的适用场景分类，不需要复杂的分析或综合应用。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。题目要求考生区分锡基和铅基巴氏合金的应用场景，这需要理解两种合金的基本特性和适用条件，但不需要深入分析或比较复杂的体系。正确选项直接提供了两种合金的典型应用场景，属于对基础概念的记忆和应用，符合等级2的描述。" + }, + { + "idx": 3540, + "question": "Briefly describe the occurrence of age strengthening and provide examples", + "answer": "Age strengthening (precipitation strengthening): The main heat treatment method for strengthening aluminum alloys is solution treatment (quenching) followed by aging. To achieve strong precipitation hardening effects, certain conditions must be met: the elements added to aluminum should have a high ultimate solubility, and this solubility should significantly decrease with temperature reduction; after quenching, a supersaturated solid solution should form, which can precipitate uniform and dispersed coherent or semi-coherent transition zones or transition phases during aging, creating a strong strain field in the matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述时效强化的发生过程并提供例子，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目不仅要求描述时效强化的基本概念（记忆和理解），还需要解释其背后的机理（如固溶处理、时效过程、过渡相形成等），并涉及多步骤的热处理工艺和材料性能变化的综合分析。这需要将多个知识点关联起来，并进行一定程度的推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对\"时效强化\"这一复杂现象进行全面分析，包括其热处理方法、必要条件、微观机制（如过饱和固溶体、共格/半共格过渡区形成）等深度机理解释。考生需要综合运用材料科学知识，理解溶解度变化、淬火效应、析出相与基体的相互作用等多个专业概念，并能够将这些概念串联起来形成完整的机理解释链条。这种在选择题中要求对复杂现象进行全面机理分析的题目，远超过简单记忆或基础理解的难度水平。" + }, + { + "idx": 3541, + "question": "Compare the microstructure, properties, and heat treatment characteristics of cupronickel.", + "answer": "
MaterialMicrostructurePropertiesHeat treatment
Cupronickelα (Cu-Ni solid solution)Good strength, excellent plasticity allowing hot and cold deformation, good corrosion resistance, high resistivityStress relief annealing
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较铜镍合金的微观结构、性能和热处理特性，需要文字解释和论述，答案以表格形式呈现了详细的比较内容，符合简答题的特征。 | 知识层次: 题目要求比较铜镍合金的微观结构、性能和热处理特性，涉及多个知识点的关联和综合分析，需要理解材料特性与处理工艺之间的关系，属于中等应用层次。 | 难度: 在选择题型中，该题目要求对cupronickel的微观结构、性能和热处理特性进行多角度分析论述。虽然题目提供了正确选项，但需要考生具备较深的知识掌握和综合分析能力，能够理解并关联多个概念（如固溶体结构、力学性能、热处理工艺等）。这种题目在选择题中属于较高难度，因为它不仅要求记忆知识点，还需要进行概念间的关联和比较分析。" + }, + { + "idx": 3542, + "question": "What are the characteristics of the microstructure, properties, and applications of typical α titanium alloys?", + "answer": "Microstructure: α or α + trace intermetallic compounds (annealed microstructure); Property characteristics: lower room temperature strength compared to other types of titanium alloys, but highest creep strength among titanium alloys at high temperatures (500~600°C), excellent corrosion resistance, good weldability, and retains good plasticity and toughness even at ultra-low temperatures (-253°C); Applications: parts with low strength requirements working below 500°C, pressure vessel materials in aerospace.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述α钛合金的微观结构特征、性能特点和应用领域，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目要求对α钛合金的微观结构、性能特点和应用进行综合描述，涉及多个知识点的关联和综合分析，需要理解材料性能与微观结构的关系，并能够结合实际应用场景进行论述。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握α钛合金的基本特性，还需要综合分析其微观结构、性能特点和应用场景之间的关联。题目涉及多个知识点（如微观结构、力学性能、耐腐蚀性、焊接性能等），并要求考生将这些知识点整合起来，理解其在特定温度条件下的表现和实际应用。这种多角度分析和概念关联的要求使得题目难度较高，属于选择题型中的等级4难度。" + }, + { + "idx": 3543, + "question": "What are the characteristics of the microstructure, properties, and applications of typical β titanium alloys?", + "answer": "Microstructure: β (quenched structure); Property characteristics: high strength, excellent stamping performance, can be strengthened by quenching and aging; Applications: parts working below 350°C, compressor blades, aircraft components", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对典型β钛合金的微观结构、性能和应用进行描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对β钛合金的微观结构、性能特点和应用进行综合描述，涉及多个知识点的关联和综合分析，需要理解并应用相关概念，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题型内，该题目需要考生对β钛合金的微观结构、性能特点和应用场景进行多角度的综合分析和关联。题目不仅要求掌握基础概念（如β相淬火组织），还需要理解性能特点（高强度、优良冲压性能）与热处理工艺（淬火时效强化）之间的关联，并能将材料特性与实际应用（350°C以下部件、压缩机叶片）进行对应。这种需要同时处理多个知识维度并进行逻辑关联的题目，在选择题中属于较高难度。" + }, + { + "idx": 3544, + "question": "What are the characteristics of Babbitt alloy in terms of lubrication principle?", + "answer": "It belongs to friction under the lubricating film. In terms of lubrication principle, it relies on the lubricating film formed between the shaft and the bearing bush to reduce the friction coefficient, thereby minimizing wear between the shaft and the bearing bush.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Babbitt合金在润滑原理方面的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Babbitt合金在润滑原理方面的基本特性，属于对材料基本概念和原理的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解Babbitt合金的润滑原理，并能够描述润滑膜的形成及其作用。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 3545, + "question": "The twinning plane of a face-centered cubic crystal is ( ) A.(112} B.{110} C.111", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查面心立方晶体孪晶面的基本概念记忆，属于对晶体学基础知识的直接回忆，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念记忆，仅需直接回忆面心立方晶体的孪晶面是{111}即可作答，无需理解或辨析其他选项。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 3546, + "question": "What are the differences between tin-based and lead-based Babbitt alloys?", + "answer": "Tin-based bearing alloy: It has a small coefficient of expansion, good embeddability and friction reduction, excellent toughness, thermal conductivity, and corrosion resistance, making it suitable for high-speed bearings. Lead-based bearing alloy: Its strength, hardness, wear resistance, and toughness are lower than those of tin-based alloys, but it is inexpensive and commonly used in small and low-speed ordinary machinery.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述锡基和铅基巴氏合金的区别，答案提供了详细的文字解释和对比，符合简答题的特征。 | 知识层次: 题目考查对锡基和铅基巴氏合金的基本特性和应用的理解和记忆，属于基础概念的记忆和分类。 | 难度: 在选择题型中，该题目要求考生能够理解和区分两种Babbitt合金的基本特性和应用场景。虽然涉及多个概念（如膨胀系数、嵌入性、摩擦减少等），但主要是对定义和分类的记忆性知识的考察，不需要复杂的分析或推理。因此，属于中等难度。" + }, + { + "idx": 3547, + "question": "What are the characteristics of the microstructure, properties, and applications of typical α+β titanium alloys?", + "answer": "Microstructure: α+β (annealed microstructure); Property characteristics: high strength, good plasticity, stable microstructure at 400°C, high creep strength, good plasticity and resistance to seawater and thermal stress corrosion at low temperatures; Applications: parts working below 400°C, manufacturing of aircraft engine blades, rocket engines", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对典型α+β钛合金的微观结构、性能和应用进行详细的文字解释和论述，答案提供了详细的描述，符合简答题的特征。 | 知识层次: 题目要求对α+β钛合金的微观结构、性能特点和应用进行综合描述，涉及多个知识点的关联和综合分析，需要理解材料特性与其应用之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解α+β钛合金的微观结构、性能特点和应用场景，并进行综合分析。题目要求考生掌握多个概念，并能将这些概念关联起来，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3548, + "question": "Why is Babbitt alloy wear-resistant?", + "answer": "Because the structural characteristic of tin-based bearing alloy is the distribution of hard particles on a soft matrix. If the structure of the bearing alloy consists of hard particles distributed on a soft matrix, during operation, the soft matrix will wear and become recessed, causing the hard particles to protrude from the matrix. This reduces the contact area between the shaft and the bearing bush, while the recesses can store lubricating oil, lowering the friction coefficient between the shaft and the bearing bush and reducing wear. Additionally, the soft matrix can withstand impact and vibration, allowing the shaft and bearing bush to fit well together and also embed small foreign hard particles, ensuring the shaft journal is not scratched, thus providing excellent wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Babbitt合金耐磨的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解Babbitt合金的基本结构特征，还需要分析其在实际工作条件下的磨损机制、润滑原理以及对外界冲击和振动的响应。这涉及到多个概念的关联和综合运用，以及对材料性能与微观结构之间关系的深入理解。思维过程要求较高的分析能力和推理能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解巴氏合金的基本结构特征（硬颗粒分布在软基体上），还需要综合运用材料科学、摩擦学原理和机械工程知识，深入分析这种结构如何通过多个协同机制（接触面积减少、润滑油储存、冲击吸收、异物嵌入等）实现耐磨性。这种需要同时解释复杂结构特征并推导多重作用机理的题目，在选择题型中属于对知识深度和综合分析能力要求极高的类型。" + }, + { + "idx": 3549, + "question": "In a crystal, the defect formed by simultaneously creating a vacancy and an interstitial atom is called ( ). A. Schottky defect B. Frenkel defect C. Interstitial defect", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查晶体缺陷的基本概念和分类的记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆晶体缺陷的定义和分类。题目直接考察Frenkel缺陷的定义，无需复杂辨析或深度理解，属于简单概念识别级别。" + }, + { + "idx": 3550, + "question": "The difference between cast iron and carbon steel lies in the presence or absence of ( )", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（A）作为答案 | 知识层次: 题目考查对铸铁和碳钢之间基本差异的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆铸铁和碳钢的基本区别（是否存在特定元素），无需理解或分析复杂概念。" + }, + { + "idx": 3551, + "question": "In a body-centered cubic structure with lattice constant a, can a dislocation with Burgers vector $a$ [100] decompose into $\\frac{a}{2}$ [111] + $\\frac{a}{2}$ [1-1-1]? ( )", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了明确的选项（A）作为答案。 | 知识层次: 题目涉及位错分解的判断，需要理解体心立方结构中的位错性质以及Burgers矢量的分解规则。虽然不涉及复杂的计算，但需要对位错分解的条件和原理有较好的理解，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 3552, + "question": "Someone said: 'A precipitation-hardening alloy can be softened by water quenching at an appropriate temperature.' Is this statement correct? Explain.", + "answer": "A precipitation-hardening alloy cannot be softened by water quenching at an appropriate temperature. The reason is that when heated to a high temperature, it forms a single solid solution structure. Rapid cooling results in a single solid solution, which, although not very hard at this stage, will subsequently undergo precipitation hardening. Therefore, a precipitation-hardening alloy can only be softened through an aging process.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，并解释原因。答案中明确指出了陈述是错误的，并提供了详细的解释。 | 知识层次: 题目不仅需要理解沉淀硬化合金的基本概念，还需要分析水淬对其性能的影响，并解释为什么水淬不能软化合金，而是需要通过时效过程来实现。这涉及到多步概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求判断一个关于沉淀硬化合金软化过程的陈述是否正确，这需要考生对沉淀硬化合金的热处理过程有深入的理解。其次，正确选项不仅需要判断陈述的正误，还需要解释原因，涉及多步概念关联和综合分析。具体来说，考生需要理解高温下形成单一固溶体结构、快速冷却后的状态以及后续沉淀硬化的过程，这些知识点需要较高的综合分析能力。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 3553, + "question": "Please list several examples of strengthening alloys during the casting process", + "answer": "For example, the inoculation treatment of gray cast iron (adding about $4\\%$ ferrosilicon or calcium-silicon alloy to the molten iron during casting for inoculation treatment), and the modification treatment of aluminum-silicon alloys (adding a modifier $\\frac{2}{3}\\mathrm{{NaF}+}$ $\\frac13\\mathrm{NaCl}$ to the alloy melt before pouring)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举几个例子来说明在铸造过程中强化合金的方法，答案提供了具体的例子和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求列举铸造过程中强化合金的例子，并给出了具体的处理方法。这属于直接应用已有知识，不需要复杂的分析或综合。虽然涉及具体的合金和处理方法，但主要是记忆和简单应用层面的知识。 | 难度: 在选择题型中，该题目属于较高难度。题目要求列举铸造过程中强化合金的具体实例，并提供了详细的处理方法和添加剂的配比（如灰铸铁的孕育处理加入4%的硅铁或硅钙合金，铝硅合金的变质处理加入2/3 NaF + 1/3 NaCl的变质剂）。这些内容不仅需要考生掌握相关知识点，还需要对具体的工艺参数和材料配比有较深的理解和记忆。因此，在选择题型中，该题目属于应用实例详细解释的难度等级。" + }, + { + "idx": 3554, + "question": "In substitutional solid solutions, the general mode of atomic diffusion is (). \\n\\nA. Atomic exchange mechanism B. Interstitial mechanism C. Vacancy mechanism", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查的是对置换固溶体中原子扩散机制的基本概念记忆，属于基础概念的理解和记忆范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察的是对置换固溶体中原子扩散机制的基本理解。虽然需要区分三种不同的扩散机制（交换机制、间隙机制和空位机制），但题目直接给出了正确选项，且知识点相对明确，属于概念理解和简单辨析的难度级别。不需要复杂的分析或深度推理，只需掌握相关定义即可正确作答。" + }, + { + "idx": 3555, + "question": "Fick's first law describes the characteristics of steady-state diffusion, where the concentration does not vary with ( ). \\n\\nA. distance B. time C. temperature", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查Fick第一定律的基本概念，即稳态扩散中浓度不随时间变化这一关键特征的理解和记忆，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目考察的是Fick第一定律的基本定义，即稳态扩散中浓度不随时间变化。选项B是直接对应这一基本概念的正确答案，无需复杂分析或深度理解。" + }, + { + "idx": 3556, + "question": "When a critical nucleus forms, the decrease in volume free energy can only compensate for ( ) of the surface energy.", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（B）作为答案 | 知识层次: 题目考查对临界核形成时体积自由能和表面能关系的基本概念记忆，属于基础概念的理解层面，不需要复杂的计算或分析。 | 难度: 该题目属于基础概念记忆层次，考察的是对临界核形成时体积自由能与表面能量关系的理解。虽然需要理解这两个概念之间的关系，但题目仅要求选择能够补偿表面能量的部分，属于概念理解和简单辨析的范畴，不需要复杂的分析或比较。因此，在选择题型中属于中等难度。" + }, + { + "idx": 3557, + "question": "In the Kirkendall effect, the main reason for marker drift is ( ) in the diffusion couple.", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项和对应的答案选项\"C\" | 知识层次: 题目考查Kirkendall效应的基本概念和原因的记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别Kirkendall效应的基本定义和原因。题目直接考察对\"marker drift\"主要原因的记忆，不需要复杂理解或辨析，符合等级1的简单概念识别标准。" + }, + { + "idx": 3558, + "question": "In cubic crystals, the (110) and (211) planes belong to the same () zone.", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（D） | 知识层次: 题目需要理解立方晶体中晶面属于同一晶带的条件，并应用晶带轴的概念进行分析。虽然不涉及复杂计算，但需要将多个概念关联起来进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 3559, + "question": "In a binary phase diagram, the lever rule for calculating the relative amounts of two phases can only be applied in ().", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（B）作为答案 | 知识层次: 题目考查对二元相图中杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察对杠杆规则应用条件的直接记忆。虽然需要理解杠杆规则的基本原理，但题目仅要求识别正确应用场景，无需复杂分析或概念区分，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3560, + "question": "In the concentration triangle of a ternary phase diagram, alloys whose compositions lie on the () have equal contents of the two components represented by the other two vertices.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对三元相图浓度三角形中特定组成线的基本概念记忆，只需识别等含量线的基本定义即可作答，不涉及计算或复杂分析。 | 难度: 在选择题中属于简单难度，仅需直接记忆三元相图中浓度三角形的定义即可选出正确答案，无需复杂理解或分析步骤。" + }, + { + "idx": 3561, + "question": "When a pure metal undergoes allotropic transformation during cooling from high temperature to room temperature with volume expansion, the atomic coordination number of the low-temperature phase is () compared to that of the high-temperature phase.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对同素异构转变过程中原子配位数变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及同素异构转变和原子配位数的概念，但题目给出了明确的体积膨胀条件，可以直接关联到配位数变化的规律（通常体积膨胀伴随配位数降低）。这需要考生对基本概念有一定理解，但不需要复杂的分析推理过程。" + }, + { + "idx": 3562, + "question": "The packing density of a simple cubic crystal is ( ). \\n\\nA. $100\\\\%$ B.65% C.52% D.58%", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（A、B、C、D）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查简单立方晶体堆积密度的基本概念记忆，属于晶体结构的基础知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆简单立方晶体的堆积密度数值即可作答，无需进行概念辨析或复杂计算。" + }, + { + "idx": 3563, + "question": "When the deformed material is heated up again, recovery and recrystallization phenomena occur, then the significant decrease in point defect concentration happens during ().", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了多个选项（虽然只显示了选项A，但题目结构表明这是选择题） | 知识层次: 题目考查对材料科学中恢复和再结晶过程中点缺陷浓度变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆点缺陷浓度显著降低发生的阶段（恢复和再结晶现象）。无需复杂辨析或深度理解，属于直接记忆性知识。" + }, + { + "idx": 3564, + "question": "For two parallel screw dislocations, when their Burgers vectors are in the same direction, the interaction force between them is (). \\n\\nA. zero B. repulsive C. attractive", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对平行螺型位错相互作用力的基本概念记忆，属于对位错基本性质的理解和记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解平行螺型位错之间的相互作用力与Burgers向量方向的关系，并进行简单辨析。题目不涉及复杂概念的区分或深度理解，但比直接记忆的定义类题目稍难。" + }, + { + "idx": 3565, + "question": "The dislocations that can undergo cross-slip must be (). \\n\\nA. Edge dislocation B. Screw dislocation C. Mixed dislocation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查位错类型及其特性的基本概念记忆，属于对screw dislocation能够进行cross-slip这一特性的直接认知。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（位错类型），但需要学生对不同类型的位错（刃型位错、螺型位错、混合位错）有明确的理解和区分能力。特别是要理解为什么只有螺型位错能够进行交滑移，这需要一定的概念辨析能力，而非简单的记忆。因此属于等级2难度。" + }, + { + "idx": 3566, + "question": "The dislocation that cannot undergo climb motion is (). \\n\\nA. Shockley partial dislocation B. Frank partial dislocation C. Edge full dislocation", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对位错类型及其运动特性的基础概念记忆，特别是Shockley部分位错、Frank部分位错和刃型全位错的基本特性区分，属于定义和分类层面的记忆性知识。 | 难度: 在选择题型中，该题目需要考生理解不同类型位错（Shockley partial dislocation, Frank partial dislocation, Edge full dislocation）的基本特性，并能够辨析它们之间的差异。虽然题目涉及的是基础概念记忆，但需要考生对位错运动机制（如climb motion）有基本的理解才能正确选择答案。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的分析或推理（等级3）。" + }, + { + "idx": 3567, + "question": "The fundamental reason for diffusion to occur in materials is ( ). \\n\\nA. Temperature changes B. Concentration gradient exists C. Chemical potential gradient exists", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查扩散现象的基本原理，属于基础概念的记忆和理解。虽然涉及化学势梯度这一概念，但整体仍属于材料科学中最基础的知识点。 | 难度: 在选择题中属于中等偏下难度，需要理解扩散的基本原理并区分浓度梯度和化学势梯度的概念。虽然题目考查的是基础概念记忆，但需要一定的概念辨析能力，不能仅靠简单记忆回答。" + }, + { + "idx": 3569, + "question": "The relationship between the probability of annealing twin formation and the stacking fault energy of a crystal is ( ). \\n\\nA. Unrelated, only depends on annealing temperature and time\\nB. Crystals with low stacking fault energy have a higher probability of forming annealing twins\\nC. Crystals with high stacking fault energy have a higher probability of forming annealing twins", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查堆垛层错能与退火孪晶形成概率之间的关系，需要理解晶体缺陷和变形机制的基本原理，并进行概念关联和综合分析。虽然不涉及复杂计算，但需要对材料科学中的晶体结构和缺陷行为有较深入的理解。 | 难度: 在选择题中属于较高难度，需要理解晶体堆垛层错能与退火孪晶形成概率之间的关系，并进行综合分析判断。题目涉及中等应用层次的知识，要求考生能够关联多个概念（堆垛层错能、退火孪晶形成机制）并做出正确选择。虽然题目提供了明确选项，但正确解答需要对材料科学中的晶体缺陷行为有较深入的理解，属于复杂分析过程的判断。" + }, + { + "idx": 3570, + "question": "Temperature indicators are sometimes produced from a coiled metal strip that uncoils a specific amount when the temperature increases. How does this work?", + "answer": "Bimetallic materials are produced by bonding two materials having different coefficients of thermal expansion to one another, forming a laminar composite. When the temperature changes, one of the materials will expand or contract more than the other material. This difference in expansion or contraction causes the bimetallic material to change shape; if the original shape is that of a coil, then the device will coil or uncoil, depending on the direction of the temperature change.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释双金属材料的工作原理，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解双金属材料的工作原理，涉及不同热膨胀系数的材料在温度变化时的行为差异，以及这种差异如何导致形状变化。虽然不涉及复杂计算，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目涉及双金属材料的热膨胀系数差异及其形状变化机制的理解。虽然不需要多步计算，但需要将热膨胀系数差异与材料形状变化进行概念关联，并综合分析温度变化对双金属线圈的影响。这种题目要求考生具备一定的材料科学基础知识，并能将多个概念联系起来进行推理，但相比更复杂的综合分析题目，其难度适中。" + }, + { + "idx": 3571, + "question": "From what kind of material would the temperature indicator be made?", + "answer": "The temperature indicator is made from bimetallic materials, which consist of two materials with different coefficients of thermal expansion bonded together.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释温度指示器的材料类型，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对温度指示器材料的基本概念记忆，仅需回答双金属材料的定义和基本原理，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对温度指示器材料的基本定义记忆，属于最基础的概念性知识。正确选项直接给出了明确的定义和组成材料，不需要任何解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3572, + "question": "What are the important properties that the material in the temperature indicator must possess?", + "answer": "In order for the material to perform well, the two materials must have very different coefficients of thermal expansion and should have high enough modulus of elasticity so that no permanent deformation of the material occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释材料在温度指示器中必须具有的重要性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释温度指示器材料必须具备的重要性能，并需要理解热膨胀系数和弹性模量的作用。这涉及多个概念的关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握材料的热膨胀系数和弹性模量的重要性，并能够综合分析这些性质如何影响温度指示器的性能。虽然不需要多步计算，但需要对材料性质有较深的理解和关联能力。" + }, + { + "idx": 3573, + "question": "What properties should the head of a carpenter's hammer possess?", + "answer": "The striking face and claws of the hammer should be hard-the metal should not dent or deform when driving or removing nails. Yet these portions must also possess some impact resistance, particularly so that chips do not flake off the striking face and cause injuries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述木工锤头应具备的性能，答案提供了详细的文字描述和解释，符合简答题的特征。 | 知识层次: 题目要求分析锤头应具备的性能，涉及硬度与抗冲击性的平衡，需要理解材料性能与应用场景的关联，并进行综合分析。虽然不涉及复杂计算，但需要对材料性能有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生综合理解锤头材料需要具备的硬度与抗冲击性的平衡，并分析这些性能在实际使用中的具体表现（如防止变形和碎片飞溅）。这涉及材料性能的综合应用分析，但不需要多角度或深度关联性论述。" + }, + { + "idx": 3574, + "question": "How would you manufacture a hammer head?", + "answer": "The head for a carpenter's hammer is produced by forging, a metalworking process; a simple steel shape is heated and formed in several steps while hot into the required shape. The head is then heat treated to produce the required mechanical and physical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何制造锤头，答案提供了详细的文字解释和论述，涉及制造过程和热处理步骤，符合简答题的特征。 | 知识层次: 题目要求解释制造锤头的具体工艺过程（锻造和热处理），涉及多个步骤和工艺原理的综合应用，需要理解金属加工和热处理的基本概念，并将其关联到实际制造过程中。虽然不涉及复杂计算，但需要对工艺步骤和目的有清晰的理解和解释。 | 难度: 在选择题中属于中等难度，题目要求理解锻造工艺的基本概念和步骤，并能够将加热、成型和热处理等多个步骤关联起来。虽然不需要进行多角度分析或深度关联性分析，但需要对金属加工工艺有一定的综合理解。" + }, + { + "idx": 3575, + "question": "Aluminum foil used for storing food weighs about 0.3g per square inch. How many atoms of aluminum are contained in one square inch of foil?", + "answer": "6.69 × 10^{21} atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及单位转换和摩尔计算，最终给出具体的数值答案。 | 知识层次: 题目需要进行基本的单位转换和摩尔计算，涉及简单的公式应用和数值计算，属于直接套用基本概念和公式的范畴。 | 难度: 在选择题中属于简单应用难度，需要应用摩尔质量和阿伏伽德罗常数的基本公式进行计算，但步骤较为直接，仅涉及单位转换和简单乘法运算。" + }, + { + "idx": 3576, + "question": "Using the densities and atomic weights, calculate the number of atoms per cubic centimeter in lead.", + "answer": "3.3 × 10^22 atoms/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过密度和原子量计算铅中每立方厘米的原子数，需要数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目要求使用给定的密度和原子量进行简单的数值计算，属于基本公式的直接应用，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于简单应用层次，需要学生掌握密度的基本概念和原子量的计算，并能够直接套用公式进行计算。虽然涉及多个步骤（如密度转换为质量，再转换为原子数），但每一步都是直接的公式应用，没有复杂的推理或分析过程。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3577, + "question": "Using the densities and atomic weights, calculate the number of atoms per cubic centimeter in lithium.", + "answer": "4.63 × 10^22 atoms/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过密度和原子量计算锂的每立方厘米原子数，需要数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要应用密度和原子质量的基本公式进行计算，属于直接套用公式的简单计算过程，不涉及多步计算或复杂概念关联。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要运用密度和原子质量的基本公式进行计算，但解题步骤较为直接，仅需套用公式并进行单位转换即可得出结果。相比单一公式直接计算的等级1题目，本题需要稍多的理解和应用能力，但不需要多个公式组合或复杂分析，因此属于等级2难度。" + }, + { + "idx": 3578, + "question": "Using data, calculate the number of iron atoms in one ton (2000 pounds).", + "answer": "9.79 × 10^{27} atoms/ton", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铁原子的数量），并给出了具体的数值答案（9.79 × 10^{27} atoms/ton），这符合计算题的特征。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及单位转换和原子数量的计算，属于直接套用基本公式的简单应用。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要将质量单位从吨转换为克，并使用阿伏伽德罗常数进行计算，但整个过程仅涉及基本公式的直接套用和单位转换，无需复杂的推理或多步骤分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3579, + "question": "Using data, calculate the volume in cubic centimeters occupied by one mole of boron.", + "answer": "4.7 cm^{3}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算硼的摩尔体积），答案是一个具体的数值（4.7 cm³），需要使用公式和数据来完成计算 | 知识层次: 题目要求进行基本的数值计算和公式应用，涉及摩尔体积的计算，属于直接套用基本公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算一摩尔硼的体积，只需应用密度公式（体积=质量/密度）并进行简单单位换算即可得出答案。由于题目提供了所有必要数据且无需复杂推导或组合多个公式，解题步骤直接明了，符合等级1的定义。" + }, + { + "idx": 3580, + "question": "In order to plate a steel part having a surface area of 200 in.^2 with a 0.002 in. thick layer of nickel, how many atoms of nickel are required?", + "answer": "5.98 x 10^23 atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及表面面积、厚度和原子数量的计算，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括计算镍的体积、质量、摩尔数，最后转换为原子数，涉及多个概念和公式的综合应用，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念并进行多步计算。题目要求计算镀镍层所需的原子数量，涉及表面面积、厚度、密度、摩尔质量和阿伏伽德罗常数等多个概念的综合应用。虽然题目提供了正确选项，但解题过程需要将单位换算、体积计算、质量转换和原子数量计算等多个步骤串联起来，属于典型的综合性计算问题。" + }, + { + "idx": 3581, + "question": "In order to plate a steel part having a surface area of 200 in.^2 with a 0.002 in. thick layer of nickel, how many moles of nickel are required?", + "answer": "0.994 mol ni required", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算镍的摩尔数），涉及公式应用（体积、密度、摩尔质量等转换），答案以具体数值形式给出 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及面积、厚度和摩尔数的转换，属于直接套用基本公式的简单计算类型。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用基本公式（如体积计算和摩尔计算），但解题步骤较为直接，仅需套用公式并进行简单单位转换即可得出答案。相比等级1的直接计算，该题需要稍多的理解和应用，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 3582, + "question": "Suppose an element has a valence of 2 and an atomic number of 27 . Based only on the quantum numbers, how many electrons must be present in the 3 d energy level?", + "answer": "7 electrons.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于量子数计算3d能级中的电子数，需要应用原子结构和电子排布的知识进行数值计算，最终给出具体的电子数量（7 electrons）。 | 知识层次: 题目需要理解原子结构和电子排布的基本原理，应用量子数来确定电子在特定能级的分布，并进行多步计算。这涉及到对原子序数、价电子和电子排布规则的综合理解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要结合原子序数、价电子数和量子数概念进行多步计算和综合分析。具体步骤包括：1) 根据原子序数27确定电子排布；2) 结合价电子数2推断可能的离子状态；3) 利用量子数分析3d能级电子数。虽然题目提供了关键信息，但需要考生具备较强的概念关联和计算能力才能正确解答。" + }, + { + "idx": 3583, + "question": "Calculate the fraction of bonding of MgO that is ionic.", + "answer": "the fraction of bonding of mgo that is ionic is 0.734. so bonding is mostly ionic.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算MgO的离子键比例），答案给出了具体的计算结果（0.734），属于典型的计算题特征。 | 知识层次: 题目涉及基本公式应用和简单计算，主要考查对离子键分数计算的理解和直接套用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行单一计算，无需多个公式组合或复杂分析。学生只需掌握简单的离子键分数计算公式即可得出答案，属于最基础的难度等级。" + }, + { + "idx": 3584, + "question": "Would you expect MgO or magnesium to have the higher modulus of elasticity? Explain.", + "answer": "( MgO has ionic bonds, which are strong compared to the metallic bonds in Mg. A higher force will be required to cause the same separation between the ions in MgO compared to the atoms in Mg. Therefore, MgO should have the higher modulus of elasticity. In Mg, E=6 × 10^{6} psi; in MgO, E=30 × 10^{6} psi.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么MgO的弹性模量比镁高，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求学生理解并比较MgO和Mg的键合类型（离子键与金属键），并解释其对弹性模量的影响。这需要学生将键合类型与材料性能关联起来，进行综合分析，而不仅仅是记忆基本概念或进行简单应用。虽然不涉及多步计算，但需要对概念进行关联和解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生比较MgO和Mg的弹性模量，并解释原因。这涉及到对离子键和金属键强度的理解，以及对弹性模量概念的掌握。虽然题目提供了具体数值，但考生仍需进行概念关联和综合分析才能得出正确结论。" + }, + { + "idx": 3585, + "question": "Calculate the atomic radius in cm for a BCC metal with a0=0.3294 nm and one atom per lattice point.", + "answer": "1.426 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算原子半径），并给出了具体的公式应用（BCC金属的原子半径与晶格参数的关系）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求应用BCC晶体结构的几何关系公式进行简单计算，只需一步转换单位（nm到cm）和直接套用原子半径公式（r=√3a0/4），属于基本公式的直接应用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用BCC金属的原子半径计算公式（r = √3 * a0 / 4），并进行简单的单位换算（nm转cm）。解题步骤单一且无需复杂分析，属于最基础的公式应用层级，因此评定为等级1。" + }, + { + "idx": 3586, + "question": "Calculate the atomic radius in cm for an FCC metal with a0=4.0862 A and one atom per lattice point.", + "answer": "1.4447 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算原子半径），并给出了具体的公式应用（FCC结构中的原子半径与晶格参数的关系），最终答案是一个具体的数值结果。 | 知识层次: 题目要求应用FCC晶体结构的几何关系公式进行单步计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了FCC金属的晶格常数a0=4.0862 Å，并要求计算原子半径。解题仅需应用FCC结构中原子半径与晶格常数的关系公式（r = a0√2 / 4），并进行简单的单位换算（Å到cm）。无需额外的概念理解或复杂步骤，属于最基础的直接套用公式类型。" + }, + { + "idx": 3587, + "question": "Determine the crystal structure for a metal with a0=4.9489 Å, r=1.75 Å and one atom per lattice point.", + "answer": "fcc", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定金属的晶体结构，需要根据给定的晶格常数和原子半径进行计算和判断，最终给出晶体结构的类型（如fcc）。虽然答案是一个简短的单词，但解答过程需要理解和应用晶体结构的知识，属于简答题的范畴。 | 知识层次: 题目要求根据给定的晶格常数和原子半径确定晶体结构，这需要应用基本的晶体结构计算公式和概念（如原子堆积因子），属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，仅需应用基本晶体结构公式（如fcc的原子半径与晶格常数关系r=a0√2/4）进行简单计算验证，无需复杂推理或多步骤分析。题目直接给出所有必要参数，属于\"直接套用公式\"的简单应用层次。" + }, + { + "idx": 3588, + "question": "Determine the crystal structure for a metal with a0=0.42906 nm, r=0.1858 nm and one atom per lattice point.", + "answer": "bcc", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算和解释确定晶体的结构类型，答案需要基于给定的参数（a0和r）进行推导，并给出具体的晶体结构类型（如bcc），这属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据给定的晶格常数和原子半径确定晶体结构，这需要应用基本的晶体几何关系公式进行计算和判断。虽然涉及一定的计算步骤，但属于直接套用公式和基本概念的应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需套用基本公式（如原子半径与晶格常数的关系）进行简单计算即可确定晶体结构类型。解题步骤直接且无需复杂分析，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 3589, + "question": "The density of potassium, which has the BCC structure and one atom per lattice point, is 0.855 g/cm3. The atomic weight of potassium is 39.09 g/mol. Calculate the lattice parameter.", + "answer": "5.3355 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶格参数，答案是一个具体的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及BCC结构的密度计算公式和单位转换，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求计算BCC结构的晶格参数，主要涉及密度公式的直接应用和单位换算。虽然需要理解BCC结构的基本概念和密度公式，但解题步骤相对直接，只需套用公式并进行简单计算即可得出答案。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3590, + "question": "The density of potassium, which has the BCC structure and one atom per lattice point, is 0.855 g/cm3. The atomic weight of potassium is 39.09 g/mol. Calculate the atomic radius of potassium.", + "answer": "2.3103 x 10^-8 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钾的原子半径，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换、BCC结构原子半径的计算等，涉及多个概念的关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的思维深度和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、密度与原子半径的关系，并进行多步计算。虽然题目给出了正确选项，但解题过程涉及单位换算、晶格常数计算和几何关系推导，属于综合性计算问题。" + }, + { + "idx": 3591, + "question": "The density of thorium, which has the FCC structure and one atom per lattice point, is 11.72 g/cm³. The atomic weight of thorium is 232 g/mol. Calculate the lattice parameter.", + "answer": "5.0856 x 10⁻⁸ cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如密度公式和FCC结构参数关系）来求解晶格参数，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的密度计算公式和FCC结构的几何关系，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。解题步骤包括使用密度公式（ρ = n*A / (V*N_A)）和FCC结构的体积公式（V = a³），然后进行简单的代数运算求解晶格参数a。虽然需要理解FCC结构和相关公式，但计算过程直接且无需复杂推理，因此属于等级2难度。" + }, + { + "idx": 3593, + "question": "A metal having a cubic structure has a density of 2.6g / {cm}^{3}, an atomic weight of 87.62g / mol, and a lattice parameter of 6.0849 Å. One atom is associated with each lattice point. Determine the crystal structure of the metal.", + "answer": "fcc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算和分析确定金属的晶体结构，答案需要基于给定的密度、原子量和晶格参数进行计算，并最终得出晶体结构的结论（如fcc）。虽然答案是一个简短的术语，但解答过程涉及多个步骤和计算，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要应用密度计算公式，结合原子量和晶格参数进行多步计算，综合分析得出晶体结构类型。涉及概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握晶体结构、密度、原子量和晶格参数之间的关系，并能进行多步计算来确定晶体结构。虽然题目提供了所有必要的信息，但需要考生综合运用这些信息进行计算和推理，才能得出正确的结论。" + }, + { + "idx": 3594, + "question": "A metal having a cubic structure has a density of 1.892g / {cm}^{3}, an atomic weight \\mathrm{of} 132.91g / mol, and a lattice parameter of € 1.13 Å. One atom is associated with each lattice point. Determine the crystal structure of the \\mathrm{metal}.", + "answer": "bcc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算和分析确定金属的晶体结构，需要文字解释和论述，而不仅仅是选择或判断。虽然答案简短（bcc），但解答过程涉及密度、原子量和晶格参数的计算和推理。 | 知识层次: 题目需要应用密度、原子质量和晶格参数的知识，通过多步计算来确定晶体的结构。这涉及到对立方晶体结构的理解以及相关公式的应用，属于中等难度的应用题目。 | 难度: 在选择题型中，这道题目属于较高难度。首先，题目要求考生掌握晶体结构、密度计算、原子量和晶格参数等多个概念。其次，解题过程涉及多步计算，包括计算单位晶胞中的原子数、验证计算结果与不同晶体结构（如bcc、fcc等）的匹配性。此外，题目还要求考生能够综合分析计算结果与晶体结构之间的关系，而不仅仅是简单的记忆或单一概念的应用。因此，这道题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 3595, + "question": "Indium has a tetragonal structure with a_{0}=0.32517nm and c_{0}=0.49459nm. The density is 7.286g / {cm}^{3} and the atomic weight is 114.82g / mol. Does indium have the simple tetragonal or body-centered tetragonal structure?", + "answer": "body-centered tetragonal structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两种晶体结构（simple tetragonal或body-centered tetragonal）中选择正确的答案，属于二选一的选择题。 | 知识层次: 题目需要应用晶体结构的基本知识，进行多步计算（如计算单位晶胞中的原子数），并结合密度和原子量等参数进行综合分析，以确定铟的晶体结构类型。这涉及到多个概念的关联和一定的计算过程，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。解题需要以下多步计算和概念关联：" + }, + { + "idx": 3596, + "question": "Bismuth has a hexagonal structure, with a0=0.4546 nm and c0=1.186 nm. The density is 9.808 g/cm3 and the atomic weight is 208.98 g/mol. Determine the volume of the unit cell.", + "answer": "0.21226 nm3 or 2.1226 x 10^-22 cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞的体积，答案是一个具体的数值结果，解答过程需要运用密度、原子量和晶格参数等数据进行计算。 | 知识层次: 题目要求应用基本的晶体学公式计算单位晶胞体积，涉及简单的数值计算和单位转换，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算单位晶胞的体积，只需要应用六方晶系的体积公式V = (3√3/2) * a0² * c0，代入给定的a0和c0值即可得到结果。不需要额外的概念理解或多步骤计算，属于最基础的计算题类型。" + }, + { + "idx": 3598, + "question": "Gallium has an orthorhombic structure, with a0=0.45258 nm, b0=0.45186 nm, and c0=0.76570 nm. The atomic radius is 0.1218 nm. The density is 5.904 g/cm3 and the atomic weight is 69.72 g/mol. Determine the number of atoms in each unit cell.", + "answer": "8 atoms/cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶体结构参数、原子半径、密度和原子量等数据，应用相关公式计算每个晶胞中的原子数。解答过程需要进行数值计算和公式推导，最终得出具体的数值结果（8 atoms/cell）。 | 知识层次: 题目需要多步计算和概念关联，包括晶体结构参数、原子半径、密度和原子量的综合分析，以确定每个晶胞中的原子数。这涉及到对晶体学基础知识的理解以及相关公式的应用，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、密度计算和单位晶胞的概念。解题步骤包括计算单位晶胞体积、利用密度和原子质量计算单位晶胞中的原子数，并理解正交晶系的结构特点。虽然题目给出了所有必要参数，但需要正确关联这些参数并进行多步计算才能得出答案。" + }, + { + "idx": 3599, + "question": "Gallium has an orthorhombic structure, with a0=0.45258 nm, b0=0.45186 nm, and c0=0.76570 nm. The atomic radius is 0.1218 nm. The density is 5.904 g/cm3 and the atomic weight is 69.72 g/mol. Determine the packing factor in the unit cell.", + "answer": "0.387.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如计算晶胞的堆积因子）来得出具体数值答案（0.387），属于典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括晶胞体积、原子体积和堆积因子的计算，涉及多个参数的关联和综合分析，需要理解和应用晶体结构的基本原理和公式。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、原子半径、密度和原子重量等多个概念，并进行多步计算（包括晶胞体积、原子体积、原子数等）才能得出正确的堆积因子。虽然题目提供了所有必要数据，但解题步骤较为复杂，需要综合分析和准确计算。" + }, + { + "idx": 3600, + "question": "Beryllium has a hexagonal crystal structure, with a0=0.22858 nm and c0=0.35842 nm. The atomic radius is 0.1143 nm, the density is 1.848 g/cm3, and the atomic weight is 9.01 g/mol. Determine the number of atoms in each unit cell.", + "answer": "2 atoms/cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定每个晶胞中的原子数，答案是一个具体的数值结果（2 atoms/cell），这符合计算题的特征。 | 知识层次: 题目需要应用基本的晶体结构参数（晶格常数、原子半径）和密度公式进行计算，属于直接套用公式和简单计算的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要考生掌握基本的晶体结构参数和密度计算公式，并进行简单的数值代入和计算。虽然涉及多个参数（a0, c0, 原子半径, 密度, 原子量），但解题步骤较为直接，主要是套用六方晶系的原子数计算公式，不需要复杂的推导或分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3601, + "question": "Beryllium has a hexagonal crystal structure, with a0=0.22858 nm and c0=0.35842 nm. The atomic radius is 0.1143 nm, the density is 1.848 g/cm3, and the atomic weight is 9.01 g/mol. Determine the packing factor in the unit cell.", + "answer": "0.77", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如晶体结构参数、原子半径、密度等）来确定单位晶胞的堆积因子，最终答案为数值结果0.77，符合计算题的特征。 | 知识层次: 题目需要应用晶体结构、原子半径、密度和原子重量等多方面的知识，进行多步计算和综合分析，以确定单位晶胞的堆积因子。这涉及到对公式的理解和应用，以及数据的合理转换和计算，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、原子半径、密度和原子重量等多个概念，并进行多步计算（包括晶胞体积计算、原子体积计算和堆积因子计算）。虽然题目提供了所有必要参数，但解题过程需要较强的综合分析能力和计算准确性，属于典型的综合性计算问题。" + }, + { + "idx": 3602, + "question": "A typical paper clip weighs 0.59g and consists of BCC iron. Calculate the number of unit cells in the paper clip.", + "answer": "3.185 × 10^21 cells", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算纸夹中的晶胞数量），需要使用公式和给定的物理量（质量和晶体结构），最终给出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括质量到摩尔数的转换、BCC结构中原子的计算以及单位晶胞数量的确定，涉及多个概念的综合应用和关联。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念并进行多步计算。具体包括：1) 理解BCC铁的单位细胞结构；2) 计算单位细胞的质量；3) 将纸夹总质量转换为单位细胞数量。虽然题目给出了正确选项，但解题过程涉及单位换算、晶体结构知识和数学运算，比简单记忆或单一概念的选择题更复杂。" + }, + { + "idx": 3603, + "question": "A typical paper clip weighs 0.59g and consists of BCC iron. Calculate the number of iron atoms in the paper clip.", + "answer": "6.37 × 10^21 atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铁原子数量），需要应用公式（通过质量和晶体结构计算原子数），答案是一个具体的数值结果。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及摩尔质量和阿伏伽德罗常数的直接套用，属于简单应用层次。虽然需要理解BCC结构的概念，但计算过程相对直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要运用BCC铁的单位晶胞原子数和摩尔质量等基本概念，但解题步骤较为直接，只需套用摩尔质量和阿伏伽德罗常数进行简单计算即可得出答案。相比单一公式直接计算的题目，该题需要稍多的知识应用，但不需要多个公式组合或复杂分析，因此在选择题型中属于等级2难度。" + }, + { + "idx": 3604, + "question": "Determine the planar density for BCC lithium in the (100) plane.", + "answer": "planar density = 0.0812 x 10^16 points/cm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(100)晶面的面密度，需要应用公式进行数值计算，答案以数值形式给出。 | 知识层次: 题目需要计算BCC锂在(100)面的平面密度，涉及晶体结构知识、原子位置确定、面积计算等多步操作，需要将晶体学概念与数学计算相结合，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、(100)晶面特征、平面密度计算公式等多个概念，并进行多步计算（包括晶格常数推导、原子位置确定、有效原子数计算等）。虽然题目提供了正确选项减少了部分计算量，但仍需要较强的综合分析能力才能正确解题。" + }, + { + "idx": 3605, + "question": "Determine the packing fraction for BCC lithium in the (100) plane.", + "answer": "packing fraction = 0.589", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算BCC锂在(100)面的堆积分数，需要应用晶体结构相关的公式进行数值计算，最终给出一个具体的数值结果（0.589）。 | 知识层次: 题目要求计算BCC锂在(100)面的堆积分数，这需要应用基本的晶体学公式和几何关系，属于直接套用公式和简单计算的范畴。虽然需要理解BCC结构和堆积分数的概念，但计算过程相对直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解BCC结构在(100)平面的原子排列方式，但主要涉及基本公式的直接套用（计算平面原子密度与晶格参数的关系），解题步骤相对简单，属于选择题型中中等偏下的难度水平。" + }, + { + "idx": 3606, + "question": "Determine the planar density for BCC lithium in the (110) plane.", + "answer": "planar density = 0.1149 x 10^16 points/cm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(110)晶面上的平面密度，需要通过数值计算和公式应用来得出具体数值结果。答案以数值形式给出，符合计算题的特征。 | 知识层次: 题目需要理解BCC晶体结构、(110)平面的原子排列，并应用平面密度计算公式进行多步计算，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、(110)晶面原子排列、平面密度计算公式等多个概念，并进行多步骤计算（包括晶格常数推导、有效原子数计算、面积计算等综合步骤）。虽然题目提供了正确选项减少了推导负担，但仍需较强的空间想象能力和计算准确性，属于需要综合分析的应用题。" + }, + { + "idx": 3607, + "question": "Determine the packing fraction for BCC lithium in the (110) plane.", + "answer": "packing fraction = 0.833", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(110)平面的堆积分数，需要应用晶体结构和几何关系的公式进行数值计算，最终给出一个具体的数值结果（0.833）。 | 知识层次: 题目需要计算BCC结构在特定晶面(110)的堆积分数，涉及晶体几何关系的理解和多步计算（包括原子半径与晶格常数的关系、晶面原子密度的计算等），属于需要概念关联和综合分析的中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、(110)平面的原子排列，并进行多步几何计算来求解堆积分数。虽然题目给出了正确选项，但解题过程涉及晶体学概念的综合应用和计算步骤的衔接，属于需要综合分析能力的题目。" + }, + { + "idx": 3608, + "question": "Determine the planar density for BCC lithium in the (111) plane.", + "answer": "planar density = 0.0469 x 10^16 points/cm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(111)晶面的平面密度，需要应用晶体学公式进行数值计算，最终给出具体的数值结果。 | 知识层次: 题目需要理解BCC晶体的结构特点，掌握(111)平面的原子排列方式，并应用平面密度的计算公式进行多步计算。这涉及到晶体学知识的综合应用和数值计算能力，属于中等难度的应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、(111)晶面的原子排列、平面密度的计算公式，并正确进行多步单位换算和数学运算。虽然题目提供了正确选项减少了干扰项判断，但计算过程涉及原子半径推导、晶面原子数计算、面积计算等综合步骤，且需要处理10^16数量级的科学计数法转换，对概念理解和计算准确性要求较高。" + }, + { + "idx": 3609, + "question": "Determine the packing fraction for BCC lithium in the (111) plane.", + "answer": "packing fraction = 1/2 / 0.866 a0^2 sqrt(3) a0 / 4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(111)面的堆积分数，答案涉及数值计算和公式应用，属于典型的计算题。 | 知识层次: 题目需要计算BCC锂在(111)面的堆积分数，涉及晶体结构、晶面指数、堆积分数计算等多步过程，需要理解BCC结构特点、晶面间距计算以及堆积分数的定义和计算方法，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、(111)晶面几何关系、原子堆积分数计算等多个概念，并进行多步骤的综合计算。题目要求将空间几何关系转化为二维平面计算，涉及原子半径与晶格常数的转换、平面内原子分布分析等复杂步骤，但作为选择题可以通过选项提示减少部分计算量。" + }, + { + "idx": 3610, + "question": "Which, if any, of these planes is close packed in BCC lithium?", + "answer": "there is no close-packed plane in bcc structures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目实际上是在判断\"BCC锂中是否存在密排面\"这一陈述的正确性，答案为明确的判断性陈述（不存在）。虽然以疑问句形式呈现，但本质是判断一个事实陈述的真伪。 | 知识层次: 题目考查对BCC晶体结构中密排面存在与否的基础概念记忆和理解，属于晶体学的基本知识点，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念记忆层次，仅需判断BCC结构中是否存在密排面这一基本事实。选择题型中只需识别正确选项，无需复杂推理或概念整合，属于最基础的正误判断难度等级。" + }, + { + "idx": 3611, + "question": "Suppose that FCC rhodium is produced as a 1-mm thick sheet, with the (111) plane parallel to the surface of the sheet. How many (111) interplanar spacings d_{111} thick is the sheet? See Appendix A for necessary data.", + "answer": "the sheet is 4.563 × 10^{6} d_{111} spacings thick.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定1毫米厚的FCC铑片中(111)晶面间距的数量。答案给出了具体的计算结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括查找附录数据、应用晶面间距公式、单位换算等，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、(111)晶面间距计算、单位换算等多个概念，并进行多步骤的综合计算。题目要求将1毫米厚度转换为(111)晶面间距的数量级，涉及查表数据、公式应用和单位转换，但选项已经给出计算结果，降低了部分难度。" + }, + { + "idx": 3612, + "question": "In a FCC unit cell, how many d_{111} are present between the 0,0,0 point and the 1,1,1 point?", + "answer": "3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算FCC晶胞中特定晶面间距的数量，需要应用晶体学知识和数值计算，答案是一个具体的数值（3），符合计算题的特征。 | 知识层次: 题目需要理解FCC晶胞的结构，并应用几何知识计算特定晶面间距的数量。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶胞结构、晶面间距概念，并进行多步计算和空间想象。虽然正确选项明确，但解题过程涉及晶面间距的推导和计数，需要综合分析能力。" + }, + { + "idx": 3613, + "question": "Determine the minimum radius of an atom that will just fit into the tetrahedral interstitial site in FCC nickel.", + "answer": "0.2797 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定原子的最小半径，需要应用相关公式和计算步骤，最终给出一个具体的数值答案（0.2797 Å）。 | 知识层次: 题目需要进行多步计算，涉及FCC晶体结构中四面体间隙的几何关系与原子半径的计算，需要理解晶体结构的基本原理并应用相关公式进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、间隙位置几何关系、原子半径计算等多个概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及复杂的几何关系和计算步骤，需要较强的空间想象能力和计算能力。" + }, + { + "idx": 3614, + "question": "Determine the minimum radius of an atom that will just fit into the octahedral interstitial site in BCC lithium.", + "answer": "0.629 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定原子半径的最小值，需要使用公式和已知参数进行计算，最终给出一个具体的数值答案（0.629 Å）。 | 知识层次: 题目需要多步计算和概念关联。首先需要理解BCC晶体结构中八面体间隙的位置和几何特征，然后应用几何关系计算间隙半径，最后结合锂的晶格常数进行计算。这涉及晶体结构知识和几何计算能力的综合应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、八面体间隙位置的计算方法，并正确应用原子半径与间隙半径的关系公式。解题涉及多步计算和概念关联，但选项已给出正确答案，减少了部分复杂性。" + }, + { + "idx": 3615, + "question": "What is the radius of an atom that will just fit into the octahedral site in FCC copper without disturbing the crystal structure?", + "answer": "0.529 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算一个原子半径的具体数值（0.529 Å），这需要通过应用晶体结构和几何关系的公式来完成。解答过程涉及数值计算和理论应用，符合计算题的特征。 | 知识层次: 题目需要应用晶体结构中的间隙位置计算知识，涉及FCC铜的晶格常数和八面体间隙半径的计算公式，需要进行多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、八面体间隙的概念，并应用原子半径与晶格参数的关系进行多步计算。虽然题目给出了正确选项，但解题过程涉及多个知识点的综合应用和计算步骤，比单纯的概念选择题更复杂。" + }, + { + "idx": 3616, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{Y}_{2} \\mathrm{O}_{3}.", + "answer": "6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要一定的解释和论述，而不仅仅是简单的计算或选择。答案虽然是一个数字，但解答过程需要理解和应用离子半径与配位数的关系。 | 知识层次: 题目要求根据离子半径确定配位数，这需要理解离子半径与配位数之间的关系，并能够应用相关规则进行计算和判断。虽然涉及基本概念，但需要综合分析离子半径数据并应用配位数规则，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解离子半径与配位数的关系，并进行多步计算和综合分析。虽然题目给出了具体化合物Y2O3，但解答过程需要结合离子半径数据、配位数规则以及晶体结构知识，属于中等应用层次的要求。" + }, + { + "idx": 3617, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{UO}_{2}.", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用离子半径数据和配位数计算规则进行数值判断，答案是一个具体的数字（6），属于计算题的特征。 | 知识层次: 题目要求根据离子半径确定配位数，这属于基本公式应用和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅要求直接应用已知的离子半径数据来确定配位数，无需复杂计算或多步骤推理。学生只需记住或查阅相关离子半径数据，并应用基本的配位数判断规则即可得出正确答案。这种类型的题目主要考察学生对基础知识的记忆和简单应用能力，属于单一公式直接计算的范畴。" + }, + { + "idx": 3618, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{BaO}.", + "answer": "8", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要一定的解释和论述，而不仅仅是简单的选择或计算。答案虽然是一个数字，但解答过程需要理解和应用离子半径与配位数的关系。 | 知识层次: 题目要求根据离子半径确定配位数，这属于基本公式应用和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需根据已知的离子半径直接套用协调数的基本规则即可得出答案。解题步骤简单直接，不需要复杂的计算或深入的概念理解，因此在选择题型内属于较低难度。" + }, + { + "idx": 3619, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{Si}_{4} N_{4}.", + "answer": "4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用相关公式和数值计算，答案是一个具体的数值（4），符合计算题的特征。 | 知识层次: 题目要求使用离子半径数据来确定配位数，这涉及基本的公式应用和简单计算，属于直接套用已知原理和数据的范畴，不需要多步计算或复杂分析。 | 难度: 在选择题中属于简单难度，需要应用离子半径与配位数关系的基本公式进行计算，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 3620, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{GeO}_{2}.", + "answer": "4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要解释和论述判断过程，答案是一个具体的数值而非选择或判断对错 | 知识层次: 题目要求根据离子半径确定配位数，这需要应用基本的离子半径数据和配位数规则进行计算和判断。虽然需要一定的理解和应用能力，但思维过程相对直接，不涉及复杂的综合分析或推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需要根据已知的离子半径直接套用基本公式或规则来确定配位数。解题步骤简单直接，无需复杂的分析或计算，且知识点掌握深度要求较低，属于基础知识的直接应用。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 3621, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{MnO}.", + "answer": "6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要解释和论述判断过程，答案是一个具体的数值而非选择或判断 | 知识层次: 题目要求根据离子半径确定配位数，这需要理解离子半径与配位数之间的关系，并能够应用相关规则（如半径比规则）进行计算和判断。虽然涉及基本概念，但需要一定的综合分析能力来关联不同知识点并得出正确结论。 | 难度: 在选择题中属于中等难度，需要理解离子半径与配位数的关系，并进行多步计算和综合分析。虽然题目给出了具体化合物MnO，但解答过程需要结合离子半径数据判断配位数，涉及中等应用层次的知识点掌握和解题步骤。" + }, + { + "idx": 3622, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{MgS}.", + "answer": "6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用材料科学知识进行判断，答案是一个具体的数值而非选择或判断对错，属于需要简要解释和论述的简答题类型 | 知识层次: 题目要求根据离子半径确定配位数，这属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需要根据已知的离子半径直接套用协调数判断规则即可得出答案。解题步骤简单，无需复杂计算或深入分析，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 3623, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{KBr}.", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用离子半径数据来确定配位数，需要通过计算和比较离子半径比来得出结果，答案是一个具体的数值(6)，属于计算题的特征 | 知识层次: 题目要求使用离子半径数据来确定配位数，这涉及基本的公式应用和简单计算，属于直接套用已知规则和数据的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求使用离子半径来确定KBr的配位数，这只需要直接应用离子半径与配位数之间的基本关系，无需复杂的计算或多步骤推理。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3624, + "question": "Would you expect NiO to have the cesium chloride, sodium chloride, or zinc blende structure?", + "answer": "sodium chloride structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的三种晶体结构（cesium chloride, sodium chloride, zinc blende）中选择NiO最可能具有的结构，属于从多个选项中选择正确答案的选择题类型。 | 知识层次: 题目考查对NiO晶体结构的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度。题目仅要求考生回忆NiO的晶体结构类型，无需进行复杂的辨析或理解多个概念。正确选项\"sodium chloride structure\"是基础材料科学中常见的记忆性知识点，属于最基础的概念记忆层次。" + }, + { + "idx": 3625, + "question": "For NiO with sodium chloride structure, determine the lattice parameter.", + "answer": "4.02 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定NiO的晶格参数，答案是一个具体的数值（4.02 Å），这表明需要进行数值计算和公式应用来解决问题。 | 知识层次: 题目要求根据NiO的氯化钠结构确定晶格参数，这属于基本公式应用和简单计算，不需要多步计算或综合分析，仅需直接套用已知的晶格参数值即可。 | 难度: 在选择题型中，该题目仅需直接应用已知的晶格参数值（4.02 Å），无需任何计算或公式推导。属于单一知识点直接回忆的简单题目，符合等级1的难度标准。" + }, + { + "idx": 3626, + "question": "For NiO with sodium chloride structure, determine the density.", + "answer": "7.64 \\mathrm{g/cm}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定NiO的密度，需要应用材料科学中的密度计算公式和晶体结构知识，答案是一个具体的数值结果。 | 知识层次: 题目需要应用密度计算公式，并理解NiO的氯化钠结构以确定晶格参数和分子数。这涉及多步计算和概念关联，但不需要复杂的推理或深度分析。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构知识（NaCl型结构）、化学计量计算、密度公式应用等多个步骤。虽然题目给出了正确选项减少了猜测成分，但解题过程需要计算晶胞参数、分子量换算、单位体积原子数等，涉及多个概念关联和单位转换，属于典型的综合性计算问题。" + }, + { + "idx": 3627, + "question": "For NiO with sodium chloride structure, determine the packing factor.", + "answer": "0.678.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定NiO的packing factor，答案是一个具体的数值结果（0.678），这表明解答过程涉及计算步骤。 | 知识层次: 题目要求计算NiO的堆积因子，这需要应用基本的晶体结构知识（如NaCl结构）和堆积因子的计算公式。虽然需要理解相关概念，但计算过程相对直接，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算NiO的堆积因子，只需直接应用已知的NaCl结构堆积因子公式（0.678）即可得出答案，无需额外推导或组合多个公式。解题步骤简单，仅需基本概念记忆和简单数值匹配。" + }, + { + "idx": 3628, + "question": "Would you expect \\mathrm{UO}_{2} to have the sodium chloride, zinc blende, or fluoride structure?", + "answer": "fluorite structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个结构选项（sodium chloride, zinc blende, fluoride）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对常见晶体结构类型及其对应化合物的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（UO2的晶体结构），但需要学生对三种常见晶体结构（NaCl、闪锌矿、萤石）有一定的理解和辨析能力。学生需要知道UO2通常采用萤石结构这一知识点，而不是简单地记忆定义。这比纯粹的概念识别（等级1）要求更高，但不需要复杂的分析或深度理解（等级3）。" + }, + { + "idx": 3629, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the lattice parameter.", + "answer": "5.2885 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定UO2的晶格参数，需要通过计算或查阅相关数据得出具体数值（5.2885 Å），属于需要数值结果的计算题。 | 知识层次: 题目要求确定UO2的晶格参数，这属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求确定具有萤石结构的UO₂的晶格参数，正确选项直接给出数值5.2885 Å。解题过程仅需应用基本公式或直接引用已知数据，无需复杂计算或多步骤推理。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3630, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the density.", + "answer": "12.13 {g/cm}^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定密度，需要应用公式和数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用密度计算公式，涉及晶体结构（萤石结构）的理解和单位晶胞参数的计算，属于多步计算和概念关联的综合应用。 | 难度: 在选择题中属于中等偏上难度，需要理解氟化物结构的概念，掌握晶胞参数计算，并进行多步密度计算。虽然题目提供了正确选项减少了部分计算负担，但仍需要综合运用晶体学和化学计量知识才能正确解答。" + }, + { + "idx": 3631, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the packing factor.", + "answer": "The packing factor is pf = 0.624.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算UO2的堆积因子(packing factor)，需要通过数值计算和公式应用来得出具体数值0.624的答案。 | 知识层次: 题目要求计算UO2的堆积因子，这需要应用基本的几何公式和晶体结构知识，属于直接套用公式的简单计算题。虽然需要理解氟化钙结构的基本特征，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式进行简单计算，属于单一公式直接计算的难度等级。学生只需知道氟化钙结构的堆积因子公式并代入数值即可得出答案，无需复杂的推理或多步骤计算。" + }, + { + "idx": 3632, + "question": "Would you expect BeO to have the sodium chloride, zinc blende, or fluorite structure?", + "answer": "BeO has the zinc blende structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三种晶体结构（sodium chloride, zinc blende, fluorite）中选择BeO最可能具有的结构类型，符合选择题的特征。 | 知识层次: 题目考查对BeO晶体结构的基础概念记忆，属于对特定材料晶体结构的直接认知，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对BeO的晶体结构有明确的理解，并能将其与钠氯化物、闪锌矿和萤石结构进行区分。这要求考生不仅记住BeO的结构类型，还需要理解不同晶体结构的特点及其适用条件。因此，相较于简单的概念识别（等级1），该题目需要更深一层的概念理解和简单辨析（等级2）。" + }, + { + "idx": 3633, + "question": "Based on the zinc blende structure of BeO, determine the lattice parameter.", + "answer": "The lattice parameter is 3.8567 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于闪锌矿结构的BeO确定晶格参数，需要通过数值计算和公式应用得出具体数值（3.8567 Å），属于典型的计算题。 | 知识层次: 题目要求基于已知的锌矿结构计算晶格参数，属于基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接应用锌矿结构的晶格参数公式进行计算，属于单一公式直接计算的简单应用。题目明确给出了正确选项，无需额外分析或组合多个公式，因此难度等级为1。" + }, + { + "idx": 3634, + "question": "Based on the zinc blende structure of BeO, determine the density.", + "answer": "The density is 2.897 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于闪锌矿结构的BeO计算密度，需要应用相关公式和数值计算，最终给出具体的密度数值。 | 知识层次: 题目需要理解锌矿结构（BeO的晶体结构），应用晶体密度计算公式，并进行多步计算（包括晶格常数、原子质量、阿伏伽德罗常数等参数的关联计算）。虽然不涉及复杂的推理或创新设计，但需要综合运用多个概念和公式来完成计算。 | 难度: 在选择题中属于中等偏上难度，需要理解锌矿结构的概念，掌握晶胞参数与密度的关系，并进行多步计算。虽然题目提供了正确选项，但解题过程涉及单位晶胞中原子的数量计算、摩尔质量转换以及体积计算等综合步骤，属于需要概念关联和综合分析的题目。" + }, + { + "idx": 3635, + "question": "Based on the zinc blende structure of BeO, determine the packing factor.", + "answer": "The packing factor is 0.684.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于闪锌矿结构的BeO计算其堆积因子，需要应用相关公式进行数值计算，最终给出具体的数值结果0.684。 | 知识层次: 题目需要理解锌矿结构（BeO）的晶体结构特点，并应用几何关系计算堆积因子。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解锌矿结构的基本概念，掌握晶格参数与原子半径的关系，并正确应用堆积因子的计算公式。题目涉及多步计算和概念关联，但选项已给出正确结果，减少了部分计算复杂度。" + }, + { + "idx": 3636, + "question": "Would you expect CsBr to have the sodium chloride, zinc blende, fluorite, or cesium chloride structure?", + "answer": "CsBr is expected to have the cesium chloride structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四种晶体结构（sodium chloride, zinc blende, fluorite, cesium chloride）中选择CsBr最可能具有的结构类型。 | 知识层次: 题目考查对晶体结构类型的基本记忆和理解，需要根据CsBr的离子半径比和已知的晶体结构类型进行匹配，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆CsBr的晶体结构类型，但只需理解离子半径比和配位数等基本原理即可做出正确选择，无需复杂的分析或比较。" + }, + { + "idx": 3637, + "question": "Based on the cesium chloride structure, determine the lattice parameter for CsBr.", + "answer": "The lattice parameter a0 = 4.1916 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于氯化铯结构确定CsBr的晶格参数，需要通过数值计算和公式应用来得出具体数值结果（4.1916 Å）。答案是一个具体的计算值，而非选择、判断或文字解释。 | 知识层次: 题目要求基于氯化铯结构计算CsBr的晶格参数，属于基本公式应用和简单计算，直接套用已知结构和计算方法即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行单一计算，属于最基础的难度等级。题目明确给出了结构类型（cesium chloride结构），并直接要求计算晶格参数，无需额外的概念理解或复杂的解题步骤。" + }, + { + "idx": 3638, + "question": "Based on the cesium chloride structure, determine the density for CsBr.", + "answer": "The density ρ = 4.8 g/cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于氯化铯结构计算CsBr的密度，需要应用相关公式和数值计算，最终给出具体的密度值（4.8 g/cm3），符合计算题的特征。 | 知识层次: 题目需要基于CsCl结构的知识，应用密度计算公式，涉及多步计算和概念关联，如晶格常数、原子质量、阿伏伽德罗常数等综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解CsCl结构类型、计算晶胞参数、应用密度公式，并进行多步单位换算和数值计算。虽然题目提供了正确选项减少了验证步骤，但仍需综合运用晶体结构和化学计量知识完成推导过程。" + }, + { + "idx": 3639, + "question": "Based on the cesium chloride structure, determine the packing factor for CsBr.", + "answer": "The packing factor pf = 0.693.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于氯化铯结构计算CsBr的堆积因子，需要应用公式进行数值计算，最终给出一个具体的数值结果(0.693)。这符合计算题的特征。 | 知识层次: 题目需要基于CsCl结构进行计算，涉及多步计算和概念关联，包括晶体结构理解、原子半径计算和堆积因子的公式应用，需要综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解CsCl晶体结构的概念，掌握堆积因子的计算方法，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及离子半径的确定、晶胞体积计算以及离子体积的求和，需要较强的概念关联和计算能力。" + }, + { + "idx": 3640, + "question": "Calculate the planar packing fraction (ppf) on the (110) plane for ZnS (with the zinc blende structure).", + "answer": "0.492", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算ZnS在(110)晶面上的平面堆积分数(ppf)，需要应用相关公式进行数值计算，最终答案为具体数值0.492，符合计算题的特征。 | 知识层次: 题目要求计算ZnS（闪锌矿结构）的(110)晶面的平面堆积分数(ppf)，这需要理解晶体结构、晶面指数和堆积分数的概念，并应用相关公式进行多步计算。虽然不涉及复杂的综合分析或创新应用，但需要将多个概念关联起来进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、平面堆积分数的概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及对ZnS锌矿结构的理解、(110)平面的原子排列分析以及平面堆积分数的计算，这些步骤需要较强的概念关联和计算能力。" + }, + { + "idx": 3641, + "question": "Calculate the planar packing fraction (ppf) on the (110) plane for CaF2 (with the fluorite structure).", + "answer": "0.699", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算CaF2在(110)面上的平面堆积分数(ppf)，需要使用数值计算和公式应用，最终答案是一个具体的数值(0.699)。 | 知识层次: 题目需要计算平面堆积分数（ppf），这涉及到理解晶体结构（氟化钙的萤石结构）和特定晶面（110）的原子排列。计算过程需要应用几何关系和公式，涉及多步计算和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解氟化钙的萤石结构、(110)晶面的原子排列方式，并进行多步计算（包括确定晶面原子数、计算有效原子面积和晶面面积等）。虽然题目提供了正确选项，但解题过程涉及概念关联和综合分析，比单纯记忆或简单计算的选择题更复杂。" + }, + { + "idx": 3642, + "question": "MgO, which has the sodium chloride structure, has a lattice parameter of 0.396 nm. Determine the planar density and the planar packing fraction for the (111) plane of MgO. What ions are present on this plane?", + "answer": "(111) plane:\n- planar density (p.d.): 0.1473 x 10^16 points/cm^2\n- planar packing fraction (ppf): 0.202\n- ions present: mg^2+ and o^2-", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（如平面密度和平面堆积分数）并应用相关公式，答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算（平面密度和平面堆积分数的计算），需要理解晶体结构、晶面指数和离子排列的概念，并进行综合分析。虽然不涉及复杂的推理或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、平面密度计算、离子分布等多个概念，并进行多步骤计算。虽然题目提供了正确选项，但学生仍需理解(111)平面的几何特征、离子排列方式，并能正确应用平面密度和堆积分数的计算公式。这需要将理论知识与数学计算相结合，属于典型的综合性计算问题。" + }, + { + "idx": 3644, + "question": "A diffracted x-ray beam is observed from the (220) planes of iron at a 2 \\theta angle of 99.1^{\\circ} when x-rays of 0.15418nm wavelength are used. Calculate the lattice parameter of the iron.", + "answer": "0.2865nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（布拉格定律）来求解铁的晶格参数，答案是一个具体的数值结果（0.2865nm），符合计算题的特征。 | 知识层次: 题目需要应用布拉格定律进行多步计算，涉及波长、衍射角和晶面间距的关联，需要综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解布拉格定律、晶面间距计算和晶格参数之间的关系，并进行多步计算。虽然题目提供了关键参数，但解题过程涉及多个概念的综合应用和单位转换，对学生的知识掌握和计算能力有一定要求。" + }, + { + "idx": 3645, + "question": "Calculate the number of vacancies per {cm}^{3} expected in copper at 1080^{\\circ} C (just below the melting temperature). The activation energy for vacancy formation is 20,000 cal/mol.", + "answer": "4.97 × 10^{19} vacancies/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铜在特定温度下的空位数），需要使用公式（如Arrhenius方程）进行计算，答案是一个具体的数值结果（4.97 × 10^{19} vacancies/cm^3）。 | 知识层次: 题目需要应用热力学公式计算空位浓度，涉及多步计算（如温度转换、能量单位转换等），并需要理解空位形成能与温度的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算和综合分析。题目涉及激活能、温度与空位浓度的关系，需要应用阿伦尼乌斯公式进行计算，并正确转换单位。虽然题目提供了必要的参数，但解题过程需要一定的物理化学基础和计算能力。" + }, + { + "idx": 3646, + "question": "The fraction of lattice points occupied by vacancies in solid aluminum at 660^{\\circ} C is 10^{-3}. What is the activation energy required to create vacancies in aluminum?", + "answer": "12800 cal/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解激活能，答案是一个具体的数值结果（12800 cal/mol），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及激活能的概念理解与公式推导，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解空位分数与温度的关系（阿伦尼乌斯方程），并进行多步计算（包括对数运算和单位转换）。虽然题目提供了关键参数，但需要综合应用热力学和材料科学知识来推导激活能，属于典型的综合性计算问题。" + }, + { + "idx": 3647, + "question": "The density of a sample of HCP beryllium is 1.844 g/cm³ and the lattice parameters are a₀=0.22858 nm and c₀=0.35842 nm. Calculate the fraction of the lattice points that contain vacancies.", + "answer": "0.0008", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，涉及密度、晶格参数和空位分数的计算，需要应用相关公式和步骤来得出具体数值答案。答案是一个具体的数值（0.0008），符合计算题的特征。 | 知识层次: 题目需要应用HCP晶体结构的基本知识，进行多步计算（包括密度计算、晶格参数应用、空位分数计算等），涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解六方密堆积（HCP）晶体的结构参数与密度的关系，并应用密度公式计算理论密度与实际密度的差异，进而推导空位分数。解题步骤包括：" + }, + { + "idx": 3649, + "question": "BCC lithium has a lattice parameter of 3.5089 × 10^-8 cm and contains one vacancy per 200 unit cells. Calculate the number of vacancies per cubic centimeter.", + "answer": "1.157 × 10^20 vacancies/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算空位浓度），需要应用公式和单位转换，最终给出具体数值答案。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的晶格参数和空位数量计算单位体积内的空位数。虽然需要理解BCC结构和空位的概念，但计算过程相对直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解BCC结构的基本概念和单位晶胞的体积计算，但解题步骤相对直接：首先计算单位晶胞的体积，然后根据给定的空位比例计算每立方厘米的空位数。主要涉及基本公式的直接套用和简单计算，不需要复杂的推导或多步骤组合。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3650, + "question": "BCC lithium has a lattice parameter of 3.5089 × 10^-8 cm and contains one vacancy per 200 unit cells. Calculate the density of Li.", + "answer": "0.532 g/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如晶格参数、空位密度等）来求解锂的密度，答案是一个具体的数值结果（0.532 g/cm³），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算单位晶胞的质量、考虑空位的影响，以及应用密度公式。这需要理解BCC结构的基本概念，并能将空位浓度与密度计算关联起来，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、晶格参数与密度的关系，并进行多步计算。题目涉及单位换算、缺陷浓度对密度的影响等综合分析，但选项提供了明确答案，减少了部分复杂性。" + }, + { + "idx": 3651, + "question": "FCC lead has a lattice parameter of 0.4949 nm and contains one vacancy per 500 Pb atoms. Calculate the density.", + "answer": "the density is 11.335 g/cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解FCC铅的密度，答案是一个具体的数值结果（11.335 g/cm3），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶格参数与密度的关系、空位浓度的计算等，需要综合应用材料科学中的基本概念和公式，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、空位浓度、密度计算等多个概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及单位换算、原子质量应用和综合公式推导，对学生的概念关联和计算能力要求较高。" + }, + { + "idx": 3652, + "question": "FCC lead has a lattice parameter of 0.4949 nm and contains one vacancy per 500 Pb atoms. Calculate the number of vacancies per gram of Pb.", + "answer": "the number of vacancies per gram of pb is 5.82 × 10^18 vacancies/g.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶格参数和空位浓度的计算，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的晶格参数和空位浓度计算每克铅中的空位数。虽然需要理解FCC结构和空位的概念，但计算过程相对直接，属于基本公式的直接套用和简单计算。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用基本公式（如计算单位晶胞中的原子数、摩尔质量等），但解题步骤相对直接，不涉及多个公式的组合或复杂的概念分析。学生只需正确套用公式并进行简单计算即可得出答案，因此难度等级为2。" + }, + { + "idx": 3653, + "question": "A niobium alloy is produced by introducing tungsten substitutional atoms in the BCC structure; eventually an alloy is produced that has a lattice parameter of 0.32554nm and a density of 11.95g / {cm}^{3}. Calculate the fraction of the atoms in the alloy that are tungsten.", + "answer": "0.345", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钨原子在合金中的比例，答案是一个具体的数值（0.345），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶格参数和密度的关系计算，以及原子分数的推导。这需要理解BCC结构、原子质量和密度之间的关系，并进行综合分析。虽然不涉及复杂的推理或机理解释，但需要多个步骤和概念的综合应用。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC结构、晶格参数与密度的关系，并进行多步计算。题目涉及原子分数计算，需要综合运用材料科学和数学知识，但选项提供了明确目标，减少了开放性问题带来的复杂度。" + }, + { + "idx": 3654, + "question": "Tin atoms are introduced into a FCC copper crystal, producing an alloy with a lattice parameter of 3.7589 × 10^{-8} cm and a density of 8.772g / {cm}^{3}. Calculate the atomic percentage of tin present in the alloy.", + "answer": "11.95%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锡在合金中的原子百分比，答案是一个具体的数值结果（11.95%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括利用晶格参数计算晶胞体积、应用密度公式计算原子质量、结合铜和锡的原子质量计算原子百分比等步骤。这需要综合运用材料科学中的晶体结构知识和化学计量知识，属于中等应用层次。 | 难度: 在选择题中属于高难度，需要综合运用多个概念（如晶体结构、密度计算、原子百分比等）并进行多步复杂计算。题目要求考生不仅掌握FCC晶格参数与密度的关系，还需要处理合金中不同原子的贡献，涉及单位换算和代数运算。这种综合性计算问题在选择题中属于较难的类型，需要较强的分析能力和计算技巧。" + }, + { + "idx": 3655, + "question": "We replace 7.5 atomic percent of the chromium atoms in its BCC crystal with tantalum. X-ray diffraction shows that the lattice parameter is 0.29158nm. Calculate the density of the alloy.", + "answer": "8.265g / {cm}^{3}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解合金的密度，答案是一个具体的数值结果（8.265g/cm³），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子百分比替换、晶格参数的应用以及密度的计算，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的思维深度和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解合金成分替换的概念、BCC晶体结构参数与密度的关系，并进行多步计算（包括原子质量换算、晶胞体积计算和密度公式应用）。虽然题目提供了关键参数（晶格常数），但仍需要综合运用材料科学和化学知识才能得出正确答案。" + }, + { + "idx": 3656, + "question": "Suppose we introduce one carbon atom for every 100 iron atoms in an interstitial position in BCC iron, giving a lattice parameter of 0.2867 nm. For the Fe-C alloy, find the density.", + "answer": "7.89 g/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Fe-C合金的密度，答案是一个具体的数值（7.89 g/cm³），这表明解答过程需要涉及材料科学中的密度计算公式和单位转换等计算步骤。 | 知识层次: 题目需要进行多步计算，包括确定晶胞中的原子数、计算晶胞质量、体积以及最终的密度计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用晶体结构、原子质量和密度计算等知识，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、原子质量和密度计算的知识。解题步骤包括：1) 理解BCC铁的单位晶胞原子数；2) 计算掺杂碳后的晶胞质量；3) 利用晶格参数计算晶胞体积；4) 综合计算密度。虽然题目给出了关键参数（晶格常数），但仍需进行多步计算和单位换算，且需要正确理解间隙固溶体的概念。相比简单回忆型选择题，这需要更高层次的应用能力。" + }, + { + "idx": 3657, + "question": "Suppose we introduce one carbon atom for every 100 iron atoms in an interstitial position in BCC iron, giving a lattice parameter of 0.2867 nm. For the Fe-C alloy, find the packing factor.", + "answer": "0.681", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Fe-C合金的堆积因子，答案是一个具体的数值结果(0.681)，这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算晶胞体积、原子体积和间隙原子体积，并应用堆积因子的公式。虽然不涉及复杂的推理分析或机理解释，但需要综合运用材料科学中的基本概念和计算方法。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、间隙原子位置、晶格参数与原子半径的关系等多个概念，并进行多步计算（包括原子半径计算、体积计算和堆积因子公式应用）。虽然题目提供了关键参数（晶格常数），但仍需要综合运用材料晶体学知识才能得出正确选项。" + }, + { + "idx": 3658, + "question": "The density of BCC iron is 7.882 g/cm³ and the lattice parameter is 0.2886 nm when hydrogen atoms are introduced at interstitial positions. Calculate the atomic fraction of hydrogen atoms.", + "answer": "0.004", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如密度、晶格参数和原子分数之间的关系）来求解氢原子的原子分数，最终答案为具体数值0.004，符合计算题的特征。 | 知识层次: 题目需要多步计算（密度计算、晶胞体积计算、原子数计算等），涉及BCC晶体结构、晶格参数、原子分数等概念的关联应用，需要综合分析能力。虽然不涉及复杂机理分析，但比简单套用公式要求更高。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC结构、密度计算、晶格参数与原子分数的关系等多个概念，并进行多步计算和综合分析。虽然题目提供了部分数据，但解题过程涉及单位转换和公式应用，对学生的应用能力有一定要求。" + }, + { + "idx": 3659, + "question": "The density of BCC iron is 7.882 g/cm³ and the lattice parameter is 0.2886 nm when hydrogen atoms are introduced at interstitial positions. Calculate the number of unit cells required on average that contain hydrogen atoms.", + "answer": "123.5", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算单位晶胞数量），答案是一个具体数值（123.5），需要使用公式和给定的物理参数（密度、晶格常数）进行计算。 | 知识层次: 题目需要进行多步计算，包括密度和晶格参数的应用，以及单位晶胞数量的计算。虽然不涉及复杂的综合分析或推理，但需要理解BCC结构的基本原理和氢原子在间隙位置的分布情况，并进行适当的数值计算。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC结构、密度计算、晶格参数和氢原子占据间隙位置等多个概念，并进行多步计算和综合分析。虽然题目给出了部分参数，但仍需考生掌握相关公式和单位转换，属于综合性计算问题。" + }, + { + "idx": 3660, + "question": "Suppose one Schottky defect is present in every tenth unit cell of MgO. MgO has the sodium chloride crystal structure and a lattice parameter of 0.396 nm. Calculate the number of anion vacancies per cm3.", + "answer": "1.61 × 10^21 vacancies/cm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算每立方厘米的阴离子空位数），需要应用公式和单位转换，最终答案为具体数值（1.61 × 10^21 vacancies/cm^3），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算单位晶胞体积、确定缺陷密度，并最终转换为每立方厘米的缺陷数。这需要理解Schottky缺陷的概念、晶格参数的应用以及单位转换的综合能力。虽然不涉及复杂的推理或机理解释，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及Schottky缺陷的概念、晶格参数的计算以及单位转换，解题步骤包括计算单位晶胞体积、确定缺陷密度以及转换为每立方厘米的缺陷数。虽然计算步骤较多，但在选择题型中，正确选项的提示可以帮助考生验证计算过程，因此难度适中。" + }, + { + "idx": 3661, + "question": "Suppose one Schottky defect is present in every tenth unit cell of MgO. MgO has the sodium chloride crystal structure and a lattice parameter of 0.396 nm. Calculate the density of the ceramic.", + "answer": "4.205 g/cm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解MgO陶瓷的密度，答案是一个具体的数值（4.205 g/cm^3），这符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括理解Schottky缺陷的概念、MgO的晶体结构、晶格参数的应用以及密度的计算公式。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷的概念、晶格参数与密度的关系，并进行多步计算。虽然题目给出了正确选项，但解题过程涉及单位换算、缺陷浓度计算和密度公式的综合应用，对学生的概念掌握和计算能力要求较高。" + }, + { + "idx": 3662, + "question": "ZnS has the zinc blende structure. If the density is 3.02 g/cm3 and the lattice parameter is 0.59583 nm, determine the number of Schottky defects per unit cell.", + "answer": "0.0535 defects per unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶格中的肖特基缺陷数量，答案是一个具体的数值结果（0.0535 defects per unit cell），这表明解答过程涉及计算步骤而非选择、判断或文字解释。 | 知识层次: 题目需要多步计算和概念关联，包括密度计算、晶格参数应用、Schottky缺陷数量的推导等综合分析过程，涉及中等难度的应用能力。 | 难度: 在选择题中属于中等偏上难度，需要综合运用密度计算、晶体结构分析以及缺陷化学的知识。解题步骤包括计算理论密度、实际密度比较、缺陷浓度推导等多个环节，涉及多步计算和概念关联。虽然题目提供了关键参数，但需要考生具备较强的综合分析能力才能正确解答。" + }, + { + "idx": 3664, + "question": "Calculate the length of the Burgers vector in BCC niobium", + "answer": "b = 2.853 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算BCC铌中Burgers矢量的长度，需要通过数值计算和公式应用来得出具体数值结果（2.853 Å），属于典型的计算题类型。 | 知识层次: 题目要求计算BCC结构中Burgers矢量的长度，这需要应用基本的晶体学公式和已知的晶格常数进行简单计算。虽然需要理解Burgers矢量的概念和BCC结构的特点，但整体上是一个直接套用公式的计算过程，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算BCC结构中的Burgers矢量长度，这只需要应用BCC晶体的Burgers矢量公式b = a√3/2（其中a为晶格常数），并代入已知的晶格常数进行简单计算即可。不需要多个公式组合或复杂推导，属于最基础的计算题类型。" + }, + { + "idx": 3665, + "question": "Calculate the length of the Burgers vector in FCC silver", + "answer": "b = 2.889 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算FCC银中Burgers矢量的长度），答案是一个具体的数值结果（2.889 Å），需要使用材料科学中的相关公式和计算方法。 | 知识层次: 题目要求计算FCC银的Burgers矢量长度，这需要应用基本的晶体学公式和已知的晶格常数进行简单计算。虽然需要理解Burgers矢量的概念，但计算过程直接且不涉及多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接应用FCC晶体结构中Burgers矢量的基本公式（b = a√2/2），并进行简单的数值计算。题目明确给出了所有必要参数（FCC银的晶格常数a=4.09Å），解题步骤单一且无需复杂推导，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 3666, + "question": "Calculate the length of the Burgers vector in diamond cubic silicon", + "answer": "b = 3.840 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers vector的长度），答案是一个具体的数值结果（3.840 Å），这符合计算题的特征。 | 知识层次: 题目需要计算Burgers向量的长度，这涉及到对晶体结构（金刚石立方硅）的理解以及相关公式的应用。虽然计算本身可能不复杂，但需要理解Burgers向量的定义、晶体结构的知识以及如何将这些知识应用到具体材料中。这属于中等应用层次，因为它需要多步计算和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解Burgers向量的概念，知道金刚石立方结构硅的晶格常数，并能正确计算Burgers向量的长度。这涉及到多个步骤的计算和对晶体结构概念的综合应用。" + }, + { + "idx": 3667, + "question": "A single crystal of an FCC metal is oriented so that the direction is parallel to an applied stress of 5000 psi. Calculate the resolved shear stress acting on the (111) slip plane in the [T] slip direction.", + "answer": "the resolved shear stress acting on the (111) slip plane in the [T] slip direction is 0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定平面和方向上的剪切应力，答案是一个具体的数值结果（0），符合计算题的特征。 | 知识层次: 题目需要应用晶体学中的施密特定律（Schmid's Law）来计算分解剪切应力，涉及多步计算和概念关联（如晶面指数、晶向指数、应力分解等），需要综合分析能力。虽然不涉及复杂的机理或创新设计，但比简单的公式应用要求更高。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体取向、应力分解、滑移系选择等多个概念，并进行多步向量计算才能得出正确结论。虽然题目给出了具体数值条件，但需要考生综合应用材料力学和晶体学知识才能判断出该特定取向下的分解切应力为零的结果。" + }, + { + "idx": 3669, + "question": "A single crystal of an FCC metal is oriented so that the direction is parallel to an applied stress of 5000 psi. Which slip system(s) will become active first?", + "answer": "the slip systems that will become active first are λ011 and λ101.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求识别并解释在特定应力条件下FCC金属单晶中首先激活的滑移系统，答案需要文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目需要理解FCC晶体的滑移系统，并应用施密特定律（Schmid's Law）来确定在特定应力方向下哪个滑移系统会首先激活。这涉及到多步计算和概念关联，但不需要复杂的推理或深度理解。 | 难度: 在选择题中属于较高难度，需要综合应用晶体学、材料力学和滑移系统激活条件等知识。解题步骤包括：1) 确定FCC晶体的滑移面和滑移方向；2) 计算不同滑移系统的施密特因子；3) 比较施密特因子大小判断哪个滑移系统会首先激活。这需要考生能够将多个概念联系起来进行综合分析，并完成多步计算。" + }, + { + "idx": 3670, + "question": "A single crystal of a BCC metal is oriented so that the direction is parallel to the applied stress. If the critical resolved shear stress required for slip is 12,000 psi, calculate the magnitude of the applied stress required to cause slip to begin in the [1,-1,1] direction on the (110) slip plane.", + "answer": "the magnitude of the applied stress required to cause slip to begin in the [1,-1,1] direction is: on the (110) slip plane: σ = ∞", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解施加应力的大小，答案给出了具体的计算结果（σ = ∞），符合计算题的特征。 | 知识层次: 题目需要应用临界分切应力概念，进行晶体取向与应力关系的多步计算，涉及向量点积和晶体学方向分析等中等复杂度的综合应用。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求计算BCC金属单晶在特定取向下的临界应力，涉及多个步骤和概念的综合应用。首先需要理解晶体取向、滑移方向和滑移面的关系，其次要应用临界分切应力的概念进行计算。题目中的正确选项表明需要认识到在给定条件下无法发生滑移（σ = ∞），这要求考生不仅掌握计算步骤，还要深入理解晶体滑移的几何限制条件。这种多变量、多概念的综合分析在选择题中属于复杂难度。" + }, + { + "idx": 3673, + "question": "The strength of titanium is found to be 65,000 psi when the grain size is 17 x 10^-6 m and 82,000 psi when the grain size is 0.8 x 10^-6 m. Determine the constants in the Hall-Petch equation.", + "answer": "the constants in the hall-petch equation are k = 19.4 psi/sqrt(d) and σ_o = 60,290 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和Hall-Petch方程进行计算，以确定方程中的常数k和σ_o。解答过程涉及数值计算和公式应用，最终需要得出具体的数值结果。 | 知识层次: 题目需要应用Hall-Petch方程进行多步计算，涉及两个不同条件下的强度数据求解方程中的常数，需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch方程的概念，并能够根据给定的数据建立方程组求解常数。解题步骤涉及多步计算和综合分析，但选择题型提供了正确选项，降低了部分难度。" + }, + { + "idx": 3674, + "question": "The strength of titanium is found to be 65,000 psi when the grain size is 17 x 10^-6 m and 82,000 psi when the grain size is 0.8 x 10^-6 m. Determine the strength of the titanium when the grain size is reduced to 0.2 x 10^-6 m.", + "answer": "the strength of the titanium when the grain size is reduced to 0.2 x 10^-6 m is 103,670 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行计算，以确定钛在特定晶粒尺寸下的强度。答案是一个具体的数值结果，需要通过数学运算得出。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的强度关系分析，需要理解晶粒尺寸对材料强度的影响机制，并进行数值计算和结果预测。 | 难度: 在选择题中属于中等偏上难度，需要应用Hall-Petch关系进行多步计算，涉及反推材料常数和预测新条件下的强度值。虽然选择题提供了正确选项，但仍需理解晶粒尺寸与强度的非线性关系，并执行两次数据点拟合才能得出答案。这超出了简单概念回忆或单步计算的难度，但尚未达到需要处理复杂多变量或非常规公式的等级4水平。" + }, + { + "idx": 3675, + "question": "For an ASTM grain size number of 8, calculate the number of grains per square inch at a magnification of 100.", + "answer": "128 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算每平方英寸的晶粒数量），并应用ASTM晶粒尺寸公式，答案是一个具体的数值结果。 | 知识层次: 题目涉及ASTM晶粒度标准的基本公式应用，计算过程直接套用公式即可完成，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接要求应用ASTM晶粒度计算公式，仅需简单代入数值即可得出结果，无需复杂推理或多步骤计算。正确选项直接对应公式计算结果，属于最基础的应用层次。" + }, + { + "idx": 3676, + "question": "For an ASTM grain size number of 8, calculate the number of grains per square inch with no magnification.", + "answer": "1.28 × 10^6 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算晶粒数量），并给出了具体的计算公式和答案形式（1.28 × 10^6 grains/in.^2），符合计算题的特征。 | 知识层次: 题目要求根据ASTM晶粒度标准直接应用公式计算单位面积内的晶粒数量，属于基本公式的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据ASTM晶粒度编号8直接套用公式计算每平方英寸的晶粒数量，无需额外的推导或组合多个公式。解题步骤简单，仅需应用基本公式并进行简单计算，因此属于最低难度等级。" + }, + { + "idx": 3677, + "question": "Determine the ASTM grain size number if 20 grains/square inch are observed at a magnification of 400 .", + "answer": "the astm grain size number is 9.3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定ASTM晶粒度数值，需要应用公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，仅需单步计算和直接套用公式，无需多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目仅需要应用ASTM晶粒度计算公式进行简单计算，无需多个公式组合或复杂分析。虽然涉及单位转换（从400倍放大率转换为实际面积），但计算步骤直接且明确，属于基本公式应用范畴。" + }, + { + "idx": 3678, + "question": "Determine the ASTM grain size number if 25 grains/square inch are observed at a magnification of 50 .", + "answer": "the astm grain size number is n = 3.6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数，答案是一个具体的数值结果（n = 3.6），这表明解答过程涉及计算步骤。 | 知识层次: 题目要求应用ASTM晶粒度计算公式进行简单计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用ASTM grain size number的计算公式，但题目已经提供了所有必要的数据（25 grains/square inch和50倍放大倍数），只需直接套用公式即可得出结果。解题步骤相对简单，不需要复杂的推导或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 3679, + "question": "Calculate the angle \\theta of a small-angle grain boundary in FCC aluminum when the dislocations are 5000 Å apart. (See Figure 4-18 and equation in Problem 4-46.)", + "answer": "\\theta = 0.0328^{\\circ}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算小角度晶界的角度），并给出了具体的参数（位错间距5000 Å）和参考公式，最终答案是一个具体的数值结果（θ = 0.0328°），符合计算题的特征。 | 知识层次: 题目要求应用给定的公式进行简单的数值计算，不需要多步推理或综合分析，属于基本公式的直接套用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求使用给定的公式（小角度晶界角度计算公式）进行简单数值代入和计算，无需额外的概念理解或复杂的步骤组合。学生只需正确应用公式并完成基本的单位转换即可得出正确答案。" + }, + { + "idx": 3680, + "question": "Atoms are found to move from one lattice position to another at the rate of 5 × 10^{5} jumps/s at 400^{\\circ} C when the activation energy for their movement is 30,000 cal/mol. Calculate the jump rate at 750^{\\circ} C.\n\\section*{", + "answer": "the jump rate at 750^{\\circ} C is 1.08 × 10^{9} jumps/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解跳跃速率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度变化对跳跃速率的影响，需要理解活化能的概念并进行对数运算和指数运算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散速率与温度的关系（阿伦尼乌斯方程），并进行多步计算。虽然题目给出了关键参数，但需要正确应用对数运算和单位转换，属于综合性计算问题。" + }, + { + "idx": 3681, + "question": "The number of vacancies in a material is related to temperature by an Arrhenius equation. If the fraction of lattice points containing vacancies is 8 × 10^{-5} \\mathrm{at} 600^{\\circ} C, determine the fraction at 1000^{\\circ} C.", + "answer": "the fraction at 1000^{\\circ} C is 0.00155.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来确定特定温度下的空位分数，答案是一个具体的数值结果。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及温度变化对空位分数的影响，需要理解方程中各参数的含义并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解Arrhenius方程的概念，并能够进行多步骤的计算和温度转换。题目要求将已知条件代入方程求解未知温度下的空位分数，涉及对数运算和指数计算，属于综合性计算问题。虽然题目提供了正确选项，但解题过程需要较强的概念关联和综合分析能力。" + }, + { + "idx": 3682, + "question": "The diffusion coefficient for Cr+3 in Cr2O3 is 6x10^-15 cm^2/s at 727C and is 1x10^-9 cm^2/s at 1400C. Calculate the activation energy q.", + "answer": "the activation energy q is 59,230 cal/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，使用阿伦尼乌斯方程计算活化能q，需要数值计算和公式应用。答案是一个具体的数值结果（59,230 cal/mol），符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯方程进行多步计算，涉及对数运算和温度转换，需要理解扩散系数与温度的关系，并正确关联公式中的参数。虽然计算过程较为直接，但需要综合运用多个概念并进行适当的数学处理。 | 难度: 在选择题中属于中等难度，需要理解扩散系数与温度的关系（阿伦尼乌斯方程），并进行多步计算来求解活化能。虽然题目提供了必要的数据，但需要考生正确应用对数运算和单位转换，属于综合性计算问题。" + }, + { + "idx": 3683, + "question": "The diffusion coefficient for Cr+3 in Cr2O3 is 6x10^-15 cm^2/s at 727C and is 1x10^-9 cm^2/s at 1400C. Calculate the constant d0.", + "answer": "the constant d0 is 0.055 cm^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用阿伦尼乌斯方程计算常数d0，属于需要数值计算和公式应用的题型。答案也是一个具体的数值结果。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及温度转换和自然对数运算，需要理解扩散系数与温度的关系，并进行综合分析以求解常数d0。 | 难度: 在选择题中属于中等难度，需要理解扩散系数的温度依赖性（阿伦尼乌斯方程），并进行多步计算来求解常数d0。虽然题目提供了必要的数据，但解题过程涉及对数运算和方程组的求解，对概念理解和计算能力有一定要求。" + }, + { + "idx": 3684, + "question": "A 0.2-mm thick wafer of silicon is treated so that a uniform concentration gradient of antimony is produced. One surface contains 1 Sb atom per 10^8 Si atoms and the other surface contains 500 Sb atoms per 10^8 Si atoms. The lattice parameter for Si is 5.407 A. Calculate the concentration gradient in (a) atomic percent Sb per cm.", + "answer": "-0.02495 at% sb/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算浓度梯度），并给出了具体的计算公式和步骤，最终需要得出一个具体的数值结果（-0.02495 at% sb/cm）。这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括浓度转换和梯度计算，涉及多个概念的综合应用，但不需要复杂的推理或深度分析。 | 难度: 在选择题中属于中等偏上难度，需要理解浓度梯度概念、原子百分比计算、单位转换等多个步骤的综合计算。虽然题目提供了关键参数，但解题过程涉及多个概念关联和单位换算，需要较强的综合分析能力。" + }, + { + "idx": 3686, + "question": "When a Cu-Zn alloy solidifies, one portion of the structure contains 25 atomic percent zinc and another portion 0.025mm away contains 20 atomic percent zinc. The lattice parameter for the FCC alloy is 3.63 x 10^-8 cm. Determine the concentration gradient in (a) atomic percent Zn per cm.", + "answer": "-2000 at% zn/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，要求确定浓度梯度，答案是一个具体的数值结果。 | 知识层次: 题目主要涉及浓度梯度的基本计算，需要应用简单的公式和单位转换，属于直接套用基本知识的范畴。虽然涉及单位转换和距离计算，但整体思维过程较为直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察基本公式应用和简单计算能力。题目要求计算浓度梯度，只需套用浓度梯度公式（ΔC/Δx）并进行单位转换即可得出答案。虽然涉及单位换算，但步骤直接且无需复杂推导，因此在选择题型中属于等级2难度。" + }, + { + "idx": 3688, + "question": "A 0.001 -in. BCC iron foil is used to separate a high hydrogen gas from a low hydrogen gas at 650^{\\circ} C .5 × 10^{8} H atoms / {cm}^{3} are in equilibrium with the hot side of the foil, while 2 × 10^{3} H atoms / {cm}^{3} are in equilibrium with the cold side. Determine the concentration gradient of hydrogen.", + "answer": "-1969 × 10^{8} h atoms/cm^3·cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氢的浓度梯度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解浓度梯度的概念并应用扩散公式进行计算，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解浓度梯度的概念，并能够正确应用公式进行计算。题目涉及多步计算过程，包括理解边界条件和正确代入数值，但不需要处理复杂多变量或高级数学技巧。" + }, + { + "idx": 3689, + "question": "A 0.001 -in. BCC iron foil is used to separate a high hydrogen gas from a low hydrogen gas at 650^{\\circ} C .5 × 10^{8} H atoms / {cm}^{3} are in equilibrium with the hot side of the foil, while 2 × 10^{3} H atoms / {cm}^{3} are in equilibrium with the cold side. Determine the flux of hydrogen through the foil.", + "answer": "0.33 × 10^{8} h atoms/cm^2·s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氢通过铁箔的流量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用菲克第一定律进行多步计算，涉及浓度梯度确定、扩散系数计算（需查阅BCC铁中氢的扩散系数数据）以及单位换算等综合分析过程，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散通量的概念，掌握菲克第一定律的应用，并进行多步骤计算。题目涉及浓度梯度、扩散系数（隐含）和厚度换算，需要综合分析多个变量才能得出正确选项。虽然题目提供了部分参数，但考生仍需具备将理论知识与实际计算结合的能力。" + }, + { + "idx": 3690, + "question": "A 1-mm sheet of FCC iron is used to contain nitrogen in a heat exchanger at 1200^{\\circ} C. The concentration of N at one surface is 0.04 atomic percent and the concentration at the second surface is 0.005 atomic percent. Determine the flux of nitrogen through the foil in N atoms / {cm}^{2}·s.", + "answer": "the flux of nitrogen through the foil is 7.57 × 10^{12} n atoms/cm^2 \\cdot s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Fick's first law of diffusion）来确定氮通过铁箔的扩散通量，答案是一个具体的数值结果（7.57 × 10^{12} n atoms/cm^2 \\cdot s），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用扩散定律（Fick's first law）和相关的材料参数（如扩散系数），同时需要理解浓度梯度的概念和单位转换。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行计算。 | 难度: 在选择题中属于中等偏上难度，需要综合运用扩散定律、浓度梯度计算和单位转换等多步骤计算过程。题目涉及FCC结构、高温扩散等概念关联，并要求考生能够正确整合这些知识来求解氮原子通量。虽然题目提供了具体参数，但解题过程需要较强的综合分析能力，属于典型的综合性计算问题。" + }, + { + "idx": 3691, + "question": "A 4-cm-diameter, 0.5-mm-thick spherical container made of BCC iron holds nitrogen at 700^{\\circ} C. The concentration at the inner surface is 0.05 atomic percent and at the outer surface is 0.002 atomic percent. Calculate the number of grams of nitrogen that are lost from the container per hour.", + "answer": "the nitrogen lost from the container per hour is 1.245 × 10^{-3} \\, \\text{g/h}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氮气从容器中每小时流失的克数，答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括扩散方程的建立、浓度梯度的计算、扩散系数的确定以及单位转换等综合分析过程，需要将材料科学中的扩散理论与实际应用相结合。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散定律、浓度梯度、球形容器的几何参数计算等多个概念，并进行多步计算和综合分析。题目涉及温度、浓度差、材料厚度等变量，要求考生能够将这些因素整合起来解决问题。虽然题目提供了正确选项，但解题过程需要较强的应用能力和计算技巧。" + }, + { + "idx": 3692, + "question": "A BCC iron structure is to be manufactured that will allow no more than 50g of hydrogen to be lost per year through each square centimeter of the iron at 400^{\\circ} C. If the concentration of hydrogen at one surface is 0.05 H atom per unit cell and is 0.001 H atom per unit cell at the second surface, determine the minimum thickness of the iron.", + "answer": "the minimum thickness of the iron is 0.179 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如扩散定律）来确定铁的最小厚度，答案是一个具体的数值结果（0.179 cm），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和BCC结构的相关知识，进行综合分析以确定最小厚度。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散定律、晶体结构、浓度梯度等概念，并进行多步计算和综合分析。虽然题目提供了正确选项，但解题过程涉及单位转换、扩散系数查找或计算、菲克第一定律的应用等复杂步骤，对学生的知识掌握和计算能力要求较高。" + }, + { + "idx": 3693, + "question": "Determine the maximum allowable temperature that will produce a flux of less than 2000 H atoms / {cm}^{2}·s through a BCC iron foil when the concentration gradient is -5 × 10^{16} atoms / {cm}^{3}·{cm}. (Note the negative sign for the flux.)", + "answer": "the maximum allowable temperature is 75k (-198^{\\circ} C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定最大允许温度，答案是一个具体的数值结果（75k），这表明解答过程涉及计算步骤和物理公式的应用。 | 知识层次: 题目需要进行多步计算，涉及菲克第一定律的应用和温度对扩散系数的影响，需要将浓度梯度与扩散通量关联起来，并通过阿伦尼乌斯方程求解温度。这要求对扩散理论有较好的理解，并能综合运用相关公式进行计算。 | 难度: 在选择题中属于中等偏上难度，需要综合运用扩散定律和温度关系公式进行多步计算。题目要求考生：" + }, + { + "idx": 3694, + "question": "Compare the rate at which oxygen ions diffuse in \\mathrm{Al}_{2} \\mathrm{O}_{3} with the rate at which aluminum ions diffuse in \\mathrm{Al}_{2} \\mathrm{O}_{3} at 1500^{\\circ} C. Explain the difference.", + "answer": "the diffusion rate of oxygen ions in \\mathrm{al}_{2}\\mathrm{o}_{3} at 1500^{\\circ}C is 3.47 × 10^{-16} {cm}^{2}/s, while the diffusion rate of aluminum ions is 2.48 × 10^{-13} {cm}^{2}/s. the difference in diffusion rates is due to the ionic radii: the oxygen ion has a larger radius (1.32 Å) compared to the aluminum ion (0.51 Å), making it easier for the smaller aluminum ion to diffuse in the ceramic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种离子的扩散速率并解释差异，答案提供了具体的扩散速率数据和文字解释，属于需要论述和解释的简答题类型。 | 知识层次: 题目要求比较两种离子在特定温度下的扩散速率，并解释差异。这涉及多步计算（扩散速率比较）和概念关联（离子半径与扩散速率的关系），需要综合分析能力。虽然不涉及复杂的机理或创新应用，但超出了简单记忆或直接套用公式的层次。 | 难度: 在选择题中属于中等难度，需要理解离子扩散速率的概念，比较不同离子的扩散速率，并解释其差异的原因。题目涉及离子半径对扩散速率的影响，需要综合分析多个因素，但解题步骤相对明确，属于中等应用层次的知识要求。" + }, + { + "idx": 3695, + "question": "Compare the diffusion coefficients of carbon in BCC iron at the allotropic transformation temperature of 912^{\\circ} C and explain the difference.", + "answer": "the diffusion coefficient of carbon in bcc iron at 912^{\\circ} C is 1.51 × 10^{-6} cm^{2} / s, while in fcc iron it is (1.92 × 10^{-7} cm^{2} / s). the packing factor of the bcc lattice (0.68) is less than that of the fcc lattice; consequently, atoms are expected to be able to diffuse more rapidly in the bcc iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较和解释碳在BCC铁中的扩散系数差异，答案提供了详细的文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求学生比较BCC和FCC铁中碳的扩散系数，并解释差异。这需要理解扩散系数的概念、晶体结构（BCC和FCC）的差异及其对扩散的影响。虽然涉及基本概念，但需要将多个知识点关联起来进行综合分析，解释现象背后的原因，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较碳在BCC铁和FCC铁中的扩散系数，并解释差异。这涉及到对晶体结构（BCC和FCC）的理解、扩散系数的概念以及温度对扩散的影响。虽然题目提供了具体数值，但需要考生理解这些数值背后的物理意义和晶体结构的影响。此外，还需要考生能够将扩散系数与晶体结构的堆积因子联系起来，进行综合分析。因此，在选择题型中，这属于中等难度的题目。" + }, + { + "idx": 3696, + "question": "Iron containing 0.05 % C is heated to 912 degrees C in an atmosphere that produces 1.20 % C at the surface and is held for 24 h. Calculate the carbon content at 0.05 cm beneath the surface if the iron is BCC.", + "answer": "For BCC iron, the carbon content at 0.05 cm beneath the surface is 0.95 % C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳含量），并涉及公式应用（扩散方程等），答案是一个具体的数值结果（0.95 % C），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及碳在BCC铁中的扩散问题，需要应用菲克第二定律等相关公式，并结合初始条件和边界条件进行综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及碳在铁中的扩散计算，需要掌握菲克第二定律的应用，同时理解BCC结构对碳扩散的影响。解题步骤包括确定扩散系数、建立扩散方程并求解，属于多步骤计算过程。虽然题目提供了部分参数，但仍需综合分析才能得出正确选项。" + }, + { + "idx": 3697, + "question": "Iron containing 0.05 % C is heated to 912 degrees C in an atmosphere that produces 1.20 % C at the surface and is held for 24 h. Calculate the carbon content at 0.05 cm beneath the surface if the iron is FCC.", + "answer": "For FCC iron, the carbon content at 0.05 cm beneath the surface is 0.95 % C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳含量），并涉及公式应用（FCC结构下的扩散计算），答案以具体数值形式给出。 | 知识层次: 题目需要进行多步计算，包括理解FCC结构对碳扩散的影响、应用扩散方程计算碳含量变化，并综合分析时间和距离对碳浓度分布的影响。这需要将多个概念关联起来并进行中等复杂度的计算。 | 难度: 在选择题中属于中等难度，需要理解扩散原理、相图知识，并进行多步计算和综合分析。虽然题目提供了正确选项，但解题过程涉及菲克第二定律的应用、边界条件设定以及浓度梯度计算，属于综合性计算问题。" + }, + { + "idx": 3698, + "question": "What temperature is required to obtain 0.50% C at a distance of 0.5mm beneath the surface of a 0.20% C steel in 2h, when 1.10% C is present at the surface? Assume that the iron is FCC.", + "answer": "the required temperature is 1180k or 907^{\\circ} C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要应用材料科学中的扩散公式进行数值计算，最终得出具体的温度数值（1180K或907°C），这属于典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和相图知识进行综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用扩散定律、相图知识和多步骤计算能力。题目要求考生能够将碳浓度梯度、扩散距离和时间等参数关联起来，并正确应用FCC结构下的扩散公式进行计算。虽然提供了正确选项可以减少部分计算量，但仍需理解题目背景和建立正确的数学模型才能验证选项的正确性。" + }, + { + "idx": 3699, + "question": "A 0.15% C steel is to be carburized at 1100^{\\circ} C, giving 0.35% C at a distance of 1mm beneath the surface. If the surface composition is maintained at 0.90% C, what time is required?", + "answer": "the required time is 51 \\mathrm{min}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及碳扩散时间的计算，答案以具体数值形式给出。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和误差函数解，综合分析碳浓度分布与时间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解碳扩散的基本概念，掌握菲克第二定律的应用，并进行多步骤计算。题目涉及表面浓度、目标浓度和距离的设定，要求考生能够正确代入公式并解出时间参数。虽然题目提供了具体数值，但计算过程需要一定的综合分析能力和对材料科学基础知识的掌握。" + }, + { + "idx": 3700, + "question": "A 0.02% C steel is to be carburized at 1200^{\\circ} C in 4h, with a point 0.6mm beneath the surface reaching 0.45% C. Calculate the carbon content required at the surface of the steel.", + "answer": "the carbon content required at the surface of the steel is 0.53% C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定钢表面的碳含量。答案是一个具体的数值结果（0.53% C），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及碳扩散公式的应用和边界条件的设定，需要理解碳浓度分布的概念，并能够将实际问题转化为数学模型进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要综合运用扩散定律和边界条件进行计算。题目涉及多步骤计算过程（包括扩散系数计算、误差函数应用等），并要求将多个材料科学概念（如碳浓度梯度、稳态扩散条件）关联起来进行综合分析。虽然选择题型提供了正确选项降低了部分难度，但仍需较强的概念理解和计算能力才能正确解答。" + }, + { + "idx": 3701, + "question": "A 1.2% C tool steel held at 1150^{\\circ} C is exposed to oxygen for 48h. The carbon content at the steel surface is zero. To what depth will the steel be decarburized to less than 0.20% C ?", + "answer": "0.177 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定脱碳深度，答案是一个具体的数值（0.177 cm），这表明需要进行数学运算和物理模型的应用。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和碳浓度分布的知识进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用扩散定律和菲克第二定律进行计算，涉及多步骤的数学推导和概念关联。虽然题目提供了关键参数，但解题过程需要将理论知识与实际应用相结合，属于典型的综合性计算问题。" + }, + { + "idx": 3702, + "question": "A 0.80% C steel must operate at 950^{\\circ} C in an oxidizing environment, where the carbon content at the steel surface is zero. Only the outermost 0.02 cm of the steel part can fall below 0.75% C. What is the maximum time that the steel part can operate?", + "answer": "the maximum time that the steel part can operate is 2.9 min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定钢部件在特定条件下的最大操作时间。答案是一个具体的数值（2.9分钟），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，包括扩散方程的运用和边界条件的设定，涉及碳在钢中的扩散行为分析，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如碳扩散、氧化环境的影响）并进行多步计算（如菲克第二定律的应用）。虽然题目提供了具体条件和限制，但解题过程涉及综合分析不同因素，如碳含量梯度、扩散时间和距离的关系，以及边界条件的应用。这比简单的单步计算或概念识别题更复杂，但比涉及多变量或非线性关系的题目略简单。" + }, + { + "idx": 3703, + "question": "A steel with \\mathrm{BBC} crystal structure containing 0.001%N is nitrided at 550^{\\circ} C for 5h. If the nitrogen content at the steel surface is 0.08%, determine the nitrogen content at 0.25mm from the surface.", + "answer": "the nitrogen content at 0.25mm from the surface is 0.049% n.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要应用扩散定律进行数值计算，通过给定的初始条件（0.001%N）、边界条件（0.08%表面浓度）和扩散参数（550°C、5h）来求解特定位置（0.25mm处）的氮浓度，最终答案为具体数值（0.049%），符合计算题的特征。 | 知识层次: 题目需要应用扩散定律进行多步计算，涉及浓度梯度、扩散系数等概念的综合运用，需要理解Fick第二定律并正确代入边界条件进行计算，属于中等难度的应用题型。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散定律和浓度分布的概念，并进行多步计算。题目涉及非稳态扩散的求解，需要应用误差函数解法和边界条件的设定，属于综合性计算问题。虽然选择题型提供了正确选项，但仍需考生具备较强的概念关联和计算能力才能正确解答。" + }, + { + "idx": 3704, + "question": "What time is required to nitride a 0.002N steel to obtain 0.12%N at a distance of 0.002 in. beneath the surface at 625^{\\circ} C ? The nitrogen content at the surface is 0.15%.\n\\[\n\\begin{array}{l}\n", + "answer": "12.8 min", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氮化所需的时间，答案是一个具体的数值（12.8 min），这表明需要进行数学运算和物理过程的计算。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数代入，需要理解氮化过程的基本原理和扩散机制，但不需要进行复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要综合运用扩散定律、浓度梯度计算以及温度对扩散系数的影响等多步骤计算过程。题目涉及多个概念关联（如表面浓度、目标浓度、扩散距离）和综合分析（温度与时间的关系），但相比需要处理复杂多变量或非线性关系的题目，计算步骤仍相对明确。" + }, + { + "idx": 3705, + "question": "We currently can successfully perform a carburizing heat treatment at 1200^{\\circ} C in 1h. In an effort to reduce the cost of the brick lining in our furnace, we propose to reduce the carburizing temperature to 950^{\\circ} C. What time will be required to give us a similar carburizing treatment?", + "answer": "9.95 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在950°C下达到与1200°C相同渗碳效果所需的时间。答案是一个具体的数值（9.95 h），这表明需要通过计算得出结果。 | 知识层次: 题目需要进行多步计算，涉及热处理温度和时间的关系，需要应用扩散定律（如阿伦尼乌斯方程）进行数值计算，并综合分析温度变化对处理时间的影响。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程（如Arrhenius方程）的应用，进行温度-时间的转换计算。题目涉及多步骤计算（包括对数运算和单位转换），并要求将热处理工艺参数关联起来综合分析。虽然提供了正确选项可以验证结果，但解题过程需要较强的概念理解和计算能力。" + }, + { + "idx": 3706, + "question": "During freezing of a Cu-Zn alloy, we find that the composition is nonuniform. By heating the alloy to 600^{\\circ} C for 3 hours, diffusion of zinc helps to make the composition more uniform. What temperature would be required if we wished to perform this homogenization treatment in 30 minutes?", + "answer": "667°c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过扩散时间与温度的关系计算出所需的温度，答案是一个具体的数值（667°C），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的应用和温度与时间关系的调整，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散动力学中的阿伦尼乌斯方程，并进行多步骤计算（包括时间-温度转换和对数运算）。虽然题目提供了部分参数，但考生仍需综合运用材料科学中的热处理和扩散知识来推导正确答案。相比单纯的概念题或单步计算题，该题目要求更高层次的分析能力和计算技巧。" + }, + { + "idx": 3707, + "question": "A ceramic part made of MgO is sintered successfully at 1700 degrees C in 90 minutes. To minimize thermal stresses during the process, we plan to reduce the temperature to 1500 degrees C. Which will limit the rate at which sintering can be done: diffusion of magnesium ions or diffusion of oxygen ions?", + "answer": "diffusion of oxygen is the slower of the two, due to the larger ionic radius of the oxygen.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪种离子扩散会限制烧结速率，并需要提供文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求分析在烧结过程中不同离子扩散速率对烧结速率的影响，需要综合运用材料科学中的扩散理论、离子半径对扩散速率的影响以及烧结动力学等知识，进行推理分析和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3708, + "question": "A ceramic part made of MgO is sintered successfully at 1700 degrees C in 90 minutes. To minimize thermal stresses during the process, we plan to reduce the temperature to 1500 degrees C. What time will be required at the lower temperature?", + "answer": "the time required at the lower temperature is 955 min or 15.9 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在较低温度下所需的时间。答案给出了具体的数值结果（955 min或15.9 h），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及烧结温度与时间的关系，需要应用相关公式进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解烧结温度与时间的关系（如阿伦尼乌斯方程的应用），并进行多步骤计算。题目涉及材料科学中的动力学概念和实际工艺参数调整，要求考生能够将理论公式与工程实践相结合，属于综合性计算问题。虽然题目提供了正确选项，但解题过程需要综合运用多个知识点和计算步骤，因此在选择题型中属于等级3难度。" + }, + { + "idx": 3709, + "question": "A 850-lb force is applied to a 0.15-in. diameter nickel wire having a yield strength of 45,000 psi and a tensile strength of 55,000 psi. Determine whether the wire will plastically deform.", + "answer": "the wire will plastically deform (48,100 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算应力并与屈服强度比较）和公式应用（应力计算公式），最终得出数值结果并判断是否发生塑性变形。答案也以数值结果和结论的形式呈现。 | 知识层次: 题目需要应用基本公式（应力计算）进行简单计算，并比较结果与给定材料性能参数（屈服强度）。虽然涉及单位换算，但整体思维过程直接，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要应用基本公式（应力计算公式）进行简单计算，并直接比较计算结果与给定材料参数。虽然涉及单位换算和简单代数运算，但解题步骤相对直接，属于选择题型中中等偏下的难度水平。" + }, + { + "idx": 3710, + "question": "A 850-lb force is applied to a 0.15-in. diameter nickel wire having a yield strength of 45,000 psi and a tensile strength of 55,000 psi. Determine whether the wire will experience necking.", + "answer": "no necking will occur (48,100 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算应力并与屈服强度和抗拉强度比较）来判断是否会发生颈缩现象，答案给出了具体的计算结果（48,100 psi）和结论。 | 知识层次: 题目需要进行简单的应力计算（力除以横截面积），并将计算结果与给定的材料强度参数进行比较。虽然涉及公式应用，但计算步骤单一，无需多步推理或综合分析，属于基本公式的直接套用和简单判断。 | 难度: 在选择题型中，该题目属于简单应用层次，需要应用基本公式（应力计算）并进行简单计算。虽然涉及应力与材料强度的比较，但解题步骤较为直接，仅需套用公式并比较数值，无需多个公式组合或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3711, + "question": "A force of 100000 N is applied to a 10mm × 20mm iron bar having a yield strength of 400 MPa. Determine whether the bar will plastically deform.", + "answer": "the bar will plastically deform because the applied stress of 500 MPa exceeds the yield strength of 400 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过计算施加的应力（force/area）并与屈服强度比较来判断是否发生塑性变形。答案中给出了具体的计算过程和数值比较，符合计算题的特征。 | 知识层次: 题目涉及基本的应力计算和与屈服强度的比较，属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要应用基本公式（应力=力/面积）进行简单计算，并将计算结果与材料的屈服强度直接比较。虽然涉及单位换算（mm²到m²），但步骤较为直接，属于等级2的简单公式应用计算难度。" + }, + { + "idx": 3712, + "question": "A force of 100000 N is applied to a 10mm × 20mm iron bar having a tensile strength of 480 MPa. Determine whether the bar will experience necking.", + "answer": "the bar will experience necking because the applied stress of 500 MPa exceeds the tensile strength of 480 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算施加的应力）并与材料的抗拉强度进行比较，以判断是否会发生颈缩现象。答案中包含了具体的计算过程和结论，符合计算题的特征。 | 知识层次: 题目涉及基本的应力计算和材料强度比较，仅需应用应力公式（应力=力/面积）并将计算结果与给定的拉伸强度进行直接比较，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算应力（应力=力/面积），但计算步骤直接且仅涉及单一公式的应用。此外，题目明确给出了所有必要参数，只需将数值代入公式并比较结果与材料的抗拉强度即可得出结论。因此，在选择题型内，该题目属于等级2难度。" + }, + { + "idx": 3713, + "question": "Calculate the maximum force that a 0.2 -in. diameter rod of \\mathrm{Al}_{2} \\mathrm{O}_{3}, having a yield strength of 35,000 psi, can withstand with no plastic deformation. Express your answer in pounds and Newtons.", + "answer": "the maximum force the rod can withstand is 1100 lb or 4891 n.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算最大受力），需要使用公式（强度与受力关系公式），答案以具体数值形式给出（1100 lb或4891 N），这些都是计算题的典型特征。 | 知识层次: 题目考查基本公式的应用和简单计算，只需要根据给定的直径和屈服强度计算最大受力，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（应力=力/面积）进行计算，无需复杂的步骤或多公式组合。题目提供了所有必要的数据，且计算过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 3714, + "question": "A force of 20,000 N will cause a 1 cm × 1 cm bar of magnesium to stretch from 10 cm to 10.045 cm. Calculate the modulus of elasticity in GPa.", + "answer": "the modulus of elasticity is 44.4 GPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（弹性模量计算公式）来求解具体数值结果，答案以具体数值形式给出（44.4 GPa），符合计算题的特征。 | 知识层次: 题目要求应用基本的弹性模量计算公式进行简单数值计算，属于直接套用公式和基本单位转换的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算镁棒的弹性模量，只需应用胡克定律的基本公式（应力=弹性模量×应变），并进行简单的单位换算和数值代入即可得出结果。解题步骤直接且无需复杂的推导或组合多个公式，符合等级1的定义。" + }, + { + "idx": 3715, + "question": "A force of 20,000 N will cause a 1 cm × 1 cm bar of magnesium to stretch from 10 cm to 10.045 cm. Calculate the modulus of elasticity in psi.", + "answer": "the modulus of elasticity is 6.44 × 10^6 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁棒的弹性模量，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的弹性模量计算公式，进行简单的数值计算和单位转换，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解弹性模量的概念并应用公式E = (F/A)/(ΔL/L)，但计算步骤相对直接，且题目提供了所有必要的数据。不需要多个公式组合或复杂的转换，因此难度等级为2。" + }, + { + "idx": 3716, + "question": "A polymer bar's dimensions are 1 in . × 2 in. × 15 in. The polymer has a modulus of elasticity of 600,000 psi. What force is required to stretch the bar elastically to 15.25 in.?", + "answer": "the force required is 200,000 lb.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的力，答案是一个具体的数值结果（200,000 lb），符合计算题的特征。 | 知识层次: 题目涉及基本的弹性模量公式应用和简单计算，仅需直接套用公式并代入数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算弹性拉伸所需的力，直接应用胡克定律（F = kΔx）即可得出答案。解题步骤简单，仅需代入已知数值（弹性模量、尺寸变化）进行基本计算，无需复杂推导或多公式组合。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3717, + "question": "An aluminum plate 0.5 cm thick is to withstand a force of 50,000N with no permanent deformation. If the aluminum has a yield strength of 125 MPa, what is the minimum width of the plate?", + "answer": "the minimum width of the plate is 8 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最小宽度，涉及力学性能参数和基本力学公式的使用。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用（应力=力/面积）和简单计算（根据已知条件求解最小宽度），不需要多步计算或复杂分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题中属于简单应用难度，需要理解屈服强度的概念并应用基本公式（应力=力/面积）进行计算，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 3718, + "question": "(a) A 3-in.-diameter rod of copper is to be reduced to a 2-in.-diameter rod by being pushed through an opening. To account for the elastic strain, what should be the diameter of the opening? The modulus of elasticity for the copper is 17 × 10^{6} psi and the yield strength is 40,000 psi.", + "answer": "the diameter of the opening should be 1.995 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定开口的直径。答案是一个具体的数值结果（1.995 in.），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及弹性应变和材料性能的综合分析，需要理解并应用弹性模量和屈服强度的概念，以及相关的计算公式。虽然不涉及复杂的推理或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性应变、模量、屈服强度等概念，并进行多步计算和综合分析。题目要求考生能够将理论知识与实际应用相结合，通过计算确定合适的开口直径。虽然给出了正确选项，但解题过程涉及多个步骤和概念的综合运用，对考生的理解能力和计算能力有一定要求。" + }, + { + "idx": 3719, + "question": "A 0.4-in. diameter, 12-in-long titanium bar has a yield strength of 50,000 psi, a modulus of elasticity of 16x10^6 psi, and Poisson's ratio of 0.30. Determine the length of the bar when a 500-lb load is applied.", + "answer": "the final length of the bar is 12.00298 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性模量、应变等）来确定棒材在受力后的长度变化，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本公式的应用和简单计算，只需要套用胡克定律和应变公式进行一步计算即可得出结果，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用胡克定律计算应变和长度变化，但步骤较为直接，仅需套用基本公式并进行简单计算。相较于等级1的直接计算，该题目需要理解应变和长度变化的关系，但不需要多个公式组合或复杂分析，因此在选择题型内属于等级2难度。" + }, + { + "idx": 3721, + "question": "A three-point bend test is performed on a block of ZrO2 that is 8 in. long, 0.50 in. wide, and 0.25 in. thick and is resting on two supports 4 in. apart. When a force of 400 lb is applied, the specimen deflects 0.037 in. and breaks. Calculate the flexural strength.", + "answer": "flexural strength = 76,800 psi", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（三点弯曲测试公式）来求解弯曲强度，答案是一个具体的数值结果（76,800 psi），符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用三点弯曲测试的公式来计算弯曲强度。虽然需要理解测试的基本原理，但主要认知层次是应用已知公式进行数值计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算flexural strength，只需套用三点弯曲强度的基本公式（flexural strength = 3FL / 2bd²），代入给定的数值即可得出结果。无需多个公式组合或复杂推导，属于最基础的应用计算题。" + }, + { + "idx": 3722, + "question": "A three-point bend test is performed on a block of ZrO2 that is 8 in. long, 0.50 in. wide, and 0.25 in. thick and is resting on two supports 4 in. apart. When a force of 400 lb is applied, the specimen deflects 0.037 in. and breaks. Calculate the flexural modulus, assuming that no plastic deformation occurs.", + "answer": "flexural modulus = 22.14 x 10^6 psi", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算flexural modulus），需要应用相关公式，答案是一个具体的数值结果（22.14 x 10^6 psi），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及弯曲模量的公式应用和单位转换，需要理解三点弯曲测试的基本原理和材料力学性能的相关概念，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解三点弯曲测试的基本概念，掌握挠度公式的应用，并进行多步骤计算。题目涉及多个变量（长度、宽度、厚度、力、挠度）的综合运用，要求考生能够正确关联公式并代入数值计算，最终得出正确的弯曲模量。虽然题目提供了所有必要参数，但计算过程较为复杂，需要一定的综合分析能力。" + }, + { + "idx": 3723, + "question": "A three-point bend test is performed on a block of silicon carbide that is 10 cm long, 1.5 cm wide, and 0.6 cm thick and is resting on two supports 7.5 cm apart. The sample breaks when a deflection of 0.09mm is recorded. Calculate the force that caused the fracture. The flexural modulus for silicon carbide is 480 GPa. Assume that no plastic deformation occurs.", + "answer": "the force that caused the fracture is 1327 n.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算导致断裂的力），并给出了具体的材料参数和几何尺寸，需要使用公式和数值计算来求解。答案也是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及弯曲模量、几何参数和断裂条件的综合分析，需要理解三点弯曲测试的基本原理并正确应用相关公式。虽然不涉及复杂的推理或机理解释，但计算过程需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解三点弯曲测试的基本原理，掌握挠度、弹性模量和力的关系公式，并进行多步计算。虽然题目提供了所有必要参数，但需要正确应用公式并转换单位（如将GPa转换为Pa，mm转换为m），这增加了复杂性。此外，题目要求综合分析材料性能和几何参数对断裂力的影响，属于综合性计算问题。" + }, + { + "idx": 3724, + "question": "A three-point bend test is performed on a block of silicon carbide that is 10 cm long, 1.5 cm wide, and 0.6 cm thick and is resting on two supports 7.5 cm apart. The sample breaks when a deflection of 0.09mm is recorded. Calculate the flexural strength. The flexural modulus for silicon carbide is 480 GPa. Assume that no plastic deformation occurs.", + "answer": "the flexural strength is 276 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及三点弯曲测试的挠度、弯曲模量等参数，最终需要计算出弯曲强度。答案也是一个具体的数值结果（276 MPa），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用三点弯曲测试的公式来计算弯曲强度，并需要理解材料力学中的相关概念。虽然计算过程较为直接，但需要正确应用公式和单位转换，涉及一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解三点弯曲测试的基本原理，掌握弯曲强度的计算公式，并进行多步计算。题目涉及长度、宽度、厚度、支撑距离、挠度等多个变量的综合运用，同时需要正确应用给定的弹性模量数据。虽然题目提供了所有必要参数，但解题步骤较为复杂，需要较强的综合分析能力。" + }, + { + "idx": 3725, + "question": "A thermosetting polymer containing glass beads is required to deflect 0.5mm when a force of 500 N is applied. The polymer part is 2 cm wide, 0.5 cm thick, and 10 cm long. If the flexural modulus is 6.9 GPa, determine the minimum distance between the supports.", + "answer": "the minimum distance between the supports is 41 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定支撑之间的最小距离，答案是一个具体的数值结果（41 mm），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及材料力学中的弯曲变形公式应用，需要理解并关联材料的弹性模量、几何尺寸和受力条件，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用材料力学和聚合物性能知识进行多步计算。题目涉及弯曲模量、载荷与变形关系的公式推导（如三点弯曲公式），需要将给定参数正确代入并进行单位换算（GPa到MPa、cm到mm）。虽然选择题提供了正确选项可以减少计算验证步骤，但仍需完成完整的公式推导和数值计算过程，属于综合性计算问题。" + }, + { + "idx": 3726, + "question": "Will the polymer fracture if its flexural strength is 85 MPa? Assume that no plastic deformation occurs.", + "answer": "the applied stress is 61.5 MPa, which is less than the flexural strength of 85 MPa; the polymer is not expected to fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过比较施加应力和弯曲强度来判断聚合物是否会断裂，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目涉及基本公式应用和简单计算，只需比较施加应力与弯曲强度的数值关系即可得出结论，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需比较施加应力（61.5 MPa）与弯曲强度（85 MPa）的数值关系即可得出结论。解题步骤直接，无需复杂计算或深入分析，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 3727, + "question": "(b) The flexural modulus of alumina is 45 × 10^{6} psi and its flexural strength is 46,000 psi. A bar of alumina 0.3 in. thick, 1.0 in. wide, and 10 in. long is placed on supports 7 in. apart. Determine the amount of deflection at the moment the bar breaks, assuming that no plastic deformation occurs.", + "answer": "the deflection at the moment the bar breaks is 0.0278 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氧化铝棒断裂时的挠度，答案是一个具体的数值结果（0.0278 in.），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用弹性力学中的梁弯曲公式，计算挠度，并关联材料的力学性能参数（弹性模量和弯曲强度）。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如弹性模量、弯曲强度、梁的挠度计算等）并进行多步骤计算。题目要求考生综合运用材料力学和弹性理论的知识，通过公式推导和数值计算得出最终结果。虽然选择题提供了正确选项，但解题过程涉及多个关键步骤和概念关联，对考生的综合分析能力有一定要求。" + }, + { + "idx": 3728, + "question": "A Brinell hardness measurement, using a 10-mm-diameter indenter and a 500-kg load, produces an indentation of 4.5mm on an aluminum plate. Determine the Brinell hardness number (HB) of the metal.", + "answer": " hb = 29.8 ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Brinell硬度计算公式）来求解硬度值，答案是一个具体的数值结果。 | 知识层次: 题目考查基本公式应用和简单计算，只需套用Brinell硬度计算公式即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型内，该题目属于单一公式直接计算的难度等级。题目要求计算布氏硬度数（HB），只需直接套用布氏硬度的基本公式进行计算，无需额外的概念理解或复杂的解题步骤。题目提供了所有必要的参数（压头直径、载荷、压痕直径），学生只需将这些数值代入公式即可得出正确答案。因此，在选择题型中，该题目属于最简单的难度等级。" + }, + { + "idx": 3729, + "question": "When a 3000-kg load is applied to a 10-mm-diameter ball in a Brinell test of a steel, an indentation of 3.1mm is produced. Estimate the tensile strength of the steel.", + "answer": "the tensile strength of the steel is 194,000 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的负载、直径和压痕尺寸，应用布氏硬度测试的相关公式计算钢的抗拉强度。答案是一个具体的数值结果，需要通过计算得出。 | 知识层次: 题目需要应用布氏硬度测试的基本公式进行多步计算，涉及载荷、压头直径和压痕直径的关联，并进一步推导材料的抗拉强度。虽然计算过程相对直接，但需要理解布氏硬度与抗拉强度之间的关系，并进行适当的单位转换和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解布氏硬度测试原理、掌握硬度与抗拉强度的转换公式，并进行多步骤计算。题目涉及载荷、压痕直径的测量以及单位换算（mm到inch），最后还需要应用经验公式估算抗拉强度。虽然提供了正确选项，但解题过程需要综合应用材料力学和测试方法知识，属于典型的综合性计算问题。" + }, + { + "idx": 3730, + "question": "A ceramic matrix composite contains internal flaws as large as 0.001 cm in length. The plane strain fracture toughness of the composite is 45 MPa / m and the tensile strength is 550 MPa. Will the flaw cause the composite to fail before the tensile strength is reached? Assume that f=1.", + "answer": "the applied stress required for the crack to cause failure is 11,354 MPa. the tensile strength of the composite is 550 MPa. any failure of the ceramic should be expected due to the massive overload, not because of the presence of the flaws.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算裂纹导致失效所需的应力），并应用断裂力学公式（K_IC = f * σ * sqrt(πa)）。答案给出了具体的计算结果和比较过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用断裂力学公式计算临界应力，并将结果与材料的拉伸强度进行比较。虽然计算过程相对直接，但需要理解断裂韧性和裂纹尺寸之间的关系，以及如何应用这些概念来预测材料的失效行为。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及平面应变断裂韧性和拉伸强度的计算，需要应用断裂力学公式（K_IC = fσ√(πa)）来计算临界应力，然后将结果与给定的拉伸强度进行比较。虽然计算步骤明确，但需要综合应用多个概念并进行数值比较，属于多步骤计算和概念关联的综合分析问题。" + }, + { + "idx": 3731, + "question": "An aluminum alloy that has a plane strain fracture toughness of 25,000 psi \\sqrt{m}. fails when a stress of 42,000 psi is applied. Observation of the fracture surface indicates that fracture began at the surface of the part. Estimate the size of the flaw that initiated fracture. Assume that f=1.1.", + "answer": "the size of the flaw that initiated fracture is 0.093 \\text{ in}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过公式计算来估计缺陷的尺寸，涉及数值计算和材料科学中的断裂力学知识。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用断裂力学中的公式进行多步计算，涉及平面应变断裂韧性和应力强度的概念关联，并需要综合分析给定的参数来估算缺陷尺寸。虽然计算过程相对直接，但需要理解公式中各参数的含义及其相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解断裂韧性和应力强度的概念，并应用相关公式进行多步计算。题目要求考生能够综合分析给定参数（断裂韧性、应力、几何因子）并正确代入公式求解缺陷尺寸，涉及中等应用层次的知识和计算能力。" + }, + { + "idx": 3732, + "question": "A polymer that contains internal flaws 1mm in length fails at a stress of 25 MPa. Determine the plane strain fracture toughness of the polymer. Assume that f=1.", + "answer": "the plane strain fracture toughness of the polymer is 0.99 \\text{mpa} \\sqrt{m}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（平面应变断裂韧性公式）来求解聚合物的平面应变断裂韧性，答案是一个具体的数值结果（0.99 MPa√m），符合计算题的特征。 | 知识层次: 题目需要应用基本公式（断裂韧性公式）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求直接应用平面应变断裂韧性的基本公式（K_IC = σ√(πa)），仅需代入给定的应力（25 MPa）和缺陷长度（1mm）即可得出结果。无需额外的概念理解或复杂计算步骤，属于最基础的公式套用类型。" + }, + { + "idx": 3733, + "question": "A ceramic part for a jet engine has a yield strength of 75,000 psi and a plane strain fracture toughness of 5,000 psi / in. To be sure that the part does not fail, we plan to assure that the maximum applied stress is only one third the yield strength. We use a nondestructive test that will detect any internal flaws greater than 0.05 in. long. Assuming that f=1.4, does our nondestructive test have the required sensitivity? Explain.", + "answer": "the length of internal flaws is 2a = 0.013 in. our nondestructive test can detect flaws as small as 0.05 in. long, which is not smaller than the critical flaw size required for failure. thus our ndt test is not satisfactory.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过计算和解释来判断非破坏性测试是否具有所需的灵敏度，答案需要文字解释和论述，而不仅仅是选择或判断对错。 | 知识层次: 题目涉及多步计算（计算最大允许应力、临界缺陷尺寸等）和概念关联（将屈服强度、断裂韧性和缺陷检测能力联系起来），需要综合分析材料的力学性能和检测技术的适用性。虽然不涉及复杂的机理或创新设计，但需要一定的理解和应用能力来解决问题。 | 难度: 在选择题型中，该题目属于较高难度，需要多步计算、概念关联和综合分析。题目要求考生首先计算最大允许应力，然后利用断裂力学公式计算临界缺陷尺寸，最后将计算结果与非破坏性检测的灵敏度进行比较。这一过程涉及多个知识点的综合应用和逻辑推理，超出了简单的概念记忆或单一计算步骤的范畴。因此，在选择题型内属于较难的题目。" + }, + { + "idx": 3734, + "question": "To survive for one million cycles under conditions that provide for equal compressive and tensile stresses, what is the fatigue strength, or maximum stress amplitude, required?", + "answer": "The fatigue strength at one million cycles is 22 mpa.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释在特定条件下所需的疲劳强度，答案提供了具体的数值和解释，符合简答题的特征。 | 知识层次: 题目要求根据给定的条件（一百万次循环）确定疲劳强度，这涉及直接应用疲劳强度的基本概念和已知数据（22 MPa）。虽然需要理解疲劳强度的定义，但主要是一个简单的数据应用过程，不需要多步计算或深入分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式或已知数据（疲劳强度在100万次循环下的标准值）即可得出正确答案。题目没有复杂的计算步骤或需要深入理解多个概念，仅需识别并选择给定的正确选项。因此，在选择题型内属于较低难度（等级2）。" + }, + { + "idx": 3735, + "question": "What are the maximum stress, the minimum stress, and the mean stress on the part during its use under conditions that provide for equal compressive and tensile stresses?", + "answer": "The maximum stress is +22 mpa, the minimum stress is -22 mpa, and the mean stress is 0 mpa.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释最大应力、最小应力和平均应力的具体数值，答案以文字形式给出具体数值，属于简答题类型。 | 知识层次: 题目涉及基本应力概念的应用，要求计算最大应力、最小应力和平均应力，属于直接套用基本公式和简单计算的范畴，不需要复杂的分析或综合思维。 | 难度: 在选择题中属于简单难度，题目直接给出了应力条件（等值压缩和拉伸应力），只需要应用基本公式计算最大、最小和平均应力。解题步骤简单，仅需套用公式即可得出答案，无需复杂分析或深入理解多个概念。" + }, + { + "idx": 3736, + "question": "What effect would the frequency of the stress application have on the fatigue strength, maximum stress, minimum stress, and mean stress?", + "answer": "A high frequency will cause heating of the polymer. As the temperature of the polymer increases, the fatigue strength will decrease. If the applied stress is not reduced, then the polymer will fail in a shorter time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释频率对疲劳强度、最大应力、最小应力和平均应力的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析应力频率对疲劳强度、最大应力、最小应力和平均应力的影响，并解释其机理（如高频导致聚合物发热进而影响疲劳强度）。这需要综合运用材料疲劳行为、热力学和聚合物性能等多方面知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解疲劳强度、最大应力、最小应力和平均应力的基本概念，还需要综合运用材料科学和热力学知识，分析高频应力应用对聚合物温度的影响，并进一步推理温度升高对疲劳强度的作用机制。解题步骤涉及多层次的因果关系分析，需要考生具备复杂现象的全面分析能力和机理深度解释能力。这种题目在选择题型中属于对综合能力和高阶思维要求极高的类型。" + }, + { + "idx": 3737, + "question": "The activation energy for self-diffusion in copper is 49,300 cal / mol. A copper specimen creps as t 0.002 N / fn .-h when a stress of 15,000 psi is applied at 600^{\\circ} C. If the creep rate of copper is dependent on self-diffusion, determine the creep rate if the temperature is 800^{\\circ} C.", + "answer": "the creep rate is 0.4, N / in·h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（涉及激活能、温度变化对蠕变速率的影响）来求解特定温度下的蠕变速率，最终答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用阿伦尼乌斯公式和蠕变速率与温度的关系进行综合分析，思维过程有一定深度要求。 | 难度: 在选择题中属于中等偏上难度，需要理解激活能、蠕变速率与温度的关系，并应用阿伦尼乌斯公式进行多步计算。题目涉及多个概念的综合应用和复杂计算过程，但选择题型提供了正确选项，降低了部分难度。" + }, + { + "idx": 3738, + "question": "When a stress of 20000 psi is applied to a material heated to 900^{\\circ} C, rupture occurs in 25000h. If the activation energy for rupture is 35000 cal / mol, determine the rupture time if the temperature is reduced to 800^{\\circ} C.", + "answer": "the rupture time at 800^{\\circ} C is 101660h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及应力、温度、活化能等参数的计算，最终需要得出一个具体的数值结果（rupture time）。答案也是一个具体的数值，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度变化对断裂时间的影响，需要理解激活能的概念并将其应用于实际计算中。虽然计算过程较为直接，但需要正确理解和应用公式，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解应力断裂时间与温度的关系，运用阿伦尼乌斯方程进行多步计算，并正确转换温度单位和能量单位。虽然题目提供了正确选项可以验证结果，但解题过程涉及对数运算和指数计算，需要较强的综合分析能力。" + }, + { + "idx": 3739, + "question": "Using the data in Figure 7-27 for an iron-chromium-nickel alloy, determine the activation energy Q_{r} for rupture in the temperature range 980 to 1090^{\\circ} C.", + "answer": "the activation energy q_{r} is 117,000 \text{ cal/mol}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表数据计算激活能Q_{r}，需要应用公式和进行数值计算，答案是一个具体的数值结果(117,000 cal/mol)，这些都是计算题的典型特征。 | 知识层次: 题目需要从图表中提取数据，并应用相关公式计算激活能，涉及多步计算和温度范围的选择，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解材料科学中的活化能概念，能够正确解读图表数据，并进行多步计算。虽然题目提供了正确选项，但解题过程涉及温度范围的选择、数据点的提取以及活化能公式的应用，需要较强的综合分析能力。" + }, + { + "idx": 3740, + "question": "Using the data in Figure 7-27 for an iron-chromium-nickel alloy, determine the constant m for rupture in the temperature range 980 to 1090^{\\circ} C.", + "answer": "the constant m for rupture is 3.9.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据（Figure 7-27）在特定温度范围内确定常数m的值，这需要进行数值计算和公式应用。答案是一个具体的数值（3.9），这表明解答过程涉及计算而非选择或判断。 | 知识层次: 题目要求根据图表数据进行断裂常数的计算，需要理解图表信息、应用相关公式，并进行多步计算。虽然不涉及复杂的机理分析或创新应用，但需要一定的综合分析能力和概念关联，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解图表数据并进行多步计算。题目要求从给定的图表中提取数据，并应用相关公式计算常数m，涉及温度范围的选择和综合分析。虽然选择题提供了正确选项，但仍需一定的计算步骤和概念关联能力。" + }, + { + "idx": 3741, + "question": "A 0.25-in.-thick copper plate is to be cold worked 63%. Find the final thickness.", + "answer": " t_{f} = 0.0925 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最终厚度，答案是一个具体的数值结果。 | 知识层次: 题目仅涉及基本的冷加工变形公式应用和简单计算，无需多步推理或综合分析，属于直接套用公式求解的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需应用冷加工变形的基本公式（t_f = t_0 * (1 - %CW/100)）进行一步计算即可得出答案，无需额外的概念理解或复杂步骤。正确选项直接对应计算结果，符合等级1的简单直接要求。" + }, + { + "idx": 3742, + "question": "A 0.25-in.-diameter copper bar is to be cold worked 63%. Find the final diameter.", + "answer": "the final diameter is 0.152 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最终的直径，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的冷加工变形计算，只需要应用简单的公式和一步计算即可得出结果，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用冷加工变形的基本公式进行简单计算，无需多个步骤或公式组合。学生只需掌握单一公式并正确代入数值即可得出答案，属于最基础的难度等级。" + }, + { + "idx": 3743, + "question": "A 2-in.-diameter copper rod is reduced to 1.5 in. diameter, then reduced again to a final diameter of 1 in. In a second case, the 2-in.-diameter rod is reduced in one step from 2 in. to a 1 in. diameter. Calculate the% CW for both cases.", + "answer": "75% in both cases.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种不同加工路径下的% CW（冷加工百分比），答案以具体数值形式给出，属于典型的计算题。 | 知识层次: 题目要求应用冷加工百分比计算公式进行简单计算，虽然涉及多步操作但计算过程直接套用公式即可完成，无需复杂分析或概念关联。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目描述了两种不同的加工步骤，但实际计算只需要套用冷加工百分比（%CW）的基本公式，且两种情况的计算过程相同，最终结果也一致。不需要复杂的分析或多步骤推导，属于直接套用公式的简单应用层次。" + }, + { + "idx": 3744, + "question": "Suppose that liquid nickel is undercooled until homogeneous nucleation occurs. Calculate the critical radius of the nucleus required. Assume that the lattice parameter of the solid FCC nickel is 0.356 nm.", + "answer": "the critical radius of the nucleus required is 6.65 × 10^-8 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界核半径，答案是一个具体的数值结果（6.65 × 10^-8 cm），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括临界半径公式的应用和单位转换，涉及对均相成核理论的理解和数值计算能力，但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解均匀成核理论、临界半径计算公式（涉及表面自由能、体积自由能变化等概念），并能正确代入FCC镍的晶格参数进行多步单位换算和计算。虽然题目提供了正确选项减少了推导步骤，但仍需要综合应用材料科学和热力学知识才能准确求解。" + }, + { + "idx": 3745, + "question": "Suppose that liquid nickel is undercooled until homogeneous nucleation occurs. Calculate the number of nickel atoms in the nucleus. Assume that the lattice parameter of the solid FCC nickel is 0.356 nm.", + "answer": "the number of nickel atoms in the nucleus is 109 atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算镍原子在核中的数量），并给出了具体的参数（FCC镍的晶格参数），答案也是一个具体的数值（109 atoms），符合计算题的特征。 | 知识层次: 题目需要应用均质形核理论，结合FCC晶体的晶格参数计算原子数，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解均匀成核、晶格参数、FCC结构等概念，并进行多步计算（如计算晶胞体积、原子数等）。虽然题目提供了正确选项，但解题过程涉及多个知识点的综合应用和计算步骤，对学生的理解能力和计算能力有一定要求。" + }, + { + "idx": 3746, + "question": "Suppose that liquid iron is undercooled until homogeneous nucleation occurs. Calculate the critical radius of the nucleus required. Assume that the lattice parameter of the solid BCC iron is 2.92 Å.", + "answer": "10.128 × 10⁻⁸ cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算临界核半径），并给出了具体的数值答案，这符合计算题的特征。 | 知识层次: 题目需要应用均相成核理论中的临界半径计算公式，涉及多步计算和概念关联（如晶格参数与临界半径的关系），但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解均匀成核、临界半径计算等概念，并进行多步骤的计算和综合分析。虽然题目给出了部分参数，但仍需考生掌握相关公式和单位转换，属于综合性计算问题。" + }, + { + "idx": 3747, + "question": "Suppose that liquid iron is undercooled until homogeneous nucleation occurs. Calculate the number of iron atoms in the nucleus. Assume that the lattice parameter of the solid BCC iron is 2.92 Å.", + "answer": "350 atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铁原子在核中的数量），并给出了具体的参数（BCC铁的晶格参数为2.92 Å），最终答案是一个具体的数值（350 atoms），这些都是计算题的典型特征。 | 知识层次: 题目需要进行多步计算，包括计算晶胞体积、每个晶胞中的原子数、核的体积以及最终的原子数。这需要理解BCC结构的基本概念，并能将这些概念应用于具体的数值计算中。虽然不涉及复杂的推理或综合分析，但需要一定的概念关联和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解均匀成核的概念，掌握BCC晶体结构的原子计算方法，并进行多步计算（包括晶胞体积、原子数、临界核尺寸等）。虽然题目提供了关键参数（晶格常数），但需要综合运用材料科学和数学知识才能得出正确选项。" + }, + { + "idx": 3748, + "question": "Suppose that solid nickel was able to nucleate homogeneously with an undercooling of only 22^{\\circ} C. How many atoms would have to group together spontaneously for this to occur? Assume that the lattice parameter of the solid FCC nickel is 0.356nm.", + "answer": "1.136 × 10^{6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，要求计算自发聚集的原子数量，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括使用均质形核理论中的临界形核功公式，并结合FCC晶体的晶格参数计算单个原子的体积，进而求出临界形核尺寸所需的原子数。这涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算。题目涉及均相成核、晶格参数、原子数量计算等概念，需要综合运用材料科学知识。虽然题目给出了晶格参数，但需要学生自行推导计算步骤，包括体积计算、原子密度计算以及临界核尺寸的关联计算。这种多步骤的综合性计算在选择题中属于较高要求，但尚未达到复杂多变量计算的最高难度。" + }, + { + "idx": 3749, + "question": "Suppose that solid iron was able to nucleate homogeneously with an undercooling of only 15^{\\circ} C. How many atoms would have to group together spontaneously for this to occur? Assume that the lattice parameter of the solid BCC iron is 2.92 Å.", + "answer": "7.676 × 10^{6} atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定过冷度下铁原子自发成核所需的原子数量。答案是一个具体的数值结果，这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解均相成核的概念、应用临界核尺寸公式、计算晶胞体积和原子数，并最终求解所需原子数。这需要将多个概念和公式关联起来，进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解均质成核理论、晶体结构参数、临界核尺寸计算等多个概念，并进行多步骤的综合计算。题目要求将理论公式（如临界核自由能公式）与给定参数（如晶格常数、过冷度）结合，最终推导出原子数量，涉及较复杂的数学运算和单位转换过程。" + }, + { + "idx": 3750, + "question": "Calculate the fraction of solidification that occurs dendritically when iron nucleates at 10 degrees Celsius undercooling. The specific heat of iron is 5.78 J/cm^3·°C.", + "answer": "0.0333", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铁在10度过冷度下发生枝晶凝固的分数），并且答案是一个具体的数值（0.0333），这表明需要通过公式和给定的参数（铁的比热容）进行计算得出结果。 | 知识层次: 题目需要进行多步计算，涉及固相分数和过冷度的概念关联，需要综合分析热力学参数（如比热容）来计算枝晶凝固分数，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解过冷度与凝固分数的关系，并应用比热容数据进行多步计算。虽然题目提供了具体参数，但解题过程涉及热力学概念的综合应用和单位换算，对学生的计算能力和概念关联能力有一定要求。" + }, + { + "idx": 3752, + "question": "Calculate the fraction of solidification that occurs dendritically when iron nucleates homogeneously. The specific heat of iron is 5.78 J/cm^3·°C.", + "answer": "all dendritically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释铁均匀成核时枝晶凝固的比例，答案需要文字解释而非计算或选择 | 知识层次: 题目主要考查对凝固过程中枝晶形成这一基本概念的理解和记忆，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆基本原理（铁均匀形核时全部以枝晶方式凝固），无需复杂分析或计算步骤。正确选项直接对应基础概念记忆层次，属于最简单的选择题难度等级。" + }, + { + "idx": 3753, + "question": "Calculate the fraction of solidification that occurs dendritically when silver nucleates at 10 degrees Celsius undercooling. The specific heat of silver is 3.25 J/cm^3·°C.", + "answer": "0.0237", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算银在10度过冷度下发生枝晶凝固的分数），需要使用给定的热容数据进行公式应用，最终给出一个具体的数值答案（0.0237）。 | 知识层次: 题目需要进行多步计算，涉及固相分数计算和热力学参数的应用，需要理解过冷度与凝固行为的关系，并正确运用比热容等参数进行计算。虽然不涉及复杂的机理分析或创新设计，但比简单套用公式更复杂，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解过冷度、比热容等概念，并进行多步计算（包括能量平衡和相变分数的推导）。虽然题目提供了具体参数，但解题过程涉及公式转换和单位统一，对学生的综合计算能力和概念关联能力有一定要求。" + }, + { + "idx": 3755, + "question": "Calculate the fraction of solidification that occurs dendritically when silver nucleates homogeneously. The specific heat of silver is 3.25 J/cm^3·°C.", + "answer": "0.842", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算银凝固时枝晶形成的比例），并且答案是一个具体的数值（0.842），这符合计算题的特征。解答过程需要应用材料科学中的相关公式和参数（如银的比热容）。 | 知识层次: 题目需要进行多步计算，涉及凝固分数和均质形核的概念关联，需要综合分析热力学参数和凝固行为，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解固相分数计算、均质形核等概念，并正确应用比热容数据进行多步计算。虽然题目提供了关键参数，但解题过程涉及热力学公式转换和综合分析能力，属于需要概念关联和计算验证的题型。" + }, + { + "idx": 3756, + "question": "A 2-in. cube solidifies in 4.6 min. Calculate (a) the mold constant in Chvorinov's rule. Assume that n=2.", + "answer": "the mold constant in chvorinov's rule is 41.48 min/in^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Chvorinov's rule）来求解模具常数，答案是一个具体的数值结果（41.48 min/in^2），符合计算题的特征。 | 知识层次: 题目要求直接套用Chvorinov's rule公式进行计算，属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用Chvorinov's rule的基本公式进行计算，属于单一公式直接计算的简单应用。解题步骤简单，仅需代入已知数值进行简单运算即可得出答案，无需复杂的分析或组合多个公式。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3757, + "question": "A 2-in. cube solidifies in 4.6 min. Calculate (b) the solidification time for a 0.5 in. x 0.5 in. x 6 in. bar cast under the same conditions. Assume that n=2.", + "answer": "the solidification time for the bar is 0.60 min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算凝固时间），并给出了具体的公式参数（n=2），最终答案是一个具体的数值结果（0.60 min），这些都是计算题的典型特征。 | 知识层次: 题目涉及基本公式的应用和简单计算，需要根据给定的条件和公式直接计算固结时间，不需要多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目要求应用基本公式（Chvorinov's rule）进行简单计算，仅需一步转换和代入，无需复杂分析或多公式组合。" + }, + { + "idx": 3758, + "question": "A 5-cm diameter sphere solidifies in 1050s. Calculate the solidification time for a 0.3 cm × 10 cm × 20 cm plate cast under the same conditions. Assume that n=2.", + "answer": "the solidification time for the plate is 31.15s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解固结时间，答案是一个具体的数值结果，解答过程需要运用材料科学中的相关公式和计算步骤。 | 知识层次: 题目需要进行多步计算，涉及固体凝固时间的公式应用和不同几何形状的转换，需要理解凝固时间与体积/表面积比的关系，并正确应用n=2的条件进行计算。虽然不涉及复杂的机理分析，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解凝固时间计算的基本概念（如Chvorinov法则），并能正确应用n=2的假设。题目涉及从球体到平板几何形状的转换计算，需要多步骤推导（包括等效模数计算和比例关系应用），但选择题型提供了正确选项，降低了部分计算验证的复杂度。" + }, + { + "idx": 3759, + "question": "Calculate the diameter of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the diameter of the riser d ≥ 6.67 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的直径），并给出了具体的公式应用（H/D比例），最终答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及铸造工艺中缩孔预防的圆柱形冒口设计，需要应用H/D比和体积关系等概念进行综合分析，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解铸造收缩原理、冒口设计公式（H/D比）并进行多步计算。题目要求将几何参数转换为数学关系式，并综合判断最小直径值，涉及中等应用层次的知识关联和计算能力。虽然选项已给出正确数值，但解题过程需要综合分析多个变量（铸件尺寸、H/D比、体积补偿关系），在选择题型中属于需要较强计算能力的题目。" + }, + { + "idx": 3760, + "question": "Calculate the height of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the height of the riser h ≥ 10 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的高度），并给出了具体的参数和条件（H/D比为1.5），答案也是一个具体的数值结果（h ≥ 10 in.），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及圆柱形冒口高度与直径比（H/D）的应用，以及防止铸件缩孔的计算。虽然公式直接给出，但需要理解并正确应用这些概念和公式来解决问题，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解圆柱形冒口高度与直径比（H/D）的概念，并将该比例关系应用于具体尺寸计算。题目要求进行多步计算（根据H/D=1.5推导冒口直径与高度的关系），并需要综合分析铸造收缩预防的条件。虽然题目给出了具体尺寸简化了部分计算，但仍需正确应用工程原理并执行单位换算，这比单纯的概念选择题更具挑战性。" + }, + { + "idx": 3761, + "question": "Calculate the volume of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the volume of the riser v ≥ 349 in.^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的体积），并给出了具体的参数（H/D比例和铸件尺寸），答案也是一个具体的数值结果（349 in.^3），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解圆柱形冒口的体积计算、H/D比的应用以及防止收缩的条件分析。虽然计算本身不复杂，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解圆柱形冒口的设计原理（H/D比）、体积计算公式，并能够将铸造收缩预防需求转化为具体计算步骤。题目要求进行多步计算（确定冒口直径与高度的关系、计算体积），并需要将理论知识与工程实践（防缩需求）相结合，但作为选择题型，正确答案的选项降低了部分推导难度。" + }, + { + "idx": 3762, + "question": "Calculate the diameter of the cylindrical riser required to prevent shrinkage in a 1 in. x 6 in. x 6 in. casting if the H/D of the riser is 1.0.", + "answer": "the diameter of the riser must be at least 2.25 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定圆柱形冒口的直径，答案是一个具体的数值（2.25 in.），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解铸造收缩原理、应用H/D比例关系以及计算圆柱形冒口的直径，涉及概念关联和综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的计算步骤和概念理解。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求计算圆柱形冒口的直径以防止收缩，涉及多步计算和概念关联（如H/D比、冒口尺寸与铸件尺寸的关系）。虽然题目提供了具体参数和正确选项，但解题过程需要综合运用材料科学和铸造工艺知识，属于中等应用层次的问题。" + }, + { + "idx": 3763, + "question": "Calculate the height of the cylindrical riser required to prevent shrinkage in a 1 in. x 6 in. x 6 in. casting if the H/D of the riser is 1.0.", + "answer": "the height of the riser must be at least 2.25 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的高度），并给出了具体的尺寸条件和比例要求（H/D=1.0），最终答案是一个具体的数值（2.25 in）。这符合计算题的特征，即需要应用公式和进行数值计算来解决问题。 | 知识层次: 题目涉及基本的公式应用和简单计算，需要根据给定的H/D比例和铸件尺寸计算冒口高度，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，需要基本公式应用和简单计算。虽然涉及H/D比的概念，但解题步骤相对直接，只需套用给定比例进行计算即可。相比等级1的直接计算，此题需要理解H/D比的含义，因此属于等级2。" + }, + { + "idx": 3764, + "question": "Calculate the volume of the cylindrical riser required to prevent shrinkage in a 1 in. x 6 in. x 6 in. casting if the H/D of the riser is 1.0.", + "answer": "the volume of the riser must be at least 8.95 in^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的体积），并且答案是一个具体的数值结果（8.95 in^3），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解铸造收缩的原理、计算铸件的体积以及确定冒口的尺寸比例（H/D=1.0），并应用相关公式计算冒口的体积。这需要概念关联和综合分析能力，而不仅仅是简单的公式套用或基础概念记忆。 | 难度: 在选择题中属于中等偏上难度，需要理解圆柱形冒口的设计原理（H/D比）、体积计算与铸件收缩补偿之间的关系。题目要求进行多步计算（确定冒口尺寸、计算体积）并综合判断冒口体积是否满足铸件补缩需求，涉及中等应用层次的知识关联和综合分析能力。虽然题目提供了H/D比简化了部分计算，但仍需正确应用几何公式和工程判断，在选择题型中属于需要一定计算和推理能力的题目。" + }, + { + "idx": 3765, + "question": "A 4-in-diameter sphere of liquid copper is allowed to solidify, producing a spherical shrinkage cavity in the center of the casting. Determine the volume and diameter of the shrinkage cavity in the copper casting.", + "answer": "shrinkage volume: 1.709 in.^{3}; diameter of shrinkage cavity: 1.30 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定收缩腔的体积和直径，答案给出了具体的数值结果，解答过程需要应用材料科学中的相关公式和计算步骤。 | 知识层次: 题目需要进行多步计算，包括体积计算和直径转换，同时需要理解铜凝固过程中的收缩现象及其对铸件的影响。虽然不涉及复杂的机理分析或创新设计，但需要综合运用材料科学中的基本概念和公式进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解铜凝固过程中的收缩原理，掌握体积收缩率的计算，并能正确应用球体体积公式进行多步推导。虽然题目提供了正确选项减少了计算量，但仍需综合分析材料特性和几何关系才能准确匹配答案。" + }, + { + "idx": 3766, + "question": "A 4-in-diameter sphere of liquid iron is allowed to solidify, producing a spherical shrinkage cavity in the center of the casting. Determine the volume and diameter of the shrinkage cavity in the iron casting.", + "answer": "shrinkage volume: 1.139 in.^{3}; diameter of shrinkage cavity: 1.30 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定体积和直径，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本的体积计算和公式应用，需要理解收缩现象并应用简单的几何公式进行计算，属于直接套用基本公式的简单应用层次。 | 难度: 在选择题中属于简单难度，仅需应用基本公式（体积计算和直径转换）并进行简单计算，无需多个公式组合或复杂分析。" + }, + { + "idx": 3767, + "question": "A 4-in. cube of a liquid metal is allowed to solidify. A spherical shrinkage cavity with a diameter of 1.49 in. is observed in the solid casting. Determine the percent volume change that occurs during solidification.", + "answer": "the percent volume change that occurs during solidification is 2.7%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定凝固过程中的体积变化百分比，答案是一个具体的数值结果（2.7%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算立方体和球体的体积，并应用体积变化的百分比公式。虽然不涉及复杂的综合分析或推理，但需要理解体积变化的概念并进行关联计算。 | 难度: 在选择题中属于中等难度，需要理解体积变化的概念，进行多步计算（包括立方体和球体的体积计算、百分比变化计算），并综合分析结果。虽然题目提供了正确选项，但解题过程涉及多个步骤和概念关联，对学生的应用能力有一定要求。" + }, + { + "idx": 3768, + "question": "A 2 cm x 4 cm x 6 cm magnesium casting is produced. After cooling to room temperature, what is the volume of the shrinkage cavity at the center of the casting?", + "answer": "the volume of the shrinkage cavity at the center of the casting is 46.03 cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算镁铸件冷却至室温后中心缩孔的体积，需要通过数值计算和公式应用来得出具体数值（46.03 cm³），属于典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括理解镁合金的收缩率、计算初始体积和最终体积，以及应用相关公式来确定收缩腔的体积。这需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解镁合金铸造收缩率的概念，进行多步体积计算（初始体积计算、收缩率应用、收缩腔体积计算），并综合分析材料特性与工艺参数的关系。虽然题目提供了正确选项，但解题过程涉及多个关联概念和计算步骤，超出了基础选择题的范畴。" + }, + { + "idx": 3769, + "question": "A 2 cm x 4 cm x 6 cm magnesium casting is produced. After cooling to room temperature, what is the percent shrinkage that must have occurred during solidification?", + "answer": "the percent shrinkage that must have occurred during solidification is 4.1%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算得出具体的百分比收缩率，需要应用相关公式和计算方法，答案是一个具体的数值结果。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及镁合金凝固收缩率的简单计算，不需要多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需要应用基本的收缩率计算公式，并进行简单的数值代入和计算。不需要多个公式组合或复杂的分析步骤，属于最基础的应用题类型。" + }, + { + "idx": 3770, + "question": "A 2 in. × 8 in. × 10 in. iron casting is produced and, after cooling to room temperature, is found to weigh 43.9 lb. Determine the percent shrinkage that must have occurred during solidification.", + "answer": "The percent shrinkage that must have occurred during solidification is 3.4%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算收缩百分比）并应用相关公式，答案是一个具体的数值结果（3.4%），符合计算题的特征。 | 知识层次: 题目涉及基本的数值计算和公式应用，需要计算铁铸件的体积和密度，然后应用简单的百分比公式来确定收缩率。虽然需要一定的理解和计算能力，但整个过程是直接的，不需要多步计算或复杂的概念关联。 | 难度: 在选择题中属于简单应用难度，需要应用基本公式（密度计算和百分比变化）并进行简单计算，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 3771, + "question": "A 2 in. × 8 in. × 10 in. iron casting is produced and, after cooling to room temperature, is found to weigh 43.9 lb. Determine the number of shrinkage pores in the casting if all of the shrinkage occurs as pores with a diameter of 0.05 in.", + "answer": "The number of shrinkage pores in the casting is 83,354 pores.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定收缩孔的数量。答案是一个具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括体积计算、密度应用、孔隙体积计算和数量估算，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要以下综合分析能力：" + }, + { + "idx": 3772, + "question": "Liquid magnesium is poured into a 2 cm × 2 cm × 24 cm mold and, as a result of directional solidification, all of the solidification shrinkage occurs along the length of the casting. Determine the length of the casting immediately after solidification is completed.", + "answer": "the length of the casting immediately after solidification is completed is 23.04 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定铸件凝固后的长度。答案是一个具体的数值结果，表明需要通过计算得出。 | 知识层次: 题目涉及基本的体积收缩计算和简单的公式应用，不需要多步计算或复杂的概念关联，属于直接套用基本知识的简单应用。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（收缩率计算）并进行简单计算即可得出答案。题目明确给出了所有必要的信息，且解题步骤非常直接，无需组合多个公式或进行复杂分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3773, + "question": "A liquid cast iron has a density of 7.65 g/cm3. Immediately after solidification, the density of the solid cast iron is found to be 7.71 g/cm3. Determine the percent volume change that occurs during solidification.", + "answer": "the percent volume change during solidification is 0.77%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定凝固过程中的体积变化百分比，答案是一个具体的数值结果。 | 知识层次: 题目需要进行简单的密度计算和百分比变化计算，属于基本公式的直接应用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用密度和体积变化的基本公式进行计算，属于单一公式直接计算的简单题目。解题步骤简单明了，只需套用公式并代入已知数值即可得出答案，无需复杂的分析或多步骤推理。" + }, + { + "idx": 3774, + "question": "Does the cast iron expand or contract during solidification?", + "answer": "the cast iron contracts during solidification.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（cast iron在凝固过程中是膨胀还是收缩），答案直接给出了对错判断（contracts during solidification） | 知识层次: 题目考查对铸铁凝固过程中体积变化这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，仅需判断铸铁在凝固过程中是膨胀还是收缩这一简单事实。在选择题型中，这属于最基本的概念正误判断，不需要复杂的理解或分析过程，因此属于等级1难度。" + }, + { + "idx": 3775, + "question": "The solubility of hydrogen in liquid aluminum at 715^{\\circ} C is found to be 1 cm^{3} / 100g \\mathrm{Al}. If all of this hydrogen precipitated as gas bubbles during solidification and remained trapped in the casting, calculate the volume percent gas in the solid aluminum.", + "answer": "2.699%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定氢在固态铝中的体积百分比。答案是一个具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算和单位转换，涉及溶解度概念的应用和体积百分比的计算，需要综合分析能力但不需要复杂的推理或创新思维。 | 难度: 在选择题中属于中等偏上难度，需要理解溶解度概念、单位换算、气体体积百分比计算等多个步骤，并进行综合分析计算。虽然题目提供了关键数据，但解题过程涉及多个转换环节（如从溶解度到体积百分比的计算），需要考生具备较强的应用能力和计算准确性。" + }, + { + "idx": 3776, + "question": "Based on Hume-Rothery's conditions, would the system Au-Ag be expected to display unlimited solid solubility? Explain.", + "answer": "Yes", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件进行解释说明，答案需要文字论述而非简单选择或判断 | 知识层次: 题目要求基于Hume-Rothery规则分析Au-Ag体系的固溶度问题，需要理解并应用多个条件（原子尺寸、电负性、价电子数、晶体结构）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸差、电负性、价电子浓度和晶体结构），并将这些概念应用于Au-Ag系统进行综合分析。虽然题目给出了正确选项，但学生仍需掌握这些概念并能够进行关联分析才能正确回答。" + }, + { + "idx": 3777, + "question": "Based on Hume-Rothery's conditions, would the system Al-Cu be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么Al-Cu系统不会显示无限固溶体，需要基于Hume-Rothery条件进行文字解释和论述，而不仅仅是简单的选择或判断。答案\"No\"只是结论的一部分，完整的回答需要详细的解释。 | 知识层次: 题目要求应用Hume-Rothery规则来分析Al-Cu系统的固溶度，需要理解并应用多个条件（如原子尺寸、电负性、价电子浓度等）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸、电负性、价电子浓度和晶体结构等），并将这些概念应用到Al-Cu系统中进行分析判断。虽然不需要多步计算，但需要综合多个因素才能得出正确结论。" + }, + { + "idx": 3778, + "question": "Based on Hume-Rothery's conditions, would the system Al-Au be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery规则解释Al-Au系统是否具有无限固溶度，需要文字解释和论述，而不仅仅是简单的选择或判断。虽然答案给出了\"No\"，但完整的回答需要解释为什么不符合Hume-Rothery条件。 | 知识层次: 题目要求应用Hume-Rothery规则来分析Al-Au系统的固溶度问题，需要理解并应用多个条件（如原子尺寸差、电负性、价电子浓度等）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸差、电负性、价电子浓度等），并将这些概念综合应用到Al-Au体系中进行分析判断。虽然题目给出了正确选项，但解题过程需要多步概念关联和综合分析，比单纯记忆性题目难度更高。" + }, + { + "idx": 3779, + "question": "Based on Hume-Rothery's conditions, would the system U-W be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件进行解释说明，答案需要文字论述而非简单选择或判断 | 知识层次: 题目要求应用Hume-Rothery规则分析具体合金系统(U-W)的固溶度问题，需要理解并关联多个条件(原子尺寸差、电负性、价电子浓度、晶体结构)，属于中等难度的概念应用和分析。虽然不涉及复杂计算，但需要对规则进行综合判断和解释说明。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸、电负性、价电子浓度和晶体结构等），并将这些概念应用于U-W系统的分析中。虽然题目给出了正确选项，但解答过程需要综合判断多个因素，并进行概念关联和综合分析。" + }, + { + "idx": 3780, + "question": "Based on Hume-Rothery's conditions, would the system Mo-Ta be expected to display unlimited solid solubility? Explain.", + "answer": "Yes", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件解释Mo-Ta系统是否显示无限固溶性，需要文字解释和论述，而不仅仅是简单的选择或判断。答案\"Yes\"只是结论部分，完整的解答还需要解释为什么符合Hume-Rothery条件。 | 知识层次: 题目要求基于Hume-Rothery规则分析Mo-Ta系统的固溶度，需要理解并应用多个条件（如原子尺寸、电负性、价电子浓度等）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸差、晶体结构、电负性和价电子浓度），并将这些概念应用于Mo-Ta体系的分析。虽然不需要复杂的计算，但需要对概念有较深的理解和综合应用能力。" + }, + { + "idx": 3781, + "question": "Based on Hume-Rothery's conditions, would the system Nb-W be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件进行解释说明，答案需要文字论述而非简单选择或判断，符合简答题的特征 | 知识层次: 题目要求基于Hume-Rothery规则分析Nb-W体系的固溶度问题，需要理解并应用多个条件（原子尺寸、电负性、价电子浓度、晶体结构）进行综合分析，属于中等应用层次。虽然不涉及复杂计算，但需要对多个概念进行关联判断。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸、电负性、晶体结构等），并将这些概念应用于Nb-W系统的分析。虽然题目给出了正确选项，但学生仍需进行多步概念关联和综合分析才能得出正确结论。" + }, + { + "idx": 3782, + "question": "Based on Hume-Rothery's conditions, would the system Mg-Zn be expected to display unlimited solid solubility? Explain.", + "answer": "No", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件解释Mg-Zn系统是否显示无限固溶性，需要文字解释和论述，而不仅仅是选择或判断对错。答案\"No\"只是结论部分，完整的回答需要解释原因。 | 知识层次: 题目要求应用Hume-Rothery规则分析Mg-Zn体系的固溶度问题，需要理解并应用多个条件（原子尺寸、电负性、价电子浓度、晶体结构）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸、电负性、价电子浓度等），并将这些概念应用于Mg-Zn体系的分析。虽然不需要进行复杂的计算，但需要对材料科学中的固溶度概念有较好的理解，并能综合判断这些因素对固溶度的影响。" + }, + { + "idx": 3783, + "question": "Based on Hume-Rothery's conditions, would the system Mg-Cd be expected to display unlimited solid solubility? Explain.", + "answer": "Yes", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件解释Mg-Cd系统是否显示无限固溶度，需要文字解释和论述，而不仅仅是选择或判断对错。答案\"Yes\"只是结论的一部分，完整的回答还需要解释原因。 | 知识层次: 题目要求基于Hume-Rothery规则分析Mg-Cd系统的固溶度问题，需要理解并应用多个条件（如原子尺寸、电负性、晶体结构等）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸差、电负性、价电子浓度等），并将这些概念综合应用到Mg-Cd体系中进行分析判断。虽然题目给出了正确选项，但解答过程需要多步概念关联和综合分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 3784, + "question": "Suppose 1 at% of the following elements is added to copper (forming a separate alloy with each element) without exceeding the solubility limit. Which one would be expected to give the higher strength alloy? For copper: r_Cu=1.278 Å (a) Au: r=1.442, φr=+12.8% (b) Mn: r=1.12, φr=-12.4% (c) Sr: r=2.151, φr=+68.3% (d) Si: r=1.176, φr=-8.0% (e) Co: r=1.253, φr=-2.0%", + "answer": "The Cu-Sr alloy would be expected to be strongest (largest size difference).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择一个能产生更高强度合金的元素，答案也是从给定的选项中选择一个正确答案。 | 知识层次: 题目需要理解固溶强化原理，分析不同溶质原子对铜基体强度的影响，综合考虑原子半径差异和电子结构因素，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。题目要求考生不仅理解固溶强化的基本原理（原子半径差异对强度的影响），还需要综合分析多个元素的原子半径差异（φr值）及其对铜合金强度的潜在影响。解题步骤涉及比较多个选项的数值差异，并选择最符合理论预期的选项。虽然题目提供了具体数据，但需要考生进行多步概念关联和综合分析，才能正确判断哪个元素会导致最高的强度提升。这超出了简单记忆或单一概念应用的范畴，属于中等偏上的选择题难度。" + }, + { + "idx": 3785, + "question": "Is any of the alloying elements expected to have unlimited solid solubility in copper? For copper: r_Cu=1.278 Å (a) Au: r=1.442, φr=+12.8% (b) Mn: r=1.12, φr=-12.4% (c) Sr: r=2.151, φr=+68.3% (d) Si: r=1.176, φr=-8.0% (e) Co: r=1.253, φr=-2.0%", + "answer": "The Cu-Au alloy satisfies Hume-Rothery's conditions and might be expected to display complete solid solubility-in fact it freezes like an isomorphous series of alloys, but a number of solid-state transformations occur at lower temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择哪个合金元素在铜中具有无限固溶度，答案也明确指出了符合Hume-Rothery条件的选项 | 知识层次: 题目需要应用Hume-Rothery规则（包括原子半径差、电负性、价电子浓度等）来分析合金元素在铜中的固溶度，涉及多步判断和综合分析。虽然规则本身是基础概念，但需要将多个条件结合起来进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。题目要求考生不仅掌握Hume-Rothery规则的基本概念（如原子半径差、电负性、价电子浓度等），还需要能够将这些规则应用到具体的合金系统中（Cu-Au）。此外，题目还涉及对多个选项的分析和比较，需要考生进行多步计算（如原子半径差百分比的计算）和综合判断。虽然题目提供了具体数据，但要求考生能够将这些数据与理论规则关联起来，并做出正确的判断。因此，该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 3786, + "question": "Suppose 1 at% of the following elements is added to copper (forming a separate alloy with each element) without exceeding the solubility limit. Which one would be expected to give the higher strength alloy? (a) Au (b) Mn (c) Sr (d) Si (e) Co", + "answer": "(c)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项（a-e）中选择一个预期能提供更高强度合金的元素，符合选择题的特征。 | 知识层次: 题目要求考生理解合金元素对铜强度的影响，并能够比较不同元素的强化效果。这需要考生掌握固溶强化的基本原理，并能够将不同元素的特性（如原子尺寸、电负性等）与强化效果联系起来。虽然不涉及复杂的计算或多步骤推理，但需要对概念进行综合应用和分析。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。需要考生：" + }, + { + "idx": 3787, + "question": "Which of these alloying elements is expected to have unlimited solid solubility in copper? (a) Au (b) Mn (c) Sr (d) Si (e) Co", + "answer": "(a)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案，具有明确的选择项和单一正确答案特征 | 知识层次: 题目考查对固溶度概念的理解以及合金元素与铜的相互作用，需要综合分析原子尺寸、电负性、晶体结构等因素来判断固溶度，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要综合运用材料科学中的固溶度概念、Hume-Rothery规则以及元素周期表知识。解题过程涉及多步分析：1) 理解铜的晶体结构(FCC) 2) 掌握Hume-Rothery规则的四个条件(原子尺寸差、电负性、价电子数、晶体结构) 3) 对各选项元素进行系统比较。特别是需要判断金(Au)与铜的相似性，这需要较深入的材料学知识而非简单记忆。虽然题目形式是选择题，但解题所需的综合分析过程使其难度高于基础概念题。" + }, + { + "idx": 3788, + "question": "Which of the following oxides is expected to have the largest solid solubility in \\mathrm{Al}_{2} \\mathrm{O}_{3} ?\n(a) \\mathrm{Y}_{2} \\mathrm{O}_{3} (b) \\mathrm{Cr}_{2} \\mathrm{O}_{3} (c) \\mathrm{Fe}_{2} \\mathrm{O}_{3}", + "answer": "\\mathrm{cr}_{2} \\mathrm{o}_{3} is expected to have the largest solid solubility in \\mathrm{al}_{2} \\mathrm{o}_{3}; in fact, they are completely soluble in one another.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择具有最大固溶度的氧化物，符合选择题的特征 | 知识层次: 题目需要理解氧化物在Al2O3中的固溶度原理，并分析不同氧化物的离子半径、电荷匹配等因素，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合考虑氧化物晶体结构、离子半径匹配性以及固溶度原理等多个材料科学概念。题目要求判断哪种氧化物在Al₂O₃中具有最大固溶度，这涉及对离子价态匹配（都是+3价氧化物）、离子半径相近性（Cr³⁰与Al³⁺半径最接近）以及晶体结构相容性的综合分析。虽然不涉及计算，但需要运用Hume-Rothery规则等固溶度理论进行多因素判断，比单纯记忆性选择题更具挑战性。" + }, + { + "idx": 3789, + "question": "How many grams of nickel must be added to 500 grams of copper to produce an\nalloy that contains 50 wt% \\alpha at 1300^{\\circ} C ?", + "answer": "541.7g ni", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算需要添加的镍的质量），并应用相关的合金成分计算公式。答案是一个具体的数值（541.7g），这表明解答过程涉及计算步骤而非选择或判断。 | 知识层次: 题目需要进行多步计算，涉及合金成分计算和相图应用，需要理解wt%的概念并正确应用相关公式。虽然不涉及复杂的机理分析，但需要综合分析题目给出的条件并进行适当的数值计算。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、质量百分比计算，并进行多步综合计算。虽然题目给出了正确选项降低了猜测难度，但仍需掌握合金成分计算和相图解读能力，步骤涉及单位转换和代数求解，属于综合性计算问题。" + }, + { + "idx": 3790, + "question": "How many grams of MgO must be added to 1kg of NiO to produce a ceramic that has a solidus temperature of 2200^{\\circ} C ?", + "answer": "332g of mgo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算MgO的质量），并应用相关公式（如相图或化学计量关系）来求解，最终给出具体的数值答案（332g of MgO）。 | 知识层次: 题目需要进行多步计算，涉及固相线温度与成分关系的理解，需要查阅相图并应用杠杆定律进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求考生：" + }, + { + "idx": 3791, + "question": "We would like to produce a MgO-\\mathrm{FeO} ceramic that is 30 wt% solid at 2000^{\\circ} C. Determine the original composition of the ceramic in wt%.", + "answer": "56.9 wt% feo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定陶瓷的原始组成（wt%），需要应用相关公式和计算方法，最终给出具体的数值答案（56.9 wt% FeO）。 | 知识层次: 题目需要进行多步计算，涉及相图分析和成分计算，需要理解相图的基本原理并应用相关公式进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求根据给定温度下的固相比例反推原始成分，涉及相图解读、杠杆定律应用和成分转换计算。虽然选择题提供了正确选项降低了部分难度，但仍需要综合分析能力和准确的计算步骤。" + }, + { + "idx": 3792, + "question": "A Nb-W alloy held at 2800°C is partly liquid and partly solid. If possible, determine the composition of each phase in the alloy.", + "answer": "l: 49% w; α: 70% w", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定合金中各相的组成，需要根据相图或相关理论进行分析和解释，答案以文字形式给出各相的组成百分比，属于需要简要回答和解释的题型。 | 知识层次: 题目需要根据相图确定合金在特定温度下的相组成，涉及多步计算和概念关联，需要综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及多步计算和概念关联，要求考生能够理解并应用相图知识来确定合金在不同相中的组成。其次，题目要求综合分析部分液体和部分固体的组成，这需要考生具备较强的逻辑推理能力和计算能力。此外，题目中的温度（2800°C）和组成（Nb-W合金）增加了题目的复杂性，考生需要准确理解相图并正确提取信息。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 3794, + "question": "A Nb-W alloy contains 55% α at 2600°C. Determine the composition of each phase.", + "answer": "l: 22% w; α: 42% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定各相的组成，答案给出了具体的数值结果，解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相组成和成分的确定，需要综合分析相图数据和给定的条件，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求确定两相组成，涉及相图解读、杠杆定律应用和百分比计算，属于综合性计算问题。虽然提供了正确选项，但仍需综合分析能力来验证答案的正确性。" + }, + { + "idx": 3795, + "question": "A Nb-W alloy contains 55% α at 2600°C. Determine the original composition of the alloy.", + "answer": "33% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金的原始成分，答案是一个具体的数值（33% w），需要通过计算得出。 | 知识层次: 题目需要进行多步计算，涉及相图分析和成分确定，需要将概念关联并进行综合分析。虽然计算本身不复杂，但需要理解相图的基本原理和成分与相比例的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、进行多步计算（包括杠杆法则应用）和综合分析成分与相变关系。虽然题目提供了关键数据（55% α），但解题过程需要将多个知识点串联起来才能推导出原始成分，这超出了简单记忆或单步计算的范畴。" + }, + { + "idx": 3796, + "question": "Suppose a 1200-lb bath of a Nb-40 wt % W alloy is held at 2800 degrees C. How many pounds of tungsten can be added to the bath before any solid forms?", + "answer": "212 additional pounds of W must be added before any solid forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定需要添加的钨的质量。答案给出了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及合金成分和相图的应用，需要综合分析温度、成分和相变条件之间的关系，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、进行多步计算（包括质量平衡和成分计算），并综合分析温度与成分的关系。虽然题目提供了正确选项减少了干扰项判断，但解题过程仍涉及较复杂的应用能力。" + }, + { + "idx": 3798, + "question": "Suppose a crucible made of pure nickel is used to contain 500g of liquid copper at 1150^{\\circ} C. Describe what happens to the system as it is held at this temperature for several hours. Explain.", + "answer": "cu dissolves ni until the cu contains enough ni that it solidifies completely. when 10% ni is dissolved, freezing begins with x = 55.5 \\text{g ni}. when 18% ni is dissolved, the bath is completely solid with x = 109.8 \\text{g ni}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述和解释系统在特定条件下的变化过程，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求描述和解释在高温下镍坩埚与液态铜之间的相互作用及其随时间的变化过程，涉及溶解、固溶体形成和相变等复杂现象。需要综合运用相图知识、溶解动力学和热力学原理进行分析和推理，属于对材料科学知识的深度理解和综合应用。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解镍和铜的相图关系，还需要进行复杂的质量计算和相变分析。正确选项涉及多个步骤的推理：1) 理解铜溶解镍的机制；2) 计算特定成分下的相变点(10%Ni时开始凝固)；3) 计算完全凝固时的成分(18%Ni)；4) 进行精确的质量计算(55.5g和109.8g Ni)。这些要求远超一般选择题的概念判断或简单计算，需要对相图有深入理解并能进行综合应用分析，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 3799, + "question": "A NiO-60 mol% MgO ceramic is allowed to solidify. Determine the composition of the first solid to form under equilibrium conditions.", + "answer": "80% mgo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定在平衡条件下形成的第一个固体的成分，需要应用相图和相关公式进行数值计算。答案是一个具体的数值（80% mgo），表明需要通过计算得出结果。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及固溶体成分的确定和平衡条件的理解，需要综合分析相图信息并进行数值计算。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算分析。题目要求考生在NiO-MgO二元相图中确定平衡凝固时首晶固相的成分，这需要综合运用杠杆定律和相图解读能力。虽然给出了正确选项减少了部分计算量，但仍需完成相图定位、相区判断和成分计算等步骤，属于典型的综合性计算问题。" + }, + { + "idx": 3800, + "question": "A NiO-60 mol% MgO ceramic is allowed to solidify. Determine the composition of the last liquid to solidify under equilibrium conditions.", + "answer": "35% mgo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定在平衡条件下最后凝固的液体的组成，需要应用相图和相关公式进行数值计算。答案是一个具体的数值（35% MgO），表明需要通过计算得出结果。 | 知识层次: 题目需要理解相图的基本原理，并应用杠杆定律进行多步计算，以确定最后凝固液体的成分。这涉及到概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算分析。题目要求考生在NiO-MgO相图中确定平衡凝固条件下最后凝固液体的成分，这需要综合运用相图知识和杠杆定律进行计算。虽然题目提供了正确选项，但解题过程涉及多个步骤和概念关联，属于综合性计算问题。" + }, + { + "idx": 3801, + "question": "A Nb-35% W alloy is allowed to solidify. Determine the composition of the first solid to form under equilibrium conditions.", + "answer": "55% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定在平衡条件下形成的第一个固体的成分，需要应用相图和相关公式进行数值计算，答案是一个具体的数值（55% w），符合计算题的特征。 | 知识层次: 题目要求根据给定的合金成分和平衡凝固条件，确定第一个固体的组成。这需要应用相图的基本知识和简单的杠杆定律计算，属于基本公式应用和直接套用的范畴。虽然需要理解相图的基本概念，但计算过程相对直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅要求根据给定的合金成分（Nb-35% W）和平衡凝固条件，直接应用相图或杠杆法则确定初始凝固固相的成分（55% W）。解题步骤简单，无需复杂计算或多公式组合，属于单一公式直接计算的范畴。" + }, + { + "idx": 3802, + "question": "A Nb-35% W alloy is allowed to solidify. Determine the composition of the last liquid to solidify under equilibrium conditions.", + "answer": "18% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金在平衡凝固条件下最后凝固液体的成分，需要应用相图和相关公式进行数值计算，答案以具体数值形式给出。 | 知识层次: 题目需要运用相图知识进行多步计算，涉及平衡条件下合金凝固过程中液相成分的变化分析，需要理解相图的基本原理并能够进行相关计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算分析。题目要求考生在Nb-W合金相图中确定最后凝固液体的成分，这需要掌握杠杆定律的应用和相图解读能力。虽然题目提供了正确选项，但解题过程涉及多个步骤的综合计算和概念关联，比单纯记忆或单步计算的选择题更复杂。" + }, + { + "idx": 3803, + "question": "An intermetallic compound is found for 10 wt% \\mathrm{Si} in the Cu-Si phase diagram. Determine the formula for the compound.", + "answer": "\\mathrm{sicu}_{4}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据给定的条件（10 wt% Si in the Cu-Si phase diagram）推导出化合物的化学式，需要一定的分析和解释过程，答案是一个具体的化学式而非简单的选择或判断。 | 知识层次: 题目需要根据相图信息进行多步计算和概念关联，包括理解相图的基本原理、计算原子百分比、推导化合物的化学式等，涉及中等程度的综合分析和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求根据给定的重量百分比计算化合物的化学式，涉及原子量计算和比例转换，属于中等应用层次的多步计算和概念关联。虽然有一定的计算步骤，但在选择题型中，通过选项可以辅助验证，降低了部分难度。" + }, + { + "idx": 3804, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the composition of the first solid to form.", + "answer": "8% Sn", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定合金凝固过程中第一个固体的成分，需要基于相图和合金凝固原理进行解释和论述，答案是一个具体的数值（8% Sn），但解答过程需要文字说明和理论支持。 | 知识层次: 题目需要理解相图的基本原理，并能够根据给定的合金成分在相图上确定初始凝固固相的成分。这涉及到多步的思维过程，包括理解相图、识别相关相区以及应用杠杆定律等概念。虽然不涉及复杂的计算或深度分析，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解相图的基本概念（如液相线和固相线），并能根据给定的合金成分（Pb-15% Sn）在相图上定位，进而确定首先形成的固相成分（8% Sn）。这涉及到对二元相图的理解和应用，但不需要复杂的多步计算或深度关联性分析。" + }, + { + "idx": 3805, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the liquidus temperature, solidus temperature, solvus temperature, and freezing range of the alloy.", + "answer": "liquidus temperature =290 c, solidus temperature =240 c, solvus temperature =170 c, freezing range =50 c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定合金的多个温度参数（liquidus temperature, solidus temperature, solvus temperature, freezing range），答案以具体数值形式给出，解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目要求根据给定的合金成分（Pb-15% Sn）确定其相变温度（liquidus、solidus、solvus）和凝固范围（freezing range），这需要应用相图的基本知识和简单的数值计算。虽然涉及多个温度点的确定，但每个点的计算都是直接基于相图数据，不需要多步计算或复杂的概念关联。因此，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据给定的合金成分（Pb-15% Sn）直接查找或应用相图中的已知数据（liquidus temperature, solidus temperature, solvus temperature, freezing range），无需进行复杂的计算或公式组合。正确选项已经提供了所有需要的数值，学生只需识别并选择正确的对应关系即可。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3806, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the amounts and compositions of each phase at 260 c.", + "answer": "l: 30% sn, α: 12% sn; % l=17%, % α=83%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定各相的含量和组成，答案给出了具体的数值计算结果（% l=17%, % α=83%），这需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律计算以及综合分析能力。题目要求确定特定温度下各相的成分和含量，涉及多步骤计算和概念关联，但选项提供了部分引导，降低了纯粹计算的复杂度。" + }, + { + "idx": 3807, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the amounts and compositions of each phase at 183 c.", + "answer": "α: 15% sn; 100% α", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定在特定温度下各相的数量和组成，这需要通过相图和相关计算来完成。答案给出了具体的数值结果，表明需要进行计算和公式应用。 | 知识层次: 题目要求根据给定的合金成分和温度，通过简单的相图应用和计算确定各相的含量和组成。这属于基本公式应用和直接套用相图知识的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求确定Pb-15% Sn合金在183°C凝固时各相的含量和组成，正确选项直接给出了α相的含量和组成（15% Sn; 100% α）。这只需要学生应用基本的相图知识或杠杆法则进行简单计算，无需复杂的分析或多步骤推理。因此，在选择题型内，该题目属于最低难度等级。" + }, + { + "idx": 3808, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the amounts and compositions of each phase at 25 c.", + "answer": "α: 2% pb, β: 100% sn; % α=87%, % β=13%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定各相的含量和组成，答案给出了具体的数值结果（% α=87%, % β=13%），这需要通过相图计算或杠杆定律等数值计算方法得出。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相的成分和相对量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆法则计算以及成分转换。题目要求确定凝固后的相组成和比例，涉及多步计算和概念关联，但选项已经提供了关键中间步骤的答案，降低了部分复杂性。" + }, + { + "idx": 3809, + "question": "Consider a Pb-35% Sn alloy. Determine if the alloy is hypoeutectic or hypereutectic.", + "answer": "hypoeutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过分析合金成分来判断其类型（hypoeutectic或hypereutectic），需要基于相图知识进行解释和论述，而不是简单的选择或计算。答案虽然简短，但需要理解合金成分与共晶点之间的关系。 | 知识层次: 题目考查对合金分类（hypoeutectic或hypereutectic）的基本概念记忆和理解，仅需根据给定的成分百分比与共晶点比较即可判断，无需复杂计算或分析。 | 难度: 在选择题型中，该题目仅需记忆Pb-Sn合金相图中35% Sn的组成位置相对于共晶点的关系，属于基础定义简答。无需解释或复杂分析，只需识别hypoeutectic的定义即可作答。" + }, + { + "idx": 3810, + "question": "Consider a Pb-35% Sn alloy. Determine the composition of the first solid to form during solidification.", + "answer": "14% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在凝固过程中首先形成的固体的成分。解答需要参考相图和相关公式进行计算，最终得出具体的数值结果（14% Sn）。 | 知识层次: 题目要求根据给定的合金成分（Pb-35% Sn）和相图知识，通过简单的查图和计算确定第一固相形成的成分（14% Sn）。这属于基本公式应用和直接套用相图知识的简单计算过程，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用相图或基本公式来确定初始凝固固相的成分，属于单一公式直接计算的简单应用。解题步骤简单，无需复杂分析或组合多个公式，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 3811, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each phase at 184°C.", + "answer": "α: 19% sn, l: 61.9% sn, % α = 63%, % l = 37%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在184°C时各相的数量和组成，答案给出了具体的数值计算结果（% α = 63%, % l = 37%），这表明解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要理解相图的基本原理并能够关联不同概念进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要掌握相图知识并进行多步计算。题目要求确定特定温度下各相的含量和组成，涉及杠杆法则的应用和相图解读，但选择题型提供了正确选项，降低了部分计算复杂度。" + }, + { + "idx": 3812, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each base at 182°C.", + "answer": "α: 19% sn, β: 97.5% sn, % α = 80%, % β = 20%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在182°C时各相的量和组成，需要使用相图和杠杆定律进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要理解相图的基本原理并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求确定Pb-35% Sn合金在182°C时各相的组成和含量，这涉及到杠杆定律的应用和相图分析。虽然选择题提供了正确选项，但仍需要考生能够正确识别相图中的关键点（如共晶点和溶解度极限），并进行组成和含量的计算。这种题目比简单的概念识别题更难，但比需要复杂推导的开放性问题简单。" + }, + { + "idx": 3813, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each microconstituent at 182°C.", + "answer": "primary α: 19% sn, % primary α = 63%, eutectic: 61.9% sn, % eutectic = 37%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在182°C时各微组成物的量和组成，答案给出了具体的数值计算结果，涉及相图分析和百分比计算，属于典型的计算题。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相组成和成分的确定，需要综合分析Pb-Sn合金在特定温度下的相平衡状态，并运用杠杆法则进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求确定Pb-35% Sn合金在182°C时的各微组成物的含量和成分，这涉及：" + }, + { + "idx": 3814, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each phase at 25°C.", + "answer": "α: 2% sn, β: 100% sn, % α = 66%, % β = 34%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在25°C时各相的数量和组成，需要使用杠杆法则等计算方法，答案给出了具体的数值计算结果。 | 知识层次: 题目需要应用杠杆法则进行多步计算，涉及相图分析和成分计算，需要将概念关联并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆法则计算以及成分分析。虽然题目提供了正确选项，但解题过程涉及多步骤计算和概念关联，包括确定相组成、计算各相百分比等，属于综合性计算问题。" + }, + { + "idx": 3815, + "question": "Consider a Pb-70% Sn alloy. Determine if the alloy is hypoeutectic or hypereutectic.", + "answer": "hypereutectic", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断给定的合金是亚共晶还是过共晶，答案是一个明确的判断结果（hypereutectic），类似于判断题中对陈述对错的判断。 | 知识层次: 题目考查对合金成分分类（亚共晶或过共晶）的基本概念记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即判断Pb-70% Sn合金是亚共晶还是过共晶。这属于最基本的概念正误判断，无需复杂推理或分析，只需记住共晶点的定义和分类即可直接作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3816, + "question": "Consider a Pb-70% Sn alloy. Determine the composition of the first solid to form during solidification.", + "answer": "98% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在凝固过程中首先形成的固体的成分，需要参考相图和相关公式进行计算，答案是一个具体的数值（98% Sn），属于计算题的特征。 | 知识层次: 题目要求根据给定的合金成分（Pb-70% Sn）确定凝固过程中首先形成的固相成分（98% Sn），这需要应用相图的基本知识和简单的相图读取技能。虽然涉及相图的理解，但主要是一个直接的应用过程，不需要多步计算或复杂的综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求确定Pb-70% Sn合金在凝固过程中首先形成的固体的成分，正确选项直接给出了98% Sn。这只需要学生记住或应用相图中关于共晶合金凝固的基本知识，无需复杂计算或多步骤推理。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3817, + "question": "Consider a Pb-70% Sn alloy. Determine the amounts and compositions of each phase at 184 degrees C.", + "answer": "beta: 97.5% sn, l: 61.9% sn, % beta = 22.8%, % l = 77.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在184°C时各相的数量和组成，答案给出了具体的数值计算结果（% beta = 22.8%, % l = 77.2%），这表明解答过程需要应用相图和相关公式进行计算。 | 知识层次: 题目需要根据相图进行多步计算，涉及相组成和相对量的确定，需要理解相图的基本原理并能够进行综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆法则应用并进行多步计算。题目要求考生能够正确识别184°C时的相组成（β相和液相），运用杠杆法则计算各相比例，同时需要准确读取相图中对应成分（61.9% Sn和97.5% Sn）。虽然选择题提供了正确选项，但解题过程涉及相图分析、成分确定和百分比计算三个关键步骤，属于典型的综合性计算问题。" + }, + { + "idx": 3819, + "question": "Consider a Pb-70% Sn alloy. Determine the amounts and compositions of each microconstituent at 182 degrees C.", + "answer": "primary beta: 97.5% sn, % primary beta = 22.8%, eutectic: 61.9% sn, % eutectic = 77.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在182°C时各微组成物的数量和成分。答案给出了具体的百分比和成分，这表明需要进行数值计算和相图分析来得出结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分比例的确定，需要综合分析相图中不同区域的组成和比例关系。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律计算，并进行多步骤综合分析。题目要求计算两种微组成物的含量和成分，涉及多个计算步骤和概念关联，但选项提供了明确的计算结果，降低了部分难度。" + }, + { + "idx": 3820, + "question": "Consider a Pb-70% Sn alloy. Determine the amounts and compositions of each phase at 25 degrees C.", + "answer": "alpha: 2% sn, beta: 100% sn, % alpha = 30%, % beta = 70%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在25°C时各相的数量和组成，答案给出了具体的数值计算结果（alpha: 2% sn, beta: 100% sn, % alpha = 30%, % beta = 70%），这需要应用相图和相关公式进行计算。 | 知识层次: 题目涉及基本的相图应用和简单的百分比计算，属于直接套用公式和基本概念的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要运用杠杆法则（lever rule）进行简单的相组成计算。虽然涉及两个相（alpha和beta）的组成和比例计算，但步骤较为直接，仅需套用基本公式即可得出结果，无需复杂的分析或组合多个公式。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3821, + "question": "Consider an Al-4% Si alloy. Determine if the alloy is hypo eutectic or hyper eutectic.", + "answer": "hypo eutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来判断合金的类型（hypo eutectic或hyper eutectic），而不是从多个选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查对合金分类的基本概念记忆和理解，只需根据硅含量与共晶点的关系判断合金类型，无需复杂分析或计算。 | 难度: 在选择题型中，该题目仅需要记忆基本的合金分类定义（hypo eutectic和hyper eutectic的区别），无需解释或复杂分析。属于最基础的概念记忆题，符合等级1标准。" + }, + { + "idx": 3822, + "question": "Consider an Al-4% Si alloy. Determine the composition of the first solid to form during solidification.", + "answer": "1% si", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Al-4% Si合金在凝固过程中第一个固体的成分，需要应用相图和相关公式进行计算，答案是一个具体的数值（1% Si）。 | 知识层次: 题目需要应用相图的基本知识进行简单计算，直接套用杠杆定律或平衡分配系数公式即可得出结果，属于基本公式应用和简单计算范畴。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅需应用基本的相图知识（如杠杆定律或固溶度曲线）进行单一公式的直接计算，无需复杂推理或多步骤分析。正确选项可直接通过简单查图或套用公式得出，符合等级1的单一公式直接计算标准。" + }, + { + "idx": 3823, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each phase at 578 degrees C.", + "answer": "alpha: 1.65% si, l: 12.6% si, % alpha=78.5%, % l=21.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定各相的数量和组成，答案给出了具体的数值计算结果，涉及相图分析和百分比计算，属于典型的计算题类型。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相的成分和相对量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要考生掌握相图知识并能进行多步计算。题目要求确定特定温度下各相的成分和比例，涉及杠杆定律的应用和百分比计算，属于综合性计算问题。虽然题目提供了正确选项，但考生仍需理解相图概念并正确应用计算方法才能得出答案。" + }, + { + "idx": 3824, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each phase at 576 degrees C.", + "answer": "alpha: 1.65% si, beta: 99.83% si, % alpha=97.6%, % beta=2.4%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定各相的数量和组成，答案给出了具体的数值结果，涉及相图分析和百分比计算，属于典型的计算题类型。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相组成和相对量的确定，需要综合分析合金成分和温度对相变的影响，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求考生掌握Al-Si相图的关键点（共晶成分和温度），并能正确应用杠杆定律计算两相比例和成分。虽然选择题型提供了正确选项，但仍需要考生进行相成分识别、温度定位和定量计算等步骤，属于综合性计算问题。" + }, + { + "idx": 3825, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each microconstituent at 576 degrees C.", + "answer": "primary alpha: 1.65% si, % primary alpha=78.5%, eutectic: 12.6% si, % eutectic=21.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的含量和成分，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相的成分和相对量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用相图知识、杠杆定律计算以及成分分析能力。题目要求计算多个微结构成分（primary alpha和eutectic）的含量和组成，涉及多步骤计算过程（如确定相界成分、应用杠杆定律两次计算）和概念关联（理解共晶反应和相组成）。虽然选择题提供了正确选项降低了部分难度，但仍需较强的综合分析能力来验证各计算步骤的正确性。" + }, + { + "idx": 3826, + "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each phase at 25 degrees C.", + "answer": "alpha: 0% si, beta: 100% si, % alpha=96%, % beta=4%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Al-4% Si合金在25°C时各相的含量和组成，答案给出了具体的数值计算结果（% alpha=96%, % beta=4%），这需要应用相图知识和杠杆定律进行计算。 | 知识层次: 题目需要应用相图的基本知识进行简单的百分比计算，涉及直接套用公式和基本概念，属于基础应用层次。 | 难度: 在选择题型中，该题目仅需要直接应用相图的基本知识，通过简单的计算即可得出答案。题目中已经给出了明确的成分和温度条件，只需要根据相图直接读取各相的成分和比例，无需复杂的推理或多步骤计算。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3827, + "question": "Consider a Al-25% Si alloy. Determine if the alloy is hypo eutectic or hyper eutectic.", + "answer": "hyper eutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过分析合金成分来判断其属于亚共晶还是过共晶，需要文字解释和论述，而不是简单的选择或判断。答案也是以文字形式给出，而非数值计算结果。 | 知识层次: 题目考查对共晶合金分类的基本概念记忆和理解，只需知道Al-Si合金的共晶点成分(12.6% Si)即可判断25% Si属于过共晶(hyper eutectic)，不需要复杂计算或分析过程。 | 难度: 该题目属于基础概念记忆类型，仅需知道Al-Si合金的共晶点（约12.6% Si）即可直接判断25% Si属于过共晶成分。选择题型中无需计算或推导，属于最简单的定义识别类题目。" + }, + { + "idx": 3828, + "question": "Consider a Al-25% Si alloy. Determine the composition of the first solid to form during solidified.", + "answer": "100% si", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定合金凝固时第一个固体的成分，需要基于相图和材料科学知识进行解释和论述，答案是一个具体的成分（100% Si），而不是从多个选项中选择或简单的对错判断，也不涉及复杂的数值计算。 | 知识层次: 题目需要理解相图的基本原理，并能够应用杠杆定律进行多步计算，确定在凝固过程中首先形成的固相成分。这涉及到概念关联和综合分析，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题中属于中等难度，需要理解相图概念并应用杠杆定律进行多步计算。虽然题目给出了具体合金成分，但需要考生综合分析Al-Si相图特性，识别共晶点位置，并推导初生相成分。这比单纯记忆知识点或简单计算更复杂，但相比需要多角度论证的题目又相对直接。" + }, + { + "idx": 3829, + "question": "Consider a Al-25% Si alloy. Determine the amounts and compositions of each phase at 578 degrees C.", + "answer": "β: 99.83% si, l: 12.6% si, %l: 85.8%, %β: 14.2%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的数量和组成，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要运用相图知识进行多步计算，涉及相组成和相含量的确定，需要综合分析相图数据并应用杠杆定律进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律应用以及多步计算。题目要求确定特定温度下合金的相组成和成分，涉及查找相图数据、计算相比例和成分，属于综合性计算问题。虽然提供了正确选项，但解题过程仍需综合分析能力。" + }, + { + "idx": 3831, + "question": "Consider a Al-25% Si alloy. Determine the amounts and compositions of each microconstituent at 576 degrees C.", + "answer": "primary β: 99.83% si, % primary β: 14.2%; eutectic: 12.6% si, % eutectic: 85.8%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的数量和组成，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相的成分和比例，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、进行多步计算（如杠杆定律应用）并综合分析各微组成物的含量和成分。虽然选项已给出正确结果，但解题过程涉及多个知识点的关联应用，属于综合性计算问题。" + }, + { + "idx": 3832, + "question": "Consider a Al-25% Si alloy. Determine the amounts and compositions of each phase at 25 degrees C.", + "answer": "α: 0% si, β: 100% si, %α: 75%, %β: 25%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定合金中各相的数量和组成，涉及数值计算和相图应用，答案以具体数值形式给出。 | 知识层次: 题目需要应用相图知识进行简单的数值计算，属于基本公式应用和直接套用范畴，不需要多步计算或综合分析。 | 难度: 在选择题型内，该题目属于单一公式直接计算的难度等级。题目仅需应用杠杆法则（lever rule）进行简单的百分比计算，无需复杂的概念理解或多步骤推理。正确选项直接给出了计算结果，学生只需识别并应用基本公式即可得出答案。" + }, + { + "idx": 3833, + "question": "A Pb-Sn alloy contains 45% alpha and 55% beta at 100C. Determine the composition of the alloy.", + "answer": "56.15% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金的成分，需要应用相图和相关公式进行数值计算，最终得出具体的百分比数值（56.15% sn）。 | 知识层次: 题目需要应用杠杆定律（lever rule）进行多步计算，涉及相图中成分比例的确定，需要理解相图的基本概念并进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解相图概念并进行多步计算。题目要求根据给定的相比例反推合金成分，涉及杠杆定律的应用和相图数据的查找，属于综合性计算问题。虽然题目提供了正确选项，但解题过程需要较强的概念关联和综合分析能力。" + }, + { + "idx": 3834, + "question": "Is the alloy hypoeutectic or hypereutectic?", + "answer": "hypoeutectic", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从\"hypoeutectic\"或\"hypereutectic\"两个选项中选择正确答案 | 知识层次: 题目考查对合金分类（hypoeutectic或hypereutectic）的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要学生理解并区分\"hypoeutectic\"和\"hypereutectic\"这两个专业术语的含义。这超出了简单的概念识别（等级1），需要一定的概念理解和辨析能力（等级2），但不需要进行复杂的分析或深度理解（等级3）。" + }, + { + "idx": 3835, + "question": "An Al-Si alloy contains 85 % α and 15 % β at 500°C. Determine the composition of the alloy.", + "answer": "15.85% Si", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金的成分，答案是一个具体的数值（15.85% Si），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及相图分析和成分计算，需要理解相图的基本原理并应用相关公式进行综合计算。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求根据给定的相比例反推合金成分，涉及杠杆定律的应用和代数运算，属于综合性计算问题。虽然选择题提供了正确选项，但仍需较深入的知识掌握和计算能力才能准确解答。" + }, + { + "idx": 3837, + "question": "A Pb-Sn alloy contains 23% primary \\alpha and 77% eutectic microconstituent. Determine the composition of the alloy.", + "answer": "x = 52% sn", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和相图应用来确定合金成分，答案是一个具体的数值结果（52% Sn），属于典型的计算题特征。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分推导，需要理解并关联多个概念，如初生相、共晶组织等，思维过程具有一定深度。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律计算，并进行多步骤综合分析。虽然题目提供了正确选项，但解题过程涉及确定合金成分与相比例的关系，需要较强的应用能力和计算技巧。" + }, + { + "idx": 3838, + "question": "An Al-Si alloy contains 15% primary \\beta and 85% eutectic microconstituent. Determine the composition of the alloy.", + "answer": "25.71% si", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定合金的成分，答案是一个具体的数值（25.71% si），而不是选择、判断或文字解释。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分推导，需要将概念关联并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、进行多步计算（包括质量分数转换和相组成分析），并综合应用杠杆定律和共晶反应知识来推导合金成分。虽然题目提供了部分已知条件，但解题过程涉及多个关联步骤和概念整合，对学生的综合分析能力有一定要求。" + }, + { + "idx": 3839, + "question": "Observation of a microstructure shows that there is 28% eutectic and 72% primary β in an Al-Li alloy. Determine the composition of the alloy and whether it is hypoeutectic or hypereutectic.", + "answer": "17.46% li, hypereutectic", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过观察到的微观结构比例（28%共晶和72%初生β）来计算合金的成分（17.46% Li）并判断其属于亚共晶还是过共晶（hypereutectic）。这需要应用杠杆定律等计算方法和相图知识，属于典型的计算题。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分判断，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解共晶反应、杠杆定律等概念，并进行多步计算和综合分析。题目要求根据显微组织比例反推合金成分并判断亚共晶或过共晶类型，涉及多个知识点的关联应用，但选项已给出正确答案，降低了部分难度。" + }, + { + "idx": 3840, + "question": "Observation of a microstructure shows that there is 28% eutectic and 72% primary β in an Al-Li alloy. How much α and β are in the eutectic microconstituent?", + "answer": "% α_est = 64% and % β_est = 36%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定α和β在共晶微结构中的百分比。答案以具体数值形式给出，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算和概念关联，涉及相图分析和成分计算，需要理解共晶反应和杠杆定律的应用，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解共晶组织的组成比例概念，并进行多步计算。题目要求从给定的共晶和初生相比例出发，进一步计算共晶微结构中α和β相的具体含量，涉及相图知识的应用和比例换算，属于综合性计算问题。虽然题目提供了正确选项，但解题过程需要较强的概念关联和综合分析能力。" + }, + { + "idx": 3841, + "question": "Calculate the total amount of alpha and beta in a Pb-50% Sn alloy at 182°C.", + "answer": "total amount of alpha = 60.5%, beta = 39.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算alpha和beta的含量百分比），答案以具体数值形式给出，需要使用相图或相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及杠杆定律的应用和相组成分析，需要将概念关联并进行综合分析，但不需要复杂的机理推导或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律应用并进行多步计算。题目要求计算特定温度下两相比例，涉及查找相图关键点、成分转换和百分比计算，但选择题型提供了正确选项降低了部分推导难度。" + }, + { + "idx": 3842, + "question": "Calculate the amount of each microconstituent in a Pb-50% Sn alloy at 182°C.", + "answer": "microconstituents: primary alpha = 27.7%, eutectic = 72.3%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算Pb-50% Sn合金在182°C时各微组分的含量，需要通过数值计算和公式应用得出结果，答案以百分比形式给出，符合计算题的特征。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及微组成分的百分比计算，需要理解相图的基本原理并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、掌握杠杆定律计算步骤，并能正确关联微结构组成与温度条件。题目涉及多步计算和综合分析，但选项已提供计算结果，降低了部分难度。" + }, + { + "idx": 3843, + "question": "What fraction of the total alpha in the alloy is contained in the eutectic microconstituent?", + "answer": "fraction of total alpha in the eutectic microconstituent f = 0.54.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算合金中共晶微结构中α相所占的比例，答案是一个具体的数值（0.54），这表明需要通过数值计算和公式应用来解答。 | 知识层次: 题目涉及基本的相图计算和公式应用，需要理解共晶组织的组成比例计算，但不需要多步计算或复杂分析 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用基本公式进行计算，但解题步骤相对直接，仅涉及单一概念（共晶微组成物中的α相分数）的简单套用，无需多步骤推导或复杂概念组合。相比等级1的直接查表或记忆题稍复杂，但远低于等级3的多公式组合计算难度。" + }, + { + "idx": 3844, + "question": "Recommend an artificial age-hardening heat treatment for a Cu-1.2% Be alloy (see Figure 12-34). Include appropriate temperatures.", + "answer": "For the Cu-1.2% Be alloy, solution treat between 530°C and 870°C (typical at 780°C), quench, and age below 530°C (typical at 330°C).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推荐一种人工时效热处理工艺，并包括适当的温度，需要文字解释和论述，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目要求根据相图推荐具体的热处理工艺参数，需要理解Cu-Be合金的时效硬化原理，并能够将相图信息转化为具体的热处理温度范围。这涉及多步思考过程（固溶处理+淬火+时效处理）和温度选择的综合分析，但不需要深入分析微观机理或进行创新设计。 | 难度: 在选择题中属于中等难度，需要理解Cu-Be合金的时效硬化处理原理，掌握固溶处理和时效处理的关键温度范围，并能将理论知识与实际应用相结合。虽然题目给出了具体温度参数，但仍需要考生具备综合分析能力，理解不同温度阶段的作用和选择依据。" + }, + { + "idx": 3845, + "question": "Compare the amount of the γ2 precipitate that forms by artificial aging at 400°C with the amount of the precipitate that forms by natural aging for a Cu-1.2% Be alloy.", + "answer": "The amount of γ2 precipitate at 400°C is 5.4%, and at room temperature, it is 8.5%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种不同条件下沉淀物的数量，答案提供了具体的数值比较，但需要解释和论述不同条件下沉淀物形成的原因和差异，属于需要文字解释的简答题类型。 | 知识层次: 题目要求比较两种不同时效条件下γ2析出相的数量，涉及多步计算和概念关联，需要综合分析时效温度对析出相数量的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及Cu-1.2% Be合金在人工时效和自然时效条件下γ2析出相数量的比较，需要掌握析出相形成的相关知识，并能对不同温度下的析出行为进行综合分析。虽然题目给出了具体数值，但正确理解这些数值背后的物理意义和形成机制仍需要一定的知识积累和应用能力。" + }, + { + "idx": 3846, + "question": "For an Fe-0.35% C alloy, determine the temperature at which austenite first begins to transform on cooling.", + "answer": "795°C", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定特定合金在冷却过程中奥氏体开始转变的温度，这需要参考铁碳相图或相关公式进行计算，答案以具体数值形式给出。 | 知识层次: 题目要求根据给定的合金成分（Fe-0.35% C）和铁碳相图，确定奥氏体开始转变的温度。这主要涉及基本公式应用和直接套用铁碳相图的知识，不需要多步计算或复杂分析。 | 难度: 在选择题型内，该题目属于单一公式直接计算的难度等级。题目要求根据Fe-C相图直接查找或应用已知的相变温度数据，无需复杂计算或多步骤推理。学生只需记住或查阅0.35%碳含量对应的奥氏体开始转变温度即可得出正确答案795°C。这属于基础知识的直接应用，符合等级1的定义。" + }, + { + "idx": 3847, + "question": "For an Fe-0.35% C alloy, determine the primary microconstituent that forms.", + "answer": "primary α-ferrite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定合金的主要微观组成，需要基于材料科学知识进行文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求根据给定的合金成分（Fe-0.35% C）确定主要微观组成物（primary α-ferrite），这需要应用铁碳相图的基本知识，属于直接套用相图信息的简单应用。虽然需要理解相图的基本概念，但不需要多步计算或综合分析，思维过程较为直接。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需根据给定的Fe-0.35% C合金成分直接套用铁碳相图的基本知识即可确定主要微观组织为primary α-ferrite。解题步骤简单直接，无需复杂计算或多概念综合分析，因此在选择题型内属于较低难度等级。" + }, + { + "idx": 3848, + "question": "For an Fe-0.35% C alloy, determine the composition and amount of each phase present at 728°C.", + "answer": "α: 0.0218% C, 56.1% γ: 0.77% C, 43.9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Fe-0.35% C合金在728°C时各相的组成和含量，需要使用相图和杠杆定律进行数值计算。答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，能够正确识别728°C时的相组成（α和γ相），并运用杠杆定律进行计算。虽然题目给出了正确选项，但解题过程涉及多个步骤和概念的综合运用，包括相图解读、成分确定和百分比计算，这些都需要一定的材料科学基础和分析能力。" + }, + { + "idx": 3849, + "question": "For an Fe-0.35% C alloy, determine the composition and amount of each phase present at 726°C.", + "answer": "α: 0.0218% C, 93.3% Fe3C: 6.67% C, 4.9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要使用杠杆法则等计算方法，答案以具体数值形式呈现，符合计算题的特征。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分转换，属于中等应用层次。虽然计算过程相对直接，但需要理解相图的基本原理和正确应用公式。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，能够正确识别726°C时的相组成（α相和Fe3C相），并运用杠杆定律进行多步计算。虽然题目提供了正确选项，但解题过程涉及相图定位、成分确定和百分比计算等多个步骤，需要较强的概念关联和综合分析能力。相比简单的概念识别题（等级1）或单一计算题（等级2），该题目对知识掌握深度和计算准确性的要求更高，但尚未达到复杂多变量计算（等级4）的程度。" + }, + { + "idx": 3850, + "question": "For an Fe-0.35% C alloy, determine the composition and amount of each microconstituent present at 726°C.", + "answer": "primary α: 0.0218% C, 56.1% pearlite: 0.77% C, 43.9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的成分和含量，答案给出了具体的数值计算结果，这需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用铁碳相图进行多步计算，包括确定相组成和相对量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，能够正确读取相图中的关键点（如共析点、溶解度极限等），并进行多步计算（杠杆定律应用）。虽然题目提供了正确选项降低了部分难度，但仍需要考生综合运用相图知识和计算能力来确定各微组成物的成分和含量。相比单纯的概念题或单步计算题，本题涉及更复杂的综合分析过程。" + }, + { + "idx": 3851, + "question": "For an Fe-1.15% C alloy, determine the temperature at which austenite first begins to transform on cooling.", + "answer": "880 degrees c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定特定合金在冷却过程中奥氏体开始转变的温度，这需要参考铁碳相图或相关公式进行计算，答案是一个具体的数值（880 degrees c），表明这是一个需要计算或查图得出的结果。 | 知识层次: 题目要求根据给定的合金成分（Fe-1.15% C）和铁碳相图，确定奥氏体开始转变的温度。这主要涉及基本公式应用和简单计算，即直接查阅铁碳相图或使用相关数据表找到对应温度。不需要多步计算或综合分析，属于直接套用基础知识的简单应用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求确定Fe-1.15% C合金在冷却时奥氏体开始转变的温度，这可以直接通过查阅铁碳相图或记忆关键温度点（如共析温度）来得出答案。无需复杂计算或多步骤推理，只需简单应用基本知识即可选择正确选项。" + }, + { + "idx": 3852, + "question": "For an Fe-1.15% C alloy, determine the primary microconstituent that forms.", + "answer": "primary Fe3C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定合金的主要微观组成物，答案需要给出具体的物质名称（primary Fe3C），属于需要简短文字回答的问题类型，而非选择、判断或计算。 | 知识层次: 题目考查对Fe-C合金相图中基本相组成的记忆和理解，只需根据给定的碳含量判断初生相为Fe3C，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即对Fe-1.15% C合金中主要微观组成相的定义性知识。学生只需记住该成分下会形成primary Fe3C即可作答，无需进行概念解释或复杂分析，属于最基础的定义简答型题目。" + }, + { + "idx": 3853, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each phase present at 728 degrees C.", + "answer": "Fe3C: 6.67% C, 6.4%; gamma: 0.77% C, 93.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要应用相图和相关公式进行计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图进行多步计算，包括确定相组成和相对量，涉及杠杆定律的应用和相图分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要考生掌握铁碳相图的基本概念（如Fe3C和gamma相的组成范围），能够正确识别728°C时的相平衡条件（共析反应温度），并应用杠杆定律进行两相组成和相对量的计算。虽然题目提供了正确选项可以部分验证计算过程，但仍需要考生完成多个步骤的推导和计算，属于综合性计算问题。" + }, + { + "idx": 3854, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each phase present at 720 degrees C.", + "answer": "alpha: 0.0218% C, 83%; Fe3C: 6.67% C, 17%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要使用相图和杠杆定律进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，能够正确读取特定温度下的相组成，并应用杠杆定律进行多步骤计算。虽然题目提供了正确选项，但解题过程涉及多个知识点的综合应用和计算步骤，对学生的理解能力和计算能力有一定要求。" + }, + { + "idx": 3855, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each microconstituent present at 726 degrees C.", + "answer": "primary Fe3C: 6.67% C, 6.4%; pearlite: 0.77% C, 93.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的成分和含量，需要应用相图和相关公式进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图和相关公式进行多步计算，包括确定各相的组成和比例，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，掌握杠杆定律的应用，并进行多步计算。题目要求确定在特定温度下合金的组成和各微组成物的含量，涉及对相图中不同相区的识别和成分的准确读取，以及综合运用杠杆定律进行计算。虽然题目提供了正确选项，但解题过程需要较强的概念关联和综合分析能力。" + }, + { + "idx": 3856, + "question": "A steel contains 8 % cementite and 92 % ferrite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 0.53 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算来估计钢中的碳含量，需要使用材料科学中的相图或相关公式进行计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的相图知识（铁碳相图）和简单的质量百分比计算，属于直接套用公式和基本概念的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据给定的铁素体和渗碳体比例直接计算钢中的碳含量，这只需要应用基本的杠杆法则或相图比例关系，无需复杂的推导或多步骤计算。正确选项直接给出了计算结果，学生只需识别并应用正确的公式即可得出答案。" + }, + { + "idx": 3857, + "question": "Is the steel hypoeutectoid or hypereutectoid?", + "answer": "the steel is hypoeutectoid.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断钢是亚共析钢还是过共析钢，属于对陈述事实的判断，答案形式为直接给出判断结果。 | 知识层次: 题目考查对钢的分类（亚共析钢或过共析钢）这一基础概念的记忆和理解，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即判断钢是亚共析钢还是过共析钢。这属于最基本的概念正误判断，无需复杂分析或推理，只需回忆相关定义即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3858, + "question": "A steel contains 18 % cementite and 82 % ferrite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 1.20 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计钢中的碳含量，需要应用相关的材料科学公式和数值计算。答案是一个具体的数值结果（1.20 % c），这表明解答过程涉及计算而非选择或判断。 | 知识层次: 题目需要应用铁碳相图的知识，通过已知的相组成比例（18% cementite和82% ferrite）来计算碳含量。这涉及到多步计算和概念关联，需要理解相图的基本原理和相组成的计算方法，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图中渗碳体和铁素体的组成比例关系，并进行多步计算来推导碳含量。虽然题目提供了具体比例，但需要考生掌握相图知识并正确应用杠杆定律进行计算，属于综合性计算问题。" + }, + { + "idx": 3860, + "question": "A steel contains 18 % pearlite and 82 % primary ferrite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 0.156 %c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过计算来估计钢的碳含量，答案是一个具体的数值（0.156 %c），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要进行多步计算和概念关联，涉及铁碳相图的应用和成分估算，需要综合分析珠光体和初生铁素体的比例来确定碳含量。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图中珠光体和初生铁素体的组成比例与碳含量的关系，并进行多步计算来估算碳含量。虽然题目给出了明确的比例关系，但仍需要考生具备综合分析能力和对相图的理解才能正确解答。" + }, + { + "idx": 3862, + "question": "A steel contains 94 % pearlite and 6 % primary cementite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 1.124 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计钢的碳含量，答案是一个具体的数值结果（1.124 % c），解答过程需要应用材料科学中的相图或相关公式进行计算。 | 知识层次: 题目需要应用杠杆定律（lever rule）进行多步计算，涉及相图中珠光体和初生渗碳体的比例关系，需要理解相图的基本原理并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图中珠光体和初生渗碳体的组成比例关系，并进行多步计算来推导碳含量。虽然题目给出了明确的比例数据，但需要考生掌握相图知识并正确应用杠杆定律进行计算，属于综合性计算问题。" + }, + { + "idx": 3864, + "question": "A steel contains 55% \\alpha and 45% \\gamma at 750^{\\circ} C. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 0.281% C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计钢的碳含量，答案是一个具体的数值结果（0.281% C），解答过程需要应用材料科学中的相图或相关公式进行计算。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的相比例和温度来估算碳含量，涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图中α和γ相的比例关系，并能正确应用杠杆定律进行多步计算。虽然题目给出了具体温度（750°C）简化了部分分析步骤，但仍需要考生综合运用相图知识和计算能力才能得出正确答案。相比单纯的概念题或单步计算题，这类题目对知识掌握深度和计算能力的要求更高，但尚未达到复杂多变量计算的难度。" + }, + { + "idx": 3865, + "question": "A steel contains 96% \\gamma and 4% \\mathrm{Fe}_{3} C at 800^{\\circ} C. Estimate the carbon content of the steel.\n\\[\n\\begin{array}{l}\n\\text {", + "answer": "the carbon content of the steel is 1.15% C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计钢的碳含量，需要使用给定的成分比例和可能的相图或公式进行计算。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及相图的应用和碳含量的估算，需要理解相图的基本原理并进行综合分析。虽然计算过程不算复杂，但需要关联多个概念和步骤，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求根据给定的γ相和Fe3C比例估算钢的碳含量，这涉及到杠杆定律的应用和相图知识的综合运用。虽然计算步骤明确，但需要考生对相图有较深的理解并能正确应用相关公式，属于综合性计算问题。" + }, + { + "idx": 3866, + "question": "A steel is heated until 40% austenite, with a carbon content of 0.5%, forms. Estimate the temperature.", + "answer": "the temperature is about 760 degrees c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算和公式应用来估计温度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的奥氏体含量和碳含量来估算温度。这涉及多步计算和概念关联，需要综合分析铁碳相图中的相关区域和相变点，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、奥氏体形成条件等多个概念，并进行多步计算和综合分析。题目要求根据给定的碳含量和奥氏体比例估算温度，这需要考生能够将理论知识与实际应用相结合，属于综合性计算问题。" + }, + { + "idx": 3867, + "question": "A steel is heated until 40% austenite, with a carbon content of 0.5%, forms. Estimate the overall carbon content of the steel.", + "answer": "the overall carbon content of the steel is 0.212% c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计钢的总体碳含量，涉及数值计算和公式应用。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及奥氏体形成比例和碳含量的关系，需要理解相图和相关公式的应用，并进行综合分析得出结果。 | 难度: 在选择题中属于中等偏上难度，需要理解奥氏体形成比例与碳含量的关系，并进行多步计算。题目要求将40%奥氏体（含碳0.5%）与剩余相（假设为铁素体）的碳含量进行综合计算，涉及相图知识和质量平衡概念。虽然选择题提供了正确选项，但仍需进行综合分析才能确认答案，比单纯的概念识别题更复杂。" + }, + { + "idx": 3868, + "question": "An isothermally transformed eutectoid steel is found to have a yield strength of 410 MPa. Estimate the transformation temperature.", + "answer": "transformation temperature =615 C", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算来估计转变温度，答案是一个具体的数值结果（615 C），这表明需要应用相关公式或经验关系进行计算。 | 知识层次: 题目需要应用材料科学中的相变温度与力学性能关系知识，进行多步计算和综合分析。虽然题目给出了具体的数值计算要求，但需要理解相变温度与屈服强度之间的关系，并可能涉及相关公式的应用，这超出了简单应用的范畴，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解等温转变曲线、屈服强度与转变温度的关系，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及多个概念的关联和计算步骤，比单纯记忆或简单计算的选择题更复杂。" + }, + { + "idx": 3869, + "question": "An isothermally transformed eutectoid steel is found to have a yield strength of 410 MPa. Estimate the interlamellar spacing in the pearlite.", + "answer": "1 / lambda=60,000 or lambda=1.67 × 10^-5 cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计珠光体的层间距，答案给出了具体的数值计算结果（1 / lambda=60,000 or lambda=1.67 × 10^-5 cm），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用已知的屈服强度与珠光体片层间距之间的关系公式进行计算，涉及多步推导和概念关联，但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解珠光体层间距与屈服强度的关系公式（Hall-Petch关系），并进行多步骤计算（包括单位换算和公式变形）。题目要求将给定的屈服强度值转换为层间距，涉及材料科学中的核心概念和计算能力，但选项已提供关键计算步骤的提示，降低了部分难度。" + }, + { + "idx": 3870, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 38", + "answer": "600 degrees C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定转变温度和微观组成，需要解释和论述，而答案是一个具体的温度值，属于简答形式 | 知识层次: 题目要求根据硬度值确定共析钢的转变温度和显微组织，这需要理解相变温度与硬度之间的关系，并能够应用相关相图知识进行综合分析。虽然不涉及复杂的计算或深度机理分析，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握共析钢的相变温度与硬度关系，需要综合运用TTT曲线和硬度转换知识，涉及多步计算和概念关联。虽然题目给出了正确选项，但解题过程需要综合分析材料性能与热处理参数的关系，属于中等应用层次的要求。" + }, + { + "idx": 3871, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 42", + "answer": "400 degrees C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定转变温度和微观组成，需要解释和论述如何根据硬度值HRC 42来确定这些参数，而不仅仅是选择一个选项或进行简单的计算。答案给出了具体的温度值，但问题的解答需要更详细的解释和论述过程。 | 知识层次: 题目要求根据硬度值确定转变温度和显微组织，涉及多步计算和概念关联，需要综合分析相图和硬度数据，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 3872, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 48", + "answer": "340 degrees C", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定特定的转变温度和微观组织以达到给定的硬度值，这需要通过计算或查阅相关相图来确定。答案以具体数值形式给出（340 degrees C），表明这是一个需要数值计算或查找的题目。 | 知识层次: 题目要求根据硬度值确定转变温度和显微组织，涉及多步计算和概念关联，需要综合分析相图和硬度数据。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如相变温度、硬度与组织的关系）并进行综合分析。题目要求将硬度值HRC 48与特定温度关联，涉及多步计算和概念关联，但选项已给出正确答案，降低了部分难度。" + }, + { + "idx": 3874, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 800^{\\circ} C for 1h, quenched to 350^{\\circ} C and held for 750s, and finally quenched to room temperature.", + "answer": "HRC =47 and the microstructure is all baninite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解钢的热处理过程及其对硬度和微观结构的影响，涉及多步热处理工艺（加热、淬火、保温、再淬火）的综合分析，以及对所得贝氏体组织和硬度的判断。这要求考生能够将热处理工艺参数与材料性能变化关联起来，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 3875, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 700^{\\circ} C, quenched to 650^{\\circ} C and held for 500s, and finally quenched to room temperature.", + "answer": "HRC =25 and the microstructure is all pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，需要文字解释和论述，答案也是以文字形式给出。 | 知识层次: 题目要求描述特定热处理条件下共析钢的硬度和显微组织，涉及对热处理工艺、相变过程以及显微组织与性能关系的理解和应用。需要将热处理步骤与相变动力学和显微组织演变联系起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及钢的热处理过程、相变行为以及最终组织和硬度的预测，要求考生能够综合运用相关知识，分析不同温度下的相变过程，并正确判断最终的组织和硬度。虽然题目提供了具体的温度和时间参数，但考生仍需具备一定的综合分析能力才能正确选择答案。" + }, + { + "idx": 3876, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 300^{\\circ} C, quenched to 300^{\\circ} C and held for 10s, and finally quenched to room temperature.", + "answer": "HRC=66 and the microstructure is all martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求理解并应用钢的热处理过程对硬度和微观结构的影响，涉及多步热处理工艺（加热、淬火、保温）与最终组织（马氏体）和性能（硬度）的关联分析。虽然答案直接给出了结果，但完整回答需要解释为什么在特定条件下会形成全马氏体组织及其对应的硬度值，这超出了简单记忆或直接套用基础概念的范畴，属于需要综合分析热处理工艺-组织-性能关系的应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及多步热处理过程（加热、淬火、保温、再淬火），要求考生理解每个步骤对材料组织和性能的影响。其次，需要综合应用相变动力学和TTT图的知识，分析在300°C保温10秒是否足以形成贝氏体或保留奥氏体。最后，题目要求将微观组织（全马氏体）与宏观性能（HRC=66）精确对应，这需要深入理解马氏体转变的硬度和组织特征。虽然题目提供了正确选项，但解题过程涉及多角度分析和概念关联，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 3877, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 1000^{\\circ} C, quenched to 3010^{\\circ} C and held for 10 s, quenched to room temperature, and then reheated to 400^{\\circ} C before finally cooling to room temperature again.", + "answer": "HRC=42 and the microstructure is all tempered martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，答案提供了具体的数值和结构描述，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及多个热处理步骤和相变过程，需要综合运用材料科学知识来分析钢的微观结构和硬度变化。这包括理解不同温度下的相变行为、淬火和回火对钢性能的影响，以及最终微观结构的形成机制。思维过程需要深度推理和综合分析，超出了简单应用或中等应用的范围。 | 难度: 在选择题型内，该题目属于最高难度等级。题目涉及复杂的相变过程和热处理步骤，要求考生综合运用材料科学知识，包括奥氏体化、淬火、回火等过程对钢的硬度和微观结构的影响。解题步骤复杂，需要考生理解并推理每个热处理步骤对最终材料性能的影响，并准确预测最终的硬度和微观结构。此外，题目还要求考生具备对复杂现象进行全面分析的能力，能够将理论知识与实际工艺条件相结合，进行机理深度解释。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 3878, + "question": "Describe the complete heat treatment required to produce a quenched and tempered eutectoid steel having a tensile strength of at least 125,000 psi. Include appropriate temperatures.", + "answer": "Austenitize at approximately 750^{\\circ} C,\nQuench to below 130^{\\circ} C (the M_{\\gamma} temperature)\nTemper at 620^{\\circ} C or less.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述完整的热处理过程，包括适当的温度，答案以文字解释和具体温度参数的形式给出，符合简答题的特征。 | 知识层次: 题目要求描述完整的热处理工艺，包括具体的温度参数，涉及多步操作（奥氏体化、淬火、回火）的综合应用。需要理解不同温度对材料性能的影响，并能根据目标强度选择合适的工艺参数。虽然不涉及复杂的计算或深度机理分析，但需要对热处理工艺有较全面的理解和应用能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解热处理的基本概念（如奥氏体化、淬火、回火），还需要掌握具体的温度参数（如750°C、130°C、620°C）及其与材料性能（125,000 psi抗拉强度）的关联。此外，题目涉及多步计算和综合分析，考生需要将理论知识与实际应用相结合，才能正确选择答案。这种题目在选择题型中属于需要多角度分析和论述的类型，因此难度等级为4。" + }, + { + "idx": 3879, + "question": "What is the austenitizing temperature required to produce a quenched and tempered eutectoid steel with a HRC hardness of less than 50?", + "answer": "Austenitize at approximately 75 degrees Celsius.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释特定温度（75°C）作为奥氏体化温度的原因，需要文字说明而非选择、判断或计算 | 知识层次: 题目需要理解奥氏体化温度与钢的硬度和热处理工艺之间的关系，涉及多步概念关联和综合分析，但不需要复杂的机理解释或创新设计。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 3880, + "question": "What is the quenching temperature required to produce a quenched and tempered eutectoid steel with a HRC hardness of less than 50?", + "answer": "Quench to below the M_gamma (less than 130 degrees Celsius).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火温度的具体要求，答案需要文字说明而非选择、判断或计算。 | 知识层次: 题目需要理解淬火温度与钢的硬度和组织转变之间的关系，涉及多步概念关联和综合分析，如M_gamma温度的概念、淬火工艺对硬度的影响等，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及淬火温度、马氏体转变温度（M_gamma）以及硬度要求等概念的综合应用，解题时需要将这些知识点关联起来，并理解它们之间的相互作用。虽然题目提供了明确的正确选项，但需要一定的背景知识才能准确判断。" + }, + { + "idx": 3881, + "question": "What is the tempering temperature range required to produce a quenched and tempered eutectoid steel with a HRC hardness of less than 50?", + "answer": "Temper at a temperature higher than 330 degrees Celsius, but less than 727 degrees Celsius.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述特定温度范围，答案需要文字说明而非选择、判断或计算 | 知识层次: 题目需要理解回火温度与硬度之间的关系，并综合应用相图知识和硬度要求来确定温度范围，涉及多步分析和概念关联。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及淬火和回火工艺的知识，要求考生知道回火温度对硬度的影响，以及共析钢的回火温度范围。此外，还需要将HRC硬度与回火温度关联起来，综合分析得出正确答案。虽然不需要复杂的计算，但需要对材料热处理的基本原理有较好的掌握。" + }, + { + "idx": 3882, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of a material property? (a) Density (b) Annealing (c) Forging (d) Single-crystal (e) Crystalline", + "answer": "(a) Density", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料性能基本概念的记忆和理解，仅需识别出密度是材料性能的典型例子，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基础概念识别，直接记忆的难度等级。题目要求识别材料属性的最佳例子，正确选项(a) Density是一个基本的材料属性，属于材料科学中最基础的概念之一。其他选项如(b) Annealing和(c) Forging是加工过程，(d) Single-crystal和(e) Crystalline是结构描述，与属性无关。因此，只需简单记忆和识别即可选出正确答案，无需深入理解或复杂分析。" + }, + { + "idx": 3883, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of material processing?(a) Extrusion(b) Crystalline(c) Amorphous(d) Glassy (e) Elastic Modulus", + "answer": "(a)Extrusion", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料加工基本概念的识别和记忆，只需从选项中选出与材料加工相关的术语，不需要复杂的分析或推理。 | 难度: 在选择题型中属于简单难度，题目直接考察对\"材料加工\"这一基础概念的识别能力。正确选项(a)Extrusion是材料加工的典型示例，而其他选项都是材料结构或性能的描述。这只需要最基本的定义记忆即可作答，无需理解或辨析过程。" + }, + { + "idx": 3884, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of material structure? (a) Single-phase (b) Elastic Modulus (c) Sintering (d) Magnetic Permeability (e) Brittle", + "answer": "(a)Single-phase", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料结构这一基础概念的记忆和理解，要求从选项中识别出最能代表材料结构的例子，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题属于简单概念识别，直接记忆的题目。题目要求识别\"material structure\"的最佳例子，正确选项(a)Single-phase是材料结构的基础概念之一，无需复杂理解或分析，只需记忆相关定义即可作答。" + }, + { + "idx": 3885, + "question": "Which class of material is generally associated with the highest density values at room temperature? (a) Composites (b) Ceramics (c) Metals (d) Polymers", + "answer": "(c) Metals", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，且答案形式为单一选项 | 知识层次: 题目考查对不同材料类别基本特性的记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆类型，仅需识别不同材料类别的密度特性，无需复杂辨析或深度理解。在选择题型中，直接记忆金属通常具有最高密度即可作答，属于最简单的难度等级。" + }, + { + "idx": 3886, + "question": "By how many orders of magnitude (powers of ten, approximately) does density vary for metals? (a) 0.13 (b) 1.3 (c) 13 (d) 130", + "answer": "(b)1.3", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对金属密度变化范围的基本概念记忆，属于基础知识的直接回忆和简单理解。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及基础概念记忆（金属密度的数量级变化），但需要学生对\"数量级\"和\"金属密度范围\"有基本理解才能正确选择。不需要复杂计算或深度分析，但比单纯的定义记忆题（等级1）要求稍高，属于概念理解和简单辨析层次。" + }, + { + "idx": 3887, + "question": "The atomic mass of an atom may be expressed as the sum of the masses of (a) Electrons (b) Neutrons (c) Protons (d) Choose all that apply.", + "answer": "(b) Neutrons and (c) Protons", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，并且有明确的选项列表和选择要求（\"Choose all that apply\"）。 | 知识层次: 题目考查原子质量的基本构成，仅需记忆和理解质子与中子的质量贡献，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆原子质量的基本组成（质子和中子）即可作答，无需复杂分析或概念辨析。题目选项设置简单明确，正确选项直接对应基础知识点，属于最简单的难度等级。" + }, + { + "idx": 3888, + "question": "The nucleus of an atom contains electrons?", + "answer": "No, the nucleus of an atom does not contain electrons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案直接给出了判断结果（No）和解释。 | 知识层次: 题目考查原子核组成的基本概念记忆，属于最基础的定义性知识，仅需记忆即可回答。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆原子核的基本组成（质子和中子）即可判断正确选项。题目不涉及概念理解或复杂陈述，属于最基础的知识点考察。" + }, + { + "idx": 3889, + "question": "The nucleus of an atom contains neutrons?", + "answer": "Yes, the nucleus of an atom contains neutrons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Yes/No），符合判断题的特征 | 知识层次: 题目考查原子核基本组成的记忆性知识，属于基础概念层次 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆原子核的基本组成即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 3890, + "question": "The nucleus of an atom contains protons?", + "answer": "Yes, the nucleus of an atom contains protons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"The nucleus of an atom contains protons\"），答案直接给出了判断结果（\"Yes\"），符合判断题的特征。 | 知识层次: 题目考查原子核基本组成的记忆性知识，仅需基础概念认知能力 | 难度: 在选择题型中，该题目仅涉及基础概念的正误判断，即原子核是否包含质子这一基本事实。题目不需要任何复杂推理或概念间的比较分析，仅需记忆性知识即可正确回答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3891, + "question": "The atomic number of an electrically neutral atom is equal to the number of:(a) protons (b) electrons (c) neutrons (d)Choose all that apply.", + "answer": "(b)electrons.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，并且提供了明确的选项(a)-(d)，符合选择题的特征。 | 知识层次: 题目考查原子序数与电子数的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅需直接记忆原子序数与电子数的关系，属于基础概念记忆层次，无需复杂分析或理解多个概念。" + }, + { + "idx": 3892, + "question": "Hafnium has six naturally occurring isotopes: 0.16% of { }^{174} Hf, with an atomic weight of 173.940 amu; 5.26% of { }^{176} Hf, with an atomic weight of 175.941 amu ; 18.60% of { }^{177} Hf, with an atomic weight of 176.943 amu ; 27.28% of { }^{178} Hf, with an atomic weight of 177.944 amu ; 13.62% of { }^{179} Hf, with an atomic weight of 178.946 amu;. and 35.08% of { }^{180} Hf, with an atomic weight of 179.947 amu. Calculate the average atomic weight of Hf. Give your answer to three decimal places.", + "answer": "the average atomic weight of hf is 178.485 amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（各同位素的原子质量与其丰度的加权平均）来求解铪的平均原子量，并给出了具体的计算步骤和精确到小数点后三位的要求。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求根据给定的同位素丰度和原子质量计算平均原子量，这属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目提供了多个同位素的数据，但计算平均原子重量的步骤是直接套用加权平均公式，不需要复杂的推理或多步骤计算。学生只需将各同位素的百分比乘以对应的原子质量，然后相加即可得到结果。因此，在选择题型内，这属于中等偏下的难度。" + }, + { + "idx": 3893, + "question": "Bromium has two naturally occurring isotopes: { }^{79} Br, with an atomic weight of 78.918 amu, and { }^{81} Br, with an atomic weight of 80.916 amu. If the average atomic weight for Br is 79.903 amu, calculate the fraction-of-occurrences of these two isotopes.Give your answer to three decimal places.", + "answer": "the fraction-of-occurrence of { }^{79}\\mathrm{br} is 0.507, and the fraction-of-occurrence of { }^{81}\\mathrm{br} is 0.493.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种同位素的出现分数，答案以具体数值形式给出，需要精确到三位小数。 | 知识层次: 题目需要应用基本的同位素丰度计算公式，进行简单的数值计算，属于直接套用公式的应用层次。虽然涉及多步计算，但思维过程较为直接，不需要复杂的综合分析或推理。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用同位素丰度的基本公式进行计算，但解题步骤相对直接，仅涉及单一公式的套用和简单的代数运算。题目要求计算两种同位素的丰度，属于基本概念的应用，不需要复杂的推理或多步骤的计算。因此，在选择题型内属于等级2的难度。" + }, + { + "idx": 3894, + "question": "An element that has the electron configuration 1 s^{2} 2 s^{2} 2 p^{6} has how many electrons? Enter numeric values only.", + "answer": "9", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的电子构型计算电子总数，需要数值计算，且答案仅要求输入数值。 | 知识层次: 题目考查电子排布的基本概念和简单计算，只需根据给定的电子排布式直接计算电子总数，属于基本公式应用和简单计算范畴。 | 难度: 在选择题型中，该题目仅需要直接计算电子配置中的电子总数，属于单一公式直接计算的简单应用。学生只需将1s²、2s²和2p⁶的电子数相加即可得到答案，无需复杂的推理或多步骤计算。" + }, + { + "idx": 3895, + "question": "The electrons that occupy the outermost filled shell are called electrons.", + "answer": "The electrons that occupy the outermost filled shell are called valence electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（valence electrons），属于需要简短文字回答的简答题类型 | 知识层次: 题目考查基本概念的记忆和理解，即对价电子（valence electrons）的定义的记忆。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即\"valence electrons\"的定义。题目直接给出了定义描述，只需选择正确的术语填空，无需任何解释或复杂分析步骤。这属于最基本的知识点掌握要求，符合等级1的标准。" + }, + { + "idx": 3896, + "question": "When all the electrons in an atom occupy the lowest possible energy states, the atom is said to be in its: (a)ground state(b)ionized state (c) cold state (d) regular state", + "answer": "(a)ground state", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确的答案，符合选择题的特征。 | 知识层次: 题目考查对原子基态这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆类型。题目仅考察对\"ground state\"这一基础定义的记忆，无需进行概念辨析或复杂理解，符合等级1的难度标准。" + }, + { + "idx": 3897, + "question": "How many p electrons at the outermost orbital do the Group VIIA elements have?", + "answer": "5 p electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的问题（VIIA族元素最外层有多少p电子），答案是一个简短的具体数值（5 p electrons），不需要计算或选择，属于简答题类型 | 知识层次: 题目考查对VIIA族元素最外层p电子数的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接询问VIIA族元素最外层p电子数，属于基础概念记忆层次，只需记住VIIA族（卤族）元素的最外层电子构型为ns²np⁵即可得出答案。不需要任何分析或推理过程，是选择题中最简单的类型。" + }, + { + "idx": 3898, + "question": "To what group in the periodic table would an element with atomic number 119 belong?(a) Group 0 (or 18) (b) Group IA (or 1) (c) Group IIA (or 2) (d) Group VIIA (or 17)", + "answer": "(b) Group IA (or 1)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查元素周期表分组的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念记忆层次，要求考生记住元素周期表中原子序数与族的关系。虽然需要记忆元素119的归属族，但这是周期表排列的基本规律之一，属于中等偏下的难度。在选择题型中，考生只需识别并回忆相关知识，无需复杂推理或分析。" + }, + { + "idx": 3899, + "question": "Calculate the energy of attraction between a cation with a valence of +2 and an anion with a valence of -2 , the centers of which are separated by a distance of 3.7nm.", + "answer": "-2.5 × 10^{-19} J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算离子间的吸引能），需要使用相关公式，且答案以数值形式给出（-2.5 × 10^{-19} J），这些都是计算题的典型特征。 | 知识层次: 题目要求应用库仑定律公式进行简单的数值计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用库仑定律公式计算离子间的吸引力，属于单一公式直接计算的类型。题目提供了所有必要参数（离子价态、距离），且计算步骤简单，无需复杂的推导或组合多个公式。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3900, + "question": "Materials whose constituent particles are bound by which type of bond are generally expected to have the lowest melting temperatures?(a) Covalent(b) Metallic(c) Ionic(d) Van der Waals(e) Hydrogen", + "answer": "(d) Van der Waals", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项中的一个 | 知识层次: 题目考查对不同类型化学键及其性质的基本概念的记忆和理解，特别是范德华力与其他化学键在熔点方面的差异。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别不同化学键类型及其一般性质（如熔点）。Van der Waals键是最弱的分子间作用力，其熔点最低是直接记忆性知识，无需复杂分析或概念辨析。" + }, + { + "idx": 3901, + "question": "Calculate % IC of the interatomic bonds for the intermetallic compound TiAl3.", + "answer": "0%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算TiAl3金属间化合物的离子键百分比(% IC)，需要使用相关公式进行计算，最终给出数值结果0%。这符合计算题的特征，需要数值计算和公式应用。 | 知识层次: 题目要求计算TiAl3的离子键百分比，这需要应用基本的化学键理论公式进行计算。虽然涉及对离子键和金属键的理解，但计算过程直接且不涉及多步推理或综合分析，属于基本公式的直接应用。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅要求直接套用基本公式（离子键百分比计算公式）进行简单计算，且正确选项为0%可以直接得出无需复杂计算步骤。属于单一公式直接应用的典型简单题目，在选择题型内相对难度极低。" + }, + { + "idx": 3902, + "question": "On the basis of this result what type of interatomic bonding would you expect to be found in TiAl3 ? (a) van der Waals (b) ionic (c) metallic (d) covalent", + "answer": " (c)metallic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项（a-d）中选择一个正确的答案，符合选择题的特征。 | 知识层次: 题目考查对金属间化合物TiAl3中原子间键合类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（金属键的类型），但需要学生理解TiAl3的组成元素特性（钛和铝都是金属元素），并能推断出金属键是主要键合类型。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较多个概念（等级3）。" + }, + { + "idx": 3903, + "question": "Which of the following microstructures is expected to be most similar to a single crystal in terms of structure and properties? Assume all of the options offer the same volumes and only consider grain boundaries as a crystalline defect for this question. (a) Textured polycrystal with about 10,000 grains (b) Random polycrystal with about 1,000,000 grains (c) Random polycrystal with about 1,000,000,000 grains (d) Amorphous", + "answer": "(a) Textured polycrystal with about 10,000 grains", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择最接近单晶结构和性能的微观结构，答案是从给定的选项中选择一个正确答案。 | 知识层次: 题目需要理解单晶和多晶的结构差异，并分析晶粒数量和取向对性能的影响。虽然涉及基础概念，但需要综合分析不同选项的微观结构特征，才能得出最接近单晶的选项。 | 难度: 在选择题中属于较高难度，需要综合理解晶体结构、晶界影响以及织构效应等多个概念。题目要求比较不同微观结构对单晶相似性的影响，涉及多步分析过程：首先需要排除非晶选项（d），然后比较随机多晶与织构多晶的晶界密度差异（b/c vs a），最后评估织构效应对性能的影响。这种综合分析过程超出了简单概念识别的范畴，属于复杂分析判断的题型要求。" + }, + { + "idx": 3904, + "question": "For a metal that has the simple cubic crystal structure, calculate the atomic radius if the metal has a density of 2.05g / {cm}^{3} and an atomic weight of 77.84g / mol.", + "answer": "the atomic radius is 0.122nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解金属的原子半径，答案是一个具体的数值结果（0.122nm），符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括晶体结构、密度、原子量和原子半径的综合计算，涉及公式应用和单位转换，思维过程有一定深度要求。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、密度计算和单位换算等多个概念。解题涉及多步计算（包括晶格常数推导、原子体积计算和半径换算），但选择题型通过选项提供了明确的目标方向，降低了开放题型的复杂度。需要理解简单立方晶体的几何关系（a=2r）并能将宏观密度与微观结构参数相关联，但不需要处理多变量或复杂公式推导。" + }, + { + "idx": 3905, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Determine the crystal structure of the metal.", + "answer": "The metal has an FCC crystal structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定金属的晶体结构，涉及单位晶胞边长、密度和原子量等参数的计算，最终得出FCC晶体结构的结论。 | 知识层次: 题目需要多步计算（包括密度公式应用、单位换算、晶体结构判断），涉及概念关联（晶胞参数、密度、原子量之间的关系），并需要综合分析计算结果来确定晶体结构类型。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生通过给定的晶胞边长、密度和原子量，计算并确定金属的晶体结构。这涉及到多步计算（如计算晶胞中的原子数）和概念关联（如理解FCC、BCC等晶体结构的特点）。虽然题目提供了所有必要的信息，但解题过程需要综合应用多个知识点，并进行一定的推理判断，因此在选择题型中属于中等偏上的难度。" + }, + { + "idx": 3906, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Determine the atomic radius of the metal.", + "answer": "The metal has an atomic radius of 0.155 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如单位晶胞边长、密度和原子量之间的关系）来确定金属的原子半径，答案是一个具体的数值结果（0.155 nm），符合计算题的特征。 | 知识层次: 题目需要多步计算（包括密度公式应用、单位换算和几何关系推导），并需要将晶体结构几何知识与材料物理性质（密度、原子量）关联起来综合分析。虽然不涉及复杂机理或创新设计，但思维过程要求高于简单套用公式。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目涉及单位晶胞边长、密度、原子量等多个参数的综合计算，要求考生掌握晶体结构、密度计算、原子半径与晶格参数的关系等知识点，并进行多步推导和计算。虽然选择题提供了正确选项，但解题过程仍需要较高的综合分析能力和计算技巧。" + }, + { + "idx": 3907, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Indicate the letter of the metal listed in the following table that has these characteristics.", + "answer": "The metal with these characteristics is metal C, which has an atomic radius of 0.155 nm and an FCC crystal structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的金属列表中选择符合特定特征的金属，答案明确指出了具体选项（金属C），符合选择题的特征。 | 知识层次: 题目需要根据给定的晶胞边长、密度和原子量计算金属的特性，并关联到晶体结构（FCC）和原子半径。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算（如单位换算、密度公式应用、晶体结构分析）和概念关联（如将计算出的原子半径与给定选项匹配）。此外，题目还要求综合分析晶体结构（FCC）与原子半径的关系，超出了基础概念记忆的范畴，属于复杂分析过程的判断。" + }, + { + "idx": 3908, + "question": "If the atomic radius of a metal that has the body-centered cubic crystal structure is 0.181nm, calculate the volume of its unit cell.", + "answer": "the volume of the unit cell is 0.0271 nm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案是一个具体的数值结果。 | 知识层次: 题目考查基本公式应用和简单计算，直接套用体心立方晶胞体积的计算公式即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算体心立方晶体结构的单位晶胞体积，只需应用已知的原子半径和体心立方晶体的几何关系公式（V = (4r/√3)^3）进行简单计算即可得出答案。无需多个公式组合或复杂推导，属于基础级别的应用。" + }, + { + "idx": 3909, + "question": "If the atomic radius of a metal that has the face-centered cubic crystal structure is 0.123nm, calculate the volume of its unit cell.", + "answer": "\\[\nv_{c}=0.258nm^{3}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案是一个具体的数值结果。 | 知识层次: 题目要求应用面心立方晶体结构的基本公式计算单位晶胞体积，属于直接套用公式的简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用面心立方晶体结构的单位晶胞体积公式（Vc = (4r/√2)^3），并进行简单的数值计算。题目提供了所有必要的信息（原子半径r=0.123nm），且无需额外的推导或组合公式。因此，在选择题型内属于最低难度等级，即单一公式直接计算。" + }, + { + "idx": 3910, + "question": "Rhodium has an atomic radius of 0.1345nm, a density of (12.41g / {cm}^{3}) and an atomic weight of 102.91 \\mathrm{g} / mol. What is rhodium's crystal structure?(a) Simple cubic(b) \\mathrm{BCC}(c) \\mathrm{FCC}", + "answer": "the crystal structure for rhodium is \\mathrm{fcc}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项(a) Simple cubic、(b) BCC、(c) FCC中选择正确答案 | 知识层次: 题目需要根据给定的原子半径、密度和原子重量，通过多步计算和综合分析来确定晶体的结构。这涉及到对晶体结构类型的基本理解，以及如何将这些参数与理论值进行比较的能力。虽然不涉及复杂的推理或创新应用，但需要一定的计算和概念关联能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生掌握原子半径、密度、原子重量与晶体结构之间的关系。其次，解题过程涉及多步计算，包括计算单位晶胞中的原子数、晶胞体积等，并需要将这些计算结果与不同晶体结构（SC、BCC、FCC）的理论值进行比较。此外，题目还要求考生能够正确应用相关公式和概念，综合分析计算结果才能得出正确答案。因此，该题目在选择题型内属于复杂分析过程的判断，难度等级为4。" + }, + { + "idx": 3911, + "question": "Niobium (Nb) has a BCC crystal structure, an atomic radius of 0.143nm and an atomic weight of 92.91g / mol. Calculate the theoretical density for nb.", + "answer": "the theoretical density for nb is 8.48g / {cm}^{3}. the experimental density for nb is 8.57g / {cm}^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铌的理论密度，涉及原子半径、晶体结构和原子重量等参数的计算过程。答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式应用和简单计算，需要运用BCC晶体结构的密度计算公式，涉及原子半径、原子质量和晶格参数等基本概念的直接套用，思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用BCC晶体结构的密度计算公式，但题目已经提供了所有必要的参数（原子半径、原子重量），并且计算步骤较为直接。不需要多个公式组合或复杂的推导过程，因此难度等级为2。" + }, + { + "idx": 3912, + "question": "Consider the ideal barium titanate \\left(\\mathrm{BaTiO}_{3}\\right) structure. What is the coordination number of the \\mathrm{Ti}^{4+} ion in terms of surrounding \\mathrm{O}^{2-} ions?\n[a] 1\n[b] 2\n[c] 3\n[d] 4\n[e] 5\n[f] 6\n[g] 7\n[h] 8", + "answer": "According to Fig. 3.10, the central \\mathrm{Ti}^{4+} ion is surrounded by six \\mathrm{O}^{2-} ions, one residing at each of the six cube faces.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的多个选项中选择正确答案，且答案明确指出了正确的选项。 | 知识层次: 题目考查对理想钛酸钡结构中Ti4+离子配位数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆理想BaTiO3结构中Ti4+离子的配位数。题目提供了明确的提示（参考图3.10），且正确选项（6）是晶体学中的常见配位数，属于简单概念识别范畴，无需复杂分析或推理。" + }, + { + "idx": 3913, + "question": "Consider the ideal barium titanate \\left(\\mathrm{BaTiO}_{3}\\right) structure. What is the coordination number of the \\mathrm{Ba}^{2+} ion in terms of surrounding \\mathrm{Ti}^{4+} ions?\n[a] 4\n[b] 6\n[c] 8\n[d] 10\n[e] 12", + "answer": "Careful consideration of Fig. 3.10, and consideration of the perovskite compound stoichiometry reveals that 12 \\mathrm{Ti}^{4+} ions surround each \\mathrm{Ba}^{2+} ion. A change in perspective is recommended to help visualize this, where the unit cell cube corners feature \\mathrm{O}^{2-} ions in the corners, \\mathrm{Ti}^{4+} ions centered along each cube edge, and \\mathrm{Ba}^{2+} ions centered in the middle of the cube.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，且提供了多个选项供选择。答案部分也明确指出了正确的选项。 | 知识层次: 题目考查对理想钛酸钡晶体结构中离子配位数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目需要理解钙钛矿结构的基本组成和离子排列方式，但不需要复杂的分析或计算。虽然需要记忆BaTiO3的结构特点，但通过简单的空间想象和结构示意图即可得出正确答案。因此，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3914, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell edge lengths?\n\\[\na=b=c\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "For both cubic and rhombohedral crystal systems all the unit cell edge lengths are equal.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定条件的晶体系统，答案也是从给定的选项中选择的。 | 知识层次: 题目考查对晶体系统基本概念的记忆和理解，特别是对立方和菱方晶系单元边长关系的识别。 | 难度: 在选择题型内，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生对晶体系统的定义和分类有一定的理解和辨析能力。题目要求考生识别哪些晶体系统的晶胞边长满足a=b=c的关系，这需要考生不仅记住各个晶体系统的特点，还需要进行简单的比较和分析。因此，相较于直接记忆的简单概念识别（等级1），该题目更偏向于概念理解和简单辨析（等级2）。" + }, + { + "idx": 3915, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell edge lengths?\n\\[\na=b \\neq c\n\\](a) Cubic(b) Hexagonal(c) Tetragonal\n\\mathrm{d}) Rhombohedral(e) Orthorhombic(f) Monoclinic (g) Triclinic", + "answer": "For both hexagonal and tetragonal crystal systems two of the unit cell edge lengths are equal to one another, but unequal to the third length.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定条件的晶体系统，答案明确给出了符合条件的选项，符合选择题的特征。 | 知识层次: 题目考查对晶体系统基本特征和分类的记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆不同晶系的晶胞边长关系，但题目明确给出了关键特征（a=b≠c），并提供了选项供选择。考生只需识别并匹配Hexagonal和Tetragonal两种晶系的特征即可，不需要进行复杂的分析或推导。这属于基础概念记忆和简单辨析的范畴。" + }, + { + "idx": 3916, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell e edge lengths?a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "For orthorhombic, monoclinic and triclinic crystal systems, all three of the unit cell edge lengths are unequal to one another.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定条件的晶体系统，属于选择题类型 | 知识层次: 题目考查对晶体系统基本分类和单元晶胞边长关系的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个晶体系统的定义和分类，但正确选项明确指出了三个晶体系统的共同特征（所有三个晶胞边长互不相等）。这要求考生不仅记忆各个晶体系统的基本定义，还需要进行简单的概念辨析和比较。然而，由于题目提供了明确的选项和正确选项的直接描述，解题步骤相对简单，不需要复杂的推理或深度理解多个概念之间的关系。因此，难度等级为2。" + }, + { + "idx": 3917, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?\n\\[\n\\alpha \\neq \\beta \\neq \\gamma \\neq 90^{\\circ}\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "Triclinic is the only crystal system for which none of the interaxial angles are equal to one another and also not equal to 90^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的正确答案 | 知识层次: 题目考查对晶体系统基本概念的记忆和理解，特别是对各晶系轴角关系的识别。 | 难度: 在选择题型中，该题目需要考生理解不同晶系的基本定义和特征，特别是对晶轴角度关系的记忆和简单辨析。虽然题目涉及多个晶系的比较，但正确选项（Triclinic）的特征较为明确，属于基础概念记忆和简单辨析的范畴，不需要复杂的分析或深度理解。因此，难度等级为2。" + }, + { + "idx": 3918, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?(a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic\ng) Triclinic", + "answer": "Cubic, tetragonal and orthorhombic crystal systems all have the three interaxial angles equal to 90^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的选项，答案给出了具体的选项组合，符合选择题的特征。 | 知识层次: 题目考查对晶体系统基本特征（晶轴角度关系）的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个晶体系统的记忆，但只需要识别具有特定角度关系（三个轴间角均为90度）的系统。这需要一定的概念理解和简单辨析能力，但不需要复杂的分析或深度理解。" + }, + { + "idx": 3919, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?\n\\[\n\\alpha=\\beta=90^{\\circ}, \\gamma=120^{\\circ}\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "Only the hexagonal crystal system has two of the interaxial angles equal to 90^{\\circ}, while the third angle is equal to 120^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的正确答案 | 知识层次: 题目考查对晶体系统基本参数（轴角关系）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆不同晶系的轴角关系，但题目明确给出了具体的角度条件，只需将条件与各晶系的基本定义进行匹配即可。不需要复杂的分析或推导，属于基础概念理解和简单辨析的范畴。" + }, + { + "idx": 3922, + "question": "Polyethylene may be fluorinated by inducing the random substitution of fluorine atoms for hydrogen. For this polymer, determine the concentration of F (in wt %) that must be added if this substitution occurs for 18.6 % of all of the original hydrogen atoms. Atomic weights for several elements are included in the following table: Carbon 12.01 g/mol, Chlorine 35.45 g/mol, Fluorine 19.00 g/mol, Hydrogen 1.008 g/mol, Oxygen 16.00 g/mol.", + "answer": "the concentration of F that must be added is 18.0 wt %.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定氟的浓度（wt%）。解答过程涉及原子量的计算和百分比转换，最终给出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括确定聚乙烯的重复单元、计算氢原子被氟原子替代的比例、计算氟原子的质量百分比等。这涉及到多个概念的关联和综合分析，而不仅仅是简单的公式应用或基础概念的记忆。 | 难度: 在选择题中属于中等偏上难度，需要理解聚合物氟化反应的概念，进行多步计算（包括原子质量计算、百分比转换等），并综合分析氢原子替换比例与最终氟含量的关系。虽然题目提供了原子质量数据，但解题过程涉及多个计算步骤和概念关联，比单纯记忆或简单计算题更复杂。" + }, + { + "idx": 3923, + "question": "Polyethylene may be fluorinated by inducing the random substitution of fluorine atoms for hydrogen. For this polymer, determine the concentration of F (in wt %) that must be added to completely fluorinate the material, i.e. to produce polytetrafluoroethylene (PTFE). Atomic weights for several elements are included in the following table: Carbon 12.01 g/mol, Chlorine 35.45 g/mol, Fluorine 19.00 g/mol, Hydrogen 1.008 g/mol, Oxygen 16.00 g/mol.", + "answer": "the concentration of F required to completely fluorinate the material is 76.0 wt %.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氟的浓度（wt %），需要用到原子重量和化学计量关系进行计算，最终给出一个具体的数值答案。 | 知识层次: 题目需要进行基本的化学计量计算，涉及原子质量和重量百分比的计算，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目要求应用基本公式进行简单计算，仅需理解聚乙烯完全氟化后生成聚四氟乙烯的化学结构变化，并套用原子量计算氟的质量百分比。解题步骤直接，无需复杂分析或多公式组合。" + }, + { + "idx": 3924, + "question": "Which of the following may form linear polymers?(a) Rubber(b) Epoxy(c) Polyethylene(d) Phenol-formaldehyde(e) Polystyrene(f) Nylon", + "answer": "Polyethylene, polystyrene and nylon may form linear polymers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择可能形成线性聚合物的材料，答案给出了具体的选择结果 | 知识层次: 题目考查对线性聚合物基本概念的记忆和理解，要求识别哪些材料可以形成线性聚合物，属于基础概念的记忆性知识。 | 难度: 该题目属于选择题型，考察的是对线性聚合物基本概念的识别和简单辨析。虽然需要记忆不同类型聚合物的结构特征，但选项中的聚乙烯、聚苯乙烯和尼龙都是典型的线性聚合物例子，属于基础材料科学知识。题目不涉及复杂概念区分或深度理解，只需对常见聚合物类型进行正确归类即可。因此，在选择题型内属于中等偏下难度（等级2）。" + }, + { + "idx": 3925, + "question": "Which of the following form network polymers?(a) Rubber(b) Epoxy(c) Polyethylene\nd) Phenol-formaldehyde(e) Polystyrene(f) Nylon\n\\", + "answer": "Epoxy and phenol-formaldehyde form network polymers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择能够形成网络聚合物的材料，答案给出了具体选项，符合选择题的特征 | 知识层次: 题目考查对聚合物类型（网络聚合物）的基本概念记忆和分类理解，不需要复杂的分析或计算。 | 难度: 在选择题型中，此题需要考生理解\"network polymers\"的定义特征，并能将其与线性/支化聚合物区分。虽然涉及多个选项，但只需识别出具有三维交联结构的聚合物(环氧树脂和酚醛树脂)，不需要复杂的分析过程。属于基础概念理解和简单辨析的难度层级。" + }, + { + "idx": 3926, + "question": "For most polymers, which configuration predominates?(a) Head-to-head(b) Head-to-tail", + "answer": "For most polymers, the head-to-tail configuration predominates.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项(a) Head-to-head和(b) Head-to-tail中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对聚合物基本构型（head-to-head和head-to-tail）的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆聚合物最常见的构型（头-尾构型）即可作答。题目选项简单明确，无需复杂分析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 3927, + "question": "Is it possible to produce a polymer that is 100% crystalline? (a) True (b) False", + "answer": "False. It is not possible to produce a polymer that is 100% crystalline. The maximum crystallinity that can be obtained is about 95%, with the remaining material being amorphous.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目以判断陈述对错的形式提问，要求选择True或False作为答案，符合判断题的特征。 | 知识层次: 题目考查对聚合物结晶度的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接询问聚合物是否可以100%结晶，正确选项明确给出了基础定义和基本原理（聚合物最大结晶度约为95%）。这只需要学生对聚合物结晶度的基本概念有记忆性了解即可回答，无需深入理解或分析多个概念。因此属于选择题型中最基础的难度等级。" + }, + { + "idx": 3928, + "question": "The number of vacancies in some hypothetical metal increases by a factor of 5 when the temperature is increased from 1040 K to 1150 K. Calculate the energy (in kj/mol ) for vacancy formation assuming that the density of the metal remains the same over this temperature range.", + "answer": "the energy for vacancy formation is 115 kj/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺形成能，答案是一个具体的数值结果（115 kj/mol），符合计算题的特征。 | 知识层次: 题目需要应用空位形成能的计算公式，涉及多步计算和温度对空位数的影响分析，需要理解并关联相关概念，但不需要复杂的推理或深度分析。 | 难度: 在选择题中属于中等偏上难度，需要理解空缺形成能的概念，并应用阿伦尼乌斯方程进行多步计算。题目涉及温度变化对空缺浓度的影响，要求考生能够综合运用热力学和材料科学知识进行推导和计算。虽然题目提供了正确选项，但解题过程需要一定的综合分析能力和数学运算技巧。" + }, + { + "idx": 3929, + "question": "The number of vacancies present in some metal at 864^{\\circ} C is 1.1 × 10^{24}{m}^{-3}. Calculate the number of vacancies at 463^{\\circ} C given that the energy for vacancy formation is 1.25 \\mathrm{eV} / atom; assume that the density at both temperatures is the same", + "answer": "the number of vacancies at 463^{\\circ} C is 5.45 × 10^{22}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如阿伦尼乌斯方程）来求解特定温度下的空位数量，答案是一个具体的数值结果。 | 知识层次: 题目需要应用阿伦尼乌斯公式计算不同温度下的空位浓度，涉及多步计算和温度对空位形成的影响，需要理解公式中各参数的含义并进行适当的单位转换和数值计算。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，包括温度转换、能量单位转换、以及使用阿伦尼乌斯方程计算空位浓度。虽然题目提供了正确选项，但解题过程需要综合运用多个知识点，包括热力学和材料科学的基础知识。" + }, + { + "idx": 3930, + "question": "In metals, there are significantly more vacancies than self-interstitials.(a) True(b) False", + "answer": "True. In metals, there are significantly more vacancies than self-interstitials; the reason for this is that the atom is significantly larger than the interstitial position in which it is situated, and, consequently significant lattice strains result.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附有简要解释。 | 知识层次: 题目考查金属中空位和自间隙原子数量的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆金属中空位和自间隙原子的相对数量关系即可作答，无需深入理解或分析。" + }, + { + "idx": 3931, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for MgO.", + "answer": "For MgO, the ionic radii of the Mn2+ and Mg2+ are 0.067 nm and 0.072 nm, respectively. Therefore the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.072 nm - 0.067 nm) / 0.072 nm × 100 = 6.9%, which value is within the acceptable range for a high degree of solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么MgO能与MnO形成完全固溶体，需要基于离子半径差异进行文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用离子半径差异的计算公式，并结合溶解度规则进行综合分析，涉及多步计算和概念关联。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道离子半径的概念，还需要计算百分比差异，并理解这一差异对固溶体溶解度的影响。虽然涉及多步计算和概念关联，但在选择题型中，这些步骤相对直接，且不需要深度论述或多角度分析。" + }, + { + "idx": 3932, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for CaO.", + "answer": "For CaO, the ionic radii of the Mn2+ and Ca2+ are 0.067 nm and 0.100 nm, respectively. Therefore, the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.100 nm - 0.067 nm) / 0.100 nm × 100 = 33%. This Δr% value is much larger than the ±15% range, and, therefore, CaO is not expected to experience any appreciable solubility in MnO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么CaO不会与MnO形成完全固溶体，答案提供了详细的文字解释和计算过程，属于需要论述的简答题类型。 | 知识层次: 题目需要计算离子半径差异百分比，并基于Hume-Rothery规则进行判断，涉及多步计算和概念关联，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握离子半径的概念，并能计算百分比差异，同时需要了解固溶体溶解度的限制条件（±15%范围）。虽然涉及多步计算和概念关联，但在选择题型中，这些步骤相对直接，不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 3933, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for BeO.", + "answer": "For BeO, the ionic radii of the Mn2+ and Be2+ are 0.067 nm and 0.035 nm, respectively. Therefore, the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.067 nm - 0.035 nm) / 0.067 nm × 100 = 48%. This Δr% value is much larger than the ±15% range, and, therefore, BeO is not expected to experience any appreciable solubility in MnO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释BeO在MnO中的固溶度问题，需要文字论述和解释离子半径差异的影响，符合简答题的特征。 | 知识层次: 题目要求应用离子半径差异百分比的计算公式，并结合固溶体溶解度规则进行分析和解释。虽然计算本身简单，但需要理解离子半径差异对固溶体形成的影响，并进行综合分析判断。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求掌握离子半径的概念，还需要进行多步计算（计算离子半径百分比差异），并综合分析结果与溶解度规则（±15%范围）的关系。此外，题目还隐含了对固溶体形成条件的深入理解，需要将多个知识点关联起来才能正确解答。这种综合分析能力在选择题型中属于较高要求。" + }, + { + "idx": 3934, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for NiO.", + "answer": "For NiO, the ionic radii of the Mn2+ and Ni2+ are 0.067 nm and 0.069 nm, respectively. Therefore, the percentage difference in ionic radii Δr% is determined as follows: Δr% = (0.069 nm - 0.067 nm) / 0.069 nm × 100 = 3%, which value is, of course, within the acceptable range for a high degree of solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释NiO与MnO形成完全固溶体的原因，需要文字论述和解释，而不是简单的选择、判断或计算。 | 知识层次: 题目要求解释NiO与MnO形成完全固溶体的原因，涉及离子半径的计算和百分比差异的分析。虽然计算简单，但需要理解固溶体形成的条件（如离子半径差异的允许范围），并能够将计算结果与理论条件关联起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握离子半径的概念，并能计算百分比差异，同时需要理解溶解度与离子半径差异之间的关系。虽然涉及多步计算和概念关联，但在选择题型中，这些步骤相对直接，且选项通常会提供明确的提示。因此，难度属于等级3。" + }, + { + "idx": 3935, + "question": "Which of these elements would you expect to form a substitutional solid solution having complete solubility with copper? The elements are: Ni, O, H, Pt, Pd, Co, C, Zn, Ag, Al, Cr, Fe. The criteria for complete solubility are: 1) the difference in atomic radii between Cu and the other element must be less than ±15%, 2) the crystal structures must be the same, 3) the electronegativities must be similar, and 4) the valences should be the same, or nearly the same.", + "answer": "Ni, Pd, and Pt meet all of the criteria and thus form substitutional solid solutions having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据给定的标准（原子半径差异、晶体结构、电负性和价态）分析多个元素，并解释哪些元素满足所有条件形成完全固溶体。答案需要详细的文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目要求应用多个标准（原子半径差异、晶体结构、电负性、价态）来筛选元素，涉及多步分析和概念关联。虽然不涉及复杂计算，但需要对材料科学中的固溶体形成条件有较深入的理解和综合应用能力。 | 难度: 在选择题中属于较高难度，需要综合考虑多个因素（原子半径差异、晶体结构、电负性、价态）并进行多步分析。题目要求考生不仅掌握基本概念，还需要能够将这些概念关联起来，对不同元素进行系统性比较。此外，题目还涉及高温条件下的同素异形转变（Co和Fe），增加了分析的复杂性。虽然题目提供了明确的选择范围，但正确选项的确定需要深入理解和综合应用材料科学原理。" + }, + { + "idx": 3936, + "question": "Which of these elements would you expect to form a substitutional solid solution of incomplete solubility with copper? The elements are: Pd, Al, Cr, Fe, H, Pt, Ni, Zn, C, Ag, O, Co. The criteria for incomplete solubility are: these metals have either BCC or HCP crystal structures, and/or the difference between their atomic radii and that for Cu are greater than ±15%, and/or have a valence different than 2+.", + "answer": "Ag, Al, Co, Cr, Fe, and Zn form substitutional solid solutions of incomplete solubility. All these metals have either BCC or HCP crystal structures, and/or the difference between their atomic radii and that for Cu are greater than ±15%, and/or have a valence different than 2+.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素列表中选择符合特定条件的元素，属于从多个选项中选择正确答案的类型。答案明确列出了符合条件的元素，符合选择题的特征。 | 知识层次: 题目要求根据给定的元素和条件（晶体结构、原子半径差异、化合价）来判断哪些元素与铜形成不完全固溶体。这需要理解固溶体的形成条件，并能将这些条件应用到具体元素的分析中。虽然涉及多个知识点（晶体结构、原子半径、化合价），但主要是对这些条件的直接应用和综合分析，属于中等应用层次。 | 难度: 在选择题型中属于较高难度，需要综合应用多个材料科学概念（晶体结构、原子半径差异、化合价）进行判断。题目要求考生不仅掌握各元素的晶体结构类型，还需计算原子半径差异并分析化合价影响，涉及多步复杂分析过程。正确选项需要同时满足多个条件，属于复杂分析过程的判断题型。" + }, + { + "idx": 3937, + "question": "Which of these elements would you expect to form an interstitial solid solution with copper? The elements are: C, Pd, Pt, H, Cr, O, Zn, Ag, Al, Co, Fe, Ni. The criteria for interstitial solid solutions are: these elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的元素列表中选择符合特定条件（原子半径显著小于铜）的元素，这符合选择题的特征，即从多个选项中选择正确答案。 | 知识层次: 题目考查对间隙固溶体形成条件的记忆和理解，即哪些元素的原子半径显著小于铜的原子半径。这属于基础概念的记忆性知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目需要考生理解间隙固溶体的定义和形成条件，即溶质原子半径必须显著小于溶剂原子半径。虽然题目给出了多个选项，但正确选项（C, H, O）可以通过记忆或简单比较原子半径得出。因此，该题目属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3938, + "question": "The concentration of carbon in an iron-carbon alloy is 0.57 wt%. What is the concentration in kilograms of carbon per cubic meter of alloy? The densities of iron and carbon are 7.87 and 2.25 \\mathrm{g} / {cm}^{3}, respectively.", + "answer": "the concentration of carbon is 11.8 kg / m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及浓度转换和密度计算，最终需要得出具体的数值结果（11.8 kg/m³）。答案形式为计算得出的具体数值，而非选择、判断或文字解释。 | 知识层次: 题目需要进行多步计算，涉及质量分数转换、密度计算和单位换算，需要综合运用多个概念和公式，但不需要复杂的推理或创新思维。 | 难度: 在选择题中属于中等偏上难度，需要理解质量分数与体积浓度的转换，涉及密度计算和单位换算，属于综合性计算问题。虽然题目给出了关键数据，但解题过程需要多步骤计算和概念关联，对学生的应用能力有一定要求。" + }, + { + "idx": 3939, + "question": "13}\nSome hypothetical alloy is composed of 12.5 wt% of metal A and 87.5 wt% of metal B. If the densities of metals A and \\mathrm{B} are 4.27 and 6.35g / {cm}^{3}, respectively, whereas their respective atomic weights are 61.4 and 125.7g / mol, determine whether the crystal structure for this alloy is simple cubic, facercentered cubic, or body-centered cubic. Assume a unit cell edge length of 0.395nm.", + "answer": "the crystal structure is body-centered cubic.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定合金的晶体结构类型，涉及密度、原子重量和晶胞边长等参数的计算。答案是基于计算结果得出的具体晶体结构类型，而非从选项中选择或简单的对错判断。 | 知识层次: 题目需要进行多步计算，包括质量分数转换为原子分数、计算单位晶胞中的原子数，并结合晶体结构的知识进行综合分析。虽然不涉及复杂的推理或机理解释，但需要关联多个概念并进行中等难度的计算。 | 难度: 在选择题中属于高难度，需要综合运用多个概念并进行复杂计算。题目涉及重量百分比、密度、原子量、晶体结构等多个知识点，解题步骤包括计算平均密度、摩尔分数、单位晶胞中的原子数等多个步骤，且需要综合分析计算结果与晶体结构的关系。这种多变量、多步骤的计算问题在选择题型中属于较复杂的难度水平。" + }, + { + "idx": 3940, + "question": "17}\nIron and vanadium both have the BCC crystal structure andV forms a substitutional solid solution in \\mathrm{Fe} for concentrations up to approximately 20 wt%V at room temperature. Determine the concentration in weight percent ofV that must be added to iron to yield a unit cell edge length of 0.289nm.", + "answer": "the concentration of \\mathrm{v} that must be added to iron to yield a unit cell edge length of 0.289nm is 12.9 wt%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定必须添加到铁中的钒的浓度，以产生特定的晶胞边长。答案是一个具体的数值（12.9 wt%），这表明需要进行计算才能得出结果。 | 知识层次: 题目需要进行多步计算，包括应用BCC晶体结构的单位晶胞边长与原子半径的关系，以及固溶体中原子半径变化对晶格常数的影响。此外，还需要将原子百分比转换为重量百分比，涉及多个概念的综合应用和计算步骤。 | 难度: 在选择题中属于中等难度，需要理解BCC晶体结构、固溶体概念，并进行多步计算，包括原子质量、晶格常数和浓度转换等综合分析。" + }, + { + "idx": 3941, + "question": "Which of the following is a (are) linear defect(s)?(a) An edge dislocation(b) A Frenkel defect(c) A Schottky defect", + "answer": "Edge and screw dislocations are linear defects.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择线性缺陷的正确答案，符合选择题的特征 | 知识层次: 题目考查对线性缺陷（linear defects）这一基本概念的记忆和理解，要求从选项中识别出属于线性缺陷的类型。这属于材料科学中晶体缺陷分类的基础知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（线性缺陷的定义），但需要考生能够区分不同类型的晶体缺陷（线性缺陷、点缺陷等）。正确选项明确指出了边缘位错属于线性缺陷，但题目中混入了点缺陷选项（Frenkel缺陷和Schottky缺陷），这要求考生不仅要记住定义，还要具备简单的概念辨析能力。不过题目没有涉及更复杂的分析或综合应用，因此难度等级为2。" + }, + { + "idx": 3942, + "question": "A photomicrograph was taken of a specimen at a magnification of 100 ×, and it was determined that the average number of grains per square inch was 200 . What is this specimen's ASTM grain size number?", + "answer": "the specimen's astm grain size number is 4.9.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数值，答案是一个具体的数值结果（4.9），这表明解答过程涉及计算步骤。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，仅需一步计算即可得出结果，属于直接套用公式的简单应用层次。 | 难度: 在选择题中属于简单难度，需要应用基本公式进行计算，但仅涉及单一公式的直接套用和简单计算步骤。" + }, + { + "idx": 3943, + "question": "Diffusion by which mechanism occurs more rapidly in metal alloys?(a) Vacancy diffusion(b) Interstitial diffusion", + "answer": "In metal alloys, interstitial diffusion takes place more rapidly than vacancy diffusion because the interstitial atoms are smaller and are more mobile. Also, there are more vacant adjacent interstitial sites than there are vacancies.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对金属合金中扩散机制的基础概念记忆和理解，仅需区分空位扩散和间隙扩散的基本特点，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解两种扩散机制（空位扩散和间隙扩散）的基本概念，但题目已经明确指出了关键区别（间隙原子更小、更易移动，且间隙空位更多），只需进行简单的概念辨析即可选出正确答案。不需要复杂的分析或推导过程，属于基础概念理解和简单辨析层次。" + }, + { + "idx": 3944, + "question": "As temperature decreases, the fraction of total number of atoms that are capable of diffusive motion(a) increases.(b) decreases.", + "answer": "As temperature decreases, the fraction of the total number of atoms that are capable of diffusive motion decreases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对温度与原子扩散能力关系这一基本概念的记忆和理解，属于材料科学中最基础的知识点。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆温度对原子扩散能力的影响这一基本原理，无需复杂辨析或深度理解。" + }, + { + "idx": 3945, + "question": "If [m] atoms of helium pass through a [a] square meter plate area every [t] hours, and if this flux is constant with time, compute the flux of helium in units of atoms per square meter per second.", + "answer": "\\[\nj = \\frac{[m]}{[a] × [t] × 3600} \\text{ atoms per square meter per second}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以求得氦的通量，答案给出了具体的计算公式和单位转换步骤。 | 知识层次: 题目要求将给定的物理量（原子数、面积、时间）通过基本公式转换为特定单位（原子/平方米/秒）的流量，属于直接套用单位换算公式的简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个简单的公式进行计算，即通过给定的原子数量、面积和时间，转换为每秒每平方米的原子通量。解题步骤非常直接，不涉及多个公式的组合或复杂的逻辑推理，符合等级1的单一公式直接计算标准。" + }, + { + "idx": 3946, + "question": "If water molecules pass through a membrane with a steady state flux of [j] mole /\\left(m^{2}\\right. day ), how long will it take, in hours, for [m] kg of water to pass through a [\\mathrm{a}] square centimeter of the membrane?", + "answer": "\\[\nt = \\frac{[m] × 1000 × 24}{[a] × [j] × 18 × 10000} \\text{ hours}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解具体的时间值，答案给出了具体的计算公式和单位转换步骤，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的参数代入公式进行转换和计算，但不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解稳态通量的概念并进行单位转换，但解题步骤相对直接，主要涉及单一公式的套用和简单的数学计算。不需要复杂的逻辑推理或多步骤推导，因此难度等级为2。" + }, + { + "idx": 3947, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the contact lens thickness likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "If the contact lens thickness is increased and all other factors are preserved, the concentration gradient decrease and the oxygen diffusion flux should decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的解释和推理过程，而不是简单的选择或判断。 | 知识层次: 题目需要理解扩散通量的概念，并分析厚度变化对浓度梯度和扩散通量的影响，涉及多步推理和概念关联，但不需要复杂的综合或创新应用。 | 难度: 在选择题中属于中等难度，需要理解扩散通量、浓度梯度以及接触镜厚度之间的关系，并进行综合分析。题目要求考生能够将多个概念关联起来，并预测厚度变化对氧气传输的影响，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 3948, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the diffusivity of oxygen gas by decreasing the contact lens porosity likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "If the lens features more voids, we expect the oxygen to permeate the membrane faster since oxygen should be able to transit voids faster than the bulk lens material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行解释和论述，答案提供了详细的文字解释，而非简单的选择、判断或计算。 | 知识层次: 题目需要理解扩散通量与孔隙率的关系，并应用扩散原理分析实际问题。虽然不涉及复杂计算，但需要将多个概念（扩散通量、孔隙率、稳态流动）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解扩散通量、孔隙率对扩散系数的影响以及稳态流动条件。题目要求分析接触镜孔隙率变化如何影响氧气扩散速率，并关联到实际应用中的氧气流量需求。解题步骤涉及多步概念关联和综合分析，超出了简单记忆或单一概念应用的层次。" + }, + { + "idx": 3949, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the ambient temperature likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "Increasing the temperature should increase the diffusivity and therefore increase the diffusion flux and flow rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述温度对氧气扩散速率的影响，答案提供了文字解释而非选择、判断或计算。 | 知识层次: 题目需要理解扩散通量和流量的关系，并应用温度对扩散系数的影响来推导结果。这涉及到多步概念关联和综合分析，但不需要复杂的推理或深度理解。 | 难度: 在选择题中属于中等难度，需要理解扩散通量、温度对扩散系数的影响以及稳态流动速率之间的关系，并进行综合分析。虽然题目涉及多个概念，但解题步骤相对直接，不需要复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 3950, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the ambient partial pressure of oxygen gas likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "Increasing the concentration of oxygen in the ambient environment will increase the concentration gradient, thereby increasing the diffusion flux of oxygen.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么增加氧气分压会增加扩散通量，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查的是扩散通量与浓度梯度之间的基本关系，属于直接应用基本原理（菲克定律）来解释现象。虽然需要理解扩散通量的定义和影响因素，但不需要多步计算或综合分析，属于简单应用层次。 | 难度: 在选择题中属于简单应用过程描述，题目直接考察对扩散通量公式的理解和应用，仅需识别浓度梯度增加会导致扩散通量增加这一基本原理，无需复杂计算或多步骤推理。" + }, + { + "idx": 3951, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 16h duration at 757^{\\circ} C will raise the carbon concentration to 0.5 wt% at a point 2.3mm from the surface. Estimate the time necessary to achieve the same concentration at a 8mm position for an identical steel and at a carburizing temperature of 1130^{\\circ} C. Assume that D_{0} is 4.6 × 10^{-5}{m}^{2} / s and Q_{d} is 104kJ / mol.", + "answer": "the time necessary to achieve the same concentration at a 8mm position for an identical steel and at a carburizing temperature of 1130^{\\circ} C is 17.9h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和温度对扩散系数的影响，最终需要计算出一个具体的时间值（17.9h）。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和温度对扩散系数的影响公式，并进行综合分析。虽然不涉及复杂的机理解释或创新设计，但需要一定的计算能力和对扩散过程的理解。 | 难度: 在选择题中属于高难度，需要综合运用扩散方程、温度对扩散系数的影响、以及时间与扩散距离的关系等多个概念进行多步骤计算。题目涉及复杂的多变量计算和综合分析，要求考生具备较强的材料科学基础和数学计算能力。" + }, + { + "idx": 3952, + "question": "The diffusion coefficient for aluminum in silicon is D_{\\mathrm{Al}} in_{\\mathrm{Si}}=3 × 10^{-16} cm^{2} / s at 300 K (note that 300 K is about room temperature).\nWhat is a reasonable value for D_{\\mathrm{Al} \\text { in } \\mathrm{Si}} at 600 K ?\nNote: Rather than performing a specific calculation, you should be able to justify your answer from the options below based on the mathematical temperature dependence of the diffusion coefficient.\n(a) D<3 × 10^{16} cm^{2} / s\n(b) D=3 × 10^{16} cm^{2} / s\n(c) D=6 × 10^{16} cm^{2} / s\n(d) D=1.5 × 10^{16} cm^{2} /{s}\n(e) D>6 × 10^{16} cm^{2} /\n(f) D=6 × 10^{-17} cm^{2} / s", + "answer": "We expect the diffusion coefficient to increase if the temperature of this system is increased. Therefore, options (a), (b), (d), and (f) are eliminated.\nFurthermore, we expect that since the diffusion coefficient is exponentially dependent on temperature, the diffusivity should increase by more than a factor of two if the absolute temperature is doubled.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项中选择一个合理的扩散系数值，并基于扩散系数的温度依赖性进行判断。答案通过排除法选择了正确的选项。 | 知识层次: 题目要求基于扩散系数的温度依赖性进行合理推断，需要理解扩散系数与温度的指数关系，并能够应用这一知识进行逻辑推理，排除不合理的选项。这涉及多步思维过程和对概念的综合应用，但不需要复杂的计算或深度机理分析。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。首先，考生需要理解扩散系数与温度的指数依赖关系，并能够推断温度升高会导致扩散系数增加。其次，考生需要排除不符合这一基本趋势的选项（a, b, d, f）。最后，考生需要进一步判断扩散系数的增加幅度是否超过线性比例（温度加倍时扩散系数的增加是否超过两倍），从而在剩余选项（c, e）中做出正确选择。这一过程涉及多步逻辑推理和对温度依赖关系的深入理解，因此在选择题型中属于较高难度。" + }, + { + "idx": 3953, + "question": "A specimen of some metal having a rectangular cross section 11.2mm × 12.4mm is pulled in tension with a force of 31200N, which produces only elastic deformation. Given that the elastic modulus of this metal is 63 \\mathrm{GPa}, calculate the resulting strain.", + "answer": "the resulting strain is 2.92 × 10^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，通过给定的力和弹性模量计算应变，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的弹性模量公式应用和简单计算，仅需一步计算即可得出结果，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用胡克定律的基本公式（应变=应力/弹性模量），并进行简单的单位换算和计算。题目提供了所有必要的数据，且解题步骤非常直接，无需组合多个公式或进行复杂的分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3954, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 277 MPa and the modulus of elasticity is 117 GPa. What is the maximum load that may be applied to a specimen having a cross-sectional area of 327 mm^2 without plastic deformation?", + "answer": "the maximum load that may be applied without plastic deformation is 86,700 N.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应力、弹性模量和横截面积的关系）来求解最大载荷，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的应力计算和弹性模量的概念，只需要应用简单的公式（应力=力/面积）进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（应力=力/面积）进行计算，无需组合多个公式或进行复杂的概念分析。解题步骤简单，属于基础级别的难度。" + }, + { + "idx": 3955, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 277 MPa and the modulus of elasticity is 117 GPa. If the original specimen length is 148 mm, what is the maximum length to which it may be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen may be stretched without causing plastic deformation is 131.30 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最大拉伸长度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用（胡克定律）和简单计算，仅需一步计算即可得出结果，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求应用胡克定律（Hooke's Law）计算弹性变形范围内的最大长度，仅需一个基本公式（应变=应力/弹性模量）和简单代数运算即可得出结果。虽然涉及单位换算（MPa到GPa），但步骤直接且无需复杂推导，属于典型的二级难度选择题。" + }, + { + "idx": 3956, + "question": "A steel bar 100mm (4.0 in.) long and having a square cross section 20mm (0.8 in.) on an edge is pulled in tension with a load of 89,000N\\left(20,000 lb_{0}\\right), and experiences an elongation of 0.10mm (4.0 × 10^{-3} in.). Assuming that the deformation is entirely elastic, calculate the elastic modulus of the steel.", + "answer": "the elastic modulus of the steel is 223 \\text{ gpa} (31.3 × 10^6 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钢的弹性模量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求应用胡克定律进行简单的弹性模量计算，仅涉及基本公式的直接套用和单步数值计算，不需要多步推导或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用弹性模量的基本公式（应力/应变），但计算步骤较为直接，仅涉及简单的单位转换和代数运算。题目提供了所有必要的数据，且变形假设为完全弹性，无需考虑复杂情况。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3957, + "question": "13: Typical relationship between E and G}\nFor most metals, the relationship between elastic and shear moduli is approximately which of the following?(a) G=0.1 E(b) G=0.2 E(c) G=0.3 E(d) G=0.4 E(e) G=0.5 E", + "answer": "the relationship between elastic and shear moduli for most metals is approximately g=0.4 e.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对弹性模量和剪切模量之间关系的基本概念记忆，属于基础知识的直接应用，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆弹性模量（E）和剪切模量（G）之间的典型关系即可作答，无需复杂理解或分析。" + }, + { + "idx": 3958, + "question": "A cylindrical rod 380mm (15.0 in.) long and having a diameter of 10.0mm (0.40 in.), is to be subjected to a tensile load of 24,500 N (5500 lbf). Which of the four metals or alloys listed below will not experience plastic deformation under this load? The materials are: Aluminum alloy (Yield Strength: 255 MPa), Brass alloy (Yield Strength: 345 MPa), Copper (Yield Strength: 250 MPa), Steel alloy (Yield Strength: 450 MPa).", + "answer": "The materials that will not experience plastic deformation under the load of 24,500 N are the Brass alloy and Steel alloy, as their yield strengths (345 MPa and 450 MPa, respectively) are greater than the applied stress.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个金属或合金选项中选择不会发生塑性变形的材料，符合选择题的特征 | 知识层次: 题目要求应用基本的应力计算公式（应力=力/面积）来判断材料是否会发生塑性变形，属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（应力=力/面积）计算应力，并与给定材料的屈服强度进行比较。解题步骤简单直接，无需公式变形或多步骤选择，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 3959, + "question": "A cylindrical rod 380mm (15.0 in.) long and having a diameter of 10.0mm (0.40 in.), is to be subjected to a tensile load of 24,500 N (5500 lbf). Which of the four metals or alloys listed below will experience an elongation of no more than 0.9mm (0.035 in.) under this load? The materials are: Aluminum alloy (Modulus of Elasticity: 70 GPa), Brass alloy (Modulus of Elasticity: 100 GPa), Copper (Modulus of Elasticity: 110 GPa), Steel alloy (Modulus of Elasticity: 207 GPa).", + "answer": "The materials that will experience an elongation of no more than 0.9mm under the load of 24,500 N are the Brass alloy, Copper, and Steel alloy, as their calculated elongations (0.57 mm, 0.52 mm, and 0.57 mm, respectively) are less than or equal to 0.9 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算不同材料的伸长量来判断哪些材料满足伸长不超过0.9mm的条件。解答过程需要应用弹性模量和应力-应变关系的公式进行数值计算，最终得出具体数值结果。 | 知识层次: 题目需要进行多步计算（包括应力、应变和伸长量的计算），需要应用胡克定律公式，并综合分析不同材料的弹性模量对伸长量的影响。虽然计算过程相对直接，但涉及多个概念关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解弹性模量的概念，进行多步计算（包括应力、应变和伸长量的计算），并对不同材料的结果进行比较分析。虽然题目提供了必要的参数，但解题过程涉及多个步骤和概念的综合应用。" + }, + { + "idx": 3960, + "question": "Based on the previous two sub-questions, which of the four metals or alloys listed below are possible candidates for the cylindrical rod that will neither experience plastic deformation nor an elongation of more than 0.9mm under a tensile load of 24,500 N?", + "answer": "The only candidate material that satisfies both conditions is the Steel alloy, with an elongation of 0.57 mm.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从四个金属或合金选项中选择符合条件的候选材料，答案明确指出唯一符合条件的材料是钢合金，符合选择题的特征。 | 知识层次: 题目要求在多步计算和综合分析的基础上，从多个候选材料中选择满足特定条件的材料。这需要理解材料的力学性能（如塑性变形和伸长量）并进行相关计算，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合应用多个概念（如塑性变形、弹性伸长、材料性能等）进行多步计算和判断。题目要求考生不仅能够理解材料的基本性能，还需要能够将这些性能与具体工程条件（负载、变形限制）关联起来，进行综合分析。这种需要结合多个知识点和计算步骤的选择题，在选择题型中属于复杂分析过程的判断难度等级。" + }, + { + "idx": 3961, + "question": "A tensile test is performed on a specimen of some metal alloy, and it is found that a true plastic strain of 0.12 is produced when a true stress of 280 MPa is applied. For this alloy, the value of the strain hardening exponent is 0.3 . On the basis of these data what true plastic strain would be expected for a total true plastic stress of 330 MPa ?", + "answer": "the true plastic strain expected for a total true plastic stress of 330 \\text{mpa} is 0.383.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的材料参数（应变硬化指数、真实塑性应变和真实应力）进行计算，以预测在另一个应力水平下的真实塑性应变。解答过程涉及数值计算和公式应用（如应变硬化公式），最终答案是一个具体的数值结果。 | 知识层次: 题目需要应用应变硬化公式进行多步计算，涉及对公式的理解和变形，以及数值计算能力。虽然不涉及复杂的综合分析或机理解释，但需要将给定的参数正确代入公式并求解，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及真实应力-应变关系、应变硬化指数的应用，以及多步骤计算过程。虽然题目提供了必要的数据，但解题过程需要综合运用这些概念和数据进行计算，属于综合性计算问题。" + }, + { + "idx": 3962, + "question": "A cylindrical specimen of a metal alloy 48.8mm long and 9.09mm in diameter is stressed in tension. A true stress of 327 MPa causes the specimen to plastically elongate to a length of 55 mm. If it is known that the strain-hardening exponent for this alloy is 0.3 , calculate the true stress (in MPa )necessary to plastically elongate a specimen of this same material from a length of 48.8mm to a length of 57.6 mm.", + "answer": "390 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应变硬化指数公式）来求解真实应力，最终需要给出具体的数值计算结果（390 MPa）。 | 知识层次: 题目需要进行多步计算，包括应变计算、应变硬化公式的应用以及不同条件下的应力转换。虽然涉及的概念（如应变硬化指数）较为基础，但需要将这些概念关联起来进行综合分析，才能得出最终结果。思维过程需要一定的深度和逻辑性，但不需要进行复杂的机理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及塑性变形、应变硬化指数、真实应力-应变关系等概念的综合运用，解题步骤包括计算初始和最终应变、应用应变硬化公式等，属于多步骤计算过程。虽然题目提供了正确选项，但解题过程需要一定的综合分析能力，因此在选择题型内属于等级3难度。" + }, + { + "idx": 3963, + "question": "A three-point transverse bending test is conducted on a cylindrical specimen of aluminum oxide having a reported flexural strength of 390 MPa (56,600 psi). If the specimen radius is 2.5mm (0.10 in.) and the support point separation distance is 30mm (1.2 in.), predict whether or not you would expect the specimen to fracture when a load of 620 N (140 lbf) is applied.", + "answer": "Since the flexural strength for this test is 379 MPa (53,500 psi), which is less than the reported flexural strength of 390 MPa, fracture is not predicted. However, there is some chance of fracture due to variability in material strength.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来预测材料是否会断裂，涉及使用给定的参数（如半径、支撑点间距、载荷）和材料强度进行数值计算，最终得出结论。答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括应力公式应用和强度比较），并综合分析测试条件与材料性能的关系，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握弯曲强度的概念，并能进行多步计算来比较实际测试强度与报告强度。虽然题目提供了所有必要的数据，但需要考生正确应用公式并理解计算结果的含义。此外，题目还涉及材料强度的变异性，增加了综合分析的要求。" + }, + { + "idx": 3964, + "question": "Calculate the value of flexural strength for this test given a cylindrical specimen of aluminum oxide with a radius of 2.5mm (0.10 in.) and a support point separation distance of 30mm (1.2 in.) when a load of 620 N (140 lbf) is applied.", + "answer": "The flexural strength for this test is 379 MPa (53,500 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（圆柱形试样的半径、支撑点间距和施加的载荷）计算弯曲强度，需要使用相关公式进行数值计算。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查对弯曲强度公式的直接应用和简单计算，不需要多步推理或综合分析，属于基本公式套用和单位换算的范畴。 | 难度: 在选择题型内，该题目属于简单公式应用计算。虽然需要应用弯曲强度的基本公式，但题目已经提供了所有必要的参数（半径、支撑点距离、载荷），只需直接套用公式进行计算即可。不需要多个公式组合或复杂推导，属于选择题型中中等偏下的难度。" + }, + { + "idx": 3965, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{cc} \\hline \\sigma_{\\mathrm{fs}} (MPa) & \\mathbf{P} \\ \\hline 100 & 0.05 \\ 50 & 0.20 \\ \\hline \\end{tabular} (a) Compute the flexural strength for a completely nonporous specimen of this material.", + "answer": "the flexural strength for a completely nonporous specimen of this material is 126 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据（弯曲强度和孔隙率）进行计算，以得出无孔隙材料的弯曲强度。答案是一个具体的数值（126 MPa），需要通过公式和数值计算得出。 | 知识层次: 题目需要应用公式进行多步计算，并理解孔隙率与弯曲强度之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解孔隙率与弯曲强度的关系，建立数学模型（如指数衰减关系），并进行多步计算推导。虽然选择题提供了正确选项，但解题过程涉及综合分析材料性能参数和数学运算，比单纯的概念选择题更复杂。" + }, + { + "idx": 3966, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{cc} \\hline \\sigma_{\\mathrm{fs}} (MPa) & \\mathbf{P} \\ \\hline 100 & 0.05 \\ 50 & 0.20 \\ \\hline \\end{tabular} (b) Compute the flexural strength for a 0.10 volume fraction porosity.", + "answer": "the flexural strength for a 0.10 volume fraction porosity is 79.4 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式计算特定孔隙率下的弯曲强度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用公式进行多步计算，涉及体积分数孔隙率与弯曲强度之间的关联分析，需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求计算特定孔隙率下的弯曲强度，涉及多步计算和概念关联，如孔隙率与强度之间的关系公式。虽然计算过程较为直接，但需要综合理解和应用相关知识，因此在选择题型内属于等级3的综合性计算问题。" + }, + { + "idx": 3967, + "question": "Mechanical twinning occurs in metals having which type(s) of crystal structure(s)?(a) \\mathrm{BCC}(b) \\mathrm{FCC}(c) \\mathrm{HCP}", + "answer": "Mechanical twinning occurs in metals having B C C and H C P crystal structures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了多个选项（a、b、c），并且答案是从这些选项中选择的。 | 知识层次: 题目考查对金属晶体结构中机械孪生现象发生条件的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（机械孪生发生的晶体结构类型），但需要学生对BCC、FCC和HCP三种晶体结构的基本特性有一定理解，并能区分哪种结构会发生机械孪生现象。这超出了简单的概念识别（等级1），但尚未达到需要深度理解和复杂概念区分的程度（等级3）。学生需要掌握晶体结构的基本知识，并能进行简单的辨析判断。" + }, + { + "idx": 3968, + "question": "How does grain size influence strength of a polycrystalline material?(a) Strengthfine-grained < strength _{\\text {course-grained }}(b) Strength _{\\text {fine-grained }}= strength _{\\text {course-grained }}(c) Strengthfine-grained > strength _{\\text {course-grained }}", + "answer": "A fine-grained material is stronger than a coarse-grained material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查的是晶粒尺寸对多晶材料强度影响的基本概念记忆和理解，属于材料科学中的基础知识点。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（晶粒尺寸对多晶材料强度的影响），但需要考生理解并辨析\"细晶强化\"这一基本原理，而不仅仅是简单记忆定义。正确选项需要区分细晶和粗晶材料的强度关系，属于概念理解和简单辨析层次。" + }, + { + "idx": 3969, + "question": "Reducing the grain size of metal improves toughness.(a) True(b) False", + "answer": "True. Reducing the grain size of a metal improves its toughness.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断结果 | 知识层次: 题目考查金属晶粒尺寸与韧性关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆金属晶粒尺寸与韧性关系的基础知识即可作答，无需深入理解或分析。" + }, + { + "idx": 3970, + "question": "As dislocation density increases, the resistance to dislocation movement(a) increases.(b) decreases.", + "answer": "As dislocation density increases, the resistance to dislocation movement increases. This phenomenon is responsible for cold working.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查位错密度与位错运动阻力关系的基本概念记忆，属于材料科学中位错理论的基础知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，此题属于基础概念的直接记忆，仅需识别位错密度增加与位错运动阻力之间的关系，无需复杂分析或概念辨析。" + }, + { + "idx": 3971, + "question": "On the average, dislocation-dislocation strain interactions are(a) repulsive.(b) attractive.", + "answer": "On the average, dislocation-dislocation strain interactions are repulsive.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对位错-位错应变相互作用的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆位错-位错应变相互作用的基本性质即可作答，无需复杂理解或辨析。" + }, + { + "idx": 3972, + "question": "As a metal is strain hardened, its ductility(a) increases(b) decreases", + "answer": "As a metal is strain hardened, its ductility decreases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查金属应变硬化与延展性关系的基本概念记忆和理解 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别金属应变硬化后延展性的变化趋势。选项直接对应教材定义，无需理解或辨析过程，属于最简单的概念识别层级。" + }, + { + "idx": 3973, + "question": "Most metals strain harden at room temperature.(a) True(b) False", + "answer": "True. Most metals strain harden at room temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案形式为True或False，符合判断题的特征 | 知识层次: 题目考查对金属应变硬化这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题型中属于基本概念正误判断，仅需记忆金属在室温下的应变硬化特性即可作答，无需深入理解或分析。" + }, + { + "idx": 3974, + "question": "During the recovery of a cold-worked material, is some of the internal strain energy relieved?", + "answer": "Some of the internal strain energy is relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is some of the internal strain energy relieved?\"），而答案直接给出了判断结果（\"Some of the internal strain energy is relieved.\"）。这符合判断题的特征，即对陈述的真伪进行判断。 | 知识层次: 题目考查冷加工材料恢复过程中内应变能变化的基本概念，属于对基本原理的记忆和理解。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即冷加工材料恢复过程中内部应变能的释放情况。正确选项直接陈述了基本原理，无需复杂理解或分析，属于最基本的概念正误判断。" + }, + { + "idx": 3975, + "question": "During the recovery of a cold-worked material, is all of the internal strain energy relieved?", + "answer": "All of the internal strain energy is not relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is all of the internal strain energy relieved?\"），而答案直接给出了判断结果（\"All of the internal strain energy is not relieved.\"），这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中内应变能释放情况的基本概念理解，属于基础知识的记忆和简单判断。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即冷加工材料恢复过程中内应变能是否完全释放的定义性知识。正确选项直接陈述了基本原理（内应变能不会完全释放），无需复杂理解或分析，属于基本概念正误判断的简单题目。" + }, + { + "idx": 3976, + "question": "During the recovery of a cold-worked material, is there some reduction in the number of dislocations?", + "answer": "There is some reduction in the number of dislocations.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is there some reduction\"），而答案直接给出了对错判断（\"There is some reduction\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中位错数量变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆冷加工材料恢复过程中位错数量变化的基本原理即可作答，无需深入理解或分析多个概念，因此属于最低难度等级。" + }, + { + "idx": 3977, + "question": "During the recovery of a cold-worked material, is there a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state?", + "answer": "There is not a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了对陈述的判断（否定），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中位错数量变化的基本概念的理解和记忆，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于冷加工材料恢复过程中位错数量变化的基本陈述是否正确。题目直接考察对恢复过程定义的理解，无需复杂推理或概念间的比较分析，属于选择题型中最简单的正误判断类型。" + }, + { + "idx": 3978, + "question": "During the recovery of a cold-worked material, is the electrical conductivity recovered to its precold-worked state?", + "answer": "The electrical conductivity is recovered to its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（是否恢复到冷加工前的状态），答案直接给出了对陈述的判断（是/否）。这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中电导率变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即冷加工材料恢复过程中电导率是否恢复到冷加工前状态的简单正误判断。题目仅要求考生回忆和识别基本定义或原理，无需深入理解或分析多个概念，因此属于最低难度等级。" + }, + { + "idx": 3979, + "question": "During the recovery of a cold-worked material, is the thermal conductivity recovered to its precold-worked state?", + "answer": "The thermal conductivity is recovered to its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即热导率是否恢复到冷加工前的状态），答案直接给出了对陈述的判断（是或否）。 | 知识层次: 题目考查对冷加工材料恢复过程中热导率变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需判断热导率在冷加工材料恢复过程中是否恢复到原始状态。题目直接给出了正确选项，无需复杂推理或概念比较，符合选择题型中最简单的正误判断难度等级。" + }, + { + "idx": 3980, + "question": "During the recovery of a cold-worked material, does the metal become more ductile, as in its precold-worked state?", + "answer": "The metal does not become more ductile, as in its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（金属是否恢复到冷加工前的延展性状态），答案直接给出了对错判断 | 知识层次: 题目考查对冷加工材料恢复过程中性能变化的基本概念记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆层次，仅需判断金属在冷加工恢复过程中是否恢复到冷加工前的延展性状态。题目直接考察对冷加工恢复过程的基本理解，无需复杂分析或概念比较，属于选择题型中最简单的正误判断类型。" + }, + { + "idx": 3981, + "question": "During the recovery of a cold-worked material, are grains with high strains replaced with new, unstrained grains?", + "answer": "Grains with high strains are not replaced with new, unstrained grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"are grains with high strains replaced with new, unstrained grains?\"），而答案直接给出了对错判断（\"Grains with high strains are not replaced with new, unstrained grains.\"）。这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料回复过程中晶粒变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于冷加工材料恢复过程中晶粒变化的陈述是否正确。题目直接考察对基本定义和原理的记忆，无需深入理解或复杂分析，因此在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3982, + "question": "During the recrystallization of a cold-worked material, is some of the internal strain energy relieved?", + "answer": "All of the internal strain energy is relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"All of the internal strain energy is relieved\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料再结晶过程中内应变能变化的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于再结晶过程中内应变能释放的基本陈述是否正确。题目结构简单，无需复杂推理或概念比较，符合选择题型中最基础的难度等级。" + }, + { + "idx": 3983, + "question": "During the recrystallization of a cold-worked material, is there some reduction in the number of dislocations?", + "answer": "There is significant reduction in the number of dislocations.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即是否在再结晶过程中位错数量会减少），答案直接给出了判断结果（位错数量显著减少），符合判断题的特征。 | 知识层次: 题目考查对再结晶过程中位错数量变化的基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接询问冷加工材料再结晶过程中位错数量是否减少，正确选项明确陈述了\"位错数量显著减少\"这一基础概念。这只需要学生对再结晶过程的基本定义和原理有记忆性知识即可正确回答，无需深入理解或分析多个概念。因此按照选择题型的难度分级标准，这属于等级1的基础概念正误判断题。" + }, + { + "idx": 3984, + "question": "During the recrystallization of a cold-worked material, does the metal become more ductile, as in its precold-worked state?", + "answer": "The metal becomes more ductile, as in its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（金属是否在再结晶后变得更延展）。答案直接给出了对陈述的判断（\"The metal becomes more ductile\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料再结晶后性能变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断金属在再结晶后是否恢复延展性这一基本事实。题目直接给出了正确选项，无需复杂分析或概念比较，符合选择题型中最简单的正误判断难度等级。" + }, + { + "idx": 3985, + "question": "During the recrystallization of a cold-worked material, are grains with high strains replaced with new, unstrained grains?", + "answer": "Grains with high strains are replaced with new, unstrained grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了判断结果（陈述是正确的）。这符合判断题的特征。 | 知识层次: 题目考查对再结晶过程中晶粒变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆再结晶过程中高应变晶粒被新无应变晶粒替代的基本原理，无需深入理解或分析复杂概念。" + }, + { + "idx": 3986, + "question": "Grain growth requirements\n}\nGrain growth must always be preceded by recovery and recrystallization.(a) True(b) False", + "answer": "False. Grain growth does not always need to be preceded by recovery and recrystallization; it may occur in materials that have not been cold worked.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（True or False），答案直接给出了False的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对晶粒生长基本概念的理解，需要记忆和判断晶粒生长是否必须经过回复和再结晶过程，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆和理解晶粒生长的基本条件即可作答，无需复杂分析或比较多个概念。" + }, + { + "idx": 3987, + "question": "A hypothetical metal alloy has a grain diameter of 2.4 × 10^{-2} mm. After a heat treatment at 575^{\\circ} C for 500min, the grain diameter has increased to 7.3 × 10^{-2} mm. Compute the time required for a specimen of this same material (i.e., \\mathrm{d}_{0}=2.4 × 10^{-2}mm ) to achieve a grain diameter of 5.5 × 10^{-2}mm while being heated at 575^{\\circ} C. Assume the N grain diameter exponent has a value of 2.2.", + "answer": "the time required for the specimen to achieve a grain diameter of 5.5 × 10^{-2} mm is 246min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解时间，答案是一个具体的数值结果（246min），解答过程需要运用材料科学中的晶粒生长公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及公式应用和数值求解，需要理解晶粒生长动力学的基本原理，并能够将给定的初始条件和目标条件代入公式进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等难度，需要理解晶粒生长动力学的基本概念，应用给定的指数关系进行多步计算，并综合分析初始条件和目标条件之间的关系。虽然题目提供了必要的参数和公式，但解题过程涉及多个步骤和数学运算，要求考生具备一定的材料科学基础和计算能力。" + }, + { + "idx": 3988, + "question": "Tensile strengths and number-average molecular weights for two polymers are as follows:\nTensile strength Number average molecular weight\n(MPa)\n(\\mathrm{g} / mol)\n37.7\n36800\n131\n62400\nEstimate the tensile strength (in MPa) for a number-average molecular weight of 51500g / mol.", + "answer": "the tensile strength for a number-average molecular weight of 51500g/mol is 95.2 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了两组拉伸强度和数均分子量的数据，要求根据这些数据估算另一个分子量下的拉伸强度。这需要通过数值计算和可能的插值或外推方法来完成。答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目要求根据给定的数据点进行简单的线性插值计算，属于基本公式的直接应用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要基本公式应用和简单计算。虽然涉及线性插值，但步骤明确且直接，属于简单公式应用计算。" + }, + { + "idx": 3989, + "question": "Tensile strengths and number-average molecular weights for two polymers are as follows\n\\[\n\\begin{array}{l}\n\\text { Tensile strength Number average molecular weight } \\\\\n(MPa) \\\\\n138 \\\\\n184 \\\\\n\\text { (g/mol) } \\\\\n12600 \\\\\n28100\n\\end{array}\n\\]\nEstimate number average molecular weight (in \\mathrm{g} / mol ) at a tensile strength of 141 MPa.", + "answer": "the estimated number average molecular weight at a tensile strength of 141 \\, MPa is 14600 \\, \\mathrm{g/mol}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了两组数据（拉伸强度和数均分子量），要求根据给定的拉伸强度估算数均分子量。这需要通过数值计算和可能的插值或外推方法来求解，属于典型的计算题。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用基本公式进行简单的数值计算，属于直接套用公式的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。题目提供了两组数据点（拉伸强度和数均分子量），要求根据给定的拉伸强度估算数均分子量。解题步骤涉及简单的线性插值或外推，属于基本公式应用和简单计算，无需多个公式组合或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3990, + "question": "The bonding forces between adhesive and adherend surfaces are thought to be(a) Electrostatic(b) Covalent(c) Chemical", + "answer": "The bonding forces between adhesive and adherend surfaces are thought to be electrostatic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对粘合剂与被粘物表面之间作用力类型的基本概念记忆，属于基础概念的选择题，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对粘合剂与被粘物表面之间的结合力类型有一定的理解和辨析能力。正确选项（静电作用）需要考生从三个选项中识别出最符合理论描述的答案，而不仅仅是简单的概念识别。这要求考生对不同类型的结合力有基本的区分能力，但不需要进行复杂的分析或深度理解。" + }, + { + "idx": 3991, + "question": "Deformation of a semicrystalline polymer by drawing produces which of the following in the direction of drawing?", + "answer": "Increase in strength in the direction of drawing.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，虽然题目中没有明确列出选项，但根据问题的结构和答案的形式可以推断这是一个选择题。 | 知识层次: 题目考查对半结晶聚合物变形行为的基本概念记忆，只需知道拉伸会导致强度增加这一基本原理即可作答，不涉及复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察的是对半结晶聚合物拉伸变形后性能变化的基本理解。虽然需要记忆特定知识点（拉伸方向强度增加），但不需要复杂的分析或概念区分，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3992, + "question": "Deformation of a semicrystalline polymer by drawing produces which of the following perpendicular to the direction of drawing?", + "answer": "Decrease in strength perpendicular to the direction of drawing.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，虽然题目中没有明确列出选项，但答案的形式表明这是一个选择题，需要从多个可能的选项中选择正确的描述。 | 知识层次: 题目考查半结晶聚合物在拉伸变形时垂直于拉伸方向的性能变化，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及半结晶聚合物变形的基本概念，但只需理解拉伸方向与强度变化的关系即可作答，无需复杂分析或多个概念的交叉比较。属于基础概念理解和简单辨析层次。" + }, + { + "idx": 3993, + "question": "How does deformation by drawing of a semicrystalline polymer affect its tensile strength?(a) Increases(b) Decreases", + "answer": "Deformation by drawing increases the tensile strength of a semicrystalline polymer. This effect is due to the highly oriented chain structure that is produced by drawing, which gives rise to higher interchain secondary bonding forces.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项(a)和(b)中选择正确答案 | 知识层次: 题目需要理解半结晶聚合物在拉伸变形过程中的微观结构变化（链取向）及其对宏观性能（拉伸强度）的影响机制，涉及概念关联和综合分析能力 | 难度: 在选择题中属于较高难度，需要理解半晶态聚合物在拉伸变形过程中的微观结构变化（如分子链取向）及其对宏观力学性能（拉伸强度）的影响机制。这涉及材料科学中的晶体学原理、聚合物加工-结构-性能关系等中等应用层次的知识，并要求考生能够综合分析变形工艺与性能提升之间的因果关系。虽然题目形式为二选一，但正确选项的解释涉及多步逻辑推导和概念关联，超出了基础记忆题的范畴。" + }, + { + "idx": 3994, + "question": "How does increasing the degree of crystallinity of a semicrystalline polymer affect its tensile strength?(a) Increases\n\\mathrm{b}) Decreases", + "answer": "Increasing the degree of crystallinity of a semicrystalline polymer leads to an increase in its tensile strength. This is due to enhanced interchain bonding and forces in crystalline regions; in response to applied stresses, interchain motions become more restrained as degree of crystallinity increases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了多个选项（a和b）供选择，并最终给出了一个明确的选项作为正确答案。 | 知识层次: 题目考查对半结晶聚合物结晶度与拉伸强度关系的直接应用，属于基本概念的直接套用，不需要复杂的分析或多步推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用关于结晶度对聚合物拉伸强度影响的基本概念即可作答。题目不涉及复杂计算或公式变形，仅需理解结晶度增加会增强分子间作用力从而提高拉伸强度这一基本原理。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 3995, + "question": "How does increasing the molecular weight of a semicrysatlline polymer affect its tensile strength?(a) Increases(b) Decreases\n\\", + "answer": "The tensile strength of a semicrystalline polymer increases with increasing molecular weight. This effect is explained by the increased chain entanglements at higher molecular weights.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（a）和（b）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对半结晶聚合物分子量与其拉伸强度关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即分子量增加对半结晶聚合物拉伸强度的影响。正确选项直接给出了基本原理的解释，无需复杂辨析或深度理解。因此，该题目属于简单概念识别，直接记忆的难度等级。" + }, + { + "idx": 3996, + "question": "Which kind of fracture (ductile or brittle) is associated with intergranular crack propagation?", + "answer": "Intergranular fracture is brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要文字解释和论述来回答关于断裂类型的问题，而不是从多个选项中选择或简单的对错判断 | 知识层次: 题目考查对断裂类型（韧性断裂和脆性断裂）的基本概念记忆，以及晶间裂纹扩展与脆性断裂的关联理解，属于基础概念的记忆和简单应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"intergranular fracture\"与\"brittle\"的对应关系。不需要解释或分析，属于最简单的定义性知识考查。" + }, + { + "idx": 3997, + "question": "Which kind of fracture (ductile or brittle) is associated with transgranular crack propagation?", + "answer": "Transgranular fracture is brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪种断裂类型与穿晶裂纹扩展相关，答案需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查对断裂类型（韧性断裂和脆性断裂）及其与穿晶裂纹扩展关系的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"穿晶断裂属于脆性断裂\"这一简单事实。不需要解释或分析多个概念，属于最基本的知识点回忆题。" + }, + { + "idx": 3998, + "question": "The fracture strength of glass may be increased by etching away a thin surface layer. It is believed that the etching may alter the surface crack geometry (i.e. reduce crack length and increase tip radius). Calculate the ratio of the etched and original crack tip radii if the fracture strength is increased by a factor of 7 when 28% of the crack length is removed.", + "answer": "the ratio of the etched and original crack tip radii is: \\[\n\\frac{\\rho_{t}^{\\prime}}{\\rho_{t}} = 32\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，通过给定的条件（fracture strength increased by a factor of 7 when 28% of the crack length is removed）来计算 etched and original crack tip radii 的比值。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及断裂强度的变化与裂纹几何参数的关系，需要应用断裂力学中的相关公式，并综合分析裂纹长度和尖端半径的变化对强度的影响。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及断裂强度的计算，需要考生掌握裂纹几何对强度的影响，并能进行多步计算。虽然题目提供了部分参数，但需要考生综合运用相关公式和概念来推导最终结果。" + }, + { + "idx": 3999, + "question": "A structural component in the shape of a flat plate 27.3mm thick is to be fabricated from a metal alloy for which the yield strength and plane strain fracture toughness values are 535 MPa and 31.3 MPa·m^{-1 / 2}, respectively. For this particular geometry, the value of Y is 1.8 . Assuming a design stress of 0.5 times the yield strength, calculate the critical length of a surface flaw.", + "answer": "the critical length of a surface flaw is 2.0 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界表面缺陷长度，答案是一个具体的数值结果（2.0 mm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括设计应力的计算、临界裂纹长度的公式应用（涉及断裂韧性和几何因子Y的综合考虑），需要将多个概念关联起来进行综合分析。虽然不涉及复杂的推理或机理解释，但超出了简单直接套用公式的层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多个步骤的计算，包括设计应力的计算、临界裂纹长度的计算，以及对材料性能参数的理解和应用。虽然题目提供了所有必要的参数，但解题过程需要综合运用这些参数进行多步计算，并正确应用相关公式。此外，题目还要求对材料的断裂力学有一定的理解，能够将理论知识与实际应用相结合。因此，在选择题型中，这道题的难度属于中等偏上。" + }, + { + "idx": 4000, + "question": "How would the plane strain fracture toughness of a metal be expected to change with rising temperature?(a) Increase(b) Decrease(c) Remain constant", + "answer": "The magnitude of the plane strain fracture toughness, K_{i c}, diminishes with decreasing temperature; therefore as temperature increases, K_{i c}, should also increase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目需要理解平面应变断裂韧性与温度变化的关系，并应用相关知识进行推理分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属的平面应变断裂韧性（K_{ic}）与温度变化的关系这一概念，并能够综合分析温度升高对材料性能的影响。虽然题目涉及的知识点较为专业，但选项明确，不需要复杂的计算过程，属于多概念综合选择的范畴。" + }, + { + "idx": 4001, + "question": "Does increasing temperature favor brittle fracture in polymers?", + "answer": "No, increasing temperature does not favor brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案直接给出了判断结果（No），符合判断题的特征 | 知识层次: 题目考查对聚合物断裂行为与温度关系的基本概念记忆，属于基础原理的直接应用，无需复杂分析或计算。 | 难度: 该题目属于基础概念正误判断题，仅需记忆温度对聚合物断裂性能的基本影响原理。在选择题型中，这属于最简单的难度等级，因为只需识别\"温度升高不利于聚合物脆性断裂\"这一基本事实，无需深入理解或分析多个概念。" + }, + { + "idx": 4002, + "question": "Does increasing strain rate favor brittle fracture in polymers?", + "answer": "Yes, increasing strain rate favors brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了对错判断。 | 知识层次: 题目考查对聚合物应变率与脆性断裂关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于选择题型中的概念理解对错判断难度。虽然问题涉及聚合物材料的基本力学行为（应变速率与脆性断裂的关系），但只需理解\"应变速率增加会促进聚合物脆性断裂\"这一基本原理即可作答，不需要进行复杂的概念比较或分析。这属于对材料科学基础概念的简单应用层次，比纯粹的定义记忆（等级1）稍难，但明显低于需要综合分析多个概念的等级3难度。" + }, + { + "idx": 4003, + "question": "Does the presence of a sharp notch favor brittle fracture in polymers?", + "answer": "Yes, the presence of a sharp notch favors brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了明确的判断（Yes），符合判断题的特征 | 知识层次: 题目考查对聚合物断裂行为的基本概念记忆和理解，涉及尖锐缺口对脆性断裂的影响这一基本原理。 | 难度: 该题目属于选择题型中的概念理解对错判断难度。题目考察的是对聚合物断裂行为基本原理的理解，特别是缺口效应这一具体概念。虽然需要理解\"尖锐缺口促进脆性断裂\"这一原理，但不需要进行多概念比较或复杂分析，属于单一概念的应用判断。在选择题型中，这比纯粹的定义记忆（等级1）稍难，但比需要综合多个概念的复杂判断（等级3）简单。" + }, + { + "idx": 4004, + "question": "Does decreasing specimen thickness favor brittle fracture in polymers?", + "answer": "No, decreasing specimen thickness does not favor brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"Does decreasing specimen thickness favor brittle fracture in polymers?\"），而答案直接给出了对错判断（\"No\"），符合判断题的特征。 | 知识层次: 题目考查对聚合物断裂行为的基本概念的理解，属于基础概念记忆范畴，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念记忆层次，仅需判断\"减小试样厚度是否有利于聚合物脆性断裂\"这一基本概念的正误。正确选项直接给出了明确的否定结论，不需要任何概念理解或分析过程，属于选择题型中最简单的正误判断题。" + }, + { + "idx": 4005, + "question": "A plate of an alloy steel has a plane-strain fracture toughness of 50 MPa·{m}^{1 / 2}. If it is known that the largest surface crack is 0.5mm long, and that the value of Y is 1.1 , which of the following can be said about this plate when a tensile stress of 1200 MPa is applied?(a) The plate will definitely fracture.(b) The plate will definitely not fracture. c) It is not possible to determine whether or not the plate will fracture.", + "answer": "the plate will definitely fracture.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（a）、（b）、（c）中选择正确答案，符合选择题的特征。 | 知识层次: 题目主要考查对断裂韧性公式的直接应用，涉及基本公式的套用和简单计算，不需要复杂的分析或推理过程。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（断裂韧性公式）并进行简单计算即可得出答案。解题步骤明确且直接，无需公式变形或多步骤推理，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 4006, + "question": "The effect of a stress raiser is more significant for which of the following types of materials?(a) Brittle materials(b) Ductile materials", + "answer": "The effect of a stress raiser is more significant for brittle materials. For a ductile material, plastic deformation ensues when the maximum stress exceeds the yield strength. This leads to a more uniform distribution of stress in the vicinity of the stress raiser and to the development of a maximum stress concentration factor less than the theoretical value. Such yielding and stress redistribution do not occur to any appreciable extent around flaws and discontinuities in brittle materials; therefore, essentially the theoretical stress concentration will result.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案，属于选择题类型 | 知识层次: 题目考查对脆性材料和韧性材料在应力集中效应上的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解脆性材料和韧性材料在应力集中效应上的区别，并进行简单辨析。题目不涉及复杂概念区分或深度理解，但比单纯的概念识别要稍难一些。" + }, + { + "idx": 4007, + "question": "A structural component is fabricated from an alloy that has a plane strain fracture toughness of 45 MPa. It has been determined that this component fails at a stress of 300 MPa when the maximum length of a surface crack is 0.95 mm. What is the maximum allowable surface crack length (in mm ) without fracture for this same component exposed to a stress of 300 MPa and made from another alloy with a plane strain fracture toughness of 100.0 MPa ? The geometry factor Y is the same in both cases.", + "answer": "the maximum allowable surface crack length without fracture is 1.55 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过公式计算最大允许的表面裂纹长度，涉及数值计算和公式应用（如断裂韧性公式），答案是一个具体的数值结果（1.55 mm）。 | 知识层次: 题目需要进行多步计算，涉及断裂力学中的公式应用和不同材料参数的比较，需要理解平面应变断裂韧性和应力强度因子的关系，并进行综合分析。虽然不涉及复杂的机理分析或创新设计，但超出了简单直接套用公式的层次。 | 难度: 在选择题中属于中等难度，需要理解断裂韧性和应力强度因子的关系，并应用公式进行多步计算。题目涉及两个不同材料的比较，需要综合分析并正确应用几何因子Y的概念。虽然计算步骤较多，但在选择题型中，正确选项的提示可以帮助验证计算结果的合理性。" + }, + { + "idx": 4008, + "question": "A cylindrical specimen 7.5mm in diameter of an S-590 alloy is to be exposed to a tensile load of 9000 N. At approximately what temperature will the steady-state creep be 10^{-2}h^{-1} ?", + "answer": "approximately 815^\\circ C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定条件下的温度值，答案是一个具体的数值结果（815°C），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用蠕变速率公式和材料特性数据，同时需要理解稳态蠕变的概念及其与温度和应力的关系。这涉及中等程度的计算和概念关联，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要以下综合分析能力：" + }, + { + "idx": 4009, + "question": "The mineral olivine is a solid solution of the silicate compounds forsterite \\left(Mg_{2} \\mathrm{SiO}_{4}\\right) and fayalite \\left(\\mathrm{Fe}_{2} \\mathrm{SiO}_{4}\\right).\nHow many chemical components are there in a sample of olivine?\n(a) 1\n(b) 2\n(c) 3\n(d) 4", + "answer": "The components of a system are defined to be the smallest set of independently variable chemical constituents that are necessary to describe the composition of each phase that is present in a system. Components are chemically distinct. In this case, we only need to specify two things. It is convenient to simply use the compounds themselves as the components, but other options exist. For instance, specifying the amount of Mg and \\mathrm{Fe} in the system automatically fixes the \\mathrm{Si} and \\mathrm{O} content, assuming the compounds are present in their stoichiometric ratios (assuming they are defect free).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)到(d)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对化学组分基本概念的理解和记忆，需要识别并应用组分定义来分析矿物橄榄石的组成。虽然涉及一定的逻辑推理，但主要依赖于对基础概念的掌握。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解“化学组分”的定义及其在具体矿物（橄榄石）中的应用。解题步骤包括识别橄榄石的组成（镁橄榄石和铁橄榄石），并理解如何根据定义确定化学组分的数量。这需要一定的概念理解和简单辨析能力，而不仅仅是直接记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4010, + "question": "Seawater, which covers the majority of the earth, is composed primarily of molecules of H_{2} \\mathrm{O} and equal numbers of \\mathrm{Na}^{+}ions and \\mathrm{Cl}^{-}ions. Suppose we have a thoroughly mixed solution (containing these species only) at 25^{\\circ} C. How many components and how many phases are in such a system?\n(a) 1 component, 1 phase\n(b) 1 component, 2 phase\n(c) 1 component, 3 phase\n(d) 1 component, 4 phase\n(e) 2 component, 1 phase\n(f) 2 component, 2 phase\n(g) 2 component, 3 phase\n(h) 2 component, 4 phase\n(i) 3 component, 1 phase\n(j) 3 component, 2 phase\n(k) 3 component, 3 phase(l) 3 component, 4 phase\n(m) 4 component, 1 phase\n(n) 4 component, 2 phase\n(o) 4 component, 3 phase\n(p) 4 component, 4 phase", + "answer": "(e) 2 component, 1 phase", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了多个选项供选择 | 知识层次: 题目考查对组分和相这两个基本概念的记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（如组分和相的定义），但需要考生理解并区分不同化学物种（H2O、Na+、Cl-）在系统中的分类方式。解题步骤相对直接，但需要明确区分独立组分数和相数的概念，并进行简单辨析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4011, + "question": "Is solid ductile cast iron (ferrite solid solution + embedded graphite spheres) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is solid ductile cast iron... a two-phase material system?\"），答案明确给出了\"Yes\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的记忆和理解，涉及材料组成和相的定义，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆材料科学中两相系统的定义即可作答。题目直接询问是否属于两相系统，并给出明确的结构描述（铁素体固溶体+石墨球），只需判断是否符合两相系统的定义特征（存在物理边界分隔化学/结构不同的区域）。在选择题型中属于最基础的认知层级，无需复杂推理或概念关联。" + }, + { + "idx": 4012, + "question": "Is solid sodium chloride (salt, NaCl) a two-phase material system?", + "answer": "No, it is a single-phase compound, not a solution. The ratio of the two ions is in a fixed stoichiometry and they adopt an orderly arrangement in the crystal.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"固体氯化钠是否是两相材料系统\"这一陈述的对错。答案直接给出了\"否\"的判断，并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对单相和多相材料系统的基本概念的理解和记忆，涉及对NaCl晶体结构的简单认知，不需要复杂的分析或推理。 | 难度: 该题目属于基础概念正误判断，仅需记忆固体氯化钠是单相化合物这一基本事实即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4013, + "question": "Is liquid bronze (Cu + Sn liquid solution) a two-phase material system?", + "answer": "No, it is a liquid solution, and solutions are single-phase by definition.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（判断液态青铜是否为两相材料系统），答案直接给出了对错判断和简要解释，符合判断题的特征。 | 知识层次: 题目考查对相和溶液定义的基础概念记忆和理解，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念正误判断，仅需记忆\"溶液是单相系统\"这一基本定义即可作答。在选择题型中属于最简单的直接知识回忆类题目，无需任何分析推理过程。" + }, + { + "idx": 4014, + "question": "Is solid gray cast iron (ferrite solid solution + embedded graphite flakes) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Is solid gray cast iron a two-phase material system?），答案直接给出了明确的判断（Yes）和简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及材料组成和相的定义，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆材料科学中关于两相系统的基本定义即可作答。题目直接询问灰色铸铁是否为两相系统，并提供了明确的正确选项描述，不涉及复杂概念分析或多步骤推理。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4015, + "question": "Is solid aluminum featuring dissolved silicon a two-phase material system?", + "answer": "No, it is a solid solution since silicon is implied to substitute for aluminum. Solutions are single-phase by definition.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个陈述的对错（\"Is solid aluminum featuring dissolved silicon a two-phase material system?\"），答案直接给出了对错判断（\"No\"）并解释了原因。这符合判断题的特征。 | 知识层次: 题目考查对固溶体和两相系统基本定义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基本概念正误判断，仅需记忆固体溶液的定义和单相系统的概念即可做出正确选择，无需深入理解或分析复杂概念。" + }, + { + "idx": 4016, + "question": "Is solid lead-tin solder (a mixture of Pb-rich and Sn-rich solid solutions) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is solid lead-tin solder... a two-phase material system?\"），答案明确给出了\"Yes\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的记忆和理解，涉及简单的分类判断，不需要复杂的分析或计算。 | 难度: 该题目属于基本概念正误判断，仅需记忆和识别\"两相材料系统\"的定义即可作答。题目直接考察对铅锡焊料相组成的记忆性知识，无需复杂推理或概念比较，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4017, + "question": "Is partially melted aluminum a two-phase material system?", + "answer": "No, the physical boundary merely separates volumes that are structurally distinct (crystalline and liquid).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"部分熔化的铝是否是两相材料系统\"这一陈述的正确性。答案直接给出了\"否\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解，仅需判断部分熔融铝是否属于两相系统，属于基础概念的记忆和理解层面。 | 难度: 该题目属于基础概念正误判断题，仅需要考生记忆并识别\"部分熔融铝是否为两相材料系统\"这一基本定义。题目提供明确的正误选项，不涉及概念理解或复杂分析，符合选择题型中最简单的难度等级标准。" + }, + { + "idx": 4018, + "question": "Is frozen water with trapped air bubbles a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is frozen water with trapped air bubbles a two-phase material system?\"），答案直接给出了判断结果（\"Yes\"）并提供了简要解释。这符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和判断，属于基础概念记忆范畴，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接考察对\"两相材料系统\"定义的理解，只需判断是否存在物理边界和化学/结构差异这两个基本要素。正确选项明确给出了定义性描述，不需要进行复杂分析或概念比较，符合等级1的简单记忆性知识考查要求。" + }, + { + "idx": 4019, + "question": "Is epoxy embedded with carbon fibers a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is epoxy embedded with carbon fibers a two-phase material system?\"），答案直接给出了明确的判断（\"Yes\"）并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及材料组成和相界面的基本定义，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅要求对基础概念进行正误判断，即判断环氧树脂嵌入碳纤维是否为两相材料系统。题目涉及的知识点较为基础，属于定义和分类的记忆性知识，无需深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4020, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must have a very [w] sizes. (w = similar, different)", + "answer": "The solute and host species must have a very similar sizes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项（similar, different）中选择一个正确答案来填空 | 知识层次: 题目考查对固溶体溶解度条件的基本概念记忆，仅需知道溶质和溶剂原子尺寸相似性这一基本原理即可作答，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目仅要求考生回忆并选择正确的定义性知识（\"similar sizes\"），无需进行概念辨析或深度理解。这种类型的题目在选择题中属于最基础的难度级别。" + }, + { + "idx": 4021, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must attempt to pack with [x] crystal structure. (x = a similar (or the same), a different)", + "answer": "The solute and host species must attempt to pack with a similar (or the same) crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求完成一个陈述句，需要填入正确的词语来补全句子，而不是从给定的选项中选择或判断对错。答案是一个完整的句子，需要理解材料科学中固溶体的条件才能正确填写。 | 知识层次: 题目考查对固溶体溶解度条件的基本概念记忆，仅需回忆并填写关键词\"a similar (or the same)\"，属于基础概念层面的知识点。 | 难度: 在选择题型中属于基本定义简答难度，仅需记忆固体溶液溶解度条件中的基本概念（溶质与主体需具有相似或相同晶体结构），无需复杂分析或推理步骤。" + }, + { + "idx": 4022, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must feature [y] valence electron configuration. (y = a similar (or the same), a different)", + "answer": "The solute and host species must feature a similar (or the same) valence electron configuration.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确的答案填空，符合选择题的特征 | 知识层次: 题目考查对固溶体溶解度条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆固体溶解度条件中关于价电子构型的基本原理。正确选项明确且无需复杂分析，属于最简单的概念识别级别。" + }, + { + "idx": 4023, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must feature [z] ability to attract electrons (electronegativity). (z = a similar, a different)", + "answer": "The solute and host species must feature a similar ability to attract electrons (electronegativity).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（a similar, a different）中选择一个正确的单词来填空，符合选择题的特征 | 知识层次: 题目考查对固溶体溶解度条件的基本概念记忆，特别是关于溶质和溶剂电负性相似性的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别并选择\"similar\"这一关键词即可完成作答。题目直接考察对固溶体溶解度条件的记忆，无需复杂理解或分析，属于最简单的概念识别级别。" + }, + { + "idx": 4024, + "question": "For a solution, which of the following is present in the higher concentration?(a) Solvent(b) Solute", + "answer": "Solvent. By definition, solvent is the element/compound that is present in a solution in the greatest amount.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a) Solvent和(b) Solute中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对溶剂和溶质基本定义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目仅考察对溶剂和溶质定义的基本记忆，无需深入理解或复杂辨析，只需识别出溶剂在溶液中浓度更高这一基本事实。" + }, + { + "idx": 4025, + "question": "A liquidus line separates which of the following combinations of phase fields?(a) Liquid and Liquid +\\alpha(b) \\alpha and Liquid +\\alpha(c) \\alpha and \\alpha+\\beta(d) Liquid +\\alpha and \\alpha+\\beta", + "answer": "A liquidus line separates Liquid and Liquid +\\alpha phase fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对相图中液相线（liquidus line）定义和功能的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，直接考察对liquidus线定义的理解，无需复杂分析或比较。只需识别liquidus线分隔的是Liquid和Liquid + α相区，属于简单概念识别和直接记忆的范畴。" + }, + { + "idx": 4026, + "question": "A solvus line separates which of the following pairs of phase fields?(a) Liquid and Liquid +\\alpha(b) \\alpha \\operatorname{and} Liquid +\\alpha(c) \\alpha and \\alpha+\\beta d) Liquid +\\alpha and \\alpha+\\beta", + "answer": "A solvus line separates \\alpha and \\alpha+\\beta phase fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了多个选项（a-d），要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对相图中solvus线定义的基本概念记忆，仅需识别solvus线分隔的相区类型，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要学生对相图中的solvus线有清晰的理解，并能正确区分不同相区之间的关系。题目要求学生在四个选项中识别出solvus线所分隔的正确相区对，这需要一定的概念理解和简单辨析能力，而不仅仅是简单的记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4027, + "question": "Which of the following kinds of information may be determined with the aid of a phase diagram? The phase(s) present at a specified temperature and composition.", + "answer": "With the aid of a phase diagram the following may be determined: The phase(s) present at a specified temperature and composition.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确的信息类型，符合选择题的特征 | 知识层次: 题目考查对相图基本功能的理解和记忆，即通过相图确定特定温度和成分下的相组成，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别相图的基本功能（确定特定温度和成分下的相态），无需复杂分析或概念辨析。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 4029, + "question": "Which of the following kinds of information may be determined with the aid of a phase diagram? The fraction(s) of phase(s) present at specified temperature and composition.", + "answer": "With the aid of a phase diagram the following may be determined: The fraction(s) of phase(s) present at a specified temperature and composition.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择关于相图可以确定的信息类型，虽然示例中只给出了一个选项，但完整的题目应该包含多个选项供选择。答案形式也是从选项中选择正确的陈述。 | 知识层次: 题目考查对相图基本功能的理解和记忆，属于基础概念层次 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即通过相图可以确定特定温度和成分下的相分数。这属于直接记忆性知识，不需要复杂的理解或分析，因此属于最简单的难度等级。" + }, + { + "idx": 4030, + "question": "At a eutectic point on a binary temperature-composition phase diagrams, how many phases are present when the system is at equilibrium?(a) 0(b) 1(c) 2(d) 3", + "answer": "At a eutectic point on a binary phase diagram, three phases (Liquid, \\alpha, and \\beta ) are present when the system is at equilibrium.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（a、b、c、d）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对二元相图中共晶点处相平衡状态的基本概念记忆，属于对基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆题，直接考察对共晶点相数的记忆。在选择题型中，只需识别并回忆\"共晶点三相共存\"这一基本概念即可作答，无需任何分析或推理过程，属于最简单的直接记忆型题目。" + }, + { + "idx": 4031, + "question": "An intermetallic compound is found in the magnesium-gallium system that has a composition of 41.1 wt% Mg - 58.9 wt% Ga. Specify the formula for this compound.(a) MgGa (b) Mg_{2} \\mathrm{Ga} (c) \\mathrm{MgGa}_{2} (d) Mg_{3} \\mathrm{Ga}_{2}", + "answer": "(b) Mg_{2}Ga", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的化学式，符合选择题的特征 | 知识层次: 题目要求根据给定的重量百分比计算化合物的化学式，涉及基本的原子量计算和简单应用，不需要复杂的分析或综合能力。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需基本公式应用和简单计算即可得出正确答案。题目直接给出了组成百分比，要求选择正确的化学式，解题步骤较为直接，无需复杂变形或多步骤推理。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 4032, + "question": "A eutectoid reaction involves which of the following phases? (a) One liquid and one solid (b) One liquid and two solid (c) Two liquids and one solid (d) Three solid", + "answer": "(d) Three solid", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查共析反应中相的基本概念记忆，只需记住共析反应涉及三个固相即可作答，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目仅涉及对共析反应定义的基础记忆，无需复杂理解或辨析。学生只需识别共析反应涉及的相数即可直接作答，属于简单概念识别类型。" + }, + { + "idx": 4033, + "question": "A peritectic reaction involves which of the following combinations of phase fields? (a) One liquid and one solid (b) One liquid and two solid (c) two liquids and one solid (d) Three solid", + "answer": "(b) One liquid and two solid", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确的组合，符合选择题的特征 | 知识层次: 题目考查对包晶反应（peritectic reaction）基本概念的记忆和理解，涉及相图的基本知识，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，考察的是对包晶反应（peritectic reaction）定义的理解。虽然需要记忆相场组合的具体内容，但选项设置较为直接，只需识别\"一个液体和两个固体\"的正确组合即可。相比等级1的直接概念识别，此题需要学生对相图反应类型有基本理解，属于概念理解和简单辨析的难度。" + }, + { + "idx": 4034, + "question": "For a congruent phase transformations there are (a) no composition alterations.(b) compositional alterations.", + "answer": "(a) no composition alterations", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对“congruent phase transformations”这一基本概念的记忆和理解，特别是其定义中关于成分变化的特点。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即“共晶相变”的定义特征。题目直接考察学生是否记住“共晶相变没有成分改变”这一基本事实，无需理解或辨析其他复杂概念。属于最简单的概念识别层级。" + }, + { + "idx": 4035, + "question": "Which of the following have a significant influence on a material's electrical resistivity?(a) impurity concentration(b) temperature(c) grain size(d) cold work(e) vacancy concentration", + "answer": "A material's electrical resistivity will depend on the following:\n- Impurity concentration\n- Vacancy concentration\n- Temperature\n- Cold work", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择对材料电阻率有显著影响的因素，答案给出了具体的选择项，符合选择题的特征 | 知识层次: 题目要求考生综合分析多个因素对材料电阻率的影响，涉及杂质浓度、温度、晶粒尺寸、冷加工和空位浓度等多个概念，需要理解这些因素如何相互作用并影响电阻率。这超出了单纯记忆基础概念的层次，属于中等应用层次的分析和综合。 | 难度: 在选择题型中属于较高难度，需要综合分析多个影响因素（杂质浓度、空位浓度、温度、冷加工）对材料电阻率的共同作用，涉及中等应用层次的知识关联和多步判断过程。" + }, + { + "idx": 4036, + "question": "Conductivity in a metal is almost always reduced by the introduction of defects into the lattice.\nThe factor primarily affected by defects is:\n[a] free electron concentration\n[b] electron charge\n[c] electron mobility\n[d] electron spin", + "answer": "[c] electron mobility", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对金属导电性影响因素的基础概念记忆，特别是缺陷对电子迁移率的影响，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解金属导电性的基本原理，并能够辨析不同因素（如自由电子浓度、电子电荷、电子迁移率和电子自旋）对导电性的影响。正确选项（电子迁移率）需要考生对缺陷如何影响电子运动有基本的理解，而不仅仅是简单的记忆。因此，该题目属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 4037, + "question": "Compute the number of electrons that each aluminum atom donates, on average, to a bulk piece of aluminum metal. Room temperature data for aluminum:\nThe resistivity of aluminum is 2.63 × 10^{-8} \\Omega·m\nThe electron mobility of aluminum is 0.0012{m}^{2} /(V·s)\nThe mass density of aluminum is 2.7g / {cm}^{3}\nThe atomic weight of aluminum is 27g / mol", + "answer": "3.29 electron/atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的物理参数（如电阻率、电子迁移率、质量密度和原子量）进行数值计算，最终得出每个铝原子平均贡献的电子数。解答过程需要应用相关公式和单位转换，答案是一个具体的数值（3.29 electron/atom），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及电阻率、电子迁移率、质量密度和原子重量等多个物理量的关联和综合分析，需要运用相关公式进行计算，但不需要进行复杂的推理分析或机理解释。 | 难度: 在选择题中属于高难度，需要综合运用多个物理概念（电阻率、电子迁移率、质量密度、原子量）进行多步骤计算，并理解金属导电的微观机制。题目要求将宏观测量参数与微观电子贡献联系起来，涉及单位转换和复杂公式推导（如载流子浓度计算），远超选择题常见的单步计算或概念识别难度。" + }, + { + "idx": 4038, + "question": "Compute the number of electrons that each atom donates, on average, to a bulk piece of hypothetical metal. Room temperature data for the metal:\nThe resistivity of the metal is [\\mathrm{r}] \\Omega·{cm}\nThe electron mobility of the metal is [m] {cm}^{2} /(V·s)\nThe mass density of the metal is [\\mathrm{d}] \\mathrm{g} / {cm}^{3}\nThe atomic weight of the metal is [\\mathrm{w}] \\mathrm{g} / mol", + "answer": "the number of free electrons donated by each atom, on average, is: \\[\n\\frac{[w]}{\\left([r]\\left(1.6 × 10^{-19}\\right)[m]\\right)\\left([d]\\left(6.022 × 10^{23}\\right)\\right)}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数（电阻率、电子迁移率、质量密度、原子量）进行数值计算，应用特定的公式来求解每个原子平均贡献的自由电子数。答案以数学表达式形式给出，需要具体的计算步骤和公式应用。 | 知识层次: 题目需要多步计算和概念关联，包括电阻率、电子迁移率、质量密度和原子重量等参数的结合应用，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要综合运用电阻率、电子迁移率、质量密度和原子重量等多个概念，并进行多步骤计算。虽然题目提供了正确选项，但理解其推导过程需要较强的物理和化学知识基础，以及综合分析能力。" + }, + { + "idx": 4039, + "question": "When an electric field is applied, in which direction are the free electrons accelerated?(a) Opposite to the direction of the electric field.(b) In the same direction as the electric field.", + "answer": "When an electric field is applied, the free electrons are accelerated in the direction opposite to that of the field.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项（a和b），要求从中选择正确的答案。 | 知识层次: 题目考查对电场中自由电子运动方向这一基本概念的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆自由电子在电场中的运动方向这一基本原理，无需复杂辨析或深度理解。在选择题型中，此类直接考察定义和基本原理的题目通常属于最简单级别。" + }, + { + "idx": 4040, + "question": "The electrical conductivity of an intrinsic semiconductor is(a) characteristic of the high-purity metal.(b) due to the presence of impurities.", + "answer": "The electrical conductivity of an intrinsic semiconductor is characteristic of the high-purity material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对半导体基本概念的记忆和理解，特别是本征半导体的电导率特性。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和记忆\"本征半导体\"的定义和特性。正确选项直接对应教材中的基础定义，无需复杂分析或概念辨析，属于最简单的难度等级。" + }, + { + "idx": 4041, + "question": "How do the electrical conductivities of metals compare with those of semiconductors?(a) \\sigma_{\\text {metals }}>\\sigma_{\\text {semiconductors }}(b) \\sigma_{\\text {metals }}=\\sigma_{\\text {semiconductors }}(c) \\sigma_{\\text {metals }}<\\sigma_{\\text {semiconductors }}", + "answer": "The electrical conductivities of metals are greater than those of semiconductors.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查的是金属和半导体电导率的基本概念和比较，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型内，该题目仅涉及基础概念记忆，即金属和半导体电导率的比较。学生只需记住金属的电导率通常高于半导体这一基本事实即可正确作答，无需进行复杂的理解或分析。因此，该题目属于简单概念识别和直接记忆的难度等级。" + }, + { + "idx": 4042, + "question": "How does increasing temperature affect the concentration of both electrons and holes in an intrinsic semiconductor?(a) Increases the concentration.(b) Decreases the concentration.(c) May increase and/or decrease the concentration, depending on the temperature range.", + "answer": "Increasing temperature increases the concentration of both electrons and holes in an intrinsic semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对温度如何影响本征半导体中电子和空穴浓度的基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆温度对半导体中电子和空穴浓度的影响这一基本原理。题目选项设计简单，正确选项直接对应基础知识点，无需复杂分析或概念区分。因此属于最简单的难度等级1。" + }, + { + "idx": 4043, + "question": "Which type of charge carrier will be introduced into a semiconductor by the presence of an acceptor impurity?(a) Electron(b) Hole", + "answer": "The presence of an acceptor impurity introduces holes into a semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查半导体中受主杂质引入载流子的基本概念，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即\"受主杂质引入空穴\"这一简单事实的识别。不需要任何理解或分析过程，属于直接记忆性知识，符合等级1的简单概念识别标准。" + }, + { + "idx": 4044, + "question": "Which type of charge carrier will be introduced into a semiconductor by the presence of a donor impurity?(a) Impurity(b) Hole", + "answer": "The presence of a donor impurity introduces electrons into a semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查半导体中施主杂质引入载流子的基本概念，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆半导体中施主杂质引入的载流子类型（电子）。题目直接考察定义性知识，无需复杂理解或分析，属于最简单的难度等级。" + }, + { + "idx": 4045, + "question": "The electrical conductivity of an extrinsic semiconductor is(a) Characteristic of the high-purity material.(b) due to the presence of impurities.", + "answer": "The electrical conductivity of an extrinsic semiconductor is due to the presence of impurities.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择关于外征半导体导电性的正确描述 | 知识层次: 题目考查对半导体导电性基本原理的记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆类型，仅需识别并记忆外征半导体的电导率是由杂质引起的这一基本事实。在选择题型中，这种直接考察定义或分类的题目属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 4046, + "question": "For an n-type semiconductor, which type of charge carrier is present in the greater concentration?(a) Hole(b) Electron", + "answer": "For an n-type semiconductor, electrons (i.e., negative charge carriers) are present in a greater concentration than holes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项（a）Hole和（b）Electron中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查n型半导体中主要载流子的基本概念记忆，属于定义和分类层面的基础知识点。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别n型半导体的主要载流子类型（电子）。题目直接考察定义性知识，无需复杂理解或分析步骤，属于最简单的难度等级。" + }, + { + "idx": 4047, + "question": "For an n-type semiconductor(a) Concentration _{\\text {electrons }}< concentration _{\\text {holes }}(b) Concentration _{\\text {electrons }}= concentration _{\\text {holes }}(c) Concentration _{\\text {electrons }}< concentration _{\\text { holes }}", + "answer": "For an n-type semiconductor, the concentration of electrons is much greater than the concentration of holes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对n型半导体基本概念的记忆和理解，即电子浓度远大于空穴浓度这一基本特性。 | 难度: 该题目属于基础概念记忆类型，仅需识别n型半导体的基本定义，即电子浓度远大于空穴浓度。在选择题型中，只需直接回忆相关知识点即可作答，无需复杂分析或理解。因此，难度等级为1，属于简单概念识别。" + }, + { + "idx": 4048, + "question": "For a p-type semiconductor, which type of charge carrier is present in the greater concentration?(a) Holes(b) Electrons", + "answer": "For a p-type semiconductor, holes, (i.e., positive charge carriers) are present in a greater concentration than electrons.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项（a）Holes和（b）Electrons中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对p型半导体中主要载流子类型的基础概念记忆，仅需知道p型半导体中空穴浓度高于电子这一基本事实即可回答，无需复杂分析或计算。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即p型半导体中多数载流子的类型。学生只需直接回忆p型半导体的定义即可选出正确答案，无需进行复杂的概念辨析或深度理解。因此，该题目属于简单概念识别，直接记忆的难度等级。" + }, + { + "idx": 4049, + "question": "For a p-type semiconductor(a) Concentration _{\\text {electrons }}< concentration _{\\text {holes }}(b) Concentration _{\\text {electrons }}= concentration _{\\text {holes }}(c) Concentration _{\\text {electrons }}< concentration _{\\text { holes }}", + "answer": "For a p-type semiconductor, the concentration of electrons is much lower than the concentration of holes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了多个选项（a, b, c），要求从中选择正确的陈述，符合选择题的特征。 | 知识层次: 题目考查对p型半导体基本概念的记忆和理解，即电子和空穴浓度的相对关系，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别p型半导体的基本特性（电子浓度远低于空穴浓度）。题目选项直接对应定义，无需复杂分析或理解，属于简单概念识别。" + }, + { + "idx": 4050, + "question": "In order for a semiconductor to exhibit extrinsic electrical characteristics, relatively high impurity concentrations are required.(a) True(b) False", + "answer": "False. Even when minute impurity concentrations (e.g., 1 atom in 10^{12} ) are present in a semiconductor, its electrical characteristics will be extrinsic.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附带简要解释 | 知识层次: 题目考查对半导体本征和外征特性的基本概念的理解，属于基础概念记忆范畴，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念正误判断，仅需记忆半导体掺杂的基本原理即可作答，无需复杂分析或概念比较。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4051, + "question": "The following electrical characteristics have been determined for both intrinsic and n-type extrinsic indium phosphide (InP) at room temperature:\n\\[\n\\begin{array}{llll}\n\\sigma(\\Omega·\\mathbf{m})^{-1} & \\boldsymbol{n}\\left(\\mathbf{m}^{-3}\\right) & \\boldsymbol{p}\\left(\\mathbf{m}^{-3}\\right) \\\\\n\\text { Intrinsic } & 2.5 × 10^{-6} & 3.0 × 10^{13} & 3.0 × 10^{13} \\\\\n\\text { Extrinsic } & 3.6 × 10^{-5} & 4.5 × 10^{14} & 2.0 × 10^{12}\n\\end{array}\n\\]\nCalculate electron and hole mobilities.\n\\mu_{\\mathrm{e}}=\n\\mu_{h}=", + "answer": "\\mu_{\\mathrm{e}} = 0.50 \\, m^{2} / \\mathrm{v}·s \\mu_{h} = 0.02 \\, m^{2} / \\mathrm{v}·s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率、电子浓度和空穴浓度数据，应用相关公式计算电子和空穴的迁移率。解答过程涉及数值计算和公式应用，最终需要给出具体的数值结果。 | 知识层次: 题目要求应用基本电导率公式（σ = n·e·μ）进行简单计算，仅需直接套用公式并代入给定数值即可求解电子和空穴迁移率，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要考生掌握基本的电导率公式（σ = n·e·μ）并进行简单的代数运算。虽然涉及两个变量（电子和空穴迁移率），但计算过程直接且无需复杂的推导或概念组合，因此属于等级2难度。" + }, + { + "idx": 4052, + "question": "Which of the following are preferred for semiconducting devices?(a) Single crystals(b) Polycrystalline materials", + "answer": "Single crystals are preferred for semiconducting devices because grain boundaries are deleterious to the performance of electronic phenomena.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对半导体器件材料选择的基本概念记忆和理解，涉及单晶和多晶材料的性能差异这一基本原理。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及半导体材料的基础概念，但只需要理解单晶和多晶材料在半导体器件中的性能差异，无需复杂的分析或计算。正确选项直接给出了关键原因（晶界对电子现象性能有害），属于概念理解和简单辨析的层次。" + }, + { + "idx": 4053, + "question": "As temperature increases, the electrical conductivities of polymers and ionic ceramics(a) Increase(b) Decrease", + "answer": "As temperature increases, the electrical conductivities of polymers and ionic ceramics increase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)和(b)中选择正确的答案，符合选择题的特征。 | 知识层次: 题目考查对聚合物和离子陶瓷电导率随温度变化的基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解聚合物和离子陶瓷的电导率随温度变化的基本原理，并进行简单辨析。题目不涉及复杂概念的区分或深度理解，但比直接记忆的简单概念识别稍难。" + }, + { + "idx": 4054, + "question": "Most polymers and ionic ceramics have energy band gap structures that are most similar to those of(a) Insulators(b) Semiconductors(c) Metals", + "answer": "Most polymers and ionic ceramics have wide energy band gaps; thus, they are most like those of insulators.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择最符合描述的答案 | 知识层次: 题目考查对材料能带结构分类的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需识别和回忆聚合物和离子陶瓷的能带结构特点，直接对应到绝缘体的定义。选择题型中无需复杂分析或比较，属于最简单的概念识别层次。" + }, + { + "idx": 4055, + "question": "The charge carriers in ionic ceramics and polymers can be(a) Electrons(b) Holes(c) Anion(d) Cations", + "answer": "The charge carriers in ionic ceramics and polymers can be electrons, holes, anions, and/or cations.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a）Electrons（b）Holes（c）Anion（d）Cations中选择正确的电荷载流子类型，符合选择题的特征。 | 知识层次: 题目考查对离子陶瓷和聚合物中电荷载流子的基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分不同类型的电荷载流子（电子、空穴、阴离子、阳离子）在离子陶瓷和聚合物中的存在情况。这要求考生不仅记住定义，还需要对这些概念有一定的理解和辨析能力。" + }, + { + "idx": 4056, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum alloys are generally not viable as lightweight structural materials in humid environments because they are highly susceptible to corrosion by water vapor.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），并且答案是一个明确的判断（F）。这符合判断题的特征。 | 知识层次: 题目考查对铝合金在潮湿环境中耐腐蚀性能的基本概念记忆和理解，属于基础知识的判断。 | 难度: 该题目属于基础概念正误判断，仅需记忆铝及铝合金的基本特性（如耐腐蚀性）即可作答。题目陈述明确，无需复杂分析或概念比较，符合选择题型中最简单的难度等级。" + }, + { + "idx": 4057, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum alloys are generally superior to pure aluminum, in terms of yield strength, because their microstructures often contain precipitate phases that strain the lattice, thereby hardening the alloy relative to pure aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案形式为简单的T/F判断，符合判断题的特征。 | 知识层次: 题目考查对铝合金强化机制的基本概念记忆和理解，即通过析出相引起晶格应变从而强化合金的原理。这属于材料科学中关于金属强化机制的基础知识，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要理解铝合金和纯铝的基本区别以及沉淀相的作用，但不需要复杂的分析或比较多个概念" + }, + { + "idx": 4058, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum is not very workable at high temperatures in air, in terms of extrusion and rolling, because a non-protective oxide grows and consumes the metal, converting it to a hard and brittle ceramic.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案形式为F（False），符合判断题的特征 | 知识层次: 题目考查对铝及其合金在高温下加工性能的基本概念记忆和理解，涉及氧化膜的形成及其对加工性能的影响，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铝在高温下的工作特性这一基础概念即可做出正确选择，无需深入理解或分析多个概念。" + }, + { + "idx": 4059, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Compared to most other metals, like steel, pure aluminum is very resistant to creep deformation.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案是一个明确的判断（F），符合判断题的特征。 | 知识层次: 题目考查对纯铝蠕变性能的基本概念记忆，属于基础知识的判断，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆纯铝的抗蠕变性能相对于其他金属（如钢）较差这一基础事实即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4060, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: The relatively low melting point of aluminum is often considered a significant limitation for structural applications.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案也是简单的T/F形式，符合判断题的特征。 | 知识层次: 题目考查对铝及其合金基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆铝及其合金的基本特性（如相对较低的熔点）即可作答。在选择题型中属于最简单的难度等级，不涉及概念理解或复杂分析。" + }, + { + "idx": 4061, + "question": "[a] Aluminum alloys are generally viable as lightweight structural materials in humid environments because they are not very susceptible to corrosion by water vapor.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Aluminum alloys are generally viable as lightweight structural materials in humid environments because they are not very susceptible to corrosion by water vapor.），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对铝合金在潮湿环境中耐腐蚀性的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目直接考察对铝合金在潮湿环境中耐腐蚀性的基础概念记忆，只需判断陈述是否正确即可，无需深入理解或分析多个概念。" + }, + { + "idx": 4062, + "question": "[b] Aluminum is not very workable at high temperatures in air, in terms of extrusion and rolling, because a non-protective oxide grows and consumes the metal, converting it to a hard and brittle ceramic.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（答案F表示错误），符合判断题的特征。 | 知识层次: 题目考查对铝在高温下加工性能的基本概念记忆，涉及铝氧化物形成及其对加工性能影响的简单事实判断，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆铝在高温下的氧化行为这一基本事实即可作答。在选择题型中属于最简单的难度等级，不涉及概念理解或复杂分析。" + }, + { + "idx": 4063, + "question": "[c] Aluminum alloys are generally superior to pure aluminum, in terms of yield strength, because their microstructures often contain precipitate phases that strain the lattice, thereby hardening the alloy relative to pure aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案T表示正确），这是典型的判断题特征。题目没有提供多个选项、不需要计算或文字解释，完全符合判断题的定义。 | 知识层次: 题目考查铝合金相对于纯铝的强化机制的基本概念，涉及沉淀相和晶格应变的基础知识，属于基础概念的记忆和理解层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目陈述了一个关于铝合金相对于纯铝的优势的基础事实，即由于沉淀相的存在导致晶格应变从而硬化合金。正确选项直接对应这一基础概念的陈述，无需深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4064, + "question": "[d] Compared to other metals, like steel, pure aluminum is very resistant to failure via fatigue.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（F表示错误），这是典型的判断题特征 | 知识层次: 题目考查对金属疲劳性能的基础概念记忆和理解，属于对纯铝与钢等金属疲劳性能差异的基本认知。 | 难度: 在选择题型中，此题属于基础概念正误判断，仅需记忆纯铝与钢在疲劳失效方面的基本特性对比即可作答，无需复杂分析或推理过程。" + }, + { + "idx": 4065, + "question": "[e] Aluminum exhibits one of the highest melting points of all metals, which makes it difficult and expensive to cast.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Aluminum exhibits one of the highest melting points of all metals, which makes it difficult and expensive to cast），并要求判断其正误（答案：F）。这是典型的判断题形式。 | 知识层次: 题目考查对铝的熔点这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接陈述了一个关于铝的错误事实（铝的熔点实际上相对较低），学生只需要凭借对金属熔点的基本记忆即可判断正误。不需要进行概念理解或复杂分析，属于最基础的难度等级。" + }, + { + "idx": 4066, + "question": "[a] Copper has a higher elastic modulus than aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜的弹性模量比铝高），并要求判断其正确性（答案为T表示正确），这符合判断题的特征 | 知识层次: 题目考查对铜和铝弹性模量这一基本物理性质的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求判断铜和铝的弹性模量高低这一基本概念的正误，属于最基础的概念记忆层次。题目仅涉及单一知识点，无需理解或分析复杂概念，解题步骤简单直接，符合等级1的难度标准。" + }, + { + "idx": 4067, + "question": "[b] The density of copper is closer to that of aluminum than it is to iron.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜的密度更接近铝而不是铁），并要求判断其正确性（答案为F，即错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对铜、铝和铁密度的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆铜、铝和铁的密度关系即可做出正确判断。题目不涉及复杂概念或分析过程，属于最简单的难度等级。" + }, + { + "idx": 4068, + "question": "[c] Bronze is an alloy of copper and zinc.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Bronze is an alloy of copper and zinc），并要求判断其正误（答案F表示错误），符合判断题的特征。 | 知识层次: 题目考查对青铜合金成分的基本概念记忆，仅需判断铜和锌是否为青铜的主要成分，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断青铜是否为铜和锌的合金这一简单事实。在选择题型中，这种直接的正误判断题属于最低难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 4069, + "question": "[d] Copper and its alloys form a green tarnish over time, consisting of sulfides and carbonates.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜及其合金会随时间形成绿色锈蚀），并要求判断其正确性（答案给出T表示正确），符合判断题的特征。 | 知识层次: 题目考查对铜及其合金表面形成的绿色锈蚀物的基本成分的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅要求识别铜及其合金随时间形成绿色锈层（由硫化物和碳酸盐组成）这一事实的正确性，不需要深入理解或分析多个概念。这是最基础的定义性知识记忆题，符合等级1的难度标准。" + }, + { + "idx": 4070, + "question": "[e] Copper is relatively resistant to corrosion by neutral and even mildly basic water, making it useful for freshwater plumbing applications.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜在中性和弱碱性水中相对耐腐蚀），并要求判断其正确性（答案T表示正确），符合判断题的特征。 | 知识层次: 题目考查对铜在特定环境下的耐腐蚀性能这一基础概念的记忆和理解，属于材料科学中的基本原理记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求考生记忆铜在中性和弱碱性水中的耐腐蚀性这一基础事实，无需进行概念理解或复杂分析。正确选项直接对应基础概念记忆层次的知识点，解题步骤简单直接。" + }, + { + "idx": 4071, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is much more abundant in the earth's crust compared to iron or aluminum.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（T/F），且答案直接给出对错判断（F），符合判断题的特征 | 知识层次: 题目考查对铜、铁和铝在地壳中丰度的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念的正误判断，即铜在地壳中的丰度与铁或铝的比较。题目不需要复杂的分析或理解多个概念，只需记忆相关基本事实即可判断正误。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4072, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is one of just a few metals that can be found in metallic form in nature.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（T/F），属于典型的判断题形式 | 知识层次: 题目考查对铜及其合金基本性质的记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆铜在自然界中的存在形式这一简单事实即可作答。在选择题型中，这类直接考察基础概念记忆的题目属于最低难度等级，不需要任何分析或推理过程。" + }, + { + "idx": 4073, + "question": "Select T / F for the following statement regarding copper & copper alloys: Pure and/or annealed copper is more difficult to machine compared to its work-hardened form or its alloys.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为T（True），符合判断题的特征 | 知识层次: 题目考查对铜及其合金加工性能的基础概念记忆，仅需判断纯铜/退火铜与加工硬化铜/合金的机械加工难易对比关系，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铜及其合金的加工性能这一基础概念即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 4074, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is a minor component (by weight) of most brass & bronze alloys.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），且答案以F（False）的形式给出，符合判断题的特征 | 知识层次: 题目考查对铜及其合金（黄铜和青铜）基本组成的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铜在黄铜和青铜合金中的主要成分地位即可作答，无需复杂分析或概念比较。" + }, + { + "idx": 4075, + "question": "Select T / F for the following statement regarding copper & copper alloys: Amongst metals and alloys copper is one of the best conductors of heat.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为T（正确），符合判断题的特征。 | 知识层次: 题目考查对铜及其合金基本物理性质（导热性）的记忆和理解，属于基础概念记忆范畴 | 难度: 该题目属于基础概念正误判断，仅需记忆铜及其合金是优良的热导体这一基本事实即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4076, + "question": "[a] Nickel is majority component (by mass) in certain superalloys such as Waspaloy TM.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为T/F），符合判断题的特征。 | 知识层次: 题目考查对镍在特定超级合金中作为主要成分的基础知识记忆，属于定义和分类的基本概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于镍在Waspaloy TM超合金中为主要成分这一事实陈述的正误。在选择题型中，这类直接考察定义或基本事实记忆的题目属于最低难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 4077, + "question": "[b] Tungsten is the lowest density metal that has structural use.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（F表示错误），符合判断题的特征。 | 知识层次: 题目考查对钨金属基本性质（密度）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆钨的基本物理性质（密度）及其在结构材料中的定位。题目陈述简单明确，只需判断\"钨是结构用金属中密度最低的\"这一说法的正误，无需进行复杂的概念分析或比较。在选择题型中，这属于最基础的知识记忆层次，因此难度等级为1。" + }, + { + "idx": 4078, + "question": "[c] Tantalum offers extremely good corrosion resistance, especially at low temperatures.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Tantalum offers extremely good corrosion resistance, especially at low temperatures），并要求判断其正确性（答案：T），符合判断题的特征。 | 知识层次: 题目考查对钽（Tantalum）腐蚀抗性这一基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆钽(Tantalum)具有良好耐腐蚀性的特性，尤其是低温环境下的表现。题目不涉及概念理解或复杂分析，仅需基础概念记忆即可正确作答，因此属于最低难度等级。" + }, + { + "idx": 4079, + "question": "[d] Magnesium metal is very similar to aluminum, in terms of its physical and mechanical properties.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Magnesium metal is very similar to aluminum, in terms of its physical and mechanical properties），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对镁和铝金属物理和机械性能相似性的基本概念记忆，属于基础知识的认知层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆镁和铝在物理和机械性质上的相似性这一基础知识点即可作答，无需深入理解或分析。" + }, + { + "idx": 4080, + "question": "[e] Beryllium metal is commonly used as an alloying agent in copper metal.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Beryllium metal is commonly used as an alloying agent in copper metal），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对铍金属作为铜合金化剂这一基本事实的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铍金属常用作铜合金的添加剂这一基础事实即可作答，无需理解或分析复杂概念，解题步骤简单直接。" + }, + { + "idx": 4081, + "question": "Increasing the alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\right) content of fireclays results in(a) an increase in maximum service temperature.(b) a decrease in maximum service temperature.", + "answer": "Increasing the alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}\\right)_{3} content of fireclays results in an increase in maximum service temperature.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对氧化铝含量与耐火粘土最高使用温度关系的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即氧化铝含量增加对耐火粘土最高使用温度的影响。正确选项直接对应记忆性知识，无需复杂理解或分析步骤，属于简单概念识别。" + }, + { + "idx": 4082, + "question": "The high-temperature performance of silica refractories is compromised by the presence of even small concentrations of alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\end{array}(a) True(b) False", + "answer": "True. The presence of even small amounts of alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3)}\\right) in silica refractory ceramics compromises their high-temperature performance.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（True/False），且答案直接给出了判断结果（True） | 知识层次: 题目考查对硅质耐火材料高温性能影响因素的基础知识记忆，仅需判断氧化铝的存在是否会影响其性能，属于基本概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接询问关于硅质耐火材料高温性能受氧化铝影响的基本事实，只需记忆相关知识点即可作答，无需深入理解或复杂分析。因此属于难度等级1。" + }, + { + "idx": 4083, + "question": "As the porosity of refractory ceramic bricks increases, what happens to the strength?", + "answer": "Strength decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释孔隙率增加对耐火陶瓷砖强度的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对多孔耐火陶瓷砖强度与孔隙率关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即孔隙率增加对耐火陶瓷砖强度的影响。正确选项直接给出了明确的结论，无需进行复杂的概念解释或分析。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4084, + "question": "As the porosity of refractory ceramic bricks increases, what happens to the chemical resistance?", + "answer": "Chemical resistance decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释孔隙率增加对耐火陶瓷砖化学抗性的影响，答案需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查对多孔耐火陶瓷砖化学抗性随孔隙率变化的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在选择题型中，这道题目属于基本定义简答的难度等级。题目直接考察对\"孔隙率增加对耐火砖化学抵抗性影响\"这一基础概念的简单记忆，只需记住\"孔隙率增加会导致化学抵抗性下降\"这一基本原理即可作答，无需进行概念解释或复杂分析。" + }, + { + "idx": 4085, + "question": "As the porosity of refractory ceramic bricks increases, what happens to the thermal insulation?", + "answer": "Thermal insulation increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释孔隙率增加对隔热性能的影响，答案需要文字解释和论述，而不是选择或判断。 | 知识层次: 题目考查对多孔材料热绝缘性能与孔隙率关系的基本概念理解，属于基础概念记忆和简单应用范畴 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即孔隙率增加对隔热性能的影响。正确选项直接对应基本原理，无需复杂推理或概念整合，属于最基础的难度等级。" + }, + { + "idx": 4086, + "question": "The presence of silica \\left(\\mathrm{SiO}_{2}\\right) in basic refractory ceramics is beneficial to their high-temperature performance.(a) True(b) False", + "answer": "False. The presence of silica \\left(\\mathrm{SiO}_{2}\\right) in basic refractory ceramics is deleterious on their hightemperature performance.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"True\"或\"False\"），答案直接给出了判断结果（False）并附带简要解释，符合判断题的特征。 | 知识层次: 题目考查对基础概念的记忆和理解，即硅在碱性耐火陶瓷中的作用及其对高温性能的影响。 | 难度: 该题目属于基础概念正误判断，仅需记忆基本概念即可作答，无需深入理解或分析。题目直接询问二氧化硅在碱性耐火陶瓷中的作用，正确选项明确指出了其有害影响，属于最基础的定义性知识。" + }, + { + "idx": 4087, + "question": "Basic refractory ceramics are often used for the containment of slags that are rich in(a) silica(b) \\mathrm{CaO}(c) MgO", + "answer": "Basic refractory ceramics are often used for the containment of slags that are rich in \\mathrm{CaO} and/or MgO.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查基础耐火陶瓷材料的基本分类和用途，属于基础概念的记忆和理解范畴 | 难度: 该题目属于基础概念记忆类型，仅需识别和记忆基本耐火陶瓷用于富含CaO和/或MgO的炉渣的常识。在选择题型中，属于最简单的直接记忆类题目，无需复杂理解或分析。" + }, + { + "idx": 4088, + "question": "Silica refractory ceramics are often used for the containment of slags that are rich in(a) silica(b) \\mathrm{CaO}(c) Mg \\mathrm{O}", + "answer": "Silica refractory ceramics are often used for the containment of slags that are rich in silica.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查对硅质耐火陶瓷材料基本用途的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅需识别和记忆基础概念（硅质耐火陶瓷的用途），无需理解或辨析其他选项。属于直接记忆性知识，符合等级1的简单概念识别标准。" + }, + { + "idx": 4089, + "question": "Such that the bond strength across the fiber-epoxy interface is [s] MPa, and the shear yield strength of the epoxy is [y] MPa, compute the minimum fiber length, in millimeters, to guarantee that the fibers are conveying an optimum fraction of force that is applied to the composite. The tensile strength of these carbon fibers is [f] MPa.", + "answer": "the minimum fiber length to guarantee that the fibers are conveying an optimum fraction of force that is applied to the composite is \\frac{[f][d]}{2[s] × 1000} millimeters.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数和公式计算最小纤维长度，答案是一个具体的计算公式和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用多个材料科学概念（如纤维-基体界面结合强度、剪切屈服强度、纤维拉伸强度）进行多步计算，并理解纤维长度与力传递效率之间的关系。虽然涉及公式的直接应用，但需要综合多个参数进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解纤维-环氧树脂界面的粘结强度、环氧树脂的剪切屈服强度以及碳纤维的拉伸强度等多个概念，并进行多步计算和综合分析。题目要求计算最小纤维长度以确保纤维传递最佳比例的力，涉及公式推导和单位转换（MPa到Pa），步骤较为复杂，但选项提供了明确的公式指引，降低了部分难度。" + }, + { + "idx": 4090, + "question": "For an aligned fibrous composite, when a stress is applied in a direction that is parallel to the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d) \\frac{3}{4}(e) 1", + "answer": "For an aligned fibrous composite when the stress is applied parallel to the fibers, the reinforcement efficiency is 1 .", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)到(e)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查的是对齐纤维复合材料在应力平行于纤维方向时的增强效率这一基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆复合材料中纤维排列方向与应力方向平行时的增强效率定义即可作答，无需复杂理解或分析步骤。" + }, + { + "idx": 4091, + "question": "For an aligned fibrous composite, when a stress is applied perpendicular to the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d)\n\\frac{3}{4}(e) 1", + "answer": "begin{tabular}{l|l|l|l|l|l|l|l|l|l|l|}\n\\hline\n\\end{tabular}\nFor an aligned fibrous composite when a stress is applied perpendicular to the fibers, the reinforcement efficiency is 0 .", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)-(e)中选择正确答案，且答案形式为选择题的选项形式 | 知识层次: 题目考查对纤维增强复合材料中增强效率这一基本概念的记忆和理解，特别是当应力垂直于纤维方向时的特殊情况。不需要复杂的计算或分析，只需记住在这种情况下增强效率为零即可。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆复合材料中纤维排列与应力方向关系的基本原理即可作答，无需复杂分析或理解多个概念。题目直接考察了当应力垂直于纤维方向时增强效率为零的定义，属于简单概念识别和直接记忆的范畴。" + }, + { + "idx": 4092, + "question": "For a fibrous composite with fibers that are randomly and uniformly oriented within a specific plane, when a stress is applied in any direction within the plane of the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d) \\frac{3}{4}(e) 1", + "answer": "For a fibrous composite with fibers that are randomly and uniformly oriented within a specific plane,when a stress is applied in any direction within the plane of the fibers, the reinforcement efficiency is \\frac{3}{8}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目涉及复合材料中纤维增强效率的计算，需要理解纤维随机分布时的力学行为，并应用相关公式进行计算。虽然不涉及复杂的多步计算或深度推理，但需要将概念与具体情境关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解纤维增强复合材料中纤维取向与应力方向的关系，并进行多步计算和综合分析。题目涉及中等应用层次的知识，要求考生能够将多个概念关联起来，并正确计算出增强效率。" + }, + { + "idx": 4093, + "question": "For a fibrous composite with fibers that are uniformly distributed and randomly oriented in all directions, when a stress is applied in any direction, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{{ }_{5}}(c) \\frac{3}{8}(d) \\frac{3}{{ }_{4}}(e) 1", + "answer": "For a fibrous composite with fibersthat are uniformly distributed and randomly oriented in all directions, when a stress is applied in any direction, the reinforcement efficiency is 1 / 5.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)-(e)中选择关于纤维增强复合材料增强效率的正确答案 | 知识层次: 题目考查对纤维复合材料增强效率的基本理解和简单应用，需要记忆随机取向纤维的增强效率值，并选择正确的选项。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式或概念即可得出答案。题目明确给出了纤维复合材料在随机取向情况下的增强效率，学生只需记忆或简单应用这一知识点即可选择正确答案，无需进行复杂的计算或变形。因此，在选择题型内属于较低难度。" + }, + { + "idx": 4094, + "question": "A stress-strain test is performed on an aligned fibrous composite such that the force is applied in the longitudinal direction. During the initial stage of the test, which phase bears most of the load?(a) Fibers(b) Matrix", + "answer": "During a stress-strain test that is performed on an aligned fibrous composite, the fibers bear more of the applied load than the matrix in the initial stage of the test.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（Fibers和Matrix）中选择一个正确答案 | 知识层次: 题目考查对纤维增强复合材料在初始受力阶段载荷分布的基本概念的理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆复合材料中纤维和基体在初始受力阶段的负载分配情况。题目直接考察学生对基本定义和分类的记忆，无需深入理解或辨析复杂概念，因此属于简单难度等级。" + }, + { + "idx": 4095, + "question": "Once the fibers fail in a fibrous composite, catastrophic failure of the piece takes place.(a) True(b) False", + "answer": "False. Once the fibers fail in a composite, catastrophic failure of the piece does not take place. Since the broken fibers are still embedded within the matrix, they are still capable of sustaining a diminished load.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案明确给出了True或False的选择，并解释了原因。 | 知识层次: 题目考查对复合材料失效行为的基本概念的理解，属于基础知识的记忆和简单应用。 | 难度: 该题目属于概念理解的对错判断，需要考生理解复合材料中纤维失效后的行为，并判断题目陈述的正确性。虽然涉及基础概念，但需要一定的理解深度，而非简单的记忆性知识。" + }, + { + "idx": 4096, + "question": "How are continuous fibers typically oriented in fibrous composites?(a) Aligned(b) Partially oriented(c) Randomly oriented", + "answer": "Continuous fibers are typically aligned in fibrous composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从三个选项(a)(b)(c)中选择关于纤维复合材料中连续纤维取向方式的正确答案 | 知识层次: 题目考查对纤维复合材料中连续纤维排列方式的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别连续纤维在纤维复合材料中的典型排列方式（对齐）。选项直接对应定义，无需复杂辨析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 4097, + "question": "How are discontinuous fibers typically oriented in fibrous composites?(a) Aligned(b) Partially oriented", + "answer": "Discontinuous fibers may be aligned, partially oriented, and randomly oriented in fibrous composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a) Aligned和(b) Partially oriented中选择关于不连续纤维在纤维复合材料中取向方式的正确答案。 | 知识层次: 题目考查对纤维复合材料中不连续纤维取向方式的基本分类记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆纤维复合材料中不连续纤维的典型取向方式。题目直接给出了正确选项，无需进行复杂的辨析或理解多个概念，因此属于简单概念识别和直接记忆的难度等级。" + }, + { + "idx": 4098, + "question": "If the fiber orientation is random, which type of fibers is normally used?(a) Discontinuous(b) Continuous", + "answer": "Discontinuous fibers are normally used when the fiber orientation is random.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（Discontinuous和Continuous）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查纤维类型与取向关系的基础概念记忆，仅需识别随机取向时通常使用的纤维类型（不连续纤维），属于对材料科学基本分类知识的直接回忆。 | 难度: 在选择题型中，此题属于基础概念记忆题，只需识别\"随机取向纤维通常使用不连续纤维\"这一简单事实，无需理解或辨析其他概念，符合等级1的简单概念识别标准。" + }, + { + "idx": 4099, + "question": "[a] Composites are single-phase materials by definition.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为F表示错误），符合判断题的特征 | 知识层次: 题目考查复合材料定义的基础概念记忆，属于对材料科学基本分类的理解 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆复合材料的定义即可判断正误。题目直接考察对\"复合材料是否为单相材料\"这一基础定义的记忆，无需理解或分析复杂概念，因此属于最低难度等级。" + }, + { + "idx": 4100, + "question": "[b] The term \"composite\" applies to materials that feature polymeric materials only.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案以F（False）给出，符合判断题的特征。 | 知识层次: 题目考查对复合材料定义的基础概念记忆和理解，仅需判断陈述是否符合基本定义，无需复杂分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆复合材料的基本定义即可判断正误，无需深入理解或分析多个概念。" + }, + { + "idx": 4101, + "question": "[c] Structural composites are, in general, highly regarded for their specific strengths.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（T/F），符合判断题的特征 | 知识层次: 题目考查对结构复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断题，仅需记忆结构复合材料的基本特性（高比强度）即可作答，无需深入理解或分析多个概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4102, + "question": "[d] Composites featuring continuous and aligned fibers for reinforcement generally offer properties that are highly isotropic compared to most metals (random polycrystals).", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（F表示错误），符合判断题的特征 | 知识层次: 题目考查对复合材料基本性质的理解，特别是关于纤维增强复合材料各向异性的基础概念。这属于对材料科学基础知识的记忆和简单理解，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念正误判断题，仅需记忆复合材料与金属在性能各向异性方面的基本差异。题目陈述明确，正确选项直接对应基础定义（连续排列纤维复合材料具有各向异性特性），无需复杂分析或概念比较，符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 4103, + "question": "Which of the following materials are typically used as fibers?(a) Graphite/carbon(b) Silicon carbide(c) Silicon nitride(d) Aluminum oxide(e) Glass(f) Boron(g) Steel\nh) Tungsten\ni) Molybdenum", + "answer": "Graphite, silicon carbide, glass, boron, and aluminum oxide are typically used as fibers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作纤维，答案是从给定选项中选择特定材料，符合选择题的特征 | 知识层次: 题目考查对常见纤维材料的基础概念记忆，只需识别哪些材料通常被用作纤维，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（纤维材料的典型种类），但需要考生对多种材料是否常用作纤维有一定的理解和辨析能力。正确选项涉及5种材料，且干扰项中包含一些可能混淆的材料（如钢、钨、钼），这要求考生不仅需要记忆常见纤维材料，还需要进行简单的概念区分。不过题目没有涉及复杂的概念关联或深度分析，因此难度等级为2。" + }, + { + "idx": 4104, + "question": "Match the fiber type 'Whiskers' with its description.", + "answer": "Whiskers are single crystals with extremely large length-to-diameter ratios.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求将纤维类型与其描述进行匹配，答案需要文字解释和论述，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查对纤维类型'Whiskers'的基本定义和特性的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求匹配纤维类型与其基本定义，属于基础概念记忆的简单任务。正确选项直接给出了\"Whiskers\"的明确定义，不需要任何解释或分析步骤，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4105, + "question": "Match the fiber type 'Fibers' with its description.", + "answer": "Fibers are polycrystalline or amorphous materials with small diameters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求将纤维类型与其描述进行匹配，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对纤维类型基本定义的理解和记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求匹配纤维类型与其基本定义，属于基础概念记忆的简单任务。正确选项直接给出了纤维的定义，无需复杂推理或比较分析，符合等级1的基本定义简答标准。" + }, + { + "idx": 4106, + "question": "Match the fiber type 'Wires' with its description.", + "answer": "Wires are large-diameter metals.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求将纤维类型与其描述进行匹配，属于从多个选项中选择正确答案的形式 | 知识层次: 题目考查对纤维类型及其描述的基础概念记忆，仅需识别和匹配\"Wires\"与其定义，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和匹配简单的定义描述（\"Wires are large-diameter metals\"），无需理解或辨析复杂概念，完全符合等级1\"简单概念识别，直接记忆\"的标准。" + }, + { + "idx": 4107, + "question": "For a composite material, which phase normally has the higher elastic modulus?(a) Fiber phase(b) Matrix phase", + "answer": "The fiber phase normally has a higher elastic modulus than the matrix phase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（Fiber phase和Matrix phase）中选择正确答案 | 知识层次: 题目考查复合材料中纤维相和基体相弹性模量的基本概念记忆，属于基础知识的直接问答，无需复杂分析或计算。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即复合材料中纤维相通常具有较高的弹性模量。学生只需直接回忆这一基本事实即可作答，无需进行任何复杂的理解或分析步骤。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4108, + "question": "For a composite material, how does the ductility of the matrix phase normally compare with the ductility of the dispersed phase?(a) more ductile(b) less ductile", + "answer": "A composite's matrix phase is normally more ductile than the dispersed phase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择正确的比较结果，符合选择题的特征 | 知识层次: 题目考查复合材料中基体相和分散相延展性的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆类型，仅需识别复合材料中基体相和分散相的延展性对比这一简单事实。选项直接对应教材定义，无需复杂分析或推理，属于选择题型中最简单的直接记忆类题目。" + }, + { + "idx": 4109, + "question": "Aramid fiber-reinforced composites have very high tensile strengths and relatively low compressive strengths.(a) True(b) False", + "answer": "True. Aramid fiber-reinforced composites have very high tensile strengths and relatively low compressive strength.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其真伪（True/False），答案直接给出判断结果，符合判断题的特征 | 知识层次: 题目考查对Aramid纤维增强复合材料基本力学性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆Aramid fiber-reinforced composites的基本特性（高拉伸强度和低压缩强度）即可做出正确选择。题目不涉及复杂概念或需要深入理解，属于最基础的难度等级。" + }, + { + "idx": 4110, + "question": "Which of aramid and metal fibers have higher strength-to-weight ratios?(a) Aramid fibers(b) Metal fibers", + "answer": "Aramid fibers have higher strength-to-weight ratios than metal fibers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对芳纶纤维和金属纤维强度重量比这一基本概念的简单记忆和比较，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即比较芳纶纤维和金属纤维的强度重量比。学生只需记住芳纶纤维具有更高的强度重量比这一事实即可选择正确答案，无需进行复杂的理解或分析。因此，该题目在选择题型内属于简单概念识别，直接记忆的难度等级。" + }, + { + "idx": 4111, + "question": "Carbon fiber-reinforced composites have relatively high strengths?", + "answer": "Carbon fiber-reinforced composites have relatively high strengths.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了该陈述的判断结果。 | 知识层次: 题目考查对碳纤维增强复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳纤维增强复合材料是否具有较高强度这一基本事实。在选择题型中，这种直接考察定义或基本特性的题目属于最简单的难度等级，不需要复杂理解或分析过程。" + }, + { + "idx": 4112, + "question": "Carbon fiber-reinforced composites have relatively high stiffnesses?", + "answer": "Carbon fiber-reinforced composites have relatively high stiffnesses.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了陈述句的重复，符合判断题的特征 | 知识层次: 题目考查对碳纤维增强复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳纤维增强复合材料是否具有较高刚度这一基本事实。在选择题型中，这种直接考察定义或基本特性的题目属于最简单的难度等级，无需复杂推理或概念比较。" + }, + { + "idx": 4113, + "question": "Carbon fiber-reinforced composites have high service temperatures (>200 degrees C)?", + "answer": "Carbon fiber-reinforced composites have high service temperatures (>200 degrees C).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了陈述句本身，符合判断题的特征。 | 知识层次: 题目考查对碳纤维增强复合材料基本性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳纤维增强复合材料是否具有高温使用性能（>200°C）这一基本事实。在选择题型中，此类正误判断题是最简单的类型，无需理解或分析复杂概念，仅需回忆相关定义即可作答。" + }, + { + "idx": 4114, + "question": "Which of the following materials are typically used as whiskers?(a) graphite/carbon(b) silicon carbide(c) silicon nitride(d) aluminum oxide(e) glass(f) boron(g) steel\nh) tungsten\ni) molybdenum", + "answer": "Graphite, silicon carbide, silicon nitride, and aluminum oxide are typically used as whiskers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作晶须（whiskers），答案给出了具体的选项组合，符合选择题的特征。 | 知识层次: 题目考查对常用晶须材料的基础概念记忆，只需从选项中识别出典型的晶须材料，无需深入分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆多种材料中哪些通常用作晶须（whiskers），但选项中的正确材料（石墨/碳、碳化硅、氮化硅和氧化铝）是材料科学中常见的晶须材料，属于基础概念记忆范畴。学生只需通过课堂学习或教材内容即可掌握这些知识点，无需进行复杂的分析或深度理解。错误选项（如玻璃、钢）与正确选项的差异较为明显，降低了辨析难度。因此，该题目在选择题型内属于等级2难度，需要一定的概念理解和简单辨析能力。" + }, + { + "idx": 4115, + "question": "Which of the following materials are typically used as wires in composites?(a) graphite/carbon(b) silicon carbide(c) silicon nitride\n\\mathrm{d}) aluminum oxide(e) glass(f) boron(g) steel\nh) tungsten\ni) molybdenum", + "answer": "Steel, tungsten, and molybdenum are typically used as wires in composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作复合材料中的线材，答案给出了具体的选择项。 | 知识层次: 题目考查对复合材料中常用线材的基本概念和分类的记忆，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆类型，要求考生识别复合材料中常用的金属丝材料。虽然选项较多（9个），但正确答案（steel, tungsten, molybdenum）都是典型的金属丝材料，在材料科学基础课程中会明确提及。需要考生对这些材料的典型应用有一定记忆和理解，但不需要复杂的分析过程。相比等级1的纯记忆题目，本题需要对材料分类和应用有基本理解，因此属于等级2难度。" + }, + { + "idx": 4116, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better fracture toughnesses?", + "answer": "Ceramic-matrix composites have higher fracture toughnesses than other ceramic materials.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Ceramic-matrix composites have higher fracture toughnesses than other ceramic materials），答案直接给出了判断结果（是或否），符合判断题的特征。 | 知识层次: 题目考查对陶瓷基复合材料基本性能（断裂韧性）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求对基础概念进行正误判断，即陶瓷基复合材料是否比其他陶瓷材料具有更高的断裂韧性。题目涉及的知识层次为基础概念记忆，不需要深入理解或复杂分析，因此属于最简单的难度等级。" + }, + { + "idx": 4117, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better oxidation resistance?", + "answer": "The answer is not provided in the given information.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断陶瓷基复合材料是否比其他陶瓷材料具有更好的抗氧化性，属于判断陈述对错的题型。答案形式也符合判断题的特征。 | 知识层次: 题目考查对陶瓷基复合材料氧化抗性的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆性知识，即陶瓷基复合材料与其他陶瓷材料在抗氧化性方面的比较。题目要求的是对基本概念的正误判断，不需要深入理解或复杂分析，因此属于等级1的难度。" + }, + { + "idx": 4118, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better stability at elevated temperatures?", + "answer": "The answer is not provided in the given information.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（陶瓷基复合材料在高温下是否比其他陶瓷材料具有更好的稳定性），答案形式为判断性结论 | 知识层次: 题目考查对陶瓷基复合材料在高温下稳定性的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即陶瓷基复合材料在高温下的稳定性与其他陶瓷材料的比较。题目要求的是对定义或分类的基本记忆，不需要深入理解或分析多个概念。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4119, + "question": "Which of the following materials are typically used as stabilizers in transformation-toughened ceramic-matrix composites?(a) \\mathrm{CaO}(b) MgO(c) \\mathrm{Y}_{2} \\mathrm{O}_{3}(d) \\mathrm{CeO}(e) \\mathrm{Al}_{2} \\mathrm{O}_{3}(f) \\mathrm{SiC}", + "answer": "(\\mathrm{CaO}, MgO, \\mathrm{Y}_{2} \\mathrm{O}_{3}, and \\mathrm{CeO} are typically used as stabilizers in transformation-toughened ceramicmatrix composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的多个选项中选择出正确的材料作为稳定剂，符合选择题的特征 | 知识层次: 题目考查对特定材料在陶瓷基复合材料中作为稳定剂的基础知识记忆，属于基础概念的记忆和理解层面。 | 难度: 该题目属于基础概念记忆类型，要求考生识别并记忆哪些材料通常用作相变增韧陶瓷基复合材料的稳定剂。虽然选项较多（6个），但正确选项明确且属于常见稳定剂（CaO, MgO, Y2O3, CeO），只需简单记忆即可作答，无需复杂分析或深度理解。在选择题型中属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 4120, + "question": "Do carbon-carbon composites exhibit high tensile moduli at elevated temperatures?", + "answer": "Carbon-carbon composites have high tensile moduli at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（碳碳复合材料在高温下是否具有高拉伸模量），答案直接给出了对错判断。这符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本性能的记忆和理解，属于基础概念层面的知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即碳-碳复合材料在高温下的拉伸模量特性。正确选项直接陈述了定义性知识，无需复杂理解或分析，属于最基本的概念正误判断。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4121, + "question": "Do carbon-carbon composites exhibit high tensile strengths at elevated temperatures?", + "answer": "Carbon-carbon composites have high tensile strengths at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"Do carbon-carbon composites exhibit high tensile strengths at elevated temperatures?\"），而答案直接给出了判断结果（\"Carbon-carbon composites have high tensile strengths at elevated temperatures.\"）。这符合判断题的特征，即对陈述的真假进行判断。 | 知识层次: 题目考查对碳碳复合材料在高温下性能的基础概念记忆，仅需了解其基本特性即可回答，无需复杂分析或应用。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳碳复合材料在高温下是否具有高拉伸强度的基本事实。题目形式为简单的是非判断，不涉及概念理解或复杂分析，符合选择题型中最基础的难度等级。" + }, + { + "idx": 4122, + "question": "Do carbon-carbon composites exhibit resistance to creep?", + "answer": "Carbon-carbon composites are highly resistant to creep.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个简单的陈述句，询问碳碳复合材料是否具有抗蠕变性，答案直接给出了对错判断（\"highly resistant to creep\"），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料抗蠕变性能这一基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，只需判断碳-碳复合材料是否具有抗蠕变性能这一简单事实。题目不要求理解复杂概念或进行多步骤分析，属于最基本的概念正误判断层级。" + }, + { + "idx": 4123, + "question": "Do carbon-carbon composites exhibit large fracture toughness values?", + "answer": "Carbon-carbon composites have large fracture toughness values.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"碳碳复合材料是否具有大的断裂韧性值\"，答案直接给出了对错判断。这符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本性能的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳碳复合材料是否具有较大的断裂韧性值这一基本事实。正确选项直接陈述了定义性知识，无需复杂理解或分析过程，在选择题型中属于最简单的正误判断级别。" + }, + { + "idx": 4124, + "question": "Do carbon-carbon composites exhibit high thermal conductivities?", + "answer": "Carbon-carbon composites have high thermal conductivities.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"碳碳复合材料是否具有高热导率\"这一陈述的正确性。答案直接给出了明确的判断结果(\"具有高热导率\")，符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断，仅需记忆碳-碳复合材料的基本特性（高导热性）即可作答，无需理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4125, + "question": "Do carbon-carbon composites exhibit low coefficients of thermal expansion?", + "answer": "Carbon-carbon composites have low coefficients of thermal expansion.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（碳-碳复合材料是否具有低热膨胀系数），答案直接给出了对陈述的判断（是/否）。这符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 在选择题型内，该题目仅涉及基础概念记忆，即碳碳复合材料的热膨胀系数特性。正确选项直接陈述了定义性知识，无需复杂理解或分析。属于最基础的正误判断，符合等级1的难度标准。" + }, + { + "idx": 4126, + "question": "Do carbon-carbon composites exhibit resistance to oxidation at elevated temperatures?", + "answer": "The answer does not specify resistance to oxidation at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断碳碳复合材料在高温下是否具有抗氧化性，答案只需判断对错即可。 | 知识层次: 题目考查对碳碳复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即碳-碳复合材料在高温下的氧化抗性这一基本定义。正确选项直接陈述了答案未明确说明氧化抗性，无需深入理解或分析，属于最基础的正误判断。因此，在选择题型内属于等级1难度。" + }, + { + "idx": 4127, + "question": "Are carbon-carbon composites low cost?", + "answer": "The answer does not specify low cost.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，询问碳碳复合材料是否低成本，答案给出了明确的判断（没有明确说明低成本），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料成本这一基本概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 该题目属于基础概念记忆层次，仅需判断\"碳碳复合材料是否低成本\"这一简单陈述的正确性。正确选项直接给出了明确答案，不需要任何推理或概念间的比较分析，是最基础的正误判断题。" + }, + { + "idx": 4128, + "question": "Laminar composites have high strengths in all directions (in three dimensions).(a) True(b) False", + "answer": "False. Laminar composites have high strengths in all directions only in their two-dimensional planes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附带简要解释。 | 知识层次: 题目考查对层状复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆层压复合材料的基本特性（二维平面高强度）即可直接判断选项正误，无需理解或分析复杂概念。" + }, + { + "idx": 4129, + "question": "The strong outer sheets of sandwich panels are separated by a layer of material that is(a) less dense than the outer sheet material(b) more dense than the outer sheet material", + "answer": "The strong outer sheets of sandwich panels are separated by a layer of material that is less dense than the outer sheet material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择正确的描述，符合选择题的特征 | 知识层次: 题目考查对夹层板结构的基本概念的记忆和理解，即夹层板中间层材料的密度特性。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆三明治板结构中夹层材料的密度特性与外表层材料的关系。题目直接给出了定义性的知识，无需复杂分析或比较，属于最简单的概念识别级别。" + }, + { + "idx": 4130, + "question": "To what temperature would 23.0kg of some material at 100^{\\circ} C be raised if 255kJ of heat is supplied? Assume a C_{p} value of 423 J/ kg-K for this material.\n(A) 26.2^{\\circ} C\n(B) 73.8^{\\circ} C\n(C) 126^{\\circ} C\n(D) 152^{\\circ} C", + "answer": "the final temperature is 126^{\\circ} C, which corresponds to answer C.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了四个选项（A、B、C、D）并给出了最终答案对应的选项。 | 知识层次: 题目涉及基本的热力学公式应用（Q = mC_pΔT），只需要直接套用公式进行简单计算即可得出答案，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（Q = m*Cp*ΔT）并进行简单计算即可得出答案。解题步骤清晰且直接，无需公式变形或多步骤推理，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 4131, + "question": "A rod of some material 0.50{m} long elongates 0.40mm on heating from 50^{\\circ} C to 151^{\\circ} C. What is the value of the linear coefficient of thermal expansion for this material?\n(A) 5.30 × 10^{-6}\\left({ }^{\\circ} C\\right)^{-1}\n(B) 7.92 × 10^{-6}\\left({ }^{\\circ} C C\\right)^{-1}\n(C) 1.60 × 10^{-5}\\left({ }^{\\circ} C\\right)^{-1}\n(D) 1.24 × 10^{-6}\\left({ }^{\\circ} C_{-}^{1}\\right.", + "answer": "the linear coefficient of thermal expansion for this material is 7.92 × 10^{-6} \\left(^{\\circ}c\\right)^{-1}, which is answer b.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的线性热膨胀系数值，并且提供了多个选项供选择 | 知识层次: 题目考查的是线性热膨胀系数的基本公式应用，只需要套用公式进行简单计算即可得出答案，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单难度。题目仅需要直接套用线性热膨胀系数的基本公式，并进行简单的数值计算。解题步骤不涉及公式变形或多步骤选择，仅需正确识别和应用公式即可得出答案。因此，在选择题型内属于等级2的简单公式选择和应用难度。" + }, + { + "idx": 4132, + "question": "A 10 meter long square bar of 316 stainless steel (edge length of 5 cm, with a modulus of 193 \\mathrm{GPa} and a yield point of 290 MPa ) is bolted securely in place when its installation temperature was around [1]^{\\circ} C. What is the expected thermal stress in the bar when its service temperature reaches [F]^{o} C ? Enter a negative indicate compressive stress, if necessary. The thermal expansion coefficient of 316 stainless steel is 16.0 × 10^{-6} \\mathrm{I} /{ }^{\\circ} C.", + "answer": "sigma_{th} = (193,000)(16 × 10^{-6})([i] - [f]) MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解热应力，答案给出了具体的计算公式和单位，需要代入数值进行计算。 | 知识层次: 题目主要考查热应力公式的直接应用，仅需代入给定参数进行简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了所有必要的参数和公式，只需要将给定的数值代入公式即可得到答案。不需要额外的推导或组合多个公式，解题步骤简单直接。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4133, + "question": "Which of the following 1kg samples is expected to change temperature the least if 100kJ of heat is perfectly transferred to each of them at a constant pressure of 1 atmosphere. The initial temperature of each specimen is 25^{\\circ} C. (a) Aluminum (b) Copper (c) Gold (d) Borosilicate Glass (e) Polystyrene", + "answer": "polystyrene will experience the smallest temperature change.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个预期温度变化最小的材料，属于典型的选择题形式。 | 知识层次: 题目需要应用比热容的基本概念和简单计算来确定不同材料在相同热量输入下的温度变化。虽然涉及多个材料的比热容值，但主要考察的是对这些数值的直接应用和比较，不需要复杂的分析或推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用比热容公式（Q=mcΔT）并比较不同材料的比热容值即可得出答案。解题步骤单一，无需公式变形或多步骤计算，属于基础概念的直接应用。" + }, + { + "idx": 4134, + "question": "If you were to locally heat identical geometry plates of the materials listed below with the same heat source, which would increase in temperature the fastest? (a) Polystyrene (b) Aluminum (c) Copper (d) Gold (e) Borosilicate Glass", + "answer": "In this scenario, the material with the highest thermal conductivity will conduct heat the fastest. Therefore this material will absorb heat and increase in temperature the fastest. In this case, copper has the highest thermal conductivity.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对材料热导率这一基本概念的简单记忆和理解，只需知道不同材料的热导率差异即可直接选择正确答案，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解热导率的基本概念，但只需比较几种常见材料的热导率即可得出答案。题目提供了明确的材料选项，且铜的热导率在选项中最高是较为基础的知识点，不需要复杂的分析或计算步骤。因此，该题目属于概念理解和简单辨析的层次。" + }, + { + "idx": 4135, + "question": "This ceramic outlier has the highest room-temperature thermal conductivity of about 2,000 watts per meter per kelvin, a value that is five time higher than the best thermally conductive metals.\n(a) \\mathrm{Al}_{2} \\mathrm{O}_{3}\n(b) \\mathrm{CaF}_{2}\n(c) \\mathrm{TiO}_{2}\n(d) \\mathrm{SrTiO}_{3}\n(e) C (diamond)", + "answer": "Diamond has the highest thermal conductivity of these options.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择具有最高室温热导率的陶瓷材料，答案形式为选择特定选项。 | 知识层次: 题目考查对材料热导率这一基本概念的记忆和理解，特别是对特定材料（如金刚石）的热导率特性的记忆。题目不涉及复杂的计算或分析，只需从选项中识别出具有最高热导率的材料。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别具有最高室温热导率的陶瓷材料。正确选项（diamond）是常见的高热导率材料，属于直接记忆性知识，无需复杂分析或理解多个概念。" + }, + { + "idx": 4136, + "question": "Which two of the following are ferromagnetic materials? \\\\(a) Aluminum oxide \\\\(b) Copper \\\\ c) Aluminum \\\\ d) Titanium \\\\ e) Iron ( \\alpha ferrite) \\\\ f) Nickel \\\\ g) MnO \\\\ h) \\mathrm{Fe}_{3} \\mathrm{O}_{4} \\\\ i) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}\n}", + "answer": "Iron ( \\alpha ferrite) and nickel are ferromagnetic materials.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择两个铁磁性材料，符合选择题的特征 | 知识层次: 题目考查对铁磁性材料的基本概念和分类的记忆，只需识别哪些材料属于铁磁性材料，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅需识别和记忆基础概念中的铁磁性材料。正确选项（Iron (α ferrite) and nickel）是常见的铁磁性材料，属于直接记忆性知识，无需复杂辨析或深度理解。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4137, + "question": "Which of the following materials display(s) antiferromagnetic behavior?(a) Aluminum oxide(b) Copper(c) Aluminum(d) Titanium(e) Iron ( \\alpha ferrite)(f) Nickel(g) MnO\nh) \\mathrm{Fe}_{3} \\mathrm{O}_{4}\ni) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}", + "answer": "(\\mathrm{MnO} is an antiferromagnetic material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择显示反铁磁行为的材料，符合选择题的特征 | 知识层次: 题目考查对反铁磁性材料的基本概念和分类的记忆，只需识别哪些材料具有反铁磁性行为，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目需要考生理解并辨析不同材料的磁性行为，特别是区分反铁磁性与其他磁性（如铁磁性、顺磁性等）。虽然题目提供了多个选项，但正确选项（MnO）是典型的反铁磁性材料，属于基础概念记忆的范畴。考生需要掌握材料分类的基本原理，但不需要复杂的分析或深度理解，因此属于中等难度（等级2）。" + }, + { + "idx": 4138, + "question": "Which of the following are ferrimagnetic materials?(a) Aluminum oxide(b) Copper(c) Aluminum(d) Titanium(e) Iron ( \\alpha ferrite)(f) Nickel(g) MnO\nh) \\mathrm{Fe}_{3} \\mathrm{O}_{4}\ni) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}", + "answer": "(\\mathrm{Fe}_{3} \\mathrm{O}_{4} and \\mathrm{NiFe}_{2} \\mathrm{O}_{4} are ferrimagnetic materials.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择出属于亚铁磁性材料的正确答案 | 知识层次: 题目考查对铁磁性材料分类的基本概念记忆，只需识别给定的材料中哪些属于铁磁性材料，不涉及复杂分析或计算。 | 难度: 该题目属于选择题型，考察的是对铁磁性材料的基础概念记忆。虽然需要识别多个选项中的铁磁性材料，但正确选项（Fe3O4和NiFe2O4）是典型的铁磁性材料，属于基础概念记忆范畴。学生只需记住这些材料的分类即可作答，无需进行复杂的分析或比较。因此，在选择题型中属于中等偏下难度。" + }, + { + "idx": 4139, + "question": "The formula for yttrium iron garnet \\left(\\mathrm{Y}_{3} \\mathrm{Fe}_{3} \\mathrm{O}_{12}\\right) may be written in the form \\mathrm{Y}_{3}^{*} \\mathrm{Fe}_{2}^{*} \\mathrm{Fe}_{3}^{d} \\mathrm{O}_{12}^{2}, where the superscripts a, c, and d represent different sites on which the \\mathrm{Y}^{3+} and \\mathrm{Fe}^{3+} ions are located. The spin magnetic moments for the \\mathrm{Y}^{3+} and \\mathrm{Fe}^{\\text {out }} ions positioned in the \\mathrm{a} and C sites are oriented parallel to one another and antiparallel to the \\mathrm{Fe}^{3+} ions in \\mathrm{d} sites. Compute the number of Bohr magnetons associated with each \\mathrm{Y}^{3+} ion, given the following information: (1) each unit cell consists of eight formula \\left(\\mathrm{Y}_{3} \\mathrm{Fe}_{5} \\mathrm{O}_{12}\\right) units; (2) the unit cell is cubic with an edge length of 1.2376nm; (3) the saturation magnetization for this material is 1.0 × 10^{4} \\mathrm{~A} / m; and (4) assume that there are 5 Bohr magnetons associated with each \\mathrm{Fe}^{3+} ion.", + "answer": "the number of bohr magnetons associated with each \\mathrm{y}^{3+} ion is 1.75 \\mathrm{bm}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和信息来求解每个Y3+离子所关联的玻尔磁子数。解答过程涉及单位晶胞的计算、饱和磁化强度的应用以及玻尔磁子数的推导，这些都是典型的计算题特征。答案以具体数值形式给出，进一步确认了这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及饱和磁化强度、单位晶胞体积、磁矩计算等概念的综合应用，需要理解不同离子位置的磁矩取向关系，并进行数值计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和多个概念的关联应用。需要理解晶体结构、磁矩计算、单位转换等知识，并进行综合分析。具体步骤包括计算单位体积内的磁矩、考虑离子排列方向、应用给定的磁化强度数据等，解题过程复杂且需要较高的计算能力。" + }, + { + "idx": 4140, + "question": "At the Curie temperature, the saturation magnetization abruptly diminishes. Which of the following magnetic material types will have Curie temperatures?(a) Diamagnetics(b) Paramagnetics(c) Ferromagnetics(d) Antiferromagnetics(e) Ferrimagnetics", + "answer": "Ferromagnetic and ferrimagnetic materials will have Curie temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案明确指出了正确选项 | 知识层次: 题目考查对磁性材料基本分类和特性的记忆，特别是关于居里温度与不同类型磁性材料的关系。只需要记住哪些材料具有居里温度即可回答，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（Curie温度的定义和适用材料类型），但需要学生能够区分不同磁性材料的特性，特别是Ferromagnetic和Ferrimagnetic材料的共同点。这要求一定的概念理解和简单辨析能力，而不仅仅是直接记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4141, + "question": "In a polycrystalline material, each grain will always consist of just a single domain.(a) True(b) False", + "answer": "False. In a polycrystalline material, each grain may consist of more than one domain.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"True\"或\"False\"），答案直接给出了判断结果（False）并附带简要解释，符合判断题的特征。 | 知识层次: 题目考查对多晶材料中晶粒和畴的基本概念的理解，属于基础概念的记忆和简单应用 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆多晶材料中晶粒与畴的基本关系即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4142, + "question": "With increasing temperature antiferromagnetic materials eventually become which of the following?(a) Diamagnetics(b) Paramagnetics(c) Ferromagnetics(d) Antiferromagnetics(e) Ferrimagnetics", + "answer": "With increasing temperature antiferromagnetic materials eventually become paramagnetic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为从给定选项中选择一个最合适的选项。 | 知识层次: 题目考查对反铁磁材料在温度升高时转变为顺磁性这一基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解反铁磁材料在温度升高时的行为变化，但只需掌握基础概念（反铁磁性与顺磁性的转变关系）即可作答，不需要进行复杂的概念区分或多步骤推理。属于概念理解和简单辨析的层次。" + }, + { + "idx": 4143, + "question": "Which type(s) of magnetic materials may be classified as either soft or hard?(a) Diamagnetic(b) Paramagnetic(c) Ferromagnetic(d) Antiferromagnetic(e) Ferrimagnetic", + "answer": "Ferromagnetic and ferrimagnetic materials may be classified as either soft or hard.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案明确指出了正确选项 | 知识层次: 题目考查对磁性材料分类的基础概念记忆，只需要理解并区分不同类型的磁性材料是否可以被分类为软磁或硬磁，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解磁性材料的基本分类（软磁和硬磁）并能够区分哪些类型（铁磁和亚铁磁）可以进一步细分为这两类。虽然涉及多个概念，但主要是基础概念的记忆和简单辨析，不需要复杂的分析或深度理解。" + }, + { + "idx": 4144, + "question": "Which of the following characteristics are displayed by soft magnetic materials in terms of hysteresis loop size?", + "answer": "Soft materials have relatively small relative hysteresis loops.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择关于软磁材料磁滞回线特性的正确答案 | 知识层次: 题目考查软磁材料的基本特性——磁滞回线大小的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求识别软磁材料的基本特性（磁滞回线较小），属于直接记忆的基础概念，无需复杂分析或比较。" + }, + { + "idx": 4145, + "question": "Which of the following characteristics are displayed by soft magnetic materials in terms of magnetization and demagnetization fields?", + "answer": "Magnetization and demagnetization may be achieved using relatively low applied fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择符合软磁材料特性的正确答案 | 知识层次: 题目考查对软磁材料在磁化和退磁过程中特性的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需识别软磁材料在磁化和退磁方面的基本特性（即\"可用较低外加磁场实现\"这一直接记忆点）。在选择题型中属于最简单的概念识别类题目，无需理解或辨析过程，完全符合等级1\"简单概念识别，直接记忆\"的标准。" + }, + { + "idx": 4146, + "question": "Which of the following characteristics are displayed by hard magnetic materials in terms of hysteresis loop size?", + "answer": "Hard materials have relatively large hysteresis loops.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释硬磁材料在磁滞回线尺寸方面表现出的特性，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查硬磁材料的基本特性（磁滞回线大小）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对硬磁材料基本特性的记忆，属于最基础的定义简答。题目直接询问硬磁材料磁滞回线的特征，正确选项明确给出了定义性描述，不需要任何解释或分析步骤。这符合等级1\"基本定义简答\"的标准，是选择题型中最简单的类型。" + }, + { + "idx": 4147, + "question": "Which of the following characteristics are displayed by hard magnetic materials in terms of magnetization and demagnetization field requirements?", + "answer": "Magnetization and demagnetization require relatively high applied fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对硬磁材料在磁化和退磁过程中所需磁场特性的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题中属于中等偏下难度，需要理解硬磁材料的基本特性（磁化和退磁需要较高外场）这一概念，但不需要进行复杂的概念比较或分析。属于基础概念理解和简单辨析层次。" + }, + { + "idx": 4148, + "question": "What is the order of magnitude wavelength for visible light?(a) 0.5 Angstroms(b) 0.5 nanometers(c) 0.5 micrometers(d) 0.5 millimeters(e) 0.5 meters(f) 0.5 kilometers", + "answer": "The wavelength of visible light is on the order of 0.5 \\mathrm{micrometers}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案明确指出了正确选项 | 知识层次: 题目考查对可见光波长范围这一基础概念的简单记忆，属于材料科学中最基础的光学知识范畴，不需要任何计算或分析过程。 | 难度: 在选择题型中，该题目仅需基础概念记忆，即对可见光波长大小的直接记忆。选项提供了不同数量级的波长，但正确答案（0.5 micrometers）是可见光波长的典型值，属于直接识别的简单概念，无需复杂理解或辨析。" + }, + { + "idx": 4149, + "question": "In the visible spectrum, a thick metal specimen will be(a) Transparent(b) Translucent(c) Opaque", + "answer": "In the visible spectrum, a thick metal specimen is opaque.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对金属在可见光谱中光学性质的基本概念记忆，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别金属在可见光谱中的基本特性（不透明性），无需复杂理解或辨析步骤。" + }, + { + "idx": 4150, + "question": "In the visible spectrum, an electrical insulator that is a single crystal and without porosity is normally(a) Transparent(b) Opaque(c) Translucent", + "answer": "In the visible spectrum, an electrical insulator that is a single crystal and without porosity\nnormally transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Transparent, Opaque, Translucent）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对材料光学性质的基本概念记忆和理解，特别是关于单晶无孔绝缘体在可见光谱中的透明性这一基础知识点。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别单晶无孔绝缘体在可见光谱下的透明特性。选项直接对应材料科学基本概念，无需复杂分析或概念辨析，属于最简单的难度等级。" + }, + { + "idx": 4151, + "question": "Match the type of light transmission with its description: Transmits light with relative little absorption.", + "answer": "A transparent material transmits light with relatively little absorption.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求匹配光的传输类型与其描述，并给出了一个具体的描述例子。虽然看起来像匹配题，但答案是以完整的句子形式给出的解释，类似于简答题需要文字解释和论述的形式。 | 知识层次: 题目考查对透明材料基本定义和特性的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，此题仅要求识别基本定义（透明材料的特性），属于最基础的概念记忆层面。题目直接给出定义描述与正确选项的对应关系，无需任何分析或推理步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4152, + "question": "Match the type of light transmission with its description: Transmits light diffusely.", + "answer": "A translucent material transmits light diffusely.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求将光的传输类型与其描述进行匹配，属于从多个选项中选择正确答案的类型 | 知识层次: 题目考查对材料光学性质基本概念的记忆和理解，即透明材料和半透明材料在光传输特性上的区别。这属于基础概念记忆层次的知识点。 | 难度: 在选择题型中，该题目仅要求识别并匹配基础概念的定义（translucent material与diffuse light transmission的关系），属于直接记忆性知识，无需复杂理解或辨析步骤。" + }, + { + "idx": 4153, + "question": "Match the type of light transmission with its description: Is impervious to light transmission.", + "answer": "An opaque material is impervious to light transmission.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求匹配光的传输类型与其描述，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断 | 知识层次: 题目考查对不透明材料基本定义和特性的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，此题仅要求识别并匹配基础定义（不透明材料的特性），属于最基础的概念记忆层面。题目直接给出定义描述，只需选择对应术语，无需任何分析或推理过程，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 4154, + "question": "In the visible spectrum, a semiconductor that is a single crystal and nonporous may be(a) Transparent(b) Translucent(c) Opaque", + "answer": "In the visible spectrum, a semiconductor that is a single crystal and nonporous may be transparent or opaque.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a) Transparent、(b) Translucent、(c) Opaque中选择可能的正确答案，符合选择题的特征。 | 知识层次: 题目考查对半导体光学性质的基本概念记忆和理解，只需知道单晶非多孔半导体在可见光谱中可能呈现透明或不透明的特性即可回答，不涉及复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解半导体在可见光谱中的光学性质（透明或不透明），并辨析单晶非多孔结构对光学特性的影响。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力。" + }, + { + "idx": 4155, + "question": "To which of the following electromagnetic radiation types are bulk metals opaque?(a) radio waves(b) microwaves(c) infrared radiation(d) ultraviolet radiation(e) X-rays", + "answer": "Bulk metals are opaque to the following radiation types: radio waves, microwaves, infrared radiation, and ultraviolet radiation.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)-(e)中选择正确的电磁辐射类型，属于典型的选择题形式。 | 知识层次: 题目考查对金属对不同电磁波段的透明性的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在选择题中属于中等偏下难度，题目考察的是对金属对不同电磁波段的透明性这一基础概念的记忆和理解。虽然需要记住多个波段（无线电波、微波、红外辐射、紫外辐射）的共性特征，但不需要进行复杂的比较分析或推导过程，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 4156, + "question": "Every nonmetallic material becomes opaque to electromagnetic radiation having some wavelength.(a) True(b) False", + "answer": "True. Every nonmetallic material becomes opaque to electromagnetic radiation having some wavelength. For all nonmetallic materials there is some maximum wavelength below which electronexcitations across the band gap will occur. This results in the adsorption of radiation, and, consequently, the material becomes opaque.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（True/False），并且答案直接给出了对错判断和简要解释，符合判断题的特征。 | 知识层次: 题目考查非金属材料对电磁辐射不透明性的基本原理的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆非金属材料对电磁辐射的基本特性即可作答，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4157, + "question": "Match the following material types with their light transmission characteristics: Single crystal electrical insulators - Opaque, Translucent, Transparent", + "answer": "Single crystal electrical insulators are transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求将材料类型与光传输特性进行匹配，属于从多个选项中选择正确答案的类型 | 知识层次: 题目考查对单晶电绝缘体光学特性的基本概念记忆，属于定义和分类层面的基础知识点。 | 难度: 在选择题型中，该题目仅要求考生记忆单晶电绝缘体的光传输特性（透明），属于基础概念的直接识别和记忆。题目不涉及复杂辨析或多概念比较，符合等级1的简单概念识别标准。" + }, + { + "idx": 4158, + "question": "Match the following material types with their light transmission characteristics: Polycrystalline and nonporous electrical insulators - Translucent, Transparent, Opaque", + "answer": "Polycrystalline and nonporous electrical insulators are translucent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Translucent, Transparent, Opaque）中选择与材料类型（Polycrystalline and nonporous electrical insulators）相匹配的光传输特性，符合选择题的特征。 | 知识层次: 题目考查对材料类型及其光传输特性的基本概念记忆和理解，属于基础知识的直接应用，无需复杂分析或综合推理。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度。题目要求匹配材料类型与其透光特性，正确选项直接给出了明确的定义（半透明），无需复杂分析或深度理解，仅需基础概念的记忆即可作答。" + }, + { + "idx": 4159, + "question": "Match the following material types with their light transmission characteristics: Porous electrical insulators - Transparent, Opaque, Translucent", + "answer": "Porous electrical insulators are opaque to visible light.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Transparent, Opaque, Translucent）中选择与材料类型（Porous electrical insulators）匹配的光传输特性。 | 知识层次: 题目考查对材料光学特性分类的基础概念记忆，仅需将材料类型与透光性进行简单匹配，不涉及复杂推理或综合分析。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆材料的光学特性分类。题目直接给出了材料类型和其对应的光传输特性，无需进行复杂辨析或深度理解，属于最简单的概念识别类型。" + }, + { + "idx": 4160, + "question": "For noncubic crystals, the index of refraction is lowest in the crystallographic direction that has the(a) Highest atomic packing density(b) Lowest atomic packing density", + "answer": "For noncubic crystals, the index of refraction is lowest in the crystallographic direc�on having the lowest atomic packing density.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对非立方晶体折射率与原子堆积密度关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然题目涉及非立方晶体的折射率与原子堆积密度的关系，但只需理解基本概念并进行简单辨析即可作答。题目明确给出了两个对立选项（最高/最低原子堆积密度），考生只需记住\"折射率最低对应最低原子堆积密度\"这一基本原理即可正确选择，无需进行复杂的分析或计算。" + }, + { + "idx": 4161, + "question": "A completely amorphous and nonporous polymer will be(a) Transparent(b) Translucent(c) Opaque", + "answer": "A completely amorphous and nonporous polymer will be transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查对非晶态聚合物光学性质这一基本概念的记忆和理解，属于材料科学基础知识的直接应用，不需要复杂的分析或计算过程。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目考察的是对非晶态无孔聚合物透明性的基础概念记忆，无需复杂分析或深度理解，只需记住相关定义即可正确回答。" + }, + { + "idx": 4162, + "question": "A beam of light is shined on a thin (sub-millimeter thick) single crystal wafer of material. The light source is special since it can be tuned to provide any wavelength of visible light on demand. The specimen is illuminated such that the frequency of light is decreased over time while the transmitted intensity of the light is measured. If the sample becomes transparent when the frequency is less than [F] THz, what is the band gap of the material, in eV? Assume that an intrinsic excitation of electrons is responsible for the absorption.", + "answer": "the band gap of the material is 4.135 × 10^{-3} [f] ev.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（将频率转换为电子伏特）来确定材料的带隙，答案是一个具体的数值计算结果。 | 知识层次: 题目主要涉及基本公式应用和简单计算，即通过给定的频率计算材料的带隙能量。虽然需要理解带隙与光频率之间的关系，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据给定的频率计算材料的带隙，只需应用基本公式E = hν（其中h是普朗克常数，ν是频率）进行简单转换即可得到正确答案。解题步骤非常直接，无需复杂的推导或多步骤计算，符合等级1的标准。" + }, + { + "idx": 4163, + "question": "Select the word combination that best completes this statement.\nWhen a semiconductor is exposed to a light source, its intrinsic carrier concentration will increase if the [a] of the light is [b] than band gap of the semiconductor.\n[a]: intensity, energy, wavelength, frequency, voltage, current, resistance\n[b]: greater, less", + "answer": "([a] energy\n[b] greater", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项组合中选择最佳答案来完成句子，符合选择题的特征 | 知识层次: 题目考查半导体材料的基本概念，即光照射对半导体本征载流子浓度的影响，以及光能量与半导体带隙的关系。这属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解半导体光激发的基本原理，并正确匹配能量与带隙的关系。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，而非单纯的直接记忆。" + }, + { + "idx": 4164, + "question": "Match the luminescence characteristics with their descriptions.\nReemission of photons occurs in much less than one second after excitation.\n- Phosphorescence\n- Fluorescence\nReemission of photons occurs in more than one second after excitation.\n- Fluorescence\n- Phosphorescence", + "answer": "Fluorescence involves reemission of photons in much less than one second after excitation; while phosphorescence involves reemission of photons in more than one second after excitation.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的匹配项，即将发光特性与描述进行配对。答案部分也明确给出了选项之间的对应关系，符合选择题的特征。 | 知识层次: 题目考查荧光和磷光的基本定义和区别，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目属于概念理解和简单辨析的难度等级。虽然题目涉及两个不同的发光现象（荧光和磷光），但只需要考生理解并区分两者的基本定义特征（光子再发射的时间差异）。不需要复杂的分析或深度理解多个概念之间的关系，属于基础概念记忆和简单辨析的范畴。" + }, + { + "idx": 4165, + "question": "Only pure materials luminesce.(a) True(b) False", + "answer": "False. Luminescent materials contain impurities.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断结果 | 知识层次: 题目考查对发光材料基本概念的记忆和理解，即纯材料和掺杂材料在发光性质上的区别。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆纯材料和发光材料的基本定义即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 4166, + "question": "Cite the difference between atomic mass and atomic weight.", + "answer": "Atomic mass is the mass of an individual atom, whereas atomic weight is the average (weighted) of the atomic masses of an atom's naturally occurring isotopes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述原子质量与原子量的区别，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即原子质量和原子量的定义及其区别，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个基础概念（原子质量和原子量），但要求考生不仅记忆定义，还需要理解两者之间的区别（个体质量 vs 同位素加权平均值）。这超出了简单的定义复述，属于概念解释和描述的层次，但尚未达到需要分析复杂概念体系的难度。" + }, + { + "idx": 4167, + "question": "Chromium has four naturally-occurring isotopes: 4.34% of { }^{50} \\mathrm{Cr}, with an atomic weight of 49.9460 amu, 83.79% of { }^{52} \\mathrm{Cr}, with an atomic weight of 51.9405 amu, 9.50% of { }^{53} \\mathrm{Cr}, with an atomic weight of 52.9407 amu, and 2.37% of { }^{54} \\mathrm{Cr}, with an atomic weight of 53.9389 amu. On the basis of these data, confirm that the average atomic weight of \\mathrm{Cr} is 51.9963 amu.", + "answer": "the average atomic weight of \\mathrm{cr} is 51.9963 \\, amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的同位素丰度和原子质量数据，通过计算确认铬的平均原子质量。解答过程需要应用加权平均公式进行数值计算，最终验证给定的平均原子质量是否正确。答案的形式是数值计算结果，而非选择、判断或文字解释。 | 知识层次: 题目要求基于给定的同位素丰度和原子质量，通过简单的加权平均计算来确认铬的平均原子质量。这属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据给定的同位素丰度和原子质量计算铬的平均原子质量，只需要套用平均原子质量的计算公式（各同位素的质量乘以其丰度后相加）即可得出结果。解题步骤简单直接，无需复杂的推理或多步骤计算，因此属于最低难度等级。" + }, + { + "idx": 4168, + "question": "How many grams are there in one amu of a material?", + "answer": "1.66 x 10^-24 g/amu", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（1 amu转换为克），答案是一个具体的数值结果（1.66 x 10^-24 g/amu），属于典型的计算题特征。 | 知识层次: 题目仅涉及基本单位换算（amu到克）的直接计算，仅需套用已知的换算系数1.66 x 10^-24 g/amu，无需多步计算或概念关联，属于基础公式的直接应用。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用（1 amu = 1.66 x 10^-24 g），无需任何额外的计算步骤或概念组合。学生只需记住或识别这一基本换算关系即可选择正确答案，属于最基础的难度等级。" + }, + { + "idx": 4169, + "question": "Mole, in the context of this book, is taken in units of gram-mole. On this basis, how many atoms are there in a pound-mole of a substance?", + "answer": "2.73 x 10^26 atoms/lb-mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定一磅摩尔物质中的原子数量。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目考查基本单位换算和简单公式应用（阿伏伽德罗常数的直接应用），仅需一步计算即可得出结果，属于基础概念的直接应用。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式（阿伏伽德罗常数）进行简单的单位转换计算，属于单一公式直接计算的类型。解题步骤简单明了，无需复杂的推理或多步骤计算，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 4170, + "question": "(a) Cite two important quantum-mechanical concepts associated with the Bohr model of the atom.", + "answer": "Two important quantum-mechanical concepts associated with the Bohr model of the atom are (1) that electrons are particles moving in discrete orbitals, and (2) electron energy is quantized into shells.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两个重要的量子力学概念，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对Bohr原子模型中两个重要量子力学概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求回忆和列举两个与玻尔原子模型相关的基本量子力学概念，属于基础概念记忆的简单任务。不需要解释或分析，只需直接回忆知识点即可。" + }, + { + "idx": 4171, + "question": "(b) Cite two important additional refinements that resulted from the wave-mechanical atomic model.", + "answer": "Two important refinements resulting from the wave-mechanical atomic model are (1) that electron position is described in terms of a probability distribution, and (2) electron energy is quantized into both shells and subshells--each electron is characterized by four quantum numbers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个重要的改进，并需要简要解释每个改进的内容，这符合简答题的特征，即需要文字解释和论述。 | 知识层次: 题目考查对波动力学原子模型带来的两个重要改进的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举两个重要的改进点，但这两个点都是基于波动力学原子模型的基础概念记忆。正确选项直接给出了明确的定义和分类（概率分布和量子化能级），不需要复杂的分析或比较。然而，考生需要准确记忆并理解这两个关键概念，这比单纯记忆基本定义（等级1）要求稍高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 4172, + "question": "Relative to electrons and electron states, what does the n quantum number specify?", + "answer": "The n quantum number designates the electron shell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释n量子数的含义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对量子数n的基本定义和作用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对n量子数定义的基本记忆，属于最基础的概念性知识。正确选项直接给出了定义，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4173, + "question": "Relative to electrons and electron states, what does the l quantum number specify?", + "answer": "The l quantum number designates the electron subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对量子数l的含义进行文字解释，答案是一个简短的论述性回答，而非选择、判断或计算。 | 知识层次: 题目考查对量子数l的基本定义和分类的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆l量子数的基本定义和功能，属于最基础的概念记忆层次。题目直接给出正确选项，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4174, + "question": "Relative to electrons and electron states, what does the mj quantum number specify?", + "answer": "The mj quantum number designates the number of electron states in each electron subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对量子数mj的含义进行文字解释和论述，答案提供了详细的描述而非选择或判断。 | 知识层次: 题目考查对量子数mj的基本定义和作用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和理解mj量子数的基本定义，属于基础概念记忆层次。题目直接询问mj量子数的指定内容，正确选项也直接给出了定义，无需复杂的分析或推理步骤。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4175, + "question": "Relative to electrons and electron states, what does the ms quantum number specify?", + "answer": "The ms quantum number designates the spin moment on each electron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释ms量子数的含义，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对量子数ms的基本定义和概念的记忆，属于基础概念记忆层次，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目仅考察对ms量子数定义的基本记忆，属于最基础的概念性知识。正确选项直接给出了定义，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4176, + "question": "For the L shell (n=2), write the four quantum numbers for all of the electrons and note which correspond to the s and p subshells.", + "answer": "For the L state, n=2, and eight electron states are possible. Possible l values are 0 and 1, while possible ml values are 0 and ±1; and possible ms values are ±1/2. Therefore, for the s states, the quantum numbers are 200(1/2) and 200(-1/2). For the p states, the quantum numbers are 210(1/2), 210(-1/2), 211(1/2), 211(-1/2), 21(-1)(1/2), and 21(-1)(-1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细写出四个量子数并指出对应的s和p子壳层，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目主要考查对量子数基本概念的记忆和理解，包括主量子数、角量子数、磁量子数和自旋量子数的定义及其在特定电子壳层中的应用。虽然需要列举所有可能的组合，但不需要复杂的计算或分析，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生记忆并应用量子数的基本概念，包括主量子数(n)、角量子数(l)、磁量子数(ml)和自旋量子数(ms)。虽然涉及多个量子数的组合，但题目提供了明确的框架（n=2的L壳层），且正确选项已经列出了所有可能的组合。考生只需理解并记忆这些基本概念即可完成题目，不需要进行复杂的推导或分析。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 4177, + "question": "For the M shell (n=3), write the four quantum numbers for all of the electrons and note which correspond to the s, p, and d subshells.", + "answer": "For the M state, n=3, and 18 states are possible. Possible l values are 0, 1, and 2; possible ml values are 0, ±1, and ±2; and possible ms values are ±1/2. Therefore, for the s states, the quantum numbers are 300(1/2), 300(-1/2), for the p states they are 310(1/2), 310(-1/2), 311(1/2), 311(-1/2), 31(-1)(1/2), and 31(-1)(-1/2); for the d states they are 320(1/2), 320(-1/2), 321(1/2), 321(-1/2), 32(-1)(1/2), 32(-1)(-1/2), 322(1/2), 322(-1/2), 32(-2)(1/2), and 32(-2)(-1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出M壳层（n=3）的所有电子的四个量子数，并指出哪些对应于s、p和d子壳层。这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式详细列出了所有可能的量子数组合，符合简答题的特征。 | 知识层次: 题目要求根据给定的量子数规则（n, l, ml, ms）列举出M壳层（n=3）中所有可能的电子状态，并分类到s、p、d子壳层。这需要应用基本的量子数规则和电子排布知识，属于直接套用规则进行简单列举的应用题。虽然涉及多个量子数的组合，但思维过程较为直接，不需要复杂的推理或综合分析。 | 难度: 在选择题中属于中等难度，需要理解量子数的基本概念（n, l, ml, ms）以及它们在s、p、d轨道中的具体应用。虽然题目给出了所有可能的量子数组合，但要求考生能够正确识别和分类这些组合对应的轨道类型（s, p, d）。这需要考生对量子数的取值范围和轨道类型的对应关系有清晰的理解，并能够进行简单的逻辑推理和分类。" + }, + { + "idx": 4178, + "question": "Give the electron configuration for the ion Fe2+.", + "answer": "The electron configuration for an Fe2+ ion is 1s2 2s2 2p6 3s2 3p6 3d6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Fe2+离子的电子排布，需要文字描述电子排布的具体情况，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查对电子排布基本概念的记忆和理解，仅需根据原子序数和离子电荷数直接写出电子排布式，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆（电子排布），但需要学生掌握铁原子的电子排布（1s2 2s2 2p6 3s2 3p6 4s2 3d6）并理解Fe2+离子是通过失去两个4s电子形成的。这涉及对电子填充顺序和离子形成过程的理解，而不仅仅是简单的定义记忆。因此，它比纯粹的定义记忆题（等级1）稍复杂，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 4179, + "question": "Give the electron configuration for the ion Al3+.", + "answer": "The electron configuration for an Al3+ ion is 1s2 2s2 2p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出电子排布式，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对电子排布这一基础概念的记忆和理解，仅需直接回忆铝离子(Al3+)的电子排布情况，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅要求记忆基础概念（电子排布式），无需解释或复杂推理。属于直接回忆型问题，符合等级1的基本定义简答标准。" + }, + { + "idx": 4180, + "question": "Give the electron configuration for the ion Cu+.", + "answer": "The electron configuration for a Cu+ ion is 1s2 2s2 2p6 3s2 3p6 3d10.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Cu+离子的电子排布，需要文字解释和论述，而不是从选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查对电子排布基本概念的记忆和理解，仅需直接回忆铜离子(Cu+)的电子构型，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求记忆铜离子(Cu+)的电子排布，但需要掌握过渡金属离子的电子排布特点，特别是铜的例外情况（4s电子先填充但3d轨道未填满）。这超出了简单的定义记忆，需要对电子排布规则有一定理解和应用能力。" + }, + { + "idx": 4181, + "question": "Give the electron configuration for the ion Ba2+.", + "answer": "The electron configuration for a Ba2+ ion is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6 4d10 5s2 5p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出Ba2+离子的电子排布，答案是一个详细的电子排布序列，需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对电子排布的基本概念的记忆和理解，不需要复杂的计算或分析，只需记住Ba2+离子的电子排布即可。 | 难度: 在选择题型中，该题目仅要求记忆基础概念（电子排布式），无需解释或分析。正确选项直接给出了完整的电子排布式，属于最基础的定义简答类型。" + }, + { + "idx": 4182, + "question": "Give the electron configuration for the ion Br-.", + "answer": "The electron configuration for a Br- ion is 1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Br-离子的电子排布，答案是一个详细的电子排布序列，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对电子排布这一基础概念的记忆和理解，不需要复杂的计算或分析，仅需直接应用原子序数和电子排布规则即可得出答案。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆（电子排布），但需要考生掌握Br原子的电子排布（1s2 2s2 2p6 3s2 3p6 3d10 4s2 4p5）并理解Br-离子是通过获得一个电子形成的（4p轨道填满）。这比单纯记忆元素符号或简单定义（等级1）要复杂，但比需要分析多个概念或进行复杂推导（等级3）要简单。" + }, + { + "idx": 4183, + "question": "Give the electron configuration for the ion O2-.", + "answer": "The electron configuration for an O2- ion is 1s2 2s2 2p6.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出电子排布式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对电子排布基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和复述氧离子O2-的电子排布，属于基础概念记忆的范畴。题目不涉及复杂的概念解释或比较分析，解题步骤简单直接，只需回忆并选择正确的电子排布即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4184, + "question": "The Na+ ion has an electron structure that is identical to which inert gas?", + "answer": "The Na+ ion has an electron configuration the same as neon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释说明Na+离子的电子结构与哪种惰性气体相同，答案需要论述和解释，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查对离子电子构型与惰性气体电子构型相同这一基本概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆基础概念，即Na+离子的电子构型与哪种惰性气体相同。无需复杂推理或概念间的比较分析，属于最基础的定义简答级别。" + }, + { + "idx": 4185, + "question": "The Cl- ion has an electron structure that is identical to which inert gas?", + "answer": "The Cl- ion has an electron configuration the same as argon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释说明Cl-离子的电子结构与哪种惰性气体相同，答案需要论述和解释，而不是选择、判断或计算。 | 知识层次: 题目考查对离子电子构型与惰性气体电子构型之间关系的基本概念记忆和理解，属于基础概念记忆范畴，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅需要记忆基础概念（Cl-离子的电子结构与哪种惰性气体相同），属于基本定义简答。解题步骤简单，只需直接回忆知识点，无需复杂分析或推理。" + }, + { + "idx": 4186, + "question": "With regard to electron configuration, what do all the elements in Group VIIA of the periodic table have in common?", + "answer": "Each of the elements in Group VIIA has five p electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释元素在周期表中的共同点，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对元素周期表中VIIA族元素电子排布的共同特征的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需回忆元素周期表中VIIA族元素的电子排布共性，即五个p电子。题目不涉及复杂概念或分析步骤，属于最基础的定义简答类型。" + }, + { + "idx": 4187, + "question": "To what group in the periodic table would an element with atomic number 114 belong?", + "answer": "From the periodic table the element having atomic number 114 would belong to group IVA. Ds, having an atomic number of 110 lies below Pt in the periodic table and in the rightmost column of group VIII. Moving four columns to the right puts element 114 under \\mathrm{Pb} and in group IVA.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素114在周期表中的归属，答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对元素周期表中元素分类的基本概念的记忆和理解，只需根据原子数定位元素在周期表中的位置即可回答，无需复杂计算或分析。 | 难度: 在选择题型中，该题目需要考生掌握元素周期表的分组原则和原子序数与元素位置的关系，属于概念解释和描述的难度级别。虽然需要一定的记忆和理解，但不需要复杂的分析或推理步骤。" + }, + { + "idx": 4188, + "question": "Determine whether the electron configuration (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{7} 4 s^{2}) is an inert gas, a halogen, an alkali metal, an alkaline earth metal, or a transition metal. Justify your choice.", + "answer": "The (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{7} 4 s^{2}) electron configuration is that of a transition metal because of an incomplete (d) subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据电子排布判断元素类别，并需要文字解释和论述来证明选择。答案提供了详细的理由说明，符合简答题的特征。 | 知识层次: 题目考查对电子构型与元素分类之间关系的基本概念记忆和理解，只需根据给定的电子构型判断元素类别，并简单解释原因，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目需要考生理解电子排布的基本概念，并能根据给定的电子排布判断元素的类别。虽然涉及过渡金属的定义，但解题步骤相对直接，只需识别d亚层未填满这一关键特征即可。相较于等级1的简单定义记忆，该题目要求稍高的概念理解和应用能力，但不需要复杂的分析或比较，因此属于中等难度。" + }, + { + "idx": 4194, + "question": "What electron subshell is being filled for the rare earth series of elements on the periodic table?", + "answer": "The 4 f subshell is being filled for the rare earth series of elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释哪个电子亚层正在被填充，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对元素周期表中稀土元素电子填充亚层的基本概念记忆，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求记忆并识别稀土元素填充的电子亚层（4f），无需解释或分析复杂概念。这是对基础概念的直接回忆，符合选择题型中最简单的难度等级标准。" + }, + { + "idx": 4195, + "question": "What electron subshell is being filled for the actinide series?", + "answer": "The 5 f subshell is being filled for the actinide series of elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释回答具体的电子亚层，答案是一个简短的文字描述，不需要选择、判断或计算。 | 知识层次: 题目考查对元素周期表中锕系元素电子填充亚层的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即对actinide系列元素填充的电子亚层进行直接回忆。题目仅要求识别正确的电子亚层（5f），无需解释或分析多个概念，属于最基础的定义简答级别。" + }, + { + "idx": 4196, + "question": "Calculate the force of attraction between a K^{+}and an \\mathrm{O}^{2-} ion the centers of which are separated by a distance of 1.5nm.", + "answer": "the force of attraction between the k^{+} and \\mathrm{o}^{2-} ions is 2.05 × 10^{-10} N.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算两个离子之间的吸引力，需要使用库仑定律等公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目要求使用库仑定律进行简单的数值计算，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算离子间的吸引力，只需要直接应用库仑定律公式F = k*q1*q2/r^2，代入给定的电荷值和距离即可得到结果。不需要额外的概念理解或复杂的计算步骤，属于最基础的应用题。" + }, + { + "idx": 4197, + "question": "Briefly cite the main differences between ionic, covalent, and metallic bonding.", + "answer": "The main differences between the various forms of primary bonding are: Ionic--there is electrostatic attraction between oppositely charged ions. Covalent--there is electron sharing between two adjacent atoms such that each atom assumes a stable electron configuration. Metallic--the positively charged ion cores are shielded from one another, and also 'glued' together by the sea of valence electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要列举离子键、共价键和金属键之间的主要区别，答案以文字解释和论述的形式呈现，没有选项或计算要求。 | 知识层次: 题目考查对离子键、共价键和金属键这三种基本化学键类型的定义和主要特点的记忆和理解，属于材料科学中最基础的概念性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求简要列举离子键、共价键和金属键的主要区别，但正确选项提供了较为详细的概念解释和描述，涉及每种键的基本原理和特征。这需要考生不仅记住定义，还要理解每种键的机制和特点，并进行简单的比较分析。因此，该题目在选择题型内属于等级2。" + }, + { + "idx": 4198, + "question": "State the Pauli exclusion principle.", + "answer": "The Pauli exclusion principle states that each electron state can hold no more than two electrons, which must have opposite spins.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述一个科学原理（Pauli exclusion principle），答案是一个完整的句子解释，符合简答题的特征。 | 知识层次: 题目考查对泡利不相容原理这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆并复述泡利不相容原理的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的直接表述，无需解释或复杂分析，因此难度等级为1。" + }, + { + "idx": 4199, + "question": "What type(s) of bonding would be expected for brass (a copper-zinc alloy)?", + "answer": "For brass, the bonding is metallic since it is a metal alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释brass的键合类型，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对金属合金键合类型的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即金属合金的键合类型。不需要解释或分析，只需识别\"brass\"是金属合金并选择\"metallic bonding\"这一基本定义。属于最基础的定义简答级别。" + }, + { + "idx": 4200, + "question": "What type(s) of bonding would be expected for rubber?", + "answer": "For rubber, the bonding is covalent with some van der Waals. (Rubber is composed primarily of carbon and hydrogen atoms.)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释橡胶的键合类型，答案提供了详细的文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对橡胶材料中化学键类型的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（橡胶的键合类型），但需要学生同时掌握共价键和范德华力两种键合方式的概念，并能将其正确组合应用于特定材料。这比单纯记忆单一键合类型（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 4201, + "question": "What type(s) of bonding would be expected for barium sulfide (BaS)?", + "answer": "For BaS, the bonding is predominantly ionic (but with some covalent character) on the basis of the relative positions of Ba and S in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释BaS的键合类型，需要文字论述和解释，而不是选择、判断或计算。答案也提供了详细的文字说明。 | 知识层次: 题目要求分析BaS的键合类型，需要理解元素在周期表中的位置对键合性质的影响，并综合判断离子键和共价键的相对贡献。这涉及多个概念的关联和综合分析，超出了单纯记忆的范畴。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生基于元素在周期表中的相对位置判断BaS的键合类型，涉及离子键和共价键的概念理解以及元素电负性的综合分析。虽然不需要复杂的计算，但需要对化学键的性质有较深的理解和关联能力。" + }, + { + "idx": 4202, + "question": "What type(s) of bonding would be expected for solid xenon?", + "answer": "For solid xenon, the bonding is van der Waals since xenon is an inert gas.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释固体氙的键合类型，答案提供了文字解释和论述，没有选项或计算要求。 | 知识层次: 题目考查对惰性气体固态时键合类型的基础概念记忆，仅需知道惰性气体通过范德华力形成固态这一基本原理即可作答，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即惰性气体固态时的键合类型。题目不涉及概念解释或复杂分析，只需识别出氙是惰性气体并回忆其固态键合方式为范德华力。因此属于最基本难度等级。" + }, + { + "idx": 4203, + "question": "What type(s) of bonding would be expected for bronze?", + "answer": "For bronze, the bonding is metallic since it is a metal alloy (composed of copper and tin).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释青铜中预期的键合类型，答案需要文字论述和解释，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对金属合金（青铜）基本键合类型的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即青铜（bronze）作为金属合金的键合类型。不需要解释或分析，只需识别并选择正确的定义性描述。这属于最基础的知识层次要求，解题步骤简单直接。" + }, + { + "idx": 4204, + "question": "What type(s) of bonding would be expected for nylon?", + "answer": "For nylon, the bonding is covalent with perhaps some van der Waals. (Nylon is composed primarily of carbon and hydrogen.)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释尼龙的键合类型，需要文字解释和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目考查对尼龙材料中化学键类型的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目要求考生理解并记忆尼龙的主要键合类型（共价键和可能的范德华力），属于基础概念记忆的范畴。虽然需要掌握两种键合类型的知识，但不需要复杂的分析或比较，因此属于中等难度。" + }, + { + "idx": 4205, + "question": "What type(s) of bonding would be expected for aluminum phosphide (AlP)?", + "answer": "For AlP the bonding is predominantly covalent (but with some ionic character) on the basis of the relative positions of Al and P in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铝磷化合物(AlP)的键合类型，答案需要文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目要求根据元素周期表中铝和磷的相对位置判断AlP的键合类型，这需要理解元素电负性差异对键合性质的影响，并综合分析共价键和离子键的特征。虽然不涉及复杂计算，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生基于元素在周期表中的相对位置判断化学键类型，涉及对共价键和离子键概念的综合理解，以及元素电负性差异的分析。虽然不需要复杂的计算，但需要将多个知识点关联起来进行判断，属于中等应用层次的知识要求。" + }, + { + "idx": 4206, + "question": "What is the difference between atomic structure and crystal structure?", + "answer": "Atomic structure relates to the number of protons and neutrons in the nucleus of an atom, as well as the number and probability distributions of the constituent electrons. On the other hand, crystal structure pertains to the arrangement of atoms in the crystalline solid material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释原子结构和晶体结构之间的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查原子结构和晶体结构这两个基本概念的定义和区别，属于基础概念的记忆和理解层次，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个基础概念（原子结构和晶体结构），但正确选项要求考生不仅能够记忆这两个概念的定义，还需要理解它们之间的区别。这需要考生具备一定的概念解释和描述能力，而不仅仅是简单的定义记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4207, + "question": "If the atomic radius of aluminum is 0.143nm, calculate the volume of its unit cell in cubic meters.", + "answer": "the volume of the unit cell is 6.62 × 10^{-29} m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（基于给定的原子半径）来求解单位晶胞的体积，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要知道单位晶胞体积的计算公式（如立方晶系的边长为4r/√2）并进行数值代入即可完成，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（单位晶胞体积计算公式）进行计算，无需多个步骤或复杂推理。题目提供了所有必要的信息（原子半径），且计算过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 4208, + "question": "Show that the atomic packing factor for BCC is 0.68 .", + "answer": "the atomic packing factor for bcc is 0.68.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算证明BCC结构的原子堆积因子为0.68，需要应用几何关系和数学计算来求解 | 知识层次: 题目要求计算BCC结构的原子堆积因子，涉及基本公式应用和简单计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解BCC（体心立方）结构的原子堆积因子概念，但计算过程仅涉及基本几何关系和简单算术运算（如球体积与晶胞体积的比例计算），无需复杂推导或多步骤组合。选择题型中只需识别正确计算结果，因此属于等级2。" + }, + { + "idx": 4209, + "question": "Iron has a BCC crystal structure, an atomic radius of 0.124nm, and an atomic weight of 55.85g / mol. Compute and compare its theoretical density with the experimental value found inside the front cover.", + "answer": "the theoretical density of iron is 7.90g / {cm}^{3}. the experimental value given inside the front cover is 7.87g / {cm}^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铁的理論密度，并与实验值进行比较。答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目主要考查对BCC晶体结构密度计算公式的直接应用，涉及原子半径、原子质量和单位换算等基本参数的使用，计算过程较为直接，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用BCC晶体结构的密度计算公式，但计算步骤相对直接，仅需套用原子半径、原子量和晶格常数之间的关系公式即可得出理论密度，并与给定实验值进行简单比较。不需要复杂的推导或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 4210, + "question": "Calculate the radius of an iridium atom, given that Ir has an FCC crystal structure, a density of 22.4g / {cm}^{3}, and an atomic weight of 192.2g / mol.", + "answer": "the radius of an iridium atom is 0.136nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铱原子的半径，答案是一个具体的数值结果（0.136nm），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括利用FCC晶体结构的几何关系、密度和原子重量的关系，以及单位转换等综合分析步骤。虽然不涉及复杂的推理分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、密度与原子半径的关系，并进行多步计算。虽然题目给出了正确选项，但解题过程涉及单位换算、晶胞体积计算、原子半径推导等综合步骤，对概念掌握和计算能力要求较高。" + }, + { + "idx": 4211, + "question": "Calculate the radius of a vanadium atom, given thatV has a BCC crystal structure, a density of 5.96 \\mathrm{g} / {cm}^{3}, and an atomic weight of 50.9g / mol.", + "answer": "the radius of a vanadium atom is 0.132 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钒原子的半径，答案是一个具体的数值结果（0.132 nm），这符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括BCC晶体结构的理解、密度的计算、原子半径的推导等，涉及多个知识点的综合应用，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、密度与原子半径的关系，并进行多步计算。虽然题目提供了所有必要信息，但解题过程涉及单位转换、晶胞体积计算和原子半径推导，属于综合性计算问题。" + }, + { + "idx": 4212, + "question": "For alloy A with atomic weight 77.4 g/mol, density 8.22 g/cm³, and atomic radius 0.125 mm, determine whether its crystal structure is FCC, BCC, or simple cubic and then justify your determination.", + "answer": "for alloy a, its crystal structure is simple cubic.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的原子量、密度和原子半径等参数进行计算，以确定晶体结构类型，并需要应用相关公式进行推导和验证。答案虽然简短，但需要通过计算过程得出。 | 知识层次: 题目需要应用密度公式和晶体结构几何关系进行多步计算，涉及原子半径、原子量和密度的综合运用，需要理解不同晶体结构的堆积方式并进行比较分析，属于中等难度的应用题型。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目要求考生掌握晶体结构的基本概念，能够进行密度、原子半径和原子量的计算，并综合分析这些数据来确定晶体结构类型。虽然题目给出了正确选项，但解题过程涉及多步骤计算和概念关联，需要考生具备一定的综合分析能力。" + }, + { + "idx": 4213, + "question": "For alloy B with atomic weight 107.6 g/mol, density 13.42 g/cm³, and atomic radius 0.133 mm, determine whether its crystal structure is FCC, BCC, or simple cubic and then justify your determination.", + "answer": "for alloy b, its crystal structure is fcc.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的原子重量、密度和原子半径等参数进行计算，以确定合金的晶体结构类型（FCC、BCC或简单立方）。解答过程需要应用材料科学中的相关公式和数值计算，最终得出晶体结构的结论。答案虽然简短，但背后涉及复杂的计算过程。 | 知识层次: 题目需要应用晶体结构计算的相关公式，通过给定的原子量、密度和原子半径来确定晶体结构类型。这涉及到多步计算和概念关联，如计算原子堆积因子（APF）并与不同晶体结构的理论值进行比较。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力来得出结论。 | 难度: 在选择题中属于中等偏上难度，需要综合运用密度公式、晶体结构几何关系、单位换算等多步骤计算，并正确关联FCC/BCC/SC的原子堆积特征才能得出结论。虽然选择题型降低了开放论证的难度，但仍需完成复杂的概念关联和数值计算过程。" + }, + { + "idx": 4214, + "question": "For alloy C with atomic weight 127.3 g/mol, density 9.23 g/cm³, and atomic radius 0.142 mm, determine whether its crystal structure is FCC, BCC, or simple cubic and then justify your determination.", + "answer": "for alloy c, its crystal structure is simple cubic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定合金的晶体结构并给出合理的解释，需要文字解释和论述，而不仅仅是选择或计算。 | 知识层次: 题目需要根据给定的原子重量、密度和原子半径，通过多步计算和综合分析来确定晶体结构类型（FCC、BCC或简单立方）。这涉及到对晶体结构基本概念的理解、相关公式的应用（如密度与晶格参数的关系）以及逻辑推理能力。虽然不涉及复杂的机理分析或创新设计，但需要一定的计算步骤和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用密度公式、晶体结构几何关系、单位换算等多步骤计算，并关联原子半径与晶格参数的关系进行综合分析判断。题目要求考生不仅要掌握各晶体结构的堆积特征，还需具备将理论公式与给定数据结合推导的能力，属于典型的中等应用层次综合分析题。" + }, + { + "idx": 4215, + "question": "The unit cell for tin has tetragonal symmetry, with a and b lattice parameters of 0.583 and 0.318nm, respectively. If its density, atomic weight, and atomic radius are 7.30g / {cm}^{3}, 118.69g / mol, and 0.151nm, respectively, compute the atomic packing factor.", + "answer": "the atomic packing factor (apf) for tin is 0.534.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如计算原子堆积因子）来得出具体数值结果（0.534），属于典型的计算题特征。 | 知识层次: 题目需要多步计算和概念关联，包括晶胞参数、密度、原子量、原子半径等信息的综合运用，以及原子堆积因子的计算公式应用。虽然不涉及复杂的推理分析或机理解释，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算，包括晶胞体积、原子体积和原子堆积因子的计算，同时需要综合运用密度、原子量和晶格参数等概念。虽然题目提供了所有必要的数据，但解题过程需要一定的综合分析能力和对材料科学基础知识的掌握。" + }, + { + "idx": 4216, + "question": "List the point coordinates of the titanium, barium, and oxygen ions for a unit cell of the perovskite crystal structure.", + "answer": " the barium ions are situated at all corner positions. The point coordinates for these ions are as follows: 000,100,110,010,001,101,111, and 011 .\nThe oxygen ions are located at all face-centered positions; therefore, their coordinates are \\frac{1}{2} \\frac{1}{2} 0, \\frac{1}{2} \\frac{1}{2} 1, \\frac{1}{2} \\frac{1}{2}, \\frac{0}{2} \\frac{1}{2}, \\frac{1}{2} 0 \\frac{1}{2}, and \\frac{1}{2} 1 \\frac{1}{2}.\nAnd, finally, the titanium ion resides at the center of the cubic unit cell, with coordinates \\frac{1}{2} \\frac{1}{2} \\frac{1}{2}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出钙钛矿晶体结构单元中钛、钡和氧离子的点坐标，答案以文字描述和坐标形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目主要考查对钙钛矿晶体结构中各离子位置坐标的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆钙钛矿晶体结构中钛、钡、氧离子的具体坐标位置，但这些都是基础概念的记忆性知识，不需要复杂的推理或分析。题目提供了明确的离子位置描述和坐标，只需正确识别和匹配即可。相比等级1的基本定义简答，此题需要记忆多个离子的具体坐标，但不需要深入理解或应用这些知识，因此属于等级2。" + }, + { + "idx": 4217, + "question": "List the point coordinates of all carbon atoms that occupy the corner positions of the diamond cubic unit cell.", + "answer": "The coordinates of these atoms are as follows: 000, 100, 110, 010, 001, 101, 111, and 011.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出金刚石立方晶胞中占据角位碳原子的点坐标，答案以列表形式给出具体坐标，属于需要具体回答的简答题类型。 | 知识层次: 题目考查对金刚石立方晶胞角位碳原子坐标的记忆，属于晶体结构的基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆并列出金刚石立方晶胞角位碳原子的坐标，属于基础概念记忆的范畴。题目不涉及复杂的概念解释或分析，仅需直接回忆和复述知识点，因此难度等级为1。" + }, + { + "idx": 4218, + "question": "List the point coordinates of all carbon atoms that reside on the face-centered positions of the diamond cubic unit cell.", + "answer": "The coordinates of these atoms are as follows: 1/2 1/2 0, 1/2 1/2 1, 1/2 0 1/2, 0 1/2 1/2, and 1/2 1/2 1/2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出金刚石立方晶胞中面心位置碳原子的坐标点，答案以文字形式给出具体的坐标值，不需要计算或选择，属于简答题类型。 | 知识层次: 题目要求列出金刚石立方晶胞中面心位置碳原子的坐标，这需要理解金刚石立方晶胞的结构特点，并能够应用空间群对称性知识来确定原子的位置。虽然不涉及复杂的计算或推理，但需要对晶体结构有较深入的理解和一定的空间想象能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金刚石立方晶胞的面心位置概念，并能正确列出所有碳原子的坐标。虽然题目给出了正确选项，但学生仍需掌握晶体结构的基本知识，并能将面心位置的概念应用到金刚石立方结构中。这需要一定的综合分析能力和对晶体学概念的理解。" + }, + { + "idx": 4219, + "question": "List the point coordinates of all carbon atoms that are positioned within the interior of the diamond cubic unit cell.", + "answer": "The coordinates of these atoms are as follows: 3/4 1/4 1/4, 1/4 3/4 3/4, 1/4 1/4 3/4, and 3/4 3/4 1/4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出金刚石立方晶胞内部所有碳原子的点坐标，答案以文字形式给出具体坐标值，不需要计算或选择，属于简答题类型。 | 知识层次: 题目主要考查对金刚石立方晶胞内部碳原子坐标的记忆，属于晶体结构的基础概念记忆性知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目要求记忆并识别金刚石立方晶胞内部碳原子的具体坐标位置。虽然涉及基础概念记忆，但需要准确回忆多个坐标值，属于概念解释和描述的难度等级。相较于仅记忆单一定义的等级1题目，此题的复杂度稍高，但仍属于中等难度范围。" + }, + { + "idx": 4220, + "question": "Using the Molecule Definition Utility found in both \"Metallic Crystal Structures and Crystallography\" and \"Ceramic Crystal Structures\" modules of VMSE, located on the book's web site [www.wiley.com/college/Callister (Student Companion Site)], generate a three-dimensional unit cell for the intermetallic compound \\mathrm{AuCu}_{3} given the following: (1) the unit cell is cubic with an edge length of 0.374nm, (2) gold atoms are situated at all cube corners, and (3) copper atoms are positioned at the centers of all unit cell faces.", + "answer": "First of all, open the \"Molecular Definition Utility\"; it may be found in either of \"Metallic Crystal Structures and Crystallography\" or \"Ceramic Crystal Structures\" modules.\nIn the \"Step 1\" window, it is necessary to define the atom types, colors for the spheres (atoms), and specify atom sizes. Let us enter \"Au\" as the name for the gold atoms (since \"Au\" the symbol for gold), and \"Cu\" as the name for the copper atoms. Next it is necessary to choose a color for each atom type from the selections that appear in the pull-down menu-for example, \"Yellow\" for Au and \"Red\" for Cu. In the \"Atom Size\" window, it is necessary to enter an atom/ion size. In the instructions for this step, it is suggested that the atom/ion diameter in nanometers be used. From the table found inside the front cover of the textbook, the atomic radii for gold and copper are 0.144nm and 0.128nm, respectively, and, therefore, their ionic diameters are twice these values (i.e., 0.288nm and 0.256nm ); therefore, we enter the values \" 0.288 \" and \" 0.256 \" for the two atom types. Now click on the \"Register\" button, followed by clicking on the \"Go to Step 2\" button.\nIn the \"Step 2\" window we specify positions for all of the atoms within the unit cell; their point coordinates are specified in the problem statement. Let's begin with gold. Click on the yellow sphere that is located to the right of the \"Molecule Definition Utility\" box. Again, Au atoms are situated at all eight corners of the cubic unit cell. One Au will be positioned at the origin of the coordinate system-i.e., its point coordinates are 000, and, therefore, we enter a \"0\" (zero) in each of the \" \\mathrm{x} \", \" \\mathrm{y} \", and \" \\mathrm{z} \" atom position boxes. Next we click on the \"Register Atom Position\" button. Now we enter the coordinates of another gold atom; let us arbitrarily select the one that resides at the corner of the unit cell that is one unit-cell length along the x-axis (i.e., at the 100 point coordinate). Inasmuch as it is located a distance of a units along the x-axis the value of \" 0.374 \" is entered in the \" \\mathrm{x} \" atom position box (since this is the value of a given in the problem statement); zeros are entered in each of the \" \\mathrm{y} \" and \" z \" position boxes. We repeat this procedure for the remaining six Au atoms.\nAfter this step has been completed, it is necessary to specify positions for the copper atoms, which are located at all six face-centered sites. To begin, we click on the red sphere that is located next to the \"Molecule Definition Utility\" box. The point coordinates for some of the Cu atoms are fractional ones; in these instances, the a unit cell length (i.e., 0.374) is multiplied by the fraction. For example, one Cu atom is located 1 \\frac{1}{2} \\frac{1}{2} coordinate. Therefore, the \\mathrm{x}, \\mathrm{y}, and \\mathrm{z} atoms positions are (1)(0.374) =0.374, \\frac{1}{2}(0.374)=0.187, and \\frac{1}{2}(0.374)=0.187, respectively.\nFor the gold atoms, the \\mathrm{x}, \\mathrm{y}, and \\mathrm{z}^{\\prime} atom position entries for all 8 sets of point coordinates are as follows: \\[\n\\begin{array}{l}\n0,0, \\text { and } 0 \\\\\n0.374,0, \\text { and } 0 \\\\\n0,0.374, \\text { and } 0 \\\\\n0,0, \\text { and } 0.374 \\\\\n0,0.374,0.374 \\\\\n0.374,0.374 \\\\\n0.374,0 .374,0 \\\\\n0.374,0.374,0.374\n\\end{array}\n\\]\nNow, for the copper atoms, the \\mathrm{x}, \\mathrm{y}, and \\mathrm{z} atom position entries for all 6 sets of point coordinates are as follows:\n\\[\n\\begin{array}{l}\n0.187,0.187,0 \\\\\n0.187,0,0.187 \\\\\n0,0.187,0.187 \\\\\n0.374,0.187,0.187 \\\\\n0.187,0.374,0.187 \\\\\n0.187,0.187,0.374\n\\end{array}\n\\]\nIn Step 3, we may specify which atoms are to be represented as being bonded to one another, and which type of bond(s) to use (single solid, single dashed, double, and triple are possibilities), or we may elect to not represent any bonds at all (in which case we are finished). If it is decided to show bonds, probably the best thing to do is to represent unit cell edges as bonds. This image may be rotated by using mouse click-and-drag\nYour image should appear as the following screen shot. Here the gold atoms appear lighter than the copper atoms. [Note: Unfortunately, with this version of the Molecular Definition Utility, it is not possible to save either the data or the image that you have generated. You may use screen capture (or screen shot) software to record and store your image.]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用特定软件工具生成三维晶胞结构，并详细描述操作步骤和参数设置，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求使用特定软件工具生成三维晶胞结构，涉及原子位置的计算和坐标输入，需要理解晶格结构和原子排列的基本原理，并进行多步操作和综合分析。虽然不涉及复杂的理论推导，但需要一定的应用能力和操作技巧。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 4221, + "question": "Convert the (010) plane into the four-index Miller-Bravais scheme for hexagonal unit cells.", + "answer": "the (010) plane in the four-index miller-bravais scheme is (01 -1 0).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求将(010)平面转换为六方晶系的四指数Miller-Bravais表示法，需要文字解释和论述转换过程，答案是一个具体的平面指数表示，而不是选择、判断或计算。 | 知识层次: 题目要求将立方晶系的(010)平面转换为六方晶系的四指数Miller-Bravais表示法，这需要理解两种晶系指数表示法的基本规则并进行直接转换，属于基本公式应用和简单计算的范畴。虽然涉及不同晶系的概念，但转换过程是直接的，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求将(010)平面转换为六方晶系的四指数Miller-Bravais表示法，这是一个直接套用基本公式的过程。解题步骤简单，只需按照转换规则进行计算即可得出正确答案(01 -1 0)。由于题目提供了明确的转换目标，且不需要复杂的分析或比较，因此在选择题型内属于较低难度等级。" + }, + { + "idx": 4222, + "question": "Convert the (101) plane into the four-index Miller-Bravais scheme for hexagonal unit cells.", + "answer": "the (101) plane in the four-index miller-bravais scheme is (10 -1 1).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求将(101)平面转换为六方晶系的四指数Miller-Bravais表示法，需要文字解释和论述转换过程，答案是一个具体的平面指数表示，属于简答题类型。 | 知识层次: 题目需要将立方晶系的Miller指数转换为六方晶系的Miller-Bravais指数，这涉及多步计算和概念关联，需要理解两种晶系指数的转换规则并进行适当的数学运算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。该题目要求将(101)平面转换为六方晶系的四指数Miller-Bravais方案，涉及对晶面指数的理解和计算。虽然题目给出了正确选项，但学生需要掌握六方晶系和三指数到四指数的转换规则，并进行适当的计算。这需要一定的概念关联和综合分析能力，但相比更复杂的题目，步骤相对明确，因此在选择题型中属于中等难度。" + }, + { + "idx": 4223, + "question": "(a) Derive the planar density expression for the HCP (0001) plane in terms of the atomic radius R.", + "answer": "the planar density expression for the hcp (0001) plane in terms of the atomic radius r is: pd_{0001} = 1 / (2 r^{2} sqrt(3))", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导HCP (0001)面的平面密度表达式，涉及原子半径R的计算和公式应用，答案是一个具体的数学表达式，符合计算题的特征。 | 知识层次: 题目要求推导HCP (0001)面的面密度表达式，涉及晶体结构几何关系的理解和多步计算，需要将原子半径与晶面几何参数关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解HCP晶体结构、(0001)晶面特征、原子半径与晶格参数关系等多个概念，并正确应用平面密度计算公式。虽然题目给出了正确选项，但需要考生具备综合分析能力才能判断选项的正确性，涉及多步推导和单位晶胞内原子数的计算。" + }, + { + "idx": 4224, + "question": "(b) Compute the planar density value for this same plane for magnesium.", + "answer": "the planar density value for the (0001) plane for magnesium is: pd_{0001}(mg) = 1.128 × 10^{19} m^{-2}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算镁的(0001)面的平面密度值，需要应用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求计算镁的(0001)面的平面密度值，这需要应用基本的平面密度计算公式，并进行简单的数值计算。虽然需要理解平面密度的概念，但整体过程是直接套用公式和进行基本计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行单一计算，无需多个公式组合或复杂分析。学生只需掌握平面密度的基本概念和公式即可直接得出答案，属于最基础的难度等级。" + }, + { + "idx": 4225, + "question": "Explain why the properties of polycrystalline materials are most often isotropic.", + "answer": "Although each individual grain in a polycrystalline material may be anisotropic, if the grains have random orientations, then the solid aggregate of the many anisotropic grains will behave isotropically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶材料性质通常为各向同性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多晶材料各向同性的原因，需要理解晶粒的各向异性与多晶材料宏观各向同性之间的关系，涉及多个概念的关联和综合分析，思维深度较高。 | 难度: 在选择题型内属于最高难度等级，因为该题目要求考生：" + }, + { + "idx": 4226, + "question": "The metal iridium has an FCC crystal structure. If the angle of diffraction for the (220) set of planes occurs at 69.22 degrees (first-order reflection) when monochromatic x-radiation having a wavelength of 0.1542 nm is used, compute the interplanar spacing for this set of planes.", + "answer": "the interplanar spacing for the (220) set of planes for iridium is 0.1357 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（布拉格定律）来求解晶面间距，答案是一个具体的数值结果（0.1357 nm），符合计算题的特征。 | 知识层次: 题目主要涉及布拉格定律的直接应用，通过给定的衍射角和波长计算晶面间距。虽然需要理解布拉格定律和晶面间距的概念，但计算过程相对直接，属于基本公式应用和简单计算范畴。 | 难度: 在选择题型中，该题目仅需要直接应用布拉格公式（nλ = 2d sinθ）进行一步计算即可得出答案。题目已经给出了所有必要的参数（衍射角、波长、反射级数），无需额外的推导或组合公式。因此，在选择题型内属于最简单的难度等级1。" + }, + { + "idx": 4227, + "question": "The metal iridium has an FCC crystal structure. Given the interplanar spacing for the (220) set of planes is 0.1357 nm, compute the atomic radius for an iridium atom.", + "answer": "the atomic radius for an iridium atom is 0.1357 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶面间距计算铱原子的原子半径，涉及数值计算和公式应用（如晶面间距公式与面心立方晶体结构的关系）。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用晶体学中的FCC结构知识，通过给定的晶面间距计算原子半径，涉及多步计算和概念关联（如晶面间距公式与FCC结构的关系），但不需要复杂的综合分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、晶面间距计算和原子半径之间的关系。解题涉及多个步骤：首先根据(220)晶面间距计算晶格常数，然后根据FCC结构特点推导原子半径。虽然题目给出了关键中间值（晶面间距），但仍需要正确应用晶体学公式和几何关系进行综合计算。相比单纯的概念记忆题，这需要更深入的知识应用能力，但比需要处理多变量或更复杂晶体学问题的题目略简单。" + }, + { + "idx": 4228, + "question": "Which of these elements would you expect to form with copper a substitutional solid solution having complete solubility? Below, atomic radius, crystal structure, electronegativity, and the most common valence are tabulated, for several elements; for those that are nonmetals, only atomic radii are indicated.", + "answer": "Ni, Pd, and Pt meet all of the criteria and thus form substitutional solid solutions having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个元素中选择符合特定条件的元素，答案给出了具体的元素名称，符合选择题的特征。 | 知识层次: 题目要求考生根据给定的元素性质（原子半径、晶体结构、电负性和价态）综合分析并选择能与铜形成完全固溶体的元素。这需要考生理解固溶体的形成条件（Hume-Rothery规则），并将这些规则应用到具体元素的性质分析中。虽然不涉及复杂的计算或多步推理，但需要对多个概念进行关联和综合判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解并应用多个材料科学的核心概念，包括原子半径、晶体结构、电负性和价态等。其次，解题过程需要综合分析表格数据，并判断哪些元素满足形成完全固溶体的条件。此外，题目还涉及高温下的同素异构转变，增加了分析的复杂性。因此，该题目在选择题型中属于需要复杂分析过程的判断，符合等级4的标准。" + }, + { + "idx": 4230, + "question": "Which of these elements would you expect to form with copper an interstitial solid solution? Below, atomic radius, crystal structure, electronegativity, and the most common valence are tabulated, for several elements; for those that are nonmetals, only atomic radii are indicated.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪些元素会与铜形成间隙固溶体，并需要基于原子半径等性质进行论述，答案提供了具体的解释而非简单的选择或判断。 | 知识层次: 题目要求考生根据给定的元素性质（原子半径、晶体结构、电负性、价态）来判断哪些元素可以与铜形成间隙固溶体。这需要考生理解间隙固溶体的形成条件，并能够综合分析多个因素（如原子半径的差异）来得出结论。虽然不涉及复杂的计算或推理，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于较高难度，需要综合理解原子半径、晶体结构、电负性和价态等多个概念，并进行多步分析和比较。题目要求考生不仅知道哪些元素可以形成间隙固溶体，还要理解为什么这些元素符合条件（原子半径显著小于铜）。这需要考生具备较强的综合分析能力和概念关联能力。" + }, + { + "idx": 4231, + "question": "What is the composition, in atom percent, of an alloy that consists of 30 wt% Zn and 70 wt% Cu ?", + "answer": "the composition of the alloy is 29.4 \\, \\text{at}% \\, \\mathrm{zn} and 70.6 \\, \\text{at}% \\, \\mathrm{cu}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如原子百分比的计算）来得出合金的组成，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的重量百分比到原子百分比的转换计算，需要应用简单的公式和进行数值计算，但不需要多步推理或综合分析。 | 难度: 在选择题中属于简单应用难度，需要应用基本公式（原子百分比计算公式）并进行简单计算，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 4232, + "question": "What is the composition, in weight percent, of an alloy that consists of 6 at% \\mathrm{Pb} and 94 \\mathrm{at}% \\mathrm{Sn} ?", + "answer": "the composition of the alloy is: 1. 10.0 \\, \\text{wt% pb} 2. 90.0 \\, \\text{wt% sn}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（原子百分比转换为重量百分比）来确定合金的组成，答案以具体数值形式给出。 | 知识层次: 题目涉及基本的原子百分比到重量百分比的转换计算，需要应用简单的公式和基本的元素质量数据，属于直接套用基本公式的简单应用层次。 | 难度: 在选择题型中，该题目需要应用基本的原子百分比与重量百分比转换公式，并进行简单的计算。虽然涉及公式应用，但步骤直接且不复杂，属于简单公式应用计算。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4233, + "question": "What is the composition, in atom percent, of an alloy that contains 99.7 lb_{m} copper, 102 lb_{m} zinc, and 2.1 lb_{m} lead?\n", + "answer": "the composition of the alloy in atom percent is: \\[\nc_{\\mathrm{cu}} = 50.0 \\, \\text{at}%\n\\] \\[\nc_{\\mathrm{zn}} = 49.7 \\, \\text{at}%\n\\] \\[\nc_{\\mathrm{pb}} = 0.3 \\, \\text{at}%\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算合金中各元素的原子百分比，需要通过数值计算和公式应用来得出具体数值。答案以具体的数值形式给出，符合计算题的特征。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及原子百分比的转换，但计算过程相对直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要应用基本的原子百分比计算公式，并进行简单的数值计算。虽然涉及多个元素的质量转换和百分比计算，但步骤较为直接，属于简单公式应用计算。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4234, + "question": "What is the composition, in atom percent, of an alloy that consists of 97 wt% Fe and 3 wt% Si?", + "answer": "the composition of the alloy is 94.2 at% fe and 5.8 at% si.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用（将重量百分比转换为原子百分比），答案以具体数值形式给出，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及原子百分比和重量百分比之间的转换，需要应用相关公式并理解其物理意义，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解质量百分比与原子百分比之间的转换关系，涉及多步计算（包括分子量计算、摩尔数转换等），并需要综合分析合金成分的转换过程。虽然题目给出了正确选项，但解题过程仍需要较强的概念关联和计算能力。" + }, + { + "idx": 4235, + "question": "Calculate the number of atoms per cubic meter in aluminum.", + "answer": "6.05 × 10^{28} atoms/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铝中每立方米的原子数），并给出了具体的计算公式和步骤，最终答案是一个具体的数值结果。 | 知识层次: 题目要求计算铝中每立方米的原子数，这需要应用基本的密度和摩尔质量公式进行计算，属于直接套用公式的简单应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式（如密度和摩尔质量的关系）进行简单计算，无需多个步骤或公式组合。属于单一公式直接计算的难度等级。" + }, + { + "idx": 4236, + "question": "The concentration of carbon in an iron-carbon alloy is 0.15 wt%. What is the concentration in kilograms of carbon per cubic meter of alloy?", + "answer": "the concentration of carbon in the alloy is 11.8 \\mathrm{kg/m^{3}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定碳在合金中的浓度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行基本的单位转换和公式应用（浓度换算），但计算过程较为直接，仅涉及单一概念的应用，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用和简单计算，即直接将给定的重量百分比转换为千克每立方米的浓度。解题步骤简单，无需复杂的推导或多步骤计算，属于最基础的难度等级。" + }, + { + "idx": 4237, + "question": "Cite the relative Burgers vector-dislocation line orientations for edge, screw, and mixed dislocations.", + "answer": "The Burgers vector and dislocation line are perpendicular for edge dislocations, parallel for screw dislocations, and neither perpendicular nor parallel for mixed dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述不同位错类型中Burgers矢量与位错线方向的相对关系，答案以文字形式详细描述了三种位错类型的特征，符合简答题的特征。 | 知识层次: 题目考查对位错类型（刃型、螺型和混合型）与伯格斯矢量相对取向的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求记忆并识别不同类型位错的Burgers矢量与位错线之间的相对取向关系，属于基础概念记忆的简单应用。题目直接给出了明确的定义对应关系，无需复杂推理或分析，因此属于最低难度等级。" + }, + { + "idx": 4238, + "question": "For an FCC single crystal, would you expect the surface energy for a (100) plane to be greater or less than that for a (111) plane? Why? ", + "answer": "The surface energy for a crystallographic plane will depend on its packing density [i.e., the planar density (Section 3.11)] - that is, the higher the packing density, the greater the number of nearest-neighbor atoms, and the more atomic bonds in that plane that are satisfied, and, consequently, the lower the surface energy. From the solution to Problem 3.54, planar densities for FCC (100) and (111) planes are \\frac{1}{4 R^{2}} and \\frac{1}{2 R^{2} \\sqrt{3}}, respectively - that is \\frac{0.25}{R^{2}} and \\frac{0.29}{R^{2}} (where R is the atomic radius). Thus, since the planar density for (111) is greater, it will have the lower surface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述为什么FCC单晶的(100)面表面能会大于或小于(111)面，答案提供了详细的文字解释和理论依据，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解表面能与晶面密度的关系，并应用FCC晶体结构的平面密度计算结果进行比较分析。虽然涉及基础概念，但需要多步推理和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多角度分析论述。题目不仅要求考生理解表面能与晶面密度的关系，还需要掌握FCC晶体结构中(100)和(111)晶面的平面密度计算。此外，题目要求考生能够将计算结果与表面能的概念进行关联，综合分析得出正确结论。这种多步骤的计算和概念关联在选择题型中属于较复杂的题目。" + }, + { + "idx": 4239, + "question": "For a BCC single crystal, would you expect the surface energy for a (100) plane to be greater or less than that for a (110) plane? Why? ", + "answer": "The surface energy for a crystallographic plane will depend on its packing density-that is, the higher the packing density, the greater the number of nearest-neighbor atoms, and the more atomic bonds in that plane that are satisfied, and, consequently, the lower the surface energy. From the solution to Problem 3.55, the planar densities for BCC (100) and (110) are \\frac{3}{16 R^{2}} and \\frac{3}{8 R^{2} \\sqrt{2}}, respectively-that is \\frac{0.19}{R^{2}} and \\frac{0.27}{R^{2}}. Thus, since the planar density for (110) is greater, it will have the lower surface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么BCC单晶的(100)面表面能会大于或小于(110)面，答案通过文字论述和比较平面密度来解释原因，没有涉及计算、选择或判断对错。 | 知识层次: 题目要求比较BCC晶体不同晶面的表面能，需要理解表面能与原子堆积密度的关系，并应用平面密度的计算结果进行分析。这涉及多步概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题型中，该题目属于较高难度，需要考生掌握晶体结构、表面能、平面密度等多个概念，并进行多步计算和综合分析。题目不仅要求考生理解BCC晶体的(100)和(110)面的平面密度计算，还需要将这些计算结果与表面能的概念关联起来，最终得出正确的比较结论。这种多角度分析和论述的要求使得该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 4240, + "question": "For a given material, would you expect the surface energy to be greater than, the same as, or less than the grain boundary energy? Why?", + "answer": "The surface energy will be greater than the grain boundary energy. For grain boundaries, some atoms on one side of a boundary will bond to atoms on the other side; such is not the case for surface atoms. Therefore, there will be fewer unsatisfied bonds along a grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么表面能会大于晶界能，需要文字论述和解释，而不是简单的选择或判断。答案也提供了详细的解释说明。 | 知识层次: 题目要求解释表面能与晶界能的关系，并分析其背后的原子键合机制。这需要综合运用材料科学中的表面与界面知识，理解原子键合状态对能量状态的影响，并进行推理分析。虽然涉及基础概念，但更侧重于机理解释和综合分析。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解表面能和晶界能的基本概念，还需要深入分析原子键合状态的差异（表面原子存在未饱和键而晶界原子部分键合），并据此进行机理层面的解释。这种需要综合材料科学原理进行推理分析的题目，比单纯记忆概念或简单比较的题目难度更高，属于选择题中的机理深度解释类型。" + }, + { + "idx": 4241, + "question": "The grain boundary energy of a small-angle grain boundary is less than for a high-angle one. Why is this so?", + "answer": "The small-angle grain boundary energy is lower than for a high-angle one because more atoms bond across the boundary for the small-angle, and, thus, there are fewer unsatisfied bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么小角度晶界的能量低于大角度晶界，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释小角度晶界能低于大角度晶界的原因，涉及晶界原子键合状态的分析和比较，需要综合运用晶界结构知识和键合理论进行机理层面的解释，思维深度较高。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解晶界能的基本概念，还需要深入分析小角度晶界与大角度晶界在原子键合方面的差异，并据此解释能量差异的机理。这需要综合运用材料科学中的晶体缺陷知识和键合理论，进行推理分析。正确选项涉及对\"未满足键\"这一微观机理的解释，属于机理深度解释层面的考核，因此符合等级4的标准。" + }, + { + "idx": 4242, + "question": "(a) Briefly describe a twin and a twin boundary.", + "answer": "A twin boundary is an interface such that atoms on one side are located at mirror image positions of those atoms situated on the other boundary side. The region on one side of this boundary is called a twin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述孪晶和孪晶界，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对孪晶和孪晶界面的基本定义和概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求考生记忆并复述孪晶和孪晶界面的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的定义性描述，无需进行解释或比较分析，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4243, + "question": "(b) Cite the difference between mechanical and annealing twins.", + "answer": "Mechanical twins are produced as a result of mechanical deformation and generally occur in BCC and HCP metals. Annealing twins form during annealing heat treatments, most often in FCC metals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释机械孪晶和退火孪晶的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对机械孪晶和退火孪晶的基本定义和形成条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个专业概念（机械孪晶和退火孪晶）的比较，但正确选项已经提供了明确的定义和区分特征（形成机制和常见金属结构）。考生只需记忆并区分这两个基本概念即可作答，不需要进行复杂的推理或综合分析。这符合等级2\"概念解释和描述\"的要求，比单纯的定义记忆（等级1）稍复杂，但远未达到需要阐述复杂概念体系的等级3难度。" + }, + { + "idx": 4244, + "question": "Briefly explain the concept of steady state as it applies to diffusion.", + "answer": "Steady-state diffusion is the situation wherein the rate of diffusion into a given system is just equal to the rate of diffusion out, such that there is no net accumulation or depletion of diffusing species--i.e., the diffusion flux is independent of time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释稳态扩散的概念，答案以文字解释和论述的形式呈现，没有涉及计算、选择或判断对错。 | 知识层次: 题目考查对稳态扩散这一基本概念的记忆和理解，不需要复杂的应用或分析，仅需解释其定义和基本原理。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释稳态扩散的概念，但正确选项已经提供了清晰的定义和关键特征（如扩散速率相等、无净积累、通量不随时间变化等）。这需要考生不仅记住定义，还要理解其背后的基本原理，但不需要进行复杂的分析或比较多个概念。因此，它属于概念解释和描述的难度等级。" + }, + { + "idx": 4245, + "question": "(a) Briefly explain the concept of a driving force.", + "answer": "The driving force is that which compels a reaction to occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释一个概念，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对\"driving force\"这一基本概念的定义和简单解释，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，此题仅要求对\"driving force\"这一基础概念进行简单定义回忆，属于最基础的定义简答层次。正确选项直接给出了概念的简明定义，不需要任何解释、分析或比较过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4246, + "question": "(b) What is the driving force for steady-state diffusion?", + "answer": "The driving force for steady-state diffusion is the concentration gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案是一个简短的文字解释，没有涉及计算或选择选项。 | 知识层次: 题目考查对扩散驱动力的基本概念记忆，仅需回答浓度梯度这一基本原理，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即稳态扩散的驱动力是浓度梯度这一基本原理。题目不涉及复杂概念体系或需要解释描述，属于最基础的定义简答级别，因此难度等级为1。" + }, + { + "idx": 4247, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 10-h duration will raise the carbon concentration to 0.45 wt% at a point 2.5mm from the surface. Estimate the time necessary to achieve the same concentration at a 5.0-mm position for an identical steel and at the same carburizing temperature.", + "answer": "the time necessary to achieve a carbon concentration of 0.45 \\text{wt}% at a 5.0 \\text{mm} position is 40 \\text{h}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以估计在特定条件下达到相同碳浓度所需的时间。答案给出了具体的数值结果（40小时），表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数调整，需要理解碳浓度与时间和位置的关系，并进行综合分析。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等难度，需要理解扩散定律（如菲克第二定律）并进行多步计算。题目要求考生能够将已知条件（时间、浓度、距离）关联起来，通过比例关系推导出新的时间值。虽然计算本身不涉及复杂变量，但需要综合运用材料科学中的扩散概念和数学推导能力。" + }, + { + "idx": 4248, + "question": "The preexponential and activation energy for the diffusion of iron in cobalt are 1.1 × 10^{-5}{m}^{2} / s and 253,300 J/ mol, respectively. At what temperature will the diffusion coefficient have a value of 2.1 × 10^{-14}{m}^{2} / s ?", + "answer": "the temperature at which the diffusion coefficient has a value of 2.1 × 10^{-14} m^{2}/s is 1518 k (1245^{\\circ} C). alternatively, using the vmse software, the temperature is found to be 1519 k.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数公式（Arrhenius方程）进行数值计算，求解特定扩散系数对应的温度。答案提供了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及对数运算和温度单位的转换，需要理解公式中各参数的含义及其相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要应用阿伦尼乌斯公式进行多步骤计算，涉及对数运算和温度单位的转换。虽然题目提供了所有必要参数，但解题过程需要准确执行数学运算和概念关联，属于综合性计算问题。" + }, + { + "idx": 4249, + "question": "The activation energy for the diffusion of carbon in chromium is 111,000 J/ mol. Calculate the diffusion coefficient at 1100 K\\left(827^{\\circ} C\\right), given that D at 1400 K\\left(1127^{\\circ} C\\right) is 6.25 × 10^{-11}{m}^{2} / s.", + "answer": "the diffusion coefficient at 1100k is 4.6 × 10^{-12}{m}^{2} / s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和扩散系数数据，应用阿伦尼乌斯方程进行数值计算，最终得出特定温度下的扩散系数。答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用阿伦尼乌斯方程计算扩散系数，并理解温度对扩散系数的影响。虽然计算过程较为直接，但需要综合运用扩散理论和数学计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解阿伦尼乌斯方程的应用，并进行多步计算。题目要求考生能够将给定的温度、扩散系数和活化能关联起来，正确运用公式计算不同温度下的扩散系数。虽然题目提供了部分已知条件，但解题过程涉及对数运算和指数计算，对考生的综合计算能力和概念理解有一定要求。" + }, + { + "idx": 4250, + "question": "The diffusion coefficients for iron in nickel are given at two temperatures: 1273 K with D = 9.4 x 10^-16 m^2/s and 1473 K with D = 2.4 x 10^-14 m^2/s. Determine the values of D0 and the activation energy Qd.", + "answer": "the values are d0 = 2.2 x 10^-5 m^2/s and the activation energy qd = 252,400 j/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，使用阿伦尼乌斯方程计算D0和激活能Qd的数值。解答过程涉及数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯方程进行多步计算，涉及对数运算和联立方程求解，需要理解温度与扩散系数的关系并正确应用公式，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与温度的关系（阿伦尼乌斯方程），并能够进行多步骤的计算来求解D0和激活能Qd。虽然题目提供了正确选项，但解题过程涉及对数运算和联立方程求解，对学生的计算能力和概念理解有较高要求。" + }, + { + "idx": 4251, + "question": "The diffusion coefficients for iron in nickel are given at two temperatures: 1273 K with D = 9.4 x 10^-16 m^2/s and 1473 K with D = 2.4 x 10^-14 m^2/s. What is the magnitude of D at 1100°C (1373 K)?", + "answer": "the magnitude of d at 1100°c (1373 k) is 5.4 x 10^-15 m^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用阿伦尼乌斯方程或其他相关公式进行计算，以得出在特定温度下的扩散系数。答案是一个具体的数值结果，需要通过计算步骤得出。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，包括求解活化能和预指数因子，然后计算新的温度下的扩散系数。这涉及到对公式的理解和综合应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等难度，需要理解扩散系数的温度依赖性（阿伦尼乌斯方程），进行多步计算（求解活化能和指前因子），并应用这些参数计算新温度下的扩散系数。虽然题目提供了部分数据，但解题过程涉及多个概念的综合运用和数学计算步骤。" + }, + { + "idx": 4252, + "question": "The diffusion coefficients for silver in copper are given at two temperatures: T(°C) = 650, D(m2/s) = 5.5 × 10^-16 and T(°C) = 900, D(m2/s) = 1.3 × 10^-13. Determine the values of D0 and Qd.", + "answer": "the values are d0 = 7.5 × 10^-5 m2/s and qd = 196,700 j/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，计算D0和Qd的值。解答过程需要应用阿伦尼乌斯方程进行数值计算，答案也是具体的数值结果。这符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯方程进行多步计算，涉及温度转换、对数运算和线性回归分析，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解阿伦尼乌斯方程的概念，并进行多步计算（包括对数运算和单位转换）。虽然题目提供了正确选项，但解题过程涉及温度转换、方程联立求解等综合分析步骤，对学生的计算能力和概念掌握深度有较高要求。" + }, + { + "idx": 4253, + "question": "The diffusion coefficients for silver in copper are given at two temperatures: T(°C) = 650, D(m2/s) = 5.5 × 10^-16 and T(°C) = 900, D(m2/s) = 1.3 × 10^-13. What is the magnitude of D at 875°C?", + "answer": "the magnitude of d at 875°c is 8.3 × 10^-14 m2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用阿伦尼乌斯方程或其他相关公式进行计算，以求出在特定温度下的扩散系数。答案是一个具体的数值结果，这表明需要进行数值计算和公式应用。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯方程进行多步计算，涉及温度转换、对数运算和指数运算，需要综合分析给定的数据点并求解未知参数，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解扩散系数与温度的关系，应用阿伦尼乌斯方程进行多步计算，并综合分析给定数据来求解未知温度下的扩散系数。虽然题目提供了必要的数据，但解题过程涉及对数运算和代数操作，对学生的计算能力和概念掌握有一定要求。" + }, + { + "idx": 4254, + "question": "Carbon is allowed to diffuse through a steel plate 15mm thick. The concentrations of carbon at the two faces are 0.65 and 0.30kg C / m^{2} Fe, which are maintained constant. If the preexponential and activation energy are 6.2 × 10^{-7}{m}^{2} / s and 80,000 J/ mol, respectively, compute the temperature at which the diffusion flux is 1.43 × 10^{-9}kg / m^{2}-s.", + "answer": "the temperature at which the diffusion flux is 1.43 × 10^{-9}kg / m^{2}-s is 1044k or 771^{\\circ} C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解温度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律（菲克第一定律）和扩散系数公式（阿伦尼乌斯方程），并进行温度求解的综合分析。虽然不涉及复杂的推理或机理解释，但需要理解和关联多个概念并进行数值计算。 | 难度: 在选择题中属于中等偏上难度，需要综合运用扩散定律、阿伦尼乌斯方程和浓度梯度计算等多个概念，并进行多步计算才能得出正确答案。虽然题目提供了所有必要参数，但解题过程涉及多个公式的串联使用和单位转换，对学生的综合分析能力有一定要求。" + }, + { + "idx": 4255, + "question": "The steady-state diffusion flux through a metal plate is 5.4 × 10^{-10}kg / m^{2}-s at a temperature of 727^{\\circ} C (1000 K) and when the concentration gradient is -350kg / m^{4}. Calculate the diffusion flux at 1027^{\\circ} C(1300 K) for the same concentration gradient and assuming an activation energy for diffusion of 125,000 J/ mol.", + "answer": "the diffusion flux at 1027^{\\circ} C (1300 k) is 1.74 × 10^{-8} \\mathrm{kg/m^{2}-s}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散通量，涉及温度变化和浓度梯度的计算，答案也是具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散通量的公式，并考虑温度对扩散系数的影响，同时需要理解阿伦尼乌斯方程的应用。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行计算。 | 难度: 在选择题中属于中等难度，需要理解扩散通量的概念、温度对扩散系数的影响，并应用阿伦尼乌斯方程进行多步计算。虽然题目提供了部分参数，但仍需综合运用多个物理概念和数学计算才能得出正确答案。" + }, + { + "idx": 4256, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 275 MPa (40,000 psi), and the modulus of elasticity is 115 GPa (16.7 x 10^6 psi). What is the maximum load that may be applied to a specimen with a cross-sectional area of 325 mm^2 (0.5 in.^2) without plastic deformation?", + "answer": "the maximum load that may be applied without plastic deformation is 89,375 n (20,000 lb_f).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应力=载荷/面积）来求解最大载荷，答案也是具体的数值计算结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即利用应力公式（应力=力/面积）来计算最大载荷，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（应力=力/面积）进行计算，无需组合多个公式或进行复杂的概念分析。解题步骤简单，只需将给定的应力值和面积代入公式即可得出最大载荷。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4257, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 275 MPa (40,000 psi), and the modulus of elasticity is 115 GPa (16.7 x 10^6 psi). If the original specimen length is 115mm (4.5 in.), what is the maximum length to which it may be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen may be stretched without causing plastic deformation is 115.28mm (4.51 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性模量和应力-应变关系）来确定最大拉伸长度，答案是一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即利用弹性模量和应力计算最大弹性变形长度，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解塑性变形开始时的应力和弹性模量的概念，但解题步骤相对直接，只需应用胡克定律（Hooke's Law）进行简单的应变计算，然后转换为长度变化。不需要复杂的分析或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 4258, + "question": "A cylindrical rod of copper (E=110g P a, 16 × 10^{6} psi) having a yield strength of 240 MPa(35,000 psi) is to be subjected to a load of 6660N\\left(1500 lb p\\right). If the length of the rod is 380 mm(15.0 in.), what must be the diameter to allow an elongation of 0.50 mm(0.020 in.) ?", + "answer": "the diameter must be 7.65mm (0.30 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定铜棒的直径，答案是一个具体的数值结果（7.65mm），解答过程需要运用材料力学中的弹性变形公式进行计算。 | 知识层次: 题目需要进行多步计算，包括应用胡克定律计算应力、应变关系，以及几何关系计算直径，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的思维深度和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要综合运用弹性模量、应力应变关系和几何变形公式进行多步计算。题目涉及单位换算、公式变形和综合分析能力，但作为选择题可以通过选项验证简化部分计算步骤。" + }, + { + "idx": 4259, + "question": "Compute the elastic modulus for titanium, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(a) the elastic modulus for titanium is 106.4 gpa, which is in very good agreement with the value of 107 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算钛的弹性模量，并与表格中的参考值进行比较。解答过程涉及数值计算和结果对比，符合计算题的特征。 | 知识层次: 题目要求计算钛的弹性模量，并与参考值进行比较。这涉及基本的应力-应变曲线分析和简单计算，属于直接套用公式和基本概念的应用层次，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用弹性模量的基本概念和简单计算，无需多个公式组合或复杂分析。题目提供了明确的数值比较，属于单一公式直接计算的简单应用层次。" + }, + { + "idx": 4260, + "question": "Compute the elastic modulus for tempered steel, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(b) the elastic modulus for tempered steel is 204.7 gpa, which is in reasonably good agreement with the value of 207 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算回火钢的弹性模量，并与表格中的数值进行比较。解答过程涉及数值计算和结果对比，符合计算题的特征。答案给出了具体的计算数值（204.7 GPa）和对比结果，进一步验证了这是一个计算题。 | 知识层次: 题目要求计算弹性模量，并比较给定表格中的数值。这涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用给定的弹性模量数值进行比较，无需复杂计算或公式组合。属于单一公式直接计算的简单应用层次，因此难度等级为1。" + }, + { + "idx": 4261, + "question": "Compute the elastic modulus for aluminum, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(c) the elastic modulus for aluminum is 69.1 gpa, which is in excellent agreement with the value of 69 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铝的弹性模量，并将计算结果与表格中的值进行比较。答案给出了具体的数值计算结果（69.1 GPa）和比较结论，这符合计算题的特征。 | 知识层次: 题目要求通过应力-应变行为计算铝的弹性模量，并将计算结果与参考表中的数值进行比较。这主要涉及基本公式的应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用已知的弹性模量数值进行比较，无需进行任何计算或公式应用。题目要求的知识点掌握深度较浅，解题步骤极其简单，属于单一数值直接比较的题型，因此属于等级1难度。" + }, + { + "idx": 4262, + "question": "Compute the elastic modulus for carbon steel, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(d) the elastic modulus for carbon steel is 215 gpa, which is in reasonable agreement with the value of 207 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出碳钢的弹性模量，并与参考表中的数值进行比较。虽然答案给出了具体数值，但解题过程需要基于应力-应变曲线进行计算，符合计算题的特征。 | 知识层次: 题目要求计算碳钢的弹性模量，并将计算结果与参考表中的数值进行比较。这主要涉及基本的应力-应变关系理解和简单的数值计算，属于直接套用基本公式和简单比较的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型内，该题目仅需要直接应用给定的弹性模量数值进行比较，无需任何计算或复杂分析。属于单一公式直接计算的简单应用层次，是最基础的难度等级。" + }, + { + "idx": 4263, + "question": "Consider a cylindrical specimen of some hypothetical metal alloy that has a diameter of 8.0 mm(0.31 in.). A tensile force of 1000N\\left(225 lb_{\\mathrm{f}}\\right) produces an elastic reduction in diameter of 2.8 × 10^{-4} mm\\left(1.10 × 10^{-5} in\\right..). Compute the modulus of elasticity for this alloy, given that Poisson's ratio is 0.30 .", + "answer": "the modulus of elasticity for this alloy is 1.705 × 10^{11} pa or 170.5 gpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解弹性模量，涉及直径变化、力和泊松比等参数的计算过程，最终需要给出具体的数值结果。答案也是一个具体的数值，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应力、应变的计算，并应用胡克定律和泊松比的概念来求解弹性模量。这需要理解相关概念并能够将它们关联起来进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要综合运用弹性模量、泊松比和应变计算等多个概念，并进行多步骤的推导和计算。虽然题目提供了所有必要的信息，但解题过程涉及多个公式的转换和单位换算，对学生的综合分析和计算能力有一定要求。" + }, + { + "idx": 4264, + "question": "A cylindrical rod 100mm long and having a diameter of 10.0mm is to be deformed using a tensile load of 27,500 N. It must not experience plastic deformation. Of the materials listed as follows, which are possible candidates? Justify your choice(s).", + "answer": "Of the alloys listed, the steel alloy is a possible candidate because it meets the criterion of not experiencing plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个材料中选择合适的候选材料，并需要文字解释和论述选择的合理性，而不是简单的选择或计算。 | 知识层次: 题目要求考生在给定的材料中选择合适的候选材料，确保在给定载荷下不发生塑性变形。这需要考生理解材料的力学性能（如屈服强度）与载荷之间的关系，并进行多步计算（如计算应力）和综合分析（比较不同材料的性能）。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生进行多步计算（如应力计算）、概念关联（理解塑性变形的条件）以及综合分析（比较不同材料的性能）。此外，题目还要求考生在多个选项中做出合理的选择，并给出明确的理由，这增加了题目的复杂性和难度。" + }, + { + "idx": 4265, + "question": "A cylindrical rod 100mm long and having a diameter of 10.0mm is to be deformed using a tensile load of 27,500 N. It must not experience a diameter reduction of more than 7.5 x 10^-3 mm. Of the materials listed as follows, which are possible candidates? Justify your choice(s).", + "answer": "Of the alloys listed, the steel alloy is a possible candidate because it meets the criterion regarding diameter reduction. The titanium alloy is not a candidate as it fails this criterion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个材料中选择符合条件的候选材料，并需要文字解释和论述选择的理由，而不是简单的选择或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目需要学生进行多步计算（如应力、应变计算）和综合分析（比较不同材料的性能），涉及概念关联（如弹性模量与直径变化的关系）和材料选择标准的应用，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握材料力学性能的基本概念（如弹性模量、泊松比等），还需要进行多步计算（如应力、应变、直径变化等），并综合分析计算结果与给定条件的匹配程度。此外，题目还要求考生在多个材料选项中进行比较和选择，需要较强的概念关联和综合分析能力。虽然题目提供了正确选项，但解题过程涉及的知识深度和步骤复杂度使其在选择题型中属于较难级别。" + }, + { + "idx": 4266, + "question": "A cylindrical metal specimen having an original diameter of 12.8mm (0.505 in.) and gauge length of 50.80mm (2.000 in.) is pulled in tension until fracture occurs. The diameter at the point of fracture is 6.60mm (0.260 in.), and the fractured gauge length is 72.14mm (2.840 in.). Calculate the ductility in terms of percent reduction in area.", + "answer": "the ductility in terms of percent reduction in area is 73.4%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解材料的延展性（以面积减少百分比表示），需要根据给定的原始尺寸和断裂后尺寸进行计算，最终得出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过原始直径和断裂后的直径计算面积减少百分比。虽然需要理解延展性的概念，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察基本公式应用和简单计算。虽然需要计算原始和断裂后的横截面积，但步骤较为直接，仅涉及单一公式（面积计算和百分比减少公式）的套用，无需多个公式组合或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4267, + "question": "A cylindrical metal specimen having an original diameter of 12.8mm (0.505 in.) and gauge length of 50.80mm (2.000 in.) is pulled in tension until fracture occurs. The diameter at the point of fracture is 6.60mm (0.260 in.), and the fractured gauge length is 72.14mm (2.840 in.). Calculate the ductility in terms of percent elongation.", + "answer": "the ductility in terms of percent elongation is 42%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（计算延展性的百分比伸长率）来得出具体数值结果（42%），属于典型的计算题类型。 | 知识层次: 题目要求进行基本的百分伸长率计算，仅需应用简单公式（(最终长度-原始长度)/原始长度×100%）并进行一步数值计算，不涉及多步运算或复杂概念关联。 | 难度: 在选择题型中，该题目仅需要直接应用百分伸长率的基本公式进行计算，即（断裂后长度 - 原始长度）/ 原始长度 × 100%。题目提供了所有必要的数值，计算过程简单直接，无需多个步骤或复杂推理，属于单一公式直接计算的难度等级。" + }, + { + "idx": 4268, + "question": "For some metal alloy, a true stress of 415 MPa(60,175 psi) produces a plastic true strain of 0.475 . How much will a specimen of this material elongate when a true stress of 325 MPa(46,125 psi) is applied if the original length is 300mm (11.8 in.)? Assume a value of 0.25 for the strain-hardening exponent n.", + "answer": "the specimen will elongate by 58.8 mm (2.31 \\text{ in}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及金属合金的真实应力、真实应变和应变硬化指数的计算，最终需要求出伸长量。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及真实应力-应变关系的公式应用，需要理解应变硬化指数的概念，并进行数值计算。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解塑性应变、应变硬化指数等概念，并进行多步计算和综合分析。题目涉及真实应力-应变关系的应用，要求考生能够正确运用公式推导和单位转换，同时需要一定的数学计算能力。虽然题目提供了部分参数，但解题过程仍需要较强的逻辑思维和计算能力。" + }, + { + "idx": 4269, + "question": "Cite five factors that lead to scatter in measured material properties.", + "answer": "The five factors that lead to scatter in measured material properties are the following: (1) test method; (2) variation in specimen fabrication procedure; (3) operator bias; (4) apparatus calibration; and (5) material inhomogeneities and/or compositional differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举导致材料性能测量分散的五个因素，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对材料性能测量中导致数据分散的五个基本因素的记忆和列举，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目要求列举五个导致材料性能测量分散的因素，属于概念解释和描述层次。虽然需要记忆多个因素，但每个因素都是基础概念，不需要复杂的分析或比较。因此，难度属于中等（等级2）。" + }, + { + "idx": 4270, + "question": "To provide some perspective on the dimensions of atomic defects, consider a metal specimen that has a dislocation density of 10^4 mm^-2. Suppose that all the dislocations in 1000 mm^3 (1 cm^3) were somehow removed and linked end to end. How far (in miles) would this chain extend?", + "answer": "for a dislocation density of 10^4 mm^-2, the chain would extend 6.2 miles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定位错链的总长度并将其转换为英里单位。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式应用和简单计算，需要将位错密度转换为总长度，并进行单位换算，思维过程较为直接，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解位错密度的概念，但解题步骤相对直接，只需套用给定的位错密度和体积进行简单计算即可得出结果。不需要多个公式组合或复杂的分析过程，因此属于等级2。" + }, + { + "idx": 4271, + "question": "Now suppose that the density is increased to 10^10 mm^-2 by cold working. What would be the chain length of dislocations in 1000 mm^3 of material?", + "answer": "for a dislocation density of 10^10 mm^-2, the chain would extend 6.2 x 10^6 miles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解位错的链长度，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的位错密度计算位错链的长度。虽然需要理解位错密度的概念，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式进行简单计算，属于单一公式直接计算的难度等级。题目给出了明确的密度数值和体积，要求计算位错链长度，解题步骤简单直接，无需复杂的推理或多步骤计算。" + }, + { + "idx": 4272, + "question": "For edge dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "edge dislocation--parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述边缘位错中施加的剪切应力方向与位错线运动方向之间的关系，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对刃位错基本概念的记忆和理解，只需要记住刃位错线运动方向与外加剪切应力方向的关系即可回答，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即刃位错中施加剪切应力方向与位错线运动方向的关系。题目直接给出正确选项\"parallel\"，无需任何解释或分析步骤，属于最简单的定义性知识考查。" + }, + { + "idx": 4273, + "question": "For screw dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "screw dislocation--perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述螺丝位错中施加的剪切应力方向与位错线运动方向之间的关系，答案需要文字描述而非选择或判断。 | 知识层次: 题目考查对螺型位错基本概念的记忆和理解，即施加的剪切应力方向与位错线运动方向之间的关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆螺丝位错的基本定义和方向关系，属于基础概念记忆层次，解题步骤简单，无需复杂分析或推理。" + }, + { + "idx": 4274, + "question": "For mixed dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "mixed dislocation--neither parallel nor perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释混合位错中施加剪切应力方向与位错线运动方向之间的关系，答案需要论述而非选择或判断 | 知识层次: 题目考查对混合位错基本概念的记忆和理解，特别是位错线运动方向与外加剪切应力方向的关系这一基本原理。 | 难度: 在选择题型中，该题目仅要求记忆混合位错的基本定义和分类，即混合位错的方向与外加剪切应力方向的关系。题目直接给出了正确选项，不需要复杂的推理或概念间的比较分析，属于最基础的概念记忆题。" + }, + { + "idx": 4275, + "question": "Define a slip system.", + "answer": "A slip system is a crystallographic plane, and, within that plane, a direction along which dislocation motion (or slip) occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"slip system\"进行定义和解释，需要提供文字论述而非选择、判断或计算 | 知识层次: 题目考查对\"slip system\"这一基本概念的定义记忆和理解，属于材料科学中晶体缺陷和塑性变形的基础知识范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并复述\"slip system\"的基本定义，属于最基础的概念性知识。题目不涉及任何解释、比较或应用层面的要求，完全符合等级1\"基本定义简答\"的标准。选择题型中此类直接考查定义的题目通常难度最低，只需简单记忆即可作答。" + }, + { + "idx": 4276, + "question": "Do all metals have the same slip system? Why or why not?", + "answer": "All metals do not have the same slip system. The reason for this is that for most metals, the slip system will consist of the most densely packed crystallographic plane, and within that plane the most closely packed direction. This plane and direction will vary from crystal structure to crystal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么所有金属的滑移系统不相同，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目不仅需要理解金属滑移系统的基本概念，还需要分析不同晶体结构对滑移系统的影响，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解金属的滑移系统概念，并能够分析不同晶体结构对滑移系统的影响。题目要求考生将晶体结构的紧密堆积面与方向的概念关联起来，并进行综合比较分析。虽然不需要多角度论述或深度关联性分析，但仍需一定的概念理解和应用能力。" + }, + { + "idx": 4277, + "question": "Consider a metal single crystal oriented such that the normal to the slip plane and the slip direction are at angles of 43.1^{\\circ} and 47.9^{\\circ}, respectively, with the tensile axis. If the critical resolved shear stress is 20.7 MPa (3000 psi), will an applied stress of 45 MPa(6500 psi) cause the single crystal to yield? If not, what stress will be necessary?", + "answer": "the resolved shear stress is 22.0 MPa (3181 psi). since this is greater than the critical resolved shear stress of 20.7 MPa (3000 psi), the single crystal will yield.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过计算临界分解剪应力来判断晶体是否会屈服，并涉及角度转换和应力计算，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的角度和应力值计算分解剪应力，并与临界分解剪应力进行比较。虽然需要理解分解剪应力的概念，但整体思维过程较为直接，属于基本公式的直接套用和简单判断。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求应用临界分切应力公式进行计算，并比较计算结果与给定临界值。虽然需要理解分切应力的概念和公式，但计算步骤直接且单一，无需组合多个公式或进行复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4278, + "question": "A single crystal of aluminum is oriented for a tensile test such that its slip plane normal makes an angle of 28.1 degrees with the tensile axis. Three possible slip directions make angles of 62.4 degrees, 72.0 degrees, and 81.1 degrees with the same tensile axis. Which of these three slip directions is most favored?", + "answer": "the most favored slip direction is at an angle of 62.4 degrees with the tensile axis.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过分析角度关系来确定最有利的滑移方向，需要一定的解释和论述，而不是简单的选择、判断或计算。答案也以简短的解释形式给出，符合简答题的特征。 | 知识层次: 题目需要应用施密特定律（Schmid's Law）计算临界分切应力，涉及多步计算和概念关联。学生需要理解滑移面和滑移方向与拉伸轴的几何关系，计算每个滑移方向的施密特因子（cosφcosλ），并比较结果以确定最有利的滑移方向。这超出了简单记忆或直接套用公式的层次，但尚未达到需要复杂分析或创新应用的程度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及晶体滑移方向的选择，需要考生掌握临界分切应力定律，并能够计算不同滑移方向的分切应力。虽然题目给出了具体角度，但仍需进行多步计算和综合分析才能确定最有利的滑移方向。" + }, + { + "idx": 4279, + "question": "A single crystal of aluminum is oriented for a tensile test such that its slip plane normal makes an angle of 28.1 degrees with the tensile axis. The most favored slip direction makes an angle of 62.4 degrees with the tensile axis. If plastic deformation begins at a tensile stress of 1.95 MPa (280 psi), determine the critical resolved shear stress for aluminum.", + "answer": "the critical resolved shear stress for aluminum is 0.80 mpa (114 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的角度和应力值，应用临界分解剪切应力的公式进行计算，最终得出一个具体的数值结果。解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用临界分切应力公式进行计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算临界分解剪应力，只需要应用Schmid定律（τ = σ * cos(φ) * cos(λ)）进行简单代入和计算即可得出结果。不需要多个公式组合或复杂分析，属于最基础的应用题类型。" + }, + { + "idx": 4280, + "question": "The critical resolved shear stress for iron is 27 MPa(4000 psi). Determine the maximum possible yield strength for a single crystal of \\mathrm{Fe} pulled in tension.", + "answer": "the maximum possible yield strength for a single crystal of \\mathrm{fe} pulled in tension is 54 MPa (8000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定单晶铁在拉伸条件下的最大可能屈服强度，需要使用临界分切应力和相关公式进行计算。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用临界分切应力的基本概念和公式进行简单计算，属于直接套用基本公式的应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求应用临界分切应力与屈服强度的基本关系公式（τ = σ/2），只需简单代入给定数值进行计算即可得出答案。无需复杂推导或多步骤分析，属于最基础的应用题类型。" + }, + { + "idx": 4281, + "question": "What is the difference between deformation by twinning and deformation by slip relative to mechanism?", + "answer": "With slip deformation there is no crystallographic reorientation, whereas with twinning there is a reorientation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种变形机制的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释变形机制中的孪生和滑移的区别，涉及晶体学重新取向的概念，需要对两种变形机制的深入理解和综合分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解滑移和孪生两种变形机制的基本概念，还需要深入掌握它们在晶体学取向变化方面的差异。正确选项涉及机理层面的解释，需要考生具备综合分析和推理能力，能够区分两种变形机制的本质区别。这种题目在选择题中属于机理深度解释的层次，对知识掌握的要求较高。" + }, + { + "idx": 4282, + "question": "What is the difference between deformation by twinning and deformation by slip relative to conditions of occurrence?", + "answer": "For slip, the atomic displacements occur in atomic spacing multiples, whereas for twinning, these displacements may be other than by atomic spacing multiples. Slip occurs in metals having many slip systems, whereas twinning occurs in metals having relatively few slip systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种变形机制的区别，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求比较两种变形机制（孪生和滑移）的发生条件，涉及对两种机制的理解和对比分析，需要将相关概念关联起来进行综合说明。虽然不涉及复杂计算或深度推理，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解滑移和孪生两种变形机制的基本概念，还需要比较它们在原子位移方式和发生条件上的差异。这涉及到多步概念关联和综合分析能力，属于中等应用层次的知识要求。正确选项包含了两个层面的对比分析（原子位移方式和滑移系统数量），需要考生在选择题型内进行多角度思考才能准确作答。" + }, + { + "idx": 4283, + "question": "What is the difference between deformation by twinning and deformation by slip relative to final result?", + "answer": "Normally slip results in relatively large deformations, whereas only small deformations result for twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种变形方式的区别，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查变形孪生和滑移变形的基本概念及其最终结果的差异，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（变形孪生和滑移的区别），但需要考生理解并比较两种变形机制的最终结果差异。正确选项明确指出了两种机制在变形程度上的区别，这要求考生不仅要记住定义，还要能够区分和描述两者的特征。相比单纯记忆定义（等级1），这种比较性描述需要更深一层的概念理解，但尚未达到需要分析复杂概念体系的等级3难度。" + }, + { + "idx": 4284, + "question": "Briefly explain why small-angle grain boundaries are not as effective in interfering with the slip process as are high-angle grain boundaries.", + "answer": "Small-angle grain boundaries are not as effective in interfering with the slip process as are high-angle grain boundaries because there is not as much crystallographic misalignment in the grain boundary region for small-angle, and therefore not as much change in slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释小角度晶界在干扰滑移过程中不如大角度晶界有效的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释小角度晶界和大角度晶界在阻碍滑移过程中的不同效果，涉及晶界结构对滑移过程的影响，需要理解晶界角度与滑移方向变化之间的关系，属于概念关联和综合分析层次。 | 难度: 在选择题中属于中等难度，需要理解晶界角度对滑移过程的影响，并进行概念比较分析。题目要求考生理解小角度晶界和高角度晶界在晶体结构错排程度上的差异，以及这种差异如何影响滑移过程。虽然不需要多步计算，但需要对材料科学中的晶界概念有较好的掌握，并能进行综合分析。" + }, + { + "idx": 4285, + "question": "Briefly explain why HCP metals are typically more brittle than FCC and BCC metals.", + "answer": "Hexagonal close packed metals are typically more brittle than FCC and BCC metals because there are fewer slip systems in HCP.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释HCP金属比FCC和BCC金属更脆的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释HCP金属比FCC和BCC金属更脆的原因，涉及晶体结构（HCP、FCC、BCC）和滑移系统的概念关联，需要综合分析不同晶体结构的滑移系统数量及其对材料性能的影响。虽然不涉及复杂计算，但需要理解并关联多个概念，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解HCP、FCC和BCC金属的晶体结构差异，并掌握滑移系统的概念及其对金属塑性的影响。虽然题目要求简要解释，但正确选项涉及多个概念的关联和综合分析，属于中等应用层次的知识要求。" + }, + { + "idx": 4286, + "question": "Two previously undeformed cylindrical specimens of an alloy are to be strain hardened by reducing their cross-sectional areas (while maintaining their circular cross sections). For one specimen, the initial and deformed radii are 16mm and 11 mm, respectively. The second specimen, with an initial radius of 12 mm, must have the same deformed hardness as the first specimen; compute the second specimen's radius after deformation.", + "answer": "the second specimen's radius after deformation is 8.25 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如应变硬化公式）来求解第二个试样变形后的半径，答案是一个具体的数值结果（8.25 mm），属于典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括应变计算和硬度关联分析，涉及概念关联和综合分析。虽然不涉及复杂的推理或创新应用，但需要理解应变硬化原理并进行相应的数值计算。 | 难度: 在选择题中属于中等难度，需要理解应变硬化概念、计算截面面积变化率并进行多步计算。题目涉及两个试样的对比分析，要求考生能够综合应用材料科学知识解决实际问题。虽然计算步骤较多，但在选择题型中通过选项可以辅助验证结果，降低了部分难度。" + }, + { + "idx": 4287, + "question": "Two previously undeformed specimens of the same metal are to be plastically deformed by reducing their cross-sectional areas. One has a circular cross section, and the other is rectangular; during deformation the circular cross section is to remain circular, and the rectangular is to remain as such. Their original and deformed dimensions are as follows:\n\\begin{tabular}{ccc}\n\\hline & Circular (diameter, \\mathbf{m m} ) & Rectangular (\\mathbf{m m}) \\\\\n\\hline Original dimensions & 15.2 & 125 × 175 \\\\\nDeformed dimensions & 11.4 & 75 × 200 \\\\\n\\hline\n\\end{tabular}\nWhich of these specimens will be the hardest after plastic deformation, and why?", + "answer": "the hardest specimen will be the deformed circular one with a cold work percentage of 43.8%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪个试样在塑性变形后会最硬，并说明原因。答案需要文字解释和论述，而不是简单的选择或计算。 | 知识层次: 题目需要计算冷加工百分比（多步计算），并理解冷加工对材料硬度的影响（概念关联），但不需要复杂的机理分析或创新设计。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及塑性变形和冷加工百分比的计算，需要学生掌握材料科学中的基本概念和公式。其次，题目要求对圆形和矩形两种不同形状的试样进行计算和比较，增加了复杂性。此外，正确选项需要学生通过多步计算（包括面积计算和冷加工百分比的计算）才能得出，并且需要理解冷加工百分比与材料硬度之间的关系。这种综合分析能力和多步计算的要求使得该题目在选择题型中属于较高难度。" + }, + { + "idx": 4288, + "question": "A cylindrical specimen of cold-worked copper has a ductility (%EL) of 25%. If its cold-worked radius is 10mm (0.40 in.), what was its radius before deformation?", + "answer": "the radius before deformation was 10.6mm (0.424 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定变形前的圆柱形铜试样的半径。答案给出了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及冷加工前后材料性能变化的关联分析，需要理解并应用相关公式来推导变形前的半径，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解冷加工对材料性能的影响，掌握延展性(%EL)与变形前后尺寸的关系，并进行多步计算推导原始尺寸。虽然题目提供了正确选项减少了计算量，但仍需综合分析材料科学原理和数学关系才能正确解答。" + }, + { + "idx": 4289, + "question": "Explain the differences in grain structure for a metal that has been cold worked and one that has been cold worked and then recrystallized.", + "answer": "During cold-working, the grain structure of the metal has been distorted to accommodate the deformation. Recrystallization produces grains that are equiaxed and smaller than the parent grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷加工和再结晶后金属晶粒结构的差异，答案需要文字解释和论述，没有提供选项或要求计算。 | 知识层次: 题目要求解释冷加工和再结晶对金属晶粒结构的影响，涉及多个概念（冷加工变形、再结晶过程、晶粒形态变化）的关联和综合分析，需要理解变形机制和再结晶原理，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解冷加工和再结晶对金属晶粒结构的影响，并进行比较分析。题目要求考生综合应用材料科学知识，比较两种不同处理方式下的晶粒结构变化，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4290, + "question": "What is the magnitude of the maximum stress that exists at the tip of an internal crack having a radius of curvature of 2.5 × 10^{-4} mm\\left(10^{-5} in.\\right) and a crack length of 2.5 × 10^{-2} mm\\left(10^{-3} in.\\right) when a tensile stress of 170 MPa(25,000 psi) is applied?", + "answer": "the magnitude of the maximum stress at the tip of the internal crack is 2404 \\text{ mpa} (354,000 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定最大应力的数值，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及应力集中公式的应用和单位转换，需要理解裂纹尖端应力集中的基本原理，并能够正确应用公式进行计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解应力集中概念并进行多步计算。题目涉及裂纹尖端应力集中公式的应用（σ_m=2σ_0√(a/ρ)），需要正确代入半径和长度参数，并进行单位换算和开方运算。虽然计算步骤明确，但涉及多个变量的处理和MPa与psi单位的转换，对概念理解和计算准确性要求较高。" + }, + { + "idx": 4291, + "question": "Estimate the theoretical fracture strength of a brittle material if it is known that fracture occurs by the propagation of an elliptically shaped surface crack of length 0.25 mm(0.01 in.) and having a tip radius of curvature of 1.2 × 10^{-3} mm\\left(4.7 × 10^{-5} in\\right..) when a stress of 1200 MPa(174,000 psi) is applied.", + "answer": "the theoretical fracture strength is 3.5 × 10^{4} MPa (5.1 × 10^{6} psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计脆性材料的理论断裂强度，答案是一个具体的数值结果，解答过程需要运用相关公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及断裂力学中的应力集中公式应用，需要理解裂纹几何参数与应力强度之间的关系，并进行数值计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解断裂力学的基本概念（如应力集中因子、裂纹尖端半径的影响），并应用相关公式进行多步计算。题目涉及单位转换和复杂数学运算，但作为选择题，正确选项的存在降低了部分难度，因为不需要完全推导过程。" + }, + { + "idx": 4292, + "question": "If the specific surface energy for soda-lime glass is 0.30 J/ m^{2}, using data contained in Table 12.5, compute the critical stress required for the propagation of a surface crack of length 0.05 mm.", + "answer": "the critical stress required for the propagation of a surface crack of length 0.05 mm is 16.2 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的数据和公式（特定表面能和裂纹长度）进行数值计算，以得出临界应力值。答案是一个具体的数值结果（16.2 MPa），这表明解答过程涉及计算步骤和公式应用。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需套用临界应力公式进行计算。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅需直接套用临界应力公式（σ_c = √(2Eγ_s/πa)），代入给定的比表面能（0.30 J/m²）和裂纹长度（0.05 mm）即可完成计算。所有参数均已明确给出，无需任何概念转换或多步骤推导，完全符合\"单一公式直接计算\"的特征。" + }, + { + "idx": 4293, + "question": "A polystyrene component must not fail when a tensile stress of 1.25 MPa(180 psi) is applied. Determine the maximum allowable surface crack length if the surface energy of polystyrene is 0.50 J/ m^{2}\\left(2.86 × 10^{-3}\\right. in.-\\left.lb_{\\mathrm{f}} / in^{2}\\right). Assume a modulus of elasticity of 3.0 \\mathrm{GPa}\\left(0.435 × 10^{6} psi\\right).", + "answer": "the maximum allowable surface crack length is 6.1 × 10^{-4} \\, m (0.61mm or 0.024 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如断裂力学公式）来确定最大允许表面裂纹长度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及表面能、弹性模量和应力等概念的关联应用，需要综合分析裂纹长度与材料性能之间的关系，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要综合运用断裂力学公式（如Griffith裂纹理论）进行多步计算，涉及应力、表面能、弹性模量等概念的关联分析，并正确转换单位。虽然题目提供了正确选项，但解题过程需要较强的概念理解和计算能力。" + }, + { + "idx": 4294, + "question": "A specimen of a 4340 steel alloy having a plane strain fracture toughness of 45 MPa \\sqrt{m}(41 ksi \\sqrt{in}.) is exposed to a stress of 1000 MPa(145,000 psi). Will this specimen experience fracture if it is known that the largest surface crack is 0.75 mm(0.03 in.) long? Why or why not? Assume that the parameter Y has a value of 1.0 .", + "answer": "the specimen will experience fracture because it can only tolerate a stress of 927 \\text{mpa} (133,500 \\text{psi}) before fracture, which is less than the applied stress of 1000 \\text{mpa} (145,000 \\text{psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算，应用断裂韧性公式来判断是否会发生断裂。答案中给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（应用断裂韧性公式计算临界应力），并需要将计算结果与给定应力进行比较以判断是否会发生断裂。虽然公式直接给出，但需要理解公式中各参数的含义并进行正确代入和计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解断裂韧性和应力强度的概念，进行多步计算（包括单位转换和公式应用），并综合分析计算结果与给定条件的对比。虽然题目提供了关键参数，但解题过程涉及多个知识点的关联应用和判断。" + }, + { + "idx": 4295, + "question": "Some aircraft component is fabricated from an aluminum alloy that has a plane strain fracture toughness of 35 MPa \\sqrt{m} (31.9 ksi \\sqrt{m}. It has been determined that fracture results at a stress of 250 MPa (36,250 psi) when the maximum (or critical) internal crack length is 2.0 mm(0.08 in.). For this same component and alloy, will fracture occur at a stress level of 325 MPa(47,125 psi) when the maximum internal crack length is 1.0 mm(0.04 in).? Why or why not?", + "answer": "fracture will not occur since the value 32.2 MPa \\sqrt{m} is less than the fracture toughness k_{ic} of the material, 35 MPa \\sqrt{m}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来解决问题，涉及应力、裂纹长度和断裂韧性的计算，最终需要比较计算结果与材料的断裂韧性来判断是否会发生断裂。答案给出了具体的计算结果和比较结论。 | 知识层次: 题目需要应用断裂力学中的临界应力强度因子公式进行多步计算，涉及应力、裂纹长度和材料断裂韧性之间的关联分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握平面应变断裂韧性的概念，并能应用断裂力学公式进行多步计算。虽然题目提供了部分已知条件，但仍需要考生正确选择和应用公式（如K=σ√(πa)），进行临界条件的比较判断。此外，题目还涉及单位转换和综合分析能力，但选择题型降低了部分计算复杂度，因此属于等级3的综合性计算问题。" + }, + { + "idx": 4296, + "question": "Suppose that a wing component on an aircraft is fabricated from an aluminum alloy that has a plane strain fracture toughness of 40 MPa \\sqrt{m} (36.4 k \\left.\\mathrm{si} \\sqrt{m}\\right). It has been determined that fracture results at a stress of 365 MPa(53,000 psi) when the maximum internal crack length is 2.5 mm(0.10 in.). For this same component and alloy, compute the stress level at which fracture will occur for a critical internal crack length of 4.0 mm(0.16 in.).", + "answer": "the stress level at which fracture will occur for a critical internal crack length of 4.0mm is 288 MPa (41,500 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解应力水平，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及平面应变断裂韧性和应力强度因子的概念关联，需要综合分析裂纹长度和应力水平的关系。虽然计算过程较为直接，但需要理解并应用相关公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解断裂力学中的平面应变断裂韧性概念，并应用应力强度因子公式进行多步计算。题目要求考生能够将给定的断裂参数（K_IC、应力、裂纹长度）关联起来，并通过公式推导出新的应力水平。虽然选项已经给出正确答案，但考生仍需具备综合分析能力才能验证选项的正确性，这比单纯记忆或简单计算更复杂。" + }, + { + "idx": 4297, + "question": "A large plate is fabricated from a steel alloy that has a plane strain fracture toughness of 55 MPa \\sqrt{m}(50 ksi \\sqrt{in}.). If, during service use, the plate is exposed to a tensile stress of 200 MPa(29,000 psi), determine the minimum length of a surface crack that will lead to fracture. Assume a value of 1.0 for Y.", + "answer": "the minimum length of a surface crack that will lead to fracture is 0.024 \\, m (24 mm).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定表面裂纹的最小长度，答案是一个具体的数值结果（0.024 m），这表明解答过程涉及计算步骤。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及平面应变断裂韧性和应力强度因子的直接套用，思维过程较为直接，无需多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目要求直接应用平面应变断裂韧性公式（K_IC = Y * σ * sqrt(πa)）进行简单计算，仅需一步代数变形即可求解裂纹长度a。虽然涉及单位转换和公式理解，但步骤直接且无需多步推导或复杂分析。" + }, + { + "idx": 4298, + "question": "Calculate the maximum internal crack length allowable for a 7075-T651 aluminum alloy (Table 8.1) component that is loaded to a stress one half of its yield strength. Assume that the value of Y is 1.35 .", + "answer": "the maximum internal crack length allowable is 0.0033 \\, m (3.3 mm).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最大内部裂纹长度，答案是一个具体的数值结果（0.0033 m），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及材料力学性能参数的应用和公式推导（如断裂力学中的裂纹长度计算），需要理解材料性能参数的意义并正确应用公式，属于中等难度的应用题目。 | 难度: 在选择题中属于中等难度，需要理解断裂力学的基本概念（如应力强度因子、临界裂纹长度等），进行多步计算（包括查表获取材料参数、代入公式求解等），并综合分析应力与裂纹长度的关系。虽然题目提供了部分参数，但仍需考生具备一定的应用能力和计算技巧。" + }, + { + "idx": 4299, + "question": "A structural component in the form of a wide plate is to be fabricated from a steel alloy that has a plane strain fracture toughness of 77.0 MPa \\sqrt{m}(70.1 ksi \\sqrt{m}.) and a yield strength of 1400 MPa(205,000 psi). The flaw size resolution limit of the flaw detection apparatus is 4.0 mm(0.16 in.) If the design stress is one half of the yield strength and the value of Y is 1.0 , determine whether or not a critical flaw for this plate is subject to detection.", + "answer": "the critical flaw size a_c is 3.9 mm. therefore, the critical flaw is not subject to detection since it is less than the 4.0 mm resolution limit.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定临界缺陷尺寸是否可被检测到。答案给出了具体的计算结果（3.9 mm），并基于计算结果进行了判断。 | 知识层次: 题目需要进行多步计算（临界裂纹尺寸计算、设计应力计算），并需要将计算结果与检测设备的限制进行比较分析。虽然公式直接给出，但需要正确应用并理解各参数之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及平面应变断裂韧性、屈服强度、设计应力等多个材料科学概念，需要进行多步计算（包括临界裂纹尺寸的计算和与检测限度的比较）。虽然题目提供了正确选项，但解题过程需要综合应用多个知识点和公式推导，属于综合性计算问题。" + }, + { + "idx": 4300, + "question": "Cite five factors that may lead to scatter in fatigue life data.", + "answer": "Five factors that lead to scatter in fatigue life data are (1) specimen fabrication and surface preparation, (2) metallurgical variables, (3) specimen alignment in the test apparatus, (4) variation in mean stress, and (5) variation in test cycle frequency.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释导致疲劳寿命数据分散的五个因素，答案以文字形式详细说明各个因素，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对疲劳寿命数据分散性影响因素的基础概念记忆，属于列举和识记基本知识点的范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求列举五个可能导致疲劳寿命数据分散的因素，属于概念解释和描述的层次。虽然需要记忆多个因素，但不需要深入分析或比较复杂的理论体系，因此属于中等难度。" + }, + { + "idx": 4301, + "question": "Briefly explain the difference between fatigue striations and beachmarks in terms of size.", + "answer": "With regard to size, beachmarks are normally of macroscopic dimensions and may be observed with the naked eye; fatigue striations are of microscopic size and it is necessary to observe them using electron microscopy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释疲劳条纹和海滩标记在尺寸上的区别，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查疲劳条纹和海滩标记的基本定义和尺寸差异，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生能够区分疲劳条纹和海滩标记在尺寸上的差异，并理解观察它们所需的不同技术手段（肉眼观察与电子显微镜）。这需要考生不仅记住定义，还要能够进行简单的概念对比和解释，属于概念解释和描述的层次。" + }, + { + "idx": 4302, + "question": "Briefly explain the difference between fatigue striations and beachmarks in terms of origin.", + "answer": "With regard to origin, beachmarks result from interruptions in the stress cycles; each fatigue striation corresponds to the advance of a fatigue crack during a single load cycle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释疲劳条纹和海滩标记在起源上的区别，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查疲劳条纹和海滩标记的基本定义和起源，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目要求考生解释两个专业术语（疲劳条纹和海滩标记）在起源方面的区别。虽然涉及基础概念记忆，但需要考生对这两个术语的定义和形成机制有清晰的理解，并能进行简单的比较分析。这超出了单纯记忆定义的难度（等级1），但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 4303, + "question": "List four measures that may be taken to increase the resistance to fatigue of a metal alloy.", + "answer": "Four measures that may be taken to increase the fatigue resistance of a metal alloy are:\n(1) Polish the surface to remove stress amplification sites.\n(2) Reduce the number of internal defects (pores, etc.) by means of altering processing and fabrication techniques.\n(3) Modify the design to eliminate notches and sudden contour changes.\n(4) Harden the outer surface of the structure by case hardening (carburizing, nitriding) or shot peening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出四种提高金属合金疲劳抗力的措施，答案以文字解释和论述的形式给出，没有选项选择、对错判断或数值计算的需求。 | 知识层次: 题目要求列举提高金属合金疲劳抗力的措施，涉及多个知识点（表面处理、内部缺陷控制、设计修改和表面硬化）的综合应用，需要理解各措施的原理和关联性，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目要求列举四种提高金属合金抗疲劳性能的措施，涉及多个概念（如表面处理、内部缺陷控制、设计优化和表面硬化）的综合分析。虽然不需要深入的计算，但需要对材料科学中的疲劳机制和相关处理方法有一定的理解和关联能力。" + }, + { + "idx": 4304, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for nickel.", + "answer": "for ni: 418 degrees c (785 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对镍材料蠕变变形温度这一基本概念的记忆和理解，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆镍的蠕变变形重要温度这一具体数值，属于基础概念记忆层面的简单问题。不需要解释或分析，只需直接回忆知识点即可作答，因此属于最低难度等级。" + }, + { + "idx": 4305, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for copper.", + "answer": "for cu: 270 degrees c (518 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个简短的具体数值，属于简答题类型。 | 知识层次: 题目主要考查对铜材料蠕变温度这一特定数值的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用过程。 | 难度: 在选择题型中，此题仅需记忆铜的蠕变温度这一具体数值，属于基础概念记忆层面的简单问题。不需要解释或分析概念，只需准确回忆特定知识点即可作答。" + }, + { + "idx": 4306, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for iron.", + "answer": "for fe: 450 degrees c (845 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要从选项中选择，也不需要计算或判断对错，属于需要简短回答的简答题类型。 | 知识层次: 题目考查对铁材料蠕变变形温度这一基本概念的记忆，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆铁材料蠕变变形开始成为重要考虑因素的温度值（450°C），属于基础概念记忆层次。题目不涉及任何解释、分析或复杂概念体系的阐述，仅需直接回忆特定数值，因此在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4307, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for tungsten.", + "answer": "for w: 1200 degrees c (2190 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题的范畴。 | 知识层次: 题目考查对钨材料蠕变变形温度这一特定数值的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，此题仅需记忆钨的蠕变变形重要温度（1200°C）这一具体数值，属于基础概念记忆层面的简单问题。不需要概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4308, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for lead.", + "answer": "for pb: -33 degrees c (-27 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对铅材料蠕变温度这一特定数值的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆铅的蠕变温度这一具体数值，属于基础概念记忆范畴。题目不涉及概念解释或复杂分析，只需直接回忆知识点即可作答，因此属于最低难度等级。" + }, + { + "idx": 4309, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for aluminum.", + "answer": "for al: 100 degrees c (212 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个简短的具体数值，符合简答题的特征。 | 知识层次: 题目考查对铝材料蠕变变形温度的基本概念记忆，不需要复杂的应用或分析，只需记住特定温度值即可。 | 难度: 在选择题型中，该题目仅要求记忆铝的蠕变变形重要温度这一基础知识点，属于基本定义简答级别。不需要解释或分析，只需直接回忆具体数值即可作答。" + }, + { + "idx": 4310, + "question": "Cite three variables that determine the microstructure of an alloy.", + "answer": "Three variables that determine the microstructure of an alloy are (1) the alloying elements present, (2) the concentrations of these alloying elements, and (3) the heat treatment of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举三个决定合金微观结构的变量，答案以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目考查对合金微观结构决定因素的基础概念记忆，仅需列举三个变量，无需深入分析或综合应用。 | 难度: 在选择题型中，该题目要求考生回忆并列举三个决定合金微观结构的变量。虽然涉及多个概念（合金元素、浓度、热处理），但都属于基础概念记忆范畴，无需复杂分析或比较。解题步骤仅需直接回忆知识点，属于概念解释和描述级别，因此评定为等级2。" + }, + { + "idx": 4311, + "question": "What thermodynamic condition must be met for a state of equilibrium to exist?", + "answer": "In order for a system to exist in a state of equilibrium the free energy must be a minimum for some specified combination of temperature, pressure, and composition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释热力学条件，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对热力学平衡状态基本条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及热力学平衡的基本概念，但正确选项要求考生不仅要记住自由能的最小化条件，还需要理解这一条件与温度、压力和组成的关联。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。" + }, + { + "idx": 4312, + "question": "For alloys of two hypothetical metals A and B, there exist an α, A-rich phase and a β, B-rich phase. From the mass fractions of both phases for two different alloys provided in the table below, (which are at the same temperature), determine the composition of the phase boundary (or solubility limit) for the α phase at this temperature.", + "answer": "the composition of the phase boundary for the α phase is 90 wt% A-10 wt% B.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的质量分数数据计算相界（或溶解度极限）的组成，需要通过数值计算和公式应用来得出具体结果（90 wt% A-10 wt% B）。 | 知识层次: 题目需要应用杠杆法则（lever rule）进行多步计算，涉及相图的理解和相组成的分析，需要将给定的质量分数数据转化为相边界组成，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图的基本概念，能够根据质量分数计算相组成，并进行综合分析。题目涉及多步计算和概念关联，但选项已经给出了明确的答案，减少了部分复杂性。" + }, + { + "idx": 4314, + "question": "A hypothetical A-B alloy of composition 55 wt% B-45 wt% A at some temperature is found to consist of mass fractions of 0.5 for both \\alpha and \\beta phases. If the composition of the \\beta phase is 90 wt% \\mathrm{~B}-10 wt% \\mathrm{~A}, what is the composition of the \\alpha phase?", + "answer": "the composition of the \\alpha phase is 20 \\text{ wt}% \\text{ b- } 80 \\text{ wt}% \\text{ a}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解α相的组成，答案是一个具体的数值结果，而不是选择、判断或文字解释。 | 知识层次: 题目涉及多步计算和概念关联，需要应用杠杆定律（lever rule）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解杠杆定律的概念，并进行多步计算和综合分析。题目要求根据已知的质量分数和相组成，通过杠杆定律反推出另一相的组成，涉及多个变量的计算和概念关联。虽然题目提供了部分已知条件，但解题过程仍需要一定的逻辑推理和计算能力。" + }, + { + "idx": 4315, + "question": "For 11.20 kg of a magnesium-lead alloy of composition 30 wt% Pb-70 wt% Mg, is it possible, at equilibrium, to have α and Mg2Pb phases having respective masses of 7.39 kg and 3.81 kg?", + "answer": "yes, it is possible to have a 30 wt% pb-70 wt% mg alloy with masses of 7.39 kg and 3.81 kg for the α and mg2pb phases, respectively.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断在特定条件下是否可能达到某种相平衡状态，答案只需回答\"yes\"或\"no\"即可，属于典型的判断题形式。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相的质量分数计算和相平衡的判断，需要综合分析合金成分与相组成的关系。 | 难度: 在选择题型中，该题目属于较高难度，需要综合运用相图知识、质量平衡计算和相组成分析。解题过程涉及多步计算（如确定各相组成和验证质量平衡）以及概念关联（如理解α相和Mg2Pb相在相图中的位置）。虽然题目提供了正确选项，但学生仍需进行综合分析才能判断其正确性，这超出了简单的概念回忆或单步计算，属于中等应用层次的要求。" + }, + { + "idx": 4316, + "question": "What will be the approximate temperature of the alloy?", + "answer": "the approximate temperature of the alloy is 190 degrees c.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算或公式应用。答案是一个简短的陈述，符合简答题的特征。 | 知识层次: 题目要求根据已知信息直接给出合金的近似温度，属于基本信息的应用，不需要复杂的计算或深入的分析。 | 难度: 在选择题中属于简单难度，题目仅要求对合金温度进行近似判断，且正确选项直接给出了具体数值，无需复杂计算或深入分析。知识层次为简单应用，符合等级2的标准。" + }, + { + "idx": 4317, + "question": "Briefly describe the phenomenon of coring and why it occurs.", + "answer": "Coring is the phenomenon whereby concentration gradients exist across grains in polycrystalline alloys, with higher concentrations of the component having the lower melting temperature at the grain boundaries. It occurs, during solidification, as a consequence of cooling rates that are too rapid to allow for the maintenance of the equilibrium composition of the solid phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述\"coring\"现象及其原因，需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目考查对\"coring\"现象的基本定义和发生原因的理解，属于基础概念的记忆和解释，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生不仅记忆\"coring\"的基本定义，还需要理解其形成原因和机制。虽然不涉及多个概念的复杂比较，但需要解释现象背后的原理，属于概念解释和描述层次，比单纯的定义记忆要求更高。" + }, + { + "idx": 4318, + "question": "Cite one undesirable consequence of coring.", + "answer": "One undesirable consequence of a cored structure is that, upon heating, the grain boundary regions will melt first and at a temperature below the equilibrium phase boundary from the phase diagram; this melting results in a loss in mechanical integrity of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述一个不良后果，答案提供了详细的文字描述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释偏析现象的一个不良后果，涉及对相图的理解、晶界行为的分析以及机械性能变化的推理，需要综合运用多个知识点并进行机理层面的解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4319, + "question": "Briefly explain why, upon solidification, an alloy of eutectic composition forms a microstructure consisting of alternating layers of the two solid phases.", + "answer": "Upon solidification, an alloy of eutectic composition forms a microstructure consisting of alternating layers\nof the two solid phases because during the solidification atomic diffusion must occur, and with this layered configuration the diffusion path length for the atoms is a minimum.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释共晶合金凝固时形成交替层状微观结构的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释共晶合金凝固过程中微观结构形成的机理，涉及原子扩散和能量最小化原理的综合分析，需要深入理解相变过程和微观组织形成的原理，属于机理层面的解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅要理解合金凝固的基本原理，还需要掌握共晶成分合金的微观结构形成机理。正确选项涉及原子扩散路径最小化的概念，这需要考生将扩散理论与微观结构形成联系起来进行综合分析。这种题目在选择题中属于需要机理深度解释的类型，比单纯记忆概念或简单应用公式的题目难度更高。" + }, + { + "idx": 4320, + "question": "What is the difference between a phase and a microconstituent?", + "answer": "A \"phase\" is a homogeneous portion of the system having uniform physical and chemical characteristics, whereas a \"microconstituent\" is an identifiable element of the microstructure (that may consist of more than one phase).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念的区别，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对\"phase\"和\"microconstituent\"这两个基本概念的定义和区别的理解，属于材料科学中最基础的概念记忆和简单对比范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念的定义，但需要考生理解和区分\"phase\"和\"microconstituent\"这两个相关但不同的概念，并进行比较分析。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 4321, + "question": "Two intermetallic compounds, A B and A B_{2}, exist for elements A and B. If the compositions for A B and A B_{2} are 34.3 wt% \\mathrm{~A}-65.7 wt% \\mathrm{~B} and 20.7 wt% \\mathrm{~A}-79.3 wt% \\mathrm{~B}, respectively, and element A is potassium, identify element B.", + "answer": "element b is arsenic (as), with an atomic weight of 74.92 \\, \\text{g/mol} . the two intermetallic compounds are \\text{kas} and \\text{kas}_2 .", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过分析和计算识别元素B，并给出具体的答案（砷），这需要文字解释和论述，而不是简单的选择或判断。答案的形式也是文字描述，而非数值或选项。 | 知识层次: 题目需要将重量百分比转换为原子百分比，并利用原子量信息推断未知元素的原子量，涉及多步计算和概念关联。虽然不涉及复杂的推理分析或机理解释，但需要一定的综合分析能力来解决问题。 | 难度: 在选择题中属于较高难度，需要综合运用多个知识点并进行多步计算。题目要求识别元素B，涉及原子量计算和化学计量关系分析。解题步骤包括：1) 理解题目中给出的两种化合物的组成百分比；2) 利用元素A（钾）的已知原子量计算元素B的原子量；3) 通过计算结果匹配元素B的可能选项。此外，还需要对化学计量关系和元素周期表有一定的了解。这种综合分析能力和多步计算的要求使得该题目在选择题型中属于较高难度。" + }, + { + "idx": 4322, + "question": "What is the principal difference between congruent and incongruent phase transformations?", + "answer": "The principal difference between congruent and incongruent phase transformations is that for congruent no compositional changes occur with any of the phases that are involved in the transformation. For incongruent there will be compositional alterations of the phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两种相变的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对相变类型的基本概念记忆和理解，即区分共格和非共格相变的主要特征，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（定义和分类），但需要考生理解并区分两个相关但不同的概念（congruent和incongruent相变）。正确选项要求考生不仅记住定义，还需要能够解释两种相变的关键区别（成分变化与否）。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 4323, + "question": "Compute the mass fraction of α ferrite in pearlite.", + "answer": "the mass fraction of α ferrite in pearlite is 0.89.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算α铁素体在珠光体中的质量分数，需要应用相关公式和数值计算，答案以数值形式给出。 | 知识层次: 题目要求计算珠光体中α铁素体的质量分数，这涉及基本的相图知识和简单的公式应用（如杠杆定律），属于直接套用基本公式进行计算的问题，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用单一公式计算α铁素体在珠光体中的质量分数，无需复杂步骤或多公式组合。属于最基础的直接计算类型，符合等级1的难度标准。" + }, + { + "idx": 4324, + "question": "Compute the mass fraction of cementite in pearlite.", + "answer": "the mass fraction of cementite in pearlite is 0.11.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算渗碳体在珠光体中的质量分数），并且答案是一个具体的数值（0.11），这表明解答过程需要应用公式和计算步骤。 | 知识层次: 题目涉及基本公式应用和简单计算，直接套用相图或杠杆定律即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接应用基本公式进行单一计算，无需复杂步骤或多公式组合。题目明确给出了计算目标（水泥体在珠光体中的质量分数），且正确选项直接呈现了计算结果，属于最基础的公式应用层次。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4325, + "question": "What is the distinction between hypoeutectoid and hypereutectoid steels?", + "answer": "A \"hypoeutectoid\" steel has a carbon concentration less than the eutectoid; on the other hand, a \"hypereutectoid\" steel has a carbon content greater than the eutectoid.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释hypoeutectoid和hypereutectoid steels的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对hypoeutectoid和hypereutectoid steels的基本定义和分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生区分并比较两个相关但不同的术语（hypoeutectoid和hypereutectoid steels），并理解它们与碳浓度的关系。这比单纯记忆一个定义（等级1）要求更高，但不需要复杂的分析或阐述（等级3）。" + }, + { + "idx": 4326, + "question": "In a hypoeutectoid steel, both eutectoid and proeutectoid ferrite exist. Explain the difference between them. What will be the carbon concentration in each?", + "answer": "For a hypoeutectoid steel, the proeutectoid ferrite is a microconstituent that formed above the eutectoid temperature. The eutectoid ferrite is one of the constituents of pearlite that formed at a temperature below the eutectoid. The carbon concentration for both ferrites is 0.022 wt% C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种铁素体的区别以及各自的碳浓度，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要解释两种铁素体的形成条件和碳浓度，涉及相变温度的理解和相图知识的应用，属于中等应用层次。虽然碳浓度是固定的，但需要理解不同铁素体的形成机制和条件，属于概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求区分两种铁素体的形成条件及其碳浓度，涉及对共析钢微观组织的理解，但选项提供了明确的答案，减少了推理的复杂性。" + }, + { + "idx": 4327, + "question": "What is the carbon concentration of an iron-carbon alloy for which the fraction of total ferrite is 0.94 ?", + "answer": "the carbon concentration of the iron-carbon alloy is 0.42 \\text{ wt% c}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算铁碳合金的碳浓度，需要通过给定的铁素体分数（0.94）进行数值计算，并应用相关公式得出具体数值（0.42 wt% C）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图的相关知识，通过给定的铁素体分数来计算碳浓度，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用铁碳相图知识、杠杆定律计算以及相分数与成分的关系。解题步骤包括：1) 理解总铁素体分数含义；2) 确定相关相区；3) 应用杠杆定律建立方程；4) 解方程求碳浓度。虽然计算过程明确，但需要准确关联多个概念，且容易在相边界值判断上出错，属于典型的综合性计算问题。" + }, + { + "idx": 4328, + "question": "What is the proeutectoid phase for an iron-carbon alloy in which the mass fractions of total ferrite and total cementite are 0.92 and 0.08 , respectively? Why?", + "answer": "the proeutectoid phase is \\alpha ferrite because the alloy composition c_{0} is less than 0.76 wt% C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么在给定的铁碳合金中先共析相是α铁素体，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解铁碳合金相图的基本概念，并能够根据给定的质量分数计算合金成分，进而判断先共析相。这涉及到多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握铁碳合金中的先共析相概念，并能根据给定的质量分数计算合金成分，进而判断先共析相的类型。这需要考生具备一定的计算能力和对相图的理解，但题目提供了足够的信息来推导出正确答案，因此难度适中。" + }, + { + "idx": 4329, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). What is the proeutectoid phase?", + "answer": "the proeutectoid phase is fe3c.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定先共析相（proeutectoid phase），答案是一个具体的相名称（Fe3C），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目需要理解铁碳相图的基本原理，并能够根据给定的碳含量和冷却条件判断出先共析相。这涉及到对相图的分析和应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。该题目涉及的知识点包括相图分析、碳含量计算和相变过程判断，需要学生综合运用这些知识来解答。虽然题目给出了具体的碳含量和温度条件，但仍需进行多步计算和概念关联才能确定正确的先共析相。" + }, + { + "idx": 4330, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). How many kilograms each of total ferrite and cementite form?", + "answer": "the total ferrite formed is 0.83 kg, and the total cementite formed is 0.17 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定铁素体和渗碳体的质量，需要应用相图和相关公式进行计算，最终给出具体的数值结果。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算以确定不同相的含量。虽然涉及基础概念，但需要理解相变过程并运用杠杆定律进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、杠杆定律等概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及多个知识点的关联应用和较复杂的计算步骤，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 4331, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). How many kilograms each of pearlite and the proeutectoid phase form?", + "answer": "the pearlite formed is 0.93 kg, and the proeutectoid phase (cementite) formed is 0.07 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算以确定珠光体和先共析相的重量，答案提供了具体的计算结果（0.93 kg和0.07 kg），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、杠杆定律的应用，并进行综合分析以确定珠光体和先共析相的重量分数。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律应用以及多步计算过程。虽然题目提供了正确选项，但解题过程涉及：" + }, + { + "idx": 4332, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). What is the proeutectoid phase?", + "answer": "ferrite is the proeutectoid phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来确定proeutectoid phase，而不是从多个选项中选择、判断对错或进行数值计算。答案“ferrite is the proeutectoid phase”是一个简短的文字回答，符合简答题的特征。 | 知识层次: 题目需要应用铁碳相图的基本知识来确定先共析相，涉及简单的相图分析和成分判断，属于直接套用基础知识的简单应用。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需基本公式应用和简单计算，直接套用知识点即可得出正确答案。题目要求判断亚共析相，只需根据给定的碳含量（0.65 wt% C）和冷却温度（低于727°C）直接应用铁碳相图的基本知识即可确定先共析相为铁素体（ferrite），无需复杂分析或多步骤推理。" + }, + { + "idx": 4333, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). How many kilograms each of total ferrite and cementite form?", + "answer": "the total ferrite formed is 2.27 kg, and the total cementite formed is 0.23 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算铁素体和渗碳体的质量），需要应用相图和相关公式来求解，最终答案以具体数值形式呈现。 | 知识层次: 题目需要进行多步计算，涉及铁碳相图的应用和成分计算，需要将基础概念与公式应用结合起来，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、杠杆定律等核心概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及确定相组成、计算各相比例、转换质量分数等复杂步骤，属于综合性计算问题。" + }, + { + "idx": 4334, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). How many kilograms each of pearlite and the proeutectoid phase form?", + "answer": "the pearlite formed is 2.12 kg, and the proeutectoid ferrite formed is 0.38 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用材料科学中的相变知识，通过公式和计算得出具体的重量结果（2.12 kg和0.38 kg）。答案的形式是具体的数值，而不是选择、判断或文字解释。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、杠杆定律的应用，并进行综合分析以确定各相的比例和重量。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，如理解奥氏体冷却过程中的相变、计算珠光体和先共析相的比例等。虽然题目给出了正确选项，但学生仍需掌握相关概念和计算方法才能正确选择。" + }, + { + "idx": 4335, + "question": "Compute the mass fraction of proeutectoid ferrite that forms in an iron-carbon alloy containing 0.25 wt% C.", + "answer": "the mass fraction of proeutectoid ferrite is 0.69.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（使用铁碳相图和杠杆定律）来求解先共析铁素体的质量分数，答案是一个具体的数值计算结果（0.69），这符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图的基本知识，通过简单的公式计算质量分数，属于基本公式的直接应用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用铁碳相图的基本知识，但解题步骤较为直接，只需套用质量分数的计算公式即可得出结果。不需要复杂的推导或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 4336, + "question": "Compute the mass fraction of pearlite that forms in an iron-carbon alloy containing 0.25 wt% C.", + "answer": "the mass fraction of pearlite is 0.31.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解珠光体的质量分数，答案是一个具体的数值结果（0.31），这表明需要进行计算过程。 | 知识层次: 题目涉及基本的铁碳合金相图知识，需要应用杠杆定律进行简单的质量分数计算，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用杠杆法则（lever rule）这一单一公式进行计算，属于基本公式的直接套用。解题步骤简单，仅需代入给定数值即可得出结果，无需复杂的推理或多步骤计算。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4337, + "question": "The microstructure of an iron-carbon alloy consists of proeutectoid ferrite and pearlite; the mass fractions of these two microconstituents are 0.286 and 0.714 , respectively. Determine the concentration of carbon in this alloy.\n\\[\n\\text {", + "answer": "0.55% \\text{c}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定铁碳合金中的碳浓度，涉及质量分数和相图的应用，需要数值计算和公式推导。答案以具体数值形式给出。 | 知识层次: 题目需要应用铁碳相图的知识，通过多步计算来确定碳的浓度。涉及质量分数的计算和相图的理解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳合金相图、先共析铁素体和珠光体的概念，并进行多步计算。虽然题目给出了质量分数，但需要正确应用杠杆定律和相图知识来推导碳浓度，涉及多个知识点的综合应用。" + }, + { + "idx": 4338, + "question": "The mass fractions of total ferrite and total cementite in an iron-carbon alloy are 0.88 and 0.12 , respectively. Is this a hypoeutectoid or hypereutectoid alloy? Why?", + "answer": "the alloy is hypereutectoid since c_0 is greater than 0.76 \\, \\text{wt% c}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么该合金是过共析合金，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要学生理解铁碳合金相图的基本概念，并能根据给定的质量分数计算碳含量，进而判断合金类型。这涉及到多步推理和概念关联，但不需要复杂的综合分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解铁碳合金相图的基本概念，能够区分亚共析和过共析合金的特征，并进行简单的质量分数计算和比较。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了关键判断依据，降低了部分分析难度。" + }, + { + "idx": 4339, + "question": "The microstructure of an iron-carbon alloy consists of proeutectoid ferrite and pearlite; the mass fractions of these microconstituents are 0.20 and 0.80 , respectively. Determine the concentration of carbon in this alloy.", + "answer": "the concentration of carbon in this alloy is 0.61% \\text{c}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定铁碳合金中的碳浓度，涉及质量分数和微观结构的数值计算，答案以具体数值形式给出。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算和概念关联。首先需要理解先共析铁素体和珠光体的定义及其在相图中的位置，然后利用杠杆定律计算碳的浓度，涉及多个知识点的综合运用和中等难度的计算过程。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳合金相图、先共析铁素体和珠光体的概念，并进行多步计算（包括质量分数转换和相图定位）。虽然题目提供了关键参数，但解题过程需要综合应用相图知识和计算公式，属于典型的综合性计算问题。" + }, + { + "idx": 4340, + "question": "Consider 2.0 kg of a 99.6 wt % Fe-0.4 wt % C alloy that is cooled to a temperature just below the eutectoid. How many kilograms of proeutectoid ferrite form?", + "answer": "0.98 kg of proeutectoid ferrite forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定条件下形成的proeutectoid ferrite的质量。答案是一个具体的数值结果（0.98 kg），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及合金成分分析、相变温度判断以及质量分数的计算，需要综合理解和应用材料科学中的相变原理和杠杆法则。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、进行多步计算（包括成分转换和杠杆法则应用），并综合分析冷却过程中的相变行为。虽然题目给出了正确选项，但解题过程涉及多个知识点的综合运用和较复杂的计算步骤。" + }, + { + "idx": 4342, + "question": "Consider 2.0 kg of a 99.6 wt % Fe-0.4 wt % C alloy that is cooled to a temperature just below the eutectoid. How many kilograms of cementite form?", + "answer": "0.114 kg of cementite forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定条件下形成的碳化铁（cementite）的质量。答案给出了具体的计算结果（0.114 kg），这表明解答过程涉及到了材料科学中的相图分析和质量平衡计算。 | 知识层次: 题目需要进行多步计算，涉及合金成分分析、相图应用和相组成计算，需要综合运用材料科学中的相变知识和公式应用，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律应用以及多步计算过程。题目涉及合金成分分析、相变温度判断和定量计算，虽然选项已给出正确答案，但仍需综合运用多个知识点才能验证正确性。" + }, + { + "idx": 4343, + "question": "Compute the maximum mass fraction of proeutectoid cementite possible for a hypereutectoid ironcarbon alloy.", + "answer": "the maximum mass fraction of proeutectoid cementite possible for a hypereutectoid iron-carbon alloy is 0.232.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算过共析铁碳合金中可能的最大先共析渗碳体质量分数，需要通过数值计算和公式应用来得出具体数值结果0.232。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算来确定先共析渗碳体的最大质量分数。这涉及到理解相图中不同区域的组成和相变过程，以及如何应用杠杆定律进行计算。虽然不涉及复杂的机理分析或创新设计，但需要综合理解和应用多个概念。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、共析反应和杠杆定律等多个概念，并进行多步骤计算。虽然题目给出了正确选项，但解题过程涉及确定合金成分范围、计算共析点前后的相比例等综合分析步骤，比单纯记忆性选择题更复杂。" + }, + { + "idx": 4344, + "question": "Is it possible to have an iron-carbon alloy for which the mass fractions of total ferrite and proeutectoid cementite are 0.846 and 0.049 , respectively? Why or why not?", + "answer": "yes, it is possible to have an iron-carbon alloy with mass fractions of total ferrite w_{\\alpha}=0.846 and proeutectoid cementite w_{\\mathrm{fe}_{3} C^{\\prime}}=0.049. the alloy composition for both conditions is 1.05 wt% C. since the composition values are equal, such an alloy exists.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释是否可能拥有特定质量分数的铁碳合金，并说明原因。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算和综合分析，以确定合金成分是否满足给定的质量分数条件。这涉及到对相图的理解、质量分数的计算以及成分的验证，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算和概念关联。题目要求考生不仅理解铁碳合金中不同相的质量分数关系，还需要通过计算验证合金成分的一致性。这种综合分析能力在选择题中较为复杂，超出了简单的概念记忆或单一计算步骤的要求。" + }, + { + "idx": 4345, + "question": "Is it possible to have an iron-carbon alloy for which the mass fractions of total cementite and pearlite are 0.039 and 0.417 , respectively? Why or why not?", + "answer": "no, such an iron-carbon alloy is not possible because the required carbon compositions for the given mass fractions of total cementite (0.28 wt% C) and pearlite (0.33 wt% C) are different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么某种铁碳合金不可能存在，需要文字论述和解释，而不是简单的选择、判断或计算。答案也提供了详细的解释说明。 | 知识层次: 题目需要应用铁碳合金相图的知识，通过给定的质量分数计算碳含量，并进行比较分析。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生进行多步计算和概念关联，综合分析铁碳合金中碳含量与不同相（渗碳体和珠光体）质量分数之间的关系。题目不仅要求理解相图的基本概念，还需要能够应用杠杆定律进行具体计算，并比较不同相所需的碳含量是否一致。这种综合分析能力在选择题中属于较高难度，因此评为等级4。" + }, + { + "idx": 4346, + "question": "Compute the mass fraction of eutectoid ferrite in an iron-carbon alloy that contains 0.43 wt% C.", + "answer": "the mass fraction of eutectoid ferrite in the iron-carbon alloy is 0.493.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算共析铁素体的质量分数），答案是一个具体的数值结果（0.493），解答过程需要应用材料科学中的相图知识和计算公式。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算来确定共析铁素体的质量分数。这涉及到理解相图中不同区域的相组成，以及如何利用杠杆法则进行计算。虽然计算本身不复杂，但需要正确理解相图和相组成的概念，并进行适当的公式应用和数值计算。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、共析反应等概念，并进行多步计算。题目要求计算共析铁素体的质量分数，涉及相组成和杠杆定律的应用，属于综合性计算问题。虽然题目给出了正确选项，但解题过程需要较强的概念关联和综合分析能力。" + }, + { + "idx": 4347, + "question": "Is it possible to determine the composition of an iron-carbon alloy if the mass fraction of eutectoid cementite is 0.104?", + "answer": "yes, it is possible to determine the alloy composition, and there are two possible answers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释是否可能确定铁碳合金的成分，并说明存在两种可能的答案，这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的质量分数进行多步计算，并关联不同相的概念来确定合金成分。这涉及到对相图的理解和计算能力，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 4348, + "question": "What is the composition of the alloy if eutectoid cementite exists in addition to proeutectoid cementite?", + "answer": "the alloy composition is 1.11 wt% c.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金的组成情况，并给出了具体的成分数值，需要文字解释和论述来回答，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解共析渗碳体和先共析渗碳体的概念，并进行多步计算来确定合金成分。这涉及到相图的应用和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生掌握铁碳相图的基本概念，理解共析渗碳体和先共析渗碳体的形成条件，并能进行多步计算和综合分析。题目不仅要求考生识别合金成分，还需要将多个知识点关联起来，进行较为复杂的推理和计算。" + }, + { + "idx": 4349, + "question": "What is the composition of a hypoeutectoid alloy where all cementite is eutectoid cementite and the mass fraction of total cementite is 0.104?", + "answer": "the composition can be determined using the lever rule.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过杠杆定律计算亚共析合金的成分，需要数值计算和公式应用 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解杠杆定律的应用、共析渗碳体的概念，并进行多步计算和综合分析。虽然题目提供了正确选项的提示，但仍需考生具备扎实的基础知识和计算能力才能准确判断。" + }, + { + "idx": 4350, + "question": "Is it possible to determine the composition of an iron-carbon alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "yes, it is possible to determine the alloy composition; and, in fact, there are two possible answers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述如何根据给定的质量分数确定铁碳合金的组成，答案提供了文字解释和可能的两种情况，符合简答题的特征。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的共析铁素体质量分数来计算合金的组成。这涉及到多步计算和概念关联，需要理解共析反应和杠杆定律的应用，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用铁碳相图知识、杠杆定律计算以及理解共析反应的概念。题目要求考生通过给定的共析铁素体质量分数反推合金成分，涉及多步计算和综合分析，且需要意识到存在两种可能的成分解（亚共析钢和过共析钢）。这种需要逆向思维和双重解意识的题目在选择题型中属于较复杂的考查方式。" + }, + { + "idx": 4351, + "question": "What is the first possible composition of the alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "for the first case, the composition is c0 = 0.70 wt % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金的组成，涉及质量分数和成分的计算，答案给出了具体的数值结果（0.70 wt % c），表明需要通过计算得出答案。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、质量分数计算以及合金成分的确定，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解合金相图、质量分数计算和共析反应等概念，并进行多步计算和综合分析。题目要求根据给定的共析铁素体质量分数反推合金成分，涉及多个知识点的关联应用和计算步骤。" + }, + { + "idx": 4352, + "question": "What is the second possible composition of the alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "for the second case, the composition is c0 = 1.22 wt % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算合金的第二种可能组成，需要应用质量分数和相图知识进行数值计算。答案给出了具体的数值结果（1.22 wt % c），表明这是一个需要计算过程的问题。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、质量分数计算以及合金成分的确定，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及合金成分的计算，需要掌握质量分数和共析铁素体的概念，并进行多步计算。虽然题目给出了正确选项，但解题过程需要综合分析多个知识点，属于中等应用层次。" + }, + { + "idx": 4353, + "question": "What is the first stage involved in the formation of particles of a new phase? Briefly describe it.", + "answer": "The first stage is nucleation. The nucleation process involves the formation of normally very small particles of the new phase(s) which are stable and capable of continued growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述新相粒子形成的第一阶段，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即成核过程的定义和简要描述，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求考生回忆并复述新相粒子形成的第一阶段（成核）及其简要描述，不涉及复杂的概念体系或分析过程。正确选项直接提供了定义和基本描述，符合基础概念记忆的知识层次要求。" + }, + { + "idx": 4354, + "question": "What is the second stage involved in the formation of particles of a new phase? Briefly describe it.", + "answer": "The second stage is growth. The growth stage is simply the increase in size of the new phase particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述新相粒子形成的第二阶段，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对相变过程中第二阶段（growth）的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅知道第二阶段的名称（生长），还需要简要描述该阶段的特点（新相颗粒尺寸的增加）。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 4355, + "question": "If copper (which has a melting point of 1085^{\\circ} C ) homogeneously nucleates at 849^{\\circ} C, calculate the critical radius given values of -1.77 × 10^{9} J/ m^{3} and 0.200 J/ m^{2}, respectively, for the latent heat of fusion and the surface free energy.", + "answer": "1.30 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界半径，答案是一个具体的数值结果（1.30 nm），这符合计算题的特征。 | 知识层次: 题目需要应用临界半径计算公式，涉及多步计算和概念关联（如熔化热、表面自由能等），但不需要复杂的综合分析或推理。 | 难度: 在选择题中属于中等偏上难度，需要理解临界半径计算公式（涉及表面自由能、过冷度、潜热等概念），并进行多步单位换算和数值计算。虽然题目提供了所有必要参数，但需要正确应用公式并处理负号问题（-1.77×10^9 J/m³表示放热过程），最终得到纳米级结果。相比简单概念题或单步计算题更复杂，但比需要推导公式或处理多变量的题目更直接。" + }, + { + "idx": 4356, + "question": "The kinetics of the austenite-to-pearlite transformation obey the Avrami relationship. Using the fraction transformed-time data given here, determine the total time required for 95% of the austenite to transform to pearlite:\n\\begin{tabular}{cc}\n\\hline Fraction Transformed & Time (s) \\\\\n\\hline 0.2 & 12.6 \\\\\n0.8 & 28.2 \\\\\n\\hline\n\\end{tabular}", + "answer": "35.7(s)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的数据和Avrami关系式进行数值计算，以确定95%奥氏体转变为珠光体所需的总时间。答案是一个具体的数值（35.7秒），这表明解答过程涉及公式应用和计算步骤。 | 知识层次: 题目需要应用Avrami关系进行多步计算，涉及数据分析和公式推导，要求将给定的分数转换-时间数据关联起来，并通过计算确定总时间。这超出了简单应用的范围，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解Avrami动力学方程并应用给定的数据点进行多步计算。解题步骤包括：1) 根据给定的两个数据点建立方程组求解Avrami方程中的参数；2) 利用求解出的参数计算95%转变所需的时间。虽然题目提供了部分数据简化了计算，但仍需要综合运用数学和材料科学知识进行推导和计算。" + }, + { + "idx": 4357, + "question": "The fraction recrystallized-time data for the recrystallization at 600^{\\circ} C of a previously deformed steel are tabulated here. Assuming that the kinetics of this process obey the Avrami relationship, determine the fraction recrystallized after a total time of 22.8min.\n\\begin{tabular}{cc}\n\\hline \\begin{tabular}{c} \nFraction \\\\\nRecrystallized\n\\end{tabular} & Time (min) \\\\\n\\hline 0.20 & 13.1 \\\\\n0.70 & 29.1 \\\\\n\\hline\n\\end{tabular}", + "answer": "0.51", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和Avrami关系进行数值计算，以确定再结晶分数，答案是一个具体的数值（0.51），需要通过公式应用和计算得出。 | 知识层次: 题目需要应用Avrami关系式进行多步计算，涉及数据拟合和方程求解，需要理解动力学方程的应用和关联实验数据，属于中等复杂度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解Avrami动力学方程并应用对数变换进行多步计算。题目要求根据给定的数据点推导方程参数，再代入新时间点求解，涉及概念关联和综合分析能力。虽然计算步骤明确，但需要较强的数学推导和应用能力，属于综合性计算问题。" + }, + { + "idx": 4358, + "question": "In terms of heat treatment and the development of microstructure, what is one major limitation of the iron-iron carbide phase diagram related to nonequilibrium phases?", + "answer": "The nonequilibrium martensite does not appear on the diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铁-碳相图的一个主要局限性，并需要文字论述，答案也是以文字形式给出解释，符合简答题的特征 | 知识层次: 题目要求理解铁-碳相图的基本原理，并能够分析其在非平衡相变中的局限性，涉及概念关联和综合分析。虽然不涉及多步计算，但需要对相图和实际热处理过程的关系有较深入的理解。 | 难度: 在选择题中属于中等难度，需要理解铁-碳相图的基本概念，并能够关联非平衡相（如马氏体）的形成条件与相图的局限性。虽然不涉及多步计算，但需要对相图的应用范围和局限性有较深入的理解，并进行综合分析。" + }, + { + "idx": 4359, + "question": "In terms of heat treatment and the development of microstructure, what is one major limitation of the iron-iron carbide phase diagram related to time-temperature relationships?", + "answer": "The diagram provides no indication as to the time-temperature relationships for the formation of pearlite, bainite, and spheroidite, all of which are composed of the equilibrium ferrite and cementite phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铁-碳相图在热处理和微观结构发展中的一个主要局限性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析铁碳相图在热处理和显微组织发展中的局限性，涉及对相图的理解以及时间-温度关系的应用，需要将多个概念关联并进行综合分析。虽然不涉及复杂计算，但需要对相图的基本原理和实际应用有较深入的理解。 | 难度: 在选择题中属于中等难度，需要理解铁-碳相图的基本概念，并能够分析其局限性。题目要求考生将相图与实际热处理过程中的时间-温度关系联系起来，进行综合分析。虽然不需要多步计算，但需要对相图的应用和微观结构形成有较深入的理解。" + }, + { + "idx": 4360, + "question": "Briefly describe the phenomena of superheating and supercooling.", + "answer": "Superheating and supercooling correspond, respectively, to heating or cooling above or below a phase transition temperature without the occurrence of the transformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述过热和过冷现象，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对超热和过冷现象的基本定义和概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求记忆和复述基础概念的定义，属于最基本的知识点掌握要求。正确选项直接给出了超热和过冷的定义，没有涉及复杂的概念体系或需要分析比较的步骤，因此属于最低难度等级。" + }, + { + "idx": 4361, + "question": "Why do these phenomena occur?", + "answer": "These phenomena occur because right at the phase transition temperature, the driving force is not sufficient to cause the transformation to occur. The driving force is enhanced during superheating or supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释相变温度下驱动力不足导致的现象，并分析过热或过冷如何增强驱动力。这需要综合运用相变理论、热力学驱动力概念，并进行机理分析和推理，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于最高难度等级。正确选项不仅要求考生理解相变温度的基本概念，还需要掌握驱动力的作用机制以及过热/过冷对驱动力的增强效应。题目涉及复杂现象的全面分析，需要综合运用热力学和动力学知识进行机理深度解释。这种题目在选择题中属于对知识掌握深度和综合分析能力要求极高的类型，远超单纯记忆或简单应用层面。" + }, + { + "idx": 4362, + "question": "Briefly cite the differences between pearlite, bainite, and spheroidite relative to microstructure.", + "answer": "The microstructures of pearlite, bainite, and spheroidite all consist of α-ferrite and cementite phases. For pearlite, the two phases exist as layers which alternate with one another. Bainite consists of very fine and parallel needle-shaped particles of cementite that are surrounded an α-ferrite matrix. For spheroidite, the matrix is ferrite, and the cementite phase is in the shape of sphere-shaped particles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述珠光体、贝氏体和球化体在微观结构上的差异，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对珠光体、贝氏体和球化体微观结构差异的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及三种不同的微观结构描述，但每个结构的特征描述相对独立且明确，不需要复杂的推理或综合分析。主要考察的是对基础概念的记忆和简单对比能力，属于\"概念解释和描述\"层次。" + }, + { + "idx": 4363, + "question": "Briefly cite the differences between pearlite, bainite, and spheroidite relative to mechanical properties.", + "answer": "Bainite is harder and stronger than pearlite, which, in turn, is harder and stronger than spheroidite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释珠光体、贝氏体和球化体在机械性能上的差异，答案以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目要求比较三种不同显微组织（pearlite, bainite, spheroidite）的机械性能差异，需要理解这些组织的形成机制及其对性能的影响，并进行综合分析。这涉及多个概念的关联和比较，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念（珠光体、贝氏体、球化体）并进行比较分析，同时掌握它们之间的机械性能差异。虽然题目涉及多个概念，但在选择题型中通过选项可以辅助判断，降低了部分难度。" + }, + { + "idx": 4364, + "question": "What is the driving force for the formation of spheroidite?", + "answer": "The driving force for the formation of spheroidite is the net reduction in ferrite-cementite phase boundary area.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释spheroidite形成的驱动力，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对spheroidite形成驱动力的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并准确回忆spheroidite形成的驱动力，即铁素体-渗碳体相界面积的净减少。这比简单的定义记忆（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 4365, + "question": "Name the microstructural products of eutectoid iron-carbon alloy (0.76 wt% C) specimens that are first completely transformed to austenite, then cooled to room temperature at a rate of 200°C/s.", + "answer": "At a rate of 200°C/s, only martensite forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述特定条件下的微观结构产物，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目要求考生理解并应用铁碳合金相变的基本原理，根据冷却速率判断微观结构产物。这需要将相变动力学知识与具体冷却条件（200°C/s）相结合进行分析，属于中等应用层次。虽然不涉及复杂计算，但需要理解连续冷却转变图（CCT图）的概念，并能够将冷却速率与相变产物对应起来。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及铁碳合金的微观结构转变，需要掌握奥氏体转变和马氏体形成的条件，以及冷却速率对微观结构的影响。虽然题目给出了具体的冷却速率，但需要考生能够将这一信息与马氏体形成的条件联系起来，进行综合分析。" + }, + { + "idx": 4368, + "question": "What is one important difference between continuous cooling transformation diagrams for plain carbon and alloy steels regarding the presence of a bainite nose?", + "answer": "For an alloy steel, a bainite nose will be present, which nose will be absent for plain carbon alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释连续冷却转变图中普通碳钢和合金钢在贝氏体鼻部存在方面的重要差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种钢的连续冷却转变图特征，涉及对合金元素影响的理解和概念关联，需要中等程度的分析和应用能力。 | 难度: 在选择题中属于中等难度，需要理解连续冷却转变图的基本概念，并能区分普通碳钢和合金钢在贝氏体鼻部存在与否的关键差异。虽然题目涉及的知识点较为专业，但在选择题型中通过正确选项可以直接对比分析，无需进行多步计算或深度关联性分析。" + }, + { + "idx": 4369, + "question": "What is one important difference between continuous cooling transformation diagrams for plain carbon and alloy steels regarding the position of the pearlite-proeutectoid noses?", + "answer": "The pearlite-proeutectoid noses for plain carbon steel alloys are positioned at shorter times than for the alloy steels.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释连续冷却转变图中普通碳钢和合金钢在珠光体-先共析体鼻部位置的重要差异，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种不同钢种的连续冷却转变图中珠光体-先共析鼻的位置差异，需要理解并应用相关概念，涉及多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解连续冷却转变图的基本概念，并能比较分析普通碳钢和合金钢在珠光体-先共析体鼻部位置上的差异。虽然题目涉及多步计算和概念关联，但在选择题型中，通过正确选项可以直接判断答案，不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 4370, + "question": "Briefly explain why there is no bainite transformation region on the continuous cooling transformation diagram for an iron-carbon alloy of eutectoid composition.", + "answer": "There is no bainite transformation region on the continuous cooling transformation diagram for an ironcarbon alloy of eutectoid composition because by the time a cooling curve has passed into the bainite region, the entirety of the alloy specimen will have transformed to pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释为什么在共析成分的铁碳合金的连续冷却转变图中没有贝氏体转变区，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释为什么在共析成分的铁碳合金连续冷却转变图中没有贝氏体转变区，这需要综合运用相变动力学、冷却速率对组织转变的影响等知识，进行推理分析。不仅需要理解珠光体和贝氏体形成的条件，还需要分析连续冷却过程中不同冷却速率下组织转变的竞争关系，思维过程较为深入。 | 难度: 在选择题型中属于最高难度等级，因为该题目要求考生不仅理解连续冷却转变图的基本概念，还需要深入掌握珠光体和贝氏体转变的动力学原理。正确选项涉及对冷却曲线与相变区域关系的复杂分析，需要综合运用相变动力学知识进行推理判断。这种题目在选择题中属于需要全面分析复杂现象的题型，远超简单记忆或基础理解的要求。" + }, + { + "idx": 4371, + "question": "Name the microstructural products of 4340 alloy steel specimens that are first completely transformed to austenite, then cooled to room temperature at a rate of 10°C/s.", + "answer": "only martensite forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述4340合金钢在特定冷却条件下的微观结构产物，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求考生理解4340合金钢的微观结构转变过程，并应用连续冷却转变图（CCT图）的知识来判断在特定冷却速率（10°C/s）下形成的产物。这需要将多个概念（奥氏体化、冷却速率、马氏体转变）关联起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解4340合金钢的相变行为、冷却速率对微观结构的影响以及马氏体形成的条件。虽然题目给出了具体的冷却速率（10°C/s），但学生需要知道这一速率足以避免其他相（如珠光体或贝氏体）的形成，从而仅形成马氏体。这涉及多个概念的关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4375, + "question": "On the basis of diffusion considerations, explain why fine pearlite forms for the moderate cooling of austenite through the eutectoid temperature, whereas coarse pearlite is the product for relatively slow cooling rates.", + "answer": "For moderately rapid cooling, the time allowed for carbon diffusion is not as great as for slower cooling rates. Therefore, the diffusion distance is shorter, and thinner layers of ferrite and cementite form (i.e., fine pearlite forms).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于扩散理论解释不同冷却速率下珠光体形成的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于扩散理论解释不同冷却速率下珠光体形成的机理，涉及扩散距离与冷却速率的关系，以及珠光体微观结构的形成过程。这需要综合运用扩散原理、相变动力学和微观结构形成的知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4376, + "question": "Briefly explain why fine pearlite is harder and stronger than coarse pearlite, which in turn is harder and stronger than spheroidite.", + "answer": "The hardness and strength of iron-carbon alloys that have microstructures consisting of \\alpha-ferrite and cementite phases depend on the boundary area between the two phases. The greater this area, the harder and stronger the alloy inasmuch as (1) these boundaries impede the motion of dislocations, and (2) the cementite phase restricts the deformation of the ferrite phase in regions adjacent to the phase boundaries. Fine pearlite is harder and stronger than coarse pearlite because the alternating ferrite-cementite layers are thinner for fine, and therefore, there is more phase boundary area. The phase boundary area between the sphere-like cementite particles and the ferrite matrix is less in spheroidite than for the alternating layered microstructure found in coarse pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释为什么细珠光体比粗珠光体更硬更强，而粗珠光体又比球化体更硬更强。答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释不同微观结构（细珠光体、粗珠光体和球化体）对材料硬度和强度的影响机制，涉及相界面对位错运动的阻碍作用以及渗碳体相限制铁素体相变形的机理。这需要综合运用材料科学中的相变、位错理论和强化机制等知识，进行深入的推理和分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4377, + "question": "Cite two reasons why martensite is so hard and brittle.", + "answer": "Two reasons why martensite is so hard and brittle are: (1) there are relatively few operable slip systems for the body-centered tetragonal crystal structure, and (2) virtually all of the carbon is in solid solution, which produces a solid-solution hardening effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列举两个原因来解释马氏体硬而脆的特性，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目要求解释马氏体硬脆性的两个原因，涉及晶体结构（体心四方晶系）和固溶强化效应的综合分析，需要理解马氏体相变的机理及其对材料性能的影响，属于对材料科学原理的深入分析和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4378, + "question": "Rank the following iron-carbon alloys and associated microstructures from the highest to the lowest tensile strength:\n(a) 0.25 wt% C with spheroidite,\n(b) 0.25 wt% C with coarse pearlite,\n(c) 0.60 wt% C with fine pearlite, and\n(d) 0.60 wt% C with coarse pearlit.", + "answer": "(c)(d)(b)(a)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的铁碳合金和微观结构选项中进行排序，选择从最高到最低抗拉强度的正确顺序。答案给出了一个特定的排序选项，符合选择题的特征。 | 知识层次: 题目要求对不同铁碳合金及其显微组织进行排序，需要理解碳含量和显微组织对材料力学性能的影响，并进行综合分析。这涉及到多个知识点的关联和比较，属于中等应用层次。 | 难度: 该题目在选择题型中属于较高难度，需要综合运用多个材料科学概念（碳含量、显微组织类型、力学性能关系）并进行多步分析判断。具体表现为：" + }, + { + "idx": 4379, + "question": "Briefly explain why the hardness of tempered martensite diminishes with tempering time at constant temperature.", + "answer": "The hardness of tempered martensite diminishes with tempering time at constant temperature because the microstructure consists of small sphere-like particles of cementite embedded within a ferrite matrix. As tempering time increases, the cementite particles grow, which reduces the ferrite-cementite phase boundary area. Since these phase boundaries act as barriers to dislocation motion, the reduction in phase boundary area leads to a decrease in hardness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释一个现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释回火马氏体硬度随回火时间降低的微观机理，涉及相变、析出相长大、位错运动障碍等多重概念的综合分析和推理，需要深入理解材料微观结构与性能的关系。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解回火马氏体的微观结构变化（渗碳体颗粒在铁素体基体中的分布），还需要掌握相界面对位错运动的阻碍机制，并能分析时间变量对微观结构演化的影响。这需要考生具备将材料科学基础理论（相变、位错理论）与工程实践（回火工艺）相结合的复杂分析能力，属于典型的机理深度解释与复杂现象全面分析题型。" + }, + { + "idx": 4381, + "question": "Briefly describe the microstructural difference between spheroidite and tempered martensite.", + "answer": "Both tempered martensite and spheroidite have sphere-like cementite particles within a ferrite matrix; however, these particles are much larger for spheroidite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述两种微观结构的差异，答案以文字解释的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对spheroidite和tempered martensite两种微观结构的基本概念记忆和理解，仅需描述它们之间的主要区别，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生比较两种微观结构的差异，涉及基础概念记忆和简单对比分析。虽然需要理解两种结构的基本特征，但题目提供了明确的比较点（碳化物颗粒大小），降低了复杂度。属于概念解释和描述级别，比单纯的定义记忆稍难，但不需要复杂的概念体系阐述。" + }, + { + "idx": 4382, + "question": "Explain why tempered martensite is much harder and stronger.", + "answer": "Tempered martensite is harder and stronger inasmuch as there is much more ferrite-cementite phase boundary area for the smaller particles; thus, there is greater reinforcement of the ferrite phase, and more phase boundary barriers to dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体更硬更强，需要文字解释和论述，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释回火马氏体硬度与强度的机理，涉及相界面对位错运动的阻碍作用以及铁素体相的强化机制，需要综合运用材料科学中的相变、位错理论和强化机制等知识进行推理分析。 | 难度: 在选择题中属于最高难度等级，题目要求深入理解马氏体回火过程中的相变机理，并能分析相界面对位错运动的阻碍作用。正确选项涉及多尺度（相界面积、颗粒尺寸、强化机制）的综合分析，需要考生具备将微观结构特征与宏观力学性能关联的高级推理能力。这种复杂现象的全方位解释在选择题型中属于对知识深度和应用能力的最高要求。" + }, + { + "idx": 4383, + "question": "List the four classifications of steels.", + "answer": "Low Carbon Steels, Medium Carbon Steels, High Carbon Steels, High Alloy Steels (Stainless and Tool)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出钢材的四种分类，需要文字回答而非选择或判断 | 知识层次: 题目考查对钢材分类的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆和识别钢材的四种基本分类，属于基础概念记忆层次。题目仅涉及简单的分类列举，无需解释或比较分析，解题步骤简单直接，符合等级1的基本定义简答标准。" + }, + { + "idx": 4384, + "question": "For Low Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: nonresponsive to heat treatments; relatively soft and weak; machinable and weldable. Typical applications: automobile bodies, structural shapes, pipelines, buildings, bridges, and tin cans.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述低碳钢的性质和典型应用，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对低碳钢的基本性质和典型应用的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述低碳钢的性质和典型应用，但正确选项已经提供了明确的答案，学生只需识别和匹配这些信息。这需要学生对低碳钢的基本性质和应用有一定的记忆和理解，但不需要进行复杂的分析或推理。因此，难度等级为2，属于概念解释和描述的层次。" + }, + { + "idx": 4385, + "question": "For Medium Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: heat treatable, relatively large combinations of mechanical characteristics. Typical applications: railway wheels and tracks, gears, crankshafts, and machine parts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述中碳钢的性能和典型应用，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对中碳钢的基本性质和典型应用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述中碳钢的性质和典型应用，但正确选项已经提供了明确的答案，学生只需识别和记忆这些关键点即可。不需要复杂的分析或推理过程，但需要掌握相关的基础概念和分类知识。" + }, + { + "idx": 4386, + "question": "For High Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: hard, strong, and relatively brittle. Typical applications: chisels, hammers, knives, and hacksaw blades.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述高碳钢的性能和典型应用，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对高碳钢基本性质和典型应用的基础概念记忆，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述高碳钢的性质和典型应用，但正确选项已经提供了明确的答案，学生只需识别和匹配这些信息即可。这需要学生对高碳钢的基本性质和应用有一定的记忆和理解，但不需要复杂的分析或推理。因此，该题目属于等级2，即概念解释和描述的难度水平。" + }, + { + "idx": 4387, + "question": "For High Alloy Steels (Stainless and Tool), briefly describe the properties and typical applications.", + "answer": "Properties: hard and wear resistant; resistant to corrosion in a large variety of environments. Typical applications: cutting tools, drills, cutlery, food processing, and surgical tools.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述高合金钢（不锈钢和工具钢）的性能和典型应用，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对高合金钢（不锈钢和工具钢）的基本性质和典型应用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述高合金钢（不锈钢和工具钢）的性能和典型应用，但正确选项已经提供了明确的答案，包括性能（硬、耐磨、耐腐蚀）和典型应用（切削工具、钻头、餐具、食品加工和手术工具）。这需要考生对高合金钢的基本概念和常见应用有一定的记忆和理解，但不需要进行复杂的分析或比较。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 4388, + "question": "Cite three reasons why ferrous alloys are used so extensively.", + "answer": "Ferrous alloys are used extensively because: (1) Iron ores exist in abundant quantities. (2) Economical extraction, refining, and fabrication techniques are available. (3) The alloys may be tailored to have a wide range of properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举三个原因，并需要文字解释和论述，符合简答题的特征 | 知识层次: 题目要求列举铁合金广泛应用的三个原因，主要考查对铁合金基本特性的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举三个原因，但每个原因都是基础概念的记忆性知识，不需要复杂的分析或推理。学生只需回忆并识别铁合金广泛使用的基本原因，如铁矿石的丰富性、经济可行的提取和加工技术，以及合金性能的可调性。这些知识点属于基础概念记忆层次，但需要一定的知识整合能力来列举多个原因。" + }, + { + "idx": 4389, + "question": "Cite three characteristics of ferrous alloys that limit their utilization.", + "answer": "Disadvantages of ferrous alloys are: (1) They are susceptible to corrosion. (2) They have a relatively high density. (3) They have relatively low electrical conductivities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举铁基合金的三个限制其应用的特性，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对铁基合金基本特性的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目要求考生回忆并列举铁基合金的三个限制性特征，属于概念解释和描述层次。虽然需要记忆多个特点，但都属于基础概念记忆范畴，无需复杂分析或比较。" + }, + { + "idx": 4390, + "question": "What is the function of alloying elements in tool steels?", + "answer": "The alloying elements in tool steels (e.g., \\mathrm{Cr}, V, \\mathrm{W}, and Mo) combine with the carbon to form very hard and wear-resistant carbide compounds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释合金元素在工具钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查合金元素在工具钢中的基本功能，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解合金元素在工具钢中的作用机制，即与碳形成硬质碳化物。这比单纯记忆定义（等级1）要求更高的理解深度，但不需要复杂的分析或比较（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4391, + "question": "On the basis of microstructure, briefly explain why gray iron is brittle and weak in tension.", + "answer": "Gray iron is weak and brittle in tension because the tips of the graphite flakes act as points of stress concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释灰口铸铁在拉伸时脆性和强度低的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于微观结构解释灰口铸铁的脆性和抗拉强度弱的原因，涉及应力集中机理的分析和微观组织与宏观性能的关联，需要综合运用材料科学知识进行推理和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅要知道灰色铸铁在拉伸时表现脆弱的表面现象，还需要深入理解其微观结构（石墨片尖端）如何作为应力集中点导致材料性能下降的机理。这需要考生具备将微观结构与宏观性能联系起来的综合分析能力，以及对材料失效机理的深入理解。在选择题型中，这种需要结合多个知识点进行机理解释的题目属于较难的类型。" + }, + { + "idx": 4392, + "question": "Compare white and nodular cast irons with respect to composition and heat treatment.", + "answer": "White iron--2.5 to 4.0 wt% C and less than 1.0 wt% Si. No heat treatment; however, cooling is rapid during solidification. Nodular cast iron--2.5 to 4.0 wt% C, 1.0 to 3.0 wt% Si, and a small amount of Mg or Ce. A heat treatment at about 700°C may be necessary to produce a ferritic matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种铸铁的成分和热处理方式，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种铸铁的成分和热处理工艺，涉及多个知识点的关联和综合分析，需要理解不同成分对材料性能的影响以及热处理工艺的选择依据，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解并比较两种铸铁的成分和热处理工艺，涉及多个概念的综合分析。虽然题目提供了具体数据，但考生仍需掌握相关知识才能正确理解和比较这些信息。" + }, + { + "idx": 4393, + "question": "Compare white and nodular cast irons with respect to microstructure.", + "answer": "White iron--There are regions of cementite interspersed within pearlite. Nodular cast iron--Nodules of graphite are embedded in a ferrite or pearlite matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的微观结构，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对白口铸铁和球墨铸铁微观结构的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生对白口铸铁和球墨铸铁的微观结构进行对比描述。虽然涉及两个不同材料的微观结构特征，但每个特征的描述相对独立且明确（白口铸铁中的渗碳体与珠光体区域、球墨铸铁中的石墨球与铁素体/珠光体基体）。题目属于基础概念记忆层次，不需要复杂的推理或概念体系整合，但比单纯的定义复述（等级1）要求稍高，属于概念解释和描述级别（等级2）。" + }, + { + "idx": 4394, + "question": "Compare white and nodular cast irons with respect to mechanical characteristics.", + "answer": "White iron--Extremely hard and brittle. Nodular cast iron--Moderate strength and ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的机械特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对白口铸铁和球墨铸铁机械性能的基本概念记忆和理解，属于基础概念对比，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两种铸铁材料的机械特性比较，但正确选项直接给出了明确的对比描述（白铸铁的硬脆性和球墨铸铁的中等强度与延展性），不需要复杂的推理或概念整合。这属于基础概念记忆层次，但需要考生能够区分和记忆两种材料的特性，属于概念解释和描述级别。" + }, + { + "idx": 4395, + "question": "Is it possible to produce malleable cast iron in pieces having large cross-sectional dimensions? Why or why not?", + "answer": "It is not possible to produce malleable iron in pieces having large cross-sectional dimensions. White cast iron is the precursor of malleable iron, and a rapid cooling rate is necessary for the formation of white iron, which may not be accomplished at interior regions of thick cross-sections.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么不能生产大截面尺寸的可锻铸铁，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解可锻铸铁的基本概念，还需要分析其生产过程中的冷却速率对材料性能的影响，以及截面尺寸对冷却速率的限制作用。这涉及到多个概念的关联和综合运用，以及对材料加工条件的深入理解。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4396, + "question": "What is the principal difference between wrought and cast alloys?", + "answer": "The principal difference between wrought and cast alloys is as follows: wrought alloys are ductile enough so as to be hot or cold worked during fabrication, whereas cast alloys are brittle to the degree that shaping by deformation is not possible and they must be fabricated by casting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述锻造合金和铸造合金的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对锻造合金和铸造合金基本概念的记忆和理解，属于定义和分类的基础知识范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（定义和分类），但需要考生理解并区分两种合金类型的关键特性（可锻性和铸造性）。正确选项提供了明确的对比描述，但需要考生掌握\"wrought\"和\"cast\"这两个专业术语的含义以及它们在加工性能上的差异。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 4397, + "question": "Why must rivets of a 2017 aluminum alloy be refrigerated before they are used?", + "answer": "Rivets of a 2017 aluminum alloy must be refrigerated before they are used because, after being solution heat treated, they precipitation harden at room temperature. Once precipitation hardened, they are too strong and brittle to be driven.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么2017铝合金铆钉在使用前必须冷藏，答案需要提供详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目不仅需要理解2017铝合金铆钉的热处理过程，还需要分析其在室温下的时效硬化行为及其对机械性能的影响。这涉及到材料科学中的相变、强化机制以及工艺控制等多个知识点的综合运用和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4398, + "question": "What is the chief difference between heat-treatable and non-heat-treatable alloys?", + "answer": "The chief difference between heat-treatable and nonheat-treatable alloys is that heat-treatable alloys may be strengthened by a heat treatment wherein a precipitate phase is formed (precipitation hardening) or a martensitic transformation occurs. Nonheat-treatable alloys are not amenable to strengthening by such treatments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两种合金的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对热可处理合金和非热可处理合金之间主要区别的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分两种合金的主要差异，包括热处理可强化合金的两种机制（沉淀硬化和马氏体转变）以及非热处理可强化合金的特性。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 4399, + "question": "Cite advantages of cold working.", + "answer": "The advantages of cold working are: (1) A high quality surface finish. (2) The mechanical properties may be varied. (3) Close dimensional tolerances.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举冷加工的优点，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对冷加工优点的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生回忆并列举冷加工的多个优点，涉及基础概念的记忆和简单描述。虽然需要掌握多个知识点，但不需要深入分析或复杂推理，属于概念解释和描述的难度层次。" + }, + { + "idx": 4400, + "question": "Cite disadvantages of cold working.", + "answer": "The disadvantages of cold working are: (1) High deformation energy requirements. (2) Large deformations must be accomplished in steps, which may be expensive. (3) A loss of ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举冷加工的缺点，答案以文字解释和论述的形式呈现，没有提供选项或需要计算，符合简答题的特征。 | 知识层次: 题目考查对冷加工缺点的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举冷加工的缺点，但选项已经提供了明确的答案，不需要考生自行回忆或组织语言。考生只需识别和选择正确的选项即可。然而，题目涉及的知识点需要考生对冷加工的基本概念和特性有一定的理解和记忆，属于概念解释和描述的层次，因此难度等级为2。" + }, + { + "idx": 4401, + "question": "Cite advantages of hot working.", + "answer": "The advantages of hot working are: (1) Large deformations are possible, which may be repeated. (2) Deformation energy requirements are relatively low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举热加工的优点，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对热加工优势的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和描述热加工的两个具体优势，而不是简单地回忆单一的定义或分类。这要求考生对热加工的基本原理有一定的理解和记忆，能够准确描述其优势。因此，相较于仅需回忆基本定义的等级1题目，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4402, + "question": "Cite disadvantages of hot working.", + "answer": "The disadvantages of hot working are: (1) A poor surface finish. (2) A variety of mechanical properties is not possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举热加工的缺点，答案以文字解释和论述的形式给出，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查对热加工缺点的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举热加工的缺点，但只需要记忆两个具体的缺点（表面光洁度差和机械性能多样性受限），不需要进行复杂的分析或比较。这属于基础概念记忆的范畴，但比简单的定义记忆稍微复杂一些，因为需要记住多个相关点。" + }, + { + "idx": 4403, + "question": "Cite advantages of forming metals by extrusion as opposed to rolling.", + "answer": "The advantages of extrusion as opposed to rolling are as follows: (1) Pieces having more complicated cross-sectional geometries may be formed. (2) Seamless tubing may be produced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举挤压成形相对于轧制的优点，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对金属挤压和轧制两种加工方法的基本概念记忆和理解，要求列举挤压相对于轧制的优势，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和比较两种金属成型工艺（挤压和轧制）的具体优势。正确选项中列举了两点明确的优势，这要求考生不仅记住这些知识点，还需要能够区分和对比两种工艺的特点。因此，相较于简单的定义记忆题（等级1），该题目需要更深一层的理解和应用（等级2）。" + }, + { + "idx": 4404, + "question": "Cite some disadvantages of forming metals by extrusion as opposed to rolling.", + "answer": "The disadvantages of extrusion over rolling are as follows: (1) Nonuniform deformation over the cross-section. (2) A variation in properties may result over a cross-section of an extruded piece.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举挤压成型相对于轧制成型的缺点，答案以文字解释和论述的形式给出，没有选项、判断对错或数值计算的要求。 | 知识层次: 题目考查对金属挤压和轧制两种成型方法的基本概念和特点的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生理解并记忆金属挤压和轧制两种工艺的基本概念及其优缺点。虽然需要比较两种工艺的差异，但题目仅要求列举挤压相对于轧制的缺点，属于概念解释和描述的层次，不需要复杂的分析或推理。因此，难度等级为2。" + }, + { + "idx": 4405, + "question": "List four situations in which casting is the preferred fabrication technique.", + "answer": "Four situations in which casting is the preferred fabrication technique are:\n(1) For large pieces and/or complicated shapes.\n(2) When mechanical strength is not an important consideration.\n(3) For alloys having low ductilities.\n(4) When it is the most economical fabrication technique.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举四种情况，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对铸造工艺适用场景的基础概念记忆，不需要复杂的分析或计算，仅需列举并简要说明铸造作为首选制造技术的四种情况。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举四种铸造作为首选制造技术的情况，但每个选项都是基于对铸造技术基本原理的理解和应用。这需要考生不仅记住铸造的基本定义，还要理解其在不同情境下的适用性。题目涉及的知识点较为基础，但需要一定的概念解释和描述能力，因此属于等级2。" + }, + { + "idx": 4406, + "question": "Compare sand casting technique", + "answer": "For sand casting, sand is the mold material, a two-piece mold is used, ordinarily the surface finish is not an important consideration, the sand may be reused (but the mold may not), casting rates are low, and large pieces are usually cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对砂型铸造技术进行比较和描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对砂型铸造技术的基本概念和特点的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于中等难度，题目要求比较砂型铸造技术的特点，涉及多个知识点的记忆和简单理解，但不需要复杂的分析或推理。正确选项列举了砂型铸造的几个关键特征，如模具材料、模具类型、表面处理、砂的重复使用、铸造速率和铸件尺寸等，这些都属于基础概念记忆的范畴，但需要考生对砂型铸造有较为全面的了解才能正确选择。" + }, + { + "idx": 4407, + "question": "Compare die casting technique", + "answer": "For die casting, a permanent mold is used, casting rates are high, the molten metal is forced into the mold under pressure, a two-piece mold is used, and small pieces are normally cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对压铸技术进行比较和描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对压铸技术的基本概念和特点的记忆和理解，如模具类型、铸造速率、压力注入等基础知识点，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个关于压铸技术的特点（如永久模具、高铸造速率、压力注入等），但这些都属于基础概念的记忆性知识，不需要复杂的分析或推理。正确选项整合了多个基本概念，但并未要求考生进行深层次的比较或应用，因此属于等级2的难度。" + }, + { + "idx": 4408, + "question": "Compare investment casting technique", + "answer": "For investment casting, a single-piece mold is used, which is not reusable; it results in high dimensional accuracy, good reproduction of detail, and a fine surface finish; and casting rates are low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较和描述投资铸造技术的特点，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对投资铸造技术的基本概念和特点的记忆和理解，如模具类型、尺寸精度、表面光洁度等，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生理解并描述投资铸造技术的多个特点（如模具类型、尺寸精度、细节再现、表面质量和铸造速率），而不仅仅是简单的定义记忆。这要求考生对概念有一定的理解和整合能力，但不需要进行复杂的比较分析或概念体系阐述。" + }, + { + "idx": 4409, + "question": "Compare lost foam casting technique", + "answer": "For lost foam casting, the pattern is polystyrene foam, whereas the mold material is sand. Complex geometries and tight tolerances are possible. Casting rates are higher than for investment, and there are few environmental wastes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对lost foam casting技术进行比较和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对消失模铸造技术的基本概念和特点的记忆和理解，包括材料选择、几何形状和公差、铸造速率以及环境影响等基础知识点，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个知识点（如泡沫材料、模具材料、几何复杂度等），但主要考察的是对消失模铸造技术基本概念的记忆和理解，而非复杂的分析或比较。正确选项提供了该技术的定义性特征和简单比较，符合\"概念解释和描述\"的难度等级。" + }, + { + "idx": 4410, + "question": "Compare continuous casting technique", + "answer": "For continuous casting, at the conclusion of the extraction process, the molten metal is cast into a continuous strand having either a rectangular or circular cross-section; these shapes are desirable for subsequent secondary metal-forming operations. The chemical composition and mechanical properties are relatively uniform throughout the cross-section.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对连续铸造技术进行比较和解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对连续铸造技术的基本概念和特点的记忆和理解，不涉及复杂分析或综合应用 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解连续铸造技术的基本概念和特点，包括其最终产品的形状（矩形或圆形截面）以及化学和机械性能的均匀性。虽然不需要复杂的分析或比较，但需要考生对连续铸造技术有一定的理解和记忆，能够准确描述其关键特征。这比简单的定义记忆（等级1）要复杂一些，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 4411, + "question": "Describe one problem that might exist with a steel weld that was cooled very rapidly.", + "answer": "If a steel weld is cooled very rapidly, martensite may form, which is very brittle. In some situations, cracks may form in the weld region as it cools.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述一个可能存在的问题，答案需要文字解释和论述，没有提供选项或要求判断对错，也不需要计算。 | 知识层次: 题目要求解释快速冷却对钢焊缝的影响，涉及马氏体形成及其脆性等概念，需要将材料科学中的相变理论与实际焊接问题关联起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解钢焊接快速冷却可能导致马氏体形成及其脆性特性，并关联到焊接区域可能产生裂纹的综合分析。题目涉及多步概念关联和综合分析，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4412, + "question": "Cite three sources of internal residual stresses in metal components.", + "answer": "Three sources of residual stresses in metal components are plastic deformation processes, nonuniform cooling of a piece that was cooled from an elevated temperature, and a phase transformation in which parent and product phases have different densities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举金属构件中内部残余应力的三个来源，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属构件内部残余应力来源的基本概念记忆和理解，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生列举金属构件内部残余应力的三个来源，属于概念解释和描述层次。虽然需要记忆多个知识点，但每个来源都是相对独立的基础概念，不需要进行复杂的比较分析或深入的概念体系阐述。相比等级1的基本定义简答，该题目对知识点的掌握深度要求略高，但仍属于中等难度范围。" + }, + { + "idx": 4413, + "question": "What are two possible adverse consequences of internal residual stresses in metal components?", + "answer": "Two adverse consequences of these stresses are distortion (or warpage) and fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举金属部件内部残余应力的两个不良后果，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对金属部件内部残余应力可能带来的不良后果的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆（内部残余应力的不良后果），但需要考生准确回忆并区分两种不同的不良后果（变形和断裂），这比单纯记忆单一概念的定义（等级1）要求更高。题目不涉及复杂概念体系或分析过程（等级3），但需要一定的概念理解和区分能力。" + }, + { + "idx": 4414, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.20 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 905°C (1660°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个数值，但解答过程需要基于材料科学知识（如铁碳相图）进行解释和推导，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要应用铁碳相图的基本知识来确定奥氏体化温度，属于直接套用相图信息的简单应用，不需要多步计算或复杂分析。 | 难度: 在选择题中属于简单应用难度，仅需直接套用铁碳相图中的基本知识（A3线）即可得出答案，无需复杂计算或深入分析。" + }, + { + "idx": 4415, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.76 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 782°C (1440°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要计算过程或选择选项，属于需要直接回答的简答题类型。 | 知识层次: 题目需要理解铁碳合金相图，并能够根据给定的碳含量（0.76 wt%）确定奥氏体化温度。这涉及到多步思维过程，包括相图的解读和具体温度点的确定，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，能够定位共析点（0.76 wt% C）对应的奥氏体化温度，并知道正常化处理需要略高于相变温度。虽然不需要复杂计算，但需要将多个概念关联起来进行综合分析。" + }, + { + "idx": 4416, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.95 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 840°C (1545°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或进行复杂的计算。虽然答案是一个数值，但解答过程需要基于材料科学知识（如铁碳相图）进行解释和判断，属于需要简要论述的简答题类型。 | 知识层次: 题目需要理解铁碳合金相图，并能够根据给定的碳含量（0.95 wt% C）确定奥氏体化温度。这涉及到多步分析和概念关联，包括相变温度和合金成分的关系，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，能够根据合金成分（0.95 wt% C）定位到共析点附近，并知道奥氏体化温度必须高于Acm线。虽然不需要复杂的计算，但需要将多个概念关联起来进行综合分析。" + }, + { + "idx": 4417, + "question": "Give the approximate temperature at which it is desirable to heat a 0.25 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 880°C (1510°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个具体的数值，但题目并未提供选项或要求进行计算，而是需要基于知识直接回答，类似于简答题的形式。 | 知识层次: 题目考查对铁碳合金热处理温度的直接应用，属于基本知识的简单应用，不需要复杂的计算或分析 | 难度: 在选择题型内，该题目属于简单应用层次，仅需要考生直接套用基本知识（铁碳相图中的A3线温度）即可得出答案，无需复杂计算或多步骤推理。题目考察的是对基础知识的直接回忆和应用能力，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 4418, + "question": "Give the approximate temperature at which it is desirable to heat a 0.45 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 830°C (1525°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个数值，但解答过程需要基于材料科学知识和对热处理工艺的理解，属于需要简要回答的问题类型。 | 知识层次: 题目考查对铁碳合金热处理温度的直接应用，需要记忆特定成分合金的退火温度，属于基本知识的直接应用，不涉及复杂计算或多概念关联。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需根据铁碳相图的基本知识直接套用0.45 wt% C对应的完全退火温度（A3线以上30-50°C），无需复杂计算或分析过程。题目考察的是对基础热处理参数的记忆和应用能力，属于选择题中较为基础的难度级别。" + }, + { + "idx": 4419, + "question": "Give the approximate temperature at which it is desirable to heat a 0.85 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 777°C (1430°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或进行复杂的计算。虽然答案是一个具体的数值，但题目本身没有提供选项或要求进行计算步骤，而是直接询问一个特定的知识点的具体数值，这更符合简答题的特征。 | 知识层次: 题目考查对铁碳合金相图中关键温度点的记忆，特别是全退火处理时的适宜温度，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆一个具体的温度数值（777°C），属于基础概念记忆层次。题目不涉及概念解释或复杂体系分析，仅需直接回忆教材或课程中给出的标准热处理温度，因此属于最低难度等级。" + }, + { + "idx": 4420, + "question": "Give the approximate temperature at which it is desirable to heat a 1.10 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 777°C (1430°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行复杂的计算。虽然答案是一个数值，但解答过程需要基于材料科学知识（铁碳相图和热处理知识）进行解释和判断，属于需要专业知识回答的简答题类型。 | 知识层次: 题目考查对铁碳合金全退火处理温度这一基本概念的记忆，属于基础概念记忆性知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目仅要求记忆铁碳合金在完全退火热处理时的近似加热温度，属于基础概念记忆性知识，无需复杂推理或分析。正确选项直接给出，解题步骤简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 4421, + "question": "What is the purpose of a spheroidizing heat treatment?", + "answer": "The purpose of a spheroidizing heat treatment is to produce a very soft and ductile steel alloy having a spheroiditic microstructure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释spheroidizing heat treatment的目的，答案是一个简短的文字解释，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对热处理工艺目的的基本概念记忆和理解，属于基础知识的直接问答，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对spheroidizing heat treatment基本定义和目的的简单记忆，属于最基础的概念性知识。正确选项直接给出了明确的定义和目的，不需要任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4422, + "question": "On what classes of alloys is a spheroidizing heat treatment normally used?", + "answer": "It is normally used on medium- and high-carbon steels, which, by virtue of carbon content, are relatively hard and strong.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释在哪些类型的合金上通常使用球化热处理，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对球化热处理应用对象的基础知识记忆，仅需回答特定类别合金的名称和基本特性，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对合金分类和热处理应用有较清晰的理解，能够将特定热处理工艺（球化退火）与适用的合金类别（中高碳钢）正确关联。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 4423, + "question": "Briefly explain the difference between hardness and hardenability.", + "answer": "Hardness is a measure of a material's resistance to localized surface deformation, whereas hardenability is a measure of the depth to which a ferrous alloy may be hardened by the formation of martensite. Hardenability is determined from hardness tests.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释两个概念的区别，答案是通过文字解释和论述来完成的，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查对硬度和淬透性这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生不仅记忆硬度（hardness）和硬化性（hardenability）的基本定义，还需要理解两者之间的区别和联系。虽然不涉及复杂的概念体系阐述，但需要考生对这两个概念有较为清晰的理解和比较能力，属于概念解释和描述的难度层次。" + }, + { + "idx": 4424, + "question": "What influence does the presence of alloying elements (other than carbon) have on the shape of a herdenability curve? Briefly explain this effect.", + "answer": "The presence of alloying elements (other than carbon) causes a much more gradual decrease in hardness with position from the quenched end for a hardenability curve. The reason for this effect is that alloying elements retard the formation of pearlitic and bainitic structures which are not as hard as martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释合金元素对淬透性曲线形状的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素对淬透性曲线形状的影响，并简要说明这种效应的原因。这需要综合运用材料科学中的相变理论、合金元素的作用机制以及淬透性曲线的理解，进行推理分析和机理解释。涉及的知识点较为复杂，且需要将多个概念关联起来进行综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4425, + "question": "Name two thermal properties of a liquid medium that will influence its quenching effectiveness.", + "answer": "The two thermal properties of a liquid medium that influence its quenching effectiveness are thermal conductivity and heat capacity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并解释液体介质的两个热性能，答案以文字解释的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对液体介质热性能的基本概念记忆，仅需列举影响淬火效果的两个热性能参数，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求回忆并列举两个基本的热性能属性（热导率和热容量），属于基础概念记忆层次。题目不涉及解释或比较，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4426, + "question": "For a ceramic compound, what are the two characteristics of the component ions that determine the crystal structure?", + "answer": "The two characteristics of component ions that determine the crystal structure of a ceramic compound are: 1) the magnitude of the electrical charge on each ion, and 2) the relative sizes of the cations and anions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述陶瓷化合物中决定晶体结构的两个离子特性，答案以文字形式详细说明了两点特征，符合简答题的特征。 | 知识层次: 题目考查的是陶瓷化合物晶体结构决定因素的基本概念记忆和理解，涉及离子电荷和相对尺寸这两个基本原理，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并记忆两个关键特征（离子电荷大小和离子相对尺寸），而不仅仅是单一的定义。这比仅回答一个基本定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 4427, + "question": "The zinc blende crystal structure is one that may be generated from close-packed planes of anions. Will the stacking sequence for this structure be FCC or HCP? Why?", + "answer": "The stacking sequence of close-packed planes of anions for the zinc blende crystal structure will be the same as FCC (and not HCP) because the anion packing is FCC.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释为什么锌闪锌矿结构的密排面堆垛序列是FCC而不是HCP，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解锌闪锌矿晶体结构的堆垛顺序，并关联到FCC和HCP两种密排结构的特点。虽然涉及基础概念，但需要综合分析两种结构的差异并给出合理解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解锌矿晶体结构、FCC和HCP堆积方式的概念，并能将阴离子的密堆积方式与晶体结构关联起来进行分析。虽然不需要多步计算，但需要对材料晶体学的基本概念有较好的掌握，并能进行综合比较。" + }, + { + "idx": 4428, + "question": "The zinc blende crystal structure is one that may be generated from close-packed planes of anions. Will cations fill tetrahedral or octahedral positions? Why?", + "answer": "The cations will fill tetrahedral positions since the coordination number for cations is four.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要解释为什么阳离子会填充四面体位置，而不是八面体位置，答案提供了详细的文字解释和论述。 | 知识层次: 题目考查对闪锌矿晶体结构中阳离子填充位置的基本概念记忆和理解，需要知道阳离子的配位数以及为什么选择四面体位置，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体结构的基本概念，但需要考生理解并记忆锌闪矿结构中阳离子的配位情况（四面体位置）及其原因（配位数为4）。这超出了简单的定义记忆，要求考生能够解释和描述基本原理，但不需要进行复杂的多概念比较或深入分析。" + }, + { + "idx": 4429, + "question": "The zinc blende crystal structure is one that may be generated from close-packed planes of anions. What fraction of the positions will be occupied?", + "answer": "Only one-half of the tetrahedral positions will be occupied because there are two tetrahedral sites per anion, and yet only one cation per anion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释锌闪矿晶体结构中位置的占据情况，答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解闪锌矿晶体结构的基本概念，并应用关于阴离子密堆积和四面体位置的知识进行综合分析。虽然不涉及复杂计算，但需要将多个概念关联起来，解释为什么只有一半的四面体位置被占据，这超出了简单记忆或直接套用的层次。 | 难度: 在选择题中属于中等难度，需要理解锌闪锌矿晶体结构的基本概念，并能够将紧密堆积的阴离子平面与四面体位置占据情况联系起来。题目要求考生不仅知道晶体结构的基本组成，还需要进行一步逻辑推理（两个四面体位置对应一个阴离子，而每个阴离子对应一个阳离子，因此只有一半位置被占据）。这涉及中等应用层次的知识，包括概念关联和简单计算，但不需要多角度或深度分析。" + }, + { + "idx": 4430, + "question": "Cadmium sulfide (CdS) has a cubic unit cell, and from x-ray diffraction data it is known that the cell edge length is 0.582nm. If the measured density is 4.82g / {cm}^{3}, how many \\mathrm{Cd}^{2+} and \\mathrm{S}^{2-} ions are there per unit cell?", + "answer": "there are four \\mathrm{cd}^{2+} and four s^{2-} ions per unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用（如密度公式、单位晶胞体积计算等）来确定单位晶胞中的离子数量，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括利用晶胞边长计算体积、密度公式的应用以及离子数量的推导，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的思维深度和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算和化学计量比等多个概念，并进行多步计算和综合分析。虽然题目提供了正确选项，但解题过程涉及单位转换、摩尔质量计算和离子数目的推导，步骤较为复杂。" + }, + { + "idx": 4431, + "question": "A hypothetical A X type of ceramic material is known to have a density of 2.65g / {cm}^{3} and a unit cell of cubic symmetry with a cell edge length of 0.43nm. The atomic weights of the A and X elements are 86.6 and 40.3g / mol, respectively. On the basis of this information, which of the following crystal structures is (are) possible for this material: rock salt, cesium chloride, or zinc blende? Justify your choice(s).", + "answer": "the only possible crystal structure for this material is cesium chloride, which has one formula unit per unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于给定的材料信息，分析并判断可能的晶体结构类型，并给出合理的解释。这需要文字解释和论述，而不是简单的选择或计算。 | 知识层次: 题目需要综合运用密度计算、晶体结构分析、单位晶胞内原子数计算等知识，进行多步推理和综合分析，以确定可能的晶体结构类型。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 4432, + "question": "In terms of bonding, explain why silicate materials have relatively low densities.", + "answer": "The silicate materials have relatively low densities because the atomic bonds are primarily covalent in nature, and, therefore, directional. This limits the packing efficiency of the atoms, and therefore, the magnitude of the density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来说明硅酸盐材料密度较低的原因，答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释硅酸盐材料密度较低的原因，涉及对共价键方向性及其对原子堆积效率影响的理解和分析。这需要将键合类型与材料性质关联起来，属于中等应用层次的知识运用。 | 难度: 在选择题中属于中等难度，需要理解硅酸盐材料的键合性质（共价键的方向性）及其对原子堆积效率的影响，并将这些概念关联起来解释密度较低的原因。虽然不涉及多步计算，但需要进行概念关联和综合分析。" + }, + { + "idx": 4433, + "question": "Would you expect Frenkel defects for anions to exist in ionic ceramics in relatively large concentrations? Why or why not?", + "answer": "Frenkel defects for anions would not exist in appreciable concentrations because the anion is quite large and is highly unlikely to exist as an interstitial.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Frenkel defects for anions在离子陶瓷中不会大量存在，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对Frenkel缺陷在离子陶瓷中的存在情况进行解释，涉及对离子尺寸和晶体结构缺陷的综合分析，需要理解缺陷形成的机理和影响因素，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解Frenkel缺陷的基本概念，还需要深入掌握离子陶瓷中阴离子的特性（如尺寸较大），并能够进行复杂的推理分析。正确选项涉及对材料微观结构和缺陷形成机理的全面理解，需要考生综合运用多个知识点（如离子半径、间隙位置、缺陷形成能等）才能得出正确结论。这种在选择题中要求机理深度解释和复杂现象全面分析的题目，对考生的知识掌握深度和综合分析能力提出了很高要求。" + }, + { + "idx": 4434, + "question": "Calculate the fraction of lattice sites that are Schottky defects for sodium chloride at its melting temperature \\left(801^{\\circ} C\\right). Assume an energy for defect formation of 2.3 \\mathrm{eV}.", + "answer": "the fraction of lattice sites that are schottky defects for sodium chloride at its melting temperature is 4.03 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Schottky缺陷的分数），并给出了具体的能量值和温度条件，答案也是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括温度转换、能量单位转换以及应用Schottky缺陷浓度公式。虽然计算过程较为直接，但需要理解缺陷形成能的概念以及公式中各参数的含义，并正确代入数值进行计算。这属于中等应用层次，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷的概念，掌握缺陷形成能的计算方法，并能正确应用Arrhenius公式进行多步骤计算。题目涉及温度单位转换、能量单位统一以及指数运算等综合计算过程，但选项已经给出了计算结果，减少了部分计算复杂度。" + }, + { + "idx": 4435, + "question": "(a) Suppose that Li2O is added as an impurity to CaO. If the Li+ substitutes for Ca2+, what kind of vacancies would you expect to form? How many of these vacancies are created for every Li+ added?", + "answer": "oxygen vacancies. Two Li+ ions added, a single oxygen vacancy is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释Li+取代Ca2+时形成的空位类型，并说明每添加一个Li+离子会形成多少个空位。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解离子替代对晶体缺陷的影响，并分析Li+替代Ca2+时电荷平衡的机制，涉及多步推理和概念关联。虽然不涉及复杂计算，但需要综合分析电荷补偿和缺陷形成的原理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及杂质掺杂和空位形成机制，要求考生掌握离子取代对晶体缺陷的影响，并能进行简单的电荷平衡计算。虽然解题步骤较为明确（Li+取代Ca2+会导致氧空位形成，且每两个Li+产生一个氧空位），但需要将晶体缺陷化学与电荷补偿原理结合起来分析，属于中等应用层次的知识运用。" + }, + { + "idx": 4436, + "question": "(b) Suppose that CaCl2 is added as an impurity to CaO. If the Cl substitutes for O2-, what kind of vacancies would you expect to form? How many of the vacancies are created for every Cl- added?", + "answer": "calcium vacancies. Two Cl- ions will lead to the formation of one calcium vacancy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述CaCl2作为杂质添加到CaO中时，Cl-取代O2-会形成何种空位以及每添加一个Cl-会形成多少个空位。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解杂质掺杂对晶体缺陷的影响，并分析Cl-取代O2-时电荷平衡的机制，涉及多步推理和概念关联。虽然不涉及复杂计算，但需要综合分析电荷补偿和缺陷形成的原理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及杂质掺杂和空位形成的机制，要求考生掌握离子替代对晶体缺陷的影响，并能进行简单的化学计量关系计算。虽然解题步骤相对明确，但需要将多个概念（如离子半径、电荷平衡、空位形成）关联起来综合分析，符合等级3的综合分析和说明要求。" + }, + { + "idx": 4437, + "question": "What point defects are possible for Al2O3 as an impurity in MgO?", + "answer": "For every Al3+ ion that substitutes for Mg2+ in MgO, a single positive charge is added. Thus, in order to maintain charge neutrality, either a positive charge must be removed or a negative charge must be added. Negative charges are added by forming O2- interstitials, which are not likely to form. Positive charges may be removed by forming Mg2+ vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al2O3作为杂质在MgO中可能形成的点缺陷类型，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要分析Al2O3作为杂质在MgO中可能形成的点缺陷，并解释电荷平衡机制。这涉及对点缺陷类型、电荷补偿机制的理解，以及综合分析不同缺陷形成的可能性（如O2-间隙与Mg2+空位的形成倾向）。需要较高的推理分析和机理解释能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解点缺陷的基本概念，还需要综合运用电荷平衡原理、晶体结构知识以及缺陷形成的能量学分析（如O2-间隙形成的不可能性）。正确选项涉及多步逻辑推理：从Al3+替代导致的电荷变化，到维持电中性的两种可能机制（阳离子空位或阴离子间隙），再到基于能量学排除其中一种机制。这种需要综合多个高阶概念并进行机理深度解释的题目，在选择题型中属于最复杂的分析层次。" + }, + { + "idx": 4438, + "question": "How many Al2+ ions must be added to form each of these defects?", + "answer": "One magnesium vacancy would be formed for every two Al3+ ions added.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释形成特定缺陷所需的离子数量关系，答案提供了文字解释而非数值计算或选择判断，符合简答题的特征。 | 知识层次: 题目需要理解缺陷形成的原理，并能够进行多步推理和计算，涉及离子替换和电荷平衡的概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解缺陷化学中的电荷补偿机制，并进行多步计算和概念关联。虽然题目给出了正确选项，但学生仍需掌握Al3+离子与镁空位之间的定量关系，并能综合分析电荷平衡问题。这超出了简单的记忆或单一概念应用，属于中等应用层次的要求。" + }, + { + "idx": 4439, + "question": "When kaolinite clay [Al2(Si2O5)(OH)4] is heated to a sufficiently high temperature, chemical water is driven off. Under these circumstances, what is the composition of the remaining product (in weight percent Al2O3)?", + "answer": "the composition of the remaining product is 45.9% Al2O3 by weight.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定剩余产物的组成（以Al2O3的重量百分比表示），需要应用化学计量和分子量计算等数值计算方法。答案是一个具体的数值结果（45.9%），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，包括化学式的摩尔质量计算、水的质量损失计算以及最终产物中Al2O3的质量百分比计算。这需要理解化学反应的基本原理，并能够将多个概念关联起来进行综合分析。虽然不涉及复杂的推理或机理解释，但超出了简单应用的范围。 | 难度: 在选择题中属于中等偏上难度，需要理解高岭石化学组成、加热脱水反应机理，并进行多步化学计量计算。题目要求考生将分子式转化为氧化物形式（Al2O3·2SiO2·2H2O），计算各组分分子量，最终推导出脱水产物的Al2O3质量百分比。虽然计算过程明确，但涉及化学概念转换和多个计算步骤，在选择题型中属于需要较强综合分析能力的题目。" + }, + { + "idx": 4440, + "question": "When kaolinite clay [Al2(Si2O5)(OH)4] is heated to a sufficiently high temperature, chemical water is driven off. What are the liquidus and solidus temperatures of this material?", + "answer": "the liquidus and solidus temperatures of this material are 1825 degrees C and 1587 degrees C, respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答具体的温度数值，但不需要进行计算或选择，而是直接提供答案。答案形式为简短的文字描述，符合简答题的特征。 | 知识层次: 题目考查对高岭石粘土加热过程中液线和固线温度的记忆，属于基础概念的记忆性知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅要求记忆特定的温度数值（1825°C和1587°C），属于基础概念记忆层次。不需要解释或分析过程，只需直接回忆知识点，因此难度最低。" + }, + { + "idx": 4441, + "question": "Why may there be significant scatter in the fracture strength for some given ceramic material?", + "answer": "There may be significant scatter in the fracture strength for some given ceramic material because the fracture strength depends on the probability of the existence of a flaw that is capable of initiating a crack; this probability varies from specimen to specimen of the same material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对陶瓷材料断裂强度存在显著分散性的原因进行文字解释和论述，答案提供了详细的解释而非选择、判断或计算。 | 知识层次: 题目要求解释陶瓷材料断裂强度存在显著分散性的原因，涉及对断裂机理的理解和分析。需要综合运用概率统计、缺陷分布和裂纹萌生等概念，进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解陶瓷材料断裂强度的基本概念，还需要深入分析断裂强度与缺陷概率之间的复杂关系，并能够解释不同样本间强度差异的机理。这需要综合运用材料科学知识、概率分析以及断裂力学原理，进行多层次的推理和解释。因此，该题目在选择题型内属于复杂现象全面分析的难度等级。" + }, + { + "idx": 4442, + "question": "Why does fracture strength increase with decreasing specimen size?", + "answer": "The fracture strength increases with decreasing specimen size because as specimen size decreases, the probability of the existence of a flaw that is capable of initiating a crack diminishes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行解释和论述，答案是一段文字解释，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释断裂强度随试样尺寸减小而增加的机理，涉及缺陷概率与裂纹萌生的关联分析，需要综合运用材料科学中的断裂力学原理进行推理和解释，思维过程具有较高的深度要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解断裂强度的基本概念，还需要掌握材料缺陷与尺寸效应的复杂关系。正确选项涉及概率性缺陷分布、裂纹萌生机理等深层次知识，需要综合运用材料科学原理进行推理分析。这种在选择题中要求解释复杂现象背后机理的题目，对考生的知识深度和逻辑思维能力都有很高要求，远超单纯记忆或简单应用类选择题的难度水平。" + }, + { + "idx": 4443, + "question": "The fracture strength of glass may be increased by etching away a thin surface layer. It is believed that the etching may alter surface crack geometry (i.e., reduce crack length and increase the tip radius). Compute the ratio of the original and etched crack tip radii for an eightfold increase in fracture strength if two-thirds of the crack length is removed.\n\\[\n\\text {", + "answer": "the ratio of the original and etched crack tip radii is 21.3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及计算裂纹尖端半径的比值，且答案以数值形式给出。 | 知识层次: 题目需要进行多步计算，涉及断裂强度的变化与裂纹几何参数的关系，需要应用格里菲斯断裂准则等概念，并进行数值计算和公式应用。虽然不涉及复杂的推理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解断裂强度的概念、裂纹几何形状的影响，并进行多步计算。题目要求计算原始和蚀刻后裂纹尖端半径的比值，涉及断裂力学的基本原理和公式应用。虽然题目提供了部分参数，但仍需要综合分析和计算才能得出正确结果。" + }, + { + "idx": 4444, + "question": "A circular specimen of MgO is loaded using a three-point bending mode. Compute the minimum possible radius of the specimen without fracture, given that the applied load is 425N\\left(95.5 lb \\mathrm{b}_{1}\\right), the flexural strength is 105 MPa(15,000 psi), and the separation between load points is 50 mm(2.0 in).", + "answer": "the minimum possible radius of the specimen without fracture is 4.0mm (0.16 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小可能的半径，答案是一个具体的数值结果，解答过程需要运用材料力学中的三点弯曲公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及弯曲强度的概念和三点弯曲模式的公式应用，需要综合分析给定的参数并正确运用公式来求解最小半径。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，要求考生综合运用材料力学和强度计算的知识。虽然题目提供了所有必要参数，但需要正确应用三点弯曲公式并转换单位，属于综合性计算问题。" + }, + { + "idx": 4446, + "question": "Would you be 100% certain of the prediction in part (a)? Why or why not?", + "answer": "the certainty of this prediction is not 100% because there is always some variability in the flexural strength for ceramic materials. since the calculated stress 379 mpa is relatively close to the flexural strength 390 mpa, there is some chance that fracture will occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对预测的确定性进行解释和论述，答案提供了详细的文字解释，说明为什么预测不是100%确定，这符合简答题的特征。 | 知识层次: 题目要求对预测的确定性进行解释，涉及对材料性能变异性的理解，以及应力与强度接近时的概率分析，需要综合运用材料科学知识进行推理和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4447, + "question": "Cite one reason why ceramic materials are, in general, harder yet more brittle than metals.", + "answer": "Crystalline ceramics are harder yet more brittle than metals because they (ceramics) have fewer slip systems, and, therefore, dislocation motion is highly restricted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述陶瓷材料比金属更硬但更脆的原因，答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷材料比金属更硬但更脆的原因，涉及对材料微观结构（如滑移系统）和力学行为（如位错运动）之间关系的深入理解。这需要综合运用晶体结构、位错理论和材料力学性能的知识，进行机理层面的分析和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4448, + "question": "The modulus of elasticity for beryllium oxide (BeO) having 5 vol% porosity is 310 GPa (45 x 10^6 psi). Compute the modulus of elasticity for the nonporous material.", + "answer": "the modulus of elasticity for the nonporous material is 342 gpa (49.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（计算非多孔材料的弹性模量）来得出具体数值答案，答案也是以具体数值形式呈现。 | 知识层次: 题目需要应用基本公式（弹性模量与孔隙率的关系）进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算非多孔材料的弹性模量，只需直接应用孔隙率与弹性模量的关系公式（如E = E0(1 - 1.9P + 0.9P^2)），并进行简单的数值代入和计算。无需复杂的推理或多步骤分析，属于最基础的难度等级。" + }, + { + "idx": 4450, + "question": "The modulus of elasticity for boron carbide (B4C) having 5 vol% porosity is 290 GPa (42 x 10^6 psi). Compute the modulus of elasticity for the nonporous material.", + "answer": "320 GPa (46.3 x 10^6 psi)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔材料的弹性模量，答案也是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（弹性模量与孔隙率的关系）进行简单计算，属于直接套用公式的范畴，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算非多孔材料的弹性模量，只需简单应用孔隙率与弹性模量的关系公式（如经验公式或理论模型）进行一步计算即可得出答案。无需多个公式组合或复杂推导，属于基础知识的直接应用。" + }, + { + "idx": 4451, + "question": "The modulus of elasticity for boron carbide (B4C) having 5 vol% porosity is 290 GPa (42 x 10^6 psi). At what volume percent porosity will the modulus of elasticity be 235 GPa (34 x 10^6 psi)?", + "answer": "the modulus of elasticity will be 235 GPa (34 x 10^6 psi) at a porosity of 15.1 vol%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解孔隙率，答案是一个具体的数值结果（15.1 vol%），而不是选择、判断或文字解释。 | 知识层次: 题目需要应用弹性模量与孔隙率之间的关系公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性模量与孔隙率之间的关系，并应用相关公式进行多步计算。虽然题目提供了部分数据，但解题过程涉及综合分析和对概念的理解，需要一定的计算能力和材料科学知识。" + }, + { + "idx": 4452, + "question": "Cite the two desirable characteristics of glasses.", + "answer": "Two desirable characteristics of glasses are optical transparency and ease of fabrication.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举玻璃的两个理想特性，需要用文字进行简要回答，不需要计算或选择选项 | 知识层次: 题目考查对玻璃材料基本特性的记忆，仅需列举两个理想特性，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆并列举玻璃的两个理想特性（光学透明性和易于加工），属于基础概念记忆层次。题目仅涉及简单的定义性知识，无需解释或分析，解题步骤直接且简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 4453, + "question": "What is crystallization?", + "answer": "Crystallization is the process whereby a glass material is caused to transform to a crystalline solid, usually as a result of a heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"crystallization\"进行定义和解释，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查基本概念的记忆和理解，即结晶化的定义和基本原理，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别结晶化的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了结晶化的定义，不需要任何解释、分析或比较过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4454, + "question": "Cite two properties that may be improved by crystallization.", + "answer": "Two properties that may be improved by crystallization are (1) a lower coefficient of thermal expansion, and (2) higher strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两个可能通过结晶改善的性能，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对结晶化改善材料性能这一基本概念的简单列举和记忆，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆并列举两个可能通过结晶改善的性质。题目不涉及概念解释或复杂体系阐述，解题步骤简单直接，符合等级1的基本定义简答标准。" + }, + { + "idx": 4455, + "question": "For refractory ceramic materials, cite three characteristics that improve with increasing porosity.", + "answer": "For refractory ceramic materials, three characteristics that improve with increasing porosity are (1) decreased thermal expansion and contraction upon thermal cycling, (2) improved thermal insulation, and (3) improved resistance to thermal shock.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释三个特性，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对耐火陶瓷材料特性的基本记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举三个特性，但这些都是与多孔耐火陶瓷材料相关的基础概念，属于记忆性知识。考生需要理解并记住这些特性，但不需要进行复杂的分析或推理。因此，难度等级为2。" + }, + { + "idx": 4456, + "question": "For refractory ceramic materials, cite two characteristics that are adversely affected by increasing porosity.", + "answer": "For refractory ceramic materials, two characteristics that are adversely affected by increasing porosity are (1) load-bearing capacity and (2) resistance to attack by corrosive materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并简要说明两个特性，答案以文字解释的形式给出，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查对耐火陶瓷材料基本特性的记忆和理解，仅需列举两个受孔隙率增加负面影响的性质，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目要求列举两个受孔隙率增加不利影响的耐火陶瓷材料特性，这仅需要记忆基础概念和基本原理，无需深入解释或复杂分析。正确选项直接提供了两个明确的特性，符合选择题型中对基础概念记忆的要求。" + }, + { + "idx": 4457, + "question": "How do the aggregate particles become bonded together in clay-based mixtures during firing?", + "answer": "For clay-based aggregates, a liquid phase forms during firing, which infiltrates the pores between the unmelted particles; upon cooling, this liquid becomes a glass, that serves as the bonding phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释粘土基混合物在烧制过程中颗粒如何结合，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释粘土基混合物在烧制过程中颗粒如何结合，涉及液相形成、渗透和冷却过程中的玻璃化转变等复杂机理，需要综合运用材料科学知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4458, + "question": "How do the aggregate particles become bonded together in cements during setting?", + "answer": "With cements, the bonding process is a chemical, hydration reaction between the water that has been added and the various cement constituents. The cement particles are bonded together by reactions that occur at the particle surfaces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释水泥中骨料颗粒在凝固过程中如何结合，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查水泥凝固过程中颗粒结合的基本原理和化学反应，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆层次的知识，但需要考生理解并描述水泥凝固过程中颗粒间化学键合的具体机制，而不仅仅是简单的定义或分类。正确选项提供了较为详细的解释，涉及水化反应和颗粒表面反应等概念，因此难度高于仅需记忆基本定义的题目（等级1），但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 4459, + "question": "What is the glass transition temperature for a noncrystalline ceramic?", + "answer": "The glass transition temperature is, for a noncrystalline ceramic, that temperature at which there is a change of slope for the specific volume versus temperature curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释玻璃转变温度的定义，答案需要文字描述和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对玻璃转变温度这一基本概念的定义和记忆，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目仅考察对玻璃转变温度这一基础概念的记忆和理解，属于基本定义简答的范畴。题目要求识别非晶陶瓷的玻璃转变温度的定义，不需要进行复杂的概念比较或分析，因此难度较低。" + }, + { + "idx": 4460, + "question": "What is the melting temperature for a crystalline material?", + "answer": "The melting temperature is, for a crystalline material and upon cooling, that temperature at which there is a sudden and discontinuous decrease in the specific-volume-versus-temperature curve.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是结晶材料的熔化温度，答案提供了详细的文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对晶体材料熔点这一基本概念的定义和理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但正确选项的描述涉及对\"melting temperature\"这一概念的具体解释，需要考生理解并记忆特定温度下材料体积变化的特征。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 4461, + "question": "Compare the softening points for 96% silica, borosilicate, and soda-lime glasses.", + "answer": "The softening point of a glass is that temperature at which the viscosity is 4 × 10^{6} \\mathrm{~Pa}·s; from Figure 13.7, these temperatures for the 96% silica, borosilicate, and soda-lime glasses are 1540^{\\circ} C\\left(2800^{\\circ} F\\right), 830^{\\circ} C\\left(1525^{\\circ} F\\right), and 700^{\\circ} C\\left(1290^{\\circ} F\\right), respectively.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较不同玻璃的软化点，答案提供了详细的温度数据并解释了软化点的定义，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目主要考查对不同类型玻璃软化点的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个玻璃类型的软化点比较，但正确选项直接提供了具体数值和来源（Figure 13.7），不需要复杂的推导或分析。主要考察的是对基础概念（软化点定义）和不同类型玻璃特性的记忆能力。解题步骤相对简单，只需识别和匹配给定的数据即可。" + }, + { + "idx": 4462, + "question": "Explain why residual thermal stresses are introduced into a glass piece when it is cooled.", + "answer": "Residual thermal stresses are introduced into a glass piece when it is cooled because surface and interior regions cool at different rates, and, therefore, contract different amounts; since the material will experience very little, if any deformation, stresses are established.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释玻璃冷却过程中残余热应力的产生原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释残余热应力在玻璃冷却过程中的产生机理，涉及不同冷却速率导致的收缩差异和应力建立，需要综合运用热力学和材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解残余热应力的基本概念，还需要掌握玻璃冷却过程中表面和内部区域冷却速率差异导致的收缩量不同这一机理。正确选项涉及对复杂现象的深度解释（冷却速率差异、收缩量差异、应力产生机制），需要考生具备综合分析和推理能力。这种题目在选择题中属于需要机理深度解释的类型，比单纯记忆或简单应用类题目难度更高。" + }, + { + "idx": 4463, + "question": "Are thermal stresses introduced upon heating? Why or why not?", + "answer": "Yes, thermal stresses will be introduced because of thermal expansion upon heating for the same reason as for thermal contraction upon cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要文字解释和论述，答案提供了详细的解释说明为什么加热会引入热应力，符合简答题的特征。 | 知识层次: 题目考查对热应力产生原因的基本概念记忆和理解，仅需解释热膨胀导致热应力的基本原理，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆（热应力与热膨胀的关系），但需要学生理解并解释\"加热时会产生热应力\"的原因，这比单纯记忆定义（等级1）要求更高。题目正确选项不仅陈述了现象，还通过类比冷却过程解释了原理，要求学生掌握概念间的关联性，但不需要进行复杂体系分析（等级3）。" + }, + { + "idx": 4464, + "question": "Borosilicate glasses and fused silica are resistant to thermal shock. Why is this so?", + "answer": "Borosilicate glasses and fused silica are resistant to thermal shock because they have relatively low coefficients of thermal expansion; therefore, upon heating or cooling, the difference in the degree of expansion or contraction across a cross-section of a ware that is constructed from these materials will be relatively low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么硼硅酸盐玻璃和熔融石英具有抗热震性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释硼硅酸盐玻璃和熔融石英抗热震性的原因，涉及材料的热膨胀系数与热应力之间的关系，需要综合运用材料科学中的热力学和力学知识进行推理分析，属于对材料性能机理的深入解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4465, + "question": "Glass pieces may also be strengthened by chemical tempering. With this procedure, the glass surface is put in a state of compression by exchanging some of the cations near the surface with other cations having a larger diameter. Suggest one type of cation that, by replacing \\mathrm{Na}^{+}, will induce chemical tempering in a soda-lime glass.", + "answer": "Chemical tempering will be accomplished by substitution, for \\mathrm{Na}^{+}, another monovalent cation with a slightly larger diameter. Both K^{+}and \\mathrm{Cs}^{+}fill these criteria, having ionic radii of 0.138 and 0.170 nm, respectively, which are larger than the ionic radius of \\mathrm{Na}^{+}(0.102nm). In fact, soda-lime glasses are tempered by a K^{+}-\\mathrm{Na}^{+}ion exchange.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，需要提出一种可以替代Na+的阳离子，并解释其如何通过化学强化来增强玻璃。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求考生理解化学强化玻璃的基本原理，并应用离子半径的知识选择合适的阳离子进行替换。这涉及到对离子交换过程的理解和离子半径的比较，属于中等应用层次。虽然题目没有涉及复杂的计算或多步骤分析，但需要考生将多个概念关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解化学强化玻璃的基本原理，并能够比较不同阳离子的半径大小及其对玻璃性能的影响。虽然题目给出了具体的离子半径数据，但考生仍需具备一定的材料科学基础知识，才能正确选择替换Na⁺的合适阳离子。此外，题目还涉及实际应用中的离子交换过程，需要考生将理论知识与实际应用相结合。" + }, + { + "idx": 4466, + "question": "Cite the two desirable characteristics of clay minerals relative to fabrication processes.", + "answer": "Two desirable characteristics of clay minerals relative to fabrication processes are (1) they become hydroplastic (and therefore formable) when mixed with water; and (2) during firing, clays melt over a range of temperatures, which allows some fusion and bonding of the ware without complete melting and a loss of mechanical integrity and shape.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释粘土矿物在制造过程中的两个理想特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对粘土矿物在加工过程中两个理想特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举粘土矿物在制造过程中的两个理想特性，但这两个特性（水塑性和烧结温度范围）属于基础概念记忆范畴，不需要复杂的分析或推理。学生只需准确回忆并描述这两个特性即可，不需要进行概念间的比较或深入阐述。因此，该题目在选择题型中属于等级2难度。" + }, + { + "idx": 4467, + "question": "From a molecular perspective, briefly explain the mechanism by which clay minerals become hydroplastic when water is added.", + "answer": "Clays become hydroplastic when water is added because the water molecules occupy regions between the layered molecular sheets; these water molecules essentially eliminate the secondary molecular bonds between adjacent sheets, and also form a thin film around the clay particles. The net result is that the clay particles are relatively free to move past one another, which is manifested as the hydroplasticity phenomenon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从分子角度简要解释黏土矿物在加水后变得具有水塑性的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从分子层面解释黏土矿物加水后产生水塑性的机理，涉及分子间作用力、水分子在层状结构中的行为以及宏观性能变化的关联，需要综合运用材料科学、化学等多学科知识进行推理分析，思维深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4468, + "question": "What are the three main components of a whiteware ceramic such as porcelain?", + "answer": "clay, quartz, and a flux.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举白瓷陶瓷的主要成分，答案需要提供具体的材料名称，而不是从选项中选择或判断对错，也不需要计算。 | 知识层次: 题目考查对白瓷陶瓷主要成分的基础概念记忆，属于定义和分类的记忆性知识 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接询问白瓷陶瓷的三种主要成分，正确选项明确给出了具体材料名称(clay, quartz, and a flux)。这只需要学生对基础概念的记忆即可作答，无需任何解释或分析步骤，属于最基础的知识点考察。在选择题型内，此类直接考查定义性知识的题目属于最低难度等级。" + }, + { + "idx": 4469, + "question": "What role does each component play in the forming and firing procedures?", + "answer": "Quartz acts as a filler material. Clay facilitates the forming operation since, when mixed with water, the mass may be made to become either hydroplastic or form a slip. Also, since clays melt over a range of temperatures, the shape of the piece being fired will be maintained. The flux facilitates the formation of a glass having a relatively low melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释每个组分在成型和烧制过程中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释各组分在成型和烧制过程中的具体作用，涉及多个材料组分的功能及其相互作用，需要理解并关联不同组分的特性和行为，属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握石英、黏土和助熔剂在成型和烧制过程中的不同作用，并能够将这些概念关联起来。虽然不需要复杂的计算，但需要对材料科学中的基本概念有较深的理解和综合分析能力。" + }, + { + "idx": 4470, + "question": "Why is it so important to control the rate of drying of a ceramic body that has been hydroplastically formed or slip cast?", + "answer": "It is important to control the rate of drying inasmuch as if the rate of drying is too rapid, there will be nonuniform shrinkage between surface and interior regions, such that warping and/or cracking of the ceramic ware may result.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么控制陶瓷体的干燥速率很重要，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解陶瓷干燥过程中的非均匀收缩现象及其后果，涉及多个概念的关联（干燥速率、收缩、变形/开裂）和综合分析（表面与内部区域的差异），但不需要复杂的机理推导或创新设计。 | 难度: 在选择题中属于中等难度，需要理解陶瓷干燥过程中的收缩不均匀性及其导致的变形和开裂问题，并进行概念关联和综合分析。虽然不涉及多步计算，但需要对材料行为有较深入的理解。" + }, + { + "idx": 4471, + "question": "Cite three factors that influence the rate of drying, and explain how each affects the rate.", + "answer": "Three factors that affect the rate of drying are temperature, humidity, and rate of air flow. The rate of drying is enhanced by increasing both the temperature and rate of air flow, and by decreasing the humidity of the air.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释影响干燥速率的三个因素，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对影响干燥速率的基本因素的记忆和简单理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举并解释三个影响干燥速率的因素，但正确选项已经提供了明确的答案框架（温度、湿度和空气流速），并简要说明了每个因素的影响方式。这需要考生不仅记住基本概念，还要理解这些因素如何具体影响干燥速率，属于概念解释和描述的层次。相比单纯的定义记忆题（等级1）或需要分析复杂概念体系的题目（等级3），该题的解题步骤和知识掌握要求处于中间水平。" + }, + { + "idx": 4472, + "question": "Cite one reason why drying shrinkage is greater for slip cast or hydroplastic products that have smaller clay particles.", + "answer": "The reason that drying shrinkage is greater for products having smaller clay particles is because there is more particle surface area, and, consequently, more water will surround a given volume of particles. The drying shrinkage will thus be greater as this water is removed, and as the interparticle separation decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么较小的粘土颗粒会导致更大的干燥收缩，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释为什么较小的粘土颗粒会导致更大的干燥收缩，这需要理解颗粒表面积与水分含量的关系，以及水分去除对颗粒间距的影响。虽然不涉及复杂的计算或综合分析，但需要将多个概念（颗粒大小、表面积、水分含量、干燥收缩）关联起来进行解释，超出了简单记忆或直接应用的层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及干燥收缩与粘土颗粒大小的关系，要求考生掌握表面面积与水分含量的关联，并能推导出颗粒间距减小对收缩的影响。虽然不需要多步计算，但需要综合分析多个材料科学概念，属于中等应用层次的知识要求。" + }, + { + "idx": 4473, + "question": "Name three factors that influence the degree to which vitrification occurs in clay-based ceramic wares.", + "answer": "(1) composition (2) the temperature of firing(3) the time at the firing temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举影响黏土基陶瓷制品玻璃化程度的三个因素，答案需要以文字形式简要说明，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查对影响陶瓷玻璃化程度的基本因素的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求列出三个影响粘土基陶瓷玻璃化程度的因素，正确选项直接给出了三个具体因素（成分、烧制温度、烧制时间），这些都是基础概念记忆性知识，无需复杂推理或分析。学生只需回忆并识别这些基本概念即可作答，因此难度较低。" + }, + { + "idx": 4474, + "question": "Explain how density, firing distortion, strength, corrosion resistance, and thermal conductivity are affected by the extent of vitrification.", + "answer": "Density will increase with degree of vitrification since the total remaining pore volume decreases. Strength will also increase with degree of vitrification inasmuch as more of the liquid phase forms, which fills in a greater fraction of pore volume. Upon cooling, the liquid forms a glass matrix of relatively high strength. Corrosion resistance normally increases also, especially at service temperatures below that at which the glass phase begins to soften. The rate of corrosion is dependent on the amount of surface area exposed to the corrosive medium; hence, decreasing the total surface area by filling in some of the surface pores, diminishes the corrosion rate. Thermal conductivity will increase with degree of vitrification. The glass phase has a higher conductivity than the pores that it has filled.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个材料性质如何受到玻璃化程度的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多个材料性能（密度、强度、耐腐蚀性、热导率）与玻璃化程度之间的关系，涉及多个概念的关联和综合分析，需要深入理解玻璃化过程的机理及其对材料性能的影响，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用多个材料科学概念（密度、强度、耐腐蚀性、热导率等），并深入理解玻璃化程度对这些性能的影响机理。正确选项不仅需要掌握每个性能与玻璃化程度的关系，还需要进行推理分析，解释为什么这些性能会随着玻璃化程度的变化而改变。此外，题目涉及高温和低温条件下的不同行为，增加了分析的复杂性。在选择题型中，这种全面、深入的机理解释和复杂现象分析属于最高难度要求。" + }, + { + "idx": 4475, + "question": "Some ceramic materials are fabricated by hot isostatic pressing. Cite some of the limitations and difficulties associated with this technique.", + "answer": "The principal disadvantage of hot-isostatic pressing is that it is expensive. The pressure is applied on a pre-formed green piece by a gas. Thus, the process is slow, and the equipment required to supply the gas and withstand the elevated temperature and pressure is costly.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举和解释热等静压技术的局限性和困难，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求考生列举热等静压技术的局限性和困难，这需要对热等静压技术的基本原理和实际应用有一定的理解，并能够综合分析其在实际操作中的问题。虽然不涉及复杂的计算或深度推理，但需要将多个概念关联起来进行论述，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解热等静压技术的基本原理及其局限性，并能综合分析设备成本、工艺速度等因素对技术应用的影响。虽然题目涉及多个概念，但在选择题型中通过正确选项可以较直接地识别关键信息。" + }, + { + "idx": 4476, + "question": "Compute repeat unit molecular weight for poly(vinyl chloride)", + "answer": "62.49g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚氯乙烯重复单元的分子量，需要通过数值计算和公式应用来得出具体数值结果62.49g/mol，符合计算题的特征。 | 知识层次: 题目要求计算聚氯乙烯重复单元的分子量，这属于基本公式的直接应用，只需理解重复单元的概念和进行简单的原子量相加计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅要求直接套用重复单元分子量的基本计算公式（即氯乙烯单体的分子量计算），无需任何额外的概念理解或步骤组合。正确选项62.49g/mol可通过简单查阅氯乙烯的原子组成（C2H3Cl）并相加标准原子量直接得出，完全符合\"单一公式直接计算\"的标准。选择题型进一步降低了难度，因为考生只需识别正确计算结果而非自行推导。" + }, + { + "idx": 4477, + "question": "Compute repeat unit molecular weight for poly(ethylene terephthalate)", + "answer": "192.16g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚对苯二甲酸乙二醇酯的重复单元分子量，需要通过数值计算和公式应用得出具体数值结果(192.16g/mol)，符合计算题的特征。 | 知识层次: 题目要求计算聚对苯二甲酸乙二醇酯的重复单元分子量，这需要应用基本的化学公式和原子量计算，属于直接套用基本知识的简单应用。 | 难度: 在选择题型中，该题目仅需直接套用已知的聚对苯二甲酸乙二醇酯重复单元分子量公式进行计算，无需额外的推导或组合多个公式。解题步骤简单直接，属于单一公式直接计算的范畴，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 4478, + "question": "Compute repeat unit molecular weight for polycarbonate", + "answer": "254.27g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行具体的数值计算（计算聚碳酸酯的重复单元分子量），答案是一个具体的数值（254.27g/mol），这符合计算题的特征。 | 知识层次: 题目要求计算聚碳酸酯的重复单元分子量，这属于基本公式应用和简单计算，直接套用分子量计算公式即可完成，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用已知的重复单元分子量计算公式，属于单一公式直接计算类型。题目提供正确选项，学生只需识别并选择正确数值，无需进行复杂推导或多步骤计算，因此属于最低难度等级。" + }, + { + "idx": 4479, + "question": "Compute repeat unit molecular weight for polydimethylsiloxane", + "answer": "74.16g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚二甲基硅氧烷的重复单元分子量，需要通过数值计算和公式应用得出具体数值结果74.16g/mol，符合计算题的特征。 | 知识层次: 题目要求计算聚二甲基硅氧烷的重复单元分子量，这属于基本公式应用和简单计算，只需理解重复单元的结构并应用原子量进行加和即可，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用单一公式（重复单元分子量计算）即可得出答案，无需复杂推导或多步骤计算。题目明确给出了重复单元结构（聚二甲基硅氧烷），且计算过程仅涉及基本原子量相加，属于最基础的应用层级。" + }, + { + "idx": 4480, + "question": "The number-average molecular weight of a polypropylene is 1,000,000g / mol. Compute the degree of polymerization.", + "answer": "23760", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚合度，答案是一个具体的数值（23760），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用基本的分子量计算公式（degree of polymerization = number-average molecular weight / monomer molecular weight），属于直接套用公式的简单计算。虽然涉及单位转换（需要知道丙烯单体分子量为42g/mol），但整体思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（聚合度 = 数均分子量 / 单体分子量）并进行简单计算。题目提供了所有必要数据（聚丙烯单体分子量为42g/mol），无需额外推导或组合公式，属于最基础的计算题类型。" + }, + { + "idx": 4481, + "question": "Compute the repeat unit molecular weight of polystyrene.", + "answer": "the repeat unit molecular weight of polystyrene is 104.14 g/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚苯乙烯的重复单元分子量，需要应用化学公式和数值计算，答案是一个具体的数值结果。 | 知识层次: 题目要求计算聚苯乙烯重复单元的分子量，这需要应用基本的化学计算和分子量公式，属于直接套用基本知识的简单应用。 | 难度: 在选择题型中，该题目仅需要直接套用已知的重复单元分子量公式进行计算，无需额外的公式组合或复杂步骤。属于单一公式直接计算的简单应用层次，因此难度等级为1。" + }, + { + "idx": 4482, + "question": "Compute the number-average molecular weight for a polystyrene for which the degree of polymerization is 25,000.", + "answer": "the number-average molecular weight for a polystyrene with a degree of polymerization of 25,000 is 2.60 x 10^6 g/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出聚合物的数均分子量，需要应用公式和数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求计算聚合物的数均分子量，涉及基本的公式应用和简单计算，即通过聚合度乘以重复单元的分子量来得到结果。不需要多步计算或复杂的概念关联，属于直接套用基本公式的简单应用。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（分子量 = 重复单元分子量 × 聚合度）进行计算，无需多步骤推理或概念组合。题目明确给出了聚合度(25,000)且聚苯乙烯重复单元分子量(104 g/mol)为已知常数，属于最基础的计算类选择题。" + }, + { + "idx": 4483, + "question": "High-density polyethylene may be chlorinated by inducing the random substitution of chlorine atoms for hydrogen. Determine the concentration of Cl (in wt%) that must be added if this substitution occurs for 5% of all the original hydrogen atoms.", + "answer": "the concentration of Cl that must be added is 20.3 wt%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定氯的浓度（wt%），答案是一个具体的数值（20.3 wt%），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，包括确定原始氢原子的数量、计算被氯取代的氢原子数量、以及最终计算氯的质量百分比。这涉及到对材料化学组成和分子结构的理解，以及相关的数学计算能力。虽然不涉及复杂的推理或综合分析，但需要一定的概念关联和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解高密度聚乙烯氯化反应的概念，掌握氢原子被氯原子随机取代的化学计量关系，并进行多步计算（包括分子量计算、取代比例换算和重量百分比计算）。虽然题目给出了明确的5%取代条件，但解题过程需要综合应用化学计量学和材料组成计算的知识，属于需要概念关联和综合分析的题目。" + }, + { + "idx": 4484, + "question": "In what ways does this chlorinated polyethylene differ from poly(vinyl chloride)?", + "answer": "chlorinated polyethylene differs from poly(vinyl chloride) in that, for pvc, (1) 25% of the side-bonding sites are substituted with Cl, and (2) the substitution is probably much less random.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种材料的不同之处，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种聚合物在氯取代方面的差异，涉及对聚合物结构和取代方式的理解，需要综合分析两种材料的结构特点，并解释其差异。这超出了简单记忆的范畴，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解氯代聚乙烯和聚氯乙烯的基本概念，还需要比较两者的具体差异，包括氯原子的取代比例和取代方式的随机性。这需要考生具备中等应用层次的知识，能够进行多步计算、概念关联和综合分析。因此，在选择题型内，该题目的难度等级为4，属于多角度分析论述的层次。" + }, + { + "idx": 4485, + "question": "Make comparisons of thermoplastic and thermosetting polymers on the basis of mechanical characteristics upon heating.", + "answer": "Thermoplastic polymers soften when heated and harden when cooled, whereas thermosetting polymers harden upon heating, while further heating will not lead to softening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对热塑性聚合物和热固性聚合物在加热时的机械特性进行比较，需要文字解释和论述，而不是选择、判断或计算。答案也以文字形式呈现，解释了两种聚合物的不同行为。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物在加热时机械特性的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目要求考生对热塑性聚合物和热固性聚合物的机械特性进行比较，属于概念解释和描述的层次。虽然需要记忆两种聚合物的基本特性，但不需要复杂的分析或推理步骤，属于中等偏下的难度。" + }, + { + "idx": 4486, + "question": "Make comparisons of thermoplastic and thermosetting polymers according to possible molecular structures.", + "answer": "Thermoplastic polymers have linear and branched structures, while for thermosetting polymers, the structures will normally be network or crosslinked.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对热塑性聚合物和热固性聚合物的分子结构进行比较，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物分子结构的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生对热塑性聚合物和热固性聚合物的分子结构进行比较分析，而不仅仅是简单的定义记忆。正确选项需要考生理解线性、支化、网络和交联等分子结构特征，并能区分两类聚合物的结构差异。这种比较分析在选择题型中属于概念解释和描述的难度层次。" + }, + { + "idx": 4487, + "question": "Is it possible to grind up and reuse phenol-formaldehyde? Why or why not?", + "answer": "It is not possible to grind up and reuse phenol-formaldehyde because it is a network thermoset polymer and, therefore, is not amenable to remolding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对酚醛树脂是否可以研磨和再利用进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对热固性聚合物基本特性的记忆和理解，即酚醛树脂作为网络热固性聚合物无法通过简单粉碎和重熔再利用的性质。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（酚醛树脂的定义和分类），但需要考生理解热固性聚合物的基本特性（不可重塑性）并应用这一知识来解释为什么酚醛树脂不能研磨后重复使用。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 4488, + "question": "Is it possible to grind up and reuse polypropylene? Why or why not?", + "answer": "Yes, it is possible to grind up and reuse polypropylene since it is a thermoplastic polymer, will soften when reheated, and, thus, may be remolded.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对是否可能研磨和再利用聚丙烯进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对聚丙烯（polypropylene）基本特性的记忆和理解，即它是一种热塑性聚合物，可以通过加热软化并重新塑形。这属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（聚丙烯的可回收性），但需要考生理解并应用\"热塑性聚合物\"这一概念来解释其可回收原理。相比单纯记忆定义（等级1），该题要求考生能够将概念与具体材料特性联系起来进行解释（等级2）。但题目不需要分析复杂概念体系或进行多步骤推理（等级3），因此属于等级2难度。" + }, + { + "idx": 4489, + "question": "The number-average molecular weight of a poly(styrene-butadiene) alternating copolymer is 1,350,000g / mol; determine the average number of styrene and butadiene repeat units per molecule.", + "answer": "the average number of styrene and butadiene repeat units per molecule is 8530.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定共聚物中苯乙烯和丁二烯重复单元的平均数量，答案是一个具体的数值，解答过程需要应用分子量和重复单元分子量的计算公式。 | 知识层次: 题目需要进行多步计算，涉及分子量的概念和重复单元的计算，需要将概念与公式应用结合起来，但不需要复杂的推理或综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解高分子化学中的分子量计算概念，掌握交替共聚物的结构特点，并进行多步计算（包括分子量换算和重复单元数计算）。虽然题目提供了正确选项，但解题过程涉及单位转换、结构分析和综合计算能力，属于需要一定知识储备和分析能力的综合性计算问题。" + }, + { + "idx": 4490, + "question": "Calculate the number-average molecular weight of a random nitrile rubber [poly(acrylonitrilebutadiene) copolymer] in which the fraction of butadiene repeat units is 0.30 ; assume that this concentration corresponds to a degree of polymerization of 2000 .", + "answer": "the number-average molecular weight of the nitrile rubber copolymer is \\bar{m}_{n} = 106740, \\text{g/mol}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算数均分子量），并给出了具体的计算条件和公式应用（聚合度为2000，重复单元分数为0.30）。答案也是一个具体的数值结果（106740 g/mol），符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括理解共聚物的组成、重复单元分子量的计算以及数均分子量的综合计算。虽然涉及基本公式应用，但需要综合分析共聚物的组成和聚合度的影响，思维过程有一定深度要求。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求计算数均分子量，涉及重复单元分数、聚合度等概念的综合运用，并需要进行多步计算。虽然题目提供了明确的参数和公式，但需要考生具备一定的材料科学基础知识和计算能力，属于中等应用层次的问题。" + }, + { + "idx": 4491, + "question": "An alternating copolymer is known to have a number-average molecular weight of 250,000g / mol and a degree of polymerization of 3420 . If one of the repeat units is styrene, which of ethylene, propylene, tetrafluoroethylene, and vinyl chloride is the other repeat unit? ", + "answer": "propylene", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（ethylene, propylene, tetrafluoroethylene, and vinyl chloride）中选择正确的另一个重复单元，符合选择题的特征。 | 知识层次: 题目需要计算分子量并分析共聚物的结构，涉及多步计算和概念关联。首先需要理解数均分子量和聚合度的关系，然后通过计算确定重复单元的分子量，最后根据选项中的单体分子量进行匹配。这需要中等程度的认知能力和综合分析。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算（如分子量计算、重复单元推断）、概念关联（如共聚物结构、单体分子量）以及综合分析（排除法判断正确单体）。虽然提供了正确选项，但解题过程涉及多个知识点的综合应用和较复杂的逻辑推理，超出了基础选择题的范畴。" + }, + { + "idx": 4492, + "question": "(a) Determine the ratio of butadiene to styrene repeat units in a copolymer having a number-average molecular weight of 350,000 g/mol and degree of polymerization of 4425.", + "answer": "1.0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定共聚物中丁二烯和苯乙烯重复单元的比例，答案是一个具体的数值（1.0），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要进行多步计算，涉及分子量和聚合度的概念关联，以及综合分析不同重复单元的比例。虽然计算过程较为直接，但需要理解并应用相关公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解共聚物组成比的计算方法，掌握数均分子量和聚合度的概念，并进行多步计算。虽然题目给出了正确选项，但解题过程涉及分子量计算、重复单元比例推导等综合分析步骤，比单纯的概念选择题更复杂。" + }, + { + "idx": 4493, + "question": "(b) Which type(s) of copolymer(s) will this copolymer be, considering the following possibilities: random, alternating, graft, and block?", + "answer": "random, alternating, graft, and block", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四种类型(random, alternating, graft, and block)中选择正确的共聚物类型，符合选择题的特征 | 知识层次: 题目考查对共聚物类型（无规、交替、接枝、嵌段）基本分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生理解和辨析不同类型的共聚物（random, alternating, graft, block），但不需要复杂的分析或深度理解。考生只需记忆并区分这些基本概念即可选出正确选项。因此，该题目属于中等难度（等级2）。" + }, + { + "idx": 4494, + "question": "Crosslinked copolymers consisting of 60 wt% ethylene and 40 wt% propylene may have elastic properties similar to those for natural rubber. For a copolymer of this composition, determine the fraction of both repeat unit types.", + "answer": "the fraction of the ethylene repeat unit is f(\\text{ethylene}) = 0.69 . the fraction of the propylene repeat unit is f(\\text{propylene}) = 0.31 .", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定乙烯和丙烯重复单元的比例，答案给出了具体的数值结果，解答过程需要应用材料科学中的相关公式和计算方法。 | 知识层次: 题目要求根据给定的重量百分比计算重复单元的比例，这需要应用基本的化学计量和分子量计算，属于直接套用公式和简单计算的范畴。虽然涉及一定的单位转换和计算步骤，但整体思维过程较为直接，不需要复杂的综合分析或推理。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式进行简单计算，属于单一公式直接计算的难度等级。题目明确给出了重量百分比，只需转换为摩尔分数即可得出答案，无需复杂的推理或多步骤计算。" + }, + { + "idx": 4495, + "question": "Explain briefly why the tendency of a polymer to crystallize decreases with increasing molecular weight.", + "answer": "The tendency of a polymer to crystallize decreases with increasing molecular weight because as the chains become longer it is more difficult for all regions along adjacent chains to align so as to produce the ordered atomic array.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释聚合物结晶倾向随分子量增加而降低的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高分子结晶倾向随分子量增加而降低的机理，需要深入理解高分子链排列和结晶过程的复杂性，涉及分子链长度对有序排列的影响机制，属于对材料科学原理的综合分析和推理解释。 | 难度: 在选择题型中，该题目属于较高难度等级。虽然题目形式为选择题，但正确选项要求考生理解高分子结晶的机理，并能分析分子量增加对结晶倾向的影响。这需要考生掌握高分子链排列的微观机制，并能将分子链长度与结晶难易度建立因果关系。相比简单记忆型或基础概念型选择题，此类题目要求考生具备机理深度解释能力，属于选择题型中较难的类型。" + }, + { + "idx": 4496, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (a) Linear and syndiotactic poly(vinyl chloride); linear and isotactic polystyrene.", + "answer": "Yes, for these two polymers it is possible to decide. The linear and syndiotactic poly(vinyl chloride) is more likely to crystallize; the phenyl side-group for polystyrene is bulkier than the Cl side-group for poly(vinyl chloride). Syndiotactic and isotactic isomers are equally likely to crystallize.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对聚合物结晶可能性进行比较，并给出理由，需要文字解释和论述，属于简答题类型。 | 知识层次: 题目要求对两种聚合物的结晶可能性进行比较分析，涉及分子结构（线性、间规立构和等规立构）和侧基体积效应的综合考量。虽然不需要复杂的计算，但需要对聚合物结晶原理和结构-性能关系有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生能够区分不同聚合物结构的结晶倾向，并解释其原因。这涉及到对聚合物链结构（如线性、间规立构和等规立构）的理解，以及对侧基大小对结晶能力影响的认识。虽然题目提供了明确的比较对象和解释，但考生仍需综合运用这些知识来做出判断。" + }, + { + "idx": 4497, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (b) Network phenol-formaldehyde; linear and heavily crosslinked cis-isoprene.", + "answer": "No, it is not possible to decide for these two polymers. Both heavily crosslinked and network polymers are not likely to crystallize.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行判断，并给出理由或解释为什么无法判断。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求对不同聚合物的结晶可能性进行比较和判断，需要理解聚合物结构（网络结构和线性交联结构）对结晶行为的影响，并进行综合分析。虽然不涉及复杂计算，但需要对材料科学中的结晶原理和聚合物结构有较深入的理解和应用能力。 | 难度: 在选择题中属于较高难度，需要综合理解聚合物结晶性、交联度影响等概念，并进行多角度比较分析。题目要求评估两种高度交联聚合物的结晶可能性，涉及对网络结构和线性交联结构的深入理解，以及判断两者均难以结晶的原因，属于多角度分析论述的层次。" + }, + { + "idx": 4498, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (c) Linear polyethylene; lightly branched isotactic polypropylene.", + "answer": "Yes, it is possible to decide for these two polymers. The linear polyethylene is more likely to crystallize. The repeat unit structure for polypropylene is chemically more complicated than is the repeat unit structure for polyethylene. Furthermore, branched structures are less likely to crystallize than are linear structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释哪一种更可能结晶以及原因。答案需要详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对两种聚合物的结晶能力进行比较，需要理解聚合物结构（线性与支化）对结晶性能的影响，并能够综合分析化学结构的复杂性和支化程度对结晶倾向的作用。这涉及多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅能够识别两种聚合物的结构差异（线性聚乙烯与轻度支化等规聚丙烯），还需要理解这些结构差异如何影响结晶能力。此外，考生需要综合应用关于聚合物结晶性的知识（如线性结构比支化结构更易结晶，化学结构复杂性对结晶的影响等）来做出判断。虽然题目提供了明确的比较点，但仍需要一定的综合分析能力来正确解答。" + }, + { + "idx": 4499, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (d) Alternating poly(styrene-ethylene) copolymer; random poly(vinyl chloride-tetrafluoroethylene) copolymer.", + "answer": "Yes, it is possible to decide for these two copolymers. The alternating poly(styrene-ethylene) copolymer is more likely to crystallize. Alternating copolymers crystallize more easily than do random copolymers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行比较，并给出理由。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求学生理解并应用聚合物结晶性的基本原理，比较两种不同结构共聚物的结晶能力。需要分析交替共聚物和无规共聚物的结构差异对结晶性的影响，并给出合理的解释。这涉及到多个概念的关联和综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生能够区分交替共聚物和随机共聚物的结晶能力，并基于聚合物结构特征做出判断。虽然不需要复杂的计算，但需要对聚合物结晶原理和共聚物类型有较深入的理解，并能将两者关联起来进行综合分析。" + }, + { + "idx": 4500, + "question": "Consider the diffusion of water vapor through a polypropylene (PP) sheet 2mm thick. The pressures of H_{2} \\mathrm{O} at the two faces are 1 kPa and 10 kPa, which are maintained constant. Assuming conditions of steady state, what is the diffusion flux [in \\left[{cm}^{3} STP\\right] / {cm}^{2}-s ] at 298 K ?", + "answer": "the diffusion flux is 1.71 × 10^{-7} \\ \\text{cm}^{3}\\text{stp}/\\text{cm}^{2}-\\text{s}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散通量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及稳态扩散条件下的扩散通量计算，需要应用菲克第一定律，并考虑气体扩散的特殊条件（STP）。虽然计算步骤较为直接，但需要理解扩散系数的概念、气体浓度的转换以及单位的一致性处理，属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散通量的概念，掌握稳态扩散的计算方法，并能正确应用相关公式进行多步骤计算。题目涉及气体扩散、压力差、材料厚度等多个变量，需要综合分析才能得出正确答案。虽然题目提供了具体数值和公式，但计算过程较为复杂，对学生的综合应用能力有一定要求。" + }, + { + "idx": 4501, + "question": "Argon diffuses through a high density polyethylene (HDPE) sheet 40mm thick at a rate of 4.0 × 10^{-7} \\left({cm}^{3} STP / {cm}^{2}-s\\right. at 325 K. The pressures of argon at the two faces are 5000 kPa and 1500 kPa, which are maintained constant. Assuming conditions of steady state, what is the permeability coefficient at 325 K ?", + "answer": "the permeability coefficient of ar through hdpe at 325k is 4.57 × 10^{-13} \\frac{{cm}^{3} \\mathrm{stp}·{cm}}{{cm}^{2}-s-\\mathrm{pa}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解渗透系数，答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散和渗透系数的相关知识，并进行综合分析。虽然计算过程较为直接，但需要理解稳态扩散条件、压力差的应用以及单位转换等概念，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散速率、压力差和渗透系数的关系，并进行多步计算。虽然题目给出了具体数值，但需要正确应用公式并转换单位，涉及中等应用层次的知识点。" + }, + { + "idx": 4502, + "question": "The permeability coefficient of a type of small gas molecule in a polymer is dependent on absolute temperature according to the following equation:\n\\[\nP_{M}=P_{M_{0}} \\exp \\left(-\\frac{Q_{p}}{R T}\\right)\n\\]\nwhere P_{M_{0}} and Q_{p} are constants for a given gas-polymer pair. Consider the diffusion of hydrogen through a poly(dimethyl siloxane) (PDMSO) sheet 20mm thick. The hydrogen pressures at the two faces are 10 kPa and 1 kPa, which are maintained constant. Compute the diffusion flux [in \\left({cm}^{3} STP\\right) / {cm}^{2}-s ] at 350 K. For this diffusion system\n\\[\n\\begin{array}{l}\nP_{M_{0}}=1.45 × 10^{-8}\\left(cm^{3} STP\\right)\\left({cm}^{3} / {cm}^{2}-s-\\mathrm{Pa}\\right. \\\\\nQ_{p}=13.7kJ / mol\n\\end{array}\n\\]\nAlso, assume a condition of steady state diffusion", + "answer": "the diffusion flux is 5.90 × 10^{-7} \\frac{\\text{cm}^{3} \\text{stp}}{\\text{cm}^{2}·\\text{s}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（扩散通量）。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目需要应用给定的公式进行多步计算，包括温度对渗透系数的影响以及扩散通量的计算。虽然不涉及复杂的综合分析或推理，但需要理解公式中各参数的含义并进行正确的数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算，包括理解渗透系数方程、应用稳态扩散条件、计算扩散通量等步骤。虽然题目提供了所有必要的参数和公式，但需要考生能够正确地将这些信息整合并应用到具体情境中。此外，题目还要求考生对单位转换和科学记数法有一定的掌握。因此，在选择题型内，这道题目属于综合性计算问题，难度等级为3。" + }, + { + "idx": 4503, + "question": "For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to\n\\[\n\\sigma(t)=\\sigma(0) \\exp \\left(-\\frac{t}{\\tau}\\right)\n\\]\nwhere \\sigma(t) and \\sigma(t) represent the time-dependent and initial (i.e., time =0 ) stresses, respectively, and t and \\tau denote elapsed time and the relaxation time; \\tau is a time-independent constant characteristic of the material. A specimen of some viscoelastic polymer the stress relaxation of which obeys Equation 15.10 was suddenly pulled in tension to a measured strain of 0.6 ; the stress necessary to maintain this constant strain was measured as a function of time. Determine E_{\\tau}(10) for this material if the initial stress level was 2.76 MPa(400 psi), which dropped to 1.72 MPa (250 psi) after 60s.", + "answer": "e_{\\tau}(10) = 4.25 \\text{ mpa (616 psi)}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和初始条件进行数值计算，最终得出一个具体的数值结果（E_{\\tau}(10) = 4.25 \\text{ mpa (616 psi)}），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用给定的应力松弛公式和计算弹性模量，需要理解应力松弛的基本概念和公式应用，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解应力松弛的概念，应用指数衰减公式进行多步计算，并综合分析初始条件和时间变化对结果的影响。虽然题目提供了具体数值和公式，但解题过程涉及多个步骤和概念关联，对学生的应用能力有一定要求。" + }, + { + "idx": 4504, + "question": "(a) Contrast the manner in which stress relaxation and viscoelastic creep tests are conducted.", + "answer": "Stress relaxation tests are conducted by rapidly straining the material elastically in tension, holding the strain level constant, and then measuring the stress as a function of time. For viscoelastic creep tests, a stress (usually tensile) is applied instantaneously and maintained constant while strain is measured as a function of time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对比两种测试方法的操作方式，需要文字解释和论述，而不是选择、判断或计算。答案也以文字描述的形式呈现，详细说明了两种测试方法的操作步骤。 | 知识层次: 题目考查对两种测试方法（应力松弛和粘弹性蠕变）的基本定义和操作步骤的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生对比两种测试方法的基本操作步骤，属于概念解释和描述的层次。虽然需要记忆和理解两种测试方法的具体操作，但并不涉及复杂的分析或推导过程，因此属于中等难度。" + }, + { + "idx": 4505, + "question": "(b) For each of these tests, cite the experimental parameter of interest and how it is determined.", + "answer": "The experimental parameters of interest from the stress relaxation and viscoelastic creep tests are the relaxation modulus and creep modulus (or creep compliance), respectively. The relaxation modulus is the ratio of stress measured after 10 s and strain; creep modulus is the ratio of stress and strain taken at a specific time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释实验参数及其确定方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对松弛模量和蠕变模量的基本定义和测定方法的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（如松弛模量和蠕变模量的定义），但要求考生能够区分两种不同的实验参数并理解其测量方法。这需要考生不仅记住定义，还要能够解释和描述这些概念在实际测试中的应用。因此，相较于仅要求基本定义简答的等级1题目，该题目对知识点的掌握深度要求更高，属于概念解释和描述的等级2难度。" + }, + { + "idx": 4506, + "question": "For thermoplastic polymers, cite five factors that favor brittle fracture.", + "answer": "For thermoplastic polymers, five factors that favor brittle fracture are as follows: (1) a reduction in temperature, (2) an increase in strain rate, (3) the presence of a sharp notch, (4) increased specimen thickness, and (5) modifications of the polymer structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释五个因素，答案以文字形式详细说明，没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目主要考查对热塑性聚合物脆性断裂影响因素的基本记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举五个因素，但每个因素都是基础概念记忆层面的知识点，不需要复杂的推理或分析。学生只需回忆并识别出与热塑性聚合物脆性断裂相关的因素即可。相较于等级1的基本定义简答，该题目需要记忆和理解多个相关概念，但不需要进行深入的阐述或比较分析。" + }, + { + "idx": 4507, + "question": "For the pair of polymers: random acrylonitrile-butadiene copolymer with 10% of possible sites crosslinked; alternating acrylonitrile-butadiene copolymer with 5% of possible sites crosslinked, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why.", + "answer": "No, it is not possible. The random acrylonitrile-butadiene copolymer will tend to a lower degree of crystallinity than the alternating acrylonitrile-butadiene copolymer inasmuch as random copolymers don't normally crystallize. On this basis only, the alternating material would have a higher modulus inasmuch as tensile modulus increases with degree of crystallinity. On the other hand, the random copolymer has a higher degree of crosslinking (10% versus 5% for the alternating copolymer), and, on this basis only would have the higher tensile modulus-an increase in crosslinking leads to an increase in E. Thus, this determination is not possible; with regard to degree of crystallinity the alternating material has the higher E, whereas the random copolymer would have a higher E value on the basis of degree of crosslinking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸模量进行比较，并详细解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求综合分析两种不同结构（随机共聚物和交替共聚物）和不同交联程度对拉伸模量的影响，需要理解结晶度和交联度对材料性能的相反作用机制，并进行权衡判断。这涉及多个因素的相互作用和推理分析，超出了简单应用或中等应用的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4508, + "question": "For the pair of polymers: branched and syndiotactic polypropylene with a degree of polymerization of 5000; linear and isotactic polypropylene with a degree of polymerization of 3000, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why.", + "answer": "Yes, it is possible. The linear and isotactic polypropylene will have a greater tensile modulus. Linear polymers are more likely to crystallize that branched ones. ", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较两种聚合物的拉伸模量并给出理由，这符合简答题的特征。 | 知识层次: 题目要求比较两种不同结构的聚丙烯的拉伸模量，需要理解聚合物结构（支化与线性、等规与间规）对结晶度和力学性能的影响，并进行综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和比较，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解聚合物结构（支化与线性、等规与间规）对结晶度和力学性能的影响，并进行多角度比较分析。题目要求判断两种不同结构聚丙烯的拉伸模量高低，涉及分子链排列、结晶能力等深层次概念关联，且需在给定条件下做出明确结论并说明理由，属于多步计算和概念关联的综合分析题。" + }, + { + "idx": 4509, + "question": "For the pair of polymers: branched polyethylene with a number-average molecular weight of 250000 g/mol; linear and isotactic poly(vinyl chloride) with a number-average molecular weight of 200000 g/mol, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why.", + "answer": "No, it is not possible. Linear polymers have higher degrees of crystallization (and higher tensile moduli) than branched polymers - on this basis, the PVC material should have the higher value of E. On the other hand, PVC has a more complex repeat unit structure than does polyethylene, which means that, on this basis, the PE would have a higher degree of crystallinity and also a greater tensile modulus. Also, tensile modulus is relatively independent of number-average molecular weight. Therefore, this determination is not possible since it is not possible to determine which of the two materials has the greater degree of crystallinity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，需要分析不同因素对聚合物拉伸模量的影响，并最终给出结论。答案也以论述形式呈现，没有涉及计算或选择选项。 | 知识层次: 题目要求综合分析两种聚合物的结构特征（支化聚乙烯和线性等规聚氯乙烯）及其对拉伸模量的影响，涉及结晶度、分子结构复杂性和分子量的多重因素。需要深入理解聚合物结构与性能的关系，并进行推理分析，以判断哪种因素对拉伸模量的影响更为显著。这超出了简单应用或中等应用的范围，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4510, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. Syndiotactic polystyrene having a number-average molecular weight of 600,000 g/mol; atactic polystyrene having a number-average molecular weight of 500,000 g/mol", + "answer": "Yes it is possible. The syndiotactic polystyrene has the higher tensile strength. Syndiotactic polymers are more likely to crystallize than atactic ones; the greater the crystallinity, the higher the tensile strength. Furthermore, the syndiotactic also has a higher molecular weight; increasing molecular weight also enhances the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的拉伸强度，并解释原因。这需要理解分子量、立体规整性（如间规立构和无规立构）对聚合物性能的影响，以及这些因素如何共同影响拉伸强度。虽然不涉及复杂的计算或多步推理，但需要对多个概念进行关联和综合分析。 | 难度: 在选择题型中，该题目要求考生进行多角度分析论述。首先需要判断是否可能比较两种聚合物的拉伸强度，然后需要分析两种聚合物的结构差异（间规与无规）和分子量差异对拉伸强度的影响。此外，还需要理解结晶度与拉伸强度的关系以及分子量对强度的影响。这些步骤涉及多个概念的关联和综合分析，超出了简单的记忆或单一概念的应用，因此在选择题型中属于较高难度。" + }, + { + "idx": 4511, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. Random acrylonitrile-butadiene copolymer with 10% of possible sites crosslinked; block acrylonitrile-butadiene copolymer with 5% of possible sites crosslinked", + "answer": "No it is not possible. The random acrylonitrile-butadiene copolymer has more crosslinking; increased crosslinking leads to an increase in strength. However, the block copolymeric material will most likely have a higher degree of crystallinity; and increasing crystallinity improves the strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对两种不同结构的聚合物（随机共聚物和嵌段共聚物）的拉伸强度进行比较，涉及多个因素的综合分析，包括交联度、结晶度对材料性能的影响。需要理解并解释这些因素如何相互作用以及它们对最终性能的贡献，这属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4512, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. Network polyester; lightly branched polypropylene", + "answer": "Yes it is possible. The network polyester will display a greater tensile strength. Relative chain motion is much more restricted than for the lightly branched polypropylene since there are many more of the strong covalent bonds for the network structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对不同聚合物的拉伸强度进行比较，并解释原因。这需要理解聚合物结构（网络结构与轻度支化结构）对力学性能的影响，属于概念关联和综合分析。虽然不涉及复杂计算，但需要对材料性能与结构关系有较深入的理解。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅能够识别两种聚合物的结构差异（网络聚酯与轻度支化聚丙烯），还需要理解这些结构如何影响材料的拉伸强度。此外，考生需要能够将结构特征与力学性能联系起来，并做出明确的判断。虽然题目提供了明确的比较点，但仍需要一定的综合分析能力来正确回答。" + }, + { + "idx": 4513, + "question": "List the two molecular characteristics that are essential for elastomers.", + "answer": "Two molecular characteristics essential for elastomers are: (1) they must be amorphous, having chains that are extensively coiled and kinked in the unstressed state; and (2) there must be some crosslinking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出两个分子特性，答案以文字解释的形式给出，没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目考查对弹性体基本分子特性的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目要求考生回忆并识别出弹性体的两个基本分子特性。虽然需要记忆两个关键点（非晶态结构和交联），但这些都是基础概念记忆层面的内容，不需要复杂的推理或分析。相较于只需回忆单一基本定义的等级1题目，此题稍微复杂一些，但仍属于概念解释和描述的范畴。" + }, + { + "idx": 4514, + "question": "Name the following polymer(s) that would be suitable for the fabrication of cups to contain hot coffee: polyethylene, polypropylene, poly(vinyl chloride), PET polyester, and polycarbonate. Why?", + "answer": "This question asks us to name which, of several polymers, would be suitable for the fabrication of cups to contain hot coffee. At its glass transition temperature, an amorphous polymer begins to soften. The maximum temperature of hot coffee is probably slightly below 100^{\\circ} C\\left(212^{\\circ} F\\right). Of the polymers listed, only polystyrene and polycarbonate have glass transition temperatures of 100^{\\circ} C or above, and would be suitable for this application.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释哪些聚合物适合制作热咖啡杯，并说明原因。答案提供了详细的解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求学生在理解聚合物玻璃化转变温度的基础上，分析不同聚合物在特定温度条件下的适用性，涉及多个概念的关联和综合分析。虽然不需要复杂的计算或深度推理，但需要对材料性能和应用场景有一定的理解和判断能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道各种聚合物的基本性质，还需要了解玻璃化转变温度的概念，并能将其与实际应用场景（热咖啡的温度）联系起来进行综合分析。虽然题目提供了多个选项，但正确解答需要考生排除不合适的选项并选择最合适的聚合物，这涉及多步推理和概念关联。" + }, + { + "idx": 4515, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Isotactic polystyrene that has a density of 1.12 g/cm3 and a weight-average molecular weight of 150,000 g/mol; syndiotactic polystyrene that has a density of 1.10 g/cm3 and a weight-average molecular weight of 125,000 g/mol", + "answer": "Yes, it is possible to determine which of the two polystyrenes has the higher Tm. The isotactic polystyrene will have the higher melting temperature because it has a higher density (i.e., less branching) and also the greater weight-average molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较熔点高低并给出理由，或说明无法决定的原因。答案需要详细的文字说明而非简单选择或计算。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这涉及到对聚合物结构（等规和间规）、密度和分子量对熔点影响的理解和应用。虽然不需要复杂的计算或深入机理分析，但需要综合多个因素进行判断和解释，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解聚合物的立体规整性（等规与间规）对熔点的影响，还需要综合考虑密度（反映分子链堆积紧密程度）和分子量这两个因素对熔点的复合影响。需要考生进行多角度分析（立体构型+密度+分子量）并正确判断各因素的优先级（立体构型影响>密度影响>分子量影响），最后得出综合结论。这种需要同时处理多个变量并理解其相互作用关系的题目，在选择题型中属于较复杂的综合分析题。" + }, + { + "idx": 4516, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Linear polyethylene that has a degree of polymerization of 5,000; linear and isotactic polypropylene that has a degree of polymerization of 6,500", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. The polypropylene will have the higher Tm because it has a bulky phenyl side group in its repeat unit structure, which is absent in the polyethylene. Furthermore, the polypropylene has a higher degree of polymerization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较熔点高低并给出理由，或说明无法判断的原因。答案也是以文字形式详细解释，而非选择、判断或计算。 | 知识层次: 题目要求学生比较两种聚合物的熔点，并解释原因。这需要理解聚合物结构（如侧基和聚合度）对熔点的影响，涉及多个概念的关联和综合分析。虽然不涉及复杂计算，但需要一定的推理和解释能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅能够识别两种聚合物的结构差异（聚乙烯与聚丙烯的侧基差异），还需要理解聚合度对熔点的影响，并综合这些因素进行判断。此外，题目还要求考生能够正确引用理由支持其选择，这需要较深的知识掌握和多角度分析能力。虽然题目提供了具体数据（聚合度），但考生仍需进行概念关联和综合分析，这在选择题型中属于较为复杂的要求。" + }, + { + "idx": 4517, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Branched and isotactic polystyrene that has a degree of polymerization of 4,000; linear and isotactic polypropylene that has a degree of polymerization of 7,500", + "answer": "No, it is not possible to determine which of the two polymers has the higher melting temperature. The polystyrene has a bulkier side group than the polypropylene; on the basis of this effect alone, the polystyrene should have the greater Tm. However, the polystyrene has more branching and a lower degree of polymerization; both of these factors lead to a lowering of the melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并详细解释原因或说明无法比较的理由。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的熔点，涉及分子结构（支化、等规性）、侧基体积效应和聚合度等多个因素的权衡分析。虽然不需要复杂的计算，但需要对聚合物结构与性能关系有较深入的理解，并能综合多个影响因素进行判断。这属于中等应用层次，需要概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生进行多角度分析论述。具体来说，考生需要：" + }, + { + "idx": 4518, + "question": "Briefly explain the difference in molecular chemistry between silicone polymers and other polymeric materials.", + "answer": "The backbone chain of most polymers consists of carbon atoms that are linked together. For the silicone polymers, this backbone chain is composed of silicon and oxygen atoms that alternate positions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释两种聚合物在分子化学上的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对硅聚合物和其他聚合物分子化学差异的基本概念记忆和理解，涉及聚合物主链组成的简单对比，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生解释两种聚合物在分子化学上的差异，涉及基础概念的记忆和理解。虽然需要区分硅氧聚合物和其他聚合物的主链组成，但不需要复杂的分析或推理步骤，属于概念解释和描述的难度等级。" + }, + { + "idx": 4519, + "question": "List two important characteristics for polymers that are to be used in fiber applications.", + "answer": "Two important characteristics for polymers that are to be used in fiber applications are: (1) they must have high molecular weights, and (2) they must have chain configurations/structures that will allow for high degrees of crystallinity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出两个重要特性，需要用文字进行简要说明，不需要计算或选择，符合简答题的特征。 | 知识层次: 题目考查对聚合物纤维应用所需特性的基本概念记忆，仅需列举两个重要特性（高分子量和可结晶结构），不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列出两个重要特性，但这两个特性（高分子量和允许高结晶度的链结构）都是聚合物纤维应用中的基础概念，不需要复杂的分析或比较。学生只需回忆并识别这两个关键特征即可，属于概念解释和描述的层次。" + }, + { + "idx": 4520, + "question": "Cite five important characteristics for polymers that are to be used in thin-film applications.", + "answer": "Five important characteristics for polymers that are to be used in thin-film applications are: (1) low density; (2) high flexibility; (3) high tensile and tear strengths; (4) resistance to moisture/chemical attack; and (5) low gas permeability.\n}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举五个重要特性，答案以文字形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目主要考查对聚合物薄膜应用所需特性的基本概念记忆，属于列举重要特征的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求列举五个重要特性，属于概念解释和描述的范畴。虽然需要记忆多个特性，但每个特性都是基础概念，不需要复杂的分析或比较。因此，难度属于中等偏下。" + }, + { + "idx": 4521, + "question": "Cite the primary differences between addition and condensation polymerization techniques.", + "answer": "For addition polymerization, the reactant species have the same chemical composition as the monomer species in the molecular chain. This is not the case for condensation polymerization, wherein there is a chemical reaction between two or more monomer species, producing the repeating unit. There is often a low molecular weight by-product for condensation polymerization; such is not found for addition polymerization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两种聚合技术的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对加成聚合和缩聚聚合两种基本聚合方法差异的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生能够理解和区分两种聚合反应的基本概念和特征。虽然涉及多个知识点（加成聚合和缩聚反应的定义、产物特征等），但题目提供了明确的对比框架，且正确选项已经将关键区别点进行了系统归纳。这属于需要概念解释和描述的难度层级，比单纯记忆定义（等级1）稍高，但不需要进行复杂的体系阐述（等级3）。" + }, + { + "idx": 4522, + "question": "Estimate the maximum thermal conductivity value for a cermet that contains 85 vol % titanium carbide (TiC) particles in a cobalt matrix. Assume thermal conductivities of 27 and 69 W/m-K for TiC and Co, respectively.", + "answer": "the maximum thermal conductivity k_max is 33.3 W/m-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计最大热导率值，答案是一个具体的数值结果，解答过程需要运用材料科学中的热导率计算原理。 | 知识层次: 题目需要进行多步计算，涉及复合材料热导率的估算，需要理解并应用复合材料热导率的最大值计算公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料热导率的混合规则（如串联模型），并正确应用体积分数进行计算。题目涉及两个材料参数的整合和多步骤计算，但选项已经给出了具体数值，减少了部分推导难度。" + }, + { + "idx": 4523, + "question": "Estimate the minimum thermal conductivity value for a cermet that contains 85 vol % titanium carbide (TiC) particles in a cobalt matrix. Assume thermal conductivities of 27 and 69 W/m-K for TiC and Co, respectively.", + "answer": "the minimum thermal conductivity k_min is 29.7 W/m-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计cermet的最小热导率值，答案是一个具体的数值结果（29.7 W/m-K），这符合计算题的特征。 | 知识层次: 题目需要应用复合材料热导率的最小值计算公式，涉及多步计算和不同材料热导率的综合考量，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解复合材料热导率的最小值计算原理，并正确应用串联模型公式进行多步计算。题目涉及两个材料的热导率数据整合和体积分数换算，属于综合性计算问题，但选项已给出正确答案降低了部分难度。" + }, + { + "idx": 4524, + "question": "A large-particle composite consisting of tungsten particles within a copper matrix is to be prepared. If the volume fractions of tungsten and copper are 0.60 and 0.40 , respectively, estimate the upper limit for the specific stiffness of this composite given the data that follow.\n\\begin{tabular}{lcc}\n\\hline & Specific Gravity & \\begin{tabular}{c} \nModulus of Elasticity \\\\\n(GPa)\n\\end{tabular} \\\\\n\\hline Copper & 8.9 & 110 \\\\\nTungsten & 19.3 & 407 \\\\\n\\hline\n\\end{tabular}", + "answer": "the upper limit for the specific stiffness of this composite is 19.0 \\text{ gpa}. an alternate approach yields a specific stiffness of 17.6 \\text{ gpa}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的体积分数和材料属性数据进行数值计算，以估计复合材料的具体刚度上限。解答过程需要应用公式和进行数值运算，最终给出具体的数值结果。答案的形式也是具体的数值，符合计算题的特征。 | 知识层次: 题目需要应用复合材料力学性能的混合法则（rule of mixtures）进行多步计算，涉及体积分数、弹性模量和比重的综合运用，需要概念关联和综合分析能力。虽然计算过程不涉及复杂的推理或创新设计，但超出了简单套用公式的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料的概念，掌握比刚度的计算方法，并进行多步计算。题目涉及体积分数、比重的转换以及弹性模量的综合运用，虽然选项给出了计算结果，但需要考生具备较强的综合分析能力才能正确理解和选择。" + }, + { + "idx": 4525, + "question": "(a) What is the distinction between cement and concrete?", + "answer": "Concrete consists of an aggregate of particles that are bonded together by a cement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释水泥和混凝土之间的区别，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查基础概念的记忆和理解，即水泥和混凝土的区别，属于定义性的知识。 | 难度: 在选择题型中，此题仅需要识别和区分两个基础材料科学概念（水泥和混凝土）的定义关系。正确选项直接给出了明确的定义对比，属于最基础的概念记忆层次，不需要复杂的分析或推理过程。" + }, + { + "idx": 4526, + "question": "(b) Cite three important limitations that restrict the use of concrete as a structural material.", + "answer": "Three limitations of concrete are: (1) it is a relatively weak and brittle material; (2) it experiences relatively large thermal expansions (contractions) with changes in temperature; and (3) it may crack when exposed to freeze-thaw cycles.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并简要解释混凝土作为结构材料的三个重要限制，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对混凝土作为结构材料的基本局限性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求列举混凝土作为结构材料的三个重要限制因素，属于概念解释和描述层次。虽然需要记忆多个知识点，但每个限制因素都是基础概念，不需要复杂的分析或比较。因此，在选择题型内属于中等难度。" + }, + { + "idx": 4527, + "question": "(c) Briefly explain three techniques that are utilized to strengthen concrete by reinforcement.", + "answer": "Three reinforcement strengthening techniques are: (1) reinforcement with steel wires, rods, etc.; (2) reinforcement with fine fibers of a high modulus material; and (3) introduction of residual compressive stresses by prestressing or postensioning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释三种强化混凝土的技术，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对混凝土增强技术的基本概念记忆和理解，仅需列举并简要解释三种常见的增强技术，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求简要解释三种强化混凝土的技术，但正确选项已经提供了明确的三种技术及其简要描述。这要求考生不仅要记住这些技术的基本概念，还需要理解每种技术的具体应用方式。相比于等级1的基本定义简答，该题目需要更深入的概念解释和描述，但不需要进行复杂的体系阐述或比较分析，因此属于等级2难度。" + }, + { + "idx": 4528, + "question": "Cite one similarity between precipitation hardening and dispersion strengthening.", + "answer": "The similarity between precipitation hardening and dispersion strengthening is the strengthening mechanism--i.e., the precipitates/particles effectively hinder dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字解释和论述两种强化机制的相似点，答案是一段简短的文字描述，没有选项、判断对错或数值计算的需求。 | 知识层次: 题目考查对两种强化机制的基本概念的理解和记忆，要求识别并描述它们的共同点，属于基础概念的记忆和简单对比。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但需要考生理解并比较两种强化机制（沉淀硬化和弥散强化）的相似之处。这不仅仅是对单一概念的简单回忆，而是需要对两种机制的基本原理有一定理解，并能识别出它们的共同点。因此，相较于仅要求基本定义简答的题目（等级1），该题目需要更深一层的概念解释和描述能力（等级2）。" + }, + { + "idx": 4529, + "question": "Cite two differences between precipitation hardening and dispersion strengthening.", + "answer": "The two differences are: (1) the hardening/strengthening effect is not retained at elevated temperatures for precipitation hardening--however, it is retained for dispersion strengthening; and (2) the strength is developed by a heat treatment for precipitation hardening--such is not the case for dispersion strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举两种方法之间的差异，并以文字形式进行解释和论述，符合简答题的特征。答案提供了详细的文字说明，而非选择、判断或计算。 | 知识层次: 题目要求比较两种强化机制的差异，涉及对两种机制的理解和对比分析，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求列举两种强化方式的区别，涉及对沉淀硬化和弥散强化两种机制的理解，并需要比较它们在高温下的行为差异以及强化方式的差异。这需要考生掌握相关概念并能进行综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4530, + "question": "A continuous and aligned fiber-reinforced composite is to be produced consisting of 30 vol% aramid fibers and 70 vol% of a polycarbonate matrix; mechanical characteristics of these two materials are as follows: Modulus of Elasticity for Aramid fiber is 131 GPa (19x10^6 psi) and Tensile Strength is 3600 MPa (520,000 psi); Modulus of Elasticity for Polycarbonate is 2.4 GPa (3.5x10^5 psi) and Tensile Strength is 65 MPa (9425 psi). Also, the stress on the polycarbonate matrix when the aramid fibers fail is 45 MPa (6500 psi). For this composite, compute the longitudinal tensile strength.", + "answer": "the longitudinal tensile strength is 1100 mpa (160,000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的材料参数和体积分数，应用复合材料力学中的混合法则（Rule of Mixtures）进行数值计算，以确定复合材料的纵向拉伸强度。答案是一个具体的数值结果，这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用复合材料力学性能的计算方法，包括体积分数、弹性模量和拉伸强度的复合效应计算。虽然不涉及复杂的机理解释或创新设计，但需要一定的综合分析能力来推导纵向拉伸强度。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料力学性能的基本概念，掌握纵向拉伸强度的计算方法，并进行多步计算。题目涉及纤维和基体的体积分数、弹性模量、拉伸强度等多个参数的综合运用，且需要正确应用混合法则进行计算。虽然题目提供了所有必要参数，但解题过程需要一定的综合分析能力。" + }, + { + "idx": 4532, + "question": "For a continuous and oriented fiber-reinforced composite, the modulus of elasticity in the longitudinal direction is 19.7 GPa (2.8 x 10^5 psi). If the volume fraction of fibers is 0.25, determine the modulus of elasticity of the fiber phase.", + "answer": "the modulus of elasticity of the fiber phase e_f is 70.4 GPa (10.2 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（纵向弹性模量和纤维体积分数）应用复合材料力学公式计算纤维相的弹性模量，答案以具体数值形式给出，属于典型的计算题类型。 | 知识层次: 题目需要应用复合材料弹性模量的混合法则公式进行计算，涉及多步推导和概念关联（纤维和基体的弹性模量关系），但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料弹性模量的混合规则（Rule of Mixtures）概念，并能够正确应用公式进行多步计算。题目要求根据已知的复合材料纵向弹性模量和纤维体积分数，反推出纤维相的弹性模量，这涉及公式变形和单位换算（GPa与psi的转换），属于综合性计算问题。虽然题目给出了正确选项，但解题过程需要较强的概念关联能力和计算准确性。" + }, + { + "idx": 4533, + "question": "For a continuous and oriented fiber-reinforced composite, the modulus of elasticity in the transverse direction is 3.66 GPa (5.3 x 10^5 psi). If the volume fraction of fibers is 0.25, determine the modulus of elasticity of the matrix phase.", + "answer": "the modulus of elasticity of the matrix phase e_m is 2.79 GPa (4.04 x 10^5 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（纤维体积分数和横向弹性模量）应用公式计算基体相的弹性模量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用复合材料横向弹性模量的计算公式，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解复合材料横向弹性模量的计算公式，并能够正确代入已知条件进行多步计算。题目涉及体积分数和弹性模量的关系，需要综合分析能力。虽然计算过程不算极其复杂，但需要准确掌握相关概念和公式。" + }, + { + "idx": 4534, + "question": "In an aligned and continuous glass fiber-reinforced nylon 6,6 composite, the fibers are to carry 94% of a load applied in the longitudinal direction. Using the data provided, determine the volume fraction of fibers that will be required.", + "answer": "the required volume fraction of fibers is 0.393.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定纤维的体积分数，答案是一个具体的数值（0.393），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用复合材料力学中的基本公式（如载荷分配公式），进行多步计算以确定纤维体积分数。虽然不涉及复杂的综合分析或推理，但需要理解载荷分配原理并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料中纤维承载比例与体积分数的关系，并进行多步计算。题目要求将载荷分配比例转化为体积分数，涉及材料力学和复合材料原理的综合应用，计算过程需要正确关联多个概念和公式。虽然题目提供了明确的计算目标，但解题步骤仍需要一定的综合分析能力。" + }, + { + "idx": 4535, + "question": "In an aligned and continuous glass fiber-reinforced nylon 6,6 composite, the fibers are to carry 94% of a load applied in the longitudinal direction. What will be the tensile strength of this composite? Assume that the matrix stress at fiber failure is 30 MPa (4350 psi).", + "answer": "the tensile strength of this composite is 1354 mpa (196,400 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的拉伸强度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及纤维和基体的应力分配，需要应用复合材料力学中的基本公式，并进行综合分析。虽然计算过程不复杂，但需要理解复合材料中各相的作用和相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料力学的基本概念（如载荷分配、纤维和基体的应力关系），并进行多步计算（包括百分比转换和应力叠加）。虽然题目提供了部分参数，但仍需综合分析才能得出正确结论，属于综合性计算问题。" + }, + { + "idx": 4536, + "question": "For a polymer-matrix fiber-reinforced composite, list three functions of the matrix phase.", + "answer": "For polymer-matrix fiber-reinforced composites, three functions of the polymer-matrix phase are: (1) to bind the fibers together so that the applied stress is distributed among the fibers; (2) to protect the surface of the fibers from being damaged; and (3) to separate the fibers and inhibit crack propagation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出聚合物基纤维增强复合材料中基体相的三个功能，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对聚合物基纤维增强复合材料中基体相功能的基本概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列出三个功能，但这些都是基础概念记忆层面的知识点，不需要复杂的分析或推理。学生只需回忆并准确描述聚合物基体相在纤维增强复合材料中的三个基本功能即可。相较于等级1的简单定义，该题目需要更多的概念解释和描述，但尚未达到等级3的复杂概念体系阐述水平。" + }, + { + "idx": 4537, + "question": "For a polymer-matrix fiber-reinforced composite, compare the desired mechanical characteristics of matrix and fiber phases.", + "answer": "The matrix phase must be ductile and is usually relatively soft, whereas the fiber phase must be stiff and strong.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较和描述聚合物基纤维增强复合材料中基体和纤维相的机械特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对聚合物基纤维增强复合材料中基体和纤维相所需机械性能的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和比较两种不同相（matrix和fiber）的机械特性，而不仅仅是简单的定义回忆。正确选项要求考生能够区分和描述matrix和fiber的机械特性，这比单纯记忆定义稍微复杂一些，但不需要复杂的分析或推理步骤。因此，难度等级为2。" + }, + { + "idx": 4538, + "question": "For a polymer-matrix fiber-reinforced composite, cite two reasons why there must be a strong bond between fiber and matrix at their interface.", + "answer": "There must be a strong interfacial bond between fiber and matrix in order to: (1) maximize the stress transmittance between matrix and fiber phases; and (2) minimize fiber pull-out, and the probability of failure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个原因，并需要文字解释和论述，答案也是以文字形式给出解释，符合简答题的特征。 | 知识层次: 题目考查对纤维增强复合材料中纤维与基体界面结合作用的基本原理的记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并记忆两个具体的理由（应力传递和最小化纤维拔出），而不仅仅是简单的定义或分类。这要求考生对纤维增强复合材料界面结合的重要性有较深入的理解，而不仅仅是表面记忆。因此，相较于仅需记忆单一概念的题目（等级1），该题目难度稍高，但尚未达到需要阐述复杂概念体系的等级3。" + }, + { + "idx": 4539, + "question": "What is the distinction between matrix and dispersed phases in a composite material?", + "answer": "The matrix phase is a continuous phase that surrounds the noncontinuous dispersed phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对复合材料中的基体和分散相进行区分和解释，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查复合材料中基体相和分散相的基本定义和区别，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅要求识别和记忆复合材料中基体相和分散相的基本定义和区别。正确选项直接给出了明确的定义描述，无需进行复杂的分析或推理。这属于最基础的概念记忆层次，符合等级1的难度标准。" + }, + { + "idx": 4540, + "question": "Contrast the mechanical characteristics of matrix and dispersed phases for fiber-reinforced composites.", + "answer": "In general, the matrix phase is relatively weak, has a low elastic modulus, but is quite ductile. On the other hand, the fiber phase is normally quite strong, stiff, and brittle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对比纤维增强复合材料中基体和分散相的力学特性，需要文字解释和论述，而不是选择、判断或计算。答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对纤维增强复合材料中基体和分散相机械特性的基本概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生对比纤维增强复合材料中基体和分散相的机械特性。虽然涉及两个相的特性描述，但知识点较为基础，属于概念解释和描述的层次。解题步骤相对简单，只需记忆并区分基体和纤维相的基本特性即可，无需复杂的分析或推导。因此，在选择题型内属于中等偏下的难度。" + }, + { + "idx": 4541, + "question": "Briefly explain the difference between oxidation and reduction electrochemical reactions.", + "answer": "Oxidation is the process by which an atom gives up an electron (or electrons) to become a cation. Reduction is the process by which an atom acquires an extra electron (or electrons) and becomes an anion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释氧化和还原电化学反应的区别，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查氧化和还原反应的基本定义和区别，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目要求考生解释氧化和还原电化学反应的基本区别，涉及两个相关概念的定义和对比。虽然需要理解并区分两个概念，但不需要复杂的分析或多步骤推理，属于概念解释和描述的难度层次。" + }, + { + "idx": 4542, + "question": "Which reaction occurs at the anode and which at the cathode?", + "answer": "Oxidation occurs at the anode; reduction at the cathode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释阳极和阴极发生的反应，需要用文字描述氧化和还原反应的位置，属于需要文字解释的简答题类型。 | 知识层次: 题目考查电化学中阳极和阴极反应的基本概念记忆，即氧化反应发生在阳极，还原反应发生在阴极。这是基础的定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即阳极和阴极上发生的反应类型（氧化和还原）。不需要复杂的推理或分析，只需直接回忆定义即可选择正确答案。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4543, + "question": "(a) Write the possible oxidation and reduction half-reactions that occur when magnesium is immersed in each of the following solutions: (i) HCl", + "answer": "In HCl, possible reactions are Mg -> Mg2+ + 2 e- (oxidation) and 2 H+ + 2 e- -> H2 (reduction).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出可能的氧化和还原半反应，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查的是基本的氧化还原反应记忆和理解，涉及简单的半反应书写，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求写出镁在HCl溶液中的氧化和还原半反应，属于基础概念记忆的范畴。学生只需回忆并写出基本的化学反应方程式，无需进行复杂的分析或推理。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4544, + "question": "(a) Write the possible oxidation and reduction half-reactions that occur when magnesium is immersed in each of the following solutions: (ii) an HCl solution containing dissolved oxygen", + "answer": "In an HCl solution containing dissolved oxygen, possible reactions are Mg -> Mg2+ + 2 e- (oxidation) and 4 H+ + O2 + 4 e- -> 2 H2O (reduction).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出可能的氧化和还原半反应，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求考生理解镁在含氧HCl溶液中的氧化还原反应，需要结合电化学基本原理（氧化和还原半反应）和具体环境（含氧酸性溶液）进行分析。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解氧化还原反应的基本概念，并能正确识别和写出镁在含氧HCl溶液中的氧化和还原半反应。虽然不涉及多步计算，但需要对不同条件下的反应有综合分析能力，并能将概念关联起来。" + }, + { + "idx": 4546, + "question": "(b) In which of these solutions would you expect the magnesium to oxidize most rapidly? Why?", + "answer": "The magnesium would probably oxidize most rapidly in the HCl solution containing dissolved oxygen and Fe2+ ions because there are two reduction reactions that will consume electrons from the oxidation of magnesium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么镁在特定溶液中会最快氧化，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目要求学生理解镁的氧化过程，并分析不同溶液中氧化速率的差异。需要综合运用电化学知识（氧化还原反应）和溶液化学知识（溶解氧和Fe2+离子的影响），属于多概念关联和综合分析层次。虽然不涉及复杂计算，但需要对反应机理有一定理解。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求理解镁的氧化过程，还需要综合分析两种还原反应（溶解氧和Fe2+离子）对氧化速率的影响。解题时需要关联多个概念（氧化还原、反应动力学、离子效应）并进行多角度分析，这超出了基础识记或简单应用的范畴。虽然题目提供了正确选项的解释，但要在选择题中准确识别这种复杂情境下的最优解，仍然需要较强的综合分析能力。" + }, + { + "idx": 4547, + "question": "Demonstrate that the value of F in Equation 17.19 is 96,500 C/mol.", + "answer": "The faraday constant F is 96,500 C/mol.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来证明法拉第常数的值，而不是进行数值计算或选择选项。答案提供了明确的陈述，但需要进一步的解释和推导过程来支持这一结论。 | 知识层次: 题目考查法拉第常数的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆法拉第常数的具体数值（96,500 C/mol），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或分析步骤，因此属于最低难度等级。" + }, + { + "idx": 4548, + "question": "Demonstrate that at 25 C (298 K), (RT)/(nF) ln x = (0.0592)/(n) log x.", + "answer": "At 25 C (298 K), (RT)/(nF) ln x = (0.0592)/(n) log x. This gives units in volts since a volt is a J/C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来证明一个等式，答案提供了详细的推导和单位说明，符合简答题的特征。 | 知识层次: 题目要求将给定的公式在特定温度下进行转换和验证，涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目仅要求直接套用基本公式进行简单计算，无需复杂的分析或推理过程。正确选项已经提供了完整的公式和单位说明，考生只需确认其正确性即可。" + }, + { + "idx": 4549, + "question": "Is a voltage generated between the two cell halves of a Zn/Zn2+ concentration cell where both electrodes are pure zinc, with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "Yes, a voltage is generated.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（是否会产生电压），答案直接给出了\"是\"或\"否\"的判断，符合判断题的特征。 | 知识层次: 题目考查对浓度电池基本原理的理解和简单应用，需要知道浓度差会产生电压，但不需要复杂的计算或多步推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需判断浓度差是否会产生电压，无需复杂计算或公式推导。考生只需理解浓度电池的基本原理即可直接选择正确选项，属于选择题型中的基础难度。" + }, + { + "idx": 4550, + "question": "What is the magnitude of the voltage generated in the Zn/Zn2+ concentration cell with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "The magnitude of the voltage is 0.0592 v.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Zn/Zn2+浓度电池的电压大小，需要使用能斯特方程等公式进行数值计算，答案是一个具体的数值结果（0.0592 v），符合计算题的特征。 | 知识层次: 题目考查的是浓度电池电压的计算，需要应用能斯特方程进行简单的数值计算，属于基本公式的直接应用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅要求应用Nernst方程的基本形式来计算浓度电池的电压，且给定的浓度差异直接可代入公式得出结果，无需复杂的推导或多步骤计算。" + }, + { + "idx": 4551, + "question": "Which electrode will be oxidized in the Zn/Zn2+ concentration cell with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "The electrode in the cell half with the Zn2+ concentration of 10^-2 M will be oxidized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释哪个电极会被氧化，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解浓度电池的工作原理，并应用能斯特方程的概念来判断电极的氧化倾向。虽然不涉及复杂的计算，但需要将多个概念（如氧化还原、浓度梯度）关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解浓度对电极电势的影响，并应用能斯特方程进行综合分析。虽然题目给出了具体浓度值，但仍需考生掌握氧化还原反应的基本原理和浓度电池的工作机制，进行多步推理才能得出正确结论。" + }, + { + "idx": 4552, + "question": "A piece of corroded steel plate was found in a submerged ocean vessel. It was estimated that the original area of the plate was 10 in^{2} and that approximately 2.6kg had corroded away during the submersion. Assuming a corrosion penetration rate of 200 \\mathrm{mpy} for this alloy in seawater, estimate the time of submersion in years. The density of steel is 7.9g / {cm}^{3}.", + "answer": "the time of submersion is 10 \\mathrm{yr}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及腐蚀速率、密度和面积等参数的运算，最终要求计算时间，答案也是具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括腐蚀速率、质量损失和面积的关系，以及单位转换等。虽然不涉及复杂的机理分析或创新设计，但需要综合应用多个概念和公式进行计算，思维过程有一定的深度要求。 | 难度: 在选择题中属于中等难度，需要理解腐蚀速率、密度和面积的关系，并进行多步计算。题目涉及单位转换（mpy到cm/yr，kg到g，in²到cm²）和综合运用密度公式（质量=密度×体积）来求解时间。虽然计算步骤较多，但在选择题型中通过选项可以验证结果，降低了部分难度。" + }, + { + "idx": 4553, + "question": "A thick steel sheet of area 400 cm^{2} is exposed to air near the ocean. After a one-year period it was found to experience a weight loss of 375g due to corrosion. To what rate of corrosion, in both mpy and mm / \\mathrm{yr}, does this correspond?", + "answer": "the corrosion rate is 1.2mm / \\mathrm{yr}. the corrosion rate is 46.7 \\mathrm{mpy}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解腐蚀速率，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位转换和公式应用（如腐蚀速率的计算），并需要理解腐蚀速率的不同单位（mpy和mm/yr）之间的转换关系。虽然不涉及复杂的综合分析或推理，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解腐蚀速率的概念，并进行多步单位换算和计算。题目涉及面积、重量损失和时间的关系，需要将克转换为毫米/年和mpy（密耳每年），这要求考生掌握相关公式和单位转换技巧。虽然题目提供了所有必要信息，但计算过程较为复杂，需要综合应用多个知识点。" + }, + { + "idx": 4554, + "question": "Cite the major differences between activation and concentration polarizations.", + "answer": "Activation polarization is the condition wherein a reaction rate is controlled by one step in a series of steps that takes place at the slowest rate. For corrosion, activation polarization is possible for both oxidation and reduction reactions. Concentration polarization occurs when a reaction rate is limited by diffusion in a solution. For corrosion, concentration polarization is possible only for reduction reactions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述激活极化和浓度极化的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对激活极化和浓度极化这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生能够解释和描述两个相关但不同的概念（激活极化和浓度极化），并指出它们在腐蚀反应中的具体应用差异。虽然涉及多个概念，但题目提供了明确的定义和区分点，不需要进行复杂的推导或综合分析，属于概念解释和描述层次的难度。" + }, + { + "idx": 4555, + "question": "Under what conditions is activation polarization rate controlling?", + "answer": "Activation polarization is rate controlling when the reaction rate is low and/or the concentration of active species in the liquid solution is high.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么条件下活化极化是速率控制步骤，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求理解活化极化控制速率的条件，涉及反应速率和活性物种浓度的综合分析，需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及激活极化在特定条件下的控制作用，要求考生能够综合理解反应速率和活性物种浓度之间的关系，并进行概念关联。虽然不需要多步计算，但需要对电化学动力学有较好的掌握，属于中等应用层次的知识点。" + }, + { + "idx": 4556, + "question": "Under what conditions is concentration polarization rate controlling?", + "answer": "Concentration polarization is rate controlling when the reaction rate is high and/or the concentration of active species in the liquid solution is low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么条件下浓度极化是速率控制步骤，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解浓度极化的控制条件，并分析反应速率和活性物种浓度之间的关系，属于中等应用层次，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解浓度极化和反应速率之间的关系，并综合分析高反应速率和低活性物种浓度的影响。虽然不涉及多步计算，但需要对概念进行关联和综合分析。" + }, + { + "idx": 4557, + "question": "Assuming that activation polarization controls both oxidation and reduction reactions, determine the rate of corrosion of metal M (in mol/cm2-s) given the following corrosion data: For Metal M: V(M/M2+)=-0.47 V, i0=5x10-10 A/cm2, β=+0.15; For Hydrogen: V(H+/H2)=0 V, i0=2x10-9 A/cm2, β=-0.12.", + "answer": "the rate of corrosion of metal m is 2.64x10-13 mol/cm2-s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的腐蚀数据和公式计算金属M的腐蚀速率，答案是一个具体的数值结果，需要通过数值计算和公式应用来得出。 | 知识层次: 题目需要应用腐蚀电化学中的活化极化理论，涉及多个参数的综合计算（交换电流密度、塔菲尔斜率等），并需要通过平衡电位和极化曲线来确定腐蚀速率。这需要理解相关概念并进行多步计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解腐蚀动力学中的活化极化概念，掌握交换电流密度和塔菲尔斜率的应用，并进行多步计算（包括平衡电位计算、腐蚀电流密度求解以及单位转换）。虽然题目提供了所有必要参数，但需要综合运用电化学知识才能正确求解腐蚀速率。" + }, + { + "idx": 4558, + "question": "Compute the corrosion potential for this reaction given the following corrosion data: For Metal M: V(M/M2+)=-0.47 V, i0=5x10-10 A/cm2, β=+0.15; For Hydrogen: V(H+/H2)=0 V, i0=2x10-9 A/cm2, β=-0.12.", + "answer": "the corrosion potential for this reaction is -0.169 v.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的腐蚀数据（电位、交换电流密度、塔菲尔斜率）进行数值计算，应用电化学腐蚀相关公式来求解腐蚀电位。答案是一个具体的数值（-0.169 V），这表明解答过程涉及计算步骤和公式应用，而非选择、判断或文字解释。 | 知识层次: 题目需要应用腐蚀电化学的基本公式进行多步计算，涉及腐蚀电位计算、交换电流密度和塔菲尔斜率的应用，需要综合分析金属和氢电极的反应参数，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解腐蚀电位的计算原理，综合运用能斯特方程和塔菲尔方程进行多步计算，并正确关联金属和氢的不同电化学参数。虽然选择题型提供了正确选项，但解题过程涉及多个变量和概念的综合分析，对学生的应用能力要求较高。" + }, + { + "idx": 4559, + "question": "Briefly describe the phenomenon of passivity.", + "answer": "Passivity is the loss of chemical reactivity, under particular environmental conditions, of normally active metals and alloys.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述钝化现象，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对\"passivity\"这一基础概念的定义和基本理解，属于记忆性知识范畴 | 难度: 在选择题型中，该题目仅要求考生记忆并复述\"passivity\"的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了现象的简单定义，没有涉及复杂解释或与其他概念的关联分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4560, + "question": "Name two common types of alloy that passivate.", + "answer": "Stainless steels and aluminum alloys often passivate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两种常见的钝化合金类型，答案需要提供具体的合金名称，属于需要文字回答的简答题类型。 | 知识层次: 题目考查对合金钝化现象的基础概念记忆，仅需列举常见的钝化合金类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆两种常见的钝化合金类型（不锈钢和铝合金），属于基础概念记忆层次。题目不涉及概念解释或复杂体系分析，仅需简单回忆知识点即可作答，因此属于最低难度等级。" + }, + { + "idx": 4561, + "question": "Why does chromium in stainless steels make them more corrosion resistant in many environments than plain carbon steels?", + "answer": "The chromium in stainless steels causes a very thin and highly adherent surface coating to form over the surface of the alloy, which protects it from further corrosion. For plain carbon steels, rust, instead of this adherent coating, forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释铬在不锈钢中的作用机制，答案需要文字解释和论述，没有提供选项或要求计算。 | 知识层次: 题目要求解释铬在不锈钢中提高耐腐蚀性的机理，涉及表面涂层形成和保护作用的综合分析，需要理解合金元素的作用机制及其与腐蚀行为的关系，属于较深层次的机理解释和推理分析。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解铬在不锈钢中的作用，还需要掌握其具体机理（形成薄而紧密的表面涂层），并能与普通碳钢的腐蚀机制进行对比分析。这需要考生具备材料科学中腐蚀防护的深层机理知识，并能综合运用这些知识解释复杂现象。题目涉及的知识点掌握深度要求较高，解题时需要结合多个概念进行推理分析，因此属于选择题型中较难的题目。" + }, + { + "idx": 4562, + "question": "Briefly explain why cold-worked metals are more susceptible to corrosion than noncold-worked metals.", + "answer": "Cold-worked metals are more susceptible to corrosion than noncold-worked metals because of the increased dislocation density for the latter. The region in the vicinity of a dislocation that intersects the surface is at a higher energy state, and, therefore, is more readily attacked by a corrosive solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释冷加工金属比非冷加工金属更容易腐蚀的原因，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释冷加工金属更易腐蚀的机理，涉及位错密度与腐蚀敏感性的关联分析，需要理解位错与表面能状态的关系，并运用材料科学原理进行推理解释，属于机理层面的复杂分析。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解冷加工金属的基本特性，还需要掌握位错密度与腐蚀敏感性的内在机理关系。正确选项涉及材料科学中的微观结构（位错）与宏观性能（腐蚀）的关联性解释，需要考生具备将抽象理论转化为具体现象分析的能力。这种在选择题中要求机理深度解释的题目，比单纯记忆概念或简单应用公式的题目难度更高，属于选择题型中的较难水平。" + }, + { + "idx": 4563, + "question": "Briefly explain why, for a small anode-to-cathode area ratio, the corrosion rate will be higher than for a large ratio.", + "answer": "For a small anode-to-cathode area ratio, the corrosion rate will be higher than for A large ratio. The reason for this is that for some given current flow associated with the corrosion reaction, for a small area ratio the current density at the anode will be greater than for a large ratio. The corrosion rate is proportional to the current density (i) according to Equation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释为什么小阳极-阴极面积比会导致更高的腐蚀速率，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解阳极-阴极面积比对腐蚀速率的影响机制，并运用电流密度的概念进行解释，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解阳极-阴极面积比的概念，并能将其与电流密度和腐蚀速率的关系联系起来进行分析。题目要求考生能够综合应用电化学腐蚀的基本原理，但不需要进行复杂的多角度或深度关联性分析。" + }, + { + "idx": 4564, + "question": "What are inhibitors?", + "answer": "Inhibitors are substances that, when added to a corrosive environment in relatively low concentrations, decrease the environment's corrosiveness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"inhibitors\"进行文字解释和论述，答案是一个完整的定义性陈述，不需要选择、判断或计算 | 知识层次: 题目考查对抑制剂这一基本概念的定义和简单理解，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别抑制剂的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的简单描述，不需要进行比较分析或复杂推理，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 4565, + "question": "What possible mechanisms account for their effectiveness?", + "answer": "Possible mechanisms that account for the effectiveness of inhibitors are: (1) elimination of a chemically active species in the solution; (2) attachment of inhibitor molecules to the corroding surface so as to interfere with either the oxidation or reduction reaction; and (3) the formation of a very thin and protective coating on the corroding surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释可能的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释抑制剂有效性的可能机制，涉及多个复杂机理的分析和综合理解，需要将不同机制关联起来进行推理和解释，思维过程深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用材料科学知识，深入理解腐蚀抑制剂的三种作用机理，并能解释其有效性。这需要考生具备复杂现象全面分析的能力，包括：" + }, + { + "idx": 4566, + "question": "Briefly describe the sacrificial anode technique used for galvanic protection.", + "answer": "A sacrificial anode is electrically coupled to the metal piece to be protected, which anode is also situated in the corrosion environment. The sacrificial anode is a metal or alloy that is chemically more reactive in the particular environment. It (the anode) preferentially oxidizes, and, upon giving up electrons to the other metal, protects it from electrochemical corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述牺牲阳极技术用于电化学保护的原理，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对牺牲阳极技术的基本概念和原理的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生不仅要记住牺牲阳极的定义，还需要理解其工作原理和应用场景。正确选项中对牺牲阳极的描述较为详细，包括其电耦合方式、化学活性优先氧化等关键点，这比简单的定义记忆要求更高，属于概念解释和描述的层次。" + }, + { + "idx": 4567, + "question": "Briefly describe the impressed current technique used for galvanic protection.", + "answer": "An impressed current from an external dc power source provides excess electrons to the metallic structure to be protected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述一种技术（impressed current technique），答案以文字解释的形式给出，符合简答题的特征。 | 知识层次: 题目考查对电化学保护技术中\"外加电流法\"基本概念的记忆和理解，仅需描述其基本原理和外部电源的作用，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别关于外加电流阴极保护技术的基本定义和原理。正确选项直接给出了该技术的核心概念描述，不需要进行复杂的分析或比较。这属于最基础的概念记忆层次，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4568, + "question": "Compute the electrical conductivity of a 5.1-mm (0.2-in.) diameter cylindrical silicon specimen 51mm (2 in.) long in which a current of 0.1 A passes in an axial direction. A voltage of 12.5V is measured across two probes that are separated by 38mm (1.5 in.).", + "answer": "the electrical conductivity is σ = 14.9 (ω·m)^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解硅圆柱体的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式（电导率公式）的直接应用和简单计算，不需要多步推理或综合分析，属于基础知识的直接运用层面。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算电导率，只需要直接应用电导率的基本公式σ = (I × L) / (V × A)，其中I是电流，L是长度，V是电压，A是横截面积。所有需要的参数都已直接给出，无需额外的推导或组合多个公式。计算过程简单直接，属于基础知识的简单应用。" + }, + { + "idx": 4569, + "question": "Compute the resistance over the entire 51mm (2 in.) of the specimen.", + "answer": "the resistance is r = 168 ω.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（Compute the resistance），并且答案给出了具体的数值结果（r = 168 ω），这符合计算题的特征。 | 知识层次: 题目要求进行基本的电阻计算，仅涉及单一公式的直接应用和简单数值计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算电阻，仅需直接套用基本公式（如欧姆定律或电阻公式）并进行简单计算即可得出答案。无需多个公式组合或复杂步骤，符合等级1的定义。" + }, + { + "idx": 4570, + "question": "Calculate the drift velocity of electrons in germanium at room temperature and when the magnitude of the electric field is 1000 V/m.", + "answer": "the drift velocity of electrons in germanium is 380 m/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算电子的漂移速度），并给出了具体的电场强度条件。答案是一个具体的数值结果（380 m/s），这表明解答过程需要应用相关公式和计算步骤。 | 知识层次: 题目要求计算电子在锗中的漂移速度，涉及基本公式应用（如漂移速度公式）和简单计算（给定电场强度下的数值计算），属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式计算电子的漂移速度，属于单一公式直接计算的简单应用层次。解题步骤简单，无需复杂的分析或组合多个公式，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 4571, + "question": "Under these circumstances, how long does it take an electron to traverse a 25-mm (1-in.) length of crystal?", + "answer": "the time required for an electron to traverse a 25-mm length of crystal is 6.6 × 10^-5 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算电子通过25毫米晶体所需的时间，答案给出了具体的数值计算结果（6.6 × 10^-5 s），这表明需要进行数值计算和公式应用。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需直接套用公式计算电子穿越晶体所需时间，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接计算，即计算电子通过给定长度晶体所需的时间。题目明确给出了正确选项，且解题步骤简单，仅需套用基本公式进行简单计算即可得出答案。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4572, + "question": "At room temperature the electrical conductivity and the electron mobility for copper are 6.0 x 10^7 (Ω·m)^-1 and 0.0030 m^2/V·s, respectively. Compute the number of free electrons per cubic meter for copper at room temperature.", + "answer": "the number of free electrons per cubic meter for copper at room temperature is 1.25 x 10^29 m^-3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率和电子迁移率数据，应用相关公式计算铜在室温下的自由电子数密度。解答过程涉及数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的电导率公式（σ = n e μ）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（电导率与电子迁移率和自由电子浓度的关系公式）进行计算，无需复杂的推导或多步骤组合。题目提供了所有必要的数据，且计算过程简单直接，属于单一公式直接计算的难度等级。" + }, + { + "idx": 4573, + "question": "At room temperature the electrical conductivity and the electron mobility for copper are 6.0 x 10^7 (Ω·m)^-1 and 0.0030 m^2/V·s, respectively. What is the number of free electrons per copper atom? Assume a density of 8.9 g/cm^3.", + "answer": "the number of free electrons per copper atom is 1.48.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铜原子中自由电子的数量，答案是一个具体的数值（1.48），这表明解答过程涉及计算步骤和物理公式的应用。 | 知识层次: 题目需要进行多步计算，包括电导率、电子迁移率和自由电子密度的关联计算，同时需要结合铜的密度和原子量进行综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解电导率、电子迁移率、自由电子密度等多个概念，并进行多步计算（包括单位转换、密度计算、原子量应用等）。虽然题目提供了部分数据，但解题过程涉及多个物理量的综合运用，超出了基础选择题的范畴。" + }, + { + "idx": 4574, + "question": "At room temperature the electrical conductivity of \\mathrm{PbTe} is 500(\\Omega·m)^{-1}, whereas the electron and hole mobilities are 0.16 and 0.075{m}^{2} / V·s, respectively. Compute the intrinsic carrier concentration for \\mathrm{PbTe} at room temperature.", + "answer": "the intrinsic carrier concentration for \\mathrm{pbte} at room temperature is 1.33 × 10^{22}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（电导率、载流子迁移率与载流子浓度的关系）来求解本征载流子浓度，答案是一个具体的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，即通过给定的电导率、电子和空穴迁移率来计算本征载流子浓度。虽然需要理解相关概念，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要学生掌握基本的电导率与载流子浓度关系公式（σ = n·e·(μ_e + μ_h)），并进行简单的代数运算来求解本征载流子浓度。虽然涉及物理概念的理解，但计算步骤直接且无需复杂推导，属于选择题中中等偏下的难度。" + }, + { + "idx": 4575, + "question": "Define the term 'intrinsic' as it pertains to semiconducting materials and provide an example.", + "answer": "intrinsic--high purity (undoped) Si, GaAs, CdS, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对'intrinsic'这一基本术语的定义及其在半导体材料中的具体示例的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求对\"intrinsic\"这一基础术语进行定义记忆，并列举常见示例材料。题目仅涉及单一概念的直接回忆，不需要解释或比较分析，属于最基本的概念记忆层次。正确选项直接给出了定义和典型示例，作答时只需识别匹配即可，解题步骤极为简单。" + }, + { + "idx": 4576, + "question": "Define the term 'extrinsic' as it pertains to semiconducting materials and provide an example.", + "answer": "extrinsic--P-doped Ge, B-doped Si, S-doped GaP, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述 | 知识层次: 题目考查对\"extrinsic\"这一基本术语的定义记忆，以及通过举例说明的理解能力，属于半导体材料的基础概念范畴。 | 难度: 在选择题型中，该题目仅要求记忆并选择\"extrinsic\"的定义和相关示例（如P-doped Ge等），属于基础概念记忆层次。题目不涉及解释或复杂概念体系，只需识别正确选项即可，因此属于最简单的等级1难度。" + }, + { + "idx": 4577, + "question": "Define the term 'compound' as it pertains to semiconducting materials and provide an example.", + "answer": "compound--GaAs, InP, CdS, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述，答案形式为简短的文字说明加示例，符合简答题的特征。 | 知识层次: 题目考查对半导体材料中\"化合物\"这一基本概念的定义记忆和简单举例，属于基础概念记忆范畴，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别半导体材料中\"compound\"的基本定义和典型例子（如GaAs、InP等）。题目属于基础概念记忆层次，无需解释或分析，只需从给定选项中识别正确答案，因此属于最简单的等级1难度。" + }, + { + "idx": 4578, + "question": "Define the term 'elemental' as it pertains to semiconducting materials and provide an example.", + "answer": "elemental--Ge and Si.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定义术语并提供例子，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对\"elemental\"这一基本术语的定义记忆和简单举例，属于基础概念的记忆性知识范畴 | 难度: 在选择题型中，该题目仅要求考生记忆并选择正确的元素示例（Ge和Si），属于基础概念记忆层次。题目不涉及解释或复杂概念体系，仅需简单回忆半导体材料的基本定义和分类，因此属于最低难度等级。" + }, + { + "idx": 4579, + "question": "Explain why no hole is generated by the electron excitation involving a donor impurity atom.", + "answer": "No hole is generated by an electron excitation involving a donor impurity atom because the excitation comes from a level within the band gap, and thus, no missing electron is created within the normally filled valence band.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在涉及施主杂质原子的电子激发过程中不会产生空穴，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释电子激发过程中空穴不产生的原因，涉及能带理论、杂质能级和电子跃迁机理的综合分析，需要深入理解半导体物理中的相关概念并进行逻辑推理。 | 难度: 在选择题中属于最高难度等级，题目要求深入理解半导体物理中的杂质能级和电子激发机制，需要综合运用能带理论、掺杂效应和载流子生成原理进行复杂分析。正确选项涉及从带隙内能级激发的特殊性质，以及价带完整性保持的机理解释，这超出了基础概念记忆和简单应用层面，属于需要全面分析复杂现象的题目类型。" + }, + { + "idx": 4580, + "question": "Explain why no free electron is generated by the electron excitation involving an acceptor impurity atom.", + "answer": "No free electron is generated by an electron excitation involving an acceptor impurity atom because the electron is excited from the valence band into the impurity level within the band gap; no free electron is introduced into the conduction band.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在涉及受主杂质原子的电子激发过程中不会产生自由电子，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释电子激发过程中自由电子未产生的原因，涉及价带、杂质能级和导带之间的电子跃迁机制，需要综合运用半导体物理知识进行推理分析，属于对材料科学中掺杂效应的深度理解。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解半导体物理中的杂质能级和电子激发机制，需要综合运用能带理论、杂质态特性以及电子跃迁原理进行复杂分析。正确选项不仅涉及多个关键概念（价带、导带、杂质能级），还需要准确描述电子激发路径的限定条件（不进入导带）。这种题目在选择题中需要考生具备机理深度解释和复杂现象全面分析的能力，远超简单记忆或基础理解的层次。" + }, + { + "idx": 4581, + "question": "Germanium to which 5 × 10^22 m^-3 Sb atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the Sb atoms may be thought of as being ionized (i.e., one charge carrier exists for each Sb atom). Is this material n-type or p-type?", + "answer": "this germanium material to which has been added 5 × 10^22 m^-3 sb atoms is n-type since sb is a donor in ge.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来判断材料的类型（n-type或p-type），而不是从多个选项中选择、判断对错或进行数值计算。答案也以文字解释的形式给出。 | 知识层次: 题目考查对半导体掺杂类型的基本概念的理解，即施主掺杂（Sb）导致n型半导体。这属于基础概念的记忆和理解，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅需要考生记忆基本的半导体类型分类知识，即知道锑（Sb）在锗（Ge）中是施主杂质，因此掺杂后形成n型半导体。不需要进行复杂的分析或推理，属于最基础的定义记忆类题目。" + }, + { + "idx": 4582, + "question": "Germanium to which 5 × 10^22 m^-3 Sb atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the Sb atoms may be thought of as being ionized (i.e., one charge carrier exists for each Sb atom). Calculate the electrical conductivity of this material, assuming electron and hole mobilities of 0.1 and 0.05 m^2/V-s, respectively.", + "answer": "the electrical conductivity of this material is 800 (ω·m)^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锗材料的电导率，答案是一个具体的数值结果，解答过程涉及电子和空穴迁移率的计算。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的掺杂浓度和载流子迁移率直接计算电导率，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目给出了所有必要的参数（掺杂浓度、载流子迁移率），并明确指出可以假设所有掺杂原子都已电离。因此，只需要直接应用电导率公式σ = n * e * μ（其中n是载流子浓度，e是电子电荷，μ是迁移率）进行计算即可。不需要额外的推导或复杂步骤，属于最基本的公式应用类型。" + }, + { + "idx": 4583, + "question": "The following electrical characteristics have been determined for both intrinsic and p-type extrinsic indium phosphide ( \\mathrm{InP} ) at room temperature:\n\\begin{tabular}{lccc}\n\\hline & \\boldsymbol{\\sigma}\\left(\\boldsymbol{\\Omega}·\\mathbf{m}\\right)^{-1} & \\mathbf{n}\\left(\\mathbf{m}^{-3}\\right) & \\mathbf{p}\\left(\\mathbf{m}^{-3}\\right) \\\\\n\\hline Intrinsic & 2.5 × 10^{-6} & 3.0 × 10^{13} & 3.0 × 10^{12} \\\\\nExtrinsic (n-type) & 3.6 × 10^{-5} & 4.5 × 10^{14} & 2.0 × 10^{12} \\\\\n\\hline\n\\end{tabular}\nCalculate electron and hole mobilities.", + "answer": "the electron and hole mobilities for \\mathrm{inp} are \\mu_{e} = 0.50 \\, m^{2}/\\mathrm{v}\\cdots and \\mu_{h} = 0.02 \\, m^{2}/\\mathrm{v}\\cdots.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率、电子浓度和空穴浓度数据，应用相关公式计算电子和空穴的迁移率。解答过程涉及数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目要求使用基本的电导率公式（σ = n·e·μ）进行简单的数值计算，属于直接套用公式和基本计算的应用层次，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用电导率公式（σ = n·e·μ），但题目已经提供了所有必要的数据（σ、n、p），只需直接代入公式进行简单计算即可得到电子和空穴迁移率。不需要多个公式组合或复杂推导，属于基础知识的直接应用。" + }, + { + "idx": 4584, + "question": "Some metal alloy is known to have electrical conductivity and electron mobility values of 1.5 × 10^{7} (\\Omega·m)^{-1} and 0.0020{m}^{2} / V·s, respectively. Through a specimen of this alloy that is 35mm thick is passed a current of 45 A. What magnetic field would need to be imposed to yield a Hall voltage of -1.0 × 10^{-7}V ?", + "answer": "the required magnetic field is 0.58 \\mathrm{tesla}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的磁场强度，答案是一个具体的数值结果（0.58 tesla），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用电导率、电子迁移率、电流密度和霍尔效应等知识，通过公式推导和数值计算得出结果，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用电导率、电子迁移率、霍尔效应等多个物理概念，并进行多步骤计算。虽然题目提供了正确选项，但解题过程涉及多个公式转换和单位换算（如厚度单位转换），需要较强的综合分析能力。相比单纯的概念选择题，这类计算型选择题对知识掌握深度和计算准确性要求更高。" + }, + { + "idx": 4585, + "question": "What is one function that a transistor may perform in an electronic circuit?", + "answer": "In an electronic circuit, a transistor may be used to amplify an electrical signal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体管在电子电路中的功能，答案是一个简短的文字解释，没有提供选项或需要计算。 | 知识层次: 题目考查晶体管在电子电路中的基本功能，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶体管的基本功能之一（信号放大），属于最基础的定义性知识。题目不涉及概念解释或复杂体系，仅需简单回忆即可作答，因此属于等级1难度。" + }, + { + "idx": 4586, + "question": "What is another function that a transistor may perform in an electronic circuit?", + "answer": "In an electronic circuit, a transistor may act as a switching device in computers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述晶体管在电子电路中的另一种功能，答案是一个简短的文字描述，没有提供选项或需要计算。 | 知识层次: 题目考查晶体管在电子电路中的基本功能，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆晶体管的基本功能之一（作为开关设备），属于最基础的定义性知识。题目不涉及概念解释或复杂体系，只需识别正确选项即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4587, + "question": "At temperatures between 775^{\\circ} C\\left(1048 K\\right) and 1100^{\\circ} C\\left(1373 K\\right), the activation energy and preexponential for the diffusion coefficient of \\mathrm{Fe}^{2+} in \\mathrm{FeO} are 102,000 J/ mol and 7.3 × 10^{-8}{m}^{2} / s, respectively. Compute the mobility for an \\mathrm{Fe}^{2+} ion at 1000^{\\circ} C(1273 K).", + "answer": "the mobility for an \\mathrm{fe}^{2+} ion at 1000^{\\circ} C (1273 k) is 8.64 × 10^{-11}{m}^{2} / \\mathrm{v}·s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和前置指数计算Fe2+离子在特定温度下的迁移率，需要使用公式进行数值计算。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用扩散系数公式和计算离子迁移率，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与迁移率的关系，并应用阿伦尼乌斯公式进行多步计算。题目涉及温度转换、激活能应用和单位换算，虽然计算步骤明确但需要较强的概念关联能力。" + }, + { + "idx": 4588, + "question": "A parallel-plate capacitor using a dielectric material having an \\varepsilon_{r} of 2.5 has a plate spacing of 1 mm (0.04 in.). If another material having a dielectric constant of 4.0 is used and the capacitance is to be unchanged, what must be the new spacing between the plates?", + "answer": "the new spacing between the plates must be 1.6 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来解决问题，涉及电容器的参数变化和计算新的板间距。答案是一个具体的数值结果（1.6 mm），而不是选择、判断或文字解释。 | 知识层次: 题目涉及基本的电容公式应用和简单计算，只需要理解电容与介电常数和板间距的关系，并进行一步计算即可得出结果。不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。题目要求考生理解平行板电容器的基本公式（C = εA/d），并能够根据给定的介电常数变化调整板间距以保持电容不变。虽然涉及两个不同的介电常数，但计算步骤直接且无需复杂的推导或分析，属于简单应用层次。" + }, + { + "idx": 4589, + "question": "(a) For each of the three types of polarization, briefly describe the mechanism by which dipoles are induced and/or oriented by the action of an applied electric field.", + "answer": "(a) For electronic polarization, the electric field causes a net displacement of the center of the negatively charged electron cloud relative to the positive nucleus. With ionic polarization, the cations and anions are displaced in opposite directions as a result of the application of an electric field. Orientation polarization is found in substances that possess permanent dipole moments; these dipole moments become aligned in the direction of the electric field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述三种极化类型的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对三种极化机制（电子极化、离子极化和取向极化）的基本概念和原理的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生简要描述三种极化机制，虽然涉及多个概念（电子极化、离子极化和取向极化），但每个概念的描述相对独立且基础，不需要复杂的分析或比较。正确选项提供了清晰的定义性描述，符合选择题型中对基础概念记忆和理解的要求。" + }, + { + "idx": 4590, + "question": "(b) For solid lead titanate (PbTiO3), gaseous neon, diamond, solid KCl, and liquid NH3 what kind(s) of polarization is (are) possible? Why?", + "answer": "(b) Electronic, ionic, and orientation polarizations would be observed in lead titanate. The lead, titanium, and oxygen would undoubtedly be largely ionic in character. Furthermore, orientation polarization is also possible inasmuch as permanent dipole moments may be induced in the same manner as for BaTiO3. Only electronic polarization is to be found in gaseous neon; being an inert gas, its atoms will not be ionized nor possess permanent dipole moments. Only electronic polarization is to be found in solid diamond; this material does not have molecules with permanent dipole moments, nor is it an ionic material. Both electronic and ionic polarizations will be found in solid KCl, since it is strongly ionic. In all probability, no permanent dipole moments will be found in this material. Both electronic and orientation polarizations are found in liquid NH3. The NH3 molecules have permanent dipole moments that are easily oriented in the liquid state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同物质可能存在的极化类型进行解释和论述，答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对不同材料的极化类型进行分析和解释，需要理解电子极化、离子极化和取向极化的基本原理，并将这些概念应用到具体的材料系统中。虽然不涉及复杂的计算或深度推理，但需要对多种材料的性质有综合理解，并能够关联不同极化类型与材料特性的关系。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生对多种材料的极化类型有深入理解，并能综合分析不同材料（如离子晶体、惰性气体、共价晶体、离子固体和极性液体）的极化机制。题目不仅涉及电子极化、离子极化和取向极化等基本概念，还需要考生能够将这些概念与具体材料特性关联起来，进行多角度分析。此外，题目还隐含了对材料化学键性质（如离子性、共价性）的理解要求，这增加了题目的复杂性和难度。" + }, + { + "idx": 4591, + "question": "For aluminum, the heat capacity at constant volume Cv at 30 K is 0.81 J/mol-K, and the Debye temperature is 375 K. Estimate the specific heat at 50 K.", + "answer": "the specific heat at 50 K is 139 J/kg-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出一个具体的数值结果（139 J/kg-K），这符合计算题的特征。 | 知识层次: 题目需要应用德拜模型和热容公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解德拜温度概念、热容与温度的关系，并进行多步计算。题目要求将摩尔热容转换为比热容，涉及单位换算和温度比例关系的应用，属于综合性计算问题。" + }, + { + "idx": 4592, + "question": "For aluminum, the heat capacity at constant volume Cv at 30 K is 0.81 J/mol-K, and the Debye temperature is 375 K. Estimate the specific heat at 425 K.", + "answer": "the specific heat at 425 K is 923 J/kg-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及热容量的估算和单位转换，答案是一个具体的数值结果。 | 知识层次: 题目需要应用德拜模型和热容公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解德拜温度的概念，掌握热容随温度变化的规律，并进行多步计算。题目涉及从已知的低温热容数据推导高温下的热容，需要综合运用德拜模型和经典热容理论，属于综合性计算问题。" + }, + { + "idx": 4593, + "question": "(a) Briefly explain why Cv rises with increasing temperature at temperatures near 0 K.", + "answer": "The reason that Cv rises with increasing temperature at temperatures near 0 K is because, in this temperature range, the allowed vibrational energy levels of the lattice waves are far apart relative to the available thermal energy, and only a portion of the lattice waves may be excited. As temperature increases, more of the lattice waves may be excited by the available thermal energy, and, hence, the ability of the solid to absorb energy (i.e., the magnitude of the heat capacity) increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释Cv在接近0 K时随温度升高的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Cv在接近0 K时随温度升高的原因，涉及晶格振动能级的激发和热能的相互作用，需要综合运用固体物理和热力学知识进行机理分析和推理。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶格振动的基本概念，还需要掌握在接近0K温度下量子化能级的热激发机制。正确选项涉及对固体热容随温度变化的微观机理的深入解释，需要综合运用统计物理和固体物理知识进行推理分析。这种复杂现象的解释在选择题型中属于对知识掌握深度和综合分析能力要求最高的类型。" + }, + { + "idx": 4594, + "question": "(b) Briefly explain why Cv becomes virtually independent of temperature at temperatures far removed from 0 K.", + "answer": "At temperatures far removed from 0 K, Cv becomes independent of temperature because all of the lattice waves have been excited and the energy required to produce an incremental temperature change is nearly constant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释Cv在远离0 K时几乎与温度无关的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Cv在远离0K温度下与温度无关的现象，这需要理解晶格波的激发机制和热容的量子理论，涉及较深层次的物理概念关联和机理解释，属于综合分析范畴。 | 难度: 在选择题型中，该题目要求考生不仅理解Cv（定容热容）的基本概念，还需要深入掌握晶格振动理论在温度远离绝对零度时的行为。正确选项涉及对晶格波激发状态的综合分析和机理解释，需要考生将多个物理概念（如热容、晶格振动、温度效应）联系起来进行推理。这种深度解释和综合运用能力在选择题中属于较高难度层次，对应知识层次中的\"复杂分析\"要求。" + }, + { + "idx": 4595, + "question": "A 0.1{m}(3.9 in.) rod of a metal elongates 0.2 mm(0.0079 in.) on heating from 20 to 100^{\\circ} C(68 \\mathrm{to} 212^{\\circ} F ). Determine the value of the linear coefficient of thermal expansion for this material.", + "answer": "the linear coefficient of thermal expansion for this material is 25.0 × 10^{-6} \\, (\\degree c)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（线性热膨胀系数公式）来确定材料的热膨胀系数，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的线性热膨胀系数公式应用，仅需一步计算即可得出结果，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算线性热膨胀系数，只需应用基本公式α = ΔL / (L0 × ΔT)，其中所有需要的数值都已直接给出（ΔL、L0、ΔT）。解题步骤简单，无需复杂推导或多公式组合，属于最基础的选择题难度。" + }, + { + "idx": 4596, + "question": "Briefly explain why the thermal conductivities are higher for crystalline than noncrystalline ceramics.", + "answer": "Thermal conductivities are higher for crystalline than for noncrystalline ceramics because, for noncrystalline, phonon scattering, and thus the resistance to heat transport, is much more effective due to the highly disordered and irregular atomic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释晶体陶瓷比非晶体陶瓷热导率高的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶体和非晶体陶瓷热导率差异的原因，涉及对声子散射和原子结构无序性的理解，需要综合分析材料微观结构与热传导性能之间的关系，属于机理解释和推理分析的层次。 | 难度: 在选择题型中，该题目属于较高难度等级。正确选项不仅要求考生理解晶体和非晶体陶瓷的基本区别，还需要掌握声子散射的概念及其对热导率的影响机制。题目涉及对材料微观结构与宏观性能关系的深入理解，需要考生能够将多个物理概念（晶体结构、声子传输、热导率）联系起来进行综合分析。这种需要解释物理机理的选择题，比单纯记忆事实或简单比较的选择题难度更高，属于复杂分析层次。" + }, + { + "idx": 4597, + "question": "Briefly explain why metals are typically better thermal conductors than ceramic materials.", + "answer": "Metals are typically better thermal conductors than are ceramic materials because, for metals, most of the heat is transported by free electrons (of which there are relatively large numbers). In ceramic materials, the primary mode of thermal conduction is via phonons, and phonons are more easily scattered than are free electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释金属比陶瓷材料导热性更好的原因，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释金属和陶瓷材料在热传导性能上的差异，涉及自由电子和声子两种不同的热传导机制，以及它们被散射的难易程度。这需要对材料的热传导机理有深入的理解和分析能力，属于对复杂概念的关联和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解金属和陶瓷材料的热传导机制差异，还需要掌握自由电子和声子在热传导中的作用原理。正确选项涉及对两种不同传导机制（电子传导 vs 声子传导）的比较分析，并需要理解散射效应对传导效率的影响。这种题目超越了简单的事实记忆，要求考生能够综合运用材料科学知识进行机理层面的解释，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 4598, + "question": "Briefly explain why porosity decreases the thermal conductivity of ceramic and polymeric materials, rendering them more thermally insulative.", + "answer": "Porosity decreases the thermal conductivity of ceramic and polymeric materials because the thermal conductivity of a gas phase that occupies pore space is extremely small relative to that of the solid material. Furthermore, contributions from gaseous convection are generally insignificant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释孔隙率如何降低陶瓷和聚合物材料的热导率，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释孔隙率如何降低陶瓷和聚合物材料的热导率，涉及对材料热传导机制的理解和概念关联，需要综合分析固体和气体相的热导率差异以及气体对流的影响。虽然不涉及复杂计算，但需要对多个概念进行关联和解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求解释孔隙率如何降低陶瓷和聚合物材料的热导率，涉及对气体相和固体材料热导率的比较，以及对气体对流贡献的理解。虽然不需要复杂的计算，但需要对相关概念有较深入的理解和综合分析能力。" + }, + { + "idx": 4599, + "question": "Briefly explain how the degree of crystallinity affects the thermal conductivity of polymeric materials and why.", + "answer": "Increasing the degree of crystallinity of a semicrystalline polymer enhances its thermal conductivity; the vibrations, rotations, etc. of the molecular chains are more effective modes of thermal transport when a crystalline structure prevails.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释结晶度对聚合物材料热导率的影响及其原因，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求解释结晶度对聚合物热导率的影响及其原因，涉及概念关联和综合分析，需要理解结晶结构对分子链振动和热传导的影响机制，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解结晶度与热导率之间的关系，并能够解释分子链振动、旋转等行为在晶体结构中对热传导的影响。虽然不涉及多步计算，但需要对概念进行关联和综合分析。" + }, + { + "idx": 4600, + "question": "For some ceramic materials, why does the thermal conductivity first decrease and then increase with rising temperature?", + "answer": "For some ceramic materials, the thermal conductivity first decreases with rising temperature because the scattering of lattice vibrations increases with temperature. At higher temperatures, the thermal conductivity will increase for some ceramics that are porous because radiant heat transfer across pores may become important, which process increases with rising temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷材料热导率随温度变化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷材料热导率随温度变化的复杂行为，涉及晶格振动散射和辐射传热两种机制的相互作用。需要深入理解材料微观结构对热传导的影响，并能综合分析不同温度区间主导机制的转变。这种机理解释和综合分析能力属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 4601, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Pure copper; aluminum bronze (95 wt% Cu-5 wt% Al).", + "answer": "Pure copper will have a larger conductivity than aluminum bronze because the impurity atoms in the latter will lead to a greater degree of free electron scattering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要理解热导率的基本概念，并能够分析杂质原子对自由电子散射的影响，从而比较两种材料的热导率。这涉及到多步推理和概念关联，但不需要复杂的综合或创新应用。 | 难度: 在选择题中属于中等难度，需要理解热导率的基本概念、杂质对自由电子散射的影响，并进行材料性能的比较分析。虽然不需要多步计算，但要求将多个概念关联起来做出判断。" + }, + { + "idx": 4602, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Fused silica; quartz.", + "answer": "Quartz will have a larger conductivity than fused silica because fused silica is noncrystalline (whereas quartz is crystalline) and lattice vibrations are more effectively scattered in noncrystalline materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目要求比较两种材料的导热性能并解释原因，涉及晶体结构对热导率影响的概念关联和综合分析，需要理解晶态与非晶态材料中声子散射的差异，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶体和非晶体材料对热导率的影响，并进行比较分析。虽然题目给出了明确的比较对象和正确选项，但仍需要掌握材料结构对热导率影响的基本原理，并能将这一原理应用到具体材料比较中。" + }, + { + "idx": 4603, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Linear polyethylene; branched polyethylene.", + "answer": "The linear polyethylene will have the larger conductivity than the branched polyethylene because the former will have the higher degree of crystallinity. Linear polymers have higher degrees of crystallinity than branched polymers. Since heat transfer is accomplished by molecular chain vibrations, and the coordination of these vibrations increases with percent crystallinity, the higher the crystallinity, the greater the thermal conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种材料的导热性进行比较并给出理由，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚乙烯的热导率，并解释原因。这需要理解线性聚乙烯和支化聚乙烯的结晶度差异，以及结晶度对热导率的影响。虽然涉及基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解线性聚乙烯和支化聚乙烯的结晶度差异，并关联结晶度与热导率的关系。虽然不涉及复杂计算，但需要综合应用材料科学中的多个概念进行比较分析。" + }, + { + "idx": 4604, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Random poly(styrene-butadiene) copolymer; alternating poly(styrene-butadiene) copolymer.", + "answer": "The alternating poly(styrene-butadiene) copolymer will have a higher crystallinity than the random copolymer; alternating copolymers crystallize more easily than random ones. The influence of crystallinity on conductivity is explained in part (c).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性并给出理由，需要文字解释和论述，而不是从选项中选择或判断对错。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求学生比较两种共聚物的热导率，并解释其差异。这需要理解共聚物结构（随机与交替）对结晶度的影响，以及结晶度如何影响热导率。虽然涉及基础概念（共聚物类型、结晶度与热导率的关系），但需要将这些概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生比较两种共聚物的热导率，并理解交替共聚物比无规共聚物更容易结晶，从而影响热导率。这需要考生掌握共聚物结构对结晶性的影响以及结晶性对热导率的影响这两个概念，并进行综合分析。虽然不需要多步计算，但需要将多个概念关联起来，因此属于中等难度。" + }, + { + "idx": 4605, + "question": "Explain the two sources of magnetic moments for electrons.", + "answer": "The two sources of magnetic moments for electrons are the electron's orbital motion around the nucleus, and also, its spin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释电子磁矩的两个来源，需要文字解释和论述，答案也是以文字形式呈现的简要说明。 | 知识层次: 题目考查对电子磁矩来源的基本概念记忆和理解，仅需回答轨道运动和自旋两个基本来源，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆和识别电子磁矩的两个基本来源（轨道运动和自旋），属于基础概念的直接回忆，无需解释或分析步骤，因此属于最低难度等级。" + }, + { + "idx": 4606, + "question": "Do all electrons have a net magnetic moment? Why or why not?", + "answer": "Each electron will have a net magnetic moment from spin, and possibly, orbital contributions, which do not cancel for an isolated atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么所有电子是否具有净磁矩，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查电子磁矩的基本概念，主要涉及自旋和轨道贡献的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 该题目在选择题型中属于中等难度。虽然问题涉及基础概念（电子磁矩），但需要考生理解并区分自旋磁矩和轨道磁矩的贡献，并知道它们在孤立原子中的表现。这超出了简单的定义记忆（等级1），但又不涉及复杂的概念体系分析（等级3）。正确选项明确指出了关键点，使得题目在选择题型中属于概念解释和描述级别。" + }, + { + "idx": 4607, + "question": "Do all atoms have a net magnetic moment? Why or why not?", + "answer": "All atoms do not have a net magnetic moment. If an atom has completely filled electron shells or subshells, there will be a cancellation of both orbital and spin magnetic moments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么不是所有原子都有净磁矩，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对原子磁矩基本概念的理解，涉及电子排布和磁矩抵消的基本原理，属于基础概念记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（原子磁矩的定义和分类），但正确选项要求考生理解电子排布与磁矩之间的关系，并能解释为什么完全填满的电子壳层会导致磁矩抵消。这需要比单纯记忆定义更深一层的概念解释能力，但不需要进行复杂的体系阐述或多概念综合分析。" + }, + { + "idx": 4608, + "question": "Confirm that there are 2.2 Bohr magnetons associated with each iron atom, given that the saturation magnetization is 1.70 × 10^{6} \\mathrm{~A} / m, that iron has a BCC crystal structure, and that the unit cell edge length is 0.2866 nm.", + "answer": "2.16 bohr magnetons/atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数（饱和磁化强度、晶体结构、晶胞边长）进行数值计算，最终得出每个铁原子的玻尔磁子数。解答过程需要应用相关公式和单位转换，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，包括利用饱和磁化强度、晶体结构参数（BCC晶格常数）和单位体积原子数计算每个铁原子的磁矩，并转换为玻尔磁子单位。这涉及多个概念的综合应用和数值计算，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念和公式进行计算。题目要求考生理解饱和磁化强度、BCC晶体结构、单位晶胞边长与原子数的关系，以及玻尔磁子与原子磁矩的转换。解题步骤包括计算单位体积内的铁原子数、推导每个原子的磁矩，最后转换为玻尔磁子单位。虽然选择题提供了正确选项，但解题过程涉及多步计算和单位转换，对概念理解和计算能力要求较高。" + }, + { + "idx": 4609, + "question": "There is associated with each atom in paramagnetic and ferromagnetic materials a net magnetic moment. Explain why ferromagnetic materials can be permanently magnetized whereas paramagnetic ones cannot.", + "answer": "Ferromagnetic materials may be permanently magnetized (whereas paramagnetic ones may not) because of the ability of net spin magnetic moments of adjacent atoms to align with one another. This mutual magnetic moment alignment in the same direction exists within small volume regions--domains. When a magnetic field is applied, favorably oriented domains grow at the expense of unfavorably oriented ones, by the motion of domain walls. When the magnetic field is removed, there remains a net magnetization by virtue of the resistance to movement of domain walls; even after total removal of the magnetic field, the magnetization of some net domain volume will be aligned near the direction that the external field was oriented.\nFor paramagnetic materials, there is no magnetic dipole coupling, and, consequently, domains do not form. When a magnetic field is removed, the atomic dipoles assume random orientations, and no magnetic moment remains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么铁磁材料可以永久磁化而顺磁材料不能，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释铁磁性和顺磁性材料在磁化行为上的差异，涉及磁矩排列、磁畴形成和运动等复杂机理的分析和推理。需要综合运用多个概念（如磁矩、磁畴、磁畴壁运动等）进行深入解释，属于对材料磁学性质的复杂分析。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 4611, + "question": "Why does the magnitude of the saturation magnetization decrease with increasing temperature for ferromagnetic materials?", + "answer": "The saturation magnetization decreases with increasing temperature because the atomic thermal vibrational motions counteract the coupling forces between the adjacent atomic dipole moments, causing some magnetic dipole misalignment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行文字解释和论述，答案提供了详细的原理说明，符合简答题的特征 | 知识层次: 题目要求解释铁磁材料饱和磁化强度随温度升高而降低的机理，涉及原子热振动与磁偶极矩耦合作用的综合分析，需要理解温度对磁有序状态的影响机制，属于对物理过程的深入推理和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4612, + "question": "Why does ferromagnetic behavior cease above the Curie temperature for ferromagnetic materials?", + "answer": "Ferromagnetic behavior ceases above the Curie temperature because the atomic thermal vibrations are sufficiently violent so as to completely destroy the mutual spin coupling forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行文字解释和论述，答案提供了详细的原理说明，符合简答题的特征。 | 知识层次: 题目要求解释铁磁材料在居里温度以上失去铁磁行为的机理，涉及原子热振动与自旋耦合力的相互作用，需要深入理解材料微观结构和宏观性能的关系，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解铁磁材料的微观机理（自旋耦合作用与热振动的关系），并能综合运用热力学与量子力学知识解释复杂相变现象。正确选项涉及原子尺度相互作用与宏观性能的关联，需要考生在选择题的有限信息中进行高阶推理，完全符合\"复杂现象全面分析\"的知识层次要求。" + }, + { + "idx": 4613, + "question": "An iron bar magnet having a coercivity of 4000 \\mathrm{~A} / m is to be demagnetized. If the bar is inserted within a cylindrical wire coil 0.15{m} long and having 100 turns, what electric current is required to generate the necessary magnetic field?", + "answer": "the required electric current is 6 \\mathrm{a}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定所需的电流值。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的参数（矫顽力、线圈长度和匝数）直接套用公式计算所需的电流。不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（H = nI/l）进行计算，解题步骤简单，属于最基础的难度等级。" + }, + { + "idx": 4614, + "question": "Visible light having a wavelength of 6 x 10^-7 m appears orange. Compute the frequency of a photon of this light.", + "answer": "the frequency of the photon is 5 x 10^14 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（频率=光速/波长）来求解光子的频率，答案是一个具体的数值结果。 | 知识层次: 题目仅涉及基本公式（频率=光速/波长）的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（频率=光速/波长）进行计算，属于最基础的难度等级。题目提供了所有必要信息，且计算步骤简单直接，无需额外的概念理解或复杂分析。" + }, + { + "idx": 4615, + "question": "Visible light having a wavelength of 6 x 10^-7 m appears orange. Compute the energy of a photon of this light.", + "answer": "the energy of the photon is 3.31 x 10^-19 j (2.07 ev).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算光子的能量，需要使用公式（如E=hc/λ）进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求计算光子的能量，涉及基本公式（E=hc/λ）的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（E = hc/λ）进行计算，无需额外的概念理解或步骤组合。题目提供了所有必要参数，且计算过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 4616, + "question": "What are the characteristics of opaque materials in terms of their appearance and light transmittance?", + "answer": "Opaque materials are impervious to light transmission; it is not possible to see through them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释不透明材料的外观和光透射特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对不透明材料基本特性的记忆和理解，属于定义和基本原理的记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需回忆不透明材料的基本定义和特性（不透光、无法看透）。在选择题型中属于最简单的直接知识回忆类题目，无需复杂推理或概念比较。" + }, + { + "idx": 4617, + "question": "What are the characteristics of translucent materials in terms of their appearance and light transmittance?", + "answer": "Light is transmitted diffusely through translucent materials (there is some internal light scattering). Objects are not clearly distinguishable when viewed through a translucent material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和描述半透明材料的外观和光透射特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对半透明材料基本特性的记忆和理解，包括光传输方式和视觉效果的描述，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆（translucent materials的定义和特性），但需要考生准确理解并描述半透明材料的光学特性（漫透射和物体辨识度）。这比单纯识别定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。正确选项完整描述了半透明材料的两个关键特征，符合\"概念解释和描述\"的难度标准。" + }, + { + "idx": 4618, + "question": "What are the characteristics of transparent materials in terms of their appearance and light transmittance?", + "answer": "Virtually all of the incident light is transmitted through transparent materials, and one can see clearly through them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释透明材料的外观和透光特性，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查透明材料的基本特性（外观和透光率）的记忆和理解，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察透明材料的基本特性（外观和透光率），正确选项是对透明材料定义的直接陈述，不需要任何解释或复杂推理。学生只需记住透明材料的定义特征即可正确作答，属于最基础的概念记忆层次。" + }, + { + "idx": 4619, + "question": "In ionic materials, how does the size of the component ions affect the extent of electronic polarization?", + "answer": "In ionic materials, the larger the size of the component ions the greater the degree of electronic polarization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释离子尺寸对电子极化的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是离子材料中离子尺寸对电子极化影响的基本概念，属于定义和基本原理的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解离子尺寸与电子极化程度之间的关系，而不仅仅是简单的定义记忆。正确选项直接给出了这一关系的结论，但考生需要具备一定的概念理解能力才能准确选择。因此，相较于纯粹的定义记忆题（等级1），此题需要更深一层的概念解释和描述能力（等级2）。" + }, + { + "idx": 4620, + "question": "Can a material have an index of refraction less than unity? Why or why not?", + "answer": "In order for a material to have an index of refraction less than unity, the velocity of light in the material (v) would necessarily have to be greater than the velocity of light in a vacuum. This is not possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对材料折射率小于1的可能性进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对折射率基本概念的理解，涉及光速在介质中的传播速度与真空中的比较，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及折射率的基本定义，但需要考生理解折射率与光速的关系，并能够推理出折射率小于1的情况在物理上不可能的原因。这超出了简单的定义记忆，需要对概念进行解释和描述。" + }, + { + "idx": 4621, + "question": "Briefly describe the phenomenon of dispersion in a transparent medium.", + "answer": "Dispersion in a transparent medium is the phenomenon wherein the index of refraction varies slightly with the wavelength of the electromagnetic radiation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述透明介质中的色散现象，答案是一个文字解释和论述的形式，符合简答题的特征 | 知识层次: 题目考查对色散现象这一基本概念的定义和简单理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目仅要求考生回忆并识别透明介质中色散现象的基本定义。题目涉及的知识点属于基础概念记忆层次，解题步骤简单，只需选择与定义相符的正确选项即可，无需进行复杂的概念比较或分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4622, + "question": "Briefly explain how reflection losses of transparent materials are minimized by thin surface coatings.", + "answer": "The thickness and dielectric constant of a thin surface coating are selected such that there is destructive interference between the light beam that is reflected from the lens-coating interface and the light beam that is reflected from the coating-air interface; thus, the net intensity of the total reflected beam is very low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释透明材料如何通过薄表面涂层减少反射损失，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释如何通过表面涂层最小化透明材料的反射损失，涉及光的干涉原理和涂层材料的选择，需要综合运用光学和材料科学的知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用光学干涉原理、材料介电常数选择以及多层反射的相位关系等复杂概念，通过推理分析解释薄膜涂层如何实现减反射的完整机理。正确选项不仅需要理解破坏性干涉的基本原理，还需要掌握涂层厚度与介电常数的匹配关系，以及两个界面反射光束的相互作用机制。这种需要多维度知识整合和机理深度解释的题目，在选择题型中代表最高层次的认知要求。" + }, + { + "idx": 4623, + "question": "The index of refraction of corundum \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\right) is anisotropic. Suppose that visible light is passing from one grain to another of different crystallographic orientation and at normal incidence to the grain boundary. Calculate the reflectivity at the boundary if the indices of refraction for the two grains are 1.757 and 1.779 in the direction of light propagation.", + "answer": "the reflectivity at the boundary is 3.87 × 10^{-5}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（反射率公式）来求解反射率，答案是一个具体的数值结果（3.87 × 10^{-5}），符合计算题的特征。 | 知识层次: 题目要求应用反射率的基本公式进行计算，涉及简单的数值代入和直接套用公式，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察基本公式的直接应用和简单计算。题目要求计算反射率，只需套用菲涅尔反射公式（R = ((n1 - n2)/(n1 + n2))^2），代入给定的折射率值即可得到结果。虽然涉及公式应用，但步骤简单，无需多个公式组合或复杂推导，因此在选择题型中属于等级2难度。" + }, + { + "idx": 4624, + "question": "Briefly explain what determines the characteristic color of a metal.", + "answer": "The characteristic color of a metal is determined by the distribution of wavelengths of the nonabsorbed light radiation that is reflected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求用文字简要解释金属特征颜色的决定因素，答案是一个简短的文字论述，符合简答题的特征 | 知识层次: 题目考查金属特征颜色的基本原理，仅需记忆和理解光反射与吸收的基本概念，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项需要理解金属颜色的决定因素，即非吸收光辐射的波长分布和反射现象。这比简单的定义记忆（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4625, + "question": "Briefly explain what determines the characteristic color of a transparent nonmetal.", + "answer": "The characteristic color of a transparent nonmetal is determined by the distribution of wavelengths of the nonabsorbed light radiation that is transmitted through the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释透明非金属特征颜色的决定因素，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对透明非金属特征颜色形成原因的基本概念理解，仅需记忆和解释基本原理，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项需要考生理解并描述透明非金属特征颜色的决定因素，而不仅仅是简单的定义记忆。这要求考生能够解释非吸收光辐射波长分布的概念，属于概念解释和描述的层次。" + }, + { + "idx": 4626, + "question": "Briefly explain why some transparent materials appear colored while others are colorless.", + "answer": "For a transparent material that appears colorless, any absorption within its interior is the same for all visible wavelengths. On the other hand, if there is any selective absorption of visible light (usually by electron excitations), the material will appear colored, its color being dependent on the frequency distribution of the transmitted light beam.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释透明材料为何呈现有色或无色，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对透明材料颜色现象的基本原理的理解和记忆，涉及吸收光谱和电子激发等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然涉及基础概念记忆，但需要考生理解并解释透明材料颜色现象背后的基本原理（选择性吸收与均匀吸收的区别）。题目要求考生能够区分两种不同光学现象的本质原因，并正确描述颜色产生的机制，这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 4627, + "question": "Briefly explain why amorphous polymers are transparent, while predominantly crystalline polymers appear opaque or, at best, translucent.", + "answer": "Amorphous polymers are normally transparent because there is no scattering of a light beam within the material. However, for semicrystalline polymers, visible light will be scattered at boundaries between amorphous and crystalline regions since they have different indices of refraction. This leads to translucency or, for extensive scattering, opacity, except for semicrystalline polymers having very small crystallites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释非晶态聚合物透明而结晶态聚合物不透明的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非晶态聚合物透明而结晶态聚合物不透明的机理，涉及光散射、折射率差异等物理原理的综合分析，需要深入理解材料微观结构与光学性能的关系，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对非晶态聚合物和结晶态聚合物的光学性质差异进行机理层面的深度解释，涉及光散射、折射率差异等复杂物理现象的综合分析。正确选项不仅需要理解两种聚合物结构的本质区别，还需要解释光散射与晶体尺寸的关系，属于复杂现象全面分析的范畴。在选择题中，这种需要多维度推理和机理解释的题目对知识掌握深度和综合分析能力要求极高。" + }, + { + "idx": 4628, + "question": "Zinc has five naturally occurring isotopes: 48.63% of { }^{64} Zn with an atomic weight of 63.929 amu; 27.90% of { }^{66} Zn with an atomic weight of 65.926 amu^{\\text {; }} 4.10% of { }^{67} Zn with an atomic weight of 66.927 amu ; 18.75% of { }^{68} Zn with an atomic weight of 67.925 amu ; and 0.62% of { }^{70} Zn with an atomic weight of 69.925 amu. Calculate the average atomic weight of Zn.", + "answer": "the average atomic weight of \\mathrm{zn} is 65.400 amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（加权平均）来求解锌的平均原子量，答案是一个具体的数值结果。 | 知识层次: 题目要求计算锌元素的平均原子量，涉及基本公式应用（加权平均）和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用平均原子量的计算公式（各同位素原子量乘以其丰度后相加），属于单一公式直接计算。题目提供了所有必要的数据，无需额外的推理或复杂的步骤，因此属于最低难度等级。" + }, + { + "idx": 4629, + "question": "Indium has two naturally occurring isotopes: { }^{113} In with an atomic weight of 112.904 amu, and { }^{115} \\mathrm{In} with an atomic weight of 114.904 amu. If the average atomic weight for In is 114.818 amu, calculate the fraction-of-occurrences of these two isotopes.", + "answer": "the fraction-of-occurrence of { }^{113}in is 0.043. the fraction-of-occurrence of { }^{115}in is 0.957.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种同位素的出现分数，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式应用和简单计算，即通过给定的同位素原子质量和平均原子质量，计算同位素的丰度分数。虽然需要一定的代数运算，但整体过程直接且无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解同位素的概念和平均原子量的计算方法，但解题步骤相对直接，只需设一个变量并解一元一次方程即可得到答案。不需要复杂的推理或多步骤计算，因此难度等级为2。" + }, + { + "idx": 4630, + "question": "Potassium iodide (KI) exhibits predominantly ionic bonding. The K+ ion has an electron structure that is identical to which inert gas?", + "answer": "The K+ ion is just a potassium atom that has lost one electron; therefore, it has an electron configuration the same as argon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释K+离子的电子结构与哪种惰性气体相同，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对离子电子结构的基本概念记忆和理解，只需知道钾离子失去一个电子后的电子排布与氩原子相同即可回答，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别K+离子的电子构型与哪种惰性气体相同。正确选项直接给出了答案，无需复杂推理或概念间的比较分析，符合选择题型中最简单的难度等级。" + }, + { + "idx": 4632, + "question": "With regard to electron configuration, what do all the elements in Group IIA of the periodic table have in common?", + "answer": "Each of the elements in Group IIA has two s electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释Group IIA元素的电子配置共同点，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对元素周期表中IIA族元素电子排布的共同特征的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即元素周期表IIA族元素的电子排布共性。正确选项直接给出了明确的定义性答案，无需任何解释或分析步骤，属于最基础的定义简答级别。" + }, + { + "idx": 4633, + "question": "To what group in the periodic table would an element with atomic number 112 belong?", + "answer": "From the periodic table the element having atomic number 112 would belong to group IIB. According to the periodic table, Ds, having an atomic number of 110 lies below Pt in the periodic table and in the right-most column of group VIII. Moving two columns to the right puts element 112 under \\mathrm{Hg} and in group IIB.\nThis element has been artificially created and given the name Copernicium with the symbol Cn. It was named after Nicolaus Copernicus, the Polish scientist who proposed that the earth moves around the sun (and not vice versa).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素112在周期表中的归属，并提供了详细的文字解释和论述，而不是简单的选择或判断。答案需要基于周期表的知识进行推理和说明，符合简答题的特征。 | 知识层次: 题目考查对元素周期表分组的基本概念的记忆和理解，仅需根据原子数定位元素在周期表中的位置，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及元素周期表的分组知识，但解题步骤相对直接，只需根据原子数定位元素在周期表中的位置即可。此外，题目提供了额外的背景信息（如元素名称和符号），但这些信息并非解题必需。因此，该题目主要考察基础概念记忆和简单应用，属于等级2的难度。" + }, + { + "idx": 4634, + "question": "Without consulting Figure or Table, determine whether the electron configuration (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{5}) is an inert gas, a halogen, an alkali metal, an alkaline earth metal, or a transition metal. Justify your choice.", + "answer": "The (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{5}) electron configuration is that of a halogen because it is one electron deficient from having a filled (p) subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据电子排布判断元素类别，并需要文字解释和论述来证明选择。答案提供了详细的解释，说明为什么该电子排布对应卤素，这符合简答题的特征。 | 知识层次: 题目考查对电子构型与元素分类之间关系的基本概念记忆和理解，只需根据电子构型判断元素类别，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆电子构型与元素分类的基本对应关系，但解题步骤相对直接，只需识别电子构型并匹配到对应的元素类别（卤素）。不需要复杂的分析或比较多个概念，仅需基础概念的记忆和简单应用。" + }, + { + "idx": 4640, + "question": "Differentiate (E_{N}) with respect to (r), and then set the resulting expression equal to zero, because the curve of (E_{N}) versus (r) is a minimum at (E_{0}).", + "answer": "The derivative of (E_{N}) with respect to (r) is set to zero to find the minimum.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对(E_{N})关于(r)进行微分，并将结果设为零以找到最小值，这涉及数值计算和公式应用。 | 知识层次: 题目要求对(E_N)关于(r)的导数进行简单计算，并将结果设为零以找到最小值。这属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单应用难度，题目要求对基本公式进行直接应用和简单计算，仅需理解如何求导并设置导数为零以找到最小值。虽然涉及微积分概念，但在选择题型中属于直接套用公式的简单计算，无需复杂分析或多步骤推理。" + }, + { + "idx": 4641, + "question": "Solve for (r) in terms of (A, B), and (n), which yields (r_{0}), the equilibrium interionic spacing.", + "answer": "The equilibrium interionic spacing (r_{0}) is solved in terms of (A, B), and (n).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式和变量关系求解平衡离子间距(r_{0})，涉及数值计算和公式应用，属于典型的计算题类型。 | 知识层次: 题目要求解平衡离子间距(r_{0})，涉及多个变量(A, B, n)的计算和公式应用，需要多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解平衡离子间距的概念，并能够将A、B、n等变量关联起来进行综合分析。虽然题目给出了正确选项，但考生仍需掌握多步计算过程和变量间的相互作用才能正确理解并选择答案。这比单纯记忆概念或简单计算要复杂，但尚未达到最复杂的多变量计算水平。" + }, + { + "idx": 4642, + "question": "Determine the expression for (E_{0}) by substitution of (r_{0}) into Equation.", + "answer": "The bonding energy (e_{0}) is given by: (e_{0}=-\frac{a}{\\left(\frac{a}{nb}\right)^{1 /(1-n)}}+\frac{b}{\\left(\frac{a}{nb}\right)^{n /(1-n)}})", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过代入公式计算得出(E_{0})的表达式，答案是一个具体的数学表达式，涉及数值计算和公式应用。 | 知识层次: 题目需要将给定的(r0)代入方程并进行多步计算来求解(E0)，涉及公式的变换和代数运算，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算和综合分析。题目要求将(r_{0})代入方程并推导出(E_{0})的表达式，涉及代数运算和指数运算，步骤较为复杂。虽然题目提供了正确选项，但理解推导过程需要一定的概念关联能力。" + }, + { + "idx": 4643, + "question": "Explain why hydrogen fluoride (HF) has a higher boiling temperature than hydrogen \\\\ chloride (\\mathrm{HCl})\\left(19.4 \\mathrm{vs} .-85^{\\circ} C\\right), even though \\mathrm{HF} has a lower molecular weight.", + "answer": "The intermolecular bonding for \\mathrm{HF} is hydrogen, whereas for \\mathrm{HCl}, the intermolecular bonding is van der Waals. Since the hydrogen bond is stronger than van der Waals, HF will have a higher melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释氢氟酸（HF）比氯化氢（HCl）沸点高的原因，答案需要文字解释和论述，涉及分子间作用力的比较，属于简答题类型。 | 知识层次: 题目要求解释氢氟酸（HF）和氯化氢（HCl）沸点差异的原因，涉及分子间作用力的比较（氢键与范德华力）以及其对物理性质的影响。这需要理解分子间作用力的类型及其强度差异，并将这些概念应用于解释具体现象，属于中等应用层次。虽然不涉及多步计算，但需要对概念进行关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解氢键和范德华力的概念，并能比较它们的相对强度以及对沸点的影响。虽然题目涉及分子间作用力的知识，但选项直接给出了关键概念和结论，减少了分析步骤的复杂性。" + }, + { + "idx": 4645, + "question": "What type(s) of bonding would be expected for calcium fluoride (CaF2)?", + "answer": "For CaF2, the bonding is predominantly ionic (but with some slight covalent character) on the basis of the relative positions of Ca and F in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释CaF2的键合类型，需要文字论述和解释，而不是从选项中选择或简单判断对错。答案也提供了详细的解释说明，符合简答题的特征。 | 知识层次: 题目考查对化学键类型（离子键和共价键）的基本概念记忆和理解，以及根据元素在周期表中的位置判断键型的能力，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目要求考生理解并描述钙氟化物的主要键合类型（离子键）以及次要特征（部分共价性），这属于概念解释和描述的层次。虽然需要记忆元素在周期表中的相对位置，但不需要复杂的分析或比较多个概念体系，因此属于中等难度。" + }, + { + "idx": 4647, + "question": "What type(s) of bonding would be expected for cadmium telluride (CdTe)?", + "answer": "For CdTe, the bonding is predominantly covalent (with some slight ionic character) on the basis of the relative positions of Cd and Te in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释CdTe的键合类型，需要文字论述和解释，而不是选择、判断或计算 | 知识层次: 题目要求根据元素在周期表中的位置判断CdTe的键合类型，需要理解共价键和离子键的特性，并能够综合分析元素的电负性差异来推断键合性质。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生根据元素在周期表中的位置判断CdTe的键合类型，涉及对共价键和离子键概念的综合理解，以及元素电负性差异的分析。虽然不需要复杂的计算，但需要对化学键理论有较深的理解和应用能力。" + }, + { + "idx": 4649, + "question": "What type(s) of bonding would be expected for tungsten?", + "answer": "For tungsten, the bonding is metallic since it is a metallic element from the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钨的键合类型，需要文字解释和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目考查对金属元素钨的键合类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别钨是金属元素并回忆其键合类型为金属键。题目不涉及复杂概念或分析步骤，属于最基础的定义简答级别。" + }, + { + "idx": 4650, + "question": "Which of the following electron configurations is for an inert gas? \\\\ (A) 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} \\\\ (B) 1 s^{2} 2 s^{2} 2 p^{6} s 3 s^{2} \\\\ (C) 1 s^{2} 2 s^{2} 2 p^{6} .3 s^{2} 3 p^{6} 4 s^{1} \\\\ (D) 1 s^{2} 2 s^{2} 2 p^{6}·3 s^{2} 3 p^{6} 3 d^{2} 4 s^{2}", + "answer": "The correct answer is A. The 1 s^{2} 2 s^{2} 2 p^{6} 13 s^{2} 3 p^{6} electron configuration is that of an inert gas because of filled 3 s and 3 p subshells.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的电子构型，符合选择题的特征 | 知识层次: 题目考查对惰性气体电子排布这一基础概念的记忆和理解，无需复杂计算或分析，仅需识别符合惰性气体特征的电子排布即可。 | 难度: 在选择题中属于中等难度，需要理解惰性气体的电子排布特征（即最外层电子排布为s²p⁶），并对给定的电子排布选项进行简单辨析。虽然涉及基础概念记忆，但需要一定的理解能力来识别正确的电子排布模式。" + }, + { + "idx": 4651, + "question": "What type(s) of bonding would be expected for bronze (a copper-tin alloy)?\n(A) Ionic bonding\n(B) Metallic bonding\n(C) Covalent bonding with some van der Waals bonding\n(D) van der Waals bonding", + "answer": "The correct answer is B. For bronze, the bonding is metallic because it is a metal alloy.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对金属合金键合类型的基本概念记忆和理解，属于基础知识点。 | 难度: 该题目属于基础概念记忆题，仅需识别青铜（铜锡合金）的键合类型为金属键。题目直接给出选项，无需复杂分析或概念辨析，属于选择题型中最简单的难度等级。" + }, + { + "idx": 4652, + "question": "What type(s) of bonding would be expected for rubber?\n(A) Ionic bonding\n(B) Metallic bonding\n(C) Covalent bonding with some van der Waals bonding\n(D) van der Waals bonding", + "answer": "FE}\nThe correct answer is C. For rubber, the bonding is covalent with some van der Waals bonding. (Rubber is composed primarily of carbon and hydrogen atoms.)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了四个选项（A-D），并给出了正确答案C。这是典型的选择题形式。 | 知识层次: 题目考查对橡胶材料键合类型的基本概念记忆和理解，属于基础知识点，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解橡胶的化学键类型（共价键和范德华力），但选项之间的区分较为明显，不需要复杂的分析过程。学生只需掌握基本的材料键合类型知识即可正确作答。" + }, + { + "idx": 4653, + "question": "If the atomic radius of lead is 0.175nm, calculate the volume of its unit cell in cubic meters.", + "answer": "the volume of the unit cell is 1.213 × 10^{-28} m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案是一个具体的数值结果。 | 知识层次: 题目要求根据给定的原子半径计算单位晶胞的体积，这属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用基本公式（立方体体积公式 V = a³，其中 a 为晶胞边长）进行简单计算。题目已给出原子半径，且未涉及多步骤推导或复杂概念转换，属于单一公式直接计算的典型等级1难度。" + }, + { + "idx": 4654, + "question": "Calculate the radius of a palladium (P d) atom, given that P d has an FCC crystal structure, a density of 12.0g / {cm}^{3}, and an atomic weight of 106.4g / mol.", + "answer": "the radius of a palladium (pd) atom is 0.138nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（FCC晶体结构、密度、原子重量等）来求解钯原子的半径，答案是一个具体的数值（0.138nm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及FCC晶体结构、密度和原子重量等概念的关联应用，需要综合分析能力来推导原子半径。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、密度、原子量等概念，并进行多步计算才能得出正确答案。虽然题目给出了正确选项，但解题过程涉及单位换算、晶格参数计算和原子半径推导等步骤，对学生的概念理解和计算能力要求较高。" + }, + { + "idx": 4655, + "question": "Calculate the radius of a tantalum (Ta) atom, given that Ta has a BCC crystal structure, a density of 16.6g / {cm}^{3}, and an atomic weight of 180.9g / mol.", + "answer": "the radius of a tantalum (ta) atom is 0.143 \\, \\text{nm}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（BCC晶体结构、密度、原子重量等）来求解钽原子的半径，答案是一个具体的数值（0.143 nm），符合计算题的特征。 | 知识层次: 题目需要应用BCC晶体结构的基本知识，进行多步计算（包括密度、原子量和晶格常数的关联计算），并最终推导出原子半径。这涉及到对晶体结构、密度公式和单位换算的综合理解与应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、密度与原子半径的关系，并进行多步计算。虽然题目提供了所有必要数据，但解题过程涉及单位转换、晶体学公式应用（如BCC的原子半径与晶格参数关系）以及代数运算，属于综合性计算问题。" + }, + { + "idx": 4656, + "question": "Titanium (Ti) has an HCP crystal structure and a density of 4.51 g/cm^3. What is the volume of its unit cell in cubic meters?", + "answer": "the volume of the ti unit cell is 1.058 x 10^-28 m^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钛的HCP晶胞体积，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用基本的密度公式和晶体结构知识进行单步计算，属于直接套用公式的简单应用类型。虽然涉及单位换算，但整体思维过程较为直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用密度公式和晶体结构的基本知识，但解题步骤相对直接，仅需套用密度公式（ρ = m/V）并结合钛的原子质量和HCP晶胞的原子数进行计算。不需要复杂的推导或多步骤转换，因此属于等级2难度。" + }, + { + "idx": 4657, + "question": "Titanium (Ti) has an HCP crystal structure and a density of 4.51 g/cm^3. If the c/a ratio is 1.58, compute the values of c and a.", + "answer": "the values of a and c are 0.296 nm and 0.468 nm, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Titanium的晶格常数a和c的值，答案给出了具体的数值结果。 | 知识层次: 题目需要应用HCP晶体结构的基本公式，进行多步计算，涉及密度、晶格常数和c/a比的概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要掌握HCP晶体结构的基本参数关系、密度计算公式，并能正确进行多步单位换算和代数运算。题目涉及c/a比值的应用、原子质量与晶胞体积的关系计算，以及纳米单位的转换，属于需要综合应用多个材料科学概念的题目。虽然选择题提供了正确选项降低了部分难度，但仍需完成较复杂的推导过程才能验证答案。" + }, + { + "idx": 4658, + "question": "Magnesium (Mg) has an HCP crystal structure and a density of 1.74 g/cm3. What is the volume of its unit cell in cubic centimeters?", + "answer": "the volume of the unit cell is 1.39 × 10^-22 cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的HCP晶胞体积，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（密度公式）进行简单计算，涉及HCP晶体结构的基本参数，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用密度公式和HCP晶体结构的基本参数进行计算，属于单一公式直接计算的类型。解题步骤简单，仅需套用公式并代入已知数值，无需复杂的分析或组合多个公式。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4659, + "question": "Magnesium (Mg) has an HCP crystal structure and a density of 1.74 g/cm3. If the c/a ratio is 1.624, compute the values of c and a.", + "answer": "the values of a and c are 0.321 nm and 0.521 nm, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的晶格常数a和c的值，答案也是具体的数值结果。 | 知识层次: 题目需要应用HCP晶体结构的相关公式进行多步计算，涉及密度、晶格常数和c/a比等概念的关联和综合分析，思维过程有一定的深度要求。 | 难度: 在选择题中属于中等偏上难度，需要理解HCP晶体结构的基本参数（如原子半径、晶格常数等）与密度之间的关系，并能够正确应用相关公式进行多步计算。题目涉及c/a比值的概念，要求考生能够综合运用晶体几何和材料密度的知识来求解具体数值。虽然选择题提供了正确选项，但解题过程仍需要较强的概念关联和计算能力，属于综合性计算问题。" + }, + { + "idx": 4660, + "question": "The unit cell for uranium (U) has orthorhombic symmetry, with a, b, and c lattice parameters of 0.286,0.587, and 0.495nm, respectively. If its density, atomic weight, and atomic radius are 19.05g / {cm}^{3}, 238.03g / mol, and 0.1385nm, respectively, compute the atomic packing factor.\n\\title{", + "answer": "the atomic packing factor (apf) for uranium is 0.536.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铀的原子堆积因子（APF），答案是一个具体的数值结果（0.536），解答过程需要运用密度、原子重量、晶格参数等数据进行计算。 | 知识层次: 题目需要计算原子堆积因子（APF），这涉及到多步计算和概念关联。首先需要理解APF的定义（体积分数），然后计算晶胞体积和原子总体积。计算过程中需要应用晶格参数、原子半径和密度等数据，并进行单位转换和综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的计算步骤和概念整合。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如晶胞参数、密度、原子量、原子半径等）并进行多步骤计算（如计算晶胞体积、原子体积、原子数等），最终综合得出原子堆积因子。虽然题目提供了所有必要参数，但计算过程涉及多个步骤和概念的综合应用，对学生的理解和计算能力有一定要求。" + }, + { + "idx": 4661, + "question": "Indium (In) has a tetragonal unit cell for which the a and c lattice parameters are 0.459 and 0.495 nm, respectively. If the atomic packing factor and atomic radius are 0.693 and 0.1625 nm, respectively, determine the number of atoms in each unit cell.", + "answer": "4.0 atoms/unit cell", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶格参数、原子堆积因子和原子半径进行数值计算，最终确定每个晶胞中的原子数。解答过程需要应用相关公式和计算步骤，答案是一个具体的数值（4.0 atoms/unit cell），符合计算题的特征。 | 知识层次: 题目需要应用晶格参数、原子堆积因子和原子半径等多重概念，进行多步计算和综合分析，以确定每个晶胞中的原子数。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等偏上难度，需要结合晶格参数、原子堆积因子和原子半径进行多步计算，并理解各参数之间的关系。虽然题目提供了所有必要数据，但解题过程涉及单位晶胞体积、原子总体积与原子堆积因子的关联计算，需要一定的综合分析能力。相比单纯的概念记忆题，该题对计算和逻辑推理的要求更高，但尚未达到复杂多变量计算的等级4难度。" + }, + { + "idx": 4662, + "question": "Indium (In) has a tetragonal unit cell for which the a and c lattice parameters are 0.459 and 0.495 nm, respectively. The atomic weight of indium is 114.82 g/mol; compute its theoretical density.", + "answer": "7.31 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如晶格参数、原子质量和密度公式）来求解理论密度，答案是一个具体的数值结果（7.31 g/cm3），符合计算题的特征。 | 知识层次: 题目要求计算材料的理论密度，涉及基本的晶格参数和原子量的应用，属于直接套用公式进行简单计算的范畴。虽然需要理解晶格参数和密度的关系，但不需要多步计算或综合分析，思维过程较为直接。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用密度计算公式（ρ = n*A / V*N_A），但解题步骤较为直接，仅需代入给定的晶格参数和原子量进行计算，无需复杂的推导或多步骤组合。题目考察的是对基本公式的掌握和简单计算能力，符合等级2的标准。" + }, + { + "idx": 4663, + "question": "Beryllium (Be) has an HCP unit cell for which the ratio of the lattice parameters c/a is 1.568. If the radius of the Be atom is 0.1143 nm, determine the unit cell volume.", + "answer": "4.87 × 10^{-23} cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（HCP晶胞参数与原子半径的关系）来确定晶胞体积，答案是一个具体的数值结果（4.87 × 10^{-23} cm3），符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括HCP晶格参数与原子半径的关系、晶格参数c/a比的应用以及体积计算公式的综合运用。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力来正确应用公式和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解HCP晶体结构的基本概念，掌握晶格参数与原子半径的关系，并进行多步计算。题目要求考生能够将c/a比与原子半径联系起来，推导出晶格参数a和c的具体数值，最后计算单位晶胞体积。虽然题目提供了部分参数，但解题过程涉及多个步骤和概念的综合运用，在选择题型中属于需要一定分析和计算能力的题目。" + }, + { + "idx": 4664, + "question": "Beryllium (Be) has an HCP unit cell for which the ratio of the lattice parameters c/a is 1.568. If the radius of the Be atom is 0.1143nm, calculate the theoretical density of Be and compare it with the literature value.", + "answer": "the theoretical density of be is 1.84 g/cm3, and the literature value is 1.85 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（HCP晶胞参数、原子半径与密度的关系）来求解铍的理论密度，并将计算结果与文献值进行比较。答案呈现为具体数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括晶格参数计算、体积计算、密度计算等），并涉及HCP晶体结构的基本概念和公式应用，需要将多个知识点关联起来进行综合分析。虽然不涉及复杂的推理或创新设计，但思维过程比简单应用更为深入。 | 难度: 在选择题中属于中等偏上难度，需要理解HCP晶体结构参数关系、原子半径与晶格参数转换、理论密度计算公式等多个概念，并进行多步骤计算和文献值对比分析。虽然选择题提供了正确选项降低了部分难度，但仍需掌握晶体学知识和单位换算能力才能正确解答。" + }, + { + "idx": 4665, + "question": "Magnesium ( Mg ) has an HCP crystal structure, a c/a ratio of 1.624 , and a density of 1.74 \\mathrm{g} / {cm}^{3}. Compute the atomic radius for Mg.", + "answer": "the atomic radius for \\mathrm{mg} is 0.160\\;nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的原子半径，答案是一个具体的数值结果（0.160 nm），符合计算题的特征。 | 知识层次: 题目涉及HCP晶体结构的几何关系、密度与原子半径的计算，需要多步计算和概念关联，包括晶格参数与原子半径的关系、密度公式的应用等，思维过程有一定深度要求。 | 难度: 在选择题中属于中等偏上难度，需要理解HCP晶体结构、c/a比、密度与原子半径之间的关系，并进行多步计算。虽然题目提供了正确选项，但解题过程涉及单位转换、几何关系推导和代数运算，需要较强的综合分析能力。" + }, + { + "idx": 4666, + "question": "Cobalt (Co) has an HCP crystal structure, an atomic radius of 0.1253nm, and a c/a ratio of 1.623. Compute the volume of the unit cell for Co.", + "answer": "the volume of the unit cell for co is 6.64 × 10^{-23} {cm}^3 or 6.64 × 10^{-2} nm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钴的单位晶胞体积，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求计算HCP晶胞体积，涉及基本公式应用和简单计算，属于直接套用公式的简单应用层次。虽然需要理解HCP结构和相关参数，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用HCP晶体结构的体积计算公式，但题目已经提供了所有必要的参数（原子半径和c/a比），计算过程直接且无需复杂推导。学生只需正确代入公式并完成单位转换即可得到答案，属于基础层次的应用题。" + }, + { + "idx": 4667, + "question": "One crystalline form of silica \\left(\\mathrm{SiO}_{2}\\right) has a cubic unit cell, and from x-ray diffraction data it is known that the cell edge length is 0.700nm. If the measured density is 2.32g / {cm}^{3}, how many \\mathrm{Si}^{4+} and \\mathrm{O}^{2}-ions are there per unit cell?", + "answer": "there are 8 \\mathrm{si}^{4+} ions and 16 \\mathrm{o}^{2-} ions per \\mathrm{sio}_{2} unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解单位晶胞中的离子数量，涉及密度、晶胞边长等物理量的计算，答案也是具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括单位转换、密度公式应用以及离子数量的推导，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、密度计算和化学计量比的知识。解题步骤包括：" + }, + { + "idx": 4668, + "question": "A hypothetical AX type of ceramic material is known to have a density of 2.10g / {cm}^{3} and a unit cell of cubic symmetry with a cell edge length of 0.57nm. The atomic weights of the A and X elements are 28.5 and 30.0g / mol, respectively. On the basis of this information, which of the following crystal structures is (are) possible for this material: sodium chloride, cesium chloride, or zinc blende? Justify your choice(s).", + "answer": "of the three possible crystal structures, only sodium chloride and zinc blende have four formula units per unit cell, and therefore, are possibilities.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的三种晶体结构（sodium chloride, cesium chloride, zinc blende）中选择可能的选项，并需要根据提供的信息进行判断和论证。答案中明确指出只有两种结构是可能的，符合选择题的特征。 | 知识层次: 题目需要综合运用晶体结构知识、密度计算和单位晶胞分析，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算（如密度计算、单位晶胞内原子数计算）和综合分析（比较不同晶体结构的特征）。题目不仅要求掌握晶体结构的基本概念，还需要将理论知识与实际计算相结合，判断哪种晶体结构符合给定的材料参数。这种综合应用和分析过程在选择题中属于较复杂的判断类型。" + }, + { + "idx": 4669, + "question": "Iron titanate, FeTiO3, forms in the ilmenite crystal structure that consists of an HCP arrangement of O2- ions. Which type of interstitial site will the Fe2+ ions occupy? Why?", + "answer": "From Table, the cation-anion radius ratio is 0.077 nm / 0.140 nm = 0.550. Since this ratio is between 0.414 and 0.732, the Fe2+ ions will occupy octahedral sites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Fe2+离子占据哪种间隙位点及其原因，答案提供了基于半径比的计算和文字解释，属于需要论述的简答题类型。 | 知识层次: 题目需要应用半径比规则进行判断，涉及多步计算和概念关联，需要综合分析离子半径比与间隙位置的关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握离子半径比的计算方法，并能够根据计算结果判断离子占据的间隙位置类型。虽然涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了关键的计算步骤和结论，降低了整体难度。因此，该题目在选择题型内属于等级3的难度。" + }, + { + "idx": 4671, + "question": "Iron titanate, FeTiO3, forms in the ilmenite crystal structure that consists of an HCP arrangement of O2- ions. What fraction of the total tetrahedral sites will be occupied?", + "answer": "Since both Fe2+ and Ti4+ ions occupy octahedral sites, no tetrahedral sites will be occupied.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述特定晶体结构中四面体位点的占据情况，答案提供了文字解释而非数值计算或选择判断 | 知识层次: 题目需要理解ilmenite晶体结构中O2-离子的HCP排列方式，并分析Fe2+和Ti4+离子占据的八面体位点情况，进而推断四面体位点的占据情况。这涉及到多步的概念关联和综合分析，而不仅仅是简单的记忆或直接应用。 | 难度: 在选择题型中，该题目属于较高难度，需要考生掌握以下知识点并进行多角度分析：" + }, + { + "idx": 4673, + "question": "To what equation does the expression for interplanar spacing (d_{\text {hkl }}) reduce for crystals having cubic symmetry, given that (a,(b), and c are the lattice parameters?", + "answer": "For the crystals having cubic symmetry, a=b=c. Making this substitution into the given equation leads to (\frac{1}{d_{h k l}^{2}}=\frac{h^{2}}{a^{2}}+\frac{k^{2}}{a^{2}}+\frac{l^{2}}{a^{2}} = \frac{h^{2}+k^{2}+l^{2}}{a^{2}}).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释立方对称晶体的晶面间距表达式如何简化，答案提供了详细的推导过程和文字解释，符合简答题的特征。 | 知识层次: 题目要求将立方对称晶体的条件（a=b=c）代入晶面间距公式进行简化，属于基本公式的直接应用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求考生将立方晶系的对称性条件（a=b=c）直接代入晶面间距公式，并进行简单的代数运算。解题步骤明确且直接，无需复杂的推导或分析。考生只需掌握基本公式和简单计算能力即可正确作答，符合选择题型中等级2的简单应用要求。" + }, + { + "idx": 4674, + "question": "To what equation does the expression for interplanar spacing (d_{\text {hkl }}) reduce for crystals having tetragonal symmetry, given that a, b and c are the lattice parameters?", + "answer": "For crystals having tetragonal symmetry, a=b \neq c. Replacing b with a in the given equation leads to (\frac{1}{d_{h k l}^{2}}=\frac{h^{2}}{a^{2}}+\frac{k^{2}}{a^{2}}+\frac{l^{2}}{c^{2}} = \frac{h^{2}+k^{2}}{a^{2}}+\frac{l^{2}}{c^{2}}).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释并推导出特定晶体对称性下的晶面间距表达式，答案提供了详细的推导过程和最终公式，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求将四方晶系的对称性条件（a=b≠c）代入晶面间距公式进行简化，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式并进行简单的代数替换（将b替换为a）。解题步骤简单明确，无需复杂推导或深入理解多个概念，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 4675, + "question": "The number-average molecular weight of a polystyrene is 500,000g / mol. Compute the degree of polymerization.\n\\title{", + "answer": "the degree of polymerization is 4800.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚合度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求计算聚合度，涉及基本公式应用（分子量除以重复单元分子量）和简单计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算聚合度，只需要应用分子量与单体分子量的简单除法公式即可得出结果，无需复杂的推理或多步骤计算。因此，在选择题型内属于最基础的难度等级。" + }, + { + "idx": 4677, + "question": "High-density polyethylene may be chlorinated by inducing the random substitution of chlorine atoms for hydrogen. In what ways does this chlorinated polyethylene differ from poly(vinyl chloride)?", + "answer": "chlorinated polyethylene differs from poly(vinyl chloride) in that, for pvc, (1) 25% of the side-bonding sites are substituted with Cl, and (2) the substitution is probably much less random.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来比较两种材料的差异，答案提供了详细的文字说明而非选择、判断或计算。 | 知识层次: 题目要求比较两种高分子材料的差异，涉及对材料结构和性能的理解，需要综合分析氯原子取代方式和随机性对材料性质的影响，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多角度分析和论述。题目不仅要求理解高密度聚乙烯氯化与聚氯乙烯在氯原子取代方面的差异，还需要比较两种材料在取代位置（25% vs 随机）和取代规律性（非随机 vs 随机）的具体区别。这涉及到对高分子材料结构改性的深入理解，以及在不同条件下取代反应特性的综合分析。在选择题型内，这种需要同时掌握具体数据（25%）和反应机理（随机性）的题目较为复杂，属于等级4难度。" + }, + { + "idx": 4678, + "question": "Compare thermoplastic and thermosetting polymers on the basis of mechanical characteristics upon heating.", + "answer": "Thermoplastic polymers soften when heated and harden when cooled, whereas thermosetting polymers harden upon heating, while further heating will not lead to softening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种聚合物在加热时的机械特性，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生同时理解和区分两种聚合物（热塑性和热固性）在加热时的不同机械特性。正确选项不仅要求记忆各自定义，还需要进行简单的对比分析。这比单纯记忆单一概念（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 4679, + "question": "Compare thermoplastic and thermosetting polymers according to possible molecular structures.", + "answer": "Thermoplastic polymers have linear and branched structures, while for thermosetting polymers, the structures will normally be network or crosslinked.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种聚合物的分子结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性聚合物和热固性聚合物分子结构的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目要求考生比较热塑性聚合物和热固性聚合物的分子结构，并选择正确的描述。虽然涉及两个概念的比较，但知识点相对基础，属于定义和分类的记忆性知识。解题步骤较为直接，只需识别并匹配正确的结构特征即可，不需要复杂的分析或推理过程。因此，在选择题型中属于中等偏下的难度等级。" + }, + { + "idx": 4680, + "question": "The number-average molecular weight of a poly(acrylonitrile-butadiene) alternating copolymer is 1,000,000g / mol; determine the average number of acrylonitrile and butadiene repeat units per molecule.", + "answer": "the average number of acrylonitrile and butadiene repeat units per molecule is 9333.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定高分子链中重复单元的平均数量，需要应用分子量和重复单元分子量的公式进行计算，答案是一个具体的数值结果。 | 知识层次: 题目需要计算交替共聚物的重复单元数量，涉及分子量的概念和公式应用，需要多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解交替共聚物的分子量计算概念，掌握重复单元分子量的计算，并进行多步综合运算才能得出正确结果。虽然题目提供了正确选项，但解题过程涉及分子结构分析、摩尔质量计算和除法运算等多个步骤，属于综合性计算问题。" + }, + { + "idx": 4681, + "question": "Calculate the number-average molecular weight of a random poly(isobutylene-isoprene) copolymer in which the fraction of isobutylene repeat units is 0.25 ; assume that this concentration corresponds to a degree of polymerization of 1500 .", + "answer": "the number-average molecular weight of the poly(isobutylene-isoprene) copolymer is \\bar{m}_{n} = 97,700g/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算数均分子量），并给出了具体的计算条件和参数（重复单元分数和聚合度）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及分子量的计算和重复单元分数的应用，需要理解并关联多个概念，如聚合度、重复单元分子量等，并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解共聚物的数均分子量计算概念，掌握重复单元分子量的加权平均方法，并能正确应用聚合度进行计算。题目涉及多步计算和概念关联，但选项已经给出了明确的计算结果，减少了推导过程的复杂性。" + }, + { + "idx": 4682, + "question": "An alternating copolymer is known to have a number-average molecular weight of 100,000g / mol and a degree of polymerization of 2210 . If one of the repeat units is ethylene, which of styrene, propylene, tetrafluoroethylene, and vinyl chloride is the other repeat unit? Why?", + "answer": "the other repeat unit is vinyl chloride, with a molecular weight of 62.49 \\mathrm{g/mol}. this matches the calculated value of 62.45 \\mathrm{g/mol} for the unknown repeat unit.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（styrene, propylene, tetrafluoroethylene, and vinyl chloride）中选择正确的重复单元，并解释原因。答案也明确指出了选择的是哪一个选项（vinyl chloride）。 | 知识层次: 题目需要计算未知重复单元的分子量，并对比给定的选项进行匹配。这涉及多步计算和概念关联，需要综合分析已知信息（如数均分子量和聚合度）来推导出正确的重复单元。虽然不涉及复杂的推理或机理解释，但需要一定的应用能力和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解交替共聚物的基本概念，并能够进行分子量和聚合度的计算。其次，需要通过计算推导出未知重复单元的正确选项，这涉及多步计算和综合分析。此外，题目还要求考生对乙烯、苯乙烯、丙烯、四氟乙烯和氯乙烯等单体的分子量有准确的记忆或计算能力。整个过程不仅需要概念理解，还需要较强的计算能力和综合分析能力，因此在选择题型中属于复杂分析过程的判断难度等级。" + }, + { + "idx": 4683, + "question": "(a) Determine the ratio of butadiene to acrylonitrile repeat units in a copolymer having a number-average molecular weight of 250,000 g/mol and a degree of polymerization of 4640.", + "answer": "the ratio of butadiene to acrylonitrile repeat units in the copolymer is fb/fa = 4.0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定共聚物中丁二烯和丙烯腈重复单元的比例，答案是一个具体的数值结果（fb/fa = 4.0），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要多步计算和概念关联，包括分子量计算、重复单元比例确定以及聚合度应用，涉及综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解共聚物组成与分子量之间的关系，进行多步计算（包括分子量计算和比例求解），并正确关联聚合度与重复单元数的概念。虽然题目提供了正确选项，但解题过程涉及多个化学概念的整合和计算步骤的综合运用。" + }, + { + "idx": 4685, + "question": "Crosslinked copolymers consisting of 35 wt% ethylene and 65 wt% propylene may have elastic properties similar to those for natural rubber. For a copolymer of this composition, determine the fraction of both repeat unit types.\n\\title{", + "answer": "the fraction of the ethylene repeat unit is 0.45. the fraction of the propylene repeat unit is 0.55.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定乙烯和丙烯重复单元的比例，答案以数值形式给出，需要应用材料科学中的组成计算知识。 | 知识层次: 题目要求根据给定的重量百分比计算重复单元的比例，这属于基本的公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式进行简单计算，属于单一公式直接计算的难度等级。题目给出了明确的重量百分比，只需转换为摩尔分数即可得出正确选项，无需复杂步骤或多公式组合。" + }, + { + "idx": 4686, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (a) Linear and atactic poly(vinyl chloride); linear and isotactic polypropylene", + "answer": "No, it is not possible to decide for these two polymers. On the basis of tacticity, the isotactic PP is more likely to crystallize than the atactic PVC. On the other hand, with regard to side-group bulkiness, the PVC is more likely to crystallize.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释是否可能确定哪一种更容易结晶，以及给出理由或说明为什么无法决定。这需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求对不同聚合物的结晶可能性进行比较和判断，需要综合考虑聚合物的立构规整性和侧基体积等因素。这涉及到多个概念的关联和综合分析，属于中等应用层次。虽然不涉及复杂的计算或深度推理，但需要对材料科学中的基本概念有一定的理解和应用能力。 | 难度: 在选择题型中属于较高难度，需要同时考虑多个因素（链规整性和侧基体积效应）进行多角度分析，并能够识别两种相互矛盾的影响因素（等规度有利于结晶但大体积侧基阻碍结晶），最终得出无法确定的结论。这超出了简单的概念比较，需要进行综合判断和矛盾因素的权衡分析。" + }, + { + "idx": 4687, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (b) Linear and syndiotactic polypropylene; crosslinked cis-polyisoprene", + "answer": "Yes, it is possible to decide for these two copolymers. The linear and syndiotactic polypropylene is more likely to crystallize than crosslinked cis-isoprene because linear polymers are more likely to crystallize than crosslinked ones.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行比较，并给出理由或解释为什么可以或不可以决定哪一种更容易结晶。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的结晶可能性，并解释原因。这需要理解聚合物结构（线性与交联、立体规整性）对结晶性能的影响，属于多概念关联和综合分析。虽然不涉及复杂计算，但需要对聚合物结晶机理有一定理解，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅能够识别不同聚合物结构（线性、间规立构、交联）对结晶能力的影响，还需要能够比较两种不同聚合物（聚丙烯和聚异戊二烯）的结晶倾向。这涉及到对聚合物结晶基本原理的理解和应用，包括分子链的规整性、交联对结晶的影响等。虽然题目提供了明确的比较对象和判断标准，但仍需要考生综合运用相关知识进行判断和解释。" + }, + { + "idx": 4688, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (c) Network phenol-formaldehyde; linear and isotactic polystyrene", + "answer": "Yes, it is possible to decide for these two polymers. The linear and isotactic polystyrene is more likely to crystallize than network phenol-formaldehyde; network polymers rarely crystallize, whereas isotactic ones crystallize relatively easily.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释哪一种更容易结晶以及原因。这需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求学生不仅需要理解聚合物结晶的基本原理（如网络聚合物和线性等规聚合物的结晶能力差异），还需要应用这些知识对不同类型聚合物进行比较和分析。这涉及到多个概念的关联和综合分析，而不仅仅是简单的记忆或直接套用。 | 难度: 在选择题中属于中等难度，需要理解聚合物结晶的基本原理（如网络结构vs线性结构、等规性对结晶的影响），并能对两种不同类型的聚合物（网络酚醛树脂和线性等规聚苯乙烯）进行对比分析。虽然不需要多步计算，但要求考生能够关联多个材料科学概念并做出正确判断。" + }, + { + "idx": 4689, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (d) Block poly(acrylonitrile-isoprene) copolymer; graft poly(chloroprene-isobutylene) copolymer", + "answer": "Yes, it is possible to decide for these two copolymers. The block poly(acrylonitrileisoprene) copolymer is more likely to crystallize than the graft poly(chloroprene-isobutylene) copolymer. Block copolymers crystallize more easily than graft ones.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行比较和解释，需要文字论述和理由说明，而不是简单的选择或判断。答案也提供了详细的解释和原因，符合简答题的特征。 | 知识层次: 题目要求对不同类型共聚物的结晶能力进行比较和判断，需要理解共聚物结构（嵌段与接枝）对结晶行为的影响，并进行综合分析。这涉及多个概念的关联和中等程度的推理分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生能够区分不同类型的共聚物（嵌段共聚物和接枝共聚物）的结晶能力，并理解其背后的原因。虽然题目提供了明确的选项，但考生需要掌握共聚物结构对结晶性能的影响这一知识点，并进行综合分析才能正确选择。这涉及到中等应用层次的知识，包括多步计算、概念关联和综合分析。" + }, + { + "idx": 4690, + "question": "For some hypothetical metal, the equilibrium number of vacancies at 900^{\\circ} C is 2.3 × 10^{25} m^{-3}. If the density and atomic weight of this metal are 7.40g / {cm}^{3} and 85.5g / mol, respectively, calculate the fraction of vacancies for this metal at 900^{\\circ} C.", + "answer": "the fraction of vacancies for this metal at 900^{\\circ} C is 4.41 × 10^{-4}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺分数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度和原子量的转换、原子密度的计算以及最终的空位分数计算。这需要理解空位形成的概念，并能将多个知识点（如密度、原子量、阿伏伽德罗常数）关联起来进行综合分析。虽然不涉及复杂的推理或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及计算金属中的空位分数，需要掌握密度、原子量和阿伏伽德罗常数等基本概念，并进行多步计算。虽然题目提供了必要的参数，但解题过程需要综合运用这些概念和公式，属于综合性计算问题。" + }, + { + "idx": 4691, + "question": "(a) Calculate the fraction of atom sites that are vacant for copper (Cu) at its melting temperature of 1084°C (1357 K). Assume an energy for vacancy formation of 0.90 eV/atom.", + "answer": "the fraction of atom sites that are vacant for copper at 1357 k is 4.56 × 10^-4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如使用能量和温度计算空缺分数）来得出具体数值结果，答案也是一个具体的计算结果（4.56 × 10^-4）。 | 知识层次: 题目要求使用给定的能量和温度计算空位分数，涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（空位分数计算公式）进行简单计算，无需多个步骤或复杂推理。题目提供了所有必要参数，学生只需正确代入数值即可得出答案。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4692, + "question": "(b) Repeat this calculation at room temperature (298 K). Assume an energy for vacancy formation of 0.90 eV/atom.", + "answer": "the fraction of atom sites that are vacant for copper at 298 k is 6.08 × 10^-16.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算空位分数），并给出了具体的计算条件和参数（温度298 K，空位形成能0.90 eV/atom）。答案是一个具体的数值结果（6.08 × 10^-16），这表明解答过程涉及公式应用和数值计算。 | 知识层次: 题目要求使用给定的能量值和温度进行简单的数值计算，直接套用公式计算空位分数，属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，属于最基础的难度等级。题目明确给出了所有必要参数（温度、空位形成能），只需将数值代入公式即可得出答案，无需额外的分析或组合多个公式。" + }, + { + "idx": 4693, + "question": "(c) What is ratio of N_V/N(1357 K) and N_V/N(298 K) ?", + "answer": "the ratio of n_v/n(1357 k) to n_v/n(298 k) is 7.5 × 10^11.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算两个温度下的N_V/N比值之比，并给出了具体的数值结果（7.5 × 10^11），这表明需要进行数值计算和公式应用。 | 知识层次: 题目需要进行多步计算，涉及不同温度下的比值计算，需要理解和应用相关公式，并综合分析计算结果。虽然不涉及复杂的推理或创新设计，但比简单应用更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解空位浓度与温度的关系公式，并进行两步独立计算（1357K和298K条件下的N_V/N比值），最后还需要对两个结果进行比值运算。虽然题目提供了正确选项，但解题过程涉及多个物理概念的关联和综合计算步骤，超出了基础选择题的范畴。" + }, + { + "idx": 4694, + "question": "Calculate the number of vacancies per cubic meter in gold (\\mathrm{Au}) at 900^{\\circ} C. The energy for vacancy formation is 0.98 \\mathrm{eV} / atom. Furthermore, the density and atomic weight for Au are 18.63 \\mathrm{g} / {cm}^{3} (at 900^{\\circ} C ) and 196.9g / mol, respectively.", + "answer": "the number of vacancies per cubic meter in gold at 900^{\\circ} C is 3.52 × 10^{24}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，涉及公式应用（如计算空位浓度），答案是一个具体的数值结果（3.52 × 10^{24}{m}^{-3}），符合计算题的特征。 | 知识层次: 题目需要多步计算和概念关联，包括应用阿伏伽德罗常数、密度和原子重量计算原子数，以及使用玻尔兹曼方程计算空位浓度。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点进行中等难度的计算。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念和公式进行计算。题目涉及的知识点包括空位浓度计算、能量单位转换、密度和原子量的应用等。解题步骤包括：1) 计算金的原子密度；2) 利用空位形成能和温度计算空位浓度；3) 进行单位转换和指数运算。虽然题目提供了所有必要参数，但需要考生熟练掌握相关公式并能正确进行多步计算，在选择题型中属于需要较强综合分析能力的题目。" + }, + { + "idx": 4695, + "question": "Calculate the fraction of lattice sites that are Schottky defects for cesium chloride at its melting temperature \\left(645^{\\circ} C\\right). Assume an energy for defect formation of 1.86 \\mathrm{eV}.", + "answer": "the fraction of lattice sites that are schottky defects for cesium chloride at its melting temperature is 7.87 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，涉及公式应用（计算Schottky缺陷的分数），答案是一个具体的数值结果（7.87 × 10^{-6}），符合计算题的特征。 | 知识层次: 题目需要应用Schottky缺陷的形成能公式进行计算，涉及多步计算和温度转换（摄氏度转开尔文），同时需要理解缺陷浓度与温度的关系。虽然计算过程相对直接，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Schottky缺陷的概念，掌握能量与温度的关系，并进行多步骤计算（包括单位转换和指数运算）。虽然题目提供了必要的参数，但需要综合应用热力学和缺陷化学的知识来解决问题。" + }, + { + "idx": 4696, + "question": "In your own words, briefly define the term stoichiometric.", + "answer": "Stoichiometric means having exactly the ratio of anions to cations as specified by the chemical formula for the compound.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用自己的话简要解释术语\"stoichiometric\"，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查基本概念的记忆和理解，要求对\"stoichiometric\"这一术语进行定义，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并复述\"stoichiometric\"的基本定义，属于最基础的概念记忆层次。正确选项直接给出了术语的标准定义，不需要任何解释、分析或应用过程，完全符合等级1\"基本定义简答\"的标准。这类题目在选择题中属于最简单的一类，只需识别定义即可作答。" + }, + { + "idx": 4697, + "question": "Under conditions where cupric oxide (CuO) is exposed to reducing atmospheres at elevated temperatures, some of the Cu2+ ions will become Cu+. Name one crystalline defect that you would expect to form in order to maintain charge neutrality.", + "answer": "For a Cu2+ O2- compound in which a small fraction of the copper ions exist as Cu+, for each Cu+ formed there is one less positive charge introduced (or one more negative charge). In order to maintain charge neutrality, we must either add an additional positive charge or subtract a negative charge. This may be accomplished be either creating Cu2+ interstitials or O2- vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释并命名一种晶体缺陷以维持电荷中性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释在特定条件下（CuO在高温还原气氛中部分Cu2+转变为Cu+）如何通过形成晶体缺陷来维持电荷中性。这需要综合运用晶体缺陷知识、电荷平衡原理以及氧化还原反应的理解，涉及多概念的关联和机理解释，思维过程较为深入。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶体缺陷的基本概念，还需要综合运用电荷平衡原理和氧化还原反应的知识，进行机理层面的深度解释。解题过程中需要分析CuO在还原气氛下的化学变化，并推理出维持电中性的具体缺陷类型（Cu2+间隙或O2-空位），这涉及到复杂现象的全面分析和多步骤的逻辑推理。在选择题型内，此类需要综合多个高阶认知技能的问题属于最难级别。" + }, + { + "idx": 4698, + "question": "Under conditions where cupric oxide (CuO) is exposed to reducing atmospheres at elevated temperatures, some of the Cu2+ ions will become Cu+. How many Cu+ ions are required for the creation of each defect?", + "answer": "There will be two Cu+ ions required for each of these defects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下Cu2+离子转变为Cu+离子的缺陷形成机制，并具体说明每个缺陷需要多少个Cu+离子。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解CuO在还原气氛下的缺陷形成机制，并分析Cu2+还原为Cu+的电荷平衡关系。这涉及多步概念关联和综合分析，但不需要复杂的机理解释或创新应用。 | 难度: 在选择题中属于较高难度，需要理解氧化铜在还原气氛下的缺陷形成机制，并能够进行多步计算和概念关联。题目不仅考察了学生对Cu2+和Cu+离子转换的理解，还要求综合分析缺陷形成的化学计量关系，这超出了基础记忆和简单应用的层次。" + }, + { + "idx": 4699, + "question": "Under conditions where cupric oxide (CuO) is exposed to reducing atmospheres at elevated temperatures, some of the Cu2+ ions will become Cu+. How would you express the chemical formula for this nonstoichiometric material?", + "answer": "The chemical formula for this nonstoichiometric material is Cu1+ O or CuO1-x, where x is some small fraction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述非化学计量材料的化学式表达方式，答案需要提供具体的化学式并解释变量含义，属于需要文字表述的简答题类型。 | 知识层次: 题目要求理解非化学计量材料的化学式表达，需要将氧化还原反应的概念与材料化学式表达相结合，属于中等应用层次。虽然不涉及复杂计算，但需要对材料在特定条件下的变化有较深入的理解，并能正确表达非化学计量比。 | 难度: 在选择题中属于较高难度，需要理解非化学计量比材料的概念，并能够将Cu2+还原为Cu+的化学变化与化学式表达联系起来。此外，题目要求考生能够正确表达非化学计量比材料的化学式，这需要一定的综合分析能力和对化学概念的理解深度。" + }, + { + "idx": 4700, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for FeO.", + "answer": "For FeO, the ionic radii of the Mg2+ and Fe2+ are 0.072 nm and 0.077 nm, respectively. The percentage difference in ionic radii is 6.5%, which is within the acceptable range for a high degree of solubility. Additionally, both MgO and FeO have rock salt crystal structures. Therefore, FeO and MgO are expected to form high degrees of solid solubility, and experimentally, they exhibit 100% solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释FeO与MgO形成完全固溶体的原因，答案提供了详细的文字解释和论述，包括离子半径差异百分比和晶体结构相似性等分析，符合简答题的特征。 | 知识层次: 题目要求解释FeO与MgO形成完全固溶体的原因，涉及离子半径比较、百分比差异计算以及晶体结构匹配性的分析。虽然不需要复杂的推理或创新，但需要综合多个知识点进行解释，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目不仅要求考生掌握离子半径和晶体结构的基本概念，还需要进行多步计算（离子半径百分比差异）和综合分析（结合半径差异和晶体结构判断溶解度）。此外，题目还要求考生能够将理论知识与实验现象（100%溶解度）联系起来，体现了多角度分析论述的能力。" + }, + { + "idx": 4701, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for BaO.", + "answer": "For BaO, the ionic radii of the Mg2+ and Ba2+ are 0.072 nm and 0.136 nm, respectively. The percentage difference in ionic radii is 47%, which is much larger than the acceptable range. Therefore, BaO is not expected to experience any appreciable solubility in MgO. Experimentally, the solubility of BaO in MgO is very small.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释BaO在MgO中的固溶度问题，需要文字解释和论述，而不是从选项中选择或简单判断对错。答案中提供了详细的离子半径比较和百分比差异分析，属于典型的简答题形式。 | 知识层次: 题目需要理解固溶体的形成条件，特别是离子半径差异对溶解度的影响，并进行简单的百分比计算。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅掌握离子半径的概念，还需要计算百分比差异，并将其与溶解度标准进行比较。此外，还需要理解实验数据与理论预测之间的关系，进行多角度分析论述。" + }, + { + "idx": 4702, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for PbO.", + "answer": "For PbO, the ionic radii of the Mg2+ and Pb2+ are 0.072 nm and 0.120 nm, respectively. The percentage difference in ionic radii is 40%, which is much larger than the acceptable range. Therefore, PbO is not expected to experience any appreciable solubility in MgO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么PbO不会与MgO形成完全固溶体，需要文字论述和解释，而不是简单的选择或判断。答案中提供了详细的离子半径比较和百分比差异分析，符合简答题的特征。 | 知识层次: 题目要求学生应用离子半径差异的概念来分析固溶体的溶解度，需要理解并应用Hume-Rothery规则中的离子半径差异标准。虽然涉及的知识点较为基础，但需要学生进行多步分析和解释，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅掌握离子半径的概念，还需要计算百分比差异并理解其在固溶体溶解度中的应用。这涉及到多步计算和概念关联，属于中等应用层次的知识。此外，题目要求对PbO在MgO中的溶解度进行综合分析，这比简单的概念识别或单一计算更为复杂。因此，在选择题型中，该题目属于较高难度，需要考生具备较强的综合分析能力。" + }, + { + "idx": 4703, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for CoO.", + "answer": "For CoO, the ionic radii of the Mg2+ and Co2+ are 0.072 nm and 0.072 nm, respectively. The percentage difference in ionic radii is 0%, which is within the acceptable range for a high degree of solubility. Therefore, CoO and MgO are expected to form high degrees of solid solubility, likely 100%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么CoO能与MgO形成完全固溶体，需要文字论述和解释，而不是简单的选择或判断 | 知识层次: 题目需要理解固溶体的形成条件，并应用离子半径差异的计算来判断溶解度。虽然涉及基础概念，但需要综合分析离子半径差异对固溶体形成的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握离子半径的概念，并能计算百分比差异，同时需要理解固溶体的形成条件。虽然涉及多步计算和概念关联，但在选择题型中，这些步骤相对直接，不需要过于复杂的推导或深度关联性分析。" + }, + { + "idx": 4704, + "question": "Suppose that CaO is added as an impurity to Li2O. If the Ca2+ substitutes for Li+, what kind of vacancies would you expect to form? How many of these vacancies are created for every Ca2+ added?", + "answer": "For Ca2+ substituting for Li+ in Li2O, lithium vacancies would be created. For each Ca2+ substituting for Li+, one positive charge is added; in order to maintain charge neutrality, a single positive charge may be removed. Positive charges are eliminated by creating lithium vacancies, and for every Ca2+ ion added, a single lithium vacancy is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释Ca2+取代Li+时形成的空位类型及其数量，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解杂质掺杂对晶体缺陷的影响，并分析电荷平衡机制。虽然涉及基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解掺杂过程中的电荷平衡原理，并能将Ca2+替代Li+的电荷变化与空位形成机制关联起来。解题步骤涉及多步逻辑推理（电荷补偿计算、空位类型判断），且需要综合分析晶体缺陷与电荷守恒的相互作用。虽然题目提供了明确选项，但概念关联和计算复杂度明显高于基础选择题。" + }, + { + "idx": 4705, + "question": "Suppose that CaO is added as an impurity to CaCl2. If the O2- substitutes for Cl-, what kind of vacancies would you expect to form? How many of these vacancies are created for every O2- added?", + "answer": "For O2- substituting for Cl- in CaCl2, chlorine vacancies would be created. For each O2- substituting for a Cl-, one negative charge is added; negative charges are eliminated by creating chlorine vacancies. In order to maintain charge neutrality, one O2- ion will lead to the formation of one chlorine vacancy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述O2-替代Cl-时形成的空位类型及其数量，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解杂质替代的电荷平衡原理，并分析由此产生的空位类型和数量。虽然涉及基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及杂质掺杂和电荷平衡的概念，要求考生能够分析O2-取代Cl-对晶体缺陷的影响，并计算相应的空位数量。虽然不需要复杂的计算，但需要综合理解电荷补偿机制和缺陷化学的基本原理。" + }, + { + "idx": 4706, + "question": "Which of these elements would you expect to form a substitutional solid solution having complete solubility with nickel? The four Hume-Rothery rules must be satisfied: (1) the difference in atomic radii between Ni and the other element (ΔR%) must be less than ±15%; (2) the crystal structures must be the same; (3) the electronegativities must be similar; and (4) the valences should be the same.", + "answer": "Pt is the only element that meets all of the criteria and thus forms a substitutional solid solution having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素中选择满足Hume-Rothery规则的选项，并给出了具体的选择标准。答案明确指出Pt是唯一符合条件的元素，符合选择题的特征。 | 知识层次: 题目要求应用Hume-Rothery规则进行综合分析，涉及多个条件的判断（原子半径差异、晶体结构、电负性、价态），需要将多个概念关联起来进行推理，属于中等应用层次。虽然不涉及复杂计算，但需要综合运用多个知识点进行分析判断。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 4708, + "question": "Which of these elements would you expect to form an interstitial solid solution with nickel? The four Hume-Rothery rules must be satisfied: (1) the difference in atomic radii between Ni and the other element (ΔR%) must be less than ±15%; (2) the crystal structures must be the same; (3) the electronegativities must be similar; and (4) the valences should be the same.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Ni.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素中选择符合Hume-Rothery规则的选项，形成间隙固溶体。答案明确给出了选项（C, H, and O），符合选择题的特征。 | 知识层次: 题目要求应用Hume-Rothery规则进行综合分析，涉及原子半径、晶体结构、电负性和价态等多个因素的判断，需要一定的概念关联和综合分析能力。虽然不涉及复杂计算，但需要对多个规则进行理解和应用，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合应用Hume-Rothery规则的所有四个条件进行判断。题目要求考生不仅理解原子半径差异（ΔR% < ±15%）这一基本条件，还需要考虑晶体结构、电负性和化合价等其他三个规则。此外，正确选项涉及的是间隙固溶体（interstitial solid solution），这需要考生能够区分间隙固溶体和置换固溶体的形成条件，并识别出C、H、O等小原子半径元素的特点。这种多条件综合分析和概念区分的要求使得该题目在选择题型中属于复杂分析过程的判断难度等级。" + }, + { + "idx": 4709, + "question": "What is the composition, in atom percent, of an alloy that consists of 92.5 wt% \\mathrm{Ag} and 7.5 wt% Cu ?", + "answer": "the composition of the alloy is 87.9 \\text{ at}% \\text{ ag} and 12.1 \\text{ at}% \\text{ cu}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如重量百分比转换为原子百分比）来得出具体的数值结果，答案也是以数值形式呈现的。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及原子百分比和重量百分比之间的转换，属于直接套用基本公式的简单应用。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用原子百分比和重量百分比之间的转换公式，但计算步骤相对直接，仅涉及基本代数运算和单位转换。不需要复杂的逻辑推理或多步骤的综合计算，因此难度等级为2。" + }, + { + "idx": 4710, + "question": "What is the composition, in atom percent, of an alloy that consists of 5.5 wt% \\mathrm{~Pb} and 94.5 wt% \\mathrm{Sn} ?", + "answer": "the composition of the alloy is 3.23 \\text{ at% pb} and 96.77 \\text{ at% sn}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如原子百分比的计算）来确定合金的组成，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的重量百分比到原子百分比的转换计算，需要应用简单的公式和原子量数据，属于直接套用基本公式的简单计算题。 | 难度: 在选择题型内，该题目属于简单公式应用计算。虽然需要应用原子百分比和重量百分比之间的转换公式，但计算步骤相对直接，仅涉及基本公式的套用和简单代数运算。不需要多个公式的组合或复杂的推导过程，因此难度等级为2。" + }, + { + "idx": 4711, + "question": "What is the composition, in weight percent, of an alloy that consists of 5 at% Cu and 95 at% Pt?", + "answer": "the composition in weight percent is: 1.68 wt% cu \n98.32 wt% pt", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（原子百分比转换为重量百分比）来得出合金的成分，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的原子百分比到重量百分比的转换计算，需要应用简单的公式和基本的元素原子量知识，属于直接套用和简单计算范畴。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用原子百分比与重量百分比之间的转换公式，但计算步骤直接且明确，仅涉及基本公式的套用和简单代数运算。题目提供了所有必要的数据，且无需复杂的推理或多步骤分析，因此难度等级为2。" + }, + { + "idx": 4712, + "question": "Calculate the composition, in weight percent, of an alloy that contains 105kg of iron, 0.2 kg of carbon, and 1.0kg of chromium.\n\\title{", + "answer": "the composition, in weight percent, of the alloy is: c_{\\mathrm{fe}} = 98.87 \\, \\text{wt}% c_{C} = 0.19 \\, \\text{wt}% c_{\\mathrm{cr}} = 0.94 \\, \\text{wt}%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算合金中各成分的重量百分比），答案是通过公式应用得出的具体数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本的重量百分比计算，只需要应用简单的公式（各组分质量除以总质量）并进行数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用重量百分比的基本公式进行计算，属于单一公式直接计算的简单应用。解题步骤简单明确，只需将各组分质量除以总质量并转换为百分比，无需复杂分析或多步骤推理，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 4713, + "question": "What is the composition, in atom percent, of an alloy that contains 44.5 lb m of \\mathrm{Ag}, 83.7 lb_{m} of \\mathrm{Au}, and 5.3 lb_{m} of Cu ?", + "answer": "the composition of the alloy in atom percent is: c_{\\mathrm{ag}} = 44.8 \\, \\text{at}% c_{\\mathrm{au}} = 46.2 \\, \\text{at}% c_{\\mathrm{cu}} = 9.0 \\, \\text{at}% ", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算合金中各元素的原子百分比组成，需要通过数值计算和公式应用来得出答案。答案以具体的数值形式呈现，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括将质量转换为摩尔数，然后计算各元素的原子百分比。这需要理解原子百分比的概念，并能够应用相关的计算公式。虽然不涉及复杂的综合分析或推理，但比简单的直接套用公式要复杂一些。 | 难度: 在选择题中属于中等偏上难度，需要进行多步骤计算和概念关联。题目要求将质量百分比转换为原子百分比，涉及计算各元素的质量、摩尔数以及最终的原子百分比。虽然选择题提供了正确选项，但解题过程需要综合运用化学计量和材料科学的基础知识，属于中等应用层次的计算问题。" + }, + { + "idx": 4714, + "question": "Calculate the number of atoms per cubic meter in \\mathrm{Pb}.", + "answer": "3.30 × 10^{28} atoms/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铅中每立方米的原子数），并给出了具体的数值答案，这符合计算题的特征。 | 知识层次: 题目要求计算铅的原子密度，这涉及基本的公式应用（如密度、摩尔质量和阿伏伽德罗常数的关系）和简单计算。虽然需要理解相关概念，但计算过程直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（如密度、摩尔质量和阿伏伽德罗常数的关系）进行简单计算，无需多个公式组合或复杂推理。属于单一公式直接计算的难度等级。" + }, + { + "idx": 4715, + "question": "Calculate the number of atoms per cubic meter in chromium.", + "answer": "the number of atoms per cubic meter in chromium is 8.33 × 10^{28} \\ \\text{atoms/m}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铬中每立方米的原子数），答案是一个具体的数值结果（8.33 × 10^{28} atoms/m^3），这符合计算题的特征。 | 知识层次: 题目要求计算铬中每立方米的原子数，这需要应用基本的密度和摩尔质量公式进行简单计算，属于直接套用基本公式的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算铬的原子密度，可以直接套用已知的铬的原子密度公式或数据（8.33 × 10^{28} atoms/m^3），无需进行复杂的推导或多步骤计算。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4716, + "question": "The concentration of \\mathrm{Si} in an \\mathrm{Fe}-\\mathrm{Si} alloy is 0.25 wt%. What is the concentration in kilograms of Si per cubic meter of alloy?", + "answer": "the concentration of \\mathrm{si} is 19.6kg / m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定硅在合金中的浓度，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的浓度单位转换和简单的公式应用，不需要多步计算或综合分析，属于直接套用基本公式的简单应用。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接计算（将重量百分比转换为体积浓度），无需复杂步骤或多公式组合。学生只需应用基本转换公式即可得出正确答案，属于最基础的难度等级。" + }, + { + "idx": 4717, + "question": "Determine the approximate density of a Ti-6Al-4V titanium alloy that has a composition of 90 wt% \\mathrm{Ti}, 6 wt% \\mathrm{Al}, and 4 wt% V.", + "answer": "the approximate density of the ti-6al-4v titanium alloy is 4.38 \\mathrm{g/cm}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定钛合金的近似密度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用密度计算公式，结合各成分的质量分数和密度进行简单计算，属于基本公式的直接套用和简单计算。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算Ti-6Al-4V钛合金的近似密度，只需应用简单的密度加权平均公式，无需复杂的推导或多步骤计算。正确选项直接给出了计算结果，考生只需确认计算过程是否正确即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4718, + "question": "Calculate the unit cell edge length for an 80 wt% \\mathrm{Ag}-20 wt% \\mathrm{Pd} alloy. All of the palladium is in solid solution, the crystal structure for this alloy is FCC, and the roomtemperature density of P d is 12.02g / {cm}^{3}.", + "answer": "the unit cell edge length for an 80 wt% \\mathrm{ag}-20 wt% \\mathrm{pd} alloy is 0.4050nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解合金的单位晶胞边长，答案是一个具体的数值结果（0.4050nm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括合金密度计算、原子质量计算和晶格常数计算，涉及多个概念的综合应用和关联分析。虽然不涉及复杂的推理或机理解释，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解合金成分、晶体结构（FCC）、密度计算等多个概念，并进行多步骤的综合计算。虽然题目提供了正确选项，但解题过程涉及单位转换、质量分数与原子分数的转换、以及晶格常数的计算，这些步骤在选择题型中属于较为复杂的综合分析问题。" + }, + { + "idx": 4719, + "question": "Some hypothetical alloy is composed of 25 wt% of metal A and 75 wt% of metal B. If the densities of metals A and B are 6.17 and 8.00g / {cm}^{3}, respectively, and their respective atomic weights are 171.3 and 162.0g / mol, determine whether the crystal structure for this alloy is simple cubic, face-centered cubic, or body-centered cubic. Assume a unit cell edge length of 0.332nm.", + "answer": "the crystal structure is simple cubic with 1.00 atom per unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行一系列数值计算，包括重量百分比、密度、原子重量和单位晶胞边长等，以确定晶体结构类型。答案基于计算结果得出，而非从给定选项中选择或简单判断对错。 | 知识层次: 题目需要进行多步计算，包括质量分数到原子分数的转换、密度计算、单位晶胞原子数的确定等，涉及多个概念的综合应用和关联分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念并进行多步计算。题目涉及合金成分、密度、原子量以及晶体结构的综合分析，解题步骤包括计算合金密度、确定单位晶胞中的原子数等，需要较强的概念关联和计算能力。" + }, + { + "idx": 4720, + "question": "Molybdenum (Mo) forms a substitutional solid solution with tungsten (W). Compute the number of molybdenum atoms per cubic centimeter for a molybdenum-tungsten alloy that contains 16.4 wt% Mo and 83.6 wt% W. The densities of pure molybdenum and tungsten are 10.22 and 19.30g / {cm}^{3}, respectively.", + "answer": "1.73 × 10^{22} \\text{ atoms/cm}^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算钼原子数每立方厘米），涉及公式应用（如密度、质量分数转换等），答案也是具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括质量分数转换为原子分数、计算合金密度、以及最终计算原子数量，涉及多个概念的综合应用和关联分析。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体、原子百分比与重量百分比的转换、密度计算等多个概念，并进行多步骤的综合计算。虽然题目给出了正确选项，但解题过程涉及多个知识点的关联和综合运用，属于综合性计算问题。" + }, + { + "idx": 4721, + "question": "Niobium forms a substitutional solid solution with vanadium. Compute the number of niobium atoms per cubic centimeter for a niobium-vanadium alloy that contains 24 wt% nb and 76 wt% V. The densities of pure niobium and vanadium are 8.57 and 6.10g / {cm}^{3}, respectively.", + "answer": "the number of niobium atoms per cubic centimeter is 1.02 × 10^{22} \\text{atoms/cm}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算铌钒合金中每立方厘米的铌原子数量，涉及数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括质量分数转换为原子分数、计算合金密度、以及最终计算铌原子数密度。虽然不涉及复杂的推理分析，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算。题目涉及固溶体、质量分数、密度计算以及原子数转换等多个知识点，需要考生综合运用这些知识进行解题。虽然题目给出了正确选项，但解题过程需要计算合金的总体积、各组分体积以及原子数转换，步骤较为复杂。" + }, + { + "idx": 4722, + "question": "For a BCC iron-carbon alloy that contains 0.1 wt% C, calculate the fraction of unit cells that contain carbon atoms.\n\\title{", + "answer": "the fraction of unit cells that contain carbon atoms is 9.31 × 10^{-3} atoms/unit cell. there is one carbon atom per 107.5 unit cells.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞中包含碳原子的比例，答案给出了具体的计算结果和单位，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算碳原子在BCC铁碳合金中的浓度，并将其转换为单位晶胞中的碳原子分数。这涉及到对BCC晶体结构的理解、原子浓度的计算以及单位晶胞的概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、碳原子固溶度、单位晶胞计算等多个概念，并进行多步骤的综合计算。虽然题目给出了具体数值，但考生需要掌握原子百分比与重量百分比的转换、单位晶胞原子数的计算等知识，并能够将这些概念联系起来进行综合分析。这种需要多步骤计算和概念关联的题目在选择题型中属于较复杂的类型。" + }, + { + "idx": 4723, + "question": "Gold (Au) forms a substitutional solid solution with silver (Ag). Compute the weight percent of gold that must be added to silver to yield an alloy that contains 5.5 × 10^{21} \\mathrm{Au} atoms per cubic centimeter. The densities of pure \\mathrm{Au} and \\mathrm{Ag} are 19.32 and 10.49g / {cm}^{3}, respectively.", + "answer": "15.9 wt%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解合金中金的重量百分比，答案是一个具体的数值（15.9 wt%），解答过程需要涉及密度、原子数等物理量的计算。 | 知识层次: 题目需要进行多步计算，包括原子浓度转换、密度计算和重量百分比计算，需要综合运用材料科学中的固溶体概念和数学计算能力。虽然不涉及复杂的机理分析或创新设计，但需要较强的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体、原子浓度、密度和重量百分比等多个概念，并进行多步计算和单位转换。虽然题目提供了正确选项，但解题过程涉及计算合金中金和银的原子数、体积分数以及最终的重量百分比，步骤较为复杂，需要较强的综合分析能力。" + }, + { + "idx": 4724, + "question": "Germanium (Ge) forms a substitutional solid solution with silicon (Si). Compute the weight percent of germanium that must be added to silicon to yield an alloy that contains 2.43 × 10^{21} Ge atoms per cubic centimeter. The densities of pure \\mathrm{Ge} and \\mathrm{Si} are 5.32 and 2.33g / {cm}^{3}, respectively.", + "answer": "11.7 wt%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解需要添加的锗的重量百分比，答案是一个具体的数值结果（11.7 wt%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子密度计算、质量分数转换等，并需要理解固溶体的基本概念和密度与原子数的关系。虽然不涉及复杂的推理分析，但需要综合应用多个知识点进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体、原子浓度、密度和重量百分比等多个概念，并进行多步计算和综合分析。虽然题目提供了正确选项，但解题过程涉及单位转换、原子量计算和密度应用，步骤较为复杂，属于综合性计算问题。" + }, + { + "idx": 4725, + "question": "For an ASTM grain size of 6, approximately how many grains would there be per square inch at a magnification of 100x?", + "answer": "32 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出ASTM晶粒尺寸为6时，在100倍放大下每平方英寸的晶粒数量。解答需要应用ASTM晶粒尺寸计算公式，属于数值计算类问题。答案以具体数值形式给出，符合计算题的特征。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，仅需直接套用公式进行简单计算即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用ASTM晶粒度的基本公式进行计算，无需额外的概念理解或复杂的解题步骤。属于单一公式直接计算的简单题目。" + }, + { + "idx": 4726, + "question": "For an ASTM grain size of 6, approximately how many grains would there be per square inch without any magnification?", + "answer": "320000 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出具体的数值结果（320000 grains/in.^2），涉及ASTM晶粒尺寸标准的公式应用，属于典型的计算题。 | 知识层次: 题目考查ASTM晶粒度标准的基本公式应用，仅需直接套用公式N=2^(n-1)进行计算，属于单一知识点、单步计算的简单应用。 | 难度: 在选择题型中，该题目仅需直接应用ASTM晶粒度计算公式，无需复杂步骤或多公式组合。属于单一公式直接计算的简单应用，符合等级1的标准。" + }, + { + "idx": 4727, + "question": "Determine the ASTM grain size number if 30 grains per square inch are measured at a magnification of 250 ×.", + "answer": "the astm grain size number is 8.6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数值，答案是一个具体的数值结果（8.6），符合计算题的特征。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，仅需直接套用公式进行简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用ASTM grain size number的计算公式，但题目已经提供了所有必要的参数（30 grains per square inch和250× magnification），只需直接套用公式即可得出结果。解题步骤相对简单，不需要复杂的推理或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 4728, + "question": "Determine the ASTM grain size number if 25 grains per square inch are measured at a magnification of 75 ×.", + "answer": "the astm grain size number is 4.8.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数值，答案是一个具体的数值结果（4.8），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用ASTM晶粒度计算公式进行简单计算，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要基本公式应用和简单计算。虽然需要套用ASTM grain size number的计算公式，但步骤较为直接，仅涉及单一公式的代入和简单数学运算，无需多个公式组合或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4729, + "question": "Briefly explain the difference between self-diffusion and interdiffusion.", + "answer": "Self-diffusion is atomic migration in pure metals--i.e., when all atoms exchanging positions are of the same type. Interdiffusion is diffusion of atoms of one metal into another metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释两种扩散的区别，答案以文字解释和论述的形式呈现，没有选项或计算要求。 | 知识层次: 题目考查对自扩散和互扩散这两个基本概念的定义和区别的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求考生解释两个相关但不同的概念（self-diffusion和interdiffusion），并区分它们的关键特征。虽然涉及基础概念记忆，但需要一定的理解能力来正确描述和对比这两个过程，而不仅仅是简单的定义复述。这属于概念解释和描述的难度级别。" + }, + { + "idx": 4730, + "question": "Self-diffusion involves the motion of atoms that are all of the same type; therefore, it is not subject to observation by compositional changes, as with interdiffusion. Suggest one way in which self-diffusion may be monitored.", + "answer": "Self-diffusion may be monitored by using radioactive isotopes of the metal being studied. The motion of these isotopic atoms may be detected by measurement of radioactivity level.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出一种监测自扩散的方法，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求学生理解自扩散的概念，并能够提出一种监测方法。这需要将放射性同位素的知识与扩散现象联系起来，属于概念关联和综合分析的应用层次。 | 难度: 在选择题中属于中等难度，需要理解自扩散的基本概念，并能够联想到放射性同位素的应用。虽然不需要复杂的计算，但需要将两个知识点（自扩散和放射性同位素监测）进行关联分析，属于中等应用层次的要求。" + }, + { + "idx": 4731, + "question": "Compare interstitial and vacancy atomic mechanisms for diffusion.", + "answer": "With vacancy diffusion, atomic motion is from one lattice site to an adjacent vacancy. Self-diffusion and the diffusion of substitutional impurities proceed via this mechanism. On the other hand, atomic motion is from interstitial site to adjacent interstitial site for the interstitial diffusion mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种扩散机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对间隙扩散和空位扩散两种原子扩散机制的基本概念的理解和记忆，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目要求考生理解和比较两种不同的扩散机制（间隙扩散和空位扩散），并能够描述它们的基本原理和区别。虽然涉及多个概念，但题目提供了明确的定义和分类，属于概念解释和描述的层次，不需要进行复杂的体系阐述或深入分析。因此，难度等级为2。" + }, + { + "idx": 4732, + "question": "Cite two reasons why interstitial diffusion is normally more rapid than vacancy diffusion.", + "answer": "Interstitial diffusion is normally more rapid than vacancy diffusion because: (1) interstitial atoms, being smaller, are more mobile; and (2) the probability of an empty adjacent interstitial site is greater than for a vacancy adjacent to a host (or substitutional impurity) atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个原因来解释间隙扩散比空位扩散更快，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对间隙扩散和空位扩散两种机制的基本理解和记忆，需要解释两种扩散速率差异的原因，属于基础概念的记忆和简单应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举两个原因，但这两个原因都是基础概念的直接应用，不需要复杂的推理或分析。学生需要理解并记忆间隙扩散和空位扩散的基本原理，并能够区分两者的特点。这比单纯的定义记忆（等级1）要求稍高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 4733, + "question": "A sheet of steel 5.0-mm thick has nitrogen atmospheres on both sides at 900^{\\circ} C and is permitted to achieve a steady-state diffusion condition. The diffusion coefficient for nitrogen in steel at this temperature is 1.85 × 10^{-10}{m}^{2} / s, and the diffusion flux is found to be 1.0 × 10^{-7} kg / m^{2}·s. Also, it is known that the concentration of nitrogen in the steel at the high-pressure surface is 2kg / m^{3}. How far into the sheet from this high-pressure side will the concentration be 0.5kg / m^{3} ? Assume a linear concentration profile.", + "answer": "the concentration will be 0.5 \\mathrm{kg/m}^{3} at a distance of 2.78 mm from the high-pressure side.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用（如菲克第一定律）来求解氮浓度在钢板中的分布距离，答案是一个具体的数值结果（2.78 mm），符合计算题的特征。 | 知识层次: 题目涉及稳态扩散条件下的菲克第一定律应用，需要多步计算（包括浓度梯度计算和距离求解），并理解线性浓度分布的概念。虽然不涉及复杂的机理分析或创新设计，但需要综合运用扩散系数、扩散通量和浓度梯度等概念进行数值计算。 | 难度: 在选择题中属于中等难度，需要理解扩散系数、扩散通量、浓度梯度等概念，并进行多步计算和综合分析。题目要求考生能够应用菲克第一定律，建立线性浓度分布模型，并通过代数运算求解距离。虽然计算步骤较多，但在选择题型中，正确选项的存在降低了部分难度，因此属于等级3。" + }, + { + "idx": 4734, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 15h duration will raise the carbon concentration to 0.35 wt% at a point 2.0mm from the surface. Estimate the time necessary to achieve the same concentration at a 6.0-mm position for an identical steel and at the same carburizing temperature.", + "answer": "the time necessary to achieve the same concentration at a 6.0-mm position is 135 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的条件和扩散方程来估算时间。答案是一个具体的数值结果（135 h），表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数调整，需要理解碳浓度与时间和位置的关系，并进行综合分析来求解新的时间。 | 难度: 在选择题中属于中等难度，需要理解扩散定律（如菲克第二定律）并进行多步计算。题目要求在不同位置达到相同碳浓度，需要综合分析距离与时间的关系（x²∝t），并正确应用比例关系进行计算。虽然计算步骤明确，但需要将概念知识与数学推导结合，属于综合性计算问题。" + }, + { + "idx": 4735, + "question": "The preexponential and activation energy for the diffusion of chromium in nickel are 1.1 × 10^{-4}{m}^{2} / s and 272,000 J/ mol, respectively. At what temperature will the diffusion coefficient have a value of 1.2 × 10^{-14}{m}^{2} / s ?", + "answer": "the temperature at which the diffusion coefficient has a value of 1.2 × 10^{-14} m^{2} / s is 1427 k or 1154^{\\circ} C. alternatively, using the vmse software, the temperature is found to be 1430 k.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数公式（阿伦尼乌斯方程）进行数值计算，求解特定扩散系数对应的温度。答案给出了具体的计算结果和单位，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及对数运算和单位转换，需要理解公式中各参数的含义及其相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解扩散系数的阿伦尼乌斯方程，并进行多步骤的计算和单位转换。虽然题目提供了必要的参数，但解题过程涉及对数运算和温度单位的转换，需要一定的综合分析能力。" + }, + { + "idx": 4736, + "question": "The activation energy for the diffusion of copper in silver is 193,000 J/ mol. Calculate the diffusion coefficient at 1200 K\\left(927^{\\circ} C\\right), given that D at 1000 K\\left(727^{\\circ} C\\right) is 1.0 × 10^{-14}{m}^{2} / s.", + "answer": "the diffusion coefficient at 1200k is 4.8 × 10^{-13}{m}^{2} / s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和扩散系数数据，应用阿伦尼乌斯方程进行数值计算，以求解在特定温度下的扩散系数。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及扩散系数与温度的关系，需要理解活化能的概念并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解扩散系数的概念，掌握阿伦尼乌斯方程的应用，并进行多步骤的计算。题目涉及温度转换、对数运算和指数计算，要求考生能够综合运用这些知识来解决问题。虽然题目提供了部分已知条件，但解题过程仍然需要一定的综合分析能力。" + }, + { + "idx": 4738, + "question": "The steady-state diffusion flux through a metal plate is 7.8 × 10^{-8}kg / m^{2}·s at a temperature of 1200^{\\circ} C(1473 K) and when the concentration gradient is -500kg / m^{4}. Calculate the diffusion flux at 1000^{\\circ} C(1273 K) for the same concentration gradient and assuming an activation energy for diffusion of 145,000 J/ mol.", + "answer": "the diffusion flux at 1000^{\\circ} C(1273k) is 1.21 × 10^{-8}kg / m^{2}·s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散通量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散通量的公式，并涉及温度变化对扩散系数的影响，需要进行多步计算和概念关联。虽然不涉及复杂的机理分析或创新设计，但需要理解和应用阿伦尼乌斯方程来计算不同温度下的扩散通量，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散通量、温度与扩散系数的关系（阿伦尼乌斯方程），并进行多步骤计算。虽然题目提供了部分参数，但仍需综合运用多个概念和公式来求解，属于综合性计算问题。" + }, + { + "idx": 4739, + "question": "Consider the diffusion of some hypothetical metal Y into another hypothetical metal Z at 950^{\\circ} C; after 10h the concentration at the 0.5mm position (in metal Z) is 2.0 wt% Y. At what position will the concentration also be 2.0 wt% Y after a 17.5h heat treatment again at 950^{\\circ} C ? Assume preexponential and activation energy values of 4.3 × 10^{-4}{m}^{2} / s and 180,000 J/ mol, respectively, for this diffusion system.", + "answer": "the position will be 0.66 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和参数代入，最终得出具体数值结果。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数代入，需要理解扩散系数与时间和位置的关系，并进行综合分析。虽然不涉及复杂的机理解释或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的应用并进行多步计算。题目涉及扩散系数的计算、时间与位置关系的综合分析，以及数学运算能力。虽然给出了正确选项，但解题过程需要较强的概念关联和计算能力。" + }, + { + "idx": 4740, + "question": "Carbon dioxide diffuses through a high-density polyethylene (HDPE) sheet 50mm thick at a rate of 2.2 × 10^{-8}\\left(cm^{3} STP / {cm}^{2}\\right.-s at 325 K. The pressures of carbon dioxide at the two faces are 4000 kPa and 2500 kPa, which are maintained constant. Assuming conditions of steady state, what is the permeability coefficient at 325 K ?", + "answer": "the permeability coefficient at 325k is 0.73 × 10^{-13} \\frac{{cm}^{3} \\mathrm{stp}·{cm}}{{cm}^{2}·s·\\mathrm{pa}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解渗透系数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用扩散定律和稳态条件，涉及压力差和厚度的综合分析，需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散速率、压力差和渗透系数的关系，并进行多步计算。题目涉及稳态条件下的渗透系数计算，需要综合应用菲克定律和渗透系数的定义，属于综合性计算问题。虽然计算步骤明确，但需要正确关联概念和单位转换，对学生的理解能力和计算能力有一定要求。" + }, + { + "idx": 4741, + "question": "A cylindrical specimen of a nickel alloy having an elastic modulus of 207 \\mathrm{GPa}\\left(30 × 10^{6} psi\\right) and an original diameter of 10.2 mm(0.40 in.) experiences only elastic deformation when a tensile load of 8900N\\left(2000 lb f_{\\mathrm{f}}\\right) is applied. Compute the maximum length of the specimen before deformation if the maximum allowable elongation is 0.25 mm(0.010 in.).", + "answer": "the maximum length of the specimen before deformation is 0.475{m} (475mm or 18.7 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最大长度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用胡克定律、应力应变关系以及几何变形公式，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用弹性模量、应力应变关系、几何变形等多重概念，并进行多步骤计算（包括应力计算、应变推导和几何关系转换）。虽然题目提供了关键参数，但解题过程涉及多个物理公式的串联应用和单位转换，对学生的概念关联和综合分析能力要求较高。" + }, + { + "idx": 4742, + "question": "An aluminum bar 125mm (5.0 in.) long and having a square cross section 16.5mm (0.65 in.) on an edge is pulled in tension with a load of 66,700N(15,000 lb) and experiences an elongation of 0.43 mm(1.7 × 10^{-2} in.). Assuming that the deformation is entirely elastic, calculate the modulus of elasticity of the aluminum.", + "answer": "the modulus of elasticity of the aluminum is 71.2 gpa (10.4 × 10^{6} psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（长度、截面积、载荷、伸长量）进行数值计算，应用胡克定律公式来求解铝的弹性模量。答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目要求应用基本公式（胡克定律）进行简单的弹性模量计算，涉及直接套用公式和单位换算，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用胡克定律和应力应变公式，但计算步骤直接且无需复杂推导。题目明确给出了所有必要参数，只需套用公式即可得出答案，属于基础应用层次。" + }, + { + "idx": 4743, + "question": "Consider a cylindrical nickel wire 2.0 mm(0.08 in.) in diameter and 3 × 10^{4}mm (1200 in.) long. Calculate its elongation when a load of 300N\\left(67 lb^{2}\\right) is applied. Assume that the deformation is totally elastic.", + "answer": "the elongation of the nickel wire is 13.8mm (0.53 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性变形公式）来求解镍丝的伸长量，答案是一个具体的数值结果（13.8mm），符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即胡克定律和弹性变形公式的直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要应用胡克定律的基本公式（应力=弹性模量×应变）进行简单计算。虽然涉及单位转换和代数运算，但解题步骤直接且无需多个公式组合，因此属于等级2难度。" + }, + { + "idx": 4744, + "question": "For a brass alloy, the stress at which plastic deformation begins is 345 MPa (50,000 psi), and the modulus of elasticity is 103 GPa (15.0 x 10^6 psi). What is the maximum load that can be applied to a specimen with a cross-sectional area of 130 mm^2 (0.2 in.^2) without plastic deformation?", + "answer": "the maximum load that can be applied without plastic deformation is 44,850 n (10,000 lb_f).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应力、模量等）来求解最大载荷，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的应力计算和公式应用，只需要直接套用应力公式（应力=力/面积）来计算最大载荷，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（应力=力/面积）进行计算，无需组合多个公式或进行复杂的概念分析。题目提供了所有必要的数据，解题步骤简单直接，属于最基础的难度等级。" + }, + { + "idx": 4745, + "question": "For a brass alloy, the stress at which plastic deformation begins is 345 MPa (50,000 psi), and the modulus of elasticity is 103 GPa (15.0 x 10^6 psi). If the original specimen length is 76mm (3.0 in.), what is the maximum length to which it can be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen can be stretched without causing plastic deformation is 76.25mm (3.01 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定最大拉伸长度，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的应力-应变关系公式应用，即胡克定律（σ = Eε），需要计算弹性变形范围内的最大长度变化。计算过程直接，仅需一步公式应用和简单代数运算，无需多步推理或综合分析。 | 难度: 在选择题型内，该题目仅需要直接应用胡克定律（Hooke's Law）进行单一公式计算，即通过应力、弹性模量和原始长度计算最大弹性变形长度。解题步骤简单，无需组合多个公式或进行复杂分析，属于最基础的难度等级。" + }, + { + "idx": 4746, + "question": "A cylindrical rod of steel (E=207 \\mathrm{GPa}, 30 × 10^{6} psi) having a yield strength of 310 MPa(45,000 psi) is to be subjected to a load of 11,100N(2500 lb). If the length of the rod is 500 mm(20.0 in.), what must be the diameter to allow an elongation of 0.38 mm(0.015 in.)?", + "answer": "the diameter must be 9.5 mm (0.376 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定圆柱形钢棒的直径。解答过程涉及弹性模量、载荷和伸长量等参数的计算，最终得出具体的直径数值。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即胡克定律和应力应变关系的直接套用，无需多步计算或综合分析。 | 难度: 在选择题中属于简单公式应用计算难度。题目要求直接应用胡克定律和圆柱体横截面积公式，步骤较为直接，只需进行简单代数运算即可得出答案。虽然涉及单位转换，但在选择题型中，这些步骤被简化，因为正确选项已经给出，减少了计算错误的可能性。" + }, + { + "idx": 4747, + "question": "A cylindrical specimen of a metal alloy 10 mm(0.4 in.) in diameter is stressed elastically in tension. A force of 15,000N(3,370 lb r) produces a reduction in specimen diameter of 7 × 10^{-3} mm(2.8 × 10^{-4} in.). Compute Poisson's ratio for this material if its elastic modulus is 100 \\mathrm{GPa} \\left(14.5 × 10^{6} psi\\right).", + "answer": "poisson's ratio for the material is v = 0.367 .", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解泊松比，需要运用弹性力学相关公式进行计算，最终给出一个具体的数值结果。 | 知识层次: 题目需要应用弹性模量和泊松比的定义，进行多步计算，包括应力、应变的计算以及泊松比的推导。虽然不涉及复杂的综合分析或创新应用，但需要理解相关概念并进行关联计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。该题目涉及弹性模量、泊松比的计算，需要综合运用力学和材料科学的知识，进行多步计算和概念关联。虽然题目给出了部分参数，但仍需要考生具备较强的综合分析能力来正确解答。" + }, + { + "idx": 4748, + "question": "Consider a cylindrical specimen of some hypothetical metal alloy that has a diameter of 10.0 mm(0.39 in.). A tensile force of 1500N(340 lb) produces an elastic reduction in diameter of 6.7 × 10^{-4} mm(2.64 ×\n10^{-5} in.). Compute the elastic modulus of this alloy, given that Poisson's ratio is 0.35 .", + "answer": "100 gpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性模量的计算）来求解，答案是一个具体的数值（100 GPa），而不是选择、判断或文字解释。 | 知识层次: 题目需要进行多步计算，包括应用弹性模量、泊松比和应变之间的关系，涉及概念关联和综合分析。虽然计算过程较为直接，但需要理解和应用多个材料科学的基本原理，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用弹性模量、泊松比和应变计算等多个概念，并进行多步骤计算。虽然题目提供了所有必要参数，但解题过程涉及多个公式转换和单位换算，对学生的概念理解和计算能力要求较高。" + }, + { + "idx": 4749, + "question": "A cylindrical rod 500mm (20.0 in.) long and having a diameter of 12.7mm (0.50 in.) is to be subjected to a tensile load of 29,000 N (6500 lb). Which of the four metals or alloys listed in the table can experience neither plastic deformation nor an elongation of more than 1.3mm (0.05 in.)?", + "answer": "Of the four metal alloys listed, only brass and steel satisfy the stipulated criteria. Brass has an elongation of 1.15 mm, and steel has an elongation of 0.56 mm, both of which are less than the maximum allowed elongation of 1.3 mm.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从四个金属或合金中选择满足特定条件的材料，答案明确指出了符合条件的选项，符合选择题的特征。 | 知识层次: 题目要求考生在给定的条件下，通过计算和比较多个金属或合金的性能参数（如塑性变形和伸长量），来判断哪些材料满足特定的工程要求。这涉及到多步计算（如应力、应变的计算）和综合分析（比较不同材料的性能），属于中等应用层次。虽然不涉及复杂的机理分析或创新设计，但需要考生能够关联多个概念并进行综合判断。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生进行多步计算，包括应力、应变和伸长量的计算。其次，需要考生综合分析材料性能表格中的数据，并将计算结果与题目要求进行比较。此外，题目还涉及塑性变形和弹性变形的概念理解，要求考生能够将理论知识与实际应用相结合。虽然题目提供了正确选项，但解题过程较为复杂，需要较强的综合分析能力和计算能力，因此在选择题型中属于等级4的难度。" + }, + { + "idx": 4750, + "question": "Why is aluminum alloy not a candidate for the cylindrical rod subjected to a tensile load of 29,000 N (6500 lb) with a maximum allowed elongation of 1.3mm (0.05 in.)?", + "answer": "Aluminum alloy is not a candidate because its elongation of 1.64mm exceeds the limit.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释为什么铝合金不适合作为圆柱杆的材料，答案提供了文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要结合材料的力学性能（如伸长率）和实际应用条件（如载荷和允许变形量）进行综合分析，涉及多步计算和概念关联，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解材料力学性能（如弹性模量、伸长率）并进行多步计算，同时将计算结果与给定限制条件进行综合分析判断。虽然题目提供了具体数值，但考生仍需掌握相关公式和概念才能正确评估铝合金是否满足要求。" + }, + { + "idx": 4751, + "question": "Why is copper not considered for the cylindrical rod subjected to a tensile load of 29,000 N (6500 lb) with a maximum allowed elongation of 1.3mm (0.05 in.)?", + "answer": "Copper is not considered due to its lower yield strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么铜不被考虑用于特定应用场景，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解铜的力学性能（如屈服强度）与具体工程应用（如承受拉伸载荷和允许伸长量）之间的关系，并进行综合分析判断。这涉及多步思考和概念关联，超出了简单记忆或直接套用的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及对材料性能（如屈服强度）的理解，以及如何将其应用于具体工程场景（如拉伸载荷下的伸长限制）。虽然题目提供了具体数值，但正确选项要求考生能够将铜的力学性能与题目要求进行关联分析，而不是简单的记忆或单一概念的应用。这需要中等层次的应用能力和综合分析能力。" + }, + { + "idx": 4754, + "question": "The following true stresses produce the corresponding true plastic strains for a brass alloy:\n\\begin{tabular}{cc}\n\\hline True Stress (psi) & True Strain \\\\\n\\hline 60,000 & 0.15 \\\\\n70,000 & 0.25 \\\\\n\\hline\n\\end{tabular}\nWhat true stress is necessary to produce a true plastic strain of 0.21 ?", + "answer": "the true stress necessary to produce a true plastic strain of 0.21 is 66,400 \\, \\text{psi} (460 mpa).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了数据表格，要求通过计算得出特定应变下的真实应力。解答过程需要应用材料科学中的应力-应变关系公式进行数值计算，最终给出具体数值答案。 | 知识层次: 题目需要应用基本公式（如应力-应变关系）进行简单计算，属于直接套用公式的范畴，无需多步计算或综合分析。 | 难度: 在选择题中属于简单应用难度，需要理解基本公式（如应力-应变关系）并进行简单计算。题目提供了直接的数据点，只需进行线性插值即可得出结果，无需复杂的推导或多步骤计算。" + }, + { + "idx": 4756, + "question": "A three-point bending test was performed on an aluminum oxide specimen having a circular cross section of radius 5.0 mm(0.20 in.); the specimen fractured at a load of 3000N (675 lb f) when the distance between the support points was 40mm (1.6 in.). Another test is to be performed on a specimen of this same material, but one that has a square cross section of 15mm (0.6 in.) length on each edge. At what load would you expect this specimen to fracture if the support point separation is maintained at 40mm (1.6 in.)?", + "answer": "the specimen with a square cross section would be expected to fracture at a load of 17,200 n (3870 lb f).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解另一个试样的断裂载荷，答案是一个具体的数值结果，解答过程需要应用材料力学中的三点弯曲测试公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及三点弯曲测试的公式应用和不同截面形状的转换计算，需要综合分析材料的力学行为和几何参数的影响。 | 难度: 在选择题中属于中等难度，需要理解三点弯曲测试的基本原理，掌握圆形和方形截面的惯性矩计算，并能正确应用断裂载荷公式进行多步计算。题目涉及材料力学和几何转换的综合应用，但选择题型提供了正确选项，降低了部分难度。" + }, + { + "idx": 4758, + "question": "Would you be 100% certain of the answer in part (a)? Why or why not?", + "answer": "the certainty of this prediction is not 100% because there is always some variability in the flexural strength for ceramic materials, and the calculated stress is relatively close to the flexural strength, so there is some chance that fracture will occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么不能100%确定答案，需要文字论述和解释，而不是选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求学生分析陶瓷材料弯曲强度的不确定性，并解释为什么预测结果不能100%确定。这需要学生理解材料性能的变异性，并能将理论计算与实际材料行为进行关联和推理分析。题目涉及的知识点较为复杂，需要综合运用材料科学原理和概率思维，思维过程的深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4759, + "question": "Compute the modulus of elasticity for the nonporous material given that the modulus of elasticity for spinel (MgAl2O4) having 5 vol% porosity is 240 GPa (35 x 10^6 psi).", + "answer": "the modulus of elasticity for the nonporous material is 265 gpa (38.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔材料的弹性模量，答案是一个具体的数值计算结果。 | 知识层次: 题目需要应用多孔材料弹性模量的计算公式，进行多步计算和概念关联，涉及孔隙率对材料性能的影响分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解孔隙率对弹性模量的影响，并应用相关公式进行多步计算。题目要求从已知多孔材料的弹性模量反推无孔隙材料的弹性模量，涉及概念关联和综合分析能力。虽然题目给出了正确选项，但解题过程需要掌握材料科学中孔隙率与力学性能的关系，并正确应用修正公式进行计算。" + }, + { + "idx": 4760, + "question": "Compute the modulus of elasticity for 15 vol% porosity given that the modulus of elasticity for spinel (MgAl2O4) having 5 vol% porosity is 240 GPa (35 x 10^6 psi).", + "answer": "the modulus of elasticity for 15 vol% porosity is 195 gpa (28.4 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解15 vol%孔隙率下的弹性模量，答案也是一个具体的数值结果。 | 知识层次: 题目需要应用多步计算和公式推导，涉及孔隙率对弹性模量的影响分析，需要理解材料性能与孔隙率的关系并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解孔隙率对弹性模量的影响，并应用相关公式进行多步计算。题目要求从已知5%孔隙率的数据推导15%孔隙率的结果，涉及概念关联和综合分析能力，但作为选择题，正确选项的存在降低了部分解题难度。" + }, + { + "idx": 4761, + "question": "Compute the modulus of elasticity for the nonporous titanium carbide (TiC) given that the modulus of elasticity for titanium carbide (TiC) having 5 vol% porosity is 310 GPa (45 x 10^6 psi).", + "answer": "the modulus of elasticity for the nonporous material is 342 gpa (49.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔碳化钛的弹性模量，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用多步计算和公式推导，涉及孔隙率对弹性模量的影响，需要理解并应用相关公式进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解孔隙率对弹性模量的影响，并应用相关公式进行多步计算。题目涉及中等应用层次的知识，要求考生能够综合分析并正确计算非多孔材料的弹性模量。虽然题目提供了部分数据，但仍需考生具备一定的材料科学基础和计算能力来推导正确答案。" + }, + { + "idx": 4762, + "question": "At what volume percent porosity will the modulus of elasticity for titanium carbide (TiC) be 240 GPa (35 x 10^6 psi)?", + "answer": "the volume percent porosity at which the modulus of elasticity is 240 gpa (35 x 10^6 psi) is 17.1 vol%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定钛碳化物的体积百分比孔隙率，以达到特定的弹性模量值。答案是一个具体的数值结果（17.1 vol%），这表明需要进行计算才能得出答案。 | 知识层次: 题目需要进行多步计算，涉及弹性模量与孔隙率的关系公式应用，需要综合分析材料性能参数并运用数学计算得出结果，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性模量与孔隙率的关系公式（如经验公式或理论模型），进行多步代数运算或查表计算，并正确应用单位换算（GPa与psi）。虽然题目提供了具体数值，但解题过程涉及材料性能参数的综合分析和公式推导能力，比单纯的概念识别题更复杂。" + }, + { + "idx": 4763, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{ll} \\hline (\\sigma_{f_{S}}(\\mathbf{M P a})) & (\boldsymbol{P}) \\ \\hline 70 & 0.10 \\ 60 & 0.15 \\ \\hline \\end{tabular} (a) Compute the flexural strength for a completely nonporous specimen of this material.", + "answer": "the flexural strength for a completely nonporous specimen of this material is 95.3 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据计算非多孔试样的弯曲强度，需要使用公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要应用公式进行多步计算，涉及孔隙率与弯曲强度之间的关系，需要理解并应用相关公式来推导无孔隙材料的弯曲强度。这超出了简单应用的范围，但不需要复杂的分析或综合能力。 | 难度: 在选择题中属于中等偏上难度，需要理解陶瓷材料弯曲强度与孔隙率之间的关系，并能够运用给定的数据进行多步计算（如建立方程、求解未知数等）。虽然题目提供了部分数据，但解题过程涉及概念关联和综合分析，要求考生具备一定的材料科学基础知识和计算能力。" + }, + { + "idx": 4764, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{ll} \\hline (\\sigma_{f_{S}}(\\mathbf{M P a})) & (\boldsymbol{P}) \\ \\hline 70 & 0.10 \\ 60 & 0.15 \\ \\hline \\end{tabular} (b) Compute the flexural strength for a 0.20 volume fraction porosity.", + "answer": "the flexural strength for a 0.20 volume fraction porosity is 51.5 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的数据计算特定孔隙率下的弯曲强度，需要使用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求基于给定的数据应用基本公式进行计算，属于直接套用公式的简单应用。虽然需要理解公式的含义，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解并应用一个基本公式来计算弯曲强度，但解题步骤相对直接，仅涉及简单的代数运算和公式套用。与更复杂的需要多个公式组合或深入概念分析的题目相比，此题的难度较低。" + }, + { + "idx": 4765, + "question": "For some viscoelastic polymers that are subjected to stress relaxation tests, the stress decays with time according to\n\\[\n\\sigma(t)=\\sigma(0) \\exp \\left(-\\frac{t}{\\tau}\\right)\n\\]\nwhere \\sigma(t) and \\sigma(0) represent the time-dependent and initial (i.e., time =0 ) stresses, respectively, and t and \\tau denote elapsed time and the relaxation time, respectively; \\tau is a time-independent constant characteristic of the material. A specimen of a viscoelastic polymer whose stress relaxation obeys Equation was suddenly pulled in tension to a measured strain of 0.5 ; the stress necessary to maintain this constant strain was measured as a function of time. Determine E_{f}(10) for this material if the initial stress level was 3.5 MPa(500 psi), which dropped to 0.5 MPa(70 psi) after 30s.", + "answer": "e_{f}(10) = 3.66 \\text{mpa} (522 \\text{psi})", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的公式和初始条件进行数值计算，最终得出一个具体的数值结果（E_{f}(10) = 3.66 \\text{mpa}）。解答过程涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目需要应用给定的应力松弛公式进行多步计算，包括初始应力和松弛时间的确定，以及最终计算E_f(10)。虽然公式直接给出，但需要理解公式中各参数的含义，并进行适当的代数运算和数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及应力松弛测试的基本概念、指数衰减公式的应用以及多步计算过程。虽然题目提供了公式和初始条件，但需要考生正确理解并应用这些信息进行综合计算，才能得出正确的弹性模量值。这要求考生具备一定的材料科学知识背景和计算能力。" + }, + { + "idx": 4766, + "question": "The following table gives a number of Rockwellg hardness values that were measured on a single steel specimen. Compute average and standard deviation hardness values.\n\\begin{tabular}{rrr}\n47.3 & 48.7 & 47.1 \\\\\n52.1 & 50.0 & 50.4 \\\\\n45.6 & 46.2 & 45.9 \\\\\n49.9 & 48.3 & 46.4 \\\\\n47.6 & 51.1 & 48.5 \\\\\n50.4 & 46.7 & 49.7\n\\end{tabular}", + "answer": "the average hardness value is 48.4 hrg. the standard deviation of the hardness values is 1.95 hrg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Rockwell硬度值的平均值和标准差，需要应用数值计算和统计公式，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本的数值计算和标准偏差公式的直接应用，不需要多步计算或复杂的概念关联，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，需要计算平均值和标准差。虽然涉及两个统计量的计算，但都是直接套用基本公式，步骤较为简单。不需要复杂的推理或多步骤组合，因此属于等级2。" + }, + { + "idx": 4767, + "question": "The following table gives a number of yield strength values (in MPa) that were measured on the same aluminum alloy. Compute average and standard deviation yield strength values.\n\\begin{tabular}{rrr}\n274.3 & 277.1 & 263.8 \\\\\n267.5 & 258.6 & 271.2 \\\\\n255.4 & 266.9 & 257.6 \\\\\n270.8 & 260.1 & 264.3 \\\\\n261.7 & 279.4 & 260.5\n\\end{tabular}", + "answer": "the average yield strength is 265.9 \\text{ mpa}. the standard deviation of the yield strength is 7.34 \\text{ mpa}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算平均屈服强度和标准偏差，需要数值计算和公式应用 | 知识层次: 题目主要涉及基本的统计计算（平均值和标准差），属于直接套用公式的应用层面，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察基本公式应用和简单计算能力。虽然需要计算平均值和标准差，但题目已经给出了所有数据，且计算步骤相对直接，只需套用公式即可得出结果。不需要复杂的分析或组合多个公式，因此属于等级2难度。" + }, + { + "idx": 4768, + "question": "What is the first criterion upon which factors of safety are based?", + "answer": "The first criterion is consequences of failure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个简短的陈述，而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查安全系数基本准则的记忆和理解，属于基础概念层次 | 难度: 在选择题型中，此题仅考察对基础定义的记忆，属于最简单的难度等级。题目直接询问安全系数的首要标准，正确选项明确给出了\"失效后果\"这一基本定义，不需要任何解释或分析步骤。学生只需记住这个基础概念即可正确作答，符合选择题型中最基础的知识点掌握要求。" + }, + { + "idx": 4769, + "question": "What is the second criterion upon which factors of safety are based?", + "answer": "The second criterion is previous experience.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个简短的陈述句，不需要计算或选择选项 | 知识层次: 题目考查对安全系数第二准则的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别安全系数的第二个标准（previous experience），属于基础概念记忆层面的简单问题。不需要解释或分析，只需从选项中选出正确表述即可，符合等级1的基本定义简答标准。" + }, + { + "idx": 4770, + "question": "What is the third criterion upon which factors of safety are based?", + "answer": "The third criterion is accuracy of measurement of mechanical forces and/or material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释第三个安全系数的标准，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对安全系数基础标准的记忆和理解，属于基本概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆安全系数的第三个标准，但这是基础概念记忆层面的知识，不需要复杂的分析或推理。题目仅要求考生回忆并识别正确的定义，属于\"概念解释和描述\"层次，比简单定义稍复杂但远未达到复杂概念体系阐述的程度。" + }, + { + "idx": 4771, + "question": "What is the fourth criterion upon which factors of safety are based?", + "answer": "The fourth criterion is economics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的问题，答案需要以文字形式给出解释或论述，而不是从选项中选择或进行判断、计算。 | 知识层次: 题目考查对安全系数基础分类标准的记忆，属于基本概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的第四准则，属于直接回忆性知识，无需解释或分析。题目结构简单，正确选项明确，符合等级1的基本定义简答标准。" + }, + { + "idx": 4772, + "question": "Consider a metal single crystal oriented such that the normal to the slip plane and the slip direction are at angles of 60^{\\circ} and 35^{\\circ}, respectively, with the tensile axis. If the critical resolved shear stress is 6.2 MPa(900 psi), will an applied stress of 12 MPa (1750 psi) cause the single crystal to yield? If not, what stress will be necessary?", + "answer": "the applied stress of 12 MPa will not cause the single crystal to yield. the necessary stress for yielding to occur is 15.1 MPa (2200 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，特别是涉及临界分解剪应力和施加应力的比较，以及计算必要的应力值。答案提供了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括应用临界分切应力公式和角度关系，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解临界分解剪应力的概念，并进行多步骤计算（包括角度转换和应力分解）。虽然题目提供了具体数值，但解题过程涉及综合分析能力，要求考生能够正确应用公式并判断结果。" + }, + { + "idx": 4773, + "question": "A single crystal of zinc is oriented for a tensile test such that its slip plane normal makes an angle of 65 degrees with the tensile axis. Three possible slip directions make angles of 30 degrees, 48 degrees, and 78 degrees with the same tensile axis. Which of these three slip directions is most favored?", + "answer": "the most favored slip direction is at an angle of 30 degrees with the tensile axis.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述哪个滑移方向最有利，而不是从给定的选项中选择答案。答案需要基于对滑移方向和角度关系的理解进行解释。 | 知识层次: 题目需要理解滑移面和滑移方向的概念，并应用施密特定律（Schmid's Law）计算不同滑移方向的施密特因子（Schmid factor），然后比较这些因子以确定最有利的滑移方向。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及晶体滑移方向的选择，需要考生掌握滑移面、滑移方向与拉伸轴夹角的关系，并能够计算和比较不同滑移方向的施密特因子（Schmid factor）。虽然题目给出了具体角度，但仍需考生理解哪个角度最有利于滑移（即施密特因子最大），这需要一定的综合分析能力。" + }, + { + "idx": 4774, + "question": "A single crystal of zinc is oriented for a tensile test such that its slip plane normal makes an angle of 65 degrees with the tensile axis. The most favored slip direction makes an angle of 30 degrees with the same tensile axis. If plastic deformation begins at a tensile stress of 2.5 MPa (355 psi), determine the critical resolved shear stress for zinc.", + "answer": "the critical resolved shear stress for zinc is 0.91 mpa (130 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用（临界分切应力公式）来求解临界分切应力，答案是一个具体的数值计算结果。 | 知识层次: 题目需要应用临界分切应力公式进行计算，涉及角度转换和应力分解，属于多步计算和概念关联的中等应用层次。虽然不涉及复杂的综合分析或机理解释，但需要理解滑移面和滑移方向的概念，并进行正确的公式应用和数值计算。 | 难度: 在选择题中属于中等偏上难度，需要理解临界分切应力的概念，掌握施密特定律的计算方法，并进行多步骤的三角函数计算。虽然题目提供了所有必要参数，但需要考生正确关联角度参数与应力分量之间的关系，属于综合性计算问题。" + }, + { + "idx": 4775, + "question": "The critical resolved shear stress for copper (Cu) is 0.48 MPa(70 psi). Determine the maximum possible yield strength for a single crystal of Cu pulled in tension.", + "answer": "the maximum possible yield strength for a single crystal of Cu pulled in tension is \\sigma_{y} = 0.96 MPa (140 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（临界分切应力与取向因子的关系）来确定单晶铜的最大可能屈服强度，答案给出了具体的数值计算结果。 | 知识层次: 题目需要应用临界分切应力的概念和公式进行简单计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需要应用临界分切应力与屈服强度的基本关系公式（σ_y = 2τ_crss），并进行简单的数值代入和计算。无需复杂的分析或多步骤推理，属于最基础的难度级别。" + }, + { + "idx": 4776, + "question": "The lower yield point for an iron that has an average grain diameter of 1 × 10^{-2}mm is 230 MPa(33,000 psi). At a grain diameter of 6 × 10^{-3} mm, the yield point increases to 275 MPa (40,000 psi). At what grain diameter will the lower yield point be 310 MPa(45,000 psi) ?\n\\underline{\\text {", + "answer": "the grain diameter at which the lower yield point is 310 MPa is 4.34 × 10^{-3} mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解特定的晶粒直径，答案是一个具体的数值结果，解答过程涉及材料科学中的Hall-Petch关系等计算步骤。 | 知识层次: 题目需要应用Hall-Petch关系进行多步计算，涉及不同晶粒尺寸下的屈服强度变化，需要理解公式中各参数的含义并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hall-Petch关系并进行多步计算。题目要求将屈服强度与晶粒尺寸的关系公式化，并通过已知数据求解未知参数，涉及材料科学中的核心概念和数学运算。虽然计算步骤明确，但需要综合应用多个知识点才能得出正确答案。" + }, + { + "idx": 4778, + "question": "Experimentally, it has been observed for single crystals of a number of metals that the critical resolved shear stress \\tau_{\\text {CrSS }} is a function of the dislocation density \\rho_{D} as\n\\[\n\\tau_{\\text {crss }}=\\tau_{0}+A \\sqrt{\\rho_{D}}\n\\]\nwhere \\tau_{0} and A are constants. For copper, the critical resolved shear stress is 0.69 MPa(100 psi) at a dislocation density of 10^{4} mm^{-2}. If it is known that the value of \\tau_{0} for copper is 0.069 MPa (10 psi), compute \\tau_{\\text {crss }} at a dislocation density of 10^{6} mm^{-2}.", + "answer": "the critical resolved shear stress \\tau_{\\text{crss}} at a dislocation density of 10^{6} mm^{-2} is 6.28 MPa (910 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和已知条件进行数值计算，最终得出一个具体的数值结果（6.28 MPa）。解答过程需要应用数学公式和代入数值计算，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，只需要将已知数值代入给定的公式中求解即可，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解临界分解剪应力与位错密度的关系公式，但解题步骤相对直接：首先根据已知条件求出常数A，然后代入新的位错密度值进行计算。整个过程仅涉及一个主要公式的两次应用和简单的代数运算，不需要复杂的推导或多步骤分析。相比等级1的直接套用公式，这里多了一个中间步骤（求A值），但整体仍属于较简单的应用层次。" + }, + { + "idx": 4779, + "question": "Briefly cite the differences between the recovery and recrystallization processes.", + "answer": "For recovery, there is some relief of internal strain energy by dislocation motion; however, there are virtually no changes in either the grain structure or mechanical characteristics. During recrystallization, on the other hand, a new set of strain-free grains forms, and the material becomes softer and more ductile.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释恢复和再结晶过程之间的差异，答案以文字形式详细论述了两个过程的不同点，符合简答题的特征。 | 知识层次: 题目考查对回复和再结晶过程的基本概念和差异的理解，属于基础概念记忆和简单对比的范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个基础概念（恢复和再结晶）的对比，但正确选项已经提供了明确的定义和区分点，不需要复杂的推理或分析。学生只需理解并记忆这两个过程的基本差异即可作答，符合选择题型中对概念解释和描述的要求。" + }, + { + "idx": 4780, + "question": "What is the driving force for recrystallization?", + "answer": "The driving force for recrystallization is the difference in internal energy between the strained and unstrained material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案提供了详细的解释而非选择或判断 | 知识层次: 题目考查对再结晶驱动力的基本概念的理解和记忆，属于材料科学中的基本原理范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"再结晶驱动力\"的基本定义，属于最基础的概念性知识。正确选项直接给出了教科书式的定义表述，无需任何解释、分析或比较过程，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 4781, + "question": "What is the driving force for grain growth?", + "answer": "The driving force for grain growth is the reduction in grain boundary energy as the total grain boundary area decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释grain growth的驱动力，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对晶粒生长驱动力这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆（晶粒生长的驱动力），但需要考生理解并描述\"晶界能量减少\"与\"晶界总面积减少\"之间的因果关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。题目正确选项完整解释了驱动力原理，符合选择题型中对概念解释和描述的要求。" + }, + { + "idx": 4782, + "question": "The average grain diameter for a brass material was measured as a function of time at 650 degrees C, which is shown in the following table at two different times: Time (min) 40, Grain Diameter (mm) 5.6 x 10^-2; Time (min) 100, Grain Diameter (mm) 8.0 x 10^-2. What was the original grain diameter?", + "answer": "the original grain diameter was 0.031 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目提供了实验数据（时间和晶粒直径），要求通过计算得出原始晶粒直径。解答过程需要应用材料科学中的晶粒生长动力学公式（如Beck方程）进行数值计算，最终给出具体数值结果（0.031 mm）。这符合计算题的特征，即通过公式推导和数值运算解决问题。 | 知识层次: 题目需要应用晶粒生长动力学公式（如Beck方程），进行多步计算和数据处理，涉及时间与晶粒直径的关系分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶粒生长动力学概念（如抛物线生长规律），进行多步对数计算和反推原始数据。虽然题目提供了关键时间点和测量值，但解题过程涉及公式变形、对数运算和单位转换，属于综合性计算问题。相比单纯记忆或单步计算的选择题，该题目对概念关联和计算能力要求较高，但未达到复杂多变量计算的最高难度。" + }, + { + "idx": 4784, + "question": "An undeformed specimen of some alloy has an average grain diameter of 0.050 mm. You are asked to reduce its average grain diameter to 0.020 mm. Is this possible? If so, explain the procedures you would use and name the processes involved. If it is not possible, explain why.", + "answer": "Yes, it is possible to reduce the average grain diameter of an undeformed alloy specimen from 0.050mm to 0.020 mm. In order to do this, plastically deform the material at room temperature (i.e., cold work it), and then anneal at an elevated temperature in order to allow recrystallization and some grain growth to occur until the average grain diameter is 0.020 mm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释是否可能减少晶粒直径，并详细说明相关过程和原理，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求考生不仅理解晶粒尺寸变化的基本原理（冷加工和退火），还需要综合应用这些知识来设计一个多步骤的过程（冷加工后控制退火条件以达到目标晶粒尺寸）。这涉及到对材料加工工艺的综合分析和应用，超出了简单记忆或直接套用的层次，但尚未达到需要创新或深度推理的复杂分析或高级综合层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道可以通过冷加工和退火来改变晶粒尺寸，还需要理解具体的操作步骤和原理。虽然题目提供了正确选项，但考生仍需具备一定的材料科学知识来确认这一过程的可行性。这涉及到对塑性变形、再结晶和晶粒生长等概念的综合理解，属于中等应用层次的知识要求。" + }, + { + "idx": 4785, + "question": "A non-cold-worked brass specimen of average grain size 0.01mm has a yield strength of 150 MPa(21,750 psi). Estimate the yield strength of this alloy after it has been heated to 500^{\\circ} C for 1000s, if it is known that the value of \\sigma_{0} is 25 MPa(3625 psi).", + "answer": "the yield strength of the brass alloy after heating to 500^{\\circ} C for 1000s is 124 MPa (18,000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过已知参数（初始屈服强度、晶粒尺寸、加热条件等）应用材料科学相关公式进行计算，最终得出一个具体的数值结果（124 MPa）。解答过程需要数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及屈服强度与晶粒尺寸的关系（Hall-Petch公式）以及热处理对晶粒尺寸的影响。需要理解并应用相关公式，进行数值计算和综合分析，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解Hall-Petch关系、热激活过程对晶粒尺寸的影响，并进行多步计算来估计加热后的屈服强度。虽然题目提供了部分参数，但仍需综合应用材料科学知识来推导最终结果。" + }, + { + "idx": 4786, + "question": "Normal butane and isobutane have boiling temperatures of -0.5^{\\circ} C and -12.3^{\\circ} C\\left(31.1^{\\circ} F\\right. and 9.9^{\\circ} F ), respectively. Briefly explain this behavior on the basis of their molecular structures.", + "answer": "Normal butane has a higher melting temperature as a result of its molecular structure . There is more of an opportunity for van der Waals bonds to form between two molecules in close proximity to one another than for isobutane because of the linear nature of each normal butane molecule.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于分子结构简要解释正丁烷和异丁烷沸点差异的行为，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求学生基于分子结构解释沸点差异，需要理解分子间作用力（范德华力）与分子形状的关系，并进行简单的分析比较。这属于中等应用层次，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解分子结构对沸点的影响，并能比较正丁烷和异丁烷的分子结构差异及其对范德华力的影响。虽然不需要复杂的计算，但需要对概念有较深的理解和综合分析能力。" + }, + { + "idx": 4787, + "question": "The tensile strength and number-average molecular weight for two poly(methyl methacrylate) materials are as follows:\n\\begin{tabular}{cc}\n\\hline Tensile Strength (MPa) & Number-Average Molecular Weight (g/mol) \\\\\n\\hline 50 & 30,000 \\\\\n150 & 50,000 \\\\\n\\hline\n\\end{tabular}\nEstimate the tensile strength at a number-average molecular weight of 40,000 g/mol.", + "answer": "the estimated tensile strength at a number-average molecular weight of 40,000 g/mol is 112.5 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了两组数据（拉伸强度和数均分子量），要求通过计算估计在特定分子量下的拉伸强度。解答过程需要数值计算和可能的插值或外推公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要应用给定的数据点进行简单的线性插值计算，属于基本公式的直接应用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解拉伸强度与数均分子量之间的关系，但题目提供了直接的数据点，只需进行简单的线性插值计算即可得出答案。解题步骤较为直接，不涉及复杂的公式组合或深入的概念分析。" + }, + { + "idx": 4788, + "question": "The tensile strength and number-average molecular weight for two polyethylene materials are as follows:\n\\begin{tabular}{cc}\n\\hline Tensile Strength (MPa) & Number-Average Molecular Weight (g/mol) \\\\\n\\hline 90 & 20,000 \\\\\n180 & 40,000 \\\\\n\\hline\n\\end{tabular}\nEstimate the number-average molecular weight that is required to give a tensile strength of 140 MPa.", + "answer": "the required number-average molecular weight is 27700 g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据（拉伸强度和数均分子量）进行数值计算，估计达到特定拉伸强度所需的数均分子量。解答过程涉及公式应用和数值计算，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算和概念关联，涉及对材料性能与分子量关系的综合分析，需要应用相关公式进行估算，思维过程有一定深度要求。 | 难度: 在选择题中属于中等难度，需要理解材料力学性能与分子量之间的关系，并进行多步计算和综合分析。题目要求根据给定的数据点建立数学模型（如线性关系），然后通过插值或外推估算目标分子量。虽然计算过程相对直接，但需要将多个概念关联起来，并正确应用数学方法。" + }, + { + "idx": 4789, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Branched and atactic poly(vinyl chloride) with a weight-average molecular weight of 100,000 g/mol; linear and isotactic poly(vinyl chloride) having a weight-average molecular weight of 75,000 g/mol", + "answer": "Yes, it is possible. The linear and isotactic poly(vinyl chloride) will display a greater tensile modulus. Linear polymers are more likely to crystallize that branched ones. In addition, polymers having isotactic structures will normally have a higher degree of crystallinity that those having atactic structures. Increasing a polymer's crystallinity leads to an increase in its tensile modulus. In addition, tensile modulus is independent of molecular weight - the atactic/branched material has the higher molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸模量进行比较，并解释原因。答案需要详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求考生比较两种聚合物的拉伸模量，并解释原因。这需要理解聚合物结构（支化、线性、等规、无规）对结晶度和力学性能的影响，以及分子量对拉伸模量的影响。虽然不涉及复杂计算，但需要综合分析多个因素（结构、结晶度、分子量）并关联到性能，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多角度分析论述。题目要求考生不仅理解聚合物的结构（支化与线性、无规与等规）对拉伸模量的影响，还需要掌握结晶度与拉伸模量的关系，以及分子量对拉伸模量的影响。此外，题目还要求考生能够综合分析这些因素，并做出正确的判断和解释。这种题目在选择题型中属于较为复杂的类型，需要考生具备较高的知识掌握深度和综合分析能力。" + }, + { + "idx": 4790, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Random styrene-butadiene copolymer with 5% of possible sites crosslinked; block styrene-butadiene copolymer with 10% of possible sites crosslinked", + "answer": "Yes, it is possible. The block styrene-butadiene copolymer with 10% of possible sites crosslinked will have the higher modulus. Block copolymers normally have higher degrees of crystallinity than random copolymers of the same material. A higher degree of crystallinity favors larger moduli. In addition, the block copolymer also has a higher degree of crosslinking; increasing the amount of crosslinking also enhances the tensile modulus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释哪种具有更高的拉伸模量及其原因。答案需要详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚合物的拉伸模量，并解释原因。这涉及到对聚合物结构（随机共聚物与嵌段共聚物）、交联度以及结晶度对力学性能影响的理解和应用。虽然不需要复杂的计算，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解聚合物结构（随机共聚物与嵌段共聚物）对力学性能的影响，还需要掌握交联度与结晶度对拉伸模量的具体作用机制。此外，题目要求考生进行多角度分析（结晶度与交联度的双重影响），并综合比较两种不同结构的聚合物性能。这种综合分析能力在选择题型中属于较复杂的认知要求，因此评为等级4。" + }, + { + "idx": 4791, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Branched polyethylene with a number-average molecular weight of 100,000 g/mol; atactic polypropylene with a number-average molecular weight of 150,000 g/mol", + "answer": "No, it is not possible. Branched polyethylene will tend to have a low degree of crystallinity since branched polymers don't normally crystallize. The atactic polypropylene probably also has a relatively low degree of crystallinity; atactic structures also don't tend to crystallize, and polypropylene has a more complex repeat unit structure than does polyethylene.Tensile modulus increases with degree of crystallinity, and it is not possible to determine which polymer is more crystalline. Furthermore, tensile modulus is independent of molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较两种聚合物的拉伸模量并给出理由，或解释为何无法判断。答案也以文字形式详细解释了原因，符合简答题的特征。 | 知识层次: 题目要求对两种聚合物的拉伸模量进行比较，涉及对聚合物结构（支化聚乙烯和无规聚丙烯）、结晶度、分子量等概念的综合分析。需要理解结晶度对拉伸模量的影响，并能够关联不同结构对结晶度的潜在影响。虽然不涉及复杂计算，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生综合运用多个高分子材料科学的概念，包括分子量对性能的影响、结晶度与力学性能的关系、聚合物链结构（支化、无规立构）对结晶能力的影响等。题目要求考生不仅能够识别这些概念，还需要进行多角度比较分析（支化PE vs 无规PP），并最终得出无法比较的结论。这种需要同时考虑多个变量（结晶度、分子量、链结构）并理解它们之间相互作用关系的题目，在选择题型中属于较高难度（等级4）。虽然题目给出了正确选项，但解题过程需要较深入的概念理解和综合分析能力。" + }, + { + "idx": 4792, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Linear and isotactic poly(vinyl chloride) with a weight-average molecular weight of 100,000 g/mol; branched and atactic poly(vinyl chloride) having a weight-average molecular weight of 75,000 g/mol", + "answer": "Yes, it is possible. The linear and isotactic material will have the higher tensile strength. Both linearity and isotacticity favor a higher degree of crystallinity than do branching and atacticity; and tensile strength increases with increasing degree of crystallinity. Furthermore, the molecular weight of the linear/isotactic material is higher (100,000 g/mol versus 75,000 g/mol), and tensile strength increases with increasing molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。题目没有提供选项，也不涉及计算，因此属于简答题。 | 知识层次: 题目要求比较两种聚合物的拉伸强度，并解释原因。这涉及到对聚合物结构（线性与支化、等规与无规）和分子量对性能影响的理解，需要综合分析多个因素（结晶度、分子量）对拉伸强度的共同作用。虽然不涉及复杂计算，但需要关联多个概念并进行逻辑推理。 | 难度: 在选择题中属于较高难度，需要综合比较两种聚合物的结构特征（线性/支化、等规/无规）和分子量对拉伸强度的影响，涉及多个概念关联和综合分析。解题步骤较为复杂，需要理解结晶度与拉伸强度的关系，以及分子量对性能的影响，并进行多角度分析论述。" + }, + { + "idx": 4793, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Graft acrylonitrile-butadiene copolymer with 10% of possible sites crosslinked; alternating acrylonitrile-butadiene copolymer with 5% of possible sites crosslinked", + "answer": "No, it is not possible. Alternating copolymers tend to be more crystalline than graft copolymers, and tensile strength increases with degree of crystallinity. However, the graft material has a higher degree of crosslinking, and tensile strength increases with the percentage of crosslinks.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释是否能够判断其拉伸强度的高低，以及原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对两种聚合物的拉伸强度进行比较，涉及结晶度和交联度对拉伸强度的影响，需要综合分析多个因素并解释原因，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生进行多角度分析论述。具体来说，考生需要理解并比较两种聚合物（接枝共聚物和交替共聚物）在结晶度和交联度方面对拉伸强度的影响。此外，题目还要求考生能够综合这些因素，判断是否能够确定哪种聚合物具有更高的拉伸强度，并解释原因。这种综合分析能力在选择题型中属于较高层次的要求。" + }, + { + "idx": 4795, + "question": "What is the magnitude of the maximum stress that exists at the tip of an internal crack having a radius of curvature of 1.9 × 10^{-4} mm\\left(7.5 × 10^{-6} in.\\right) and a crack length of 3.8 × 10^{-2} mm\\left(1.5 × 10^{-3}\\right. in.) when a tensile stress of 140 MPa(20,000 psi) is applied?", + "answer": "the magnitude of the maximum stress is 2800 \\text{ mpa} (400,000 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算裂纹尖端最大应力的大小，需要应用相关公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解应力集中概念并正确应用相关公式进行计算，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解应力集中概念、掌握裂纹尖端应力计算公式，并进行多步单位换算和数值计算。虽然题目提供了公式所需的所有参数，但计算过程涉及指数运算和单位转换，对学生的应用能力和计算准确性有较高要求。" + }, + { + "idx": 4796, + "question": "Estimate the theoretical fracture strength of a brittle material if it is known that fracture occurs by the propagation of an elliptically shaped surface crack of length 0.5 mm(0.02 in.) and a tip radius of curvature of 5 × 10^{-3} mm\\left(2 × 10^{-4} in\\right), when a stress of 1035 MPa(150,000 psi) is applied.", + "answer": "the theoretical fracture strength of the material is 20.7 gpa (3 × 10^{6} psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计材料的理论断裂强度，答案是一个具体的数值结果，解答过程需要运用相关公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及断裂强度的理论公式应用，需要理解裂纹长度、尖端半径与应力之间的关系，并进行数值计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解断裂强度的理论计算，涉及多步骤的公式应用和单位转换。题目要求考生能够正确应用应力集中公式，并进行单位换算和数值计算，属于综合性计算问题。虽然题目提供了具体数值，但计算过程需要精确和细心，对考生的概念理解和计算能力有一定要求。" + }, + { + "idx": 4797, + "question": "A specimen of a 4340 steel alloy with a plane strain fracture toughness of 54.8 MPa \\sqrt{m} (50 ksi \\sqrt{m}.) is exposed to a stress of 1030 MPa(150,000 psi). Will this specimen experience fracture if the largest surface crack is 0.5mm ( 0.02 in.) long? Why or why not? Assume that the parameter Y has a value of 1.0 .", + "answer": "the specimen will not experience fracture because it can tolerate a critical stress of 1380 \\text{ mpa} before fracture, which is greater than the applied stress of 1030 \\text{ mpa}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定试样是否会断裂。答案中给出了具体的计算结果（临界应力为1380 MPa），并基于计算结果进行了判断。 | 知识层次: 题目需要进行多步计算，包括应用断裂力学公式计算临界应力，并与实际应力进行比较。虽然公式直接给出，但需要理解参数的含义并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及平面应变断裂韧性和临界应力的计算，需要应用公式进行多步骤计算，并综合分析计算结果与给定应力条件的关系。虽然题目提供了所有必要参数，但解题过程需要一定的材料力学知识和对断裂力学概念的理解。" + }, + { + "idx": 4798, + "question": "An aircraft component is fabricated from an aluminum alloy that has a plane strain fracture toughness of 40 MPa sqrt(m) (36.4 ksi sqrt(in)). It has been determined that fracture results at a stress of 300 MPa (43,500 psi) when the maximum (or critical) internal crack length is 4.0mm (0.16 in.). For this same component and alloy, will fracture occur at a stress level of 260 MPa (38,000 psi) when the maximum internal crack length is 6.0mm (0.24 in.)? Why or why not?", + "answer": "fracture will occur since the value 42.4 MPa sqrt(m) is greater than the fracture toughness K_IC of the material, 40 MPa sqrt(m).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过公式计算临界应力强度因子，并与材料的断裂韧性进行比较，从而判断是否会发生断裂。解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用断裂力学中的应力强度因子公式进行多步计算，并结合材料的断裂韧性进行综合分析判断。虽然计算过程相对直接，但需要理解公式中各参数的含义及其相互关系，并进行适当的数值计算和比较。 | 难度: 在选择题中属于中等难度，需要理解断裂韧性和临界应力强度因子的概念，并进行多步计算（包括应力强度因子的公式应用和比较分析）。虽然题目提供了部分参数，但需要考生综合运用这些参数来判断是否会发生断裂，涉及概念关联和综合分析能力。" + }, + { + "idx": 4800, + "question": "A structural component is fabricated from an alloy that has a plane-strain fracture toughness of 62 MPa \\sqrt{m}. It has been determined that this component fails at a stress of 250 MPa when the maximum length of a surface crack is 1.6 mm. What is the maximum allowable surface crack length (in mm ) without fracture for this same component exposed to a stress of 250 MPa and made from another alloy that has a plane strain fracture toughness of 51 MPa \\sqrt{m} ?", + "answer": "the maximum allowable surface crack length without fracture is 1.08 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及平面应变断裂韧性和应力等参数的计算，最终要求得出最大允许表面裂纹长度的具体数值。答案也是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及平面应变断裂韧性和应力强度因子的概念关联，需要综合分析不同合金的断裂韧性对最大允许表面裂纹长度的影响。虽然计算过程相对直接，但需要理解和应用相关公式，并进行适当的数值计算。 | 难度: 在选择题中属于中等难度，需要理解断裂韧性和应力强度因子的概念，并进行多步计算来求解最大允许裂纹长度。题目涉及多个变量的综合分析，但计算过程相对直接，属于综合性计算问题。" + }, + { + "idx": 4801, + "question": "A large plate is fabricated from a steel alloy that has a plane strain fracture toughness of 82.4 MPa \\sqrt{m}(75.0 ksi \\sqrt{m}.). If the plate is exposed to a tensile stress of 345 MPa(50,000 psi) during service use, determine the minimum length of a surface crack that will lead to fracture. Assume a value of 1.0 for Y.", + "answer": "the minimum length of a surface crack that will lead to fracture is 0.0182 \\text{ m} (18.2 mm).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用平面应变断裂韧性公式）来确定表面裂纹的最小长度，答案是一个具体的数值结果。 | 知识层次: 题目需要应用平面应变断裂韧性公式进行多步计算，涉及应力强度因子与裂纹长度的关系，并需要综合分析给定条件（如Y值假设）来求解最小裂纹长度。虽然公式直接给出，但需要理解各参数意义并进行正确代入计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解断裂力学的基本概念（如平面应变断裂韧性、应力强度因子等），并能够正确应用相关公式进行多步骤计算。题目要求考生能够将理论知识与实际应用相结合，综合分析给定条件并得出正确结论。虽然题目提供了所有必要参数，但解题过程涉及多个步骤和概念关联，对考生的综合能力有一定要求。" + }, + { + "idx": 4806, + "question": "What is the maximum carbon content possible for a plain carbon steel that must have an impact energy of at least 200 Jat -50^{\\circ} C ?", + "answer": "the maximum carbon concentration is 0.11% C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算最大碳含量，需要基于材料科学的知识和公式进行数值计算，最终给出具体的数值答案（0.11% C）。 | 知识层次: 题目需要多步计算和概念关联，涉及碳含量与冲击韧性的关系，并需要综合分析材料性能数据来确定最大碳含量。 | 难度: 在选择题中属于中等偏上难度，需要综合理解碳钢的碳含量与冲击韧性的关系，并结合温度影响进行多步分析判断。题目要求考生不仅掌握材料性能的基本概念，还需要能够将不同知识点关联起来进行综合分析，才能正确选择最大碳含量限制。" + }, + { + "idx": 4807, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for tin.", + "answer": "for sn, -71°c or -96°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要从多个选项中选择，也不需要判断对错或进行复杂的计算。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对特定材料（锡）的蠕变温度这一基础概念的记忆，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆锡（Sn）的蠕变变形温度这一基础概念，属于单一知识点的直接回忆。题目不涉及概念解释或复杂分析，仅需选择正确的温度数值，因此难度等级为1。" + }, + { + "idx": 4808, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for molybdenum.", + "answer": "for mo, 776°c or 1429°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答形式。 | 知识层次: 题目考查对特定材料（钼）的蠕变变形温度的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆特定材料（钼）的蠕变温度这一基础数据，属于单一事实性知识的直接回忆。不需要概念解释或复杂分析，完全符合等级1\"基本定义简答\"的标准。选择题型中此类直接考查记忆点的题目属于最低难度层级。" + }, + { + "idx": 4810, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for gold.", + "answer": "for au, 262°c or 504°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对金属蠕变温度这一基础概念的记忆，只需直接回忆黄金的蠕变起始温度即可，不涉及复杂计算或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆黄金的蠕变变形温度这一具体数值，属于基础概念记忆的简单问题。不需要解释或分析，只需直接回忆知识点即可作答。" + }, + { + "idx": 4811, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for zinc.", + "answer": "for zn, 4°c or 39°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个简短的具体数值，符合简答题的特征。 | 知识层次: 题目考查对锌材料蠕变变形温度这一基本概念的记忆，不需要复杂的应用或分析，仅需记住特定数值即可回答。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需要考生记住锌的蠕变变形温度这一具体数值即可。题目不涉及复杂的概念解释或分析过程，属于最简单的记忆性知识考察。" + }, + { + "idx": 4812, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for chromium.", + "answer": "for cr, 586°c or 1087°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答形式。 | 知识层次: 题目考查对铬材料蠕变温度这一特定数值的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆铬的蠕变变形温度这一具体数值，属于基础概念记忆的范畴。题目没有涉及复杂的概念解释或比较分析，解题步骤简单直接，只需回忆相关知识即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4813, + "question": "A cylindrical specimen 13.2mm in diameter of an S-590 alloy is to be exposed to a tensile load of 27,000N. At approximately what temperature will the steady-state creep be 10^{-3} h^{-1} ?", + "answer": "the temperature would be approximately 775^\\circ c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定条件下的温度值，答案是一个具体的数值（775°C），这表明解答过程涉及计算和可能的数据查找或插值。 | 知识层次: 题目需要进行多步计算，包括应用蠕变速率公式和材料性能参数，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目涉及圆柱形试样的直径、拉伸载荷以及稳态蠕变速率，要求考生能够综合运用材料科学中的蠕变理论和相关公式进行计算。虽然题目提供了正确选项，但解题过程需要多步骤计算和概念关联，包括应力计算、蠕变方程的运用以及温度的反推，这些步骤在选择题型中属于较为复杂的计算问题。" + }, + { + "idx": 4814, + "question": "Steady-state creep rate data are given in the following table for a nickel alloy at 538^{\\circ} C \\\\ (811 K):\n\\begin{tabular}{lc}\n\\hline \\dot{\\varepsilon}_{s}\\left(h^{-1}\\right) & \\sigma(M P(a) \\\\\n\\hline 10^{-7} & 22.0 \\\\\n10^{-6} & 36.1 \\\\\n\\hline\n\\end{tabular}\nCompute the stress at which the steady-state creep is 10^{-5}h^{-1} (also at 538^{\\circ} C ).", + "answer": "the stress at which the steady-state creep is 10^{-5}h^{-1} is 59.4 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式计算特定条件下的应力值，答案是一个具体的数值结果，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要进行多步计算，包括对稳态蠕变速率的对数处理、应力与蠕变速率关系的分析（如幂律蠕变方程的运用），以及通过已有数据点求解未知应力值。这需要理解蠕变行为的基本原理，并能将概念与数学计算相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解稳态蠕变速率与应力之间的关系，并进行多步计算。题目要求根据给定的数据点，通过插值或外推方法计算新的应力值，涉及对数坐标下的线性关系分析。虽然计算步骤相对明确，但需要综合应用材料科学中的蠕变概念和数学计算能力。" + }, + { + "idx": 4815, + "question": "Steady-state creep rate data are given in the following table for some alloy taken at 200^{\\circ} C(473 K) :\n\\begin{tabular}{ll}\n\\hlines\\left(h^{-1}\\right) & \\sigma[MPa(psi)] \\\\\n\\hline 2.5 × 10^{-3} & 55(8000) \\\\\n2.4 × 10^{-2} & 69(10,000) \\\\\n\\hline\n\\end{tabular}\nIf it is known that the activation energy for creep is 140,000 J/ mol, compute the steady-state creep rate at a temperature of 250^{\\circ} C(523 K) and a stress level of 48 MPa(7000 psi).", + "answer": "the steady-state creep rate at 250^{\\circ} C and 48 MPa is 1.94 × 10^{-2} h^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（蠕变速率与温度、应力的关系）进行数值计算，最终得出一个具体的数值结果（1.94 × 10^{-2} h^{-1}）。解答过程涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目需要应用稳态蠕变速率的公式，涉及多步计算和温度、应力对蠕变速率的影响分析。虽然题目给出了激活能，但仍需理解并应用相关公式进行计算，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解稳态蠕变速率与温度、应力的关系，并应用阿伦尼乌斯公式进行多步计算。题目涉及多个变量（温度、应力、活化能）的综合分析，且需要正确代入和转换单位。虽然提供了正确选项，但解题过程需要较强的概念关联和计算能力。" + }, + { + "idx": 4816, + "question": "Steady-state creep data taken for an iron at a stress level of 140 MPa(20,000 psi) are given here:\n\\begin{tabular}{cc}\n\\hline\\dot{\\epsilon}_{s}\\left(h^{-1}\\right) & T(K) \\\\\n\\hline 6.6 × 10^{-4} & 1090 \\\\\n8.8 × 10^{-2} & 1200 \\\\\n\\hline\n\\end{tabular}\nIf it is known that the value of the stress exponent n for this alloy is 8.5 , compute the steady-state creep rate at 1300 K and a stress level of 83 MPa(12,000 psi).", + "answer": "the steady-state creep rate at 1300k and a stress level of 83 MPa is 4.31 × 10^{-2}h^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（应力指数n）计算稳态蠕变速率，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用稳态蠕变速率公式，进行多步计算，包括温度转换、应力指数应用和数值计算，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解稳态蠕变速率与应力和温度的关系，并应用应力指数进行多步计算。题目涉及多个概念的综合运用和较为复杂的计算过程，但正确选项的提供降低了部分难度。" + }, + { + "idx": 4817, + "question": "If ice homogeneously nucleates at -40^{\\circ} C, calculate the critical radius given values of - 3.1 × 10^{8} J/ m^{3} and 25 × 10^{-3} J/ m^{2}, respectively, for the latent heat of fusion and the surface free energy.", + "answer": "the critical radius is 1.10 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数值和公式计算临界半径，答案是一个具体的数值结果（1.10 nm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及临界半径公式的应用，需要理解并关联表面自由能和潜热的概念，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解临界半径的计算公式，并正确代入给定的参数（潜热和表面自由能）进行多步计算。虽然题目提供了所有必要数据，但仍需综合应用热力学和成核理论的知识来解决问题。" + }, + { + "idx": 4818, + "question": "It is known that the kinetics of recrystallization for some alloy obeys the Avrami equation, and that the value of n in the exponential is 5.0. If, at some temperature, the fraction recrystallized is 0.30 after 100 min, determine the rate of recrystallization at this temperature.", + "answer": "the rate of recrystallization at this temperature is 8.76 × 10^{-3}, \\text{min}^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的Avrami方程参数和条件，通过数值计算确定再结晶速率。解答过程涉及公式应用和具体数值计算，最终答案是一个具体的数值结果。 | 知识层次: 题目需要应用Avrami方程进行多步计算，涉及对公式的理解和变形，以及数值计算能力。虽然不涉及复杂的综合分析或机理解释，但需要将给定的参数代入方程并求解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解Avrami方程的概念，并能正确应用方程进行多步骤计算。题目要求考生在已知n值和部分再结晶分数的情况下，计算再结晶速率，涉及对数运算和指数运算，计算过程较为复杂。虽然题目提供了正确选项，但解题过程需要较强的综合分析能力和数学运算能力。" + }, + { + "idx": 4820, + "question": "The fraction recrystallized-time data for the recrystallization at 350^{\\circ} C of a previously deformed aluminum are tabulated here. Assuming that the kinetics of this process obey the Avrami relationship, determine the fraction recrystallized after a total time of 116.8min.\n\\begin{tabular}{cc}\n\\hline Fraction Recrystallized & Time (min) \\\\\n\\hline 0.30 & 95.2 \\\\\n0.80 & 126.6 \\\\\n\\hline\n\\end{tabular}", + "answer": "the fraction recrystallized after a total time of 116.8min is 0.65.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和Avrami关系进行数值计算，以确定在特定时间下的再结晶分数。答案是一个具体的数值结果（0.65），需要通过公式应用和计算得出。 | 知识层次: 题目需要应用Avrami关系进行多步计算，涉及公式变换和数值求解，要求对动力学过程有较好的理解，并能够将实验数据与理论模型关联起来。 | 难度: 在选择题中属于中等难度，需要理解Avrami动力学关系并进行多步计算。题目要求根据给定的数据点拟合Avrami方程，然后外推计算特定时间点的再结晶分数。这涉及对数变换、线性回归和指数计算等步骤，属于综合性计算问题。虽然题目提供了部分数据点，但解题过程仍需要较强的数学和材料科学知识综合应用能力。" + }, + { + "idx": 4823, + "question": "What is the principal difference between natural and artificial aging processes?", + "answer": "For precipitation hardening, natural aging is allowing the precipitation process to occur at the ambient temperature; artificial aging is carried out at an elevated temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释自然时效和人工时效的主要区别，答案以文字形式进行解释和论述，没有提供选项或要求判断对错，也不需要数值计算。 | 知识层次: 题目考查对自然时效和人工时效两种工艺的基本定义和区别的记忆与理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分自然老化和人工老化的定义及其在沉淀硬化过程中的不同应用。正确选项提供了明确的对比解释，但考生仍需掌握相关背景知识才能准确作答。相较于仅要求记忆单一定义的等级1题目，此题要求考生对两个相关概念进行解释和描述，因此属于等级2难度。" + }, + { + "idx": 4824, + "question": "Which of the following polymers would be suitable for the fabrication of cups to contain hot coffee: polyethylene, polypropylene, poly(vinyl chloride), PET polyester, and polycarbonate. Why?", + "answer": "This question asks us to name, which, of five polymers, would be suitable for the fabrication of cups to contain hot coffee. At its glass transition temperature, an amorphous polymer begins to soften. The maximum temperature of hot coffee is probably slightly below 100^{\\circ} C\\left(212^{\\circ} F\\right). Of the polymers listed, only polystyrene and polycarbonate have glass transition temperatures of 100^{\\circ} C or above, and would be suitable for this application.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么某些聚合物适合制作热咖啡杯，需要文字解释和论述，而不是简单的选择或判断。答案提供了详细的解释和理由，符合简答题的特征。 | 知识层次: 题目要求考生从多个聚合物中选择适合制作热咖啡杯的材料，并解释原因。这需要考生理解聚合物的玻璃转变温度及其在实际应用中的意义，进行综合分析。虽然不涉及复杂的计算或深度推理，但需要将多个概念关联起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握不同聚合物的玻璃化转变温度及其在实际应用中的意义，同时需要综合分析这些材料在高温条件下的性能表现。虽然题目提供了多个选项，但正确选项的推导需要考生具备一定的材料科学知识，并能将这些知识应用到具体情境中。" + }, + { + "idx": 4825, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Branched polyethylene having a number-average molecular weight of 850,000 g/mol; linear polyethylene having a number-average molecular weight of 850,000 g/mol", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. The linear polyethylene will most likely have a higher percent crystallinity, and, therefore, a higher melting temperature than the branched polyethylene. The molecular weights of both materials are the same and, thus, molecular weight is not a consideration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求比较两种聚乙烯的熔点，并解释原因。这需要理解分子结构（线性和支化）对结晶度和熔点的影响，以及分子量的作用。虽然不涉及复杂计算，但需要综合分析多个因素（分子结构、结晶度、分子量）并做出判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解聚乙烯的分子结构（线性和支化）对结晶度和熔点的影响，还需要考生能够综合分析分子量相同的情况下，结构差异如何影响材料性能。此外，题目要求考生进行多步推理和比较，包括判断可能性、选择正确选项并解释原因，这涉及到多角度分析和论述。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 4826, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Polytetrafluoroethylene having a density of 2.14 g/cm3 and a weight-average molecular weight of 600,000 g/mol; PTFE having a density of 2.20 g/cm3 and a weight-average molecular weight of 600,000 g/mol", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. Of these two polytetrafluoroethylene polymers, the PTFE with the higher density (2.20 g/cm3) will have the higher percent crystallinity, and, therefore, a higher melting temperature than the lower density PTFE. The molecular weights of both materials are the same and, thus, molecular weight is not a consideration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并解释原因。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这涉及到对聚合物密度、分子量和结晶度之间关系的理解，以及这些因素如何影响熔点。虽然不需要复杂的计算，但需要综合分析多个因素（密度、分子量、结晶度）并理解它们之间的相互作用。这超出了简单记忆或直接套用的层次，属于中等应用水平。 | 难度: 在选择题中属于较高难度，需要综合理解聚合物密度、结晶度和熔融温度之间的关系，并进行多角度分析。题目要求比较两种PTFE的熔融温度，涉及密度和分子量的影响，需要考生能够关联多个概念并做出判断。虽然分子量相同，但密度的差异导致结晶度的不同，进而影响熔融温度。这种综合分析在选择题中属于较复杂的题目类型。" + }, + { + "idx": 4827, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Linear and syndiotactic poly(vinyl chloride) having a number-average molecular weight of 500,000 g/mol; linear polyethylene having a number-average molecular weight of 225,000 g/mol", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. The linear polyethylene will have the greater melting temperature inasmuch as it will have a higher degree of crystallinity; polymers having a syndiotactic structure do not crystallize as easily as those polymers having identical single-atom side groups. With regard to molecular weight, or rather, degree of polymerization, it is about the same for both materials (8000), and therefore, is not a consideration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较熔点高低并给出理由，或说明无法判断的原因。答案也以详细的文字解释形式呈现，符合简答题的特征。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这涉及到对聚合物结构（线性聚乙烯和间规聚氯乙烯）和结晶度影响熔点的理解，以及分子量对熔点的影响的评估。虽然不需要复杂的计算，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解聚合物结构（线性与间规立构）、分子量影响、结晶度与熔点的关系等多个概念，并进行多角度比较分析。题目要求判断可能性、选择正确聚合物并解释原因，涉及多步推理和概念关联，超出基础记忆或单一概念应用层次。" + }, + { + "idx": 4828, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Linear and syndiotactic polypropylene having a weight-average molecular weight of 500,000 g/mol; linear and atactic polypropylene having a weight-average molecular weight of 750,000 g/mol", + "answer": "No, it is not possible to determine which of the two polymers has the higher melting temperature. The syndiotactic polypropylene will have a higher degree of crystallinity than the atactic material. On the basis of this effect alone, the syndiotactic PP should have the greater Tm, since melting temperature increases with degree of crystallinity. However, the molecular weight for the syndiotactic polypropylene (500,000 g/mol) is less than for the atactic material (750,000 g/mol); a lowering of molecular weight generally results in a reduction of melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的熔点进行比较，并解释原因或说明无法比较的理由。答案需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求对两种聚合物的熔点进行比较，需要考虑多个因素（立体规整性、分子量）的综合影响，并进行权衡分析。这涉及到对聚合物结构与性能关系的深入理解，以及在不同影响因素之间进行推理判断的能力。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4829, + "question": "Compute the electrical conductivity of a cylindrical silicon specimen 7.0mm (0.28 in.) diameter and 57mm (2.25 in.) in length in which a current of 0.25 A passes in an axial direction. A voltage of 24V is measured across two probes that are separated by 45mm (1.75 in.).", + "answer": "12.2 (omega·m)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的物理参数（直径、长度、电流、电压）进行计算，最终得出电导率的数值结果。解答过程需要应用欧姆定律和电导率计算公式，属于典型的计算题类型。答案以数值形式给出，进一步验证了这是计算题。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的电流、电压和几何尺寸计算电导率，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算硅圆柱体的电导率，只需要应用基本的电导率公式（σ = (I × L) / (V × A)），其中所有需要的参数（电流、电压、长度和横截面积）都已直接给出或可以通过简单计算得出。解题步骤简单直接，无需多个公式组合或复杂分析，因此属于最简单的难度等级。" + }, + { + "idx": 4830, + "question": "Compute the resistance over the entire 57mm (2.25 in.) of the specimen.", + "answer": "the resistance over the entire specimen length is 121.4 omega.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算电阻值），答案给出了具体的计算结果（121.4 omega），这符合计算题的特征。 | 知识层次: 题目仅需基本公式应用和简单计算，无需多步推理或综合分析 | 难度: 在选择题型中，该题目仅需要直接应用基本公式进行简单计算，属于单一公式直接计算的难度等级。题目明确给出了所需的参数（57mm长度）和正确选项（121.4欧姆），无需额外的步骤或复杂的分析。" + }, + { + "idx": 4831, + "question": "What is the distinction between electronic and ionic conduction? \\\\", + "answer": "When a current arises from a flow of electrons, the conduction is termed electronic; for \\\\ ionic conduction, the current results from the net motion of charged ions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释电子传导和离子传导的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查电子传导和离子传导的基本定义和区别，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并区分电子传导和离子传导的基本定义，属于最基础的概念记忆层次。正确选项直接给出了两者的定义对比，不需要进行额外的分析或推理，因此属于难度等级1。" + }, + { + "idx": 4832, + "question": "In terms of electron energy band structure, discuss reasons for the difference in electrical \\\\ conductivity among metals, semiconductors, and insulators.", + "answer": "For metallic materials, there are vacant electron energy states adjacent to the highest filled state; thus, very little energy is required to excite large numbers of electrons into conducting states. These electrons are those that participate in the conduction process, and, because there are so many of them, metals are good electrical conductors.\nThere are no empty electron states adjacent to and above filled states for semiconductors and insulators, but rather, an energy band gap across which electrons must be excited in order to participate in the conduction process. Thermal excitation of electrons occurs, and the number of electrons excited will be less than for metals, and will depend on the band gap energy. For semiconductors, the band gap is narrower than for insulators; consequently, at a specific temperature more electrons will be excited for semiconductors, giving rise to higher conductivities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论金属、半导体和绝缘体在电子能带结构方面的导电性差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从电子能带结构的角度讨论金属、半导体和绝缘体导电性差异的原因，涉及对不同材料能带结构的深入理解和分析，需要综合运用能带理论、电子激发机制等知识进行推理和解释，思维过程较为复杂。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用电子能带结构的知识，深入理解金属、半导体和绝缘体导电性差异的机理。正确选项不仅需要考生掌握能带理论的基本概念，还需要能够分析不同材料中电子激发和导电过程的差异，包括能带间隙对导电性的影响、热激发的作用等。这种题目要求考生具备复杂现象全面分析的能力，能够将多个知识点整合并解释深层次的物理机制，因此在选择题型中属于最高难度。" + }, + { + "idx": 4833, + "question": "How does the electron structure of an isolated atom differ from that of a solid material?", + "answer": "For an isolated atom, there exist discrete electron energy states (arranged into shells and subshells); each state may be occupied by, at most, two electrons, which must have opposite spins. On the other hand, an electron band structure is found for solid materials; within each band exist closely spaced yet discrete electron states, each of which may be occupied by, at most, two electrons, having opposite spins. The number of electron states in each band will equal the total number of corresponding states contributed by all of the atoms in the solid.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释孤立原子和固体材料中电子结构的差异，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求比较孤立原子和固体材料中电子结构的差异，涉及对电子能级和能带结构的理解，需要将多个概念关联起来进行综合分析。虽然不涉及复杂计算，但需要对电子状态和能带理论有较深入的理解和应用。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解孤立原子和固体材料中电子结构的基本概念，还需要能够比较和分析两者之间的差异。具体来说，考生需要掌握离散电子能级和电子能带结构的区别，以及电子填充规则在不同情况下的应用。此外，题目还涉及多步计算和概念关联，要求考生具备综合分析能力。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 4834, + "question": "Briefly state what is meant by the drift velocity of a free electron.", + "answer": "The drift velocity of a free electron is the average electron velocity in the direction of the force imposed by an electric field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释自由电子的漂移速度的定义，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对自由电子漂移速度这一基本概念的定义和简单理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目仅要求考生记忆并复述自由电子漂移速度的基本定义，属于最基础的概念记忆层次。题目不涉及任何解释、分析或复杂概念的整合，解题步骤极为简单，仅需识别正确选项即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4835, + "question": "Briefly state what is meant by the mobility of a free electron.", + "answer": "The mobility is the proportionality constant between the drift velocity and the electric field. It is also a measure of the frequency of scattering events (and is inversely proportional to the frequency of scattering).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释自由电子迁移率的概念，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对自由电子迁移率这一基本概念的定义和理解，属于基础概念的记忆性知识，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目要求考生不仅记忆自由电子迁移率的基本定义，还需要理解其与漂移速度和电场之间的关系，以及散射事件频率的影响。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。因此属于概念解释和描述的中等难度等级。" + }, + { + "idx": 4836, + "question": "(a) Calculate the drift velocity of electrons in silicon at room temperature and when the magnitude of the electric field is 500 V/m.", + "answer": "the drift velocity of electrons in silicon at room temperature and when the magnitude of the electric field is 500 V/m is 72.5 m/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解电子在硅中的漂移速度，答案是一个具体的数值计算结果。 | 知识层次: 题目要求使用基本公式（如电子迁移率和电场的关系）进行直接计算，属于简单应用层次。虽然需要知道硅中电子迁移率的具体数值，但整体计算过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式（如v_d = μE）进行简单计算，无需多个公式组合或复杂分析。题目明确给出了所有必要参数（电场强度500 V/m和硅中电子迁移率），解题步骤非常直接，属于单一公式直接计算的简单应用层次。" + }, + { + "idx": 4837, + "question": "(b) Under these circumstances, how long does it take an electron to traverse a 25-mm length of crystal?", + "answer": "under these circumstances, it takes an electron 3.45 x 10^-4 s to traverse a 25-mm length of crystal.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算电子通过25毫米晶体所需的时间，答案给出了具体的数值计算结果（3.45 x 10^-4 s），这表明解答过程需要应用相关的物理公式和数值计算。 | 知识层次: 题目要求进行基本的数值计算和公式应用，属于直接套用公式的简单计算过程，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行简单计算，属于单一公式直接计算的难度等级。题目明确给出了所需的条件和公式应用场景，解题步骤简单直接，无需复杂的推理或多步骤计算。" + }, + { + "idx": 4838, + "question": "At room temperature the electrical conductivity and the electron mobility for aluminum are 3.8 x 10^7 (Ω·m)^-1 and 0.0012 m^2/V·s, respectively. Compute the number of free electrons per cubic meter for aluminum at room temperature.", + "answer": "the number of free electrons per cubic meter for aluminum at room temperature is 1.98 x 10^29 m^-3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率和电子迁移率数据，应用相关公式计算铝在室温下的自由电子密度。解答过程涉及数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目要求应用基本的电导率和电子迁移率公式进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算铝在室温下的自由电子数密度，只需直接套用电导率与电子迁移率的关系公式（σ = n e μ），并进行简单的代数运算即可得到答案。无需复杂的推导或多步骤计算，属于最基础的应用题。" + }, + { + "idx": 4839, + "question": "At room temperature the electrical conductivity and the electron mobility for aluminum are 3.8 x 10^7 (Ω·m)^-1 and 0.0012 m^2/V·s, respectively. What is the number of free electrons per aluminum atom? Assume a density of 2.7 g/cm^3.", + "answer": "the number of free electrons per aluminum atom is 3.28 electrons/al atom.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定每个铝原子中的自由电子数量。答案是一个具体的数值结果，而不是选择、判断或文字解释。 | 知识层次: 题目需要进行多步计算，涉及电导率、电子迁移率和密度的概念关联，以及自由电子数的综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的计算能力和概念理解。 | 难度: 在选择题中属于中等偏上难度，需要综合运用电导率、电子迁移率、密度等概念，并进行多步计算才能得出结果。虽然题目提供了所有必要数据，但解题过程涉及单位转换、公式推导和综合分析能力，对学生的知识掌握深度和计算能力要求较高。" + }, + { + "idx": 4840, + "question": "At room temperature the electrical conductivity of P b S is 25\\left(\\Omega·m\\right)^{-1}, whereas the electron and hole mobilities are 0.06 and 0.02{m}^{2} / V·s, respectively. Compute the intrinsic carrier concentration for PbS at room temperature.", + "answer": "the intrinsic carrier concentration for pbs at room temperature is 1.95 × 10^{21}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率、电子和空穴迁移率等参数，应用相关公式计算本征载流子浓度。答案是一个具体的数值结果，需要通过计算得出。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的电导率、电子和空穴迁移率来计算本征载流子浓度。虽然需要理解相关概念，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算本征载流子浓度，只需直接套用电导率与载流子浓度和迁移率的关系公式（σ = n_i * e * (μ_e + μ_h)），并进行简单的代数运算即可得出答案。无需多个公式组合或复杂的概念理解，因此属于最基础的难度等级。" + }, + { + "idx": 4841, + "question": "An n-type semiconductor is known to have an electron concentration of 5 × 10^{17}{m}^{-3}. If the electron drift velocity is 350{m} / s in an electric field of 1000V / m, calculate the conductivity of this material.", + "answer": "the conductivity of the material is 0.028, (\\omega·m)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解材料的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的电子浓度、电子漂移速度和电场强度来计算电导率。虽然需要理解半导体物理中的基本概念，但整体思维过程较为直接，属于基本公式的直接套用和简单计算。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解半导体电导率的基本概念，但解题步骤相对直接，仅需套用电导率公式（σ = n·e·μ，其中μ可通过漂移速度与电场关系求得）。题目提供了所有必要参数，且计算过程不涉及复杂转换或多步骤推导，属于选择题型中中等偏下的难度水平。" + }, + { + "idx": 4842, + "question": "Predict whether Nitrogen (N) will act as a donor or an acceptor when added to Silicon (Si). Assume that the impurity elements are substitutional.", + "answer": "Nitrogen will act as a donor in Si. Since it (N) is from group VA of the periodic table, and an N atom has one more valence electron than an Si atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来预测氮在硅中的行为，并给出相应的理由，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查对半导体掺杂基本原理的记忆和理解，涉及元素周期表中族属性和价电子数的基本概念，属于基础概念层次。 | 难度: 在选择题型中，该题目需要考生理解并应用基本的半导体掺杂原理，即通过比较氮（N）和硅（Si）的价电子数来判断氮在硅中的掺杂行为。虽然涉及基础概念记忆，但需要一定的解释和描述能力，属于概念解释和描述的难度等级。" + }, + { + "idx": 4843, + "question": "Predict whether Boron (B) will act as a donor or an acceptor when added to Germanium (Ge). Assume that the impurity elements are substitutional.", + "answer": "Boron will act as an acceptor in Ge. Since it (B) is from group IIIA of the periodic table, a B atom has one less valence electron than a Ge atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，需要分析Boron在Germanium中的行为并给出理由，而不是简单的选择或判断。 | 知识层次: 题目考查对半导体掺杂基本原理的记忆和理解，只需要知道硼是III族元素，在IV族元素锗中会形成受主杂质这一基本概念即可回答。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（掺杂元素的施主/受主性质），但需要考生理解并应用周期表中元素价电子数的概念，以及掺杂半导体材料的基本原理。解题步骤包括识别B和Ge的价电子数差异，并据此判断掺杂类型，这比单纯记忆定义（等级1）要求更高的概念理解和应用能力，但尚未达到复杂概念体系阐述（等级3）的程度。" + }, + { + "idx": 4844, + "question": "Predict whether Sulfur (S) will act as a donor or an acceptor when added to Indium Antimonide (InSb). Assume that the impurity elements are substitutional.", + "answer": "Sulfur will act as a donor in InSb. Since S is from group VIA of the periodic table, it will substitute for Sb; an S atom has one more valence electron than an Sb atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测硫在锑化铟中的行为并解释原因，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解元素在半导体中的掺杂行为，涉及元素周期表族数的知识，并需要将这一知识应用到具体的半导体材料InSb中。虽然不需要复杂的计算或多步骤推理，但需要对概念进行关联和综合分析，以判断硫在InSb中的掺杂类型。 | 难度: 在选择题中属于中等难度，需要理解半导体掺杂原理、元素周期表分组特性以及替代性杂质行为等概念，并进行综合分析判断硫在InSb中的掺杂行为。虽然不需要多步计算，但需要将多个知识点关联起来才能正确解答。" + }, + { + "idx": 4845, + "question": "Predict whether Indium (In) will act as a donor or an acceptor when added to Cadmium Sulfide (CdS). Assume that the impurity elements are substitutional.", + "answer": "Indium will act as a donor in CdS. Since In is from group IIIA of the periodic table, it will substitute for Cd; an In atom has one more valence electron than a Cd atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测铟在硫化镉中的行为并解释原因，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析掺杂元素在半导体中的行为，需要理解元素周期表中族的概念、价电子数的差异以及掺杂对半导体导电类型的影响。这涉及多步概念关联和综合分析，但不需要复杂的机理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解元素周期表中元素的族属性和价电子数目的概念，并能够将这一知识应用到具体的半导体材料掺杂情境中。解题步骤涉及识别In和Cd的价电子差异，并推断出掺杂后的电子行为。虽然不需要复杂的计算，但需要综合分析和概念关联的能力。" + }, + { + "idx": 4846, + "question": "Predict whether Arsenic (As) will act as a donor or an acceptor when added to Zinc Telluride (ZnTe). Assume that the impurity elements are substitutional.", + "answer": "Arsenic will act as an acceptor in ZnTe. Since As is from group VA of the periodic table, it will substitute for Te; furthermore, an As atom has one less valence electron than a Te atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求预测砷在碲化锌中的行为，并给出解释。答案需要文字论述和解释，而不是简单的选择或判断。 | 知识层次: 题目需要理解掺杂元素在半导体中的行为，涉及元素周期表分组和价电子数的比较，以及掺杂后对材料电学性能的影响。虽然不涉及复杂计算，但需要综合分析As在ZnTe中的替代位置和电子行为，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解多个概念并进行综合分析。题目要求考生不仅知道砷（As）和碲（Te）在周期表中的位置，还需要理解掺杂半导体中施主和受主的概念，以及杂质替代对材料电学性质的影响。此外，题目还要求考生能够将不同知识点关联起来，进行多步推理和判断。因此，该题目在选择题型内属于较高难度。" + }, + { + "idx": 4847, + "question": "Germanium to which 10^24 m^-3 As atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the As atoms may be thought of as being ionized (i.e., one charge carrier exists for each As atom). Is this material n-type or p-type?", + "answer": "this germanium material to which has been added 10^24 m^-3 as atoms is n-type since as is a donor in ge.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来判断材料是n型还是p型半导体，而不是从选项中选择或进行数值计算。答案也以简短的文字解释形式给出。 | 知识层次: 题目考查对半导体掺杂类型的基本概念记忆和理解，只需识别砷(As)在锗(Ge)中是施主杂质这一基本事实即可判断材料为n型半导体。 | 难度: 在选择题型中，该题目仅需要基础概念记忆，即识别掺杂元素As在Ge中的行为类型（n型或p型）。题目直接给出了关键信息（As作为施主杂质），无需复杂推理或概念整合，属于最基础的定义简答级别。" + }, + { + "idx": 4848, + "question": "Germanium to which 10^24 m^-3 As atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the As atoms may be thought of as being ionized (i.e., one charge carrier exists for each As atom). Calculate the electrical conductivity of this material, assuming electron and hole mobilities of 0.1 and 0.05 m^2/V-s, respectively.", + "answer": "the conductivity is equal to 1.60 × 10^4 (ω·m)^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锗材料的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的掺杂浓度和载流子迁移率直接计算电导率。虽然需要理解半导体掺杂和载流子迁移的概念，但计算过程较为直接，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算掺杂锗的电导率，只需应用电导率的基本公式σ = n * e * μ（其中n为载流子浓度，e为电子电荷，μ为载流子迁移率），并将给定的数值直接代入即可得到结果。无需多个公式组合或复杂分析，属于最基础的计算题。" + }, + { + "idx": 4849, + "question": "A metal alloy is known to have electrical conductivity and electron mobility values of 1.2 × 10^{7}(\\Omega·m)^{-1} and 0.0050{m}^{2} / V·s, respectively. A current of 40 \\mathrm{~A} is passed through a specimen of this alloy that is 35mm thick. What magnetic field would need to be imposed to yield a Hall voltage of -3.5 × 10^{-7}V ?", + "answer": "the required magnetic field is 0.735, \\text{tesla}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的磁场强度，答案是一个具体的数值结果（0.735 tesla），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用电导率、电子迁移率、电流密度和霍尔效应等知识，通过公式推导和数值计算得出结果。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及电导率、电子迁移率、电流、厚度和霍尔电压等多个物理量的综合计算，解题步骤较为复杂，需要运用霍尔效应的相关公式进行多步推导和计算。虽然题目提供了所有必要的信息，但需要考生具备较强的综合分析能力和计算技巧。" + }, + { + "idx": 4850, + "question": "At temperatures between 540^{\\circ} C(813 K) and 727^{\\circ} C(1000 K), the activation energy and preexponential for the diffusion coefficient of \\mathrm{Na}^{+}in \\mathrm{NaCl} are 173,000 J/ mol and 4.0 × 10^{-4} m^{2} / s, respectively. Compute the mobility for an \\mathrm{Na}^{+}ion at 600^{\\circ} C(873 K).", + "answer": "the mobility for a \\mathrm{na}^{+} ion at 600^{\\circ} C (873 k) is 2.34 × 10^{-13} m^{2}/\\mathrm{v}-s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和前置指数计算钠离子在特定温度下的迁移率，需要使用公式进行数值计算，答案也是一个具体的数值结果。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式计算离子迁移率，涉及多步计算和概念关联，但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与迁移率的关系，并应用阿伦尼乌斯公式进行多步计算。题目涉及温度转换、单位统一和公式推导，虽然选项已给出正确答案，但仍需较强的综合分析能力来验证。" + }, + { + "idx": 4851, + "question": "A parallel-plate capacitor using a dielectric material having an \\varepsilon_{\\mathrm{r}} of 2.2 has a plate spacing of 2mm ( 0.08 in.). If another material having a dielectric constant of 3.7 is used and the capacitance is to be unchanged, what must be the new spacing between the plates?", + "answer": "the new spacing between the plates must be 3.36 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解新的板间距，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的电容公式应用和简单的数值计算，只需要直接套用公式并调整参数即可得到答案，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求应用电容的基本公式（C = εA/d），并通过简单的代数运算（保持C不变，调整d以补偿ε的变化）来求解新的板间距。虽然涉及两个不同的介电常数，但解题步骤直接且无需复杂的推导或概念整合，属于选择题型中较为基础的难度水平。" + }, + { + "idx": 4852, + "question": "Consider a parallel-plate capacitor having an area of 3225 mm2 (5 in.2), a plate separation of 1mm (0.04 in.), and a material having a dielectric constant of 3.5 positioned between the plates. What is the capacitance of this capacitor?", + "answer": "the capacitance of this capacitor is 100 pf.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（电容公式）来求解电容器的电容值，答案是一个具体的数值结果（100 pf），属于典型的计算题特征。 | 知识层次: 题目涉及基本的电容计算公式应用（C = εA/d），只需要直接套用公式并进行简单的数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算平行板电容器的电容，只需直接套用平行板电容公式C = ε₀εᵣA/d，其中所有参数（面积A、板间距d、介电常数εᵣ）都已给出，且不需要单位换算（题目已提供统一单位）。解题步骤简单直接，属于最基本的知识应用层次。" + }, + { + "idx": 4853, + "question": "Consider a parallel-plate capacitor having an area of 3225 mm2 (5 in.2), a plate separation of 1mm (0.04 in.), and a material having a dielectric constant of 3.5 positioned between the plates. Compute the electric field that must be applied for 2 × 10−8 C to be stored on each plate.", + "answer": "the electric field that must be applied is 2.0 × 105 v/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及电容器的面积、板间距、介电常数等参数，最终需要计算出电场强度。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的电容公式应用和简单计算，如电容公式C=εA/d和电场强度E=V/d的直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。题目要求计算平行板电容器中的电场强度，涉及的基本公式为电容的定义式C=Q/V和电容与电场的关系式E=V/d。虽然需要应用两个公式，但步骤直接且计算简单，属于基础知识的直接应用。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4854, + "question": "The polarization P of a dielectric material positioned within a parallel-plate capacitor is to be 4.0 × 10^-6 C/m^2. What must be the dielectric constant if an electric field of 10^5 V/m is applied?", + "answer": "the dielectric constant εr must be 5.52.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定介电常数的值。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的应用和简单计算，需要理解极化、介电常数和电场之间的关系，并进行直接套用公式计算。不需要多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目仅需应用单一公式（P = ε0(εr - 1)E）进行简单代数运算即可求解。虽然涉及介电常数的概念，但计算步骤直接且无需复杂推导，符合等级2的简单公式应用计算标准。" + }, + { + "idx": 4855, + "question": "The polarization P of a dielectric material positioned within a parallel-plate capacitor is to be 4.0 × 10^-6 C/m^2. What will be the dielectric displacement D?", + "answer": "the dielectric displacement D will be 4.89 × 10^-6 c/m^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解电介质位移D，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用基本公式（如电介质位移D与极化P的关系）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式计算，无需多个公式组合或复杂分析。题目明确给出了极化强度P，并直接要求计算电位移D，属于单一公式直接计算的简单应用层次。" + }, + { + "idx": 4856, + "question": "For each of the three types of polarization, briefly describe the mechanism by which dipoles are induced and/or oriented by the action of an applied electric field.", + "answer": "For electronic polarization, the electric field causes a net displacement of the center of the negatively charged electron cloud relative to the positive nucleus. With ionic polarization, the cations and anions are displaced in opposite directions as a result of the application of an electric field. Orientation polarization is found in substances that possess permanent dipole moments; these dipole moments become aligned in the direction of the electric field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述三种极化类型的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对三种极化机制的基本概念记忆和理解，包括电子极化、离子极化和取向极化的定义和基本原理，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生对三种极化机制进行简要描述，涉及电子极化、离子极化和取向极化的基本原理。虽然需要记忆和理解多个概念，但每个概念的描述相对独立且直接，不需要复杂的比较分析或深入推导。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 4857, + "question": "For gaseous argon, solid LiF, liquid H2O, and solid Si, what kind(s) of polarization is (are) possible? Why?", + "answer": "Only electronic polarization is found in gaseous argon; being an inert gas, its atoms will not be ionized nor possess permanent dipole moments. Both electronic and ionic polarizations are found in solid LiF, since it is strongly ionic. In all probability, no permanent dipole moments will be found in this material. Both electronic and orientation polarizations are found in liquid H2O. The H2O molecules have permanent dipole moments that are easily oriented in the liquid state. Only electronic polarization is to be found in solid Si; this material does not have molecules with permanent dipole moments, nor is it an ionic material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同物质中可能存在的极化类型进行解释和论述，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求对不同物质（气态氩、固态LiF、液态H2O、固态Si）的极化类型进行分析和解释，需要理解电子极化、离子极化和取向极化的定义及其在不同物质中的适用性。这涉及到多步概念关联和综合分析，不仅需要记忆基本概念，还需要应用这些概念来解释具体材料的极化行为。思维过程需要一定的深度和逻辑性，但不需要创新或设计优化。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解不同物质状态下的极化类型，还需要分析每种物质的具体特性（如惰性气体、离子晶体、极性分子等）如何影响其极化行为。解题步骤涉及多个概念的综合应用和比较分析，需要考生具备较强的概念关联能力和综合分析能力。此外，题目还要求考生对不同物质的极化机制进行多角度分析，这在选择题型中属于较为复杂的任务。" + }, + { + "idx": 4863, + "question": "Compare gray and malleable cast irons with respect to composition and heat treatment", + "answer": "Gray iron--2.5 to 4.0 wt% C and 1.0 to 3.0 wt% Si. For most gray irons there is no heat treatment after solidification. Malleable iron--2.5 to 4.0 wt% C and less than 1.0 wt% Si. White iron is heated in a nonoxidizing atmosphere and at a temperature between 800 and 900°C for an extended time period.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较灰铸铁和可锻铸铁的成分和热处理，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较灰铸铁和可锻铸铁的成分和热处理工艺，涉及多个知识点的关联和综合分析。虽然需要记忆成分范围，但更需要对两种铸铁的热处理工艺进行理解和比较，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目要求比较灰铸铁和可锻铸铁的成分和热处理工艺，涉及多个概念的综合分析。虽然题目提供了具体的数据和条件，但需要考生理解并关联这些信息才能正确作答。" + }, + { + "idx": 4864, + "question": "Compare gray and malleable cast irons with respect to microstructure", + "answer": "Gray iron--Graphite flakes are embedded in a ferrite or pearlite matrix. Malleable iron--Graphite clusters are embedded in a ferrite or pearlite matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的微观结构，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对灰铸铁和可锻铸铁微观结构的基本概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两种铸铁的微观结构比较，但正确选项提供了明确的对比信息（石墨形态和基体组织），属于概念解释和描述层面。不需要复杂的分析或推导，只需记忆并区分两种铸铁的关键特征即可。相较于等级1的简单定义题，此题需要掌握更多细节知识，但尚未达到等级3的复杂概念体系阐述要求。" + }, + { + "idx": 4865, + "question": "Compare gray and malleable cast irons with respect to mechanical characteristics", + "answer": "Gray iron--Relatively weak and brittle in tension; good capacity for damping vibrations. Malleable iron--Moderate strength and ductility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种铸铁的机械特性，需要文字解释和论述，而不是选择、判断或计算。答案也以文字形式呈现，符合简答题的特征。 | 知识层次: 题目考查对灰铸铁和可锻铸铁机械特性的基本概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两种铸铁的机械特性比较，但正确选项已经提供了明确的对比描述（强度、脆性、减震能力等），属于概念解释和描述层面。不需要进行复杂的推导或综合分析，只需记忆和识别关键特征即可。因此符合等级2的标准。" + }, + { + "idx": 4866, + "question": "What are the distinctive features, limitations, and applications of titanium alloys?", + "answer": "Distinctive features: relatively low density, high melting temperatures, and high strengths are possible. Limitation: because of chemical reactivity with other materials at elevated temperatures, these alloys are expensive to refine. Applications: aircraft structures, space vehicles, and in chemical and petroleum industries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释钛合金的独特特征、局限性和应用，需要文字论述而非选择、判断或计算。答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求对钛合金的独特特征、局限性和应用进行综合论述，涉及多个知识点的关联和综合分析，需要理解材料特性与应用场景的关系，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解钛合金的多个特性（如密度、熔点、强度）并进行综合分析，同时还要考虑其化学活性和应用领域。题目要求考生将多个知识点关联起来，但不需要进行过于复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 4867, + "question": "What are the distinctive features, limitations, and applications of refractory metals?", + "answer": "Distinctive features: extremely high melting temperatures; large elastic moduli, hardnesses, and strengths. Limitation: some experience rapid oxidation at elevated temperatures. Applications: extrusion dies, structural parts in space vehicles, incandescent light filaments, x-ray tubes, and welding electrodes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述耐火金属的独特特征、局限性和应用，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求对耐火金属的独特特征、局限性和应用进行解释和论述，涉及多个知识点的关联和综合分析，需要理解并应用相关概念，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握耐火金属的显著特征、局限性和应用，这涉及多个知识点的综合运用。虽然题目提供了正确选项，但考生仍需具备一定的知识储备和分析能力，才能准确识别和关联这些信息。" + }, + { + "idx": 4868, + "question": "What are the distinctive features, limitations, and applications of superalloys?", + "answer": "Distinctive features: able to withstand high temperatures and oxidizing atmospheres for long time periods. Applications: aircraft turbines, nuclear reactors, and petrochemical equipment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述超级合金的独特特征、局限性和应用，答案提供了文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释超合金的独特特征、局限性和应用，需要将多个概念关联起来进行综合分析，并理解其在特定场景下的应用。这超出了单纯记忆基础概念的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等难度，需要理解超级合金的多个特征（耐高温、抗氧化等）并关联其具体应用场景（航空涡轮、核反应堆等），但选项已明确给出关键信息，无需进行多角度或深度关联性分析。" + }, + { + "idx": 4869, + "question": "What are the distinctive features, limitations, and applications of noble metals?", + "answer": "Distinctive features: highly resistant to oxidation, especially at elevated temperatures; soft and ductile. Limitation: expensive. Applications: jewelry, dental restoration materials, coins, catalysts, and thermocouples.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述贵金属的独特特征、局限性和应用，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求对贵金属的独特特征、局限性和应用进行解释和论述，涉及多个知识点的关联和综合分析，需要一定的理解和应用能力，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握贵金属的多个方面（特征、局限性和应用），并能够将这些知识点关联起来。虽然不需要复杂的计算，但需要对材料科学中的多个概念有综合理解，这比单纯记忆单一知识点要复杂。" + }, + { + "idx": 4870, + "question": "For the MgO-Al2O3 system, what is the maximum temperature that is possible without the formation of a liquid phase?", + "answer": "This problem asks that we specify, for the MgO-Al2O3 system, the maximum temperature without the formation of a liquid phase; it is approximately 2800 degrees Celsius.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在MgO-Al2O3系统中不形成液相的最高温度，答案提供了具体的温度值并需要文字解释，符合简答题的特征。 | 知识层次: 题目需要理解MgO-Al2O3系统的相图，并从中提取关键信息（最高无液相温度），这涉及多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解MgO-Al2O3系统的相图知识，并能够识别不形成液相的最高温度点。虽然题目给出了具体数值，但解答过程需要综合分析和概念关联，属于中等应用层次的知识要求。" + }, + { + "idx": 4871, + "question": "For the MgO-Al2O3 system, at what composition or over what range of compositions will this maximum temperature be achieved?", + "answer": "This maximum temperature is possible for pure MgO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在MgO-Al2O3系统中达到最高温度的具体组成或组成范围，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解MgO-Al2O3系统的相图特性，并能够分析特定组成下的温度变化趋势，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解MgO-Al2O3系统的相图和相关热力学概念，并进行综合分析。题目要求考生识别在特定系统中达到最高温度的条件，这需要将多个知识点关联起来，并应用相图知识进行判断。虽然题目给出了正确选项，但解题过程仍需要一定的概念理解和分析能力。" + }, + { + "idx": 4872, + "question": "What are the characteristics of sand casting technique?", + "answer": "For sand casting, sand is the mold material, a two-piece mold is used, ordinarily the surface finish is not an important consideration, the sand may be reused (but the mold may not), casting rates are low, and large pieces are usually cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释砂型铸造技术的特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对砂型铸造技术基本特征的记忆和理解，属于基础概念层面的知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个关于砂型铸造技术的特点，但这些特点都是基础概念的记忆性知识，不需要进行复杂的分析或比较。正确选项列举了砂型铸造的几个关键特征，如模具材料、模具类型、表面处理、砂的重复使用性、铸造速率和铸件尺寸等，这些都是对砂型铸造技术的基本描述。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 4873, + "question": "What are the characteristics of die casting technique?", + "answer": "For die casting, a permanent mold is used, casting rates are high, the molten metal is forced into the mold under pressure, a two-piece mold is used, and small pieces are normally cast.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释die casting technique的特征，答案提供了详细的文字描述和论述，符合简答题的特点 | 知识层次: 题目考查对压铸技术基本特征的理解和记忆，属于基础概念层次 | 难度: 该题目属于选择题型，要求考生识别并选择出压铸技术的特点。虽然涉及多个特点（永久模具、高铸造率、压力下注入熔融金属、两件式模具、通常铸造小件），但这些都属于基础概念记忆层次的定义和描述，不需要复杂的分析或推理。在选择题型中，这属于中等难度，因为需要考生对压铸技术有基本的理解和记忆，但不需要深入的概念体系阐述或复杂比较。" + }, + { + "idx": 4874, + "question": "What are the characteristics of investment casting technique?", + "answer": "For investment casting, a single-piece mold is used, which is not reusable; it results in high dimensional accuracy, good reproduction of detail, and a fine surface finish; and casting rates are low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释投资铸造技术的特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对熔模铸造技术特点的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解并记忆投资铸造技术的基本特征，包括模具类型、尺寸精度、细节再现和表面光洁度等。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 4875, + "question": "What are the characteristics of lost-foam casting technique?", + "answer": "For lost foam casting, the pattern is polystyrene foam, whereas the mold material is sand. Complex geometries and tight tolerances are possible. Casting rates are higher than for investment, and there are few environmental wastes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述lost-foam casting technique的特点，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查对消失模铸造技术特点的基本概念记忆和理解，包括材料组成、工艺特点和优势等基础性知识，不涉及复杂分析或综合应用。 | 难度: 该题目在选择题型中属于中等难度。虽然考察的是基础概念记忆（lost-foam casting technique的定义和特点），但正确选项包含了多个关键特征（材料组成、几何复杂度、生产效率和环保性），需要学生对这一铸造技术有较全面的记忆和理解，而非仅仅记住单一特征。这比仅考察基本定义的等级1题目要求更高，但尚未达到需要分析复杂概念体系的等级3难度。" + }, + { + "idx": 4876, + "question": "What are the characteristics of continuous casting technique?", + "answer": "For continuous casting, at the conclusion of the extraction process, the molten metal is cast into a continuous strand having either a rectangular or circular cross-section; these shapes are desirable for subsequent secondary metal-forming operations. The chemical composition and mechanical properties are relatively uniform throughout the cross-section.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释连续铸造技术的特点，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查连续铸造技术的基本特征，属于对基本原理和特点的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型内，该题目属于概念解释和描述难度等级。题目要求考生理解连续铸造技术的基本特征，包括铸造过程的描述和最终产品的形状与性质。虽然涉及多个知识点（如铸造过程、产品形状、机械性能等），但都属于基础概念记忆层次，不需要复杂的分析或比较。正确选项提供了清晰的解释，考生只需识别和匹配这些特征即可。" + }, + { + "idx": 4877, + "question": "What is the distinction between dye and pigment colorants?", + "answer": "The distinction between dye and pigment colorants is that a dye dissolves within and becomes a part of the polymer structure, whereas a pigment does not dissolve, but remains as a separate phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释染料和颜料着色剂之间的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查染料和颜料的基本定义和区别，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生区分染料和颜料两种着色剂的关键差异（溶解性与聚合物结构的关系）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。正确选项明确指出了两者的核心区别，考生只需理解并选择这一关键差异点即可。" + }, + { + "idx": 4878, + "question": "Cite four factors that determine what fabrication technique is used to form polymeric materials.", + "answer": "Four factors that determine what fabrication technique is used to form polymeric materials are: (1) whether the polymer is thermoplastic or thermosetting; (2) if thermoplastic, the softening temperature; (3) atmospheric stability; and (4) the geometry and size of the finished product.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释决定聚合物材料制造技术的四个因素，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对聚合物材料加工技术选择因素的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举四个决定聚合物材料制造技术的因素，但每个因素都是基础概念的记忆性知识，不需要复杂的分析或比较。考生需要理解并记忆这些基本概念，但不需要进行深入的推理或综合应用。因此，难度等级为2。" + }, + { + "idx": 4879, + "question": "What is the process of compression molding used to form plastic materials?", + "answer": "For compression molding, both heat and pressure are applied after the polymer and necessary additives are situated between the mold members.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释压缩成型的过程，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目考查压缩成型过程的基本概念和原理，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对压缩成型工艺基本定义的记忆，属于最基础的概念性知识。正确选项直接描述了该工艺的核心要素（加热加压和模具位置），不需要任何解释或复杂推理过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4880, + "question": "What is the process of transfer molding used to form plastic materials?", + "answer": "For transfer molding, the solid materials (normally thermosetting in nature) are first melted in the transfer chamber prior to being forced into the die.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释transfer molding的过程，答案提供了详细的文字描述和论述，符合简答题的特征 | 知识层次: 题目考查对转移模塑工艺的基本概念和过程的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（定义、分类、基本原理等），但需要考生理解并描述转移模塑的具体过程，包括材料的初始状态（固体热固性材料）、熔化过程（在转移室中）以及最终成型方式（被压入模具）。这比简单的定义记忆（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 4881, + "question": "What is the process of injection molding used to form plastic materials?", + "answer": "For injection molding (normally used for thermoplastic materials), the raw materials are impelled by a ram through a heating chamber, and finally into the die cavity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释注射成型的过程，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查注射成型过程的基本概念和原理，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别注射成型的基本定义和流程，属于最基础的概念记忆层次。正确选项直接描述了注射成型的过程，没有涉及复杂概念或需要分析比较的内容，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 4882, + "question": "Why must fiber materials that are melt-spun be thermoplastic?", + "answer": "Fiber materials that are melt spun must be thermoplastic because they must be capable of forming a viscous liquid when heated, which is not possible for thermosets.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释为什么熔纺纤维材料必须是热塑性的，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对热塑性材料基本特性的记忆和理解，即为什么熔融纺丝的材料必须是热塑性的。这属于基础概念的记忆和简单解释，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并区分热塑性材料和热固性材料的特性，并能够解释为什么熔融纺丝必须使用热塑性材料。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 4883, + "question": "Why must fiber materials that are drawn be thermoplastic?", + "answer": "Fiber materials that are drawn must be thermoplastic because during drawing, mechanical elongation must be possible; inasmuch as thermosetting materials are, in general, hard and relatively brittle, they are not easily elongated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么纤维材料在拉伸过程中必须是热塑性的，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解纤维材料在拉伸过程中的行为，并解释为什么必须是热塑性材料。这涉及到对热塑性和热固性材料性质的理解，以及它们在拉伸过程中的行为差异。虽然不涉及复杂的计算或深度推理，但需要对材料性质和应用场景有一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解纤维材料的特性（热塑性和热固性）以及它们在拉伸过程中的行为差异。题目要求考生将材料性质与加工工艺（拉伸）关联起来，并进行综合分析。虽然不涉及复杂计算，但需要掌握多个相关概念并理解它们之间的相互作用。" + }, + { + "idx": 4884, + "question": "Estimate the maximum thermal conductivity value for a cermet that contains 90 vol% titanium carbide (TiC) particles in a nickel matrix. Assume thermal conductivities of 27 and 67 W/m·K for TiC and Ni, respectively.", + "answer": "the maximum thermal conductivity k_max is 31.0 W/m·K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计cermet的最大热导率值，答案是一个具体的数值结果（31.0 W/m·K），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用复合材料热导率的计算公式，涉及多步计算和不同材料性能的综合分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解复合材料热导率的概念，掌握混合规则（如串联模型），并进行多步计算。虽然题目给出了具体数值，但需要正确应用公式和逻辑推理才能得出正确答案。" + }, + { + "idx": 4885, + "question": "Estimate the minimum thermal conductivity value for a cermet that contains 90 vol% titanium carbide (TiC) particles in a nickel matrix. Assume thermal conductivities of 27 and 67 W/m·K for TiC and Ni, respectively.", + "answer": "the minimum thermal conductivity k_min is 28.7 W/m·K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计cermet的最小热导率值，答案是一个具体的数值结果（28.7 W/m·K），这表明需要进行计算才能得出答案。 | 知识层次: 题目需要应用基本的复合材料热导率计算公式，进行简单的数值计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求使用混合材料热导率的最小值公式（k_min = 1/(V1/k1 + V2/k2)）进行直接计算，仅涉及单一公式的套用和简单数值代入。虽然需要理解组分体积分数和热导率的概念，但解题步骤明确且计算简单，属于基础应用层次。" + }, + { + "idx": 4887, + "question": "For a continuous and oriented fiber-reinforced composite, the moduli of elasticity in the longitudinal and transverse directions are 33.1 and 3.66 \\mathrm{GPa}\\left(4.8 × 10^{6}\\right. and \\left.5.3 × 10^{5} psi\\right), respectively. If the volume fraction of fibers is 0.30 , determine the moduli of elasticity of fiber and matrix phases.", + "answer": "the moduli of elasticity of the matrix and fiber phases are: \\[\ne_{m} = 2.6 \\, \\text{gpa} (3.77 × 10^{5} \\, \\text{psi})\n\\] \\[\ne_{f} = 104 \\, \\text{gpa} (15 × 10^{6} \\, \\text{psi})\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的复合材料纵向和横向弹性模量以及纤维体积分数，计算出纤维和基体相的弹性模量。这需要进行数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要应用复合材料弹性模量的计算公式，涉及纵向和横向弹性模量的关系，以及纤维和基体体积分数的考虑。虽然计算过程相对直接，但需要理解复合材料的力学行为和公式的适用条件，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解复合材料纵向和横向弹性模量的概念，并运用体积分数进行多步计算。虽然题目提供了正确选项，但解题过程涉及综合分析弹性模量的关系，属于中等应用层次的知识要求。" + }, + { + "idx": 4888, + "question": "In an aligned and continuous carbon fiber-reinforced nylon 6,6 composite, the fibers are to carry 97% of a load applied in the longitudinal direction. Using the data provided, determine the volume fraction of fibers required.", + "answer": "the volume fraction of fibers required is 0.258.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式进行计算，以确定纤维的体积分数。答案是一个具体的数值（0.258），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要进行多步计算，涉及复合材料中纤维承载比例的公式应用和体积分数的推导，需要理解复合材料力学的基本原理并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料力学的基本概念（如载荷分配原理），进行多步计算（包括应力-应变关系和体积分数转换），并综合分析给定条件（97%载荷由纤维承担）。虽然题目提供了正确选项减少了计算量，但仍需掌握相关公式推导和单位转换能力，属于综合性计算问题。" + }, + { + "idx": 4889, + "question": "In an aligned and continuous carbon fiber-reinforced nylon 6,6 composite, the fibers are to carry 97% of a load applied in the longitudinal direction. What will be the tensile strength of this composite? Assume that the matrix stress at fiber failure is 50 MPa (7250 psi).", + "answer": "the tensile strength of this composite is 1070 mpa (155,000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的拉伸强度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及复合材料中纤维和基体的应力分配，需要理解纤维增强复合材料的力学行为，并应用相关公式进行计算。虽然题目给出了部分参数，但仍需综合分析才能得出最终结果。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料力学的基本概念（如载荷分配、纤维与基体的应力关系），并进行多步骤计算（包括载荷分配比例转换、基体应力叠加等综合运算）。虽然题目提供了关键参数，但解题过程涉及多个知识点的关联应用，比单纯的概念选择题更复杂。" + }, + { + "idx": 4890, + "question": "Cite several reasons why fiberglass-reinforced composites are used extensively.", + "answer": "Reasons why fiberglass-reinforced composites are utilized extensively are: (1) glass fibers are very inexpensive to produce; (2) these composites have relatively high specific strengths; and (3) they are chemically inert in a wide variety of environments.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释纤维增强复合材料广泛使用的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对纤维增强复合材料应用原因的基础概念记忆和理解，答案列举的是该类材料的基本特性和优势，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举多个原因，但每个原因都是基础概念的记忆性知识（如玻璃纤维的生产成本、复合材料的比强度、化学惰性等），不需要复杂的分析或推理。正确选项已经明确列出了三个具体原因，考生只需识别和匹配这些基础知识点即可。相比等级1的简单定义题，该题目需要记忆和理解稍多的信息点，但不需要深入分析或综合应用，因此属于等级2难度。" + }, + { + "idx": 4891, + "question": "Cite several limitations of fiberglass-reinforced composites.", + "answer": "Several limitations of these composites are: (1) care must be exercised in handling the fibers inasmuch as they are susceptible to surface damage; (2) they are lacking in stiffness in comparison to other fibrous composites; and (3) they are limited as to maximum temperature use.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举纤维增强复合材料的几个局限性，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目考查对纤维增强复合材料局限性的基本记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举纤维增强复合材料的几个局限性，但正确选项已经提供了明确的三个具体限制条件。考生需要理解并记忆这些基本概念，但不需要进行复杂的分析或比较。这属于概念解释和描述的层次，比简单的定义记忆稍难，但比需要阐述复杂概念体系的题目要简单。" + }, + { + "idx": 4892, + "question": "What is a hybrid composite?", + "answer": "A hybrid composite is a composite that is reinforced with two or more different fiber materials in a single matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"hybrid composite\"进行文字解释和论述，答案是一个定义性的描述，不需要选择、判断或计算 | 知识层次: 题目考查对混合复合材料基本定义的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，此题仅考察对\"hybrid composite\"基本定义的记忆，属于最基础的概念性知识。题目只需识别正确选项中的定义描述，不需要任何解释、比较或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4893, + "question": "List two important advantages of hybrid composites over normal fiber composites.", + "answer": "Two advantages of hybrid composites are: (1) better overall property combinations, and (2) failure is not as catastrophic as with single-fiber composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举混合复合材料的两个重要优势，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对混合复合材料优势的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生回忆并列举两种混合复合材料的优势，属于概念解释和描述的层次。虽然需要记忆具体知识点，但不需要复杂的分析或比较，相对直接。因此属于中等难度。" + }, + { + "idx": 4894, + "question": "(a) Write an expression for the modulus of elasticity for a hybrid composite in which all fibers of both types are oriented in the same direction.", + "answer": "the expression for the modulus of elasticity for a hybrid composite with all fibers aligned in the same direction is: e_cl = e_m v_m + e_f1 v_f1 + e_f2 v_f2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出混合复合材料弹性模量的表达式，需要文字解释和论述，答案是一个公式表达式，属于简答题类型。 | 知识层次: 题目要求写出混合复合材料弹性模量的表达式，这属于基本公式的直接应用。虽然涉及多个组分（基体和两种纤维），但只需简单地将各组分模量按其体积分数加权求和，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用过程描述。题目要求直接套用已知的混合复合材料弹性模量公式，无需复杂的分析或计算步骤。考生只需识别并应用基本公式即可得出正确答案，属于基础难度水平。" + }, + { + "idx": 4895, + "question": "(b) Using this expression, compute the longitudinal modulus of elasticity of a hybrid composite consisting of aramid and glass fibers in volume fractions of 0.25 and 0.35 , respectively, within a polyester resin matrix [E_m=4.0 GPa (6x10^5 psi)].", + "answer": "the longitudinal modulus of elasticity of the hybrid composite is: e_cl = 59.7 gpa (8.67x10^6 psi)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的表达式计算混合复合材料的纵向弹性模量，涉及数值计算和公式应用。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求使用给定的表达式计算混合复合材料的纵向弹性模量，涉及基本公式的直接应用和简单计算。虽然需要理解复合材料中各组分体积分数的概念，但整体上是一个直接的数值计算过程，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接套用和简单计算能力。题目给出了所有必要的参数和明确的公式应用场景，解题步骤仅需代入数值进行计算，无需复杂的分析或组合多个公式。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4896, + "question": "Briefly describe laminar composites.", + "answer": "Laminar composites are a series of sheets or panels, each of which has a preferred high-strength direction. These sheets are stacked and then cemented together such that the orientation of the high-strength direction varies from layer to layer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述层状复合材料，答案以文字解释和论述的形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对层状复合材料基本概念的记忆和理解，包括其结构和组成方式，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但正确选项需要对层状复合材料的结构和组成有较为清晰的理解和描述，而不仅仅是简单的定义复述。这需要考生能够解释和描述概念，而不仅仅是识别或回忆基本定义。因此，该题目在选择题型内属于等级2的难度。" + }, + { + "idx": 4897, + "question": "What is the prime reason for fabricating laminar composites?", + "answer": "These composites are constructed in order to have a relatively high strength in virtually all directions within the plane of the laminate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释层状复合材料制造的主要原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对层状复合材料基本概念的记忆和理解，即其制造的主要原因是为了在层压板平面内各个方向上具有相对较高的强度。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（层压复合材料的定义和基本原理），但正确选项需要考生理解并描述层压复合材料的主要优势（即在层压平面内各个方向上具有较高强度）。这比简单的定义记忆（等级1）要求更高，但不需要复杂的分析或比较（等级3）。因此，该题目属于等级2难度。" + }, + { + "idx": 4898, + "question": "Is a voltage generated between the two cell halves of an Fe/Fe2+ concentration cell where both electrodes are pure iron, with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "Yes, a voltage is generated.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（是否会产生电压），答案直接给出\"Yes\"或\"No\"形式的判断，不需要计算或详细解释。 | 知识层次: 题目考查浓度电池的基本原理和简单应用，需要理解浓度差如何产生电压，并直接套用能斯特方程的基本概念来判断是否有电压产生。不需要多步计算或复杂的综合分析。 | 难度: 在选择题型中，该题目属于简单应用结果判断。题目直接考察对浓度电池基本原理的理解，只需判断在给定条件下是否会产生电压，无需进行复杂计算或多步骤推理。正确选项可以直接通过套用基本概念得出，符合等级2的简单应用要求。" + }, + { + "idx": 4899, + "question": "What is the magnitude of the voltage generated in an Fe/Fe2+ concentration cell with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "The magnitude of the voltage is 0.0414 V.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Fe/Fe2+浓度电池中产生的电压大小，需要通过公式应用和数值计算得出具体数值的答案。答案给出了具体的电压值0.0414 V，这表明解答过程涉及计算步骤。 | 知识层次: 题目涉及基本的电化学公式应用（Nernst方程），只需要直接套用公式进行简单计算即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用能斯特方程来计算电压，但题目已经给出了明确的浓度值，只需要直接套用公式并进行简单的对数计算即可得出结果。不需要复杂的推导或多步骤的公式组合，因此难度等级为2。" + }, + { + "idx": 4900, + "question": "Which electrode will be oxidized in an Fe/Fe2+ concentration cell with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "Oxidation occurs in the cell half with the lower Fe2+ concentration (2 × 10^-2 M).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释哪个电极会被氧化，并给出了具体的浓度条件，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解浓度电池的工作原理，并应用能斯特方程的概念来判断氧化发生的条件。虽然不涉及复杂计算，但需要将浓度差异与氧化还原倾向联系起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及浓度电池中电极氧化的判断，需要掌握能斯特方程的应用和氧化还原反应的基本原理。虽然不需要复杂的计算，但需要对浓度与电极电势的关系有清晰的理解，并能综合分析不同浓度条件下的氧化倾向。这种题目在选择题型中属于需要一定概念关联和逻辑推理的类型，但步骤并不十分复杂。" + }, + { + "idx": 4901, + "question": "For the aluminum and cast iron pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the aluminum-cast iron couple, corrosion is possible, and aluminum will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪个金属会腐蚀，需要文字解释和论述，答案也以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求预测铝和铸铁在海水中的腐蚀可能性，并判断哪种金属会腐蚀。这需要理解电偶腐蚀的基本原理，并能够应用这些原理分析具体金属对的腐蚀行为。虽然不涉及复杂计算，但需要对金属的电化学性质（如电极电位）有基本了解，并能进行简单的综合分析。 | 难度: 在选择题中属于中等难度，需要理解电偶腐蚀的基本原理，并能正确识别铝和铸铁在电偶序中的相对位置。此外，还需要综合分析海水环境对腐蚀的影响。虽然不需要复杂的计算，但需要将多个概念关联起来进行判断。" + }, + { + "idx": 4902, + "question": "For the Inconel and nickel pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the Inconel-nickel couple, corrosion is unlikely inasmuch as both alloys appear within the same set of brackets (in both active and passive states).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并解释哪种金属/合金会腐蚀，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求预测腐蚀可能性并解释原因，涉及对材料腐蚀行为的综合分析，需要理解不同金属在特定环境下的电化学行为及其相互作用。虽然不涉及复杂计算，但需要关联多个概念进行判断，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生对Inconel和镍在海水中的腐蚀行为有基本了解，并能根据它们在电偶序中的位置（同一组括号内）判断腐蚀可能性。这涉及中等应用层次的知识，包括多步计算、概念关联和综合分析，但不需要过于复杂的推导或深度关联性分析。" + }, + { + "idx": 4903, + "question": "For the cadmium and zinc pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the cadmium-zinc couple, corrosion is possible, and zinc will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪种金属会腐蚀，需要文字解释和论述，答案也是以文字形式给出，没有选项或计算要求。 | 知识层次: 题目需要应用基本的电化学腐蚀原理（如电偶腐蚀）来判断金属对的腐蚀行为，属于直接套用基础知识的简单应用，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本的腐蚀原理知识（如电偶序）即可得出答案。解题步骤简单，无需复杂计算或多概念综合分析，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 4904, + "question": "For the brass and titanium pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the brass-titanium pair, corrosion is possible, and brass will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪个金属会腐蚀，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求预测腐蚀可能性并确定腐蚀金属，需要理解电偶腐蚀的基本原理（不同金属的电化学电位差异），并应用这些知识进行综合分析。虽然不涉及复杂计算，但需要关联多个概念（如金属的活性、环境因素等）进行判断，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解电偶腐蚀的基本原理，并能识别不同金属在特定环境（海水）下的电化学行为。题目要求考生将金属的电偶序知识应用到具体配对（黄铜-钛）中，并判断腐蚀倾向和优先腐蚀的金属。这需要考生掌握中等应用层次的知识，包括多步概念关联和综合分析能力，但不需要进行复杂的多角度或深度关联性分析。" + }, + { + "idx": 4905, + "question": "For the low-carbon steel and copper pair that are coupled in seawater, predict the possibility of corrosion; if corrosion is probable, note which metal/alloy will corrode.", + "answer": "For the low-carbon steel-copper couple, corrosion is possible, and the low-carbon steel will corrode.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求预测腐蚀可能性并指出哪种金属会腐蚀，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求预测特定金属对在特定环境中的腐蚀可能性，并判断哪个金属会腐蚀。这需要理解电偶腐蚀的基本原理（不同金属的电化学电位差异），并能将其应用于具体情境（低碳钢和铜在海水中的耦合）。虽然不涉及复杂计算，但需要综合分析金属特性和环境因素，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解电偶腐蚀的基本原理，能够识别不同金属在电偶序中的相对位置，并综合分析在特定环境（海水）下的腐蚀行为。虽然不需要多步计算，但要求考生将多个概念（电偶序、环境因素、腐蚀倾向）关联起来进行判断。" + }, + { + "idx": 4906, + "question": "A piece of corroded metal alloy plate was found in a submerged ocean vessel. It was estimated that the original area of the plate was 800 cm^2 and that approximately 7.6kg had corroded away during the submersion. Assuming a corrosion penetration rate of 4mm / yr for this alloy in seawater, estimate the time of submersion in years. The density of the alloy is 4.5g/cm^3.", + "answer": "the time of submersion is 5.27 yr.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及腐蚀速率、面积、质量损失和密度等参数的运算，最终得出时间估计值。答案以数值形式呈现，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量与体积的转换、腐蚀速率的应用以及时间的估算。虽然不涉及复杂的综合分析或机理解释，但需要将多个概念（腐蚀速率、密度、面积）关联起来进行计算，思维过程有一定的深度要求。 | 难度: 在选择题中属于中等难度，需要理解腐蚀速率、密度和面积等概念，并进行多步计算和综合分析。题目涉及单位转换和公式应用，但步骤相对明确，属于综合性计算问题。" + }, + { + "idx": 4908, + "question": "Compute the corrosion potential for this reaction. The following corrosion data are known about the metal and solution: For Metal M: V_(MM^2+) = -0.90 V, i_0 = 10^-12 A/cm^2, beta = +0.10. For Hydrogen: V_(H^-/H_2) = 0 V, i_0 = 10^-10 A/cm^2.", + "answer": "the corrosion potential for this reaction is -0.420 V.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的腐蚀数据和公式计算腐蚀电位，答案是一个具体的数值（-0.420 V），这表明解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用腐蚀电化学的基本公式，进行多步计算，涉及腐蚀电位和电流密度的关联分析，需要理解并综合运用多个参数（如平衡电位、交换电流密度、Tafel斜率等）来求解腐蚀电位。虽然不涉及复杂的机理分析或创新设计，但计算过程需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解腐蚀电位的计算原理，掌握能斯特方程和塔菲尔斜率的概念，并进行多步计算。题目涉及两个半反应的电位和交换电流密度，需要综合分析并正确应用公式才能得出答案。虽然选择题提供了正确选项，但解题过程仍需要较强的概念关联和计算能力。" + }, + { + "idx": 4910, + "question": "For a concentration cell, briefly explain why corrosion occurs at the region having the lower concentration.", + "answer": "Inasmuch as \\left[\\mathrm{M}_{\\mathrm{L}}^{2+}\\right] \\prec\\left[\\mathrm{M}_{H}^{2+}\\right] then the natural logarithm of the \\left[\\mathrm{M}^{2+}\\right] ratio is negative, which yields a positive value for \\Delta V. This means that the electrochemical reaction is spontaneous as written, or that oxidation occurs at the electrode having the lower \\mathrm{M}^{2+} concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释腐蚀发生在低浓度区域的原因，答案提供了文字解释和论述，没有涉及计算、选择或判断对错。 | 知识层次: 题目要求解释浓度电池中腐蚀发生的机理，涉及电化学反应的驱动力和自发性的分析，需要综合运用电化学原理和热力学知识进行推理和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4911, + "question": "For copper, the heat capacity at constant volume C_V at 20 K is 0.38 J/mol-K and the Debye temperature is 340 K. Estimate the specific heat at 40 K.", + "answer": "the specific heat for copper at 40 K is 47.8 J/kg-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计铜在40 K时的比热容，答案是一个具体的数值结果。 | 知识层次: 题目需要应用德拜模型和热容公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解德拜温度与热容的关系，并应用德拜模型进行多步计算。题目涉及概念关联和综合分析，但计算过程相对明确，属于综合性计算问题。" + }, + { + "idx": 4913, + "question": "A 0.4-m (15.7-in.) rod of a metal elongates 0.48mm (0.019 in.) on heating from 20^{\\circ} C to 100^{\\circ} C\\left(68^{\\circ} F\\right. to \\left.212^{\\circ} F\\right). Determine the value of the linear coefficient of thermal expansion for this material.", + "answer": "the linear coefficient of thermal expansion for this material is 15.0 × 10^{-6} \\, ({}^{\\circ} C)^{-1} [8.40 × 10^{-6} \\, ({}^{\\circ} \\mathrm{f})^{-1}].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（线性热膨胀系数公式）来确定材料的线性热膨胀系数，答案是一个具体的数值计算结果。 | 知识层次: 题目涉及基本的线性热膨胀系数公式应用和简单计算，仅需直接套用公式并代入已知数值即可求解，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算线性热膨胀系数，只需直接套用公式α = ΔL / (L0 × ΔT)，代入给定的数值即可得出结果。解题步骤简单，无需复杂的分析或多步骤计算，符合等级1的标准。" + }, + { + "idx": 4914, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Pure silver; sterling silver (92.5 wt% Ag-7.5 wt% Cu)", + "answer": "Pure silver will have a larger conductivity than sterling silver because the impurity atoms in the latter will lead to a greater degree of free electron scattering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的导热性能，并解释原因。这需要理解热导率的基本概念（基础概念），同时需要分析杂质对自由电子散射的影响（概念关联和综合分析）。虽然不涉及复杂计算，但需要将多个知识点联系起来进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解热导率与材料纯度的关系，并分析杂质对自由电子散射的影响。虽然不需要复杂计算，但需要将多个概念（纯度、电子散射、热导率机制）进行关联分析才能正确判断。" + }, + { + "idx": 4915, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Fused silica; polycrystalline silica", + "answer": "Polycrystalline silica will have a larger conductivity than fused silica because fused silica is noncrystalline and lattice vibrations are more effectively scattered in noncrystalline materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性能并给出合理的解释，需要文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求比较两种材料的导热性能，并解释原因。这需要理解晶体结构对热导率的影响，以及非晶态和多晶态材料在热传导机制上的差异。虽然涉及基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解非晶态和多晶态材料对热导率的影响机制，并进行比较分析。题目要求考生掌握晶格振动散射的基本原理，并能将其应用于具体材料系统的比较，这需要中等层次的概念关联和综合分析能力。" + }, + { + "idx": 4916, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Linear and syndiotactic poly(vinyl chloride) (DP =1000); linear and syndiotactic polystyrene (DP=1000)", + "answer": "The poly(vinyl chloride) will have the larger conductivity than the polystyrene because the former will have the higher degree of crystallinity. Both polymers are syndiotactic and have the same degree of polymerization. However, with regard to side-group bulkiness, the PVC is more likely to crystallize. Since heat transfer is by molecular chain vibrations, and the coordination of these vibrations increases with percent crystallinity, the higher the crystallinity, the greater the thermal conductivity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并解释选择的原因，需要文字解释和论述，而不是简单的选择或判断。答案中提供了详细的解释和论证过程，符合简答题的特征。 | 知识层次: 题目要求比较两种聚合物的热导率，并基于结晶度和分子结构进行解释。这需要理解聚合物的结构-性能关系，以及结晶度对热导率的影响。虽然涉及基础概念，但需要综合分析多个因素（如侧基体积、结晶度等）来得出结论，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较两种聚合物的热导率，涉及结晶度、分子链振动和热传导机制等概念的综合应用。虽然题目给出了明确的比较标准（结晶度），但需要考生理解并关联这些概念才能正确选择答案。解题步骤包括分析聚合物结构、比较结晶度差异以及理解热传导机制，属于中等应用层次的知识要求。" + }, + { + "idx": 4917, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Atactic polypropylene (Mw=10^6 g/mol); isotactic polypropylene (Mw=10^5 g/mol)", + "answer": "The isotactic polypropylene will have a larger thermal conductivity than the atactic polypropylene because isotactic polymers have higher degrees of crystallinity. The influence of crystallinity on conductivity is explained in part (c).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性能并给出理由，需要文字解释和论述，而不是简单的选择或判断。答案中提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求比较两种聚合物的热导率，并解释原因。这需要理解聚合物结构（等规和无规）对结晶度的影响，以及结晶度如何影响热导率。虽然涉及多个概念，但主要是概念关联和综合分析，不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解聚合物立构规整性（isotactic vs atactic）对结晶度的影响，以及结晶度与热导率的关系这两个关键概念，并进行比较分析。虽然不涉及复杂计算，但需要综合应用材料结构-性能关系的知识来做出判断。" + }, + { + "idx": 4918, + "question": "Briefly explain why thermal stresses may be introduced into a structure by rapid heating or cooling.", + "answer": "Thermal stresses may be introduced into a structure by rapid heating or cooling because temperature gradients are established across the cross section due to more rapid temperature changes at the surface than within the interior; thus, the surface will expand or contract at a different rate than the interior and since this surface expansion or contraction will be restrained by the interior, stresses will be introduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释热应力产生的原因，答案是通过文字论述来解释现象，符合简答题的特征 | 知识层次: 题目要求解释热应力产生的机理，涉及温度梯度、膨胀/收缩速率差异以及内部约束等概念的关联和综合分析，需要一定的理解深度和思维过程，但不需要复杂的创新或设计优化。 | 难度: 在选择题中属于中等难度，需要理解温度梯度、热膨胀/收缩以及应力产生机制等多个概念，并能将这些概念关联起来进行综合分析。虽然题目不涉及多步计算，但要求考生能够解释现象背后的物理原理，这在选择题型中属于需要一定深度理解的题目。" + }, + { + "idx": 4919, + "question": "For cooling, what is the nature of the surface stresses?", + "answer": "For cooling, the surface stresses will be tensile in nature since the interior contracts to a lesser degree than the cooler surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对冷却过程中表面应力的性质进行解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目考查冷却过程中表面应力的基本性质和原因，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（冷却时表面应力的性质），但需要考生理解并描述应力产生的机制（内部和表面收缩差异导致拉伸应力）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 4920, + "question": "For heating, what is the nature of the surface stresses?", + "answer": "For heating, the surface stresses will be compressive in nature since the interior expands to a lesser degree than the hotter surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释加热时表面应力的性质，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对加热过程中表面应力性质的基本理解，属于基础概念的记忆和简单应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要理解加热过程中表面应力的性质及其产生原因（即内部和表面膨胀程度差异导致的压缩应力）。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4921, + "question": "The magnetic flux density within a bar of some material is 0.630 tesla at an H field of 5 x 10^5 A/m. Compute the magnetic permeability for this material.", + "answer": "1.260 x 10^-6 h/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（磁通密度与磁场强度的关系）来求解磁导率，答案是一个具体的数值结果。 | 知识层次: 题目要求计算磁导率，仅需应用基本公式（B = μH）进行一步计算，无需多步推理或综合分析。 | 难度: 在选择题中属于最低难度，仅需直接套用磁导率的基本公式（μ = B/H）并进行简单计算即可得出结果，无需额外的概念理解或步骤组合。" + }, + { + "idx": 4922, + "question": "The magnetic flux density within a bar of some material is 0.630 tesla at an H field of 5 x 10^5 A/m. Compute the magnetic susceptibility for this material.", + "answer": "2.387 x 10^-3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（磁通密度和磁场强度的关系）来求解磁化率，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（磁化率与磁感应强度、磁场强度的关系）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题中属于简单难度，仅需应用基本公式（磁化率公式）并进行简单计算。题目直接给出了磁场强度和磁通密度，只需套用公式即可得出结果，无需复杂的推导或多步骤计算。" + }, + { + "idx": 4923, + "question": "The magnetic flux density within a bar of some material is 0.630 tesla at an H field of 5 x 10^5 A/m. What type(s) of magnetism would you suggest is (are) being displayed by this material? Why?", + "answer": "This material would display both diamagnetic and paramagnetic behavior. All materials are diamagnetic, and since χm is positive and on the order of 10^-3, there would also be a paramagnetic contribution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料显示的磁性类型及其原因，答案提供了详细的文字解释和论述，而非简单的选择、判断或计算。 | 知识层次: 题目要求根据给定的磁场强度和磁通密度判断材料的磁性类型，并解释原因。这需要理解磁性的基本概念（如抗磁性和顺磁性），并能将理论知识与给定的数据联系起来进行分析。虽然不涉及复杂的计算或多步骤推理，但需要对磁化率的概念及其与磁性行为的关系有一定的理解，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生不仅理解基本的磁学概念（如磁通密度、磁场强度、磁化率等），还需要能够综合分析材料的磁性行为。题目要求考生识别并解释材料同时表现出抗磁性和顺磁性的原因，这涉及到对材料磁性的多角度分析。此外，题目中的计算步骤虽然不复杂，但需要考生将理论知识与具体数值关联起来，进行综合判断。因此，该题目在选择题型中属于较高难度，需要考生具备较强的概念关联和综合分析能力。" + }, + { + "idx": 4924, + "question": "A net magnetic moment is associated with each atom in paramagnetic and ferromagnetic materials. Explain why ferromagnetic materials can be permanently magnetized whereas paramagnetic ones cannot.", + "answer": "Ferromagnetic materials may be permanently magnetized (whereas paramagnetic ones may not) because of the ability of net spin magnetic moments of adjacent atoms to align with one another. This mutual magnetic moment alignment in the same direction exists within small volume regions - domains. When a magnetic field is applied, favorably oriented domains grow at the expense of unfavorably oriented ones, by the motion of domain walls. When the magnetic field is removed, there remains a net magnetization by virtue of the resistance to movement of domain walls; even after total removal of the magnetic field, the magnetization of some net domain volume will be aligned near the direction that the external field was oriented.For paramagnetic materials, there is no magnetic dipole coupling, and, consequently, domains do not form. When a magnetic field is removed, the atomic dipoles assume random orientations, and no magnetic moment remains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么铁磁材料可以永久磁化而顺磁材料不能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释铁磁性和顺磁性材料在磁化行为上的差异，涉及磁矩排列、磁畴形成和磁畴壁运动等复杂机制的分析。需要综合运用多个概念，进行推理和解释，属于对材料磁学性质的深入理解。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4925, + "question": "The chemical formula for copper ferrite may be written as \\left(\\mathrm{CuFe}_{2} \\mathrm{O}_{4}\\right)_{8} because there are eight formula units per unit cell. If this material has a saturation magnetization of 1.35 × 10^{5} A/m and a density of 5.40g /cm^3, estimate the number of Bohr magnetons associated with each Cu^{2+} ion.", + "answer": "1.07 bohr magnetons/cu^{2+} ion", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以估计每个Cu^{2+}离子相关的玻尔磁子数。答案以数值形式给出，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括利用饱和磁化强度和密度计算每个Cu^{2+}离子的玻尔磁子数，涉及公式应用和概念关联，需要综合分析材料性质和单位晶胞信息。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如单位晶胞、饱和磁化强度、密度、玻尔磁子等）并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及多个物理量的转换和关联，对学生的综合应用能力要求较高。" + }, + { + "idx": 4926, + "question": "The formula for samarium iron garnet (Sm3Fe5O12) may be written in the form Sm3^aFe2^cFe3^dO12, where the superscripts a, c, and d represent different sites on which the Sm^3+ and Fe^3+ ions are located. The spin magnetic moments for the Sm^3+ and Fe^3+ ions positioned in a and c sites are oriented parallel to one another and antiparallel to the Fe^3+ ions in d sites. Compute the number of Bohr magnetons associated with each Sm^3+ ion, given the following information: (1) each unit cell consists of eight formula (Sm3Fe5O12) units; (2) the unit cell is cubic with an edge length of 1.2529 nm; (3) the saturation magnetization for this material is 1.35 × 10^5 A/m; and (4) there are 5 Bohr magnetons associated with each Fe^3+ ion.", + "answer": "2.86 bm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的信息和公式进行计算，最终得出一个具体的数值结果（2.86 bm）。解答过程需要应用材料科学中的磁学知识和数学计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个概念的综合应用，包括磁矩计算、单位晶胞分析、饱和磁化强度与磁矩的关系等。虽然不涉及复杂的推理分析或创新设计，但需要较强的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算和综合分析。题目涉及材料科学中的磁学性质计算，需要掌握单位晶胞、饱和磁化强度、玻尔磁子等概念，并能将这些概念关联起来进行综合计算。虽然题目提供了所有必要的信息，但解题步骤较为复杂，需要较高的概念理解和计算能力。" + }, + { + "idx": 4927, + "question": "An iron bar magnet having a coercivity of 7000 A/m is to be demagnetized. If the bar is inserted within a cylindrical wire coil 0.25m long and having 150 turns, what electric current is required to generate the necessary magnetic field?", + "answer": "11.7A", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，要求计算所需的电流值，答案是一个具体的数值（11.7A），解答过程涉及物理公式和单位转换。 | 知识层次: 题目需要进行多步计算（计算磁场强度、应用安培定律等），涉及概念关联（磁场强度与电流的关系），并需要综合分析（将磁体的矫顽力与线圈参数联系起来）。虽然不涉及复杂的推理或创新设计，但超出了简单应用的范围。 | 难度: 在选择题中属于中等偏上难度，需要理解磁滞回线、磁场强度与电流的关系等概念，并进行多步计算（包括单位换算和公式应用）。虽然题目提供了明确的计算路径，但涉及多个物理概念的关联运用，比单纯记忆性题目更具挑战性。" + }, + { + "idx": 4928, + "question": "Cite the differences between type I and type II superconductors.", + "answer": "For type I superconductors, with increasing magnetic field the material is completely diamagnetic and superconductive below H_{C}, while at H_{C} conduction becomes normal and complete magnetic flux penetration takes place. On the other hand, for type II superconductors upon increasing the magnitude of the magnetic field, the transition from the superconducting to normal conducting states is gradual between lower-critical and upper-critical fields; so also is magnetic flux penetration gradual. Furthermore, type II superconductors generally have higher critical temperatures and critical magnetic fields.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来比较两种超导体的差异，答案提供了详细的描述和对比，符合简答题的特征。 | 知识层次: 题目考查对I型和II型超导体基本特性的记忆和理解，主要涉及它们的磁性和导电性在不同磁场条件下的表现差异，属于基础概念的记忆和分类范畴。 | 难度: 在选择题型中，该题目要求考生解释和描述两种超导体的区别，涉及基础概念的记忆和比较。虽然需要理解多个概念，但题目提供了明确的对比点（如磁场响应、临界温度等），属于概念解释和描述的难度层次，不需要复杂的分析或推导。" + }, + { + "idx": 4929, + "question": "Briefly describe the Meissner effect.", + "answer": "The Meissner effect is a phenomenon found in superconductors wherein, in the superconducting state, the material is diamagnetic and completely excludes any external magnetic field from its interior. In the normal conducting state complete magnetic flux penetration of the material occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Meissner效应，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对Meissner效应的基本定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目要求考生对Meissner效应进行概念解释和描述，而非仅回答基本定义或进行复杂概念体系阐述。题目涉及对超导体在超导态和正常态下对磁场响应的描述，属于中等难度的概念理解题。" + }, + { + "idx": 4930, + "question": "Visible light having a wavelength of 5 x 10^-7 m appears green. Compute the frequency of a photon of this light.", + "answer": "the frequency of the photon is 6 x 10^14 s^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用光速公式 c = λν）来求解光子的频率，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（频率=光速/波长）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用光速公式（c = λν）进行简单计算，属于单一公式直接计算的类型。学生只需记住公式并代入已知数值即可得出答案，无需复杂的推理或多步骤运算。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4931, + "question": "Visible light having a wavelength of 5 x 10^-7 m appears green. Compute the energy of a photon of this light.", + "answer": "the energy of the photon is 3.98 x 10^-19 j (2.48 ev).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算光子的能量），并给出了具体的公式应用（使用波长计算光子能量）。答案也是以数值形式呈现的。 | 知识层次: 题目涉及基本公式（光子能量公式E=hc/λ）的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（E=hc/λ）进行计算，无需多个步骤或公式组合。题目提供了所有必要的信息，且计算过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 4935, + "question": "Can a material have a positive index of refraction less than unity? Why or why not?", + "answer": "In order for a material to have an index of refraction less than unity, the velocity of light in the material (v) would necessarily have to be greater than the velocity of light in a vacuum . This is not possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么材料不能具有小于1的正折射率，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对折射率小于1的物理可能性进行深入分析和解释，涉及光速在介质中的传播特性与真空光速的关系，需要综合运用电磁学理论和材料光学性质的知识进行推理和论证。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4936, + "question": "The index of refraction of quartz is anisotropic. Suppose that visible light is passing from one grain to another of different crystallographic orientation and at normal incidence to the grain boundary. Calculate the reflectivity at the boundary if the indices of refraction for the two grains are 1.544 and 1.553 in the direction of light propagation.", + "answer": "the reflectivity at the boundary is 8.45 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解反射率，答案是一个具体的数值结果（8.45 × 10^{-6}），这符合计算题的特征。 | 知识层次: 题目要求使用反射率的基本公式进行计算，涉及简单的数值代入和直接套用公式，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求计算反射率，直接给出了两个晶粒的折射率，只需套用菲涅尔反射公式（R = ((n1 - n2)/(n1 + n2))^2）进行计算即可。虽然涉及各向异性折射率的概念，但在选择题中只需进行简单数值代入和平方运算，无需复杂推导或多步骤分析。" + }, + { + "idx": 4937, + "question": "Zinc selenide has a band gap of 2.58 eV. Over what range of wavelengths of visible light is it transparent?", + "answer": "pure znse is transparent to visible light having wavelengths between 0.48 and 0.7 \\mu m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要根据给定的能带隙值（2.58 eV）计算对应的波长范围，涉及公式应用和数值计算。答案给出了具体的计算结果（0.48到0.7微米），表明这是一个需要计算步骤的问题。 | 知识层次: 题目需要应用基本的公式（如能隙与波长的关系公式）进行简单计算，属于直接套用基本公式的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题中属于简单难度，需要应用基本公式（波长与能量的转换公式）进行简单计算，但不需要多个公式组合或复杂分析。" + } +] \ No newline at end of file diff --git a/layer2/PGEE/code/step4_filter.py b/layer2/PGEE/code/step4_filter.py index be88ac1..24f448e 100644 --- a/layer2/PGEE/code/step4_filter.py +++ b/layer2/PGEE/code/step4_filter.py @@ -788,26 +788,23 @@ class EnhancedQuestionClassifier: f"等级{level}: {desc}" for level, desc in criteria.items() ]) - prompt = f"""请为以下题目在同题型内评估难度等级。 + prompt = f"""请为以下题目在选择题型内评估难度等级。 题目：{question} -答案：{answer} -题型：{type_info['name']} - {type_info['description']} +正确选项：{answer} 知识层次：{level_info['name']} - {level_info['description']} -在该题型和知识层次下的难度等级标准： +在选择题型和不同知识层次下的难度等级标准： {criteria_desc} 重要说明： -- 难度评估必须在相同题型内进行比较 -- 不同题型有不同的固有难度，需要排除题型本身的影响 -- 重点关注在该题型框架内的相对难度 +- 难度评估必须在选择题型内进行比较（仅给定正确选项） 评估考虑因素： -- 同类题型中的知识点掌握深度要求 -- 同类题型中的解题步骤复杂程度 -- 在该题型内的相对难度水平 -- 对该题型能力的具体要求 +- 选择题型中的知识点掌握深度要求 +- 选择题型中的解题步骤复杂程度 +- 选择题型内的相对难度水平 +- 选择题型能力的具体要求 请严格按照以下格式返回： 难度：[等级数字] @@ -1506,12 +1503,12 @@ def advanced_main(): questions = classifier.load_questions_from_json(INPUT_FILE) import random random.shuffle(questions) # 打乱题目顺序 - questions = questions[:100] # 测试时可以先处理一小部分 + # questions = questions[:100] # 测试时可以先处理一小部分 print("开始三阶段分类处理...") classified_questions = classifier.classify_questions_batch( questions=questions, - max_workers=10, + max_workers=20, save_interval=10, output_file=OUTPUT_FILE ) diff --git a/layer2/PGEE/code/step4_filtered_high_quality_questions.json b/layer2/PGEE/code/step4_filtered_high_quality_questions.json index ab174d9..c95805c 100644 --- a/layer2/PGEE/code/step4_filtered_high_quality_questions.json +++ b/layer2/PGEE/code/step4_filtered_high_quality_questions.json @@ -1,4 +1,2680 @@ [ + { + "idx": 2353, + "question": "Brass $(77,77)$ has a B2 structure, with a $z_{17}$ to $C11$ atomic ratio of 46:54. At $450-20=20$, if $900\\\\div\\\\cdots$ of the ($112$ 1/2, 1/2) positions are occupied by copper atoms, what percentage of the $(0,0,0)$ positions are occupied by copper atoms?", + "answer": "The stoichiometric composition of $C112.77$ is $5(\\\\angle17)=500^{\\\\circ}$. In the stoichiometric alloy, the ($112$, $117$, $112$) positions are entirely occupied by copper atoms, and the $(0,0,0)$ positions are entirely occupied by zinc atoms. Currently, the ratio of $217$ to $Cu$ atoms is $46:54$, and at $450-40$, $90\\\\%$ of the ($112$, 1/2, 1/2) positions are occupied by copper atoms. Thus, in the alloy, $\\\\sum11$ atoms have $0.5\\\\times0.0=4500$ located at the (1/2, 1/2, 1/2) positions. The remaining $0.54-0.45=0.00$ are located at the (0, 0, 0) positions, meaning $0.09/0.5=180\\\\dot{0}$ of the (0, 0, 0) positions are occupied by $c_{11}$ atoms. This can also be verified in the opposite direction. From the calculation results above, it shows that in the alloy, $z u$ atoms have $0.5-0.45=500$ located at the ($112$ 1/2, 1/2) positions and $0.5\\\\times(1-1).18)=410.0$ located at the (0, 0, 0) positions. Therefore, the content of $z_{1}$ in the alloy should be $0.41+0.05=4600$, which matches the given alloy composition.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目涉及复杂的数值计算和公式应用，需要根据给定的原子比例和位置占有率进行一系列数学运算来求解最终百分比。答案中展示了详细的计算步骤和验证过程，符合计算题的特征。 | 知识层次: 题目涉及复杂的晶体结构分析、原子位置占据率的计算、以及合金成分的推理验证。需要综合运用材料科学中的晶体学知识、化学计量学计算以及多步骤的逻辑推理。题目中的计算和验证过程较为复杂，涉及多个概念的综合应用和深度分析，超出了简单或中等应用的范围。 | 难度: 在选择题型内，该题目属于高难度综合计算题。题目涉及复杂的材料科学概念（如B2结构、原子位置占有率）、多步骤的化学计量计算（包括比例转换、百分比计算）以及需要综合运用多个知识点进行推理分析（如验证计算结果与给定合金成分的匹配性）。解题过程需要深入理解晶体结构和原子分布，并进行非直观的数学运算，远超选择题型的常规难度要求。正确选项的推导过程涉及多个逻辑层次和计算步骤，属于选择题型中最复杂的分析类型。" + }, + { + "idx": 2852, + "question": "Given that a straight dislocation line in an alloy is hindered by second-phase particles with a spacing of $\\\\pmb{\\\\lambda}$ during its motion, prove that the shear stress required for the dislocation to continue moving via the bypass mechanism is: 2T-Bln(2), where T is the line tension; b is the Burgers vector; $_{!G}$ is the shear modulus; $\\\\pmb{\\\\gamma}_{0}$ is the radius of the second-phase particle; and $B$ is a constant.", + "answer": "Strengthening effect of non-deformable particles: When a moving dislocation encounters non-deformable particles, it will be blocked, causing the dislocation line to bend around them. Since the dislocation has line tension $\\\\pmb{T}$, bending the dislocation line requires overcoming the effect of its line tension. The shear stress required for the dislocation line to bypass particles with spacing $\\\\lambda$ is The line tension of a dislocation is analogous to the surface tension of a liquid and can be represented by the energy per unit length of the dislocation. The energy per unit length of the dislocation $T=E=\\\\frac{G b^{2}}{4\\\\pi k}\\\\ln\\\\frac{\\\\bar{R}}{r_{0}}$ Gn. Substituting this into the above equation, then", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求证明一个具体的公式，并给出了详细的推导过程，涉及数值计算和公式应用。 | 知识层次: 题目要求证明一个关于位错绕过第二相粒子所需的剪切应力的公式，这涉及到位错理论、线张力概念、Burgers矢量、剪切模量等多个材料科学中的高级概念的综合运用。此外，题目还要求进行推理分析和机理解释，而不仅仅是简单的公式应用或记忆。因此，这属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于高难度综合计算等级。题目要求证明一个复杂的剪切应力公式，涉及多个材料科学中的高级概念（如位错线张力、Burgers矢量、剪切模量等），并需要综合运用这些概念进行推导。解题步骤复杂，需要深入理解位错与第二相粒子相互作用的机理，并进行数学推导。这种题目在选择题中属于最高难度级别，因为它不仅测试知识点的掌握深度，还要求考生具备综合分析和复杂计算能力。" + }, + { + "idx": 2593, + "question": "A closed dislocation loop lies on the slip plane of a prism with a square cross-section. The two sides of the square are along the x and y axes, and the Burgers vector is along the z-axis. If the dislocation loop can only glide, determine the equilibrium shape of the dislocation loop and the critical stress for initiation under the stress distribution condition τxz = τyz = τ = const. (Assume the line tension is approximately constant.)", + "answer": "f = (σ ⋅ b) × υ = (u - v)τbk; the initiation stress τp = 2G exp(-2πw/b)/(1-υ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定位错环的平衡形状和临界应力，需要通过公式计算得出具体数值结果。答案给出了具体的计算公式和结果，符合计算题的特征。 | 知识层次: 题目涉及复杂的力学分析，需要综合运用位错理论、应力分析和能量平衡原理，推导位错环的平衡形状和临界应力。这需要深入理解位错行为、应力场与位错的相互作用，以及线张力的概念，并进行多步推理和计算。 | 难度: 在选择题型内，该题目属于高难度综合计算问题。题目涉及复杂的位错理论、应力分析和临界应力计算，需要综合运用多个高级概念（如Burgers矢量、滑移面、线张力等）并进行机理推导。解题步骤要求：1)理解位错环在应力场中的平衡条件；2)推导临界应力公式；3)处理各向异性应力条件。这远超选择题的一般概念辨析或简单计算要求，需要深入的理论知识和较强的数学推导能力。" + }, + { + "idx": 2140, + "question": "A diffusion couple is formed by butt welding a long high-carbon steel rod and a long pure iron rod. Analyze the variation of the concentration distribution curve over time.", + "answer": "This problem is a spreading plane source diffusion issue. As shown in Figure 5-6, the initial conditions are: at t=0, x<0, c=c0; x>0, c=0. The left eutectoid steel rod is divided into volume elements with thickness d, so the carbon content per unit area is c0 d. Considering only the effect of this volume element, it is equivalent to an instantaneous plane source diffusion problem. After diffusion time t, the concentration at point P(x) at a distance ξ from this volume element is cξ=(c0 dξ)/(2√(πDt))exp(-ξ²/(4Dt)). Using the superposition principle, the total concentration at point P at time t should be the sum of contributions from all volume elements, i.e., c(x,t)=(c0)/(2√(πDt))∫_x^∞exp(-ξ²/(4Dt))dξ=(c0)/√π∫_(x/√π)^∞exp(-η²)dη. Here, η=ξ/2√Dt; erf(β)=2/√π∫_0^βe^(-η²)dη. erf(β) is the error function, and its values are given in Table 5-1. Note that erf(β)=∫_β^∞e^(-η²)dη=∫_0^∞e^(-η²)dη-∫_0^βe^(-η²)dη=√π/2[1-erf(β)]. Thus, c(x,t)=c0/2 erf(x²/(2√Dt)), as shown in Figure 5-7. When x<0, the concentration increases with |x|; when x>0, the concentration decreases with x; at x=0, when t>0, c=c0/2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析浓度分布曲线随时间的变化，解答过程中涉及复杂的数学推导和公式应用，包括积分、误差函数等计算步骤，属于典型的计算题类型。 | 知识层次: 题目涉及扩散偶的浓度分布随时间变化的分析，需要综合运用扩散理论、误差函数、叠加原理等知识，进行多步推理和计算，属于复杂分析和综合运用层次。 | 难度: 在选择题型内，该题目属于高难度综合计算问题。题目涉及复杂的扩散偶分析，需要综合运用扩散理论、误差函数（erf）以及叠加原理等多个高级概念。解题步骤包括初始条件的设定、体积元素的划分、瞬时平面源扩散问题的等效处理、积分运算以及误差函数的应用，这些都要求考生具备深厚的材料科学基础和数学分析能力。此外，题目还要求考生能够理解和解释浓度分布曲线的变化机理，这在选择题型中属于最高层次的难度要求。" + }, + { + "idx": 2224, + "question": "Assuming the recrystallization temperature is defined as the temperature at which 95% recrystallization is completed within 1h, according to the Arrhenius equations Ṅ=N0exp(−Qn/RT) and G=G0exp(−Qg/RT), it can be inferred that the recrystallization temperature will be a function of G and Ṅ. Determine the functional relationship between the recrystallization temperature and G0, N0, Qg, Qn.", + "answer": "According to the J-M equation, if the temperature at which 95% recrystallization is completed within 1h is defined as TF, then 0.95=1−exp(−π/3 ṄG3t0^4). Therefore, t0=(2.86/ṄG3)^1/4. Substituting the Arrhenius equations, we obtain N0G0^3exp(−(Qn+3Qg)/RTF)=k. Rearranging gives TF=(Qn+3Qg)/(R ln(N0G0^3/k))=k′(Qn+3Qg). This equation represents the functional relationship between TF and N0, G0, Qn, Qg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据给定的Arrhenius方程推导出再结晶温度与G0、N0、Qg、Qn之间的函数关系，答案中涉及了公式推导和数学运算，属于需要数值计算和公式应用的题型。 | 知识层次: 题目需要综合运用Arrhenius方程和J-M方程，进行多步推导和公式变换，涉及多个变量的关联分析，思维过程较为复杂，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于高难度综合计算。题目要求综合运用Arrhenius方程和J-M方程，进行多步骤的数学推导和变量替换，最终得出复杂的函数关系。这不仅需要深入理解材料科学中的再结晶机理，还需要较强的数学推导能力和综合运用知识的能力。在选择题型内，这种需要多学科知识综合和复杂推导的题目属于最高难度等级。" + }, + { + "idx": 3939, + "question": "13}\nSome hypothetical alloy is composed of 12.5 wt% of metal A and 87.5 wt% of metal B. If the densities of metals A and \\mathrm{B} are 4.27 and 6.35g / {cm}^{3}, respectively, whereas their respective atomic weights are 61.4 and 125.7g / mol, determine whether the crystal structure for this alloy is simple cubic, facercentered cubic, or body-centered cubic. Assume a unit cell edge length of 0.395nm.", + "answer": "the crystal structure is body-centered cubic.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定合金的晶体结构类型，涉及密度、原子重量和晶胞边长等参数的计算。答案是基于计算结果得出的具体晶体结构类型，而非从选项中选择或简单的对错判断。 | 知识层次: 题目需要进行多步计算，包括质量分数转换为原子分数、计算单位晶胞中的原子数，并结合晶体结构的知识进行综合分析。虽然不涉及复杂的推理或机理解释，但需要关联多个概念并进行中等难度的计算。 | 难度: 在选择题中属于高难度，需要综合运用多个概念并进行复杂计算。题目涉及重量百分比、密度、原子量、晶体结构等多个知识点，解题步骤包括计算平均密度、摩尔分数、单位晶胞中的原子数等多个步骤，且需要综合分析计算结果与晶体结构的关系。这种多变量、多步骤的计算问题在选择题型中属于较复杂的难度水平。" + }, + { + "idx": 3654, + "question": "Tin atoms are introduced into a FCC copper crystal, producing an alloy with a lattice parameter of 3.7589 × 10^{-8} cm and a density of 8.772g / {cm}^{3}. Calculate the atomic percentage of tin present in the alloy.", + "answer": "11.95%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锡在合金中的原子百分比，答案是一个具体的数值结果（11.95%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括利用晶格参数计算晶胞体积、应用密度公式计算原子质量、结合铜和锡的原子质量计算原子百分比等步骤。这需要综合运用材料科学中的晶体结构知识和化学计量知识，属于中等应用层次。 | 难度: 在选择题中属于高难度，需要综合运用多个概念（如晶体结构、密度计算、原子百分比等）并进行多步复杂计算。题目要求考生不仅掌握FCC晶格参数与密度的关系，还需要处理合金中不同原子的贡献，涉及单位换算和代数运算。这种综合性计算问题在选择题中属于较难的类型，需要较强的分析能力和计算技巧。" + }, + { + "idx": 2599, + "question": "On the (111) plane of a copper single crystal, there is a right-handed screw dislocation with $b=a/2$ [10 ], where $a=0.36\\\\mathsf{n m}$. Now, a tensile stress of $10^{6}\\\\mathsf{P a}$ is applied along the [001] direction. Find the force acting on the screw dislocation.", + "answer": "Using the Peach-Koehler formula, we obtain \\n\\n$$\\n{f}=(\\\\sigma\\\\cdot b)\\\\times\\\\upsilon\\n$$\\n\\n$$\\n\\\\begin{array}{r l}&{\\\\langle\\\\left[\\\\begin{array}{l}{\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}}\\\\ {\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}\\\\bar{\\\\mathbb{O}}}\\\\end{array}\\\\right]\\\\bullet\\\\frac{\\\\bar{\\\\mathbb{a}}}{2}\\\\left[\\\\begin{array}{l}{1}\\\\ {\\\\bar{\\\\mathbb{O}}}\\\\ {-1}\\\\end{array}\\\\right]\\\\rangle\\\\times\\\\frac{\\\\sqrt{2}}{2}\\\\left[\\\\begin{array}{l}{1}\\\\ {\\\\bar{\\\\mathbb{O}}}\\\\ {-1}\\\\end{array}\\\\right]=\\\\frac{\\\\rho}{(-\\\\sqrt{2/4})\\\\mathsf{a}\\\\upsigma_{z}j},}\\\\end{array}\\n$$\\n\\nThus, $\\\\pounds=1.27\\\\times10^{-4}$ N/m, and the direction is along the negative $\\\\pmb{\\\\ y}$-axis.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过应用Peach-Koehler公式进行数值计算，最终得出一个具体的力值（1.27×10^-4 N/m），并确定其方向。答案涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目需要应用Peach-Koehler公式进行多步计算，涉及应力、柏氏矢量和位错线方向的向量运算，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于高难度，需要深入理解Peach-Koehler公式的应用，进行多步骤的向量和矩阵运算，并正确识别晶体学方向和应力张量的关系。题目涉及复杂的多变量计算和综合分析能力，远超一般选择题的简单概念判断或单步计算要求。" + }, + { + "idx": 2780, + "question": "The homogeneous nucleation rate of pure metals can be expressed by the following equation: $$ \\\\dot{N}=A\\\\exp\\\\Bigl(-\\\\frac{\\\\Delta G^{*}}{k T}\\\\Bigr)\\\\exp\\\\Bigl(-\\\\frac{Q}{k T}\\\\Bigr)$$ where $A\\\\approx10^{35}\\\\mathfrak{s e x p}\\\\left\\\\{-\\\\frac{Q}{k T}\\\\right\\\\}\\\\approx10^{-2}\\\\mathfrak{s}$, $\\\\Delta G^{*}$ is the critical nucleation work; $\\\\pmb{k}$ is the Boltzmann constant, with a value of $1.38\\\\times10^{-23}\\\\mathrm{J}/\\\\mathrm{K}$. \\n\\n$\\\\textcircled{1}$ Assuming undercooling $\\\\Delta T$ is $20\\\\mathrm{\\\\mathcal{C}}$ and ${\\\\bf 200}\\\\%$, interfacial energy $\\\\sigma{=}2\\\\times10^{-5}~\\\\mathrm{J/cm^{2}}$, heat of fusion $\\\\Delta H_{\\\\mathrm{m}}=$ $\\\\mathrm{12600J/mol}$, melting point $\\\\mathcal{T}_{\\\\mathbf{m}}{=}1000\\\\:\\\\mathrm{K}$, molar volume $V{=}6~\\\\mathrm{cm}^{3}/\\\\mathrm{mol}$, calculate the homogeneous nucleation rate $\\\\dot{N}$. \\n\\n$\\\\textcircled{2}$ If it is heterogeneous nucleation, with the contact angle between the nucleus and impurity $\\\\pmb{\\\\theta}\\\\mathrm{=}60^{\\\\circ}$, how does $\\\\dot{N}$ change? What is $\\\\Delta T$? \\n\\n$\\\\textcircled{3}$ Derive the relationship between $\\\\neq^{*}$ and $\\\\mathbf{\\\\Delta}\\\\pmb{\\\\Delta}^{T}$, and calculate $\\\\begin{array}{l}{\\\\underbrace{\\\\Delta\\\\mathcal{T}}_{\\\\mathcal{T}_{\\\\infty}}}\\\\end{array}$ when $r^{*}=1{\\\\mathrm{~nm}}$.", + "answer": "$$ \\\\begin{array}{l}{{\\\\dot{N}=A\\\\exp\\\\Bigl(-\\\\frac{\\\\Delta G^{*}}{{\\\\dot{k}}T}\\\\Bigr)\\\\exp\\\\Bigl\\\\{-\\\\frac{Q}{k t}\\\\Bigr\\\\}}}\\\\ {{{}}}\\\\ {{=10^{35}\\\\times10^{-2}\\\\times\\\\exp\\\\Bigl(-\\\\frac{16\\\\pi\\\\sigma^{3}}{3\\\\Delta G_{v}^{2}k T}\\\\Bigr)}}\\\\ {{{}}}\\\\ {{=10^{33}\\\\times\\\\exp\\\\Bigl(-\\\\frac{16\\\\pi\\\\sigma^{3}T_{\\\\mathrm{a}}^{2}V^{2}}{3k T\\\\Delta{\\\\dot{H}}^{2}\\\\Delta{\\\\dot{T}}^{2}}\\\\Bigr)}}\\\\end{array}$$ $\\\\textcircled{1}$ \\n\\nWhen $\\\\Delta T=20\\\\mathrm{~C~}$: $$ {\\\\dot{N}}{=}10^{33}\\\\exp\\\\Bigl[{-\\\\frac{16\\\\times3.14\\\\times(2\\\\times10^{-5})^{3}\\\\times1000^{2}\\\\times6^{2}}{3\\\\times1.38\\\\times10^{-23}\\\\times800\\\\times12600^{2}\\\\times200^{2}}}\\\\Bigr]$$ $\\\\textcircled{2}$ When $\\\\theta=60^{\\\\circ}$: The heterogeneous nucleation free energy $$ \\\\Delta G_{\\\\mathrm{in}}^{*}=\\\\Delta G^{*}\\\\ \\\\Bigl(\\\\frac{2-3\\\\mathrm{cos}60^{\\\\circ}+\\\\mathrm{cos}^{3}60^{\\\\circ}}{4}\\\\Bigr)=0.156\\\\Delta G^{*}.$$ When $\\\\Delta T{=}20\\\\mathrm{~C~}$, $\\\\dot{N}=10^{33}\\\\exp(-0.156\\\\times5615,8)=0$. When $\\\\Delta{\\\\cal T}{=}200\\\\Upsilon$, $\\\\dot{N}{=}10^{33}\\\\exp(-0.156\\\\times68.79){=}2.2\\\\times10^{28}\\\\left({\\\\mathrm{cm}}^{-3}{\\\\mathrm{s}}^{-1}\\\\right)$. Assuming undercooling is $\\\\Delta T,T{=}T_{\\\\infty}{-}\\\\Delta T$, according to the given conditions: $$ 1=10^{33}\\\\exp\\\\Bigl(-\\\\frac{16\\\\times3.14\\\\times200^{3}\\\\times1000^{2}\\\\times6^{2}}{3\\\\times1.38\\\\times10^{-16}\\\\times(12600\\\\times10^{7})^{2}(1000-\\\\Delta T)\\\\Delta T^{2}}\\\\times0.156\\\\Bigr)$$ or $$ 10^{-33}=\\\\exp\\\\Bigl(-\\\\frac{3.43\\\\times10^{8}}{(1000-\\\\Delta T)\\\\Delta T^{2}}\\\\Bigr)$$ Taking the logarithm of both sides: $$ 75.98={\\\\frac{3.43\\\\times10^{8}}{(1000-\\\\Delta T)\\\\Delta T^{2}}}$$ $$ (1000-\\\\Delta T)\\\\Delta T^{\\\\circ}=4.51\\\\times10^{6}$$ Thus: $$ \\\\Delta T\\\\approx70^{\\\\circ}C$$ $\\\\textcircled{3}$ $$ r^{\\\\bullet}=\\\\frac{2\\\\sigma}{\\\\Delta G}=\\\\frac{2\\\\sigma T_{\\\\mathrm{m}}V}{\\\\Delta H\\\\Delta T}$$ $$ {\\\\frac{\\\\Delta\\\\mathrm{T}}{\\\\mathrm{T}_{\\\\mathrm{m}}}}={\\\\frac{2\\\\sigma V}{\\\\Delta H r^{\\\\ast}}}$$ When $r^{*}=1\\\\mathrm{nm}$: $$ \\\\frac{\\\\Delta T}{T_{\\\\mathrm{m}}}=\\\\frac{2\\\\times200\\\\times6}{12600\\\\times10^{7}\\\\times1\\\\times10^{-7}}=0.19$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算均匀成核速率、非均匀成核速率的变化以及推导临界半径与过冷度之间的关系，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用公式进行计算和分析，包括均质形核率、异质形核率的变化以及临界半径与过冷度的关系推导。虽然不涉及复杂的机理解释或创新设计，但需要较高的综合分析能力。 | 难度: 在选择题中属于高难度题目，需要处理复杂的多变量计算和综合分析。题目涉及多个步骤的计算，包括临界成核功、界面能、熔化热等参数的运用，以及在不同条件下的比较分析（如均质成核与非均质成核的对比）。此外，还需要推导关系式并进行数值计算，对学生的综合应用能力和数学处理能力要求较高。" + }, + { + "idx": 2396, + "question": "Assuming the resistance (shear stress) that dislocation slip needs to overcome is 1.5×10^8 Pa for 30-51=Fe alloy, the shear modulus G for 3% Si-Fe alloy is 3.5×10^11 Pa, and the lattice constant is 0.28 nm. How thick is the low-dislocation-density layer near the surface of the 3% Si-Fe alloy? It is known that iron-silicon alloy has a body-centered cubic structure, and the Burgers vector length is 0.28√3/2 nm = 0.242 nm.", + "answer": "Due to the effect of surface image force, dislocations near the surface are subjected to the image force F_im. When the image force is greater than or equal to the resistance to dislocation slip, the dislocation slips out of the surface, reducing the dislocation density near the surface. Taking a screw dislocation as an example, the image force F_im per unit length parallel to the surface is F_im = τ_in b = G b^2 / (4π d), where d is the distance of the dislocation from the surface. When F_im equals the resistance to dislocation slip, d represents the thickness of the low-dislocation-density layer near the surface. Therefore, d ≤ G b / (4π τ_⊥). The thickness of the low-dislocation-density layer for the iron-silicon alloy is d = (3.5×10^11 × 0.242×10^-9) / (4π × 1.5×10^8) m = 4.88×10^-8 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解低位错密度层的厚度，解答过程中涉及多个物理量的代入和计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如表面镜像力、位错滑移阻力等），但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于高难度，需要综合运用多个材料科学概念（如位错理论、表面镜像力、剪切模量等），进行多步骤计算（包括单位转换、公式推导和数值计算），并理解复杂物理现象（位错在近表面的行为）。题目涉及的知识点深度和计算复杂度明显高于普通选择题要求。" + }, + { + "idx": 2392, + "question": "A face-centered cubic single crystal undergoes tensile deformation with the tensile axis along [001]. Determine the force on a dislocation with Burgers vector $b{=}a[\\overline{{\\textbf{\\vert}}}0\\mathbf{\\vert}]/2$ and line direction $t$ parallel to [121] in the slip direction. The lattice constant is given as $=0.35\\\\pi m$.", + "answer": "The force $F$ per unit length of the dislocation line in the slip plane is the product of the resolved shear stress $=5$ in the slip direction of the applied stress field and the Burgers vector $h$: $F_{n}=n+$. Under uniaxial tension (stress $(\\overline{o})$), $\\\\tau=\\\\sigma\\\\mathrm{cos}\\\\lambda\\\\cos\\\\varphi$, where $\\\\lambda$ is the angle between the tensile axis and the Burgers vector, and $11\\\\pi$ is the angle between the tensile axis and the normal to the slip plane. Since $b{=}a[\\overline{{\\textbf{l}}}()]\\\\backslash2$ and $t$ is parallel to [121], the slip plane is the plane containing both the Burgers vector and the dislocation line, hence the slip plane is (111). Therefore, 2 is the angle between [001]-[101], and $42$ is the angle between [001]-[111]. Using the crystallographic angle formula for cubic systems, $$\\\\cos\\\\lambda={\\\\frac{1}{\\\\sqrt{1}\\\\sqrt{1+1}}}={\\\\frac{1}{\\\\sqrt{2}}}\\\\qquad\\\\cos\\\\varphi={\\\\frac{1}{\\\\sqrt{1}\\\\sqrt{1+1+1}}}={\\\\frac{1}{\\\\sqrt{3}}}$$ Thus, $=\\\\sigma/\\\\sqrt{6}=0.408\\\\sigma$, and the magnitude of $11$ is $\\\\alpha\\\\sqrt{2}/2=0.36\\\\times10^{-9}\\\\times\\\\sqrt{2}/2=2.55\\\\times10^{-10}\\\\mathrm{m}$. Finally, $$ F_{\\\\mathrm{g}}=\\\\tau b=0.408\\\\times2.55\\\\times10^{-10}\\\\sigma\\\\mathrm{N}/\\\\mathrm{m}=1.04\\\\times10^{-10}\\\\sigma\\\\mathrm{N}/\\\\mathrm{m}$$ where the unit of $\\\\frac{1}{a^{2}}$ is $\\\\mathsf{P}_{\\\\perp}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定位错上的力，解答过程中涉及到了晶体学角度公式、应力分解和单位转换等计算步骤，最终给出了具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括确定滑移面、计算角度、应用晶体学公式、计算分解剪应力以及最终的力计算。虽然不需要复杂的推理分析或机理解释，但需要综合运用多个知识点进行中等难度的计算和分析。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。需要综合运用晶体学、位错理论、应力分析等多个知识点，并进行多步骤的计算推导。具体包括：" + }, + { + "idx": 139, + "question": "The viscosity of Pyrex glass is 10^9 Pa·s at 1400°C and 10^13 Pa·s at 840°C. To facilitate forming, approximately what temperature is required for the glass to reach a viscosity of 10^5 Pa·s?", + "answer": "According to the formula: η = η0 exp(ΔE / (R T)). Given η0 = 11.22 Pa·s and ΔE = 254.62 kJ/mol. When η = 10^5 Pa·s, 10^5 = 11.22 exp(254.62 × 1000 / ((273 + t) × 8.314)). Solving gives t = 3094.2°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，以求解特定温度值。答案展示了详细的公式应用和计算过程，符合计算题的特征。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及对数运算和温度转换，需要理解粘度与温度的关系并正确应用公式。虽然不涉及复杂的综合分析或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于高难度题目，需要理解粘度与温度的复杂关系，应用阿伦尼乌斯公式进行多步计算，涉及对数运算和温度转换，且需要处理较大的数值范围和单位换算。解题过程需要较强的综合分析能力和数学运算技巧，超出了选择题常见的简单计算或概念判断的范畴。" + }, + { + "idx": 325, + "question": "Calculate the number of atoms in the critical nucleus for copper with a face-centered cubic crystal structure. (a=0.3615nm)", + "answer": "The volume of the critical nucleus V = (4/3) × π × (γ*)³ = (4/3) × 3.14 × (1.087 × 10⁻⁷)³ = 5.39 × 10⁻²¹ cm³. The unit cell volume V_cell = a³ = (0.3615 × 10⁻⁷)³ = 4.72 × 10⁻²³ cm³. The number of unit cells N = V / V_cell = 5.39 × 10⁻²¹ / 4.72 × 10⁻²³ ≈ 114. The number of atoms in a face-centered cubic unit cell is 4, so the number of atoms in the critical nucleus = 114 × 4 = 456.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及原子数量、体积等具体计算步骤，答案也以数值结果呈现。 | 知识层次: 题目需要进行多步计算，包括临界核体积的计算、晶胞体积的计算以及单位晶胞内原子数的应用。虽然涉及的概念和公式较为基础，但需要将这些概念和公式综合运用，进行多步推导和计算，属于中等应用层次。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求进行多步骤的复杂计算，包括临界核体积、晶胞体积的计算，以及单位晶胞内原子数的转换。此外，还需要理解面心立方晶体结构的基本概念，并将这些概念综合应用到实际问题中。这种题目不仅考察了基础知识的掌握，还要求考生具备较强的计算能力和综合分析能力，因此在选择题型中属于复杂多变量计算的高难度题目。" + }, + { + "idx": 135, + "question": "CeO2 has a fluorite structure. When 15 mol% CaO is added to form a solid solution, the measured density of the solid solution is d = 7.01 g/cm³, and the unit cell parameter is a = 0.5417 nm. Determine through calculation which type of solid solution is formed. The atomic weights are Ce 140.12, Ca 40.08, O 16.00.", + "answer": "For the CaO-CeO2 solid solution, from the perspective of maintaining electrical neutrality, it can form either an oxygen vacancy solid solution or a solid solution with Ca²⁺ embedded in the anion interstitial sites. The solid solution equations are as follows: For substitutional solid solution, x = 0.15, 1 - x = 0.85, 2 - x = 1.85, so the chemical formula of the substitutional solid solution is Ca0.15Ce0.85O1.85. Since CeO2 has a fluorite structure, the number of unit cell molecules Z = 4, and the unit cell contains three types of ions: Ca²⁺, Ce⁴⁺, and O²⁻. The mass of the unit cell is: W = ΣWi = [4 × (0.15/1) × MCa²⁺ + 4 × (0.85/1) × MCe⁴⁺ + 8 × (1.85/2) × MO²⁻] / 6.022 × 10²² = 102.766 × 10⁻²² g. The calculated density dR = W/V = 0.6465 g/cm³. For interstitial solid solution, the chemical formula is Ca2Ce1-yO2. Compared with the given composition Ca0.15Ce0.85O1.85, the O²⁻ content differs: Ca0.15Ce0.85O1.85 → Ca0.15×2/1.85Ce0.85×2/1.85O2. y = 0.15 × 2 / 1.85, 1 - y = 0.85 × 2 / 1.85 ⇒ y = 0.15 / 1.85. The chemical formula of the interstitial solid solution is Ca0.15×2/1.85Ce1.7/1.85O2. Similarly, the calculated density dg = W/V = 7.033 g/cm³. The measured density is d = 7.01 g/cm³, which is close to d2. Therefore, an interstitial solid solution is formed, with interstitial Ca²⁺ ions present.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算确定形成的固溶体类型，涉及密度、晶胞参数和原子量的计算，答案中展示了详细的公式应用和数值计算过程。 | 知识层次: 题目需要进行多步计算，包括化学式的推导、单位晶胞质量的计算、密度的计算等，同时需要理解固溶体的形成机制和电中性原则，涉及多个概念的关联和综合分析。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和概念关联。需要考生掌握固体溶液的形成机制、密度计算、晶胞参数与化学组成的关联等知识点，并进行综合分析。计算过程涉及多个变量和步骤，包括化学式的推导、单位晶胞质量的计算、密度的比较等，对考生的综合能力和计算精度要求较高。" + }, + { + "idx": 2173, + "question": "When stretching a copper single crystal, if the direction of the tensile axis is [001], $\\\\sigma=10^{6}$ Pa. Calculate the force on the screw dislocation line with Burgers vector $b=$ $\\\\frac{a}{2}$ [101] on the (111) plane $(a_{\\\\mathrm{Cu}}=0.36\\\\mathrm{nm})$.", + "answer": "Let the resolved shear stress of the applied tensile stress along the [101] direction on the (111) slip plane be $\\\\tau$, then $$ x \\\\tau=\\\\sigma{\\\\cos}\\\\varphi{\\\\cos}\\\\lambda\\n $$\\n where, $\\\\varphi$ is the angle between [001] and the normal [111] of the (111) plane, $\\\\lambda$ is the angle between [001] and the [101] direction. \\n\\nSo $$ \\\\tau=10^{6}\\\\times{\\\\frac{1}{{\\\\sqrt{1}}\\\\times{\\\\sqrt{3}}}}\\\\times{\\\\frac{1}{\\\\sqrt{2}}}=4.0825\\\\times10^{5}{\\\\mathrm{~Pa}}\\n $$\\n If the force on the screw dislocation line is $F_{\\\\mathrm{d}}$, then $$ F_{\\\\mathrm{d}}=\\\\tau b=4.0825\\\\times10^{5}\\\\times{\\\\frac{\\\\sqrt{2}}{2}}\\\\times0.36\\\\times10^{-9}=1.039\\\\times10^{-4}~{\\\\mathrm{N/m}}\\n $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了应力分解、角度计算和力的计算，最终给出了具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括计算分解剪应力、角度计算以及最终的力计算，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的理解和应用能力。 | 难度: 在选择题型中，这道题目属于高难度等级。原因如下：" + }, + { + "idx": 854, + "question": "When the vacancy equilibrium concentration in germanium crystals decreases by six orders of magnitude from $600\\\\%$ to $300\\\\mathrm{\\\\textperthousand}$, calculate the vacancy formation energy in germanium crystals (Boltzmann constant $k=8.617\\\\times10^{-5}\\\\mathrm{eV}/\\\\mathrm{K})$.", + "answer": "The equilibrium concentration formula for Schottky defects is: $$\\\\begin{array}{r l}&{\\\\mathrm{atsing~sefiell}\\\\eta+\\\\mathrm{fight}\\\\mathcal{R}\\\\Sigma\\\\Delta t:}\\\\ &{\\\\qquad\\\\overline{{C}}_{\\\\mathrm{s}}\\\\leq e\\\\Bigg\\\\{-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg\\\\}=\\\\mathrm{evel}\\\\Bigg(-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg)=\\\\mathrm{evel}\\\\Bigg(-\\\\frac{\\\\Delta C_{s}}{H\\\\Gamma}\\\\Bigg)}\\\\ &{\\\\mathrm{atsin}}\\\\ &{\\\\frac{\\\\Delta C_{s}}{H\\\\mathcal{N}_{x}\\\\Gamma}=-\\\\mathrm{in}\\\\overline{{C}}_{s},}\\\\ &{\\\\frac{\\\\Delta C_{s}}{\\\\Delta W_{x}}\\\\Bigg(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\Bigg)=\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}-\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}}\\\\ &{\\\\Delta G_{s}=\\\\frac{\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}-\\\\mathrm{in}\\\\overline{{C}}_{\\\\mathrm{s}}}{\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}}(k\\\\chi_{x})}\\\\ &{\\\\qquad-\\\\frac{1}{\\\\frac{\\\\mathrm{fim}}{2}-\\\\frac{1}{T_{2}}}\\\\frac{\\\\kappa_{\\\\mathrm{B}}\\\\lambda_{1}\\\\Gamma\\\\kappa_{\\\\mathrm{m}}t^{-1}}{-\\\\frac{1}{\\\\omega_{0}+2/3}}}\\\\ &{\\\\qquad\\\\frac{1}{3(\\\\omega+2/3)}-\\\\frac{1}{6(\\\\omega+2/3)}}\\\\ &{\\\\qquad\\\\nu\\\\neq\\\\ell\\\\geq\\\\frac{1}{\\\\mathrm{in}\\\\mathcal{L}_{x}\\\\Bigg\\\\{1,2,3\\\\}\\\\Gamma\\\\kappa_{\\\\mathrm{m}}\\\\mathcal{R}_{x}\\\\Bigg\\\\}.}\\\\end{array}$$ That is, $10^{5}\\\\mathrm{J}^{\\\\cdot}\\\\mathrm{mol}^{-1}$ in germanium crystals.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空位形成能，答案中包含了具体的计算公式和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用Schottky缺陷的平衡浓度公式，进行多步计算和温度与浓度关系的综合分析。虽然涉及基本的公式应用，但需要理解温度变化对空位浓度的影响，并进行对数运算和能量计算，属于中等应用层次。 | 难度: 在选择题型中，这道题目属于高难度等级。题目涉及复杂的多步计算和概念关联，需要考生深入理解Schottky缺陷的平衡浓度公式，并能正确应用Boltzmann常数进行能量计算。题目中的公式推导和变量处理较为复杂，且需要考生具备综合分析能力，能够将多个物理概念和数学步骤结合起来解决问题。此外，题目中的符号和表达式较为复杂，增加了理解和解题的难度。因此，在选择题型内，这道题目属于复杂多变量计算的高难度等级。" + }, + { + "idx": 2792, + "question": "Given a diffusion couple composed of pure chromium and pure iron, it is known that when the mole fraction x_Cr=0.478, ∂x/∂z=126/cm, and the interdiffusion coefficient D=1.43×10^(-8) m²/s, find the intrinsic diffusion coefficients D_Cr and D_Fe of chromium and iron.", + "answer": "According to the Kirkendall effect, the marker velocity vₐ = (D_Cr - D_Fe)×126. The interdiffusion coefficient D = x_Fe D_Cr + x_Cr D_Fe → 0.478 D_Fe + (1-0.478) D_Cr = 1.43×10^(-8) m²/s. By solving these two equations together with the marker velocity vₐ at the Matano plane, we obtain D_Cr = 2.23×10^(-9) cm²/s and D_Fe = 0.56×10^(-9) cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铬和铁的本征扩散系数D_Cr和D_Fe，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用Kirkendall效应和扩散系数的相关公式，进行多步计算和概念关联，包括解方程组和数值计算，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于高难度，需要理解Kirkendall效应、Matano平面、扩散系数等多个概念，并进行多步计算和综合分析。题目涉及多个变量和方程联立求解，计算过程复杂，对知识点的掌握深度和解题能力要求较高。" + }, + { + "idx": 4037, + "question": "Compute the number of electrons that each aluminum atom donates, on average, to a bulk piece of aluminum metal. Room temperature data for aluminum:\nThe resistivity of aluminum is 2.63 × 10^{-8} \\Omega·m\nThe electron mobility of aluminum is 0.0012{m}^{2} /(V·s)\nThe mass density of aluminum is 2.7g / {cm}^{3}\nThe atomic weight of aluminum is 27g / mol", + "answer": "3.29 electron/atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的物理参数（如电阻率、电子迁移率、质量密度和原子量）进行数值计算，最终得出每个铝原子平均贡献的电子数。解答过程需要应用相关公式和单位转换，答案是一个具体的数值（3.29 electron/atom），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及电阻率、电子迁移率、质量密度和原子重量等多个物理量的关联和综合分析，需要运用相关公式进行计算，但不需要进行复杂的推理分析或机理解释。 | 难度: 在选择题中属于高难度，需要综合运用多个物理概念（电阻率、电子迁移率、质量密度、原子量）进行多步骤计算，并理解金属导电的微观机制。题目要求将宏观测量参数与微观电子贡献联系起来，涉及单位转换和复杂公式推导（如载流子浓度计算），远超选择题常见的单步计算或概念识别难度。" + }, + { + "idx": 3670, + "question": "A single crystal of a BCC metal is oriented so that the direction is parallel to the applied stress. If the critical resolved shear stress required for slip is 12,000 psi, calculate the magnitude of the applied stress required to cause slip to begin in the [1,-1,1] direction on the (110) slip plane.", + "answer": "the magnitude of the applied stress required to cause slip to begin in the [1,-1,1] direction is: on the (110) slip plane: σ = ∞", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解施加应力的大小，答案给出了具体的计算结果（σ = ∞），符合计算题的特征。 | 知识层次: 题目需要应用临界分切应力概念，进行晶体取向与应力关系的多步计算，涉及向量点积和晶体学方向分析等中等复杂度的综合应用。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求计算BCC金属单晶在特定取向下的临界应力，涉及多个步骤和概念的综合应用。首先需要理解晶体取向、滑移方向和滑移面的关系，其次要应用临界分切应力的概念进行计算。题目中的正确选项表明需要认识到在给定条件下无法发生滑移（σ = ∞），这要求考生不仅掌握计算步骤，还要深入理解晶体滑移的几何限制条件。这种多变量、多概念的综合分析在选择题中属于复杂难度。" + }, + { + "idx": 2850, + "question": "A single crystal of A1 is made into a tensile specimen (with a cross-sectional area of 9 mm²) for room-temperature tensile testing. The tensile axis forms an angle of $36.7^{\\\\circ}$ with [001], $19.1^{\\\\circ}$ with [011], and $22.2^{\\\\circ}$ with [111]. The load at the onset of yielding is 20.4 N. Determine the resolved shear stress on the primary slip system.", + "answer": "From the known tensile axis direction, the primary slip system can be determined as (111)[101] using the standard projection diagram of the cubic crystal system (001). Let the stress axis direction be $[u\\\\tau\\\\mathbf{w}]$. From the given conditions, we have $$\\\\cos36.7^{\\\\circ}=\\\\frac{w}{\\\\sqrt{u^{2}+v^{2}+w^{2}}}$$$$\\\\cos19.1^{\\\\circ}=\\\\frac{v+w}{\\\\sqrt{2}\\\\sqrt{u^{2}+v^{2}+w^{2}}}$$$$\\\\cos22.2^{\\\\circ}={\\\\frac{u+v+w}{{\\\\sqrt{3}}{\\\\sqrt{{u}^{2}+{v}^{2}+{w}^{2}}}}}$$Let $u^{2}+v^{2}+w^{2}=1$, then solving gives $\\\\scriptstyle\\\\pmb{u}=0.26$, $v{=}0.54$, ${\\\\mathfrak{w}}{=}0.80$. Thus, $\\\\cos\\\\lambda={\\\\frac{0.26+0.80}{\\\\sqrt{2}}}=0.75$ $$\\\\cos\\\\phi=\\\\frac{-0.26+0.54+0.80}{\\\\sqrt{3}}=0.62$$$$\\\\tau=\\\\sigma\\\\cos\\\\lambda\\\\cos\\\\phi=\\\\frac{20.4}{9\\\\times10^{-6}}\\\\times0.75\\\\times0.62=1.01(\\\\mathrm{MPa})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定解析剪切应力，解答过程中涉及多个步骤的数学运算和方向余弦的计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括确定主滑移系统、计算方向余弦、求解应力分量等，涉及多个概念的综合应用和关联分析，但不需要进行复杂的机理推理或创新设计。 | 难度: 在选择题型中，该题目属于高难度等级。题目涉及复杂的多变量计算，需要掌握晶体学方向指数的计算、解析剪切应力的概念，以及多步骤的数学推导和计算过程。解题过程中需要求解方向余弦、确定主滑移系统，并进行应力分解，这些步骤在选择题型中都属于较高难度的要求。此外，题目还要求考生能够综合运用多个知识点，进行复杂的数学运算，这在选择题型中属于较为复杂和综合性的问题。" + }, + { + "idx": 2436, + "question": "The critical resolved shear stress of aluminum is $2.40\\\\approx10^{5}$ Pa. When the tensile axis is [001], what is the tensile stress required to cause yielding?", + "answer": "The relationship between tensile stress $\\\\sqrt{h}$ and the resolved shear stress on the slip system is =coscos, where and are the angles between the tensile direction and the slip direction and the normal to the slip plane, respectively. The crystal structure of aluminum is fcc, and the slip system is $11117=110.3$. When the tensile axis is [001], since it is perpendicular to [110] and [110], the resolved shear stress on the slip systems composed of them is 0, and they will not activate. The geometric relationship between the [001] axis and its slip systems is equivalent, and their resolved shear stresses are equal. Taking the (111)[011] slip system as an example, the tensile stress required to cause yielding is calculated. The cosine of the angle $\\\\varphi$ between [001] and the slip plane normal [111], cos$\\\\varphi$, and the cosine of the angle $\\\\lambda$ between [001] and the slip direction [011], cos$\\\\lambda$, are respectively $$ \\\\cos\\\\varphi={\\\\frac{1}{\\\\sqrt{1}{\\\\sqrt{3}}}}={\\\\frac{1}{\\\\sqrt{3}}}\\\\cos\\\\lambda={\\\\frac{1}{\\\\sqrt{1}{\\\\sqrt{2}}}}={\\\\frac{1}{\\\\sqrt{2}}}$$ When the critical resolved shear stress $\\\\frac{\\\\sqrt{1}}{2}=\\\\frac{1}{2}$ is $2.40\\\\times0^{-}10^{5}Pa$, the corresponding stress $\\\\alpha$ is the yield stress: $$ \\\\sigma_{\\\\circ}={\\\\frac{\\\\tau_{\\\\circ}}{\\\\cos\\\\varphi\\\\cos\\\\lambda}}=2.4\\\\times10^{5}\\\\times{\\\\sqrt{3}}\\\\times{\\\\sqrt{2}}\\\\mathbf{Pa}=5.89\\\\times10^{5}\\\\mathbf{Pa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的拉伸应力，解答过程中涉及到了角度计算、余弦值求解以及临界剪切应力的转换，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界分切应力与拉伸应力之间的关系，并应用几何关系进行计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在选择题中属于高难度，需要深入理解晶体结构和滑移系统的概念，进行多步计算和综合分析。题目涉及复杂的几何关系和三角函数计算，要求考生能够将理论知识与实际计算相结合，解决复杂多变量问题。" + }, + { + "idx": 166, + "question": "A glass composition (wt%) is Na2O 14%, CaO 13%, SiO2 73%, with a density of 2.5 g/cm3. Calculate the atomic packing factor (AFP) and structural parameter values of this glass?", + "answer": "The average molecular weight of the glass GW=0.14×62+0.13×56+0.73×60.02=59.77. The number of atoms in 1Å3 is n=2.5×10-24×6.02×1023/59.77=0.252 atoms/Å3. The volume occupied by atoms in 1Å3 V=0.0252×4/3π[0.14×2×0.983+0.13×1.063+0.73×0.393+(0.14+0.13+0.73+0.13+0.13)]×1.323=0.4685. AFP=0.46. Structural parameters: Na2O wt% 14, CaO wt% 13, SiO2 wt% 73; mol Na2O 0.23, CaO 0.23, SiO2 1.22; mol% Na2O 13.7, CaO 13.7, SiO2 72.6. R=(13.7+13.7+72.6×2)/72.6=2.38. Z=4. X=2R-Z=2.38×2-4=0.76. Y=Z-X=4-0.76=3.24.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算原子堆积因子（AFP）和结构参数值。答案中提供了详细的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括平均分子量计算、原子数密度计算、原子体积计算以及原子堆积因子计算，同时还需要理解和应用结构参数的概念和公式。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点并进行关联分析。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。需要完成以下高难度步骤：" + }, + { + "idx": 4139, + "question": "The formula for yttrium iron garnet \\left(\\mathrm{Y}_{3} \\mathrm{Fe}_{3} \\mathrm{O}_{12}\\right) may be written in the form \\mathrm{Y}_{3}^{*} \\mathrm{Fe}_{2}^{*} \\mathrm{Fe}_{3}^{d} \\mathrm{O}_{12}^{2}, where the superscripts a, c, and d represent different sites on which the \\mathrm{Y}^{3+} and \\mathrm{Fe}^{3+} ions are located. The spin magnetic moments for the \\mathrm{Y}^{3+} and \\mathrm{Fe}^{\\text {out }} ions positioned in the \\mathrm{a} and C sites are oriented parallel to one another and antiparallel to the \\mathrm{Fe}^{3+} ions in \\mathrm{d} sites. Compute the number of Bohr magnetons associated with each \\mathrm{Y}^{3+} ion, given the following information: (1) each unit cell consists of eight formula \\left(\\mathrm{Y}_{3} \\mathrm{Fe}_{5} \\mathrm{O}_{12}\\right) units; (2) the unit cell is cubic with an edge length of 1.2376nm; (3) the saturation magnetization for this material is 1.0 × 10^{4} \\mathrm{~A} / m; and (4) assume that there are 5 Bohr magnetons associated with each \\mathrm{Fe}^{3+} ion.", + "answer": "the number of bohr magnetons associated with each \\mathrm{y}^{3+} ion is 1.75 \\mathrm{bm}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和信息来求解每个Y3+离子所关联的玻尔磁子数。解答过程涉及单位晶胞的计算、饱和磁化强度的应用以及玻尔磁子数的推导，这些都是典型的计算题特征。答案以具体数值形式给出，进一步确认了这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及饱和磁化强度、单位晶胞体积、磁矩计算等概念的综合应用，需要理解不同离子位置的磁矩取向关系，并进行数值计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和多个概念的关联应用。需要理解晶体结构、磁矩计算、单位转换等知识，并进行综合分析。具体步骤包括计算单位体积内的磁矩、考虑离子排列方向、应用给定的磁化强度数据等，解题过程复杂且需要较高的计算能力。" + }, + { + "idx": 2404, + "question": "The shear modulus of Ni is G=75 GPa, and the intrinsic stacking fault energy is γ=150 mJ/m². Calculate the equilibrium width of dislocation extension.", + "answer": "Since the perfect dislocation before decomposition is an edge dislocation, the equilibrium width d₀ of the extended dislocation is d₀=Gb²/(8πγ)×(2+ν)/(1−ν)=75×10⁹×(0.147×10⁻⁹)²/(8π×150×10⁻³)×(2+1/3)/(1−1/3) m=1.505×10⁻⁹ m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（equilibrium width of dislocation extension）。答案中展示了详细的公式应用和计算过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解剪切模量、堆垛层错能以及位错扩展平衡宽度的概念，并能够正确代入公式进行计算。虽然计算过程较为直接，但需要对相关物理概念和公式有一定的理解和应用能力。 | 难度: 在选择题中属于高难度，题目涉及多步骤计算和多个物理概念的关联应用（如剪切模量、堆垛层错能、位错扩展宽度公式），需要综合运用材料科学和力学知识进行复杂计算。此外，题目还要求对泊松比等参数有深入理解，并正确代入公式进行推导，这在选择题型中属于较高要求。" + }, + { + "idx": 2460, + "question": "Estimate the number of atomic clusters containing 60 atoms in 1cm³ of copper at its melting point temperature. The atomic volume of liquid copper is 1.6×10⁻²⁹m³, the surface energy is 0.177J/m², and the melting point is 1356K.", + "answer": "According to nᵢ = n exp(-ΔG / k_B T), first calculate the energy ΔG₆₀ of a 60-atom cluster. The radius of the cluster r = (3×60×1.6×10⁻²⁹ / 4π)^(1/3), and the surface area A₆₀ = 4πr² = 4π(3×60×1.6×10⁻²⁹ / 4π)^(2/3). ΔG₆₀ = A₆₀γ = 4π(3×60×1.6×10⁻²⁹ / 4π)^(2/3)×0.177 = 8.33×10⁻¹⁹J. The number of atoms per cm³ n = 1 / (1.6×10⁻²³) = 6.25×10²² cm⁻³. n₆₀ = 6.25×10²² exp(-8.33×10⁻¹⁹ / (1.38×10⁻²³×1356)) = 2.91×10³ cm⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计铜中60原子团簇的数量，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算，包括原子团簇半径、表面积、能量变化等，并应用了热力学公式和指数函数。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行计算，属于中等应用层次。 | 难度: 在选择题中属于高难度，需要综合运用多个物理概念（原子体积、表面能、热力学等）进行多步骤计算，涉及复杂公式推导和变量转换，且计算精度要求较高。" + }, + { + "idx": 2417, + "question": "Consider a two-dimensional rectangular crystal with side lengths $L_{1}$ and $L_{\\\\pm}$ $L_{1}$ and $L_{\\\\perp}$. The interfacial energies for the two sides are $71$ and p, respectively. If the interfacial area remains constant ($L_{1}L_{1}=$ constant), prove that the equilibrium shape satisfies the relation $L_{1}/L_{2}=m g/y_{2}$.", + "answer": "The total surface energy of this crystal is $E=2(L_{1}y+L_{2}y_{2})$. At equilibrium shape, the following relation holds: $$ \\\\mathrm{d}E=2(L_{1}\\\\mathrm{d}\\\\gamma_{1}+\\\\gamma_{1}\\\\mathrm{d}L_{1}+L_{2}\\\\mathrm{d}\\\\gamma_{2}+\\\\gamma_{2}\\\\mathrm{d}L_{2})=0 $$ Since $72$ and $79$ are independent of length, the equation simplifies to $$ \\\\gamma_{1}\\\\mathrm{d}L_{1}+\\\\gamma_{1}\\\\mathrm{d}L_{2}=0 $$ Given that the area $[1L]=$ constant, i.e., $\\\\angle1\\\\mathrm{d}L_{2}+L_{2}\\\\mathrm{d}L_{1}=0$, substituting this relation into the above equation yields $L_{1}:L_{2}=m:21$. Q.E.D.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数学推导和公式应用来证明一个关系式，解答过程涉及微分和代数运算，属于典型的计算题类型。 | 知识层次: 题目涉及多步计算和概念关联，需要应用表面能的概念和平衡条件，并通过微分和代数运算推导出平衡形状的关系。虽然不涉及复杂的综合分析或创新应用，但需要一定的理解和计算能力。 | 难度: 在选择题中属于高难度，题目涉及多变量计算和综合分析。需要理解晶体平衡形状的概念，掌握表面能的计算方法，并能正确应用微分和约束条件进行推导。解题步骤包括建立能量表达式、微分处理、代入约束条件等多个复杂步骤，对学生的综合能力要求较高。" + }, + { + "idx": 2912, + "question": "The concentration fluctuation equation for spinodal decomposition is given by $C-C_{0}=\\\\mathtt{e}^{R(\\\\lambda)t}\\\\cos{\\\\frac{2\\\\pi}{\\\\lambda}{Z}}$. Find the critical wavelength, where $R(\\\\lambda)=-M\\\\frac{4\\\\pi^{2}}{\\\\lambda}\\\\biggl[\\\\vert G^{\\\\prime}+2\\\\eta Y+\\\\frac{8\\\\pi^{2}K}{\\\\lambda^{2}}\\\\biggr]$; M is the interdiffusion mobility; $\\\\eta$ is the mismatch due to concentration gradient; $Y=\\\\frac{E}{(1-\\\\nu)}$ ($E$ is the elastic modulus, $\\\\nu$ is the Poisson's ratio); $K$ is a constant; $\\\\lambda$ is the wavelength; $Z$ is the distance; $t$ is the time; $\\\\vert G^{\\\\prime}={\\\\frac{\\\\partial^{2}\\\\dot{G_{s}}}{\\\\partial x^{2}}}$ ($G_{s}$ is the free energy of the solid solution, $_x$ represents the composition of the solid solution).", + "answer": "When $R\\\\langle\\\\lambda\\\\rangle=0$, \\n\\n$$\\nC-C_{\\\\mathrm{0}}=\\\\cos\\\\frac{2\\\\pi}{\\\\lambda}Z\\n$$\\n\\nAt this point, the composition fluctuation does not change with time, meaning spinodal decomposition does not occur. Spinodal decomposition can only occur when $R\\\\langle\\\\lambda\\\\rangle>0$, i.e., the $\\\\lambda$ value when $R(\\\\lambda)=0$ is the critical wavelength $\\\\lambda_{c}$. Therefore, \\n\\n$$\\nG^{\\\\prime\\\\prime}+2\\\\eta Y+\\\\frac{8\\\\pi^{2}K}{\\\\lambda_{\\\\odot}^{2}}=0\\n$$\\n\\n$$\\n\\\\lambda_{\\\\mathrm{{c}}}=\\\\Bigl[\\\\frac{-8\\\\pi^{2}K}{\\\\vec{G}^{\\\\eta}+2\\\\eta Y}\\\\Bigr]^{\\\\frac{3}{2}}\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和条件，计算临界波长（critical wavelength）。解答过程涉及公式推导和数值计算，符合计算题的特征。 | 知识层次: 题目需要理解spinodal分解的浓度波动方程，并应用给定的公式进行多步计算以找到临界波长。虽然涉及多个变量和参数，但主要是基于给定的公式进行推导和计算，不需要进行复杂的机理分析或创新应用。 | 难度: 在选择题中属于高难度，需要深入理解多个复杂概念（如自旋分解、临界波长、自由能等），并进行多步计算和综合分析。题目涉及多个变量和参数（如M、η、Y、K等），要求考生能够正确应用公式并推导临界波长的表达式。解题步骤复杂，需要较高的数学和物理基础。" + }, + { + "idx": 145, + "question": "The working range of a certain type of glass is from $870^{\\\\circ}\\\\mathrm{C}$ ($\\\\eta=10^{6}\\\\mathrm{{Pa}\\\\cdot{}}$) to $1300^{\\\\circ}\\\\mathrm{C}$ ($\\\\eta=10^{2.5}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$). Estimate its annealing point ($\\\\eta=10^{12}\\\\mathrm{{Pa}\\\\cdot\\\\Delta s}$)?", + "answer": "According to the formula: $\\\\mathfrak{H}=\\\\mathfrak{N}_{0}\\\\exp(\\\\frac{\\\\Delta\\\\mathcal{E}}{R T})$ \\n\\nAt $870^{\\\\circ}\\\\mathrm{C}$, $\\\\eta=10^{6}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$, T=870+273=1143K, $10^{6}=1.57\\\\times10^{-7}\\\\exp[\\\\frac{280.16\\\\times1000}{1143\\\\times8.314}]$ (1) \\nAt $1300^{\\\\circ}\\\\mathrm{C}$, $\\\\eta=10^{2.5}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$ (2) \\nBy solving equations (1) and (2) simultaneously, we get: $\\\\mathfrak{V}_{0}=1.57\\\\times\\\\ensuremath{10^{-7}}\\\\mathrm{Pa}\\\\cdot\\\\mathrm{s}$, $\\\\Delta E=280.16\\\\mathrm{kJ/mol}$ \\nWhen $\\\\eta=10^{12}\\\\mathrm{{Pa}\\\\cdot\\\\mathrm{{s}}}$, $10^{12}=1.57\\\\times10^{-7}\\\\exp[\\\\frac{280.16\\\\times1000}{(273+t)\\\\times8.314}]$ \\nSolving gives $t=505.15^{\\\\circ}\\\\mathrm{C}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计玻璃的退火点，解答过程中涉及多个步骤的数学计算和方程求解。 | 知识层次: 题目需要应用粘度-温度关系的公式进行多步计算，涉及对数运算和方程求解，同时需要理解粘度与温度之间的关系，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和多个变量的综合分析。需要理解并应用粘度与温度关系的公式，同时进行对数运算和方程求解。解题步骤包括：" + }, + { + "idx": 2286, + "question": "A steel wire (with a diameter of $1~\\\\mathrm{mm}$) is coated with a layer of copper (total diameter of $2~\\\\mathrm{mm}$). What is the thermal expansion coefficient of this composite material? The elastic modulus of steel is $E_{\\\\mathrm{st}}{=}205~\\\\mathrm{GPa}$, and that of copper is $E_{\\\\mathrm{cu}}{=}110~\\\\mathrm{GPa}$; their expansion coefficients are $\\\\alpha_{\\\\mathrm{st}}=1.1\\\\times10^{-6}/\\\\mathsf{\\\\Pi}^{\\\\circ}\\\\mathsf{C}, \\\\alpha_{\\\\mathrm{Cu}}=17\\\\times10^{-6}/\\\\mathsf{\\\\Pi}^{\\\\circ}\\\\mathsf{C}$ respectively.", + "answer": "Under no-load conditions, the composite material satisfies $(\\\\Delta l/L)_{\\\\mathrm{st}}=(\\\\Delta l/L)_{\\\\mathrm{cu}}$, and the forces $F_{\\\\mathrm{Cu}}=-F_{\\\\mathrm{st}}$. If $\\\\Delta t= 1^{\\\\circ}\\\\mathrm{C}$, then $$ A_{\\\\mathrm{Cu}}=\\\\pi(\\\\frac{d}{2})^{2}=(\\\\pi/4)(0.002\\\\mathrm{m})^{2}-0.8\\\\times10^{-6}\\\\mathrm{m}^{2}=2.4\\\\times10^{-6}\\\\mathrm{m}^{2}$$ $$ (\\\\Delta l/L)_{\\\\mathrm{st}}=(\\\\Delta l/L)_{\\\\mathrm{cu}}$$ $$ \\\\begin{array}{r}{\\\\left[\\\\alpha\\\\Delta t+(F/A)/E\\\\right]_{\\\\ast}=\\\\left[\\\\alpha\\\\Delta t+(F/A)/E\\\\right]_{\\\\mathrm{cu}}}\\\\end{array}$$ $$ 1\\\\times10^{-6})\\\\times1+{\\\\frac{F_{\\\\mathrm{st}}/(0.8\\\\times10^{-6}{\\\\mathrm{m}}^{2})}{205\\\\times10^{9}{\\\\mathrm{N/m}}^{2}}}=(17\\\\times10^{-6})\\\\times1+{\\\\frac{-F_{\\\\mathrm{st}}/(2.4\\\\times10^{-6}{\\\\mathrm{m}}^{2})}{110\\\\times10^{9}{\\\\mathrm{N/m}}^{2}}}$$ When $\\\\Delta t=1~^{\\\\circ}C$, then $$ (\\\\Delta l/L)_{\\\\mathrm{cu}}=(17\\\\times10^{-6}/^{9}\\\\mathbb{C}\\\\times1^{9}\\\\mathbb{C})+\\\\frac{=0.61~\\\\mathrm{N}/(2.4\\\\times10^{-6}~\\\\mathrm{m}^{2})}{110\\\\times10^{9}~\\\\mathrm{N/m}^{2}}=15\\\\times10^{-6}$$ Thus, the thermal expansion coefficient of the composite material is $$ \\\\overline{{\\\\alpha}}=15\\\\times10^{-6}/^{\\\\circ}\\\\mathrm{C}$$ $A_{\\\\mathrm{st}}=\\\\pi(\\\\frac{d}{2})^{2}=(\\\\pi/4)(0.001~\\\\mathrm{m})^{2}=0.8\\\\times10^{-6}~\\\\mathrm{m}^{2}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及热膨胀系数的复合计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用热膨胀系数、弹性模量等知识，并进行综合分析。虽然不涉及复杂的推理分析或机理解释，但需要理解和应用多个物理概念和公式，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及多步复杂计算和多个物理概念的关联应用。需要正确理解复合材料的膨胀行为，建立力学平衡方程，并进行精确的数值计算。解题步骤包括面积计算、应变平衡方程建立、力平衡条件应用以及最终的热膨胀系数求解，涉及多个变量和单位转换，对综合分析和计算能力要求较高。" + }, + { + "idx": 2690, + "question": "Polypropylene is polymerized from propylene, with the chemical formula C3H6. Crystalline polypropylene belongs to the monoclinic crystal system, with lattice constants α = 0.665 nm, b = 2.096 nm, c = 0.65 nm, α = γ = 90°, β = 99.3°, and a density ρ = 0.91 g/cm³. Calculate the number of C and H atoms in the unit cell of crystalline polypropylene.", + "answer": "Assuming there are x C atoms in the polypropylene unit cell, then there are 2x H atoms. The volume of the unit cell is $$ V = a b c \\\\sin \\\\beta $$ $$ \\\\rho = \\\\frac{x \\\\cdot 12.011 + 2x \\\\cdot 1.008}{(6.65 \\\\times 10^{-8})(20.96 \\\\times 10^{-8})(6.5 \\\\times 10^{-8}) \\\\sin 99.3 \\\\times 6.023 \\\\times 10^{23}} = 0.91 $$ $$ x = \\\\frac{0.91 \\\\times 6.65 \\\\times 2.096 \\\\times 6.5 \\\\times \\\\sin 99.3 \\\\times 6.023}{12.011 + 2 \\\\times 1.008} = 34.936 \\\\approx 35 $$ $$ 2x = 2 \\\\times 35 = 70 $$ Therefore, the C3H6 unit cell contains 35 C atoms and 70 H atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞中的碳和氢原子数量，答案展示了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括单位晶胞体积的计算、密度的计算以及原子数量的推导，涉及晶体学参数和化学计量关系的综合分析。虽然不涉及复杂的机理分析或创新设计，但需要较高的计算能力和对晶体结构参数的理解。 | 难度: 在选择题中属于高难度，需要综合运用晶体学、化学计量学和密度计算等多个概念，进行多步骤的复杂计算，包括单位晶胞体积计算、原子质量求和、阿伏伽德罗常数应用等，最终还需要正确解方程并四舍五入得到整数解。这种综合性计算问题在选择题型中属于最复杂的类型之一。" + }, + { + "idx": 2839, + "question": "For a bcc crystal with a critical resolved shear stress of 60MPa on the (110)[111] slip system, how much stress must be applied in the [001] direction to initiate slip?", + "answer": "Vector dot product:\\n[001] direction:\\na⋅b=|a|⋅|b|cosθ⇒cosθ=(a⋅b)/(|a|⋅|b|)=(a1b1+a2b2+a3b3)/(√(a1²+a2²+a3²)⋅√(b1²+b2²+b3²))\\ncosλ=1/(1×√3)=1/√3,\\ncosφ=0/(1×√2)=0\\nσ=τt/(cosλcosφ)=60/((1/√3)×0)=∞,\\nTherefore, slip cannot be initiated in this direction no matter how much stress is applied.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，涉及向量点积和临界分切应力的计算，最终得出一个具体的数值结果（∞）。答案展示了详细的数学推导过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括向量点积、方向余弦计算和临界分切应力公式的应用。虽然不涉及复杂的综合分析或机理解释，但需要理解晶体滑移系统的基本原理，并能正确应用相关公式进行计算。 | 难度: 在选择题中属于高难度，需要深入理解晶体滑移系统的概念，进行多步骤的向量点积计算，并综合分析临界分切应力的应用。题目涉及复杂的多变量计算和概念关联，对学生的知识掌握深度和计算能力要求较高。" + }, + { + "idx": 3951, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 16h duration at 757^{\\circ} C will raise the carbon concentration to 0.5 wt% at a point 2.3mm from the surface. Estimate the time necessary to achieve the same concentration at a 8mm position for an identical steel and at a carburizing temperature of 1130^{\\circ} C. Assume that D_{0} is 4.6 × 10^{-5}{m}^{2} / s and Q_{d} is 104kJ / mol.", + "answer": "the time necessary to achieve the same concentration at a 8mm position for an identical steel and at a carburizing temperature of 1130^{\\circ} C is 17.9h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散方程和温度对扩散系数的影响，最终需要计算出一个具体的时间值（17.9h）。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散方程和温度对扩散系数的影响公式，并进行综合分析。虽然不涉及复杂的机理解释或创新设计，但需要一定的计算能力和对扩散过程的理解。 | 难度: 在选择题中属于高难度，需要综合运用扩散方程、温度对扩散系数的影响、以及时间与扩散距离的关系等多个概念进行多步骤计算。题目涉及复杂的多变量计算和综合分析，要求考生具备较强的材料科学基础和数学计算能力。" + }, + { + "idx": 193, + "question": "At 20°C, the saturated vapor pressure of water is 2338Pa, the density is 998.3 kg/m³, and the surface tension is 0.07275 N/m. What is the saturated vapor pressure of a water droplet with a radius of 10⁻⁹m at 20°C?", + "answer": "According to the formula ΔP = 2γ/Δ, we can calculate ΔP = 2 × 0.07275 / 10⁻⁹ = 1.455 × 10⁸ N/m². Based on the Kelvin equation ln(P/P₀) = 2(Mγ)/(ρRT)(1/r), simplified to ln(P/P₀) = (MΔP)/(ρRT), substituting the known conditions gives: ln(P/2338) = (18 × 10⁻³ × 1.455 × 10⁸)/(998.3 × 8.314 × 293) = 1.077. P = 6864Pa. Finally, the saturated vapor pressure P of a water droplet with a radius of 10⁻⁹m at 20°C is calculated to be 6864Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如Kelvin方程）来求解水滴的饱和蒸气压，答案给出了具体的计算过程和最终数值结果。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如Kelvin方程和表面张力的关系），需要综合分析已知条件并正确代入公式求解。虽然不涉及复杂的推理分析或创新应用，但超出了简单直接套用公式的范畴。 | 难度: 在选择题中属于高难度，题目涉及多步骤计算和多个物理概念的关联应用（如饱和蒸汽压、表面张力、开尔文方程等），需要综合运用公式推导和数值计算能力，解题过程复杂且对知识掌握深度要求较高。" + }, + { + "idx": 2351, + "question": "Iron carbide Fe3C is an orthorhombic intermetallic compound with lattice constants of a=0.4514nm, b=0.5080nm, c=0.6734nm, and a density of 7.65g/cm³. Determine the number of iron and carbon atoms in the unit cell.", + "answer": "From the appendix, the atomic masses of Fe and C are found to be 55.85g/mol and 12g/mol, respectively. The mass of each Fe and C atom is A_Fe = [55.85/(6.023×10^23)]g = 9.273×10^-23g, A_C = [12/(6.023×10^23)]g = 1.992×10^-23g. The atomic ratio of Fe to C is 3:1. Assuming there are n C atoms in the unit cell, there should be 3n Fe atoms. The density of Fe3C is ρ_Fe3C = (n × A_Fe + 3n × A_C) / V_unit cell. Therefore, 7.65 = [(9.273 × 3n + 1.992n) × 10^-23] / [0.4514 × 10^-7 × 0.5080 × 10^-7 × 0.6734 × 10^-7] = [29.811 × 10^-23 × n] / [1.544 × 10^-22]. Solving for n gives n = [7.65 × 1.544 × 10^-22] / [29.811 × 10^-23] = 3.97. Thus, there are 4 C atoms and 3 × 4 = 12 Fe atoms in the unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞中的铁和碳原子数量，解答过程中涉及到了密度、晶格常数、原子质量等参数的计算，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括原子质量的计算、密度公式的应用、单位换算以及解方程求解原子数量。虽然涉及的概念和公式较为基础，但需要将这些知识点综合运用，并进行适当的数值计算和逻辑推理，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。需要掌握晶体结构、密度计算、原子质量换算等多个知识点，并进行多步骤的综合计算。解题过程涉及单位换算、代数方程求解等复杂操作，且需要准确关联多个概念。相比其他选择题，该题的解题步骤和思维复杂度显著更高，因此属于最高难度等级。" + }, + { + "idx": 2258, + "question": "The following equation represents the change in the system's free energy caused by the formation of a crystal embryo containing $n$ atoms. $$ \\\\Delta G=-\\\\:b n\\\\left(\\\\Delta G_{V}-E_{\\\\mathrm{s}}\\\\right)+a n^{2/3}\\\\gamma_{\\\\upalpha/\\\\upbeta} $$ where $\\\\Delta G_{V}$ is the free energy change per unit volume of the crystal embryo; $\\\\gamma_{\\\\mathfrak{a}/\\\\mathfrak{g}}$ is the interfacial energy; $E_{\\\\mathrm{s}}$ is the strain energy; $a, b$ are coefficients whose values are determined by the shape of the crystal embryo. \\n\\nFind the values of $a$ and $b$ when the crystal embryo is spherical. If $\\\\Delta G_{V}, \\\\gamma_{\\\\scriptscriptstyle\\\\alpha/\\\\beta}, E_{s}$ are all constants, derive the nucleation energy $\\\\Delta G^{*}$ for a spherical nucleus.", + "answer": "If precipitation occurs simultaneously throughout the parent phase, and the composition of the parent phase changes continuously with the formation of the new phase, but the grain morphology and orientation remain unchanged, it is called continuous precipitation. \\n\\nIn contrast to continuous precipitation, when precipitation occurs, the solid solution within a certain surrounding range immediately changes from a supersaturated state to a saturated state, forming a distinct interface with the original composition of the parent phase. After nucleation at grain boundaries, it grows into the grain interior in an alternating lamellar distribution. Not only does the composition change abruptly at the interface, but the orientation also changes. This is discontinuous precipitation. The main difference lies in the length of the diffusion path. In the former, the diffusion field extends over a considerable distance, while in the latter, the diffusion distance is on the order of the lamellar spacing (generally less than $1~\\\\mu\\\\mathrm{m}$). \\n\\nDiscontinuous precipitation has the following characteristics: \\n\\n(1) At the interface between the precipitate and the matrix, the composition is discontinuous; the interfaces between the precipitate and the matrix are all high-angle incoherent interfaces, indicating that the crystal orientation is also discontinuous. (2) Cellular precipitates usually nucleate at the grain boundaries of the matrix $({\\\\alpha^{\\\\prime}})$ and always grow into one of the adjacent grains of the $\\\\alpha^{'}$ phase. (3) During the growth of cellular precipitates, the redistribution of solute atoms is achieved through interfacial diffusion between the precipitate and the parent phase, with the diffusion distance typically less than $1~\\\\mu\\\\mathrm{m}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过公式推导和计算来求解特定条件下的系数（a和b）以及成核能（ΔG*），这属于典型的计算题。答案部分虽然包含了一些概念解释，但核心要求是进行数学推导和计算。 | 知识层次: 题目要求推导球形晶核的成核能ΔG*，涉及多步计算和公式应用，需要理解自由能变化方程中各参数的含义及其相互关系，并进行适当的数学推导。虽然不涉及复杂的综合分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多变量计算和概念关联。需要理解自由能变化方程中的各项含义，并推导球形晶核的成核能。此外，还需要掌握连续和不连续析出的区别及其特征，综合分析多个概念和计算步骤。" + }, + { + "idx": 2461, + "question": "What is the ratio of nucleation rates between intragranular coherent disc-shaped nucleation and grain boundary incoherent double spherical cap-shaped nucleation? Given the grain diameter Π=10^-3 m, temperature T=1000 K, and Boltzmann constant k=1.38×10^-23 J/K.", + "answer": "The calculation process for the nucleation rate ratio I2/I1 is as follows: I2/I1 = (d/L)exp[-(ΔGb* - ΔG*)/kT] = (10^-9/10^-3)exp[-(2.615×10^-18 - 1.26×10^-18)/(1.38×10^-23×1000)] = 2.27×10^-49. The result shows that the nucleation rate for intragranular coherent nucleation is higher than that for grain boundary incoherent nucleation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种形核速率之比，答案中包含了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用公式进行数值计算，并理解不同形核机制的能量差异。虽然计算过程较为直接，但需要综合运用多个知识点，包括形核能垒、Boltzmann分布等，属于中等应用层次。 | 难度: 在选择题型内，该题目属于高难度等级。题目涉及复杂的多步骤计算过程，包括不同形核机制的激活能差计算、玻尔兹曼因子应用以及尺寸参数比值的综合运算。需要考生同时掌握形核理论、热力学公式转换和指数运算技巧，并能正确关联多个物理概念（如相干/非相干界面、晶界形核几何因子等）。这种在选择题中要求进行多变量复杂计算和概念深度整合的题目，显著高于常规选择题的认知负荷要求。" + }, + { + "idx": 2570, + "question": "Change the tension in the previous question to compression, and calculate the crystal orientation and shear strain", + "answer": "Using $A=a-\\textsf{v}(a\\cdot b)n,$, let $\\textsf{A}=\\textsf{[u0w]}$, we get $\\mathsf{A}=[2\\bar{1}3]-4\\lor[111]/\\surd6$. From this, it can be seen that $\\scriptstyle{\\boldsymbol{\\mathsf{u}}}=3$, $v=4$, $\\gamma=-\\sqrt{6/4}$, so the crystal orientation is [304], and the shear strain is - $\\surd6/4$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行晶体取向和剪切应变的计算，答案中包含了具体的数学运算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及晶体取向和剪切应变的计算，需要应用公式并进行综合分析。虽然题目给出了具体的计算步骤，但仍需要理解晶体学中的向量运算和应变计算，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及多步计算和复杂的概念关联。正确选项需要理解晶体取向和剪切应变的计算，并应用特定的公式进行推导。解题步骤包括变量替换、向量运算和数学推导，涉及多个知识点的综合应用。此外，题目还要求对计算结果进行解释，进一步增加了难度。在选择题型内，这种复杂多变量计算和综合分析的要求使得题目难度较高。" + }, + { + "idx": 2860, + "question": "Given that the yield strengths of pure iron with average grain diameters of $\\\\boldsymbol{1}\\\\mathfrak{mm}$ and $0.0625\\\\mathbf{mm}$ are 112.7MPa and 196$\\\\mathbf{MPa}$ respectively, what is the yield strength of pure iron with an average grain diameter of $0.0196\\\\mathrm{mm}$?", + "answer": "$$\\\\tau={\\\\frac{G b}{\\\\lambda}}={\\\\frac{G{\\\\frac{\\\\sqrt{3}}{2}}a}{\\\\lambda}}={\\\\frac{7.9\\\\times10^{19}\\\\times{\\\\frac{\\\\sqrt{3}}{2}}\\\\times0.28\\\\times10^{-9}}{41.2\\\\times10^{-6}}}=0.465(\\\\mathrm{MPa})$$\\n\\n$$\\\\left\\\\{\\\\begin{array}{l}{{112,7=\\\\sigma_{\\\\circ}+k(1\\\\times10^{\\\\circ})^{-\\\\frac{1}{2}},}}\\\\ {{}}\\\\ {{196=\\\\sigma_{\\\\circ}+k(0.0625\\\\times10^{\\\\circ})^{-\\\\frac{1}{2}}}}\\\\end{array}\\\\right.,$$\\n\\nThe solution is\\n\\n$$\\\\begin{array}{l}{{\\\\pmb{\\\\mathscr{s}}}_{\\\\mathscr{0}}=84,935(\\\\mathrm{MPa})}\\\\ {\\\\backslash_{\\\\pmb{\\\\mathscr{k}}}=0.878}\\\\end{array}$$\\n\\nTherefore, $\\\\sigma_{\\\\ast}=84.935+0.878(0.0196\\\\times10^{-3})^{-\\\\frac{2}{2}}=283.255(\\\\mathrm{MPa})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出一个具体的数值结果。答案中包含了详细的公式推导和计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括解方程组和公式应用，涉及Hall-Petch关系的理解和运用，需要一定的综合分析能力。 | 难度: 在选择题中属于高难度题目，需要理解Hall-Petch关系并进行多步计算。题目要求考生首先建立方程组求解材料常数，然后应用这些常数计算新的晶粒尺寸下的屈服强度。涉及对数运算、单位换算和复杂公式推导，对计算精度和概念理解要求很高。" + }, + { + "idx": 2096, + "question": "A eutectic reaction in the Mg-Ni system is given by $$ \\\\operatorname{L}_{w_{\\\\mathrm{Ni}}=0.235}\\\\frac{570^{\\\\circ}\\\\mathrm{C}}{\\\\Longleftarrow}\\\\alpha_{(\\\\#\\\\mathbb{M}_{\\\\operatorname{g}})}+\\\\mathrm{Mg}_{2}\\\\mathrm{Ni}_{w_{\\\\mathrm{Ni}}=0.546} $$ Let $\\\\omega_{\\\\mathrm{Ni}}^{1}=C_{1}$ be a hypoeutectic alloy and $\\\\boldsymbol{w_{\\\\mathrm{Ni}}^{2}}=C_{2}$ be a hypereutectic alloy. The mass fraction of the proeutectic phase in these two alloys is equal, but the total amount of $\\\\upalpha$ in alloy $\\\\mathrm{C}_{1}$ is 2.5 times that in alloy $\\\\mathrm{C}_{2}$. Calculate the compositions of $\\\\mathrm{C}_{1}$ and $\\\\mathrm{C}_{2}$.", + "answer": "The composition of alloy $C_{1}$ is $w_{\\\\mathrm{Mg}}=0.873$, $w_{\\\\mathrm{Ni}}=0.127$. The composition of alloy $\\\\mathrm{C}_{2}$ is $w_{\\\\mathrm{Mg}}=0.66,w_{\\\\mathrm{Ni}}=0.368$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定两种合金的组成，答案给出了具体的数值结果，解答过程需要运用相图分析和质量分数计算等材料科学中的计算方法。 | 知识层次: 题目涉及多步计算和概念关联，需要理解共晶反应的基本原理，并应用杠杆定律进行质量分数的计算。虽然不涉及复杂的推理分析或机理解释，但需要综合分析合金的成分与相组成之间的关系，并进行数值计算。 | 难度: 在选择题中属于高难度题目，需要深入理解共晶反应、相图分析、质量分数计算等多个材料科学核心概念。题目涉及多变量计算（C1和C2合金的成分计算）、多步骤推理（通过质量分数相等和α相总量关系建立方程组），以及综合分析能力（将相图信息与数学计算相结合）。这些要求明显超出了选择题型的常规难度水平，需要考生具备较强的应用能力和计算技巧。" + }, + { + "idx": 2741, + "question": "It is known that liquid pure nickel undergoes homogeneous nucleation at an undercooling of 319°C under 1.013×10^5 Pa (1 atm). Given the critical nucleus radius as 1 nm, the melting point of pure nickel as 1726 K, the heat of fusion Lm = 18075 J/mol, and the molar volume V = 6.6 cm^3/mol, calculate the liquid-solid interfacial energy and the critical nucleation work for pure nickel.", + "answer": "Since r* = 2σ/ΔGv = 2σTm/LmΔT = 2σTm V/ΔHmΔT, and for solidification, ΔGv = LmΔT/Tm, thus σ = r*ΔGv/2V = r*ΔHmΔT/2VTm = 1×10^-7 × 18075 × 319 / 2 × 1726 × 6.6 = 2.53×10^-5 (J/cm^2) = 0.253 (J/m^2). ΔG* = 16πσ^3Tm^2Vs^2 / 3ΔHm^2ΔT^2 = 16 × 3.14 × (2.53×10^-5)^3 × 1726^2 × 6.6^2 / 3 × 18075^2 × 319^2 = 1.06×10^-18 (J).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及多个物理量的计算和推导，最终需要得出具体的数值结果。答案中展示了详细的公式应用和计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个公式的应用和概念关联，如临界核半径、熔化热、摩尔体积等，需要综合分析并正确代入数值进行计算。虽然不涉及复杂的推理分析或机理解释，但计算过程较为复杂，超出了简单应用的范围。 | 难度: 在选择题中属于高难度题目，需要综合运用多个热力学和材料科学概念（如均相成核、临界核半径、界面能等），并进行多步骤的复杂计算。题目涉及多个变量的转换和单位统一（如J/cm²到J/m²的转换），且需要正确应用公式推导过程。这种题目在选择题型中属于需要深度理解和较强计算能力的类型，远超基础概念题和简单计算题的难度水平。" + }, + { + "idx": 2197, + "question": "Given that the recovery activation energy of a zinc single crystal is $20000\\\\mathrm{J/mol}$, removing $2\\\\%$ of the work hardening at $50^{\\\\circ}\\\\mathrm{C}$ requires $13\\\\textup{d}$; how much should the temperature be increased to remove the same amount of work hardening in $5\\\\textrm{min}$?", + "answer": "When cold-plastically deformed metal undergoes recovery, if the recovery amount $R$ (in this case, the removed portion of work hardening) is constant, the relationship between the required recovery time $t$ and the recovery temperature $T$ can be expressed as $$ \\\\ln t=a+{\\\\frac{Q}{R}}{\\\\frac{1}{T}}$$ where $a$ is a constant; $\\\\boldsymbol{Q}$ is the recovery activation energy. Accordingly, we have $$ \\\\frac{t_{1}}{t_{2}}=\\\\exp\\\\biggl[-\\\\frac{Q}{R}\\\\Bigl(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}}\\\\Bigr)\\\\biggr]$$ From the problem statement, $$ T_{2}=-50^{\\\\circ}C=223\\\\mathrm{~K~}$$ $$ t_{2}=13~\\\\mathrm{d}=18~500~\\\\mathrm{min},\\\\quad Q=20~000~\\\\mathrm{J/mol}$$ When $t_{1}=5\\\\mathrm{min}$ is required, then $$ {\\\\frac{5}{18500}}{=}\\\\exp\\\\Bigl[-{\\\\frac{20000}{2}}\\\\Bigl({\\\\frac{1}{223}}-{\\\\frac{1}{T_{1}}}\\\\Bigr)\\\\Bigr]$$ $$ {\\\\frac{1}{T_{1}}}={\\\\frac{1}{223}}-{\\\\frac{\\\\ln3700}{10000}}$$ Therefore, the recovery temperature $$ T_{1}=273\\\\mathrm{~K~}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及激活能、温度和时间的关系，最终要求计算出一个具体的温度值。解答过程中使用了数学公式和代数运算，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解恢复激活能的概念，并能够将时间、温度与激活能之间的关系进行综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的计算能力和概念关联能力。 | 难度: 在选择题型中，这道题目属于高难度等级。题目涉及多个复杂步骤和概念的综合运用，包括：" + }, + { + "idx": 2903, + "question": "The crystallization activation energy of amorphous alloys can be determined using the Ozawa plotting method, which utilizes the linear relationship between the crystallization temperature $\\scriptstyle{\\mathcal{T}}_{\\mathbf{z}}$ and the heating rate $^{a}$ measured under different continuous heating conditions. The $\\pmb{T_{x}}$ values for the pre-crystallization phase $\\alpha{\\boldsymbol{-}}\\mathbf{\\overline{{F}}}\\mathbf{e}$ of the amorphous FenBsSis alloy have been measured as shown in the table below. Calculate the activation energy.", + "answer": "Based on the data in the table, plot the graph (see Figure 42), which approximates a straight line. Using the least squares method, the equations of the straight lines are fitted as follows: \\n$$\\n\\\\ln{\\\\frac{T_{x}}{a}}={\\\\frac{46}{T_{x}}}-53\\n$$\\n$$\\n\\\\ln{\\\\frac{T_{x}}{a}}={\\\\frac{49}{T_{x}}}-57\\n$$\\nFrom the slope of the straight lines, the activation energy for the precipitation stage of the ${\\\\mathfrak{a}}{\\\\mathfrak{F}}{\\\\mathfrak{e}}$ pre-crystallization phase is determined to be $(382\\\\sim407)\\\\mathrm{kJ/mol}_{\\\\circ}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的数据和公式进行数值计算，最终得出激活能的数值。解答过程中涉及绘制图表、拟合直线方程和从斜率中确定激活能，这些都是典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括绘制图表、拟合直线方程，并通过斜率计算激活能量。这涉及到对Ozawa绘图法的理解和应用，以及对实验数据的综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于高难度，题目涉及多步骤计算和概念关联，需要综合分析表格数据、绘制图形、拟合直线方程，并通过斜率计算激活能量。解题过程复杂，涉及多个变量和计算步骤，对知识掌握深度和计算能力要求较高。" + }, + { + "idx": 2511, + "question": "Derive the conversion formula between the lattice constant $\\\\mathfrak{a}_{R}$ in rhombohedral axes and the lattice constant $\\\\pmb{\\\\complement H}$ in hexagonal axes for a rhombohedral crystal.", + "answer": "In $\\\\pmb{a}_{\\\\sf H}$, $b_H$, $\\\\pmb{\\\\mathbb{G H}}$, $a_{R}=1/s$ [1 1], so the lattice constant $a_{R}=\\\\mathsf{L}$ $\\\\begin{array}{r l}&{=\\\\mathsf{a_{H}}\\\\bullet\\\\mathsf{s q r t}(\\\\mathsf{U}^{2}+\\\\mathsf{V}^{2}+\\\\mathsf{W}^{2}\\\\mathsf{c_{H}}^{2}/\\\\mathsf{a_{H}}^{2}-\\\\mathsf{U V})}\\\\ &{=\\\\V_{3}\\\\vee(3\\\\mathsf{a_{H}}^{2}+\\\\mathsf{c_{H}}^{2}),}\\\\end{array}$ Also, since ${\\\\pmb{\\\\upalpha}}_{\\\\aleph}$ is the angle between the crystallographic directions $\\\\%$ [1 1] and $\\\\%$ [121], the lattice constant $\\\\texttt{a}_{\\\\texttt{R}}$ $\\\\begin{array}{r l}{=\\\\mathsf{a r c o s}(c_{\\\\mathsf{G}_{\\\\mathsf{H}}}{}^{2}/\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2}{}-3/2)/(3+\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}/\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2})}\\\\ {=\\\\mathsf{a r c o s}(}&{(2\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}{}-3\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2})/(6\\\\mathsf{a}_{\\\\mathsf{H}}{}^{2}+2\\\\mathsf{c}_{\\\\mathsf{H}}{}^{2}))\\\\circ}\\\\end{array}$ ) gives $a_H = a_R\\\\cdot\\\\sqrt{2(1-\\\\cos\\\\alpha)}$; $c_{H}=a_{R}\\\\cdot\\\\mathsf{s q r t}(3(1+2\\\\cos\\\\theta)\\\\circ$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导晶格常数之间的转换公式，涉及数学推导和公式应用，答案中包含了具体的数学表达式和计算步骤，符合计算题的特征。 | 知识层次: 题目要求推导晶格常数在菱方和六方坐标系之间的转换公式，涉及多步计算和概念关联，需要综合分析不同坐标系之间的关系，并应用相关数学和晶体学知识。虽然不涉及复杂的机理或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题型内，该题目属于高难度等级。题目涉及复杂的多步计算和概念关联，需要深入理解晶格常数在菱方和六方坐标系之间的转换关系。解题过程不仅需要掌握基本的晶体学知识，还需要进行多变量计算和综合分析，包括向量运算、三角函数转换等高级数学操作。这些要求超出了选择题型中常见的简单概念识别或单步计算，属于复杂多变量计算范畴。" + }, + { + "idx": 2364, + "question": "The copolymer contains PVC (polyvinyl chloride — $T_{2}H_{2}C-1-$) and PVA (polyvinyl alcohol —CHO—). The mass fraction of PVC is $1\\\\Psi_{\\\\mathrm{W}_{\\\\mathrm{E}}}=\\\\mathrm{B},5\\\\Psi_{\\\\mathrm{W}}$, and the mass fraction of PVA is $14^{\\\\circ}=15^{\\\\circ}$. Determine the mole fractions of PVC and PVA.", + "answer": "First, calculate the molar masses of PVC and PVA. The relative atomic mass of C is 12.0I, $\\\\mathsf{H}$ is 1.008, Cl is 35.45, and O is $16.00$. The molar mass of PVC is $(2\\\\times12+3\\\\times1+35.45)\\\\underline{{{\\\\mathrm{g}}}}/110|=62.45\\\\underline{{{\\\\mathrm{g}}}}/1101$. The molar mass of PVA is $(4\\\\times12+6\\\\times1+2\\\\times16)\\\\mathrm{g/mol}=86\\\\mathrm{g/mol}$. In $100\\\\underline{{\\\\underline{{\\\\mathbf{I}}}}}$ of the polymer, there are $85/62,45=1,36\\\\mathrm{PVC}$ moles and $15:80=0.174$ PVA moles. Therefore, the mole fraction of PVC in the polymer, Ac, and the mole fraction of PVC, $f^{\\\\prime}(x)$, are: $$ f_{\\\\mathrm{vc}}={\\\\frac{1.36}{1.36+0.174}}=0.887\\\\qquadf_{\\\\mathrm{vA}}={\\\\frac{0.174}{1.36+0.174}}=0.113$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算确定PVC和PVA的摩尔分数，涉及摩尔质量的计算和摩尔分数的推导，答案展示了具体的计算步骤和结果。 | 知识层次: 题目涉及多步计算，包括摩尔质量的计算、质量分数到摩尔分数的转换，以及最终的摩尔分数计算。虽然不涉及复杂的推理或综合分析，但需要理解和应用多个概念，并进行关联计算。 | 难度: 在选择题型中，该题目属于高难度等级。题目涉及多步计算过程，包括摩尔质量的计算、质量分数与摩尔分数的转换，以及最终的分数计算。此外，题目还要求对高分子化学中的基本概念有深入理解，如共聚物的组成和摩尔分数的定义。这些步骤和概念的综合运用使得该题目在选择题型中显得较为复杂和具有挑战性。" + }, + { + "idx": 2596, + "question": "Derive the elastic energy formula for a mixed dislocation.", + "answer": "$\\\\begin{array}{r l}&{\\\\mathsf{E}=\\\\mathsf{E}_{\\\\mathsf{o}1}\\\\left(\\\\mathcal{V}\\\\right)+\\\\mathsf{E}_{\\\\mathsf{e}1}\\\\left(\\\\frac{\\\\mathsf{i}\\\\mathcal{R}}{\\\\mathsf{s}\\\\mathsf{t}_{\\\\mathrm{A}}}\\\\right)=\\\\mathsf{G b}^{2}|\\\\mathsf{s}\\\\mathsf{i n}^{2}\\\\mathsf{a}\\\\star|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)/\\\\left[4\\\\pi\\\\left(1-\\\\upsilon\\\\right)\\\\right]+\\\\mathsf{G b}^{2}|\\\\mathsf{c o s}^{2}\\\\mathsf{a}\\\\star|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)}\\\\ &{\\\\mathrm{~\\\\ensuremath~{\\\\left/~\\\\left(4\\\\pi\\\\right)~\\\\tau~=~\\\\mathsf{Gb}^2|\\\\tau~\\\\left(1-\\\\upsilon\\\\cos^2\\\\theta\\\\right)~\\\\cdot~|\\\\mathsf{n}\\\\left(\\\\mathsf{R}/\\\\mathsf{r}_{0}\\\\right)~\\\\middle/~\\\\left[4\\\\pi\\\\left(1-\\\\upsilon\\\\right)\\\\right]~\\\\right.~}}\\\\end{array}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导混合位错的弹性能量公式，涉及复杂的数学推导和公式应用，答案呈现为详细的数学表达式和推导过程，符合计算题的特征。 | 知识层次: 题目要求推导混合位错的弹性能量公式，涉及多步计算和概念关联，需要理解位错的基本性质、弹性理论的应用以及数学推导能力。虽然不涉及复杂的综合分析或创新应用，但比简单应用更复杂，需要中等程度的认知能力和知识点的关联。 | 难度: 在选择题型中，该题目属于复杂多变量计算问题。正确选项涉及弹性力学中的混合位错能量公式推导，需要掌握剪切模量(G)、伯格斯矢量(b)、泊松比(ν)等多个变量的相互作用关系。题目要求考生能够理解并应用位错能量分解为刃型分量和螺型分量的概念，进行三角函数转换和综合计算。在选择题型中，这种需要同时处理多个物理概念和数学变换的题目属于最高难度等级。" + }, + { + "idx": 2729, + "question": "Given that the lattice constant of a $\\\\mathrm{\\\\hat{Cu}}$ crystal is $a=0.35\\\\mathrm{nm}$, the shear modulus $G=4\\\\times10^{4}MPa$, and there is a dislocation with Burgers vector $\\\\pmb{\\\\mathscr{b}}==\\\\frac{a}{2}[\\\\overline{{1}}01]$, where the dislocation line direction is [-101], calculate the strain energy of this dislocation.", + "answer": "Based on the relationship between the Burgers vector and the dislocation line, it is known that this dislocation is a screw dislocation, and its strain energy is $$ \\\\begin{array}{r}{E=\\\\frac{G b^{2}}{4\\\\pi}\\\\mathrm{ln}\\\\frac{{R}}{r_{\\\\mathrm{0}}}}\\\\end{array}$$ $r_{0}\\\\approx b-{\\\\frac{\\\\sqrt{2}}{2}}a=0.707\\\\times0.35\\\\times10^{-6}=2.475\\\\times10^{-10}({\\\\mathrm{m}})$ $R{\\\\approx}1\\\\times10~^{\\\\circ}\\\\mathrm{m}$ $E={\\\\frac{4\\\\times10^{10}\\\\times(2.475\\\\times10^{-16})^{2}}{4\\\\pi}}\\\\ln{\\\\frac{10^{-2}}{2.475\\\\times10^{-10}}}=3.415\\\\times10^{-9}(\\\\mathrm{N}\\\\cdot\\\\mathrm{m}/\\\\mathrm{m})$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解位错的应变能，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括确定位错类型、计算应变能公式中的各项参数，并进行数值计算。虽然涉及的知识点较为基础，但需要综合运用位错理论和弹性力学的基本原理，属于中等应用层次。 | 难度: 在选择题中属于高难度，需要深入理解位错理论、Burgers向量与位错线的关系，并进行多步复杂计算，包括对数运算和单位转换。题目要求综合应用材料力学和晶体学知识，涉及多个变量和公式推导，对学生的分析能力和计算精度要求较高。" + }, + { + "idx": 2247, + "question": "During solid-state phase transformation, assuming the new phase nucleus is spherical and the volume free energy change per atom ΔGv=200ΔT/Tc (J/cm³), the critical transformation temperature Tc=1000K, the strain energy Es=4 J/cm³, the coherent interface energy γ_coherent=40×10⁻⁷ J/cm², and the incoherent interface energy γ_incoherent=400×10⁻⁷ J/cm², calculate ΔT when ΔG_coherent* = ΔG_incoherent*.", + "answer": "Let ΔG_coherent* = ΔG_incoherent*, then (40×10⁻⁷)³ / (200×ΔT/1000 - 4)² = (400×10⁻⁷)³ / (200×ΔT/1000)². Solving gives ΔT ≈ 21K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解ΔT的值，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相变过程中的能量变化，并应用临界形核功的公式进行推导和计算。虽然不涉及复杂的机理分析或创新设计，但需要综合分析多个参数之间的关系，并进行适当的数学处理。 | 难度: 在选择题型内，该题目属于复杂多变量计算问题。题目要求考生理解固态相变中的多个关键概念（如体积自由能变化、应变能、共格与非共格界面能），并建立它们之间的数学关系。解题过程涉及多个步骤的代数运算和方程求解，包括设定方程、代入数值、解方程等。此外，题目还要求考生能够综合应用这些概念来比较共格和非共格形核的临界条件。这种综合性和复杂性在选择题型中属于较高难度，因此评估为等级4。" + }, + { + "idx": 2276, + "question": "Please derive the rule of mixtures for the longitudinal elastic modulus of a fiberglass composite fishing rod (composed of longitudinally aligned glass fibers and polyester resin as the bonding fiber).", + "answer": "The derivation assumes that the two constituent materials have the same Poisson's ratio, and the transverse strain is negligible. Under longitudinal loading, the strains of the two components must be equal, i.e., $$ {\\\\varepsilon}_{\\\\mathfrak{g}1}={\\\\varepsilon}_{\\\\mathfrak{m}}={\\\\varepsilon}_{\\\\mathfrak{p}\\\\mathfrak{r}}$$ $$ {\\\\frac{F/f_{\\\\mathrm{^{gl}}}}{E_{\\\\mathrm{gl}}}}={\\\\frac{F/A}{E_{\\\\mathrm{m}}}}={\\\\frac{F/f_{\\\\mathrm{pr}}}{E_{\\\\mathrm{pr}}}}$$ where $E_{\\\\mathrm{m}}$ is the elastic modulus of the mixture; $_{\\\\mathrm{g1}}$ represents glass fiber; pr represents resin fiber; $A$ is the total cross-sectional area (can be considered as 1), and $f$ is the cross-sectional area (or volume) fraction of different materials. Then, $$ \\\\begin{array}{c}{F_{\\\\mathrm{g1}}=\\\\frac{f_{\\\\mathrm{g1}}E_{\\\\mathrm{g1}}F}{E_{\\\\mathrm{m}}}}\\\\\\\\ {F_{\\\\mathrm{pr}}=\\\\frac{f_{\\\\mathrm{pr}}E_{\\\\mathrm{pr}}F}{E_{\\\\mathrm{m}}}}\\\\end{array}$$ Since $F=F_{\\\\mathrm{gl}}+F_{\\\\mathrm{pr}}$, it follows that $$ F=\\\\frac{(f_{\\\\mathrm{gl}}E_{\\\\mathrm{gl}}+f_{\\\\mathrm{pr}}+E_{\\\\mathrm{pr}})F}{E_{\\\\mathrm{m}}}$$ $$ E_{\\\\mathrm{m}}=f_{\\\\mathrm{g1}}E_{\\\\mathrm{g1}}+f_{\\\\mathrm{pr}}E_{\\\\mathrm{pr}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导纤维增强复合材料纵向弹性模量的混合规则，涉及公式推导和数学运算，答案展示了详细的推导过程和最终公式，属于需要数值计算和公式应用的计算题。 | 知识层次: 题目需要多步计算和概念关联，涉及复合材料弹性模量的混合规则推导，需要理解应变相等假设和体积分数的应用，并进行公式推导和综合。虽然不涉及复杂的机理分析或创新设计，但超出了简单套用公式的范畴。 | 难度: 在选择题型中，该题目属于高难度级别。题目要求推导纤维增强复合材料纵向弹性模量的混合规则，涉及多个概念的综合运用和复杂的多步计算。具体来说，题目需要考生理解并应用以下内容：" + }, + { + "idx": 2464, + "question": "Given that the shear moduli G of the parent phase and the precipitate phase are the same, and the parent phase is an isotropic continuous medium. If a coherent nucleus forms, derive the expression for the size at which the disc-shaped nucleus loses coherence during growth.", + "answer": "For a disc-shaped nucleus, let the radius be r and the thickness be t. Before coherence is lost, the sum of the misfit strain energy and the interfacial energy is πr^2t×4Gδ^2+2πr^2γ_ci0+2πrtγ_in. After coherence is lost, there is no misfit strain energy, and the disc interface changes from coherent to incoherent, so the energy becomes 2πr^2γ_in+2πrtγ_in. At the critical size, the energies of coherent and incoherent states should be equal, i.e., πr^2t*×4Gδ^2+2πr^2γ_ci0+2πrt*γ_in=2πr^2γ_in+2πrt*γ_in. Solving gives t*=(γ_in−γ_ci0)/(2Gδ^2).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导一个表达式，涉及公式应用和数值计算，最终给出一个具体的解。答案展示了详细的推导过程和最终的数学表达式，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相干与非相干界面的能量变化，并推导临界尺寸的表达式。虽然不涉及复杂的综合分析或创新应用，但需要一定的推理和计算能力。 | 难度: 在选择题中属于高难度，需要理解多个复杂概念（如剪切模量、相干性、应变能等），进行多步骤计算（能量平衡方程的建立与求解），并综合分析临界尺寸的物理意义。题目涉及多变量计算和概念关联，对材料科学基础知识的掌握深度要求较高。" + }, + { + "idx": 2245, + "question": "Using classical nucleation theory, calculate the shape factor η of a new phase when a cubic nucleus is formed by $n$ atoms during a solid-state phase transformation.", + "answer": "According to classical nucleation theory, during a solid-state phase transformation, the change in the system's free energy is given by $$ \\\\Delta G=n\\\\Delta G_{V}+S\\\\gamma+n E_{s}$$ where $\\\\Delta G_{V}$ is the free energy difference per atom between the old and new phases; S is the surface area of the nucleus; $\\\\gamma$ is the average surface energy; $E_{s}$ is the strain energy per atom in the nucleus; $n$ is the number of atoms in the nucleus. Assuming the density of the new phase is $\\\\rho$ and the relative atomic mass is $M,$ the volume occupied per gram-atom of the new phase material is $M/\\\\rho;$ the volume occupied per atom of the new phase is $M/(\\\\rho N_{0});$ the volume of a nucleus with $n$ atoms is $n M/(\\\\rho N_{0})$. If a cubic nucleus is formed, its edge length is $(n M/(\\\\rho N_{\\\\circ}))^{1/3}$, and the surface area of the nucleus is $6(n M/(\\\\rho N_{\\\\circ}))^{2/3}$. Thus, the shape factor $$\\\\eta=(M/(\\\\rho N_{\\\\circ}))^{2/3}$$ and the free energy change is $$ \\\\Delta G=n\\\\Delta G_{V}+6(M/(\\\\rho N_{\\\\L_{0}}))^{2/3}n^{2/3}\\\\gamma+n E_{s}$$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求使用经典成核理论计算立方核的形状因子η，涉及多个公式推导和数值计算步骤，答案呈现了详细的计算过程和最终公式结果。 | 知识层次: 题目需要应用经典成核理论进行多步计算，涉及自由能变化、表面能、应变能等多个概念的关联和综合分析。虽然不需要复杂的推理分析或创新应用，但需要理解和应用多个公式，并进行适当的数学推导和计算。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和多个概念的关联应用。需要理解经典成核理论、自由能变化公式、立方核的形成、体积和表面积的计算，以及形状因子的推导。此外，还需要对原子体积、密度、相对原子质量等概念有深入理解，并能将这些概念综合运用到具体计算中。这种题目不仅要求考生掌握相关理论知识，还需要具备较强的数学推导和综合分析能力。" + }, + { + "idx": 2308, + "question": "Parameters of short fiber composite: $\\\\varphi_{\\\\mathrm{f}}=0.4$, $d_{\\\\mathrm{t}}=25\\\\mu\\\\mathrm{m}$, $\\\\sigma_{\\\\mathrm{{\\\\scriptscriptstyle M}}}=2500\\\\mathrm{MPa}$, $\\\\sigma_{\\\\mathfrak{m u}}=275~\\\\mathrm{MPa}$, and the interfacial shear strength between fiber and matrix is $200\\\\mathrm{MPa}$. Assuming the fiber stress varies linearly at both ends of the fiber, approximately estimate the strength of the randomly oriented short fiber composite when the fiber length is $1~\\\\mathrm{mm}$.", + "answer": "Since the fiber fracture strain and the stress-strain curve of the matrix are not given, it is difficult to determine $\\\\sigma_{\\\\mathrm{m}}^{*}$. Thus, $\\\\sigma_{\\\\mathrm{mu}}$ is used to approximate $\\\\sigma_{\\\\mathrm{m}}^{*}$, and $200\\\\mathrm{MPa}$ is used to approximate $\\\\tau_{y}$. First, calculate $L_{\\\\mathrm{c}}$: $$ $$ $\\\\sigma_{\\\\mathrm{cu}}=\\\\Big(1-\\\\frac{L_{\\\\mathrm{c}}}{2L}\\\\Big)\\\\sigma_{\\\\mathrm{fu}}\\\\varphi_{\\\\mathrm{f}}+\\\\sigma_{\\\\mathrm{m}}^{*}(1-\\\\varphi_{\\\\mathrm{f}})=$ $$ $\\\\left(1-\\\\frac{156.25\\\\times10^{-6}\\\\mathrm{m}}{2\\\\times1.0\\\\times10^{-3}\\\\mathrm{m}}\\\\right)\\\\times2~500~\\\\mathrm{MPa}\\\\times0.4+275~\\\\mathrm{MPa}\\\\times0.6=1~087~\\\\mathrm{MPa}$ The strength of the randomly oriented short fiber composite is approximately $\\\\mathrm{~1~}087\\\\mathrm{~MPa}$. $L_{\\\\mathrm{{c}}}={\\\\frac{d_{\\\\mathrm{{t}}}\\\\sigma_{\\\\mathrm{{fu}}}}{2\\\\tau_{\\\\mathrm{{y}}}}}\\\\approx{\\\\frac{25\\\\times10^{-6}~{\\\\mathrm{m}}\\\\times2~500~{\\\\mathrm{MPa}}}{2\\\\times200~{\\\\mathrm{MPa}}}}=156.25\\\\times10^{-6}~{\\\\mathrm{m}}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估算随机取向短纤维复合材料的强度，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算临界纤维长度（Lc）并应用复合材料的强度公式，同时需要理解纤维和基体的应力分布以及界面剪切强度的作用。虽然不涉及复杂的机理分析或创新设计，但需要综合应用多个概念和公式进行中等难度的计算。 | 难度: 在选择题中属于高难度，题目涉及多步复杂计算和多个材料参数的关联分析。需要计算临界纤维长度（Lc），并应用复合材料的强度公式进行综合计算。此外，题目还要求对未给定的参数进行合理近似（如用σmu近似σm*），这增加了题目的复杂性和对概念理解的深度要求。在选择题型中，这种需要多变量处理和综合判断的题目属于较高难度等级。" + }, + { + "idx": 2456, + "question": "For the allotropic transformation of pure metal $(x\\\\rightarrow\\\\beta)$, at a certain degree of undercooling, the volume Gibbs free energy difference between the two phases is $7\\\\times10^{8} kJ/m^{3}$, and the interfacial energy is $0.5 J/m^{2}$. If the strain energy of nucleation is neglected, calculate the critical nucleus size and the critical nucleation energy for the formation of a disk-shaped nucleus with a diameter $(D)$ to thickness $(1)$ ratio $(D//)$ of 20.", + "answer": "For the disk-shaped nucleus, the critical nucleus diameter $D^{*}=-\\\\frac{88}{3}\\\\frac{\\\\gamma}{\\\\Delta G_{V}}=\\\\frac{88\\\\times0.6}{3\\\\times7\\\\times10^{8}}m=2.514\\\\times10^{-8}m$. The critical nucleation energy is $\\\\Delta G^{*}=[-\\\\frac{\\\\pi}{80}\\\\times(2.514\\\\times10^{-8})^{3}\\\\times7\\\\times10^{8}+\\\\frac{11\\\\pi}{20}\\\\times(2.514\\\\times10^{-8})^{2}\\\\times0.6]J=2.184\\\\times10^{-16}J$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及临界核尺寸和临界成核能量的具体计算过程，答案也以数值结果呈现。 | 知识层次: 题目涉及多步计算和公式应用，需要理解临界核尺寸和临界成核能量的概念，并能够正确应用相关公式进行计算。虽然题目提供了具体的数值和公式，但需要综合运用这些信息进行求解，属于中等应用层次。 | 难度: 在选择题中属于高难度，题目涉及多步复杂计算和多个概念的关联应用。需要计算临界核尺寸和临界成核能，涉及体积吉布斯自由能差、界面能等参数的代入和转换，且计算步骤繁琐，容易出错。此外，题目还要求对盘状核的形状比进行考虑，增加了复杂性。" + }, + { + "idx": 2736, + "question": "The lattice constant of a copper single crystal is $a=0.36\\\\mathfrak{n m}$. When the copper single crystal sample is subjected to tensile deformation at a constant strain rate, the true strain of the sample is $6\\\\%$ after $\\\\mathtt{3s}$. If the average velocity of dislocation motion is $4\\\\times10^{-3}~\\\\mathrm{cm/s}$, calculate the average dislocation density in the crystal.", + "answer": "① The two nodes in the dislocation network and the dislocation segments between them can act as F-R sources, and the shear stress required for dislocation multiplication is the minimum shear stress required to activate the F-R source; $$ D=\\\\frac{G b}{\\\\tau}$$ ② $$ D=\\\\frac{G b}{\\\\tau}=\\\\frac{G b}{\\\\frac{G}{100}}=100b=100~\\\\frac{\\\\sqrt{2}}{2}a=25.5\\\\left(\\\\mathrm{nm}\\\\right)$$ ③ For a three-dimensional dislocation network $$ \\\\rho={\\\\frac{2}{D^{2}}}=2\\\\left({\\\\frac{\\\\tau}{G b}}\\\\right)^{2}=2\\\\left({\\\\frac{42\\\\times10^{6}}{50\\\\times10^{8}\\\\times2.55\\\\times10^{-8}}}\\\\right)^{2}=2.17\\\\times10^{9}{\\\\mathrm{cm}}^{-2}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解平均位错密度，答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括使用Frank-Read源公式、剪切应力计算、位错密度公式等，涉及多个概念的综合应用和数值计算，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于高难度，题目涉及多步计算和多个概念的关联应用。需要理解晶格常数、应变率、位错运动速度等概念，并进行复杂的数学推导和计算。此外，题目还要求综合分析位错密度与剪切应力、弹性模量等参数的关系，涉及多变量计算和物理概念的深入理解。" + }, + { + "idx": 2868, + "question": "Based on the equation $t_{0.95}=\\\\left[\\\\frac{2.85}{\\\\dot{N}G^{3}}\\\\right]^{\\\\frac{1}{4}}$, derive the functional relationship between the recrystallization temperature $T_{R}$ and $G_{0},N_{0},Q_{g}$ and $Q_{n}$.", + "answer": "$t_{0.95}=\\\\Big[\\\\frac{2.85}{\\\\tilde{N}\\\\bar{G}^{3}}\\\\Big]^{\\\\frac{1}{4}}=\\\\Big[\\\\frac{2.85}{N_{0}G_{0}^{3}}\\\\Big]^{\\\\frac{1}{4}}\\\\:\\\\mathrm{exp}\\\\Big(\\\\frac{Q_{n}+3Q_{\\\\ell}}{4k T}\\\\Big)$. Substituting $T=T_{\\\\parallel}\\\\circ\\\\mathcal{t}_{0,85}=1$, we get $$\\\\exp\\\\Big(\\\\frac{Q_{n}+3Q_{s}}{4k T_{\\\\mathrm{R}}}\\\\Big)=\\\\Big[\\\\frac{2,85}{N_{0}G_{0}^{3}}\\\\Big]^{-\\\\frac{1}{4}},\\\\frac{Q_{n}+3Q_{\\\\mathrm{g}}}{4k T_{\\\\mathrm{R}}}=-\\\\frac{1}{4}\\\\ln\\\\frac{2.85}{N_{0}G_{0}^{3}},$$ Therefore, $T_{\\\\mathbb{R}}=-\\\\frac{Q_{n}+3Q_{g}}{k\\\\ln\\\\Bigl(\\\\frac{2.85}{N_{0}G_{0}^{3}}\\\\Bigr)}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于给定的方程推导出再结晶温度与其他变量之间的函数关系，解答过程涉及公式变换和数学推导，最终得出一个具体的表达式，符合计算题的特征。 | 知识层次: 题目需要多步计算和公式推导，涉及多个变量（G0, N0, Qg, Qn）的关联和综合分析，要求对再结晶温度与这些参数之间的函数关系有较深的理解和应用能力。虽然不涉及复杂的机理分析或创新设计，但已超出简单应用的范围。 | 难度: 在选择题中属于高难度，需要理解复杂的多变量关系并进行多步推导计算。题目涉及多个变量（G0, N0, Qg, Qn）的相互作用，要求考生能够综合运用材料科学中的再结晶理论、Arrhenius方程和对数运算等知识。解题步骤包括指数转换、对数运算和代数重组，且需要准确理解物理意义与数学表达式的对应关系。这种复杂度和深度在选择题型中属于最高难度级别。" + }, + { + "idx": 2740, + "question": "To achieve homogeneous nucleation at 2045K, by how much must the atmospheric pressure be increased? Given the volume change during solidification ΔV= -0.26 cm^3/mol (1J=9.87×10^6 cm^3·Pa)", + "answer": "For homogeneous nucleation to occur at 1726K, an undercooling of 319°C is required. To achieve this, the pressure must be increased to raise the solidification temperature of pure nickel from 1726K to 2045K: dP/dT=ΔH/TΔV. Integrating this equation: ∫1.013×10^5^P dP=∫1726^2045 ΔH/TΔV dT P-1.013×10^5=ΔH/ΔV ln2045/1726=18075/0.26×9.87×10^5×ln2045/1726=116366×10^5(Pa). Thus, when P=116366×10^5-1.013×10^5=116365×10^5(Pa), homogeneous nucleation can occur at 2045K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如dP/dT=ΔH/TΔV的积分计算）来确定需要增加的大气压力值，最终给出具体的数值结果。这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括公式应用和积分运算，同时需要理解相变热力学中的Clausius-Clapeyron方程及其在凝固过程中的应用。虽然涉及一定的综合分析，但整体上仍属于中等难度的应用题目。 | 难度: 在选择题中属于高难度，题目涉及多步骤的复杂计算和概念的综合应用。需要理解并应用热力学公式（dP/dT=ΔH/TΔV），进行积分计算，同时处理单位转换（1J=9.87×10^6 cm^3·Pa）。此外，还需要综合分析温度变化对压力需求的影响，并进行精确的对数运算。这些步骤在选择题型中属于较高层次的认知要求，需要较强的计算能力和概念关联能力。" + }, + { + "idx": 2506, + "question": "Derive the conversion formula between the lattice constant $a_{R}$ in rhombohedral axes and the lattice constant $\\pmb{a}_{\\sf H}$ in hexagonal axes for a rhombohedral crystal.", + "answer": "Under $\\pmb{a}_{\\sf H}$, bH, $\\pmb{\\mathbb{G H}}$, $a_{R}=1/s$ [1 1], so the lattice constant $a_{R}=\\mathsf{L}$ $\\begin{array}{r l}&{=\\mathsf{a_{H}}\\bullet\\mathsf{s q r t}(\\mathsf{U}^{2}+\\mathsf{V}^{2}+\\mathsf{W}^{2}\\mathsf{c_{H}}^{2}/\\mathsf{a_{H}}^{2}-\\mathsf{U V})}\\ &{=\\V_{3}\\vee(3\\mathsf{a_{H}}^{2}+\\mathsf{c_{H}}^{2}),}\\end{array}$ Since ${\\pmb{\\upalpha}}_{\\aleph}$ is the angle between the crystallographic directions $\\%$ [1 1] and $\\%$ [121], the lattice constant $\\texttt{a}_{\\texttt{R}}$ $\\begin{array}{r l}{=\\mathsf{a r c o s}(c_{\\mathsf{G}_{\\mathsf{H}}}{}^{2}/\\mathsf{a}_{\\mathsf{H}}{}^{2}{}-3/2)/(3+\\mathsf{c}_{\\mathsf{H}}{}^{2}/\\mathsf{a}_{\\mathsf{H}}{}^{2})}\\ {=\\mathsf{a r c o s}(}&{(2\\mathsf{c}_{\\mathsf{H}}{}^{2}{}-3\\mathsf{a}_{\\mathsf{H}}{}^{2})/(6\\mathsf{a}_{\\mathsf{H}}{}^{2}+2\\mathsf{c}_{\\mathsf{H}}{}^{2}))\\circ}\\end{array}$ ) gives a H = aR·sqrt (2(1-cosα)); $c_{H}=a_{R}\\cdot\\mathsf{s q r t}(3(1+2\\cos\\theta)\\circ$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推导晶格常数之间的转换公式，涉及数值计算和公式应用，答案中包含了具体的数学推导过程和公式转换，属于典型的计算题类型。 | 知识层次: 题目需要多步计算和概念关联，涉及不同晶系之间的转换公式推导，需要综合分析能力和对晶体学基础知识的理解。虽然不涉及复杂的机理解释或创新应用，但已经超出了简单应用的范围。 | 难度: 在选择题型内，该题目属于高难度等级。题目涉及复杂的多步计算和概念关联，需要深入理解晶格常数转换公式的推导过程。正确选项包含了多个数学运算和物理概念的结合，如向量运算、三角函数和晶格几何关系的综合分析。此外，题目还要求对六方晶系和菱方晶系之间的转换有清晰的认识，这在实际应用中属于较高层次的知识要求。因此，在选择题型中，该题目的难度属于复杂多变量计算的最高等级。" + }, + { + "idx": 2423, + "question": "A $C_{5}^{5}$ Fe plate with a thickness of $1.2\\\\pi m m$. One side is carburizing and the other side is decarburizing atmosphere, with surface concentrations of $\\\\mathrm{Pr}(C)=0.01200$ and $1+1(1-)=0.007500$, respectively. At $750-10$, when steady-state diffusion is achieved in the plate, the measured diffusion flux is $1.4\\\\times10^{-8}k g/m^{2}\\\\cdot5$. Find the diffusion coefficient of carbon at this temperature. $\\\\mathrm{{.}_{W}(C)=0.8\\\\%\\\\equiv60k g/m^{3})}$", + "answer": "First, convert the mass concentration to volume concentration. Since $\\\\begin{array}{r}{w(\\\\mathbf{C})=0,8\\\\%=60\\\\mathrm{kg/m^{3}}}\\\\end{array}$, the volume concentrations of $\\\\mathbb{C}_{1}{=}\\\\mathrm{w}(\\\\mathbb{C})=0,012\\\\%$ and $\\\\mathrm{C_{2}}{=}{}_{\\\\mathrm{W}}(\\\\mathrm{C}){=}0.00750/\\\\$ are: $$ C_{1}=\\\\frac{0.012}{0.8}\\\\times60=0.9\\\\mathrm{kg\\\\cdotm^{-3}}\\\\quad C_{2}=\\\\frac{0.0075}{0.8}\\\\times60=0.5625\\\\mathrm{kg\\\\cdotm^{-3}}$$ This is a one-dimensional steady-state diffusion problem, and the diffusion coefficient does not vary with concentration, so the concentration distribution in the plate is linear. Based on the given data, the concentration gradient in the plate can be calculated: $$ \\\\frac{\\\\mathrm{d}C}{\\\\mathrm{d}x}=\\\\frac{0.5625-0.9}{1.2\\\\times10^{-3}}\\\\mathrm{kg/m^{4}}=-281.25\\\\mathrm{kg/m^{4}}$$ According to the one-dimensional steady-state diffusion equation, the diffusion coefficient is $$ {\\\\cal D}=-J{\\\\frac{\\\\mathrm{d}\\\\mathrm{r}}{\\\\mathrm{d}C}}=1.4\\\\times10^{\\\\mathrm{~8}}\\\\times{\\\\frac{1}{281.25}}\\\\mathrm{m}^{2}/\\\\mathrm{s}=4.98\\\\times10^{-11}\\\\mathrm{m}^{2}/\\\\mathrm{s}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散系数，解答过程中涉及浓度转换、浓度梯度计算以及扩散系数的推导，这些都是典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将质量浓度转换为体积浓度，并应用一维稳态扩散方程进行计算。虽然不涉及复杂的推理分析或机理解释，但需要综合运用多个知识点进行中等难度的应用。 | 难度: 在选择题中属于高难度题目，需要综合运用多个概念（如浓度转换、稳态扩散、浓度梯度计算等），并进行多步骤的复杂计算。题目涉及的单位转换和公式推导也增加了难度，属于需要深入理解和综合分析的类型。" + }, + { + "idx": 2466, + "question": "What is the critical nucleation energy ΔG* when nucleation occurs as coherent disc-shaped particles within grains? Given the ratio of disc diameter to thickness D/N=10, the nucleation driving force ΔG1=5×10^8 J/m^3, the coherent interfacial energy γco=0.05×(1/17)^2, and the incoherent interfacial energy γin=0.5 J/m^2.", + "answer": "The calculation process for the critical nucleation energy ΔG* is as follows: The relationship between the disc radius r and thickness t is t = r/5. The disc volume equals πr^2t = πr^3/5. The disc top surface area equals πr^2, and the disc side surface area equals 2πrt = 2πr^2/5. The energy required for nucleation ΔG is ΔG = (πr^3/5)ΔG1 + 2πr^2γco + (2πr^2/5)γin. Differentiating with respect to r and setting it to zero, the critical size r* = (4×5γco + 4γin)/(3ΔG1) = (4×5×0.05 + 4×0.5)/(3×5×10^8) m = 2×10^-9 m. Substituting r* back into the ΔG equation, we obtain ΔG* = [-(π(2×10^-9)^3)/5 ×5×10^8 + 2π×(2×10^-9)^2×0.05 + (2π(2×10^-9)^2)/5×0.5] J = 1.26×10^-18 J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界成核能ΔG*，答案中包含了详细的数学推导和数值代入过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界成核能量的计算过程，并综合应用给定的参数和公式进行推导和计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题型中，该题目属于高难度等级。题目涉及多步骤的复杂计算过程，包括几何关系转换、能量方程建立、微分求极值以及多参数代入计算。解题者需要同时掌握形核理论、界面能概念和数学建模能力，并能够将这些知识综合应用于具体问题。计算过程中涉及多个变量的处理和单位转换，容易出现计算错误。这种复杂度和综合能力要求明显高于选择题型的平均水平，因此评定为等级4。" + }, + { + "idx": 862, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Determine the crystal orientation and shear strain at the onset of double slip.", + "answer": "It can be calculated as follows: L=l+γ(l⋅n)b Substituting into the above equation: [m] =[123] + [[123][][10] √3 1√2 Thus, v=1+γ4/√6=2, W=−3−γ4/√6 Solving gives v=2, w=−4, γ=√6/4 That is, the orientation at the onset of double slip is [112], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体取向和剪切应变，答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目涉及晶体塑性变形中的双滑移起始条件计算，需要多步计算和概念关联（如晶体取向、剪切应变计算），并需要综合分析滑移系激活条件。虽然不涉及复杂机理分析或创新设计，但已超出简单套用公式的范畴。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和概念关联，需要综合分析晶体取向和剪切应变的关系。解题过程包括向量运算、方程求解和物理概念应用，对学生的计算能力和理解深度要求较高。" + }, + { + "idx": 2574, + "question": "Using L=ds/+ds†(′⋅η)b, let L=[u 0 w], find the crystal orientation and shear strain.", + "answer": "L=[2 1 3]+4∨[111]/√6, from which it can be seen that u=3, v=4, γ=√6/4, so the crystal orientation is [304], and the shear strain is √6/4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和条件进行数值计算，最终得出晶体取向和剪切应变的数值结果。解答过程涉及数学运算和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解晶体取向和剪切应变的概念，并进行数值计算和综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多变量计算和综合分析。需要理解晶体取向和剪切应变的概念，并进行多步骤的计算推导。正确选项的解析过程需要将多个变量（u, v, γ）与晶体取向和剪切应变关联起来，计算过程较为复杂。此外，题目还要求对给定的数学表达式进行解析，进一步增加了难度。" + }, + { + "idx": 1703, + "question": "For two types of diffusion with activation energies of E1= 83.7 kJ/mol and E2=251 kJ/mol, how does the diffusion rate change when the temperature increases from 25°C to 600°C?", + "answer": "From D=D0exp(-Q/RT): when the temperature increases from 298K to 873K, the diffusion rate D increases by 4.6×10^9 and 9.5×10^28 times, respectively.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过公式计算扩散速率的变化，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散速率公式进行多步计算，涉及不同温度下的比较和指数运算，需要理解公式中各参数的意义并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于高难度题目，需要综合运用扩散速率公式进行多步复杂计算。题目要求计算两种不同激活能情况下温度变化对扩散速率的影响，涉及指数函数的复杂运算（从298K到873K的9.5×10^28倍变化计算），需要准确理解并应用Arrhenius方程，同时处理两个不同激活能系统的对比分析。这种需要处理多变量、进行指数级计算并比较不同系统行为的题目，在选择题型中属于最复杂的类型之一。" + }, + { + "idx": 2361, + "question": "How to compare the density difference between SiO2 and Al2O3 by calculating the packing density?", + "answer": "The relative atomic mass of SiO2 is 16. For SiO2, the mass of each SiO2 molecule is A_SiO2=(28.09+2×16)/(6.023×10^23) g=9.977×10^-23 g. The number of SiO2 molecules per cm³ is n_SiO2=ρ_SiO2/A_SiO2=2.55/9.977×10^-23=2.556×10^22 per cm³. The number of Si4+ and O2- ions per cm³ are n_Si4+=2.556×10^22 per cm³ and n_O2-=5.112×10^22 per cm³, respectively. The packing density of SiO2 is η_SiO2=(n_Si4+×4πr_Si4+^3/3 + n_O2-×4πr_O2-^3/3)/1=(4π/3)(2.556×0.039^3 + 5.112×0.132^3)×10^22×10^-21=0.577. For Al2O3, the mass of each Al2O3 molecule is A_Al2O3=(2×26.98+3×16)/(6.023×10^23) g=1.693×10^-22 g. The number of Al2O3 molecules per cm³ is n_Al2O3=ρ_Al2O3/A_Al2O3=3.95/1.693×10^-22=2.330×10^22 per cm³. The number of Al3+ and O2- ions per cm³ are n_Al3+=4.660×10^22 per cm³ and n_O2-=6.990×10^22 per cm³, respectively. The packing density of Al2O3 is η_Al2O3=(n_Al3+×4πr_Al3+^3/3 + n_O2-×4πr_O2-^3/3)/1=(4π/3)(4.660×0.057^3 + 6.990×0.132^3)×10^22×10^-21=0.714. Since η_Al2O3=0.714 is greater than η_SiO2=0.577, the density of Al2O3 is greater than that of SiO2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过计算SiO2和Al2O3的堆积密度来比较它们的密度差异，答案中包含了详细的数值计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算分子质量、分子数、离子数以及堆积密度，并进行综合分析比较。虽然不涉及复杂的推理分析或创新应用，但需要一定的理解和应用能力来正确执行这些步骤。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求通过计算堆积密度来比较SiO2和Al2O3的密度差异，涉及多个复杂的计算步骤和概念关联。具体包括：" + }, + { + "idx": 2259, + "question": "In the process of solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the time at which the phase transformation rate is the fastest.", + "answer": "$$ \\\\varphi=1-\\\\exp\\\\Bigl(-\\\\textstyle{\\\\frac{\\\\pi}{3}}\\\\dot{N}G^{3}t^{4}\\\\Bigr)$$ $$ \\\\frac{\\\\mathrm{d}\\\\varphi}{\\\\mathrm{d}t}=\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ $$ \\\\frac{\\\\mathrm{d}^{2}\\\\varphi}{\\\\mathrm{d}t^{2}}=-\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)^{2}\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)+\\\\left(\\\\frac{12}{3}\\\\pi\\\\dot{N}G^{3}t^{2}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ ${\\\\frac{\\\\mathrm{d}^{2}\\\\varphi}{\\\\mathrm{d}t^{2}}}=0$ , i.e.,$$ -\\\\left({\\\\frac{4}{3}}\\\\pi{\\\\dot{N}}G^{3}t^{3}\\\\right)^{2}+\\\\left({\\\\frac{12}{3}}\\\\pi{\\\\dot{N}}G^{3}t^{2}\\\\right)=0$$ $$ t_{\\\\mathrm{max}}=\\\\left(\\\\frac{9}{4\\\\pi\\\\dot{N}G^{3}}\\\\right)^{1/4}=\\\\left[\\\\frac{9}{4\\\\times3.14\\\\times1000\\\\times(3\\\\times10^{-5})^{3}}\\\\right]^{\\\\frac{1}{4}}=403$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出具体的时间值。解答过程涉及导数和极值计算，属于典型的计算题特征。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，包括求导和求解方程，涉及对相变动力学的基本理解和公式的综合应用，但不需要复杂的推理或创新性思维。 | 难度: 在选择题中属于高难度，需要深入理解Johnson-Mehl方程及其微分运算，进行多步骤的数学推导和计算，包括二阶导数的求解和极值点的确定，涉及复杂的多变量计算和综合分析能力。" + }, + { + "idx": 3173, + "question": "The density of $\\\\mathrm{CaF}_{2}$ is $\\\\rho=3.18~\\\\mathrm{g/cm}^{3}$, the lattice constant is $a=0.5463\\\\mathrm{nm}$, and the relative atomic masses of Ca and F are 40.08 and 19.00, respectively. Calculate the number of Schottky vacancies in the unit cell of CaF2.", + "answer": "To maintain electrical neutrality, in the $\\\\mathrm{CaF}_{2}$ ionic crystal, for every Schottky defect formed, one $\\\\mathrm{Ca}^{2+}$ and two $\\\\mathbf{F}^{-}$ must be lost simultaneously. Let the number of Schottky defects in the unit cell be $x$, then $$ x\\\\rho=\\\\frac{\\\\left(4-x\\\\right)\\\\left(40.08+19\\\\times2\\\\right)/6.023\\\\times10^{23}}{5.463^{3}\\\\times10^{-24}}\\\\approx3.18\\\\left({\\\\mathrm{g}}/{\\\\mathrm{cm}^{3}}\\\\right) $$ Therefore, $$ x=4-\\\\frac{6.023\\\\times10^{23}\\\\times3.18\\\\times5.463^{3}\\\\times10^{-24}}{40.08+19.00\\\\times2}\\\\approx6.10\\\\times10^{-4}\\\\uparrow $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了密度、晶格常数、相对原子质量等数据的计算，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括密度、晶格常数和相对原子质量的综合应用，同时需要理解肖特基缺陷的形成机制和电中性条件。虽然不涉及复杂的推理分析或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于高难度，题目涉及复杂的多步计算和概念关联。需要理解Schottky缺陷的概念，掌握密度和晶格常数的关系，进行单位换算和代数运算，并综合分析多个变量。解题步骤复杂，对知识点的掌握深度要求较高。" + }, + { + "idx": 2714, + "question": "The vacancy formation energy (E_v) and interstitial atom formation energy (E_i) of Al are 0.76 eV and 3.0 eV, respectively. Calculate the ratio of the equilibrium concentration of vacancies to the equilibrium concentration of interstitial atoms in Al at 500°C.", + "answer": "At 500°C: C_V/C_i = e^((1/(8.617×10^-5×773))(3.0-0.76)) = e^33.63 = 4.026×10^14", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及能量和浓度的计算，答案也是通过具体计算得出的数值结果。 | 知识层次: 题目需要应用缺陷形成能的基本概念，进行多步计算（包括温度转换、玻尔兹曼因子计算和指数运算），并理解平衡浓度与形成能之间的关系。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个知识点进行计算和结果解释。 | 难度: 在选择题中属于中等偏上难度，需要理解空位形成能和间隙原子形成能的概念，掌握平衡浓度计算公式，并能正确进行多步指数运算。题目涉及温度单位转换（°C转K）、玻尔兹曼常数应用以及综合计算能力，但选项提供了明确的解题路径，减少了部分分析难度。" + }, + { + "idx": 4926, + "question": "The formula for samarium iron garnet (Sm3Fe5O12) may be written in the form Sm3^aFe2^cFe3^dO12, where the superscripts a, c, and d represent different sites on which the Sm^3+ and Fe^3+ ions are located. The spin magnetic moments for the Sm^3+ and Fe^3+ ions positioned in a and c sites are oriented parallel to one another and antiparallel to the Fe^3+ ions in d sites. Compute the number of Bohr magnetons associated with each Sm^3+ ion, given the following information: (1) each unit cell consists of eight formula (Sm3Fe5O12) units; (2) the unit cell is cubic with an edge length of 1.2529 nm; (3) the saturation magnetization for this material is 1.35 × 10^5 A/m; and (4) there are 5 Bohr magnetons associated with each Fe^3+ ion.", + "answer": "2.86 bm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的信息和公式进行计算，最终得出一个具体的数值结果（2.86 bm）。解答过程需要应用材料科学中的磁学知识和数学计算，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个概念的综合应用，包括磁矩计算、单位晶胞分析、饱和磁化强度与磁矩的关系等。虽然不涉及复杂的推理分析或创新设计，但需要较强的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算和综合分析。题目涉及材料科学中的磁学性质计算，需要掌握单位晶胞、饱和磁化强度、玻尔磁子等概念，并能将这些概念关联起来进行综合计算。虽然题目提供了所有必要的信息，但解题步骤较为复杂，需要较高的概念理解和计算能力。" + }, + { + "idx": 4327, + "question": "What is the carbon concentration of an iron-carbon alloy for which the fraction of total ferrite is 0.94 ?", + "answer": "the carbon concentration of the iron-carbon alloy is 0.42 \\text{ wt% c}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算铁碳合金的碳浓度，需要通过给定的铁素体分数（0.94）进行数值计算，并应用相关公式得出具体数值（0.42 wt% C）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图的相关知识，通过给定的铁素体分数来计算碳浓度，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要综合运用铁碳相图知识、杠杆定律计算以及相分数与成分的关系。解题步骤包括：1) 理解总铁素体分数含义；2) 确定相关相区；3) 应用杠杆定律建立方程；4) 解方程求碳浓度。虽然计算过程明确，但需要准确关联多个概念，且容易在相边界值判断上出错，属于典型的综合性计算问题。" + }, + { + "idx": 1982, + "question": "At $800^{\\circ}\\mathrm{C}$, one atom in $10^{10}$ atoms has sufficient energy to move within the solid, while at $900^{\\circ}\\mathrm{C}$, only one atom in $10^{9}$ atoms does. Calculate the activation energy (J/atom).", + "answer": "$0.4\\times10^{-18}~\\mathrm{J}/$ atom", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解激活能（J/atom），答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度与激活能的关系，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解阿伦尼乌斯方程的概念，并进行多步计算和综合分析。题目涉及温度变化与活化能的关系，需要考生将给定的数据转换为合适的数学表达式，并进行对数运算来求解活化能。虽然计算步骤较多，但在选择题型中，正确选项的提示可以降低部分难度。" + }, + { + "idx": 3868, + "question": "An isothermally transformed eutectoid steel is found to have a yield strength of 410 MPa. Estimate the transformation temperature.", + "answer": "transformation temperature =615 C", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算来估计转变温度，答案是一个具体的数值结果（615 C），这表明需要应用相关公式或经验关系进行计算。 | 知识层次: 题目需要应用材料科学中的相变温度与力学性能关系知识，进行多步计算和综合分析。虽然题目给出了具体的数值计算要求，但需要理解相变温度与屈服强度之间的关系，并可能涉及相关公式的应用，这超出了简单应用的范畴，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解等温转变曲线、屈服强度与转变温度的关系，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及多个概念的关联和计算步骤，比单纯记忆或简单计算的选择题更复杂。" + }, + { + "idx": 2717, + "question": "Using the vacancy concentrations at 20℃ and 1020℃, set up the equations to solve for the vacancy formation energy Ev and entropy Sv.", + "answer": "5 × 10^-24 = exp(Sv/k) × exp[-Ev/(293k)], 1 × 10^-4 = exp(Sv/k) × exp[-Ev/(1293k)].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的方程和条件进行数值计算和公式应用，以求解空缺形成能Ev和熵Sv。答案给出了具体的方程形式，需要进一步的数学运算来解出未知数。 | 知识层次: 题目需要建立并求解两个方程来计算空位形成能和熵，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解空缺浓度与温度的关系，掌握指数方程的对数变换技巧，并能建立联立方程求解两个未知数（Ev和Sv）。虽然题目给出了正确选项，但需要考生具备将物理概念转化为数学表达的能力，并理解熵和能量的温度依赖性。这超出了简单的概念回忆或单步计算，属于需要多步推导和概念关联的综合问题。" + }, + { + "idx": 3962, + "question": "A cylindrical specimen of a metal alloy 48.8mm long and 9.09mm in diameter is stressed in tension. A true stress of 327 MPa causes the specimen to plastically elongate to a length of 55 mm. If it is known that the strain-hardening exponent for this alloy is 0.3 , calculate the true stress (in MPa )necessary to plastically elongate a specimen of this same material from a length of 48.8mm to a length of 57.6 mm.", + "answer": "390 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（应变硬化指数公式）来求解真实应力，最终需要给出具体的数值计算结果（390 MPa）。 | 知识层次: 题目需要进行多步计算，包括应变计算、应变硬化公式的应用以及不同条件下的应力转换。虽然涉及的概念（如应变硬化指数）较为基础，但需要将这些概念关联起来进行综合分析，才能得出最终结果。思维过程需要一定的深度和逻辑性，但不需要进行复杂的机理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及塑性变形、应变硬化指数、真实应力-应变关系等概念的综合运用，解题步骤包括计算初始和最终应变、应用应变硬化公式等，属于多步骤计算过程。虽然题目提供了正确选项，但解题过程需要一定的综合分析能力，因此在选择题型内属于等级3难度。" + }, + { + "idx": 195, + "question": "At 17°C, the solubility of large particles of 1,2-dinitrobenzene in water is 0.0059 mol/L, and the interfacial tension between 1,2-dinitrobenzene solid and the solution is 0.0257 N/m. Calculate the solubility of 1,2-dinitrobenzene with a diameter of 10^-8 m in water. The density of 1,2-dinitrobenzene solid is 1565 kg/m^3.", + "answer": "According to the formula ln(C/C0) = 2(γ_sM)/(dRTρ), substituting the known data, ln(C/0.0059) = 2 × (0.0257 × 168) / (1565 × 8.314 × 290 × 10^-8) = 114.42. From this, the solubility of 1,2-dinitrobenzene with a diameter of 10^-8 m in water can be calculated as 0.029 mol/L.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出具体的溶解度数值，属于典型的计算题。答案中展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和概念关联（如溶解度、界面张力、粒子尺寸效应等），需要综合分析已知条件并正确代入公式求解。虽然不涉及复杂的推理分析或创新应用，但比简单应用更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解溶解度与颗粒尺寸的关系公式，并进行多步计算。题目涉及多个物理量的代入和单位转换，要求考生具备较强的综合计算能力和对公式的理解。虽然题目提供了正确选项，但解题过程需要较高的注意力集中和计算准确性。" + }, + { + "idx": 2394, + "question": "In a crystal, there is a pair of parallel edge dislocations on the slip plane. How large should their spacing be to prevent movement due to their interaction? Assume the slip resistance (shear stress) of the dislocation is $\\\\square A^{\\\\prime\\\\prime}\\\\approx10^{5}Pa$, $1=0.3$, $G=5\\\\times10^{10}Pa$ (express the answer in terms of b).", + "answer": "Two parallel edge dislocations (denoted as A and B), with dislocation A located on the $\\\\underline{{\\\\underline{{\\\\pi}}}}$ axis of the coordinate frame. The force per unit length exerted by dislocation A on parallel dislocation B at position $(x,y)$ in the slip direction is F. Since both dislocations are on the same slip plane, the force is $F_{s}^{\\\\mathrm{A\\\\toB}}=\\\\frac{G b^{2}}{2\\\\pi(1-\\\\nu)}\\\\frac{1}{x}$ G²1, where x is the distance between the two dislocations. When this force equals or exceeds the resistance $\\\\cdot E_{1}b$ that the dislocation must overcome to slip, the two dislocations can slide. Therefore, when $$\\\\leq\\\\frac{\\\\vec{\\\\left(r\\\\right)}^{h}}{\\\\underline{{\\\\vec{2}\\\\pi(1-\\\\nu^{\\\\prime})}}}\\\\frac{1}{\\\\tau_{\\\\perp}}$$, the two dislocations will slide. That is, $$ \\\\displaystyle{x\\\\leq\\\\frac{G b}{2\\\\pi(1-\\\\nu)}\\\\frac{1}{\\\\tau_{\\\\mathrm{pe}}}}{=\\\\frac{5\\\\times10^{10}b}{2\\\\pi(1-0.3)}\\\\frac{1}{9.8\\\\times10^{5}}}{=1.16\\\\times10^{4}b}$$. If the two dislocations have the same sign, they will move toward each other until the distance between them is less than the calculated $^\\\\texttt{I}$ and then remain stationary. If the two dislocations have opposite signs, they will attract and annihilate each other when the distance between them is less than the calculated $x$. The two dislocations will remain stationary only if the distance between them is greater than $\\\\gamma^{-}$. The force in the climb direction is 0, so no climb will occur regardless of the distance between the two dislocations.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定两个平行刃位错之间的临界间距，以防止它们因相互作用而移动。解答过程中涉及到了具体的公式推导和数值代入计算，最终给出了一个具体的数值结果（1.16×10^4b），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错相互作用力的公式应用，并进行数值计算。虽然不需要复杂的推理分析或创新应用，但需要综合运用材料科学中的位错理论和力学知识来解决问题。 | 难度: 在选择题中属于中等偏上难度，需要理解位错相互作用的基本概念，掌握剪切应力与位错间距的关系，并进行多步计算。题目涉及平行刃位错在滑移面上的相互作用力计算，需要将理论公式与给定数值结合，最终推导出临界间距。虽然题目提供了部分公式，但仍需要考生综合运用材料力学和位错理论的知识来完成解答。" + }, + { + "idx": 2871, + "question": "Given a $1~\\\\mathrm{cm}^{3}$ brass sample annealed at $700\\\\textcircled{1}$ with an initial grain diameter of $2.16\\\\times10^{-3}~\\\\mathrm{cm}$, the grain boundary energy of brass is $0.5J/\\\\mathfrak{m}^{2}$. A calorimeter measured a total heat release of 0.035J after holding for $2\\\\mathtt{h}$. Determine the grain size after holding for $2\\\\mathtt{h}$.", + "answer": "Assuming the heat released after holding for $2\\\\textrm{h}$ is due to grain growth, where the reduction in total grain boundary area releases energy. From quantitative metallography, the relationship between the interfacial area per unit volume $S_{V}$ and the grain diameter $d$ on the cross-section is $S_{v}={\\\\frac{2}{d}}$. Therefore, $$\\\\scriptstyle Q={\\\\Big(}{\\\\frac{2}{d_{1}}}-{\\\\frac{2}{d_{2}}}{\\\\Big)}\\\\gamma,\\\\quad{\\\\frac{1}{d_{2}}}={\\\\frac{1}{d_{1}}}-{\\\\frac{Q}{2\\\\gamma}}$$Substituting the corresponding data, we obtain $$d_{z}=8.9\\\\times10^{3}(\\\\mathrm{cm)}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶粒尺寸，答案给出了具体的计算过程和最终数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括理解晶界能与晶粒尺寸的关系、应用定量金相学公式进行计算，以及综合分析热释放与晶粒生长的关系。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和数学运算技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如晶界能、晶粒生长热力学关系）并进行多步计算（包括代数转换和单位换算）。题目要求将理论公式与实验数据结合，综合分析得出最终晶粒尺寸，涉及中等应用层次的知识点。虽然选项提供了计算路径，但步骤和概念关联的复杂度仍使其高于基础计算题。" + }, + { + "idx": 4884, + "question": "Estimate the maximum thermal conductivity value for a cermet that contains 90 vol% titanium carbide (TiC) particles in a nickel matrix. Assume thermal conductivities of 27 and 67 W/m·K for TiC and Ni, respectively.", + "answer": "the maximum thermal conductivity k_max is 31.0 W/m·K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计cermet的最大热导率值，答案是一个具体的数值结果（31.0 W/m·K），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用复合材料热导率的计算公式，涉及多步计算和不同材料性能的综合分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解复合材料热导率的概念，掌握混合规则（如串联模型），并进行多步计算。虽然题目给出了具体数值，但需要正确应用公式和逻辑推理才能得出正确答案。" + }, + { + "idx": 269, + "question": "For spherical Al2O3 particles with a diameter of 1μm surrounded by excess MgO particles, the formation of spinel is observed. At a constant temperature, 20% of the Al2O3 reacts in the first hour. Calculate the time required for complete reaction using the Jander equation.", + "answer": "Calculation using the Jander equation: [1-(1-G)^(1/3)]^2 = kt ⇒ k = [1-(1-G)^(1/3)]^2 / t Substituting the reaction time of 1h and reaction progress of 20% given in the problem, we obtain k = [1-(1-0.2)^(1/3)]^2 / 1 = 5.138×10^-3 h^-1 Therefore, the time required for complete reaction (G=1) is t = 1/k = 1/(5.138×10^-3) = 194.62 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用Jander方程进行数值计算，并给出具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要应用Jander方程进行多步计算，涉及反应动力学和固体反应的基本原理。虽然计算过程相对直接，但需要对公式进行适当变形和数值代入，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解Jander方程的应用并进行多步骤计算。题目要求考生不仅掌握反应动力学的基本概念，还需要能够正确代入数值并解方程。虽然计算过程较为直接，但涉及多个步骤和公式转换，属于综合性计算问题。" + }, + { + "idx": 2497, + "question": "Calculate the angles between low-index crystallographic directions with indices not exceeding 3 in cubic crystals (presented in a list)", + "answer": "Use the crystallographic direction angle formula cosθ=(u1u2+v1v2+w1w2)/sqrt((u1²+v1²+w1²)*(u2²+v2²+w2²)) to calculate. The angle between two crystallographic direction families may have multiple values depending on the selected directions. The specific calculation results need to list all crystallographic direction combinations with indices not exceeding 3 and their corresponding angles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用特定的公式计算立方晶体中低指数晶向之间的角度，并列出所有不超过3的晶向组合及其对应角度。这需要数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目要求应用立方晶体中低指数晶向间夹角的计算公式，涉及多步计算和不同晶向组合的综合分析。虽然公式本身是直接的，但需要列举所有指数不超过3的晶向组合并计算对应角度，这增加了复杂性和关联度，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要掌握立方晶体中晶向角度的计算公式，并能够正确应用该公式进行多步计算。题目要求列出所有指数不超过3的晶向组合及其对应角度，涉及多个变量的组合和计算，具有一定的综合性。虽然题目提供了明确的公式，但计算过程较为繁琐，需要较高的注意力和准确性。" + }, + { + "idx": 4734, + "question": "For a steel alloy it has been determined that a carburizing heat treatment of 15h duration will raise the carbon concentration to 0.35 wt% at a point 2.0mm from the surface. Estimate the time necessary to achieve the same concentration at a 6.0-mm position for an identical steel and at the same carburizing temperature.", + "answer": "the time necessary to achieve the same concentration at a 6.0-mm position is 135 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的条件和扩散方程来估算时间。答案是一个具体的数值结果（135 h），表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的公式应用和参数调整，需要理解碳浓度与时间和位置的关系，并进行综合分析来求解新的时间。 | 难度: 在选择题中属于中等难度，需要理解扩散定律（如菲克第二定律）并进行多步计算。题目要求在不同位置达到相同碳浓度，需要综合分析距离与时间的关系（x²∝t），并正确应用比例关系进行计算。虽然计算步骤明确，但需要将概念知识与数学推导结合，属于综合性计算问题。" + }, + { + "idx": 2666, + "question": "The lattice constant of Cr is $\\mathbf{a=0.2884nm}$, and the density is $\\rho{=}7.19\\mathrm{g}/\\mathrm{cm}^{3}$. Determine the crystal structure of $\\mathrm{Cr}$ at this time.", + "answer": "p= $\\rho{=}\\frac{n A_{\\tau}}{a\\times N_{\\mathrm{A}}}\\Rightarrow n=\\frac{\\rho a^{3}N_{\\mathrm{A}}}{A_{\\tau}}{=}\\frac{7.19\\times(2.884\\times10^{-8})^{3}\\times6.023\\times10^{23}}{52.0}{=}1.9977\\approx2$, hence it is a bcc structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定晶体的结构，解答过程中涉及到了密度、晶格常数、阿伏伽德罗常数等物理量的计算，最终通过计算结果得出晶体结构类型。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换和数值计算，同时需要将计算结果与晶体结构理论关联起来进行综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算、单位换算等多个概念，并进行多步骤计算和综合分析。虽然题目提供了公式和计算过程，但考生仍需掌握相关知识点才能正确理解和应用。" + }, + { + "idx": 4795, + "question": "What is the magnitude of the maximum stress that exists at the tip of an internal crack having a radius of curvature of 1.9 × 10^{-4} mm\\left(7.5 × 10^{-6} in.\\right) and a crack length of 3.8 × 10^{-2} mm\\left(1.5 × 10^{-3}\\right. in.) when a tensile stress of 140 MPa(20,000 psi) is applied?", + "answer": "the magnitude of the maximum stress is 2800 \\text{ mpa} (400,000 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算裂纹尖端最大应力的大小，需要应用相关公式进行数值计算，答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解应力集中概念并正确应用相关公式进行计算，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解应力集中概念、掌握裂纹尖端应力计算公式，并进行多步单位换算和数值计算。虽然题目提供了公式所需的所有参数，但计算过程涉及指数运算和单位转换，对学生的应用能力和计算准确性有较高要求。" + }, + { + "idx": 4339, + "question": "The microstructure of an iron-carbon alloy consists of proeutectoid ferrite and pearlite; the mass fractions of these microconstituents are 0.20 and 0.80 , respectively. Determine the concentration of carbon in this alloy.", + "answer": "the concentration of carbon in this alloy is 0.61% \\text{c}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定铁碳合金中的碳浓度，涉及质量分数和微观结构的数值计算，答案以具体数值形式给出。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算和概念关联。首先需要理解先共析铁素体和珠光体的定义及其在相图中的位置，然后利用杠杆定律计算碳的浓度，涉及多个知识点的综合运用和中等难度的计算过程。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳合金相图、先共析铁素体和珠光体的概念，并进行多步计算（包括质量分数转换和相图定位）。虽然题目提供了关键参数，但解题过程需要综合应用相图知识和计算公式，属于典型的综合性计算问题。" + }, + { + "idx": 3651, + "question": "FCC lead has a lattice parameter of 0.4949 nm and contains one vacancy per 500 Pb atoms. Calculate the density.", + "answer": "the density is 11.335 g/cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解FCC铅的密度，答案是一个具体的数值结果（11.335 g/cm3），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶格参数与密度的关系、空位浓度的计算等，需要综合应用材料科学中的基本概念和公式，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、空位浓度、密度计算等多个概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及单位换算、原子质量应用和综合公式推导，对学生的概念关联和计算能力要求较高。" + }, + { + "idx": 3906, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Determine the atomic radius of the metal.", + "answer": "The metal has an atomic radius of 0.155 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如单位晶胞边长、密度和原子量之间的关系）来确定金属的原子半径，答案是一个具体的数值结果（0.155 nm），符合计算题的特征。 | 知识层次: 题目需要多步计算（包括密度公式应用、单位换算和几何关系推导），并需要将晶体结构几何知识与材料物理性质（密度、原子量）关联起来综合分析。虽然不涉及复杂机理或创新设计，但思维过程要求高于简单套用公式。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目涉及单位晶胞边长、密度、原子量等多个参数的综合计算，要求考生掌握晶体结构、密度计算、原子半径与晶格参数的关系等知识点，并进行多步推导和计算。虽然选择题提供了正确选项，但解题过程仍需要较高的综合分析能力和计算技巧。" + }, + { + "idx": 4680, + "question": "The number-average molecular weight of a poly(acrylonitrile-butadiene) alternating copolymer is 1,000,000g / mol; determine the average number of acrylonitrile and butadiene repeat units per molecule.", + "answer": "the average number of acrylonitrile and butadiene repeat units per molecule is 9333.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定高分子链中重复单元的平均数量，需要应用分子量和重复单元分子量的公式进行计算，答案是一个具体的数值结果。 | 知识层次: 题目需要计算交替共聚物的重复单元数量，涉及分子量的概念和公式应用，需要多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解交替共聚物的分子量计算概念，掌握重复单元分子量的计算，并进行多步综合运算才能得出正确结果。虽然题目提供了正确选项，但解题过程涉及分子结构分析、摩尔质量计算和除法运算等多个步骤，属于综合性计算问题。" + }, + { + "idx": 4736, + "question": "The activation energy for the diffusion of copper in silver is 193,000 J/ mol. Calculate the diffusion coefficient at 1200 K\\left(927^{\\circ} C\\right), given that D at 1000 K\\left(727^{\\circ} C\\right) is 1.0 × 10^{-14}{m}^{2} / s.", + "answer": "the diffusion coefficient at 1200k is 4.8 × 10^{-13}{m}^{2} / s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和扩散系数数据，应用阿伦尼乌斯方程进行数值计算，以求解在特定温度下的扩散系数。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及扩散系数与温度的关系，需要理解活化能的概念并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解扩散系数的概念，掌握阿伦尼乌斯方程的应用，并进行多步骤的计算。题目涉及温度转换、对数运算和指数计算，要求考生能够综合运用这些知识来解决问题。虽然题目提供了部分已知条件，但解题过程仍然需要一定的综合分析能力。" + }, + { + "idx": 4664, + "question": "Beryllium (Be) has an HCP unit cell for which the ratio of the lattice parameters c/a is 1.568. If the radius of the Be atom is 0.1143nm, calculate the theoretical density of Be and compare it with the literature value.", + "answer": "the theoretical density of be is 1.84 g/cm3, and the literature value is 1.85 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（HCP晶胞参数、原子半径与密度的关系）来求解铍的理论密度，并将计算结果与文献值进行比较。答案呈现为具体数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（包括晶格参数计算、体积计算、密度计算等），并涉及HCP晶体结构的基本概念和公式应用，需要将多个知识点关联起来进行综合分析。虽然不涉及复杂的推理或创新设计，但思维过程比简单应用更为深入。 | 难度: 在选择题中属于中等偏上难度，需要理解HCP晶体结构参数关系、原子半径与晶格参数转换、理论密度计算公式等多个概念，并进行多步骤计算和文献值对比分析。虽然选择题提供了正确选项降低了部分难度，但仍需掌握晶体学知识和单位换算能力才能正确解答。" + }, + { + "idx": 2015, + "question": "The maximum solid solubility (mole fraction) of carbon in γ-Fe is x_C=8.9×10^-2. Given that C atoms occupy octahedral interstitial sites, calculate the percentage of octahedral interstitial sites occupied by C atoms.", + "answer": "The percentage of octahedral interstitial sites occupied by C atoms is 10.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算碳原子占据八面体间隙的百分比），并给出了具体的数值答案（10.2%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及固溶体最大固溶度的概念、晶格间隙位置的计算以及百分比转换，需要综合运用材料科学中的相关知识和公式。虽然不涉及复杂的机理分析或创新设计，但思维过程要求一定的深度和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体、间隙位置和浓度计算等多个概念，并进行多步计算和综合分析。虽然题目提供了关键数据，但需要正确应用晶体学知识和数学转换才能得出正确答案。" + }, + { + "idx": 2191, + "question": "Given the Burgers vector of a dislocation as b, the bubble radius as r, and the specific interfacial energy between the bubble and metal as σ, determine the increment of shear stress Δτ.", + "answer": "The increased interfacial area between the bubble and metal after the dislocation cuts the bubble is A=2rb. The increment of interfacial energy is 2rbσ. If the increment of shear stress for a dislocation cutting one bubble is Δτ', then the work done by the stress is Δτ'b. Therefore, 2rbσ=Δτ'b, Δτ'=2rσ. When the bubble density is n, the total increment of shear stress Δτ=nΔτ'=2nrσ. It can be seen that the increment of shear stress is proportional to the bubble density.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（Burgers vector、bubble radius、specific interfacial energy）进行计算，并得出增量剪切应力的数值结果。解答过程涉及公式应用和数值推导，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和概念关联，包括理解位错切割气泡导致的界面能增加、应力增量与气泡密度的关系等综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（Burgers向量、位错切割气泡的界面能增量、剪切应力增量等）并进行多步计算和综合分析。题目涉及中等应用层次的知识点，要求考生能够将不同概念关联起来，并通过逻辑推导得出最终结论。虽然题目提供了正确选项的详细推导过程，但在选择题型内仍需要考生具备较强的概念理解和计算能力才能正确解答。" + }, + { + "idx": 3806, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the amounts and compositions of each phase at 260 c.", + "answer": "l: 30% sn, α: 12% sn; % l=17%, % α=83%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定各相的含量和组成，答案给出了具体的数值计算结果（% l=17%, % α=83%），这需要应用相图和相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律计算以及综合分析能力。题目要求确定特定温度下各相的成分和含量，涉及多步骤计算和概念关联，但选项提供了部分引导，降低了纯粹计算的复杂度。" + }, + { + "idx": 2910, + "question": "At the same temperature, when the α phase (85% A, 10% B, 5% C) and β phase (10% A, 20% B, 70% C) each account for 50%, estimate the composition of the alloy.", + "answer": "Let the alloy composition be x, which must lie on the line connecting the α-β phase composition points. According to the lever rule: (α/β) = (x - 10%) / (85% - x) = 1; solving gives x = 47.5% A; then, from the concentration triangle, B = 14.5% and C = 38% are obtained.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用（杠杆定律）来求解合金的成分，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要应用杠杆规则进行多步计算，同时需要理解相图中成分点的连接和浓度三角形的概念，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解杠杆规则的应用，进行多步计算，并正确运用浓度三角形概念来推导合金成分。虽然题目提供了明确的解题路径，但涉及多个计算步骤和概念的综合运用，对学生的理解和计算能力有一定要求。" + }, + { + "idx": 2648, + "question": "It is known that pure titanium at 20°C is α-Ti (hcp structure), with lattice constants a=0.2951nm and c=0.4679nm. Calculate the interplanar spacing of the (112) plane.", + "answer": "For the hcp structure, when h+2k=3n (n=0,1,2,3...), and l is an odd number, there is an additional plane. d_(112)=1/√[(4/3)((h²+hk+k²)/a²)+(l/c)²]=1/√[(4/3)((1²+1×1+1²)/0.2951²)+(2/0.4679)²]=0.1248nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解(112)晶面的面间距，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要应用hcp结构的晶面间距计算公式，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要掌握hcp结构晶面间距的计算公式，理解晶面指数的含义，并能正确代入数值进行多步骤计算。题目涉及的概念和计算步骤较为复杂，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 1006, + "question": "If a piece of iron is heated from room temperature 20°C to 850°C, then cooled very quickly to 20°C, calculate the change in the number of vacancies before and after the treatment (assuming the energy required to form 1 mole of vacancies in iron is 104600J).", + "answer": "$$ \\\\cdot\\\\frac{c_{850\\\\mathrm{PC}}}{c_{20\\\\mathrm{PC}}}=\\\\frac{A\\\\mathrm{e}^{-\\\\frac{\\\\Delta E}{k\\\\cdot(850+273)}}}{A\\\\mathrm{e}^{-\\\\frac{\\\\Delta E}{k\\\\cdot(20+273)}}}=\\\\mathrm{e}^{-\\\\frac{104675}{1123\\\\times8.31}\\\\frac{104675}{293\\\\times8.31}}=6.3\\\\times10^{13}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式和参数来计算空位数的变化，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括温度转换（摄氏到开尔文）、应用阿伦尼乌斯公式计算空位浓度比，以及对数运算。虽然不涉及多个概念的复杂关联或深度机理分析，但需要正确理解和应用热力学公式进行计算，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解空位形成能的概念，掌握阿伦尼乌斯公式的应用，并进行多步温度单位转换和指数计算。虽然题目提供了关键参数，但需要综合运用热力学和材料科学知识完成从摄氏温度到开尔文温度的转换、玻尔兹曼常数应用以及复杂的指数运算。相比简单记忆或单步计算的选择题，该题目对计算能力和概念关联性要求较高，但尚未达到多变量交互作用的复杂程度。" + }, + { + "idx": 63, + "question": "Based on the projection of Mg2[SiO4] on the (100) plane, answer: what is the number of molecules in the unit cell?", + "answer": "z=4", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于投影计算晶胞中的分子数量，需要通过结构分析和数值计算得出具体数值（z=4），属于需要应用晶体学知识和计算方法的计算题。 | 知识层次: 题目需要基于晶体投影进行多步计算，涉及晶体结构分析和单位晶胞分子数的确定，需要概念关联和综合分析能力 | 难度: 在选择题中属于中等偏上难度，需要理解晶体投影、单位细胞分子数计算等概念，并进行多步骤的空间想象和综合分析。虽然题目提供了正确选项，但解题过程涉及对晶体结构的理解和投影分析，属于综合性计算问题。" + }, + { + "idx": 1088, + "question": "Assuming carbon atoms are all located in the octahedral interstices of γ-Fe, at 1000°C, 1.7 weight percent of carbon atoms are dissolved in γ-Fe. Calculate how many carbon atoms are present in 100 unit cells and determine the proportion of octahedral interstices occupied by carbon atoms (the atomic weight of iron is 55.85, and the atomic weight of carbon is 12.01).", + "answer": "γ-Fe has a face-centered cubic structure, with 4 Fe atoms and 4 octahedral interstices per unit cell. Let the number of carbon atoms in one unit cell be $A$, then: Solving gives $A=0.32$ $$\\frac{100A\\times12.01}{100\\times4\\times55.85+100A\\times12.01}=1.7\\%$$ Thus, the number of carbon atoms in 100 unit cells is: $0.32\\times100=32$ The proportion of octahedral interstices occupied by C atoms: $$A/4=0.32/4=0.08=8\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程涉及单位换算、比例计算和百分比求解，最终需要得出具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解γ-Fe的面心立方结构、八面体间隙的位置和数量，以及碳原子在其中的溶解比例。同时，需要进行质量百分比和原子数量的转换计算，综合分析碳原子占据间隙的比例。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解面心立方结构、间隙位置、原子百分比与重量百分比转换等多个概念，并进行多步骤的综合计算。虽然题目提供了正确选项作为参考，但仍需要考生具备较强的概念关联能力和计算能力才能正确解答。" + }, + { + "idx": 4817, + "question": "If ice homogeneously nucleates at -40^{\\circ} C, calculate the critical radius given values of - 3.1 × 10^{8} J/ m^{3} and 25 × 10^{-3} J/ m^{2}, respectively, for the latent heat of fusion and the surface free energy.", + "answer": "the critical radius is 1.10 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数值和公式计算临界半径，答案是一个具体的数值结果（1.10 nm），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及临界半径公式的应用，需要理解并关联表面自由能和潜热的概念，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解临界半径的计算公式，并正确代入给定的参数（潜热和表面自由能）进行多步计算。虽然题目提供了所有必要数据，但仍需综合应用热力学和成核理论的知识来解决问题。" + }, + { + "idx": 2594, + "question": "If the applied stress is uniformly distributed, find the net force acting on any dislocation loop.", + "answer": "In general, the formula for the force on a dislocation is ${\\mathsf{d}}F=({\\textsf{\\sigma}}\\cdot{\\textsf{\\em b}})\\times{\\mathsf{d}}/,$. Since the applied stress is uniformly distributed, $\\pmb{\\upsigma}$ and $\\pmb{b}$ are both constants. Therefore, the net force on any dislocation loop is $\\oint\\mathbf{d}F=\\oint{\\bigl(}\\upsigma\\bullet b{\\bigr)}\\times\\mathbf{d}/={\\bigl(}\\upsigma\\bullet b{\\bigr)}\\oint\\mathbf{d}/={\\bigl(}\\upsigma$ • $b)\\times0=0.$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式计算均匀应力下的净力，答案展示了具体的数学推导和积分过程，符合计算题的特征。 | 知识层次: 题目涉及对均匀应力分布下位错环受力情况的综合分析，需要应用位错力的基本公式并进行积分运算。虽然公式本身是基础的，但需要理解应力、位错矢量和积分路径之间的关系，并进行多步推导和计算。这超出了简单应用的范畴，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如均匀应力分布、位错力公式、环路积分等）并进行多步计算和综合分析。虽然题目提供了正确选项的推导过程，但考生仍需掌握相关物理概念和数学运算才能正确理解和验证该选项。" + }, + { + "idx": 2453, + "question": "For the allotropic transformation of a pure metal $(x\\\\rightarrow\\\\beta)$, at a certain degree of undercooling, the volume Gibbs free energy difference between the two phases is $7\\\\times10^{8} kJ/m^{3}$, and the interfacial energy is $0.5 J/m^{2}$. If the strain energy of nucleation is neglected, calculate the critical nucleus size and the critical nucleation work for forming a cubic nucleus.", + "answer": "For a cubic nucleus, the critical edge length $a^{*}=-\\\\frac{4\\\\gamma}{\\\\Delta G_{V}}=\\\\frac{4\\\\times0.6}{7\\\\times10^{8}}m=3.428\\\\times10^{-9}m$. The critical nucleation work is $\\\\Delta G^{*}=\\\\frac{1}{3}\\\\gamma A^{*}=\\\\frac{1}{3}\\\\times6\\\\times(3.428\\\\times10^{-9})^{2}\\\\times0.6J=1.44\\\\times10^{-17}J$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和物理公式的使用，最终给出数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界核尺寸和临界形核功的计算方法，并应用相关公式进行综合分析。虽然题目提供了具体数值，但仍需理解公式背后的物理意义和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（吉布斯自由能差、界面能、临界核尺寸、临界成核功）并进行多步计算。题目要求考生能够将理论公式应用于具体几何形状（立方体核），并正确执行单位转换和代数运算。虽然题目提供了关键参数，但需要考生综合运用材料科学和热力学知识来推导和计算最终结果。" + }, + { + "idx": 51, + "question": "The chemical handbook lists the density of NH4Cl as 1.5 g/cm3. X-ray data indicate that NH4Cl has two crystal structures: one is the NaCl-type structure with a=0.726 nm, and the other is the CsCl structure with a=0.387 nm. To which crystal type does the above density value belong? (The NH4+ ion occupies the crystal lattice as a single unit).", + "answer": "Solution: If NH4Cl has the NaCl structure, the density can be calculated using the formula: rho = n / (N_A * V) * M. Thus, the calculation yields: rho = 4 / (6.02 * 10^23) * 52.5 / (0.726 * 10^-7)^3 = 0.912 g/cm3. If NH4Cl has the CsCl structure, the density can be calculated using the formula: rho = n / (N_A * V) * M. Thus, the calculation yields: rho = 1 / (6.02 * 10^23) * 52.5 / (0.387 * 10^-7)^3 = 1.505 g/cm3. The calculation shows that the density of the NaCl-type NH4Cl is close to the value given in the chemical handbook, so the density corresponds to the NaCl crystal type.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定密度对应的晶体类型，解答过程中涉及到了密度的计算公式和具体数值的代入计算。 | 知识层次: 题目需要进行多步计算，涉及晶体结构、密度公式的应用，以及不同晶体结构的比较分析。虽然计算过程相对直接，但需要理解晶体结构类型和密度计算的关系，并进行综合分析以确定正确的晶体类型。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构的概念，掌握密度计算公式，并进行多步计算和比较分析。虽然题目提供了部分数据，但需要考生自行选择正确的计算路径并验证结果，涉及多个知识点的综合应用。" + }, + { + "idx": 3691, + "question": "A 4-cm-diameter, 0.5-mm-thick spherical container made of BCC iron holds nitrogen at 700^{\\circ} C. The concentration at the inner surface is 0.05 atomic percent and at the outer surface is 0.002 atomic percent. Calculate the number of grams of nitrogen that are lost from the container per hour.", + "answer": "the nitrogen lost from the container per hour is 1.245 × 10^{-3} \\, \\text{g/h}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解氮气从容器中每小时流失的克数，答案是一个具体的数值结果。 | 知识层次: 题目涉及多步计算和概念关联，包括扩散方程的建立、浓度梯度的计算、扩散系数的确定以及单位转换等综合分析过程，需要将材料科学中的扩散理论与实际应用相结合。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散定律、浓度梯度、球形容器的几何参数计算等多个概念，并进行多步计算和综合分析。题目涉及温度、浓度差、材料厚度等变量，要求考生能够将这些因素整合起来解决问题。虽然题目提供了正确选项，但解题过程需要较强的应用能力和计算技巧。" + }, + { + "idx": 4759, + "question": "Compute the modulus of elasticity for the nonporous material given that the modulus of elasticity for spinel (MgAl2O4) having 5 vol% porosity is 240 GPa (35 x 10^6 psi).", + "answer": "the modulus of elasticity for the nonporous material is 265 gpa (38.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔材料的弹性模量，答案是一个具体的数值计算结果。 | 知识层次: 题目需要应用多孔材料弹性模量的计算公式，进行多步计算和概念关联，涉及孔隙率对材料性能的影响分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解孔隙率对弹性模量的影响，并应用相关公式进行多步计算。题目要求从已知多孔材料的弹性模量反推无孔隙材料的弹性模量，涉及概念关联和综合分析能力。虽然题目给出了正确选项，但解题过程需要掌握材料科学中孔隙率与力学性能的关系，并正确应用修正公式进行计算。" + }, + { + "idx": 2248, + "question": "For zinc in copper, c0=wZn=0.0001, E=-0.12 eV, calculate the critical temperature for solute segregation.", + "answer": "c=c0exp(-E/kT). When complete solute segregation occurs, c=wx=1, T=T∥s, 1=c0exp(-E/kT), then T∥⊥=-E/kln(1/c0). Substituting c0=wZn=0.0001, E=-0.12 eV=-1.602×10^-19×0.12 J, T∥∥=(1.602×10^-19×0.12)/(1.381×10^-23×ln(1/0.0001))=151 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及多个步骤的数学运算和物理常数的代入，最终得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括公式变换、单位转换和数值代入，涉及对溶质偏析临界温度概念的理解和公式应用。虽然计算过程较为直接，但需要综合运用多个知识点，如能量单位转换、对数运算等，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解溶质偏析的概念，掌握指数公式的变形应用，并进行多步单位换算和数值计算。题目涉及能量单位转换(eV→J)、对数运算和临界温度推导，虽然计算过程明确但步骤较多，对学生的公式应用和计算能力要求较高。" + }, + { + "idx": 2469, + "question": "For a silicon-containing low-alloy steel ingot with dendritic segregation and a dendrite arm spacing of 500μm, diffusion annealing is performed at 1200°C. To reduce the segregation amplitude to 10% of its original value, how long should the holding time be for carbon? Given that the diffusion coefficient of carbon in austenite at 1200°C is 2.23×10^(-6)cm^2/s.", + "answer": "When dendritic segregation exists, the solute composition is distributed with the dendrite arm spacing as the period, where the period l is 500μm=0.05cm. According to the trigonometric series solution of the diffusion equation, the concentration amplitude decays with a decay factor, i.e., C=C¯+C0sin(πx/l)exp(-π^2Dt/l^2). If the amplitude decays to 1/10 of its original value, then exp(-π^2Dt/l^2)=0.1. Therefore, the required time for carbon is: t=l^2/(π^2D)ln0.1=-(0.025)^2/(π^2×2.23×10^(-6))ln0.1s=65.3s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解所需的保温时间，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目需要进行多步计算，包括理解扩散方程的三角级数解、应用衰减因子公式、以及对数运算。虽然涉及的知识点较为明确，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的解法和浓度振幅衰减的概念，并进行多步计算。题目涉及三角函数解、指数衰减和时间计算，需要综合分析多个知识点才能得出正确答案。虽然计算步骤明确，但概念关联和公式应用要求较高，属于综合性计算问题。" + }, + { + "idx": 2348, + "question": "Assuming the atomic radius remains unchanged before and after the transformation, calculate the volume change of pure iron when it transforms from bcc to fcc structure at 17°C.", + "answer": "Assuming the atomic radius remains unchanged before and after the transformation, the volume change after the transformation is (a_f^3 - 2a_b^3)/(2a_b^3) = ((4r_f/√2)^3 - 2(4r_b/√3)^3)/(2(4r_b/√3)^3) = ((4/√2)^3 - 2(4/√3)^3)/(2(4/√3)^3) = -8.196%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及原子半径、晶体结构转变和体积变化的计算，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及晶体结构参数（bcc和fcc的晶格常数与原子半径的关系）的转换和体积变化的计算，需要综合应用相关公式和概念，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构转变的概念，掌握bcc和fcc晶格常数与原子半径的关系，并进行多步计算和综合分析。虽然题目给出了计算步骤，但需要考生具备较强的空间想象能力和数学计算能力，才能正确理解并应用公式。" + }, + { + "idx": 4764, + "question": "The flexural strength and associated volume fraction porosity for two specimens of the same ceramic material are as follows: \begin{tabular}{ll} \\hline (\\sigma_{f_{S}}(\\mathbf{M P a})) & (\boldsymbol{P}) \\ \\hline 70 & 0.10 \\ 60 & 0.15 \\ \\hline \\end{tabular} (b) Compute the flexural strength for a 0.20 volume fraction porosity.", + "answer": "the flexural strength for a 0.20 volume fraction porosity is 51.5 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的数据计算特定孔隙率下的弯曲强度，需要使用公式进行数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求基于给定的数据应用基本公式进行计算，属于直接套用公式的简单应用。虽然需要理解公式的含义，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解并应用一个基本公式来计算弯曲强度，但解题步骤相对直接，仅涉及简单的代数运算和公式套用。与更复杂的需要多个公式组合或深入概念分析的题目相比，此题的难度较低。" + }, + { + "idx": 3988, + "question": "Tensile strengths and number-average molecular weights for two polymers are as follows:\nTensile strength Number average molecular weight\n(MPa)\n(\\mathrm{g} / mol)\n37.7\n36800\n131\n62400\nEstimate the tensile strength (in MPa) for a number-average molecular weight of 51500g / mol.", + "answer": "the tensile strength for a number-average molecular weight of 51500g/mol is 95.2 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了两组拉伸强度和数均分子量的数据，要求根据这些数据估算另一个分子量下的拉伸强度。这需要通过数值计算和可能的插值或外推方法来完成。答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目要求根据给定的数据点进行简单的线性插值计算，属于基本公式的直接应用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要基本公式应用和简单计算。虽然涉及线性插值，但步骤明确且直接，属于简单公式应用计算。" + }, + { + "idx": 4853, + "question": "Consider a parallel-plate capacitor having an area of 3225 mm2 (5 in.2), a plate separation of 1mm (0.04 in.), and a material having a dielectric constant of 3.5 positioned between the plates. Compute the electric field that must be applied for 2 × 10−8 C to be stored on each plate.", + "answer": "the electric field that must be applied is 2.0 × 105 v/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及电容器的面积、板间距、介电常数等参数，最终需要计算出电场强度。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的电容公式应用和简单计算，如电容公式C=εA/d和电场强度E=V/d的直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。题目要求计算平行板电容器中的电场强度，涉及的基本公式为电容的定义式C=Q/V和电容与电场的关系式E=V/d。虽然需要应用两个公式，但步骤直接且计算简单，属于基础知识的直接应用。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2400, + "question": "In a Ni single crystal, there is a dislocation with Burgers vector b=a[0]12 on the (11T) plane. The lattice constant a=0.35 nm. What is the length of the dislocation's Burgers vector?", + "answer": "Solution: The Ni crystal has an fcc structure, and the Burgers vector b is of the [110]/2 type. Therefore, the length of the Burgers vector is b=a√2/2=0.35√2/2=0.254 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算位错的Burgers矢量的长度，需要通过给定的晶格常数和Burgers矢量的类型进行数值计算，最终得出具体的数值结果。答案中展示了具体的计算过程和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式应用和简单计算，即通过已知的晶格常数和Burgers向量的类型直接套用公式计算其长度。虽然需要理解Burgers向量的类型和fcc结构的基本知识，但整体思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要知道fcc结构中Burgers vector的类型和计算公式，但解题步骤相对直接，仅需套用公式b=a√2/2并进行简单计算即可得出答案。不需要多个公式组合或复杂的概念分析，因此在选择题型内属于等级2难度。" + }, + { + "idx": 4270, + "question": "To provide some perspective on the dimensions of atomic defects, consider a metal specimen that has a dislocation density of 10^4 mm^-2. Suppose that all the dislocations in 1000 mm^3 (1 cm^3) were somehow removed and linked end to end. How far (in miles) would this chain extend?", + "answer": "for a dislocation density of 10^4 mm^-2, the chain would extend 6.2 miles.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定位错链的总长度并将其转换为英里单位。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式应用和简单计算，需要将位错密度转换为总长度，并进行单位换算，思维过程较为直接，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解位错密度的概念，但解题步骤相对直接，只需套用给定的位错密度和体积进行简单计算即可得出结果。不需要多个公式组合或复杂的分析过程，因此属于等级2。" + }, + { + "idx": 2616, + "question": "The atomic number of copper is 29, its relative atomic mass is 63.54, and it has two isotopes, Cu63 and Cu65. Calculate the percentage content of the two copper isotopes.", + "answer": "$A{\\\\mathrm{r}}=63.54=63x+65\\\\times(1-x);\\\\quad x={\\\\frac{65-63.54}{2}}=0.73\\\\rightarrow73\\\\mathcal{V}_{0}\\\\left(\\\\mathrm{Cu}^{\\\\mathrm{63}}\\\\right);$ $1-x=0.27\\\\substack{\\\\rightarrow27\\\\%(\\\\mathrm{Cu}^{65})}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解两种铜同位素的百分比含量，答案展示了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式应用和简单计算，通过给定的原子质量和同位素信息直接套用公式求解百分比含量，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及同位素百分比的计算，但解题步骤明确且直接，只需套用给定的相对原子质量公式并进行简单的代数运算即可得出答案。不需要复杂的推理或多步骤的公式组合，因此难度等级为2。" + }, + { + "idx": 3715, + "question": "A force of 20,000 N will cause a 1 cm × 1 cm bar of magnesium to stretch from 10 cm to 10.045 cm. Calculate the modulus of elasticity in psi.", + "answer": "the modulus of elasticity is 6.44 × 10^6 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁棒的弹性模量，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本的弹性模量计算公式，进行简单的数值计算和单位转换，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解弹性模量的概念并应用公式E = (F/A)/(ΔL/L)，但计算步骤相对直接，且题目提供了所有必要的数据。不需要多个公式组合或复杂的转换，因此难度等级为2。" + }, + { + "idx": 1953, + "question": "2. Please calculate the angle between (111) and (111) in a simple cubic crystal.", + "answer": "$${{\\\\cos\\\\alpha=\\\\frac{h_{1}h_{2}+k_{1}k_{2}+l_{1}l_{2}}{\\\\sqrt{h_{1}^{2}+k_{1}^{2}+l_{1}^{2}\\\\sqrt{h_{2}^{2}+k_{2}^{2}+l_{2}^{2}}}}\\\\mathrm{\\\\textstyle=\\\\frac{1-1+1}{\\\\sqrt{3}\\\\times\\\\sqrt{3}}=\\\\frac{1}{3}}}}\\\\ {{\\\\alpha=70^{\\\\circ}32^{\\\\prime}\\\\quad\\\\qquad\\\\quad}}\\\\end{array} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算简单立方晶体中(111)和(111)晶面之间的夹角，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用基本的晶体学公式计算晶面夹角，属于直接套用公式的简单计算类型，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要套用晶面夹角公式并进行简单计算，但步骤明确且直接，无需多个公式组合或复杂推导。正确选项已提供完整计算过程，学生只需理解基本公式的应用即可完成。" + }, + { + "idx": 2287, + "question": "Calculate the average stress σf of β-SiC whiskers when the critical length is not reached, given the matrix yield strength σy=76MPa, fiber length L=70μm, and diameter df=0.5μm.", + "answer": "For β-SiC whiskers, the average stress σf = (τy × L) / df = (σy × L) / (2 × df) = (76 × 70×10^-6) / (2 × 0.5×10^-6) = 5320MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，给出了具体的参数和计算公式，最终需要得出一个具体的数值结果。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及纤维增强复合材料的应力传递机制，但计算过程较为直接，仅需套用给定公式进行数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解基本概念（如临界长度未达到时的平均应力计算公式），但解题步骤相对直接，仅需套用单一公式并进行简单单位换算和代数运算。不需要组合多个公式或进行复杂分析，因此属于等级2难度。" + }, + { + "idx": 4257, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 275 MPa (40,000 psi), and the modulus of elasticity is 115 GPa (16.7 x 10^6 psi). If the original specimen length is 115mm (4.5 in.), what is the maximum length to which it may be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen may be stretched without causing plastic deformation is 115.28mm (4.51 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性模量和应力-应变关系）来确定最大拉伸长度，答案是一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即利用弹性模量和应力计算最大弹性变形长度，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解塑性变形开始时的应力和弹性模量的概念，但解题步骤相对直接，只需应用胡克定律（Hooke's Law）进行简单的应变计算，然后转换为长度变化。不需要复杂的分析或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 2283, + "question": "Calculate the fiber stress σf of Al2O3 short fibers when the length exceeds the critical length, given the fiber tensile strength σfa=2275MPa, critical length Lc=299.3μm, and actual length L=4mm.", + "answer": "For Al2O3 short fibers, the fiber stress σf = (1 - Lc/(2L)) × σfa = (1 - 299.3×10^-6/(2 × 4000×10^-6)) × 2275 = 2190MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和单位转换，最终给出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，虽然需要理解临界长度的概念，但整体思维过程较为直接，属于基本公式套用和数值计算的范畴。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解临界长度和实际长度的概念，但解题步骤仅涉及直接套用一个明确的公式（σf = (1 - Lc/(2L)) × σfa），并进行简单的单位换算和代数运算。不需要多个公式组合或复杂的推导过程，因此难度等级为2。" + }, + { + "idx": 2695, + "question": "Calculate the theoretical density of α-Fe (given a=0.286nm for α-Fe, Ar(Fe)=55.85, NA=6.023×10²³)", + "answer": "ρtheoretical=2×Ar(Fe)/(a³×NA)=2×55.85/((2.86×10⁻⁸)³×6.023×10²³)=7.9276(g/cm³)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（晶格常数a、原子量Ar、阿伏伽德罗常数NA）和公式（理论密度计算公式）进行数值计算，最终得出具体的密度值7.9276g/cm³，符合计算题的特征。 | 知识层次: 题目要求应用基本公式进行简单计算，涉及晶体结构参数和密度的直接套用，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用密度计算公式，但步骤较为直接，仅涉及单一公式的代入和简单数值计算，无需复杂的推导或多步骤分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3686, + "question": "When a Cu-Zn alloy solidifies, one portion of the structure contains 25 atomic percent zinc and another portion 0.025mm away contains 20 atomic percent zinc. The lattice parameter for the FCC alloy is 3.63 x 10^-8 cm. Determine the concentration gradient in (a) atomic percent Zn per cm.", + "answer": "-2000 at% zn/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，要求确定浓度梯度，答案是一个具体的数值结果。 | 知识层次: 题目主要涉及浓度梯度的基本计算，需要应用简单的公式和单位转换，属于直接套用基本知识的范畴。虽然涉及单位转换和距离计算，但整体思维过程较为直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察基本公式应用和简单计算能力。题目要求计算浓度梯度，只需套用浓度梯度公式（ΔC/Δx）并进行单位转换即可得出答案。虽然涉及单位换算，但步骤直接且无需复杂推导，因此在选择题型中属于等级2难度。" + }, + { + "idx": 3678, + "question": "Determine the ASTM grain size number if 25 grains/square inch are observed at a magnification of 50 .", + "answer": "the astm grain size number is n = 3.6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数，答案是一个具体的数值结果（n = 3.6），这表明解答过程涉及计算步骤。 | 知识层次: 题目要求应用ASTM晶粒度计算公式进行简单计算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用ASTM grain size number的计算公式，但题目已经提供了所有必要的数据（25 grains/square inch和50倍放大倍数），只需直接套用公式即可得出结果。解题步骤相对简单，不需要复杂的推导或多步骤计算，因此属于等级2难度。" + }, + { + "idx": 4266, + "question": "A cylindrical metal specimen having an original diameter of 12.8mm (0.505 in.) and gauge length of 50.80mm (2.000 in.) is pulled in tension until fracture occurs. The diameter at the point of fracture is 6.60mm (0.260 in.), and the fractured gauge length is 72.14mm (2.840 in.). Calculate the ductility in terms of percent reduction in area.", + "answer": "the ductility in terms of percent reduction in area is 73.4%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解材料的延展性（以面积减少百分比表示），需要根据给定的原始尺寸和断裂后尺寸进行计算，最终得出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过原始直径和断裂后的直径计算面积减少百分比。虽然需要理解延展性的概念，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察基本公式应用和简单计算。虽然需要计算原始和断裂后的横截面积，但步骤较为直接，仅涉及单一公式（面积计算和百分比减少公式）的套用，无需多个公式组合或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 1969, + "question": "Please compare the distortion energy of the two dislocations b1= a/2[111] and b2=a[100] in FCC crystals, which one is greater.", + "answer": "∣b₁∣=a/2√(1+1+1)=√3/2a ∣b₂∣=a√(1+0+0)=a Therefore, the distortion energy of b1 is smaller.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算两个位错的畸变能并进行比较，解答过程中涉及数值计算和公式应用（如计算位错矢量的模），最终通过计算结果得出比较结论。 | 知识层次: 题目涉及基本的矢量长度计算和公式应用，属于简单计算和直接套用类型，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算两个位错的畸变能并进行比较，但仅涉及基本的矢量模长公式和简单比较，无需复杂推导或多步骤计算。正确选项直接给出了计算过程和结论，符合等级2的标准。" + }, + { + "idx": 2882, + "question": "Assuming we add Na2O with w(Na2O)=10% to SiO2, please calculate the ratio of oxygen to silicon.", + "answer": "There are 90at% SiO2 and 10at% Na2O, so O:Si = (0.9×2 + 0.1) : 0.9 = 2.111. Since O:Si = 2.111 < 2.5, there is a good tendency for glass formation.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算氧与硅的比例），并应用了化学计量公式。答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需将给定的百分比转换为原子百分比并进行简单的比例计算，无需多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目涉及基本公式应用和简单计算，仅需理解氧硅比的概念并进行直接套用计算，无需复杂步骤或多公式组合。" + }, + { + "idx": 197, + "question": "The surface tension of alumina under vacuum is approximately $0.9\\\\mathrm{N/m}$, the surface tension of liquid iron is $1.72\\\\mathrm{N/m}$, and the interfacial tension between liquid iron and alumina under the same conditions is $2.3\\\\mathrm{N/m}$. What is the contact angle? Can liquid iron wet alumina?", + "answer": "$$\\\\cos\\\\theta=\\\\frac{\\\\gamma_{s v}-\\\\gamma_{s l}}{\\\\gamma_{b}}=\\\\frac{0.9-2.3}{1.72}=0.814,\\\\theta=144.5^{0}>90^{\\\\circ},B T\\\\cup\\\\gamma_{\\\\mathrm{SRE}}\\\\times1875^{\\\\circ}$$ So it cannot wet.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解接触角，并判断液体铁是否能润湿氧化铝。答案中包含了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及表面张力和接触角的基本公式应用，通过直接套用公式进行计算即可得出结果，不需要多步计算或综合分析。虽然需要理解表面张力和接触角的概念，但整体思维过程较为直接和简单。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解表面张力和接触角的概念，但解题步骤相对直接，只需套用给定的公式进行计算即可得出答案。不需要复杂的分析或多步骤推理，因此难度等级为2。" + }, + { + "idx": 3605, + "question": "Determine the packing fraction for BCC lithium in the (100) plane.", + "answer": "packing fraction = 0.589", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算BCC锂在(100)面的堆积分数，需要应用晶体结构相关的公式进行数值计算，最终给出一个具体的数值结果（0.589）。 | 知识层次: 题目要求计算BCC锂在(100)面的堆积分数，这需要应用基本的晶体学公式和几何关系，属于直接套用公式和简单计算的范畴。虽然需要理解BCC结构和堆积分数的概念，但计算过程相对直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解BCC结构在(100)平面的原子排列方式，但主要涉及基本公式的直接套用（计算平面原子密度与晶格参数的关系），解题步骤相对简单，属于选择题型中中等偏下的难度水平。" + }, + { + "idx": 4710, + "question": "What is the composition, in atom percent, of an alloy that consists of 5.5 wt% \\mathrm{~Pb} and 94.5 wt% \\mathrm{Sn} ?", + "answer": "the composition of the alloy is 3.23 \\text{ at% pb} and 96.77 \\text{ at% sn}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如原子百分比的计算）来确定合金的组成，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的重量百分比到原子百分比的转换计算，需要应用简单的公式和原子量数据，属于直接套用基本公式的简单计算题。 | 难度: 在选择题型内，该题目属于简单公式应用计算。虽然需要应用原子百分比和重量百分比之间的转换公式，但计算步骤相对直接，仅涉及基本公式的套用和简单代数运算。不需要多个公式的组合或复杂的推导过程，因此难度等级为2。" + }, + { + "idx": 2023, + "question": "A solid solution contains xMgO=30/10−2 and xLiF=70/10−2. What are the mass fractions of Li+, Mg2+, F−, and O2−?", + "answer": "wLi+=16/10−2, wMg2+=24/10−2, wF−=44/10−2, wO2−=16/10−2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算得出各离子的质量分数，需要应用化学计量和质量分数的计算公式，答案以具体数值形式给出。 | 知识层次: 题目涉及基本公式应用和简单计算，需要将摩尔分数转换为质量分数，属于直接套用公式的计算题，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用质量分数的基本公式，但计算步骤直接且无需复杂转换。题目提供了摩尔分数，只需简单转换为质量分数，属于选择题中较为基础的题型。" + }, + { + "idx": 4208, + "question": "Show that the atomic packing factor for BCC is 0.68 .", + "answer": "the atomic packing factor for bcc is 0.68.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算证明BCC结构的原子堆积因子为0.68，需要应用几何关系和数学计算来求解 | 知识层次: 题目要求计算BCC结构的原子堆积因子，涉及基本公式应用和简单计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解BCC（体心立方）结构的原子堆积因子概念，但计算过程仅涉及基本几何关系和简单算术运算（如球体积与晶胞体积的比例计算），无需复杂推导或多步骤组合。选择题型中只需识别正确计算结果，因此属于等级2。" + }, + { + "idx": 3956, + "question": "A steel bar 100mm (4.0 in.) long and having a square cross section 20mm (0.8 in.) on an edge is pulled in tension with a load of 89,000N\\left(20,000 lb_{0}\\right), and experiences an elongation of 0.10mm (4.0 × 10^{-3} in.). Assuming that the deformation is entirely elastic, calculate the elastic modulus of the steel.", + "answer": "the elastic modulus of the steel is 223 \\text{ gpa} (31.3 × 10^6 \\text{ psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钢的弹性模量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求应用胡克定律进行简单的弹性模量计算，仅涉及基本公式的直接套用和单步数值计算，不需要多步推导或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用弹性模量的基本公式（应力/应变），但计算步骤较为直接，仅涉及简单的单位转换和代数运算。题目提供了所有必要的数据，且变形假设为完全弹性，无需考虑复杂情况。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 259, + "question": "Calculate the diffusion coefficient of carbon in α-Fe (body-centered cubic), given the diffusion coefficient formula as D=0.0079exp[-83600/RT] cm²/s, temperature T=800°C (1073K), and gas constant R=8.314 J/(mol·K).", + "answer": "Substitute T=1073K into the formula D=0.0079exp[-83600/(8.314×1073)] cm²/s, and calculate to obtain D_α=6.7×10^-7 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目主要涉及直接套用给定的扩散系数公式进行数值计算，无需多步推理或综合分析，属于基本公式应用和简单计算范畴。 | 难度: 在选择题型中，该题目仅需要直接套用给定的扩散系数公式，并进行简单的数值计算。解题步骤非常直接，不涉及多个公式的组合或复杂的概念理解，因此属于单一公式直接计算的难度等级1。" + }, + { + "idx": 4167, + "question": "Chromium has four naturally-occurring isotopes: 4.34% of { }^{50} \\mathrm{Cr}, with an atomic weight of 49.9460 amu, 83.79% of { }^{52} \\mathrm{Cr}, with an atomic weight of 51.9405 amu, 9.50% of { }^{53} \\mathrm{Cr}, with an atomic weight of 52.9407 amu, and 2.37% of { }^{54} \\mathrm{Cr}, with an atomic weight of 53.9389 amu. On the basis of these data, confirm that the average atomic weight of \\mathrm{Cr} is 51.9963 amu.", + "answer": "the average atomic weight of \\mathrm{cr} is 51.9963 \\, amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的同位素丰度和原子质量数据，通过计算确认铬的平均原子质量。解答过程需要应用加权平均公式进行数值计算，最终验证给定的平均原子质量是否正确。答案的形式是数值计算结果，而非选择、判断或文字解释。 | 知识层次: 题目要求基于给定的同位素丰度和原子质量，通过简单的加权平均计算来确认铬的平均原子质量。这属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据给定的同位素丰度和原子质量计算铬的平均原子质量，只需要套用平均原子质量的计算公式（各同位素的质量乘以其丰度后相加）即可得出结果。解题步骤简单直接，无需复杂的推理或多步骤计算，因此属于最低难度等级。" + }, + { + "idx": 1758, + "question": "When n spheres form a cubic close packing, what is the number of octahedral voids?", + "answer": "n", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算立方密堆积中八面体空隙的数量，需要应用材料科学中的晶体结构知识进行数值计算，答案是一个具体的数值(n)。 | 知识层次: 题目需要应用立方密堆积中八面体空隙数量的基本公式，属于直接套用已知知识进行简单计算的情况，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目直接考察立方密堆积中八面体空隙数量的基本公式应用（n个球体对应n个八面体空隙），无需任何计算或推导过程，仅需记忆或识别这一基本知识点即可作答。" + }, + { + "idx": 4162, + "question": "A beam of light is shined on a thin (sub-millimeter thick) single crystal wafer of material. The light source is special since it can be tuned to provide any wavelength of visible light on demand. The specimen is illuminated such that the frequency of light is decreased over time while the transmitted intensity of the light is measured. If the sample becomes transparent when the frequency is less than [F] THz, what is the band gap of the material, in eV? Assume that an intrinsic excitation of electrons is responsible for the absorption.", + "answer": "the band gap of the material is 4.135 × 10^{-3} [f] ev.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（将频率转换为电子伏特）来确定材料的带隙，答案是一个具体的数值计算结果。 | 知识层次: 题目主要涉及基本公式应用和简单计算，即通过给定的频率计算材料的带隙能量。虽然需要理解带隙与光频率之间的关系，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据给定的频率计算材料的带隙，只需应用基本公式E = hν（其中h是普朗克常数，ν是频率）进行简单转换即可得到正确答案。解题步骤非常直接，无需复杂的推导或多步骤计算，符合等级1的标准。" + }, + { + "idx": 3190, + "question": "In the symmetric tilt grain boundary of face-centered cubic metal $\\\\mathrm{Cu}$, the spacing between two positive edge dislocations is $D=1000\\\\mathrm{nm}$. Assuming the extra half-plane of the edge dislocation is the (110) plane and $d_{110}=0.1278\\\\mathrm{~nm}$, find the tilt angle $\\\\theta$ of the tilt grain boundary.", + "answer": "The unit dislocation of the face-centered cubic structure is $b=\\\\frac{a}{2}\\\\langle110\\\\rangle$. Since the {110} plane has an extra atomic plane, $b=2d_{110}=2\\\\times0.1278=0.2556\\\\mathrm{nm}$. The tilt angle $\\\\theta$ of the tilt grain boundary can be calculated using the following deformation formula: $$ \\\\theta\\\\approx\\\\frac{b}{D}=\\\\frac{0.2556}{1000}=2.556\\\\times10^{-4}\\\\times\\\\frac{180}{\\\\pi}\\\\approx0.0146^{\\\\circ} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解倾斜角θ，答案中给出了具体的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过已知的位错间距和晶面间距计算倾斜角度，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式进行计算，即通过已知的位错间距和位错矢量计算倾斜角度。解题步骤简单，无需复杂的推理或多步骤计算，属于最基础的难度等级。" + }, + { + "idx": 2275, + "question": "Referring to the composite material in the previous question. Given that the elastic modulus of steel is 205 GPa and the elastic modulus of copper is 110 GPa. What is the elastic modulus of this composite material?", + "answer": "E=(φE)st+(φE)cu=0.25×(205000 MPa)+0.75×(110000 MPa)=130000 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的弹性模量和体积分数进行数值计算，并应用混合法则公式来求解复合材料的弹性模量。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，只需要将给定的弹性模量和体积分数代入公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的复合弹性模量公式（E=(φE)st+(φE)cu），并进行简单的数值代入和计算。无需理解多个概念或进行复杂的分析，属于单一公式直接计算的难度等级。" + }, + { + "idx": 2651, + "question": "Given that pure titanium at 900°C is β-Ti (bcc structure) with a lattice constant a=0.3307nm, calculate the (001) interplanar spacing.", + "answer": "For the (001) plane of bcc structure, d_(001)=1/2×a/√1²=1/2×0.3307/1=0.1653nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算(001)晶面间距），并应用了晶体学公式（d_(001)=a/√(h²+k²+l²)），答案是一个具体的计算结果（0.1653nm）。这符合计算题的特征。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及晶体学中晶面间距的计算，属于基础知识的直接运用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即d_(001)=1/2×a/√1²，无需额外的概念理解或步骤组合。属于最基础的难度等级。" + }, + { + "idx": 28, + "question": "In MgS, the unit cell parameter a=0.5201 nm, and the anions are in contact with each other. Calculate the radius of S2-.", + "answer": "In MgS, a=0.5201 nm, and the anions are in contact with each other, a=2√2 r-, thus rS2-=0.5201 nm / (2√2) = 0.177 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，具体涉及单位晶胞参数和离子半径的计算，答案也是通过数学运算得出的具体数值。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过给定的晶胞参数和几何关系（a=2√2 r-）来计算离子半径，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（a=2√2 r-）进行计算，解题步骤简单且直接，无需多个公式组合或复杂分析。属于最基础的难度等级。" + }, + { + "idx": 4262, + "question": "Compute the elastic modulus for carbon steel, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(d) the elastic modulus for carbon steel is 215 gpa, which is in reasonable agreement with the value of 207 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出碳钢的弹性模量，并与参考表中的数值进行比较。虽然答案给出了具体数值，但解题过程需要基于应力-应变曲线进行计算，符合计算题的特征。 | 知识层次: 题目要求计算碳钢的弹性模量，并将计算结果与参考表中的数值进行比较。这主要涉及基本的应力-应变关系理解和简单的数值计算，属于直接套用基本公式和简单比较的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型内，该题目仅需要直接应用给定的弹性模量数值进行比较，无需任何计算或复杂分析。属于单一公式直接计算的简单应用层次，是最基础的难度等级。" + }, + { + "idx": 4132, + "question": "A 10 meter long square bar of 316 stainless steel (edge length of 5 cm, with a modulus of 193 \\mathrm{GPa} and a yield point of 290 MPa ) is bolted securely in place when its installation temperature was around [1]^{\\circ} C. What is the expected thermal stress in the bar when its service temperature reaches [F]^{o} C ? Enter a negative indicate compressive stress, if necessary. The thermal expansion coefficient of 316 stainless steel is 16.0 × 10^{-6} \\mathrm{I} /{ }^{\\circ} C.", + "answer": "sigma_{th} = (193,000)(16 × 10^{-6})([i] - [f]) MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解热应力，答案给出了具体的计算公式和单位，需要代入数值进行计算。 | 知识层次: 题目主要考查热应力公式的直接应用，仅需代入给定参数进行简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了所有必要的参数和公式，只需要将给定的数值代入公式即可得到答案。不需要额外的推导或组合多个公式，解题步骤简单直接。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1785, + "question": "Pb has a face-centered cubic structure with an atomic radius of 0.1750 nm. Calculate the volume of its unit cell.", + "answer": "V = a³ = (2√2r)³ = 0.1212 nm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用原子半径计算面心立方结构的晶胞体积）来得出具体数值结果，答案也是一个具体的计算结果。 | 知识层次: 题目考查基本公式应用和简单计算，直接套用面心立方结构的边长与原子半径关系公式（a = 2√2r）并进行立方计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（V = a³ = (2√2r)³）进行计算，无需额外的公式组合或复杂步骤。属于最基础的难度等级，适合考察学生对基本公式的理解和简单应用能力。" + }, + { + "idx": 2415, + "question": "If the Burgers vector magnitude of a grain boundary dislocation is 0.253nm, what is the misorientation between the two sides of the grain boundary?", + "answer": "The misorientation between the two grains at the grain boundary is θ = b/D = (0.253 × 10^-9)/(10 × 10^-6) × (180/π) = 1.45 × 10^-3 degrees.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解晶界两侧的取向差，答案给出了具体的计算过程和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的Burgers向量大小和晶界间距计算晶界两侧的取向差。虽然需要理解Burgers向量和晶界取向差的概念，但计算过程相对直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（θ = b/D）并进行简单计算，无需理解多个概念或进行复杂分析。属于最基础的难度等级。" + }, + { + "idx": 2028, + "question": "Assuming the density of MgO is 3.6 g/cm3 and the density of LiF is 2.6 g/cm3, what is the density of the solid solution?", + "answer": "The density of the solid solution ρ=2.9 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目给出了具体材料的密度数据，要求通过计算得出固溶体的密度。解答过程需要应用密度计算公式，最终给出数值结果。这符合计算题的特征。 | 知识层次: 题目需要应用密度计算公式进行简单计算，属于基本公式的直接套用，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用密度计算公式，属于单一公式直接计算的简单应用。题目提供了所有必要的数据，解题步骤简单明了，无需复杂的推理或多步骤计算，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 3637, + "question": "Based on the cesium chloride structure, determine the lattice parameter for CsBr.", + "answer": "The lattice parameter a0 = 4.1916 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于氯化铯结构确定CsBr的晶格参数，需要通过数值计算和公式应用来得出具体数值结果（4.1916 Å）。答案是一个具体的计算值，而非选择、判断或文字解释。 | 知识层次: 题目要求基于氯化铯结构计算CsBr的晶格参数，属于基本公式应用和简单计算，直接套用已知结构和计算方法即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行单一计算，属于最基础的难度等级。题目明确给出了结构类型（cesium chloride结构），并直接要求计算晶格参数，无需额外的概念理解或复杂的解题步骤。" + }, + { + "idx": 4226, + "question": "The metal iridium has an FCC crystal structure. If the angle of diffraction for the (220) set of planes occurs at 69.22 degrees (first-order reflection) when monochromatic x-radiation having a wavelength of 0.1542 nm is used, compute the interplanar spacing for this set of planes.", + "answer": "the interplanar spacing for the (220) set of planes for iridium is 0.1357 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（布拉格定律）来求解晶面间距，答案是一个具体的数值结果（0.1357 nm），符合计算题的特征。 | 知识层次: 题目主要涉及布拉格定律的直接应用，通过给定的衍射角和波长计算晶面间距。虽然需要理解布拉格定律和晶面间距的概念，但计算过程相对直接，属于基本公式应用和简单计算范畴。 | 难度: 在选择题型中，该题目仅需要直接应用布拉格公式（nλ = 2d sinθ）进行一步计算即可得出答案。题目已经给出了所有必要的参数（衍射角、波长、反射级数），无需额外的推导或组合公式。因此，在选择题型内属于最简单的难度等级1。" + }, + { + "idx": 3216, + "question": "Given: The critical nucleus size of aluminum r*=94.5 nm, atomic volume V0=1.66×10^-29 m^3. Calculate the number of atoms Nr* in a nucleus with radius r*.", + "answer": "Nr* = (4/3 π r*^3) / V0 = (4/3 π × (94.5 × 10^-9)^3) / (1.66 × 10^-29) = 2.12 × 10^8", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的临界核尺寸和原子体积计算核中的原子数量，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即使用球形体积公式除以原子体积来得到原子数量。解题步骤简单，无需组合多个公式或进行复杂的概念分析，属于最基础的直接计算类型。" + }, + { + "idx": 185, + "question": "At high temperature, a metal is melted on an Al2O3 plate. If the liquid surface energy is only half of the Al2O3 surface energy, while the interfacial energy is twice the Al2O3 surface tension, estimate the size of the contact angle?", + "answer": "Substituting the known data into the Young's equation, cosθ=(0.5−1)/0.5=−1, the contact angle can be calculated to be approximately 180 degrees.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用（使用Young's方程计算接触角），答案给出了具体的计算过程和结果（180度）。 | 知识层次: 题目主要涉及Young's方程的直接应用和简单的数值计算，不需要多步推理或综合分析，属于基本公式的直接套用。 | 难度: 在选择题型内，该题目属于单一公式直接计算的难度等级。题目直接给出了所有必要的数据，只需将已知数值代入Young's方程（cosθ=(γSV - γSL)/γLV）即可得出结果。解题步骤简单明了，无需额外的概念理解或复杂的计算过程，符合等级1的定义。" + }, + { + "idx": 3676, + "question": "For an ASTM grain size number of 8, calculate the number of grains per square inch with no magnification.", + "answer": "1.28 × 10^6 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算晶粒数量），并给出了具体的计算公式和答案形式（1.28 × 10^6 grains/in.^2），符合计算题的特征。 | 知识层次: 题目要求根据ASTM晶粒度标准直接应用公式计算单位面积内的晶粒数量，属于基本公式的直接应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求根据ASTM晶粒度编号8直接套用公式计算每平方英寸的晶粒数量，无需额外的推导或组合多个公式。解题步骤简单，仅需应用基本公式并进行简单计算，因此属于最低难度等级。" + }, + { + "idx": 3206, + "question": "A Cu-30%Zn brass cold-rolled sheet undergoes 25% cold deformation, resulting in a thickness of 1cm. Find the original thickness Lo.", + "answer": "From (Lo - 1)/Lo = 25%, solving gives Lo = 4/3 cm ≈ 1.333 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解原始厚度Lo，答案是通过数学计算得出的具体数值结果。 | 知识层次: 题目仅涉及基本的百分比变形计算和简单代数运算，属于直接套用公式和基本计算的应用层次，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，即通过给定的变形百分比和最终厚度求解原始厚度。解题步骤简单，仅需一步代数运算即可得出答案，无需组合多个公式或进行复杂分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4168, + "question": "How many grams are there in one amu of a material?", + "answer": "1.66 x 10^-24 g/amu", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（1 amu转换为克），答案是一个具体的数值结果（1.66 x 10^-24 g/amu），属于典型的计算题特征。 | 知识层次: 题目仅涉及基本单位换算（amu到克）的直接计算，仅需套用已知的换算系数1.66 x 10^-24 g/amu，无需多步计算或概念关联，属于基础公式的直接应用。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用（1 amu = 1.66 x 10^-24 g），无需任何额外的计算步骤或概念组合。学生只需记住或识别这一基本换算关系即可选择正确答案，属于最基础的难度等级。" + }, + { + "idx": 4236, + "question": "The concentration of carbon in an iron-carbon alloy is 0.15 wt%. What is the concentration in kilograms of carbon per cubic meter of alloy?", + "answer": "the concentration of carbon in the alloy is 11.8 \\mathrm{kg/m^{3}}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定碳在合金中的浓度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行基本的单位转换和公式应用（浓度换算），但计算过程较为直接，仅涉及单一概念的应用，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用和简单计算，即直接将给定的重量百分比转换为千克每立方米的浓度。解题步骤简单，无需复杂的推导或多步骤计算，属于最基础的难度等级。" + }, + { + "idx": 1244, + "question": "According to the phase rule, what is the degree of freedom when the number of equilibrium phases in a binary system is at its maximum?", + "answer": "18", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律计算二元系统中平衡相数最大时的自由度，需要应用公式进行数值计算，答案是一个具体的数值(18)，符合计算题的特征。 | 知识层次: 题目考查相律公式的直接应用，仅需将二元系统的最大平衡相数代入公式进行简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于最简单难度等级。题目直接考察对相律公式（F = C - P + 2）的简单套用，在二元系统中最大平衡相数时（P=3），只需将数值代入公式即可得出自由度F=1。不需要任何额外的推导或复杂计算，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 2256, + "question": "During the solid-state phase transformation, assuming the nucleation rate $\\\\dot{N}$ and growth rate $G$ of the new phase are constants, the volume fraction of the new phase formed after time $t$ can be obtained using the Johnson-Mehl equation, i.e., $$ \\\\begin{array}{r}{\\\\varphi=1-\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)}\\\\end{array}$$ Given the nucleation rate $\\\\dot{N}=1~000/(\\\\mathrm{cm}^{3}\\\\bullet\\\\mathrm{s}),G=3\\\\times10^{5}~\\\\mathrm{cm/s},$ calculate the maximum transformation rate during the phase transformation.", + "answer": "$$ \\\\frac{\\\\mathrm{d}\\\\varphi}{\\\\mathrm{d}t}=\\\\left(\\\\frac{4}{3}\\\\pi\\\\dot{N}G^{3}t^{3}\\\\right)\\\\exp\\\\left(-\\\\frac{\\\\pi}{3}\\\\dot{N}G^{3}t^{4}\\\\right)$$ Substitute $t_{\\\\mathrm{max}}=403$ into the above equation to calculate the maximum transformation rate.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，通过给定的参数和公式计算出最大转变速率，答案也给出了具体的计算步骤和结果。 | 知识层次: 题目需要应用Johnson-Mehl方程进行多步计算，包括求导和数值代入，涉及对相变动力学的基本理解和公式的综合应用，但不需要复杂的推理或深度分析。 | 难度: 在选择题中属于中等难度，需要理解Johnson-Mehl方程并正确求导得到转化速率表达式，然后代入给定参数进行多步计算。题目涉及中等应用层次的知识点，要求综合分析和多步计算能力。" + }, + { + "idx": 3841, + "question": "Calculate the total amount of alpha and beta in a Pb-50% Sn alloy at 182°C.", + "answer": "total amount of alpha = 60.5%, beta = 39.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算alpha和beta的含量百分比），答案以具体数值形式给出，需要使用相图或相关公式进行计算。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及杠杆定律的应用和相组成分析，需要将概念关联并进行综合分析，但不需要复杂的机理推导或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律应用并进行多步计算。题目要求计算特定温度下两相比例，涉及查找相图关键点、成分转换和百分比计算，但选择题型提供了正确选项降低了部分推导难度。" + }, + { + "idx": 4666, + "question": "Cobalt (Co) has an HCP crystal structure, an atomic radius of 0.1253nm, and a c/a ratio of 1.623. Compute the volume of the unit cell for Co.", + "answer": "the volume of the unit cell for co is 6.64 × 10^{-23} {cm}^3 or 6.64 × 10^{-2} nm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解钴的单位晶胞体积，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求计算HCP晶胞体积，涉及基本公式应用和简单计算，属于直接套用公式的简单应用层次。虽然需要理解HCP结构和相关参数，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用HCP晶体结构的体积计算公式，但题目已经提供了所有必要的参数（原子半径和c/a比），计算过程直接且无需复杂推导。学生只需正确代入公式并完成单位转换即可得到答案，属于基础层次的应用题。" + }, + { + "idx": 25, + "question": "In CaO, the unit cell parameter a=0.480 nm, and the anions and cations are in contact with each other. Find the radius of O2-. The radius of Ca2+ is known to be 0.107 nm.", + "answer": "In CaO, a=0.480 nm, and the anions and cations are in contact with each other. a=2(r+ + r-), therefore rO2-=(0.480 nm / 2) - 0.107 nm = 0.097 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数和公式进行数值计算，最终得出O2-的半径。解答过程涉及单位换算和简单的代数运算，符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要直接套用已知的半径和晶格参数关系公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。题目直接给出了单位晶胞参数和离子半径的关系公式（a=2(r+ + r-)），只需简单代入已知数值进行计算即可得出答案。虽然需要理解离子半径的概念和晶胞参数的关系，但解题步骤直接且无需复杂的推理或组合多个公式，因此在选择题型内属于等级2难度。" + }, + { + "idx": 1989, + "question": "Calculate the shear stress required for slip to occur in a nickel crystal with this F-R dislocation source. Given that for Ni, G=7.9×10^10 Pa, a=0.350 nm.", + "answer": "τ_Ni=1.95×10^7 Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算镍晶体中滑移所需的剪切应力），并给出了具体的材料参数（G=7.9×10^10 Pa, a=0.350 nm）和最终数值答案（τ_Ni=1.95×10^7 Pa），这符合计算题的特征。 | 知识层次: 题目要求直接应用弗兰克-瑞德位错源公式进行单步计算，仅需代入给定参数（G和a）即可求解剪切应力，属于基本公式的直接套用，无需多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目要求直接应用F-R位错源的基本公式计算剪切应力，仅需简单代入给定参数（G和a）并进行一步计算即可得出结果，无需组合多个公式或进行复杂分析。" + }, + { + "idx": 1246, + "question": "According to the phase rule, what is the maximum number of equilibrium phases in a binary system represented on the phase diagram?", + "answer": "19", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目涉及相律的应用和数值计算，需要根据相律公式（F = C - P + 2）进行计算得出最大平衡相数，答案是一个具体数值（19），属于计算题特征。 | 知识层次: 题目考查对相律公式的直接应用，需要简单的数值计算，属于基本公式应用和简单计算范畴。虽然涉及相律这一基础概念，但主要考察的是对公式的理解和直接套用能力，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目直接考察对相律公式（F = C - P + 2）的简单应用，只需将二元系统条件（C=2）代入公式并计算最大相数（F=0时）。解题过程仅需一步公式代入和基本算术运算，完全符合等级1\"单一公式直接计算\"的标准。选择题型中这种直接套用基础公式的题目属于最基础难度。" + }, + { + "idx": 1394, + "question": "Calculate the coordination number of the cation in the compound CaF2, given r(Ca2+)=0.106nm and r(F-)=0.133nm", + "answer": "8", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数值计算CaF2中阳离子的配位数，涉及数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目要求应用离子半径比公式计算配位数，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了离子半径数据，并直接要求计算配位数，只需应用简单的半径比公式即可得出答案。无需多个公式组合或复杂分析，属于最基础的计算类型。" + }, + { + "idx": 1682, + "question": "Based on the radius difference between Ca2+ and Mg2+ ions, calculate and determine whether CaO-MgO meets the size condition for forming a continuous solid solution. (The radii of Ca2+ and Mg2+ ions are known to be 0.1nm and 0.072nm, respectively)", + "answer": "Size difference calculation: (0.1 - 0.072) / 0.1 = 28%. The size difference exceeds 15%, thus it does not meet the size condition for forming a continuous solid solution.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行具体的数值计算（半径差百分比计算），并根据计算结果得出结论（是否满足形成连续固溶体的尺寸条件）。答案展示了完整的计算过程和基于计算结果的判断，符合计算题的特征。 | 知识层次: 题目要求进行简单的数值计算和公式应用，即通过给定的离子半径计算尺寸差异百分比，并根据已知条件判断是否符合形成连续固溶体的尺寸条件。这一过程涉及基本的公式应用和直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用半径差公式进行计算，但步骤较为直接，仅涉及单一公式和简单百分比计算，无需多个概念或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3579, + "question": "Using data, calculate the volume in cubic centimeters occupied by one mole of boron.", + "answer": "4.7 cm^{3}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算硼的摩尔体积），答案是一个具体的数值（4.7 cm³），需要使用公式和数据来完成计算 | 知识层次: 题目要求进行基本的数值计算和公式应用，涉及摩尔体积的计算，属于直接套用基本公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算一摩尔硼的体积，只需应用密度公式（体积=质量/密度）并进行简单单位换算即可得出答案。由于题目提供了所有必要数据且无需复杂推导或组合多个公式，解题步骤直接明了，符合等级1的定义。" + }, + { + "idx": 4557, + "question": "Assuming that activation polarization controls both oxidation and reduction reactions, determine the rate of corrosion of metal M (in mol/cm2-s) given the following corrosion data: For Metal M: V(M/M2+)=-0.47 V, i0=5x10-10 A/cm2, β=+0.15; For Hydrogen: V(H+/H2)=0 V, i0=2x10-9 A/cm2, β=-0.12.", + "answer": "the rate of corrosion of metal m is 2.64x10-13 mol/cm2-s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的腐蚀数据和公式计算金属M的腐蚀速率，答案是一个具体的数值结果，需要通过数值计算和公式应用来得出。 | 知识层次: 题目需要应用腐蚀电化学中的活化极化理论，涉及多个参数的综合计算（交换电流密度、塔菲尔斜率等），并需要通过平衡电位和极化曲线来确定腐蚀速率。这需要理解相关概念并进行多步计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解腐蚀动力学中的活化极化概念，掌握交换电流密度和塔菲尔斜率的应用，并进行多步计算（包括平衡电位计算、腐蚀电流密度求解以及单位转换）。虽然题目提供了所有必要参数，但需要综合运用电化学知识才能正确求解腐蚀速率。" + }, + { + "idx": 1123, + "question": "If the carbon content is 0.8% in high-carbon steel with an original grain size of 0.05mm, calculate the grain size and its growth value after holding at 760‰ for 1 hour. The formula D^(1/n) - D0^(1/n) = c t can be used for calculation, where at 760‰, the constant c is 6×10^(-16), n is 0.1, D and D0 are grain sizes in mm, and t is time in minutes.", + "answer": "Holding at 760‰ for 1h: D^(1/0.1) - D0^(1/0.1) = 6×10^(-16)×60; D^10 - D0^10 = 3.6×10^(-14); D^10 = 3.6×10^(-14) + D0^10 = 0.05^10 + 3.6×10^(-14) = 9.77×10^(-14) + 3.6×10^(-14) = 13.4×10^(-14); D = (13.4×10^(-14))^(1/10) = 5.16×10^(-2) mm = 0.0516mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，最终得出具体的数值结果（0.0516mm），这符合计算题的特征。解答过程涉及公式应用和数值运算，不需要选择或判断，也不需要文字论述。 | 知识层次: 题目需要进行多步计算，包括公式的代入和求解，涉及对晶粒生长公式的理解和应用。虽然计算过程较为直接，但需要一定的综合分析能力和对公式中各参数的理解。 | 难度: 在选择题中属于中等偏上难度，需要理解晶粒生长公式并正确代入数值进行多步计算。题目涉及指数运算和单位转换，要求考生具备综合应用公式和计算的能力。虽然提供了公式和常数，但计算步骤较多且需要精确处理小数值，属于综合性计算问题。" + }, + { + "idx": 4725, + "question": "For an ASTM grain size of 6, approximately how many grains would there be per square inch at a magnification of 100x?", + "answer": "32 grains/in.^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出ASTM晶粒尺寸为6时，在100倍放大下每平方英寸的晶粒数量。解答需要应用ASTM晶粒尺寸计算公式，属于数值计算类问题。答案以具体数值形式给出，符合计算题的特征。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，仅需直接套用公式进行简单计算即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用ASTM晶粒度的基本公式进行计算，无需额外的概念理解或复杂的解题步骤。属于单一公式直接计算的简单题目。" + }, + { + "idx": 4716, + "question": "The concentration of \\mathrm{Si} in an \\mathrm{Fe}-\\mathrm{Si} alloy is 0.25 wt%. What is the concentration in kilograms of Si per cubic meter of alloy?", + "answer": "the concentration of \\mathrm{si} is 19.6kg / m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定硅在合金中的浓度，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的浓度单位转换和简单的公式应用，不需要多步计算或综合分析，属于直接套用基本公式的简单应用。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接计算（将重量百分比转换为体积浓度），无需复杂步骤或多公式组合。学生只需应用基本转换公式即可得出正确答案，属于最基础的难度等级。" + }, + { + "idx": 21, + "question": "Calculate the coordination number in a hexagonal close-packed unit cell", + "answer": "Coordination number 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算六方密堆积晶胞中的配位数，需要通过数值计算和公式应用来得出答案（Coordination number 6）。 | 知识层次: 题目要求计算六方密堆积晶胞中的配位数，这需要应用基本的晶体学知识，但计算过程相对直接，仅涉及基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式（六方密堆积的配位数固定为12），无需任何计算或复杂步骤。题目给出的正确选项\"Coordination number 6\"实际上是错误的（六方密堆积的正确配位数应为12），但即使如此，这仍属于最简单的记忆性题目类型，只需记住单一知识点即可作答。" + }, + { + "idx": 3872, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 48", + "answer": "340 degrees C", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定特定的转变温度和微观组织以达到给定的硬度值，这需要通过计算或查阅相关相图来确定。答案以具体数值形式给出（340 degrees C），表明这是一个需要数值计算或查找的题目。 | 知识层次: 题目要求根据硬度值确定转变温度和显微组织，涉及多步计算和概念关联，需要综合分析相图和硬度数据。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如相变温度、硬度与组织的关系）并进行综合分析。题目要求将硬度值HRC 48与特定温度关联，涉及多步计算和概念关联，但选项已给出正确答案，降低了部分难度。" + }, + { + "idx": 3165, + "question": "The vacancy formation energy of copper is 1.7×10⁻¹⁹ J. Calculate the average vacancy concentration C at 1000°C, given the Boltzmann constant K=1.38×10⁻²³ J/K.", + "answer": "The average vacancy concentration C = e^(-Ev/KT) = exp{- (1.7×10⁻¹⁹) / (1.38×10⁻²³ × 1273)} ≈ 6.27×10⁻⁵", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用Boltzmann公式计算空位浓度，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解并应用Boltzmann公式计算空位浓度，但题目已经提供了所有必要的参数和公式，解题步骤相对直接，仅需代入数值并进行简单计算即可得出结果。相较于需要多个公式组合或复杂分析的题目，此题的难度较低。" + }, + { + "idx": 2037, + "question": "Polyvinyl chloride C2H3Cln is dissolved in an organic solvent, with its C-C bond length set at 0.154nm, and the number of bonds in the chain x=2n. If the root mean square length is only half of that in (1), what is the molecular mass?", + "answer": "The molecular mass M=7125g.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及分子质量的计算，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括理解聚氯乙烯的分子结构、键长与链长的关系，以及均方根长度的概念。此外，还需要将分子质量的计算与给定的条件关联起来，进行综合分析。虽然不涉及复杂的机理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解聚合物链的构象统计概念（如均方根长度与键数的关系），进行多步计算（包括键数推导、分子量计算），并正确关联题目给出的条件（如键长和键数关系）。虽然题目提供了部分参数，但需要综合运用高分子物理和化学计量知识才能得出正确选项。" + }, + { + "idx": 3961, + "question": "A tensile test is performed on a specimen of some metal alloy, and it is found that a true plastic strain of 0.12 is produced when a true stress of 280 MPa is applied. For this alloy, the value of the strain hardening exponent is 0.3 . On the basis of these data what true plastic strain would be expected for a total true plastic stress of 330 MPa ?", + "answer": "the true plastic strain expected for a total true plastic stress of 330 \\text{mpa} is 0.383.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的材料参数（应变硬化指数、真实塑性应变和真实应力）进行计算，以预测在另一个应力水平下的真实塑性应变。解答过程涉及数值计算和公式应用（如应变硬化公式），最终答案是一个具体的数值结果。 | 知识层次: 题目需要应用应变硬化公式进行多步计算，涉及对公式的理解和变形，以及数值计算能力。虽然不涉及复杂的综合分析或机理解释，但需要将给定的参数正确代入公式并求解，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及真实应力-应变关系、应变硬化指数的应用，以及多步骤计算过程。虽然题目提供了必要的数据，但解题过程需要综合运用这些概念和数据进行计算，属于综合性计算问题。" + }, + { + "idx": 3576, + "question": "Using the densities and atomic weights, calculate the number of atoms per cubic centimeter in lead.", + "answer": "3.3 × 10^22 atoms/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过密度和原子量计算铅中每立方厘米的原子数，需要数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目要求使用给定的密度和原子量进行简单的数值计算，属于基本公式的直接应用，不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目属于简单应用层次，需要学生掌握密度的基本概念和原子量的计算，并能够直接套用公式进行计算。虽然涉及多个步骤（如密度转换为质量，再转换为原子数），但每一步都是直接的公式应用，没有复杂的推理或分析过程。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4675, + "question": "The number-average molecular weight of a polystyrene is 500,000g / mol. Compute the degree of polymerization.\n\\title{", + "answer": "the degree of polymerization is 4800.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚合度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求计算聚合度，涉及基本公式应用（分子量除以重复单元分子量）和简单计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算聚合度，只需要应用分子量与单体分子量的简单除法公式即可得出结果，无需复杂的推理或多步骤计算。因此，在选择题型内属于最基础的难度等级。" + }, + { + "idx": 4723, + "question": "Gold (Au) forms a substitutional solid solution with silver (Ag). Compute the weight percent of gold that must be added to silver to yield an alloy that contains 5.5 × 10^{21} \\mathrm{Au} atoms per cubic centimeter. The densities of pure \\mathrm{Au} and \\mathrm{Ag} are 19.32 and 10.49g / {cm}^{3}, respectively.", + "answer": "15.9 wt%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解合金中金的重量百分比，答案是一个具体的数值（15.9 wt%），解答过程需要涉及密度、原子数等物理量的计算。 | 知识层次: 题目需要进行多步计算，包括原子浓度转换、密度计算和重量百分比计算，需要综合运用材料科学中的固溶体概念和数学计算能力。虽然不涉及复杂的机理分析或创新设计，但需要较强的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体、原子浓度、密度和重量百分比等多个概念，并进行多步计算和单位转换。虽然题目提供了正确选项，但解题过程涉及计算合金中金和银的原子数、体积分数以及最终的重量百分比，步骤较为复杂，需要较强的综合分析能力。" + }, + { + "idx": 4294, + "question": "A specimen of a 4340 steel alloy having a plane strain fracture toughness of 45 MPa \\sqrt{m}(41 ksi \\sqrt{in}.) is exposed to a stress of 1000 MPa(145,000 psi). Will this specimen experience fracture if it is known that the largest surface crack is 0.75 mm(0.03 in.) long? Why or why not? Assume that the parameter Y has a value of 1.0 .", + "answer": "the specimen will experience fracture because it can only tolerate a stress of 927 \\text{mpa} (133,500 \\text{psi}) before fracture, which is less than the applied stress of 1000 \\text{mpa} (145,000 \\text{psi}).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算，应用断裂韧性公式来判断是否会发生断裂。答案中给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（应用断裂韧性公式计算临界应力），并需要将计算结果与给定应力进行比较以判断是否会发生断裂。虽然公式直接给出，但需要理解公式中各参数的含义并进行正确代入和计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解断裂韧性和应力强度的概念，进行多步计算（包括单位转换和公式应用），并综合分析计算结果与给定条件的对比。虽然题目提供了关键参数，但解题过程涉及多个知识点的关联应用和判断。" + }, + { + "idx": 2311, + "question": "Derive the relational expression for φ_min in randomly oriented short fiber composites", + "answer": "For randomly oriented short fibers, from σ_Lu=σ_fu[1-L_c/(2L)]φ_f+σ_m*(1-φ_f)=σ_mu(1-φ_f), φ_min=(σ_mu-σ_m*)/[σ_fu(1-L_c/(2L))+σ_mu-σ_m*], note that L>L_c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求推导一个关系表达式，涉及公式应用和数值计算，答案给出了具体的数学表达式和条件说明，符合计算题的特征。 | 知识层次: 题目要求推导随机取向短纤维复合材料中φ_min的关系表达式，涉及多步计算和概念关联（如σ_Lu、σ_fu、L_c等参数的相互关系），需要综合分析不同条件下的力学行为，并应用相关公式进行推导。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料强度理论中的关键概念（如临界纤维长度L_c、基体和纤维的强度贡献等），并能够正确关联和代入多步推导公式。虽然题目给出了正确选项，但需要考生具备综合分析能力来验证公式的正确性，涉及中等应用层次的知识点整合和计算步骤。" + }, + { + "idx": 3156, + "question": "It is known that polyethylene belongs to the body-centered orthorhombic structure, with lattice constants a=0.740nm, b=0.493nm, c=0.253nm, and two molecular chains passing through a unit cell. Calculate the density ρc of fully crystalline polyethylene.", + "answer": "Polyethylene (C2H4) is produced through addition polymerization, with its repeating unit being CH2-CH2. Considering one repeating unit as a lattice point, it can be determined that each unit cell contains two repeating units. Therefore, the density ρc of fully crystalline polyethylene can be calculated as ρc = 2(12×2 + 1×4) / (6.023×10^23) / (0.740×0.493×0.253)×10^-21 ≈ 1.01 g/cm³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解聚乙烯的密度，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括分子量的计算、单位晶胞体积的计算以及密度的计算，同时需要理解晶格常数和单位晶胞的概念，并能够将这些概念和公式结合起来进行综合分析。虽然不涉及复杂的推理分析或创新应用，但已经超出了简单应用的范围。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算、化学式推导等多个概念，并进行多步骤的综合计算。虽然题目提供了部分参数，但需要考生自行推导化学式、计算分子量、理解单位晶胞概念，并正确应用密度公式进行计算。这些步骤在选择题型中属于较为复杂的综合分析过程。" + }, + { + "idx": 1122, + "question": "If the carbon content is 0.8% in high-carbon steel with an initial grain size of 0.05mm, calculate the grain size and its growth value after holding at 870‰ for 1 hour. The formula D^(1/n) - D0^(1/n) = c t can be used for calculation, where at 870‰, the constant c is 2×10^(-8), n is 0.2, D and D0 are grain sizes in mm, and t is time in min.", + "answer": "At 870‰ for 1h: D^(1/0.2) - D0^(1/0.2) = 2×10^(-8)×60; D^5 - D0^5 = 1.2×10^(-6); D^5 = 0.05^5 + 1.2×10^(-6) = 3.125×10^(-7) + 12×10^(-7) = 15.13×10^(-7); D = (15.13×10^(-7))^(1/5) mm = 0.069mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，以求解晶粒尺寸及其生长值。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解晶粒生长公式并正确代入数值进行计算，同时需要处理单位转换（小时到分钟）和指数运算。虽然计算过程较为直接，但涉及多个步骤和概念的综合应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算和公式应用，需要考生理解晶粒生长公式并正确代入数值进行计算。虽然题目提供了公式和常数，但计算过程较为复杂，包括指数运算和单位转换，对考生的计算能力和细节处理能力有一定要求。" + }, + { + "idx": 3757, + "question": "A 2-in. cube solidifies in 4.6 min. Calculate (b) the solidification time for a 0.5 in. x 0.5 in. x 6 in. bar cast under the same conditions. Assume that n=2.", + "answer": "the solidification time for the bar is 0.60 min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算凝固时间），并给出了具体的公式参数（n=2），最终答案是一个具体的数值结果（0.60 min），这些都是计算题的典型特征。 | 知识层次: 题目涉及基本公式的应用和简单计算，需要根据给定的条件和公式直接计算固结时间，不需要多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目要求应用基本公式（Chvorinov's rule）进行简单计算，仅需一步转换和代入，无需复杂分析或多公式组合。" + }, + { + "idx": 4695, + "question": "Calculate the fraction of lattice sites that are Schottky defects for cesium chloride at its melting temperature \\left(645^{\\circ} C\\right). Assume an energy for defect formation of 1.86 \\mathrm{eV}.", + "answer": "the fraction of lattice sites that are schottky defects for cesium chloride at its melting temperature is 7.87 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，涉及公式应用（计算Schottky缺陷的分数），答案是一个具体的数值结果（7.87 × 10^{-6}），符合计算题的特征。 | 知识层次: 题目需要应用Schottky缺陷的形成能公式进行计算，涉及多步计算和温度转换（摄氏度转开尔文），同时需要理解缺陷浓度与温度的关系。虽然计算过程相对直接，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Schottky缺陷的概念，掌握能量与温度的关系，并进行多步骤计算（包括单位转换和指数运算）。虽然题目提供了必要的参数，但需要综合应用热力学和缺陷化学的知识来解决问题。" + }, + { + "idx": 2126, + "question": "If carburizing is performed for 10 hours at both 927°C and 870°C, what is the difference in carburized layer thickness?", + "answer": "δ927τ/δ870τ=1.41.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来比较两种温度下渗碳层厚度的差异，答案以数值比例形式给出，体现了计算题的特征。 | 知识层次: 题目需要应用扩散定律和温度对扩散系数的影响公式进行多步计算，涉及不同温度下扩散系数的比较和计算，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的温度依赖关系（阿伦尼乌斯方程），进行多步计算比较不同温度下的扩散系数，并最终推导出厚度比例关系。虽然题目提供了正确选项减少了计算量，但仍需掌握碳扩散的物理机制和数学关系才能正确选择。" + }, + { + "idx": 4767, + "question": "The following table gives a number of yield strength values (in MPa) that were measured on the same aluminum alloy. Compute average and standard deviation yield strength values.\n\\begin{tabular}{rrr}\n274.3 & 277.1 & 263.8 \\\\\n267.5 & 258.6 & 271.2 \\\\\n255.4 & 266.9 & 257.6 \\\\\n270.8 & 260.1 & 264.3 \\\\\n261.7 & 279.4 & 260.5\n\\end{tabular}", + "answer": "the average yield strength is 265.9 \\text{ mpa}. the standard deviation of the yield strength is 7.34 \\text{ mpa}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算平均屈服强度和标准偏差，需要数值计算和公式应用 | 知识层次: 题目主要涉及基本的统计计算（平均值和标准差），属于直接套用公式的应用层面，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察基本公式应用和简单计算能力。虽然需要计算平均值和标准差，但题目已经给出了所有数据，且计算步骤相对直接，只需套用公式即可得出结果。不需要复杂的分析或组合多个公式，因此属于等级2难度。" + }, + { + "idx": 4535, + "question": "In an aligned and continuous glass fiber-reinforced nylon 6,6 composite, the fibers are to carry 94% of a load applied in the longitudinal direction. What will be the tensile strength of this composite? Assume that the matrix stress at fiber failure is 30 MPa (4350 psi).", + "answer": "the tensile strength of this composite is 1354 mpa (196,400 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料的拉伸强度，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，涉及纤维和基体的应力分配，需要应用复合材料力学中的基本公式，并进行综合分析。虽然计算过程不复杂，但需要理解复合材料中各相的作用和相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料力学的基本概念（如载荷分配、纤维和基体的应力关系），并进行多步计算（包括百分比转换和应力叠加）。虽然题目提供了部分参数，但仍需综合分析才能得出正确结论，属于综合性计算问题。" + }, + { + "idx": 1078, + "question": "Calculate the relative content of each microstructural constituent in an alloy containing 0.40% C when it is cooled to room temperature under equilibrium conditions.", + "answer": "The relative content of each microstructural constituent: w_P=(0.40-0.0218)/(0.77-0.0218)×100%=50.5%; w_a=1-w_P=1-50.5%=49.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定合金中各微观结构组成的相对含量，答案给出了具体的计算过程和结果。 | 知识层次: 题目要求应用杠杆定律进行简单的二元合金相组成计算，属于基本公式的直接套用和单步计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用杠杆定律公式进行相对含量的计算，但解题步骤明确且直接，仅涉及单一公式的套用和简单代数运算。不需要复杂的推导或多步骤分析，符合选择题型中等级2的难度标准。" + }, + { + "idx": 3716, + "question": "A polymer bar's dimensions are 1 in . × 2 in. × 15 in. The polymer has a modulus of elasticity of 600,000 psi. What force is required to stretch the bar elastically to 15.25 in.?", + "answer": "the force required is 200,000 lb.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的力，答案是一个具体的数值结果（200,000 lb），符合计算题的特征。 | 知识层次: 题目涉及基本的弹性模量公式应用和简单计算，仅需直接套用公式并代入数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算弹性拉伸所需的力，直接应用胡克定律（F = kΔx）即可得出答案。解题步骤简单，仅需代入已知数值（弹性模量、尺寸变化）进行基本计算，无需复杂推导或多公式组合。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2732, + "question": "The dislocation spacing of a Ni crystal is ${\\\\bf2000n m}$. Assuming each dislocation is caused by an additional (110) atomic plane, calculate the $\\\\pmb\\\\theta$ angle of the small-angle grain boundary.", + "answer": "The interplanar spacing of (110) is $d_{110}=\\\\frac{1}{2}\\\\times\\\\frac{\\\\alpha}{\\\\sqrt{1^{2}+1^{2}+0}}=\\\\stackrel{0.35238}{2\\\\sqrt{2}}=0.1246(\\\\mathrm{nm})$. $$ \\\\sin\\\\frac{\\\\theta}{2}=\\\\frac{d_{110}}{\\\\cal{I}}=\\\\frac{0.1246}{2000}=6.23\\\\times10^{-5},$$ $$ \\\\theta{=0.003569527^{\\\\circ}}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要理解小角度晶界的定义和计算步骤，但不需要复杂的综合分析或推理过程。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算小角度晶界的θ角，解题步骤仅涉及直接套用已知的晶面间距公式和简单的三角函数关系，无需多个公式组合或复杂的分析过程。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3955, + "question": "For a bronze alloy, the stress at which plastic deformation begins is 277 MPa and the modulus of elasticity is 117 GPa. If the original specimen length is 148 mm, what is the maximum length to which it may be stretched without causing plastic deformation?", + "answer": "the maximum length to which the specimen may be stretched without causing plastic deformation is 131.30 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解最大拉伸长度，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用（胡克定律）和简单计算，仅需一步计算即可得出结果，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求应用胡克定律（Hooke's Law）计算弹性变形范围内的最大长度，仅需一个基本公式（应变=应力/弹性模量）和简单代数运算即可得出结果。虽然涉及单位换算（MPa到GPa），但步骤直接且无需复杂推导，属于典型的二级难度选择题。" + }, + { + "idx": 3765, + "question": "A 4-in-diameter sphere of liquid copper is allowed to solidify, producing a spherical shrinkage cavity in the center of the casting. Determine the volume and diameter of the shrinkage cavity in the copper casting.", + "answer": "shrinkage volume: 1.709 in.^{3}; diameter of shrinkage cavity: 1.30 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定收缩腔的体积和直径，答案给出了具体的数值结果，解答过程需要应用材料科学中的相关公式和计算步骤。 | 知识层次: 题目需要进行多步计算，包括体积计算和直径转换，同时需要理解铜凝固过程中的收缩现象及其对铸件的影响。虽然不涉及复杂的机理分析或创新设计，但需要综合运用材料科学中的基本概念和公式进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解铜凝固过程中的收缩原理，掌握体积收缩率的计算，并能正确应用球体体积公式进行多步推导。虽然题目提供了正确选项减少了计算量，但仍需综合分析材料特性和几何关系才能准确匹配答案。" + }, + { + "idx": 4829, + "question": "Compute the electrical conductivity of a cylindrical silicon specimen 7.0mm (0.28 in.) diameter and 57mm (2.25 in.) in length in which a current of 0.25 A passes in an axial direction. A voltage of 24V is measured across two probes that are separated by 45mm (1.75 in.).", + "answer": "12.2 (omega·m)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的物理参数（直径、长度、电流、电压）进行计算，最终得出电导率的数值结果。解答过程需要应用欧姆定律和电导率计算公式，属于典型的计算题类型。答案以数值形式给出，进一步验证了这是计算题。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的电流、电压和几何尺寸计算电导率，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算硅圆柱体的电导率，只需要应用基本的电导率公式（σ = (I × L) / (V × A)），其中所有需要的参数（电流、电压、长度和横截面积）都已直接给出或可以通过简单计算得出。解题步骤简单直接，无需多个公式组合或复杂分析，因此属于最简单的难度等级。" + }, + { + "idx": 2870, + "question": "Given that the Tm of Cu is 1083°C, estimate the minimum recrystallization temperature of Cu.", + "answer": "According to the empirical formula, the recrystallization temperature Tr≈0.4Tm. Therefore, the minimum recrystallization temperature of Cu is Tr=0.4×(1083+273)=542.4(K)=269.4(°C). In production, to improve efficiency, the actual recrystallization annealing temperature in factories is usually set at Tr+(100~200)(°C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（使用0.4Tm的公式）并给出具体温度结果，答案呈现了完整的计算过程和单位转换，符合计算题的特征。 | 知识层次: 题目主要考查对经验公式的直接应用和简单计算，涉及将熔点转换为绝对温度并进行基本乘法运算，属于基本公式的直接套用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用一个基本公式（Tr≈0.4Tm）并进行简单的温度单位转换，但解题步骤直接且明确，不需要复杂的推理或多步骤计算。因此，在选择题型内属于较低难度。" + }, + { + "idx": 4260, + "question": "Compute the elastic modulus for tempered steel, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(b) the elastic modulus for tempered steel is 204.7 gpa, which is in reasonably good agreement with the value of 207 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算回火钢的弹性模量，并与表格中的数值进行比较。解答过程涉及数值计算和结果对比，符合计算题的特征。答案给出了具体的计算数值（204.7 GPa）和对比结果，进一步验证了这是一个计算题。 | 知识层次: 题目要求计算弹性模量，并比较给定表格中的数值。这涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用给定的弹性模量数值进行比较，无需复杂计算或公式组合。属于单一公式直接计算的简单应用层次，因此难度等级为1。" + }, + { + "idx": 1984, + "question": "When the radii of silicon and oxygen in quartz (SiO2) are 0.038 nm and 0.114 nm respectively, what is the packing density (assuming the atoms are spherical)?", + "answer": "0.33", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解石英的堆积密度，答案是一个具体的数值（0.33），解答过程需要运用材料科学中的相关公式和计算步骤。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及原子半径和堆积密度的简单计算，属于直接套用公式的范畴，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算石英（SiO2）的堆积密度，只需要应用堆积密度的基本公式（原子体积总和除以晶胞体积），并代入给定的硅和氧的半径值进行简单计算即可。无需组合多个公式或进行复杂的推导分析，因此属于最基础的难度等级。" + }, + { + "idx": 3220, + "question": "A face-centered cubic single crystal is stretched with [131] as the force axis. When the tensile stress is 1×10^7Pa, determine the resolved shear stress on the (111)[1\\\\overline{1}0] slip system.", + "answer": "For the (111)[1\\\\overline{1}0] slip system, cosφ=5√33/33; cosλ=-√22/11. Therefore, τ3=1×10^7×(5√33/33)×(-√22/11)=3.7×10^6Pa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定滑移系上的分切应力，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目需要计算面心立方单晶在特定拉伸方向下的分切应力，涉及晶体学方向指数的计算、施密特因子的求解以及分切应力公式的应用。虽然计算步骤明确，但需要理解晶体学方向与滑移系统的关系，并进行多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体滑移系统的概念，掌握分解剪应力的计算方法，并进行多步向量运算和三角函数计算。虽然题目提供了正确选项，但解题过程涉及方向余弦计算、向量点积和综合分析，比单纯的概念选择题更复杂。" + }, + { + "idx": 2873, + "question": "Given that H70 brass [w(Zn)=30%] requires 1 hour to complete recrystallization at a constant temperature of 400°C, and 2 hours at 390°C, calculate the time required to complete recrystallization at a constant temperature of 420°C.", + "answer": "Recrystallization is a thermally activated process, so the recrystallization rate; v_R = A exp(-Q/RT), and the recrystallization rate is inversely proportional to the time t required to achieve a certain volume fraction, i.e., v_R ∝ 1/t. 1/t = A' exp(-Q/RT) When recrystallization of the same degree occurs at two different constant temperatures, t1/t2 = e^(-Q/R (1/T2 - 1/T1)) Taking the natural logarithm on both sides: ln(t1/t2) = -Q/R (1/T2 - 1/T1). Similarly, ln(t1/t3) = -Q/R (1/T3 - 1/T1). Thus, (ln(t1/t2)) / (ln(t1/t3)) = (1/T2 - 1/T1) / (1/T3 - 1/T1) Substituting the corresponding data, we obtain t3 = 0.26 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在420°C下完成再结晶所需的时间。解答过程中涉及到了热激活过程的公式推导、对数运算和数值代入计算，这些都是计算题的典型特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解再结晶过程的动力学关系，并运用对数变换和温度-时间关系进行综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及热激活过程的速率方程、比例关系的推导、对数运算以及温度与时间的综合计算。解题步骤包括建立方程、代入数据、解方程等多个步骤，需要较强的综合分析能力和数学运算能力。虽然题目提供了部分解题思路，但整体计算过程较为复杂，属于综合性计算问题。" + }, + { + "idx": 3867, + "question": "A steel is heated until 40% austenite, with a carbon content of 0.5%, forms. Estimate the overall carbon content of the steel.", + "answer": "the overall carbon content of the steel is 0.212% c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计钢的总体碳含量，涉及数值计算和公式应用。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及奥氏体形成比例和碳含量的关系，需要理解相图和相关公式的应用，并进行综合分析得出结果。 | 难度: 在选择题中属于中等偏上难度，需要理解奥氏体形成比例与碳含量的关系，并进行多步计算。题目要求将40%奥氏体（含碳0.5%）与剩余相（假设为铁素体）的碳含量进行综合计算，涉及相图知识和质量平衡概念。虽然选择题提供了正确选项，但仍需进行综合分析才能确认答案，比单纯的概念识别题更复杂。" + }, + { + "idx": 4355, + "question": "If copper (which has a melting point of 1085^{\\circ} C ) homogeneously nucleates at 849^{\\circ} C, calculate the critical radius given values of -1.77 × 10^{9} J/ m^{3} and 0.200 J/ m^{2}, respectively, for the latent heat of fusion and the surface free energy.", + "answer": "1.30 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界半径，答案是一个具体的数值结果（1.30 nm），这符合计算题的特征。 | 知识层次: 题目需要应用临界半径计算公式，涉及多步计算和概念关联（如熔化热、表面自由能等），但不需要复杂的综合分析或推理。 | 难度: 在选择题中属于中等偏上难度，需要理解临界半径计算公式（涉及表面自由能、过冷度、潜热等概念），并进行多步单位换算和数值计算。虽然题目提供了所有必要参数，但需要正确应用公式并处理负号问题（-1.77×10^9 J/m³表示放热过程），最终得到纳米级结果。相比简单概念题或单步计算题更复杂，但比需要推导公式或处理多变量的题目更直接。" + }, + { + "idx": 3802, + "question": "A Nb-35% W alloy is allowed to solidify. Determine the composition of the last liquid to solidify under equilibrium conditions.", + "answer": "18% w", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金在平衡凝固条件下最后凝固液体的成分，需要应用相图和相关公式进行数值计算，答案以具体数值形式给出。 | 知识层次: 题目需要运用相图知识进行多步计算，涉及平衡条件下合金凝固过程中液相成分的变化分析，需要理解相图的基本原理并能够进行相关计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算分析。题目要求考生在Nb-W合金相图中确定最后凝固液体的成分，这需要掌握杠杆定律的应用和相图解读能力。虽然题目提供了正确选项，但解题过程涉及多个步骤的综合计算和概念关联，比单纯记忆或单步计算的选择题更复杂。" + }, + { + "idx": 2019, + "question": "Calculate the distance between the center of a sodium ion and the next nearest Cl− ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.482nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子和氯离子之间的距离），并给出了具体的半径数据，解答过程需要应用公式和计算步骤，最终答案是一个具体的数值（0.482nm）。 | 知识层次: 题目要求应用基本公式（离子半径相加）进行简单计算，属于直接套用已知数据进行一步运算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算NaCl晶体中钠离子与下一个最近氯离子之间的距离，只需应用简单的晶体几何关系（如面心立方结构中离子间距的计算公式）和给定的离子半径进行直接相加即可得出答案。解题步骤简单，无需复杂的推导或多步计算，符合等级1的定义。" + }, + { + "idx": 4314, + "question": "A hypothetical A-B alloy of composition 55 wt% B-45 wt% A at some temperature is found to consist of mass fractions of 0.5 for both \\alpha and \\beta phases. If the composition of the \\beta phase is 90 wt% \\mathrm{~B}-10 wt% \\mathrm{~A}, what is the composition of the \\alpha phase?", + "answer": "the composition of the \\alpha phase is 20 \\text{ wt}% \\text{ b- } 80 \\text{ wt}% \\text{ a}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解α相的组成，答案是一个具体的数值结果，而不是选择、判断或文字解释。 | 知识层次: 题目涉及多步计算和概念关联，需要应用杠杆定律（lever rule）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解杠杆定律的概念，并进行多步计算和综合分析。题目要求根据已知的质量分数和相组成，通过杠杆定律反推出另一相的组成，涉及多个变量的计算和概念关联。虽然题目提供了部分已知条件，但解题过程仍需要一定的逻辑推理和计算能力。" + }, + { + "idx": 4533, + "question": "For a continuous and oriented fiber-reinforced composite, the modulus of elasticity in the transverse direction is 3.66 GPa (5.3 x 10^5 psi). If the volume fraction of fibers is 0.25, determine the modulus of elasticity of the matrix phase.", + "answer": "the modulus of elasticity of the matrix phase e_m is 2.79 GPa (4.04 x 10^5 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（纤维体积分数和横向弹性模量）应用公式计算基体相的弹性模量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用复合材料横向弹性模量的计算公式，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解复合材料横向弹性模量的计算公式，并能够正确代入已知条件进行多步计算。题目涉及体积分数和弹性模量的关系，需要综合分析能力。虽然计算过程不算极其复杂，但需要准确掌握相关概念和公式。" + }, + { + "idx": 2045, + "question": "Given that the density of fully crystalline polyethylene (PE) is 1.01 g/cm³ and that of high-density polyethylene (HDPE) is 0.96 g/cm³, calculate the size of the 'free space' in HDPE.", + "answer": "The free space in HDPE is (1 cm³ / 0.96 g) - (1 cm³ / 1.01 g) = 0.052 cm³/g", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过计算得出的具体数值 | 知识层次: 题目需要进行基本的密度计算和简单的公式应用，涉及直接套用已知数据进行数值计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的密度公式进行计算，属于单一公式直接计算的类型。解题步骤简单明确，无需复杂的推理或多步骤运算，符合等级1的难度标准。" + }, + { + "idx": 2680, + "question": "A solid solution contains x(MgO) at 30% and x(LiF) at 70%. Calculate the mass fractions of Li1+, Mg2+, F1-, and O2-. The relative atomic masses of Mg, O, Li, and F are 24.31, 16.00, 6.94, and 19.00, respectively.", + "answer": "w(Li+) = (0.7 × 6.94) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 16%\\nw(Mg2+) = (0.3 × 24.31) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 24%\\nw(F-) = (0.7 × 19) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 44%\\nw(O2-) = (0.3 × 16) / [0.3 × (24.31 + 16) + 0.7 × (6.94 + 19)] = 16%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，涉及质量分数的计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要将给定的摩尔分数转换为质量分数，并进行相应的数值计算。虽然涉及多个步骤，但每个步骤都是直接套用公式，没有复杂的综合分析或推理过程。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然涉及多个离子的质量分数计算，但每个计算步骤都是直接套用相同的质量分数公式，且各步骤之间相互独立，没有复杂的逻辑转换或组合。题目主要考察对基本质量分数公式的理解和简单应用能力，符合等级2的简单公式应用计算标准。" + }, + { + "idx": 3577, + "question": "Using the densities and atomic weights, calculate the number of atoms per cubic centimeter in lithium.", + "answer": "4.63 × 10^22 atoms/cm^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过密度和原子量计算锂的每立方厘米原子数，需要数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要应用密度和原子质量的基本公式进行计算，属于直接套用公式的简单计算过程，不涉及多步计算或复杂概念关联。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要运用密度和原子质量的基本公式进行计算，但解题步骤较为直接，仅需套用公式并进行单位转换即可得出结果。相比单一公式直接计算的等级1题目，本题需要稍多的理解和应用能力，但不需要多个公式组合或复杂分析，因此属于等级2难度。" + }, + { + "idx": 2971, + "question": "According to the Hall-Petch formula σ=σ₀+kd⁻¹/², given σ₀=55.3MPa, k=272MPa·μm¹/², d=39.8μm, find the yield strength σ after annealing for 90 minutes.", + "answer": "σ = 55.3MPa + 272MPa·μm¹/² × (39.8μm)⁻¹/² = 55.3MPa + 272MPa·μm¹/² × 0.1585μm⁻¹/² = 55.3MPa + 43.1MPa = 98.4MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果（yield strength σ），这符合计算题的特征。 | 知识层次: 题目主要考查对Hall-Petch公式的直接应用和简单计算，不需要多步推理或综合分析，属于基本公式套用和数值计算的范畴。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了Hall-Petch公式和所有需要的参数，解题步骤仅需将给定数值代入公式并进行简单的算术运算即可得到正确答案。不需要额外的概念理解或复杂的分析过程，符合等级1的简单直接计算要求。" + }, + { + "idx": 3758, + "question": "A 5-cm diameter sphere solidifies in 1050s. Calculate the solidification time for a 0.3 cm × 10 cm × 20 cm plate cast under the same conditions. Assume that n=2.", + "answer": "the solidification time for the plate is 31.15s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解固结时间，答案是一个具体的数值结果，解答过程需要运用材料科学中的相关公式和计算步骤。 | 知识层次: 题目需要进行多步计算，涉及固体凝固时间的公式应用和不同几何形状的转换，需要理解凝固时间与体积/表面积比的关系，并正确应用n=2的条件进行计算。虽然不涉及复杂的机理分析，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解凝固时间计算的基本概念（如Chvorinov法则），并能正确应用n=2的假设。题目涉及从球体到平板几何形状的转换计算，需要多步骤推导（包括等效模数计算和比例关系应用），但选择题型提供了正确选项，降低了部分计算验证的复杂度。" + }, + { + "idx": 2785, + "question": "There is a silicon single crystal wafer with a thickness of 0.5 mm. On one end face, every 10^7 silicon atoms contain two atoms, while the other end face has an increased concentration of gallium after treatment. Determine how many gallium atoms per 10^7 silicon atoms are required on this face to achieve a concentration gradient of 2×10^26 atoms/m³·m. The lattice constant of silicon is 0.5407 nm.", + "answer": "Silicon has a diamond structure, with 8 atoms per unit cell. Therefore, the volume corresponding to 10^7 atoms is: V = (10^7 / 8) × a₀³ = (10^7 / 8) × (0.5407 × 10^-9)^3 = 1.976 × 10^-22 m³. Let x be the number of gallium atoms per 10^7 silicon atoms on this end face. Then: Δρ/Δx = [(x / V) - (2 / V)] / (0.5 × 10^-3) = 2 × 10^26. x = 2 + 0.5 × 10^-3 × 2 × 10^26 × 1.976 × 10^-22 = 21.76 ≈ 22. Thus, this end face must contain 22 gallium atoms per 10^7 silicon atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算体积、浓度梯度等，最终得出具体的数值答案。解答过程涉及多个步骤的数学运算和物理概念的应用。 | 知识层次: 题目需要进行多步计算，包括单位晶胞体积的计算、浓度梯度的计算以及最终求解所需的镓原子数量。虽然涉及基础概念如晶体结构和浓度梯度，但需要将这些概念关联起来进行综合分析，并应用公式进行数值计算。思维过程要求一定的深度和逻辑性，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解硅的晶体结构、浓度梯度概念，并进行多步计算。虽然题目提供了部分计算步骤，但仍需要综合应用多个知识点（如单位晶胞计算、浓度梯度公式转换）才能得出正确答案。相比简单概念题或单步计算题，该题的复杂度和综合分析要求更高，但尚未达到复杂多变量计算的难度。" + }, + { + "idx": 2326, + "question": "In an aluminum specimen, the dislocation density within the grains was measured to be 2×10^12 m^−2. Assuming all dislocations are edge dislocations and are entirely concentrated at subgrain boundaries (i.e., low-angle grain boundaries), with their Burgers vector b=a/2⟨110⟩. If the cross-sections of the subgrain boundaries are all regular hexagons, and the tilt angle between subgrains is 2°, calculate the dislocation spacing at the subgrain boundary (given the lattice constant of aluminum a=0.404 nm).", + "answer": "The dislocation spacing D is calculated by the formula D = b / θ, where b is the Burgers vector and θ is the tilt angle. The Burgers vector b = (√2/2) × 0.404 nm = 0.286 nm. The tilt angle θ = 2° = 2 × (3.14/180) rad = 0.0349 rad. Therefore, D = 0.286 nm / 0.0349 = 8.188 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及具体的物理量（如Burgers向量、倾斜角度）和数学运算（如角度转换、除法运算），最终需要得出一个具体的数值结果（位错间距）。解答过程完全基于计算步骤，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括Burgers向量的计算、角度转换以及最终应用公式计算位错间距。虽然涉及的概念和公式较为基础，但需要将这些知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解位错密度、柏氏矢量、小角度晶界等概念，并进行多步计算和单位转换。虽然题目提供了计算公式，但需要正确应用和综合多个知识点才能得出答案。" + }, + { + "idx": 4761, + "question": "Compute the modulus of elasticity for the nonporous titanium carbide (TiC) given that the modulus of elasticity for titanium carbide (TiC) having 5 vol% porosity is 310 GPa (45 x 10^6 psi).", + "answer": "the modulus of elasticity for the nonporous material is 342 gpa (49.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非多孔碳化钛的弹性模量，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用多步计算和公式推导，涉及孔隙率对弹性模量的影响，需要理解并应用相关公式进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解孔隙率对弹性模量的影响，并应用相关公式进行多步计算。题目涉及中等应用层次的知识，要求考生能够综合分析并正确计算非多孔材料的弹性模量。虽然题目提供了部分数据，但仍需考生具备一定的材料科学基础和计算能力来推导正确答案。" + }, + { + "idx": 4814, + "question": "Steady-state creep rate data are given in the following table for a nickel alloy at 538^{\\circ} C \\\\ (811 K):\n\\begin{tabular}{lc}\n\\hline \\dot{\\varepsilon}_{s}\\left(h^{-1}\\right) & \\sigma(M P(a) \\\\\n\\hline 10^{-7} & 22.0 \\\\\n10^{-6} & 36.1 \\\\\n\\hline\n\\end{tabular}\nCompute the stress at which the steady-state creep is 10^{-5}h^{-1} (also at 538^{\\circ} C ).", + "answer": "the stress at which the steady-state creep is 10^{-5}h^{-1} is 59.4 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式计算特定条件下的应力值，答案是一个具体的数值结果，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要进行多步计算，包括对稳态蠕变速率的对数处理、应力与蠕变速率关系的分析（如幂律蠕变方程的运用），以及通过已有数据点求解未知应力值。这需要理解蠕变行为的基本原理，并能将概念与数学计算相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解稳态蠕变速率与应力之间的关系，并进行多步计算。题目要求根据给定的数据点，通过插值或外推方法计算新的应力值，涉及对数坐标下的线性关系分析。虽然计算步骤相对明确，但需要综合应用材料科学中的蠕变概念和数学计算能力。" + }, + { + "idx": 2608, + "question": "Estimate the equilibrium width of extended dislocations in stainless steel. Given the lattice constant of stainless steel a = 0.356 nm, shear modulus G = 10×10^6 N/cm^2, and stacking fault energy γ_I = 15×10^-6 J/m^2.", + "answer": "Stainless steel has a face-centered cubic structure, and the equilibrium width of extended dislocations d_0 = G a^2 / (24πγ_I). Substituting the data: d_0 = (10×10^6 N/cm^2) × (0.356×10^-9 m)^2 / (24π × 15×10^-6 J/m^2) = 1.12×10^-5 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和单位转换，符合计算题的特征。 | 知识层次: 题目需要应用公式进行多步计算，涉及材料科学中的基本概念（如剪切模量、堆垛层错能）和公式推导，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如晶格常数、剪切模量、堆垛层错能）并进行多步骤计算。题目要求将给定的公式代入数值并进行单位换算，涉及中等应用层次的知识综合运用。虽然计算过程明确，但需要较强的概念关联能力和计算准确性。" + }, + { + "idx": 556, + "question": "Given: When the grain size of annealed pure iron is 16 per $\\mathbf{\\chi}_{\\mathbf{m}\\mathbf{m}^{2}}$, the yield strength $\\sigma_{\\mathsf{s}}=100\\mathrm{N/\\Omega}$ $\\mathbf{m}\\mathbf{m}^{2}$; when the grain size is 4096 per $\\prime_{\\mathbf{m}\\mathbf{m}^{2}}$, $\\sigma_{\\mathrm{s}}=250\\mathrm{N}/\\mathrm{mm}^{2}$. Find the value of yield strength $\\pmb{\\sigma_{\\S}}$ when the grain size is 256 per $\\mathbf{m}\\mathbf{m}^{2}$.", + "answer": "According to the Hall-Petch formula: $\\sigma_{\\mathrm{s}}=\\sigma_{0}+K_{\\mathrm{y}}d^{-1/2}$, the yield strength $\\sigma_{\\mathbf{s}}$ of the material is calculated from the average grain size $^d$. Expressing the grain size in terms of the radius of an equal-area circle: $$d_{1}=(4A_{1}/\\pi)^{1/2}d_{2}=(4A_{2}/\\pi)^{1/2}$$$A_{1}$ and $A_{2}$ are the grain areas. Thus, $$\\sigma_{\\mathrm{s1}}=\\sigma_{0}+K_{\\mathrm{y}}d_{1}^{-1/2}\\sigma_{\\mathrm{s2}}=\\sigma_{0}+K_{\\mathrm{y}}d_{2}^{-1/2}$$Given that $A_{1}=1/16\\mathrm{mm}^{2}$, $A_{2}=1/4096\\mathrm{mm}^{2}$, $\\sigma_{\\mathrm{s}1}=100\\mathrm{N/mm}^{2}$, $\\sigma_{\\mathrm{s}2}=250\\mathrm{N}/\\mathrm{mm}^{2}$, substituting into the above equations yields $K_{\\mathrm{y}}=25{\\sqrt{2}}\\pi^{-1/4}\\mathrm{N}/\\mathrm{mm}^{3/2}$, $\\pmb{\\sigma_{0}}=50\\mathbf{N}/\\mathbf{m}\\mathbf{m}^{2}$. Then, with $A_{3}=1/256\\mathrm{mm}^{2}$, we find $\\sigma_{\\mathbf{s}3}=150\\mathbf{N}/\\mathbf{m}\\mathbf{m}^{2}$. (10 points)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（Hall-Petch公式）进行数值计算，最终得出一个具体的数值结果（yield strength的值）。解答过程涉及公式应用和代数运算，符合计算题的特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值代入和求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和单位转换。虽然题目提供了部分已知条件，但仍需进行综合分析才能得出最终答案。" + }, + { + "idx": 4252, + "question": "The diffusion coefficients for silver in copper are given at two temperatures: T(°C) = 650, D(m2/s) = 5.5 × 10^-16 and T(°C) = 900, D(m2/s) = 1.3 × 10^-13. Determine the values of D0 and Qd.", + "answer": "the values are d0 = 7.5 × 10^-5 m2/s and qd = 196,700 j/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，计算D0和Qd的值。解答过程需要应用阿伦尼乌斯方程进行数值计算，答案也是具体的数值结果。这符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯方程进行多步计算，涉及温度转换、对数运算和线性回归分析，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解阿伦尼乌斯方程的概念，并进行多步计算（包括对数运算和单位转换）。虽然题目提供了正确选项，但解题过程涉及温度转换、方程联立求解等综合分析步骤，对学生的计算能力和概念掌握深度有较高要求。" + }, + { + "idx": 4336, + "question": "Compute the mass fraction of pearlite that forms in an iron-carbon alloy containing 0.25 wt% C.", + "answer": "the mass fraction of pearlite is 0.31.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解珠光体的质量分数，答案是一个具体的数值结果（0.31），这表明需要进行计算过程。 | 知识层次: 题目涉及基本的铁碳合金相图知识，需要应用杠杆定律进行简单的质量分数计算，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用杠杆法则（lever rule）这一单一公式进行计算，属于基本公式的直接套用。解题步骤简单，仅需代入给定数值即可得出结果，无需复杂的推理或多步骤计算。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2036, + "question": "For a copolymer ABS with equal mass fractions of each component, what is the ratio of the monomers (A—acrylonitrile; B—butadiene; S—styrene)?", + "answer": "The mole fractions of the monomers are \\n\\n$$\\nx_{\\\\#Z\\\\#}=20/10^{-2},\\\\quad x_{\\\\sf T\\\\lceil-w\\\\rceil}=40/10^{-2},\\\\quad x_{\\\\#\\\\mathbb{W}\\\\#\\\\mathbb{W}}=40/10^{-2}\\n$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算共聚物ABS中单体的摩尔分数比，需要通过数值计算和公式应用来得出答案。答案中给出了具体的计算结果和数学表达式，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要将质量分数转换为摩尔分数，并考虑不同单体的分子量差异，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解共聚物的组成概念，并进行多步计算。题目涉及质量分数与摩尔分数的转换，需要掌握各单体的分子量并进行综合计算。虽然题目给出了正确选项，但解题过程需要较强的化学计算能力和概念关联能力，属于综合性计算问题。" + }, + { + "idx": 4434, + "question": "Calculate the fraction of lattice sites that are Schottky defects for sodium chloride at its melting temperature \\left(801^{\\circ} C\\right). Assume an energy for defect formation of 2.3 \\mathrm{eV}.", + "answer": "the fraction of lattice sites that are schottky defects for sodium chloride at its melting temperature is 4.03 × 10^{-6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Schottky缺陷的分数），并给出了具体的能量值和温度条件，答案也是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括温度转换、能量单位转换以及应用Schottky缺陷浓度公式。虽然计算过程较为直接，但需要理解缺陷形成能的概念以及公式中各参数的含义，并正确代入数值进行计算。这属于中等应用层次，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷的概念，掌握缺陷形成能的计算方法，并能正确应用Arrhenius公式进行多步骤计算。题目涉及温度单位转换、能量单位统一以及指数运算等综合计算过程，但选项已经给出了计算结果，减少了部分计算复杂度。" + }, + { + "idx": 3760, + "question": "Calculate the height of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the height of the riser h ≥ 10 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的高度），并给出了具体的参数和条件（H/D比为1.5），答案也是一个具体的数值结果（h ≥ 10 in.），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及圆柱形冒口高度与直径比（H/D）的应用，以及防止铸件缩孔的计算。虽然公式直接给出，但需要理解并正确应用这些概念和公式来解决问题，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解圆柱形冒口高度与直径比（H/D）的概念，并将该比例关系应用于具体尺寸计算。题目要求进行多步计算（根据H/D=1.5推导冒口直径与高度的关系），并需要综合分析铸造收缩预防的条件。虽然题目给出了具体尺寸简化了部分计算，但仍需正确应用工程原理并执行单位换算，这比单纯的概念选择题更具挑战性。" + }, + { + "idx": 4357, + "question": "The fraction recrystallized-time data for the recrystallization at 600^{\\circ} C of a previously deformed steel are tabulated here. Assuming that the kinetics of this process obey the Avrami relationship, determine the fraction recrystallized after a total time of 22.8min.\n\\begin{tabular}{cc}\n\\hline \\begin{tabular}{c} \nFraction \\\\\nRecrystallized\n\\end{tabular} & Time (min) \\\\\n\\hline 0.20 & 13.1 \\\\\n0.70 & 29.1 \\\\\n\\hline\n\\end{tabular}", + "answer": "0.51", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和Avrami关系进行数值计算，以确定再结晶分数，答案是一个具体的数值（0.51），需要通过公式应用和计算得出。 | 知识层次: 题目需要应用Avrami关系式进行多步计算，涉及数据拟合和方程求解，需要理解动力学方程的应用和关联实验数据，属于中等复杂度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解Avrami动力学方程并应用对数变换进行多步计算。题目要求根据给定的数据点推导方程参数，再代入新时间点求解，涉及概念关联和综合分析能力。虽然计算步骤明确，但需要较强的数学推导和应用能力，属于综合性计算问题。" + }, + { + "idx": 1393, + "question": "Calculate the coordination number of the cation in the compound Cr2O3, given r(Cr3+)=0.064nm, r(O2-)=0.132nm", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（离子半径比）来确定配位数，答案是一个具体的数值结果（6），符合计算题的特征。 | 知识层次: 题目要求计算Cr2O3中阳离子的配位数，涉及离子半径比的计算和配位数判断，属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单公式应用计算难度。题目要求计算Cr2O3中阳离子的配位数，给出了Cr3+和O2-的离子半径，可以直接应用配位数与离子半径比的关系公式进行计算。虽然需要记忆和理解配位数与半径比的关系，但计算过程简单直接，属于基本公式应用和简单计算的范畴。" + }, + { + "idx": 4482, + "question": "Compute the number-average molecular weight for a polystyrene for which the degree of polymerization is 25,000.", + "answer": "the number-average molecular weight for a polystyrene with a degree of polymerization of 25,000 is 2.60 x 10^6 g/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算得出聚合物的数均分子量，需要应用公式和数值计算，答案也是具体的数值结果。 | 知识层次: 题目要求计算聚合物的数均分子量，涉及基本的公式应用和简单计算，即通过聚合度乘以重复单元的分子量来得到结果。不需要多步计算或复杂的概念关联，属于直接套用基本公式的简单应用。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（分子量 = 重复单元分子量 × 聚合度）进行计算，无需多步骤推理或概念组合。题目明确给出了聚合度(25,000)且聚苯乙烯重复单元分子量(104 g/mol)为已知常数，属于最基础的计算类选择题。" + }, + { + "idx": 2310, + "question": "When the strength of short fiber composites reaches 95% of the strength of continuous composites, calculate $\\\\frac{L_{\\\\mathrm{c}}}{L}$", + "answer": "The strength of short fibers is The strength of continuous fibers is$$ \\\\sigma_{\\\\mathrm{Lu}}=\\\\sigma_{\\\\mathrm{fu}}\\\\bigg[1-\\\\frac{L_{\\\\mathrm{c}}}{2L}\\\\bigg]\\\\varphi_{\\\\mathrm{~f~}}+\\\\sigma_{\\\\mathrm{m~}}^{*}(1-\\\\varphi_{\\\\mathrm{~f~}}) $$ $$ \\\\sigma_{\\\\mathrm{Lu}}=\\\\sigma_{\\\\mathrm{fu}}\\\\varphi_{\\\\mathrm{~f~}}+\\\\sigma_{\\\\mathrm{m~}}^{*}(1-\\\\varphi_{\\\\mathrm{~f~}}) $$In the equation, $\\\\sigma_{\\\\mathrm{m}}^{*}(1-\\\\varphi_{\\\\mathrm{f}})$ contributes little to the strength. After omitting it and comparing the two equations, we obtain$$ 1-\\\\frac{L_{\\\\mathrm{c}}}{2L}=0.95,\\\\qquad\\\\frac{L_{\\\\mathrm{c}}}{L}=0.1 $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式应用和数值计算来求解特定比值（$\\\\frac{L_{\\\\mathrm{c}}}{L}$），答案给出了具体的计算步骤和最终数值结果（0.1），符合计算题的特征。 | 知识层次: 题目需要进行多步计算和公式应用，涉及短纤维和连续纤维强度的比较，需要理解并应用相关公式，同时进行数值计算和比较分析。虽然不涉及复杂的推理或机理解释，但需要一定的综合分析能力来解决问题。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料强度的基本概念，掌握连续纤维和短纤维强度公式的差异，并能正确进行多步数学推导和计算。题目要求考生将两个强度公式进行对比分析，并正确解出Lc/L的值，涉及概念关联和综合分析能力。虽然题目提供了正确选项，但推导过程需要较强的逻辑思维和计算能力，在选择题型中属于较复杂的计算问题。" + }, + { + "idx": 1050, + "question": "Calculate the content of pearlite in the microstructure of an Fe-0.4%C alloy", + "answer": "The content of pearlite in the microstructure: P%=[(0.4-0.0218)/(0.77-0.0218)]×100%=50.55%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解珠光体含量，答案给出了具体的计算过程和数值结果 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，属于对杠杆定律的直接套用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅要求应用一个基本公式（杠杆定律）进行简单计算，无需多个公式组合或复杂分析。学生只需正确代入给定数值即可得出答案，解题步骤直接且明确。" + }, + { + "idx": 3177, + "question": "The lattice constant of α-Fe is $a=0.28664\\mathrm{nm}.$ When two adjacent grains form a symmetric tilt boundary with a tilt angle of 1°, calculate the spacing $D$ of the edge dislocations.", + "answer": "The Burgers vector of the unit dislocation in a body-centered cubic structure is $b=\\frac{a}{2}\\textcircled{111},$ so $b={\\frac{\\sqrt{3}}{2}}a.$ Using the formula $$ D={\\frac{b}{\\theta}}={\\frac{\\sqrt{3}}{2}}\\times0.28664/0.0175\\approx14.183{\\mathrm{~nm}} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及使用Burgers向量和倾斜角度来计算位错间距，答案是一个具体的数值结果。 | 知识层次: 题目需要理解体心立方结构中的位错概念，应用Burgers向量的计算，并运用公式进行多步计算以求解位错间距。虽然不涉及复杂的综合分析或创新应用，但需要将多个概念和计算步骤结合起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及晶格常数、对称倾斜晶界、位错间距等多个材料科学概念，并需要进行多步计算（包括矢量计算和角度转换）。虽然题目提供了关键公式，但需要考生正确识别和应用这些概念，属于综合性计算问题。" + }, + { + "idx": 2845, + "question": "For FCC and BCC metals during plastic deformation, the relationship between flow stress and dislocation density ρ is given by τ=τ0+αGb√ρ, where τ0 is the stress required for dislocation motion without interference from other dislocations, i.e., the shear stress without work hardening, G is the shear modulus, b is the Burgers vector of the dislocation, and α is a material-dependent constant, α=0.3∼0.5. If a Cu single crystal has τ0=700 kPa, initial dislocation density ρ0=10^5 cm−2, G=42×10^3 MPa, b=0.256 nm, α=0.4, what is the critical resolved shear stress?", + "answer": "τ=τ0+αGb√ρ0=700+0.4×42×10^6×0.256×10^−9×√10^9=836 kPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出一个具体的数值结果（临界分解剪切应力）。解答过程涉及公式应用和单位换算，属于典型的计算题类型。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即通过给定的公式和参数计算临界分切应力。虽然需要理解公式中各参数的含义，但整体上属于直接套用公式进行计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目提供了多个参数和公式，但解题过程仅需直接套用给定的公式τ=τ0+αGb√ρ0，并进行简单的数值计算。不需要多个公式的组合或复杂的推导步骤，因此属于等级2难度。" + }, + { + "idx": 3761, + "question": "Calculate the volume of the cylindrical riser required to prevent shrinkage in a 4 in. × 10 in. × 20 in. casting if the H / D of the riser is 1.5.", + "answer": "the volume of the riser v ≥ 349 in.^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的体积），并给出了具体的参数（H/D比例和铸件尺寸），答案也是一个具体的数值结果（349 in.^3），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解圆柱形冒口的体积计算、H/D比的应用以及防止收缩的条件分析。虽然计算本身不复杂，但需要综合运用多个概念和公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解圆柱形冒口的设计原理（H/D比）、体积计算公式，并能够将铸造收缩预防需求转化为具体计算步骤。题目要求进行多步计算（确定冒口直径与高度的关系、计算体积），并需要将理论知识与工程实践（防缩需求）相结合，但作为选择题型，正确答案的选项降低了部分推导难度。" + }, + { + "idx": 2463, + "question": "Estimate the number of clusters containing 10 atoms in 1cm³ of copper at its melting point temperature. The atomic volume of liquid copper is 1.6×10⁻²⁹m³, the surface energy is 0.177J/m², and the melting point is 1356K.", + "answer": "According to nᵢ = n exp(-ΔG / k_B T), first calculate the energy ΔG₁₀ of a 10-atom cluster. The radius of the cluster r = (3×10×1.6×10⁻²⁹ / 4π)^(1/3), and the surface area A₁₀ = 4πr² = 4π(3×10×1.6×10⁻²⁹ / 4π)^(2/3). ΔG₁₀ = A₁₀γ = 4π(3×10×1.6×10⁻²⁹ / 4π)^(2/3)×0.177 = 2.52×10⁻¹⁹J. The number of atoms per cm³ n = 1 / (1.6×10⁻²³) = 6.25×10²² cm⁻³. n₁₀ = 6.25×10²² exp(-2.52×10⁻¹⁹ / (1.38×10⁻²³×1356)) = 8.85×10¹⁰ cm⁻³.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算能量、半径、表面积等，并最终得出具体的数值结果。答案中展示了详细的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子团簇半径和表面积的计算、能量计算以及最终的数量估算。虽然涉及公式的直接应用，但需要理解各个参数之间的关系，并进行综合分析。题目还要求对材料科学中的表面能和原子体积等概念有一定的理解，但不需要进行复杂的机理分析或创新设计。 | 难度: 在选择题中属于高难度，题目涉及多步骤的复杂计算和多个物理概念的关联应用。解题过程需要计算原子团簇的半径和表面积，进而求解能量变化，最后应用玻尔兹曼分布公式计算团簇数量。每一步都需要精确的数学运算和对物理概念的深入理解，综合性强，计算复杂度高。" + }, + { + "idx": 37, + "question": "Calculate the ratio of the number of tetrahedral voids to the number of O2- ions", + "answer": "The ratio of the number of tetrahedral voids to the number of O2- ions is 2:1", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算四面体空隙与O2-离子的数量比），答案给出了具体的计算结果（2:1），这符合计算题的特征 | 知识层次: 题目要求计算四面体空隙与O2-离子数量的比值，这属于基本公式应用和简单计算，直接套用晶体结构中的空隙比例知识即可得出结果，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接应用基本公式（四面体空隙数与阴离子数的比例关系）进行简单计算，无需复杂推理或多步骤操作。属于单一公式直接计算的类型，因此难度等级为1。" + }, + { + "idx": 4855, + "question": "The polarization P of a dielectric material positioned within a parallel-plate capacitor is to be 4.0 × 10^-6 C/m^2. What will be the dielectric displacement D?", + "answer": "the dielectric displacement D will be 4.89 × 10^-6 c/m^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解电介质位移D，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用基本公式（如电介质位移D与极化P的关系）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式计算，无需多个公式组合或复杂分析。题目明确给出了极化强度P，并直接要求计算电位移D，属于单一公式直接计算的简单应用层次。" + }, + { + "idx": 249, + "question": "What concentration of trivalent ions is required to ensure that the diffusion of Ca2+ in CaO remains non-intrinsic up to the melting point of CaO (2600°C)? The Schottky defect formation energy of CaO is known to be 6eV.", + "answer": "The defect reaction for doping M3+ is as follows: M2O3 → 2M′′Ca + V′′Ca + 3OO. When CaO is at its melting point, the concentration of Schottky defects is: [V′′Ca] = exp(-ΔHf / 2RT) = exp(-6 × 1.6 × 10^-19 × 6.23 × 10^23 / (2 × 8.314 × 2873)) = 3.6 × 10^-6. Therefore, to ensure that the diffusion of Ca2+ in CaO remains non-intrinsic up to the melting point of CaO (2600°C), the concentration of M3+ must be [M3+] = [M′′Ca] = 2[V′′Ca] > [V′′Ca], i.e., [M3+] > 2 × 3.6 × 10^-6 = 7.2 × 10^-6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算Schottky缺陷的浓度以及确定三价离子的浓度要求。答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解Schottky缺陷的形成能、扩散机制以及掺杂浓度对扩散行为的影响，并进行相应的数值计算。虽然不涉及复杂的推理分析或创新应用，但需要综合运用多个知识点进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷形成能的概念，掌握缺陷反应方程式的书写，并能进行多步计算（包括指数运算和单位转换）。此外，还需要综合分析掺杂浓度与缺陷浓度的关系，确保非本征扩散条件。虽然题目提供了正确选项，但解题过程涉及多个概念关联和计算步骤，对学生的知识掌握和计算能力要求较高。" + }, { "idx": 888, "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, calculate the packing density ξ of diamond.", @@ -9,19 +2685,619 @@ "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求通过数值计算和公式应用来求解金刚石的堆积密度，解答过程中涉及原子间距、原子半径、单位晶胞体积等具体计算步骤，最终得出一个数值结果。 | 知识层次: 题目需要进行多步计算（包括原子半径计算、单位晶胞体积计算、原子总体积计算等），并需要理解金刚石晶胞的结构特点（原子位置和贡献比例），涉及概念关联和综合分析。虽然计算过程较为直接，但需要结合晶体结构知识和数学计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解钻石晶胞的结构（包括原子位置和贡献比例），正确计算原子半径，应用球体体积公式，并最终计算堆积密度。虽然步骤较多，但每个步骤都是材料科学中的基础计算，没有涉及复杂变量或高级数学技巧。" + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解金刚石的堆积密度，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目需要进行多步计算，包括原子半径的计算、单位晶胞体积的计算以及堆积密度的计算。此外，还需要理解金刚石晶胞中原子的分布和贡献比例，涉及多个概念的关联和综合分析。虽然不涉及复杂的推理或机理解释，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等偏上难度，需要理解钻石晶胞的原子分布、计算原子半径、计算原子总体积和晶胞体积，并进行多步计算和综合分析。虽然题目提供了部分关键数据，但解题过程涉及多个概念和计算步骤，对学生的知识掌握和计算能力要求较高。" }, { - "idx": 1786, - "question": "The chemical composition of a glass is: 24mol% Na2O, 12mol% Al2O3, 64mol% SiO2. Calculate the four structural parameters Z, R, X, and Y of this glass.", - "answer": "Converted to 6Na2O·3Al2O3·16SiO2; Z=4; R=2.17; Y=3.66; X=0.34.", + "idx": 1777, + "question": "There is a green body with an initial particle size of 5μm. After sintering for 2h, x/r=0.1. If sintering proceeds until x/r=0.2 (without considering grain growth), what is the required sintering time when material transport is dominated by viscous flow?", + "answer": "8h", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求进行数值计算（计算四个结构参数Z、R、X、Y），需要应用特定公式和计算方法，且答案以数值形式呈现。 | 知识层次: 题目需要进行多步计算和概念关联，包括化学组成的转换、结构参数的计算（Z, R, X, Y），涉及多个公式的综合应用，需要一定的分析和理解能力。 | 难度: 在计算题中属于综合性计算问题，需要理解玻璃结构参数的概念，进行多步计算和公式应用，涉及摩尔百分比的转换和多个参数的求解，但步骤相对明确，没有过于复杂的变量处理。" + "reasoning": "题型: 题目需要基于给定的初始条件和物理关系（x/r与时间的关系）进行数值计算，最终得出一个具体的数值答案（8h）。解答过程涉及公式应用和数学推导，属于典型的计算题特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解烧结动力学中的基本公式（如x/r与时间的关系），并能够进行数值计算。虽然不需要复杂的机理分析或创新应用，但需要综合分析题目条件并应用正确的公式进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解烧结动力学中的关键概念（如x/r比值与时间的关系），并应用viscous flow主导的烧结模型进行两步计算（从初始状态到x/r=0.1，再推算到x/r=0.2的时间）。虽然不涉及多变量，但需要正确关联理论公式与实际问题，并进行指数关系的推导计算。" + }, + { + "idx": 2337, + "question": "Given the diffusion constant of carbon in γ-Fe, D₀ = 2.0 × 10⁻⁵ m²·s⁻¹, and the activation energy for diffusion, Q = 1.4 × 10⁵ J/mol (R = 8.31 J/(mol·K)). Under the condition of a carbon potential Cₚ = 1.1% C, carburization of 20# steel is performed at 880°C. To achieve the same effect as carburizing at 927°C for 5 hours, how long should the carburization time be? (Huazhong University of Science and Technology postgraduate entrance exam question)", + "answer": "T₁ = 927°C = 1200 K. From D = D₀ exp(−Q/RT), we have D₁ = D₁₂₀₀ = 2.0 × 10⁻⁵ exp(−1.4 × 10⁵ / (8.31 × 1200)) = 1.6 × 10⁻¹¹ m²·s⁻¹. T₂ = 880°C = 1153 K. D₂ = D₁₁₅₃ = 2.0 × 10⁻⁵ exp(−1.4 × 10⁵ / (8.31 × 1153)) = 0.902 × 10⁻¹¹ m²·s⁻¹. Therefore, tₓ = (1.6 × 10⁻¹¹ × 5) / (0.902 × 10⁻¹¹) = 9 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及扩散常数的计算和时间的转换，最终需要得出具体的时间数值。答案也是通过一系列计算步骤得出的具体数值，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散公式进行温度转换和扩散系数计算，并通过综合分析确定等效的渗碳时间。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解扩散常数、活化能、温度对扩散系数的影响等多个概念，并进行多步计算和综合分析。虽然题目提供了公式和参数，但需要正确应用阿伦尼乌斯方程计算不同温度下的扩散系数，并通过比例关系求解时间，涉及较为复杂的计算过程。" + }, + { + "idx": 2132, + "question": "Calculate the interplanar spacing and jump probability of interstitial atoms between octahedral interstitial sites in face-centered cubic and body-centered cubic crystals. The interstitial diffusion formula is D=α²PΓ, where α is the distance between adjacent parallel crystal planes, P is the jump probability in a given direction, and Γ is the atomic jump frequency.", + "answer": "Face-centered cubic crystal (fcc): α=a/√2, P=1/6; Body-centered cubic crystal (bcc): α=a/2, P=1/6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及晶体结构的参数计算和扩散概率的推导，答案给出了具体的计算结果和参数值。 | 知识层次: 题目需要进行多步计算，包括计算晶面间距和跳跃概率，并应用扩散公式。虽然涉及基本概念和公式，但需要理解晶体结构和扩散机制，并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构（fcc和bcc）的几何特征、间隙原子扩散机制，并应用给定的扩散公式进行多步计算。题目要求考生能够正确识别晶面间距α的计算方法（fcc为a/√2，bcc为a/2）以及跳跃概率P的取值（均为1/6），这需要对晶体学和扩散理论有较深的理解和综合应用能力。虽然题目提供了公式，但需要考生自主关联多个概念并完成计算步骤，因此在选择题型中属于综合性计算问题。" + }, + { + "idx": 23, + "question": "Based on the radius ratio relationship, determine the coordination number of K+ when coordinated with O2-. Given rO2-=0.132nm and rK+=0.131nm.", + "answer": "For K+, r+/r-=0.131/0.132=0.99; according to the relationship between cation coordination number and the radius ratio of positive to negative ions, the coordination number is 8.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于半径比关系进行计算，以确定K+的配位数。解答过程中需要进行数值计算（r+/r- = 0.131/0.132 = 0.99）并应用半径比与配位数的关系规则。答案是一个具体的数值结果（配位数为8），符合计算题的特征。 | 知识层次: 题目涉及基本的半径比计算和直接套用协调数与半径比的关系表，属于基本公式应用和简单计算范畴，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用半径比公式进行计算，解题步骤简单且单一，属于最基础的难度等级。学生只需掌握半径比与配位数之间的基本关系，并进行简单的除法运算即可得出正确答案，无需复杂的分析或多步骤推理。" + }, + { + "idx": 3631, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the packing factor.", + "answer": "The packing factor is pf = 0.624.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算UO2的堆积因子(packing factor)，需要通过数值计算和公式应用来得出具体数值0.624的答案。 | 知识层次: 题目要求计算UO2的堆积因子，这需要应用基本的几何公式和晶体结构知识，属于直接套用公式的简单计算题。虽然需要理解氟化钙结构的基本特征，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式进行简单计算，属于单一公式直接计算的难度等级。学生只需知道氟化钙结构的堆积因子公式并代入数值即可得出答案，无需复杂的推理或多步骤计算。" + }, + { + "idx": 2289, + "question": "A contact device is made of silver-tungsten composite material. Its production process involves first creating a porous tungsten powder metallurgy blank, then infiltrating pure silver into the pores. Before silver infiltration, the density of the tungsten compact is 14.5 g/cm³. Calculate the volume fraction of the pores. The density of pure tungsten is known to be 19.3 g/cm³. Assume the tungsten blank is very thin and all pores are open.", + "answer": "The pore density ρ_pore is obviously zero. Therefore, φ_pore = 1 - φ_tungsten = 1 - (ρc / ρ_tungsten) = 1 - (14.5 / 19.3) = 0.25", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解孔隙的体积分数，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知的钨块密度和纯钨密度来计算孔隙的体积分数。虽然需要理解孔隙和材料密度的关系，但计算过程直接且步骤单一，属于简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。解题仅需应用一个基本公式（体积分数计算公式），且计算步骤简单直接（只需代入已知数值进行除法运算）。题目中所有必要参数均已明确给出，无需进行任何概念转换或额外推导，完全符合等级1\"单一公式直接计算\"的特征。" + }, + { + "idx": 459, + "question": "Given that the density of GaAs is ${5.307\\\\mathrm{g/cm}^{3}}$, the atomic weights of Ga and As are 69.72 and 74.92 respectively, and its crystal structure is cubic $\\\\mathbf{Z}\\\\mathbf{n}\\\\mathbf{S}$ type, find the unit cell parameter of GaAs.", + "answer": "Constituent composition: $w_{\\\\mathrm{F}}={\\\\frac{0.77-0.65}{0.77-0.022}}\\\\times100\\\\%=16.0\\\\%$ $w_{\\\\mathrm{P}}=1-16.0\\\\%=84.0\\\\%$ Phase composition: $w_{\\\\alpha}=\\\\frac{6.69-0.65}{6.69-0.22}\\\\times100\\\\%=90.6\\\\%$ WFe,c = 1 - 90.6% = 9.4% VII. The crystal structure of GaAs is cubic $\\\\mathbf{Z}\\\\mathbf{n}\\\\mathbf{S}$ type, so there are 4 $\\\\mathrm{Ga}$ and 4 $\\\\mathbf{As}$ in the unit cell. Unit cell weight $W={\\\\frac{\\\\left(M_{A}+M_{B}\\\\right)\\\\times4}{N}}={\\\\frac{(69.72+74.92)\\\\times4{\\\\mathrm{g/mol}}}{6.022\\\\times10^{23}/{\\\\mathrm{mol}}}}=96.07\\\\times10^{-23}{\\\\mathrm{g}}$ Unit cell volume $V=a^{3},\\\\rho=\\\\frac{W}{a^{3}}$ Unit cell parameter $a=\\\\sqrt[3]{\\\\frac{W}{\\\\rho}}=\\\\sqrt[3]{\\\\frac{96.07\\\\times10^{-23}}{5.307}}\\\\mathrm{{cm}}=0.5657\\\\times10^{-7}\\\\mathrm{{cm}}=0.5657\\\\mathrm{{nm}}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的密度、原子重量和晶体结构信息，应用公式计算GaAs的晶胞参数。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位晶胞重量、体积的计算，以及密度的应用，涉及多个概念的综合运用和关联。虽然计算过程较为直接，但需要理解晶体结构、原子量和密度之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用密度计算、晶体结构知识、单位换算等多步骤计算过程。题目要求考生理解立方ZnS型晶体结构（包含4个Ga和4个As原子），并能正确计算晶胞质量和体积，最终推导晶格常数。虽然提供了计算公式，但涉及多个物理概念的串联应用和单位转换，在选择题型中属于需要较强综合分析能力的题目。" + }, + { + "idx": 4227, + "question": "The metal iridium has an FCC crystal structure. Given the interplanar spacing for the (220) set of planes is 0.1357 nm, compute the atomic radius for an iridium atom.", + "answer": "the atomic radius for an iridium atom is 0.1357 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的晶面间距计算铱原子的原子半径，涉及数值计算和公式应用（如晶面间距公式与面心立方晶体结构的关系）。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用晶体学中的FCC结构知识，通过给定的晶面间距计算原子半径，涉及多步计算和概念关联（如晶面间距公式与FCC结构的关系），但不需要复杂的综合分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、晶面间距计算和原子半径之间的关系。解题涉及多个步骤：首先根据(220)晶面间距计算晶格常数，然后根据FCC结构特点推导原子半径。虽然题目给出了关键中间值（晶面间距），但仍需要正确应用晶体学公式和几何关系进行综合计算。相比单纯的概念记忆题，这需要更深入的知识应用能力，但比需要处理多变量或更复杂晶体学问题的题目略简单。" + }, + { + "idx": 4906, + "question": "A piece of corroded metal alloy plate was found in a submerged ocean vessel. It was estimated that the original area of the plate was 800 cm^2 and that approximately 7.6kg had corroded away during the submersion. Assuming a corrosion penetration rate of 4mm / yr for this alloy in seawater, estimate the time of submersion in years. The density of the alloy is 4.5g/cm^3.", + "answer": "the time of submersion is 5.27 yr.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及腐蚀速率、面积、质量损失和密度等参数的运算，最终得出时间估计值。答案以数值形式呈现，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量与体积的转换、腐蚀速率的应用以及时间的估算。虽然不涉及复杂的综合分析或机理解释，但需要将多个概念（腐蚀速率、密度、面积）关联起来进行计算，思维过程有一定的深度要求。 | 难度: 在选择题中属于中等难度，需要理解腐蚀速率、密度和面积等概念，并进行多步计算和综合分析。题目涉及单位转换和公式应用，但步骤相对明确，属于综合性计算问题。" + }, + { + "idx": 2886, + "question": "In a eutectic reaction of the Mg-Ni system, let C1 be the hypoeutectic alloy and C2 be the hypereutectic alloy. The total amount of α in alloy C1 is 2.5 times that in alloy C2. Determine the compositions of C1 and C2.", + "answer": "Let the total amount of α in C1 be α1, then: α1=(54.6-C1)/54.6 Let the total amount of α in C2 be α2, then: α2=(54.6-C2)/54.6 According to the given condition, α1=2.5α2, that is: (54.6-C1)/54.6=2.5*(54.6-C2)/54.6 Substituting C2=54.6-1.323C1 into the above equation, we can solve for: C1=w(Ni)=12.7% C2=w(Ni)=37.8%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来解决问题，答案给出了具体的计算过程和最终数值结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要运用杠杆定律进行合金成分计算，并通过建立方程求解未知数。虽然不涉及复杂的机理分析或创新设计，但需要综合理解和应用相图知识。 | 难度: 在选择题中属于中等偏上难度，需要理解共晶反应、亚共晶和过共晶合金的概念，并运用杠杆定律进行多步计算。题目要求建立两个合金中α相含量的关系式，并通过代数运算求解成分，涉及综合分析和计算能力。虽然题目提供了正确选项，但推导过程需要较强的概念关联和计算能力，在选择题型中属于较复杂的计算问题。" + }, + { + "idx": 4653, + "question": "If the atomic radius of lead is 0.175nm, calculate the volume of its unit cell in cubic meters.", + "answer": "the volume of the unit cell is 1.213 × 10^{-28} m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案是一个具体的数值结果。 | 知识层次: 题目要求根据给定的原子半径计算单位晶胞的体积，这属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用基本公式（立方体体积公式 V = a³，其中 a 为晶胞边长）进行简单计算。题目已给出原子半径，且未涉及多步骤推导或复杂概念转换，属于单一公式直接计算的典型等级1难度。" + }, + { + "idx": 4231, + "question": "What is the composition, in atom percent, of an alloy that consists of 30 wt% Zn and 70 wt% Cu ?", + "answer": "the composition of the alloy is 29.4 \\, \\text{at}% \\, \\mathrm{zn} and 70.6 \\, \\text{at}% \\, \\mathrm{cu}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如原子百分比的计算）来得出合金的组成，答案也是具体的数值结果。 | 知识层次: 题目涉及基本的重量百分比到原子百分比的转换计算，需要应用简单的公式和进行数值计算，但不需要多步推理或综合分析。 | 难度: 在选择题中属于简单应用难度，需要应用基本公式（原子百分比计算公式）并进行简单计算，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 4530, + "question": "A continuous and aligned fiber-reinforced composite is to be produced consisting of 30 vol% aramid fibers and 70 vol% of a polycarbonate matrix; mechanical characteristics of these two materials are as follows: Modulus of Elasticity for Aramid fiber is 131 GPa (19x10^6 psi) and Tensile Strength is 3600 MPa (520,000 psi); Modulus of Elasticity for Polycarbonate is 2.4 GPa (3.5x10^5 psi) and Tensile Strength is 65 MPa (9425 psi). Also, the stress on the polycarbonate matrix when the aramid fibers fail is 45 MPa (6500 psi). For this composite, compute the longitudinal tensile strength.", + "answer": "the longitudinal tensile strength is 1100 mpa (160,000 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的材料参数和体积分数，应用复合材料力学中的混合法则（Rule of Mixtures）进行数值计算，以确定复合材料的纵向拉伸强度。答案是一个具体的数值结果，这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用复合材料力学性能的计算方法，包括体积分数、弹性模量和拉伸强度的复合效应计算。虽然不涉及复杂的机理解释或创新设计，但需要一定的综合分析能力来推导纵向拉伸强度。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料力学性能的基本概念，掌握纵向拉伸强度的计算方法，并进行多步计算。题目涉及纤维和基体的体积分数、弹性模量、拉伸强度等多个参数的综合运用，且需要正确应用混合法则进行计算。虽然题目提供了所有必要参数，但解题过程需要一定的综合分析能力。" + }, + { + "idx": 1051, + "question": "Calculate the graphite content in Fe-3.6%C alloy", + "answer": "The graphite content is: wG = (3.6 - 0.68) / (100 - 0.68) × 100% ≈ 2.94%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过计算得出的具体数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需直接套用给定的公式进行计算即可，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用特定公式进行百分比计算，但解题步骤明确且直接，仅涉及单一公式的简单应用和基础代数运算，无需多步骤推导或复杂概念整合。相比等级1的直接计算题稍复杂，但远低于等级3的多公式组合难度。" + }, + { + "idx": 4691, + "question": "(a) Calculate the fraction of atom sites that are vacant for copper (Cu) at its melting temperature of 1084°C (1357 K). Assume an energy for vacancy formation of 0.90 eV/atom.", + "answer": "the fraction of atom sites that are vacant for copper at 1357 k is 4.56 × 10^-4.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如使用能量和温度计算空缺分数）来得出具体数值结果，答案也是一个具体的计算结果（4.56 × 10^-4）。 | 知识层次: 题目要求使用给定的能量和温度计算空位分数，涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（空位分数计算公式）进行简单计算，无需多个步骤或复杂推理。题目提供了所有必要参数，学生只需正确代入数值即可得出答案。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2849, + "question": "Calculate the shear strength τ of 40 steel, given that the shear modulus of Fe is G=7.9×10^4 MPa, the lattice constant of α-Fe is a=0.28 nm, and the average spacing of Fe3C particles is λ=41.2 μm.", + "answer": "τ = (G * b) / λ = (G * (√3/2) * a) / λ = (7.9×10^4 * (√3/2) * 0.28×10^-3) / 41.2 = 0.465 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及给定的参数和公式推导，最终得出一个具体的数值结果。答案展示了完整的计算过程和最终结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及剪切强度公式的应用、晶格常数和粒子间距的转换，以及数值计算。虽然公式直接给出，但需要理解各参数的含义并进行单位转换和计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解剪切强度、剪切模量、晶格常数和粒子间距等多个概念，并进行多步计算和综合分析。虽然题目提供了公式和具体数值，但计算过程涉及单位转换和数学运算，对学生的概念掌握和计算能力有一定要求。" + }, + { + "idx": 2759, + "question": "There is a dislocation loop on the crystal slip plane, and a shear stress $\\\\boldsymbol{\\\\tau}$ is applied in the direction of its Burgers vector. What is the minimum radius required for the dislocation loop to remain stable in the crystal?", + "answer": "The force acting on the ds arc segment of the dislocation line: $\\\\pmb{\\\\tau}\\\\cdot\\\\pmb{b}\\\\cdot\\\\mathbf{d}\\\\mathscr{s}.$ At the same time, the line tension on the dislocation line: $T{\\\\approx}\\\\alpha\\\\cdot G\\\\cdot b^{2}$ , where the horizontal component: $2(\\\\alpha G b^{2})\\\\sin\\\\frac{\\\\mathrm{d}\\\\theta}{2}$ Thus, $$ \\\\mathrm{d}s=r\\\\mathrm{d}{\\\\theta},\\\\sin\\\\frac{\\\\mathrm{d}\\\\theta}{2}\\\\approx\\\\frac{\\\\mathrm{d}\\\\theta}{2}$$ When the two forces reach equilibrium, they are equal, i.e., Therefore, $$ \\\\begin{array}{c}{{\\\\tau\\\\bullet b\\\\bullet\\\\mathrm{d}s=2(a G b^{2}){\\\\frac{\\\\mathrm{d}\\\\theta}{2}}}}\\\\\\\\ {{\\\\tau\\\\bullet b\\\\bullet r_{c}\\\\bullet\\\\mathrm{d}\\\\theta=a G b^{2}\\\\mathrm{d}\\\\theta}}\\\\\\\\ {{r_{\\\\bullet}={\\\\frac{a G b}{\\\\tau}}}}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算最小半径以使位错环在晶体中保持稳定，答案通过公式推导和数值计算得出，涉及力的平衡和数学运算。 | 知识层次: 题目涉及多步计算和概念关联，需要理解位错环的受力平衡条件，并应用线张力和剪切应力的公式进行推导。虽然不涉及复杂的综合分析或创新应用，但需要一定的物理理解和数学推导能力。 | 难度: 在选择题中属于中等偏上难度，需要理解位错环的受力平衡条件、线张力概念，并进行多步数学推导和变量替换。虽然题目给出了关键公式，但需要综合应用材料力学和晶体缺陷知识才能正确推导出临界半径表达式。" + }, + { + "idx": 256, + "question": "The diffusion coefficients of carbon in titanium measured at different temperatures are 2×10−9cm2/s (736℃), 5×10−9cm2/s (782℃), and 1.3×10−8cm2/s (838℃). Please calculate the activation energy for diffusion.", + "answer": "From the previous step, it is known that Q=2342787J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用公式计算扩散的活化能。答案是一个具体的数值结果，需要通过数值计算和公式应用得出。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及对数运算和线性回归分析，属于中等应用层次。虽然计算过程较为直接，但需要理解扩散系数与温度的关系，并进行数据处理和公式转换。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与温度的关系（阿伦尼乌斯方程），进行多步对数计算和斜率求解，最后转换为激活能量。虽然选择题提供了正确选项，但仍需完成完整的计算流程才能验证答案的正确性，涉及中等应用层次的知识综合运用能力。" + }, + { + "idx": 3667, + "question": "A single crystal of an FCC metal is oriented so that the direction is parallel to an applied stress of 5000 psi. Calculate the resolved shear stress acting on the (111) slip plane in the [T] slip direction.", + "answer": "the resolved shear stress acting on the (111) slip plane in the [T] slip direction is 0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定平面和方向上的剪切应力，答案是一个具体的数值结果（0），符合计算题的特征。 | 知识层次: 题目需要应用晶体学中的施密特定律（Schmid's Law）来计算分解剪切应力，涉及多步计算和概念关联（如晶面指数、晶向指数、应力分解等），需要综合分析能力。虽然不涉及复杂的机理或创新设计，但比简单的公式应用要求更高。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体取向、应力分解、滑移系选择等多个概念，并进行多步向量计算才能得出正确结论。虽然题目给出了具体数值条件，但需要考生综合应用材料力学和晶体学知识才能判断出该特定取向下的分解切应力为零的结果。" + }, + { + "idx": 3771, + "question": "A 2 in. × 8 in. × 10 in. iron casting is produced and, after cooling to room temperature, is found to weigh 43.9 lb. Determine the number of shrinkage pores in the casting if all of the shrinkage occurs as pores with a diameter of 0.05 in.", + "answer": "The number of shrinkage pores in the casting is 83,354 pores.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定收缩孔的数量。答案是一个具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，包括体积计算、密度应用、孔隙体积计算和数量估算，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要以下综合分析能力：" + }, + { + "idx": 2354, + "question": "(2) Calculate the theoretical density of CsCl.", + "answer": "First, calculate the lattice constant from the ionic radii. Since the crystal structure is simple cubic, the diagonal length of the cube should be the sum of the diameters of the negative and positive ions, i.e., equal to $2(0.181+0.165)\\\\mathrm{nm}=0.692$ nm. The diagonal length equals $\\\\sqrt{3}a$, so $a=0.692/\\\\sqrt{3}=0.3995$ nm. From the appendix, the relative atomic masses of Cl and Cs are $35.45$ and $132.91$, respectively. The mass of each Cl and Cs atom is $35.45/6.023\\\\times10^{23}=5.885\\\\times10^{-23}$ g and $132.91/6.023\\\\times10^{23}=2.207\\\\times10^{-22}$ g. A unit cell contains one Cl ion and one Cs ion, so the theoretical density of CsCl is $\\\\rho_{\\\\text{(CsCl)}}=\\\\frac{5.885\\\\times10^{-23}+2.207\\\\times10^{-22}}{(0.3995\\\\times10^{-7})^{3}}\\\\text{g/cm}^{3}=4.38\\\\text{g/cm}^{3}$. The calculated theoretical density is slightly higher than the experimentally measured density, possibly because the estimated lattice constant is smaller than the actual value.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解CsCl的理论密度，解答过程中涉及多个计算步骤和公式推导，最终得出具体数值结果。 | 知识层次: 题目需要进行多步计算，包括从离子半径计算晶格常数、利用相对原子质量计算单个原子的质量、结合单位晶胞中的原子数计算理论密度，并涉及简单的误差分析。虽然不涉及复杂的综合分析或创新应用，但需要多个概念和公式的关联应用，超出了简单直接套用的层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、离子半径、晶格常数计算、相对原子质量转换、密度公式应用等多个概念，并进行多步骤的综合计算。虽然题目提供了完整的解题步骤，但在选择题型中需要考生快速识别关键计算点并验证结果，对知识掌握和计算能力要求较高。" + }, + { + "idx": 3606, + "question": "Determine the planar density for BCC lithium in the (110) plane.", + "answer": "planar density = 0.1149 x 10^16 points/cm^2", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算BCC锂在(110)晶面上的平面密度，需要通过数值计算和公式应用来得出具体数值结果。答案以数值形式给出，符合计算题的特征。 | 知识层次: 题目需要理解BCC晶体结构、(110)平面的原子排列，并应用平面密度计算公式进行多步计算，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、(110)晶面原子排列、平面密度计算公式等多个概念，并进行多步骤计算（包括晶格常数推导、有效原子数计算、面积计算等综合步骤）。虽然题目提供了正确选项减少了推导负担，但仍需较强的空间想象能力和计算准确性，属于需要综合分析的应用题。" + }, + { + "idx": 2793, + "question": "For pure iron carburized at $950\\\\mathrm{\\\\textperthousand}$, it is desired to achieve a carbon content of $\\\\mathfrak{w}{1}\\\\left(\\\\mathbb{C}\\\\right)=0,9\\\\%$ at a depth of $0.1\\\\mathrm{mm}$. Assuming the surface carbon content remains at $w{2}\\\\left(\\\\mathsf{C}\\\\right)=1.20\\\\%$, and the diffusion coefficient $D_{\\\\mathtt{Y F e}}{=}10^{{-}10}\\\\ensuremath{\\\\mathbf{m}}^{2}/\\\\mathbf{s},$, calculate the minimum carburization time required to meet this requirement.", + "answer": "$$\\\\begin{array}{c}{\\\\frac x{2\\\\sqrt{D t}}=0,8163}}\\\\ {{{\\\\mathrm x}=2\\\\times0.8163\\\\times\\\\sqrt{1.1\\\\times10^{-1}\\\\times3600}}}\\\\ {{{\\\\mathrm x}=0.032\\\\mathrm{(cm)}}}\\\\ {{{\\\\mathrm w}_{2}-{\\\\mathrm w}_{1}=\\\\mathrm{erf}\\\\left({\\\\frac{x}{2\\\\sqrt{D t}}}\\\\right)}}\\\\ {{{\\\\mathrm x}_{2}-{\\\\mathrm w}_{0}=\\\\mathrm{erf}\\\\left({\\\\frac{0.1\\\\times10^{-3}}{2\\\\sqrt{10^{-10}\\\\times t}}}\\\\right)}}\\\\end{array}$$ $$\\\\operatorname{erf}{\\\\Big(}{\\\\frac{5}{\\\\sqrt{t}}}{\\\\Big)}=0.25$$ Look up the table to find $$\\\\frac{5}{\\\\sqrt{t}}\\\\approx0.2763,$$ hence $$t\\\\approx327(\\\\mathrm{s})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小渗碳时间，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和误差函数表进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程和误差函数的概念，并进行多步骤计算。题目涉及查找表格数据和解方程，但整体计算过程在选择题型内相对可控，属于综合性计算问题。" + }, + { + "idx": 2820, + "question": "It is known that the porosity of sintered $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ is $5\\\\%$, and its $E=370\\\\mathrm{GPa}$. If another sintered $\\\\mathrm{Al}_{2}\\\\mathrm{O}_{3}$ has $E=270\\\\mathrm{GPa}$, find its porosity.", + "answer": "The relationship between the $\\\\pmb{E}$ of ceramic materials and their pore volume fraction $\\\\varphi$ can be expressed by the following equation: $$E=E_{\\\\circ}(1-1.9\\\\varphi+0.9\\\\varphi^{2})$$where $E_{0}$ is the elastic modulus of the material without pores. Substituting the known conditions into the above equation, we obtain $$E_{\\\\circ}={\\\\frac{E}{1-1.9{\\\\varphi}+0.9{\\\\varphi}^{2}}}={\\\\frac{370\\\\times10^{\\\\vartheta}}{1-1.9\\\\times0.05+0.9\\\\times(0.05)^{2}}}=407.8({\\\\mathrm{GPa}})$$$$270\\\\times10^{9}=407.8\\\\times10^{9}(1-1.9\\\\varphi_{1}+0.9\\\\varphi_{1})$$Thus, $\\\\varphi_{1}=19.61\\\\%$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解孔隙率，答案展示了具体的计算过程和公式推导，符合计算题的特征。 | 知识层次: 题目需要应用给定的公式进行多步计算，涉及数值代入和求解过程，需要理解孔隙率与弹性模量之间的关系，并进行适当的数学运算。虽然不涉及复杂的综合分析或创新应用，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性模量与孔隙率的关系公式，并进行多步计算。题目要求考生首先根据已知条件求解无孔隙材料的弹性模量，然后再利用该值计算新的孔隙率。虽然计算步骤较多，但公式明确且无需复杂推导，因此在选择题型内属于综合性计算问题。" + }, + { + "idx": 2865, + "question": "After cold working, the dislocation density of $\\\\mathbf{A}\\\\mathbf{g}$ is $10^{12}/\\\\mathfrak{c m}^{2}$. Assuming that the recrystallization nucleus moves from a high-angle grain boundary into the deformed matrix, find the minimum radius of curvature for the bulging grain boundary $\\\\scriptstyle\\\\left(\\\\mathbf{A}\\\\mathbf{g}_{:}G=30\\\\mathrm{GPa},b=0.3\\\\mathrm{nm},\\\\gamma=0.4\\\\mathrm{J}/\\\\mathrm{m}^{2}\\\\right)$.", + "answer": "The driving force $F$ for the movement of the $\\\\mathbf{Ag}$ recrystallization nucleus from a high-angle grain boundary into the deformed matrix is the stored energy from cold working, $F= G b^{2}\\\\left(\\\\rho_{1}-\\\\rho_{0}\\\\right)$. Since $\\\\rho_{1}\\\\gg\\\\rho_{0}$, $\\\\scriptstyle{F\\\\approx G b^{2}\\\\rho_{1}}$. The bulged grain boundary is subjected to a force $f$ directed toward its center of curvature. When the radius of curvature of the bulge is $R$, $f= \\\\frac{2\\\\gamma}{R},f$ $\\\\scriptstyle{\\\\dot{F}}$ $R_{\\\\mathrm{min}}$ $f$ $F$ $$F{=}f,$$$$G\\\\delta^{2}\\\\rho_{\\\\mathrm{f}}=\\\\frac{2\\\\gamma}{R_{\\\\mathrm{rein}}}$$$$R_{\\\\mathrm{aia}}={\\\\frac{2\\\\gamma}{G b^{2}\\\\rho_{1}}}={\\\\frac{2\\\\times0.4}{30\\\\times10^{8}\\\\times(3\\\\times10^{-10})^{2}\\\\times10^{16}}}=2.9\\\\times10^{-8}({\\\\mathrm{m}})=29({\\\\mathrm{nm}})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最小曲率半径，答案中包含了具体的计算步骤和最终数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解冷加工后的位错密度、再结晶核的形成以及晶界弯曲的力学平衡等概念，并应用相关公式进行计算。虽然题目提供了必要的参数和公式，但需要综合运用这些知识来解决问题，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如位错密度、再结晶驱动力、晶界曲率半径等）并进行多步计算。题目要求将理论公式与给定参数结合，推导出最小曲率半径，涉及综合性计算和概念关联。虽然题目提供了所有必要参数，但解题步骤较为复杂，需要较强的综合分析能力。" + }, + { + "idx": 3142, + "question": "γ-Fe has a lattice constant α=0.3633nm slightly above 910 ℃, find the atomic radius of γ-Fe", + "answer": "The atomic radius of γ-Fe r=√2/4×a=√2/4×0.3633=0.1284nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用晶格常数计算原子半径）来得出具体数值结果，答案是一个具体的计算结果（0.1284nm），符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要套用已知的公式（r=√2/4×a）和给定的数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（r=√2/4×a）进行计算，无需额外的公式组合或复杂推导。题目要求的知识点掌握深度较浅，解题步骤简单直接，属于最基础的难度等级。" + }, + { + "idx": 2017, + "question": "The maximum solid solubility (mole fraction) of nitrogen in γ-Fe is x_N=10.3×10^-2. Given that N atoms occupy octahedral interstitial sites, calculate the percentage of octahedral interstitial sites occupied by N atoms.", + "answer": "The percentage of octahedral interstitial sites occupied by N atoms is 12.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算氮原子占据八面体间隙的百分比），并给出了具体的数值和公式应用（最大固溶度和间隙位置信息）。答案也是一个具体的数值结果。 | 知识层次: 题目需要应用给定的最大固溶度数据，结合晶体结构中八面体间隙位置的基本知识，进行简单的百分比计算。虽然涉及晶体结构的概念，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需应用给定的最大固溶度（mole fraction）数据，并直接计算占据八面体间隙位置的氮原子百分比。解题步骤简单直接，无需多个公式组合或复杂分析，符合等级1的标准。" + }, + { + "idx": 4286, + "question": "Two previously undeformed cylindrical specimens of an alloy are to be strain hardened by reducing their cross-sectional areas (while maintaining their circular cross sections). For one specimen, the initial and deformed radii are 16mm and 11 mm, respectively. The second specimen, with an initial radius of 12 mm, must have the same deformed hardness as the first specimen; compute the second specimen's radius after deformation.", + "answer": "the second specimen's radius after deformation is 8.25 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如应变硬化公式）来求解第二个试样变形后的半径，答案是一个具体的数值结果（8.25 mm），属于典型的计算题特征。 | 知识层次: 题目需要进行多步计算，包括应变计算和硬度关联分析，涉及概念关联和综合分析。虽然不涉及复杂的推理或创新应用，但需要理解应变硬化原理并进行相应的数值计算。 | 难度: 在选择题中属于中等难度，需要理解应变硬化概念、计算截面面积变化率并进行多步计算。题目涉及两个试样的对比分析，要求考生能够综合应用材料科学知识解决实际问题。虽然计算步骤较多，但在选择题型中通过选项可以辅助验证结果，降低了部分难度。" + }, + { + "idx": 2854, + "question": "For an Al2O3 specimen with a square cross-section of side length 12mm in a three-point bending test, the distance between the two supports is 40mm. Given the material's fracture strength σfs=352.6 MPa, find the load at fracture Ff.", + "answer": "Ff = (2 * σfs * b^3) / (3 * L) = (2 * 352.6 * 10^6 * (12 * 10^-3)^3) / (3 * 40 * 10^-3) = 10154.9 N", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解断裂载荷Ff，答案是一个具体的数值结果，解答过程涉及公式代入和单位转换，符合计算题的特征。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及三点弯曲测试中的断裂强度公式直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解三点弯曲测试的基本原理和公式，但解题步骤相对直接，仅需套用给定的公式并进行简单的单位转换和计算。不需要多个公式的组合或复杂的分析，因此属于等级2难度。" + }, + { + "idx": 1973, + "question": "In the <100> direction of copper (fcc, a=0.361nm), what is the linear density of atoms?", + "answer": "The linear density of Cu atoms is 2.77×10^6 atoms/mm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铜在<100>方向上的线性原子密度，需要应用晶体结构参数和公式进行数值计算，答案给出了具体的计算结果。 | 知识层次: 题目需要应用基本的线性密度计算公式，并代入给定的晶格常数进行计算，属于直接套用公式的简单应用层次。虽然需要理解晶向和晶格结构的基本概念，但整体思维过程较为直接，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算铜在<100>方向的线性原子密度，仅需应用线性密度的基本公式（1/a）并进行单位转换（从nm到mm），无需复杂的推导或多步骤计算。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4500, + "question": "Consider the diffusion of water vapor through a polypropylene (PP) sheet 2mm thick. The pressures of H_{2} \\mathrm{O} at the two faces are 1 kPa and 10 kPa, which are maintained constant. Assuming conditions of steady state, what is the diffusion flux [in \\left[{cm}^{3} STP\\right] / {cm}^{2}-s ] at 298 K ?", + "answer": "the diffusion flux is 1.71 × 10^{-7} \\ \\text{cm}^{3}\\text{stp}/\\text{cm}^{2}-\\text{s}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散通量，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及稳态扩散条件下的扩散通量计算，需要应用菲克第一定律，并考虑气体扩散的特殊条件（STP）。虽然计算步骤较为直接，但需要理解扩散系数的概念、气体浓度的转换以及单位的一致性处理，属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散通量的概念，掌握稳态扩散的计算方法，并能正确应用相关公式进行多步骤计算。题目涉及气体扩散、压力差、材料厚度等多个变量，需要综合分析才能得出正确答案。虽然题目提供了具体数值和公式，但计算过程较为复杂，对学生的综合应用能力有一定要求。" + }, + { + "idx": 3683, + "question": "The diffusion coefficient for Cr+3 in Cr2O3 is 6x10^-15 cm^2/s at 727C and is 1x10^-9 cm^2/s at 1400C. Calculate the constant d0.", + "answer": "the constant d0 is 0.055 cm^2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用阿伦尼乌斯方程计算常数d0，属于需要数值计算和公式应用的题型。答案也是一个具体的数值结果。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及温度转换和自然对数运算，需要理解扩散系数与温度的关系，并进行综合分析以求解常数d0。 | 难度: 在选择题中属于中等难度，需要理解扩散系数的温度依赖性（阿伦尼乌斯方程），并进行多步计算来求解常数d0。虽然题目提供了必要的数据，但解题过程涉及对数运算和方程组的求解，对概念理解和计算能力有一定要求。" + }, + { + "idx": 255, + "question": "Given that the activation energy Q for Zn2+ diffusion in ZnS is 48856 J/mol, and D0=3×10−15 cm2/s, calculate the diffusion coefficient at 750°C.", + "answer": "Substituting T=1023K into D=D0exp(−Q/RT) yields D1023=9.6×10−4 cm2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行具体的计算，最终得出一个数值结果。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目要求直接套用扩散系数公式进行计算，仅需简单代入已知数值和温度转换，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用给定的扩散系数公式D=D0exp(−Q/RT)，并进行简单的数值代入和计算。不需要额外的概念理解或复杂的解题步骤，属于单一公式直接计算的难度等级。" + }, + { + "idx": 4479, + "question": "Compute repeat unit molecular weight for polydimethylsiloxane", + "answer": "74.16g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算聚二甲基硅氧烷的重复单元分子量，需要通过数值计算和公式应用得出具体数值结果74.16g/mol，符合计算题的特征。 | 知识层次: 题目要求计算聚二甲基硅氧烷的重复单元分子量，这属于基本公式应用和简单计算，只需理解重复单元的结构并应用原子量进行加和即可，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接套用单一公式（重复单元分子量计算）即可得出答案，无需复杂推导或多步骤计算。题目明确给出了重复单元结构（聚二甲基硅氧烷），且计算过程仅涉及基本原子量相加，属于最基础的应用层级。" + }, + { + "idx": 3602, + "question": "A typical paper clip weighs 0.59g and consists of BCC iron. Calculate the number of unit cells in the paper clip.", + "answer": "3.185 × 10^21 cells", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算纸夹中的晶胞数量），需要使用公式和给定的物理量（质量和晶体结构），最终给出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括质量到摩尔数的转换、BCC结构中原子的计算以及单位晶胞数量的确定，涉及多个概念的综合应用和关联。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念并进行多步计算。具体包括：1) 理解BCC铁的单位细胞结构；2) 计算单位细胞的质量；3) 将纸夹总质量转换为单位细胞数量。虽然题目给出了正确选项，但解题过程涉及单位换算、晶体结构知识和数学运算，比简单记忆或单一概念的选择题更复杂。" + }, + { + "idx": 4253, + "question": "The diffusion coefficients for silver in copper are given at two temperatures: T(°C) = 650, D(m2/s) = 5.5 × 10^-16 and T(°C) = 900, D(m2/s) = 1.3 × 10^-13. What is the magnitude of D at 875°C?", + "answer": "the magnitude of d at 875°c is 8.3 × 10^-14 m2/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数和温度数据，应用阿伦尼乌斯方程或其他相关公式进行计算，以求出在特定温度下的扩散系数。答案是一个具体的数值结果，这表明需要进行数值计算和公式应用。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯方程进行多步计算，涉及温度转换、对数运算和指数运算，需要综合分析给定的数据点并求解未知参数，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解扩散系数与温度的关系，应用阿伦尼乌斯方程进行多步计算，并综合分析给定数据来求解未知温度下的扩散系数。虽然题目提供了必要的数据，但解题过程涉及对数运算和代数操作，对学生的计算能力和概念掌握有一定要求。" + }, + { + "idx": 3854, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each phase present at 720 degrees C.", + "answer": "alpha: 0.0218% C, 83%; Fe3C: 6.67% C, 17%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要使用相图和杠杆定律进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图进行多步计算，包括确定相组成和相对含量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，能够正确读取特定温度下的相组成，并应用杠杆定律进行多步骤计算。虽然题目提供了正确选项，但解题过程涉及多个知识点的综合应用和计算步骤，对学生的理解能力和计算能力有一定要求。" + }, + { + "idx": 3214, + "question": "Compress the above stretched specimen from L to L0, and calculate the engineering linear strain and true linear strain during the compression process.", + "answer": "Engineering linear strain ε = (L0 - L) / L; true linear strain e = ln(L0 / L)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算公式和结果形式，符合计算题的特征。 | 知识层次: 题目要求应用基本的工程应变和真实应变公式进行计算，属于直接套用公式的简单应用，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用两个不同的应变公式（工程线性应变和真实线性应变），但这两个公式都是直接套用，无需复杂的推导或组合计算。题目要求考生掌握基本公式的应用能力，但解题步骤相对简单，属于选择题型中的中等偏下难度。" + }, + { + "idx": 2029, + "question": "A common polymer has C2H2Cl2 as its monomer, with an average molecular weight of 60000u (using the relative atomic masses of the elements as Ar(C)=12, Ar(H)=1, Ar(Cl)=35.5). Calculate the mass of the monomer.", + "answer": "The mass of the monomer is 12×2 + 1×2 + 35.5×2 = 97u/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算单体的质量），并给出了具体的原子质量和计算公式，答案也是通过计算得出的具体数值。 | 知识层次: 题目仅需应用基本化学公式进行简单的分子量计算，无需多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行简单的原子质量相加计算，无需复杂的推理或多步骤操作。属于单一公式直接计算的难度等级。" + }, + { + "idx": 2783, + "question": "Given a diffusion couple composed of pure chromium and pure iron, after 1 hour of diffusion, the Matano plane moved by 1.52×10^(-3) cm. It is known that the ratio of the square of the distance moved by the Matano plane to the diffusion time is a constant. Determine the moving speed of the Matano plane.", + "answer": "According to the given conditions: x²/t = k, the moving speed of the Matano plane vₐ = dx/dt = k/(2x) = x/(2t) = (1.52×10^(-3))/(2×3600) cm/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程涉及数学运算和物理公式的使用，最终给出具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的条件和公式直接计算Matano平面的移动速度，不需要多步计算或复杂的概念关联。 | 难度: 在选择题中属于简单公式应用计算难度，题目要求直接套用给定的公式x²/t = k，并通过简单的代数变换和数值代入计算出Matano平面的移动速度。解题步骤清晰且直接，不需要复杂的推理或多步骤计算，符合等级2的标准。" + }, + { + "idx": 4261, + "question": "Compute the elastic modulus for aluminum, whose stress-strain behavior may be observed in the 'Tensile Tests' module of Virtual Materials Science and Engineering (VMSE). How does this value compare with that presented in Table 6.1 for the same metal?", + "answer": "(c) the elastic modulus for aluminum is 69.1 gpa, which is in excellent agreement with the value of 69 gpa from table 6.1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算铝的弹性模量，并将计算结果与表格中的值进行比较。答案给出了具体的数值计算结果（69.1 GPa）和比较结论，这符合计算题的特征。 | 知识层次: 题目要求通过应力-应变行为计算铝的弹性模量，并将计算结果与参考表中的数值进行比较。这主要涉及基本公式的应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用已知的弹性模量数值进行比较，无需进行任何计算或公式应用。题目要求的知识点掌握深度较浅，解题步骤极其简单，属于单一数值直接比较的题型，因此属于等级1难度。" + }, + { + "idx": 2016, + "question": "Calculate the distance between the center of a sodium ion and its nearest neighboring positive ion in NaCl (given the radii of Na+ and Cl− are 0.097nm and 0.181nm, respectively).", + "answer": "0.393nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算钠离子与其最近邻正离子之间的距离），并给出了具体的离子半径数据。答案是一个具体的数值（0.393nm），需要通过公式应用和计算得出。 | 知识层次: 题目要求应用给定的离子半径数据进行简单计算，直接套用离子间距公式（半径相加），无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用给定的离子半径数据进行简单加法计算（Na+半径 + Cl−半径 = 0.097nm + 0.181nm = 0.278nm），然后乘以√2（因为NaCl晶体结构中最近邻正离子位于面心立方位置）得到最终距离0.393nm。整个过程仅涉及单一晶体学距离公式的直接套用，无需多步骤推导或复杂概念整合，属于最基础的计算类选择题。" + }, + { + "idx": 1086, + "question": "For annealed low-carbon steel with a grain size of NA=16 grains/mm², its yield strength σs=100MPa; when NA=4096 grains/mm², σs=250MPa. Calculate the yield strength when NA=250 grains/mm².", + "answer": "According to the Hall-Petch formula: $\\sigma_{\\mathrm{s}}=\\sigma_{0}+K d^{-1/2}$. Since $N_{A}$ is inversely proportional to the square of the grain diameter $\\pmb{d}$, we have: Furthermore, it can be solved that $$\\begin{array}{c}{{\\displaystyle{\\sigma_{\\mathrm{s}}=100}{\\mathrm{MPa}}=\\sigma_{0}+K{d_{1}}^{-1/2}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=250}{\\mathrm{MPa}}=\\sigma_{0}+K{d_{2}}^{-1/2}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=\\sigma_{0}+K{d_{3}}^{-1/2}}}}\\ {{\\displaystyle{d_{2}}/d_{1}=1/16\\qquadd_{3}/d_{1}=4/5~\\sqrt{10}}}\\ {{\\displaystyle{\\sigma_{\\mathrm{s}}=149}{\\mathrm{MPa}}}}\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和公式进行数值计算，最终得出一个具体的数值结果（149MPa），这符合计算题的特征。解答过程中需要应用Hall-Petch公式并进行多步计算推导。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸条件下的屈服强度计算，需要理解公式中各参数的关系并进行数值求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和数学计算技巧。 | 难度: 在选择题中属于中等难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和概念关联。虽然题目提供了部分计算步骤，但仍需要考生理解公式中各变量的关系，并能正确代入数值进行计算。此外，题目还涉及对晶粒尺寸与屈服强度关系的综合分析，增加了题目的复杂性。" + }, + { + "idx": 4766, + "question": "The following table gives a number of Rockwellg hardness values that were measured on a single steel specimen. Compute average and standard deviation hardness values.\n\\begin{tabular}{rrr}\n47.3 & 48.7 & 47.1 \\\\\n52.1 & 50.0 & 50.4 \\\\\n45.6 & 46.2 & 45.9 \\\\\n49.9 & 48.3 & 46.4 \\\\\n47.6 & 51.1 & 48.5 \\\\\n50.4 & 46.7 & 49.7\n\\end{tabular}", + "answer": "the average hardness value is 48.4 hrg. the standard deviation of the hardness values is 1.95 hrg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Rockwell硬度值的平均值和标准差，需要应用数值计算和统计公式，答案也是具体的数值结果。 | 知识层次: 题目主要涉及基本的数值计算和标准偏差公式的直接应用，不需要多步计算或复杂的概念关联，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，需要计算平均值和标准差。虽然涉及两个统计量的计算，但都是直接套用基本公式，步骤较为简单。不需要复杂的推理或多步骤组合，因此属于等级2。" + }, + { + "idx": 4352, + "question": "What is the second possible composition of the alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "for the second case, the composition is c0 = 1.22 wt % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算合金的第二种可能组成，需要应用质量分数和相图知识进行数值计算。答案给出了具体的数值结果（1.22 wt % c），表明这是一个需要计算过程的问题。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、质量分数计算以及合金成分的确定，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及合金成分的计算，需要掌握质量分数和共析铁素体的概念，并进行多步计算。虽然题目给出了正确选项，但解题过程需要综合分析多个知识点，属于中等应用层次。" + }, + { + "idx": 4232, + "question": "What is the composition, in weight percent, of an alloy that consists of 6 at% \\mathrm{Pb} and 94 \\mathrm{at}% \\mathrm{Sn} ?", + "answer": "the composition of the alloy is: 1. 10.0 \\, \\text{wt% pb} 2. 90.0 \\, \\text{wt% sn}", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（原子百分比转换为重量百分比）来确定合金的组成，答案以具体数值形式给出。 | 知识层次: 题目涉及基本的原子百分比到重量百分比的转换计算，需要应用简单的公式和基本的元素质量数据，属于直接套用基本公式的简单应用层次。 | 难度: 在选择题型中，该题目需要应用基本的原子百分比与重量百分比转换公式，并进行简单的计算。虽然涉及公式应用，但步骤直接且不复杂，属于简单公式应用计算。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4762, + "question": "At what volume percent porosity will the modulus of elasticity for titanium carbide (TiC) be 240 GPa (35 x 10^6 psi)?", + "answer": "the volume percent porosity at which the modulus of elasticity is 240 gpa (35 x 10^6 psi) is 17.1 vol%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定钛碳化物的体积百分比孔隙率，以达到特定的弹性模量值。答案是一个具体的数值结果（17.1 vol%），这表明需要进行计算才能得出答案。 | 知识层次: 题目需要进行多步计算，涉及弹性模量与孔隙率的关系公式应用，需要综合分析材料性能参数并运用数学计算得出结果，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性模量与孔隙率的关系公式（如经验公式或理论模型），进行多步代数运算或查表计算，并正确应用单位换算（GPa与psi）。虽然题目提供了具体数值，但解题过程涉及材料性能参数的综合分析和公式推导能力，比单纯的概念识别题更复杂。" + }, + { + "idx": 4038, + "question": "Compute the number of electrons that each atom donates, on average, to a bulk piece of hypothetical metal. Room temperature data for the metal:\nThe resistivity of the metal is [\\mathrm{r}] \\Omega·{cm}\nThe electron mobility of the metal is [m] {cm}^{2} /(V·s)\nThe mass density of the metal is [\\mathrm{d}] \\mathrm{g} / {cm}^{3}\nThe atomic weight of the metal is [\\mathrm{w}] \\mathrm{g} / mol", + "answer": "the number of free electrons donated by each atom, on average, is: \\[\n\\frac{[w]}{\\left([r]\\left(1.6 × 10^{-19}\\right)[m]\\right)\\left([d]\\left(6.022 × 10^{23}\\right)\\right)}\n\\]", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的物理参数（电阻率、电子迁移率、质量密度、原子量）进行数值计算，应用特定的公式来求解每个原子平均贡献的自由电子数。答案以数学表达式形式给出，需要具体的计算步骤和公式应用。 | 知识层次: 题目需要多步计算和概念关联，包括电阻率、电子迁移率、质量密度和原子重量等参数的结合应用，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要综合运用电阻率、电子迁移率、质量密度和原子重量等多个概念，并进行多步骤计算。虽然题目提供了正确选项，但理解其推导过程需要较强的物理和化学知识基础，以及综合分析能力。" + }, + { + "idx": 1025, + "question": "Calculate the multiple of change in the diffusion coefficient when the temperature increases from 927°C to 1027°C.", + "answer": "Multiple of change = D1027°C / D927°C = (4.788×10^(-11)) / (1.663×10^(-11)) ≈ 2.88 times", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算扩散系数的变化倍数），并给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需套用扩散系数与温度的关系公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用扩散系数随温度变化的公式并进行简单的除法计算。题目提供了具体的数值，无需额外的推导或复杂的步骤，属于单一公式直接计算的难度等级。" + }, + { + "idx": 94, + "question": "The density of MgO is $3.58\\\\mathrm{g/cm^{3}}$, and its lattice parameter is $0.42\\\\mathrm{nm}$. Calculate the number of Schottky defects per unit cell of MgO.", + "answer": "Let the number of molecules per unit cell of defective $\\\\mathrm{MgO}$ be ${\\\\bf X}$, the unit cell volume $\\\\mathrm{V}{=}$ (4.20)°, $\\\\scriptstyle{\\\\mathbf{x}}={\\\\mathbf{p}}$ VNO/M=3.96. The number of Schottky defects per unit cell $:=4-\\\\tt X=0.04$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算单位晶胞体积、应用密度公式求解缺陷数量，涉及概念关联和综合分析。虽然不涉及复杂的机理分析或创新设计，但需要一定的理解和应用能力。 | 难度: 在选择题中属于中等偏上难度，需要理解密度、晶格参数与缺陷浓度之间的关系，并进行多步计算。虽然题目提供了部分计算步骤，但仍需综合应用材料科学中的基本概念和公式来推导正确答案。" + }, + { + "idx": 2644, + "question": "There is a copolymer ABS (A—acrylonitrile, B—butadiene, S—styrene), with the same mass fraction for each monomer. Calculate the mole fraction of each monomer.", + "answer": "Acrylonitrile (—C2H3CN—) monomer has a relative molecular mass of 53; butadiene (—C2H3C2H3—) monomer has a relative molecular mass of 54; styrene (—C2H3C6H5—) monomer has a relative molecular mass of 104. Assuming each weighs 1 g, then acrylonitrile has 1/53 mol, butadiene has 1/54 mol, and styrene has 1/104 mol. Therefore, the mole fractions of the monomers are: x_acrylonitrile = (1/53) / (1/53 + 1/54 + 1/104) = 40.1%; x_butadiene = (1/54) / (1/53 + 1/54 + 1/104) = 39.4%; x_styrene = (1/104) / (1/53 + 1/54 + 1/104) = 20.5%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算每个单体的摩尔分数，涉及数值计算和公式应用，答案给出了具体的计算过程和结果。 | 知识层次: 题目涉及基本的摩尔分数计算，需要应用相对分子质量和简单的数学运算，属于直接套用公式和基本计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算三个单体的摩尔分数，但每个步骤都是直接套用基本公式（摩尔分数定义），且计算过程较为直接。题目提供了所有必要的相对分子质量数据，避免了额外的查找或推导步骤。因此，在选择题型内属于等级2难度，比单一公式直接计算稍复杂，但不需要多个公式的组合或深入的概念分析。" }, { "idx": 2090, @@ -33,43 +3309,235 @@ "knowledge_level_name": "简单应用", "difficulty": 2, "final_level": "Level_2", - "reasoning": "题型: 题目要求计算在特定温度下α相和γ相的成分，需要参考相图或相关公式进行数值计算，答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用铁碳相图的基本知识，通过查图和简单计算确定两相的成分，属于基本公式应用和直接套用范畴，不需要多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求根据给定的温度（800°C）和钢的成分（Fe-0.002C），直接应用铁碳相图或相关公式来确定α相和γ相的成分。虽然需要理解相图的基本概念和组成关系，但计算过程相对直接，仅涉及简单的数值查找和基本公式应用，不需要复杂的推导或多步骤计算。因此，在计算题题型内属于等级2难度。" + "reasoning": "题型: 题目要求计算在特定温度下α相和γ相的成分，需要参考相图或相关公式进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图的基本知识，通过查图和简单计算确定α相和γ相的成分。虽然涉及相图的理解，但计算过程直接，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于简单应用层次，需要考生根据给定的温度（800°C）和钢的成分（Fe-0.002C），直接套用铁碳相图的基本知识来确定α相和γ相的成分。虽然涉及相图的应用，但题目已经提供了具体的温度点，且选项直接给出了计算结果，减少了复杂推导的需求。因此，该题目在选择题型内属于等级2难度，即简单公式应用计算。" }, { - "idx": 2209, - "question": "Given that brass containing ${w_{\\\\mathrm{Zn}}}=0.30$ requires $^{1\\\\textrm{h}}$ to complete recrystallization at a constant temperature of $400^{\\\\circ}\\\\mathrm{C}$, and $2\\\\textrm{h}$ at $390^{\\\\circ}\\\\mathrm{C}$, calculate the time required to complete recrystallization at a constant temperature of $420^{\\\\circ}\\\\mathrm{C}$.", - "answer": "The rate of recrystallization is given by $Q$ is the activation energy for recrystallization) Let $t$ be the time required to complete recrystallization, then$$ $$ \\\\begin{array}{r}{\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}=\\\\ln\\\\frac{t_{2}}{t_{1}}}\\\\\\\\ {\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{3}}=\\\\ln\\\\frac{t_{3}}{t_{1}}}\\\\end{array}$$ Substituting $T_{1}=673~\\\\mathrm{K},t_{1}=1~\\\\mathrm{h};T_{2}=663~\\\\mathrm{K},t_{2}=2~\\\\mathrm{h};T_{3}=693~\\\\mathrm{K}$ into the above equations, we obtain$$ t_{3}\\\\approx0.26~\\\\mathrm{h}$$ That is, completing recrystallization at a constant temperature of $420^{\\\\circ}\\\\mathrm{C}$ requires approximately $0,26\\\\mathrm{~h~}$ \\\\begin{array}{c}{{V_{\\\\parallel\\\\parallel}t=1}}\\\\\\\\ {{A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{1}}}t_{1}=A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{2}}}t_{2}=A\\\\mathrm{e}^{\\\\frac{-Q}{R T_{3}}}t_{3}}}\\\\\\\\ {{-\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{2}}\\\\Big)=\\\\ln\\\\frac{t_{2}}{t_{1}}}}\\\\\\\\ {{-\\\\frac{Q}{R}\\\\Big(\\\\frac{1}{T_{1}}-\\\\frac{1}{T_{3}}\\\\Big)=\\\\ln\\\\frac{t_{3}}{t_{1}}}}\\\\end{array}", + "idx": 1099, + "question": "Calculate the planar density of the (100) plane in a face-centered cubic crystal, given the atomic radius r=(√2/4)a", + "answer": "For the (100) plane of a face-centered cubic crystal, there are 2 atoms. The planar density is calculated as: 2×π(√2/4 a)^2 / a^2 = 2π×1/8 = π/4 = 0.785", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了平面密度的计算和原子半径的代入，最终给出了具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即计算面心立方晶体(100)面的平面密度。虽然需要理解晶体结构和原子半径的关系，但整体上是一个直接套用公式的计算过程，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用平面密度的计算公式，但题目已经给出了原子半径与晶格常数的关系，且计算步骤较为直接，仅需套用公式并进行简单代数运算即可得出结果。相较于需要多个公式组合或复杂分析的题目，此题的解题步骤较为简单，属于选择题型中的中等偏低难度。" + }, + { + "idx": 2196, + "question": "A subgrain boundary is composed of several edge dislocations with a misorientation of 0.057 degrees. Assuming there is no interaction between the dislocations before polygonization, by what factor does the distortion energy change after the formation of the subgrain?", + "answer": "The energy per unit length of a dislocation line is W_I = (G b^2) / (4π(1-ν)) * ln(R/r_0), where r_0 is the radius of the dislocation core region and R is the radius of the maximum range of the dislocation stress field. If we take r_0 ≈ b = 10^-8 cm and R ≈ 10^-4 cm, then before polygonization, W_D = (G b^2) / (4π(1-ν)) * ln(10^4). After polygonization, R = D = b / θ = 10^-8 / 10^-3 = 10^-5 cm, and W_31* = (G b^2) / (4π(1-ν)) * ln(10^3). Thus, W_I* / W_I1 = ln(10^3) / ln(10^4) = 0.75.", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在特定温度下完成再结晶所需的时间。答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解再结晶速率与温度的关系，并通过给定的数据点求解未知条件下的时间。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、对数运算和方程求解。虽然计算步骤较多，但变量关系明确，属于该题型内的中等偏上难度。" + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解亚晶界形成后畸变能的变化因子，答案中包含了具体的公式推导和数值计算过程。 | 知识层次: 题目需要进行多步计算，涉及位错能量公式的应用和变形前后的能量比较，需要理解位错的基本概念和能量计算原理，并进行综合分析。虽然不涉及复杂的机理分析或创新应用，但计算过程需要一定的思维深度和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解位错能量公式、多边形化过程以及角度与距离的转换关系。题目涉及多步骤计算（如计算前后能量比）和概念关联（如位错核心半径与应力场范围的关系），但未达到复杂多变量计算的程度。" }, { - "idx": 2239, - "question": "In Fe-Si steel (with $\\\\mathrm{{\\\\tau}}\\\\mathrm{{{w}}}_{\\\\mathrm{{Si}}}$ being 0.03), the measured diameter of $\\\\mathrm{MnS}$ particles is $0.4\\\\mu\\\\mathrm{m}$, and the number of particles per $1~\\\\mathrm{m}\\\\mathrm{m}^{2}$ is $2\\\\times10^{5}$. Calculate the effect of $\\\\mathrm{MnS}$ on the austenite grain growth during normal heat treatment of this steel (i.e., calculate the austenite grain size).", - "answer": "Let the number of $\\\\mathrm{MnS}$ particles per unit volume be $N_{\\\\mathrm{V}}(1/\\\\mathrm{m}\\\\mathrm{m}^{3})$. Given the number of MnS particles per unit area $N_{\\\\mathrm{A}}=$ $2\\\\times10^{5}~1/\\\\mathrm{m}\\\\mathrm{m}^{2}$ and the particle diameter $d=0.4~\\\\mu\\\\mathrm{m}$. According to the principles of quantitative metallography, $$ N_{\\\\mathrm{A}}=d N_{\\\\mathrm{v}} $$ The volume fraction of MnS is $$ \\\\varphi={\\\\frac{1}{6}}\\\\pi d^{3}N_{\\\\mathrm{v}}={\\\\frac{1}{6}}\\\\pi d^{2}N_{\\\\mathrm{A}}= $$ $$ \\\\frac{1}{6}\\\\pi\\\\times(0.4\\\\times10^{-3})^{2}\\\\times2\\\\times10^{5}=0.0167 $$ Therefore, during the heating of this steel, due to the effect of $\\\\mathrm{MnS}$ particles, the limiting size for austenite grain growth is $$ \\\\overline{{\\\\cal D}}_{\\\\mathrm{lim}}=\\\\frac{4r}{3\\\\varphi}=\\\\frac{4\\\\times0.2}{3\\\\times0.016~7}=16~\\\\mu\\\\mathrm{m} $$", + "idx": 4690, + "question": "For some hypothetical metal, the equilibrium number of vacancies at 900^{\\circ} C is 2.3 × 10^{25} m^{-3}. If the density and atomic weight of this metal are 7.40g / {cm}^{3} and 85.5g / mol, respectively, calculate the fraction of vacancies for this metal at 900^{\\circ} C.", + "answer": "the fraction of vacancies for this metal at 900^{\\circ} C is 4.41 × 10^{-4}.", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求通过数值计算和公式应用来求解奥氏体晶粒尺寸，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括体积分数的计算和晶粒生长极限尺寸的计算，同时需要理解MnS颗粒对奥氏体晶粒生长的抑制作用。虽然涉及公式应用和数值计算，但不需要复杂的推理分析或机理解释。 | 难度: 在计算题中属于综合性计算问题，需要多步计算和概念关联。题目要求计算MnS对奥氏体晶粒长大的影响，涉及定量金相学原理、体积分数计算以及晶粒尺寸限制公式的应用。虽然计算步骤较多，但每个步骤相对明确，属于中等应用层次的计算题。" + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺分数，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度和原子量的转换、原子密度的计算以及最终的空位分数计算。这需要理解空位形成的概念，并能将多个知识点（如密度、原子量、阿伏伽德罗常数）关联起来进行综合分析。虽然不涉及复杂的推理或创新设计，但计算过程较为复杂，超出了简单应用的范畴。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及计算金属中的空位分数，需要掌握密度、原子量和阿伏伽德罗常数等基本概念，并进行多步计算。虽然题目提供了必要的参数，但解题过程需要综合运用这些概念和公式，属于综合性计算问题。" }, { - "idx": 2794, - "question": "There are two diffusion reactions with activation energies of Q_1=83.7 kJ/mol and Q_2=251 kJ/mol, respectively. Observe the effect of increasing the temperature from 25°C to 600°C on the diffusion with an activation energy of Q_2=251 kJ/mol, and comment on the results.", - "answer": "From D=D_0 exp(-Q/RT), we get D_873/D_298=exp[-251000/(8.314)×(298-873)/(873×298)]=9.5×10^28. For the temperature increase from 298K to 873K, the diffusion rate D increases by 9.5×10^28 times, showing that the higher the activation energy, the more sensitive the diffusion rate is to temperature.", + "idx": 3614, + "question": "Determine the minimum radius of an atom that will just fit into the octahedral interstitial site in BCC lithium.", + "answer": "0.629 Å", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求通过公式计算扩散速率的变化，并给出具体的数值结果。解答过程中需要应用扩散公式进行数值计算，最终得出扩散速率增加的倍数。 | 知识层次: 题目需要应用扩散公式进行多步计算，并分析温度变化对扩散速率的影响，涉及概念关联和综合分析。虽然计算过程较为直接，但需要理解公式中各参数的含义及其相互关系，以及对结果的解释，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用阿伦尼乌斯公式进行多步计算，并理解温度变化对扩散速率的影响机制。题目涉及较高阶的数学运算（指数计算）和物理概念的关联分析，但尚未达到复杂多变量计算的程度。" + "reasoning": "题型: 题目要求通过数值计算确定原子半径的最小值，需要使用公式和已知参数进行计算，最终给出一个具体的数值答案（0.629 Å）。 | 知识层次: 题目需要多步计算和概念关联。首先需要理解BCC晶体结构中八面体间隙的位置和几何特征，然后应用几何关系计算间隙半径，最后结合锂的晶格常数进行计算。这涉及晶体结构知识和几何计算能力的综合应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解BCC晶体结构、八面体间隙位置的计算方法，并正确应用原子半径与间隙半径的关系公式。解题涉及多步计算和概念关联，但选项已给出正确答案，减少了部分复杂性。" + }, + { + "idx": 2107, + "question": "Given the solid solubility equation of carbon in α-Fe in equilibrium with cementite as $$ w_{\\mathrm{C}}^{\\alpha}=2.55\\exp{\\frac{-11.3\\times10^{3}}{R T}} $$, assuming the solid solubility equation of carbon in austenite is similar to this equation, write this equation based on the Fe-Fe3C phase diagram.", + "answer": "Let the solid solubility equation of C in γ be $$ w_{\\mathrm{c}}^{\\gamma}=A\\exp\\bigl(-\\frac{Q}{R T}\\bigr) $$ Taking the logarithm of both sides, we get $$ \\ln w_{\\mathrm{c}}^{\\gamma}=\\ln A-\\frac{Q}{R T} $$ From the Fe-Fe3C phase diagram, we have $\\ln0.77=\\ln A-{\\frac{Q}{R\\times1000}}$ $$ \\ln2.11=\\ln A-{\\frac{Q}{R\\times1~421}}\\quad. $$ Combining these two equations, we obtain $Q=28\\mathrm{kJ}$, $A=22,3$, thus $$ w_{\\mathrm{c}}^{\\mathrm{r}}=22.3\\exp\\Bigl(-\\frac{2.8\\times10^{3}}{R T}\\Bigr) $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的固溶度方程和Fe-Fe3C相图，推导出奥氏体中碳的固溶度方程。解答过程涉及对数运算、方程联立求解和参数确定，属于典型的计算题。答案展示了具体的计算步骤和最终结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要从给定的固溶度方程出发，结合Fe-Fe3C相图的数据进行推导和计算。虽然题目给出了部分指导，但仍需要理解相图信息并正确应用对数变换和联立方程求解，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶度方程的形式，掌握对数变换方法，并能从Fe-Fe3C相图中提取关键数据点（0.77%和2.11%碳含量）建立联立方程。解题过程涉及多步推导（取对数、建立方程、解方程组）和温度单位换算（1000K和1421K），最后还需将求得的参数代回原方程。虽然题目给出了正确推导过程，但在选择题环境下需要考生具备综合分析能力和计算技巧来判断选项的正确性。" + }, + { + "idx": 3623, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{KBr}.", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用离子半径数据来确定配位数，需要通过计算和比较离子半径比来得出结果，答案是一个具体的数值(6)，属于计算题的特征 | 知识层次: 题目要求使用离子半径数据来确定配位数，这涉及基本的公式应用和简单计算，属于直接套用已知规则和数据的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求使用离子半径来确定KBr的配位数，这只需要直接应用离子半径与配位数之间的基本关系，无需复杂的计算或多步骤推理。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4569, + "question": "Compute the resistance over the entire 51mm (2 in.) of the specimen.", + "answer": "the resistance is r = 168 ω.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（Compute the resistance），并且答案给出了具体的数值结果（r = 168 ω），这符合计算题的特征。 | 知识层次: 题目要求进行基本的电阻计算，仅涉及单一公式的直接应用和简单数值计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算电阻，仅需直接套用基本公式（如欧姆定律或电阻公式）并进行简单计算即可得出答案。无需多个公式组合或复杂步骤，符合等级1的定义。" + }, + { + "idx": 3575, + "question": "Aluminum foil used for storing food weighs about 0.3g per square inch. How many atoms of aluminum are contained in one square inch of foil?", + "answer": "6.69 × 10^{21} atoms", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及单位转换和摩尔计算，最终给出具体的数值答案。 | 知识层次: 题目需要进行基本的单位转换和摩尔计算，涉及简单的公式应用和数值计算，属于直接套用基本概念和公式的范畴。 | 难度: 在选择题中属于简单应用难度，需要应用摩尔质量和阿伏伽德罗常数的基本公式进行计算，但步骤较为直接，仅涉及单位转换和简单乘法运算。" + }, + { + "idx": 2890, + "question": "Using the data from the previous question, assuming the alloy composition is Al-0.5%Cu and there is no convection in the liquid, calculate the temperature gradient required to maintain a planar solid-liquid interface.", + "answer": "G≥(m w0 R(1-k0))/(D k0)=(320×0.005×3×10^-4×(1-0.16))/(3×10^-5×0.16)=84℃/cm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及公式应用和参数代入，需要理解温度梯度与合金成分、扩散系数等参数之间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解合金凝固理论中的多个关键概念（如成分过冷、溶质分配系数等），并正确应用公式进行多步骤计算。题目要求将理论知识与具体参数代入相结合，且计算过程涉及单位换算和负号处理，在选择题型中属于需要较强综合分析能力的题目。" + }, + { + "idx": 2983, + "question": "Calculate the diffusion coefficient D of carbon at 920°C, given the activation energy for diffusion is 133984 J/mol and D0=0.23 cm²/s.", + "answer": "D = D0 × exp(-Q/(RT)) = 0.23 × exp(-133984/(8.314 × (273 + 920))) = 3.12 × 10^-7 cm²/s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数D的具体数值。答案是一个具体的计算结果，而不是选择、判断或文字解释。 | 知识层次: 题目主要考查基本公式的直接应用和简单计算，涉及扩散系数的计算，需要套用给定的公式和参数进行数值计算，思维过程较为直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（D = D0 × exp(-Q/(RT))）并进行简单的数值计算。题目没有涉及多个公式的组合或复杂的逻辑推理，属于单一公式直接计算的类型，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 2202, + "question": "Given that the melting point of copper is 1,083℃, estimate the minimum recrystallization temperature of copper", + "answer": "The minimum recrystallization temperature of copper is T_r=0.4×(1,083+273)=542 K", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用0.4乘以铜的熔点加上273来转换单位并计算最低再结晶温度）来得出具体数值结果，答案是一个计算得出的数值而非文字解释或选择判断。 | 知识层次: 题目涉及基本公式应用（0.4×Tm）和简单计算（温度转换和乘法），不需要多步计算或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目仅需直接套用单一公式（T_r=0.4×(T_m+273)）进行简单计算，无需理解多个概念或进行复杂分析。题目明确给出了铜的熔点数据，解题步骤仅涉及基本代数运算，属于最基础的应用层级。" + }, + { + "idx": 4571, + "question": "Under these circumstances, how long does it take an electron to traverse a 25-mm (1-in.) length of crystal?", + "answer": "the time required for an electron to traverse a 25-mm length of crystal is 6.6 × 10^-5 s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算电子通过25毫米晶体所需的时间，答案给出了具体的数值计算结果（6.6 × 10^-5 s），这表明需要进行数值计算和公式应用。 | 知识层次: 题目涉及基本公式应用和简单计算，仅需直接套用公式计算电子穿越晶体所需时间，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接计算，即计算电子通过给定长度晶体所需的时间。题目明确给出了正确选项，且解题步骤简单，仅需套用基本公式进行简单计算即可得出答案。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4715, + "question": "Calculate the number of atoms per cubic meter in chromium.", + "answer": "the number of atoms per cubic meter in chromium is 8.33 × 10^{28} \\ \\text{atoms/m}^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铬中每立方米的原子数），答案是一个具体的数值结果（8.33 × 10^{28} atoms/m^3），这符合计算题的特征。 | 知识层次: 题目要求计算铬中每立方米的原子数，这需要应用基本的密度和摩尔质量公式进行简单计算，属于直接套用基本公式的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅要求计算铬的原子密度，可以直接套用已知的铬的原子密度公式或数据（8.33 × 10^{28} atoms/m^3），无需进行复杂的推导或多步骤计算。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4776, + "question": "The lower yield point for an iron that has an average grain diameter of 1 × 10^{-2}mm is 230 MPa(33,000 psi). At a grain diameter of 6 × 10^{-3} mm, the yield point increases to 275 MPa (40,000 psi). At what grain diameter will the lower yield point be 310 MPa(45,000 psi) ?\n\\underline{\\text {", + "answer": "the grain diameter at which the lower yield point is 310 MPa is 4.34 × 10^{-3} mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解特定的晶粒直径，答案是一个具体的数值结果，解答过程涉及材料科学中的Hall-Petch关系等计算步骤。 | 知识层次: 题目需要应用Hall-Petch关系进行多步计算，涉及不同晶粒尺寸下的屈服强度变化，需要理解公式中各参数的含义并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hall-Petch关系并进行多步计算。题目要求将屈服强度与晶粒尺寸的关系公式化，并通过已知数据求解未知参数，涉及材料科学中的核心概念和数学运算。虽然计算步骤明确，但需要综合应用多个知识点才能得出正确答案。" + }, + { + "idx": 4588, + "question": "A parallel-plate capacitor using a dielectric material having an \\varepsilon_{r} of 2.5 has a plate spacing of 1 mm (0.04 in.). If another material having a dielectric constant of 4.0 is used and the capacitance is to be unchanged, what must be the new spacing between the plates?", + "answer": "the new spacing between the plates must be 1.6 mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过数值计算和公式应用来解决问题，涉及电容器的参数变化和计算新的板间距。答案是一个具体的数值结果（1.6 mm），而不是选择、判断或文字解释。 | 知识层次: 题目涉及基本的电容公式应用和简单计算，只需要理解电容与介电常数和板间距的关系，并进行一步计算即可得出结果。不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。题目要求考生理解平行板电容器的基本公式（C = εA/d），并能够根据给定的介电常数变化调整板间距以保持电容不变。虽然涉及两个不同的介电常数，但计算步骤直接且无需复杂的推导或分析，属于简单应用层次。" + }, + { + "idx": 2798, + "question": "Calculate the total migration distance $S$ of carbon atoms, given the carbon atom jump frequency as $\\Gamma=1.7\\times10^{9}/\\mathrm{s}$, jump distance as $2.53\\times10^{-10}\\mathrm{m}$, and time as $4\\mathrm{h}$.", + "answer": "$4\\mathrm{h}=4\\times3600\\mathrm{s}$, $S=\\Gamma \\cdot t \\cdot r=1.7\\times10^{9}\\times4\\times3600\\times2.53\\times10^{-10}=6193\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及单位转换和乘法运算，最终给出具体的计算结果。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即利用给定的参数（跳频、跳跃距离和时间）通过公式计算迁移距离。虽然需要单位转换，但整体思维过程较为直接，不涉及多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，解题步骤简单，仅涉及基本公式应用和简单计算，无需多个公式组合或复杂分析，因此属于最低难度等级。" + }, + { + "idx": 3763, + "question": "Calculate the height of the cylindrical riser required to prevent shrinkage in a 1 in. x 6 in. x 6 in. casting if the H/D of the riser is 1.0.", + "answer": "the height of the riser must be at least 2.25 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算圆柱形冒口的高度），并给出了具体的尺寸条件和比例要求（H/D=1.0），最终答案是一个具体的数值（2.25 in）。这符合计算题的特征，即需要应用公式和进行数值计算来解决问题。 | 知识层次: 题目涉及基本的公式应用和简单计算，需要根据给定的H/D比例和铸件尺寸计算冒口高度，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，需要基本公式应用和简单计算。虽然涉及H/D比的概念，但解题步骤相对直接，只需套用给定比例进行计算即可。相比等级1的直接计算，此题需要理解H/D比的含义，因此属于等级2。" + }, + { + "idx": 200, + "question": "The eutectic of the MgO-Al2O3-SiO2 system is placed on a Si3N4 ceramic plate. At the eutectic temperature, the surface tension of the liquid phase is 900 mN/m, the interfacial energy between the liquid and solid is 600 mN/m, and the measured contact angle is 70.52°. Find the surface tension of Si3N4.", + "answer": "Yv = Ycosθ + Y = 900cos70.52° + 600 = 900 mN/m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Si3N4的表面张力，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即使用表面张力和接触角的公式进行直接计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目直接给出了所需的公式（Yv = Ycosθ + Y），并且只需要进行简单的代入和计算（代入θ=70.52°和给定的表面张力值）。虽然涉及到了接触角和表面张力的概念，但解题步骤非常直接，无需复杂的推导或分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4207, + "question": "If the atomic radius of aluminum is 0.143nm, calculate the volume of its unit cell in cubic meters.", + "answer": "the volume of the unit cell is 6.62 × 10^{-29} m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（基于给定的原子半径）来求解单位晶胞的体积，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要知道单位晶胞体积的计算公式（如立方晶系的边长为4r/√2）并进行数值代入即可完成，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（单位晶胞体积计算公式）进行计算，无需多个步骤或复杂推理。题目提供了所有必要的信息（原子半径），且计算过程简单直接，属于最基础的难度等级。" }, { "idx": 2818, @@ -81,79 +3549,2743 @@ "knowledge_level_name": "简单应用", "difficulty": 2, "final_level": "Level_2", - "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝线在拉力作用下的总长度，答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式（胡克定律）的直接应用和简单计算，不需要多步推理或综合分析，属于基础知识的直接运用。 | 难度: 在计算题中属于简单公式应用计算，仅需直接套用Hooke's law公式进行一步变形和数值代入。虽然涉及单位换算（GPa到Pa，mm到m），但计算过程明确且无复杂推导步骤，属于该题型内中等偏下难度。" + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝线在拉伸力作用下的总长度，答案中包含了具体的计算步骤和最终数值结果，符合计算题的特征。 | 知识层次: 题目主要考查Hooke's law的基本公式应用和简单计算，涉及弹性模量、应力和应变的基本概念，计算过程直接套用公式，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目涉及弹性模量、应力应变关系等概念，但解题过程仅需直接套用Hooke's定律公式，进行简单的代数运算即可得出结果。不需要复杂的推导或多步骤计算，属于选择题中较为基础的题型。" }, { - "idx": 2846, - "question": "Indicate the easy slip plane and easy slip direction of Cu crystal, and calculate the slip plane spacing, atomic spacing in the slip direction, and lattice resistance. (Given G_Cu=48.3GPa, ν=0.3)", - "answer": "Cu has an fcc structure, with the easy slip plane being {111} and the easy slip direction being <110>. The slip plane spacing d_(111)=a/√3, and the atomic spacing in the slip direction b=√2/2a. The lattice resistance τ_PN=(2×48.3×10^9)/(1-0.3)×exp[-2π(a/√3)/((1-0.3)(√2/2)a)]=90.45MPa.", + "idx": 4223, + "question": "(a) Derive the planar density expression for the HCP (0001) plane in terms of the atomic radius R.", + "answer": "the planar density expression for the hcp (0001) plane in terms of the atomic radius r is: pd_{0001} = 1 / (2 r^{2} sqrt(3))", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求进行数值计算和公式应用，包括计算滑移面间距、滑移方向原子间距和晶格阻力，答案中给出了具体的计算过程和结果。 | 知识层次: 题目需要理解Cu晶体的fcc结构，识别易滑移面和方向，并应用公式计算滑移面间距、原子间距和晶格阻力。涉及多步计算和概念关联，但不需要复杂的综合分析或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解晶体结构的基本概念（如fcc结构、滑移面和滑移方向），掌握相关公式（如滑移面间距、原子间距的计算），并进行多步骤的数值计算（包括指数函数的应用）。虽然涉及多个计算步骤，但整体思路清晰，属于中等应用层次的计算题。" + "reasoning": "题型: 题目要求推导HCP (0001)面的平面密度表达式，涉及原子半径R的计算和公式应用，答案是一个具体的数学表达式，符合计算题的特征。 | 知识层次: 题目要求推导HCP (0001)面的面密度表达式，涉及晶体结构几何关系的理解和多步计算，需要将原子半径与晶面几何参数关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解HCP晶体结构、(0001)晶面特征、原子半径与晶格参数关系等多个概念，并正确应用平面密度计算公式。虽然题目给出了正确选项，但需要考生具备综合分析能力才能判断选项的正确性，涉及多步推导和单位晶胞内原子数的计算。" }, { - "idx": 3153, - "question": "In stable ZrO2 material, cations form an fcc structure, and anions occupy tetrahedral interstitial sites. If 20 mol% CaO is added, calculate how many anions are needed for 100 cations?", - "answer": "Since the amount of CaO added to ZrO2 is 20 mol%, the total charge number for 100 cations is 20×2 + 80×4 = 360. To maintain electrical neutrality, the required number of O2− anions is 360 ÷ 2 = 180.", + "idx": 4430, + "question": "Cadmium sulfide (CdS) has a cubic unit cell, and from x-ray diffraction data it is known that the cell edge length is 0.582nm. If the measured density is 4.82g / {cm}^{3}, how many \\mathrm{Cd}^{2+} and \\mathrm{S}^{2-} ions are there per unit cell?", + "answer": "there are four \\mathrm{cd}^{2+} and four s^{2-} ions per unit cell.", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求进行数值计算（计算需要的阴离子数量），并应用了电荷平衡的公式来解决问题。答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（计算总电荷数、维持电中性所需阴离子数），并需要理解掺杂对电荷平衡的影响，涉及概念关联和综合分析。 | 难度: 在计算题中属于综合性计算问题，需要理解电荷平衡的概念，进行多步计算（包括摩尔百分比转换、电荷总和计算、电中性平衡计算），并正确应用化学计量关系。虽然不涉及复杂多变量，但解题步骤和概念关联要求较高，属于该题型内的中等偏上难度。" + "reasoning": "题型: 题目需要通过数值计算和公式应用（如密度公式、单位晶胞体积计算等）来确定单位晶胞中的离子数量，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括利用晶胞边长计算体积、密度公式的应用以及离子数量的推导，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的思维深度和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算和化学计量比等多个概念，并进行多步计算和综合分析。虽然题目提供了正确选项，但解题过程涉及单位转换、摩尔质量计算和离子数目的推导，步骤较为复杂。" }, { - "idx": 3173, - "question": "The density of $\\\\mathrm{CaF}_{2}$ is $\\\\rho=3.18~\\\\mathrm{g/cm}^{3}$, the lattice constant is $a=0.5463\\\\mathrm{nm}$, and the relative atomic masses of Ca and F are 40.08 and 19.00, respectively. Calculate the number of Schottky vacancies in the unit cell of CaF2.", - "answer": "To maintain electrical neutrality, in the $\\\\mathrm{CaF}_{2}$ ionic crystal, for every Schottky defect formed, one $\\\\mathrm{Ca}^{2+}$ and two $\\\\mathbf{F}^{-}$ must be lost simultaneously. Let the number of Schottky defects in the unit cell be $x$, then $$ x\\\\rho=\\\\frac{\\\\left(4-x\\\\right)\\\\left(40.08+19\\\\times2\\\\right)/6.023\\\\times10^{23}}{5.463^{3}\\\\times10^{-24}}\\\\approx3.18\\\\left({\\\\mathrm{g}}/{\\\\mathrm{cm}^{3}}\\\\right) $$ Therefore, $$ x=4-\\\\frac{6.023\\\\times10^{23}\\\\times3.18\\\\times5.463^{3}\\\\times10^{-24}}{40.08+19.00\\\\times2}\\\\approx6.10\\\\times10^{-4}\\\\uparrow $$", + "idx": 3732, + "question": "A polymer that contains internal flaws 1mm in length fails at a stress of 25 MPa. Determine the plane strain fracture toughness of the polymer. Assume that f=1.", + "answer": "the plane strain fracture toughness of the polymer is 0.99 \\text{mpa} \\sqrt{m}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（平面应变断裂韧性公式）来求解聚合物的平面应变断裂韧性，答案是一个具体的数值结果（0.99 MPa√m），符合计算题的特征。 | 知识层次: 题目需要应用基本公式（断裂韧性公式）进行简单计算，属于直接套用公式的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求直接应用平面应变断裂韧性的基本公式（K_IC = σ√(πa)），仅需代入给定的应力（25 MPa）和缺陷长度（1mm）即可得出结果。无需额外的概念理解或复杂计算步骤，属于最基础的公式套用类型。" + }, + { + "idx": 2843, + "question": "For a bcc crystal with a critical resolved shear stress of ${60}\\\\mathbf{M}\\\\mathbf{Pa}$ on the (110)[111] slip system, how much stress must be applied in the [001] and [010] directions to initiate slip?", + "answer": "$A C$ and $A^{\\\\prime}C^{\\\\prime}$ are the distances between two adjacent slip planes in the crystal before and after stretching, respectively. Since the distance between slip planes remains unchanged before and after stretching, i.e., $A C{=}A^{\\\\prime}C^{\\\\prime}$, we have \\n$$\\n\\\\epsilon={\\\\frac{A^{\\\\prime}B^{\\\\prime}-A B}{A B}}={\\\\frac{{\\\\frac{A^{\\\\prime}C^{\\\\prime}}{\\\\sin30^{\\\\circ}}}-{\\\\frac{A C}{\\\\sin45^{\\\\circ}}}}{\\\\frac{A C}{\\\\sin45^{\\\\circ}}}}\\n$$\\n\\n$$\\n={\\\\frac{2-{\\\\sqrt{2}}}{\\\\sqrt{2}}}=41.4\\\\%\\n$$", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了密度、晶格常数、相对原子质量等数据的计算，最终得出肖特基空位的数量。答案展示了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位换算、以及缺陷化学中的电荷平衡考虑。虽然不涉及复杂的机理分析或创新设计，但需要综合运用多个概念和公式进行数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要理解Schottky缺陷的概念，进行多步计算，包括密度公式的应用、单位转换和数值计算。虽然涉及多个步骤和概念关联，但整体计算过程相对直接，没有过于复杂的变量或推导过程。" + "reasoning": "题型: 题目要求计算在特定方向上施加的应力以启动滑移，涉及数值计算和公式应用。答案中包含了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解临界分切应力的概念，并应用施密特定律计算不同方向上的应力分量。虽然不涉及复杂的机理分析或创新设计，但需要综合分析晶体结构和应力方向的关系。 | 难度: 在选择题中属于中等偏上难度，需要理解临界分切应力的概念，并能够正确应用施密特定律进行计算。题目涉及多步计算过程，包括确定施密特因子和计算所需应力，同时需要综合分析晶体结构和滑移系统的几何关系。虽然题目提供了明确的方向和滑移系统，但解题步骤较为复杂，需要较强的概念关联和计算能力。" }, { - "idx": 3824, - "question": "Consider an Al-4% Si alloy. Determine the amounts and compositions of each phase at 576 degrees C.", - "answer": "alpha: 1.65% si, beta: 99.83% si, % alpha=97.6%, % beta=2.4%", + "idx": 3171, + "question": "Two positive edge dislocations on the same slip plane, each with a Burgers vector b, when they approach infinitely close, what is the total energy?", + "answer": "When two positive edge dislocations approach infinitely close, it is equivalent to the energy of a single large dislocation with a Burgers vector 2b, W=α⋅G(2b)²=4αGb²", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求通过计算确定各相的含量和组成，答案给出了具体的数值结果，涉及相图分析和成分计算，属于典型的计算题类型。 | 知识层次: 题目需要应用相图知识进行多步计算，包括确定各相的成分和相对量，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在计算题中属于综合性计算问题，需要理解相图概念并进行多步计算。题目要求确定特定温度下合金的各相组成和比例，涉及读取相图数据、应用杠杆法则计算相比例，以及综合分析相组成。虽然步骤明确，但需要准确关联多个概念和进行精确计算，因此在同类计算题中属于中等偏上难度。" + "reasoning": "题型: 题目要求计算两个正刃位错无限接近时的总能量，答案涉及数值计算和公式应用（W=α⋅G(2b)²=4αGb²），属于典型的计算题。 | 知识层次: 题目需要理解位错的基本概念（如Burgers向量和能量关系），并应用公式进行多步计算（从单个位错能量推导出两个位错接近时的总能量）。虽然涉及基础概念，但需要一定的综合分析能力来理解位错相互作用的等效性。 | 难度: 在选择题中属于中等难度，需要理解位错能量公式（W=αGb²）的概念，并能将两个相同位错的接近等效为一个双倍伯格斯矢量的位错（2b），然后进行能量计算（4αGb²）。这涉及多步概念关联和公式应用，但不需要处理复杂变量或多种条件组合。" }, { - "idx": 3911, - "question": "Niobium (Nb) has a BCC crystal structure, an atomic radius of 0.143nm and an atomic weight of 92.91g / mol. Calculate the theoretical density for nb.", - "answer": "the theoretical density for nb is 8.48g / {cm}^{3}. the experimental density for nb is 8.57g / {cm}^{3}.", + "idx": 3692, + "question": "A BCC iron structure is to be manufactured that will allow no more than 50g of hydrogen to be lost per year through each square centimeter of the iron at 400^{\\circ} C. If the concentration of hydrogen at one surface is 0.05 H atom per unit cell and is 0.001 H atom per unit cell at the second surface, determine the minimum thickness of the iron.", + "answer": "the minimum thickness of the iron is 0.179 cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如扩散定律）来确定铁的最小厚度，答案是一个具体的数值结果（0.179 cm），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和BCC结构的相关知识，进行综合分析以确定最小厚度。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散定律、晶体结构、浓度梯度等概念，并进行多步计算和综合分析。虽然题目提供了正确选项，但解题过程涉及单位转换、扩散系数查找或计算、菲克第一定律的应用等复杂步骤，对学生的知识掌握和计算能力要求较高。" + }, + { + "idx": 1776, + "question": "A green body with an initial particle size of 5μm is sintered for 2h to reach x/r=0.1. If sintering continues until x/r=0.2 (without considering grain growth), what is the required sintering time when material transport occurs via dissolution-precipitation?", + "answer": "128h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算，涉及公式应用（如烧结时间与x/r的关系），答案是一个具体的数值（128h），属于典型的计算题特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解溶解-沉淀机制下的烧结动力学关系，并通过初始条件推导出新的烧结时间。虽然不涉及复杂的机理分析或创新设计，但需要将概念关联并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解溶解-沉淀机制下的烧结动力学关系，并能正确应用x/r与时间的关系公式（通常为立方关系）。解题需要两个关键步骤：1) 根据初始条件建立时间与x/r的关系；2) 利用立方关系计算新x/r对应的时间（0.2/0.1的立方倍）。虽然计算本身不复杂，但需要准确识别材料传输机制对应的动力学模型，并正确关联题目条件与理论公式。" + }, + { + "idx": 3666, + "question": "Calculate the length of the Burgers vector in diamond cubic silicon", + "answer": "b = 3.840 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Burgers vector的长度），答案是一个具体的数值结果（3.840 Å），这符合计算题的特征。 | 知识层次: 题目需要计算Burgers向量的长度，这涉及到对晶体结构（金刚石立方硅）的理解以及相关公式的应用。虽然计算本身可能不复杂，但需要理解Burgers向量的定义、晶体结构的知识以及如何将这些知识应用到具体材料中。这属于中等应用层次，因为它需要多步计算和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解Burgers向量的概念，知道金刚石立方结构硅的晶格常数，并能正确计算Burgers向量的长度。这涉及到多个步骤的计算和对晶体结构概念的综合应用。" + }, + { + "idx": 2321, + "question": "In a Kevlar fiber-epoxy resin composite, the fiber volume fraction is 0.3, the elastic modulus of the epoxy resin is 31 GPa, and the elastic modulus of the Kevlar fiber is 124 GPa. Calculate the modulus parallel to the fiber direction.", + "answer": "The modulus in the fiber direction is 58.9 GPa. Calculation process: E_T=0.3×124+0.7×31=58.9 GPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解复合材料在纤维方向的模量，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目考查基本公式的直接应用和简单计算，仅需套用复合材料模量的混合法则公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（混合法则）进行计算，无需复杂的分析或组合多个公式。解题步骤简单明了，属于最基础的难度等级。" + }, + { + "idx": 2891, + "question": "Using the data from the previous question, assuming the alloy composition is Al-2%Cu and there is no liquid convection, calculate the interface temperature at the beginning of solidification", + "answer": "T=T0-m(w0/k0)=660.37-320×(0.02/0.16)=620.37℃", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是一个具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需理解公式中各参数的含义并进行数值代入计算。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算（T=T0-m(w0/k0)），无需额外的理解或组合多个公式。题目提供了所有必要的数据，解题步骤简单直接，属于最基础的难度等级。" + }, + { + "idx": 3629, + "question": "For \\mathrm{UO}_{2} with fluorite structure, determine the lattice parameter.", + "answer": "5.2885 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定UO2的晶格参数，需要通过计算或查阅相关数据得出具体数值（5.2885 Å），属于需要数值结果的计算题。 | 知识层次: 题目要求确定UO2的晶格参数，这属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求确定具有萤石结构的UO₂的晶格参数，正确选项直接给出数值5.2885 Å。解题过程仅需应用基本公式或直接引用已知数据，无需复杂计算或多步骤推理。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4839, + "question": "At room temperature the electrical conductivity and the electron mobility for aluminum are 3.8 x 10^7 (Ω·m)^-1 and 0.0012 m^2/V·s, respectively. What is the number of free electrons per aluminum atom? Assume a density of 2.7 g/cm^3.", + "answer": "the number of free electrons per aluminum atom is 3.28 electrons/al atom.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定每个铝原子中的自由电子数量。答案是一个具体的数值结果，而不是选择、判断或文字解释。 | 知识层次: 题目需要进行多步计算，涉及电导率、电子迁移率和密度的概念关联，以及自由电子数的综合分析。虽然不涉及复杂的推理或机理解释，但需要一定的计算能力和概念理解。 | 难度: 在选择题中属于中等偏上难度，需要综合运用电导率、电子迁移率、密度等概念，并进行多步计算才能得出结果。虽然题目提供了所有必要数据，但解题过程涉及单位转换、公式推导和综合分析能力，对学生的知识掌握深度和计算能力要求较高。" + }, + { + "idx": 4813, + "question": "A cylindrical specimen 13.2mm in diameter of an S-590 alloy is to be exposed to a tensile load of 27,000N. At approximately what temperature will the steady-state creep be 10^{-3} h^{-1} ?", + "answer": "the temperature would be approximately 775^\\circ c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定特定条件下的温度值，答案是一个具体的数值（775°C），这表明解答过程涉及计算和可能的数据查找或插值。 | 知识层次: 题目需要进行多步计算，包括应用蠕变速率公式和材料性能参数，涉及概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行比较分析。题目涉及圆柱形试样的直径、拉伸载荷以及稳态蠕变速率，要求考生能够综合运用材料科学中的蠕变理论和相关公式进行计算。虽然题目提供了正确选项，但解题过程需要多步骤计算和概念关联，包括应力计算、蠕变方程的运用以及温度的反推，这些步骤在选择题型中属于较为复杂的计算问题。" + }, + { + "idx": 3796, + "question": "Suppose a 1200-lb bath of a Nb-40 wt % W alloy is held at 2800 degrees C. How many pounds of tungsten can be added to the bath before any solid forms?", + "answer": "212 additional pounds of W must be added before any solid forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定需要添加的钨的质量。答案给出了具体的数值结果，表明这是一个计算题。 | 知识层次: 题目需要进行多步计算，涉及合金成分和相图的应用，需要综合分析温度、成分和相变条件之间的关系，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、进行多步计算（包括质量平衡和成分计算），并综合分析温度与成分的关系。虽然题目提供了正确选项减少了干扰项判断，但解题过程仍涉及较复杂的应用能力。" + }, + { + "idx": 43, + "question": "According to the radius ratio relationship, what is the coordination number when Al3+ coordinates with O2-? Given rO2-=0.132nm, rAl3+=0.057nm.", + "answer": "For Al3+, r+/r-=0.057/0.132=0.43; based on the relationship between cation coordination number and the radius ratio of positive to negative ions, the coordination number is 6.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径进行数值计算（r+/r-比值），并根据半径比关系确定配位数。解答过程涉及具体计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目主要涉及半径比的计算和基本配位数关系的直接应用，属于基本公式套用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需应用半径比公式（r+/r-）进行简单计算，并根据给定的半径比直接查表或记忆对应的配位数。无需多个公式组合或复杂推理，解题步骤简单直接，属于基础知识的简单应用。" + }, + { + "idx": 2158, + "question": "The critical resolved shear stress of an aluminum single crystal at room temperature is $7.9\\\\times10^{5}~\\\\mathrm{Pa}$. If a tensile test is performed on an aluminum single crystal specimen at room temperature with the tensile axis in the [123] direction, and the possible activated slip system is (111)[101], determine the stress required to cause the specimen to yield.", + "answer": "The aluminum crystal has a face-centered cubic lattice, and its slip system is $\\\\{111\\\\}<110>$. When performing a tensile test on an aluminum single crystal: $$ \\\\sigma_{s}=\\\\frac{\\\\tau_{\\\\mathrm{c}}}{\\\\cos\\\\varphi\\\\cos\\\\lambda} $$ Given $\\\\tau_{\\\\mathrm{c}}=7.9\\\\times10^{5}~\\\\mathrm{Pa}$, when the external force axis direction is [123], the possible activated slip system is (111)[101]. Thus, $\\\\varphi$ is the angle between [123] and the normal [111] of the (111) crystal plane, and $\\\\lambda$ is the angle between [123] and [101]. $$ \\\\mathrm{cos}\\\\varphi={\\\\frac{{\\\\overline{{1}}}+2+3}{\\\\sqrt{14}\\\\times\\\\sqrt{3}}}={\\\\frac{4}{\\\\sqrt{42}}} $$ $$ \\\\cos\\\\lambda={\\\\frac{1+0+3}{\\\\sqrt{14}\\\\times{\\\\sqrt{2}}}}={\\\\frac{2}{\\\\sqrt{7}}} $$ Therefore, $$ \\\\sigma_{\\\\mathrm{s}}=\\\\frac{7.9\\\\times10^{5}}{\\\\frac{4}{\\\\sqrt{42}}\\\\times\\\\frac{2}{\\\\sqrt{7}}}=1.69\\\\times10^{6}~\\\\mathrm{Pa} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定应力值，解答过程中涉及角度计算和临界分切应力的应用，最终得出具体的数值结果。 | 知识层次: 题目涉及多步计算，需要理解临界分切应力的概念，并应用施密特定律进行计算。同时需要计算晶体学方向之间的角度，涉及多个步骤和概念的综合应用。 | 难度: 在选择题中属于中等偏上难度，需要理解临界分切应力的概念，掌握晶体学方向指数的计算，并能正确应用施密特定律进行多步骤计算。题目涉及向量点积、角度计算和应力转换等综合分析步骤，对学生的空间想象力和数学计算能力有一定要求。虽然题目提供了具体方向和滑移系统，但计算过程较为复杂，属于综合性计算问题。" + }, + { + "idx": 2374, + "question": "Assuming an ionic crystal has monovalent cations and anions, with a cation vacancy formation energy of 2000, an anion vacancy formation energy of 101-1'tra01, and a cation interstitial formation energy of 30k=1,17701, calculate the relative concentration of Schottky defects.", + "answer": "The formation energy of a Schottky defect is the sum of the cation vacancy formation energy and the anion vacancy formation energy, which is (20+40) kJ/mol = 60 kJ/mol. The relative concentration of Schottky defects is exp(-60×10^3/RT). For example, at room temperature (300K), the above ratio equals 0.018.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算（计算Schottky缺陷的相对浓度），并给出了具体的能量值和计算公式（exp(-60×10^3/RT)），最终需要得出一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括理解Schottky缺陷的形成能计算和相对浓度的公式应用，涉及能量求和和指数计算，需要一定的综合分析能力。虽然公式直接给出，但需要正确理解和应用这些公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解Schottky缺陷的形成能计算概念，并正确应用公式进行多步计算（包括能量求和和指数运算）。虽然题目提供了部分计算示例，但仍需要考生掌握相关物理化学知识才能正确推导和验证选项。" + }, + { + "idx": 4478, + "question": "Compute repeat unit molecular weight for polycarbonate", + "answer": "254.27g/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行具体的数值计算（计算聚碳酸酯的重复单元分子量），答案是一个具体的数值（254.27g/mol），这符合计算题的特征。 | 知识层次: 题目要求计算聚碳酸酯的重复单元分子量，这属于基本公式应用和简单计算，直接套用分子量计算公式即可完成，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用已知的重复单元分子量计算公式，属于单一公式直接计算类型。题目提供正确选项，学生只需识别并选择正确数值，无需进行复杂推导或多步骤计算，因此属于最低难度等级。" + }, + { + "idx": 3258, + "question": "Given that brass with a zinc mass fraction of 30% takes 1 hour to complete recrystallization at a constant temperature of 400°C, and 2 hours at 390°C, calculate how much time is needed to complete recrystallization at a constant temperature of 420°C.", + "answer": "Recrystallization of cold-deformed metal is also a thermally activated process, and the recrystallization rate follows the Arrhenius equation $$ V_{\\overline{{\\{\\}}}}=A^{\\prime}\\cdot\\mathrm{e}^{-Q/R T} $$ Since $V_{\\overrightarrow{\\vert\\overrightarrow{\\vert\\cdot}\\vert}}$ is inversely proportional to the time $\\scriptstyle t$ required to achieve a certain volume fraction $x_{\\upsilon}$, i.e., $V_{\\mathrm{\\#}}\\propto1/t$, we have $$ \\frac{1}{t_{1}}=A\\mathrm{e}^{-\\frac{Q}{R T_{1}}};\\frac{1}{t_{2}}=A\\mathrm{e}^{-\\frac{Q}{R T_{2}}};\\frac{1}{t_{3}}=A\\mathrm{e}^{-\\frac{Q}{R T_{3}}} $$ From the above three equations, dividing them pairwise yields $$ \\frac{t_{2}}{t_{1}}=\\mathrm{e}^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{2}}\\right)};\\quad\\frac{t_{3}}{t_{1}}=\\mathrm{e}^{-\\frac{Q}{R}\\left(\\frac{1}{T_{1}}-\\frac{1}{T_{3}}\\right)} $$ Taking the natural logarithm and then dividing gives $$ \\frac{\\ln(t_{2}/t_{1})}{\\ln(t_{3}/t_{1})}=\\frac{1/T_{1}-1/T_{2}}{1/T_{1}-1/T_{3}} $$ Substituting $T_{1}=673~\\mathrm{K},t_{1}=1~\\mathrm{h};~T_{2}=663~\\mathrm{K},t_{2}=2~\\mathrm{h};~T_{3}=693~\\mathrm{K}$ into the above equation, we obtain $t_{3}=0.27$ h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Arrhenius方程）来解决具体问题，答案给出了详细的计算过程和最终的时间结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要应用Arrhenius方程进行推导和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解Arrhenius方程及其在再结晶过程中的应用，进行多步计算和温度转换（摄氏到开尔文），并正确运用对数运算来求解时间。虽然题目提供了必要的公式和数据，但解题步骤较为复杂，涉及多个概念的综合运用和计算。" + }, + { + "idx": 2661, + "question": "The crystal structure of Ni is face-centered cubic, and its atomic radius is r=0.1243nm. Calculate the lattice constant of Ni.", + "answer": "a=4r/sqrt(2)=4×0.1243/sqrt(2)=0.3516(nm)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（使用原子半径和面心立方晶格常数公式）来求解镍的晶格常数，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要套用已知的原子半径和面心立方晶格常数的关系公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了面心立方晶体的晶格常数计算公式a=4r/sqrt(2)，只需要将给定的原子半径r=0.1243nm代入公式进行简单计算即可得到正确答案。不需要额外的概念理解或复杂的解题步骤，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 4641, + "question": "Solve for (r) in terms of (A, B), and (n), which yields (r_{0}), the equilibrium interionic spacing.", + "answer": "The equilibrium interionic spacing (r_{0}) is solved in terms of (A, B), and (n).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过公式和变量关系求解平衡离子间距(r_{0})，涉及数值计算和公式应用，属于典型的计算题类型。 | 知识层次: 题目要求解平衡离子间距(r_{0})，涉及多个变量(A, B, n)的计算和公式应用，需要多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解平衡离子间距的概念，并能够将A、B、n等变量关联起来进行综合分析。虽然题目给出了正确选项，但考生仍需掌握多步计算过程和变量间的相互作用才能正确理解并选择答案。这比单纯记忆概念或简单计算要复杂，但尚未达到最复杂的多变量计算水平。" + }, + { + "idx": 2049, + "question": "What is the quantitative relationship between the critical nucleus radius r_k and the undercooling ΔT?", + "answer": "The critical nucleus radius r_k, whose size is related to the undercooling, is given by r_k=(2σT_m)/(L_m)×1/ΔT", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求定量描述临界核半径r_k与过冷度ΔT之间的关系，并给出了具体的计算公式，需要应用公式进行计算和推导 | 知识层次: 题目要求应用给定的公式进行定量计算，涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用，即临界核半径与过冷度之间的定量关系。学生只需识别并正确套用给定公式即可作答，无需进行额外的计算或概念分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 881, + "question": "Given that the nearest neighbor atomic spacing in a diamond unit cell is 0.1544nm, determine the lattice constant a of diamond.", + "answer": "The nearest neighbor atomic spacing is 0.1544nm, i.e., the bond length d = 0.1544nm. In the diamond structure, the relationship between the bond length and the lattice constant is d = (a√3)/4, thus a = (4d)/√3 = (4 × 0.1544nm)/1.732 ≈ 0.3566nm.", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "simple_application", "knowledge_level_name": "简单应用", "difficulty": 2, "final_level": "Level_2", - "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铌的理论密度，答案给出了具体的计算结果，符合计算题的特征。 | 知识层次: 题目涉及基本的晶体结构参数（BCC）和原子半径，需要应用密度计算公式进行简单数值计算，属于直接套用基本公式的范畴。虽然需要理解BCC结构的晶格常数与原子半径的关系，但整体思维过程较为直接，不涉及多步计算或综合分析。 | 难度: 在计算题中属于简单公式应用计算难度。题目要求计算理论密度，需要应用BCC晶体结构的边长与原子半径关系公式（a = 4r/√3）以及密度计算公式（ρ = nA/VcNA），但这两个公式都是材料科学基础课程中的标准公式，且计算过程直接套用即可完成，无需复杂推导或组合多个公式。虽然涉及单位换算（nm到cm），但这是常规操作，不增加额外难度。" + "reasoning": "题型: 题目要求通过数值计算和公式应用（d = (a√3)/4）来确定晶格常数a，解答过程涉及具体的数学运算和单位转换，属于典型的计算题。 | 知识层次: 题目涉及基本的公式应用和简单计算，即通过已知的原子间距和钻石结构的几何关系直接套用公式求解晶格常数。虽然需要理解钻石结构的基本几何关系，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解钻石结构中原子间距与晶格常数的关系，但解题步骤直接，仅需套用一个基本公式（d = (a√3)/4）并进行简单代数运算即可得出答案。无需多个公式组合或复杂分析，因此属于等级2难度。" }, { - "idx": 4443, - "question": "The fracture strength of glass may be increased by etching away a thin surface layer. It is believed that the etching may alter surface crack geometry (i.e., reduce crack length and increase the tip radius). Compute the ratio of the original and etched crack tip radii for an eightfold increase in fracture strength if two-thirds of the crack length is removed.\n\\[\n\\text {", - "answer": "the ratio of the original and etched crack tip radii is 21.3.", + "idx": 1022, + "question": "Given that for carbon diffusion in γ-Fe, D0=2.0×10^(-5)m²/s, Q=1.4×10^5J/mol, gas constant R=8.314J/(mol·K), calculate the diffusion coefficient D1027°C at 1027°C.", + "answer": "D1027°C = D0 * exp(-Q / (R * T)) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * (1027 + 273))) = 2.0×10^(-5) * exp(-1.4×10^5 / (8.314 * 1300)) = 2.0×10^(-5) * exp(-12.953) ≈ 2.0×10^(-5) * 2.394×10^(-6) ≈ 4.788×10^(-11) m²/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出扩散系数的具体数值，属于典型的计算题。 | 知识层次: 题目主要考查对扩散系数公式的直接应用和简单计算，涉及温度单位的转换和指数运算，但不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目仅涉及单一公式的直接应用和简单计算，无需多个公式组合或复杂分析。学生只需正确代入给定数值到阿伦尼乌斯方程中并进行指数运算即可得出结果。" + }, + { + "idx": 2633, + "question": "The density of Al2O3 is 3.8g/cm3, calculate how many atoms are contained in 1g?", + "answer": "The relative molecular mass of Al2O3 M=26.98×2+16×3=101.96, the number of atoms contained in 1g is 1/101.96×6.023×1023×5=2.95×1022", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算1g Al2O3中的原子数量），答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目涉及基本的分子量计算和摩尔概念的应用，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用相对分子质量和阿伏伽德罗常数的概念，但解题步骤较为直接，仅需套用基本公式并进行简单计算即可得出答案。不需要复杂的逻辑推理或多步骤转换，因此在选择题型内属于中等偏下难度。" + }, + { + "idx": 3191, + "question": "Given: the melting point of aluminum Tm=993K, the volumetric heat of fusion Lm=1.836×10^9 J/m^3, the solid-liquid interface specific surface energy σ=93 mJ/m^2, and the atomic volume V0=1.66×10^-29 m^3. Considering the solidification of liquid aluminum at 1 atm, when the undercooling ΔT=19℃, calculate the critical nucleus size r*.", + "answer": "The critical nucleus size r* = (2σ Tm) / (Lm ΔT) = (2 × 93 × 10^-3 × 993) / (1.836 × 10^9 × 19) = 9.45 × 10^-8 m = 94.5 nm", "question_type": "calculation", "question_type_name": "计算题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_3", - "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定原始和蚀刻裂纹尖端半径的比率。解答过程涉及材料科学中的断裂强度公式和几何变化计算，最终答案是一个具体的数值（21.3），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及断裂强度的概念和裂纹几何变化的综合分析。虽然公式应用是基础，但需要理解裂纹长度和尖端半径对断裂强度的影响，并进行相应的数值计算，属于中等应用层次。 | 难度: 在计算题中属于综合性计算问题，需要应用断裂力学公式，进行多步计算和概念关联。题目涉及裂纹几何变化对断裂强度的影响，要求理解表面裂纹长度和尖端半径的关系，并通过给定的强度变化比例反推原始和蚀刻后的尖端半径比值。虽然计算步骤明确，但需要综合分析多个变量和概念，属于中等偏上的难度。" + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出一个具体的数值结果（临界核尺寸r*），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及多个参数的关联和综合分析，包括临界核尺寸的计算公式应用和单位转换，需要一定的理解和应用能力。 | 难度: 在选择题中属于中等偏上难度，需要理解临界核尺寸的概念，掌握相关公式，并进行多步计算。题目涉及多个物理量的代入和单位换算，要求考生具备一定的综合分析能力和计算准确性。虽然题目提供了所有必要参数，但计算过程较为复杂，需要仔细处理指数运算和单位转换。" + }, + { + "idx": 192, + "question": "If a small bubble with a radius of $10^{-8}\\\\mathrm{m}$ is generated in water at $100^{\\\\circ}\\\\mathrm{C}$ and 101325Pa, can this small bubble exist and grow? The density of water at this time is $958\\\\mathrm{kg}/\\\\mathrm{m}^{3}$, and the surface tension is $0.0589\\\\mathrm{N/m}$.", + "answer": "According to the formula $\\\\Delta P={\\\\frac{2\\\\gamma}{\\\\Delta}}$, the additional pressure can be calculated as $\\\\triangle P{=}2\\\\times0.0589/10^{-8}{=}1.178\\\\times10^{7}\\\\mathrm{Pa}$. For a bubble in liquid, the pressure inside the bubble is $P=P_{0}{\\\\longrightarrow}\\\\triangle P{=}101325{-}1.178{\\\\times}10^{7}<0$. Therefore, this small bubble cannot exist.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要通过公式计算额外压力，并根据计算结果判断气泡是否能存在。答案展示了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式（ΔP=2γ/r）的直接应用和简单计算，不需要多步推理或综合分析。虽然需要理解气泡存在的条件，但整体思维过程较为直接，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求直接套用公式$\\\\Delta P={\\\\frac{2\\\\gamma}{\\\\Delta}}$进行计算，并理解气泡内外压力差的概念。虽然涉及基本物理概念的理解，但解题步骤相对简单，仅需一次公式应用和简单计算即可得出结论。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 276, + "question": "The reaction of forming mullite from Al2O3 and SiO powders is controlled by diffusion and conforms to the Jander equation. The experiment was conducted under constant temperature conditions. When the reaction proceeded for 1 hour, it was measured that 15% of the reactants had reacted. In how much time will all the reactants be converted into products?", + "answer": "According to the Jander equation, [1-(1-0.15)^(1/3)]^2=k×1 ⇒ k=0.00278. The time required for the reaction to complete (G=1) is t=1/k=1/(2.78×10^(-3))=359.63h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，解答过程涉及使用Jander方程进行数学推导和计算，最终得出具体的时间数值。 | 知识层次: 题目需要应用Jander方程进行多步计算，涉及反应进度与时间的关系推导，需要理解扩散控制的反应动力学模型，并进行数值计算和公式转换，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Jander方程的应用并进行多步计算。题目要求考生首先根据已知条件计算反应速率常数k，然后利用该常数计算完全反应所需时间。这涉及到对扩散控制反应动力学的理解以及代数运算能力，属于综合性计算问题。" + }, + { + "idx": 2700, + "question": "Given the vibration frequency of atoms around a vacancy in Cu as 1×10¹³ s⁻¹, ΔEv as 0.15×10⁻¹⁸ J, and exp(ΔSm/k) approximately 1, calculate the migration frequency of vacancies at room temperature 27°C (300K).", + "answer": "ν=ν₀zexp(−ΔEv/kT)exp(ΔSm/k), ν₃₀₀=1×10¹³×12×exp(−0.15×10⁻¹⁸/(1.38×10⁻²³×300))×1=2.207×10⁻² s⁻¹", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，给出了具体的物理参数和计算公式，最终需要计算出迁移频率的数值结果。答案也是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用公式进行多步计算，涉及振动频率、迁移能、熵变等多个概念的关联，并需要正确代入数值进行计算，思维过程有一定深度要求。 | 难度: 在选择题中属于中等偏上难度，需要理解振动频率、迁移能、熵变等多个概念，并正确应用Arrhenius方程进行多步骤计算。题目涉及单位换算（温度转换）、指数运算和常数代入，计算过程较为复杂，但选项提供了完整的解题路径，降低了部分难度。" + }, + { + "idx": 2739, + "question": "If an extra (111) plane is embedded, causing a small-angle grain boundary tilted by 1° in α-Fe, calculate the average distance between the dislocations.", + "answer": "The lattice constant of α-Fe crystal $$ \\\\alpha=\\\\frac{4r_{\\\\mathrm{Fe}}}{\\\\sqrt{3}}=\\\\frac{4\\\\times0.1241}{\\\\sqrt{3}}=0.2866(\\\\mathrm{nm})$$ $$x d_{111}={\\\\frac{a}{\\\\sqrt{{{1}}^{2}+{{1}}^{2}+{{1}}^{2}}}}={\\\\frac{0.2866}{\\\\sqrt{3}}}=0.16547({\\\\mathrm{nm}})$$ $$ \\\\sin{\\\\frac{\\\\theta}{2}}={\\\\frac{d_{\\\\mathrm{{111}}}}{\\\\it{l}}}$$ $$ \\\\begin{array}{r}{\\\\lambda=\\\\frac{d_{\\\\mathrm{{n1}}}}{\\\\sin\\\\frac{\\\\theta}{2}}=\\\\frac{0.16547}{\\\\sin\\\\left(\\\\frac{1}{2}\\\\right)^{\\\\circ}}=18.9615(\\\\mathrm{nm})}\\\\end{array}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解晶格常数、晶面间距以及小角度晶界的几何关系，并应用三角函数进行计算。虽然不涉及复杂的综合分析或创新应用，但需要一定的综合分析能力和对材料科学基础知识的理解。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、晶面间距计算、小角度晶界与位错的关系等多个概念，并进行多步骤的计算和综合分析。虽然题目提供了计算公式和步骤，但需要考生具备扎实的基础知识和一定的计算能力才能正确解答。" + }, + { + "idx": 2786, + "question": "A carbon steel with w(C)=0.1% is carburized at 930°C, reaching a carbon concentration of 0.45% at a depth of 0.05cm. For all times t>0, the carburizing atmosphere maintains a surface composition of 1%. Assuming D=0.2×10^(-5) exp(-140000/RT)(m²/s), calculate the carburizing time.", + "answer": "From Fick's second law, the solution is w=w_s-(w_s-w_0)erf(x/(2√(Dt))). Substituting the data gives (1%-0.45%)/(1%-0.1%)=erf(0.05/(2√(Dt))), i.e., 0.61=erf(0.05/(2√(Dt))). Looking up the table yields 0.05/(2√(Dt))=0.61, and D=0.2×exp(-140000/(8.314×1203))=1.67×10^(-7)(cm²/s). Therefore, the carburizing time t≈1.0×10^3(s).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及Fick第二定律的解析解和误差函数的使用，最终需要计算出具体的渗碳时间。答案中包含了详细的数学推导和数值代入过程，符合计算题的特征。 | 知识层次: 题目需要应用Fick第二定律进行多步计算，包括查表、数值代入和单位转换等操作，涉及扩散系数的计算和误差函数的应用，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要综合运用菲克第二定律、误差函数查表、温度换算和扩散系数计算等多个步骤。虽然题目提供了关键公式和数据，但解题过程涉及多个概念关联和计算环节，包括查表换算和单位转换，对学生的综合分析能力有一定要求。" + }, + { + "idx": 3855, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each microconstituent present at 726 degrees C.", + "answer": "primary Fe3C: 6.67% C, 6.4%; pearlite: 0.77% C, 93.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各微组成物的成分和含量，需要应用相图和相关公式进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图和相关公式进行多步计算，包括确定各相的组成和比例，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，掌握杠杆定律的应用，并进行多步计算。题目要求确定在特定温度下合金的组成和各微组成物的含量，涉及对相图中不同相区的识别和成分的准确读取，以及综合运用杠杆定律进行计算。虽然题目提供了正确选项，但解题过程需要较强的概念关联和综合分析能力。" + }, + { + "idx": 3617, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{UO}_{2}.", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用离子半径数据和配位数计算规则进行数值判断，答案是一个具体的数字（6），属于计算题的特征。 | 知识层次: 题目要求根据离子半径确定配位数，这属于基本公式应用和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅要求直接应用已知的离子半径数据来确定配位数，无需复杂计算或多步骤推理。学生只需记住或查阅相关离子半径数据，并应用基本的配位数判断规则即可得出正确答案。这种类型的题目主要考察学生对基础知识的记忆和简单应用能力，属于单一公式直接计算的范畴。" + }, + { + "idx": 2692, + "question": "Diamond is a crystalline form of carbon with a lattice constant α = 0.357 nm. When it transforms into the graphite (ρ = 2.25 g/cm³) structure, calculate the change in volume.", + "answer": "The crystal structure of diamond is a complex face-centered cubic structure, with each unit cell containing a total of 8 carbon atoms. The density of diamond is $$ ρ = (8 × 12) / ((0.357 × 10⁻⁷)³ × 6.023 × 10²³) = 3.503 (g/cm³) $$. For 1 g of carbon, when it is in the diamond structure, its volume is $$ V₁ = 1 / 3.503 = 0.285 (cm³) $$. When it is in the graphite structure, its volume is $$ V₂ = 1 / 2.25 = 0.444 (cm³) $$. Therefore, the volume expansion when transforming from diamond to graphite is = (V₂ - V₁) / V₁ = (0.444 - 0.285) / 0.285 ≈ 55.8%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解体积变化，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括晶体结构分析、密度计算、体积转换和百分比变化计算。虽然不涉及复杂的推理或综合分析，但需要理解和应用多个概念，并进行关联计算。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算和体积变化的概念，并进行多步计算和综合分析。虽然题目提供了具体数值和公式，但解题过程涉及多个步骤和概念关联，对学生的计算能力和理解深度有一定要求。" + }, + { + "idx": 4324, + "question": "Compute the mass fraction of cementite in pearlite.", + "answer": "the mass fraction of cementite in pearlite is 0.11.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算渗碳体在珠光体中的质量分数），并且答案是一个具体的数值（0.11），这表明解答过程需要应用公式和计算步骤。 | 知识层次: 题目涉及基本公式应用和简单计算，直接套用相图或杠杆定律即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需直接应用基本公式进行单一计算，无需复杂步骤或多公式组合。题目明确给出了计算目标（水泥体在珠光体中的质量分数），且正确选项直接呈现了计算结果，属于最基础的公式应用层次。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3613, + "question": "Determine the minimum radius of an atom that will just fit into the tetrahedral interstitial site in FCC nickel.", + "answer": "0.2797 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定原子的最小半径，需要应用相关公式和计算步骤，最终给出一个具体的数值答案（0.2797 Å）。 | 知识层次: 题目需要进行多步计算，涉及FCC晶体结构中四面体间隙的几何关系与原子半径的计算，需要理解晶体结构的基本原理并应用相关公式进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、间隙位置几何关系、原子半径计算等多个概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及复杂的几何关系和计算步骤，需要较强的空间想象能力和计算能力。" + }, + { + "idx": 4840, + "question": "At room temperature the electrical conductivity of P b S is 25\\left(\\Omega·m\\right)^{-1}, whereas the electron and hole mobilities are 0.06 and 0.02{m}^{2} / V·s, respectively. Compute the intrinsic carrier concentration for PbS at room temperature.", + "answer": "the intrinsic carrier concentration for pbs at room temperature is 1.95 × 10^{21}{m}^{-3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率、电子和空穴迁移率等参数，应用相关公式计算本征载流子浓度。答案是一个具体的数值结果，需要通过计算得出。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的电导率、电子和空穴迁移率来计算本征载流子浓度。虽然需要理解相关概念，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算本征载流子浓度，只需直接套用电导率与载流子浓度和迁移率的关系公式（σ = n_i * e * (μ_e + μ_h)），并进行简单的代数运算即可得出答案。无需多个公式组合或复杂的概念理解，因此属于最基础的难度等级。" + }, + { + "idx": 1734, + "question": "Given the vacancy formation energy of aluminum is 0.76 eV/vacancy, and the lattice constant of aluminum at 25°C is 0.405 nm, at what temperature will the vacancy concentration in aluminum be 1000 times that at 25°C?", + "answer": "Let the vacancy concentration at 25°C be n1=8.34×10^9 vacancies/cm3, and the vacancy concentration after 1000 times be n2=8.34×10^12 vacancies/cm3. According to the vacancy concentration formula Cv=Ae^(-Qv/RT), we have n2/n1=e^(Qv/R(1/T1-1/T2)). Substituting n2=1000n1, Qv=0.76eV=0.76×1.602×10-19J, R=8.31J/mol·K, T1=298K, we solve for T2≈434K. Therefore, the vacancy concentration in aluminum at approximately 434K is 1000 times that at 25°C.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解特定温度下的空位浓度变化，答案中包含了具体的计算步骤和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用空位浓度公式进行多步计算，涉及能量单位转换和温度关系的推导，需要综合分析能力和概念关联。虽然计算过程明确，但需要理解公式中各参数的意义及其相互关系，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解空位浓度公式并进行多步计算。题目涉及能量单位转换（eV到J）、温度转换（℃到K）、对数运算以及综合公式推导。虽然提供了关键参数，但解题过程需要较强的概念关联和综合分析能力，属于典型的综合性计算问题。" + }, + { + "idx": 1928, + "question": "Given a powder compact with an average particle size of 5μm, after sintering for 2 hours, the neck growth ratio x/r=0.1. If grain growth is not considered, how much time is required to sinter the compact to a neck growth ratio x/r=0.2 through diffusion mass transport?", + "answer": "Diffusion mass transport formula: x/r = k r^(-3/5) t^(1/5). Substituting x/r=0.1, r=5μm, t=2h to solve for k: 0.1 = k (5)^(-3/5) (2)^(1/5), yielding k. Then substituting x/r=0.2, r=5μm and k to solve for t: 0.2 = k (5)^(-3/5) t^(1/5), yielding t=64h. Diffusion mass transport requires 64h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的公式和条件求解所需时间，答案也是具体的数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解扩散质量传输公式并正确代入数值求解常数k，然后再次应用公式求解新的时间t。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散质量传输公式并进行多步计算。题目要求考生首先根据已知条件求解常数k，然后利用k值计算新的时间t。虽然计算步骤明确，但涉及指数运算和代数求解，对考生的计算能力和公式应用能力有一定要求。" + }, + { + "idx": 4292, + "question": "If the specific surface energy for soda-lime glass is 0.30 J/ m^{2}, using data contained in Table 12.5, compute the critical stress required for the propagation of a surface crack of length 0.05 mm.", + "answer": "the critical stress required for the propagation of a surface crack of length 0.05 mm is 16.2 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的数据和公式（特定表面能和裂纹长度）进行数值计算，以得出临界应力值。答案是一个具体的数值结果（16.2 MPa），这表明解答过程涉及计算步骤和公式应用。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需套用临界应力公式进行计算。 | 难度: 在选择题型中，该题目属于最低难度等级。题目仅需直接套用临界应力公式（σ_c = √(2Eγ_s/πa)），代入给定的比表面能（0.30 J/m²）和裂纹长度（0.05 mm）即可完成计算。所有参数均已明确给出，无需任何概念转换或多步骤推导，完全符合\"单一公式直接计算\"的特征。" + }, + { + "idx": 829, + "question": "Given that the recrystallization activation energy of a Cu-30%Zn alloy is 250 kJ/mol, and it takes 1 hour for this alloy to complete recrystallization at a constant temperature of 400°C, calculate how many hours it will take for this alloy to complete recrystallization at a constant temperature of 390°C.", + "answer": "According to the formula, t2/t1 = exp[-Q/R(1/T1 - 1/T2)] = exp[-250×10^3/8.314×(1/(400+273) - 1/(390+273))] = 1.962. Therefore, t2 = t1×1.962 = 1.962 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及激活能和温度对再结晶时间的影响，需要应用Arrhenius方程进行数值计算，并理解温度与时间的关系。虽然计算过程较为直接，但需要将多个概念关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及激活能、温度与时间的关系，以及阿伦尼乌斯公式的应用。解题步骤包括温度单位的转换（摄氏温度到开尔文温度）、公式的正确代入和计算，以及对数运算。虽然题目提供了正确选项，但理解和应用这些概念需要一定的综合分析能力。" + }, + { + "idx": 2626, + "question": "Given that the relative atomic mass of Si is 28.09, if there are 5×10^10 electrons capable of free movement in 100g of Si, calculate the proportion of freely moving electrons to the total number of valence electrons.", + "answer": "Number of atoms = (100 / 28.09) × 6.023 × 10^23 = 2.144 × 10^24; Number of valence electrons = 4 × number of atoms = 4 × 2.144 × 10^24 = 8.576 × 10^24; Proportion = (5 × 10^10) / (8.576 × 10^24) = 5.830 × 10^-15", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，包括计算原子数量、价电子数量以及自由电子比例。答案以数值形式呈现，展示了具体的计算步骤和结果。 | 知识层次: 题目需要进行多步计算，包括原子数量的计算、价电子总数的计算以及最终比例的计算。虽然涉及的概念（相对原子质量、价电子）是基础的，但需要将这些概念关联起来进行综合分析。思维过程要求一定的深度，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解相对原子质量、摩尔计算、价电子概念，并进行多步骤计算和综合分析。虽然题目提供了具体数值和计算步骤，但涉及的知识点较多且需要准确串联，对学生的概念掌握和计算能力要求较高。" + }, + { + "idx": 3769, + "question": "A 2 cm x 4 cm x 6 cm magnesium casting is produced. After cooling to room temperature, what is the percent shrinkage that must have occurred during solidification?", + "answer": "the percent shrinkage that must have occurred during solidification is 4.1%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算得出具体的百分比收缩率，需要应用相关公式和计算方法，答案是一个具体的数值结果。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及镁合金凝固收缩率的简单计算，不需要多步推理或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅需要应用基本的收缩率计算公式，并进行简单的数值代入和计算。不需要多个公式组合或复杂的分析步骤，属于最基础的应用题类型。" + }, + { + "idx": 2560, + "question": "If a single crystal aluminum rod with a diameter of $5mm$ starts to slip when a tensile force of 40N is applied along the rod axis [123], find the critical resolved shear stress of aluminum during slipping.", + "answer": "Single crystal aluminum has an FCC structure, and the slip system is {111}<110>. Using the imaging rule, the slip plane and slip direction are determined to be (11)[101]. The angles between them and the axis are respectively: $$ \\begin{array}{r l}&{\\mathtt{cos}\\Phi=\\left[123\\right]\\bullet[\\overline{{1}}11]/(\\left|\\left[123\\right]\\right|\\left[\\overline{{1}}11\\right]|)=4/\\surd42;}\\ &{\\mathtt{cos}\\mathtt{\\lambda}=\\left[123\\right]\\bullet[101]/(\\left|\\left[123\\right]\\right|\\left[101\\right]|)=2/\\surd7;}\\end{array} $$ Therefore, the critical resolved shear stress τc = $\\mathsf{\\bar{cos}\\lambda cos\\Phi/A_{0}=\\lambda\\cdots=0.95MPa}.$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界分切应力，解答过程中涉及角度计算、应力公式应用和具体数值代入，属于典型的计算题。 | 知识层次: 题目需要进行多步计算，包括确定滑移面和滑移方向、计算角度、应用临界分切应力公式等。同时需要理解FCC结构的滑移系统概念和成像规则，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、滑移系统、成像规则等概念，并进行多步计算（包括向量点积、角度计算、应力公式应用等）。虽然题目提供了部分计算步骤，但仍要求考生具备较强的综合分析能力和计算准确性。" + }, + { + "idx": 4760, + "question": "Compute the modulus of elasticity for 15 vol% porosity given that the modulus of elasticity for spinel (MgAl2O4) having 5 vol% porosity is 240 GPa (35 x 10^6 psi).", + "answer": "the modulus of elasticity for 15 vol% porosity is 195 gpa (28.4 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解15 vol%孔隙率下的弹性模量，答案也是一个具体的数值结果。 | 知识层次: 题目需要应用多步计算和公式推导，涉及孔隙率对弹性模量的影响分析，需要理解材料性能与孔隙率的关系并进行数值计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解孔隙率对弹性模量的影响，并应用相关公式进行多步计算。题目要求从已知5%孔隙率的数据推导15%孔隙率的结果，涉及概念关联和综合分析能力，但作为选择题，正确选项的存在降低了部分解题难度。" + }, + { + "idx": 2077, + "question": "In the Al-Mg alloy, $x_{\\\\mathrm{Mg}}=0.05$, calculate the mass fraction of Mg ($w_{\\\\mathrm{Mg}}$) in the alloy (given that the relative atomic mass of Mg is 24.31 and Al is 26.98).", + "answer": "$w_{\\\\mathrm{Mg}}=0.0453$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的相对原子质量和摩尔分数来计算镁的质量分数，答案是一个具体的数值结果。 | 知识层次: 题目考查基本的质量分数计算，仅需套用简单公式（质量分数=组分质量/总质量），涉及单一概念的直接应用和基本数值计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用单一公式（质量分数计算公式）进行简单计算，无需复杂的推理或多步骤操作。题目提供了所有必要的数据，且计算过程直接明了，属于最基础的难度等级。" + }, + { + "idx": 4583, + "question": "The following electrical characteristics have been determined for both intrinsic and p-type extrinsic indium phosphide ( \\mathrm{InP} ) at room temperature:\n\\begin{tabular}{lccc}\n\\hline & \\boldsymbol{\\sigma}\\left(\\boldsymbol{\\Omega}·\\mathbf{m}\\right)^{-1} & \\mathbf{n}\\left(\\mathbf{m}^{-3}\\right) & \\mathbf{p}\\left(\\mathbf{m}^{-3}\\right) \\\\\n\\hline Intrinsic & 2.5 × 10^{-6} & 3.0 × 10^{13} & 3.0 × 10^{12} \\\\\nExtrinsic (n-type) & 3.6 × 10^{-5} & 4.5 × 10^{14} & 2.0 × 10^{12} \\\\\n\\hline\n\\end{tabular}\nCalculate electron and hole mobilities.", + "answer": "the electron and hole mobilities for \\mathrm{inp} are \\mu_{e} = 0.50 \\, m^{2}/\\mathrm{v}\\cdots and \\mu_{h} = 0.02 \\, m^{2}/\\mathrm{v}\\cdots.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率、电子浓度和空穴浓度数据，应用相关公式计算电子和空穴的迁移率。解答过程涉及数值计算和公式应用，答案也是具体的数值结果。 | 知识层次: 题目要求使用基本的电导率公式（σ = n·e·μ）进行简单的数值计算，属于直接套用公式和基本计算的应用层次，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用电导率公式（σ = n·e·μ），但题目已经提供了所有必要的数据（σ、n、p），只需直接代入公式进行简单计算即可得到电子和空穴迁移率。不需要多个公式组合或复杂推导，属于基础知识的直接应用。" + }, + { + "idx": 140, + "question": "The viscosity of Pyrex glass is 10^9 Pa·s at 1400℃ and 10^13 Pa·s at 840℃. What is the activation energy for viscous flow?", + "answer": "According to the formula: η = η0 exp(ΔE / (R T)). At 1400℃, η = 10^9 Pa·s, T = 1400 + 273 = 1673 K, 10^9 = η0 exp(ΔE / (1673 × 8.314)). At 840℃, η = 10^13 Pa·s, T = 840 + 273 = 1113 K, 10^13 = η0 exp(ΔE / (1113 × 8.314)). Solving the two equations simultaneously yields: η0 = 11.22 Pa·s, ΔE = 254.62 kJ/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的粘度和温度数据，应用阿伦尼乌斯公式进行数值计算，求解粘性流动的活化能。答案涉及公式推导和数值计算过程，符合计算题的特征。 | 知识层次: 题目需要应用阿伦尼乌斯公式进行多步计算，涉及温度转换、对数运算和联立方程求解，属于中等应用层次。虽然不涉及复杂的机理分析，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解粘度与温度的关系公式，并进行多步计算和方程联立求解。虽然题目提供了具体数值，但解题过程涉及对数运算和单位转换，对学生的计算能力和概念理解有一定要求。" + }, + { + "idx": 4658, + "question": "Magnesium (Mg) has an HCP crystal structure and a density of 1.74 g/cm3. What is the volume of its unit cell in cubic centimeters?", + "answer": "the volume of the unit cell is 1.39 × 10^-22 cm3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解镁的HCP晶胞体积，答案是一个具体的数值结果。 | 知识层次: 题目需要应用基本公式（密度公式）进行简单计算，涉及HCP晶体结构的基本参数，但不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用密度公式和HCP晶体结构的基本参数进行计算，属于单一公式直接计算的类型。解题步骤简单，仅需套用公式并代入已知数值，无需复杂的分析或组合多个公式。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3770, + "question": "A 2 in. × 8 in. × 10 in. iron casting is produced and, after cooling to room temperature, is found to weigh 43.9 lb. Determine the percent shrinkage that must have occurred during solidification.", + "answer": "The percent shrinkage that must have occurred during solidification is 3.4%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算收缩百分比）并应用相关公式，答案是一个具体的数值结果（3.4%），符合计算题的特征。 | 知识层次: 题目涉及基本的数值计算和公式应用，需要计算铁铸件的体积和密度，然后应用简单的百分比公式来确定收缩率。虽然需要一定的理解和计算能力，但整个过程是直接的，不需要多步计算或复杂的概念关联。 | 难度: 在选择题中属于简单应用难度，需要应用基本公式（密度计算和百分比变化）并进行简单计算，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 4592, + "question": "For aluminum, the heat capacity at constant volume Cv at 30 K is 0.81 J/mol-K, and the Debye temperature is 375 K. Estimate the specific heat at 425 K.", + "answer": "the specific heat at 425 K is 923 J/kg-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及热容量的估算和单位转换，答案是一个具体的数值结果。 | 知识层次: 题目需要应用德拜模型和热容公式进行多步计算，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解德拜温度的概念，掌握热容随温度变化的规律，并进行多步计算。题目涉及从已知的低温热容数据推导高温下的热容，需要综合运用德拜模型和经典热容理论，属于综合性计算问题。" + }, + { + "idx": 4849, + "question": "A metal alloy is known to have electrical conductivity and electron mobility values of 1.2 × 10^{7}(\\Omega·m)^{-1} and 0.0050{m}^{2} / V·s, respectively. A current of 40 \\mathrm{~A} is passed through a specimen of this alloy that is 35mm thick. What magnetic field would need to be imposed to yield a Hall voltage of -3.5 × 10^{-7}V ?", + "answer": "the required magnetic field is 0.735, \\text{tesla}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的磁场强度，答案是一个具体的数值结果（0.735 tesla），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用电导率、电子迁移率、电流密度和霍尔效应等知识，通过公式推导和数值计算得出结果。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及电导率、电子迁移率、电流、厚度和霍尔电压等多个物理量的综合计算，解题步骤较为复杂，需要运用霍尔效应的相关公式进行多步推导和计算。虽然题目提供了所有必要的信息，但需要考生具备较强的综合分析能力和计算技巧。" + }, + { + "idx": 1053, + "question": "If the aforementioned alloy undergoes directional solidification in a 100cm long horizontal round mold, assuming no diffusion in the solid phase during solidification and complete mixing of the liquid composition, and the lines in the phase diagram can be simplified as straight lines, calculate the length of the ledeburite structure at the end of solidification. It is known that the length of the δ phase is 28.75cm, the length of the γ phase is 70.08cm, and the total length is 100cm.", + "answer": "The length of the ledeburite structure is: (100-28.75-70.08)cm=1.17cm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，并给出了具体的计算步骤和最终数值结果。解答过程涉及公式应用和逻辑推理，符合计算题的特征。 | 知识层次: 题目主要涉及基本的数值计算和简单的公式应用，无需多步计算或复杂的概念关联。解题过程直接套用已知数据，进行简单的减法运算即可得出结果。 | 难度: 在选择题型中，该题目仅需要简单的减法计算，直接套用已知数据即可得出答案。无需复杂的公式应用或多步骤推理，属于单一公式直接计算的难度等级。" + }, + { + "idx": 4714, + "question": "Calculate the number of atoms per cubic meter in \\mathrm{Pb}.", + "answer": "3.30 × 10^{28} atoms/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铅中每立方米的原子数），并给出了具体的数值答案，这符合计算题的特征。 | 知识层次: 题目要求计算铅的原子密度，这涉及基本的公式应用（如密度、摩尔质量和阿伏伽德罗常数的关系）和简单计算。虽然需要理解相关概念，但计算过程直接，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（如密度、摩尔质量和阿伏伽德罗常数的关系）进行简单计算，无需多个公式组合或复杂推理。属于单一公式直接计算的难度等级。" + }, + { + "idx": 142, + "question": "A borosilicate glass used for sealing lamps has an annealing point of 544°C and a softening point of 780°C. Calculate the activation energy for viscous flow of this glass.", + "answer": "According to the formula: η=η0exp(ΔE/RT). At the annealing point of 544°C, η=1.0×10^12 Pa·s, T=544+273=817K; at the softening point of 780°C, η=4.5×10^6 Pa·s, T=780+273=1053K. Solving the simultaneous equations gives: η0=1.39×10^-12 Pa·s, ΔE=373.13 kJ/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的温度和粘度数据，应用公式计算玻璃的粘流活化能，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要应用粘性流动的Arrhenius方程进行多步计算，涉及两个温度点的数据联立求解，需要理解活化能的概念和公式转换，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解粘性流动的激活能计算公式，并能够正确转换温度单位（摄氏到开尔文）。解题过程涉及解联立方程，需要一定的数学能力和对公式的理解。虽然题目提供了关键数据点，但计算步骤较多，容易在单位转换或方程求解中出现错误。" + }, + { + "idx": 1349, + "question": "A stress of 70MPa is applied in the [001] direction of an FCC crystal. Which slip system in the crystal will activate first?", + "answer": "The resolved shear stress on the (111)[10-1] slip system is 28.58MPa, while the (1-11)[110] slip system does not slip. Therefore, the (111)[10-1] slip system activates first.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要计算不同滑移系上的分切应力，通过数值比较确定哪个滑移系先启动。答案中给出了具体的计算数值和比较过程，符合计算题的特征。 | 知识层次: 题目需要应用Schmid定律计算分解剪切应力，涉及多步计算和概念关联，但不需要复杂的综合分析或推理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生计算不同滑移系的分切应力，并比较计算结果以确定哪个滑移系会首先激活。这涉及到晶体学方向、滑移系的选择、分切应力公式的应用等多个步骤的计算和概念理解。虽然题目提供了正确选项，但考生仍需具备综合分析能力才能正确解答。" + }, + { + "idx": 2084, + "question": "Calculate the relative amounts of secondary cementite, eutectic cementite, and eutectoid cementite in ledeburite", + "answer": "In ledeburite, the relative amount of Fe_3C_I is 10.15%, the relative amount of Fe_3C_3tan is 41.21%, and the relative amount of eutectoid Fe:C is 3.9%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算特定成分的相对含量，答案给出了具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要计算不同形态的渗碳体在莱氏体中的相对含量，涉及多步计算和概念关联（如区分二次渗碳体、共晶渗碳体和共析渗碳体），但不需要复杂的机理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念（如二次渗碳体、共晶渗碳体、共析渗碳体）并进行多步计算和综合分析。题目要求计算不同相的含量比例，涉及中等应用层次的知识，需要将概念关联起来并执行精确计算。" + }, + { + "idx": 2098, + "question": "Under equilibrium cooling conditions, a carbon steel obtains a microstructure containing 50% pearlite and 50% ferrite. What is the mass fraction of carbon in this alloy?", + "answer": "x=wC=0.385", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解碳的质量分数，答案是一个具体的数值结果（x=wC=0.385），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用杠杆定律（lever rule）进行多步计算，涉及相图中相组成与碳含量的关系，需要理解并关联多个概念（如珠光体、铁素体的形成条件及其碳含量），并进行综合分析得出结果。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、杠杆定律的应用，并进行多步计算。题目要求考生能够将50%珠光体和50%铁素体的微观组织比例转化为碳含量计算，这需要综合运用相图知识和计算能力，属于典型的综合性计算问题。虽然题目给出了正确选项，但解题过程涉及多个概念关联和计算步骤，在选择题型中属于较复杂的题目。" + }, + { + "idx": 4816, + "question": "Steady-state creep data taken for an iron at a stress level of 140 MPa(20,000 psi) are given here:\n\\begin{tabular}{cc}\n\\hline\\dot{\\epsilon}_{s}\\left(h^{-1}\\right) & T(K) \\\\\n\\hline 6.6 × 10^{-4} & 1090 \\\\\n8.8 × 10^{-2} & 1200 \\\\\n\\hline\n\\end{tabular}\nIf it is known that the value of the stress exponent n for this alloy is 8.5 , compute the steady-state creep rate at 1300 K and a stress level of 83 MPa(12,000 psi).", + "answer": "the steady-state creep rate at 1300k and a stress level of 83 MPa is 4.31 × 10^{-2}h^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（应力指数n）计算稳态蠕变速率，答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要应用稳态蠕变速率公式，进行多步计算，包括温度转换、应力指数应用和数值计算，涉及概念关联和综合分析，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解稳态蠕变速率与应力和温度的关系，并应用应力指数进行多步计算。题目涉及多个概念的综合运用和较为复杂的计算过程，但正确选项的提供降低了部分难度。" + }, + { + "idx": 3224, + "question": "A copper single crystal is subjected to tension with the tensile axis along the [001] direction and σ=10^6 Pa. Calculate the force acting on a screw dislocation line with Burgers vector b=(a/2)[1̄01] on the (111) plane. Given a_Cu=0.36 nm.", + "answer": "The tensile stress is applied along the [001] direction. On the (111) slip plane, the resolved shear stress along the [1̄01] direction is τ=σcosφcosλ, where cosφ=1/√3, cosλ=1/√2, and σ=10^6 Pa. Thus, τ=10^6×(1/√3)×(1/√2)≈4.08×10^5 Pa. The force per unit length on the dislocation line is F_d=τb=4.08×10^5×(√2/2)×0.36×10^(-9)≈1.04×10^(-4) N/m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及应力分解、剪切应力计算以及位错线受力计算等具体运算步骤，最终需要得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括计算分解剪切应力、应用施密特定律、计算位错受力等步骤。虽然涉及的概念和公式较为基础，但需要将这些概念和公式关联起来进行综合分析，思维过程有一定的深度要求。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如Burgers向量、滑移面、分解剪应力等）并进行多步计算（包括方向余弦计算、分解剪应力公式应用、单位转换等）。虽然题目提供了具体公式和步骤，但综合应用和计算过程仍具有一定复杂性，属于综合性计算问题。" + }, + { + "idx": 2194, + "question": "Given that the elastic modulus of sintered alumina is $370\\\\mathrm{GPa}$ when its porosity is $5\\\\%$, if the elastic modulus of another sintered alumina is $270~\\\\mathrm{GPa}$, calculate its porosity.", + "answer": "The relationship between the elastic modulus $E$ of ceramic materials and their pore volume fraction $\\\\varphi$ can be expressed as $$ E=E_{\\\\circ}(1-1.9\\\\varphi+0.9\\\\varphi^{2}) $$ where $E_{0}$ is the elastic modulus of the material without pores. Given that when $\\\\varphi=0.05$, $E=370~\\\\mathrm{GPa}$, thus $$ E_{\\\\circ}={\\\\frac{E}{1-1.9{\\\\varphi}+0.9{\\\\varphi}^{2}}}={\\\\frac{370}{1-1.9\\\\times0.05+0.9\\\\times(0.05)^{2}}}=407.8{\\\\mathrm{~GPa}} $$ When $E=270$ GPa, $$ 270=407.8(1-1.9\\\\varphi+0.9\\\\varphi^{2}) $$ which simplifies to $$ 0.9\\\\varphi^{2}-1.9\\\\varphi+0.338=0 $$ Therefore, $$ \\\\varphi=0.196=19.6\\\\% $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数值计算另一个烧结氧化铝的孔隙率，解答过程涉及数值计算和公式应用。 | 知识层次: 题目需要进行多步计算，包括公式的推导和数值求解，涉及弹性模量与孔隙率之间的非线性关系，需要一定的综合分析能力。虽然不涉及复杂的机理分析或创新设计，但超出了简单直接套用公式的范围。 | 难度: 在选择题中属于中等偏上难度，需要理解弹性模量与孔隙率的关系公式，并进行多步计算。首先需要根据已知条件求解无孔隙时的弹性模量E0，然后代入新的弹性模量值建立方程，最后解二次方程得到孔隙率。整个过程涉及公式推导、数值计算和方程求解，但题目提供了完整的解题思路，降低了部分难度。" + }, + { + "idx": 4263, + "question": "Consider a cylindrical specimen of some hypothetical metal alloy that has a diameter of 8.0 mm(0.31 in.). A tensile force of 1000N\\left(225 lb_{\\mathrm{f}}\\right) produces an elastic reduction in diameter of 2.8 × 10^{-4} mm\\left(1.10 × 10^{-5} in\\right..). Compute the modulus of elasticity for this alloy, given that Poisson's ratio is 0.30 .", + "answer": "the modulus of elasticity for this alloy is 1.705 × 10^{11} pa or 170.5 gpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解弹性模量，涉及直径变化、力和泊松比等参数的计算过程，最终需要给出具体的数值结果。答案也是一个具体的数值，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应力、应变的计算，并应用胡克定律和泊松比的概念来求解弹性模量。这需要理解相关概念并能够将它们关联起来进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要综合运用弹性模量、泊松比和应变计算等多个概念，并进行多步骤的推导和计算。虽然题目提供了所有必要的信息，但解题过程涉及多个公式的转换和单位换算，对学生的综合分析和计算能力有一定要求。" + }, + { + "idx": 4841, + "question": "An n-type semiconductor is known to have an electron concentration of 5 × 10^{17}{m}^{-3}. If the electron drift velocity is 350{m} / s in an electric field of 1000V / m, calculate the conductivity of this material.", + "answer": "the conductivity of the material is 0.028, (\\omega·m)^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解材料的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的电子浓度、电子漂移速度和电场强度来计算电导率。虽然需要理解半导体物理中的基本概念，但整体思维过程较为直接，属于基本公式的直接套用和简单计算。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解半导体电导率的基本概念，但解题步骤相对直接，仅需套用电导率公式（σ = n·e·μ，其中μ可通过漂移速度与电场关系求得）。题目提供了所有必要参数，且计算过程不涉及复杂转换或多步骤推导，属于选择题型中中等偏下的难度水平。" + }, + { + "idx": 1269, + "question": "When a spherical embryo with radius r appears in an undercooled liquid, what is the critical nucleus radius?", + "answer": "-2σ/ΔGv", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算临界核半径，需要应用公式(-2σ/ΔGv)进行数值计算，答案是一个具体的计算结果表达式 | 知识层次: 题目要求直接应用临界核半径公式（-2σ/ΔGv），属于基本公式的直接套用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（临界核半径公式）进行计算，无需额外的步骤或组合多个公式。属于最基础的难度等级，适合考察学生对基本公式的记忆和简单应用能力。" + }, + { + "idx": 4258, + "question": "A cylindrical rod of copper (E=110g P a, 16 × 10^{6} psi) having a yield strength of 240 MPa(35,000 psi) is to be subjected to a load of 6660N\\left(1500 lb p\\right). If the length of the rod is 380 mm(15.0 in.), what must be the diameter to allow an elongation of 0.50 mm(0.020 in.) ?", + "answer": "the diameter must be 7.65mm (0.30 in).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定铜棒的直径，答案是一个具体的数值结果（7.65mm），解答过程需要运用材料力学中的弹性变形公式进行计算。 | 知识层次: 题目需要进行多步计算，包括应用胡克定律计算应力、应变关系，以及几何关系计算直径，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但需要一定的思维深度和计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要综合运用弹性模量、应力应变关系和几何变形公式进行多步计算。题目涉及单位换算、公式变形和综合分析能力，但作为选择题可以通过选项验证简化部分计算步骤。" + }, + { + "idx": 3664, + "question": "Calculate the length of the Burgers vector in BCC niobium", + "answer": "b = 2.853 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算BCC铌中Burgers矢量的长度，需要通过数值计算和公式应用来得出具体数值结果（2.853 Å），属于典型的计算题类型。 | 知识层次: 题目要求计算BCC结构中Burgers矢量的长度，这需要应用基本的晶体学公式和已知的晶格常数进行简单计算。虽然需要理解Burgers矢量的概念和BCC结构的特点，但整体上是一个直接套用公式的计算过程，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算BCC结构中的Burgers矢量长度，这只需要应用BCC晶体的Burgers矢量公式b = a√3/2（其中a为晶格常数），并代入已知的晶格常数进行简单计算即可。不需要多个公式组合或复杂推导，属于最基础的计算题类型。" + }, + { + "idx": 2658, + "question": "Using the method of analytic geometry, how to determine the angle θ between two crystal planes in a cubic crystal system", + "answer": "Let there be two crystal planes (h1,k1,l1) and (h2,k2,l2) in the cubic crystal system. The angle θ between them is the angle between their respective normals [h1,k1,l1] and [h2,k2,l2]. Therefore, cosθ=(h1h2+k1k2+l1l2)/(√(h1²+k1²+l1²)·√(h2²+k2²+l2²)), and the angle θ between the two crystal planes is θ=arccos(cosθ).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用解析几何方法计算立方晶系中两个晶面之间的夹角θ，答案中给出了具体的计算公式和步骤，涉及数值计算和公式应用。 | 知识层次: 题目需要应用解析几何方法计算立方晶系中两个晶面之间的夹角，涉及多步计算（包括向量点积和模的计算）和概念关联（晶面指数与法向量的关系），但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握立方晶系中晶面夹角的计算方法，涉及向量点积和反余弦函数的应用。虽然计算步骤较多，但在选择题型中，考生只需识别正确的公式和步骤，无需实际进行复杂计算，因此难度适中。" + }, + { + "idx": 304, + "question": "During the melt cooling and crystallization process, given the solid-liquid interface energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=418 J/cm^3 at 1000°C, calculate the critical nucleus radius.", + "answer": "The critical nucleus radius r* = -2γ_sl/△Gv = -2×5×10^-6/418 = 2.39×10^-9 m = 2.39 nm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数值进行计算，最终得出一个具体的数值结果（临界核半径），属于典型的计算题类型。 | 知识层次: 题目要求直接套用临界核半径公式进行计算，属于基本公式应用和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（临界核半径公式）进行简单计算，无需理解多个概念或进行复杂分析。解题步骤非常直接，属于最基础的难度等级。" + }, + { + "idx": 4331, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). How many kilograms each of pearlite and the proeutectoid phase form?", + "answer": "the pearlite formed is 0.93 kg, and the proeutectoid phase (cementite) formed is 0.07 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算以确定珠光体和先共析相的重量，答案提供了具体的计算结果（0.93 kg和0.07 kg），这符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、杠杆定律的应用，并进行综合分析以确定珠光体和先共析相的重量分数。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、杠杆定律应用以及多步计算过程。虽然题目提供了正确选项，但解题过程涉及：" + }, + { + "idx": 2323, + "question": "If manufacturing a continuous aluminum fiber cable with epoxy resin as the matrix and a volume fraction of 0.30, predict the electrical conductivity of the cable. The electrical conductivity of aluminum is $3.8\\\\times10^{7}~\\\\mathrm{S/m}$, and the electrical conductivity of epoxy resin is $10^{-11}~\\\\mathrm{S/m}$.", + "answer": "$1.14\\\\times10^{5}~\\\\mathrm{{S/m}}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来预测电缆的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用（混合材料的电导率计算），只需要简单的数值代入和计算，无需多步推理或综合分析。 | 难度: 在选择题型内，该题目属于简单应用层次，需要基本公式应用和简单计算。题目直接给出了两种材料的电导率和体积分数，只需套用混合材料的电导率公式进行计算即可得出答案。虽然涉及公式应用，但步骤较为直接，不需要复杂的推导或多步骤计算，因此在选择题型中属于等级2难度。" + }, + { + "idx": 2047, + "question": "Given that the density of fully crystalline polyethylene (PE) is 1.01 g/cm³ and that of low-density polyethylene (LDPE) is 0.92 g/cm³, calculate the size of the 'free space' in LDPE.", + "answer": "The free space in LDPE is (1 cm³ / 0.92 g) - (1 cm³ / 1.01 g) = 0.097 cm³/g", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算LDPE中的'free space'），并给出了具体的密度数据和计算公式，最终需要得出一个具体的数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过已知密度值计算自由空间的大小。虽然需要理解密度的概念和自由空间的含义，但整体思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解密度的概念并应用公式进行计算，但解题步骤较为直接，仅涉及两个密度的简单比较和减法运算。不需要复杂的推理或多步骤的公式组合，因此难度等级为2。" + }, + { + "idx": 4522, + "question": "Estimate the maximum thermal conductivity value for a cermet that contains 85 vol % titanium carbide (TiC) particles in a cobalt matrix. Assume thermal conductivities of 27 and 69 W/m-K for TiC and Co, respectively.", + "answer": "the maximum thermal conductivity k_max is 33.3 W/m-K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来估计最大热导率值，答案是一个具体的数值结果，解答过程需要运用材料科学中的热导率计算原理。 | 知识层次: 题目需要进行多步计算，涉及复合材料热导率的估算，需要理解并应用复合材料热导率的最大值计算公式，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解复合材料热导率的混合规则（如串联模型），并正确应用体积分数进行计算。题目涉及两个材料参数的整合和多步骤计算，但选项已经给出了具体数值，减少了部分推导难度。" + }, + { + "idx": 2465, + "question": "For heterogeneous nucleation at grain boundaries (double spherical cap shape, with all interfaces being incoherent), what is the critical nucleus formation energy ΔGb*? Given the contact angle θ=50°, nucleation driving force ΔG1=5×10^8 J/m^3, and incoherent interface energy γin=0.5 J/m^2.", + "answer": "The calculation process for the critical nucleus formation energy ΔGb* is as follows: First, calculate the shape factor f(θ) = 0.5×(2-3cos50°+cos^3 50°) = 0.3125. The critical nucleus radius for homogeneous nucleation (spherical shape) rin* = 2γin/ΔG1 = 2×0.5/(5×10^8) m = 2×10^-9 m. The critical nucleus formation energy for homogeneous nucleation ΔGin* = (16π/3)(γin^3)/(ΔG1^2) = (16π/3)(0.5^3)/(5×10^8)^2 J = 8.37×10^-18 J. The critical nucleus formation energy for heterogeneous nucleation ΔGb* = f(θ)ΔGin* = 8.37×10^-18×0.3125 J = 2.615×10^-18 J.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解临界核形成能量ΔGb*，答案中包含了具体的计算步骤和数值结果。 | 知识层次: 题目涉及多步计算和概念关联，需要理解异质成核的形状因子、临界核形成能的计算方法，并综合应用相关公式进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如异质形核、临界核形成能、接触角等）并进行多步骤计算（包括形状因子计算、临界核半径计算、均质形核能计算等）。虽然题目提供了具体数值和公式，但解题过程涉及多个变量和步骤的综合运用，对学生的计算能力和概念关联能力要求较高。" + }, + { + "idx": 2709, + "question": "Given that Al has an fcc crystal structure with a lattice constant α=0.405 nm, and the vacancy concentration at 550°C is 2×10-6, calculate the average spacing between these vacancies if they are uniformly distributed in the crystal.", + "answer": "The number of lattice points in $1~\\\\mu\\\\mathrm m^{3}$ volume of Al is $$ N={\\\\frac{1}{a^{3}}}\\\\times4\\\\Rightarrow{\\\\frac{1}{(0.405\\\\times10^{-6})^{3}}}=6.021\\\\times10^{10}$$ Therefore, the number of vacancies in $1~\\\\mu\\\\mathrm m^{3}$ volume is $$ n_{V}=\\\\mathrm{CN}=6.021\\\\times10^{10}\\\\times2\\\\times10^{-6}=1.204\\\\times10^{5}$$ Assuming the vacancies are uniformly distributed in the crystal, the average spacing between them is $$ L=\\\\sqrt[3]{\\\\frac{1}{n_{v}}}=\\\\sqrt[3]{\\\\frac{1}{1.204\\\\times10^{5}}}=0.02025(\\\\mu\\\\mathrm{m})=20.25\\\\mathrm{nm}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解空缺的平均间距，答案中包含了具体的计算步骤和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要计算晶格点的数量、空位浓度，并进一步推导空位之间的平均间距。虽然不涉及复杂的机理分析或创新应用，但需要综合运用晶体结构和缺陷的知识进行中等难度的计算。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、空位浓度、均匀分布等概念，并进行多步计算（包括晶格点计算、空位数量计算和平均间距计算）。虽然题目提供了正确选项，但解题过程涉及多个物理概念的关联和综合应用，对学生的计算能力和概念理解要求较高。" + }, + { + "idx": 298, + "question": "The atomic weight of iron is 55.84, its density is 7.3g/cm³, its melting point is 1593°C, its heat of fusion is 11495J/mol, and the solid-liquid interface energy is 2.04×10⁻⁵J/cm². Calculate the critical nucleus size at an undercooling of 10°C.", + "answer": "ΔGᵥ = - (7.3×10³)/(55.84×10⁻³) × (11495×283)/1876 = -2.267×10⁸ J/m³\\nr* = - (2×2.04×10⁻⁵)/(-2.267×10⁸) = 1.8×10⁻⁷ m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用热力学和材料科学知识进行计算，包括临界核尺寸的计算公式应用和单位转换等，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步计算和多个概念的关联应用，包括原子重量、密度、熔点、熔化热、界面能等参数的转换和综合运用。虽然题目提供了正确选项，但解题过程需要理解并正确应用热力学公式和临界核尺寸的计算方法，属于综合性计算问题。" + }, + { + "idx": 2198, + "question": "The strength of OFHC copper (oxygen-free high-conductivity copper) can be increased by more than 2 times after cold drawing deformation. If the safety factor for allowable stress is taken as 2, calculate the service life of an OFHC copper component working at $130^{\\\\circ}\\\\mathrm{C}$. (Given: $A=10^{12}1/\\\\operatorname*{min}, \\\\frac{Q}{R}=$ $1.5\\\\times10^{4}~\\\\mathrm{K}, t_{0.5}$ is the time required for 50% recrystallization)", + "answer": "Since OFHC copper operates at $130^{\\\\circ}C$, with a strength design safety factor of 2, for cold-worked and strengthened materials, only 50% recrystallization is allowed, i.e., $$ \\\\begin{array}{r}{\\\\frac{1}{t_{0.5}}=A\\\\mathrm{exp}\\\\left(-\\\\frac{Q}{R T}\\\\right)} \\\\ {\\\\mathrm{lg}(A t_{0.5})=\\\\frac{Q}{R T}\\\\mathrm{lg}\\\\mathrm{~e~}}\\\\end{array}$$ $A=10^{12}~1/\\\\operatorname*{min}{},\\\\frac{Q}{R}=1.5\\\\times10^{4}~\\\\mathrm{K}{},T=130^{\\\\circ}\\\\mathrm{C}=403~\\\\mathrm{K}$. Therefore, $$ t_{0.5}=14497\\\\mathrm{min}=242\\\\mathrm{h}$$ Thus, the service life of OFHC copper under these working conditions is $242\\\\mathrm{~h~}$ \\\\lg(10^{12}t_{0.5})={\\\\frac{1.5\\\\times10^{4}}{403}}\\\\times0.4342$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及到了具体的数学运算和物理公式的使用，最终得出一个具体的数值结果（242小时）。 | 知识层次: 题目需要进行多步计算，包括温度单位转换、公式应用（Arrhenius方程）、对数运算和单位转换，涉及材料科学中的再结晶动力学概念。虽然计算过程较为直接，但需要理解和应用多个知识点，并进行综合分析以得出最终的服务寿命。 | 难度: 在选择题中属于中等偏上难度，需要理解材料科学中的再结晶动力学概念，掌握Arrhenius方程的应用，并进行多步骤计算。题目涉及温度转换、对数运算和单位换算，综合性强，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 4837, + "question": "(b) Under these circumstances, how long does it take an electron to traverse a 25-mm length of crystal?", + "answer": "under these circumstances, it takes an electron 3.45 x 10^-4 s to traverse a 25-mm length of crystal.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算电子通过25毫米晶体所需的时间，答案给出了具体的数值计算结果（3.45 x 10^-4 s），这表明解答过程需要应用相关的物理公式和数值计算。 | 知识层次: 题目要求进行基本的数值计算和公式应用，属于直接套用公式的简单计算过程，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式进行简单计算，属于单一公式直接计算的难度等级。题目明确给出了所需的条件和公式应用场景，解题步骤简单直接，无需复杂的推理或多步骤计算。" + }, + { + "idx": 2380, + "question": "According to the $FE=Fe=C$ phase diagram, calculate the relative amounts of the primary phase (austenite) and eutectic in an iron-carbon alloy with a carbon mass fraction of $3.6$ just after solidification is completed.", + "answer": "Just after solidification is completed, the carbon compositions of the primary phase and eutectic structure are $2.14$ and $4.3$ respectively. Therefore, the relative amounts of the primary phase and eutectic just after solidification are: $$ A^{\\\\gamma}=\\\\frac{4.3-3.6}{4.3-2.14}=32.4\\\\% \\\\qquad A^{0}=1-32.4\\\\%=67.6\\\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据相图进行数值计算，应用杠杆定律来求解各相的相对含量，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解相图、应用杠杆定律计算相对量，并涉及概念关联（如初生相和共晶组织的组成）。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来正确应用相图知识进行计算。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，掌握杠杆定律的应用，并进行多步计算。虽然题目提供了关键数值，但考生仍需正确识别相图中的关键点（如共晶点和初生相成分），并准确应用公式计算相对含量。这比单纯记忆或简单计算更复杂，但相比涉及多变量或更复杂相变的题目，其难度适中。" + }, + { + "idx": 2881, + "question": "In practice, it is often considered that the grain size of steel will significantly grow when heated to 870°C. If the original grain diameter of the steel is 0.05 mm, the empirical formula for grain growth is D^(1/n)−D0^(1/n)=c t, where D is the grown grain diameter; D0 is the original grain diameter; c is the proportional constant; t is the holding time. Given that at 870°C, n=0.2, c=2×10^(−8), find the grain diameter of steel with 0.8% carbon content after holding at 870°C for 1 hour.", + "answer": "At 870°C: D^5=(0.05)^5+2×10^(−8)×60=1.513×10^(−6) D=0.0686(mm). Compared to the original grain diameter, it has significantly grown (approximately 37%).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和参数进行数值计算，最终得出具体的数值结果（0.0686 mm），属于典型的计算题。 | 知识层次: 题目需要进行多步计算，包括代入公式、单位转换和数值求解，同时需要理解晶粒生长的经验公式及其参数的含义。虽然不涉及复杂的综合分析或机理解释，但比简单的直接套用公式更具挑战性。 | 难度: 在选择题中属于中等偏上难度，需要理解并应用晶粒生长经验公式，进行多步骤计算（包括指数运算和单位转换），同时需要综合分析计算结果与原始数据的对比关系。题目涉及材料科学中的具体应用场景，要求考生具备将理论公式与实际问题相结合的能力。" + }, + { + "idx": 3673, + "question": "The strength of titanium is found to be 65,000 psi when the grain size is 17 x 10^-6 m and 82,000 psi when the grain size is 0.8 x 10^-6 m. Determine the constants in the Hall-Petch equation.", + "answer": "the constants in the hall-petch equation are k = 19.4 psi/sqrt(d) and σ_o = 60,290 psi.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和Hall-Petch方程进行计算，以确定方程中的常数k和σ_o。解答过程涉及数值计算和公式应用，最终需要得出具体的数值结果。 | 知识层次: 题目需要应用Hall-Petch方程进行多步计算，涉及两个不同条件下的强度数据求解方程中的常数，需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch方程的概念，并能够根据给定的数据建立方程组求解常数。解题步骤涉及多步计算和综合分析，但选择题型提供了正确选项，降低了部分难度。" + }, + { + "idx": 2689, + "question": "Given that the number-average relative molecular weight of linear polytetrafluoroethylene is 5×10^5, its C-C bond length is 0.154 nm, and the bond angle θ is 109°, calculate its root-mean-square length.", + "answer": "The root-mean-square length r=d√N=0.154×√(1.0×10^4)=15.4 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数（分子量、键长、键角）应用公式计算均方根长度，答案呈现为具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解根均方长度的概念、应用相关公式（r=d√N）以及进行数值计算。虽然不涉及复杂的综合分析或推理，但需要将多个概念（如键长、键角和分子量）关联起来进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解高分子链的均方根末端距计算公式（r=d√N），并正确关联题目给出的参数（键长d=0.154 nm、聚合度N=5×10^5/100=5×10^3）。虽然计算步骤明确（先求聚合度再开方计算），但需要综合应用高分子物理知识和三角函数计算（109°键角隐含的投影关系），且涉及数量级转换（将5×10^5分子量转换为聚合度）。相比简单概念选择题（等级1）或单步计算题（等级2），该题需要更系统的知识整合能力。" + }, + { + "idx": 2710, + "question": "Given that W at 20℃ has one vacancy per 10^23 unit cells, and each unit cell contains 2 W atoms, calculate the vacancy concentration C at 20℃.", + "answer": "C_20 = 1 / (2 × 10^23) = 5 × 10^-24.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体的数学运算和单位转换，最终给出一个数值结果。 | 知识层次: 题目仅涉及基本公式应用和简单计算，直接套用给定的数值进行计算即可，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用一个基本公式（空缺浓度计算）并进行简单的数值计算。解题步骤非常直接，没有涉及多个公式的组合或复杂的概念分析，因此属于单一公式直接计算的难度等级1。" + }, + { + "idx": 2812, + "question": "Given the diffusion coefficient of Al in Al2O3, D0(Al) = 2.8×10^-3 m^2/s, and the activation energy Q = 477 kJ/mol, calculate its diffusion coefficient D at a temperature of 2000 K.", + "answer": "D = D0 * exp(-Q / (R * T)) = 2.8×10^-3 * exp(-477000 / (8.314 * 2000)) = 9.7×10^-16 m^2/s", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式（D = D0 * exp(-Q / (R * T))）来求解扩散系数D，答案是一个具体的计算结果（9.7×10^-16 m^2/s）。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及扩散系数的计算，需要直接套用给定的公式和参数进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的扩散系数公式进行计算，无需额外的概念理解或复杂的解题步骤。题目提供了所有必要的参数（D0, Q, R, T），只需将这些数值代入公式即可得出答案。因此，该题目属于单一公式直接计算的难度等级。" + }, + { + "idx": 252, + "question": "Calculate the diffusion activation energy Q and D0 value of Al3+ in Al2O3", + "answer": "According to D=D0exp(-Q/RT), the ratio of diffusion coefficients of Al2O3 at 1393℃ and 1716℃ can be used to calculate Q and D0. The specific calculation process is: D3/D4 = exp[-Q/R(1/T3 - 1/T4)], where T3=1666K(1393℃), T4=1989K(1716℃). Solving this equation yields the Q value, and substituting it into the diffusion coefficient at any temperature gives D0.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解扩散激活能Q和D0值，答案中给出了具体的计算步骤和公式应用过程，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解扩散激活能的概念，并能够将不同温度下的扩散系数关联起来进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散激活能的概念，掌握阿伦尼乌斯方程的应用，并能进行多步计算和温度单位的转换。虽然题目提供了具体的计算步骤，但需要综合运用多个知识点，包括对数运算和代数求解，属于综合性计算问题。" + }, + { + "idx": 4448, + "question": "The modulus of elasticity for beryllium oxide (BeO) having 5 vol% porosity is 310 GPa (45 x 10^6 psi). Compute the modulus of elasticity for the nonporous material.", + "answer": "the modulus of elasticity for the nonporous material is 342 gpa (49.6 x 10^6 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（计算非多孔材料的弹性模量）来得出具体数值答案，答案也是以具体数值形式呈现。 | 知识层次: 题目需要应用基本公式（弹性模量与孔隙率的关系）进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算非多孔材料的弹性模量，只需直接应用孔隙率与弹性模量的关系公式（如E = E0(1 - 1.9P + 0.9P^2)），并进行简单的数值代入和计算。无需复杂的推理或多步骤分析，属于最基础的难度等级。" + }, + { + "idx": 3799, + "question": "A NiO-60 mol% MgO ceramic is allowed to solidify. Determine the composition of the first solid to form under equilibrium conditions.", + "answer": "80% mgo", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定在平衡条件下形成的第一个固体的成分，需要应用相图和相关公式进行数值计算。答案是一个具体的数值（80% mgo），表明需要通过计算得出结果。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及固溶体成分的确定和平衡条件的理解，需要综合分析相图信息并进行数值计算。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算分析。题目要求考生在NiO-MgO二元相图中确定平衡凝固时首晶固相的成分，这需要综合运用杠杆定律和相图解读能力。虽然给出了正确选项减少了部分计算量，但仍需完成相图定位、相区判断和成分计算等步骤，属于典型的综合性计算问题。" + }, + { + "idx": 4235, + "question": "Calculate the number of atoms per cubic meter in aluminum.", + "answer": "6.05 × 10^{28} atoms/m^3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算铝中每立方米的原子数），并给出了具体的计算公式和步骤，最终答案是一个具体的数值结果。 | 知识层次: 题目要求计算铝中每立方米的原子数，这需要应用基本的密度和摩尔质量公式进行计算，属于直接套用公式的简单应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用基本公式（如密度和摩尔质量的关系）进行简单计算，无需多个步骤或公式组合。属于单一公式直接计算的难度等级。" + }, + { + "idx": 4820, + "question": "The fraction recrystallized-time data for the recrystallization at 350^{\\circ} C of a previously deformed aluminum are tabulated here. Assuming that the kinetics of this process obey the Avrami relationship, determine the fraction recrystallized after a total time of 116.8min.\n\\begin{tabular}{cc}\n\\hline Fraction Recrystallized & Time (min) \\\\\n\\hline 0.30 & 95.2 \\\\\n0.80 & 126.6 \\\\\n\\hline\n\\end{tabular}", + "answer": "the fraction recrystallized after a total time of 116.8min is 0.65.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和Avrami关系进行数值计算，以确定在特定时间下的再结晶分数。答案是一个具体的数值结果（0.65），需要通过公式应用和计算得出。 | 知识层次: 题目需要应用Avrami关系进行多步计算，涉及公式变换和数值求解，要求对动力学过程有较好的理解，并能够将实验数据与理论模型关联起来。 | 难度: 在选择题中属于中等难度，需要理解Avrami动力学关系并进行多步计算。题目要求根据给定的数据点拟合Avrami方程，然后外推计算特定时间点的再结晶分数。这涉及对数变换、线性回归和指数计算等步骤，属于综合性计算问题。虽然题目提供了部分数据点，但解题过程仍需要较强的数学和材料科学知识综合应用能力。" + }, + { + "idx": 4248, + "question": "The preexponential and activation energy for the diffusion of iron in cobalt are 1.1 × 10^{-5}{m}^{2} / s and 253,300 J/ mol, respectively. At what temperature will the diffusion coefficient have a value of 2.1 × 10^{-14}{m}^{2} / s ?", + "answer": "the temperature at which the diffusion coefficient has a value of 2.1 × 10^{-14} m^{2}/s is 1518 k (1245^{\\circ} C). alternatively, using the vmse software, the temperature is found to be 1519 k.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的扩散系数公式（Arrhenius方程）进行数值计算，求解特定扩散系数对应的温度。答案提供了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式进行多步计算，涉及对数运算和温度单位的转换，需要理解公式中各参数的含义及其相互关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要应用阿伦尼乌斯公式进行多步骤计算，涉及对数运算和温度单位的转换。虽然题目提供了所有必要参数，但解题过程需要准确执行数学运算和概念关联，属于综合性计算问题。" + }, + { + "idx": 2699, + "question": "There is a glass containing soda, with a mass fraction of SiO2 at 80% and Na2O at 20%. Calculate the fraction of non-bridging O atoms.", + "answer": "According to the problem, assume there is 100g of glass, containing 80g of SiO2 and 20g of Na2O. First, calculate their molar fractions: The amount of SiO2 is 80/(28.09+2×16.00)=1.331(mol) ⇒ x_SiO2=80.47%. The amount of Na2O is 20/(2×22.99+16.00)=0.323(mol) ⇒ x_Na2O=19.53%. Now, using 100mol as the basis, then: 80.47SiO2 = 80.47Si + 160.94O 19.53Na2O = 39.06Na + 19.53O Since each Na+ produces one non-bridging oxygen ion, there are 39.06 non-bridging oxygen atoms, while the bridging oxygen atoms are: (160.94 + 19.53) - 39.06 = 141.41 The fraction of non-bridging oxygen atoms is then: 39.06/180.47 = 0.216", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非桥氧原子的比例，解答过程中涉及摩尔分数计算和化学计量关系，最终得出具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括摩尔分数的计算、非桥氧和桥氧原子的数量计算，以及最终的比例计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用化学计量和玻璃结构的基本知识，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解玻璃结构中的非桥氧和桥氧概念，并进行多步计算。题目涉及摩尔分数计算、原子平衡以及非桥氧比例的推导，步骤较为复杂，但选项提供了明确的解题路径，降低了部分难度。" + }, + { + "idx": 3767, + "question": "A 4-in. cube of a liquid metal is allowed to solidify. A spherical shrinkage cavity with a diameter of 1.49 in. is observed in the solid casting. Determine the percent volume change that occurs during solidification.", + "answer": "the percent volume change that occurs during solidification is 2.7%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定凝固过程中的体积变化百分比，答案是一个具体的数值结果（2.7%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括计算立方体和球体的体积，并应用体积变化的百分比公式。虽然不涉及复杂的综合分析或推理，但需要理解体积变化的概念并进行关联计算。 | 难度: 在选择题中属于中等难度，需要理解体积变化的概念，进行多步计算（包括立方体和球体的体积计算、百分比变化计算），并综合分析结果。虽然题目提供了正确选项，但解题过程涉及多个步骤和概念关联，对学生的应用能力有一定要求。" + }, + { + "idx": 2668, + "question": "In indium with a tetragonal structure, the relative atomic mass A_r=114.82, atomic radius r=0.1625 nm, lattice constants a=0.3252 nm, c=0.4946 nm, and density ρ=7.286 g/cm³. How many atoms are there in the unit cell of In?", + "answer": "n=(ρa²c×N_A)/A_r=(7.286×(3.252×10^-8)^2×(4.946×10^-8)×6.023×10^23)/114.82=1.9991≈2. Therefore, there are 2 atoms in the unit cell of In.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞中的原子数量，答案涉及具体的数学运算和单位转换。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的密度、晶格常数和相对原子质量等参数，直接套用公式计算单位晶胞中的原子数。虽然需要理解相关概念和公式，但思维过程较为直接，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及密度、晶格常数和原子质量等多个参数，但解题步骤明确且直接，只需套用单一公式（单位晶胞原子数计算公式）并进行简单代数运算即可得出答案。不需要复杂的逻辑推理或多步骤推导，符合选择题型中等级2的难度标准。" + }, + { + "idx": 2825, + "question": "An aluminum rod with a length of 20m and a diameter of 14mm is drawn through a die with an aperture of 12.7mm. Calculate the length of the aluminum rod after drawing.", + "answer": "During the deformation process, the total volume remains unchanged. Let the length after drawing be L, then π(14.0/2)^2×20×10^3 = π(12.7/2)^2×L×10^3, L=24.3m", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铝棒在拉伸后的长度，答案也是通过具体的计算步骤得出的数值结果。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及体积不变原理的直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用体积不变原理这一基本公式进行计算，解题步骤简单，无需组合多个公式或进行复杂分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4850, + "question": "At temperatures between 540^{\\circ} C(813 K) and 727^{\\circ} C(1000 K), the activation energy and preexponential for the diffusion coefficient of \\mathrm{Na}^{+}in \\mathrm{NaCl} are 173,000 J/ mol and 4.0 × 10^{-4} m^{2} / s, respectively. Compute the mobility for an \\mathrm{Na}^{+}ion at 600^{\\circ} C(873 K).", + "answer": "the mobility for a \\mathrm{na}^{+} ion at 600^{\\circ} C (873 k) is 2.34 × 10^{-13} m^{2}/\\mathrm{v}-s.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的激活能和前置指数计算钠离子在特定温度下的迁移率，需要使用公式进行数值计算，答案也是一个具体的数值结果。 | 知识层次: 题目需要应用扩散系数的阿伦尼乌斯公式计算离子迁移率，涉及多步计算和概念关联，但不需要复杂的综合分析或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散系数与迁移率的关系，并应用阿伦尼乌斯公式进行多步计算。题目涉及温度转换、单位统一和公式推导，虽然选项已给出正确答案，但仍需较强的综合分析能力来验证。" + }, + { + "idx": 2285, + "question": "Calculate the critical volume fraction φtr of Al2O3 short fiber reinforced composite, given the matrix tensile strength σm=186MPa, yield strength σy=76MPa, and fiber stress σf=2190MPa.", + "answer": "For Al2O3 short fibers, the critical volume fraction φtr = (σm - σy) / (σf - σy) = (186 - 76) / (2190 - 76) = 0.052.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果 | 知识层次: 题目涉及基本公式的直接应用和简单计算，无需多步推理或综合分析，仅需理解公式中各参数的含义并进行数值代入即可求解。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了所有必要的参数，并且只需要套用一个简单的公式（φtr = (σm - σy) / (σf - σy)）即可得出答案。计算过程简单，无需复杂的推理或多步骤的推导，因此属于最低难度等级。" + }, + { + "idx": 3858, + "question": "A steel contains 18 % cementite and 82 % ferrite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 1.20 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算来估计钢中的碳含量，需要应用相关的材料科学公式和数值计算。答案是一个具体的数值结果（1.20 % c），这表明解答过程涉及计算而非选择或判断。 | 知识层次: 题目需要应用铁碳相图的知识，通过已知的相组成比例（18% cementite和82% ferrite）来计算碳含量。这涉及到多步计算和概念关联，需要理解相图的基本原理和相组成的计算方法，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图中渗碳体和铁素体的组成比例关系，并进行多步计算来推导碳含量。虽然题目提供了具体比例，但需要考生掌握相图知识并正确应用杠杆定律进行计算，属于综合性计算问题。" + }, + { + "idx": 4584, + "question": "Some metal alloy is known to have electrical conductivity and electron mobility values of 1.5 × 10^{7} (\\Omega·m)^{-1} and 0.0020{m}^{2} / V·s, respectively. Through a specimen of this alloy that is 35mm thick is passed a current of 45 A. What magnetic field would need to be imposed to yield a Hall voltage of -1.0 × 10^{-7}V ?", + "answer": "the required magnetic field is 0.58 \\mathrm{tesla}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来求解所需的磁场强度，答案是一个具体的数值结果（0.58 tesla），符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合运用电导率、电子迁移率、电流密度和霍尔效应等知识，通过公式推导和数值计算得出结果，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用电导率、电子迁移率、霍尔效应等多个物理概念，并进行多步骤计算。虽然题目提供了正确选项，但解题过程涉及多个公式转换和单位换算（如厚度单位转换），需要较强的综合分析能力。相比单纯的概念选择题，这类计算型选择题对知识掌握深度和计算准确性要求更高。" + }, + { + "idx": 3942, + "question": "A photomicrograph was taken of a specimen at a magnification of 100 ×, and it was determined that the average number of grains per square inch was 200 . What is this specimen's ASTM grain size number?", + "answer": "the specimen's astm grain size number is 4.9.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ASTM晶粒度数值，答案是一个具体的数值结果（4.9），这表明解答过程涉及计算步骤。 | 知识层次: 题目涉及基本的ASTM晶粒度计算公式应用，仅需一步计算即可得出结果，属于直接套用公式的简单应用层次。 | 难度: 在选择题中属于简单难度，需要应用基本公式进行计算，但仅涉及单一公式的直接套用和简单计算步骤。" + }, + { + "idx": 2746, + "question": "Determine the solidification velocity $R$ required to maintain a planar liquid-solid interface during directional solidification of an 8% B binary alloy. Given the temperature gradient $G=225^{\\\\circ}C$/cm, the diffusion coefficient of component B $D=2\\\\times10^{-4}$ cm²/s, the equilibrium partition coefficient $\\\\pmb{k}_{0}=0.3$, and the slope of the binary alloy liquidus line $m=0.142^{\\\\circ}C$/%, which means the temperature decreases by $0.142^{\\\\circ}C$ for every 1% increase in B solute concentration.", + "answer": "nan", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的参数和公式计算固相速度R，需要应用材料科学中的相关理论和数值计算方法，属于典型的计算题。 | 知识层次: 题目需要应用多个给定的参数（温度梯度、扩散系数、分配系数、液相线斜率）进行多步计算，涉及公式应用和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如温度梯度、扩散系数、平衡分配系数、液相线斜率等）并进行多步计算和综合分析。题目要求计算维持平面液-固界面所需的凝固速度，涉及多个变量的关联和计算步骤，但不需要处理过于复杂的多变量交互作用。" + }, + { + "idx": 3748, + "question": "Suppose that solid nickel was able to nucleate homogeneously with an undercooling of only 22^{\\circ} C. How many atoms would have to group together spontaneously for this to occur? Assume that the lattice parameter of the solid FCC nickel is 0.356nm.", + "answer": "1.136 × 10^{6}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，要求计算自发聚集的原子数量，答案是一个具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括使用均质形核理论中的临界形核功公式，并结合FCC晶体的晶格参数计算单个原子的体积，进而求出临界形核尺寸所需的原子数。这涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算。题目涉及均相成核、晶格参数、原子数量计算等概念，需要综合运用材料科学知识。虽然题目给出了晶格参数，但需要学生自行推导计算步骤，包括体积计算、原子密度计算以及临界核尺寸的关联计算。这种多步骤的综合性计算在选择题中属于较高要求，但尚未达到复杂多变量计算的最高难度。" + }, + { + "idx": 4553, + "question": "A thick steel sheet of area 400 cm^{2} is exposed to air near the ocean. After a one-year period it was found to experience a weight loss of 375g due to corrosion. To what rate of corrosion, in both mpy and mm / \\mathrm{yr}, does this correspond?", + "answer": "the corrosion rate is 1.2mm / \\mathrm{yr}. the corrosion rate is 46.7 \\mathrm{mpy}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解腐蚀速率，答案也是具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括单位转换和公式应用（如腐蚀速率的计算），并需要理解腐蚀速率的不同单位（mpy和mm/yr）之间的转换关系。虽然不涉及复杂的综合分析或推理，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解腐蚀速率的概念，并进行多步单位换算和计算。题目涉及面积、重量损失和时间的关系，需要将克转换为毫米/年和mpy（密耳每年），这要求考生掌握相关公式和单位转换技巧。虽然题目提供了所有必要信息，但计算过程较为复杂，需要综合应用多个知识点。" + }, + { + "idx": 4838, + "question": "At room temperature the electrical conductivity and the electron mobility for aluminum are 3.8 x 10^7 (Ω·m)^-1 and 0.0012 m^2/V·s, respectively. Compute the number of free electrons per cubic meter for aluminum at room temperature.", + "answer": "the number of free electrons per cubic meter for aluminum at room temperature is 1.98 x 10^29 m^-3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的电导率和电子迁移率数据，应用相关公式计算铝在室温下的自由电子密度。解答过程涉及数值计算和公式应用，答案是一个具体的数值结果。 | 知识层次: 题目要求应用基本的电导率和电子迁移率公式进行简单计算，属于直接套用公式的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算铝在室温下的自由电子数密度，只需直接套用电导率与电子迁移率的关系公式（σ = n e μ），并进行简单的代数运算即可得到答案。无需复杂的推导或多步骤计算，属于最基础的应用题。" + }, + { + "idx": 1981, + "question": "The density of quartz (SiO2) is 2.65 Mg/m3. How many silicon atoms (and oxygen atoms) are there in 1 m3?", + "answer": "5.29×10^28 silicon atoms /m3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算硅和氧原子的数量），并给出了具体的答案（5.29×10^28 silicon atoms /m3），这需要应用密度和摩尔质量等公式进行计算。 | 知识层次: 题目需要进行基本的密度和摩尔质量计算，涉及简单的公式应用和单位转换，属于直接套用基本概念和公式的范畴。虽然需要计算硅和氧原子的数量，但整个过程是线性的，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要知道石英的分子式和密度，以及阿伏伽德罗常数的概念，但解题步骤相对直接：先计算石英的摩尔质量，然后利用密度和摩尔质量求出摩尔数，最后乘以阿伏伽德罗常数得到硅原子数量。这些步骤都是基础公式的简单应用，不需要复杂的推导或多步骤组合计算，因此在选择题型内属于等级2难度。" + }, + { + "idx": 1949, + "question": "It is known that for a certain crystal at 500°C, 1 vacancy can form for every 10^10 atoms. What is the vacancy formation energy of this crystal? (Given: the constant A=0.0539 for this crystal, Boltzmann constant k=1.381×10^-23 J/K)", + "answer": "$$ x\\\\begin{array}{c}{{c=A\\\\exp\\\\enspace\\\\big(\\\\enspace-\\\\frac{\\\\Delta E_{V}}{k T}\\\\big)}}\\\\ {{\\\\Delta E_{V}=-k T\\\\mathrm{ln}\\\\frac{c}{A}=\\\\mathrm{-\\\\enspace\\\\left[1.381\\\\times10^{-23}\\\\times\\\\enspace\\\\left(500+273\\\\right)\\\\right]\\\\enspace\\\\mathrm{ln}\\\\frac{10^{-10}}{0.0539}\\\\mathrm{\\\\scriptsize\\\\mathrm{~J}}}}}\\\\\\\\ {{=1.068\\\\times10^{-20}\\\\times17.8=1.9\\\\times10^{-19}\\\\mathrm{\\\\scriptsize{\\\\times10^{-19}}}}}\\\\\\\\ \\n $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出空缺形成能的具体数值。答案展示了详细的推导过程和计算结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解空位形成能的概念，并能够正确应用玻尔兹曼方程进行计算。虽然计算过程较为直接，但需要将多个概念（如浓度、温度、能量）关联起来，并进行对数运算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解空位形成能的概念，掌握相关公式，并进行多步计算。题目涉及对数运算、单位转换和常数代入，要求考生具备较强的综合计算能力和概念关联能力。虽然题目提供了公式和常数，但计算过程较为复杂，需要仔细推导和验证。" + }, + { + "idx": 4743, + "question": "Consider a cylindrical nickel wire 2.0 mm(0.08 in.) in diameter and 3 × 10^{4}mm (1200 in.) long. Calculate its elongation when a load of 300N\\left(67 lb^{2}\\right) is applied. Assume that the deformation is totally elastic.", + "answer": "the elongation of the nickel wire is 13.8mm (0.53 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如弹性变形公式）来求解镍丝的伸长量，答案是一个具体的数值结果（13.8mm），符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即胡克定律和弹性变形公式的直接套用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要应用胡克定律的基本公式（应力=弹性模量×应变）进行简单计算。虽然涉及单位转换和代数运算，但解题步骤直接且无需多个公式组合，因此属于等级2难度。" + }, + { + "idx": 2383, + "question": "Assuming a monovalent cation and anion in an ionic crystal, the cation vacancy formation energy is 2000, the anion vacancy formation energy is 101-1'tra01, the cation interstitial formation energy is 30k=1,17701, calculate the concentration ratio of Schottky defects to Frenkel defects.", + "answer": "The concentration ratio of Schottky defects to Frenkel defects is exp(-60×10^3/RT)/exp(-50×10^3/RT)=exp(-10×10^3/RT). For example, at room temperature (300K), the above ratio equals 0.018.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Schottky缺陷与Frenkel缺陷的浓度比，答案给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目涉及多步计算和概念关联，需要综合应用Schottky缺陷和Frenkel缺陷的形成能公式，并进行浓度比的计算。虽然不涉及复杂的推理分析或机理解释，但需要理解和应用相关公式，并进行适当的数值计算。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及离子晶体中的缺陷形成能计算，需要掌握Schottky缺陷和Frenkel缺陷的概念，并能正确应用相关公式进行多步计算。虽然题目提供了部分数值，但需要考生能够正确理解并应用这些数值进行综合分析，最终得出正确的浓度比。此外，题目还要求考生能够理解温度对缺陷浓度的影响，并在特定温度下进行计算，这增加了题目的综合性和难度。" + }, + { + "idx": 2025, + "question": "The theoretical strength of amorphous materials is calculated to be $G/6\\\\sim G/4$, where $G$ is the shear modulus. Given $\\\\nu=0.25$, estimate the theoretical strength of glass (an amorphous material) based on its elastic properties (given $E=70~000~\\\\mathrm{MPa}$).", + "answer": "Therefore, the theoretical strength ranges between 0.4E and 0.4E, that is, $$4~900\\\\sim7~000~\\\\mathrm{MPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于给定的弹性模量（E=70 000 MPa）和泊松比（ν=0.25）计算玻璃的理论强度范围。解答过程涉及数值计算和公式应用（G=E/2(1+ν)），最终给出数值结果（4 900~7 000 MPa）。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的弹性模量和泊松比计算理论强度范围，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求基于给定的弹性模量E和泊松比ν，通过基本公式（G=E/[2(1+ν)]）计算剪切模量G，然后直接套用理论强度范围公式（G/6~G/4）进行计算。虽然涉及两个步骤，但都是直接套用基础公式，无需复杂推导或概念整合，因此在选择题型中属于等级2难度。" + }, + { + "idx": 4628, + "question": "Zinc has five naturally occurring isotopes: 48.63% of { }^{64} Zn with an atomic weight of 63.929 amu; 27.90% of { }^{66} Zn with an atomic weight of 65.926 amu^{\\text {; }} 4.10% of { }^{67} Zn with an atomic weight of 66.927 amu ; 18.75% of { }^{68} Zn with an atomic weight of 67.925 amu ; and 0.62% of { }^{70} Zn with an atomic weight of 69.925 amu. Calculate the average atomic weight of Zn.", + "answer": "the average atomic weight of \\mathrm{zn} is 65.400 amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（加权平均）来求解锌的平均原子量，答案是一个具体的数值结果。 | 知识层次: 题目要求计算锌元素的平均原子量，涉及基本公式应用（加权平均）和简单计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用平均原子量的计算公式（各同位素原子量乘以其丰度后相加），属于单一公式直接计算。题目提供了所有必要的数据，无需额外的推理或复杂的步骤，因此属于最低难度等级。" + }, + { + "idx": 4719, + "question": "Some hypothetical alloy is composed of 25 wt% of metal A and 75 wt% of metal B. If the densities of metals A and B are 6.17 and 8.00g / {cm}^{3}, respectively, and their respective atomic weights are 171.3 and 162.0g / mol, determine whether the crystal structure for this alloy is simple cubic, face-centered cubic, or body-centered cubic. Assume a unit cell edge length of 0.332nm.", + "answer": "the crystal structure is simple cubic with 1.00 atom per unit cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行一系列数值计算，包括重量百分比、密度、原子重量和单位晶胞边长等，以确定晶体结构类型。答案基于计算结果得出，而非从给定选项中选择或简单判断对错。 | 知识层次: 题目需要进行多步计算，包括质量分数到原子分数的转换、密度计算、单位晶胞原子数的确定等，涉及多个概念的综合应用和关联分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要综合运用多个概念并进行多步计算。题目涉及合金成分、密度、原子量以及晶体结构的综合分析，解题步骤包括计算合金密度、确定单位晶胞中的原子数等，需要较强的概念关联和计算能力。" + }, + { + "idx": 3987, + "question": "A hypothetical metal alloy has a grain diameter of 2.4 × 10^{-2} mm. After a heat treatment at 575^{\\circ} C for 500min, the grain diameter has increased to 7.3 × 10^{-2} mm. Compute the time required for a specimen of this same material (i.e., \\mathrm{d}_{0}=2.4 × 10^{-2}mm ) to achieve a grain diameter of 5.5 × 10^{-2}mm while being heated at 575^{\\circ} C. Assume the N grain diameter exponent has a value of 2.2.", + "answer": "the time required for the specimen to achieve a grain diameter of 5.5 × 10^{-2} mm is 246min.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解时间，答案是一个具体的数值结果（246min），解答过程需要运用材料科学中的晶粒生长公式进行计算。 | 知识层次: 题目需要进行多步计算，涉及公式应用和数值求解，需要理解晶粒生长动力学的基本原理，并能够将给定的初始条件和目标条件代入公式进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和概念关联。 | 难度: 在选择题中属于中等难度，需要理解晶粒生长动力学的基本概念，应用给定的指数关系进行多步计算，并综合分析初始条件和目标条件之间的关系。虽然题目提供了必要的参数和公式，但解题过程涉及多个步骤和数学运算，要求考生具备一定的材料科学基础和计算能力。" + }, + { + "idx": 3596, + "question": "Bismuth has a hexagonal structure, with a0=0.4546 nm and c0=1.186 nm. The density is 9.808 g/cm3 and the atomic weight is 208.98 g/mol. Determine the volume of the unit cell.", + "answer": "0.21226 nm3 or 2.1226 x 10^-22 cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定单位晶胞的体积，答案是一个具体的数值结果，解答过程需要运用密度、原子量和晶格参数等数据进行计算。 | 知识层次: 题目要求应用基本的晶体学公式计算单位晶胞体积，涉及简单的数值计算和单位转换，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算单位晶胞的体积，只需要应用六方晶系的体积公式V = (3√3/2) * a0² * c0，代入给定的a0和c0值即可得到结果。不需要额外的概念理解或多步骤计算，属于最基础的计算题类型。" + }, + { + "idx": 4215, + "question": "The unit cell for tin has tetragonal symmetry, with a and b lattice parameters of 0.583 and 0.318nm, respectively. If its density, atomic weight, and atomic radius are 7.30g / {cm}^{3}, 118.69g / mol, and 0.151nm, respectively, compute the atomic packing factor.", + "answer": "the atomic packing factor (apf) for tin is 0.534.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如计算原子堆积因子）来得出具体数值结果（0.534），属于典型的计算题特征。 | 知识层次: 题目需要多步计算和概念关联，包括晶胞参数、密度、原子量、原子半径等信息的综合运用，以及原子堆积因子的计算公式应用。虽然不涉及复杂的推理分析或机理解释，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算，包括晶胞体积、原子体积和原子堆积因子的计算，同时需要综合运用密度、原子量和晶格参数等概念。虽然题目提供了所有必要的数据，但解题过程需要一定的综合分析能力和对材料科学基础知识的掌握。" + }, + { + "idx": 1697, + "question": "Given: When the grain size of annealed pure iron is 16 per mm², the yield strength σₛ = 100 MPa. When the grain size is 4096 per mm², σₛ = 250 MPa. Find the value of yield strength σₛ when the grain size is 256 per mm².", + "answer": "According to the Hall-Petch formula, σₛ = σ₀ + Kd⁻¹ᐟ², the yield strength σₛ of the material is calculated from the average grain size d. The grain size is represented by the radius of an equal-area circle, i.e., d₁ = (4A₁/π)¹ᐟ², d₂ = (4A₂/π)¹ᐟ², where A₁ and A₂ are the grain areas. Thus, σₛ₁ = σ₀ + Kd₁⁻¹ᐟ², σₛ₂ = σ₀ + Kd₂⁻¹ᐟ². Given A₁ = 1/16 mm², A₂ = 1/4096 mm², σₛ₁ = 100 MPa, σₛ₂ = 250 MPa, we find K = 25√2 π⁻¹ᐟ⁴ MPa·mm¹ᐟ², σ₀ = 50 MPa. Then, with A₃ = 1/256 mm², we find σₛ₃ = 150 MPa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的数据和公式（Hall-Petch公式）进行计算，最终得出一个具体的数值结果（150 MPa）。解答过程涉及数值计算和公式应用，符合计算题的特征。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值求解。虽然计算过程较为直接，但需要一定的综合分析能力和公式应用技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和单位转换。虽然题目提供了关键公式和部分参数，但需要考生自行推导K值和σ₀值，并最终计算出新的屈服强度。这要求对材料科学中的晶粒尺寸与力学性能关系有较好的理解，并能进行综合计算分析。" + }, + { + "idx": 4709, + "question": "What is the composition, in atom percent, of an alloy that consists of 92.5 wt% \\mathrm{Ag} and 7.5 wt% Cu ?", + "answer": "the composition of the alloy is 87.9 \\text{ at}% \\text{ ag} and 12.1 \\text{ at}% \\text{ cu}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（如重量百分比转换为原子百分比）来得出具体的数值结果，答案也是以数值形式呈现的。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及原子百分比和重量百分比之间的转换，属于直接套用基本公式的简单应用。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用原子百分比和重量百分比之间的转换公式，但计算步骤相对直接，仅涉及基本代数运算和单位转换。不需要复杂的逻辑推理或多步骤的综合计算，因此难度等级为2。" + }, + { + "idx": 2335, + "question": "Given that the recrystallization activation energy of a Cu-Zn alloy (w_Zn=0.30) is 250 kJ/mol, and this alloy takes 1 hour to complete recrystallization at a constant temperature of 400°C, how many hours does it take for this alloy to complete recrystallization at a constant temperature of 390°C? (Shanghai Jiao Tong University postgraduate entrance exam question)", + "answer": "Given T_1=400°C=673 K, t_1=1 h, T_2=390°C=663 K, Q=2.5×10^5 J/mol. Let the time required to complete recrystallization at 390°C be t_2, then from A e^(-Q/(R T_1 )) t_1=A e^(-Q/(R T_2 )) t_2, we get t_1/t_2=e^[-Q/R (1/T_2 -1/T_1 )]=e^[-2.5×10^5/8.31×(1/663-1/673)]=0.509. Therefore, t_2=1.96 h.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解在390°C下完成再结晶所需的时间，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及多步计算和公式应用，需要理解再结晶激活能的概念，并能够正确应用阿伦尼乌斯公式进行计算。虽然计算过程较为直接，但需要将温度转换为开尔文温标，并进行指数运算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解并应用阿伦尼乌斯方程进行多步计算，涉及温度转换、指数运算和综合分析。虽然题目提供了所有必要参数，但解题过程需要较强的概念关联能力和计算技巧，属于综合性计算问题。" + }, + { + "idx": 2244, + "question": "In the regular melt α, the total driving force ΔG for the precipitation of β can be approximately expressed as ΔG=RT[x_o ln(x_o/x_e)+(1-x_o)ln((1-x_o)/(1-x_e))]-2Ω(x_o-x_e)^2. Given T=600K, x_o=0.1, x_e=0.02, Ω=0, use this expression to estimate the total driving force for α→α′+β.", + "answer": "Given T=600K, x_o=0.1, x_e=0.02, R=8.31 J/(mol·K). ΔG=RT[x_o ln(x_o/x_e)+(1-x_o)ln((1-x_o)/(1-x_e))]=8.31×600×[0.1 ln(0.1/0.02)+(1-0.1)ln((1-0.1)/(1-0.02))]=420.8 J/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式和参数进行数值计算，最终得出一个具体的数值结果。答案展示了具体的计算步骤和最终结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，不需要多步推理或综合分析，仅需将给定数值代入公式进行计算即可。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目提供了所有必要的参数和公式，只需要将给定的数值代入公式中进行简单的计算即可得到答案。不需要理解多个概念或进行复杂的分析，解题步骤非常直接和简单。" + }, + { + "idx": 1627, + "question": "Given that the yield strength of industrial pure copper is $\\\\sigma{\\\\mathrm{s}}=70\\\\mathrm{MPa}$, with a grain size of $N{\\\\mathbf{A}}=18$ per $\\\\nearrow\\\\mathbf{mm}^{2}$; when $N{\\\\mathbf{A}}=4025$ per $/\\\\mathbf{m}\\\\mathbf{m}^{2}$, $\\\\pmb{\\\\sigma{\\\\mathrm{s}}=95\\\\mathrm{MPa}}$; calculate the yield strength ${\\\\pmb{\\\\sigma}}{\\\\mathfrak{s}}$ when $N{\\\\mathrm{A}}=260$ per $\\\\scriptstyle\\\\left/\\\\mathbf{mm}^{2}\\\\right.$.", + "answer": "The relationship between grain size and yield strength satisfies the Hall-Petch formula, i.e., $$ \\\\sigma_{\\\\mathrm{s}}=\\\\sigma_{0}+K d^{-1/2} $$ Representing grain size by the diameter of an equal-area circle, thus $$ \\\\begin{array}{c}{{d=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{N_{\\\\mathrm{a}}}\\\\right)^{1/2}}}\\\\\\\\ {{d_{1}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{18}\\\\right)^{1/2}=0.22\\\\mathrm{mm}}}\\\\\\\\ {{d_{2}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{4025}\\\\right)^{1/2}=1.45\\\\times10^{-2}\\\\mathrm{mm}}}\\\\\\\\ {{d_{3}=\\\\mathrm{\\\\Gamma}\\\\left({8}/{3\\\\pi}/{260}\\\\right)^{1/2}=5.71\\\\times10^{-2}\\\\mathrm{mm}}}\\\\\\\\ {{\\\\sigma_{\\\\mathrm{s}1}=\\\\sigma_{0}+K d_{1}^{\\\\mathrm{\\\\Gamma}-1/2},\\\\sigma_{\\\\mathrm{s}2}=\\\\sigma_{0}+K d_{2}^{\\\\mathrm{\\\\Gamma}-1/2}}}\\\\end{array} $$ Substituting ${\\\\pmb\\\\sigma}_{\\\\mathrm{s}1}=70\\\\mathrm{MPa},{\\\\pmb\\\\sigma}_{\\\\mathrm{s}2}=95\\\\mathrm{MPa}$ to solve for $K=0.13\\\\mathrm{MPa\\\\cdot m^{1/2}},\\\\sigma_{0}=61.3\\\\mathrm{MPa}$, hence $\\\\sigma_{\\\\mathrm{s}}=78.3\\\\mathrm{MPa}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解屈服强度，解答过程中涉及到了Hall-Petch公式的应用和具体的数值计算步骤。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值代入和求解。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力和计算技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和变量求解。虽然题目提供了部分中间步骤，但仍需要考生具备综合分析能力和对材料科学基础概念的掌握。" + }, + { + "idx": 136, + "question": "The viscosity of SiO2 melt is 10^14 Pa·s at 1000°C and 10^7 Pa·s at 1400°C. What is the activation energy for viscous flow of SiO2 glass?", + "answer": "According to the formula: η=η0exp(ΔE/RT)\\nAt 1000°C, η=10^14 Pa·s, T=1000+273=1273 K\\nAt 1400°C, η=10^7 Pa·s, T=1400+273=1673 K\\nSolving the two equations simultaneously yields: η0=5.27×10^-16 Pa·s\\nΔE=713.5 kJ/mol", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解SiO2玻璃的粘流活化能，答案中包含了具体的计算步骤和结果。 | 知识层次: 题目需要应用Arrhenius方程进行多步计算，涉及温度转换和联立方程求解，属于中等应用层次。虽然不涉及复杂的概念关联或综合分析，但需要一定的计算能力和公式应用技巧。 | 难度: 在选择题中属于中等难度，需要理解粘度与温度的关系公式，进行多步计算（包括温度转换和联立方程求解），并综合分析结果。虽然题目提供了公式和步骤，但计算过程较为复杂，涉及对数运算和单位转换，对学生的计算能力和概念理解有一定要求。" + }, + { + "idx": 19, + "question": "Calculate the number of atoms in a hexagonal close-packed unit cell", + "answer": "Number of atoms 6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算六方密堆积晶胞中的原子数），答案是一个具体的数值结果（6），需要通过公式应用和计算过程来得出答案 | 知识层次: 题目要求计算六方密堆积晶胞中的原子数，这需要应用基本的晶体学知识和简单的数学计算。虽然需要理解六方密堆积的结构特点，但计算过程直接且不涉及多步推理或复杂分析，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（六方密堆积晶胞原子数计算公式）进行简单计算，无需复杂步骤或多公式组合。属于单一公式直接计算的等级1难度。" + }, + { + "idx": 4613, + "question": "An iron bar magnet having a coercivity of 4000 \\mathrm{~A} / m is to be demagnetized. If the bar is inserted within a cylindrical wire coil 0.15{m} long and having 100 turns, what electric current is required to generate the necessary magnetic field?", + "answer": "the required electric current is 6 \\mathrm{a}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定所需的电流值。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即根据给定的参数（矫顽力、线圈长度和匝数）直接套用公式计算所需的电流。不需要多步计算或复杂的概念关联。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（H = nI/l）进行计算，解题步骤简单，属于最基础的难度等级。" + }, + { + "idx": 3908, + "question": "If the atomic radius of a metal that has the body-centered cubic crystal structure is 0.181nm, calculate the volume of its unit cell.", + "answer": "the volume of the unit cell is 0.0271 nm^3.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解单位晶胞的体积，答案是一个具体的数值结果。 | 知识层次: 题目考查基本公式应用和简单计算，直接套用体心立方晶胞体积的计算公式即可得出结果，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算体心立方晶体结构的单位晶胞体积，只需应用已知的原子半径和体心立方晶体的几何关系公式（V = (4r/√3)^3）进行简单计算即可得出答案。无需多个公式组合或复杂推导，属于基础级别的应用。" + }, + { + "idx": 188, + "question": "At $20^{\\\\circ}\\\\mathrm{C}$ and normal pressure, mercury with a radius of $10~\\\\mathrm{^{-3}}\\\\mathrm{m}$ is dispersed into small mercury droplets with a radius of $10^{-9}\\\\mathrm{m}$. Calculate the work required for this process. The surface tension of mercury at $20^{\\\\circ}\\\\mathrm{C}$ is $0.47\\\\mathrm{N/m}$.", + "answer": "The work required for this process should equal the increase in the system's surface energy, i.e., $\\\\[ \\\\overline{W} = \\\\frac{0.47 \\\\times 10^{-9}}{10^{-27}} \\\\times 4 \\\\times 3.14 \\\\times 10^{-18} = 59 \\\\, \\\\text{W} \\\\]$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，涉及公式应用和具体数值的代入计算，答案也是具体的数值结果。 | 知识层次: 题目需要进行多步计算，包括表面能的计算和液滴数量的估算，涉及概念关联和综合分析。虽然公式应用直接，但需要理解表面能与液滴半径变化的关系，并进行适当的单位转换和数值计算。 | 难度: 在选择题中属于中等偏上难度，需要理解表面能的概念，掌握表面张力与表面积变化的关系，并进行多步计算。题目涉及从宏观到微观的尺度转换，要求考生能够正确应用公式并处理数量级变化，属于综合性计算问题。" + }, + { + "idx": 2670, + "question": "The crystal structure of Mo is body-centered cubic, with a lattice constant $a{=}0.3147{\\mathrm{~nm}}$. Determine the atomic radius $\\\\scriptstyle{\\\\mathcal{r}}_{\\\\circ}$ of Mo.", + "answer": "$$ \\\\alpha{=}\\\\frac{4r}{\\\\sqrt{3}}\\\\Rightarrow r{=}\\\\frac{\\\\sqrt{3}}{4}\\\\alpha{=}\\\\frac{\\\\sqrt{3}}{4}\\\\times0.3147{=}0.1363(\\\\mathrm{nm})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（体心立方晶格常数与原子半径的关系公式）来求解Mo的原子半径，答案是一个具体的数值计算结果。 | 知识层次: 题目考查基本的公式应用和简单计算，仅需将已知的晶格常数代入体心立方结构的原子半径公式进行计算，无需多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目仅涉及单一公式的直接应用（体心立方晶格常数与原子半径的关系公式），解题步骤简单明确，只需将已知数值代入公式并进行简单计算即可得出答案。无需多个公式组合或复杂分析，符合等级2的标准。" + }, + { + "idx": 3581, + "question": "In order to plate a steel part having a surface area of 200 in.^2 with a 0.002 in. thick layer of nickel, how many moles of nickel are required?", + "answer": "0.994 mol ni required", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算镍的摩尔数），涉及公式应用（体积、密度、摩尔质量等转换），答案以具体数值形式给出 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及面积、厚度和摩尔数的转换，属于直接套用基本公式的简单计算类型。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用基本公式（如体积计算和摩尔计算），但解题步骤较为直接，仅需套用公式并进行简单单位转换即可得出答案。相比等级1的直接计算，该题需要稍多的理解和应用，但不需要多个公式组合或复杂分析。" + }, + { + "idx": 2568, + "question": "The sample axis is rotated to [111], what is the rotation axis?", + "answer": "The rotation axis is [2 1 3]×[111]=[4 1 3].", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行向量叉乘计算来求解旋转轴，答案是通过数学运算得出的具体数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算（向量叉乘），并需要理解晶体学中旋转轴的概念及其计算方法，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解向量叉积的概念，并能正确应用公式进行计算。题目要求将样本轴旋转到[111]方向，并计算旋转轴，涉及多步计算和概念关联。虽然题目给出了正确选项的计算过程，但在选择题型中，学生仍需具备一定的综合分析能力才能正确理解和解答。" + }, + { + "idx": 2478, + "question": "A copper block subjected to large cold deformation has a stored energy of 2×10^5 J·m^-3, and the typical value of high-angle boundary energy is 0.5 J·m^-2. According to the classical homogeneous nucleation theory, what is the critical nucleus size for recrystallization?", + "answer": "According to classical nucleation theory, the critical nucleus radius r* = 2γ/ΔG, where γ is the boundary energy and ΔG is the stored energy per unit volume. Substituting the boundary energy and stored energy, we obtain r* = (2×0.5)/(2×10^5) m = 5×10^-7 m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和数据进行数值计算，最终得出一个具体的数值结果（临界核尺寸）。解答过程涉及公式应用和单位换算，符合计算题的特征。 | 知识层次: 题目主要涉及经典均质形核理论的基本公式应用，即通过给定的边界能和储存能直接套用公式计算临界核尺寸。虽然需要理解相关概念，但计算过程简单直接，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（r* = 2γ/ΔG）并进行简单的数值代入计算。解题步骤非常直接，无需多个公式组合或复杂的概念理解，属于最基础的难度等级。" + }, + { + "idx": 1388, + "question": "Calculate the coordination number of the cation in the compound MgO, given r(Mg2+)=0.078nm, r(O2-)=0.132nm", + "answer": "6", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的离子半径数值进行计算，以确定MgO中阳离子的配位数。解答过程需要应用半径比规则进行数值计算，最终得出具体的数值答案（6）。 | 知识层次: 题目要求根据给定的离子半径计算配位数，属于基本公式的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算MgO中阳离子的配位数，仅需根据给定的离子半径比值（r+/r-）直接套用配位数与半径比的关系表即可得出答案。无需多个公式组合或复杂计算步骤，属于基础知识的简单应用。" + }, + { + "idx": 3839, + "question": "Observation of a microstructure shows that there is 28% eutectic and 72% primary β in an Al-Li alloy. Determine the composition of the alloy and whether it is hypoeutectic or hypereutectic.", + "answer": "17.46% li, hypereutectic", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过观察到的微观结构比例（28%共晶和72%初生β）来计算合金的成分（17.46% Li）并判断其属于亚共晶还是过共晶（hypereutectic）。这需要应用杠杆定律等计算方法和相图知识，属于典型的计算题。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分判断，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解共晶反应、杠杆定律等概念，并进行多步计算和综合分析。题目要求根据显微组织比例反推合金成分并判断亚共晶或过共晶类型，涉及多个知识点的关联应用，但选项已给出正确答案，降低了部分难度。" + }, + { + "idx": 3699, + "question": "A 0.15% C steel is to be carburized at 1100^{\\circ} C, giving 0.35% C at a distance of 1mm beneath the surface. If the surface composition is maintained at 0.90% C, what time is required?", + "answer": "the required time is 51 \\mathrm{min}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及碳扩散时间的计算，答案以具体数值形式给出。 | 知识层次: 题目涉及多步计算和概念关联，需要应用扩散定律和误差函数解，综合分析碳浓度分布与时间的关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解碳扩散的基本概念，掌握菲克第二定律的应用，并进行多步骤计算。题目涉及表面浓度、目标浓度和距离的设定，要求考生能够正确代入公式并解出时间参数。虽然题目提供了具体数值，但计算过程需要一定的综合分析能力和对材料科学基础知识的掌握。" + }, + { + "idx": 2869, + "question": "Given that the Tm of Fe is 1538°C, estimate the minimum recrystallization temperature of Fe.", + "answer": "According to the empirical formula, the recrystallization temperature Tr≈0.4Tm. Therefore, the minimum recrystallization temperature of Fe is Tr=0.4×(1538+273)=724.4(K)=451.4(°C). In production, to improve efficiency, the actual recrystallization annealing temperature in factories is usually selected as Tr+(100~200)(°C).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（0.4×(1538+273)）并应用经验公式（Tr≈0.4Tm）来求解铁的再结晶温度，属于典型的计算题类型。答案中给出了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查对经验公式的直接应用和简单计算，涉及将熔点转换为绝对温度并进行基本乘法运算，属于基本公式的直接套用和简单计算范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的经验公式（Tr≈0.4Tm）进行简单计算，无需额外的概念理解或复杂的解题步骤。属于单一公式直接计算的类型，因此难度等级为1。" + }, + { + "idx": 173, + "question": "How much Na2O should be added to SiO2 to make the O/Si ratio of the glass equal to 2.5? Assume the amount of SiO2 is ymol.", + "answer": "Let xmol of Na2O be added, then O/Si=(x+2y)/y=2.5. Solving gives x=y/2, meaning when the molar ratio of the two is 1:2, O/Si=2.5.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过设定变量和建立方程来求解所需的Na2O量。答案展示了具体的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的O/Si比例关系进行代数运算，属于直接套用公式和简单计算的范畴，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解O/Si比的概念并正确设置方程，但解题步骤相对直接，仅涉及单一公式的简单代数运算（解一元一次方程）。相比更复杂的多步骤计算或概念组合题，此题的难度较低，属于等级2。" + }, + { + "idx": 2956, + "question": "According to the relationship d²=kt and k=17.6μm²/min, find the grain diameter d after annealing for 60 minutes.", + "answer": "d = √(17.6μm²/min × 60min) = √1056μm² = 32.5μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和数学运算，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析，属于基础知识的简单应用。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式d²=kt，并进行简单的平方根计算即可得出答案。解题步骤非常直接，无需组合多个公式或进行复杂分析，属于最基础的难度等级。" + }, + { + "idx": 1101, + "question": "A metal test bar with a length of 20cm and a cross-sectional area of 4cm² is fixed at the upper end and subjected to a tensile force of 980N at the lower end. Find the angle θ at which the shear stress is maximum.", + "answer": "The angle θ at which the shear stress is maximum is 45°.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用来求解最大剪应力对应的角度θ，答案是一个具体的数值结果（45°），这符合计算题的特征。 | 知识层次: 题目涉及基本的应力计算和公式应用，需要理解剪切应力的概念并应用相关公式进行计算，但不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，需要应用基本的剪切应力公式，并进行简单的角度计算。虽然涉及公式应用，但步骤直接且不涉及多个公式的组合。" + }, + { + "idx": 3812, + "question": "Consider a Pb-35% Sn alloy. Determine the amounts and compositions of each base at 182°C.", + "answer": "α: 19% sn, β: 97.5% sn, % α = 80%, % β = 20%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Pb-35% Sn合金在182°C时各相的量和组成，需要使用相图和杠杆定律进行数值计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要理解相图的基本原理并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念并进行多步计算。题目要求确定Pb-35% Sn合金在182°C时各相的组成和含量，这涉及到杠杆定律的应用和相图分析。虽然选择题提供了正确选项，但仍需要考生能够正确识别相图中的关键点（如共晶点和溶解度极限），并进行组成和含量的计算。这种题目比简单的概念识别题更难，但比需要复杂推导的开放性问题简单。" + }, + { + "idx": 3706, + "question": "During freezing of a Cu-Zn alloy, we find that the composition is nonuniform. By heating the alloy to 600^{\\circ} C for 3 hours, diffusion of zinc helps to make the composition more uniform. What temperature would be required if we wished to perform this homogenization treatment in 30 minutes?", + "answer": "667°c", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过扩散时间与温度的关系计算出所需的温度，答案是一个具体的数值（667°C），符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及扩散方程的应用和温度与时间关系的调整，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散动力学中的阿伦尼乌斯方程，并进行多步骤计算（包括时间-温度转换和对数运算）。虽然题目提供了部分参数，但考生仍需综合运用材料科学中的热处理和扩散知识来推导正确答案。相比单纯的概念题或单步计算题，该题目要求更高层次的分析能力和计算技巧。" + }, + { + "idx": 2857, + "question": "The recovery activation energy of iron is $88.9\\\\mathrm{kJ/mol}$. If cold-deformed iron is subjected to recovery treatment at $400^{\\\\circ}\\\\mathrm{C}$ to retain 60% of its work hardening, it takes $160\\\\mathfrak{min}$. How much time is needed to achieve the same effect with recovery treatment at $450\\\\mathrm{~C~}$?", + "answer": "$$\\\\frac{t_{1}}{t_{2}}=\\\\mathrm{e}^{-{\\\\frac{Q}{R}(\\\\frac{1}{T_{2}}-\\\\frac{1}{T_{1}})}} , t_{2}={\\\\frac{t_{1}}{\\\\mathrm{e}^{-{\\\\frac{\\\\mathrm{{Q}}}{\\\\scriptscriptstyle{R}}}\\\\big({\\\\frac{1}{T_{2}}}-{\\\\frac{1}{T_{1}}}\\\\big)}}}}={\\\\frac{160}{\\\\mathrm{e}^{-{\\\\frac{80.5}{831}}\\\\big({\\\\frac{1}{723}}-{\\\\frac{1}{673}}\\\\big)}}}=59(\\\\operatorname*{min})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来解决问题，答案给出了具体的计算过程和最终的时间结果。 | 知识层次: 题目需要进行多步计算，包括公式应用和数值计算，涉及温度转换和激活能的概念关联，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及恢复激活能的概念，需要应用阿伦尼乌斯公式进行多步计算，包括温度转换和指数运算。虽然题目提供了公式，但需要正确代入数值并进行复杂的数学运算才能得出正确答案。这要求考生具备中等应用层次的知识，能够将理论知识与实际计算相结合。" + }, + { + "idx": 4787, + "question": "The tensile strength and number-average molecular weight for two poly(methyl methacrylate) materials are as follows:\n\\begin{tabular}{cc}\n\\hline Tensile Strength (MPa) & Number-Average Molecular Weight (g/mol) \\\\\n\\hline 50 & 30,000 \\\\\n150 & 50,000 \\\\\n\\hline\n\\end{tabular}\nEstimate the tensile strength at a number-average molecular weight of 40,000 g/mol.", + "answer": "the estimated tensile strength at a number-average molecular weight of 40,000 g/mol is 112.5 mpa.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了两组数据（拉伸强度和数均分子量），要求通过计算估计在特定分子量下的拉伸强度。解答过程需要数值计算和可能的插值或外推公式应用，答案也是具体的数值结果。 | 知识层次: 题目需要应用给定的数据点进行简单的线性插值计算，属于基本公式的直接应用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解拉伸强度与数均分子量之间的关系，但题目提供了直接的数据点，只需进行简单的线性插值计算即可得出答案。解题步骤较为直接，不涉及复杂的公式组合或深入的概念分析。" + }, + { + "idx": 2022, + "question": "A common polymer has C2H2Cl2 as its monomer, with an average molecular weight of 60000u (using the relative atomic masses of the elements as Ar(C)=12, Ar(H)=1, Ar(Cl)=35.5). What is its degree of polymerization?", + "answer": "The degree of polymerization is n = 60000 / 97 = 620", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（分子量计算和聚合度计算），并应用相关公式（聚合度 = 聚合物分子量 / 单体分子量）。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目考查基本的公式应用和简单计算，只需要将聚合物的平均分子量除以单体的分子量即可得到聚合度，属于直接套用公式的计算题。 | 难度: 在选择题型中，该题目仅需要直接套用基本公式（分子量除以单体分子量）进行简单计算，无需额外的概念理解或复杂步骤。属于单一公式直接计算的难度等级。" + }, + { + "idx": 3647, + "question": "The density of a sample of HCP beryllium is 1.844 g/cm³ and the lattice parameters are a₀=0.22858 nm and c₀=0.35842 nm. Calculate the fraction of the lattice points that contain vacancies.", + "answer": "0.0008", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，涉及密度、晶格参数和空位分数的计算，需要应用相关公式和步骤来得出具体数值答案。答案是一个具体的数值（0.0008），符合计算题的特征。 | 知识层次: 题目需要应用HCP晶体结构的基本知识，进行多步计算（包括密度计算、晶格参数应用、空位分数计算等），涉及概念关联和综合分析，但不需要复杂的推理或机理解释。 | 难度: 在选择题中属于中等偏上难度，需要理解六方密堆积（HCP）晶体的结构参数与密度的关系，并应用密度公式计算理论密度与实际密度的差异，进而推导空位分数。解题步骤包括：" + }, + { + "idx": 190, + "question": "In $2080^{\\\\circ}\\\\mathrm{C}$ $\\\\mathrm{Al_{2}O_{3}}$ (L), there is a small bubble with a radius of $10~\\\\mathrm{^{-8}m}$. What is the additional pressure experienced by the bubble? It is known that the surface tension of $\\\\mathrm{Al_{2}O_{3}}$ (L) at $2080^{\\\\circ}\\\\mathrm{C}$ is $0.700\\\\mathrm{N/m}$.", + "answer": "According to the formula $\\\\triangle P=2y$, the additional pressure can be calculated as $\\\\triangle P{=}2\\\\times0.7/10^{-8}{=}1.$ $4\\\\times10^{8}\\\\mathrm{N}$.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式计算气泡的额外压力，答案给出了具体的计算过程和数值结果，符合计算题的特征。 | 知识层次: 题目主要考查基本公式（Laplace压力公式）的直接应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（△P=2y）进行计算，无需理解多个概念或进行复杂的分析。解题步骤简单，仅涉及基本公式应用和简单计算，属于最基础的难度等级。" + }, + { + "idx": 96, + "question": "In the non-stoichiometric compound Fe_xO, Fe^{3+}/Fe^{2+}=0.1. Find the vacancy concentration in Fe_xO.", + "answer": "Fe2O3 →2FeFe +3O0+V_Fe. Let y be the concentration of Fe^{3+}, then 2y =0.1→2y=0.1-0.3y→y=0.1/2.3=0.0435. The vacancy concentration [V_Fe''] = y = 0.0435.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非化学计量化合物Fe_xO中的空位浓度，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及非化学计量化合物Fe_xO中Fe^{3+}/Fe^{2+}比值的计算，需要理解缺陷化学的基本原理，并应用相关公式进行多步计算。虽然不涉及复杂的机理分析或创新设计，但需要综合分析缺陷反应方程和浓度关系，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解非化学计量化合物的概念，掌握Fe^{3+}/Fe^{2+}比例与空位浓度的关系，并进行多步计算推导。题目涉及电荷平衡和缺陷化学的综合分析，虽然给出了正确选项的推导过程，但仍需要较强的概念关联和计算能力才能正确解答。" + }, + { + "idx": 160, + "question": "Calculate the structural parameters and non-bridging oxygen fraction of the glass (2) Na2O•CaO•Al2O3•SiO2", + "answer": "Na2O+CaO/(2*Al2O3)=2>1, Al is considered as a network-forming ion. Z=4, R=(1+1+3+2)/(2+1)=2.33, X=2R-Z=4.66-4=0.66, Y=4-0.66=3.34. Non-bridging oxygen %=0.66/(1.67+0.66)=28.3%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及结构参数和非桥氧分数的计算，答案以数值结果呈现。 | 知识层次: 题目需要进行多步计算，涉及结构参数和非桥氧分数的计算，需要理解网络形成离子的概念，并应用相关公式进行综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如网络形成离子、结构参数计算、非桥氧分数等）并进行多步骤计算（包括比值判断、Z值计算、R值计算、X/Y值推导等）。虽然题目提供了正确选项，但解题过程涉及多个关联概念和综合计算步骤，超出了基础选择题的单一知识点考察范围。" + }, + { + "idx": 3665, + "question": "Calculate the length of the Burgers vector in FCC silver", + "answer": "b = 2.889 Å", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算FCC银中Burgers矢量的长度），答案是一个具体的数值结果（2.889 Å），需要使用材料科学中的相关公式和计算方法。 | 知识层次: 题目要求计算FCC银的Burgers矢量长度，这需要应用基本的晶体学公式和已知的晶格常数进行简单计算。虽然需要理解Burgers矢量的概念，但计算过程直接且不涉及多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需直接应用FCC晶体结构中Burgers矢量的基本公式（b = a√2/2），并进行简单的数值计算。题目明确给出了所有必要参数（FCC银的晶格常数a=4.09Å），解题步骤单一且无需复杂推导，完全符合等级1\"单一公式直接计算\"的标准。" + }, + { + "idx": 31, + "question": "In CaS, the unit cell parameter a=0.567 nm, and the anions and cations are in contact with each other. Calculate the radius of Ca2+. The radius of S2- is known to be 0.177 nm.", + "answer": "In CaS, a=0.567 nm, and the anions and cations are in contact with each other, a=2(r+ + r-), therefore rCa2+=(0.567 nm / 2) - 0.177 nm = 0.107 nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算，应用给定的公式（a=2(r+ + r-)）来求解Ca2+的半径，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的公式应用和简单计算，只需要直接套用已知的半径公式进行计算即可，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（a=2(r+ + r-)）进行简单计算即可得出答案，无需额外的概念理解或步骤组合。属于最基础的直接计算类型。" + }, + { + "idx": 4746, + "question": "A cylindrical rod of steel (E=207 \\mathrm{GPa}, 30 × 10^{6} psi) having a yield strength of 310 MPa(45,000 psi) is to be subjected to a load of 11,100N(2500 lb). If the length of the rod is 500 mm(20.0 in.), what must be the diameter to allow an elongation of 0.38 mm(0.015 in.)?", + "answer": "the diameter must be 9.5 mm (0.376 in.).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定圆柱形钢棒的直径。解答过程涉及弹性模量、载荷和伸长量等参数的计算，最终得出具体的直径数值。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即胡克定律和应力应变关系的直接套用，无需多步计算或综合分析。 | 难度: 在选择题中属于简单公式应用计算难度。题目要求直接应用胡克定律和圆柱体横截面积公式，步骤较为直接，只需进行简单代数运算即可得出答案。虽然涉及单位转换，但在选择题型中，这些步骤被简化，因为正确选项已经给出，减少了计算错误的可能性。" + }, + { + "idx": 3656, + "question": "Suppose we introduce one carbon atom for every 100 iron atoms in an interstitial position in BCC iron, giving a lattice parameter of 0.2867 nm. For the Fe-C alloy, find the density.", + "answer": "7.89 g/cm³", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解Fe-C合金的密度，答案是一个具体的数值（7.89 g/cm³），这表明解答过程需要涉及材料科学中的密度计算公式和单位转换等计算步骤。 | 知识层次: 题目需要进行多步计算，包括确定晶胞中的原子数、计算晶胞质量、体积以及最终的密度计算。虽然不涉及复杂的机理分析或创新设计，但需要综合运用晶体结构、原子质量和密度计算等知识，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要综合运用晶体结构、原子质量和密度计算的知识。解题步骤包括：1) 理解BCC铁的单位晶胞原子数；2) 计算掺杂碳后的晶胞质量；3) 利用晶格参数计算晶胞体积；4) 综合计算密度。虽然题目给出了关键参数（晶格常数），但仍需进行多步计算和单位换算，且需要正确理解间隙固溶体的概念。相比简单回忆型选择题，这需要更高层次的应用能力。" + }, + { + "idx": 3938, + "question": "The concentration of carbon in an iron-carbon alloy is 0.57 wt%. What is the concentration in kilograms of carbon per cubic meter of alloy? The densities of iron and carbon are 7.87 and 2.25 \\mathrm{g} / {cm}^{3}, respectively.", + "answer": "the concentration of carbon is 11.8 kg / m^{3}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，涉及浓度转换和密度计算，最终需要得出具体的数值结果（11.8 kg/m³）。答案形式为计算得出的具体数值，而非选择、判断或文字解释。 | 知识层次: 题目需要进行多步计算，涉及质量分数转换、密度计算和单位换算，需要综合运用多个概念和公式，但不需要复杂的推理或创新思维。 | 难度: 在选择题中属于中等偏上难度，需要理解质量分数与体积浓度的转换，涉及密度计算和单位换算，属于综合性计算问题。虽然题目给出了关键数据，但解题过程需要多步骤计算和概念关联，对学生的应用能力有一定要求。" + }, + { + "idx": 2088, + "question": "Based on microstructural analysis, the volume of graphite in a gray cast iron accounts for 12%, and the volume of ferrite accounts for 88%. Determine the value of ωC (given that the density of graphite ρG=2.2 g/cm³, and the density of ferrite ρα=7.8 g/cm³).", + "answer": "ωC=0.037.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定ωC的值，答案是一个具体的数值结果，解答过程需要运用给定的密度数据和体积百分比进行计算。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及体积分数和密度的转换，属于直接套用公式的计算题，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要应用密度和体积分数的基本公式，但解题步骤较为直接，仅需套用公式进行简单计算即可得出结果。不需要复杂的推理或多步骤的公式组合，因此在选择题型内属于等级2难度。" + }, + { + "idx": 18, + "question": "Calculate the packing coefficient in a face-centered cubic unit cell", + "answer": "Atomic packing coefficient APC=(4×(4/3)πr^3)/(2√2r)^3=74.05%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算面心立方晶胞的堆积系数），答案给出了具体的计算公式和计算结果（74.05%），符合计算题的特征 | 知识层次: 题目要求应用基本公式（球体积公式和立方体体积公式）进行直接计算，并套用到面心立方晶胞的具体结构中。虽然需要理解晶胞结构和原子堆积的概念，但计算过程相对直接，属于基本公式应用和简单计算的范畴。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要理解面心立方晶胞的结构和原子堆积系数的概念，但解题步骤相对直接，只需套用给定的公式进行计算即可。不需要多个公式的组合或复杂的推导过程，因此难度等级为2。" + }, + { + "idx": 2853, + "question": "For an Al2O3 specimen with a circular cross-section in a three-point bending test, the cross-sectional radius r=3.5mm, the span between the two supports is 50mm, and it fractures under a load of 950N. Calculate the fracture strength σfs of the material.", + "answer": "σfs = (Ff * L) / (π * r^3) = (950 * 50 * 10^-3) / (π * (3.5 * 10^-3)^3) = 352.6 MPa", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程涉及具体数值的代入和计算，最终得出一个具体的数值结果（352.6 MPa）。 | 知识层次: 题目主要考查基本公式的应用和简单计算，涉及三点弯曲测试中的断裂强度计算，属于直接套用公式的范畴，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然需要套用三点弯曲测试的断裂强度公式，但计算步骤直接且明确，仅涉及单一公式的代入和简单数学运算。题目没有复杂的转换或额外概念要求，属于基础应用层次。" + }, + { + "idx": 3892, + "question": "Hafnium has six naturally occurring isotopes: 0.16% of { }^{174} Hf, with an atomic weight of 173.940 amu; 5.26% of { }^{176} Hf, with an atomic weight of 175.941 amu ; 18.60% of { }^{177} Hf, with an atomic weight of 176.943 amu ; 27.28% of { }^{178} Hf, with an atomic weight of 177.944 amu ; 13.62% of { }^{179} Hf, with an atomic weight of 178.946 amu;. and 35.08% of { }^{180} Hf, with an atomic weight of 179.947 amu. Calculate the average atomic weight of Hf. Give your answer to three decimal places.", + "answer": "the average atomic weight of hf is 178.485 amu.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算（各同位素的原子质量与其丰度的加权平均）来求解铪的平均原子量，并给出了具体的计算步骤和精确到小数点后三位的要求。答案也是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求根据给定的同位素丰度和原子质量计算平均原子量，这属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然题目提供了多个同位素的数据，但计算平均原子重量的步骤是直接套用加权平均公式，不需要复杂的推理或多步骤计算。学生只需将各同位素的百分比乘以对应的原子质量，然后相加即可得到结果。因此，在选择题型内，这属于中等偏下的难度。" + }, + { + "idx": 4742, + "question": "An aluminum bar 125mm (5.0 in.) long and having a square cross section 16.5mm (0.65 in.) on an edge is pulled in tension with a load of 66,700N(15,000 lb) and experiences an elongation of 0.43 mm(1.7 × 10^{-2} in.). Assuming that the deformation is entirely elastic, calculate the modulus of elasticity of the aluminum.", + "answer": "the modulus of elasticity of the aluminum is 71.2 gpa (10.4 × 10^{6} psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（长度、截面积、载荷、伸长量）进行数值计算，应用胡克定律公式来求解铝的弹性模量。答案是一个具体的数值计算结果，符合计算题的特征。 | 知识层次: 题目要求应用基本公式（胡克定律）进行简单的弹性模量计算，涉及直接套用公式和单位换算，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用胡克定律和应力应变公式，但计算步骤直接且无需复杂推导。题目明确给出了所有必要参数，只需套用公式即可得出答案，属于基础应用层次。" + }, + { + "idx": 2828, + "question": "Determine the engineering strain εe and true strain εT when compressed from h to 0.9h, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (0.9 - 1)h / h = -10%; εT = ln(0.9h / h) = -10.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算工程应变和真实应变）并应用相关公式，答案也以数值形式给出，符合计算题的特征。 | 知识层次: 题目要求进行基本的工程应变和真实应变计算，涉及直接套用公式（εe = ΔL/L0 和 εT = ln(L/L0)），属于简单应用层次。虽然需要理解两种应变的定义，但计算过程直接且无需多步推理或综合分析。 | 难度: 在选择题中属于简单应用难度，需要应用工程应变和真实应变两个基本公式进行计算，但不需要复杂的推导或分析。题目直接给出了变形前后的高度比，只需套用公式即可得出结果。虽然涉及两个公式，但计算过程简单直接，属于选择题型中的基础难度水平。" + }, + { + "idx": 4334, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). How many kilograms each of pearlite and the proeutectoid phase form?", + "answer": "the pearlite formed is 2.12 kg, and the proeutectoid ferrite formed is 0.38 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算，应用材料科学中的相变知识，通过公式和计算得出具体的重量结果（2.12 kg和0.38 kg）。答案的形式是具体的数值，而不是选择、判断或文字解释。 | 知识层次: 题目涉及多步计算和概念关联，需要理解相图、杠杆定律的应用，并进行综合分析以确定各相的比例和重量。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，如理解奥氏体冷却过程中的相变、计算珠光体和先共析相的比例等。虽然题目给出了正确选项，但学生仍需掌握相关概念和计算方法才能正确选择。" + }, + { + "idx": 1070, + "question": "Assuming carbon atoms are all located in the octahedral interstices of γ-Fe, calculate the maximum proportion of octahedral interstices occupied by carbon atoms in γ-Fe. (The atomic weight of iron is 55.85, and the Avogadro constant is 0.602×10^24)", + "answer": "In the γ-Fe phase, the maximum carbon concentration C_max = 2.11%. Given that γ-Fe has an FCC structure with n = 4, there are 400 Fe atoms per 100 unit cells. The mass fraction of Fe is: w_Fe = 1 - 2.11% = 97.89%. The total mass is: M = (400 × 55.85) / 0.9789 = 22821.5. The number of carbon atoms is: n_c = (M × C_max) / M_c = (22821.5 × 0.0211) / 12 = 40. Thus, there are 40 carbon atoms per 100 unit cells.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，以确定γ-Fe中碳原子占据八面体间隙的最大比例。答案中包含了具体的计算步骤和数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括质量分数的转换、总质量的计算以及碳原子数量的确定。虽然涉及的是基本的公式应用，但需要综合运用多个概念和步骤来解决问题，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解γ-Fe的FCC结构、碳原子占据八面体间隙的概念，并进行多步计算（包括质量分数计算、总质量计算和碳原子数量计算）。虽然题目提供了部分数据，但仍需要综合应用材料科学和化学知识来解决问题。" + }, + { + "idx": 1488, + "question": "For the equilibrium state of T12 steel (w_C=1.2%), write its room temperature microstructure constituents and calculate the mass fraction of each constituent.", + "answer": "Microstructure constituents: P+Fe3CⅡ. w_P=(6.69-1.2)/(6.69-0.77)×100%≈92.74%. w_Fe3CⅡ=(1.2-0.77)/(6.69-0.77)×100%≈7.26%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算质量分数（w_P和w_Fe3CⅡ），需要使用给定的公式进行数值计算，答案呈现为具体的计算结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，需要根据给定的碳含量和铁碳相图进行直接套用公式计算各相的质量分数。虽然需要理解铁碳相图的基本概念，但整体思维过程较为直接，不涉及多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要应用杠杆定律计算质量分数，但解题步骤明确且直接，只需套用单一公式即可完成计算。相较于需要多个公式组合或复杂分析的题目，该题的解题过程较为简单直接。" + }, + { + "idx": 3615, + "question": "What is the radius of an atom that will just fit into the octahedral site in FCC copper without disturbing the crystal structure?", + "answer": "0.529 Å.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求计算一个原子半径的具体数值（0.529 Å），这需要通过应用晶体结构和几何关系的公式来完成。解答过程涉及数值计算和理论应用，符合计算题的特征。 | 知识层次: 题目需要应用晶体结构中的间隙位置计算知识，涉及FCC铜的晶格常数和八面体间隙半径的计算公式，需要进行多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、八面体间隙的概念，并应用原子半径与晶格参数的关系进行多步计算。虽然题目给出了正确选项，但解题过程涉及多个知识点的综合应用和计算步骤，比单纯的概念选择题更复杂。" + }, + { + "idx": 4330, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). How many kilograms each of total ferrite and cementite form?", + "answer": "the total ferrite formed is 0.83 kg, and the total cementite formed is 0.17 kg.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算确定铁素体和渗碳体的质量，需要应用相图和相关公式进行计算，最终给出具体的数值结果。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算以确定不同相的含量。虽然涉及基础概念，但需要理解相变过程并运用杠杆定律进行计算，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图、杠杆定律等概念，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及多个知识点的关联应用和较复杂的计算步骤，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 3151, + "question": "In has a tetragonal structure, with a relative atomic mass Ar=114.82, lattice constants a=0.3252 nm, c=0.4946 nm, atomic radius r=0.1625 nm, density ρ=7.286 g/cm³. Determine the number of atoms per unit cell of In.", + "answer": "From the density expression ρ=(n×114.82)/((0.3252×10⁻⁷)²×0.4946×10⁻⁷×6.023×10²³)≈7.286, the number of atoms per unit cell is obtained as n≈1.999, n=2, which should be a body-centered tetragonal structure.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要通过数值计算和公式应用来确定每个晶胞中的原子数，答案给出了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，包括密度公式的应用、单位转换和数值计算，同时需要理解晶体结构的基本概念和关联密度与晶胞参数的关系。虽然不涉及复杂的推理分析，但需要综合运用多个知识点进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解晶体结构、密度计算和单位晶胞原子数的关系，并进行多步计算和综合分析。虽然题目提供了所有必要的数据，但解题过程涉及单位换算、公式应用和逻辑推理，需要较强的应用能力和计算技巧。" + }, + { + "idx": 3862, + "question": "A steel contains 94 % pearlite and 6 % primary cementite at room temperature. Estimate the carbon content of the steel.", + "answer": "the carbon content of the steel is 1.124 % c.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算估计钢的碳含量，答案是一个具体的数值结果（1.124 % c），解答过程需要应用材料科学中的相图或相关公式进行计算。 | 知识层次: 题目需要应用杠杆定律（lever rule）进行多步计算，涉及相图中珠光体和初生渗碳体的比例关系，需要理解相图的基本原理并进行综合分析。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图中珠光体和初生渗碳体的组成比例关系，并进行多步计算来推导碳含量。虽然题目给出了明确的比例数据，但需要考生掌握相图知识并正确应用杠杆定律进行计算，属于综合性计算问题。" + }, + { + "idx": 306, + "question": "During the melt cooling and crystallization process, given the solid-liquid interfacial energy γ_sl=5×10^-6 J/cm^2 and the unit volume free energy change △Gv=2090 J/cm^3 at 900°C, calculate the energy required for the phase transition.", + "answer": "The energy required for the phase transition △G* = 16πγ_sl^3/3(△Gv)^2 = 16×3.14×(5×10^-6)^3/3×(2090)^2 = 3.24×10^-19 J", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案是通过具体计算得出的数值结果。 | 知识层次: 题目主要涉及基本公式的直接套用和简单计算，不需要多步推理或综合分析，属于对相变能量计算的基本应用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目明确给出了所需的公式和所有必要的参数，只需要将这些数值代入公式进行简单的计算即可得到正确答案。不需要理解多个概念或进行复杂的分析，因此属于最低难度等级。" + }, + { + "idx": 2634, + "question": "The percentage of ionic character in the bonding between elements A and B can be approximately expressed by the following formula: IC(%)=[1-e^(-0.25(x_A-x_B)^2)]×100, where x_A and x_B are the electronegativity values of elements A and B, respectively. Given that the electronegativities of In and Sb are 1.7 and 1.9, respectively, calculate the IC(%) for InSb.", + "answer": "For InSb: IC(%)=[1-e^(-0.25)(1.9-1.7)^2]×100=1.0%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的公式进行数值计算，最终得出一个具体的百分比数值。解答过程涉及代入已知的电子亲和力值并进行数学运算，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，只需将给定的电负性值代入公式进行计算即可，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用给定的公式进行简单计算，无需额外的概念理解或复杂的解题步骤。题目提供了所有必要的信息（电负性值和公式），学生只需将数值代入公式并完成基本的数学运算即可得出答案。因此，该题目在选择题型内属于最低难度等级。" + }, + { + "idx": 3710, + "question": "A 850-lb force is applied to a 0.15-in. diameter nickel wire having a yield strength of 45,000 psi and a tensile strength of 55,000 psi. Determine whether the wire will experience necking.", + "answer": "no necking will occur (48,100 psi).", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目需要进行数值计算（计算应力并与屈服强度和抗拉强度比较）来判断是否会发生颈缩现象，答案给出了具体的计算结果（48,100 psi）和结论。 | 知识层次: 题目需要进行简单的应力计算（力除以横截面积），并将计算结果与给定的材料强度参数进行比较。虽然涉及公式应用，但计算步骤单一，无需多步推理或综合分析，属于基本公式的直接套用和简单判断。 | 难度: 在选择题型中，该题目属于简单应用层次，需要应用基本公式（应力计算）并进行简单计算。虽然涉及应力与材料强度的比较，但解题步骤较为直接，仅需套用公式并比较数值，无需多个公式组合或复杂分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3820, + "question": "Consider a Pb-70% Sn alloy. Determine the amounts and compositions of each phase at 25 degrees C.", + "answer": "alpha: 2% sn, beta: 100% sn, % alpha = 30%, % beta = 70%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过计算确定Pb-70% Sn合金在25°C时各相的数量和组成，答案给出了具体的数值计算结果（alpha: 2% sn, beta: 100% sn, % alpha = 30%, % beta = 70%），这需要应用相图和相关公式进行计算。 | 知识层次: 题目涉及基本的相图应用和简单的百分比计算，属于直接套用公式和基本概念的应用层次，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要运用杠杆法则（lever rule）进行简单的相组成计算。虽然涉及两个相（alpha和beta）的组成和比例计算，但步骤较为直接，仅需套用基本公式即可得出结果，无需复杂的分析或组合多个公式。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 2477, + "question": "How much energy is released before and after the merging?", + "answer": "The grain boundary energy per unit area after merging is 2θ E0(A - ln2θ), the energy of the two grain boundaries before merging is 2θ E0(A - lnθ), and the relative value of released energy after merging ΔE is ΔE = (2θ E0(A - lnθ) - 2θ E0(A - ln2θ))/(2θ E0(A - lnθ)) = (ln2θ - lnθ)/(0.5 - lnθ) = (ln(2 × 10^-3) - ln10^-3)/(0.5 - ln10^-3) = 9.35%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，答案中包含了具体的计算过程和结果。 | 知识层次: 题目需要进行多步计算，涉及公式的应用和推导，需要理解晶界能量变化的概念，并进行综合分析以得出最终的能量释放值。虽然不涉及复杂的机理或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多步计算和概念关联，要求考生能够理解并应用能量释放的计算公式，同时进行对数运算和百分比计算。虽然计算步骤较多，但在选择题型中，选项提供了明确的公式和计算路径，降低了部分难度。" + }, + { + "idx": 4815, + "question": "Steady-state creep rate data are given in the following table for some alloy taken at 200^{\\circ} C(473 K) :\n\\begin{tabular}{ll}\n\\hlines\\left(h^{-1}\\right) & \\sigma[MPa(psi)] \\\\\n\\hline 2.5 × 10^{-3} & 55(8000) \\\\\n2.4 × 10^{-2} & 69(10,000) \\\\\n\\hline\n\\end{tabular}\nIf it is known that the activation energy for creep is 140,000 J/ mol, compute the steady-state creep rate at a temperature of 250^{\\circ} C(523 K) and a stress level of 48 MPa(7000 psi).", + "answer": "the steady-state creep rate at 250^{\\circ} C and 48 MPa is 1.94 × 10^{-2} h^{-1}.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过给定的数据和公式（蠕变速率与温度、应力的关系）进行数值计算，最终得出一个具体的数值结果（1.94 × 10^{-2} h^{-1}）。解答过程涉及公式应用和数值计算，符合计算题的特征。 | 知识层次: 题目需要应用稳态蠕变速率的公式，涉及多步计算和温度、应力对蠕变速率的影响分析。虽然题目给出了激活能，但仍需理解并应用相关公式进行计算，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要理解稳态蠕变速率与温度、应力的关系，并应用阿伦尼乌斯公式进行多步计算。题目涉及多个变量（温度、应力、活化能）的综合分析，且需要正确代入和转换单位。虽然提供了正确选项，但解题过程需要较强的概念关联和计算能力。" + }, + { + "idx": 1019, + "question": "Given a certain low-carbon steel with $\\sigma_{0}=64\\mathrm{kPa}$, $K=393.7\\mathbf{k}\\mathbf{Pa}\\cdot\\mu\\mathbf{m}^{\\frac{1}{2}}$, and a grain diameter of $50\\mu\\mathrm{m}$, what is the yield strength of this low-carbon steel?", + "answer": "According to the Hall-Petch formula: $$\\sigma_{\\mathrm{s}}=\\sigma_{0}+K d^{-{\\frac{1}{2}}}=(64+393.7\\times50^{-{\\frac{1}{2}}})\\mathbf{kPa}=(64+55.68)\\mathbf{kPa}=119.7\\mathbf{kPa}$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的参数和公式（Hall-Petch公式）进行数值计算，最终得出一个具体的数值结果（yield strength）。答案展示了完整的计算过程和结果，符合计算题的特征。 | 知识层次: 题目主要考查Hall-Petch公式的直接应用和简单计算，不需要多步计算或综合分析，属于基本公式的直接套用。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了Hall-Petch公式，并提供了所有必要的参数（σ₀、K、d），只需将这些数值代入公式进行简单的数学运算即可得到答案。不需要额外的概念理解或复杂的分析步骤，属于最基础的难度级别。" + }, + { + "idx": 2279, + "question": "Calculate the critical length Lc of Al2O3 short fibers, given a diameter of 10μm, tensile strength of 2275MPa, and interfacial shear strength τy approximated by the matrix yield strength of 76MPa.", + "answer": "For Al2O3 short fibers, the critical length Lc = (10×10^-6 × 2275) / (2 × 38) = 299.3×10^-6 m = 299.3μm. Since the actual length of 4mm is greater than Lc, the fibers can achieve maximum strengthening effect.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的参数（直径、拉伸强度、界面剪切强度）进行数值计算，应用公式求出临界长度Lc，答案也是具体的计算结果。整个过程符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，即使用给定的参数和公式计算临界长度Lc。虽然需要理解临界长度的概念，但整体思维过程较为直接，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅涉及单一公式的直接应用和简单计算，即使用临界长度公式 Lc = (d × σ) / (2 × τ) 进行计算。解题步骤简单，无需多个公式组合或复杂分析，属于最基础的难度等级。" + }, + { + "idx": 2014, + "question": "The density of ZnS is $4.1~\\\\mathrm{Mg}/\\\\mathrm{m}^{3}$, calculate the distance between the centers of the two ions based on this", + "answer": "The distance between the centers of the two ions is $0.234\\\\mathrm{~n}\\\\mathrm{m}$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的密度数据进行计算，得出两个离子中心之间的距离。答案是一个具体的数值结果（0.234 nm），这表明需要通过公式和数值计算来解决问题，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括密度与晶格参数的关系推导，以及离子间距的计算，涉及概念关联和综合分析。虽然不涉及复杂的推理分析或机理解释，但比简单的公式应用要求更高。 | 难度: 在选择题中属于中等偏上难度，需要综合运用密度计算、晶体结构知识和单位换算等多步骤计算过程。题目要求考生根据密度数据反推离子间距，涉及对ZnS晶体结构的理解（如闪锌矿结构）、阿伏伽德罗常数的应用以及立方晶系几何关系的推导。虽然选择题提供了正确选项可以部分降低难度，但仍需要考生具备较强的综合分析能力和计算技巧，属于需要多概念关联的综合性计算问题。" + }, + { + "idx": 3639, + "question": "Based on the cesium chloride structure, determine the packing factor for CsBr.", + "answer": "The packing factor pf = 0.693.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于氯化铯结构计算CsBr的堆积因子，需要应用公式进行数值计算，最终给出一个具体的数值结果(0.693)。这符合计算题的特征。 | 知识层次: 题目需要基于CsCl结构进行计算，涉及多步计算和概念关联，包括晶体结构理解、原子半径计算和堆积因子的公式应用，需要综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解CsCl晶体结构的概念，掌握堆积因子的计算方法，并进行多步计算和综合分析。虽然题目给出了正确选项，但解题过程涉及离子半径的确定、晶胞体积计算以及离子体积的求和，需要较强的概念关联和计算能力。" + }, + { + "idx": 3853, + "question": "For an Fe-1.15% C alloy, determine the composition and amount of each phase present at 728 degrees C.", + "answer": "Fe3C: 6.67% C, 6.4%; gamma: 0.77% C, 93.6%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定合金中各相的组成和含量，需要应用相图和相关公式进行计算，答案给出了具体的数值结果。 | 知识层次: 题目需要应用铁碳相图进行多步计算，包括确定相组成和相对量，涉及杠杆定律的应用和相图分析，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要考生掌握铁碳相图的基本概念（如Fe3C和gamma相的组成范围），能够正确识别728°C时的相平衡条件（共析反应温度），并应用杠杆定律进行两相组成和相对量的计算。虽然题目提供了正确选项可以部分验证计算过程，但仍需要考生完成多个步骤的推导和计算，属于综合性计算问题。" + }, + { + "idx": 4895, + "question": "(b) Using this expression, compute the longitudinal modulus of elasticity of a hybrid composite consisting of aramid and glass fibers in volume fractions of 0.25 and 0.35 , respectively, within a polyester resin matrix [E_m=4.0 GPa (6x10^5 psi)].", + "answer": "the longitudinal modulus of elasticity of the hybrid composite is: e_cl = 59.7 gpa (8.67x10^6 psi)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求使用给定的表达式计算混合复合材料的纵向弹性模量，涉及数值计算和公式应用。答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目要求使用给定的表达式计算混合复合材料的纵向弹性模量，涉及基本公式的直接应用和简单计算。虽然需要理解复合材料中各组分体积分数的概念，但整体上是一个直接的数值计算过程，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接套用和简单计算能力。题目给出了所有必要的参数和明确的公式应用场景，解题步骤仅需代入数值进行计算，无需复杂的分析或组合多个公式。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4692, + "question": "(b) Repeat this calculation at room temperature (298 K). Assume an energy for vacancy formation of 0.90 eV/atom.", + "answer": "the fraction of atom sites that are vacant for copper at 298 k is 6.08 × 10^-16.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（计算空位分数），并给出了具体的计算条件和参数（温度298 K，空位形成能0.90 eV/atom）。答案是一个具体的数值结果（6.08 × 10^-16），这表明解答过程涉及公式应用和数值计算。 | 知识层次: 题目要求使用给定的能量值和温度进行简单的数值计算，直接套用公式计算空位分数，属于基本公式应用和简单计算，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式进行计算，属于最基础的难度等级。题目明确给出了所有必要参数（温度、空位形成能），只需将数值代入公式即可得出答案，无需额外的分析或组合多个公式。" + }, + { + "idx": 3749, + "question": "Suppose that solid iron was able to nucleate homogeneously with an undercooling of only 15^{\\circ} C. How many atoms would have to group together spontaneously for this to occur? Assume that the lattice parameter of the solid BCC iron is 2.92 Å.", + "answer": "7.676 × 10^{6} atoms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定过冷度下铁原子自发成核所需的原子数量。答案是一个具体的数值结果，这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括理解均相成核的概念、应用临界核尺寸公式、计算晶胞体积和原子数，并最终求解所需原子数。这需要将多个概念和公式关联起来，进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解均质成核理论、晶体结构参数、临界核尺寸计算等多个概念，并进行多步骤的综合计算。题目要求将理论公式（如临界核自由能公式）与给定参数（如晶格常数、过冷度）结合，最终推导出原子数量，涉及较复杂的数学运算和单位转换过程。" + }, + { + "idx": 2827, + "question": "Determine the engineering strain εe and true strain εT when the length increases from L to 1.1L, and explain which one better reflects the true deformation characteristics", + "answer": "εe = (1.1 - 1)L / L = 10%; εT = ln(1.1L / L) = 9.5%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求进行数值计算（工程应变和真实应变）并应用相关公式，答案以计算结果形式呈现 | 知识层次: 题目主要涉及工程应变和真实应变的基本公式应用和简单计算，不需要多步计算或综合分析，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要计算工程应变和真实应变，但两者都是直接套用基本公式（工程应变εe = ΔL/L，真实应变εT = ln(Lf/L0)），且计算过程简单。题目仅要求对两种应变进行基本计算和简单比较，不涉及复杂推导或多步骤分析，因此在选择题型内属于等级2难度。" + }, + { + "idx": 4848, + "question": "Germanium to which 10^24 m^-3 As atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the As atoms may be thought of as being ionized (i.e., one charge carrier exists for each As atom). Calculate the electrical conductivity of this material, assuming electron and hole mobilities of 0.1 and 0.05 m^2/V-s, respectively.", + "answer": "the conductivity is equal to 1.60 × 10^4 (ω·m)^-1.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解锗材料的电导率，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即通过给定的掺杂浓度和载流子迁移率直接计算电导率。虽然需要理解半导体掺杂和载流子迁移的概念，但计算过程较为直接，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求计算掺杂锗的电导率，只需应用电导率的基本公式σ = n * e * μ（其中n为载流子浓度，e为电子电荷，μ为载流子迁移率），并将给定的数值直接代入即可得到结果。无需多个公式组合或复杂分析，属于最基础的计算题。" + }, + { + "idx": 4550, + "question": "What is the magnitude of the voltage generated in the Zn/Zn2+ concentration cell with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "The magnitude of the voltage is 0.0592 v.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求计算Zn/Zn2+浓度电池的电压大小，需要使用能斯特方程等公式进行数值计算，答案是一个具体的数值结果（0.0592 v），符合计算题的特征。 | 知识层次: 题目考查的是浓度电池电压的计算，需要应用能斯特方程进行简单的数值计算，属于基本公式的直接应用，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目仅要求应用Nernst方程的基本形式来计算浓度电池的电压，且给定的浓度差异直接可代入公式得出结果，无需复杂的推导或多步骤计算。" + }, + { + "idx": 3705, + "question": "We currently can successfully perform a carburizing heat treatment at 1200^{\\circ} C in 1h. In an effort to reduce the cost of the brick lining in our furnace, we propose to reduce the carburizing temperature to 950^{\\circ} C. What time will be required to give us a similar carburizing treatment?", + "answer": "9.95 h", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在950°C下达到与1200°C相同渗碳效果所需的时间。答案是一个具体的数值（9.95 h），这表明需要通过计算得出结果。 | 知识层次: 题目需要进行多步计算，涉及热处理温度和时间的关系，需要应用扩散定律（如阿伦尼乌斯方程）进行数值计算，并综合分析温度变化对处理时间的影响。虽然不涉及复杂的机理分析或创新设计，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程（如Arrhenius方程）的应用，进行温度-时间的转换计算。题目涉及多步骤计算（包括对数运算和单位转换），并要求将热处理工艺参数关联起来综合分析。虽然提供了正确选项可以验证结果，但解题过程需要较强的概念理解和计算能力。" + }, + { + "idx": 3730, + "question": "A ceramic matrix composite contains internal flaws as large as 0.001 cm in length. The plane strain fracture toughness of the composite is 45 MPa / m and the tensile strength is 550 MPa. Will the flaw cause the composite to fail before the tensile strength is reached? Assume that f=1.", + "answer": "the applied stress required for the crack to cause failure is 11,354 MPa. the tensile strength of the composite is 550 MPa. any failure of the ceramic should be expected due to the massive overload, not because of the presence of the flaws.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算（计算裂纹导致失效所需的应力），并应用断裂力学公式（K_IC = f * σ * sqrt(πa)）。答案给出了具体的计算结果和比较过程，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括应用断裂力学公式计算临界应力，并将结果与材料的拉伸强度进行比较。虽然计算过程相对直接，但需要理解断裂韧性和裂纹尺寸之间的关系，以及如何应用这些概念来预测材料的失效行为。这超出了简单应用的范围，但尚未达到复杂分析或高级综合的层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及平面应变断裂韧性和拉伸强度的计算，需要应用断裂力学公式（K_IC = fσ√(πa)）来计算临界应力，然后将结果与给定的拉伸强度进行比较。虽然计算步骤明确，但需要综合应用多个概念并进行数值比较，属于多步骤计算和概念关联的综合分析问题。" + }, + { + "idx": 4340, + "question": "Consider 2.0 kg of a 99.6 wt % Fe-0.4 wt % C alloy that is cooled to a temperature just below the eutectoid. How many kilograms of proeutectoid ferrite form?", + "answer": "0.98 kg of proeutectoid ferrite forms.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，以确定在特定条件下形成的proeutectoid ferrite的质量。答案是一个具体的数值结果（0.98 kg），这表明解答过程涉及计算步骤。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及合金成分分析、相变温度判断以及质量分数的计算，需要综合理解和应用材料科学中的相变原理和杠杆法则。 | 难度: 在选择题中属于中等偏上难度，需要理解相图概念、进行多步计算（包括成分转换和杠杆法则应用），并综合分析冷却过程中的相变行为。虽然题目给出了正确选项，但解题过程涉及多个知识点的综合运用和较复杂的计算步骤。" + }, + { + "idx": 2672, + "question": "If the atomic fraction of Zn dissolved in a Cu crystal is 10%, what is the maximum additional atomic fraction of Sn that can be dissolved?", + "answer": "1.36=(1(100-10-x3)+2×10+4x3)/100, solving gives x3=8.67, meaning a maximum of 8.67% Sn can be additionally dissolved.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用，通过给定的原子分数和公式求解最大可溶解的Sn原子分数。答案是通过具体计算得出的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行多步计算和公式应用，涉及原子分数的计算和溶解度的理解，需要综合分析不同元素在晶体中的溶解行为，并运用数学方法求解。虽然不涉及复杂的机理分析或创新设计，但比简单的直接套用公式更复杂。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体原子分数计算的概念，并能够正确设置和求解方程。题目涉及多步计算和概念关联，需要综合分析能力来正确解答。虽然题目给出了正确选项的计算过程，但理解并应用这些步骤仍然需要一定的专业知识。" + }, + { + "idx": 3742, + "question": "A 0.25-in.-diameter copper bar is to be cold worked 63%. Find the final diameter.", + "answer": "the final diameter is 0.152 in.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解最终的直径，答案是一个具体的数值结果。 | 知识层次: 题目涉及基本的冷加工变形计算，只需要应用简单的公式和一步计算即可得出结果，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目仅需要直接应用冷加工变形的基本公式进行简单计算，无需多个步骤或公式组合。学生只需掌握单一公式并正确代入数值即可得出答案，属于最基础的难度等级。" + }, + { + "idx": 4724, + "question": "Germanium (Ge) forms a substitutional solid solution with silicon (Si). Compute the weight percent of germanium that must be added to silicon to yield an alloy that contains 2.43 × 10^{21} Ge atoms per cubic centimeter. The densities of pure \\mathrm{Ge} and \\mathrm{Si} are 5.32 and 2.33g / {cm}^{3}, respectively.", + "answer": "11.7 wt%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解需要添加的锗的重量百分比，答案是一个具体的数值结果（11.7 wt%），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括原子密度计算、质量分数转换等，并需要理解固溶体的基本概念和密度与原子数的关系。虽然不涉及复杂的推理分析，但需要综合应用多个知识点进行计算。 | 难度: 在选择题中属于中等偏上难度，需要理解固溶体、原子浓度、密度和重量百分比等多个概念，并进行多步计算和综合分析。虽然题目提供了正确选项，但解题过程涉及单位转换、原子量计算和密度应用，步骤较为复杂，属于综合性计算问题。" + }, + { + "idx": 2150, + "question": "A 20m long aluminum rod with a diameter of 14.0mm is drawn through a die with an aperture of 12.7mm. Calculate the dimensions of the aluminum rod after drawing.", + "answer": "The aluminum rod undergoes plastic deformation during drawing, but the total volume remains unchanged. Assuming the length after drawing is L, then π×(14.0/2)^2×20×10^3=π×(12.7/2)^2×L×10^3, L=24.3m.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（体积不变原理）来确定铝棒在拉伸后的尺寸，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目主要涉及基本公式的应用和简单计算，即利用体积不变原理进行单步计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及体积不变原理和几何公式的应用，但解题步骤较为直接，仅需套用单一公式并进行简单代数运算即可得出答案。不需要复杂的逻辑推理或多步骤计算，因此在选择题型内属于较低难度。" + }, + { + "idx": 97, + "question": "In the non-stoichiometric compound Fe_xO, Fe^{3+}/Fe^{2+}=0.1, find the value of x in Fe_xO.", + "answer": "Let y be the concentration of Fe^{3+}, y=0.0435. x=1-y=1-0.0435=0.9565, thus the chemical formula is Fe_0.9565O.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解非化学计量化合物Fe_xO中的x值，答案是一个具体的数值结果，解答过程涉及化学计量和电荷平衡的计算。 | 知识层次: 题目涉及非化学计量化合物的计算，需要理解Fe^{3+}/Fe^{2+}比例的概念，并进行多步计算来确定x的值。虽然计算过程不算特别复杂，但需要将概念与计算结合起来，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解非化学计量比化合物的概念，掌握Fe^{3+}/Fe^{2+}比例的计算方法，并进行多步计算才能得出最终结果。虽然题目提供了部分计算过程，但仍需要考生具备综合分析能力和化学计量关系的理解。" + }, + { + "idx": 2896, + "question": "Calculate the relative amounts (in mol%) of monoclinic ZrO2 solid solution (Monoclinic ZrO2 SS) and cubic ZrO2 solid solution (Cubic ZrO2 SS) at room temperature for a CaO–ZrO2 ceramic with w(CaO)=4%. Assume that the solubilities of monoclinic ZrO2 solid solution and cubic ZrO2 solid solution at room temperature are 2mol% CaO and 15mol% CaO, respectively.", + "answer": "Using the conversion formula between mole fraction and mass fraction, the mole fraction corresponding to w(Ca)=4% can be calculated: xA = (wA/ArA)/(wA/ArA + wB/ArB) = (4/(40+16))/(4/(40+16) + 96/(91+16×2)) ≈ 0.08; thus, 4wt% CaO = 8mol% CaO. Moreover, it can be observed from the figure that the solubility limit changes little below 900°C, yielding: monoclinic phase % = (xcub - x)/(xcub - xmono) × 100% = (15 - 8)/(15 - 2) × 100% = 53.8%; cubic phase % = (x - xmono)/(xcub - xmono) × 100% = (8 - 2)/(15 - 2) × 100% = 46.2%.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，涉及摩尔百分比的计算和相图分析，答案展示了具体的计算步骤和结果。 | 知识层次: 题目需要进行多步计算，包括摩尔分数转换和相组成计算，涉及对相图的理解和公式应用，需要综合分析不同相在特定条件下的溶解度限制。虽然不涉及复杂的机理分析或创新设计，但超出了简单应用的范围，属于中等难度的应用题目。 | 难度: 在选择题中属于中等偏上难度，需要完成多步骤计算（包括摩尔分数转换和相比例计算），同时需要理解溶解度限和相图概念。虽然题目提供了关键参数，但解题过程涉及多个公式的综合应用和逻辑推导，对考生的计算能力和概念关联能力有较高要求。" + }, + { + "idx": 4642, + "question": "Determine the expression for (E_{0}) by substitution of (r_{0}) into Equation.", + "answer": "The bonding energy (e_{0}) is given by: (e_{0}=-\frac{a}{\\left(\frac{a}{nb}\right)^{1 /(1-n)}}+\frac{b}{\\left(\frac{a}{nb}\right)^{n /(1-n)}})", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过代入公式计算得出(E_{0})的表达式，答案是一个具体的数学表达式，涉及数值计算和公式应用。 | 知识层次: 题目需要将给定的(r0)代入方程并进行多步计算来求解(E0)，涉及公式的变换和代数运算，需要一定的概念关联和综合分析能力，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念并进行多步计算和综合分析。题目要求将(r_{0})代入方程并推导出(E_{0})的表达式，涉及代数运算和指数运算，步骤较为复杂。虽然题目提供了正确选项，但理解推导过程需要一定的概念关联能力。" + }, + { + "idx": 3247, + "question": "Carburize industrial pure iron at 920°C. If the carbon concentration on the workpiece surface remains constant, i.e., w_C=1.2%, the diffusion coefficient D=1.5×10^-11 m^2/s, and carburize for 10h. If the carburized layer depth is defined as the distance from the surface to where the carbon mass fraction is 0.2%, find the carburized layer depth?", + "answer": "Substitute C_x=0.2 into the formula C_x=1.2[1-erf(6.8×10^2x)]. Referencing the error function table, Z≈6.8×10^2x=0.9784, the layer depth is x=0.00144m=1.44mm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解渗碳层深度，答案给出了具体的计算过程和数值结果。 | 知识层次: 题目涉及扩散方程的数值计算和误差函数表的应用，需要多步计算和概念关联，但不需要复杂的推理分析或创新设计。 | 难度: 在选择题中属于中等偏上难度，需要理解扩散方程的应用、误差函数的使用以及多步骤计算过程。题目要求考生能够正确代入公式并查阅误差函数表，同时进行单位换算。虽然题目提供了明确的公式和参数，但解题过程涉及多个概念的综合运用和精确计算，属于综合性计算问题。" + }, + { + "idx": 3208, + "question": "A specimen with an original gauge length of L0 is stretched to L. Determine the engineering linear strain and true linear strain during the stretching process.", + "answer": "Engineering linear strain ε = (L - L0) / L0; true linear strain e = ln(L / L0)", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过公式计算工程线性应变和真实线性应变，答案给出了具体的计算公式和结果形式，属于典型的计算题。 | 知识层次: 题目要求直接应用工程应变和真实应变的定义公式进行计算，属于基本公式的直接套用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算。虽然涉及两个不同的应变定义（工程应变和真实应变），但都是直接套用基本公式，不需要复杂的推导或组合计算。学生只需记住这两个公式并正确应用即可，解题步骤相对简单。" + }, + { + "idx": 4234, + "question": "What is the composition, in atom percent, of an alloy that consists of 97 wt% Fe and 3 wt% Si?", + "answer": "the composition of the alloy is 94.2 at% fe and 5.8 at% si.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目需要进行数值计算和公式应用（将重量百分比转换为原子百分比），答案以具体数值形式给出，符合计算题的特征。 | 知识层次: 题目需要进行多步计算，涉及原子百分比和重量百分比之间的转换，需要应用相关公式并理解其物理意义，属于中等应用层次。 | 难度: 在选择题中属于中等偏上难度，需要理解质量百分比与原子百分比之间的转换关系，涉及多步计算（包括分子量计算、摩尔数转换等），并需要综合分析合金成分的转换过程。虽然题目给出了正确选项，但解题过程仍需要较强的概念关联和计算能力。" + }, + { + "idx": 2863, + "question": "Given that the yield strength of industrial pure copper is ${\\\\pmb{\\\\sigma{s}}}=70~{\\\\bf M}{\\\\bf P}{\\\\bf a}$, its grain size is $N{\\\\mathrm{A}}=18$ per $'\\\\mathbf{m}\\\\mathbf{m}^{2}$, and when $N{\\\\mathbf{A}}=$ $\\\\bf{4025}$ per $\\\\scriptstyle{\\\\prime}{\\\\mathbf{m}\\\\mathbf{m}^{2}}$, ${\\\\pmb{\\\\sigma}}{\\\\mathsf{S}}={\\\\pmb{95}}\\\\mathbf{M}\\\\mathbf{P}{\\\\bf a}$. Calculate ${\\\\pmb\\\\sigma_{\\\\mathfrak{s}}}$ when $N{\\\\mathbf{A}}=260$ per $\\\\scriptstyle{\\\\left/{\\\\mathfrak{m m}}^{2}\\\\right.}$.", + "answer": "Let the average grain diameter be $^{d}$, and the number of grains per $\\\\scriptstyle\\\\mathtt{m m}^{2}$ be $N_{\\\\Lambda}$. It can be proven that: Thus $$d=\\\\sqrt{\\\\frac{8}{3\\\\pi N_{\\\\Lambda}}}$$$$d_{1}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times\\\\mathrm{i}8}}=0.217(\\\\mathrm{mm})$$$$d_{2}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times4025}}=1.452\\\\times10^{-2}(\\\\mathrm{mm})$$$$d_{3}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times260}}=5.714\\\\times10^{-2}(\\\\mathrm{mm})$$Substituting into the Hall-Petch formula: Solving $$\\\\left\\\\{\\\\begin{array}{l l}{{70=\\\\sigma_{0}+k(0,217\\\\times10^{-3})^{-\\\\frac{1}{2}}}}\\\\ {{95=\\\\sigma_{0}+k(1,452\\\\times10^{-5})^{-\\\\frac{1}{2}}}}\\\\end{array}\\\\right.$$$$\\\\begin{array}{r}{\\\\sigma_{0}=61,3\\\\mathrm{MPa},\\\\quad k=0,1285}\\\\end{array}$$$$\\\\sigma_{5}=61,3+0.1285\\\\times(5,714\\\\times10^{-5})^{-\\\\frac{1}{2}}=78.3(\\\\mathrm{MPa})$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch公式）来求解特定条件下的屈服强度，答案给出了详细的计算过程和最终数值结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度求解，需要理解公式中各参数的含义并进行适当的代数运算。虽然不涉及复杂的机理分析或创新设计，但计算过程较为复杂，需要一定的综合分析能力。 | 难度: 在选择题中属于中等偏上难度，题目涉及多步骤计算和概念关联。需要掌握Hall-Petch公式的应用，能够正确计算晶粒尺寸，并建立方程组求解材料常数。虽然题目提供了正确选项，但解题过程需要综合运用材料科学知识和数学计算能力，属于综合性计算问题。" + }, + { + "idx": 3848, + "question": "For an Fe-0.35% C alloy, determine the composition and amount of each phase present at 728°C.", + "answer": "α: 0.0218% C, 56.1% γ: 0.77% C, 43.9%", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算确定Fe-0.35% C合金在728°C时各相的组成和含量，需要使用相图和杠杆定律进行数值计算。答案给出了具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要应用杠杆定律进行多步计算，涉及相图分析和成分确定，需要概念关联和综合分析能力。 | 难度: 在选择题中属于中等偏上难度，需要理解铁碳相图的基本概念，能够正确识别728°C时的相组成（α和γ相），并运用杠杆定律进行计算。虽然题目给出了正确选项，但解题过程涉及多个步骤和概念的综合运用，包括相图解读、成分确定和百分比计算，这些都需要一定的材料科学基础和分析能力。" + }, + { + "idx": 2009, + "question": "Calculate the electron concentration at the solid solubility limit (mole fraction) for Cd, Zn, Sn, and Sb, given their valences are 2, 3, 4, and 5 respectively, Ag is 1, and the solid solubility limits (mole fractions) are x_Cd=42.5×10^-2, x_Zn=20×10^-2, x_Sn=12×10^-2, x_Sb=7×10^-2", + "answer": "The electron concentration at the solid solubility limit can be calculated using the formula c=Z_A(1-x_B)+Z_Bx_B. Here, Z_A and Z_B are the numbers of valence electrons for components A and B respectively; x_B is the mole fraction of component B. The electron concentration for Cd=1×(1-0.425)+2×0.425=1.43; for Zn=1×(1-0.20)+3×0.20=1.42; for Sn=1×(1-0.12)+4×0.12=1.39; for Sb=1×(1-0.07)+5×0.07=1.31.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过给定的公式和数据进行数值计算，最终得出具体的电子浓度数值。解答过程涉及公式应用和数值代入，符合计算题的特征。 | 知识层次: 题目主要涉及基本公式的直接应用和简单计算，需要理解电子浓度的计算公式并代入给定的数值进行计算，无需多步推理或综合分析。 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目要求直接套用给定的公式c=Z_A(1-x_B)+Z_Bx_B进行计算，无需额外的概念理解或复杂的解题步骤。每个元素的电子浓度计算都是独立且重复的简单算术操作，属于基础的应用题。" + }, + { + "idx": 271, + "question": "When the temperature increases from 451°C to 493°C, the rate increases by a factor of 10. Calculate the activation energy of this process. (Analyze using Table 8-2 and Figure 8-22)", + "answer": "k=c exp(-Q/RT), and since G²=kt, substituting T₁=451°C=724K, T₂=493°C=766K, G₁=G, G₂=10G, we get k₂/k₁=G₂²/G₁²=exp(-Q/RT₂)/exp(-Q/RT₁)=100. Solving for Q gives Q=RT₁T₂ln(k₂/k₁)/(T₂-T₁)=8.314×724×766×ln(100)/(766-724)=505.561×10³ J/mol.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解激活能，答案中包含了具体的计算步骤和公式推导，符合计算题的特征。 | 知识层次: 题目涉及多步计算和公式应用，需要理解阿伦尼乌斯方程并正确代入温度转换后的数值进行计算。虽然不涉及复杂的机理分析或创新设计，但需要一定的综合分析能力来关联不同概念并正确执行计算步骤。 | 难度: 在选择题中属于中等偏上难度，需要理解阿伦尼乌斯方程的应用，进行多步计算和温度单位转换，并正确代入公式求解活化能。虽然题目提供了部分解题思路，但仍需较强的综合分析能力和计算技巧。" + }, + { + "idx": 2953, + "question": "According to the relationship d²=kt and k=17.6μm²/min, find the grain diameter d after annealing for 90 minutes.", + "answer": "d = √(17.6μm²/min × 90min) = √1584μm² = 39.8μm", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的公式和参数进行数值计算，最终得出一个具体的数值结果。解答过程涉及公式应用和数学运算，符合计算题的特征。 | 知识层次: 题目仅涉及基本公式的直接套用和简单计算，无需多步推理或综合分析 | 难度: 在选择题型中，该题目属于单一公式直接计算的难度等级。题目直接给出了公式d²=kt和k的值，只需要将时间t=90min代入公式并进行简单的平方根计算即可得到答案。解题步骤非常直接，无需复杂的推理或多步骤计算，符合等级1的定义。" + }, + { + "idx": 4210, + "question": "Calculate the radius of an iridium atom, given that Ir has an FCC crystal structure, a density of 22.4g / {cm}^{3}, and an atomic weight of 192.2g / mol.", + "answer": "the radius of an iridium atom is 0.136nm.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解铱原子的半径，答案是一个具体的数值结果（0.136nm），这符合计算题的特征。 | 知识层次: 题目需要进行多步计算，包括利用FCC晶体结构的几何关系、密度和原子重量的关系，以及单位转换等综合分析步骤。虽然不涉及复杂的推理分析或创新应用，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解FCC晶体结构、密度与原子半径的关系，并进行多步计算。虽然题目给出了正确选项，但解题过程涉及单位换算、晶胞体积计算、原子半径推导等综合步骤，对概念掌握和计算能力要求较高。" + }, + { + "idx": 3138, + "question": "Determine whether the dislocation reaction $\\frac{1}{2}[111]\\rightarrow\\frac{1}{8}[110]+\\frac{1}{4}[112]+\\frac{1}{8}[110]=0.$ 110] can proceed, and why?", + "answer": "$$ \\Sigma b_{\\mathbb{H}}=\\Sigma b_{\\mathbb{E}}=\\frac{1}{2}[111]$$Thus, this dislocation reaction satisfies the geometric condition$$ x\\Sigma b_{j j}^{2}=\\frac{3}{4}>\\Sigma b_{j j}^{2}=\\frac{1+1}{64}+\\frac{1+1+4}{16}+\\frac{1+1}{64}=\\frac{7}{16} $$Therefore, it also satisfies the energy condition, so this dislocation reaction can proceed spontaneously.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算验证位错反应的能量条件是否满足，答案中包含了具体的矢量计算和能量比较，属于需要数值计算和公式应用的类型。 | 知识层次: 题目需要进行多步计算（矢量分解、能量条件验证），并需要理解位错反应的能量条件和几何条件之间的关系。虽然不涉及复杂的机理分析或创新应用，但需要综合运用位错理论和能量守恒原理进行计算和判断。 | 难度: 在选择题中属于中等偏上难度，需要理解位错反应的基本概念，进行矢量运算验证几何条件，并通过能量计算判断反应可行性。题目涉及多步骤计算和综合分析，但选项提供了关键计算步骤，降低了部分难度。" + }, + { + "idx": 168, + "question": "By adding $20\\%\\\\mathrm{B}_{2}0_{3}$ to $\\\\mathrm{Si0_{2}}$, calculate the $0:\\\\mathrm{Si}$ ratio of the melt.", + "answer": "S $\\\\frac{{\\\\cal O}}{\\\\bar{\\\\cal S}\\\\bar{\\\\imath}}=\\\\frac{1\\\\times2+0.2\\\\times3}{1+0.2\\\\times2}=1.86$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解O/Si的比例，答案是一个具体的数值结果，符合计算题的特征。 | 知识层次: 题目需要进行基本的数值计算和公式应用，涉及简单的化学计量比计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。题目要求计算O/Si比例，涉及基本化学计量和百分比添加的计算。虽然需要应用两个简单的公式（B2O3和SiO2的化学计量关系），但步骤直接且无需复杂推导。在选择题型内，这属于中等偏下难度，因为解题过程清晰且计算简单。" + }, + { + "idx": 2171, + "question": "For annealed pure iron with a grain size of $N_{\\\\mathrm{A}}=16$ grains/mm², its yield strength $\\\\sigma_{\\\\textrm{s}}=100$ MPa; when $N_{\\\\mathrm{A}}=4~096$ grains/mm², $\\\\sigma_{\\\\mathrm{s}}=250\\\\mathrm{MPa}$. Calculate $\\\\sigma_{s}$ when $N_{\\\\mathrm{A}}=250$ grains/mm².", + "answer": "Let the average grain diameter be $d$, and the number of grains per square millimeter be $N_{\\\\mathrm{A}}$. It can be proven that $$ d=\\\\sqrt{\\\\frac{8}{3\\\\pi N_{\\\\mathrm{A}}}} $$ Therefore, $$ d_{1}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times16}}=0.053\\\\mathrm{~mm} $$ $$ d_{2}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times4~096}}=2.072\\\\times10^{-4}~\\\\mathrm{mm} $$ $$ d_{3}=\\\\sqrt{\\\\frac{8}{3\\\\pi\\\\times250}}=3.395\\\\times10^{-3}\\\\mathrm{mm} $$ Substituting into the Hall-Petch formula, $$ \\\\begin{array}{l}{\\\\left\\\\{100=\\\\sigma_{0}+K(0.053)^{-1/2}\\\\right.} \\\\\\\\ {\\\\left.250=\\\\sigma_{0}+K(2.072\\\\times10^{-4})^{-1/2}\\\\right.}\\\\end{array} $$ Solving gives $$ \\\\sigma_{0}=90\\\\mathrm{MPa} $$ Therefore, when $N_{\\\\mathrm{A}}=250$ grains/mm² and $d=3.395\\\\times10^{-3}\\\\mathrm{mm}$, $$ \\\\sigma_{\\\\mathrm{s}}=90+2.303\\\\times(3.395\\\\times10^{-3})^{-1/2}=129.5~\\\\mathrm{MPa} $$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Hall-Petch公式）来求解特定条件下的屈服强度，答案包含详细的数学推导和计算结果。 | 知识层次: 题目需要应用Hall-Petch公式进行多步计算，涉及不同晶粒尺寸下的屈服强度计算，需要理解公式中各参数的含义并进行数值求解。虽然不涉及复杂的机理分析或创新应用，但需要一定的综合分析能力和计算技巧。 | 难度: 在选择题中属于中等偏上难度，需要理解Hall-Petch公式并正确应用，涉及多步计算和变量求解。虽然题目提供了部分计算过程，但需要考生掌握晶粒尺寸与屈服强度的关系，并能正确代入公式求解。此外，还需要解二元一次方程组来求得材料常数，最后再进行一次公式应用计算目标值。这些步骤在选择题型中属于较为复杂的计算过程。" + }, + { + "idx": 2683, + "question": "A solid solution contains x(MgO) at 30% and x(LiF) at 70%. If the density of MgO is 3.6 g/cm3 and the density of LiF is 2.6 g/cm3, what is the density of this solid solution?", + "answer": "The density of the solid solution ρ = 0.3 × 3.6 + 0.7 × 2.6 = 2.9 g/cm3", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来求解固溶体的密度，答案是一个具体的数值计算结果。 | 知识层次: 题目涉及基本公式的直接应用和简单计算，仅需将给定的摩尔分数和密度数据进行加权平均即可得出结果，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目仅需要直接套用单一公式（密度加权平均公式）进行计算，无需额外的概念理解或步骤组合。解题过程简单直接，属于最基础的难度等级。" + }, + { + "idx": 2243, + "question": "The carbon in iron, c0=wC=0.0001, E=-0.5 eV, calculate the critical temperature for solute segregation.", + "answer": "c=c0exp(-E/kT), when complete solute segregation occurs, c=wx=1, T=T∥s, 1=c0exp(-E/kT), then T∥⊥=-E/kln(1/c0). Substituting c0=wC=0.0001, E=-0.5 eV=-1.602×10^-19×0.5 J, T∥∥=(1.602×10^-19×0.5)/(1.381×10^-23×ln(1/0.0001))=629 K.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求进行数值计算和公式应用，解答过程中涉及代入数值、使用公式和最终得出计算结果。 | 知识层次: 题目需要进行多步计算，包括公式的变形和数值代入，同时需要理解溶质偏析的临界温度概念，并正确应用相关公式进行计算。虽然不涉及复杂的综合分析或机理解释，但需要一定的概念关联和计算能力。 | 难度: 在选择题中属于中等偏上难度，需要理解多个概念（如溶质偏聚、临界温度计算）并进行多步计算（包括指数运算、单位转换和代数求解）。虽然题目提供了正确选项的推导过程，但仍要求考生能够综合运用物理化学知识，正确代入数值并执行计算步骤。" + }, + { + "idx": 3600, + "question": "Beryllium has a hexagonal crystal structure, with a0=0.22858 nm and c0=0.35842 nm. The atomic radius is 0.1143 nm, the density is 1.848 g/cm3, and the atomic weight is 9.01 g/mol. Determine the number of atoms in each unit cell.", + "answer": "2 atoms/cell.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用来确定每个晶胞中的原子数，答案是一个具体的数值结果（2 atoms/cell），这符合计算题的特征。 | 知识层次: 题目需要应用基本的晶体结构参数（晶格常数、原子半径）和密度公式进行计算，属于直接套用公式和简单计算的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，需要考生掌握基本的晶体结构参数和密度计算公式，并进行简单的数值代入和计算。虽然涉及多个参数（a0, c0, 原子半径, 密度, 原子量），但解题步骤较为直接，主要是套用六方晶系的原子数计算公式，不需要复杂的推导或分析。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3756, + "question": "A 2-in. cube solidifies in 4.6 min. Calculate (a) the mold constant in Chvorinov's rule. Assume that n=2.", + "answer": "the mold constant in chvorinov's rule is 41.48 min/in^2.", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过数值计算和公式应用（Chvorinov's rule）来求解模具常数，答案是一个具体的数值结果（41.48 min/in^2），符合计算题的特征。 | 知识层次: 题目要求直接套用Chvorinov's rule公式进行计算，属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目仅需要直接套用Chvorinov's rule的基本公式进行计算，属于单一公式直接计算的简单应用。解题步骤简单，仅需代入已知数值进行简单运算即可得出答案，无需复杂的分析或组合多个公式。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2371, + "question": "According to the $F E=F e=C$ phase diagram, calculate the relative amounts of phases in an iron-carbon alloy at room temperature under equilibrium conditions, where the mass fraction of carbon is $0.14$.", + "answer": "At room temperature, the equilibrium phases of the iron-carbon alloy are $\\alpha$-Fe (the mass fraction of carbon is $0.008$) and $Fe_3C$ (the mass fraction of carbon is $6.67$). Therefore, for an alloy with a mass fraction of carbon of $0.14$ at room temperature under equilibrium conditions, the relative amounts (mass fractions) of the $\\alpha$-Fe phase and the $Fe_3C$ phase are: $$ A^{\\alpha}=\\frac{6.67-0.14}{6.67-0.008}=98.62\\% \\qquad A^{Fe_3C}=1-98.62\\%=1.38\\%$$", + "question_type": "calculation", + "question_type_name": "计算题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据给定的铁碳相图计算特定成分合金在室温下的相组成比例，解答过程涉及数值计算和杠杆定律的应用，答案以具体数值形式呈现。 | 知识层次: 题目主要考查对铁碳相图的基本理解和杠杆定律的简单应用，涉及单一条件下的质量分数计算，属于基本公式的直接套用和简单计算。 | 难度: 在选择题型中，该题目属于简单公式应用计算难度。虽然需要理解铁碳相图的基本概念和杠杆定律的应用，但解题步骤相对直接，仅需套用一个公式进行计算。相比单一公式直接计算的题目（等级1），该题需要稍多的理解，但相比需要多个公式组合的题目（等级3）仍较为简单。" + }, + { + "idx": 2210, + "question": "Design an experimental method to determine the variation of recrystallization nucleation rate $\\dot{N}$ with time at a certain temperature (T).", + "answer": "The recrystallization nucleation rate $\\dot{N}$ can be determined using the metallographic method. Specific steps: Heat a batch of specimens deformed with a large strain to a certain temperature (T) and hold, then quench one specimen at regular time intervals t. Observe the prepared metallographic samples under a microscope and count the number of recrystallization nuclei N. After obtaining a set of data (several points), plot an N-t graph. The slope at each point on the N-t curve represents the recrystallization nucleation rate $\\dot{N}$ of the material at temperature T for different holding times.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计实验方法并详细描述步骤，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求设计一个实验方法来测定再结晶形核速率随时间的变化，这需要综合运用材料科学中的再结晶理论、实验设计和数据分析等多方面知识。实验步骤涉及热处理、金相观察、数据收集和曲线绘制等多个环节，需要深入理解再结晶过程的机理，并能将理论知识转化为具体的实验方案。此外，还需要对实验结果进行分析和解释，以确定形核速率的变化规律。整个过程体现了创新应用、深度理解和设计优化的能力。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2211, + "question": "Design an experimental method to determine the variation of growth linear velocity G with time at a certain temperature (T).", + "answer": "The growth linear velocity G can be determined using the metallographic method. Specific steps: Perform metallographic observation on a set of quenched samples from the nucleation rate experiment, measure the linear dimension D of the largest nucleus in each sample (representing different holding times), plot a D-t graph, and the slope at each point on the D-t curve represents the growth linear velocity G at temperature T for different holding times.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计一个实验方法，并详细描述实验步骤和数据处理过程，这需要文字解释和论述，属于简答题类型。 | 知识层次: 题目要求设计实验方法来确定生长线性速度G随时间的变化，这需要综合运用材料科学知识、实验设计和数据分析能力。涉及多步骤的实验操作、数据收集和解释，以及对生长动力学的深入理解。这属于高级综合层次，需要创新应用和设计优化。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握材料科学中的基本概念（如生长线性速度、金相观察方法），还需要具备创新应用能力来设计实验步骤（如淬火样品处理、最大晶核尺寸测量、D-t曲线绘制与斜率分析）。解题过程涉及多步骤综合操作和深度理解温度T对生长速度G的动态影响机制，远超常规选择题对知识点简单识记或单一概念应用的要求。" + }, + { + "idx": 2215, + "question": "Point out the unreasonable aspects of the above process and formulate a reasonable grain refinement process", + "answer": "Under the condition of 80% deformation, annealing at 150°C for 1h can refine its grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "advanced_synthesis", + "knowledge_level_name": "高级综合", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出不合理之处并提出合理的晶粒细化工艺，需要文字解释和论述，答案也给出了具体的工艺条件说明，符合简答题的特征。 | 知识层次: 题目要求指出不合理之处并设计合理的晶粒细化工艺，需要综合运用材料科学知识进行深度分析和优化设计，涉及对工艺参数的理解、材料行为的预测以及创新性的工艺方案制定。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握材料科学中关于晶粒细化的基本原理，还需要具备创新应用和设计优化的能力。正确选项涉及具体的工艺参数（80%变形量、150°C退火1小时），这需要考生对材料加工工艺有深入理解，并能将这些知识应用于实际问题的解决。此外，题目要求指出不合理之处并制定合理的晶粒细化工艺，这需要综合运用多个知识点并进行创造性思考，远超一般选择题的认知要求。" + }, + { + "idx": 2257, + "question": "What is the main difference between precipitation decomposition and spinodal decomposition in the formation of precipitated phases?", + "answer": "The main difference between the two in the formation of precipitated phases lies in the nucleation driving force and the compositional change of the new phase. During precipitation transformation, the formation of the new phase requires significant concentration fluctuations, and the composition of the new phase changes abruptly compared to the parent phase, resulting in interfacial energy. This necessitates a larger nucleation driving force to overcome the interfacial energy, meaning a greater degree of undercooling is required. In contrast, spinodal decomposition does not involve a nucleation process or abrupt compositional changes; any small concentration fluctuation can lead to the formation and growth of the new phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种分解过程的主要区别，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求对两种分解机制在析出相形成过程中的差异进行深入分析和比较，涉及成核驱动力、成分变化、界面能等机理层面的解释，需要综合运用相关概念并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解两种分解机制（沉淀分解和旋节分解）在形成析出相时的核心差异，包括成核驱动力和新相成分变化的机理。正确选项涉及复杂的热力学和动力学概念，需要综合运用材料科学原理进行推理分析。考生必须掌握浓度波动、界面能、过冷度等专业概念，并能区分成核生长与连续分解的本质区别。这种机理深度解释和复杂现象全面分析的要求，远超一般选择题的知识点记忆层面，属于选择题型中的顶尖认知负荷题目。" + }, + { + "idx": 3174, + "question": "Given that the dislocation line Φt of a newly formed Frank partial dislocation lies on the (111) plane, with b = a/3 [111] perpendicular to the (111) plane, explain why this dislocation is a sessile dislocation.", + "answer": "The plane determined by b and t is certainly not the close-packed plane of the face-centered cubic structure, hence this dislocation cannot glide and is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来说明为什么给定的Frank partial dislocation是一个sessile dislocation，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目要求解释为什么Frank部分位错是固定位错，需要理解位错的性质、滑移面与柏氏矢量的关系，以及面心立方结构中的密排面特性。这涉及多个概念的关联和综合分析，需要推理和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1716, + "question": "Talk about your understanding of high-strength materials.", + "answer": "For structural materials, one of the most important performance indicators is strength. Strength refers to a material's ability to resist deformation and fracture. Improving the strength of a material can save materials and reduce costs. When utilizing the mechanical properties of materials, people always hope that the materials used have sufficient strength. They aim to reasonably apply and develop material strengthening methods to tap into the potential of material performance. Theoretically, there are two approaches to increasing the strength of metal materials: one is to completely eliminate internal dislocations and other defects, bringing its strength close to the theoretical strength. Although it is currently possible to produce high-strength metal whiskers without dislocations, practical applications remain challenging because the high strength obtained this way is unstable, highly sensitive to operational effects and surface conditions, and the strength drops significantly once dislocations occur. Therefore, in production practice, the primary approach to strengthening metals is to introduce a large number of defects to hinder dislocation movement. For example, common strengthening methods for metal materials include solid solution strengthening, grain refinement strengthening, second-phase particle strengthening, and deformation strengthening. By comprehensively applying these strengthening methods, it is possible to approach the theoretical strength from another perspective. For instance, in iron and titanium, up to 38% of the theoretical strength can be achieved. Some new high-strength aluminum alloys, such as Al-Li alloys, Al-Cu-Mg series alloys, Al-Zn-Mg series alloys, high-Zn-content Al-Zn-Mg alloys, Al-Mg-Sc series alloys, Al-Zn-Mg-Sc series alloys, and aluminum matrix composites, have achieved high strength and other comprehensive properties through various strengthening methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对高强材料进行理解和论述，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求对高强材料进行深入理解和论述，涉及多种强化方法的综合运用、理论强度与实际应用的对比分析，以及具体合金体系的性能优化。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对高强材料的理解进行全面分析，涉及多种强化方法的综合运用、理论强度的概念、实际应用中的限制条件等复杂知识点。正确选项不仅需要掌握材料强度的基本定义，还需要理解金属材料强化的多种机理（如固溶强化、晶粒细化强化等），并能分析不同强化方法的实际应用效果和理论限制。这种深度和广度的知识要求在选择题型中属于最复杂的分析层次，需要考生具备综合运用和推理分析的能力。" + }, + { + "idx": 1493, + "question": "Explain the characteristics of the recrystallization process during heating of cold-deformed metals", + "answer": "The microstructure undergoes changes, transforming from elongated grains due to cold deformation into new equiaxed grains. Mechanical properties change drastically, with strength and hardness sharply decreasing and plasticity increasing, returning to the state before deformation. The stored energy from deformation is fully released during recrystallization, eliminating the three types of stresses (lattice distortion) and reducing dislocation density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释冷变形金属加热过程中再结晶过程的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释冷变形金属加热过程中再结晶过程的特性，涉及微观结构变化、机械性能变化、储存能量释放等多个方面的综合分析。需要理解再结晶的机理，并能关联不同现象（如晶粒形状变化、位错密度变化、应力消除等）之间的内在联系。这属于对材料科学中相变和变形机理的深入理解和综合分析，超出了基础概念记忆和简单应用的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生全面理解冷变形金属再结晶过程的微观结构变化、力学性能转变以及能量释放机制。正确选项不仅需要掌握多个复杂概念（如晶粒形态转变、位错密度变化、变形储能释放），还需要将这些概念整合成一个连贯的机理解释。这种题目在选择题中属于需要深度分析和综合判断的类型，远超简单记忆或单一概念应用的难度水平。" + }, + { + "idx": 300, + "question": "What are the differences and similarities between spinodal decomposition and precipitation decomposition?", + "answer": "Spinodal decomposition involves the segregation through diffusion, decomposing a single solid solution into two solid solutions with the same structure as the parent phase but different compositions. Precipitation decomposition is the process of precipitating a second phase from a supersaturated solid solution. Their main differences are as follows: (1) Spinodal decomposition belongs to continuous phase transformation. It is a solid-state phase transformation without a thermodynamic energy barrier or nucleation. Precipitation decomposition is a nucleation-growth type phase transformation, with a thermodynamic energy barrier and a nucleation process. (2) In the early stages of spinodal decomposition, compositional fluctuations within the parent phase are gradually established, and the compositions of the two phases change continuously over time following a sinusoidal distribution pattern, eventually reaching the equilibrium phase composition. Once the nucleus of precipitation decomposition forms in the parent phase, its composition is that of the equilibrium phase, with little subsequent change. (3) Spinodal decomposition occurs uniformly in the parent phase; precipitation nuclei generally form at crystal defects. (4) The amplification process in spinodal decomposition occurs through uphill diffusion. The formation of precipitate nuclei occurs through downhill diffusion. (5) The two segregated regions in spinodal decomposition have an indistinct coherent interface. The precipitate phase and the parent phase have a distinct interface. (6) The microstructure of spinodal decomposition is regular, while that of precipitation decomposition is less uniform. Similarity: Both proceed through solute diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种分解过程的区别和相似之处，需要详细的文字论述和比较，符合简答题的特征。答案提供了详细的解释和对比，没有涉及选择、判断或计算。 | 知识层次: 题目要求对两种分解过程进行详细的比较和相似性分析，涉及多个方面的差异和共同点，需要深入理解和综合分析材料科学中的相变机制和扩散过程。这不仅需要记忆基本概念，还需要对相关原理进行推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面理解和分析两种复杂的材料分解机制（spinodal decomposition和precipitation decomposition），包括它们的差异（6个方面）和相似性（1个方面）。这需要考生：" + }, + { + "idx": 2874, + "question": "Explain how the following factors affect $G_{0},N_{0},Q_{8}$, and $Q_{n}$: degree of pre-deformation; original grain size; metal purity.", + "answer": "The driving force for primary recrystallization is the distortion energy of the crystal after deformation. The transition of the crystal from the high-energy state after distortion to the low-energy state of annealing is a spontaneous trend. However, this change in energy state requires atoms to overcome a potential barrier $\\\\Delta E$, the height of which depends on the lattice distortion energy after deformation. When the distortion energy is high, $\\\\Delta E$ decreases, and the nucleation and growth activation energies $\\\\mathbf{Q}_{\\\\mathfrak{n}}, \\\\mathbf{Q}_{\\\\mathfrak{g}}$ both decrease, thereby accelerating the recrystallization rate. Therefore, all factors affecting the distortion energy after deformation will influence $\\\\mathbf{Q}_{\\\\mathbf{n}}, \\\\mathbf{Q}_{\\\\mathbf{\\\\tilde{g}}}$, and $T_{\\\\mathsf{R}}$. From the above analysis, within a certain range of deformation, the higher the degree of pre-deformation and the finer the original grain size, the greater the distortion energy after deformation, and the lower $Q_{\\\\mathfrak{n}}, Q_{\\\\mathfrak{g}}$ will be. The effect of metal purity on $\\\\mathbf{Q}_{\\\\mathrm{n}}, \\\\mathbf{Q}_{\\\\mathrm{g}}$ can be considered from two aspects. On one hand, impurities increase the distortion energy, reducing $Q_{\\\\mathrm{n}}$ and $\\\\mathbf{Q}_{\\\\mathrm{g}}$. On the other hand, impurities also hinder interface migration, increasing $\\\\mathbf{\\\\hat{Q}}_{\\\\mathrm{n}}, \\\\mathbf{\\\\hat{Q}}_{\\\\mathrm{g}}$. These two opposing effects coexist, and the dominant one determines the outcome. $\\\\aleph_{\\\\mathfrak{g}}\\\\mathrm{G}_{\\\\mathfrak{o}}$ is only related to the intrinsic nature of the metal and is not significantly affected by the degree of pre-deformation, original grain size, or metal purity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个因素对材料科学中特定参数的影响，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求解释多个因素（预变形程度、原始晶粒尺寸、金属纯度）对再结晶过程中关键参数（G0、N0、Q8、Qn）的影响机制，涉及变形能、激活能等概念的关联分析，需要综合运用材料科学原理进行推理和解释，思维过程较为深入和复杂。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用多个材料科学概念（如变形能、再结晶驱动力、激活能等），并进行复杂的机理分析和推理。正确选项不仅需要理解各因素（预变形程度、原始晶粒尺寸、金属纯度）对变形能的影响，还需要分析这些因素如何通过改变激活能（Qn, Qg）来影响再结晶过程。此外，题目还涉及金属纯度对激活能的双重影响机制（降低变形能 vs 阻碍界面迁移），这需要考生具备深入的材料科学机理知识和综合分析能力。在选择题型中，这种需要多维度推理和复杂机理解释的题目属于最难的一类。" + }, + { + "idx": 1547, + "question": "Using Al-4.5%Cu alloy as an example, explain the microstructural transformation during 130% aging", + "answer": "After quenching, the aluminum alloy forms a supersaturated solid solution. Subsequent heating and holding will cause the sequential precipitation of GP zones, θ′′, θ′, and θ phases within the solid solution. Among these, α and θ are equilibrium phases; GP zones, θ′′, and θ′ are metastable phases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金在130%时效过程中的微观结构转变，需要详细的文字描述和论述，而不是选择、判断或计算。答案提供了详细的相变过程描述，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金在130%时效过程中的微观结构转变，涉及多个相变阶段（GP区、θ′′、θ′和θ相）的形成和演变，需要综合运用材料科学中的相变理论、热力学和动力学知识，进行机理分析和推理。这超出了简单记忆或基本应用的范围，属于对复杂过程的深入理解和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2226, + "question": "Why do metallic materials exhibit better mechanical properties after hot working compared to the as-cast state?", + "answer": "During hot working, metallic materials undergo dynamic deformation, dynamic recovery, and recrystallization processes. The columnar crystal zones and coarse equiaxed crystal zones disappear and are replaced by finer equiaxed grains. Many dispersed shrinkage pores and microcracks in the original ingot vanish due to mechanical welding effects, and microsegregation is also reduced to some extent through compression and diffusion. Consequently, the material's density and mechanical properties (especially plasticity and toughness) are improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么金属材料在热加工后比铸态具有更好的机械性能，答案提供了详细的文字解释和论述过程，符合简答题的特征。 | 知识层次: 题目要求解释金属材料在热加工后机械性能改善的机理，涉及动态变形、动态回复和再结晶等多个过程，需要综合分析材料微观结构变化与宏观性能之间的关系，属于复杂分析和机理解释的范畴。 | 难度: 在选择题中属于最高难度等级，需要深入理解金属材料热加工过程中的动态变形、动态回复和再结晶等复杂现象，并能综合解释这些过程如何改善材料的机械性能。题目要求考生不仅掌握基本概念，还需要进行机理深度解释和复杂现象全面分析，属于选择题型中对知识掌握深度和综合分析能力要求最高的类型。" + }, + { + "idx": 4433, + "question": "Would you expect Frenkel defects for anions to exist in ionic ceramics in relatively large concentrations? Why or why not?", + "answer": "Frenkel defects for anions would not exist in appreciable concentrations because the anion is quite large and is highly unlikely to exist as an interstitial.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Frenkel defects for anions在离子陶瓷中不会大量存在，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对Frenkel缺陷在离子陶瓷中的存在情况进行解释，涉及对离子尺寸和晶体结构缺陷的综合分析，需要理解缺陷形成的机理和影响因素，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解Frenkel缺陷的基本概念，还需要深入掌握离子陶瓷中阴离子的特性（如尺寸较大），并能够进行复杂的推理分析。正确选项涉及对材料微观结构和缺陷形成机理的全面理解，需要考生综合运用多个知识点（如离子半径、间隙位置、缺陷形成能等）才能得出正确结论。这种在选择题中要求机理深度解释和复杂现象全面分析的题目，对考生的知识掌握深度和综合分析能力提出了很高要求。" + }, + { + "idx": 243, + "question": "The batching of high-alumina cement is usually selected within the range of the CA phase region, and it is often produced by firing to melting and then cooling. The main mineral of high-alumina cement is CA, and C2AS has no hydraulic properties, so it is desirable that the cement does not contain C2AS. Therefore, what range of batching should be chosen within the CA phase region, and why (note that complete equilibrium cannot be achieved during production, and independent crystallization processes may occur)?", + "answer": "High-alumina cement has the characteristic of rapid hardening and is widely used in the defense industry. The batching range is Al2O3 35%~55%, CaO 35%~45%, SiO2 5%~10%, Fe2O3 0~15%. This can prevent the formation of C2AS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么选择特定的配料范围，并需要文字论述来支持答案，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求分析高铝水泥配料范围的选择原因，涉及矿物相的形成条件、生产工艺的限制（无法达到完全平衡）以及独立结晶过程的影响。这需要综合运用材料科学知识，进行推理分析，解释为什么特定的配料范围可以防止C2AS的形成，属于复杂分析层次。 | 难度: 在选择题中属于最高难度，需要综合运用材料科学知识进行复杂分析。题目涉及高铝水泥的配料范围选择、矿物相平衡、生产工艺限制（非完全平衡状态）等多重因素，要求考生不仅掌握CA相区的理论基础，还要理解C2AS相的水硬性缺失机理，并能根据生产实际条件推导出最优配料比例。正确选项的确定需要完成从相图分析到工业应用的完整推理链条，远超单纯记忆性知识的考查范畴。" + }, + { + "idx": 2178, + "question": "For face-centered cubic crystals, it is generally required to have five independent slip systems for slip to occur. Is this conclusion correct? Please explain the reason and the conditions under which this conclusion applies.", + "answer": "This conclusion is correct. Because generally, representing a deformation requires nine strain components, i.e., $$ \\\\mathfrak{\\\\varepsilon}_{i j}=\\\\left|\\\\begin{array}{l l l}{\\\\varepsilon_{x x}}&{\\\\mathfrak{\\\\varepsilon}_{x y}}&{\\\\mathfrak{\\\\varepsilon}_{x z}}\\\\\\\\{\\\\mathfrak{\\\\varepsilon}_{y y}}&{\\\\mathfrak{\\\\varepsilon}_{y x}}&{\\\\mathfrak{\\\\varepsilon}_{y z}}\\\\\\\\{\\\\mathfrak{\\\\varepsilon}_{z z}}&{\\\\mathfrak{\\\\varepsilon}_{z x}}&{\\\\mathfrak{\\\\varepsilon}_{z y}}\\\\end{array}\\\\right| $$ but $\\\\varepsilon_{x y}=\\\\varepsilon_{y x}, \\\\varepsilon_{y z}=\\\\varepsilon_{z y}, \\\\varepsilon_{z x}=\\\\varepsilon_{x z}$; thus, there are only six components left. Since the deformation is required to be uniform and continuous, the volume remains unchanged before and after deformation, i.e., $\\\\Delta V{=}_{\\\\epsilon_{x x}}+\\\\epsilon_{y y}+\\\\epsilon_{z z}{=}0$. With this constraint, there are only five independent strain components. Each independent strain component is generated by an independent slip system; therefore, five independent slip systems are needed to produce five independent strain components. When applying this conclusion, attention must be paid to the size of the crystal. The volume cannot be too small; it must be larger than the spacing between slip bands so that the plastic deformation can be considered uniform. However, the volume cannot be too large either; it must remain within the range of linear plastic deformation, such as not exceeding the size of a single grain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结论的正确性及其适用条件，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释面心立方晶体需要五个独立滑移系统的原因，还需要分析该结论适用的条件。这涉及到对晶体塑性变形机制的深入理解，包括应变张量的分析、体积不变条件的应用，以及晶体尺寸对变形均匀性的影响。需要综合运用多个概念进行推理分析，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3260, + "question": "A factory was conducting solution treatment on the jaw plates of a crusher made of high manganese steel. After heating at 1100°C, the plates were suspended with cold-drawn steel wires and transported by a crane to the quenching water tank. During transportation, the steel wire suddenly broke. This wire was new and had no defects. Analyze the cause of the steel wire fracture.", + "answer": "Due to work hardening, the cold-drawn steel wire has high strength and strong load-bearing capacity. However, when heated by the red-hot jaw plate, once the temperature rises above $T_{\\overrightarrow{\\mathbb{H}}}$, recrystallization occurs, causing a decrease in strength. As a result, the wire can no longer bear the weight of the jaw plate, leading to fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢线断裂的原因，答案提供了详细的文字解释和论述，涉及材料科学中的工作硬化和再结晶现象，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要综合运用材料科学中的相变、热处理和力学性能等知识，分析冷拉钢丝在高温条件下的性能变化及其断裂原因。涉及多个概念的关联和推理分析，思维过程较为深入。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4376, + "question": "Briefly explain why fine pearlite is harder and stronger than coarse pearlite, which in turn is harder and stronger than spheroidite.", + "answer": "The hardness and strength of iron-carbon alloys that have microstructures consisting of \\alpha-ferrite and cementite phases depend on the boundary area between the two phases. The greater this area, the harder and stronger the alloy inasmuch as (1) these boundaries impede the motion of dislocations, and (2) the cementite phase restricts the deformation of the ferrite phase in regions adjacent to the phase boundaries. Fine pearlite is harder and stronger than coarse pearlite because the alternating ferrite-cementite layers are thinner for fine, and therefore, there is more phase boundary area. The phase boundary area between the sphere-like cementite particles and the ferrite matrix is less in spheroidite than for the alternating layered microstructure found in coarse pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释为什么细珠光体比粗珠光体更硬更强，而粗珠光体又比球化体更硬更强。答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释不同微观结构（细珠光体、粗珠光体和球化体）对材料硬度和强度的影响机制，涉及相界面对位错运动的阻碍作用以及渗碳体相限制铁素体相变形的机理。这需要综合运用材料科学中的相变、位错理论和强化机制等知识，进行深入的推理和分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 500, + "question": "What effect will this dislocation reaction have on the plastic deformation of the metal?", + "answer": "The dislocation reaction generates a sessile dislocation $\\pmb{a}/2$ [110], which will hinder the movement of dislocations on the (111) and (111) planes, resulting in significant strain hardening macroscopically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应对金属塑性变形的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错反应对金属塑性变形的影响，涉及到位错运动的阻碍机制和宏观应变硬化现象的解释。这需要综合运用位错理论、晶体塑性变形机制等多方面知识，并进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解位错反应的基本概念，还需要能够分析位错反应对金属塑性变形的影响机制。正确选项涉及到位错运动的阻碍作用及其宏观表现（应变硬化），这需要考生具备综合运用知识、推理分析和机理解释的能力。此外，题目还要求考生能够将微观的位错行为与宏观的力学性能变化联系起来，这种跨尺度的综合分析在选择题型中属于最复杂的考查形式。" + }, + { + "idx": 2481, + "question": "Demonstrate why there are no fewer than 14 Bravais lattices", + "answer": "For any one of the 14 lattices, it is impossible to find a method of connecting nodes to form a new unit cell while preserving the symmetry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来证明为什么存在不少于14种布拉维格子，答案提供了详细的解释而非选择、判断或计算。 | 知识层次: 题目要求解释14种Bravais晶格存在的必然性，这需要深入理解晶体对称性和空间群的概念，并能够进行逻辑推理和分析。这不仅仅是记忆或简单应用，而是需要对晶体学原理有较深的理解和综合分析能力。 | 难度: 在选择题型内，该题目属于最高难度等级。正确选项要求考生不仅掌握14种布拉维晶格的基本概念，还需要深入理解晶格对称性和单元晶胞构建的复杂机理。题目涉及对晶体学对称操作（如旋转、反射、平移）的综合运用，以及通过推理分析证明\"无法通过节点连接形成新单元晶胞\"这一抽象结论。这种在选择题中要求对复杂现象进行全面分析的能力，远超单纯记忆或简单应用层面，属于材料科学晶体学领域的顶级认知要求。" + }, + { + "idx": 1151, + "question": "What effect does constitutional supercooling have on crystal growth morphology?", + "answer": "During the crystallization of solid solutions, constitutional supercooling significantly influences the morphology of crystal growth, leading to the formation of cellular structures or even dendritic crystals even under a positive temperature gradient. Specifically, without constitutional supercooling, the interface advances in a planar manner; with slight constitutional supercooling, the interface becomes cellular; and with substantial constitutional supercooling, the interface turns dendritic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释 constitutional supercooling 对晶体生长形态的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对constitutional supercooling对晶体生长形态影响的深入分析和解释，需要综合运用相关概念和机理，理解不同条件下的界面形态变化，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目涉及复杂的材料科学机理（成分过冷对晶体生长形貌的影响），要求考生不仅理解成分过冷的概念，还需要掌握其对晶体生长界面形貌（平面状→胞状→枝晶状）的渐进影响机制。正确选项包含三个层次的分析（无成分过冷、轻微成分过冷、显著成分过冷），需要综合运用相变动力学和扩散理论进行推理判断，完全符合\"复杂现象全面分析\"的知识层次要求。在选择题型中，这种需要多维度机理解释和现象分析的题目属于最难的类别。" + }, + { + "idx": 1264, + "question": "What is a twin crystal? Explain its formation mechanism.", + "answer": "A twin crystal refers to two crystals (or two parts of one crystal) forming a mirror-symmetric orientation relationship along a common crystal plane, and these two parts are called twin crystals. The formation of twin crystals is due to uniform shear occurring throughout the twin region during twinning deformation, where the relative displacement of each crystal layer is caused by the movement of a partial dislocation. Taking face-centered cubic crystals as an example, the formation of twin crystals requires the generation of stacking faults. For instance, face-centered cubic crystals are stacked in the order of ABCABC··· on the 111 plane, which can be represented as △△△△△⋯. If the stacking sequence is reversed starting from a certain layer, becoming ABCACBACBA·.……., i.e., △△△∇∇∇∇⋯, the upper and lower parts of the crystal form a mirror-symmetric twin relationship. It can be observed that the ···CAC part corresponds to a stacking fault, followed by stacking in the reversed order, which still belongs to the normal FCC stacking sequence but is exactly opposite to the sequence of the crystal part before the fault, thus forming a symmetric relationship. This process is caused by the movement of a partial dislocation (Shockley partial dislocation).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释双晶的定义及其形成机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释孪晶的定义（基础概念），还需要详细阐述其形成机制，包括剪切变形、部分位错运动以及堆垛顺序变化等复杂过程。这需要深入理解晶体结构、位错理论和变形机制，并进行综合分析，属于对知识的深度理解和复杂应用。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解并解释双晶的形成机制，涉及复杂的晶体学概念（如堆垛顺序、部分位错运动）和对称性关系。正确选项不仅需要识别双晶的定义，还需详细描述面心立方晶体中通过堆垛层错和部分位错运动形成镜像对称的完整机理过程。这种综合运用晶体缺陷理论和空间想象力的题目，在选择题中属于对知识深度和推理能力要求极高的类型。" + }, + { + "idx": 2591, + "question": "When the crystal around an edge dislocation contains vacancies below the equilibrium concentration, how will the dislocation climb?", + "answer": "Negative climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错攀移的行为，需要文字论述而非选择或判断，答案\"Negative climb\"是一个简短的术语解释而非计算结果 | 知识层次: 题目要求理解空位浓度与位错攀移之间的关系，并分析在特定条件下（空位浓度低于平衡浓度）位错攀移的方向。这需要综合运用位错理论、扩散机制和热力学知识，进行推理分析和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 3097, + "question": "Through what means can the performance of composite materials be further improved and their application scope expanded?", + "answer": "Composite materials refer to multiphase materials artificially synthesized from two or more materials with different properties through various process methods. Composite materials not only retain the optimal characteristics of their constituent materials but also possess new properties resulting from their combination. For example, the fracture energy of glass fiber is only 7.5×10^-2J, while that of commonly used resin is about 2.26×10^-2J. However, the composite material composed of glass fiber and thermosetting resin, known as thermosetting fiberglass, has a fracture energy as high as 17.6J, with its strength significantly higher than that of resin and its brittleness much lower than that of glass fiber. It is evident that 'compositing' has become an important means to improve material performance. Therefore, composite materials are attracting increasing attention, and the development and application of new composite materials are becoming more widespread.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何提高复合材料性能并扩大其应用范围，答案提供了详细的解释和例子，符合简答题的特征。 | 知识层次: 题目要求分析复合材料的性能提升方法和应用范围扩展，涉及多材料组合的综合性能分析、机理解释和实际应用的综合考量，需要深入理解和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解复合材料的基本概念，还需要通过具体数据（如断裂能数值）进行复杂现象的分析和推理。此外，题目涉及多材料性能的综合比较和新性能的机理解释，需要考生具备较高的综合分析能力和深度知识掌握。这种题目在选择题中属于要求最高、复杂度最大的类型。" + }, + { + "idx": 3434, + "question": "Explain the practical significance of adding common alloying elements to steel based on their influence on the kinetic curves during the cooling transformation of steel.", + "answer": "Influence on cooling transformation: The addition of alloying elements (except cobalt and aluminum) shifts the position of the isothermal transformation C-curve of undercooled austenite to the right. Strong carbide-forming elements not only shift the C-curve to the right but also alter its shape, resulting in the separation of the pearlite and bainite transformation curves. Therefore, the effects of adding alloying elements are: (1) improving hardenability; (2) carbide-forming elements can also enhance the wear resistance, tempering stability, and red hardness of steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素对钢冷却转变动力学曲线的实际意义，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释合金元素对钢冷却转变动力学曲线的影响及其实际意义，涉及多个合金元素的作用机制、对C曲线形状和位置的影响，以及这些变化如何改善钢的性能（如淬透性、耐磨性、回火稳定性等）。这需要综合运用材料科学知识，进行机理分析和推理，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解合金元素对钢的冷却转变动力学曲线的影响，还需要综合运用这些知识来解释实际应用中的意义。具体来说，考生需要掌握合金元素（除钴和铝外）如何使过冷奥氏体的等温转变C曲线右移，以及强碳化物形成元素如何改变曲线形状并分离珠光体和贝氏体转变曲线。此外，题目还要求考生理解这些变化如何提高钢的淬透性、耐磨性、回火稳定性和红硬性。这种题目需要考生具备深入的材料科学知识，能够进行复杂的推理和分析，因此在选择题型中属于最高难度。" + }, + { + "idx": 3187, + "question": "Describe the structural conditions of crystalline phase transition", + "answer": "The structural fluctuations present in the liquid are the basis for the formation of crystal nuclei during crystallization, therefore, structural fluctuations are the necessary structural conditions for the crystallization process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述晶体相变的结构条件，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求描述晶体相变的结构条件，涉及对结构波动在结晶过程中作用的深入理解和分析，需要综合运用材料科学中的相变理论和结构知识，进行机理层面的解释和推理。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解结晶过程中的结构波动及其与晶体成核的关系，涉及复杂现象的综合分析和机理解释。正确选项不仅需要掌握结晶学的基本概念，还需要能够将这些概念联系起来，进行推理分析。这种深度和综合性的知识运用在选择题中较为罕见，因此属于最高难度等级。" }, { "idx": 38, @@ -163,21 +6295,189 @@ "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释MgO和CaO反应活性的差异，答案通过文字解释和论述给出了原因，涉及离子半径和结构松紧度的比较，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释MgO和CaO在相同晶体结构下与水反应活性的差异，需要分析离子半径对晶体结构的影响以及水分子进入晶格的难易程度，涉及离子半径、晶体结构、反应活性等多个概念的关联和综合分析，属于复杂分析层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求解释MgO和CaO在反应活性上的差异，需要考生理解离子半径对晶体结构的影响，并进一步分析这种结构差异如何导致反应活性的不同。虽然题目涉及的知识点较为基础（离子半径、晶体结构），但需要将这些知识点综合运用并进行逻辑推理，才能完整解释现象。相比只需简单记忆或直接应用的题目（等级1-3），该题目对知识点的掌握深度和逻辑推理能力有更高要求，但尚未达到需要分析多因素交互作用的复杂现象全面分析（等级5）程度。" + "reasoning": "题型: 题目要求解释MgO和CaO反应活性的差异，答案提供了详细的文字解释和论述，涉及离子半径差异和结构松紧度对反应性的影响，符合简答题的特征。 | 知识层次: 题目要求解释MgO和CaO在反应活性上的差异，涉及离子半径对晶体结构的影响以及与水反应机理的分析。需要综合运用晶体结构知识、离子半径效应和化学反应活性等多方面知识进行推理和解释，思维过程较为深入。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解MgO和CaO的晶体结构差异，还需要分析离子半径对结构紧密度的影响，并进一步推导出水分子进入晶格的难易程度与反应活性的关系。这需要综合运用晶体结构知识、离子半径效应以及化学反应机理的解释能力，属于复杂现象全面分析的层次。选择题型中，此类题目对知识深度和推理能力的要求较高，因此评为等级5。" }, { - "idx": 99, - "question": "When two edge dislocations with the same sign meet on the same slip plane, will they repel or attract each other?", - "answer": "Repel, tensile stress overlaps, compressive stress overlaps.", + "idx": 265, + "question": "Analyze the reasons why the diffusion coefficient of anions is generally smaller than that of cations in ionic crystals.", + "answer": "In ionic crystals, anions generally form close packing, while cations fill the tetrahedral or octahedral voids. Therefore, cations diffuse more easily. If anions diffuse, the crystal packing arrangement must be altered, disrupting the structural framework of the ionic crystal, which results in greater resistance. Hence, in ionic crystals, the diffusion coefficient of anions is generally smaller than that of cations.", "question_type": "short_answer", "question_type_name": "简答题", - "knowledge_level": "medium_application", - "knowledge_level_name": "中等应用", - "difficulty": 4, + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释两个同号刃位错在同一滑移面上相遇时的相互作用（排斥或吸引），并需要文字解释其背后的原因（拉伸应力重叠、压缩应力重叠）。答案提供了简短的文字解释，而非选择或判断形式。 | 知识层次: 题目需要理解位错的基本概念（基础记忆），并进一步分析相同符号位错相遇时的应力场相互作用（概念关联和综合分析）。虽然不涉及复杂计算，但需要将位错应力场的知识应用到具体情境中，属于中等应用层次。 | 难度: 在简答题中，该题目属于较高难度。首先，题目要求理解位错的基本概念和相互作用机制；其次，需要分析相同符号位错相遇时的应力场叠加效应；最后，还需结合拉伸和压缩应力场的具体分布进行综合论述。这些步骤涉及多角度分析和概念关联，超出了简单的概念复述或单一知识点应用，符合等级4的多角度分析论述要求。" + "reasoning": "题型: 题目要求分析离子晶体中阴离子扩散系数通常小于阳离子的原因，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析离子晶体中阴离子扩散系数小于阳离子的原因，涉及对晶体结构、扩散机制和能量障碍的综合理解。需要解释阴离子紧密堆积和阳离子占据空隙的结构特点，以及扩散过程中结构框架改变带来的阻力增加。这种分析需要将多个概念关联起来，并进行推理和机理解释，属于较高层次的认知能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解离子晶体中阴离子和阳离子的扩散机制，还需要深入分析晶体结构对扩散系数的影响。正确选项涉及对晶体堆积方式、空隙填充以及结构框架破坏的综合考量，需要考生具备复杂的推理分析能力和机理解释能力。这种题目在选择题中属于对知识深度和综合运用能力要求极高的类型。" + }, + { + "idx": 4758, + "question": "Would you be 100% certain of the answer in part (a)? Why or why not?", + "answer": "the certainty of this prediction is not 100% because there is always some variability in the flexural strength for ceramic materials, and the calculated stress is relatively close to the flexural strength, so there is some chance that fracture will occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么不能100%确定答案，需要文字论述和解释，而不是选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求学生分析陶瓷材料弯曲强度的不确定性，并解释为什么预测结果不能100%确定。这需要学生理解材料性能的变异性，并能将理论计算与实际材料行为进行关联和推理分析。题目涉及的知识点较为复杂，需要综合运用材料科学原理和概率思维，思维过程的深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3253, + "question": "For an Fe-3% (Si) alloy containing MnS particles, when the particle radius is $0.05\\\\mu m$ and the volume fraction is approximately 1%, annealing below 850℃ results in the cessation of normal grain growth when the average grain diameter of the matrix is $6\\\\mu m$. Analyze the reason for this phenomenon.", + "answer": "According to the formula for calculating the limiting average grain size: $$\\\\overline{{D}}_{\\\\mathrm{lim}}=\\\\frac{4r}{3\\\\varphi}=\\\\frac{4\\\\times0.05}{3\\\\times0.01}=6.7~\\\\mu\\\\mathrm{m}$$ The dispersed particles exert a pinning effect on grain boundary migration. When the driving force for grain boundary migration provided by grain boundary energy equals the resistance to grain boundary migration caused by the dispersed particles, the limiting grain size is reached. Further holding does not increase the grain size, as calculated by $\\\\overline{{D}}_{\\\\mathrm{lim}}=6.7~\\\\mu m$. During annealing, the average matrix diameter is 6 μm, which is already close to $\\\\overline{{D}}_{\\\\mathrm{lim}}$, so grain growth becomes extremely slow and nearly stops.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析现象的原因，答案提供了详细的文字解释和论述，包括公式应用和理论分析，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的晶粒生长理论、第二相粒子钉扎效应以及相关公式计算，进行推理分析和机理解释。涉及多步计算和概念关联，思维过程要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用材料科学中的晶粒生长理论、第二相粒子钉扎效应以及相关计算公式，进行复杂的推理分析和机理解释。具体来说，考生需要：" + }, + { + "idx": 26, + "question": "According to the closest packing principle, the higher the space utilization, the more stable the structure. The space utilization of the diamond structure is very low (only 34.01%), why is it also very stable?", + "answer": "The closest packing principle is based on the spherical symmetry and non-directionality of the electron cloud distribution of particles, so it only applies to typical ionic crystals and metallic crystals, and cannot be used to measure the stability of atomic crystals. In addition, the number of single bonds in diamond is 4, meaning each atom is surrounded by 4 single bonds (or atoms), forming a three-dimensional structure through covalent bonding of tetrahedra sharing vertices. Therefore, although the space utilization of the diamond structure is very low (only 34.01%), it is still very stable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么金刚石结构在空间利用率低的情况下仍然非常稳定，答案提供了详细的文字解释和论述，涉及电子云分布、晶体类型和共价键结构等概念，符合简答题的特征。 | 知识层次: 题目不仅要求理解最密堆积原理和空间利用率的基本概念，还需要分析其适用范围和局限性。此外，需要深入解释金刚石结构的稳定性机制，涉及共价键的方向性和三维网络结构的形成，这需要综合运用多个概念并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 921, + "question": "Analyze the crystallization process of an iron-carbon alloy with a carbon content of 0.12%", + "answer": "For steel with 0.12% carbon, when cooled from the liquid phase, δ-ferrite forms first. The compositions of the solid and liquid phases change according to the solidus and liquidus lines on the phase diagram. At the peritectic temperature of 1495°C, partial peritectic reaction occurs; the new phase γ-austenite nucleates on the pre-existing δ-ferrite and grows into both the δ-ferrite and liquid phase. After the reaction, the microstructure consists of two phases: δ-ferrite + γ-austenite. The relative amount of δ-ferrite is: (0.17-0.12)/(0.17-0.09)=62.5%. Upon further cooling, single-phase austenite is obtained.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析铁碳合金的结晶过程，答案提供了详细的文字解释和论述，包括相变过程、温度变化和相组成计算，符合简答题的特征。 | 知识层次: 题目要求分析铁碳合金的结晶过程，涉及相图的理解、相变反应的描述、相对量的计算以及微观结构的演变。这需要综合运用相图知识、相变机理和定量计算，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对铁碳合金的结晶过程进行复杂现象全面分析，涉及多个相变过程（δ-铁素体形成、包晶反应、γ-奥氏体形成）、相图解读（固相线和液相线变化）、以及定量计算（相对含量62.5%）。解题需要综合运用相图知识、热力学原理和显微组织演变机理，并能够解释各阶段的相变行为和最终组织组成。这种深度和广度的知识整合在选择题型中属于最具挑战性的类型。" + }, + { + "idx": 330, + "question": "Why is the liquid/solid interface front of an alloy more prone to undercooling during solidification compared to that of a pure metal?", + "answer": "The interface front of an alloy exhibits constitutional undercooling, where solute enrichment at the front raises the local melting point, making undercooling more likely to occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金在凝固过程中比纯金属更容易发生过冷的原因，答案需要文字解释和论述，涉及材料科学中的概念和原理，属于简答题类型。 | 知识层次: 题目需要解释合金凝固过程中液/固界面前沿更容易发生过冷的原因，涉及溶质富集和局部熔点升高的机理分析，属于综合运用和推理分析的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2365, + "question": "A lightly cross-linked rubber band is stretched several times its original length and returns to its original length after the force is removed. If the stretched rubber band is placed below its glass transition temperature, what will happen to its length after the force is removed? Why?", + "answer": "When the stretched rubber band is placed below its glass transition temperature, it transitions into a glassy state. The glass transition causes the atoms to change from delocalized to localized (solidification), so it cannot return to its original length after the external force is removed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释现象并论述原因，答案需要文字解释和论述，没有提供选项或要求计算 | 知识层次: 题目要求分析橡胶带在玻璃化转变温度以下的行为变化，并解释其背后的机理。这需要综合运用材料科学中的高分子物理知识，理解玻璃化转变对材料性能的影响，以及橡胶弹性的基本原理。思维过程涉及多个概念的关联和深层次的理解，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1607, + "question": "What are the causes and movement characteristics of Shockley partial dislocations in face-centered cubic crystals?", + "answer": "In face-centered cubic crystals, Shockley partial dislocations are generated by non-uniform slip. They can be edge dislocations, screw dislocations, or mixed dislocations, and are capable of slipping.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Shockley partial dislocations的成因和运动特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Shockley不全位错的成因和运动特性，涉及面心立方晶体中的位错理论、位错类型（刃型、螺型、混合型）及其滑移能力。这需要综合运用材料科学中的位错理论，进行机理分析和推理，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1295, + "question": "Why does pure metal grow in a planar manner during solidification under a positive temperature gradient?", + "answer": "During crystallization, the interface of pure metal is rough and grows under a positive temperature gradient. As the crystal grows, heat is dissipated through the solid mold wall, making the solid-liquid interface isothermal. If dynamic undercooling is achieved, the interface moves forward. If there is a small protrusion locally on the interface extending into the superheated liquid phase, the protrusion will be melted, so the interface remains straight; the crystal grows in a planar manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纯金属在正温度梯度下凝固时为何以平面方式生长，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释纯金属在正温度梯度下凝固时平面生长的机理，涉及动态过冷、界面粗糙性、热量传递等多个概念的关联和综合分析，需要深入理解并推理分析其背后的物理机制。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2808, + "question": "Compare the oxidation resistance of NiO and W-doped NiO (i.e., NiO-WO3), which one is better?", + "answer": "Due to the introduction of W, the vacancy concentration increases, making it easier for oxygen in the air and Ni2+ ions in the oxide to migrate in and out of the surface, thereby increasing the oxidation rate. As a result, the oxidation resistance is reduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较NiO和W-doped NiO的氧化抗性，并解释哪一种更好。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较NiO和W掺杂NiO的氧化抗性，并解释其机理。这需要理解掺杂对材料性能的影响，分析空位浓度变化对氧化速率的作用机制，涉及多个概念的关联和综合运用。思维过程需要推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解NiO和W-doped NiO的基本性质，还需要掌握掺杂对材料氧化抗性的影响机制。正确选项涉及复杂的材料科学原理，包括空位浓度变化、离子迁移性以及氧化速率的关系。考生需要综合运用材料化学和缺陷化学知识进行推理分析，并解释掺杂引入的W如何通过改变材料微观结构来影响宏观性能。这种需要多维度知识整合和机理深度解释的题目，在选择题型中属于最高难度级别。" + }, + { + "idx": 4375, + "question": "On the basis of diffusion considerations, explain why fine pearlite forms for the moderate cooling of austenite through the eutectoid temperature, whereas coarse pearlite is the product for relatively slow cooling rates.", + "answer": "For moderately rapid cooling, the time allowed for carbon diffusion is not as great as for slower cooling rates. Therefore, the diffusion distance is shorter, and thinner layers of ferrite and cementite form (i.e., fine pearlite forms).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于扩散理论解释不同冷却速率下珠光体形成的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于扩散理论解释不同冷却速率下珠光体形成的机理，涉及扩散距离与冷却速率的关系，以及珠光体微观结构的形成过程。这需要综合运用扩散原理、相变动力学和微观结构形成的知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1301, + "question": "Why do metal crystals always slide along the slip plane and slip direction during the slip process?", + "answer": "The slip of metal crystals is the result of dislocation movement, and the dislocation movement is mainly subjected to the resistance of the crystal lattice. In the crystal, the greater the interplanar spacing between the densest atomic planes, and the smaller the atomic spacing in the most closely packed direction, the smaller the sliding resistance when dislocations slide along the slip plane and slip direction. Therefore, metal crystals always slide along the slip plane and slip direction during the slip process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属晶体在滑移过程中为何总是沿滑移面和滑移方向滑动，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属晶体滑移过程中的机理，涉及位错运动、晶格阻力、原子面间距和方向等复杂概念的综合分析和推理。需要深入理解晶体结构和位错理论，并能够将这些概念关联起来进行解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解金属晶体滑移的微观机制，包括位错运动、晶格阻力、密排面和密排方向等复杂概念的综合运用。正确选项不仅需要解释滑移现象，还需要分析晶面间距和原子间距对滑移阻力的影响机理。这种题目要求考生具备将多个高阶材料科学原理进行系统性整合和推理分析的能力，远超单纯记忆或简单应用层面，属于选择题型中最复杂的机理深度解释类题目。" + }, + { + "idx": 3345, + "question": "Among the various types of steel currently used in industry, cold-drawn high-carbon steel wire has the highest strength (up to 3000 MPa). This type of wire is generally obtained by first undergoing austenitization, followed by isothermal treatment in a lead bath at 500°C, and then cold drawing. Analyze the reasons for the high strength of this material.", + "answer": "When high-carbon steel undergoes isothermal treatment at 550°C after austenitization, the interlamellar spacing of pearlite can be made very small. Subsequent cold drawing not only increases the dislocation density in the ferrite of the pearlite, causing work hardening and subgrain refinement, but also further reduces the interlamellar spacing of the pearlite, thereby achieving high strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高碳钢冷拉钢丝高强度的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高碳钢丝高强度的原因，涉及多个热处理和加工步骤（奥氏体化、等温处理、冷拔）的综合作用机制，需要理解珠光体层间距、位错密度增加、亚晶粒细化等微观结构变化对宏观性能的影响，属于需要综合运用材料科学知识进行机理分析和解释的复杂问题。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解高碳钢的微观结构变化（如珠光体片层间距、位错密度增加等），还需要综合运用热处理和冷加工的知识，分析多个工艺步骤对材料性能的影响机制。正确选项涉及复杂的热力学和动力学过程解释，需要考生具备深入的材料科学原理知识和综合分析能力。这种题目在选择题型中属于对机理深度解释和复杂现象全面分析的最高要求。" + }, + { + "idx": 577, + "question": "In a face-centered cubic crystal, a dislocation with Burgers vector b1= [101] meets a dislocation with b2= [121]. Explain the reason whether the dislocation reaction can occur.", + "answer": "Energy condition: b1^2+b2^2= (a^2/4)(1+0+1)+(a^2/36)(1+4+1)=a^2/2+a^2/6=2a^2/3, b3^2= (a^2/9)(1+1+1)=a^2/3, b3^2, <100>, <110> directions, while soft-oriented stress axes correspond to single slip, such as the <123> direction.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释两种回火脆性的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种回火脆性的主要区别，并涉及它们的形成机理。这需要深入理解材料科学中的相变、析出和偏析现象，以及它们对材料性能的影响。回答不仅需要记忆两种脆性的定义，还需要分析它们的可逆性差异和具体的微观机制，属于较高层次的认知能力要求。 | 难度: 在简答题-复杂分析题型中，该题目要求对两种回火脆性进行全面比较分析，涉及不可逆/可逆性差异、碳化物析出机制、杂质元素偏析等多重机理解释。需要综合运用材料相变、合金元素作用等知识体系进行深度推理，属于该题型下对复杂现象进行机理阐释的最高难度层级。" + "reasoning": "题型: 题目要求解释为什么在变形过程中某些晶粒表现出单滑移而其他晶粒表现出多滑移，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释多晶变形过程中不同晶粒表现出单滑移和多滑移的原因，涉及晶体取向、应力轴方向与滑移系激活的复杂关系。需要综合运用晶体塑性变形理论、Schmid因子分析以及不同晶向的滑移系激活条件，属于机理分析和推理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" }, { - "idx": 1240, - "question": "What does the size of the critical nucleus radius depend on?", - "answer": "ΔGV and σ", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求解释临界核半径大小取决于哪些因素，答案需要文字说明（ΔGV and σ），属于简答题类型 | 知识层次: 题目考查临界核半径与自由能变化(ΔGV)和表面能(σ)的基本关系，属于基本原理的记忆性知识 | 难度: 在简答题题型中，该题目要求解释临界核半径尺寸的依赖因素(ΔGV和σ)，属于概念解释和描述层面。虽然需要记忆两个关键参数，但不需要展开复杂推导或阐述多因素间的相互作用，因此属于等级2难度。这比单纯背诵定义(等级1)要求略高，但低于需要系统阐述理论推导过程的等级3题目。" - }, - { - "idx": 1292, - "question": "If the slip of the jog is inconsistent with the slip of the main dislocation line, the main dislocation line will drag the jog to produce climb motion, resulting in what phenomenon?", - "answer": "Jog hardening", + "idx": 939, + "question": "Analyze the causes of primary banded structure formation.", + "answer": "The formation of primary banded structure is related to dendrite formation during solidification and the hot rolling process, where the dark bands are dendrite trunks (with fewer solutes) and the white bands are interdendritic regions enriched with impurities.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释一个现象（jog hardening），需要文字论述而非选择、判断或计算。 | 知识层次: 题目涉及位错运动中的复杂机制分析，需要理解位错与割阶的相互作用以及攀移运动导致的硬化现象，属于对材料变形机理的深入解释和推理分析。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅理解位错运动的基本概念，还需要分析位错线与jog之间的相互作用及其导致的攀移运动现象。这需要考生具备综合运用位错理论和材料变形机理的能力，并能准确描述jog hardening这一复杂现象的产生原因。虽然题目没有要求全面分析所有可能的影响因素，但对机理的解释深度要求较高，因此属于等级4难度。" + "reasoning": "题型: 题目要求分析带状结构形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析初级带状结构形成的原因，涉及凝固过程中的枝晶形成和热轧工艺的综合分析，需要理解枝晶主干和枝晶间区域的成分差异及其对结构形成的影响。这需要综合运用材料科学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" }, { - "idx": 1329, - "question": "Explain the origin and morphological characteristics of Fe3CIII", - "answer": "Fe3CIII: Originates from the precipitation reaction of ferrite, generally distributed in a network pattern along grain boundaries.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "medium_application", - "knowledge_level_name": "中等应用", - "difficulty": 3, - "final_level": "Level_4", - "reasoning": "题型: 题目要求解释Fe3CIII的起源和形态特征，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求解释Fe3CIII的起源和形态特征，涉及相变过程和显微组织观察，需要将多个概念（如沉淀反应、铁素体、晶界分布）关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。题目要求解释Fe3CIII的起源和形态特征，需要考生理解并关联多个概念（如沉淀反应、铁素体、晶界分布等），并进行综合分析。虽然涉及的知识点较为专业，但解题步骤相对直接，不需要多角度或深度关联性分析，因此属于等级3的综合分析和说明难度。" - }, - { - "idx": 1460, - "question": "What effect do second-phase particles have on the plastic deformation of alloys? Use dislocation theory to explain the mechanism.", - "answer": "Key points: They increase the strength of the alloy and the flow resistance during plastic deformation. This is because the resistance increases when dislocations cut through deformable second-phase particles or bypass non-deformable second-phase particles.", + "idx": 2904, + "question": "Explain why crystal structures do not possess 5-fold or higher than 6-fold symmetry axes?", + "answer": "5-fold or higher than 6-fold symmetry axes cannot satisfy the condition of identical surroundings around lattice points, lack translational symmetry, and thus cannot achieve a regularly periodic arrangement of crystal structures.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求使用位错理论解释第二相粒子对合金塑性变形的影响，答案需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求使用位错理论解释第二相粒子对合金塑性变形的影响机制，涉及对位错与第二相粒子相互作用的深入理解和综合分析。需要考生不仅理解位错理论的基本概念，还要能够分析位错切割或绕过第二相粒子的过程，并解释其对合金强度和塑性变形的影响。这种题目要求较高的推理分析和机理解释能力，属于复杂分析层次。 | 难度: 在简答题（需要文字解释和论述）的题型框架内，该题目属于机理深度解释难度等级。题目要求运用位错理论解释第二相粒子对合金塑性变形的影响机制，需要考生不仅掌握位错与第二相粒子的相互作用原理，还要能够清晰阐述可变形/不可变形粒子的强化机制。虽然不涉及多系统交互作用的复杂现象分析（等级5特征），但需要将位错理论、塑性变形和强化机制进行系统性整合，符合等级4对机理深度解释的要求。" + "reasoning": "题型: 题目要求解释晶体结构为何不具备5重或高于6重的对称轴，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求解释晶体结构中不存在5重或高于6重对称轴的原因，这需要综合运用晶体学的基本原理（如平移对称性、点阵理论）进行推理分析，并解释其物理机制。这超出了简单记忆或直接应用的范畴，属于对晶体对称性深层次理解的复杂分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求解释晶体结构中不存在5重或高于6重对称轴的原因，涉及对晶体学基本原理的深入理解，包括点阵的平移对称性和周期性排列的限制条件。正确选项不仅需要识别对称性限制，还需综合运用晶体学知识进行机理解释，这要求考生具备较高的分析推理能力和对复杂现象的全面理解。在选择题型中，此类题目通常需要考生超越简单记忆，进行深层次的概念整合和逻辑推理，因此难度等级为5。" }, { - "idx": 1530, - "question": "Explain the strengthening mechanism of solid solution strengthening", - "answer": "Solid solution strengthening: For both substitutional atoms and interstitial atoms, under suitable conditions, atomic segregation may occur to form atmospheres. For substitutional lattices, when solute atoms are larger than solvent atoms, solute atoms tend to accumulate in the expanded region of edge dislocations; conversely, they accumulate in the compressed region. Interstitial atoms always tend to accumulate in the expanded region. This phenomenon of diffusion-driven accumulation near dislocations is called Cottrell atmosphere. The Cottrell atmosphere has a pinning effect on dislocations, thereby increasing strength.", + "idx": 2309, + "question": "In what aspects should the improvement of interface bonding be considered to reduce interfacial residual stress?", + "answer": "Reduce interfacial residual stress", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释固溶强化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及位错与溶质原子的相互作用、Cottrell气团的形成及其对位错的钉扎效应等复杂概念。需要深入理解材料科学中的位错理论和扩散机制，并进行综合分析，属于机理解释层面的问题。 | 难度: 在简答题题型中，该题目属于机理深度解释的难度等级。题目要求详细解释固溶强化的机制，包括置换原子和间隙原子的行为、Cottrell气团的形成及其对位错的钉扎效应。这需要学生不仅理解基本概念，还需要能够综合运用知识进行推理分析，解释复杂的物理现象。虽然题目没有要求全面分析所有可能的复杂现象，但对机理的解释深度要求较高，因此属于等级4。" + "reasoning": "题型: 题目要求从多个方面进行解释和论述，答案需要文字描述而非选择或计算 | 知识层次: 题目要求从多个方面考虑如何改善界面结合以减少界面残余应力，这需要对界面结合的机理、残余应力的产生原因及其影响因素有深入的理解，并能够综合运用这些知识进行分析和推理。这超出了简单记忆或直接应用的范畴，属于复杂分析和综合运用的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用材料科学知识，深入理解界面结合和残余应力的复杂关系，并进行机理层面的解释。考生需要掌握界面结合的多个改进方面（如材料选择、工艺参数、界面设计等），并能推理分析这些因素如何共同影响残余应力的形成和降低。这种题目不仅测试知识广度，更考察对复杂现象的全面分析能力，远超出简单记忆或单一概念的应用。" }, { - "idx": 1618, - "question": "When titanium oxide is oxygen-deficient, the following reaction can occur: $\\\\mathrm{TiO}_{2}-\\\\frac{1}{2}0_{2}{\\\\rightarrow}\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}+\\\\mathrm{V}_{0}^{\\\\ast}$. Please correctly write the defect equation and explain the meaning of each term.", - "answer": "The defect equation is $2\\\\mathrm{TiO}_{2}-\\\\frac{1}{2}0_{{2}}{\\\\rightarrow}2\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}+\\\\mathrm{V}_{0}^{\\\\ast}+30_{0}$. $\\\\mathrm{Ti^{\\\\prime}}_{\\\\mathrm{Ti}}$: Titanium dioxide loses oxygen, generating $\\\\mathbb{T}^{3+}$ occupying the $\\\\mathbf{Ti}^{4+}$ lattice site, with an effective charge of -1. $\\\\mathbf{V}_{0}^{*}$: Oxygen vacancy, with an effective charge of $^{+2}$. $0_{\\\\mathfrak{o}}$: Oxygen still occupies the oxygen lattice site.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "medium_application", - "knowledge_level_name": "中等应用", - "difficulty": 4, - "final_level": "Level_5", - "reasoning": "题型: 题目要求正确写出缺陷方程并解释每个术语的含义，这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求正确书写缺陷方程并解释各项含义，涉及多步概念关联和综合分析。需要理解缺陷化学符号表示法、电荷补偿机制等概念，并能将氧空位与钛离子价态变化关联起来进行分析，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要正确书写缺陷方程并解释每个术语的含义。题目涉及多步计算和概念关联，要求考生综合理解缺陷化学中的电荷平衡和缺陷符号表示。此外，还需要对钛氧化物氧缺陷的生成机制有深入理解，并能准确描述缺陷的有效电荷状态。这些要求使得该题目在同类简答题中难度较高。" - }, - { - "idx": 1695, - "question": "How do different types of bonding affect the hardness of crystalline materials?", - "answer": "The hardness of crystalline materials is closely related to the type of bonding. Crystals bonded by covalent, ionic, and metallic bonds generally exhibit higher hardness than those bonded by molecular bonds.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求解释不同键合类型如何影响晶体材料的硬度，答案提供了文字解释和论述，没有选项、判断或计算要求。 | 知识层次: 题目主要考查对不同类型化学键与晶体硬度关系的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在简答题题型中，该题目属于概念解释和描述级别。虽然涉及不同键合类型对硬度的影响，但只需简要说明各类键合与硬度的基本关系，无需深入分析或构建复杂概念体系。属于对基础概念记忆性知识的应用，但比单纯的定义简答（等级1）要求稍高。" - }, - { - "idx": 1721, - "question": "What effect does constitutional supercooling have on the solidification structure of alloys?", - "answer": "The occurrence of constitutional supercooling phenomenon will cause multicomponent alloys to develop cellular or dendritic structures even under a positive temperature gradient.", + "idx": 4457, + "question": "How do the aggregate particles become bonded together in clay-based mixtures during firing?", + "answer": "For clay-based aggregates, a liquid phase forms during firing, which infiltrates the pores between the unmelted particles; upon cooling, this liquid becomes a glass, that serves as the bonding phase.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释constitutional supercooling对合金凝固结构的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对constitutional supercooling现象的理解及其对合金凝固结构的影响，需要综合运用材料科学中的凝固理论和相变知识，进行机理的解释和分析。这超出了简单记忆或基本应用的范畴，属于对复杂现象的深入理解和分析。 | 难度: 在简答题-复杂分析题型中，该题目要求对\"成分过冷\"这一专业现象进行机理深度解释，需要综合运用相变原理、热力学和凝固组织形成机制等知识。虽然不涉及多现象交叉分析（等级5特征），但需要对单一复杂现象进行完整的因果链条阐述，符合等级4\"机理深度解释\"的标准。" + "reasoning": "题型: 题目要求解释粘土基混合物在烧制过程中颗粒如何结合，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释粘土基混合物在烧制过程中颗粒如何结合，涉及液相形成、渗透和冷却过程中的玻璃化转变等复杂机理，需要综合运用材料科学知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" }, { - "idx": 1805, - "question": "What are grain growth and secondary recrystallization?", - "answer": "Grain growth is the process in which the average grain size of a strain-free material continuously increases during heat treatment without altering its distribution. Within the body, grain sizes grow uniformly, and during grain growth, pores remain at grain boundaries or their intersections. Secondary recrystallization is an abnormal growth process where a few large grains grow at the expense of fine grains, representing the abnormal growth of individual grains. During secondary recrystallization, pores become trapped inside the grains.", + "idx": 2268, + "question": "Why do transition phases appear during the precipitation process?", + "answer": "Transition phases appear during the precipitation process because the system requires a series of intermediate transition phases to gradually reduce free energy during the transformation from a supersaturated solid solution to the equilibrium phase. These transition phases, with their crystal structures and compositions intermediate between GP zones and the equilibrium phase, can reduce nucleation work and strain energy, making the phase transformation process easier to proceed.", "question_type": "short_answer", "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求对\"grain growth\"和\"secondary recrystallization\"这两个概念进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查的是对晶粒生长和二次再结晶这两个基本概念的定义和描述，属于基础概念的记忆和理解范畴，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求解释\"grain growth\"和\"secondary recrystallization\"两个概念，需要考生对这两个概念有基本的理解和记忆，并能用文字进行描述。虽然涉及两个相关概念，但都属于基础概念记忆层次，不需要进行复杂的概念体系阐述或深入分析。在简答题题型中，这属于中等偏下的难度，比单纯的定义简答(等级1)要求稍高，但远低于需要阐述复杂概念体系的题目(等级3)。" + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释过渡相在析出过程中出现的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释过渡相在析出过程中出现的原因，涉及自由能降低、中间过渡相的作用、晶体结构和成分的中间性、形核功和应变能的减少等多个方面的综合分析。需要深入理解相变机理，并能将这些概念关联起来进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解相变过程中的自由能变化、过渡相的作用机理等复杂概念，并能综合运用这些知识解释现象。正确选项涉及多个专业概念（如GP区、应变能、形核功等）的关联分析，需要考生具备将理论知识转化为机理解释的能力，这远超出简单记忆或基础理解的范畴。在选择题型中，此类需要综合推理和机理深度分析的题目属于最复杂的类型。" + }, + { + "idx": 1478, + "question": "Using the constitutional undercooling theory, explain the relationship between the casting properties (fluidity, distribution characteristics of shrinkage porosity) of an alloy and the vertical distance between the liquidus and solidus lines in its phase diagram.", + "answer": "The casting properties (fluidity, distribution characteristics of shrinkage porosity) of an alloy are related to the vertical distance between the liquidus and solidus lines in its phase diagram. The larger the vertical distance, the poorer the fluidity of the alloy, and the more likely shrinkage porosity is to be distributed dispersedly. The condition for constitutional undercooling is given by: $\\\\frac{-m C_{0}(1-k_{0})}{D k_{0}}$, where G is the actual temperature gradient in the liquid ahead of the liquid/solid interface, R is the velocity of the liquid/solid interface movement, $\\\\pmb{D}$ is the diffusion coefficient of solute atoms in the liquid phase, $\\\\mathbf{\\abla}m$ is the slope of the liquidus line in the alloy phase diagram, $C_{0}$ is the composition of the alloy, and $k_{0}$ is the equilibrium partition coefficient of the alloy. It can be proven that $\\\\frac{\\\\mathrm{-}m C_{0}~\\\\left(1-k_{0}\\\\right)}{k_{0}}$ in the above equation is the vertical distance between the liquidus and solidus lines for the $C_{0}$ alloy in its phase diagram. Clearly, the larger the vertical distance between the liquidus and solidus lines, the greater the tendency for constitutional undercooling in the alloy, and the more the liquid/solid interface tends to grow dendritically. This hinders the fluidity of the alloy melt and also causes dispersed shrinkage porosity to form in the interdendritic regions due to insufficient feeding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用成分过冷理论解释合金铸造性能与相图中液相线和固相线垂直距离之间的关系，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求运用成分过冷理论解释合金铸造性能与相图中液相线和固相线垂直距离的关系，涉及多个概念的关联和综合分析，需要深入理解成分过冷的条件及其对合金凝固行为的影响，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 936, + "question": "What is the main difference between nucleation and growth during solidification and nucleation and growth during recrystallization?", + "answer": "The driving force for nucleation and growth during solidification is the chemical potential difference between the new and old phases, while the driving force for nucleation and growth during recrystallization is solely the stored deformation energy. Nucleation during solidification is often homogeneous; nucleation during recrystallization typically occurs in existing regions of deformation inhomogeneity, such as near grain boundaries, shear bands, deformation bands, or around second-phase particles. During solidification growth, there is no orientation relationship with the parent phase, whereas during recrystallization growth, there may be a certain orientation relationship.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述两种过程中成核和生长的主要区别，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种不同过程中成核和生长的差异，涉及多个概念的综合运用和机理的解释，需要深入理解固化和再结晶的驱动机制、成核位置以及生长过程中的取向关系等复杂因素。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解固化和再结晶过程中的成核与生长机制，还需要深入比较两者的驱动力差异、成核位置差异以及生长过程中的取向关系差异。这需要综合运用材料科学中的相变理论、变形储能概念以及微观结构演化知识，进行复杂的推理分析和机理解释。选择题型中此类综合比较题目对知识深度和逻辑分析能力要求极高，因此属于最高难度等级。" + }, + { + "idx": 562, + "question": "Analyze the changes in vacancies and dislocations in deformed metals during the recrystallization stage and their effects on properties.", + "answer": "Recrystallization stage: With the rearrangement of atoms during recrystallization, the dislocation density significantly decreases, the complex dislocation interactions generated during deformation disappear, the work hardening phenomenon vanishes, and the various properties of the deformed metal return to their pre-deformation state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析变形金属在再结晶阶段的空位和位错变化及其对性能的影响，需要详细的文字解释和论述。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析变形金属在再结晶阶段空位和位错的变化及其对性能的影响，需要综合运用材料科学中的变形、再结晶、位错理论等知识，进行推理分析和机理解释。这涉及到多个知识点的关联和深入理解，思维过程要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解金属再结晶阶段的微观机制，包括空位和位错的变化及其对性能的影响。正确选项不仅涉及多个复杂概念（如位错密度、加工硬化现象），还需要综合推理分析这些变化如何导致性能恢复。这种题目要求考生具备机理深度解释和复杂现象全面分析的能力，远超简单记忆或基础理解层面。" }, { "idx": 1965, @@ -427,93 +6631,273 @@ "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释现象并论述原因，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要综合运用动态再结晶理论（T_recrystallization=(0.35～0.45)Tm）和热加工概念来解释锡板在室温弯曲时的现象，涉及机理分析和多概念关联，思维过程要求较高。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅要知道锡板在室温下弯曲时会发生动态再结晶，还需要理解并解释为什么会出现这种现象（即根据再结晶温度公式T_recrystallization=(0.35～0.45)Tm进行热加工判定）。这需要考生具备将理论公式与实际现象相结合的能力，并能进行合理的推理分析。虽然题目没有要求更复杂的多因素分析或跨学科知识整合，但已经达到了机理解释类简答题的较高难度水平。" + "reasoning": "题型: 题目要求解释现象并论述原因，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要综合运用动态再结晶理论（T_recrystallization=(0.35～0.45)Tm）和热加工概念，分析室温下锡板弯曲过程中的现象。这涉及材料科学中的相变机理、温度对材料行为的影响等复杂概念，并要求进行推理分析来解释现象。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" }, { - "idx": 2048, - "question": "What is a critical nucleus?", - "answer": "According to the relationship between free energy and the radius of an embryo, it can be known that embryos with radius rr_k have the potential to nucleate; while embryos with r=r_k may either disappear or grow stably. Therefore, an embryo with radius r_k is called a critical nucleus. Its physical meaning is that the short-range ordered atomic clusters emerging in the undercooled liquid can become nuclei and grow when their size r≥r_k.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求解释\"critical nucleus\"的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对临界核（critical nucleus）这一基本概念的定义和物理意义的记忆和理解，属于基础概念记忆范畴。 | 难度: 在简答题中属于概念解释和描述难度等级。题目要求解释\"critical nucleus\"的定义及其物理意义，涉及自由能与胚胎半径的关系，需要理解并描述临界核的形成条件（r=r_k）及其在形核过程中的作用。虽然需要一定的概念理解和文字组织能力，但不需要深入分析复杂概念体系或进行多步骤推导，属于中等难度的概念解释题。" - }, - { - "idx": 2052, - "question": "Point out the errors in the following concepts and correct them: (1) The so-called degree of undercooling refers to the difference between the temperature at which a plateau appears on the cooling curve during crystallization and the melting point; while the dynamic degree of undercooling refers to the difference between the actual temperature of the liquid phase during crystallization and the melting point.", - "answer": "The difference between the actual crystallization temperature on the cooling curve and the melting point; the difference between the temperature of the liquid at the liquid-solid interface front and the melting point.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也是以文字形式给出修正后的概念，符合简答题的特征。 | 知识层次: 题目考查对\"过冷度\"和\"动态过冷度\"这两个基本概念的定义理解和辨析，属于基础概念记忆和理解范畴 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求指出并纠正关于过冷度的错误概念，需要学生对基础概念有准确的理解和描述能力，但不需要进行复杂的概念体系阐述或深入分析。该题主要考察学生对\"过冷度\"和\"动态过冷度\"这两个基础概念的定义和区别的掌握程度，属于中等难度的概念解释题。" - }, - { - "idx": 2072, - "question": "Point out the errors in the following concept and correct them: (9) If 10,000 nucleation agents are added to an undercooled liquid, then 10,000 grains will form after crystallization.", - "answer": "then tens of thousands of grains will form after crystallization.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "medium_application", - "knowledge_level_name": "中等应用", - "difficulty": 3, - "final_level": "Level_4", - "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求识别并纠正关于成核剂与晶粒形成关系的错误概念，需要理解成核过程的基本原理并应用这些知识来分析具体情境。虽然涉及基础概念，但需要将多个知识点（成核剂的作用、晶粒形成机制）关联起来进行综合分析，属于中等应用层次。 | 难度: 在简答题中属于中等难度，需要理解成核剂的作用机制和晶粒形成过程，并能指出原概念的不足并进行修正。虽然不需要多角度分析或深度关联性分析，但需要对相关概念有较好的掌握并能进行简单的综合说明。" - }, - { - "idx": 2094, - "question": "How to obtain the mass and Cu content of solid α2 by heating solid α1 to melting, slowly cooling to 900°C, and pouring off the liquid?", - "answer": "Heat the solid (α1) in (1) to melting, slowly cool to 900°C, pour off the liquid, and the remaining solid α2 has a weight of 390g with w_Cu≈0.03.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "medium_application", - "knowledge_level_name": "中等应用", - "difficulty": 3, - "final_level": "Level_4", - "reasoning": "题型: 题目要求通过文字解释和论述来描述如何通过加热、冷却和倒出液体来获得固体α2的质量和铜含量，答案提供了具体的步骤和结果，但没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目涉及多步操作（加热、冷却、分离）和结果分析（质量测定和成分计算），需要综合运用相图知识和实验操作步骤的理解，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度（等级3）。题目要求通过加热、冷却和分离步骤来获取固体α2的质量和铜含量，涉及多步操作和基本计算。虽然需要理解相图和分离过程的概念，但不需要进行复杂的多角度分析或深度关联性分析。解题步骤相对直接，主要考察对实验操作和基础计算的理解与应用。" - }, - { - "idx": 2139, - "question": "Why is the carburizing temperature for steel parts generally chosen to be in the γ phase region?", - "answer": "Because the maximum carbon solubility (mass fraction) in α-Fe is only 0.0218%. For steel with a carbon mass fraction greater than 0.0218%, the carbon concentration gradient in the part during carburizing is zero, making carburizing impossible. Even for pure iron, carburizing in the α phase region results in a very small concentration gradient in the iron, and a high carbon layer cannot be obtained on the surface. Additionally, due to the low temperature, the diffusion coefficient is also very small, making the carburizing process extremely slow and practically meaningless. The carbon solubility in γ-Fe is high, allowing a higher carbon concentration gradient on the surface during carburizing, which facilitates the carburizing process.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "complex_analysis", - "knowledge_level_name": "复杂分析", - "difficulty": 4, - "final_level": "Level_5", - "reasoning": "题型: 题目要求解释为什么钢件的渗碳温度通常选择在γ相区，答案提供了详细的文字解释和论述，涉及碳溶解度、浓度梯度、扩散系数等多个方面，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释为什么钢件的渗碳温度通常选择在γ相区，这涉及到对碳在α-Fe和γ-Fe中溶解度的理解、浓度梯度的概念、扩散系数的温度依赖性以及渗碳过程的动力学分析。解答需要综合运用多个概念，进行推理分析，并解释机理，属于复杂分析的层次。 | 难度: 在简答题中属于机理深度解释难度等级。该题目要求考生不仅掌握γ相区和α相区碳溶解度的基本差异，还需要理解碳浓度梯度、扩散系数等概念对渗碳过程的影响机制。解题时需要综合运用相图知识、扩散原理和工艺参数分析能力，对渗碳温度选择的多个技术原因进行逻辑串联和机理层面的解释。虽然不涉及跨学科整合（等级5特征），但已经达到单一学科内较深层次的机理分析要求。" - }, - { - "idx": 2224, - "question": "Assuming the recrystallization temperature is defined as the temperature at which 95% recrystallization is completed within 1h, according to the Arrhenius equations Ṅ=N0exp(−Qn/RT) and G=G0exp(−Qg/RT), it can be inferred that the recrystallization temperature will be a function of G and Ṅ. Determine the functional relationship between the recrystallization temperature and G0, N0, Qg, Qn.", - "answer": "According to the J-M equation, if the temperature at which 95% recrystallization is completed within 1h is defined as TF, then 0.95=1−exp(−π/3 ṄG3t0^4). Therefore, t0=(2.86/ṄG3)^1/4. Substituting the Arrhenius equations, we obtain N0G0^3exp(−(Qn+3Qg)/RTF)=k. Rearranging gives TF=(Qn+3Qg)/(R ln(N0G0^3/k))=k′(Qn+3Qg). This equation represents the functional relationship between TF and N0, G0, Qn, Qg.", + "idx": 973, + "question": "What effects do interfaces, surfaces, and dislocations have on atomic diffusion in metals or alloys?", + "answer": "Interfaces, surfaces, and dislocations act as fast diffusion paths.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求推导和解释功能关系，答案提供了详细的数学推导和文字解释，符合简答题的特征。 | 知识层次: 题目要求根据Arrhenius方程推导再结晶温度与G0、N0、Qg、Qn之间的函数关系，涉及多步计算、概念关联和综合分析。需要理解再结晶温度的定义，运用J-M方程和Arrhenius方程进行推导，并进行数学变换和逻辑推理，思维过程较为复杂。 | 难度: 在简答题 - 需要文字解释和论述的题型中，该题目属于复杂分析 - 综合运用、推理分析、机理解释的知识层次。题目要求根据Arrhenius方程推导再结晶温度与G0、N0、Qn、Qg之间的函数关系，涉及多个步骤的综合运用和机理的深度解释。解题过程需要理解并应用J-M方程，进行数学推导和物理意义的解释，步骤复杂且对知识点的掌握深度要求高。因此，在该题型内属于最高难度等级5。" + "reasoning": "题型: 题目要求解释和论述界面、表面和位错对原子扩散的影响，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目要求分析界面、表面和位错对金属或合金中原子扩散的影响，并解释其作为快速扩散路径的机理。这需要综合运用多个概念（如扩散机制、晶体缺陷等），进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解界面、表面和位错的基本概念，还需要综合运用这些知识来分析它们对金属或合金中原子扩散的影响机制。正确选项涉及复杂现象的全面分析，需要考生具备机理深度解释的能力，能够将多个知识点联系起来进行推理和综合判断。这种题目在选择题型中属于对知识掌握深度和综合分析能力要求极高的类型。" }, { - "idx": 2431, - "question": "Is the diffusion in oxide ceramics a vacancy exchange mechanism or a rotary exchange mechanism?", - "answer": "The bonding in oxide ceramics is ionic bonding, and the diffusion mechanism in ionic crystals is primarily the vacancy exchange mechanism. The activation energy for the rotary exchange mechanism is too high and often disrupts the ionic bonding, so it cannot be the diffusion mechanism.", + "idx": 3256, + "question": "Describe the recovery mechanism at low temperatures of 0.1~0.3Tm", + "answer": "Recovery at 0.1~0.3Tm low temperatures primarily involves the movement of point defects, where vacancies and interstitial atoms migrate to grain boundaries or dislocations and annihilate, the recombination of vacancies and interstitial atoms, and the aggregation of vacancies to form vacancy pairs or vacancy clusters, leading to a significant reduction in point defect density.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释和论述扩散机制的类型，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目要求分析氧化物陶瓷中的扩散机制，涉及离子键合、空位交换机制和旋转交换机制的对比，需要综合运用材料科学中的扩散理论和晶体缺陷知识，进行机理的解释和推理分析。这超出了简单记忆或基本应用的范围，属于较为复杂的分析和综合运用层次。 | 难度: 在简答题题型中，该题目属于机理深度解释难度。题目要求考生不仅了解氧化物陶瓷中的扩散机制，还需要分析比较空位交换机制和旋转交换机制的差异，并基于离子键的特性进行推理。这需要考生具备扎实的材料科学基础知识和一定的分析推理能力，但尚未达到全面分析复杂现象的最高难度。" + "reasoning": "题型: 题目要求描述低温下的恢复机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释低温下的回复机制，涉及点缺陷的迁移、湮灭和聚集等微观过程，需要综合运用材料科学中的缺陷理论和热力学知识，进行机理层面的分析和解释。这超出了简单记忆或基本应用的范畴，属于需要深入理解和综合分析的内容。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求对低温恢复机制进行全面的机理解释，涉及点缺陷（空位和间隙原子）的迁移、复合以及聚集形成空位对或空位团簇等复杂现象的综合分析。这不仅需要深入理解材料科学中的缺陷理论，还需要能够将这些概念综合运用来解释具体的恢复过程。此外，题目还要求对温度范围（0.1~0.3Tm）的影响有清晰的认识，进一步增加了题目的复杂性和难度。因此，在选择题型中，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 3397, + "question": "Why can't Cr12MoV steel be turned into stainless steel through heat treatment?", + "answer": "Because Cr is the main factor that makes steel corrosion-resistant. It can increase the electrode potential of the steel. If its mass fraction is small (below 13 %), the electrode potential cannot be significantly increased, nor can a single-phase structure be formed, so the corrosion resistance of the steel cannot be significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Cr12MoV钢不能通过热处理变成不锈钢，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释Cr12MoV钢不能通过热处理转变为不锈钢的原因，涉及Cr元素对钢的耐腐蚀性能的影响机制，包括电极电位的变化和单相结构的形成条件。这需要综合运用材料科学中的合金元素作用原理、热处理对组织性能的影响以及腐蚀机制等多方面知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3459, + "question": "Based on the role of alloying elements used in stainless steel, analyze the main characteristics of austenitic stainless steel? What are the main shortcomings? How to prevent or overcome them?", + "answer": "Austenitic stainless steel belongs to nickel-chromium steel, which has excellent corrosion resistance and heat resistance. However, intergranular corrosion may occur at 450~850°C. It is usually prevented by reducing the mass fraction of carbon, adding elements that can form stable carbides (such as Ti), and applying appropriate heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析奥氏体不锈钢的主要特性、主要缺点以及如何预防或克服这些缺点，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求分析奥氏体不锈钢的主要特性、主要缺点以及预防或克服这些缺点的方法，涉及多个知识点的综合运用和推理分析。需要理解合金元素在不锈钢中的作用、奥氏体不锈钢的性能特点、晶间腐蚀的机理以及预防措施等，思维过程较为深入和复杂。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握不锈钢中合金元素的作用，还需要深入理解奥氏体不锈钢的主要特性、主要缺点及其预防措施。这涉及到多个复杂概念的整合，包括腐蚀机理、合金元素的影响以及热处理工艺的应用。此外，正确选项中的内容需要考生具备综合分析和推理能力，能够将理论知识应用于实际问题的解决。因此，在选择题型内，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 3204, + "question": "How does increasing undercooling refine grains?", + "answer": "Increasing the undercooling ΔT causes both N and Vg to increase, but the growth rate of N is greater than that of Vg. Therefore, the value of N/Vg increases, meaning z becomes larger.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释undercooling如何细化晶粒，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要解释增加过冷度如何细化晶粒，涉及成核率（N）和生长速率（Vg）的变化及其相对关系，要求综合运用成核与生长理论进行机理分析，思维过程较深入。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解过冷度（ΔT）对晶粒细化（N/Vg）的影响机制，还需要综合运用成核率（N）和生长速率（Vg）的动态关系进行推理分析。正确选项涉及多变量相互作用（N和Vg增速差异）的机理解释，且需要推导最终结论（z值变化），这显著超出了基础概念记忆或简单比较的认知层次，完全符合\"复杂现象全面分析\"的能力要求。" + }, + { + "idx": 4424, + "question": "What influence does the presence of alloying elements (other than carbon) have on the shape of a herdenability curve? Briefly explain this effect.", + "answer": "The presence of alloying elements (other than carbon) causes a much more gradual decrease in hardness with position from the quenched end for a hardenability curve. The reason for this effect is that alloying elements retard the formation of pearlitic and bainitic structures which are not as hard as martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释合金元素对淬透性曲线形状的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金元素对淬透性曲线形状的影响，并简要说明这种效应的原因。这需要综合运用材料科学中的相变理论、合金元素的作用机制以及淬透性曲线的理解，进行推理分析和机理解释。涉及的知识点较为复杂，且需要将多个概念关联起来进行综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4382, + "question": "Explain why tempered martensite is much harder and stronger.", + "answer": "Tempered martensite is harder and stronger inasmuch as there is much more ferrite-cementite phase boundary area for the smaller particles; thus, there is greater reinforcement of the ferrite phase, and more phase boundary barriers to dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体更硬更强，需要文字解释和论述，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释回火马氏体硬度与强度的机理，涉及相界面对位错运动的阻碍作用以及铁素体相的强化机制，需要综合运用材料科学中的相变、位错理论和强化机制等知识进行推理分析。 | 难度: 在选择题中属于最高难度等级，题目要求深入理解马氏体回火过程中的相变机理，并能分析相界面对位错运动的阻碍作用。正确选项涉及多尺度（相界面积、颗粒尺寸、强化机制）的综合分析，需要考生具备将微观结构特征与宏观力学性能关联的高级推理能力。这种复杂现象的全方位解释在选择题型中属于对知识深度和应用能力的最高要求。" + }, + { + "idx": 2271, + "question": "For a φ5mm carbon steel sample with a carbon mass fraction of w_c=0.012, after quenching at 860°C and then tempering, how will the microstructure change during the tempering process?", + "answer": "For carbon steel with w_c=0.012, when tempered below 100°C, carbon atoms form carbon-rich regions; during tempering at 100~200°C, a large number of fine carbides precipitate, resulting in a slight increase in hardness; during tempering at 200~300°C, retained austenite transforms into tempered martensite (or bainite), causing an increase in hardness, but at the same time, the hardness of martensite decreases, so overall, the hardness change is minimal; when tempered above 300°C, carbides continue to precipitate, followed by carbide growth and spheroidization, while the α phase undergoes recovery and recrystallization, leading to a decrease in hardness and an increase in toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述碳钢样品在回火过程中微观结构的变化过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析碳钢在回火过程中微观结构的变化，涉及多个温度阶段的相变和性能变化，需要综合运用材料科学中的相变理论、热处理原理和显微组织分析知识。解答过程需要对不同温度下的回火机制进行推理和解释，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对碳钢在回火过程中的微观组织变化有深入的理解，包括不同温度区间内的碳原子行为、碳化物析出、残余奥氏体转变以及α相的回复再结晶等复杂现象。解题需要综合运用材料科学中的相变理论、热处理原理和显微组织分析知识，进行多步骤的推理和机理解释。这种题目不仅考察知识点的记忆，更强调对复杂现象全面分析的能力，因此在选择题型中属于最高难度。" + }, + { + "idx": 791, + "question": "2. The concentration of structural defects in non-stoichiometric compounds is related to the nature and pressure of the surrounding atmosphere. Analyze how the density of the non-stoichiometric compounds Fe1-xO and Zn1+xO will change if the partial pressure of the surrounding oxygen atmosphere is increased.", + "answer": "If the partial pressure of the surrounding oxygen atmosphere is increased, the value of x in the non-stoichiometric compound Fe1-xO increases, leading to an increase in the concentration of cation vacancies, which results in a decrease in the density of Fe1-xO. Similarly, if the partial pressure of the surrounding oxygen atmosphere is increased, the value of x in the non-stoichiometric compound Zn1+xO decreases, leading to a reduction in the concentration of interstitial cations, which also results in a decrease in the density of Zn1+xO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析非化学计量化合物中结构缺陷浓度与周围氧气分压的关系，并解释其对密度的影响。答案需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析非化学计量化合物中结构缺陷浓度与周围氧气分压的关系，并解释其对密度的影响。这需要综合运用缺陷化学、非化学计量化合物的性质以及环境条件对材料性能的影响等多方面知识，进行推理分析和机理解释。思维过程涉及多个概念的关联和综合分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅理解非化学计量化合物的基本概念，还需要深入掌握缺陷化学的机理，能够分析氧分压变化对两种不同类型非化学计量化合物（Fe1-xO和Zn1+xO）缺陷浓度和密度的不同影响。解题需要综合运用多个知识点，包括缺陷类型、缺陷反应方程、质量作用定律等，并进行复杂的推理分析。此外，题目涉及两种化合物的对比分析，增加了思维复杂度，完全符合选择题型中\"复杂现象全面分析\"的最高难度标准。" + }, + { + "idx": 2222, + "question": "How to distinguish dynamic and static recovery, and dynamic and static recrystallization from the microstructure", + "answer": "During static recovery, clear subgrain boundaries can be observed, while static recrystallization forms equiaxed grains. In contrast, dynamic recovery forms cellular substructures, and dynamic recrystallization produces dislocation-tangled cells within equiaxed grains, which are finer than those formed by static recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来区分动态和静态恢复以及动态和静态再结晶的微观结构特征，答案提供了详细的描述和对比，符合简答题的特点。 | 知识层次: 题目要求区分动态和静态回复以及动态和静态再结晶的微观结构特征，这需要对不同过程形成的微观结构有深入的理解和分析能力。不仅需要记忆各种结构的特征，还需要综合比较和解释不同过程之间的差异，涉及多个概念的关联和综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解动态和静态恢复、动态和静态再结晶的基本概念，还需要能够从微观结构特征上准确区分这四种现象。正确选项涉及多个复杂微观结构的对比分析（如亚晶界、等轴晶、胞状亚结构、位错缠结等），并需要综合运用材料科学原理进行机理层面的解释。这种题目在选择题中属于对知识深度和综合分析能力要求极高的类型，完全符合\"复杂现象全面分析\"的等级5标准。" + }, + { + "idx": 974, + "question": "How does the third component affect binary diffusion?", + "answer": "The third component can have different effects on binary diffusion, such as Mo and W reducing the diffusion coefficient of C in γ-Fe; Co and Si accelerating the diffusion of C; Mn and Ni having little effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第三组分对二元扩散的影响，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释第三组分对二元扩散的影响，并列举了不同元素的具体作用。这需要综合运用扩散理论、理解不同元素在材料中的行为，并进行机理上的解释。涉及多个概念的关联和综合分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3373, + "question": "What is the reason why alloying elements improve the tempering stability of steel?", + "answer": "Non-carbide forming elements have the effect of delaying the decomposition of martensite. This is because they can dissolve into ε-carbide and stabilize it, slowing down the aggregation rate of carbides. Compared to carbon steel, the final decomposition temperature of martensite may be delayed to 350-500℃, which is 100-150℃ higher than that of carbon steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金元素提高钢的回火稳定性的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释合金元素提高钢的回火稳定性的机理，涉及非碳化物形成元素对马氏体分解的延迟作用、ε-碳化物的稳定化以及碳化物聚集速率的减缓等复杂过程。这需要综合运用材料科学中的相变理论、合金化原理和热力学知识，进行深入的推理分析和机理解释。 | 难度: 在选择题中属于最高难度等级，题目要求考生深入理解合金元素对钢回火稳定性的影响机理，包括非碳化物形成元素如何延迟马氏体分解、稳定ε碳化物以及减缓碳化物聚集速率等复杂现象。需要综合运用材料科学知识进行推理分析，并解释背后的物理冶金原理，这远超出简单记忆或基础理解的范畴。" + }, + { + "idx": 1723, + "question": "Summarize the grain boundary strengthening mechanism in the application of dislocation theory in materials science, considering the factors affecting the strength of metal materials", + "answer": "Grain boundary strengthening, according to the Hall-Petch formula, essentially means that additional stress is required for dislocations to cross grain boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对晶界强化机制进行总结，并考虑影响金属材料强度的因素，需要文字解释和论述，而不是选择、判断或计算。答案也提供了简要的解释，符合简答题的特征。 | 知识层次: 题目要求总结晶界强化机制，并应用位错理论进行解释，同时考虑影响金属材料强度的因素。这需要综合运用多个概念（晶界、位错、Hall-Petch关系等），进行机理层面的分析和解释，涉及较高层次的认知能力和思维深度。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2726, + "question": "Are the types of dislocations the same at each point on a dislocation loop?", + "answer": "Judging by the angle between the dislocation line and the Burgers vector, if the Burgers vector of a dislocation loop is perpendicular to the dislocation line at each point on the loop, then the nature of the dislocations is the same at each point on the loop, all being edge dislocations; however, if the Burgers vector of the dislocation loop is parallel to the plane where the dislocation line lies, then some are pure edge dislocations, some are pure screw dislocations, and others are mixed dislocations; when the Burgers vector intersects the dislocation loop line at a certain angle, although each point on this dislocation loop is a mixed dislocation, the edge and screw components at each point are different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对位错环上各点位错类型是否相同进行解释和论述，答案提供了详细的文字解释，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析位错环上各点位错类型的异同，需要理解位错线与伯格斯矢量的角度关系，并综合运用边缘位错、螺型位错和混合位错的概念进行推理分析。这涉及多个概念的关联和综合运用，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用位错理论中的多个核心概念（如位错线、伯格斯矢量、刃型位错、螺型位错、混合位错等），并能够根据伯格斯矢量与位错线之间的角度关系进行复杂的推理分析。解题时需要理解并应用位错环上不同位置位错性质的动态变化，涉及三维空间想象和矢量分析能力。这种需要全面分析复杂现象并作出机理深度解释的题目，在选择题型中属于最具挑战性的类型。" + }, + { + "idx": 581, + "question": "Analyze the effect of stacking fault energy on the thermoplastic deformation of metals.", + "answer": "High stacking fault energy metals mainly undergo recovery softening during thermoplastic deformation; low stacking fault energy metals mainly undergo recrystallization softening, and their stress-strain curves exhibit different characteristics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析堆垛层错能对金属热塑性变形的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析堆垛层错能对金属热塑性变形的影响，涉及不同堆垛层错能金属的软化机制（回复软化和再结晶软化）及其应力-应变曲线特征的差异。这需要综合运用材料科学中的位错理论、热力学和动力学知识，进行机理层面的解释和关联分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1265, + "question": "From the perspective of bonding, discuss why metals generally exhibit higher plasticity or ductility compared to inorganic non-metals.", + "answer": "The bonding in metallic materials is primarily metallic bonding, while transition metals exhibit a mix of metallic and covalent bonding. Inorganic non-metallic materials are mainly bonded through ionic and covalent bonds. Metallic bonding is characterized by electron delocalization, where free electrons can move throughout the crystal, giving the bond no saturation or directionality. Due to the absence of saturation and directionality, each atom can potentially bond with more atoms and tends to form low-energy close-packed structures. When metals undergo deformation under force, the relative positions of atoms change without breaking the metallic bonds, which grants metals excellent ductility. Ionic bonding involves ions as the bonding units, where the bond is maintained by electrostatic attraction between positive and negative ions. This bond is strong, making it difficult for free electrons to move. Covalent bonds are formed between two or more atoms with similar electronegativity through shared electron pairs. Each bond has a fixed orientation, coordination numbers are relatively small, and the bonds are strong. Shared electron pairs between adjacent atoms cannot move freely, giving covalent bonds directionality and saturation, which generally results in poor plasticity and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合角度讨论金属与无机非金属的塑性差异，需要详细的文字解释和论述，答案也呈现为一段完整的论述性文字，符合简答题的特征。 | 知识层次: 题目要求从化学键的角度深入分析和比较金属与无机非金属材料的塑性差异，涉及多种键合类型（金属键、离子键、共价键）的特性及其对材料性能的影响机制。需要综合运用材料科学和化学键理论的知识，进行推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从键合角度深入分析金属与无机非金属的塑性差异，涉及多种键合类型（金属键、离子键、共价键）的特性比较，以及这些特性如何影响材料的宏观性能。解题需要综合运用材料科学中的键合理论，理解电子行为（如离域电子与局域电子的区别）、键的方向性与饱和性等抽象概念，并能将这些微观机制与宏观塑性表现建立逻辑关联。这种在选择题中要求进行多层次的机理解释和复杂现象分析，远超一般选择题的概念识别或简单应用要求。" + }, + { + "idx": 999, + "question": "Please analyze the characteristics and mechanisms of grain refinement strengthening.", + "answer": "Grain refinement strengthening: It is caused by the increase in the number of grains and the decrease in their size, which increases the resistance to continuous dislocation slip, leading to strengthening. At the same time, the dispersion of slip also enhances plasticity. This strengthening mechanism is the only one that can simultaneously increase both strength and plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶粒细化强化的特点和机制，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求分析晶粒细化强化的特性和机制，涉及对材料科学中强化机理的深入理解和解释，需要综合运用相关知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求分析晶粒细化强化的特性和机理，涉及多个复杂概念的整合，包括晶粒数量增加、尺寸减小对位错滑移阻力的影响，以及滑移分散对塑性的增强作用。此外，题目还强调这是唯一能同时提高强度和塑性的强化机制，需要考生具备深入的材料科学知识，能够进行综合分析和机理解释。这种题目不仅测试知识点的记忆，更考察对复杂现象的理解和推理能力，因此在选择题型中属于最高难度。" + }, + { + "idx": 2671, + "question": "Compared with question 1, explain the reasons for the difference.", + "answer": "Reasons for the difference: different crystal structures and different atomic radii; when the coordination number of atoms in the crystal structure decreases, the atomic radius contracts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释晶体结构和原子半径差异的原因，涉及对晶体结构变化与原子半径关系的深入理解和分析，需要综合运用材料科学知识进行推理和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2013, + "question": "Why can only the two components of substitutional solid solutions mutually dissolve infinitely, while interstitial solid solutions cannot?", + "answer": "This is because when a solid solution forms, the dissolution of solute atoms causes lattice distortion in the solvent structure, thereby increasing the system's energy. The greater the difference in atomic size between the solute and solvent, the more severe the lattice distortion, leading to higher distortion energy, lower structural stability, and smaller solubility. Generally, the lattice distortion caused by solute atoms in interstitial solid solutions is more significant, so they cannot mutually dissolve infinitely but only have limited solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么置换固溶体可以无限互溶而间隙固溶体不能，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释置换固溶体和间隙固溶体在无限互溶方面的差异，涉及晶格畸变、系统能量变化、原子尺寸差异对溶解度的影响等复杂机理分析，需要综合运用多个概念并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 807, + "question": "Briefly describe the growth mechanism of pure metal crystals", + "answer": "The crystal growth mechanism refers to the microscopic growth mode of crystals, which is related to the liquid-solid interface structure. For substances with rough interfaces, since about $50\\\\%$ of the atomic positions on the interface are vacant, these vacancies can accept atoms. Therefore, liquid atoms can individually enter the vacancies and connect with the crystal, causing the interface to advance perpendicularly along its normal direction, resulting in continuous growth. For crystals with smooth interfaces, growth does not occur through the attachment of individual atoms but rather through homogeneous nucleation, forming a two-dimensional nucleus one atomic layer thick on the crystallographic facet interface, creating a step between the new nucleus and the original interface. Individual atoms can then fill in the step, allowing the two-dimensional nucleus to grow laterally. Once the layer is filled, a new two-dimensional nucleus forms on the new interface, and the process repeats. If the smooth interface of the crystal has an exposed screw dislocation, the interface becomes a spiral surface, forming a step that never disappears. Atoms attach to the step, enabling crystal growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述纯金属晶体的生长机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述纯金属晶体的生长机制，涉及液体-固体界面结构、粗糙界面和光滑界面的生长模式、二维核形成、螺旋位错等复杂概念。需要综合运用材料科学中的晶体生长理论，进行机理的解释和分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解金属晶体生长的微观机制，涉及粗糙界面和光滑界面的不同生长方式，以及二维核形成和螺旋位错等复杂概念。解题需要综合运用材料科学知识，进行机理深度解释和复杂现象全面分析，对知识掌握深度和推理能力要求极高。" + }, + { + "idx": 1150, + "question": "What is constitutional supercooling?", + "answer": "During the solidification of a solid solution alloy, the distribution of solute in the liquid phase changes, which alters the alloy's melting point. Even if the actual temperature distribution remains unchanged, the degree of supercooling at the solid-liquid interface front will vary. Therefore, the supercooling of a solid solution alloy is determined by both the changing alloy melting point and the actual temperature distribution. This type of supercooling caused by changes in liquid phase composition is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"constitutional supercooling\"进行文字解释和论述，答案提供了详细的定义和形成机制说明，符合简答题的特征。 | 知识层次: 题目要求解释constitutional supercooling的机理，涉及固溶体合金凝固过程中溶质分布变化对熔点的影响，以及实际温度分布与合金熔点变化之间的相互作用。这需要综合运用材料科学中的凝固理论、相变原理和热力学知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2333, + "question": "Why are ionic solids medium-density materials?", + "answer": "The structural unit of an ionic crystal is an electrically neutral molecule composed of a set of positive and negative ions. The stacking of ions in ionic crystals must consider the role of electrical charge. In actual ionic crystals, the radii of positive and negative ions differ significantly. Generally, the negative ions are stacked in a cubic or hexagonal close-packed arrangement, while the smaller positive ions fill the gaps in this close-packed structure. This filling method of positive ions can uniformly separate the negative ions, increasing the distance between them so they no longer contact each other. Such a stacking structure can achieve higher packing density than covalently bonded crystals while satisfying the requirement of alternating arrangement of oppositely charged ions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么离子固体是中等密度材料，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释离子固体中等密度的原因，涉及离子晶体的结构单元、电荷作用、离子半径差异、堆积方式以及填充方式等多个概念的综合分析。需要深入理解离子晶体的结构特点，并能将这些概念关联起来进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解离子晶体的基本结构特征，还需要综合运用晶体堆积理论、离子半径差异的影响、电荷平衡原理等多重概念进行机理层面的深度解释。正确选项涉及复杂的空间堆积分析（立方/六方密堆积）、离子填充机制（间隙填充）以及静电作用对晶体密度的综合影响，这远远超出了选择题通常考查的单一知识点记忆或简单应用层面。考生必须能够将多个高阶概念整合推理，才能准确理解离子晶体中等密度的形成机制，这完全符合\"复杂现象全面分析\"的知识层次要求。" }, { "idx": 2837, @@ -525,43 +6909,175 @@ "knowledge_level_name": "复杂分析", "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案是基于对晶体结构和滑移系统的分析，没有涉及选择题的选项、判断题的对错判断或计算题的数值计算。 | 知识层次: 题目要求分析MgO晶体在特定应力方向下的滑移行为，需要综合运用晶体学知识（标准投影图）、滑移系统特性以及应力方向与滑移面的几何关系进行推理分析。这涉及多个概念的关联和深层次理解，属于复杂分析范畴。 | 难度: 在简答题-复杂分析题型中，该题目要求综合运用晶体学知识、标准投影图分析以及滑移系统特性进行推理。需要深入理解立方晶系的几何关系，并能通过空间思维判断不存在满足条件的应力方向。解题过程涉及多步骤逻辑推导和机理解释，属于该题型内对综合分析能力要求最高的复杂现象全面分析层级。" + "reasoning": "题型: 题目要求通过文字解释和论述来分析在特定条件下滑移不会发生的方向，答案提供了详细的解释和论证过程，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析MgO晶体结构中的滑移系统特性，并基于立方晶系标准投影图进行空间几何关系的推理，判断在何种拉伸或压缩方向下滑移不会发生。这需要综合运用晶体学知识、滑移系统特性以及空间几何分析能力，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" }, { - "idx": 3017, - "question": "The close-packed {111} planes of the face-centered cubic (fcc) structure are stacked in the sequence ABCABC..., while the close-packed {0001} planes of the hexagonal close-packed (hcp) structure are stacked in the sequence ABABAB.... Explain how and by introducing what type of dislocations the fcc structure can be entirely transformed into the hcp structure.", - "answer": "Accordingly, if the C-layer atoms are moved to the E position (or E2, E positions, all referring to projection positions), the arrangement of the C atomic layer can be changed to that of the A atomic layer. If the B atomic layer is correspondingly moved at this time, it will change to the arrangement of the C atomic layer, and the A-layer atoms will change to the arrangement of the B layer. Therefore, introducing a partial dislocation of $\\frac{a}{6}(11\\overline{2})$ (or $\\frac{a}{6}(1\\overline{2}1)$, or $\\frac{a}{6}(211)$) into the second layer of the ABCABC... stacking and allowing it to sweep through the third layer and subsequent layers can change the atomic arrangement to ABABCABC.... Then, introducing the same dislocation into the fourth layer and performing the same operation can change the atomic arrangement to ABABABCABC..., and so on, resulting in the ABABAB... stacking sequence. In summary, by introducing partial dislocations of $\\frac{a}{6}(11\\overline{2})$ (or $\\frac{a}{6}(1\\overline{2}1)$, or $\\frac{a}{6}(211)$) into every second layer (111) plane (where n = 1, 2, 3,...) of the fcc structure's ABCABC... stacking, i.e., introducing a partial dislocation every other layer in the (111) plane, the stacking sequence can be changed to ABABAB..., thereby transforming it into the hcp stacking structure.", + "idx": 834, + "question": "Indicate the fourth main mechanism of alloy strengthening and explain the reason for its strengthening", + "answer": "Order strengthening. The dislocations in ordered alloys are superdislocations. To cause plastic deformation in the metal, both partial dislocations of the superdislocation need to move simultaneously, thus requiring greater external stress. The bonding force between dissimilar element atoms is stronger than that between similar element atoms, so the ordered arrangement of dissimilar atoms gives ordered alloys higher strength.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释如何通过引入位错将面心立方结构转变为六方密排结构，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求解释如何通过引入特定类型的位错将面心立方结构完全转变为六方密排结构，这需要深入理解晶体结构、位错类型及其对晶体结构转变的影响。解答过程涉及多步推理和综合分析，包括位错类型的选择、位错运动对原子层排列的影响，以及如何通过重复操作实现整个结构的转变。这属于复杂分析层次，需要综合运用晶体学和位错理论的知识。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用晶体结构、位错理论和堆垛序列变换的知识点。解题需要深入理解fcc和hcp结构的堆垛差异，准确描述位错类型（a/6<112>型不全位错）及其引入方式，并完整解释通过位错运动实现结构转变的机理。整个过程涉及多个知识点的综合运用和严密的逻辑推理，在同类题型中属于最高难度的复杂现象全面分析。" + "reasoning": "题型: 题目要求解释合金强化的第四种主要机制及其强化原因，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金强化的第四种主要机制（有序强化）及其强化原因，涉及对超位错、塑性变形机制以及原子间结合力的深入理解和综合分析。需要将多个概念关联起来，并进行机理层面的解释，思维深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" }, { - "idx": 3136, - "question": "What is secondary recrystallization (abnormal growth)?", - "answer": "After recrystallization is completed, continued heating or holding may lead to discontinuous grain growth, where the growth of most grains is inhibited, while a few grains grow rapidly, which is called abnormal growth, also known as secondary recrystallization.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求对“secondary recrystallization (abnormal growth)”进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶（异常生长）这一基本概念的定义和描述，属于基础概念的记忆和理解范畴。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。虽然需要解释\"二次再结晶\"的定义和现象，但不需要阐述复杂的理论体系或进行多层次的逻辑推导。题目要求的是对基础概念的记忆和简单扩展说明，符合等级2对知识掌握深度和解题步骤的要求。" - }, - { - "idx": 3223, - "question": "In the compression test of a magnesium single crystal at room temperature, the [0001] direction coincides with the compression axis. Assuming that the critical resolved shear stress for twinning on the (10\\\\overline{1}2) plane is 10 times that for slip on the (0001) plane, denoted as $\\\\tau_{\\\\mathrm{e}}$, determine whether the crystal will undergo twinning or slip when the compressive stress is sufficiently large, and explain why.", - "answer": "If the compression axis coincides with the [0001] direction, since the slip directions of different slip systems in magnesium are the same, all being <11\\\\overline{2}0> directions, and the slip directions are all perpendicular to the [0001] direction, $\\\\cos\\\\lambda=0$. Therefore, $\\\\sigma_{S}=\\\\frac{\\\\sigma_{C}}{\\\\cos\\\\lambda\\\\cos\\\\phi}=\\\\infty$. No matter how large the pressure is, slip cannot occur. However, the twinning plane is {10\\\\overline{1}2}, and the twinning direction is {10\\\\overline{1}2}. When compressed along the [0001] direction, there is a resolved shear stress. When the external force reaches a certain value, twinning will occur along {10\\\\overline{1}2}<\\\\overline{1}011>{10\\\\overline{1}2}. In this example, the resolved shear stress for twinning has already reached 10 times $\\\\tau_{C}$, so twinning deformation can occur.", + "idx": 1297, + "question": "What are the differences in the nucleation and growth processes among recrystallization, primary recrystallization, and secondary recrystallization?", + "answer": "Recrystallization and primary recrystallization involve nucleation and growth processes; secondary recrystallization only involves a growth process.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释在特定条件下晶体是发生孪生还是滑移，并给出原因。答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求综合运用晶体学知识、滑移和孪生的临界分切应力概念，并进行力学分析。需要理解镁单晶的滑移和孪生系统特性，计算分切应力，并比较不同变形机制的临界条件。涉及多步推理和综合分析，属于复杂分析层次。 | 难度: 在简答题的复杂分析题型中，该题目要求综合运用晶体学、力学和材料变形机理的知识，进行深入的推理分析。具体包括：" + "reasoning": "题型: 题目要求解释和论述不同再结晶过程中的成核和生长过程的差异，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目要求对不同再结晶过程（再结晶、初次再结晶和二次再结晶）的形核和生长过程进行比较和分析，涉及多个概念的关联和机理的解释，需要综合运用知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合理解并区分三种再结晶过程（再结晶、初次再结晶和二次再结晶）的成核与生长机制差异。这需要考生不仅掌握每个过程的定义，还需要深入理解其背后的材料科学机理，并能进行复杂的推理分析。正确选项涉及对二次再结晶特殊性的精确把握（仅生长过程），这体现了对复杂现象的全面分析能力。在选择题型中，这种需要多概念综合比较和机理深度解释的题目属于最难类型。" + }, + { + "idx": 4437, + "question": "What point defects are possible for Al2O3 as an impurity in MgO?", + "answer": "For every Al3+ ion that substitutes for Mg2+ in MgO, a single positive charge is added. Thus, in order to maintain charge neutrality, either a positive charge must be removed or a negative charge must be added. Negative charges are added by forming O2- interstitials, which are not likely to form. Positive charges may be removed by forming Mg2+ vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al2O3作为杂质在MgO中可能形成的点缺陷类型，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要分析Al2O3作为杂质在MgO中可能形成的点缺陷，并解释电荷平衡机制。这涉及对点缺陷类型、电荷补偿机制的理解，以及综合分析不同缺陷形成的可能性（如O2-间隙与Mg2+空位的形成倾向）。需要较高的推理分析和机理解释能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解点缺陷的基本概念，还需要综合运用电荷平衡原理、晶体结构知识以及缺陷形成的能量学分析（如O2-间隙形成的不可能性）。正确选项涉及多步逻辑推理：从Al3+替代导致的电荷变化，到维持电中性的两种可能机制（阳离子空位或阴离子间隙），再到基于能量学排除其中一种机制。这种需要综合多个高阶概念并进行机理深度解释的题目，在选择题型中属于最复杂的分析层次。" + }, + { + "idx": 1687, + "question": "What are the differences in the roles of slip and twinning in the mechanisms of plastic deformation?", + "answer": "Slip is the primary mechanism of plastic deformation. When the slip system is unfavorable for slip deformation to occur, twinning can alter the orientation of the slip system relative to the external force, enabling further slip processes to take place.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述滑移和孪生在塑性变形机制中的不同作用，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释滑移和孪生在塑性变形机制中的不同作用，需要综合运用材料科学中的变形机制知识，进行推理分析和机理解释。这涉及到对两种变形机制的深入理解及其在特定条件下的相互作用，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 1350, + "question": "Analyze the essential similarities between work hardening, fine grain strengthening, solid solution strengthening, and second-phase strengthening", + "answer": "Similarities: All involve hindering dislocation movement, increasing the resistance to dislocation glide, thereby strengthening the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析四种强化机制的相似性，需要文字解释和论述，答案也是以文字形式给出，符合简答题的特征。 | 知识层次: 题目要求分析四种强化机制的相似性，涉及对位错运动阻碍机理的综合理解和比较分析，需要深入理解材料强化机制的本质，并进行概念间的关联和推理分析。这超出了简单记忆或基本应用层次，属于需要综合运用知识进行复杂分析的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求分析四种强化机制的相似性，涉及多个复杂概念的综合运用和机理解释。正确选项需要深入理解位错运动受阻的共同本质，并能够将不同强化机制的微观机理联系起来。这种题目不仅考察知识点的记忆，更要求考生具备高阶的分析推理能力，能够从不同现象中抽象出共同规律，属于复杂现象全面分析的层次。" + }, + { + "idx": 2255, + "question": "Analyze the main reasons for dislocations promoting nucleation in the case where the composition of the new phase differs from that of the parent phase", + "answer": "When the composition of the new phase differs from that of the parent phase, the segregation of solute atoms along dislocation lines (forming Cottrell atmospheres) facilitates the precipitation of the new phase and also promotes nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析并解释位错促进新相成核的主要原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析位错促进新相形核的主要原因，涉及溶质原子在位错线上的偏聚（Cottrell气团）及其对新相析出的影响。这需要综合运用位错理论、相变原理和扩散知识，进行机理层面的解释和推理分析，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1717, + "question": "What is the effect of the interaction between dislocations and solute atoms on the properties of metallic materials?", + "answer": "The interaction between dislocations and solute atoms in alloys forms Cottrell atmospheres, leading to yield phenomena and strain aging.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述位错与溶质原子相互作用对金属材料性能的影响，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释位错与溶质原子相互作用对金属材料性能的影响机制，涉及位错理论、溶质原子扩散、Cottrell气团形成等复杂概念的综合运用和机理解释，需要深入分析和推理。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1920, + "question": "Explain the formation conditions and characteristics of structural defects in anion vacancy-type non-stoichiometric compounds", + "answer": "Under reducing atmosphere, high valence state changes to low valence state, n-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结构缺陷的形成条件和特征，需要文字解释和论述，而不是选择、判断或计算。答案提供了简要的解释，符合简答题的特点。 | 知识层次: 题目要求解释阴离子空位型非化学计量化合物的结构缺陷形成条件和特征，涉及还原气氛下的价态变化和半导体类型判断，需要综合运用材料科学、固体化学和半导体物理等多学科知识，进行机理分析和推理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解非化学计量化合物中阴离子空位型结构缺陷的形成条件和特征，还需要掌握还原气氛下高价态向低价态转变的机理，以及n型半导体的相关特性。这些知识点涉及复杂的材料科学原理和深入的机理分析，需要考生具备综合运用知识、推理分析和解释机理的能力。在选择题型中，这类题目通常要求考生在多个复杂概念之间建立联系，并准确识别正确选项，因此难度最高。" + }, + { + "idx": 3194, + "question": "Briefly describe the mechanism of crystal growth.", + "answer": "The mechanism of crystal growth refers to the microscopic growth mode of crystals, which is related to the structure of the liquid/solid interface. For substances with rough interfaces, approximately $50\\\\%$ of the atomic positions on the interface are vacant. These vacancies can accept atoms, allowing liquid atoms to individually occupy the vacancies and connect with the crystal. The interface moves perpendicularly along its normal direction, exhibiting continuous growth. For crystals with smooth interfaces, growth does not occur through the attachment of individual atoms. Instead, it proceeds via homogeneous nucleation, forming a two-dimensional nucleus one atomic layer thick on the crystallographic facet interface. This creates a step between the new nucleus and the original interface. Individual atoms can then fill in the step, enabling lateral growth of the two-dimensional nucleus. Once the layer is filled, a new two-dimensional nucleus forms on the new interface, and the process repeats. If the smooth interface of a crystal has an exposed screw dislocation, the interface becomes a spiral surface, forming a step that never disappears. Atoms attach to this step, allowing the crystal to grow.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶体生长的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求详细描述晶体生长的微观机制，涉及粗糙界面和平滑界面的不同生长模式，以及二维成核和螺旋位错等复杂概念。需要综合运用材料科学中的晶体生长理论，进行机理的解释和分析，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对晶体生长的微观机制进行深度解释，涉及粗糙界面和光滑界面的不同生长模式，以及二维成核和螺旋位错等复杂概念的综合运用。正确选项不仅需要理解多个专业术语和物理过程，还需要将这些概念有机串联起来解释完整的生长机理。这种需要同时掌握界面结构、原子附着方式、生长动力学等多维度知识的题目，在选择题中属于对专业知识和分析能力要求极高的类型，完全符合\"复杂现象全面分析\"的等级5标准。" + }, + { + "idx": 2551, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of bonding types.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Ionic or covalent bondsPrimarily metallic bondsMetallic bondsMixed type: metallic bonds between metal atoms, and covalent bonds between metal and metalloid atoms
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求总结和比较不同类型的金属间化合物，需要文字解释和论述，答案以表格形式呈现了详细的比较信息，符合简答题的特征。 | 知识层次: 题目要求对不同类型的金属间化合物（如价化合物、电子化合物、TCP相、间隙相等）的键合类型进行总结和比较，这需要综合运用多个知识点，进行推理分析和机理解释。不仅需要理解每种化合物的键合特性，还需要进行比较和综合分析，思维过程的深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2367, + "question": "After washing and drying clothes containing artificial fibers, the clothes shrink. Please explain.", + "answer": "The fiber polymers in clothes made of artificial fibers are stretched and have a certain crystalline state. When the clothes are washed, the stretched state is removed, causing the polymer chains to return to a curled state. This is because the value of the curled state is greater than that of the stretched state, resulting in the clothes shrinking.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释人工纤维衣物洗涤后缩水的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释人工纤维衣物洗涤后收缩的机理，涉及聚合物链的拉伸状态、结晶态变化以及能量状态比较等复杂概念。需要综合运用高分子材料学知识进行推理分析，解释现象背后的物理化学原理，属于机理层面的解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1548, + "question": "Taking the Al-4.5%Cu alloy as an example, explain the hardness changes during the 130% aging process", + "answer": "The formation of GP zones will increase the hardness of the material (the first aging peak). After prolonged aging, the GP zones dissolve, and the hardness decreases. The formation of θ′′ causes the hardness to continue increasing (the second aging peak). When θ′′ completely dissolves and transforms into θ′ and θ′ transforms into θ, the hardness begins to decrease.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金在130%时效过程中硬度变化的原因，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金在130%时效过程中硬度的变化，涉及多个时效阶段的相变过程（GP区、θ′′、θ′和θ的形成与溶解）及其对硬度的影响。这需要综合运用材料科学中的相变理论、时效硬化机理等知识，进行多步骤的推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题中属于最高难度，需要全面理解Al-4.5%Cu合金时效过程中的多个相变阶段及其对硬度的影响机制。题目要求考生不仅掌握GP区、θ′′、θ′和θ相的形成顺序，还要理解这些相变对材料硬度变化的复杂影响（包括两次硬度峰值和中间下降过程）。这需要综合运用材料科学知识进行推理分析，属于复杂现象全面分析的层次。" + }, + { + "idx": 2379, + "question": "Can all parts of a dislocation loop be screw dislocations? Why?", + "answer": "The Burgers vector of a screw dislocation is parallel to the dislocation line. A single dislocation has only one Burgers vector, and a dislocation loop cannot be parallel to one direction everywhere. Therefore, a dislocation loop cannot have all its parts as screw dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么位错环的所有部分不能都是螺型位错，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对位错环的性质进行深入分析，涉及位错线的方向与Burgers矢量的关系，需要综合运用位错理论的基本概念进行推理和解释。这超出了简单记忆或直接应用的范畴，属于对材料科学中位错行为的复杂分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1612, + "question": "What are the formation and movement characteristics of Frank partial dislocations in face-centered cubic crystals?", + "answer": "Frank partial dislocations are caused by the removal or insertion of a close-packed plane, and their Burgers vector is perpendicular to the slip plane. Therefore, Frank partial dislocations cannot glide but can only climb.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Frank partial dislocations的形成和运动特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Frank不全位错的形成和运动特性，涉及位错的形成机制、Burgers向量的方向性以及位错滑移和攀移的区别。这需要综合运用位错理论、晶体结构知识以及位错运动的机理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" }, { "idx": 3251, @@ -571,81 +7087,1965 @@ "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", - "difficulty": 4, + "difficulty": 5, "final_level": "Level_5", - "reasoning": "题型: 题目要求描述高温下的回复机制，需要详细的文字解释和论述，答案也提供了详细的机制描述和过程说明，符合简答题的特征。 | 知识层次: 题目要求解释高温下恢复机制的具体过程，涉及位错攀移、多边形化、亚晶合并等多个复杂概念的综合运用和机理解释，需要深入分析和推理。 | 难度: 在简答题-复杂分析题型中，该题目要求对高温恢复机制进行机理深度解释，涉及多个专业概念（如位错攀移、多边形化、亚晶合并等）的综合运用和推理分析。虽然未达到最高级别的复杂现象全面分析（如涉及多机制交互作用或定量计算），但已明显超出基础概念描述层面，属于需要深入理解材料科学原理才能完整回答的问题类型。" + "reasoning": "题型: 题目要求描述高温下的回复机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高温下（>0.5Tm）的回复机制，涉及位错攀移、多边形化、亚晶合并等多个复杂过程及其相互作用。需要综合运用位错理论、扩散机制和显微组织演变等知识进行机理层面的分析，属于需要深度理解和推理的复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解高温恢复机制，包括位错攀移、多边形化、亚晶合并等复杂现象，并能够综合运用这些知识进行机理解释。这需要考生具备扎实的材料科学基础和高级分析能力，远超简单的概念记忆或单一知识点应用。" }, { - "idx": 3327, - "question": "Describe the purpose of quenching", - "answer": "Quenching can significantly improve the strength and hardness of steel. Combined with tempering at different temperatures, it can achieve a balance of strength, hardness, and toughness to meet various requirements.", + "idx": 268, + "question": "Explain from the perspectives of structure and energy why $\\mathrm{D}_{\\rightleftarrows\\mathrm{m}}>\\mathrm{D}_{\\rightleftarrows\\mathrm{m}}>\\mathrm{D}$ within the crystal.", + "answer": "Under the influence of surface forces, the particles on the solid surface undergo polarization, deformation, rearrangement, and cause lattice distortion, making the surface structure different from the interior and placing the surface in a higher energy state. The internal particles of the crystal are arranged periodically, with each particle's force field being symmetrical. The activation energy required for particle migration on the surface is smaller than that within the crystal, resulting in a larger diffusion coefficient. Similarly, the arrangement of particles at grain boundaries differs from the interior, being disordered and containing defects such as vacancies and dislocations, placing them in a state of stress distortion with higher energy. The activation energy required for particle migration at grain boundaries is smaller than that within the crystal, leading to a larger diffusion coefficient. However, compared to the interior of the crystal, particles at grain boundaries are influenced by two grains to reach an equilibrium state, adopting a transitional arrangement with lower energy than surface particles. Thus, the resistance to particle migration is greater, resulting in $\\mathrm{D}_{\\mathrm{~\\rightmoon~}}\\mathrm{\\approx}{}$ the surface.", "question_type": "short_answer", "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求描述淬火的目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查淬火的基本目的和效果，属于对基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目属于概念解释和描述难度等级。题目要求描述淬火的目的，并涉及淬火与回火结合的效果，需要一定的知识理解和描述能力，但不需要复杂的体系阐述或深入分析。属于中等难度的概念解释题。" + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从结构和能量的角度解释晶体中扩散系数的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求从结构和能量的角度解释晶体中不同区域的扩散系数差异，涉及表面、晶界和晶体内部的结构差异、能量状态以及粒子迁移的激活能等复杂概念的综合分析和推理。需要深入理解材料科学中的扩散机制、缺陷理论和能量状态，并进行多方面的关联和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从结构和能量的角度深入解释晶体中不同区域的扩散系数差异，涉及表面力、极化、晶格畸变、晶界缺陷等多个复杂概念的综合运用。解题需要全面分析表面、晶界和晶体内部的结构差异与能量状态，并推理其对扩散激活能和扩散系数的影响机制。这种深度机理解释和复杂现象分析在选择题中属于对知识掌握和逻辑推理能力的最高要求。" }, { - "idx": 3334, - "question": "Explain why the initial structure with fine lamellar pearlite is better using the austenite isothermal formation mechanism.", - "answer": "Increasing the dispersion of carbides can accelerate the transformation from pearlite to austenite.", + "idx": 1921, + "question": "Explain the formation conditions and characteristics of structural defects in cation interstitial non-stoichiometric compounds", + "answer": "Under reducing atmosphere, high valence state changes to low valence state, n-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结构缺陷的形成条件和特征，需要详细的文字论述和解释，而不是简单的选择、判断或计算。答案也提供了具体的解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释阳离子间隙非化学计量化合物的结构缺陷形成条件和特征，涉及还原气氛下的价态变化和半导体类型判断，需要综合运用材料科学中的缺陷化学、半导体物理等知识，进行机理分析和推理。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 93, + "question": "Both MgO (NaCl-type structure) and Li2O (anti-fluorite-type structure) are based on the cubic close packing of oxygen, and the cations are in the gaps of this arrangement. Why are Frenkel-type point defects the main defects in Li2O?", + "answer": "Li occupies octahedral voids. The octahedral voids are larger, making it easier for Li ions to move from their normal lattice sites to interstitial positions, forming Frenkel defects (simultaneous presence of cation vacancies and interstitial cations).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Li2O中Frenkel型点缺陷是主要缺陷，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释Frenkel型点缺陷在Li2O中为主要缺陷的原因，涉及晶体结构、间隙位置、离子迁移等概念的关联和综合分析，需要深入理解晶体缺陷形成的机理和影响因素，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解MgO和Li2O的晶体结构差异，还需要深入掌握Frenkel缺陷的形成机理。正确选项涉及对八面体空隙大小的理解、离子迁移能力的分析，以及缺陷形成的综合解释。这需要考生具备将晶体结构知识、缺陷化学原理和离子迁移特性等多方面知识进行整合分析的能力，属于复杂现象的全面分析层次。在选择题型中，这种需要多维度知识综合运用和深度机理解释的题目最为困难。" + }, + { + "idx": 4622, + "question": "Briefly explain how reflection losses of transparent materials are minimized by thin surface coatings.", + "answer": "The thickness and dielectric constant of a thin surface coating are selected such that there is destructive interference between the light beam that is reflected from the lens-coating interface and the light beam that is reflected from the coating-air interface; thus, the net intensity of the total reflected beam is very low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释透明材料如何通过薄表面涂层减少反射损失，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释如何通过表面涂层最小化透明材料的反射损失，涉及光的干涉原理和涂层材料的选择，需要综合运用光学和材料科学的知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用光学干涉原理、材料介电常数选择以及多层反射的相位关系等复杂概念，通过推理分析解释薄膜涂层如何实现减反射的完整机理。正确选项不仅需要理解破坏性干涉的基本原理，还需要掌握涂层厚度与介电常数的匹配关系，以及两个界面反射光束的相互作用机制。这种需要多维度知识整合和机理深度解释的题目，在选择题型中代表最高层次的认知要求。" + }, + { + "idx": 270, + "question": "When measuring the decomposition rate of alumina monohydrate, it was found that during the isothermal reaction, the mass loss increased linearly with time up to about 50%, and the rate of mass loss was less than the linear law when exceeding 50%. The rate increases exponentially with temperature. Is this a diffusion-controlled reaction or an interface first-order reaction-controlled reaction?", + "answer": "According to the analysis of the kinetic equations for some important solid-phase reactions in Table 8-2 and the G-t/t0.5 curves for various types of reactions in Figure 8-22, it is known from the problem statement that when G ≤ 50%, G-t shows a linear relationship, and when G > 50%, G-t is less than the linear law. This is a diffusion-controlled reaction, and G² = kt.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述反应类型（扩散控制反应或界面一级反应控制反应），答案提供了详细的分析和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析实验数据并判断反应类型，需要综合运用动力学方程和反应机理知识，涉及多步推理和综合分析。不仅需要理解扩散控制和界面一级反应控制的区别，还需要根据G-t关系曲线进行判断，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3250, + "question": "Describe the recovery mechanism at medium temperatures of 0.3~0.5Tm", + "answer": "At medium-temperature recovery of 0.3~0.5Tm, dislocations glide on slip planes, causing dislocations of opposite signs to meet and annihilate, reducing dislocation density, rearranging and recombining within dislocation tangles, and regularizing subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述中等温度下的恢复机制，答案是一段详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述中等温度下的回复机制，涉及位错的滑移、湮灭、重排和亚晶粒的规则化等复杂过程，需要综合运用位错理论、热激活过程和微观结构演变等知识进行机理分析和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生深入理解并综合运用材料科学中的位错理论、恢复机制以及温度对材料性能的影响等多个复杂概念。正确选项不仅描述了位错的滑移和湮灭过程，还涉及到位错密度的减少、位错缠结的重排和重组，以及亚晶粒的规则化等高级内容。这需要考生具备较强的推理分析能力和机理解释能力，能够将多个知识点有机结合起来进行综合判断。因此，在选择题型中，该题目的难度属于最高等级。" + }, + { + "idx": 4467, + "question": "From a molecular perspective, briefly explain the mechanism by which clay minerals become hydroplastic when water is added.", + "answer": "Clays become hydroplastic when water is added because the water molecules occupy regions between the layered molecular sheets; these water molecules essentially eliminate the secondary molecular bonds between adjacent sheets, and also form a thin film around the clay particles. The net result is that the clay particles are relatively free to move past one another, which is manifested as the hydroplasticity phenomenon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从分子角度简要解释黏土矿物在加水后变得具有水塑性的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从分子层面解释黏土矿物加水后产生水塑性的机理，涉及分子间作用力、水分子在层状结构中的行为以及宏观性能变化的关联，需要综合运用材料科学、化学等多学科知识进行推理分析，思维深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1336, + "question": "Explain the cause of the first type of temper brittleness", + "answer": "The first type of temper brittleness occurs due to the precipitation of discontinuous thin-shell-like carbides along the interfaces of martensite laths or plates during martensite decomposition, which reduces the fracture strength of grain boundaries, making them the path for crack propagation and thus leading to brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第一类回火脆性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第一类回火脆性的原因，涉及马氏体分解过程中碳化物的析出行为及其对晶界断裂强度的影响，需要综合运用材料科学中的相变、断裂机理等知识进行推理分析，思维深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解马氏体分解过程中不连续薄壳状碳化物的析出机制，以及其对晶界断裂强度和裂纹扩展路径的影响。这需要综合运用材料科学知识，进行复杂的机理分析和推理，属于复杂现象的全面分析层次。在选择题型中，此类题目对知识点的掌握深度和解题能力要求极高。" + }, + { + "idx": 2206, + "question": "A cold-drawn steel wire rope was used to hoist a large workpiece into a furnace and was heated together with the workpiece to $1,000^{\\circ}\\mathrm{C}$. Upon completion of heating, when the workpiece was lifted out, the steel wire rope broke. Analyze the reason for this.", + "answer": "The processing of the cold-drawn steel wire rope is a cold-working process. Due to work hardening, the strength and hardness of the steel wire increase, thereby enhancing its load-bearing capacity. When heated, if the temperature exceeds its recrystallization temperature, the steel wire rope undergoes recrystallization, leading to a reduction in strength and hardness. Once the external load exceeds its load-bearing capacity, it will break.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析钢丝绳断裂的原因，答案提供了详细的文字解释和论述，涉及冷加工、加工硬化、再结晶等材料科学概念，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析冷拔钢丝绳在高温下断裂的原因，涉及冷加工、加工硬化、再结晶温度等多个概念的综合运用和机理解释。需要理解材料在不同温度下的行为变化，并分析其与断裂现象的因果关系，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 463, + "question": "Explain the differences in metallographic structure between plate martensite and lath martensite", + "answer": "
Plate martensiteThe initially formed martensite needles traverse the austenite grains, while subsequently formed ones gradually become smaller. The plates are not parallel to each other. Those with C%>1.4% have a midrib
Lath martensiteThe original austenite grains are divided into several blocks, each consisting of several lath bundles, and each lath bundle is composed of many parallel lath martensites
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释板条马氏体和片状马氏体在金相组织上的差异，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求解释板条马氏体和片状马氏体在金相组织上的差异，这需要对马氏体转变机制、晶体结构以及显微组织特征有深入的理解和分析能力。答案中不仅描述了两种马氏体的形态特征，还涉及了它们的形成过程和相互关系，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2346, + "question": "Based on the above calculation results, explain the relationship between the atomic radius and volume change when pure iron transforms from bcc to fcc structure at 17°C.", + "answer": "From the calculated results above, it can be seen that if the atomic radius remains unchanged before and after the transformation, the volume change after the transformation would be very large, which is inconsistent with the actual measured results and also contradicts the nature of metallic bonds. Therefore, for the same metal, the atomic radius of different structures should change to minimize the volume change as much as possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于计算结果解释原子半径与体积变化之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释原子半径与体积变化之间的关系，涉及晶体结构转变的机理分析，需要综合运用金属键性质、晶体结构知识以及实际测量结果的对比，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生基于计算结果，解释纯铁在17°C从bcc转变为fcc结构时原子半径与体积变化的关系。这需要考生：" + }, + { + "idx": 1298, + "question": "Why do solid solution alloys usually grow in a dendritic manner during solidification under a positive temperature gradient?", + "answer": "During the crystallization of solid solutions, constitutional supercooling occurs, leading to a constitutionally supercooled zone ahead of the solid-liquid interface. If any small protrusion exists on the interface, it will extend into the constitutionally supercooled zone and continue to grow as it gains supercooling. Therefore, the interface cannot remain flat and stable, resulting in dendritic growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么固溶体合金在正温度梯度下凝固时通常以枝晶方式生长，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释固溶体合金在正温度梯度下凝固时形成枝晶的原因，涉及成分过冷、固液界面稳定性等概念的关联和综合分析，需要深入理解凝固过程中的热力学和动力学机制，并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 674, + "question": "What is the effect of a third element on the diffusion of components in a binary alloy?", + "answer": "The third element that forms compounds with the components in the alloy hinders the diffusion of solute atoms, thereby reducing the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释第三元素对二元合金中组分扩散的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及第三元素对二元合金中组分扩散的影响，需要理解扩散机制、第三元素与合金组分的相互作用，以及这些因素如何影响扩散系数。这需要对扩散过程进行机理层面的解释和综合分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解二元合金中扩散的基本概念，还需要分析第三元素对扩散系数的影响机制。正确选项涉及化合物形成对溶质原子扩散的阻碍作用，这需要考生具备综合运用材料科学原理、进行推理分析和机理解释的能力。这种复杂现象全面分析的题目在选择题中属于最高难度，因为它超越了简单记忆或单一概念应用，要求考生整合多个知识点并推导出结论。" + }, + { + "idx": 2331, + "question": "According to solidification theory, how does increasing the undercooling ΔT refine the grain size of castings?", + "answer": "Increase the undercooling ΔT. As ΔT increases, both N and Vs increase, but the growth rate of N is greater than that of Vs. Therefore, the value of N/Vs increases, meaning z increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释增加过冷度ΔT如何细化铸件晶粒尺寸，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释过冷度ΔT如何细化铸件晶粒尺寸，涉及凝固理论中的成核速率N和生长速率Vs的变化关系，需要综合运用凝固理论的基本原理，进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1864, + "question": "Briefly describe the crystallographic characteristics of martensitic transformation.", + "answer": "The crystallographic characteristics of martensitic transformation include: a strict orientation relationship between the new phase and the parent phase during the transformation, maintenance of a coherent relationship through shear, the presence of a habit plane that remains undistorted and unrotated before and after the transformation, and macroscopic continuity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体相变的晶体学特征，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求描述马氏体相变的晶体学特征，涉及多个复杂概念的关联和综合分析，包括新相与母相的取向关系、剪切保持的相干关系、习惯面的不变性以及宏观连续性等。这需要深入理解相变机理和晶体学原理，并进行推理分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用多个复杂概念（如取向关系、共格关系、惯习面等），并理解马氏体相变的晶体学机理。正确选项涉及对相变过程中微观结构和宏观现象的全面分析，需要考生具备深度推理和机理解释能力。这种综合性的知识运用和复杂现象分析在选择题中属于最高难度水平。" + }, + { + "idx": 2149, + "question": "Point out the error in the following concept: (5) The coordination number of body-centered cubic is smaller than that of face-centered cubic crystals, so according to the Pa² relation, the atomic diffusion coefficient in α-Fe should be smaller than that in γ-Fe.", + "answer": "Although the coordination number of body-centered cubic crystals is small, they belong to a non-close-packed structure. Compared with the close-packed structure of face-centered cubic crystals, the correlation coefficient f in the formula does not differ much (0.72 and 0.78), but the atomic spacing is larger, and the vibrational frequency ν of atoms is higher due to weaker constraints, which has a much greater effect than the coordination number. Moreover, the resistance that atoms need to overcome for migration is also smaller, specifically manifested as a lower diffusion activation energy and a larger diffusion constant. In reality, at the same temperature, α-Fe has a higher self-diffusion coefficient, and the diffusion coefficient of solute atoms in α-Fe is higher than that in γ-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行详细解释，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求分析体心立方和面心立方晶体结构对扩散系数的影响，涉及多个因素的比较和权衡（如配位数、原子间距、振动频率、扩散激活能等），需要进行综合推理和机理解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握晶体结构、扩散系数和激活能等基础概念，还需要深入理解Pa²关系及其影响因素。题目涉及多个复杂因素的比较分析（如配位数、原子间距、振动频率、扩散激活能等），并要求综合这些因素进行机理层面的解释。正确选项需要考生具备将理论知识应用于实际材料现象（α-Fe和γ-Fe扩散差异）的能力，这属于复杂现象全面分析的范畴。在选择题型中，这种需要多维度推理和机理深度解释的题目最具挑战性。" + }, + { + "idx": 2569, + "question": "Change the tension in the previous question to compression, determine the specimen axis rotation direction and rotation axis", + "answer": "The specimen axis rotation direction is [111], and the rotation axis is $[2\\bar{1}3]\\times[111]=[\\bar{4}13]$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定试样轴的旋转方向和旋转轴，答案给出了具体的旋转方向和旋转轴的计算结果，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求从张力条件转变为压缩条件，并确定试样轴的旋转方向和旋转轴。这需要深入理解晶体学中的方向指数和旋转机制，涉及多个概念的关联和综合分析。解答过程中需要运用向量叉积等数学工具，进行推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3429, + "question": "What are the differences in heat treatment processes between alloy steel and carbon steel?", + "answer": "Due to the influence of alloying elements on critical temperature, point E, and point S, the heat treatment temperature of alloy steel differs from that of carbon steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢和碳钢在热处理过程中的差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较合金钢和碳钢的热处理工艺差异，涉及合金元素对临界温度、E点和S点的影响，需要综合运用材料科学知识进行推理分析，解释不同钢种热处理温度差异的机理。这超出了简单记忆或应用层面，属于需要深度理解和综合分析的内容。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解合金钢和碳钢的热处理差异，还需要掌握合金元素对临界温度、E点和S点的影响机制。这需要综合运用材料科学知识，进行复杂的推理分析，并解释热处理温度差异的深层机理。正确选项涉及多个专业概念的联动关系，远超简单记忆或基础理解的层次，属于复杂现象全面分析的范畴。" + }, + { + "idx": 846, + "question": "Indicate and explain the internal substructure in the characteristics of martensitic transformation", + "answer": "In addition to lattice shear, martensitic transformation also involves lattice-invariant shear, accomplished through slip or twinning, resulting in the formation of dislocation or twin substructures within the martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的内部亚结构特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释马氏体相变的内部亚结构特征，涉及晶格剪切和晶格不变剪切的机制，以及位错或孪晶亚结构的形成。这需要综合运用相变理论、晶体缺陷知识，并进行机理层面的解释和分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解马氏体相变的内部亚结构特征，包括晶格剪切和晶格不变剪切机制（滑移或孪生），并能解释由此产生的位错或孪晶亚结构。这需要综合运用相变机理知识，进行复杂的推理分析，属于\"复杂现象全面分析\"的知识层次。选择题型中仅凭正确选项就能看出其考查的知识深度和综合能力要求明显高于常规选择题。" + }, + { + "idx": 1916, + "question": "Explain the formation conditions and characteristics of structural defects in anion interstitial non-stoichiometric compounds", + "answer": "Under oxidizing atmosphere, low valence state changes to high valence state, p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释结构缺陷的形成条件和特征，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求解释非化学计量化合物中结构缺陷的形成条件和特征，涉及氧化气氛下的价态变化和半导体类型，需要综合运用材料科学和化学原理进行机理分析和推理。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解非化学计量化合物的基本概念，还需要掌握结构缺陷的形成条件（氧化气氛）及其对材料性能的影响（p型半导体特性）。这需要综合运用晶体化学、缺陷化学和半导体物理等多学科知识，并进行机理层面的深度解释。在选择题型中，这种需要多维度分析和机理推理的题目属于最复杂的类型。" + }, + { + "idx": 2305, + "question": "Explain why in short-fiber composites with $L>N$, only a few nuclei form and rapidly grow, resulting in the largest grain size after recrystallization. Beyond the critical deformation degree, the cold deformation degree is inversely proportional to the recrystallized grain size. When the deformation degree reaches a certain level, the grain size remains essentially unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷变形程度对再结晶晶粒尺寸的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析冷变形程度对再结晶晶粒尺寸的影响，涉及多个阶段的变形程度与再结晶行为的关系，需要综合运用材料科学中的变形、储存能、再结晶形核与长大等机理进行推理分析。解答过程中不仅需要理解基本概念，还需要对不同变形程度下的再结晶行为进行详细解释和综合分析，思维深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面分析冷变形程度对再结晶晶粒尺寸的影响机理，涉及多个关键概念（临界变形度、储存能、形核率与生长速率关系等）的综合运用。正确选项不仅需要理解不同变形程度区间（低于临界、等于临界、高于临界）的物理机制差异，还需要解释G>>N条件下的晶粒生长动力学原理。这种在选择题中要求对复杂现象进行多阶段机理解释和定量关系分析的情况，属于选择题型中最具挑战性的考核形式。" + }, + { + "idx": 1531, + "question": "Explain the strengthening mechanism of work hardening", + "answer": "Work hardening: During the plastic deformation of cold-worked metals, a large number of dislocations are formed. Some of these dislocations become immobile dislocations, thereby increasing their resistance to mobile dislocations. This makes further deformation of the material difficult, resulting in work hardening or strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释加工硬化的强化机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释加工硬化的强化机制，涉及位错的形成、运动及其相互作用等复杂概念，需要综合运用材料科学中的位错理论和塑性变形知识进行机理层面的分析和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解位错理论、塑性变形机制以及加工硬化的微观机理，并能够将这些复杂概念整合起来进行综合解释。这需要考生具备扎实的材料科学基础，能够将抽象的理论知识与实际现象联系起来，属于复杂现象的全面分析层次。在选择题型中，这类需要深度机理解释和综合分析的题目通常是最具挑战性的。" + }, + { + "idx": 2540, + "question": "Why do real solid solutions often not conform to Vegard's law?", + "answer": "Because Vegard's law reflects the influence of composition on the structure of alloy phases, but the structure of alloy phases is affected not only by composition but also by other factors (such as electron concentration, electronegativity, etc.), which cause real solid solutions to deviate from Vegard's law.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么实际固溶体常常不符合Vegard定律，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释为什么实际固溶体不符合Vegard定律，这需要理解Vegard定律的基本原理，并分析影响合金相结构的多种因素（如电子浓度、电负性等），涉及多因素的综合分析和机理解释，思维深度较高。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解Vegard's law的基本概念，还需要综合运用多个影响因素（如电子浓度、电负性等）来解释实际固溶体偏离该定律的原因。这需要考生具备深入的材料科学机理知识，能够进行复杂现象的全面分析和推理，属于选择题型中要求较高的综合分析和机理解释能力。" + }, + { + "idx": 667, + "question": "Briefly explain the role of the second phase during cold plastic deformation", + "answer": "The primary deformation modes of duplex alloys remain slip and twinning. Due to differences in the type, quantity, size, shape, distribution characteristics of the second phase in the alloy, as well as its interfacial bonding with the matrix, the influence of the second phase on plastic deformation is complex. If both phases in the duplex alloy are plastic, and the size and deformability of the second phase are similar to those of the matrix, the deformation of the alloy depends on the volume fraction of the two phases. If one phase is plastic and the other is hard and brittle, the plastic deformation of the alloy mainly depends on the presence of the hard and brittle phase. If the second phase is coarse or large-needle-shaped, deformation occurs only in the matrix, and the alloy's plasticity will not be high. If the second phase is continuously distributed along the grain boundaries of the solid solution, the alloy becomes very brittle and almost incapable of plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释第二相在冷塑性变形中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释第二相在冷塑性变形中的作用，涉及多种因素（类型、数量、尺寸、形状、分布特征等）的综合影响，需要深入分析和理解不同情况下第二相对塑性变形的复杂影响机制。这需要综合运用相关知识，进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生全面分析第二相在冷塑性变形中的复杂作用机制，涉及多种变量（类型、数量、尺寸、形状、分布特征等）的综合影响，并需要区分不同条件下的变形主导因素（双相塑性/硬脆相/粗大相/晶界连续相等）。这种题目不仅要求掌握材料变形的基础理论，还需要具备将多因素相互作用进行系统推理的能力，属于典型的复杂现象全面分析层次。" + }, + { + "idx": 129, + "question": "Analyze the reason why monovalent alkali metal oxides reduce the viscosity of silicate melts.", + "answer": "Generally, alkali metal oxides (Li2O, Na2O, K2O, Rb2O, Cs2O) can reduce melt viscosity. These cations, due to their small charge, large radius, and weak interaction with O2-, provide 'free oxygen' in the system, increasing the O/Si ratio. This causes the original silicon-oxygen anion groups to depolymerize into simpler structural units, thereby reducing the activation energy and decreasing viscosity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析碱金属氧化物降低硅酸盐熔体粘度的原因，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析碱金属氧化物降低硅酸盐熔体粘度的原因，涉及离子特性（小电荷、大半径、弱相互作用）、氧硅比变化、硅氧阴离子基团的解聚以及活化能降低等多个方面的综合分析和机理解释。这需要深入理解材料科学中的结构-性能关系，并进行多因素的推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握碱金属氧化物的基本性质，还需要深入理解硅酸盐熔体粘度的变化机理。题目涉及多个复杂概念的综合运用，包括阳离子特性（电荷、半径）、氧硅比变化、硅氧阴离子基团的解聚过程以及活化能的影响机制。这种需要从微观结构角度解释宏观性质变化的题目，在选择题型中属于对知识深度和综合分析能力要求极高的类型。" + }, + { + "idx": 3275, + "question": "What is the reason for the formation of a 'precipitate-free zone' near grain boundaries in age-hardening alloys?", + "answer": "In the case of the decomposition of a supersaturated solid solution, when rapidly cooled from a high temperature, along with the solute atoms being supersaturatedly retained in the solid solution, a large number of supersaturated vacancies are also retained. These vacancies, on one hand, promote the diffusion of solute atoms and, on the other hand, act as nucleation sites for precipitates, facilitating heterogeneous nucleation and causing the precipitates to disperse throughout the matrix. When observing the distribution of precipitates in age-hardening alloys, a 'precipitate-free zone' is often seen near grain boundaries, where no precipitates are visible. This is because the supersaturated vacancies near the grain boundaries diffuse to the grain boundaries and disappear, so no heterogeneous nucleation or precipitation occurs in this region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释“precipitate-free zone”形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释\"precipitate-free zone\"的形成原因，涉及多个材料科学概念的关联和综合分析，包括固溶体的分解、过饱和空位的作用、异质成核机制以及晶界对空位扩散的影响。需要深入理解这些概念之间的相互作用，并进行推理分析来解释现象。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解基本的沉淀硬化机制，还需要综合运用多个复杂概念（如过饱和空位、异质形核、晶界扩散等）进行机理深度解释。正确选项涉及多步骤推理分析，包括：" + }, + { + "idx": 940, + "question": "Analyze the causes of secondary banded structure formation.", + "answer": "The formation of secondary banded structure is the result of solid-state transformation. The white bands are proeutectoid ferrite, and the black bands are pearlite, which must form on the basis of primary bands. These bands are all related to element segregation and the special distribution of inclusions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析二次带状结构形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析二次带状结构的形成原因，涉及固态相变、先共析铁素体和珠光体的形成机制，以及元素偏析和夹杂物分布的影响。这需要综合运用材料科学中的相变理论、显微组织分析等知识，进行机理的解释和推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解二次带状结构的形成机理，包括固态相变、先共析铁素体和珠光体的形成过程，以及元素偏析和夹杂物特殊分布的综合影响。正确选项不仅需要识别现象，还需要解释多层次的复杂因果关系，涉及材料科学中较深层次的理论知识。这种题目在选择题中属于需要全面分析复杂现象的典型代表，远超出基础概念识别的难度水平。" + }, + { + "idx": 843, + "question": "Indicate and explain the surface relief and shear coherency in the characteristics of martensitic transformation", + "answer": "Martensitic transformation produces uniform shear or lattice shear, causing structural changes, resulting in surface relief phenomena on the specimen. The interface between martensite and the parent phase is a coherent interface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变的表面浮雕和剪切共格性特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释马氏体相变的表面浮凸和剪切共格性特征，涉及对相变机理的深入理解和综合分析，需要将结构变化与表面现象关联起来，并进行推理分析。 | 难度: 在选择题型内，该题目属于高难度等级。题目要求考生不仅理解马氏体相变的基本概念，还需要掌握其表面浮凸现象和剪切共格性的机理。正确选项涉及对相变过程中均匀剪切或晶格剪切的结构变化、表面浮凸现象的成因以及马氏体与母相界面的共格性质的综合理解。这需要考生具备复杂分析能力，能够综合运用多个知识点进行推理和解释，符合选择题型中最高难度等级的要求。" + }, + { + "idx": 3115, + "question": "What are the characteristics of future materials science research?", + "answer": "Currently, due to the increasing demand for new materials, there is a desire to enhance theoretical predictability and reduce blind experimentation in materials development as much as possible. Objectively, the in-depth development of modern fundamental sciences such as physics and chemistry has provided many new principles and concepts. More importantly, advancements in computer information processing technology, as well as various material preparation and characterization techniques, have led to some new features in materials development and design. 1) In terms of the microscopic structure design of materials, the focus will shift from the microstructural level (-1μm) to the molecular and atomic levels (1~10nm) and the electronic level (0.1~1nm) (developing micrometer and nanometer materials). 2) The conceptual idea of mixing organic, inorganic, and metallic materials at the atomic and molecular levels to form so-called 'hybrid' (Hybrid) materials, exploring new pathways for synthetic materials. 3) In the development of new materials, based on databases and knowledge repositories, computers are used to predict the properties of new materials and simulate the relationship between the microscopic structure and properties of new materials. 4) In-depth research into the production processes of materials under various conditions, employing new thinking and adopting new technologies to develop new materials, such as the design of semiconductor superlattice materials, exemplified by 'bandgap engineering' or 'atomic engineering.' This involves controlling the electronic structure of materials to create multilayer heterostructure periodic materials composed of alternating ultrathin layers of different semiconductors, thereby greatly advancing the development of semiconductor lasers. 5) Selecting key objectives and organizing multidisciplinary efforts to jointly design certain new materials, such as the concept and practice of 'functionally graded' materials (FGM) proposed according to the requirements of aerospace thermal protection materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对材料科学未来研究的特征进行详细的文字解释和论述，答案提供了多个方面的详细描述，符合简答题的特点。 | 知识层次: 题目要求对材料科学未来研究的特点进行详细论述，涉及多个复杂概念和跨学科知识的综合运用，如微观结构设计、混合材料概念、计算机模拟、生产工艺研究以及多学科协作设计新材料等。这需要深入理解材料科学的前沿发展，并能将这些概念关联起来进行综合分析，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目涉及未来材料科学研究的多个复杂特征，包括微观结构设计、混合材料概念、计算机预测与模拟、材料生产工艺研究以及多学科协作设计新材料等。这些内容不仅要求考生具备深厚的材料科学基础知识，还需要能够综合运用物理、化学、计算机等多学科知识进行推理分析。此外，题目中的概念如\"功能梯度材料\"和\"半导体超晶格材料\"的设计原理，需要对材料科学的前沿研究有深入理解。因此，该题目在选择题型内属于复杂现象全面分析的难度等级。" + }, + { + "idx": 2445, + "question": "What are the differences in the formation mechanisms between crystal texture and polymer texture?", + "answer": "Polycrystalline texture is formed by the deformation and rotation of grains under force, while polymer texture is formed by the ordered arrangement and distribution of molecular chains under force, along with the rotational orientation of crystalline blocks in the amorphous region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体织构和聚合物织构的形成机制差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较晶体织构和聚合物织构的形成机制，涉及不同材料体系（金属/聚合物）的微观结构演变机理，需要综合运用晶体学、高分子物理等知识进行机理层面的对比分析，属于需要深度理解和推理分析的复杂问题。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2219, + "question": "To refine the grain size of a pure aluminum part, the cold deformation was increased to 80%, followed by annealing at 650°C for 1 hour, but coarse grains were still obtained. Analyze the reason.", + "answer": "The reason is the inappropriate selection of recrystallization annealing temperature (the temperature was too high). According to the estimation of T_rec ≈ 0.4T_melt, where T_melt = 100°C, the recrystallization temperature should not exceed 200°C. Since annealing was performed at 650°C for 1 hour, the grains remained coarse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析原因并进行文字解释和论述，答案提供了详细的解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要综合运用材料科学中的再结晶理论、温度计算和晶粒生长机制，进行推理分析。涉及多步思维过程，包括理解冷变形对晶粒尺寸的影响、计算再结晶温度、分析高温退火对晶粒生长的作用机制等。 | 难度: 在选择题型中属于高难度，题目要求综合运用材料科学知识（如再结晶温度计算、晶粒细化机理）并进行复杂推理分析。需要理解并应用T_rec ≈ 0.4T_melt公式，正确判断温度选择不当的影响，同时解释高温退火导致晶粒粗化的深层机理。这种需要多步骤计算和机理解释的题目在选择题中属于最高难度层级。" + }, + { + "idx": 374, + "question": "Briefly describe the laws of changes in material microstructure and properties during recovery and recrystallization annealing", + "answer": "As the annealing temperature increases or the annealing time prolongs, dislocation tangles in the deformed structure evolve into subgrains, which merge and grow; recrystallization nucleation and growth occur in areas of uneven deformation, with equiaxed grains replacing elongated deformed grains; followed by normal grain growth; in terms of properties, strength and hardness decrease, electrical resistance decreases; plasticity and toughness improve, and density increases. These processes are more pronounced during the recrystallization stage than during the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述材料在回复和再结晶退火过程中微观结构和性能变化的规律，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目要求描述材料在回复和再结晶退火过程中微观结构和性能变化的规律，这需要综合运用多个概念（如位错、亚晶、再结晶形核与长大等）进行关联分析，并解释这些变化对材料性能的影响。这涉及到对材料科学中复杂机理的理解和解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用材料科学知识，深入理解回复和再结晶退火过程中微观结构和性能变化的复杂机理。正确选项不仅需要识别多个物理冶金现象（如位错重组、亚晶合并、再结晶形核与长大），还需准确关联微观结构演变与宏观性能变化（强度、电阻率、塑性等）。这种题目要求考生具备高阶分析能力和机理解释能力，远超简单记忆或基础理解层面，属于复杂现象全面分析的典型代表。" + }, + { + "idx": 4600, + "question": "For some ceramic materials, why does the thermal conductivity first decrease and then increase with rising temperature?", + "answer": "For some ceramic materials, the thermal conductivity first decreases with rising temperature because the scattering of lattice vibrations increases with temperature. At higher temperatures, the thermal conductivity will increase for some ceramics that are porous because radiant heat transfer across pores may become important, which process increases with rising temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷材料热导率随温度变化的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷材料热导率随温度变化的复杂行为，涉及晶格振动散射和辐射传热两种机制的相互作用。需要深入理解材料微观结构对热传导的影响，并能综合分析不同温度区间主导机制的转变。这种机理解释和综合分析能力属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 3329, + "question": "There is a 20 steel workpiece with a diameter of φ12mm, which is carburized and then air-cooled, followed by normal quenching and tempering. Analyze the microstructure from the surface to the core of the workpiece after carburizing and air-cooling, and after quenching and tempering.", + "answer": "After air-cooling: P + Fe3CI, P, P + F; After quenching and tempering: M⊥+ FeC, tempered M, tempered M + F.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析工件从表面到核心的微观结构变化，需要详细的文字解释和论述，答案也是以描述性文字形式呈现，而非选择、判断或计算。 | 知识层次: 题目要求分析从表面到核心的微观结构变化，涉及多个热处理步骤（渗碳、空冷、淬火、回火）的综合影响，需要深入理解材料相变原理和热处理工艺对微观结构的影响，并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1544, + "question": "Taking the tensile curve of low-carbon steel as an example, use dislocation theory to explain the phenomenon of work hardening", + "answer": "When deformation continues, the stress increases again due to a significant rise in the number of dislocations, a phenomenon known as work hardening. This occurs because cold-deformed metals generate a large number of dislocations during plastic deformation, some of which become immobile dislocations. These immobile dislocations increase resistance to mobile dislocations, making further deformation of the material more difficult, resulting in work hardening or strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用位错理论解释低碳钢拉伸曲线中的加工硬化现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢拉伸曲线中的加工硬化现象，涉及位错运动的机理、位错间的相互作用以及材料变形行为的综合分析。这需要深入理解位错理论，并能将其与材料的宏观力学行为联系起来，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生运用位错理论解释低碳钢拉伸曲线中的加工硬化现象，涉及复杂的机理分析和综合推理。正确选项不仅需要理解位错运动的基本概念，还需要掌握位错增殖、不动位错形成及其对材料变形抗力的影响机制。这种题目在选择题中属于对知识深度和应用能力要求极高的类型，需要考生将多个高阶概念整合并建立因果关系，完全符合\"复杂现象全面分析\"的等级5标准。" + }, + { + "idx": 2443, + "question": "For a ceramic oxide, in which temperature ranges does the vacancy diffusion mechanism occur as intrinsic or extrinsic?", + "answer": "If the ceramic oxide is a solid solution, the incorporation of solutes with different valences will generate extrinsic point defects. The concentration of intrinsic point defects changes drastically with temperature, while the concentration of extrinsic point defects does not vary with temperature. Therefore, at low temperatures, the concentration of extrinsic vacancies is higher than that of intrinsic vacancies, and this difference becomes more pronounced as the temperature decreases. Thus, in the low-temperature range, the extrinsic vacancy diffusion mechanism dominates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释陶瓷氧化物中空位扩散机制在何种温度范围内表现为本征或外征，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要综合运用点缺陷理论、温度对缺陷浓度的影响以及扩散机制的知识，进行推理分析和机理解释。涉及多个概念的关联和综合分析，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用陶瓷氧化物中本征与非本征点缺陷的知识，理解不同温度范围内扩散机制的主导因素，并能够分析掺杂价态对缺陷浓度的影响。解题需要：" + }, + { + "idx": 3126, + "question": "What is the shape memory mechanism of shape memory alloys?", + "answer": "After heating and quenching, shape memory alloy materials obtain thermoelastic martensite. The interface between this martensite and the parent phase has good coherency, so the martensite phase continuously shrinks and grows during heating and cooling. When the temperature exceeds the As point, the martensite undergoes plastic transformation into the parent phase. If pressure is applied in the martensitic state, the martensite lattice orientation changes, resulting in deformation. This deformed martensite undergoes reversible phase transformation upon heating, reverting to the parent phase state, causing the entire lattice to restore its original form, thereby eliminating the deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释形状记忆合金的形状记忆机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释形状记忆合金的形状记忆机制，涉及热弹性马氏体、相变过程、晶格取向变化等多个复杂概念的综合运用和机理解释，需要深入理解和分析相变过程中的物理机制及其与材料性能的关系。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解形状记忆合金的复杂机理，包括热弹性马氏体的形成、相变过程、晶格取向变化以及可逆相变等多个复杂概念的综合运用。解题步骤涉及多个层次的推理分析，需要对材料科学中的相变机理有深刻的理解和掌握。此外，题目还要求将理论知识与实际现象（如加热、冷却、压力应用等）相结合，进行全面的分析。因此，在选择题型内，该题目属于复杂现象全面分析的难度等级。" + }, + { + "idx": 2324, + "question": "Why are most covalent solids low-density materials?", + "answer": "Most covalent solids have low packing density because the interatomic bonds are constrained by bond saturation and directionality.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "complex_analysis", "knowledge_level_name": "复杂分析", "difficulty": 4, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释为什么初始结构具有细片状珠光体更好，并涉及奥氏体等温形成机制，需要文字解释和论述。答案也是以论述形式给出，而非选择、判断或计算。 | 知识层次: 题目要求解释初始细片层珠光体结构更优的原因，并涉及奥氏体等温形成机制的分析。这需要综合运用材料科学中的相变原理、组织与性能关系等知识，进行机理层面的推理和解释，属于较高层次的认知要求。 | 难度: 在简答题题型中，该题目要求对珠光体向奥氏体转变的机理进行深度解释，涉及扩散、碳化物分散等复杂概念的综合运用。虽然不需要全面分析多个复杂现象的相互作用（等级5特征），但需要对单一转变过程进行机理层面的详细阐述，符合等级4\"机理深度解释\"的标准。该难度高于基础概念解释类简答题，但低于需要多因素综合分析的最高难度简答题。" + "reasoning": "题型: 题目要求解释为什么大多数共价固体是低密度材料，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释共价固体低密度的原因，涉及共价键的方向性和饱和性等复杂概念，需要综合运用材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解共价固体的基本性质，还需要深入分析键饱和性和方向性对堆积密度的影响机制。正确选项涉及对共价键特性的机理解释，需要综合运用材料科学知识进行推理分析，这超出了简单记忆或基础理解的范畴。在选择题型内，这类需要机理深度解释的题目通常属于难度等级4。" }, { - "idx": 3362, - "question": "Discuss the factors affecting the plasticity of materials", - "answer": "The main factors affecting the plasticity of steel include: (1) the influence of solute atoms; (2) the influence of grain size; (3) the influence of the second phase; (4) the influence of dislocation strengthening, etc.", + "idx": 2296, + "question": "What is the role and mechanism of dispersion strengthening?", + "answer": "Dispersion strengthening: mainly applied to metal matrices, by adding hard particles such as Al2O3, TiC, SiC, etc., with particle sizes around 0.01~0.1μm. These particles dispersed in the metal or alloy can effectively hinder the movement of dislocations, providing significant strengthening effects, but the matrix remains the primary load-bearing component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释分散强化的作用和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释分散强化的定义和基本原理，还需要详细说明其作用机制（如阻碍位错运动）和实际应用（如添加特定颗粒），涉及多个概念的关联和综合分析，思维深度较高。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解分散强化的基本概念，还需要掌握其具体机制（如硬质颗粒如何阻碍位错运动）和应用条件（金属基体、颗粒尺寸范围等）。这需要考生具备材料强化机理的深入知识，并能将多个专业概念（位错理论、第二相强化、载荷传递机制）进行整合分析。虽然题目提供了正确选项，但选项内容本身涉及专业术语和机理描述，需要考生在选择题型内进行较高层次的认知加工。" + }, + { + "idx": 580, + "question": "How do dislocations affect the diffusion rate in metallic materials?", + "answer": "Dislocations influence the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错如何影响金属材料中的扩散速率，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释位错如何影响金属材料中的扩散速率，这涉及到位错与扩散机制的相互作用，需要综合运用位错理论和扩散理论进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于机理深度解释难度。题目要求考生不仅要理解位错的基本概念，还需要掌握位错如何影响金属材料中的扩散速率这一具体机理。这需要考生具备将位错理论与扩散理论相结合的能力，并进行一定程度的推理分析。虽然题目给出了正确选项，但正确选项本身是对复杂现象的概括性描述，考生需要理解背后的科学原理才能准确判断选项的正确性。因此，该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 4462, + "question": "Explain why residual thermal stresses are introduced into a glass piece when it is cooled.", + "answer": "Residual thermal stresses are introduced into a glass piece when it is cooled because surface and interior regions cool at different rates, and, therefore, contract different amounts; since the material will experience very little, if any deformation, stresses are established.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释玻璃冷却过程中残余热应力的产生原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释残余热应力在玻璃冷却过程中的产生机理，涉及不同冷却速率导致的收缩差异和应力建立，需要综合运用热力学和材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解残余热应力的基本概念，还需要掌握玻璃冷却过程中表面和内部区域冷却速率差异导致的收缩量不同这一机理。正确选项涉及对复杂现象的深度解释（冷却速率差异、收缩量差异、应力产生机制），需要考生具备综合分析和推理能力。这种题目在选择题中属于需要机理深度解释的类型，比单纯记忆或简单应用类题目难度更高。" + }, + { + "idx": 2186, + "question": "Briefly analyze the essential similarities and differences of solid solution strengthening", + "answer": "Solid solution strengthening results from the interaction between dislocations and solute atoms, namely the Cottrell atmosphere hindering dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要分析固溶强化的本质异同点，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析固溶强化的本质相似性和差异性，涉及位错与溶质原子的相互作用机制（Cottrell气团阻碍位错运动），需要综合运用材料科学中的位错理论和强化机制知识进行机理层面的解释和分析。这超出了简单记忆或基础应用的范畴，属于需要深入理解和推理分析的复杂问题。 | 难度: 在选择题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要掌握位错与溶质原子相互作用的机理（如Cottrell气团对位错运动的阻碍作用）。这属于对材料强化机理的深度解释，需要考生具备将微观机制与宏观性能联系起来的分析能力，符合等级4\"机理深度解释\"的标准。选择题型中仅提供正确选项时，判断该选项的准确性需要较高的专业知识储备。" + }, + { + "idx": 1202, + "question": "Why can screw dislocations only undergo glide motion?", + "answer": "Because it does not have a fixed half-atom plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么螺型位错只能进行滑移运动，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要解释螺位错只能进行滑移运动的机理，涉及位错的基本性质、运动方式及其与晶体结构的关系。这要求对位错理论有较深入的理解，并能进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生理解并解释螺型位错只能进行滑移运动的机理，这需要深入掌握位错的基本概念和运动机制。正确选项涉及对位错结构中半原子面的理解，这属于复杂分析层次的知识点。此外，题目要求考生能够将抽象的理论知识与具体现象联系起来，进行推理分析，这在选择题型中属于较高层次的认知要求。因此，该题目在选择题型内应评为等级4难度。" + }, + { + "idx": 4597, + "question": "Briefly explain why metals are typically better thermal conductors than ceramic materials.", + "answer": "Metals are typically better thermal conductors than are ceramic materials because, for metals, most of the heat is transported by free electrons (of which there are relatively large numbers). In ceramic materials, the primary mode of thermal conduction is via phonons, and phonons are more easily scattered than are free electrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释金属比陶瓷材料导热性更好的原因，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释金属和陶瓷材料在热传导性能上的差异，涉及自由电子和声子两种不同的热传导机制，以及它们被散射的难易程度。这需要对材料的热传导机理有深入的理解和分析能力，属于对复杂概念的关联和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解金属和陶瓷材料的热传导机制差异，还需要掌握自由电子和声子在热传导中的作用原理。正确选项涉及对两种不同传导机制（电子传导 vs 声子传导）的比较分析，并需要理解散射效应对传导效率的影响。这种题目超越了简单的事实记忆，要求考生能够综合运用材料科学知识进行机理层面的解释，符合等级4\"机理深度解释\"的标准。" + }, + { + "idx": 4391, + "question": "On the basis of microstructure, briefly explain why gray iron is brittle and weak in tension.", + "answer": "Gray iron is weak and brittle in tension because the tips of the graphite flakes act as points of stress concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释灰口铸铁在拉伸时脆性和强度低的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求基于微观结构解释灰口铸铁的脆性和抗拉强度弱的原因，涉及应力集中机理的分析和微观组织与宏观性能的关联，需要综合运用材料科学知识进行推理和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅要知道灰色铸铁在拉伸时表现脆弱的表面现象，还需要深入理解其微观结构（石墨片尖端）如何作为应力集中点导致材料性能下降的机理。这需要考生具备将微观结构与宏观性能联系起来的综合分析能力，以及对材料失效机理的深入理解。在选择题型中，这种需要结合多个知识点进行机理解释的题目属于较难的类型。" + }, + { + "idx": 3530, + "question": "Taking A1-4Cu alloy as an example, explain the changes in microstructure and properties during the aging process.", + "answer": "Aging refers to the phenomenon where the supersaturated solid solution of aluminum alloy obtained after quenching decomposes over time at a certain temperature, leading to an increase in the strength and hardness of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释A1-4Cu合金在时效过程中微观结构和性能的变化，需要详细的文字解释和论述，符合简答题的特征。答案也提供了详细的文字解释，而非选择、判断或计算。 | 知识层次: 题目要求解释A1-4Cu合金在时效过程中微观结构和性能的变化，这需要综合运用材料科学中的相变、强化机制等知识，进行推理分析和机理解释，涉及多个知识点的关联和深入理解。 | 难度: 在选择题型中，该题目要求考生不仅理解铝合金时效处理的基本概念，还需要掌握微观结构变化与性能提升之间的机理关系。正确选项涉及对过饱和固溶体分解过程的解释，以及时效过程中强度硬度变化的因果关系，属于需要机理深度解释的复杂分析题。相比单纯记忆性选择题，该题需要更高层次的综合推理能力，因此在选择题型中属于较高难度(等级4)。" + }, + { + "idx": 4495, + "question": "Explain briefly why the tendency of a polymer to crystallize decreases with increasing molecular weight.", + "answer": "The tendency of a polymer to crystallize decreases with increasing molecular weight because as the chains become longer it is more difficult for all regions along adjacent chains to align so as to produce the ordered atomic array.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释聚合物结晶倾向随分子量增加而降低的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释高分子结晶倾向随分子量增加而降低的机理，需要深入理解高分子链排列和结晶过程的复杂性，涉及分子链长度对有序排列的影响机制，属于对材料科学原理的综合分析和推理解释。 | 难度: 在选择题型中，该题目属于较高难度等级。虽然题目形式为选择题，但正确选项要求考生理解高分子结晶的机理，并能分析分子量增加对结晶倾向的影响。这需要考生掌握高分子链排列的微观机制，并能将分子链长度与结晶难易度建立因果关系。相比简单记忆型或基础概念型选择题，此类题目要求考生具备机理深度解释能力，属于选择题型中较难的类型。" + }, + { + "idx": 253, + "question": "Explain the difference in diffusion coefficients between hydrogen and nickel in face-centered cubic iron.", + "answer": "Compared to nickel atoms, hydrogen atoms are much smaller and can diffuse more easily through the gaps in face-centered cubic iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释氢和镍在面心立方铁中扩散系数的差异，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释氢和镍在面心立方铁中扩散系数的差异，涉及原子尺寸效应和晶体结构间隙扩散机理的综合分析，需要理解扩散机制和原子尺寸对扩散行为的影响，属于复杂分析和推理解释的范畴。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解扩散系数的概念，还需要掌握氢和镍原子在面心立方铁中的扩散机理差异。正确选项涉及对原子尺寸效应的深入理解以及晶体结构间隙扩散的机理分析，这需要考生具备综合运用材料科学知识的能力。虽然题目以选择题形式呈现，但考察的知识深度和推理复杂度明显高于基础概念题，属于需要机理深度解释的难度等级。" + }, + { + "idx": 4240, + "question": "For a given material, would you expect the surface energy to be greater than, the same as, or less than the grain boundary energy? Why?", + "answer": "The surface energy will be greater than the grain boundary energy. For grain boundaries, some atoms on one side of a boundary will bond to atoms on the other side; such is not the case for surface atoms. Therefore, there will be fewer unsatisfied bonds along a grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么表面能会大于晶界能，需要文字论述和解释，而不是简单的选择或判断。答案也提供了详细的解释说明。 | 知识层次: 题目要求解释表面能与晶界能的关系，并分析其背后的原子键合机制。这需要综合运用材料科学中的表面与界面知识，理解原子键合状态对能量状态的影响，并进行推理分析。虽然涉及基础概念，但更侧重于机理解释和综合分析。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解表面能和晶界能的基本概念，还需要深入分析原子键合状态的差异（表面原子存在未饱和键而晶界原子部分键合），并据此进行机理层面的解释。这种需要综合材料科学原理进行推理分析的题目，比单纯记忆概念或简单比较的题目难度更高，属于选择题中的机理深度解释类型。" + }, + { + "idx": 2143, + "question": "Point out the errors in the following concept: (1) If there is no diffusion flow in a solid, it means that atoms are not diffusing.", + "answer": "Even if there is no macroscopic diffusion flow in a solid, diffusion still occurs due to the migration jumps of atomic thermal vibrations. Self-diffusion in pure substances is a typical example.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行解释，答案通过文字论述说明了即使没有宏观扩散流，扩散仍然发生的原因，符合简答题的特征。 | 知识层次: 题目要求分析并指出概念中的错误，需要理解扩散现象的微观机制（原子热振动迁移）与宏观表现（扩散流）之间的关系，并进行推理分析。这涉及对扩散原理的深度理解和综合运用，超出了简单记忆或应用的范畴。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求理解扩散的基本概念，还需要深入掌握扩散的微观机理（如原子热振动迁移跳跃）和宏观表现（无净扩散流）之间的关系。正确选项涉及对自扩散现象的机理解释，这需要学生具备将微观原子行为与宏观现象联系起来的能力，属于复杂分析层次的知识运用。" + }, + { + "idx": 584, + "question": "What is the role of dislocations in the nucleation of the second phase?", + "answer": "Dislocations are preferential sites for the nucleation of the second phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对dislocations在第二相成核中的作用进行文字解释和论述，答案提供了简要的解释，符合简答题的特征。 | 知识层次: 题目涉及位错在第二相形核中的作用，需要理解位错的性质及其对形核过程的影响机制，属于对材料科学中微观结构和相变机理的综合分析和解释。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅知道位错的基本概念，还需要理解位错在第二相形核过程中的具体作用机制。题目涉及的知识点较为深入，需要考生具备综合运用和推理分析的能力，能够解释位错作为第二相形核的择优位点的机理。这种题目在选择题型中属于机理深度解释的层次，难度较高。" + }, + { + "idx": 1357, + "question": "Analyze the fundamental differences in solid solution strengthening", + "answer": "Solid solution strengthening: solute atoms gather along dislocations and pin them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析固溶强化的基本原理，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求分析固溶强化的基本原理，涉及溶质原子与位错的相互作用机制，需要综合运用材料科学中的位错理论和强化机制知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要掌握溶质原子在位错周围的聚集行为及其对位错运动的钉扎机制。这涉及到对材料科学中位错理论和强化机理的深度理解，属于机理深度解释的层次。虽然题目提供了正确选项，但考生需要具备较高的知识整合能力和机理分析能力才能准确判断。因此，在选择题型内属于较高难度等级。" + }, + { + "idx": 1013, + "question": "From the perspective of bonding, analyze the characteristics of ceramic materials", + "answer": "Ceramic materials: primarily covalent and ionic bonds, hard, brittle, difficult to deform, high melting point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从键合的角度分析陶瓷材料的特性，需要文字解释和论述，答案也是以文字形式呈现的简要论述。 | 知识层次: 题目要求从化学键的角度分析陶瓷材料的特性，需要综合运用化学键理论（共价键和离子键）与材料性能（硬度、脆性、变形能力、熔点）之间的关联，进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于复杂分析的层次。 | 难度: 在选择题型中，该题目要求考生从化学键合的角度深入分析陶瓷材料的特性，涉及共价键和离子键的综合理解，以及这些键合类型如何影响材料的硬度、脆性、变形能力和熔点。这需要考生不仅掌握基础概念，还能进行机理层面的解释和推理，属于较高难度的选择题。" + }, + { + "idx": 4281, + "question": "What is the difference between deformation by twinning and deformation by slip relative to mechanism?", + "answer": "With slip deformation there is no crystallographic reorientation, whereas with twinning there is a reorientation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种变形机制的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释变形机制中的孪生和滑移的区别，涉及晶体学重新取向的概念，需要对两种变形机制的深入理解和综合分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解滑移和孪生两种变形机制的基本概念，还需要深入掌握它们在晶体学取向变化方面的差异。正确选项涉及机理层面的解释，需要考生具备综合分析和推理能力，能够区分两种变形机制的本质区别。这种题目在选择题中属于机理深度解释的层次，对知识掌握的要求较高。" + }, + { + "idx": 1024, + "question": "Analyze the effect of cold plastic deformation on the mechanical properties of alloys", + "answer": "(2) Mechanical properties: The dislocation density increases, dislocations become entangled with each other, and the resistance to movement increases, resulting in work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金力学性能的影响，涉及位错密度增加、位错纠缠和加工硬化等机理的解释，需要综合运用材料科学中的变形机制和力学性能变化的知识，进行推理分析和机理解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解冷塑性变形对合金机械性能的影响，还需要掌握位错密度增加、位错纠缠以及由此导致的加工硬化等机理。这些知识点涉及较深的材料科学原理，需要考生具备综合运用和推理分析的能力。此外，题目要求考生在多个选项中识别出正确描述这些复杂现象的选项，这增加了题目的难度。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 319, + "question": "Why is the strength of solid solutions often higher than that of pure metals?", + "answer": "Because the different sizes of the two types of atoms in the alloy cause lattice distortion, which hinders dislocation movement and results in solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么固溶体的强度通常高于纯金属，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及原子尺寸差异导致的晶格畸变以及位错运动的阻碍作用，需要综合运用材料科学中的晶体缺陷和强化机制知识进行推理分析。 | 难度: 在选择题型中，该题目要求考生不仅理解固溶强化的基本概念，还需要掌握晶格畸变和位错运动之间的相互作用机制。这涉及到对材料科学中较为复杂的原理进行解释和分析，属于机理深度解释的层次。虽然题目提供了正确选项，但考生需要具备较高的知识整合能力和推理分析能力才能准确理解并选择正确答案。因此，在选择题型内属于较高难度等级。" + }, + { + "idx": 2291, + "question": "What is the role and mechanism of particle (granular) reinforcement?", + "answer": "Particle reinforcement: Hard particles with a diameter of 1~50 μm are added to the matrix. The particles can bear part of the load, but the matrix bears the main load. The particles restrict the deformation of the matrix through mechanical constraint. Properly sized and uniformly distributed particles can effectively strengthen the material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释颗粒增强的作用和机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释颗粒增强的作用和机制，涉及对颗粒与基体之间相互作用的深入理解，需要分析颗粒如何分担载荷、限制基体变形等机理，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解颗粒增强的基本概念，还需要掌握其作用机理（如机械约束、载荷分担等）。题目涉及对颗粒尺寸、分布和基体相互作用等复杂因素的综合分析，属于机理深度解释层次。虽然题目提供了正确选项，但需要考生具备较强的材料科学背景知识才能准确理解和判断。" + }, + { + "idx": 290, + "question": "Analyze the effect of strain energy on the shape of the new phase", + "answer": "Strain energy can influence the shape of the new phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对新相形状的影响，需要文字解释和论述，答案形式为简短的文字说明而非计算或选择 | 知识层次: 题目要求分析应变能对新相形状的影响，这需要综合运用材料科学中的相变理论、弹性力学和热力学知识，进行推理分析和机理解释。涉及多个概念的关联和深层次理解，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求分析应变能对新相形状的影响，这涉及到对材料科学中相变机理的深入理解。正确选项虽然简洁，但背后需要考生掌握应变能与相变形状之间的复杂关系，并能进行机理层面的解释。这种题目不仅测试基础概念，还要求考生能够综合运用知识进行推理分析，因此在选择题型中属于机理深度解释的难度等级。" + }, + { + "idx": 1556, + "question": "Based on the relationship between dislocation motion and crystal slip, analyze the relationship between the Burgers vector of a pure screw dislocation and the direction of the dislocation line", + "answer": "The Burgers vector is parallel to the direction of the dislocation line", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析位错运动与晶体滑移之间的关系，并解释纯螺型位错的Burgers矢量与位错线方向的关系。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析纯螺型位错的Burgers矢量与位错线方向之间的关系，这需要深入理解位错运动与晶体滑移的机理，并进行推理分析。这超出了基础概念记忆和简单应用的范畴，属于需要综合运用知识进行复杂分析的层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生深入理解位错运动与晶体滑移的关系，并能够综合运用这些知识来分析纯螺型位错的Burgers矢量与位错线方向的关系。这需要考生具备机理深度解释的能力，而不仅仅是简单的记忆或识别。此外，题目涉及的知识点较为复杂，解题步骤需要一定的推理和分析，因此在选择题型内属于等级4的难度。" + }, + { + "idx": 4562, + "question": "Briefly explain why cold-worked metals are more susceptible to corrosion than noncold-worked metals.", + "answer": "Cold-worked metals are more susceptible to corrosion than noncold-worked metals because of the increased dislocation density for the latter. The region in the vicinity of a dislocation that intersects the surface is at a higher energy state, and, therefore, is more readily attacked by a corrosive solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释冷加工金属比非冷加工金属更容易腐蚀的原因，答案通过文字解释和论述来回答，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释冷加工金属更易腐蚀的机理，涉及位错密度与腐蚀敏感性的关联分析，需要理解位错与表面能状态的关系，并运用材料科学原理进行推理解释，属于机理层面的复杂分析。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解冷加工金属的基本特性，还需要掌握位错密度与腐蚀敏感性的内在机理关系。正确选项涉及材料科学中的微观结构（位错）与宏观性能（腐蚀）的关联性解释，需要考生具备将抽象理论转化为具体现象分析的能力。这种在选择题中要求机理深度解释的题目，比单纯记忆概念或简单应用公式的题目难度更高，属于选择题型中的较难水平。" + }, + { + "idx": 4319, + "question": "Briefly explain why, upon solidification, an alloy of eutectic composition forms a microstructure consisting of alternating layers of the two solid phases.", + "answer": "Upon solidification, an alloy of eutectic composition forms a microstructure consisting of alternating layers\nof the two solid phases because during the solidification atomic diffusion must occur, and with this layered configuration the diffusion path length for the atoms is a minimum.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释共晶合金凝固时形成交替层状微观结构的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释共晶合金凝固过程中微观结构形成的机理，涉及原子扩散和能量最小化原理的综合分析，需要深入理解相变过程和微观组织形成的原理，属于机理层面的解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅要理解合金凝固的基本原理，还需要掌握共晶成分合金的微观结构形成机理。正确选项涉及原子扩散路径最小化的概念，这需要考生将扩散理论与微观结构形成联系起来进行综合分析。这种题目在选择题中属于需要机理深度解释的类型，比单纯记忆概念或简单应用公式的题目难度更高。" + }, + { + "idx": 4241, + "question": "The grain boundary energy of a small-angle grain boundary is less than for a high-angle one. Why is this so?", + "answer": "The small-angle grain boundary energy is lower than for a high-angle one because more atoms bond across the boundary for the small-angle, and, thus, there are fewer unsatisfied bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么小角度晶界的能量低于大角度晶界，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释小角度晶界能低于大角度晶界的原因，涉及晶界原子键合状态的分析和比较，需要综合运用晶界结构知识和键合理论进行机理层面的解释，思维深度较高。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解晶界能的基本概念，还需要深入分析小角度晶界与大角度晶界在原子键合方面的差异，并据此解释能量差异的机理。这需要综合运用材料科学中的晶体缺陷知识和键合理论，进行推理分析。正确选项涉及对\"未满足键\"这一微观机理的解释，属于机理深度解释层面的考核，因此符合等级4的标准。" + }, + { + "idx": 998, + "question": "Please analyze the characteristics and mechanisms of work hardening.", + "answer": "Work hardening: is the strengthening caused by the multiplication of dislocations due to plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析work hardening的特性和机制，需要文字解释和论述，答案也提供了简要的解释，符合简答题的特征。 | 知识层次: 题目要求分析加工硬化的特征和机制，涉及对位错增殖和塑性变形等复杂机理的解释和综合分析，需要深入理解和推理分析能力。 | 难度: 在选择题型中，该题目属于较高难度。题目要求分析加工硬化的特性和机理，正确选项涉及位错增殖和塑性变形的综合理解。这需要考生不仅掌握位错理论的基本概念，还要能够将这些概念与材料强化机制联系起来进行机理层面的解释。在选择题型内，这种需要综合运用知识并理解深层机理的题目属于等级4难度。" + }, + { + "idx": 1351, + "question": "Analyze the fundamental differences of grain refinement strengthening", + "answer": "Grain refinement strengthening: increases grain boundaries, enlarges the range of dislocation pile-up.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶粒细化强化的基本原理差异，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析晶粒细化强化的基本原理和机制，涉及对晶界和位错堆积范围变化的深入理解，需要综合运用材料科学中的强化机制知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求分析晶粒细化强化的基本原理，正确选项涉及对晶界增加和位错堆积范围扩大这两个关键机理的理解。这需要考生不仅掌握基本概念，还要能够将不同知识点联系起来进行机理层面的解释。虽然题目以选择题形式呈现，但考察的是对复杂材料强化机制的深度理解，属于\"机理深度解释\"的知识层次。在选择题型内，这类需要综合运用知识进行推理分析的题目难度明显高于单纯记忆或简单理解的题目。" + }, + { + "idx": 1710, + "question": "How to control and improve the microstructure in metal materials through heat treatment?", + "answer": "The microstructure of metal materials can be altered through heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过热处理控制和改善金属材料的微观结构，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求通过热处理控制和改善金属材料的微观结构，这需要对热处理工艺（如退火、淬火、回火等）的机理有深入理解，并能综合分析不同工艺参数（如温度、时间、冷却速率）对微观结构的影响。此外，还需要推理分析不同金属材料的相变行为及其与性能的关系，属于复杂分析和综合运用的范畴。 | 难度: 在选择题型内，该题目属于较高难度等级。题目涉及金属材料微观结构的控制和改善，需要通过热处理的机理深度解释来理解。正确选项要求考生不仅掌握热处理的基本概念，还需要理解微观结构变化的机理，并能综合运用这些知识进行分析。这超出了简单记忆或基础理解的范畴，属于复杂分析层次，因此在选择题型内属于等级4的难度。" + }, + { + "idx": 4596, + "question": "Briefly explain why the thermal conductivities are higher for crystalline than noncrystalline ceramics.", + "answer": "Thermal conductivities are higher for crystalline than for noncrystalline ceramics because, for noncrystalline, phonon scattering, and thus the resistance to heat transport, is much more effective due to the highly disordered and irregular atomic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释晶体陶瓷比非晶体陶瓷热导率高的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶体和非晶体陶瓷热导率差异的原因，涉及对声子散射和原子结构无序性的理解，需要综合分析材料微观结构与热传导性能之间的关系，属于机理解释和推理分析的层次。 | 难度: 在选择题型中，该题目属于较高难度等级。正确选项不仅要求考生理解晶体和非晶体陶瓷的基本区别，还需要掌握声子散射的概念及其对热导率的影响机制。题目涉及对材料微观结构与宏观性能关系的深入理解，需要考生能够将多个物理概念（晶体结构、声子传输、热导率）联系起来进行综合分析。这种需要解释物理机理的选择题，比单纯记忆事实或简单比较的选择题难度更高，属于复杂分析层次。" + }, + { + "idx": 3467, + "question": "Why does alloy steel have less heat treatment deformation than carbon steel?", + "answer": "The addition of alloying elements (except C) increases the hardenability of the steel, so when obtaining the same structure, alloy steel can choose a slower cooling medium, resulting in less heat treatment deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金钢比碳钢热处理变形小的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释合金钢与碳钢在热处理变形方面的差异，涉及合金元素对淬透性的影响、冷却介质选择与组织转变的关系等复杂机理分析，需要综合运用材料科学原理进行推理和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解合金钢和碳钢的基本区别，还需要掌握合金元素对钢的淬透性影响这一较深层次的机理知识。正确选项涉及多个关键概念的综合运用（合金元素、淬透性、冷却介质选择、热处理变形关系），需要考生进行机理层面的推理分析才能准确作答。这种需要将多个专业知识模块串联起来解释复杂现象的题目，在选择题中属于难度较高的类型。" + }, + { + "idx": 1023, + "question": "Analyze the effect of cold plastic deformation on the energy of the alloy system", + "answer": "(4) The system energy includes two parts: 1 The lattice distortion caused by a large number of defects generated during cold deformation increases the distortion energy; 2 The microscopic and macroscopic internal stresses caused by uneven deformation between grains and different parts of the workpiece. These two parts are collectively referred to as stored energy, with the former being the primary. The changes in microstructure and properties caused by cold deformation prepare the alloy for subsequent recovery and recrystallization in terms of both structure and energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金系统能量的影响，答案提供了详细的文字解释和论述，包括两部分能量的变化及其对后续恢复和再结晶的影响，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金系统能量的影响，涉及多个方面的综合理解和分析，包括缺陷导致的晶格畸变、微观和宏观内应力等复杂概念，并需要将这些因素关联起来解释存储能量的形成及其对后续回复和再结晶的影响。这需要较高的认知能力和深度思维过程。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解冷塑性变形对合金系统能量的影响，还需要综合运用多个知识点进行推理分析。具体来说，考生需要掌握以下内容：" + }, + { + "idx": 1344, + "question": "How does the type of solid solution affect the diffusion coefficient?", + "answer": "Different solid solutions have different atomic diffusion and mechanisms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同类型的固溶体如何影响扩散系数，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析不同类型固溶体对扩散系数的影响机制，需要综合运用扩散理论、固溶体特性以及原子扩散机制的知识，并进行推理分析和机理解释。这超出了简单记忆或基本应用的范围，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目要求考生理解不同类型固溶体对扩散系数的影响机制，涉及原子扩散和机理的解释。这需要考生具备较深的知识掌握和综合分析能力，属于机理深度解释的难度等级。" + }, + { + "idx": 264, + "question": "The diffusion activation energies of carbon, nitrogen, and hydrogen in body-centered cubic iron are 84 kJ/mol, 75 kJ/mol, and 13 kJ/mol, respectively. Analyze and explain this difference.", + "answer": "The atomic radii of carbon, nitrogen, and hydrogen decrease sequentially. The smaller the atomic radius, the easier it is for the atom to diffuse through the gaps in body-centered cubic iron, and the lower the corresponding diffusion activation energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析和解释扩散激活能的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析不同元素在体心立方铁中扩散激活能的差异，并解释其机理。这需要综合运用原子半径、晶体结构间隙和扩散机制等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅掌握扩散激活能的基本概念，还需要理解原子半径与晶体结构间隙之间的关系，并能将这些知识综合运用到体心立方铁的特定结构中。正确选项涉及机理层面的解释（原子半径越小越容易扩散），需要考生进行推理分析并解释现象背后的物理机制。这种在选择题中要求机理深度解释的题目，明显高于单纯记忆或简单应用的难度水平，但尚未达到需要全面分析复杂现象的最高难度（等级5）。" + }, + { + "idx": 1482, + "question": "At 727°C, the maximum carbon content in the equilibrium iron-carbon alloy is w_C=0.0218% for ferrite, while the carbon content in austenite is w_C=0.77%. Explain why the carbon content differs so greatly between the two.", + "answer": "Because the radius of the flat octahedral interstitial sites in the ferrite crystal is much smaller than that of the regular octahedral interstitial sites in the austenite crystal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种晶体结构中碳含量差异的原因，需要文字解释和论述，而不是选择、判断或计算。答案提供了详细的晶体结构差异解释，符合简答题的特征。 | 知识层次: 题目要求解释铁素体和奥氏体中碳含量差异的原因，涉及晶体结构中间隙位置的差异及其对碳溶解度的影响。这需要深入理解晶体结构、间隙固溶体以及相变等概念，并进行综合分析。思维过程需要从微观结构特征推导宏观性质差异，属于复杂分析和机理解释的范畴。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生理解并比较铁素体和奥氏体晶体结构中碳溶解度的差异，并解释其根本原因。正确选项涉及晶体结构中间隙位置的几何特征（平面八面体间隙与规则八面体间隙的半径差异），这需要考生具备：" + }, + { + "idx": 2807, + "question": "Explain why the diffusion activation energy of polycrystals is lower than that of single crystals.", + "answer": "Polycrystals have grain boundaries, and the 'short-circuit' diffusion effect of grain boundaries increases the diffusion rate, thus resulting in a lower diffusion activation energy. The diffusion in single crystals is purely bulk diffusion, which has a higher activation energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶体的扩散激活能低于单晶体的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释多晶和单晶扩散激活能差异的机理，涉及对晶界扩散效应的理解和综合分析，属于对材料科学中扩散机制的深入分析和解释。 | 难度: 在选择题型内，该题目属于机理深度解释难度。题目要求考生不仅理解扩散激活能的基本概念，还需要掌握多晶体和单晶体在扩散机制上的差异，特别是晶界“短路”扩散效应的原理。这需要考生具备较高的知识综合运用能力和机理解释能力，能够将多个知识点联系起来进行推理分析。虽然题目提供了正确选项，但选项本身包含了较为复杂的机理描述，对考生的理解深度有较高要求。" + }, + { + "idx": 64, + "question": "Graphite, talc, and kaolinite have layered structures. Explain the differences in the structure of graphite and the resulting differences in properties.", + "answer": "Compared to talc and kaolinite, in graphite, the carbon atoms in the same layer undergo SP2 hybridization, forming large π bonds, and each layer has a hexagonal network structure. Due to the large interlayer gaps, electrons can move within the same layer, enabling electrical conductivity. The layers are held together by intermolecular forces, making graphite relatively soft.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释石墨的结构差异及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释石墨与滑石、高岭石在结构上的差异及其对性能的影响，涉及SP2杂化、π键形成、导电性机制等复杂概念的综合运用和推理分析。需要深入理解材料的结构-性能关系，并进行多层次的比较和解释。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解石墨、滑石和高岭石的层状结构，还需要深入分析石墨中碳原子的SP2杂化、大π键的形成以及由此导致的导电性和软性等特性。这需要考生具备扎实的材料科学基础，能够综合运用多个概念进行推理分析，并解释其中的机理。因此，在选择题型内，该题目属于机理深度解释的难度等级。" + }, + { + "idx": 3069, + "question": "Why is the tensile strength of ceramics often much lower than the theoretical strength?", + "answer": "Due to the splitting effect of pores and stress concentration during tension, the tensile strength of ceramics is lower than the theoretical strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的抗拉强度通常远低于理论强度，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释陶瓷材料拉伸强度低于理论强度的原因，涉及孔隙效应和应力集中等复杂机理的分析，需要综合运用材料科学知识进行推理和解释。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解陶瓷材料的基本性能特点，还需要掌握孔隙和应力集中对材料强度影响的机理。正确选项涉及对复杂现象（孔隙分裂效应和应力集中）的综合分析，需要考生具备将理论知识应用于具体材料性能解释的能力。这超出了简单记忆或基础理解的范畴，属于需要机理深度解释的题目类型。" + }, + { + "idx": 4561, + "question": "Why does chromium in stainless steels make them more corrosion resistant in many environments than plain carbon steels?", + "answer": "The chromium in stainless steels causes a very thin and highly adherent surface coating to form over the surface of the alloy, which protects it from further corrosion. For plain carbon steels, rust, instead of this adherent coating, forms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释铬在不锈钢中的作用机制，答案需要文字解释和论述，没有提供选项或要求计算。 | 知识层次: 题目要求解释铬在不锈钢中提高耐腐蚀性的机理，涉及表面涂层形成和保护作用的综合分析，需要理解合金元素的作用机制及其与腐蚀行为的关系，属于较深层次的机理解释和推理分析。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解铬在不锈钢中的作用，还需要掌握其具体机理（形成薄而紧密的表面涂层），并能与普通碳钢的腐蚀机制进行对比分析。这需要考生具备材料科学中腐蚀防护的深层机理知识，并能综合运用这些知识解释复杂现象。题目涉及的知识点掌握深度要求较高，解题时需要结合多个概念进行推理分析，因此属于选择题型中较难的题目。" + }, + { + "idx": 4594, + "question": "(b) Briefly explain why Cv becomes virtually independent of temperature at temperatures far removed from 0 K.", + "answer": "At temperatures far removed from 0 K, Cv becomes independent of temperature because all of the lattice waves have been excited and the energy required to produce an incremental temperature change is nearly constant.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释Cv在远离0 K时几乎与温度无关的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Cv在远离0K温度下与温度无关的现象，这需要理解晶格波的激发机制和热容的量子理论，涉及较深层次的物理概念关联和机理解释，属于综合分析范畴。 | 难度: 在选择题型中，该题目要求考生不仅理解Cv（定容热容）的基本概念，还需要深入掌握晶格振动理论在温度远离绝对零度时的行为。正确选项涉及对晶格波激发状态的综合分析和机理解释，需要考生将多个物理概念（如热容、晶格振动、温度效应）联系起来进行推理。这种深度解释和综合运用能力在选择题中属于较高难度层次，对应知识层次中的\"复杂分析\"要求。" + }, + { + "idx": 3400, + "question": "Analyze the special role of alloying elements (such as Cr, Si, Al, etc.) in improving the thermal stability of steel", + "answer": "Alloying elements (Cr, Si, Al, etc.) form dense protective oxide films at high temperatures, preventing the oxidation of steel and thereby enhancing thermal stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析合金元素在提高钢的热稳定性中的特殊作用，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析合金元素在提高钢的热稳定性中的特殊作用，涉及多种合金元素（Cr、Si、Al等）的协同效应和机理解释，需要综合运用材料科学知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于机理深度解释难度。正确选项不仅要求考生识别合金元素（Cr、Si、Al等）的作用，还需要理解其形成致密氧化膜的具体机理及其对钢热稳定性的影响。这需要考生具备较深的知识储备和机理分析能力，能够将多个概念（如氧化膜形成、高温防护、热稳定性提升）综合联系起来进行推理解释。虽然题目以选择题形式呈现，但正确选项涉及的知识深度和综合推理要求使其达到等级4的难度水平。" + }, + { + "idx": 1339, + "question": "Briefly describe the third essential reason for the high hardness of martensite: grain boundary strengthening mechanism", + "answer": "Whether it is the laths of lath martensite or the plates of plate martensite, they are all very fine, and the grain boundary strengthening mechanism also plays a significant role.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第三个主要原因，即晶界强化机制，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体高硬度的第三个重要原因——晶界强化机制，这需要对马氏体微观结构（板条马氏体和片状马氏体）有深入理解，并能分析晶界强化对硬度的影响机制。这属于综合运用材料科学知识进行推理分析的层次。 | 难度: 在选择题型中，该题目属于机理深度解释难度。正确选项不仅需要考生理解马氏体的基本结构（板条马氏体和片状马氏体），还需要掌握晶界强化机制的具体作用原理。这要求考生能够将微观结构与宏观性能联系起来，并进行机理层面的解释。虽然题目提供了正确选项，但理解其背后的科学原理需要较高的知识掌握深度和分析能力。" + }, + { + "idx": 321, + "question": "What is the reason for the increase in strength caused by the proliferation of line defects and planar defects in crystals?", + "answer": "The reason is that the increase in both types of defects significantly hinders the movement of dislocations, thereby enhancing strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体中线缺陷和面缺陷增殖导致强度增加的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释线缺陷和面缺陷增殖导致强度增加的机理，涉及对晶体缺陷与位错运动之间相互作用的深入理解和综合分析，需要运用材料科学中的位错理论和强化机制进行推理分析。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅要理解线缺陷和面缺陷的基本概念，还需要深入掌握它们如何阻碍位错运动的机理。题目涉及晶体缺陷与力学性能之间的复杂关系，需要综合运用材料科学中的多个知识点进行推理分析，解释强度增加的深层原因。这种题目超出了简单记忆或基础理解的范畴，属于机理深度解释的层次。" + }, + { + "idx": 1718, + "question": "What is the effect of dislocations on the nucleation of the second phase?", + "answer": "Dislocations are preferential sites for the nucleation of the second phase, and typically the second phase can nucleate and grow preferentially at dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错对第二相形核的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及位错对第二相形核的影响机制，需要理解位错作为形核位点的原理，并能够解释第二相在位错处优先形核和生长的原因。这需要对位错和第二相形核的相互作用进行综合分析，属于机理层面的解释，思维深度较高。 | 难度: 在选择题型中，该题目属于较高难度等级。题目要求考生不仅理解位错的基本概念，还需要掌握位错对第二相形核的影响机制。正确选项涉及位错作为第二相形核的择优位置，并解释了第二相在位错处优先形核和生长的机理。这需要考生具备综合运用知识、推理分析和机理解释的能力，属于复杂分析层次。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 3465, + "question": "What is the difference between the purpose of quenching for austenitic stainless steel and wear-resistant steel compared to that of general steel?", + "answer": "The purpose of quenching for austenitic stainless steel and wear-resistant steel is to obtain a single-phase, uniform austenitic structure, preventing the formation of secondary phases that could cause intergranular corrosion. Therefore, the quenching of austenitic stainless steel is referred to as solution treatment, while for wear-resistant steel, the quenching process, which results in a single austenitic structure with high plasticity and toughness, is also known as water toughening treatment.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 4, "final_level": "Level_5", - "reasoning": "题型: 题目要求讨论影响材料塑性的因素，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求讨论影响材料塑性的多个因素，涉及多个概念（如溶质原子、晶粒尺寸、第二相、位错强化等）的关联和综合分析，需要理解这些因素如何相互作用并影响材料的塑性行为，属于中等应用层次。 | 难度: 在简答题中属于较高难度，需要从多个角度（溶质原子、晶粒尺寸、第二相、位错强化等）分析影响材料塑性的因素，并进行综合论述。虽然不需要进行深度关联性分析（如不同因素之间的相互作用机制），但仍需展示对材料科学原理的较全面理解和应用能力。" + "reasoning": "题型: 题目要求解释淬火对奥氏体不锈钢和耐磨钢与普通钢的不同目的，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解不同钢材淬火目的的区别，并解释其背后的原理和术语（如固溶处理和水韧处理），涉及多个概念的关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题型中，该题目需要考生理解并比较不同钢材（奥氏体不锈钢、耐磨钢和普通钢）淬火目的的区别，涉及多个专业概念（单相奥氏体组织、二次相、晶间腐蚀等）和热处理工艺（固溶处理、水韧处理）。解题时需要综合分析不同材料的热处理目的和机理，属于多角度分析论述的难度等级。" }, { - "idx": 3512, - "question": "Compare the machinability of HT150 and annealed 20 steel", - "answer": "The machinability of HT150 is better than that of 20 steel.", - "question_type": "short_answer", - "question_type_name": "简答题", - "knowledge_level": "medium_application", - "knowledge_level_name": "中等应用", - "difficulty": 3, - "final_level": "Level_4", - "reasoning": "题型: 题目要求比较两种材料的机械加工性能，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的机械加工性能，需要理解材料性能与加工性的关系，并进行综合分析。虽然不涉及复杂计算，但需要对材料状态（HT150和退火20钢）及其对加工性能的影响有一定理解，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于中等难度。虽然需要比较两种材料的机械加工性能，但主要涉及对材料基本性能的理解和简单对比，不需要多角度或深度关联性分析。解题步骤相对直接，只需说明HT150的机械加工性能优于20钢即可，无需复杂的计算或深入的概念关联。" - }, - { - "idx": 3872, - "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 48", - "answer": "340 degrees C", + "idx": 4347, + "question": "Is it possible to determine the composition of an iron-carbon alloy if the mass fraction of eutectoid cementite is 0.104?", + "answer": "yes, it is possible to determine the alloy composition, and there are two possible answers.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 4, "final_level": "Level_5", - "reasoning": "题型: 题目要求确定转变温度和微观组织，需要文字解释和论述，答案形式为具体数值但需要结合材料科学知识进行解释 | 知识层次: 题目要求根据硬度值确定共析钢的转变温度和微观组织，需要理解相变温度与硬度之间的关系，并能够应用相关相图知识进行综合分析。这涉及多步推理和概念关联，属于中等应用层次。 | 难度: 在简答题题型中，该题目属于较高难度。首先需要理解共析钢的相变特性与硬度关系，其次要掌握TTT曲线或CCT曲线的应用，最后要能准确关联特定硬度值(HRC 48)与对应的转变温度(340°C)和显微组织。这需要多步概念关联和综合分析能力，包括相变动力学、硬度测试原理和显微组织识别等多个知识点的整合应用。虽然不需要进行复杂的数学计算，但对材料科学基础理论的掌握深度要求较高，属于需要多角度分析论述的题目。" + "reasoning": "题型: 题目要求解释是否可能确定铁碳合金的成分，并说明存在两种可能的答案，这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的质量分数进行多步计算，并关联不同相的概念来确定合金成分。这涉及到对相图的理解和计算能力，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" }, { - "idx": 4243, - "question": "(b) Cite the difference between mechanical and annealing twins.", - "answer": "Mechanical twins are produced as a result of mechanical deformation and generally occur in BCC and HCP metals. Annealing twins form during annealing heat treatments, most often in FCC metals.", + "idx": 828, + "question": "Indicate the second main mechanism of alloy strengthening and explain its strengthening reason", + "answer": "Precipitation strengthening and dispersion strengthening. The compounds of alloying elements and matrix elements obtained through phase transformation processes in alloys, as well as hard particles mechanically mixed into the matrix material, both cause alloy strengthening, referred to as precipitation strengthening and dispersion strengthening, respectively. The effects of precipitation strengthening and dispersion strengthening are much greater than solid solution strengthening. When dislocations encounter second phases during movement, they need to cut through (small-sized particles in precipitation strengthening and particles in dispersion strengthening) or bypass (large-sized particles in precipitation strengthening) the second phases. Therefore, the second phases (precipitates and dispersoids) hinder dislocation motion.", "question_type": "short_answer", "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求解释两种孪晶的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对机械孪晶和退火孪晶这两种基本概念的定义和形成条件的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在简答题题型中，该题目要求解释两种孪晶的区别，涉及基础概念的记忆和简单对比。虽然需要掌握机械孪晶和退火孪晶的定义及形成条件，但不需要深入分析或阐述复杂概念体系，属于概念解释和描述的中等难度级别。" + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的第二种主要机制及其强化原因，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求记忆合金强化的第二种主要机制（沉淀强化和弥散强化），还需要解释其强化原因，涉及位错运动与第二相粒子的相互作用机制。这需要理解概念之间的关联，并进行一定的综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求识别合金强化的第二种主要机制（沉淀强化和弥散强化），还需要理解其强化原理。正确选项涉及多个概念的综合分析，包括相变过程、第二相粒子对位错运动的阻碍机制（切割或绕过），以及与固溶强化的效果比较。这需要考生具备较深的知识掌握和多角度分析能力，超出了简单的记忆或单一概念的应用。" + }, + { + "idx": 3439, + "question": "What are the main reasons for the different carbon contents in engineering structural steel, carburizing steel, quenched and tempered steel, spring steel, and bearing steel?", + "answer": "Engineering structural steel is mainly used for engineering structures, where the strength requirement is not high, but the weldability requirement is high, so the mass fraction of carbon is low. The carbon content of carburizing steel cannot be high to ensure high toughness in the core. Quenched and tempered steel should have good comprehensive mechanical properties after quenching and tempering, meaning not only high strength but also good toughness, so medium carbon steel is used. Spring steel requires high elastic limit and fatigue strength, so the mass fraction of carbon cannot be too low, but if it is too high, brittleness increases. Bearing steel requires high hardness and high wear resistance, so a high mass fraction of carbon is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同钢材中碳含量差异的主要原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同类型钢材的碳含量差异进行解释，涉及多个概念的综合分析和关联，需要理解各类钢材的性能要求与碳含量之间的关系，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度，因为它要求考生不仅理解不同钢材的基本特性，还需要综合分析碳含量与钢材性能之间的多角度关系。题目涉及五种不同类型的钢材，每种钢材的碳含量选择都有其特定的工程应用背景和性能要求，考生需要将这些概念关联起来进行多角度分析论述。此外，解题步骤较为复杂，需要考生具备较强的材料科学知识背景和综合分析能力。" + }, + { + "idx": 4350, + "question": "Is it possible to determine the composition of an iron-carbon alloy if the mass fraction of eutectoid ferrite is 0.82?", + "answer": "yes, it is possible to determine the alloy composition; and, in fact, there are two possible answers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述如何根据给定的质量分数确定铁碳合金的组成，答案提供了文字解释和可能的两种情况，符合简答题的特征。 | 知识层次: 题目需要应用铁碳相图的知识，通过给定的共析铁素体质量分数来计算合金的组成。这涉及到多步计算和概念关联，需要理解共析反应和杠杆定律的应用，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用铁碳相图知识、杠杆定律计算以及理解共析反应的概念。题目要求考生通过给定的共析铁素体质量分数反推合金成分，涉及多步计算和综合分析，且需要意识到存在两种可能的成分解（亚共析钢和过共析钢）。这种需要逆向思维和双重解意识的题目在选择题型中属于较复杂的考查方式。" + }, + { + "idx": 3381, + "question": "Why are medium carbon (alloy) steels mostly used to manufacture gearbox gears for machine tools?", + "answer": "Their working conditions are much better than those of automobiles, requiring certain toughness in the core and higher hardness on the surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么中碳（合金）钢主要用于制造机床齿轮箱齿轮，答案提供了文字解释和论述，说明其工作条件和性能要求，符合简答题的特征。 | 知识层次: 题目需要结合材料科学中的碳钢性能特点（如韧性、硬度）与具体应用场景（齿轮箱齿轮的工作条件）进行综合分析，涉及多概念关联和中等程度的推理分析。 | 难度: 在选择题中属于较高难度，题目涉及多个概念的综合分析，包括材料性能（韧性、硬度）、工作条件比较（机床齿轮箱与汽车齿轮的差异）以及材料选择依据。解题需要将材料科学知识与工程应用场景进行多角度关联，并理解表面处理与核心性能的不同要求。这种需要跨领域知识整合的题目在选择题型中属于较复杂类型。" + }, + { + "idx": 2078, + "question": "Point out the errors in the following concepts and correct them: (21) Pure metal crystallization grows in a dendritic morphology or a planar morphology, which is unrelated to the melting entropy of the metal.", + "answer": "Because it is also related to the structure of the liquid-solid interface (α=ξΔSm/k), i.e., it is related to the melting entropy of the metal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解纯金属结晶的基本形态（基础概念），还需要分析界面结构与熔化熵的关系（概念关联），并指出原陈述的错误（综合分析）。这涉及到多步思维过程和概念间的联系，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解金属结晶的形态与熔化熵之间的关系，并能够分析液体-固体界面结构的影响。题目要求不仅识别错误概念，还需提供正确的关联性解释，涉及多步计算和概念关联的综合分析。" + }, + { + "idx": 3210, + "question": "Can close-packed hexagonal metal magnesium produce cross-slip? What is the slip direction?", + "answer": "In addition to the (0001) $<11$ $\\overline{2}0>$ slip system, magnesium also has $|10\\overline{{1}}1\\}<11\\overline{{2}}0$ > slip systems, and the slip direction is always $<11\\overline{{2}}0:$, so cross-slip can occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁金属是否能够产生交叉滑移以及滑移方向，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目不仅需要记忆镁的滑移系统，还需要理解滑移方向的概念，并分析交叉滑移的可能性。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，题目涉及密排六方金属镁的滑移系统和交叉滑移的概念，需要考生不仅掌握基本的滑移方向知识，还需要理解交叉滑移的条件和机制。此外，题目要求综合分析不同滑移系统之间的关系，并准确识别滑移方向，这需要较深的知识掌握和多角度分析能力。" + }, + { + "idx": 235, + "question": "Compare the characteristics of the singular peritectic point in ternary invariant points, and write its equilibrium relationship", + "answer": "If the invariant point is at the intersection position, it is a singular eutectic point; if it is at the conjugate position, it is a double peritectic point. The phase transformation relationship is L_{(g)}+A⇌D+C, L_{(g)}+A+B⇌S", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较三元不变点中单一包晶点的特性并写出其平衡关系，需要文字解释和论述，答案也是以文字形式呈现的详细解释，符合简答题的特征。 | 知识层次: 题目要求比较三元不变点中的单一包晶点特征并写出其平衡关系，涉及多个概念的关联和综合分析，需要理解相图的基本原理并应用相关知识进行解释。虽然不涉及复杂的计算或创新设计，但需要一定的思维深度和概念关联能力。 | 难度: 在选择题型内，该题目属于较高难度，原因如下：" + }, + { + "idx": 4827, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Linear and syndiotactic poly(vinyl chloride) having a number-average molecular weight of 500,000 g/mol; linear polyethylene having a number-average molecular weight of 225,000 g/mol", + "answer": "Yes, it is possible to determine which polymer has the higher melting temperature. The linear polyethylene will have the greater melting temperature inasmuch as it will have a higher degree of crystallinity; polymers having a syndiotactic structure do not crystallize as easily as those polymers having identical single-atom side groups. With regard to molecular weight, or rather, degree of polymerization, it is about the same for both materials (8000), and therefore, is not a consideration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较熔点高低并给出理由，或说明无法判断的原因。答案也以详细的文字解释形式呈现，符合简答题的特征。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这涉及到对聚合物结构（线性聚乙烯和间规聚氯乙烯）和结晶度影响熔点的理解，以及分子量对熔点的影响的评估。虽然不需要复杂的计算，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解聚合物结构（线性与间规立构）、分子量影响、结晶度与熔点的关系等多个概念，并进行多角度比较分析。题目要求判断可能性、选择正确聚合物并解释原因，涉及多步推理和概念关联，超出基础记忆或单一概念应用层次。" + }, + { + "idx": 3382, + "question": "How to select the carbon content in steel for machine parts based on their service conditions?", + "answer": "For non-critical parts with low requirements for comprehensive mechanical properties, medium carbon steel can be selected. For parts requiring good surface wear resistance and high contact fatigue resistance, while the entire part withstands impact loads and the core requires high toughness, carburizing steel, i.e., low carbon steel or low carbon alloy steel, should be selected. For parts requiring high comprehensive mechanical properties, quenched and tempered steel, i.e., medium carbon steel or medium carbon alloy steel, should be selected. Carbon steel and alloy steel with higher carbon content can be used to manufacture springs. Bearings should be made of rolling bearing steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求基于服务条件选择钢材的碳含量，答案提供了详细的文字解释和论述，说明不同工况下应选择的钢材类型及其原因，符合简答题的特征。 | 知识层次: 题目要求根据不同的服役条件选择钢材的碳含量，涉及多个概念的综合应用和分析，如机械性能、磨损抵抗、疲劳抵抗等，需要将材料性能与使用条件关联起来进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解不同碳含量钢材的基本特性，还需要根据具体的服务条件（如非关键部件、表面耐磨性要求、冲击载荷承受能力、核心韧性需求等）进行多角度分析和综合判断。题目涉及多个概念关联和综合分析步骤，需要考生具备较强的知识应用能力和逻辑推理能力，因此在选择题型内属于等级4的难度。" + }, + { + "idx": 1038, + "question": "Law of the center of gravity", + "answer": "Law of the center of gravity: In a ternary alloy phase diagram, if $R$ decomposes into three phases $\\alpha,~\\beta,$ $\\gamma$, then the concentration point of $R$ phase must be located at the center of gravity of $\\Delta\\alpha\\beta\\gamma$ (which is the weight center of gravity of the three phases, not the geometric center of the triangle). Moreover, the weight of $R$ phase has the following relationship with the weights of $\\alpha$, $\\beta$, and $\\gamma$ phases: $$ \\begin{array}{r l}&{w_{R}\\times R d=w_{\\alpha}\\times\\alpha d}\\ &{w_{R}\\times R e=w_{\\beta}\\times\\beta e}\\ &{w_{R}\\times R f=w_{\\gamma}\\times\\gamma f}\\end{array}$$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对“Law of the center of gravity”进行解释和论述，答案提供了详细的文字描述和公式说明，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及三元合金相图中重心定律的应用，需要理解并应用重心定律进行多步计算和概念关联。虽然题目给出了具体的公式，但需要理解这些公式的物理意义以及如何在实际问题中应用，这超出了简单记忆或直接套用的范畴，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及三元合金相图中的重心定律，需要考生对相图的基本概念和重心定律有深入理解。其次，题目不仅要求识别重心定律的应用，还需要理解浓度点与三相重心之间的关系，以及重量关系的数学表达。此外，题目中的数学表达式和几何概念结合，增加了理解的复杂性。因此，该题目在选择题型中属于需要多角度分析和综合应用知识的难度等级。" + }, + { + "idx": 1885, + "question": "When a small amount of CaO is doped into ThO2, write the possible defect reaction equation (8)", + "answer": "8) 2CaO → CaTh'' + Cai'' + 2O0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出可能的缺陷反应方程，需要文字解释和论述，答案是一个具体的反应方程式，属于简答题类型。 | 知识层次: 题目要求写出掺杂CaO到ThO2中的缺陷反应方程，这需要理解缺陷化学的基本原理，并能够应用这些原理来推导具体的缺陷反应。虽然不涉及复杂的计算或多步推理，但需要对缺陷类型和电荷平衡有较好的理解，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。首先，题目要求考生理解掺杂过程中的缺陷反应方程，这需要掌握晶体缺陷的基本概念和符号表示。其次，正确选项涉及多步计算和概念关联，考生需要正确识别掺杂离子（Ca²⁺）在ThO₂基质中的取代位置和电荷补偿机制。此外，题目还要求综合分析掺杂过程中可能产生的缺陷类型（如CaTh''和Cai''），这超出了简单的记忆或单一概念的应用，需要考生具备较强的逻辑推理和综合分析能力。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 2312, + "question": "What are the requirements for compounding? Can any two materials form a composite material after compounding? What are the requirements for dissolution and wetting bonding?", + "answer": "For dissolution and wetting bonding, the matrix must wet the reinforcement, and mutual diffusion and dissolution should occur to form a bond. For reaction bonding, the matrix and reinforcement should react to form favorable interfacial products, whose thickness must be controlled below a critical value.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对复合材料的复合要求、溶解和润湿结合的要求进行文字解释和论述，答案也是以文字形式详细解释相关概念和条件，符合简答题的特征。 | 知识层次: 题目要求解释复合材料的复合要求以及溶解和润湿结合的条件，涉及多个概念的关联和综合分析，需要理解材料之间的相互作用和界面行为，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目涉及复合材料制备中的多个关键概念（溶解润湿结合与反应结合），要求考生不仅理解界面润湿和扩散溶解的基本原理，还需要掌握界面产物厚度控制这一特定条件。正确选项整合了两种不同结合机制的要求，需要进行多角度对比分析才能准确判断。虽然不涉及计算，但需要对复合材料界面科学有较深入的理解才能正确作答。" + }, + { + "idx": 883, + "question": "A compression test is conducted along the axial direction of an FCC metal single crystal specimen with a cross-sectional area of 10cm². The critical resolved shear stress is known to be 0.1kgf/mm², and the initial orientation of the rod axis is [215]. Please determine the double slip systems.", + "answer": "Double slip systems: (111)[011] + (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定双滑移系统，需要基于晶体学知识和方向分析进行文字解释和论述，答案以系统组合的形式给出，而非数值计算或选择判断。 | 知识层次: 题目需要理解FCC金属的滑移系统，并应用临界分切应力和晶体取向的知识来确定双滑移系统。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合运用晶体学知识、临界分切应力概念以及滑移系分析能力。解题过程涉及多个步骤：1) 确定FCC晶体的滑移系 2) 计算施密特因子 3) 分析初始取向[215]下的潜在滑移系 4) 判断双滑移条件。虽然题目给出了正确选项，但要在选择题中准确判断需要深入理解晶体塑性变形机制和滑移系激活条件，涉及中等应用层次的多步计算和概念关联。" + }, + { + "idx": 2175, + "question": "Give examples of the impact of Lüders bands on industrial production and methods to prevent them.", + "answer": "Lüders bands can cause the surface of workpieces made from low-carbon thin steel sheets to become rough and uneven during stamping and forming. The solution, based on the strain aging principle, involves subjecting the steel sheet to a slight cold rolling process (e.g., 1%∼2% reduction) before stamping to eliminate the yield point, followed by stamping and forming. Alternatively, adding small amounts of Ti, Al, C, and N to the steel to form compounds can also eliminate the yield point.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求给出具体例子和解决方法，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Lüders bands对工业生产的影响以及预防方法，涉及对材料科学中应变时效原理的理解和应用，需要多步分析和概念关联。虽然不涉及复杂计算，但需要对材料行为及其工业应用有较深入的理解和综合分析能力。 | 难度: 在选择题中属于较高难度，题目要求考生不仅要理解Lüders bands的概念及其对工业生产的影响，还需要掌握具体的预防方法（如冷轧工艺和合金添加）。这涉及到多步骤的分析和综合应用知识的能力，包括对材料科学原理（应变时效）的理解和实际工业应用的关联。此外，题目还要求考生能够区分不同解决方案的适用性和原理，这增加了题目的复杂性和难度。" + }, + { + "idx": 926, + "question": "Briefly describe the characteristics of the peritectic reaction in a binary system and calculate the degrees of freedom at equilibrium for each phase.", + "answer": "The peritectic reaction is: a liquid phase reacts with a solid phase to form another solid phase, where the newly formed solid phase envelops the original solid phase. The reaction requires diffusion within the solid phase and proceeds relatively slowly. When a peritectic reaction occurs, the degrees of freedom are 0, meaning the compositions of the three phases are fixed, and the temperature is also fixed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述包晶反应的特点并计算平衡时的自由度，需要文字解释和论述，没有涉及选择题、判断题或纯计算题的特征。 | 知识层次: 题目不仅要求描述包晶反应的基本特征（基础概念），还需要计算平衡时各相的自由度（简单应用），并解释其物理意义（概念关联）。这涉及多步思维过程和概念的综合运用，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解包晶反应的基本概念，还需要掌握自由度计算的方法，并将两者结合起来进行综合分析。题目涉及多步计算和概念关联，属于中等应用层次的知识点。此外，题目要求考生在选择题型中展示对复杂概念的理解和应用能力，这比单纯记忆或简单分析更具挑战性。因此，该题目在选择题型内属于较高难度等级。" + }, + { + "idx": 2352, + "question": "Predict the crystal structure of CsCl", + "answer": "From the appendix, the electronegativities of Cs and Cl are found to be 0.82 and 3.16, respectively: the ionic radii are r(Cs+)=0.165 nm, r(Cl-)=0.181 nm. The electronegativity difference ΔEN=3.16-0.82=2.34, the ionic bond character is 75%, the covalent character is 25%, primarily ionic bonding. The ratio of anion radius to cation radius r(Cs+)/r(Cl-)=0.165/0.181=0.912. From the data given in Table 3-5 in the text, the cation should occupy the interstitial site at the center of a cube formed by the anions, corresponding to CN(Cl-)=8; the ratio of the number of anions to cations is 1:1, so CN(Cs+)=8. This crystal structure should be a simple cubic structure, with Cl- at the cube corners and Cs+ at the cube center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来预测CsCl的晶体结构，答案中包含了详细的推理过程和依据，没有涉及选择、判断或数值计算。 | 知识层次: 题目需要综合运用电负性、离子半径比、配位数等概念，通过多步计算和查表分析，最终确定晶体结构。虽然涉及多个知识点，但主要是基于已有规则和数据的直接应用，不需要复杂的推理或创新。 | 难度: 在选择题型内，该题目属于较高难度，需要考生进行多步计算（如电负性差、离子半径比）、概念关联（离子键与共价键比例、配位数判断）以及综合分析（晶体结构预测）。虽然题目提供了部分数据，但要求考生能够整合多个知识点并应用表格数据进行推理，这超出了基础记忆或简单计算的范畴，属于多角度分析论述的层次。" + }, + { + "idx": 217, + "question": "What measures can be taken in production to increase or decrease the plasticity of clay to meet the needs of forming processes?", + "answer": "In production, the specific surface area of mineral components can be increased to enhance the capillary force, thereby increasing plasticity; the valence of adsorbed cations can also be increased or decreased to alter the plasticity of clay; or the particle size of minerals can be reduced to increase contact points, thereby enhancing the plasticity of clay;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述具体的生产措施来调节粘土的塑性，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求考生理解并应用材料科学中的塑性调节方法，涉及多个知识点（如矿物成分的比表面积、吸附阳离子的价态、矿物颗粒尺寸等）的综合应用，需要一定的分析和关联能力，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题型中，该题目要求考生不仅理解粘土塑性的基本概念，还需要掌握多种调控塑性的具体方法（如增加矿物组分比表面积、改变吸附阳离子价态、减小矿物粒径等）。这些知识点涉及材料科学中的多步计算和概念关联，需要考生进行综合分析才能正确作答。相比单纯记忆性选择题，该题需要更高层次的应用能力和多角度思考，因此在选择题型中属于较高难度等级。" + }, + { + "idx": 3440, + "question": "If 20CrMnTi is used as carburizing steel, what are the differences in its mechanical properties, process performance, and process characteristics? Why?", + "answer": "20CrMnTi is a medium-hardenability carburizing steel used for manufacturing larger-sized parts that bear moderate loads. The carburizing temperature is 930~950°C, the quenching temperature is 870~890°C (oil quenching), and the tempering temperature is 190°C. The differences mainly result from the types and contents of alloying elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释20CrMnTi作为渗碳钢在机械性能、工艺性能和工艺特性方面的差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析20CrMnTi作为渗碳钢在机械性能、工艺性能和工艺特性上的差异，并解释原因。这需要理解合金元素的类型和含量如何影响材料的性能，涉及多步分析和概念关联，但不需要过于复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，题目不仅要求理解20CrMnTi作为渗碳钢的基本性能和应用，还需要分析其机械性能、工艺性能和工艺特点的差异，并解释这些差异的原因。这涉及到对合金元素类型和含量的深入理解，以及它们如何影响材料的性能。此外，题目还要求综合多个知识点进行多角度分析，超出了简单的记忆或单一概念的应用。" + }, + { + "idx": 1328, + "question": "According to the reaction temperature from high to low, sequentially write the reaction formulas of the three-phase equilibrium reactions in the Fe-Fe3C alloy system", + "answer": "L0.53 + δ0.09 → γ0.17 (1495°C)\\nL4.3 → γ2.11 + Fe3C (1148°C)\\nγ0.77 → α0.0218 + Fe3C (727°C)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求按照反应温度从高到低的顺序写出Fe-Fe3C合金系统中的三相平衡反应式，答案是以文字形式列出具体的反应式和对应的温度，不需要计算或选择，属于简答题类型。 | 知识层次: 题目要求按照温度顺序写出Fe-Fe3C合金系统中的三相平衡反应公式，这需要理解合金相图的基本原理，并能够将不同温度下的反应进行关联和综合分析。虽然涉及记忆性知识，但更强调对相图的理解和应用，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。首先，题目要求考生掌握Fe-Fe3C合金系统中三相平衡反应的具体反应式及其对应的温度顺序，这需要深入理解相图和相关反应。其次，题目涉及多个反应式的记忆和排序，要求考生能够准确关联反应式与温度，并进行综合分析。此外，正确选项中的反应式和温度数据较为复杂，增加了记忆和理解的难度。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 3285, + "question": "Under what conditions can austenite transform into lamellar pearlite?", + "answer": "When the austenitizing temperature is high, the holding time is long, the composition of austenite is uniform, and the cooling rate is fast, lamellar pearlite is prone to form.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在什么条件下奥氏体可以转变为层状珠光体，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释奥氏体转变为层状珠光体的条件，涉及多个因素（温度、时间、成分均匀性、冷却速率）的综合分析，需要理解相变原理并关联实际工艺条件，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅掌握奥氏体向层状珠光体转变的基本条件，还需要综合分析多个因素（奥氏体化温度、保温时间、成分均匀性和冷却速率）之间的相互作用。这种多因素关联分析在选择题中属于较复杂的思维过程，需要考生具备较强的概念整合能力和综合分析能力，因此属于等级4难度。" + }, + { + "idx": 2489, + "question": "Write all the equivalent crystallographic direction indices in the <123> direction family of the cubic crystal system", + "answer": "<123>=[123]+[1̄23]+[12̄3]+[123̄]+[132]+[1̄32]+[13̄2]+[132̄]+[213]+[2̄13]+[21̄3]+[213̄]+[231]+[2̄31]+[23̄1]+[231̄]+[312]+[3̄12]+[31̄2]+[312̄]+[321]+[3̄21]+[32̄1]+[321̄]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出立方晶系中<123>方向族的所有等效结晶学方向指数，需要列举所有可能的组合，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目要求写出立方晶系中<123>方向族的所有等效晶向指数，这需要理解晶向指数的定义和立方晶系的对称性，并能够应用对称操作生成所有等效方向。虽然不涉及复杂的计算或综合分析，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求掌握立方晶系中等效晶向指数的概念，这需要深入理解晶体学中的对称性操作。其次，解题过程涉及多步计算和排列组合，需要系统性地考虑所有可能的符号变化和指数排列。此外，题目还要求综合分析不同晶向之间的等效关系，这超出了简单记忆或单一概念应用的范畴。虽然题目提供了正确选项，但在选择题型中理解和验证这些选项的正确性仍然需要较高的认知能力和计算技巧。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 2925, + "question": "After quenching, 1.2% steel obtains a martensite and a small amount of retained austenite structure. What changes will occur when heated to 680°C and held for 2 hours?", + "answer": "Carbides are distributed in granular form within the ferrite matrix, resulting in a granular pearlite structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料在特定热处理条件下的结构变化，答案提供了详细的文字描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求分析淬火后钢在特定热处理条件下的组织转变，涉及多个概念（马氏体、残余奥氏体、回火过程）的关联和综合分析，需要理解热处理工艺对材料微观结构的影响机制，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解淬火后的组织转变、回火过程中的相变行为以及最终组织的形成机制。题目要求考生将多个热处理概念（马氏体、残余奥氏体、碳化物析出、粒状珠光体形成）进行关联分析，并预测特定工艺参数（680°C保温2小时）下的微观组织演变。这超出了简单记忆的范畴，需要进行多步骤的逻辑推理和综合判断。" + }, + { + "idx": 3310, + "question": "Explain the application of upper bainite and lower bainite in production", + "answer": "a) Isothermal quenching of bainite (lower bainite) is often used to replace quenching + low-temperature tempering; b) Ultra-high strength steel obtains a composite structure of bainite (lower) + martensite to achieve the best combination of strength and toughness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释上贝氏体和下贝氏体在生产中的应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释上贝氏体和下贝氏体在生产中的应用，涉及对贝氏体形成条件、性能特点及其在热处理工艺中的具体应用的理解和综合分析。需要将贝氏体的分类（上贝氏体和下贝氏体）与其在实际生产中的具体应用场景联系起来，并进行一定的解释和论述。这属于中等应用层次，需要多步概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解上贝氏体和下贝氏体的基本概念，还需要掌握它们在工业生产中的具体应用场景。题目涉及等温淬火工艺替代传统淬火+低温回火的综合分析，以及超高强度钢中复合组织的性能优化策略，需要考生进行多角度分析和概念关联。正确选项包含两个需要综合判断的技术应用场景，在选择题型内属于需要较强应用分析能力的题目。" + }, + { + "idx": 3527, + "question": "Explain the role of Mg element in aluminum alloys", + "answer": "Magnesium has a good solid solution strengthening effect in aluminum, which can increase the strength of aluminum while also reducing its density. The precipitation strengthening effect of magnesium-aluminum alloys is not significant, but they exhibit good corrosion resistance and can be used as corrosion-resistant alloys. Magnesium cannot serve as the main additive element for high-strength aluminum alloys alone; it must be combined with other elements to fully utilize its effects.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁元素在铝合金中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释镁元素在铝合金中的作用，涉及固溶强化、沉淀强化、腐蚀抗力等多个概念的综合应用，需要理解镁元素与其他元素的协同效应，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解镁在铝合金中的基本固溶强化作用，还需要综合分析其与其他元素的协同效应、对密度的影响、腐蚀性能以及在高强度铝合金中的应用限制。这涉及多角度分析论述，超出了简单的概念记忆或单一知识点应用，属于较高难度的选择题。" + }, + { + "idx": 2555, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the rotation rule and the rotation axis.", + "answer": "The specimen axis turns toward [0 1], and the rotation axis is [2 1 3]×[0 1 1]=[2 1 2], i.e., [1 ].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述旋转规则和旋转轴，答案提供了详细的文字解释和推导过程，而不是简单的选择、判断或数值计算。 | 知识层次: 题目需要理解晶体取向和旋转规则，并应用向量叉积计算旋转轴，涉及多步计算和概念关联，但不需要深度推理或创新应用。 | 难度: 在选择题中属于较高难度，需要理解晶体学方向、旋转规则和向量叉积计算等多个概念，并进行多步综合分析和计算。题目要求确定旋转方向和旋转轴，涉及多个知识点的关联和综合应用，解题步骤较为复杂，对学生的综合分析能力要求较高。" + }, + { + "idx": 4344, + "question": "Is it possible to have an iron-carbon alloy for which the mass fractions of total ferrite and proeutectoid cementite are 0.846 and 0.049 , respectively? Why or why not?", + "answer": "yes, it is possible to have an iron-carbon alloy with mass fractions of total ferrite w_{\\alpha}=0.846 and proeutectoid cementite w_{\\mathrm{fe}_{3} C^{\\prime}}=0.049. the alloy composition for both conditions is 1.05 wt% C. since the composition values are equal, such an alloy exists.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释是否可能拥有特定质量分数的铁碳合金，并说明原因。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用铁碳相图的知识，进行多步计算和综合分析，以确定合金成分是否满足给定的质量分数条件。这涉及到对相图的理解、质量分数的计算以及成分的验证，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算和概念关联。题目要求考生不仅理解铁碳合金中不同相的质量分数关系，还需要通过计算验证合金成分的一致性。这种综合分析能力在选择题中较为复杂，超出了简单的概念记忆或单一计算步骤的要求。" + }, + { + "idx": 2217, + "question": "Explain the meanings of N0, G0, Qg, Qn and their influencing factors.", + "answer": "N0 and G0 are constants in the Arrhenius equation; Qn is the activation energy for recrystallization nucleation; Qg is the activation energy for recrystallized grain growth. Qn and Qg are mainly influenced by deformation amount, metal composition, metal purity, and original grain size. When the deformation amount exceeds 5%, Qn and Qg are approximately equal. For high-purity metals, the value of Qg is roughly equivalent to the activation energy for grain boundary self-diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多个术语的含义及其影响因素，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释多个专业术语的含义及其影响因素，涉及对Arrhenius方程中常数的理解、再结晶成核和晶粒生长的活化能概念，以及这些参数如何受变形量、金属成分、纯度和原始晶粒尺寸的影响。这需要将多个概念关联起来进行综合分析，而不仅仅是简单的记忆或理解。 | 难度: 在选择题中属于较高难度，题目要求理解多个专业术语（N0, G0, Qg, Qn）及其相互关系，并分析它们的影响因素。需要综合运用材料科学知识，包括Arrhenius方程、再结晶成核和晶粒生长的激活能等概念。此外，还需考虑变形量、金属成分、纯度和原始晶粒尺寸等多个影响因素，并进行比较分析。这种多角度分析和概念关联的要求使得题目在选择题型中难度较高。" + }, + { + "idx": 4791, + "question": "For the following pair of polymers, do the following: (1) state whether it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and cite the reason(s) for your choice; and (3) if it is not possible to decide, state why. Branched polyethylene with a number-average molecular weight of 100,000 g/mol; atactic polypropylene with a number-average molecular weight of 150,000 g/mol", + "answer": "No, it is not possible. Branched polyethylene will tend to have a low degree of crystallinity since branched polymers don't normally crystallize. The atactic polypropylene probably also has a relatively low degree of crystallinity; atactic structures also don't tend to crystallize, and polypropylene has a more complex repeat unit structure than does polyethylene.Tensile modulus increases with degree of crystallinity, and it is not possible to determine which polymer is more crystalline. Furthermore, tensile modulus is independent of molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较两种聚合物的拉伸模量并给出理由，或解释为何无法判断。答案也以文字形式详细解释了原因，符合简答题的特征。 | 知识层次: 题目要求对两种聚合物的拉伸模量进行比较，涉及对聚合物结构（支化聚乙烯和无规聚丙烯）、结晶度、分子量等概念的综合分析。需要理解结晶度对拉伸模量的影响，并能够关联不同结构对结晶度的潜在影响。虽然不涉及复杂计算，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生综合运用多个高分子材料科学的概念，包括分子量对性能的影响、结晶度与力学性能的关系、聚合物链结构（支化、无规立构）对结晶能力的影响等。题目要求考生不仅能够识别这些概念，还需要进行多角度比较分析（支化PE vs 无规PP），并最终得出无法比较的结论。这种需要同时考虑多个变量（结晶度、分子量、链结构）并理解它们之间相互作用关系的题目，在选择题型中属于较高难度（等级4）。虽然题目给出了正确选项，但解题过程需要较深入的概念理解和综合分析能力。" + }, + { + "idx": 3543, + "question": "What are the characteristics of the microstructure, properties, and applications of typical β titanium alloys?", + "answer": "Microstructure: β (quenched structure); Property characteristics: high strength, excellent stamping performance, can be strengthened by quenching and aging; Applications: parts working below 350°C, compressor blades, aircraft components", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对典型β钛合金的微观结构、性能和应用进行描述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对β钛合金的微观结构、性能特点和应用进行综合描述，涉及多个知识点的关联和综合分析，需要理解并应用相关概念，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题型内，该题目需要考生对β钛合金的微观结构、性能特点和应用场景进行多角度的综合分析和关联。题目不仅要求掌握基础概念（如β相淬火组织），还需要理解性能特点（高强度、优良冲压性能）与热处理工艺（淬火时效强化）之间的关联，并能将材料特性与实际应用（350°C以下部件、压缩机叶片）进行对应。这种需要同时处理多个知识维度并进行逻辑关联的题目，在选择题中属于较高难度。" + }, + { + "idx": 2398, + "question": "In a face-centered cubic crystal, there are two dislocations with their Burgers vectors $b$ and the planes on which they are gliding as follows: Dislocation A has $b^{[i]}=a[0]1]12$ and glides on the (111) plane; Dislocation B has $b^{(h)}=a[10\\overline{{1}}]/2$ and glides on the (111) plane. If the two dislocations are parallel, what are the tangent vectors of these two dislocations?", + "answer": "Since the (111) and (111) planes intersect, when the dislocations on these two planes are parallel to each other, the direction of the dislocation line can only be the line of intersection of the two planes. Using the zone law, it is easy to determine that the line of intersection of the (111) and (111) planes is [110], so the tangent vectors of the two dislocation lines are [110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定两个位错的切线向量，解答过程涉及晶体几何和位错理论的应用，需要详细的文字说明而非简单的选择或计算。 | 知识层次: 题目需要理解面心立方晶体中的位错性质，应用晶面相交的几何关系（区定律）来确定位错线的方向。这涉及多步分析和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 2381, + "question": "MgO dissolves into Al2O3 to form a solid solution. Assuming Mg2+ replaces Al3+, write the reaction equation using Kroger-Vink notation.", + "answer": "2MgO forms 2MgAl' + V..O + 2OOX through Al2O3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Kroger-Vink符号写出反应方程式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求使用Kroger-Vink符号表示固溶体形成反应，这需要理解缺陷化学的基本原理和符号规则，并能够将其应用于具体反应中。虽然不涉及复杂的计算或综合分析，但需要将多个概念（如离子取代、缺陷形成）关联起来，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求使用Kroger-Vink符号表示反应方程，这需要学生对缺陷化学符号系统有深入理解。其次，题目涉及离子替代反应，需要学生掌握电荷平衡和缺陷补偿的概念。此外，解题过程需要多步推理：1) 识别Mg2+替代Al3+产生的缺陷类型；2) 确定电荷补偿机制；3) 正确应用Kroger-Vink符号表示所有缺陷和晶格位置。这种综合分析能力和多概念关联的要求，使该题在选择题型中属于较难水平。" + }, + { + "idx": 3450, + "question": "5CrNiMo, 3Cr2W8V, and H11 (or H13) all belong to hot-work die steels. Are there any differences in their usage? Why?", + "answer": "Yes, there are differences. Their total alloying element contents are low-alloy (5CrNiMo), medium-alloy (H11), and high-alloy (3Cr2W8V), respectively. 5CrNiMo is used for hot forging dies, H11 replaces 3Cr2W8V for small and medium-sized mechanical forging dies and hot extrusion dies with relatively low operating temperatures, while 3Cr2W8V is used for hot extrusion dies. The reason for their differences in usage lies in the varying types and amounts of alloying elements, which result in different levels of thermal strength, thermal fatigue resistance, and high-temperature oxidation resistance, hence their different applications.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释不同热作模具钢的使用差异及其原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求对不同热作模具钢的使用差异进行比较和解释，涉及合金元素含量、热强度、热疲劳抗力等概念的综合分析，需要理解不同合金元素对性能的影响及其在实际应用中的选择依据。这属于中等应用层次，需要多步概念关联和综合分析。 | 难度: 在选择题型内，该题目属于较高难度，因为需要考生不仅掌握不同热作模具钢的基本分类（低合金、中合金、高合金），还要理解合金元素含量与性能（热强度、抗热疲劳性、高温抗氧化性）的关联性，并能综合分析不同钢种在实际应用中的选择依据（如锻造模、挤压模的工况差异）。题目要求将材料成分、性能、应用场景三个维度进行多角度关联分析，超越了单纯记忆或单一概念比较的层次。" + }, + { + "idx": 2835, + "question": "For a pre-annealed metal polycrystal, the true stress-strain curve in the plastic region can be approximately expressed as ∇σ_T= kε_T^n, where k and n are empirical constants, referred to as the strength coefficient and strain hardening exponent, respectively. If there are two materials, A and B, with roughly equal k values, but n_A=0.5 and n_B=0.2, which one has a higher dislocation density at the same plastic strain, and why?", + "answer": "When ε_T<1, if 0
Classification of solid-state phase transformationsCharacteristics of phase transformations
Allotropic transformation in pure metalsChanges from one crystal structure to another with temperature or pressure variation, involving nucleation and growth processes
Polymorphic transformation in solid solutionsSimilar to allotropic transformation, such as Y in Fe-Ni alloys
Precipitation transformationDecomposition of supersaturated solid solutions, precipitating metastable or stable secondary phases
Eutectoid transformationA single phase decomposes into two phases with different structures through eutectoid transformation, such as Y→α+FeC in Fe-C alloys
Peritectoid transformationTwo phases with different structures transform into another phase through peritectoid transformation, such as α+Y→β in Ag-Al alloys, often leaving residual α phase
Martensitic transformationNo change in composition between the new and old phases during transformation; atoms undergo coordinated rearrangement (shear) without diffusion, maintaining strict orientation relationships and coherency, with surface relief effects observable on polished surfaces
Massive transformationChanges in crystal structure of metals or alloys without composition change between new and old phases, characterized by nucleation and growth with minimal diffusion, rapid growth via incoherent interface migration, producing irregular massive products, as seen in pure iron, low-carbon steel, Cu-Al alloys, and Cu-Ga alloys
Bainitic transformationOccurs in steel and many non-ferrous alloys, combining features of martensitic and diffusional transformations, resulting in composition changes; in steel, bainitic transformation is considered to proceed via coherent shear of iron atoms and diffusion of carbon atoms
Spinodal decompositionA non-nucleation decomposition process where a solid solution decomposes into two phases with the same crystal structure but different compositions (continuously varying within a certain range)
Order-disorder transformationTransition of alloy elements from random to ordered arrangement without structural change
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释各种固态相变的主要特征，答案以表格形式详细列出了不同类型相变的分类和特征，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求对不同类型的固态相变进行分类并描述其主要特征，这需要理解各种相变的基本原理和特点，并进行一定的综合分析。虽然涉及记忆性知识，但更强调对概念的理解和关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅掌握多种固态相变的基本概念，还需要理解每种相变的具体特征和区别。题目涉及的知识点较多，包括多种相变类型的分类和详细描述，需要考生具备较强的综合分析能力和概念关联能力。此外，题目中的正确选项以表格形式呈现，增加了信息的复杂性和理解难度，要求考生能够快速准确地提取和比较关键信息。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 2476, + "question": "If the stored energy is mainly contributed by dislocations, establish the relationship between dislocation density and critical nucleus size.", + "answer": "The energy of a dislocation per unit length is approximately Gb^2. Let the dislocation density be ρ, then the dislocation energy per unit volume is ρGb^2. If the stored energy E is mainly contributed by dislocations, the relationship between the critical nucleus radius and dislocation density is r* = 4γ/(ρGb^2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求建立关系并解释，答案提供了详细的文字解释和公式推导，符合简答题的特征 | 知识层次: 题目需要建立位错密度与临界核尺寸之间的关系，涉及位错能量计算和临界核半径公式的应用。虽然涉及基本概念（位错能量、临界核尺寸），但需要多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求建立位错密度与临界核尺寸之间的关系，这涉及到多个材料科学的核心概念，如位错能量、临界核半径等。其次，解题步骤较为复杂，需要理解位错能量与位错密度的关系，并将其与临界核尺寸的计算公式相结合。此外，题目要求综合分析多个概念并进行多步计算，这在选择题型中属于较为复杂的任务。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 2260, + "question": "What is the difference between continuous and discontinuous precipitation?", + "answer": "If precipitation occurs simultaneously throughout the parent phase, and the composition of the parent phase changes continuously with the formation of the new phase, but the grain morphology and orientation remain unchanged, it is called continuous precipitation. In contrast to continuous precipitation, when precipitation occurs, the solid solution within a certain range around it immediately changes from a supersaturated state to a saturated state, forming a distinct interface with the original composition of the parent phase. After nucleation at grain boundaries, it grows into the grain interior with an alternating lamellar distribution. Not only does the composition change abruptly at the interface, but the orientation also changes, which is called discontinuous precipitation. The main difference lies in the length of the diffusion path. In the former, the diffusion field extends over a considerable distance, while in the latter, the diffusion distance is only on the order of the lamellar spacing (generally less than 1 μm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释连续和不连续沉淀的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释连续和不连续析出的区别，涉及对析出过程的理解、扩散路径的分析以及微观结构的描述。虽然包含基础概念，但需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解连续和不连续析出的基本概念，还需要掌握两者在析出过程中的微观结构变化、成分变化、取向变化等多方面的差异。解题时需要综合分析多个知识点，包括扩散路径长度、界面特性、析出形态等，并进行多角度的比较分析。这种深度和广度的知识要求，使得该题目在选择题型中属于较难的水平。" + }, + { + "idx": 2888, + "question": "Based on the shown CaO·ZrO2 phase diagram, write down all the isothermal three-phase transformations.", + "answer": "There are three isothermal three-phase transformations in the shown ZrO2-σ·CaO phase diagram: peritectic reaction: L+T-ZrO3→C-ZrO2; eutectic reaction: L→(C-ZrO2+ZrCaO3); eutectoid reaction: T-ZrO2→M-ZrO2+C-ZrO2; where L represents liquid phase, T represents tetragonal, C represents cubic, M represents monoclinic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据相图写出所有等温三相转变，答案需要文字解释和论述，没有选项或计算要求 | 知识层次: 题目要求基于相图识别等温三相转变，需要理解相图的基本原理和三相反应的类型（包晶、共晶、共析），并能将相图中的信息与这些概念关联起来。这需要一定的综合分析能力，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求基于相图识别所有等温三相转变，这需要深入理解相图的结构和符号含义。其次，正确选项涉及多个专业术语（如peritectic、eutectic、eutectoid反应）和相变类型（L, T-ZrO3, C-ZrO2等），需要考生具备较强的相图分析能力和材料科学专业知识。此外，解题过程需要综合分析和关联多个概念，而不仅仅是简单的记忆或单一概念的应用。因此，在选择题型中，该题目属于多角度分析论述的难度等级。" + }, + { + "idx": 4264, + "question": "A cylindrical rod 100mm long and having a diameter of 10.0mm is to be deformed using a tensile load of 27,500 N. It must not experience plastic deformation. Of the materials listed as follows, which are possible candidates? Justify your choice(s).", + "answer": "Of the alloys listed, the steel alloy is a possible candidate because it meets the criterion of not experiencing plastic deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个材料中选择合适的候选材料，并需要文字解释和论述选择的合理性，而不是简单的选择或计算。 | 知识层次: 题目要求考生在给定的材料中选择合适的候选材料，确保在给定载荷下不发生塑性变形。这需要考生理解材料的力学性能（如屈服强度）与载荷之间的关系，并进行多步计算（如计算应力）和综合分析（比较不同材料的性能）。虽然不涉及复杂的推理或创新设计，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生进行多步计算（如应力计算）、概念关联（理解塑性变形的条件）以及综合分析（比较不同材料的性能）。此外，题目还要求考生在多个选项中做出合理的选择，并给出明确的理由，这增加了题目的复杂性和难度。" + }, + { + "idx": 2154, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], indicate the direction of dislocation line movement during slip in the cases of pure edge dislocation and pure screw dislocation.", + "answer": "In the case of pure edge dislocation, the direction of dislocation line movement is parallel to b; in the case of pure screw dislocation, the direction of dislocation line movement is perpendicular to b.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述纯刃型位错和纯螺型位错在位错线移动时的方向，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析面心立方晶体中特定滑移系统下纯刃型位错和纯螺型位错的运动方向，需要理解位错类型与运动方向的关系，并能够将这一知识应用到具体晶体结构中。这涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 3521, + "question": "Please specify the type of cast iron and heat treatment method that should be used for ball mill liners, and why?", + "answer": "Ball mill liners: alloy nodular cast iron (such as medium manganese cast iron).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述特定材料的选择原因，答案需要文字说明而非简单选择或判断 | 知识层次: 题目要求选择特定类型的铸铁和热处理方法来满足球磨机衬板的使用需求，这需要理解不同铸铁材料的性能特点及其热处理工艺的影响，属于多概念关联和综合分析的应用层次。虽然不涉及复杂的计算或深度机理分析，但需要综合考虑材料选择与工艺匹配的合理性。 | 难度: 在选择题型内，该题目要求考生不仅掌握球磨机衬板材料的基本选择标准，还需要理解合金球墨铸铁（如中锰铸铁）的具体特性和适用原因。这涉及到多步概念关联和综合分析，包括材料性能、应用场景和热处理方法的匹配。虽然题目提供了正确选项，但考生仍需具备较深的知识储备和实际应用能力才能准确判断，因此属于较高难度等级。" + }, + { + "idx": 1938, + "question": "Discuss the conditions and characteristics of dissolution-precipitation mass transfer", + "answer": "The conditions for dissolution-precipitation mass transfer are: a considerable amount of liquid phase, high solubility of the solid phase in the liquid phase, and the liquid phase can wet the solid phase; the characteristics are: dissolution at particle contact points and deposition on flat surfaces, dissolution of small grains and deposition on large grains, and the mass transfer process is also a grain growth process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论溶解-沉淀传质的条件和特征，需要文字解释和论述，答案也提供了详细的描述和解释，符合简答题的特点。 | 知识层次: 题目要求讨论溶解-沉淀传质的条件和特征，涉及多个知识点的关联和综合分析，需要理解基本原理并能够解释其在实际过程中的表现，属于中等应用层次。 | 难度: 在选择题型中，该题目需要考生理解并综合多个概念（溶解-沉淀传质的条件和特征），并能够将这些概念关联起来进行分析。题目不仅要求识别基本条件（液相量、溶解度、润湿性），还需要掌握具体的传质特征（接触点溶解、平坦面沉积、小颗粒溶解大颗粒沉积、晶粒生长过程）。这种多角度分析和概念关联的要求使得题目在选择题型中属于较高难度等级。" + }, + { + "idx": 4497, + "question": "For the following pairs of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (b) Network phenol-formaldehyde; linear and heavily crosslinked cis-isoprene.", + "answer": "No, it is not possible to decide for these two polymers. Both heavily crosslinked and network polymers are not likely to crystallize.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行判断，并给出理由或解释为什么无法判断。这需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求对不同聚合物的结晶可能性进行比较和判断，需要理解聚合物结构（网络结构和线性交联结构）对结晶行为的影响，并进行综合分析。虽然不涉及复杂计算，但需要对材料科学中的结晶原理和聚合物结构有较深入的理解和应用能力。 | 难度: 在选择题中属于较高难度，需要综合理解聚合物结晶性、交联度影响等概念，并进行多角度比较分析。题目要求评估两种高度交联聚合物的结晶可能性，涉及对网络结构和线性交联结构的深入理解，以及判断两者均难以结晶的原因，属于多角度分析论述的层次。" + }, + { + "idx": 1480, + "question": "Explain the characteristics of the recovery process when cold-deformed metal is heated", + "answer": "During the recovery process, the microstructure does not change, and the elongated grains in the deformed state are still maintained. The recovery process completely eliminates the macroscopic first-class stresses caused by deformation and removes most of the microscopic second-class stresses. Generally, mechanical properties change little during recovery, with hardness and strength slightly decreasing, plasticity slightly improving, and some physical properties undergoing significant changes—resistivity notably decreases, while density increases. The deformation-stored energy is partially released during the recovery stage.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释冷变形金属加热时回复过程的特性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷变形金属加热时的回复过程特性，涉及微观结构、应力消除、机械性能和物理性能变化等多方面的综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和综合分析，思维过程有一定深度。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅理解冷变形金属加热过程中的回复过程，还需要掌握微观结构变化、应力消除、机械性能变化以及物理性能变化等多个方面的知识。此外，题目涉及的知识点需要考生进行多角度分析，包括宏观和微观层面的变化，以及不同性能指标的变化趋势。这种综合分析能力在选择题型中属于较高要求，因此难度等级为4。" + }, + { + "idx": 2092, + "question": "How to obtain the mass and Cu content of solid α4 by heating solid α3 to melting and slowly cooling it to 935°C before pouring off the liquid?", + "answer": "Heat α3 to melting again, slowly cool it to 935°C, pour off the liquid, leaving only α4, with a mass of 180g and a Cu content of w_Cu≈0.013.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字描述如何通过加热和冷却过程获得特定固体的质量和铜含量，答案提供了具体的操作步骤和结果，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目涉及多步操作（加热、冷却、倒出液体）和综合分析（计算质量和铜含量），需要理解相图概念并应用相关原理进行计算，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及多步操作（加热、冷却、倾倒液体）和多个概念（相变、成分分析）的综合应用。其次，解题需要准确理解相图原理和成分计算，并能将实验操作步骤与理论计算结果关联起来。最后，题目要求考生在选择题的有限选项中识别出同时满足质量（180g）和成分（w_Cu≈0.013）两个条件的正确答案，这需要较强的综合分析能力。这些因素使得该题在选择题型中属于需要多角度分析论述的难度等级。" + }, + { + "idx": 665, + "question": "What are the methods for controlling the texture of metal materials?", + "answer": "One method to control texture is by regulating the processing and heat treatment regimes to obtain a processed structure with only slight texture and a fine-grained recrystallized structure. Additionally, altering the production process of rolled plates, combining intermediate recrystallization annealing during cold working with final recovery annealing can control texture. The cross-rolling method can also be employed. Controlling the hot rolling process of aluminum alloy sheets, multi-directional cross cold rolling, and corresponding annealing can reduce the formation of ears.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释控制金属材料织构的方法，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目涉及多种控制金属材料织构的方法，需要理解不同加工和热处理工艺对织构的影响，并进行综合分析。虽然不需要复杂的推理或创新设计，但需要将多个概念关联起来，如加工工艺、热处理和织构控制之间的关系，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握金属材料织构控制的基本方法，还需要理解多步骤的加工和热处理工艺的综合应用。题目涉及的知识点包括加工工艺调控、热处理制度、冷热轧制工艺以及退火处理等多个方面，需要考生能够将这些概念关联起来进行综合分析。此外，题目还提到了具体的工艺方法如交叉轧制和多向冷轧，这要求考生具备一定的实际应用知识。因此，该题目在选择题型中属于多角度分析论述的难度等级。" + }, + { + "idx": 886, + "question": "A single crystal test bar of an FCC metal with a cross-sectional area of 10 cm² is subjected to a compression test along the axial direction. The critical resolved shear stress is known to be 0.1 kgf/mm², and the initial orientation of the bar axis is [215]. Please determine the initial slip system (specific indices are required).", + "answer": "Initial slip system: (111)[011].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定初始滑移系统（需要具体的指数），这需要文字解释和论述，而不是简单的选择、判断或数值计算。 | 知识层次: 题目要求确定初始滑移系统，需要理解FCC金属的滑移系概念，并应用临界分切应力定律进行计算。这涉及到多步计算和概念关联，包括确定可能的滑移面和滑移方向，计算施密特因子，并选择具有最大分切应力的滑移系统。虽然不涉及复杂的推理分析或创新应用，但需要一定的综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算和综合分析。具体来说，考生需要：" + }, + { + "idx": 77, + "question": "What are the factors affecting the formation of substitutional solid solutions?", + "answer": "Factors influencing the formation of substitutional solid solutions include: (1) Ionic size: The 15% rule - 1. If (R1-R2)/R1 > 15%, discontinuous. 2. If ≤15%, continuous. 3. If >40%, solid solution cannot form. (2) Ionic valence: Same valence leads to continuous solid solution formation. (3) Crystal structure factors: Same structure of matrix and impurity results in continuous solid solution. (4) Field strength factor. (5) Electronegativity: Small difference favors solid solution formation, while large difference leads to compound formation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求列举和解释影响置换固溶体形成的因素，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释影响置换固溶体形成的多个因素，涉及离子尺寸、离子价态、晶体结构等多个概念的综合应用和分析，需要理解这些因素之间的关联及其对固溶体形成的影响机制，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生掌握多个关键因素（离子尺寸、离子价态、晶体结构、场强因子、电负性）并理解它们之间的相互作用关系。正确选项不仅需要识别这些因素，还要理解15%规则等具体量化标准，以及不同条件下（连续/不连续固溶体、化合物形成）的判定逻辑。这超出了简单记忆的范畴，需要考生进行多角度分析和概念关联，符合等级4\"多角度分析论述\"的标准。" + }, + { + "idx": 3363, + "question": "Discuss the factors affecting the strength of materials", + "answer": "The mechanical properties of materials are related to their chemical composition, internal microstructure, inclusions and surface microstructure, as well as stress state.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论影响材料强度的因素，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求讨论影响材料强度的因素，涉及多个知识点的关联和综合分析，如化学成分、内部微观结构、夹杂物和表面微观结构等，需要理解这些因素如何相互作用影响材料强度，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅理解材料强度的基本概念，还需要综合分析多个影响因素（化学组成、内部微观结构、夹杂物、表面微观结构、应力状态）之间的关联性。这超出了单一概念的记忆或简单应用，属于多角度分析论述的层次，符合等级4的标准。" }, { "idx": 4348, @@ -657,31 +9057,9163 @@ "knowledge_level_name": "中等应用", "difficulty": 4, "final_level": "Level_5", - "reasoning": "题型: 题目要求解释合金的组成情况，并给出了具体的成分数值，需要文字解释和论述来回答，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解共析渗碳体和先共析渗碳体的概念，并运用铁碳相图进行多步分析来确定合金成分，涉及概念关联和综合分析。 | 难度: 在简答题中属于较高难度，需要理解并关联多个概念（如eutectoid cementite和proeutectoid cementite），进行多步计算（确定合金成分），并进行综合分析（解释为什么特定成分会导致这两种相的存在）。这超出了基础概念回忆或简单计算的范畴，属于多角度分析论述的层次。" + "reasoning": "题型: 题目要求解释合金的组成情况，并给出了具体的成分数值，需要文字解释和论述来回答，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解共析渗碳体和先共析渗碳体的概念，并进行多步计算来确定合金成分。这涉及到相图的应用和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生掌握铁碳相图的基本概念，理解共析渗碳体和先共析渗碳体的形成条件，并能进行多步计算和综合分析。题目不仅要求考生识别合金成分，还需要将多个知识点关联起来，进行较为复杂的推理和计算。" }, { - "idx": 4528, - "question": "Cite one similarity between precipitation hardening and dispersion strengthening.", - "answer": "The similarity between precipitation hardening and dispersion strengthening is the strengthening mechanism--i.e., the precipitates/particles effectively hinder dislocation motion.", + "idx": 3948, + "question": "If an increased steady-state flow rate of O2 (oxygen molecules per second) to the cornea is desired, is increasing the diffusivity of oxygen gas by decreasing the contact lens porosity likely to be useful? Note: the flow rate is equal to product of the diffusion flux and an area of interest through which diffusion occurs.", + "answer": "If the lens features more voids, we expect the oxygen to permeate the membrane faster since oxygen should be able to transit voids faster than the bulk lens material.", "question_type": "short_answer", "question_type_name": "简答题", - "knowledge_level": "basic_concepts", - "knowledge_level_name": "基础概念记忆", - "difficulty": 2, - "final_level": "Level_3", - "reasoning": "题型: 题目要求用文字解释和论述两种强化机制的相似点，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对两种强化机制的基本概念的理解和记忆，只需要回答一个相似点，不涉及复杂的应用或分析。 | 难度: 在简答题题型中，该题目要求解释两种强化机制的相似之处，属于概念解释和描述的难度级别。虽然需要理解两种机制的基本原理，但不需要深入阐述复杂的概念体系或进行多层次的比较分析。" + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行解释和论述，答案提供了详细的文字解释，而非简单的选择、判断或计算。 | 知识层次: 题目需要理解扩散通量与孔隙率的关系，并应用扩散原理分析实际问题。虽然不涉及复杂计算，但需要将多个概念（扩散通量、孔隙率、稳态流动）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解扩散通量、孔隙率对扩散系数的影响以及稳态流动条件。题目要求分析接触镜孔隙率变化如何影响氧气扩散速率，并关联到实际应用中的氧气流量需求。解题步骤涉及多步概念关联和综合分析，超出了简单记忆或单一概念应用的层次。" }, { - "idx": 4562, - "question": "Briefly explain why cold-worked metals are more susceptible to corrosion than noncold-worked metals.", - "answer": "Cold-worked metals are more susceptible to corrosion than noncold-worked metals because of the increased dislocation density for the latter. The region in the vicinity of a dislocation that intersects the surface is at a higher energy state, and, therefore, is more readily attacked by a corrosive solution.", + "idx": 654, + "question": "For industrial pure copper ingots with low stacking fault energy, after hot breakdown rolling at $T=0.5T_{\\\\xi\\\\sharp,\\\\xi}$ temperature, what methods can be used in the final process to obtain soft-state products, and why?", + "answer": "To obtain soft-state products, cold working followed by recrystallization annealing can be used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述如何通过特定方法获得软态产品，并说明原因，答案需要文字解释而非选择、判断或计算。 | 知识层次: 题目需要理解低堆垛层错能工业纯铜的热轧工艺，并应用冷加工和再结晶退火的知识来解决问题。这涉及到多步工艺选择和基本原理的应用，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 2152, + "question": "For a face-centered cubic crystal, the movable slip system is (111)[110]. If the slip is caused by a pure edge dislocation, indicate the direction of the dislocation line.", + "answer": "The dislocation line lies on the slip plane (111). Let the direction of the dislocation line be [uow], then u+v-w=0; the dislocation line is perpendicular to b, i.e., perpendicular to [110], so -u+v=0. From the above two equations, u:v:w=1:1:2, thus the direction of the dislocation line is [112].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来确定位错线的方向，答案给出了详细的推导过程和结论，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解面心立方晶体的滑移系统，并应用几何关系推导位错线方向。涉及多步计算和概念关联，需要综合分析滑移面、位错线和柏氏矢量的几何关系。 | 难度: 在选择题型中，该题目属于较高难度。原因如下：" + }, + { + "idx": 682, + "question": "How to control the grain size of materials in production", + "answer": "1. Use inoculation treatment or rapid cooling to refine grains during casting; 2. Control rolling process parameters to refine the microstructure during hot working; 3. Utilize alloy elements to pin grain boundaries and inhibit grain growth during recrystallization annealing; 4. Coordinate the relationship between cold deformation amount and heating temperature according to the recrystallization diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释如何控制材料生产中的晶粒尺寸，答案提供了多个步骤和方法的文字论述，符合简答题的特征。 | 知识层次: 题目要求对材料生产过程中晶粒尺寸控制的方法进行解释和论述，涉及多个工艺步骤（铸造、热加工、再结晶退火等）的综合应用，需要理解不同工艺参数对晶粒尺寸的影响，并进行概念关联和综合分析。虽然不涉及复杂计算，但需要多步骤的思维过程和工艺参数的协调控制。 | 难度: 在选择题型内，该题目属于较高难度，因为：" + }, + { + "idx": 2112, + "question": "Point out the errors in the following concept and correct them: From the condition for constitutional supercooling <
MaterialMicrostructurePropertiesHeat treatment
Cupronickelα (Cu-Ni solid solution)Good strength, excellent plasticity allowing hot and cold deformation, good corrosion resistance, high resistivityStress relief annealing
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较铜镍合金的微观结构、性能和热处理特性，需要文字解释和论述，答案以表格形式呈现了详细的比较内容，符合简答题的特征。 | 知识层次: 题目要求比较铜镍合金的微观结构、性能和热处理特性，涉及多个知识点的关联和综合分析，需要理解材料特性与处理工艺之间的关系，属于中等应用层次。 | 难度: 在选择题型中，该题目要求对cupronickel的微观结构、性能和热处理特性进行多角度分析论述。虽然题目提供了正确选项，但需要考生具备较深的知识掌握和综合分析能力，能够理解并关联多个概念（如固溶体结构、力学性能、热处理工艺等）。这种题目在选择题中属于较高难度，因为它不仅要求记忆知识点，还需要进行概念间的关联和比较分析。" + }, + { + "idx": 3379, + "question": "What is the role of carbon and alloying elements in high-speed steel?", + "answer": "The purpose of high carbon content is to form carbides with carbide-forming elements such as Cr, W, Mo, and V, and to ensure a strong martensitic matrix to enhance the hardness and wear resistance of the steel. W, Mo, and V primarily improve the red hardness of the steel, as the carbides formed by these elements have high hardness and produce a 'secondary hardening' effect, thereby significantly enhancing the steel's red hardness, hardness, and wear resistance. Cr mainly improves the hardenability of the steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释碳和合金元素在高速钢中的作用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释碳和合金元素在高速钢中的作用，涉及多个元素的协同效应和机理解释，需要综合分析不同元素对钢性能的影响，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解高碳钢和合金元素的基本作用，还需要综合分析不同元素（如Cr、W、Mo、V）在高速钢中的具体功能及其相互作用。题目涉及多个概念（如碳化物形成、马氏体基体、红硬性、二次硬化效应等），并要求考生将这些概念关联起来，进行多角度分析。此外，解题步骤较为复杂，需要考生具备较强的材料科学知识背景和综合分析能力。" + }, + { + "idx": 3553, + "question": "Please list several examples of strengthening alloys during the casting process", + "answer": "For example, the inoculation treatment of gray cast iron (adding about $4\\%$ ferrosilicon or calcium-silicon alloy to the molten iron during casting for inoculation treatment), and the modification treatment of aluminum-silicon alloys (adding a modifier $\\frac{2}{3}\\mathrm{{NaF}+}$ $\\frac13\\mathrm{NaCl}$ to the alloy melt before pouring)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列举几个例子来说明在铸造过程中强化合金的方法，答案提供了具体的例子和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求列举铸造过程中强化合金的例子，并给出了具体的处理方法。这属于直接应用已有知识，不需要复杂的分析或综合。虽然涉及具体的合金和处理方法，但主要是记忆和简单应用层面的知识。 | 难度: 在选择题型中，该题目属于较高难度。题目要求列举铸造过程中强化合金的具体实例，并提供了详细的处理方法和添加剂的配比（如灰铸铁的孕育处理加入4%的硅铁或硅钙合金，铝硅合金的变质处理加入2/3 NaF + 1/3 NaCl的变质剂）。这些内容不仅需要考生掌握相关知识点，还需要对具体的工艺参数和材料配比有较深的理解和记忆。因此，在选择题型中，该题目属于应用实例详细解释的难度等级。" + }, + { + "idx": 231, + "question": "At what temperature does the clay completely melt?", + "answer": "Complete melting means the solid phase completely disappears, which should be at the temperature where the 33% line intersects with the liquidus line.", "question_type": "short_answer", "question_type_name": "简答题", "knowledge_level": "medium_application", "knowledge_level_name": "中等应用", "difficulty": 3, "final_level": "Level_4", - "reasoning": "题型: 题目要求简要解释冷加工金属比非冷加工金属更容易腐蚀的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷加工金属更易腐蚀的原因，涉及位错密度与腐蚀敏感性的关联，需要理解位错对材料表面能状态的影响，并进行概念关联和综合分析。 | 难度: 在简答题中属于中等难度，需要理解冷加工金属的位错密度增加及其对腐蚀敏感性的影响，并进行简要的解释和论述。虽然涉及概念关联，但不需要多角度或深度分析。" + "reasoning": "题型: 题目要求解释在什么温度下粘土完全熔化，答案需要文字解释和论述，说明完全熔化的定义以及如何确定该温度，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解相图的基本原理，并能通过分析相图中的特定线（33%线和液相线）的交点来确定完全熔化的温度。这涉及到对相图的理解和应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解相图的基本概念（如液相线、固相线），并能将图表信息与百分比数据关联分析。虽然不涉及复杂计算，但要求考生综合运用相图知识和数据解读能力来确定完全熔化的温度点。" + }, + { + "idx": 1191, + "question": "How to solve the difficulties caused by work hardening in subsequent processing?", + "answer": "Recrystallization annealing can be used to eliminate the difficulties caused by work hardening in subsequent processing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何解决加工硬化带来的困难，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目涉及工作硬化的后续处理问题，需要理解工作硬化的概念及其影响，并应用再结晶退火这一解决方案。这需要多步思维过程，包括识别问题、理解再结晶退火的作用机制，并将其应用于具体情境中。虽然不涉及复杂的计算或深度机理分析，但需要对相关概念进行关联和综合应用。 | 难度: 在选择题中属于中等难度，题目涉及工作硬化和再结晶退火的概念关联，需要考生理解材料加工过程中的微观结构变化及其对后续加工的影响。虽然题目给出了正确选项，但考生仍需掌握工作硬化的基本原理和再结晶退火的作用机制，才能准确选择答案。这要求一定的综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 4416, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.95 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 840°C (1545°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或进行复杂的计算。虽然答案是一个数值，但解答过程需要基于材料科学知识（如铁碳相图）进行解释和判断，属于需要简要论述的简答题类型。 | 知识层次: 题目需要理解铁碳合金相图，并能够根据给定的碳含量（0.95 wt% C）确定奥氏体化温度。这涉及到多步分析和概念关联，包括相变温度和合金成分的关系，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，能够根据合金成分（0.95 wt% C）定位到共析点附近，并知道奥氏体化温度必须高于Acm线。虽然不需要复杂的计算，但需要将多个概念关联起来进行综合分析。" + }, + { + "idx": 3166, + "question": "To dissolve MgF2 into LiF, what type of vacancies should be introduced into LiF?", + "answer": "Dissolving MgF2 into LiF, i.e., replacing Li+ with Mg2+, generates cation vacancies.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释和论述溶解MgF2到LiF中时应该引入的空位类型，答案以文字解释的形式给出，没有选项或计算要求。 | 知识层次: 题目需要理解溶解过程中离子替换的机制，并关联到空位的产生，涉及多步推理和概念关联，但不需要复杂的综合分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解离子替换的概念以及由此产生的空位类型。虽然题目涉及多个概念（离子替换、空位形成），但在选择题型中，正确选项直接给出了结论，减少了分析步骤的复杂性。考生需要具备将Mg2+替换Li+与阳离子空位形成关联起来的能力，这属于中等应用层次的知识要求。" + }, + { + "idx": 343, + "question": "Briefly describe the effect of deformation temperature on metal properties under uniaxial compression.", + "answer": "As the deformation temperature increases, the rates of both strength increase and plasticity decrease slow down.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述变形温度对金属性能的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释变形温度对金属性能的影响，需要理解温度与金属力学性能（强度和塑性）之间的关系，并进行一定的综合分析。这涉及到多个概念的关联和中等程度的分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解金属变形温度与强度、塑性之间的关系，并能综合分析温度变化对这两种性能变化速率的影响。题目要求考生将多个概念关联起来，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3497, + "question": "How to distinguish between 45 steel and HT150 metals through macroscopic fracture analysis", + "answer": "Macroscopic fracture analysis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来区分两种金属材料，答案形式为文字描述而非选择、判断或计算。 | 知识层次: 题目要求通过宏观断口分析区分45钢和HT150金属，这需要理解两种材料的断口特征（如45钢的韧性断裂和HT150的脆性断裂），并能将这些特征与实际观察结果关联起来进行分析。虽然不涉及复杂计算，但需要综合运用材料科学知识进行判断，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属材料的宏观断裂特征（如45钢的韧性断裂和HT150的脆性断裂表现），并能通过断口形貌（纤维状/结晶状）进行区分。题目要求将材料性能知识与实际观察技能结合，但无需多角度或深度关联性分析。" + }, + { + "idx": 4918, + "question": "Briefly explain why thermal stresses may be introduced into a structure by rapid heating or cooling.", + "answer": "Thermal stresses may be introduced into a structure by rapid heating or cooling because temperature gradients are established across the cross section due to more rapid temperature changes at the surface than within the interior; thus, the surface will expand or contract at a different rate than the interior and since this surface expansion or contraction will be restrained by the interior, stresses will be introduced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释热应力产生的原因，答案是通过文字论述来解释现象，符合简答题的特征 | 知识层次: 题目要求解释热应力产生的机理，涉及温度梯度、膨胀/收缩速率差异以及内部约束等概念的关联和综合分析，需要一定的理解深度和思维过程，但不需要复杂的创新或设计优化。 | 难度: 在选择题中属于中等难度，需要理解温度梯度、热膨胀/收缩以及应力产生机制等多个概念，并能将这些概念关联起来进行综合分析。虽然题目不涉及多步计算，但要求考生能够解释现象背后的物理原理，这在选择题型中属于需要一定深度理解的题目。" + }, + { + "idx": 950, + "question": "List another method to increase the number of nuclei during solidification, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Add inoculants. They provide a large number of heterogeneous nucleation sites, increase the nucleation rate, and reduce the nucleation barrier.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出另一种增加凝固过程中晶核数量的方法，并简要分析晶核数量增加的原因。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求列举另一种增加凝固过程中晶核数量的方法，并简要分析原因。这需要理解凝固过程中的成核机制，并能够将异质成核的概念与实际应用（如添加孕育剂）联系起来。虽然涉及基础概念，但需要一定的综合分析能力来理解和解释成核率增加的原因。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道增加晶核数量的方法（添加孕育剂），还需要理解其背后的原理（提供异质形核位点、提高形核率、降低形核能垒）。这涉及对凝固过程中形核机制的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1939, + "question": "Homogeneous nucleation and heterogeneous nucleation have the same critical nucleus radius, and the critical nucleation work for heterogeneous nucleation is also equal to one-third of the surface energy. Why is heterogeneous nucleation easier than homogeneous nucleation?", + "answer": "Because in heterogeneous nucleation, impurities or mold cavities act as part of the nucleus. That is to say, fewer atoms need to be mobilized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要文字解释和论述，说明为什么异质成核比均质成核更容易，答案提供了详细的解释而非简单的选择或判断。 | 知识层次: 题目涉及对均相成核和非均相成核的理解，需要比较两者的临界核半径和成核功，并解释非均相成核更容易的原因。这需要将多个概念关联起来进行分析，并理解杂质或模具空腔在成核过程中的作用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及均匀成核和非均匀成核的临界核半径和临界成核功的概念，并需要理解为什么非均匀成核更容易。虽然题目给出了正确选项，但需要考生掌握相关概念并能够进行综合分析。" + }, + { + "idx": 1960, + "question": "What is the difference in diffusion coefficients between substitutional diffusion and interstitial diffusion?", + "answer": "The interstitial diffusion coefficient is independent of vacancy concentration, whereas the substitutional diffusion coefficient is related to vacancy concentration (can be expressed by a formula). Generally, the interstitial diffusion coefficient is greater than the substitutional diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种扩散系数之间的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种扩散机制的扩散系数差异，涉及对扩散机制的理解和关联分析，需要将扩散系数与空位浓度等概念联系起来，并进行综合分析。虽然不涉及复杂计算，但需要对相关概念有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生区分两种扩散机制（置换扩散和间隙扩散）的扩散系数差异，并理解它们与空位浓度的关系。虽然不需要进行多步计算，但需要对概念有较深的理解和关联能力。" + }, + { + "idx": 673, + "question": "How does the difference in properties between the diffusing element and the solvent metal affect the diffusion coefficient?", + "answer": "The greater the difference in properties between the diffusing element and the solvent metal, the larger the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释扩散元素与溶剂金属之间性质差异对扩散系数的影响，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目要求解释扩散元素与溶剂金属性质差异对扩散系数的影响，涉及多步概念关联和综合分析，需要理解扩散机制并应用相关原理进行解释。 | 难度: 在选择题中属于中等难度，需要理解扩散元素与溶剂金属性质差异对扩散系数的影响这一概念，并进行综合分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项直接给出了结论，减少了推导的复杂性。因此，难度等级为3，属于中等应用层次。" + }, + { + "idx": 531, + "question": "5. When Ca0 is doped into ZrO2, where Ca2+ ions replace Zr4+ ions, due to the requirement of electrical neutrality, this substitution simultaneously creates a (9) defect, which can be represented by the (10) defect reaction equation.", + "answer": "(9) vacancy; (10) CaO→ZrO2CaZr′′+V0..+ O0", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求填写空缺部分并写出缺陷反应方程，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求理解掺杂过程中的电荷平衡原理，并写出缺陷反应方程，涉及多步概念关联和综合分析，需要将基础概念应用到具体情境中。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及掺杂缺陷的形成和电荷平衡，需要考生掌握离子取代对晶体结构的影响以及缺陷反应方程的书写。虽然题目提供了正确选项，但考生仍需具备一定的材料科学基础，能够将Ca2+取代Zr4+的电荷补偿机制与氧空位的形成联系起来，并正确理解缺陷反应方程的含义。这需要中等层次的应用能力，包括多步计算、概念关联和综合分析。" + }, + { + "idx": 4470, + "question": "Why is it so important to control the rate of drying of a ceramic body that has been hydroplastically formed or slip cast?", + "answer": "It is important to control the rate of drying inasmuch as if the rate of drying is too rapid, there will be nonuniform shrinkage between surface and interior regions, such that warping and/or cracking of the ceramic ware may result.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么控制陶瓷体的干燥速率很重要，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解陶瓷干燥过程中的非均匀收缩现象及其后果，涉及多个概念的关联（干燥速率、收缩、变形/开裂）和综合分析（表面与内部区域的差异），但不需要复杂的机理推导或创新设计。 | 难度: 在选择题中属于中等难度，需要理解陶瓷干燥过程中的收缩不均匀性及其导致的变形和开裂问题，并进行概念关联和综合分析。虽然不涉及多步计算，但需要对材料行为有较深入的理解。" + }, + { + "idx": 1098, + "question": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vectors of the dislocation lines, respectively, so a curved dislocation line has different properties.", + "answer": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vectors of the dislocation lines, respectively. For a curved dislocation line, its Burgers vector remains constant, but the properties vary along the line as the geometric relationship between the direction vector of the dislocation line and the Burgers vector changes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对位错的性质进行文字解释和论述，答案提供了详细的描述和分析，符合简答题的特征。 | 知识层次: 题目涉及位错的基本概念（刃位错和螺位错的柏氏矢量方向）以及它们在曲线位错线上的变化，需要理解并应用这些概念来分析位错性质的变化。虽然知识点本身属于基础概念，但题目要求对不同位错类型在曲线位错线上的性质变化进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解位错的基本概念（刃位错和螺位错的柏氏矢量方向与位错线方向的关系），并能综合分析弯曲位错线上不同位置的性质变化。题目涉及多个概念的关联和比较，但不需要进行复杂的多角度分析或深度关联性分析。" + }, + { + "idx": 42, + "question": "According to the电价规则, when half of the octahedral interstitial sites are filled, what valence cations should be inserted into the interstices, and provide examples to illustrate.", + "answer": "The valence ratio of anions to cations should be 1:2, such as TiO2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释电价规则并举例说明，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解电价规则并应用到具体情境中，涉及多步推理和概念关联，如计算价态比例并举例说明，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解电价规则、间隙位置填充比例以及阴阳离子价态比等多个概念，并进行综合分析。题目要求考生不仅掌握基本概念，还要能够应用这些概念进行多步计算和关联分析，如通过TiO2的例子来说明1:2的价态比。这比单纯记忆知识点或简单应用要复杂，但相比需要多角度分析或深度关联性分析的题目，其难度适中。" + }, + { + "idx": 4750, + "question": "Why is aluminum alloy not a candidate for the cylindrical rod subjected to a tensile load of 29,000 N (6500 lb) with a maximum allowed elongation of 1.3mm (0.05 in.)?", + "answer": "Aluminum alloy is not a candidate because its elongation of 1.64mm exceeds the limit.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目需要解释为什么铝合金不适合作为圆柱杆的材料，答案提供了文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要结合材料的力学性能（如伸长率）和实际应用条件（如载荷和允许变形量）进行综合分析，涉及多步计算和概念关联，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解材料力学性能（如弹性模量、伸长率）并进行多步计算，同时将计算结果与给定限制条件进行综合分析判断。虽然题目提供了具体数值，但考生仍需掌握相关公式和概念才能正确评估铝合金是否满足要求。" + }, + { + "idx": 1944, + "question": "For metals without phase transformation in the solid state, if not remelted, how to refine grains through cold deformation and recrystallization?", + "answer": "By performing significant cold deformation followed by recrystallization at an appropriate temperature to obtain fine grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案提供了详细的步骤和方法，而不是简单的选择或判断。 | 知识层次: 题目需要理解冷变形和再结晶的基本原理，并能够将这两个概念关联起来，综合分析如何通过这两个步骤细化晶粒。这涉及到多步的知识应用和概念关联，而不仅仅是简单的记忆或直接套用。 | 难度: 在选择题中属于中等难度，需要理解金属冷变形和再结晶的基本概念，并能将这两个过程关联起来综合分析其对晶粒细化的影响。题目要求考生不仅知道冷变形和再结晶的单独作用，还要理解它们结合使用的效果，属于中等应用层次的知识要求。" + }, + { + "idx": 2102, + "question": "Point out the errors in the following concept and correct them: Repeatedly 'melting and solidifying' a solid solution alloy rod and using directional rapid solidification can effectively purify the metal.", + "answer": "Repeatedly perform zone melting and use directional slow solidification.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也是以文字形式给出修正后的正确概念。 | 知识层次: 题目要求识别并纠正错误概念，涉及对金属纯化方法的理解和应用，需要综合分析熔化、凝固过程对金属纯度的影响，并正确选择工艺参数（如快速或慢速凝固）。这超出了简单记忆的范畴，需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求识别并纠正错误概念，涉及对\"melting and solidifying\"与\"zone melting\"、\"rapid solidification\"与\"slow solidification\"等专业术语的区分和理解。虽然不需要复杂的计算，但需要对材料科学中的提纯原理有较深入的理解，并能将不同概念关联起来进行综合分析。" + }, + { + "idx": 3307, + "question": "What is the microstructural transformation of quenched steel during tempering at 250-400°C?", + "answer": "Transformation of carbides", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释淬火钢在250-400°C回火时的微观结构转变，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对淬火钢在回火过程中微观结构转变的理解，需要将温度范围与具体的碳化物转变相关联，属于中等应用层次的知识。虽然不涉及复杂计算，但需要对材料科学中的相变和碳化物形成有较深入的理解，并能够综合分析不同温度下的微观结构变化。 | 难度: 在选择题中属于中等难度，需要理解淬火钢在回火过程中的微观结构转变，并关联碳化物的转变这一具体知识点。题目涉及中等应用层次的知识，要求考生能够综合分析回火温度范围与微观结构变化的关系，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3283, + "question": "What is the significance of the TTT diagram for eutectoid carbon steel in practical heat treatment?", + "answer": "The isothermal transformation C-curve (TTT curve) can determine the process parameters during isothermal heat treatment of steel, namely the isothermal temperature, isothermal time, and the microstructure after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释TTT图的实际意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释TTT图在实际热处理中的意义，涉及对等温热处理过程参数（温度、时间）和最终组织的综合分析，需要将理论知识与实际应用相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解TTT图的基本概念及其在热处理中的应用，并能将多个概念（如等温温度、时间和显微组织）关联起来进行综合分析。虽然不涉及复杂的计算，但需要对材料科学中的基本原理有较好的掌握。" + }, + { + "idx": 4205, + "question": "What type(s) of bonding would be expected for aluminum phosphide (AlP)?", + "answer": "For AlP the bonding is predominantly covalent (but with some ionic character) on the basis of the relative positions of Al and P in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释铝磷化合物(AlP)的键合类型，答案需要文字论述和解释，而不是选择、判断或计算。 | 知识层次: 题目要求根据元素周期表中铝和磷的相对位置判断AlP的键合类型，这需要理解元素电负性差异对键合性质的影响，并综合分析共价键和离子键的特征。虽然不涉及复杂计算，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生基于元素在周期表中的相对位置判断化学键类型，涉及对共价键和离子键概念的综合理解，以及元素电负性差异的分析。虽然不需要复杂的计算，但需要将多个知识点关联起来进行判断，属于中等应用层次的知识要求。" + }, + { + "idx": 604, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the change of alloy properties is: electrical conductivity", + "answer": "decreases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释无序固溶体转变为有序固溶体时合金性能的一般变化趋势，答案需要文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目要求解释无序固溶体转变为有序固溶体时导电性变化的趋势，这需要理解固溶体结构变化与导电性之间的关系，涉及多个概念的关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解有序固溶体和无序固溶体的概念，并关联其对导电性能的影响。虽然题目给出了正确选项，但需要考生掌握材料科学中固溶体有序化对电子散射机制的影响这一知识点，并进行综合分析判断。" + }, + { + "idx": 3473, + "question": "Why do alloy tool steels have higher wear resistance and hot hardness than carbon steels?", + "answer": "Alloy tool steels contain certain alloying elements that form alloy carbides with the carbon in the steel. These alloy carbides have high hardness and high melting points, which is why alloy tool steels exhibit higher wear resistance and hot hardness than carbon steels.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金工具钢比碳钢具有更高耐磨性和热硬度的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解合金工具钢和碳钢在耐磨性和热硬度上的差异，并解释合金元素如何通过形成合金碳化物来提高性能。这涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解合金工具钢和碳钢的基本概念，并能够分析合金元素如何形成合金碳化物及其对性能的影响。虽然不需要复杂的计算，但需要对材料科学中的基本概念有较好的掌握，并能进行简单的综合分析。" + }, + { + "idx": 3844, + "question": "Recommend an artificial age-hardening heat treatment for a Cu-1.2% Be alloy (see Figure 12-34). Include appropriate temperatures.", + "answer": "For the Cu-1.2% Be alloy, solution treat between 530°C and 870°C (typical at 780°C), quench, and age below 530°C (typical at 330°C).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求推荐一种人工时效热处理工艺，并包括适当的温度，需要文字解释和论述，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目要求根据相图推荐具体的热处理工艺参数，需要理解Cu-Be合金的时效硬化原理，并能够将相图信息转化为具体的热处理温度范围。这涉及多步思考过程（固溶处理+淬火+时效处理）和温度选择的综合分析，但不需要深入分析微观机理或进行创新设计。 | 难度: 在选择题中属于中等难度，需要理解Cu-Be合金的时效硬化处理原理，掌握固溶处理和时效处理的关键温度范围，并能将理论知识与实际应用相结合。虽然题目给出了具体温度参数，但仍需要考生具备综合分析能力，理解不同温度阶段的作用和选择依据。" + }, + { + "idx": 1712, + "question": "How to control and improve the microstructure in metallic materials through processing methods?", + "answer": "The microstructure of metallic materials can be altered through various processing methods, such as cooling rate and method during casting, temperature gradient, and the magnitude and method of pressure processing after casting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来回答如何通过加工方法控制和改善金属材料的微观结构，答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求通过加工方法控制和改善金属材料的微观结构，涉及多种加工方法的综合应用和概念关联，需要理解不同加工参数（如冷却速率、温度梯度、压力加工等）对微观结构的影响，并进行综合分析。这超出了简单记忆或直接套用的层次，但尚未达到需要复杂推理或创新设计的程度。 | 难度: 在选择题中属于中等难度，需要理解金属材料微观结构控制的基本概念，并能够关联不同加工方法（如冷却速率、温度梯度、压力加工等）对微观结构的影响。虽然题目涉及多个概念的综合分析，但在选择题型中，正确选项已经提供了明确的关联性说明，不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3442, + "question": "If Cr12MoV steel is selected to manufacture cold work molds, what heat treatment process should be formulated? Why?", + "answer": "For Cr12MoV steel used in cold work molds, the heat treatment process is the primary hardening method: quenching at 980～1030‰ and tempering at 200-270°C. Reason: The primary hardening method of Cr12MoV steel can provide the steel with high hardness and wear resistance, minimal heat treatment deformation, and most molds made of Cr12MoV steel without special requirements adopt this method.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Cr12MoV钢制造冷作模具时应采用的热处理工艺及其原因，答案提供了详细的工艺参数和理论依据，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求制定Cr12MoV钢的热处理工艺并解释原因，涉及多步热处理过程（淬火和回火）的选择和参数设定，以及这些工艺对材料性能（硬度、耐磨性、变形）的影响。这需要综合理解材料的热处理原理和具体应用场景，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道Cr12MoV钢的热处理工艺，还需要理解为什么选择这种工艺（高硬度、耐磨性、热处理变形小等）。这涉及到对材料性能和应用的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3780, + "question": "Based on Hume-Rothery's conditions, would the system Mo-Ta be expected to display unlimited solid solubility? Explain.", + "answer": "Yes", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求基于Hume-Rothery条件解释Mo-Ta系统是否显示无限固溶性，需要文字解释和论述，而不仅仅是简单的选择或判断。答案\"Yes\"只是结论部分，完整的解答还需要解释为什么符合Hume-Rothery条件。 | 知识层次: 题目要求基于Hume-Rothery规则分析Mo-Ta系统的固溶度，需要理解并应用多个条件（如原子尺寸、电负性、价电子浓度等）进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hume-Rothery规则中的多个条件（如原子尺寸差、晶体结构、电负性和价电子浓度），并将这些概念应用于Mo-Ta体系的分析。虽然不需要复杂的计算，但需要对概念有较深的理解和综合应用能力。" + }, + { + "idx": 2313, + "question": "If unidirectional continuous fibers are unevenly distributed but all well-aligned in parallel, will it affect the elastic modulus? Please explain.", + "answer": "No effect. The modulus of the composite material $\\\\boldsymbol{E}_{\\\\mathrm{{L}}}=\\\\varphi_{\\\\mathrm{{f}}}\\\\boldsymbol{E}_{\\\\mathrm{{f}}}+\\\\varphi_{\\\\mathrm{{m}}}\\\\boldsymbol{E}_{\\\\mathrm{{m}}}$ varies linearly with the fiber volume percentage. Areas with dense fiber arrangement have a higher elastic modulus, while areas with sparse fiber arrangement have a lower elastic modulus. However, the linear relationship is additive, and the overall average modulus still equals the elastic modulus of a composite material with uniformly arranged fibers of the same volume fraction, meaning there is no effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释不均匀分布但平行排列的单向连续纤维是否会影响弹性模量，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目涉及复合材料弹性模量的计算和分布不均匀性的影响分析，需要理解弹性模量与纤维体积分数的线性关系，并能综合分析不同分布情况下的平均模量。虽然公式直接给出，但需要解释不均匀分布对整体模量的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解复合材料弹性模量的计算公式，并能够分析纤维分布不均匀但对整体模量的影响。题目涉及多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4512, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile strength than the other; (2) if this is possible, note which has the higher tensile strength and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why. Network polyester; lightly branched polypropylene", + "answer": "Yes it is possible. The network polyester will display a greater tensile strength. Relative chain motion is much more restricted than for the lightly branched polypropylene since there are many more of the strong covalent bonds for the network structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的拉伸强度进行比较，并解释原因，需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求对不同聚合物的拉伸强度进行比较，并解释原因。这需要理解聚合物结构（网络结构与轻度支化结构）对力学性能的影响，属于概念关联和综合分析。虽然不涉及复杂计算，但需要对材料性能与结构关系有较深入的理解。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅能够识别两种聚合物的结构差异（网络聚酯与轻度支化聚丙烯），还需要理解这些结构如何影响材料的拉伸强度。此外，考生需要能够将结构特征与力学性能联系起来，并做出明确的判断。虽然题目提供了明确的比较点，但仍需要一定的综合分析能力来正确回答。" + }, + { + "idx": 863, + "question": "Explain one of the three main mechanisms of alloy strengthening from a microstructural perspective: grain boundary strengthening, and provide an example", + "answer": "According to the Hall-Petch formula, the relationship between the yield point σs and the grain diameter d is σs=σ0+k d^(-1/2). The essence is that additional stress is required for dislocations to cross grain boundaries. Therefore, steels for low-temperature applications often adopt a fine-grained structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释合金强化的机制之一（晶界强化），并提供例子，需要文字解释和论述。答案中包含了理论解释（Hall-Petch公式）和实际应用例子（低温用钢的细晶结构），符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释合金强化的机制之一（晶界强化），并给出实例。这需要理解Hall-Petch公式及其物理意义，同时能够将理论知识与实际应用（如低温用钢的细晶结构）联系起来。虽然涉及基础概念，但需要一定的概念关联和综合分析能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解Hall-Petch公式的基本概念及其物理意义，并能将其与具体的应用实例（低温用钢的细晶结构）联系起来。题目要求考生不仅掌握公式本身，还要能够解释其微观机制，并给出实际应用的例子，这涉及多步的概念关联和综合分析。" + }, + { + "idx": 3317, + "question": "Describe the microstructure type, obtaining conditions, characteristics, and mechanical properties of steel after high-temperature tempering", + "answer": "High-temperature tempering Tempered sorbite 500-650℃ Good combination of strength and toughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述高温回火后钢的微观结构类型、获得条件、特征和机械性能，需要文字解释和论述，答案也以简短的文字形式呈现。 | 知识层次: 题目要求描述高温回火后钢的微观结构类型、获得条件、特征和力学性能，涉及多个知识点的关联和综合分析，需要理解回火温度对钢性能的影响机制，并能够将微观结构与宏观性能联系起来。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生综合掌握高温回火后的钢的微观结构类型、获得条件、特性以及力学性能，并能够将这些知识点关联起来。虽然题目给出了正确选项，但考生仍需具备一定的综合分析能力才能准确选择。" + }, + { + "idx": 1840, + "question": "What is the relationship between △L/L and sintering time in the mass transfer process?", + "answer": "(29) △L/L∝t", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释△L/L与烧结时间之间的关系，答案需要文字描述和论述，而非简单的选择、判断或计算。 | 知识层次: 题目涉及烧结过程中质量传递的基本关系，需要理解△L/L与时间t的关系，并应用相应的公式或原理进行解释。这属于中等应用层次，因为它需要将概念与公式关联起来，并进行一定的综合分析。 | 难度: 在选择题中属于中等难度，需要理解烧结过程中的质量传递概念，并能将△L/L与时间t的关系进行综合分析。题目要求考生掌握中等应用层次的知识，包括多步计算和概念关联，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 4602, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Fused silica; quartz.", + "answer": "Quartz will have a larger conductivity than fused silica because fused silica is noncrystalline (whereas quartz is crystalline) and lattice vibrations are more effectively scattered in noncrystalline materials.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目要求比较两种材料的导热性能并解释原因，涉及晶体结构对热导率影响的概念关联和综合分析，需要理解晶态与非晶态材料中声子散射的差异，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶体和非晶体材料对热导率的影响，并进行比较分析。虽然题目给出了明确的比较对象和正确选项，但仍需要掌握材料结构对热导率影响的基本原理，并能将这一原理应用到具体材料比较中。" + }, + { + "idx": 4563, + "question": "Briefly explain why, for a small anode-to-cathode area ratio, the corrosion rate will be higher than for a large ratio.", + "answer": "For a small anode-to-cathode area ratio, the corrosion rate will be higher than for A large ratio. The reason for this is that for some given current flow associated with the corrosion reaction, for a small area ratio the current density at the anode will be greater than for a large ratio. The corrosion rate is proportional to the current density (i) according to Equation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释为什么小阳极-阴极面积比会导致更高的腐蚀速率，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解阳极-阴极面积比对腐蚀速率的影响机制，并运用电流密度的概念进行解释，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解阳极-阴极面积比的概念，并能将其与电流密度和腐蚀速率的关系联系起来进行分析。题目要求考生能够综合应用电化学腐蚀的基本原理，但不需要进行复杂的多角度或深度关联性分析。" + }, + { + "idx": 4329, + "question": "Consider 1.0 kg of austenite containing 1.15 wt % C, cooled to below 727 C (1341 F). What is the proeutectoid phase?", + "answer": "the proeutectoid phase is fe3c.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来确定先共析相（proeutectoid phase），答案是一个具体的相名称（Fe3C），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目需要理解铁碳相图的基本原理，并能够根据给定的碳含量和冷却条件判断出先共析相。这涉及到对相图的分析和应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。该题目涉及的知识点包括相图分析、碳含量计算和相变过程判断，需要学生综合运用这些知识来解答。虽然题目给出了具体的碳含量和温度条件，但仍需进行多步计算和概念关联才能确定正确的先共析相。" + }, + { + "idx": 247, + "question": "Provide a full explanation of the various property value estimates you made in the calculation. The Schottky defect formation energy of CaO is known to be 6eV.", + "answer": "The property values used in the calculation include: Schottky defect formation energy ΔHf = 6 eV, converted to joules as 6 × 1.6 × 10^-19 J; Avogadro's constant NA = 6.23 × 10^23 mol^-1; gas constant R = 8.314 J/(mol·K); melting point temperature T = 2600℃ = 2873 K. These values are used to calculate the Schottky defect concentration [V′′Ca] = exp(-ΔHf / 2RT).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提供详细的解释和论述，说明计算中使用的各种属性值估计，答案也以文字解释的形式呈现，没有涉及数值计算或公式应用的具体过程。 | 知识层次: 题目要求解释计算中使用的各种属性值，并涉及单位转换和基本公式的应用。虽然计算本身并不复杂，但需要理解Schottky缺陷形成能的概念，并将其与Avogadro常数、气体常数和温度等关联起来进行多步计算。这超出了简单记忆或直接套用公式的层次，属于中等应用水平。 | 难度: 在选择题中属于中等难度，题目要求考生理解并应用多个概念（如Schottky缺陷形成能、单位转换、阿伏伽德罗常数、气体常数等），并进行多步计算和综合分析。虽然涉及的知识点较多，但题目提供了明确的公式和数值，降低了部分难度。" + }, + { + "idx": 3519, + "question": "Please indicate the type of cast iron and heat treatment method that should be used for plowshares, and why?", + "answer": "Plowshare: white cast iron.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述适合犁铧的铸铁类型和热处理方法及其原因，需要文字解释而非选择、判断或计算 | 知识层次: 题目要求选择铸铁类型和热处理方法，并解释原因。这需要理解不同铸铁的特性及其应用场景，以及热处理方法对性能的影响。虽然涉及基础概念，但需要将多个知识点关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道不同类型的铸铁及其特性，还需要理解不同应用场景下材料的选择依据。此外，题目还涉及热处理方法的考虑，这需要考生将材料特性与实际应用需求进行关联分析。虽然题目给出了正确选项，但考生仍需具备一定的综合分析能力才能做出正确选择。" + }, + { + "idx": 3304, + "question": "Compare the distribution of alloying elements in bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, alloying elements are redistributed through diffusion, while in bainitic transformation and martensitic transformation, alloying elements do not diffuse.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对不同相变过程中合金元素的分布进行比较和解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目要求比较三种相变过程中合金元素的分布情况，涉及多个概念（扩散、相变类型）的关联和综合分析，需要理解不同相变过程的机制及其对合金元素分布的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较三种不同相变过程中合金元素的分布情况，涉及扩散和非扩散机制的理解。虽然不需要多步计算，但需要对珠光体相变、贝氏体相变和马氏体相变的基本原理有清晰认识，并能综合分析不同相变过程中合金元素的行为差异。这属于中等应用层次的知识要求，符合等级3的综合分析和说明标准。" + }, + { + "idx": 2800, + "question": "Indicate approximately in which temperature range grain boundary diffusion dominates.", + "answer": "In the low-temperature region (when 1/T is large), the lnD value of grain boundary diffusion is higher than that of bulk diffusion, and grain boundary diffusion dominates at this time. As the temperature increases (1/T decreases), the two curves will intersect, and in the high-temperature region above the intersection point, bulk diffusion will dominate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在哪个温度范围内晶界扩散占主导地位，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求解释晶界扩散在特定温度范围内占主导的原因，涉及对扩散机制的理解和温度对扩散行为的影响分析。需要将晶界扩散和体扩散的概念关联起来，并通过温度变化对扩散系数的影响进行综合分析。虽然不涉及复杂计算，但需要一定的概念关联和推理分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握晶界扩散和体扩散的基本概念，并能分析温度变化对两种扩散机制的影响。虽然不需要复杂的计算，但需要对扩散机制在不同温度区间的相对优势进行综合判断，涉及概念关联和综合分析能力。" + }, + { + "idx": 3574, + "question": "How would you manufacture a hammer head?", + "answer": "The head for a carpenter's hammer is produced by forging, a metalworking process; a simple steel shape is heated and formed in several steps while hot into the required shape. The head is then heat treated to produce the required mechanical and physical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何制造锤头，答案提供了详细的文字解释和论述，涉及制造过程和热处理步骤，符合简答题的特征。 | 知识层次: 题目要求解释制造锤头的具体工艺过程（锻造和热处理），涉及多个步骤和工艺原理的综合应用，需要理解金属加工和热处理的基本概念，并将其关联到实际制造过程中。虽然不涉及复杂计算，但需要对工艺步骤和目的有清晰的理解和解释。 | 难度: 在选择题中属于中等难度，题目要求理解锻造工艺的基本概念和步骤，并能够将加热、成型和热处理等多个步骤关联起来。虽然不需要进行多角度分析或深度关联性分析，但需要对金属加工工艺有一定的综合理解。" + }, + { + "idx": 3492, + "question": "How to improve the corrosion resistance of steel?", + "answer": "Methods to improve the corrosion resistance of steel: (a) Increase the electrode potential of the metal. (b) Make the metal easier to passivate. (c) Obtain a single-phase structure with uniform chemical composition, microstructure, and metal purity, aiming to avoid the formation of microcells.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释如何提高钢的耐腐蚀性，答案提供了详细的文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求对提高钢材耐腐蚀性的方法进行解释和论述，涉及多个概念（电极电位、钝化、单相结构等）的关联和综合分析，需要一定的理解和应用能力，但不需要复杂的创新或深度设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握提高钢材耐腐蚀性的多种方法，并能够区分不同方法的原理和效果。正确选项涉及电极电位、钝化现象以及微观结构等概念，需要考生具备一定的综合分析能力。虽然题目提供了具体选项，但需要对材料科学中的腐蚀防护有较深入的理解才能准确选择最佳答案。" + }, + { + "idx": 2207, + "question": "There are three types of ingots: pure Ti, Al, and Pb. It is known that the melting point of Ti is 1672°C, with a hexagonal close-packed structure below 883°C and a face-centered cubic structure above 883°C; the melting point of Al is 660°C, with a face-centered cubic structure; the melting point of Pb is 328°C, with a face-centered cubic structure. Determine the order of their rolling difficulty at room temperature (20°C).", + "answer": "At room temperature, Pb is the easiest to roll, followed by Al, and Ti is the most difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据材料的结构和性质进行解释和论述，最终得出一个排序结论，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要综合运用金属的晶体结构、相变温度和室温下的力学性能等知识，通过分析不同金属在室温下的晶体结构（如Ti的HCP结构在室温下更难变形，而Al和Pb的FCC结构相对容易变形）来推断其轧制难度。这涉及多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握不同金属的晶体结构、熔点以及这些性质对室温下轧制难度的影响。解题步骤包括识别各金属的晶体结构、分析其室温下的塑性变形能力，并进行综合比较。虽然不涉及复杂计算，但需要将多个材料科学概念关联起来，属于中等应用层次的知识要求。" + }, + { + "idx": 559, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of the third component.", + "answer": "The third component. Depending on the nature of the added third component, some promote diffusion while others hinder it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响原子扩散的因素，并简要说明第三组分的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求列举影响原子扩散的因素（基础概念），还需要解释第三组元的具体影响（概念关联和综合分析），涉及多因素相互作用的理解和解释。 | 难度: 在选择题中属于中等难度，需要理解原子扩散的基本概念以及第三组分对扩散的影响，并进行综合分析。题目要求考生不仅知道第三组分的存在会影响扩散，还需要理解其可能促进或阻碍扩散的双重作用，这涉及对材料科学中扩散机制的较深入理解。" + }, + { + "idx": 1125, + "question": "Why can the lever rule be used to analyze the relative content of each phase in the horizontal section of a ternary equilibrium phase diagram", + "answer": "On the horizontal section (i.e., the four-phase equilibrium plane) of a ternary equilibrium phase diagram, the composition of each phase and the temperature are all determined, so the lever rule can be used to analyze the relative content of each phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么杠杆定律可以用于分析三元平衡相图中水平截面上各相的相对含量，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要理解三元平衡相图中水平截面的特性，并应用杠杆规则来分析各相的相对含量。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解杠杆规则在三元平衡相图中的具体应用，并能够将多个概念（如四相平衡平面、相组成确定等）进行关联分析。虽然题目提供了正确选项，但考生仍需具备一定的综合分析能力才能准确理解并选择正确答案。" + }, + { + "idx": 4643, + "question": "Explain why hydrogen fluoride (HF) has a higher boiling temperature than hydrogen \\\\ chloride (\\mathrm{HCl})\\left(19.4 \\mathrm{vs} .-85^{\\circ} C\\right), even though \\mathrm{HF} has a lower molecular weight.", + "answer": "The intermolecular bonding for \\mathrm{HF} is hydrogen, whereas for \\mathrm{HCl}, the intermolecular bonding is van der Waals. Since the hydrogen bond is stronger than van der Waals, HF will have a higher melting temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释氢氟酸（HF）比氯化氢（HCl）沸点高的原因，答案需要文字解释和论述，涉及分子间作用力的比较，属于简答题类型。 | 知识层次: 题目要求解释氢氟酸（HF）和氯化氢（HCl）沸点差异的原因，涉及分子间作用力的比较（氢键与范德华力）以及其对物理性质的影响。这需要理解分子间作用力的类型及其强度差异，并将这些概念应用于解释具体现象，属于中等应用层次。虽然不涉及多步计算，但需要对概念进行关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解氢键和范德华力的概念，并能比较它们的相对强度以及对沸点的影响。虽然题目涉及分子间作用力的知识，但选项直接给出了关键概念和结论，减少了分析步骤的复杂性。" + }, + { + "idx": 948, + "question": "List one method to increase the number of nuclei during the solidification process, and briefly analyze the reason for the increase in the number of nuclei.", + "answer": "Increase the cooling rate to enhance the degree of undercooling. The phase transformation driving force is increased, thereby improving the nucleation rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出一种方法并简要分析原因，需要文字解释和论述，符合简答题的特征 | 知识层次: 题目要求列举一种增加凝固过程中晶核数量的方法，并简要分析其原因。这需要理解凝固过程中的成核机制，并将冷却速率与过冷度、相变驱动力和成核速率之间的关系联系起来。虽然不涉及复杂的计算或多步骤分析，但需要对概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道增加冷却速率可以提高形核率，还需要理解其背后的原理（过冷度增加导致相变驱动力增大）。这涉及对凝固过程中形核机制的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3572, + "question": "What are the important properties that the material in the temperature indicator must possess?", + "answer": "In order for the material to perform well, the two materials must have very different coefficients of thermal expansion and should have high enough modulus of elasticity so that no permanent deformation of the material occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释材料在温度指示器中必须具有的重要性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释温度指示器材料必须具备的重要性能，并需要理解热膨胀系数和弹性模量的作用。这涉及多个概念的关联和综合分析，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握材料的热膨胀系数和弹性模量的重要性，并能够综合分析这些性质如何影响温度指示器的性能。虽然不需要多步计算，但需要对材料性质有较深的理解和关联能力。" + }, + { + "idx": 4914, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Pure silver; sterling silver (92.5 wt% Ag-7.5 wt% Cu)", + "answer": "Pure silver will have a larger conductivity than sterling silver because the impurity atoms in the latter will lead to a greater degree of free electron scattering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的热导率并给出理由，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的导热性能，并解释原因。这需要理解热导率的基本概念（基础概念），同时需要分析杂质对自由电子散射的影响（概念关联和综合分析）。虽然不涉及复杂计算，但需要将多个知识点联系起来进行解释，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解热导率与材料纯度的关系，并分析杂质对自由电子散射的影响。虽然不需要复杂计算，但需要将多个概念（纯度、电子散射、热导率机制）进行关联分析才能正确判断。" + }, + { + "idx": 1963, + "question": "At room temperature, a sheet of iron (with a melting point of 1538°C) is bent back and forth. What phenomenon will occur as the bending continues? Why?", + "answer": "According to T_recrystallization = (0.35–0.45)T_melting, the processing of Fe at room temperature is cold working. Therefore, as bending proceeds, the sheet undergoes work hardening, and continued deformation leads to fracture of the iron sheet.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释现象并论述原因，答案提供了详细的文字解释和理论依据，符合简答题的特征。 | 知识层次: 题目需要理解冷加工和再结晶温度的概念，并应用公式T_recrystallization = (0.35–0.45)T_melting进行计算和判断。同时，需要解释铁片在室温下弯曲时发生的加工硬化和最终断裂的现象，涉及多个概念的关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及冷加工、再结晶温度计算、加工硬化等概念的综合应用，要求考生能够将理论知识与实际现象关联起来，并进行多步推理。虽然题目提供了计算公式，但仍需考生具备一定的材料科学基础才能正确理解和应用这些概念。" + }, + { + "idx": 569, + "question": "In a face-centered cubic crystal, a dislocation with Burgers vector b1= [101] meets a dislocation with b2= [121]. Can a dislocation reaction occur to form b3? Write the equation.", + "answer": "Geometric condition: b3=b1+b2= a/2[101]+a/6[121]=a/6[222]=a/3[111]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释是否会发生位错反应并写出反应方程，需要文字解释和论述，答案也以文字和方程形式呈现。 | 知识层次: 题目涉及位错反应的计算和几何条件的应用，需要理解位错Burgers向量的概念，并能进行向量运算和简化。虽然计算步骤不多，但需要将多个概念关联起来，并进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解位错反应的基本概念，掌握Burgers矢量的计算方法，并能进行多步矢量运算和综合分析。虽然题目涉及的知识点较为专业，但在选择题型中，通过给定的正确选项可以辅助验证计算过程，降低了部分难度。" + }, + { + "idx": 4551, + "question": "Which electrode will be oxidized in the Zn/Zn2+ concentration cell with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "The electrode in the cell half with the Zn2+ concentration of 10^-2 M will be oxidized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释哪个电极会被氧化，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解浓度电池的工作原理，并应用能斯特方程的概念来判断电极的氧化倾向。虽然不涉及复杂的计算，但需要将多个概念（如氧化还原、浓度梯度）关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解浓度对电极电势的影响，并应用能斯特方程进行综合分析。虽然题目给出了具体浓度值，但仍需考生掌握氧化还原反应的基本原理和浓度电池的工作机制，进行多步推理才能得出正确结论。" + }, + { + "idx": 141, + "question": "From the following two glaze formulas, determine the difference in their melting temperatures? Explain the reason. Glaze formula 1: 0.2K2O 0.2Na2O 0.4CaO 0.2PbO 0.3Al2O3 2.1SiO2; Glaze formula 2: 0.2K2O 0.2MgO 0.6CaO 1.1Al2O3 10.0SiO2", + "answer": "(2) The melting temperature of glaze formula 1 > the melting temperature of glaze formula 2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种釉配方的熔化温度差异并解释原因，需要文字解释和论述，而不是简单的选择、判断或计算 | 知识层次: 题目要求比较两种釉料配方的熔化温度差异并解释原因，这涉及到对釉料成分及其对熔化温度影响的理解和应用。需要分析不同氧化物（如K2O、Na2O、CaO、PbO、MgO、Al2O3、SiO2）在釉料中的作用及其对熔化温度的影响，属于多步计算和概念关联的综合分析。虽然不涉及复杂的推理或创新设计，但需要一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求比较两种釉料配方的熔融温度差异，并解释原因。这涉及到对釉料成分（如K2O、Na2O、CaO、PbO、Al2O3、SiO2等）及其对熔融温度影响的理解。虽然题目提供了具体的配方，但需要考生能够识别关键成分（如PbO的助熔作用、Al2O3和SiO2的提高熔融温度作用）并进行综合分析。此外，还需要进行多步计算和概念关联，但因为是选择题，正确选项已经给出，减少了部分难度。" + }, + { + "idx": 4556, + "question": "Under what conditions is concentration polarization rate controlling?", + "answer": "Concentration polarization is rate controlling when the reaction rate is high and/or the concentration of active species in the liquid solution is low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么条件下浓度极化是速率控制步骤，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解浓度极化的控制条件，并分析反应速率和活性物种浓度之间的关系，属于中等应用层次，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解浓度极化和反应速率之间的关系，并综合分析高反应速率和低活性物种浓度的影响。虽然不涉及多步计算，但需要对概念进行关联和综合分析。" + }, + { + "idx": 721, + "question": "What is the relationship between secondary recrystallization and the particle size of the raw material", + "answer": "Secondary recrystallization is also related to the particle size of the raw material", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释二次再结晶与原材料颗粒尺寸之间的关系，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及二次再结晶与原材料颗粒尺寸之间的关系，需要理解两者之间的关联并进行综合分析，属于中等应用层次的知识点。 | 难度: 在选择题中属于中等难度，需要理解二次再结晶与原料颗粒尺寸之间的关系，并进行概念关联和综合分析。虽然题目涉及的知识点较为专业，但在选择题型中，通过正确选项可以直接判断出答案，不需要进行多步计算或深度关联性分析。" + }, + { + "idx": 146, + "question": "What are the kinetic factors affecting the glass formation process?", + "answer": "The key factor affecting glass formation is the cooling rate of the melt. Whether the melt crystallizes or forms glass is related to the degree of supercooling, viscosity, nucleation rate, and crystal growth rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释影响玻璃形成过程的动力学因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释影响玻璃形成过程的动力学因素，涉及多个相关概念（冷却速率、过冷度、粘度、成核速率、晶体生长速率）的关联和综合分析，需要理解这些因素之间的相互作用及其对玻璃形成的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念（冷却速率、过冷度、粘度、成核速率和晶体生长速率）并进行综合分析。虽然题目涉及多个因素，但在选择题型中只需识别关键因素，不需要进行多步计算或深度关联性分析。" + }, + { + "idx": 4883, + "question": "Why must fiber materials that are drawn be thermoplastic?", + "answer": "Fiber materials that are drawn must be thermoplastic because during drawing, mechanical elongation must be possible; inasmuch as thermosetting materials are, in general, hard and relatively brittle, they are not easily elongated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么纤维材料在拉伸过程中必须是热塑性的，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要理解纤维材料在拉伸过程中的行为，并解释为什么必须是热塑性材料。这涉及到对热塑性和热固性材料性质的理解，以及它们在拉伸过程中的行为差异。虽然不涉及复杂的计算或深度推理，但需要对材料性质和应用场景有一定的综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解纤维材料的特性（热塑性和热固性）以及它们在拉伸过程中的行为差异。题目要求考生将材料性质与加工工艺（拉伸）关联起来，并进行综合分析。虽然不涉及复杂计算，但需要掌握多个相关概念并理解它们之间的相互作用。" + }, + { + "idx": 571, + "question": "When $\\\\mathrm{Yb}\\\\mathrm{F}_{3}$ and $\\\\mathbf{NaF}$ are doped into $\\\\mathbf{CaF}_{2}$ crystals, if both ytterbium ions and sodium ions replace the cation positions, please write the defect reaction equation.", + "answer": "$\\\\mathrm{YbF}_{3}+\\\\mathrm{NaF}\\\\xrightarrow{\\\\mathrm{CaF}_{2}}\\\\mathrm{Yb}_{\\\\mathrm{Ca}}^{*}+\\\\mathrm{Na}_{\\\\mathrm{Ca}}^{\\\\prime}+4\\\\mathrm{F}_{\\\\mathrm{Fc}}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出缺陷反应方程，需要文字解释和论述，答案形式为化学方程式，属于简答题类型 | 知识层次: 题目要求写出缺陷反应方程，需要理解掺杂过程中离子的取代位置和电荷平衡，涉及多步概念关联和综合分析，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握缺陷化学的基本概念，能够正确写出掺杂反应的缺陷反应方程。虽然题目给出了掺杂物质和基体，但需要考生理解Yb和Na在CaF2中的取代位置，并正确写出缺陷反应方程，包括缺陷符号和电荷平衡。这需要一定的综合分析能力和对缺陷化学知识的掌握。" + }, + { + "idx": 122, + "question": "Use experimental methods to identify crystalline SiO2", + "answer": "Use X-ray detection. Crystalline SiO2—particles are arranged regularly in three-dimensional space, exhibiting anisotropy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求使用实验方法识别晶体SiO2，答案提供了具体的实验方法（X射线检测）和解释（晶体SiO2的三维规则排列和各向异性），属于需要文字解释和论述的简答题。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别晶体SiO2，并解释其结构特征。这涉及基本的实验技术应用和晶体学基本概念的理解，属于简单应用层次。 | 难度: 在选择题中属于中等难度，需要理解X射线检测的基本原理以及晶体结构（如各向异性）的特性，并能将两者联系起来进行判断。虽然题目给出了直接的应用方法说明，但需要考生具备一定的知识背景才能正确选择答案。" + }, + { + "idx": 4177, + "question": "For the M shell (n=3), write the four quantum numbers for all of the electrons and note which correspond to the s, p, and d subshells.", + "answer": "For the M state, n=3, and 18 states are possible. Possible l values are 0, 1, and 2; possible ml values are 0, ±1, and ±2; and possible ms values are ±1/2. Therefore, for the s states, the quantum numbers are 300(1/2), 300(-1/2), for the p states they are 310(1/2), 310(-1/2), 311(1/2), 311(-1/2), 31(-1)(1/2), and 31(-1)(-1/2); for the d states they are 320(1/2), 320(-1/2), 321(1/2), 321(-1/2), 32(-1)(1/2), 32(-1)(-1/2), 322(1/2), 322(-1/2), 32(-2)(1/2), and 32(-2)(-1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出M壳层（n=3）的所有电子的四个量子数，并指出哪些对应于s、p和d子壳层。这需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式详细列出了所有可能的量子数组合，符合简答题的特征。 | 知识层次: 题目要求根据给定的量子数规则（n, l, ml, ms）列举出M壳层（n=3）中所有可能的电子状态，并分类到s、p、d子壳层。这需要应用基本的量子数规则和电子排布知识，属于直接套用规则进行简单列举的应用题。虽然涉及多个量子数的组合，但思维过程较为直接，不需要复杂的推理或综合分析。 | 难度: 在选择题中属于中等难度，需要理解量子数的基本概念（n, l, ml, ms）以及它们在s、p、d轨道中的具体应用。虽然题目给出了所有可能的量子数组合，但要求考生能够正确识别和分类这些组合对应的轨道类型（s, p, d）。这需要考生对量子数的取值范围和轨道类型的对应关系有清晰的理解，并能够进行简单的逻辑推理和分类。" + }, + { + "idx": 2895, + "question": "Briefly describe the advantages of polymer alloying", + "answer": "Through alloying, polymers can overcome certain performance weaknesses of single-component polymers (homopolymers). For example, polypropylene (PP) is prone to brittle fracture at low temperatures, but blending with butadiene rubber (BR) can significantly improve the toughness of polypropylene. It can also broaden the applications of polymers. For instance, blending polyethylene (PE) with different densities can produce foam plastics with various properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述聚合物合金化的优势，答案通过文字解释和举例进行了论述，符合简答题的特征。 | 知识层次: 题目要求简要描述聚合物合金化的优势，涉及对基本概念的理解和简单应用，如通过具体例子（PP与BR的混合）说明性能改进，属于直接套用基本原理进行解释的范畴。 | 难度: 在选择题中属于中等难度，题目要求考生理解聚合物合金化的基本概念，并能通过具体实例（如PP与BR的混合、PE不同密度的混合）来说明其优势。这需要考生不仅掌握基本概念，还能应用这些概念解释实际案例，但不需要进行复杂的分析或计算。" + }, + { + "idx": 575, + "question": "Give one application of solidification theory in the crystallization of metallic materials, and briefly explain it", + "answer": "Ingot structure control. By controlling the cooling rate and temperature gradient during solidification, the grain size and distribution of the ingot can be adjusted, thereby improving the mechanical properties of the metallic material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个应用实例并进行简要解释，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求给出一个凝固理论在金属材料结晶中的应用实例，并简要解释。这需要将凝固理论的基本原理应用到具体场景中，属于直接套用理论解释实际问题的简单应用层次。虽然涉及理论的应用，但不需要多步计算或综合分析，思维深度要求不高。 | 难度: 在选择题中属于中等难度，需要理解固体化理论的基本概念，并能将其应用于金属材料的结晶过程。题目要求选择一个具体的应用实例（铸锭结构控制），并简要解释其原理（通过控制冷却速率和温度梯度来调整晶粒尺寸和分布）。这需要考生不仅记住知识点，还能进行简单的应用分析，但不需要复杂的计算或深入的理论推导。" + }, + { + "idx": 1420, + "question": "What is the difference in the conduction mechanisms between intrinsic semiconductors and doped semiconductors?", + "answer": "In intrinsic semiconductors, the charge carriers participating in conduction are electrons in the conduction band and an equal number of holes in the valence band, with the Fermi level located at the center of the band gap. In doped semiconductors, the charge carriers participating in conduction are electrons in the conduction band and an unequal number of holes in the valence band, with the Fermi level not located at the center of the band gap—either shifting upward (as in $\\mathbf{n}$-type semiconductors) or downward (as in p-type semiconductors).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述本征半导体和掺杂半导体的导电机制差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查半导体导电机制的基本概念，包括本征半导体和掺杂半导体的区别，以及费米能级的位置变化。这些内容属于材料科学中的基础概念记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解并记忆本征半导体和掺杂半导体的基本定义，还需要掌握它们的导电机理差异，包括载流子类型、数量关系以及费米能级位置的变化。这涉及到多个概念的比较和综合分析，超出了简单的定义记忆或单一概念解释的范畴。" + }, + { + "idx": 3272, + "question": "What are the main characteristics of diffusion-type phase transformations?", + "answer": "The fundamental characteristics of diffusion-type phase transformations are: $\\textcircled{1}$ Atomic diffusion occurs during the phase transformation, and the transformation rate is controlled by diffusion, i.e., determined by the diffusion speed. $\\textcircled{2}$ In alloy phase transformations, the compositions of the new phase and the parent phase are often different. $\\textcircled{3}$ There is only volume change caused by the difference in specific volume between the new phase and the parent phase, with no shape alteration. Phase transformations such as allotropic transformation in pure metals, polymorphic transformation in solid solutions, precipitation transformation, eutectoid transformation, spinodal decomposition, and ordering transformation all belong to diffusion-type phase transformations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散型相变的主要特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目考查扩散型相变的基本特征，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题中属于较高难度，题目要求掌握扩散型相变的基本特征，并理解多个相关概念（如原子扩散、相变速率控制、新相与母相成分差异、体积变化等）。此外，还需要将这些概念整合成一个完整的体系进行阐述，涉及的知识点较多且需要深入理解。" + }, + { + "idx": 924, + "question": "1. Edge dislocation and screw dislocation models", + "answer": "Cut the upper half of the crystal, insert half a crystal plane, and then bond it together; in this way, within a certain range near the centerline corresponding to the edge end, the atoms undergo regular misalignment. Its characteristic is that the upper half is under compression, and the lower half is under tension. This is the same as the scenario caused by edge dislocations in real crystals, known as the edge dislocation model. Similarly, cut the front half of the crystal, use the edge end as the boundary to make the left and right parts undergo a relative shear of one atomic spacing up and down, and then bond them together. At this time, near the boundary line between the sheared and unsheared regions, the atomic misalignment is similar to that of a real screw dislocation, known as the screw dislocation model.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对刃型位错和螺型位错模型进行详细的文字解释和论述，答案形式为描述性文字而非选择、判断或计算。 | 知识层次: 题目主要考查对边缘位错和螺位错模型的基本概念和特征的理解与记忆，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于高难度。题目要求考生不仅要记忆边缘位错和螺旋位错的定义，还需要理解它们的形成过程和特征。具体来说，考生需要掌握切割晶体、插入半晶面、原子错位等复杂概念，并能区分压缩和拉伸的不同效果。此外，题目还涉及相对剪切和原子间距的变化，这些都是较为复杂的知识点。因此，该题目在选择题型内属于高难度等级。" + }, + { + "idx": 2181, + "question": "What is the difference between fibrous structure and texture?", + "answer": "Fibrous structure is formed by grains, impurities, second phases, defects, etc., being elongated into fibrous shapes along the main deformation direction of the metal; whereas texture refers to the certain orientation relationship among grains after cold working, where certain crystal planes or directions are parallel to each other and all parallel to an external reference direction of the component.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述两个概念之间的区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对纤维结构和织构这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题中属于较高难度，题目要求考生不仅要理解\"纤维结构\"和\"织构\"这两个专业术语的定义，还需要能够区分和比较这两个概念的具体特征和形成机制。正确选项包含了多个专业知识点（如晶粒变形、杂质分布、晶体取向关系等），需要考生对这些概念有较深入的理解才能准确作答。此外，题目涉及金属材料科学中较为复杂的微观结构概念体系，在选择题型内属于需要综合分析能力的高难度题目。" + }, + { + "idx": 1096, + "question": "Interstitial solid solutions and interstitial compounds both belong to interstitial phases.", + "answer": "The Burgers vectors of edge dislocations and screw dislocations are perpendicular and parallel to the direction vector of the dislocation line, respectively. For a curved dislocation line, its Burgers vector remains constant, but the properties vary along different sections depending on the geometric relationship between the direction vector of the dislocation line and the Burgers vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对间隙固溶体和间隙化合物的概念进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对间隙固溶体和间隙化合物的基本概念记忆，以及它们是否属于间隙相的分类理解。这属于基础概念的记忆和简单分类问题，不需要复杂的应用或分析。 | 难度: 在选择题中属于较高难度，题目涉及多个复杂概念（如Burgers向量、刃型位错、螺型位错、位错线方向向量等）的相互关系，并要求理解这些概念在不同几何条件下的变化规律。需要考生具备扎实的晶体缺陷理论基础和空间几何分析能力，属于需要综合运用多个知识点进行判断的题目类型。" + }, + { + "idx": 206, + "question": "Explain the differences between structural water, bound water (tightly bound water, loosely bound water), and free water in clay.", + "answer": "Structural water in clay refers to the water within the clay structure. Since clay particles are generally negatively charged and water is a polar molecule, when clay particles are dispersed in water, under the influence of the negative electric field on the clay surface, water molecules align in a specific orientation around the clay particles, forming hydrogen bonds with the oxygen and hydroxyl groups on the surface, with their negative ends facing outward. A negatively charged surface forms around the first layer of water molecules, attracting a second layer of water molecules. The attractive force of the negative electric field on water molecules weakens with increasing distance from the clay surface, causing the arrangement of water molecules to transition gradually from ordered to disordered. The inner layer of water molecules arranged in an ordered manner is called tightly bound water, which surrounds the clay particles and moves together with them as a whole in the medium, with a thickness of approximately 3 to 10 water molecules. The outer layer of water molecules, which is less ordered, is called loosely bound water. Due to their greater distance from the clay particle surface, the binding force between them is weaker. The water beyond the loosely bound water is called free water.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释不同类型的水在粘土中的区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对粘土中不同类型水的定义和分类的记忆和理解，属于基础概念的记忆性知识。虽然涉及了一些水分子排列和相互作用的描述，但整体上仍属于对基本概念的解释和论述，没有涉及复杂的应用或分析。 | 难度: 在选择题中属于高难度，题目要求考生理解并区分粘土中不同状态的水（结构水、结合水中的紧密结合水和松散结合水、自由水）的定义及其形成机制。这涉及多个复杂概念的阐述和比较，需要考生对粘土颗粒表面电场作用、水分子排列方式以及不同水层的特性有深入的理解。此外，题目还要求考生能够将这些概念联系起来，形成一个完整的知识体系，这在选择题型中属于较高难度的要求。" + }, + { + "idx": 880, + "question": "Briefly describe Pauling's rules", + "answer": "Pauling's rules: $\\textcircled{1}$ The coordination polyhedron rule: A coordination polyhedron of anions is formed around a cation. The distance between the cation and anion depends on the sum of their ionic radii, while the coordination number depends on the ratio of their ionic radii. $\\textcircled{2}$ The electrostatic valence rule: In forming an ionic bond, the number of valence electrons given by the cation equals the number received by the anion. $\\textcircled{3}$ The rule of polyhedron linkage: Coordination polyhedra tend to share vertices, followed by edges and faces. The higher the cation's valence and the lower its coordination number, the more pronounced this effect. $\\textcircled{4}$ In crystals containing more than one type of cation, the coordination polyhedra of anions around cations with higher valence and smaller coordination numbers tend to share vertices. $\\textcircled{5}$ The types of coordination polyhedra in a crystal tend to be minimal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述Pauling's rules，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目主要考查对Pauling规则的基本概念的记忆和理解，包括其五个主要规则的描述。这些内容属于材料科学中晶体结构的基础知识，不需要复杂的应用或分析，只需对规则进行简要解释即可。 | 难度: 在选择题型中，该题目属于高难度等级。虽然题目要求的是基础概念记忆，但Pauling's rules包含五个具体规则，每个规则都需要准确理解和记忆。选择题型中，正确选项需要涵盖所有规则，考生必须能够区分和识别每个规则的具体内容。此外，这些规则涉及多个相关概念（如配位多面体、离子半径、电价等），需要考生具备较高的知识整合能力。因此，在选择题型内，该题目属于复杂概念体系阐述的难度等级。" + }, + { + "idx": 2545, + "question": "Describe Pauling's rules regarding the structure of ionic compounds", + "answer": "(1) A coordination polyhedron of anions is formed around the cation, with the distance between the cation and anion determined by the sum of their ionic radii, and the coordination number determined by the ratio of the cation to anion radii; (2) The number of valence electrons provided by the cation equals the number of valence electrons received by the anion, hence Z+/CN+=Z-/CN-; (3) In a coordination structure, when coordination polyhedra share edges, especially faces, their stability decreases, and this effect is more pronounced for cations with higher valence and lower coordination numbers; (4) In crystals containing more than one type of cation, the coordination polyhedra of anions around cations with higher valence and smaller coordination numbers tend to connect by sharing vertices; (5) The types of coordination polyhedra in a crystal tend to be minimized.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述Pauling关于离子化合物结构的规则，需要文字解释和论述，答案以列举要点形式呈现，符合简答题的特征 | 知识层次: 题目要求描述Pauling规则，属于对基本原理的记忆性知识，主要考查学生对基础概念的理解和记忆能力，不涉及复杂的应用或分析过程。 | 难度: 在选择题中属于高难度，题目要求描述Pauling规则，涉及多个复杂概念和原理的综合阐述，包括离子半径比、配位数、配位多面体的稳定性、高电荷阳离子的配位多面体连接方式以及晶体中配位多面体类型的最小化等。这些内容不仅需要记忆，还需要深入理解和整合多个相关概念，因此在选择题型中属于较高难度。" + }, + { + "idx": 315, + "question": "Compare interstitial solid solution and interstitial phase", + "answer": "Commonality: In both, the alloying elements are in interstitial positions and are themselves very small in size. Differences: Interstitial solid solution is a solid solution that retains the crystal structure of the solvent and has very low solubility, exhibiting tough and good plastic properties; interstitial phase is an intermediate phase (size-factor compound), with A and B atoms in proportional quantities, exhibiting hard properties and poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种不同的材料科学概念（间隙固溶体和间隙相），并详细解释它们的共同点和差异。答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对间隙固溶体和间隙相的基本概念的记忆和理解，包括它们的共同点和区别，属于基础概念的记忆性知识。 | 难度: 在选择题中属于较高难度，需要理解并比较两个复杂概念（间隙固溶体和间隙相）的共同点和差异点。题目不仅要求记忆定义，还需要分析两者的晶体结构、溶解度、力学性能等多方面特征，并进行综合对比。这种题目在选择题型中属于对知识掌握深度和综合分析能力要求较高的类型。" + }, + { + "idx": 3160, + "question": "What type does the alloy phase Fe3C belong to, and what are its structural characteristics?", + "answer": "Fe3C is a complex lattice interstitial compound with an orthorhombic crystal system. Its unit cell contains 12 iron atoms and 4 carbon atoms. The iron atoms are arranged in a close-packed manner, forming octahedrons, with carbon atoms located in the octahedral interstitial sites. The corner atoms of the octahedrons are shared by two adjacent octahedrons, and there is a certain orientation between the octahedrons.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C合金相的类型和结构特征，答案提供了详细的文字描述和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对Fe3C合金相的类型和结构特征的基本概念记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题中属于较高难度，需要掌握复杂概念体系。题目要求考生不仅知道Fe3C的分类（复杂间隙化合物），还需理解其正交晶系结构特征、晶胞组成（12Fe+4C）、铁原子密排方式形成的八面体间隙，以及碳原子在其中的位置分布。这些知识点涉及晶体结构、原子排列和间隙理论等多个相互关联的概念，需要考生具备较强的空间想象能力和对金属学基础理论的深入理解。" + }, + { + "idx": 954, + "question": "What are the factors affecting solid solubility?", + "answer": "The factors affecting solid solubility include: 1. Atomic size factor. When the relative difference in atomic diameters between the solvent and solute is less than ±15%, there is a large substitutional solubility. 2. Electronegativity factor. The smaller the electronegativity difference between the solvent and solute, the greater the solubility; generally, a difference less than 0.4∼0.5 results in higher solubility. 3. Electron concentration factor. This has two aspects: one is the atomic valence effect, meaning for the same solvent metal, the higher the valence of the solute, the lower the solubility; the other is the relative valence effect, meaning the solubility of a high-valence solute in a low-valence solvent is higher than the opposite scenario.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释影响固溶度的因素，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对影响固溶度的因素的基本概念的记忆和理解，包括原子尺寸因素、电负性因素和电子浓度因素等基本原理，不需要复杂的应用或分析。 | 难度: 在选择题中属于高难度，题目要求考生掌握并理解多个影响固溶度的因素（原子尺寸因素、电负性因素、电子浓度因素），每个因素又包含具体的判断标准和原理。考生需要整合这些复杂概念体系，并能在选项中准确识别或匹配这些知识点。这超出了简单定义记忆的范畴，属于对复杂概念体系的阐述和应用。" + }, + { + "idx": 1680, + "question": "Compare the electronegativity of Ca and Mg, and determine whether CaO-MgO meets the electronegativity condition for forming a solid solution. (The electronegativity of Ca is 1.0, and that of Mg is 1.2)", + "answer": "The electronegativity of Ca is 1.0, and that of Mg is 1.2. Their electronegativity values are close and within the same period, meeting the electronegativity condition for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较Ca和Mg的电负性，并判断CaO-MgO是否符合形成固溶体的电负性条件。答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种元素的电负性并判断是否符合形成固溶体的条件，涉及基本概念的应用和简单判断，不需要复杂的分析或多步计算。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对电负性基本概念的理解和简单比较。题目提供了明确的电负性数值，只需进行直接比较和判断是否符合固溶体形成的电负性条件，无需复杂计算或多步骤推理。属于选择题中较为基础的难度水平。" + }, + { + "idx": 34, + "question": "According to the rules of ionic compound formation, when all octahedral interstitial sites are filled, what valence cations should be inserted in the interstitial sites? Please provide examples.", + "answer": "The ratio of cation to anion valences should be 1:1, such as NaCl.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释离子化合物形成规则，并提供例子，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对离子化合物形成规则的基本应用，需要理解八面体间隙填充的价态规则，并给出具体例子。虽然涉及一定的概念理解，但主要是直接应用基本原理，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用难度。题目直接考察对离子化合物形成规则的基本理解，只需套用已知的1:1价态比例规则即可选出正确答案。解题步骤简单明确，不需要复杂分析或计算，符合选择题型中对基本知识点直接应用的考查要求。" + }, + { + "idx": 3384, + "question": "What is the approximate quenching process in the manufacturing route of round dies made from 9SiCr steel?", + "answer": "Quenching process: Heating temperature 850-870°C (oil quenching).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释具体的淬火工艺参数，答案以文字形式给出具体温度范围和淬火介质，属于需要文字解释的简答题类型 | 知识层次: 题目考查的是特定材料（9SiCr钢）在特定工艺（淬火）中的具体参数（加热温度850-870°C，油淬）的应用，属于直接套用工艺知识的简单应用层次，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用已知的淬火工艺参数（850-870°C油淬）即可作答，无需复杂计算或概念分析。题目考察的是对基础工艺参数的记忆能力，符合等级2“简单应用过程描述”的标准。" + }, + { + "idx": 4332, + "question": "Consider 2.5 kg of austenite containing 0.65 wt % C, cooled to below 727 C (1341 F). What is the proeutectoid phase?", + "answer": "ferrite is the proeutectoid phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来确定proeutectoid phase，而不是从多个选项中选择、判断对错或进行数值计算。答案“ferrite is the proeutectoid phase”是一个简短的文字回答，符合简答题的特征。 | 知识层次: 题目需要应用铁碳相图的基本知识来确定先共析相，涉及简单的相图分析和成分判断，属于直接套用基础知识的简单应用。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需基本公式应用和简单计算，直接套用知识点即可得出正确答案。题目要求判断亚共析相，只需根据给定的碳含量（0.65 wt% C）和冷却温度（低于727°C）直接应用铁碳相图的基本知识即可确定先共析相为铁素体（ferrite），无需复杂分析或多步骤推理。" + }, + { + "idx": 452, + "question": "Approximate process parameters for recrystallization annealing", + "answer": "Process parameters: Heating temperature T=0.4Tm plus 100~200Ω, heating time depends on the specific furnace load and workpiece size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求提供近似的过程参数，答案以文字解释和论述的形式给出，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求提供再结晶退火的近似工艺参数，涉及基本公式（T=0.4Tm）和简单应用（加热温度的计算和加热时间的估计），属于直接套用基本知识的范畴，不需要复杂的分析或综合。 | 难度: 在选择题中属于较低难度，题目仅要求考生识别正确的再结晶退火工艺参数描述，涉及基本公式应用（0.4Tm）和简单参数范围记忆（100~200Ω），无需复杂计算或概念比较。" + }, + { + "idx": 3847, + "question": "For an Fe-0.35% C alloy, determine the primary microconstituent that forms.", + "answer": "primary α-ferrite", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定合金的主要微观组成，需要基于材料科学知识进行文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目要求根据给定的合金成分（Fe-0.35% C）确定主要微观组成物（primary α-ferrite），这需要应用铁碳相图的基本知识，属于直接套用相图信息的简单应用。虽然需要理解相图的基本概念，但不需要多步计算或综合分析，思维过程较为直接。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需根据给定的Fe-0.35% C合金成分直接套用铁碳相图的基本知识即可确定主要微观组织为primary α-ferrite。解题步骤简单直接，无需复杂计算或多概念综合分析，因此在选择题型内属于较低难度等级。" + }, + { + "idx": 1044, + "question": "Write all the crystallographic directions included in the <123> direction family in the cubic crystal system.", + "answer": "[123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], [123], [132], [231], [213], [321], [312], totaling 24 crystallographic directions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举立方晶系中<123>方向族包含的所有晶向，需要文字描述和具体列举，不涉及选择、判断或数值计算。 | 知识层次: 题目要求列出立方晶系中<123>方向族的所有晶向，这需要应用立方晶系晶向指数的基本规则和对称性知识，属于直接套用基本概念进行简单列举的应用层次。虽然涉及多个方向的计算，但思维过程较为直接，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对立方晶系中晶向族的基本理解和直接套用。虽然需要列举多个晶向，但所有选项都是通过简单的排列组合得出，无需复杂计算或深入分析。因此，在选择题型内属于较低难度。" + }, + { + "idx": 352, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the atomic radius of an FCC unit cell?", + "answer": "The atomic radius is √2a/4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释常见的晶体结构参数，并给出FCC晶胞的原子半径，需要文字解释和论述，答案形式为简短的文字描述。 | 知识层次: 题目要求描述晶体结构（晶胞）的常见参数，并计算面心立方晶胞的原子半径。这需要应用基本的晶体学知识（如晶胞参数的定义）和简单的数学计算（如原子半径与晶格常数的关系公式）。虽然需要一定的理解，但主要是直接套用已知公式进行计算，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（FCC原子半径公式）进行计算。题目提供了明确的参数（a）和公式结构，解题步骤简单直接，无需复杂分析或概念比较。在选择题型内，此类直接应用公式的题目通常属于较低难度等级。" + }, + { + "idx": 246, + "question": "The diffusion coefficient values of Al2O3 at 1393°C and 1716°C", + "answer": "As shown in the figure, the diffusion coefficient values of Al2O3 at 1393°C and 1716°C are D3 and D4, respectively (specific values need to be read from the figure).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表读取并描述扩散系数值，答案需要文字解释和具体数值的引用，属于简答题类型。 | 知识层次: 题目要求从图中读取扩散系数值，属于基本数据的直接应用，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接应用和简单计算能力。题目提供了明确的温度点和对应的扩散系数值，只需要根据图表读取具体数值即可完成选择，无需复杂的分析或推理过程。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 1676, + "question": "Compare the number of valence electrons in CaO and MgO, and determine whether CaO-MgO meets the electron concentration condition for forming a solid solution.", + "answer": "CaO and MgO have the same number of valence electrons, meeting the electron concentration condition for forming a solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较CaO和MgO的价电子数，并判断是否满足形成固溶体的电子浓度条件，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要比较CaO和MgO的价电子数，并判断是否符合形成固溶体的电子浓度条件。这涉及基本概念的应用（价电子数和固溶体形成条件），但不需要复杂的计算或深入的分析，属于直接套用基本原理的简单应用。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需要基本公式应用和简单计算。题目直接比较CaO和MgO的价电子数，并套用固溶体形成的电子浓度条件，解题步骤简单明了，无需复杂分析或深入理解多个概念。" + }, + { + "idx": 2027, + "question": "An organic compound has the composition ${w_{\\mathrm{C}}=62.1/10^{-2}}$, ${w_{\\mathrm{H}}}=10.3/1\\\\time10^{-2}$, $\\\\varpi_{0}=27.6/10^{-2}$. Try to write the possible name of the compound.", + "answer": "\\\\mathrm{{C}:\\\\mathrm{{H}:\\\\mathrm{{O}=\\\\frac{62.\\\\mathrm{{1}}}{12.\\\\mathrm{{,011}}}:\\\\frac{10.\\\\mathrm{{3}}}{1.\\\\mathrm{{007}\\\\mathrm{{97}}}}:\\\\frac{27.6}{15.\\\\mathrm{{9994}}}=5.2:10.2:1.7\\\\approx3:6:10.4:1.7\\\\approx3:6:1.74:\\\\mathrm{{8}.\\\\mathrm{{1}:\\\\mathrm{{7}}}}}}} Therefore, the possible compound is $\\\\mathrm{CH}_{3}\\\\mathrm{COCH}_{3}$ (acetone).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据给定的元素组成比例推导出可能的有机化合物名称，并给出详细的推导过程。答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目要求根据给定的元素组成比例计算并推断可能的有机化合物名称，主要涉及基本的化学计量计算和简单的分子式推导，属于基本公式应用和直接套用的范畴。虽然需要一定的计算步骤，但整体思维过程较为直接，不涉及复杂的概念关联或综合分析。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求根据给定的元素组成比例计算并推断可能的有机化合物名称。解题步骤包括基本的化学计量计算和简单的比例转换，最终直接套用常见有机化合物的分子式（丙酮）。选择题型中，这种题目仅需基本公式应用和简单计算，无需复杂的分析或推理过程，因此难度较低。" + }, + { + "idx": 3735, + "question": "What are the maximum stress, the minimum stress, and the mean stress on the part during its use under conditions that provide for equal compressive and tensile stresses?", + "answer": "The maximum stress is +22 mpa, the minimum stress is -22 mpa, and the mean stress is 0 mpa.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释最大应力、最小应力和平均应力的具体数值，答案以文字形式给出具体数值，属于简答题类型。 | 知识层次: 题目涉及基本应力概念的应用，要求计算最大应力、最小应力和平均应力，属于直接套用基本公式和简单计算的范畴，不需要复杂的分析或综合思维。 | 难度: 在选择题中属于简单难度，题目直接给出了应力条件（等值压缩和拉伸应力），只需要应用基本公式计算最大、最小和平均应力。解题步骤简单，仅需套用公式即可得出答案，无需复杂分析或深入理解多个概念。" + }, + { + "idx": 4674, + "question": "To what equation does the expression for interplanar spacing (d_{\text {hkl }}) reduce for crystals having tetragonal symmetry, given that a, b and c are the lattice parameters?", + "answer": "For crystals having tetragonal symmetry, a=b \neq c. Replacing b with a in the given equation leads to (\frac{1}{d_{h k l}^{2}}=\frac{h^{2}}{a^{2}}+\frac{k^{2}}{a^{2}}+\frac{l^{2}}{c^{2}} = \frac{h^{2}+k^{2}}{a^{2}}+\frac{l^{2}}{c^{2}}).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释并推导出特定晶体对称性下的晶面间距表达式，答案提供了详细的推导过程和最终公式，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求将四方晶系的对称性条件（a=b≠c）代入晶面间距公式进行简化，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式并进行简单的代数替换（将b替换为a）。解题步骤简单明确，无需复杂推导或深入理解多个概念，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 351, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the packing density of an FCC unit cell?", + "answer": "Packing density 0.74.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述晶体结构的常见参数，并计算FCC晶胞的堆积密度，需要文字解释和数值计算相结合的回答方式。 | 知识层次: 题目要求描述晶体结构（晶胞）的常见参数，并计算FCC晶胞的堆积密度。虽然需要理解晶体结构的基本概念，但主要涉及基本公式的应用和简单计算，属于直接套用和简单应用层次。 | 难度: 在选择题中属于简单应用难度，题目直接考察对FCC晶胞堆积密度的记忆和基本公式应用，无需复杂计算或分析，仅需正确识别和选择给定的正确选项。" + }, + { + "idx": 4894, + "question": "(a) Write an expression for the modulus of elasticity for a hybrid composite in which all fibers of both types are oriented in the same direction.", + "answer": "the expression for the modulus of elasticity for a hybrid composite with all fibers aligned in the same direction is: e_cl = e_m v_m + e_f1 v_f1 + e_f2 v_f2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出混合复合材料弹性模量的表达式，需要文字解释和论述，答案是一个公式表达式，属于简答题类型。 | 知识层次: 题目要求写出混合复合材料弹性模量的表达式，这属于基本公式的直接应用。虽然涉及多个组分（基体和两种纤维），但只需简单地将各组分模量按其体积分数加权求和，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用过程描述。题目要求直接套用已知的混合复合材料弹性模量公式，无需复杂的分析或计算步骤。考生只需识别并应用基本公式即可得出正确答案，属于基础难度水平。" + }, + { + "idx": 125, + "question": "Use experimental methods to identify silica gel", + "answer": "Use X-ray detection. Silica gel—loose and porous.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用实验方法识别硅胶，答案需要文字解释和论述具体的实验方法（X射线检测）和硅胶的特征（松散多孔），属于需要文字解释的简答题类型。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别硅胶，并描述其特性（松散多孔）。这属于直接应用基本的实验技术和材料特性知识，不需要复杂的分析或综合过程。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需识别正确的实验方法（X-ray检测）并理解硅胶的基本特性（松散多孔）。题目直接给出了正确选项，无需复杂分析或多步骤推理，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 4418, + "question": "Give the approximate temperature at which it is desirable to heat a 0.45 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 830°C (1525°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个数值，但解答过程需要基于材料科学知识和对热处理工艺的理解，属于需要简要回答的问题类型。 | 知识层次: 题目考查对铁碳合金热处理温度的直接应用，需要记忆特定成分合金的退火温度，属于基本知识的直接应用，不涉及复杂计算或多概念关联。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需根据铁碳相图的基本知识直接套用0.45 wt% C对应的完全退火温度（A3线以上30-50°C），无需复杂计算或分析过程。题目考察的是对基础热处理参数的记忆和应用能力，属于选择题中较为基础的难度级别。" + }, + { + "idx": 4417, + "question": "Give the approximate temperature at which it is desirable to heat a 0.25 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 880°C (1510°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个具体的数值，但题目并未提供选项或要求进行计算，而是需要基于知识直接回答，类似于简答题的形式。 | 知识层次: 题目考查对铁碳合金热处理温度的直接应用，属于基本知识的简单应用，不需要复杂的计算或分析 | 难度: 在选择题型内，该题目属于简单应用层次，仅需要考生直接套用基本知识（铁碳相图中的A3线温度）即可得出答案，无需复杂计算或多步骤推理。题目考察的是对基础知识的直接回忆和应用能力，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 2334, + "question": "What type of solid solution is formed when hydrogen atoms dissolve in aluminum?", + "answer": "The crystal structure of aluminum is fcc. From the appendix, the radius of the hydrogen atom is found to be rH=0.046nm, and the radius of the aluminum atom is rAl=0.143nm. The radius ratio rH/rAl=0.046/0.143=0.32.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释氢原子溶解在铝中形成的固溶体类型，答案提供了晶体结构、原子半径比等文字解释和论述，没有涉及选项选择、对错判断或具体数值计算。 | 知识层次: 题目需要应用基本的半径比计算来判断固溶体类型，属于直接套用基本公式和简单计算的范畴，不涉及多步计算或复杂分析。 | 难度: 在选择题中属于较低难度，题目仅要求简单应用基本公式进行计算（半径比计算），并直接套用已知数据（原子半径）。解题步骤简单直接，无需复杂分析或概念整合。" + }, + { + "idx": 3336, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for normalizing φ25 hot-rolled eutectoid steel.", + "answer": "Normalizing: 780°C holding for 1h, air cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求确定热处理条件（温度、时间、冷却速率等），答案需要文字解释和论述，而不是从选项中选择或简单的对错判断或数值计算。 | 知识层次: 题目要求根据给定的材料（φ25热轧共析钢）直接应用标准的热处理工艺（正火），涉及温度、时间和冷却方式等具体参数的记忆和应用，属于直接套用标准工艺的简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用标准热处理工艺参数（780°C保温1小时空冷）即可作答。不需要进行计算或复杂分析，属于对基础知识的直接应用，符合等级2\"简单应用过程描述\"的特征。" + }, + { + "idx": 3460, + "question": "What are the different application scenarios for austenitic stainless steel, wear-resistant steel, and quenched tool steel?", + "answer": "Wear-resistant steel is used to make working parts that withstand strong impact and pressure, such as bulldozer blades and railway switches. Quenched tool steel is used in situations that do not require withstanding strong impact pressure but demand high wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对不同类型钢材的应用场景进行文字解释和论述，答案提供了详细的描述而非选择或判断。 | 知识层次: 题目要求对不同类型钢材的应用场景进行解释和论述，涉及的是基本概念的直接应用和简单关联，不需要复杂的分析或综合推理。 | 难度: 在选择题中属于简单应用难度，题目直接描述了不同钢材的应用场景，只需根据题目内容进行匹配选择，无需复杂分析或计算。" + }, + { + "idx": 3172, + "question": "Two positive edge dislocations on the same slip plane, with Burgers vector b and separated by a distance L, when L is much larger than the magnitude of the Burgers vector, what is the total energy?", + "answer": "When the two edge dislocations are far apart, the total energy equals the sum of their individual energies, regardless of whether they are like or unlike dislocations, given by W=W1+W2=2αGb2", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个刃位错在特定条件下的总能量，答案提供了理论解释和公式应用，需要文字论述而非简单选择或判断。 | 知识层次: 题目考查对位错能量基本公式的直接应用，仅需简单计算和套用公式，无需多步推理或综合分析。 | 难度: 在选择题型内，该题目属于简单应用层次，仅需直接套用基本公式进行计算。题目明确给出了两个刃位错的总能量等于各自能量之和的条件，且不需要复杂的分析或比较。因此，在选择题型中属于较低难度，符合等级2的标准。" + }, + { + "idx": 121, + "question": "Use experimental methods to identify SiO2 glass", + "answer": "Use X-ray detection. SiO2 glass - isotropic.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求使用实验方法识别SiO2玻璃，答案提供了具体的实验方法（X-ray detection）和结果（isotropic），这需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求使用实验方法（X射线检测）来识别SiO2玻璃，并解释其各向同性特性。这属于基本实验方法的直接应用，不需要复杂的分析或多步骤推理，主要涉及对实验原理和材料特性的简单理解和应用。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本知识（X-ray检测和SiO2玻璃的各向同性特性）即可选出正确选项，无需复杂分析或多步骤推理。" + }, + { + "idx": 4414, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.20 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 905°C (1660°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或进行判断。虽然答案是一个数值，但解答过程需要基于材料科学知识（如铁碳相图）进行解释和推导，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要应用铁碳相图的基本知识来确定奥氏体化温度，属于直接套用相图信息的简单应用，不需要多步计算或复杂分析。 | 难度: 在选择题中属于简单应用难度，仅需直接套用铁碳相图中的基本知识（A3线）即可得出答案，无需复杂计算或深入分析。" + }, + { + "idx": 661, + "question": "Choose any material and describe its possible uses and processing methods.", + "answer": "Aluminum alloy is used to manufacture packaging containers such as beverage cans and food cans. For example, beverage companies like Coca-Cola and Pepsi extensively use aluminum alloy cans, which offer excellent sealing, corrosion resistance, and recyclability, ensuring beverage quality protection and convenience for consumers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求选择一个材料并描述其用途和加工方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述材料的用途和加工方法，属于对基础知识的直接应用，不需要复杂的分析或综合。答案中提到的铝合金属性及其在包装容器中的应用是材料科学中的常见案例，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用过程描述。题目要求选择一个材料并描述其用途和加工方法，正确选项直接给出了铝合金属的具体应用实例（饮料罐和食品罐）及其优点（密封性、耐腐蚀性、可回收性），这些都是材料科学中的基本知识点。题目不需要复杂的计算或深入的分析，只需对材料的基本应用有了解即可作答。因此，在选择题型内属于较低难度。" + }, + { + "idx": 2161, + "question": "For a face-centered cubic crystal with a movable slip system of (111)[110], indicate the Burgers vector of the unit dislocation causing the slip (taking the lattice constant a=0.2nm).", + "answer": "The Burgers vector of the unit dislocation causing the slip is b=a/2[110], which is the vector represented by the line connecting two adjacent atoms along the slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释并给出Burgers vector的具体表达式，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求应用基本的晶体学知识（面心立方晶体的滑移系和伯格斯矢量）进行计算和解释，涉及直接套用已知公式和概念，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接套用和简单计算。题目明确给出了晶体结构和滑移系统，只需根据已知条件直接应用Burgers向量的计算公式即可得出答案，无需复杂的分析或推理过程。因此，在选择题型内属于较低难度。" + }, + { + "idx": 3726, + "question": "Will the polymer fracture if its flexural strength is 85 MPa? Assume that no plastic deformation occurs.", + "answer": "the applied stress is 61.5 MPa, which is less than the flexural strength of 85 MPa; the polymer is not expected to fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过比较施加应力和弯曲强度来判断聚合物是否会断裂，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目涉及基本公式应用和简单计算，只需比较施加应力与弯曲强度的数值关系即可得出结论，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需比较施加应力（61.5 MPa）与弯曲强度（85 MPa）的数值关系即可得出结论。解题步骤直接，无需复杂计算或深入分析，符合等级2\"简单应用过程描述\"的标准。" + }, + { + "idx": 3734, + "question": "To survive for one million cycles under conditions that provide for equal compressive and tensile stresses, what is the fatigue strength, or maximum stress amplitude, required?", + "answer": "The fatigue strength at one million cycles is 22 mpa.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释在特定条件下所需的疲劳强度，答案提供了具体的数值和解释，符合简答题的特征。 | 知识层次: 题目要求根据给定的条件（一百万次循环）确定疲劳强度，这涉及直接应用疲劳强度的基本概念和已知数据（22 MPa）。虽然需要理解疲劳强度的定义，但主要是一个简单的数据应用过程，不需要多步计算或深入分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式或已知数据（疲劳强度在100万次循环下的标准值）即可得出正确答案。题目没有复杂的计算步骤或需要深入理解多个概念，仅需识别并选择给定的正确选项。因此，在选择题型内属于较低难度（等级2）。" + }, + { + "idx": 3588, + "question": "Determine the crystal structure for a metal with a0=0.42906 nm, r=0.1858 nm and one atom per lattice point.", + "answer": "bcc", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算和解释确定晶体的结构类型，答案需要基于给定的参数（a0和r）进行推导，并给出具体的晶体结构类型（如bcc），这属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求根据给定的晶格常数和原子半径确定晶体结构，这需要应用基本的晶体几何关系公式进行计算和判断。虽然涉及一定的计算步骤，但属于直接套用公式和基本概念的应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需套用基本公式（如原子半径与晶格常数的关系）进行简单计算即可确定晶体结构类型。解题步骤直接且无需复杂分析，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 4673, + "question": "To what equation does the expression for interplanar spacing (d_{\text {hkl }}) reduce for crystals having cubic symmetry, given that (a,(b), and c are the lattice parameters?", + "answer": "For the crystals having cubic symmetry, a=b=c. Making this substitution into the given equation leads to (\frac{1}{d_{h k l}^{2}}=\frac{h^{2}}{a^{2}}+\frac{k^{2}}{a^{2}}+\frac{l^{2}}{a^{2}} = \frac{h^{2}+k^{2}+l^{2}}{a^{2}}).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释立方对称晶体的晶面间距表达式如何简化，答案提供了详细的推导过程和文字解释，符合简答题的特征。 | 知识层次: 题目要求将立方对称晶体的条件（a=b=c）代入晶面间距公式进行简化，属于基本公式的直接应用，无需多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求考生将立方晶系的对称性条件（a=b=c）直接代入晶面间距公式，并进行简单的代数运算。解题步骤明确且直接，无需复杂的推导或分析。考生只需掌握基本公式和简单计算能力即可正确作答，符合选择题型中等级2的简单应用要求。" + }, + { + "idx": 245, + "question": "The diffusion coefficient values of CaO at 1145°C and 1650°C", + "answer": "As shown in the figure, the diffusion coefficient values of CaO at 1145°C and 1650°C are D1 and D2, respectively (specific values need to be read from the figure).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据图表中的数据提供具体的扩散系数值，需要读取图表并给出具体数值，属于需要简短回答的问题。 | 知识层次: 题目要求从图中读取扩散系数的具体数值，属于基本数据的直接应用，不需要复杂的计算或深入的分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需要根据图表读取扩散系数值并进行简单比较。题目提供了明确的信息来源（图表）和具体温度点，不需要复杂的计算或深入的概念理解。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 3622, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{MgS}.", + "answer": "6", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要应用材料科学知识进行判断，答案是一个具体的数值而非选择或判断对错，属于需要简要解释和论述的简答题类型 | 知识层次: 题目要求根据离子半径确定配位数，这属于基本公式应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需要根据已知的离子半径直接套用协调数判断规则即可得出答案。解题步骤简单，无需复杂计算或深入分析，符合等级2的简单应用过程描述标准。" + }, + { + "idx": 3618, + "question": "Using the ionic radii, determine the coordination number expected for \\mathrm{BaO}.", + "answer": "8", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据离子半径确定配位数，需要一定的解释和论述，而不仅仅是简单的选择或计算。答案虽然是一个数字，但解答过程需要理解和应用离子半径与配位数的关系。 | 知识层次: 题目要求根据离子半径确定配位数，这属于基本公式应用和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需根据已知的离子半径直接套用协调数的基本规则即可得出答案。解题步骤简单直接，不需要复杂的计算或深入的概念理解，因此在选择题型内属于较低难度。" + }, + { + "idx": 803, + "question": "What are the methods of alloy strengthening?", + "answer": "Grain refinement strengthening, solid solution strengthening, multiphase strengthening, dispersion strengthening (age hardening), and work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举合金强化的方法，答案是通过文字解释和论述的形式给出，没有提供选项或要求判断对错，也不需要数值计算。 | 知识层次: 题目考查合金强化方法的基本分类和记忆，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生掌握合金强化的多种方法（晶粒细化强化、固溶强化、多相强化、弥散强化/时效硬化、加工硬化），并能准确识别和区分这些方法。这比单纯记忆单个定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 3070, + "question": "What is reaction sintering?", + "answer": "Reaction sintering is a process in which ceramic powders of various compounds (such as Si, Si-SiN4 powder, etc.) are pressed into shape and then subjected to special chemical treatment during sintering to obtain ceramics.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"reaction sintering\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对反应烧结（reaction sintering）这一基本概念的定义和简单描述，属于基础概念的记忆和理解层次，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求考生理解反应烧结的定义和基本原理，但不需要进行复杂的概念体系阐述或比较分析。正确选项提供了明确的定义和基本过程描述，属于中等难度的选择题。" + }, + { + "idx": 822, + "question": "What are the main characteristics of Frank partial dislocations in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "Frank partial dislocation; Burgers vector is 1/3 <111>; the nature of the dislocation is edge-type; the formation method involves inserting or removing a layer of {111} close-packed plane in a local region of the crystal; the motion state is that it can only climb, not glide.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释Frank partial dislocations在FCC晶体中的主要特征，包括多个方面的描述（如位错名称、Burgers矢量、位错性质、形成方法和运动状态），答案提供了全面的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对Frank partial dislocations在FCC晶体中的基本特性的记忆和理解，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态等基础概念。这些内容属于材料科学中位错理论的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生记忆并理解Frank partial dislocations的多个关键特征，包括名称、Burgers向量、位错性质、形成方法和运动状态。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或比较。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 899, + "question": "Write the mathematical expression of Fick's first law and explain its significance.", + "answer": "In one dimension, J=-D(dc/dx). J: diffusion flux, the amount of substance diffusing per unit time through a unit area, g/s·m²; D: diffusion coefficient, m²/s; dc/dx: concentration gradient, g/m³. Its significance is that the amount of substance diffused is proportional to the concentration gradient of the substance and in the opposite direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出Fick第一定律的数学表达式并解释其意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Fick第一定律的基本数学表达式及其物理意义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅记忆Fick's第一定律的数学表达式，还需要解释其物理意义和各符号的含义。这超出了单纯的定义记忆（等级1），但并未涉及复杂的概念体系或深入的分析（等级3）。因此，属于概念解释和描述的难度等级2。" + }, + { + "idx": 1192, + "question": "What is the second type of temper brittleness?", + "answer": "The brittleness that occurs during tempering between 450~650℃ is called high-temperature temper brittleness, also known as the second type of temper brittleness. The second type of temper brittleness is reversible. The main reason for its occurrence is that impurity elements such as Sb, Sn, P, and As segregate to the original austenite grain boundaries during tempering, weakening the atomic bonding force at the austenite grain boundaries and reducing the grain boundary fracture strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释第二类回火脆性的定义和原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对第二类回火脆性的定义、发生温度范围、可逆性以及主要原因等基本概念的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解第二类回火脆性的定义、温度范围、可逆性以及产生原因等多个知识点。正确选项提供了较为详细的解释，考生需要将这些信息整合并选择正确的描述。相比于仅需记忆简单定义的等级1题目，该题目对概念的理解和描述要求更高，但尚未达到需要阐述复杂概念体系的等级3难度。" + }, + { + "idx": 311, + "question": "Are there differences in the atomic stacking modes and packing densities between face-centered cubic and hexagonal close-packed metals? Please explain.", + "answer": "FCC stacks in the ABCABC sequence, while HCP stacks in the ABABAB sequence; there is no difference in packing density, both are 0.74.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释面心立方和六方密堆积金属的原子堆垛方式和堆积密度差异，答案需要文字论述和解释，而非选择、判断或计算。 | 知识层次: 题目考查对FCC和HCP两种晶体结构的基本概念的记忆和理解，包括它们的原子堆垛顺序和堆积密度。不需要复杂的计算或综合分析，只需直接回答基本概念即可。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个晶体结构（FCC和HCP）的比较，但正确选项直接给出了明确的序列差异和相同的堆积密度，不需要复杂的推导或分析。主要考察的是对基础概念的记忆和简单对比，符合等级2的概念解释和描述要求。" + }, + { + "idx": 1859, + "question": "In the face-centered cubic close-packed structure of the NaCl unit cell, how many octahedral voids are there?", + "answer": "There are a total of 4 octahedral voids in the NaCl unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求回答一个具体的问题，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对晶体结构中八面体空隙数量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（NaCl晶胞中的八面体空隙数量），但需要学生对面心立方紧密堆积结构有清晰的理解，并能准确计算空隙数量。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 718, + "question": "Types and quantitative relationship of voids", + "answer": "When equal-sized spheres are closely packed, the main types of voids are octahedral voids and tetrahedral voids. When $\\pmb{n}$ spheres are closely packed, there will be $\\textbf{\\em n}$ octahedral voids and $2n$ tetrahedral voids", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释紧密堆积中空隙的类型和数量关系，答案提供了详细的文字解释和定量关系，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，主要涉及空隙的类型和数量关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生掌握两种空隙类型（八面体空隙和四面体空隙）的定义及其数量关系。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。题目要求考生能够理解和描述空隙类型及其数量关系，符合等级2的难度标准。" + }, + { + "idx": 3025, + "question": "What is the aging of polymers?", + "answer": "The phenomenon where polymer materials gradually degrade in performance and eventually lose their use value due to external factors such as oxygen, light, heat, mechanical force, water vapor, and microorganisms during long-term storage and use is called aging. The fundamental cause of aging is the cross-linking and scission of polymer molecular chains under the influence of external factors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对聚合物老化的现象进行解释和论述，答案提供了详细的文字描述和原因分析，符合简答题的特征。 | 知识层次: 题目考查聚合物老化的基本定义和原因，属于基础概念的记忆和理解，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆聚合物老化的定义及其根本原因，涉及多个外部因素和分子链变化的基本原理。虽然需要掌握一定的基础知识，但不需要进行复杂的分析或比较，属于中等难度的选择题。" + }, + { + "idx": 367, + "question": "What is deformation texture?", + "answer": "The deformation process causes the grains to rotate, and finally certain crystallographic directions within each grain tend to become parallel. This preferred orientation due to deformation is called deformation texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"deformation texture\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即变形织构的定义和形成原因，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆\"deformation texture\"的定义和形成机制，需要掌握材料科学中关于晶体取向的基本概念。虽然涉及多个知识点（晶粒旋转、晶体学方向、择优取向），但整体仍属于单一概念的解释范畴，不需要进行复杂的概念体系分析或比较。在选择题型中，这属于中等偏基础的难度，比简单定义记忆稍复杂，但不及需要综合分析的多概念题目难度。" + }, + { + "idx": 1204, + "question": "During the crystallization of a solid solution, nucleation requires both (13) fluctuations and (14) fluctuations, as well as (15) fluctuations.", + "answer": "(13) structure; (14) energy; (15) composition", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定的关键词（structure, energy, composition）来完成句子，而不是从给定的选项中选择或进行判断、计算。这种形式更接近于简答题，需要考生回忆或理解相关概念来填写空白。 | 知识层次: 题目考查对结晶过程中成核所需波动类型的基本概念记忆，包括结构、能量和成分波动，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生同时掌握结构、能量和成分三个方面的波动在结晶成核过程中的作用。这比单纯记忆一个定义或概念（等级1）要复杂一些，但不需要进行复杂的分析或推理（等级3）。考生需要理解这三个波动的基本概念及其在结晶过程中的重要性，但不需要深入阐述或应用这些概念。" + }, + { + "idx": 4401, + "question": "Cite advantages of hot working.", + "answer": "The advantages of hot working are: (1) Large deformations are possible, which may be repeated. (2) Deformation energy requirements are relatively low.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举热加工的优点，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对热加工优势的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和描述热加工的两个具体优势，而不是简单地回忆单一的定义或分类。这要求考生对热加工的基本原理有一定的理解和记忆，能够准确描述其优势。因此，相较于仅需回忆基本定义的等级1题目，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 923, + "question": "Briefly describe the types of defects in metal crystals", + "answer": "According to size, they can be divided into: point defects, such as solute, impurity atoms, vacancies; line defects, such as dislocations; planar defects, such as various grain boundaries, phase boundaries, surfaces, etc.; volume defects, such as pores, bubbles, etc. Volume defects are absolutely harmful to material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述金属晶体中的缺陷类型，答案提供了详细的文字解释和分类论述，符合简答题的特征。 | 知识层次: 题目考查金属晶体缺陷的基本分类和定义，属于基础概念的记忆和理解层面，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目要求考生对金属晶体缺陷的分类进行描述，涉及点缺陷、线缺陷、面缺陷和体缺陷的基本概念。虽然需要记忆多个分类和例子，但题目仅要求简要描述，不涉及复杂的概念体系或深入分析，属于概念解释和描述的难度水平。" + }, + { + "idx": 942, + "question": "Briefly describe the characteristics of growth in solid-state phase transformations", + "answer": "The occurrence of habit phenomena, i.e., there is a precipitation sequence; special/regular microstructural morphologies, such as lamellar, acicular.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述固态相变中生长的特征，答案以文字解释和论述的形式给出，符合简答题的特点。 | 知识层次: 题目考查对固态相变生长特性的基本概念记忆和理解，涉及常见的现象和微观结构形态，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生描述固态相变中生长的特征，涉及基础概念的记忆和理解。虽然需要掌握一定的专业术语和基本原理，但题目仅要求简要描述，不需要复杂的分析或比较。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 4732, + "question": "Cite two reasons why interstitial diffusion is normally more rapid than vacancy diffusion.", + "answer": "Interstitial diffusion is normally more rapid than vacancy diffusion because: (1) interstitial atoms, being smaller, are more mobile; and (2) the probability of an empty adjacent interstitial site is greater than for a vacancy adjacent to a host (or substitutional impurity) atom.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举两个原因来解释间隙扩散比空位扩散更快，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对间隙扩散和空位扩散两种机制的基本理解和记忆，需要解释两种扩散速率差异的原因，属于基础概念的记忆和简单应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举两个原因，但这两个原因都是基础概念的直接应用，不需要复杂的推理或分析。学生需要理解并记忆间隙扩散和空位扩散的基本原理，并能够区分两者的特点。这比单纯的定义记忆（等级1）要求稍高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 1293, + "question": "What does secondary recrystallization conceptually refer to?", + "answer": "Secondary recrystallization refers to the phenomenon where, after recrystallization annealing, a metal subjected to higher temperatures or prolonged holding times experiences a few grains rapidly consuming other grains and growing, resulting in the entire metal being composed of a small number of exceptionally large grains that are tens to hundreds of times larger than the post-recrystallization grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"secondary recrystallization\"这一概念进行解释和论述，答案是一段详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对二次再结晶这一基础概念的定义和现象描述，属于记忆和理解层次的知识点，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对二次再结晶的定义和现象有较为深入的理解，能够描述其过程和结果。相比于简单的定义简答（等级1），该题目要求考生能够解释和描述一个具体的材料科学现象，属于概念解释和描述的层次（等级2）。" + }, + { + "idx": 1575, + "question": "4. Constitutional supercooling", + "answer": "During crystallization, the phenomenon where a supercooled zone forms in the liquid phase near the solid-liquid interface due to the redistribution of components between the solid and liquid phases is called constitutional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Constitutional supercooling\"这一现象进行文字解释和论述，答案提供了详细的定义和解释，符合简答题的特征。 | 知识层次: 题目考查对\"Constitutional supercooling\"这一基本概念的定义和现象描述，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并描述\"constitutional supercooling\"这一现象的定义和形成原因。这比简单识别定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2901, + "question": "Briefly describe the methods of polymer alloying", + "answer": "The preparation methods of polymer alloys can be divided into physical methods and chemical methods. Physical blending methods include dry powder blending, melt blending, and latex blending, with melt blending being the most commonly used. Chemical blending methods mainly include copolymerization-blending and interpenetrating polymer network methods.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述聚合物合金化的方法，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对聚合物合金制备方法的基本分类和简单描述，主要涉及记忆性知识，如物理方法和化学方法的具体类型及其特点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述聚合物合金化的方法，但正确选项已经提供了明确的分类和具体方法，包括物理方法和化学方法的具体类型。这需要考生不仅记住基本概念，还要理解并区分不同的制备方法。然而，由于选项已经结构化地呈现了信息，不需要考生自行组织复杂的概念体系，因此难度属于等级2。" + }, + { + "idx": 79, + "question": "What is the effect of forming a solid solution on the mechanical properties of materials?", + "answer": "Solid solution strengthening; the dissolution of solute atoms increases the strength and hardness of the solid solution. The strength and hardness of the solid solution are often higher than those of the constituent elements, while the plasticity is lower.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释固溶体对材料机械性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对固溶体强化这一基本概念的记忆和理解，属于材料科学中的基本原理和现象解释，不涉及复杂的计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（固溶强化），但正确选项不仅需要识别\"固溶强化\"这一概念，还需要理解其对机械性能的具体影响（强度硬度增加、塑性降低）。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。题目要求考生能够将固溶强化的基本原理与材料性能变化联系起来，属于概念解释和描述的难度层次。" + }, + { + "idx": 4216, + "question": "List the point coordinates of the titanium, barium, and oxygen ions for a unit cell of the perovskite crystal structure.", + "answer": " the barium ions are situated at all corner positions. The point coordinates for these ions are as follows: 000,100,110,010,001,101,111, and 011 .\nThe oxygen ions are located at all face-centered positions; therefore, their coordinates are \\frac{1}{2} \\frac{1}{2} 0, \\frac{1}{2} \\frac{1}{2} 1, \\frac{1}{2} \\frac{1}{2}, \\frac{0}{2} \\frac{1}{2}, \\frac{1}{2} 0 \\frac{1}{2}, and \\frac{1}{2} 1 \\frac{1}{2}.\nAnd, finally, the titanium ion resides at the center of the cubic unit cell, with coordinates \\frac{1}{2} \\frac{1}{2} \\frac{1}{2}.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列出钙钛矿晶体结构单元中钛、钡和氧离子的点坐标，答案以文字描述和坐标形式给出，不需要计算或选择，属于简答题类型。 | 知识层次: 题目主要考查对钙钛矿晶体结构中各离子位置坐标的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆钙钛矿晶体结构中钛、钡、氧离子的具体坐标位置，但这些都是基础概念的记忆性知识，不需要复杂的推理或分析。题目提供了明确的离子位置描述和坐标，只需正确识别和匹配即可。相比等级1的基本定义简答，此题需要记忆多个离子的具体坐标，但不需要深入理解或应用这些知识，因此属于等级2。" + }, + { + "idx": 17, + "question": "Write the coordinates of all nodes on the unit parallelepiped of the face-centered cubic lattice.", + "answer": "All nodes on the unit parallelepiped of the face-centered cubic lattice are: (000), (001), (100), (101), (110), (010), (011), (111), (1/2 0 1/2), (0 1/2 1/2), (1/2 1/2 0), (1 1/2 1/2), (1/2 1 1/2).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求写出面心立方晶格单位平行六面体上所有节点的坐标，答案需要列举具体的坐标点，属于需要文字解释和列举的简答题类型。 | 知识层次: 题目考查对面心立方晶格单位平行六面体节点坐标的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求记忆面心立方晶格单位平行六面体上所有节点的坐标，但需要掌握面心立方晶格的基本结构和节点分布规律。解题步骤相对简单，只需根据面心立方晶格的定义和对称性列举出所有节点坐标即可。然而，由于涉及多个坐标点的记忆和分类，对基础概念的记忆和理解有一定要求，因此难度略高于基本定义简答。" + }, + { + "idx": 1902, + "question": "What are the main mass transfer mechanisms in liquid phase sintering?", + "answer": "(30) Flow mass transfer; (31) Dissolution-precipitation mass transfer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释液相烧结中的主要传质机制，答案提供了两种机制的简要描述，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查液相烧结中主要传质机制的基本概念记忆和理解，属于定义和分类等记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生准确区分和识别液相烧结中的两种主要传质机制（流动传质和溶解-沉淀传质）。这比单纯记忆单一概念的定义（等级1）要求更高，但不需要进行复杂的概念体系阐述或比较分析（等级3）。" + }, + { + "idx": 3159, + "question": "What type of alloy phase does CuZn belong to, and what are its structural characteristics?", + "answer": "CuZn is an electron compound, c13=3.12, with a body-centered cubic structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释CuZn合金相的类型及其结构特征，答案提供了详细的文字描述和结构特点，符合简答题的特征。 | 知识层次: 题目考查合金相的基本分类和结构特征的记忆，属于基础概念的记忆和理解层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及合金相的类型和结构特征，但正确选项直接提供了CuZn的电子化合物类型、c13值和体心立方结构，这些信息属于基础概念记忆范畴。考生需要掌握电子化合物的定义和体心立方结构的基本特征，但不需要进行复杂的分析或推理。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4891, + "question": "Cite several limitations of fiberglass-reinforced composites.", + "answer": "Several limitations of these composites are: (1) care must be exercised in handling the fibers inasmuch as they are susceptible to surface damage; (2) they are lacking in stiffness in comparison to other fibrous composites; and (3) they are limited as to maximum temperature use.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举纤维增强复合材料的几个局限性，答案以文字解释和论述的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目考查对纤维增强复合材料局限性的基本记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举纤维增强复合材料的几个局限性，但正确选项已经提供了明确的三个具体限制条件。考生需要理解并记忆这些基本概念，但不需要进行复杂的分析或比较。这属于概念解释和描述的层次，比简单的定义记忆稍难，但比需要阐述复杂概念体系的题目要简单。" + }, + { + "idx": 3501, + "question": "What is the main difference between cast iron and carbon steel?", + "answer": "The main difference between carbon steel and cast iron lies in the carbon content and the form of carbon present. The carbon content in cast iron is greater than 2.11%, while that in carbon steel is greater than 0.0218% but less than 2.11%. In carbon steel, apart from a portion dissolved in ferrite, all other carbon exists in the form of Fe3C. In cast iron, a small amount of carbon is dissolved in ferrite, while most of the carbon exists in the form of graphite (gray cast iron) or Fe3C (white cast iron). The microstructure is not entirely the same, leading to differences in properties (both processing and service performance).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释cast iron和carbon steel的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对碳钢和铸铁的基本区别的记忆和理解，主要涉及碳含量和碳的存在形式等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分两种材料（铸铁和碳钢）在碳含量和碳存在形式上的差异。正确选项提供了较为详细的解释，包括碳含量的具体范围、碳的存在形式（Fe3C或石墨）以及由此导致的性能差异。这要求考生不仅记住定义，还要能够理解和比较这些概念。因此，在选择题型内，该题目属于等级2（概念解释和描述）难度。" + }, + { + "idx": 4384, + "question": "For Low Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: nonresponsive to heat treatments; relatively soft and weak; machinable and weldable. Typical applications: automobile bodies, structural shapes, pipelines, buildings, bridges, and tin cans.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述低碳钢的性质和典型应用，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对低碳钢的基本性质和典型应用的记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述低碳钢的性质和典型应用，但正确选项已经提供了明确的答案，学生只需识别和匹配这些信息。这需要学生对低碳钢的基本性质和应用有一定的记忆和理解，但不需要进行复杂的分析或推理。因此，难度等级为2，属于概念解释和描述的层次。" + }, + { + "idx": 892, + "question": "Term explanation: Burgers vector", + "answer": "An important vector describing the characteristics of a dislocation, which comprehensively reflects the magnitude and direction of the total distortion within the dislocation region; it also represents the amount of relative sliding of the crystal after the dislocation has swept through.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语\"Burgers vector\"进行解释，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对Burgers vector这一基本概念的定义和特性的记忆和理解，属于材料科学中位错理论的基础知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释Burgers vector的定义和特性，虽然涉及一定的专业术语和概念，但整体上属于对基础概念的记忆和理解，不需要复杂的分析或比较。正确选项提供了较为全面的解释，但并未涉及多个概念的交叉或复杂体系阐述。" + }, + { + "idx": 502, + "question": "Configuration of polymer chains", + "answer": "Configuration of polymer chains: The spatial geometric arrangement of atoms in polymers fixed by chemical bonds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Configuration of polymer chains\"进行文字解释和论述，答案提供了概念的定义和说明，符合简答题的特征 | 知识层次: 题目考查聚合物链构型的定义，属于基础概念的记忆和理解，不涉及应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别聚合物链构型的定义，属于基础概念的直接回忆。题目没有涉及复杂的概念体系或需要多步骤的分析过程，因此属于最低难度等级。" + }, + { + "idx": 4425, + "question": "Name two thermal properties of a liquid medium that will influence its quenching effectiveness.", + "answer": "The two thermal properties of a liquid medium that influence its quenching effectiveness are thermal conductivity and heat capacity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举并解释液体介质的两个热性能，答案以文字解释的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对液体介质热性能的基本概念记忆，仅需列举影响淬火效果的两个热性能参数，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅要求回忆并列举两个基本的热性能属性（热导率和热容量），属于基础概念记忆层次。题目不涉及解释或比较，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 558, + "question": "What are the factors affecting atomic diffusion in crystalline solids? Briefly explain the influence of temperature.", + "answer": "Temperature. The higher the temperature, the greater the diffusion coefficient and the faster the diffusion rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释影响原子扩散的因素并简要说明温度的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查原子扩散影响因素的基础概念记忆，特别是温度对扩散系数和扩散速率影响的基本原理理解，属于基础概念记忆和理解范畴。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆和识别影响原子扩散的因素（温度）及其基本影响（温度升高导致扩散系数增大和扩散速率加快）。不需要进行复杂的概念解释或体系阐述，解题步骤简单直接，仅需基础概念的记忆即可正确回答。" + }, + { + "idx": 430, + "question": "7. The typical ingot structure usually consists of (17)", + "answer": "Surface fine grain zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的结构名称（Surface fine grain zone），属于需要简短文字回答的题目类型，而不是从多个选项中选择或判断对错。 | 知识层次: 题目考查典型铸锭结构的基本组成部分，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对典型铸锭结构的基本组成部分的记忆，属于基础概念记忆层次。正确选项直接对应教材或课堂讲授的定义，无需复杂推理或概念间的比较分析，符合等级1“基本定义简答”的标准。" + }, + { + "idx": 1431, + "question": "The commonly used method to refine grains in casting processes is (19)", + "answer": "(19) Increasing the cooling rate", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个简短的具体答案（\"Increasing the cooling rate\"），而不是从多个选项中选择或判断对错，也不需要计算或详细论述。 | 知识层次: 题目考查的是铸造过程中细化晶粒的常用方法，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆并识别铸造过程中细化晶粒的常用方法。题目仅涉及单一知识点（冷却速率与晶粒尺寸的关系），无需复杂分析或概念比较，属于最基础的难度等级。" + }, + { + "idx": 563, + "question": "Briefly explain the disadvantages brought by the work hardening phenomenon", + "answer": "Disadvantages brought by the work hardening phenomenon: causes difficulty in plastic deformation. (3 points)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要解释工作硬化现象带来的缺点，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对work hardening现象带来的劣势的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆工作硬化现象的一个基本缺点（导致塑性变形困难），属于基础概念记忆层次，无需解释或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 602, + "question": "When a disordered solid solution transforms into an ordered solid solution, the general trend in the changes of alloy properties is that strength and hardness", + "answer": "increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释有序固溶体转变对合金性能的影响趋势，答案需要文字描述（increase），属于简答题类型。 | 知识层次: 题目考查对有序固溶体转变后合金性能变化的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需记住有序固溶体转变后强度和硬度的一般变化趋势即可作答。题目直接给出正确选项，无需复杂推理或概念比较，属于最基本的选择题难度。" + }, + { + "idx": 1663, + "question": "In a solid solution, when solute atoms and solvent atoms occupy fixed positions respectively, and the ratio of solute atoms to solvent atoms in each unit cell is constant, this ordered structure is called _ (6)—", + "answer": "(6) superlattice", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（superlattice）来补全句子，属于需要简短文字回答的题目类型。 | 知识层次: 题目考查对有序结构（超晶格）这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即\"超晶格\"（superlattice）的定义。题目直接描述了有序结构的特征，并提供了明确的正确选项，无需复杂分析或推理。属于最基础的定义简答类型。" + }, + { + "idx": 529, + "question": "1. Kaolinite belongs to the layered silicate structure, with one layer being (1) and another layer being (2).", + "answer": "(1) silicon-oxygen tetrahedral layer; (2) aluminum-oxygen octahedral layer", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定术语（硅氧四面体层和铝氧八面体层），属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查高岭石（Kaolinite）的层状硅酸盐结构的基本组成，即硅氧四面体层和铝氧八面体层的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即高岭石的层状硅酸盐结构由硅氧四面体层和铝氧八面体层组成。无需复杂推理或概念间的联系分析，属于最基本的知识点复现。" + }, + { + "idx": 1893, + "question": "Wetting is an important behavior at the solid-liquid interface, one of the methods to improve wetting is (18)", + "answer": "Changing surface roughness", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求提供一个简短但具体的答案（\"Changing surface roughness\"），而不是从多个选项中选择或进行判断或计算。这种形式更符合简答题的特征。 | 知识层次: 题目考查对润湿行为及其改善方法的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生记住改善润湿性的一种方法即可作答，无需进行复杂的概念解释或分析。题目直接给出了正确选项，且知识点较为单一，属于选择题中最简单的难度等级。" + }, + { + "idx": 1489, + "question": "Which hazardous substances are prohibited by the EU RoHS Directive (now enacted as a regulation) that came into effect on July 1, 2006? What are their maximum allowable concentrations?", + "answer": "Prohibited substances include lead (Pb, 0.1%), mercury (Hg, 0.1%), cadmium (Cd, 0.01%), hexavalent chromium (Cr+6, 0.1%), polybrominated biphenyls (PPB, 0.1%), and polybrominated diphenyl ethers (PBDE, 0.1%).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出欧盟RoHS指令禁止的有害物质及其最大允许浓度，需要文字解释和论述，而不是从选项中选择或判断对错。答案提供了详细的物质名称和浓度限制，符合简答题的特征。 | 知识层次: 题目考查对欧盟RoHS指令中禁止的有害物质及其最大允许浓度的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求记忆欧盟RoHS指令中禁止的有害物质及其最大允许浓度，这属于基础概念记忆的范畴。正确选项直接列出了具体的物质和对应的浓度限制，没有涉及复杂的概念解释或体系阐述。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1278, + "question": "What is the growth mode of crystals related to?", + "answer": "Interface structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体生长模式与什么相关，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查晶体生长模式与界面结构的关系，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，涉及晶体生长模式与界面结构关系的简单定义。题目仅要求识别正确选项\"Interface structure\"，无需复杂推理或多概念整合，属于最基本的知识点掌握要求。" + }, + { + "idx": 1247, + "question": "What is the movement of an edge dislocation perpendicular to the slip plane called?", + "answer": "Climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用一个特定的术语（\"Climb\"）来回答问题，而不是从多个选项中选择或判断对错，也不需要计算或公式应用。这符合简答题的特征，即需要简洁准确的回答。 | 知识层次: 题目考查对位错运动基本概念的记忆和理解，特别是边缘位错在垂直于滑移面方向上的运动名称。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即边缘位错垂直于滑移面运动的名称。正确选项\"Climb\"是材料科学中的基本术语，属于直接的定义性知识，无需复杂推理或概念关联。选择题型中此类直接考查定义的题目属于最低难度等级。" + }, + { + "idx": 1672, + "question": "Linear polymers can be reused and are called (19)__ plastics", + "answer": "(19) thermoplastic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（thermoplastic）来完成句子，属于需要提供简短文字答案的题型 | 知识层次: 题目考查对线性聚合物分类的基本概念记忆，仅需回答\"thermoplastic\"这一术语，属于基础概念的记忆性知识。 | 难度: 在选择题型中属于基础难度，仅需要记忆线性聚合物的基本分类术语\"thermoplastic\"这一单一知识点，无需解释或分析其他概念。题目直接考查基础定义记忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 413, + "question": "1. In the ionic crystal structure, the positive and negative ions form (1)", + "answer": "coordination polyhedron", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（coordination polyhedron）作为答案，而不是从多个选项中选择或判断对错，也不需要计算。这符合简答题的特征，即需要提供简短而具体的答案。 | 知识层次: 题目考查的是对离子晶体结构中正负离子排列方式的基本概念记忆，即配位多面体的定义，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需要考生回忆并识别\"coordination polyhedron\"这一专业术语的定义。题目直接考查对离子晶体结构中正负离子排列方式的基本概念，不需要进行任何解释或分析，属于最简单的记忆性知识考查。" + }, + { + "idx": 1506, + "question": "Compared with pure iron, how do the plasticity and toughness of ferrite change", + "answer": "Lower", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和比较纯铁和铁素体的塑性和韧性变化，需要文字论述而非简单选择或判断 | 知识层次: 题目考查的是对纯铁和铁素体塑性及韧性差异的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即纯铁与铁素体的塑性和韧性比较。题目仅要求选择正确选项\"Lower\"，无需解释或分析，属于最基本的知识点掌握深度要求。解题步骤极其简单，只需回忆相关定义即可作答，因此属于等级1难度。" + }, + { + "idx": 3454, + "question": "What are the types of heat-resistant steels?", + "answer": "Commonly used heat-resistant steels are roughly divided into three categories according to their microstructure in the normalized state: pearlitic steel, martensitic steel, and austenitic steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和列举热阻钢的类型，答案提供了详细的分类和说明，属于需要文字解释和论述的简答题。 | 知识层次: 题目考查对热阻钢分类的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求记忆和识别热阻钢的基本分类，属于基础概念记忆层次。题目直接给出了正确选项，无需进行复杂的概念比较或分析，解题步骤简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 3852, + "question": "For an Fe-1.15% C alloy, determine the primary microconstituent that forms.", + "answer": "primary Fe3C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求确定合金的主要微观组成物，答案需要给出具体的物质名称（primary Fe3C），属于需要简短文字回答的问题类型，而非选择、判断或计算。 | 知识层次: 题目考查对Fe-C合金相图中基本相组成的记忆和理解，只需根据给定的碳含量判断初生相为Fe3C，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即对Fe-1.15% C合金中主要微观组成相的定义性知识。学生只需记住该成分下会形成primary Fe3C即可作答，无需进行概念解释或复杂分析，属于最基础的定义简答型题目。" + }, + { + "idx": 1924, + "question": "Please explain what a perfect dislocation is", + "answer": "Perfect dislocation: The Burgers vector is an integer multiple of the lattice vector.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"perfect dislocation\"的概念，需要文字解释和论述，答案也是以文字形式给出的定义说明 | 知识层次: 题目考查对完美位错这一基本概念的定义记忆，属于材料科学中晶体缺陷的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别完美位错的基本定义（柏氏矢量是晶格矢量的整数倍）。这属于最基础的概念记忆题，不需要解释或分析过程，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4649, + "question": "What type(s) of bonding would be expected for tungsten?", + "answer": "For tungsten, the bonding is metallic since it is a metallic element from the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释钨的键合类型，需要文字解释和论述，而不是从选项中选择或判断对错，也不涉及数值计算。 | 知识层次: 题目考查对金属元素钨的键合类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别钨是金属元素并回忆其键合类型为金属键。题目不涉及复杂概念或分析步骤，属于最基础的定义简答级别。" + }, + { + "idx": 1198, + "question": "What kind of motion can an edge dislocation undergo?", + "answer": "Slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释边缘位错可以进行的运动类型，答案需要文字描述（\"Slip\"），属于需要简要文字解释的简答题类型。 | 知识层次: 题目考查位错运动类型的基础概念记忆，仅需回答\"滑移\"这一基本定义，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基本定义（edge dislocation的运动方式）的记忆，属于最基础的概念性知识，无需复杂分析或推理步骤。正确选项\"Slip\"是位错运动的标准术语，直接对应教材中的基础定义，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 538, + "question": "7. Small-angle grain boundaries are composed of dislocations, among which symmetric tilt boundaries are composed of (14) dislocations, and twist boundaries are composed of (15) dislocations.", + "answer": "(14) edge; (15) screw", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定类型的位错名称（刃型位错和螺型位错），属于需要准确回答特定术语的简答题形式。虽然形式上类似填空题，但根据提供的题型选项，最接近的是简答题类型。 | 知识层次: 题目考查对小角度晶界和位错类型的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接考察对对称倾斜晶界和扭转晶界组成位错类型的基础记忆，无需复杂推理或概念比较。正确选项直接对应基础概念记忆，属于最基础的选择题难度。" + }, + { + "idx": 1337, + "question": "Explain the temperature range and alias of the second type of temper brittleness", + "answer": "The brittleness that occurs when tempering between 450~650°C is called high-temperature temper brittleness, also known as the second type of temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释第二类回火脆性的温度范围和别名，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对第二类回火脆性的温度范围和别名的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆并识别\"第二类回火脆性\"的温度范围和别名，属于基础概念的直接回忆，无需复杂分析或推理步骤。正确选项直接提供了定义性信息，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4808, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for molybdenum.", + "answer": "for mo, 776°c or 1429°f.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答形式。 | 知识层次: 题目考查对特定材料（钼）的蠕变变形温度的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆特定材料（钼）的蠕变温度这一基础数据，属于单一事实性知识的直接回忆。不需要概念解释或复杂分析，完全符合等级1\"基本定义简答\"的标准。选择题型中此类直接考查记忆点的题目属于最低难度层级。" + }, + { + "idx": 3571, + "question": "From what kind of material would the temperature indicator be made?", + "answer": "The temperature indicator is made from bimetallic materials, which consist of two materials with different coefficients of thermal expansion bonded together.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释温度指示器的材料类型，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对温度指示器材料的基本概念记忆，仅需回答双金属材料的定义和基本原理，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对温度指示器材料的基本定义记忆，属于最基础的概念性知识。正确选项直接给出了明确的定义和组成材料，不需要任何解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 81, + "question": "Explain the meaning of the symbol V_{Cl}^*", + "answer": "Chlorine ion vacancy, with a single positive charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号V_{Cl}^*的含义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对缺陷化学符号的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目仅要求识别和记忆基础符号的定义（氯离子空位带一个正电荷），属于最基础的概念记忆层次。不需要解释或分析，只需直接回忆符号对应的定义即可，因此属于等级1的简单难度。" + }, + { + "idx": 48, + "question": "What are the structural characteristics of island silicates?", + "answer": "The structural characteristics of island silicates: [Si04] shares 0 O2-, the shape is tetrahedral, the complex anion group is [Si04], and the Si:O ratio is 1:4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释岛状硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对岛状硅酸盐结构特征的基本概念记忆和理解，包括[Si04]的共享氧离子数、形状、复杂阴离子团和Si:O比例等基础知识点，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目要求回答岛状硅酸盐的结构特征，正确选项直接给出了具体的结构特征描述，包括[Si04]的共享氧离子数量、形状、复杂阴离子基团以及Si:O比例。这些信息都是基础概念记忆层面的知识，不需要复杂的分析或推理，只需对定义和基本原理进行记忆即可回答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 86, + "question": "Explain the meaning of the symbol V_{Na}'", + "answer": "Sodium ion vacancy, with a single negative charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对材料科学中缺陷化学符号的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅要求识别并记忆基础符号的定义（钠离子空位带一个负电荷），属于最基础的概念记忆层次，无需解释或分析过程。" + }, + { + "idx": 1667, + "question": "The manner in which the crystal interface advances into the liquid phase during crystallization is called __（8）—, which is related to the microscopic structure of the liquid-solid interface", + "answer": "（8）crystal growth mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语（crystal growth mechanism）来完整描述结晶过程中晶体界面向液相推进的方式，属于需要简短文字回答的题目类型。 | 知识层次: 题目考查晶体生长机制这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接询问晶体生长过程中的特定术语（crystal growth mechanism），属于基础概念记忆的范畴，仅需考生回忆并识别正确的定义性术语即可，无需进行复杂的解释或分析。" + }, + { + "idx": 3511, + "question": "In the graphitization process of cast iron, if the first stage is completely graphitized and the second stage is not graphitized, what type of cast iron structure is obtained?", + "answer": "P+G (graphite)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要解释在铸铁石墨化过程中特定条件下的结构类型，答案以文字形式给出（P+G (graphite)），属于简答题类型 | 知识层次: 题目考查对铸铁石墨化过程的基础概念记忆，只需识别石墨化不同阶段的结果对应的铸铁结构类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对铸铁石墨化过程基础概念的记忆，即知道第一阶段完全石墨化和第二阶段未石墨化会得到P+G（石墨）结构的铸铁。不需要解释或分析复杂概念体系，只需识别正确选项即可。" + }, + { + "idx": 606, + "question": "In the Fe-Fe3C phase diagram, what carbon content is greater than that of cast iron?", + "answer": "2.11%C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（2.11%C），而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。虽然答案简短，但属于直接回答问题的简答题形式。 | 知识层次: 题目考查对Fe-Fe3C相图中关键点（2.11%C）的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆Fe-Fe3C相图中铸铁的碳含量临界值（2.11%C）这一单一知识点即可作答。题目不涉及概念解释或复杂体系分析，完全符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 1446, + "question": "For a screw dislocation line, what is the relationship between its cross-slip motion direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释螺丝位错线的交叉滑移运动方向与伯格斯矢量之间的关系，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对螺位错基本性质的理解，即其交叉滑移运动方向与Burgers向量的关系，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别螺位错线的交叉滑移运动方向与伯格斯矢量之间的基本关系（垂直）。这属于基础概念记忆层次，无需解释或分析，只需直接回忆定义即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 198, + "question": "From an atomic scale perspective, explain the differences in the bonding effects of welding", + "answer": "Welding: A process where two or more materials (of the same or different types) are permanently joined by heating, applying pressure, or both, to achieve atomic bonding. The conditions during welding include: base material type, plate thickness, groove shape, joint form, restraint state, ambient temperature and humidity, cleanliness, as well as the type and diameter of the welding wire (or electrode), welding current, voltage, welding speed, welding sequence, deposition method, and gun (or electrode) manipulation method determined based on the above factors. If the weld groove or surface has impurities such as oil (paint), water, or rust, they can cause defects like pores, inclusions, slag, or cracks in the weld, posing hazards and potential risks to the welded joint.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释焊接的键合效应差异，需要详细的文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求从原子尺度解释焊接的键合效应差异，涉及多因素综合分析（材料类型、工艺参数、环境条件等）及其对焊接质量的影响机制，需要深入理解原子键合原理并关联实际焊接条件，属于机理层面的复杂分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求从原子尺度解释焊接的键合效应，涉及复杂的机理分析和综合因素考量。正确选项不仅需要理解焊接的基本定义，还需要掌握多种影响因素（如材料类型、环境条件、工艺参数等）及其相互作用机制。此外，题目还要求分析杂质对焊接缺陷的影响机理，这需要深入的材料科学知识和工程实践经验。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最高难度级别。" + }, + { + "idx": 2170, + "question": "What is single slip? What are the characteristics of its slip lines?", + "answer": "Single slip refers to the slip occurring on only one slip system. The slip lines appear as a series of parallel straight lines. This is because in single slip, only one set of slip systems is active, where all slip planes are parallel to each other and the slip directions are identical.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"single slip\"及其滑移线特征进行文字解释和论述，答案提供了详细的定义和特征描述，符合简答题的特点。 | 知识层次: 题目考查对单滑移及其滑移线特征的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生不仅知道单滑移的定义，还要理解其滑移线的特征。正确选项中对单滑移的解释和滑移线特征的描述较为详细，要求考生具备一定的概念理解和描述能力，而不仅仅是简单的定义记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4396, + "question": "What is the principal difference between wrought and cast alloys?", + "answer": "The principal difference between wrought and cast alloys is as follows: wrought alloys are ductile enough so as to be hot or cold worked during fabrication, whereas cast alloys are brittle to the degree that shaping by deformation is not possible and they must be fabricated by casting.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述锻造合金和铸造合金的主要区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对锻造合金和铸造合金基本概念的记忆和理解，属于定义和分类的基础知识范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（定义和分类），但需要考生理解并区分两种合金类型的关键特性（可锻性和铸造性）。正确选项提供了明确的对比描述，但需要考生掌握\"wrought\"和\"cast\"这两个专业术语的含义以及它们在加工性能上的差异。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 1557, + "question": "10. First-order phase transition", + "answer": "A phase transition where the free energies of the old and new phases are equal before and after the transition, but their first-order partial derivatives are unequal.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"First-order phase transition\"进行文字解释和论述，答案是一个详细的定义描述，符合简答题的特征。 | 知识层次: 题目考查一级相变的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆一级相变的定义，即自由能在相变前后相等但一阶偏导数不等。虽然需要掌握一定的概念知识，但不需要复杂的分析或比较多个概念，因此属于中等难度。" + }, + { + "idx": 479, + "question": "7. What are the main structural types (subtypes) of silicate crystals?", + "answer": "Island, group (or ring), chain, layer, framework", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举硅酸盐晶体的主要结构类型，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对硅酸盐晶体主要结构类型的基本分类记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅要求考生回忆并选择硅酸盐晶体的主要结构类型（岛状、群状/环状、链状、层状、框架状）。在选择题型中，这类直接考察定义和分类的记忆性知识属于最简单的难度等级，不需要任何解释、分析或推理过程。" + }, + { + "idx": 2567, + "question": "If tension is applied along the [2 3] direction of an aluminum single crystal, determine the rotation law and rotation axis of the crystal during double slip.", + "answer": "During double slip, the specimen axis rotates towards [0 1], with the rotation axis n1=[1 1 2]×[0 1 1]=[1 1 1], and simultaneously rotates towards [101], with the rotation axis n2=[1 1 2]×[101]=[1 1 1]. The resultant rotation axis is [000], so the crystal no longer rotates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述双滑移过程中晶体的旋转规律和旋转轴，答案提供了详细的文字解释和推导过程，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求确定双滑移过程中晶体的旋转规律和旋转轴，涉及晶体学方向、滑移系统、旋转轴计算等复杂概念的综合运用和推理分析。需要理解双滑移机制，进行向量叉积计算，并解释最终的旋转行为，思维过程深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用晶体学、滑移系和旋转定律等复杂知识，进行多步骤推理分析。需要正确理解双滑移条件下的晶体旋转机制，计算两个滑移系的旋转轴，并推导最终合成旋转轴。这种深度机理解释和复杂现象分析在选择题中非常罕见，对学生的材料科学理论基础和空间思维能力要求极高。" + }, + { + "idx": 2111, + "question": "Point out the error in the following concept and correct it: In the Fe-Fe3C system alloys, only hypereutectoid steels have secondary cementite in their equilibrium crystallization structure.", + "answer": "Only when the iron-carbon alloy with a carbon mass fraction of 0.0077 < w_c < 0.043 undergoes equilibrium crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目要求识别并纠正Fe-Fe3C系统中关于二次渗碳体形成的错误概念，需要理解不同碳含量范围内合金的平衡结晶结构，并能够将这一概念应用到具体情境中。这涉及到多步分析和概念关联，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解Fe-Fe3C相图的基本概念，还需要能够区分不同碳含量范围内的合金特性，并准确识别原陈述中的错误。解题过程涉及：" + }, + { + "idx": 422, + "question": "3. The factors influencing the formation of substitutional solid solutions include _ (7)", + "answer": "Crystal structure type", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举影响置换固溶体形成的因素，需要文字解释和论述，而不是从选项中选择或简单判断对错 | 知识层次: 题目考查的是对形成置换固溶体的影响因素之一（晶体结构类型）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"影响置换固溶体形成的因素包括晶体结构类型\"。题目仅要求识别正确选项，无需解释或分析，属于最基本的概念记忆层次。" + }, + { + "idx": 1499, + "question": "What is the reason for age hardening in Al-4.5%Cu alloy?", + "answer": "The reasons for age hardening are: first, when the precipitated metastable disk-shaped phase has a certain orientation relationship with the parent phase, it generates significant elastic strain in the matrix, which can markedly strengthen the alloy; second, when the alloy undergoes deformation, the interaction between dispersed particles and dislocations strengthens the alloy. If the precipitate particles are deformable, the work required to increase the surface energy of the particles when dislocations cut through them raises the resistance to dislocation motion, thereby strengthening the alloy. If the precipitate particles are strong and coherent with the matrix, the dislocation lines find it difficult to cut through the particles and will bypass them under applied stress, leaving dislocation loops. For the alloy to continue deforming, the stress exerted by the particles as the dislocation lines bypass them must be overcome, requiring further increase in the applied stress, meaning the alloy achieves age hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al-4.5%Cu合金时效硬化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释Al-4.5%Cu合金时效硬化的原因，涉及多个机理的综合分析，包括亚稳相与母相的取向关系、弹性应变、位错与析出粒子的相互作用等。需要深入理解材料科学中的相变、位错理论和强化机制，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解Al-4.5%Cu合金的时效硬化机理，包括亚稳相析出、弹性应变强化、位错与析出颗粒的相互作用等复杂概念。正确选项不仅需要掌握多个专业知识点，还需要将这些知识点综合运用来解释时效硬化的多重机制。此外，题目涉及位错切割颗粒和位错绕过颗粒两种不同情况下的强化机制，要求考生具备较强的推理分析和机理解释能力。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最难的一类。" + }, + { + "idx": 962, + "question": "Briefly describe the slip system", + "answer": "A slip system in a crystal refers to a combination of a slip plane and a slip direction on that plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述滑移系统的定义，答案以文字解释的形式给出，符合简答题的特征 | 知识层次: 题目考查对滑移系统这一基本概念的定义记忆和理解，属于材料科学中的基础知识点，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"滑移系统\"的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的定义复述，无需解释或比较多个概念，解题步骤极为简单，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 91, + "question": "Write the defect reaction equation for the formation of Frenkel defects (Ag entering interstitial sites) in AgI", + "answer": "AgAg $V_{Ag}$ $+Ag_{i}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出缺陷反应方程式，需要文字解释和论述，答案形式为化学方程式而非选择、判断或计算 | 知识层次: 题目考查对Frenkel缺陷形成的基本概念和反应方程的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求写出Frenkel缺陷的形成反应方程，属于基础概念记忆的范畴。题目直接给出了正确选项，不需要复杂的分析或推理，只需记住基本的缺陷反应方程即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 810, + "question": "What is the significance of strain hardening in production?", + "answer": "Strain hardening, also known as work hardening, can improve the strength and hardness of alloys. For example, cold-drawn steel wires are strengthened by utilizing the strain hardening effect. Especially for some alloys that cannot be strengthened by heat treatment, strain hardening is a very important strengthening method.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应变硬化的意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释应变硬化的定义（基础概念），还需要说明其在生产中的具体应用和重要性（概念关联和综合分析），涉及多步思维过程和对材料强化机制的理解。 | 难度: 在选择题中属于中等难度，题目要求理解应变硬化的概念及其在生产中的实际应用（如冷拔钢丝的强化），并需要将这一概念与合金强化方法（特别是无法通过热处理强化的合金）进行关联分析。虽然不涉及复杂计算，但需要综合理解和应用材料科学中的基本概念。" + }, + { + "idx": 2817, + "question": "What are the changes in properties of a Gu–30%Zn brass sheet after cold rolling?", + "answer": "After cold rolling, the strength and hardness of the brass sheet increase, while plasticity and toughness decrease, which is the phenomenon of work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷轧后黄铜板材性能的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释冷轧后黄铜板材性能的变化，涉及多个性能指标（强度、硬度、塑性、韧性）的综合分析，需要理解冷加工对材料性能的影响机制（加工硬化现象），属于中等应用层次的知识。 | 难度: 在选择题中属于中等难度，需要理解冷轧对黄铜板材性能的影响，包括强度、硬度、塑性和韧性的变化，并关联到加工硬化现象。虽然不需要多步计算，但需要对材料科学中的基本概念有较好的掌握，并能综合分析不同性能指标的变化趋势。" + }, + { + "idx": 334, + "question": "What is the main difference between recrystallization and crystallization?", + "answer": "Recrystallization is only a microstructural change without structural transformation, driven by deformation stored energy; crystallization is the process of forming crystals from amorphous liquid, gas, or solid states.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的主要区别，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对recrystallization和crystallization这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题中属于中等难度，题目要求区分两个相关但不同的概念（再结晶和结晶），需要理解各自的基本定义和驱动机制。虽然不涉及复杂的概念体系阐述，但需要准确记忆和比较两个过程的本质区别，属于概念解释和描述的层次。" + }, + { + "idx": 678, + "question": "How does the effect of solute elements on the melting point of alloys influence the diffusion coefficient?", + "answer": "Solute elements that can lower the melting point of alloys (or cause a decrease in the liquidus line) will increase the diffusion coefficient; conversely, they will decrease the diffusion coefficient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释溶质元素对合金熔点的影响如何影响扩散系数，答案提供了文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析溶质元素对合金熔点的影响如何进一步影响扩散系数，涉及多个概念的关联和机理解释，需要综合运用材料科学中的热力学和动力学知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4586, + "question": "What is another function that a transistor may perform in an electronic circuit?", + "answer": "In an electronic circuit, a transistor may act as a switching device in computers.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述晶体管在电子电路中的另一种功能，答案是一个简短的文字描述，没有提供选项或需要计算。 | 知识层次: 题目考查晶体管在电子电路中的基本功能，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆晶体管的基本功能之一（作为开关设备），属于最基础的定义性知识。题目不涉及概念解释或复杂体系，只需识别正确选项即可，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 627, + "question": "According to the solidification theory, analyze the characteristics of typical ingot structure", + "answer": "The typical ingot structure features fine equiaxed crystals in the outer layer, columnar crystals extending inward from the surface, and coarse equiaxed crystals in the center.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据凝固理论分析典型铸锭结构的特征，答案以文字解释和论述的形式呈现，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求根据凝固理论分析典型铸锭结构的特征，需要理解并应用凝固理论的基本原理，关联不同晶体结构的形成原因，并进行综合分析。这超出了单纯记忆基础概念的层次，但尚未达到复杂分析或高级综合的要求。 | 难度: 在选择题中属于中等难度，需要理解典型铸锭结构的三个主要特征（外层细等轴晶、中间柱状晶和中心粗等轴晶），并能将这些特征与凝固理论的基本原理联系起来。虽然不需要进行多步计算，但需要对凝固过程中的晶体生长机制有较好的理解，并能综合分析不同区域的晶体形态差异。" + }, + { + "idx": 1091, + "question": "What are the characteristics of the room temperature tensile curve of aluminum alloy?", + "answer": "Aluminum alloy does not exhibit a distinct yield point phenomenon.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述铝合金室温拉伸曲线的特征，答案提供了文字解释而非选择或判断 | 知识层次: 题目考查对铝合金室温拉伸曲线特性的基本概念记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对铝合金室温拉伸曲线特性的基础记忆性知识，正确选项直接给出了明确的特征描述（不表现明显屈服点现象），不需要进行概念解释或复杂分析。这属于最基本的概念记忆层次，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4537, + "question": "For a polymer-matrix fiber-reinforced composite, compare the desired mechanical characteristics of matrix and fiber phases.", + "answer": "The matrix phase must be ductile and is usually relatively soft, whereas the fiber phase must be stiff and strong.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较和描述聚合物基纤维增强复合材料中基体和纤维相的机械特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对聚合物基纤维增强复合材料中基体和纤维相所需机械性能的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和比较两种不同相（matrix和fiber）的机械特性，而不仅仅是简单的定义回忆。正确选项要求考生能够区分和描述matrix和fiber的机械特性，这比单纯记忆定义稍微复杂一些，但不需要复杂的分析或推理步骤。因此，难度等级为2。" + }, + { + "idx": 3301, + "question": "Compare the lattice shear during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "Pearlitic transformation involves no lattice shear, while bainitic transformation and martensitic transformation involve lattice shear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同相变过程中的晶格剪切进行比较和解释，答案以文字论述形式呈现，没有涉及计算或选择判断。 | 知识层次: 题目要求比较三种相变过程中的晶格剪切现象，涉及多个概念（bainitic、pearlitic、martensitic transformation）的关联和综合分析。虽然不涉及复杂计算，但需要对不同相变机制的理解和比较，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对三种不同的相变过程（贝氏体相变、珠光体相变和马氏体相变）的晶格剪切行为进行比较分析。这需要考生不仅掌握每种相变的基本概念，还需要理解晶格剪切在不同相变中的具体表现及其差异。此外，题目涉及的知识点较为深入，需要考生能够将多个概念关联起来进行综合分析，属于多角度分析论述的层次。因此，在选择题型内，该题目的难度等级为4。" + }, + { + "idx": 278, + "question": "Analyze the effect of mineralizers on solid-state reactions", + "answer": "The larger the lattice energy, the more complete and stable the structure, and the lower the reaction activity. Adding mineralizers can enhance solid-state reactions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析矿物化剂对固态反应的影响，答案提供了文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求分析矿化剂对固态反应的影响，涉及对反应机理的理解和解释，需要综合运用材料科学中的固态反应理论、晶体结构稳定性以及反应动力学等知识，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 171, + "question": "When Na2O is added to SiO2, making O/Si=2.5, is the crystallization ability enhanced or weakened?", + "answer": "Because O/Si increases, the viscosity decreases, and the crystallization ability is enhanced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释Na2O添加到SiO2中导致O/Si=2.5时结晶能力的变化，答案提供了文字解释和论述，说明粘度降低和结晶能力增强的原因，符合简答题的特征。 | 知识层次: 题目需要理解Na2O和SiO2的相互作用对O/Si比的影响，以及O/Si比变化对粘度和结晶能力的影响。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及Na2O和SiO2的反应，以及O/Si比例变化对粘度和结晶能力的影响。虽然题目给出了正确选项，但学生需要掌握相关概念（如O/Si比例、粘度与结晶能力的关系）才能正确选择。这需要一定的综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1838, + "question": "What factors does the concentration of component defects mainly depend on?", + "answer": "Solid solubility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释影响组分缺陷浓度的主要因素，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查的是对组分缺陷浓度主要依赖因素的基本概念记忆，即固溶度（solid solubility），属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，要求考生回忆\"组分缺陷浓度主要取决于什么\"这一简单定义。正确选项\"固溶度\"是材料科学中的基本术语，无需复杂推理或概念比较，属于最基础的定义简答级别。" + }, + { + "idx": 551, + "question": "6. The driving force for nucleation in solid-state phase transformation is (11), and the main resistances are (12) and (13).", + "answer": "(11) The difference in free energy between the new phase and the parent phase; (12) Interface energy; (13) Strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分的内容，答案需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查固态相变中成核的驱动力和主要阻力的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。虽然题目涉及多个概念（自由能差、界面能、应变能），但每个概念都是固态相变中的基础概念，且题目明确给出了正确选项，不需要进行复杂的比较分析。主要考察的是对基本概念的记忆和理解，属于中等偏下的难度水平。" + }, + { + "idx": 2230, + "question": "The tungsten filament in a light bulb operates at very high temperatures, leading to significant grain growth. When large grains spanning the filament form, the filament becomes brittle under certain conditions and may fracture due to stresses caused by thermal expansion during heating and cooling. Find a method to extend the lifespan of the tungsten filament.", + "answer": "Dispersed, particulate second phases (such as $\\\\mathrm{ThO}_{2}$) can be introduced into the tungsten filament to restrict grain growth. If the volume fraction of $\\\\mathrm{ThO}_{2}$ is $\\\\varphi$ and the radius is $r$, the limiting grain size $R = \\\\frac{4r}{3\\\\varphi(1+\\\\cos\\\\alpha)}$ (where $\\\\alpha$ is the contact angle). By selecting appropriate values of $\\\\varphi$ and $r$ to minimize $R$, grain growth can be effectively halted. Since grain refinement significantly reduces the brittleness of the filament, it becomes less prone to fracture, thereby effectively extending its lifespan.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求提出一个方法来延长钨丝寿命，并给出了详细的解释和公式应用，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求综合运用材料科学知识（如晶粒生长限制机制、第二相颗粒的作用）进行推理分析，解释如何通过控制第二相颗粒的参数（体积分数和半径）来优化钨丝性能，涉及多概念关联和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1994, + "question": "In the expression for calculating the force on dislocation motion, $f=\\tau b$, what does $\\tau$ refer to?", + "answer": "The resolved shear stress of the external force in the slip direction on the slip plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号$\\tau$的含义，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对位错运动中基本概念的记忆和理解，即τ的定义和物理意义，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆类型，仅需回忆并识别$\\tau$的定义。在选择题型中，这种直接考查定义的问题属于最简单的难度等级，不需要复杂的分析或推理步骤。" + }, + { + "idx": 1440, + "question": "What is the solid solution method of carbon in ferrite?", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释碳在铁素体中的固溶方式，答案需要文字描述（\"Interstitial\"），属于简答题类型。 | 知识层次: 题目考查的是碳在铁素体中的固溶方式这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即碳在铁素体中的固溶方式（间隙固溶）。题目仅要求识别正确术语\"Interstitial\"，无需解释或分析，属于最基本的知识点回忆，因此属于等级1难度。" + }, + { + "idx": 653, + "question": "Describe the main strengthening mechanisms that can be employed for industrial pure aluminum", + "answer": "The main strengthening mechanisms for industrial pure aluminum are work hardening and grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述工业纯铝的主要强化机制，需要文字解释和论述，答案也是以文字形式呈现的简要说明。 | 知识层次: 题目考查对工业纯铝主要强化机制的基础概念记忆和理解，涉及简单的分类和基本原理，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述强化机制，但在选择题的上下文中，正确选项已经提供了明确的答案（加工硬化和晶粒细化强化）。这需要考生对工业纯铝的基本强化机制有概念性的理解和记忆，但不需要进行复杂的分析或比较。题目考察的是对基础概念的掌握程度，属于\"概念解释和描述\"层次的知识。" + }, + { + "idx": 2468, + "question": "What are the similarities between polymer crystallization and metal crystallization in terms of the crystallization process?", + "answer": "Polymer crystallization and metal crystallization follow the general phase transition rules: 1 The crystallization process consists of nucleation and growth processes: (1) 1/2 Heterogeneous nucleation is dominant: (1-1) The kinetic equation has the same form as the Avrami equation: 4 Large undercooling results in small grain size. 5 The melting point of small particles is lower than that of large particles, exhibiting a Gibbs-Thomson-like effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释聚合物结晶和金属结晶在结晶过程中的相似之处，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较聚合物结晶和金属结晶过程的相似性，涉及多个概念（成核、生长、动力学方程、过冷度影响等）的关联和综合分析，需要理解并应用这些概念进行论述，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题中属于较高难度，题目要求考生对聚合物结晶和金属结晶的过程进行多角度分析，包括成核与生长过程、动力学方程形式、过冷度对晶粒尺寸的影响以及吉布斯-汤姆逊效应等多个方面的综合理解。需要考生具备较强的概念关联能力和综合分析能力，能够将不同知识点联系起来进行论述。" + }, + { + "idx": 228, + "question": "At this temperature, after prolonged holding to reach equilibrium, what is the phase composition of the system?", + "answer": "After prolonged holding at 1595°C, the system consists of liquid phase and A3S2, with L% = 21.8%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述系统在特定条件下的相组成，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求根据相图分析特定温度下的平衡相组成，需要理解相图的基本原理并应用相律进行计算，涉及多步分析和概念关联，但不需要复杂的机理推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解相平衡概念、温度对相组成的影响，并能将给定温度与相图关联起来进行综合分析。虽然题目提供了具体温度条件，但仍需考生掌握多步计算和概念关联能力才能正确解答。" + }, + { + "idx": 39, + "question": "Calculate whether the valence of O2- in CaTiO3 crystal is saturated?", + "answer": "In CaTiO3 crystal, the coordination number of Ca2+ CN=12, the coordination number of Ti4+ CN=6, and the coordination number of O2- CN=6, so CN ∑i(z+/CN)=2=|z−|, that is, the valence of O2- is saturated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来判断O2-在CaTiO3晶体中的价态是否饱和，答案提供了详细的解释和计算过程，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解晶体结构中离子的配位数和价态饱和的概念，并进行多步计算和综合分析，涉及多个知识点的关联和简单推理。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求计算O2-在CaTiO3晶体中的价态是否饱和，涉及多个离子的配位数计算和价态平衡的综合分析。虽然解题步骤较为明确，但需要掌握晶体化学中的配位数概念和价态平衡原理，并进行多步计算和概念关联。在选择题型中，这种题目要求考生具备一定的综合分析能力，但不需要进行多角度或深度关联性分析，因此属于等级3难度。" + }, + { + "idx": 460, + "question": "What effect does a smooth interface have on the crystal growth morphology?", + "answer": "For a smooth interface, under a positive temperature gradient, planar growth occurs. When the isothermal surface is not parallel to the crystal plane with the lowest surface energy, the interface divides into a series of small steps, and the growth process involves atoms adding to the steps. The small step surfaces are the crystal planes with the lowest surface energy. Under a negative temperature gradient, the crystal grows into polyhedrons with their own characteristics or faceted dendrites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释平滑界面对晶体生长形态的影响，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目涉及晶体生长形态的机理分析，需要综合理解平滑界面对晶体生长的影响，包括温度梯度、等温面与晶体平面的关系、生长过程中的原子添加机制等。这需要深入的分析和推理，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生综合运用晶体生长、界面能、温度梯度等多方面知识，并深入理解平滑界面对晶体生长形态影响的复杂机理。正确选项不仅涉及正负温度梯度下不同生长模式的对比分析，还需要解释台阶生长机制与最低表面能晶面的关系，体现了对复杂现象的全面分析能力。这种需要多维度知识整合和机理深度解释的题目，在选择题中属于最具挑战性的类型。" + }, + { + "idx": 3339, + "question": "Determine the heat treatment conditions (temperature, time, cooling rate, etc.) for φ25 hot-rolled eutectoid steel during annealing.", + "answer": "Annealing: hold at 760°C for 1h, furnace cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定热处理条件（温度、时间、冷却速率等），需要文字解释和论述，答案给出了具体的处理条件和方式，属于简答题类型。 | 知识层次: 题目要求确定热轧共析钢的退火热处理条件，涉及温度、时间和冷却速率等参数的选择。这需要理解退火工艺的基本原理，并能根据具体材料（φ25热轧共析钢）进行参数选择和调整。虽然有一定的记忆成分，但更多是需要将理论知识应用到具体情境中，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。该题目要求考生掌握热轧共析钢的退火热处理条件，包括温度、时间和冷却速率等参数。虽然题目给出了正确选项，但考生需要理解退火工艺的基本原理，并能将理论知识与实际应用相结合。此外，还需要对共析钢的相变温度有所了解，才能正确判断760°C的保温温度是否合适。这些要求使得该题目在选择题型中处于中等难度水平。" + }, + { + "idx": 1136, + "question": "Solid solution strengthening", + "answer": "Solid solution strengthening: When a solid solution is formed, the solvent lattice becomes distorted due to the dissolution of solute atoms. The stress field of the solute atoms interacts with dislocations, hindering their movement and increasing the resistance to dislocation motion. This results in a critical resolved shear stress much higher than that of pure metals, making the activation of slip systems more difficult compared to pure metals. Consequently, the material's resistance to plastic deformation increases, leading to higher hardness and strength, while plasticity and toughness decrease. This phenomenon is known as solid solution strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对“固溶强化”这一现象进行详细的文字解释和论述，答案提供了完整的定义、机制和影响，符合简答题的特征。 | 知识层次: 题目要求解释固溶强化的机理，涉及溶质原子与位错的相互作用、临界分切应力的变化以及对材料性能的影响等多个方面的综合分析。这需要深入理解材料科学中的位错理论和强化机制，并进行推理分析，属于复杂分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解固溶强化的基本概念，还需要深入掌握其微观机理（如晶格畸变、位错运动阻碍等），并能综合分析其对材料力学性能的影响（强度提高、塑性韧性下降）。这种需要同时运用材料科学原理和力学性能知识的综合分析题，在选择题型中属于最复杂的类型，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 744, + "question": "The basis for classifying silicate crystals is (6)", + "answer": "[ $\\mathrm{Si}0{4}$ connection method", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释硅酸盐晶体分类的基础，需要文字描述和论述，答案给出了具体的分类依据（[ $\\mathrm{Si}0{4}$ connection method），属于简答题类型 | 知识层次: 题目考查对硅酸盐晶体分类基础的记忆和理解，主要涉及硅氧四面体连接方式这一基本概念，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求考生记忆并识别硅酸盐晶体分类的基础依据（$\\mathrm{Si}0_{4}$连接方式），无需解释或分析概念关系，属于最基础的概念记忆性知识，且选项直接指向核心定义，解题步骤简单明确。" + }, + { + "idx": 873, + "question": "What is the Kirkendall effect", + "answer": "On an FCC-structured α-brass (Cu+30%Zn) rod, very fine molybdenum wires are applied as markers, and then copper is plated on the brass, enclosing the molybdenum wires between the brass and copper. Diffusion is carried out at a certain temperature. The molybdenum wires serve only as markers and do not participate in the diffusion throughout the experiment. The diffusing components are copper and zinc, which form a substitutional solid solution. During the diffusion process in a substitutional solid solution, the markers placed at the original interface move toward the direction of the lower melting point element, with the displacement distance following a parabolic relationship with time. The reason for this phenomenon is that the lower melting point component diffuses faster, while the higher melting point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应的现象和原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要详细描述实验过程、扩散机制以及不同元素扩散速率的差异如何导致标记物的移动。这涉及到对扩散现象的深入理解、不同元素扩散行为的比较分析以及实验现象的机理解释，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目不仅要求考生掌握Kirkendall效应的基本概念，还需要深入理解扩散机制、固溶体结构、标记物的作用以及不同元素扩散速率的差异。此外，题目涉及复杂的实验设计和现象解释，要求考生能够综合运用材料科学知识进行推理分析。这种深度和广度的知识要求，以及解题过程中的综合分析能力，使得该题目在选择题型中属于最高难度水平。" + }, + { + "idx": 855, + "question": "Explain one of the main mechanisms of alloy strengthening from a microstructural perspective: solid solution strengthening, and provide examples", + "answer": "Solid solution strengthening occurs when alloying atoms dissolved in the lattice interstices or lattice points, due to their different sizes compared to the matrix atoms, create stress fields that hinder dislocation movement. Examples include Cottrell atmospheres and Suzuki atmospheres. The former refers to interstitial atoms preferentially distributing in the tensile stress region of edge dislocations in BCC metals, pinning the dislocations. The latter involves alloying elements preferentially distributing in the stacking fault regions of extended dislocations in FCC metals, reducing stacking fault energy, expanding the stacking fault region, and making the slip of extended dislocations more difficult.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释合金强化的主要机制之一（固溶强化），并从微观结构角度进行说明，同时提供例子。答案需要详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从微观结构角度解释固溶强化的主要机制，并提供具体例子（如Cottrell和Suzuki气团）。这需要深入理解位错与溶质原子的相互作用、应力场分布以及不同晶体结构（BCC/FCC）中的强化机理，涉及多概念关联和机理解释，属于综合分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握合金强化的基本概念，还需要深入理解固溶强化的微观机制，包括位错与溶质原子的相互作用（如Cottrell气团和Suzuki气团的形成原理）。此外，题目还要求考生能够区分BCC和FCC金属中不同的强化机制，并解释其对位错运动的影响。这种题目需要考生具备扎实的材料科学基础和综合分析能力，能够将多个复杂概念联系起来进行推理分析，因此在选择题型中属于最高难度等级。" + }, + { + "idx": 1580, + "question": "9. Spinodal decomposition", + "answer": "A transformation in which a solid solution decomposes into two solid solutions with the same structure as the parent phase but different compositions through uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对Spinodal decomposition进行文字解释和论述，答案是一个详细的定义描述，符合简答题的特征 | 知识层次: 题目考查对Spinodal decomposition这一基础概念的定义和基本原理的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项需要对spinodal decomposition的定义和过程有较为清晰的理解，包括\"uphill diffusion\"这一关键概念。这超出了简单的定义记忆（等级1），需要一定的概念解释和描述能力（等级2），但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 2584, + "question": "In a simple cubic crystal, pure bending of the (010) plane around the [001] axis will form what type of dislocation (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[010]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求详细解释和论述晶体中位错类型、位错线方向和Burgers向量的关系，答案需要文字描述而非简单选择或判断 | 知识层次: 题目需要理解晶体结构、位错类型及其几何关系，涉及多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解晶体结构、位错类型、伯格斯矢量等概念，并进行综合分析。题目要求将纯弯曲变形与位错类型关联，并正确识别位错线方向和伯格斯矢量方向，涉及多步概念关联和空间想象能力。虽然题目给出了具体晶面和旋转轴，但仍需要较强的晶体学基础才能正确解答。" + }, + { + "idx": 2139, + "question": "Why is the carburizing temperature for steel parts generally chosen to be in the γ phase region?", + "answer": "Because the maximum carbon solubility (mass fraction) in α-Fe is only 0.0218%. For steel with a carbon mass fraction greater than 0.0218%, the carbon concentration gradient in the part during carburizing is zero, making carburizing impossible. Even for pure iron, carburizing in the α phase region results in a very small concentration gradient in the iron, and a high carbon layer cannot be obtained on the surface. Additionally, due to the low temperature, the diffusion coefficient is also very small, making the carburizing process extremely slow and practically meaningless. The carbon solubility in γ-Fe is high, allowing a higher carbon concentration gradient on the surface during carburizing, which facilitates the carburizing process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么钢件的渗碳温度通常选择在γ相区，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要解释为什么钢的渗碳温度选择在γ相区，涉及碳在α-Fe和γ-Fe中的溶解度差异、浓度梯度、扩散系数等多个概念的综合分析，以及渗碳过程的机理解释。这需要深入理解相图、扩散原理和工艺参数选择之间的关系，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。题目不仅要求考生掌握γ相区和α相区碳溶解度的基本概念，还需要深入理解碳浓度梯度、扩散系数等复杂机理。正确选项涉及多个知识点的综合运用和推理分析，包括碳溶解度差异、浓度梯度对渗碳过程的影响、温度对扩散系数的作用等。此外，题目要求考生将这些因素整合起来，全面分析为何γ相区更适合渗碳工艺，这超出了单纯记忆的范畴，属于复杂现象的全面分析层次。在选择题型中，这种需要多维度推理和机理深度解释的题目属于最高难度级别。" + }, + { + "idx": 746, + "question": "After the interaction between water and clay, what can be formed around the clay colloidal particles as the distance increases: (8) what?", + "answer": "Firmly bound water", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个具体的术语而非从多个选项中选择或判断对错，也不涉及计算。 | 知识层次: 题目考查对粘土胶体颗粒周围水分子分布的基本概念记忆，特别是\"firmly bound water\"这一术语的定义和形成原理的理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即\"firmly bound water\"这一术语的定义。学生只需识别并回忆该特定概念即可作答，无需进行概念解释或复杂分析，属于最简单的记忆性知识考查。" + }, + { + "idx": 3395, + "question": "Why is Cr12MoV steel not stainless steel?", + "answer": "Because Cr is the main factor that makes steel corrosion-resistant. It can increase the electrode potential of steel. If its mass fraction is small (below 13 %), the electrode potential cannot be significantly increased, nor can a single-phase structure be formed, so the corrosion resistance of the steel cannot be significantly improved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么Cr12MoV钢不是不锈钢，答案提供了详细的文字解释和论述，涉及Cr含量对钢的耐腐蚀性能的影响，符合简答题的特征。 | 知识层次: 题目需要理解Cr在钢中的作用机制，并分析其含量对钢的耐腐蚀性能的影响。这涉及到多个概念的关联和综合分析，如Cr的质量分数、电极电位、单相结构形成等，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要理解Cr对钢的耐腐蚀性的影响机制，包括电极电位提升和单相结构形成的条件，并进行多角度分析论述。题目要求考生不仅掌握基本概念，还需要综合分析Cr含量与耐腐蚀性之间的关系，涉及较深层次的材料科学知识。" + }, + { + "idx": 1137, + "question": "According to the phase rule, what is the degree of freedom when the ternary system has the maximum number of equilibrium phases?", + "answer": "Zero", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求根据相律解释三元系统在最大平衡相数时的自由度，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对相律（phase rule）这一基本原理的记忆和理解，特别是关于自由度（degree of freedom）在特定条件下的直接应用。虽然涉及三元系统和最大平衡相数，但答案直接来源于相律的基本定义，不需要复杂的计算或综合分析。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目直接考察对相律基础概念的简单记忆，只需知道三元系统在最大平衡相数时的自由度为零即可选出正确选项，无需复杂推理或概念间的联系分析。" + }, + { + "idx": 1028, + "question": "Analyze the characteristics of grain boundaries from the perspective of their energy features", + "answer": "Energy features of grain boundaries: Atoms have higher energy and stronger activity compared to the grain interior. Characteristics of grain boundaries: (1) Grain boundary—distortion—grain boundary energy—transformation to a lower energy state—grain growth, grain boundary straightening—reduction in grain boundary area. (2) Hindering dislocation movement—increase in σb—grain refinement strengthening. (4) High grain boundary energy and complex structure—easily meeting the conditions for solid-state phase transformation—primary site for solid-state phase transformation. (5) Poor chemical stability—grain boundaries are prone to corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析晶界的能量特征及其相关特性，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求从能量特征的角度分析晶界的特性，涉及多个复杂概念的关联和综合分析，如晶界能、位错运动、固态相变条件等，需要深入理解和推理分析晶界的能量状态及其对材料性能的影响。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从能量特征的角度综合分析晶界的特性，涉及多个复杂概念和机理的深度解释（如晶界能量、位错运动阻碍、固态相变条件等）。正确选项包含5个不同维度的晶界特性分析，每个维度都需要对材料科学中的核心机理有深刻理解。考生需要同时掌握晶界结构、能量状态、力学性能影响、相变行为等多方面知识，并能将这些知识点相互关联形成系统认知。这种在选择题型内要求全面分析复杂现象并解释深层机理的题目，对学生的知识整合能力和高阶思维能力提出了极高要求。" + }, + { + "idx": 4283, + "question": "What is the difference between deformation by twinning and deformation by slip relative to final result?", + "answer": "Normally slip results in relatively large deformations, whereas only small deformations result for twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种变形方式的区别，答案需要文字论述而非选择、判断或计算。 | 知识层次: 题目考查变形孪生和滑移变形的基本概念及其最终结果的差异，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（变形孪生和滑移的区别），但需要考生理解并比较两种变形机制的最终结果差异。正确选项明确指出了两种机制在变形程度上的区别，这要求考生不仅要记住定义，还要能够区分和描述两者的特征。相比单纯记忆定义（等级1），这种比较性描述需要更深一层的概念理解，但尚未达到需要分析复杂概念体系的等级3难度。" + }, + { + "idx": 1724, + "question": "Combining the factors affecting the strength of metal materials, summarize the solid solution strengthening mechanism in the application of dislocation theory in materials science", + "answer": "The possible dislocation mechanisms of solid solution strengthening mainly include the pinning of dislocations by solute atom atmospheres, which increases the resistance to dislocation slip. Examples include the Cottrell atmosphere and Snoek atmosphere resulting from the elastic interaction between solute atoms and dislocations, as well as the Suzuki atmosphere arising from the interaction between solute atoms and extended dislocations, which increases the stacking fault width, making dislocation constriction and cross-slip more difficult. The segregation and short-range order formed by solute atoms raise the energy when dislocations pass through and disrupt these configurations, thereby increasing the resistance to dislocation motion. Additionally, the electrostatic interaction between solute atoms and dislocations generates resistance to dislocation slip, enhancing the material's strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求结合金属材料强度的影响因素，总结固溶强化机制在材料科学位错理论中的应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求结合金属材料强度的多种影响因素，运用位错理论来总结固溶强化机制。这需要深入理解位错与溶质原子之间的相互作用机制（如Cottrell atmosphere、Snoek atmosphere、Suzuki atmosphere等），并能够综合分析这些机制如何影响材料的强度。题目涉及多个复杂概念的关联和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用材料科学中的多个高级概念（如固溶强化机制、位错理论、Cottrell/Snoek/Suzuki atmosphere等），并需要深入理解这些机理之间的相互作用。正确选项不仅涉及多个专业术语的准确解释，还需要将这些概念串联起来形成完整的机理解释链。这种题目要求考生具备将理论知识应用于复杂现象分析的能力，远超简单记忆或基础理解的层次，属于选择题型中最具挑战性的综合推理分析类型。" + }, + { + "idx": 4244, + "question": "Briefly explain the concept of steady state as it applies to diffusion.", + "answer": "Steady-state diffusion is the situation wherein the rate of diffusion into a given system is just equal to the rate of diffusion out, such that there is no net accumulation or depletion of diffusing species--i.e., the diffusion flux is independent of time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释稳态扩散的概念，答案以文字解释和论述的形式呈现，没有涉及计算、选择或判断对错。 | 知识层次: 题目考查对稳态扩散这一基本概念的记忆和理解，不需要复杂的应用或分析，仅需解释其定义和基本原理。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释稳态扩散的概念，但正确选项已经提供了清晰的定义和关键特征（如扩散速率相等、无净积累、通量不随时间变化等）。这需要考生不仅记住定义，还要理解其背后的基本原理，但不需要进行复杂的分析或比较多个概念。因此，它属于概念解释和描述的难度等级。" + }, + { + "idx": 60, + "question": "What type of silicate structure does Mg3[Si4O10](OH)2 belong to?", + "answer": "Layered (double-chain)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Mg3[Si4O10](OH)2所属的硅酸盐结构类型，需要文字描述和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对硅酸盐结构分类的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（硅酸盐结构分类），但需要考生准确记忆并区分不同类型的硅酸盐结构（如层状、双链等）。相比等级1的直接定义简答，该题目要求考生对硅酸盐结构分类有更深入的理解和记忆，属于概念解释和描述层次的难度。" + }, + { + "idx": 379, + "question": "In the diamond structure, carbon is connected by (5) bonds, and the coordination number is (6).", + "answer": "(5) covalent; (6) 4", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写特定术语（covalent和4）来补全句子，属于需要简短文字回答的简答题类型，而非选择、判断或计算题。 | 知识层次: 题目考查金刚石结构中碳原子之间的键合类型和配位数的基本概念记忆，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对金刚石结构中碳原子键合类型和配位数的记忆性知识，无需复杂的概念解释或分析。正确选项直接对应基础概念记忆，解题步骤简单明了。" + }, + { + "idx": 527, + "question": "2. The symmetry elements of the internal structure of a crystal are (3), (4), and (5) in addition to c, Pλ, Ln, and Lin.", + "answer": "(3) Translation axis; (4) Glide plane; (5) Screw axis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体内部结构的对称元素，答案需要文字描述和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查晶体内部结构对称元素的基本概念记忆，包括平移轴、滑移面和螺旋轴等基础定义和分类，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确识别并匹配晶体内部结构的对称元素（如平移轴、滑移面和螺旋轴）的具体名称。这要求考生不仅记住这些定义，还需要理解它们的分类和基本原理，而不仅仅是简单的定义复述。因此，相较于仅需基本定义简答的等级1题目，该题的难度稍高，属于等级2。" + }, + { + "idx": 2744, + "question": "Indicate the close-packed plane of an ideal hexagonal close-packed crystal structure", + "answer": "The close-packed plane is {0001}", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出密排面，答案需要文字说明具体的晶面指数，属于需要简短文字回答的问题 | 知识层次: 题目考查对六方密堆积晶体结构中密排面的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对六方密堆积晶体结构密排面的基本定义记忆，属于最基础的概念性知识。正确选项直接给出了标准答案{0001}晶面，无需任何解释或推理过程，完全符合\"基础概念记忆\"层次的要求。在选择题难度谱系中，这属于最简单的等级1问题。" + }, + { + "idx": 3261, + "question": "What is superplasticity?", + "answer": "When metallic materials are stretched under certain conditions, their elongation can reach over 200%, or even exceed 1000%. This property is called superplasticity. During superplastic deformation, the true stress-true strain conforms to the relation: σT(εT,T)=C·ε̇T^m, where m is called the strain rate sensitivity constant. When m=0.3-0.8, the material can exhibit superplasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"superplasticity\"这一概念进行文字解释和论述，答案提供了详细的定义和相关公式说明，符合简答题的特征。 | 知识层次: 题目主要考查对超塑性这一基本概念的定义和简单描述，涉及记忆和理解层面，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆超塑性的定义及其基本特征，包括伸长率范围和应变速率敏感性常数的关系。虽然涉及一些公式和参数，但整体上仍属于对基础概念的描述，不需要复杂的分析或比较。" + }, + { + "idx": 4269, + "question": "Cite five factors that lead to scatter in measured material properties.", + "answer": "The five factors that lead to scatter in measured material properties are the following: (1) test method; (2) variation in specimen fabrication procedure; (3) operator bias; (4) apparatus calibration; and (5) material inhomogeneities and/or compositional differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举导致材料性能测量分散的五个因素，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对材料性能测量中导致数据分散的五个基本因素的记忆和列举，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目要求列举五个导致材料性能测量分散的因素，属于概念解释和描述层次。虽然需要记忆多个因素，但每个因素都是基础概念，不需要复杂的分析或比较。因此，难度属于中等（等级2）。" + }, + { + "idx": 3809, + "question": "Consider a Pb-35% Sn alloy. Determine if the alloy is hypoeutectic or hypereutectic.", + "answer": "hypoeutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过分析合金成分来判断其类型（hypoeutectic或hypereutectic），需要基于相图知识进行解释和论述，而不是简单的选择或计算。答案虽然简短，但需要理解合金成分与共晶点之间的关系。 | 知识层次: 题目考查对合金分类（hypoeutectic或hypereutectic）的基本概念记忆和理解，仅需根据给定的成分百分比与共晶点比较即可判断，无需复杂计算或分析。 | 难度: 在选择题型中，该题目仅需记忆Pb-Sn合金相图中35% Sn的组成位置相对于共晶点的关系，属于基础定义简答。无需解释或复杂分析，只需识别hypoeutectic的定义即可作答。" + }, + { + "idx": 4272, + "question": "For edge dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "edge dislocation--parallel", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述边缘位错中施加的剪切应力方向与位错线运动方向之间的关系，答案需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对刃位错基本概念的记忆和理解，只需要记住刃位错线运动方向与外加剪切应力方向的关系即可回答，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即刃位错中施加剪切应力方向与位错线运动方向的关系。题目直接给出正确选项\"parallel\"，无需任何解释或分析步骤，属于最简单的定义性知识考查。" + }, + { + "idx": 2521, + "question": "Discuss the significance of atomic radius in ionic crystals and its influencing factors, with examples provided.", + "answer": "For ionic crystals, the sizes of cations and anions are represented by ionic radii r+ and r-, respectively. Assuming that the same ion has the same radius in different ionic crystals, the ionic radius can be roughly determined. However, the ionic radius is only an approximate concept, as electrons cannot completely detach from the cation. Therefore, many ionic bonds have more or less covalent character. When this feature is particularly prominent, the significance of the ionic radius becomes less precise.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论离子晶体中原子半径的重要性及其影响因素，并提供例子。答案是一段详细的文字解释和论述，没有涉及选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求讨论离子晶体中原子半径的意义及其影响因素，并提供例子。这需要理解离子半径的概念，分析其在离子晶体中的重要性，以及影响离子半径的因素，如电子构型、配位数等。此外，还需要能够举例说明，这涉及到概念之间的关联和综合分析。虽然不涉及复杂的计算或创新设计，但需要一定的理解和应用能力，超出了单纯的基础概念记忆。 | 难度: 在选择题型内，该题目需要考生理解并分析离子晶体中原子半径的重要性及其影响因素，同时要求能够关联多个概念（如离子半径、共价特性等）进行综合论述。题目不仅涉及基础概念的记忆，还需要进行多角度分析，属于较高难度的选择题。" + }, + { + "idx": 508, + "question": "Can magnesium oxide and aluminum oxide (solute) form a continuous solid solution? Explain the reason.", + "answer": "They cannot form a continuous solid solution due to different crystal structures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释镁氧化物和铝氧化物是否能形成连续固溶体，并说明原因。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解固溶体的形成条件，并分析两种氧化物的晶体结构差异对固溶体形成的影响，涉及概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道镁氧化物和铝氧化物的晶体结构不同，还需要理解这一差异如何影响它们形成连续固溶体的能力。这涉及到对晶体结构和固溶体形成条件的综合理解，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 1286, + "question": "The negative sign of the diffusion flux indicates that diffusion proceeds from high concentration to low concentration, and the driving force for diffusion in this process is (20)", + "answer": "Chemical potential gradient (chemical force)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述扩散过程的驱动力，答案是一个概念性的解释（化学势梯度），而不是从多个选项中选择或进行数值计算。 | 知识层次: 题目考查扩散通量的负号含义以及扩散驱动力的基本概念，属于对基本原理的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生记住扩散过程的驱动力是化学势梯度（化学力）这一基本定义。题目直接给出明确选项，无需复杂推理或概念比较，属于最简单的记忆性知识考查。" + }, + { + "idx": 801, + "question": "What are the characteristics of various alloy strengthening methods?", + "answer": "Grain refinement strengthening, solid solution strengthening, multiphase strengthening, dispersion strengthening (age hardening), and work hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释各种合金强化方法的特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目考查对合金强化方法的基本概念和分类的记忆，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个合金强化方法的概念，但正确选项已经明确列出了五种主要的强化方法（晶粒细化强化、固溶强化、多相强化、弥散强化（时效硬化）和加工硬化），考生只需识别和记忆这些基本分类即可。不需要进行复杂的比较分析或深入的概念阐述，因此难度等级为2。" + }, + { + "idx": 2266, + "question": "Describe the characteristics of diffusionless phase transformation.", + "answer": "Diffusionless phase transformation has the following characteristics: (1) There is a shape change caused by uniform shear, resulting in a change in the crystal's external form. (2) Since the phase transformation process is diffusionless, the new phase and the parent phase have the same chemical composition. (3) There is a certain crystallographic orientation relationship between the parent phase and the new phase. (4) The phase boundary moves extremely fast, approaching the speed of sound.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述扩散less相变的特征，答案以文字解释和论述的形式呈现，没有选项、判断或计算要求。 | 知识层次: 题目要求描述扩散相变的特征，涉及对相变过程中晶体结构变化、化学成分保持、取向关系以及相界移动速度的理解和综合分析。虽然不涉及复杂计算，但需要将多个概念关联起来进行解释，属于中等应用层次。 | 难度: 在选择题型内，该题目属于较高难度。题目要求考生不仅理解扩散型相变的基本概念，还需要掌握扩散型相变与无扩散型相变的区别，并能综合分析无扩散型相变的多个特征（如形状变化、化学成分不变、晶体学取向关系、相界移动速度等）。这些知识点需要考生进行多角度分析和关联性思考，而不仅仅是简单的记忆或单一概念的应用。因此，该题目在选择题型中属于等级4的难度。" + }, + { + "idx": 1188, + "question": "Discuss the characteristics exhibited by solid solution alloys during the solidification process and explain the reasons?", + "answer": "During the crystallization of a solid solution, constitutional supercooling occurs, leading to the formation of a constitutionally supercooled zone ahead of the solid-liquid interface. If any small protrusion appears on the interface, it will extend into the constitutionally supercooled zone and continue to grow by obtaining supercooling. As a result, the interface cannot remain flat and stable, leading to the formation of dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论固溶体合金在凝固过程中的特性并解释原因，需要详细的文字解释和论述，符合简答题的特征。答案也提供了详细的解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求讨论固溶体合金在凝固过程中的特性并解释原因，涉及对凝固过程中成分过冷、固液界面稳定性以及枝晶形成机理的深入理解和分析。这需要综合运用材料科学中的相变理论、热力学和动力学知识，进行推理和解释，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解固溶体合金凝固过程中的复杂现象（如成分过冷、枝晶形成机理），并需要综合运用材料科学原理进行机理解释。正确选项涉及多步骤推理分析（从界面不稳定到枝晶形成的完整因果链），且需要掌握\"成分过冷区\"等专业概念之间的相互作用机制。这种在选择题中要求对复杂凝固现象进行全面机理分析的题目，远超过基础识记或简单应用层面，属于选择题型中最具挑战性的类型。" + }, + { + "idx": 3249, + "question": "Please design an experimental plan to measure the recrystallization activation energy of a metal sheet cold-rolled by 75%.", + "answer": "Subject the cold-rolled specimen to isothermal recrystallization at different temperatures, and for each recrystallization temperature, determine the time t required to achieve a certain recrystallized volume fraction x_V. Since the recrystallization rate of cold-deformed metal V_rec ∝ 1/t = A′ e^(-Q_R/RT), take the logarithm of both sides: ln(1/t) = ln A′ - Q_R/RT The relationship between ln(1/t) and 1/T is linear. Plot this line using experimental data, and the slope of the line can be used to determine the recrystallization activation energy Q_R.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求设计一个实验计划来测量金属薄板的再结晶活化能，答案提供了详细的实验步骤和理论依据，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求设计实验方案来测量金属板材的再结晶激活能，涉及多步实验设计、数据分析和机理解释。需要综合运用材料科学中的再结晶理论、动力学分析以及实验技能，进行推理分析和综合运用。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅理解金属再结晶的基本概念，还需要掌握实验设计、数据处理和机理分析的综合能力。具体体现在：" + }, + { + "idx": 767, + "question": "What are the differences between solid-phase sintering and liquid-phase sintering?", + "answer": "Due to the faster mass transfer rate by flow compared to diffusion, liquid-phase sintering has a higher densification rate and requires a lower sintering temperature. Additionally, the rate of the liquid-phase sintering process is also related to factors such as the amount of liquid phase, its properties (viscosity, surface tension, etc.), the wetting condition between the liquid and solid phases, and the solubility of the solid phase in the liquid phase. The factors influencing liquid-phase sintering are more complex than those in solid-phase sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述固相烧结和液相烧结之间的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较固相烧结和液相烧结的差异，并详细解释液相烧结的速率影响因素，涉及多个复杂因素的综合分析，如质量传输速率、液相性质、润湿条件和固相溶解度等。这需要深入理解烧结机理和综合运用相关知识进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3325, + "question": "What are the types and characteristics of temper brittleness?", + "answer": "There are mainly two types of temper brittleness, namely low-temperature temper brittleness and high-temperature temper brittleness. Low-temperature temper brittleness, also known as the first type of temper brittleness, occurs to varying degrees in almost all industrial steels and is independent of the cooling rate after tempering. Therefore, it is also called irreversible temper brittleness (i.e., it occurs whether cooled rapidly or slowly). High-temperature temper brittleness, also known as the second type of temper brittleness, is characterized by its occurrence only in steels with specific compositions. Whether temper brittleness occurs depends on the cooling rate after tempering, i.e., it appears with slow cooling after tempering but not with rapid cooling, hence it is also called reversible temper brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述回火脆性的类型和特征，答案提供了详细的文字解释和分类说明，符合简答题的特点。 | 知识层次: 题目主要考查对回火脆性的类型和特点的记忆和理解，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生理解和描述两种回火脆性的类型及其特点，涉及概念的解释和描述，但不需要复杂的比较分析或深入的概念体系阐述。因此，属于中等难度。" + }, + { + "idx": 2838, + "question": "A cross-slip system consists of one slip direction and two crystallographic planes containing this slip direction, such as the (101) [111] (110) in bcc crystals. Write down three other cross-slip systems of the same type for bcc crystals.", + "answer": "From the standard projection diagram of the cubic crystal system (001), it can be found that the other three cross-slip systems of the same type for bcc crystals are: (101) [111] (110), (011) [111] (110), (110) [111] (101).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求写出三个其他交叉滑移系统，需要文字解释和论述，而不是选择、判断或计算。答案也是以文字形式给出具体的滑移系统，符合简答题的特征。 | 知识层次: 题目要求学生在理解bcc晶体滑移系统的基础上，通过标准投影图找出其他相同类型的交叉滑移系统。这需要学生不仅记忆bcc晶体的滑移方向和晶面，还需要理解交叉滑移系统的构成原理，并进行一定的分析和应用。虽然不涉及复杂的计算或深度推理，但需要多步的概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握bcc晶体的交叉滑移系统，并能从标准投影图中识别出其他相同类型的交叉滑移系统。这需要考生具备一定的晶体学知识，能够理解滑移方向和晶面之间的关系，并能进行多步的分析和综合。虽然题目提供了部分提示（如标准投影图），但考生仍需具备一定的空间想象能力和综合分析能力才能正确解答。" + }, + { + "idx": 1761, + "question": "The reason why a base-centered lattice cannot exist in the cubic system is _(9)", + "answer": "If a base-centered lattice existed in the cubic system, the characteristic 4L3 symmetry of the cubic system would no longer exist, which does not conform to the symmetry characteristics of the cubic system", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在立方晶系中不能存在底心点阵，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释为什么底心立方晶系不存在，需要理解立方晶系的对称性特征（4L3对称性）以及底心晶格对对称性的影响。这涉及到对晶体学对称性和晶格类型的综合分析，需要推理和解释机理，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解立方晶系的基本对称性特征（4L3对称性），还需要进行复杂的推理分析，解释为什么底心点阵在立方晶系中无法存在。这涉及到对晶体学对称性原理的深度理解和综合运用，远超简单的记忆或概念辨析。正确选项的推导需要考生将对称性原理与点阵类型的具体限制相结合，属于复杂现象全面分析的范畴。" + }, + { + "idx": 833, + "question": "Explain the processes and characteristics of recovery, recrystallization, and grain growth when cold-deformed metal is heated.", + "answer": "When cold-deformed metal is heated, three processes occur sequentially: recovery, recrystallization, and grain growth. Their respective characteristics are as follows:\\n\\n(1) Characteristics of the recovery process\\n\\n① The microstructure does not change during recovery, and the elongated grains of the deformed state are still retained.\\n\\n② The recovery process completely eliminates the macroscopic (Type I) stresses caused by deformation and largely eliminates the microscopic (Type II) stresses.\\n\\n③ During recovery, the mechanical properties generally change little, with hardness and strength only slightly decreasing, plasticity slightly increasing, and certain physical properties changing significantly, such as resistivity decreasing markedly and density increasing.\\n\\n④ The stored energy from deformation is partially released during the recovery stage.\\n\\n(2) Characteristics of the recrystallization process\\n\\n① The microstructure changes, transforming from the elongated grains of cold deformation into new equiaxed grains.\\n\\n② The mechanical properties change drastically, with strength and hardness sharply decreasing and plasticity increasing, returning to the state before deformation.\\n\\n③ The stored energy from deformation is fully released during recrystallization, lattice distortions (Type III stresses) are eliminated, and dislocation density decreases.\\n\\n(3) Characteristics of the grain growth process\\n\\n① The grains grow larger.\\n\\n② It causes changes in some properties, such as decreases in strength, plasticity, and toughness.\\n\\n③ Along with grain growth, other structural changes occur, such as recrystallization texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释冷变形金属加热时的三个过程（回复、再结晶和晶粒长大）及其特征，答案提供了详细的文字描述和论述，符合简答题的特点。 | 知识层次: 题目要求解释冷变形金属加热时的三个过程（回复、再结晶和晶粒长大）及其特征，涉及多个知识点的综合运用和机理解释。需要深入理解每个过程的微观结构变化、力学性能变化以及能量释放等复杂机制，并进行综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用多个复杂概念（恢复、再结晶和晶粒长大），深入理解这些过程的机理和特征，并进行全面的推理分析。正确选项详细描述了每个过程的微观结构变化、力学性能变化、应力消除和能量释放等关键特征，需要考生具备扎实的材料科学基础和综合分析能力。这种深度和广度的知识要求在选择题型中属于最复杂的层次。" + }, + { + "idx": 3933, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for BeO.", + "answer": "For BeO, the ionic radii of the Mn2+ and Be2+ are 0.067 nm and 0.035 nm, respectively. Therefore, the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.067 nm - 0.035 nm) / 0.067 nm × 100 = 48%. This Δr% value is much larger than the ±15% range, and, therefore, BeO is not expected to experience any appreciable solubility in MnO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释BeO在MnO中的固溶度问题，需要文字论述和解释离子半径差异的影响，符合简答题的特征。 | 知识层次: 题目要求应用离子半径差异百分比的计算公式，并结合固溶体溶解度规则进行分析和解释。虽然计算本身简单，但需要理解离子半径差异对固溶体形成的影响，并进行综合分析判断。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求掌握离子半径的概念，还需要进行多步计算（计算离子半径百分比差异），并综合分析结果与溶解度规则（±15%范围）的关系。此外，题目还隐含了对固溶体形成条件的深入理解，需要将多个知识点关联起来才能正确解答。这种综合分析能力在选择题型中属于较高要求。" + }, + { + "idx": 3001, + "question": "What usually breaks first when a polymer material fractures under force?", + "answer": "Covalent bonds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释聚合物材料在受力断裂时首先断裂的化学键类型，需要文字解释和论述，而不是从选项中选择或简单判断对错。 | 知识层次: 题目考查聚合物材料断裂时共价键断裂的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅考察对聚合物材料断裂时最先断裂的化学键类型的基础记忆，属于最基本的概念性知识，无需解释或分析步骤。正确选项\"共价键\"是高分子材料断裂机理中的基础定义，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 952, + "question": "Briefly describe the crystallization process of steel with a carbon content of 0.25%", + "answer": "The liquid phase first solidifies into ferrite, and a peritectic reaction occurs at 1495°C to form γ-austenite; upon further cooling, the remaining liquid phase precipitates γ-austenite again, which then transforms into single-phase austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述钢的结晶过程，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求描述钢的结晶过程，涉及相变反应和温度变化，需要理解并关联多个概念（如铁素体、奥氏体、包晶反应等），并进行综合分析。虽然不涉及复杂计算，但需要对相图和相关转变有较深的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解钢的结晶过程、相变反应（如包晶反应）以及不同温度下的相组成变化。虽然题目提供了具体的碳含量和温度信息，但解题者仍需综合运用相图知识和相变原理来分析结晶过程，涉及多步概念关联和综合分析。" + }, + { + "idx": 4392, + "question": "Compare white and nodular cast irons with respect to composition and heat treatment.", + "answer": "White iron--2.5 to 4.0 wt% C and less than 1.0 wt% Si. No heat treatment; however, cooling is rapid during solidification. Nodular cast iron--2.5 to 4.0 wt% C, 1.0 to 3.0 wt% Si, and a small amount of Mg or Ce. A heat treatment at about 700°C may be necessary to produce a ferritic matrix.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种铸铁的成分和热处理方式，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种铸铁的成分和热处理工艺，涉及多个知识点的关联和综合分析，需要理解不同成分对材料性能的影响以及热处理工艺的选择依据，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解并比较两种铸铁的成分和热处理工艺，涉及多个概念的综合分析。虽然题目提供了具体数据，但考生仍需掌握相关知识才能正确理解和比较这些信息。" + }, + { + "idx": 174, + "question": "What is surface tension?", + "answer": "Surface tension: the surface constriction force acting perpendicularly on a unit length line segment or the work required to increase an object's surface area by one unit; σ= force/total length (N/m)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"surface tension\"进行文字解释和定义，答案提供了概念描述和公式说明，属于需要文字论述的简答题类型 | 知识层次: 题目考查表面张力的基本定义和单位，属于基础概念的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅考察对表面张力基本定义的记忆，属于最基础的概念性知识。正确选项直接给出了表面张力的定义和公式，不需要任何分析或推理过程，完全符合\"基本定义简答\"的难度等级特征。" + }, + { + "idx": 3446, + "question": "Since high-speed steel already has good red hardness, why is high-speed steel generally not used for die-casting molds, and why was the steel grade 3Cr2W8V developed?", + "answer": "Although high-speed steel has high hardness, high wear resistance, and red hardness, its toughness and thermal fatigue properties are inferior to those of 3Cr2W8V, so high-speed steel is not used for die-casting molds.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么高速钢不用于压铸模具以及3Cr2W8V钢种的开发原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅需要理解高速钢和3Cr2W8V钢的基本性能特点，还需要分析它们在特定应用场景（压铸模具）下的适用性差异，涉及材料性能的综合比较和实际应用中的权衡考量。这要求考生具备较高的综合分析能力和对材料性能与使用条件之间关系的深入理解。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解高速钢和3Cr2W8V钢的基本性能特点，还需要综合分析它们在韧性、热疲劳性能等方面的差异，并推理出材料选择背后的机理。这种题目需要考生具备深入的材料科学知识，能够对不同材料的性能进行对比分析，并理解材料选择背后的工程考量。在选择题型中，这种需要多维度综合分析和机理解释的题目属于最复杂的一类。" + }, + { + "idx": 968, + "question": "What is the structural model that constitutes a small-angle grain boundary?", + "answer": "The structural model of a small-angle grain boundary is the dislocation model, for example, a symmetric tilt grain boundary is described by a set of parallel edge dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释小角度晶界的结构模型，答案提供了详细的文字描述和例子，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对小角度晶界结构模型的基本概念记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 该题目在选择题型中属于中等难度。虽然考察的是基础概念记忆（小角度晶界的结构模型），但需要考生不仅记住\"位错模型\"这一关键词，还要理解对称倾侧晶界与平行刃位错之间的关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。选择题型中，正确选项提供了具体示例，降低了纯粹记忆的难度，但仍需一定概念理解能力。" + }, + { + "idx": 4225, + "question": "Explain why the properties of polycrystalline materials are most often isotropic.", + "answer": "Although each individual grain in a polycrystalline material may be anisotropic, if the grains have random orientations, then the solid aggregate of the many anisotropic grains will behave isotropically.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释多晶材料性质通常为各向同性的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释多晶材料各向同性的原因，需要理解晶粒的各向异性与多晶材料宏观各向同性之间的关系，涉及多个概念的关联和综合分析，思维深度较高。 | 难度: 在选择题型内属于最高难度等级，因为该题目要求考生：" + }, + { + "idx": 1306, + "question": "At room temperature, bending a lead plate makes it increasingly harder, but after some time, bending it again makes the lead plate as soft as it was initially. Why? Please explain this phenomenon.", + "answer": "At room temperature, bending a lead plate makes it increasingly harder due to work hardening, which increases the strength and hardness of the lead plate. After some time, because the melting point of lead is relatively low, recrystallization softening occurs at room temperature, causing its hardness to decrease again.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释一个现象，答案需要文字解释和论述，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目要求解释材料在变形后的硬度变化现象，涉及工作硬化和再结晶软化两个关键概念，需要理解这些现象的机理及其相互关系。此外，还需要结合铅的低熔点特性来解释室温下的再结晶行为，这需要较高的综合分析能力和对材料科学原理的深入理解。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解工作硬化和再结晶软化的基本概念，还需要综合运用这些知识来解释复杂现象。正确选项涉及多个步骤的推理分析，包括识别初始硬度增加的原因（工作硬化）和后续硬度恢复的原因（再结晶软化），并需要理解铅的低熔点特性如何影响室温下的再结晶过程。这种综合运用和深度机理解释的要求在选择题中属于最复杂的类型。" + }, + { + "idx": 4463, + "question": "Are thermal stresses introduced upon heating? Why or why not?", + "answer": "Yes, thermal stresses will be introduced because of thermal expansion upon heating for the same reason as for thermal contraction upon cooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目需要文字解释和论述，答案提供了详细的解释说明为什么加热会引入热应力，符合简答题的特征。 | 知识层次: 题目考查对热应力产生原因的基本概念记忆和理解，仅需解释热膨胀导致热应力的基本原理，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆（热应力与热膨胀的关系），但需要学生理解并解释\"加热时会产生热应力\"的原因，这比单纯记忆定义（等级1）要求更高。题目正确选项不仅陈述了现象，还通过类比冷却过程解释了原理，要求学生掌握概念间的关联性，但不需要进行复杂体系分析（等级3）。" + }, + { + "idx": 3316, + "question": "Describe the types of low-temperature tempered structures in steel, the conditions for obtaining them, their structural characteristics, and mechanical properties", + "answer": "Low-temperature tempering Tempered martensite 150-250°C High hardness, high wear resistance", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述低温回火钢结构的类型、获得条件、结构特征和机械性能，需要详细的文字解释和论述，而不是简单的选择、判断或计算。答案提供了简要的信息，但完整的回答需要更详细的描述。 | 知识层次: 题目要求描述低温回火组织的类型、获得条件、结构特征和力学性能，涉及多个知识点的关联和综合分析，需要理解不同条件对组织性能的影响，并进行一定程度的推理和解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握低溫回火钢的结构类型、获得条件、结构特征和机械性能，并能够将这些知识点关联起来。虽然题目提供了正确选项，但考生仍需具备一定的综合分析能力，才能准确匹配各个要素。" + }, + { + "idx": 3092, + "question": "What is the reinforcement mechanism of fiber-reinforced composites?", + "answer": "Fiber-reinforced composites are formed by combining high-strength, high-modulus continuous (long) fibers or discontinuous (short) fibers with a matrix (resin, metal, ceramic, etc.). When the composite material is subjected to force, the high-strength, high-modulus reinforcing fibers bear most of the load, while the matrix primarily acts as a medium to transfer and disperse the load.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释纤维增强复合材料的增强机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查纤维增强复合材料的基本增强机制，属于基本原理的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述纤维增强复合材料的增强机制，包括纤维和基体的作用。这比简单的定义记忆（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 2880, + "question": "How to distinguish between cold and hot working?", + "answer": "The recrystallization temperature is the dividing line between cold and hot working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何区分冷加工和热加工，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查冷加工和热加工的基本区分标准，即再结晶温度的概念，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅考察对基础定义的记忆，即区分冷热加工的分界线是再结晶温度。不需要解释或分析，只需识别正确选项。属于最基本的概念记忆题，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 3804, + "question": "Consider a Pb-15% Sn alloy. During solidification, determine the composition of the first solid to form.", + "answer": "8% Sn", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定合金凝固过程中第一个固体的成分，需要基于相图和合金凝固原理进行解释和论述，答案是一个具体的数值（8% Sn），但解答过程需要文字说明和理论支持。 | 知识层次: 题目需要理解相图的基本原理，并能够根据给定的合金成分在相图上确定初始凝固固相的成分。这涉及到多步的思维过程，包括理解相图、识别相关相区以及应用杠杆定律等概念。虽然不涉及复杂的计算或深度分析，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于中等难度，需要理解相图的基本概念（如液相线和固相线），并能根据给定的合金成分（Pb-15% Sn）在相图上定位，进而确定首先形成的固相成分（8% Sn）。这涉及到对二元相图的理解和应用，但不需要复杂的多步计算或深度关联性分析。" + }, + { + "idx": 3481, + "question": "Compare the properties of four alloy tool steels: 9SiCr, Cr12, 5CrMnMo, and W18Cr4V", + "answer": "
Steel gradeProperties
9SiCrHigh strength and high wear resistance
Cr12High strength and high wear resistance
5CrMnMoBest comprehensive mechanical properties
W18Cr4VHigh strength and high wear resistance
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较四种合金工具钢的性能，答案以表格形式呈现了每种钢的性能特点，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较四种合金工具钢的性能，需要理解每种钢的基本特性并进行综合分析。虽然不涉及复杂的计算或机理分析，但需要对不同材料的性能有一定的理解和关联，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生对四种合金工具钢（9SiCr、Cr12、5CrMnMo、W18Cr4V）的性能进行多角度比较和分析。虽然题目提供了正确选项，但考生需要具备较深的知识储备，能够理解并区分不同钢材的高强度、高耐磨性以及综合机械性能等特性。此外，题目涉及的知识层次为中等应用，要求考生进行多步计算、概念关联和综合分析，这在选择题型中属于较高难度的要求。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 2441, + "question": "What are the similarities between crystal texture and polymer texture in a broad sense?", + "answer": "In a broad sense, the textures of the two are similar.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对晶体织构和聚合物织构的相似性进行文字解释和论述，答案也是以文字形式给出的简要回答 | 知识层次: 题目考查对晶体织构和聚合物织构相似性的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目仅要求识别和记忆晶体纹理和聚合物纹理在广义上的相似性这一基本定义。题目属于基础概念记忆层次，不需要复杂的解释或分析，只需选择正确的陈述即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1145, + "question": "The unit of diffusion flux is (24)", + "answer": "(24)1/cm2·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写扩散通量的单位，需要提供具体的单位名称，属于简答题类型 | 知识层次: 题目考查扩散通量的单位这一基础概念的记忆，属于定义性知识的直接回忆，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即扩散通量的单位。题目直接给出正确选项，无需任何解释或复杂推理，属于最简单的记忆性知识考查。" + }, + { + "idx": 266, + "question": "What are the advantages, disadvantages, and applicable conditions of the Jander equation?", + "answer": "The Jander equation has good adaptability in the initial stage of the reaction, but the Jander model assumes that the cross-section of spherical particles remains unchanged. Therefore, it is only applicable to cases with low conversion rates in the initial stage of the reaction. Both equations are only applicable to stable diffusion conditions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Jander方程的优缺点和适用条件，答案提供了文字论述而非选择、判断或计算，符合简答题的特征。 | 知识层次: 题目要求分析Jander方程的优缺点和适用条件，涉及对模型假设的理解、适用范围的判断以及稳定扩散条件的综合分析。这需要将多个概念关联起来进行中等程度的分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题型中，该题目要求考生不仅要理解Jander方程的基本概念，还需要综合分析其优缺点和适用条件。题目涉及多个知识点的关联，包括方程在反应初期的适应性、球形颗粒横截面不变的假设限制，以及稳定扩散条件的适用范围。这些要求超出了简单的记忆或单一概念的应用，属于多角度分析论述的层次，因此难度等级为4。" + }, + { + "idx": 1095, + "question": "Cross-slip can enable multiple slip systems in crystals", + "answer": "Cross-slip is the process where a dislocation line transfers from one slip plane to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对交叉滑移现象进行解释，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对交叉滑移这一基本概念的定义和简单理解，属于基础概念记忆范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别交叉滑移的基本定义，属于基础概念记忆层次。题目直接给出了正确选项的定义，无需进行复杂的解释或分析，因此属于最简单的难度等级1。" + }, + { + "idx": 3226, + "question": "What are the practical applications of fracture toughness K_IC in mechanical design?", + "answer": "1. Given the working stress σ and the fracture toughness K_IC of the material, the maximum allowable crack size a_c in the workpiece can be estimated. 2. Given the crack size a and the working stress σ, the stress intensity factor K_I during operation can be determined to provide a theoretical basis for reasonable material selection. 3. Given K_IC and the existing crack size a, the maximum allowable stress σ can be determined. If the working stress is less than this stress, the crack will not propagate; otherwise, the crack will become unstable.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释断裂韧性K_IC在机械设计中的实际应用，答案提供了详细的文字解释和论述，没有涉及计算、选择或判断对错。 | 知识层次: 题目要求应用断裂韧性K_IC的概念来解决实际工程问题，涉及多步计算和概念关联，如估算最大允许裂纹尺寸、确定应力强度因子和最大允许应力等。这需要理解断裂力学的基本原理，并能将其应用于具体的设计场景，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及多个步骤的计算和概念关联，要求考生能够综合分析材料的工作应力、断裂韧性和裂纹尺寸之间的关系。虽然题目提供了具体的应用场景，但需要考生具备一定的材料力学知识基础，能够将理论知识与实际应用相结合。" + }, + { + "idx": 3515, + "question": "Compare the tensile strength of HT150 and annealed 20 steel", + "answer": "The tensile strength of 20 steel is much higher than that of HT150.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的拉伸强度，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的拉伸强度，需要理解HT150和20钢的基本性能特点，并能够分析退火处理对20钢性能的影响。这涉及到材料性能的综合分析和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解HT150和20 steel的力学性能特点，并进行比较分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了明确的结论，减少了推理的复杂性。" + }, + { + "idx": 219, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite mineral), compare the differences in thixotropy of the two slurries when the same amount of electrolyte is added.", + "answer": "Adding Na2CO3 basically has no effect on the thixotropy of the clay, while adding Na2SiO3 reduces the thixotropy of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆体触变性的影响，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对黏土浆体触变性的影响，涉及对电解质作用机理的理解和应用，需要综合分析不同电解质与黏土矿物之间的相互作用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握Na2CO3和Na2SiO3对粘土浆体触变性的影响，并能够区分两者之间的差异。虽然题目提供了正确选项，但考生仍需具备一定的材料科学知识，特别是关于电解质对粘土浆体性质的影响，以及触变性的概念。此外，题目还要求考生能够综合分析不同电解质的作用效果，这增加了题目的复杂性。" + }, + { + "idx": 1555, + "question": "8. Aging of aluminum alloys", + "answer": "After high-temperature solution treatment, aluminum alloys are rapidly cooled to form a supersaturated solid solution, followed by the precipitation of metastable phases during subsequent heating and holding processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对铝合金时效过程进行文字解释和论述，答案提供了详细的描述性回答，符合简答题的特征 | 知识层次: 题目涉及铝合金时效处理的多步过程（高温固溶处理、快速冷却、亚稳相析出），需要理解并关联多个概念（如过饱和固溶体、亚稳相形成等），属于中等应用层次。虽然不涉及复杂计算，但需要对时效机理有一定深度的理解。 | 难度: 在选择题中属于中等难度，题目涉及铝合金时效处理的多步过程（高温固溶处理、快速冷却、过饱和固溶体形成、亚稳相析出），需要考生理解并关联多个材料科学概念。虽然不需要多角度分析或深度关联性分析，但要求对铝合金热处理原理有较好的掌握，并能综合分析各步骤之间的逻辑关系。" + }, + { + "idx": 10, + "question": "What are the characteristics of hydrogen bonds?", + "answer": "A hydrogen bond is a bond formed between two atoms with relatively high electronegativity, and it possesses saturation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释氢键的特性，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查氢键的基本定义和特性，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆氢键的基本定义和特性，属于基础概念记忆层次。正确选项直接描述了氢键的形成条件和饱和性，无需复杂推理或概念间的比较分析。因此，在选择题型内属于基本定义简答的难度等级。" + }, + { + "idx": 2580, + "question": "Highly cold-rolled aluminum sheets will form a well-developed {001}<100> texture (cube texture) after high-temperature annealing. If such an aluminum sheet is deep-drawn into a cup, how many ears will be produced?", + "answer": "Eight ears will be produced during deep drawing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在深冲过程中会产生八个耳朵，需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解冷轧铝板在高温退火后形成的立方织构（{001}<100>）及其在深冲过程中的行为。虽然涉及基础概念（织构和深冲），但需要将织构与深冲过程中产生的耳数关联起来，进行一定的分析和应用。这需要多步思考和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 745, + "question": "In the face-centered cubic crystal structure, the close-packed plane is (7)", + "answer": "{111} plane", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的知识点（面心立方晶体结构中的密排面），答案是一个特定的晶体学平面（{111} plane），不需要计算或选择，属于简答题类型 | 知识层次: 题目考查面心立方晶体结构中密排面的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需考生记住面心立方晶体结构中密排面的晶面指数{111}即可作答。题目不涉及任何概念解释或复杂分析过程，完全基于对基本定义的直接回忆，因此属于最简单的难度等级1。" + }, + { + "idx": 1009, + "question": "What are the common characteristics of the two major types of ceramic crystalline phases?", + "answer": "(1) The bonding is primarily ionic, with a certain proportion of covalent bonding; (2) They have a definite composition that can be expressed by an exact chemical formula; (3) They exhibit typical non-metallic properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述陶瓷晶相的常见特征，答案以文字形式列出多个要点，符合简答题的特点。 | 知识层次: 题目考查陶瓷晶体相的基本特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及陶瓷晶体相的基本特性，但正确选项涵盖了多个关键点（离子键与共价键比例、确定化学式、非金属性质），需要考生对基础概念有一定的理解和记忆。不过，这些知识点属于材料科学中的基础内容，且选项之间没有复杂的逻辑关系或需要深入分析，因此难度等级为2。" + }, + { + "idx": 1026, + "question": "Analyze the effect of cold plastic deformation on the physical and chemical properties of alloys", + "answer": "(3) Physical and chemical properties: The changes are complex, mainly affecting electrical conductivity, thermal conductivity, chemical activity, chemical potential, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析冷塑性变形对合金物理和化学性质的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析冷塑性变形对合金物理和化学性质的影响，涉及多个性质（电导率、热导率、化学活性、化学势等）的综合分析，需要理解变形与性质变化之间的机理，并进行推理和解释。这超出了简单记忆或应用，属于复杂分析和综合运用的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 172, + "question": "Adding 50mol% Na2O to SiO2, can this ratio form a glass? Why?", + "answer": "Yes, it can form a glass. When 50mol% Na2O is added, although the continuous SiO network skeleton becomes relaxed, it still maintains a three-dimensional network structure, allowing the formation of a glass.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么50mol% Na2O添加到SiO2中可以形成玻璃，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解Na2O和SiO2在玻璃形成中的作用，并分析特定比例下网络结构的变化，涉及多步概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解玻璃形成的条件以及Na2O对SiO2网络结构的影响，并进行综合分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了关键分析步骤和结论，降低了答题的复杂程度。" + }, + { + "idx": 4153, + "question": "Match the type of light transmission with its description: Is impervious to light transmission.", + "answer": "An opaque material is impervious to light transmission.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求匹配光的传输类型与其描述，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断 | 知识层次: 题目考查对不透明材料基本定义和特性的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，此题仅要求识别并匹配基础定义（不透明材料的特性），属于最基础的概念记忆层面。题目直接给出定义描述，只需选择对应术语，无需任何分析或推理过程，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 457, + "question": "What effect does a smooth interface have on crystal growth modes?", + "answer": "For a smooth interface, lateral growth occurs, including two-dimensional nucleation growth and screw dislocation growth.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释平滑界面对晶体生长模式的影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及晶体生长模式的机理分析，需要理解平滑界面对生长模式的影响，并解释两种具体的生长机制（二维成核生长和螺旋位错生长）。这需要综合运用晶体生长理论，进行推理和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶体生长的基本概念，还需要掌握平滑界面对生长模式的具体影响机制（如二维成核生长和螺旋位错生长）。这需要综合运用材料科学、晶体学和界面科学的知识，进行复杂现象的全面分析和机理深度解释。正确选项涉及多个专业术语和生长模式的对比分析，远超选择题常见的记忆或简单应用层次，属于需要高阶思维和学科交叉能力的复杂分析题型。" + }, + { + "idx": 3448, + "question": "List several types of ledeburitic steel you are familiar with?", + "answer": "High-speed steel, Cr12, Cr12MoV, etc. all belong to ledeburitic steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列出几种熟悉的莱氏体钢类型，答案以文字形式列举具体例子，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对莱氏体钢（ledeburitic steel）分类的基本记忆，只需列举熟悉的类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅要求列举几种莱氏体钢的常见类型，属于基础概念记忆的范畴。正确选项直接提供了具体的钢种名称（如高速钢、Cr12、Cr12MoV等），无需复杂的分析或推理过程。题目仅测试学生对莱氏体钢分类的简单记忆能力，因此属于选择题型中最基础的难度等级。" + }, + { + "idx": 3407, + "question": "What measures can be taken to ensure the long-term dimensional stability of measuring tools?", + "answer": "The method of cold treatment after quenching can be adopted to reduce the amount of retained austenite and achieve long-term dimensional stability.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出措施来确保测量工具的长期尺寸稳定性，答案提供了具体的处理方法并进行了简要解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释如何通过冷处理来确保测量工具的长期尺寸稳定性，涉及热处理工艺的应用和材料微观组织的控制，需要理解奥氏体残留量对尺寸稳定性的影响，并进行综合分析。这属于中等应用层次，需要将多个概念关联起来并给出具体的工艺措施。 | 难度: 在选择题中属于中等难度，题目涉及热处理工艺中的冷处理概念及其对残余奥氏体的影响，需要考生理解材料科学中的相变原理和尺寸稳定性控制方法。虽然不涉及复杂计算，但要求将多个概念（淬火、冷处理、残余奥氏体、尺寸稳定性）进行关联分析才能正确作答。" + }, + { + "idx": 4689, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (d) Block poly(acrylonitrile-isoprene) copolymer; graft poly(chloroprene-isobutylene) copolymer", + "answer": "Yes, it is possible to decide for these two copolymers. The block poly(acrylonitrileisoprene) copolymer is more likely to crystallize than the graft poly(chloroprene-isobutylene) copolymer. Block copolymers crystallize more easily than graft ones.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物的结晶可能性进行比较和解释，需要文字论述和理由说明，而不是简单的选择或判断。答案也提供了详细的解释和原因，符合简答题的特征。 | 知识层次: 题目要求对不同类型共聚物的结晶能力进行比较和判断，需要理解共聚物结构（嵌段与接枝）对结晶行为的影响，并进行综合分析。这涉及多个概念的关联和中等程度的推理分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生能够区分不同类型的共聚物（嵌段共聚物和接枝共聚物）的结晶能力，并理解其背后的原因。虽然题目提供了明确的选项，但考生需要掌握共聚物结构对结晶性能的影响这一知识点，并进行综合分析才能正确选择。这涉及到中等应用层次的知识，包括多步计算、概念关联和综合分析。" + }, + { + "idx": 797, + "question": "What factors influence the formation of amorphous metals? Why", + "answer": "Viscosity of liquid metal: the higher the viscosity, the more difficult the atomic diffusion, making it easier to retain the liquid metal structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释影响非晶金属形成的因素，答案提供了文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目要求分析非晶金属形成的因素，并解释原因，涉及多因素的综合分析和机理解释，需要深入理解原子扩散、粘度等概念及其相互作用，属于复杂分析层次。 | 难度: 在选择题型中，该题目要求考生不仅理解基本概念（如粘度、原子扩散），还需要综合运用这些知识进行复杂现象的全面分析（粘度如何影响非晶态金属的形成）。正确选项涉及机理深度解释（粘度与原子扩散的关系及其对金属结构的影响），这超出了简单记忆或基础理解的范畴，属于选择题型中的高难度水平。" + }, + { + "idx": 825, + "question": "What are the main characteristics of the L-C sessile dislocation in FCC crystals? Including the dislocation name, Burgers vector, dislocation nature, formation method, and motion state.", + "answer": "L-C sessile dislocation (with multiple configurations); Burgers vector is for example—[110] 6; dislocation nature is screw-type, edge-type, mixed-type; formation method is obtained through Shockley partial dislocation synthesis (or dislocation reaction); motion state is immobile.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释L-C sessile dislocation的主要特征，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态。答案提供了详细的文字解释和论述，而不是从选项中选择或简单的对错判断，也不需要数值计算。 | 知识层次: 题目要求对L-C sessile dislocation的多个特征进行描述，包括Burgers vector、位错性质、形成方法和运动状态等，需要综合理解和应用多个相关概念，并进行一定的关联分析。虽然不涉及复杂的计算或深度推理，但需要将多个知识点整合起来回答，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅掌握L-C sessile dislocation的基本概念，还需要理解其多种配置、Burgers向量的具体例子、位错性质（包括螺型、刃型和混合型）、形成方法（如通过Shockley部分位错合成或位错反应）以及运动状态（不可移动）。这需要考生具备多角度分析的能力，能够将多个概念关联起来进行综合分析，属于较高难度的选择题。" + }, + { + "idx": 1535, + "question": "Recrystallization annealing", + "answer": "Recrystallization annealing: For plastically deformed metals, during the reheating process, when the temperature exceeds the recrystallization temperature, new grains with low defect density are formed, restoring properties such as strength to their pre-deformation levels, while the phase structure remains unchanged.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Recrystallization annealing\"进行文字解释和论述，答案提供了详细的定义和过程描述，符合简答题的特征。 | 知识层次: 题目考查对再结晶退火这一基本概念的记忆和理解，包括其定义、发生条件和效果，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（recrystallization annealing的定义和基本原理），但正确选项需要考生理解并描述一个相对完整的过程（包括温度条件、晶粒变化和性能恢复等），而不仅仅是简单的定义复述。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 333, + "question": "Give the basic conditions (driving force) for metal recrystallization.", + "answer": "There must be a certain amount of deformation stored energy and a certain temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出金属再结晶的基本条件（驱动力），答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查金属再结晶的基本条件，属于基本原理的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求记忆金属再结晶的基本条件（变形储存能量和一定温度），属于基础概念记忆层次，无需复杂分析或推理，因此属于最低难度等级。" + }, + { + "idx": 2059, + "question": "Point out the errors in the following concept and correct them: (8) During the crystallization of certain castings, due to the faster cooling rate, the homogeneous nucleation rate N1 increases, and the heterogeneous nucleation rate N2 also increases. Therefore, the total nucleation rate is N=N1+N2.", + "answer": "Then the total nucleation rate is N=N2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求指出并纠正关于结晶过程中成核速率的错误概念，涉及对均质成核和非均质成核的理解，以及它们在实际结晶过程中的相互作用。这需要学生不仅记住基本概念，还要能够应用这些概念来分析具体情境，并进行适当的修正。思维过程涉及多步分析和概念关联，但不需要复杂的机理推理或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 233, + "question": "Compare the characteristics of the eutectic point in ternary invariant points and write its equilibrium relationship", + "answer": "The eutectic point is a type of invariant point where several crystalline phases simultaneously precipitate from the melt upon cooling or melt together upon heating. The phase equilibrium relationship is L(E)⇄A+B+C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较三元不变点中共晶点的特性并写出其平衡关系，需要文字解释和论述，答案也以文字形式给出解释和公式。 | 知识层次: 题目考查对共晶点特性的基本概念记忆和简单理解，涉及相平衡关系的基本原理，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（定义、分类、基本原理等），但需要考生理解并描述三元共晶点的特征及其平衡关系，而不仅仅是简单的定义复述。题目要求考生能够将共晶点的概念扩展到三元体系，并写出具体的相平衡关系式，这比单纯记忆定义需要更深一层的理解和应用。因此，在选择题型中属于等级2的难度。" + }, + { + "idx": 2261, + "question": "Describe the precipitation sequence of Al-Cu alloy", + "answer": "The precipitation sequence of Al-Cu alloy is: GP zones → θ′′ metastable phase → θ′ metastable phase → θ phase (equilibrium phase)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述Al-Cu合金的析出序列，需要文字解释和论述，答案给出了详细的析出过程，符合简答题的特征。 | 知识层次: 题目考查Al-Cu合金的析出序列，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述Al-Cu合金的析出序列，但正确选项已经提供了完整的序列，学生只需记忆和理解这一序列即可。这涉及到基础概念的记忆和简单描述，不需要复杂的分析或比较。因此，在选择题型内，这属于等级2的难度。" + }, + { + "idx": 1411, + "question": "What type of diffusion does the homogenization of intracrystalline segregation during diffusion annealing belong to?", + "answer": "The homogenization of intracrystalline segregation during diffusion annealing belongs to interdiffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对扩散退火过程中晶内偏析的均匀化类型进行解释，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查扩散类型的基本概念记忆和理解，属于对基础分类知识的直接问答 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即对\"interdiffusion\"这一术语的定义和分类的直接回忆。题目不需要解释或描述概念，更不需要分析复杂概念体系，完全符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2070, + "question": "Point out the errors in the following concept and correct them: (11) In order to produce a batch of sand castings with significant thickness variations and require uniform grain size, it can be satisfied by merely adding nucleating agents in the process.", + "answer": "It can be satisfied by merely accelerating the cooling of thicker sections (such as adding chills) in the process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。答案也以文字形式给出，解释了如何通过加速较厚部分的冷却来满足要求。 | 知识层次: 题目要求识别并纠正关于铸造过程中晶粒尺寸控制的错误概念，需要理解晶粒尺寸控制的基本原理（如冷却速率的影响）以及如何在实际操作中应用这些原理（如使用冷却装置）。这涉及到多步思考和概念关联，但不需要复杂的综合分析或创新设计。 | 难度: 在选择题中属于中等难度，需要理解砂型铸造中晶粒尺寸均匀性的控制原理，并综合分析冷却速度与成核剂的作用机制。题目要求识别原概念的误区（仅靠成核剂无法解决厚度差异问题），并选择正确的工艺措施（加速厚壁部分冷却）。这涉及中等应用层次的知识关联和工艺综合分析能力，但不需要多角度或深度关联性分析。" + }, + { + "idx": 1348, + "question": "Briefly describe the fifth essential reason for the high hardness of martensite: the aging strengthening mechanism", + "answer": "After the formation of martensite, carbon and alloy element atoms diffuse and segregate or precipitate to dislocations or other crystal defects, pinning the dislocations and making them difficult to move, thereby increasing the hardness and strength of martensite through aging strengthening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述马氏体高硬度的第五个原因，答案是一段文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释马氏体高硬度的第五个重要原因——时效强化机制，涉及碳和合金元素原子的扩散、偏聚或析出，以及位错钉扎等复杂机理。这需要综合运用材料科学中的相变、扩散、位错理论等知识，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解马氏体高硬度的基本原因，还需要掌握时效强化机制的详细机理，包括碳和合金元素原子的扩散、偏聚或析出过程，以及这些过程如何钉扎位错并阻碍其运动。这需要考生具备综合运用材料科学知识的能力，能够进行复杂的推理分析和机理解释。此外，题目涉及的知识点较为深入，解题步骤复杂，对考生的理解深度和分析能力要求较高，因此在选择题型内属于复杂现象全面分析的难度等级。" + }, + { + "idx": 2192, + "question": "Why is the actual tensile strength of ceramics lower than the theoretical yield strength?", + "answer": "This is due to the unavoidable microscopic voids present during the sintering of ceramic powders. During cooling or thermal cycling, thermal stresses generate microcracks, and surface cracks caused by corrosion result in ceramics, unlike metals, having inherent microcracks. At the crack tip, severe stress concentration occurs. According to elastic mechanics estimates, the maximum stress at the crack tip has already reached the theoretical fracture strength or theoretical yield strength (because ceramic crystals have very few mobile dislocations, and dislocation motion is extremely difficult, so once the yield strength is reached, fracture occurs). Conversely, one can calculate the nominal stress at which the crystal fractures when the maximum stress at the crack tip equals the theoretical yield strength, and this value is extremely close to the actual measured tensile strength.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么陶瓷的实际拉伸强度低于理论屈服强度，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目需要综合运用弹性力学、陶瓷材料微观结构和断裂机理等多方面知识进行深入分析和解释，涉及复杂的应力集中和理论强度与实际强度差异的机理探讨。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解陶瓷材料的基本性能，还需要深入掌握微观结构缺陷（如微孔、微裂纹）对材料强度的影响机制。正确选项涉及复杂的应力集中分析、理论强度与实际强度的差异解释，以及陶瓷晶体中位错运动的特殊性。此外，解题过程需要综合运用弹性力学和材料科学知识进行推理分析，属于复杂现象的全面分析层次，远超一般选择题的概念记忆或简单应用要求。" + }, + { + "idx": 1355, + "question": "According to solidification theory, what is the fundamental principle of grain refinement through modification treatment?", + "answer": "Modification treatment. That is, adding a modifier to the molten metal before pouring to promote heterogeneous nucleation and increase the number of nuclei, thereby refining the grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述改性处理的基本原理，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对凝固理论中晶粒细化机理的理解和应用，需要将改性处理与异质形核、晶粒细化等概念关联起来，并进行综合分析。虽然涉及基本原理，但需要一定的概念关联和解释能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及固溶理论的基本原理，要求考生掌握晶粒细化的改性处理方法，并能够理解异质形核和晶核数量增加的概念。虽然题目没有涉及复杂的计算，但需要对相关概念进行综合分析和关联，因此在选择题型中属于中等难度。" + }, + { + "idx": 621, + "question": "Peritectoid reaction and eutectoid reaction", + "answer": "Peritectoid reaction and eutectoid reaction: The process in which two solid phases react to form one solid phase is called a peritectoid reaction, while the reaction in which one solid phase decomposes into two other solid phases is called a eutectoid reaction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对两个专业术语进行解释和论述，答案提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对相变反应的基本概念（包析反应和共析反应）的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个不同的反应类型（Peritectoid reaction和eutectoid reaction），但正确选项提供了明确的定义和区分，属于概念解释和描述的层次。学生需要理解并记忆这两种反应的基本定义和区别，但不需要进行复杂的分析或比较多个概念体系。因此，难度等级为2。" + }, + { + "idx": 4611, + "question": "Why does the magnitude of the saturation magnetization decrease with increasing temperature for ferromagnetic materials?", + "answer": "The saturation magnetization decreases with increasing temperature because the atomic thermal vibrational motions counteract the coupling forces between the adjacent atomic dipole moments, causing some magnetic dipole misalignment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行文字解释和论述，答案提供了详细的原理说明，符合简答题的特征 | 知识层次: 题目要求解释铁磁材料饱和磁化强度随温度升高而降低的机理，涉及原子热振动与磁偶极矩耦合作用的综合分析，需要理解温度对磁有序状态的影响机制，属于对物理过程的深入推理和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1927, + "question": "Please write the Burgers vector of the shortest unit dislocation in BCC crystals", + "answer": "BCC: a/2<111>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出BCC晶体中最短单位位错的Burgers矢量，答案需要特定的文字表述（a/2<111>），属于需要特定知识回答的简答题类型 | 知识层次: 题目考查BCC晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆BCC晶体中最短单位位错的Burgers矢量表达式a/2<111>，属于基础概念记忆层次。题目不涉及概念解释或复杂体系阐述，仅需直接回忆定义即可作答，因此属于最简单的难度等级1。" + }, + { + "idx": 4688, + "question": "For the following pairs of polymers, do the following: (1) State whether it is possible to determine whether one polymer is more likely to crystallize than the other; (2) if it is possible, note which is the more likely and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. (c) Network phenol-formaldehyde; linear and isotactic polystyrene", + "answer": "Yes, it is possible to decide for these two polymers. The linear and isotactic polystyrene is more likely to crystallize than network phenol-formaldehyde; network polymers rarely crystallize, whereas isotactic ones crystallize relatively easily.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对两种聚合物进行比较，并解释哪一种更容易结晶以及原因。这需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求学生不仅需要理解聚合物结晶的基本原理（如网络聚合物和线性等规聚合物的结晶能力差异），还需要应用这些知识对不同类型聚合物进行比较和分析。这涉及到多个概念的关联和综合分析，而不仅仅是简单的记忆或直接套用。 | 难度: 在选择题中属于中等难度，需要理解聚合物结晶的基本原理（如网络结构vs线性结构、等规性对结晶的影响），并能对两种不同类型的聚合物（网络酚醛树脂和线性等规聚苯乙烯）进行对比分析。虽然不需要多步计算，但要求考生能够关联多个材料科学概念并做出正确判断。" + }, + { + "idx": 4419, + "question": "Give the approximate temperature at which it is desirable to heat a 0.85 wt% C iron-carbon alloy during a full anneal heat treatment.", + "answer": "About 777°C (1430°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或进行复杂的计算。虽然答案是一个具体的数值，但题目本身没有提供选项或要求进行计算步骤，而是直接询问一个特定的知识点的具体数值，这更符合简答题的特征。 | 知识层次: 题目考查对铁碳合金相图中关键温度点的记忆，特别是全退火处理时的适宜温度，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆一个具体的温度数值（777°C），属于基础概念记忆层次。题目不涉及概念解释或复杂体系分析，仅需直接回忆教材或课程中给出的标准热处理温度，因此属于最低难度等级。" + }, + { + "idx": 3077, + "question": "In fiber-reinforced composites, the fibers with relatively good performance are mainly (1), (2), (3), (4).", + "answer": "(1)glass fiber; (2)carbon fiber; (3)boron fiber; (4)silicon carbide fiber", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举性能较好的纤维增强复合材料中的纤维类型，答案以列举的形式给出，不需要计算或判断对错，属于简答题类型。 | 知识层次: 题目主要考查对纤维增强复合材料中常用高性能纤维种类的记忆，属于基础概念和分类知识的范畴，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆纤维增强复合材料中性能较好的纤维类型，属于基础概念记忆的简单题目。题目提供了明确的选项，无需进行复杂的概念解释或比较分析，仅需识别和回忆相关知识即可。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3352, + "question": "In eutectoid steel, both pearlite and tempered martensite (assuming tempered at 400°C) are composed of ferrite and carbide. Why is the strength of tempered martensite higher than that of the strongest pearlite?", + "answer": "The morphology of ferrite and the number of internal defects differ between the two. In pearlite, the ferrite is lamellar with fewer crystal defects (dislocations, twins), whereas in tempered martensite, the ferrite is acicular, and the number of crystal defects is much higher due to quenching. The morphology and dispersion of carbides also differ. In pearlite, the carbides are lamellar with low dispersion, while in martensite, the carbides are fine particles with high dispersion. Thus, the strength of tempered martensite is higher than that of the strongest pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么回火马氏体的强度高于最强的珠光体，答案提供了详细的文字解释和论述，涉及两种组织的铁素体和碳化物的形态、缺陷数量等差异，符合简答题的特征。 | 知识层次: 题目要求解释两种不同微观组织（珠光体和回火马氏体）的强度差异，涉及晶体缺陷、碳化物形态和分散度等多个因素的对比分析。需要综合运用材料科学中的相变、强化机制等知识，进行深入的推理和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解珠光体和回火马氏体的基本组成（铁素体和碳化物），还需要深入分析两者在铁素体形态、晶体缺陷数量、碳化物形态和分散度等方面的差异。此外，题目涉及淬火和回火工艺对材料性能的影响，需要综合运用材料科学中的相变理论和强化机制知识进行推理分析。正确选项的解释涉及多个复杂概念的交叉对比，属于复杂现象全面分析的层次，因此在选择题型中属于最高难度。" + }, + { + "idx": 498, + "question": "What are the main characteristics of martensitic transformation in steel?", + "answer": "(1) Transformation characteristics: $\\textcircled{1}$ Diffusionless, neither Fe nor C atoms diffuse. (2 points) $\\textcircled{2}$ Coherent shear, with habit plane and orientation relationship between the new phase and parent phase. (2 points) $\\textcircled{3}$ Non-isothermal nature. (1 point) $\\textcircled{4}$ Incompleteness of martensitic transformation. (1 point)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释马氏体相变的主要特征，答案以文字形式详细列出了多个特征点，需要论述和解释，符合简答题的特点。 | 知识层次: 题目考查马氏体相变的主要特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念点（扩散性、共格剪切、非等温性、不完全性），但每个概念点都是基础定义和描述性的内容，不需要进行复杂的比较分析或推导。学生只需准确记忆并识别马氏体转变的主要特征即可作答。因此，该题目在选择题型内属于等级2（概念解释和描述）难度。" + }, + { + "idx": 1673, + "question": "Cross-linked polymers cannot be reused and are called (20)__ plastics", + "answer": "(20) thermosetting", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（thermosetting）来完成句子，这属于需要简短文字回答的类型，而不是从多个选项中选择或进行判断/计算 | 知识层次: 题目考查对交联聚合物分类的基础概念记忆，特别是热固性塑料的定义和特性，属于基础概念记忆性知识。 | 难度: 在选择题型中属于基础难度，仅需要记忆和识别\"thermosetting plastics\"这一基本定义即可作答，不涉及概念解释或复杂分析。题目直接考查学生对塑料分类的基础概念记忆，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 4548, + "question": "Demonstrate that at 25 C (298 K), (RT)/(nF) ln x = (0.0592)/(n) log x.", + "answer": "At 25 C (298 K), (RT)/(nF) ln x = (0.0592)/(n) log x. This gives units in volts since a volt is a J/C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来证明一个等式，答案提供了详细的推导和单位说明，符合简答题的特征。 | 知识层次: 题目要求将给定的公式在特定温度下进行转换和验证，涉及基本公式的应用和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题中属于简单难度，题目仅要求直接套用基本公式进行简单计算，无需复杂的分析或推理过程。正确选项已经提供了完整的公式和单位说明，考生只需确认其正确性即可。" + }, + { + "idx": 633, + "question": "Explain why solid solution alloys can grow in a dendritic manner under a positive temperature gradient during solidification, while pure metals cannot form dendritic crystals.", + "answer": "Due to solute redistribution causing constitutional supercooling, solid solution alloys can grow dendritically even under a positive temperature gradient during solidification; whereas pure metals require a negative temperature gradient to form dendritic crystals.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液合金在正温度梯度下为何会以枝晶方式生长，而纯金属则不能形成枝晶晶体，需要文字解释和论述。答案提供了详细的解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固溶体合金在正温度梯度下形成枝晶的机理，并对比纯金属的凝固行为。这需要综合运用溶质再分配、成分过冷等概念进行机理分析，涉及多个知识点的关联和深入理解，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 369, + "question": "How to represent the fiber texture?", + "answer": "The fiber texture is represented as .", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释如何表示纤维织构，答案提供了具体的表示方法，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对纤维织构表示方法的基本概念记忆，仅需回答标准表示符号，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆纤维织构的基本表示方法（），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释或分析步骤，因此属于最简单的难度等级。" + }, + { + "idx": 525, + "question": "What changes occur in the properties of metal after plastic deformation?", + "answer": "In terms of properties, cold-deformed metal will undergo work hardening, manifested as a significant increase in strength and a noticeable decrease in plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释金属在塑性变形后性质的变化，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查金属塑性变形后性能变化的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述金属塑性变形后的具体性能变化（如加工硬化、强度增加和塑性下降），而不仅仅是简单的定义或分类。这要求考生对相关概念有一定的理解和应用能力，但不需要进行复杂的体系阐述或比较分析。" + }, + { + "idx": 41, + "question": "According to the电价规则, when half of the tetrahedral interstitial sites are filled, what valency cations should be inserted into the interstitial sites, and provide an example to illustrate.", + "answer": "The ratio of cation to anion valency should be 1:1, such as ZnS.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释电价规则并举例说明，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解电价规则并应用到具体情境中，涉及多步推理和概念关联，如确定填隙位置与离子价态的关系，并举例说明。 | 难度: 在选择题中属于中等难度，题目要求理解电价规则并能够应用该规则进行多步计算和概念关联。需要综合分析填充一半四面体间隙位时阳离子的价态选择，并给出具体实例（如ZnS）来说明。虽然涉及多个概念和步骤，但在选择题型中通过选项可以辅助判断，因此难度适中。" + }, + { + "idx": 4415, + "question": "Give the approximate minimum temperature at which it is possible to austenitize a 0.76 wt% C iron-carbon alloy during a normalizing heat treatment.", + "answer": "At least 782°C (1440°F)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，不需要计算过程或选择选项，属于需要直接回答的简答题类型。 | 知识层次: 题目需要理解铁碳合金相图，并能够根据给定的碳含量（0.76 wt%）确定奥氏体化温度。这涉及到多步思维过程，包括相图的解读和具体温度点的确定，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铁碳相图的基本概念，能够定位共析点（0.76 wt% C）对应的奥氏体化温度，并知道正常化处理需要略高于相变温度。虽然不需要复杂计算，但需要将多个概念关联起来进行综合分析。" + }, + { + "idx": 3935, + "question": "Which of these elements would you expect to form a substitutional solid solution having complete solubility with copper? The elements are: Ni, O, H, Pt, Pd, Co, C, Zn, Ag, Al, Cr, Fe. The criteria for complete solubility are: 1) the difference in atomic radii between Cu and the other element must be less than ±15%, 2) the crystal structures must be the same, 3) the electronegativities must be similar, and 4) the valences should be the same, or nearly the same.", + "answer": "Ni, Pd, and Pt meet all of the criteria and thus form substitutional solid solutions having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求根据给定的标准（原子半径差异、晶体结构、电负性和价态）分析多个元素，并解释哪些元素满足所有条件形成完全固溶体。答案需要详细的文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目要求应用多个标准（原子半径差异、晶体结构、电负性、价态）来筛选元素，涉及多步分析和概念关联。虽然不涉及复杂计算，但需要对材料科学中的固溶体形成条件有较深入的理解和综合应用能力。 | 难度: 在选择题中属于较高难度，需要综合考虑多个因素（原子半径差异、晶体结构、电负性、价态）并进行多步分析。题目要求考生不仅掌握基本概念，还需要能够将这些概念关联起来，对不同元素进行系统性比较。此外，题目还涉及高温条件下的同素异形转变（Co和Fe），增加了分析的复杂性。虽然题目提供了明确的选择范围，但正确选项的确定需要深入理解和综合应用材料科学原理。" + }, + { + "idx": 3423, + "question": "Which commonly used alloying elements belong to the γ-phase expanding elements?", + "answer": "Nickel, manganese, cobalt, carbon, nitrogen, and copper expand the γ-phase region.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举γ相扩展元素，答案以文字形式给出具体元素名称，属于需要文字解释和论述的简答题类型 | 知识层次: 题目考查对γ-phase expanding elements的基本记忆和分类，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅需识别γ相扩展元素的基本分类。选择题型中只需从给定选项中识别正确元素组合，不涉及概念解释或复杂分析，属于最基础的定义识别难度等级。" + }, + { + "idx": 3391, + "question": "A batch of carbon tool steel workpieces were found to have insufficient hardness after quenching. It is estimated that either surface decarburization occurred or the cooling rate during quenching was too low. How to quickly determine the cause of the problem.", + "answer": "Metallographic examination.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来快速确定问题的原因，答案“Metallographic examination”是一个简短的解决方案描述，属于需要文字解释的简答题类型。 | 知识层次: 题目要求通过金相检验来快速确定硬度不足的原因，这需要将金相检验的基本原理与实际问题的分析相结合，属于中等应用层次。虽然金相检验本身是基础概念，但如何将其应用于具体问题的诊断需要一定的综合分析能力，涉及多步思考和概念关联。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及碳工具钢淬火后硬度不足的两个可能原因（表面脱碳或淬火冷却速率过低），要求考生通过金相检验快速确定原因。这需要考生具备材料科学基础知识，能够将金相检验方法与问题原因关联起来，并进行综合分析判断。虽然不需要多步计算，但需要概念关联和综合分析能力，因此在选择题型中属于等级3难度。" + }, + { + "idx": 3878, + "question": "Describe the complete heat treatment required to produce a quenched and tempered eutectoid steel having a tensile strength of at least 125,000 psi. Include appropriate temperatures.", + "answer": "Austenitize at approximately 750^{\\circ} C,\nQuench to below 130^{\\circ} C (the M_{\\gamma} temperature)\nTemper at 620^{\\circ} C or less.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述完整的热处理过程，包括适当的温度，答案以文字解释和具体温度参数的形式给出，符合简答题的特征。 | 知识层次: 题目要求描述完整的热处理工艺，包括具体的温度参数，涉及多步操作（奥氏体化、淬火、回火）的综合应用。需要理解不同温度对材料性能的影响，并能根据目标强度选择合适的工艺参数。虽然不涉及复杂的计算或深度机理分析，但需要对热处理工艺有较全面的理解和应用能力。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解热处理的基本概念（如奥氏体化、淬火、回火），还需要掌握具体的温度参数（如750°C、130°C、620°C）及其与材料性能（125,000 psi抗拉强度）的关联。此外，题目涉及多步计算和综合分析，考生需要将理论知识与实际应用相结合，才能正确选择答案。这种题目在选择题型中属于需要多角度分析和论述的类型，因此难度等级为4。" + }, + { + "idx": 2691, + "question": "The ionic radii of $\\\\mathrm{Al}^{3+}$ and $\\\\mathrm{O}^{2-}$ are $0.051\\\\mathrm{nm}$ and $0.132\\\\mathrm{nm}$ respectively. Determine the coordination number of $\\\\mathbf{Al}_{2}\\\\mathbf{O}_{3}$.", + "answer": "The ratio of the two ionic radii is $\\\\frac{0.051}{0.132}{=}0.386$. The coordination number (CN) of an ionic crystal depends on the ratio of the cation to anion radii. Referring to the table, when $\\\\frac{r_{+}}{r_{-}}$ is between $0.225\\\\sim0.414$, the CN is 4. The shape of the anion polyhedron is tetrahedral.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过计算离子半径比并参考表格数据来确定配位数，答案需要文字解释和论述，而非简单的选择或判断。 | 知识层次: 题目主要涉及离子半径比的计算和查表确定配位数，属于基本公式应用和直接套用已有知识，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用层次。题目要求考生根据给定的离子半径比值直接查表确定配位数，涉及的知识点较为基础，解题步骤简单直接，仅需进行简单的计算和查表操作。不需要复杂的推理或多步骤分析，因此难度较低。" + }, + { + "idx": 752, + "question": "As a result of what reason, 'compositional defects' are inevitably produced in the crystal structure?", + "answer": "Doping of non-equivalent ions", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释“compositional defects”产生的原因，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查的是对\"compositional defects\"产生原因的基础概念记忆和理解，只需要回答掺杂非等价离子这一基本原理即可，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接询问晶体结构中\"compositional defects\"产生的原因，正确选项\"Doping of non-equivalent ions\"是该缺陷的标准定义性答案，无需复杂推理或概念比较。学生只需记住基础概念即可作答，符合选择题型中最基础的知识记忆要求。" + }, + { + "idx": 4935, + "question": "Can a material have a positive index of refraction less than unity? Why or why not?", + "answer": "In order for a material to have an index of refraction less than unity, the velocity of light in the material (v) would necessarily have to be greater than the velocity of light in a vacuum . This is not possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么材料不能具有小于1的正折射率，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求对折射率小于1的物理可能性进行深入分析和解释，涉及光速在介质中的传播特性与真空光速的关系，需要综合运用电磁学理论和材料光学性质的知识进行推理和论证。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 402, + "question": "What are the main factors affecting grain boundary migration?", + "answer": "The main factors affecting grain boundary migration rate: 1 solute atoms; 2 second-phase particles; 3 temperature; 4 orientation of grains on both sides of the grain boundary.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响晶界迁移的主要因素，答案以文字解释和论述的形式呈现，没有提供选项或要求计算，符合简答题的特征。 | 知识层次: 题目考查对影响晶界迁移的主要因素的基本概念记忆和理解，不需要复杂的分析或综合运用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个因素（溶质原子、第二相粒子、温度、晶粒取向），但每个因素都是基础概念记忆层面的知识点，不需要复杂的分析或推理。学生只需识别并回忆这些影响晶界迁移的主要因素即可作答，属于概念解释和描述层级。" + }, + { + "idx": 4867, + "question": "What are the distinctive features, limitations, and applications of refractory metals?", + "answer": "Distinctive features: extremely high melting temperatures; large elastic moduli, hardnesses, and strengths. Limitation: some experience rapid oxidation at elevated temperatures. Applications: extrusion dies, structural parts in space vehicles, incandescent light filaments, x-ray tubes, and welding electrodes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述耐火金属的独特特征、局限性和应用，答案提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求对耐火金属的独特特征、局限性和应用进行解释和论述，涉及多个知识点的关联和综合分析，需要理解并应用相关概念，但不需要复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握耐火金属的显著特征、局限性和应用，这涉及多个知识点的综合运用。虽然题目提供了正确选项，但考生仍需具备一定的知识储备和分析能力，才能准确识别和关联这些信息。" + }, + { + "idx": 471, + "question": "Coordination polyhedron", + "answer": "The polyhedron formed by connecting the centers of atoms or ions directly bonded to a central atom or ion is called the coordination polyhedron of that atom or ion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"Coordination polyhedron\"进行定义和解释，答案以文字形式给出，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对\"coordination polyhedron\"这一基本概念的定义记忆和理解，不涉及应用或分析过程 | 难度: 在选择题型中，该题目仅考察对\"配位多面体\"这一基础概念的定义记忆，属于最基础的知识层次。题目仅要求识别正确描述定义的正确选项，无需解释或分析概念之间的关系，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2544, + "question": "Summarize and compare various intermetallic compounds such as valence compounds, electron compounds, TCP phases, and interstitial phases (interstitial compounds) in terms of the main factors determining their structures and theoretical foundations.", + "answer": "
Valence compoundsElectron compoundsTCP phasesInterstitial phases
Electronegativity, electron shell theoryElectron concentration, electron theoryComponent atomic radius ratio, topologyComponent atomic radius ratio, spatial geometry
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对不同金属间化合物进行总结和比较，需要文字解释和论述，答案以表格形式呈现了不同化合物的理论基础和决定因素，符合简答题的特征。 | 知识层次: 题目要求对不同类型金属间化合物的结构决定因素和理论基础进行总结和比较，这需要综合运用多个知识点，进行概念关联和综合分析。涉及电子理论、拓扑学、空间几何等多方面知识的整合，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1477, + "question": "Explain the characteristics of grain growth process during heating of cold-deformed metals", + "answer": "Grain growth. It causes some property changes, such as decreases in strength, plasticity, and toughness. Along with grain growth, other structural changes also occur, such as recrystallization texture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释冷变形金属加热过程中晶粒生长的特性，需要文字解释和论述，答案也提供了详细的文字描述，符合简答题的特征。 | 知识层次: 题目要求解释冷变形金属加热过程中的晶粒生长特性，涉及晶粒生长对性能的影响以及其他结构变化（如再结晶织构）。这需要将多个概念（晶粒生长、性能变化、结构变化）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解冷变形金属加热过程中的晶粒生长特性及其对性能的影响，并关联其他结构变化如再结晶织构。虽然不涉及多步计算，但需要对多个概念进行综合分析和说明。" + }, + { + "idx": 1003, + "question": "Assuming that the active slip system in a face-centered cubic crystal is (111)[011], please provide the Burgers vector of the unit dislocation for the slip.", + "answer": "The Burgers vector of the unit dislocation is ${\\vec{b}}={\\frac{a}{2}}$ [011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提供Burgers vector的具体表达式，需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目需要理解面心立方晶体中的滑移系统概念，并应用Burgers向量的计算方法。虽然涉及基础概念，但需要将多个知识点（滑移系统、Burgers向量计算）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行综合分析。题目要求考生掌握面心立方晶体中的滑移系统（111）[011]，并正确识别单位位错的伯格斯矢量。这需要考生具备晶体结构、滑移系统和位错的基本知识，并能将这些概念关联起来进行多步计算。虽然题目给出了正确选项，但考生仍需理解伯格斯矢量的计算方法和单位位错的概念，才能确认选项的正确性。因此，在选择题型内，该题目属于中等应用难度，对应等级3。" + }, + { + "idx": 1241, + "question": "When dΔG/dr=0, what is the obtained 'r' value called?", + "answer": "Critical nucleus radius", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述特定概念（临界核半径），不需要计算或选择选项 | 知识层次: 题目考查对临界核半径这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对\"Critical nucleus radius\"这一基础定义的记忆，不需要解释或复杂分析，属于最基本的概念记忆题。" + }, + { + "idx": 4835, + "question": "Briefly state what is meant by the mobility of a free electron.", + "answer": "The mobility is the proportionality constant between the drift velocity and the electric field. It is also a measure of the frequency of scattering events (and is inversely proportional to the frequency of scattering).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释自由电子迁移率的概念，答案以文字解释和论述的形式给出，符合简答题的特征。 | 知识层次: 题目考查对自由电子迁移率这一基本概念的定义和理解，属于基础概念的记忆性知识，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目要求考生不仅记忆自由电子迁移率的基本定义，还需要理解其与漂移速度和电场之间的关系，以及散射事件频率的影响。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。因此属于概念解释和描述的中等难度等级。" + }, + { + "idx": 1271, + "question": "The solubility of substitutional solid solutions is related to atomic size factor, (4), electron concentration factor, and (5).", + "answer": "4) electronegativity factor; (5) crystal structure factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分的内容，需要根据知识进行文字解释和补充，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对固溶体溶解度影响因素的基本概念记忆，包括原子尺寸因素、电负性因素、电子浓度因素和晶体结构因素等基础知识点，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然涉及基础概念记忆，但需要考生同时掌握原子尺寸因素、电子浓度因素、电负性因素和晶体结构因素四个相关概念，并正确匹配括号编号。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。题目主要测试对固溶体溶解度影响因素的分类记忆能力，属于选择题中典型的\"多概念匹配\"类型。" + }, + { + "idx": 1485, + "question": "From the perspective of bonding in materials, analyze the reasons for the differences in elastic modulus among ceramic materials, metal materials, and polymer materials", + "answer": "The magnitude of a material's elastic modulus depends on the strength of the bonding within the material. Ceramic materials are bonded by strong ionic or covalent bonds, hence their elastic modulus is very large; metal materials are bonded by weaker metallic bonds, hence their elastic modulus is smaller; in polymer materials, the molecular chains are bonded by strong covalent bonds, but the chains themselves are bonded by very weak secondary bonds, hence their elastic modulus is very small.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从材料键合的角度分析陶瓷、金属和聚合物材料弹性模量差异的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求从材料键合的角度分析陶瓷、金属和聚合物材料弹性模量差异的原因，涉及对不同材料键合类型的深入理解、键合强度与弹性模量关系的综合分析，以及不同材料类别之间的对比分析。这需要综合运用材料科学中的键合理论、弹性模量的影响因素等知识，进行推理和解释，属于复杂分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握陶瓷、金属和聚合物材料的基本键合类型，还需要深入理解不同键合类型对弹性模量的影响机制。题目涉及复杂现象的综合分析，需要考生将键合强度与宏观力学性能（弹性模量）直接关联，并进行跨材料类别的比较推理。这种在选择题中要求机理深度解释和复杂现象全面分析的题目，对知识整合能力和材料科学原理的应用能力提出了极高要求，因此属于选择题型中的最高难度等级。" + }, + { + "idx": 986, + "question": "What are the characteristics of solid-state phase transformation in metals in terms of growth?", + "answer": "Exhibits habit plane phenomena, with specific microstructural morphologies such as plate-like or needle-like.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属中固态相变的生长特性，答案提供了文字描述和论述，符合简答题的特征 | 知识层次: 题目要求解释金属固态相变在生长方面的特征，涉及习惯面现象和特定显微组织形态（如片状或针状），这需要对相变机理、晶体学关系和显微组织形成有深入的理解和分析能力。这超出了简单记忆或基本应用，需要综合运用知识进行推理和解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解固态相变的基本概念，还需要掌握生长过程中的特定现象（如习惯面现象）和微观结构形态（如板状或针状）。这需要综合运用材料科学知识，进行复杂现象的分析和机理解释，远超简单的记忆或基础理解层次。" + }, + { + "idx": 4432, + "question": "In terms of bonding, explain why silicate materials have relatively low densities.", + "answer": "The silicate materials have relatively low densities because the atomic bonds are primarily covalent in nature, and, therefore, directional. This limits the packing efficiency of the atoms, and therefore, the magnitude of the density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过文字解释和论述来说明硅酸盐材料密度较低的原因，答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释硅酸盐材料密度较低的原因，涉及对共价键方向性及其对原子堆积效率影响的理解和分析。这需要将键合类型与材料性质关联起来，属于中等应用层次的知识运用。 | 难度: 在选择题中属于中等难度，需要理解硅酸盐材料的键合性质（共价键的方向性）及其对原子堆积效率的影响，并将这些概念关联起来解释密度较低的原因。虽然不涉及多步计算，但需要进行概念关联和综合分析。" + }, + { + "idx": 3318, + "question": "Compare the approximate diffusion distances/mm of carbon atoms during bainitic transformation, pearlitic transformation, and martensitic transformation", + "answer": "In pearlitic transformation, the diffusion distance of carbon atoms is greater than 10mm; in bainitic transformation, the diffusion distance of carbon atoms is 0~10mm; in martensitic transformation, the diffusion distance of carbon atoms is 0mm.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对不同相变过程中碳原子的扩散距离进行比较和解释，答案以文字形式详细描述了不同相变过程中的扩散距离范围，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求比较不同相变过程中碳原子的扩散距离，涉及对珠光体、贝氏体和马氏体相变过程的理解，需要综合分析不同相变机制对碳原子扩散的影响。虽然不涉及复杂计算，但需要对多个概念进行关联和比较，思维过程有一定深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生比较碳原子在不同相变过程中的扩散距离，涉及对珠光体转变、贝氏体转变和马氏体转变的理解。虽然题目提供了正确选项，但考生仍需掌握这些相变的基本特征和扩散机制，才能正确判断和比较扩散距离。这需要中等层次的知识应用能力，包括概念关联和综合分析。" + }, + { + "idx": 4273, + "question": "For screw dislocation, cite the relationship between the direction of the applied shear stress and the direction of dislocation line motion.", + "answer": "screw dislocation--perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述螺丝位错中施加的剪切应力方向与位错线运动方向之间的关系，答案需要文字描述而非选择或判断。 | 知识层次: 题目考查对螺型位错基本概念的记忆和理解，即施加的剪切应力方向与位错线运动方向之间的关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆螺丝位错的基本定义和方向关系，属于基础概念记忆层次，解题步骤简单，无需复杂分析或推理。" + }, + { + "idx": 1155, + "question": "Analyze the changes of vacancies and dislocations during the low-temperature recovery stage and their effects on properties", + "answer": "During the low-temperature recovery stage, the primary phenomenon is the disappearance of vacancies. The large number of vacancies generated after cold deformation are drastically reduced through various mechanisms, including vacancy migration to surfaces or grain boundaries, recombination of vacancies with interstitial atoms, interaction between vacancies and dislocations, and aggregation of vacancies into vacancy clusters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析低温回复阶段空位和位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析低温回复阶段空位和位错的变化及其对性能的影响，涉及多个机制的相互作用（空位迁移、复合、聚集等），需要综合运用材料科学知识进行推理分析和机理解释，思维过程深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 427, + "question": "6. Common methods for strengthening metal materials include: (13)", + "answer": "Grain refinement strengthening", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举金属材料强化的常见方法，需要简要回答具体强化方式（晶粒细化强化），属于需要文字解释的简答题类型。 | 知识层次: 题目考查对金属材料强化方法的基础概念记忆，属于基本原理等记忆性知识 | 难度: 在选择题型中，该题目仅考察对金属材料强化方法中最基础概念的识别能力（晶粒细化强化），属于单一知识点的基础记忆层面，不需要解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 3340, + "question": "There is a batch of approximately 10,000 pieces of 45 steel gears, which are subjected to relatively low contact stress but require good wear resistance on the teeth and minimal heat treatment deformation. What surface treatment should be selected for these parts? Why?", + "answer": "High-frequency surface quenching. After high-frequency surface quenching, the surface hardness is 1-2 HRC higher than conventional quenching, providing good wear resistance. Additionally, since high-frequency surface quenching results in minimal heat treatment deformation, this process is selected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述选择某种表面处理的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求根据具体工况（低接触应力、耐磨性要求、热处理变形小）选择合适的表面处理方法，并解释原因。这需要综合理解高频表面淬火的工艺特点（硬度提升、变形小）与材料性能（45钢）的关联，属于多因素综合分析的应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生综合考量材料特性（45钢）、应用场景（低接触应力但高耐磨需求）以及热处理工艺特性（高频表面淬火变形小且硬度更高），才能正确选择表面处理方法。这涉及多步概念关联和综合分析能力，但无需进行多角度或深度关联性分析，因此符合等级3的标准。" + }, + { + "idx": 1429, + "question": "The type of bonding in a material determines the level of its elastic modulus. What type of bond predominates in metallic materials, how strong is the bonding, and consequently, what is their elastic modulus like?", + "answer": "Metallic materials are primarily bonded by metallic bonds, which are relatively weak, resulting in a lower elastic modulus.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目需要解释金属材料中的主要键合类型、键合强度及其对弹性模量的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查金属材料中主要键合类型及其对弹性模量的影响，属于基础概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接询问金属材料的主要键合类型、键合强度及其对弹性模量的影响，正确选项仅需记忆金属键的基本特性（相对较弱，导致较低的弹性模量），无需额外推理或跨概念整合。知识点明确且单一，符合等级1对「基础概念记忆」的要求。" + }, + { + "idx": 1534, + "question": "What is uphill diffusion?", + "answer": "Uphill diffusion refers to the process where substances diffuse from regions of low concentration to regions of high concentration, resulting in an increased concentration gradient. Examples include the copper-rich clusters formed in the early stages of aging in aluminum-copper alloys and the solute-enriched regions formed during spinodal decomposition in certain alloy solid solutions. The true driving force for uphill diffusion is the chemical potential gradient, not the concentration gradient. Although diffusion leads to an increase in the concentration gradient, the chemical potential gradient actually decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对\"uphill diffusion\"进行文字解释和论述，答案提供了详细的定义、示例和原理说明，符合简答题的特征。 | 知识层次: 题目不仅要求解释uphill diffusion的定义，还需要论述其驱动机制（化学势梯度而非浓度梯度）和实际例子（铝铜合金时效早期和调幅分解），涉及多个概念的关联和综合分析，思维深度较高。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3870, + "question": "Determine the required transformation temperature and microconstituent if an eutectoid steel is to have the hardness value HRC 38", + "answer": "600 degrees C", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定转变温度和微观组成，需要解释和论述，而答案是一个具体的温度值，属于简答形式 | 知识层次: 题目要求根据硬度值确定共析钢的转变温度和显微组织，这需要理解相变温度与硬度之间的关系，并能够应用相关相图知识进行综合分析。虽然不涉及复杂的计算或深度机理分析，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握共析钢的相变温度与硬度关系，需要综合运用TTT曲线和硬度转换知识，涉及多步计算和概念关联。虽然题目给出了正确选项，但解题过程需要综合分析材料性能与热处理参数的关系，属于中等应用层次的要求。" + }, + { + "idx": 3508, + "question": "Compare the hardness of HT150 and annealed 20 steel", + "answer": "The tensile strength and hardness are not significantly different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的硬度，答案需要文字解释和论述，而非选择、判断或计算 | 知识层次: 题目要求比较两种材料的硬度，涉及对材料性能（HT150和20钢）的理解和应用，需要综合分析不同热处理状态（退火）对材料性能的影响。虽然不涉及复杂计算，但需要对材料科学中的基本概念（如硬度、热处理）有较深的理解，并能进行概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解HT150和annealed 20 steel的基本性能特点，并能够比较它们的硬度和抗拉强度。虽然不涉及复杂的计算，但需要对材料性能有基本的了解，并能进行简单的综合分析。" + }, + { + "idx": 2824, + "question": "Given that the glass transition temperature of polyethylene is $T_{\\\\mathrm{g}}=-68~\\\\mathrm{^\\\\circ C}$, that of polyoxymethylene is $\\\\mathcal{T}_{\\\\varepsilon}=-83^{\\\\circ}\\\\mathrm{C}$, and that of polydimethylsiloxane is $T_{\\\\mathrm{{s}}}=-128^{\\\\circ}\\\\mathrm{{C}}$, analyze the general relationship between the flexibility of polymer chains and their $T_{\\\\mathfrak{s}}$.", + "answer": "The repeating unit structure of polyethylene is: —CH2—CH2—; the repeating unit structure of polyoxymethylene is: —$\\\\mathbf{CH_{3}}$—O—, and the repeating unit structure of polydimethylsiloxane is: —Si$\\\\mathbf{CH_{3}}$$\\\\mathbf{CH_{3}}$—O—. Since the internal rotation of the Si—O bond is easier than that of the C—O bond, and the internal rotation of the C—O bond is easier than that of the C—C bond, the easier the internal rotation, the better the flexibility of the molecular chain. It can thus be concluded that as flexibility increases, the temperature $T_{g}$ decreases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析聚合物链的柔韧性与玻璃化转变温度之间的关系，并提供文字解释和论述。答案中包含了详细的分子结构分析和逻辑推理，符合简答题的特征。 | 知识层次: 题目要求分析聚合物链柔性与玻璃化转变温度之间的关系，涉及多个聚合物结构的比较和内部旋转能力的分析。需要理解聚合物链柔性的影响因素，并将这些因素与玻璃化转变温度的变化联系起来。虽然不需要复杂的计算或深度推理，但需要综合多个概念进行解释，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解多个概念并进行比较分析。题目要求分析聚合物链的柔韧性与玻璃化转变温度（Tg）之间的关系，涉及对不同聚合物重复单元结构的理解、内部旋转难易程度的比较，以及这些因素如何影响分子链的柔韧性和Tg。此外，还需要综合这些信息得出结论，属于多角度分析论述的层次。" + }, + { + "idx": 3419, + "question": "Explain the meaning of the steel grade W6Mo5Cr4V2", + "answer": "W6Mo5Cr4V2 is a high-speed steel, wc=0.85%, ww=6%, WMo=5%, wc=4%, wv=3%", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钢号W6Mo5Cr4V2的含义，答案提供了详细的文字解释和成分说明，符合简答题的特征。 | 知识层次: 题目考查对高速钢牌号W6Mo5Cr4V2的基本成分记忆和理解，属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生解释特定钢号的成分含义，属于概念解释和描述层次。虽然需要记忆具体的元素含量百分比，但不需要复杂的分析或比较，属于中等偏下的难度。" + }, + { + "idx": 820, + "question": "How many types of two-dimensional lattices are there? Indicate their types and illustrate with diagrams.", + "answer": "There are 5 types of two-dimensional lattices, namely oblique, hexagonal, rectangular, centered rectangular, and square, as shown in Table 1-1.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和描述二维晶格的类型，并附上图示，这需要文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对二维晶格类型的基础概念记忆和分类理解，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目要求考生记忆并识别二维晶格的五种类型，属于基础概念记忆的范畴。虽然需要记忆五种类型的名称，但不需要深入理解其背后的原理或进行复杂的分析。相对于等级1的基本定义简答，该题目稍微复杂一些，因为它涉及多个分类的记忆，但仍属于概念解释和描述的难度水平。" + }, + { + "idx": 1964, + "question": "Please compare the similarities between binary eutectic transformation and peritectic transformation", + "answer": "Similarities: isothermal and constant composition transformation; both appear as horizontal lines on the phase diagram.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较二元共晶转变和包晶转变的相似之处，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对二元共晶转变和包晶转变的基本概念记忆和理解，涉及相图中的基本特征和等温转变等基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求比较二元共晶转变和包晶转变的相似性，但正确选项已经明确给出了两个关键相似点（等温和恒定组成转变，以及在相图中表现为水平线）。这要求考生不仅要记忆两种转变的基本定义，还需要理解它们在相图中的表现特征。因此，题目涉及的概念解释和描述，属于等级2的难度。" + }, + { + "idx": 78, + "question": "Based on the projection diagram of Mg2[SiO4] on the (100) plane, answer: How many types of coordination polyhedra are there in the structure, and what are the connection modes between the various coordination polyhedra?", + "answer": "There are two types of coordination polyhedra, [SiO4] and [MgO6]. [MgO6] octahedra in the same layer share edges, such as 59[MgO] and 49[MgO6] sharing edges 7502- and 2702-. [MgO6] octahedra in different layers share vertices, such as 1[MgO] and 51[MgO6] sharing vertex 2202-. [MgO] and [SiO4] in the same layer share vertices, such as T[MgO] and 7[SiO4] sharing vertex 2202-. [MgO6] and [SiO4] in different layers share edges, such as T[MgO] and 43[SiO4] sharing 2802- and 2802-.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述结构中的配位多面体类型及其连接方式，答案提供了详细的文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求分析晶体结构中的配位多面体类型及其连接方式，需要综合运用晶体学知识、空间想象能力和结构分析技巧。这涉及到对投影图的深入理解、配位多面体的识别以及它们之间连接方式的推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 835, + "question": "Explain the formation reasons of the surface fine grain zone in typical ingot structure", + "answer": "The surface fine grain zone has numerous nucleation sites, fast cooling rate, and large undercooling, growing dendritically in various directions, thus forming fine, equiaxed crystals. Due to the rapid crystallization of the fine grain zone, the released latent heat of crystallization cannot dissipate in time, causing the temperature at the liquid-solid interface to rise sharply. This quickly halts the development of the fine grain zone, resulting in a very thin shell of fine grain zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释典型铸锭结构中表面细晶区的形成原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释典型铸锭结构中表面细晶区的形成原因，涉及多个因素的相互作用（如形核位点、冷却速率、过冷度等）以及结晶潜热的影响，需要综合运用材料科学中的凝固原理和热力学知识进行推理分析。这种题目不仅要求对基础概念的理解，还需要将这些概念关联起来，解释复杂的物理现象，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解并综合运用多个复杂概念（如成核位点、冷却速率、过冷度、枝晶生长方向、结晶潜热等），并能够解释这些因素如何相互作用形成表面细晶区。此外，还需要理解温度变化对细晶区发展的影响机制。这种需要全面分析复杂现象并解释其机理的题目，在选择题型中属于最难的一类。" + }, + { + "idx": 3477, + "question": "For a machine tool spindle made of 40Cr steel, the core requires good strength and toughness (200-300HB), while the journal needs to be hard and wear-resistant (HRC54-58). Describe the microstructure after preparatory heat treatment.", + "answer": "Microstructure after preparatory heat treatment: tempered sorbite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求描述预备热处理后的微观结构，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对材料热处理后微观结构的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别40Cr钢经过预备热处理后的微观组织（回火索氏体），属于基础概念记忆层面的知识，无需解释或分析过程，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1193, + "question": "Analyze the changes of vacancies during the low-temperature recovery stage and their impact on properties", + "answer": "During the low-temperature recovery stage, the main manifestation is the disappearance of vacancies. The large number of vacancies generated after cold deformation are drastically reduced through mechanisms such as vacancies migrating to surfaces or grain boundaries, recombination of vacancies with interstitial atoms, interaction of vacancies with dislocations, and aggregation of vacancies into vacancy clusters.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析低温回复阶段空位的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析低温回复阶段空位的变化及其对性能的影响，涉及空位迁移、重组、与位错相互作用以及聚集等复杂机制的解释和综合分析，需要深入理解材料科学中的缺陷行为及其对材料性能的影响，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 909, + "question": "Briefly describe the differences between solid-state phase transformation and liquid-state phase transformation", + "answer": "The nucleation resistance includes an additional strain energy term, leading to an increase in the critical radius and nucleation work for solid-state phase transformation; the new phase can appear in a metastable manner, with coherent, semi-coherent interfaces, specific orientation relationships, and heterogeneous nucleation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述固态相变和液态相变之间的差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释固态相变和液态相变的差异，涉及成核阻力、临界半径、成核功、界面类型、取向关系等复杂概念的综合分析和对比，需要深入理解相变机理并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解固态相变和液态相变的基本概念，还需要深入掌握成核阻力、临界半径、成核功等复杂机理。正确选项涉及多个专业术语（如相干/半相干界面、取向关系等）和综合知识点的运用（应变能项对成核过程的影响）。这需要考生具备将多个高级概念整合分析的能力，并能够解释相变过程中的复杂现象。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最难的一类。" + }, + { + "idx": 3875, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 700^{\\circ} C, quenched to 650^{\\circ} C and held for 500s, and finally quenched to room temperature.", + "answer": "HRC =25 and the microstructure is all pearlite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，需要文字解释和论述，答案也是以文字形式给出。 | 知识层次: 题目要求描述特定热处理条件下共析钢的硬度和显微组织，涉及对热处理工艺、相变过程以及显微组织与性能关系的理解和应用。需要将热处理步骤与相变动力学和显微组织演变联系起来，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及钢的热处理过程、相变行为以及最终组织和硬度的预测，要求考生能够综合运用相关知识，分析不同温度下的相变过程，并正确判断最终的组织和硬度。虽然题目提供了具体的温度和时间参数，但考生仍需具备一定的综合分析能力才能正确选择答案。" + }, + { + "idx": 4900, + "question": "Which electrode will be oxidized in an Fe/Fe2+ concentration cell with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "Oxidation occurs in the cell half with the lower Fe2+ concentration (2 × 10^-2 M).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释哪个电极会被氧化，并给出了具体的浓度条件，答案需要文字解释和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目需要理解浓度电池的工作原理，并应用能斯特方程的概念来判断氧化发生的条件。虽然不涉及复杂计算，但需要将浓度差异与氧化还原倾向联系起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及浓度电池中电极氧化的判断，需要掌握能斯特方程的应用和氧化还原反应的基本原理。虽然不需要复杂的计算，但需要对浓度与电极电势的关系有清晰的理解，并能综合分析不同浓度条件下的氧化倾向。这种题目在选择题型中属于需要一定概念关联和逻辑推理的类型，但步骤并不十分复杂。" + }, + { + "idx": 2598, + "question": "What kind of a pair of dislocations is equivalent to a row of vacancies (or a row of interstitial atoms)?", + "answer": "When the half-atomic planes of a positive edge dislocation and a negative edge dislocation lie on the same plane, leaving out one atomic site in between will form a row of vacancies, while overlapping one atomic site will form a row of interstitial atoms.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释何种位错对等价于空位行或间隙原子行，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释位错对与空位或间隙原子行的等效关系，涉及位错类型（正负刃位错）的相互作用及其对晶体缺陷形成的影响。这需要理解位错的基本概念，并能将不同概念（位错、空位、间隙原子）关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解正负刃位错的基本概念，还需要能够综合分析和关联这些概念来推导出空位或间隙原子行的形成机制。解题步骤涉及多步逻辑推理和概念的综合应用，超出了简单的记忆或单一概念的应用。此外，题目要求考生在选择题的有限选项中识别出正确的理论解释，这需要较高的分析能力和对材料科学原理的深入理解。" + }, + { + "idx": 4301, + "question": "Briefly explain the difference between fatigue striations and beachmarks in terms of size.", + "answer": "With regard to size, beachmarks are normally of macroscopic dimensions and may be observed with the naked eye; fatigue striations are of microscopic size and it is necessary to observe them using electron microscopy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释疲劳条纹和海滩标记在尺寸上的区别，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查疲劳条纹和海滩标记的基本定义和尺寸差异，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但要求考生能够区分疲劳条纹和海滩标记在尺寸上的差异，并理解观察它们所需的不同技术手段（肉眼观察与电子显微镜）。这需要考生不仅记住定义，还要能够进行简单的概念对比和解释，属于概念解释和描述的层次。" + }, + { + "idx": 218, + "question": "Using Na2CO3 and Na2SiO3 to dilute the same type of clay slurry (mainly composed of kaolinite mineral), compare the differences in the casting rate of the two slurries when the same amount of electrolyte is added.", + "answer": "The addition of Na2CO3 basically has no effect on the casting rate of the clay, while the addition of Na2SiO3 increases the casting rate of the slurry.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种电解质对粘土浆料浇注速率的影响，并给出解释。答案需要文字论述两种电解质的不同效果，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种电解质对粘土浆料浇注速率的影响，涉及对电解质作用机理的理解和应用，需要综合分析不同电解质在粘土浆料中的行为差异，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解电解质对粘土浆料浇注速率的影响，并比较两种不同电解质（Na2CO3和Na2SiO3）的作用差异。题目要求考生综合分析两种电解质在相同条件下的不同效果，涉及多步概念关联和比较分析，但不需要进行复杂的多角度或深度关联性分析。" + }, + { + "idx": 612, + "question": "What are the two basic phases that make up the room-temperature equilibrium structure of iron-carbon alloys", + "answer": "Ferrite (α)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释铁碳合金在室温下的平衡结构的基本相，需要文字解释和论述，答案形式为简短的文字描述而非选择或判断。 | 知识层次: 题目考查铁碳合金室温平衡结构的基本相组成，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求识别铁碳合金室温平衡结构的基本相之一（铁素体α），属于最基础的定义性知识。不需要解释或比较多个概念，只需记忆单一知识点即可作答，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 1842, + "question": "What is the relationship between △L/L and sintering time in the dissolution-precipitation mass transfer process?", + "answer": "(30) △L/L∝t^(1/3)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释烧结时间与△L/L之间的关系，答案是一个数学表达式，需要简要说明其物理意义，属于需要文字解释的简答题类型。 | 知识层次: 题目涉及溶解-沉淀传质过程中烧结时间与长度变化的关系，需要理解并应用相关公式（△L/L∝t^(1/3)），属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解溶解-沉淀传质过程的基本原理，并能将烧结时间与尺寸变化关系进行综合分析。题目要求考生掌握△L/L与时间t的1/3次方关系这一特定知识点，并能在选项中进行正确识别。虽然不涉及多步计算，但需要对烧结动力学有较好的概念理解。" + }, + { + "idx": 238, + "question": "From an atomic scale perspective, explain the differences in the bonding mechanism of glass-to-metal sealing.", + "answer": "The sealing of glass and metal is governed by many factors. The most important factors affecting the seal are the following four aspects: (1) Oxidation of the metal: Before the hermetic sealing of glass and metal, the metal is usually moderately oxidized, placing the metal oxide between the glass and the metal. This step is essential for sealing and is also a microscopic control method for glass sealing. The oxidation treatment of the metal is the most critical factor affecting the sealing of glass and metal, and the oxidation mechanism is a key issue in sealing technology. (2) Thermal expansion coefficients of glass and metal: The consistency of the thermal expansion coefficients of glass and metal is a macroscopic control method for achieving good sealing. When the glass melt is sealed with the metal, the glass at high temperature has sufficient viscous fluidity. It deforms while simultaneously contracting along the thermal contraction curve of the metal. However, as the temperature decreases, the glass gradually loses its fluidity, causing it to separate from the metal's thermal contraction curve. This change is continuous and depends on the cooling rate, making it impossible to determine a specific temperature at which the glass separates from the metal's contraction curve. For convenience, a specific temperature TM is often used to represent the state when the glass is fixed to the metal. This means that when T > Tμ, the glass has complete fluidity and does not generate stress. When T < Ti1, the sealing glass contracts along its inherent thermal contraction curve. This specific temperature TM is called the solidification temperature, which is very close to the strain temperature of the glass. At any temperature T, a contraction difference ∠d is generated between the glass and metal, producing stress proportional to △d in the seal. When the stress exceeds the strength limit of the glass, the glass is damaged, affecting the hermeticity of the seal. Below the solidification temperature Ty, the relative relationship of the thermal contraction curves essentially reflects the matching degree of the expansion coefficients, i.e., the contraction difference between the glass and metal starting from Ty should be: △d = (ag - am)(T - T) (Equation 1-1). In Equation 1-1, ag and am represent the expansion coefficients of the glass and metal, respectively, from TM to the matching temperature T. To eliminate permanent stress in the glass, the seal must be annealed. Proper annealing is crucial for sealing quality. After annealing, the seal should not be cooled rapidly because the metal has better thermal conductivity than the glass, causing the metal to cool faster. When the expansion coefficients of the metal and glass are the same, this difference in cooling rates causes the metal to contract more than the glass. Once the glass loses fluidity, the metal must cool within a narrow range, and the length changes affect the adhesion between the glass and metal. If the rapid cooling starts at a temperature above the lower limit of the glass's annealing temperature, the glass will be in a stretched state. To prevent this tensile stress and to ensure the glass is slightly pressurized, the metal part is often heated separately with a gas flame after sealing. (3) Strength of the glass and interfacial diffusion: On the basis of matching the thermal expansion coefficients of the glass and metal, improving the mechanical strength of the glass, especially its tensile strength, is beneficial when the seal is subjected to thermal shock, thermal stress due to temperature gradients, or external forces during use. Generally, the compressive strength of glass can be very high, reaching 600~1500 MPa, while the tensile strength is extremely low, only about 10% of the compressive strength. In practice, only tensile strength poses problems. If possible, using crystallized glass for sealing is an effective way to improve the tensile strength of the glass, typically achieving 3~5 times or even more than 5 times the original tensile strength. It must be noted that the presence of a large number of bubbles (especially clustered bubbles) at the sealing interface is highly detrimental, as it can reduce mechanical strength and cause chronic leaks. Gas dissolved in the metal being released during sealing heating is one cause of bubbles, which is rare in metals like tungsten, molybdenum, and platinum but more common in nickel, iron, and their alloys. To eliminate this factor, metals produced by vacuum smelting are preferred, or the metal can be pre-degassed by heating in a vacuum or hydrogen atmosphere. Another cause of bubbles is carbon, especially in the surface layer of the metal, which oxidizes into carbon dioxide gas during sealing, forming bubbles. This is more severe in nickel, iron, and their alloys than in other metals. The solution is to anneal the metal in wet hydrogen or a vacuum to remove gas and carbon, thereby preventing bubble formation. The annealing temperature is generally 900~1100°C, and the duration depends on the thickness of the metal. Near the sealing interface, there are two scenarios: one involves direct mutual diffusion at the interface between two different materials, such as in glass-to-glass optical grinding seals or metal-to-metal welding. The other involves placing a different material at the interface to facilitate sealing, such as in glass-to-metal or ceramic-to-metal seals where direct mutual diffusion is difficult. In this case, melting diffusion occurs. However, whether mutual diffusion or melting diffusion occurs, the composition and properties near the interface differ from those in the bulk material, and this variation significantly affects the stability of the seal. (4) Shape, size, and surface roughness of the seal: The magnitude and distribution of stress within the seal are influenced by its shape and size. When the stress exceeds the strength limit of the sealing material, the seal is inevitably damaged. Generally, after sealing, if the seal is only a component of an electron tube or vacuum device and requires further processing or sealing with another similar device, it must undergo additional heat treatment or mechanical force. The temporary stress caused by external forces will combine with the thermal contraction stress between the materials. The combined effect of the permanent stress from thermal contraction differences and temporary stress from various causes is considerable. If the influence of shape and size on stress is overlooked, the stability of the seal may be compromised. For example, in production, the plasticity of thin metal edges can be utilized to reduce stress, or even the elasticity of the metal can be used for sealing. Additionally, adhesion tests have shown that if the substrate has uniform凹凸 (凹凸 refers to surface roughness or unevenness), the adhesion is good, which positively affects the sealing.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释玻璃与金属密封的键合机制差异，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求从原子尺度解释玻璃-金属密封的键合机制，涉及多个复杂因素的综合分析，包括金属氧化、热膨胀系数匹配、玻璃强度和界面扩散、密封形状和表面粗糙度等。需要深入理解材料科学原理，并进行多方面的推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求从原子尺度解释玻璃-金属密封的键合机制，涉及多个复杂因素的综合分析，包括金属氧化、热膨胀系数匹配、玻璃强度和界面扩散、密封形状和表面粗糙度等。正确选项详细阐述了这些因素的相互作用和影响，需要考生具备深厚的材料科学知识，能够理解并整合多个高级概念。此外，解题过程需要综合运用物理、化学和材料力学等多学科知识，进行复杂的推理和机理分析，远超一般选择题的认知要求。" + }, + { + "idx": 2527, + "question": "Explain the term: superstructure (superlattice)", + "answer": "A complex lattice composed of the sublattices of each component in an ordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"superstructure (superlattice)\"，答案是一个文字解释和论述，没有选项、判断或计算要求。 | 知识层次: 题目考查对\"superstructure (superlattice)\"这一术语的基本定义和概念的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅知道\"超结构\"的基本定义，还需要理解其组成原理（由有序固溶体中各组分的亚晶格构成）。这超出了简单的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的等级3。属于需要概念解释和描述的中间难度等级。" + }, + { + "idx": 3509, + "question": "Compare the anti-friction properties of HT150 and annealed 20 steel", + "answer": "HT150 has better anti-friction properties than 20 steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的抗摩擦性能，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求比较两种材料的抗摩擦性能，需要理解材料的基本性质（如HT150的铸铁特性和20钢的退火状态特性），并分析这些性质如何影响抗摩擦性能。这涉及多步分析和概念关联，但不需要复杂的机理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解HT150和20钢的材料特性，并进行抗摩擦性能的比较分析。题目要求考生综合运用材料科学知识，对两种材料的性能进行对比，涉及多步计算和概念关联。" + }, + { + "idx": 817, + "question": "How many equivalent slip systems can be simultaneously activated when a face-centered cubic metal single crystal is stretched along [111]? And specifically write the indices of each slip system.", + "answer": "When an FCC-structured crystal is stretched along the [111] direction, there are 6 equivalent slip systems, which are: (111)[011], (111)[110], (111)[011], (111)[101], (111)[101], (111)[110].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细写出等效滑移系统的数量及其具体指数，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求确定面心立方金属单晶在特定拉伸方向下的等效滑移系统数量及其具体指数，这需要理解滑移系统的基本概念、晶体学方向的计算以及等效滑移系统的判断。虽然涉及一定的记忆性知识，但更需要对概念的综合应用和分析能力，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 114, + "question": "Explain why only substitutional solid solutions can achieve complete mutual solubility between the two components, while interstitial solid solutions cannot.", + "answer": "(1) The interstitial sites in a crystal are limited, with an impurity accommodation capacity of $\\zeta10\\%$; (2) The formation of interstitial solid solutions generally increases the lattice constant, and when this increase reaches a certain extent, the lattice becomes unstable and dissociates; substitutional solid solutions are formed by the exchange of positions between ions of the same type, which does not affect the bonding, thus allowing the formation of continuous solid solutions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么只有置换型固溶体可以实现两种组分的完全互溶，而间隙型固溶体不能。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释置换型固溶体和间隙型固溶体在完全互溶性方面的差异，涉及晶体结构、晶格稳定性、键合作用等多个概念的综合分析和关联。需要深入理解两种固溶体的形成机制及其对材料性能的影响，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解置换固溶体和间隙固溶体的基本概念，还需要深入掌握晶体结构、晶格稳定性、溶解度限制等复杂机理。正确选项涉及多个专业知识点（如间隙位置限制、晶格常数变化、键合影响等），并要求将这些知识点综合运用来解释溶解度差异现象。此外，选项表述包含专业术语和定量数据（ζ10%），需要考生具备较强的材料科学理论基础和分析推理能力。这种在选择题中要求对复杂现象进行全面机理分析的题目，在选择题型内属于最高难度级别。" + }, + { + "idx": 4441, + "question": "Why may there be significant scatter in the fracture strength for some given ceramic material?", + "answer": "There may be significant scatter in the fracture strength for some given ceramic material because the fracture strength depends on the probability of the existence of a flaw that is capable of initiating a crack; this probability varies from specimen to specimen of the same material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对陶瓷材料断裂强度存在显著分散性的原因进行文字解释和论述，答案提供了详细的解释而非选择、判断或计算。 | 知识层次: 题目要求解释陶瓷材料断裂强度存在显著分散性的原因，涉及对断裂机理的理解和分析。需要综合运用概率统计、缺陷分布和裂纹萌生等概念，进行推理和解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解陶瓷材料断裂强度的基本概念，还需要深入分析断裂强度与缺陷概率之间的复杂关系，并能够解释不同样本间强度差异的机理。这需要综合运用材料科学知识、概率分析以及断裂力学原理，进行多层次的推理和解释。因此，该题目在选择题型内属于复杂现象全面分析的难度等级。" + }, + { + "idx": 1516, + "question": "For an edge dislocation line, its Burgers vector is __(17)__ to the dislocation line", + "answer": "(17) perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Burgers vector的方向），答案是一个单词（perpendicular），属于简答题的填空形式，需要学生对相关概念有准确理解。 | 知识层次: 题目考查对位错基本概念的记忆和理解，特别是伯格斯矢量与位错线方向的关系，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对位错线柏氏矢量方向这一基础概念的记忆，属于最基本的知识点复现。题目仅要求选择\"perpendicular\"这个固定搭配，不需要任何解释或推导过程，符合等级1\"基本定义简答\"的特征。" + }, + { + "idx": 133, + "question": "Describe the structural and property characteristics of Na2O·2SiO2 melt", + "answer": "
StructureSix-membered or eight-membered rings, long-range disorder
PropertiesHigh electrical conductivity, high surface tension
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述Na2O·2SiO2熔体的结构和性能特征，需要文字解释和论述。答案以表格形式呈现了结构和性能的具体特点，符合简答题的特征。 | 知识层次: 题目要求描述Na2O·2SiO2熔体的结构和性能特征，涉及对材料结构（如六元环或八元环、长程无序）和性能（如高电导率、高表面张力）的综合分析，需要理解并关联多个概念，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅要掌握Na2O·2SiO2熔体的基本结构特征（如六元环或八元环、长程无序），还需要理解其相关性能特点（如高电导率、高表面张力）。这涉及到多步概念关联和综合分析，属于中等应用层次的知识。虽然题目提供了正确选项，但需要考生在选择题型内进行多角度分析，将结构和性能特征联系起来，因此难度较高，属于等级4。" + }, + { + "idx": 1936, + "question": "Please write the Burgers vector of the shortest unit dislocation in an FCC crystal", + "answer": "FCC: a/2<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出FCC晶体中最短单位位错的Burgers矢量，答案需要特定的文字表述（a/2<110>），而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查FCC晶体中最短单位位错的Burgers向量的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆FCC晶体中最短单位位错的Burgers向量这一基础定义，无需解释或分析，属于最简单的记忆性知识考察。" + }, + { + "idx": 2704, + "question": "To dissolve MgF2 into LiF, what type of vacancies (anion or cation) need to be introduced into LiF?", + "answer": "To dissolve MgF2 into LiF by replacing Mg2+ with Li+, anion vacancies must be introduced to balance the charge and maintain the original MgF2 structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么需要引入特定的空位来溶解MgF2到LiF中，答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目需要理解溶解过程中的电荷平衡原理，并分析引入何种空位来维持结构稳定性，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及溶解过程中的电荷平衡和空位引入的概念，需要考生综合理解MgF2和LiF的结构差异以及电荷补偿机制。虽然不需要复杂的计算，但需要对材料科学中的缺陷化学有较好的理解，并能将不同概念关联起来进行分析。" + }, + { + "idx": 1584, + "question": "1. The macroscopic symmetry elements of crystals include (1), (2), (3), (4), and (5)", + "answer": "(1) center of symmetry; (2) axis of symmetry; (3) plane of symmetry; (4) rotoinversion axis; (5) rotoreflection axis", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举晶体的宏观对称元素，答案需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对晶体宏观对称元素的基本概念的记忆和理解，不需要复杂的应用或分析，只需列举出对称元素的名称即可。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求记忆晶体宏观对称元素的基本分类，无需进行概念解释或复杂体系阐述。正确选项直接对应基础概念记忆的知识层次，解题步骤简单，仅需识别和匹配对称元素的名称即可。" + }, + { + "idx": 1144, + "question": "How many slip systems can be formed in face-centered cubic metals?", + "answer": "12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答面心立方金属中可以形成的滑移系统数量，答案是一个具体的数字（12），但需要基于对滑移系统的理解和计算得出，属于需要简要回答的问题。 | 知识层次: 题目考查面心立方金属滑移系统数量的记忆性知识，属于基础概念的记忆和理解层面，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目仅需记忆面心立方金属的滑移系统数量（12个），属于基础概念记忆，无需复杂推理或分析。题目直接考察定义性知识，解题步骤简单，符合等级1的基本定义简答标准。" + }, + { + "idx": 1800, + "question": "What are the diffusion coefficient, activation energy, and characteristics of extrinsic diffusion?", + "answer": "The activation energy of extrinsic diffusion only includes the migration energy of particles, and extrinsic diffusion dominates at low temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释扩散系数、激活能和外在扩散的特性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对外在扩散（extrinsic diffusion）的基本概念和特性的记忆和理解，包括扩散系数、激活能及其在低温下的主导作用。这些内容属于材料科学中扩散现象的基础知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及扩散系数、激活能和外在扩散特性等基础概念，但正确选项需要考生理解外在扩散的激活能仅包括粒子迁移能，并且外在扩散在低温下占主导地位。这要求考生不仅记住定义，还需要理解概念之间的关系和应用场景。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 331, + "question": "What is the main difference between slip and twinning?", + "answer": "The shear displacement produced by slip is an integer multiple of the atomic spacing, while that produced by twinning is a fraction of the atomic spacing; this leads to a series of other differences.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释slip和twinning的主要区别，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对滑移和孪生这两种塑性变形机制的基本概念的理解和记忆，主要涉及定义和基本原理的对比，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分两种变形机制（滑移和孪生）的关键差异，即剪切位移与原子间距的关系。这超出了简单的定义记忆，要求考生能够解释和描述概念之间的区别。不过，题目并未涉及复杂的多概念体系分析或深入的应用，因此属于等级2难度。" + }, + { + "idx": 1141, + "question": "The typical crystal structure types of metals are (1), (2), and (3), and what are their corresponding coordination numbers?", + "answer": "(4) 12; (5) 8; (6) 12;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的晶体结构类型和对应的配位数，需要文字解释和论述，而不是从选项中选择或判断对错。答案的形式也是填空式的简答形式。 | 知识层次: 题目考查金属典型晶体结构类型及其配位数的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅要求记忆金属的典型晶体结构类型及其对应的配位数，无需进行概念解释或复杂分析。正确选项直接对应记忆性知识点，解题步骤简单，属于基础概念记忆层次中最简单的类型。" + }, + { + "idx": 1172, + "question": "What type of solid solution is formed when the radius of solute atoms differs significantly from that of solvent atoms?", + "answer": "Interstitial", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述不同类型的固溶体形成条件，答案需要文字说明而非选择或判断 | 知识层次: 题目考查的是对固溶体类型的基本概念的记忆和理解，特别是当溶质原子半径与溶剂原子半径差异显著时形成的固溶体类型。这属于基础概念的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即固溶体的分类定义。学生只需记住当溶质原子半径与溶剂原子半径差异显著时形成间隙固溶体（Interstitial）这一基本事实即可作答，无需进行概念解释或复杂分析。" + }, + { + "idx": 2619, + "question": "Given that the atomic number of an element is 32, based on its electron configuration, indicate which period it belongs to.", + "answer": "The fourth period", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求基于电子构型指出元素所属的周期，需要文字解释和论述，答案形式为简短的文字回答而非选择、判断或计算。 | 知识层次: 题目考查对元素周期表周期划分的基本概念记忆和理解，仅需根据原子序数确定电子排布并对应到周期表的位置，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅需要记忆原子序数与周期表周期的对应关系，属于基础概念记忆的简单应用。解题步骤简单，只需根据原子序数32直接对应到第四周期，无需复杂推理或概念整合。" + }, + { + "idx": 1016, + "question": "For cold-rolled pure copper sheets, what heat treatment should be performed if further cold rolling to reduce thickness is required?", + "answer": "To continue cold deformation, high-temperature annealing should be conducted to induce recrystallization and soften the microstructure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取的热处理措施，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对冷轧纯铜板材的热处理工艺选择，需要理解冷变形后的材料状态以及再结晶退火的作用，属于将基本原理应用于具体工艺场景的中等应用层次。虽然不涉及复杂计算，但需要综合分析材料状态与热处理目的之间的关系。 | 难度: 在选择题中属于中等难度，需要理解冷轧纯铜板材的加工硬化现象、再结晶退火的作用以及后续冷轧工艺要求之间的关联。题目要求考生综合应用材料加工和热处理知识，判断在特定工艺条件下应采取的热处理措施，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2201, + "question": "Based on the minimum recrystallization temperature of iron, 723 K, select the recrystallization annealing temperature for iron", + "answer": "The recrystallization annealing temperature for iron T=823∼923 K", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求基于给定的最低再结晶温度选择一个合适的再结晶退火温度范围，答案给出了具体的温度范围，属于需要文字解释和论述的简答题类型 | 知识层次: 题目要求基于已知的最低再结晶温度（723 K）选择铁的再结晶退火温度，这属于直接应用基本公式或经验规则（通常在最低再结晶温度以上100-200 K）来确定具体参数。虽然需要理解再结晶温度的概念，但主要考察的是简单应用能力，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用已知的最低再结晶温度（723 K）并选择适当的再结晶退火温度范围（823∼923 K）。题目不涉及复杂计算或多步骤推理，仅需基本知识点的记忆和应用，因此难度较低。" + }, + { + "idx": 281, + "question": "Analyze the effect of strain energy on the kinetics of solid-state phase transformations", + "answer": "Strain energy can influence the kinetics of phase transformation processes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析应变能对固态相变动力学的影响，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求分析应变能对固态相变动力学的影响，这需要综合运用材料科学中的相变理论、热力学和动力学知识，进行机理层面的解释和推理分析。涉及多个概念的关联和深入理解，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解应变能的基本概念，还需要综合分析其对固态相变动力学的影响机制。正确选项涉及复杂现象的全面分析，需要考生具备将热力学、动力学和材料微观结构知识进行整合的能力。这种在选择题中考查机理深度解释和复杂现象分析的能力，远超过简单记忆或基础理解层面，属于选择题型中的顶级难度。" + }, + { + "idx": 3479, + "question": "What is the difference between the wear resistance principle of wear-resistant steel and that of quenched tool steel?", + "answer": "The wear resistance principle of wear-resistant steel is that the single austenite structure is subjected to strong impact and pressure during work, resulting in stress-induced martensite and work hardening, which greatly increases the wear resistance of the steel. Quenched tool steel obtains high hardness and high wear resistance tempered martensite through quenching + low-temperature tempering, giving the steel high wear resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种钢材的耐磨原理差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释两种钢材的耐磨原理，涉及材料微观结构转变（如奥氏体向马氏体的应力诱导转变）和热处理工艺（淬火+低温回火）对性能的影响。这需要综合运用材料科学知识，理解不同机制如何导致耐磨性提升，并进行对比分析，属于机理层面的解释和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 540, + "question": "9.Linear polymers can be reused, also known as (20); cross-linked polymers cannot be reused and are called thermosetting plastics.", + "answer": "(20) Thermoplastic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个术语（Thermoplastic）来补全句子，属于需要文字回答的简答题类型，而非从多个选项中选择或判断对错。 | 知识层次: 题目考查对线性聚合物和交联聚合物基本分类的记忆，以及热塑性和热固性塑料这两个基础概念的理解。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接考察对线性聚合物和交联聚合物的基本分类记忆，仅需识别\"Thermoplastic\"这一术语即可作答，无需进行概念解释或复杂分析。正确选项与题干中的关键提示词\"reused\"直接对应，属于最基础的概念记忆层次。" + }, + { + "idx": 1313, + "question": "Dynamic recovery and dynamic recrystallization refer to the simultaneous occurrence of (15) during deformation.", + "answer": "(15) softening and strain hardening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写一个特定的术语或短语来完成句子，而不是从多个选项中选择或进行判断。答案需要简要的文字描述，符合简答题的特征。 | 知识层次: 题目考查动态回复和动态再结晶的基本概念，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生同时理解动态恢复和动态再结晶的定义，并能够将这两个概念与软化及应变硬化联系起来。这比单纯记忆单个定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 3334, + "question": "Explain why the initial structure with fine lamellar pearlite is better using the austenite isothermal formation mechanism.", + "answer": "Increasing the dispersion of carbides can accelerate the transformation from pearlite to austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么初始结构具有细片状珠光体更好，需要使用奥氏体等温形成机制进行论述。答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释初始细片层珠光体结构更优的原因，并涉及奥氏体等温形成机制的分析。这需要综合运用材料科学中的相变原理、组织-性能关系等知识，进行机理层面的推理和解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解珠光体到奥氏体的转变机制，还需要掌握碳化物分散度对相变动力学的影响。正确选项涉及微观结构-性能关系的深层机理分析，需要综合材料科学、相变动力学和扩散理论等多学科知识进行推理判断。这种在选择题中要求对复杂现象进行全面分析的题目，对考生的知识整合能力和高阶思维能力提出了极高要求。" + }, + { + "idx": 3107, + "question": "Below the critical temperature Tc, superconductors exhibit complete (2) what property?", + "answer": "Diamagnetism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字回答超导体在临界温度以下表现出的特定性质，答案\"Diamagnetism\"是一个术语而非选项，需要学生对概念的理解和表述。 | 知识层次: 题目考查超导体在临界温度以下表现出的基本性质（完全抗磁性）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需考生回忆超导体的基本特性之一——完全抗磁性（Diamagnetism）。题目直接考查定义性知识，无需解释或分析，解题步骤简单，属于最基础难度等级。" + }, + { + "idx": 1132, + "question": "The typical crystal structure types of metals are (1), (2), and (3). What are their names?", + "answer": "(1) fcc; (2) bcc; (3) hcp;", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写金属的典型晶体结构类型名称，答案需要提供具体的结构名称（fcc, bcc, hcp），属于简答形式而非选择、判断或计算。 | 知识层次: 题目考查金属典型晶体结构类型的基本概念记忆，只需回忆并列举出常见的三种结构名称（fcc、bcc、hcp），不涉及应用、分析或综合等高阶认知能力。 | 难度: 在选择题型中，该题目仅要求记忆金属的三种典型晶体结构类型（fcc、bcc、hcp），属于基础概念记忆，无需解释或分析。解题步骤简单，只需直接回忆知识点即可选择正确答案，因此在选择题型内属于最低难度等级。" + }, + { + "idx": 74, + "question": "Explain the meaning of the symbol V_{Na}", + "answer": "Sodium atom vacancy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释符号V_{Na}的含义，需要文字解释和论述，答案\"Sodium atom vacancy\"是一个简短的文字解释，符合简答题的特征 | 知识层次: 题目考查对材料科学中缺陷符号的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅要求识别和记忆基础符号的定义（钠原子空位），属于最基本的概念记忆层次。不需要解释或分析，只需直接回忆符号对应的含义，因此属于最低难度等级。" + }, + { + "idx": 1218, + "question": "Why is carburization performed in γ-Fe around 930‰, where the diffusion coefficient increases with temperature at high temperatures?", + "answer": "At high temperatures, the diffusion coefficient increases with temperature, so high temperatures are chosen. However, excessively high temperatures can cause significant grain growth in austenite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在特定温度下进行渗碳处理，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目涉及扩散系数与温度关系的机理解释，以及晶粒生长的综合分析，需要结合多个知识点进行推理和分析，思维深度较高。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2538, + "question": "What is Vegard's law?", + "answer": "Experiments have found that when two isomorphous salts form a continuous solid solution, the lattice constant of the solid solution has a linear relationship with the composition, meaning the lattice constant is proportional to the concentration of any component. This is Vegard's law.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Vegard's law的定义和内容，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查Vegard's law的基本定义和原理，属于基础概念的记忆和理解范畴，不涉及复杂应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目涉及Vegard's law的定义，但正确选项提供了较为详细的解释，包括实验发现、线性关系和比例关系等关键要素，超出了简单定义的范围。然而，题目并未要求考生进行复杂的概念体系阐述或比较分析，因此属于中等难度。" + }, + { + "idx": 4282, + "question": "What is the difference between deformation by twinning and deformation by slip relative to conditions of occurrence?", + "answer": "For slip, the atomic displacements occur in atomic spacing multiples, whereas for twinning, these displacements may be other than by atomic spacing multiples. Slip occurs in metals having many slip systems, whereas twinning occurs in metals having relatively few slip systems.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种变形机制的区别，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目要求比较两种变形机制（孪生和滑移）的发生条件，涉及对两种机制的理解和对比分析，需要将相关概念关联起来进行综合说明。虽然不涉及复杂计算或深度推理，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解滑移和孪生两种变形机制的基本概念，还需要比较它们在原子位移方式和发生条件上的差异。这涉及到多步概念关联和综合分析能力，属于中等应用层次的知识要求。正确选项包含了两个层面的对比分析（原子位移方式和滑移系统数量），需要考生在选择题型内进行多角度思考才能准确作答。" + }, + { + "idx": 4246, + "question": "(b) What is the driving force for steady-state diffusion?", + "answer": "The driving force for steady-state diffusion is the concentration gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述驱动力的概念，答案是一个简短的文字解释，没有涉及计算或选择选项。 | 知识层次: 题目考查对扩散驱动力的基本概念记忆，仅需回答浓度梯度这一基本原理，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即稳态扩散的驱动力是浓度梯度这一基本原理。题目不涉及复杂概念体系或需要解释描述，属于最基础的定义简答级别，因此难度等级为1。" + }, + { + "idx": 3364, + "question": "Classify according to the interaction between alloying elements and carbon, and indicate which elements are strong carbide-forming elements. What are the performance characteristics of strong carbides?", + "answer": "Strong carbide-forming elements: titanium, zirconium, vanadium, niobium. Strong carbides are relatively stable, with high melting points, high hardness, and relatively high brittleness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求分类并指出强碳化物形成元素，并解释强碳化物的性能特征。答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目主要考查对合金元素与碳相互作用分类的记忆，以及强碳化物形成元素的列举和性能特征的描述，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（强碳化物形成元素及其性能特点），但正确选项已经明确列出了具体的元素和性能特征，不需要考生进行复杂的比较分析或推导。主要考察的是对基础概念的记忆和理解，属于\"概念解释和描述\"层次。" + }, + { + "idx": 1560, + "question": "State Fick's second law (one-dimensional) and explain the meaning and units of each physical quantity in the formula", + "answer": "Fick's second law (one-dimensional): ∂C/∂t=D(∂²C/∂x²). In the formula, C is the concentration (g/cm³); D is the diffusion coefficient (cm²/s); t is the time (s); x is the distance (cm).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求陈述Fick第二定律并解释公式中每个物理量的含义和单位，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对Fick第二定律的基本记忆和理解，包括公式中各物理量的含义和单位，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生不仅记忆菲克第二定律的数学表达式，还需要解释公式中各个物理量的含义和单位。这超出了单纯的定义记忆（等级1），但尚未达到需要阐述复杂概念体系的程度（等级3）。题目考察的是对基础概念的理解和描述能力，属于概念解释和描述层次，因此评定为等级2难度。" + }, + { + "idx": 2899, + "question": "Briefly describe the characteristics of nanomaterials from the perspective of internal microstructure.", + "answer": "Nanomaterials refer to materials that have at least one dimension in the three-dimensional space at the nanoscale or are composed of them as basic units. According to dimensionality, the basic units of nanomaterials can be divided into three categories: (1) Zero-dimensional, meaning all three spatial dimensions are at the nanoscale, such as nanopowder materials; (2) One-dimensional, meaning two dimensions in space are at the nanoscale, such as nanowires, nanorods, nanotubes, etc.; (3) Two-dimensional, meaning one dimension in three-dimensional space is at the nanoscale, such as ultrathin films, multilayer films, and superlattices. Due to the ultrafine size of nanoparticles, they are on the same order of magnitude as the wavelength of light waves, neutron wavelength, mean free path, etc., resulting in quantum size effects, small size effects, surface effects, macroscopic quantum tunneling effects, and when the volume fraction exceeds $50\\%$, the influence of grain boundary structure causes nanomaterials to exhibit unique mechanical, physical, and chemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述纳米材料从内部微观结构角度的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目主要考查对纳米材料基本概念的记忆和理解，包括其定义、分类（零维、一维、二维）以及由于尺寸效应带来的特性（量子尺寸效应、小尺寸效应、表面效应等）。这些内容属于基础概念和基本原理的记忆性知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及了纳米材料的基本定义和分类，但需要考生理解和记忆多个概念（如零维、一维、二维纳米材料的具体例子）以及纳米材料的基本特性（如量子尺寸效应、小尺寸效应等）。这些知识点虽然属于基础概念记忆层次，但需要考生对纳米材料的内部微观结构有较为全面的理解，而不仅仅是简单的定义记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3932, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for CaO.", + "answer": "For CaO, the ionic radii of the Mn2+ and Ca2+ are 0.067 nm and 0.100 nm, respectively. Therefore, the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.100 nm - 0.067 nm) / 0.100 nm × 100 = 33%. This Δr% value is much larger than the ±15% range, and, therefore, CaO is not expected to experience any appreciable solubility in MnO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么CaO不会与MnO形成完全固溶体，答案提供了详细的文字解释和计算过程，属于需要论述的简答题类型。 | 知识层次: 题目需要计算离子半径差异百分比，并基于Hume-Rothery规则进行判断，涉及多步计算和概念关联，但不需要复杂的推理分析或机理解释。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握离子半径的概念，并能计算百分比差异，同时需要了解固溶体溶解度的限制条件（±15%范围）。虽然涉及多步计算和概念关联，但在选择题型中，这些步骤相对直接，不需要进行深度关联性分析或多角度论述。" + }, + { + "idx": 4199, + "question": "What type(s) of bonding would be expected for brass (a copper-zinc alloy)?", + "answer": "For brass, the bonding is metallic since it is a metal alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释brass的键合类型，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对金属合金键合类型的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即金属合金的键合类型。不需要解释或分析，只需识别\"brass\"是金属合金并选择\"metallic bonding\"这一基本定义。属于最基础的定义简答级别。" + }, + { + "idx": 4458, + "question": "How do the aggregate particles become bonded together in cements during setting?", + "answer": "With cements, the bonding process is a chemical, hydration reaction between the water that has been added and the various cement constituents. The cement particles are bonded together by reactions that occur at the particle surfaces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释水泥中骨料颗粒在凝固过程中如何结合，答案提供了详细的文字解释和论述，没有涉及选项选择、对错判断或数值计算。 | 知识层次: 题目考查水泥凝固过程中颗粒结合的基本原理和化学反应，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆层次的知识，但需要考生理解并描述水泥凝固过程中颗粒间化学键合的具体机制，而不仅仅是简单的定义或分类。正确选项提供了较为详细的解释，涉及水化反应和颗粒表面反应等概念，因此难度高于仅需记忆基本定义的题目（等级1），但尚未达到需要阐述复杂概念体系的难度（等级3）。" + }, + { + "idx": 1617, + "question": "The equilibrium concentration of point defects increases with the rise of __ (4).", + "answer": "(4) temperature", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（temperature）来补全句子，属于需要简短文字回答的类型，没有提供选项或要求判断对错，也不需要计算。 | 知识层次: 题目考查点缺陷平衡浓度与温度关系的基本概念记忆，属于材料科学基础理论中的基本原理记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆题，仅需考生记住\"温度升高会增加点缺陷平衡浓度\"这一基本原理即可作答。题目直接考查定义性知识，不需要解释或分析过程，解题步骤极为简单，属于选择题中最基础的难度等级。" + }, + { + "idx": 481, + "question": "What is the ground-state electron configuration of Cr (atomic number 24)?", + "answer": "1s22s22p63s23p63d54s1", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求直接写出铬（Cr）的基态电子构型，不需要从多个选项中选择，也不涉及判断对错或数值计算，而是需要准确写出电子排布式，属于简答题类型。 | 知识层次: 题目考查对原子基态电子排布的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目要求记忆铬（Cr）的基态电子排布，属于基础概念记忆的范畴。虽然需要记住特定的电子排布顺序，但不需要进行复杂的分析或推理。相对于更简单的定义简答题（等级1），此题需要记忆的元素更多，但仍在概念解释和描述的难度范围内。" + }, + { + "idx": 2101, + "question": "Under equilibrium cooling conditions, a carbon steel obtains a microstructure consisting of 50% pearlite and 50% ferrite. If it is heated to 850°C, what microstructure will be obtained?", + "answer": "Entirely austenite (A) microstructure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在特定温度下材料的微观结构变化，答案需要文字描述和论述，而非选择、判断或计算。 | 知识层次: 题目需要理解铁碳相图的基本原理，并能够根据给定的条件（50%珠光体和50%铁素体）推断出钢的碳含量，然后进一步分析在850°C加热时的相变过程。这涉及到多步的概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及碳钢在平衡冷却条件下的微观结构（珠光体和铁素体比例），以及加热到850°C后的相变过程。解答需要综合运用铁碳相图知识，判断在给定温度下钢的相组成，并理解奥氏体形成的条件。虽然不涉及复杂计算，但需要对相变概念有清晰的理解和关联分析能力。" + }, + { + "idx": 434, + "question": "7.Typical ingot structure usually has (19)", + "answer": "Central equiaxed crystal zone", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（Central equiaxed crystal zone）作为答案，这属于需要简短文字回答的问题类型，而不是从多个选项中选择或判断对错 | 知识层次: 题目考查典型铸锭结构的基本概念记忆，属于定义和分类等记忆性知识。 | 难度: 在选择题型中，该题目仅考察对典型铸锭结构的基本定义记忆，属于最基础的概念性知识。学生只需识别\"Central equiaxed crystal zone\"这一标准术语即可作答，无需进行概念解释或复杂分析，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 1109, + "question": "Number of atoms per unit cell", + "answer": "Number of atoms per unit cell: In the spatial structure of a crystal, a unit cell is adjacent to 26 other unit cells. Therefore, the atoms at the 8 corners, 12 edges, and 6 faces of the unit cell are shared with other unit cells, and only the atoms inside the unit cell entirely belong to this unit cell. The sum of the fractional contributions of the shared atoms and the actual number of atoms belonging to this unit cell is called the number of atoms per unit cell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对“Number of atoms per unit cell”进行文字解释和论述，答案提供了详细的描述和解释，而不是选择、判断或计算。 | 知识层次: 题目考查晶体学中晶胞原子数的基本概念，主要涉及原子共享原理的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生理解并记忆晶体结构中单位晶胞内原子数的计算方法，包括共享原子的分数贡献和实际属于该晶胞的原子数。虽然涉及多个概念（如角、边、面共享原子的计算），但整体上属于基础概念的记忆和简单应用，不需要复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 1242, + "question": "What does a decrease in 'r' imply about the nucleation rate?", + "answer": "Increase", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释\"r\"减小对形核速率的影响，需要文字说明其关系，答案\"increase\"是对问题的简要回答而非选择或判断 | 知识层次: 题目考查对成核速率与参数'r'关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即对'nucleation rate'与'r'关系的定义性知识。正确选项直接对应基本定义，无需复杂推理或概念整合，属于最简单的记忆性题目类型。" + }, + { + "idx": 1699, + "question": "Explain your overall understanding of the relationship between a material's composition, microstructure, processing, and properties.", + "answer": "The relationship between a material's composition, microstructure, processing, and properties is very close and mutually influential. The ultimate goal of materials scientists is to design reasonable compositions and formulate optimal production processes based on final requirements, thereby producing materials that meet the specifications. Only by understanding and controlling the structure of materials can the desired material properties be achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对材料组成、微观结构、加工和性能之间的关系进行解释和论述，答案以文字形式展开说明，符合简答题的特征。 | 知识层次: 题目要求解释材料组成、微观结构、加工和性能之间的复杂关系，需要综合运用多个概念并进行推理分析，涉及深层次的理解和关联，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生综合运用材料科学的核心概念（成分、微观结构、加工工艺和性能）之间的复杂关系，并进行机理层面的深度解释。正确选项不仅需要理解这些概念之间的相互影响，还需要掌握如何通过设计和控制这些因素来实现特定性能的材料。这种综合分析能力在选择题型中属于最高要求，需要考生具备扎实的理论基础和综合推理能力。" + }, + { + "idx": 3130, + "question": "Explain the basic concept and terminology: Twinning", + "answer": "Twinning: One of the important forms of cold plastic deformation, occurring as a uniform shear within the crystal, always along certain crystallographic planes and directions. After deformation, the deformed part and the undeformed part exhibit a mirror-symmetric orientation relationship, hence this type of plastic deformation is called twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即孪生的定义、发生机制和特征，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求解释\"Twinning\"这一概念，但正确选项已经提供了明确的定义、发生机制和特征描述，不需要考生进行复杂的分析或比较多个概念。考生只需理解并记忆这些基本概念即可正确回答，因此属于中等难度。" + }, + { + "idx": 3182, + "question": "Analyze whether a screw dislocation with Burgers vector $b=\\frac{a}{2}$ [overline{{1}}10] moving on the (111) plane in a face-centered cubic crystal can cross-slip onto one of the (111), (11overline{1}), or (overline{1}11) planes when obstructed. Why?", + "answer": "For the screw dislocation with $b=\\frac{a}{2}[\\overline{{1}}10]$, the dislocation line $t=\\left[\\overline{{1}}10\\right]$. Since [\\overline{{1}}10] $[\\overline{{1}}10]=0$, the [\\overline{{1}}10] direction lies on the (11overline{1}) plane, meaning $t$ is also on the (11overline{1}) plane. Therefore, the intersection line of (111) and (11overline{1}) planes is [\\overline{{1}}10], so the screw dislocation with $b=\\frac{a}{2}$ [\\overline{{1}}10] can cross-slip onto the (11overline{1}) plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析一个具体的材料科学现象（螺位错的交叉滑移），并解释其原因。答案提供了详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析螺位错在面心立方晶体中的交滑移行为，涉及位错线方向、滑移面几何关系以及交滑移条件的综合判断。需要深入理解位错几何学、晶体学方向计算以及交滑移机制，属于需要综合运用多个概念进行推理分析的复杂问题。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用晶体学、位错理论以及几何分析等多方面知识，深入理解螺位错的滑移机制和交叉滑移条件。解题步骤复杂，需要分析Burgers向量、位错线方向与滑移面的几何关系，并进行推理判断。此外，题目涉及复杂的空间想象和数学计算，对学生的综合分析和推理能力要求极高。" + }, + { + "idx": 4604, + "question": "For the following pair of materials, decide which has the larger thermal conductivity. Justify your choice. Random poly(styrene-butadiene) copolymer; alternating poly(styrene-butadiene) copolymer.", + "answer": "The alternating poly(styrene-butadiene) copolymer will have a higher crystallinity than the random copolymer; alternating copolymers crystallize more easily than random ones. The influence of crystallinity on conductivity is explained in part (c).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的导热性并给出理由，需要文字解释和论述，而不是从选项中选择或判断对错。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求学生比较两种共聚物的热导率，并解释其差异。这需要理解共聚物结构（随机与交替）对结晶度的影响，以及结晶度如何影响热导率。虽然涉及基础概念（共聚物类型、结晶度与热导率的关系），但需要将这些概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生比较两种共聚物的热导率，并理解交替共聚物比无规共聚物更容易结晶，从而影响热导率。这需要考生掌握共聚物结构对结晶性的影响以及结晶性对热导率的影响这两个概念，并进行综合分析。虽然不需要多步计算，但需要将多个概念关联起来，因此属于中等难度。" + }, + { + "idx": 3289, + "question": "What is the significance of the CCT diagram of eutectoid carbon steel in practical heat treatment?", + "answer": "The CCT curve can determine the heat treatment process parameters of steel during continuous cooling, such as the critical quenching cooling rate, quenching medium, and microstructure after heat treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释CCT图在实际热处理中的意义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释CCT图在实际热处理中的意义，涉及对CCT图的理解和应用，需要将理论知识与实际热处理工艺参数（如临界淬火冷却速率、淬火介质和热处理后的显微组织）联系起来，属于中等应用层次。这不仅仅是对基础概念的简单记忆，而是需要一定的分析和综合能力来理解和应用CCT图的信息。 | 难度: 在选择题中属于中等难度，需要理解CCT图的基本概念及其在热处理中的实际应用，并能将多个概念（如临界淬火冷却速率、淬火介质和热处理后的显微组织）进行关联分析。虽然题目涉及多步计算和综合分析，但在选择题型中，正确选项已经提供了明确的关联性分析，因此难度属于等级3。" + }, + { + "idx": 2504, + "question": "What is the reason for the difference in property changes between short-period elements and long-period elements?", + "answer": "This is because the number of subshell electrons in the long-period transition elements also affects the properties of the elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释元素性质变化的原因，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释短周期元素和长周期元素性质差异的原因，涉及对元素周期表中不同周期元素电子排布和性质变化的深入理解，需要综合运用原子结构和周期律的知识进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 47, + "question": "Into which categories can silicate crystals be classified?", + "answer": "Silicate crystals can be specifically classified into five categories: island, group, chain, layer, and framework.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对硅酸盐晶体进行分类，并需要文字解释和论述，答案提供了具体的分类名称，符合简答题的特征 | 知识层次: 题目考查对硅酸盐晶体分类的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆硅酸盐晶体的五种基本分类（岛状、群状、链状、层状和架状），属于基础概念的直接回忆。不需要解释或分析，只需识别正确选项，因此属于最简单的难度等级。" + }, + { + "idx": 838, + "question": "Write the close-packed plane, interplanar spacing of close-packed planes, close-packed direction, and minimum unit length of the close-packed direction for BCC crystals.", + "answer": "
BCC110}√2 D 2<111>√3 2 a
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细描述BCC晶体的密排面、密排面间距、密排方向及其最小单位长度，需要文字解释和论述，答案以表格形式呈现了具体参数，符合简答题的特征。 | 知识层次: 题目要求写出BCC晶体的密排面、密排面间距、密排方向和密排方向的最小单位长度，这些内容属于晶体结构的基本性质，需要记忆和理解基本概念，并进行简单的公式应用和计算。虽然涉及多个知识点，但每个知识点都是直接套用和简单计算，不需要复杂的分析或综合。 | 难度: 在选择题型中，该题目属于简单应用难度。题目要求直接套用BCC晶体的基本公式和概念，如密排面、面间距、密排方向及其最小单位长度。虽然涉及多个知识点，但都是晶体学中的基础内容，且题目提供了正确选项，学生只需识别和匹配即可，无需复杂计算或深入分析。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 196, + "question": "From an atomic scale perspective, explain the differences in the bonding mechanism of adhesive joining", + "answer": "The essence of adhesion, like adsorption, is the result of surface forces between two substances. Adhesive effects can be manifested through phenomena such as friction during relative sliding of two phases, aggregation of solid powders, and sintering.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从原子尺度解释粘接机制的差异，需要文字解释和论述，属于简答题类型。答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求从原子尺度解释粘接机制的差异，涉及表面力、吸附现象以及多种粘附效应的表现，需要综合运用材料科学中的原子键合理论、表面科学和界面现象等知识，进行机理层面的深入分析和解释。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1632, + "question": "In face-centered cubic crystals, the partial dislocation caused by (6)__ is called the Shockley partial dislocation", + "answer": "(6) non-uniform slip", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（non-uniform slip）来完整句子，这属于需要提供简短文字答案的简答题类型，而不是从多个选项中选择或进行判断。 | 知识层次: 题目考查的是面心立方晶体中部分位错的基本概念和分类，需要记忆和理解Shockley部分位错的定义及其形成原因，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅考察基础概念的记忆，即Shockley partial dislocation的定义和成因。正确选项\"non-uniform slip\"是直接对应教材中的定义性知识，无需复杂推理或概念关联。属于最基础的定义简答层级，符合等级1标准。" + }, + { + "idx": 1071, + "question": "Describe the phase transformation process, products, and reaction conditions along the ECF line in the phase diagram", + "answer": "The ECF line undergoes a eutectic reaction: L_C ⇌ γ_E + Fe3C; the product is: ledeburite (Ld)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求描述相变过程、产物和反应条件，需要文字解释和论述，答案也是以文字形式给出具体反应和产物，符合简答题的特征。 | 知识层次: 题目要求描述相变过程、产物及反应条件，涉及相图中ECF线的共晶反应，需要理解相图的基本原理并能够关联不同概念（如相变过程、产物组成等），属于中等应用层次。虽然涉及基础概念，但需要一定的综合分析能力来阐述反应条件和产物。 | 难度: 在选择题中属于中等难度，需要理解相图中的ECF线、共晶反应、产物莱氏体等多个概念，并进行综合分析。虽然题目给出了正确选项，但需要考生具备将相图知识与反应条件、产物关联起来的能力，属于中等应用层次的知识要求。" + }, + { + "idx": 3573, + "question": "What properties should the head of a carpenter's hammer possess?", + "answer": "The striking face and claws of the hammer should be hard-the metal should not dent or deform when driving or removing nails. Yet these portions must also possess some impact resistance, particularly so that chips do not flake off the striking face and cause injuries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述木工锤头应具备的性能，答案提供了详细的文字描述和解释，符合简答题的特征。 | 知识层次: 题目要求分析锤头应具备的性能，涉及硬度与抗冲击性的平衡，需要理解材料性能与应用场景的关联，并进行综合分析。虽然不涉及复杂计算，但需要对材料性能有较深入的理解和应用能力。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生综合理解锤头材料需要具备的硬度与抗冲击性的平衡，并分析这些性能在实际使用中的具体表现（如防止变形和碎片飞溅）。这涉及材料性能的综合应用分析，但不需要多角度或深度关联性论述。" + }, + { + "idx": 1922, + "question": "Explain the formation conditions and characteristics of structural defects in cation vacancy-type non-stoichiometric compounds", + "answer": "Under oxidizing atmosphere, low valence state changes to high valence state, p-type semiconductor.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释阳离子空位型非化学计量化合物的结构缺陷形成条件和特征，需要详细的文字解释和论述。答案提供了氧化气氛下价态变化和半导体类型的描述，符合简答题的特点。 | 知识层次: 题目要求解释阳离子空位型非化学计量化合物的结构缺陷形成条件和特征，涉及氧化气氛下的价态变化和半导体类型转变，需要综合运用材料科学中的缺陷化学、半导体物理等知识，进行机理分析和推理。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解非化学计量化合物的基本概念，还需要深入掌握结构缺陷的形成条件（氧化气氛）及其对材料性能的影响（p型半导体特性）。这需要综合运用晶体化学、缺陷化学和半导体物理等多学科知识进行机理层面的深度解释，并能够将氧化还原反应与半导体类型变化联系起来。选择题型中仅给出正确选项的情况下，考生仍需具备从复杂现象中提取关键特征的能力，这远超简单记忆或基础理解的层次。" + }, + { + "idx": 4265, + "question": "A cylindrical rod 100mm long and having a diameter of 10.0mm is to be deformed using a tensile load of 27,500 N. It must not experience a diameter reduction of more than 7.5 x 10^-3 mm. Of the materials listed as follows, which are possible candidates? Justify your choice(s).", + "answer": "Of the alloys listed, the steel alloy is a possible candidate because it meets the criterion regarding diameter reduction. The titanium alloy is not a candidate as it fails this criterion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从多个材料中选择符合条件的候选材料，并需要文字解释和论述选择的理由，而不是简单的选择或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目需要学生进行多步计算（如应力、应变计算）和综合分析（比较不同材料的性能），涉及概念关联（如弹性模量与直径变化的关系）和材料选择标准的应用，但不需要复杂的机理分析或创新设计。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生掌握材料力学性能的基本概念（如弹性模量、泊松比等），还需要进行多步计算（如应力、应变、直径变化等），并综合分析计算结果与给定条件的匹配程度。此外，题目还要求考生在多个材料选项中进行比较和选择，需要较强的概念关联和综合分析能力。虽然题目提供了正确选项，但解题过程涉及的知识深度和步骤复杂度使其在选择题型中属于较难级别。" + }, + { + "idx": 4579, + "question": "Explain why no hole is generated by the electron excitation involving a donor impurity atom.", + "answer": "No hole is generated by an electron excitation involving a donor impurity atom because the excitation comes from a level within the band gap, and thus, no missing electron is created within the normally filled valence band.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在涉及施主杂质原子的电子激发过程中不会产生空穴，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释电子激发过程中空穴不产生的原因，涉及能带理论、杂质能级和电子跃迁机理的综合分析，需要深入理解半导体物理中的相关概念并进行逻辑推理。 | 难度: 在选择题中属于最高难度等级，题目要求深入理解半导体物理中的杂质能级和电子激发机制，需要综合运用能带理论、掺杂效应和载流子生成原理进行复杂分析。正确选项涉及从带隙内能级激发的特殊性质，以及价带完整性保持的机理解释，这超出了基础概念记忆和简单应用层面，属于需要全面分析复杂现象的题目类型。" + }, + { + "idx": 4581, + "question": "Germanium to which 5 × 10^22 m^-3 Sb atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the Sb atoms may be thought of as being ionized (i.e., one charge carrier exists for each Sb atom). Is this material n-type or p-type?", + "answer": "this germanium material to which has been added 5 × 10^22 m^-3 sb atoms is n-type since sb is a donor in ge.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来判断材料的类型（n-type或p-type），而不是从多个选项中选择、判断对错或进行数值计算。答案也以文字解释的形式给出。 | 知识层次: 题目考查对半导体掺杂类型的基本概念的理解，即施主掺杂（Sb）导致n型半导体。这属于基础概念的记忆和理解，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅需要考生记忆基本的半导体类型分类知识，即知道锑（Sb）在锗（Ge）中是施主杂质，因此掺杂后形成n型半导体。不需要进行复杂的分析或推理，属于最基础的定义记忆类题目。" + }, + { + "idx": 934, + "question": "Briefly describe the role and influence of grain boundaries on the plastic deformation of polycrystals", + "answer": "The slip planes on both sides of the grain boundary are not parallel. On one hand, grain boundaries act as obstacles to dislocation motion, causing pile-ups and strengthening; meanwhile, they necessitate the occurrence of multiple slip systems near the grain boundaries to accommodate the deformation on both sides.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶界对多晶体塑性变形的作用和影响，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释晶界在多晶塑性变形中的作用和影响，涉及位错运动、滑移系统协调等机理分析，需要综合运用材料科学中的多个概念并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 793, + "question": "Explain what type of solid solution compound Fe3C belongs to", + "answer": "Fe3C is an interstitial compound, belonging to the interstitial phase with a complex structure", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Fe3C属于哪种固溶体化合物，需要文字解释和论述，答案也是以文字形式给出解释说明 | 知识层次: 题目考查对Fe3C分类的基础概念记忆和理解，属于材料科学中固溶体类型的基本知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并区分不同类型的固溶体化合物（如间隙相和间隙化合物），并能够正确识别Fe3C的具体分类。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的体系阐述（等级3）。" + }, + { + "idx": 4447, + "question": "Cite one reason why ceramic materials are, in general, harder yet more brittle than metals.", + "answer": "Crystalline ceramics are harder yet more brittle than metals because they (ceramics) have fewer slip systems, and, therefore, dislocation motion is highly restricted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述陶瓷材料比金属更硬但更脆的原因，答案提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释陶瓷材料比金属更硬但更脆的原因，涉及对材料微观结构（如滑移系统）和力学行为（如位错运动）之间关系的深入理解。这需要综合运用晶体结构、位错理论和材料力学性能的知识，进行机理层面的分析和解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4242, + "question": "(a) Briefly describe a twin and a twin boundary.", + "answer": "A twin boundary is an interface such that atoms on one side are located at mirror image positions of those atoms situated on the other boundary side. The region on one side of this boundary is called a twin.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求简要描述孪晶和孪晶界，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对孪晶和孪晶界面的基本定义和概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求考生记忆并复述孪晶和孪晶界面的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的定义性描述，无需进行解释或比较分析，解题步骤简单直接，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 979, + "question": "What is the difference in phase transformation resistance between the solid-state phase transformation of metals and the crystallization process of metals?", + "answer": "There is an additional term of strain energy in the phase transformation resistance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属的固态相变和结晶过程在相变阻力上的差异，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较金属固态相变和结晶过程的相变阻力差异，并解释其中应变能的作用。这需要深入理解相变机制、能量变化和微观结构演变，涉及多个概念的关联和综合分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2133, + "question": "What would be the result if carburizing of steel parts is not conducted in the γ phase region?", + "answer": "If carburizing is not performed in the γ phase region, since the maximum carbon solubility (mass fraction) in α-Fe is only 0.0218%, for steel with a carbon mass fraction greater than 0.0218%, the carbon concentration gradient in the part during carburizing would be zero, making carburizing impossible; even for pure iron, when carburizing in the α phase region, the concentration gradient in the iron is very small, and a high carbon layer cannot be obtained on the surface. Additionally, due to the low temperature, the diffusion coefficient is also very small, making the carburizing process extremely slow and practically meaningless.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在γ相区外进行钢件渗碳的结果，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释在非γ相区进行渗碳的后果，涉及对相图、扩散系数和浓度梯度的综合分析，需要深入理解材料科学中的相变和扩散机制，并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解γ相区和α相区的碳溶解度差异，还需要综合运用扩散系数、浓度梯度等概念进行机理分析。正确选项涉及多个专业概念的联动解释（如碳溶解度限制、扩散动力学、相变条件等），需要考生具备将材料科学原理与工程实践相结合的复杂分析能力。这种在选择题中要求全面分析相变、扩散和工艺参数相互作用的题目，已经达到了选择题型中最高的认知要求层次。" + }, + { + "idx": 1545, + "question": "5．Extended dislocation", + "answer": "A complete dislocation dissociates into two partial dislocations and the stacking fault between them, and this dislocation configuration is called an extended dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Extended dislocation\"进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对扩展位错（extended dislocation）这一基本概念的定义和构成的理解，属于材料科学中位错理论的基础知识记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（定义、分类、基本原理等），但需要考生准确理解并区分\"complete dislocation\"、\"partial dislocations\"和\"stacking fault\"这几个专业术语及其相互关系。这比单纯记忆一个简单定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1182, + "question": "Ferritic stainless steel is (27)", + "answer": "(27) 1Cr17", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的材料牌号（1Cr17），属于需要简短文字回答的形式，没有提供选项或需要判断对错，也不涉及计算过程。 | 知识层次: 题目考查对铁素体不锈钢基本分类的记忆，仅需回答特定牌号1Cr17，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别Ferritic stainless steel的正确选项1Cr17，无需复杂推理或概念比较。在选择题型中，此类直接考察定义和分类的记忆性知识属于最低难度等级。" + }, + { + "idx": 1012, + "question": "What are the characterization methods for dislocation density?", + "answer": "There are two methods: volume density, which is the length of dislocation lines per unit volume; and surface density, which is the number of dislocation lines perpendicularly passing through a unit area.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和论述位错密度的表征方法，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对位错密度表征方法的基本概念记忆和理解，仅需回答两种方法的定义，不涉及应用或分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生记忆并理解位错密度的两种表征方法（体积密度和表面密度）的定义，但不需要进行复杂的比较分析或推导。虽然涉及两个概念，但都属于基础概念记忆层次，解题步骤相对简单，只需正确识别和匹配定义即可。" + }, + { + "idx": 1588, + "question": "The microscopic mechanisms of diffusion in crystalline solids include (12)", + "answer": "(12) interstitial mechanism", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释晶体固体中扩散的微观机制，答案以文字形式给出，需要简要描述扩散机制的类型。 | 知识层次: 题目考查晶体固体中扩散的微观机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别晶体固体中扩散的微观机制之一（间隙机制），属于基础概念记忆层次。题目仅涉及单一知识点的直接回忆，无需解释、比较或分析多个概念，因此属于选择题型中最简单的难度等级。" + }, + { + "idx": 328, + "question": "What are the main mechanisms of metal plastic deformation at room temperature?", + "answer": "The main deformation mechanisms are slip and twinning.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属在室温下的主要塑性变形机制，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查金属塑性变形的基本机制（滑移和孪生）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆金属塑性变形的基本机制（滑移和孪生），属于最基础的定义性知识。题目不涉及概念解释或复杂体系阐述，只需识别正确选项即可，因此属于最低难度等级。" + }, + { + "idx": 4634, + "question": "Without consulting Figure or Table, determine whether the electron configuration (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{5}) is an inert gas, a halogen, an alkali metal, an alkaline earth metal, or a transition metal. Justify your choice.", + "answer": "The (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{5}) electron configuration is that of a halogen because it is one electron deficient from having a filled (p) subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据电子排布判断元素类别，并需要文字解释和论述来证明选择。答案提供了详细的解释，说明为什么该电子排布对应卤素，这符合简答题的特征。 | 知识层次: 题目考查对电子构型与元素分类之间关系的基本概念记忆和理解，只需根据电子构型判断元素类别，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆电子构型与元素分类的基本对应关系，但解题步骤相对直接，只需识别电子构型并匹配到对应的元素类别（卤素）。不需要复杂的分析或比较多个概念，仅需基础概念的记忆和简单应用。" + }, + { + "idx": 244, + "question": "How should the cooling rate of high iron composition (P<1.38) in the burning zone be controlled?", + "answer": "For compositions with an alumina modulus P<1.38, the melt cooling and crystallization process passes through the WT2 boundary, where the liquid phase absorbs C2S back and precipitates CsS and C4AF. Therefore, the slower the clinker cooling rate, the closer it approaches equilibrium, and the more fully C2S is absorbed back. The content of CS in the clinker will increase, which is beneficial for cement quality. Thus, for clinker with P<1.38, the cooling rate in the burning zone should be appropriately slowed down.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对高铁成分（P<1.38）在燃烧区的冷却速率控制进行解释和论述，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及对高铁成分在燃烧区冷却速率的控制机制的理解，需要综合运用材料科学中的相变原理和水泥熟料形成过程的知识。解答过程中需要分析冷却速率对相变路径和最终产物组成的影响，并基于此提出控制策略，体现了较高的认知层次和综合分析能力。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅要理解高铁成分（P<1.38）在燃烧区的冷却速率控制原理，还需要掌握熔体冷却和结晶过程中通过WT2边界时液相吸收C2S并析出CsS和C4AF的复杂机理。此外，题目还要求考生能够推理分析冷却速率对水泥质量的影响，并综合运用这些知识得出正确的控制策略。这种题目不仅考察了多个复杂概念的掌握，还需要考生进行深层次的机理解释和综合推理，因此在选择题型中属于最高难度。" + }, + { + "idx": 2595, + "question": "When the crystal around an edge dislocation contains interstitial atoms below the equilibrium concentration, how will the dislocation climb?", + "answer": "Positive climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下位错如何攀移，需要文字描述和论述，答案\"Positive climb\"是一个简短的定性描述，而非从多个选项中选择或简单判断对错。 | 知识层次: 题目涉及位错攀移机制与间隙原子浓度关系的深入分析，需要综合运用位错理论和扩散知识进行推理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 941, + "question": "Briefly describe the characteristics of nucleation in solid-state phase transformations", + "answer": "Non-uniform nucleation, with specific orientation relationships, often forming coherent or semi-coherent interfaces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要描述固态相变中成核的特征，答案以文字解释的形式给出，没有选项、判断或计算要求。 | 知识层次: 题目要求描述固态相变中成核的特征，涉及非均匀成核、特定取向关系以及相干/半相干界面的形成。这需要将多个概念（成核理论、界面结构、取向关系）进行关联和综合分析，而不仅仅是基础概念的简单记忆。回答需要理解这些概念之间的关系，并能够进行中等程度的整合应用。 | 难度: 在选择题中属于中等难度，需要理解固态相变中形核的基本特征，包括非均匀形核、特定取向关系以及相干/半相干界面的形成等概念，并能将这些概念关联起来进行综合分析。虽然不涉及多步计算，但需要对多个相关概念有较好的掌握和理解。" + }, + { + "idx": 4612, + "question": "Why does ferromagnetic behavior cease above the Curie temperature for ferromagnetic materials?", + "answer": "Ferromagnetic behavior ceases above the Curie temperature because the atomic thermal vibrations are sufficiently violent so as to completely destroy the mutual spin coupling forces.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对现象进行文字解释和论述，答案提供了详细的原理说明，符合简答题的特征。 | 知识层次: 题目要求解释铁磁材料在居里温度以上失去铁磁行为的机理，涉及原子热振动与自旋耦合力的相互作用，需要深入理解材料微观结构和宏观性能的关系，属于综合运用和推理分析的层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解铁磁材料的微观机理（自旋耦合作用与热振动的关系），并能综合运用热力学与量子力学知识解释复杂相变现象。正确选项涉及原子尺度相互作用与宏观性能的关联，需要考生在选择题的有限信息中进行高阶推理，完全符合\"复杂现象全面分析\"的知识层次要求。" + }, + { + "idx": 4616, + "question": "What are the characteristics of opaque materials in terms of their appearance and light transmittance?", + "answer": "Opaque materials are impervious to light transmission; it is not possible to see through them.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释不透明材料的外观和光透射特性，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对不透明材料基本特性的记忆和理解，属于定义和基本原理的记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需回忆不透明材料的基本定义和特性（不透光、无法看透）。在选择题型中属于最简单的直接知识回忆类题目，无需复杂推理或概念比较。" + }, + { + "idx": 1698, + "question": "Explain your understanding of the relationship between the structure and properties of materials.", + "answer": "The internal structure of materials can be divided into different levels, including atomic structure, the arrangement of atoms, as well as microstructure and structural defects. If the same crystalline material has its grain or 'phase' morphology and distribution altered, its properties can be significantly improved. Whether it is metals, ceramics, semiconductors, polymers, or composite materials, their development is closely related to structure. Only by understanding and controlling the structure of materials can we achieve the desired material properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释材料结构与性能之间的关系，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释材料结构与性能之间的关系，涉及多个结构层次（原子结构、原子排列、微观结构、结构缺陷）及其对性能的影响，需要综合运用材料科学知识进行推理分析和机理解释，思维过程深度要求较高。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对材料结构与性能的关系有深入的理解，并能综合运用多个层次的知识（如原子结构、微观结构、缺陷等）进行复杂分析。正确选项不仅需要识别不同结构层次的影响，还要理解结构变化如何导致性能改善，这涉及机理深度解释和复杂现象的全面分析。在选择题中，这种综合性和深度要求显著高于简单的概念识别或单一知识点回忆。" + }, + { + "idx": 857, + "question": "When an aluminum (Al) single crystal is stretched along the [123] direction to induce plastic deformation, determine the rotation law and rotation axis of the crystal during double slip.", + "answer": "During double slip, the specimen axis rotates toward [101], with the rotation axis being n1=[11¯2]×[10¯1]=[¯1¯1¯1], and also rotates toward [011], with the rotation axis being n2=[11¯2]×[01¯1]=[111]. Therefore, the resultant rotation axis is n=n1+ n2=[000], meaning the crystal orientation no longer changes and is only elongated.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体在双滑移过程中的旋转规律和旋转轴，答案提供了详细的文字解释和论述，没有涉及选择、判断或数值计算。 | 知识层次: 题目要求分析铝单晶在双滑移过程中的旋转规律和旋转轴，涉及晶体塑性变形机制的综合理解和推理分析。需要综合运用晶体学、滑移系选择、旋转轴计算等知识，并进行多步推理和解释，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求综合运用晶体塑性变形、双滑移机制、晶体旋转定律等复杂概念，并进行矢量运算和空间几何分析。解题步骤涉及多个高阶知识点的整合，包括确定滑移方向、计算旋转轴、理解双滑移条件下的合成效应等。正确选项的推导需要深入理解晶体力学行为并具备较强的空间推理能力，远超一般选择题的认知要求。" + }, + { + "idx": 1629, + "question": "A dislocation whose Burgers vector equals a lattice vector is called __ (5)_", + "answer": "(5) perfect dislocation", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（perfect dislocation）来补全句子，属于需要简短文字回答的题目类型 | 知识层次: 题目考查的是位错的基本概念和分类，特别是完美位错的定义，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，此题属于基本定义简答难度。题目直接考察对\"perfect dislocation\"这一基础概念的定义记忆，只需识别Burgers vector等于晶格矢量这一关键特征即可作答，无需概念解释或复杂推理。选择题型中此类直接考查术语定义的题目属于最基础难度层级。" + }, + { + "idx": 4508, + "question": "For the pair of polymers: branched and syndiotactic polypropylene with a degree of polymerization of 5000; linear and isotactic polypropylene with a degree of polymerization of 3000, do the following: (1) state whether or not it is possible to decide whether one polymer has a higher tensile modulus than the other; (2) if this is possible, note which has the higher tensile modulus and then cite the reason(s) for your choice; and (3) if it is not possible to decide, then state why.", + "answer": "Yes, it is possible. The linear and isotactic polypropylene will have a greater tensile modulus. Linear polymers are more likely to crystallize that branched ones. ", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较两种聚合物的拉伸模量并给出理由，这符合简答题的特征。 | 知识层次: 题目要求比较两种不同结构的聚丙烯的拉伸模量，需要理解聚合物结构（支化与线性、等规与间规）对结晶度和力学性能的影响，并进行综合分析。虽然不涉及复杂计算，但需要对多个概念进行关联和比较，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解聚合物结构（支化与线性、等规与间规）对结晶度和力学性能的影响，并进行多角度比较分析。题目要求判断两种不同结构聚丙烯的拉伸模量高低，涉及分子链排列、结晶能力等深层次概念关联，且需在给定条件下做出明确结论并说明理由，属于多步计算和概念关联的综合分析题。" + }, + { + "idx": 3507, + "question": "Compare the welding performance of HT150 and annealed 20 steel", + "answer": "The welding performance of 20 steel is better than that of HT150.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的焊接性能，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的焊接性能，需要理解材料的基本性质（如HT150是铸铁，20钢是低碳钢）以及焊接性能的影响因素（如碳含量、热处理状态等），并进行综合分析。这涉及到多个概念的关联和中等程度的分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解HT150和20钢的焊接性能特点，并进行比较分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了明确的比较结论，降低了分析难度。" + }, + { + "idx": 601, + "question": "The coordination number of FCC structure is", + "answer": "12", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答FCC结构的配位数，答案是一个具体的数值（12），不需要从多个选项中选择，也不需要判断对错或进行复杂的计算。虽然答案简短，但属于直接回答问题的简答题类型。 | 知识层次: 题目考查面心立方(FCC)结构配位数的记忆，属于晶体结构中最基础的概念性知识，不需要复杂的计算或分析过程。 | 难度: 在选择题型中，该题目仅考察对FCC结构配位数的基础定义记忆，属于最基础的概念性知识。题目仅需选择正确数字选项，无需任何解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 273, + "question": "The formation reaction of mullite from Al2O3 and SiO powders is diffusion-controlled and conforms to the Jander equation. What effective measures should be taken to accelerate the formation of mullite?", + "answer": "All factors favorable for diffusion can be employed to accelerate the formation of mullite: reducing particle size, using reactive reactants (such as Al2O3·3H2O), applying appropriate pressure, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求提出有效的措施来加速莫来石的形成，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求考生理解扩散控制反应的基本原理（Jander方程），并能综合运用扩散影响因素（如颗粒尺寸、反应物活性、压力等）来提出加速莫来石形成的具体措施。这需要多步概念关联和综合分析能力，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解扩散控制反应的基本原理，并能够综合分析多种促进扩散的因素（如粒径减小、反应物活性、压力等）对反应速率的影响。虽然不需要进行复杂的计算，但需要对Jander方程和相关概念有一定的掌握，并能将这些概念关联起来进行判断。" + }, + { + "idx": 71, + "question": "What are the characteristics of non-stoichiometric compounds?", + "answer": "Characteristics of non-stoichiometric compounds: The formation and defect concentration of non-stoichiometric compounds are related to the nature and pressure of the atmosphere; they can be regarded as solid solutions of higher-valent and lower-valent compounds; the defect concentration is related to temperature, which can be seen from the equilibrium constant; non-stoichiometric compounds are all semiconductors.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释非化学计量化合物的特征，答案提供了详细的文字解释和论述，符合简答题的特点。 | 知识层次: 题目要求解释非化学计量化合物的特性，涉及多个相关概念（如缺陷浓度、温度影响、半导体性质等）的综合分析，需要理解并关联这些概念，而不仅仅是记忆基础定义。虽然不涉及复杂计算，但需要一定的概念关联和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。正确选项涵盖了非化学计量化合物的多个关键特征，包括与气氛性质和压力的关系、高低价态化合物的固溶体性质、缺陷浓度与温度的关系以及半导体特性。这些知识点需要考生不仅理解基本概念，还能进行多角度分析和概念关联。此外，题目要求考生能够综合这些信息并识别出正确选项，这在选择题型中属于较为复杂的综合分析任务。" + }, + { + "idx": 1631, + "question": "What are the main resistances to nucleation in solid-state phase transformations?", + "answer": "Interfacial energy and elastic strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释和列举固态相变中成核的主要阻力，答案以文字形式给出，需要简要说明和论述 | 知识层次: 题目考查固态相变中成核的主要阻力，即界面能和弹性应变能，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生同时掌握\"界面能\"和\"弹性应变能\"这两个关键概念，并理解它们对固态相变中形核阻力的影响。这比单纯记忆单一概念的定义（等级1）要求更高，但又不涉及复杂的概念体系分析（等级3）。" + }, + { + "idx": 2033, + "question": "Describe the thermodynamic conditions of crystallization phase transition", + "answer": "Analysis of the change in system free energy during crystallization phase transition shows that the thermodynamic condition for crystallization is ΔG<0. From the change in free energy per unit volume ΔGB=-LmΔT/Tm, it can be seen that only when ΔT>0 can ΔGg<0 be achieved. That is, only undercooling can make ΔG<0.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述结晶相变的热力学条件，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析结晶相变的热力学条件，涉及系统自由能变化和单位体积自由能变化的计算，需要理解并应用相关公式（ΔG<0和ΔGB=-LmΔT/Tm），同时需要关联概念（过冷度ΔT>0）来综合解释热力学条件。这属于中等应用层次，需要多步推理和概念关联。 | 难度: 在选择题中属于较高难度，题目要求分析结晶相变的热力学条件，涉及系统自由能变化、单位体积自由能变化以及过冷度等概念的综合理解和计算。需要考生能够将多个热力学概念关联起来，并进行多步推导和分析，才能得出正确的结论。这种题目不仅考察基本概念的理解，还要求考生能够进行综合分析和应用，因此在选择题型中属于较高难度。" + }, + { + "idx": 477, + "question": "3. In solid-state crystals, diffusion can be classified into which two types based on whether new phase structures are formed during atomic diffusion?", + "answer": "Atomic diffusion and reactive diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释和论述扩散的分类，答案需要文字描述而非选择或判断 | 知识层次: 题目考查对固态晶体中扩散类型的基本分类记忆，属于基础概念的记忆和理解层面 | 难度: 在选择题型中，该题目仅考察对固态晶体扩散分类的基础概念记忆，属于最基础的定义简答类型。题目直接给出两种扩散类型的名称（原子扩散和反应扩散），不需要进行概念解释或复杂分析，只需识别正确分类即可。这种题目在选择题中属于最低难度级别。" + }, + { + "idx": 1206, + "question": "The characteristics of polycrystalline plastic deformation are (18)ity, (19)ity, and (20)ity.", + "answer": "(18) non-simultaneous; (19) coordinated; (20) non-uniform", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写特定的单词或短语来完成句子，而不是从给定的选项中选择或进行判断。答案需要根据知识储备来填写，属于简答题的范畴。 | 知识层次: 题目考查对多晶塑性变形特性的基础概念记忆，仅需回忆并填写三个特征词汇，无需深入分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆，但需要考生准确回忆并匹配三个不同的特性（非同时性、协调性和非均匀性），这比单纯记忆一个定义或概念要复杂一些。此外，题目采用了填空题的形式，增加了对记忆准确性的要求。不过，由于选项已经给出，考生不需要进行复杂的推理或分析，因此难度仍属于中等水平。" + }, + { + "idx": 3792, + "question": "A Nb-W alloy held at 2800°C is partly liquid and partly solid. If possible, determine the composition of each phase in the alloy.", + "answer": "l: 49% w; α: 70% w", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求确定合金中各相的组成，需要根据相图或相关理论进行分析和解释，答案以文字形式给出各相的组成百分比，属于需要简要回答和解释的题型。 | 知识层次: 题目需要根据相图确定合金在特定温度下的相组成，涉及多步计算和概念关联，需要综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及多步计算和概念关联，要求考生能够理解并应用相图知识来确定合金在不同相中的组成。其次，题目要求综合分析部分液体和部分固体的组成，这需要考生具备较强的逻辑推理能力和计算能力。此外，题目中的温度（2800°C）和组成（Nb-W合金）增加了题目的复杂性，考生需要准确理解相图并正确提取信息。因此，该题目在选择题型内属于多角度分析论述的难度等级。" + }, + { + "idx": 1527, + "question": "Give examples of the basic strengthening forms of materials", + "answer": "The basic strengthening forms of materials include: solid solution strengthening, strain hardening, precipitation strengthening and dispersion strengthening, grain refinement strengthening, etc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举材料的基本强化形式，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对材料强化基本形式的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举材料强化的基本形式，但正确选项已经提供了完整的分类体系（固溶强化、应变硬化、沉淀强化、弥散强化和晶粒细化强化等）。这需要考生对材料强化机制有较全面的概念性理解，而不仅仅是记忆单个定义。题目考察的是对\"基本强化形式\"这一分类体系的掌握程度，属于概念解释和描述的层次，但不需要进行复杂的比较分析或体系阐述。" + }, + { + "idx": 903, + "question": "Term explanation: secondary recrystallization", + "answer": "The phenomenon of abnormal growth of a few grains occurring when normal growth is inhibited after the completion of recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语进行解释，需要文字解释和论述，答案形式为一段文字描述，符合简答题的特征 | 知识层次: 题目考查对\"二次再结晶\"这一基本概念的定义记忆和理解，属于材料科学中基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。虽然题目要求解释\"secondary recrystallization\"这一专业术语，但正确选项提供了明确的定义描述，不需要进行复杂的概念体系阐述或比较分析。学生只需理解并记忆该现象的基本定义即可作答，不需要深入理解其机理或与其他概念的关联。因此，在选择题型内属于中等偏下的难度水平。" + }, + { + "idx": 972, + "question": "How does temperature affect atomic diffusion in metals or alloys?", + "answer": "Temperature follows the relationship D=Doe-Q/RT, where an increase in temperature accelerates diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释温度如何影响金属或合金中的原子扩散，需要文字解释和论述，而不是选择、判断或计算。答案提供了扩散系数与温度的关系，并解释了温度升高对扩散的影响，符合简答题的特征。 | 知识层次: 题目涉及扩散系数与温度关系的公式应用，需要理解阿伦尼乌斯方程中各参数的含义及其物理意义，并能够解释温度变化对扩散速率的影响机制。这属于中等应用层次，需要将基本概念与公式关联起来进行综合分析。 | 难度: 在选择题中属于中等难度，需要理解扩散系数与温度的关系公式D=Doe-Q/RT，并能够综合分析温度变化对扩散速率的影响。题目涉及中等应用层次的知识，要求考生进行概念关联和多步计算，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3827, + "question": "Consider a Al-25% Si alloy. Determine if the alloy is hypo eutectic or hyper eutectic.", + "answer": "hyper eutectic", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过分析合金成分来判断其属于亚共晶还是过共晶，需要文字解释和论述，而不是简单的选择或判断。答案也是以文字形式给出，而非数值计算结果。 | 知识层次: 题目考查对共晶合金分类的基本概念记忆和理解，只需知道Al-Si合金的共晶点成分(12.6% Si)即可判断25% Si属于过共晶(hyper eutectic)，不需要复杂计算或分析过程。 | 难度: 该题目属于基础概念记忆类型，仅需知道Al-Si合金的共晶点（约12.6% Si）即可直接判断25% Si属于过共晶成分。选择题型中无需计算或推导，属于最简单的定义识别类题目。" + }, + { + "idx": 1721, + "question": "What effect does constitutional supercooling have on the solidification structure of alloys?", + "answer": "The occurrence of constitutional supercooling phenomenon will cause multicomponent alloys to develop cellular or dendritic structures even under a positive temperature gradient.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释constitutional supercooling对合金凝固结构的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及合金凝固过程中成分过冷现象对凝固组织的影响，需要理解成分过冷的形成机制及其与凝固组织形貌的关系，属于对材料科学中凝固理论的深入分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目涉及复杂的合金凝固现象，要求考生不仅理解\"成分过冷\"的概念，还需要掌握其对凝固组织的影响机制。正确选项需要综合温度梯度、多组分合金特性以及凝固组织形态学等多方面知识进行推理分析。这种题目在选择题中属于对机理深度解释和复杂现象全面分析要求最高的类型，需要考生具备扎实的理论基础和综合分析能力。" + }, + { + "idx": 3466, + "question": "How is structural steel further subdivided?", + "answer": "Structural steel is divided into: engineering structural steel and mechanical component steel. Engineering structural steel is further divided into: ordinary carbon structural steel and ordinary low-alloy steel. Mechanical component steel is divided into: carburizing steel, quenched and tempered steel, spring steel, and rolling bearing steel.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对结构钢的细分进行文字解释和论述，答案提供了详细的分类和说明，符合简答题的特征。 | 知识层次: 题目考查结构钢的基本分类和子分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个分类和细分概念，但所有信息都集中在结构钢的分类体系上，属于单一知识点的系统性记忆。考生需要准确回忆并匹配不同层级的分类关系，但不需要进行跨概念比较或复杂推理。这比单纯记忆基本定义（等级1）要求更高，但尚未达到需要整合多个复杂概念体系的难度（等级3）。" + }, + { + "idx": 844, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of perfect dislocations in FCC crystals?", + "answer": "Perfect dislocation (relatively rare in actual crystals); 1 <110> 2; screw type, edge type, mixed type; local slip or local displacement; can slip or climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求详细解释和描述FCC晶体中完美位错的多个特征（名称、伯氏矢量、位错性质、形成方法和运动状态），答案提供了详细的文字解释而非单一选项或简单判断，符合简答题的特征。 | 知识层次: 题目考查的是FCC晶体中完美位错的基本概念，包括位错名称、Burgers矢量、位错性质、形成方法和运动状态等记忆性知识，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生记忆并理解FCC晶体中完美位错的基本概念，包括位错名称、伯氏矢量、位错性质、形成方式和运动状态。虽然涉及多个知识点，但都属于基础概念记忆范畴，不需要复杂的分析或比较。题目主要考察对定义和分类的记忆，属于选择题型中的中等难度（等级2）。" + }, + { + "idx": 157, + "question": "For glass No. 1 with the composition of Na2O 8 wt%, Al2O3 12 wt%, and SiO2 80 wt%, use the glass structural parameters to explain the magnitude of its viscosity at high temperatures?", + "answer": "For No. 1: Z=4 Na2O/Al2O3=8.16/7.47>1 Al2O3 is considered as a network-forming ion R=(8.16+7.47×3+84.37×2)/(7.47×2+84.37)=2.007 X1=2R−Z=0.014 Y1=4−X=3.986 Y1=3.986, therefore, the viscosity of No. 1 at high temperatures is high.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用玻璃结构参数来解释高温粘度的大小，答案提供了详细的参数计算和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求运用玻璃结构参数（如Z、R、X1、Y1等）进行多步计算和综合分析，解释高温粘度的变化机理。这需要深入理解玻璃结构参数之间的关系及其对粘度的影响，属于复杂分析和推理的范畴。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求综合运用玻璃结构参数（如Z、R、X1、Y1等）进行复杂计算和推理分析，以解释高温粘度的变化机理。解题步骤涉及多个参数的转换和计算，需要深入理解网络形成离子、网络修饰离子等概念，并能将这些概念与粘度变化机理联系起来。这种综合运用和深度分析的要求在选择题型中属于最高难度等级。" + }, + { + "idx": 3504, + "question": "Compare the compressive strength of HT150 and annealed 20 steel", + "answer": "The tensile strength and hardness of the two are not much different.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求比较两种材料的压缩强度，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求比较两种材料的压缩强度，涉及对材料性能的理解和对比分析，需要综合运用材料科学知识进行多步思考和概念关联，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解HT150和退火20钢的压缩强度特性，并进行比较分析。虽然题目涉及多步计算和概念关联，但在选择题型中，正确选项已经提供了关键比较点，降低了答题的复杂性。" + }, + { + "idx": 1827, + "question": "What type of diffusion problems is Fick's second law applicable to solve?", + "answer": "Non-steady-state diffusion", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释Fick's second law适用的扩散问题类型，答案是一个简短的文字描述而非选择、判断或计算 | 知识层次: 题目考查对Fick第二定律适用范围的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅要求考生记忆并识别Fick's第二定律适用的扩散类型（非稳态扩散），属于基础概念的直接回忆。题目不涉及概念解释或复杂体系分析，仅需从选项中选出正确的基本定义，因此属于最简单的难度等级。" + }, + { + "idx": 4180, + "question": "Give the electron configuration for the ion Cu+.", + "answer": "The electron configuration for a Cu+ ion is 1s2 2s2 2p6 3s2 3p6 3d10.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求给出Cu+离子的电子排布，需要文字解释和论述，而不是从选项中选择或判断对错，也不需要数值计算。 | 知识层次: 题目考查对电子排布基本概念的记忆和理解，仅需直接回忆铜离子(Cu+)的电子构型，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求记忆铜离子(Cu+)的电子排布，但需要掌握过渡金属离子的电子排布特点，特别是铜的例外情况（4s电子先填充但3d轨道未填满）。这超出了简单的定义记忆，需要对电子排布规则有一定理解和应用能力。" + }, + { + "idx": 1458, + "question": "For metals that have undergone pre-cold plastic deformation, recrystallization annealing should be performed before further cold plastic deformation, and the annealing temperature is (46)", + "answer": "0.4Tm", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的数值（0.4Tm）作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。这符合简答题的特征，即需要提供简短而具体的答案。 | 知识层次: 题目考查对金属再结晶退火温度的基本概念记忆，即0.4Tm这一特定数值的掌握，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需记住\"再结晶退火温度应为0.4Tm\"这一简单定义即可作答。在选择题型中，这种直接考查单一知识点的题目属于最低难度等级，不需要任何解释或分析过程，完全基于记忆性知识。" + }, + { + "idx": 1034, + "question": "Compositional supercooling", + "answer": "Compositional supercooling: During the solidification of an alloy solution, the theoretical solidification temperature remains unchanged, and the degree of supercooling is entirely determined by the distribution of solute components. This type of supercooling is called compositional supercooling.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Compositional supercooling\"进行文字解释和论述，答案提供了详细的定义和说明，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，即compositional supercooling的定义和基本原理，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解并描述\"compositional supercooling\"的定义和基本原理。题目要求考生不仅知道这个术语，还要能够解释其背后的物理机制（如固溶体凝固过程中溶质分布对过冷度的影响）。这比简单的定义识别（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 3000, + "question": "What are the usage states corresponding to these mechanical states?", + "answer": "(5)Plastic; (6)Rubber; (7)Flow resin", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释机械状态对应的使用状态，答案需要文字描述而非选择或计算 | 知识层次: 题目考查对材料在不同机械状态下对应使用状态的基础概念记忆，如塑性、橡胶态和流动树脂态，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基本定义简答的难度等级。题目仅要求考生记忆并匹配机械状态与对应的使用状态（塑料、橡胶、流动树脂），属于基础概念记忆层次，无需复杂推理或分析。正确选项直接对应定义，解题步骤简单明了。" + }, + { + "idx": 456, + "question": "Can the perfect dislocation $\\pmb{b}_{1}$ in a face-centered cubic crystal decompose into partial dislocations $b_{2}, b_{3}?$ Given ${\\pmb b}_{1}=\\frac{a}{2}[\\stackrel{-}{1}10], {\\pmb b}_{2}=\\frac{a}{6}[\\stackrel{-}{1}2\\stackrel{-}{1}], {\\pmb b}_{3}=\\frac{a}{6}[\\stackrel{-}{2}11],$ state the reasons.", + "answer": "Geometric condition: $\\begin{array}{l}{{\\vec{b}_{1}=a/2\\cdot\\left[\\stackrel{\\rightharpoonup}{1}10\\right]}}\\ {{}}\\ {{\\vec{b}_{2}+\\stackrel{\\rightharpoonup}{b}_{3}=a/6\\cdot\\left[\\stackrel{\\rightharpoonup}{3}30\\right]=a/2\\cdot\\left[\\stackrel{\\rightharpoonup}{1}10\\right]}}\\end{array}$ Energy condition: $\\mid\\vec{b}_{1}\\mid^{2}=(a/2\\sqrt{1+1+0})^{2}=a^{2}/2$ $|\\vec{b}_{2}|^{2}+|\\vec{b}_{3}|^{2}=(a/6\\sqrt{1+4+1})^{2}+\\bigl(a/6\\sqrt{4+1+1}^{2}=a^{2}/3 and {10-10}<11-20>, and the possible slip directions are all perpendicular to [0001], so slip does not occur in this case; c/a=1.62<√3, so [0001] is in the obtuse angle region of K1 and K2, and twinning will increase during deformation. Therefore, twinning occurs when stretched along the [0001] direction, and twinning changes the crystal orientation, which may further lead to slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释镁单晶在[0001]方向拉伸时的变形模式，答案提供了详细的文字解释和论述，包括滑移系统和孪生的条件分析，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析镁单晶在特定拉伸方向下的变形模式，涉及滑移和孪生机制的对比、晶体学方向的分析以及变形过程中晶体取向变化的推理。这需要综合运用材料科学中的晶体塑性理论、滑移系统分析以及孪生条件判断，属于对多个概念的深度理解和复杂推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用镁单晶的滑移和孪生机制知识，分析特定拉伸方向[0001]下的变形模式。解题需要深入理解晶体学方向、临界分切应力比较、滑移系几何限制（方向垂直性）以及c/a比值对孪生倾向的影响等多重因素，最后还需推理变形过程中晶体取向变化的二次效应。这种需要多维度机理交叉分析且包含因果链推理的题目，在选择题中属于最复杂的考查类型。" + }, + { + "idx": 1996, + "question": "What is the difference between a space lattice and a crystal lattice?", + "answer": "A crystal lattice, also known as a crystal structure, refers to the specific arrangement of atoms; whereas a space lattice abstracts atoms as pure geometric points by ignoring their volume.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两个概念之间的区别，答案需要文字论述和解释，没有提供选项或要求判断对错或进行数值计算。 | 知识层次: 题目考查对空间点阵和晶体点阵这两个基本概念的定义和区别的记忆和理解，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个相关概念（空间点阵和晶体点阵）的比较，但正确选项提供了清晰的定义和区分，不需要复杂的推理或深入的概念体系理解。主要考察的是对基础概念的记忆和简单解释能力，符合等级2“概念解释和描述”的要求。" + }, + { + "idx": 4515, + "question": "For the following pair of polymers, do the following: (1) state whether or not it is possible to determine whether one polymer has a higher melting temperature than the other; (2) if it is possible, note which has the higher melting temperature and then cite reason(s) for your choice; and (3) if it is not possible to decide, then state why. Isotactic polystyrene that has a density of 1.12 g/cm3 and a weight-average molecular weight of 150,000 g/mol; syndiotactic polystyrene that has a density of 1.10 g/cm3 and a weight-average molecular weight of 125,000 g/mol", + "answer": "Yes, it is possible to determine which of the two polystyrenes has the higher Tm. The isotactic polystyrene will have the higher melting temperature because it has a higher density (i.e., less branching) and also the greater weight-average molecular weight.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，包括判断可能性、比较熔点高低并给出理由，或说明无法决定的原因。答案需要详细的文字说明而非简单选择或计算。 | 知识层次: 题目要求比较两种聚合物的熔点，并解释原因。这涉及到对聚合物结构（等规和间规）、密度和分子量对熔点影响的理解和应用。虽然不需要复杂的计算或深入机理分析，但需要综合多个因素进行判断和解释，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解聚合物的立体规整性（等规与间规）对熔点的影响，还需要综合考虑密度（反映分子链堆积紧密程度）和分子量这两个因素对熔点的复合影响。需要考生进行多角度分析（立体构型+密度+分子量）并正确判断各因素的优先级（立体构型影响>密度影响>分子量影响），最后得出综合结论。这种需要同时处理多个变量并理解其相互作用关系的题目，在选择题型中属于较复杂的综合分析题。" + }, + { + "idx": 2501, + "question": "What is the crystal structure of diamond?", + "answer": "The crystal structure of diamond is FCC with tetrahedral interstices, where carbon atoms are located at the bonding points of the FCC lattice and four non-adjacent tetrahedral interstice positions.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释钻石的晶体结构，答案需要详细的文字描述和论述，而不是从选项中选择或简单的对错判断。 | 知识层次: 题目考查对金刚石晶体结构这一基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并描述金刚石的晶体结构（FCC晶格和四面体间隙位置）。这比简单的定义记忆（等级1）要求更高，但尚未达到复杂概念体系阐述（等级3）的程度。考生需要掌握FCC晶格和四面体间隙的基本知识，并能正确描述碳原子的位置分布。" + }, + { + "idx": 4389, + "question": "Cite three characteristics of ferrous alloys that limit their utilization.", + "answer": "Disadvantages of ferrous alloys are: (1) They are susceptible to corrosion. (2) They have a relatively high density. (3) They have relatively low electrical conductivities.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举铁基合金的三个限制其应用的特性，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对铁基合金基本特性的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目要求考生回忆并列举铁基合金的三个限制性特征，属于概念解释和描述层次。虽然需要记忆多个特点，但都属于基础概念记忆范畴，无需复杂分析或比较。" + }, + { + "idx": 3183, + "question": "Explain the concept of undercooling", + "answer": "The temperature difference between the actual crystallization temperature and the theoretical crystallization temperature is called the undercooling (ΔT=Tm−Tn). It is required by the thermodynamic conditions of phase transformation. Only when ΔT>0 can the condition that the free energy of the solid phase is lower than that of the liquid phase be achieved. The free energy difference between the liquid and solid phases is the driving force for crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"undercooling\"的概念，答案提供了详细的文字解释和论述，包括定义、公式和热力学条件的说明，符合简答题的特征。 | 知识层次: 题目主要考查对undercooling这一基础概念的定义和基本原理的记忆与理解，涉及温度差和自由能差等基本概念，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释过冷的概念，并涉及基本的温度差和热力学条件，但不需要复杂的分析或比较多个概念。正确选项提供了清晰的定义和基本原理，属于中等难度的选择题。" + }, + { + "idx": 381, + "question": "The driving force for solid-state phase transformation is (10), while the resistances are (11) and (12).", + "answer": "(10) free energy difference between new and old phases; (11) interface energy; (12) strain energy", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的术语或概念，而不是从选项中选择或判断对错，也不需要计算。答案需要简要的文字解释，符合简答题的特征。 | 知识层次: 题目考查对固态相变驱动力和阻力的基本概念记忆，包括自由能差、界面能和应变能等基础概念的理解和识别 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目直接考察学生对固态相变驱动力和阻力的基础概念记忆，只需识别并匹配正确的术语（自由能差、界面能、应变能）即可，无需进行概念解释或复杂分析。" + }, + { + "idx": 1309, + "question": "A decrease in $r^{}$ means the number of nucleation sites (4).", + "answer": "increases", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个单词（increases）来回答问题，属于简短的文字回答形式，不需要计算或选择选项 | 知识层次: 题目考查的是对成核位点与半径关系的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，此题仅涉及基础概念记忆，即对\"$r^{}$\"与成核位点数量关系的定义性知识。题目仅要求识别正确选项\"increases\"，无需解释或分析过程，属于最基础的定义简答层级。" + }, + { + "idx": 2579, + "question": "Can inserting an additional columnar half-atom plane in a crystal form a dislocation loop? Why?", + "answer": "A dislocation loop cannot be formed. Assuming a dislocation loop could form, it would consist entirely of edge dislocations. According to l⊥b, the Burgers vector $\\pmb{b}$ at each point of the loop should be along the radial direction, meaning the $\\pmb{b}$ at different points on the loop would vary. This contradicts the fact that a single dislocation line has only one $\\pmb{b}$.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么插入额外的柱状半原子平面不能形成位错环，需要文字论述和理论依据，而不是简单的选择、判断或计算。 | 知识层次: 题目涉及位错环的形成机制和伯格斯矢量的方向性分析，需要综合运用位错理论和晶体学知识进行推理和解释，思维过程较为深入。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求综合运用晶体缺陷理论（特别是位错环的形成机制）、Burgers向量的性质以及几何分析能力。解题时需要：" + }, + { + "idx": 2212, + "question": "When cold-drawn copper wires are used as overhead conductors (requiring certain strength), what final heat treatment process should be adopted?", + "answer": "Stress relief annealing (low-temperature annealing) should be adopted.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释应采取何种最终热处理工艺，答案需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求根据具体应用场景（冷拉铜线作为架空导线）选择适当的热处理工艺，需要理解材料性能与工艺之间的关系，并进行综合分析。虽然答案较为直接，但需要将材料科学原理与实际应用相结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解铜线作为架空导体的应用场景及其强度要求，并关联到适当的热处理工艺。虽然题目涉及多步概念关联和综合分析，但在选择题型中，通过排除法可以缩小选项范围，降低解题难度。" + }, + { + "idx": 4188, + "question": "Determine whether the electron configuration (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{7} 4 s^{2}) is an inert gas, a halogen, an alkali metal, an alkaline earth metal, or a transition metal. Justify your choice.", + "answer": "The (1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{7} 4 s^{2}) electron configuration is that of a transition metal because of an incomplete (d) subshell.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求根据电子排布判断元素类别，并需要文字解释和论述来证明选择。答案提供了详细的理由说明，符合简答题的特征。 | 知识层次: 题目考查对电子构型与元素分类之间关系的基本概念记忆和理解，只需根据给定的电子构型判断元素类别，并简单解释原因，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目需要考生理解电子排布的基本概念，并能根据给定的电子排布判断元素的类别。虽然涉及过渡金属的定义，但解题步骤相对直接，只需识别d亚层未填满这一关键特征即可。相较于等级1的简单定义记忆，该题目要求稍高的概念理解和应用能力，但不需要复杂的分析或比较，因此属于中等难度。" + }, + { + "idx": 4455, + "question": "For refractory ceramic materials, cite three characteristics that improve with increasing porosity.", + "answer": "For refractory ceramic materials, three characteristics that improve with increasing porosity are (1) decreased thermal expansion and contraction upon thermal cycling, (2) improved thermal insulation, and (3) improved resistance to thermal shock.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举并解释三个特性，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查对耐火陶瓷材料特性的基本记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求列举三个特性，但这些都是与多孔耐火陶瓷材料相关的基础概念，属于记忆性知识。考生需要理解并记住这些特性，但不需要进行复杂的分析或推理。因此，难度等级为2。" + }, + { + "idx": 1194, + "question": "The typical crystal structures of metals are (1), (2), and (3)", + "answer": "(1) body-centered cubic; (2) face-centered cubic; (3) close-packed hexagonal", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写金属的典型晶体结构名称，答案需要以文字形式提供具体结构名称，属于简答题类型 | 知识层次: 题目考查金属典型晶体结构的基础概念记忆，仅需回忆和列举三种常见结构类型，不涉及应用或分析。 | 难度: 该题目属于基础概念记忆类型，仅需回忆金属的三种典型晶体结构名称（体心立方、面心立方和密排六方）。在选择题型中，这种直接考察定义或分类的记忆性知识属于最低难度等级，无需解释或分析步骤。" + }, + { + "idx": 794, + "question": "1. Briefly describe the characteristics of grain growth and secondary recrystallization, as well as the causes of secondary recrystallization and methods to prevent it.", + "answer": "Characteristics of grain growth: Grain growth is a process in which the average grain size of a strain-free material continuously increases during heat treatment without changing its distribution. The grain size grows uniformly within the body; during grain growth, pores remain at grain boundaries or grain boundary intersections. Characteristics of secondary recrystallization: It is an abnormal growth process where a few large grains grow at the expense of fine grains. It involves the abnormal growth of individual grains; during secondary recrystallization, pores are trapped inside the grains; secondary recrystallization is also related to the particle size of the raw material. Causes of secondary recrystallization: Non-uniform particle size of the raw material, excessively high sintering temperature, and too fast sintering rate. Methods to prevent secondary recrystallization: Control sintering temperature and time, ensure uniformity of raw material particle size, and introduce sintering additives.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要描述晶粒生长和二次再结晶的特征、二次再结晶的原因及防止方法，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目要求描述晶粒生长和二次再结晶的特征，分析二次再结晶的原因及预防方法，涉及多个概念的关联和综合分析，需要理解并应用相关知识进行解释和论述，但不需要进行复杂的推理或创新设计。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解晶粒生长和二次再结晶的特征，还需要分析二次再结晶的原因及预防方法。这涉及多个概念的关联和综合分析，需要考生具备较深的知识掌握和逻辑推理能力。" + }, + { + "idx": 332, + "question": "What are the morphological differences between typical metals (such as iron) and typical non-metals (such as silicon, graphite) when grown individually in the liquid phase?", + "answer": "Because they are rough interface (iron) and smooth interface (silicon, etc.) respectively, the former forms uniform equiaxed crystals or dendrites, while the latter forms regular polygons with angular shapes.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释金属和非金属在液相生长时的形态差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释金属和非金属在液相生长时的形态差异，涉及界面粗糙度与晶体形态的关联分析，需要理解并应用材料科学中的界面理论和晶体生长原理，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解金属（如铁）和非金属（如硅、石墨）在液相生长时的形态差异，这涉及多个材料科学的核心概念。其次，正确选项不仅需要考生识别粗糙界面和平滑界面的区别，还需要进一步关联这些界面特性与晶体形态（如等轴晶、枝晶、规则多边形）之间的关系。这种多步骤的概念关联和综合分析能力在选择题中属于较高要求。此外，题目还隐含了对材料生长机制的深入理解，进一步提升了难度。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 4871, + "question": "For the MgO-Al2O3 system, at what composition or over what range of compositions will this maximum temperature be achieved?", + "answer": "This maximum temperature is possible for pure MgO.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在MgO-Al2O3系统中达到最高温度的具体组成或组成范围，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解MgO-Al2O3系统的相图特性，并能够分析特定组成下的温度变化趋势，涉及多步概念关联和综合分析。 | 难度: 在选择题中属于中等难度，需要理解MgO-Al2O3系统的相图和相关热力学概念，并进行综合分析。题目要求考生识别在特定系统中达到最高温度的条件，这需要将多个知识点关联起来，并应用相图知识进行判断。虽然题目给出了正确选项，但解题过程仍需要一定的概念理解和分析能力。" + }, + { + "idx": 740, + "question": "What are the two types of arrangements in the closest packing of equal-sized spheres?", + "answer": "(2) Cubic close packing; (3) Hexagonal close packing", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求列举两种最密堆积方式，需要文字解释和论述，而不是从选项中选择或判断对错 | 知识层次: 题目考查对等径球最密堆积两种排列方式的基础概念记忆，属于材料科学中最基本的晶体结构知识，仅需回忆和识别两种类型（立方最密堆积和六方最密堆积），不涉及应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆两种最密堆积方式的名称（立方最密堆积和六方最密堆积），属于基础概念的直接回忆，无需解释或分析步骤，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2514, + "question": "Discuss the significance of atomic radius in metal crystals and its influencing factors, and provide examples for illustration", + "answer": "For metal crystals, the atomic radius is defined as half the distance between the nuclei of nearest-neighbor atoms in the crystal of the same element. In metal crystals, the coordination number affects the atomic radius. For example, α-Fe (CN=8) has an atomic radius 3% smaller than that of γ-Fe (CN=12). Generally, the atomic radius for CN=12 is used.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论金属晶体中原子半径的重要性及其影响因素，并提供示例进行说明。答案以文字解释和论述的形式呈现，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求讨论原子半径在金属晶体中的重要性及其影响因素，并提供实例说明。这需要理解原子半径的定义、协调数对原子半径的影响，以及不同晶体结构（如α-Fe和γ-Fe）之间的比较。虽然涉及基础概念，但需要将这些概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型内，该题目要求考生不仅理解原子半径的基本定义，还需要掌握配位数对原子半径的影响，并能通过具体例子（α-Fe和γ-Fe）进行多角度分析。此外，题目还涉及不同配位数下原子半径的通用标准，需要考生进行综合论述和比较分析，因此属于较高难度等级。" + }, + { + "idx": 2073, + "question": "Point out the errors in the following concepts and correct them: (18) When a nucleation agent is added to liquid pure metal, its growth morphology always appears dendritic.", + "answer": "Its growth morphology will not change.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念错误并进行修正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对成核剂添加后金属生长形态变化的基本概念的理解和记忆，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解成核剂对纯金属生长形态的影响，并能够识别和纠正错误概念。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 2145, + "question": "Point out the error in the following concept: (2) Because the direction of each jump of solid atoms is random, the diffusion flux is zero under any circumstances.", + "answer": "The direction of each jump of atoms is random. Only when the system is in thermal equilibrium, the probability of atoms jumping in any direction is equal. At this time, although there is atomic migration (i.e., diffusion), there is no macroscopic diffusion flow. If the system is in a non-equilibrium state, there must be a gradient of thermodynamic potential in the system (specifically expressed as concentration gradient, chemical potential gradient, strain energy gradient, etc.). The probability of atoms jumping in the direction of decreasing thermodynamic potential will be greater than that in the direction of increasing thermodynamic potential. As a result, macroscopic diffusion flow occurs.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求指出概念中的错误并进行详细的文字解释和论述，答案形式为一段完整的论述性文字，而非选择、判断或计算。 | 知识层次: 题目要求对扩散现象进行深入分析，涉及非平衡态热力学、概率统计和宏观扩散流的关系，需要综合运用多个概念并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 938, + "question": "What is secondary banded structure?", + "answer": "Secondary banding is a product of solid-state transformation. Under nitric acid alcohol etching, the white bands are proeutectoid ferrite, and the black bands are pearlite, also known as micro banded structure. Secondary banding only occurs on the basis of primary banding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释\"secondary banded structure\"的概念，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对二次带状结构这一基本概念的定义和特征的理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生不仅记住\"secondary banded structure\"的定义，还要理解其形成机制（固态转变产物）、在特定条件下的表现（硝酸酒精腐蚀后的白黑带）以及与primary banding的关系。这些内容超出了简单的定义记忆，需要对概念进行一定程度的解释和描述，但尚未达到需要阐述复杂概念体系的难度。" + }, + { + "idx": 693, + "question": "Summarize the role of dislocations in materials", + "answer": "Dislocations can greatly influence the performance of materials, and their roles in materials are diverse: (1) The plastic deformation of metallic materials is accomplished through dislocation motion. (2) Dislocations have a distorted stress field around them, which can strengthen materials through mechanisms such as cutting or bypassing second-phase particles. Increasing dislocation density during cold working can also strengthen materials, as can the formation of Cottrell atmospheres. Additionally, mutual intersections during dislocation motion or the formation of jogs and Lomer-Cottrell locks can strengthen materials, thereby affecting their strength. (3) Dislocations influence the precipitation of second phases and have an impact on solid-state phase transformations such as nucleation mechanisms during recrystallization. (4) The areas around dislocations serve as preferential diffusion pathways.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对位错在材料中的作用进行总结和论述，答案以文字解释和列举要点的方式呈现，符合简答题的特征。 | 知识层次: 题目要求对位错在材料中的多种作用进行综合分析和解释，涉及位错运动、应力场、强化机制、相变和扩散等多个方面的知识，需要深入理解和关联不同概念，并进行综合论述。 | 难度: 在选择题型中，该题目属于最高难度等级。正确选项不仅要求考生全面掌握位错在材料中的多种作用机制（包括塑性变形、强化机制、相变影响和扩散路径），还需要将这些复杂现象进行综合分析和机理解释。题目涉及多个高阶材料科学概念的交叉运用，且每个作用机制都需要深入理解其物理本质，这远超出简单记忆或单一概念应用的难度水平。在选择题型内，此类需要综合多个复杂机理进行推理判断的题目属于最难级别。" + }, + { + "idx": 105, + "question": "Taking the dissolution of solute A0 in solvent B2O3 as an example, compare the chemical compositions of solid solutions, compounds, and mechanical mixtures.", + "answer": "
Comparison itemSolid solutionCompoundMechanical mixture
Chemical compositionB2xAxO X （x=0~2）AB2O4AO+B2O3
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求比较固体溶液、化合物和机械混合物的化学成分，并以表格形式展示答案，这需要文字解释和论述，而非选择、判断或计算。 | 知识层次: 题目要求比较固体溶液、化合物和机械混合物的化学组成，涉及多个概念的关联和综合分析，需要理解不同物质状态下的化学组成变化，并进行对比分析。这超出了单纯记忆基础概念的层次，属于中等应用水平。 | 难度: 在选择题型中，该题目要求考生不仅理解固体溶液、化合物和机械混合物的基本概念，还需要能够比较它们的化学组成。题目通过表格形式呈现了三种不同物质类型的化学组成，要求考生能够识别并区分这些组成。这涉及到多步的概念关联和综合分析，属于较高难度的选择题。此外，题目还涉及中等应用层次的知识，需要考生具备一定的化学组成分析和比较能力。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 2542, + "question": "Discuss the general rules of oxide structures.", + "answer": "An important characteristic of oxide structures is the close packing of oxygen ions. In most simple oxide structures, oxygen ions are arranged in face-centered cubic, hexagonal close-packed, or approximately close-packed simple cubic configurations, while the cations occupy octahedral interstitial sites, tetrahedral interstitial sites, or the body center of the simple cubic lattice.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求讨论氧化物结构的一般规则，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对氧化物结构基本规则的理解和记忆，涉及氧离子的紧密堆积方式及阳离子占据的间隙位置等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及氧化物结构的基本规则，但正确选项需要考生理解并记忆氧离子的紧密堆积方式（如面心立方、六方紧密堆积等）以及阳离子占据的间隙位置（如八面体间隙、四面体间隙等）。这超出了简单的定义记忆，需要对相关概念有一定的理解和描述能力。然而，题目并未要求考生进行复杂的比较分析或推导，因此难度等级为2。" + }, + { + "idx": 2418, + "question": "Two parallel low-angle tilt boundaries have misorientation angles of 6 and degrees, respectively. Is it possible for these two boundaries to merge into a single boundary with a misorientation angle of $\\\\theta_{1}+\\\\theta_{2}$?", + "answer": "The energy of a low-angle grain boundary is $$ \\\\gamma_{_\\\\mathrm{\\\\scriptsize{ab}}}=\\\\gamma_{_0}\\\\theta(\\\\mathcal{A}^{\\\\mathrm{\\\\scriptsize{r}}}-\\\\ln\\\\theta) $$ where $M^{\\\\prime}$ is a constant. The energy before the merging of the two boundaries is $$ \\\\gamma_{\\\\bar{0}}\\\\theta_{\\\\bar{1}}(A^{\\\\prime}-\\\\ln\\\\theta_{1})+\\\\gamma_{\\\\bar{0}}\\\\theta_{\\\\bar{z}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\bar{z}}) $$ The energy after merging is: $$ \\\\gamma_{\\\\mathrm{o}}(\\\\theta_{\\\\mathrm{i}}+\\\\theta_{\\\\mathrm{z}})[A^{\\\\prime}-\\\\mathrm{ln}(\\\\theta_{\\\\mathrm{i}}+\\\\theta_{\\\\mathrm{z}})] $$ The energy difference $\\\\bar{A}E$ before and after merging is: $$ \\\\begin{array}{r l}&{\\\\Delta E=\\\\gamma_{\\\\mathrm{0}}(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})[A^{\\\\prime}-\\\\ln(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})]-\\\\gamma_{\\\\mathrm{0}}\\\\theta_{\\\\mathrm{1}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\mathrm{1}})-\\\\gamma_{\\\\mathrm{0}}\\\\theta_{\\\\mathrm{2}}(A^{\\\\prime}-\\\\ln\\\\theta_{\\\\mathrm{2}})} &{\\\\qquad=\\\\gamma_{\\\\mathrm{0}}A^{\\\\prime}(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}-\\\\theta_{\\\\mathrm{1}}-\\\\theta_{\\\\mathrm{2}})-\\\\gamma_{\\\\mathrm{0}}[(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})\\\\ln(\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}})-\\\\theta_{\\\\mathrm{1}}\\\\ln\\\\theta_{\\\\mathrm{1}}-\\\\theta_{\\\\mathrm{2}}\\\\ln\\\\theta_{\\\\mathrm{2}}]} &{\\\\qquad=\\\\gamma_{\\\\mathrm{0}}[\\\\theta_{\\\\mathrm{1}}\\\\ln\\\\frac{\\\\theta_{\\\\mathrm{1}}}{\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}}+\\\\theta_{\\\\mathrm{2}}\\\\ln\\\\frac{\\\\theta_{\\\\mathrm{2}}}{\\\\theta_{\\\\mathrm{1}}+\\\\theta_{\\\\mathrm{2}}}]}\\\\end{array} $$ Because $y=\\\\frac{1}{2}$ $C A$ and $C H_{2}$ are both positive, $\\\\left|\\\\Pi\\\\right|\\\\left|\\\\hat{H}_{l}\\\\right|\\\\left|\\\\hat{H}_{1}+\\\\hat{H}_{2}\\\\right|\\\\right|$ and $\\\\|\\\\bar{\\\\boldsymbol{\\\\Pi}}\\\\|\\\\hat{\\\\cal{Q}}^{\\\\prime}(\\\\hat{\\\\cal{Q}}_{1}+\\\\hat{\\\\cal{Q}}_{2})\\\\|$ are both less than 0. This process reduces energy, so it can proceed. In fact, during the recovery process of deformed materials, a large number of such processes occur, namely the coarsening of subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过文字解释和论述来回答问题，答案中包含了详细的公式推导和能量变化的分析，属于需要论述和解释的简答题类型。 | 知识层次: 题目涉及低角度晶界的能量计算和合并过程的能量变化分析，需要综合运用晶界能量公式、对数运算和能量差计算，并进行机理解释。思维过程要求较高的分析能力和对材料恢复过程的理解。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3131, + "question": "Explain the basic concept and terminology: Modification treatment", + "answer": "Modification treatment: Before casting metal or alloy, adding certain solid-phase substances that can promote heterogeneous nucleation or hinder the growth of crystal nuclei into the molten metal to refine the grains of the casting is called modification treatment.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释基本概念和术语，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查基本概念的记忆和理解，要求解释\"Modification treatment\"的定义和基本原理，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求解释\"Modification treatment\"的基本概念和术语，正确选项提供了明确的定义和基本原理，但不需要进行复杂的概念体系阐述或多概念比较分析。该题目主要考察对单一概念的记忆和理解，符合选择题型中中等难度的要求。" + }, + { + "idx": 1195, + "question": "Analyze the changes in dislocations during the high-temperature recovery stage and their impact on properties", + "answer": "During the high-temperature recovery stage, the kinetic conditions for dislocation motion are more sufficient, involving both slip and climb, which leads to a tendency for the dislocation densities on multiple slip planes to become equal. The interactions between dislocations cause the dislocations on the same slip plane to distribute uniformly with roughly equal spacing, forming regularly arranged dislocation walls perpendicular to the slip plane, a process known as polygonization. The dislocation walls formed by polygonization are small-angle grain boundaries, which divide the original grain into several subgrains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析高温回复阶段位错的变化及其对性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求分析高温回复阶段位错的变化及其对性能的影响，涉及位错运动、多边形化过程、小角度晶界形成等多个复杂概念的综合运用和机理解释，需要深入理解和推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解高温回复阶段位错运动的动力学条件（滑移和攀移），并分析其对多滑移面位错密度均衡化的影响。需要掌握位错相互作用导致的均匀分布机制，以及多边形化形成小角度晶界的完整过程。这些内容涉及复杂现象的综合分析和机理深度解释，远超一般选择题的概念识别层面，需要考生具备将多个高阶概念整合推理的能力。" + }, + { + "idx": 2435, + "question": "How is texture formed in crystals?", + "answer": "A crystal is a three-dimensionally periodic ordered arrangement, which has a certain orientation relative to a reference coordinate. The orientations of the grains in a polycrystal have an orientation distribution relative to the reference coordinate. If the orientation distribution of the polycrystal deviates from a random distribution, texture is formed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释晶体中织构的形成过程，答案提供了详细的文字解释和论述，没有涉及选项选择、判断对错或数值计算。 | 知识层次: 题目考查晶体织构形成的基本概念和定义，主要涉及记忆和理解晶体取向分布与织构形成的关系，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及晶体结构的基本概念，但正确选项不仅需要记忆晶体的定义，还需要理解多晶体中晶粒取向分布与随机分布偏离时形成织构的概念。这超出了简单的定义记忆，属于概念解释和描述的层次。" + }, + { + "idx": 3424, + "question": "Which of these elements can form infinite solid solutions with Fe? What are the conditions?", + "answer": "Manganese, nickel, and cobalt can form infinite solid solutions with γ-Fe. Whether alloying elements expand or contract the γ region mainly depends on factors such as their lattice type, atomic size, electronic structure, and electrochemical properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释哪些元素可以与Fe形成无限固溶体，并说明条件，需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目不仅需要记忆哪些元素能与γ-Fe形成无限固溶体，还需要理解并解释形成条件（如晶格类型、原子尺寸、电子结构等），涉及多个概念的关联和综合分析。 | 难度: 在选择题中属于较高难度，需要考生掌握γ-Fe的晶体结构特性，理解无限固溶体的形成条件，并能综合分析合金元素对γ相区的影响因素（晶格类型、原子尺寸、电子结构等）。题目不仅考察单一知识点，还要求将多个材料科学概念关联起来进行判断，属于多角度分析论述的层次。" + }, + { + "idx": 483, + "question": "8. Intermetallic compounds typically include what controlled by electronegativity, close-packed phases primarily governed by atomic size, and what mainly controlled by electron concentration?", + "answer": "Normal valence compounds, topologically close-packed phases, electron compounds", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求通过文字解释和论述来回答关于金属间化合物的不同类型及其控制因素的问题，答案形式为简短的文字描述而非选择或判断。 | 知识层次: 题目考查对金属间化合物分类的基本概念记忆，包括电负性控制的正价化合物、原子尺寸控制的密排相和电子浓度控制的电子化合物。这些都属于材料科学中基础的定义和分类知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个概念（金属间化合物的分类及其控制因素），但正确选项直接对应题干中的三个空，属于概念解释和描述层面的知识。考生需要记忆并理解这些基本分类原则，但不需要进行复杂的分析或推导。" + }, + { + "idx": 1324, + "question": "Dendritic segregation", + "answer": "Dendritic segregation: It is a type of microsegregation in materials, where under non-equilibrium cooling conditions, the newly formed solid solution grains after a homogeneous transformation exhibit non-uniform composition within. The initially crystallized core contains more high-melting-point component atoms, while the later crystallized outer regions contain more low-melting-point component atoms. Typically, solid solution crystals grow in a dendritic manner, resulting in the dendrite arms containing more high-melting-point components and the interdendritic regions containing more low-melting-point component atoms. This leads to compositional inhomogeneity within the same grain.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对\"Dendritic segregation\"进行详细的文字解释和论述，答案提供了概念定义、形成机制和具体表现等详细说明，符合简答题的特征。 | 知识层次: 题目考查的是对\"Dendritic segregation\"这一基本概念的定义和描述，属于材料科学中关于微观偏析的基础知识。答案主要涉及对现象的定义、形成原因和特征的记忆性解释，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对\"枝晶偏析\"的定义、形成原因及其在材料中的具体表现有较为全面的理解。题目不仅要求记忆定义，还需要理解非平衡冷却条件下固溶体晶粒的成分不均匀性及其与枝晶生长方式的关系。这种程度的描述性解释在选择题中属于概念解释和描述级别，比单纯的定义简答（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 2079, + "question": "Point out the errors in the following concepts and correct them: (20) From a macroscopic perspective, if the liquid-solid interface is straight, it is called a smooth interface structure; if it is zigzag like metal, it is called a rough interface structure.", + "answer": "The straight one is called a rough interface structure; the zigzag one is called a smooth interface structure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念错误并进行修正，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查的是对液体-固体界面结构的基本概念的记忆和理解，即区分平滑界面结构和粗糙界面结构的定义。虽然需要纠正错误概念，但整体上仍属于基础概念的记忆和简单应用范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对\"平滑界面结构\"和\"粗糙界面结构\"的定义有准确的理解，并能识别出题目中给出的错误描述。这比单纯记忆定义（等级1）要求更高，需要考生能够辨别概念的正误并进行修正，但不需要进行复杂的体系阐述（等级3）。" + }, + { + "idx": 4318, + "question": "Cite one undesirable consequence of coring.", + "answer": "One undesirable consequence of a cored structure is that, upon heating, the grain boundary regions will melt first and at a temperature below the equilibrium phase boundary from the phase diagram; this melting results in a loss in mechanical integrity of the alloy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用文字解释和论述一个不良后果，答案提供了详细的文字描述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释偏析现象的一个不良后果，涉及对相图的理解、晶界行为的分析以及机械性能变化的推理，需要综合运用多个知识点并进行机理层面的解释。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 454, + "question": "What is a smooth interface?", + "answer": "Smooth interface: It is another type of solid-liquid interface where the atoms on the solid-phase interface are arranged into a flat atomic plane, specifically a certain crystallographic plane.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对“smooth interface”进行文字解释和论述，答案提供了详细的定义和描述，符合简答题的特征。 | 知识层次: 题目考查对平滑界面这一基本概念的定义和特征的理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆和识别“smooth interface”的基本定义，属于基础概念记忆层次。正确选项直接给出了定义，没有涉及复杂的概念体系或需要推理分析的内容，因此属于最简单的难度等级。" + }, + { + "idx": 147, + "question": "What are the crystallochemical factors affecting the glass formation process?", + "answer": "The crystallochemical factors affecting glass formation include: the size and arrangement of complex anion groups, bond strength, and bond type.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述影响玻璃形成的结晶化学因素，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对玻璃形成过程中结晶化学因素的综合分析，需要理解并关联多个概念（如复杂阴离子基团的尺寸和排列、键强度和键类型），并进行一定程度的解释和论述。这超出了单纯记忆基础概念的层次，但尚未达到复杂分析或高级综合的深度。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及玻璃形成过程中的结晶化学因素，包括复杂阴离子基团的大小和排列、键强度和键类型等概念。虽然不需要多步计算，但需要对多个概念进行关联和综合分析，才能正确理解并选择答案。" + }, + { + "idx": 3874, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 800^{\\circ} C for 1h, quenched to 350^{\\circ} C and held for 750s, and finally quenched to room temperature.", + "answer": "HRC =47 and the microstructure is all baninite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目需要理解钢的热处理过程及其对硬度和微观结构的影响，涉及多步热处理工艺（加热、淬火、保温、再淬火）的综合分析，以及对所得贝氏体组织和硬度的判断。这要求考生能够将热处理工艺参数与材料性能变化关联起来，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 1997, + "question": "How are jogs generally formed on dislocation lines?", + "answer": "Intersection of dislocations.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释位错线上jog的形成方式，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查位错线上jog形成的基本概念，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"jogs\"在位错线上的形成方式。正确选项直接给出了定义性的答案（Intersection of dislocations），不需要任何解释或推理过程。这属于最基本的知识点回忆型题目，符合等级1\"基本定义简答\"的标准。" + }, + { + "idx": 2382, + "question": "MgO dissolves into Al2O3 to form a solid solution, assuming the formation of cation interstitials. Write the reaction equation using Kroger-Vink notation.", + "answer": "3MgO forms 3Mg••i + 2V•Al + 3OO× through Al2O3", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用Kroger-Vink符号写出反应方程式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求使用Kroger-Vink符号表示固溶体形成反应，涉及缺陷化学的复杂概念和符号系统，需要深入理解缺陷反应机理和符号表示方法，并进行综合分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1959, + "question": "What are the conditions for forming an infinite solid solution?", + "answer": "The same crystal structure of the two components is a necessary condition for forming an infinite solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释形成无限固溶体的条件，答案提供了文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对无限固溶体形成条件的基本概念记忆和理解，主要涉及晶体结构相同这一必要条件的知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于基本定义简答难度。题目仅考察对无限固溶体形成条件的必要条件的记忆，即两种组分具有相同的晶体结构。不需要解释或分析其他因素，属于最基础的概念记忆层次。" + }, + { + "idx": 2518, + "question": "Explain the term: sublattice", + "answer": "The respective Bravais lattices occupied by the constituent atoms in an ordered solid solution.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释术语\"sublattice\"，需要文字解释和论述，答案也是以文字形式给出的定义说明 | 知识层次: 题目考查对\"sublattice\"这一基本概念的定义和记忆，属于材料科学中晶体结构的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生对\"sublattice\"这一术语进行概念解释和描述，属于基础概念记忆层次。虽然需要理解并准确描述该术语的定义，但并不涉及复杂的概念体系阐述或多概念比较分析，因此在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 748, + "question": "What are the two main factors that determine the concentration of component defects?", + "answer": "Solid solubility", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释两个主要因素，需要文字论述而非选择、判断或计算 | 知识层次: 题目考查的是对材料科学中缺陷浓度决定因素的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的定义性知识（固体溶解度），不需要进行概念解释或复杂体系阐述。题目直接考查对\"component defects浓度决定因素\"这一基本定义的记忆，属于最基础的知识点掌握要求。" + }, + { + "idx": 4633, + "question": "To what group in the periodic table would an element with atomic number 112 belong?", + "answer": "From the periodic table the element having atomic number 112 would belong to group IIB. According to the periodic table, Ds, having an atomic number of 110 lies below Pt in the periodic table and in the right-most column of group VIII. Moving two columns to the right puts element 112 under \\mathrm{Hg} and in group IIB.\nThis element has been artificially created and given the name Copernicium with the symbol Cn. It was named after Nicolaus Copernicus, the Polish scientist who proposed that the earth moves around the sun (and not vice versa).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素112在周期表中的归属，并提供了详细的文字解释和论述，而不是简单的选择或判断。答案需要基于周期表的知识进行推理和说明，符合简答题的特征。 | 知识层次: 题目考查对元素周期表分组的基本概念的记忆和理解，仅需根据原子数定位元素在周期表中的位置，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及元素周期表的分组知识，但解题步骤相对直接，只需根据原子数定位元素在周期表中的位置即可。此外，题目提供了额外的背景信息（如元素名称和符号），但这些信息并非解题必需。因此，该题目主要考察基础概念记忆和简单应用，属于等级2的难度。" + }, + { + "idx": 3349, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the isothermal transformation curve?", + "answer": "Using the isothermal transformation curve can only provide an approximate estimation of the normalizing effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求对等温转变曲线在预测正火效果中的适用性进行解释和论述，答案提供了文字解释而非选择、判断或计算 | 知识层次: 题目涉及使用等温转变曲线来预测正火效果，需要理解等温转变曲线的含义及其在热处理中的应用，属于多步计算和概念关联的中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解等温转变曲线的应用范围及其局限性，并能综合分析其对正火效果的预测能力。题目要求考生将材料科学中的等温转变曲线与实际工艺效果联系起来，进行概念关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 2590, + "question": "When the crystal around an edge dislocation contains an excess of vacancies, how will the dislocation climb?", + "answer": "Positive climb", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错攀移的行为，需要文字解释和论述，答案\"Positive climb\"是一个简短的文字回答，而不是从多个选项中选择或判断对错 | 知识层次: 题目涉及位错攀移机制的分析，需要理解空位对位错运动的影响，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3120, + "question": "What are the characteristics of resistance materials?", + "answer": "The general requirements are high and stable resistance values, a small temperature coefficient of resistance, and sufficient mechanical strength, while also requiring a small thermoelectric potential with copper, good corrosion resistance, and ease of machining and welding.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释电阻材料的特性，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对电阻材料特性的基本概念记忆和理解，不涉及复杂计算或综合分析，仅需列举和描述基本特性。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生记忆并理解电阻材料的基本特性，包括高且稳定的电阻值、小的温度系数、足够的机械强度等。虽然涉及多个特性，但都属于基础概念记忆范畴，不需要复杂的分析或比较。因此，难度等级为2。" + }, + { + "idx": 1546, + "question": "Please explain the effect of stacking fault energy on the work hardening rate of metals", + "answer": "For screw dislocations, cross-slip allows two screw dislocations of opposite signs (left and right) on the same slip plane to meet and annihilate each other, thereby reducing the dislocation multiplication rate. For metals with low stacking fault energy, cross-slip of dislocations is difficult, resulting in a high dislocation multiplication rate during deformation and an increased work hardening rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释堆垛层错能对金属加工硬化率的影响，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释堆垛层错能对金属加工硬化率的影响机制，涉及位错运动、交叉滑移等复杂概念的综合分析和推理。需要深入理解位错行为与材料性能之间的关系，并进行机理层面的解释，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 681, + "question": "Explain the effect of grain size on the high-temperature mechanical properties of metallic materials", + "answer": "High-temperature weakening. Grain boundaries become weak points at high temperatures, excessively fine grains reduce high-temperature creep resistance, and appropriately coarsening grains is beneficial for high-temperature performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶粒尺寸对金属材料高温力学性能的影响，需要文字解释和论述，答案也提供了详细的文字说明而非选择或判断。 | 知识层次: 题目要求解释晶粒尺寸对金属材料高温力学性能的影响，涉及晶界在高温下的行为、晶粒尺寸与高温蠕变抗力的关系，以及晶粒适当粗化对高温性能的益处。这需要综合运用材料科学中的晶体缺陷、高温变形机制等知识，进行推理分析和机理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。它要求考生不仅理解晶粒尺寸对高温力学性能的影响机理，还需要综合运用多个知识点（如晶界弱化、蠕变抗力、晶粒粗化效应等）进行推理分析。正确选项涉及复杂现象的全面解释，包括微观机制与宏观性能的关联，这远超简单记忆或基础理解的范畴，符合选择题型内对\"复杂现象全面分析\"能力的最高要求。" + }, + { + "idx": 3078, + "question": "In fiber composite materials, how should the diameter of carbon fibers be", + "answer": "Small", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对碳纤维直径的选择进行解释，答案需要文字论述而非选择或判断 | 知识层次: 题目考查对碳纤维直径在纤维复合材料中作用的基本概念记忆和理解，属于基础性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即碳纤维直径的基本要求。题目直接询问\"how should the diameter of carbon fibers be\"，正确选项为\"Small\"，属于最基础的定义性知识，无需解释或分析。在选择题难度等级中，这属于最简单的等级1，即基本定义简答。" + }, + { + "idx": 675, + "question": "Explain the effect of grain size on the mechanical properties of metal materials at room temperature", + "answer": "Room temperature strengthening. Fine grain strengthening can improve the strength and hardness of metal materials. The smaller the grain size, the more grain boundaries there are, and the greater the resistance to dislocation movement.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释晶粒尺寸对金属材料力学性能的影响，需要文字解释和论述，而不是选择、判断或计算。答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释晶粒尺寸对金属材料力学性能的影响，涉及晶粒尺寸与晶界数量、位错运动阻力之间的关系，需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解晶粒尺寸对金属材料力学性能的影响，并能够关联晶界数量与位错运动阻力之间的关系。虽然题目涉及多个概念的关联，但在选择题型中，正确选项已经提供了明确的解释，降低了分析难度。" + }, + { + "idx": 4187, + "question": "To what group in the periodic table would an element with atomic number 114 belong?", + "answer": "From the periodic table the element having atomic number 114 would belong to group IVA. Ds, having an atomic number of 110 lies below Pt in the periodic table and in the rightmost column of group VIII. Moving four columns to the right puts element 114 under \\mathrm{Pb} and in group IVA.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素114在周期表中的归属，答案提供了详细的文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对元素周期表中元素分类的基本概念的记忆和理解，只需根据原子数定位元素在周期表中的位置即可回答，无需复杂计算或分析。 | 难度: 在选择题型中，该题目需要考生掌握元素周期表的分组原则和原子序数与元素位置的关系，属于概念解释和描述的难度级别。虽然需要一定的记忆和理解，但不需要复杂的分析或推理步骤。" + }, + { + "idx": 1677, + "question": "The methods for strengthening metal materials include (13) _ strengthening, (14) strengthening, (15) strengthening, _ (16) strengthening", + "answer": "(13) solid solution; (14) dislocation; (15) fine grain; (16) dispersion (or precipitate particles)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写具体的强化方法名称，需要根据知识进行文字回答，而不是选择、判断或计算 | 知识层次: 题目主要考查对金属材料强化方法的基本概念的记忆和理解，包括固溶强化、位错强化、细晶强化和弥散强化等基础知识点，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确回忆并区分四种不同的金属强化方法（固溶强化、位错强化、细晶强化、弥散强化或沉淀强化）。这要求考生不仅记住定义，还要能正确分类和匹配每种强化方法的名称。相比等级1的简单定义回忆，该题目需要更深入的概念理解和分类能力，但尚未达到等级3的复杂概念体系阐述水平。" + }, + { + "idx": 2585, + "question": "For a simple cubic crystal, pure bending of the (110) plane around the [001] axis will form what type of dislocations (specify the direction of the dislocation line and the Burgers vector).", + "answer": "Edge type, dislocation line direction=[001], Burgers vector=a[100] or a[010]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释和论述晶体弯曲形成的位错类型、位错线方向和伯格斯矢量，答案需要文字描述而非简单选择或判断。 | 知识层次: 题目需要理解晶体结构、位错类型和伯格斯矢量的概念，并能够将这些概念关联起来进行分析。虽然不涉及复杂的计算，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合理解晶体结构、位错类型、伯格斯矢量等概念，并进行多步分析和关联。题目要求确定位错类型、位错线方向和伯格斯矢量，涉及多个知识点的综合应用和计算，超出了简单记忆或单一概念的应用。" + }, + { + "idx": 4627, + "question": "Briefly explain why amorphous polymers are transparent, while predominantly crystalline polymers appear opaque or, at best, translucent.", + "answer": "Amorphous polymers are normally transparent because there is no scattering of a light beam within the material. However, for semicrystalline polymers, visible light will be scattered at boundaries between amorphous and crystalline regions since they have different indices of refraction. This leads to translucency or, for extensive scattering, opacity, except for semicrystalline polymers having very small crystallites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求简要解释非晶态聚合物透明而结晶态聚合物不透明的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非晶态聚合物透明而结晶态聚合物不透明的机理，涉及光散射、折射率差异等物理原理的综合分析，需要深入理解材料微观结构与光学性能的关系，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对非晶态聚合物和结晶态聚合物的光学性质差异进行机理层面的深度解释，涉及光散射、折射率差异等复杂物理现象的综合分析。正确选项不仅需要理解两种聚合物结构的本质区别，还需要解释光散射与晶体尺寸的关系，属于复杂现象全面分析的范畴。在选择题中，这种需要多维度推理和机理解释的题目对知识掌握深度和综合分析能力要求极高。" + }, + { + "idx": 3353, + "question": "Suppose the microstructure of a certain alloy consists of spherical second-phase particles and a matrix. If the actual diameters of the second-phase particles are all equal, how should the particle size be determined under a metallographic microscope?", + "answer": "Measure the diameter of the largest particle.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来说明如何确定粒子尺寸，而不是从选项中选择、判断对错或进行数值计算。 | 知识层次: 题目考查对金相显微镜下测量第二相粒子尺寸的基本方法的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即测量第二相颗粒直径的基本方法。正确选项直接给出了明确的答案，无需复杂推理或概念比较，属于最基础的定义简答级别。" + }, + { + "idx": 1634, + "question": "The adsorption occurring on the surface of solids can be divided into two types: (15) and (16).", + "answer": "(15) Physical adsorption; (16) Chemical adsorption", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写两个空缺处的答案，需要根据知识进行文字回答，而不是选择、判断或计算 | 知识层次: 题目考查对固体表面吸附类型的基本分类记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求记忆固体表面吸附的两种基本类型（物理吸附和化学吸附），属于基础概念记忆，无需解释或复杂分析。题目直接给出正确选项，考察的是对基础定义的简单回忆，因此属于等级1难度。" + }, + { + "idx": 499, + "question": "What are the Burgers vector and dislocation properties of the generated dislocation?", + "answer": "The Burgers vector of the generated dislocation $\\widehat{b}_{3}$ is $a/2~[110]$, which is a pure edge dislocation. The slip plane (001) is not the slip plane of the face-centered cubic structure, so it is a sessile dislocation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和描述Burgers矢量和位错性质，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释Burgers矢量和位错性质，涉及位错类型和滑移面的分析，需要将多个概念关联起来进行综合判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要掌握Burgers矢量和位错性质的基本概念，还需要理解面心立方结构中的滑移面特性，并能综合分析位错类型（纯刃型位错）与滑移面的匹配关系。解题过程涉及多步概念关联和结构分析，超出了简单记忆或单一概念应用的范畴，属于需要多角度分析论述的中等应用层次题目。" + }, + { + "idx": 985, + "question": "Both allotropic transformation and recrystallization transformation occur through nucleation and growth mechanisms. What are the differences between them?", + "answer": "Allotropic transformation is a phase transition process, where the derivative of a certain thermodynamic quantity becomes discontinuous; recrystallization transformation is merely the reformation of grains and not a phase transition process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释和论述两种转变过程的区别，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求比较两种不同的相变机制（同素异构转变和再结晶转变），需要理解它们的本质区别，并能够关联相关概念进行综合分析。虽然涉及基础概念，但需要更深入的理解和应用能力来区分这两种机制。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求区分同素异构转变和再结晶转变这两种不同的相变过程，涉及对相变和再结晶的基本概念的理解，以及它们之间的差异。虽然题目没有涉及复杂的计算，但需要对材料科学中的相变和再结晶有清晰的认识，并能进行概念上的比较。因此，在选择题型内属于等级3的难度。" + }, + { + "idx": 350, + "question": "(Taking the face-centered cubic unit cell as an example) What are the common parameters used to describe the characteristics of a crystal structure (unit cell)? What is the stacking sequence of an FCC unit cell?", + "answer": "The stacking sequence is ABCABC.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求文字解释和论述晶体结构（晶胞）的常见参数以及面心立方晶胞的堆垛顺序，答案以文字形式给出，没有涉及计算或选择。 | 知识层次: 题目考查晶体结构的基本参数和面心立方(FCC)晶体的堆垛顺序，这些都是材料科学中基础概念的记忆和理解，不涉及复杂的计算或分析。 | 难度: 在选择题型中，该题目仅要求记忆并选择FCC晶体的堆垛顺序（ABCABC），属于基础概念记忆层次。题目不涉及复杂的概念解释或分析，仅需直接回忆定义性知识，因此难度等级为1。" + }, + { + "idx": 4308, + "question": "Give the approximate temperature at which creep deformation becomes an important consideration for lead.", + "answer": "for pb: -33 degrees c (-27 degrees f)", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求给出一个具体的温度值作为答案，而不是从多个选项中选择或判断对错，也不需要复杂的计算过程。答案是一个具体的数值，属于简答题类型。 | 知识层次: 题目考查对铅材料蠕变温度这一特定数值的记忆，属于基础概念的记忆性知识，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅要求记忆铅的蠕变温度这一具体数值，属于基础概念记忆范畴。题目不涉及概念解释或复杂分析，只需直接回忆知识点即可作答，因此属于最低难度等级。" + }, + { + "idx": 2104, + "question": "Point out the errors in the following concepts and correct them: In the solid solution alloy, whether during equilibrium or non-equilibrium crystallization, the liquid phase composition at the liquid-solid interface changes along the average liquid composition line; the solid phase composition changes along the average solid composition line.", + "answer": "The liquid phase composition at the liquid-solid interface changes along the liquidus line; the solid phase composition changes along the solidus line.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对固溶体合金结晶过程中液相和固相成分变化路径的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解并区分平衡结晶和非平衡结晶过程中液相和固相成分的变化规律。虽然题目涉及的是基础概念记忆，但需要考生准确掌握液相线和固相线的定义及其在相图中的应用，并能识别和纠正错误描述。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。" + }, + { + "idx": 1821, + "question": "One of the conditions for clay slurry peptization is (6)", + "answer": "The medium is alkaline", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字简要回答粘土浆料胶溶的条件之一，答案是一个简短的陈述句，不需要选择、判断或计算 | 知识层次: 题目考查对粘土浆体胶溶条件的基本概念记忆，仅需回答介质为碱性这一基本条件，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需回忆粘土浆料胶溶作用的条件之一（介质呈碱性）即可作答。题目不涉及概念解释或复杂体系分析，属于最简单的定义性知识考查。" + }, + { + "idx": 2007, + "question": "Analyze the type of solid solution formed by H in α-Fe and γ-Fe, their locations, and the solubility (mole fraction). The atomic radii of the elements are as follows: H: 0.046 nm, α-Fe: 0.124 nm, γ-Fe: 0.126 nm", + "answer": "H forms an interstitial solid solution in α-Fe. Due to the significant difference in size factors, the solubility (mole fraction) is very small. The location of H in α-Fe is mostly at the octahedral interstitial centers. The solubility decreases rapidly with decreasing temperature. In γ-Fe, H also forms an interstitial solid solution, located at the octahedral interstitial centers, with slightly higher solubility than in α-Fe.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析H在α-Fe和γ-Fe中形成的固溶体类型、位置和溶解度，需要详细的文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求分析氢在α-Fe和γ-Fe中形成的固溶体类型、位置以及溶解度，涉及多个概念的关联和综合分析。需要理解间隙固溶体的形成条件、原子半径的影响、间隙位置的选择以及温度对溶解度的影响等。虽然不涉及复杂的计算或机理的深入解释，但需要对多个知识点进行综合应用和分析。 | 难度: 在选择题型中，该题目属于较高难度，要求考生不仅理解间隙固溶体的基本概念，还需要掌握不同晶体结构（α-Fe和γ-Fe）中间隙位置的特点，并能分析原子半径差异对溶解度的影响。此外，题目还涉及温度对溶解度的复杂影响，需要多角度分析和综合判断。正确选项的表述也较为复杂，包含多个关键知识点和逻辑关系，对考生的综合分析能力要求较高。" + }, + { + "idx": 1988, + "question": "What conclusion can be drawn from the calculation results?", + "answer": "When θ=10°, the distance between dislocations is only 5∼6 atomic spacings, indicating that the dislocation density is too high at this point. This suggests that the model is no longer applicable when the θ angle is large.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求根据计算结果得出结论，答案需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目要求根据计算结果进行分析和结论推导，涉及多步计算和概念关联，需要综合分析能力来判断模型适用性。 | 难度: 在选择题中属于中等难度，需要理解位错密度与角度θ的关系，并能从计算结果中综合分析出模型适用性的结论。题目涉及多步计算和概念关联，但选项本身提供了明确的结论线索，不需要进行更深层次的分析或论述。" + }, + { + "idx": 911, + "question": "What is the difference in the driving force for nucleation during recrystallization and solidification?", + "answer": "The driving force for nucleation during solidification is the chemical potential difference between the new and old phases, while the driving force for recrystallization is only the stored energy of deformation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种不同过程中成核驱动力的差异，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求比较两种不同相变过程（再结晶和凝固）的成核驱动力，涉及对材料科学中相变和变形储存能等概念的理解和应用。虽然不需要复杂的计算，但需要对多个概念进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求区分两种不同相变过程（再结晶和凝固）的成核驱动力来源，涉及对化学势差和变形储存能等概念的理解和对比。虽然不需要多步计算，但需要综合分析不同相变机制的特点，属于中等应用层次的知识要求。" + }, + { + "idx": 1442, + "question": "For an edge dislocation line, what is the relationship between its climb direction and the Burgers vector?", + "answer": "Perpendicular", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释刃位错线的攀移方向与伯格斯矢量之间的关系，答案需要文字解释和论述，而不是简单的选择或判断。 | 知识层次: 题目考查对位错基本性质的理解，特别是刃位错的攀移方向与伯格斯矢量之间的关系，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即刃位错线的攀移方向与其柏氏矢量的关系。题目直接给出了正确选项\"Perpendicular\"，无需任何解释或分析步骤，属于最基础的定义简答级别。" + }, + { + "idx": 1683, + "question": "What is the difference between slip and twinning in terms of deformation modes?", + "answer": "The slip process involves the relative sliding of one part of the crystal relative to another, while the twinning process involves the uniform shear of one part of the crystal relative to another.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释两种变形模式的区别，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对滑移和孪生这两种变形模式的基本定义和区别的理解，属于基础概念的记忆和简单对比。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及两个基本概念（slip和twinning）的比较，但正确选项已经清晰地给出了两者的定义和区别，不需要复杂的推理或分析。学生只需理解并记忆这两个概念的基本特征即可作答。因此，该题目属于概念解释和描述的难度等级。" + }, + { + "idx": 3387, + "question": "The bolts on the gear hobbing machine should have been made of 45 steel, but T12 steel was mistakenly used, and the annealing process for 45 steel was followed. What structure will be obtained in this case? What will be the performance?", + "answer": "Annealing: The structure will be lamellar pearlite and networked carbides. Steel with such a structure is prone to deformation and cracking during quenching.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下材料的结构和性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目需要理解不同钢材（45钢和T12钢）的性质差异，并分析在错误的热处理工艺（45钢的退火工艺应用于T12钢）下会产生的组织结构和性能变化。这涉及到多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于较高难度，需要综合理解材料科学中的多个概念（如钢种特性、热处理工艺、组织结构与性能关系），并能够将错误材料选择与错误工艺步骤的后果进行关联分析。题目要求考生不仅识别出T12钢与45钢的差异，还要预测在错误工艺下会形成的具体组织结构（层状珠光体+网状碳化物）及其对机械性能的影响（淬火时易变形开裂），这需要多步骤的逻辑推理和综合分析能力。" + }, + { + "idx": 1952, + "question": "What are the common phase structures in solids?", + "answer": "The common phase structures in solids include: solid solution (element), compound, ceramic crystalline phase, amorphous phase, and molecular phase.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释常见的固相结构类型，答案以文字解释和论述的形式呈现，没有提供选项或要求进行判断或计算。 | 知识层次: 题目考查对固体中常见相结构的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生掌握并区分多种不同的固体相结构（如固溶体、化合物、陶瓷晶相等），这比单纯记忆单个定义要复杂。题目不涉及复杂的概念体系阐述或深入分析，但要求对多个相关概念有清晰的理解和分类能力，因此属于等级2难度。" + }, + { + "idx": 1381, + "question": "Using dislocation theory, explain one of the reasons for work hardening in pure metal single crystals.", + "answer": "Dislocation intersections occur, and the resulting jogs impede dislocation motion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释纯金属单晶加工硬化的原因，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求运用位错理论解释纯金属单晶加工硬化的原因，涉及位错相互作用和运动阻碍的机理分析，需要综合理解和推理能力，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生运用位错理论解释纯金属单晶体的加工硬化现象，涉及复杂的机理分析和推理过程。正确选项需要理解位错交叉和位错运动受阻的微观机制，这要求考生具备深入的材料科学知识和综合分析能力。在选择题型中，这种需要综合运用多个高级概念并解释复杂现象的题目属于最高难度级别。" + }, + { + "idx": 4703, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MgO? Explain your answer for CoO.", + "answer": "For CoO, the ionic radii of the Mg2+ and Co2+ are 0.072 nm and 0.072 nm, respectively. The percentage difference in ionic radii is 0%, which is within the acceptable range for a high degree of solubility. Therefore, CoO and MgO are expected to form high degrees of solid solubility, likely 100%.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么CoO能与MgO形成完全固溶体，需要文字论述和解释，而不是简单的选择或判断 | 知识层次: 题目需要理解固溶体的形成条件，并应用离子半径差异的计算来判断溶解度。虽然涉及基础概念，但需要综合分析离子半径差异对固溶体形成的影响，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生掌握离子半径的概念，并能计算百分比差异，同时需要理解固溶体的形成条件。虽然涉及多步计算和概念关联，但在选择题型中，这些步骤相对直接，不需要过于复杂的推导或深度关联性分析。" + }, + { + "idx": 84, + "question": "Explain the meaning of the symbol Ca_{K}^*", + "answer": "Ca2+ occupies the K site, with a unit positive charge", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释符号的含义，需要文字解释和论述，答案也是以文字形式给出，没有涉及选择、判断或计算。 | 知识层次: 题目考查对材料科学中符号表示的基本概念的记忆和理解，涉及离子占据晶格位置及其电荷状态的简单描述，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生解释符号Ca_{K}^*的含义，属于概念解释和描述层次。虽然需要记忆基础概念，但不需要复杂的分析或比较多个概念。正确选项直接给出了定义，因此难度适中。" + }, + { + "idx": 2553, + "question": "Write all possible slip systems for an FCC crystal at room temperature (specific crystallographic plane and direction indices are required).", + "answer": "There are a total of 12 possible slip systems: (111)[10 ], (111)[01 ], (111)[1 0], ( 11)[110], ( 11)[0 1], ( 11)[101], (1 1)[110], (1 1)[10 ], (1 1)[011], (11 )[011], (11 )[101], (11 )[1 0].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举所有可能的滑移系统，需要详细说明具体的晶面和晶向指数，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对FCC晶体滑移系统的基本概念的记忆和理解，需要列举所有可能的滑移面和滑移方向，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求记忆FCC晶体的12个可能的滑移系统，包括具体的晶面和晶向指数。虽然需要记忆的内容较多，但属于基础概念记忆的范畴，不需要复杂的分析或推理。相较于等级1的基本定义简答，该题目需要更详细的知识点记忆，但不需要深入的概念解释或复杂体系的阐述，因此属于等级2的难度。" + }, + { + "idx": 1600, + "question": "Explain the reason for the shape memory effect produced by martensitic transformation", + "answer": "The fundamental reasons are the diffusionless nature, coherent shear characteristics, and reversible transformation of martensitic transformation. During the cooling process of the parent phase, external stress induces martensitic transformation, utilizing the pseudoelasticity of martensitic transformation to produce macroscopic deformation. During the heating process, when the temperature exceeds the reverse transformation temperature of martensitic transformation, shape recovery occurs along with the reverse transformation of thermoelastic martensite, completing the shape memory process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释马氏体相变产生形状记忆效应的原因，需要文字解释和论述，答案也提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目要求解释马氏体相变产生形状记忆效应的原因，涉及扩散特性、相干剪切特性和可逆相变等复杂机理的综合分析。需要深入理解马氏体相变的特性及其与形状记忆效应的关系，并进行推理分析，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解马氏体相变的扩散性、相干剪切特性和可逆转变等复杂机理，并能将这些概念综合运用到形状记忆效应的解释中。正确选项不仅涉及多个高级材料科学概念的整合，还需要对相变过程中的热力学和动力学有深刻理解。这种题目在选择题中属于需要全面分析复杂现象的难度水平，远超简单记忆或基础理解的题目要求。" + }, + { + "idx": 2298, + "question": "What role does the reinforcement play in composite materials?", + "answer": "From the perspective that the reinforcement in structural composites mainly bears the load, it is generally required that the reinforcement has high strength and high modulus. The volume fraction of the reinforcement and its bonding performance with the matrix greatly influence the properties of the composite material. The combined action of the reinforcement, matrix, and interface can alter the toughness, fatigue resistance, creep resistance, impact resistance, and other properties of the composite material.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释复合材料中增强体的作用，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对复合材料中增强体作用的基本概念的理解和记忆，涉及增强体的功能、要求及其对材料性能的影响，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。题目要求考生理解复合材料中增强体的作用及其对材料性能的影响，涉及多个基本概念（如强度、模量、体积分数、界面性能等）的综合描述。虽然不需要复杂的分析或推导，但需要对相关概念有清晰的理解和记忆，并能将这些概念联系起来解释增强体的作用。因此，该题目在选择题型中属于等级2（概念解释和描述）。" + }, + { + "idx": 2315, + "question": "When unidirectional continuous composites are subjected to longitudinal stress and the fibers fracture, what length will the fibers break into, and analyze why this type of fracture occurs.", + "answer": "The fibers will break into short segments with lengths of $L_{\\\\mathrm{c}}$ or $2L_{\\\\mathrm{c}}$. According to the shear-lag theory analysis, when the short fiber length is $L_{\\\\mathrm{c}}$, the maximum normal stress in the fiber can reach the fiber fracture stress.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释纤维断裂的长度和原因，答案提供了理论分析和文字解释，没有涉及计算或选择选项。 | 知识层次: 题目不仅要求解释纤维断裂后的长度，还需要分析断裂机理（剪切滞后理论），涉及多概念关联和机理解释，思维深度达到分析推理层面。 | 难度: 在选择题型中，该题目属于最高难度等级。题目不仅要求考生掌握剪切滞后理论（shear-lag theory）的核心概念，还需要理解纤维断裂的临界长度（Lc）这一专业参数。正确选项涉及对复合材料断裂机理的深度解释（为什么断裂成特定长度）和复杂现象分析（应力传递与断裂的关联性）。考生需要综合运用材料力学、复合材料原理等多学科知识进行推理，这远超简单记忆或基础概念选择题的要求。在选择题型中，此类需要机理深度解释和复杂现象全面分析的题目属于最难类型。" + }, + { + "idx": 3093, + "question": "What types can composites be classified into based on the types of reinforcing materials?", + "answer": "Fiber-reinforced composites, particle-reinforced composites, and laminated composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释复合材料基于增强材料类型的分类，答案以文字形式给出具体分类，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查复合材料按增强材料类型分类的基本概念记忆和理解 | 难度: 在选择题型中，该题目仅考察基础概念记忆，即复合材料根据增强材料类型的分类。正确选项直接给出了三种明确的分类（纤维增强、颗粒增强和层压复合材料），无需复杂推理或概念间的比较分析。属于最基本的选择题难度，只需识别和回忆定义性知识即可作答。" + }, + { + "idx": 1190, + "question": "What is the first type of temper brittleness?", + "answer": "The brittleness that occurs during tempering between 250~400°C is called low-temperature temper brittleness, also known as the first type of temper brittleness. The first type of temper brittleness is irreversible temper brittleness, which is caused by the discontinuous thin-shell-like carbides precipitated along the interface of martensite laths or plates during martensite decomposition, reducing the fracture strength of grain boundaries and making them the path for crack propagation, thus leading to brittle fracture.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释什么是第一种回火脆性，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查的是对第一类回火脆性的定义和基本机理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但正确选项不仅需要考生知道第一类回火脆性的温度范围（250~400°C），还需要理解其不可逆性以及微观机制（碳化物析出导致晶界强度降低）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要阐述复杂概念体系（等级3）的程度。" + }, + { + "idx": 1622, + "question": "If different atomic planes in a crystal are represented by letters such as A, B, C, D, etc., the stacking sequence of atoms in a face-centered cubic crystal is _(1)_, and the stacking sequence of atoms in a hexagonal close-packed crystal is _(2)_.", + "answer": "(1) ABCABCABC...; (2) ABABAB.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写具体的堆叠序列，需要文字描述而非选择、判断或计算。 | 知识层次: 题目考查对晶体结构中面心立方和六方密堆积原子堆垛序列的基础概念记忆，属于基本原理的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅要求记忆两种晶体结构（面心立方和六方密堆积）的原子堆垛序列。题目直接给出了正确选项，无需进行复杂的分析或推理。属于基础概念记忆的简单题目，符合等级1的基本定义简答难度。" + }, + { + "idx": 3877, + "question": "Describe the hardness and microstructure in an eutectoid steel that has been heated to 1000^{\\circ} C, quenched to 3010^{\\circ} C and held for 10 s, quenched to room temperature, and then reheated to 400^{\\circ} C before finally cooling to room temperature again.", + "answer": "HRC=42 and the microstructure is all tempered martensite.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求描述材料的硬度和微观结构，答案提供了具体的数值和结构描述，需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及多个热处理步骤和相变过程，需要综合运用材料科学知识来分析钢的微观结构和硬度变化。这包括理解不同温度下的相变行为、淬火和回火对钢性能的影响，以及最终微观结构的形成机制。思维过程需要深度推理和综合分析，超出了简单应用或中等应用的范围。 | 难度: 在选择题型内，该题目属于最高难度等级。题目涉及复杂的相变过程和热处理步骤，要求考生综合运用材料科学知识，包括奥氏体化、淬火、回火等过程对钢的硬度和微观结构的影响。解题步骤复杂，需要考生理解并推理每个热处理步骤对最终材料性能的影响，并准确预测最终的硬度和微观结构。此外，题目还要求考生具备对复杂现象进行全面分析的能力，能够将理论知识与实际工艺条件相结合，进行机理深度解释。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 4893, + "question": "List two important advantages of hybrid composites over normal fiber composites.", + "answer": "Two advantages of hybrid composites are: (1) better overall property combinations, and (2) failure is not as catastrophic as with single-fiber composites.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举混合复合材料的两个重要优势，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目考查对混合复合材料优势的基本概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目要求考生回忆并列举两种混合复合材料的优势，属于概念解释和描述的层次。虽然需要记忆具体知识点，但不需要复杂的分析或比较，相对直接。因此属于中等难度。" + }, + { + "idx": 2537, + "question": "What is the relationship between the mechanical properties of a solid solution and those of its pure components? Please provide a qualitative explanation.", + "answer": "The strength and hardness of a solid solution are often higher than those of its components, while the plasticity is lower. This is because: (1) For interstitial solid solutions, solute atoms tend to preferentially distribute along dislocation lines, forming interstitial atom 'atmospheres' that firmly pin the dislocations, thereby strengthening the material; (2) For substitutional solid solutions, solute atoms are usually uniformly distributed within the lattice, causing lattice distortion, which increases the resistance to dislocation motion, though this strengthening effect is relatively smaller.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求对固溶体与其纯组分机械性能之间的关系进行定性解释，答案提供了详细的文字论述和解释，符合简答题的特征。 | 知识层次: 题目要求对固溶体机械性能与其纯组分之间的关系进行定性解释，涉及对位错钉扎、晶格畸变等机理的分析和推理，需要综合运用材料科学中的多个概念并进行关联分析。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4385, + "question": "For Medium Carbon Steels, briefly describe the properties and typical applications.", + "answer": "Properties: heat treatable, relatively large combinations of mechanical characteristics. Typical applications: railway wheels and tracks, gears, crankshafts, and machine parts.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述中碳钢的性能和典型应用，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对中碳钢的基本性质和典型应用的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述中碳钢的性质和典型应用，但正确选项已经提供了明确的答案，学生只需识别和记忆这些关键点即可。不需要复杂的分析或推理过程，但需要掌握相关的基础概念和分类知识。" + }, + { + "idx": 1173, + "question": "What type of solid solution can be formed when the atomic radius of the solute is similar to that of the solvent?", + "answer": "Substitutional", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述来回答问题，答案是一个具体的术语而非选择或判断 | 知识层次: 题目考查的是对固溶体类型的基础概念记忆和理解，特别是当溶质和溶剂原子半径相似时形成的置换型固溶体。这属于材料科学中的基本分类知识，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即对固溶体类型的定义和分类的记忆。题目直接询问当溶质和溶剂的原子半径相似时形成的固溶体类型，正确答案\"Substitutional\"是基础定义的一部分，无需复杂推理或概念间的比较分析。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1316, + "question": "What is the main phenomenon during the low-temperature recovery of cold-worked metals?", + "answer": "The disappearance of point defects", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释低温恢复冷加工金属的主要现象，答案需要文字解释和论述，而不是从选项中选择或判断对错。 | 知识层次: 题目考查对冷加工金属低温回复过程中主要现象的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需回忆低温恢复过程中点缺陷消失这一基本现象。选择题型中仅需识别正确选项，无需解释或分析，属于最简单的定义识别类题目。" + }, + { + "idx": 963, + "question": "According to the size of defects relative to the crystal dimensions and their range of influence, into which categories can defects be classified? Briefly describe the characteristics of these categories.", + "answer": "There are four categories: Point defects: Very small in all three dimensions, such as solute atoms, interstitial atoms, and vacancies. Line defects: Very small in two dimensions, but large in the third dimension, potentially extending through the entire crystal, referring to dislocations. Planar defects: Very small in one dimension but large in the other two dimensions, such as grain boundaries and phase boundaries. Volume defects: Relatively large in all three dimensions but not excessively so, such as second-phase particles and microscopic voids.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对缺陷进行分类并简要描述各类别的特征，答案以文字解释和论述的形式呈现，符合简答题的特点。 | 知识层次: 题目考查对晶体缺陷分类的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目要求考生理解和描述四种缺陷分类及其特征，属于概念解释和描述的层次。虽然需要记忆和掌握多个概念，但题目提供了明确的分类和特征描述，解题步骤相对直接，不需要复杂的分析或比较。因此，在选择题型内属于中等难度（等级2）。" + }, + { + "idx": 618, + "question": "Cold working and hot working", + "answer": "Cold working and hot working: Generally distinguished based on the recrystallization temperature of metal materials. Processing above the recrystallization temperature is called hot working, while processing below the recrystallization temperature and at room temperature is called cold working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对冷加工和热加工进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对冷加工和热加工的基本定义和分类的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求区分冷加工和热加工的定义，并基于再结晶温度进行区分。虽然涉及基础概念记忆，但需要理解并解释两个加工方式的区别，属于中等难度的选择题。不需要复杂的分析或比较多个概念体系，因此不属于最高难度等级。" + }, + { + "idx": 68, + "question": "In silicate crystals, why can Al3+ partially replace Si4+ in the silicon-oxygen framework?", + "answer": "Al3+ can form [AlO4]5- with O2-. Al3+ and Si4+ are in the second period and have similar properties, making it easy for Al3+ to enter the silicate crystal structure and undergo isomorphous substitution with Si4+. Due to compliance with Pauling's rules, only partial substitution is possible.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Al3+可以部分替代Si4+的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要解释Al3+在硅酸盐晶体中部分替代Si4+的原因，涉及[AlO4]5-的形成、Al3+和Si4+的性质相似性、同晶替代以及Pauling规则的遵守。这需要综合运用晶体化学、离子替代机制和结构规则等多方面知识，并进行推理分析，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1708, + "question": "Please analyze with examples the influence of material processing on the service performance of materials.", + "answer": "The material processing process has a significant and complex impact on the service performance of materials. Materials must also undergo reasonable technological processes to be prepared into materials with practical value. Through rational and economical synthesis and processing methods, many new materials can be continuously created, or the composition and structure of many traditional materials can be altered and precisely controlled, further exploring and enhancing material properties. The preparation/synthesis and processing of materials not only impart certain dimensions and shapes to materials but are also essential means to control their composition and structure. For example, steel can undergo heat treatments such as annealing, quenching, and tempering to alter its internal structure and achieve desired properties. Cold-rolled silicon steel sheets can significantly reduce iron loss through complex processing steps that align grains in a specific orientation. The blades of aircraft engines can be made into single-crystal blades through solidification control during casting, eliminating grain boundaries and greatly improving their service temperature and performance.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求通过例子分析材料加工对材料服役性能的影响，答案提供了详细的文字解释和论述，包括具体的例子和过程描述，符合简答题的特征。 | 知识层次: 题目要求分析材料加工对材料服役性能的影响，并提供实例进行说明。这需要综合运用材料科学的知识，理解加工工艺与材料性能之间的关系，进行推理分析和机理解释。题目不仅涉及多个加工工艺（如热处理、冷轧、铸造控制等），还需要将这些工艺与材料的结构和性能变化联系起来，思维过程的深度要求较高。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解材料加工对材料性能的影响，还需要能够综合运用多个知识点（如热处理、晶粒取向控制、单晶制备等）进行复杂现象的全面分析。正确选项涉及机理深度解释和复杂现象的全面分析，需要考生具备较高的知识整合能力和推理分析能力。此外，题目中的例子（如钢的热处理、冷轧硅钢片、单晶叶片）要求考生能够将理论知识与实际应用相结合，进一步增加了题目的难度。因此，在选择题型内，该题目属于最高难度等级。" + }, + { + "idx": 1719, + "question": "How to control and improve the microstructure in metallic materials through rapid solidification and powder metallurgy?", + "answer": "Non-equilibrium microstructures can be obtained through rapid solidification and powder metallurgy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释如何通过快速凝固和粉末冶金控制和改善金属材料的微观结构，答案需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目要求解释如何通过快速凝固和粉末冶金控制和改善金属材料的微观结构，这需要综合运用材料科学中的相变、凝固理论和加工工艺知识，进行推理分析和机理解释。涉及的知识点复杂且关联度高，思维过程需要深入分析和综合运用。 | 难度: 在选择题型中，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 2264, + "question": "For a φ5mm carbon steel sample with a carbon mass fraction of w_c=0.003, after heating and quenching at 860°C, the sample is tempered. How will the microstructure change during the tempering process?", + "answer": "For carbon steel with w_c=0.003, when tempered below 200°C, the changes in microstructure morphology are minor, and the hardness change is also small. However, the tendency for carbon atoms to segregate near dislocation lines increases. When the tempering temperature exceeds 250°C, cementite precipitates between laths or along dislocation lines, leading to a decrease in strength and plasticity. When the tempering temperature reaches 300~400°C, lamellar or rod-shaped cementite precipitates, causing a significant reduction in hardness and strength, while plasticity begins to increase. During tempering at 400~700°C, the carbides undergo aggregation, growth, and spheroidization, and the α phase undergoes recovery and recrystallization. At this stage, hardness and strength gradually decrease, while plasticity gradually increases.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细描述碳钢样品在回火过程中微观结构的变化，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析碳钢在回火过程中微观结构的变化，涉及多个温度阶段的不同相变行为和性能变化，需要综合运用材料科学中的相变理论、碳钢的回火行为以及微观结构与性能之间的关系等知识进行推理分析。这超出了简单记忆或基本应用的范畴，属于对复杂机理的解释和综合分析。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1448, + "question": "Compared to pure iron, how do the plasticity and toughness of ferrite change?", + "answer": "Lower", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释ferrite的塑性和韧性相对于纯铁的变化情况，需要文字解释和论述，而不是简单的选择或判断 | 知识层次: 题目考查对纯铁和铁素体塑性及韧性差异的基础概念记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，此题仅涉及基础概念记忆，要求考生回忆纯铁与铁素体在塑性和韧性方面的差异。题目仅提供正确选项\"Lower\"，无需复杂分析或推理，属于最基本的概念性知识考察。" + }, + { + "idx": 847, + "question": "Write the reaction equation for the decomposition of a perfect dislocation into an extended dislocation in a face-centered cubic (FCC) crystal, and analyze the possibility of the reaction.", + "answer": "Taking the (111) plane as an example, there are three reaction equations for the decomposition of a perfect dislocation into an extended dislocation on this plane: \\n(1) ${\\\\frac{1}{2}}[110]{-}{\\\\frac{1}{6}}[121]+{\\\\frac{1}{6}}[21\\\\overline{{1}}]$ Geometric condition: ${\\\\frac{1}{2}}[110]={\\\\frac{1}{6}}[121]+{\\\\frac{1}{2}}[21\\\\bar{1}]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\biggl[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\biggr]={\\\\frac{1}{3}}$ Therefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed. \\n(2) $\\\\frac{1}{2}[011]{\\\\rightarrow}\\\\frac{1}{6}[121]+\\\\frac{1}{6}[\\\\overline{{{1}}}12]$ Geometric condition: ${\\\\frac{1}{2}}[011]={\\\\frac{1}{6}}[121]+{\\\\frac{1}{2}}[\\\\overline{{{1}}}12]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\Big[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\Big]={\\\\frac{1}{3}}$ Therefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed. \\n(3) $\\\\frac{1}{2}[\\\\overline{{1}}01]{\\\\rightarrow}\\\\frac{1}{6}[\\\\overline{{1}}12]+\\\\frac{1}{6}[\\\\overline{{2}}\\\\overline{{1}}1]$ Geometric condition: $\\\\frac{1}{2}[\\\\overline{{1}}01]=\\\\frac{1}{6}[\\\\overline{{1}}12]+\\\\frac{1}{6}[\\\\overline{{2}}\\\\overline{{1}}1]$ Energy condition: $\\\\left({\\\\frac{\\\\sqrt{2}}{2}}\\\\right)^{2}={\\\\frac{1}{2}}>\\\\Big[\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}+\\\\left({\\\\frac{\\\\sqrt{6}}{6}}\\\\right)^{2}\\\\Big]={\\\\frac{1}{3}}$ \\nTherefore, it meets the geometric and energy conditions for dislocation reactions, and this dislocation reaction can proceed.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求写出反应方程式并分析反应的可能性，答案提供了详细的反应方程式和几何条件、能量条件的分析，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求写出面心立方晶体中完美位错分解为扩展位错的反应方程，并分析反应的可能性。这需要深入理解位错反应的条件（几何条件和能量条件），并进行综合分析和计算。涉及多个步骤的推理和复杂的机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握面心立方晶体中位错分解的基本概念，还需要能够写出具体的反应方程式，并进行几何条件和能量条件的分析。这需要考生具备以下能力：" + }, + { + "idx": 3736, + "question": "What effect would the frequency of the stress application have on the fatigue strength, maximum stress, minimum stress, and mean stress?", + "answer": "A high frequency will cause heating of the polymer. As the temperature of the polymer increases, the fatigue strength will decrease. If the applied stress is not reduced, then the polymer will fail in a shorter time.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释频率对疲劳强度、最大应力、最小应力和平均应力的影响，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求分析应力频率对疲劳强度、最大应力、最小应力和平均应力的影响，并解释其机理（如高频导致聚合物发热进而影响疲劳强度）。这需要综合运用材料疲劳行为、热力学和聚合物性能等多方面知识，进行推理分析和机理解释，属于较高层次的认知要求。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解疲劳强度、最大应力、最小应力和平均应力的基本概念，还需要综合运用材料科学和热力学知识，分析高频应力应用对聚合物温度的影响，并进一步推理温度升高对疲劳强度的作用机制。解题步骤涉及多层次的因果关系分析，需要考生具备复杂现象的全面分析能力和机理深度解释能力。这种题目在选择题型中属于对综合能力和高阶思维要求极高的类型。" + }, + { + "idx": 3389, + "question": "What is the general process of spheroidizing annealing in the manufacturing process of round dies made from 9SiCr steel?", + "answer": "Spheroidizing annealing process: heating temperature 790-810°C, isothermal temperature 700-720°C.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释球化退火的一般过程，答案提供了具体的温度参数，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查的是球化退火工艺的具体参数设置，需要理解工艺原理并关联具体材料（9SiCr钢）的应用，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及具体的工艺参数（加热温度和等温温度），需要考生对9SiCr钢的球化退火工艺有基本了解，并能将理论知识与实际工艺参数对应起来。虽然不需要复杂的计算，但需要对材料热处理工艺有综合理解才能正确选择答案。" + }, + { + "idx": 2162, + "question": "When a compressive force is applied along the [0001] direction of a hexagonal close-packed single crystal, what are the possibilities of deformation and the primary mode of deformation?", + "answer": "The slip plane of hexagonal close-packed metals is (0001), and the resolved shear stress on the slip plane in the [0001] direction is zero, so the single crystal cannot slip. During compression, after elastic deformation, twinning may occur.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释在特定条件下材料的变形可能性及主要变形模式，答案提供了详细的文字解释和论述，没有涉及选择题、判断题或计算题的特征。 | 知识层次: 题目要求分析六方密堆积单晶在特定方向受压时的变形可能性及主要变形模式，涉及对滑移面和孪生变形的理解，需要将晶体结构、滑移系和应力分析等概念关联起来进行综合分析。虽然不涉及复杂计算，但需要多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 215, + "question": "Many properties of clay are related to the types of adsorbed cations. Indicate the variation pattern of the casting time of clay slurry when adsorbing the following different cations (use arrows to represent: small—large) H+ Al3+ Ba2+ Sr2+ Ca2+ Mg2+ NH4+ K+ Na+ Li+", + "answer": "H+ < Al3+ < Ba2+ < Sr2+ < Ca2+ < Mg2+ < NH4+ < K+ < Na+ < Li+", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用箭头表示不同阳离子吸附时粘土浆料浇注时间的变化规律，需要根据材料科学知识进行排序和解释，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求考生理解不同阳离子对粘土浆料浇注时间的影响，并能够根据离子特性（如离子半径、电荷数等）进行排序。这需要考生掌握粘土吸附阳离子的基本原理，并能将这些原理应用到具体情境中进行分析和判断。虽然不涉及复杂的计算或深度机理分析，但需要考生对多个概念进行关联和综合运用。 | 难度: 在选择题型中，该题目需要考生掌握粘土吸附不同阳离子时对浇铸时间的影响规律，涉及多个阳离子的比较和排序。考生需要理解阳离子的电荷、半径等性质对粘土性能的影响，并进行综合分析。虽然题目给出了正确选项，但需要考生具备较强的概念关联和综合分析能力，属于较高难度的选择题。" + }, + { + "idx": 1412, + "question": "By what mechanism do metal materials conduct heat?", + "answer": "Metal materials mainly conduct heat through free electrons", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释金属材料导热的具体机制，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查金属材料导热的基本机制，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆层次，仅需识别金属导热的主要机制是自由电子这一基本定义。在选择题型中，这是最基础的知识点考察，不需要解释或分析，只需从选项中识别正确的基本原理表述。" + }, + { + "idx": 1621, + "question": "The process in which a single solid phase simultaneously precipitates two new solid phases with different compositions and crystal structures is called (8)__ transformation", + "answer": "(8) eutectoid", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个特定的术语（eutectoid transformation）来完成句子，属于需要准确回忆和填写特定知识点的简答题类型。 | 知识层次: 题目考查对\"eutectoid transformation\"这一基本概念的记忆和理解，属于材料科学中相变的基础知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即\"eutectoid transformation\"的定义。题目直接给出了定义描述，只需选择正确的术语填空，无需解释或分析。这属于最基本的概念记忆题，在选择题型中属于最低难度等级。" + }, + { + "idx": 757, + "question": "Causes of secondary recrystallization", + "answer": "Causes of secondary recrystallization: uneven particle size of raw materials, excessively high sintering temperature, and too fast sintering rate.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释二次再结晶的原因，答案以文字解释和论述的形式给出，没有选项、判断或计算要求 | 知识层次: 题目考查对二次再结晶原因的基础概念记忆和理解，答案直接列举了三个常见原因，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和记忆次级再结晶的多个具体原因（原料颗粒大小不均、烧结温度过高、烧结速率过快），而不仅仅是简单的定义或单一因素。这要求考生对相关概念有一定的理解和整合能力，但不需要进行复杂的分析或比较。" + }, + { + "idx": 677, + "question": "Explain uphill diffusion", + "answer": "Uphill diffusion is a diffusion process where the diffusing element moves from a region of low concentration to a region of high concentration; examples include the formation of various solute atom atmospheres and the formation of eutectoid reaction products, both of which are uphill diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释\"uphill diffusion\"的概念，并提供相关例子，这需要文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释uphill diffusion现象，涉及从低浓度向高浓度扩散的特殊过程，需要理解扩散的基本原理并关联实际例子（如溶质原子氛围和共析反应产物）。虽然包含基础概念，但需要将概念与实际应用结合，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解\"uphill diffusion\"这一非直观概念，并能将其与常规扩散区分。题目要求考生不仅掌握浓度梯度驱动的普通扩散机制，还需理解在特定条件下（如化学势梯度驱动）物质会逆向扩散的现象。同时需要关联实际材料科学案例（如溶质原子气团形成、共析反应产物形成），体现概念的综合应用能力。但作为选择题，正确选项已提供完整解释，降低了答题复杂度。" + }, + { + "idx": 4202, + "question": "What type(s) of bonding would be expected for solid xenon?", + "answer": "For solid xenon, the bonding is van der Waals since xenon is an inert gas.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释固体氙的键合类型，答案提供了文字解释和论述，没有选项或计算要求。 | 知识层次: 题目考查对惰性气体固态时键合类型的基础概念记忆，仅需知道惰性气体通过范德华力形成固态这一基本原理即可作答，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即惰性气体固态时的键合类型。题目不涉及概念解释或复杂分析，只需识别出氙是惰性气体并回忆其固态键合方式为范德华力。因此属于最基本难度等级。" + }, + { + "idx": 4645, + "question": "What type(s) of bonding would be expected for calcium fluoride (CaF2)?", + "answer": "For CaF2, the bonding is predominantly ionic (but with some slight covalent character) on the basis of the relative positions of Ca and F in the periodic table.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释CaF2的键合类型，需要文字论述和解释，而不是从选项中选择或简单判断对错。答案也提供了详细的解释说明，符合简答题的特征。 | 知识层次: 题目考查对化学键类型（离子键和共价键）的基本概念记忆和理解，以及根据元素在周期表中的位置判断键型的能力，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目要求考生理解并描述钙氟化物的主要键合类型（离子键）以及次要特征（部分共价性），这属于概念解释和描述的层次。虽然需要记忆元素在周期表中的相对位置，但不需要复杂的分析或比较多个概念体系，因此属于中等难度。" + }, + { + "idx": 3036, + "question": "The roles of the glass phase in ceramics are (1), (2), (3), and (4).", + "answer": "(1) bonding dispersed crystalline phases; (2) reducing sintering temperature; (3) inhibiting grain growth; (4) filling pores", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举玻璃相在陶瓷中的作用，答案需要以文字形式解释和论述多个要点，符合简答题的特征。 | 知识层次: 题目考查对陶瓷中玻璃相作用的基本概念记忆，属于定义和基本原理的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个玻璃相在陶瓷中的作用，但每个作用都是基础概念记忆层面的知识点，不需要复杂的分析或推理。学生只需回忆并识别出正确的功能描述即可。相较于等级1的简单定义题，该题目需要记忆多个相关知识点，但不需要深入理解或应用，因此属于等级2难度。" + }, + { + "idx": 4303, + "question": "List four measures that may be taken to increase the resistance to fatigue of a metal alloy.", + "answer": "Four measures that may be taken to increase the fatigue resistance of a metal alloy are:\n(1) Polish the surface to remove stress amplification sites.\n(2) Reduce the number of internal defects (pores, etc.) by means of altering processing and fabrication techniques.\n(3) Modify the design to eliminate notches and sudden contour changes.\n(4) Harden the outer surface of the structure by case hardening (carburizing, nitriding) or shot peening.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出四种提高金属合金疲劳抗力的措施，答案以文字解释和论述的形式给出，没有选项选择、对错判断或数值计算的需求。 | 知识层次: 题目要求列举提高金属合金疲劳抗力的措施，涉及多个知识点（表面处理、内部缺陷控制、设计修改和表面硬化）的综合应用，需要理解各措施的原理和关联性，属于中等应用层次。 | 难度: 在选择题中属于中等难度，题目要求列举四种提高金属合金抗疲劳性能的措施，涉及多个概念（如表面处理、内部缺陷控制、设计优化和表面硬化）的综合分析。虽然不需要深入的计算，但需要对材料科学中的疲劳机制和相关处理方法有一定的理解和关联能力。" + }, + { + "idx": 1308, + "question": "The solubility of substitutional solid solutions is related to atomic size factor, (1), electron concentration factor, and (2).", + "answer": "(1) electronegativity factor; (2) crystal structure factor", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求填写空缺部分的内容，需要根据知识进行文字解释和论述，而不是从选项中选择或进行数值计算。 | 知识层次: 题目考查对固溶体溶解度影响因素的基本概念记忆，包括原子尺寸因素、电负性因素、电子浓度因素和晶体结构因素等基础知识点，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生同时掌握原子尺寸因素、电子浓度因素、电负性因素和晶体结构因素等多个相关概念，并理解它们之间的关联。题目要求考生在给定的选项中正确匹配两个空缺部分，这比单纯记忆单个定义要复杂一些，但不需要进行复杂的分析或推理。" + }, + { + "idx": 1428, + "question": "What is the most close-packed direction in a face-centered cubic crystal?", + "answer": "<110>", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个特定的晶体学方向，答案是一个具体的晶体学指数<110>，不需要计算或选择，属于需要直接回答的简答题类型。 | 知识层次: 题目考查对晶体结构中密排方向的基本概念记忆，属于基础概念记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目仅考察对最密排方向的基础概念记忆，属于最基础的定义简答级别。学生只需记住面心立方晶体中最密排方向是<110>即可作答，不需要进行任何解释或复杂分析。" + }, + { + "idx": 4284, + "question": "Briefly explain why small-angle grain boundaries are not as effective in interfering with the slip process as are high-angle grain boundaries.", + "answer": "Small-angle grain boundaries are not as effective in interfering with the slip process as are high-angle grain boundaries because there is not as much crystallographic misalignment in the grain boundary region for small-angle, and therefore not as much change in slip direction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求简要解释小角度晶界在干扰滑移过程中不如大角度晶界有效的原因，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释小角度晶界和大角度晶界在阻碍滑移过程中的不同效果，涉及晶界结构对滑移过程的影响，需要理解晶界角度与滑移方向变化之间的关系，属于概念关联和综合分析层次。 | 难度: 在选择题中属于中等难度，需要理解晶界角度对滑移过程的影响，并进行概念比较分析。题目要求考生理解小角度晶界和高角度晶界在晶体结构错排程度上的差异，以及这种差异如何影响滑移过程。虽然不需要多步计算，但需要对材料科学中的晶界概念有较好的掌握，并能进行综合分析。" + }, + { + "idx": 991, + "question": "Describe the common internal and external interfaces in metal crystals.", + "answer": "They include grain boundaries, phase boundaries, surfaces, twin boundaries, and stacking faults. Grain boundaries are the interfaces between grains of the same type; phase boundaries are the interfaces between phases with different structures and compositions; surfaces are the interfaces between crystals and the atmosphere or external environment; twin boundaries are new interfaces formed after twinning, which are special high-angle grain boundaries and can be coherent or semi-coherent; low-energy stacking faults are new interfaces formed within a single-phase crystal due to anomalous changes in stacking sequence, which are also low-energy interfaces with energy levels similar to twin boundaries.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求描述金属晶体中常见的内部和外部界面，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目主要考查对金属晶体中常见内部和外部界面的定义和分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求描述金属晶体中常见的内部和外部界面，但正确选项已经提供了明确的分类和定义，包括晶界、相界、表面、孪晶界和堆垛层错等。这些概念属于基础概念记忆层次，但需要考生对每种界面的定义和特点有一定的理解和记忆。题目不需要复杂的分析或比较，但要求考生能够准确识别和描述这些界面类型。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 3205, + "question": "How does adding a nucleating agent (modification treatment) refine the grain size?", + "answer": "After adding a nucleating agent, it can promote heterogeneous nucleation in the undercooled liquid. It not only increases the substrates required for heterogeneous nucleation but also reduces the critical nucleus volume, both of which will increase the number of nuclei, thereby refining the grain size.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释添加成核剂如何细化晶粒尺寸，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释成核剂如何细化晶粒的机理，涉及异质成核、临界晶核体积等概念的关联和综合分析，需要深入理解并解释多个因素如何共同作用，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解成核剂的基本作用（促进异质成核），还需要综合分析其对临界晶核体积和成核基底数量的双重影响机制。正确选项涉及凝固学中较深层次的机理解释（降低临界晶核体积与增加成核基底协同作用），需要将\"过冷液体中的异质成核理论\"与\"晶粒细化实际效果\"建立逻辑关联。这种在选择题中要求对复杂现象进行多因素机理解释的题目，远超单纯记忆或简单应用层面，属于典型的复杂分析层次。" + }, + { + "idx": 3350, + "question": "To predict the normalizing effect of φ25 eutectoid steel bars, how applicable is the continuous cooling transformation curve?", + "answer": "To predict the microstructure and hardness after cooling, the continuous cooling transformation curve should be used, as normalizing is a continuous cooling process.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释连续冷却转变曲线在预测正火效果中的适用性，答案提供了文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求将连续冷却转变曲线应用于预测正火效果，涉及概念关联和综合分析，需要理解正火过程与连续冷却转变曲线的关系，并应用该知识进行预测。 | 难度: 在选择题中属于中等难度，需要理解连续冷却转变曲线的应用场景，并能将其与正火工艺（连续冷却过程）关联起来。题目要求考生不仅知道连续冷却转变曲线的基本概念，还要能综合分析其在预测显微组织和硬度方面的适用性。这种题目涉及多步概念关联和综合分析，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 3144, + "question": "It is known that the stacking fault energy of a certain stainless steel is very low, γ=0.013 J/m². After cold pressing deformation with reductions of 8% and 60%, recrystallization annealing is performed. Explain the difference in grain size after recrystallization annealing between the two cases. Why?", + "answer": "After recrystallization annealing, with a reduction of 8%, the deformation is near the critical deformation level. The small deformation amount results in low stored energy and a small driving force for recrystallization. Although recrystallization can occur, the nucleation rate is low, leading to very coarse grains. With a reduction of 60%, the stored energy is high, the driving force for recrystallization is large, and the nucleation rate is high, resulting in fine grains after recrystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两种情况下再结晶退火后晶粒尺寸的差异及其原因，答案通过文字论述进行详细解释，没有涉及计算、选择或判断对错。 | 知识层次: 题目需要综合运用材料科学中的变形、储存能、再结晶驱动力和晶粒尺寸控制等知识，进行机理分析和推理。不仅要求理解低堆垛层错能不锈钢的特性，还需要分析不同变形量对储存能和再结晶行为的影响，进而解释晶粒尺寸差异的原因。这涉及多个概念的关联和深层次的机理解释，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅理解堆垛层错能、冷压变形和再结晶退火等基础概念，还需要综合运用这些知识进行复杂现象的分析和机理解释。具体来说，考生需要：" + }, + { + "idx": 448, + "question": "Explain the reason for cold deformation strengthening of pure metals using dislocation theory", + "answer": "Strengthening reason: Dislocation intersection produces kinks and jogs, dislocation reactions produce immobile dislocations, and dislocation multiplication increases dislocation density.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求用位错理论解释纯金属冷变形强化的原因，需要文字解释和论述，答案也是以文字形式给出解释。 | 知识层次: 题目要求使用位错理论解释纯金属冷变形强化的原因，涉及位错相互作用、位错反应和位错增殖等复杂机理的分析和解释，需要综合运用多个概念并进行推理分析。 | 难度: 在选择题型内，该题目属于最高难度等级。理由如下：" + }, + { + "idx": 4488, + "question": "Is it possible to grind up and reuse polypropylene? Why or why not?", + "answer": "Yes, it is possible to grind up and reuse polypropylene since it is a thermoplastic polymer, will soften when reheated, and, thus, may be remolded.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对是否可能研磨和再利用聚丙烯进行解释和论述，答案提供了详细的文字解释，符合简答题的特征。 | 知识层次: 题目考查对聚丙烯（polypropylene）基本特性的记忆和理解，即它是一种热塑性聚合物，可以通过加热软化并重新塑形。这属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（聚丙烯的可回收性），但需要考生理解并应用\"热塑性聚合物\"这一概念来解释其可回收原理。相比单纯记忆定义（等级1），该题要求考生能够将概念与具体材料特性联系起来进行解释（等级2）。但题目不需要分析复杂概念体系或进行多步骤推理（等级3），因此属于等级2难度。" + }, + { + "idx": 4626, + "question": "Briefly explain why some transparent materials appear colored while others are colorless.", + "answer": "For a transparent material that appears colorless, any absorption within its interior is the same for all visible wavelengths. On the other hand, if there is any selective absorption of visible light (usually by electron excitations), the material will appear colored, its color being dependent on the frequency distribution of the transmitted light beam.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要解释透明材料为何呈现有色或无色，需要文字解释和论述，答案也提供了详细的文字说明，符合简答题的特征。 | 知识层次: 题目考查对透明材料颜色现象的基本原理的理解和记忆，涉及吸收光谱和电子激发等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然涉及基础概念记忆，但需要考生理解并解释透明材料颜色现象背后的基本原理（选择性吸收与均匀吸收的区别）。题目要求考生能够区分两种不同光学现象的本质原因，并正确描述颜色产生的机制，这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 2507, + "question": "Why do the properties of elements change periodically with atomic number?", + "answer": "Because the properties of elements are mainly determined by the number of outer valence electrons, and the number of valence electrons changes periodically with atomic number, thus reflecting the periodic changes in the properties of elements.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素性质随原子序数周期性变化的原因，答案需要文字解释和论述，符合简答题的特征 | 知识层次: 题目考查对元素性质周期性变化的基本原理的理解和记忆，主要涉及外层价电子数与原子序数的关系这一基础概念，不需要复杂的推理或综合分析。 | 难度: 该题目在选择题型中属于中等难度。虽然题目涉及基础概念记忆，但需要理解元素性质周期性变化的原因，并能够将原子序数与价电子数的周期性变化联系起来。正确选项不仅要求记忆基本原理，还需要进行简单的概念解释和描述，因此难度高于基本定义简答的等级1，但尚未达到复杂概念体系阐述的等级3。" + }, + { + "idx": 1691, + "question": "How does the magnitude of bond energy affect the properties of materials?", + "answer": "The magnitude of bond energy directly influences material properties. The higher the bond energy, the greater the material's strength typically is. Additionally, high bond energy usually leads to a high melting point, low thermal expansion coefficient, and high density. The corrosion of engineering materials is essentially a process of bond formation and destruction.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述键能大小如何影响材料性能，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目要求解释键能大小对材料性能的影响，涉及多个性能指标（强度、熔点、热膨胀系数、密度）的综合分析，需要理解键能与这些性能之间的关联，并进行一定的推理分析。虽然不涉及复杂计算，但需要对多个概念进行关联和综合，思维过程有一定深度。 | 难度: 在选择题中属于较高难度，题目要求考生理解并关联多个材料科学概念（如键能、强度、熔点、热膨胀系数、密度和腐蚀机制）。正确选项不仅需要识别键能对单一性质的影响，还需综合分析其对多种材料特性的共同作用机制。此外，题目涉及工程材料腐蚀的微观过程（键的形成与破坏），属于跨知识点整合，对概念掌握深度和逻辑推导能力要求较高。" + }, + { + "idx": 4238, + "question": "For an FCC single crystal, would you expect the surface energy for a (100) plane to be greater or less than that for a (111) plane? Why? ", + "answer": "The surface energy for a crystallographic plane will depend on its packing density [i.e., the planar density (Section 3.11)] - that is, the higher the packing density, the greater the number of nearest-neighbor atoms, and the more atomic bonds in that plane that are satisfied, and, consequently, the lower the surface energy. From the solution to Problem 3.54, planar densities for FCC (100) and (111) planes are \\frac{1}{4 R^{2}} and \\frac{1}{2 R^{2} \\sqrt{3}}, respectively - that is \\frac{0.25}{R^{2}} and \\frac{0.29}{R^{2}} (where R is the atomic radius). Thus, since the planar density for (111) is greater, it will have the lower surface energy.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述为什么FCC单晶的(100)面表面能会大于或小于(111)面，答案提供了详细的文字解释和理论依据，而不是简单的选择、判断或计算。 | 知识层次: 题目需要理解表面能与晶面密度的关系，并应用FCC晶体结构的平面密度计算结果进行比较分析。虽然涉及基础概念，但需要多步推理和综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多角度分析论述。题目不仅要求考生理解表面能与晶面密度的关系，还需要掌握FCC晶体结构中(100)和(111)晶面的平面密度计算。此外，题目要求考生能够将计算结果与表面能的概念进行关联，综合分析得出正确结论。这种多步骤的计算和概念关联在选择题型中属于较复杂的题目。" + }, + { + "idx": 2427, + "question": "At what temperature can the contribution of grain boundary diffusion be neglected?", + "answer": "From the data, it can be seen that at 1200K, the difference between Dapp and D1 is already very small, and the special contribution of grain boundary diffusion can be neglected.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释在什么温度下晶界扩散的贡献可以忽略，答案提供了具体的温度（1200K）并解释了原因，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目需要理解晶界扩散的贡献及其与温度的关系，并基于数据进行综合分析判断。这涉及多步概念关联和综合分析，而不仅仅是基础概念的记忆或简单应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及对晶界扩散贡献的理解，需要考生掌握扩散系数（Dapp和D1）的概念，并能从数据中分析出温度对晶界扩散贡献的影响。虽然题目提供了具体数据（1200K），但考生仍需具备综合分析能力，判断在何种条件下晶界扩散的贡献可以忽略。这要求考生不仅理解基本概念，还能进行简单的数据分析和逻辑推理。" + }, + { + "idx": 1764, + "question": "What is the viscosity corresponding to the characteristic temperature Tg?", + "answer": "(18)1013dPa·s", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求回答一个具体的数值（1013dPa·s），这个数值是材料科学中关于玻璃化转变温度（Tg）对应的粘度的标准值，不需要计算或选择，属于需要直接回答的简答题类型。 | 知识层次: 题目考查的是材料科学中玻璃化转变温度(Tg)对应的粘度值这一基本概念的记忆，属于定义性知识的直接回忆，不涉及复杂计算或分析。 | 难度: 在选择题型中，该题目仅考察对基础概念的记忆，即Tg温度对应的粘度值。不需要解释或分析，只需直接回忆正确答案1013dPa·s。属于最简单的记忆性题目类型。" + }, + { + "idx": 2058, + "question": "Point out the errors in the following concepts and correct them: (2) During metal crystallization, atoms transition from a disordered arrangement in the liquid phase to an ordered arrangement in the solid phase, which reduces the entropy of the system, making it a spontaneous process.", + "answer": "Reduces the free energy of the system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行修正，需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目考查对金属结晶过程中热力学基本概念的理解和记忆，主要涉及熵和自由能的变化关系，属于基础概念的记忆和简单应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（金属结晶过程中的熵变和自由能变化），但需要考生不仅记住定义，还要理解熵变和自由能变化之间的关系。题目要求识别错误概念并选择正确表述，这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。因此，该题目属于概念解释和描述层次的难度（等级2）。" + }, + { + "idx": 496, + "question": "What processes does aging typically undergo?", + "answer": "Aging process: 1) Formation of GP zones. 2) Formation of a series of metastable intermediate phases that maintain coherency or semi-coherency with the parent phase. 3) Formation of stable precipitates. 4) Coarsening and growth of stable precipitates.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释老化过程的不同阶段，答案以文字形式详细描述了老化过程的四个阶段，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查对时效处理过程的基本概念记忆和理解，主要涉及时效过程中各个阶段的描述，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个步骤的记忆（GP zones的形成、亚稳中间相的形成、稳定析出相的形成以及其粗化和生长），但这些步骤都是老化过程的典型阶段，属于基础概念的记忆性知识。学生需要能够回忆并识别老化过程的不同阶段，但不需要进行复杂的分析或比较。因此，该题目在选择题型中属于等级2的难度。" + }, + { + "idx": 2725, + "question": "There are two left-handed screw dislocation lines, each with an energy of $E_{1}$. When they approach infinitely close, what is the total energy?", + "answer": "Since the strain energy of a dislocation is proportional to $b^{2}$, and the energies of like-signed screw dislocations are the same, their Burgers vectors must be identical. If they approach infinitely close and merge into a new dislocation with a Burgers vector of 2b, the total energy should be $4E_{1}$. However, in reality, this dislocation reaction cannot proceed because the energy increases after merging. Moreover, like dislocations repel each other, and the repulsive force between two like-signed dislocations will prevent them from approaching infinitely close.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释两个左旋螺位错线接近时的总能量变化，并论述位错反应不能进行的原因。答案包含详细的文字解释和理论分析，而非简单的计算或选择。 | 知识层次: 题目涉及位错能量计算、位错反应的能量变化分析以及位错间相互作用力的理解，需要综合运用位错理论、能量守恒原理和力学分析，属于复杂分析和推理的范畴。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 1957, + "question": "What are the factors affecting the solubility of substitutional solid solutions?", + "answer": "The influencing factors include: ①Atomic size; ②Crystal structure; ③Electronegativity; ④Electron concentration.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释影响置换固溶体溶解度的因素，答案以文字形式给出多个影响因素，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目考查的是对置换固溶体溶解度影响因素的基本概念记忆和理解，涉及原子尺寸、晶体结构、电负性和电子浓度等基础知识点，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个影响因素（原子尺寸、晶体结构、电负性、电子浓度），但每个因素都是基础概念记忆层面的知识点，不需要复杂的分析或推理。学生只需回忆并识别这些基本影响因素即可作答，不需要进行概念间的关联或深入解释。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 232, + "question": "When the system generates 40% liquid phase, what temperature should be reached?", + "answer": "The temperature at which 40% liquid phase is generated needs to be determined by referring to the phase diagram, and the specific temperature is not provided in the answer.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求通过参考相图来确定温度，答案需要文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求通过相图确定特定液相比例对应的温度，需要理解相图的基本原理，并能进行多步分析和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解相图的概念并能进行综合分析。题目要求确定生成40%液相时的温度，这需要考生能够解读相图并关联相关概念，但不需要进行多角度或深度关联性分析。" + }, + { + "idx": 917, + "question": "Briefly describe normal segregation in the macro-segregation of ingots", + "answer": "Normal segregation: refers to the phenomenon where the initially solidified portion has lower solute content and the later solidified portion has higher solute content, according to the alloy's distribution coefficient (assuming k0<1). Due to the large size of the ingot, the composition varies from the surface to the center, resulting in non-uniformity, and the segregation occurs on a macroscopic scale, known as macro-segregation.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述正常偏析现象，答案以文字解释和论述的形式呈现，没有涉及选择、判断或计算。 | 知识层次: 题目考查对宏观偏析中正常偏析现象的基本定义和原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求的是基础概念记忆，但需要考生理解并描述\"正常偏析\"的定义、形成原因及其在宏观尺度上的表现。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的概念体系阐述（等级3）。考生需要掌握合金分配系数与凝固顺序的关系，并能解释宏观偏析的形成机制，这属于概念解释和描述的难度层次。" + }, + { + "idx": 55, + "question": "What are the structural characteristics of framework silicates?", + "answer": "The structural characteristics of framework silicates: [SiO4] shares 4 O2-, forming a skeleton [(AlxSi4)O], with the complex anion group being [SiO4]4, and the Si:O ratio is 1:4.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释框架硅酸盐的结构特征，答案提供了详细的文字描述和论述，符合简答题的特征。 | 知识层次: 题目考查对硅酸盐结构基本特征的定义和记忆，属于基础概念的记忆和理解范畴，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生准确理解并记忆框架硅酸盐的结构特征，包括[SiO4]的共享氧原子数量、骨架结构[(AlxSi4)O]、复杂阴离子组[SiO4]4以及Si:O的比例。这些知识点需要一定的记忆和理解，但不需要复杂的分析或比较。因此，在选择题型中属于等级2的难度。" + }, + { + "idx": 811, + "question": "During non-equilibrium solidification of solid solution alloys, sometimes microsegregation forms, and sometimes macrosegregation forms. What is the reason for this?", + "answer": "Microsegregation occurs within the range of a single grain and is caused by the slow diffusion rate during crystallization. Macrosegregation occurs throughout the entire part or sample and is caused by the redistribution of solute atoms during crystallization.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释微偏析和宏观偏析形成的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释非平衡凝固过程中微观偏析和宏观偏析的形成原因，涉及对扩散速率和溶质原子再分布的理解，需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，题目要求区分微偏析和宏观偏析的形成原因，涉及非平衡凝固过程中的扩散速率和溶质原子再分布等复杂概念。需要考生综合理解并关联多个知识点，进行多角度分析才能正确解答。" + }, + { + "idx": 464, + "question": "Explain the difference in substructure between plate martensite and lath martensite", + "answer": "
Plate martensiteThere are a large number of twins in the middle of the martensite, and dislocations at the edges. The midrib is fine twins
Lath martensiteThere are high-density dislocations inside the martensite, forming dislocation cells
", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释板条马氏体和片状马氏体的亚结构差异，答案以文字描述和表格形式呈现，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求解释板条马氏体和片状马氏体的亚结构差异，涉及对马氏体内部微观结构的深入理解和分析，需要综合运用材料科学中的相变理论和显微组织知识，并进行推理分析。这超出了基础概念记忆和简单应用的范畴，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生深入理解并区分两种马氏体的亚结构差异，涉及复杂的微观结构特征（如孪晶、位错、位错胞等）。正确选项需要综合运用材料科学知识进行机理解释和对比分析，属于复杂现象的全面分析层次。选择题型中此类题目对知识深度和综合分析能力要求极高，远超简单记忆或基础理解层面。" + }, + { + "idx": 4543, + "question": "(a) Write the possible oxidation and reduction half-reactions that occur when magnesium is immersed in each of the following solutions: (i) HCl", + "answer": "In HCl, possible reactions are Mg -> Mg2+ + 2 e- (oxidation) and 2 H+ + 2 e- -> H2 (reduction).", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求写出可能的氧化和还原半反应，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查的是基本的氧化还原反应记忆和理解，涉及简单的半反应书写，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求写出镁在HCl溶液中的氧化和还原半反应，属于基础概念记忆的范畴。学生只需回忆并写出基本的化学反应方程式，无需进行复杂的分析或推理。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3931, + "question": "Which of the following oxides would you expect to form substitutional solid solutions that have complete (i.e., 100%) solubility with MnO? Explain your answers for MgO.", + "answer": "For MgO, the ionic radii of the Mn2+ and Mg2+ are 0.067 nm and 0.072 nm, respectively. Therefore the percentage difference in ionic radii, Δr% is determined as follows: Δr% = (0.072 nm - 0.067 nm) / 0.072 nm × 100 = 6.9%, which value is within the acceptable range for a high degree of solubility.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释为什么MgO能与MnO形成完全固溶体，需要基于离子半径差异进行文字解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目需要应用离子半径差异的计算公式，并结合溶解度规则进行综合分析，涉及多步计算和概念关联。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求考生不仅知道离子半径的概念，还需要计算百分比差异，并理解这一差异对固溶体溶解度的影响。虽然涉及多步计算和概念关联，但在选择题型中，这些步骤相对直接，且不需要深度论述或多角度分析。" + }, + { + "idx": 2727, + "question": "Indicate the nature types of the three dislocations in the dislocation reaction $$ \\frac{a}{2}[10\\overline{{{1}}}] + \\frac{a}{6}[\\overline{{{1}}}21] \\rightarrow \\frac{a}{3}[11\\overline{{{1}}}] $$?", + "answer": "Referring to the Thompson tetrahedron, this dislocation reaction corresponds to $\\begin{array}{r l r l r l r l r l}{{\\bf C}{\\bf A}}&{{}}&{+}&{{}{\\bf a}{\\bf C}}&{}&{{}\\searrow}&{}&{{\\bf a}{\\bf A}}\\end{array}$", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释位错反应的性质类型，并参考Thompson四面体进行说明。答案提供了详细的文字解释和图示说明，属于需要文字论述的简答题类型。 | 知识层次: 题目涉及位错反应的分析，需要理解Thompson四面体的应用，以及位错类型的识别和反应过程的解释。这需要综合运用材料科学中的位错理论，进行推理分析和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅掌握Thompson四面体的复杂符号系统，还需要理解位错反应的能量和几何条件，并能将抽象的位错反应符号与具体的晶体学概念对应起来。这需要考生具备：" + }, + { + "idx": 2823, + "question": "Analyze the influence of molecular chain flexibility on the viscous flow temperature of polymers", + "answer": "From the relationship between chain segments and the energy barrier difference (potential barrier) Lp=l exp{Δε/kT}, it can be seen that the better the molecular chain flexibility, the lower the potential barrier (Δε) for internal rotation, and the shorter the flow unit segments. According to the segmental motion mechanism of polymer flow, flexible molecules require smaller free volume space for flow, thus viscous flow can occur at relatively lower temperatures.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求分析分子链柔顺性对聚合物粘流温度的影响，答案提供了详细的文字解释和论述，涉及分子链段运动机制和自由体积空间等概念，属于需要展开说明的简答题类型。 | 知识层次: 题目要求分析分子链柔顺性对聚合物粘流温度的影响，涉及分子链段运动机制、自由体积理论等复杂概念的关联和综合分析，需要深入理解聚合物流动的机理并进行推理分析。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解聚合物分子链柔性与粘流温度之间的复杂关系，涉及分子链段运动机理、能垒差（势垒）计算以及自由体积理论等高级概念。正确选项不仅需要综合运用多个知识点（如Lp=l exp{Δε/kT}公式的物理意义、链段运动机制等），还需要进行机理层面的深度解释和推理分析。这种题目在选择题中属于对知识掌握深度和综合分析能力要求极高的类型，完全符合等级5\"复杂现象全面分析\"的标准。" + }, + { + "idx": 4919, + "question": "For cooling, what is the nature of the surface stresses?", + "answer": "For cooling, the surface stresses will be tensile in nature since the interior contracts to a lesser degree than the cooler surface.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对冷却过程中表面应力的性质进行解释，答案提供了详细的文字论述，符合简答题的特征。 | 知识层次: 题目考查冷却过程中表面应力的基本性质和原因，属于基础概念的记忆和理解，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（冷却时表面应力的性质），但需要考生理解并描述应力产生的机制（内部和表面收缩差异导致拉伸应力）。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念体系（等级3）的程度。" + }, + { + "idx": 894, + "question": "Term explanation: phase diagram", + "answer": "A graphical representation describing the conditions for phase equilibrium or the coexistence relationships of phases; it can also be referred to as the geometric trajectory of thermodynamic parameters at equilibrium.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求对术语进行解释，答案是一段文字描述，属于简答题类型 | 知识层次: 题目考查对相图这一基础概念的定义和基本理解，属于记忆性知识范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目要求解释\"phase diagram\"这一基础概念，但正确选项提供了较为详细的描述，包括图形表示、相平衡条件以及热力学参数轨迹等。这需要学生对相图有基本的理解和记忆，而不仅仅是简单的定义复述。因此，该题目在选择题型中属于概念解释和描述级别(等级2)。" + }, + { + "idx": 668, + "question": "How does the anisotropy of crystals affect the diffusion coefficient?", + "answer": "The anisotropy of crystals also affects the diffusion coefficient, but this anisotropy gradually decreases with increasing temperature.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶体各向异性如何影响扩散系数，需要文字解释和论述，而不是选择、判断或计算 | 知识层次: 题目涉及晶体各向异性对扩散系数的影响机制分析，需要综合运用晶体结构、扩散理论和温度效应的知识，并进行推理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解晶体各向异性对扩散系数的影响机制，还需要掌握温度变化对各向异性效应的调控规律。这需要综合运用晶体学、扩散动力学和热力学知识进行复杂现象分析，属于需要深度机理解释和全面分析的题目类型。正确选项涉及两个变量的耦合作用（各向异性+温度），在选择题型中属于认知要求最高的考查形式。" + }, + { + "idx": 875, + "question": "What is the Kirkendall effect? Please explain it using diffusion theory.", + "answer": "Kirkendall effect: In the diffusion process of substitutional solid solutions, markers placed at the original interface move towards the direction of the low-melting-point element, with the movement rate following a parabolic relationship with time. The Kirkendall effect negates the exchange mechanism of diffusion in substitutional solid solutions and confirms the vacancy mechanism; different components in the system have different partial diffusion coefficients. Relatively speaking, the low-melting-point component diffuses faster, while the high-melting-point component diffuses slower. This unequal atomic exchange results in the Kirkendall effect.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释Kirkendall效应并用扩散理论进行说明，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目不仅要求解释Kirkendall效应的定义，还需要运用扩散理论进行深入分析，涉及不同组分的扩散系数差异、空位机制等复杂概念，并需要将这些概念关联起来进行综合解释。这需要较高的分析能力和对扩散机理的深入理解。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求考生不仅理解Kirkendall效应的基本概念，还需要运用扩散理论进行机理深度解释，涉及多个复杂概念的综合运用（如置换固溶体、扩散机制、部分扩散系数等）。正确选项包含了对现象全面分析的要素（如标记移动方向与时间的关系、不同组元扩散速率的差异等），这远超选择题型通常考查的记忆或简单理解层面，需要考生具备高阶推理和分析能力。" + }, + { + "idx": 4847, + "question": "Germanium to which 10^24 m^-3 As atoms have been added is an extrinsic semiconductor at room temperature, and virtually all the As atoms may be thought of as being ionized (i.e., one charge carrier exists for each As atom). Is this material n-type or p-type?", + "answer": "this germanium material to which has been added 10^24 m^-3 as atoms is n-type since as is a donor in ge.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求通过文字解释和论述来判断材料是n型还是p型半导体，而不是从选项中选择或进行数值计算。答案也以简短的文字解释形式给出。 | 知识层次: 题目考查对半导体掺杂类型的基本概念记忆和理解，只需识别砷(As)在锗(Ge)中是施主杂质这一基本事实即可判断材料为n型半导体。 | 难度: 在选择题型中，该题目仅需要基础概念记忆，即识别掺杂元素As在Ge中的行为类型（n型或p型）。题目直接给出了关键信息（As作为施主杂质），无需复杂推理或概念整合，属于最基础的定义简答级别。" + }, + { + "idx": 912, + "question": "What is the difference in orientation relationship between growth during recrystallization and growth during solidification?", + "answer": "During solidification growth, there is no orientation relationship with the parent phase, whereas during recrystallization growth, a specific orientation relationship may exist.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释两种生长过程中的取向关系差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较两种不同生长过程中的取向关系，涉及对再结晶和凝固过程的理解，需要将多个概念关联起来进行综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及再结晶和凝固过程中的取向关系差异，要求考生掌握两种不同相变过程的基本原理，并能区分它们之间的关键区别。虽然不需要复杂的计算，但需要对材料科学中的相变和晶体生长有较深入的理解。" + }, + { + "idx": 1605, + "question": "2. Explain the reasons for strengthening through aging treatment.", + "answer": "During the precipitation process of a supersaturated solid solution, the initially formed metastable precipitates maintain coherent or semi-coherent interfaces with the matrix phase. If the precipitate particles possess high strength, they will cause the gliding dislocations to bend and bypass the second-phase particles, leaving dislocation loops behind. This increases the dislocation line length, and both the second-phase particles and the dislocation loops enhance the resistance to subsequent dislocation motion, resulting in second-phase strengthening. If the precipitate particles can undergo deformation, new phase interfaces will form, disrupting the coherent (or semi-coherent) interfaces between the precipitates and the matrix phase. The slip planes will experience misfit, potentially destroying the ordered arrangement. In summary, macroscopic strengthening is achieved.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释时效处理强化的原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释时效强化的机理，涉及析出相与基体相的界面关系、位错运动与第二相粒子的相互作用、以及宏观强化效果的成因。这需要综合运用材料科学中的相变理论、位错理论和强化机制等多方面知识，进行深入的推理分析和机理解释。 | 难度: 在选择题型中，该题目属于最高难度等级。题目要求深入理解时效强化处理的机理，包括亚稳析出相与基体相的共格/半共格界面关系、位错绕过第二相粒子的过程、位错环的形成及其对后续位错运动的阻碍作用等复杂概念。此外，还需要综合理解析出相变形对界面关系和有序排列的影响。这些知识点涉及材料科学中较为深入的理论，需要考生具备较强的综合分析能力和机理解释能力。在选择题型中，这种需要全面分析复杂现象并解释深层机理的题目属于最高难度级别。" + }, + { + "idx": 1773, + "question": "11. The crystallographic characteristics of martensitic transformation are manifested as: _(28)_, etc.", + "answer": "(28) maintaining coherent relationship", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求填写一个具体的术语或短语（\"maintaining coherent relationship\"）来补充句子，这属于需要简短文字回答的类型，而非选择、判断或计算。 | 知识层次: 题目考查马氏体相变的晶体学特征，属于基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆马氏体相变的晶体学特征之一，即保持共格关系。这属于基础概念记忆层次，无需复杂分析或推理，仅需对定义性知识进行简单回忆。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 2144, + "question": "In a ternary system during diffusion, can a two-phase coexistence region appear within the diffusion layer? Why?", + "answer": "A two-phase coexistence region can exist within the diffusion layer of a ternary system. The reasons are as follows: In a ternary system, when two phases coexist, due to the degree of freedom being 2, at a constant temperature, the composition of the coexisting phases can change. This disrupts the chemical potential balance of the same component atoms in the two phases, leading to diffusion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在三元系统中扩散层内会出现两相共存区域，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目涉及三元系统中扩散层的两相共存现象，需要理解相平衡的自由度概念、化学势平衡的破坏机制以及扩散过程的驱动因素。这需要综合运用相图知识、热力学原理和扩散理论进行推理分析，属于复杂分析层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求对三元系统中的扩散现象进行复杂分析，涉及两相共存区域的机理解释和化学势平衡的推理。需要综合运用热力学、相平衡和扩散理论的知识，进行深度解释和全面分析。这种题目不仅考察知识点的掌握深度，还要求考生能够将多个复杂概念联系起来进行推理，因此在选择题型中属于最难的一类。" + }, + { + "idx": 1926, + "question": "Why do primitive, face-centered, and body-centered lattices exist in the cubic system, but not base-centered lattices?", + "answer": "The characteristic of the cubic system is the presence of 4L3 axes, which exist in the primitive, face-centered, and body-centered lattices of the cubic system. If a base-centered lattice were to exist in the cubic system, the 4L3 axes would not be possible in such a lattice. Therefore, the base-centered lattice does not conform to the symmetry characteristics of the cubic system and cannot exist in it.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释为什么在立方晶系中存在原始、面心和体心点阵，但不存在底心点阵。答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目需要深入理解立方晶系的对称性特征（4L3轴），并分析不同点阵类型（原始、面心、体心）如何满足这些对称性要求。同时，需要推理为什么底心点阵不符合立方晶系的对称性特征，涉及对称性原理和点阵类型的综合分析，属于较高层次的认知能力要求。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 3195, + "question": "What are the characteristics of the central equiaxed grain zone in the ingot structure?", + "answer": "The center is the equiaxed grain zone. Its formation is due to the further increase in mold wall temperature and the further decrease in liquid undercooling, resulting in the heat dissipation directionality of the remaining liquid becoming less obvious and the liquid being in a state of uniform cooling. At the same time, unmelted impurities, broken dendrites, etc., tend to concentrate in the remaining liquid, all of which promote the formation of equiaxed grains.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述中心等轴晶区的特征，答案提供了详细的文字描述和解释，符合简答题的特点。 | 知识层次: 题目要求解释铸锭结构中中心等轴晶区的形成机理，涉及多个因素的相互作用（如温度变化、液体过冷度、散热方向性、杂质和枝晶碎片的影响等），需要综合运用材料科学中的凝固原理和晶体生长知识进行推理分析，思维过程较为深入。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解铸锭结构中中心等轴晶区的特征，还需要综合运用材料科学知识，分析其形成机理（如模具壁温升高、液体过冷度降低、散热方向性减弱等），并解释杂质和破碎枝晶对等轴晶形成的影响。这种复杂现象全面分析和机理深度解释的要求，在选择题型中属于最高难度级别，需要考生具备扎实的理论基础和综合分析能力。" + }, + { + "idx": 225, + "question": "What is Gibbs phase rule?", + "answer": "The phase rule is a fundamental law of phase equilibrium derived by Gibbs based on thermodynamic principles, also known as Gibbs phase rule, used to describe the relationship between the number of degrees of freedom, the number of components, and the number of phases in a system at phase equilibrium. The general mathematical expression is F=C-P+2, where F is the number of degrees of freedom, C is the number of components, P is the number of phases, and 2 represents the two variables of temperature and pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Gibbs phase rule的定义和数学表达式，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查Gibbs相律的基本定义和数学表达式，属于基础概念的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（Gibbs相律的定义和数学表达式），但需要考生理解并描述相律中各变量的含义及其相互关系。相比单纯记忆定义（等级1），该题目要求对概念进行解释和描述（等级2），但不需要进行复杂的概念体系阐述或应用（等级3）。" + }, + { + "idx": 2566, + "question": "Change the tension in the previous question to compression, determine the double slip system", + "answer": "The double slip system is (111)[0 1]－(1 1)[011]", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求确定双滑移系统，答案是一个具体的滑移系统组合，需要基于材料科学知识进行解释和论述，而不是简单的选择、判断或计算。 | 知识层次: 题目要求将张力条件改为压缩条件，并确定双滑移系统，这需要理解滑移系统的基本原理，并能根据不同的应力条件（张力或压缩）进行综合分析。虽然不涉及复杂的推理或创新设计，但需要多步思考和概念关联，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目要求将张力改为压缩并确定双滑移系统，涉及对晶体滑移系统的理解和应用，需要综合分析不同滑移系统的可能性。虽然题目给出了正确选项，但需要考生具备一定的材料科学基础知识和计算能力，能够将概念与实际应用相结合。" + }, + { + "idx": 859, + "question": "Tensile deformation is applied along the [123] direction of an aluminum (Al) single crystal to induce plastic deformation. Determine the rotation rule and rotation axis.", + "answer": "During single slip, the specimen axis should rotate towards [101], and the rotation axis is [12¯3]×[10¯1]=[¯1¯1¯1].", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释和论述塑性变形过程中的旋转规则和旋转轴，答案提供了详细的文字解释和向量计算，属于需要文字解释和论述的简答题类型。 | 知识层次: 题目要求确定单晶铝在拉伸变形过程中的旋转规则和旋转轴，这需要综合运用晶体塑性变形的基本原理、滑移系统的选择、晶体取向变化等知识。解答过程涉及多个概念的关联和综合分析，包括滑移方向的确定、旋转轴的计算以及旋转方向的判断，思维过程较为复杂，属于较高层次的认知要求。 | 难度: 在选择题型中，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 988, + "question": "What are the common macrostructural defects in steel ingots?", + "answer": "Macro defects include: macrosegregation (such as normal segregation, inverse segregation, gravity segregation), banded structure, as well as shrinkage cavities, porosity, and blowholes. Strictly speaking, it also includes the structural inhomogeneity of the three-crystal zone.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举和解释钢锭中常见的宏观结构缺陷，答案提供了详细的文字解释和论述，没有涉及选择、判断或计算。 | 知识层次: 题目考查对钢锭宏观缺陷的基本分类和记忆，属于基础概念的记忆和理解层次，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个宏观缺陷类型，但主要是要求记忆和识别常见的宏观缺陷分类，不需要深入分析或比较。正确选项提供了明确的分类和例子，属于概念解释和描述的层次，但不需要复杂的推理或应用。" + }, + { + "idx": 4218, + "question": "List the point coordinates of all carbon atoms that reside on the face-centered positions of the diamond cubic unit cell.", + "answer": "The coordinates of these atoms are as follows: 1/2 1/2 0, 1/2 1/2 1, 1/2 0 1/2, 0 1/2 1/2, and 1/2 1/2 1/2.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求列出金刚石立方晶胞中面心位置碳原子的坐标点，答案以文字形式给出具体的坐标值，不需要计算或选择，属于简答题类型。 | 知识层次: 题目要求列出金刚石立方晶胞中面心位置碳原子的坐标，这需要理解金刚石立方晶胞的结构特点，并能够应用空间群对称性知识来确定原子的位置。虽然不涉及复杂的计算或推理，但需要对晶体结构有较深入的理解和一定的空间想象能力，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金刚石立方晶胞的面心位置概念，并能正确列出所有碳原子的坐标。虽然题目给出了正确选项，但学生仍需掌握晶体结构的基本知识，并能将面心位置的概念应用到金刚石立方结构中。这需要一定的综合分析能力和对晶体学概念的理解。" + }, + { + "idx": 664, + "question": "Explain the industrial applications of work hardening", + "answer": "Industrial applications of work hardening: During processing, the resistance of metal to plastic deformation continuously increases, making the metal brittle and necessitating multiple intermediate annealing processes, which requires more power consumption for cold working of the metal; work hardening provides the metal matrix with a certain ability to resist accidental overload; appropriate combination of work hardening and plastic deformation enables uniform plastic deformation of the metal, and some processing methods require the metal to have a certain degree of work hardening; work hardening is also one of the important means to strengthen metals, and for some pure metals, work hardening is a key method to improve strength; some components continuously harden on the surface under working conditions, meeting requirements for impact and wear resistance on the surface; after work hardening, the plasticity of materials decreases, improving machinability of materials such as low-carbon steel; the final properties of products can be controlled through cold working.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释工业应用，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求解释和论述工作硬化的工业应用，涉及多个应用场景和原理的综合分析，需要将工作硬化的基本原理与实际工业应用相结合，进行多方面的阐述和关联。虽然不涉及复杂的计算或深度机理分析，但需要对概念进行关联和综合应用，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它要求考生不仅理解工作硬化的基本概念，还需要综合分析其在工业应用中的多个方面。题目涉及多个知识点，如金属的塑性变形、脆性变化、中间退火工艺、冷加工能耗、金属强化机制等，并要求考生能够将这些概念关联起来，进行多角度分析。此外，题目还要求考生理解工作硬化对材料性能的影响，如表面硬化、耐磨性、塑性变化等，这需要较深的知识掌握和综合分析能力。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 2534, + "question": "Briefly describe the influence of atomic valence on solid solubility according to the Hume-Rothery rules", + "answer": "The solid solubility of two elements is related to their atomic valence. The solubility of a high-valence element in a low-valence element is greater than that of a low-valence element in a high-valence element.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述原子价对固溶度的影响，答案以文字解释和论述的形式呈现，符合简答题的特征。 | 知识层次: 题目考查对Hume-Rothery规则中原子价对固溶度影响的基本概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及Hume-Rothery规则的基础概念记忆，但需要考生理解并描述原子价对固溶度的影响关系，而不仅仅是简单的定义记忆。正确选项要求考生能够解释两种不同价态元素之间的固溶度差异，这需要一定的概念理解和描述能力，但不需要复杂的分析或比较多个概念体系。" + }, + { + "idx": 4589, + "question": "(a) For each of the three types of polarization, briefly describe the mechanism by which dipoles are induced and/or oriented by the action of an applied electric field.", + "answer": "(a) For electronic polarization, the electric field causes a net displacement of the center of the negatively charged electron cloud relative to the positive nucleus. With ionic polarization, the cations and anions are displaced in opposite directions as a result of the application of an electric field. Orientation polarization is found in substances that possess permanent dipole moments; these dipole moments become aligned in the direction of the electric field.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述三种极化类型的机制，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对三种极化机制（电子极化、离子极化和取向极化）的基本概念和原理的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念解释和描述难度等级。题目要求考生简要描述三种极化机制，虽然涉及多个概念（电子极化、离子极化和取向极化），但每个概念的描述相对独立且基础，不需要复杂的分析或比较。正确选项提供了清晰的定义性描述，符合选择题型中对基础概念记忆和理解的要求。" + }, + { + "idx": 2612, + "question": "In the periodic table, how do the properties of elements change from left to right within the same period?", + "answer": "From left to right, ionization energy increases, the ability to lose electrons decreases, the ability to gain electrons increases, metallic character weakens, and non-metallic character strengthens.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释元素周期表中同一周期内元素性质的变化趋势，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查元素周期表中同一周期内元素性质变化的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个元素性质的变化趋势（电离能、得失电子能力、金属性/非金属性），但这些都属于基础概念记忆范畴，且变化规律在周期表中呈现系统性。考生需要理解并记忆这些规律，但不需要进行复杂的推导或分析。相比等级1的简单定义题，该题需要整合多个相关概念；但相比等级3的复杂概念体系阐述题，其知识点的关联性和深度要求较低。" + }, + { + "idx": 3506, + "question": "Compare the microstructures of HT150 and annealed 20 steel", + "answer": "Microstructure: a) HT150: F+P+G (graphite); b) 20 steel: F+P.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求比较两种材料的微观结构，答案需要文字解释和论述，没有提供选项或要求计算，属于简答题类型。 | 知识层次: 题目主要考查对HT150和20钢两种材料微观结构的基础概念记忆，包括铁素体(F)、珠光体(P)和石墨(G)等基本组织的识别，属于材料科学中基础知识的记忆和理解层面。 | 难度: 在选择题型中，该题目要求考生记忆并区分两种不同材料的微观结构组成（HT150的F+P+G和20钢的F+P）。虽然涉及基础概念的记忆，但需要考生掌握两种材料的分类和基本组成，属于概念解释和描述的难度等级。题目不涉及复杂的概念体系或深入的分析，因此难度适中。" + }, + { + "idx": 3284, + "question": "Methods for controlling austenite grain size", + "answer": "Methods for controlling austenite grain size: a) Establish appropriate heating specifications, including controlling heating temperature and holding time, rapid short-term heating; b) Control carbon content within a certain range and add a certain amount of alloying elements that hinder austenite grain growth, such as: Al, V, Ti, Zr, Nb, etc.; c) Consider the influence of the original microstructure, such as lamellar pearlite being more prone to coarsening than spheroidized pearlite during heating.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_4", + "reasoning": "题型: 题目要求解释控制奥氏体晶粒尺寸的方法，答案提供了详细的文字解释和论述，没有选项或计算要求，符合简答题的特征。 | 知识层次: 题目要求解释控制奥氏体晶粒尺寸的方法，涉及加热规范、合金元素添加和原始组织影响等多个方面的知识。需要综合理解和应用材料科学中的基本原理，并进行一定的分析和关联，但不需要过于复杂的推理或创新设计。 | 难度: 在选择题中属于中等难度，需要理解多个概念并进行比较分析。题目涉及控制奥氏体晶粒尺寸的多种方法，包括加热规范、碳含量和合金元素的影响以及原始组织的影响。虽然不需要复杂的计算，但需要对材料科学中的相关概念有较深的理解，并能综合分析不同因素对奥氏体晶粒尺寸的影响。" + }, + { + "idx": 324, + "question": "Explain the meaning of interstitial phase", + "answer": "Interstitial phase is an intermediate phase (size-factor compound), and the number of A and B atoms is proportional. The alloy components are all in interstitial positions, with very small sizes themselves. In terms of properties, it exhibits high hardness and poor plasticity.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释间隙相的含义，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对间隙相（interstitial phase）这一基本概念的定义和特性的记忆和理解，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目要求考生解释\"interstitial phase\"的定义和基本特性，属于概念解释和描述的难度级别。虽然涉及多个知识点（如定义、结构特点、性质），但不需要复杂的分析或比较，只需记忆和理解基本概念即可回答。因此属于中等难度（等级2）。" + }, + { + "idx": 222, + "question": "What is the practical significance of Gibbs phase rule?", + "answer": "Applying the phase rule can conveniently determine the degrees of freedom of an equilibrium system.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求解释Gibbs相律的实际意义，答案需要文字论述而非选择、判断或计算 | 知识层次: 题目考查对Gibbs相规则的基本概念和实用意义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于选择题型中的概念解释和描述难度等级。题目要求考生理解Gibbs相律的实际意义，并能够识别其应用场景（确定平衡系统的自由度）。虽然涉及基础概念记忆，但需要一定的理解能力来将原理与实际应用联系起来，比单纯记忆定义（等级1）稍复杂，但不需要复杂概念体系阐述（等级3）。" + }, + { + "idx": 2183, + "question": "Use dislocation theory to explain the yield phenomenon of low-carbon steel.", + "answer": "The yield phenomenon of low-carbon steel can be explained by dislocation theory. Since low-carbon steel is an alloy based on ferrite, carbon (nitrogen) atoms in ferrite interact with dislocations and tend to aggregate in the tensile stress regions of dislocation lines to reduce the distortion energy of the system, forming Cottrell atmospheres that 'pin' the dislocations, thereby increasing σs. Once dislocations break free from the pinning of these atmospheres, they can continue to move under lower stress, leading to the appearance of the lower yield point on the stress-strain curve. For a specimen that has already yielded, if it is unloaded and immediately reloaded in tension, the yield point does not reappear because the dislocations have already escaped the pinning of the atmospheres. However, if the unloaded specimen is left for a long time or slightly heated before retesting, the solute atoms will diffuse back and re-aggregate around the dislocation lines to form atmospheres, causing the yield phenomenon to reappear.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求使用位错理论解释低碳钢的屈服现象，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求运用位错理论解释低碳钢的屈服现象，涉及位错与溶质原子的相互作用、柯氏气团的形成及其对位错的钉扎作用、应力-应变曲线的特征以及卸载和重新加载对屈服现象的影响。这需要深入理解位错理论，综合分析多个概念和机制，并进行推理分析，属于复杂分析的层次。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅掌握位错理论的基本概念，还需要深入理解低碳钢屈服现象的微观机理，包括柯氏气团的形成、位错钉扎效应、应力-应变曲线特征以及时效现象等复杂内容。正确选项涉及多个知识点的综合运用和机理深度解释，需要考生具备将理论知识与实际材料行为联系起来的能力。这种题目在选择题型中属于需要复杂现象全面分析的类型，对考生的理解深度和综合分析能力要求极高。" + }, + { + "idx": 852, + "question": "What are the dislocation name, Burgers vector, dislocation nature, formation method, and motion state of the Frank partial dislocation in FCC crystals?", + "answer": "Frank partial dislocation; 1 <111> 3; edge type; formed by inserting or removing a layer of {111} close-packed plane in a local region of the crystal; can only climb, cannot glide", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求详细解释Frank partial dislocation在FCC晶体中的多个属性（名称、Burgers矢量、位错性质、形成方法和运动状态），答案以文字形式给出详细说明，符合简答题的特征。 | 知识层次: 题目要求回答Frank部分位错的多个属性（名称、Burgers矢量、位错性质、形成方法和运动状态），涉及多个概念的关联和综合分析，需要理解位错的基本性质及其在FCC晶体中的具体表现，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，要求考生掌握Frank部分位错的多个关键属性（名称、Burgers矢量、位错性质、形成方法和运动状态），并能够将这些概念综合关联起来。题目不仅考察单一知识点的记忆，还需要对FCC晶体中位错行为的深入理解，涉及多步分析和概念整合。此外，正确选项中的信息较为复杂，需要考生具备较强的综合分析能力。" + }, + { + "idx": 2114, + "question": "Point out the error in the following concept and correct it: The fundamental difference between ferrite and austenite lies in their different solid solubility, with the former being small and the latter large.", + "answer": "The fundamental difference lies in their crystal structures, with the former being bcc and the latter fcc.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求指出概念中的错误并进行纠正，需要文字解释和论述，而不是从选项中选择或进行数值计算。答案也以文字形式呈现，解释了晶体结构的差异。 | 知识层次: 题目考查对铁素体和奥氏体基本概念的记忆和理解，特别是它们的晶体结构差异，属于基础概念的记忆性知识。 | 难度: 在选择题中属于中等难度，需要理解并区分铁素体和奥氏体的基本概念，特别是它们的晶体结构差异。虽然题目涉及基础概念记忆，但需要考生能够识别错误并选择正确的定义，这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或概念体系阐述（等级3）。" + }, + { + "idx": 4564, + "question": "What are inhibitors?", + "answer": "Inhibitors are substances that, when added to a corrosive environment in relatively low concentrations, decrease the environment's corrosiveness.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求对\"inhibitors\"进行文字解释和论述，答案是一个完整的定义性陈述，不需要选择、判断或计算 | 知识层次: 题目考查对抑制剂这一基本概念的定义和简单理解，属于基础概念记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别抑制剂的基本定义，属于最基础的概念记忆层次。题目仅涉及单一概念的简单描述，不需要进行比较分析或复杂推理，因此属于等级1的基本定义简答难度。" + }, + { + "idx": 515, + "question": "In face-centered cubic metals, can the dislocation b3 generated by the dislocation reaction b1 + b2 = b3 move on the slip plane?", + "answer": "The slip plane of face-centered cubic metals is {111}, and b3 is perpendicular to this crystal plane, so it cannot slip.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目需要解释和论述为什么位错b3不能在滑移面上移动，答案提供了详细的晶体学分析和文字解释，符合简答题的特征。 | 知识层次: 题目涉及面心立方金属中位错反应生成的位错b3在滑移面上的运动能力，需要综合运用位错理论、晶体学知识以及滑移机制进行推理分析。解答不仅需要理解位错反应的基本原理，还需要分析位错b3与滑移面{111}的几何关系，判断其是否能够滑移。这属于对多个概念的深度理解和综合应用，思维过程较为复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 4403, + "question": "Cite advantages of forming metals by extrusion as opposed to rolling.", + "answer": "The advantages of extrusion as opposed to rolling are as follows: (1) Pieces having more complicated cross-sectional geometries may be formed. (2) Seamless tubing may be produced.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求列举挤压成形相对于轧制的优点，答案以文字解释和论述的形式给出，没有选项或计算要求。 | 知识层次: 题目考查对金属挤压和轧制两种加工方法的基本概念记忆和理解，要求列举挤压相对于轧制的优势，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解和比较两种金属成型工艺（挤压和轧制）的具体优势。正确选项中列举了两点明确的优势，这要求考生不仅记住这些知识点，还需要能够区分和对比两种工艺的特点。因此，相较于简单的定义记忆题（等级1），该题目需要更深一层的理解和应用（等级2）。" + }, + { + "idx": 1187, + "question": "Discuss the characteristics exhibited by pure metals during the solidification process and explain the reasons?", + "answer": "During crystallization, the interface of a pure metal is rough and grows under a positive temperature gradient. Since heat is dissipated through the solid mold wall as the crystal grows, the solid-liquid interface remains isothermal. If a dynamic undercooling is achieved, the interface advances forward. If a small protrusion locally extends into the overheated liquid phase, it will be melted, keeping the interface straight, and the crystal grows in a planar manner.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求讨论纯金属在凝固过程中表现出的特性并解释原因，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求讨论纯金属在凝固过程中的特性并解释原因，涉及对结晶过程中界面形态、温度梯度、动态过冷等复杂现象的综合分析和机理解释，需要较高的认知能力和深度理解。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生对纯金属凝固过程中的界面特性、温度梯度、动态过冷等复杂现象进行全面分析，并解释晶体生长的平面方式。这需要综合运用材料科学中的多个高级概念，进行深入的机理推理和解释。选择题型中通常不涉及如此复杂的分析过程，因此该题目在选择题型内属于极难级别。" + }, + { + "idx": 990, + "question": "Please briefly describe the basic conditions for the crystallization of binary alloys.", + "answer": "Thermodynamic condition: $\\\\Delta G<0$; structural condition: $r>r^{*}$; energy condition: $A>\\\\Delta G_{\\\\mathrm{max}}$; composition condition.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_3", + "reasoning": "题型: 题目要求简要描述二元合金结晶的基本条件，需要文字解释和论述，而不是选择、判断或计算。 | 知识层次: 题目考查二元合金结晶的基本条件，属于基本原理的记忆和理解，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目要求考生描述二元合金结晶的基本条件，涉及多个概念（热力学条件、结构条件、能量条件和成分条件）的解释和描述。虽然需要记忆多个知识点，但不需要进行复杂的比较分析或深入的概念体系阐述，属于中等难度的概念解释和描述题目。" + }, + { + "idx": 2884, + "question": "What are the main differences in the microstructure between dynamic recrystallization and static recrystallization?", + "answer": "Although the microstructure after dynamic recrystallization also consists of equiaxed grains, the grain boundaries are serrated, and the grains contain subgrains divided by dislocation tangles. This differs from the grains produced by static recrystallization, which have a very low dislocation density. Therefore, the strength and hardness of dynamically recrystallized structures with the same grain size are higher than those of statically recrystallized ones. The grain size after dynamic recrystallization is proportional to the flow stress. Additionally, the lower the strain rate and the higher the deformation temperature, the larger and more complete the grains after dynamic recrystallization will be.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释动态再结晶和静态再结晶在微观结构上的主要差异，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目要求比较动态再结晶和静态再结晶的微观结构差异，涉及对两种再结晶过程的深入理解、微观结构的详细描述（如锯齿状晶界、亚晶粒等）、以及力学性能差异的解释。这需要综合运用材料科学中的再结晶理论、位错理论以及变形条件对微观结构的影响等多方面知识，并进行推理分析和机理解释。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求考生不仅掌握动态再结晶和静态再结晶的基本概念，还需要深入理解两者微观结构的差异及其对材料性能的影响机制。正确选项涉及多个复杂知识点（如锯齿状晶界、亚晶结构、位错密度与强度的关系、流变应力和晶粒尺寸的关系等），并要求考生能够综合运用这些知识进行推理分析。此外，题目还考察了应变速率和变形温度对动态再结晶晶粒尺寸的影响，这需要考生具备机理层面的深入理解和复杂现象的全面分析能力。在选择题型中，这种需要多维度知识整合和机理深度解释的题目属于最难的一类。" + }, + { + "idx": 108, + "question": "Explain the differences between solid solutions, lattice defects, and non-stoichiometric compounds", + "answer": "Thermal defects - intrinsic defects; solid solutions - extrinsic defects; non-stoichiometric compounds - caused by changes in environmental atmosphere properties and pressure.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的差异，需要详细的文字解释和论述，而不是选择、判断或计算。答案也提供了详细的解释，符合简答题的特征。 | 知识层次: 题目要求解释固体溶液、晶格缺陷和非化学计量化合物之间的差异，这需要理解并关联多个概念，进行综合分析。虽然涉及基础概念，但需要将这些概念进行比较和关联，属于中等应用层次。 | 难度: 在选择题型中，该题目要求考生不仅要理解固体溶液、晶格缺陷和非化学计量化合物的基本概念，还需要能够区分它们之间的差异，并正确匹配到热缺陷、外禀缺陷和环境因素导致的缺陷。这涉及到多步的概念关联和综合分析，属于较高难度的选择题。" + }, + { + "idx": 1409, + "question": "In substitutional solid solutions, by what mechanism do solute atoms diffuse?", + "answer": "In substitutional solid solutions, solute atoms diffuse by the vacancy mechanism.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求用文字解释和论述溶质原子在置换固溶体中的扩散机制，答案提供了详细的文字说明而非选择、判断或计算。 | 知识层次: 题目考查对置换固溶体中溶质原子扩散机制的基本概念记忆，即空位机制的理解和表述，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目仅要求记忆基础概念中的定义和基本原理，即溶质原子在置换固溶体中的扩散机制。题目直接给出了正确选项，无需进行复杂的分析或比较，属于最基础的定义简答类型。" + }, + { + "idx": 634, + "question": "Explain the influence of grain boundaries on material properties", + "answer": "Grain boundaries affect various aspects of materials, possessing grain boundary energy, influencing the shape of second phases in polycrystalline materials. Grain boundaries can move, exhibit grain boundary segregation, undergo changes in grain boundary charge, bear load transfer effects, have low melting points and are prone to overheating. Grain boundaries serve as easy diffusion paths, facilitate nucleation, and are susceptible to corrosion.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_5", + "reasoning": "题型: 题目要求解释晶界对材料性能的影响，答案提供了详细的文字解释和论述，符合简答题的特征 | 知识层次: 题目要求解释晶界对材料性能的影响，涉及多个方面的知识（如晶界能、扩散路径、腐蚀敏感性等），需要将不同概念关联起来进行综合分析，但不需要进行复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，题目要求考生不仅理解晶界的基本概念，还需要掌握晶界对材料性能的多方面影响，包括能量、形貌、运动、偏析、电荷、载荷传递、熔点、扩散路径、形核和腐蚀等多个角度。这需要考生具备较强的综合分析能力和对材料科学中晶界相关知识的深入理解。" + }, + { + "idx": 2524, + "question": "Explain the term: phase", + "answer": "A portion or region within an alloy that has the same (or continuously varying) composition, structure, and properties.", + "question_type": "short_answer", + "question_type_name": "简答题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_2", + "reasoning": "题型: 题目要求解释术语\"phase\"，答案提供了详细的文字解释和论述，符合简答题的特征。 | 知识层次: 题目考查对\"phase\"这一基本概念的定义记忆和理解，属于材料科学中最基础的概念性知识。 | 难度: 在选择题型中，该题目仅要求考生记忆并识别\"phase\"的基本定义，属于最基础的概念记忆层次。题目正确选项直接给出了术语的标准定义，不需要任何解释、分析或比较过程，完全符合等级1\"基本定义简答\"的难度标准。" + }, + { + "idx": 104, + "question": "Grain boundaries can be divided into small-angle grain boundaries and large-angle grain boundaries. Can large-angle grain boundaries be described by arrays of dislocations?", + "answer": "No, in large-angle grain boundaries, the atomic arrangement is close to a disordered state, and the distance between dislocations may only be 1 or 2 atoms in size, which is not applicable to large-angle grain boundaries.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（\"Can large-angle grain boundaries be described by arrays of dislocations?\"），答案明确给出了\"否\"的回答并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对晶界分类和位错描述的基本概念的理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解大角度晶界的原子排列状态以及位错阵列的适用性。题目不仅要求记忆定义，还需要对概念进行一定的理解和判断，因此难度高于简单的正误判断（等级1），但尚未达到复杂概念陈述的判断（等级3）。" + }, + { + "idx": 134, + "question": "Can glass be formed by rapid quenching at 1050°C?", + "answer": "At this temperature, rapid quenching can form glass.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（玻璃是否可以通过在1050°C快速淬火形成），答案直接给出了对错判断。 | 知识层次: 题目考查玻璃形成的基本原理和温度条件的记忆，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅涉及玻璃形成的基本原理和温度条件的记忆性知识，不需要深入理解或复杂分析。正确选项直接陈述了基础概念，属于最基础层次的难度。" + }, + { + "idx": 384, + "question": "The higher the diffusion temperature, the more conducive it is to diffusion.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查扩散温度与扩散速率之间关系的基本原理记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅涉及扩散温度与扩散速率关系的简单记忆性知识，无需理解复杂概念或进行多步骤分析。正确选项直接对应基础概念记忆层次，符合等级1的难度标准。" + }, + { + "idx": 386, + "question": "From a diffusion perspective, the mobility of low-angle grain boundaries is lower compared to that of high-angle grain boundaries.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（低角度晶界的迁移率低于高角度晶界），并要求判断其正确性（√表示正确），这符合判断题的特征。 | 知识层次: 题目考查的是关于晶界扩散特性的基本概念记忆，即低角度晶界和高角度晶界在扩散过程中的迁移率差异。这属于对材料科学中晶界行为的基础知识的理解和记忆，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅涉及低角度晶界和高角度晶界迁移性的比较，属于基础概念记忆层次，无需复杂分析或推理。学生只需记住相关定义即可直接判断正误，因此难度最低。" + }, + { + "idx": 389, + "question": "The decrease in volume free energy during the formation of a critical nucleus can only compensate for 1/3 of the newly added surface energy.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（The decrease in volume free energy during the formation of a critical nucleus can only compensate for 1/3 of the newly added surface energy），并要求判断其正确性（答案给出的是×，表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对临界核形成过程中体积自由能和表面能量关系的记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生理解临界晶核形成过程中体积自由能减少与表面能增加的关系。虽然涉及两个能量概念，但只需判断\"1/3补偿\"这一具体数值关系的正误，不需要进行复杂的概念比较或计算分析，属于选择题型中中等偏下的难度。" + }, + { + "idx": 390, + "question": "Both edge dislocations and screw dislocations have climb and glide motions.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Both edge dislocations and screw dislocations have climb and glide motions），要求判断其正误（答案给出×表示错误），符合判断题的特征 | 知识层次: 题目考查对位错类型及其运动方式的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对位错运动方式的基本理解，需要区分边缘位错和螺型位错的不同运动特性（边缘位错有攀移和滑移，而螺型位错只有滑移）。虽然涉及两个概念，但属于基础概念记忆层次，不需要复杂的分析步骤。" + }, + { + "idx": 391, + "question": "Both thermoplastic and thermosetting plastics can be reused.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Both thermoplastic and thermosetting plastics can be reused），并要求判断其正确性（答案给出×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对热塑性塑料和热固性塑料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆热塑性塑料和热固性塑料的基本特性即可作答。在选择题型中，这类直接考察定义记忆的题目属于最简单级别，无需复杂分析或推理过程。" + }, + { + "idx": 394, + "question": "The brittle phase is dispersed in granular form in the matrix of another phase, which is a microstructure state that is more beneficial to the strength and toughness of the material.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The brittle phase is dispersed...），并要求判断其正确性（答案：√），这是典型的判断题特征。 | 知识层次: 题目考查对材料微观结构状态及其对性能影响的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断给定的陈述是否正确。题目描述的是材料科学中关于微观结构对强度和韧性影响的基本概念，正确选项明确，无需复杂分析或推理。在选择题型中，此类题目属于最简单的难度等级，仅需对基本定义或分类有记忆即可正确作答。" + }, + { + "idx": 395, + "question": "Grain boundaries with a misorientation angle less than $2^{\\circ}$ between adjacent grains are called high-angle grain boundaries.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Grain boundaries with a misorientation angle less than $2^{\\circ}$ between adjacent grains are called high-angle grain boundaries），并要求判断其正误（答案给出的是×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对晶界分类的基本概念记忆，特别是低角度晶界和高角度晶界的定义区分，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于晶界分类的定义是否正确。题目陈述明确，只需识别\"小于2°的晶界称为小角度晶界\"这一基本概念即可判断正误，无需深入理解或分析。在选择题型中，这类直接考察定义记忆的题目属于最简单的难度等级。" + }, + { + "idx": 396, + "question": "If the arrangement of atoms in the parent phase of an alloy is ordered, then after martensitic transformation, the arrangement of atoms in the martensite becomes disordered.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（关于马氏体转变后原子排列有序性的描述），并要求判断该陈述的对错（答案用×表示错误）。这符合判断题的特征，即判断陈述的真伪。 | 知识层次: 题目考查对马氏体相变中原子排列有序性的基本概念记忆和理解，属于基础概念层面的判断题 | 难度: 该题目属于基础概念记忆层次，仅需判断马氏体相变后原子排列是否有序这一基本定义的正确性。在选择题型中属于最简单的正误判断题，不需要复杂分析或概念比较，完全基于对基础概念的准确记忆即可作答。" + }, + { + "idx": 399, + "question": "Are the geometric conditions for the following dislocation reaction satisfied? Among them: b1=a/2[110], b2=a/6[12¯1], b3=a/6[211]", + "answer": "Geometric conditions: after the reaction b2+b3=a/6[12¯1]+a/6[211]=a/6[330]=a/2[110] before the reaction b1=a/2[110] the geometric conditions are satisfied", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断给定的位错反应几何条件是否满足，答案直接给出了判断结果（满足或不满足），属于判断题的特征。 | 知识层次: 题目要求判断位错反应的几何条件是否满足，涉及基本的向量运算和位错反应的基本原理。虽然需要一定的理解，但主要是直接应用公式和简单计算，不需要多步推理或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，主要考察对基本公式的直接套用和简单计算能力。题目要求判断位错反应的几何条件是否满足，解题步骤明确且直接，只需进行简单的矢量相加和比较即可得出正确结论。因此，在选择题型内属于较低难度，符合等级2的标准。" + }, + { + "idx": 432, + "question": "Point defects are thermodynamically stable defects, and a certain number of equilibrium defects exist in crystals at a given temperature, also known as intrinsic defects.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确与否（√表示正确），符合判断题的特征。 | 知识层次: 题目考查点缺陷的基本概念和定义，属于基础概念的记忆和理解范畴 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆点缺陷的定义和特性即可做出正确选择，无需深入理解或分析复杂概念。" + }, + { + "idx": 435, + "question": "Non-spontaneous nucleation still requires structural fluctuations, compositional fluctuations, and energy fluctuations.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述句，要求判断其正确性（用√表示正确），符合判断题的特征 | 知识层次: 题目考查对非自发成核所需条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断一个简单陈述的正确性，涉及的是基础概念记忆层次的知识点（非自发形核的基本要求），无需复杂分析或推理。学生只需回忆相关定义即可作答，属于选择题型中最简单的难度等级。" + }, + { + "idx": 436, + "question": "The eutectic transformation occurs in systems where the liquid phase is completely miscible and the solid phase is completely immiscible.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确与否（答案给出的是×表示错误），符合判断题的特征。 | 知识层次: 题目考查共晶转变的基本概念，属于定义和基本原理的记忆性知识 | 难度: 该题目属于基础概念正误判断，仅需记忆共晶转变的定义和条件即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 437, + "question": "Polymers with simple structure, high regularity, and good symmetry are not prone to crystallization.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案用×表示错误），符合判断题的特征 | 知识层次: 题目考查对聚合物结晶条件的基本概念记忆和理解，涉及结构简单性、规则性和对称性对结晶倾向的影响，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆聚合物结晶的基本原理即可作答，无需深入理解或分析多个概念。题目结构简单，直接考察基础定义，因此属于最低难度等级。" + }, + { + "idx": 438, + "question": "The reason why the carbon solubility of austenite is higher than that of ferrite is because the crystal interstices of austenite are larger.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√），符合判断题的特征 | 知识层次: 题目考查对奥氏体和铁素体晶体间隙大小及其对碳溶解度影响的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆奥氏体和铁素体的碳溶解度差异原因这一基本原理即可作答，无需复杂分析或推理过程。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 440, + "question": "In a ternary phase diagram, the degree of freedom at the eutectic temperature point is 0. At this time, it is a three-phase equilibrium.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（三元相图中共晶温度点的自由度为0，此时为三相平衡），并要求判断其正误（答案给出×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对三元相图中自由度概念和三相平衡条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆三元相图中共晶温度点的自由度概念即可作答。在选择题型中属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 441, + "question": "During diffusion, solute atoms always migrate from high concentration to low concentration.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其对错（答案给出的是×表示错误），符合判断题的特征 | 知识层次: 题目考查扩散过程中溶质原子迁移方向的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于非常基础的概念正误判断。只需要记忆扩散过程中溶质原子的迁移方向这一基本原理即可作答，无需深入理解或分析多个概念。题目直接考察对基础定义的记忆，属于选择题型中最简单的难度等级。" + }, + { + "idx": 442, + "question": "In the crystal structure of iodides, iodine occupies the corners of the cube and the body-centered position, so its structure type is body-centered lattice.", + "answer": "(×)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（碘在晶体结构中的位置和结构类型），并要求判断其正确性（答案给出×表示错误），符合判断题的特征。 | 知识层次: 题目考查晶体结构类型的基本概念记忆和理解，涉及简单的晶体结构分类知识，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体结构类型的基本定义即可判断。在选择题型中属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 443, + "question": "The yield strength σs of crystalline materials changes with the variation of the tensile axis relative to the crystal orientation.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The yield strength σs of crystalline materials changes with the variation of the tensile axis relative to the crystal orientation），并要求判断其正确性（答案给出√表示正确）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查的是晶体材料屈服强度与拉伸轴相对于晶体取向变化的基本概念，属于基础概念的记忆和理解范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体材料屈服强度与拉伸轴方向关系的基本原理即可作答，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 444, + "question": "Generally speaking, during solid-state phase transformations, crystal defects in the parent phase can promote the formation of the new phase.", + "answer": "(√)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对固态相变中晶体缺陷作用的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 该题目属于基础概念正误判断，仅需记忆晶体缺陷对固态相变的影响这一基本原理即可作答。在选择题型中属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 484, + "question": "In the bainitic transformation, neither Fe nor C atoms undergo diffusion.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（In the bainitic transformation, neither Fe nor C atoms undergo diffusion），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查贝氏体转变过程中Fe和C原子扩散行为的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆贝氏体转变过程中Fe和C原子的扩散行为即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 485, + "question": "In the solid-state crystal diffusion process, the direction of diffusing atom migration is always from high concentration to low concentration.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查固体晶体扩散过程中原子迁移方向的基本概念，属于对基本原理的记忆和理解。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆扩散过程的基本原理即可作答，无需深入理解或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 486, + "question": "The finer the grain size, the higher the strength and hardness of the crystal, and the better the plasticity and toughness.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶粒尺寸与材料力学性能关系的基本概念记忆，属于材料科学中最基础的知识点之一，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆晶粒尺寸与材料性能的基本关系即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 487, + "question": "During solid-state phase transformation, crystal defects in the parent phase hinder the formation of nuclei of the new phase.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述句要求判断对错，答案以\"√\"形式给出，符合判断题的特征 | 知识层次: 题目考查对固态相变过程中晶体缺陷对成核影响的基本概念的理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需考生记忆并判断\"晶体缺陷阻碍新相形核\"这一基本原理的正确性。在选择题型中，这类直接考察定义和基本原理记忆的题目属于最简单的难度等级，不需要复杂的概念理解或分析过程。" + }, + { + "idx": 489, + "question": "Component crystal types differ, but under specific conditions, they can also form infinitely miscible solid solutions.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对晶体类型和固溶体形成条件的基本概念记忆，属于基础概念层面的判断题 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆晶体类型和固溶体的基本定义即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 490, + "question": "Polymers with simple structures, high regularity, and good symmetry are prone to crystallization.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物结晶基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅涉及聚合物结晶的基本原理，即结构简单、规则性高和对称性好的聚合物易于结晶这一基础概念的陈述。正确选项为√，表明这是一个直接的记忆性知识判断，无需复杂的分析或推理。因此，在选择题型内，该题目属于最低难度等级。" + }, + { + "idx": 491, + "question": "Two edge dislocations with opposite signs and parallel dislocation lines on the same slip plane will move away from each other due to their interaction.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征。 | 知识层次: 题目考查对位错相互作用这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆位错相互作用的基本原理即可判断正误。在选择题型中属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 493, + "question": "In the cesium chloride structure, chlorine occupies the corner positions and the body center position of the cube, so its structure type is body-centered lattice.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（关于氯化铯结构的描述），并要求判断其正确性（答案用×表示错误），这符合判断题的特征。 | 知识层次: 题目考查对晶体结构类型的基本概念记忆和理解，涉及简单的定义和分类知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆并识别氯化铯结构的正确描述即可。题目直接考察对体心晶格定义的理解，无需复杂分析或推理步骤，属于最基础难度等级。" + }, + { + "idx": 495, + "question": "The reason why the carbon solubility of austenite is higher than that of ferrite is that the interstitial spaces in the austenite crystal structure are larger.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），这是典型的判断题特征 | 知识层次: 题目考查对奥氏体和铁素体晶体结构中碳溶解度的基本概念的理解，属于基础概念的记忆和简单理解范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆奥氏体和铁素体的晶体结构差异这一基本原理即可作答。在选择题型中，这类仅涉及单一概念记忆的判断题属于最低难度等级。" + }, + { + "idx": 683, + "question": "All symmetry elements present in macroscopic crystals must pass through the center of the crystal", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体对称元素基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念正误判断，仅需记忆晶体对称元素的基本定义即可作答，无需深入理解或分析。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 684, + "question": "The symmetry characteristic of the cubic crystal system is having four 3-fold axes", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（立方晶系的对称性特征是具有四个三重轴），并要求判断其正确性（√表示正确），这是典型的判断题形式 | 知识层次: 题目考查立方晶系对称性特征的基础概念记忆，仅需判断\"四个三次轴\"这一基本特征的正确性，属于定义性知识的直接应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断立方晶系的对称性特征是否正确，即是否具有四个三重轴。这属于基础概念的记忆性知识，不需要深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 685, + "question": "The core of microscopic symmetry elements is the translation axis", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述句要求判断对错（√表示正确），符合判断题的特征 | 知识层次: 题目考查对微观对称元素核心概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，这道题目属于非常基础的正误判断题，仅需要考生记忆微观对称元素的核心概念（平移轴）即可做出正确判断。题目不涉及概念理解或复杂陈述的分析，完全符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 686, + "question": "Amorphous silicon prepared by CVD method also possesses the four general characteristics of glass", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（\"Amorphous silicon prepared by CVD method also possesses the four general characteristics of glass\"），并要求判断其正误（答案给出\"×\"表示错误），这符合判断题的特征。 | 知识层次: 题目考查对非晶硅和玻璃基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需要考生记忆无定形硅的基本特性即可作答。在选择题型中，这类直接考察定义和分类的记忆性知识题目属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 688, + "question": "Order-disorder transformation refers to the transformation between crystals and non-crystals", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案给出的是×表示错误），符合判断题的特征 | 知识层次: 题目考查对有序-无序转变这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆\"有序-无序转变\"的定义即可判断对错，无需理解或分析复杂概念，解题步骤简单直接。" + }, + { + "idx": 689, + "question": "A solid solution is an amorphous solid that has dissolved impurity components", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（A solid solution is an amorphous solid that has dissolved impurity components），并要求判断其正确性（答案给出×表示错误），符合判断题的特征。 | 知识层次: 题目考查对固溶体（solid solution）基本概念的记忆和理解，需要判断陈述是否正确，属于基础概念记忆的范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆固体溶液的定义即可判断正误。在选择题型中，这类题目对知识点掌握深度要求最低，解题步骤最简单，属于最基础的难度等级。" + }, + { + "idx": 690, + "question": "Most solid-phase reactions are controlled by diffusion rates", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对固相反应控制机制这一基础概念的记忆和理解，属于基本原理的记忆性知识 | 难度: 该题目属于基础概念正误判断题，仅需记忆\"大多数固相反应由扩散速率控制\"这一基本原理即可作答。在选择题型中，这类直接考察定义和基本原理记忆的题目属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 691, + "question": "At low temperatures, the diffusion that generally occurs in crystals is intrinsic diffusion", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体中扩散类型的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆类，仅需判断\"低温下晶体中通常发生的扩散是内扩散\"这一陈述的正确性。在选择题型中，这属于最简单的正误判断题，无需复杂推理或概念比较，仅需对基本定义有记忆即可。因此符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 692, + "question": "In the wetting of solid-liquid interfaces, increasing the roughness of the solid surface necessarily improves wetting.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案以×表示错误，符合判断题的特征。 | 知识层次: 题目考查对固体-液体界面润湿现象中表面粗糙度影响的基本概念的理解，属于基础概念的记忆和简单应用。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅考察对固体-液体界面润湿基本原理的记忆，即表面粗糙度并不必然改善润湿性。不需要理解复杂概念或进行多步骤分析，只需识别陈述是否正确。属于最基础的概念判断题。" + }, + { + "idx": 694, + "question": "Sintering is a process that involves various physical and chemical changes", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（以×表示错误），符合判断题的特征 | 知识层次: 题目考查对烧结过程的基本概念的理解和记忆，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断题，仅需记忆烧结过程的基本定义即可判断正误，无需深入理解或分析多个概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 714, + "question": "There are countless translational axes in the crystal structure", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体结构中平移轴的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆晶体结构中存在无数平移轴这一基本原理即可做出正确选择，无需复杂理解或分析步骤。" + }, + { + "idx": 715, + "question": "Pauling's rules apply to all crystal structures", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征 | 知识层次: 题目考查对Pauling规则适用范围的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念正误判断题，仅需记忆Pauling规则的基本适用范围即可作答。在选择题型中，这类题目仅测试学生对基本定义的记忆能力，无需理解或分析复杂概念，因此属于最低难度等级。" + }, + { + "idx": 716, + "question": "The ratio of the intercepts of a crystal plane on the three coordinate axes must be a simple integer ratio", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体学中晶面截距比的基本概念，属于基础知识的记忆和理解层面，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念正误判断，仅需记忆晶体平面截距比的基本定义即可作答，无需理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 719, + "question": "The dislocation line of an edge dislocation is parallel to the slip direction.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对位错线方向与滑移方向关系的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆边缘位错的位错线与滑移方向的关系即可作答，无需深入理解或分析。" + }, + { + "idx": 720, + "question": "Generally speaking, grain boundaries are the main diffusion channels for pores to reach the exterior of the sintered body.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查对晶界作为烧结体中孔隙扩散主要通道这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶界是烧结体中孔隙扩散的主要通道这一基本原理即可作答，无需深入理解或分析多个概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 722, + "question": "Feldspar is a silicate crystal with a layered structure", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对长石（Feldspar）晶体结构这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆长石（Feldspar）的基本结构特征即可作答。题目直接给出陈述，要求判断其正确性，无需复杂推理或概念间的关联分析，符合等级1的难度标准。" + }, + { + "idx": 723, + "question": "For some materials, no matter how fast the cooling rate is, it is impossible to form a glass", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征 | 知识层次: 题目考查对材料科学中玻璃形成能力的基本概念的理解，涉及冷却速率与玻璃形成之间的关系，属于基础概念的记忆和简单判断。 | 难度: 该题目属于基础概念正误判断题，仅需记忆材料科学中关于玻璃形成的基本原理即可作答。在选择题型中，这类题目仅需识别正确选项，不涉及复杂概念理解或分析过程，属于最简单的难度等级。" + }, + { + "idx": 724, + "question": "The flow of clay slurry belongs to plastic flow", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The flow of clay slurry belongs to plastic flow），要求判断其正确性（√），这是典型的判断题形式。答案只需判断对错，不需要选择或解释。 | 知识层次: 题目考查对粘土浆流动性质的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆粘土浆的流动类型属于塑性流动这一基本定义即可作答。在选择题型中，这类仅需识别基础概念正误的题目属于最低难度等级。" + }, + { + "idx": 725, + "question": "The Jander equation has a wider applicable range than the Ginstling equation", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The Jander equation has a wider applicable range than the Ginstling equation），并要求判断其正误（答案：×），这符合判断题的特征。 | 知识层次: 题目考查对Jander方程和Ginstling方程适用范围的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆Jander方程和Ginstling方程的适用范围即可做出判断，无需深入理解或分析。" + }, + { + "idx": 726, + "question": "Non-stoichiometric structural defects are a type of impurity defect caused by doping", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案用×表示错误），符合判断题的特征 | 知识层次: 题目考查对非化学计量结构缺陷类型的基本概念记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念正误判断题，仅需记忆非化学计量缺陷的定义和分类即可作答。在选择题型中，这类题目仅考察最基本的概念记忆能力，无需理解或分析过程，因此属于最低难度等级。" + }, + { + "idx": 727, + "question": "At low temperatures, the diffusion that generally occurs in crystals is extrinsic diffusion", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体扩散类型的基础概念记忆，特别是低温下扩散类型的判断，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆低温下晶体扩散类型的基本定义即可作答，无需复杂理解或分析步骤。" + }, + { + "idx": 728, + "question": "Most solid-phase reactions are controlled by the diffusion rate.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（用×表示错误），符合判断题的特征 | 知识层次: 题目考查对固相反应控制因素这一基本概念的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题型中属于基本概念正误判断，仅需记忆固体相反应通常由扩散速率控制这一基本原理即可判断正误，无需深入理解或分析复杂概念。" + }, + { + "idx": 729, + "question": "During the cooling process of the melt, the greater the degree of undercooling, the greater the overall crystallization rate", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对结晶速率与过冷度关系这一基本概念的记忆和理解，属于材料科学中的基础知识点。 | 难度: 在选择题型中，此题属于基本概念正误判断，仅需记忆并确认\"过冷度与结晶速率的关系\"这一基础概念的正确性，无需深入理解或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 731, + "question": "In a narrow sense, the phase transition process is a physical change process", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对相变过程基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆狭义相变过程的定义即可作答，无需深入理解或分析。" + }, + { + "idx": 760, + "question": "In the orthorhombic crystal system, the (001) plane must be perpendicular to the (110) plane", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对正交晶系中晶面垂直关系的基本概念记忆和理解，属于晶体学基础知识的直接应用，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅考察对正交晶系中晶面垂直关系的基础定义记忆，不需要理解或分析多个概念，解题步骤非常简单直接。" + }, + { + "idx": 763, + "question": "In macroscopic crystals, the symmetry elements present must all pass through the center of the crystal", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对晶体对称性基础概念的简单记忆和理解，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆层次，仅需判断对称元素是否必须通过晶体中心这一基本定义的正确性。在选择题型中，这种直接的正误判断题属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 766, + "question": "Diamond, graphite, and carbon nanotubes are allotropes of carbon", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Diamond, graphite, and carbon nanotubes are allotropes of carbon），并要求判断其正误（答案：√），这符合判断题的特征 | 知识层次: 题目考查对碳的同素异形体的基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念正误判断，仅需记忆碳的三种同素异形体名称即可作答，无需理解或分析复杂概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 771, + "question": "As long as the temperature is above 0K, point defects always exist in crystals", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查晶体中点缺陷存在的基本原理，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆点缺陷在晶体中存在的条件即可作答，无需深入理解或分析。题目直接考察对\"温度高于0K时晶体中总是存在点缺陷\"这一基础概念的识记能力，属于最基础的难度等级。" + }, + { + "idx": 772, + "question": "Fick's first law is applicable to solving unstable diffusion problems", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为×表示错误），符合判断题的特征 | 知识层次: 题目考查对Fick's first law适用范围这一基本概念的简单记忆和理解，不涉及复杂应用或分析 | 难度: 该题目属于基础概念正误判断题，仅需记忆Fick第一定律的适用范围即可作答，无需理解或分析复杂概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 773, + "question": "In the cubic crystal system, the possible types of space lattices are F, I, and C", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（立方晶系中可能的空间格子类型是F、I和C），并要求判断其正确性（答案给出×表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查立方晶系中空间点阵类型的基本概念记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆立方晶系中可能的空间格子类型即可做出正确判断，无需深入理解或复杂分析。" + }, + { + "idx": 775, + "question": "The critical radius of the nucleus $r_{k}$ decreases with increasing $\\Delta T$, making the phase transition easier to proceed.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（The critical radius of the nucleus $r_{k}$ decreases with increasing $\\Delta T$, making the phase transition easier to proceed），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查对临界核半径与过冷度关系这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅考察对\"临界核半径与过冷度关系\"这一基础概念的记忆，不需要理解或分析多个概念。正确选项直接对应教材中的基本原理表述，属于最基础的定义性知识考察，因此难度等级为1。" + }, + { + "idx": 778, + "question": "During the growth of crystals, there must be the presence of undercooling", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（×表示错误），符合判断题的特征 | 知识层次: 题目考查晶体生长过程中过冷现象的基本概念记忆和理解，属于基础概念层次 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆晶体生长过程中过冷度的基本定义即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 779, + "question": "For the same system, the nucleation barrier for heterogeneous nucleation ≤ the nucleation barrier for homogeneous nucleation.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（异质成核的成核势垒≤均质成核的成核势垒），要求判断其正确性（答案为√表示正确），这符合判断题的特征 | 知识层次: 题目考查对异质成核和均质成核能垒差异的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆并确认\"异质成核能垒≤均质成核能垒\"这一基本原理的正确性，无需深入理解或分析多个概念，解题步骤简单直接。" + }, + { + "idx": 780, + "question": "Liquid phase sintering refers to a sintering process in which a liquid phase is present.", + "answer": "×", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案用×表示错误），符合判断题的特征 | 知识层次: 题目考查对液相烧结这一基本概念的记忆和理解，属于定义性知识的判断，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念正误判断题，仅需记忆液相烧结的定义即可判断正误，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 877, + "question": "Determine whether the following dislocation reaction can occur in FCC and confirm the reaction direction in the absence of external force: 1/6[112]+1/6[110]⇔1/3[111]", + "answer": "It can occur, to the left.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否可以在FCC中发生，并确认反应方向，答案给出了明确的判断（可以发生）和方向（向左），属于判断陈述的对错类型。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应的方向和可能性。这涉及到多步分析和概念关联，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题型中，该题目需要综合分析位错反应的能量条件和方向判断，涉及多步计算和概念关联，属于中等应用层次。需要考生不仅理解位错反应的基本原理，还要能够应用这些原理进行具体分析，判断反应的方向和可能性。这种综合分析能力的要求使得该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 884, + "question": "Determine whether the following dislocation reaction can occur in FCC and confirm the reaction direction in the absence of external forces: 1/2[10−1]⇔1/6[2−1−1]+1/6[11−1]", + "answer": "It can occur, to the right.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否可以在FCC中发生，并确认反应方向，答案给出了明确的判断（可以发生）和方向（向右），符合判断题的特征。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应是否可行以及反应方向。这涉及到多步分析和概念关联，而不仅仅是简单的记忆或直接套用公式。 | 难度: 在选择题型中，该题目属于较高难度。需要综合运用以下能力：" + }, + { + "idx": 889, + "question": "Determine whether the following dislocation reaction can proceed in FCC and confirm the reaction direction in the absence of external forces: 1/3[112]+1/2[111]⇔1/6[11−1]", + "answer": "The reaction cannot proceed.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能进行，并给出明确结论（\"The reaction cannot proceed\"），这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目需要理解位错反应的基本原理，并能够应用这些原理来判断反应是否可行。虽然不涉及复杂的计算，但需要对FCC晶体结构中的位错类型和反应方向有较深入的理解，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。需要综合运用位错反应的能量条件（Frank判据）和晶体学知识进行多步计算和判断。解题过程涉及矢量运算、能量比较和反应方向分析，属于需要综合分析结果判断的类型。虽然题目提供了反应式，但需要考生自行验证反应前后的能量变化和晶体学可行性，比单纯的概念识别或简单计算题更复杂。" + }, + { + "idx": 1084, + "question": "Are the shapes of the room-temperature tensile curves of low-carbon steel and aluminum alloy the same?", + "answer": "The shapes of the room-temperature tensile curves of low-carbon steel and aluminum alloy are not the same.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（低碳钢和铝合金的室温拉伸曲线形状是否相同），答案直接给出了明确的判断结果（不相同），符合判断题的特征。 | 知识层次: 题目考查对低合金钢和铝合金室温拉伸曲线形状差异的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目要求考生比较低碳钢和铝合金的室温拉伸曲线形状是否相同，这需要考生掌握两种材料的基本拉伸行为特征，属于对基础概念的对比理解。虽然需要记忆两种材料的特性，但不需要复杂的分析或推理过程，因此属于中等偏下的难度等级。" + }, + { + "idx": 1097, + "question": "For metals or alloys without phase transformation in the solid state, their grain size cannot be changed unless remelted.", + "answer": "For metals or alloys without phase transformation in the solid state, their grain size can also be changed through plastic deformation and recrystallization treatment without remelting.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目陈述了一个观点，答案是对该观点的判断和修正，符合判断题的特征 | 知识层次: 题目涉及金属或合金的晶粒尺寸变化机制，需要理解塑性变形和再结晶处理对晶粒尺寸的影响，属于多概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。题目涉及金属或合金的晶粒尺寸变化机制，需要考生理解无固态相变材料的晶粒尺寸改变途径（塑性变形和再结晶处理），并能综合分析题目陈述的错误之处。这要求考生不仅掌握基础概念，还能进行多步骤的逻辑推理和判断，属于综合分析结果判断的难度等级。" + }, + { + "idx": 1112, + "question": "The Burgers vector of edge dislocations and screw dislocations changes with the direction vector of the dislocation line.", + "answer": "Wrong! The Burgers vector of an edge dislocation is perpendicular to the direction vector of the dislocation line; the Burgers vector of a screw dislocation is parallel to the direction vector of the dislocation line.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个观点（The Burgers vector of edge dislocations and screw dislocations changes with the direction vector of the dislocation line），并要求判断其正确性。答案明确指出了该陈述是错误的，并给出了正确的解释。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对位错类型及其Burgers向量方向的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（位错的Burgers矢量方向），但需要考生理解并区分两种不同类型位错（刃型位错和螺型位错）的Burgers矢量与位错线方向的关系。这比单纯记忆定义（等级1）要求更高，但尚未达到需要分析复杂概念陈述（等级3）的程度。" + }, + { + "idx": 1113, + "question": "Both austenite and pearlite are solid solutions of carbon in $\\alpha-\\mathrm{\\bfFe}$ with a body-centered cubic structure.", + "answer": "Wrong! Austenite is a solid solution of carbon in $\\gamma.$ -Fe with a face-centered cubic structure, while pearlite is a two-phase structure composed of ferrite and cementite.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Both austenite and pearlite are solid solutions of carbon in α-Fe with a body-centered cubic structure），要求判断其正确性。答案明确指出该陈述是错误的，并给出了正确的解释。这符合判断题的特征，即判断陈述的对错并给出解释。 | 知识层次: 题目考查对奥氏体和珠光体这两种材料的基本概念的记忆和理解，包括它们的晶体结构和组成。这属于基础概念记忆的范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解并区分奥氏体和珠光体的晶体结构及组成，但不需要复杂的分析或推理。" + }, + { + "idx": 1115, + "question": "The diffusion of solute atoms always proceeds from regions of high concentration to regions of low concentration.", + "answer": "Wrong! The accurate statement is that the diffusion of solute atoms always proceeds from regions of high chemical potential to regions of low chemical potential. Only in this way can the driving force of reactive diffusion be satisfactorily explained.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性，答案明确指出该陈述是错误的并给出正确表述，符合判断题的特征。 | 知识层次: 题目不仅需要理解扩散的基本概念（从高浓度到低浓度），还需要理解化学势在扩散过程中的作用，这涉及到概念的关联和综合分析。虽然题目形式是判断题，但需要更深入的理解才能正确判断陈述的对错。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生掌握扩散的基本概念（从高浓度到低浓度），还需要理解更深入的化学势概念。正确选项涉及对扩散驱动力的本质理解（化学势梯度而非浓度梯度），并能解释反应扩散的驱动力机制。这需要考生将扩散理论与热力学概念进行综合关联分析，属于中等应用层次的多步概念判断。相比单纯记忆浓度梯度扩散的题目（难度2-3），本题需要更高层次的概念整合能力。" + }, + { + "idx": 1116, + "question": "Both martensitic transformation and bainitic transformation are diffusionless solid-state phase transformations.", + "answer": "Wrong! Martensitic transformation is a diffusionless solid-state phase transformation, while bainitic transformation involves both a diffusionless shear process and a diffusive atomic transport process, they are not the same.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述（Both martensitic transformation and bainitic transformation are diffusionless solid-state phase transformations），并要求判断其正确性（答案指出该陈述是错误的）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对马氏体相变和贝氏体相变这两种固态相变基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型内，该题目属于概念理解的对错判断难度等级。题目考察学生对马氏体相变和贝氏体相变的基本概念的理解，需要区分两种相变过程的差异。虽然涉及两个概念，但都属于基础概念记忆层次，解题步骤相对简单，只需判断陈述是否正确即可。因此属于等级2难度。" + }, + { + "idx": 1117, + "question": "In the iron-carbon phase diagram, the horizontal line where the eutectoid reaction occurs has two-phase regions both above and below it, which does not conform to the phase region contact rule.", + "answer": "Wrong! The horizontal line where the eutectoid reaction occurs in the iron-carbon phase diagram represents a three-phase equilibrium reaction, which is actually a three-phase region. Thus, the difference in the number of phases between the two-phase regions above and below the horizontal line is still 1, still conforming to the phase region contact rule.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个关于铁碳相图的观点，并要求判断其正确性。答案明确指出了该陈述是错误的，并给出了解释。这符合判断题的特征，即判断陈述的对错并给出理由。 | 知识层次: 题目考查对铁碳相图中共析反应水平线的基本概念的理解，涉及相区接触规则的应用，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察了对铁碳相图中共析反应水平线的理解，需要考生掌握相区接触规则的基本原理，并能够正确判断题目陈述的错误之处。虽然涉及多个概念，但主要考察的是对基础概念的理解和应用，解题步骤相对直接，不需要复杂的分析过程。" + }, + { + "idx": 1219, + "question": "Dislocations belong to crystal defects and also to line defects.", + "answer": "~\\\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案使用了判断题常见的符号（√）表示正确。 | 知识层次: 题目考查对晶体缺陷分类的基本概念记忆，属于定义和分类的基础知识层次。 | 难度: 在选择题型中，该题目属于非常基础的概念正误判断。题目仅要求考生记忆并识别位错（dislocations）属于晶体缺陷和线缺陷这一基本分类知识，不需要进行任何概念理解或复杂分析。这种类型的题目只需要考生对基础定义和分类有简单的记忆即可正确回答，因此属于难度等级1。" + }, + { + "idx": 1220, + "question": "Peritectic transformation refers to the transformation in which a liquid phase interacts with a solid phase, enveloping the original solid phase to form another new solid phase.", + "answer": "~\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（包晶转变的定义），并要求判断其正确性（答案标记为正确符号~\\surd~），这符合判断题的特征 | 知识层次: 题目考查对包晶转变（Peritectic transformation）这一基本概念的记忆和理解，属于定义性知识的判断，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接给出了包晶转变的定义，要求判断其正确性。这种题目只需要学生对基础概念有记忆即可作答，不需要深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 1221, + "question": "Materials with different crystal lattices have different slip systems, thus their tendency to deform also varies.", + "answer": "~\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案以对错符号（~\\surd~）给出，符合判断题的特征 | 知识层次: 题目考查晶体结构和滑移系统的基本概念，属于基础概念的记忆和理解层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求识别晶体结构与变形倾向之间的基本关系，属于基础概念记忆层次，无需深入理解或分析多个概念。解题步骤简单，只需判断陈述的正确性。" + }, + { + "idx": 1222, + "question": "The higher the dislocation density, the larger the Burgers vector of the corresponding dislocation.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案以\"~\\\\times~\"形式给出，表示错误判断，这是典型的判断题特征 | 知识层次: 题目考查对位错密度和伯格斯矢量之间关系的基本概念的理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆并判断位错密度与伯格斯矢量之间的基本关系是否正确。题目陈述简单直接，不需要复杂的理解或分析过程，在选择题型中属于最基本的难度等级。" + }, + { + "idx": 1223, + "question": "Generally, the higher the activation energy for atomic diffusion in a crystal, the larger the diffusion coefficient and the faster the diffusion rate.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（\"Generally, the higher the activation energy for atomic diffusion in a crystal, the larger the diffusion coefficient and the faster the diffusion rate.\"），并要求判断其正确性（答案标记为~\\\\times~表示错误）。这是典型的判断题形式，不需要计算或解释，只需判断陈述的对错。 | 知识层次: 题目考查对原子扩散基本概念的理解，即激活能与扩散系数之间的关系，属于基础概念的记忆和理解层面。 | 难度: 该题目属于基础概念正误判断，仅需记忆激活能与扩散系数之间的关系即可作答，无需复杂推理或概念比较。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1224, + "question": "Stacking faults result from the local presence of an extra half atomic plane in the crystal lattice.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案形式为判断符号（~\\\\times~表示错误），符合判断题的特征 | 知识层次: 题目考查堆垛层错的基本概念，属于晶体缺陷的基础知识，主要依赖记忆和理解。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于堆垛缺陷的定义是否正确。在选择题型中，这类题目仅涉及单一概念的正误判断，无需深入理解或分析，因此属于最低难度等级。" + }, + { + "idx": 1225, + "question": "Metal solidification occurs through two processes: nucleation of the solid phase and grain growth. During the grain growth process, the liquid-solid interface of pure metals (such as Fe, Ni, Cu, Au, etc.) generally remains smooth.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（金属凝固过程中纯金属的液固界面通常保持平滑），并要求判断其正确性（答案给出的是×，表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查金属凝固过程中晶粒生长和液固界面形态的基础概念记忆，属于对基本原理的记忆性知识 | 难度: 该题目属于基础概念记忆层次，仅需判断关于金属凝固过程中液固界面形态的基本陈述是否正确。题目涉及的知识点较为简单，属于纯记忆性内容，无需深入理解或分析多个概念。在选择题型中，此类正误判断题通常属于最低难度等级。" + }, + { + "idx": 1226, + "question": "Non-equilibrium crystallization refers to the crystallization of an alloy under actual cooling conditions where the cooling rate is relatively high, deviating from equilibrium conditions. Under non-equilibrium conditions, the composition of the newly formed solid solution after a homogeneous transformation is inhomogeneous.", + "answer": "~\\\\surd~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（答案用对勾符号表示正确） | 知识层次: 题目考查非平衡结晶的基本定义和特征，属于基础概念的记忆和理解范畴，不涉及复杂计算或综合分析。 | 难度: 该题目属于基础概念正误判断题，仅需识别非平衡结晶的定义特征即可作答。题目直接给出定义性描述，无需推理或分析，属于选择题型中最简单的难度等级。" + }, + { + "idx": 1228, + "question": "Due to the varying degrees of tightness in the regular arrangement of atoms in different directions, the spacing between atoms and the bonding forces between them differ, resulting in different properties in different directions. Therefore, most metals and alloys also exhibit anisotropic characteristics.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目陈述了一个关于金属和合金各向异性特征的事实，答案以对错符号(~\\\\times~)的形式给出，符合判断题的特征。 | 知识层次: 题目考查对金属和各向异性特性的基本概念的理解和记忆，不涉及复杂的应用或分析。 | 难度: 该题目属于基础概念记忆层次，考察学生对金属和合金各向异性特性的理解。虽然涉及多个概念（原子排列紧密度、原子间距、键合力），但只需判断\"大多数金属和合金也表现出各向异性特性\"这一陈述的正确性，不需要进行复杂的概念比较或分析。在选择题型中，这属于需要理解概念但对错判断相对直接的中等难度题目。" + }, + { + "idx": 1230, + "question": "Solid-state diffusion: (1) The diffusion of iron atoms in steel belongs to self-diffusion and is unrelated to the concentration gradient. (2) The diffusion of alloying elements in steel belongs to hetero-diffusion; in the absence of a chemical gradient, it is related to the concentration gradient. (3) The first law of diffusion is only applicable to steady-state diffusion conditions, hence it cannot be used to accurately determine the diffusion coefficient of carbon during the carburization process of steel. (4) Up-hill diffusion is solely related to the chemical gradient of the diffusing element and is unrelated to the concentration gradient. (5) The multiplication of dislocations is achieved through the diffusion movement of atoms.", + "answer": "(1)(4)(5)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出多个陈述，要求判断哪些陈述是正确的（即(1)(4)(5)），这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目主要考查对固体扩散基本概念的记忆和理解，如自扩散、异扩散、扩散定律的适用条件等，不涉及复杂的计算或综合分析。 | 难度: 在选择题型中，该题目属于中等难度。题目涉及多个扩散相关的基础概念（如自扩散、异扩散、上坡扩散等），需要考生不仅记忆这些定义，还要理解它们在不同条件下的应用和相互关系。虽然题目提供了明确的判断点（1）（4）（5），但需要考生对扩散机制有较好的理解才能准确判断每个陈述的正确性。题目不涉及复杂的计算或推导，但需要对基础概念有清晰的认识和区分能力。" + }, + { + "idx": 1231, + "question": "Steel with a carbon content below the composition of point $S$ in the Fe-C phase diagram cannot obtain a completely pearlitic structure under any composition or condition.", + "answer": "~\\\\times~", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目给出一个陈述（Steel with a carbon content below the composition of point $S$ in the Fe-C phase diagram cannot obtain a completely pearlitic structure under any composition or condition），并要求判断其正确性（答案用~\\\\times~表示错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目需要理解Fe-C相图中点S的含义，并能够分析不同碳含量下钢的组织转变能力，涉及相图知识的应用和综合分析能力。 | 难度: 在选择题中属于较高难度，需要综合分析Fe-C相图中关键点S的含义，理解珠光体形成的条件限制，并判断不同碳含量下的相变可能性。题目涉及多步概念关联和相图分析能力，要求考生在选择题框架内进行复杂的结果判断。" + }, + { + "idx": 1234, + "question": "Fracture characteristics of metals: (1) One form of brittle fracture is transgranular cleavage. (2) Cleavage fractures mainly exhibit river patterns. (3) The propagation direction of micro-cracks can be determined by the flow direction of the rivers, i.e., the convergence direction of the rivers indicates the crack propagation direction. (4) Some materials exhibit tongue patterns in their ductile fracture surfaces. (5) Ductile fractures mainly manifest as intergranular dimple fracture forms.", + "answer": "(2) (3) (5)", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出了一系列陈述，要求判断哪些陈述是正确的（即选择正确的陈述作为答案）。这种形式符合判断题的特征，即从多个陈述中识别出正确的部分。 | 知识层次: 题目考查金属断裂特征的基础概念记忆，包括脆性断裂和韧性断裂的形貌特征及其判断依据，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个关于金属断裂特性的陈述，但主要考察的是对基础概念的理解和判断。正确选项(2)、(3)、(5)需要考生能够区分脆性断裂和韧性断裂的特征，并理解河流花样和舌状花样等微观形貌的含义。虽然涉及多个概念，但都属于基础概念记忆层次，不需要复杂的分析或推理。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 1333, + "question": "Explain the reversibility of the second type of temper embrittlement", + "answer": "The second type of temper embrittlement is reversible.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"The second type of temper embrittlement is reversible\"），答案直接给出了对错判断（\"is reversible\"），符合判断题的特征。 | 知识层次: 题目考查对第二类回火脆性可逆性的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求对基础概念（第二类回火脆性的可逆性）进行正误判断，属于最基本的概念记忆层次，无需复杂理解或分析步骤。" + }, + { + "idx": 1396, + "question": "Determine whether the following statement is correct: After recovery annealing of cold-deformed metal, its mechanical properties can return to the state before deformation.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征 | 知识层次: 题目考查对冷变形金属在恢复退火后机械性能变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆金属材料冷变形和再结晶退火后的性能变化这一基本原理即可作答。在选择题型中，这类仅需识别定义或基本原理正确与否的题目属于最低难度等级。" + }, + { + "idx": 1399, + "question": "Determine whether the following statement is correct: Edge dislocations can undergo cross-slip.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个陈述的正确性（\"Edge dislocations can undergo cross-slip\"），并且给出了明确的判断结果（\"Incorrect\"）。这符合判断题的特征，即只需要判断陈述的对错，而不需要选择、计算或详细解释。 | 知识层次: 题目考查对位错基本行为（边缘位错的交滑移能力）这一基础概念的记忆和理解，属于材料科学中晶体缺陷的基础知识范畴。 | 难度: 该题目属于基础概念正误判断，仅需记忆边缘位错的基本特性即可作答。在选择题型中属于最简单的难度等级，不需要复杂分析或概念间的比较。" + }, + { + "idx": 1401, + "question": "Determine whether the following statement is correct: The distinction between hot (deformation) working and cold (deformation) working of metals is based on the temperature of the deformation process.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了正确或错误的结论，符合判断题的特征。 | 知识层次: 题目考查对金属热加工和冷加工区分标准的基本概念记忆，属于定义性知识的判断。 | 难度: 该题目属于基础概念正误判断，仅需记忆热加工和冷加工的定义区别即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1402, + "question": "Determine whether the following statement is correct: Recrystallization is a process of nucleation and core growth, therefore it is a phase transformation process.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征 | 知识层次: 题目考查对再结晶过程是否属于相变过程这一基本概念的理解和判断，属于基础概念的记忆和辨析范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆并识别\"再结晶\"的基本定义和特性即可作答。在选择题型中，这类直接考察定义记忆的题目属于最简单的难度等级，不需要复杂的分析或推理过程。" + }, + { + "idx": 1403, + "question": "Determine whether the following statement is correct: The growth of recrystallization nuclei is accompanied by the movement of grain boundaries, so the driving force is grain boundary energy.", + "answer": "Incorrect", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Incorrect\"的判断结果，符合判断题的特征。 | 知识层次: 题目涉及再结晶核生长和晶界移动的驱动力的判断，需要理解再结晶过程中的能量变化和晶界行为，属于概念关联和综合分析的中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析再结晶核生长过程中的驱动力来源，并正确判断晶界能并非主要驱动力。题目涉及中等应用层次的知识点关联和多步概念判断，要求考生区分表面能、应变能和晶界能等不同驱动力的作用机制。" + }, + { + "idx": 1405, + "question": "Determine whether the following statement is correct: Point defects in crystals are a type of thermodynamic equilibrium defect, while dislocations are not thermodynamic equilibrium defects.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了\"Correct\"，符合判断题的特征 | 知识层次: 题目考查对晶体缺陷类型及其热力学平衡性质的基本概念记忆和理解，属于基础概念层次 | 难度: 该题目属于基本概念正误判断，仅需记忆点缺陷和位错的热力学平衡特性即可作答。在选择题型中属于最简单的直接概念判断，无需复杂分析或推理过程。" + }, + { + "idx": 1453, + "question": "After cold plastic deformation, the strength and hardness of metal (40)", + "answer": "increase", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（冷塑性变形后金属的强度和硬度增加），并要求判断其正确性。答案\"increase\"是对该陈述的肯定判断，符合判断题的特征。 | 知识层次: 题目考查冷塑性变形对金属强度和硬度影响的基本概念记忆，属于材料科学中最基础的知识点之一，无需复杂分析或计算。 | 难度: 该题目属于基础概念记忆层次，仅需判断冷塑性变形后金属强度和硬度的变化趋势。正确选项\"increase\"是材料科学中最基础的概念之一，无需复杂分析或推理，属于选择题型中最简单的正误判断类型。" + }, + { + "idx": 1463, + "question": "The direction of crystal slip is the direction of dislocation line movement within the slip plane.", + "answer": "False", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案形式为True或False | 知识层次: 题目考查晶体滑移方向与位错线运动方向的基本概念记忆和理解，属于材料科学中位错理论的基础知识点。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体滑移方向与位错线运动方向的关系这一基本定义即可作答。在选择题型中，这类仅需识别概念正误的题目属于最低难度等级。" + }, + { + "idx": 1466, + "question": "A pure edge dislocation loop can form in a crystal.", + "answer": "True", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（True/False），符合判断题的特征 | 知识层次: 题目考查对位错类型（边缘位错环）这一基本概念的认知和理解，属于材料科学中晶体缺陷的基础知识范畴，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆边缘位错环的定义即可判断正确选项，无需深入理解或分析复杂概念。" + }, + { + "idx": 1468, + "question": "A screw dislocation line can only undergo glide motion, not climb motion.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（A screw dislocation line can only undergo glide motion, not climb motion），要求判断其正确性（Correct），这是典型的判断题特征。 | 知识层次: 题目考查对位错运动方式（滑移和攀移）的基本概念记忆和理解，属于材料科学中位错理论的基础知识点。 | 难度: 该题目属于基础概念正误判断题，仅需记忆螺丝位错线的基本运动特性（滑移与攀移的区别），无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1469, + "question": "In a binary alloy phase diagram, the greater the distance between the liquidus and solidus lines, the worse the fluidity of the alloy.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对二元合金相图中液相线和固相线距离与合金流动性关系的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆二元合金相图中液相线和固相线距离与合金流动性的关系这一基础概念即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 1470, + "question": "The presence of vacancies always increases the free energy of a crystal.", + "answer": "False", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（True/False），答案直接给出了False的判断，符合判断题的特征。 | 知识层次: 题目考查对晶体缺陷中空位概念的基本理解，属于基础概念的记忆和判断，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念正误判断题，仅需记忆晶体缺陷中空位对自由能影响的基本原理即可作答。在选择题型中属于最简单的直接判断类题目，无需复杂推理或概念比较。" + }, + { + "idx": 1471, + "question": "The presence of dislocations always increases the free energy of a crystal.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct/Incorrect），属于典型的判断题形式。答案只需给出对错判断，无需解释或计算。 | 知识层次: 题目考查对位错基本性质的理解，属于晶体缺陷的基础概念记忆范畴 | 难度: 该题目属于基础概念记忆层次，仅需判断关于位错增加晶体自由能量的陈述是否正确。在选择题型中，这类直接考察定义或基本原理记忆的题目属于最低难度等级，无需复杂分析或推理过程。" + }, + { + "idx": 1472, + "question": "The driving force for the growth of recrystallization nuclei is the reduction of deformation stored energy, while the driving force for the growth of recrystallized grains is the reduction of total grain boundary energy.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（Correct），属于典型的判断题形式 | 知识层次: 题目考查对再结晶过程中驱动力这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念正误判断题，仅需记忆再结晶核生长和再结晶晶粒生长的驱动力这两个基本概念即可作答，无需理解或分析复杂关系，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 1473, + "question": "In essence, a twin is also a stacking fault", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对孪晶和堆垛层错这两个基础概念的理解和记忆，属于材料科学中的基本概念辨析 | 难度: 该题目属于基础概念记忆层次，仅需判断\"孪晶也是一种堆垛层错\"这一陈述的正误。在选择题型中，这种直接考察定义或分类记忆的题目属于最基本的难度等级（等级1），不需要复杂的理解或分析过程。" + }, + { + "idx": 1474, + "question": "Under the condition of no solid-phase diffusion and complete liquid-phase mixing, constitutional supercooling cannot occur during the solidification of solid solutions.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征 | 知识层次: 题目考查对固溶体凝固过程中成分过冷条件的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对\"成分过冷\"这一基础概念的理解，需要考生掌握在特定条件下（无固相扩散和完全液相混合）成分过冷是否会发生的基本原理。虽然涉及多个条件限制，但核心概念较为明确，不需要复杂的分析推理过程，属于中等偏下的难度水平。" + }, + { + "idx": 1475, + "question": "In the vertical section of a ternary phase diagram, the lever rule cannot be used to determine the mass fractions of the three equilibrium phases.", + "answer": "Correct", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Correct），符合判断题的特征。题目没有提供多个选项，也不需要计算或文字解释，只需判断陈述的对错。 | 知识层次: 题目考查对三元相图中杠杆规则应用范围的基础概念记忆，仅需判断陈述是否正确，不涉及复杂分析或计算。 | 难度: 该题目属于基础概念正误判断，仅需记忆三元相图中杠杆规则的应用限制即可作答，无需深入理解或分析多个概念。在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1941, + "question": "For metals without phase transformation in the solid state, can the grain size be refined without remelting?", + "answer": "Yes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Yes/No），符合判断题的特征。答案直接给出\"是\"或\"否\"的判断结果，不需要选择、计算或解释。 | 知识层次: 题目考查对金属晶粒细化方法的基础概念记忆，特别是关于无固态相变金属的晶粒细化可能性，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆金属晶粒细化方法的基本原理即可作答，无需复杂分析或概念比较。题目直接询问是否可以通过非重熔方式细化晶粒，属于最基础的定义性知识考查。" + }, + { + "idx": 1943, + "question": "In an FCC crystal, does the dislocation reaction a/2[10-1] + a/6[-121] → a/3[11-1] satisfy the geometric conditions?", + "answer": "Geometric conditions: b1 + b2 = (1/2 - 1/6)a + (0 + 2/6)b + (-1/2 + 1/6)c = 1/3a + 1/3b - 1/3c = a/3[11-1], satisfying the geometric conditions.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个具体的陈述（位错反应是否满足几何条件）的对错，答案给出了明确的判断依据和计算过程，符合判断题的特征 | 知识层次: 题目涉及位错反应几何条件的验证，需要进行多步计算和概念关联，包括矢量相加和验证是否符合几何条件。虽然不涉及复杂的推理分析或机理解释，但需要一定的综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解FCC晶体中的位错反应，并能够进行矢量计算。其次，解题过程涉及多步计算（矢量相加和分量计算），需要考生具备较强的空间想象能力和数学运算能力。最后，题目要求考生综合判断几何条件是否满足，这需要对位错反应的基本原理有深入理解。因此，该题目在选择题型中属于综合分析结果判断的难度等级。" + }, + { + "idx": 1977, + "question": "Determine whether the following dislocation reaction can proceed: $a[100]\\\\rightarrow\\\\frac{a}{2}[101]+\\\\frac{a}{2}[10{\\\\overline{{1}}}]$", + "answer": "No. Energy condition: $\\\\sum b_{\\\\mathbb{M}}^{2}=\\\\sum b_{E}^{2}=a^{2}$, the energy on both sides is equal.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能进行，答案直接给出\"是\"或\"否\"的判断结果，并附带简要解释。这符合判断题的特征，即对某个陈述或命题进行真伪判断。虽然答案中包含能量计算说明，但核心要求仍是判断反应能否进行。 | 知识层次: 题目需要应用位错反应的能量条件进行计算和判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。需要考生掌握位错反应的能量条件计算，能够正确应用矢量运算进行能量比较（∑b²的计算）。题目涉及多步概念关联（位错反应规则、能量条件判断）和综合分析（两边能量相等时的反应可能性判断），超出了简单的概念记忆或单步计算。虽然题目提供了正确选项，但解题过程需要较强的材料科学理论基础和计算能力，属于中等应用层次中较复杂的题目。" + }, + { + "idx": 1980, + "question": "Determine whether the following dislocation reaction can occur: $\\\\frac{a}{3}[112]+\\\\frac{a}{2}[111]\\\\rightarrow\\\\frac{a}{6}[11\\\\overline{{{1}}}]$", + "answer": "No. Geometric condition: $\\\\sum b_{\\\\mathbb{H}}=\\\\frac{a}{b}[557],\\\\sum b_{\\\\mathbb{H}}=\\\\frac{a}{b}[11\\\\overline{{1}}]$, cannot be satisfied.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能够发生，答案直接给出了\"否\"的判断结果，并提供了几何条件的验证依据。这符合判断题的特征，即对陈述或命题进行真伪判断。 | 知识层次: 题目需要应用位错反应的基本原理进行几何条件的判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求判断位错反应是否能够发生，这需要理解位错反应的几何条件和能量条件。其次，解题过程涉及多步计算和概念关联，包括位错矢量的计算和比较。最后，题目要求综合分析计算结果来判断反应是否满足条件，这超出了简单的概念记忆或单一计算步骤，属于中等应用层次的知识要求。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 1985, + "question": "Determine whether the following dislocation reaction can proceed: $\\\\frac{a}{2}[10\\\\overline{{{1}}}]+\\\\frac{a}{6}[\\\\overline{{{1}}}21]\\\\rightarrow\\\\frac{a}{3}[11\\\\overline{{{1}}}]$", + "answer": "Yes. Geometric condition: $\\\\sum b_{\\\\tt H}=\\\\sum b_{\\\\tt G}=\\\\frac{\\\\alpha}{3}[11\\\\overline{{1}}]$; energy condition: $\\\\sum b_{\\\\mathbb{H}}^{2}={\\\\frac{2}{3}}a^{2}>$ $\\\\sum b_{E}^{2}={\\\\frac{1}{3}}a^{2}.$", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能够进行，答案给出了明确的\"yes\"判断，并提供了几何条件和能量条件的验证，符合判断题的特征。 | 知识层次: 题目需要应用位错反应的能量条件和几何条件进行判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求判断位错反应是否可以进行，这需要理解位错反应的几何条件和能量条件。其次，解题过程涉及多个步骤的计算和概念的综合应用，包括矢量运算和能量比较。虽然题目提供了正确选项，但学生仍需具备扎实的基础知识和综合分析能力才能正确判断。因此，在选择题型内，该题目属于等级4的难度。" + }, + { + "idx": 1987, + "question": "Determine whether the following dislocation reaction can proceed: $a[100]\\\\rightarrow\\\\frac{a}{2}[111]+\\\\frac{a}{2}[1\\\\overline{{{11}}}]_{\\\\circ}$.", + "answer": "No. Energy condition: $\\\\sum b_{\\\\mathbb{H}}^{2}=a^{2}<\\\\sum b_{\\\\mathbb{H}}^{2}={\\\\frac{3}{2}}a^{2}$, meaning the energy increases after the reaction.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断位错反应是否能进行，答案直接给出了\"是\"或\"否\"的判断，并提供了能量条件的解释。这符合判断题的特征，即对某个陈述或现象进行真伪判断。 | 知识层次: 题目需要应用位错反应的能量条件进行判断，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题中属于较高难度，需要综合运用位错能量计算和反应条件判断的知识。题目要求考生不仅理解位错反应的能量条件（∑b²），还需要进行多步计算和比较（计算反应前后总伯氏矢量的平方和），最后综合分析得出反应不能进行的结论。这超出了单纯概念记忆或简单计算的范畴，属于需要综合分析判断的题目类型。" + }, + { + "idx": 1998, + "question": "Can a dislocation loop be formed by inserting a columnar half-atom plane in a crystal?", + "answer": "No. Because a dislocation loop can only be formed when the crystal inside the loop undergoes slip while the crystal outside does not.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（\"Can a dislocation loop be formed...\"），答案直接给出对错判断（\"No\"）并简要解释原因，符合判断题的特征。 | 知识层次: 题目考查对位错环形成条件的基本概念的理解和记忆，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解位错环的形成机制，并能够区分插入半原子平面与位错环形成的不同条件。正确选项的解释需要考生对位错环的形成原理有一定的理解，而不仅仅是简单的定义记忆。因此，该题目在选择题型中属于概念理解的对错判断难度等级。" + }, + { + "idx": 2002, + "question": "Is the statement 'Small-angle grain boundaries are all formed by edge dislocations arranged into walls' correct?", + "answer": "No. Twist boundaries are formed by crossed screw dislocations of the same sign.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的正确性（'Small-angle grain boundaries are all formed by edge dislocations arranged into walls'），答案直接给出了该陈述是错误的（No）并提供了正确的解释。这符合判断题的特征，即判断陈述的对错并简要说明原因。 | 知识层次: 题目考查对晶界类型和位错排列的基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。题目考察学生对小角度晶界形成机制的理解，需要区分边缘位错和螺旋位错在晶界形成中的作用。虽然涉及基础概念记忆，但需要将定义和分类知识应用到具体情境中进行判断，比单纯的正误判断稍复杂，但不需要多概念比较分析。" + }, + { + "idx": 2064, + "question": "Point out the errors in the following concepts and correct them: (6) In liquid metal, any embryo that emerges with a radius smaller than the critical nucleus radius cannot nucleate, but as long as there is sufficient energy fluctuation to provide the nucleation work, nucleation is still possible.", + "answer": "Nucleation cannot occur, even if there is sufficient energy fluctuation to provide it, nucleation still cannot occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出概念中的错误并纠正，类似于判断陈述的对错并给出正确解释 | 知识层次: 题目考查对成核基本概念的记忆和理解，特别是临界核半径和能量波动在成核过程中的作用。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。题目要求考生理解临界核半径的概念以及成核的基本原理，并能够判断在能量波动足够的情况下，半径小于临界核半径的胚团是否能够成核。虽然涉及基础概念的记忆，但需要一定的理解深度来判断陈述的正确性，因此属于中等难度。" + }, + { + "idx": 2068, + "question": "Point out the errors in the following concepts and correct them: (10) From the calculation formula of heterogeneous nucleation work A_hetero = A_g(2-3cosθ+cos³θ), it can be seen that when the wetting angle θ=0°, the nucleation work for heterogeneous nucleation is the largest.", + "answer": "The nucleation work for heterogeneous nucleation is the smallest.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断给定的概念陈述是否正确，并指出错误和纠正，这符合判断题的特征。答案是对原陈述的判断和修正，而不是选择、计算或详细解释。 | 知识层次: 题目考查对异质形核功公式的理解和记忆，属于基础概念的判断和纠正，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。题目要求考生理解异质成核功的计算公式及其物理意义，特别是润湿角θ=0°时的特殊情况。虽然涉及公式记忆，但主要考察的是对公式物理意义的理解，而非复杂的推导或分析。因此属于中等难度，需要考生具备一定的概念理解能力。" + }, + { + "idx": 2071, + "question": "Point out the errors in the following concepts and correct them: (13) When studying the process of refining grains in a certain metal, the main focus is to find nucleating agents with low melting points and lattice constants similar to those of the metal, as their nucleation catalytic efficiency is the highest.", + "answer": "The main focus is to find those with high melting points, and.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出并纠正错误概念，这类似于判断题中判断陈述的对错并给出正确解释。答案部分直接指出了原陈述中的错误并提供了正确的表述，符合判断题的特征。 | 知识层次: 题目考查对晶粒细化过程中形核剂选择的基本概念的理解和记忆，属于基础概念范畴。 | 难度: 在选择题型中，这道题目属于中等难度。虽然考察的是基础概念记忆（晶粒细化过程中的形核剂选择标准），但需要考生不仅记住正确概念（高熔点），还要能够识别并纠正题目中给出的错误概念（低熔点）。这比单纯的正误判断（等级1）要求更高，但不需要进行复杂概念分析（等级3）。" + }, + { + "idx": 2076, + "question": "Point out the errors in the following concepts and correct them: (16) The microstructure morphology of a saturated aqueous solution of ammonium chloride and pure metal at the end of crystallization is the same, with the former exhibiting dendritic crystals and the latter also exhibiting dendritic crystals.", + "answer": "The microstructure morphology at the end of crystallization is different; the former exhibits dendritic crystals (with water between the branches), while the latter exhibits individual (blocky) grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出并纠正概念中的错误，类似于判断陈述的对错并给出正确解释。答案形式是对原陈述的否定和修正，符合判断题的特征。 | 知识层次: 题目考查对结晶过程中微观结构形态的基础概念记忆和理解，涉及对饱和溶液和纯金属结晶形态差异的基本认识。 | 难度: 在选择题型中，该题目属于中等偏下难度。题目要求考生区分两种不同结晶过程的微观结构形态，需要理解饱和氯化铵水溶液和纯金属在结晶结束时的不同表现。虽然涉及基础概念记忆，但需要考生对结晶形态有清晰的理解，并能正确识别和纠正错误陈述。解题步骤相对简单，但需要准确的概念掌握。" + }, + { + "idx": 2080, + "question": "Point out the errors in the following concepts and correct them: (23) During metal crystallization, the dynamic undercooling required for crystal growth is sometimes greater than the critical undercooling required for nucleation.", + "answer": "The dynamic undercooling is smaller than the critical undercooling required for nucleation.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求指出并纠正错误概念，答案直接给出了正确的陈述，类似于判断陈述的对错并给出正确版本 | 知识层次: 题目考查金属结晶过程中动态过冷度和临界过冷度的基本概念记忆和理解，属于基础概念层面的知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目要求考生理解金属结晶过程中动态过冷和临界过冷的相对大小关系，并判断原陈述的错误之处。这需要考生掌握基础概念并能进行简单的比较分析，但不需要复杂的推理或多概念整合，因此属于中等难度。" + }, + { + "idx": 2106, + "question": "Point out the error in the following concept and correct it: In the directional solidification process of a solid solution alloy rod, the faster the liquid-solid interface advances, the more severe the macrosegregation in the rod.", + "answer": "the less severe the macrosegregation in the rod.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求指出并纠正一个概念错误，类似于判断陈述的对错并给出正确表述。答案形式是直接纠正错误陈述，不需要计算或详细论述。 | 知识层次: 题目涉及对定向凝固过程中宏观偏析现象的理解和应用，需要将凝固速率与偏析程度的关系进行综合分析，属于中等应用层次的知识点。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅要理解定向凝固过程的基本原理，还需要掌握宏观偏析的形成机制及其与凝固速率的关系。这需要考生能够综合分析多个概念（如溶质分配、扩散速率、界面稳定性等），并正确判断因果关系。虽然题目给出了正确选项，但判断过程涉及中等应用层次的知识关联和综合分析能力，比单纯的概念识别或单步计算更为复杂。" }, { "idx": 2108, @@ -691,9 +18223,441 @@ "question_type_name": "判断题", "knowledge_level": "basic_concepts", "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求指出错误概念并纠正，类似于判断陈述的对错并给出正确陈述。答案形式是直接给出正确陈述，符合判断题的特征。 | 知识层次: 题目考查对固溶体晶粒中枝晶偏析和单相概念的基本理解，属于基础概念的记忆和判断。 | 难度: 该题目属于基础概念正误判断，仅需识别并纠正一个明确的错误概念（\"整个晶粒不是单相\"），正确选项直接给出了标准定义（\"整个晶粒是单相\"）。题目不涉及概念关系的分析或复杂推理，完全依赖对\"固溶体晶粒\"和\"枝晶偏析\"这两个基础定义的记忆性判断，符合等级1对知识点掌握深度和解题步骤简单性的要求。" + }, + { + "idx": 2110, + "question": "Point out the incorrect concept and correct it: Using circulating water to cool the metal mold is beneficial for obtaining a columnar crystal zone to improve the compactness of the casting.", + "answer": "It is not beneficial for obtaining a columnar crystal zone.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个概念的正确性（指出错误概念并纠正），答案直接给出了判断结果（不正确），这符合判断题的特征。 | 知识层次: 题目考查对金属铸造过程中冷却方式对晶体结构影响的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中属于基本概念正误判断，仅需识别并纠正一个简单的错误概念，不需要深入理解或分析多个概念。" + }, + { + "idx": 2117, + "question": "Point out the errors in the following concepts and correct them: All equilibrium crystallization processes of carbon steel undergo eutectoid transformation but no eutectic transformation; conversely, cast iron only undergoes eutectic transformation but no eutectoid transformation.", + "answer": "Conversely, cast iron undergoes both eutectic transformation and eutectoid transformation.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", "difficulty": 2, "final_level": "Level_2", - "reasoning": "题型: 题目要求判断一个概念的正确性并纠正错误，属于判断对错并改正的题型。答案直接给出了正确的陈述，符合判断题的特征。 | 知识层次: 题目考查对固溶体晶粒中枝晶偏析和单相概念的基本理解，属于基础概念的记忆和判断。 | 难度: 在判断题题型中，该题目属于概念理解的对错判断难度等级。题目要求考生不仅能够识别出错误的概念陈述，还需要进行纠正，这比单纯判断正误（等级1）要求更高的概念理解深度。但题目并未涉及多个概念的交叉或复杂逻辑推理（等级3），因此属于中等难度。" + "reasoning": "题型: 题目要求判断陈述的对错并指出错误概念，答案是对错误陈述的纠正，符合判断题的特征 | 知识层次: 题目考查对碳钢和铸铁相变过程的基本概念记忆和理解，需要识别并纠正关于共晶和共析转变的错误陈述，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目要求考生理解并区分碳钢和铸铁在平衡结晶过程中的相变行为（共析转变和共晶转变），并识别出原陈述中的错误。虽然涉及两个材料系统的相变概念，但只需要对基本定义和分类有清晰记忆即可做出正确判断，不需要复杂的分析或推理过程。" + }, + { + "idx": 2135, + "question": "When diffusion occurs via the vacancy mechanism, each atomic jump corresponds to a reverse jump of the vacancy without creating a new vacancy, yet the diffusion activation energy includes the vacancy formation energy. Is this statement correct? Please provide the correct explanation.", + "answer": "This statement is incorrect. The macroscopic diffusion flux in solids is not the result of directional jumps of individual atoms, nor is the diffusion activation energy the energy barrier that must be overcome for each jump during atomic migration. Atomic jumps in solids are random in nature, and the diffusion flux is the macroscopic manifestation of the statistical outcome of random jumps of diffusing particles (such as atoms or ions) in the solid. When diffusion in a crystal occurs via the vacancy mechanism, any atomic jump between two equilibrium positions must simultaneously satisfy two conditions: (1) The atom must possess energy higher than a certain critical value $\\Delta G_{\\mathrm{f}}$, i.e., the activation energy for atomic jumps, to overcome the resistance hindering the jump; (2) A vacancy must exist at the adjacent equilibrium position of the atom. According to statistical thermodynamics theory, at a given temperature $T$, the probability $P_{\\textrm{f}}$ that any atom in the crystal has energy higher than $\\Delta G_{\\mathrm{f}}$, i.e., the atomic percentage of atoms with energy exceeding $\\Delta G_{\\mathrm{f}}$, is $$P_{\\mathrm{f}}=\\exp\\Bigl(\\frac{-\\Delta G_{\\mathrm{f}}}{k T}\\Bigr)$$ The equilibrium vacancy concentration $c_{\\mathrm{v}}$ in the crystal, i.e., the probability $P_{\\mathrm{~v~}}$ of a vacancy appearing at any atomic equilibrium position, is $$P_{\\mathrm{v}}=\\exp\\Bigl(\\frac{-\\Delta G_{\\mathrm{v}}}{k T}\\Bigr)$$ Clearly, the probability $P$ that an atom in the crystal undergoes a jump at any given moment is $$P=P_{\\mathrm{f}}P_{\\mathrm{v}}=\\exp\\Bigl(-\\frac{\\Delta G_{\\mathrm{f}}+\\Delta G_{\\mathrm{v}}}{k T}\\Bigr)=\\exp\\Bigl(-\\frac{Q}{R T}\\Bigr)$$ Here, $P$ also equals the atomic percentage of atoms undergoing jumps at that moment. The term $Q=\\Delta G_{\\mathrm{f}}+\\Delta G_{\\mathrm{v}}$ represents the diffusion activation energy for the vacancy diffusion mechanism.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目首先要求判断一个陈述是否正确（\"Is this statement correct?\"），然后需要提供正确的解释。这符合判断题的特征，即先判断对错，再解释原因。答案中明确指出了陈述的错误，并提供了详细的解释来支持判断。 | 知识层次: 题目不仅要求判断陈述的对错，还需要深入理解扩散激活能的组成和空位扩散机制的统计热力学基础。解答过程涉及多个概念的关联（如空位形成能、跳跃激活能、扩散通量的统计本质）和综合分析（概率计算、统计热力学理论的应用），思维过程较为深入和复杂。 | 难度: 在选择题型内，该题目属于最高难度等级。原因如下：" + }, + { + "idx": 2147, + "question": "Point out the error in the following concept: (4) In an interstitial solid solution, the higher the solute concentration, the more interstitial sites are occupied by the solute, leaving fewer vacant interstitial sites for diffusion, i.e., the value of $_z$ decreases, leading to a reduction in the diffusion coefficient.", + "answer": "In fact, this scenario is impossible. The solubility of solute atoms in an interstitial solid solution is very limited. Even in a supersaturated state, the number of solute atoms is several orders of magnitude smaller than the total number of interstitial sites in the crystal. Therefore, the interstitial sites around the solute atoms can be considered entirely vacant. That is, for a given crystal structure, 𝓏 is a constant.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个概念陈述是否正确，并指出其中的错误。答案通过解释说明了原陈述的错误之处，符合判断题的特征。 | 知识层次: 题目需要理解间隙固溶体的基本概念，并能够分析间隙位置占据与扩散系数之间的关系。虽然涉及基础概念，但需要综合分析间隙固溶体的溶解度限制和扩散机制，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析多个概念并进行推理判断。题目要求考生不仅理解间隙固溶体的基本概念，还需要掌握溶质原子在间隙固溶体中的溶解度限制，以及扩散系数的相关影响因素。此外，还需要判断题目中描述的情景是否可能，并给出正确的解释。这涉及到多步的概念关联和综合分析，因此难度较高。" + }, + { + "idx": 2225, + "question": "Determine whether the following statement is correct. (1) Appropriate recrystallization annealing can refine the grain size of metal castings.", + "answer": "Incorrect. Only for metals that have undergone cold deformation (with significant deformation) can the grain size be refined through appropriate recrystallization annealing.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案直接给出了对错判断并解释了原因，符合判断题的特征 | 知识层次: 题目不仅需要理解再结晶退火的基本概念，还需要分析其在特定条件下的应用（冷变形金属），涉及概念关联和综合分析。 | 难度: 在选择题中属于较高难度，需要综合分析金属铸造和冷变形两个不同条件下的再结晶退火效果。题目不仅要求判断陈述的正确性，还需要理解再结晶退火对晶粒细化的适用条件（仅适用于经过显著冷变形的金属），这涉及多个概念的关联和综合判断。" + }, + { + "idx": 2227, + "question": "Determine whether the following view is correct. (7) Recovery, recrystallization, and grain growth are all processes of nucleation and growth, and their driving force is the stored energy.", + "answer": "Incorrect. Only the recrystallization process is a nucleation and growth process, and its driving force is the stored energy.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断给定的观点是否正确，答案直接给出了对错判断并简要解释了原因，符合判断题的特征。 | 知识层次: 题目涉及恢复、再结晶和晶粒长大三个过程的区分，需要理解它们的驱动机制和是否为形核长大过程。这需要将多个概念关联起来进行分析，而不仅仅是记忆单个概念的定义。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生综合分析恢复、再结晶和晶粒长大三个过程的本质及其驱动力，并判断给定观点的正确性。需要考生掌握这些过程的区别（如哪些属于形核长大机制）以及各自驱动力的来源（如储存能的作用范围）。这涉及多概念关联和综合分析能力，超出了简单记忆或单一概念应用的层次，符合等级4中\"综合分析结果判断\"的标准。" + }, + { + "idx": 2228, + "question": "Determine whether the following statement is correct. (3) Polygonization causes the scattered dislocations to gather together to form dislocation walls, and the superposition of dislocation stress fields increases the lattice distortion.", + "answer": "Incorrect. During the polygonization process, the vacancy concentration decreases and dislocations recombine, causing dislocations of opposite signs to cancel each other out, reducing dislocation density and thereby alleviating lattice distortion.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案明确指出了陈述的错误并解释了原因，符合判断题的特征。 | 知识层次: 题目涉及对多边形化过程中位错行为的理解，需要将位错重组、应力场叠加和晶格畸变等概念进行关联分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析多边形化过程中位错重组和应力场变化的复杂关系。题目不仅要求理解位错运动的基本概念，还需要掌握位错相互作用对晶格畸变的影响机制。正确选项涉及多步推理过程（位错重组→符号相反位错抵消→位错密度降低→晶格畸变减轻），且需要将多个材料科学概念（多边形化、位错应力场、晶格畸变）关联起来进行判断。这超出了简单记忆或单一概念应用的层次，属于需要综合分析能力的中等应用题型。" + }, + { + "idx": 2229, + "question": "Determine whether the following statement is correct. (4) For any metal that undergoes cold deformation followed by recrystallization annealing, the grain size can be refined.", + "answer": "Incorrect. If the metal is deformed at the critical deformation degree, the grain size will coarsen after recrystallization annealing.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个陈述的正确性（\"Determine whether the following statement is correct\"），答案直接给出了该陈述是错误的（\"Incorrect\"）并解释了原因。这符合判断题的特征，即判断给定陈述的对错。 | 知识层次: 题目不仅需要理解冷变形和再结晶退火的基本概念，还需要分析临界变形度对晶粒尺寸的影响，涉及多步概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解冷变形和再结晶退火的基本概念，还需要掌握临界变形程度对晶粒尺寸的影响这一特定知识点。解题时需要综合分析变形程度与再结晶后晶粒尺寸的关系，并判断题目陈述的正确性。这种综合分析结果判断的能力要求高于简单的概念记忆或单一知识点应用，因此属于等级4难度。" + }, + { + "idx": 2231, + "question": "Determine whether the following view is correct. (5) The recrystallization temperature of a certain aluminum alloy is 320°C, indicating that this alloy can only undergo recovery below 320°C, while recrystallization must occur above 320°C.", + "answer": "Incorrect. Recrystallization is not a phase transformation. Therefore, it can occur over a wide temperature range.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断给定的观点是否正确，答案直接给出了对错判断并简要解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶温度及其相关基础概念的记忆和理解，属于材料科学中的基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（如recrystallization的定义和温度范围），但需要考生不仅记住定义，还要理解recrystallization不是一个相变过程，并且能够在不同温度下发生。这要求考生对概念有一定的理解深度，而不仅仅是简单的记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 2232, + "question": "Determine whether the following statement is correct. (2) Dynamic recrystallization only occurs under hot deformation conditions, therefore, metals deformed at room temperature will not undergo dynamic recrystallization.", + "answer": "Incorrect. The recrystallization temperature of some metals is below room temperature, so deformation at room temperature is also considered hot deformation, and dynamic recrystallization can occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的正确性，答案明确指出了原陈述的错误并给出了解释，符合判断题的特征。 | 知识层次: 题目不仅需要理解动态再结晶的基本概念，还需要结合不同金属的再结晶温度进行综合分析，判断在室温条件下是否可能发生动态再结晶。这涉及到对概念的应用和一定程度的推理分析。 | 难度: 在选择题中属于较高难度，需要综合分析动态再结晶的条件和金属的再结晶温度概念，并理解室温变形对某些金属而言可能属于热变形范畴。题目要求考生不仅掌握基础概念，还需要进行多步逻辑推理和特殊情况判断。" + }, + { + "idx": 2233, + "question": "Determine whether the following statement is correct. (6) The melting point of 20# steel is lower than that of pure iron, so its recrystallization temperature is also lower than that of pure iron.", + "answer": "Incorrect. The presence of trace solute atoms (wC=0.002 in 20# steel) hinders the recrystallization of the metal, thereby increasing its recrystallization temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案明确指出\"Incorrect\"并给出解释，符合判断题的特征 | 知识层次: 题目需要理解合金元素对金属性能的影响，并能够将溶质原子对再结晶温度的阻碍作用与熔点变化的影响进行综合分析。这涉及到多个概念的关联和一定程度的推理分析，超出了简单记忆或直接套用的层次。 | 难度: 在选择题中属于较高难度，需要综合分析多个概念（熔点、再结晶温度、溶质原子影响）并进行逻辑推理判断正误。题目不仅考察基础概念理解，还要求考生掌握溶质原子对金属再结晶行为的复杂影响机制，属于中等应用层次的多步骤综合分析题。" + }, + { + "idx": 2234, + "question": "Determine whether the following view is correct. (8) The greater the deformation of the metal, the more likely the recrystallization mechanism of grain boundary bulging nucleation will occur.", + "answer": "Incorrect. When the cold deformation degree of the metal is small, uneven deformation is more likely to occur in adjacent grains, that is, the dislocation density differs, making the recrystallization mechanism of grain boundary bulging nucleation more likely to occur.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断一个陈述是否正确（Determine whether the following view is correct），并且答案直接给出了该陈述是错误的（Incorrect）以及解释原因。这符合判断题的特征，即对给定的陈述进行对错判断。 | 知识层次: 题目涉及金属变形与再结晶机制的关联分析，需要理解变形程度对晶界凸起形核机制的影响，并进行综合判断，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析金属变形程度与再结晶机制之间的关系。题目不仅要求理解晶界凸起成核机制的概念，还需要掌握变形程度对位错密度分布的影响，并能将这两个概念关联起来进行判断。正确选项的解释涉及多步推理过程，包括理解小变形时的不均匀变形特性及其对位错密度差异的影响，这超出了简单概念记忆的范畴，需要进行较深入的综合分析。" + }, + { + "idx": 2235, + "question": "Determine whether the following view is correct. (9) Normal grain growth is the consumption of small grains by large grains, while abnormal growth is the consumption of large grains by small grains.", + "answer": "Incorrect. Normal grain growth is uniform growth driven by interface curvature, whereas abnormal growth is non-uniform growth where large grains consume small grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个陈述是否正确，答案明确指出了陈述的错误并给出了正确解释，符合判断题的特征。 | 知识层次: 题目考查对正常晶粒生长和异常晶粒生长这两个基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断，仅需记忆并区分正常晶粒生长和异常晶粒生长的基本定义即可作答。在选择题型中属于最简单的难度等级，不涉及复杂概念分析或比较。" + }, + { + "idx": 2236, + "question": "Determine whether the following statement is correct. (10) The second-phase particles in an alloy generally can hinder recrystallization but promote grain growth.", + "answer": "Incorrect. The second-phase particles in an alloy generally can hinder recrystallization and also impede grain growth.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了正确与否的判断并解释了原因 | 知识层次: 题目考查对第二相粒子在合金中作用的理解，需要将多个概念（再结晶、晶粒长大）关联起来进行分析，并判断其对错。这超出了单纯记忆基础概念的层次，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合分析第二相粒子对再结晶和晶粒长大的影响，并理解两者之间的相互作用关系。题目要求判断陈述的正确性，并选择正确的解释，涉及多步概念关联和综合分析能力。" + }, + { + "idx": 2237, + "question": "Determine whether the following statement is correct. (13) Recrystallization is a nucleation-growth process, so it is also a phase transformation process.", + "answer": "Incorrect. Although recrystallization is a nucleation-growth process, the crystal lattice type does not change, so it is not a phase transformation process.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的正确性，答案明确指出了陈述的错误并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶过程和相变过程这两个基础概念的理解和区分，属于基础概念的记忆和辨析范畴 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆（再结晶和相变），但需要考生理解两个关键概念之间的关系（再结晶是形核-生长过程但不改变晶格类型）。这超出了简单的定义记忆（等级1），但尚未达到需要分析复杂概念陈述的程度（等级3）。考生需要正确区分形核-生长过程和相变过程的本质区别，这属于概念理解层面的对错判断。" + }, + { + "idx": 2238, + "question": "Determine whether the following statement is correct. (11) Recrystallization texture is the deformation texture retained during the recrystallization process.", + "answer": "Incorrect. Recrystallization texture is the texture formed during the recrystallization (primary, secondary) process of cold-deformed metals. It is formed on the basis of deformation texture, with two scenarios: one is retaining the original deformation texture, and the other is the disappearance of the original deformation texture, replaced by a new recrystallization texture.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目明确要求判断陈述的正确性（Determine whether the following statement is correct），且答案直接给出了该陈述是错误的（Incorrect）并解释了原因，符合判断题的特征。 | 知识层次: 题目考查对再结晶织构这一基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目要求判断关于再结晶织构的陈述是否正确，需要考生理解再结晶织构的定义及其与变形织构的关系。虽然涉及基础概念记忆，但需要一定的概念理解和应用能力，属于中等偏下的难度。" + }, + { + "idx": 2242, + "question": "Determine whether the following view is correct. (12) When the deformation is large and relatively uniform, the grains after recrystallization tend to undergo normal growth, otherwise, abnormal growth is more likely to occur.", + "answer": "Incorrect. Normal grain growth is the process of uniform grain growth that occurs during continued heating or holding after recrystallization is completed; whereas abnormal grain growth is the process of non-uniform grain growth that occurs under certain conditions (i.e., stable grains after recrystallization, the presence of a few grains favorable for growth, and high-temperature heating) following normal grain growth.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断给定的观点是否正确（\"Determine whether the following view is correct\"），答案明确给出了\"incorrect\"的判断并解释了原因，符合判断题的特征。 | 知识层次: 题目涉及对再结晶后晶粒生长行为的判断，需要理解正常晶粒生长和异常晶粒生长的条件及其区别，属于对多个概念的综合应用和分析。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生理解再结晶后晶粒生长的基本概念（正常生长和异常生长），还需要综合分析变形条件与生长类型之间的关系。正确选项需要考生能够区分两种生长模式的发生条件和时序关系（正常生长在先，异常生长在后），并识别题目中关于变形条件描述的误导性。这需要将多个材料科学概念（再结晶、晶粒生长、变形条件）关联起来进行综合判断，属于中等应用层次的知识运用。" + }, + { + "idx": 2357, + "question": "Is the glass transition temperature of ordinary window glass above or below room temperature?", + "answer": "The glass transition temperature of ordinary window glass should be above room temperature. If it were below room temperature, the glass would remain in a liquid state at room temperature, albeit with high viscosity and some fluidity, meaning the atoms would still be delocalized. Consequently, it could not maintain a fixed shape at room temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断\"普通窗玻璃的玻璃化转变温度是否高于室温\"这一陈述的对错，答案给出了明确的判断和解释，符合判断题的特征。 | 知识层次: 题目考查对玻璃转变温度这一基本概念的记忆和理解，以及其在室温下的状态判断，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断普通窗玻璃的玻璃化转变温度是否高于室温，属于对基础概念的记忆性知识。正确选项直接给出了结论，不需要复杂的分析或推理过程，因此难度等级为1。" + }, + { + "idx": 2639, + "question": "Determine whether [-110] lies on the (111) plane", + "answer": "Using the zone law: h u + k v + l w = 0, here 1×(-1) + 1×1 + 1×0 = 0, thus [-110] lies on the (111) plane.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述（[-110]是否在(111)平面上）的对错，答案通过应用特定规则（zone law）进行验证，最终给出明确的判断结果。 | 知识层次: 题目需要应用基本的晶体学公式（zone law）进行简单计算，属于直接套用公式的简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（zone law）并进行简单计算即可得出正确结论。解题步骤明确且不复杂，无需深入分析或多步骤推理，符合等级2的简单应用结果判断标准。" + }, + { + "idx": 2721, + "question": "If the positive direction of a dislocation line is defined as the original opposite direction, does the type and nature of the dislocation change?", + "answer": "The type and nature of this dislocation do not change.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（dislocation的类型和性质是否改变），答案直接给出了对错判断（不改变） | 知识层次: 题目考查对位错线方向和位错类型及性质的基本概念的理解，属于基础概念记忆范畴。 | 难度: 该题目属于基本概念正误判断，仅需记忆和理解位错线方向定义对位错类型和性质的影响即可作答，无需复杂分析或推理过程。在选择题型中属于最基础的难度等级。" + }, + { + "idx": 3005, + "question": "The mechanical properties of polymers are mainly determined by their degree of polymerization, crystallinity, and intermolecular forces.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物机械性能决定因素的基础概念记忆，仅需识别三个关键因素（聚合度、结晶度和分子间作用力）的正确性，不涉及应用或分析过程。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆聚合物机械性能的决定因素（聚合度、结晶度和分子间作用力）即可做出正确判断，无需深入理解或分析。" + }, + { + "idx": 3006, + "question": "Linear polymers with high molecular weight exhibit glassy (or crystalline) state, high elastic state, and viscous flow state. Three-dimensional polymers with high crosslinking density do not possess high elasticity or viscous flow state.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对聚合物状态和交联密度影响的基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆线性聚合物和三维聚合物的基本状态特性即可做出正确选择，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3007, + "question": "ABS plastic is an engineering material with excellent comprehensive properties.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（ABS plastic is an engineering material with excellent comprehensive properties），并要求判断其正确性（答案：√），符合判断题的特征。 | 知识层次: 题目考查对ABS塑料基本特性的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆ABS塑料的基本定义和特性即可做出正确选择，无需深入理解或分析复杂概念。" + }, + { + "idx": 3038, + "question": "The structure of glass is an irregular network formed by silicon-oxygen tetrahedra in space.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（玻璃的结构是由硅氧四面体在空间中形成的无规则网络），并要求判断其正确性（答案用√表示正确），这符合判断题的特征。 | 知识层次: 题目考查对玻璃结构这一基础概念的记忆和理解，涉及硅氧四面体在空间中的不规则网络结构这一基本原理。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求判断关于玻璃结构的描述是否正确，涉及的是基础概念的记忆，无需深入理解或分析。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3043, + "question": "Oxide ceramics have a close-packed structure and exhibit high melting points and chemical stability due to strong ionic bonds.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对氧化物陶瓷基本特性的记忆和理解，包括其紧密堆积结构、高熔点和化学稳定性等基础概念，不涉及复杂的应用或分析。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆氧化物陶瓷的基本特性（如紧密堆积结构、高熔点、化学稳定性及强离子键）即可做出正确判断，无需深入理解或分析多个概念。" + }, + { + "idx": 3045, + "question": "Ceramic materials can be used as high-temperature materials and also as wear-resistant materials.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对陶瓷材料基本应用领域的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念正误判断题，仅需记忆陶瓷材料的基本应用领域（高温材料和耐磨材料），无需深入理解或分析多个概念。在选择题型中，这是最简单的难度等级，仅需识别陈述是否符合基础定义。" + }, + { + "idx": 3047, + "question": "Ceramic materials can be used as cutting tool materials, and can also be used as thermal insulation materials.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Ceramic materials can be used as cutting tool materials, and can also be used as thermal insulation materials），并要求判断其正确性（答案：√），这符合判断题的特征。 | 知识层次: 题目考查对陶瓷材料基本用途的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆陶瓷材料的常见用途即可作答，无需深入理解或分析多个概念。题目直接陈述了陶瓷材料的两种应用，正确选项明确，属于最基础难度的记忆性知识题目。" + }, + { + "idx": 3049, + "question": "Ceramic materials have low tensile strength but high compressive strength.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（陶瓷材料具有低抗拉强度但高抗压强度），并要求判断其正确性（答案用√表示正确），这符合判断题的特征。 | 知识层次: 题目考查对陶瓷材料基本力学性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆陶瓷材料的基本力学特性（低抗拉强度、高抗压强度）即可作答。在选择题型中属于最简单的难度等级，不需要理解或分析复杂概念。" + }, + { + "idx": 3082, + "question": "In fiber-reinforced composites, the smaller the fiber diameter, the better the fiber reinforcement effect.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对纤维增强复合材料中纤维直径与增强效果关系的基本概念的理解和记忆，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆纤维增强复合材料中纤维直径与增强效果的基本关系即可作答，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3086, + "question": "In order to achieve high strength in composite materials, the elastic modulus of the fibers must be very high.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查对复合材料中纤维弹性模量与强度关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅考察对复合材料强度与纤维弹性模量关系这一基础概念的简单记忆，无需深入理解或分析。正确选项直接对应教材中的基本原理陈述，属于最基础的选择题难度等级。" + }, + { + "idx": 3110, + "question": "Hydrogen storage alloys are alloys that form hydrogen-containing solid solutions by absorbing hydrogen, and under certain conditions, these alloys decompose to release hydrogen", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，并要求判断其正确性（答案以√表示正确），符合判断题的特征 | 知识层次: 题目考查对氢存储合金基本概念的记忆和理解，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于储氢合金定义的陈述是否正确。在选择题型中，这种直接考察定义记忆的题目属于最简单的难度等级，不需要复杂的概念理解或分析过程。" + }, + { + "idx": 3200, + "question": "Does the ingot structure necessarily have three crystal zones?", + "answer": "It should be pointed out that not all ingot structures have three crystal zones. Due to different solidification conditions, an ingot may only have one type of crystal zone or only two types of crystal zones.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，即“铸锭结构是否必然有三个晶区”，而答案明确指出了该陈述的错误性，并解释了原因。这符合判断题的特征。 | 知识层次: 题目考查对铸锭结构基本概念的记忆和理解，涉及铸锭晶体区的分类和形成条件，属于基础概念层次。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对铸锭结构晶体区基本概念的理解，需要判断\"是否所有铸锭结构都必然具有三个晶体区\"这一陈述的正确性。虽然涉及基础概念记忆，但需要考生理解铸锭结构形成原理和不同凝固条件的影响，属于对概念理解的简单应用判断，比单纯记忆性知识（等级1）略高，但尚未达到需要分析复杂概念陈述的等级3难度。" + }, + { + "idx": 3231, + "question": "In the actual crystallization process of metals, nucleation occurs in two ways: homogeneous nucleation and heterogeneous nucleation. Since homogeneous nucleation requires higher nucleation energy, heterogeneous nucleation is predominantly observed.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（√表示正确），符合判断题的特征 | 知识层次: 题目考查金属结晶过程中均质形核和非均质形核的基本概念及其能量差异的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于金属结晶过程中均匀成核和非均匀成核的基本陈述是否正确。题目直接给出了明确的正误判断选项（√），无需进行复杂的概念分析或比较。在选择题型中，这类直接考察定义和分类记忆的题目属于最简单的难度等级。" + }, + { + "idx": 3232, + "question": "Some solid solutions with certain atomic ratios are disordered solid solutions at high temperatures, and may transform into ordered solid solutions when cooled below a certain critical temperature. Once the ordering transition occurs, it can lead to abrupt changes in certain properties.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，并要求判断其正确性（答案用√表示正确），符合判断题的特征。 | 知识层次: 题目考查对固溶体有序-无序转变这一基本概念的记忆和理解，属于材料科学中的基础知识点，不需要复杂的分析或计算。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅要求考生识别关于固溶体有序-无序转变的基本定义和现象描述是否正确，不需要进行复杂的概念分析或比较。这种题型主要测试对基础概念的记忆能力，属于选择题型中最基础的难度等级。" + }, + { + "idx": 3234, + "question": "Using the three-axis system to index the crystallographic plane indices and direction indices of a hexagonal close-packed structure, the resulting indices for the same family of planes or directions are different.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（√表示正确），符合判断题的特征。 | 知识层次: 题目考查对六方密堆积结构晶面指数和方向指数标定方法的基础概念记忆，属于对基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度。虽然涉及六方密堆积结构的晶面指数和方向指数的概念，但题目仅要求判断关于不同坐标系下指数差异的基本陈述是否正确，不需要复杂的分析或比较多个概念。因此属于中等难度。" + }, + { + "idx": 3235, + "question": "During the crystallization of liquid metal, the degree of undercooling required to form an embryo equal to the critical nucleus radius in the undercooled liquid is called the critical undercooling.", + "answer": "√", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案用√表示正确），这符合判断题的特征 | 知识层次: 题目考查对临界过冷度这一基本概念的记忆和理解，属于定义性知识，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆题型，仅需判断\"临界过冷度\"的定义是否正确。题目直接给出定义陈述，不需要任何推导或分析，属于选择题型中最简单的正误判断题。在选择题型内，这类仅需记忆定义即可作答的题目属于最低难度等级。" }, { "idx": 3297, @@ -705,7 +18669,1447 @@ "knowledge_level_name": "中等应用", "difficulty": 4, "final_level": "Level_4", - "reasoning": "题型: 题目要求判断一个陈述的对错，并解释原因。答案明确指出了陈述的错误之处，并提供了详细的解释。 | 知识层次: 题目不仅需要理解马氏体硬度和强度的基本概念，还需要分析碳含量、马氏体形态和板条尺寸对性能的影响，涉及多个概念的关联和综合分析。 | 难度: 在判断题题型中，该题目属于综合分析结果判断难度。题目不仅要求判断陈述的对错，还需要解释原因，涉及对马氏体强度和硬度影响因素的深入理解（碳含量、马氏体形态和板条尺寸等）。这需要将多个材料科学概念关联起来进行综合分析，比单纯判断正误的题目更为复杂。" + "reasoning": "题型: 题目要求判断一个陈述的对错，并解释原因。答案明确指出了陈述的部分正确性和错误性，并提供了详细的解释。 | 知识层次: 题目不仅需要理解马氏体硬度和强度的基本概念，还需要分析碳含量、马氏体形态和板条尺寸对性能的影响，涉及多个概念的关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。题目不仅要求考生掌握马氏体硬度和强度的基本概念，还需要理解碳含量对硬度的直接影响，以及马氏体形态和板条尺寸对强度的额外影响。这需要综合分析多个因素，并判断原始陈述的正确性。解题过程涉及多步概念关联和结果判断，超出了简单记忆或单一概念应用的范畴，符合等级4的综合分析要求。" + }, + { + "idx": 3302, + "question": "Is the statement that the plasticity and toughness of martensite mainly depend on its substructure correct? Why?", + "answer": "Yes. The plasticity and toughness of martensite mainly depend on its substructure.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求判断一个陈述是否正确（\"Is the statement...correct?\"），并且答案直接给出了对陈述的判断（\"Yes\"），这符合判断题的特征。虽然题目还要求解释原因（\"Why?\"），但主要考察的是对陈述真伪的判断能力。 | 知识层次: 题目不仅需要判断陈述的对错，还需要解释为什么，涉及对马氏体亚结构与其塑性和韧性关系的深入理解和分析。这需要综合运用材料科学知识，进行推理和机理解释，属于较高层次的认知能力要求。 | 难度: 在选择题型中，该题目属于高难度等级。题目要求考生不仅理解马氏体的塑性和韧性与亚结构的关系，还需要进行深度分析和机理解释。正确选项涉及复杂的材料科学知识，需要综合运用多个概念并进行推理分析，才能得出正确结论。这种题目在选择题型中属于较高层次的认知要求，因此难度等级为5。" + }, + { + "idx": 3342, + "question": "If a $\\phi5\\$ hot-rolled steel specimen is heated to 650℃, held isothermally for 15s, and then quenched in water, can the isothermal transformation curve be used to analyze the final microstructure obtained?", + "answer": "No. The isothermal transformation curve describes the transformation of undercooled austenite. The hot-rolled eutectoid steel heated to 650℃ does not undergo austenitization.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（是否可以使用等温转变曲线分析最终获得的微观结构），答案直接给出了\"是/否\"的判断（No），并提供了简要解释。这符合判断题的特征。 | 知识层次: 题目考查对等温转变曲线基本概念的理解，即它仅适用于过冷奥氏体的转变，而不适用于未发生奥氏体化的情况。这属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等难度，需要理解等温转变曲线的基本概念及其应用条件，并判断题目描述的情况是否符合这些条件。虽然不涉及复杂的分析步骤，但需要对基础概念有一定的理解和应用能力。" + }, + { + "idx": 3486, + "question": "Can one prolonged tempering at 560°C replace three tempering processes at 560°C?", + "answer": "No. Because a single tempering is difficult to completely eliminate retained austenite, multiple tempering processes are required to reduce the retained austenite to the minimum amount. Moreover, each subsequent tempering can eliminate the internal stress generated by the transformation of austenite into martensite during the previous tempering.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目是一个是非判断问题，要求判断“一次长时间回火是否可以替代三次回火”这一陈述的正确性。答案明确给出了“No”并解释了原因，符合判断题的特征。 | 知识层次: 题目涉及回火工艺对残余奥氏体消除的影响，需要理解多次回火的作用机理和残余奥氏体转变的复杂过程。解答不仅需要知道多次回火的必要性，还需要分析每次回火对内部应力和组织转变的影响，属于综合运用和推理分析的层次。 | 难度: 在选择题型中属于高难度，需要深入理解回火工艺的机理，包括残余奥氏体的消除、内应力的产生与消除等复杂过程。题目要求综合运用材料科学知识进行推理分析，判断单一长时间回火是否能替代多次回火的效果，涉及多个知识点的综合应用和机理解释。" + }, + { + "idx": 3491, + "question": "Can austenitic stainless steel be strengthened by heat treatment?", + "answer": "No. Because after quenching (solution treatment), austenitic stainless steel undergoes no phase transformation, and all second-phase particles dissolve into the austenite. As a result, its hardness and strength drop to the lowest level after quenching, so it cannot be strengthened by heat treatment.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Can austenitic stainless steel be strengthened by heat treatment?），而答案明确给出了判断结果（No）并提供了简要解释。这符合判断题的特征，即判断陈述的对错并提供简要说明。 | 知识层次: 题目考查对奥氏体不锈钢热处理强化原理的基础概念记忆和理解，无需复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于概念理解的对错判断难度等级。题目考察的是对奥氏体不锈钢热处理强化原理的理解，需要学生掌握奥氏体不锈钢在淬火后的相变行为和强化机制。虽然涉及专业概念，但只需判断一个基本原理的正确性，不需要进行复杂的概念比较或综合分析。" + }, + { + "idx": 3503, + "question": "Is Cr12MoV a stainless steel?", + "answer": "Cr12MoV is not a stainless steel, it is a cold work die steel. The w_Cr of stainless steel is ≥13%.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断\"Cr12MoV is a stainless steel\"这一陈述的对错，答案明确给出了判断结果和解释，符合判断题的特征。 | 知识层次: 题目考查对不锈钢定义和Cr12MoV钢种分类的基本概念记忆，仅需判断材料类型是否符合不锈钢的铬含量标准，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念正误判断，仅需记忆不锈钢的基本定义（铬含量≥13%）和Cr12MoV钢的分类即可作答。在选择题型中，这类直接考查定义记忆的题目属于最低难度等级。" + }, + { + "idx": 3552, + "question": "Someone said: 'A precipitation-hardening alloy can be softened by water quenching at an appropriate temperature.' Is this statement correct? Explain.", + "answer": "A precipitation-hardening alloy cannot be softened by water quenching at an appropriate temperature. The reason is that when heated to a high temperature, it forms a single solid solution structure. Rapid cooling results in a single solid solution, which, although not very hard at this stage, will subsequently undergo precipitation hardening. Therefore, a precipitation-hardening alloy can only be softened through an aging process.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断陈述的对错，并解释原因。答案中明确指出了陈述是错误的，并提供了详细的解释。 | 知识层次: 题目不仅需要理解沉淀硬化合金的基本概念，还需要分析水淬对其性能的影响，并解释为什么水淬不能软化合金，而是需要通过时效过程来实现。这涉及到多步概念关联和综合分析。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求判断一个关于沉淀硬化合金软化过程的陈述是否正确，这需要考生对沉淀硬化合金的热处理过程有深入的理解。其次，正确选项不仅需要判断陈述的正误，还需要解释原因，涉及多步概念关联和综合分析。具体来说，考生需要理解高温下形成单一固溶体结构、快速冷却后的状态以及后续沉淀硬化的过程，这些知识点需要较高的综合分析能力。因此，该题目在选择题型内属于等级4的难度。" + }, + { + "idx": 3610, + "question": "Which, if any, of these planes is close packed in BCC lithium?", + "answer": "there is no close-packed plane in bcc structures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目实际上是在判断\"BCC锂中是否存在密排面\"这一陈述的正确性，答案为明确的判断性陈述（不存在）。虽然以疑问句形式呈现，但本质是判断一个事实陈述的真伪。 | 知识层次: 题目考查对BCC晶体结构中密排面存在与否的基础概念记忆和理解，属于晶体学的基本知识点，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念记忆层次，仅需判断BCC结构中是否存在密排面这一基本事实。选择题型中只需识别正确选项，无需复杂推理或概念整合，属于最基础的正误判断难度等级。" + }, + { + "idx": 3774, + "question": "Does the cast iron expand or contract during solidification?", + "answer": "the cast iron contracts during solidification.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（cast iron在凝固过程中是膨胀还是收缩），答案直接给出了对错判断（contracts during solidification） | 知识层次: 题目考查对铸铁凝固过程中体积变化这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，仅需判断铸铁在凝固过程中是膨胀还是收缩这一简单事实。在选择题型中，这属于最基本的概念正误判断，不需要复杂的理解或分析过程，因此属于等级1难度。" + }, + { + "idx": 3815, + "question": "Consider a Pb-70% Sn alloy. Determine if the alloy is hypoeutectic or hypereutectic.", + "answer": "hypereutectic", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断给定的合金是亚共晶还是过共晶，答案是一个明确的判断结果（hypereutectic），类似于判断题中对陈述对错的判断。 | 知识层次: 题目考查对合金成分分类（亚共晶或过共晶）的基本概念记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即判断Pb-70% Sn合金是亚共晶还是过共晶。这属于最基本的概念正误判断，无需复杂推理或分析，只需记住共晶点的定义和分类即可直接作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3857, + "question": "Is the steel hypoeutectoid or hypereutectoid?", + "answer": "the steel is hypoeutectoid.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断钢是亚共析钢还是过共析钢，属于对陈述事实的判断，答案形式为直接给出判断结果。 | 知识层次: 题目考查对钢的分类（亚共析钢或过共析钢）这一基础概念的记忆和理解，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即判断钢是亚共析钢还是过共析钢。这属于最基本的概念正误判断，无需复杂分析或推理，只需回忆相关定义即可作答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3888, + "question": "The nucleus of an atom contains electrons?", + "answer": "No, the nucleus of an atom does not contain electrons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案直接给出了判断结果（No）和解释。 | 知识层次: 题目考查原子核组成的基本概念记忆，属于最基础的定义性知识，仅需记忆即可回答。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆原子核的基本组成（质子和中子）即可判断正确选项。题目不涉及概念理解或复杂陈述，属于最基础的知识点考察。" + }, + { + "idx": 3889, + "question": "The nucleus of an atom contains neutrons?", + "answer": "Yes, the nucleus of an atom contains neutrons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（Yes/No），符合判断题的特征 | 知识层次: 题目考查原子核基本组成的记忆性知识，属于基础概念层次 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆原子核的基本组成即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 3890, + "question": "The nucleus of an atom contains protons?", + "answer": "Yes, the nucleus of an atom contains protons.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"The nucleus of an atom contains protons\"），答案直接给出了判断结果（\"Yes\"），符合判断题的特征。 | 知识层次: 题目考查原子核基本组成的记忆性知识，仅需基础概念认知能力 | 难度: 在选择题型中，该题目仅涉及基础概念的正误判断，即原子核是否包含质子这一基本事实。题目不需要任何复杂推理或概念间的比较分析，仅需记忆性知识即可正确回答。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 3927, + "question": "Is it possible to produce a polymer that is 100% crystalline? (a) True (b) False", + "answer": "False. It is not possible to produce a polymer that is 100% crystalline. The maximum crystallinity that can be obtained is about 95%, with the remaining material being amorphous.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目以判断陈述对错的形式提问，要求选择True或False作为答案，符合判断题的特征。 | 知识层次: 题目考查对聚合物结晶度的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接询问聚合物是否可以100%结晶，正确选项明确给出了基础定义和基本原理（聚合物最大结晶度约为95%）。这只需要学生对聚合物结晶度的基本概念有记忆性了解即可回答，无需深入理解或分析多个概念。因此属于选择题型中最基础的难度等级。" + }, + { + "idx": 3930, + "question": "In metals, there are significantly more vacancies than self-interstitials.(a) True(b) False", + "answer": "True. In metals, there are significantly more vacancies than self-interstitials; the reason for this is that the atom is significantly larger than the interstitial position in which it is situated, and, consequently significant lattice strains result.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附有简要解释。 | 知识层次: 题目考查金属中空位和自间隙原子数量的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆金属中空位和自间隙原子的相对数量关系即可作答，无需深入理解或分析。" + }, + { + "idx": 3969, + "question": "Reducing the grain size of metal improves toughness.(a) True(b) False", + "answer": "True. Reducing the grain size of a metal improves its toughness.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断结果 | 知识层次: 题目考查金属晶粒尺寸与韧性关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆金属晶粒尺寸与韧性关系的基础知识即可作答，无需深入理解或分析。" + }, + { + "idx": 3973, + "question": "Most metals strain harden at room temperature.(a) True(b) False", + "answer": "True. Most metals strain harden at room temperature.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案形式为True或False，符合判断题的特征 | 知识层次: 题目考查对金属应变硬化这一基本概念的记忆和理解，属于基础概念记忆层次。 | 难度: 在选择题型中属于基本概念正误判断，仅需记忆金属在室温下的应变硬化特性即可作答，无需深入理解或分析。" + }, + { + "idx": 3974, + "question": "During the recovery of a cold-worked material, is some of the internal strain energy relieved?", + "answer": "Some of the internal strain energy is relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is some of the internal strain energy relieved?\"），而答案直接给出了判断结果（\"Some of the internal strain energy is relieved.\"）。这符合判断题的特征，即对陈述的真伪进行判断。 | 知识层次: 题目考查冷加工材料恢复过程中内应变能变化的基本概念，属于对基本原理的记忆和理解。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即冷加工材料恢复过程中内部应变能的释放情况。正确选项直接陈述了基本原理，无需复杂理解或分析，属于最基本的概念正误判断。" + }, + { + "idx": 3975, + "question": "During the recovery of a cold-worked material, is all of the internal strain energy relieved?", + "answer": "All of the internal strain energy is not relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is all of the internal strain energy relieved?\"），而答案直接给出了判断结果（\"All of the internal strain energy is not relieved.\"），这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中内应变能释放情况的基本概念理解，属于基础知识的记忆和简单判断。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即冷加工材料恢复过程中内应变能是否完全释放的定义性知识。正确选项直接陈述了基本原理（内应变能不会完全释放），无需复杂理解或分析，属于基本概念正误判断的简单题目。" + }, + { + "idx": 3976, + "question": "During the recovery of a cold-worked material, is there some reduction in the number of dislocations?", + "answer": "There is some reduction in the number of dislocations.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"is there some reduction\"），而答案直接给出了对错判断（\"There is some reduction\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中位错数量变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆冷加工材料恢复过程中位错数量变化的基本原理即可作答，无需深入理解或分析多个概念，因此属于最低难度等级。" + }, + { + "idx": 3977, + "question": "During the recovery of a cold-worked material, is there a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state?", + "answer": "There is not a significant reduction in the number of dislocations, to approximately the number found in the precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了对陈述的判断（否定），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中位错数量变化的基本概念的理解和记忆，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于冷加工材料恢复过程中位错数量变化的基本陈述是否正确。题目直接考察对恢复过程定义的理解，无需复杂推理或概念间的比较分析，属于选择题型中最简单的正误判断类型。" + }, + { + "idx": 3978, + "question": "During the recovery of a cold-worked material, is the electrical conductivity recovered to its precold-worked state?", + "answer": "The electrical conductivity is recovered to its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（是否恢复到冷加工前的状态），答案直接给出了对陈述的判断（是/否）。这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料恢复过程中电导率变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即冷加工材料恢复过程中电导率是否恢复到冷加工前状态的简单正误判断。题目仅要求考生回忆和识别基本定义或原理，无需深入理解或分析多个概念，因此属于最低难度等级。" + }, + { + "idx": 3979, + "question": "During the recovery of a cold-worked material, is the thermal conductivity recovered to its precold-worked state?", + "answer": "The thermal conductivity is recovered to its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即热导率是否恢复到冷加工前的状态），答案直接给出了对陈述的判断（是或否）。 | 知识层次: 题目考查对冷加工材料恢复过程中热导率变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需判断热导率在冷加工材料恢复过程中是否恢复到原始状态。题目直接给出了正确选项，无需复杂推理或概念比较，符合选择题型中最简单的正误判断难度等级。" + }, + { + "idx": 3980, + "question": "During the recovery of a cold-worked material, does the metal become more ductile, as in its precold-worked state?", + "answer": "The metal does not become more ductile, as in its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（金属是否恢复到冷加工前的延展性状态），答案直接给出了对错判断 | 知识层次: 题目考查对冷加工材料恢复过程中性能变化的基本概念记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆层次，仅需判断金属在冷加工恢复过程中是否恢复到冷加工前的延展性状态。题目直接考察对冷加工恢复过程的基本理解，无需复杂分析或概念比较，属于选择题型中最简单的正误判断类型。" + }, + { + "idx": 3981, + "question": "During the recovery of a cold-worked material, are grains with high strains replaced with new, unstrained grains?", + "answer": "Grains with high strains are not replaced with new, unstrained grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"are grains with high strains replaced with new, unstrained grains?\"），而答案直接给出了对错判断（\"Grains with high strains are not replaced with new, unstrained grains.\"）。这符合判断题的特征。 | 知识层次: 题目考查对冷加工材料回复过程中晶粒变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于冷加工材料恢复过程中晶粒变化的陈述是否正确。题目直接考察对基本定义和原理的记忆，无需深入理解或复杂分析，因此在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3982, + "question": "During the recrystallization of a cold-worked material, is some of the internal strain energy relieved?", + "answer": "All of the internal strain energy is relieved.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"All of the internal strain energy is relieved\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料再结晶过程中内应变能变化的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于再结晶过程中内应变能释放的基本陈述是否正确。题目结构简单，无需复杂推理或概念比较，符合选择题型中最基础的难度等级。" + }, + { + "idx": 3983, + "question": "During the recrystallization of a cold-worked material, is there some reduction in the number of dislocations?", + "answer": "There is significant reduction in the number of dislocations.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（即是否在再结晶过程中位错数量会减少），答案直接给出了判断结果（位错数量显著减少），符合判断题的特征。 | 知识层次: 题目考查对再结晶过程中位错数量变化的基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接询问冷加工材料再结晶过程中位错数量是否减少，正确选项明确陈述了\"位错数量显著减少\"这一基础概念。这只需要学生对再结晶过程的基本定义和原理有记忆性知识即可正确回答，无需深入理解或分析多个概念。因此按照选择题型的难度分级标准，这属于等级1的基础概念正误判断题。" + }, + { + "idx": 3984, + "question": "During the recrystallization of a cold-worked material, does the metal become more ductile, as in its precold-worked state?", + "answer": "The metal becomes more ductile, as in its precold-worked state.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（金属是否在再结晶后变得更延展）。答案直接给出了对陈述的判断（\"The metal becomes more ductile\"），符合判断题的特征。 | 知识层次: 题目考查对冷加工材料再结晶后性能变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断金属在再结晶后是否恢复延展性这一基本事实。题目直接给出了正确选项，无需复杂分析或概念比较，符合选择题型中最简单的正误判断难度等级。" + }, + { + "idx": 3985, + "question": "During the recrystallization of a cold-worked material, are grains with high strains replaced with new, unstrained grains?", + "answer": "Grains with high strains are replaced with new, unstrained grains.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了判断结果（陈述是正确的）。这符合判断题的特征。 | 知识层次: 题目考查对再结晶过程中晶粒变化的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆再结晶过程中高应变晶粒被新无应变晶粒替代的基本原理，无需深入理解或分析复杂概念。" + }, + { + "idx": 3986, + "question": "Grain growth requirements\n}\nGrain growth must always be preceded by recovery and recrystallization.(a) True(b) False", + "answer": "False. Grain growth does not always need to be preceded by recovery and recrystallization; it may occur in materials that have not been cold worked.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（True or False），答案直接给出了False的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对晶粒生长基本概念的理解，需要记忆和判断晶粒生长是否必须经过回复和再结晶过程，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆和理解晶粒生长的基本条件即可作答，无需复杂分析或比较多个概念。" + }, + { + "idx": 4001, + "question": "Does increasing temperature favor brittle fracture in polymers?", + "answer": "No, increasing temperature does not favor brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对/错），答案直接给出了判断结果（No），符合判断题的特征 | 知识层次: 题目考查对聚合物断裂行为与温度关系的基本概念记忆，属于基础原理的直接应用，无需复杂分析或计算。 | 难度: 该题目属于基础概念正误判断题，仅需记忆温度对聚合物断裂性能的基本影响原理。在选择题型中，这属于最简单的难度等级，因为只需识别\"温度升高不利于聚合物脆性断裂\"这一基本事实，无需深入理解或分析多个概念。" + }, + { + "idx": 4002, + "question": "Does increasing strain rate favor brittle fracture in polymers?", + "answer": "Yes, increasing strain rate favors brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了对错判断。 | 知识层次: 题目考查对聚合物应变率与脆性断裂关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于选择题型中的概念理解对错判断难度。虽然问题涉及聚合物材料的基本力学行为（应变速率与脆性断裂的关系），但只需理解\"应变速率增加会促进聚合物脆性断裂\"这一基本原理即可作答，不需要进行复杂的概念比较或分析。这属于对材料科学基础概念的简单应用层次，比纯粹的定义记忆（等级1）稍难，但明显低于需要综合分析多个概念的等级3难度。" + }, + { + "idx": 4003, + "question": "Does the presence of a sharp notch favor brittle fracture in polymers?", + "answer": "Yes, the presence of a sharp notch favors brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了明确的判断（Yes），符合判断题的特征 | 知识层次: 题目考查对聚合物断裂行为的基本概念记忆和理解，涉及尖锐缺口对脆性断裂的影响这一基本原理。 | 难度: 该题目属于选择题型中的概念理解对错判断难度。题目考察的是对聚合物断裂行为基本原理的理解，特别是缺口效应这一具体概念。虽然需要理解\"尖锐缺口促进脆性断裂\"这一原理，但不需要进行多概念比较或复杂分析，属于单一概念的应用判断。在选择题型中，这比纯粹的定义记忆（等级1）稍难，但比需要综合多个概念的复杂判断（等级3）简单。" + }, + { + "idx": 4004, + "question": "Does decreasing specimen thickness favor brittle fracture in polymers?", + "answer": "No, decreasing specimen thickness does not favor brittle fracture in polymers.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"Does decreasing specimen thickness favor brittle fracture in polymers?\"），而答案直接给出了对错判断（\"No\"），符合判断题的特征。 | 知识层次: 题目考查对聚合物断裂行为的基本概念的理解，属于基础概念记忆范畴，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念记忆层次，仅需判断\"减小试样厚度是否有利于聚合物脆性断裂\"这一基本概念的正误。正确选项直接给出了明确的否定结论，不需要任何概念理解或分析过程，属于选择题型中最简单的正误判断题。" + }, + { + "idx": 4011, + "question": "Is solid ductile cast iron (ferrite solid solution + embedded graphite spheres) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is solid ductile cast iron... a two-phase material system?\"），答案明确给出了\"Yes\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的记忆和理解，涉及材料组成和相的定义，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆材料科学中两相系统的定义即可作答。题目直接询问是否属于两相系统，并给出明确的结构描述（铁素体固溶体+石墨球），只需判断是否符合两相系统的定义特征（存在物理边界分隔化学/结构不同的区域）。在选择题型中属于最基础的认知层级，无需复杂推理或概念关联。" + }, + { + "idx": 4012, + "question": "Is solid sodium chloride (salt, NaCl) a two-phase material system?", + "answer": "No, it is a single-phase compound, not a solution. The ratio of the two ions is in a fixed stoichiometry and they adopt an orderly arrangement in the crystal.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"固体氯化钠是否是两相材料系统\"这一陈述的对错。答案直接给出了\"否\"的判断，并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对单相和多相材料系统的基本概念的理解和记忆，涉及对NaCl晶体结构的简单认知，不需要复杂的分析或推理。 | 难度: 该题目属于基础概念正误判断，仅需记忆固体氯化钠是单相化合物这一基本事实即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4013, + "question": "Is liquid bronze (Cu + Sn liquid solution) a two-phase material system?", + "answer": "No, it is a liquid solution, and solutions are single-phase by definition.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（判断液态青铜是否为两相材料系统），答案直接给出了对错判断和简要解释，符合判断题的特征。 | 知识层次: 题目考查对相和溶液定义的基础概念记忆和理解，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念正误判断，仅需记忆\"溶液是单相系统\"这一基本定义即可作答。在选择题型中属于最简单的直接知识回忆类题目，无需任何分析推理过程。" + }, + { + "idx": 4014, + "question": "Is solid gray cast iron (ferrite solid solution + embedded graphite flakes) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Is solid gray cast iron a two-phase material system?），答案直接给出了明确的判断（Yes）和简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及材料组成和相的定义，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆材料科学中关于两相系统的基本定义即可作答。题目直接询问灰色铸铁是否为两相系统，并提供了明确的正确选项描述，不涉及复杂概念分析或多步骤推理。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4015, + "question": "Is solid aluminum featuring dissolved silicon a two-phase material system?", + "answer": "No, it is a solid solution since silicon is implied to substitute for aluminum. Solutions are single-phase by definition.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断一个陈述的对错（\"Is solid aluminum featuring dissolved silicon a two-phase material system?\"），答案直接给出了对错判断（\"No\"）并解释了原因。这符合判断题的特征。 | 知识层次: 题目考查对固溶体和两相系统基本定义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基本概念正误判断，仅需记忆固体溶液的定义和单相系统的概念即可做出正确选择，无需深入理解或分析复杂概念。" + }, + { + "idx": 4016, + "question": "Is solid lead-tin solder (a mixture of Pb-rich and Sn-rich solid solutions) a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is solid lead-tin solder... a two-phase material system?\"），答案明确给出了\"Yes\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的记忆和理解，涉及简单的分类判断，不需要复杂的分析或计算。 | 难度: 该题目属于基本概念正误判断，仅需记忆和识别\"两相材料系统\"的定义即可作答。题目直接考察对铅锡焊料相组成的记忆性知识，无需复杂推理或概念比较，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4017, + "question": "Is partially melted aluminum a two-phase material system?", + "answer": "No, the physical boundary merely separates volumes that are structurally distinct (crystalline and liquid).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"部分熔化的铝是否是两相材料系统\"这一陈述的正确性。答案直接给出了\"否\"的判断并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解，仅需判断部分熔融铝是否属于两相系统，属于基础概念的记忆和理解层面。 | 难度: 该题目属于基础概念正误判断题，仅需要考生记忆并识别\"部分熔融铝是否为两相材料系统\"这一基本定义。题目提供明确的正误选项，不涉及概念理解或复杂分析，符合选择题型中最简单的难度等级标准。" + }, + { + "idx": 4018, + "question": "Is frozen water with trapped air bubbles a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is frozen water with trapped air bubbles a two-phase material system?\"），答案直接给出了判断结果（\"Yes\"）并提供了简要解释。这符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和判断，属于基础概念记忆范畴，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接考察对\"两相材料系统\"定义的理解，只需判断是否存在物理边界和化学/结构差异这两个基本要素。正确选项明确给出了定义性描述，不需要进行复杂分析或概念比较，符合等级1的简单记忆性知识考查要求。" + }, + { + "idx": 4019, + "question": "Is epoxy embedded with carbon fibers a two-phase material system?", + "answer": "Yes, it is a two-phase system because there is a physical boundary beyond the particle level that separates chemically and structurally distinct volumes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"Is epoxy embedded with carbon fibers a two-phase material system?\"），答案直接给出了明确的判断（\"Yes\"）并提供了简要解释，符合判断题的特征。 | 知识层次: 题目考查对两相材料系统基本概念的理解和记忆，涉及材料组成和相界面的基本定义，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅要求对基础概念进行正误判断，即判断环氧树脂嵌入碳纤维是否为两相材料系统。题目涉及的知识点较为基础，属于定义和分类的记忆性知识，无需深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4050, + "question": "In order for a semiconductor to exhibit extrinsic electrical characteristics, relatively high impurity concentrations are required.(a) True(b) False", + "answer": "False. Even when minute impurity concentrations (e.g., 1 atom in 10^{12} ) are present in a semiconductor, its electrical characteristics will be extrinsic.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附带简要解释 | 知识层次: 题目考查对半导体本征和外征特性的基本概念的理解，属于基础概念记忆范畴，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念正误判断，仅需记忆半导体掺杂的基本原理即可作答，无需复杂分析或概念比较。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4056, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum alloys are generally not viable as lightweight structural materials in humid environments because they are highly susceptible to corrosion by water vapor.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），并且答案是一个明确的判断（F）。这符合判断题的特征。 | 知识层次: 题目考查对铝合金在潮湿环境中耐腐蚀性能的基本概念记忆和理解，属于基础知识的判断。 | 难度: 该题目属于基础概念正误判断，仅需记忆铝及铝合金的基本特性（如耐腐蚀性）即可作答。题目陈述明确，无需复杂分析或概念比较，符合选择题型中最简单的难度等级。" + }, + { + "idx": 4057, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum alloys are generally superior to pure aluminum, in terms of yield strength, because their microstructures often contain precipitate phases that strain the lattice, thereby hardening the alloy relative to pure aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案形式为简单的T/F判断，符合判断题的特征。 | 知识层次: 题目考查对铝合金强化机制的基本概念记忆和理解，即通过析出相引起晶格应变从而强化合金的原理。这属于材料科学中关于金属强化机制的基础知识，不需要复杂的分析或综合应用。 | 难度: 在选择题中属于中等偏下难度，需要理解铝合金和纯铝的基本区别以及沉淀相的作用，但不需要复杂的分析或比较多个概念" + }, + { + "idx": 4058, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Aluminum is not very workable at high temperatures in air, in terms of extrusion and rolling, because a non-protective oxide grows and consumes the metal, converting it to a hard and brittle ceramic.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案形式为F（False），符合判断题的特征 | 知识层次: 题目考查对铝及其合金在高温下加工性能的基本概念记忆和理解，涉及氧化膜的形成及其对加工性能的影响，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铝在高温下的工作特性这一基础概念即可做出正确选择，无需深入理解或分析多个概念。" + }, + { + "idx": 4059, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: Compared to most other metals, like steel, pure aluminum is very resistant to creep deformation.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案是一个明确的判断（F），符合判断题的特征。 | 知识层次: 题目考查对纯铝蠕变性能的基本概念记忆，属于基础知识的判断，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆纯铝的抗蠕变性能相对于其他金属（如钢）较差这一基础事实即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4060, + "question": "Select T/F for the following statement regarding aluminum / aluminum alloys: The relatively low melting point of aluminum is often considered a significant limitation for structural applications.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），答案也是简单的T/F形式，符合判断题的特征。 | 知识层次: 题目考查对铝及其合金基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆铝及其合金的基本特性（如相对较低的熔点）即可作答。在选择题型中属于最简单的难度等级，不涉及概念理解或复杂分析。" + }, + { + "idx": 4061, + "question": "[a] Aluminum alloys are generally viable as lightweight structural materials in humid environments because they are not very susceptible to corrosion by water vapor.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Aluminum alloys are generally viable as lightweight structural materials in humid environments because they are not very susceptible to corrosion by water vapor.），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对铝合金在潮湿环境中耐腐蚀性的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目直接考察对铝合金在潮湿环境中耐腐蚀性的基础概念记忆，只需判断陈述是否正确即可，无需深入理解或分析多个概念。" + }, + { + "idx": 4062, + "question": "[b] Aluminum is not very workable at high temperatures in air, in terms of extrusion and rolling, because a non-protective oxide grows and consumes the metal, converting it to a hard and brittle ceramic.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述，要求判断其正确性（答案F表示错误），符合判断题的特征。 | 知识层次: 题目考查对铝在高温下加工性能的基本概念记忆，涉及铝氧化物形成及其对加工性能影响的简单事实判断，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念正误判断题，仅需记忆铝在高温下的氧化行为这一基本事实即可作答。在选择题型中属于最简单的难度等级，不涉及概念理解或复杂分析。" + }, + { + "idx": 4063, + "question": "[c] Aluminum alloys are generally superior to pure aluminum, in terms of yield strength, because their microstructures often contain precipitate phases that strain the lattice, thereby hardening the alloy relative to pure aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（答案T表示正确），这是典型的判断题特征。题目没有提供多个选项、不需要计算或文字解释，完全符合判断题的定义。 | 知识层次: 题目考查铝合金相对于纯铝的强化机制的基本概念，涉及沉淀相和晶格应变的基础知识，属于基础概念的记忆和理解层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目陈述了一个关于铝合金相对于纯铝的优势的基础事实，即由于沉淀相的存在导致晶格应变从而硬化合金。正确选项直接对应这一基础概念的陈述，无需深入理解或分析多个概念。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4064, + "question": "[d] Compared to other metals, like steel, pure aluminum is very resistant to failure via fatigue.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其正确性（F表示错误），这是典型的判断题特征 | 知识层次: 题目考查对金属疲劳性能的基础概念记忆和理解，属于对纯铝与钢等金属疲劳性能差异的基本认知。 | 难度: 在选择题型中，此题属于基础概念正误判断，仅需记忆纯铝与钢在疲劳失效方面的基本特性对比即可作答，无需复杂分析或推理过程。" + }, + { + "idx": 4065, + "question": "[e] Aluminum exhibits one of the highest melting points of all metals, which makes it difficult and expensive to cast.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Aluminum exhibits one of the highest melting points of all metals, which makes it difficult and expensive to cast），并要求判断其正误（答案：F）。这是典型的判断题形式。 | 知识层次: 题目考查对铝的熔点这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接陈述了一个关于铝的错误事实（铝的熔点实际上相对较低），学生只需要凭借对金属熔点的基本记忆即可判断正误。不需要进行概念理解或复杂分析，属于最基础的难度等级。" + }, + { + "idx": 4066, + "question": "[a] Copper has a higher elastic modulus than aluminum.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜的弹性模量比铝高），并要求判断其正确性（答案为T表示正确），这符合判断题的特征 | 知识层次: 题目考查对铜和铝弹性模量这一基本物理性质的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求判断铜和铝的弹性模量高低这一基本概念的正误，属于最基础的概念记忆层次。题目仅涉及单一知识点，无需理解或分析复杂概念，解题步骤简单直接，符合等级1的难度标准。" + }, + { + "idx": 4067, + "question": "[b] The density of copper is closer to that of aluminum than it is to iron.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜的密度更接近铝而不是铁），并要求判断其正确性（答案为F，即错误）。这符合判断题的特征，即判断陈述的对错。 | 知识层次: 题目考查对铜、铝和铁密度的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念正误判断，仅需记忆铜、铝和铁的密度关系即可做出正确判断。题目不涉及复杂概念或分析过程，属于最简单的难度等级。" + }, + { + "idx": 4068, + "question": "[c] Bronze is an alloy of copper and zinc.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Bronze is an alloy of copper and zinc），并要求判断其正误（答案F表示错误），符合判断题的特征。 | 知识层次: 题目考查对青铜合金成分的基本概念记忆，仅需判断铜和锌是否为青铜的主要成分，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断青铜是否为铜和锌的合金这一简单事实。在选择题型中，这种直接的正误判断题属于最低难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 4069, + "question": "[d] Copper and its alloys form a green tarnish over time, consisting of sulfides and carbonates.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜及其合金会随时间形成绿色锈蚀），并要求判断其正确性（答案给出T表示正确），符合判断题的特征。 | 知识层次: 题目考查对铜及其合金表面形成的绿色锈蚀物的基本成分的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，此题属于基本概念正误判断。题目仅要求识别铜及其合金随时间形成绿色锈层（由硫化物和碳酸盐组成）这一事实的正确性，不需要深入理解或分析多个概念。这是最基础的定义性知识记忆题，符合等级1的难度标准。" + }, + { + "idx": 4070, + "question": "[e] Copper is relatively resistant to corrosion by neutral and even mildly basic water, making it useful for freshwater plumbing applications.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（铜在中性和弱碱性水中相对耐腐蚀），并要求判断其正确性（答案T表示正确），符合判断题的特征。 | 知识层次: 题目考查对铜在特定环境下的耐腐蚀性能这一基础概念的记忆和理解，属于材料科学中的基本原理记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目仅要求考生记忆铜在中性和弱碱性水中的耐腐蚀性这一基础事实，无需进行概念理解或复杂分析。正确选项直接对应基础概念记忆层次的知识点，解题步骤简单直接。" + }, + { + "idx": 4071, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is much more abundant in the earth's crust compared to iron or aluminum.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（T/F），且答案直接给出对错判断（F），符合判断题的特征 | 知识层次: 题目考查对铜、铁和铝在地壳中丰度的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念的正误判断，即铜在地壳中的丰度与铁或铝的比较。题目不需要复杂的分析或理解多个概念，只需记忆相关基本事实即可判断正误。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4072, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is one of just a few metals that can be found in metallic form in nature.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（T/F），属于典型的判断题形式 | 知识层次: 题目考查对铜及其合金基本性质的记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆铜在自然界中的存在形式这一简单事实即可作答。在选择题型中，这类直接考察基础概念记忆的题目属于最低难度等级，不需要任何分析或推理过程。" + }, + { + "idx": 4073, + "question": "Select T / F for the following statement regarding copper & copper alloys: Pure and/or annealed copper is more difficult to machine compared to its work-hardened form or its alloys.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为T（True），符合判断题的特征 | 知识层次: 题目考查对铜及其合金加工性能的基础概念记忆，仅需判断纯铜/退火铜与加工硬化铜/合金的机械加工难易对比关系，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铜及其合金的加工性能这一基础概念即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 4074, + "question": "Select T / F for the following statement regarding copper & copper alloys: Copper is a minor component (by weight) of most brass & bronze alloys.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T/F），且答案以F（False）的形式给出，符合判断题的特征 | 知识层次: 题目考查对铜及其合金（黄铜和青铜）基本组成的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铜在黄铜和青铜合金中的主要成分地位即可作答，无需复杂分析或概念比较。" + }, + { + "idx": 4075, + "question": "Select T / F for the following statement regarding copper & copper alloys: Amongst metals and alloys copper is one of the best conductors of heat.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Select T / F），答案形式为T（正确），符合判断题的特征。 | 知识层次: 题目考查对铜及其合金基本物理性质（导热性）的记忆和理解，属于基础概念记忆范畴 | 难度: 该题目属于基础概念正误判断，仅需记忆铜及其合金是优良的热导体这一基本事实即可作答，无需深入理解或分析多个概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4076, + "question": "[a] Nickel is majority component (by mass) in certain superalloys such as Waspaloy TM.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为T/F），符合判断题的特征。 | 知识层次: 题目考查对镍在特定超级合金中作为主要成分的基础知识记忆，属于定义和分类的基本概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断关于镍在Waspaloy TM超合金中为主要成分这一事实陈述的正误。在选择题型中，这类直接考察定义或基本事实记忆的题目属于最低难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 4077, + "question": "[b] Tungsten is the lowest density metal that has structural use.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（F表示错误），符合判断题的特征。 | 知识层次: 题目考查对钨金属基本性质（密度）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断题，仅需记忆钨的基本物理性质（密度）及其在结构材料中的定位。题目陈述简单明确，只需判断\"钨是结构用金属中密度最低的\"这一说法的正误，无需进行复杂的概念分析或比较。在选择题型中，这属于最基础的知识记忆层次，因此难度等级为1。" + }, + { + "idx": 4078, + "question": "[c] Tantalum offers extremely good corrosion resistance, especially at low temperatures.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Tantalum offers extremely good corrosion resistance, especially at low temperatures），并要求判断其正确性（答案：T），符合判断题的特征。 | 知识层次: 题目考查对钽（Tantalum）腐蚀抗性这一基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆钽(Tantalum)具有良好耐腐蚀性的特性，尤其是低温环境下的表现。题目不涉及概念理解或复杂分析，仅需基础概念记忆即可正确作答，因此属于最低难度等级。" + }, + { + "idx": 4079, + "question": "[d] Magnesium metal is very similar to aluminum, in terms of its physical and mechanical properties.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Magnesium metal is very similar to aluminum, in terms of its physical and mechanical properties），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对镁和铝金属物理和机械性能相似性的基本概念记忆，属于基础知识的认知层次。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆镁和铝在物理和机械性质上的相似性这一基础知识点即可作答，无需深入理解或分析。" + }, + { + "idx": 4080, + "question": "[e] Beryllium metal is commonly used as an alloying agent in copper metal.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述（Beryllium metal is commonly used as an alloying agent in copper metal），并要求判断其正误（答案：T），符合判断题的特征。 | 知识层次: 题目考查对铍金属作为铜合金化剂这一基本事实的记忆，属于基础概念的记忆性知识，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆铍金属常用作铜合金的添加剂这一基础事实即可作答，无需理解或分析复杂概念，解题步骤简单直接。" + }, + { + "idx": 4082, + "question": "The high-temperature performance of silica refractories is compromised by the presence of even small concentrations of alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\end{array}(a) True(b) False", + "answer": "True. The presence of even small amounts of alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3)}\\right) in silica refractory ceramics compromises their high-temperature performance.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（True/False），且答案直接给出了判断结果（True） | 知识层次: 题目考查对硅质耐火材料高温性能影响因素的基础知识记忆，仅需判断氧化铝的存在是否会影响其性能，属于基本概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于基本概念正误判断。题目直接询问关于硅质耐火材料高温性能受氧化铝影响的基本事实，只需记忆相关知识点即可作答，无需深入理解或复杂分析。因此属于难度等级1。" + }, + { + "idx": 4086, + "question": "The presence of silica \\left(\\mathrm{SiO}_{2}\\right) in basic refractory ceramics is beneficial to their high-temperature performance.(a) True(b) False", + "answer": "False. The presence of silica \\left(\\mathrm{SiO}_{2}\\right) in basic refractory ceramics is deleterious on their hightemperature performance.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"True\"或\"False\"），答案直接给出了判断结果（False）并附带简要解释，符合判断题的特征。 | 知识层次: 题目考查对基础概念的记忆和理解，即硅在碱性耐火陶瓷中的作用及其对高温性能的影响。 | 难度: 该题目属于基础概念正误判断，仅需记忆基本概念即可作答，无需深入理解或分析。题目直接询问二氧化硅在碱性耐火陶瓷中的作用，正确选项明确指出了其有害影响，属于最基础的定义性知识。" + }, + { + "idx": 4095, + "question": "Once the fibers fail in a fibrous composite, catastrophic failure of the piece takes place.(a) True(b) False", + "answer": "False. Once the fibers fail in a composite, catastrophic failure of the piece does not take place. Since the broken fibers are still embedded within the matrix, they are still capable of sustaining a diminished load.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断陈述的对错，答案明确给出了True或False的选择，并解释了原因。 | 知识层次: 题目考查对复合材料失效行为的基本概念的理解，属于基础知识的记忆和简单应用。 | 难度: 该题目属于概念理解的对错判断，需要考生理解复合材料中纤维失效后的行为，并判断题目陈述的正确性。虽然涉及基础概念，但需要一定的理解深度，而非简单的记忆性知识。" + }, + { + "idx": 4099, + "question": "[a] Composites are single-phase materials by definition.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（答案为F表示错误），符合判断题的特征 | 知识层次: 题目考查复合材料定义的基础概念记忆，属于对材料科学基本分类的理解 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆复合材料的定义即可判断正误。题目直接考察对\"复合材料是否为单相材料\"这一基础定义的记忆，无需理解或分析复杂概念，因此属于最低难度等级。" + }, + { + "idx": 4100, + "question": "[b] The term \"composite\" applies to materials that feature polymeric materials only.", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案以F（False）给出，符合判断题的特征。 | 知识层次: 题目考查对复合材料定义的基础概念记忆和理解，仅需判断陈述是否符合基本定义，无需复杂分析或应用。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆复合材料的基本定义即可判断正误，无需深入理解或分析多个概念。" + }, + { + "idx": 4101, + "question": "[c] Structural composites are, in general, highly regarded for their specific strengths.", + "answer": "T", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（T/F），符合判断题的特征 | 知识层次: 题目考查对结构复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断题，仅需记忆结构复合材料的基本特性（高比强度）即可作答，无需深入理解或分析多个概念，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4102, + "question": "[d] Composites featuring continuous and aligned fibers for reinforcement generally offer properties that are highly isotropic compared to most metals (random polycrystals).", + "answer": "F", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（F表示错误），符合判断题的特征 | 知识层次: 题目考查对复合材料基本性质的理解，特别是关于纤维增强复合材料各向异性的基础概念。这属于对材料科学基础知识的记忆和简单理解，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念正误判断题，仅需记忆复合材料与金属在性能各向异性方面的基本差异。题目陈述明确，正确选项直接对应基础定义（连续排列纤维复合材料具有各向异性特性），无需复杂分析或概念比较，符合等级1\"基本概念正误判断\"的标准。" + }, + { + "idx": 4109, + "question": "Aramid fiber-reinforced composites have very high tensile strengths and relatively low compressive strengths.(a) True(b) False", + "answer": "True. Aramid fiber-reinforced composites have very high tensile strengths and relatively low compressive strength.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目给出一个陈述并要求判断其真伪（True/False），答案直接给出判断结果，符合判断题的特征 | 知识层次: 题目考查对Aramid纤维增强复合材料基本力学性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆Aramid fiber-reinforced composites的基本特性（高拉伸强度和低压缩强度）即可做出正确选择。题目不涉及复杂概念或需要深入理解，属于最基础的难度等级。" + }, + { + "idx": 4111, + "question": "Carbon fiber-reinforced composites have relatively high strengths?", + "answer": "Carbon fiber-reinforced composites have relatively high strengths.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了该陈述的判断结果。 | 知识层次: 题目考查对碳纤维增强复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳纤维增强复合材料是否具有较高强度这一基本事实。在选择题型中，这种直接考察定义或基本特性的题目属于最简单的难度等级，不需要复杂理解或分析过程。" + }, + { + "idx": 4112, + "question": "Carbon fiber-reinforced composites have relatively high stiffnesses?", + "answer": "Carbon fiber-reinforced composites have relatively high stiffnesses.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性，答案直接给出了陈述句的重复，符合判断题的特征 | 知识层次: 题目考查对碳纤维增强复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳纤维增强复合材料是否具有较高刚度这一基本事实。在选择题型中，这种直接考察定义或基本特性的题目属于最简单的难度等级，无需复杂推理或概念比较。" + }, + { + "idx": 4113, + "question": "Carbon fiber-reinforced composites have high service temperatures (>200 degrees C)?", + "answer": "Carbon fiber-reinforced composites have high service temperatures (>200 degrees C).", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（对错），答案直接给出了陈述句本身，符合判断题的特征。 | 知识层次: 题目考查对碳纤维增强复合材料基本性能的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳纤维增强复合材料是否具有高温使用性能（>200°C）这一基本事实。在选择题型中，此类正误判断题是最简单的类型，无需理解或分析复杂概念，仅需回忆相关定义即可作答。" + }, + { + "idx": 4116, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better fracture toughnesses?", + "answer": "Ceramic-matrix composites have higher fracture toughnesses than other ceramic materials.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（Ceramic-matrix composites have higher fracture toughnesses than other ceramic materials），答案直接给出了判断结果（是或否），符合判断题的特征。 | 知识层次: 题目考查对陶瓷基复合材料基本性能（断裂韧性）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求对基础概念进行正误判断，即陶瓷基复合材料是否比其他陶瓷材料具有更高的断裂韧性。题目涉及的知识层次为基础概念记忆，不需要深入理解或复杂分析，因此属于最简单的难度等级。" + }, + { + "idx": 4117, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better oxidation resistance?", + "answer": "The answer is not provided in the given information.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断陶瓷基复合材料是否比其他陶瓷材料具有更好的抗氧化性，属于判断陈述对错的题型。答案形式也符合判断题的特征。 | 知识层次: 题目考查对陶瓷基复合材料氧化抗性的基本概念记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆性知识，即陶瓷基复合材料与其他陶瓷材料在抗氧化性方面的比较。题目要求的是对基本概念的正误判断，不需要深入理解或复杂分析，因此属于等级1的难度。" + }, + { + "idx": 4118, + "question": "Compared to other ceramic materials, do ceramic-matrix composites have better stability at elevated temperatures?", + "answer": "The answer is not provided in the given information.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（陶瓷基复合材料在高温下是否比其他陶瓷材料具有更好的稳定性），答案形式为判断性结论 | 知识层次: 题目考查对陶瓷基复合材料在高温下稳定性的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即陶瓷基复合材料在高温下的稳定性与其他陶瓷材料的比较。题目要求的是对定义或分类的基本记忆，不需要深入理解或分析多个概念。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 4120, + "question": "Do carbon-carbon composites exhibit high tensile moduli at elevated temperatures?", + "answer": "Carbon-carbon composites have high tensile moduli at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（碳碳复合材料在高温下是否具有高拉伸模量），答案直接给出了对错判断。这符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本性能的记忆和理解，属于基础概念层面的知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即碳-碳复合材料在高温下的拉伸模量特性。正确选项直接陈述了定义性知识，无需复杂理解或分析，属于最基本的概念正误判断。因此，在选择题型内属于最低难度等级。" + }, + { + "idx": 4121, + "question": "Do carbon-carbon composites exhibit high tensile strengths at elevated temperatures?", + "answer": "Carbon-carbon composites have high tensile strengths at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（\"Do carbon-carbon composites exhibit high tensile strengths at elevated temperatures?\"），而答案直接给出了判断结果（\"Carbon-carbon composites have high tensile strengths at elevated temperatures.\"）。这符合判断题的特征，即对陈述的真假进行判断。 | 知识层次: 题目考查对碳碳复合材料在高温下性能的基础概念记忆，仅需了解其基本特性即可回答，无需复杂分析或应用。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳碳复合材料在高温下是否具有高拉伸强度的基本事实。题目形式为简单的是非判断，不涉及概念理解或复杂分析，符合选择题型中最基础的难度等级。" + }, + { + "idx": 4122, + "question": "Do carbon-carbon composites exhibit resistance to creep?", + "answer": "Carbon-carbon composites are highly resistant to creep.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个简单的陈述句，询问碳碳复合材料是否具有抗蠕变性，答案直接给出了对错判断（\"highly resistant to creep\"），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料抗蠕变性能这一基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，只需判断碳-碳复合材料是否具有抗蠕变性能这一简单事实。题目不要求理解复杂概念或进行多步骤分析，属于最基本的概念正误判断层级。" + }, + { + "idx": 4123, + "question": "Do carbon-carbon composites exhibit large fracture toughness values?", + "answer": "Carbon-carbon composites have large fracture toughness values.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"碳碳复合材料是否具有大的断裂韧性值\"，答案直接给出了对错判断。这符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本性能的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需判断碳碳复合材料是否具有较大的断裂韧性值这一基本事实。正确选项直接陈述了定义性知识，无需复杂理解或分析过程，在选择题型中属于最简单的正误判断级别。" + }, + { + "idx": 4124, + "question": "Do carbon-carbon composites exhibit high thermal conductivities?", + "answer": "Carbon-carbon composites have high thermal conductivities.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，要求判断\"碳碳复合材料是否具有高热导率\"这一陈述的正确性。答案直接给出了明确的判断结果(\"具有高热导率\")，符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念正误判断，仅需记忆碳-碳复合材料的基本特性（高导热性）即可作答，无需理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4125, + "question": "Do carbon-carbon composites exhibit low coefficients of thermal expansion?", + "answer": "Carbon-carbon composites have low coefficients of thermal expansion.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断其正确性（碳-碳复合材料是否具有低热膨胀系数），答案直接给出了对陈述的判断（是/否）。这符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 在选择题型内，该题目仅涉及基础概念记忆，即碳碳复合材料的热膨胀系数特性。正确选项直接陈述了定义性知识，无需复杂理解或分析。属于最基础的正误判断，符合等级1的难度标准。" + }, + { + "idx": 4126, + "question": "Do carbon-carbon composites exhibit resistance to oxidation at elevated temperatures?", + "answer": "The answer does not specify resistance to oxidation at elevated temperatures.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个陈述句，要求判断碳碳复合材料在高温下是否具有抗氧化性，答案只需判断对错即可。 | 知识层次: 题目考查对碳碳复合材料基本特性的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即碳-碳复合材料在高温下的氧化抗性这一基本定义。正确选项直接陈述了答案未明确说明氧化抗性，无需深入理解或分析，属于最基础的正误判断。因此，在选择题型内属于等级1难度。" + }, + { + "idx": 4127, + "question": "Are carbon-carbon composites low cost?", + "answer": "The answer does not specify low cost.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目是一个是非判断问题，询问碳碳复合材料是否低成本，答案给出了明确的判断（没有明确说明低成本），符合判断题的特征。 | 知识层次: 题目考查对碳碳复合材料成本这一基本概念的记忆和理解，不涉及复杂分析或综合应用。 | 难度: 该题目属于基础概念记忆层次，仅需判断\"碳碳复合材料是否低成本\"这一简单陈述的正确性。正确选项直接给出了明确答案，不需要任何推理或概念间的比较分析，是最基础的正误判断题。" + }, + { + "idx": 4128, + "question": "Laminar composites have high strengths in all directions (in three dimensions).(a) True(b) False", + "answer": "False. Laminar composites have high strengths in all directions only in their two-dimensional planes.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断，并附带简要解释。 | 知识层次: 题目考查对层状复合材料基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆层压复合材料的基本特性（二维平面高强度）即可直接判断选项正误，无需理解或分析复杂概念。" + }, + { + "idx": 4141, + "question": "In a polycrystalline material, each grain will always consist of just a single domain.(a) True(b) False", + "answer": "False. In a polycrystalline material, each grain may consist of more than one domain.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（\"True\"或\"False\"），答案直接给出了判断结果（False）并附带简要解释，符合判断题的特征。 | 知识层次: 题目考查对多晶材料中晶粒和畴的基本概念的理解，属于基础概念的记忆和简单应用 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆多晶材料中晶粒与畴的基本关系即可作答，无需深入理解或分析复杂概念。" + }, + { + "idx": 4156, + "question": "Every nonmetallic material becomes opaque to electromagnetic radiation having some wavelength.(a) True(b) False", + "answer": "True. Every nonmetallic material becomes opaque to electromagnetic radiation having some wavelength. For all nonmetallic materials there is some maximum wavelength below which electronexcitations across the band gap will occur. This results in the adsorption of radiation, and, consequently, the material becomes opaque.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错（True/False），并且答案直接给出了对错判断和简要解释，符合判断题的特征。 | 知识层次: 题目考查非金属材料对电磁辐射不透明性的基本原理的记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念正误判断，仅需记忆非金属材料对电磁辐射的基本特性即可作答，无需深入理解或分析复杂概念。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 4165, + "question": "Only pure materials luminesce.(a) True(b) False", + "answer": "False. Luminescent materials contain impurities.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求判断陈述的对错，答案直接给出了True或False的判断结果 | 知识层次: 题目考查对发光材料基本概念的记忆和理解，即纯材料和掺杂材料在发光性质上的区别。 | 难度: 在选择题型中，该题目属于基本概念正误判断，仅需记忆纯材料和发光材料的基本定义即可作答，无需深入理解或分析多个概念。" + }, + { + "idx": 4315, + "question": "For 11.20 kg of a magnesium-lead alloy of composition 30 wt% Pb-70 wt% Mg, is it possible, at equilibrium, to have α and Mg2Pb phases having respective masses of 7.39 kg and 3.81 kg?", + "answer": "yes, it is possible to have a 30 wt% pb-70 wt% mg alloy with masses of 7.39 kg and 3.81 kg for the α and mg2pb phases, respectively.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求判断在特定条件下是否可能达到某种相平衡状态，答案只需回答\"yes\"或\"no\"即可，属于典型的判断题形式。 | 知识层次: 题目需要应用相图知识进行多步计算，涉及相的质量分数计算和相平衡的判断，需要综合分析合金成分与相组成的关系。 | 难度: 在选择题型中，该题目属于较高难度，需要综合运用相图知识、质量平衡计算和相组成分析。解题过程涉及多步计算（如确定各相组成和验证质量平衡）以及概念关联（如理解α相和Mg2Pb相在相图中的位置）。虽然题目提供了正确选项，但学生仍需进行综合分析才能判断其正确性，这超出了简单的概念回忆或单步计算，属于中等应用层次的要求。" + }, + { + "idx": 4549, + "question": "Is a voltage generated between the two cell halves of a Zn/Zn2+ concentration cell where both electrodes are pure zinc, with Zn2+ concentrations of 1.0 M and 10^-2 M?", + "answer": "Yes, a voltage is generated.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（是否会产生电压），答案直接给出了\"是\"或\"否\"的判断，符合判断题的特征。 | 知识层次: 题目考查对浓度电池基本原理的理解和简单应用，需要知道浓度差会产生电压，但不需要复杂的计算或多步推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需判断浓度差是否会产生电压，无需复杂计算或公式推导。考生只需理解浓度电池的基本原理即可直接选择正确选项，属于选择题型中的基础难度。" + }, + { + "idx": 4898, + "question": "Is a voltage generated between the two cell halves of an Fe/Fe2+ concentration cell where both electrodes are pure iron, with Fe2+ concentrations of 0.5 M and 2 × 10^-2 M?", + "answer": "Yes, a voltage is generated.", + "question_type": "true_false", + "question_type_name": "判断题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求判断一个陈述的对错（是否会产生电压），答案直接给出\"Yes\"或\"No\"形式的判断，不需要计算或详细解释。 | 知识层次: 题目考查浓度电池的基本原理和简单应用，需要理解浓度差如何产生电压，并直接套用能斯特方程的基本概念来判断是否有电压产生。不需要多步计算或复杂的综合分析。 | 难度: 在选择题型中，该题目属于简单应用结果判断。题目直接考察对浓度电池基本原理的理解，只需判断在给定条件下是否会产生电压，无需进行复杂计算或多步骤推理。正确选项可以直接通过套用基本概念得出，符合等级2的简单应用要求。" + }, + { + "idx": 2967, + "question": "In a body-centered cubic structure with a lattice constant of $\\pmb{\\alpha}$, can a dislocation with a Burgers vector of a[100] decompose into $\\frac{a}{2}[111]+\\frac{a}{2}[1\\overline{{{1}}}\\overline{{{1}}}]$? (A) No (B) Yes (C) Possibly", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目涉及位错分解的复杂分析，需要理解Burgers矢量的守恒条件以及不同位错之间的相互作用。这要求综合运用材料科学中的晶体结构和位错理论，进行推理分析以判断分解是否可行。 | 难度: 在选择题型内，该题目属于最高难度等级。题目要求深入理解体心立方结构中的位错分解机制，并能够综合运用晶体学知识和位错理论进行推理分析。解题步骤复杂，需要判断Burgers矢量的分解是否满足能量和几何条件，涉及多个概念的深度整合和机理分析。此外，题目还要求对晶体学方向指数的运算有精确掌握，这在选择题型中属于非常高的认知要求。" + }, + { + "idx": 2760, + "question": "In a body-centered cubic structure, can a dislocation with Burgers vector $a[100]$ decompose into $\\frac{a}{2}[111]+\\frac{a}{2}[1\\overline{1}\\overline{1}]$? (A) No (B) Yes (C) Possible", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "complex_analysis", + "knowledge_level_name": "复杂分析", + "difficulty": 5, + "final_level": "Level_5", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确答案，符合选择题的特征。 | 知识层次: 题目涉及位错分解的矢量分析，需要理解Burgers矢量的几何关系、位错分解的能量条件以及晶体结构对位错行为的限制。这需要综合运用晶体学、位错理论和能量分析等多方面知识，属于复杂分析层次。 | 难度: 在选择题型中，该题目属于最高难度等级。它要求考生不仅掌握体心立方结构中的位错分解原理，还需要深入理解Burgers矢量的计算和能量守恒条件。解题步骤涉及复杂的矢量运算和能量分析，需要综合运用多个知识点进行推理判断。此外，题目中的选项设计也增加了判断的复杂性，要求考生具备深度推理和机理分析能力。" + }, + { + "idx": 3784, + "question": "Suppose 1 at% of the following elements is added to copper (forming a separate alloy with each element) without exceeding the solubility limit. Which one would be expected to give the higher strength alloy? For copper: r_Cu=1.278 Å (a) Au: r=1.442, φr=+12.8% (b) Mn: r=1.12, φr=-12.4% (c) Sr: r=2.151, φr=+68.3% (d) Si: r=1.176, φr=-8.0% (e) Co: r=1.253, φr=-2.0%", + "answer": "The Cu-Sr alloy would be expected to be strongest (largest size difference).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择一个能产生更高强度合金的元素，答案也是从给定的选项中选择一个正确答案。 | 知识层次: 题目需要理解固溶强化原理，分析不同溶质原子对铜基体强度的影响，综合考虑原子半径差异和电子结构因素，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。题目要求考生不仅理解固溶强化的基本原理（原子半径差异对强度的影响），还需要综合分析多个元素的原子半径差异（φr值）及其对铜合金强度的潜在影响。解题步骤涉及比较多个选项的数值差异，并选择最符合理论预期的选项。虽然题目提供了具体数据，但需要考生进行多步概念关联和综合分析，才能正确判断哪个元素会导致最高的强度提升。这超出了简单记忆或单一概念应用的范畴，属于中等偏上的选择题难度。" + }, + { + "idx": 4378, + "question": "Rank the following iron-carbon alloys and associated microstructures from the highest to the lowest tensile strength:\n(a) 0.25 wt% C with spheroidite,\n(b) 0.25 wt% C with coarse pearlite,\n(c) 0.60 wt% C with fine pearlite, and\n(d) 0.60 wt% C with coarse pearlit.", + "answer": "(c)(d)(b)(a)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的铁碳合金和微观结构选项中进行排序，选择从最高到最低抗拉强度的正确顺序。答案给出了一个特定的排序选项，符合选择题的特征。 | 知识层次: 题目要求对不同铁碳合金及其显微组织进行排序，需要理解碳含量和显微组织对材料力学性能的影响，并进行综合分析。这涉及到多个知识点的关联和比较，属于中等应用层次。 | 难度: 该题目在选择题型中属于较高难度，需要综合运用多个材料科学概念（碳含量、显微组织类型、力学性能关系）并进行多步分析判断。具体表现为：" + }, + { + "idx": 3551, + "question": "In a body-centered cubic structure with lattice constant a, can a dislocation with Burgers vector $a$ [100] decompose into $\\frac{a}{2}$ [111] + $\\frac{a}{2}$ [1-1-1]? ( )", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了明确的选项（A）作为答案。 | 知识层次: 题目涉及位错分解的判断，需要理解体心立方结构中的位错性质以及Burgers矢量的分解规则。虽然不涉及复杂的计算，但需要对位错分解的条件和原理有较好的理解，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生具备以下能力：" + }, + { + "idx": 750, + "question": "In the ${\\\\bf R O}\\\\mathrm{-SiO}{2}$ system, the order of the size of the immiscibility regions for: (1) $\\\\mathbf{Mg0-SiO}{2}$; (2) $\\\\mathbf{CaO}\\\\mathbf{-SiO}{2}$; (3) $\\\\mathbf{SrO}\\\\mathbf{-SiO}{2}$; (4) BaO$\\\\mathrm{SiO}_{2}$ is (a)$\\\\left(1\\\\right)>\\\\left(2\\\\right)>\\\\left(3\\\\right)>\\\\left(4\\\\right)$(b)(4)>(3)>(2)>(1)(c)$\\\\left(2\\\\right)>\\\\left(1\\\\right)>\\\\left(3\\\\right)>\\\\left(4\\\\right)$ (d $)(3)>(4)>(2)>(1)$", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择正确的顺序排列，属于选择题类型 | 知识层次: 题目要求对不同氧化物-SiO2系统中的不混溶区大小进行排序，这需要理解离子半径对相图不混溶区的影响，并能够综合分析不同氧化物的特性（如离子半径变化趋势）来推断不混溶区的大小顺序。这属于中等应用层次，涉及多步分析和概念关联。 | 难度: 在选择题中属于较高难度，需要综合理解RO-SiO2系统中不同氧化物的不混溶区域大小规律，并掌握碱土金属离子半径对相分离的影响。题目要求考生将多个概念（离子半径效应、相图特征）进行关联分析，并正确排序四种系统的相对大小关系，解题步骤涉及多步逻辑判断和比较。虽然题目提供了选项引导，但正确解答需要较深入的材料科学知识背景和综合分析能力。" + }, + { + "idx": 4682, + "question": "An alternating copolymer is known to have a number-average molecular weight of 100,000g / mol and a degree of polymerization of 2210 . If one of the repeat units is ethylene, which of styrene, propylene, tetrafluoroethylene, and vinyl chloride is the other repeat unit? Why?", + "answer": "the other repeat unit is vinyl chloride, with a molecular weight of 62.49 \\mathrm{g/mol}. this matches the calculated value of 62.45 \\mathrm{g/mol} for the unknown repeat unit.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（styrene, propylene, tetrafluoroethylene, and vinyl chloride）中选择正确的重复单元，并解释原因。答案也明确指出了选择的是哪一个选项（vinyl chloride）。 | 知识层次: 题目需要计算未知重复单元的分子量，并对比给定的选项进行匹配。这涉及多步计算和概念关联，需要综合分析已知信息（如数均分子量和聚合度）来推导出正确的重复单元。虽然不涉及复杂的推理或机理解释，但需要一定的应用能力和综合分析能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解交替共聚物的基本概念，并能够进行分子量和聚合度的计算。其次，需要通过计算推导出未知重复单元的正确选项，这涉及多步计算和综合分析。此外，题目还要求考生对乙烯、苯乙烯、丙烯、四氟乙烯和氯乙烯等单体的分子量有准确的记忆或计算能力。整个过程不仅需要概念理解，还需要较强的计算能力和综合分析能力，因此在选择题型中属于复杂分析过程的判断难度等级。" + }, + { + "idx": 3788, + "question": "Which of the following oxides is expected to have the largest solid solubility in \\mathrm{Al}_{2} \\mathrm{O}_{3} ?\n(a) \\mathrm{Y}_{2} \\mathrm{O}_{3} (b) \\mathrm{Cr}_{2} \\mathrm{O}_{3} (c) \\mathrm{Fe}_{2} \\mathrm{O}_{3}", + "answer": "\\mathrm{cr}_{2} \\mathrm{o}_{3} is expected to have the largest solid solubility in \\mathrm{al}_{2} \\mathrm{o}_{3}; in fact, they are completely soluble in one another.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择具有最大固溶度的氧化物，符合选择题的特征 | 知识层次: 题目需要理解氧化物在Al2O3中的固溶度原理，并分析不同氧化物的离子半径、电荷匹配等因素，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合考虑氧化物晶体结构、离子半径匹配性以及固溶度原理等多个材料科学概念。题目要求判断哪种氧化物在Al₂O₃中具有最大固溶度，这涉及对离子价态匹配（都是+3价氧化物）、离子半径相近性（Cr³⁰与Al³⁺半径最接近）以及晶体结构相容性的综合分析。虽然不涉及计算，但需要运用Hume-Rothery规则等固溶度理论进行多因素判断，比单纯记忆性选择题更具挑战性。" + }, + { + "idx": 4668, + "question": "A hypothetical AX type of ceramic material is known to have a density of 2.10g / {cm}^{3} and a unit cell of cubic symmetry with a cell edge length of 0.57nm. The atomic weights of the A and X elements are 28.5 and 30.0g / mol, respectively. On the basis of this information, which of the following crystal structures is (are) possible for this material: sodium chloride, cesium chloride, or zinc blende? Justify your choice(s).", + "answer": "of the three possible crystal structures, only sodium chloride and zinc blende have four formula units per unit cell, and therefore, are possibilities.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的三种晶体结构（sodium chloride, cesium chloride, zinc blende）中选择可能的选项，并需要根据提供的信息进行判断和论证。答案中明确指出只有两种结构是可能的，符合选择题的特征。 | 知识层次: 题目需要综合运用晶体结构知识、密度计算和单位晶胞分析，涉及多步计算和概念关联，但不需要复杂的推理分析或创新应用。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算（如密度计算、单位晶胞内原子数计算）和综合分析（比较不同晶体结构的特征）。题目不仅要求掌握晶体结构的基本概念，还需要将理论知识与实际计算相结合，判断哪种晶体结构符合给定的材料参数。这种综合应用和分析过程在选择题中属于较复杂的判断类型。" + }, + { + "idx": 4708, + "question": "Which of these elements would you expect to form an interstitial solid solution with nickel? The four Hume-Rothery rules must be satisfied: (1) the difference in atomic radii between Ni and the other element (ΔR%) must be less than ±15%; (2) the crystal structures must be the same; (3) the electronegativities must be similar; and (4) the valences should be the same.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Ni.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素中选择符合Hume-Rothery规则的选项，形成间隙固溶体。答案明确给出了选项（C, H, and O），符合选择题的特征。 | 知识层次: 题目要求应用Hume-Rothery规则进行综合分析，涉及原子半径、晶体结构、电负性和价态等多个因素的判断，需要一定的概念关联和综合分析能力。虽然不涉及复杂计算，但需要对多个规则进行理解和应用，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合应用Hume-Rothery规则的所有四个条件进行判断。题目要求考生不仅理解原子半径差异（ΔR% < ±15%）这一基本条件，还需要考虑晶体结构、电负性和化合价等其他三个规则。此外，正确选项涉及的是间隙固溶体（interstitial solid solution），这需要考生能够区分间隙固溶体和置换固溶体的形成条件，并识别出C、H、O等小原子半径元素的特点。这种多条件综合分析和概念区分的要求使得该题目在选择题型中属于复杂分析过程的判断难度等级。" + }, + { + "idx": 2944, + "question": "In a binary system composed of A and B, when α and β phases are in equilibrium, the relationship between composition (x) and free energy (G) for the two components is (A) $G^{\\\\alpha}=G^{\\\\beta}$ (B) $\\\\mathrm{d}G^{\\\\circ}/\\\\mathrm{d}x=\\\\mathrm{d}G^{\\\\beta}/\\\\mathrm{d}x$ (C) $G_{\\\\tt A}=G_{\\\\tt B}$", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项（A、B、C）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查二元系统中两相平衡时自由能与成分关系的理解，需要掌握自由能曲线的概念及其在相平衡中的应用，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目涉及二元系统中α和β相平衡时的自由能关系，需要理解热力学平衡条件（化学势相等）及其数学表达形式。其次，正确选项B要求考生掌握自由能对成分的偏导数（即化学势的斜率）在相平衡时必须相等的原理，这需要将热力学概念与数学微分运算相结合。此外，题目中的干扰项A和C分别设置了常见错误选项（直接比较相自由能或组分自由能），增加了判断难度。综合来看，该题需要考生在多步概念关联和综合分析的基础上才能正确选择，符合等级4\"复杂分析过程的判断\"的标准。" + }, + { + "idx": 2968, + "question": "In $\\\\mathrm{Ti}\\\\Omega_{2}$, when a portion of $\\\\mathrm{^{\\\\circ}Ti^{\\\\circ}}$ is reduced to $\\\\mathrm{Ti^{3+}}$, to balance the charge, there appears \\n\\n(A) oxygen ion vacancy (B) titanium ion vacancy (C) cation vacancy", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目涉及电荷平衡和缺陷化学的基本原理，需要理解Ti3+的形成如何影响晶格中的电荷平衡，并推断出氧空位的形成。这需要将多个概念关联起来进行综合分析，而不仅仅是记忆基础概念或进行简单应用。 | 难度: 在选择题型中，该题目属于较高难度。首先需要理解TiΩ2的晶体结构以及Ti3+的形成机制，其次要分析电荷平衡的原理，最后需要判断哪种缺陷类型能够补偿电荷变化。这个过程涉及晶体缺陷化学、氧化还原反应和电荷守恒等多个概念的关联分析，解题步骤较为复杂，属于需要综合分析判断的题目类型。" + }, + { + "idx": 701, + "question": "In the thermodynamic relation of diffusion coefficient, $\\\\left(1+\\\\frac{\\\\partial{\\\\ln{\\\\gamma_{i}}}}{\\\\partial{\\\\ln{N_{i}}}}\\\\right)$ is called the thermodynamic factor of diffusion coefficient. In non-ideal mixing systems: when the thermodynamic factor of diffusion coefficient $>0$, the diffusion result causes the solute to (A); when the thermodynamic factor of diffusion coefficient $<0$, the diffusion result causes the solute to (B). (a) segregation occurs (b) concentration remains unchanged (c) concentration tends to be uniform", + "answer": "On the curve of glass properties changing with temperature, there are two characteristic temperatures (18) and (19), and the viscosities corresponding to these two characteristic temperatures are (20) and (21) respectively.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（a）、（b）、（c）中选择正确的答案填入（A）和（B）的位置 | 知识层次: 题目涉及扩散系数的热力学因子及其在非理想混合系统中的影响，需要理解热力学因子的定义及其与扩散结果的关系。虽然题目给出了热力学因子的表达式，但需要考生理解其物理意义，并能够根据热力学因子的正负判断扩散结果。这需要一定的概念关联和综合分析能力，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解非理想混合系统中扩散系数的热力学因子概念，并能够分析其正负值对溶质扩散结果的影响。题目涉及多个概念的关联和综合分析，解题步骤较为复杂，需要较强的应用能力和判断力。" + }, + { + "idx": 2945, + "question": "The relationship between the growth velocity (vg) of a certain crystal during solidification and the dynamic undercooling (ΔTx) at the liquid-solid interface front is vg proportional to ΔTx^2. This crystal belongs to which growth mechanism? (A) Continuous growth (B) Growth via screw dislocations (C) Two-dimensional nucleation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对晶体生长机制的理解和应用，需要将生长速度与动态过冷度的关系与不同的生长机制联系起来进行分析，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解晶体生长机制中的动态过冷与生长速度的关系，并能够将数学关系（vg ∝ ΔTx^2）与具体的生长机制（如螺位错生长）联系起来。此外，还需要对连续生长、二维成核等其他机制有一定的了解，才能正确选择。这需要多步的概念关联和综合分析，超出了基础记忆或简单理解的层次。" + }, + { + "idx": 1757, + "question": "In the thermodynamic relation of diffusion coefficient, $\\\\left(1+\\\\frac{\\\\partial\\\\mathrm{ln}\\\\gamma_{i}}{\\\\partial\\\\mathrm{ln}N_{\\\\mathrm{i}}}\\\\right)$ is called the thermodynamic factor of diffusion coefficient. In a non-ideal mixing system: when the thermodynamic factor of diffusion coefficient > 0, the diffusion result causes the solute to ____; when the thermodynamic factor of diffusion coefficient < 0, the diffusion result causes the solute to ____. a. segregate b. concentration remains unchanged c. concentration tends to be uniform", + "answer": "c a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（a. segregate b. concentration remains unchanged c. concentration tends to be uniform）中选择正确的填空答案，符合选择题的特征。 | 知识层次: 题目涉及非理想混合系统中扩散系数的热力学因子及其对溶质扩散结果的影响，需要理解热力学因子的概念及其与扩散行为的关系，属于中等应用层次。需要将热力学因子与扩散结果联系起来进行分析，但不需要复杂的推理或综合运用。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度等级。题目要求考生不仅要理解扩散系数的热力学因子概念，还需要掌握非理想混合系统中热力学因子与扩散结果之间的关联。解题步骤涉及对热力学因子正负值的含义进行判断，并将其与溶质的扩散行为（偏聚或均匀化）联系起来。这种综合分析过程超出了简单概念记忆或单一知识点应用的范围，属于需要多步推理和概念关联的中等应用层次题目。" + }, + { + "idx": 3936, + "question": "Which of these elements would you expect to form a substitutional solid solution of incomplete solubility with copper? The elements are: Pd, Al, Cr, Fe, H, Pt, Ni, Zn, C, Ag, O, Co. The criteria for incomplete solubility are: these metals have either BCC or HCP crystal structures, and/or the difference between their atomic radii and that for Cu are greater than ±15%, and/or have a valence different than 2+.", + "answer": "Ag, Al, Co, Cr, Fe, and Zn form substitutional solid solutions of incomplete solubility. All these metals have either BCC or HCP crystal structures, and/or the difference between their atomic radii and that for Cu are greater than ±15%, and/or have a valence different than 2+.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素列表中选择符合特定条件的元素，属于从多个选项中选择正确答案的类型。答案明确列出了符合条件的元素，符合选择题的特征。 | 知识层次: 题目要求根据给定的元素和条件（晶体结构、原子半径差异、化合价）来判断哪些元素与铜形成不完全固溶体。这需要理解固溶体的形成条件，并能将这些条件应用到具体元素的分析中。虽然涉及多个知识点（晶体结构、原子半径、化合价），但主要是对这些条件的直接应用和综合分析，属于中等应用层次。 | 难度: 在选择题型中属于较高难度，需要综合应用多个材料科学概念（晶体结构、原子半径差异、化合价）进行判断。题目要求考生不仅掌握各元素的晶体结构类型，还需计算原子半径差异并分析化合价影响，涉及多步复杂分析过程。正确选项需要同时满足多个条件，属于复杂分析过程的判断题型。" + }, + { + "idx": 3238, + "question": "The main mechanism of high-temperature recovery is A. Dislocation slip and cross-slip B. Dislocation climb and polygonization C. Polygonization and subgrain coalescence D. Bulge nucleation and subgrain coalescence", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对高温回复机制的理解和应用，需要将多个概念（位错攀移和多边化）关联起来进行分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解高温回复的主要机制，还需要区分多个相似但不同的概念（如位错滑移、交叉滑移、位错攀移、多边形化等）。解题过程涉及综合分析多个材料科学原理，并准确关联到高温回复的具体机制。此外，选项中的术语和概念需要较深的理解才能正确判断，属于中等应用层次的多步分析和概念关联题目。" + }, + { + "idx": 4491, + "question": "An alternating copolymer is known to have a number-average molecular weight of 250,000g / mol and a degree of polymerization of 3420 . If one of the repeat units is styrene, which of ethylene, propylene, tetrafluoroethylene, and vinyl chloride is the other repeat unit? ", + "answer": "propylene", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项（ethylene, propylene, tetrafluoroethylene, and vinyl chloride）中选择正确的另一个重复单元，符合选择题的特征。 | 知识层次: 题目需要计算分子量并分析共聚物的结构，涉及多步计算和概念关联。首先需要理解数均分子量和聚合度的关系，然后通过计算确定重复单元的分子量，最后根据选项中的单体分子量进行匹配。这需要中等程度的认知能力和综合分析。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算（如分子量计算、重复单元推断）、概念关联（如共聚物结构、单体分子量）以及综合分析（排除法判断正确单体）。虽然提供了正确选项，但解题过程涉及多个知识点的综合应用和较复杂的逻辑推理，超出了基础选择题的范畴。" + }, + { + "idx": 3558, + "question": "In cubic crystals, the (110) and (211) planes belong to the same () zone.", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（D） | 知识层次: 题目需要理解立方晶体中晶面属于同一晶带的条件，并应用晶带轴的概念进行分析。虽然不涉及复杂计算，但需要将多个概念关联起来进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 3787, + "question": "Which of these alloying elements is expected to have unlimited solid solubility in copper? (a) Au (b) Mn (c) Sr (d) Si (e) Co", + "answer": "(a)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案，具有明确的选择项和单一正确答案特征 | 知识层次: 题目考查对固溶度概念的理解以及合金元素与铜的相互作用，需要综合分析原子尺寸、电负性、晶体结构等因素来判断固溶度，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要综合运用材料科学中的固溶度概念、Hume-Rothery规则以及元素周期表知识。解题过程涉及多步分析：1) 理解铜的晶体结构(FCC) 2) 掌握Hume-Rothery规则的四个条件(原子尺寸差、电负性、价电子数、晶体结构) 3) 对各选项元素进行系统比较。特别是需要判断金(Au)与铜的相似性，这需要较深入的材料学知识而非简单记忆。虽然题目形式是选择题，但解题所需的综合分析过程使其难度高于基础概念题。" + }, + { + "idx": 1816, + "question": "In the phase diagram of a ternary condensed system, if there are n boundary lines, the number of connection lines in this phase diagram must be a. (n+1) lines b. (n-1) lines c. n lines d. none", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目涉及三元相图中边界线和连接线数量的关系，需要理解相图的基本原理并应用相关规则进行推理判断，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解三元相图中边界线与连接线的关系，并进行综合分析判断。题目涉及多步计算和概念关联，要求考生具备较强的相图分析能力和空间想象能力。虽然给出了具体选项，但需要考生对相图结构有深入理解才能正确选择。" + }, + { + "idx": 3242, + "question": "When polycrystalline metal is heated to a relatively high temperature and held, the grains will grow. The grain growth mode is A. Subgrain coalescence and growth B. Grain boundary bowing outward and growth C. Grain boundary moving toward the curvature center D. Movement of Y junctions", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对晶粒生长模式的理解，需要将晶界移动与曲率中心的关系进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，此题属于较高难度。题目涉及多晶金属在高温下的晶粒生长机制，需要考生理解晶界移动的物理机制（如曲率驱动迁移）并综合分析不同生长模式的区别。正确选项C要求考生掌握晶界向曲率中心移动这一非直观概念，并能排除其他看似合理的干扰选项（如亚晶合并或Y结移动）。这需要将材料科学基础理论与实际现象关联，属于中等应用层次的多步分析判断。" }, { "idx": 3952, @@ -717,6 +20121,3330 @@ "knowledge_level_name": "中等应用", "difficulty": 4, "final_level": "Level_4", - "reasoning": "题型: 题目要求从多个选项中选择一个合理的扩散系数值，并基于扩散系数的温度依赖性进行判断。答案形式为从给定的选项中选择最合适的答案。 | 知识层次: 题目要求理解扩散系数与温度的数学关系，并基于此进行合理推断。虽然不需要具体计算，但需要理解温度对扩散系数的指数影响，并能够排除不符合温度依赖关系的选项。这涉及到多步推理和概念关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解扩散系数的温度依赖性（阿伦尼乌斯方程），并能够基于温度变化对扩散系数的影响进行合理推断。题目要求考生不仅知道扩散系数随温度升高而增加，还需要判断增加的幅度（指数关系导致超过线性增长）。此外，需要排除多个干扰选项，综合分析能力要求较高。" + "reasoning": "题型: 题目要求从给定的选项中选择一个合理的扩散系数值，并基于扩散系数的温度依赖性进行判断。答案通过排除法选择了正确的选项。 | 知识层次: 题目要求基于扩散系数的温度依赖性进行合理推断，需要理解扩散系数与温度的指数关系，并能够应用这一知识进行逻辑推理，排除不合理的选项。这涉及多步思维过程和对概念的综合应用，但不需要复杂的计算或深度机理分析。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。首先，考生需要理解扩散系数与温度的指数依赖关系，并能够推断温度升高会导致扩散系数增加。其次，考生需要排除不符合这一基本趋势的选项（a, b, d, f）。最后，考生需要进一步判断扩散系数的增加幅度是否超过线性比例（温度加倍时扩散系数的增加是否超过两倍），从而在剩余选项（c, e）中做出正确选择。这一过程涉及多步逻辑推理和对温度依赖关系的深入理解，因此在选择题型中属于较高难度。" + }, + { + "idx": 3080, + "question": "When designing fiber-reinforced composites, for a matrix with lower toughness, the coefficient of expansion of the fiber can be what? A. Slightly lower B. Very different C. Slightly higher D. The same", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案 | 知识层次: 题目涉及复合材料设计中纤维与基体热膨胀系数的匹配问题，需要理解材料性能之间的相互作用关系，并做出适当选择。这属于中等应用层次，需要将材料性能知识应用于具体设计情境中，但不需要复杂的计算或深度分析。 | 难度: 在选择题型中，该题目属于较高难度。题目要求考生不仅理解纤维增强复合材料的基本概念，还需要掌握基体韧性与纤维膨胀系数之间的复杂关系。解题过程需要综合分析材料性能的匹配原则，并判断在特定条件下（基体韧性较低时）纤维膨胀系数的合理选择。这超出了简单记忆或单一概念应用的范畴，属于需要多步推理和综合分析的选择题。" + }, + { + "idx": 2938, + "question": "After welding A and A-B alloy, the Kirkendall effect occurs, and the interface is measured to move towards the A sample. Then (A) The diffusion rate of component A is greater than that of component B (B) The opposite of (A) (C) The diffusion rates of components A and B are the same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项（A）、（B）、（C）中选择正确答案 | 知识层次: 题目考查Kirkendall效应的应用，需要理解扩散速率差异对界面移动方向的影响，涉及概念关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题中属于较高难度，需要理解Kirkendall效应的基本原理，并能将界面移动方向与扩散速率差异进行关联分析。题目要求考生不仅掌握扩散概念，还需要进行逆向推理（从界面移动方向反推扩散速率关系），涉及多步逻辑推理和概念的综合应用。" + }, + { + "idx": 3786, + "question": "Suppose 1 at% of the following elements is added to copper (forming a separate alloy with each element) without exceeding the solubility limit. Which one would be expected to give the higher strength alloy? (a) Au (b) Mn (c) Sr (d) Si (e) Co", + "answer": "(c)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项（a-e）中选择一个预期能提供更高强度合金的元素，符合选择题的特征。 | 知识层次: 题目要求考生理解合金元素对铜强度的影响，并能够比较不同元素的强化效果。这需要考生掌握固溶强化的基本原理，并能够将不同元素的特性（如原子尺寸、电负性等）与强化效果联系起来。虽然不涉及复杂的计算或多步骤推理，但需要对概念进行综合应用和分析。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。需要考生：" + }, + { + "idx": 3785, + "question": "Is any of the alloying elements expected to have unlimited solid solubility in copper? For copper: r_Cu=1.278 Å (a) Au: r=1.442, φr=+12.8% (b) Mn: r=1.12, φr=-12.4% (c) Sr: r=2.151, φr=+68.3% (d) Si: r=1.176, φr=-8.0% (e) Co: r=1.253, φr=-2.0%", + "answer": "The Cu-Au alloy satisfies Hume-Rothery's conditions and might be expected to display complete solid solubility-in fact it freezes like an isomorphous series of alloys, but a number of solid-state transformations occur at lower temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择哪个合金元素在铜中具有无限固溶度，答案也明确指出了符合Hume-Rothery条件的选项 | 知识层次: 题目需要应用Hume-Rothery规则（包括原子半径差、电负性、价电子浓度等）来分析合金元素在铜中的固溶度，涉及多步判断和综合分析。虽然规则本身是基础概念，但需要将多个条件结合起来进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。题目要求考生不仅掌握Hume-Rothery规则的基本概念（如原子半径差、电负性、价电子浓度等），还需要能够将这些规则应用到具体的合金系统中（Cu-Au）。此外，题目还涉及对多个选项的分析和比较，需要考生进行多步计算（如原子半径差百分比的计算）和综合判断。虽然题目提供了具体数据，但要求考生能够将这些数据与理论规则关联起来，并做出正确的判断。因此，该题目在选择题型中属于较高难度等级。" + }, + { + "idx": 4092, + "question": "For a fibrous composite with fibers that are randomly and uniformly oriented within a specific plane, when a stress is applied in any direction within the plane of the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d) \\frac{3}{4}(e) 1", + "answer": "For a fibrous composite with fibers that are randomly and uniformly oriented within a specific plane,when a stress is applied in any direction within the plane of the fibers, the reinforcement efficiency is \\frac{3}{8}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目涉及复合材料中纤维增强效率的计算，需要理解纤维随机分布时的力学行为，并应用相关公式进行计算。虽然不涉及复杂的多步计算或深度推理，但需要将概念与具体情境关联，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解纤维增强复合材料中纤维取向与应力方向的关系，并进行多步计算和综合分析。题目涉及中等应用层次的知识，要求考生能够将多个概念关联起来，并正确计算出增强效率。" + }, + { + "idx": 4749, + "question": "A cylindrical rod 500mm (20.0 in.) long and having a diameter of 12.7mm (0.50 in.) is to be subjected to a tensile load of 29,000 N (6500 lb). Which of the four metals or alloys listed in the table can experience neither plastic deformation nor an elongation of more than 1.3mm (0.05 in.)?", + "answer": "Of the four metal alloys listed, only brass and steel satisfy the stipulated criteria. Brass has an elongation of 1.15 mm, and steel has an elongation of 0.56 mm, both of which are less than the maximum allowed elongation of 1.3 mm.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从四个金属或合金中选择满足特定条件的材料，答案明确指出了符合条件的选项，符合选择题的特征。 | 知识层次: 题目要求考生在给定的条件下，通过计算和比较多个金属或合金的性能参数（如塑性变形和伸长量），来判断哪些材料满足特定的工程要求。这涉及到多步计算（如应力、应变的计算）和综合分析（比较不同材料的性能），属于中等应用层次。虽然不涉及复杂的机理分析或创新设计，但需要考生能够关联多个概念并进行综合判断。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生进行多步计算，包括应力、应变和伸长量的计算。其次，需要考生综合分析材料性能表格中的数据，并将计算结果与题目要求进行比较。此外，题目还涉及塑性变形和弹性变形的概念理解，要求考生能够将理论知识与实际应用相结合。虽然题目提供了正确选项，但解题过程较为复杂，需要较强的综合分析能力和计算能力，因此在选择题型中属于等级4的难度。" + }, + { + "idx": 2723, + "question": "Assume there is an edge dislocation with Burgers vector b in the [0-10] direction gliding along the (100) plane. If another edge dislocation with Burgers vector in the [010] direction moves through the (001) plane, will this dislocation form a kink or a jog when passing through the aforementioned dislocation?", + "answer": "Kink", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两个选项（kink或jog）中选择正确答案 | 知识层次: 题目需要理解位错的基本概念（如Burgers向量和滑移面），并能够分析两种不同位错相互作用时的行为。这涉及到多个概念的关联和综合分析，但不需要复杂的推理或创新应用。 | 难度: 在选择题型中，这道题目属于较高难度，需要考生综合运用位错理论中的多个概念（Burgers矢量、滑移面、割阶与扭折的形成机制）并进行空间几何关系的判断。具体来说：" + }, + { + "idx": 3993, + "question": "How does deformation by drawing of a semicrystalline polymer affect its tensile strength?(a) Increases(b) Decreases", + "answer": "Deformation by drawing increases the tensile strength of a semicrystalline polymer. This effect is due to the highly oriented chain structure that is produced by drawing, which gives rise to higher interchain secondary bonding forces.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的选项(a)和(b)中选择正确答案 | 知识层次: 题目需要理解半结晶聚合物在拉伸变形过程中的微观结构变化（链取向）及其对宏观性能（拉伸强度）的影响机制，涉及概念关联和综合分析能力 | 难度: 在选择题中属于较高难度，需要理解半晶态聚合物在拉伸变形过程中的微观结构变化（如分子链取向）及其对宏观力学性能（拉伸强度）的影响机制。这涉及材料科学中的晶体学原理、聚合物加工-结构-性能关系等中等应用层次的知识，并要求考生能够综合分析变形工艺与性能提升之间的因果关系。虽然题目形式为二选一，但正确选项的解释涉及多步逻辑推导和概念关联，超出了基础记忆题的范畴。" + }, + { + "idx": 3910, + "question": "Rhodium has an atomic radius of 0.1345nm, a density of (12.41g / {cm}^{3}) and an atomic weight of 102.91 \\mathrm{g} / mol. What is rhodium's crystal structure?(a) Simple cubic(b) \\mathrm{BCC}(c) \\mathrm{FCC}", + "answer": "the crystal structure for rhodium is \\mathrm{fcc}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项(a) Simple cubic、(b) BCC、(c) FCC中选择正确答案 | 知识层次: 题目需要根据给定的原子半径、密度和原子重量，通过多步计算和综合分析来确定晶体的结构。这涉及到对晶体结构类型的基本理解，以及如何将这些参数与理论值进行比较的能力。虽然不涉及复杂的推理或创新应用，但需要一定的计算和概念关联能力。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生掌握原子半径、密度、原子重量与晶体结构之间的关系。其次，解题过程涉及多步计算，包括计算单位晶胞中的原子数、晶胞体积等，并需要将这些计算结果与不同晶体结构（SC、BCC、FCC）的理论值进行比较。此外，题目还要求考生能够正确应用相关公式和概念，综合分析计算结果才能得出正确答案。因此，该题目在选择题型内属于复杂分析过程的判断，难度等级为4。" + }, + { + "idx": 3595, + "question": "Indium has a tetragonal structure with a_{0}=0.32517nm and c_{0}=0.49459nm. The density is 7.286g / {cm}^{3} and the atomic weight is 114.82g / mol. Does indium have the simple tetragonal or body-centered tetragonal structure?", + "answer": "body-centered tetragonal structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两种晶体结构（simple tetragonal或body-centered tetragonal）中选择正确的答案，属于二选一的选择题。 | 知识层次: 题目需要应用晶体结构的基本知识，进行多步计算（如计算单位晶胞中的原子数），并结合密度和原子量等参数进行综合分析，以确定铟的晶体结构类型。这涉及到多个概念的关联和一定的计算过程，属于中等应用层次。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。解题需要以下多步计算和概念关联：" + }, + { + "idx": 742, + "question": "Ionic crystals usually reduce their surface energy through the polarization deformation and rearrangement of surface ions. Among the following ionic crystals, the one with the smallest surface energy is (a) $\\\\mathrm{CaF}{2}$ (b) $\\\\mathrm{Pb}\\\\mathrm{F}{2}$ c) $\\\\mathrm{Pb}\\\\mathbf{I}{2}$ (d) $\\\\mathbf{BaSO{4}}$ (e) SrsO4", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案 | 知识层次: 题目要求考生理解离子晶体表面能的概念，并能够分析不同离子晶体的极化变形和离子重排对表面能的影响。这需要考生将多个概念（如离子极化、离子半径、晶格能等）进行关联和综合分析，属于中等应用层次。 | 难度: 在选择题型中属于较高难度，需要综合理解离子晶体表面能的影响因素（如离子极化率、晶格能等），并比较不同化合物的离子特性（如PbI2中I-的大离子半径和高极化率导致表面能显著降低）。解题过程涉及多个概念的综合分析（极化效应、离子半径、晶格类型）以及化合物性质的横向比较，超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 2922, + "question": "In cubic crystals, the (110) and (211) planes belong to the same zone axis.", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（D） | 知识层次: 题目需要理解立方晶体中晶面与晶带轴的关系，并能够判断不同晶面是否属于同一晶带轴。这涉及到对晶体几何学基本原理的应用，以及综合分析不同晶面指数的关系，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。需要掌握立方晶体中晶面指数和晶带轴的概念，并能进行多步计算和综合分析。题目要求判断(110)和(211)晶面是否属于同一晶带轴，这需要运用晶带定律进行计算验证，涉及多个概念的综合应用和较复杂的分析过程。在选择题型内，这种需要多步计算和概念关联的题目相对难度较高。" + }, + { + "idx": 3569, + "question": "The relationship between the probability of annealing twin formation and the stacking fault energy of a crystal is ( ). \\n\\nA. Unrelated, only depends on annealing temperature and time\\nB. Crystals with low stacking fault energy have a higher probability of forming annealing twins\\nC. Crystals with high stacking fault energy have a higher probability of forming annealing twins", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查堆垛层错能与退火孪晶形成概率之间的关系，需要理解晶体缺陷和变形机制的基本原理，并进行概念关联和综合分析。虽然不涉及复杂计算，但需要对材料科学中的晶体结构和缺陷行为有较深入的理解。 | 难度: 在选择题中属于较高难度，需要理解晶体堆垛层错能与退火孪晶形成概率之间的关系，并进行综合分析判断。题目涉及中等应用层次的知识，要求考生能够关联多个概念（堆垛层错能、退火孪晶形成机制）并做出正确选择。虽然题目提供了明确选项，但正确解答需要对材料科学中的晶体缺陷行为有较深入的理解，属于复杂分析过程的判断。" + }, + { + "idx": 697, + "question": "Ionic crystals typically reduce their surface energy through the polarization deformation and rearrangement of surface ions. Among the following ionic crystals, the one with the smallest surface energy is (a) CaF2 (b) PbF2 (c) PbI2 (d) BaSO4 (e) SrSO4", + "answer": "The main reasons for clay charging are: (11) _, (12) _, and (13) _", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择具有最小表面能的离子晶体，符合选择题的特征 | 知识层次: 题目要求考生理解离子晶体的表面能概念，并能够分析不同离子晶体的极化变形和离子重排对表面能的影响。这需要考生综合运用材料科学中的晶体结构和表面能相关知识，进行中等程度的分析和比较。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。题目要求考生理解离子晶体表面能的影响因素，包括极化变形和表面离子重排等概念，并能综合分析不同离子晶体的性质（如离子半径、极化能力、晶格结构等）来比较表面能大小。这需要考生具备较深的知识掌握和综合分析能力，超出了简单概念记忆或单一知识点的应用水平。" + }, + { + "idx": 4000, + "question": "How would the plane strain fracture toughness of a metal be expected to change with rising temperature?(a) Increase(b) Decrease(c) Remain constant", + "answer": "The magnitude of the plane strain fracture toughness, K_{i c}, diminishes with decreasing temperature; therefore as temperature increases, K_{i c}, should also increase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目需要理解平面应变断裂韧性与温度变化的关系，并应用相关知识进行推理分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解金属的平面应变断裂韧性（K_{ic}）与温度变化的关系这一概念，并能够综合分析温度升高对材料性能的影响。虽然题目涉及的知识点较为专业，但选项明确，不需要复杂的计算过程，属于多概念综合选择的范畴。" + }, + { + "idx": 3087, + "question": "When designing fiber composites, for a matrix with good plasticity, how can the coefficient of expansion of carbon fiber be? A. Slightly lower B. Very different C. Slightly higher D. The same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 3, + "final_level": "Level_3", + "reasoning": "题型: 题目要求从选项（A. Slightly lower B. Very different C. Slightly higher D. The same）中选择正确答案 | 知识层次: 题目要求在设计纤维复合材料时，考虑基体塑性和碳纤维膨胀系数的匹配关系，需要理解材料性能之间的相互作用并进行综合分析，属于中等应用层次。 | 难度: 在选择题中属于中等难度，需要理解复合材料设计中基体塑性与纤维膨胀系数的匹配关系，并进行概念关联分析。题目考察的是对材料性能协调性的综合判断能力，但不需要复杂的计算过程。" + }, + { + "idx": 1229, + "question": "Iron-carbon alloy equilibrium phase diagram: (1) Contains peritectic transformation. (2) Contains eutectic transformation. (3) Contains congruent transformation. (4) Contains monotectic transformation. (5) Contains precipitation transformation of solid solution.", + "answer": "(1)(2)(3)(5)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的陈述组合，符合选择题的特征 | 知识层次: 题目考查对铁碳合金平衡相图中不同类型转变的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题中属于较高难度，需要深入理解铁碳合金相图中的多种相变类型（包晶、共晶、同成分、析出等），并能准确区分和识别这些概念。题目要求考生不仅记忆相变类型，还需辨析不同相变的特征及其在相图中的表现，涉及多个知识点的综合应用。" + }, + { + "idx": 703, + "question": "In the phase transformation of quartz, the one that belongs to reconstructive transformation is (a) $\\\\alpha\\\\cdot$ quartz $=====\\\\alpha\\\\cdot$ tridymite (b) $\\\\alpha\\\\cdot$ quartz $\\\\mathbf{\\\\mu}=====\\\\beta\\\\mathbf{\\\\sigma}$ quartz (c) $\\\\alpha\\\\cdot$ tridymite $=====\\\\alpha\\\\cdot$ quartz (d) $\\\\alpha\\\\cdot$-cristobalite $\\\\begin{array}{r}{======\\\\beta.}\\\\end{array}$ cristobalite", + "answer": "Intrinsic diffusion is the migration of particles caused by (22), and the activation energy of intrinsic diffusion consists of two parts: (23) and (24). The relationship between the diffusion coefficient and temperature is given by: (25).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 3, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案，属于选择题类型 | 知识层次: 题目考查石英相变类型的基本概念记忆，特别是重构型相变的识别，属于基础概念的记忆和理解范畴。 | 难度: 在选择题中属于较高难度，需要理解石英相变中的重构型转变（reconstructive transformation）和位移型转变（displacive transformation）的区别，并能正确识别具体相变类型。题目涉及多个石英变体的相变过程，需要考生对每种相变的特点有深入理解才能做出正确选择。" + }, + { + "idx": 3994, + "question": "How does increasing the degree of crystallinity of a semicrystalline polymer affect its tensile strength?(a) Increases\n\\mathrm{b}) Decreases", + "answer": "Increasing the degree of crystallinity of a semicrystalline polymer leads to an increase in its tensile strength. This is due to enhanced interchain bonding and forces in crystalline regions; in response to applied stresses, interchain motions become more restrained as degree of crystallinity increases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了多个选项（a和b）供选择，并最终给出了一个明确的选项作为正确答案。 | 知识层次: 题目考查对半结晶聚合物结晶度与拉伸强度关系的直接应用，属于基本概念的直接套用，不需要复杂的分析或多步推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用关于结晶度对聚合物拉伸强度影响的基本概念即可作答。题目不涉及复杂计算或公式变形，仅需理解结晶度增加会增强分子间作用力从而提高拉伸强度这一基本原理。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 3062, + "question": "What material is suitable for steam turbine blades? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramics D.Manganese brass", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择最适合蒸汽涡轮叶片的材料，答案形式为选项中的一个字母 | 知识层次: 题目考查对特定应用场景下材料选择的基本知识，需要理解不同材料的特性和适用环境，但不需要复杂的分析或综合推理。 | 难度: 在选择题中属于简单难度，题目直接考察对蒸汽轮机叶片材料的基本知识，只需识别2Cr13是适合的材料，无需复杂计算或多步骤推理。" + }, + { + "idx": 4133, + "question": "Which of the following 1kg samples is expected to change temperature the least if 100kJ of heat is perfectly transferred to each of them at a constant pressure of 1 atmosphere. The initial temperature of each specimen is 25^{\\circ} C. (a) Aluminum (b) Copper (c) Gold (d) Borosilicate Glass (e) Polystyrene", + "answer": "polystyrene will experience the smallest temperature change.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个预期温度变化最小的材料，属于典型的选择题形式。 | 知识层次: 题目需要应用比热容的基本概念和简单计算来确定不同材料在相同热量输入下的温度变化。虽然涉及多个材料的比热容值，但主要考察的是对这些数值的直接应用和比较，不需要复杂的分析或推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用比热容公式（Q=mcΔT）并比较不同材料的比热容值即可得出答案。解题步骤单一，无需公式变形或多步骤计算，属于基础概念的直接应用。" + }, + { + "idx": 2981, + "question": "According to the Clausius-Clapeyron equation, as pressure increases, the temperature at which Y-Fe transforms into $\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}\\\\mathsf{\\\\Gamma}$", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案（答案：B），符合选择题的特征 | 知识层次: 题目考查Clausius-Clapeyron方程的基本应用，需要理解方程的含义并直接套用公式来判断温度变化趋势，属于简单应用层次。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用Clausius-Clapeyron方程的基本公式，无需进行公式变形或多步骤计算。题目要求考生根据压力增加对相变温度的影响做出简单判断，属于基础知识的直接应用，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 1748, + "question": "During liquid-solid phase transformation, the heterogeneous nucleation barrier is related to the contact angle θ. When , the heterogeneous nucleation barrier is reduced by half compared to the homogeneous nucleation barrier. a.θ=0° b.θ=45° c.θ=90° d.θ=180°", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对异质成核能垒与接触角关系的理解，需要应用基本公式和概念进行简单计算和判断，属于直接套用知识点的范畴。 | 难度: 在选择题型中，该题目属于简单难度。题目直接考察对异质形核能垒与接触角关系的理解，只需应用基本公式即可得出答案。解题步骤简单，无需复杂计算或公式变形，属于直接套用知识点的类型。" + }, + { + "idx": 3958, + "question": "A cylindrical rod 380mm (15.0 in.) long and having a diameter of 10.0mm (0.40 in.), is to be subjected to a tensile load of 24,500 N (5500 lbf). Which of the four metals or alloys listed below will not experience plastic deformation under this load? The materials are: Aluminum alloy (Yield Strength: 255 MPa), Brass alloy (Yield Strength: 345 MPa), Copper (Yield Strength: 250 MPa), Steel alloy (Yield Strength: 450 MPa).", + "answer": "The materials that will not experience plastic deformation under the load of 24,500 N are the Brass alloy and Steel alloy, as their yield strengths (345 MPa and 450 MPa, respectively) are greater than the applied stress.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个金属或合金选项中选择不会发生塑性变形的材料，符合选择题的特征 | 知识层次: 题目要求应用基本的应力计算公式（应力=力/面积）来判断材料是否会发生塑性变形，属于直接套用公式和简单计算的范畴，不需要多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（应力=力/面积）计算应力，并与给定材料的屈服强度进行比较。解题步骤简单直接，无需公式变形或多步骤选择，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 2961, + "question": "In the hexagonal crystal system, the interplanar spacing of $(11\\\\overline{2}0)$ is $(10\\\\overline{1}0)$ interplanar spacing.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（A） | 知识层次: 题目考查六方晶系中间距的计算，需要应用基本的晶体学公式，属于简单应用层次。虽然需要理解晶面指数的含义，但计算过程直接，不涉及多步计算或综合分析。 | 难度: 在选择题中属于简单难度，题目直接要求应用六方晶系的面间距公式进行计算，无需复杂变形或多步骤选择，仅需基本公式选择和简单计算即可得出答案。" + }, + { + "idx": 4093, + "question": "For a fibrous composite with fibers that are uniformly distributed and randomly oriented in all directions, when a stress is applied in any direction, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{{ }_{5}}(c) \\frac{3}{8}(d) \\frac{3}{{ }_{4}}(e) 1", + "answer": "For a fibrous composite with fibersthat are uniformly distributed and randomly oriented in all directions, when a stress is applied in any direction, the reinforcement efficiency is 1 / 5.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)-(e)中选择关于纤维增强复合材料增强效率的正确答案 | 知识层次: 题目考查对纤维复合材料增强效率的基本理解和简单应用，需要记忆随机取向纤维的增强效率值，并选择正确的选项。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式或概念即可得出答案。题目明确给出了纤维复合材料在随机取向情况下的增强效率，学生只需记忆或简单应用这一知识点即可选择正确答案，无需进行复杂的计算或变形。因此，在选择题型内属于较低难度。" + }, + { + "idx": 2754, + "question": "In the hexagonal crystal system, the interplanar spacing of (11-20) plane is (1010) plane spacing.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查六方晶系中晶面间距的计算，属于基本公式的直接应用，无需多步计算或综合分析。 | 难度: 在选择题型中，该题目属于简单难度。题目直接考察六方晶系中晶面间距的基本公式应用，只需正确选择并套用公式即可得出答案，无需复杂计算或变形步骤。知识层次为简单应用，符合等级2的标准。" + }, + { + "idx": 2979, + "question": "In the ionic compound $\\\\mathbf{MgO}$, the cation most likely to replace $\\\\mathbf{Mg}^{2+}$ in the compound (given the radii (nm) of each cation: (${\\\\bf Mg}^{2+}$) 0.066, ($\\\\mathbb{C}a^{2+}$) 0.099, ($\\\\mathrm{Li^{+}}$) 0.066, ($\\\\mathbf{Fe}^{\\\\mathbf{2+}}$) 0.074) is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的多个选项中选择最可能替换Mg2+的阳离子，答案以选项形式给出（C），符合选择题的特征。 | 知识层次: 题目考查离子半径数据的直接应用，需要根据给定的离子半径数据选择最可能替换Mg²⁰的阳离子。虽然涉及离子半径的概念，但主要是简单的数据比较和选择，不需要复杂的分析或推理。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接比较给定离子半径数据并选择最接近Mg²⁰半径的选项（Ca²⁺）。无需复杂计算或公式变形，属于基础概念的直接应用。" + }, + { + "idx": 4130, + "question": "To what temperature would 23.0kg of some material at 100^{\\circ} C be raised if 255kJ of heat is supplied? Assume a C_{p} value of 423 J/ kg-K for this material.\n(A) 26.2^{\\circ} C\n(B) 73.8^{\\circ} C\n(C) 126^{\\circ} C\n(D) 152^{\\circ} C", + "answer": "the final temperature is 126^{\\circ} C, which corresponds to answer C.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了四个选项（A、B、C、D）并给出了最终答案对应的选项。 | 知识层次: 题目涉及基本的热力学公式应用（Q = mC_pΔT），只需要直接套用公式进行简单计算即可得出答案，不需要多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（Q = m*Cp*ΔT）并进行简单计算即可得出答案。解题步骤清晰且直接，无需公式变形或多步骤推理，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 4005, + "question": "A plate of an alloy steel has a plane-strain fracture toughness of 50 MPa·{m}^{1 / 2}. If it is known that the largest surface crack is 0.5mm long, and that the value of Y is 1.1 , which of the following can be said about this plate when a tensile stress of 1200 MPa is applied?(a) The plate will definitely fracture.(b) The plate will definitely not fracture. c) It is not possible to determine whether or not the plate will fracture.", + "answer": "the plate will definitely fracture.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（a）、（b）、（c）中选择正确答案，符合选择题的特征。 | 知识层次: 题目主要考查对断裂韧性公式的直接应用，涉及基本公式的套用和简单计算，不需要复杂的分析或推理过程。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需直接套用基本公式（断裂韧性公式）并进行简单计算即可得出答案。解题步骤明确且直接，无需公式变形或多步骤推理，符合等级2的简单公式选择和应用标准。" + }, + { + "idx": 4131, + "question": "A rod of some material 0.50{m} long elongates 0.40mm on heating from 50^{\\circ} C to 151^{\\circ} C. What is the value of the linear coefficient of thermal expansion for this material?\n(A) 5.30 × 10^{-6}\\left({ }^{\\circ} C\\right)^{-1}\n(B) 7.92 × 10^{-6}\\left({ }^{\\circ} C C\\right)^{-1}\n(C) 1.60 × 10^{-5}\\left({ }^{\\circ} C\\right)^{-1}\n(D) 1.24 × 10^{-6}\\left({ }^{\\circ} C_{-}^{1}\\right.", + "answer": "the linear coefficient of thermal expansion for this material is 7.92 × 10^{-6} \\left(^{\\circ}c\\right)^{-1}, which is answer b.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的线性热膨胀系数值，并且提供了多个选项供选择 | 知识层次: 题目考查的是线性热膨胀系数的基本公式应用，只需要套用公式进行简单计算即可得出答案，不涉及多步计算或复杂分析。 | 难度: 在选择题型中，该题目属于简单难度。题目仅需要直接套用线性热膨胀系数的基本公式，并进行简单的数值计算。解题步骤不涉及公式变形或多步骤选择，仅需正确识别和应用公式即可得出答案。因此，在选择题型内属于等级2的简单公式选择和应用难度。" + }, + { + "idx": 4031, + "question": "An intermetallic compound is found in the magnesium-gallium system that has a composition of 41.1 wt% Mg - 58.9 wt% Ga. Specify the formula for this compound.(a) MgGa (b) Mg_{2} \\mathrm{Ga} (c) \\mathrm{MgGa}_{2} (d) Mg_{3} \\mathrm{Ga}_{2}", + "answer": "(b) Mg_{2}Ga", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "simple_application", + "knowledge_level_name": "简单应用", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的化学式，符合选择题的特征 | 知识层次: 题目要求根据给定的重量百分比计算化合物的化学式，涉及基本的原子量计算和简单应用，不需要复杂的分析或综合能力。 | 难度: 在选择题型中，该题目属于简单应用层次，仅需基本公式应用和简单计算即可得出正确答案。题目直接给出了组成百分比，要求选择正确的化学式，解题步骤较为直接，无需复杂变形或多步骤推理。因此，在选择题型内属于较低难度等级。" + }, + { + "idx": 3022, + "question": "Comparison of mechanical properties, the (1) of polymers is better than that of metal materials. A. Stiffness B. Strength C. Impact strength (toughness) D. Specific strength", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物和金属材料机械性能基本概念的对比记忆，属于基础概念的记忆和理解。 | 难度: 该题目属于基础概念记忆层次，但需要考生理解\"specific strength\"的定义（强度与密度之比）并能与金属材料进行简单比较。虽然不涉及复杂分析，但比单纯记忆定义略高一个难度层次，属于概念理解和简单辨析级别。" + }, + { + "idx": 3011, + "question": "To which category of compounds do nylon and polysulfone belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物分类的基本概念记忆，只需要知道尼龙和聚砜属于杂链有机聚合物即可回答，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（有机聚合物的分类），但需要学生理解并区分\"碳链有机聚合物\"和\"杂链有机聚合物\"这两个概念。学生需要知道尼龙和聚砜的分子结构特点（含有杂原子），才能正确选择\"杂链有机聚合物\"这个选项。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析过程（等级3）。" + }, + { + "idx": 4119, + "question": "Which of the following materials are typically used as stabilizers in transformation-toughened ceramic-matrix composites?(a) \\mathrm{CaO}(b) MgO(c) \\mathrm{Y}_{2} \\mathrm{O}_{3}(d) \\mathrm{CeO}(e) \\mathrm{Al}_{2} \\mathrm{O}_{3}(f) \\mathrm{SiC}", + "answer": "(\\mathrm{CaO}, MgO, \\mathrm{Y}_{2} \\mathrm{O}_{3}, and \\mathrm{CeO} are typically used as stabilizers in transformation-toughened ceramicmatrix composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的多个选项中选择出正确的材料作为稳定剂，符合选择题的特征 | 知识层次: 题目考查对特定材料在陶瓷基复合材料中作为稳定剂的基础知识记忆，属于基础概念的记忆和理解层面。 | 难度: 该题目属于基础概念记忆类型，要求考生识别并记忆哪些材料通常用作相变增韧陶瓷基复合材料的稳定剂。虽然选项较多（6个），但正确选项明确且属于常见稳定剂（CaO, MgO, Y2O3, CeO），只需简单记忆即可作答，无需复杂分析或深度理解。在选择题型中属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 2946, + "question": "When most of the latent heat of crystallization can be dissipated through the liquid phase during ingot solidification, the main solid microstructure is (A) dendritic crystal (B) columnar crystal (C) spherulite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个选项（A、B、C）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对凝固过程中微观结构形成的基本概念的理解和记忆，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆层次，考察学生对凝固过程中微观组织形成的理解。虽然需要知道不同晶体结构（枝晶、柱状晶、球晶）的形成条件，但题目已经明确给出了关键条件（潜热通过液相散失），只需将这一条件与枝晶形成对应起来即可。相比纯粹的定义记忆题（等级1），此题需要一定的概念理解和简单辨析能力，但不需要复杂的分析或深度推理（等级3）。" + }, + { + "idx": 3902, + "question": "On the basis of this result what type of interatomic bonding would you expect to be found in TiAl3 ? (a) van der Waals (b) ionic (c) metallic (d) covalent", + "answer": " (c)metallic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项（a-d）中选择一个正确的答案，符合选择题的特征。 | 知识层次: 题目考查对金属间化合物TiAl3中原子间键合类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（金属键的类型），但需要学生理解TiAl3的组成元素特性（钛和铝都是金属元素），并能推断出金属键是主要键合类型。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较多个概念（等级3）。" + }, + { + "idx": 1232, + "question": "Austenite in steel: \\n\\n(1) Can be represented as a $\\upgamma$-solid solution with dissolved carbon atoms. \\n\\n(2) Can be represented as an $\\alpha$-solid solution with dissolved carbon atoms. \\n(3) Exhibits good plasticity both at room temperature and high temperatures. \\n(4) Has ferromagnetism. \\n(5) Has paramagnetism.", + "answer": "(1) (3)(5)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的陈述，答案形式为选择特定编号的选项，符合选择题的特征 | 知识层次: 题目考查对奥氏体（Austenite）基本特性的记忆和理解，包括其晶体结构（γ-固溶体）、磁性（顺磁性）和塑性等基础概念，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目需要考生理解奥氏体的基本定义和特性，包括其晶体结构（γ-固溶体）、塑性行为以及磁性特征。虽然涉及多个概念，但这些都属于基础概念记忆层次，且选项之间有明显的区分度，不需要复杂的推理或深度分析。因此，难度属于等级2，即概念理解和简单辨析。" + }, + { + "idx": 3886, + "question": "By how many orders of magnitude (powers of ten, approximately) does density vary for metals? (a) 0.13 (b) 1.3 (c) 13 (d) 130", + "answer": "(b)1.3", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对金属密度变化范围的基本概念记忆，属于基础知识的直接回忆和简单理解。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及基础概念记忆（金属密度的数量级变化），但需要学生对\"数量级\"和\"金属密度范围\"有基本理解才能正确选择。不需要复杂计算或深度分析，但比单纯的定义记忆题（等级1）要求稍高，属于概念理解和简单辨析层次。" + }, + { + "idx": 2976, + "question": "The difference between cast iron and carbon steel lies in the presence or absence of (A) ledeburite (B) pearlite (C) ferrite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对铸铁和碳钢的基本组成相的记忆，特别是莱氏体的存在与否这一基础概念，属于材料科学中基础知识的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解铸铁和碳钢的基本区别，并能够识别莱氏体（ledeburite）的存在与否是关键差异点。虽然涉及基础概念记忆，但需要一定的材料学知识来区分不同组织的特征，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 3925, + "question": "Which of the following form network polymers?(a) Rubber(b) Epoxy(c) Polyethylene\nd) Phenol-formaldehyde(e) Polystyrene(f) Nylon\n\\", + "answer": "Epoxy and phenol-formaldehyde form network polymers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择能够形成网络聚合物的材料，答案给出了具体选项，符合选择题的特征 | 知识层次: 题目考查对聚合物类型（网络聚合物）的基本概念记忆和分类理解，不需要复杂的分析或计算。 | 难度: 在选择题型中，此题需要考生理解\"network polymers\"的定义特征，并能将其与线性/支化聚合物区分。虽然涉及多个选项，但只需识别出具有三维交联结构的聚合物(环氧树脂和酚醛树脂)，不需要复杂的分析过程。属于基础概念理解和简单辨析的难度层级。" + }, + { + "idx": 2929, + "question": "In substitutional solid solution alloys, the diffusion of solute atoms is achieved through . (A) Atomic exchange mechanism (B) Interstitial diffusion mechanism (C) Vacancy mechanism", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于置换固溶体中溶质原子扩散机制的正确描述 | 知识层次: 题目考查的是对置换固溶体中溶质原子扩散机制的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要学生对固溶体扩散机制有一定的理解和辨析能力，能够区分原子交换机制、间隙扩散机制和空位机制。学生需要掌握这些机制的基本定义和特点，才能正确选择答案。因此，该题目属于等级2，需要概念理解和简单辨析。" + }, + { + "idx": 4134, + "question": "If you were to locally heat identical geometry plates of the materials listed below with the same heat source, which would increase in temperature the fastest? (a) Polystyrene (b) Aluminum (c) Copper (d) Gold (e) Borosilicate Glass", + "answer": "In this scenario, the material with the highest thermal conductivity will conduct heat the fastest. Therefore this material will absorb heat and increase in temperature the fastest. In this case, copper has the highest thermal conductivity.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对材料热导率这一基本概念的简单记忆和理解，只需知道不同材料的热导率差异即可直接选择正确答案，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解热导率的基本概念，但只需比较几种常见材料的热导率即可得出答案。题目提供了明确的材料选项，且铜的热导率在选项中最高是较为基础的知识点，不需要复杂的分析或计算步骤。因此，该题目属于概念理解和简单辨析的层次。" + }, + { + "idx": 4140, + "question": "At the Curie temperature, the saturation magnetization abruptly diminishes. Which of the following magnetic material types will have Curie temperatures?(a) Diamagnetics(b) Paramagnetics(c) Ferromagnetics(d) Antiferromagnetics(e) Ferrimagnetics", + "answer": "Ferromagnetic and ferrimagnetic materials will have Curie temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案明确指出了正确选项 | 知识层次: 题目考查对磁性材料基本分类和特性的记忆，特别是关于居里温度与不同类型磁性材料的关系。只需要记住哪些材料具有居里温度即可回答，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（Curie温度的定义和适用材料类型），但需要学生能够区分不同磁性材料的特性，特别是Ferromagnetic和Ferrimagnetic材料的共同点。这要求一定的概念理解和简单辨析能力，而不仅仅是直接记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4044, + "question": "Which type of charge carrier will be introduced into a semiconductor by the presence of a donor impurity?(a) Impurity(b) Hole", + "answer": "The presence of a donor impurity introduces electrons into a semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查半导体中施主杂质引入载流子的基本概念，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆半导体中施主杂质引入的载流子类型（电子）。题目直接考察定义性知识，无需复杂理解或分析，属于最简单的难度等级。" + }, + { + "idx": 2930, + "question": "The flexibility of polymer materials mainly depends on the mobility of . (A) Main chain segments (B) Side groups (C) Functional groups or atoms within side groups", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查聚合物材料柔韧性的基本概念，即主链段的运动性，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别聚合物材料柔韧性的主要决定因素（主链段的活动性），无需复杂辨析或深度理解。选项直接对应基础知识点，属于简单概念识别。" + }, + { + "idx": 4024, + "question": "For a solution, which of the following is present in the higher concentration?(a) Solvent(b) Solute", + "answer": "Solvent. By definition, solvent is the element/compound that is present in a solution in the greatest amount.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a) Solvent和(b) Solute中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对溶剂和溶质基本定义的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目仅考察对溶剂和溶质定义的基本记忆，无需深入理解或复杂辨析，只需识别出溶剂在溶液中浓度更高这一基本事实。" + }, + { + "idx": 738, + "question": "Which valence state of cations must be present in the exchange of originally adsorbed cations in clay for mud peptization? (d) Monovalent (e) Divalent (f) Trivalent", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项（d、e、f）中选择一个正确答案（d），符合选择题的特征 | 知识层次: 题目考查粘土中阳离子交换的基本概念，即单价阳离子在泥浆胶溶中的作用，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别黏土中阳离子交换的基本原理（单价阳离子促进泥浆胶溶）。题目直接给出定义性知识，无需理解或辨析其他选项的化学意义，属于最简单的概念识别题。" + }, + { + "idx": 3058, + "question": "What are included in traditional ceramics? Options: A. Cement B. Alumina C. Silicon carbide D. Boron nitride E. Refractory materials F. Household ceramics G. Silicon nitride H. Glass", + "answer": "A,F,H", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项列表和答案组合 | 知识层次: 题目考查对传统陶瓷分类的基础概念记忆，只需识别哪些选项属于传统陶瓷范畴，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别传统陶瓷的常见组成材料（水泥、家用陶瓷、玻璃）。选项明确区分传统陶瓷与先进陶瓷材料，无需复杂分析或深度理解，属于直接记忆性知识。在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3995, + "question": "How does increasing the molecular weight of a semicrysatlline polymer affect its tensile strength?(a) Increases(b) Decreases\n\\", + "answer": "The tensile strength of a semicrystalline polymer increases with increasing molecular weight. This effect is explained by the increased chain entanglements at higher molecular weights.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（a）和（b）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对半结晶聚合物分子量与其拉伸强度关系的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即分子量增加对半结晶聚合物拉伸强度的影响。正确选项直接给出了基本原理的解释，无需复杂辨析或深度理解。因此，该题目属于简单概念识别，直接记忆的难度等级。" + }, + { + "idx": 4034, + "question": "For a congruent phase transformations there are (a) no composition alterations.(b) compositional alterations.", + "answer": "(a) no composition alterations", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对“congruent phase transformations”这一基本概念的记忆和理解，特别是其定义中关于成分变化的特点。这属于基础概念的记忆性知识，不需要复杂的应用或分析。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即“共晶相变”的定义特征。题目直接考察学生是否记住“共晶相变没有成分改变”这一基本事实，无需理解或辨析其他复杂概念。属于最简单的概念识别层级。" + }, + { + "idx": 4048, + "question": "For a p-type semiconductor, which type of charge carrier is present in the greater concentration?(a) Holes(b) Electrons", + "answer": "For a p-type semiconductor, holes, (i.e., positive charge carriers) are present in a greater concentration than electrons.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项（a）Holes和（b）Electrons中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对p型半导体中主要载流子类型的基础概念记忆，仅需知道p型半导体中空穴浓度高于电子这一基本事实即可回答，无需复杂分析或计算。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即p型半导体中多数载流子的类型。学生只需直接回忆p型半导体的定义即可选出正确答案，无需进行复杂的概念辨析或深度理解。因此，该题目属于简单概念识别，直接记忆的难度等级。" + }, + { + "idx": 3972, + "question": "As a metal is strain hardened, its ductility(a) increases(b) decreases", + "answer": "As a metal is strain hardened, its ductility decreases.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查金属应变硬化与延展性关系的基本概念记忆和理解 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别金属应变硬化后延展性的变化趋势。选项直接对应教材定义，无需理解或辨析过程，属于最简单的概念识别层级。" + }, + { + "idx": 3882, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of a material property? (a) Density (b) Annealing (c) Forging (d) Single-crystal (e) Crystalline", + "answer": "(a) Density", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料性能基本概念的记忆和理解，仅需识别出密度是材料性能的典型例子，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基础概念识别，直接记忆的难度等级。题目要求识别材料属性的最佳例子，正确选项(a) Density是一个基本的材料属性，属于材料科学中最基础的概念之一。其他选项如(b) Annealing和(c) Forging是加工过程，(d) Single-crystal和(e) Crystalline是结构描述，与属性无关。因此，只需简单记忆和识别即可选出正确答案，无需深入理解或复杂分析。" + }, + { + "idx": 1873, + "question": "Most solid-phase reactions fall into A. Chemical reaction kinetics range B. Diffusion kinetics range C. Transition range", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查对固相反应动力学范围的基本分类记忆，属于基础概念的记忆和理解层面，不需要复杂的分析或应用过程。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需识别\"Most solid-phase reactions\"的分类归属。题目直接考察对固相反应动力学范围的基本定义记忆，无需复杂辨析或深度理解。正确选项B（Diffusion kinetics range）是教材中明确指出的标准答案，属于简单概念识别层级。" + }, + { + "idx": 3883, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of material processing?(a) Extrusion(b) Crystalline(c) Amorphous(d) Glassy (e) Elastic Modulus", + "answer": "(a)Extrusion", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料加工基本概念的识别和记忆，只需从选项中选出与材料加工相关的术语，不需要复杂的分析或推理。 | 难度: 在选择题型中属于简单难度，题目直接考察对\"材料加工\"这一基础概念的识别能力。正确选项(a)Extrusion是材料加工的典型示例，而其他选项都是材料结构或性能的描述。这只需要最基本的定义记忆即可作答，无需理解或辨析过程。" + }, + { + "idx": 2939, + "question": "The Peierls-Nabarro force for dislocation slip is smaller.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（A） | 知识层次: 题目考查Peierls-Nabarro力的基本概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆Peierls-Nabarro力的定义及其与位错滑移的关系，无需复杂理解或分析步骤。" + }, + { + "idx": 4040, + "question": "The electrical conductivity of an intrinsic semiconductor is(a) characteristic of the high-purity metal.(b) due to the presence of impurities.", + "answer": "The electrical conductivity of an intrinsic semiconductor is characteristic of the high-purity material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对半导体基本概念的记忆和理解，特别是本征半导体的电导率特性。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和记忆\"本征半导体\"的定义和特性。正确选项直接对应教材中的基础定义，无需复杂分析或概念辨析，属于最简单的难度等级。" + }, + { + "idx": 3971, + "question": "On the average, dislocation-dislocation strain interactions are(a) repulsive.(b) attractive.", + "answer": "On the average, dislocation-dislocation strain interactions are repulsive.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对位错-位错应变相互作用的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆位错-位错应变相互作用的基本性质即可作答，无需复杂理解或辨析。" + }, + { + "idx": 3056, + "question": "What can SiC ceramics be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对SiC陶瓷用途的基本概念记忆，属于基础知识的直接回忆和识别，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆层次，仅需识别SiC陶瓷的基本用途。选项B（Blade）是直接记忆性知识点，无需复杂分析或概念辨析，符合等级1的简单概念识别标准。" + }, + { + "idx": 1884, + "question": "Fick's first law can be directly applied to solve the problem of . A．steady-state diffusion B．non-steady-state diffusion C．any diffusion", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对Fick's第一定律适用条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念记忆题，直接考察Fick第一定律的应用范围。只需识别\"稳态扩散\"这一基本定义，无需进行概念辨析或复杂分析。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 3023, + "question": "When a polymer material is subjected to force, the elasticity achieved by the movement of chain segments is (2). A. Ordinary elasticity B. High elasticity C. Viscoelasticity D. Forced elasticity", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对聚合物材料弹性类型的基本概念记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生理解聚合物材料在受力时的弹性类型，并能够区分普通弹性、高弹性、粘弹性和强制弹性等概念。这要求考生不仅记住定义，还要能够进行简单的概念辨析。" + }, + { + "idx": 1140, + "question": "What kind of motion cannot be performed by a screw dislocation?", + "answer": "Climb", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案\"Climb\"是其中一个选项 | 知识层次: 题目考查对位错运动类型的基础概念记忆，特别是关于螺型位错不能进行的运动类型（攀移）这一基本知识点。 | 难度: 在选择题型中，该题目需要考生理解螺型位错的基本运动方式（滑移和攀移），并能够区分这两种运动的特点。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，因此属于等级2难度。" + }, + { + "idx": 4030, + "question": "At a eutectic point on a binary temperature-composition phase diagrams, how many phases are present when the system is at equilibrium?(a) 0(b) 1(c) 2(d) 3", + "answer": "At a eutectic point on a binary phase diagram, three phases (Liquid, \\alpha, and \\beta ) are present when the system is at equilibrium.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（a、b、c、d）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对二元相图中共晶点处相平衡状态的基本概念记忆，属于对基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆题，直接考察对共晶点相数的记忆。在选择题型中，只需识别并回忆\"共晶点三相共存\"这一基本概念即可作答，无需任何分析或推理过程，属于最简单的直接记忆型题目。" + }, + { + "idx": 3917, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?\n\\[\n\\alpha \\neq \\beta \\neq \\gamma \\neq 90^{\\circ}\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "Triclinic is the only crystal system for which none of the interaxial angles are equal to one another and also not equal to 90^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的正确答案 | 知识层次: 题目考查对晶体系统基本概念的记忆和理解，特别是对各晶系轴角关系的识别。 | 难度: 在选择题型中，该题目需要考生理解不同晶系的基本定义和特征，特别是对晶轴角度关系的记忆和简单辨析。虽然题目涉及多个晶系的比较，但正确选项（Triclinic）的特征较为明确，属于基础概念记忆和简单辨析的范畴，不需要复杂的分析或深度理解。因此，难度等级为2。" + }, + { + "idx": 1878, + "question": "The viscosity corresponding to the glass transition temperature Tf is A.105dPa·s B.109dPa·s C.1011dPa·s D.1013dPa·s", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择与玻璃转变温度Tf对应的粘度值，属于典型的选择题形式 | 知识层次: 题目考查对玻璃转变温度对应粘度值的记忆，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅需记忆玻璃转变温度对应的粘度值即可选出正确答案，属于基础概念的直接记忆，无需复杂理解或分析。" + }, + { + "idx": 4149, + "question": "In the visible spectrum, a thick metal specimen will be(a) Transparent(b) Translucent(c) Opaque", + "answer": "In the visible spectrum, a thick metal specimen is opaque.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对金属在可见光谱中光学性质的基本概念记忆，属于基础概念的记忆和理解层面。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别金属在可见光谱中的基本特性（不透明性），无需复杂理解或辨析步骤。" + }, + { + "idx": 3014, + "question": "The usage state of synthetic fibers is (). A. Crystalline state B. Glassy state C. High elastic state D. Viscous flow state", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C、D）中选择正确答案 | 知识层次: 题目考查对合成纤维使用状态这一基础概念的简单记忆和理解，属于材料科学中最基本的知识点，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然考察的是基础概念记忆（合成纤维的使用状态），但需要考生理解并区分\"玻璃态\"与其他状态（如晶态、高弹态、粘流态）的不同。这比单纯记忆定义（等级1）要求稍高，但不需要复杂的分析比较（等级3）。正确选项B需要考生掌握合成纤维在常温下的典型状态特征。" + }, + { + "idx": 3055, + "question": "What can alumina ceramic be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "C,E", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案形式为选项字母组合，符合选择题的特征 | 知识层次: 题目考查对氧化铝陶瓷常见用途的基础概念记忆，只需从给定选项中选择正确的应用场景，不涉及复杂分析或综合运用。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生了解氧化铝陶瓷的基本用途。虽然需要记忆多个应用场景，但选项之间的区分度较高，只需简单辨析即可选出正确答案。不需要复杂的分析或深度理解，因此属于等级2难度。" + }, + { + "idx": 4032, + "question": "A eutectoid reaction involves which of the following phases? (a) One liquid and one solid (b) One liquid and two solid (c) Two liquids and one solid (d) Three solid", + "answer": "(d) Three solid", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查共析反应中相的基本概念记忆，只需记住共析反应涉及三个固相即可作答，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目仅涉及对共析反应定义的基础记忆，无需复杂理解或辨析。学生只需识别共析反应涉及的相数即可直接作答，属于简单概念识别类型。" + }, + { + "idx": 4022, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must feature [y] valence electron configuration. (y = a similar (or the same), a different)", + "answer": "The solute and host species must feature a similar (or the same) valence electron configuration.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确的答案填空，符合选择题的特征 | 知识层次: 题目考查对固溶体溶解度条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆固体溶解度条件中关于价电子构型的基本原理。正确选项明确且无需复杂分析，属于最简单的概念识别级别。" + }, + { + "idx": 2962, + "question": "In the seven polymorphic forms of $\\\\mathrm{{SiO}}_{2}$, there are two types of transformations: one is displacive transformation, and the other is reconstructive transformation. The activation energy required for displacive transformation is _____ that for reconstructive transformation. (A) greater than (B) less than (C) equal to", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对两种相变类型（位移型相变和重构型相变）的基本概念记忆，特别是它们所需活化能的相对大小，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目需要理解两种相变类型（位移型相变和重构型相变）的基本概念，并比较它们的活化能大小。虽然涉及两个概念，但题目直接给出了明确的比较关系，不需要复杂的分析或推理过程，属于概念理解和简单辨析的难度级别。" + }, + { + "idx": 3896, + "question": "When all the electrons in an atom occupy the lowest possible energy states, the atom is said to be in its: (a)ground state(b)ionized state (c) cold state (d) regular state", + "answer": "(a)ground state", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确的答案，符合选择题的特征。 | 知识层次: 题目考查对原子基态这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆类型。题目仅考察对\"ground state\"这一基础定义的记忆，无需进行概念辨析或复杂理解，符合等级1的难度标准。" + }, + { + "idx": 1819, + "question": "The essence of a crystal is (2)", + "answer": "(2) Particles are arranged in a periodic repetition in three-dimensional space", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案明确对应选项(2) | 知识层次: 题目考查晶体本质的基本概念记忆，仅需理解晶体中粒子在三维空间周期性排列的定义，不涉及复杂分析或应用。 | 难度: 在选择题型中，此题属于基础概念记忆，仅需识别晶体本质的定义即可作答，无需复杂理解或分析。正确选项直接对应晶体结构的基本特征，属于简单概念识别层级。" + }, + { + "idx": 3085, + "question": "The reinforcing effect is best when the diameter of the fine particle phase in fine-grained composites is (1). A. $<0.01~\\\\mu\\\\mathrm{m}$ B.0.01\\\\~0.1-pm $\\\\mathrm{C.}>0.1\\\\mu m$", + "answer": "(1)B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对细粒复合材料中细颗粒相直径对增强效果影响的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目考察的是对细颗粒复合材料中细颗粒相直径范围的基础概念记忆，只需记住最佳增强效果的直径范围是0.01~0.1微米即可选择正确答案，无需复杂的理解或分析过程。" + }, + { + "idx": 3549, + "question": "In a crystal, the defect formed by simultaneously creating a vacancy and an interstitial atom is called ( ). A. Schottky defect B. Frenkel defect C. Interstitial defect", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查晶体缺陷的基本概念和分类的记忆，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆晶体缺陷的定义和分类。题目直接考察Frenkel缺陷的定义，无需复杂辨析或深度理解，属于简单概念识别级别。" + }, + { + "idx": 3887, + "question": "The atomic mass of an atom may be expressed as the sum of the masses of (a) Electrons (b) Neutrons (c) Protons (d) Choose all that apply.", + "answer": "(b) Neutrons and (c) Protons", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，并且有明确的选项列表和选择要求（\"Choose all that apply\"）。 | 知识层次: 题目考查原子质量的基本构成，仅需记忆和理解质子与中子的质量贡献，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆原子质量的基本组成（质子和中子）即可作答，无需复杂分析或概念辨析。题目选项设置简单明确，正确选项直接对应基础知识点，属于最简单的难度等级。" + }, + { + "idx": 4493, + "question": "(b) Which type(s) of copolymer(s) will this copolymer be, considering the following possibilities: random, alternating, graft, and block?", + "answer": "random, alternating, graft, and block", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四种类型(random, alternating, graft, and block)中选择正确的共聚物类型，符合选择题的特征 | 知识层次: 题目考查对共聚物类型（无规、交替、接枝、嵌段）基本分类的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目要求考生理解和辨析不同类型的共聚物（random, alternating, graft, block），但不需要复杂的分析或深度理解。考生只需记忆并区分这些基本概念即可选出正确选项。因此，该题目属于中等难度（等级2）。" + }, + { + "idx": 2724, + "question": "Assume there is an edge dislocation with a b in the [0-10] direction gliding along the (100) crystal plane. If a screw dislocation with a b direction of [100] gliding on the (001) crystal plane passes through the aforementioned dislocation, will it form a kink or a jog?", + "answer": "Jog", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从两个选项（kink或jog）中选择正确答案 | 知识层次: 题目需要理解位错的基本概念（如刃位错和螺位错的性质），并能够应用这些概念来分析两种位错相互作用的结果。虽然不涉及复杂的计算或多步推理，但需要对位错运动和相互作用有一定的综合分析能力。 | 难度: 在选择题型中，该题目属于复杂分析过程的判断难度。首先，题目涉及两种不同类型的位错（刃型位错和螺型位错）的相互作用，需要考生对位错的基本性质（如柏氏矢量和滑移面）有清晰的理解。其次，题目要求考生分析两种位错相互穿过时形成的缺陷类型（kink或jog），这需要综合应用位错理论中的相关知识，并进行空间想象和逻辑推理。此外，题目中的晶体学方向和平面描述增加了复杂性，要求考生能够准确地将抽象概念转化为具体情境。因此，该题目在选择题型内属于较高难度，需要考生具备较强的综合分析能力和概念应用能力。" + }, + { + "idx": 2772, + "question": "In the ternary composition triangle, alloys whose compositions lie on the have equal contents of the two components represented by the other two vertices. (A) The perpendicular bisector passing through the vertex of the triangle (B) Any straight line passing through the vertex of the triangle (C) A straight line passing through the vertex of the triangle and forming a $45^{\\circ}$ angle with the opposite side", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对三元相图中特定组成线的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，但需要考生理解三元相图中通过顶点的垂直平分线的定义及其含义。虽然题目直接考察定义，但需要一定的概念理解和简单辨析能力，因此属于等级2难度。" + }, + { + "idx": 700, + "question": "The four structural parameters $z$, $R$, $X$, and $Y$ of the $\\mathrm{Na}{2}\\mathrm{{\\bfO}}\\cdot\\mathrm{Ca}\\mathrm{{\\bfO}}\\cdot\\mathrm{Al}{2}\\mathrm{{\\bfO}}{3}\\cdot2\\mathrm{SiO}{2}$ glass", + "answer": "$,1.{\\surd};2.{\\surd};3.{\\searrow};4.\\times;5.\\times;6.\\times;7.{\\surd};8.\\times;9.\\times;10.\\times_{\\mathrm{~o~}}$ II. 1. b; 2. d; 3. a; 4. a; 5. c; 6. c; 7. (A) c、(B) a; 8. a、c; 9.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目答案中包含多个选项的选择（如1. b; 2. d; 3. a等），符合选择题的特征 | 知识层次: 题目考查的是对材料科学中玻璃结构参数的基本概念记忆和理解，属于基础知识的直接应用，不需要复杂的分析或综合能力。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生对玻璃结构参数的定义和分类有一定的理解和辨析能力。题目中的正确选项涉及多个参数的判断，需要考生能够区分不同参数的含义和应用，而不仅仅是简单的记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 2749, + "question": "The $c/a$ ratio for an ideal hexagonal close-packed metal is ", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项字母形式给出 | 知识层次: 题目考查对理想六方密堆积金属的c/a比值的记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆理想六方密堆积金属的$c/a$比值这一具体数值即可作答。在选择题型中，此类直接考察定义或基本数值的记忆性题目属于最简单的难度等级，无需理解或分析过程。" + }, + { + "idx": 4107, + "question": "For a composite material, which phase normally has the higher elastic modulus?(a) Fiber phase(b) Matrix phase", + "answer": "The fiber phase normally has a higher elastic modulus than the matrix phase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（Fiber phase和Matrix phase）中选择正确答案 | 知识层次: 题目考查复合材料中纤维相和基体相弹性模量的基本概念记忆，属于基础知识的直接问答，无需复杂分析或计算。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即复合材料中纤维相通常具有较高的弹性模量。学生只需直接回忆这一基本事实即可作答，无需进行任何复杂的理解或分析步骤。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1807, + "question": "In the spinel (MgAl2O4) structure, O2- forms a cubic close packing, and Mg2+ ions fill a. 1/2 of the tetrahedral voids b. 1/2 of the octahedral voids c. 1/8 of the tetrahedral voids d. 1/8 of the octahedral voids", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案 | 知识层次: 题目考查对尖晶石结构中离子填充位置的基础概念记忆，属于对晶体结构基本知识的直接应用，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（spinel结构中离子的填充情况），但需要考生对立方紧密堆积中的四面体和八面体空隙有清晰的理解，并能区分不同离子填充的具体比例。这比单纯记忆定义（等级1）要求更高，但尚未达到需要复杂概念区分或深度理解的程度（等级3）。" + }, + { + "idx": 4103, + "question": "Which of the following materials are typically used as fibers?(a) Graphite/carbon(b) Silicon carbide(c) Silicon nitride(d) Aluminum oxide(e) Glass(f) Boron(g) Steel\nh) Tungsten\ni) Molybdenum", + "answer": "Graphite, silicon carbide, glass, boron, and aluminum oxide are typically used as fibers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作纤维，答案是从给定选项中选择特定材料，符合选择题的特征 | 知识层次: 题目考查对常见纤维材料的基础概念记忆，只需识别哪些材料通常被用作纤维，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（纤维材料的典型种类），但需要考生对多种材料是否常用作纤维有一定的理解和辨析能力。正确选项涉及5种材料，且干扰项中包含一些可能混淆的材料（如钢、钨、钼），这要求考生不仅需要记忆常见纤维材料，还需要进行简单的概念区分。不过题目没有涉及复杂的概念关联或深度分析，因此难度等级为2。" + }, + { + "idx": 4043, + "question": "Which type of charge carrier will be introduced into a semiconductor by the presence of an acceptor impurity?(a) Electron(b) Hole", + "answer": "The presence of an acceptor impurity introduces holes into a semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项(a)和(b)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查半导体中受主杂质引入载流子的基本概念，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即\"受主杂质引入空穴\"这一简单事实的识别。不需要任何理解或分析过程，属于直接记忆性知识，符合等级1的简单概念识别标准。" + }, + { + "idx": 3021, + "question": "The plasticity of a polymer is related to which temperature? A. $T_{\\mathrm{m}}$ B. $T_{_{8}}$ C. $T_{t}$ D.Ta", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对聚合物塑性相关温度的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别与聚合物塑性相关的温度符号Ta，无需复杂理解或辨析其他选项。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 4025, + "question": "A liquidus line separates which of the following combinations of phase fields?(a) Liquid and Liquid +\\alpha(b) \\alpha and Liquid +\\alpha(c) \\alpha and \\alpha+\\beta(d) Liquid +\\alpha and \\alpha+\\beta", + "answer": "A liquidus line separates Liquid and Liquid +\\alpha phase fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对相图中液相线（liquidus line）定义和功能的基本记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，直接考察对liquidus线定义的理解，无需复杂分析或比较。只需识别liquidus线分隔的是Liquid和Liquid + α相区，属于简单概念识别和直接记忆的范畴。" + }, + { + "idx": 4045, + "question": "The electrical conductivity of an extrinsic semiconductor is(a) Characteristic of the high-purity material.(b) due to the presence of impurities.", + "answer": "The electrical conductivity of an extrinsic semiconductor is due to the presence of impurities.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择关于外征半导体导电性的正确描述 | 知识层次: 题目考查对半导体导电性基本原理的记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆类型，仅需识别并记忆外征半导体的电导率是由杂质引起的这一基本事实。在选择题型中，这种直接考察定义或分类的题目属于最简单的难度等级，不需要复杂的理解或分析过程。" + }, + { + "idx": 3907, + "question": "Some metal is known to have a cubic unit cell with an edge length of 0.437 nm. In addition, it has a density of 4.37 g/cm3 and an atomic weight of 54.85 g/mol. Indicate the letter of the metal listed in the following table that has these characteristics.", + "answer": "The metal with these characteristics is metal C, which has an atomic radius of 0.155 nm and an FCC crystal structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的金属列表中选择符合特定特征的金属，答案明确指出了具体选项（金属C），符合选择题的特征。 | 知识层次: 题目需要根据给定的晶胞边长、密度和原子量计算金属的特性，并关联到晶体结构（FCC）和原子半径。这涉及多步计算和概念关联，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要考生进行多步计算（如单位换算、密度公式应用、晶体结构分析）和概念关联（如将计算出的原子半径与给定选项匹配）。此外，题目还要求综合分析晶体结构（FCC）与原子半径的关系，超出了基础概念记忆的范畴，属于复杂分析过程的判断。" + }, + { + "idx": 4036, + "question": "Conductivity in a metal is almost always reduced by the introduction of defects into the lattice.\nThe factor primarily affected by defects is:\n[a] free electron concentration\n[b] electron charge\n[c] electron mobility\n[d] electron spin", + "answer": "[c] electron mobility", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对金属导电性影响因素的基础概念记忆，特别是缺陷对电子迁移率的影响，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解金属导电性的基本原理，并能够辨析不同因素（如自由电子浓度、电子电荷、电子迁移率和电子自旋）对导电性的影响。正确选项（电子迁移率）需要考生对缺陷如何影响电子运动有基本的理解，而不仅仅是简单的记忆。因此，该题目属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 4136, + "question": "Which two of the following are ferromagnetic materials? \\\\(a) Aluminum oxide \\\\(b) Copper \\\\ c) Aluminum \\\\ d) Titanium \\\\ e) Iron ( \\alpha ferrite) \\\\ f) Nickel \\\\ g) MnO \\\\ h) \\mathrm{Fe}_{3} \\mathrm{O}_{4} \\\\ i) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}\n}", + "answer": "Iron ( \\alpha ferrite) and nickel are ferromagnetic materials.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择两个铁磁性材料，符合选择题的特征 | 知识层次: 题目考查对铁磁性材料的基本概念和分类的记忆，只需识别哪些材料属于铁磁性材料，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，该题目仅需识别和记忆基础概念中的铁磁性材料。正确选项（Iron (α ferrite) and nickel）是常见的铁磁性材料，属于直接记忆性知识，无需复杂辨析或深度理解。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 1808, + "question": "Kaolinite belongs to the layered silicate structure, and its structural feature is a. two-layer type trioctahedral structure b. three-layer type trioctahedral structure c. two-layer type dioctahedral structure d. three-layer type dioctahedral structure", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择关于高岭石结构特征的正确答案 | 知识层次: 题目考查对高岭石（Kaolinite）结构特征的基础概念记忆，属于对层状硅酸盐结构分类的基本知识点的直接考察。 | 难度: 在选择题型中，该题目属于中等难度。虽然考察的是基础概念记忆，但需要考生对高岭石的结构特征有清晰的理解，并能够区分两层型和三层型、三八面体和二八面体等专业术语。题目要求考生不仅记住高岭石属于二八面体结构，还要在四个相似选项中准确识别出正确描述。这比单纯的概念识别（等级1）要求更高，但尚未达到需要深度理解和复杂概念区分的等级3难度。" + }, + { + "idx": 4143, + "question": "Which type(s) of magnetic materials may be classified as either soft or hard?(a) Diamagnetic(b) Paramagnetic(c) Ferromagnetic(d) Antiferromagnetic(e) Ferrimagnetic", + "answer": "Ferromagnetic and ferrimagnetic materials may be classified as either soft or hard.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，答案明确指出了正确选项 | 知识层次: 题目考查对磁性材料分类的基础概念记忆，只需要理解并区分不同类型的磁性材料是否可以被分类为软磁或硬磁，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解磁性材料的基本分类（软磁和硬磁）并能够区分哪些类型（铁磁和亚铁磁）可以进一步细分为这两类。虽然涉及多个概念，但主要是基础概念的记忆和简单辨析，不需要复杂的分析或深度理解。" + }, + { + "idx": 4106, + "question": "Match the fiber type 'Wires' with its description.", + "answer": "Wires are large-diameter metals.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求将纤维类型与其描述进行匹配，属于从多个选项中选择正确答案的形式 | 知识层次: 题目考查对纤维类型及其描述的基础概念记忆，仅需识别和匹配\"Wires\"与其定义，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和匹配简单的定义描述（\"Wires are large-diameter metals\"），无需理解或辨析复杂概念，完全符合等级1\"简单概念识别，直接记忆\"的标准。" + }, + { + "idx": 1747, + "question": "In UO2 crystals, the diffusion of O2- proceeds via the mechanism. a. vacancy b. interstitial c. dopant point defect", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a. vacancy b. interstitial c. dopant point defect）中选择一个正确答案（b），符合选择题的特征。 | 知识层次: 题目考查对UO2晶体中O2-扩散机制的基础概念记忆，属于对基本原理和分类的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生了解UO2晶体中O2-的扩散机制。虽然需要记忆具体机制类型（间隙扩散），但不需要复杂的分析或比较过程。在选择题型中属于概念理解和简单辨析难度，比纯粹的概念识别（等级1）稍高，但低于需要深度理解的复杂概念区分（等级3）。" + }, + { + "idx": 4081, + "question": "Increasing the alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}_{3}\\right) content of fireclays results in(a) an increase in maximum service temperature.(b) a decrease in maximum service temperature.", + "answer": "Increasing the alumina \\left(\\mathrm{Al}_{2} \\mathrm{O}\\right)_{3} content of fireclays results in an increase in maximum service temperature.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查对氧化铝含量与耐火粘土最高使用温度关系的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即氧化铝含量增加对耐火粘土最高使用温度的影响。正确选项直接对应记忆性知识，无需复杂理解或分析步骤，属于简单概念识别。" + }, + { + "idx": 3915, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell edge lengths?\n\\[\na=b \\neq c\n\\](a) Cubic(b) Hexagonal(c) Tetragonal\n\\mathrm{d}) Rhombohedral(e) Orthorhombic(f) Monoclinic (g) Triclinic", + "answer": "For both hexagonal and tetragonal crystal systems two of the unit cell edge lengths are equal to one another, but unequal to the third length.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定条件的晶体系统，答案明确给出了符合条件的选项，符合选择题的特征。 | 知识层次: 题目考查对晶体系统基本特征和分类的记忆和理解，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆不同晶系的晶胞边长关系，但题目明确给出了关键特征（a=b≠c），并提供了选项供选择。考生只需识别并匹配Hexagonal和Tetragonal两种晶系的特征即可，不需要进行复杂的分析或推导。这属于基础概念记忆和简单辨析的范畴。" + }, + { + "idx": 4152, + "question": "Match the type of light transmission with its description: Transmits light diffusely.", + "answer": "A translucent material transmits light diffusely.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求将光的传输类型与其描述进行匹配，属于从多个选项中选择正确答案的类型 | 知识层次: 题目考查对材料光学性质基本概念的记忆和理解，即透明材料和半透明材料在光传输特性上的区别。这属于基础概念记忆层次的知识点。 | 难度: 在选择题型中，该题目仅要求识别并匹配基础概念的定义（translucent material与diffuse light transmission的关系），属于直接记忆性知识，无需复杂理解或辨析步骤。" + }, + { + "idx": 2942, + "question": "During the nucleation stage of solidification, only when the radius of the nucleus equals or exceeds the critical size can it become a crystallization core. When the formed nucleus has a radius equal to the critical size, the free energy change of the system is", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对凝固过程中临界核尺寸和系统自由能变化的基本概念的理解和记忆，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解临界尺寸与自由能变化之间的关系，而不仅仅是简单的定义记忆。学生需要掌握成核阶段的基本原理，并能够将临界尺寸与系统自由能变化联系起来。这比单纯的概念识别（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 1430, + "question": "Which is the most closely packed plane of a body-centered cubic crystal?", + "answer": "110", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个可能的晶体平面中选择最紧密排列的平面，答案\"110\"是其中一个特定选项 | 知识层次: 题目考查对体心立方晶体最密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆体心立方晶体最密排面的定义即可选出正确答案110。不需要进行概念辨析或复杂分析，符合等级1的简单概念识别标准。" + }, + { + "idx": 1751, + "question": "In the sintering process, the mass transfer method that only gradually increases the strength of the green body without causing shrinkage of the green body is a. lattice diffusion b. flow mass transfer c. evaporation-condensation d. dissolution-precipitation", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案，符合选择题的特征 | 知识层次: 题目考查烧结过程中物质传递方式的基本概念记忆和理解，特别是蒸发-凝聚这一特定机制的特征，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解烧结过程中不同传质方式的基本概念及其对生坯的影响，并进行简单辨析。虽然涉及多个概念，但题目明确给出了关键特征（不引起收缩），降低了分析复杂度。" + }, + { + "idx": 3957, + "question": "13: Typical relationship between E and G}\nFor most metals, the relationship between elastic and shear moduli is approximately which of the following?(a) G=0.1 E(b) G=0.2 E(c) G=0.3 E(d) G=0.4 E(e) G=0.5 E", + "answer": "the relationship between elastic and shear moduli for most metals is approximately g=0.4 e.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对弹性模量和剪切模量之间关系的基本概念记忆，属于基础知识的直接应用，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆弹性模量（E）和剪切模量（G）之间的典型关系即可作答，无需复杂理解或分析。" + }, + { + "idx": 2999, + "question": "What are the mechanical states of high polymers with larger molecular weight that are not completely crystalline?", + "answer": "(1) Glassy state; (2) High elastic state; (3) Leathery state; (4) Viscous flow state", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对高分子材料机械状态分类的基础概念记忆，属于定义和分类的记忆性知识，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆层次，考察高分子材料在不同机械状态下的分类。虽然需要记忆多个状态（玻璃态、高弹态、皮革态、粘流态），但选项均为直接对应的专业术语，不涉及复杂辨析或深度理解。在选择题型中属于概念理解和简单辨析难度，略高于简单识别但未达到复杂区分程度。" + }, + { + "idx": 3912, + "question": "Consider the ideal barium titanate \\left(\\mathrm{BaTiO}_{3}\\right) structure. What is the coordination number of the \\mathrm{Ti}^{4+} ion in terms of surrounding \\mathrm{O}^{2-} ions?\n[a] 1\n[b] 2\n[c] 3\n[d] 4\n[e] 5\n[f] 6\n[g] 7\n[h] 8", + "answer": "According to Fig. 3.10, the central \\mathrm{Ti}^{4+} ion is surrounded by six \\mathrm{O}^{2-} ions, one residing at each of the six cube faces.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的多个选项中选择正确答案，且答案明确指出了正确的选项。 | 知识层次: 题目考查对理想钛酸钡结构中Ti4+离子配位数的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆理想BaTiO3结构中Ti4+离子的配位数。题目提供了明确的提示（参考图3.10），且正确选项（6）是晶体学中的常见配位数，属于简单概念识别范畴，无需复杂分析或推理。" + }, + { + "idx": 4110, + "question": "Which of aramid and metal fibers have higher strength-to-weight ratios?(a) Aramid fibers(b) Metal fibers", + "answer": "Aramid fibers have higher strength-to-weight ratios than metal fibers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对芳纶纤维和金属纤维强度重量比这一基本概念的简单记忆和比较，不涉及复杂计算或综合分析。 | 难度: 在选择题型中，该题目仅涉及基础概念记忆，即比较芳纶纤维和金属纤维的强度重量比。学生只需记住芳纶纤维具有更高的强度重量比这一事实即可选择正确答案，无需进行复杂的理解或分析。因此，该题目在选择题型内属于简单概念识别，直接记忆的难度等级。" + }, + { + "idx": 730, + "question": "A space lattice is formed by arranging in space with a regular repetition. (a) atoms (b) ions (c) geometric points (d) molecules", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（a、b、c、d）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查空间点阵的基本概念，即由几何点在空间中规则排列形成，属于基础概念的记忆和理解。 | 难度: 该题目属于基础概念记忆类型，仅需识别\"space lattice\"的定义即可直接选择正确答案。在选择题型中属于最简单的直接记忆类题目，无需理解或辨析其他选项。正确选项(c) geometric points是空间点阵的标准定义，属于材料科学中最基础的概念记忆层次。" + }, + { + "idx": 2752, + "question": "Cesium chloride (CsCl) has an ordered body-centered cubic structure, which belongs to (A) body-centered cubic lattice (B) face-centered cubic lattice (C) simple cubic lattice", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对晶体结构分类的基本概念记忆，只需识别CsCl的晶体结构类型即可，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（CsCl的晶体结构类型），但需要考生理解并区分不同的立方晶格类型（体心立方、面心立方和简单立方）。正确选项（C）需要考生能够辨析CsCl的有序体心立方结构实际上属于简单立方格子，而不是直接选择体心立方格子（A）。这种辨析需要一定的概念理解和简单分析能力，因此难度等级为2。" + }, + { + "idx": 4049, + "question": "For a p-type semiconductor(a) Concentration _{\\text {electrons }}< concentration _{\\text {holes }}(b) Concentration _{\\text {electrons }}= concentration _{\\text {holes }}(c) Concentration _{\\text {electrons }}< concentration _{\\text { holes }}", + "answer": "For a p-type semiconductor, the concentration of electrons is much lower than the concentration of holes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了多个选项（a, b, c），要求从中选择正确的陈述，符合选择题的特征。 | 知识层次: 题目考查对p型半导体基本概念的记忆和理解，即电子和空穴浓度的相对关系，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别p型半导体的基本特性（电子浓度远低于空穴浓度）。题目选项直接对应定义，无需复杂分析或理解，属于简单概念识别。" + }, + { + "idx": 4041, + "question": "How do the electrical conductivities of metals compare with those of semiconductors?(a) \\sigma_{\\text {metals }}>\\sigma_{\\text {semiconductors }}(b) \\sigma_{\\text {metals }}=\\sigma_{\\text {semiconductors }}(c) \\sigma_{\\text {metals }}<\\sigma_{\\text {semiconductors }}", + "answer": "The electrical conductivities of metals are greater than those of semiconductors.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查的是金属和半导体电导率的基本概念和比较，属于基础概念的记忆和理解范畴。 | 难度: 在选择题型内，该题目仅涉及基础概念记忆，即金属和半导体电导率的比较。学生只需记住金属的电导率通常高于半导体这一基本事实即可正确作答，无需进行复杂的理解或分析。因此，该题目属于简单概念识别和直接记忆的难度等级。" + }, + { + "idx": 3054, + "question": "What are the main types of special ceramics? Options: A. Cement B. Alumina C. Silicon carbide D. Boron nitride E. Refractory materials F. Household ceramics G. Silicon nitride H. Glass", + "answer": "B,C,D,E,G", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择特殊陶瓷的主要类型，答案给出了具体选项组合，符合选择题的特征 | 知识层次: 题目考查对特殊陶瓷主要类型的基础概念记忆，属于分类知识的直接回忆，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别特殊陶瓷的主要类型。正确选项（B, C, D, E, G）均为常见的特殊陶瓷材料，且题目明确给出了选项范围，无需复杂辨析或深度理解。学生只需记住这些基本分类即可正确作答，因此难度等级为1。" + }, + { + "idx": 3239, + "question": "Among the following alloy phase structures, the one with high melting point, high hardness, great brittleness, and simple crystal structure is A. Topologically close-packed phase B. Interstitial compound with complex lattice structure C. Electron compound D. Interstitial phase", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对合金相结构基本特性的记忆和理解，如熔点、硬度、脆性和晶体结构的简单性等基础概念，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个合金相结构的特性比较，但正确选项D（间隙相）具有明确的特征描述（高熔点、高硬度、大脆性、简单晶体结构），这些特征在基础材料科学课程中通常会被强调和记忆。考生需要理解并辨析不同合金相结构的基本特性，但不需要进行复杂的分析或推导。因此，该题目在选择题型中属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3628, + "question": "Would you expect \\mathrm{UO}_{2} to have the sodium chloride, zinc blende, or fluoride structure?", + "answer": "fluorite structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三个结构选项（sodium chloride, zinc blende, fluoride）中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对常见晶体结构类型及其对应化合物的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考查的是基础概念记忆（UO2的晶体结构），但需要学生对三种常见晶体结构（NaCl、闪锌矿、萤石）有一定的理解和辨析能力。学生需要知道UO2通常采用萤石结构这一知识点，而不是简单地记忆定义。这比纯粹的概念识别（等级1）要求更高，但不需要复杂的分析或深度理解（等级3）。" + }, + { + "idx": 2769, + "question": "In a binary alloy phase diagram, the lever rule for calculating the relative amounts of two phases can only be applied in", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，并且提供了选项（B）作为答案 | 知识层次: 题目考查对杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解杠杆法则的应用条件，但题目仅要求识别该法则适用的特定区域（两相区），属于基础概念的直接应用。不需要复杂的分析或计算，只需记住杠杆法则的基本适用条件即可正确作答。" + }, + { + "idx": 3554, + "question": "In substitutional solid solutions, the general mode of atomic diffusion is (). \\n\\nA. Atomic exchange mechanism B. Interstitial mechanism C. Vacancy mechanism", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查的是对置换固溶体中原子扩散机制的基本概念记忆，属于基础概念的理解和记忆范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察的是对置换固溶体中原子扩散机制的基本理解。虽然需要区分三种不同的扩散机制（交换机制、间隙机制和空位机制），但题目直接给出了正确选项，且知识点相对明确，属于概念理解和简单辨析的难度级别。不需要复杂的分析或深度推理，只需掌握相关定义即可正确作答。" + }, + { + "idx": 4114, + "question": "Which of the following materials are typically used as whiskers?(a) graphite/carbon(b) silicon carbide(c) silicon nitride(d) aluminum oxide(e) glass(f) boron(g) steel\nh) tungsten\ni) molybdenum", + "answer": "Graphite, silicon carbide, silicon nitride, and aluminum oxide are typically used as whiskers.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作晶须（whiskers），答案给出了具体的选项组合，符合选择题的特征。 | 知识层次: 题目考查对常用晶须材料的基础概念记忆，只需从选项中识别出典型的晶须材料，无需深入分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆多种材料中哪些通常用作晶须（whiskers），但选项中的正确材料（石墨/碳、碳化硅、氮化硅和氧化铝）是材料科学中常见的晶须材料，属于基础概念记忆范畴。学生只需通过课堂学习或教材内容即可掌握这些知识点，无需进行复杂的分析或深度理解。错误选项（如玻璃、钢）与正确选项的差异较为明显，降低了辨析难度。因此，该题目在选择题型内属于等级2难度，需要一定的概念理解和简单辨析能力。" + }, + { + "idx": 3010, + "question": "To which category of compounds do silicone resins and silicone rubbers belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Element-organic compounds D. Inorganic polymers", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对硅树脂和硅橡胶所属化合物类别的基本概念记忆，属于定义和分类的基础知识，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要考生理解并区分不同类型化合物的分类标准。虽然题目涉及的是基础概念记忆，但需要对\"元素有机化合物\"的定义有明确理解，并能与其它选项(如碳链聚合物、杂链聚合物等)进行简单辨析。不需要复杂的分析过程，但比单纯记忆概念略高一个层次。" + }, + { + "idx": 2970, + "question": "From the symmetry of the repeating structural unit (mer) of polymers, the one that is most prone to crystallization is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择最易结晶的聚合物重复结构单元，答案以选项字母形式给出 | 知识层次: 题目考查对聚合物结构对称性与结晶倾向之间关系的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（聚合物结构单元的对称性与结晶倾向的关系），但需要考生理解对称性对结晶的影响这一基本原理，并进行简单辨析。相比直接记忆定义（等级1），该题目要求更高一层的概念理解。" + }, + { + "idx": 1870, + "question": "The crystal structure with point group L6L27PC belongs to the crystal system. A. Cubic B. Hexagonal C. Tetragonal D. Orthorhombic", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体结构点群和晶系分类的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对晶体结构和点群分类有一定的理解和辨析能力。具体来说，考生需要知道L6L27PC对应的晶体系统是Hexagonal，这不仅仅是对定义的简单记忆，还需要对点群符号和晶体系统之间的关系有一定的理解。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 1869, + "question": "Among the seven crystal systems, the number of crystal systems belonging to the highest crystal category is A.1 B.2 C.3 D.4", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择正确答案 | 知识层次: 题目考查对晶体系统分类的基础概念记忆，属于对晶体学基本分类体系的直接考察，不需要复杂的应用或分析过程。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆七种晶系中最高晶系的分类数量，无需复杂辨析或深度理解。题目直接给出明确选项，解题步骤简单，属于最基础的难度等级。" + }, + { + "idx": 3050, + "question": "The porosity of special ceramics is (4). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(4)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查特殊陶瓷孔隙率这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆特殊陶瓷的孔隙率范围即可作答，无需复杂理解或辨析步骤。" + }, + { + "idx": 2980, + "question": "In the concentration equilateral triangle of a ternary phase diagram, for alloys whose composition lies on , the content of the two components represented by the other two vertices is equal. (A) The perpendicular bisector passing through the vertex of the triangle (B) Any straight line passing through the vertex of the triangle (C) A straight line passing through the vertex of the triangle and forming a $45^{\\\\circ}$ angle with the opposite side", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对三元相图等浓度三角形中成分线的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解三元相图中等边三角形的几何特性，并能够正确识别垂直于对边的中线与通过顶点的其他直线的区别。这要求考生不仅记住定义，还需要进行简单的几何概念辨析。" + }, + { + "idx": 1806, + "question": "In the orthorhombic system, the possible types of space lattices are a.P, I, C b.P, 1, F c.P, C, F d.P, F, 1, C", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案 | 知识层次: 题目考查对正交晶系可能的空间格子类型的基本概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生记住正交晶系中可能的空间格子类型。虽然需要记忆多个选项，但只需识别正确组合，无需复杂分析或深度理解。相对于等级1的直接记忆题目，该题需要简单辨析不同选项的差异，因此属于等级2难度。" + }, + { + "idx": 2758, + "question": "The twinning plane of a face-centered cubic crystal is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（C） | 知识层次: 题目考查面心立方晶体孪晶面的基本概念记忆，属于晶体学中的基础定义性知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆（面心立方晶体的孪晶面），但需要学生对晶体结构有一定理解才能准确选择正确选项。相比纯粹的定义记忆题（等级1），此题需要学生对晶面类型进行简单辨析，但不需要复杂的分析过程（等级3）。" + }, + { + "idx": 4035, + "question": "Which of the following have a significant influence on a material's electrical resistivity?(a) impurity concentration(b) temperature(c) grain size(d) cold work(e) vacancy concentration", + "answer": "A material's electrical resistivity will depend on the following:\n- Impurity concentration\n- Vacancy concentration\n- Temperature\n- Cold work", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择对材料电阻率有显著影响的因素，答案给出了具体的选择项，符合选择题的特征 | 知识层次: 题目要求考生综合分析多个因素对材料电阻率的影响，涉及杂质浓度、温度、晶粒尺寸、冷加工和空位浓度等多个概念，需要理解这些因素如何相互作用并影响电阻率。这超出了单纯记忆基础概念的层次，属于中等应用层次的分析和综合。 | 难度: 在选择题型中属于较高难度，需要综合分析多个影响因素（杂质浓度、空位浓度、温度、冷加工）对材料电阻率的共同作用，涉及中等应用层次的知识关联和多步判断过程。" + }, + { + "idx": 1876, + "question": "Among the following types of crystals, the order of forming interstitial solid solutions is A. zeolite > CaF2 > TiO2 > MgO B. MgO > TiO2 > CaF2 > zeolite C. CaF2 > TiO2 > MgO > zeolite D. TiO2 > MgO > CaF2 > zeolite", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的顺序，属于选择题类型 | 知识层次: 题目考查对晶体间隙固溶体形成顺序的基础概念记忆，属于对基本原理和分类的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，主要考察对晶体形成间隙固溶体顺序的记忆。虽然需要记住四种晶体的具体顺序，但不需要复杂的分析或推理过程。在选择题型中，这属于需要简单概念理解和记忆的题目，难度适中。" + }, + { + "idx": 2936, + "question": "When a deformed material is reheated and undergoes recovery and recrystallization phenomena, the significant decrease in point defect concentration occurs during (A) recovery stage (B) recrystallization stage (C) grain growth stage", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对材料科学中恢复和再结晶过程中点缺陷浓度变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题中属于中等偏易难度，需要理解恢复阶段和再结晶阶段的基本概念，并能区分点缺陷浓度显著下降发生的具体阶段。虽然涉及多个概念，但选项间的区分度较高，只需基础概念理解和简单辨析即可正确作答。" + }, + { + "idx": 705, + "question": "In the sintering process, the mass transfer method that only changes the pore shape without causing shrinkage of the green body is (a) surface diffusion (b) flow mass transfer (c) evaporation-condensation (d) grain boundary diffusion", + "answer": "Martensitic transformation has the following characteristics: (26), (27), (28), and (29)_, etc. IV. Term Explanation (15 points) (Choose five questions; if all are answered, only the first five will be graded) 1. Network former 2. First-order phase transition 3. Schottky defect 4. Polymorphism 5. Wetting 6. Homogeneous nucleation 7. Non-stoichiometric structural defects 8. Grain growth", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（a）表面扩散、（b）流动质量传递、（c）蒸发-凝聚、（d）晶界扩散中选择正确的烧结过程中仅改变孔隙形状而不引起坯体收缩的质量传递方法。 | 知识层次: 题目考查烧结过程中质量传递方式的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目需要理解烧结过程中不同质量传递方式的特点，并能够区分它们对坯体收缩的影响。虽然涉及多个概念，但选项之间的区分度较高，属于概念理解和简单辨析的难度层次。" + }, + { + "idx": 4108, + "question": "For a composite material, how does the ductility of the matrix phase normally compare with the ductility of the dispersed phase?(a) more ductile(b) less ductile", + "answer": "A composite's matrix phase is normally more ductile than the dispersed phase.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目提供了两个选项(a)和(b)，要求从中选择正确的比较结果，符合选择题的特征 | 知识层次: 题目考查复合材料中基体相和分散相延展性的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆类型，仅需识别复合材料中基体相和分散相的延展性对比这一简单事实。选项直接对应教材定义，无需复杂分析或推理，属于选择题型中最简单的直接记忆类题目。" + }, + { + "idx": 2933, + "question": "Among the three crystal structures of fcc, bcc, and hcp materials, the one most prone to forming twins during plastic deformation is (A) fcc (B) bcc (C) hcp", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从三个选项（A、B、C）中选择最易形成孪晶的晶体结构，符合选择题的特征 | 知识层次: 题目考查对晶体结构（fcc、bcc、hcp）及其塑性变形行为的基础概念记忆，特别是关于孪生倾向性的基本知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生识别并记忆不同晶体结构在塑性变形中形成孪晶的倾向性。虽然需要区分fcc、bcc和hcp三种结构，但知识点较为明确，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 2941, + "question": "The relationship between the probability of annealing twin formation and the stacking fault energy of the crystal is (A) unrelated, only dependent on the annealing temperature and time (B) crystals with low stacking fault energy have a higher probability of forming annealing twins (C) crystals with high stacking fault energy have a higher probability of forming annealing twins", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对堆垛层错能与退火孪晶形成概率关系这一基本概念的记忆和理解，属于基础概念记忆范畴。 | 难度: 在选择题中属于中等偏下难度，需要理解堆垛层错能与退火孪晶形成概率之间的关系这一基础概念，并进行简单辨析。虽然涉及基本原理的记忆，但选项之间的区分度较高，正确选项较为明显。" + }, + { + "idx": 1880, + "question": "Under the same system and the same degree of supercooling, the heterogeneous nucleation rate is always the homogeneous nucleation rate. A. Greater than or equal to B. Less than or equal to C. Equal to D. Not necessarily", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查的是对均相成核和非均相成核速率比较的基本概念记忆和理解，属于基础概念层次的知识点。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察的是对异质成核和均质成核速率关系的直接记忆。虽然需要理解\"相同系统和相同过冷度\"条件下的比较关系，但选项提供了明确的对比方向（A选项直接给出了正确关系），不需要复杂的分析或推导。因此属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3555, + "question": "Fick's first law describes the characteristics of steady-state diffusion, where the concentration does not vary with ( ). \\n\\nA. distance B. time C. temperature", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查Fick第一定律的基本概念，即稳态扩散中浓度不随时间变化这一关键特征的理解和记忆，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目考察的是Fick第一定律的基本定义，即稳态扩散中浓度不随时间变化。选项B是直接对应这一基本概念的正确答案，无需复杂分析或深度理解。" + }, + { + "idx": 2931, + "question": "Two parallel screw dislocations, when their Burgers vectors are in the same direction, the interaction force between them is (A) zero (B) repulsive (C) attractive", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于两个平行螺位错相互作用力的正确答案 | 知识层次: 题目考查对平行螺型位错相互作用力的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解螺位错相互作用的基本原理，并能够区分不同Burgers向量方向下的相互作用力类型（排斥或吸引）。这比单纯记忆定义（等级1）要求更高，但不需要复杂的分析或比较（等级3）。" + }, + { + "idx": 3960, + "question": "Based on the previous two sub-questions, which of the four metals or alloys listed below are possible candidates for the cylindrical rod that will neither experience plastic deformation nor an elongation of more than 0.9mm under a tensile load of 24,500 N?", + "answer": "The only candidate material that satisfies both conditions is the Steel alloy, with an elongation of 0.57 mm.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从四个金属或合金选项中选择符合条件的候选材料，答案明确指出唯一符合条件的材料是钢合金，符合选择题的特征。 | 知识层次: 题目要求在多步计算和综合分析的基础上，从多个候选材料中选择满足特定条件的材料。这需要理解材料的力学性能（如塑性变形和伸长量）并进行相关计算，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要综合应用多个概念（如塑性变形、弹性伸长、材料性能等）进行多步计算和判断。题目要求考生不仅能够理解材料的基本性能，还需要能够将这些性能与具体工程条件（负载、变形限制）关联起来，进行综合分析。这种需要结合多个知识点和计算步骤的选择题，在选择题型中属于复杂分析过程的判断难度等级。" + }, + { + "idx": 3083, + "question": "What materials can be used to manufacture the vehicle body itself? Options: A. Carbon fiber resin composite material B. Thermosetting fiberglass C. Boron fiber resin composite material", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对车辆制造材料的基础概念记忆，只需从给定选项中选择正确的材料类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和直接回忆材料科学中的基本分类知识。选项明确且直接对应车辆制造中常用的材料，无需复杂辨析或深度理解。" + }, + { + "idx": 3903, + "question": "Which of the following microstructures is expected to be most similar to a single crystal in terms of structure and properties? Assume all of the options offer the same volumes and only consider grain boundaries as a crystalline defect for this question. (a) Textured polycrystal with about 10,000 grains (b) Random polycrystal with about 1,000,000 grains (c) Random polycrystal with about 1,000,000,000 grains (d) Amorphous", + "answer": "(a) Textured polycrystal with about 10,000 grains", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择最接近单晶结构和性能的微观结构，答案是从给定的选项中选择一个正确答案。 | 知识层次: 题目需要理解单晶和多晶的结构差异，并分析晶粒数量和取向对性能的影响。虽然涉及基础概念，但需要综合分析不同选项的微观结构特征，才能得出最接近单晶的选项。 | 难度: 在选择题中属于较高难度，需要综合理解晶体结构、晶界影响以及织构效应等多个概念。题目要求比较不同微观结构对单晶相似性的影响，涉及多步分析过程：首先需要排除非晶选项（d），然后比较随机多晶与织构多晶的晶界密度差异（b/c vs a），最后评估织构效应对性能的影响。这种综合分析过程超出了简单概念识别的范畴，属于复杂分析判断的题型要求。" + }, + { + "idx": 3919, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?\n\\[\n\\alpha=\\beta=90^{\\circ}, \\gamma=120^{\\circ}\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "Only the hexagonal crystal system has two of the interaxial angles equal to 90^{\\circ}, while the third angle is equal to 120^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的正确答案 | 知识层次: 题目考查对晶体系统基本参数（轴角关系）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆不同晶系的轴角关系，但题目明确给出了具体的角度条件，只需将条件与各晶系的基本定义进行匹配即可。不需要复杂的分析或推导，属于基础概念理解和简单辨析的范畴。" + }, + { + "idx": 3884, + "question": "Materials Science and Engineering is the study of material behavior & performance and how this is simultaneously related to structure, properties, and processing. Which of the following is the best example of material structure? (a) Single-phase (b) Elastic Modulus (c) Sintering (d) Magnetic Permeability (e) Brittle", + "answer": "(a)Single-phase", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择最佳答案，符合选择题的特征 | 知识层次: 题目考查对材料结构这一基础概念的记忆和理解，要求从选项中识别出最能代表材料结构的例子，属于基础概念记忆性知识。 | 难度: 在选择题型中，此题属于简单概念识别，直接记忆的题目。题目要求识别\"material structure\"的最佳例子，正确选项(a)Single-phase是材料结构的基础概念之一，无需复杂理解或分析，只需记忆相关定义即可作答。" + }, + { + "idx": 3992, + "question": "Deformation of a semicrystalline polymer by drawing produces which of the following perpendicular to the direction of drawing?", + "answer": "Decrease in strength perpendicular to the direction of drawing.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，虽然题目中没有明确列出选项，但答案的形式表明这是一个选择题，需要从多个可能的选项中选择正确的描述。 | 知识层次: 题目考查半结晶聚合物在拉伸变形时垂直于拉伸方向的性能变化，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然涉及半结晶聚合物变形的基本概念，但只需理解拉伸方向与强度变化的关系即可作答，无需复杂分析或多个概念的交叉比较。属于基础概念理解和简单辨析层次。" + }, + { + "idx": 2767, + "question": "The difference between cast iron and carbon steel lies in the presence of", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案形式为选项字母（A） | 知识层次: 题目考查对铸铁和碳钢之间差异的基础概念记忆，仅需识别铸铁中特有的元素存在即可回答，属于定义性知识范畴 | 难度: 在选择题型中，该题目仅需识别和记忆基础概念（铸铁与碳钢的区别在于某种成分的存在），属于直接记忆性知识，无需复杂理解或分析步骤。" + }, + { + "idx": 1809, + "question": "In the non-stoichiometric compound Cd1+xO, the type of non-stoichiometric structural defect present is a. anion vacancy b. cation vacancy c. anion interstitial d. cation interstitial", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查非化学计量化合物中缺陷类型的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生识别非化学计量化合物Cd1+xO中的缺陷类型。虽然涉及特定缺陷类型的记忆（阳离子间隙），但不需要复杂的分析或概念间的比较，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3060, + "question": "What type of chemical bond is primarily found in carbides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对碳化物中主要化学键类型的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆碳化物的主要化学键类型，但选项中的概念区分较为明确（金属键、共价键、分子键、离子键），且共价键是碳化物最典型的键型这一知识点在基础化学中较为常见。不过仍需要一定的概念理解能力来排除其他干扰选项，因此属于等级2难度。" + }, + { + "idx": 1749, + "question": "In a ternary system phase diagram, if there are n boundary lines, then the number of connecting lines that can be drawn in this phase diagram is . a. 3 b. n - 1 c. n d. n+1", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a. 3 b. n - 1 c. n d. n+1）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对三元相图中边界线和连接线数量关系的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（三元系统相图的边界线和连接线数量关系），但需要考生理解相图的基本构造原理和边界线与连接线之间的对应关系，而不仅仅是简单的定义记忆。正确选项需要考生通过基本概念的理解进行简单辨析，因此属于等级2难度。" + }, + { + "idx": 1810, + "question": "Among various layered silicate structures, the unit cell parameters that are similar are a.a0 and b0 b.a0 and c0 c.c0 and b0 d.c0", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项a、b、c、d中选择正确答案 | 知识层次: 题目考查对层状硅酸盐结构单元晶胞参数的基本概念记忆，只需识别相似参数即可，不涉及复杂分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别和回忆层状硅酸盐结构中单元晶胞参数的相似性。题目直接给出了正确选项，无需复杂辨析或深度理解，属于选择题型中最简单的难度等级。" + }, + { + "idx": 1740, + "question": "The space lattice is an abstraction derived from the ____ in the crystal structure. a. atoms b. ions c. geometric points d. equivalent points", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对晶体结构中空间点阵这一基础概念的记忆和理解，属于定义性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解空间点阵是从晶体结构中的等效点抽象出来的概念，并进行简单的概念辨析。虽然涉及基础概念记忆，但需要区分几何点和等效点的差异，比单纯记忆定义稍复杂。" + }, + { + "idx": 3564, + "question": "For two parallel screw dislocations, when their Burgers vectors are in the same direction, the interaction force between them is (). \\n\\nA. zero B. repulsive C. attractive", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对平行螺型位错相互作用力的基本概念记忆，属于对位错基本性质的理解和记忆性知识 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解平行螺型位错之间的相互作用力与Burgers向量方向的关系，并进行简单辨析。题目不涉及复杂概念的区分或深度理解，但比直接记忆的定义类题目稍难。" + }, + { + "idx": 733, + "question": "The crystal structure with point group $\\\\bf F m3m$ belongs to the crystal system. (a) cubic (b) hexagonal (c) tetragonal (d) orthorhombic", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)(b)(c)(d)中选择正确答案 | 知识层次: 题目考查对晶体结构和点群分类的基础概念记忆，只需识别$F m3m$属于立方晶系即可，无需复杂分析或计算。 | 难度: 该题目属于基础概念记忆类型，仅需识别点群符号$F m3m$对应的晶系即可。在选择题型中，这是最直接的记忆性知识应用，无需复杂理解或辨析步骤。" + }, + { + "idx": 1993, + "question": "Among the three common crystal structures of metals, which structure cannot serve as a space lattice?", + "answer": "Hexagonal close-packed structure", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从三种常见的金属晶体结构中选择一个不能作为空间点阵的结构，属于从多个选项中选择正确答案的类型 | 知识层次: 题目考查对金属常见晶体结构及其空间点阵特性的基础概念记忆，属于定义和分类层面的记忆性知识 | 难度: 在选择题型中，此题需要考生理解三种常见金属晶体结构（体心立方、面心立方和六方密堆）的基本概念，并能够区分空间点阵（Bravais点阵）与晶体结构的区别。虽然题目考察的是基础概念记忆，但需要一定的概念辨析能力，因为六方密堆结构本身不是空间点阵（它需要两个点来描述完整结构）。这比单纯记忆定义（等级1）要求稍高，但不需要复杂的分析过程（等级3）。" + }, + { + "idx": 1741, + "question": "According to the law of rational indices, the coordinate axes in a crystal structure should be selected in the direction of . a．mutually perpendicular b．close-packed planes c．rows in the crystal", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项a、b、c中选择正确答案，符合选择题的特征 | 知识层次: 题目考查晶体结构中坐标轴选择方向的基本概念记忆，属于对\"有理指数定律\"基础知识的直接考察。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然考察的是基础概念记忆，但需要学生对\"law of rational indices\"有基本理解，并能区分\"rows in the crystal\"与其他选项的区别。相比直接记忆定义（等级1），此题需要一定的概念辨析能力（等级2），但不需要复杂的分析推理（等级3）。" + }, + { + "idx": 4652, + "question": "What type(s) of bonding would be expected for rubber?\n(A) Ionic bonding\n(B) Metallic bonding\n(C) Covalent bonding with some van der Waals bonding\n(D) van der Waals bonding", + "answer": "FE}\nThe correct answer is C. For rubber, the bonding is covalent with some van der Waals bonding. (Rubber is composed primarily of carbon and hydrogen atoms.)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了四个选项（A-D），并给出了正确答案C。这是典型的选择题形式。 | 知识层次: 题目考查对橡胶材料键合类型的基本概念记忆和理解，属于基础知识点，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解橡胶的化学键类型（共价键和范德华力），但选项之间的区分较为明显，不需要复杂的分析过程。学生只需掌握基本的材料键合类型知识即可正确作答。" + }, + { + "idx": 3009, + "question": "Silicate glass, mica, and asbestos belong to which category of compounds? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对无机聚合物分类的基本概念记忆，只需识别给定的材料属于哪一类化合物，不涉及复杂的应用或分析过程。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需识别无机聚合物的常见实例（硅酸盐玻璃、云母、石棉）。选项区分明显，无需复杂分析或概念辨析，符合等级1\"简单概念识别，直接记忆\"的标准。" + }, + { + "idx": 3967, + "question": "Mechanical twinning occurs in metals having which type(s) of crystal structure(s)?(a) \\mathrm{BCC}(b) \\mathrm{FCC}(c) \\mathrm{HCP}", + "answer": "Mechanical twinning occurs in metals having B C C and H C P crystal structures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，提供了多个选项（a、b、c），并且答案是从这些选项中选择的。 | 知识层次: 题目考查对金属晶体结构中机械孪生现象发生条件的记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（机械孪生发生的晶体结构类型），但需要学生对BCC、FCC和HCP三种晶体结构的基本特性有一定理解，并能区分哪种结构会发生机械孪生现象。这超出了简单的概念识别（等级1），但尚未达到需要深度理解和复杂概念区分的程度（等级3）。学生需要掌握晶体结构的基本知识，并能进行简单的辨析判断。" + }, + { + "idx": 3632, + "question": "Would you expect BeO to have the sodium chloride, zinc blende, or fluorite structure?", + "answer": "BeO has the zinc blende structure.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的三种晶体结构（sodium chloride, zinc blende, fluorite）中选择BeO最可能具有的结构类型，符合选择题的特征。 | 知识层次: 题目考查对BeO晶体结构的基础概念记忆，属于对特定材料晶体结构的直接认知，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对BeO的晶体结构有明确的理解，并能将其与钠氯化物、闪锌矿和萤石结构进行区分。这要求考生不仅记住BeO的结构类型，还需要理解不同晶体结构的特点及其适用条件。因此，相较于简单的概念识别（等级1），该题目需要更深一层的概念理解和简单辨析（等级2）。" + }, + { + "idx": 3113, + "question": "The active layer and passive layer of a thermostatic bimetal strip are respectively (1). A. Constant expansion alloy and high expansion alloy B. High expansion alloy and constant expansion alloy C. Constant expansion alloy and low expansion alloy D. High expansion alloy and low expansion alloy", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了四个选项供选择，符合选择题的特征。 | 知识层次: 题目考查对热双金属片主动层和被动层材料分类的基础概念记忆，属于定义和分类的基本原理记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然考察的是基础概念记忆（热双金属片的主动层和被动层材料），但需要考生区分高膨胀合金和低膨胀合金的概念，并进行简单配对。相比纯粹的定义复述（等级1），此题需要一定的概念理解和材料特性辨析能力，但不需要复杂的分析过程（等级3）。正确选项D的区分度主要体现在对\"高/低膨胀\"这一组对立概念的掌握上。" + }, + { + "idx": 3245, + "question": "The correct order of coordination numbers for the following alloy phases from small to large is A.SiC、NaCl、a-Fe、Cu B.a-Fe、SiC、Cu、NaClC.a-Fe、Cu、SiC、NaCl D.SiC、a=Fe、NaCl、Cu", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的配位数顺序，答案形式为选项A，符合选择题的特征。 | 知识层次: 题目考查对合金相配位数顺序的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目需要考生理解和辨析不同合金相的配位数概念，并进行排序比较。虽然涉及多个材料的配位数记忆，但属于基础概念的理解和简单应用，不需要复杂的分析或深度推理。因此属于中等难度（等级2）。" + }, + { + "idx": 2972, + "question": "In the Kirkendall effect, the main reason for marker shift in a diffusion couple is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项标记（C）作为答案 | 知识层次: 题目考查Kirkendall效应的基本原理和原因，属于基础概念的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解Kirkendall效应的基本原理和标记物移动的原因，但不需要进行复杂的概念区分或深度分析。" + }, + { + "idx": 1427, + "question": "Which is the most closely packed plane in a face-centered cubic crystal?", + "answer": "111", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个可能的晶体平面中选择最紧密堆积的平面，虽然题目中没有明确列出选项，但这类问题通常是在给定的选项中进行选择，答案\"111\"是一个特定的选项。 | 知识层次: 题目考查对晶体结构中最密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆类型。学生只需记住面心立方晶体中最密排面是(111)面这一基本事实即可作答，无需进行复杂的概念辨析或深度理解。" + }, + { + "idx": 4042, + "question": "How does increasing temperature affect the concentration of both electrons and holes in an intrinsic semiconductor?(a) Increases the concentration.(b) Decreases the concentration.(c) May increase and/or decrease the concentration, depending on the temperature range.", + "answer": "Increasing temperature increases the concentration of both electrons and holes in an intrinsic semiconductor.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对温度如何影响本征半导体中电子和空穴浓度的基本原理的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆温度对半导体中电子和空穴浓度的影响这一基本原理。题目选项设计简单，正确选项直接对应基础知识点，无需复杂分析或概念区分。因此属于最简单的难度等级1。" + }, + { + "idx": 2935, + "question": "The dislocation that cannot undergo climb motion is (A) Shockley partial dislocation (B) Frank partial dislocation (C) edge perfect dislocation", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(A)、(B)、(C)中选择一个正确答案 | 知识层次: 题目考查对位错类型及其运动方式的基本概念记忆和理解，属于材料科学中晶体缺陷的基础知识范畴。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生理解不同类型位错（Shockley partial dislocation、Frank partial dislocation、edge perfect dislocation）的基本特性，并能够区分它们之间的运动方式。特别是需要知道Shockley partial dislocation不能进行climb motion这一特定知识点。这比单纯记忆定义要复杂一些，但不需要进行深度分析或多概念比较。" + }, + { + "idx": 3088, + "question": "What materials can be used to manufacture rocket supports? Options: A. Carbon fiber resin composite B. Thermosetting fiberglass C. Boron fiber resin composite", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对火箭支撑材料的基本概念记忆，只需要从给定的选项中选择正确的材料类型，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，此题需要考生理解不同复合材料的基本特性及其在火箭支撑结构中的应用。虽然选项都是复合材料，但需要考生对硼纤维树脂复合材料的特殊性能（如高强度、高刚度）有一定了解才能正确选择。这超出了简单的概念识别（等级1），但尚未达到需要复杂概念区分（等级3）的程度。" + }, + { + "idx": 4135, + "question": "This ceramic outlier has the highest room-temperature thermal conductivity of about 2,000 watts per meter per kelvin, a value that is five time higher than the best thermally conductive metals.\n(a) \\mathrm{Al}_{2} \\mathrm{O}_{3}\n(b) \\mathrm{CaF}_{2}\n(c) \\mathrm{TiO}_{2}\n(d) \\mathrm{SrTiO}_{3}\n(e) C (diamond)", + "answer": "Diamond has the highest thermal conductivity of these options.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择具有最高室温热导率的陶瓷材料，答案形式为选择特定选项。 | 知识层次: 题目考查对材料热导率这一基本概念的记忆和理解，特别是对特定材料（如金刚石）的热导率特性的记忆。题目不涉及复杂的计算或分析，只需从选项中识别出具有最高热导率的材料。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别具有最高室温热导率的陶瓷材料。正确选项（diamond）是常见的高热导率材料，属于直接记忆性知识，无需复杂分析或理解多个概念。" + }, + { + "idx": 3900, + "question": "Materials whose constituent particles are bound by which type of bond are generally expected to have the lowest melting temperatures?(a) Covalent(b) Metallic(c) Ionic(d) Van der Waals(e) Hydrogen", + "answer": "(d) Van der Waals", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项中的一个 | 知识层次: 题目考查对不同类型化学键及其性质的基本概念的记忆和理解，特别是范德华力与其他化学键在熔点方面的差异。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别不同化学键类型及其一般性质（如熔点）。Van der Waals键是最弱的分子间作用力，其熔点最低是直接记忆性知识，无需复杂分析或概念辨析。" + }, + { + "idx": 4055, + "question": "The charge carriers in ionic ceramics and polymers can be(a) Electrons(b) Holes(c) Anion(d) Cations", + "answer": "The charge carriers in ionic ceramics and polymers can be electrons, holes, anions, and/or cations.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项（a）Electrons（b）Holes（c）Anion（d）Cations中选择正确的电荷载流子类型，符合选择题的特征。 | 知识层次: 题目考查对离子陶瓷和聚合物中电荷载流子的基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解并区分不同类型的电荷载流子（电子、空穴、阴离子、阳离子）在离子陶瓷和聚合物中的存在情况。这要求考生不仅记住定义，还需要对这些概念有一定的理解和辨析能力。" + }, + { + "idx": 3016, + "question": "The usage state of plastic is (). A. Crystalline state B. Glassy state C. High elastic state D. Viscous flow state", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择塑料使用状态的正确答案 | 知识层次: 题目考查塑料使用状态的基本概念记忆，属于对材料科学基础知识的直接考察，无需复杂推理或综合分析。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别塑料的使用状态为玻璃态（Glassy state），无需复杂辨析或深度理解。题目直接考察定义性知识，属于简单概念识别。" + }, + { + "idx": 2757, + "question": "The ordered structure formation temperature of any alloy is _____ the disordered structure formation temperature. (A) Lower than (B) Higher than (C) May be lower or higher than", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案 | 知识层次: 题目考查对合金有序结构和无序结构形成温度关系的基本概念记忆，属于基础概念的理解和记忆层次。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆合金有序结构和无序结构的形成温度关系。选项明确且无需复杂分析，属于最简单的概念识别层次。" + }, + { + "idx": 3566, + "question": "The dislocation that cannot undergo climb motion is (). \\n\\nA. Shockley partial dislocation B. Frank partial dislocation C. Edge full dislocation", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对位错类型及其运动特性的基础概念记忆，特别是Shockley部分位错、Frank部分位错和刃型全位错的基本特性区分，属于定义和分类层面的记忆性知识。 | 难度: 在选择题型中，该题目需要考生理解不同类型位错（Shockley partial dislocation, Frank partial dislocation, Edge full dislocation）的基本特性，并能够辨析它们之间的差异。虽然题目涉及的是基础概念记忆，但需要考生对位错运动机制（如climb motion）有基本的理解才能正确选择答案。这比单纯记忆定义（等级1）要求更高，但不需要进行复杂的分析或推理（等级3）。" + }, + { + "idx": 4142, + "question": "With increasing temperature antiferromagnetic materials eventually become which of the following?(a) Diamagnetics(b) Paramagnetics(c) Ferromagnetics(d) Antiferromagnetics(e) Ferrimagnetics", + "answer": "With increasing temperature antiferromagnetic materials eventually become paramagnetic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为从给定选项中选择一个最合适的选项。 | 知识层次: 题目考查对反铁磁材料在温度升高时转变为顺磁性这一基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解反铁磁材料在温度升高时的行为变化，但只需掌握基础概念（反铁磁性与顺磁性的转变关系）即可作答，不需要进行复杂的概念区分或多步骤推理。属于概念理解和简单辨析的层次。" + }, + { + "idx": 3560, + "question": "In the concentration triangle of a ternary phase diagram, alloys whose compositions lie on the () have equal contents of the two components represented by the other two vertices.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查对三元相图浓度三角形中特定组成线的基本概念记忆，只需识别等含量线的基本定义即可作答，不涉及计算或复杂分析。 | 难度: 在选择题中属于简单难度，仅需直接记忆三元相图中浓度三角形的定义即可选出正确答案，无需复杂理解或分析步骤。" + }, + { + "idx": 3559, + "question": "In a binary phase diagram, the lever rule for calculating the relative amounts of two phases can only be applied in ().", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（B）作为答案 | 知识层次: 题目考查对二元相图中杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察对杠杆规则应用条件的直接记忆。虽然需要理解杠杆规则的基本原理，但题目仅要求识别正确应用场景，无需复杂分析或概念区分，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 4161, + "question": "A completely amorphous and nonporous polymer will be(a) Transparent(b) Translucent(c) Opaque", + "answer": "A completely amorphous and nonporous polymer will be transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查对非晶态聚合物光学性质这一基本概念的记忆和理解，属于材料科学基础知识的直接应用，不需要复杂的分析或计算过程。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目考察的是对非晶态无孔聚合物透明性的基础概念记忆，无需复杂分析或深度理解，只需记住相关定义即可正确回答。" + }, + { + "idx": 1814, + "question": "In the sintering process, the mass transfer method that only changes the pore shape without causing shrinkage of the green body is a. diffusion mass transfer b. flow mass transfer c. evaporation-condensation mass transfer d. grain boundary diffusion", + "answer": "c", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查烧结过程中质量传递方式的基本概念记忆，特别是蒸发-凝聚质量传递的特点，属于基础概念的记忆和理解。 | 难度: 该题目属于基础概念记忆层次，要求考生识别烧结过程中不同传质方式的特点。虽然需要理解蒸发-凝聚传质与其他传质方式的区别，但题目直接给出了关键特征（不引起收缩），属于概念理解和简单辨析的难度级别。在选择题型中，不需要复杂的分析过程，只需将特征与选项对应即可。" + }, + { + "idx": 3970, + "question": "As dislocation density increases, the resistance to dislocation movement(a) increases.(b) decreases.", + "answer": "As dislocation density increases, the resistance to dislocation movement increases. This phenomenon is responsible for cold working.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案 | 知识层次: 题目考查位错密度与位错运动阻力关系的基本概念记忆，属于材料科学中位错理论的基础知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，此题属于基础概念的直接记忆，仅需识别位错密度增加与位错运动阻力之间的关系，无需复杂分析或概念辨析。" + }, + { + "idx": 2975, + "question": "In substitutional solid solutions, the mode of atomic diffusion is generally", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项标记（C）作为答案 | 知识层次: 题目考查的是置换固溶体中原子扩散方式的基本概念记忆，属于材料科学中最基础的知识点之一，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别\"substitutional solid solutions\"中原子的扩散方式这一简单概念。题目直接考察定义性知识，无需理解或辨析过程，属于最基础的选择题难度等级。" + }, + { + "idx": 3918, + "question": "Which crystal system(s) listed below has (have) the following interaxial angle relationship?(a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic\ng) Triclinic", + "answer": "Cubic, tetragonal and orthorhombic crystal systems all have the three interaxial angles equal to 90^{\\circ}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定晶体系统特征的选项，答案给出了具体的选项组合，符合选择题的特征。 | 知识层次: 题目考查对晶体系统基本特征（晶轴角度关系）的记忆和理解，属于基础概念记忆范畴 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及多个晶体系统的记忆，但只需要识别具有特定角度关系（三个轴间角均为90度）的系统。这需要一定的概念理解和简单辨析能力，但不需要复杂的分析或深度理解。" + }, + { + "idx": 4020, + "question": "Complete the following statement regarding conditions that must be satisfied in order for a solid solution to exhibit extensive solubility. The solute and host species must have a very [w] sizes. (w = similar, different)", + "answer": "The solute and host species must have a very similar sizes.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项（similar, different）中选择一个正确答案来填空 | 知识层次: 题目考查对固溶体溶解度条件的基本概念记忆，仅需知道溶质和溶剂原子尺寸相似性这一基本原理即可作答，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度等级。题目仅要求考生回忆并选择正确的定义性知识（\"similar sizes\"），无需进行概念辨析或深度理解。这种类型的题目在选择题中属于最基础的难度级别。" + }, + { + "idx": 3035, + "question": "Rubber is an excellent damping material and friction material due to its outstanding (1). A. High elasticity B. Viscoelasticity C. Plastic D. Anti-friction", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查橡胶材料的基本特性记忆，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目仅需识别橡胶的基本特性（高弹性），属于直接记忆的基础概念，无需复杂辨析或深度理解。题目选项设置简单明确，正确选项A与其他选项区分明显，符合等级1的简单概念识别标准。" + }, + { + "idx": 1744, + "question": "In the non-stoichiometric compound ZrO2-x, the lattice defect present is a. anion vacancy b. cation vacancy c. anion interstitial d. cation interstitial", + "answer": "a", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查非化学计量化合物中晶格缺陷类型的基本概念记忆，仅需识别ZrO2-x中存在的缺陷类型（阴离子空位），无需复杂分析或计算。 | 难度: 在选择题型中，该题目需要理解非化学计量化合物ZrO2-x中的晶格缺陷类型，并能够区分阴离子空位、阳离子空位、阴离子间隙和阳离子间隙等概念。虽然题目涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，因此属于等级2难度。" + }, + { + "idx": 1745, + "question": "a≠b≠c,α≠β≠γ crystals belong to the crystal system. a. cubic b. hexagonal c. tetragonal d. orthorhombic", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项（a. cubic b. hexagonal c. tetragonal d. orthorhombic）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查晶体系统分类的基本概念记忆，只需记住不同晶体系统的晶格参数特征即可选择正确答案。 | 难度: 在选择题中属于中等偏下难度，需要理解晶体系统的基本分类和特征，并能根据题目描述的条件（a≠b≠c,α≠β≠γ）进行简单辨析，但不需要复杂的分析或深度理解多个概念。" + }, + { + "idx": 3926, + "question": "For most polymers, which configuration predominates?(a) Head-to-head(b) Head-to-tail", + "answer": "For most polymers, the head-to-tail configuration predominates.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的两个选项(a) Head-to-head和(b) Head-to-tail中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对聚合物基本构型（head-to-head和head-to-tail）的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆聚合物最常见的构型（头-尾构型）即可作答。题目选项简单明确，无需复杂分析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 3937, + "question": "Which of these elements would you expect to form an interstitial solid solution with copper? The elements are: C, Pd, Pt, H, Cr, O, Zn, Ag, Al, Co, Fe, Ni. The criteria for interstitial solid solutions are: these elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "answer": "C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Cu.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的元素列表中选择符合特定条件（原子半径显著小于铜）的元素，这符合选择题的特征，即从多个选项中选择正确答案。 | 知识层次: 题目考查对间隙固溶体形成条件的记忆和理解，即哪些元素的原子半径显著小于铜的原子半径。这属于基础概念的记忆性知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目需要考生理解间隙固溶体的定义和形成条件，即溶质原子半径必须显著小于溶剂原子半径。虽然题目给出了多个选项，但正确选项（C, H, O）可以通过记忆或简单比较原子半径得出。因此，该题目属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3891, + "question": "The atomic number of an electrically neutral atom is equal to the number of:(a) protons (b) electrons (c) neutrons (d)Choose all that apply.", + "answer": "(b)electrons.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，并且提供了明确的选项(a)-(d)，符合选择题的特征。 | 知识层次: 题目考查原子序数与电子数的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目仅需直接记忆原子序数与电子数的关系，属于基础概念记忆层次，无需复杂分析或理解多个概念。" + }, + { + "idx": 3046, + "question": "What type of chemical bond is primarily found in nitrides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对化学键类型的基本概念记忆和理解，属于基础概念记忆性知识 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要记忆氮化物中主要的化学键类型（共价键），但选项中的其他键类型（金属键、分子键、离子键）与共价键有较明显的区别，只需基础的概念理解和简单辨析即可选出正确答案。不需要复杂的分析或深度理解多个概念之间的关系。" + }, + { + "idx": 2957, + "question": "The main reason why it is difficult to form a single-phase structure in polymer alloys is that the alloy has (A) smaller mixing entropy (B) opposite to (A) (C) smaller mixing heat", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物合金形成单相结构困难原因的基础概念记忆，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（聚合物合金的单相结构形成困难的主要原因），但需要考生理解并区分\"混合熵\"和\"混合热\"这两个概念。正确选项A（较小的混合熵）需要考生对聚合物合金的基本原理有一定理解，而不仅仅是简单的概念识别。不过题目没有涉及更复杂的分析或多概念综合比较，因此难度属于等级2。" + }, + { + "idx": 3061, + "question": "What material is suitable for the handle of a test pen? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramic D.Manganese brass", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择最适合用于测试笔手柄的材料，答案形式为单一选项（A）。 | 知识层次: 题目考查对材料基本性质和适用场景的记忆和理解，属于基础概念记忆范畴。 | 难度: 该题目属于基础概念记忆类型，仅需识别和记忆常见材料的应用场景。选项A（Polyvinyl chloride）是测试笔手柄的常见材料，属于直接记忆性知识，无需复杂理解或辨析。其他选项虽然涉及不同材料，但题目要求的是基础应用场景的识别，因此难度等级为1。" + }, + { + "idx": 3057, + "question": "What can silicon nitride ceramics be used for? Options: A. Grinding wheel B. Blade C. Cutting tool D. Abrasive E. Crucible", + "answer": "A,D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项列表和答案组合 | 知识层次: 题目考查对氮化硅陶瓷用途的基础概念记忆，只需从选项中识别其典型应用场景，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别硅氮化物陶瓷的基本用途。选项直接对应材料的基本应用领域（研磨轮和磨料），无需复杂辨析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 3013, + "question": "The form of polymer with the lowest expansion coefficient is (1). A. Linear B. Branched C. Crosslinked", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，且答案形式为选项编号，符合选择题的特征 | 知识层次: 题目考查对聚合物结构类型（线性、支化、交联）及其基本性质（膨胀系数）的记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别聚合物形式与膨胀系数之间的基本关系。选项直接对应记忆性知识，无需复杂辨析或深度理解，属于选择题型中最简单的难度等级。" + }, + { + "idx": 1284, + "question": "According to the phase rule, when the degrees of freedom in a ternary system are zero, it is represented on the phase diagram as", + "answer": "plane", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，虽然题目中没有明确给出选项，但答案\"plane\"暗示这是一个选择题的答案选项之一 | 知识层次: 题目考查对相律基础概念的记忆和理解，涉及自由度为零时在三元相图中的表示方式，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆相律在多元系统中的自由度与相图表示的关系。题目明确给出了正确选项，无需复杂辨析或深度理解，属于最简单的概念识别类型。" + }, + { + "idx": 3236, + "question": "At room temperature, the plastic deformation modes of metal polycrystals are A. Slip, twinning, creep B. Slip, twinning, kinking C. Slip, climb, cross-slip D. Slip, twinning, grain boundary sliding", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C、D）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查金属多晶体在室温下的塑性变形模式的基本概念记忆，属于基础概念记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解金属多晶体在室温下的塑性变形模式，并对选项中的概念进行简单辨析。虽然涉及多个变形模式（滑移、孪生、扭折），但这些都是基础概念，不需要复杂的分析或深度理解即可选出正确答案。" + }, + { + "idx": 3562, + "question": "The packing density of a simple cubic crystal is ( ). \\n\\nA. $100\\\\%$ B.65% C.52% D.58%", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（A、B、C、D）中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查简单立方晶体堆积密度的基本概念记忆，属于晶体结构的基础知识，不需要复杂的计算或分析。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆简单立方晶体的堆积密度数值即可作答，无需进行概念辨析或复杂计算。" + }, + { + "idx": 2763, + "question": "The driving force for atomic diffusion is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查原子扩散驱动力的基本概念记忆，属于材料科学中最基础的定义性知识，不需要复杂的分析或应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别\"原子扩散驱动力\"这一简单概念的定义即可作答。在选择题型中属于直接记忆类题目，无需理解或辨析过程，符合等级1的简单概念识别标准。" + }, + { + "idx": 737, + "question": "In the non-stoichiometric compound $\\\\operatorname{Cd}_{1+x}0$, the lattice defect present is (a) anion vacancy (b) cation vacancy (c) anion interstitial (d) cation interstitial", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)到(d)中选择正确答案 | 知识层次: 题目考查对非化学计量化合物中晶格缺陷类型的基础概念记忆和理解，只需识别Cd1+xO中存在的缺陷类型即可，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及非化学计量化合物的晶格缺陷这一基础概念，但需要考生理解并区分不同类型的缺陷（如空位和间隙）。正确选项（d）要求考生能够识别出阳离子间隙的存在，这需要一定的概念理解和简单辨析能力，而不仅仅是直接记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 3898, + "question": "To what group in the periodic table would an element with atomic number 119 belong?(a) Group 0 (or 18) (b) Group IA (or 1) (c) Group IIA (or 2) (d) Group VIIA (or 17)", + "answer": "(b) Group IA (or 1)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的四个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查元素周期表分组的记忆和理解，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念记忆层次，要求考生记住元素周期表中原子序数与族的关系。虽然需要记忆元素119的归属族，但这是周期表排列的基本规律之一，属于中等偏下的难度。在选择题型中，考生只需识别并回忆相关知识，无需复杂推理或分析。" + }, + { + "idx": 3052, + "question": "The porosity of ordinary ceramics is (2). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(2)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查普通陶瓷孔隙率的基本概念记忆，属于定义性知识的直接回忆，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需直接回忆普通陶瓷的孔隙率范围即可选出正确答案，无需复杂理解或分析步骤。" + }, + { + "idx": 743, + "question": "In the closest packing of equal large spheres, what is the packing arrangement of hexagonal close packing?", + "answer": "(5) ABAB……", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项编号形式给出 | 知识层次: 题目考查对六方最密堆积（hexagonal close packing）排列方式的基础概念记忆，只需要记住其层序排列为ABAB...即可回答，不涉及复杂计算或分析。 | 难度: 在选择题型中，该题目仅需要考生记忆并识别六方最密堆积（hexagonal close packing）的排列方式ABAB……，属于基础概念的直接记忆，无需理解或辨析其他复杂概念。因此，在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3914, + "question": "Which crystal system(s) listed below has (have) the following relationship for the unit cell edge lengths?\n\\[\na=b=c\n\\](a) Cubic(b) Hexagonal(c) Tetragonal(d) Rhombohedral(e) Orthorhombic(f) Monoclinic(g) Triclinic", + "answer": "For both cubic and rhombohedral crystal systems all the unit cell edge lengths are equal.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择符合特定条件的晶体系统，答案也是从给定的选项中选择的。 | 知识层次: 题目考查对晶体系统基本概念的记忆和理解，特别是对立方和菱方晶系单元边长关系的识别。 | 难度: 在选择题型内，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要考生对晶体系统的定义和分类有一定的理解和辨析能力。题目要求考生识别哪些晶体系统的晶胞边长满足a=b=c的关系，这需要考生不仅记住各个晶体系统的特点，还需要进行简单的比较和分析。因此，相较于直接记忆的简单概念识别（等级1），该题目更偏向于概念理解和简单辨析（等级2）。" + }, + { + "idx": 4006, + "question": "The effect of a stress raiser is more significant for which of the following types of materials?(a) Brittle materials(b) Ductile materials", + "answer": "The effect of a stress raiser is more significant for brittle materials. For a ductile material, plastic deformation ensues when the maximum stress exceeds the yield strength. This leads to a more uniform distribution of stress in the vicinity of the stress raiser and to the development of a maximum stress concentration factor less than the theoretical value. Such yielding and stress redistribution do not occur to any appreciable extent around flaws and discontinuities in brittle materials; therefore, essentially the theoretical stress concentration will result.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)和(b)中选择正确答案，属于选择题类型 | 知识层次: 题目考查对脆性材料和韧性材料在应力集中效应上的基本概念的理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要考生理解脆性材料和韧性材料在应力集中效应上的区别，并进行简单辨析。题目不涉及复杂概念区分或深度理解，但比单纯的概念识别要稍难一些。" + }, + { + "idx": 2920, + "question": "In the face-centered cubic (fcc) structure of aluminum crystal, the coordination number of each aluminum atom on the (111) plane is (A)12 (B) 6 (C) 4 (D) 3", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A）12、（B）6、（C）4、（D）3中选择正确答案 | 知识层次: 题目考查面心立方结构中(111)晶面上原子的配位数这一基本概念的记忆和理解，属于晶体学基础知识的直接应用。 | 难度: 在选择题中属于中等难度，需要理解面心立方结构的基本概念和(111)平面的原子排列，并进行简单的空间想象和计数。虽然不涉及复杂的计算或深度推理，但需要一定的晶体学基础知识。" + }, + { + "idx": 3051, + "question": "The porosity of cermet is (1). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(1)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对cermet孔隙率这一基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆金属陶瓷（cermet）的孔隙率范围即可作答。题目选项设置简单明确，无需进行概念辨析或复杂推理，完全符合等级1\"简单概念识别，直接记忆\"的特征。在选择题型中属于最基础的难度层级。" + }, + { + "idx": 4163, + "question": "Select the word combination that best completes this statement.\nWhen a semiconductor is exposed to a light source, its intrinsic carrier concentration will increase if the [a] of the light is [b] than band gap of the semiconductor.\n[a]: intensity, energy, wavelength, frequency, voltage, current, resistance\n[b]: greater, less", + "answer": "([a] energy\n[b] greater", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项组合中选择最佳答案来完成句子，符合选择题的特征 | 知识层次: 题目考查半导体材料的基本概念，即光照射对半导体本征载流子浓度的影响，以及光能量与半导体带隙的关系。这属于基础概念的记忆和理解范畴，不需要复杂的应用或分析。 | 难度: 在选择题中属于中等偏下难度，需要理解半导体光激发的基本原理，并正确匹配能量与带隙的关系。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力，而非单纯的直接记忆。" + }, + { + "idx": 3550, + "question": "The difference between cast iron and carbon steel lies in the presence or absence of ( )", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（A）作为答案 | 知识层次: 题目考查对铸铁和碳钢之间基本差异的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题中属于简单难度，仅需直接记忆铸铁和碳钢的基本区别（是否存在特定元素），无需理解或分析复杂概念。" + }, + { + "idx": 2978, + "question": "Network polymers cannot exhibit", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（C） | 知识层次: 题目考查对网络聚合物基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别网络聚合物不能表现的性质，属于直接记忆性知识，无需复杂分析或概念辨析。" + }, + { + "idx": 3943, + "question": "Diffusion by which mechanism occurs more rapidly in metal alloys?(a) Vacancy diffusion(b) Interstitial diffusion", + "answer": "In metal alloys, interstitial diffusion takes place more rapidly than vacancy diffusion because the interstitial atoms are smaller and are more mobile. Also, there are more vacant adjacent interstitial sites than there are vacancies.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从两个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对金属合金中扩散机制的基础概念记忆和理解，仅需区分空位扩散和间隙扩散的基本特点，不涉及复杂分析或综合应用。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解两种扩散机制（空位扩散和间隙扩散）的基本概念，但题目已经明确指出了关键区别（间隙原子更小、更易移动，且间隙空位更多），只需进行简单的概念辨析即可选出正确答案。不需要复杂的分析或推导过程，属于基础概念理解和简单辨析层次。" + }, + { + "idx": 3105, + "question": "High elastic alloys have (1). A. high elastic limit and high elastic modulus B. high elastic limit and low elastic modulus C. low elastic limit and high elastic modulus D. low elastic limit and low elastic modulus", + "answer": "(1)B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对高弹性合金基本特性的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然题目涉及高弹性合金的两个关键特性（弹性极限和弹性模量），但选项设计相对直接，只需理解高弹性合金的基本定义即可选出正确答案。不需要复杂的分析或多个概念的交叉比较，属于概念理解和简单辨析的层次。" + }, + { + "idx": 2924, + "question": "In polyethylene polymer materials, the C一H chemical bond belongs to (A) metallic bond (B) ionic bond (C) covalent bond (D) hydrogen bond", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项（A、B、C、D）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚乙烯材料中C一H化学键类型的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别C一H化学键的类型为共价键，无需复杂辨析或深度理解，属于简单概念识别。" + }, + { + "idx": 4706, + "question": "Which of these elements would you expect to form a substitutional solid solution having complete solubility with nickel? The four Hume-Rothery rules must be satisfied: (1) the difference in atomic radii between Ni and the other element (ΔR%) must be less than ±15%; (2) the crystal structures must be the same; (3) the electronegativities must be similar; and (4) the valences should be the same.", + "answer": "Pt is the only element that meets all of the criteria and thus forms a substitutional solid solution having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从给定的元素中选择满足Hume-Rothery规则的选项，并给出了具体的选择标准。答案明确指出Pt是唯一符合条件的元素，符合选择题的特征。 | 知识层次: 题目要求应用Hume-Rothery规则进行综合分析，涉及多个条件的判断（原子半径差异、晶体结构、电负性、价态），需要将多个概念关联起来进行推理，属于中等应用层次。虽然不涉及复杂计算，但需要综合运用多个知识点进行分析判断。 | 难度: 在选择题型中，该题目属于较高难度，原因如下：" + }, + { + "idx": 3557, + "question": "In the Kirkendall effect, the main reason for marker drift is ( ) in the diffusion couple.", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项和对应的答案选项\"C\" | 知识层次: 题目考查Kirkendall效应的基本概念和原因的记忆，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别Kirkendall效应的基本定义和原因。题目直接考察对\"marker drift\"主要原因的记忆，不需要复杂理解或辨析，符合等级1的简单概念识别标准。" + }, + { + "idx": 3059, + "question": "What material is suitable for a thermocouple sheath? Options: A.Polyvinyl chloride B.2Cr13 C.High-temperature ceramics D.Manganese brass", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择适合用于热电偶护套的材料，且提供了四个具体选项和唯一正确答案 | 知识层次: 题目考查对热电偶套管材料选择的基本概念记忆，只需知道高温陶瓷具有耐高温特性这一基础知识即可作答，无需复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆热电偶护套材料的合适选项。选项C（高温陶瓷）是热电偶护套的常见材料，属于直接记忆性知识，无需复杂辨析或深度理解。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 735, + "question": "Montmorillonite belongs to which type of silicate structure. (a) Island silicate structure (b) Layered silicate structure (c) Chain silicate structure (d) Framework silicate structure", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确的硅酸盐结构类型，符合选择题的特征 | 知识层次: 题目考查对硅酸盐结构分类的基础概念记忆，只需识别蒙脱石属于层状硅酸盐结构即可，不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别蒙脱石属于层状硅酸盐结构这一直接记忆性知识点，无需复杂辨析或深度理解。" + }, + { + "idx": 3246, + "question": "Which of the following statements about zone melting is correct? A. For alloys with $K_{0}<1$, the solute is enriched at the end, and the beginning is purified; for alloys with $K_{0}>1$, the solute is enriched at the beginning, and the end is purified. B. For alloys with $K_{0}<1$, the solute is enriched at the beginning, and the end is purified; for alloys with $K_{0}>1$, the solute is enriched at the end, and the beginning is purified. C. Regardless of $K_{0}<1$ or $K_{0}>1$, the solute is enriched at the beginning. D. Regardless of $K_{0}<1$ or $K_{0}>1$, the solute is enriched at the end.", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个选项中选择关于区域熔炼的正确陈述，符合选择题的特征 | 知识层次: 题目考查对区域熔炼过程中溶质分布规律的理解和应用，需要掌握分配系数K0与溶质分布的关系，并进行综合分析。虽然涉及基础概念，但需要对不同K0值条件下的溶质分布进行判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，因为它不仅要求考生理解分区熔炼的基本原理，还需要掌握分配系数（K0）与溶质分布之间的关系。题目涉及两种不同情况（K0<1和K0>1）的综合分析，要求考生能够正确判断溶质在开始和结束位置的富集与纯化情况。这种多概念综合和复杂分析过程的判断使得该题目在选择题型中属于较难级别。" + }, + { + "idx": 1874, + "question": "When water-based substances melt into a liquid state, their volume undergoes the phenomenon of . A. expansion B. contraction C. no change", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查水基物质熔化时体积变化的基本现象记忆，属于基础概念的记忆和理解范畴 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即水基物质在融化时体积变化的现象。学生只需记住\"水基物质融化时体积收缩\"这一基本事实即可正确作答，无需进行概念辨析或深度理解。题目选项简单明确，属于直接记忆性知识，因此难度等级为1。" + }, + { + "idx": 1746, + "question": "The melt is a mixture of . a. polymers with the same degree of polymerization and free alkali b. various polymers with different degrees of polymerization c. various oligomers d. various high polymers", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且提供了明确的选项和答案 | 知识层次: 题目考查对熔体混合物组成的基本概念记忆和理解，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆层次，要求考生理解\"melt\"的组成成分。虽然需要区分不同聚合度的聚合物概念，但选项间的区分度较为明显，正确选项b直接对应教材定义，无需复杂分析。在选择题型中属于需要简单概念辨析的难度等级。" + }, + { + "idx": 3073, + "question": "What is gray cast iron composed of?", + "answer": "(3) steel matrix; (4) graphite", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案中给出了编号选项(3)和(4)，表明这是一个从多个选项中选择正确组合的选择题。 | 知识层次: 题目考查对灰铸铁组成成分的基础概念记忆，只需回答其基本构成要素（钢基体和石墨），不涉及复杂分析或应用。 | 难度: 在选择题型中，该题目仅需基础概念记忆，直接考察灰铸铁的组成成分（钢基体和石墨），无需复杂理解或辨析，属于简单概念识别层级。" + }, + { + "idx": 4158, + "question": "Match the following material types with their light transmission characteristics: Polycrystalline and nonporous electrical insulators - Translucent, Transparent, Opaque", + "answer": "Polycrystalline and nonporous electrical insulators are translucent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Translucent, Transparent, Opaque）中选择与材料类型（Polycrystalline and nonporous electrical insulators）相匹配的光传输特性，符合选择题的特征。 | 知识层次: 题目考查对材料类型及其光传输特性的基本概念记忆和理解，属于基础知识的直接应用，无需复杂分析或综合推理。 | 难度: 在选择题型中，该题目属于简单概念识别，直接记忆的难度。题目要求匹配材料类型与其透光特性，正确选项直接给出了明确的定义（半透明），无需复杂分析或深度理解，仅需基础概念的记忆即可作答。" + }, + { + "idx": 3241, + "question": "The driving force for atomic diffusion is A. Concentration gradient of components B. Temperature gradient C. Chemical potential gradient of components", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案 | 知识层次: 题目考查对原子扩散驱动力的基本概念的记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然考查的是基础概念记忆，但需要学生对\"原子扩散驱动力\"这一概念有准确理解，并能区分浓度梯度、温度梯度和化学势梯度这三个相近概念。正确选项C不是最直观的选项(学生可能首先想到浓度梯度)，因此需要一定的概念辨析能力，但不需要复杂的分析过程。" + }, + { + "idx": 4154, + "question": "In the visible spectrum, a semiconductor that is a single crystal and nonporous may be(a) Transparent(b) Translucent(c) Opaque", + "answer": "In the visible spectrum, a semiconductor that is a single crystal and nonporous may be transparent or opaque.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a) Transparent、(b) Translucent、(c) Opaque中选择可能的正确答案，符合选择题的特征。 | 知识层次: 题目考查对半导体光学性质的基本概念记忆和理解，只需知道单晶非多孔半导体在可见光谱中可能呈现透明或不透明的特性即可回答，不涉及复杂分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解半导体在可见光谱中的光学性质（透明或不透明），并辨析单晶非多孔结构对光学特性的影响。虽然涉及基础概念记忆，但需要一定的概念理解和简单辨析能力。" + }, + { + "idx": 4145, + "question": "Which of the following characteristics are displayed by soft magnetic materials in terms of magnetization and demagnetization fields?", + "answer": "Magnetization and demagnetization may be achieved using relatively low applied fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择符合软磁材料特性的正确答案 | 知识层次: 题目考查对软磁材料在磁化和退磁过程中特性的基本概念记忆和理解，属于基础概念层次。 | 难度: 该题目属于基础概念记忆层次，仅需识别软磁材料在磁化和退磁方面的基本特性（即\"可用较低外加磁场实现\"这一直接记忆点）。在选择题型中属于最简单的概念识别类题目，无需理解或辨析过程，完全符合等级1\"简单概念识别，直接记忆\"的标准。" + }, + { + "idx": 3053, + "question": "The porosity of thermal insulation material is (3). A.5%~10% B.<5% C.<0.5% D.>10%", + "answer": "(3)D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对热绝缘材料孔隙率范围的基础概念记忆，属于定义性知识的直接回忆。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆热绝缘材料的孔隙率范围即可选择正确答案。选项之间的区分度明显，无需复杂分析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 162, + "question": "Among the following three substances, which one is the least likely to form glass, and why? (1) Na2O·2SiO2; (2) Na2O·SiO2; (3) NaCl", + "answer": "(3) NaCl is the least likely to form glass. NaCl lacks a network structure and is a typical ionic crystal, making it difficult to form glass.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从三个选项中选择最不可能形成玻璃的物质，并解释原因，符合选择题的特征 | 知识层次: 题目要求考生理解玻璃形成的基本原理（网络结构），并能够分析不同物质的化学组成和结构特点（离子晶体vs硅酸盐），从而判断其形成玻璃的能力。这需要将多个概念关联起来进行综合分析，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度，需要综合应用多个概念进行分析判断。题目要求考生不仅了解玻璃形成的基本原理（网络结构的重要性），还需要比较三种不同物质的结构特性（硅酸盐网络结构 vs 离子晶体结构），并做出正确判断。解题过程涉及材料科学中玻璃形成能力的核心概念，需要将晶体结构知识与玻璃形成条件进行关联分析，属于复杂分析过程的判断题型。" + }, + { + "idx": 2753, + "question": "The [001] direction in a cubic crystal is", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确答案，且答案以选项字母形式给出 | 知识层次: 题目考查对立方晶体中[001]方向的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆立方晶体中[001]方向的定义即可作答，无需复杂理解或辨析步骤。" + }, + { + "idx": 2761, + "question": "In substitutional solid solutions, the general mode of atomic diffusion is", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（C） | 知识层次: 题目考查的是置换固溶体中原子扩散的基本模式，属于基础概念的记忆和理解范畴，不需要复杂的分析或综合应用。 | 难度: 在选择题型中，该题目仅涉及基础概念的记忆，即替换固溶体中原子扩散的一般模式。学生只需直接回忆相关定义即可选择正确答案，无需进行复杂的概念辨析或深度理解。因此，该题目在选择题型内属于最简单的难度等级。" + }, + { + "idx": 3545, + "question": "The twinning plane of a face-centered cubic crystal is ( ) A.(112} B.{110} C.111", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查面心立方晶体孪晶面的基本概念记忆，属于对晶体学基础知识的直接回忆，不需要复杂的分析或计算。 | 难度: 该题目属于基础概念记忆，仅需直接回忆面心立方晶体的孪晶面是{111}即可作答，无需理解或辨析其他选项。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 4650, + "question": "Which of the following electron configurations is for an inert gas? \\\\ (A) 1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} \\\\ (B) 1 s^{2} 2 s^{2} 2 p^{6} s 3 s^{2} \\\\ (C) 1 s^{2} 2 s^{2} 2 p^{6} .3 s^{2} 3 p^{6} 4 s^{1} \\\\ (D) 1 s^{2} 2 s^{2} 2 p^{6}·3 s^{2} 3 p^{6} 3 d^{2} 4 s^{2}", + "answer": "The correct answer is A. The 1 s^{2} 2 s^{2} 2 p^{6} 13 s^{2} 3 p^{6} electron configuration is that of an inert gas because of filled 3 s and 3 p subshells.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确的电子构型，符合选择题的特征 | 知识层次: 题目考查对惰性气体电子排布这一基础概念的记忆和理解，无需复杂计算或分析，仅需识别符合惰性气体特征的电子排布即可。 | 难度: 在选择题中属于中等难度，需要理解惰性气体的电子排布特征（即最外层电子排布为s²p⁶），并对给定的电子排布选项进行简单辨析。虽然涉及基础概念记忆，但需要一定的理解能力来识别正确的电子排布模式。" + }, + { + "idx": 4097, + "question": "How are discontinuous fibers typically oriented in fibrous composites?(a) Aligned(b) Partially oriented", + "answer": "Discontinuous fibers may be aligned, partially oriented, and randomly oriented in fibrous composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项(a) Aligned和(b) Partially oriented中选择关于不连续纤维在纤维复合材料中取向方式的正确答案。 | 知识层次: 题目考查对纤维复合材料中不连续纤维取向方式的基本分类记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆纤维复合材料中不连续纤维的典型取向方式。题目直接给出了正确选项，无需进行复杂的辨析或理解多个概念，因此属于简单概念识别和直接记忆的难度等级。" + }, + { + "idx": 4155, + "question": "To which of the following electromagnetic radiation types are bulk metals opaque?(a) radio waves(b) microwaves(c) infrared radiation(d) ultraviolet radiation(e) X-rays", + "answer": "Bulk metals are opaque to the following radiation types: radio waves, microwaves, infrared radiation, and ultraviolet radiation.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)-(e)中选择正确的电磁辐射类型，属于典型的选择题形式。 | 知识层次: 题目考查对金属对不同电磁波段的透明性的基本概念记忆和理解，属于基础知识的直接应用。 | 难度: 在选择题中属于中等偏下难度，题目考察的是对金属对不同电磁波段的透明性这一基础概念的记忆和理解。虽然需要记住多个波段（无线电波、微波、红外辐射、紫外辐射）的共性特征，但不需要进行复杂的比较分析或推导过程，属于概念理解和简单辨析的范畴。" + }, + { + "idx": 3990, + "question": "The bonding forces between adhesive and adherend surfaces are thought to be(a) Electrostatic(b) Covalent(c) Chemical", + "answer": "The bonding forces between adhesive and adherend surfaces are thought to be electrostatic.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项(a)、(b)、(c)中选择一个正确答案，符合选择题的特征。 | 知识层次: 题目考查对粘合剂与被粘物表面之间作用力类型的基本概念记忆，属于基础概念的选择题，不需要复杂的分析或应用。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要考生对粘合剂与被粘物表面之间的结合力类型有一定的理解和辨析能力。正确选项（静电作用）需要考生从三个选项中识别出最符合理论描述的答案，而不仅仅是简单的概念识别。这要求考生对不同类型的结合力有基本的区分能力，但不需要进行复杂的分析或深度理解。" + }, + { + "idx": 1872, + "question": "The crystal structure of diamond is , and the coordination number of carbon atoms is A. face-centered cubic lattice B. simple cubic lattice C. body-centered cubic lattice D. 3 E. 4 F. 6 G. 8", + "answer": "A, E", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案由多个选项组成（A, E），符合选择题的特征。 | 知识层次: 题目考查对金刚石晶体结构和碳原子配位数的基础概念记忆，属于定义和基本原理的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆钻石的晶体结构（面心立方格子）和碳原子的配位数（4）。在选择题型中，这种直接记忆的知识点属于最简单的难度等级，不需要进行概念辨析或深度理解。" + }, + { + "idx": 1897, + "question": "8.The characteristic of reversible polymorphic transformation is: (23)", + "answer": "(23) The polymorphic transformation temperature is lower than the melting points of both crystal forms", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项编号(23)给出，符合选择题的特征 | 知识层次: 题目考查可逆多晶型转变的基本特征，属于对基础概念的记忆和理解，不需要复杂的应用或分析。 | 难度: 该题目属于基础概念记忆层次，要求考生掌握可逆多晶型转变的特征。虽然需要记忆具体定义，但选项直接给出了明确的特征描述（转变温度低于两种晶型的熔点），不需要复杂的分析或比较。在选择题型中属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 4164, + "question": "Match the luminescence characteristics with their descriptions.\nReemission of photons occurs in much less than one second after excitation.\n- Phosphorescence\n- Fluorescence\nReemission of photons occurs in more than one second after excitation.\n- Fluorescence\n- Phosphorescence", + "answer": "Fluorescence involves reemission of photons in much less than one second after excitation; while phosphorescence involves reemission of photons in more than one second after excitation.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从给定的选项中选择正确的匹配项，即将发光特性与描述进行配对。答案部分也明确给出了选项之间的对应关系，符合选择题的特征。 | 知识层次: 题目考查荧光和磷光的基本定义和区别，属于基础概念的记忆和理解 | 难度: 在选择题型中，该题目属于概念理解和简单辨析的难度等级。虽然题目涉及两个不同的发光现象（荧光和磷光），但只需要考生理解并区分两者的基本定义特征（光子再发射的时间差异）。不需要复杂的分析或深度理解多个概念之间的关系，属于基础概念记忆和简单辨析的范畴。" + }, + { + "idx": 3941, + "question": "Which of the following is a (are) linear defect(s)?(a) An edge dislocation(b) A Frenkel defect(c) A Schottky defect", + "answer": "Edge and screw dislocations are linear defects.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择线性缺陷的正确答案，符合选择题的特征 | 知识层次: 题目考查对线性缺陷（linear defects）这一基本概念的记忆和理解，要求从选项中识别出属于线性缺陷的类型。这属于材料科学中晶体缺陷分类的基础知识，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（线性缺陷的定义），但需要考生能够区分不同类型的晶体缺陷（线性缺陷、点缺陷等）。正确选项明确指出了边缘位错属于线性缺陷，但题目中混入了点缺陷选项（Frenkel缺陷和Schottky缺陷），这要求考生不仅要记住定义，还要具备简单的概念辨析能力。不过题目没有涉及更复杂的分析或综合应用，因此难度等级为2。" + }, + { + "idx": 1812, + "question": "The viscosity corresponding to the glass transition temperature Tg is a.108dPa·s b.1010dPa·s c.1011dPa·s d.1013dPa·s", + "answer": "d", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的四个选项中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对玻璃转变温度Tg对应粘度值的记忆，属于基础概念的记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆玻璃转变温度Tg对应的粘度数值即可选出正确答案。在选择题型中，这种仅需简单记忆的知识点属于最低难度等级。" + }, + { + "idx": 4228, + "question": "Which of these elements would you expect to form with copper a substitutional solid solution having complete solubility? Below, atomic radius, crystal structure, electronegativity, and the most common valence are tabulated, for several elements; for those that are nonmetals, only atomic radii are indicated.", + "answer": "Ni, Pd, and Pt meet all of the criteria and thus form substitutional solid solutions having complete solubility. At elevated temperatures Co and Fe experience allotropic transformations to the FCC crystal structure, and thus display complete solid solubility at these temperatures.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从多个元素中选择符合特定条件的元素，答案给出了具体的元素名称，符合选择题的特征。 | 知识层次: 题目要求考生根据给定的元素性质（原子半径、晶体结构、电负性和价态）综合分析并选择能与铜形成完全固溶体的元素。这需要考生理解固溶体的形成条件（Hume-Rothery规则），并将这些规则应用到具体元素的性质分析中。虽然不涉及复杂的计算或多步推理，但需要对多个概念进行关联和综合判断，属于中等应用层次。 | 难度: 在选择题型中，该题目属于较高难度。首先，题目要求考生理解并应用多个材料科学的核心概念，包括原子半径、晶体结构、电负性和价态等。其次，解题过程需要综合分析表格数据，并判断哪些元素满足形成完全固溶体的条件。此外，题目还涉及高温下的同素异构转变，增加了分析的复杂性。因此，该题目在选择题型中属于需要复杂分析过程的判断，符合等级4的标准。" + }, + { + "idx": 2926, + "question": "When a pure metal undergoes an allotropic transformation during cooling from high temperature to room temperature with volume expansion, the atomic coordination number of the low-temperature phase is ___ that of the high-temperature phase. (A) Lower (B) Higher (C) The same", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对同素异构转变过程中原子配位数变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆（同素异构转变和原子配位数），但需要考生理解体积膨胀与配位数变化之间的关系，并进行简单辨析。题目不涉及复杂概念的区分或深度理解，但比直接记忆性题目（等级1）要求稍高。" + }, + { + "idx": 4148, + "question": "What is the order of magnitude wavelength for visible light?(a) 0.5 Angstroms(b) 0.5 nanometers(c) 0.5 micrometers(d) 0.5 millimeters(e) 0.5 meters(f) 0.5 kilometers", + "answer": "The wavelength of visible light is on the order of 0.5 \\mathrm{micrometers}.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案明确指出了正确选项 | 知识层次: 题目考查对可见光波长范围这一基础概念的简单记忆，属于材料科学中最基础的光学知识范畴，不需要任何计算或分析过程。 | 难度: 在选择题型中，该题目仅需基础概念记忆，即对可见光波长大小的直接记忆。选项提供了不同数量级的波长，但正确答案（0.5 micrometers）是可见光波长的典型值，属于直接识别的简单概念，无需复杂理解或辨析。" + }, + { + "idx": 4096, + "question": "How are continuous fibers typically oriented in fibrous composites?(a) Aligned(b) Partially oriented(c) Randomly oriented", + "answer": "Continuous fibers are typically aligned in fibrous composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从三个选项(a)(b)(c)中选择关于纤维复合材料中连续纤维取向方式的正确答案 | 知识层次: 题目考查对纤维复合材料中连续纤维排列方式的基本概念的记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别连续纤维在纤维复合材料中的典型排列方式（对齐）。选项直接对应定义，无需复杂辨析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 2770, + "question": "According to the vertical section of a ternary phase diagram, one can", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项字母形式给出（B） | 知识层次: 题目考查对三元相图垂直截面图的基本理解和记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅考察对三元相图垂直截面基本功能的记忆性知识，属于最基础的概念识别层级。学生只需直接回忆教材定义即可作答，无需任何理解或分析过程。" + }, + { + "idx": 4094, + "question": "A stress-strain test is performed on an aligned fibrous composite such that the force is applied in the longitudinal direction. During the initial stage of the test, which phase bears most of the load?(a) Fibers(b) Matrix", + "answer": "During a stress-strain test that is performed on an aligned fibrous composite, the fibers bear more of the applied load than the matrix in the initial stage of the test.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从两个选项（Fibers和Matrix）中选择一个正确答案 | 知识层次: 题目考查对纤维增强复合材料在初始受力阶段载荷分布的基本概念的理解，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆复合材料中纤维和基体在初始受力阶段的负载分配情况。题目直接考察学生对基本定义和分类的记忆，无需深入理解或辨析复杂概念，因此属于简单难度等级。" + }, + { + "idx": 734, + "question": "In the $\\\\mathbf{ABO}_{3}$ (perovskite) type structure, B ions occupy (a) tetrahedral voids (b) octahedral voids (c) cubic voids (d) trigonal prismatic voids", + "answer": "b", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)-(d)中选择B离子在钙钛矿结构中所占据的空隙类型，符合选择题的特征 | 知识层次: 题目考查对钙钛矿结构中离子占据位置的基础概念记忆，属于定义和分类层面的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆ABO3钙钛矿结构中B离子占据的间隙类型（八面体间隙），无需复杂分析或概念辨析。属于最简单的直接记忆类题目。" + }, + { + "idx": 4150, + "question": "In the visible spectrum, an electrical insulator that is a single crystal and without porosity is normally(a) Transparent(b) Opaque(c) Translucent", + "answer": "In the visible spectrum, an electrical insulator that is a single crystal and without porosity\nnormally transparent.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Transparent, Opaque, Translucent）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查对材料光学性质的基本概念记忆和理解，特别是关于单晶无孔绝缘体在可见光谱中的透明性这一基础知识点。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别单晶无孔绝缘体在可见光谱下的透明特性。选项直接对应材料科学基本概念，无需复杂分析或概念辨析，属于最简单的难度等级。" + }, + { + "idx": 2762, + "question": "The condition for an alloy to develop constitutional supercooling during solidification is . (where $T_{\\\\ L}$ is the solidification start temperature of the alloy with composition $C_{\\\\mathrm{L}}$)", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "medium_application", + "knowledge_level_name": "中等应用", + "difficulty": 4, + "final_level": "Level_4", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项A作为答案 | 知识层次: 题目考查合金凝固过程中成分过冷的条件判断，需要理解凝固温度与成分的关系，并综合分析相关参数的影响，属于中等应用层次。 | 难度: 在选择题中属于较高难度，需要理解合金凝固过程中的多个概念（如固相线温度、成分过冷条件等），并能够将这些概念关联起来进行综合分析判断。题目要求考生不仅掌握基础概念，还需要进行多步计算和逻辑推理才能得出正确结论，这超出了简单记忆或单一概念应用的范畴。" + }, + { + "idx": 4137, + "question": "Which of the following materials display(s) antiferromagnetic behavior?(a) Aluminum oxide(b) Copper(c) Aluminum(d) Titanium(e) Iron ( \\alpha ferrite)(f) Nickel(g) MnO\nh) \\mathrm{Fe}_{3} \\mathrm{O}_{4}\ni) \\mathrm{NiFe}_{2} \\mathrm{O}_{4}", + "answer": "(\\mathrm{MnO} is an antiferromagnetic material.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择显示反铁磁行为的材料，符合选择题的特征 | 知识层次: 题目考查对反铁磁性材料的基本概念和分类的记忆，只需识别哪些材料具有反铁磁性行为，不需要复杂的分析或计算。 | 难度: 在选择题型中，该题目需要考生理解并辨析不同材料的磁性行为，特别是区分反铁磁性与其他磁性（如铁磁性、顺磁性等）。虽然题目提供了多个选项，但正确选项（MnO）是典型的反铁磁性材料，属于基础概念记忆的范畴。考生需要掌握材料分类的基本原理，但不需要复杂的分析或深度理解，因此属于中等难度（等级2）。" + }, + { + "idx": 2755, + "question": "In a crystal, the defect formed by creating a vacancy while simultaneously generating an interstitial atom is called", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查晶体缺陷的基本概念和分类，属于定义和基本原理的记忆性知识。 | 难度: 在选择题型中，此题属于基础概念记忆，仅需识别并回忆晶体缺陷的定义和分类。题目直接考察对\"Frenkel defect\"这一术语的记忆，无需复杂理解或分析，属于最简单的难度等级。" + }, + { + "idx": 2768, + "question": "The effective distribution coefficient $K_{i}$ represents the degree of mixing in the liquid phase, and its value range is . (where $K_{\\circ}$ is the equilibrium distribution coefficient)", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（B） | 知识层次: 题目考查对有效分布系数$K_{i}$的定义及其取值范围的基本概念记忆，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生记住有效分配系数的定义及其取值范围。虽然需要理解概念，但不需要进行复杂的分析或比较，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 4115, + "question": "Which of the following materials are typically used as wires in composites?(a) graphite/carbon(b) silicon carbide(c) silicon nitride\n\\mathrm{d}) aluminum oxide(e) glass(f) boron(g) steel\nh) tungsten\ni) molybdenum", + "answer": "Steel, tungsten, and molybdenum are typically used as wires in composites.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择哪些材料通常用作复合材料中的线材，答案给出了具体的选择项。 | 知识层次: 题目考查对复合材料中常用线材的基本概念和分类的记忆，属于基础概念记忆性知识。 | 难度: 该题目属于基础概念记忆类型，要求考生识别复合材料中常用的金属丝材料。虽然选项较多（9个），但正确答案（steel, tungsten, molybdenum）都是典型的金属丝材料，在材料科学基础课程中会明确提及。需要考生对这些材料的典型应用有一定记忆和理解，但不需要复杂的分析过程。相比等级1的纯记忆题目，本题需要对材料分类和应用有基本理解，因此属于等级2难度。" + }, + { + "idx": 2937, + "question": "A sample composed of three components is analyzed by X-ray diffraction (XRD) in air to study its phase transformation with temperature changes. The maximum number of coexisting phases that can be recorded is .", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，答案以选项形式给出（C） | 知识层次: 题目考查对相律（Gibbs Phase Rule）这一基础概念的记忆和理解，属于材料科学中最基本的相平衡原理知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆X射线衍射（XRD）分析中相变研究的基本原理，即吉布斯相律（Gibbs Phase Rule）在开放系统中的简单应用。题目无需复杂分析或概念辨析，仅需记住在空气环境下（开放系统）最大共存相数的定义即可选出正确答案。因此属于最简单的难度等级。" + }, + { + "idx": 3018, + "question": "When a polymer material is subjected to force, the elasticity achieved by the elongation of bond length is (1). A. Ordinary elasticity B. High elasticity C. Viscoelasticity D. Forced elasticity", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C、D中选择一个正确答案 | 知识层次: 题目考查对聚合物材料弹性类型的基本概念记忆和理解，属于定义性知识，不需要复杂的分析或计算。 | 难度: 在选择题中属于中等偏下难度，需要理解聚合物材料在受力时的弹性类型，并进行简单辨析。虽然涉及基础概念记忆，但需要区分不同弹性类型的定义，属于概念理解和简单辨析的层次。" + }, + { + "idx": 3048, + "question": "What type of chemical bond is primarily found in oxides? A. Metallic bond B. Covalent bond C. Molecular bond D. Ionic bond", + "answer": "D", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择关于氧化物中主要化学键类型的正确答案 | 知识层次: 题目考查对氧化物中主要化学键类型的基础概念记忆，属于定义和分类层面的基本知识。 | 难度: 在选择题型中，此题属于基础概念记忆类型，仅需识别氧化物中主要存在的化学键类型（离子键），无需进行概念辨析或复杂分析。题目选项直接对应基本知识点，属于最简单的难度等级。" + }, + { + "idx": 3111, + "question": "The temperature coefficient of resistance (1) of resistive materials. A. The larger the better B. The smaller the better C. No requirement on size", + "answer": "(1)C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案 | 知识层次: 题目考查对电阻材料温度系数这一基本概念的记忆和理解，属于基础概念记忆性知识 | 难度: 该题目属于基础概念记忆类型，仅需直接回忆电阻温度系数的基本定义即可作答。在选择题型中属于最简单的难度等级，不需要任何分析或推理过程，完全依赖对基础概念的识记能力。" + }, + { + "idx": 3565, + "question": "The dislocations that can undergo cross-slip must be (). \\n\\nA. Edge dislocation B. Screw dislocation C. Mixed dislocation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项A、B、C中选择正确答案，符合选择题的特征 | 知识层次: 题目考查位错类型及其特性的基本概念记忆，属于对screw dislocation能够进行cross-slip这一特性的直接认知。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆（位错类型），但需要学生对不同类型的位错（刃型位错、螺型位错、混合位错）有明确的理解和区分能力。特别是要理解为什么只有螺型位错能够进行交滑移，这需要一定的概念辨析能力，而非简单的记忆。因此属于等级2难度。" + }, + { + "idx": 4090, + "question": "For an aligned fibrous composite, when a stress is applied in a direction that is parallel to the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d) \\frac{3}{4}(e) 1", + "answer": "For an aligned fibrous composite when the stress is applied parallel to the fibers, the reinforcement efficiency is 1 .", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)到(e)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查的是对齐纤维复合材料在应力平行于纤维方向时的增强效率这一基本概念的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆复合材料中纤维排列方向与应力方向平行时的增强效率定义即可作答，无需复杂理解或分析步骤。" + }, + { + "idx": 1871, + "question": "Kaolinite belongs to the silicate of . A. Chain structure B. Layered structure C. Framework structure D. Island structure", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对高岭石（Kaolinite）所属硅酸盐结构类型的基础概念记忆，属于定义和分类的记忆性知识。 | 难度: 在选择题型中，此题属于简单概念识别，直接记忆类型。题目直接考察高岭石属于哪种硅酸盐结构，只需记住高岭石属于层状结构即可作答，无需进行概念辨析或复杂分析。" + }, + { + "idx": 4026, + "question": "A solvus line separates which of the following pairs of phase fields?(a) Liquid and Liquid +\\alpha(b) \\alpha \\operatorname{and} Liquid +\\alpha(c) \\alpha and \\alpha+\\beta d) Liquid +\\alpha and \\alpha+\\beta", + "answer": "A solvus line separates \\alpha and \\alpha+\\beta phase fields.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目提供了多个选项（a-d），要求从中选择正确答案，符合选择题的特征。 | 知识层次: 题目考查对相图中solvus线定义的基本概念记忆，仅需识别solvus线分隔的相区类型，属于基础概念记忆层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目考察的是基础概念记忆，但需要学生对相图中的solvus线有清晰的理解，并能正确区分不同相区之间的关系。题目要求学生在四个选项中识别出solvus线所分隔的正确相区对，这需要一定的概念理解和简单辨析能力，而不仅仅是简单的记忆。因此，该题目在选择题型内属于等级2难度。" + }, + { + "idx": 4159, + "question": "Match the following material types with their light transmission characteristics: Porous electrical insulators - Transparent, Opaque, Translucent", + "answer": "Porous electrical insulators are opaque to visible light.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项（Transparent, Opaque, Translucent）中选择与材料类型（Porous electrical insulators）匹配的光传输特性。 | 知识层次: 题目考查对材料光学特性分类的基础概念记忆，仅需将材料类型与透光性进行简单匹配，不涉及复杂推理或综合分析。 | 难度: 在选择题型中，该题目属于基础概念记忆，仅需识别和回忆材料的光学特性分类。题目直接给出了材料类型和其对应的光传输特性，无需进行复杂辨析或深度理解，属于最简单的概念识别类型。" + }, + { + "idx": 2947, + "question": "The dislocation that can undergo cross-slip must be (A) edge dislocation (B) screw dislocation (C) mixed dislocation", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择关于位错类型的正确答案 | 知识层次: 题目考查对位错类型及其特性的基本概念记忆和理解，属于基础概念记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，要求考生理解并区分不同类型的位错（刃型位错、螺型位错、混合位错）的基本特性。虽然题目直接考察的是记忆性知识，但需要考生对位错类型及其行为（如交滑移）有明确的理解和简单辨析能力，因此属于中等难度。" + }, + { + "idx": 4651, + "question": "What type(s) of bonding would be expected for bronze (a copper-tin alloy)?\n(A) Ionic bonding\n(B) Metallic bonding\n(C) Covalent bonding with some van der Waals bonding\n(D) van der Waals bonding", + "answer": "The correct answer is B. For bronze, the bonding is metallic because it is a metal alloy.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案 | 知识层次: 题目考查对金属合金键合类型的基本概念记忆和理解，属于基础知识点。 | 难度: 该题目属于基础概念记忆题，仅需识别青铜（铜锡合金）的键合类型为金属键。题目直接给出选项，无需复杂分析或概念辨析，属于选择题型中最简单的难度等级。" + }, + { + "idx": 4144, + "question": "Which of the following characteristics are displayed by soft magnetic materials in terms of hysteresis loop size?", + "answer": "Soft materials have relatively small relative hysteresis loops.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择关于软磁材料磁滞回线特性的正确答案 | 知识层次: 题目考查软磁材料的基本特性——磁滞回线大小的记忆和理解，属于基础概念的记忆性知识。 | 难度: 在选择题型中，该题目仅要求识别软磁材料的基本特性（磁滞回线较小），属于直接记忆的基础概念，无需复杂分析或比较。" + }, + { + "idx": 3019, + "question": "The one that is easier to obtain a crystalline structure is (1). B. Branched molecules A. Linear molecules C. Three-dimensional molecules", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，且答案形式为选项编号 | 知识层次: 题目考查对分子结构与结晶性关系的基础概念记忆，只需区分线性分子和支化/三维分子在结晶难易度上的基本差异，属于基础概念记忆范畴。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，仅需识别线性分子更容易形成晶体结构这一简单事实。题目选项直接对应知识点，无需复杂分析或深度理解，属于最简单的概念识别类型。" + }, + { + "idx": 3112, + "question": "Shape memory alloy components undergo plastic deformation in the (1) state and recover their original shape after (2). A. Martensite Heating transforms into parent phase B. Parent phase Cooling transforms into martensite C. Martensite Staying for several days D. Parent phase Heating transforms into new parent phase", + "answer": "(1)A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查形状记忆合金的基本相变过程，属于基础概念的记忆和理解，不需要复杂的分析或应用。 | 难度: 在选择题中属于中等偏下难度，需要理解形状记忆合金的基本原理和相变过程，但选项设计较为直接，只需识别正确的相变状态即可选出答案。" + }, + { + "idx": 3834, + "question": "Is the alloy hypoeutectic or hypereutectic?", + "answer": "hypoeutectic", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从\"hypoeutectic\"或\"hypereutectic\"两个选项中选择正确答案 | 知识层次: 题目考查对合金分类（hypoeutectic或hypereutectic）的基本概念记忆和理解，属于基础概念层次。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及的是基础概念记忆，但需要学生理解并区分\"hypoeutectic\"和\"hypereutectic\"这两个专业术语的含义。这超出了简单的概念识别（等级1），需要一定的概念理解和辨析能力（等级2），但不需要进行复杂的分析或深度理解（等级3）。" + }, + { + "idx": 3040, + "question": "Which compounds can be used to prepare high-temperature ceramics?", + "answer": "(1) Oxides; (2) Carbides; (3) Nitrides; (4) Borides; (5) Silicides", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择可以用于制备高温陶瓷的化合物，答案给出了多个具体选项供选择 | 知识层次: 题目考查对高温陶瓷制备材料的分类和基本概念的记忆，不需要复杂的分析或综合应用。 | 难度: 该题目属于基础概念记忆类型，仅需识别和记忆哪些化合物可用于制备高温陶瓷。正确选项直接列出了氧化物、碳化物、氮化物、硼化物和硅化物，这些都是高温陶瓷的常见原料，无需深入理解或辨析。因此，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 3567, + "question": "The fundamental reason for diffusion to occur in materials is ( ). \\n\\nA. Temperature changes B. Concentration gradient exists C. Chemical potential gradient exists", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从多个选项（A、B、C）中选择一个正确答案，符合选择题的特征 | 知识层次: 题目考查扩散现象的基本原理，属于基础概念的记忆和理解。虽然涉及化学势梯度这一概念，但整体仍属于材料科学中最基础的知识点。 | 难度: 在选择题中属于中等偏下难度，需要理解扩散的基本原理并区分浓度梯度和化学势梯度的概念。虽然题目考查的是基础概念记忆，但需要一定的概念辨析能力，不能仅靠简单记忆回答。" + }, + { + "idx": 3563, + "question": "When the deformed material is heated up again, recovery and recrystallization phenomena occur, then the significant decrease in point defect concentration happens during ().", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了多个选项（虽然只显示了选项A，但题目结构表明这是选择题） | 知识层次: 题目考查对材料科学中恢复和再结晶过程中点缺陷浓度变化的基础概念记忆和理解，属于基本原理的记忆性知识。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需识别和回忆点缺陷浓度显著降低发生的阶段（恢复和再结晶现象）。无需复杂辨析或深度理解，属于直接记忆性知识。" + }, + { + "idx": 2977, + "question": "In binary phase diagrams, the lever rule for calculating the relative amounts of two phases can only be used in", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（B） | 知识层次: 题目考查对杠杆规则应用条件的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于中等偏下难度。虽然需要理解杠杆法则的基本原理和应用条件，但题目仅要求识别该法则的使用范围（两相区），属于概念理解和简单辨析层面。不需要进行复杂计算或多概念交叉分析，因此难度低于需要深度理解的题目。" + }, + { + "idx": 699, + "question": "In the face-centered cubic crystal structure, the close-packed plane is (a) {001} plane (b) {011} plane (c) {111} plane", + "answer": "The main reasons for clay charging are: (11) (12) and (13)", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查面心立方晶体结构中密排面的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆面心立方晶体结构中最密排面的晶面指数即可。选项(c) {111} plane是晶体学中的基本常识，无需复杂分析或理解，属于简单概念识别层次。" + }, + { + "idx": 4009, + "question": "The mineral olivine is a solid solution of the silicate compounds forsterite \\left(Mg_{2} \\mathrm{SiO}_{4}\\right) and fayalite \\left(\\mathrm{Fe}_{2} \\mathrm{SiO}_{4}\\right).\nHow many chemical components are there in a sample of olivine?\n(a) 1\n(b) 2\n(c) 3\n(d) 4", + "answer": "The components of a system are defined to be the smallest set of independently variable chemical constituents that are necessary to describe the composition of each phase that is present in a system. Components are chemically distinct. In this case, we only need to specify two things. It is convenient to simply use the compounds themselves as the components, but other options exist. For instance, specifying the amount of Mg and \\mathrm{Fe} in the system automatically fixes the \\mathrm{Si} and \\mathrm{O} content, assuming the compounds are present in their stoichiometric ratios (assuming they are defect free).", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项(a)到(d)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对化学组分基本概念的理解和记忆，需要识别并应用组分定义来分析矿物橄榄石的组成。虽然涉及一定的逻辑推理，但主要依赖于对基础概念的掌握。 | 难度: 在选择题型中，该题目属于中等难度。虽然题目涉及基础概念记忆，但需要理解“化学组分”的定义及其在具体矿物（橄榄石）中的应用。解题步骤包括识别橄榄石的组成（镁橄榄石和铁橄榄石），并理解如何根据定义确定化学组分的数量。这需要一定的概念理解和简单辨析能力，而不仅仅是直接记忆。因此，在选择题型内属于等级2难度。" + }, + { + "idx": 4088, + "question": "Silica refractory ceramics are often used for the containment of slags that are rich in(a) silica(b) \\mathrm{CaO}(c) Mg \\mathrm{O}", + "answer": "Silica refractory ceramics are often used for the containment of slags that are rich in silica.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案 | 知识层次: 题目考查对硅质耐火陶瓷材料基本用途的记忆和理解，属于基础概念的记忆性知识 | 难度: 在选择题型中，该题目仅需识别和记忆基础概念（硅质耐火陶瓷的用途），无需理解或辨析其他选项。属于直接记忆性知识，符合等级1的简单概念识别标准。" + }, + { + "idx": 3244, + "question": "Which of the following statements about dislocation loops is correct? A. A dislocation loop cannot be entirely edge dislocation everywhere. B. A dislocation loop can be entirely edge dislocation everywhere. C. A dislocation loop must simultaneously contain both edge dislocation and screw dislocation. D. A dislocation loop must simultaneously contain edge dislocation, screw dislocation, and mixed dislocation.", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从四个选项中选择关于位错环的正确陈述，符合选择题的特征 | 知识层次: 题目考查对位错环基本概念的理解，属于对位错类型（刃型位错和螺型位错）及其在环状结构中分布情况的记忆性知识。 | 难度: 在选择题中属于中等偏下难度，需要理解位错环的基本概念和类型，并能区分边缘位错和螺型位错的特征。虽然涉及概念辨析，但不需要复杂的分析步骤。" + }, + { + "idx": 3885, + "question": "Which class of material is generally associated with the highest density values at room temperature? (a) Composites (b) Ceramics (c) Metals (d) Polymers", + "answer": "(c) Metals", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从四个选项中选择正确答案，且答案形式为单一选项 | 知识层次: 题目考查对不同材料类别基本特性的记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆类型，仅需识别不同材料类别的密度特性，无需复杂辨析或深度理解。在选择题型中，直接记忆金属通常具有最高密度即可作答，属于最简单的难度等级。" + }, + { + "idx": 2764, + "question": "When a critical nucleus forms, the reduction in volume free energy can only compensate for the surface energy by ", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（B） | 知识层次: 题目考查的是关于临界核形成时体积自由能和表面能之间关系的基本概念记忆，属于对基本原理的理解和记忆性知识。 | 难度: 该题目属于基础概念记忆类型，主要考察对临界核形成时体积自由能与表面能关系的理解。虽然需要一定的概念理解，但选项直接指向基本原理，不需要复杂的分析或比较，因此在选择题型中属于中等偏下难度。" + }, + { + "idx": 4087, + "question": "Basic refractory ceramics are often used for the containment of slags that are rich in(a) silica(b) \\mathrm{CaO}(c) MgO", + "answer": "Basic refractory ceramics are often used for the containment of slags that are rich in \\mathrm{CaO} and/or MgO.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)、(b)、(c)中选择正确答案，符合选择题的特征 | 知识层次: 题目考查基础耐火陶瓷材料的基本分类和用途，属于基础概念的记忆和理解范畴 | 难度: 该题目属于基础概念记忆类型，仅需识别和记忆基本耐火陶瓷用于富含CaO和/或MgO的炉渣的常识。在选择题型中，属于最简单的直接记忆类题目，无需复杂理解或分析。" + }, + { + "idx": 3991, + "question": "Deformation of a semicrystalline polymer by drawing produces which of the following in the direction of drawing?", + "answer": "Increase in strength in the direction of drawing.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，虽然题目中没有明确列出选项，但根据问题的结构和答案的形式可以推断这是一个选择题。 | 知识层次: 题目考查对半结晶聚合物变形行为的基本概念记忆，只需知道拉伸会导致强度增加这一基本原理即可作答，不涉及复杂分析或计算。 | 难度: 在选择题型中，该题目属于基础概念记忆层次，考察的是对半结晶聚合物拉伸变形后性能变化的基本理解。虽然需要记忆特定知识点（拉伸方向强度增加），但不需要复杂的分析或概念区分，属于概念理解和简单辨析的难度等级。" + }, + { + "idx": 3556, + "question": "When a critical nucleus forms, the decrease in volume free energy can only compensate for ( ) of the surface energy.", + "answer": "B", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且提供了选项（B）作为答案 | 知识层次: 题目考查对临界核形成时体积自由能和表面能关系的基本概念记忆，属于基础概念的理解层面，不需要复杂的计算或分析。 | 难度: 该题目属于基础概念记忆层次，考察的是对临界核形成时体积自由能与表面能量关系的理解。虽然需要理解这两个概念之间的关系，但题目仅要求选择能够补偿表面能量的部分，属于概念理解和简单辨析的范畴，不需要复杂的分析或比较。因此，在选择题型中属于中等难度。" + }, + { + "idx": 4027, + "question": "Which of the following kinds of information may be determined with the aid of a phase diagram? The phase(s) present at a specified temperature and composition.", + "answer": "With the aid of a phase diagram the following may be determined: The phase(s) present at a specified temperature and composition.", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从给定的选项中选择正确的信息类型，符合选择题的特征 | 知识层次: 题目考查对相图基本功能的理解和记忆，即通过相图确定特定温度和成分下的相组成，属于基础概念的记忆性知识。 | 难度: 该题目属于基础概念记忆类型，仅需识别相图的基本功能（确定特定温度和成分下的相态），无需复杂分析或概念辨析。在选择题型中属于最简单的直接记忆类题目。" + }, + { + "idx": 3012, + "question": "To which category of compounds do Teflon (polytetrafluoroethylene) and Plexiglas (polymethyl methacrylate) belong? Options: A. Carbon-chain organic polymers B. Heterochain organic polymers C. Elemental organic compounds D. Inorganic polymers", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从多个选项中选择正确答案，符合选择题的特征 | 知识层次: 题目考查对聚合物基本分类的记忆和理解，属于基础概念层次 | 难度: 该题目属于基础概念记忆类型，仅需识别Teflon和Plexiglas属于碳链有机聚合物这一简单事实。选项直接对应记忆性知识，无需复杂理解或辨析过程，在选择题型中属于最简单的难度等级。" + }, + { + "idx": 2932, + "question": "In ionic crystals, if Schottky defects are formed in a local region, the concentration of cation vacancies in this region is equal to . \\n\\n(A) Anion vacancy concentration (B) Interstitial anion concentration (C) Interstitial cation concentration", + "answer": "A", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项（A、B、C）中选择正确答案，符合选择题的特征 | 知识层次: 题目考查离子晶体中肖特基缺陷的基本概念，即阳离子空位浓度与阴离子空位浓度的关系，属于基础概念的记忆和理解。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆Schottky缺陷的定义即可得出正确答案。题目选项设计简单，没有涉及复杂的概念辨析或深度理解，符合等级1的简单概念识别标准。" + }, + { + "idx": 4091, + "question": "For an aligned fibrous composite, when a stress is applied perpendicular to the fibers, what is the reinforcement efficiency?(a) 0(b) \\frac{1}{5}(c) \\frac{3}{8}(d)\n\\frac{3}{4}(e) 1", + "answer": "begin{tabular}{l|l|l|l|l|l|l|l|l|l|l|}\n\\hline\n\\end{tabular}\nFor an aligned fibrous composite when a stress is applied perpendicular to the fibers, the reinforcement efficiency is 0 .", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 1, + "final_level": "Level_1", + "reasoning": "题型: 题目要求从选项(a)-(e)中选择正确答案，且答案形式为选择题的选项形式 | 知识层次: 题目考查对纤维增强复合材料中增强效率这一基本概念的记忆和理解，特别是当应力垂直于纤维方向时的特殊情况。不需要复杂的计算或分析，只需记住在这种情况下增强效率为零即可。 | 难度: 在选择题型中，该题目属于基础概念记忆类型，仅需直接回忆复合材料中纤维排列与应力方向关系的基本原理即可作答，无需复杂分析或理解多个概念。题目直接考察了当应力垂直于纤维方向时增强效率为零的定义，属于简单概念识别和直接记忆的范畴。" + }, + { + "idx": 2765, + "question": "In the Kirkendall effect, the main reason for marker drift is the diffusion couple's ", + "answer": "C", + "question_type": "multiple_choice", + "question_type_name": "选择题", + "knowledge_level": "basic_concepts", + "knowledge_level_name": "基础概念记忆", + "difficulty": 2, + "final_level": "Level_2", + "reasoning": "题型: 题目要求从选项中选择正确答案，且答案以选项形式给出（C） | 知识层次: 题目考查Kirkendall效应的基本概念和原因，属于对基本原理的记忆和理解。 | 难度: 在选择题中属于中等偏下难度，需要理解Kirkendall效应的基本原理和标记漂移的原因，但不需要进行复杂的比较分析或深度推理。" } ] \ No newline at end of file diff --git a/layer2/PGEE/code/step4_high_quality.py b/layer2/PGEE/code/step4_high_quality.py index bba5961..77f10b1 100644 --- a/layer2/PGEE/code/step4_high_quality.py +++ b/layer2/PGEE/code/step4_high_quality.py @@ -10,16 +10,16 @@ class QuestionFilterAndSelector: def __init__(self): # 各题型的最低难度阈值（排除过于简单的题目） self.min_difficulty_thresholds = { - "calculation": 2, # 计算题：排除难度1的基础计算 - "short_answer": 2, # 简答题：排除难度1的简单记忆 - "true_false": 2, # 判断题：排除难度1的基础概念判断 - "multiple_choice": 2 # 选择题：排除难度1的简单选择 + "calculation": 1, # 计算题：排除难度1的基础计算 + "short_answer": 1, # 简答题：排除难度1的简单记忆 + "true_false": 1, # 判断题：排除难度1的基础概念判断 + "multiple_choice": 1 # 选择题：排除难度1的简单选择 } # 各知识层次的最低难度要求 self.knowledge_level_min_difficulty = { - "basic_concepts": 2, # 基础概念至少难度2（需要理解，不只是记忆） - "simple_application": 2, # 简单应用至少难度2 + "basic_concepts": 1, # 基础概念至少难度2（需要理解，不只是记忆） + "simple_application": 1, # 简单应用至少难度2 "medium_application": 2, # 中等应用至少难度2 "complex_analysis": 3, # 复杂分析至少难度3 "advanced_synthesis": 4 # 高级综合至少难度4 @@ -41,14 +41,29 @@ class QuestionFilterAndSelector: "advanced_synthesis": 0.05 # 5% 高级综合 }, "difficulty_levels": { - 1: 0.05, # 5% 难度1（仅保留最有价值的） - 2: 0.25, # 25% 难度2 + 1: 0.15, # 5% 难度1（仅保留最有价值的） + 2: 0.15, # 25% 难度2 3: 0.35, # 35% 难度3 4: 0.25, # 25% 难度4 5: 0.10 # 10% 难度5 } } + def clean_text_for_excel(self, text: str) -> str: + """清理文本，移除Excel不支持的字符""" + if not isinstance(text, str): + return str(text) + + # 移除或替换Excel不支持的控制字符 + # 保留常见的可打印字符 + cleaned = ''.join(char if ord(char) >= 32 or char in '\t\n\r' else ' ' for char in text) + + # 限制长度，避免Excel单元格过长 + if len(cleaned) > 32767: # Excel单元格字符限制 + cleaned = cleaned[:32760] + "..." + + return cleaned + def filter_questions_by_quality(self, questions: List[Dict]) -> List[Dict]: """第一步：按质量标准过滤题目""" filtered_questions = [] @@ -72,9 +87,9 @@ class QuestionFilterAndSelector: if difficulty < min_level_difficulty: continue - # 特殊过滤规则 - if self._should_exclude_question(q): - continue + # # 特殊过滤规则 + # if self._should_exclude_question(q): + # continue filtered_questions.append(q) @@ -92,8 +107,8 @@ class QuestionFilterAndSelector: if len(q['question'].strip()) < 20: # 题目太短 return False - if len(q['answer'].strip()) < 5: # 答案太短 - return False + # if len(q['answer'].strip()) < 5: # 答案太短 + # return False return True @@ -469,14 +484,25 @@ def main_filter_questions(): # 导出详细分析 try: - df_original = pd.DataFrame(all_questions) - df_selected = pd.DataFrame(selected_questions) + # 清理数据中的特殊字符 + cleaned_selected = [] + for q in selected_questions: + cleaned_q = {} + for key, value in q.items(): + cleaned_q[key] = selector.clean_text_for_excel(value) + cleaned_selected.append(cleaned_q) + + df_selected = pd.DataFrame(cleaned_selected) with pd.ExcelWriter(ANALYSIS_FILE, engine='openpyxl') as writer: - df_selected.to_excel(writer, sheet_name='筛选结果', index=False) + # df_selected.to_excel(writer, sheet_name='筛选结果', index=False) + # 只保存关键字段到Excel，避免长文本问题 + summary_df = df_selected[['question_type', 'knowledge_level', 'difficulty', 'final_level']].copy() + summary_df.to_excel(writer, sheet_name='筛选结果概要', index=False) # 统计对比 comparison_data = [] + df_original = pd.DataFrame(all_questions) for metric in ['question_type', 'knowledge_level', 'difficulty']: orig_dist = df_original[metric].value_counts(normalize=True) * 100 sel_dist = df_selected[metric].value_counts(normalize=True) * 100 diff --git a/layer2/PGEE/code/step4_question_analysis.xlsx b/layer2/PGEE/code/step4_question_analysis.xlsx index c470a3a..5c0e595 100644 Binary files a/layer2/PGEE/code/step4_question_analysis.xlsx and b/layer2/PGEE/code/step4_question_analysis.xlsx differ diff --git a/layer2/PGEE/code/step4_selection_analysis.xlsx b/layer2/PGEE/code/step4_selection_analysis.xlsx index c773503..b5776ac 100644 Binary files a/layer2/PGEE/code/step4_selection_analysis.xlsx and b/layer2/PGEE/code/step4_selection_analysis.xlsx differ